An Investigation of the Painting Technique in Portraits by Jens Juel

DEFF Research Database (Denmark)

Slotsgaard, Tine Louise

2014-01-01

This paper summarizes the findings of the first technical art historical study executed on paintings by the Danish portrait painter Jens Juel. Eight portrait paintings on canvas from two different time periods in the career of Jens Juel have been examined and compared in order to establish the use...... of materials, working methods and painting techniques, and whether an artistic development can be traced. The findings include the characteristics of the canvas structure and painting grounds, how the canvas was prepared and the artist’s use of underdrawing, as well as the layered build up of the carnation...

Application of Chemometric Techniques to Colorimetric Data in Classifying Automobile Paint

International Nuclear Information System (INIS)

Nur Awatif Rosli; Rozita Osman; Norashikin Saim; Mohd Zuli Jaafar

2015-01-01

The analysis of paint chips is of great interest to forensic investigators, particularly in the examination of hit-and run cases. This study proposes a direct and rapid method in classifying automobile paint samples based on colorimetric data sets; absorption value, reflectance value, luminosity value (L), degree of redness (a) and degree of yellowness (b) obtained from video spectral comparator (VSC) technique. A total of 42 automobile paint samples from 7 manufacturers were analysed. The colorimetric datasets obtained from VSC analysis were subjected to chemometric technique namely cluster analysis (CA) and principal component analysis (PCA). Based on CA, 5 clusters were generated; Cluster 1 consisted of silver color, cluster 2 consisted of white color, cluster 3 consisted of blue and black colors, cluster 4 consisted of red color and cluster 5 consisted of light blue color. PCA resulted in two latent factors explaining 95.58 % of the total variance, enabled to group the 42 automobile paints into five groups. Chemometric application on colorimetric datasets provide meaningful classification of automobile paints based on their tone colour (L, a, b) and light intensity These approaches have the potential to ease the interpretation of complex spectral data involving a large number of comparisons. (author)

New approaches for investigating paintings by ion beam techniques

International Nuclear Information System (INIS)

Beck, L.; Viguerie, L. de; Walter, Ph.; Pichon, L.; Gutierrez, P.C.; Salomon, J.; Menu, M.; Sorieul, S.

2010-01-01

Up to now, among the IBA techniques, only PIXE has been used for analyzing paintings. However, quantitative PIXE analysis is sometimes difficult to interpret due to the layered structure, the presence of varnish and organic binder and, in some cases, discoloration of the pigments has been observed due to the interaction of the ion beam with the compounds. In order to improve the characterization of paintings, we propose some alternative experimental procedures. First of all, backscattering spectrometry (BS) and PIXE are simultaneously combined in order to collect complementary information such as layer thickness and organic compound quantification. The simultaneous PIXE and BS experiments also have the advantage of being able to analyze the same area in one experiment. This combination, implemented with an external beam, was directly applied on paintings and on painting cross-sections for the study of Italian Renaissance masterpieces. We have obtained valuable results not only on the pigment itself but also, for the first time, on the binder to pigment proportion which is not well documented in the ancient recipes. Moreover, in order to restrain beam damages due to the ion stopping power, we propose to analyze very thin painting cross-sections by a combination of PIXE-RBS and Scanning Transmission Ion Microscopy (STIM).

New approaches for investigating paintings by ion beam techniques

Science.gov (United States)

Beck, L.; de Viguerie, L.; Walter, Ph.; Pichon, L.; Gutiérrez, P. C.; Salomon, J.; Menu, M.; Sorieul, S.

2010-06-01

Up to now, among the IBA techniques, only PIXE has been used for analyzing paintings. However, quantitative PIXE analysis is sometimes difficult to interpret due to the layered structure, the presence of varnish and organic binder and, in some cases, discoloration of the pigments has been observed due to the interaction of the ion beam with the compounds. In order to improve the characterization of paintings, we propose some alternative experimental procedures. First of all, backscattering spectrometry (BS) and PIXE are simultaneously combined in order to collect complementary information such as layer thickness and organic compound quantification. The simultaneous PIXE and BS experiments also have the advantage of being able to analyze the same area in one experiment. This combination, implemented with an external beam, was directly applied on paintings and on painting cross-sections for the study of Italian Renaissance masterpieces. We have obtained valuable results not only on the pigment itself but also, for the first time, on the binder to pigment proportion which is not well documented in the ancient recipes. Moreover, in order to restrain beam damages due to the ion stopping power, we propose to analyze very thin painting cross-sections by a combination of PIXE-RBS and Scanning Transmission Ion Microscopy (STIM).

New approaches for investigating paintings by ion beam techniques

Energy Technology Data Exchange (ETDEWEB)

Beck, L., E-mail: Lucile.beck@cea.f [Centre de Recherche et de Restauration des Musees de France (C2RMF), CNRS-UMR 171, Palais du Louvre - Porte des Lions, 14 quai Francois Mitterrand, 75001 Paris (France); Viguerie, L. de; Walter, Ph.; Pichon, L. [Centre de Recherche et de Restauration des Musees de France (C2RMF), CNRS-UMR 171, Palais du Louvre - Porte des Lions, 14 quai Francois Mitterrand, 75001 Paris (France); Gutierrez, P.C. [Centro de Micro-Analisis de Materiales (CMAM), Universidad Autonoma de Madrid, Campus de Cantoblanco, E-28049 Madrid (Spain); Salomon, J.; Menu, M. [Centre de Recherche et de Restauration des Musees de France (C2RMF), CNRS-UMR 171, Palais du Louvre - Porte des Lions, 14 quai Francois Mitterrand, 75001 Paris (France); Sorieul, S. [Centre d' Etudes Nucleaires de Bordeaux-Gradignan, IN2P3, UMR 5797, Universite de Bordeaux 1, Chemin du Solarium BP120, 33175 Gradignan Cedex (France)

2010-06-15

Up to now, among the IBA techniques, only PIXE has been used for analyzing paintings. However, quantitative PIXE analysis is sometimes difficult to interpret due to the layered structure, the presence of varnish and organic binder and, in some cases, discoloration of the pigments has been observed due to the interaction of the ion beam with the compounds. In order to improve the characterization of paintings, we propose some alternative experimental procedures. First of all, backscattering spectrometry (BS) and PIXE are simultaneously combined in order to collect complementary information such as layer thickness and organic compound quantification. The simultaneous PIXE and BS experiments also have the advantage of being able to analyze the same area in one experiment. This combination, implemented with an external beam, was directly applied on paintings and on painting cross-sections for the study of Italian Renaissance masterpieces. We have obtained valuable results not only on the pigment itself but also, for the first time, on the binder to pigment proportion which is not well documented in the ancient recipes. Moreover, in order to restrain beam damages due to the ion stopping power, we propose to analyze very thin painting cross-sections by a combination of PIXE-RBS and Scanning Transmission Ion Microscopy (STIM).

PSP Program close out documentation

Energy Technology Data Exchange (ETDEWEB)

Andringa, K.; Hootman, H.E.; Ferrara, A.S.; Smith, P.K.; Congdon, J.W.; Randolph, H.W.; Young, R.H.; Driggers, F.E.; Topp, S.V.

1985-12-31

In December 1982 DOE-SR directed SRL to study the feasibility and impact of a program to lower the U-236 content of the Highly Enriched Uranium (HEU) stockpile used as fuel for the SRP reactors. In response to this request SRL assessed four technologies, Atomic Vapor Laser Isotope Separation (AVLIS), Molecular Laser Isotope Separation (MLIS), Gas Centrifuge, and the Plasma Separation Process (PSP) for this purpose with the assistance of the Engineering Department. In April 1983 cost/benefit analyses for these processes, high spot cost estimates for production facilities, and process uncertainties were submitted to DOE-SR with a recommendation to proceed with the conceptual design and supporting development programs for a facility based on the use of the PSP process. The current program status for the PSP development program at SRL and the design and documentation of a production facility at SRP, referred to as the Fuel Improvement Demonstration Facility (FIDF), is described in this report.

TA3 - Dosimetry and instrumentation supply of the M-Fish technique to the Fish-3 painting technique for analysing translocations: A radiotherapy-treated patient study

International Nuclear Information System (INIS)

Pouzoulet, F.; Roch-Lefevre, S.; Giraudet, A.L.; Vaurijoux, A.; Voisin, P.A.; Buard, V.; Delbos, M.; Voisin, Ph.; Roy, L.; Bourhis, J.

2006-01-01

Purpose: Currently, the chromosome translocation study is the best method to estimate the dose of an old radiation exposure. Fluorescent In Situ Hybridization (F.I.S.H.) technique allows an easy detection of this kind of aberrations. However, as only a few number of chromosomes is usually painted, some bias could skew the result. To evaluate the advantage of using full genome staining (M-F.I.S.H. technique) compared with three chromosomes labelling (F.I.S.H.-3 painting), we compared translocation yields in radiotherapy treated patients. Methods: Chromosome aberration analyses were performed on peripheral blood lymphocyte cultures of two patients treated for a throat cancer by radiotherapy. Blood samples were obtained, before, along the treatment and six or four months later. For each sample, a dicentrics analysis was performed together with translocation analysis either with F.I.S.H.-3 painting or M-F.I.S.H.. Results: By confronting results from the F.I.S.H.-3 painting technique and the M-F.I.S.H. technique, significant differences were revealed. The translocations yield seemed to be stable with the F.I.S.H.-3 painting technique whereas it is not the case with the M-F.I.S.H. technique. This difference in results was explained by the bias induced by F.I.S.H.-3 Painting technique in the visualisation of complex aberrations. Furthermore, we found the presence of a clone bearing a translocation involving a painted chromosome. Conclusions: According to the potential bias of F.I.S.H.-3 painting on translocations study, the M-F.I.S.H. technique should provide more precise and reproducible results. Because of its more difficult implement, it seems hardly applicable to retrospective dosimetry instead of F.I.S.H.-3 painting technique. (authors)

TA3 - Dosimetry and instrumentation supply of the M-Fish technique to the Fish-3 painting technique for analysing translocations: A radiotherapy-treated patient study

Energy Technology Data Exchange (ETDEWEB)

Pouzoulet, F.; Roch-Lefevre, S.; Giraudet, A.L.; Vaurijoux, A.; Voisin, P.A.; Buard, V.; Delbos, M.; Voisin, Ph.; Roy, L. [Institut de Radioprotection et de Surete Nucleaire, Lab. de Dosimetrie Biologique, 92 - Fontenay aux Roses (France); Bourhis, J. [Laboratoire UPRES EA 27-10, Radiosensibilite des Tumeurs et Tissus sains, PR1, 94 - Villejuif (France)

2006-07-01

Purpose: Currently, the chromosome translocation study is the best method to estimate the dose of an old radiation exposure. Fluorescent In Situ Hybridization (F.I.S.H.) technique allows an easy detection of this kind of aberrations. However, as only a few number of chromosomes is usually painted, some bias could skew the result. To evaluate the advantage of using full genome staining (M-F.I.S.H. technique) compared with three chromosomes labelling (F.I.S.H.-3 painting), we compared translocation yields in radiotherapy treated patients. Methods: Chromosome aberration analyses were performed on peripheral blood lymphocyte cultures of two patients treated for a throat cancer by radiotherapy. Blood samples were obtained, before, along the treatment and six or four months later. For each sample, a dicentrics analysis was performed together with translocation analysis either with F.I.S.H.-3 painting or M-F.I.S.H.. Results: By confronting results from the F.I.S.H.-3 painting technique and the M-F.I.S.H. technique, significant differences were revealed. The translocations yield seemed to be stable with the F.I.S.H.-3 painting technique whereas it is not the case with the M-F.I.S.H. technique. This difference in results was explained by the bias induced by F.I.S.H.-3 Painting technique in the visualisation of complex aberrations. Furthermore, we found the presence of a clone bearing a translocation involving a painted chromosome. Conclusions: According to the potential bias of F.I.S.H.-3 painting on translocations study, the M-F.I.S.H. technique should provide more precise and reproducible results. Because of its more difficult implement, it seems hardly applicable to retrospective dosimetry instead of F.I.S.H.-3 painting technique. (authors)

Enamel paint techniques in archaeology and their identification using XRF and micro-XRF

Science.gov (United States)

Hložek, M.; Trojek, T.; Komoróczy, B.; Prokeš, R.

2017-08-01

This investigation focuses in detail on the analysis of discoveries in South Moravia - important sites from the Roman period in Pasohlávky and Mušov. Using X-ray fluorescence analysis and micro-analysis we help identify the techniques of enamel paint and give a thorough chemical analysis in details which would not be possible to determine by means of macroscopic examination. We thus address the influence of elemental composition on the final colour of the enamel paint and describe the less known technique of combining enamel with millefiori. The material analyses of the metal artefacts decorated with enamel paint significantly contribute to our knowledge of the technology being used during the Roman period.

Conceptual design for PSP mounting bracket

Energy Technology Data Exchange (ETDEWEB)

Ransom, G.; Stein, R. [Martin Marietta Energy Systems, Inc., Piketon, OH (United States)

1991-12-31

Protective structural packages (PSP`s or overpacks) used to ship 2 1/2-ton UF{sub 6} product cylinders are bolted to truck trailers. All bolts penetrate two longitudinal rows of wooden planks. Removal and replacement is required at various intervals for maintenance and routine testing. A conceptual design is presented for mounting brackets which would securely attach PSP`s to trailer frames, reduce removal and replacement time, and minimize risk of personnel injury.

Study of Materials and Techniques for the Conservation of Two Miniature Paintings

Directory of Open Access Journals (Sweden)

Moustafa Attia Mohie

2018-03-01

Full Text Available This research includes a study on the conservation of two miniature paintings produced by unknown artists and probably dated to the second half of the 18th century. These paintings are registered at the Museum of Helwan University, Faculty of Applied Arts, Giza, Egypt, No. (A of 100/6.This research also includes a historical and artistic study of the paintings. To study the materials and techniques used in their execution, several methods were used. XRD, XRD-EDAX was used for the examination and analysis of inorganic materials; in the case of organic materials, FTIR, UV was used to identify the pigment materials, glue, varnish, isolation layer or condition of the paper support. The oil medium in the paint layer was identified by the GLC method. Cross sections of both paintings were examined to find out about the technical knowledge used in constructing the painting / pictorial layers.Finally, this research involves a study of how to separate two oil paintings executed on one paper support, and the most important procedures needed to carry out this step, as well as those necessary for reconstructing the painting layers. In addition, a new method is described to treat cracks.Another new method was used to protect the paper support of these paintings from high relative humidity. This research also proposes a new tear mending method for paper objects instead of the traditional methods used in international paper and manuscript conservation laboratories.

Defective plastic infection-control barriers and faulty technique may cause PSP plate contamination used in digital intraoral radiography.

Science.gov (United States)

Kuperstein, Arthur S

2012-09-01

Fifty-two disinfected photostimulable phosphor (PSP) plates in plastic barrier envelopes were evaluated for contamination following placement in 30 study participants. Forty-four plates were acceptable for use in the study. The risk factor was the abundant oropharyngeal microbial flora and its ability to breach infection-control barrier sheaths. The presence of bacterial colonies on an agar plate was used to determine bacterial contamination and the presence of any growth indicated failure of the barrier envelope. Before clinical placement of the plates, quality review of the PSP plates revealed defects in the integrity of 4 barrier envelopes most likely caused by forceps-related damage or failure to achieve a uniform seal during manufacturing. These defects allowed substantial contamination. Contamination also occurred as a result of failure to extract the PSP plate from the barrier envelope cleanly. Of the 44 barriers with no obvious signs of a defect, 3 produced bacterial growth following culture. The authors concluded that digital sensor sheathed in barrier envelopes remain a potential source of contamination. PSP plates must be disinfected between removal from a contaminated barrier envelope (used in a patient) and placement in a new barrier envelope. In addition, placement into the barrier envelope should ideally be carried out under aseptic conditions. Finally, the integrity of each sealed barrier envelope must be verified visually. Copyright © 2012. Published by Mosby, Inc. All rights reserved.

Study of Pictorial technique in a colonial wall painting from El Padre coffee plantation using XRF and complementary technique

International Nuclear Information System (INIS)

Rodriguez, G.; Mendoza, A.

2001-01-01

This investigation is based on the study of the pictorial technique employed in a wall painting from El Padre coffee plantation situation in Madruga, Havana, and built at beginning of XIX century. The knowledge about pictorical techniques that was used in a painting is a typical research in Archaeometry, because it is so important the art historical information as scientific results to conclude about the real materials and procedures that were used in the past by the artists . The prediction of a wall painting pictorical technique is carrying out trough the knowledge of pigments, mortars layers and binding substance composition. The non destructive inorganic microanalysis of mortars layers and pigments was determined by a portable XRF system, which is very useful because of the most of pigments are of inorganic nature. A pinpoint samples microanalysis of each color from the painting were done by complementary and traditional technique in stratigraphic studies such as: optical microscopy, micro- chemical drop test, Scanning Electron Microscopy with Energy Dispersive X-Ray attachment (SEM-EDX), gas chromatography and Fourier Transformed Infra Red Spectroscopy (FTIR). The overlapping of layers was obtained by optical microscopy, The mortars composition was investigated by micro-chemical drop test and SEM/EDX and further confirmed by FTIR. The presence of binding substances in colors layers was identified by specific staining test and Gas Chromatography

Investigation of leaching of an antifouling agent from marine paint formulations using radiotracer technique

International Nuclear Information System (INIS)

Pant, H.J.; Sharma, V.K.; Gursharan Singh; Kalgutkar, D.B.; Patil, S.P.; Jayachandran, N.; Unni, V.K.P.

2012-01-01

A radiotracer technique was used to investigate the leaching of an antifouling agent from different marine paint formulations with an objective to select the best paint formulation for bulk production. The antifouling agent (Diuron) itself was labeled with carbon-14 (half-life: 5,730 years, β-energy: 156 keV) and used as a radiotracer. The different paint formulations added with radiolabeled Diuron were applied onto suitably selected substrates and measured for initial intensity of β-radiation using a Geiger-Muller detector connected to a ratemeter. The painted substrates were subjected to shower tests for a pre-decided time and subsequently measured for β-radiations. The comparison of intensity of β-radiations in substrates prior and post shower tests provides information about leaching of antifouling agent Diuron from the paint formulation. The high leaching percentage of antifouling agent Diuron post shower tests indicates non-suitability of paint formulation for marine and civil structures. However, low leaching rate of Diuron will make a paint formulation more efficient and suitable. Based on the results of investigation, a paint formulation with minimum leaching rate was identified and selected for bulk production by a paint company. (author)

XRF analyses for the study of painting technique and degradation on frescoes by Beato Angelico: first results

International Nuclear Information System (INIS)

Mazzinghi, A.

2014-01-01

Beato Angelico is one of the most important Italian painters of the Renaissance period, in particular he was a master of the so-called 'Buon fresco' technique for mural paintings. A wide diagnostic campaign with X-Ray Fluorescence (XRF) analyses has been carried out on three masterworks painted by Beato Angelico in the San Marco monastery in Florence: the Crocifissione con Santi, the 'Annunciazione' and the 'Madonna delle Ombre'. The latter is painted by mixing fresco and secco techniques, which makes it of particular interest for the study of two different paintings techniques of the same artist. Then the aim of the study was focused on the characterization of the painting palette, and therefore the painting techniques, used by Beato Angelico. Moreover, the conservators were interested in the study of degradation processes and old restoration treatments. Our analyses have been carried out by means of the XRF spectrometer developed at LABEC laboratory at Istituto Nazionale di Fisica Nucleare in Florence (Italy). XRF is indeed especially suited for such a kind of study, allowing for multi-elemental, nondestructive, non-invasive analyses in a short time, with portable instruments. In this paper the first results concerning the XRF analysis are presented.

Check-All-That-Apply (CATA), Sorting, and Polarized Sensory Positioning (PSP) with Astringent Stimuli

Science.gov (United States)

Fleming, Erin E.; Ziegler, Gregory R.; Hayes, John E.

2015-01-01

Multiple rapid sensory profiling techniques have been developed as more efficient alternatives to traditional sensory descriptive analysis. Here, we compare the results of three rapid sensory profiling techniques – check-all-that-apply (CATA), sorting, and polarized sensory positioning (PSP) – using a diverse range of astringent stimuli. These rapid methods differ in their theoretical basis, implementation, and data analyses, and the relative advantages and limitations are largely unexplored. Additionally, we were interested in using these methods to compare varied astringent stimuli, as these compounds are difficult to characterize using traditional descriptive analysis due to high fatigue and potential carry-over. In the CATA experiment, subjects (n=41) were asked to rate the overall intensity of each stimulus as well as to endorse any relevant terms (from a list of 13) which characterized the sample. In the sorting experiment, subjects (n=30) assigned intensity-matched stimuli into groups 1-on-1 with the experimenter. In the PSP experiment, (n=41) subjects first sampled and took notes on three blind references (‘poles’) before rating each stimulus for its similarity to each of the 3 poles. Two-dimensional perceptual maps from correspondence analysis (CATA), multidimensional scaling (sorting), and multiple factor analysis (PSP) were remarkably similar, with normalized RV coefficients indicating significantly similar plots, regardless of method. Agglomerative hierarchical clustering of all data sets using Ward’s minimum variance as the linkage criteria showed the clusters of astringent stimuli were approximately based on the respective class of astringent agent. Based on the descriptive CATA data, it appears these differences may be due to the presence of side tastes such as bitterness and sourness, rather than astringent sub-qualities per se. Although all three methods are considered ‘rapid,’ our prior experience with sorting suggests it is best

Western European influences on Post-Byzantine panel painting technique through binding media identification

International Nuclear Information System (INIS)

Kouloumpi, E.; Lawson, G.; Pavlidis, B.

2006-01-01

Post-Byzantine is called the period after the invasion of the Ottomans in Constantinople, the capital of Byzantium in 1453, which lasted until the establishment of the first Greek State in 1836. The Post - Byzantine era is one of the most important artistic periods of the Neo-Hellenic Pictorial Art, since, through cultural exchanges with Western Europe, it sets the fundaments for oil painting. The thematology changes from religious to civil, the technique changes from egg yolk to egg-oil emulsion in order to end up to pure oil painting and finally, it opens 'the gates' for the modern artistic movements of the world. The current research is focused on the study of the effects of western influences on the technique and pictorial characteristics of the post-Byzantine icons by the study of any changes in the pigment's binding media through scientific analyses (SEM-EDX, micro-FTIR and GC), as well as of any changes in the painting style of the icons through comparison with both Byzantine and western painting standards. Research never ends and the results of this work give rise to further analysis, in order to throw some light to this transitional period of art. (Author)

Landscape Painting. Rewriting Painting in the Postmedium Condition

Directory of Open Access Journals (Sweden)

Gal, Nissim

2011-02-01

Full Text Available Is landscape painting still relevant today? To answer this question the article examines the work of the contemporary artist Yehudit Sasportas. Sasporas offers a unique kind of written-drawn landscape painting that moves between the manual and the mechanical. The theoretical perspectives from which it is approached are taken, among others, from Plato, Heidegger and Derrida on the issue of writing. Sasportas painting, which may be characterized as "painting under erasure" or "Landscape Painting", serves as a key to understanding the status of painting as a relevant medium, not because it defines medium according to the modernist Greenbergian formula, but because it enables an understanding of painting as a field that exists in a variety of media. Painting as a field, in Sasportas's art, works and lives within various techniques and materials, even when it includes within itself a melancholic mark indicating doubt about its own relevance.

Composition and stratigraphy of the paint layers: investigation on the Madonna dei Fusi by ion beam analysis techniques

Science.gov (United States)

Grassi, N.

2005-06-01

In the framework of the extensive study on the wood painting "Madonna dei fusi" attributed to Leonardo da Vinci, Ion Beam Analysis (IBA) techniques were used at the Florence accelerator laboratory to get information about the elemental composition of the paint layers. After a brief description of the basic principle and the general features of IBA techniques, we will illustrate in detail how the analysis allowed us to characterise the pigments of original and restored areas and the substrate composition, and to obtain information about the stratigraphy of the painting, also providing an estimate of the paint layer thickness.

Radiation resistance of paralytic shellfish poison (PSP) toxins

Energy Technology Data Exchange (ETDEWEB)

San Juan, Edith M

2000-04-01

Radiation resistance of paralytic shellfish poison (PSP) toxins, obtained from Pyrodinium bahamense var. compressum in shellstocks of green mussels, was determined by subjecting the semi-purified toxin extract as well as the shellstocks of green mussels to high doses of ionizing radiation of 5, 10, 15 and 20 kGy. The concentration of the PSP toxins was determined by the Standard Mouse Bioassay (SMB) method. The radiation assistance of the toxins was determined by plotting the PSP toxin concentration versus applied dose in a semilog paper. The D{sub 10} value or decimal reduction dose was obtained from the straight line which is the dose required to reduce the toxicity level by 90%. The effects of irradiation on the quality of green mussels in terms of its physico-chemical, microbiological and sensory attributes were also conducted. The effect of irradiation on the fatty acid components of green mussels was determined by gas chromatography. Radiation resistance of the PSP toxins was determined to be lower in samples with initially high toxicity level as compared with samples with initially low toxicity level. The D{sub 10} values of samples with initially high PSP level were 28.5 kGy in shellstocks of green musssels and 17.5 kGy in the semi-purified toxin extract. When the PSP level was low initially, the D{sub 10} values were as high as 57.5 and 43.5 kGy in shellstocks of green mussels for the two trials, and 43.0 kGy in semi-purified toxin extract. The microbial load of the irradiated mussels was remarkably reduced. No differnce in color and odor characteristics were observed in the mussel samples subjected to varying doses of ionizing radiation. There was darkening in the color of mussel meat and its juice. The concentration of the fatty acid components in the fresh green mussels were considerably higher as compared with those present in the irradiated mussels, though some volatile fatty acids were detected as a result of irradiation. (Author)

Radiation resistance of paralytic shellfish poison (PSP) toxins

International Nuclear Information System (INIS)

San Juan, Edith M.

2000-04-01

Radiation resistance of paralytic shellfish poison (PSP) toxins, obtained from Pyrodinium bahamense var. compressum in shellstocks of green mussels, was determined by subjecting the semi-purified toxin extract as well as the shellstocks of green mussels to high doses of ionizing radiation of 5, 10, 15 and 20 kGy. The concentration of the PSP toxins was determined by the Standard Mouse Bioassay (SMB) method. The radiation assistance of the toxins was determined by plotting the PSP toxin concentration versus applied dose in a semilog paper. The D 10 value or decimal reduction dose was obtained from the straight line which is the dose required to reduce the toxicity level by 90%. The effects of irradiation on the quality of green mussels in terms of its physico-chemical, microbiological and sensory attributes were also conducted. The effect of irradiation on the fatty acid components of green mussels was determined by gas chromatography. Radiation resistance of the PSP toxins was determined to be lower in samples with initially high toxicity level as compared with samples with initially low toxicity level. The D 10 values of samples with initially high PSP level were 28.5 kGy in shellstocks of green musssels and 17.5 kGy in the semi-purified toxin extract. When the PSP level was low initially, the D 10 values were as high as 57.5 and 43.5 kGy in shellstocks of green mussels for the two trials, and 43.0 kGy in semi-purified toxin extract. The microbial load of the irradiated mussels was remarkably reduced. No differnce in color and odor characteristics were observed in the mussel samples subjected to varying doses of ionizing radiation. There was darkening in the color of mussel meat and its juice. The concentration of the fatty acid components in the fresh green mussels were considerably higher as compared with those present in the irradiated mussels, though some volatile fatty acids were detected as a result of irradiation. (Author)

Paralytic Shellfish Poisoning (PSP in Margarita Island, Venezuela

Directory of Open Access Journals (Sweden)

Amelia La Barbera-Sánchez

2004-09-01

Full Text Available A severe outbreak of Paralytic Shellfish Poisoning (PSP occurred in Manzanillo and Guayacán, northwestern coast of Margarita Island, Venezuela, between August and October 1991. A bloom of dinoflagellates including Prorocentrum gracile, Gymnodinium catenatum and Alexandrium tamarense seemed to be responsible for this outbreak. Levels of PSP toxins in mussels (Perna perna exceeded the international safety limit of saxitoxin, 80 µg STX/100 g meat. PSP toxin values varied between 2 548 and 115 µg STX/100 g meat in Manzanillo, and between 1 422 and 86 µg STX/100 g meat in Guayacán. At both locations, the highest levels were detected in August, when 24 patients exhibited typical symptoms of PSP toxicity after consuming cooked mussels (16 required hospitalization. A high pressure liquid chromatographic (HPLC procedure was recently used on the 1991 samples. The major toxin detected in samples of both locations was decarbamoyl saxitoxin (dcSTX, but low concentrations of saxitoxin were also found in Manzanillo samples. Gonyautoxins GTX1, GTX2 and GTX3 were detected only at Guayacán, while in both locations, decarbamoylgonyatouxin (dcGTX2,3 toxins were detected. These findings represent the first time that causative toxins of PSP in Venezuela have been chemically identified, and confirm the presence of dcSTX and dcGTX in mussels from the Caribbean Sea. The presence of dcSTX and dcGTX in shellfish is indicative that Gymnodinium catenatum was a causative organism for outbreak of PSPUn severo brote de intoxicación paralizante por moluscos (PSP en inglés ocurrió en Manzanillo y Guayacán en la costa noroeste de la Isla de Margarita, Venezuela entre agosto y octubre de 1991. Una proliferación de Prorocentrum gracile, Gymnodinium catenatum y Alexandrium tamarense causó el brote. Los niveles de PSP en mejillón (Perna perna superaron los niveles máximos permisibles de saxitoxina, 80 µg STX/100g carne. Los niveles de toxinas variaron entre 2 548 y 115

A multi-technique approach for the characterization of Roman mural paintings

Energy Technology Data Exchange (ETDEWEB)

Toschi, Francesco [CNR-IMIP (Istituto di Metodologie Inorganiche e dei Plasmi), Area della Ricerca Roma 1, Via Salaria Km. 29,300, 00016 Monterotondo, Roma, (Italy); Paladini, Alessandra, E-mail: alessandra.paladini@cnr.it [CNR-IMIP (Istituto di Metodologie Inorganiche e dei Plasmi), Area della Ricerca Roma 1, Via Salaria Km. 29,300, 00016 Monterotondo, Roma, (Italy); Colosi, Francesca [CNR-ITABC (Istituto per le Tecnologie Applicate ai Beni Culturali), Area della Ricerca Roma 1, Via Salaria Km. 29,300, 00016 Monterotondo, Roma (Italy); Cafarelli, Patrizia; Valentini, Veronica [CNR-IMIP (Istituto di Metodologie Inorganiche e dei Plasmi), Area della Ricerca Roma 1, Via Salaria Km. 29,300, 00016 Monterotondo, Roma, (Italy); Falconieri, Mauro; Gagliardi, Serena [ENEA, C.R. Casaccia, via Anguillarese 301, 00060 Roma (Italy); Santoro, Paola [CNR-ISMA (Istituto di Studi sul Mediterraneo Antico), Area della Ricerca Roma 1, Via Salaria Km. 29,300, 00016 Monterotondo, Roma (Italy)

2013-11-01

In the frame of an ongoing archeological study on the Sabina area, a countryside close to Rome, white and red samples of roman wall paintings have been investigated by combining X-ray diffraction and different spectroscopic methodologies, namely laser induced breakdown spectroscopy, μ-Raman and Fourier transform infrared attenuated total reflectance spectroscopy. The used multi-technique approach has allowed the unambiguous identification of the red pigment as red ochre and has provided insight on the provenance of both the pigment and the material used for the realization of the wall paintings. The experimental results have confirmed some assumptions on the use of local materials in roman rural architecture.

Non-invasive Florentine Renaissance Panel Painting Replica Structures Investigation by Using Terahertz Time-Domain Imaging (THz-TDI) Technique

DEFF Research Database (Denmark)

Dandolo, Corinna Ludovica Koch; Picollo, Marcello; Cucci, Costanza

2016-01-01

The potentials of the Terahertz Time-Domain Imaging (THz-TDI) technique for a non-invasive inspection of panel paintings have been considered in detail. The THz-TD data acquired on a replica of a panel painting made in imitation of Italian Renaissance panel paintings were processed in order to pr...

Wavenumber-frequency Spectra of Pressure Fluctuations Measured via Fast Response Pressure Sensitive Paint

Science.gov (United States)

Panda, J.; Roozeboom, N. H.; Ross, J. C.

2016-01-01

The recent advancement in fast-response Pressure-Sensitive Paint (PSP) allows time-resolved measurements of unsteady pressure fluctuations from a dense grid of spatial points on a wind tunnel model. This capability allows for direct calculations of the wavenumber-frequency (k-?) spectrum of pressure fluctuations. Such data, useful for the vibro-acoustics analysis of aerospace vehicles, are difficult to obtain otherwise. For the present work, time histories of pressure fluctuations on a flat plate subjected to vortex shedding from a rectangular bluff-body were measured using PSP. The light intensity levels in the photographic images were then converted to instantaneous pressure histories by applying calibration constants, which were calculated from a few dynamic pressure sensors placed at selective points on the plate. Fourier transform of the time-histories from a large number of spatial points provided k-? spectra for pressure fluctuations. The data provides first glimpse into the possibility of creating detailed forcing functions for vibro-acoustics analysis of aerospace vehicles, albeit for a limited frequency range.

Paintings - high-energy protons detect pigments and paint-layers

International Nuclear Information System (INIS)

Denker, A.; Opitz-Coutureau, J.

2004-01-01

High-energy PIXE was used to identify pigment composition, sequencing and the thickness of paint-layers. Before applying the technique to valuable masterpieces, mock-ups were examined in a collaboration with the Kunsthistorisches Museum, Vienna. The results of high-energy PIXE were compared to conventional cross-section analysis. In addition, the non-destructiveness of the technique was investigated thoroughly. After this preparative work, two ancient paintings have been examined and the results are presented in this paper

Analysis of painted arts by energy sensitive radiographic techniques with the Pixel Detector Timepix

International Nuclear Information System (INIS)

Zemlicka, J; Jakubek, J; Kroupa, M; Hradil, D; Hradilova, J; Mislerova, H

2011-01-01

Non-invasive techniques utilizing X-ray radiation offer a significant advantage in scientific investigations of painted arts and other cultural artefacts such as painted artworks or statues. In addition, there is also great demand for a mobile analytical and real-time imaging device given the fact that many fine arts cannot be transported. The highly sensitive hybrid semiconductor pixel detector, Timepix, is capable of detecting and resolving subtle and low-contrast differences in the inner composition of a wide variety of objects. Moreover, it is able to map the surface distribution of the contained elements. Several transmission and emission techniques are presented which have been proposed and tested for the analysis of painted artworks. This study focuses on the novel techniques of X-ray transmission radiography (conventional and energy sensitive) and X-ray induced fluorescence imaging (XRF) which can be realised at the table-top scale with the state-of-the-art pixel detector Timepix. Transmission radiography analyses the changes in the X-ray beam intensity caused by specific attenuation of different components in the sample. The conventional approach uses all energies from the source spectrum for the creation of the image while the energy sensitive alternative creates images in given energy intervals which enable identification and separation of materials. The XRF setup is based on the detection of characteristic radiation induced by X-ray photons through a pinhole geometry collimator. The XRF method is extremely sensitive to the material composition but it creates only surface maps of the elemental distribution. For the purpose of the analysis several sets of painted layers have been prepared in a restoration laboratory. The composition of these layers corresponds to those of real historical paintings from the 19 th century. An overview of the current status of our methods will be given with respect to the instrumentation and the application in the field of

Analysis of painted arts by energy sensitive radiographic techniques with the Pixel Detector Timepix

Energy Technology Data Exchange (ETDEWEB)

Zemlicka, J; Jakubek, J; Kroupa, M [Institute of Experimental and Applied Physics, Czech Technical University Prague, Horska 3a/22, 128 00 Prague 2 (Czech Republic); Hradil, D [Institute of Inorganic Chemistry, AS CR, v.v.i., ALMA, 50 68 Husinec-Oeez (Czech Republic); Hradilova, J; Mislerova, H, E-mail: jan.zemlicka@utef.cvut.cz [Academy of Fine Arts in Prague, ALMA, U Akademie 4, 170 2, Prague 7 (Czech Republic)

2011-01-15

Non-invasive techniques utilizing X-ray radiation offer a significant advantage in scientific investigations of painted arts and other cultural artefacts such as painted artworks or statues. In addition, there is also great demand for a mobile analytical and real-time imaging device given the fact that many fine arts cannot be transported. The highly sensitive hybrid semiconductor pixel detector, Timepix, is capable of detecting and resolving subtle and low-contrast differences in the inner composition of a wide variety of objects. Moreover, it is able to map the surface distribution of the contained elements. Several transmission and emission techniques are presented which have been proposed and tested for the analysis of painted artworks. This study focuses on the novel techniques of X-ray transmission radiography (conventional and energy sensitive) and X-ray induced fluorescence imaging (XRF) which can be realised at the table-top scale with the state-of-the-art pixel detector Timepix. Transmission radiography analyses the changes in the X-ray beam intensity caused by specific attenuation of different components in the sample. The conventional approach uses all energies from the source spectrum for the creation of the image while the energy sensitive alternative creates images in given energy intervals which enable identification and separation of materials. The XRF setup is based on the detection of characteristic radiation induced by X-ray photons through a pinhole geometry collimator. The XRF method is extremely sensitive to the material composition but it creates only surface maps of the elemental distribution. For the purpose of the analysis several sets of painted layers have been prepared in a restoration laboratory. The composition of these layers corresponds to those of real historical paintings from the 19{sup th} century. An overview of the current status of our methods will be given with respect to the instrumentation and the application in the field

The Disturbance of Gaze in Progressive Supranuclear Palsy (PSP: Implications for Pathogenesis

Directory of Open Access Journals (Sweden)

Athena L Chen

2010-12-01

Full Text Available Progressive supranuclear palsy (PSP is a disease of later life that is currently regarded as a form of neurodegenerative tauopathy. Disturbance of gaze is a cardinal clinical feature of PSP that often helps clinicians to establish the diagnosis. Since the neurobiology of gaze control is now well understood, it is possible to use eye movements as investigational tools to understand aspects of the pathogenesis of PSP. In this review, we summarize each disorder of gaze control that occurs in PSP, drawing on our studies of fifty patients, and on reports from other laboratories that have measured the disturbances of eye movements. When these gaze disorders are approached by considering each functional class of eye movements and its neurobiological basis, a distinct pattern of eye movement deficits emerges that provides insight into the pathogenesis of PSP. Although some aspects of all forms of eye movements are affected in PSP, the predominant defects concern vertical saccades (slow and hypometric, both up and down, impaired vergence, and inability to modulate the linear vestibulo-ocular reflex appropriately for viewing distance. These vertical and vergence eye movements habitually work in concert to enable visuomotor skills that are important during locomotion with the hands free. Taken with the prominent early feature of falls, these findings suggest that PSP tauopathy impairs a recently-evolved neural system concerned with bipedal locomotion in an erect posture and frequent gaze shifts between the distant environment and proximate hands. This approach provides a conceptual framework that can be used to address the nosological challenge posed by overlapping clinical and neuropathological features of neurodegenerative tauopathies.

Streptococcus pneumoniae PspC Subgroup Prevalence in Invasive Disease and Differences in Contribution to Complement Evasion.

Science.gov (United States)

van der Maten, Erika; van den Broek, Bryan; de Jonge, Marien I; Rensen, Kim J W; Eleveld, Marc J; Zomer, Aldert L; Cremers, Amelieke J H; Ferwerda, Gerben; de Groot, Ronald; Langereis, Jeroen D; van der Flier, Michiel

2018-04-01

The pneumococcal capsular serotype is an important determinant of complement resistance and invasive disease potential, but other virulence factors have also been found to contribute. Pneumococcal surface protein C (PspC), a highly variable virulence protein that binds complement factor H to evade C3 opsonization, is divided into two subgroups: choline-bound subgroup I and LPxTG-anchored subgroup II. The prevalence of different PspC subgroups in invasive pneumococcal disease (IPD) and functional differences in complement evasion are unknown. The prevalence of PspC subgroups in IPD isolates was determined in a collection of 349 sequenced strains of Streptococcus pneumoniae isolated from adult patients. pspC deletion mutants and isogenic pspC switch mutants were constructed to study differences in factor H binding and complement evasion in relation to capsule thickness. Subgroup I pspC was far more prevalent in IPD isolates than subgroup II pspC The presence of capsule was associated with a greater ability of bound factor H to reduce complement opsonization. Pneumococcal subgroup I PspC bound significantly more factor H and showed more effective complement evasion than subgroup II PspC in isogenic encapsulated pneumococci. We conclude that variation in the PspC subgroups, independent of capsule serotypes, affects pneumococcal factor H binding and its ability to evade complement deposition. Copyright © 2018 American Society for Microbiology.

Characterization of the Teotihuacan mural painting: application of the external particle beam as non destructive technique

International Nuclear Information System (INIS)

Martinez, C.; Manzanilla, L.; Ruvalcaba, J.L.; Ontalba, M.A.

2005-01-01

The characterization of technical indicators contained in the painting mural should follow a minim methodology from their discovery in the archaeological excavations until their analysis in the laboratory, with the purpose of rescuing diagnostic elements that mark the stages of socio cultural development in the towns. With this spirit it was carried out the present study analyzing some fragments of the Teotihuacan mural painting. The analysis consisted on applying some of the analytical techniques with particle beams used for archaeometry like the Proton induced X-ray emission (PIXE) and the particle elastic backscattering (RBS), due to it is treated of complementary techniques, very sensitive, of multielemental character, but mainly because its are non destructive analytical techniques. (Author)

Familias de la proteína de superficie PspA de Streptococcus pneumoniae: Relación con serotipos y localización Pneumococcal surface protein A (PspA families: Relation with serotypes and clinical site of infection

Directory of Open Access Journals (Sweden)

Clara Mayoral

2010-10-01

Full Text Available PspA, proteína de superficie de Streptococcus pneumoniae es un factor de virulencia, fuertemente inmunogénica y común a todos los serotipos. Aunque el gen que codifica para esta proteína presenta una marcada heterogeneidad en la región correspondiente al N-terminal, la PspA contiene epitopes conservados de manera tal que la inmunización genera protección contra neumococos pertenecientes a diversos tipos capsulares y con distintas PspA. A pesar del marcado polimorfismo del gen pspA es posible agrupar las distintas variantes en 3 familias mayoritarias. Estas propiedades las convierten en candidatas ideales para elaborar vacunas. Debido a que la mayoría de los trabajos sobre identificación de familias fueron realizados sobre serotipos frecuentes en otros países, el objetivo fue identificar las familias de PspA de aislamientos de pacientes de nuestra región y relacionarlas con los serotipos prevalentes y patologías. Se estudiaron 70 aislamientos, provenientes de niños con infecciones invasoras. Se aplicó una PCR utilizando cebadores específicos de cada familia. El 60% fueron familia 1 y 34% familia 2. En un 6% no se identificó ninguna de las familias de PspA. Los serotipos 1 y 5 presentaron familia 1 únicamente; los serotipos 14, 6B, 19F y 18C mostraron genes de ambas familias. La familia 1 se observó en 60% de las neumonías y 50% de las meningitis. La familia 2 en 33% de neumonías y 50% de meningitis. Esta información podría ser un valioso aporte para la formulación de una vacuna regional efectiva utilizando PspA recombinante como inmunógeno.PspA, a pneumococcal surface protein, is highly immunogenic and common to all serotypes. Although pspA gene shows a great heterogeneity at the N-terminal region, PspA protein has conserved epytopes which are able to elicit protective cross-reaction against various serotypes presenting different PspA. In spite of the high polimorfism of the PspA, three majority families can be identified

The organic materials in the Five Northern Provinces' Assembly Hall: disclosing the painting technique of the Qing dynasty painters in civil buildings

Science.gov (United States)

Lluveras-Tenorio, A.; Bonaduce, I.; Sabatini, F.; Degano, I.; Blaensdorf, C.; Pouyet, E.; Cotte, M.; Ma, L.; Colombini, M. P.

2015-11-01

The beiwusheng huiguan (`Meeting hall of the Five Northern Dynasties') is a building complex from the Qing dynasty (1636-1912 ad) located in Wafangdian, near Ziyang, in the south of the Chinese Province of Shaanxi. Two of the preserved halls are richly decorated with wall paintings dated probably in 1848 ad and representing scenes of the `Romance of the Three Kingdoms' and Confucian moral tales. They are a rare example of well-preserved mural paintings of high artistic value inside civil buildings. The aims of this paper are the chemical characterization and localization of organic materials used as binders and colorants in the wall paintings. A multi-analytical approach, consisting in the combined use of gas chromatographic-mass spectrometric techniques (GC/MS and Py-GC/MS) and high-pressure liquid chromatography with diode array detector (HPLC-DAD), was chosen for these purposes. Proteinaceous materials (animal glue and egg), saccharide material (fruit tree gum) and a siccative oil were identified in different paint layers supplying invaluable information about the painting technique used. Moreover, the analyses of organic dyes allowed identifying indigo and gallic acid in more than one sample adding fundamental information about Chinese artists' techniques in mural paintings, missing from the previous studies. To shed light on the gilding technique, the distribution of the painting materials was achieved by means of synchrotron radiation Fourier transform infrared spectroscopy (SR micro-FTIR) and X-ray fluorescence (SR micro-XRF). The results obtained from the multi-analytical approach enabled us to determine the organic materials both binders and organic colorants used by Chinese artisans, highlighting the high technical level achieved in nineteenth century. The binding media and the organic colorants identified, as well as their distribution, allowed the discussion on the painting technique used by the artists of the Qing dynasty giving information for the

Murillo's paintings revealed by spectroscopic techniques and dedicated laboratory-made micro X-ray diffraction

Energy Technology Data Exchange (ETDEWEB)

Duran, A., E-mail: adrian@icmse.csic.es [Materials Science Institute of Seville, Avda Americo Vespucio 49, 41092 Seville (Spain); Centre de Recherche et de Restauration des Musees de France (C2RMF-CNRS), Palais du Louvre, 14 quai Francois Mitterrand, 75001 Paris (France); Siguenza, M.B.; Franquelo, M.L.; Haro, M.C. Jimenez de; Justo, A.; Perez-Rodriguez, J.L. [Materials Science Institute of Seville, Avda Americo Vespucio 49, 41092 Seville (Spain)

2010-06-25

This paper describes one of the first case studies using micro-diffraction laboratory-made systems to analyse painting cross-sections. Pigments, such as lead white, vermilion, red ochre, red lac, lapis lazuli, smalt, lead tin yellow type I, massicot, ivory black, lamp black and malachite, were detected in cross-sections prepared from six Bartolome Esteban Murillo paintings by micro-Raman and micro-XRD combined with complementary techniques (optical microscopy, SEM-EDS, and FT-IR). The use of micro-XRD was necessary due to the poor results obtained with conventional XRD. In some cases, pigment identification was only possible by combining results from the different analytical techniques utilised in this study.

Room Temperature Stable PspA-Based Nanovaccine Induces Protective Immunity

Directory of Open Access Journals (Sweden)

Danielle A. Wagner-Muñiz

2018-03-01

Full Text Available Streptococcus pneumoniae is a major causative agent of pneumonia, a debilitating disease particularly in young and elderly populations, and is the leading worldwide cause of death in children under the age of five. While there are existing vaccines against S. pneumoniae, none are protective across all serotypes. Pneumococcal surface protein A (PspA, a key virulence factor of S. pneumoniae, is an antigen that may be incorporated into future vaccines to address the immunological challenges presented by the diversity of capsular antigens. PspA has been shown to be immunogenic and capable of initiating a humoral immune response that is reactive across approximately 94% of pneumococcal strains. Biodegradable polyanhydrides have been studied as a nanoparticle-based vaccine (i.e., nanovaccine platform to stabilize labile proteins, to provide adjuvanticity, and enhance patient compliance by providing protective immunity in a single dose. In this study, we designed a room temperature stable PspA-based polyanhydride nanovaccine that eliminated the need for a free protein component (i.e., 100% encapsulated within the nanoparticles. Mice were immunized once with the lead nanovaccine and upon challenge, presented significantly higher survival rates than animals immunized with soluble protein alone, even with a 25-fold reduction in protein dose. This lead nanovaccine formulation performed similarly to protein adjuvanted with Alum, however, with much less tissue reactogenicity at the site of immunization. By eliminating the free PspA from the nanovaccine formulation, the lead nanovaccine was efficacious after being stored dry for 60 days at room temperature, breaking the need for maintaining the cold chain. Altogether, this study demonstrated that a single dose PspA-based nanovaccine against S. pneumoniae induced protective immunity and provided thermal stability when stored at room temperature for at least 60 days.

Removal of the phage-shock protein PspB causes reduction of virulence in Salmonella enterica serovar Typhimurium independently of NRAMP1.

Science.gov (United States)

Wallrodt, Inke; Jelsbak, Lotte; Thomsen, Line E; Brix, Lena; Lemire, Sébastien; Gautier, Laurent; Nielsen, Dennis S; Jovanovic, Goran; Buck, Martin; Olsen, John E

2014-06-01

The phage-shock protein (Psp) system is believed to manage membrane stress in all Enterobacteriaceae and has recently emerged as being important for virulence in several pathogenic species of this phylum. The core of the Psp system consists of the pspA-D operon and the distantly located pspG gene. In Salmonella enterica serovar Typhimurium (S. Typhimurium), it has recently been reported that PspA is essential for systemic infection of mice, but only in NRAMP1(+) mice, signifying that attenuation is related to coping with divalent cation starvation in the intracellular environment. In the present study, we investigated the contribution of individual psp genes to virulence of S. Typhimurium. Interestingly, deletion of the whole pspA-D set of genes caused attenuation in both NRAMP1(+) and NRAMP1(-) mice, indicating that one or more of the psp genes contribute to virulence independently of NRAMP1 expression in the host. Investigations of single gene mutants showed that knock out of pspB reduced virulence in both types of mice, while deletion of pspA only caused attenuation in NRAMP1(+) mice, and deletion of pspD had a minor effect in NRAMP1(-) mice, while deletions of either pspC or pspG did not affect virulence. Experiments addressed at elucidating the role of PspB in virulence revealed that PspB is dispensable for uptake to and intracellular replication in cultured macrophages and resistance to complement-induced killing. Furthermore, the Psp system of S. Typhimurium was dispensable during pIV-induced secretin stress. In conclusion, our results demonstrate that removal of PspB reduces virulence in S. Typhimurium independently of host NRAMP1 expression, demonstrating that PspB has roles in intra-host survival distinct from the reported contributions of PspA. © 2014 The Authors.

Non-destructive and micro-invasive testing techniques for characterizing materials, structures and restoration problems in mural paintings

Energy Technology Data Exchange (ETDEWEB)

Tortora, Mariagrazia, E-mail: Mariagrazia.Tortora@univaq.it [University of L’Aquila, Department of Physical and Chemical Sciences, Via Vetoio (Coppito 1), I-67100, Loc. Coppito, L’Aquila, AQ (Italy); Sfarra, Stefano, E-mail: Stefano.Sfarra@univaq.it [Las.E.R. Laboratory, University of L’Aquila, Department of Industrial and Information Engineering and Economics, Piazzale E. Pontieri 1, I-67100, Loc. Monteluco di Roio, Roio Poggio, L’Aquila, AQ, Italy, (Italy); Chiarini, Marco, E-mail: mchiarini@unite.it [University of Teramo, Department of Bioscience and Technology for Food Agriculture and Environment, Via Carlo Lerici 1, I-64023, Mosciano Sant’Angelo, Teramo, TE, Italy, (Italy); Daniele, Valeria, E-mail: Valeria.Daniele@univaq.it [University of L’Aquila, Department of Industrial and Information Engineering and Economics, Piazzale E. Pontieri 1, I-67100, Loc. Monteluco di Roio, Roio Poggio, L’Aquila, AQ (Italy); Taglieri, Giuliana, E-mail: Giuliana.Taglieri@univaq.it [University of L’Aquila, Department of Industrial and Information Engineering and Economics, Piazzale E. Pontieri 1, I-67100, Loc. Monteluco di Roio, Roio Poggio, L’Aquila, AQ (Italy); Cerichelli, Giorgio, E-mail: Giorgio.Cerichelli@univaq.it [University of L’Aquila, Department of Physical and Chemical Sciences, Via Vetoio (Coppito 1), I-67100, Loc. Coppito, L’Aquila, AQ (Italy)

2016-11-30

Highlights: • Infrared thermography allowed to identify structural damage and rising damp effect. • The present approach provided insights on the used pigments and painting techniques. • FT-IR, XRF and XRD analyses of the mortar sample showed the peculiar composition. • 1D, 2D NMR analyses were useful for the identification of the restoration polymer. • NMR technique also allowed to characterize the plasticizing agents. - Abstract: In this paper, chemical and structural studies of medieval wall paintings in Ocre (L’Aquila, Italy) are presented. During the latest restoration campaign, non-destructive (Near-Infrared Reflectography and Infrared Thermography) and micro-invasive (Nuclear Magnetic Resonance, Fourier Transform Infrared Spectroscopy, μ-Raman, Scanning Electron Microscopy with X-ray Microanalysis, X-Ray Diffraction, X-Ray Fluorescence, Optical Microscopy, Mass Spectrometry, Thermogravimetry) analyses were performed in order to determine the detachments of wall surfaces and the characterization of original and restoration materials. Data integration allowed to reconstruct the conservative history, the execution techniques and the conservation problems of the artefact, as well as to assess the effectiveness of restoration activities adopted. The combined use of physical and micro-chemical techniques proved to be effective for an in-depth study of materials stratification of paintings.

Non-destructive and micro-invasive testing techniques for characterizing materials, structures and restoration problems in mural paintings

International Nuclear Information System (INIS)

Tortora, Mariagrazia; Sfarra, Stefano; Chiarini, Marco; Daniele, Valeria; Taglieri, Giuliana; Cerichelli, Giorgio

2016-01-01

Highlights: • Infrared thermography allowed to identify structural damage and rising damp effect. • The present approach provided insights on the used pigments and painting techniques. • FT-IR, XRF and XRD analyses of the mortar sample showed the peculiar composition. • 1D, 2D NMR analyses were useful for the identification of the restoration polymer. • NMR technique also allowed to characterize the plasticizing agents. - Abstract: In this paper, chemical and structural studies of medieval wall paintings in Ocre (L’Aquila, Italy) are presented. During the latest restoration campaign, non-destructive (Near-Infrared Reflectography and Infrared Thermography) and micro-invasive (Nuclear Magnetic Resonance, Fourier Transform Infrared Spectroscopy, μ-Raman, Scanning Electron Microscopy with X-ray Microanalysis, X-Ray Diffraction, X-Ray Fluorescence, Optical Microscopy, Mass Spectrometry, Thermogravimetry) analyses were performed in order to determine the detachments of wall surfaces and the characterization of original and restoration materials. Data integration allowed to reconstruct the conservative history, the execution techniques and the conservation problems of the artefact, as well as to assess the effectiveness of restoration activities adopted. The combined use of physical and micro-chemical techniques proved to be effective for an in-depth study of materials stratification of paintings.

Sustaining private sector participation (PSP) in solid waste management in Lagos, Nigeria, a developing country

Energy Technology Data Exchange (ETDEWEB)

Adebola, G. [Richbol Environmental Services Ltd., Lagos (Nigeria)

2000-07-01

Solid waste management in Lagos, Nigeria includes refuse collection and transportation to a landfill site. Disposal of the refuse and maintenance of the landfill site is also included in this task which, in the past was always a responsibility of the Government Agencies at the local level as a social service. This service has recently been privatised in the name of Private Sector Participation (PSP) in domestic refuse collection and disposal. As a new operator in about 23 wards in the ongoing PSP of domestic refuse, Richbol Environmental Ltd., recognized the enormous effort that government will have to make to sustain PSP in solid waste management. Governments can maintain control through re-orientation, legislation, enforcement, strengthening the PSP operators, integrating existing operators, and monitoring the activities of PSP operators. This paper presented a brief overview of the institutional changes that solid waste management has undergone in Lagos since 1977. It was emphasized that integrated waste management is extremely capital intensive. An integrated PSP can be a long term solution to waste management in developing, cash poor countries. The economic importance of PSP lies in the fact that it will reduce government expenditure and will also create a healthier environment and provide employment opportunities for thousands of employees and contribute to the gross domestic product of the country. 5 refs., 3 tabs., 1 fig.

75 FR 29324 - Preferred Supplier Program (PSP)

Science.gov (United States)

2010-05-25

..., DON will use a 5-star system based upon the 5-color ratings used in CPARS, as follows: CPARS PSP Red 0... contractors with the greatest motivation to achieve PSS? 3. Energy Efficiency is a critical DON requirement...

Membrane Stored Curvature Elastic Stress Modulates Recruitment of Maintenance Proteins PspA and Vipp1.

Science.gov (United States)

McDonald, Christopher; Jovanovic, Goran; Ces, Oscar; Buck, Martin

2015-09-01

Phage shock protein A (PspA), which is responsible for maintaining inner membrane integrity under stress in enterobacteria, and vesicle-inducting protein in plastids 1 (Vipp1), which functions for membrane maintenance and thylakoid biogenesis in cyanobacteria and plants, are similar peripheral membrane-binding proteins. Their homologous N-terminal amphipathic helices are required for membrane binding; however, the membrane features recognized and required for expressing their functionalities have remained largely uncharacterized. Rigorously controlled, in vitro methodologies with lipid vesicles and purified proteins were used in this study and provided the first biochemical and biophysical characterizations of membrane binding by PspA and Vipp1. Both proteins are found to sense stored curvature elastic (SCE) stress and anionic lipids within the membrane. PspA has an enhanced sensitivity for SCE stress and a higher affinity for the membrane than Vipp1. These variations in binding may be crucial for some of the proteins' differing roles in vivo. Assays probing the transcriptional regulatory function of PspA in the presence of vesicles showed that a relief of transcription inhibition occurs in an SCE stress-specific manner. This in vitro recapitulation of membrane stress-dependent transcription control suggests that the Psp response may be mounted in vivo when a cell's inner membrane experiences increased SCE stress. All cell types maintain the integrity of their membrane systems. One widely distributed membrane stress response system in bacteria is the phage shock protein (Psp) system. The central component, peripheral membrane protein PspA, which mitigates inner membrane stress in bacteria, has a counterpart, Vipp1, which functions for membrane maintenance and thylakoid biogenesis in plants and photosynthetic bacteria. Membrane association of both these proteins is accepted as playing a pivotal role in their functions. Here we show that direct membrane binding by

Uncover the mantle: rediscovering Gregório Lopes palette and technique with a study on the painting "Mater Misericordiae"

Science.gov (United States)

Antunes, Vanessa; Candeias, António; Oliveira, Maria J.; Carvalho, Maria L.; Dias, Cristina Barrocas; Manhita, Ana; Francisco, Maria J.; Costa, Sónia; Lauw, Alexandra; Manso, Marta

2016-11-01

Gregório Lopes (c. 1490-1550) was one of the most prominent painters of the renaissance and Mannerism in Portugal. The painting "Mater Misericordiae" made for the Sesimbra Holy House of Mercy, circa 1535-1538, is one of the most significant works of the artist, and his only painting on this theme, being also one of the most significant Portuguese paintings of sixteenth century. The recent restoration provided the possibility to study materially the painting for the first time, with a multianalytical methodology incorporating portable energy-dispersive X-ray fluorescence spectroscopy, scanning electron microscopy-energy-dispersive spectroscopy, micro-X-ray diffraction, micro-Raman spectroscopy and high-performance liquid chromatography coupled to diode array and mass spectrometry detectors. The analytical study was complemented by infrared reflectography, allowing the study of the underdrawing technique and also by dendrochronology to confirm the date of the wooden panels (1535-1538). The results of this study were compared with previous ones on the painter's workshop, and significant differences and similitudes were found in the materials and techniques used.

Removal of the phage-shock protein PspB causes reduction of virulence in Salmonella enterica serovar Typhimurium independently of NRAMP1

DEFF Research Database (Denmark)

Wallrodt, Inke; Jelsbak, Lotte; Thomsen, Line E.

2014-01-01

The phage-shock protein (Psp) system is believed to manage membrane stress in all Enterobacteriaceae and has recently emerged as being important for virulence in several pathogenic species of this phylum. The core of the Psp system consists of the pspA-D operon and the distantly located pspG gene......IV-induced secretin stress. In conclusion, our results demonstrate that removal of PspB reduces virulence in S. Typhimurium independently of host NRAMP1 expression, demonstrating that PspB has roles in intra-host survival distinct from the reported contributions of PspA....

PSP SAR interferometry monitoring of ground and structure deformations in the archeological site of Pompeii

Science.gov (United States)

Costantini, Mario; Francioni, Elena; Paglia, Luca; Minati, Federico; Margottini, Claudio; Spizzichino, Daniele; Trigila, Alessandro; Iadanza, Carla; De Nigris, Bruno

2016-04-01

The "Major Project Pompeii" (MPP) is a great collective commitment of different institututions and people to set about solving the serious problem of conservation of the largest archeological sites in the world. The ancient city of Pompeii with its 66 hectares, 44 of which are excaveted, is divided into 9 regiones (district), subdivided in 118 insulae (blocks) and almost 1500 domus (houses), and is Unesco site since 1996. The Italian Ministry for Heritage and Cultural Activities and Tourism (MiBACT) and Finmeccanica Group have sealed an agreement whereby the Finmeccanica Group will donate innovative technologies and services for monitoring and protecting the archaeological site of Pompeii. Moreover, the Italian Institute for Environment Protection and Research (ISPRA) - Geological Survey of Italy, was also involved to support the ground based analysis and interpretation of the measurements provided by the industrial team, in order to promote an interdisciplinary approach. In this work, we will focus on ground deformation measurements obtained by satellite SAR interferometry and on their interpretation. The satellite monitoring service is based on the processing of COSMO-SkyMed Himage data by the e-Geos proprietary Persistent Scatterer Pair (PSP) SAR interferometry technology. The PSP technique is a proven SAR interferometry method characterized by the fact of exploiting in the processing only the relative properties between close points (pairs) in order to overcome atmospheric artifacts (which are one of the main problems of SAR interferometry). Validations analyses showed that this technique applied to COSMO-SkyMed Himage data is able to retrieve very dense (except of course on vegetated or cultivated areas) millimetric deformation measurements with sub-metric localization. By means of the COSMO-SkyMed PSP SAR interferometry processing, a historical analysis of the ground and structure deformations occurred over the entire archaeological site of Pompeii in the

Postural imbalance and falls in PSP correlate with functional pathology of the thalamus.

Science.gov (United States)

Zwergal, A; la Fougère, C; Lorenzl, S; Rominger, A; Xiong, G; Deutschenbaur, L; Linn, J; Krafczyk, S; Dieterich, M; Brandt, T; Strupp, M; Bartenstein, P; Jahn, K

2011-07-12

To determine how postural imbalance and falls are related to regional cerebral glucose metabolism (PET) and functional activation of the cerebral postural network (fMRI) in patients with progressive supranuclear palsy (PSP). Sixteen patients with PSP, who had self-monitored their frequency of falls, underwent a standardized clinical assessment, posturographic measurement of balance during modified sensory input, and a resting [¹⁸F]FDG-PET. In addition, patients performed an fMRI paradigm using mental imagery of standing. Results were compared to healthy controls (n = 16). The frequency of falls/month in patients (range 1-40) correlated with total PSP rating score (r = 0.90). Total sway path in PSP significantly correlated with frequency of falls, especially during modulated sensory input (eyes open: r = 0.62, eyes closed: r = 0.67, eyes open/head extended: r = 0.84, eyes open/foam-padded platform: r = 0.87). Higher sway path values and frequency of falls were associated with decreased regional glucose metabolism (rCGM) in the thalamus (sway path: r = -0.80, falls: r = -0.64) and increased rCGM in the precentral gyrus (sway path: r = 0.79, falls: r = 0.64). Mental imagery of standing during fMRI revealed a reduced activation of the mesencephalic brainstem tegmentum and the thalamus in patients with postural imbalance and falls. The new and clinically relevant finding of this study is that imbalance and falls in PSP are closely associated with thalamic dysfunction. Deficits in thalamic postural control get most evident when balance is assessed during modified sensory input. The results are consistent with the hypothesis that reduced thalamic activation via the ascending brainstem projections may cause postural imbalance in PSP.

Large-scale quantitative analysis of painting arts.

Science.gov (United States)

Kim, Daniel; Son, Seung-Woo; Jeong, Hawoong

2014-12-11

Scientists have made efforts to understand the beauty of painting art in their own languages. As digital image acquisition of painting arts has made rapid progress, researchers have come to a point where it is possible to perform statistical analysis of a large-scale database of artistic paints to make a bridge between art and science. Using digital image processing techniques, we investigate three quantitative measures of images - the usage of individual colors, the variety of colors, and the roughness of the brightness. We found a difference in color usage between classical paintings and photographs, and a significantly low color variety of the medieval period. Interestingly, moreover, the increment of roughness exponent as painting techniques such as chiaroscuro and sfumato have advanced is consistent with historical circumstances.

Detection of pregnancy by radioimmunoassay of a pregnancy serum protein (PSP60) in cattle

International Nuclear Information System (INIS)

Mialon, M.M.; Renand, G.; Camous, S.; Martal, J.; Menissier, F.

1994-01-01

The accuracy and efficiency of pregnancy diagnoses in cattle by pregnancy serum protein (PSP60) radioimmunoassay, a progesterone radioimmunoassay or oestrus detection were compared. Blood samples were taken from 349 suckling heifers and cows ( 1 191 inseminations) at 28, 35, 50 and 90 d post-insemination for PSP60 determination and at 22-23 d for progesterone. Females were declared nonpregnant when plasma PSP60 concentration was lower than 0.2 ng/ml at 28, 35 and 50 d and 0.5 ng/ml at 90 d. When compared with rectal palpation at 90 d, the accuracy of positive (negative) diagnoses by progesterone assay was 80% (100%) in heifers and 75% (99%) in cows. The accuracy of positive diagnoses by PSP60 assay increased with gestation stage from 90% on d 28 in heifers (74% in cows) to 100% (99% in cows) at the time of rectal palpation. This accuracy was 84% on d 28 in cows when the interval from calving to blood sampling was higher than 115 d. Whatever the stage, the accuracy of negative diagnoses was higher than 90%. Efficiency in detecting pregnant or nonpregnant females on d 28 was equivalent to the progesterone assay. The method for detecting oestrus applied in this experiment was as efficient as the PSP60 or progesterone test at any stage of gestation. The PSP60 test is very flexible, which makes its use particularly interesting in naturally mated suckling herds because of the uncertainty regarding the date of fertilization. (authors)

Texton-based analysis of paintings

NARCIS (Netherlands)

Van der Maaten, L.J.P.; Postma, E.O.

2010-01-01

The visual examination of paintings is traditionally performed by skilled art historians using their eyes. Recent advances in intelligent systems may support art historians in determining the authenticity or date of creation of paintings. In this paper, we propose a technique for the examination of

THE IDENTIFICATION OF THE BINDING MEDIA IN THE TANG DYNASTY CHINESE WALL PAINTINGS BY USING Py-GC/MS AND GC/MS TECHNIQUES

Directory of Open Access Journals (Sweden)

Hong GUO

2011-06-01

Full Text Available The archaeological discoveries of Tang tomb murals in Xi’an, China brought to light unprecedented data for the study of the art of the Tang Dynasty (618-907 AD. The spectacular murals with their particular contents provided first-hand material for the study of Chinese history and the techniques of wall paintings during the Tang Dynasty. In order to gain a better understanding of the materials used and to preserve those paintings, pyrolysis-gas chromatography-mass spectrometry (Py-GC/MS and gas chromatography-mass spectrometry (GC/MS were applied for the characterization of the binding media in the paintings. The combination of these analytical techniques is an ideal methodology to identify binding media in unknown samples.

Non-destructive and micro-invasive testing techniques for characterizing materials, structures and restoration problems in mural paintings

Science.gov (United States)

Tortora, Mariagrazia; Sfarra, Stefano; Chiarini, Marco; Daniele, Valeria; Taglieri, Giuliana; Cerichelli, Giorgio

2016-11-01

In this paper, chemical and structural studies of medieval wall paintings in Ocre (L'Aquila, Italy) are presented. During the latest restoration campaign, non-destructive (Near-Infrared Reflectography and Infrared Thermography) and micro-invasive (Nuclear Magnetic Resonance, Fourier Transform Infrared Spectroscopy, μ-Raman, Scanning Electron Microscopy with X-ray Microanalysis, X-Ray Diffraction, X-Ray Fluorescence, Optical Microscopy, Mass Spectrometry, Thermogravimetry) analyses were performed in order to determine the detachments of wall surfaces and the characterization of original and restoration materials. Data integration allowed to reconstruct the conservative history, the execution techniques and the conservation problems of the artefact, as well as to assess the effectiveness of restoration activities adopted. The combined use of physical and micro-chemical techniques proved to be effective for an in-depth study of materials stratification of paintings.

Electrochemical assessment of magnetite anti corrosive paints

International Nuclear Information System (INIS)

Escobar, D. M.; Arroyave, C.; Jaramillo, F.; Mattos, O. R.; Margarit, I. c.; Calderon, J.

2003-01-01

With the purpose of deepening in the understanding of the mechanisms of protection of anticorrosive pigments based on iron oxides, this work has been carried out on the production of pure magnetite, and copper and chromium doped magnetite, which were evaluated by different characterization techniques. The paints were prepared with a solvent less epoxy resin maintaining the Pigment volume Content near the Practical Critical value (CPVC), established for each pigment. The paints were applied on polished steel and monitored with electrochemical techniques at total immersion conditions. Permeability and impedance measurements of free films were also done. Impedance data were simulated with the Boukamp software. Results show that the paints pigmented with doped magnetite present better behaviour than a paint prepared with commercial hematite. (Author) 8 refs

CSF neurofilament light chain and phosphorylated tau 181 predict disease progression in PSP.

Science.gov (United States)

Rojas, Julio C; Bang, Jee; Lobach, Iryna V; Tsai, Richard M; Rabinovici, Gil D; Miller, Bruce L; Boxer, Adam L

2018-01-23

To determine the ability of CSF biomarkers to predict disease progression in progressive supranuclear palsy (PSP). We compared the ability of baseline CSF β-amyloid 1-42 , tau, phosphorylated tau 181 (p-tau), and neurofilament light chain (NfL) concentrations, measured by INNO-BIA AlzBio3 or ELISA, to predict 52-week changes in clinical (PSP Rating Scale [PSPRS] and Schwab and England Activities of Daily Living [SEADL]), neuropsychological, and regional brain volumes on MRI using linear mixed effects models controlled for age, sex, and baseline disease severity, and Fisher F density curves to compare effect sizes in 50 patients with PSP. Similar analyses were done using plasma NfL measured by single molecule arrays in 141 patients. Higher CSF NfL concentration predicted more rapid decline (biomarker × time interaction) over 52 weeks in PSPRS ( p = 0.004, false discovery rate-corrected) and SEADL ( p = 0.008), whereas lower baseline CSF p-tau predicted faster decline on PSPRS ( p = 0.004). Higher CSF tau concentrations predicted faster decline by SEADL ( p = 0.004). The CSF NfL/p-tau ratio was superior for predicting change in PSPRS, compared to p-tau ( p = 0.003) or NfL ( p = 0.001) alone. Higher NfL concentrations in CSF or blood were associated with greater superior cerebellar peduncle atrophy (fixed effect, p ≤ 0.029 and 0.008, respectively). Both CSF p-tau and NfL correlate with disease severity and rate of disease progression in PSP. The inverse correlation of p-tau with disease severity suggests a potentially different mechanism of tau pathology in PSP as compared to Alzheimer disease. Copyright © 2017 American Academy of Neurology.

The physicochemical characterization of cave paintings of Baja California

International Nuclear Information System (INIS)

Valdez, B.; Cobo, J.; Schorr, M.; Cota, L.; Oviedo, F.

2006-01-01

The Palaeolithic paintings of Baja California constitute an important contribution to the national, historic and cultural patrimony of Mexico. The aim of this investigation was to determine the physicochemical characteristics, the microstructure and texture of these polychrome paintings, painted on rocks encountered in the mountainous, desert/arid zones of Baja California and Baja California South. The first stage of this work was devoted to the examination and recording of the cave paintings of 'El Vallecito', a narrow fluvial valley displaying large granitic rocks emerging from the sandy soil. Tiny painting samples were collected and analyzed by SEM, EDS and FTIR techniques. The painters used four main colours: red, black, yellow and white. The paint raw materials are mineral pigments: white (kaolin, calcite, and gypsum), red (hematite), yellow (ochre, limonite), black (charcoal from burnt wood or calcined bones) and water as a diluent and/or a binder, all encountered in the painters habitat. The minerals were collected, ground and sometimes heated to change their tone. By mixing with water, a spreadable paste or a thick slurry was produced, which was applied with the fingers for lines or a piece of animal skin for figures, respectively. The 100% solids, dry paint converts into a dense, hard layer, incrusted into the grainy, rough, hollow granite rock surface. This paint might be called s tone on stone , explaining its permanence for centuries enduring heat, wind and weather. A simulation of the painting technique was done at the Materials and Corrosion Laboratory, UABC by collecting mineral pigments, preparing the paint as a paste or slurry and applying it on a granitic rock. Knowing the paint composition, production and application techniques will be useful in e conservation and restoration of cave paintings and stone-built, ancient structures such as pyramids, cathedrals and monuments. (Author)

Investigation of the gilding technique in two post-Byzantine wall paintings using micro-analytical techniques

International Nuclear Information System (INIS)

Katsibiri, Olga; Boon, Jaap J.

2004-01-01

The main churches of two important monasteries in Thessalia, Central Greece, are decorated with wall paintings that hail from the post-Byzantine period. The mural decoration of the main church of the St. Byssarionas Monastery at Doussiko has been attributed to the iconographer Tzortzis. The same painter is believed to have also operated in the main church of the Transfiguration Monastery at the monastic community of Meteora. The light microscopic (LM) examination of the cross-sections of samples taken from the gilded areas of the wall paintings, together with the direct temperature resolved mass spectrometric (DTMS) and scanning electron microscopy-energy dispersive X-ray spectroscopic (SEM-EDX) analysis, revealed a further resemblance of the materials and the methodology employed. The gold leaf was applied to the paintings by means of a mordant, which contains linseed oil mixed with a lead-containing dryer and an earth pigment or clay. The present study can constitute additional evidence to reinforce the idea that the two churches may have been painted by the same painter or workshop

Combination of pneumococcal surface protein A (PspA with whole cell pertussis vaccine increases protection against pneumococcal challenge in mice.

Directory of Open Access Journals (Sweden)

Maria Leonor S Oliveira

Full Text Available Streptococcus pneumoniae is the leading cause of respiratory acute infections around the world. In Latin America, approximately 20,000 children under 5 years of age die of pneumococcal diseases annually. Pneumococcal surface protein A (PspA is among the best-characterized pneumococcal antigens that confer protection in animal models of pneumococcal infections and, as such, is a good alternative for the currently available conjugated vaccines. Efficient immune responses directed to PspA in animal models have already been described. Nevertheless, few low cost adjuvants for a subunit pneumococcal vaccine have been proposed to date. Here, we have tested the adjuvant properties of the whole cell Bordetella pertussis vaccine (wP that is currently part of the DTP (diphtheria-tetanus-pertussis vaccine administrated to children in several countries, as an adjuvant to PspA. Nasal immunization of BALB/c mice with a combination of PspA5 and wP or wP(low--a new generation vaccine that contains low levels of B. pertussis LPS--conferred protection against a respiratory lethal challenge with S. pneumoniae. Both PspA5-wP and PspA5-wP(low vaccines induced high levels of systemic and mucosal antibodies against PspA5, with similar profile, indicating no essential requirement for B. pertussis LPS in the adjuvant properties of wP. Accordingly, nasal immunization of C3H/HeJ mice with PspA5-wP conferred protection against the pneumococcal challenge, thus ruling out a role for TLR4 responses in the adjuvant activity and the protection mechanisms triggered by the vaccines. The high levels of anti-PspA5 antibodies correlated with increased cross-reactivity against PspAs from different clades and also reflected in cross-protection. In addition, passive immunization experiments indicated that antibodies played an important role in protection in this model. Finally, subcutaneous immunization with a combination of PspA5 with DTP(low protected mice against challenge with two

Lined canvas paintings

DEFF Research Database (Denmark)

Krarup Andersen, Cecil

2013-01-01

at 50% RH but increased the stress level severely in dry conditions and offered no support to the painting at 70-80 % RH. This means that the traditional glue-paste lining techniques and the wax-resin technique in high RH seem to limit the advisable RH fluctuation in a cultural institution. Conversely...

Fly ash based zeolitic pigments for application in anticorrosive paints

International Nuclear Information System (INIS)

Shaw, Ruchi; Tiwari, Sangeeta

2016-01-01

The purpose of this work is to evaluate the utilization of waste fly ash in anticorrosive paints. Zeolite NaY was synthesized from waste fly ash and subsequently modified by exchanging its nominal cation Na + with Mg 2+ and Ca 2+ ions. The metal ion exchanged zeolite was then used as anticorrosive zeolitic pigments in paints. The prepared zeolite NaY was characterized using X-Ray diffraction technique and Scanning electron microscopy. The size, shape and density of the prepared fly ash based pigments were determined by various techniques. The paints were prepared by using fly ash based zeolitic pigments in epoxy resin and the percentages of pigments used in paints were 2% and 5%. These paints were applied to the mild steel panels and the anticorrosive properties of the pigments were assessed by the electrochemical spectroscopy technique (EIS).

The identification of synthetic organic pigments in modern paints and modern paintings using pyrolysis-gas chromatography-mass spectrometry.

Science.gov (United States)

Russell, Joanna; Singer, Brian W; Perry, Justin J; Bacon, Anne

2011-05-01

A collection of more than 70 synthetic organic pigments were analysed using pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS). We report on the analysis of diketo-pyrrolo-pyrrole, isoindolinone and perylene pigments which are classes not previously reported as being analysed by this technique. We also report on a number of azo pigments (2-naphthol, naphthol AS, arylide, diarylide, benzimidazolone and disazo condensation pigments) and phthalocyanine pigments, the Py-GC-MS analysis of which has not been previously reported. The members of each class were found to fragment in a consistent way and the pyrolysis products are reported. The technique was successfully applied to the analysis of paints used by the artist Francis Bacon (1909-1992), to simultaneously identify synthetic organic pigments and synthetic binding media in two samples of paint taken from Bacon's studio and micro-samples taken from three of his paintings and one painting attributed to him.

The pancreas responds to remote damage and systemic stress by secretion of the pancreatic secretory proteins PSP/regI and PAP/regIII.

Science.gov (United States)

Reding, Theresia; Palmiere, Cristian; Pazhepurackel, Clinsyjos; Schiesser, Marc; Bimmler, Daniel; Schlegel, Andrea; Süss, Ursula; Steiner, Sabrina; Mancina, Leandro; Seleznik, Gitta; Graf, Rolf

2017-05-02

In patients with infection and sepsis serum levels of Pancreatic Stone protein/regenerating protein I (PSP) are highly elevated. The origin of PSP during these conditions is presumably the pancreas, however, an intestinal origin cannot be excluded. Similarly, pancreatitis-associated protein (PAP) was identified in the pancreas. These proteins were also localized in intestinal organs. Here we aim to elucidate the bio-distribution of PSP and PAP in animal models of sepsis and in healthy humans. PSP and PAP responded to remote lesions in rats although the pancreatic response was much more pronounced than the intestinal. Tissue distribution of PSP demonstrated a 100-fold higher content in the pancreas compared to any other organ while PAP was most abundant in the small intestine. Both proteins responded to CLP or sham operation in the pancreas. PSP also increased in the intestine during CLP. The distribution of PSP and PAP in human tissue mirrored the distribution in the murine models. Distribution of PSP and PAP was visualized by immunohistochemistry. Rats and mice underwent midline laparotomies followed by mobilization of tissue and incision of the pancreatic duct or duodenum. Standard cecum-ligation-puncture (CLP) procedures or sham laparotomies were performed. Human tissue extracts were analyzed for PSP and PAP. The pancreas reacts to remote lesions and septic insults in mice and rats with increased PSP synthesis, while PAP is selectively responsive to septic events. Furthermore, our results suggest that serum PSP in septic patients is predominantly derived through an acute phase response of the pancreas.

Localization of proteins in paint cross-sections by scanning electrochemical microscopy as an alternative immunochemical detection technique

Energy Technology Data Exchange (ETDEWEB)

Sciutto, Giorgia; Prati, Silvia [Microchemistry and Microscopy Art Diagnostic Laboratory, University of Bologna, Via Guaccimanni 42, Ravenna 48121 (Italy); Department of Chemistry “G. Ciamician”, University of Bologna, Via Selmi, Bologna 2 40126 (Italy); Mazzeo, Rocco, E-mail: rocco.mazzeo@unibo.it [Microchemistry and Microscopy Art Diagnostic Laboratory, University of Bologna, Via Guaccimanni 42, Ravenna 48121 (Italy); Department of Chemistry “G. Ciamician”, University of Bologna, Via Selmi, Bologna 2 40126 (Italy); Zangheri, Martina; Roda, Aldo; Bardini, Luca; Valenti, Giovanni; Rapino, Stefania [Department of Chemistry “G. Ciamician”, University of Bologna, Via Selmi, Bologna 2 40126 (Italy); Marcaccio, Massimo, E-mail: massimo.marcaccio@unibo.it [Department of Chemistry “G. Ciamician”, University of Bologna, Via Selmi, Bologna 2 40126 (Italy)

2014-06-01

Highlights: • Advanced immuno-electrochemical detection of proteins in paint samples by SECM. • Analysis performed directly on cross-section with high spatial resolution. • Identification of HRP catalytic activity for a selective location of analyte. • Satisfactory results were obtained for aged real samples. • The way forward for an extensive application of SECM in conservation science is shown. - Abstract: The qualitative identification of proteinaceous substances, as well as their location within a complex paint stratigraphy, is one of the most challenging issues in the characterization of painting materials. Nevertheless, information on paint components represent a crucial task for studies concerning both the ancient painting techniques adopted and the state of conservation, being fundamental investigations for the selection of appropriate conservation actions. The present research was aimed at developing a new detection approach for the immunochemical localization of ovalbumin in paint cross-sections based on the use of scanning electrochemical microscopy (SECM). The immunochemical analyses were performed using an anti-ovalbumin primary antibody and a secondary antibody labelled with horseradish peroxidase (HRP). SECM measurements were performed in feedback mode using benzoquinone (BQ)/hydroquinone (H{sub 2}Q) redox couple. In presence of hydrogen peroxide (H{sub 2}O{sub 2}), HRP catalyzes the re-oxidation of H{sub 2}Q to BQ and the increment of BQ concentration in correspondence of the target protein was detected by SECM through the electrochemical reduction of the regenerated BQ at the microelectrode. Indeed, the localization of ovalbumin was possible thanks to a clear discrimination of SECM currents, achieved by the comparison of the measurements recorded before and after H{sub 2}O{sub 2} administration, based on the HRP on/off approach. The method was evaluated both on samples from standard mocks-up and on a historical sample, collected from a

X-ray fluorescence in Member States (Italy): Portable EDXRF in a multi-technique approach for the analyses of large paintings

International Nuclear Information System (INIS)

Ridolfi, Stefano

2014-01-01

Energy-dispersive X-ray fluorescence (EDXRF) with its portable capability, generally characterized by a small Xray tube and a Si-PIN or Si-drift detector, is particularly useful to analyze works of art. The main aspect that characterizes the EDXRF technique is its non-invasive character. This characteristic that makes the technique so powerful and appealing is on the other hand the main source of uncertainty in XRF measurements on Cultural Heritage. This problem is even more evident when we analyze paintings because of their intrinsic stratigraphic essence. As a matter of fact a painting is made of several layers: the support, which can be mainly of wood, canvas, paper; the preparation layer, mainly gypsums, white lead or ochre; pigment layers and at the end the protective varnish layer. The penetrating power of X rays allows that most of the times the information of all the layers reaches the detector. Most of the information that is in the spectrum arrives from deep layers of which we have no clue. In order to better understand this concept, let us use the equation of A. Markowicz. in which the various uncertainties that influence the analyses with portable EDXRF are reported. Let us adjust this equation for non invasive portable EDXRF analysis. The second, the third and the fourth term do not exist, for obvious reasons. Only the first and the last term influence the total uncertainty of an EDXRF analysis. The ways to reduce the influence of the fifth term is known by any scientist: good stability of the system, long measuring time, correct standard samples, good energy resolution etc. But what about the first term when we are executing a non invasive analysis? An example that shows the influence of the sample representation in the increasing of the uncertainty of a XRF analysis is the case in which we are asked to determine the original pigments used in a painting. If we have no clue of where restoration areas are dislocated on the painting, the probability of

4D Visualization of Painted Sculpture and Murals

Science.gov (United States)

Ai, M. Y.; Tong, H.; Shen, L.; Wang, R. X.; Zhang, F.; Zhang, Z. C.; Hu, Q. W.; Zhu, Y. X.; Zhang, H.

2015-08-01

Most cultural heritage applications address visualization with using various media or platforms: desktop-based multimedia presentations, museum kiosks, or videos produced with computer animation. However, these techniques can not directly reveal or show the course that the colorful surface of painted sculpture and murals becomes faint along with the change of the climate and time. Most current techniques just preserve the current appearance and disseminate the current situation of the painted sculpture and murals. The course how these forms of cultural heritage change along the time has not been visualized. In this paper we developed an approach to modelling of painted sculpture and murals that has undergone changes over the years. Different hypotheses has also be given if there is uncertainty. A painted sculpture of Mogao Grottoes is used to demonstate this approach.

Laboratory two-dimensional X-ray microdiffraction technique: a support for authentication of an unknown Ghirlandaio painting

International Nuclear Information System (INIS)

Bontempi, E.; Benedetti, D.; Zacco, A.; Borgese, L.; Depero, L.E.; Massardi, A.

2008-01-01

Europe has a very rich and diversified cultural heritage of art works, including buildings, monuments and objects of all sizes, involving a great variety of materials. The continuous discovery of new art works opens the problem of their authentication. Advanced analytical techniques can be fundamental to understand the way of life, the culture and the technical and intellectual know-how of the artists. Indeed, the authentication of an art work involves the identification of the used materials, their production techniques and procedures used for the work realization. It is possible to know the origin and provenance of materials, including the location of the natural sources. Advanced analytical techniques also help one to understand degradation processes, corrosion, weathering, and preservation-conservation protocols. In this paper we present a painting attributed to Domenico Ghirlandaio. Ghirlandaio is a well-known artist of fifteenth century who contributes to the apprenticeship of Michelangelo Buonarroti. The study of the pigments used in this painting, which belongs to a private collection, has been supported mainly by means of laboratory two-dimensional X-ray microdiffraction (μXRD 2 ). The possibility to obtain information about not only the phase, but also microstructure allows one to extract interesting consideration and to obtain evidence of the painter's style and intention. (orig.)

Analysis of Pumped Storage Plants (PSP) viability associated with other types of intermittent renewable energy

International Nuclear Information System (INIS)

Andrade, J G P; Barbosa, P S F; Luvizotto, E Jr; Zuculin, S; Pinto, Marrc; Filho, G L Tiago

2014-01-01

The energy generated by wind or solar photovoltaic (PV system) can be used by PSP to accumulate water in the upper reservoir, in the form of potential energy to be used later, during periods of high energy demand. This procedure offers the advantage of enabling the use of intermittent renewable energy source in times of growing needs of the electric power supply. The location of the PSP, the environmental aspects involved, their possible use for various purposes (stability of the power system at peak times, associate the turbine water for public supply purposes, among others) and the discussion of regulatory issues needs to be debated in the current context, where environmental issues require reliable sources of power generation and demand shows strong growth rates. A dynamic model is used to analyze the behavior of a PSP proposal for a site in Brazil, analyzing a complete cycle of its operation as a pump or turbine. The existing difficulties to use this proposal based on existing regulatory policies are also discussed, and a list of recommended adjustments is provided to allow the penetrations of PSP projects in the Brazilian institutional framework, coupled with other intermittent energy sources

THz reflectometric imaging of medieval wall paintings

DEFF Research Database (Denmark)

Dandolo, Corinna Ludovica Koch; Jepsen, Peter Uhd

2013-01-01

Terahertz time-domain reflectometry has been applied to the investigation of a medieval Danish wall painting. The technique has been able to detect the presence of carbonblack layer on the surface of the wall painting and a buried insertion characterized by high reflectivity values has been found...

Historical evolution of oil painting media: A rheological study

Science.gov (United States)

de Viguerie, Laurence; Ducouret, Guylaine; Lequeux, François; Moutard-Martin, Thierry; Walter, Philippe

2009-09-01

Rheology is the science of flow, which is a phenomenon found in every painting operation, such as decorative paintings or protective coatings. In this article, the principles of rheology as applied to paintings and coatings are recalled in a first part and the rheological criteria required in the paint industry presented. Indeed, different flow behaviours leads to different finishes. The same procedure and techniques as in industry can be employed to explain some evolutions in oil painting aspects over the centuries. The first recipes for oil painting indicate the use of treated oil, resins and spirits. This article deals with the evolution of the composition of these systems as media for oil painting, according to rheological clues. During the Renaissance period, the media used were Newtonian or slightly shear thinning and allowed one a perfect levelling. Then techniques changed, paints became more opaque with less addition of oil/resin media, and brushstrokes appeared visible. Some preparations containing lead, oil and mastic resin, whose flow behaviour is closed to those required in industry, may have appeared during the 17th century and are still used and sold today. To cite this article: L. de Viguerie et al., C. R. Physique 10 (2009).

Cleaning of Easel Paintings: An Overview

International Nuclear Information System (INIS)

Bordalo, R.; Morais, P.J.; Gouveia, H.; Young, C.

2006-01-01

The application of laser cleaning to paintings is relatively recent despite its use on stone-based materials for over 30 years. The cleaning of paintings is of high importance, because it is the least reversible invasive intervention, as well as the most usual of all conservation treatments. Paintings are multilayer system of heterogeneous nature, often very sensitive and inherent difficult to clean. Being a noncontact method, laser cleaning has advantages compared to alternative techniques. Over the last decade, there have been important research studies and advances. However, they are far from sufficient to study the effects on painting materials and to establish the best parameters for each material under investigation. This paper presents a historical overview of the application of laser technology to the cleaning of paintings giving special emphasis on the research of the last decade. An overview of the current research into the interaction between the radiation and the different painting materials (varnish, pigments, and medium) is also given. The pigment's mechanisms of discoloration and the presence of media as a variable factor in the discoloration of pigments are discussed.

Oils, paintings and chemistry

Directory of Open Access Journals (Sweden)

Maria Eduarda Machado de Araújo

2005-01-01

Full Text Available In oil paintings artists use oils to apply pigments. These oils firstly are liquid and then solidify in a thin film. Many chemical reactions are involved in drying and also in the aging of these oils. Drying is a continuous process that begins with the oxidation of insaturated fatty acids from triglycerides to originate peroxides. These compounds suffer a cascade of reactions that lead to cross linking bonds between fatty acids residues, transforming the oil in a solid film. Identification of the film oil is possible using the palmitic/stearic ratio (P/S by chromatographic (GC and/or spectroscopic techniques. Sterol composition, phytosterols or cholesterol, determined by GC-MS or FTIR techniques, allows investigators to distinguish between oil painting and a temper one that used egg as the binding medium.

A comparison of film and 3 digital imaging systems for natural dental caries detection: CCD, CMOS, PSP and film

Energy Technology Data Exchange (ETDEWEB)

Han, Won Jeong [Dankook University College of Medicine, Seoul (Korea, Republic of)

2004-03-15

To evaluate the diagnostic accuracy of occlusal and proximal caries detection using CCD, CMOS, PSP and film system. 32 occlusal and 30 proximal tooth surfaces were radiographed under standardized conditions using 3 digital systems; CCD (CDX-2000HQ, Biomedysis Co., Seoul, Korea), CMOS (Schick, Schick Inc., Long Island, USA), PSP (Digora FMX, Orion Co./Soredex, Helsinki, Finland) and 1 film system (Kodak Insight, Eastman Kodak, Rochester, USA). 5 observers examined the radiographs for occlusal and proximal caries using a 5-point confidence scale. The presence of caries was validated histologically and radiographically. Diagnostic accuracy was evaluated using ROC curve areas (AZ). Analysis using ROC curves revealed the area under each curve which indicated a diagnostic accuracy. For occlusal caries, Kodak Insight film had an Az of 0.765, CCD one of 0.730, CMOS one of 0.742 and PSP one of 0.735. For proximal caries, Kodak Insight film had an Az of 0.833, CCD one of 0.832, CMOS one of 0.828 and PSP one of 0.868. No statistically significant difference was noted between any of the imaging modalities. CCD, CMOS, PSP and film performed equally well in the detection of occlusal and proximal dental caries. CCD, CMOS and PSP-based digital images provided a level of diagnostic performance comparable to Kodak Insight film.

A comparison of film and 3 digital imaging systems for natural dental caries detection: CCD, CMOS, PSP and film

International Nuclear Information System (INIS)

Han, Won Jeong

2004-01-01

To evaluate the diagnostic accuracy of occlusal and proximal caries detection using CCD, CMOS, PSP and film system. 32 occlusal and 30 proximal tooth surfaces were radiographed under standardized conditions using 3 digital systems; CCD (CDX-2000HQ, Biomedysis Co., Seoul, Korea), CMOS (Schick, Schick Inc., Long Island, USA), PSP (Digora FMX, Orion Co./Soredex, Helsinki, Finland) and 1 film system (Kodak Insight, Eastman Kodak, Rochester, USA). 5 observers examined the radiographs for occlusal and proximal caries using a 5-point confidence scale. The presence of caries was validated histologically and radiographically. Diagnostic accuracy was evaluated using ROC curve areas (AZ). Analysis using ROC curves revealed the area under each curve which indicated a diagnostic accuracy. For occlusal caries, Kodak Insight film had an Az of 0.765, CCD one of 0.730, CMOS one of 0.742 and PSP one of 0.735. For proximal caries, Kodak Insight film had an Az of 0.833, CCD one of 0.832, CMOS one of 0.828 and PSP one of 0.868. No statistically significant difference was noted between any of the imaging modalities. CCD, CMOS, PSP and film performed equally well in the detection of occlusal and proximal dental caries. CCD, CMOS and PSP-based digital images provided a level of diagnostic performance comparable to Kodak Insight film.

Onoufrios, the famous XVI's century iconographer, creator of the ``Berati School'': studying the technique and materials used in wall paintings of inscribed churches

Science.gov (United States)

Pavlidou, E.; Arapi, M.; Zorba, T.; Anastasiou, M.; Civici, N.; Stamati, F.; Paraskevopoulos, K. M.

2006-06-01

The study of the materials and techniques employed for wall painting, complementing the information from historical and aesthetic data, contributes to the integrated knowledge of the iconographer and his period. In the 16th century, regarding the iconography in the former Byzantine area, besides the School of Crete and Francos Catelanos and his school, a third artistic personality who also created his own school, Onoufrios, appeared in central Albania and expanded his activity as a painter to northern Greece as well as nearby areas, such as Ohrid. Inscriptions documenting the works of Onoufrios are found in some of the churches that he decorated with wall paintings: “St. Apostles” (1547) Kastoria Greece, “St. Nicolas” Shelcan Albania, “St. Paraskevi” (1554), Valsh Albania, while are attributed to him the church of “St. Theodores” in Berati, Albania (before 1547) and others. He is one of the best icon painters of the whole Balkan region, and the best painter that has ever worked in Albanian territory. Onoufrios managed to combine the local painting tradition with the best tradition of the eastern (Paleologian) and western (Italian) schools, resulting in a realistic and natural depiction. He is the creator of the “Berati School” that expanded to other parts of the peninsula. His individual character can be distinguished in the work of his students: his son Nikolaos (who inherited his style in painting), Onoufrios from Cyprus, etc. Based on careful observations, we extracted number of paint samples from wall paintings of three of the above mentioned churches. Ground and paint layers were examined using micro-FTIR, Optical Microscopy, TXRF and SEM-EDS, to characterize materials and methods used by the artist to create these works. Our findings in each church are discussed and compared with the others in order to understand how and with what material and resources the painter worked and how he developed his technique. The presence of calcium

PSP: rapid identification of orthologous coding genes under positive selection across multiple closely related prokaryotic genomes.

Science.gov (United States)

Su, Fei; Ou, Hong-Yu; Tao, Fei; Tang, Hongzhi; Xu, Ping

2013-12-27

With genomic sequences of many closely related bacterial strains made available by deep sequencing, it is now possible to investigate trends in prokaryotic microevolution. Positive selection is a sub-process of microevolution, in which a particular mutation is favored, causing the allele frequency to continuously shift in one direction. Wide scanning of prokaryotic genomes has shown that positive selection at the molecular level is much more frequent than expected. Genes with significant positive selection may play key roles in bacterial adaption to different environmental pressures. However, selection pressure analyses are computationally intensive and awkward to configure. Here we describe an open access web server, which is designated as PSP (Positive Selection analysis for Prokaryotic genomes) for performing evolutionary analysis on orthologous coding genes, specially designed for rapid comparison of dozens of closely related prokaryotic genomes. Remarkably, PSP facilitates functional exploration at the multiple levels by assignments and enrichments of KO, GO or COG terms. To illustrate this user-friendly tool, we analyzed Escherichia coli and Bacillus cereus genomes and found that several genes, which play key roles in human infection and antibiotic resistance, show significant evidence of positive selection. PSP is freely available to all users without any login requirement at: http://db-mml.sjtu.edu.cn/PSP/. PSP ultimately allows researchers to do genome-scale analysis for evolutionary selection across multiple prokaryotic genomes rapidly and easily, and identify the genes undergoing positive selection, which may play key roles in the interactions of host-pathogen and/or environmental adaptation.

Conservation problems with paintings containing fluorescent layers of paint

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Stefanie De Winter

2010-11-01

Full Text Available L’artiste moderne cherche continuellement de nouvelles techniques. Des nouveaux matériaux tels que l’éponge, le polyester, le sable, etc. sont devenus courants. Ces développements amènent de nouveaux problèmes dans le domaine de la conservation (préventive des matériaux en question. Chaque matériau doit être analysé individuellement afin de préserver  le mieux possible l’intention de l’artiste à long terme. La présente recherche concerne des matériaux très récents: les pigments et les couleurs fluorescentes. Ces derniers n’ont fait leur apparition qu’au vingtième siècle. Pour cette raison les données concernant leur dégradation et leur conservation sont peu nombreuses. La majorité des tableaux fluorescents sont conçus pour être montrés sous éclairage UV. En cas de dommage, si l’œuvre a besoin d’être retouchée, ceci pose un grand problème esthétique. La retouche devient visible sous les lampes UV. La première partie de la recherche concerne la composition des différentes sortes de pigments et de peintures. Par la suite, les différentes causes de dégradation- lumière UV, chaleur, etc.- sont analysées en détail. Pour conclure, un possible remède est proposé.In modern art we can see that artists are breaking with traditional techniques. New materials like sponge, polyester, sand, etc. are being used. This causes a lot of new problems in the (preventive conservation of works containing these materials. Every material needs to be researched individually so the exact intention of the artist can be preserved for a (relatively long period. My research is about very recent materials: fluorescent pigments and paints. These only started to be used by artists from the 60’s. That's why there is not much information about their aging and ways to (preventively conserve them. A lot of fluorescent paintings are meant to be shown under UV-light. If a fluorescent painting has damage and needs to be retouched

A review on paint sludge from automotive industries: Generation, characteristics and management.

Science.gov (United States)

Salihoglu, Guray; Salihoglu, Nezih Kamil

2016-03-15

The automotive manufacturing process results in the consumption of several natural sources and the generation of various types of wastes. The primary source of hazardous wastes at an automotive manufacturing plant is the painting process, and the major waste fraction is paint sludge, which is classified with EU waste code of 080113* implying hazardous characteristics. The amount of the paint sludge generated increases every year with the worldwide increase in the car production. The characteristics of the paint sludge, which mainly designate the management route, are mainly determined by the type of the paint used, application technique employed, and the chemicals applied such as flocculants, detackifiers, pH boosters, antifoam agents, and biocides as well as the dewatering techniques preferred. Major routes for the disposal of the paint sludges are incineration as hazardous waste or combustion at cement kilns. Because of high dissolved organic carbon content of the paint, the paint sludge cannot be accepted by landfills according to European Union Legislations. More investigations are needed in the field of paint sludge recycling such as recycling it as a new paint or as other formulations, or making use of the sludge for the production of construction materials. Research on the applicability of the paint sludge in composting and biogasification can also be useful. Ongoing research is currently being conducted on new application techniques to increase the effectiveness of paint transfer, which helps to prevent the generation of paint sludge. Advancements in paint and coating chemistry such as the reduction in the coating layers with its thickness also help to decrease the level of paint sludge generation. Investigations on the effects of the chemicals on the recycling potential of paint sludges and consideration of these effects by the chemical manufacturer companies would be extremely important. This review presents the formation of paint sludge, the factors

Nanoparticles Ni electroplating and black paint for solar collector applications

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J. El Nady

2016-06-01

Full Text Available A nanoparticles layer of bright nickel base was deposited on copper substrates using electrodeposition technique before spraying the paint. IR reflectance of the paint was found to be around 0.4 without bright nickel layer and the reflectance increased to 0.6 at a Ni layer thickness of 750 nm. The efficiency of the constructed solar collectors using black paint and black paint combined with bright nickel was found to be better than black paint individually. After aging tests under high temperature, Bright nickel improved the stability of the absorber paint. The collector optical gain FR(τα was lowered by 24.7% for the commercial paint and lowered by 19.3% for the commercial paint combined with bright nickel. The overall heat loss FR(UL was increased by 3.3% for the commercial paint and increased by 2.7% for the commercial paint combined with bright nickel after the temperature aging test.

Anionic lipids and the cytoskeletal proteins MreB and RodZ define the spatio-temporal distribution and function of membrane stress controller PspA in Escherichia coli.

Science.gov (United States)

Jovanovic, Goran; Mehta, Parul; Ying, Liming; Buck, Martin

2014-11-01

All cell types must maintain the integrity of their membranes. The conserved bacterial membrane-associated protein PspA is a major effector acting upon extracytoplasmic stress and is implicated in protection of the inner membrane of pathogens, formation of biofilms and multi-drug-resistant persister cells. PspA and its homologues in Gram-positive bacteria and archaea protect the cell envelope whilst also supporting thylakoid biogenesis in cyanobacteria and higher plants. In enterobacteria, PspA is a dual function protein negatively regulating the Psp system in the absence of stress and acting as an effector of membrane integrity upon stress. We show that in Escherichia coli the low-order oligomeric PspA regulatory complex associates with cardiolipin-rich, curved polar inner membrane regions. There, cardiolipin and the flotillin 1 homologue YqiK support the PspBC sensors in transducing a membrane stress signal to the PspA-PspF inhibitory complex. After stress perception, PspA high-order oligomeric effector complexes initially assemble in polar membrane regions. Subsequently, the discrete spatial distribution and dynamics of PspA effector(s) in lateral membrane regions depend on the actin homologue MreB and the peptidoglycan machinery protein RodZ. The consequences of loss of cytoplasmic membrane anionic lipids, MreB, RodZ and/or YqiK suggest that the mode of action of the PspA effector is closely associated with cell envelope organization. © 2014 The Authors.

Defects detection and non-destructive testing (NDT) techniques in paintings: a unified approach through measurements of deformation

Science.gov (United States)

Sfarra, S.; Ibarra-Castanedo, C.; Ambrosini, D.; Paoletti, D.; Bendada, A.; Maldague, X.

2013-05-01

The present study is focused on two topics. The first one is a mathematical model, useful to understand the deformation of paintings, which uses straining devices, adjustable and micrometrically controlled via a pin supported in a hollow cylinder. Strains were analyzed by holographic interferometry (HI) technique using an appropriate frame. The second one concerns the need to improve the conservator's knowledge about the defect's detection and defect's propagation in acrylic painting characterized of underdrawings and pentimenti. To fulfill this task, a sample was manufactured to clarify the several uncertainties inherent the influence of external factors on their conservation. Subsurface anomalies were also retrieved by near-infrared reflectography (NIRR) and transmittography (NIRT) techniques, using LED lamps and several narrow-band filters mounted on a CMOS camera, working at different wavelengths each other and in combination with UV imaging. In addition, a sponge glued on the rear side of the canvas was impregnated with a precise amount of water by means of a syringe to verify the "stretcher effect" by the digital speckle photography (DSP) technique (using MatPIV). The same effect also affects the sharp transition of the canvas at the stretcher's edge. In this case, a possible mechanism is a direct mechanical contact between stretcher and canvas that was investigated by HI technique. Finally, advanced algorithms applied to the square heating thermography (SHT) data were very useful to detect three Mylar® inserts simulating different type of defects. These fabricated defects were also identified by optical techniques, while the visual inspection was the only one capable of detecting a biological damage.

Fra Angelico’s painting technique revealed by terahertz time-domain imaging (THz-TDI)

DEFF Research Database (Denmark)

Dandolo, Corinna Ludovica Koch; Picollo, Marcello; Cucci, Costanza

2016-01-01

We have investigated with terahertz time-domain imaging (THz-TDI) the well-known Lamentation over the dead Christ panel painting (San Marco Museum, Florence) painted by Fra Giovanni Angelico within 1436 and 1441. The investigation provided a better understanding of the construction and gilding te...

Nondestructive analysis of automotive paints with spectral domain optical coherence tomography.

Science.gov (United States)

Dong, Yue; Lawman, Samuel; Zheng, Yalin; Williams, Dominic; Zhang, Jinke; Shen, Yao-Chun

2016-05-01

We have demonstrated for the first time, to our knowledge, the use of optical coherence tomography (OCT) as an analytical tool for nondestructively characterizing the individual paint layer thickness of multiple layered automotive paints. A graph-based segmentation method was used for automatic analysis of the thickness distribution for the top layers of solid color paints. The thicknesses measured with OCT were in good agreement with the optical microscope and ultrasonic techniques that are the current standard in the automobile industry. Because of its high axial resolution (5.5 μm), the OCT technique was shown to be able to resolve the thickness of individual paint layers down to 11 μm. With its high lateral resolution (12.4 μm), the OCT system was also able to measure the cross-sectional area of the aluminum flakes in a metallic automotive paint. The range of values measured was 300-1850  μm2. In summary, the proposed OCT is a noncontact, high-resolution technique that has the potential for inclusion as part of the quality assurance process in automobile coating.

Noise resistance applied to the study paints

International Nuclear Information System (INIS)

Lanchas Garcia-Zarco, S.; Alfosin Perez, V.; Suarez Garcia, A.; Urrejola Madrinan, S.; Sanchez Bermudez, A.

2015-01-01

Electrochemical noise is one of the methods of analysis used to interpret the phenomenon of corrosion. It has a number of advantages over other methodology types including its simplicity, its low cost and the fact that it does not disturb the system. This methodology appears to be effective together with other techniques in metal-electrolyte systems. In this case the technique is applied on its own on commercial anti-corrosion paints for which no information is available from other techniques. The main result of this study reveals the effectiveness of the noise resistance parameter, which had already been tested in the lab, when it is used to explain how the paint system behaves in industry. (Author)

PSP SAR interferometry monitoring of ground and structure deformations applied to archaeological sites

Science.gov (United States)

Costantini, Mario; Francioni, Elena; Trillo, Francesco; Minati, Federico; Margottini, Claudio; Spizzichino, Daniele; Trigila, Alessandro; Iadanza, Carla

2017-04-01

Archaeological sites and cultural heritage are considered as critical assets for the society, representing not only the history of region or a culture, but also contributing to create a common identity of people living in a certain region. In this view, it is becoming more and more urgent to preserve them from climate changes effect and in general from their degradation. These structures are usually just as precious as fragile: remote sensing technology can be useful to monitor these treasures. In this work, we will focus on ground deformation measurements obtained by satellite SAR interferometry and on the methodology adopted and implemented in order to use the results operatively for conservation policies in a Italian archaeological site. The analysis is based on the processing of COSMO-SkyMed Himage data by the e-GEOS proprietary Persistent Scatterer Pair (PSP) SAR interferometry technology. The PSP technique is a proven SAR interferometry technology characterized by the fact of exploiting in the processing only the relative properties between close points (pairs) in order to overcome atmospheric artefacts (which are one of the main problems of SAR interferometry). Validations analyses [Costantini et al. 2015] settled that this technique applied to COSMO-SkyMed Himage data is able to retrieve very dense (except of course on vegetated or cultivated areas) millimetric deformation measurements with sub-metric localization. Considering the limitations of all the interferometric techniques, in particular the fact that the measurement are along the line of sight (LOS) and the geometric distortions, in order to obtain the maximum information from interferometric analysis, both ascending and descending geometry have been used. The ascending analysis allows selecting measurements points over the top and, approximately, South-West part of the structures, while the descending one over the top and the South-East part of the structures. The interferometric techniques needs

Influence of preoperative septic peritonitis and anastomotic technique on the dehiscence of enterectomy sites in dogs: A retrospective review of 210 anastomoses.

Science.gov (United States)

Davis, Daniel J; Demianiuk, Ryan M; Musser, Jon; Podsiedlik, Maria; Hauptman, Joe

2018-01-01

To determine the influence of preoperative septic peritonitis (PSP) and stapled versus hand-sewn anastomoses on the dehiscence of intestinal resection and anastomosis (IRA). We hypothesized that the incidence of IRA dehiscence would be greater (1) when performed with PSP and (2) for hand-sewn anastomoses. Retrospective. Client-owned dogs at Michigan State University Veterinary Teaching Hospital. Records of dogs surviving 72 hours after IRAs between 2003 and 2013 were reviewed for age, gender, neuter status, weight, presence of PSP, preoperative albumin, IRA indication and location, anastomotic technique, suture type, postoperative dehiscence and timing, duration of hospitalization, last follow-up, and other complications. Univariate logistic regression and chi-square analysis were used to screen prognostic factors; factors with P dogs fulfilled the inclusion criteria. Dehiscence was diagnosed in 11.4% cases, 6.6% without PSP, and 21.1% with PSP (P = .01). Indication for IRA did not influence the risk of dehiscence. No association was detected between anastomotic technique and IRA dehiscence in dogs without PSP (stapled 4.2%, hand-sewn 8.1%); however, stapled anastomoses were less likely to dehisce in dogs with PSP (stapled 9.7%, hand-sewn 28.9%). Risk factors for dehiscence included PSP (P = .005) and hand-sewn technique (P = .02). Our results confirmed that PSP is a risk factor for dehiscence of IRA and suggest that patients with PSP may be a unique surgical population, in which stapling may be preferred over hand-sewn anastomoses after enterectomies. © 2017 The American College of Veterinary Surgeons.

Painting with polygons: a procedural watercolor engine.

Science.gov (United States)

DiVerdi, Stephen; Krishnaswamy, Aravind; Měch, Radomír; Ito, Daichi

2013-05-01

Existing natural media painting simulations have produced high-quality results, but have required powerful compute hardware and have been limited to screen resolutions. Digital artists would like to be able to use watercolor-like painting tools, but at print resolutions and on lower end hardware such as laptops or even slates. We present a procedural algorithm for generating watercolor-like dynamic paint behaviors in a lightweight manner. Our goal is not to exactly duplicate watercolor painting, but to create a range of dynamic behaviors that allow users to achieve a similar style of process and result, while at the same time having a unique character of its own. Our stroke representation is vector based, allowing for rendering at arbitrary resolutions, and our procedural pigment advection algorithm is fast enough to support painting on slate devices. We demonstrate our technique in a commercially available slate application used by professional artists. Finally, we present a detailed analysis of the different vector-rendering technologies available.

Effects of Robot Assisted Gait Training in Progressive Supranuclear Palsy (PSP: a preliminary report.

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Patrizio eSale

2014-04-01

Full Text Available Background and Purpose: Progressive supranuclear palsy (PSP is a rare neurodegenerative disease clinically characterized by prominent axial extrapyramidal motor symptoms with frequent falls. Over the last years the introduction of robotic technologies to recover lower limb function has been greatly employed in the rehabilitative practice. This observational trial is aimed at investigating the feasibility, the effectiveness and the efficacy of end-effector robot training in people with PSP.Method: Pilot observational trial.Participants: Five cognitively intact participants with PSP and gait disorders.Interventions: Patients were submitted to a rehabilitative program of robot-assisted walking sessions for 45 minutes, 5 times a week for 4 weeks.Main outcome measures: The spatiotemporal parameters at the beginning (T0 and at the end of treatment (T1 were recorded by a gait analysis laboratory.Results: Robot training was feasible, acceptable and safe and all participants completed the prescribed training sessions. All patients showed an improvement in the gait index (Mean velocity, Cadence, Step length and Step width (T0 versus T1.Conclusions: Robot training is a feasible and safe form of rehabilitation for cognitively intact people with PSP. This innovative approach can contribute to improve lower limb motor recovery. The focus on gait recovery is another quality that makes this research important for clinical practice. On the whole, the simplicity of treatment, the lack of side effects and the positive results in the patients support the recommendation to extend the trials of this treatment. Further investigation regarding the effectiveness of robot training in time is necessary.Trial registration: ClinicalTrials.gov NCT01668407.

Digital holographic inspection for drying processes of paint films and ink dots

Science.gov (United States)

Yokota, M.; Aoyama, F.

2017-06-01

Digital holographic techniques to investigate drying processes of both paint films and ink dot is presented. The proposed technique based on digital holographic interferometry can achieve both visualization of variations and analysis of dryness of paint films in the drying process by using phase changes between two subsequent reconstructed complex amplitudes of the reflected light from the film. To follow the drying processes, holograms are recorded at a constant time interval. Phase-shifting digital holography has been applied to analyze the dryness of commercial paints applied on the metal plate. For analysis of an ink dot having diameter of a few hundred micrometers, digital holographic microscopy is applied to evaluating the time history of dryness of ink dot in the drying process. This paper describes these holographic techniques applied to the commercially available paint and ink and presents some experimental results.

Historical origins of Petrykivsky decorative painting

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T. A. Harkava

2017-07-01

Full Text Available Petrykivsky decorative painting is a part of Ukrainian folk art. Domestic science of folk art has originated and has been developing primarily as a study of archaeological antiquities and artistic monuments of the past. Scientific papers, which comprehended the process of folk art development, began to appear in the late nineteenth century, Archaeological Congresses became the impetus for their appearance. Being a representative of the decorative painting, Petrikivsky decorative painting is rooted by its murals to Tripoli. It was created as a peasant domestic drawing. Inexhaustible diversity of local variants of Petrikivsky decorative painting, its evolutionary change, the individual characteristics of paintings of hundreds of famous Ukrainian artists do not even allow comparing it to any other European counterparts, each of which is characterized only by some individual techniques. Petrikivsky decorative painting got the significant boost in its distribution and development when it «came down» from walls to paper. Paper pictures - malyovky - were stucked to walls following the traditional rules of domestic interior’s decoration. Petrikivsky decorative painting got the official status in 1913, when E. Evenbah, by the initiative of D.I. Yavornytsky, gathered the collection of Petrikivsky decorative painting’s malyovkas and organized the exhibition in St. Petersburg. Motives of painting are rooted into the local flora and fauna and into the historical tradition. However, Petrikivsky decorative painting is not a direct reflection of natural motifs. World, created in paintings, is the product of the imagination of folk artist, it is the stylization of local flowers, fruits and birds. First names of Masters of Petrikivsky decorative painting, which appeared in historical sources, were T. Pata, N. Bilokin, I. Pavlenko. Their official recognition happened in 1930 after their participation in the first republican exhibition, which was later shown

Fiber Bragg Grating Sensor to Monitor Stress Kinetics in Drying Process of Commercial Latex Paints

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Ivo de Lourenço

2010-05-01

Full Text Available In this paper, we report a study about the application of packaged fiber Bragg gratings used as strain sensors to monitor the stress kinetics during the drying process of commercial latex paints. Three stages of drying with distinct mechanical deformation and temporal behaviors were identified for the samples, with mechanical deformation from 15 μm to 21 μm in the longitudinal film dimension on time intervals from 370 to 600 minutes. Drying time tests based on human sense technique described by the Brazilian Technical Standards NBR 9558 were also done. The results obtained shows that human sense technique has a limited perception of the drying process and that the optical measurement system proposed can be used to characterize correctly the dry-through stage of paint. The influence of solvent (water addition in the drying process was also investigated. The paint was diluted with four parts paint and one part water (80% paint, and one part paint and one part water (50% paint. It was observed that the increase of the water ratio mixed into the paint decreases both the mechanical deformation magnitude and the paint dry-through time. Contraction of 5.2 μm and 10.4 μm were measured for concentrations of 50% and 80% of paint in the mixture, respectively. For both diluted paints the dry-through time was approximately 170 minutes less than undiluted paint. The optical technique proposed in this work can contribute to the development of new standards to specify the drying time of paint coatings.

[Can solar/geomagnetic activity restrict the occurrence of some shellfish poisoning outbreaks? The example of PSP caused by Gymnodinium catenatum at the Atlantic Portuguese coast].

Science.gov (United States)

Vale, P

2013-01-01

Cyclic outbreaks of accumulation of paralytic shellfish poisoning (PSP) toxins in mussels attributed to Gymnodinium catenatum blooms displayed several of the highest inter-annual maxima coincidental with minima of the 11-year solar sunspot number (SSN) cycle. The monthly distribution of PSP was associated with low levels of the solar radio flux, a more quantitative approach than SSN for fluctuations in solar activity. A comparison between monthly distribution of PSP and other common biotoxins (okadaic acid (OA), dinophysistoxin-2 (DTX2) and amnesic shellfish poisoning (ASP) toxins) demonstrated that only PSP was significantly associated with low levels of radio flux (p < 0.01). PSP occurrence suggests a prior decline in solar activity could be required to act as a trigger, in a similar manner to a photoperiodic signal. The seasonal frequency increased towards autumn during the study period, which might be related to the progressive atmospheric cut-off of deleterious radiation associated with the seasonal change in solar declination, and might play an additional role in seasonal signal-triggering. PSP distribution was also associated with low levels of the geomagnetic index Aa. A comparison between monthly distribution of PSP and other common biotoxins, also demonstrated that only PSP was significantly associated with low levels of the Aa index (p < 0.01). In some years of SSN minima no significant PSP-outbreaks in mussels were detected. This was attributed to a steady rise in geomagnetic activity that could disrupt the triggering signal. Global distribution patterns show that hotspots for G. catenatum blooms are regions with deficient crustal magnetic anomalies. In addition to the variable magnetic field mostly of solar origin, static fields related to magnetized rocks in the crust and upper mantle might play a role in restricting worldwide geographic distribution.

The inhibitory effects of polysaccharide peptides (PsP of Ganoderma lucidum against atherosclerosis in rats with dyslipidemia

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Titin Andri Wihastuti

2017-04-01

Full Text Available BackgroundAtherosclerosis occurs as a result of low-density lipoprotein (LDL deposits oxidation. Endothelial dysfunction is an early process of atherosclerosis. Restoring endothelial lining back to normal by endothelial progenitor cells (EPCs is critical for slowing or reversing vascular disease progression. Oxidative stress from hydrogen peroxide (H2O2 is increased in dyslipidemia so that antioxidant agent is required to prevent destruction of blood vessels.ObjectivesThis study aims to report Ganoderma lucidum polysaccharide peptide (PsP effects in atherogenic process by measuring H2O2 level, IL-10 level, and EPC number in blood serum, and also intima-media thickness of aorta in dyslipidemia Wistar rat model by giving them a hypercholesterol diet (HCD.Materials and methodsThe study was an experimental in vivo post-test with control group design. Thirty-five Wistar rats (Rattus norwegicus were divided into five groups (normal diet group, HCD group, and hypercholesterol groups that received 50 mg/kg, 150 mg/kg, and 300 mg/kg bodyweight PsP.ResultsEach treatment group showed significant results for the administration of PsP using the one-way analysis of variance test (p<0.050 for the reduction of H2O2 (p = 0.003, levels of IL-10 (p = 0.027, number of EPC in the blood serum (p = 0.011, and the intima-media thickness of the aorta (p = 0.000. PsP from G. lucidum is a potent antioxidant and may prevent atherogenesis process in patients with dyslipidemia.ConclusionsThe optimum doses of PsP in this study is 300 mg/kg bodyweight. Further studies are required to determine the antioxidant effects of PsP G. lucidum and its benefits in the management of dyslipidemia.

Using anti-corrosive paints on ships

Energy Technology Data Exchange (ETDEWEB)

Smith, J

1969-02-07

Anit-corrosive paints on the outside of ship's hulls fall into 3 groups: the area below the water, the boot- topping area at the waterline, and the weatherwork including the hull and superstructure. Typical formulations of primer and paint are given for use in each section. Anti-corrosion paints must always be considered in conjunction with the kind and amount of surface preparation that can be given. The requirement for faster descaling techniques and higher standards of surface preparation has led to the introduction of automated centrifugal abrasive blasting machines for all new plates and sections. If it is not possible to remove old coatings by abrasive blasting, then the traditional method of chipping followed by wire brushing must be used. The removal of mill scale by abrasive blasting can produce a clean metal surface which is liable to rapid corrosion unless it is painted immediately. A pre-fabrication or shop primer is used which is normally applied by airless spray equipment synchronized with the sand blasting machinery.

External beam PIXE analysis of painting

International Nuclear Information System (INIS)

Pascholati, Paulo R.; Rizzutto, Marcia A.; Barbosa, Marcel D.L.; Albuquerque, Cindy

2005-01-01

The preservation and conservation of mankind cultural heritage has become an important issue worldwide. Non-destructive analytical techniques are suitable, for example, to analyze precious and unique objects of art and archaeology. Among those techniques Particle Induced X-Ray Emission (PIXE) has good advantage to identify elemental composition present in these kinds of objects. The Laboratorio de Analise de Materiais por Feixes Ionicos-LAMFI of the Institute of Physics of the University of Sao Paulo has been installed an external beam facility for PIXE analysis. This new setup is being used for the analysis of archaeological pottery artifacts, paintings and biological tissues (teeth and bones), which are not compatible with the high vacuum of the regular PIXE target chamber. In addition most art and archaeological objects are too large for the evacuated analysis chamber. Applications of this facility will be presented in the analysis of one painting of the beginning of the last century. The chemical elements identified in the painting were Ca, Ti, Cr, Cu, Fe, Zn, Pb and Ba. The PIXE measurements were done non-destructively and no visible damage was observed on the irradiated object. (author)

Familias de la proteína de superficie PspA de Streptococcus pneumoniae: Relación con serotipos y localización

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Clara Mayoral

2010-10-01

Full Text Available PspA, proteína de superficie de Streptococcus pneumoniae es un factor de virulencia, fuertemente inmunogénica y común a todos los serotipos. Aunque el gen que codifica para esta proteína presenta una marcada heterogeneidad en la región correspondiente al N-terminal, la PspA contiene epitopes conservados de manera tal que la inmunización genera protección contra neumococos pertenecientes a diversos tipos capsulares y con distintas PspA. A pesar del marcado polimorfismo del gen pspA es posible agrupar las distintas variantes en 3 familias mayoritarias. Estas propiedades las convierten en candidatas ideales para elaborar vacunas. Debido a que la mayoría de los trabajos sobre identificación de familias fueron realizados sobre serotipos frecuentes en otros países, el objetivo fue identificar las familias de PspA de aislamientos de pacientes de nuestra región y relacionarlas con los serotipos prevalentes y patologías. Se estudiaron 70 aislamientos, provenientes de niños con infecciones invasoras. Se aplicó una PCR utilizando cebadores específicos de cada familia. El 60% fueron familia 1 y 34% familia 2. En un 6% no se identificó ninguna de las familias de PspA. Los serotipos 1 y 5 presentaron familia 1 únicamente; los serotipos 14, 6B, 19F y 18C mostraron genes de ambas familias. La familia 1 se observó en 60% de las neumonías y 50% de las meningitis. La familia 2 en 33% de neumonías y 50% de meningitis. Esta información podría ser un valioso aporte para la formulación de una vacuna regional efectiva utilizando PspA recombinante como inmunógeno.

Immunomodulatory effect of APS and PSP is mediated by Ca2+-cAMP and TLR4/NF-κB signaling pathway in macrophage.

Science.gov (United States)

Wang, Zhixue; Liu, Zijing; Zhou, Lijng; Long, Tingting; Zhou, Xing; Bao, Yixi

2017-01-01

This study is to investigate the role of second messengers and TLR4/NF-κB signaling pathway in the immunomodulatory activities of Astragalus polysaccharide (APS) and Polysaccharopeptide (PSP) in macrophages. RAW 264.7 macrophage cells were treated with APS, PSP, lipopolysaccharide (LPS), or NiCl 2 . Power-spectral method was used to detect protein kinase C (PKC) and Griess reaction to detect nitric oxide (NO). ELISA was conducted to detect cyclic adenosine monophosphate (cAMP), diglycerides (DAG), inositol 1, 4, 5-triphosphate (IP3), tumor necrosis factor-α (TNF-α) and interleukin-6 (IL-6). Confocal laser scanning microscopy was performed to detect calcium level. qRT-PCR and Western blot was used to detect mRNA and protein expression of NF-κB. APS and PSP significantly increased the concentrations of intracellular second messengers (NO, cAMP, DAG, IP3, Ca 2+ ) and the activity of PKC in macrophages (pAPS and PSP (pAPS and PSP mediated immunomodulatory activities in macrophages. Copyright © 2016 Elsevier B.V. All rights reserved.

In vitro comparison between the image obtained using PSP plates and Kodak E-speed films.

Science.gov (United States)

Petel, R; Yaroslavsky, L; Kaffe, I

2014-07-01

The aim of this study was to compare the intra-oral radiographic images obtained by a PSP digital radiography system ("Orex", Israel) with that obtained using Kodak Ultra speed films in terms of image quality, radiation dosage and diagnostic value. The physical measurement of image quality was conducted with an aluminum step-wedge. Radiation dosage was measured with a dosimeter. Fog and base levels were measured by developing unexposed films and scanning unexposed PSP plates. The in vitro model included preparation and radiographic evaluation of approximal artificial lesions in premolars and molars in depths ranging from 0.25 mm to 1.00 mm. Radiographs were evaluated for the existence of a lesion and its size by 8 experienced clinicians. Relative contrast was similar in both methods. The resolving power of the digital system was lower than that of the E-speed film. As for the subjective evaluation of artificial lesions, there was no significant difference between the two methods excluding those tooth images without lesions, where the analog method was found to be more accurate. The PSP system ("Orex") provides good image quality and diagnostic information with reduced exposure when compared with E-speed film.

PORTRAIT ART IN NATIONAL PAINTING (1959-1970

Directory of Open Access Journals (Sweden)

LOZOVANU VLADIMIR

2016-12-01

Full Text Available The author of this article describes the portrait in national painting during the 1960s, years that marked political, social and cultural changes that contributed to the spiritual emancipation of the creative personality and the formation of new plastic tendencies in the field of portrait painting. He also describes the famous artists` portrait painting creations that have contributed to the spiritual emancipation of the creating personality and the establishment of new plastic tendencies in the fi eld of portrait painting. In the article, there are examples of representative portraits that are described in the context of the period when they were created. The author identifi es the methods, techniques, ideas and aspirations used in the works of plastic artists for drawing portraits that allow to form an ample conception about this phenomenon. The presented information is useful to artists, teachers and students who work in the field of visual art.

Digital cleaning and "dirt" layer visualization of an oil painting.

Science.gov (United States)

Palomero, Cherry May T; Soriano, Maricor N

2011-10-10

We demonstrate a new digital cleaning technique which uses a neural network that is trained to learn the transformation from dirty to clean segments of a painting image. The inputs and outputs of the network are pixels belonging to dirty and clean segments found in Fernando Amorsolo's Malacañang by the River. After digital cleaning we visualize the painting's discoloration by assuming it to be a transmission filter superimposed on the clean painting. Using an RGB color-to-spectrum transformation to obtain the point-per-point spectra of the clean and dirty painting images, we calculate this "dirt" filter and render it for the whole image.

49 CFR 173.173 - Paint, paint-related material, adhesives, ink and resins.

Science.gov (United States)

2010-10-01

... 49 Transportation 2 2010-10-01 2010-10-01 false Paint, paint-related material, adhesives, ink and... Than Class 1 and Class 7 § 173.173 Paint, paint-related material, adhesives, ink and resins. (a) When..., paint-related material, adhesives, ink and resins must be packaged as follows: (1) As prescribed in...

Spectroscopic analysis of XIV century wall paintings from Patriarchate of Peć Monastery, Serbia

Science.gov (United States)

Marić-Stojanović, M.; Bajuk-Bogdanović, D.; Uskoković-Marković, S.; Holclajtner-Antunović, I.

2018-02-01

The Church of the Holy Mother of God Hodegetria in Peć is decorated with wall paintings that date from the beginning of the 14th century. In terms of style they correspond to Byzantine wall paintings from the epoch of Paleologos. The painting technique and pigment pallete has been examined on micro fragments in thin cross-sections by means of optical microscopy (OM), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS) and micro- Raman spectroscopy. Use of the fresco technique and two supporting plaster layers was noted on the majority of samples, while in large blue painted areas, a combination of fresco and secco techniques was used. The SEM-EDS results showed the presence of Ca as the main component of plaster besides the traces of Si and Mg. In some samples egg white as a binder was identified. The paint film is often multilayered. Twelve pigments were identified, mainly natural earth pigments such as red ochre, yellow ochre and green earth. A mixture of pigments was used for attaining desirable optical and aesthetical impressions. As decay product only weddelite was detected in many preparatory and painted samples.

Neutron-induced autoradiography used in the investigation of modern pigments in paintings of known composition

International Nuclear Information System (INIS)

Aderhold, H.C.; Taft, W.S.

1992-01-01

Neutron-Induced Autoradiography is an effective analytical technique for mapping the location of a number of specified pigments in paintings. Most paintings which have been examined through neutron-induced autoradiography to date were painted prior to the introduction of the most common of modern pigments. By understanding die nuclear properties of these pigments, as revealed by this technique, a more informed analysis of modem paintings may result This investigation is part of an ongoing program to develop case studies for presentation to an undergraduate class at Cornell University, 'Art, Isotopes and Analysis'. We have found that this technique is a graphic and effective method of presenting nuclear reactions and radioactivity to non-specialists. Sample paintings are produced using pigments of known composition. A sequence of discreet layers, each a separate image, is documented in order to establish a reference for accurately interpreting the autoradiographs. The painting is then activated in the Cornell TRIGA reactor and a series of autoradiographs produced Gamma spectra taken before and after each film exposure gives us detailed information on which radioisotopes (and therefore, which pigments), are active. (author)

Nontypeable pneumococci can be divided into multiple cps types, including one type expressing the novel gene pspK.

Science.gov (United States)

Park, In Ho; Kim, Kyung-Hyo; Andrade, Ana Lucia; Briles, David E; McDaniel, Larry S; Nahm, Moon H

2012-01-01

Although virulence of Streptococcus pneumoniae is associated with its capsule, some pathogenic S. pneumoniae isolates lack capsules and are serologically nontypeable (NT). We obtained 64 isolates that were identified as NT "pneumococci" (i.e., bacteria satisfying the conventional definition but without the multilocus sequence typing [MLST]-based definition of S. pneumoniae) by the traditional criteria. All 64 were optochin sensitive and had lytA, and 63 had ply. Twelve isolates had cpsA, suggesting the presence of a conventional but defective capsular polysaccharide synthesis (cps) locus. The 52 cpsA-negative isolates could be divided into three null capsule clades (NCC) based on aliC (aliB-like ORF1), aliD (aliB-like ORF2), and our newly discovered gene, pspK, in their cps loci. pspK encodes a protein with a long alpha-helical region containing an LPxTG motif and a YPT motif known to bind human pIgR. There were nine isolates in NCC1 (pspK(+) but negative for aliC and aliD), 32 isolates in NCC2 (aliC(+) aliD(+) but negative for pspK), and 11 in NCC3 (aliD(+) but negative for aliC and pspK). Among 52 cpsA-negative isolates, 41 were identified as S. pneumoniae by MLST analysis. All NCC1 and most NCC2 isolates were S. pneumoniae, whereas all nine NCC3 and two NCC2 isolates were not S. pneumoniae. Several NCC1 and NCC2 isolates from multiple individuals had identical MLST and cps regions, showing that unencapsulated S. pneumoniae can be infectious among humans. Furthermore, NCC1 and NCC2 S. pneumoniae isolates could colonize mice as well as encapsulated S. pneumoniae, although S. pneumoniae with an artificially disrupted cps locus did not. Moreover, an NCC1 isolate with pspK deletion did not colonize mice, suggesting that pspK is critical for colonization. Thus, PspK may provide pneumococci a means of surviving in the nasopharynx without capsule. IMPORTANCE The presence of a capsule is critical for many pathogenic bacteria, including pneumococci. Reflecting the

Pointillist Watercolor Paintings: Exploring Optical Mixing.

Science.gov (United States)

Hamwi, Richard

2001-01-01

Focuses on the pointillist painting process offering background information about technique and how it can be used in the art classroom. Explores the appropriateness of the process for elementary through secondary school students. Includes educational objectives. (CMK)

Utility and accuracy of perceptual voice and speech distinctions in the diagnosis of Parkinson's disease, PSP and MSA-P.

Science.gov (United States)

Miller, Nick; Nath, Uma; Noble, Emma; Burn, David

2017-06-01

To determine if perceptual speech measures distinguish people with Parkinson's disease (PD), multiple system atrophy with predominant parkinsonism (MSA-P) and progressive supranuclear palsy (PSP). Speech-language therapists blind to patient characteristics employed clinical rating scales to evaluate speech/voice in 24 people with clinically diagnosed PD, 17 with PSP and 9 with MSA-P, matched for disease duration (mean 4.9 years, standard deviation 2.2). No consistent intergroup differences appeared on specific speech/voice variables. People with PD were significantly less impaired on overall speech/voice severity. Analyses by severity suggested further investigation around laryngeal, resonance and fluency changes may characterize individual groups. MSA-P and PSP compared with PD were distinguished by severity of speech/voice deterioration, but individual speech/voice parameters failed to consistently differentiate groups.

The total hemispheric emissivity of painted aluminum honeycomb at cryogenic temperatures

Energy Technology Data Exchange (ETDEWEB)

Tuttle, J.; Canavan, E.; DiPirro, M.; Li, X. [NASA Goddard Space Flight Center, Code 552 Greenbelt, Maryland, 20771 (United States); Knollenberg, P. [Northrop Grumman Aerospace Systems Redondo Beach, CA 90278 (United States)

2014-01-29

NASA uses high-emissivity surfaces on deep-space radiators and thermal radiation absorbers in test chambers. Aluminum honeycomb core material, when coated with a high-emissivity paint, provides a lightweight, mechanically robust, and relatively inexpensive black surface that retains its high emissivity down to low temperatures. At temperatures below about 100 Kelvin, this material performs much better than the paint itself. We measured the total hemispheric emissivity of various painted honeycomb configurations using an adaptation of an innovative technique developed for characterizing thin black coatings. These measurements were performed from room temperature down to 30 Kelvin. We describe the measurement technique and compare the results with predictions from a detailed thermal model of each honeycomb configuration.

Wooden Supports in 12th–16th-Century European Paintings

DEFF Research Database (Denmark)

2016-01-01

Jacqueline Marette's Connaissance des primitifs par l'étude du bois du XIIe au XVIe siècle' (1961) is a unique resource on the history of painting techniques that combines scholarship in art history, conservation, and wood science. With support from the Getty Foundation's Panel Paintings Initiati...... features critical readings of the original texts and updated references, as well as commentary from specialists with technical expertise and art-historical knowledge on northern European panel paintings from the 12th to the 16th centuries....

Visualization of pigment distributions in paintings using synchrotron K-edge imaging

International Nuclear Information System (INIS)

Krug, K.; Dik, J.; Leeuw, M.; Whitson, A. den; Tortora, J.; Coan, P.; Nemoz, C.; Bravin, A.

2006-01-01

X-ray radiography plays an important role in the study of artworks and archaeological artifacts. The internal structure of objects provides information on genesis, authenticity, painting technique, material condition and conservation history. Transmission radiography, however, does not provide information on the exact elemental composition of objects and heavy metal layers can shadow or obscure the ones including lighter elements. This paper presents the first application of synchrotron-based K-edge absorption imaging applied to paintings. Using highly monochromatic radiation, K-edge imaging is used to obtain elemental distribution images over large areas. Such elemental maps visualize the distribution of an individual pigment throughout the paint stratigraphy. This provides color information on hidden paint layers, which is of great relevance to art historians and painting conservators. The main advantage is the quick data acquisition time and the sensitivity to elements throughout the entire paint stratigraphy. The examination of a test painting is shown and further instrumental developments are discussed. (orig.)

Increased persistence of antifouling paint biocides when associated with paint particles

International Nuclear Information System (INIS)

Thomas, K.V.; McHugh, M.; Hilton, M.; Waldock, M.

2003-01-01

Release of biocides associated with paint particles into marinas may increase their persistence in the environment. - Current regulatory risk assessment procedures only assess the impact of antifouling paint biocides that are released through leaching from a painted surface. Hull cleaning activities can lead to particles of antifouling paint containing biocides to enter the environment. Comparative pseudo-first order anaerobic degradation rate constants and half-lives were determined for a selection of common antifouling paint booster biocides, their degradation products, and associated with paint particles. Anaerobic half-lives of <0.5 days were calculated for chlorothalonil, dichlofluanid, and SeaNine 211, between 1 and 3 days for DCPMU and DCPU, between 14 and 35 days for diuron and CPDU, and over 226 days for GS26575 and Irgarol 1051. Increased persistence was observed when the compounds were introduced to sediments associated with antifouling paint particles. When present as antifouling paint particles, an increased half-life of 9.9 days for SeaNine 211 and 1.4 days was calculated for dichlofluanid, no significant degradation was observed for diuron. It is suspected that this is due to much of the biocide being initially bound within the matrix of the paint particle that is slowly released through dissolution processes into the sediment pore water prior to degradation. The release of booster biocides associated with paint particles into marinas has the potential to lead to their accumulation unless activities such as hull cleaning are strictly regulated

Increased persistence of antifouling paint biocides when associated with paint particles

Energy Technology Data Exchange (ETDEWEB)

Thomas, K.V.; McHugh, M.; Hilton, M.; Waldock, M

2003-05-01

Release of biocides associated with paint particles into marinas may increase their persistence in the environment. - Current regulatory risk assessment procedures only assess the impact of antifouling paint biocides that are released through leaching from a painted surface. Hull cleaning activities can lead to particles of antifouling paint containing biocides to enter the environment. Comparative pseudo-first order anaerobic degradation rate constants and half-lives were determined for a selection of common antifouling paint booster biocides, their degradation products, and associated with paint particles. Anaerobic half-lives of <0.5 days were calculated for chlorothalonil, dichlofluanid, and SeaNine 211, between 1 and 3 days for DCPMU and DCPU, between 14 and 35 days for diuron and CPDU, and over 226 days for GS26575 and Irgarol 1051. Increased persistence was observed when the compounds were introduced to sediments associated with antifouling paint particles. When present as antifouling paint particles, an increased half-life of 9.9 days for SeaNine 211 and 1.4 days was calculated for dichlofluanid, no significant degradation was observed for diuron. It is suspected that this is due to much of the biocide being initially bound within the matrix of the paint particle that is slowly released through dissolution processes into the sediment pore water prior to degradation. The release of booster biocides associated with paint particles into marinas has the potential to lead to their accumulation unless activities such as hull cleaning are strictly regulated.

Hierarchical Micro-Nano Coatings by Painting

Science.gov (United States)

Kirveslahti, Anna; Korhonen, Tuulia; Suvanto, Mika; Pakkanen, Tapani A.

2016-03-01

In this paper, the wettability properties of coatings with hierarchical surface structures and low surface energy were studied. Hierarchically structured coatings were produced by using hydrophobic fumed silica nanoparticles and polytetrafluoroethylene (PTFE) microparticles as additives in polyester (PES) and polyvinyldifluoride (PVDF). These particles created hierarchical micro-nano structures on the paint surfaces and lowered or supported the already low surface energy of the paint. Two standard application techniques for paint application were employed and the presented coatings are suitable for mass production and use in large surface areas. By regulating the particle concentrations, it was possible to modify wettability properties gradually. Highly hydrophobic surfaces were achieved with the highest contact angle of 165∘. Dynamic contact angle measurements were carried out for a set of selected samples and low hysteresis was obtained. Produced coatings possessed long lasting durability in the air and in underwater conditions.

Automatic forensic analysis of automotive paints using optical microscopy.

Science.gov (United States)

Thoonen, Guy; Nys, Bart; Vander Haeghen, Yves; De Roy, Gilbert; Scheunders, Paul

2016-02-01

The timely identification of vehicles involved in an accident, such as a hit-and-run situation, bears great importance in forensics. To this end, procedures have been defined for analyzing car paint samples that combine techniques such as visual analysis and Fourier transform infrared spectroscopy. This work proposes a new methodology in order to automate the visual analysis using image retrieval. Specifically, color and texture information is extracted from a microscopic image of a recovered paint sample, and this information is then compared with the same features for a database of paint types, resulting in a shortlist of candidate paints. In order to demonstrate the operation of the methodology, a test database has been set up and two retrieval experiments have been performed. The first experiment quantifies the performance of the procedure for retrieving exact matches, while the second experiment emulates the real-life situation of paint samples that experience changes in color and texture over time. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

Non-invasive in situ Examination of Colour Changes of Blue Paints in Danish Golden Age Paintings

DEFF Research Database (Denmark)

Buti, David; Vila, Anna; Filtenborg, Troels Folke

A non-invasive study of some paintings containing areas of paint with a Prussian blue component has been conducted at the Statens Museum for Kunst. The in situ campaign has been carried out with a range of different spectroscopic portable techniques, provided by the MOLAB transnational access...... of the frame. Prussian blue is a hydrated iron(III) hexacyanoferrate(II) complex of variable composition depending on the manufacturing [1]. It has been reported that the method of preparation, as well as the use of white pigments or extenders to dilute the blue pigment, may be a factor contributing to its......, the current in situ campaign aimed at mapping and understanding the degradation of Prussian blue and lead white admixtures using non-invasive portable techniques. The presence of Prussian blue was detected, with the MOLAB analytical means, in all the exposed, faded areas, although the colour had turned pale...

Painting

DEFF Research Database (Denmark)

Petersen, Anne Ring

2012-01-01

and discursive battles over the essentially self-reflective question of “What is painting?” Over the last decades it has also become an intermedial laboratory in which artists experiment with developing a connective aesthetic in the interface between painting and other media. Accordingly, it is has become...

Differential PIXE for investigating the layer structure of paintings

Science.gov (United States)

Mandò, P. A.; Fedi, M. E.; Grassi, N.; Migliori, A.

2005-09-01

This paper reports an example of how the differential PIXE technique can be successfully applied to the investigation of wood or canvas paintings. The work analysed is a famous wood painting by Leonardo da Vinci, the "Madonna dei fusi" (ex-Reford version, 1501), chosen for a pilot study in a wide international project aimed at analysing Leonardo's works of art by means of non-destructive techniques. While illustrating the results obtained concerning the identification of pigments and the discrimination of the stratigraphy of layers, the merits and limits of differential PIXE in general are pointed out.

Differential PIXE for investigating the layer structure of paintings

International Nuclear Information System (INIS)

Mando, P.A.; Fedi, M.E.; Grassi, N.; Migliori, A.

2005-01-01

This paper reports an example of how the differential PIXE technique can be successfully applied to the investigation of wood or canvas paintings. The work analysed is a famous wood painting by Leonardo da Vinci, the 'Madonna dei fusi' (ex-Reford version, 1501), chosen for a pilot study in a wide international project aimed at analysing Leonardo's works of art by means of non-destructive techniques. While illustrating the results obtained concerning the identification of pigments and the discrimination of the stratigraphy of layers, the merits and limits of differential PIXE in general are pointed out

Self-Expression or Teacher Influence: The Shaw System of Finger-Painting.

Science.gov (United States)

Stankiewicz, Mary Ann

1984-01-01

Finger painting is often regarded as the epitome of free expression for children. However, a careful review of the history of Ruth Shaw's finger-painting system reveals that it was dominated by specific techniques and stylistic conventions taught without a critical understanding of art history or appreciation. (IS)

Marine atmospheres provide a tough test for protective paint systems

Energy Technology Data Exchange (ETDEWEB)

Steptoe, G.G.C.

1980-04-01

Protective paints based on chlorinated rubber (CR) offer good resistance to salt-laden atmospheres and extreme climatic conditions, possess low moisture and oxygen permeability, and are resistant to a variety of chemicals, which allows them to counter the acidic and alkaline conditions tha arise from the corrosion of steel in salt water and from cathodic protection. Airless spray techniques allow CR paints to be applied much faster in thick coatings to large surface areas. CR paints can be formulated to produce a dry film thickness of 80-100 jm in one application. One study concluded that the extra expense for good surface preparation and high-performance paint can be regained in 2-4 yr as a result of lower maintenance costs. CR paints can be used successfully with cathodic protection; however, their tolerance to overprotection is less than that of some alternative systems; CR paints are considered to be suitable for use up to a maximum of -0.95 v. The numerous applications of CR paint include large crude carriers, offshore oil structures, oil terminals (e.g., the Flotta terminal in the Orkneys), and storage tanks.

Digital radiographic techniques in the analysis of paintings

International Nuclear Information System (INIS)

James, A.E. Jr.; Gibbs, S.J.; James, A.E. III; Pickens, D.R.; Sloan, M.; Price, R.R.; Erickson, J.J.

1985-01-01

In this chapter the authors use the term digital radiography to mean any method of radiographic image production in which the silver halide-based film is replaced by an electronic sensor for production of an image. There are essentially three types of digital radiographic systems available at present, but others will be developed. These differ primarily in the method of image production and the rapidity with which images can be produced. The three methods discussed are digital fluoroscopy, scanned projection radiography, and the scanned point source radiography. Each has certain characteristics which, if properly utilized, will allow improved x-ray analysis of paintings

Study of mural paintings by Fulvio Pennacchi in São Paulo City by mineralogical techniques

Directory of Open Access Journals (Sweden)

Eliane A. Del Lama

2009-03-01

Full Text Available The present research deals with two mural paintings made in 1947 with the fresco technique by Fulvio Pennacchi in the Catholic Chapel of the Hospital das Clínicas (São Paulo City, Brazil, namely the Virgin Annunciation and the Supper at Emmaus. This study regards the materials and painting techniques used by the artist, based on historical research,on in situ observations and laboratory analytical techniques (stereomicroscopy,scanning electron microscopy with an energy dispersive spectrometer, X-ray diffractometry, electron microprobe, images obtained with UV-light, aiming to improve the methods of characterization of objects of our cultural heritage, and to enhance its preservation accordingly. The results lead to the identification of the plaster components and of distinct layers in the frescoes, besides further information on grain size, impurities and textures, composition of pigments, and features of deterioration, such as efflorescences. The degree of degradation of the murals painting was assessed by this way. Our data suggest that a single layer of plaster was used by Pennacchi, as a common mortar with fine- and medium-grained aggregates. Differences in texture were obtained by adding gypsum to the plaster.A presente pesquisa trata de duas pinturas murais feitas em 1947 por Fulvio Pennacchi com a técnica do afresco na Capela Católica do Hospital das Clínicas (São Paulo, Brasil, intituladas Anunciação da Virgem e Ceia de Emaús. Este estudo considera os materiais e as técnicas de pintura usadas pelo artista, baseado na pesquisa histórica, observações in situ e técnicas analíticas de laboratório (estereomicroscopia, microscopia eletrônica de varredura com detector de espectro de energia dispersiva, difração de raios X, microssonda eletrônica, imagens obtidas com luz ultravioleta, visando aperfeiçoar os métodos de caracterização de objetos do nosso patrimônio cultural, e otimizar sua preservação adequadamente. Os

Optimization of Robotic Spray Painting process Parameters using Taguchi Method

Science.gov (United States)

Chidhambara, K. V.; Latha Shankar, B.; Vijaykumar

2018-02-01

Automated spray painting process is gaining interest in industry and research recently due to extensive application of spray painting in automobile industries. Automating spray painting process has advantages of improved quality, productivity, reduced labor, clean environment and particularly cost effectiveness. This study investigates the performance characteristics of an industrial robot Fanuc 250ib for an automated painting process using statistical tool Taguchi’s Design of Experiment technique. The experiment is designed using Taguchi’s L25 orthogonal array by considering three factors and five levels for each factor. The objective of this work is to explore the major control parameters and to optimize the same for the improved quality of the paint coating measured in terms of Dry Film thickness(DFT), which also results in reduced rejection. Further Analysis of Variance (ANOVA) is performed to know the influence of individual factors on DFT. It is observed that shaping air and paint flow are the most influencing parameters. Multiple regression model is formulated for estimating predicted values of DFT. Confirmation test is then conducted and comparison results show that error is within acceptable level.

Radiocarbon dating of ancient rock paintings

Energy Technology Data Exchange (ETDEWEB)

Ilger, W.A.; Hyman, M.; Rowe, M.W. [Texas A and M Univ., College Station, TX (United States). Dept. of Chemistry; Southon, J. [Lawrence Livermore National Lab., CA (United States)

1995-06-20

This report presents progress made on a technique for {sup 14}C dating pictographs. A low-temperature oxygen plasma is used coupled with high-vacuum technologies to selectively remove C-containing material in the paints without contamination from inorganic carbon from rock substrates or accretions.

Radiocarbon dating of ancient rock paintings

International Nuclear Information System (INIS)

Ilger, W.A.; Hyman, M.; Rowe, M.W.

1995-01-01

This report presents progress made on a technique for 14 C dating pictographs. A low-temperature oxygen plasma is used coupled with high-vacuum technologies to selectively remove C-containing material in the paints without contamination from inorganic carbon from rock substrates or accretions

Limewashed mural paintings as seen by VIS-IR reflectography

Science.gov (United States)

Fontana, R.; Striova, J.; Barucci, M.; Pampaloni, E.; Raffaelli, M.; Pezzati, L.; Mariotti, P.

2015-06-01

Near-Infrared (NIR) reflectography is a well-established technique for painting diagnostics, offering a fundamental contribution to the conservation of paintings. Since the '80s it has been routinely applied to study the execution technique of the author, as well as the presence of pentimenti, retouches, integrations or underdrawing. In the last decades IR reflectography has been extended to the visible (VIS) spectral range, providing information about the pigment composition. Up to now the multispectral analysis is still applied at an experimental level, as the processing of the image set is not straightforward. Rarely multispectral VIS-IR application has been applied to frescos, probably due to the lack, in most cases, of a scattering background. In this work we present the results provided by a multispectral scanning device based on single sensor acquisition, working in the 380-2500 nm spectral range, that is a laboratory prototype specifically built for research-grade imaging. The technique have been applied on a mock up simulating a mural painting substrate where an underdrawing, made of either carbon or iron-gall ink, was covered by different surface layers of limewash, the so-called scialbo.

Egyptian Tomb Painting.

Science.gov (United States)

Schroeder, Liesa

1999-01-01

Provides an activity where sixth-grade students replicated the Egyptian art form of tomb painting. Explains that the students researched information about Egyptian culture and history in order to familiarize themselves with Egyptian wall-painting style. Discusses the process of creating tomb paintings in detail. (CMK)

Analytical Characterization of Rococo Paintings in Egypt: Preliminary Results from El-Gawhara Palace at Cairo

Directory of Open Access Journals (Sweden)

Fatma REFAAT

2012-12-01

Full Text Available El-Gawhara palace (1813–1814 AD is situated south of the Mosque of Muhammad Ali in the Cairo Citadel. This palace is an important example of the best early 19th century rococo decorations in Egypt. The present study reports some of the results obtained from the application of different analytical techniques to characterize some rococo paintings at El-Gawhara palace at Cairo, Egypt. The characterization of the studied paintings was carried out by means of optical microscopy (OM, scanning electron microscopy equipped with an energy dispersive X-ray detector (EDS and Fourier transform infrared spectroscopy (FT−IR. The obtained results allowed the identification of the chemical composition, structure and the painting technique employed in these paintings. This methodology reveals some useful information on some rococo paintings dating back to the 19th century in Egypt.

Noise resistance applied to the study of zinc rich paints

International Nuclear Information System (INIS)

Espada Recarey, L.; Sanchez Bermudez, A.; Urrejola Madrinan, S.; Bouzada Alvela, F.

2001-01-01

Electrochemical Noise has been one of the more useful analysis methods to the study the corrosion processes due to the fact that it is simple and cheap. The objective of this work is to check the efficiency of this technique when it is applied to the study of Rich Zinc Paints and specifically the Noise Resistance parameter which is very efficiency to study metal-electrolyte systems. Then this technique was applied to Rich Zinc Paints systems of which we have already information by means of electrochemical impedance spectroscopy. The outcomes of this paper show the efficiency of applying Noise Resistance technique to explain the behavior of this kind of systems. (Author) 18 refs

Surface analysis characterisation of gum binders used in modern watercolour paints

Science.gov (United States)

Sano, Naoko; Cumpson, Peter J.

2016-02-01

Conducting this study has demonstrated that not only SEM-EDX but also XPS can be an efficient tool for characterising watercolour paint surfaces. We find that surface effects are mediated by water. Once the powdered components in the watercolour come into contact with water they dramatically transform their chemical structures at the surface and show the presence of pigment components with a random dispersion within the gum layer. Hence the topmost surface of the paint is confirmed as being composed of the gum binder components. This result is difficult to confirm using just one analytical technique (either XPS or SEM-EDX). In addition, peak fitting of C1s XPS spectra suggests that the gum binder in the commercial watercolour paints is probably gum arabic (by comparison with the reference materials). This identification is not conclusive, but the combination techniques of XPS and SEM shows the surface structure with material distribution of the gum binder and the other ingredients of the watercolour paints. Therefore as a unique technique, XPS combined with SEM-EDX may prove a useful method in the study of surface structure for not only watercolour objects but also other art objects; which may in future help in the conservation for art.

Non-invasive in-situ investigations versus micro-sampling: a comparative study on a Renoirs painting

International Nuclear Information System (INIS)

Miliani, C.; Sgamellotti, A.; Universita degli Studi di Perugia . Centro di Eccellenza SMAArt; Scientific Methodologies applied to Archaeology and Art)

2007-01-01

In this paper, a multi-technique in-situ non-invasive approach has been followed for the study of the materials used for a painting by Pierre-Auguste Renoir, ''A woman at her toilette''. The study was carried out using five portable spectroscopic techniques, namely X-ray fluorescence, mid-infrared reflectance spectroscopy, near infrared reflectance spectroscopy, and UV-Vis spectroscopy in absorption and emission. The painting was selected as a case study because it was examined in advance of the current investigation using conventional micro-sampling techniques. This provided the opportunity to evaluate potential and limitations of the non-invasive approach to the complex case of the modern painting. (orig.)

Color alteration of the paint used for iris painting in ocular prostheses

Directory of Open Access Journals (Sweden)

Aline Úrsula Rocha Fernandes

2009-12-01

Full Text Available The purpose of this study was to assess color alteration of the paints used for iris painting in artificial eyes. Five disks of heat cured acrylic resin were confectioned by microwave energy for each paint analyzed, in a total of 40 specimens. Each specimen consisted of a colorless acrylic resin disk and another of equal size, of scleral white colored acrylic resin, with the painting interposed between the two disks. The specimens were submitted to an accelerated aging process in a chamber under ultraviolet radiation for 1,008 hours. To assess color variation, a reflective spectrophotometer was used. The results were statistically analyzed by ANOVA and the Tukey test (p < 0.05. All the paints underwent chromatic alteration. The oil paint presented the highest resistance to accelerated aging.

Oil painting on tinplate by Francisco José Resende

Directory of Open Access Journals (Sweden)

Ana Rita Veiga

2010-11-01

Full Text Available Cet article se concentre sur l'étude des techniques d'exécution, des matériaux et de l'état de conservation de trois peintures à l'huile sur fer-blanc (acier couvert d'étain du peintre portugais Francisco José Resende (1825 – 1893. Bien que le choix de peindre sur un support métallique n'était pas commun au XIXème siècle, cet auteur a exécuté au long de sa vie différentes œuvres sur ce substrat. Dans ces recherches, apparaissent les résultats comparatifs de la technique d'exécution de Francisco Resende et des matériaux présents dans les couches picturales et dans le support des trois œuvres faisant l'objet de l'étude. Bien qu'elles aient été exécutées à des dates similaires, on remarque des problèmes de conservation distincts - notamment les détachements, les cloques et la corrosion -, qui sont décrits et liés aux matériaux constituants des peintures.This article focuses on the study of execution techniques, material composition and condition of three oil paintings on tinplate – a thin sheet of steel coated with tin - by the Portuguese painter Francisco José Resende (1825-1893. Although the choice to paint on a metallic support was not very common in the nineteenth century, the painter executed several works on this support. The comparative results focus on Francisco Resende’s technique of execution, the materials used in the paint layers and on the support of the three works which are being studied. Although executed in the same period, they show different conservation problems - namely delamination and blistering of the paint layers, and also corrosion of the support.

On the study of oil paint adhesion on optically transparent glass: Conservation of reverse paintings on glass

International Nuclear Information System (INIS)

Bayle, M.; Waugh, D.G.; Colston, B.J.; Lawrence, J.

2015-01-01

Highlights: • Adhesion characteristics analysed with respect to reverse paintings on glass. • Physical properties of surfaces and pigments found to affect cohesion and adhesion. • Environmental effects on pigment adhesion to glass have been documented. • Vermillion pigment hardest compared to other pigments, especially with adhesives. • Wettability used to assess adhesion properties relating to reverse paintings on glass. - Abstract: Reverse painting on glass is a technique which consists of applying a cold paint layer on the reverse-side of glass. The main challenge facing these artworks is the fragile adhesion of the pictorial layer – a simple movement can modify the appearance of the painting. This paper details a study into the adhesion parameters of pigments on glass and the comparison between different pigments. The relationships between the binder (linseed oil) with pigments and the glass with or without the use of an adhesive are studied. Physical analyses by surface characterisation have been carried out to better understand the influence of the pigment. The use of a sessile drop device, optical microscopy, scanning electron microscopy (SEM), a surface 3D profiler and a pencil hardness scratch tester were necessary to establish a comparison of the pictorial layer adhesion. A comparison of the effect of two adhesives, namely ox gall and gum arabic, has shown that the adhesion is not only linked to the physical parameters but that possible chemical reactions can influence the results. Finally, a treatment based on humidity-extreme storage has shown the weakness of some pictorial layers.

On the study of oil paint adhesion on optically transparent glass: Conservation of reverse paintings on glass

Energy Technology Data Exchange (ETDEWEB)

Bayle, M. [Historic and Ancient Materials Group, School of Chemistry, University of Lincoln, Brayford Pool, Lincoln LN6 7TS (United Kingdom); Waugh, D.G., E-mail: d.waugh@chester.ac.uk [Laser Engineering and Manufacturing Research Centre, Faculty of Science and Engineering, University of Chester, Thornton Science Park, Ince, Chester CH2 4NU (United Kingdom); Colston, B.J. [Historic and Ancient Materials Group, School of Chemistry, University of Lincoln, Brayford Pool, Lincoln LN6 7TS (United Kingdom); Lawrence, J. [Laser Engineering and Manufacturing Research Centre, Faculty of Science and Engineering, University of Chester, Thornton Science Park, Ince, Chester CH2 4NU (United Kingdom)

2015-12-01

Highlights: • Adhesion characteristics analysed with respect to reverse paintings on glass. • Physical properties of surfaces and pigments found to affect cohesion and adhesion. • Environmental effects on pigment adhesion to glass have been documented. • Vermillion pigment hardest compared to other pigments, especially with adhesives. • Wettability used to assess adhesion properties relating to reverse paintings on glass. - Abstract: Reverse painting on glass is a technique which consists of applying a cold paint layer on the reverse-side of glass. The main challenge facing these artworks is the fragile adhesion of the pictorial layer – a simple movement can modify the appearance of the painting. This paper details a study into the adhesion parameters of pigments on glass and the comparison between different pigments. The relationships between the binder (linseed oil) with pigments and the glass with or without the use of an adhesive are studied. Physical analyses by surface characterisation have been carried out to better understand the influence of the pigment. The use of a sessile drop device, optical microscopy, scanning electron microscopy (SEM), a surface 3D profiler and a pencil hardness scratch tester were necessary to establish a comparison of the pictorial layer adhesion. A comparison of the effect of two adhesives, namely ox gall and gum arabic, has shown that the adhesion is not only linked to the physical parameters but that possible chemical reactions can influence the results. Finally, a treatment based on humidity-extreme storage has shown the weakness of some pictorial layers.

Between Formula and Freestyle. Nicolai Abildgaard and Eighteenth-Century Painting Technique

DEFF Research Database (Denmark)

Filtenborg, Troels; Vila Espuna, Anna

As the most important Danish history painter, Nicolai Abildgaard (1743-1809) worked in a century that saw marked shifts in the styles of painting, from the late Baroque via Rococo to Neoclassicism, as well as the emergence of art academies throughout Europe as the prevalent factor in the training...

Oil-based paint poisoning

Science.gov (United States)

Paint - oil-based - poisoning ... Hydrocarbons are the primary poisonous ingredient in oil paints. Some oil paints have heavy metals such as lead, mercury, cobalt, and barium added as pigment. These heavy metals can cause additional ...

Process Waste Assessment - Paint Shop

International Nuclear Information System (INIS)

Phillips, N.M.

1993-06-01

This Process Waste Assessment was conducted to evaluate hazardous wastes generated in the Paint Shop, Building 913, Room 130. Special attention is given to waste streams generated by the spray painting process because it requires a number of steps for preparing, priming, and painting an object. Also, the spray paint booth covers the largest area in R-130. The largest and most costly waste stream to dispose of is open-quote Paint Shop wasteclose quotes -- a combination of paint cans, rags, sticks, filters, and paper containers. These items are compacted in 55-gallon drums and disposed of as solid hazardous waste. Recommendations are made for minimizing waste in the Paint Shop. Paint Shop personnel are very aware of the need to minimize hazardous wastes and are continuously looking for opportunities to do so

Pigments identification in Havana Colonial wall painting by portable XRF System

International Nuclear Information System (INIS)

Nazca, J.; Mendoza, A.; Rodriguez, A.; Rodriguez, T.

2001-01-01

The Havana City historical center is being recuperated in the las years. Numerous are the colonial houses with values typical wall painting as internal decoration that need to be investigated and restored. The pigment identification is essential to have knowledge about pictorial technique and to help and monitor the restoration process. The identification of inorganic pigments in the Havana colonial wall painting has been not almost studied. The opportunity to have a new Portable XRF system in the Archaeometry laboratory of the Conservation and Restoration Gabinet of Havana Historitian Office allows to investigate the wall painting, samples that because of its more of this nature it would be impossible to move to the laboratory for non destructive analysis. The most of the pigment are made of inorganic elements and they can be identified property by XRF technique. All complete archaeometric investigation has to use several technique and to work in a multidisciplinary research team to give a fundamental answer about the past, The suitable techniques selection to employ depends of the art Historitian and archaeologist's questions. The pictorial technique are traditionally investigated using stratigraphical information obtained by Optical Microscopy and organic compound determination by Gas Chromatography. The global analysis of the results from the different employed techniques and the discussion from the restaurateur point of view is presented

PIXE analysis of historical paintings: Is the gain worth the risk?

Energy Technology Data Exchange (ETDEWEB)

Calligaro, T. [Centre de recherche et de restauration des musées de France, C2RMF, Palais du Louvre – Porte des Lions, 14 Quai François Mitterrand, 75001 Paris (France); PSL Research University, Chimie ParisTech – CNRS, Institut de Recherche Chimie Paris, UMR8247, 75005 Paris (France); Fédération de recherche NewAGLAE, FR3506 CNRS – Ministère de la Culture – IRCP, Palais du Louvre, 75001 Paris (France); Gonzalez, V. [Centre de recherche et de restauration des musées de France, C2RMF, Palais du Louvre – Porte des Lions, 14 Quai François Mitterrand, 75001 Paris (France); PSL Research University, Chimie ParisTech – CNRS, Institut de Recherche Chimie Paris, UMR8247, 75005 Paris (France); Pichon, L. [Centre de recherche et de restauration des musées de France, C2RMF, Palais du Louvre – Porte des Lions, 14 Quai François Mitterrand, 75001 Paris (France); Fédération de recherche NewAGLAE, FR3506 CNRS – Ministère de la Culture – IRCP, Palais du Louvre, 75001 Paris (France)

2015-11-15

The PIXE analysis of easel paintings constitutes a challenging task. Despite recognized merits and a few emblematic applications, PIXE has never been routinely applied to these fragile, complex and precious targets. The present work discusses the place of PIXE in the study of easel paintings and opens up perspectives for a more systematic usage of this analytical technique. Progress achieved since decades in the implementation of PIXE to study such fragile cultural heritage artefacts is reviewed, notably at the LABEC laboratory in Italy and at the AGLAE facility of the C2RMF in France. Two specific techniques developed for paintings are detailed and exemplified on Renaissance painting masterpieces: differential PIXE for paint layers depth profiling and multi-scale elemental mapping for the imaging of pigment distribution. Beam-induced damage, a major concern, notably depends on the employed beam fluence in particle/cm{sup 2} or μC/cm{sup 2}. After recalling previous works on damage induced in chemical products comparable to pigments, we present the behaviour under different fluences of protons of a few MeV (1–300 μC/cm{sup 2}) of targets having high resemblance to historical easel paintings: pellets of specially synthesized lead white pigments, layers of lead white mixed with linseed oil and areas containing lead white of two 19th century paintworks. The results shed new lights on the behaviour of paintworks under the beam and pave the way to strategies for damage mitigation. In particular, the lowering of PIXE performance induced by the decrease of the beam fluence sets a trade-off between risk of damage and gained information which also impacts the PIXE scanning protocol for paintings. As an illustration of an adequate adjustment of this balance, we report the exploratory application of PIXE mapping to a large area of a 19th century easel painting without damage. The recorded elemental maps are compared to elemental maps collected on the same area using

PIXE analysis of historical paintings: Is the gain worth the risk?

International Nuclear Information System (INIS)

Calligaro, T.; Gonzalez, V.; Pichon, L.

2015-01-01

The PIXE analysis of easel paintings constitutes a challenging task. Despite recognized merits and a few emblematic applications, PIXE has never been routinely applied to these fragile, complex and precious targets. The present work discusses the place of PIXE in the study of easel paintings and opens up perspectives for a more systematic usage of this analytical technique. Progress achieved since decades in the implementation of PIXE to study such fragile cultural heritage artefacts is reviewed, notably at the LABEC laboratory in Italy and at the AGLAE facility of the C2RMF in France. Two specific techniques developed for paintings are detailed and exemplified on Renaissance painting masterpieces: differential PIXE for paint layers depth profiling and multi-scale elemental mapping for the imaging of pigment distribution. Beam-induced damage, a major concern, notably depends on the employed beam fluence in particle/cm"2 or μC/cm"2. After recalling previous works on damage induced in chemical products comparable to pigments, we present the behaviour under different fluences of protons of a few MeV (1–300 μC/cm"2) of targets having high resemblance to historical easel paintings: pellets of specially synthesized lead white pigments, layers of lead white mixed with linseed oil and areas containing lead white of two 19th century paintworks. The results shed new lights on the behaviour of paintworks under the beam and pave the way to strategies for damage mitigation. In particular, the lowering of PIXE performance induced by the decrease of the beam fluence sets a trade-off between risk of damage and gained information which also impacts the PIXE scanning protocol for paintings. As an illustration of an adequate adjustment of this balance, we report the exploratory application of PIXE mapping to a large area of a 19th century easel painting without damage. The recorded elemental maps are compared to elemental maps collected on the same area using laboratory

PIXE analysis of historical paintings: Is the gain worth the risk?

Science.gov (United States)

Calligaro, T.; Gonzalez, V.; Pichon, L.

2015-11-01

The PIXE analysis of easel paintings constitutes a challenging task. Despite recognized merits and a few emblematic applications, PIXE has never been routinely applied to these fragile, complex and precious targets. The present work discusses the place of PIXE in the study of easel paintings and opens up perspectives for a more systematic usage of this analytical technique. Progress achieved since decades in the implementation of PIXE to study such fragile cultural heritage artefacts is reviewed, notably at the LABEC laboratory in Italy and at the AGLAE facility of the C2RMF in France. Two specific techniques developed for paintings are detailed and exemplified on Renaissance painting masterpieces: differential PIXE for paint layers depth profiling and multi-scale elemental mapping for the imaging of pigment distribution. Beam-induced damage, a major concern, notably depends on the employed beam fluence in particle/cm2 or μC/cm2. After recalling previous works on damage induced in chemical products comparable to pigments, we present the behaviour under different fluences of protons of a few MeV (1-300 μC/cm2) of targets having high resemblance to historical easel paintings: pellets of specially synthesized lead white pigments, layers of lead white mixed with linseed oil and areas containing lead white of two 19th century paintworks. The results shed new lights on the behaviour of paintworks under the beam and pave the way to strategies for damage mitigation. In particular, the lowering of PIXE performance induced by the decrease of the beam fluence sets a trade-off between risk of damage and gained information which also impacts the PIXE scanning protocol for paintings. As an illustration of an adequate adjustment of this balance, we report the exploratory application of PIXE mapping to a large area of a 19th century easel painting without damage. The recorded elemental maps are compared to elemental maps collected on the same area using laboratory-based scanning

Immunomodulatory effects of herbal formula of astragalus polysaccharide (APS) and polysaccharopeptide (PSP) in mice with lung cancer.

Science.gov (United States)

Zhou, Xing; Liu, Zijing; Long, Tingting; Zhou, Lijng; Bao, Yixi

2018-01-01

This study is to investigate the immunomodulatory effects of the herbal formula of astragalus polysaccharide (APS) and polysaccharopeptide (PSP) in mouse models of immunosuppression and lung cancer. Immune parameters were recorded for these model mice. Peripheral white blood cells (WBC) were detected with the automatic blood cell analyzer. Spleen and thymus indices, and tumor inhibition ratio were obtained. Percentage of peripheral blood CD4 + and CD8 + T lymphocytes were detected by flow cytometry. Serum levels of Th1 (IL-2, TNF, and IFN-γ), Th2 (IL-4, IL-6, and IL-10), and Th17 (IL-17A) were detected with the BD cytometric bead array (CBA) mouseTh1/Th2/Th17 cytokine kit. Compared with the NS group, the PSP and APS herbal formula significantly improved the WBC, thymus index, spleen index, CD4 + /CD8 + ratio, TNF, IFN-γ, IL-2, andIL-17Ainimmunosuppressivemice and lung cancer mice (PAPS herbal formula group (PAPS herbal formula group induced comparable tumor inhibiting effect with the AMD group (23.3% and 24.1%, respectively). The PSP+APS herbal formula have immunomodulatory effects and anti-tumor activity in mice with of lung cancer. Copyright © 2017 Elsevier B.V. All rights reserved.

[18F]FDDNP PET in Tauopathies: Correlation to post mortem Pathology in a Case of Progressive Supranuclear Palsy (PSP)

Science.gov (United States)

Villegas, Brendon Josef

This investigation of [18F]FDDNP was conducted in an effort to confirm the presence of disease in a patient with Progressive Supranuclear Palsy (PSP) and to correlate the ante mortem PET scan results to the post mortem pathology. The immunohistochemical and immunofluorescent staining of Paired Helical Filamentous (PHF) tau (AT8) and Amyloid Beta (6F/3D) misfolded proteins demonstrated a widespread deposition in the cortical and subcortical nuclei, the white matter, cerebellar white matter and the medulla oblongata. The in vitro autoradiography demonstrated a neocortical signal comprised of well-delineated amyloid beta in the nucleated layers I/II and hyperphosphorylated tau in the deeper layers III through VI. The autoradiography was well correlated with the immunohistochemical staining in adjacent tissue slides. The binding of the parametric [ 18F]FDDNP distribution volume ratio (DVR) correlated well (Spearman's rho = 0.962, p = .004) with the deposition of tau but not with the presence of amyloid beta (Spearman's rho = -0.829, p = .041). The [ 18F]FDDNP DVR signal appears to be primarily due to the large amount of bound hyperphosphorylated tau (p-tau) and the amyloid beta negligibly contributes to the total signal. Unlabeled FDDNP was shown to bind to tau in the form of globose tangles in the rostral ventromedial medulla as confirmed with both Thioflavin S and PHF-tau Immunofluorescence. The binding of [18F]FDDNP to the human neuroanatomy was investigated in two cohorts of distinct tauopathies and compared to the binding in two tau-negative cohorts against control patients. A cohort of PSP patients (n = 12) with a mean age of 63.8 years and a cohort of Chronic Traumatic Encephalopathy (CTE) patients (n = 14) with a mean age of 58.1 years are both characterized by the presence of various degrees of tau pathology in their brains. The cohort of Parkinson's Disease (PD) patients (n = 16) with a mean age of 63.2 years is initially characterized by clinical symptoms

Atomic Oxygen Treatment as a Method of Recovering Smoke Damaged Paintings. Revised

Science.gov (United States)

Rutledge, Sharon K.; Banks, Bruce A.; Forkapa, Mark; Stueber, Thomas; Sechkar, Edward; Malinowski, Kevin

1999-01-01

A noncontact technique is described that uses atomic oxygen, generated under low pressure in the presence of nitrogen, to remove soot and charred varnish from the surface of a painting. The process, which involves surface oxidation, permits control of the amount of surface material removed. The effectiveness of the process was evaluated by reflectance measurements from selected areas made during the removal of soot from acrylic gesso, ink on paper, and varnished oil paint substrates. For the latter substrate, treatment also involved the removal of damaged varnish and paint binder from the surface.

Finanční analýza PSP enegineering, a. s.

OpenAIRE

Červinková, Hana

2007-01-01

The purpose of this work is to carry out financial analysis of a manufacturing company which is aimed at discovering of its total financial health, present progress and is also trying to evaluate future perspective. In the methodological part there are selected methods and procedures of financial analysis characterized which are applied also in the practical part. This part is composed of several sections. In the introduction the company PSP engineering a.s. is introduced, also its focus and ...

Selective paint coatings for coloured solar absorbers: Polyurethane thickness insensitive spectrally selective (TISS) paints (Part II)

Energy Technology Data Exchange (ETDEWEB)

Orel, B.; Spreizer, H.; Surca Vuk, A.; Fir, M. [National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana (Slovenia); Merlini, D.; Vodlan, M. [Color d.d., Cesta komandanta Staneta 4, SI-1230 Medvode (Slovenia); Koehl, M. [Fraunhofer-Institute for Solar Energy Systems ISE, Heidenhofstr. 2, D-79110 Freiburg (Germany)

2007-01-23

Red, green and blue paints were prepared for use as thickness insensitive spectrally selective (TISS) paint coatings for solar facade absorbers. The paints were composed of a polyurethane resin binder in which various pigments were incorporated in such a way that they formed stable paint dispersions, satisfying stability criteria for facade coatings. A low emittance of the paints was achieved by using low-emittance aluminium flake pigments combined with iron oxide (red coloured paints). Black pigment was added to adjust solar absorptance. Blue and green paints were made by the addition of coloured aluminium flake pigment and the solar absorptance was also adjusted by the addition of black pigment. Efficiency for photo-thermal conversion of solar radiation was assessed by evaluation of the corresponding performance criteria, which enabled the selection of paints whose performance criteria values were higher than 0 (spectrally non-selective black coating). The results confirmed that blue and green paints and to minor extent red ones, combined selectivity with colour. The morphology of the paints was assessed, revealing that the colours originated from the deposition of finely dispersed colour and/or black pigment on the surface of the aluminium flakes during paint preparation. (author)

The influence of paint dispersion parameters on the spectral selectivity of black-pigmented coatings

Energy Technology Data Exchange (ETDEWEB)

Gunde, M.K.; Orel, Z.C. [National Institute of Chemistry, Ljubljana (Slovenia); Hutchins, M.G. [Oxford Brookes University, Oxford (United Kingdom). School of Engineering

2003-10-31

The optical properties of variously prepared black-pigmented solar absorbing paints were calculated in terms of their effective absorption and scattering abilities. The phenomenological two-parameter Kubelka-Munk effective medium theory was applied. Paints with the same composition were prepared for different degrees of pigment dispersion and characterized by the average size of pigment agglomerates present in the pigment/vehicle system. Prepared paints were applied to aluminium foil in two ways, by coil coating and by spraying. The size of coarse pigment particles and the paint application technique influence the spectral selectivity and thus determine the final performance of spectrally selective surfaces. (author)

Painting rusted steel: The role of aluminum phosphosilicate

International Nuclear Information System (INIS)

Roselli, S.N.; Amo, B. del; Carbonari, R.O.; Di Sarli, A.R.; Romagnoli, R.

2013-01-01

Highlights: •Aluminum phosphosilicate is an acid pigment which could act as mild phosphating agent. •Aluminum phosphosilicate can phosphatize iron oxides on rusted surfaces. •Aluminum phosphosilicate is compatible with acid binders. •Aluminum phosphosilicate could replace chromate in complete painting schemes. •Aluminum phosphosilicate primers improve paints adhesion on rusted surfaces. -- Abstract: Surface preparation is a key factor for the adequate performance of a paint system. The aim of this investigation is to employ a wash-primer to accomplish the chemical conversion of rusted surface when current cleaning operations are difficult to carry out. The active component of the wash-primer was aluminum phosphosilicate whose electrochemical behavior and the composition of the generated protective layer, both, were studied by electrochemical techniques and scanning electron microscopy (SEM), respectively. Primed rusted steel panels were coated with an alkyd system to perform accelerated tests in the salt spray chamber and electrochemical impedance measurements (EIS). These tests were conducted in parallel with a chromate wash primer and the same alkyd system. Results showed that the wash-primer containing aluminum phosphosilicate could be used satisfactorily to paint rusted steel exhibiting a similar performance to the chromate primer

Virtual hairy brush for digital painting and calligraphy

Institute of Scientific and Technical Information of China (English)

XU Songhua; Lau Francis C. M.; XU Congfu; PAN Yunhe

2005-01-01

The design of user friendly and expressive virtual brush systems for interactive digital painting and calligraphy has attracted a lot of attention and effort in both computer graphics and human-computer interaction circles for a long time. Providing a digital environment for paper-less artwork creation is not only challenging in terms of algorithmic design, but also promising for its potential market values. This paper proposes a novel algorithmic framework for interactive digital painting and calligraphy based a novel virtual hairy brush model. The algorithms in the kernel of our simulation framework are built upon solid modeling techniques. Implementing the algorithms, we have developed a virtual hairy brush prototype system with which end users can interactively produce high-quality digital paintings and calligraphic artwork. (The latest progress of our virtual brush project is reported at the website "http://www.cs.hku.hk/~songhua/e-brush/".)

2D imaging and 3D sensing data acquisition and mutual registration for painting conservation

Science.gov (United States)

Fontana, Raffaella; Gambino, Maria Chiara; Greco, Marinella; Marras, Luciano; Pampaloni, Enrico M.; Pelagotti, Anna; Pezzati, Luca; Poggi, Pasquale

2005-01-01

We describe the application of 2D and 3D data acquisition and mutual registration to the conservation of paintings. RGB color image acquisition, IR and UV fluorescence imaging, together with the more recent hyperspectral imaging (32 bands) are among the most useful techniques in this field. They generally are meant to provide information on the painting materials, on the employed techniques and on the object state of conservation. However, only when the various images are perfectly registered on each other and on the 3D model, no ambiguity is possible and safe conclusions may be drawn. We present the integration of 2D and 3D measurements carried out on two different paintings: "Madonna of the Yarnwinder" by Leonardo da Vinci, and "Portrait of Lionello d'Este", by Pisanello, both painted in the XV century.

Microscale radiocarbon dating of paintings

International Nuclear Information System (INIS)

Hendriks, Laura; Hajdas, Irka; McIntyre, Cameron; Kueffner, Markus; Ferreira, Ester S.B.; Scherrer, Nadim C.

2016-01-01

In this paper, radiocarbon dating of paintings using minimal sample sizes has been investigated, in an effort to address the problem of limited access to sample material in paintings. 14 C analyses were conducted on signed and dated paintings from two Swiss artists of the twentieth century. The selected paintings dated from the 1930s and 1960s, provided the opportunity to evaluate the dating accuracy on paintings realized before and after 1950 AD when the 14 C bomb peak was created, as a result of the nuclear tests conducted in the 1950/1960s. The work focused on the one hand on minimizing the size of the canvas sample required for accelerator mass spectrometer radiocarbon measurement on the gas ion source of the MICADAS and, on the other hand, on testing the possibility of dating the organic binder of the paint. Following careful characterization of the paint composition by X-ray fluorescence spectroscopy, Fourier transformed infrared spectroscopy, and Raman spectroscopy, paints containing no other carbon source than the natural organic binder were identified and dated. (orig.)

Microscale radiocarbon dating of paintings

Energy Technology Data Exchange (ETDEWEB)

Hendriks, Laura; Hajdas, Irka; McIntyre, Cameron [ETH Zurich, Ion Beam Physics, Zurich (Switzerland); Kueffner, Markus; Ferreira, Ester S.B. [SIK-ISEA, Zurich, Zurich (Switzerland); Scherrer, Nadim C. [Bern University of Applied Sciences, HKB, Bern (Switzerland)

2016-03-15

In this paper, radiocarbon dating of paintings using minimal sample sizes has been investigated, in an effort to address the problem of limited access to sample material in paintings. {sup 14}C analyses were conducted on signed and dated paintings from two Swiss artists of the twentieth century. The selected paintings dated from the 1930s and 1960s, provided the opportunity to evaluate the dating accuracy on paintings realized before and after 1950 AD when the {sup 14}C bomb peak was created, as a result of the nuclear tests conducted in the 1950/1960s. The work focused on the one hand on minimizing the size of the canvas sample required for accelerator mass spectrometer radiocarbon measurement on the gas ion source of the MICADAS and, on the other hand, on testing the possibility of dating the organic binder of the paint. Following careful characterization of the paint composition by X-ray fluorescence spectroscopy, Fourier transformed infrared spectroscopy, and Raman spectroscopy, paints containing no other carbon source than the natural organic binder were identified and dated. (orig.)

Use of an Atmospheric Atomic Oxygen Beam for Restoration of Defaced Paintings

Science.gov (United States)

Banks, Bruce A.; Rutledge, Sharon K.; Karla, Margaret; Norris, Mary Jo; Real, William A.; Haytas, Christy A.

1999-01-01

An atmospheric atomic oxygen beam has been found to be effective in removing organic materials through oxidation that are typical of graffiti or other contaminant defacements which may occur to the surfaces of paintings. The technique, developed by the National Aeronautics and Space Administration, is portable and was successfully used at the Carnegie Museum of Art to remove a lipstick smudge from the surface of porous paint on the Andy Warhol painting "Bathtub." This process was also evaluated for suitability to remove felt tip and ball point ink graffiti from paper, gesso on canvas and cotton canvas.

Photocatalytic surface reactions on indoor wall paint.

Science.gov (United States)

Salthammer, T; Fuhrmann, F

2007-09-15

The reduction of indoor air pollutants by air cleaning systems has received considerable interest, and a number of techniques are now available. So far, the method of photocatalysis was mainly applied by use of titanium dioxide (TiO2) in flow reactors under UV light of high intensity. Nowadays, indoor wall paints are equipped with modified TiO2 to work as a catalyst under indoor daylight or artificial light. In chamber experiments carried out under indoor related conditions itwas shown thatthe method works for nitrogen dioxide with air exchange and for formaldehyde without air exchange at high concentrations. In further experiments with volatile organic compounds (VOCs), a small effect was found for terpenoids with high kOH rate constants. For other VOCs and carbon monoxide there was no degradation at all or the surface acted as a reversible sink. Secondary emissions from the reaction of paint constituents were observed on exposure to light. From the results it is concluded that recipes of photocatalytic wall paints need to be optimized for better efficiency under indoor conditions.

Linear Optimization Techniques for Product-Mix of Paints Production in Nigeria

Directory of Open Access Journals (Sweden)

Sulaimon Olanrewaju Adebiyi

2014-02-01

Full Text Available Many paint producers in Nigeria do not lend themselves to flexible production process which is important for them to manage the use of resources for effective optimal production. These goals can be achieved through the application of optimization models in their resources allocation and utilisation. This research focuses on linear optimization for achieving product- mix optimization in terms of the product identification and the right quantity in paint production in Nigeria for better profit and optimum firm performance. The computational experiments in this research contains data and information on the units item costs, unit contribution margin, maximum resources capacity, individual products absorption rate and other constraints that are particular to each of the five products produced in the company employed as case study. In data analysis, linear programming model was employed with the aid LINDO 11 software to analyse the data. The result has showed that only two out of the five products under consideration are profitable. It also revealed the rate to which the company needs to reduce cost incurred on the three other products before making them profitable for production.

Multispectral Photogrammetric Data Acquisition and Processing Forwall Paintings Studies

Science.gov (United States)

Pamart, A.; Guillon, O.; Faraci, S.; Gattet, E.; Genevois, M.; Vallet, J. M.; De Luca, L.

2017-02-01

In the field of wall paintings studies different imaging techniques are commonly used for the documentation and the decision making in term of conservation and restoration. There is nowadays some challenging issues to merge scientific imaging techniques in a multimodal context (i.e. multi-sensors, multi-dimensions, multi-spectral and multi-temporal approaches). For decades those CH objects has been widely documented with Technical Photography (TP) which gives precious information to understand or retrieve the painting layouts and history. More recently there is an increasing demand of the use of digital photogrammetry in order to provide, as one of the possible output, an orthophotomosaic which brings a possibility for metrical quantification of conservators/restorators observations and actions planning. This paper presents some ongoing experimentations of the LabCom MAP-CICRP relying on the assumption that those techniques can be merged through a common pipeline to share their own benefits and create a more complete documentation.

Painting: Is It Indigenous to Ghanaian Culture?

Directory of Open Access Journals (Sweden)

Emmanuel Antwi

2014-10-01

Full Text Available Painting could be said to be well grounded in all cultures worldwide. This is underpinned by the vast record of cave art as globally represented, even though this phenomenon does not seamlessly continue into some ancient traditions that followed. In the face of the above however, to find the traditional period of a people one has to identify the geographical area of this group in order to consider the autochthonous art practice of the place so as to determine its cultural beginnings, extent, and forms of art explored. In the case of Ghana, one observes that, art historians usually site the beginning of painting at the time when colonial educational training of the arts was begun in Achimota from the 1900s. The study was conducted using historical review and analysis, unstructured interview guides as well as participant and non-participant observational techniques in a descriptive design at Sirigu, Ahwiaa and Ntonso, revealing the forms of painting that existed in the country before the introduction of formal training by the colonial masters. The result showed that Ghanaians traditionally practiced different kinds of painting, long before the colonial art training programme was introduced. We feel it should be of concern for any people to be able to tell, not only how, and why but also when they started doing the things that matter to their existence and cultural heritage.

Optical measurements of paintings and the creation of an artwork database for authenticity.

Directory of Open Access Journals (Sweden)

Seonhee Hwang

Full Text Available Paintings have high cultural and commercial value, so that needs to be preserved. Many techniques have been attempted to analyze properties of paintings, including X-ray analysis and optical coherence tomography (OCT methods, and enable conservation of paintings from forgeries. In this paper, we suggest a simple and accurate optical analysis system to protect them from counterfeit which is comprised of fiber optics reflectance spectroscopy (FORS and line laser-based topographic analysis. The system is designed to fully cover the whole area of paintings regardless of its size for the accurate analysis. For additional assessments, a line laser-based high resolved OCT was utilized. Some forgeries were created by the experts from the three different styles of genuine paintings for the experiments. After measuring surface properties of paintings, we could observe the results from the genuine works and the forgeries have the distinctive characteristics. The forgeries could be distinguished maximally 76.5% with obtained RGB spectra by FORS and 100% by topographic analysis. Through the several executions, the reliability of the system was confirmed. We could verify that the measurement system is worthwhile for the conservation of the valuable paintings. To store the surface information of the paintings in micron scale, we created a numerical database. Consequently, we secured the databases of three different famous Korean paintings for accurate authenticity.

Self Cleaning Paint: Introduction of Photocatalytic Particles into a Paint System

DEFF Research Database (Denmark)

Gunnarsson, Sverrir Grimur

The current industrial PhD work was aimed at synthesising a photocatalytic composite material which could be used to give organic wood paint films self-cleaning and anti-microbial properties. The current PhD work was done in collaboration between Dyrup A/S and Technical University of Denmark...... consists of an introduction to relevant concepts and literature followed by results, presented as research papers, and a patent application. Four research papers are introduced as individual chapters. Chapter 4 discusses the synthesis and optimisation of anatase TiO2 coated microspheres, chapter 5......-cleaning coatings containing TiO2 coated microspheres. The results show that introducing a photocatalyst into an organic paint system as a coating on inert carrier particles results in durable and weather stable paint films. The paint films exhibit selfcleaning properties and are able to resist the attack of micro...

Selectively strippable paint schemes

Science.gov (United States)

Stein, R.; Thumm, D.; Blackford, Roger W.

1993-03-01

In order to meet the requirements of more environmentally acceptable paint stripping processes many different removal methods are under evaluation. These new processes can be divided into mechanical and chemical methods. ICI has developed a paint scheme with intermediate coat and fluid resistant polyurethane topcoat which can be stripped chemically in a short period of time with methylene chloride free and phenol free paint strippers.

Painting for protection

International Nuclear Information System (INIS)

Stepto, G.G.C.

1981-01-01

Despite the use of special alloys, paint is still the most economical and practical method of protecting steel. Chlorinated rubber resin based paint systems are shown to be satisfactory in areas requiring decontamination as well as for outside exposed areas of nuclear power plants. (author)

The use of neutron activation to detect a photographic image under a painting

International Nuclear Information System (INIS)

Wall, T.; Bird, R.

1980-01-01

Neutron activation followed by autoradiography has been used in a number of studies of oil paintings to reveal brush technique, overpainting, pigment types and other information. The facilities of the Australian Atomic Energy Commission Research Establishment have been used to investigate whether there is a photographic image underlying a painting by the Swedish born artist Carl Magnus Oscar Fristrom (1856-1919)

A PSP-based small-signal MOSFET model for both quasi-static and nonquasi-static operations

NARCIS (Netherlands)

Aarts, A.C.T.; Smit, G.D.J.; Scholten, A.J.; Klaassen, D.B.M.

2008-01-01

In this paper, a small-signal MOSFET model is described, which takes the local effects of both velocity saturation and transverse mobility reduction into account. The model is based on the PSP model and is valid for both quasi-static and nonquasi-static (NQS) operations. Recently, it has been found

The physicochemical characterization of cave paintings of Baja California; Caracterizacion fisicoquimica de pigmentos y soportes en pinturas murales: caso Mayapan, Yucatan

Energy Technology Data Exchange (ETDEWEB)

Valdez, B.; Cobo, J.; Schorr, M. [Area de Corrosion y Materiales, Instituto de Ingenieria, Universidad Autonoma de Baja California, Blvd. Benito Juarez, S/N, 21280, Mexicali, B.C. (Mexico); Cota, L. [Centro de Ciencias de la Materia Condensada, UNAM, Ensenada, B.C. (Mexico); Oviedo, F. [Centro INAH - BC, Ensenada, B.C. (Mexico)]. e-mail: benval@iing.mxl.uabc.mx

2006-07-01

The Palaeolithic paintings of Baja California constitute an important contribution to the national, historic and cultural patrimony of Mexico. The aim of this investigation was to determine the physicochemical characteristics, the microstructure and texture of these polychrome paintings, painted on rocks encountered in the mountainous, desert/arid zones of Baja California and Baja California South. The first stage of this work was devoted to the examination and recording of the cave paintings of 'El Vallecito', a narrow fluvial valley displaying large granitic rocks emerging from the sandy soil. Tiny painting samples were collected and analyzed by SEM, EDS and FTIR techniques. The painters used four main colours: red, black, yellow and white. The paint raw materials are mineral pigments: white (kaolin, calcite, and gypsum), red (hematite), yellow (ochre, limonite), black (charcoal from burnt wood or calcined bones) and water as a diluent and/or a binder, all encountered in the painters habitat. The minerals were collected, ground and sometimes heated to change their tone. By mixing with water, a spreadable paste or a thick slurry was produced, which was applied with the fingers for lines or a piece of animal skin for figures, respectively. The 100% solids, dry paint converts into a dense, hard layer, incrusted into the grainy, rough, hollow granite rock surface. This paint might be called {sup s}tone on stone{sup ,} explaining its permanence for centuries enduring heat, wind and weather. A simulation of the painting technique was done at the Materials and Corrosion Laboratory, UABC by collecting mineral pigments, preparing the paint as a paste or slurry and applying it on a granitic rock. Knowing the paint composition, production and application techniques will be useful in e conservation and restoration of cave paintings and stone-built, ancient structures such as pyramids, cathedrals and monuments. (Author)

Local Treatment for Monochrome Outdoor Painted Metal Sculptures: Assessing the suitability of conservation paints for retouching

OpenAIRE

van Basten, Nikki; Defeyt, Catherine; Rivenc, Rachel

2015-01-01

When outdoor painted sculptures get chipped, scratched or abraded, conservators might consider local retouching treatments as an option that would protect the exposed metal substrate and restore the aesthetic integrity, thus postponing a very costly and invasive overall repainting. Unfortunately, matching colour gloss and texture on large monochrome surfaces is always challenging. This paper reports on research undertaken to investigate some of the materials and application techniques that co...

Atomic Oxygen Treatment as a Method of Recovering Smoke Damaged Paintings

Science.gov (United States)

Rutledge, Sharon K.; Banks, Bruce A.; Forkapa, Mark; Stueber, Thomas; Sechkar, Edward; Malinowski, Kevin

1998-01-01

Smoke damage, as a result of a fire, can be difficult to remove from some types of painting media without causing swelling, leaching or pigment movement or removal. A non-contact technique has been developed which can remove soot from the surface of a painting by use of a gently flowing gas containing atomic oxygen. The atomic oxygen chemically reacts with the soot on the surface creating gasses such as carbon monoxide and carbon dioxide which can be removed through the use of an exhaust system. The reaction is limited to the surface so that the process can be timed to stop when the paint layer is reached. Atomic oxygen is a primary component of the low Earth orbital environment, but can be generated on Earth through various methods. This paper will discuss the results of atomic oxygen treatment of soot exposed acrylic gesso, ink on paper, and a varnished oil painting. Reflectance measurements were used to characterize the surfaces before and after treatment.

From the ground up: Surface and sub-surface effects in fifteenth- and sixteenth-century Netherlandish paintings

NARCIS (Netherlands)

Vandivere, A.L.S.

2013-01-01

This doctoral dissertation explores the techniques that were used to build up fifteenth- and sixteenth-century Netherlandish oil paintings, from the ground up. Paintings are more than two-dimensional images; they are physical objects composed of several layers, usually: the support, ground,

Order-fractal transitions in abstract paintings

Energy Technology Data Exchange (ETDEWEB)

Calleja, E.M. de la, E-mail: elsama79@gmail.com [Instituto de Física, Universidade Federal do Rio Grande do Sul, Caixa Postal 15051, 91501-970, Porto Alegre, RS (Brazil); Cervantes, F. [Department of Applied Physics, CINVESTAV-IPN, Carr. Antigua a Progreso km.6, Cordemex, C.P.97310, Mérida, Yucatán (Mexico); Calleja, J. de la [Department of Informatics, Universidad Politécnica de Puebla, 72640 (Mexico)

2016-08-15

In this study, we determined the degree of order for 22 Jackson Pollock paintings using the Hausdorff–Besicovitch fractal dimension. Based on the maximum value of each multi-fractal spectrum, the artworks were classified according to the year in which they were painted. It has been reported that Pollock’s paintings are fractal and that this feature was more evident in his later works. However, our results show that the fractal dimension of these paintings ranges among values close to two. We characterize this behavior as a fractal-order transition. Based on the study of disorder-order transition in physical systems, we interpreted the fractal-order transition via the dark paint strokes in Pollock’s paintings as structured lines that follow a power law measured by the fractal dimension. We determined self-similarity in specific paintings, thereby demonstrating an important dependence on the scale of observations. We also characterized the fractal spectrum for the painting entitled Teri’s Find. We obtained similar spectra for Teri’s Find and Number 5, thereby suggesting that the fractal dimension cannot be rejected completely as a quantitative parameter for authenticating these artworks. -- Highlights: •We determined the degree of order in Jackson Pollock paintings using the Hausdorff–Besicovitch dimension. •We detected a fractal-order transition from Pollock’s paintings between 1947 and 1951. •We suggest that Jackson Pollock could have painted Teri’s Find.

Accelerated bridge paint test program.

Science.gov (United States)

2011-07-06

The accelerated bridge paint (AB-Paint) program evaluated a new Sherwin-Williams two-coat, : fast-curing paint system. The system is comprised of an organic zinc-rich primer (SW Corothane I : Galvapac One-Pack Zinc-Rich Primer B65 G11) and a polyurea...

Hyperspectral remote sensing techniques applied to the noninvasive investigation of mural paintings: a feasibility study carried out on a wall painting by Beato Angelico in Florence

Science.gov (United States)

Cucci, Costanza; Picollo, Marcello; Chiarantini, Leandro; Sereni, Barbara

2015-06-01

Nowadays hyperspectral imaging is a well-established methodology for the non-invasive diagnostics of polychrome surfaces, and is increasingly utilized in museums and conservation laboratories for documentation purposes and in support of restoration procedures. However, so far the applications of hyperspectral imaging have been mainly limited to easel paintings or paper-based artifacts. Indeed, specifically designed hyperspectral imagers, are usually used for applications in museum context. These devices work at short-distances from the targets and cover limited size surfaces. Instead, almost still unexplored remain the applications of hyperspectral imaging to the investigations of frescoes and large size mural paintings. For this type of artworks a remote sensing approach, based on sensors capable of acquiring hyperspectral data from distances of the order of tens of meters, is needed. This paper illustrates an application of hyperspectral remote sensing to an important wall-painting by Beato Angelico, located in the San Marco Museum in Florence. Measurements were carried out using a re-adapted version of the Galileo Avionica Multisensor Hyperspectral System (SIM-GA), an avionic hyperspectral imager originally designed for applications from mobile platforms. This system operates in the 400-2500 nm range with over 700 channels, thus guaranteeing acquisition of high resolution hyperspectral data exploitable for materials identification and mapping. In the present application, the SIM-GA device was mounted on a static scanning platform for ground-based applications. The preliminary results obtained on the Angelico's wall-painting are discussed, with highlights on the main technical issues addressed to optimize the SIM-GA system for new applications on cultural assets.

Elof Risebye – A Pioneer in the Transfer of Wall Paintings on the Wrong Path

DEFF Research Database (Denmark)

Brajer, Isabelle Eve

2001-01-01

The transfer of wall paintings was introduced to Denmark by Italian restorers in 1913. A misunderstanding of this technique led to the development of a faulty method by Elof Risebye, an artist, who by chance got involved in the restoration of wall paintings. The use of the wrong adhesive resulted...... in massive damage of the paint layer. Risebye disguised his losses by overpainting, which he carried out according to his own style of painting, not at all following the style of the painter's whose work he was restoring. He also taught his students at the Fresco and Mosaic School how to detach frescoes......, thus disseminating his faulty method. Due to Risebye's activities there are a significant number of transferred wall paintings in Denmark which are in dire need of treatment today....

Structuralist readings: Painting vs. picture

Directory of Open Access Journals (Sweden)

Marinkov-Pavlović Lidija

2016-01-01

Full Text Available The aim of the paper is to point to two fundamentally different strategies of painting practice, that is, to two subsystems of painting: picture and painting. This differentiation can be made within the framework of semiotic and semiological analyses which have developed in theory under the influence of structuralism. The first part of the paper offers a basic insight into the linguistic foundation of structuralistic concept, and then sets a thesis about the possibility of analogue reconceptualisation of semiotics/semiology of painting through Julia Kristeva's semiotics and Roland Barthes' semiology. In addition, it points to the concrete concepts of structural analysis which have accentuated the opposition picture-painting with the examples of art practice concurrent to the development of structuralism. However, what is revealed is that various structuralist readings are significantly subjective to unstable relationship between the basic elements in the pictorial object, that is, in the work of painting.

A scientific approach to the characterization of the painting materials of Fra Mattia della Robbia polychrome terracotta altarpiece

Science.gov (United States)

Amadori, M. L.; Barcelli, S.; Casoli, A.; Mazzeo, R.; Prati, S.

2013-12-01

During the last restoration (2008-2011) of the polychrome terracotta altarpiece called Coronation of Virgin between Saints Rocco, Sebastian, Peter martyr and Antonio abbot, located in the collegiate church of S. Maria Assunta in Montecassiano (Macerata, Italy), scientific investigations were carried out to acquire detailed information about the painting technique. The identification of materials allowed a correct restoration. The altarpiece is almost entirely realized by Marco della Robbia (Fra Mattia), dates back to the first half of the XVI century and represents an interesting example of painted terracotta produced by using two different techniques: glazed polychrome terracotta and the "cold painting" technique. The characterization of the samples' material constituents was obtained by analysing the cross-sections and the fragments by different techniques (optical, SEM-EDS and ATR-FTIR microscopy as well as GC-MS), as the real nature of a component is often difficult to assess with one single technique. The optical microscope examination of paint cross-sections shows the presence of many layers, indicating the complexity of the paint stratigraphic morphologies. The original polychromy of della Robbia's masterpiece is constituted of cinnabar, red lake, red lead, orpiment, red ochre, lead white, lead tin yellow, green earth and raw umber. Two different types of gilding technique have been distinguished. The first one presents a glue mordant, and the second one shows an oil mordant composed by a mixture of red lead, red ochre, cinnabar and orpiment. The GC-MS analysis allowed the characterisation of linseed oil and a mixture of animal glue and egg as binding media stratigraphically located by the use of ATR-FTIR mapping microscopy. The analytical results of the painted terracotta integrated investigations show that original technique adopted is characterised by the application of pigments in an oil-binding medium directly applied on the substrates, probably treated

Methylisothiazolinone and benzisothiazolinone are widely used in paint: a multicentre study of paints from five European countries

DEFF Research Database (Denmark)

Schwensen, Jakob F; Lundov, Michael; Bossi, Rossana

2015-01-01

were found in paints from all five countries. Paints purchased in Denmark and Sweden contained especially high concentrations of BIT. CONCLUSION: The use of MI across European countries is extensive. In view of the ongoing epidemic of MI contact allergy, an evaluation of the safety of MI in paints......BACKGROUND: In view of the current epidemic of contact allergy to methylisothiazolinone (MI), it is important to clarify the extent of use of MI and related isothiazolinones in paints currently available for the consumer and worker in Europe. OBJECTIVES: To elucidate the use and concentrations...... of MI, methylchloroisothiazolinone (MCI) and benzisothiazolinone (BIT) in paints on the European retail market. METHODS: Wall paints (n = 71) were randomly purchased in retail outlets in five European countries. The paints were quantitatively analysed for their contents of MI, MCI and BIT by high...

A quasi-monochromatic X-rays source for art painting pigments investigation

Energy Technology Data Exchange (ETDEWEB)

Albertin, F.; Franconieri, A.; Gambaccini, M.; Petrucci, F.; Chiozzi, S. [University of Ferrara, Department of Physics and INFN, Ferrara (Italy); Moro, D. [University of Padova, Department of Physics, Padova (Italy); LNL - INFN, Legnaro, Padova (Italy)

2009-08-15

Monochromatic X-ray sources can be used for several applications, like in medicine or in studying our cultural heritage. We are investigating imaging systems based on a tuneable energy band X-ray source, to obtain an element mapping of painting layers using the K-edge technique. The narrow energy band beams are obtained with conventional X-ray source via Bragg diffraction on a mosaic crystal; such an analysis has been performed at different diffraction angles, tuning the energy to investigate spectra of interest from the artistic point of view, like zinc and copper. In this paper the characteristics of the system in terms of fluence rate are reported, and first results of this technique on canvas samples and painting are presented. (orig.)

Vision of Spaces in the Paintings of the Asháninka sheripiare Noe Morales Silva

Directory of Open Access Journals (Sweden)

Luisa Elvira Belaunde

2011-02-01

Full Text Available Amazonian shamanic painting is a hybrid art born from the coming together of Western figurative techniques, indigenous body painting and visionary shamanic experiences. It is a testimonial art by which painters express their visionary experiences to a foreign public aiming to understand the Amazonian universe. In his watercolors and drawings, the Asháninka healer Noé Silva Morales bears witness to his life as a sheripiare through the construction of visionary spaces carefully painted with skins of luminous designs.

Radiation safety in radioluminous paint workshop handling tritium activated paint

International Nuclear Information System (INIS)

Gaur, P.K.; Venkateswaran, T.V.

1986-01-01

This paper discusses the safety features related to a workshop when tritium activated luminous paint is handled by workmen. Salient features of the workshop and the methods employed for monitoring the radiation levels are briefly outlined and results are discussed. The importance of proper ventilation of the workplace and precautions to be taken in the storage of painted articles are highlighted. (author). 1 table, 3 figs

KMAH index and separation of PSP-waves from streamer data

Science.gov (United States)

Mitrofanov, Georgy; Priimenko, Viatcheslav

2017-08-01

The presence of triplications (caustics) can be a serious problem in seismic data processing and analysis. The travel-time curve becomes multi-valued and the geometrical spreading correction factor tends to zero due to energy focusing. To select the regions of possible triplications (caustics) of travel-times, which can arise during the propagation of reflected seismic waves, we use the Keller-Maslov-Arnol'd-Hörmander (KMAH) index. The identification of such regions improves the selection of signals associated with target reflecting horizons and their use in solving various inverse dynamic problems, including amplitude-versus-offset (AVO) and full-waveform inversions. The importance of the KMAH index increases in 4D surveys when the structure of the model is already known, and it is necessary to conduct a detailed analysis of the shapes of seismic signals with increasing accuracy when solving inverse seismic problems. In addition, this index can be valuable when solving various marine seismic problems associated with single and converted waves, in particular with PSP-waves. The present work is dedicated to the separation of signals associated with this type of wave using surface marine seismic data. However, the proposed algorithm has a wider application. It is based on: (i) a priori information on the medium under study; (ii) ray tracing method. The ray tracing method enables the identification of the corresponding signals and the determination of the time and space intervals, in which such signals are most accurately traced. These intervals are used in the selection of target signals, particularly signals related to PSP-waves. In order to select optimal areas of observation with higher amplitudes of target signals, we use the τ -p transform. To improve the stability of the signal separation, KMAH index is used. This approach allows the elimination of possible triplications (caustics) in the travel-time curve from the selected intervals.

NON-INVASIVE SURVEY OF OLD PAINTINGS USING VNIR HYPERSPECTRAL SENSOR

Directory of Open Access Journals (Sweden)

E. Matouskova

2013-07-01

Full Text Available Hyperspectral imaging is relatively new method developed primarily for army applications with respect to detection of possible chemical weapon existence and as an efficient assistant for a geological survey. The method is based on recording spectral profile for many hundreds of narrow spectral band. The technique gives full spectral curve of explored pixel which is an unparalleled signature of pixels material. Spectral signatures can then be compared with pre-defined spectral libraries or they can be created with respect to application. A new project named "New Modern Methods of Non-invasive Survey of Historical Site Objects" started at CTU in Prague with the New Year. The project is designed for 4 years and is funded by the Ministry of Culture in the Czech Republic. It is focused on material and chemical composition, damage diagnostics, condition description of paintings, images, construction components and whole structure object analysis in cultural heritage domain. This paper shows first results of the project on painting documentation field as well as used instrument. Hyperspec VNIR by Headwall Photonics was used for this analysis. It operates in the spectral range between 400 and 1000 nm. Comparison with infrared photography is discussed. The goal of this contribution is a non-destructive deep exploration of specific paintings. Two original 17th century paintings by Flemish authors Thomas van Apshoven ("On the Road" and David Teniers the Younger ("The Interior of a Mill" were chosen for the first analysis with a kind permission of academic painter Mr. M. Martan. Both paintings oil painted on wooden panel. This combination was chosen because of the possibility of underdrawing visualization which is supposed to be the most uncomplicated painting combination for this type of analysis.

Effects of gamma rays on a restored painting from the XVIIth century

International Nuclear Information System (INIS)

Rizzo, M.M.; Machado, L.D.B.; Borrely, S.I.; Sampa, M.H.O.; Rela, P.R.; Farah, J.P.S.; Schumacher, R.I.

2002-01-01

The subject of this study is a Peruvian painting from the 17th century, which has been recently restored and then contaminated by mould. It received different unsuccessful treatments. Therefore, radiation process was suggested as an alternative once it is an effective technology for decontamination and conservation purposes. The aim of this study is to investigate the influence of irradiation process on the original painting and on the products used in the restoration process. These products were irradiated with 60 Co gamma rays applying doses in the range of 6-25 kGy. The polymeric materials were characterized by thermal analysis techniques before and after irradiation. The colour of the pigments irradiated and non-irradiated were compared by spectrophotometric analysis. Small samples removed of the original painting were also irradiated and investigated. The results obtained until now allowed concluding that the irradiation with the appropriated dose of 6.0 kGy, according to the literature, will not damage the restored painting

Computer analysis of ATR-FTIR spectra of paint samples for forensic purposes

Science.gov (United States)

Szafarska, Małgorzata; Woźniakiewicz, Michał; Pilch, Mariusz; Zięba-Palus, Janina; Kościelniak, Paweł

2009-04-01

A method of subtraction and normalization of IR spectra (MSN-IR) was developed and successfully applied to extract mathematically the pure paint spectrum from the spectrum of paint coat on different bases, both acquired by the Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) technique. The method consists of several stages encompassing several normalization and subtraction processes. The similarity of the spectrum obtained with the reference spectrum was estimated by means of the normalized Manhattan distance. The utility and performance of the method proposed were tested by examination of five different paints sprayed on plastic (polyester) foil and on fabric materials (cotton). It was found that the numerical algorithm applied is able - in contrast to other mathematical approaches conventionally used for the same aim - to reconstruct a pure paint IR spectrum effectively without a loss of chemical information provided. The approach allows the physical separation of a paint from a base to be avoided, hence a time and work-load of analysis to be considerably reduced. The results obtained prove that the method can be considered as a useful tool which can be applied to forensic purposes.

The painting technique of the vaulted roof at the Saadian Tomb of Mulay Ahmed Al Mansour: preliminary results

International Nuclear Information System (INIS)

Andreotti, A.; Colombini, M. P.; Lluveras, A.; Raihan, M.; Ibnoussina, M.; Tanouti, B.; Boujamid, A.

2010-01-01

The Saadian tombs date back from the time of the sultan Ahmed Al Mansour (1578-1603). the tombs have, because of the beauty of their decoration, been a major attraction for visitors of Marrakech. The central mausoleum, the Hall of Twelve Columns, contains the tombs of ahmed Al Mansour and his family. It's dark, lavish, and ornate, with a huge vaulted roof, carved cedar doors and moucharabia (carved wooden screens traditionally to separate the sexes), and gray Italian marble columns. Samples from the painted roof have been collected and are currently under analysis to understand the executive technique used in its decoration. Generally, samples from painted works of art are characterised by the presence of several different organic materials together with pigments, fillers and dryers. A GC-MS analytical procedure for the characterisation of lipids, waxes, resins, pitch, tar, proteinaceous and polysaccharide material in the same paint micro-sample is applied to each collected micro-sample. The analytical procedure is based on a multi step sample pre-treatment that is able to separate the various organic components into different fractions (polysacharide, lipiresinous and proteinaceous), which are separately analyzed by GC-MS after purification and derivatisation. In particuler, this method achieves: -- the identification of proteinaceous binder (egg, collagen, casein) on the basis of the quantitative determination of the amino acid profile processed by principal component analysis -- the identification of lipids (linseed oil, poppy seed oil, walnut oil and egg), plant resins, animal resins,tar or pitches and natural waxes on the basis of the quantitative determination of fatty and dicarboxylic acids, and molecular pattern recognition of alchols and hydrocarbons and terpenic molecular markers -- the identification of th polysaccharide binder( starch, tragacanth gum, arabic gum, fruit tree gum, guar gum, karayagum) on the basis of the quantitative

Paintings on copper by the Flemish artist Frans Francken II: PIXE characterization by external microbeam

International Nuclear Information System (INIS)

Corregidor, V.; Oliveira, A.R.; Rodrigues, P.A.; Alves, L.C.

2015-01-01

Resorting to an external proton microbeam, PIXE analyses of three oil paintings on copper support dated from the XVII century and attributed to the Flemish artist Frans Francken II, were undertaken. The present work aims to contribute to the compositional study of the painting materials employed by XVII century artists that exploited copper as a support for oil painting, and specifically the materials used by Francken’s workshop, particularly copper plates. Because of the low thickness of the pictorial layers of this type of paintings and its non-destructive character, PIXE is the ideal technique to study the elemental composition of the paintings. Several spots in each painting were chosen for analysis in order to cover almost all the pigments used in the colour palette. Lead and calcium were detected in practically every analysed regions, probably related to the presence of lead white and chalk, usually used as ground layer on copper paintings. Small quantities of gold were also detected, which is present in many of this artist’s works to embellish some details of the representations. Also this work reports the first application of the external proton microbeam set-up available at CTN/IST in Portugal for the characterization of oil paintings

Raman spectroscopic analysis of the Maya wall paintings in Ek'Balam, Mexico

Science.gov (United States)

Vandenabeele, P.; Bodé, S.; Alonso, A.; Moens, L.

2005-08-01

Raman spectroscopy has been applied to the examination of wall painting fragments from the archaeological site of Ek'Balam (Yucatán, Mexico). Thirty-three samples have been studied, all originating from room 23 of the Acropolis, and being representative of the painting technique at Ek'Balam during the late Classic Maya period. Several pigments such as haematite, calcite, carbon, cinnabar and indigo were identified in these samples. The latter pigment was presumed to be present as 'Maya blue', which is an intercalation product of indigo and palygorskite clay. The observed Raman spectra are reported and some band assignments have been made. This survey is the first Raman spectroscopic examination of a whole set of pigments in archaeological Maya wall painting fragments.

3D synchrotron x-ray microtomography of paint samples

Science.gov (United States)

Ferreira, Ester S. B.; Boon, Jaap J.; van der Horst, Jerre; Scherrer, Nadim C.; Marone, Federica; Stampanoni, Marco

2009-07-01

Synchrotron based X-ray microtomography is a novel way to examine paint samples. The three dimensional distribution of pigment particles, binding media and their deterioration products as well as other features such as voids, are made visible in their original context through a computing environment without the need of physical sectioning. This avoids manipulation related artefacts. Experiments on paint chips (approximately 500 micron wide) were done on the TOMCAT beam line (TOmographic Microscopy and Coherent rAdiology experimenTs) at the Paul Scherrer Institute in Villigen, CH, using an x-ray energy of up to 40 keV. The x-ray absorption images are obtained at a resolution of 350 nm. The 3D dataset was analysed using the commercial 3D imaging software Avizo 5.1. Through this process, virtual sections of the paint sample can be obtained in any orientation. One of the topics currently under research are the ground layers of paintings by Cuno Amiet (1868- 1961), one of the most important Swiss painters of classical modernism, whose early work is currently the focus of research at the Swiss Institute for Art Research (SIK-ISEA). This technique gives access to information such as sample surface morphology, porosity, particle size distribution and even particle identification. In the case of calcium carbonate grounds for example, features like microfossils present in natural chalks, can be reconstructed and their species identified, thus potentially providing information towards the mineral origin. One further elegant feature of this technique is that a target section can be selected within the 3D data set, before exposing it to obtain chemical data. Virtual sections can then be compared with cross sections of the same samples made in the traditional way.

Impact on the environment from steel bridge paint deterioration using lead isotopic tracing, paint compositions and soil deconstruction

Energy Technology Data Exchange (ETDEWEB)

Gulson, Brian, E-mail: brian.gulson@mq.edu.au [Department of Environmental Science, Macquarie University, Sydney, NSW 2109 (Australia); CSIRO Energy Flagship, North Ryde, NSW 2113 (Australia); Chiaradia, Massimo [Department of Mineralogy, University of Geneva, Geneva (Switzerland); Davis, Jeffrey [CSIRO Energy Flagship, North Ryde, NSW 2113 (Australia); O' Connor, Gary [Queensland Department of Environment & Heritage Protection, Brisbane, QLD 4000 (Australia)

2016-04-15

Deterioration and repair of lead paint on steel structures can result in contamination of the ambient environment but other sources of lead such as from past use of leaded paint and gasoline and industrial activities can also contribute to the contamination. Using a combination of high precision lead isotopic tracing, detailed paint examination, including with scanning electron microscopy, and soil deconstruction we have compared paint on a steel bridge and bulk soil and lead-rich particles separated from soil. The majority of Pb found in the paint derives from Australian sources but some also has a probable US origin. The isotopic data for the bulk soils and selected particles lie on a mixing line with end members the geologically ancient Broken Hill lead and possible European lead which is suggested to be derived from old lead paint and industrial activities. Data for gasoline-derived particulates lie on this array and probably contribute to soil Pb. Although paint from the bridge can be a source of lead in the soils, isotopic tracing, paint morphology and mineralogical identification indicate that other sources, including from paint, gasoline and industrial activities, are contributing factors to the lead burden. Even though physical characteristics and elemental composition are the same in some particles, the isotopic signatures demonstrate that the sources are different. Plots using {sup 206}Pb/{sup 208}Pb vs {sup 206}Pb/{sup 207}Pb ratios, the common representation these days, do not allow for source discrimination in this investigation. - Highlights: • Soil Pb values up to 1200 mg/kg below Pb painted bridge • Microscopy & SEM characterised up to 6 different paint layers. • Isotopes identified different sources of Pb including paint and gasoline. • Multiple methods provide definitive answers.

24 CFR 35.1320 - Lead-based paint inspections, paint testing, risk assessments, lead-hazard screens, and...

Science.gov (United States)

2010-04-01

... 24 Housing and Urban Development 1 2010-04-01 2010-04-01 false Lead-based paint inspections, paint testing, risk assessments, lead-hazard screens, and reevaluations. 35.1320 Section 35.1320 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development LEAD-BASED PAINT...

75 FR 6383 - Lead-Based Paint Renovation, Repair and Painting, and Pre-Renovation Education Activities in...

Science.gov (United States)

2010-02-09

..., Repair and Painting, and Pre- Renovation Education Activities in Target Housing and Child Occupied....C. 2682(c)(3), and a lead-based paint pre-renovation education program in accordance with section... TSCA, and a lead-based paint pre-renovation education program in accordance with section 406(b) of TSCA...

Preference for and discrimination of paintings by mice.

Directory of Open Access Journals (Sweden)

Shigeru Watanabe

Full Text Available I measured preference for paintings (Renoir vs. Picasso or Kandinsky vs. Mondrian in mice. In general mice did not display a painting preference except for two mice: one preferred Renoir to Picasso, and the other preferred Kandinsky to Mondrian. Thereafter, I examined discrimination of paintings with new mice. When exposure to paintings of one artist was associated with an injection of morphine (3.0 mg/kg, mice displayed conditioned preference for those paintings, showing discrimination of paintings by Renoir from those by Picasso, and paintings by Kandinsky from those by Mondrian after the conditioning. They also exhibited generalization of the preference to novel paintings of the artists. After conditioning with morphine for a set of paintings consisting of two artists, mice showed discrimination between two sets of paintings also from the two artists but not in association with morphine. These results suggest that mice can discriminate not only between an artist's style but also among paintings of the same artist. When mice were trained to discriminate a pair of paintings by Kandinsky and Renoir in an operant chamber equipped with a touch screen, they showed transfer of the discrimination to new pairs of the artists, but did not show transfer of discrimination of paintings by other artists, suggesting generalization.

Identification and imaging of modern paints using Secondary Ion Mass Spectrometry with MeV ions

Science.gov (United States)

Bogdanović Radović, Iva; Siketić, Zdravko; Jembrih-Simbürger, Dubravka; Marković, Nikola; Anghelone, Marta; Stoytschew, Valentin; Jakšić, Milko

2017-09-01

Secondary Ion Mass Spectrometry using MeV ion excitation was applied to analyse modern paint materials containing synthetic organic pigments and binders. It was demonstrated that synthetic organic pigments and binder components with molecular masses in the m/z range from 1 to 1200 could be identified in different paint samples with a high efficiency and in a single measurement. Different ways of mounting of mostly insulating paint samples were tested prior to the analysis in order to achieve the highest possible yield of pigment main molecular ions. As Time-of-Flight mass spectrometer for MeV Secondary Ion Mass Spectrometry is attached to the heavy ion microprobe, molecular imaging on cross-sections of small paint fragments was performed using focused ions. Due to the fact that molecules are extracted from the uppermost layer of the sample and to avoid surface contamination, the paint samples were not embedded in the resin as is usually done when imaging of paint samples using different techniques in the field of cultural heritage.

PAINT SUPPLIES AND LOCATION: EXAMINING ICI

Directory of Open Access Journals (Sweden)

M. Herron

2016-01-01

Full Text Available How important is location to an international retailer? Not just any retailer but the second largest paint retailer in the world. Imperial Chemical Industries (ICI was a British chemical company and was at one stage the largest manufacturer in Britain. Formed from the merger of several leading British chemical companies in 1926, ICI makes paints and speciality products, including food ingredients, speciality polymers, electronic materials, fragrances and flavourings. ICI paints purchased the Cleveland Ohiobased Glidden Coatings & Resins (Glidden Paint Company in 1986 for USD$580 million. The addition of Glidden to ICI's North American operations more than doubled that subsidiary's annual sales to $3 billion and increased ICI's corporate presence in the United States dramatically. A decline in paint and solvent consumption during the 2000 decade slowed the average growth of the paint industry to about 2% annually. Rauch Associates, the leading US paint analyst firm, predicted near-term growth to slow even further to 1.2% per annum. Through the 1990’s and early 2000’s Glidden paint was sold only through Glidden-badged paint stores and smaller retailers under licence, developing a strong identifiable brand and reputation. How were potential Glidden retail paint store locations chosen across America to enable and support this market growth? This paper investigates the real process that was developed and applied to construct a national network of retail outlets across the United States. It also highlights the change in direction that occurred at ICI paints culminating in its eventual acquisition by AkzoNobel in 2008 who immediately sold parts of ICI to Henkel, and integrated ICI's remaining operations within its existing organisation. This sale and the associated corporate restructure caused considerable change in marketing directions allowing for the first time the selling of Glidden paint products to mass market centres

Integrating imaging FTIR and secondary ion mass spectrometry for the analysis of embedded paint cross-sections

DEFF Research Database (Denmark)

Heeren, Ron M.A.; Boon, Jaap J.; Noble, Petria

1999-01-01

Novel chemical imaging techniques provide new insight in the organic chemistry of embedded paint cross-sections. FTIR imaging microscopy delivers a two-dimensional image of the functional group distribution, revealing chemical aspects of the binding medium in each individual paint layer. Secondar...... and identity of various lead soaps and lead hydroxychloride in these inclusions....

Development of multi-functional nano-paint for energy harvesting applications

Directory of Open Access Journals (Sweden)

Bir B. Bohara

2018-02-01

Full Text Available The multi-functionality of lead magnesium niobate-lead titanate/paint (PMN-PT/paint nanocomposite films for energy harvesting via piezoelectric and pyroelectric effects is described. PMN-PT/paint films have been fabricated by a conventional paint-brushing technique to provide a low-cost, low-temperature and low–energy route to create multi-functional films. The properties investigated included dielectric constants, ε' and ε'', as a function of temperature, frequency and composition. From these parameters, it is indicated that the dielectric constants and AC conductivity (σAC increase with an increase of filler content and temperature, implying an improvement of the functionality of the films. The results revealed that σAC obeyed the relation σAC = Aωs, and exponent s, was found to decrease by increasing the temperature. The correlated barrier hopping was the dominant conduction mechanism in the nanocomposite films. The efforts were made to investigate the performance of nanocomposite films to mechanical vibrations and thermal variations. A cantilever system was designed and examined to assess its performance as energy harvesters. The highest output voltage and power for a PMN-PT/paint based harvester with a broad frequency response operating in the -31-piezoelectric mode were 65 mV and 1 nW, respectively. Voltage and power were shown to be enhanced by application of thermal variations. Thus, films could be utilized for combined energy harvesting via piezoelectric and pyroelectric characteristics. Keywords: Dielectric, Pyroelectricity, Piezoelectricity, Nanocomposites, PMN-PT, Energy harvesting

Construction, characterization and evaluation of the protective efficacy of the Streptococcus suis double mutant strain ΔSsPep/ΔSsPspC as a live vaccine candidate in mice.

Science.gov (United States)

Hu, Jin; You, Wujin; Wang, Bin; Hu, Xueying; Tan, Chen; Liu, Jinlin; Chen, Huanchun; Bei, Weicheng

2015-01-01

Streptococcus suis serotype 2 (S. suis 2) causes sepsis and meningitis in piglets and humans, and results in one of the most serious bacterial diseases affecting the production of commercial pigs around the world. Due to the failure of the current inactivated vaccine to protect against the disease, development of a new attenuated live vaccine against S. suis 2 by deleting essential virulence factors is urgently needed. We have previously reported the construction and characterization of an SsPep single gene deletion mutant strain ΔSsPep based on S. suis 2. Our previous results have shown that SsPep plays a critical role in the pathogenesis of S. suis 2. In this study, a precisely defined double-deletion mutant ΔSsPep/ΔSsPspC of S. suis 2 without antibiotic-resistance markers was constructed based on ΔSsPep, and the levels of virulence of the wild-type (WT) and ΔSsPep/ΔSsPspC were compared in a mouse experimental infection model. We demonstrated that the double mutant ΔSsPep/ΔSsPspC was less virulent than the WT, and could induce a noticeable antibody response. Analysis of IgG subclasses (IgG1 and IgG2a) indicated that both Th1 and Th2 responses were induced by ΔSsPep/ΔSsPspC, although the IgG2a (Th1) response predominated over the IgG1 (Th2) response. Moreover, ΔSsPep/ΔSsPspC could confer 90% protective efficacy against challenge with a lethal dose of fully virulent S. suis 2. Taken together, these data demonstrate that ΔSsPep/ΔSsPspC can be used as an effective live vaccine and provide a novel strategy against infection of S. suis 2. Copyright © 2014 Elsevier GmbH. All rights reserved.

Implementation of an Optical Coherence Tomography system for painting characterization

International Nuclear Information System (INIS)

Kashyap, Hannah U. K. S.; Mota, Claudia C. B. O.; Kyotoku, Bernardo B. C.; Gomes, Anderson S. L.; Santos-Filho, Plinio B.

2009-01-01

Optical Coherence Tomography (OCT) is a new but well established imaging technique for medical diagnosis, which can produce two- or three-dimensional images of bio-tissues with a few μm spatial resolution. Its potential as a non-invasive tool for art conservation of paintings and other objects has been realized recently. In this work, we report the implementation of two OCT systems applied to painting characterization. One system operates in the so-called spectral domain, with a central wavelength of 840 nm and axial resolution of 10 μm. The second system has its central wavelength at 1280 nm, with spatial resolution of 20 μm, and operates in the time domain. Both systems are independently controlled and have imaging software developed in-house using Lab View. Using both systems, a 15 years old acrylic portrait has been analyzed, where the paint layers, light and dark colors, and the cotton treads of the canvas could be identified. (Author)

Ink and Wash Painting for Children with Visual Impairment

Science.gov (United States)

Shih, Chih-Ming; Chao, Hsin-Yi

2010-01-01

Five children with visual impairments received instruction in drawing, using ink and wash painting and calligraphy techniques. A special system developed by a blind Taiwanese Chinese calligrapher, Tsann-Cherng Liaw, was used to help the children orient and refine their work. Children's performance on simple drawing tasks was compared before and…

Chromosome painting in plants.

NARCIS (Netherlands)

Schubert, I.; Fransz, P.F.; Fuchs, J.; Jong, de J.H.

2001-01-01

The current 'state-of-art' as to chromosome painting in plants is reviewed. We define different situations described as painting so far: i) Genomic in situ hybridisation (GISH) with total genomic DNA to distinguish alien chromosomes on the basis of divergent dispersed repeats, ii) 'Chromosomal in

Mobile depth profiling and sub-surface imaging techniques for historical paintings—A review

International Nuclear Information System (INIS)

Alfeld, Matthias; Broekaert, José A.C.

2013-01-01

Hidden, sub-surface paint layers and features contain valuable information for the art-historical investigation of a painting's past and for its conservation for coming generations. The number of techniques available for the study of these features has been considerably extended in the last decades and established techniques have been refined. This review focuses on mobile non-destructive subsurface imaging and depth profiling techniques, which allow for the in-situ investigation of easel paintings, i.e. paintings on a portable support. Among the techniques discussed are: X-ray radiography and infrared reflectography, which are long established methods and are in use for several decades. Their capabilities of element/species specific imaging have been extended by the introduction of energy/wavelength resolved measurements. Scanning macro-X-ray fluorescence analysis made it for the first time possible to acquire elemental distribution images in-situ and optical coherence tomography allows for the non-destructive study the surface paint layers in virtual cross-sections. These techniques and their variants are presented next to other techniques, such as Terahertz imaging, Nuclear Magnetic Resonance depth profiling and established techniques for non destructive testing (thermography, ultrasonic imaging and laser based interference methods) applied in the conservation of historical paintings. Next to selected case studies the capabilities and limitations of the techniques are discussed. - Highlights: • All mobile sub-surface and depth-profiling techniques for paintings are reviewed. • The number of techniques available has increased considerably in the last years. • X-ray radiography and infrared reflectography are still the most used techniques. • Scanning macro-XRF and optical coherence tomography begin to establish. • Industrial non destructive testing techniques support the preservation of paintings

Bioaccessibility of metals in soils and dusts contaminated by marine antifouling paint particles

International Nuclear Information System (INIS)

Turner, Andrew; Singh, Nimisha; Richards, Jonathan P.

2009-01-01

Fragments of antifouling paint and environmental geosolids have been sampled from the island of Malta and analysed for total and bioaccessible metals. Total concentrations of Ba, Cd, Cu, Pb, Sn and Zn were two to three orders of magnitude higher in spent antifouling composites relative to respective values in background soils and road dusts. Paint fragments were visible in geosolids taken from the immediate vicinity of boat maintenance facilities and mass balance calculations, based on Ba as a paint tracer, suggested that the most contaminated soils, road dusts and boatyard dusts contained about 1%, 7% and 9%, respectively, of antifouling particles. Human bioaccessibilities of metals were evaluated in selected samples using a physiologically based extraction technique. Accessibilities of Cd, Cu, Pb and Zn in the most contaminated solids were sufficient to be cause for concern for individuals working in the boat repair industry and to the wider, local community. - Geosolids near boat maintenance facilities are contaminated by antifouling paint particles containing high concentrations of bioaccessible metals.

Bioaccessibility of metals in soils and dusts contaminated by marine antifouling paint particles

Energy Technology Data Exchange (ETDEWEB)

Turner, Andrew, E-mail: aturner@plymouth.ac.u [School of Earth, Ocean and Environmental Sciences, University of Plymouth, Drake Circus, Plymouth PL4 8AA (United Kingdom); Singh, Nimisha; Richards, Jonathan P. [School of Earth, Ocean and Environmental Sciences, University of Plymouth, Drake Circus, Plymouth PL4 8AA (United Kingdom)

2009-05-15

Fragments of antifouling paint and environmental geosolids have been sampled from the island of Malta and analysed for total and bioaccessible metals. Total concentrations of Ba, Cd, Cu, Pb, Sn and Zn were two to three orders of magnitude higher in spent antifouling composites relative to respective values in background soils and road dusts. Paint fragments were visible in geosolids taken from the immediate vicinity of boat maintenance facilities and mass balance calculations, based on Ba as a paint tracer, suggested that the most contaminated soils, road dusts and boatyard dusts contained about 1%, 7% and 9%, respectively, of antifouling particles. Human bioaccessibilities of metals were evaluated in selected samples using a physiologically based extraction technique. Accessibilities of Cd, Cu, Pb and Zn in the most contaminated solids were sufficient to be cause for concern for individuals working in the boat repair industry and to the wider, local community. - Geosolids near boat maintenance facilities are contaminated by antifouling paint particles containing high concentrations of bioaccessible metals.

The colors of paintings and viewers' preferences.

Science.gov (United States)

Nascimento, Sérgio M C; Linhares, João M M; Montagner, Cristina; João, Catarina A R; Amano, Kinjiro; Alfaro, Catarina; Bailão, Ana

2017-01-01

One hypothesis to explain the aesthetics of paintings is that it depends on the extent to which they mimic natural image statistics. In fact, paintings and natural scenes share several statistical image regularities but the colors of paintings seem generally more biased towards red than natural scenes. Is the particular option for colors in each painting, even if less naturalistic, critical for perceived beauty? Here we show that it is. In the experiments, 50 naïve observers, unfamiliar with the 10 paintings tested, could rotate the color gamut of the paintings and select the one producing the best subjective impression. The distributions of angles obtained are described by normal distributions with maxima deviating, on average, only 7 degrees from the original gamut orientation and full width at half maximum just above the threshold to perceive a chromatic change in the paintings. Crucially, for data pooled across observers and abstract paintings the maximum of the distribution was at zero degrees, i.e., the same as the original. This demonstrates that artists know what chromatic compositions match viewers' preferences and that the option for less naturalistic colors does not constrain the aesthetic value of paintings. Copyright © 2016 Elsevier Ltd. All rights reserved.

Applications of optical coherence tomography in the non-contact assessment of automotive paints

Science.gov (United States)

Lawman, Samuel; Zhang, Jinke; Williams, Bryan M.; Zheng, Yalin; Shen, Yao-Chun

2017-06-01

The multiple layer paint systems on modern cars serve two end purposes, they firstly protect against corrosion and secondly give the desired visual appearance. To ensure consistent corrosion protection and appearance, suitable Quality Assurance (QA) measures on the final product are required. Various (layer thickness and consistency, layer composition, flake statistics, surface profile and layer dryness) parameters are of importance, each with specific techniques that can measure one or some of them but no technique that can measure all or most of them. Optical Coherence Tomography (OCT) is a 3D imaging technique with micrometre resolution. Since 2016, OCT measurements of layer thickness and consistency, layer composition fingerprint and flake statistics have been reported. In this paper we demonstrate two more novel applications of OCT to automotive paints. Firstly, we use OCT to quantify unwanted surface texture, which leads to an "orange peel" visual defect. This was done by measuring the surface profiles of automotive paints, with an unoptimised precision of 37 nm over lateral range of 7 mm, to quantify texture of less than 500 nm. Secondly, we demonstrate that OCT can measure how dry a coating layer is by measuring how fast it is still shrinking quasiinstantaneously, using Fourier phase sensitivity.

The characterization of canvas painting by the Serbian artist Milo Milunović using X-ray fluorescence, micro-Raman and FTIR spectroscopy

International Nuclear Information System (INIS)

Damjanović, Lj.; Gajić-Kvaščev, M.; Đurđević, J.; Andrić, V.; Marić-Stojanović, M.; Lazić, T.; Nikolić, S.

2015-01-01

A canvas painting by Milo Milunović “The Inspiration of the poet” was studied by energy dispersive X-Ray fluorescence (EDXRF), micro-Raman and Fourier transform infrared (FTIR) spectroscopy in order to identify materials used by the artist and his painting technique. Study is perfomed combining in situ non-destructive method with the preparation and study of cross-section samples and raw fragments of the samples. Milo Milunović, an eminent painter from Balkan region, made a copy of the Nicolas Poussin's original painting in Louvre in 1926/27. Obtained results revealed following pigments on the investigated canvas painting: vermilion, minium, cobalt blue, ultramarine, lead white, zinc white, cadmium yellow, chrome-based green pigment and several earth pigments – red and yellow ocher, green earth and umber. Ground layer was made of lead white mixed with calcium carbonate. - Highlights: • In situ EDXRF, micro-Raman and FTIR spectroscopy were employed. • Pallete of painting “The Inspiration of the poet” by Milunović has been determined. • Obtained results allowed evaluation of the painter’s technique. • Milo Milunović worked on the clay ground imitating Nicoals Poussin’s technique

A multi-analytical study of the fifteenth century mural paintings of the Batalha Monastery (Portugal) in view of their conservation

Science.gov (United States)

Valadas, S.; Candeias, A.; Dias, C.; Schiavon, N.; Cotovio, M.; Pestana, J.; Gil, M.; Mirão, J.

2013-12-01

The systematic characterization of the painting's palette and technique applied on the execution of the mural paintings of the Batalha Monastery (Batalha, Leiria, Portugal) is presented. These are the oldest mural paintings known in Portugal (apart from Roman frescoes) and represent the beginning of an artistic Portuguese tradition that continues until the nineteenth century. The aim of the study was to identify for the first time by adopting a multi-analytical physico-chemical approach of the pigments, binder, and alteration products (white veils, crusts, and pigment alteration) of these unique works of arts in order not only to better understand the painting technique, but also to support a conservation-restoration intervention that took place from April to August 2010. Micro-sampling of paint layers was performed on representative areas of the paintings. The characterization of the pigments and binders was carried out by microscopy and microanalysis of cross sections using optical microscopy, scanning electron microscopy coupled with energy dispersive X-ray spectrometry (SEM-EDS), micro-FTIR, and micro X-ray diffraction. The combined analysis of the paintings allowed the identification of the painting's palette: Vermillion (HgS) and red ochre for the reds, yellow ochres for the yellows, green earths and malachite for the greens, azurite for the blues, and carbon for the blacks. The use of the pigment is dependent of the motive painted while the most expensive materials were used in the most important iconographic motives. Alteration of malachite was identified in darkened layers in green areas of the paintings. White veil areas on the surface of the paintings were identified as calcite from precipitation/dissolution processes due to water run-off on the sacristy dome ceiling and walls.

THE STROGANOV OR OLD BELIEVERS’ ICON PAINTING TRADITION IN THE WORKS OF N.S. LESKOV

Directory of Open Access Journals (Sweden)

Yana Valeryevna Karsakova

2012-11-01

Full Text Available N.S. Leskov is known to have been a collector of icons and a connoisseur of history and techniques of icon painting. In his work as a writer he made use of his visual impression of icons painted in the old believers' tradition. Unlike modern scholars, when acting as an iconographer, Leskov did not classify old believers' icon painting as a separate trend, subsuming it within the “Stroganov school”. In the 19th century, the Stroganov school icons were distinguished by the mark of the Stroganov family name on the icon's reverse side. Such icons were believed to have been painted in the workshops officially set up by the Stroganov family. “An old believers' school icon” would be the one painted by at a workshop owned by old believers for the use in their prayer rooms or churches. Leskov's opinion on the insoluble link between the Stroganov and old believers' school of icon painting well agreed with the works of I.P. Sakharov the writer was quite familiar with, as well as with the ideas old believers themselves expressed concerning the history and traditions of icon painting. Leskov knew these opinions through communication with icon painters who professed the old belief version of Orthodox Christianity.

Canaletto's Colour: the inspiration and implications of changing grounds, pigments and paint application in the artist's English period

Directory of Open Access Journals (Sweden)

Roxane Sperber

2016-04-01

Full Text Available This article explores the English period of Giovanni Antonio Canal (Canaletto from a technical perspective. Six paintings by the artist, from the collection of the Yale Center for British Art, compose the focus of the study. Addressing the question of whether Canaletto’s English paintings were different or, as has long been held, inferior to his Venetian works, this article details changes to the artist’s grounds, painting technique, and palette when working in England.

Structuralist readings: Painting vs. picture

OpenAIRE

Marinkov-Pavlović Lidija

2016-01-01

The aim of the paper is to point to two fundamentally different strategies of painting practice, that is, to two subsystems of painting: picture and painting. This differentiation can be made within the framework of semiotic and semiological analyses which have developed in theory under the influence of structuralism. The first part of the paper offers a basic insight into the linguistic foundation of structuralistic concept, and then sets a thesis about the possibility of analogue reconceptu...

A spectroscopic study of Brazilwood paints in medieval books of hours.

Science.gov (United States)

Melo, Maria João; Otero, Vanessa; Vitorino, Tatiana; Araújo, Rita; Muralha, Vânia S F; Lemos, Ana; Picollo, Marcello

2014-01-01

In this work, microspectrofluorimetry was for the first time applied to the identification of the red organic lakes that are characteristic of the lavish illuminations found in 15(th) century books of hours. Microspectrofluorimetry identified those red paints, ranging from opaque pink to dark red glazes, as brazilwood lakes. An unequivocal characterization was achieved by comparison with reference paints produced following recipes from the medieval treatise The Book on How to Make Colours, and was further confirmed by fiber optic reflectance spectroscopy (FORS). For these treasured cultural objects, microspectrofluorimetry and FORS proved to be the only techniques that could identify, in situ or in microsamples, the chromophore responsible for the pinkish hues: a brazilein-Al(3+) complex. Additionally, a multi-analytical approach provided a full characterization of the color paints, including pigments, additives, and binders. Microspectroscopic techniques, based on infrared and X-ray radiation, enabled us to disclose the full palette of these medieval manuscripts, including the elusive greens, for which, besides malachite, basic copper sulfates were found; Raman microscopy suggested a mixture of brochantite and langite. Infrared analysis proved invaluable for a full characterization of the additives that were applied as fillers or whites (chalk, gypsum, and white lead) as well as the proteinaceous and polysaccharide binders that were found pure or in mixture.

Influence of ns-laser wavelength in laser-induced breakdown spectroscopy for discrimination of painting techniques

Science.gov (United States)

Bai, Xueshi; Syvilay, Delphine; Wilkie-Chancellier, Nicolas; Texier, Annick; Martinez, Loic; Serfaty, Stéphane; Martos-Levif, Dominique; Detalle, Vincent

2017-08-01

The influence of ns-laser wavelength to discriminate ancient painting techniques such as are fresco, casein, animal glue, egg yolk and oil was investigated in this work. This study was carried out with a single shot laser on samples covered by a layer made of a mixture of the cinnabar pigment and different binders. Three wavelengths based on Nd: YAG laser were investigated (1064, 532 and 266 nm). The plasma is controlled at the same electron temperature after an adjustment of pulse energy for these three wavelengths on a fresco sample without organic binder. This approach allows to eliminate the effects of laser pulse energy and the material laser absorption. Afterwards, the emission spectra were compared to separate different techniques. The organic binding media has been separated based on the relative emission intensity of the present CN or C2 rovibrational emissions. In order to test the capability of separating or identifying, the chemometric approach (PCA) was applied to the different matrix. The different solutions in term of wavelength range to optimise the identification was investigated. We focused on the evaluation for the laser wavelength to insure a better separation. The different capacity was interpreted by differentiating the binders by the altered interaction mechanisms between the laser photon and the binders. Also, the electron temperature in the plasma was estimated, which provided the evidences to our findings.

Canvas Supports in Paintings by Nicolai Abildgaard: Fabrics and Formats

DEFF Research Database (Denmark)

Filtenborg, Troels Folke

2015-01-01

An investigation of the technique and materials in paintings by the Danish artist Nicolai Abildgaard (1743 – 1809) included examination of the canvas supports in a large number of his works. Thread count and weave density were studied by automated weave-mapping computer software, designed for wor...

Mobile depth profiling and sub-surface imaging techniques for historical paintings—A review

Energy Technology Data Exchange (ETDEWEB)

Alfeld, Matthias, E-mail: matthias.alfeld@desy.de [University of Hamburg, Department of Chemistry, Martin-Luther-King Platz 6, D-20146 Hamburg (Germany); University of Antwerp, Department of Chemistry, Groenenbrogerlaan 171, B-2020 Antwerp (Belgium); Broekaert, José A.C., E-mail: jose.broekaert@chemie.uni-hamburg.de [University of Hamburg, Department of Chemistry, Martin-Luther-King Platz 6, D-20146 Hamburg (Germany)

2013-10-01

Hidden, sub-surface paint layers and features contain valuable information for the art-historical investigation of a painting's past and for its conservation for coming generations. The number of techniques available for the study of these features has been considerably extended in the last decades and established techniques have been refined. This review focuses on mobile non-destructive subsurface imaging and depth profiling techniques, which allow for the in-situ investigation of easel paintings, i.e. paintings on a portable support. Among the techniques discussed are: X-ray radiography and infrared reflectography, which are long established methods and are in use for several decades. Their capabilities of element/species specific imaging have been extended by the introduction of energy/wavelength resolved measurements. Scanning macro-X-ray fluorescence analysis made it for the first time possible to acquire elemental distribution images in-situ and optical coherence tomography allows for the non-destructive study the surface paint layers in virtual cross-sections. These techniques and their variants are presented next to other techniques, such as Terahertz imaging, Nuclear Magnetic Resonance depth profiling and established techniques for non destructive testing (thermography, ultrasonic imaging and laser based interference methods) applied in the conservation of historical paintings. Next to selected case studies the capabilities and limitations of the techniques are discussed. - Highlights: • All mobile sub-surface and depth-profiling techniques for paintings are reviewed. • The number of techniques available has increased considerably in the last years. • X-ray radiography and infrared reflectography are still the most used techniques. • Scanning macro-XRF and optical coherence tomography begin to establish. • Industrial non destructive testing techniques support the preservation of paintings.

Lead content in household paints in India

International Nuclear Information System (INIS)

Kumar, Abhay; Gottesfeld, Perry

2008-01-01

Lead and its compounds are used in paints not only to impart colour but also to make it durable, corrosion resistant and to improve drying. Adverse health impacts of lead especially on children have led countries to restrict or ban its use in paints. While U.S. and other developed countries instituted measures to limit the use of lead in paints, some developing countries including India have failed to regulate their lead content. The present study was undertaken to determine the levels of lead in new latex (water-based) and enamel paints (oil-based) intended for residential use in India. A total of 69 paint samples (38 latex and 31 enamel samples) from six of the most popular brands were analysed for lead concentrations. While all latex paint samples contained low levels of lead, (i.e., well below 600 ppm as regulated by United States' Consumer Products Safety Commission) the enamel paint samples of all but one brand contained significant concentrations of lead, ranging up to 140,000 ppm. In fact 84% of the enamel paints tested exceeded 600 ppm whereas only 38 % of all samples (including latex and enamel types) exceeded this regulatory level

Three-dimensional characterization of pigment dispersion in dried paint films using focused ion beam-scanning electron microscopy.

Science.gov (United States)

Lin, Jui-Ching; Heeschen, William; Reffner, John; Hook, John

2012-04-01

The combination of integrated focused ion beam-scanning electron microscope (FIB-SEM) serial sectioning and imaging techniques with image analysis provided quantitative characterization of three-dimensional (3D) pigment dispersion in dried paint films. The focused ion beam in a FIB-SEM dual beam system enables great control in slicing paints, and the sectioning process can be synchronized with SEM imaging providing high quality serial cross-section images for 3D reconstruction. Application of Euclidean distance map and ultimate eroded points image analysis methods can provide quantitative characterization of 3D particle distribution. It is concluded that 3D measurement of binder distribution in paints is effective to characterize the order of pigment dispersion in dried paint films.

Microscopy and the Mystery of Pablo Picasso's Paints

Science.gov (United States)

Rose, Volker

A deep connection to our past and shared cultural heritage must be preserved to foster a balanced society where all humanity can thrive. This talk will describe analysis of paint materials used by Pablo Picasso at the nanoscale, as only possible at the brightest synchrotron sources. It will highlight how new imaging techniques can reveal the invisible, bringing to light underlying compositions of old masters' paintings. This in turn enables the writing of new art history and provides important material clues that can assist with attribution and authentication. We will explain how the use of new technology can lead to new discoveries, which, in turn, can change the public's and the specialists' perception of great works of art. ∖In collaboration with scientists from The Art Institute of Chicago we have teamed up to study the chemical make up of zinc oxide pigments used in artworks by Pablo Picasso. We will show how highly focused X-ray beams with nanoscale spatial resolution and trace element sensitivity have helped to determine that Picasso has used conventional house paint in some of his paintings. Surprisingly, the study gives also new insights into the pigment material zinc oxide, which has also great potential in a variety of applications such as in spintronics or as transparent electrodes in solar panels. Work at the Advanced Photon Source and the Center for Nanoscale Materials was supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under contract DEAC02-06CH11357.

Thermal imaging method to visualize a hidden painting thermally excited by far infrared radiations

Science.gov (United States)

Davin, T.; Wang, X.; Chabane, A.; Pawelko, R.; Guida, G.; Serio, B.; Hervé, P.

2015-06-01

The diagnosis of hidden painting is a major issue for cultural heritage. In this paper, a non-destructive active infrared thermographic technique was considered to reveal paintings covered by a lime layer. An extended infrared spectral range radiation was used as the excitation source. The external long wave infrared energy source delivered to the surface is then propagated through the material until it encounters a painting zone. Due to several thermal effects, the sample surface then presents non-uniformity patterns. Using a high sensitive infrared camera, the presence of covered pigments can thus be highlighted by the analysis of the non-stationary phenomena. Reconstituted thermal contrast images of mural samples covered by a lime layer are shown.

Smart paint sensor for monitoring structural vibrations

International Nuclear Information System (INIS)

Al-Saffar, Y; Baz, A; Aldraihem, O

2012-01-01

A class of smart paint sensors is proposed for monitoring the structural vibration of beams. The sensor is manufactured from an epoxy resin which is mixed with carbon black nano-particles to make it electrically conducting and sensitive to mechanical vibrations. A comprehensive theoretical and experimental investigation is presented to understand the underlying phenomena governing the operation of this class of paint sensors and evaluate its performance characteristics. A theoretical model is presented to model the electromechanical behavior of the sensor system using molecular theory. The model is integrated with an amplifier circuit in order to predict the current and voltage developed by the paint sensor when subjected to loading. Furthermore, the sensor/amplifier circuit models are coupled with a finite element model of a base beam to which the sensor is bonded. The resulting multi-field model is utilized to predict the behavior of both the sensor and the beam when subjected to a wide variety of vibration excitations. The predictions of the multi-field finite element model are validated experimentally and the behavior of the sensor is evaluated both in the time and the frequency domains. The performance of the sensor is compared with the performance of conventional strain gages to emphasize its potential and merits. The presented techniques are currently being extended to sensors that can monitor the vibration and structural power flow of two-dimensional structures. (paper)

Global mapping of stratigraphy of an old-master painting using sparsity-based terahertz reflectometry.

Science.gov (United States)

Dong, Junliang; Locquet, Alexandre; Melis, Marcello; Citrin, D S

2017-11-08

The process by which art paintings are produced typically involves the successive applications of preparatory and paint layers to a canvas or other support; however, there is an absence of nondestructive modalities to provide a global mapping of the stratigraphy, information that is crucial for evaluation of its authenticity and attribution, for insights into historical or artist-specific techniques, as well as for conservation. We demonstrate sparsity-based terahertz reflectometry can be applied to extract a detailed 3D mapping of the layer structure of the 17th century easel painting Madonna in Preghiera by the workshop of Giovanni Battista Salvi da Sassoferrato, in which the structure of the canvas support, the ground, imprimatura, underpainting, pictorial, and varnish layers are identified quantitatively. In addition, a hitherto unidentified restoration of the varnish has been found. Our approach unlocks the full promise of terahertz reflectometry to provide a global and detailed account of an easel painting's stratigraphy by exploiting the sparse deconvolution, without which terahertz reflectometry in the past has only provided a meager tool for the characterization of paintings with paint-layer thicknesses smaller than 50 μm. The proposed modality can also be employed across a broad range of applications in nondestructive testing and biomedical imaging.

Retrospective dosimetry using chromosome painting

International Nuclear Information System (INIS)

Nasazzi, N.B.; Giorgio, M.D.; Taja, M.R.

2000-01-01

Chromosome aberration frequency measured in peripheral lymphocytes of persons exposed to ionizing radiation has been used since 1960s for dose assessment. Suspected overexposure is usually evaluated by the frequency of dicentrics and centric rings using an appropriate in vitro calibration curve. However, these chromosome aberrations are unstable with time after exposure and dose reconstruction may encounter uncertainties when the time between the exposure and the analysis is considerable or even unknown. It appears that translocations persist with time after exposure and may be used as an indication of acute past overexposures. Moreover, they appear to accumulate the cytogenetical information, which correlates with the dose received under fractionated, chronic or even occupational exposure conditions. Translocations may be detected using G-banding, which allows to score the total amount of radiation induced translocations but it is a time consuming method, or by Chromosome Painting, a method base on the Fluorescence in situ Hybridization (FISH) technique, painting only some chromosome pairs with specific whole chromosome probes and then extrapolating the observed translocation frequencies to the full genome. The latter method allows a faster aberration scoring than G-banding and appears to be the most promissory tool for biodosimetry, particularly when it is necessary to assess low doses and consequently to score a large number of metaphases, e.g. radiation workers exposed within dose limits. As with the unstable chromosome aberration, it is necessary an in vitro calibration curve based on the frequency of stable chromosome aberrations to assess doses. Our laboratory performed calibration curves for Co 60 γ-rays based on the frequencies of unstable (dicentrics and centric rings detected by conventional Giemsa staining) and stable chromosome aberrations (translocations and inversions, detected by G-banding). In order to minimize the interlaboratory variability, we

Antibiotic Extraction as a Recent Biocontrol Method for Aspergillus Niger andAspergillus Flavus Fungi in Ancient Egyptian mural paintings

Science.gov (United States)

Hemdan, R. Elmitwalli; Fatma, Helmi M.; Rizk, Mohammed A.; Hagrassy, Abeer F.

Biodeterioration of mural paintings by Aspergillus niger and Aspergillus flavus Fungi has been proved in different mural paintings in Egypt nowadays. Several researches have studied the effect of fungi on mural paintings, the mechanism of interaction and methods of control. But none of these researches gives us the solution without causing a side effect. In this paper, for the first time, a recent treatment by antibiotic "6 penthyl α pyrone phenol" was applied as a successful technique for elimination of Aspergillus niger and Aspergillus flavus. On the other hand, it is favorable for cleaning Surfaces of Murals executed by tembera technique from the fungi metabolism which caused a black pigments on surfaces.

Determination of thickness of thin turbid painted over-layers using micro-scale spatially offset Raman spectroscopy

Science.gov (United States)

Conti, Claudia; Realini, Marco; Colombo, Chiara; Botteon, Alessandra; Bertasa, Moira; Striova, Jana; Barucci, Marco; Matousek, Pavel

2016-12-01

We present a method for estimating the thickness of thin turbid layers using defocusing micro-spatially offset Raman spectroscopy (micro-SORS). The approach, applicable to highly turbid systems, enables one to predict depths in excess of those accessible with conventional Raman microscopy. The technique can be used, for example, to establish the paint layer thickness on cultural heritage objects, such as panel canvases, mural paintings, painted statues and decorated objects. Other applications include analysis in polymer, biological and biomedical disciplines, catalytic and forensics sciences where highly turbid overlayers are often present and where invasive probing may not be possible or is undesirable. The method comprises two stages: (i) a calibration step for training the method on a well characterized sample set with a known thickness, and (ii) a prediction step where the prediction of layer thickness is carried out non-invasively on samples of unknown thickness of the same chemical and physical make up as the calibration set. An illustrative example of a practical deployment of this method is the analysis of larger areas of paintings. In this case, first, a calibration would be performed on a fragment of painting of a known thickness (e.g. derived from cross-sectional analysis) and subsequently the analysis of thickness across larger areas of painting could then be carried out non-invasively. The performance of the method is compared with that of the more established optical coherence tomography (OCT) technique on identical sample set. This article is part of the themed issue "Raman spectroscopy in art and archaeology".

Microanalysis of paint layers in polychrome sculptures

International Nuclear Information System (INIS)

Mendoza, A.; Falcucci, C.; Jaksic, M.

2001-01-01

Cross sections paint layers of polychromes sculpture of the 16 century, located at the City Museum of Havana and currently in the restoration process, have been analyzed by capillary based μXRF , μPIXE , SEM -EDX and light microscopy. Experimental parameters (geometry measurement time) of the capillary based μXRF set up (nominal end diameter equal to 10 μm) were optimized to achieve the resolution required for meaningful scintigraphic studies of the art and archaeological objects, Cumulative x-rays spectra for each layer were obtained in order to perform semi-quantitative analysis. The employed pigments were identified by the characteristics elements and the elemental maps precisely reproduced photographs obtained by means of light microscopy. In the case of nuclear microprobe, RBS for Stoichiometry analysis of paint layers was also performed. additional information on the organic materials was also obtained by chemical analysis. Complementary results obtained by using the analytical techniques are presented and discussed from the point of view of the restoration processes

Development of new imaging techniques for the study and interpretation of late Rembrandt paintings

NARCIS (Netherlands)

Noble, P.; van Loon, A.; van der Snickt, G.; Janssens, K.; Alfeld, M.; Dik, J.; Bridgland, J.

2014-01-01

Recent macro-XRF scanning of Rembrandt’s Selfportrait from 1669 in the Mauritshuis – as part of the ReVisRembrandt project – has revealed significant new information about the pigments and build-up of the painting. The elemental distribution maps make clear that the umber-rich ground plays a very

Development of new imaging techniques for the study and interpretation of late Rembrandt paintings

NARCIS (Netherlands)

Noble, Petria; van Loon, A.; van der Snickt, G.R.; Janssens, Koen; Alfeld, Matthias; Dik, J.; Bridgland, Janet

2014-01-01

Recent macro-XRF scanning of Rembrandt’s Selfportrait from 1669 in the Mauritshuis – as part of the ReVisRembrandt project – has revealed significant
new information about the pigments and build-up of the painting. The elemental distribution maps make clear that the umber-rich ground plays a

Overexpression of PSP1 enhances growth of transgenic Arabidopsis plants under ambient air conditions.

Science.gov (United States)

Han, Xiaofang; Peng, Keli; Wu, Haixia; Song, Shanshan; Zhu, Yerong; Bai, Yanling; Wang, Yong

2017-07-01

The importance of the phosphorylated pathway (PPSB) of L-serine (Ser) biosynthesis in plant growth and development has been demonstrated, but its specific role in leaves and interaction with photorespiration, the main leaf Ser biosynthetic pathway at daytime, are still unclear. To investigate whether changes in biosynthesis of Ser by the PPSB in leaves could have an impact on photorespiration and plant growth, we overexpressed PSP1, the last enzyme of this pathway, under control of the Cauliflower Mosaic Virus 35S promoter in Arabidopsis thaliana. Overexpressor plants grown in normal air displayed larger rosette diameter and leaf area as well as higher fresh and dry weight than the wild type. By contrast, no statistically significant differences to the wild type were observed when the overexpressor seedlings were transferred to elevated CO 2 , indicating a relationship between PSP1 overexpression and photorespiration. Additionally, the transgenic plants displayed higher photorespiration, an increase in CO 2 net-uptake and stronger expression in the light of genes encoding enzymes involved in photorespiration. We further demonstrated that expression of many genes involved in nitrogen assimilation was also promoted in leaves of transgenic plants and that leaf nitrate reductase activity increased in the light, too, although not in the dark. Our results suggest a close correlation between the function of PPSB and photorespiration, and also nitrogen metabolism in leaves.

3D painting documentation: evaluation of conservation conditions with 3D imaging and ranging techniques

Directory of Open Access Journals (Sweden)

D. Abate

2014-06-01

Full Text Available The monitoring of paintings, both on canvas and wooden support, is a crucial issue for the preservation and conservation of this kind of artworks. Many environmental factors (e.g. humidity, temperature, illumination, etc., as well as bad conservation practices (e.g. wrong restorations, inappropriate locations, etc., can compromise the material conditions over time and deteriorate an artwork. The article presents an on-going project realized by a multidisciplinary team composed by the ENEA UTICT 3D GraphLab, the 3D Optical Metrology Unit of the Bruno Kessler Foundation and the Soprintendenza per i Beni Storico Artistici ed Etnoantropologici of Bologna (Italy. The goal of the project is the multi-temporal 3D documentation and monitoring of paintings – at the moment in bad conservation’s situation - and the provision of some metrics to quantify the deformations and damages.

Preparation of water paint by radiation

International Nuclear Information System (INIS)

Makuuchi, Keizo

1984-01-01

The development of coatings which do not require any organic solvent have been the social needs. The emulsion made by radiation method is considered to meet possibly this requirement, but it has not been utilized well in the application to water paint. In this review, the investigation concerning the synthesis of water paint raw material by radiation is summarized. In the introduction, radiation curing, water paint and radiation emulsion polymerization are outlined, in the section of γ-ray emulsion polymerization, clean emulsion, cross-linked polymer particles and low temperature polymerization are described, and in the section of paint characteristics of radiation-induced emulsion-polymerized emulsion, the synthesis of thermosetting emulsion, the relation between the method of polymerization and the properties of emulsion, the performance of coating film, and self-hardening emulsion are explained. In the following section of skin-core double layer structured particle emulsion, skin-core double layer structured particles, optimal monomer composition, optimal polymerization process, the manufacturing test with a pilot plant, the performance of the paint, the durability of skin-core double layer structured particle coating film and low temperature curing water paint are described, and in the section of synthesis of emulsion by utilization of electron beam, electron beam emulsion polymerization and the synthesis of water paint by electron beam graft polymerization are described. (Yoshitake, I.)

Denotative and connotative meanings of paintings

Directory of Open Access Journals (Sweden)

Vasić Sandra

2007-01-01

Full Text Available In this study the relationships between judgments of paintings denotative and connotative meanings was investigated. Denotative domain was defined as motif (represented object, e.g. portrait, landscape etc. and message (information carried by paintings, e.g. celebration of patriotism. Connotative domain was defined as subjective experience, i.e. affective or metaphoric impression produced by painting (e.g. feeling of pleasure, impression of dynamics, and so on. In preliminary study the list of 39 motifs was specified empirically. The four dimensions of pictorial message were taken from the previous study (Marković, 2006: Subjectivism, Ideology, Decoration and Constructivism vs. Realism. The four dimensions of paintings subjective experience were taken from the previous study as well (Radonjić and Marković, 2005: Regularity, Attraction, Arousal and Relaxation. In Experiment 1 subjects were asked to associate 39 motifs with 18 paintings. In Experiment 2 subjects were asked to judge 24 paintings on four dimensions of pictorial message. Results form Experiment 1 have shown that dimensions of paintings subjective experience were significantly correlated with only five motifs (e.g. everyday life was negatively correlated with Arousal, battle was negatively correlated with Relaxation, and so on. Results from Experiment 2 have shown that Subjectivism and Constructivism are negatively correlated with Regularity, and positively correlated with Arousal. Decoration is negatively correlated with Arousal and positively with Attraction and Relaxation.

Feasibility of dose painting using volumetric modulated arc optimization and delivery

DEFF Research Database (Denmark)

Korreman, Stine; Ulrich, Silke; Bowen, Stephen

2010-01-01

Dose painting strategies are limited by optimization algorithms in treatment planning systems and physical constraints of the beam delivery. We investigate dose conformity using the RapidArc optimizer and beam delivery technique. Furthermore, robustness of the plans with respect to positioning un...

Investigating the effect of artists’ paint formulation on degradation rates of TiO2‑based oil paints

NARCIS (Netherlands)

van Driel, B.A.; van den Berg, K. J.; Smout, M.; Dekker, N; Kooyman, P.J.; Dik, J.

2018-01-01

This study reports on the effect of artists’ paint formulation on degradation rates of TiO2-based oil paints. Titanium white oil paint exists in a multitude of different recipes, and the effect of the formulation on photocatalytic binder
degradation kinetics is unknown. These formulations

Application of automotive paint sludge in the production of white ceramic

International Nuclear Information System (INIS)

Praxedes, P.B.; Ponte, H.A.; Mymrine, V.

2016-01-01

Full text: Paint wastes of an automotive industry were evaluated in terms of their chemical and mineralogical characteristics in order to analyse its potential use as a reinforcing agent in white ceramic. Both kaolin and sludge paint were analysed using the techniques of XRF, XRD, SEM, EDS. In order to understand the behaviour of the sludge during firing, TGA and DTA analysis were done. Samples containing kaolin and 0, 1, 2, 4 and 8 (wt.%) sludge paint were prepared. The ceramics were compacted at 10MPa and sintered at 1000 °C, 1200 °C, 1250 °C and 1300 °C. Water absorption, linear shrinkage and flexural strength were the mechanical properties evaluated in the samples. The experimental results showed that the samples with lagers amounts of sludge performed better or similar to the samples that only contained kaolin. The insertion of 8 (wt.%) of sludge in the specimen increased flexural strength in 63%. (author)

Density determination of nail polishes and paint chips using magnetic levitation

Science.gov (United States)

Huang, Peggy P.

Trace evidence is often small, easily overlooked, and difficult to analyze. This study describes a nondestructive method to separate and accurately determine the density of trace evidence samples, specifically nail polish and paint chip using magnetic levitation (MagLev). By determining the levitation height of each sample in the MagLev device, the density of the sample is back extrapolated using a standard density bead linear regression line. The results show that MagLev distinguishes among eight clear nail polishes, including samples from the same manufacturer; separates select colored nail polishes from the same manufacturer; can determine the density range of household paint chips; and shows limited levitation for unknown paint chips. MagLev provides a simple, affordable, and nondestructive means of determining density. The addition of co-solutes to the paramagnetic solution to expand the density range may result in greater discriminatory power and separation and lead to further applications of this technique.

The putative thiosulfate sulfurtransferases PspE and GlpE contribute to virulence of Salmonella Typhimurium in the mouse model of systemic disease.

Directory of Open Access Journals (Sweden)

Inke Wallrodt

Full Text Available The phage-shock protein PspE and GlpE of the glycerol 3-phosphate regulon of Salmonella enterica serovar Typhimurium are predicted to belong to the class of thiosulfate sulfurtransferases, enzymes that traffic sulfur between molecules. In the present study we demonstrated that the two genes contribute to S. Typhimurium virulence, as a glpE and pspE double deletion strain showed significantly decreased virulence in a mouse model of systemic infection. However, challenge of cultured epithelial cells and macrophages did not reveal any virulence-associated phenotypes. We hypothesized that their contribution to virulence could be in sulfur metabolism or by contributing to resistance to nitric oxide, oxidative stress, or cyanide detoxification. In vitro studies demonstrated that glpE but not pspE was important for resistance to H2O2. Since the double mutant, which was the one affected in virulence, was not affected in this assay, we concluded that resistance to oxidative stress and the virulence phenotype was most likely not linked. The two genes did not contribute to nitric oxid stress, to synthesis of essential sulfur containing amino acids, nor to detoxification of cyanide. Currently, the precise mechanism by which they contribute to virulence remains elusive.

Effect of paint fumes on histoarchitecture of the testes of adult male ...

African Journals Online (AJOL)

abdominal incision was performed after which one testis was received from each rats, preserved in 10% formal saline and further processed for histological study using Hematoxylin and eosin technique. Results: The testes of the paint fumes ...

LSST Painting Risk Evaluation Memo

Energy Technology Data Exchange (ETDEWEB)

Wolfe, Justin E. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2016-11-10

The optics subsystem is required to paint the edges of optics black where possible. Due to the risks in applying the paint LSST requests a review of the impact of removing this requirement for the filters and L3.

Internal contamination by tritium caused by radioluminescent paints

Energy Technology Data Exchange (ETDEWEB)

Adamiak-Ziemba, J.; Doniec, J.

1985-01-01

The internal contamination investigations covered 23 persons using radioluminescence paints containing tritium, assembling devices painted with those paints, and those having no contact with active paints but working next to the painting room. Determined were concentrations of tritium excreted with urine, air contamination at workplaces, contamination of workplace areas and hand skin. At the time covered by the investigations, the mean annual equivalent doses for those using tritium paints were reduced from 14-20 mSv to about 5 mSv. In those working next to the painting room they were reduced from 5.8-15 to 0.23 mSv. The exposure of those assembling the devices does not exceed 1 mSv. It was demonstrated that the main cause of the tritium exposure level was air contamination in working rooms.

Chromatic changes to artificial irises produced using different techniques

Science.gov (United States)

Bannwart, Lisiane Cristina; Goiato, Marcelo Coelho; dos Santos, Daniela Micheline; Moreno, Amália; Pesqueira, Aldiéris Alves; Haddad, Marcela Filié; Andreotti, Agda Marobo; de Medeiros, Rodrigo Antonio

2013-05-01

Ocular prostheses are important determinants of their users' aesthetic recovery and self-esteem. Because of use, ocular prostheses longevity is strongly affected by instability of the iris color due to polymerization. The goal of this study is to examine how the color of the artificial iris button is affected by different techniques of artificial wear and by the application of varnish following polymerization of the colorless acrylic resin that covers the colored paint. We produce 60 samples (n=10) according to the wear technique applied: conventional technique without varnish (PE); conventional technique with varnish (PEV); technique involving a prefabricated cap without varnish (CA); technique involving a prefabricated cap with varnish (CAV); technique involving inverted painting without varnish (PI); and technique involving inverted painting with varnish (PIV). Color readings using a spectrophotometer are taken before and after polymerization. We submitted the data obtained to analyses of variance and Tukey's test (P<0.05). The color test shows significant changes after polymerization in all groups. The PE and PI techniques have clinically acceptable values of ΔE, independent of whether we apply varnish to protect the paint. The PI technique produces the least color change, whereas the PE and CA techniques significantly improve color stability.

Forensic Art History: the Ädel Painting Dispute 1839-1841

Directory of Open Access Journals (Sweden)

Ingalill Nyström

2018-03-01

Full Text Available This article concerns a 19th century dispute about twenty pieces of decorated furniture painted by the 19th century painter Anders Erik Ädel (1809-1888 from Söderhamn, Hälsingland, Sweden. Ädel is considered to be one of the foremost painters in Hälsingland. His art works - painted furniture and interiors - are displayed in museums and can also be found in the Decorated Farmhouses of Hälsingland, UNESCO World Heritage. In 1839, Ädel accused his client, the farmer Erik Olofsson, in court of having paid too little for the objects he had painted as he had used more pigments than those for which he had been paid. Almost 180 years later scientific methods combined with historic source research were used to understand what pigments Ädel actually used. Through this study we demonstrate how multidisciplinary collaboration between sciences and humanities can contribute to deeper knowledge and new interpretations. The scientific analyses were preceded by analyses of the judicial protocols found. Non-invasive analyses using XRF instruments were conducted in situ, supplemented by other spectroscopic methods in the lab. The judicial protocols give an insight into what pigments Ädel had access to, and when combined with the scientific analyses, this information provides historic evidence of the artist's materials and painting technique.

Contribution of the microbial communities detected on an oil painting on canvas to its biodeterioration.

Directory of Open Access Journals (Sweden)

María Del Mar López-Miras

Full Text Available In this study, we investigated the microbial community (bacteria and fungi colonising an oil painting on canvas, which showed visible signs of biodeterioration. A combined strategy, comprising culture-dependent and -independent techniques, was selected. The results derived from the two techniques were disparate. Most of the isolated bacterial strains belonged to related species of the phylum Firmicutes, as Bacillus sp. and Paenisporosarcina sp., whereas the majority of the non-cultivable members of the bacterial community were shown to be related to species of the phylum Proteobacteria, as Stenotrophomonas sp. Fungal communities also showed discrepancies: the isolated fungal strains belonged to different genera of the order Eurotiales, as Penicillium and Eurotium, and the non-cultivable belonged to species of the order Pleosporales and Saccharomycetales. The cultivable microorganisms, which exhibited enzymatic activities related to the deterioration processes, were selected to evaluate their biodeteriorative potential on canvas paintings; namely Arthrobacter sp. as the representative bacterium and Penicillium sp. as the representative fungus. With this aim, a sample taken from the painting studied in this work was examined to determine the stratigraphic sequence of its cross-section. From this information, "mock paintings," simulating the structure of the original painting, were prepared, inoculated with the selected bacterial and fungal strains, and subsequently examined by micro-Fourier Transform Infrared spectroscopy, in order to determine their potential susceptibility to microbial degradation. The FTIR-spectra revealed that neither Arthrobacter sp. nor Penicillium sp. alone, were able to induce chemical changes on the various materials used to prepare "mock paintings." Only when inoculated together, could a synergistic effect on the FTIR-spectra be observed, in the form of a variation in band position on the spectrum.

Neural correlates of viewing paintings

DEFF Research Database (Denmark)

Vartanian, Oshin; Skov, Martin

2014-01-01

Many studies involving functional magnetic resonance imaging (fMRI) have exposed participants to paintings under varying task demands. To isolate neural systems that are activated reliably across fMRI studies in response to viewing paintings regardless of variation in task demands, a quantitative...

A portable X-ray diffraction apparatus for in situ analyses of masters' paintings

Science.gov (United States)

Eveno, Myriam; Duran, Adrian; Castaing, Jacques

2010-09-01

It is rare that the analyses of materials in paintings can be carried out by taking micro-samples. Valuable works of art are best studied in situ by non-invasive techniques. For that purpose, a portable X-ray diffraction and fluorescence apparatus has been designed and constructed at the C2RMF. This apparatus has been used for paintings of Rembrandt, Leonardo da Vinci, Van Gogh, Mantegna, etc. Results are given to illustrate the performance of X-ray diffraction, especially when X-ray fluorescence does not bring sufficient information to conclude.

A portable X-ray diffraction apparatus for in situ analyses of masters' paintings

International Nuclear Information System (INIS)

Eveno, Myriam; Duran, Adrian; Castaing, Jacques

2010-01-01

It is rare that the analyses of materials in paintings can be carried out by taking micro-samples. Valuable works of art are best studied in situ by non-invasive techniques. For that purpose, a portable X-ray diffraction and fluorescence apparatus has been designed and constructed at the C2RMF. This apparatus has been used for paintings of Rembrandt, Leonardo da Vinci, Van Gogh, Mantegna, etc. Results are given to illustrate the performance of X-ray diffraction, especially when X-ray fluorescence does not bring sufficient information to conclude. (orig.)

New biocides for antifouling paints

International Nuclear Information System (INIS)

Mazziotti, Isabella; Massanisso, Paolo; Cremisini, Carlo; Chiavarini, Salvatore; Fantini, Michele; Morabito, Roberto

2005-01-01

The antifouling paints are used for protecting the hulls of the boasts from the undesirable accumulation of micro-organisms, plants, and animals on artificial surfaces (marine biological fouling). These paints constitute a potential risk for the marine environment, because of the presence in their formulation, among the other potentially toxic components, of organic compounds acting as biocide. The environmental problems associated with the use of the organotin compounds as biocides in the antifouling paints, have lead to the international ban of these compounds. In the article the new antifouling paints coming up the national and international market are shortly introduced and discussed, with particular attention respect to the new organic compounds used as biocides. In Italy quite a few marine monitoring campaigns have been carried out for organotin compounds, on the contrary there is a lack of data regarding the presence of other biocides [it

XRF, μ-XRD and μ-spectroscopic techniques for revealing the composition and structure of paint layers on polychrome sculptures after multiple restorations.

Science.gov (United States)

Franquelo, M L; Duran, A; Castaing, J; Arquillo, D; Perez-Rodriguez, J L

2012-01-30

This paper presents the novel application of recently developed analytical techniques to the study of paint layers on sculptures that have been restored/repainted several times across centuries. Analyses were performed using portable XRF, μ-XRD and μ-Raman instruments. Other techniques, such as optical microscopy, SEM-EDX and μ-FTIR, were also used. Pigments and other materials including vermilion, minium, red lac, ivory black, lead white, barium white, zinc white (zincite), titanium white (rutile and anatase), lithopone, gold and brass were detected. Pigments from both ancient and modern times were found due to the different restorations/repaintings carried out. μ-Raman was very useful to characterise some pigments that were difficult to determine by μ-XRD. In some cases, pigments identification was only possible by combining results from the different analytical techniques used in this work. This work is the first article devoted to the study of sculpture cross-section samples using laboratory-made μ-XRD systems. Copyright © 2011 Elsevier B.V. All rights reserved.

Mural Painting as Inclusive Art Learning Experience

Science.gov (United States)

Ho, Kong

2010-01-01

Traditional art education, like other academic disciplines, emphasizes competitiveness and individualism. Through a mural painting curriculum, learners participate in mural art and history appreciation, are active in mural theme or content construction, and engage in hands-on mural design and painting processes. When mural paintings are produced…

Troubled traces: painting and displaying intercultural traumas of Aboriginality

Directory of Open Access Journals (Sweden)

Heather Kamarra Shearer

2014-10-01

Full Text Available Behind the pointillism of dot paintings or ‘naïve’ techniques, Aboriginal artists stridently critique histories of injustice, incarceration, racism, colonialism and dispossession. This personal testimony from Heather Kamarra Shearer, one of the ‘stolen generation’ of Aboriginal Australians, reflects on her life story and her present vocation in the field of legal rights and as an artist.

Investigation of Layer Structure of the Takamatsuzuka Mural Paintings by Terahertz Imaging Technique

Science.gov (United States)

Inuzuka, M.; Kouzuma, Y.; Sugioka, N.; Fukunaga, K.; Tateishi, T.

2017-04-01

Terahertz imaging can be a powerful tool in conservation science for cultural heritages. In this study, a new terahertz imaging system was applied to the Takamatsuzuka mural painting of a blue dragon, and the condition of the plaster layer was diagnosed. As a result, the locations where the plaster layer appears solid on the surface but in actuality may have peeled off the underlying tuff stone were revealed and viewed as two-dimensional images.

Salt damage of stone, plaster and painted layers at a medieval church, South-Hungary

Science.gov (United States)

Török, Ákos; Galambos, Éva

2016-04-01

The Chapel of Pécsvárad is one of the best preserved and oldest medieval stone monument in South Hungary. It dates back to the 11th century. The interior of the chapel is decorated with wall paintings, which are later and probably originating from the late 12th century. The wall painting is partly preserved and it is located on an interior stone wall of the chapel facing to the East. The wall painting shows various forms of damage from salt efflorescence to chipping. The current research provides information on the in situ and laboratory analyses of salts, plasters, pigments and stone material suggesting mechanisms of decay that lead to partial loss of the painting. Both on site techniques and laboratory analyses were performed. Imaging techniques such as UV luminescence and IR thermography were used to identify the moist and salt covered zones on the wall surface. Portable moisture meter were also applied to map the wet zones in the interior and also at the external part of the chapel. Schmidt hammer and Duroscop were used for testing the surface strength of stone. Laboratory tests were focused on mineralogical and chemical compositional analyses. Small samples of stone, mortar, plaster and pigments were tested by optical microscopy, SEM-EDX, XRD and Thermogravimetric analyses. According to our tests the chapel was predominantly made of porous limestone and sandstone. Laboratory analyses proved that the major salt responsible for the damage of external walls are gypsum and halite, while in the interior part higher amount of halite and significant amount of sodium-nitrate were found besides gypsum. The painted layers are on Byzantine-type of plaster with organic compounds (plant fragments) and with a substrate layer rich in calcium carbonate. The identified pigments are dominantly earth pigments such as iron-oxide containing red and yellow (ochre) and green earth. A unique preservation of ultramarine blue in Hungary was found on the wall painting. The partial

Examination of lead concentrations in new decorative enamel paints in four countries with different histories of activity in lead paint regulation

International Nuclear Information System (INIS)

Clark, C. Scott; Kumar, Abhay; Mohapatra, Piyush; Rajankar, Prashant; Nycz, Zuleica; Hambartsumyan, Amalia; Astanina, Lydia; Roda, Sandy; Lind, Caroline; Menrath, William; Peng, Hongying

2014-01-01

Paints with high lead concentrations (ppm) continue to be sold around the world in many developing countries and those with economies in transition representing a major preventable environmental health hazard that is being increased as the economies expand and paint consumption is increasing. Prior lead paint testing had been performed in Brazil and India and these countries were selected to examine the impact of a new regulatory limit in Brazil and the impact of efforts of non-governmental organizations and others to stop the use of lead compounds in manufacturing paints. Armenia and Kazakhstan, in Central Asia, were selected because no information on lead concentration in those regions was available, no regulatory activities were evident and non-governmental organizations in the IPEN network were available to participate. Another objective of this research was to evaluate the lead loading (µg/cm 2 ) limit determined by X-Ray Fluorescence (XRF) for areas on toys that are too small to obtain a sample of sufficient size for laboratory analysis. The lead concentrations in more than three-fourths of the paints from Armenia and Kazakhstan exceeded 90 ppm, the limit in the United States, and 600 ppm, the limit in Brazil. The percentages were about one-half as high in Brazil and India. The average concentration in paints purchased in Armenia, 25,000 ppm, is among the highest that has been previously reported, that in Kazakhstan, 15,700 ppm, and India, 16,600, about median. The average concentration in Brazil, 5600 ppm, is among the lowest observed. Paints in Brazil that contained an average of 36,000 ppm before the regulatory limit became effective were below detection (<9 ppm) in samples collected in the current study. The lack of any apparent public monitoring of paint lead content as part of regulatory enforcement makes it difficult to determine whether the regulation was a major factor contributing to the decline in lead use in these paints. Using data from the

STUDY OF SOME ARCHAEOMETRIC CHARACTERISTICS USED IN PANEL PAINTING ICONS AUTHENTICATION

Directory of Open Access Journals (Sweden)

Raluca Anamaria Cristache

2014-12-01

Full Text Available The authentication of cultural heritage assets is a complex process of scientific investigation which regards obtaining information about: author (painter, the period when it was made, the owners and other data related to the main contexts of their evolution in time (routes travelled. In fact, the identification of specific archaeometric features is aimed, in determining the materials composition and the patina, then the study of artistic techniques and technology used in the making process of a work of art. Latest serves to define the patrimonial elements and the role of the artifact in time. The expertise of old panel painting icons requires an interdisciplinary approach, correlating the artistic style with technique and materials used. In this regard, the specific techniques of microscopy and spectroscopy are very useful tools for determining the composition of structural elements and their deterioration / degradation state. This work presents a comparative study of the paper used in the preparation layer of three icons painted in Russian style. As an analysis techniques were used the micro and macro photography assisted by Optical Microscopy (OM, SEM-EDX and micro-FTIR. Based on the experimental data obtained, it was found that the icons belong to the first half of the 19th century.

Coherent x-ray diffraction imaging of paint pigment particles by scanning a phase plate modulator

International Nuclear Information System (INIS)

Chu, Y.S.; Chen, B.; Zhang, F.; Berenguer, F.; Bean, R.; Kewish, C.; Vila-Comamala, J.; Rodenburg, J.; Robinson, I.

2011-01-01

We have implemented a coherent x-ray diffraction imaging technique that scans a phase plate to modulate wave-fronts of the x-ray beam transmitted by samples. The method was applied to measure a decorative alkyd paint containing iron oxide red pigment particles. By employing an iterative algorithm for wave-front modulation phase retrieval, we obtained an image of the paint sample that shows the distribution of the pigment particles and is consistent with the result obtained from a transmission x-ray microscope. The technique has been experimentally proven to be a feasible coherent x-ray imaging method with about 120 nm spatial resolution and was shown to work well with industrially relevant specimens.

Spectrally selective paint coatings. Preparation and characterization

Energy Technology Data Exchange (ETDEWEB)

Crnjak Orel, Z.C.; Klanjsek Gunde, M. [National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana (Slovenia)

2001-06-01

Preparation and characterization of spectrally selective paint coating for photothermal solar energy conversion are discussed. The applied methods for preparation of paints with described measurements and calculations of black-pigmented coatings were reviewed. The article represents not only possible future applications but also past and current applications of spectrally selective paint coating which are used all over the world since the 1980s. Spectrally selective paint coatings based on combinations of two types of resins, various types of pigments and three types of silica, were prepared. The influence of pigment type and pigment volume concentration (PVC) was studied by applying the Kubelka-Munk (K-M) theory. The relation between the degrees of dispersion and distribution of pigment particles across the paint layer is discussed in terms of K-M coefficients.

Painting Reproductions on Display

Directory of Open Access Journals (Sweden)

Joanna Iranowska

2017-09-01

Full Text Available Paintings in museums might occasionally be replaced by a photoprint mimicking the original. This article is an investigation of what constitutes a good reproduction of an artwork (oil painting that is meant to be displayed. The article discusses what the usefulness of reproductions depends on, applying the Valuation Studies approach, which means the primary concern is with the practice of valuing itself. In other words, the study focuses on how museum experts evaluate reproduc-tions of oil paintings. The article analyses three cases of displaying digitally prin-ted copies of Edvard Munch's oil paintings between 2013 and 2015 in the Munch Museum and in the National Gallery in Oslo. The study is based on a series of semi-structured interviews with the experts, working at and for the museums, that were involved in producing and exhibiting of the photoprints: curators, con-servators, museum educators, and external manufacturers. The interviews were grouped into five clusters, which I have chosen to call registers of valuing following Frank Heuts and Annemarie Mol (2013. The described valuation practices have to do with delivering experiences to the public, obtaining mimetic resemblance, solving ethical aspects, exhibitions' budget, and last but not least, with the time perspective.

Zinc, Paint loss and Harmony in blue

DEFF Research Database (Denmark)

Vila, Anna; Krarup Andersen, Cecil; Baadsgaard, Elizabeth

2016-01-01

P.S. Krøyer’s late and most popular paintings have proven very difficult to preserve, and as zinc white has been known to cause structural problems in paintings, the authors investigate if the damage seen in the late paintings can be related to the use of this relatively new pigment. Eight painti...

Characterization of constitutive materials and technology of the mural painting of the acropolis of the archaeological zone of Ek Balam, Yucatan, Mexico

International Nuclear Information System (INIS)

Alonso O, A.; Vazquez N, J.; Ruiz M, C.; Mendoza A, D.; Espinosa P, M.; Ruvalcaba, J.L.; Vandenabeele, P.

2005-01-01

The conservation project of Ek'Balam is one of the few experiences of systematic conservation applied in an archaeological Maya site at the Yucatan Peninsula in Mexico. The project started in the year 2001 when important stone, stucco and painting decorations were discovered during archaeological excavations. Being a recently discovered site, the conservation program includes a research program based on particular conservation issues detected as potential risk of archaeological data losses. One of the research topics is based on deter- mining the ancient painting technology used in mural and stucco decorations through the characterization of building and decorative composite materials. Archaeometric techniques have been used to fulfil the proposed goal. Raman, X-ray Fluorescence, Light and Electron Microscopy were practiced on a set of 35 wall painting samples. Preliminary results obtained on pigments characterization have partially revealed general features of wall painting technique at Ek'Balam during the late Classic period. Some particular pigments, not reported ever for mural paintings, have been identified in Ek'Balam samples. (Author)

SPECIFIC FEATURES OF THE PORTRAIT IN NATIONAL PAINTING AND SCULPTURE (1945-1960

Directory of Open Access Journals (Sweden)

LOZOVANU VLADIMIR

2016-12-01

Full Text Available The present article is devoted to the peculiarities of the portrait in national painting and sculpture in the period of the 1950s. The text refl ects the creation of prominent artists who have realized the most famous portrait works. The author presents examples of representative portraits and they are analysed in the context of the period we refer to. He identifies both the methods, techniques, the ideas and aspiration of plastic artists who have practised portrait art. the presented information is useful to artists and teachers working in the fi eld of visual arts and to students who are interested in portrait painting.

Conservation of 19th and early 20th century oil paintings - in situ studies using the environmental scanning electron microscope

International Nuclear Information System (INIS)

White, R.; Phillips, M.; Wuhrer, R.; Thomas, D.

2003-01-01

Full text: Most 19th and early 20th century oil paintings suffer from fading, discolouration, pitting, cracking swelling or the loss of material due to the embrittlement or the extreme friability of the paint layers. As a consequence of this deterioration, they require special care by experienced conservators to ensure their continued preservation. These aging processes are a consequence of (i) chemical interactions between pigments, oils and binders used by the artist and (ii) the action of air, water and ultra-violet irradiation on these materials. The influence of chemical interactions is pertinent for paintings of this era as the industrial revolution brought forth new colourful chemicals that were quickly adopted as pigments with varying success. The conservation of oil paintings requires an understanding of the individual structure of each work of art and what mechanisms underlie its deterioration. This generally involves the need for (i) correct identification of the pigments used by the artist, (ii) a detailed knowledge of the chemical interaction between these pigments, (iii) an understanding of the artist's method of mixing colours and laying paint on the canvas and (iv) a detailed knowledge of the role of the atmosphere, moisture and UV irradiation on painting deterioration. In addition to dealing with the deterioration that occurs within the painting, conservators spend a large portion of their time correcting earlier failed conservation attempts. Most oil paintings from this era are valuable from an artistic or historic perspective and only an extremely small sample may be excised from the work, hence microscopy is an indispensable technique in art preservation. Optical microscopy is the core analysis technique used, however, in recent years a limited number of conservators have begun to use Environmental scanning electron microscopy (ESEM) technology to examine paint layers to take advantage of the accurate and rapid identification of elements present

Paint Scaler. Innovative Technology Summary Report

International Nuclear Information System (INIS)

None

2000-01-01

The Paint Scaler can collect paint samples quickly and efficiently for lab analysis. The Rotary Hammer Drill is a 24-V battery operated, 3/4-in. rotary hammer drill. When used with an optional chipping adapter, the Bosch Rotary Hammer Drill can be used to perform chipping and chiseling tasks such as paint removal from either concrete or metal surfaces. It is ultra-compact, lightweight with an ergonomic balanced grip. The battery operation gives the operator more flexibility during sampling activities

Serum levels of pancreatic stone protein (PSP/reg1A as an indicator of beta-cell apoptosis suggest an increased apoptosis rate in hepatocyte nuclear factor 1 alpha (HNF1A-MODY carriers from the third decade of life onward

Directory of Open Access Journals (Sweden)

Bacon Siobhan

2012-07-01

Full Text Available Abstract Background Mutations in the transcription factor hepatocyte nuclear factor-1-alpha (HNF1A result in the commonest type of maturity onset diabetes of the young (MODY. HNF1A-MODY carriers have reduced pancreatic beta cell mass, partially due to an increased rate of apoptosis. To date, it has not been possible to determine when apoptosis is occurring in HNF1A-MODY.We have recently demonstrated that beta cell apoptosis stimulates the expression of the pancreatic stone protein/regenerating (PSP/reg gene in surviving neighbour cells, and that PSP/reg1A protein is subsequently secreted from these cells. The objective of this study was to determine whether serum levels of PSP/reg1A are elevated during disease progression in HNF1A-MODY carriers, and whether it may provide information regarding the onset of beta-cell apoptosis. Methods We analysed serum PSP/reg1A levels and correlated with clinical and biochemical parameters in subjects with HNF1A-MODY, glucokinase (GCK-MODY, and type 1 diabetes mellitus. A control group of normoglycaemic subjects was also analysed. Results PSP/reg1A serum levels were significantly elevated in HNF1A-MODY (n = 37 subjects compared to controls (n = 60 (median = 12.50 ng/ml, IQR = 10.61-17.87 ng/ml versus median = 10.72 ng/ml, IQR = 8.94-12.54 ng/ml, p = 0.0008. PSP/reg1A correlated negatively with insulin levels during OGTT, (rho = −0.40, p = 0.02. Interestingly we noted a significant positive correlation of PSP/reg1A with age of the HNF1A-MODY carriers (rho = 0.40 p = 0.02 with an age of 25 years separating carriers with low and high PSP/reg1A levels. Patients with type 1 diabetes mellitus also had elevated serum levels of PSP/reg1A compared to controls, however this was independent of the duration of diabetes. Conclusion Our data suggest that beta cell apoptosis contributes increasingly to the pathophysiology of HNF1A-MODY in patients 25 years and over

Serum levels of pancreatic stone protein (PSP)/reg1A as an indicator of beta-cell apoptosis suggest an increased apoptosis rate in hepatocyte nuclear factor 1 alpha (HNF1A-MODY) carriers from the third decade of life onward

LENUS (Irish Health Repository)

Bacon, Siobhan

2012-07-18

AbstractBackgroundMutations in the transcription factor hepatocyte nuclear factor-1-alpha (HNF1A) result in the commonest type of maturity onset diabetes of the young (MODY). HNF1A-MODY carriers have reduced pancreatic beta cell mass, partially due to an increased rate of apoptosis. To date, it has not been possible to determine when apoptosis is occurring in HNF1A-MODY.We have recently demonstrated that beta cell apoptosis stimulates the expression of the pancreatic stone protein\\/regenerating (PSP\\/reg) gene in surviving neighbour cells, and that PSP\\/reg1A protein is subsequently secreted from these cells. The objective of this study was to determine whether serum levels of PSP\\/reg1A are elevated during disease progression in HNF1A-MODY carriers, and whether it may provide information regarding the onset of beta-cell apoptosis.MethodsWe analysed serum PSP\\/reg1A levels and correlated with clinical and biochemical parameters in subjects with HNF1A-MODY, glucokinase (GCK-MODY), and type 1 diabetes mellitus. A control group of normoglycaemic subjects was also analysed.ResultsPSP\\/reg1A serum levels were significantly elevated in HNF1A-MODY (n = 37) subjects compared to controls (n = 60) (median = 12.50 ng\\/ml, IQR = 10.61-17.87 ng\\/ml versus median = 10.72 ng\\/ml, IQR = 8.94-12.54 ng\\/ml, p = 0.0008). PSP\\/reg1A correlated negatively with insulin levels during OGTT, (rho = −0.40, p = 0.02). Interestingly we noted a significant positive correlation of PSP\\/reg1A with age of the HNF1A-MODY carriers (rho = 0.40 p = 0.02) with an age of 25 years separating carriers with low and high PSP\\/reg1A levels. Patients with type 1 diabetes mellitus also had elevated serum levels of PSP\\/reg1A compared to controls, however this was independent of the duration of diabetes.ConclusionOur data suggest that beta cell apoptosis contributes increasingly to the pathophysiology of HNF1A-MODY in patients 25 years and

Examination of lead concentrations in new decorative enamel paints in four countries with different histories of activity in lead paint regulation

Energy Technology Data Exchange (ETDEWEB)

Clark, C. Scott, E-mail: clarkcs@ucmail.uc.edu [Department of Environmental Health, University of Cincinnati (United States); International POPS Elimination Network (IPEN), San Francisco (United States); Kumar, Abhay; Mohapatra, Piyush; Rajankar, Prashant [Toxics Link, New Delhi (India); Nycz, Zuleica [APROMAC Environmental Protection Association and Toxisphera Environmental Health Association, Curitiba, Parana (Brazil); Hambartsumyan, Amalia [Greenwomen, Almaty (Kazakhstan); Astanina, Lydia [Khazer Ecological and Cultural Non-Governmental Organization, Yerevan (Armenia); Roda, Sandy; Lind, Caroline; Menrath, William; Peng, Hongying [Department of Environmental Health, University of Cincinnati (United States)

2014-07-15

Paints with high lead concentrations (ppm) continue to be sold around the world in many developing countries and those with economies in transition representing a major preventable environmental health hazard that is being increased as the economies expand and paint consumption is increasing. Prior lead paint testing had been performed in Brazil and India and these countries were selected to examine the impact of a new regulatory limit in Brazil and the impact of efforts of non-governmental organizations and others to stop the use of lead compounds in manufacturing paints. Armenia and Kazakhstan, in Central Asia, were selected because no information on lead concentration in those regions was available, no regulatory activities were evident and non-governmental organizations in the IPEN network were available to participate. Another objective of this research was to evaluate the lead loading (µg/cm{sup 2}) limit determined by X-Ray Fluorescence (XRF) for areas on toys that are too small to obtain a sample of sufficient size for laboratory analysis. The lead concentrations in more than three-fourths of the paints from Armenia and Kazakhstan exceeded 90 ppm, the limit in the United States, and 600 ppm, the limit in Brazil. The percentages were about one-half as high in Brazil and India. The average concentration in paints purchased in Armenia, 25,000 ppm, is among the highest that has been previously reported, that in Kazakhstan, 15,700 ppm, and India, 16,600, about median. The average concentration in Brazil, 5600 ppm, is among the lowest observed. Paints in Brazil that contained an average of 36,000 ppm before the regulatory limit became effective were below detection (<9 ppm) in samples collected in the current study. The lack of any apparent public monitoring of paint lead content as part of regulatory enforcement makes it difficult to determine whether the regulation was a major factor contributing to the decline in lead use in these paints. Using data from the

Sanding dust from nanoparticle-containing paints: Physical characterisation

International Nuclear Information System (INIS)

Koponen, I K; Jensen, K A; Schneider, T

2009-01-01

Increasing use of nanoparticles in different industrial applications has raised a new potential health risk to the workers as well as to the consumers. This study investigates the particle size distributions of sanding dust released from paints produced with and without engineered nanoparticles. Dust emissions from sanding painted plates were found to consist of five size modes; three modes under 1 μm and two modes around 1 and 2 μm. We observed that the sander was the only source of particles smaller than 50 nm and they dominated the number concentration spectra. Mass and surface area spectra were dominated by the 1 and 2 μm modes. Addition of nanoparticles caused only minor changes in the geometric mean diameters of the particle modes generated during sanding of two paints doped with 17 nm TiO2 and 95 nm Carbon Black nanoparticles as compared to the size modes generated during sanding a conventional reference paint. However, the number concentrations in the different size modes varied considerably in between the two NP-doped paints and the reference paint. Therefore, from a physical point of view, there may be a difference in the exposure risk during sanding surfaces covered with nanoparticle-based paints as compared to sanding conventional paints.

24 CFR 35.135 - Use of paint containing lead.

Science.gov (United States)

2010-04-01

... 24 Housing and Urban Development 1 2010-04-01 2010-04-01 false Use of paint containing lead. 35... Urban Development LEAD-BASED PAINT POISONING PREVENTION IN CERTAIN RESIDENTIAL STRUCTURES General Lead-Based Paint Requirements and Definitions for All Programs. § 35.135 Use of paint containing lead. (a...

Water-Based Pressure-Sensitive Paints

Science.gov (United States)

Jordan, Jeffrey D.; Watkins, A. Neal; Oglesby, Donald M.; Ingram, JoAnne L.

2006-01-01

Water-based pressure-sensitive paints (PSPs) have been invented as alternatives to conventional organic-solvent-based pressure-sensitive paints, which are used primarily for indicating distributions of air pressure on wind-tunnel models. Typically, PSPs are sprayed onto aerodynamic models after they have been mounted in wind tunnels. When conventional organic-solvent-based PSPs are used, this practice creates a problem of removing toxic fumes from inside the wind tunnels. The use of water-based PSPs eliminates this problem. The waterbased PSPs offer high performance as pressure indicators, plus all the advantages of common water-based paints (low toxicity, low concentrations of volatile organic compounds, and easy cleanup by use of water).

Radioactive Decontamination by Strippable Paint

International Nuclear Information System (INIS)

Chantaraparprachoom, N.; Mishima, K.

1998-01-01

The strippable paint, one of the adhesion method, is to decontaminate solid surface of materials or/and a large area. Two kinds of specimen planchet, SUS 304 stainless steel and polycarbonate plastic, contaminated with radioactive 137 Cs were studied under various conditions. It included surface bottom types, the flat and convex concentric circle type, normal condition at room temperature and overheat condition (∼80 degree celsius). This method used coating paints which contains some elements to have a reaction with radioactive materials selectively. ALARA-Decon clear, Rempack-X200 clear, JD-P5-Mrs.Coat and Pro-Blue-color guard were selected to use as the coating paints. The contaminated surface was coated by the strippable paint under the optimum time, followed by peeling the paint seal. The Rempack-X200 showed the best result, the highest decontamination efficiency which are about 99-100% for all conditions of specimens. The JD-P5 and ALARA-Decon showed good results, which are 98-99% decontamination efficiency for the normal condition set of specimens and about 94-97% for the overheat set of specimens. They can decontaminate polycarbonate specimens better than stainless steel specimens. The Pro-Blue-color guard showed the lowest decontamination efficiency of which 60% for polycarbonate specimens at normal condition and 40%, 30% for stainless steel specimens at normal and overheat conditions respectively. There was no effects of surface bottom types significantly

Ultraviolet-radiation-curable paints

Energy Technology Data Exchange (ETDEWEB)

Grosset, A M; Su, W F.A.; Vanderglas, E

1981-09-30

In product finishing lines, ultraviolet radiation curing of paints on prefabricated structures could be more energy efficient than curing by natural gas fired ovens, and could eliminate solvent emission. Diffuse ultraviolet light can cure paints on three dimensional metal parts. In the uv curing process, the spectral output of radiation sources must complement the absorption spectra of pigments and photoactive agents. Photosensitive compounds, such as thioxanthones, can photoinitiate unsaturated resins, such as acrylated polyurethanes, by a free radical mechanism. Newly developed cationic photoinitiators, such as sulfonium or iodonium salts (the so-called onium salts) of complex metal halide anions, can be used in polymerization of epoxy paints by ultraviolet light radiation. One-coat enamels, topcoats, and primers have been developed which can be photoinitiated to produce hard, adherent films. This process has been tested in a laboratory scale unit by spray coating these materials on three-dimensional objects and passing them through a tunnel containing uv lamps.

76 FR 27044 - Lead-Based Paint Renovation, Repair and Painting, and Pre-Renovation Education Activities in...

Science.gov (United States)

2011-05-10

..., Repair and Painting, and Pre- Renovation Education Activities in Target Housing and Child Occupied...), and a lead-based paint pre-renovation education program in accordance with section 406(b) of TSCA, 15... renovation and remodeling activities of pre-1978 housing and child-occupied facilities in the State of...

Automotive Painting Technology A Monozukuri-Hitozukuri Perspective

CERN Document Server

Salazar, Abraham; Saito, Kozo

2013-01-01

This book offers unique and valuable contributions to the field. It offers breadth and inclusiveness. Most existing works on automotive painting cover only a single aspect of this complex topic, such as the chemistry of paint or paint booth technology. Monozukuri and Hitozukuri are Japanese terms that can be translated as “making things” and “developing people” but their implications in Japanese are richer and more complex than this minimal translation would indicate. The Monozukuri-Hitozukuri perspective is drawn from essential principles on which the Toyota approach to problem-solving and continuous improvement is based. From this perspective, neither painting technology R&D nor painting technology use in manufacturing can be done successfully without integrating technological and human concerns involved with making and learning in the broadest sense, as the hyphen is meant to indicate. The editors provide case studies and examples -- drawn from Mr. Toda’s 33 years of experience with automotiv...

The use of combined synchrotron radiation micro FT-IR and XRD for the characterization of Romanesque wall paintings

International Nuclear Information System (INIS)

Salvado, N.; Buti, S.; Pantos, E.; Bahrami, F.; Labrador, A.; Pradell, T.

2008-01-01

The high analytical sensitivity and high spatial resolution of synchrotron radiation-based techniques, in particular SR-XRD and SR-FT-IR, allows the identification of complex micrometric mixtures of compounds that constitute the different layers of ancient paintings. The reliability of the measurements even with an extremely small amount of sampled material is very high, and this is particularly important when analyzing art works. Furthermore, the micro size (10 x 10μm for FT-IR and 30 to 50 μm squared spot size for XRD) of the beam enables one to obtain detailed compositional profiles from the different chromatic and preparation layers. The sensitivity of the techniques is high enough for the determination of minor and trace compounds, such as reaction and weathering compounds. We report here the identification of pigments in the Romanesque wall paintings found in situ in the church of Saint Eulalia of Unha place in the Aran valley (central Pyrenees). During the first centuries of the second millennium numerous religious buildings were built in Western Europe in the Romanesque style. In particular, a great number of churches were built in the Pyrenees, most of which were decorated with wall paintings. Although only a few of these paintings have survived, they represent one of the most important collections of Romanesque art, both for their quantity and quality. A full identification of the pigments, binder, supports, and reaction and weathering compounds has been obtained. The results obtained, in particular aerinite as a pigment, indicate a clear connection between the paintings found in this Occitanian church and the Catalan Romanesque paintings from the south bound of the Pyrenees. (orig.)

The use of combined synchrotron radiation micro FT-IR and XRD for the characterization of Romanesque wall paintings

Energy Technology Data Exchange (ETDEWEB)

Salvado, N.; Buti, S. [Universitat Politecnica de Catalunya, Dpt. d' Enginyeria Quimica, EPSEVG, Vilanova i la Geltru, Barcelona (Spain); Pantos, E.; Bahrami, F. [CCLRC, Daresbury Laboratory, Warrington (United Kingdom); Labrador, A. [LLS, BM16-ESRF, BP 220, Grenoble Cedex (France); Pradell, T. [Universitat Politecnica de Catalunya, Dpt. Fisica i Enginyeria Nuclear, ESAB, Castelldefels, Barcelona (Spain)

2008-01-15

The high analytical sensitivity and high spatial resolution of synchrotron radiation-based techniques, in particular SR-XRD and SR-FT-IR, allows the identification of complex micrometric mixtures of compounds that constitute the different layers of ancient paintings. The reliability of the measurements even with an extremely small amount of sampled material is very high, and this is particularly important when analyzing art works. Furthermore, the micro size (10 x 10{mu}m for FT-IR and 30 to 50 {mu}m squared spot size for XRD) of the beam enables one to obtain detailed compositional profiles from the different chromatic and preparation layers. The sensitivity of the techniques is high enough for the determination of minor and trace compounds, such as reaction and weathering compounds. We report here the identification of pigments in the Romanesque wall paintings found in situ in the church of Saint Eulalia of Unha place in the Aran valley (central Pyrenees). During the first centuries of the second millennium numerous religious buildings were built in Western Europe in the Romanesque style. In particular, a great number of churches were built in the Pyrenees, most of which were decorated with wall paintings. Although only a few of these paintings have survived, they represent one of the most important collections of Romanesque art, both for their quantity and quality. A full identification of the pigments, binder, supports, and reaction and weathering compounds has been obtained. The results obtained, in particular aerinite as a pigment, indicate a clear connection between the paintings found in this Occitanian church and the Catalan Romanesque paintings from the south bound of the Pyrenees. (orig.)

Three-dimensional micro-XRF investigations of paint layers with a tabletop setup

International Nuclear Information System (INIS)

Kanngiesser, Birgit; Malzer, Wolfgang; Rodriguez, Alexis Fuentes; Reiche, Ina

2005-01-01

The non-destructive investigation of art and archaeological objects with depth sensitivity is now possible using 3D micro-XRF spectroscopy. More detailed answers for questions on painting techniques, on the pigment palette, on the production processes and indirectly on dating or provenancing of objects are accessible now. This was already illustrated by the investigation of Mughal miniatures with a confocal setup at the synchrotron source BESSY. In this paper we demonstrate the feasibility of 3D micro-XRF spectroscopy with a tabletop setup and discuss its sensitivity in comparison to the synchrotron-based setup. Investigated objects are glass standards and also prepared paint layers. Perspectives for other types of studies are proposed

Study of the effects of low-fluence laser irradiation on wall paintings: Test measurements on fresco model samples

Science.gov (United States)

Raimondi, Valentina; Cucci, Costanza; Cuzman, Oana; Fornacelli, Cristina; Galeotti, Monica; Gomoiu, Ioana; Lognoli, David; Mohanu, Dan; Palombi, Lorenzo; Picollo, Marcello; Tiano, Piero

2013-11-01

Laser-induced fluorescence is widely applied in several fields as a diagnostic tool to characterise organic and inorganic materials and could be also exploited for non-invasive remote investigation of wall paintings using the fluorescence lidar technique. The latter relies on the use of a low-fluence pulsed UV laser and a telescope to carry out remote spectroscopy on a given target. A first step to investigate the applicability of this technique is to assess the effects of low-fluence laser radiation on wall paintings. This paper presents a study devoted to investigate the effects of pulsed UV laser radiation on a set of fresco model samples prepared using different pigments. To irradiate the samples we used a tripled-frequency Q-switched Nd:YAG laser (emission wavelength: 355 nm; pulse width: 5 ns). We varied the laser fluence from 0.1 mJ/cm2 to 1 mJ/cm2 and the number of laser pulses from 1 to 500 shots. We characterised the investigated materials using several diagnostic and analytical techniques (colorimetry, optical microscopy, fibre optical reflectance spectroscopy and ATR-FT-IR microscopy) to compare the surface texture and their composition before and after laser irradiation. Results open good prospects for a non-invasive investigation of wall paintings using the fluorescence lidar technique.

Study of the effects of low-fluence laser irradiation on wall paintings: Test measurements on fresco model samples

International Nuclear Information System (INIS)

Raimondi, Valentina; Cucci, Costanza; Cuzman, Oana; Fornacelli, Cristina; Galeotti, Monica; Gomoiu, Ioana; Lognoli, David; Mohanu, Dan; Palombi, Lorenzo; Picollo, Marcello; Tiano, Piero

2013-01-01

Laser-induced fluorescence is widely applied in several fields as a diagnostic tool to characterise organic and inorganic materials and could be also exploited for non-invasive remote investigation of wall paintings using the fluorescence lidar technique. The latter relies on the use of a low-fluence pulsed UV laser and a telescope to carry out remote spectroscopy on a given target. A first step to investigate the applicability of this technique is to assess the effects of low-fluence laser radiation on wall paintings. This paper presents a study devoted to investigate the effects of pulsed UV laser radiation on a set of fresco model samples prepared using different pigments. To irradiate the samples we used a tripled-frequency Q-switched Nd:YAG laser (emission wavelength: 355 nm; pulse width: 5 ns). We varied the laser fluence from 0.1 mJ/cm 2 to 1 mJ/cm 2 and the number of laser pulses from 1 to 500 shots. We characterised the investigated materials using several diagnostic and analytical techniques (colorimetry, optical microscopy, fibre optical reflectance spectroscopy and ATR-FT-IR microscopy) to compare the surface texture and their composition before and after laser irradiation. Results open good prospects for a non-invasive investigation of wall paintings using the fluorescence lidar technique.

Role of the masonry in paintings during a seismic event analyzed by infrared vision

Science.gov (United States)

López, F.; Sfarra, S.; Ibarra-Castanedo, C.; Ambrosini, D.; Maldague, X. P. V.

2015-06-01

In this work, pulsed phase thermography (PPT), principal component thermography (PCT), and partial least squares thermography (PLST) techniques were applied in order to detect the masonry texture, as well as to map the subsurface damages formed beneath three different mural paintings. The latter were inspected after the 2009 earthquake, i.e., the seismic event that devastated L'Aquila City (Italy) and its surroundings. The mural supports explored by infrared thermography (IRT) are constituted by a single leaf, and the sides of the inspected paintings are confined by marble frames or by buried horizontal and vertical structures. Hence, the analyzed objects can be considered as monolithic structures. IRT can help to understand the masonry morphology, e.g. if there exist structural continuity between the arriccio layer (the first coat of plaster) and the support. In the present case, the heating phase was provided by lamps or propane gas and feature detection was enhanced by advanced signal processing. A comparison among the results is presented. Two of the three objects analyzed, painted by the art masters Serbucci and Avicola, are preserved inside Santa Maria della Croce di Roio Church in Roio Poggio (L'Aquila, Italy); they were executed on two masonries built in different periods. The last one was realized in Montorio al Vomano (Teramo, Italy) on the internal cloister of the Zoccolanti's Church (undated). The villages are separated by 50 km as the crow flies. Finally, near-infrared reflectography (NIRR) technique was also used to investigate the condition of the painting layer.

Imagined memories of painting

OpenAIRE

Horta, Maia Schmidt, 1974-

2011-01-01

Tese de mestrado, Pintura, Universidade de Lisboa, Faculdade de Belas Artes, 2011 A Tese é compsota por dois volumes, um em portugês, outro em inglês Visual imagery, narratives and locations have always been linked to the study of memory. Memory has always been linked to art history and historical shifts in the study of memory had a direct impact on the history of painting. Painting was based on stories and served to make those stories memorable. Since then there have been numerous inve...

T urkish Women’s Figures and Clothing Properties Seen in Ottoman Term Orientalist Paintings

Directory of Open Access Journals (Sweden)

Hatice HARMANKAYA

2015-07-01

Full Text Available Among movements appearing in the painting art, the one most affecting the Turkish painting has become orientalism. Orientalism is defined as the West and Ea st’s effort to understand each other better. The 18 th century, when the Ottoman Empire is socially, economically and politically in the decline stage, is also the beginning of the orientalist movement. Great interest has been shown to Turkish and foreign painters in the terms of Sultan Selim III, Abdülmecid and Abdü laziz. Cultural interaction between painters has revealed an interest on using the Ottoman and East motifs not only in the side of the Ottoman and also in Western art. Topics of Orientalist painters are generally figure compositions and landscapes. That figure compositions take place in orientalism has caused the woman figure in the painting art to come to the forefront. In this research, it was focused on the women’s figures and clothes the orientalist painters used in their paintings while narrati ng their own, their cities and societies. Epochal figurative paintings of European and Turkish painters, who composed works on the Ottoman territories, were examined in terms of woman images, spaces, clothing, daily - use articles and other cultural items. T he women’s clothes’ model properties, ornamentations, accessories, fabrics and material types were emphasized. Since there wasn’t any style consensus in orientalist paintings, comments of painters on woman images and clothing were compared. In the research the descriptive method was used, and the data were got with the document scanning technique.

Library Search Prefilters for Vehicle Manufacturers to Assist in the Forensic Examination of Automotive Paints.

Science.gov (United States)

Lavine, Barry K; White, Collin G; Ding, Tao

2018-03-01

Pattern recognition techniques have been applied to the infrared (IR) spectral libraries of the Paint Data Query (PDQ) database to differentiate between nonidentical but similar IR spectra of automotive paints. To tackle the problem of library searching, search prefilters were developed to identify the vehicle make from IR spectra of the clear coat, surfacer-primer, and e-coat layers. To develop these search prefilters with the appropriate degree of accuracy, IR spectra from the PDQ database were preprocessed using the discrete wavelet transform to enhance subtle but significant features in the IR spectral data. Wavelet coefficients characteristic of vehicle make were identified using a genetic algorithm for pattern recognition and feature selection. Search prefilters to identify automotive manufacturer through IR spectra obtained from a paint chip recovered at a crime scene were developed using 1596 original manufacturer's paint systems spanning six makes (General Motors, Chrysler, Ford, Honda, Nissan, and Toyota) within a limited production year range (2000-2006). Search prefilters for vehicle manufacturer that were developed as part of this study were successfully validated using IR spectra obtained directly from the PDQ database. Information obtained from these search prefilters can serve to quantify the discrimination power of original automotive paint encountered in casework and further efforts to succinctly communicate trace evidential significance to the courts.

PSP toxin levels and plankton community composition and abundance in size-fractionated vertical profiles during spring/summer blooms of the toxic dinoflagellate Alexandrium fundyense in the Gulf of Maine and on Georges Bank, 2007, 2008, and 2010: 2. Plankton community composition and abundance.

Science.gov (United States)

Petitpas, Christian M; Turner, Jefferson T; Deeds, Jonathan R; Keafer, Bruce A; McGillicuddy, Dennis J; Milligan, Peter J; Shue, Vangie; White, Kevin D; Anderson, Donald M

2014-05-01

As part of the Gulf of Maine Toxicity (GOMTOX) project, we determined Alexandrium fundyense abundance, paralytic shellfish poisoning (PSP) toxin levels in various plankton size fractions, and the community composition of potential grazers of A. fundyense in plankton size fractions during blooms of this toxic dinoflagellate in the coastal Gulf of Maine and on Georges Bank in spring and summer of 2007, 2008, and 2010. PSP toxins and A. fundyense cells were found throughout the sampled water column (down to 50 m) in the 20-64 μm size fractions. While PSP toxins were widespread throughout all size classes of the zooplankton grazing community, the majority of the toxin was measured in the 20-64 μm size fraction. A. fundyense cellular toxin content estimated from field samples was significantly higher in the coastal Gulf of Maine than on Georges Bank. Most samples containing PSP toxins in the present study had diverse assemblages of grazers. However, some samples clearly suggested PSP toxin accumulation in several different grazer taxa including tintinnids, heterotrophic dinoflagellates of the genus Protoperidinium , barnacle nauplii, the harpacticoid copepod Microsetella norvegica , the calanoid copepods Calanus finmarchicus and Pseudocalanus spp., the marine cladoceran Evadne nordmanni , and hydroids of the genus Clytia . Thus, a diverse assemblage of zooplankton grazers accumulated PSP toxins through food-web interactions. This raises the question of whether PSP toxins pose a potential human health risk not only from nearshore bivalve shellfish, but also potentially from fish and other upper-level consumers in zooplankton-based pelagic food webs.

A Short History of the Chemistry of Painting.

Science.gov (United States)

Friedstein, Harriet G.

1981-01-01

Includes information on: (1) relationship of art and science; (2) paintings' early history; (3) Egyptian, Greek, Chinese, Byzantine, and Medieval painting; (4) chemical analysis of pigments; (5) chemistry of early pigments; and (6) paint media. Tabular data are provided on chemical names for artists' pigments with their earliest known dates. (CS)

Staicele Paint Manufactory, Ochre Deposit of Reciems: A Retrospective Journey Through the History of Staicele Paint Manufactory and Evaluation of Production Technologies

Directory of Open Access Journals (Sweden)

Kokins Aigars

2017-05-01

Full Text Available A historical paint manufactory in Staicele, Latvia (1967, was using local resources – colour earth. Oil paint composition consisted of pigment, drying oil, varnish and siccative. It had two different tones that are obtained by using natural colour earth pigments: ochre and its burnt form (burnt umber. Pigment quality was analyzed using historical documents, modern pigment tests, and manufactory technology. Chemical composition, particle size, and pigment tone were determined, and the coating ability was calculated. A palette of oil paints based on the historical recipes for restoring Staicele oil paints was created. Properties of colour earth pigments were compared to specimens taken from the local source of iron that is located near the old paint factory. Results provide a historical and technological insight as well as insight in the properties of the basic paint composition.

Efficacy and toxicity of self-polishing biocide-free antifouling paints

International Nuclear Information System (INIS)

Loeschau, Margit; Kraetke, Renate

2005-01-01

The ban on harmful substances in antifouling paints requires the development of new antifouling strategies. Alternatives should be as effective as conventional paints but of lower toxicity. In the present study two commercially available, self-polishing antifouling paints were examined in order to get information on their antifouling properties and toxicological potential. Efficacy was shown in settlement assays with the marine barnacle species Balanus amphitrite, however, efficacy was related to toxic effects observed on target and non-target organisms. Toxicity of the paint extracts was concentration-dependent and differed according to the paint and the species investigated. Toxicity could at least partially be attributed to zinc leached from the paints. Effects of a water-soluble paint were more pronounced in larvae of B. amphitrite, Artemia salina and in the green algae Dunaliella tertiolecta. Embryos of the freshwater species Danio rerio and Vibrio fisheri were more affected by a paint based on organic solvents. - For alternative antifouling paints efficacy as well as adverse effects on non-target organisms and the aquatic environment should be carefully assessed

Development of a portable ESPI system for the analysis in situ of mural paintings

Science.gov (United States)

Boaglio, E.; Lamas, J.; López, Ana J.; Ramil, A.; Pereira, L.; Prieto, B.; Silva, B.

2012-10-01

The use of Electronic Speckle Pattern Interferometry (ESPI) is well documented in the literature as a non-destructive technique for structural diagnostics in the field of cultural heritage.. In the case of mural paintings the lack of adhesion between the plaster and the mural support is one of the most important risk factors that threaten their conservation. With this non-invasive method it is possible to detect detachments and cracks in the paintings before they become visible The objective of this work is the development of ESPI portable equipment based on a fibre interferometer for in situ qualitative analysis of mural paintings. The novelty of the presented set up is the use of a variable ratio coupler which makes the system more immune to vibrations and allows for better use of available light compared with the equivalent of free air guided. This configuration simplifies the arrangement and makes it possible to obtain ESPI interferograms with high contrast; moreover, the use of a ceramic heater as excitation source enables the analysis during the heating. Preliminary results obtained in laboratory conditions have shown that detachments and cracks can be successfully detected on model samples of the wall paintings.

Piezoelectric paint: characterization for further applications

International Nuclear Information System (INIS)

Yang, C; Fritzen, C-P

2012-01-01

Piezoelectric paint is a very attractive piezoelectric composite in many fields, such as non-destructive testing, or structural health monitoring. However, there are still many obstacles which restrict the real application of it. One of the main problems is that piezoelectric paint lacks a standard fabrication procedure, thus characterization is needed before use. The work presented here explores the characterization of piezoelectric paint. It starts with fabrication of samples with certain piezoelectric powder weight percentages. The microstructures of the samples are investigated by a scanning electron microscope; the results indicate that the fabrication method can produce high quality samples. This is followed by measurements of Young’s modulus and sensitivity. The piezoelectric charge constant d 31 is then deduced from the experimental data; the results agree well with a published result, which validates the effectiveness of the fabrication and characterization method. The characterized piezoelectric paint can expand its applications into different fields and therefore becomes a more promising and competitive smart material. (paper)

Effect of hydrophobic paints coating for tritium reduction in concrete materials

International Nuclear Information System (INIS)

Edao, Y.; Fukada, S.; Nishimura, Y.; Katayama, K.; Takeishi, T.; Hatano, Y.; Taguchi, A.

2012-01-01

Highlights: ► Effects of hydrophobic paint coating in tritium transport are investigated. ► Two kinds of paints, acrylic-silicon resin and epoxy resin are used. ► The hydrophobic paints are effective to reduce tritium permeation. ► The effect of tritium reduction of epoxy paint is higher than that of silicon. - Abstract: The effects of hydrophobic paint coating on a concrete material of cement paste on the tritium transport are investigated. The cement paste is coated with two kinds of paints, acrylic-silicon resin paint and epoxy resin paint. We investigated the amount of tritium trapped in the samples exposed to tritiated water vapor by means of sorption and release. It was found that both the hydrophobic paints could reduce effectively tritium permeation during 50 days exposure of tritiated water vapor. The effect of tritium reduction of the epoxy paint was higher than that of silicon while the amount of tritium trapped in the epoxy paint was larger than that of silicon due to difference of the structure. Based on an analysis of a diffusion model, the rate-determining step of tritium migration through cement paste coated with the paints is diffusion through the paints respectively. It was found that tritium was easy to penetrate through silicon because there were many pores or voids in the silicon comparatively. In the case of tritium released from the epoxy paint, it is considered that tritium diffusion in epoxy is slow due to retardation by isotope exchange reaction to water included in epoxy paint.

Experimental investigation of drag reduction effect of Si-Polyurea paint

International Nuclear Information System (INIS)

Lee, In Won; Jang, Ho Yun; Chun, Ho Hwan; Kwon, Sang Hoon

2008-01-01

A novel Silicone-Polyurea paint has been newly developed and introduced for the antifouling marine paint. This paint is featured with such advantages as the shock-proofness and the scratch-proofness. In addition, the roughness of the resulting paint film is found to be much less than the conventional SPC AF paints. Ultra fast drying ability enables the formation of very thick paint film, e. g., 500μm. The Silicone-Polyurea resin exhibits similar material behavior as that of silicone rubber in terms of hardness and elongation. This material is regarded as a potent candidate to substantiate the compliant coating for the skin friction reduction. This study aims at the assessment of the drag reducing efficiency of the silicone-polyurea paint

Computerized tomography of the painting 'The first mass in Brazil' (Vitor Meireles)

International Nuclear Information System (INIS)

Oliveira, Davi F.; Calza, Cristiane; Rocha, Henrique S.; Lopes, Ricardo T.

2007-01-01

In this work it was performed the radiographic analysis of the painting 'The First Mass in Brazil' ('Primeira Missa no Brasil) executed by Vitor Meireles, in 1860. Radiographic techniques have been used in museums to the study of cultural heritage objects in order to reveal internal details that would otherwise be invisible. This work used Computerized Radiography with an Imaging Plate detector (IP). It consists of a thin layer of photostimulable phosphor crystals (BaFBr:Eu 2+ ) deposited on a flexible polyester support film. When the IP is exposed to an x-ray source, part of the energy is stored as a latent image in the phosphor. Analyzing the radiographic images it is possible to observe the canvas weave, including stretching marks generated when the fabric was fixed on the wooden support. Several regions with detachment and cracking of painting were also revealed. When occurred losses of fabric, the holes were filled with mortar before the retouching; these areas, with higher density than the original painting support, can be clearly observed at the radiographs. The knowledge of all changes and its location is very important to the restoration process, especially in the first stage when the old reinforcement of the fabric will be replaced, in order to avoid the remove of painting pieces together to the reinforcement. (author)

Multilayers quantitative X-ray fluorescence analysis applied to easel paintings.

Science.gov (United States)

de Viguerie, Laurence; Sole, V Armando; Walter, Philippe

2009-12-01

X-ray fluorescence spectrometry (XRF) allows a rapid and simple determination of the elemental composition of a material. As a non-destructive tool, it has been extensively used for analysis in art and archaeology since the early 1970s. Whereas it is commonly used for qualitative analysis, recent efforts have been made to develop quantitative treatment even with portable systems. However, the interpretation of the results obtained with this technique can turn out to be problematic in the case of layered structures such as easel paintings. The use of differential X-ray attenuation enables modelling of the various layers: indeed, the absorption of X-rays through different layers will result in modification of intensity ratio between the different characteristic lines. This work focuses on the possibility to use XRF with the fundamental parameters method to reconstruct the composition and thickness of the layers. This method was tested on several multilayers standards and gives a maximum error of 15% for thicknesses and errors of 10% for concentrations. On a painting test sample that was rather inhomogeneous, the XRF analysis provides an average value. This method was applied in situ to estimate the thickness of the layers a painting from Marco d'Oggiono, pupil of Leonardo da Vinci.

Difference in brain activations during appreciating paintings and photographic analogues

Directory of Open Access Journals (Sweden)

Yoshinori eMizokami

2014-07-01

Full Text Available Several studies have investigated neural correlates of aesthetic appreciation for paintings but to date the findings have been heterogeneous. This heterogeneity may be attributed to previous studies’ measurement of aesthetic appreciation of not only the beauty of paintings but also the beauty of motifs of the paintings. In order to better elucidate the beauty of paintings, it seems necessary to compare aesthetic appreciation of paintings and photographic analogues which included corresponding real images. We prepared for famous painters’ pictures and their photographic analogues which were set up to resemble each painting in order to investigate the hypothesis that there exist specific neural correlates associated with the aesthetic appreciation for paintings. Forty-four subjects participated in functional magnetic resonance study which required comparisons of aesthetic appreciation of paintings of still life and landscape versus photographic analogues including corresponding real images of still life and landscape. Bilateral cuneus and the left lingual gyrus were activated in the comparison of aesthetic appreciation of paintings versus photographic analogues. In conclusion, the present findings suggest a possibility of the existence of specific neural correlates associated with the aesthetic appreciation for paintings and that bilateral cuneus and the left lingual gyrus may be involved.

Development of paint area estimation software for ship compartments and structures

Directory of Open Access Journals (Sweden)

Doo-Yeoun Cho

2016-03-01

Full Text Available The painting process of large ships is an intense manual operation that typically comprises 9–12% of the total shipbuilding cost. Accordingly, shipbuilders need to estimate the required amount of anti-corrosive coatings and painting resources for inventory and cost control. This study aims to develop a software system which enables the shipbuilders to estimate paint area using existing 3D CAD ship structural models. The geometric information of the ships structure are extracted from the existing shipbuilding CAD/CAM system and used to create painting zones. After specifying the painting zones, users can generate the paint faces by clipping structural parts inside each zone. Finally, the paint resources may be obtained from the product of the paint areas and required paint thickness. Implementing the developed software system to real shipbuilders' operations has contributed to improved productivity, faster resource estimation, better accuracy, and fewer coating defects over their conventional manual calculation methods for painting resource estimation.

Perceptual dimensions of style in paintings

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Marković Slobodan

2007-01-01

Full Text Available The main purpose of this study is to specify the basic perceptual dimensions underlying the judgments of the physical features which define the style in paintings (e.g. salient form, colorful surface, oval contours etc.. The other aim of the study is to correlate these dimensions with the subjective (affective dimensions of the experience of paintings. In the preliminary study a set of 25 pairs of elementary perceptual descriptors were empirically specified, and a set of 25 bipolar scales were made (e.g. uncolored-multicolored. In the experiment 30 subjects judged 24 paintings (paintings were taken from the study of Radonjić and Marković, 2004 on 25 scales. Factor analysis revealed the four factors: form (scales: precise, neat, salient form etc., color (color contrast, lightness contrast, vivid colors, space (voluminosity, depth and oval contours and complexity (multicolored, ornate, detailed. Obtained factors reflected the nature of the phenomenological and neural segregation of form, color, depth processing, and partially of complexity processing (e.g. spatial frequency processing within both the form and color subsystem. The aim of the next step of analysis was to specify the correlations between two groups of judgments: (a mean judgments of 24 paintings on perceptual factors and (b mean judgments of the same set of 24 paintings on subjective (affective experience factors, i.e. regularity, attraction, arousal and relaxation (judgments taken from Radonjić and Marković, 2005. The following significant correlations were obtained: regularity-form, regularity-space, attraction-form and arousal-complexity (negative correlation. The reasons for the unexpected negative correlation between arousal and complexity should be specified in further studies.

Non-Photorealistic Rendering in Chinese Painting of Animals

Institute of Scientific and Technical Information of China (English)

无

2002-01-01

A set of algorithms is proposed in this paper to automatically transform 3D animal models to Chinese painting style. Inspired by real painting process in Chinese painting of animals, we divide the whole rendering process into two parts: borderline stroke making and interior shading. In borderline stroke making process we first find 3D model silhouettes in real-time depending on the viewing direction of a user. After retrieving silhouette information from all model edges, a stroke linking mechanism is applied to link these independent edges into a long stroke. Finally we grow a plain thin silhouette line to a stylus stroke with various widths at each control point and a 2D brush model is combined with it to simulate a Chinese painting stroke. In the interior shading pipeline, three stages are used to convert a Gouraud-shading image to a Chinese painting style image: color quantization, ink diffusion and box filtering. The color quantization stage assigns all pixels in an image into four color levels and each level represents a color layer in a Chinese painting. Ink diffusion stage is used to transfer inks and water between different levels and to grow areas in an irregular way. The box filtering stage blurs sharp borders between different levels to embellish the appearance of final interior shading image. In addition to automatic rendering, an interactive Chinese painting system which is equipped with friendly input devices can be also combined to generate more artistic Chinese painting images manually.

Audience Perception of Effective Communication in Nigerian Paintings

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Johnson Adelani Abodunrin

2017-01-01

Full Text Available Artists in Nigeria perceived effective communication differently irrespective of the socio-economic status.Communication effectiveness depends largely on the understanding of the message being passed between a sender and a receiver. Painting has been used over time to express emotion and feeling to the perceiving audience. The study is audience’s perception of communication in Nigeria painting and how it varies with the socio-economic characteristics such as age, education, gender, and being professional artist or art lovers. Questionnaires were distributed and administered to examine how the status of the art audience makes or mars effective communication in painting. The inferential statistics that were employed include “chi-square test” to test the relationship between different variables. The data were taken in ordinal form using Likert’s scale, and transformed into interval data. This was done by attaching statistical weights to the responses in the order of importance which were summed up for the parametric testing. Findings show that gender factor has nothing to do with the understanding of paintings. Also, the level of education obtained by the audience does not have much to do with understanding of contemporary Nigerian painting but a better exposure to the issue concerning the stylistic development of Nigerian painting. Art practitioners must adequately be guided on stylistic trend in painting, art education should be more intensified in educational curriculum in Nigeria. The paper concludes that audience requires a better exposure to the issues concerning the stylistic development of Nigerian painting for effective communication to take place.

The putative thiosulfate sulfurtransferases PspE and GlpE contribute to virulence of Salmonella Typhimurium in the mouse model of systemic disease

DEFF Research Database (Denmark)

Wallrodt, Inke; Jelsbak, Lotte; Thorndahl, Lotte

2013-01-01

contribute to S. Typhimurium virulence, as a glpE and pspE double deletion strain showed significantly decreased virulence in a mouse model of systemic infection. However, challenge of cultured epithelial cells and macrophages did not reveal any virulence-associated phenotypes. We hypothesized...

A Case Study Application Of Time Study Model In Paint ...

African Journals Online (AJOL)

This paper presents a case study in the development and application of a time study model in a paint manufacturing company. The organization specializes in the production of different grades of paint and paint containers. The paint production activities include; weighing of raw materials, drying of raw materials, dissolving ...

The abstract unconscious in painting

OpenAIRE

Parker, David

2009-01-01

The Abstract Unconscious in Painting addresses painting as experiential process, critically examining the psychological factors involved in the formation of imagery as it emerges through imaginative responses to the process of mark making and the structuring of space and form. The paper sets this process in relation to theoretical material drawn from Jungian and Post Jungian Psychology ( Avens, 1980; Hillman, 1975) the arts ( Gombrich, 1960; Kuspit, 2000; McKeever, 2005; Worringer, 1908) and ...

Pigeons can discriminate "good" and "bad" paintings by children.

Science.gov (United States)

Watanabe, Shigeru

2010-01-01

Humans have the unique ability to create art, but non-human animals may be able to discriminate "good" art from "bad" art. In this study, I investigated whether pigeons could be trained to discriminate between paintings that had been judged by humans as either "bad" or "good". To do this, adult human observers first classified several children's paintings as either "good" (beautiful) or "bad" (ugly). Using operant conditioning procedures, pigeons were then reinforced for pecking at "good" paintings. After the pigeons learned the discrimination task, they were presented with novel pictures of both "good" and "bad" children's paintings to test whether they had successfully learned to discriminate between these two stimulus categories. The results showed that pigeons could discriminate novel "good" and "bad" paintings. Then, to determine which cues the subjects used for the discrimination, I conducted tests of the stimuli when the paintings were of reduced size or grayscale. In addition, I tested their ability to discriminate when the painting stimuli were mosaic and partial occluded. The pigeons maintained discrimination performance when the paintings were reduced in size. However, discrimination performance decreased when stimuli were presented as grayscale images or when a mosaic effect was applied to the original stimuli in order to disrupt spatial frequency. Thus, the pigeons used both color and pattern cues for their discrimination. The partial occlusion did not disrupt the discriminative behavior suggesting that the pigeons did not attend to particular parts, namely upper, lower, left or right half, of the paintings. These results suggest that the pigeons are capable of learning the concept of a stimulus class that humans name "good" pictures. The second experiment showed that pigeons learned to discriminate watercolor paintings from pastel paintings. The subjects showed generalization to novel paintings. Then, as the first experiment, size reduction test

Tapestry paintings in the main church in Breda

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Micha Leeflang

2010-02-01

Full Text Available This article is an adaptation of some reports made between 2005 and 2007 for the art-historical preliminary research into the restorations of the wall paintings in the main church in Breda. In addition, a proposal for restoration is given for the paintings dealt with, emphasizing the preservation of the representations. The first priority in all the paintings is consolidating loose paint and removing dirt from the surface. Subsequently, old putty is removed so as to expose the original painting as much as possible. During the restoration large voids will have to be filled up in a neutral shade – in a lighter shade than the original – so that the distinction between original and restoration remains visible. On the south choir wall in the second bay of the ambulatory at the top three pairs of yellow cloth scissors are painted on a green field (illustration 1. As scissors were an important element in the textile industry, it is plausible that this chapel was painted on the instructions of the cloth guild (illustration 2. The various stages in the production process of the cloth were strictly inspected. These inspections were accompanied by affixing lead seals (illustration 3, which could be considered a full guarantee for the client. Around the scissors in the cloth- scissors chapel in Breda small circles are painted, which were not mentioned in the literature. Although the exact meaning is unknown, these circles could represent lead seals and could thus be a reference to the high quality of the products of the cloth guild in Breda. Both on the second choir pillar at the southside and on the freestanding clustered pillar in the south ambulatory angels with a red cloth of honour are painted (illustration 7, 9 and 10. The former painting dates from approximately 1510-1520 and the latter from the second half of the sixteenth century. It is very likely that the red painted cloth of honour functioned as a background for a sculpture. In miniature art

Rock paintings in Fern Cave, Lava Beds National Monument, California: Not the 1054 A.D. (Crab Nebula) Supernova

International Nuclear Information System (INIS)

Armitage, R.A.; Hyman, M.; Rowe, M. W.

1997-01-01

On July 4, 1054 A.D. a supernova brighter than Venus appeared in the sky, remaining visible for approximately 23 days and 650 nights. It was chronicled in five independent historic accounts, four in China and one in Japan. For at least 40 years investigators have attributed certain distinctive rock paintings and carvings in the western United States as recordings of the 1054 A.D. supernova. More than twenty such depictions (circle or star-like symbols and a crescent) have been located. Two panels of rock paintings in Lava Beds National Monument, California, one at Fern Cave and one at Symbol Bridge, were listed as recording the 1054 A.D. supernova. The only direct means of assessing the likelihood that a 'supernova' representation records the 1054 A.D. event is to date the rock painting or carving. At Texas A and M University, was developed a plasma-chemical extraction technique that permits to analyze the 14 C in rock paintings, whether the pigments used were charcoal or inorganic Fe- and Mn- oxides and hydroxides with organic binder/vehicles. This paper presents direct 14 C age estimates on a rock painting suggested to represent the 1054 A.D. supernova. Charcoal pigment samples were collected from three figures in proximity at Fern Cave: a crescent pointing downward and two nearby circles, one above and one below the crescent. The AMS 14 C analysis on each sample using this technique show that these images do not represent the 1054 A.D. supernova

Introductory guide to painting

CSIR Research Space (South Africa)

Cromarty, R.E

1985-01-01

Full Text Available , and have doubts about it, you are wel- come to contact the NBRl for advice. It is always best when buying a paint system to select the products of a single manufacturer. the grain as it dries. Several coats can be used to give a high-gloss finish... rendering Those who have lived on a farm will probably remember how surplus fat used to be treated with an alkali to make soap. The same thing can happen at the point where some oil paints come in contact with the wall. The alkali, which is always...

Paintings discrimination by mice: Different strategies for different paintings.

Science.gov (United States)

Watanabe, Shigeru

2017-09-01

C57BL/6 mice were trained on simultaneous discrimination of paintings with multiple exemplars, using an operant chamber with a touch screen. The number of exemplars was successively increased up to six. Those mice trained in Kandinsky/Mondrian discrimination showed improved learning and generalization, whereas those trained in Picasso/Renoir discrimination showed no improvements in learning or generalization. These results suggest category-like discrimination in the Kandinsky/Mondrian task, but item-to-item discrimination in the Picasso/Renoir task. Mice maintained their discriminative behavior in a pixelization test with various paintings; however, mice in the Picasso/Renoir task showed poor performance in a test that employed scrambling processing. These results do not indicate that discrimination strategy for any Kandinsky/Mondrian combinations differed from that for any Picasso/Monet combinations but suggest the mice employed different strategies of discrimination tasks depending upon stimuli. Copyright © 2017 Elsevier B.V. All rights reserved.

Composition in Athenian black-figure vase-painting : The 'Chariot in profile’ type scene

NARCIS (Netherlands)

Helle, G.

2017-01-01

All Athenian vases painted using the black-figure technique reflect the conventions of Athenian pictorial language. These were familiar to Athenians in the 6th century BCE, but we – after 2,500 years – can discover them only by studying and analysing the surviving images. Because large numbers

Study of the effects of low-fluence laser irradiation on wall paintings: Test measurements on fresco model samples

Energy Technology Data Exchange (ETDEWEB)

Raimondi, Valentina, E-mail: v.raimondi@ifac.cnr.it [‘Nello Carrara’Applied Physics Institute-National Research Council of Italy (CNR-IFAC), Firenze (Italy); Cucci, Costanza [‘Nello Carrara’Applied Physics Institute-National Research Council of Italy (CNR-IFAC), Firenze (Italy); Cuzman, Oana [Institute for the Conservation and Promotion of Cultural Heritage-National Research Council (CNR-ICVBC), Firenze (Italy); Fornacelli, Cristina [‘Nello Carrara’Applied Physics Institute-National Research Council of Italy (CNR-IFAC), Firenze (Italy); Galeotti, Monica [Opificio delle Pietre Dure (OPD), Firenze (Italy); Gomoiu, Ioana [National University of Art, Bucharest (Romania); Lognoli, David [‘Nello Carrara’Applied Physics Institute-National Research Council of Italy (CNR-IFAC), Firenze (Italy); Mohanu, Dan [National University of Art, Bucharest (Romania); Palombi, Lorenzo; Picollo, Marcello [‘Nello Carrara’Applied Physics Institute-National Research Council of Italy (CNR-IFAC), Firenze (Italy); Tiano, Piero [Institute for the Conservation and Promotion of Cultural Heritage-National Research Council (CNR-ICVBC), Firenze (Italy)

2013-11-01

Laser-induced fluorescence is widely applied in several fields as a diagnostic tool to characterise organic and inorganic materials and could be also exploited for non-invasive remote investigation of wall paintings using the fluorescence lidar technique. The latter relies on the use of a low-fluence pulsed UV laser and a telescope to carry out remote spectroscopy on a given target. A first step to investigate the applicability of this technique is to assess the effects of low-fluence laser radiation on wall paintings. This paper presents a study devoted to investigate the effects of pulsed UV laser radiation on a set of fresco model samples prepared using different pigments. To irradiate the samples we used a tripled-frequency Q-switched Nd:YAG laser (emission wavelength: 355 nm; pulse width: 5 ns). We varied the laser fluence from 0.1 mJ/cm{sup 2} to 1 mJ/cm{sup 2} and the number of laser pulses from 1 to 500 shots. We characterised the investigated materials using several diagnostic and analytical techniques (colorimetry, optical microscopy, fibre optical reflectance spectroscopy and ATR-FT-IR microscopy) to compare the surface texture and their composition before and after laser irradiation. Results open good prospects for a non-invasive investigation of wall paintings using the fluorescence lidar technique.

TeraHertz imaging of hidden paint layers on canvas

NARCIS (Netherlands)

Adam, A.J.L.; Planken, P.C.M.; Meloni, S.; Dik, J.

2009-01-01

We show terahertz reflection images of hidden paint layers in a painting on canvas and compare the results with X-ray Radiography and Infrared Reflectography. Our terahertz measurements show strong reflections from both the canvas/paint interface and from the raw umber/lead white interface,

Training facilitates object recognition in cubist paintings

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Martin Wiesmann

2010-03-01

Full Text Available To the naïve observer, cubist paintings contain geometrical forms in which familiar objects are hardly recognizable, even in the presence of a meaningful title. We used fMRI to test whether a short training session about Cubism would facilitate object recognition in paintings by Picasso, Braque and Gris. Subjects, who had no formal art education, were presented with titled or untitled cubist paintings and scrambled images, and performed object recognition tasks. Relative to the control group, trained subjects recognized more objects in the paintings, their response latencies were significantly shorter, and they showed enhanced activation in the parahippocampal cortex, with a parametric increase in the amplitude of the fMRI signal as a function of the number of recognized objects. Moreover, trained subjects were slower to report not recognizing any familiar objects in the paintings and these longer response latencies were correlated with activation in a fronto-parietal network. These findings suggest that trained subjects adopted a visual search strategy and used contextual associations to perform the tasks. Our study supports the proactive brain framework, according to which the brain uses associations to generate predictions.

The art in science: electron microscopy and paintings conservation

International Nuclear Information System (INIS)

Waters, L.

2003-01-01

Full text: When examining a painting, a conservator uses many different and complementary methods of analysis to build an understanding of the materials and way the painting was constructed. Common methods of examination include x-radiography, infrared reflectography, ultraviolet fluorescence and optical microscopy of the surface of the painting. Minute samples of paint prepared as cross-sections are sometimes taken for optical examination under the microscope, and it is these that can, conveniently, be further analysed with electron microscopy to yield another level of information. Electron microscopy has a valuable role to play within the examination of paintings, be it for pigment identification alone, or at the other end of the spectrum, for informing issues around the attribution of works of art. This paper provides an overview of the use of electron microscopy in the conservation of paintings by discussing examples of work undertaken by the National Gallery of Victoria and the CSIRO. Work described includes the problem of distinguishing between restorers' original paint in a landscape by Arthur Streeton, and the examination of the ground or priming layer in a Rembrandt portrait which clarified its attribution to his studio. Copyright (2003) Australian Microbeam Analysis Society

Roosters Rule: A Painted Paper Collage

Science.gov (United States)

Brady, Susan

2011-01-01

On perusing American collage artist Eric Carle's book, "Rooster's Off to See the World," at an annual school book fair, the author, mesmerized by the carnival of colors and collage on each page, thought "What a wonderful visual aid for a combination painting and collage unit." Her first-graders were involved in a painting unit, and knowing their…

Detecting Corrosion Under Paint and Insulation

Science.gov (United States)

Bastin, Gary L.

2011-01-01

Corrosion is a major concern at the Kennedy Space Center in Florida due to the proximity of the center to the Atlantic Ocean and to salt water lagoons. High humidity, salt fogs, and ocean breezes, provide an ideal environment in which painted steel structures become corroded. Maintenance of painted steel structures is a never-ending process.

29 CFR 1915.33 - Chemical paint and preservative removers.

Science.gov (United States)

2010-07-01

... 29 Labor 7 2010-07-01 2010-07-01 false Chemical paint and preservative removers. 1915.33 Section... Preparation and Preservation § 1915.33 Chemical paint and preservative removers. (a) Employees shall be protected against skin contact during the handling and application of chemical paint and preservative...

Self-Cleaning Mineral Paint for Application in Architectural Heritage

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Sudipto Pal

2016-10-01

Full Text Available A mineral silicate paint has been developed for architectural heritage. To enhance durability, any type of organic additive has been avoided. Potassium silicate was the binder agent intended to give strong adherence and durability to stone and concretes. Incorporation of mainly anatase titanium dioxide was intended to act both as a white, bright pigment and as a photocatalyst. Reflectivity analyses on the paint in the visible-to-near infrared wavelength region show high solar heat reflection. The self-cleaning activity of the mineral paint was evaluated by the degradation of organic dyes under solar light irradiation. Anatase titania was effective in decomposing organic and airborne pollutants with the solar radiation. The optical properties and self-cleaning activity were compared with the organic binder-based paints and commercial paints. Developed paints possess high stability: since they contain only inorganic components that do not fade with exposure to solar radiation, photocatalytic self-cleaning capability further enhances such stability.

Metal soaps in oil paint : Structure, mechanisms and dynamics

NARCIS (Netherlands)

Hermans, J.J.

2017-01-01

From a chemical point of view, oil paintings are not stable objects. Visually, changes in the appearance of an oil painting might be very slow, but over the course of centuries, chemical reactions and physical processes do affect the colour, texture and integrity of oil paint layers. This thesis

Paint and Pregnancy

Science.gov (United States)

... of paints used for industry, the arts, and hobbies. Years ago, lead and mercury were used in ... high amounts of toluene – higher exposure than a hobby or professional painter would likely have. I work ...

Evaluation of stabilization of steel surface corrosion by paints

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Aleš Dvořák

2005-01-01

Full Text Available This article deals with laboratory experiments focused on protective and stabilizing effects of paints designed to protect rusted steel surfaces. Two well-known paints (the Hammerite No.1 Rustbeater synthetic paint and the Antirezin water-soluble paint have been evaluated. The standardized tests according to ČSN have been used for the evaluation. Stabilization of rusted steel surface hasn’t been demonstrated during the tests. The SEM test method that covers micro-analysis of elements has been used for the evaluation as well.

Use of infrared hyperspectral imaging as an aid for paint identification

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A. Polak

2016-10-01

Full Text Available Art authentication is a complicated process that often requires the extensive study of high value objects. Although a series of non-destructive techniques is already available for art scientists, new techniques, extending current possibilities, are still required. In this paper, the use of a novel mid-infrared tunable imager is proposed as an active hyperspectral imaging system for art work analysis. The system provides access to a range of wavelengths in the electromagnetic spectrum (2500–3750 nm which are otherwise difficult to access using conventional hyperspectral imaging (HSI equipment. The use of such a tool could be beneficial if applied to the paint classification problem and could help analysts map the diversity of pigments within a given painting. The performance of this tool is demonstrated and compared with a conventional, off-the-shelf HSI system operating in the near infrared spectral region (900–1700 nm. Various challenges associated with laser-based imaging are demonstrated and solutions to these challenges as well as the results of applying classification algorithms to datasets captured using both HSI systems are presented. While the conventional HSI system provides data in which more pigments can be accurately classified, the result of applying the proposed laser-based imaging system demonstrates the validity of this technique for application in art authentication tasks.

A methodological approach to study the stability of selected watercolours for painting reintegration, through reflectance spectrophotometry, Fourier transform infrared spectroscopy and hyperspectral imaging

Science.gov (United States)

Pelosi, Claudia; Capobianco, Giuseppe; Agresti, Giorgia; Bonifazi, Giuseppe; Morresi, Fabio; Rossi, Sara; Santamaria, Ulderico; Serranti, Silvia

2018-06-01

The aim of this work is to investigate the stability to simulated solar radiation of some paintings samples through a new methodological approach adopting non-invasive spectroscopic techniques. In particular, commercial watercolours and iron oxide based pigments were used, these last ones being prepared for the experimental by gum Arabic in order to propose a possible substitute for traditional reintegration materials. Reflectance spectrophotometry in the visible range and Hyperspectral Imaging in the short wave infrared were chosen as non-invasive techniques for evaluation the stability to irradiation of the chosen pigments. These were studied before and after artificial ageing procedure performed in Solar Box chamber under controlled conditions. Data were treated and elaborated in order to evaluate the sensitivity of the chosen techniques in identifying the variations on paint layers, induced by photo-degradation, before they could be observed by eye. Furthermore a supervised classification method for monitoring the painted surface changes adopting a multivariate approach was successfully applied.

Measurement of adhesion properties between topcoat paint and metallized/galvanized steel with surface energy measurement equipment.

Science.gov (United States)

2013-09-01

The objectives of this research project are: (1) Compare the adhesion properties of NEPCOAT-approved topcoat paint over : metallized or galvanized steel. Use surface-energy measuring technique to characterize the wetting properties of the liqui...

Using spatial information about recurrence risk for robust optimization of dose-painting prescription functions

International Nuclear Information System (INIS)

Bender, Edward T.

2012-01-01

Purpose: To develop a robust method for deriving dose-painting prescription functions using spatial information about the risk for disease recurrence. Methods: Spatial distributions of radiobiological model parameters are derived from distributions of recurrence risk after uniform irradiation. These model parameters are then used to derive optimal dose-painting prescription functions given a constant mean biologically effective dose. Results: An estimate for the optimal dose distribution can be derived based on spatial information about recurrence risk. Dose painting based on imaging markers that are moderately or poorly correlated with recurrence risk are predicted to potentially result in inferior disease control when compared the same mean biologically effective dose delivered uniformly. A robust optimization approach may partially mitigate this issue. Conclusions: The methods described here can be used to derive an estimate for a robust, patient-specific prescription function for use in dose painting. Two approximate scaling relationships were observed: First, the optimal choice for the maximum dose differential when using either a linear or two-compartment prescription function is proportional to R, where R is the Pearson correlation coefficient between a given imaging marker and recurrence risk after uniform irradiation. Second, the predicted maximum possible gain in tumor control probability for any robust optimization technique is nearly proportional to the square of R.

Reassessing the extent of the Q classification for containment paint

International Nuclear Information System (INIS)

Spires, G.

1995-01-01

A mounting number of site-specific paint debris transport and screen clogging analyses submitted to justify substandard containment paint work have been deemed persuasive by virtue of favorable U.S. Nuclear Regulatory Commission safety evaluation report (SER) findings. These lay a strong foundation for a standardized approach to redefining the extent to which paint in containment needs to be considered open-quotes Q.close quotes This information justifies an initiative by licensees to roll back paint work quality commitments made at the design phase. This paper questions the validity of the basic premise that all primary containment paint can significantly compromise core and containment cooling [emergency core cooling system/engineered safeguard feature (ECCS/ESF)]. It is posited that the physical extent of painted containment surfaces for which extant material qualification and quality control (QC) structures need apply can be limited to zones relatively proximate to ECCS/ESF suction points. For other painted containment surfaces, simplified criteria should be allowed

Dissolution of organic solvents from painted surfaces into water

International Nuclear Information System (INIS)

Wren, J.C.; Jobe, D.J.; Sanipelli, G.G.; Ball, J.M.

2000-01-01

The presence of volatile iodine in containment buildings is one of the major safety concerns in the potential event of nuclear reactor accidents. Organic impurities in containment water, originating from various painted structural surfaces and organic materials, could have a significant impact on iodine volatility following an accident. To determine the source and magnitude of organic impurities and their effects on time-dependent iodine volatility, the dissolution for organic constituents from paints used in reactor buildings has been studied under postulated accident conditions. The studies of the organic dissolution from carbon steel coupons coated with zinc-primed vinyl, epoxy-primed polyurethane or epoxy paints over the temperature range 25-90 deg C are reported. Relatively large activation energies were measured for the release of the principal organic compounds from painted surfaces, suggesting it is the release of the solvents from the paint matrix rather than their diffusion through the solution that is the rate determining step for the dissolution mechanism. The similarities in the values of activation energies for the dissolution of different organic compounds from the paints suggest the release rate is independent of the nature of the painted surface or the type of organic being released from the surface. These two observations indicate that it may be possible to write a generalized rate expression for the release of organic compounds from painted surfaces in containment following an accident. The possible implications of these results for predicting iodine volatility in containment are also discussed. (author)

Beam loss reduction by injection painting in the 3-GeV rapid cycling synchrotron of the Japan Proton Accelerator Research Complex

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H. Hotchi

2012-04-01

Full Text Available The 3-GeV rapid cycling synchrotron (RCS of the Japan Proton Accelerator Research Complex was commissioned in October 2007. Via the initial beam tuning and a series of underlying beam studies with low-intensity beams, since December 2009, we have intermittently been performing beam tuning experiments with higher-intensity beams including the injection painting technique. By optimizing the injection painting parameters, we have successfully achieved a 420 kW-equivalent output intensity at a low-level intensity loss of less than 1%. Also the corresponding numerical simulation well reproduced the observed painting parameter dependence on the beam loss, and captured a characteristic behavior of the high-intensity beam in the injection painting process. In this paper, we present the experimental results obtained in the course of the RCS beam power ramp-up, especially on the beam loss reduction achieved by employing the injection painting, together with the numerical simulation results.

High resolution spectroscopic mapping imaging applied in situ to multilayer structures for stratigraphic identification of painted art objects

Science.gov (United States)

Karagiannis, Georgios Th.

2016-04-01

The development of non-destructive techniques is a reality in the field of conservation science. These techniques are usually not so accurate, as the analytical micro-sampling techniques, however, the proper development of soft-computing techniques can improve their accuracy. In this work, we propose a real-time fast acquisition spectroscopic mapping imaging system that operates from the ultraviolet to mid infrared (UV/Vis/nIR/mIR) area of the electromagnetic spectrum and it is supported by a set of soft-computing methods to identify the materials that exist in a stratigraphic structure of paint layers. Particularly, the system acquires spectra in diffuse-reflectance mode, scanning in a Region-Of-Interest (ROI), and having wavelength range from 200 up to 5000 nm. Also, a fuzzy c-means clustering algorithm, i.e., the particular soft-computing algorithm, produces the mapping images. The evaluation of the method was tested on a byzantine painted icon.

Measurement of tritium in dial painting industry

International Nuclear Information System (INIS)

Sawant, J.V.; Rudran, Kamala

1995-01-01

Tritium in the form of polystyrene is used coated on zinc sulphide as the active component for the manufacture of self-luminous paint. To study the radiological implication of airborne tritium in the luminous paint industry air monitoring study was conducted by cold strip method and Andersen method. Airborne particulate in different locations in luminous paint (LP) building and background areas were observed to be associated with activity median aerodynamic diameter (AMAD) of 1.8 to 5.0 um. Dose to soft tissue and lungs and effective whole body dose were evaluated. (author). 6 refs., 2 figs., 4 tabs., 2 ills

A multi-analytical approach for the characterization of wall painting materials on contemporary buildings

Science.gov (United States)

Magrini, Donata; Bracci, Susanna; Cantisani, Emma; Conti, Claudia; Rava, Antonio; Sansonetti, Antonio; Shank, Will; Colombini, MariaPerla

2017-02-01

Samples from Keith Haring's wall painting of the Necker Children Hospital in Paris were studied by a multi-analytical protocol. X-ray fluorescence (XRF), powder X-ray diffraction (XRDP), Electron microscope (SEM-EDS), Infrared and Raman spectroscopy (μ-FT-IR and μ-Raman) measurements were performed in order to characterize the materials and to identify the art technique used to produce this contemporary work. Materials from the mural suffered from severe detachments of materials and several fragments were found on the ground beneath. Some of these fragments, which were representative of the whole palette and stratigraphic sequence, were collected and studied. The fragments were sufficiently large to enable non-invasive measurements to be performed in order to characterize the materials. A comparison of the data of the techniques applied revealed that Haring's palette was composed of organic pigments such as Naphtol red, phthalocyanine blue and green and Hansa yellow, in accordance with those used previously by the artist in other painted murals.

Romano-British wall paintings: Raman spectroscopic analysis of fragments from two urban sites of early military colonisation

Science.gov (United States)

Edwards, H. G. M.; Middleton, P. S.; Hargreaves, M. D.

2009-08-01

Raman spectroscopic analyses of 1st century AD Romano-British villa wall-painting fragments from two important military and early urban centres at Colchester and Lincoln have demonstrated some interesting contrasts in technique and palette usage. Colchester, the earliest fortified settlement, developed a sophisticated painting and craft industry compared with Lincoln in the assimilation of novel substrate preparation ideas and pigment adoption. The earliest use of the rather rare purple mineral pigment, caput mortuum, hitherto reported in only a few Roman villas elsewhere in mainland Europe, is in evidence in this early phase settlement and the use of gypsum as a special ground preparation agent as an additive to the more common limewash putty to enhance the effect of the use of lazurite as a pigment is worthy of note in this context. Otherwise, the pigments are seen to be those that are quite normally encountered in Roman villas, namely, haematite, goethite, terre verte, and carbon. The results of this study indicate that at Colchester there was a continued development in technique into the colonial phase compared with a stagnation in Lincoln; these scientific results have created a stimulus for further historical research into pigment and techniques development for wall paintings at the fringe of the Roman Empire in the 1st-3rd Centuries AD.

Usage of radiography techniques for restoration of Cizre Mardin Ulucami door

International Nuclear Information System (INIS)

Tugrul, B.; Sungur, F.; Gorkem, A.; Olcer, N.

1986-01-01

In this study, one of the two sections of Cizre-Mardin Ulucami door is investigated by x-ray radiography technique whether it has some patterns similar to those which were discovered during the restoration of the first section of the door. Some painted and traced parts have been fixed and torn down, cleared and investigated. In the study, many pieces of the first part of the door including the second door have been investigated by x-ray radiography technique and have been evaluated. Furthermore, neutrography has been applied on some painted parts for the investigation of traces of painting. (author)

Spectroscopic study of an icon painted on wooden panel

Directory of Open Access Journals (Sweden)

Stojanović Sofija R.

2015-01-01

Full Text Available Russian icon painted on wooden panel analyzed in this work is interesting for art historians because there is no precise information in which workshops it was made or who the author was. Similar icons are often found in churches and monasteries in our region. In order to obtain information about materials used for creation of investigated icon two micro-analytical techniques were used: Energy-Dispersive X-Ray Fluorescence spectroscopy (EDXRF and micro-Raman spectroscopy. Obtained results confirmed presence of following materials: lead-white, vermilion, minium, ultramarine, brown and green earth pigments and silver in combination with yellow organic varnish, which served to an iconographer for gilding. Ground layer was made of calcite. Blue pigment ultramarine was probably used for blue colour as well as for obtaining particulars hues in several parts of the paint layer. This can be important information for further research concerning particular workshop in which the icon was made. Identified materials are typical for Russian iconography of the 19th century. [Projekat Ministarstva nauke Republike Srbije, br. OI 177021 i OI 177012

Electrochemical Decontamination of Painted and Heavily Corroded Metals

International Nuclear Information System (INIS)

Marczak, S.; Anderson, J.; Dziewinski, J.

1998-01-01

The radioactive metal wastes that are generated from nuclear fuel plants and radiochemical laboratories are mainly contaminated by the surface deposition of radioactive isotopes. There are presently several techniques used in removing surface contamination involving physical and chemical processes. However, there has been very little research done in the area of soiled, heavily oxidized, and painted metals. Researchers at Los Alamos National Laboratory have been developing electrochemical procedures for the decontamination of bare and painted metal objects. These methods have been found to be effective on highly corroded as well as relatively new metals. This study has been successful in decontaminating projectiles and shrapnel excavated during environmental restoration projects after 40+ years of exposure to the elements. Heavily corroded augers used in sampling activities throughout the area were also successfully decontaminated. This process has demonstrated its effectiveness and offers several advantages over the present metal decontamination practices of media blasting and chemical solvents. These advantages include the addition of no toxic or hazardous chemicals, low operating temperature and pressure, and easily scaleable equipment. It is in their future plans to use this process in the decontamination of gloveboxes destined for disposal as TRU waste

The Conservation of Panel paintings

DEFF Research Database (Denmark)

Until the early 17th century almost all portable paintings were created on wood supports, including masterpieces by famous painters, ranging from Giotto to Dürer to Rembrandt. The structural conservation of these paintings requires specific knowledge and skills as the supports are susceptible...... and conservation of these artworks. The Netherlands Organisation for Scientific Research (NWO) and the Rijksmuseum Amsterdam brought together a group of experts from different disciplines to recommend specific areas in the field that would benefit from systematic research. The experts concluded that targeted...

Non-destructive and in situ analysis of Egyptian wall paintings by X-ray diffraction and X-ray fluorescence portable systems

International Nuclear Information System (INIS)

Pages-Camagna, S.; Laval, E.; Vigears, D.; Duran, A.

2010-01-01

The concurrence and complementarities of obtained images under various wavelengths and the elemental and structural analyses provided by XRF and XRD, using portable non-invasive systems, have allowed for obtaining accurate data about the employed pictorial technique in two Egyptian wall paintings dating from the New Kingdom. Thus, compounds such as Egyptian blue, Egyptian green, goethite, jarosite, hematite, calcite, anhydrite or huntite have been detected in the paintings. The performance of the measurements by the different techniques and its contribution to the knowledge of the materials are discussed. They notably give a clue on the origin of arsenic compounds, unexpectedly detected in some decors. (orig.)

Monitoring translocations by M-FISH and three-color FISH painting techniques. A study of two radiotherapy patients

International Nuclear Information System (INIS)

Pouzoulet, F.; Roch-Lefevre, S.; Giraudet, AL.

2007-01-01

To compare translocation rate using either M-FISH or FISH-3 in two patients treated for head and neck cancer, with a view to retrospective dosimetry. Translocation analysis was performed on peripheral blood lymphocyte cultures from blood samples taken at different times during the radiotherapy (0 Gy, 12 Gy and 50 Gy) and a few months after the end of the treatment (follow-up). Estimated translocation yield varied according to the FISH technique used. At 50 Gy and follow-up points, the translocation yields were higher with FISH-3 than with M-FISH. This difference can be attributed to three events. First, an increase in complex aberrations was observed for 50 Gy and follow-up points compared with 0 Gy and 12 Gy points. Second, at the end of treatment for patient A, involvement of chromosomes 2, 4, 12 in translocations was less than expected according to the Lucas formula. Third, a clone bearing a translocation involving a FISH-3 painted chromosome was detected. More translocations were detected with M-FISH than with FISH-3, and so M-FISH is expected to improve the accuracy of chromosome aberration analyses in some situations. (author)

Does antifouling paint select for antibiotic resistance?

Science.gov (United States)

Flach, Carl-Fredrik; Pal, Chandan; Svensson, Carl Johan; Kristiansson, Erik; Östman, Marcus; Bengtsson-Palme, Johan; Tysklind, Mats; Larsson, D G Joakim

2017-07-15

There is concern that heavy metals and biocides contribute to the development of antibiotic resistance via co-selection. Most antifouling paints contain high amounts of such substances, which risks turning painted ship hulls into highly mobile refuges and breeding grounds for antibiotic-resistant bacteria. The objectives of this study were to start investigate if heavy-metal based antifouling paints can pose a risk for co-selection of antibiotic-resistant bacteria and, if so, identify the underlying genetic basis. Plastic panels with one side painted with copper and zinc-containing antifouling paint were submerged in a Swedish marina and biofilms from both sides of the panels were harvested after 2.5-4weeks. DNA was isolated from the biofilms and subjected to metagenomic sequencing. Biofilm bacteria were cultured on marine agar supplemented with tetracycline, gentamicin, copper sulfate or zinc sulfate. Biofilm communities from painted surfaces displayed lower taxonomic diversity and enrichment of Gammaproteobacteria. Bacteria from these communities showed increased resistance to both heavy metals and tetracycline but not to gentamicin. Significantly higher abundance of metal and biocide resistance genes was observed, whereas mobile antibiotic resistance genes were not enriched in these communities. In contrast, we found an enrichment of chromosomal RND efflux system genes, including such with documented ability to confer decreased susceptibility to both antibiotics and biocides/heavy metals. This was paralleled by increased abundances of integron-associated integrase and ISCR transposase genes. The results show that the heavy metal-based antifouling paint exerts a strong selection pressure on marine bacterial communities and can co-select for certain antibiotic-resistant bacteria, likely by favoring species and strains carrying genes that provide cross-resistance. Although this does not indicate an immediate risk for promotion of mobile antibiotic resistance, the

Push-Pull Ventilation in a Painting Shop for Large Steel Constructions

DEFF Research Database (Denmark)

Svidt, Kjeld; Heiselberg, Per

This paper describes the analysis of a push-pull ventilation system for a painting shop that is used for painting steel chimneys and windmill towers.......This paper describes the analysis of a push-pull ventilation system for a painting shop that is used for painting steel chimneys and windmill towers....

Are Shaman Paintings Material Religion or Religious Art?

Directory of Open Access Journals (Sweden)

Jong-chun Park

2017-12-01

Full Text Available Laurel Kendall, Jongsung Yang, and Yul Soo Yoon. God Pictures in Korean Contexts: The Ownership and Meaning of Shaman Paintings. Honolulu: University of Hawai'i Press, 2015. God Pictures in Korean Contexts: The Ownership and Meaning of Shaman Paintings is a pioneering work, one that explores the proverbial “road not taken” by previous research on the subject. The authors situate “the lives of Korean shaman paintings [musindo] in a complex South Korean world; in shaman shrines, private collections, and museums." Incorporating their vivid experiences in the field, authors Laurel Kendall, anthropologist and curator at the American Museum of Natural History; Jongsung Yang, collector and director of the Museum of Shamanism in Seoul; and Yul Soo Yoon, art historian and director of the Gahoe Museum in Seoul, investigate not merely the religious meanings and functions of shaman paintings, but how these meanings and functions are accepted, appropriated, and even created, depending on the interests of various participants—shamans, painters, collectors of shaman paintings, and so on—who are relevant to these visual forms of expressive culture.

Analysis of materials of the mural painting 'Los Prometeos' of Arnold Belkin, Managua, Nicaragua

International Nuclear Information System (INIS)

Espinosa, M.E.; Tapia, M.

2004-01-01

Arnold Belkin was one of the most important exponents of the new muralism, in his paintings topics like war, dead, injustice, as well as hope, peace, society transformation and science benefits to the humankind were always related. One of these murals is the 'Los Prometeos' located at Managua, Nicaragua. This mural painting actually is suffering a localized deterioration by weather conditions (humidity) and manufacture techniques. Samples were collected from different spots of mural which shows the deterioration problem, in order to characterized them scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray diffraction were used to analyzed the soluble salts influences (sulfates and chlorides) in the deterioration mechanism problem. (Author) 9 refs., 10 tabs., 17 figs

33 CFR 118.140 - Painting bridge piers.

Science.gov (United States)

2010-07-01

... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Painting bridge piers. 118.140 Section 118.140 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY BRIDGES BRIDGE LIGHTING AND OTHER SIGNALS § 118.140 Painting bridge piers. The District Commander may require...

Noise resistance applied to the study paints; Aplicacion de la tecnica de ruido electroquimico al estudio de pinturas comerciales de efecto barrera

Energy Technology Data Exchange (ETDEWEB)

Lanchas Garcia-Zarco, S.; Alfosin Perez, V.; Suarez Garcia, A.; Urrejola Madrinan, S.; Sanchez Bermudez, A.

2015-03-30

Electrochemical noise is one of the methods of analysis used to interpret the phenomenon of corrosion. It has a number of advantages over other methodology types including its simplicity, its low cost and the fact that it does not disturb the system. This methodology appears to be effective together with other techniques in metal-electrolyte systems. In this case the technique is applied on its own on commercial anti-corrosion paints for which no information is available from other techniques. The main result of this study reveals the effectiveness of the noise resistance parameter, which had already been tested in the lab, when it is used to explain how the paint system behaves in industry. (Author)

Identification of the chemical inventory of different paint types applied in nuclear facilities

International Nuclear Information System (INIS)

Sabrina Tietze; Foreman, M.R.St.J.; Ekberg, CH.H.; Chalmers University of Technology, Chemical and Biological Engineering, Goeteborg; Dongen van, B.E.

2013-01-01

The floors, concrete walls and many of the metal surfaces in nuclear power plant containments are coated with zinc primers or paint films to preserve the metal surfaces and simplify decontamination in the containment after the occurrence of a severe nuclear incident or accident. A chemical examination of paint films from different nuclear installations out of operation, as well as current operating ones, reveals that different types of paints are used whose composition can vary significantly. Results obtained for one type of paint at a certain nuclear site are in most cases unlikely to be comparable with sites painted with another type of paint. During normal operation and particularly during nuclear accidents, the paints will degrade under the high temperature, steam and irradiation influence. As paint and its degradation products can act as sources and depots for volatile iodine compounds, the type and aging conditions of the paint films will have a significant impact on the source term of the volatile fission product iodine. Thus, great care should be taken when extrapolating any results obtained for the interaction of radioactive iodine with one paint product to a different paint product. The main focus of the study is a comparison of the chemical profile of paint films applied in Swedish nuclear power plants. Teknopox Aqua V A, an epoxy paint recently used at Ringhals 2, and an emulsion paint used in the scrubber buildings of Ringhals 1-4 are compared with a paint film from Barsebaeck nuclear power plant unit 1 that had been aged under real reactor conditions for 20 years. In addition, two paint films, an emulsion and a gloss paint, used in an international nuclear fuel reprocessing facility, are compared with the paints from the Swedish nuclear power plants. (author)

Chromosome painting analysis of X-ray-induced aberrations in human lymphocytes in vitro

International Nuclear Information System (INIS)

Matsuoka, A.; Hayashi, M.; Yamazaki, N.; Sofuni, T.

1994-01-01

Chromosomal rearrangements in human lymphocytes induced by X-rays (0, 0.5, 1.0 and 2.0 Gray) were analyzed using chromosome painting. DNA probes for human chromosomes 1, 3 or 4 alone, and a combination of 1 and 4, were used for analysis. The frequency of cells with rearrangements, i.e. reciprocal translocations, dicentrics, insertions, tricentrics and fragments, involving chromosome 4 increased with dose in both 48 and 72 h cultures. The number of translocations per cell also increased with dose at 48 and 72 h. Dicentrics increased with dose in 48 h but not in 72 h cultures. The estimated genomic frequency of aberrations per cell was comparable with results in banded cells. No difference was shown on the detection efficiency of chromosome rearrangements among the various DNA probes used. Since this technique does not necessarily require well-spread metaphases for analysis, it is possible to increase the number of analyzable metaphases compared with the banding technique. Chromosome painting is a simpler, more objective and practical method for detecting chromosome rearrangements than conventional banding analyses. (Author)

Aerial vehicle with paint for detection of radiological and chemical warfare agents

Science.gov (United States)

Farmer, Joseph C.; Brunk, James L.; Day, S. Daniel

2013-04-02

A paint that warns of radiological or chemical substances comprising a paint operatively connected to the surface, an indicator material carried by the paint that provides an indication of the radiological or chemical substances, and a thermo-activation material carried by the paint. In one embodiment, a method of warning of radiological or chemical substances comprising the steps of painting a surface with an indicator material, and monitoring the surface for indications of the radiological or chemical substances. In another embodiment, a paint is operatively connected to a vehicle and an indicator material is carried by the paint that provides an indication of the radiological or chemical substances.

Are Shaman Paintings Material Religion or Religious Art?

OpenAIRE

Jong-chun Park

2017-01-01

Laurel Kendall, Jongsung Yang, and Yul Soo Yoon. God Pictures in Korean Contexts: The Ownership and Meaning of Shaman Paintings. Honolulu: University of Hawai'i Press, 2015. God Pictures in Korean Contexts: The Ownership and Meaning of Shaman Paintings is a pioneering work, one that explores the proverbial “road not taken” by previous research on the subject. The authors situate “the lives of Korean shaman paintings [musindo] in a complex South Korean world; in shaman shrines, private co...

Examining the ground layer of St. Anthony from Padua 19th century oil painting by Raman spectroscopy, scanning electron microscopy and X-ray diffraction

International Nuclear Information System (INIS)

Vančo, Ľubomír; Kadlečíková, Magdaléna; Breza, Juraj; Čaplovič, Ľubomír; Gregor, Miloš

2013-01-01

Highlights: ► Raman spectroscopic examination of uncovered and covered paint layers of a real painting. ► Deconvolution of Raman peaks of lead white. ► Comparison of results with energy-dispersive analysis and X-ray diffraction. - Abstract: In this paper we studied the material composition of the ground layer of a neoclassical painting. We used Raman spectroscopy (RS) as a prime method. Thereafter scanning electron microscopy combined with energy dispersive spectroscopy (SEM–EDS) and X-ray powder diffraction (XRD) were employed as complementary techniques. The painting inspected was of the side altar in King St. Stephen's Church in Galanta (Slovakia), signed and dated by Jos. Chr. Mayer 1870. Analysis was carried out on both covered and uncovered ground layers. Four principal compounds (barite, lead white, calcite, dolomite) and two minor compounds (sphalerite, quartz) were identified. This ground composition is consistent with the 19th century painting technique used in Central Europe consisting of white pigments and white fillers. Transformation of lead white occurred under laser irradiation. Subdominant Raman peaks of the components were measured. The observed results elucidate useful partnership of RS and SEM–EDS measurements supported by X-ray powder diffraction as well as possibilities and limitations of non-destructive analysis of covered lower layers by RS.

WORKING POSTURE ANALYSIS AND DESIGN USING RULA (RAPID UPPER LIMB ASSESSMENT METHOD IN PRODUCTION PROCESS AT PT. INDANA PAINT

Directory of Open Access Journals (Sweden)

Yongky Kusnandar Djiono

2013-12-01

Full Text Available Working posture can affect the comfort and productivity of labor in doing manual work. In this study, RULA method is used to determine the risk level of musculoskeletal disorders (MSDs injury in the production process at PT. Indana Paint (consists of mixing and packaging steps for water-based paint, solvent-based paint, and base paint production, and then given proposed improvements to reduce the risk level. Method used in this research is direct observation and video recording of every work element to determine some awkward postures that will be assessed using RULA method. Thirty awkward postures are found, there are 7 working posture (23.3% have low risk level, 11 working posture (36.7% have medium risk level, and 12 working posture (40% have high risk level. Proposed improvements given is to brief the workers on appropriate lifting technique and working methods, adding mechanical aids for handling drums, and working position height adjustment.

EDXRF Analysis of pigments of the Joaquin Sorolla Artistic Paintings

International Nuclear Information System (INIS)

Ferrero, Jose L.; Roldan Clodoaldo, David; Mario Alvarez, Juanes

1999-01-01

The study of the pictorial work of Joaquin Sorolla has not been carried out from the point of view of the scientific analysis. Analytical techniques give us objective information about materials and process used in artistic works of art. In this sense, the Archaeometry Unit of the Institute of Material Science of the Valencia University (ICMUV), has carried out the first analysis of pigments of the paintings of Sorolla by Energy Dispersive X-Ray Fluorescence(EDXRF)

13 CFR 120.173 - Lead-based paint.

Science.gov (United States)

2010-01-01

... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Lead-based paint. 120.173 Section 120.173 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS LOANS Policies Applying to All Business Loans Requirements Imposed Under Other Laws and Orders § 120.173 Lead-based paint. If...

Nanoclays for polymer nanocomposites, paints, inks, greases

Indian Academy of Sciences (India)

... rheological modifier for paints, inks and greases, drug delivery vehicle for controlled release of therapeutic agents, and nanoclays for industrial waste water as well as potable water treatment to make further step into green environment. A little amount of nanoclay can alter the entire properties of polymers, paints, inks and ...

A study on impact monitoring using a piezoelectric paint sensor

International Nuclear Information System (INIS)

Choi, Kyung Woo; Kang, Dong Hoon; Park, Seung Bok; Kang, Lae Hyong

2015-01-01

The piezoelectric paint sensor is a paint type sensor comprising of an epoxy and piezoelectric powder, which is the main component of a piezoelectric material. This sensor can be easily attached to any type of structure as compared to other sensors because it is viable to directly apply it on structures, as in the case with a typical paint. In this study, the capability of piezoelectric paint sensor for impact detection was evaluated. In Particular, the applications of the piezoelectric paint sensor for railroad vehicles were considered. There have been various cases reported about the damages caused by flying gravel to the under-cover of the railroad vehicle during operation. In order to prevent this, real-time monitoring of the large under-cover surface of the railroad vehicle is unavoidable. Under the assumption of vehicle application, sensor sensitivities were measured after multiple and prolonged exposure to thermal cycle environment -20⁓60 degrees Celsius). Sensitivity evaluation of paint sensor under environmental conditions was conducted in an aluminum specimen. In results, despite the small variations in sensitivity, we could confirm the applicability of this paint sensor for impact detection even after a severe environmental exposure test

Zhang Qing and His Meticulous Chinese Paintings

Institute of Scientific and Technical Information of China (English)

JULIE; M.SEGRAVES

2002-01-01

ZHANG Qing was initially drawn to the bird and flower paint-ings of the Tang and Song dynasties (7th-12th centuries). Later,Qing Dynasty (1644-1911) artist Ren Bonian, famous for hispaintings of figures, also became an important influence.Although Zhang Qing considers his style to be firmly rooted in tradi-

Nondestructive multispectral reflectoscopy between 800 and 1900 nm: An instrument for the investigation of the stratigraphy in paintings.

Science.gov (United States)

Karagiannis, G; Salpistis, Chr; Sergiadis, G; Chryssoulakis, Y

2007-06-01

In the present work, a powerful tool for the investigation of paintings is presented. This permits the tuneable multispectral real time imaging between 200 and 5000 nm and the simultaneous multispectral acquisition of spectroscopic data from the same region. We propose the term infrared reflectoscopy for tuneable infrared imaging in paintings (Chryssonlakis and Chassery, The Application of Physicochemical Methods of Analysis and Image Processing Techniques to Painted Works of Art, Erasmus Project ICP-88-006-6, Athens, June, 1989) for a technique that is effective especially when the spectroscopic data acquisition is performed between 800 and 1900 nm. Elements such as underdrawings, old damage that is not visible to the naked eye, later interventions or overpaintings, hidden signatures, nonvisible inscriptions, and authenticity features can thus be detected with the overlying paint layers becoming successively "transparent" due to the deep infrared penetration. The spectroscopic data are collected from each point of the studied area with a 5 nm step through grey level measurement, after adequate infrared reflectance (%R) and curve calibration. The detection limits of the infrared detector as well as the power distribution of the radiation coming out through the micrometer slit assembly of the monochromator in use are also taken into account. Inorganic pigments can thus be identified and their physicochemical properties directly compared to the corresponding infrared images at each wavelength within the optimum region. In order to check its effectiveness, this method was applied on an experimental portable icon of a known stratigraphy.

Sadhana | Indian Academy of Sciences

Indian Academy of Sciences (India)

... a simple delta wing in low supersonic flow (M = 1·8). The PSP system utilized for both the cases involve Optrod- B 1 paint, a specially designed UV lamp for excitation and two scientific grade CCD cameras for imaging. Typical results are shown using both the algebraic transformation approach and resection methodology.

A New Quantitative Method for the Non-Invasive Documentation of Morphological Damage in Paintings Using RTI Surface Normals

Directory of Open Access Journals (Sweden)

Marcello Manfredi

2014-07-01

Full Text Available In this paper we propose a reliable surface imaging method for the non-invasive detection of morphological changes in paintings. Usually, the evaluation and quantification of changes and defects results mostly from an optical and subjective assessment, through the comparison of the previous and subsequent state of conservation and by means of condition reports. Using quantitative Reflectance Transformation Imaging (RTI we obtain detailed information on the geometry and morphology of the painting surface with a fast, precise and non-invasive method. Accurate and quantitative measurements of deterioration were acquired after the painting experienced artificial damage. Morphological changes were documented using normal vector images while the intensity map succeeded in highlighting, quantifying and describing the physical changes. We estimate that the technique can detect a morphological damage slightly smaller than 0.3 mm, which would be difficult to detect with the eye, considering the painting size. This non-invasive tool could be very useful, for example, to examine paintings and artwork before they travel on loan or during a restoration. The method lends itself to automated analysis of large images and datasets. Quantitative RTI thus eases the transition of extending human vision into the realm of measuring change over time.

Fabrication and calibration of a piezoelectric nanocomposite paint

Science.gov (United States)

Osho, Samuel; Wu, Nan; Aramfard, Mohammad; Deng, Chuang; Ojo, Olanrewaju

2018-03-01

A new liquid form piezoelectric nanocomposite paint material is fabricated with possible applications as dynamic strain sensors and/or piezoelectric transducers. The applied coating is in the form of low-cost paint, which is flexible and bonds strongly on a metallic surface after drying out via the solvent-casting method. The nanocomposite is produced by an ultrasonic mixture of varying percentages of zinc oxide (ZnO) nanoparticle water dispersion, poly vinyl acetate glue (PVA) and carbon nanotubes (CNTs). ZnO nanoparticles are used as the piezoelectric sensing elements in a PVA matrix of the paint, while CNTs are introduced as robust bridge of ZnO particles enhancing the piezoelectricity and material properties. Transmission electron microscopy (TEM) images confirmed the linkages of ZnO nanoparticles in the composite by CNTs. Through piezoelectricity calibration, the optimum mixing ratio with the highest piezoelectricity is 78.1 wt% ZnO, 19.5 wt% PVA glue and 2.4 wt% multi-wall carbon nanotubes (MWCNTs). Through nanoindentation tests for the characterization of the mechanical properties of the nano-composite paint, it is found that Young’s modulus and hardness reached a threshold point in the increment in the addition of CNTs to the paint before showing signs of decline. Detailed analysis and explanation of the calibration results and physical phenomenon are provided. The stable paint material is ready to be applied on rough area of engineering structures as sensor and transducer.

Cleaning and Restoration of an Oil Painting with a Polymer Gel in Iran

Directory of Open Access Journals (Sweden)

Siyamak Alizadeh

2018-03-01

Full Text Available One of the major stages in the conservation and restoration of a painting is to clean its colored surface of unwanted stains, and old and darkened varnishes. Various solvents have been used to date for this purpose; however, new cleaning materials have also come onto the market in the past decade that are still unknown and may never have been employed in Iran. The present study aims to introduce a polymer gel and use an in vitro sample of the substance for cleaning and to then present the results of the tests carried out. Applying a polymer gel in the cleaning of paintings yielded better results and greater advantages over the solvents previously used to clean artworks. The advantages include, performing on the surface without penetrating the lower layers, the absence of residues after application, flexibility, solubility and the gentle removal of old stains and varnishes, maintaining clarity and cleaning the surface by simple removal of the thin dried layer, which requires no mechanical pressure. Microscopic examinations and pH testing showed that this new alternative technique can be of use in cleaning the color layers of oil paintings.

Studies on some Indian paints for radiochemical plants

International Nuclear Information System (INIS)

Mahesh Kumar, V.V.; Srinivasan, R.; Natarajan, R.

1996-01-01

The choice of paints in areas subjected to contamination and radiation in nuclear installation need special attention. The types of generic coatings are examined with reference to these requirements. Among those examined, certain types of epoxy paints are found to be attractive for these applications. Samples of epoxy paints obtained from some Indian manufacturers are tested for their suitability. Decontaminability and radiation resistance properties are also evaluated with special reference to radiochemical plants. Important specifications for such applications are listed. This report summarizes the results of these studies. (author)

Noise resistance applied to the study of zinc rich paints; Aplicacion de la resistencia de ruido al estudio de pinturas ricas en zinc

Energy Technology Data Exchange (ETDEWEB)

Espada Recarey, L.; Sanchez Bermudez, A.; Urrejola Madrinan, S.; Bouzada Alvela, F. [Universidad de Vigo (Spain)

2001-07-01

Electrochemical Noise has been one of the more useful analysis methods to the study the corrosion processes due to the fact that it is simple and cheap. The objective of this work is to check the efficiency of this technique when it is applied to the study of Rich Zinc Paints and specifically the Noise Resistance parameter which is very efficiency to study metal-electrolyte systems. Then this technique was applied to Rich Zinc Paints systems of which we have already information by means of electrochemical impedance spectroscopy. The outcomes of this paper show the efficiency of applying Noise Resistance technique to explain the behavior of this kind of systems. (Author) 18 refs.

Can painted glass felt or glass fibre cloth be used as vapour barrier?

DEFF Research Database (Denmark)

El-Khattam, Amira; Andersen, Mie Them; Hansen, Kurt Kielsgaard

2014-01-01

In most Nordic homes the interior surfaces of walls and ceilings have some kind of surface treatment for aesthetical reasons. The treatments can for example be glass felt or glass fibre cloth which are painted afterwards. To evaluate the hygrothermal performance of walls and ceilings...... treatments. The surface treatments were glass felt or glass fibre cloth with different types of paints or just paint. The paint types were acrylic paint and silicate paint. The results show that the paint type has high influence on the water vapour resistance while the underlay i.e. glass felt or glass fibre...... acrylic paint on glass felt or glass fibre cloth cannot be used instead of a vapour barrier....

Library Signage: Applications for the Apple Macintosh and MacPaint.

Science.gov (United States)

Diskin, Jill A.; FitzGerald, Patricia

1984-01-01

Describes specific applications of the Macintosh computer at Carnegie-Mellon University Libraries, where MacPaint was used as a flexible, easy to use, and powerful tool to produce informational, instructional, and promotional signage. Profiles of system hardware and software, an evaluation of the computer program MacPaint, and MacPaint signage…

Elemental composition of paint cross sections by nuclear microprobe analysis

International Nuclear Information System (INIS)

Nens, B.; Trocellier, P.; Engelmann, C.; Lahanier, C.

1982-09-01

Physico-chemical characterization of pigments used in artistic painting give precious indications on age of paintings and sometimes on geographical origin of ores. After recalling the principle of protons microprobe, first results obtained by microanalysis of painting cross sections for non destructive microanalysis of impurities in white lead are given [fr

Factors effecting paint performance on wood siding

Science.gov (United States)

Christopher G. Hunt; R. Sam Williams; Mark Knaebe; Peter Sotos; Steven Lacher

2009-01-01

Several different studies are compared to assess the effectiveness of commercial water repellent preservatives (WRP’s) in the late 1990’s on vertical and horizontal siding. Besides WRP, variables included wood species, exposure location (Wisconsin or Mississippi), and solid color stain vs. primer + paint. Data on substrate checking and paint flaking are presented....

The Sign System in Chinese Landscape Paintings

Science.gov (United States)

McMahon, Cliff G.

2003-01-01

Paintings emerge from a culture field and must be interpreted in relation to the net of culture. A given culture will be implicated by the sign system used by the painter. Everyone agrees that in Chinese landscape paintings, the most important cultural bond is to ancient Chinese Taoism, and to a lesser degree, to Confucianism. Obviously, then, the…

The genesis of Jan Steens painting 'As the old ones sing, so the young ones pipe' from the Gemaeldegalerie Berlin

International Nuclear Information System (INIS)

Denker, A.; Kleinert, K.; Laurenze-Landsberg, C.; Reimelt, M.; Schroeder-Smeibidl, B.

2011-01-01

In collaboration with the research reactor of the Helmholtz-Zentrum Berlin fuer Materialien und Energie, the Gemaeldegalerie Berlin is the only institute worldwide, which systematically employs the method of Neutron-Activation-Autoradiography to analyze paintings and painting techniques. To date more than 70 paintings were investigated with this effective, non-destructive, and exceptional method. It allows the visualization of structures and layers beneath the top surface and, in addition, enables the identification of elements contained in the pigments. The instrument B8 at the research reactor BER II is dedicated to this research. Jan Steen is one of the prolific artists from the 17th century. Like other artists from that time he produced several versions of one specific topic during life-time. The topic 'As the old ones sing, so the young ones pipe' was painted by Jan Steen in 13 versions. The painting from the Gemaeldegalerie is an exception in this series as it differs in style and content from the other oeuvres. The question arises: why did the artist deviate from his usual scheme? The possible answer is provided by X-ray images and neutron autoradiographs made of the painting, allowing insight into hidden paint layers and, therefore, in the genesis of the painting. Jan Steen did not simply change the composition of the room and the figures. He originally intended an altogether different topic. Assumedly it was supposed to be a so-called merry company, located in a generous, stately room. Many pieces of this sophisticated ambiance have been eliminated from the version visible today; others were modified and integrated into the composition of the new painting. Thus, Jan Steen commenced the topic 'As the old ones sing, so the young ones pipe' from a different context.

Conservation of a group of Chinese paintings and calligraphies from the Camilo Pessanha collection: an example of a "less oriental" approach

Directory of Open Access Journals (Sweden)

Miguel J. L. Lourenço

2011-01-01

Full Text Available This paper presents the conservation treatment of a group of twenty Chinese calligraphies and paintings. These artworks are part of the Camilo Pessanha (1867-1926 collection that belongs to the Museu Nacional de Machado de Castro, and are currently on loan to the Museu do Oriente in Lisbon. The project was managed by the Fundação Oriente, and carried out at the conservation and restoration department of the Instituto dos Museus e da Conservação. There were three groups of works of art: scrolls with paintings and calligraphy on paper; scrolls with paintings on gilded paper; and paintings on silk. A brief characterization of the oriental scroll is followed by an overview of the traditional oriental conservation techniques for this type of art, as well as recently described practices. Ethical and theoretical considerations relating to the conservation treatments will be also discussed.

Identification and comparison of lead white of the 15-th century Gdansk panel paintings by neutron activation analysis

International Nuclear Information System (INIS)

Olszewska-Swietlik, J.; Panczyk, E.

2005-01-01

The lead white has been used in painting science the middle ages both as a priming ground and pigment. Purity of the lead white is directly connected with the lead purification methods that have undergone considerable changes throughout centuries. Marked progress in this respect was noted in the 19-th century. That is why determination of such elements a Ag, Hg, Zn, Cu, Co, Cr, Ba and Sb in the lead white gives reliable information regarding the age of the painting in question. Analyses of samples of the lead white taken from genuine 15-th century panel paintings representing the so-called Pomeranian school were carried out using instrumental neutron activation analysis technique. The total of 32 elements were determined in those samples; also the comparison of the data for Malopolska and Silesian schools was performed. (author)

Matte painting in stereoscopic synthetic imagery

Science.gov (United States)

Eisenmann, Jonathan; Parent, Rick

2010-02-01

While there have been numerous studies concerning human perception in stereoscopic environments, rules of thumb for cinematography in stereoscopy have not yet been well-established. To that aim, we present experiments and results of subject testing in a stereoscopic environment, similar to that of a theater (i.e. large flat screen without head-tracking). In particular we wish to empirically identify thresholds at which different types of backgrounds, referred to in the computer animation industry as matte paintings, can be used while still maintaining the illusion of seamless perspective and depth for a particular scene and camera shot. In monoscopic synthetic imagery, any type of matte painting that maintains proper perspective lines, depth cues, and coherent lighting and textures saves in production costs while still maintaining the illusion of an alternate cinematic reality. However, in stereoscopic synthetic imagery, a 2D matte painting that worked in monoscopy may fail to provide the intended illusion of depth because the viewer has added depth information provided by stereopsis. We intend to observe two stereoscopic perceptual thresholds in this study which will provide practical guidelines indicating when to use each of three types of matte paintings. We ran subject tests in two virtual testing environments, each with varying conditions. Data were collected showing how the choices of the users matched the correct response, and the resulting perceptual threshold patterns are discussed below.

Finite Element Modeling of Vibrations in Canvas Paintings

NARCIS (Netherlands)

Chiriboga Arroyo, P.G.

2013-01-01

Preventing vibration damage from occurring to valuable and sensitive canvas paintings is of main concern for museums and art conservation institutions. This concern has grown in recent years due to the increasing demand of paintings for exhibitions worldwide and the concomitant need for their

Opportunities application of cleaner production practices in paint industry

International Nuclear Information System (INIS)

Mohammed, Y. S. Y.

2010-08-01

There are releases of volatile organic compounds VOC from paint manufacturing process steps and from cleaning operations in El Mohandas Paint Factory. These emission can cause health, safety and productivity problems in the work area. Hence cleaner production application is necessary in this case. Some of the manufacturing processes and equipment used to accomplish these manufacturing are analyzed and generate cleaner production opportunities, implement some of cleaner production solutions of VOC emission control by some of the methods used by paint facilities in reducing emissions. It was found that there is no control available for emissions factors in paints manufacturing process, so that VOC emission based on raw material consumption rather than calculation emission from processes or equipment by alternative method. (Author)

Study of the Wall Paintings of the Cenador Del Leon in the Real Alcazar of Seville

Science.gov (United States)

Robador, Maria Dolores; Mancera, Inmaculada; Perez-Maqueda, Rafael; Albardonedo, Antonio

2017-10-01

The paintings on the walls of the Cenador del Leon located in the gardens of the Real Alcazar in Seville next to the Pabellon de Carlos V in the Jardin Ingles area have been studied. The components of the wall paintings cross-sections, which were prepared using small samples taken from the walls of Cenador del Leon, were characterized using infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis. The cross-sections of the collected samples indicated that the paint layer is well adhered to the preparation layer without any discontinuity, and only one carbonation layer exists at the top of the sequence of layers. These data suggest that the paint was applied on a fresco surface, and therefore, the adopted technique was fresco. Based on the different elements detected by EDX analysis of the cross-sections, the detected pigments included iron oxides accompanied by clay minerals (or earths) in the red pink, golden yellow and yellow colours, blue smelt for the blue colour and basic copper chloride (atacamite) for the green colour. In one sample, the particles were composed of Ba and S from barium sulphate and Ti and O from rutile titanium oxide due to a modern pigment.

Non-destructive micro-analytical differentiation of copper pigments in paint layers of works of art using laboratory-based techniques

Czech Academy of Sciences Publication Activity Database

Švarcová, Silvie; Čermáková, Zdeňka; Hradilová, J.; Bezdička, Petr; Hradil, David

2014-01-01

Roč. 132, NOV (2014), s. 514-525 ISSN 1386-1425 Institutional support: RVO:61388980 Keywords : Copper pigments * Infrared spectroscopy * Microanalysis * Model experiments * Paintings * Powder X-ray micro-diffraction Subject RIV: CA - Inorganic Chemistry Impact factor: 2.353, year: 2014

Test Production of Anti-Corrosive Paint in Laboratory Scale

International Nuclear Information System (INIS)

Thein Thein Win, Daw; Khin Aye Tint, Daw; Wai Min Than, Daw

2003-02-01

The main purpose of this project is to produce the anti-corrosive paint in laboratory scale. In these experiments, local raw materials, natural resin (shellac), pine oil, turpentine and ethyl alcohol wer applied basically. Laboratory trials were undrtaken to determine the suitablity of raw materials ane their composition for anti-corrosive paint manufacture.The results obtained show that the anti-corrosive paint from experiment No.(30) is suitable for steel plate and this is also considered commercially economics

Pendekatan Pemandangan Realistik dengan Menggunakan Digital Matte Painting

Directory of Open Access Journals (Sweden)

Satrya Mahardhika

2011-04-01

Full Text Available Movie is one entertainment that is favored by most people. Scenery appearance and spectacular shoots made movie needs high budget for the production. There are shoots looking difficult and needing extra efforts, but obviously it could be solved by using latest technology. Such technology is a combination of 3D and digital painting or image so it could bring digital painting alive: matte painting, a breakthrough in visual effects and movie. The research is conducted through exploration from manipulated images, references and retrieved real images in the specific place. Camera movement is also an important frame to define how far the image will be seen in the camera. So, when it is applied, it has no images that less-showed in camera framing. Although it has limitation in 2D images taken from limited frame, digital matte painting is able to answer industry needs in entertainment to create things that look real.  

Synthesis of goodness and beauty of Petrikivsky decorative painting

Directory of Open Access Journals (Sweden)

T. A. Harkava

2017-06-01

Full Text Available Petrykivsky decorative painting as a unique manifestation of Ukrainian national culture has been studied in the article. This painting is recognized all over the world as an intangible cultural heritage of humanity in the context of its philosophical principles. Petrykivsky decorative painting by its basis — murals,  reaches Tripoli and puts the Ukrainian culture among the ancient cultures of the world. At various stages of ethnos’ existence, Ukrainian folk decorative art was an important part of the spiritual life and reflected its identity, ensuring the continuity of spiritual connection between generations. Motives of Petrykivka decorative painting describe the local flora and fauna and the local historical tradition. Folk artists get their inspiration from the mother nature, traditional for the Ukrainian people worship to Mother-land and all beautiful things, which are created by it. However, Petrykivsky decorative painting is not a direct reflection of natural motifs. World, created in paintings, is the product of the imagination of folk artist. Calocagathia (synthesis of beauty and goodness of Petrykivsky school is seen in high spiritual and moral culture of the Ukrainian people, in their pursuit to improve the space of their life, to perpetuate the generous beauty of the world by the love to beauty and goodness in all its forms using a variety of colors and patterns.

Characterization of TCHQ-induced genotoxicity and mutagenesis using the pSP189 shuttle vector in mammalian cells

Energy Technology Data Exchange (ETDEWEB)

Wang Jing, E-mail: avaecn@gmail.com [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China); Yu Shouyi [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China); Jiao Shouhai [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China); Shandong Institute of Endocrine and Metabolic Diseases, Shandong Academy of Medical Sciences, Jinan 250062 (China); Lv Xiaowen [Feed Safety Reference Laboratory of Ministry of Agriculture, Feed Research Institute, Chinese Academy of Agricultural Sciences, Beijing 100081 (China); Ma Min [Laboratory of Environmental Biotechnology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China); Zhu Benzhan; Du Yuguo [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China)

2012-01-03

Tetrachlorohydroquinone (TCHQ) is a major toxic metabolite of the widely used wood preservative, pentachlorophenol (PCP), and it has also been implicated in PCP genotoxicity. However, the underlying mechanisms of genotoxicity and mutagenesis induced by TCHQ remain unclear. In this study, we examined the genotoxicity of TCHQ by using comet assays to detect DNA breakage and formation of TCHQ-DNA adducts. Then, we further verified the levels of mutagenesis by using the pSP189 shuttle vector in A549 human lung carcinoma cells. We demonstrated that TCHQ causes significant genotoxicity by inducing DNA breakage and forming DNA adducts. Additionally, DNA sequence analysis of the TCHQ-induced mutations revealed that 85.36% were single base substitutions, 9.76% were single base insertions, and 4.88% were large fragment deletions. More than 80% of the base substitutions occurred at G:C base pairs, and the mutations were G:C to C:G, G:C to T:A or G:C to A:T transversions and transitions. The most common types of mutations in A549 cells were G:C to A:T (37.14%) and A:T to C:G transitions (14.29%) and G:C to C:G (34.29%) and G:C to T:A (11.43%) transversions. We identified hotspots at nucleotides 129, 141, and 155 in the supF gene of plasmid pSP189. These mutation hotspots accounted for 63% of all single base substitutions. We conclude that TCHQ induces sequence-specific DNA mutations at high frequencies. Therefore, the safety of using this product would be carefully examined.

Characterization of aerosols produced by laser-matter interaction during paint-stripping experiments by laser

International Nuclear Information System (INIS)

Dewalle, P.

2009-01-01

Laser ablation is one of the physical processes that are being considered for paint stripping in possibly contaminated areas, especially for decommissioning and dismantling of nuclear facilities. In this regard, the knowledge of 'ablation products', consisting of particles and gases, is an important issue.The numeric and weight concentration of particles, their size distribution, their morphology and their density have been determined for laser ablation of two wall paints. The main gas species have also been identified. The aerosol is composed of nano-particles, of which the number is predominant, and sub-micron particles. Their morphologies and their chemical composition are very distinct: carbon aggregates have been identified, as well as spherical particles of titanium dioxide. These results show that nano-scale aggregates come from the vaporization of the paint polymer, whereas sub-micron particles are due to mechanical ejection of titanium dioxide particles. The expansion of the plume resulting from laser-paint interaction has been monitored by means of three optical techniques: light extinction, scattering and emission. The frames show the propagation of a shock wave followed by the ejection of matter with a specific 'mushroom' shape. Measurements based on these results show that the peripheral part of the plume contains the primary particles of carbon aggregates; it is the warmest area, which reaches a few thousands Kelvin degrees. Its central part is composed of titanium dioxide spherical particles. (author) [fr

PaintShop Photo Pro X3 For Photographers

CERN Document Server

McMahon, Ken

2010-01-01

If you are a digital photographer who's new to PaintShop Photo Pro or digital imaging in general, or have recently upgraded to the all-new version X3, this is the book for you! Packed with full color images to provide inspiration and easy to follow, step-by-step projects, you'll learn the ins and outs of this fantastic program in no time so you can start correcting and editing your images to create stunning works of art. Whether you want to learn or refresh yourself on the basics, such as effective cropping or simple color correction, or move on to more sophisticated techniques like creating s

A technique to identify annual growth rings in Eucalyptus grandis using annual measurements of diameter at breast height and gamma ray densitometry

CSIR Research Space (South Africa)

Naidoo, Sasha

2010-06-01

Full Text Available A technique was developed to identify annual growth rings in E. grandis using a combination of annual measurements of diameter at breast height (DBH) from permanent sample plot (PSP) datasets and bark-pith density profiles. By assessing the pattern...

What You Should Know about Using Paint Strippers

Science.gov (United States)

... is readily absorbed through the skin and may cause health problems. Adverse health effects in the developing fetus have been noted in laboratory animals exposed to some of the chemicals in paint strippers. Therefore, women of child-bearing age who work with or use paint strippers on a regular ...

Isothiazolinones are still widely used in paints purchased in five European countries

DEFF Research Database (Denmark)

Thomsen, Andreas V.; Schwensen, Jakob F.; Bossi, Rossana

2018-01-01

BACKGROUND: An increasing incidence of contact allergy to methylisothiazolinone (MI) has been seen, caused, in particular, by cosmetic products and paints. A study from 2015 showed that 93.0% of paints bought in five European countries contained MI. New regulations have been discussed for paints...... in the EU, which may have influenced this market. OBJECTIVES: To re-evaluate the use and concentrations of MI and four other isothiazolinones in water-based wall paints. METHODS: Water-based white wall paints (n = 60) were purchased in retail stores in five European countries: Denmark, France, Germany...

Capabilities and limitations of handheld Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) for the analysis of colourants and binders in 20th-century reverse paintings on glass

Science.gov (United States)

Steger, Simon; Stege, Heike; Bretz, Simone; Hahn, Oliver

2018-04-01

A non-invasive method has been carried out to show the capabilities and limitations of Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) for identifying of colourants and binders in modern reverse glass paintings. For this purpose, the reverse glass paintings "Zwei Frauen am Tisch" (1920-22), "Bäume" (1946) (both by Heinrich Campendonk), "Lofoten" (1933) (Edith Campendonk-van Leckwyck) and "Ohne Titel" (1954) (Marianne Uhlenhuth), were measured. In contrast to other techniques (e.g. panel and mural painting), the paint layers are applied in reverse succession. In multi-layered paint systems, the front paint layer may no longer be accessible. The work points out the different spectral appearance of a given substance (gypsum, basic lead white) in reverse glass paintings. However, inverted bands, band overlapping and derivative-shaped spectral features can be interpreted by comparing the spectra from the paintings with spectra from pure powders and pigment/linseed oil mock-ups. Moreover, the work focuses on this method's capabilities in identifying synthetic organic pigments (SOP). Reference spectra of three common SOP (PG7, PY1, PR83) were obtained from powders and historical colour charts. We identified PR83 and PY1 in two reverse glass paintings, using the measured reference spectra. The recorded DRIFTS spectra of pure linseed oil, gum Arabic, mastic, polyvinyl acetate resin and bees wax can be used to classify the binding media of the measured paintings.

PMT signal increase using a wavelength shifting paint

Energy Technology Data Exchange (ETDEWEB)

Allada, K. [Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Hurlbut, Ch. [Eljen Technology, Sweetwater, TX 79556 (United States); Ou, L.; Schmookler, B. [Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Shahinyan, A. [Yerevan Physics Institute, Yerevan (Armenia); Wojtsekhowski, B., E-mail: bogdanw@jlab.org [Thomas Jefferson National Accelerator Facility, Newport News, VA 23606 (United States)

2015-05-11

We report a 1.65 times increase of the PMT signal and a simple procedure of application of a new wavelength shifting (WLS) paint for PMTs with non-UV-transparent windows. Samples of four different WLS paints, made from hydrocarbon polymers and organic fluors, were tested on a 5-in. PMT (ET 9390KB) using Cherenkov radiation produced in fused silica disks by {sup 106}Ru electrons on a ‘table-top’ setup. The best performing paint was employed on two different types of 5-in. PMTs (ET 9390KB and XP4572B), installed in atmospheric pressure CO{sub 2} gas Cherenkov detectors, and tested using GeV electrons.

Preventive conservation applied to "Casa dos Patudos" oil painting collection

Directory of Open Access Journals (Sweden)

Mafalda Fernandes

2016-01-01

Full Text Available The main objective of this work was the identification of specific risks affecting the collection of oil paintings in the historic house "Casa dos Patudos" (Alpiarça, Portugal and the development of mitigation strategies for the risks encountered. The methodology used was proposed by the Canadian Conservation Institute. The results showed that the main risks affecting this collection result from incorrect handling, increase in paint detachment due to the maintenance of paintings with paint lifting on display, occurrence of insect pests, high fluctuations in relative humidity and, excessive exposure to ultraviolet radiation. Several preventive conservation strategies to mitigate these risks are proposed.

On Degradation of Cast Iron Surface-Protective Paint Coat Joint

Directory of Open Access Journals (Sweden)

Tupaj M.

2016-09-01

Full Text Available The paper is a presentation of a study on issues concerning degradation of protective paint coat having an adverse impact on aesthetic qualities of thin-walled cast-iron castings fabricated in furan resin sand. Microscopic examination and microanalyses of chemistry indicated that under the coat of paint covering the surface of a thin-walled casting, layers of oxides could be found presence of which can be most probably attributed to careless cleaning of the casting surface before the paint application process, as well as corrosion pits evidencing existence of damp residues under the paint layers contributing to creation of corrosion micro-cells

Images of power in contemporary Nigerian paintings | Gbaden ...

African Journals Online (AJOL)

Contemporary Nigerian paintings are replete with images and notions of power and power relations among the ethnically pluralistic peoples of Nigeria. This paper presents a select number of paintings that best manifest the idea of how power is depicted and how power influences human thinking and aspiration from a ...

Cyclic voltammetry and RBS study of paint components

International Nuclear Information System (INIS)

Bowman, Lynn; Spencer, Dirk; Muntele, Claudiu; Muntele, Iulia; Ila, D.

2007-01-01

Heavy metals and metalloid ions are found in environmental matrices. The most toxic are lead, cadmium and mercury. These three heavy metals have no biological function and are toxic at all concentrations. Lead is one of the most insidious heavy metals and is introduced into the environment by many different means. It persists in both urban and rural settings, being found in paint chips, pottery, crystal and pharmaceutical and nutritional products. The analysis of heavy elements such as lead in soil is of particular importance [W.T. Sturges, R.M. Harrison, Sci. Total Environ. 44 (3) (1985) 225; M.L. Lepow, L. Bruckman, M. Gillette, S. Markowitz, R. Robino, J. Kapish, Environ. Res. 10 (3) (1975) 415; A.E. Daniels, J.R. Kominsky, P.J. Clark, J. Hazard. Mater. B 87 (2001) 117; G. Hutter, D. Moshman, J. Hazard. Mater. 40 (1995) 1]. In preparing the methods for lead detection in paint, we have used Rutherford backscattering spectrometry (RBS) in order to study the type and amount of heavy metal content in paint samples collected at various sites in the historic campus at A and M University (AAMU). We will show the results of our study with emphasis on comparison of what we learned about presence of lead in paints using our ion beam methods compared with the analysis of lead in paints using cyclic voltammetry

Computer Aided Design of a Low-Cost Painting Robot

Directory of Open Access Journals (Sweden)

SYEDA MARIA KHATOON ZAIDI

2017-10-01

Full Text Available The application of robots or robotic systems for painting parts is becoming increasingly conventional; to improve reliability, productivity, consistency and to decrease waste. However, in Pakistan only highend Industries are able to afford the luxury of a robotic system for various purposes. In this study we propose an economical Painting Robot that a small-scale industry can install in their plant with ease. The importance of this robot is that being cost effective, it can easily be replaced in small manufacturing industries and therefore, eliminate health problems occurring to the individual in charge of painting parts on an everyday basis. To achieve this aim, the robot is made with local parts with only few exceptions, to cut costs; and the programming language is kept at a mediocre level. Image processing is used to establish object recognition and it can be programmed to paint various simple geometries. The robot is placed on a conveyer belt to maximize productivity. A four DoF (Degree of Freedom arm increases the working envelope and accessibility of painting different shaped parts with ease. This robot is capable of painting up, front, back, left and right sides of the part with a single colour. Initially CAD (Computer Aided Design models of the robot were developed which were analyzed, modified and improved to withstand loading condition and perform its task efficiently. After design selection, appropriate motors and materials were selected and the robot was developed. Throughout the development phase, minor problems and errors were fixed accordingly as they arose. Lastly the robot was integrated with the computer and image processing for autonomous control. The final results demonstrated that the robot is economical and reduces paint wastage.

Computer aided design of a low-cost painting robot

International Nuclear Information System (INIS)

Zaidi, S.M.; Janejo, F.; Mujtaba, S.B.

2017-01-01

The application of robots or robotic systems for painting parts is becoming increasingly conventional; to improve reliability, productivity, consistency and to decrease waste. However, in Pakistan only highend Industries are able to afford the luxury of a robotic system for various purposes. In this study we propose an economical Painting Robot that a small-scale industry can install in their plant with ease. The importance of this robot is that being cost effective, it can easily be replaced in small manufacturing industries and therefore, eliminate health problems occurring to the individual in charge of painting parts on an everyday basis. To achieve this aim, the robot is made with local parts with only few exceptions, to cut costs; and the programming language is kept at a mediocre level. Image processing is used to establish object recognition and it can be programmed to paint various simple geometries. The robot is placed on a conveyer belt to maximize productivity. A four DoF (Degree of Freedom) arm increases the working envelope and accessibility of painting different shaped parts with ease. This robot is capable of painting up, front, back, left and right sides of the part with a single colour. Initially CAD (Computer Aided Design) models of the robot were developed which were analyzed, modified and improved to withstand loading condition and perform its task efficiently. After design selection, appropriate motors and materials were selected and the robot was developed. Throughout the development phase, minor problems and errors were fixed accordingly as they arose. Lastly the robot was integrated with the computer and image processing for autonomous control. The final results demonstrated that the robot is economical and reduces paint wastage. (author)

Experiments on moisture form of concrete and adhesion of paints

International Nuclear Information System (INIS)

Kita, Daizo; Sumino, Masahiro

1975-01-01

It is necessary for radiation-resisting paints to adhere tightly to concrete in order to exhibit superior effects. As adhesion of paints to concrete is greatly affected by moisture content of concrete, this content is checked severely in the field. However, it may be considered that adhesion will be affected by the form of the moisture in the concrete also. Therefore, experiments were conducted with mortar to investigate the interrelations between pF-moisture content, moisture form and adhesion of paint. The following results were obtained: 1) Adhesion of paint becomes stronger as moisture content falls. 2) Adhesion strength of paint rises sharply until moisture content falls to a pF-value of 5.5 after which the strength is increased gradually until moisture content reaches pF of 7.0. 3) The pF-moisture content of 5.5 varies greatly depending on the mix proportions of mortar, but the form of moisture in such cases remains fixed and unchanged. (auth.)

Performance study of the paints for use in nuclear installations

International Nuclear Information System (INIS)

Yamashita, T.

1978-01-01

The performance of some Brazilian commercial paints under physical, chemical and radiation conditions typical of nuclear installations is studied. Resistance to gama rays in the range of 10 4 - 10 9 rad as well as the susceptibility to contamination, ease of decontamination and chemical resistance in 9 different types of paints are studied. Finally, suggestions are provided for the best choice of commercial paints according to their specific uses [pt

Cultural Collage Paintings

Science.gov (United States)

Coy, Mary

2011-01-01

In this article, the author describes a cultural collage painting project. Three things served as the impetus for this project: (1) a desire for students to explore the theme of "culture"; (2) an appreciation for the photo-montaged, layered images one sees in print media; and (3) noticing that projects from core subject areas hanging on the walls…

Simulating reflectance at interfaces coated with household paints

Science.gov (United States)

Prisland, Zachary

The paint and coatings industry is constantly working to improve their product, making a more efficient product at a cheaper cost. This requires some research and learning on the part of the companies, particularly in optical studies. For example, Burgess Pigment Company has developed a method, using a flash calciner, to quickly dehydrate clay, essentially popping it like popcorn, in order to add air pockets to the individual particles of clay. Clay that has undergone this process can improve the reflective properties of paint. The human eye, as a sensory organ, relies on reflected light in order to provide vision. As the major goal of paint is to be seen, it is easy to infer that it would be of utmost importance for the paint to reflect large amounts of light to appear more visible to the human eye and so using clay that has air pockets would be more desirable. The primary goal of this thesis will be to explore optical theory in an attempt to explain why the addition of air pockets could produce a more effective product.

Degradation of Emerald green in oil paint and its contribution to the rapid change in colour of the Descente des vaches (1834-1835) painted by Theodore Rousseau

NARCIS (Netherlands)

Keune, K.; Boon, J.J.; Boitelle, R.; Shimadzu, Y.

2013-01-01

Descente des vaches (1836) by Theodore Rousseau in the Mesdag Collection in The Hague is barely readable and its paint layers are in poor condition. The surface of the painting is strongly deformed and cracked, the whole painting has darkened and especially the greens have lost all or most of their

"Revealing hidden paint layers in oil paintings by means of scanning macro-XRF: a mock-up study based on Rembrandt's ""An old man in military costume"""

OpenAIRE

Alfeld, Matthias; De Nolf, Wout; Cagno, Simone; Appel, Karen; Siddons, D. Peter; Kuczewski, Anthony; Janssens, Koen; Dik, Joris; Trentelman, Karen; Walton, Marc; Sartorius, Andrea

2013-01-01

Over the past several decades the oeuvre of Rembrandt has been the subject of extensive art historical and scientific investigations. One of the most striking features to emerge is his frequent re-use of canvases and panels. The painting An Old Man in Military Costume (78.PB.246), in the collection of the J. Paul Getty Museum, is an example of such a re-used panel. Conventional imaging techniques revealed the presence of a second portrait under the surface portrait, but the details of this hi...

Experiencing art: the influence of expertise and painting abstraction level

Directory of Open Access Journals (Sweden)

Elina ePihko

2011-09-01

Full Text Available How does expertise influence the perception of representational and abstract paintings? We asked 20 experts on art history and 20 laypersons to explore and evaluate a series of paintings ranging in style from representational to abstract in five categories. We compared subjective aesthetic judgments and emotional evaluations, gaze patterns, and electrodermal reactivity between the two groups of participants. The level of abstraction affected aesthetic judgments and emotional valence ratings of the laypersons but had no effect on the opinions of the experts: the laypersons’ aesthetic and emotional ratings were highest for representational paintings and lowest for abstract paintings, whereas the opinions of the experts were independent of the abstraction level. The gaze patterns of both groups changed as the level of abstraction increased: the number of fixations and the length of the scanpaths increased while the duration of the fixations decreased. The viewing strategies—reflected in the target, location and path of the fixations—however indicated that experts and laypersons paid attention to different aspects of the paintings. The electrodermal reactivity did not vary according to the level of abstraction in either group but expertise was reflected in weaker responses, compared with laypersons, to information received about the paintings.

The cleaner, the greener? Product sustainability assessment of the biomimetic façade paint Lotusan® in comparison to the conventional façade paint Jumbosil®

Directory of Open Access Journals (Sweden)

Florian Antony

2016-12-01

Full Text Available Background: The debate on the question whether biomimetics has a specific potential to contribute to sustainability is discussed among scientists, business leaders, politicians and those responsible for project funding. The objective of this paper is to contribute to this controversial debate by presenting the sustainability assessment of one of the most well-known and most successful biomimetic products: the façade paint Lotusan®.Results: As a first step it has been examined and verified that the façade paint Lotusan® is correctly defined as a biomimetic product. Secondly, Lotusan® has been assessed and compared to a conventional façade paint within the course of a detailed product sustainability assessment (PROSA. For purposes of comparison, the façade paint Jumbosil® was chosen as reference for a conventional paint available on the market. The benefit analysis showed that both paints fulfil equally well the requirements of functional utility. With respect to the symbolic utility, Lotusan® has a particular added aesthetic value by the preservation of the optical quality over the life cycle. Within the social analysis no substantial differences between the two paints could be found regarding the handling and disposal of the final products. Regarding the life-cycle cost, Lotusan® is the more expensive product. However, the higher investment cost for a Lotusan®-based façade painting are more than compensated by the longer life time, resulting in both reduced overall material demand and lower labour cost. In terms of the life-cycle impact assessment, it can be ascertained that substantial differences between the paints arise from the respective service life, which are presented in terms of four scenario analyses.Conclusion: In summary, the biomimetic façade paint Lotusan® has been identified as a cost-effective and at the same time resource-saving product. Based on the underlying data and assumptions it could be demonstrated that

Measurements of tritium for radiological protection purposes in dial painting industry

International Nuclear Information System (INIS)

Sawant, J.V.; Rudran, Kamala; Pillai, K.C.

1990-01-01

Tritium is used as the active component in self-luminous paint. During dial painting process luminous paints releases tritium in air, causing air contamination. In the present paper results of a preliminary study on air monitoring and estimation of air samples in a local watch industry are given. (author). 5 refs., 2 t abs

Synergism in anticorrosive paints

Indian Academy of Sciences (India)

1CIDEPINT (CONICET–CICPBA): Centro de Investigación y Desarrollo en Tecnología de Pinturas,. Calle 52e/121 y 122, .... plus SOFTCORR 352 software. 2.2 Experimental paints ..... tigaciones Científicas y Técnicas), CICPBA (Comisión de.

Electronic Paint: Understanding Children's Representation through Their Interactions with Digital Paint

Science.gov (United States)

Matthews, John; Seow, Peter

2007-01-01

This article investigates very young children's use of a stylus-driven, electronic painting and drawing on the tablet PC. The authors compare their development in the use of this device with their use of other mark-making media, including those which derive from pencil and paper technologies and also with mouse-driven electronic paintbox programs.…

Interdisciplinary study of the panel painting depicting the "Pentecostes", attributed to Fernão Gomes

Directory of Open Access Journals (Sweden)

Diana Conde

2010-01-01

Full Text Available This paper presents a study on the technique and materials used in the panel painting entitled Pentecostes, attributed to the artist Fernão Gomes (XVIIth century, housed in the Museu Nacional de Arte Antiga, in Lisbon. The study also includes the diagnosis of the conservation state of the painting and the description of the cleaning intervention. For identification of the materials and determination of the conservation state, several analytical techniques were used: micro-FTIR and GC-MS, for identification of the binder and varnish; micro-Raman and micro-FTIR, for identification of fillers and pigments; micro-XRF and SEM-EDX, for elemental analysis; optical microscopy, with visible and fluorescent radiation, and infrared photography, for morphological observation and study of pictorial technique. The analytical approach led to the identification of materials common at the time: gypsum with animal glue, lead white, yellow and red ochres, black earths (based on Mn, Bi, Fe, azurite, possible green earth, lead red, oil and oily varnish with residues of cholesterol. After various cleaning tests, a gel suggested by the literature was chosen (recipe no. 105.4 developed by R. Wolbers and proved to be effective in the removal of the aged and polymerized varnish.

Lead levels in new enamel household paints from Asia, Africa and South America.

Science.gov (United States)

Clark, C Scott; Rampal, Krishna G; Thuppil, Venkatesh; Roda, Sandy M; Succop, Paul; Menrath, William; Chen, Chin K; Adebamowo, Eugenious O; Agbede, Oluwole A; Sridhar, Mynepalli K C; Adebamowo, Clement A; Zakaria, Yehia; El-Safty, Amal; Shinde, Rana M; Yu, Jiefei

2009-10-01

In 2006 a report on the analysis for lead in 80 new residential paints from four countries in Asia revealed high levels in three of the countries (China, India and Malaysia) and low levels in a fourth country (Singapore) where a lead in paint regulation was enforced. The authors warned of the possible export of lead-painted consumer products to the United States and other countries and the dangers the lead paint represented to children in the countries where it was available for purchase. The need for a worldwide ban on the use of lead in paints was emphasized to prevent an increase in exposure and disease from this very preventable environmental source. Since the earlier paper almost 300 additional new paint samples have been collected from the four initial countries plus 8 additional countries, three from Asia, three from Africa and two from South America. During the intervening time period two million toys and other items imported into the United States were recalled because the lead content exceeded the United States standard. High lead paints were detected in all 12 countries. The average lead concentration by country ranged from 6988 (Singapore) to 31,960ppm (Ecuador). One multinational company sold high lead paint in one country through January 2007 but sold low lead paint later in 2007 indicating that a major change to cease adding lead to their paints had occurred. However, the finding that almost one-third of the samples would meet the new United States standard for new paint of 90ppm, suggests that the technology is already available in at least 11 of the 12 countries to produce low lead enamel paints for domestic use. The need remains urgent to establish effective worldwide controls to prevent the needless poisoning of millions of children from this preventable exposure.

Complementary standoff chemical imaging to map and identify artist materials in an early Italian Renaissance panel painting.

Science.gov (United States)

Dooley, Kathryn A; Conover, Damon M; Glinsman, Lisha Deming; Delaney, John K

2014-12-08

Two imaging modalities based on molecular and elemental spectroscopy were used to characterize a painting by Cosimo Tura. Visible-to-near-infrared (400-1680 nm) reflectance imaging spectroscopy (RIS) and X-ray fluorescence (XRF) imaging spectroscopy were employed to identify pigments and determine their spatial distribution with higher confidence than from either technique alone. For example, Mary's red robe was modeled through the distribution of an insect-derived red lake (RIS map) and lead white (XRF lead map), rather than a layer of red lake on vermilion. The RIS image cube was also used to isolate the preparatory design by mapping the reflectance spectra associated with it. In conjunction with results from an earlier RIS study (1650-2500 nm) to map and identify the binding media, a more thorough understanding was gained of the materials and techniques used in the painting. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Radiation exposure to dial painters from 3H luminous paint industry

International Nuclear Information System (INIS)

Sawant, J.V.

1992-01-01

Tritium is used as the active component in self-luminous paint. The paper describes in-vitro solubilisation study of luminous paint in blood serum. Besides urine samples of luminous paint workers and air samples of two watch factories were analysed for 3 H. The results of these analysis are also presented. (author). 8 refs., 4 figs., 4 tabs

An integrated study for mapping the moisture distribution in an ancient damaged wall painting.

Science.gov (United States)

Capitani, Donatella; Proietti, Noemi; Gobbino, Marco; Soroldoni, Luigi; Casellato, Umberto; Valentini, Massimo; Rosina, Elisabetta

2009-12-01

An integrated study of microclimate monitoring, IR thermography (IRT), gravimetric tests and portable unilateral nuclear magnetic resonance (NMR) was applied in the framework of planning emergency intervention on a very deteriorated wall painting in San Rocco church, Cornaredo (Milan, Italy). The IRT investigation supported by gravimetric tests showed that the worst damage, due to water infiltration, was localized on the wall painting of the northern wall. Unilateral NMR, a new non-destructive technique which measures the hydrogen signal of the moisture and that was applied directly to the wall, allowed a detailed map of the distribution of the moisture in the plaster underlying the wall panting to be obtained. With a proper calibration of the integral of the recorded signal with suitable specimens, each area of the map corresponded to an accurate amount of moisture. IRT, gravimetric tests and unilateral NMR applied to investigate the northern wall painting showed the presence of two wet areas separated by a dry area. The moisture found in the lower area was ascribed to the occurrence of rising damp at the bottom of the wall due to the slope of the garden soil towards the northern exterior. The moisture found in the upper area was ascribed to condensation phenomena associated with the presence of a considerable amount of soluble, hygroscopic salts. In the framework of this integrated study, IRT investigation and gravimetric methods validated portable unilateral NMR as a new analytical tool for measuring in situ and without any sampling of the distribution and amount of moisture in wall paintings.

Experimental Visualizations of a Generic Launch Vehicle Flow Field: Time-Resolved Shadowgraph and Infrared Imaging

Science.gov (United States)

Garbeff, Theodore J., II; Panda, Jayanta; Ross, James C.

2017-01-01

Time-Resolved shadowgraph and infrared (IR) imaging were performed to investigate off-body and on-body flow features of a generic, 'hammer-head' launch vehicle geometry previously tested by Coe and Nute (1962). The measurements discussed here were one part of a large range of wind tunnel test techniques that included steady-state pressure sensitive paint (PSP), dynamic PSP, unsteady surface pressures, and unsteady force measurements. Image data was captured over a Mach number range of 0.6 less than or equal to M less than or equal to 1.2 at a Reynolds number of 3 million per foot. Both shadowgraph and IR imagery were captured in conjunction with unsteady pressures and forces and correlated with IRIG-B timing. High-speed shadowgraph imagery was used to identify wake structure and reattachment behind the payload fairing of the vehicle. Various data processing strategies were employed and ultimately these results correlated well with the location and magnitude of unsteady surface pressure measurements. Two research grade IR cameras were positioned to image boundary layer transition at the vehicle nose and flow reattachment behind the payload fairing. The poor emissivity of the model surface treatment (fast PSP) proved to be challenging for the infrared measurement. Reference image subtraction and contrast limited adaptive histogram equalization (CLAHE) were used to analyze this dataset. Ultimately turbulent boundary layer transition was observed and located forward of the trip dot line at the model sphere-cone junction. Flow reattachment location was identified behind the payload fairing in both steady and unsteady thermal data. As demonstrated in this effort, recent advances in high-speed and thermal imaging technology have modernized classical techniques providing a new viewpoint for the modern researcher

Prior states: evolution of composition and color in two Barnett Newman paintings

Science.gov (United States)

Epley, Bradford A.; Rogge, Corina E.

2015-11-01

The color field paintings of Barnett Newman, one of the great American abstract expressionist painters, are seminal works of the modern era. They feature large flat fields of vibrant colors intended to allow the viewer to connect with the paintings in immediate, visceral ways. Despite the apparent simplicity of his compositions, Newman considered himself an intuitive painter and allowed his compositions to evolve during the painting process. Two paintings in the Menil Collection, Untitled 2 (1950) and Unfinished Painting [Blue and Brown 1970— #2] (1970) display visual evidence of former states, but attempts to elucidate earlier compositions by X-radiography were inconclusive due to the lack of contrast in paint densities. We applied limited sampling and used a handheld X-ray fluorescence spectrometer in a `scanning' manner to determine the color and composition of the previous states of these paintings to help us better understand their evolution. Newman altered his initial cadmium red and alizarin composition in Untitled 2 (1950) by overpainting the alizarin region with a wider band of Mars black paint. He then modulated the surface of the black by partially covering it with a carbonaceous black with a different gloss. For Unfinished Painting [Blue and Brown 1970— #2] (1970), Newman not only changed the cadmium red to an umber but simplified the composition, removing multiple zips and refining it to its current monumental state. This evidence of Newman's decision-making processes permits a tantalizing glimpse of the artist consistently looking both ahead and backward, experimenting and revisiting.

Leaching of copper and zinc from spent antifouling paint particles

International Nuclear Information System (INIS)

Singh, Nimisha; Turner, Andrew

2009-01-01

Leaching of Cu and Zn from a composite of spent antifouling paint particles, containing about 300 mg g -1 and 110 mg g -1 of the respective metals, was studied in batch experiments. For a given set of simulated environmental conditions, release of Cu was independent of paint particle concentration due to attainment of pseudo-saturation, but Zn was less constrained by solubility effects and release increased with increasing particle concentration. Leaching of Cu increased but Zn decreased with increasing salinity, consistent with mechanisms governing the dissolution of Cu 2 O in the presence of chloride and Zn acrylates in the presence of seawater cations. Because of complex reaction kinetics and the presence of calcium carbonate in the paint matrix, metal leaching appeared to be greater at 4 deg. C than 19 deg. C under many conditions. These findings have important environmental and biological implications regarding the deliberate or inadvertent disposal of antifouling paint residues. - Copper and zinc are readily leached from particles of spent antifouling paint under a range of environmental conditions

Paint coating characterization for thermoelastic stress analysis of metallic materials

International Nuclear Information System (INIS)

Robinson, A F; Dulieu-Barton, J M; Quinn, S; Burguete, R L

2010-01-01

In thermoelastic stress analysis (TSA) it is normal practice to coat metallic specimens with black paint to enhance and standardize the surface emissivity. It is assumed that the paint coating has no effect on the thermal emission from the specimen, but it is well known that the response is sensitive to paint coating thickness, particularly at higher frequencies. In this paper the effects of loading frequency and paint coating thickness on the thermoelastic response are investigated. The thermoelastic response is compared to theory, and optimum test conditions and coating characteristics are suggested. The motivation for the work is to develop a TSA-based means of residual stress assessment, where the measurement of much smaller temperature changes than those that are resolved in standard TSA is required; therefore the analysis is much more sensitive to the effects of the paint coating. However, the work presented in this paper is relevant to a wide range of TSA investigations and presents data that will be of interest to all practitioners of TSA

Leaching of copper and zinc from spent antifouling paint particles

Energy Technology Data Exchange (ETDEWEB)

Singh, Nimisha [School of Earth, Ocean and Environmental Sciences, University of Plymouth, Drake Circus, Plymouth PL4 8AA (United Kingdom); Turner, Andrew [School of Earth, Ocean and Environmental Sciences, University of Plymouth, Drake Circus, Plymouth PL4 8AA (United Kingdom)], E-mail: aturner@plymouth.ac.uk

2009-02-15

Leaching of Cu and Zn from a composite of spent antifouling paint particles, containing about 300 mg g{sup -1} and 110 mg g{sup -1} of the respective metals, was studied in batch experiments. For a given set of simulated environmental conditions, release of Cu was independent of paint particle concentration due to attainment of pseudo-saturation, but Zn was less constrained by solubility effects and release increased with increasing particle concentration. Leaching of Cu increased but Zn decreased with increasing salinity, consistent with mechanisms governing the dissolution of Cu{sub 2}O in the presence of chloride and Zn acrylates in the presence of seawater cations. Because of complex reaction kinetics and the presence of calcium carbonate in the paint matrix, metal leaching appeared to be greater at 4 deg. C than 19 deg. C under many conditions. These findings have important environmental and biological implications regarding the deliberate or inadvertent disposal of antifouling paint residues. - Copper and zinc are readily leached from particles of spent antifouling paint under a range of environmental conditions.

Characterization of hidden defects of an original XVI century painting on wood by Electronic Speckle Pattern Interferometry (Electronic Speckle Pattern Interferometry survey on a wooden painting)

International Nuclear Information System (INIS)

Arena, G.

2015-01-01

Electronic Speckle Pattern Interferometry, a non-contact and nondestructive optical diagnostic technique, was employed for evaluating the conservation state of a XVI century painting on wood. The whole structure alterations, induced by the laboratory temperature and relative humidity variations, were evaluated. Long-term analysis, by sequential recording and subsequent off-line processing of the fringes progression, was carried out. Local flaws and hidden detachments of pictorial layers from the support, which could not be recognized by traditional art-restorer survey methods, were also easily revealed. In such a case, a simple measurement approach was utilized, with the aim to get a user-friendly method for art conservators. The results demonstrate that the interferometry method can largely improve the traditional art conservation survey techniques.

The painting of the Veluća's church

Directory of Open Access Journals (Sweden)

Andrejić Živojin R.

2013-01-01

Full Text Available Bogorodičina Church in Veluća was built by the Czar Despot Dejan and his wife Teodora before 1368 and they had it painted form 1368 to 1371, as a family memory and the mausoleum in the inheritance territory of his parent, Despot Ivaniš. In the beginning of the painting works, while painting the dome space, the renowned founders found a very good painter, but he, for some reason ended his work never finishing the job. Around 1370 the founders did not have an opportunity to find a good painter, so they hired a group of painters from the Seacoast that had no qualities. Their drawings were much more simplified and painting procedure quite poor. The flat portraits and bodies without volume with thin arms are weightless. And in combination with poor colouring they clearly stand aside compared to the total medieval Serbian painting. By style, but spatially very far away, the similarities can only be found in the paintings of Georgia. On the other hand, the total ideological and theological creation of the painting program is on a very high level and undoubtedly expresses the spirituality of the founder and the local episcope. The symbolical connection had been set and between cycles where all the saints of the church year were presented together with the composition of the The Doom. The organic connection has been established with the whole content of Christian dogma and the earthly history of the founder and his family. The program narration has strong messages on multiple family and legal belonging to the ruling house of Nemanjić. The Doom is in symbolical function with the ruler's iconography and setting of the divine rights of the earthly rule of the founders their parents as suzerains and their descendants. The symbolism of The Doom in Veluća is not only symbolical but it contains some historical reality. As a mausoleum building Veluća has an overall painting program of funerary character that fits into all traditions that were set in the

Perceptual, semantic and affective dimensions of experience of abstract and representational paintings

Directory of Open Access Journals (Sweden)

Marković Slobodan

2011-01-01

Full Text Available In this study the difference between representational and abstract paintings in judgments on perceptual, semantic and affective dimensions was investigated. Two groups of participants judged the sets of representational and abstract paintings on three groups of dimensions: perceptual (Form, Color, Space and Complexity, semantic (Illusion-Construction of Reality, Expression, Ideology and Decoration, and affective (Hedonic Tone, Arousal, Relaxation and Regularity. The results have shown that representational paintings have higher judgments on the perceptual dimensions of Form and Complexity, the semantic dimension of the Illusion of Reality (the opposite pole of the Construction of Reality, and the affective dimension of Regularity. On the other hand, abstract paintings have higher judgments on the perceptual dimension of Color, the semantic dimensions of Construction of Reality (the opposite pole of the Illusion of Reality and Expression, and the affective dimension Arousal. A discriminant analysis indicated that all three sets of dimensions are relatively good predictors of the classification of representational and abstract paintings (61-100%. The results suggest that the subjective categorization of paintings is generally based on the recognizability of pictorial content (representational vs. abstract, but some formal or stylistic properties play a role in the categorization, as well: some expressionistic representational paintings were classified in an abstract category, and some geometrically abstract paintings were classified as representational.

Non-invasive techniques for revealing the palette of the Romantic painter Francesco Hayez

Science.gov (United States)

Rampazzi, Laura; Brunello, Valentina; Corti, Cristina; Lissoni, Elena

2017-04-01

This paper describes the first systematic analysis of the palette of Francesco Hayez, one of the most outstanding artists of European Romanticism, whose painting technique has never been extensively investigated despite the plethora of artistic studies. He lived in a particular moment in the history of painting, as in the first half of the 19th century many synthetic pigments were available, also in tin tubes, but traditional materials were still used. Sixteen paintings on canvas and on panels, created between 1823 and 1868, were analyzed in situ through non-invasive techniques (infrared reflectography and infrared reflection spectroscopy). Imaging investigation provided clues on painting technique, revealing some cases of pentimenti and underdrawings. A preliminary survey was carried out on a hundred pure pigments used up to the 19th century and on new synthetic colours, in order to attain reference spectra for the interpretation of painting spectra. The portable infrared instrument provided insight into Hayez's painting materials, identifying barite, ivory black, lead-tin yellow, Naples yellow, ochres, Prussian blue, and white lead. The pigments were often blended, to obtain a unique fabric appearance or to attain cold shades. The results pointed to a siccative oil as a binder, mixed with white lead so that it could act as a catalyzer in polymerization reactions, and in some cases with a proteinaceous binder and resins. The preparation was made with gypsum and white lead mixed with a siccative oil. The results showed that the artist used a typical traditional palette, throughout his career, in order to lead to brilliant colours and with long-term stability. Anyway, the possible presence of cobalt blue in a few paintings suggests that Hayez had probably started testing the new colours, since the second decade of 19th century.

Lead content of dried films of domestic paints currently sold in Nigeria

International Nuclear Information System (INIS)

Adebamowo, Eugenious O.; Scott Clark, C.; Roda, Sandy; Agbede, Oluwole A.; Sridhar, Mynepalli K.C.; Adebamowo, Clement A.

2007-01-01

Children are at higher risk from lead exposure because their developing neural system is susceptible to its neurotoxic effects. We studied lead levels of paints manufactured in Nigeria in 2006. Lead levels in 5 colors of paints, each from different manufacturers were measured using flame-atomic absorption spectroscopy. We found that 96% of the paints had higher than recommended levels of lead. The mean lead level of paints ranged from 84.8 to 50,000 ppm, with mean of 14,500 ppm and median of 15,800 ppm. The main determinant of lead levels was color of the paint. As lead levels in paint sold in the past years in Nigeria are likely to be at least as high as that currently sold, it is likely that many existing houses contain dangerously high levels of lead. Efforts need to be undertaken to assess the presence of high lead levels in existing housing and if detected, intervention programs for eliminating risk of exposure should be developed in addition to measures to increase awareness and enforce regulations leading to the elimination of lead based domestic paint

Manganese and Iron Catalysts in Alkyd Paints and Coatings

Directory of Open Access Journals (Sweden)

Ronald Hage

2016-04-01

Full Text Available Many paint, ink and coating formulations contain alkyd-based resins which cure via autoxidation mechanisms. Whilst cobalt-soaps have been used for many decades, there is a continuing and accelerating desire by paint companies to develop alternatives for the cobalt soaps, due to likely classification as carcinogens under the REACH (Registration, Evaluation, Authorisation and Restriction of Chemicals legislation. Alternative driers, for example manganese and iron soaps, have been applied for this purpose. However, relatively poor curing capabilities make it necessary to increase the level of metal salts to such a level that often coloring of the paint formulation occurs. More recent developments include the application of manganese and iron complexes with a variety of organic ligands. This review will discuss the chemistry of alkyd resin curing, the applications and reactions of cobalt-soaps as curing agents, and, subsequently, the paint drying aspects and mechanisms of (model alkyd curing using manganese and iron catalysts.

Allergic Contact Dermatitis From Methylisothiazolinone in Residential Wall Paint.

Science.gov (United States)

Goodier, Molly C; Ljungberg, Linda; Persson, Christina; Engfeldt, Malin; Bruze, Magnus; Warshaw, Erin M

A 33-year-old woman presented to our clinic for suspected photoallergic contact dermatitis with a recent episode of severe, vesicular dermatitis involving exposed skin and correlating with relocation to a new home. Biopsy results showed spongiotic and lichenoid dermatitis with eosinophils. Patch test results showed a very strong (+++) reaction to methylisothiazolinone (MI), mild (+) reaction to MI/methylchloroisothiazolinone, and no reaction to benzisothiazolinone. These allergens were found in several personal products. However, the patient was suspicious of 4 wall paints recently used in her home. Semiopen patch tests to 3 Behr interior paints showed positive results. Nine controls showed negative results. High-performance liquid chromatography demonstrated MI and benzisothiazolinone in all 4 paints at concentrations ranging from 50 to 100 ppm and 290 to 340 ppm, respectively. Although MI has been reported to cause occupational airborne contact dermatitis in European household painters, to our knowledge, this is the first documented case of paint-related MI allergy in the United States.

Aesthetic Emotions Across Arts: A Comparison Between Painting and Music

Science.gov (United States)

Miu, Andrei C.; Pițur, Simina; Szentágotai-Tătar, Aurora

2016-01-01

Emotional responses to art have long been subject of debate, but only recently have they started to be investigated in affective science. The aim of this study was to compare perceptions regarding frequency of aesthetic emotions, contributing factors, and motivation which characterize the experiences of looking at painting and listening to music. Parallel surveys were filled in online by participants (N = 971) interested in music and painting. By comparing self-reported characteristics of these experiences, this study found that compared to listening to music, looking at painting was associated with increased frequency of wonder and decreased frequencies of joyful activation and power. In addition to increased vitality, as reflected by the latter two emotions, listening to music was also more frequently associated with emotions such as tenderness, nostalgia, peacefulness, and sadness. Compared to painting-related emotions, music-related emotions were perceived as more similar to emotions in other everyday life situations. Participants reported that stimulus features and previous knowledge made more important contributions to emotional responses to painting, whereas prior mood, physical context and the presence of other people were considered more important in relation to emotional responses to music. Self-education motivation was more frequently associated with looking at painting, whereas mood repair and keeping company motivations were reported more frequently in relation to listening to music. Participants with visual arts education reported increased vitality-related emotions in their experience of looking at painting. In contrast, no relation was found between music education and emotional responses to music. These findings offer a more general perspective on aesthetic emotions and encourage integrative research linking different types of aesthetic experience. PMID:26779072

Aesthetic Emotions Across Arts: A Comparison Between Painting and Music.

Science.gov (United States)

Miu, Andrei C; Pițur, Simina; Szentágotai-Tătar, Aurora

2015-01-01

Emotional responses to art have long been subject of debate, but only recently have they started to be investigated in affective science. The aim of this study was to compare perceptions regarding frequency of aesthetic emotions, contributing factors, and motivation which characterize the experiences of looking at painting and listening to music. Parallel surveys were filled in online by participants (N = 971) interested in music and painting. By comparing self-reported characteristics of these experiences, this study found that compared to listening to music, looking at painting was associated with increased frequency of wonder and decreased frequencies of joyful activation and power. In addition to increased vitality, as reflected by the latter two emotions, listening to music was also more frequently associated with emotions such as tenderness, nostalgia, peacefulness, and sadness. Compared to painting-related emotions, music-related emotions were perceived as more similar to emotions in other everyday life situations. Participants reported that stimulus features and previous knowledge made more important contributions to emotional responses to painting, whereas prior mood, physical context and the presence of other people were considered more important in relation to emotional responses to music. Self-education motivation was more frequently associated with looking at painting, whereas mood repair and keeping company motivations were reported more frequently in relation to listening to music. Participants with visual arts education reported increased vitality-related emotions in their experience of looking at painting. In contrast, no relation was found between music education and emotional responses to music. These findings offer a more general perspective on aesthetic emotions and encourage integrative research linking different types of aesthetic experience.

Aesthetic emotions across arts: A comparison between painting and music

Directory of Open Access Journals (Sweden)

Andrei C. Miu

2016-01-01

Full Text Available Emotional responses to art have long been subject of debate, but only recently have they started to be investigated in affective science. The aim of this study was to compare perceptions regarding frequency of aesthetic emotions, contributing factors and motivation which characterize the experiences of looking at painting and listening to music. Parallel surveys were filled in online by participants (N = 971 interested in music and painting. By comparing self-reported characteristics of these experiences, this study found that compared to listening to music, looking at painting was associated with increased frequency of wonder and decreased frequencies of joyful activation and power. In addition to increased vitality, as reflected by the latter two emotions, listening to music was also more frequently associated with emotions such as tenderness, nostalgia, peacefulness and sadness. Compared to painting-related emotions, music-related emotions were perceived as more similar to emotions in other everyday life situations. Participants reported that stimulus features and previous knowledge made more important contributions to emotional responses to painting, whereas prior mood, physical context and the presence of other people were considered more important in relation to emotional responses to music. Self-education motivation was more frequently associated with looking at painting, whereas mood repair and keeping company motivations were reported more frequently in relation to listening to music. Participants with visual arts education reported increased vitality-related emotions in their experience of looking at painting. In contrast, no relation was found between music education and emotional responses to music. These findings offer a more general perspective on aesthetic emotions and encourage integrative research linking different types of aesthetic experience.

Study of decontamination and radiation resistance properties of Indian paints

International Nuclear Information System (INIS)

Shah, S.M.; Gopinathan, E.; Bhagwath, A.M.

1976-01-01

A brief introduction to the study of contamination and radiation resistance properties of Indian paints used as coating for structural materials in the nuclear industry is given. The general composition of paints such as epoxy, vinyl, alkyd, phenolic, chlesimated rubber, etc. is given. Method of sample preparation, processing and actual evaluation of decontaminability are described. The results have been discussed in terms of decontamination factors. Some recommendations based on the performance of the paints studied are also included. (K.B.)

Painting Patterns with Pixels.

Science.gov (United States)

Yoerg, Kim

2002-01-01

Describes an art unit for middle school students where they created their own original pattern through the use of "ClarisWorks Paint." Discusses the procedure for the project and the evaluation used at the end of the unit. Emphasizes the importance of learning about computers. (CMK)

Il camouflage nel campo allargato. Variazioni su Disruptive Pattern Material e Dazzle Painting nella cultura visiva contemporanea

OpenAIRE

Maite Méndez Baiges

2016-01-01

The First World War was the scenario that led to the invention and systematic use of military camouflage techniques. Between them, the two fundamental modes of static or pictorial camouflage: mimetic, known as Disruptive Pattern Material, and the naval, called Dazzle Painting. Avantgarde artists contributed to their birth. Immediately, there was the transfer of these techniques to the civilian sphere, revealing that its essentially practical essence did not prevent the exploitation of its aes...

Painting for nuclear power stations and machinery and equipments according to quality assurance program of ANSI

International Nuclear Information System (INIS)

Fukuda, Shinzo; Tsuchiya, Yukikazu.

1979-01-01

Recently, painting for nuclear power stations is carried out with the paints made domestically, and these paints are tested and judged generally according to the items of performance evaluation decided by the American National Standard Institute. In Japan, there is no standard regarding the paints for nuclear power stations. Painting is very important process, and it is appropriate to introduce quality assurance program into it. In this paper, the contents of ANSI standard concerning the paints and painting for nuclear power stations are explained, and the outline of the painting of heat exchangers carried out in accordance with the quality assurance program in the Tamano Shipyard, Mitsui Shipbuilding and Engineering Co., Ltd., is described. The test items for evaluating the general performance of the paints, the testing method for evaluating the endurance at the time of an accident, the quality assurance for the paints used for the facilities handling radiation and others are explained. Various problems arise when the quality assurance program of ANSI is applied actually to painting. It is difficult to judge the quality of paints and painting with numerical values, and much efforts were required to establish the quality assurance organization. The conditions for painting, the handling of many documents, the measures to unsatisfactory painting and so on caused much difficulties. (Kako, I.)

Recycling of paint-contaminated grit.

Science.gov (United States)

Taha, R; al-Alawi, D; al-Nabhani, M; Pillay, A E; al-Hamdi, A

2001-08-01

The impact on the environment of using paint-contaminated grit (PCG) as a partial or full replacement for sand in Portland cement mortar and asphalt concrete mixtures was investigated. The grit waste material originated from abrasive blasting of offshore steel structures. There is a major environmental concern regarding the safe disposal of the spent blasting abrasives that contain paint chips or paint particles and other debris removed from the surface of the steel structures. This work investigated the potential reuse of PCG in Portland cement concrete (PCC) and hot mix asphalt concrete. Several studies were conducted to establish the integrity of the materials containing the recycled grit. These included the chemical and physical characterization of natural sand and PCG, the assay of leaches associated with the grit material for hazardous metal contaminants, such as Cr, Cd and Pb, and the assessment of the mechanical properties of the PCG-substituted mortars by applying special tests (such as Marshall stability and determination of the flow properties) to the PCG-substituted asphalt concrete mixtures. The overall results demonstrated that the potential reuse of PCG in PCC and asphalt concrete mixtures would not pose any environmental threat and could produce several benefits, such as reduced disposal costs, protection of water sources from improper disposal practices and reduced costs in the production of natural aggregates and asphalt cement.

The Restoration of Paintings at the Imperial Hermitage (Saint-Petersburg at the Beginning of the 19th Century

Directory of Open Access Journals (Sweden)

Mariam Nikogosyan

2012-04-01

Full Text Available Le début du XIXe siècle fut une période charnière pour l’histoire de la formation des restaurateurs en Russie. F.K. Labensky, conservateur de la Galerie de l’Ermitage de 1797 à 1850, met en place un atelier de restauration avec un personnel permanent, travaillant sur la collection de la peinture impériale. Assistant de Labensky, restaurateur A.F. Mitrokhine, apprend toutes les techniques connues de restauration mécanique - doublage, parquetage et même transposition des peintures, - et les développe. Une école spéciale est créée près de l’atelier de l'Ermitage à 1819, supervisé par Mitrokhine, ou les jeunes diplômés de l'Académie impériale de l'Art se familiarise à la fois avec la restauration mécanique et picturale des peintures. Les apprentis de l'école de Mitrokhine transmettent ensuite ses techniques à la prochaine génération de restaurateurs de l’Ermitage.The beginning of the 19th century was a period of formation of restoration school in Russia. F.K.Labensky, Curator of the Hermitage Picture Gallery from 1797 onwards till 1850, arranged a restoration studio with a permanent staff working on Imperial painting collection.  Labensky’s assistant, a restorer A.F. Mitrokhin learned all known techniques of mechanical restoration – relining, cradling and even transfer of paintings, - and developed them on his own. A special school was established by the Hermitage studio in 1819, supervised by Mitrokhin, were young graduates of Imperial Academy of Art were taught both mechanical and painting restoration. The apprentices of Mitrokhin school passed his techniques to next generation of Hermitage restorers.

Study by micro-Raman spectroscopy of wall paints (external parts and cross-sections) from reales alcazares of Seville (Spain)

Science.gov (United States)

Perez-Rodriguez, José Luis; Centeno, Miguel Angel; Robador, María Dolores; Siguenza, Belinda; Durán, Adrián

2013-04-01

The Reales Alcazares of Sevilla was originally builded by the Arabic in the year 913. The Mudejar Palace was built by Christian King Pedro I between 1364 and 1366. At the end of XV century the Catholic Kings, Isabel and Fernando made important transformations especially in the Mudejar Palace. Recently, wall paints from Catholic Kings periods were found during works of conservations in the first floor of the Palace. The study of these paints by non-destructive techniques was considered of great interest in order to determine the technology of manufacture and the originality of the artwork. The main objective of this work was to apply the Raman spectroscopy technique on the surface of the wall and on the different layers of the cross-sections prepared in order to characterize the pigments and the plaster present in these wall paints. Little information was obtained using a portable Raman spectrometer. In this case the dispersive integrated Horiba Jobin-Yvon LabRaman HR800 system was employed. Small samples of black, red, yellow, white and green colour were taken from the artwork. The surface of the samples were directly studed by the Raman spectroscopy instrument using red (785 nm) and green (522 nm) lasers, similarly to non-invasive experimental technique. This technique showed the presence of gypsum (SO4Ca.2H2O) and calcite (CaCO3) in all the studied samples However, the pigments responsible of different colours were not detected. The surface of these wall paints was covered with gypsum and calcite due to contamination. These mineras were also characterized by XRD and SEM-EDX. The presence of these compounds and the heterogeneous surface did not permit the characterization of the pigments responsible of the colour. In order to better characterization of the pigments and plaster used the study was carried out on cross-sections. The black colour was performed using carbon black. Two different red layers were detected one constituted by cinnabar and lead carbonate and

The Monetary Appreciation of Paintings : From Realism to Magritte

NARCIS (Netherlands)

Renneboog, L.D.R.; van Houte, T.

1999-01-01

This study investigates how investments in painted arts compare to those in stocks in terms of risk return trade off using Sharpe and Treynor ratios and Markowitz efficient frontiers. A large database was analysed consisting of more than 10500 auction prices of Belgian painted art over the period

Analysis of fresco paintings by X-ray fluorescence method

International Nuclear Information System (INIS)

Cechak, T.; Gerndt, J.; Musilek, L.; Kopecka, I.

2000-01-01

In this work we present the application of X-ray fluorescence analysis (XRFA) to examine fresco paintings from the Karlstejn castle. The X-ray fluorescence apparatus built and operated in the Laboratory of Quantitative Methods in Research of Ancient Monuments was used for the purpose of fresco paintings measurements. The X-ray sources (radionuclides) generate the characteristic X-ray photons from the sample. The Si(Li) detector measures numbers and energies of photons emitted from the specimen. The energy and number of photons detected can be converted into kind and amount of measured atoms. These results give data for qualitative and quantitative analysis of samples. XRFA is relatively simple and non-destructive method. Capability of in-situ measurement is one of big advantages of this method. The radionuclide sources of exciting radiation (e.g. 55 Fe enables the excitation of elements with Z up to 23, 238 Pu is used in interval of Z from 20 to 39 etc.) were used. An Si(Li) semiconductor detector with a 5 l Dewar vessel and portable spectroscopy system enable the in situ measurement. Narrow collimation of the exciting beam makes it possible to select the measured area of fresco painting. The valuable fresco paintings from the Karlstejn castle were investigated in this way. The measurements were carried out in collaboration with the Analytical Laboratory of the State Institute for the Preservation of Historic Monuments. A suitable analysis of paintings makes it possible to detect the kind of colours and evaluate changes in the surface colour of paintings and suggest useful and timely procedures for their conservation and restoration. (author)

Effects of Tactile Sensations during Finger Painting on Mindfulness, Emotions, and Scope of Attention

Science.gov (United States)

Stanko-Kaczmarek, Maja; Kaczmarek, Lukasz D.

2016-01-01

Research has shown that creative performance, such as painting, influences affective and cognitive processes. Yet little is known about how tactile sensations experienced during painting determine what individuals feel and how they think while they create. Based on prior research, finger painting (compared to brush painting) was expected to…

Photonic Paint Developed with Metallic Three-Dimensional Photonic Crystals

Science.gov (United States)

Sun, Po; Williams, John D.

2012-01-01

This work details the design and simulation of an inconspicuous photonic paint that can be applied onto an object for anticounterfeit and tag, track, and locate (TTL) applications. The paint consists of three-dimensional metallic tilted woodpile photonic crystals embedded into a visible and infrared transparent polymer film, which can be applied to almost any surface. The tilted woodpile photonic crystals are designed with a specific pass band detectable at nearly all incident angles of light. When painted onto a surface, these crystals provide a unique reflective infra-red optical signature that can be easily observed and recorded to verify the location or contents of a package.

An ESR study of the spectra of paint pigments in 'drying' linseed oil

International Nuclear Information System (INIS)

Slogett, R.; Troup, G.; Hutton, D.

1999-01-01

Full text: Since previous ESR work on the identification of RAW paint pigments, mainly mineral, looked promising, we decided to examine the spectra when the pigments were applied, in oil, to a non-reactive, microwave transparent polymer. The polymer used shows no significant ESR signals in the range 2000-4000 gauss at ∼9.1 GHz and room temperature. The oil used is Winsor and Newton Drying Linseed Oil, and contains 'manganese driers'. The spectrum of the pure liquid oil is shown, as well as that of the dried oil on the substrate. Many of the pigment spectra shown are so strong that not a trace of the oil Mn(2+) can be seen at the pigment concentrations used. The effect of the linseed oil on modern synthetic indigo, an organic pigment still available made from plants, is also shown. ESR still looks to be a useful supplementary technique for paint pigment identification

Painting and Writing Matters

DEFF Research Database (Denmark)

Balle, Søren Hattesen

materialization. At the same time as O’Hara and Rivers investigate the often conflicting powers of both genres to incarnate the reality of the material world (especially the human body) in their respective media, they also playfully foreground the materiality of painterly/poetic text as paint and writing...

Positive fEMG Patterns with Ambiguity in Paintings.

Science.gov (United States)

Jakesch, Martina; Goller, Juergen; Leder, Helmut

2017-01-01

Whereas ambiguity in everyday life is often negatively evaluated, it is considered key in art appreciation. In a facial EMG study, we tested whether the positive role of visual ambiguity in paintings is reflected in a continuous affective evaluation on a subtle level. We presented ambiguous (disfluent) and non-ambiguous (fluent) versions of Magritte paintings and found that M. Zygomaticus major activation was higher and M. corrugator supercilii activation was lower for ambiguous than for non-ambiguous versions. Our findings reflect a positive continuous affective evaluation to visual ambiguity in paintings over the 5 s presentation time. We claim that this finding is indirect evidence for the hypothesis that visual stimuli classified as art, evoke a safe state for indulging into experiencing ambiguity, challenging the notion that processing fluency is generally related to positive affect.

Microclimate boxes for panel paintings

DEFF Research Database (Denmark)

Wadum, Jørgen

1998-01-01

The use of microclimate boxes to protect vulnerable panel paintings is, therefore, not a new phenomenon of the past two or three decades. Rather, it has been a concern for conservators and curators to protect these objects of art at home and in transit since the end of the nineteenth century....... The increased number of travelling exhibitions in recent years has heightened the need to protect paintings during circulation (Thomson 1961; Mecklenburg 1991). The use and design of microclimate boxes have been evolving since 1892. These boxes may be divided into three broad groups: those using an active...... buffer material to stabilize the internal RH, a more recent box containing no added buffer material, and, in recent times, boxes with an altered gas content. Another concern is the appearance (aesthetics) of the box....

Painting models

Science.gov (United States)

Baart, F.; Donchyts, G.; van Dam, A.; Plieger, M.

2015-12-01

The emergence of interactive art has blurred the line between electronic, computer graphics and art. Here we apply this art form to numerical models. Here we show how the transformation of a numerical model into an interactive painting can both provide insights and solve real world problems. The cases that are used as an example include forensic reconstructions, dredging optimization, barrier design. The system can be fed using any source of time varying vector fields, such as hydrodynamic models. The cases used here, the Indian Ocean (HYCOM), the Wadden Sea (Delft3D Curvilinear), San Francisco Bay (3Di subgrid and Delft3D Flexible Mesh), show that the method used is suitable for different time and spatial scales. High resolution numerical models become interactive paintings by exchanging their velocity fields with a high resolution (>=1M cells) image based flow visualization that runs in a html5 compatible web browser. The image based flow visualization combines three images into a new image: the current image, a drawing, and a uv + mask field. The advection scheme that computes the resultant image is executed in the graphics card using WebGL, allowing for 1M grid cells at 60Hz performance on mediocre graphic cards. The software is provided as open source software. By using different sources for a drawing one can gain insight into several aspects of the velocity fields. These aspects include not only the commonly represented magnitude and direction, but also divergence, topology and turbulence .

PIXE analysis on Maya blue in Prehispanic and colonial mural paintings

Energy Technology Data Exchange (ETDEWEB)

Sanchez del Rio, M. [Departamento de Fisica, Universidad Autonoma Metropolitana, Iztapalapa, DF 09340 (Mexico); Martinetto, P. [Laboratoire de Cristallographie, CNRS, BP 166, F-30842 Grenoble (France); Solis, C. [Instituto de Fisica, Universidad Nacional Autonoma de Mexico, Mexico, DF 04510 (Mexico)]. E-mail: corina@fisica.unam.mx; Reyes-Valerio, C. [Instituto Nacional de Antropologi' a e Historia, Mexico, DF (Mexico)

2006-08-15

Particle induced X-ray emission (PIXE) experiments have been carried out at the AGLAE facility (Paris) on several mural samples containing Maya blue from different Prehispanic archaeological sites (Cacaxtla, El Tajin, Tamuin, Santa Cecilia Acatitlan) and from several colonial convents in the Mexican plateau (Jiutepec, Totimehuacan, Tezontepec and Cuauhtinchan). The analysis of the concentration of several elements permitted to extract some information on the technique used for painting the mural, usually fresco. Principal component analysis permitted to classify the samples into groups. This grouping is discussed in relation to geographic and historic data.

Corrosion of packaged cadmium plated electrical control units from paint vapors

International Nuclear Information System (INIS)

Brough, L.A.

1987-01-01

One of the most widely used methods of controlling the degradation of steel is the application of paint. It is relatively easy to accomplish and very economical. Painted steel is used successfully for many applications, including industrial equipment with electrical enclosures. Unless the proper paint and application procedures are selected, corrosion problems may develop directly from the paint, as the following incident will illustrate. A few years ago, a large electrical control enclosure [30 x 72 x 18 in. (76 x 183 x 46 cm)] was supplied to a customer with the control wiring and hardware mounted inside, which included a number of cadmium plated components. The enclosure had been painted inside with a fast drying, vinyl alkyd white enamel shortly before assembly. Since it was known that the completed unit would probably be stored at the customer's plant site for some time before installation, elaborate procedures were followed to retard or prevent degradation of any part of the system

Influence of antifouling paint on freshwater invertebrates (Mytilidae, Chironomidae and Naididae): density, richness and composition.

Science.gov (United States)

Fujita, D S; Takeda, A M; Coutinho, R; Fernandes, F C

2015-11-01

We conducted a study about invertebrates on artificial substrates with different antifouling paints in order to answer the following questions 1) is there lower accumulation of organic matter on substrates with antifouling paints, 2) is invertebrate colonization influenced by the release of biocides from antifouling paints, 3) is the colonization of aquatic invertebrates positively influenced by the material accumulated upon the substrate surface and 4) is the assemblage composition of invertebrates similar among the different antifouling paints? To answer these questions, four structures were installed in the Baía River in February 1st, 2007. Each structure was composed of 7 wood boards: 5 boards painted with each type of antifouling paints (T1, T2, T3, T4 and T5), one painted only with the primer (Pr) and the other without any paint (Cn). After 365 days, we observed a greater accumulation of organic matter in the substrates with T2 and T3 paint coatings. Limnoperna fortunei was recorded in all tested paints, with higher densities in the control, primer, T2 and T3. The colonization of Chironomidae and Naididae on the substrate was positively influenced by L. fortunei density. The non-metric multidimensional scaling (NMDS) of the invertebrate community provided evidence of the clear distinction of invertebrate assemblages among the paints. Paints T2 and T3 were the most similar to the control and primer. Our results suggest that antifouling paints applied on substrates hinder invertebrate colonization by decreasing the density and richness of invertebrates.

Investigation of VOC emissions from indoor and outdoor painting processes in shipyards

Science.gov (United States)

Celebi, Ugur Bugra; Vardar, Nurten

Volatile organic compounds (VOCs) from painting solvents are one of the most important sources of pollutant outputs for the shipbuilding and ship repair industry. Two ships of equal tonnage with the same painted area as each other, which were built in Turkish shipyards, are compared in terms of VOCs produced during painting and coating. Total area of all painted surfaces and total paint consumption of a 3500 deadweight tonne (DWT) oil/chemical tanker and a general cargo ship are calculated. An improved model for calculating the surface emissions of VOCs from painting and coating processes is utilized. Material balance emission estimation approach is employed to calculate the amount of VOCs, since it is used most often where a relatively large amount of material is emitted during use, and/or all air emissions are uncaptured. For both ships calculated VOCs are presented in figures. For the years 2005 and 2006 the total deadweight tonnage of ships delivered in Tuzla region, where 42 shipyards are located, is known. Therefore, a linear estimation is made to guess the total annual VOC emissions caused by painting operations. Finally, this information is used to project the total amount of VOCs emitted to the atmosphere for the year 2010.