Studies to overcome the manufacturing problems in blast furnace tap hole clay of Integrated Steel Plants: Experimental approach

Science.gov (United States)

Siva kumar, R.; Mohammed, Raffi; Srinivasa Rao, K.

2018-03-01

Integrated Steel Plants commonly uses Blast Furnace route for iron production which accounts for over 60 % of the world iron output. Blast Furnace runs for ten to twenty years without repairing hearth walls and Tap Hole (TH). Tap hole is an outlet for hot metal produced in a Blast Furnace and run from the shell of the furnace into the interior allowing access to the molten material. Tapping is the term used for drilling a hole through the tap hole which allows the molten iron and slag to flow out. In Iron making process, removal of liquid iron from furnace and sending it for steel making is known as cast house practice. For tapping liquid iron and operating the tap hole requires a special type of clay. Tap hole clay (THC) used to stop the flow of liquid iron and slag from the blast furnace. Present work deals with the study on manufacturing of THC at Visakhapatnam Steel Plant and problems related to manufacturing. Experiments were conducted to solve the identified problems and results are furnished in detail. The findings can improve the manufacturing process and improve the productivity of tap hole clay.

Usage of Thermodynamic Activity for Optimization of Power Expenses in Respect of Casting Process in Arc Steel-Melting Furnace

Directory of Open Access Journals (Sweden)

A. N. Chichko

2006-01-01

Full Text Available The equilibrium between carbon and oxygen has been investigated during oxidizing refining in an arc steel-melting furnace. It is shown that there is a possibility to apply an equilibrium thermodynamic. It has been established that during oxidizing refining FeO concentration in slag practically does not depend on C concentration in metal. It is demonstrated that in a number of cases metal carbon oxidation is characterized by the presence of a transit period that may be attributed to incomplete slag-formation process.

Removal of Heavy Metals from Steel Making Waste Water by Using Electric Arc Furnace Slag

Directory of Open Access Journals (Sweden)

C. L. Beh

2012-01-01

Full Text Available This work investigated the reduction of chemical oxygen demand (COD, biological oxygen demand (BOD, total suspended solids (TSS and the concentration of heavy metals of wastewater from a steel making plant. Adsorption experiments were carried out by electric arc furnace slag (EAFS in a fixed-bed column mode. The raw wastewater did not meet the standard B limitations, having high values of BOD, COD, TSS, Iron, Zinc, Manganese and Copper. After passing through the fixed bed column, BOD, COD and TSS values decreased to 1.6, 6.3 and <2 mgL-1, respectively while the concentration of Iron, Zinc, Manganese and Copper were 0.08, 0.01, 0.03 and 0.07 mgL-1, respectively. The results confirmed that EAFS can be used as an efficient adsorbent for producing treated water that comply with the Standard B limitations for an industrial effluent.

Determination of the annealing for AISI430 steel in a continous furnace

International Nuclear Information System (INIS)

Pinto, A.H.; Diab Junior, A.

1984-01-01

It's discussed a mathematical model, which represents the heating of a steel piece inside a continuous annealing furnace. It's described the experimental technique used to obtain good annealing conditions for a required quality. (Author) [pt

Performance of an effectively integrated biomass multi-stage gasification system and a steel industry heat treatment furnace

International Nuclear Information System (INIS)

Gunarathne, Duleeka Sandamali; Mellin, Pelle; Yang, Weihong; Pettersson, Magnus; Ljunggren, Rolf

2016-01-01

Highlights: • Multi-stage biomass gasification is integrated with steel heat treatment furnace. • Fossil fuel derived CO_2 emission is eliminated by replacing natural gas with syngas. • The integrated system uses waste heat from the furnace for biomass gasification. • Up to 13% increment of the gasifier system energy efficiency is observed. • Fuel switching results in 10% lower flue gas loss and improved furnace efficiency. - Abstract: The challenges of replacing fossil fuel with renewable energy in steel industry furnaces include not only reducing CO_2 emissions but also increasing the system energy efficiency. In this work, a multi-stage gasification system is chosen for the integration with a heat treatment furnace in the steel powder industry to recover different rank/temperature waste heat back to the biomass gasification system, resulting higher system energy efficiency. A system model based on Aspen Plus was developed for the proposed integrated system considering all steps, including biomass drying, pyrolysis, gasification and the combustion of syngas in the furnace. Both low temperature (up to 400 °C) and high temperature (up to 700 °C) heat recovery possibilities were analysed in terms of energy efficiency by optimizing the biomass pretreatment temperature. The required process conditions of the furnace can be achieved by using syngas. No major changes to the furnace, combustion technology or flue gas handling system are necessary for this fuel switching. Only a slight revamp of the burner system and a new waste heat recovery system from the flue gases are required. Both the furnace efficiency and gasifier system efficiency are improved by integration with the waste heat recovery. The heat recovery from the hot furnace flue gas for biomass drying and steam superheating is the most promising option from an energy efficiency point of view. This option recovers two thirds of the available waste heat, according to the pinch analysis performed

Applications of controlled thermonuclear reactor (CTR) fusion power in the steel industry

International Nuclear Information System (INIS)

Jordan, R.K.; Steinberg, M.

1975-03-01

A review of the process and economics of basic steel production is presented for the purpose of indicating where CTR fusion energy may be applicable. The present conventional air blown blast furnace produces a relatively low Btu value top gas with limited usefulness. The industry consumes relatively large amounts of natural gas for reheating ingots, plates, etc. A concept is presented wherein oxygen is used in the blast furnace which would double the capacity of the furnace and produce a rich carbon monoxide gas stream useful as synthesis gas for methanol and ammonia production. A CTR supplying high energy radiation in a blanket would disproportionate carbon dioxide to carbon monoxide and oxygen which could be used at high temperatures in the blast furnace in place of an oxygen supply stream. Coke would be used in this scheme. In a second scheme the oxygen is separated from the disproportioned CO 2 stream and CO is used in a direct reduction furnace which is followed by an electric furnace to refine the reduced product. Other schemes include iron ore reduction with electrolytic hydrogen and the use of thermal energy for reforming coal with steam or CO 2 for production of reducing gas. The electrosmelting of scrap metal using CTR power could become an important operation in the future. A complex of steel, fertilizer, fuel and chemical production is presented. Steel capacity and power requirement data are presented and projected to the year 2020. (U.S.)

Calculation of gas release from DC and AC arc furnaces in a foundry

Science.gov (United States)

Krutyanskii, M. M.; Nekhamin, S. M.; Rebikov, E. M.

2016-12-01

A procedure for the calculation of gas release from arc furnaces is presented. The procedure is based on the stoichiometric ratios of the oxidation of carbon in liquid iron during the oxidation heat period and the oxidation of iron from a steel charge by oxygen in the period of solid charge melting during the gas exchange of the furnace cavity with the external atmosphere.

Paired Straight Hearth Furnace - Transformational Ironmaking Process

Energy Technology Data Exchange (ETDEWEB)

Lu, Wei-Kao [McMaster Univ., Hamilton, ON (Canada); Debski, Paul [Andritz Metals Inc.,Canonsburg, PA (United States)

2014-11-19

The U. S. steel industry has reduced its energy intensity per ton of steel shipped by 33% since 1990. However, further significant gains in energy efficiency will require the development of new, transformational iron and steelmaking processes. The Paired Straight Hearth Furnace (PSH) process is an emerging alternative high productivity, direct reduced iron (DRI) technology that may achieve very low fuel rates and has the potential to replace blast furnace ironmaking. The PSH furnace can operate independently or may be coupled with other melting technologies to produce liquid hot metal that is both similar to blast furnace iron and suitable as a feedstock for basic oxygen steelmaking furnaces. The PSH process uses non-metallurgical coal as a reductant to convert iron oxides such as iron ore and steelmaking by-product oxides to DRI pellets. In this process, a multi-layer, nominally 120mm tall bed of composite “green balls” made from oxide, coal and binder is built up and contained within a moving refractory hearth. The pellet bed absorbs radiant heat energy during exposure to the high temperature interior refractory surfaces of the PSH while generating a strongly reducing gas atmosphere in the bed that yields a highly metalized DRI product. The PSH concept has been well tested in static hearth experiments. A moving bed design is being developed. The process developers believe that if successful, the PSH process has the potential to replace blast furnaces and coke ovens at a fraction of the operating and capital cost while using about 30% less energy relative to current blast furnace technology. DRI output could also feed electric arc furnaces (EAFs) by displacing a portion of the scrap charge.

Lance for fuel and oxygen injection into smelting or refining furnace

Science.gov (United States)

Schlichting, Mark R.

1994-01-01

A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

Chemical energy in electro arc furnace - examples from experience

International Nuclear Information System (INIS)

Shushlevski, Ljupcho; Georgievski, Panche; Hadzhidaovski, Ilija

2004-01-01

Great competition on the market in steel-producing and chemical lack of electrical energy leads to realization of new project in section Steelworks AD 'Makstil' - Skopje named: 'Substitution of electrical energy i.e. entering of additional chemical energy in Electrical arc furnace for steel melting using fuels-naturual gas (CH 4 ), oxygen (O 2 ) and carbon (C)'. It is accumulate experience from two and one half year of intensive use of chemical energy with its accompanying problems, appropriate efficiency and economy in process for steel producing. In 2001 year we announced and described project for using of an additional alternative chemical energy in aggregate Electrical are furnace. In this work we will present realization, working experience and efficiency of the system for generating chemical energy. Practical realization needs serious approach in chemical energy usage The usage of chemical energy brings restrictions and needs many innovation for protection of equipment from shown aggressiveness during the combustion of fuel gasses. (Author)

Dilute Oxygen Combustion Phase I Final Report

Energy Technology Data Exchange (ETDEWEB)

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

1997-10-31

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions

Dilute oxygen combustion. Phase I report

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-10-01

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NO{sub x}) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NO{sub x} through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NO{sub x} production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature ({approximately}1366 K) oxidant (7-27% O{sub 2} vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d{sup +} scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d{sup +} scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW ({approximately}0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric

Business diversification in blast furnace steel makers. Koro kakusha no takakuka no jokyo

Energy Technology Data Exchange (ETDEWEB)

1991-11-01

Scenarios are presented for the current business diversification and future business developments by the three Japanese blast furnace steel makers (Kawasaki Steel, Kobe Steel and Shin Nippon Steel). The conceptions for their advancement into the 2lst century are more or less similar. The business diversification commenced for Kawasaki Steel in 1985, Kobe Steel in 1989 and Shin Nippon Steel in 1987, all taking a pattern of tree-like development into related businesses starting from the basic industry. Their new businesses may be summarized generically as: electronics industry (LSI, silicon, electronic devices, information and communication); new material related business (ferrite, ceramics, metal powder, metal foils); chemical business (plastics, etc.); engineerings (architecture, urban andregional developments, etc.); and service business (system network development, lease business, real estate, leisure business, etc.). Endeavors are made also on full-scale entity into tertiary industries, and amenity field. M A and joint venture businesses are attempted in wide scale and positive manners also in overseas countries. 6 fige., 4 tads.

The determination of oxygen in metals using an impulse heating furnace with a simple transfer lock

International Nuclear Information System (INIS)

Dale, L.S.; de Jong, S.; Kelly, J.W.; Whittem, R.N.

1975-05-01

An impulse heating furnace has been constructed for the determination of low levels of oxygen down to 100 μg g -1 in metals. The furnace is equipped with a sample transfer lock which permits samples to be loaded into outgassed crucibles in a helium atmosphere. As a result, blank levels in the range 2 to 3 μg oxygen are obtained; the modification also results in shorter sample processing time. The apparatus is described, and its suitability for oxygen determinations at these levels has been verified by comparison of results obtained on reference and analysed materials. (author)

Mass Balance Modeling for Electric Arc Furnace and Ladle Furnace System in Steelmaking Facility in Turkey

Institute of Scientific and Technical Information of China (English)

(I)smail Ekmek(c)i; Ya(s)ar Yetisken; (U)nal (C)amdali

2007-01-01

In the electric arc furnace (EAF) steel production processes, scrap steel is principally used as a raw material instead of iron ore. In the steelmaking process with EAF, scrap is first melted in the furnace and then the desired chemical composition of the steel can be obtained in a special furnace such as ladle furnace (LF). This kind of furnace process is used for the secondary refining of alloy steel. LF furnace offers strong heating fluxes and enables precise temperature control, thereby allowing for the addition of desired amounts of various alloying elements. It also provides outstanding desulfurization at high-temperature treatment by reducing molten steel fluxes and removing deoxidation products. Elemental analysis with mass balance modeling is important to know the precise amount of required alloys for the LF input with respect to scrap composition. In present study, chemical reactions with mass conservation law in EAF and LF were modeled altogether as a whole system and chemical compositions of the final steel alloy output can be obtained precisely according to different scrap compositions, alloying elements ratios, and other input amounts. Besides, it was found that the mass efficiency for iron element in the system is 95.93%. These efficiencies are calculated for all input elements as 8.45% for C, 30.31% for Si, 46.36% for Mn, 30.64% for P, 41.96% for S, and 69.79% for Cr, etc. These efficiencies provide valuable ideas about the amount of the input materials that are vanished or combusted for 100 kg of each of the input materials in the EAF and LF system.

Energy saving projects in two steel companies in Fushun City, China

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

With an objective of saving energy and reducing greenhouse gas emission, investigations and discussions were given on two steel making companies in China. Discussions were given for Fushun Special Steel Co., Ltd. on abolishment and unification of four electric furnaces into two new electric furnaces, and for Fushun New Steel Co., Ltd. on installation of a granulation reinforcing facility, a segregation reinforcing device, and cooler waste heat recovery boilers for the sintering machine, installation of sensors including the waste gas oxygen concentration meter, adoption of a process computer, and optimization of the furnace temperature patterns for the heating furnace. As a result of the discussions, it was revealed that the unit requirement for electric power used at Fushun Special Steel can be reduced largely, and so can the fuel used at Fushun New Steel. The annual energy saving effect would be about 500 million yen relative to the investment amount of 2.8 billion yen at Fushun Special Steel, and about 400 million yen relative to the investment amount of about 400 million yen at Fushun New Steel. The greenhouse gas emission would be reduced annually by 40,000 t-CO2 and 60,000 t-CO2 respectively. Fushun Special Steel will execute an international bid in May this year. (NEDO)

Oxygen blast furnace and combined cycle (OBF-CC) - an efficient iron-making and power generation process

International Nuclear Information System (INIS)

Jianwei, Y.; Guolong, S.; Cunjiang, K.; Tianjun, Y.

2003-01-01

A new iron and power generating process, oxygen blast furnace and combined cycle (OBF-CC), is presented. In order to support the opinion, the features of the oxygen blast furnace and integrated coal gasification and combined cycle (IGCC) are summarized. The relation between the blasting parameters and the output gas quantity, as well as caloric value is calculated based on mass and energy balance. Analysis and calculation indicate that the OBF-CC will be an efficient iron-making and power generation process with higher energy efficiency and less pollution

An intervention for noise control of blast furnace in steel industry.

Science.gov (United States)

Golmohammadi, Rostam; Giahi, Omid; Aliabadi, Mohsen; Darvishi, Ebrahim

2014-01-01

Noise pollution is currently a major health risk factor for workers in industries. The aim of this study was to investigate noise pollution and implement a control intervention plan for blast furnace in a steel industry. The measurement of sound pressure level (SPL) along with frequency analysis was done with the sound-level-meter Cell-450. Personal noise exposure was performed using dosimeter TES-1345 calibrated with CEL-282. Before planning noise controls, acoustic insulation properties of the furnace control unit and workers' rest room were assessed. Control room and workers' rest room were redesigned in order to improve acoustical condition. The SPL before intervention around the Blast Furnace was 90.3 dB (L) and its dominant frequency was 4000 Hz. Besides, noise transmission loss of the control and rest rooms were 10.3 dB and 4.2 dB, respectively. After intervention, noise reduction rates in the control and rest rooms were 27.4 dB and 27.7 dB, respectively. The workers' noise dose before and after the intervention was 240% and less than 100%, respectively. Improvement the workroom acoustic conditions through noise insulation can be considered effective method for preventing workers exposure to harmful noise.

DEVELOPMENT OF SOFTWARE “PRODSP-1.0” FOR OPTIMIZATION OF THE DEPHOSPHORIZATION PROCESSES IN ARC STEEL-FURNACES FOR TECHNOLOGICAL LINE-UP OF RUP “BMZ”

Directory of Open Access Journals (Sweden)

A. A. Chichko

2006-01-01

Full Text Available The software “ProDSP-1,0” allowing to forecast the dynamics of the dephosphorizaiton process at casting course in arc steel-furnace, is worked out. The examples of working of different program operating regimes, showing the possibilities of phosphorus control in steel-furnace of RUP ‘'BMZ'' are given.

Effect of dissolved oxygen on SCC of LP turbine steel

International Nuclear Information System (INIS)

Maeng, W. Y.; Lee, J. H.; Kim, W. C.

2002-01-01

Slow Strain Rate Tests (SSRT) were carried out to investigate the effect of dissolved oxygen on Stress Corrosion Cracking (SCC) susceptibility of 3.5NiCrMoV steels used in discs of Low-Pressure (LP) steam turbines in electric power generating plants. The influence of dissolved oxygen on cracking in water was studied; for this purpose, specimens were strained to fracture at 150 .deg. C in water environments with various amounts of dissolved oxygen. The maximum elongation of the turbine steel decreased with increasing dissolved oxygen. Dissolved oxygen significantly affected the SCC susceptibility of turbine steel in water. The increase of the SCC susceptibility of the turbine steel in a higher dissolved oxygen environment is due to the non protectiveness of the oxide layer of the turbine steel surface and the increase of corrosion current

Heavy metal recovery from electric arc furnace steel slag by using hydrochloric acid leaching

Science.gov (United States)

Wei, Lim Jin; Haan, Ong Teng; Shean Yaw, Thomas Choong; Chuah Abdullah, Luqman; Razak, Mus'ab Abdul; Cionita, Tezara; Toudehdehghan, Abdolreza

2018-03-01

Electric Arc Furnace steel slag (EAFS) is the waste produced in steelmaking industry. Environmental problem such as pollution will occur when dumping the steel slag waste into the landfill. These steel slags have properties that are suitable for various applications such as water treatment and wastewater. The objective of this study is to develop efficient and economical chlorination route for EAFS extraction by using leaching process. Various parameters such as concentration of hydrochloric acid, particle size of steel slag, reaction time and reaction temperature are investigated to determine the optimum conditions. As a result, the dissolution rate can be determined by changing the parameters, such as concentration of hydrochloric acid, particle size of steel slag, reaction time and reaction temperature. The optimum conditions for dissolution rates for the leaching process is at 3.0 M hydrochloric acid, particle size of 1.18 mm, reaction time of 2.5 hour and the temperature of 90°C.

The efficacy of radiant heat controls on workers' heat stress around the blast furnace of a steel industry.

Science.gov (United States)

Giahi, Omid; Darvishi, Ebrahim; Aliabadi, Mohsen; Khoubi, Jamshid

2015-01-01

Workers' exposure to excessive heat in molten industries is mainly due to radiant heat from hot sources. The aim of this study was to evaluate the efficacy of radiant heat controls on workers heat stress around a typical blast furnace. Two main interventions were applied for reducing radiant heat around the blast furnace of a steel industry located in western Iran. These included using a heat absorbing system in the furnace body and installing reflective aluminum barrier in the main workstation. Heat stress indexes were measured before and after each intervention using the digital WBGT-meter. The results showed MRT and WBGT indexes decreased by 20 °C and 3.9 °C, respectively after using heat absorbing system and also decreased by 18.6 °C and 2.5 °C, respectively after installing a reflective barrier. These indexes decrease by 26.5 °C and 5.2 °C, respectively due to the simultaneous application of the two interventions which were statistically significant (p steel industries.

Mutual Influence of Special Components in Baotou Steel Blast Furnace Slag on the Crystallization Behavior of Glass

OpenAIRE

Wang, Yici; Jiang, Qi; Luo, Guoping; Yu, Wenwu; Ban, Yan

2012-01-01

In the process of glass-ceramics prepared with Baotou steel blast furnace slag, quartz sand, and other raw materials by melting method, the mutual influence of the special components such as CaF2, REXOY, TiO2, K2O, and Na2O in the blast furnace slag on the crystallization behavior of parent glass was investigated using differential thermal analysis (DTA) and X-ray diffraction (XRD). The results show that the special components in slag can reduce the crystallization temperature and promote cry...

Continuous austempering fluidized bed furnace. Final report

Energy Technology Data Exchange (ETDEWEB)

Srinivasan, M.N. [Lamar Univ., Beaumont, TX (United States). Dept. of Mechanical Engineering

1997-09-23

The intended objective of this project was to show the benefits of using a fluidized bed furnace for austenitizing and austempering of steel castings in a continuous manner. The division of responsibilities was as follows: (1) design of the fluidized bed furnace--Kemp Development Corporation; (2) fabrication of the fluidized bed furnace--Quality Electric Steel, Inc.; (3) procedure for austempering of steel castings, analysis of the results after austempering--Texas A and M University (Texas Engineering Experiment Station). The Department of Energy provided funding to Texas A and M University and Kemp Development Corporation. The responsibility of Quality Electric Steel was to fabricate the fluidized bed, make test castings and perform austempering of the steel castings in the fluidized bed, at their own expense. The project goals had to be reviewed several times due to financial constraints and technical difficulties encountered during the course of the project. The modifications made and the associated events are listed in chronological order.

Technical Update: Johnson Space Center system using a solid electrolytic cell in a remote location to measure oxygen fugacities in CO/CO2 controlled-atmosphere furnaces

Science.gov (United States)

Jurewicz, A. J. G.; Williams, R. J.; Le, L.; Wagstaff, J.; Lofgren, G.; Lanier, A.; Carter, W.; Roshko, A.

1993-01-01

Details are given for the design and application of a (one atmosphere) redox-control system. This system differs from that given in NASA Technical Memorandum 58234 in that it uses a single solid-electrolytic cell in a remote location to measure the oxygen fugacities of multiple CO/CO2 controlled-atmosphere furnaces. This remote measurement extends the range of sample-furnace conditions that can be measured using a solid-electrolytic cell, and cuts costs by extending the life of the sensors and by minimizing the number of sensors in use. The system consists of a reference furnace and an exhaust-gas manifold. The reference furnace is designed according to the redox control system of NASA Technical Memorandum 58234, and any number of CO/CO2 controlled-atmosphere furnaces can be attached to the exhaust-gas manifold. Using the manifold, the exhaust gas from individual CO/CO2 controlled atmosphere furnaces can be diverted through the reference furnace, where a solid-electrolyte cell is used to read the ambient oxygen fugacity. The oxygen fugacity measured in the reference furnace can then be used to calculate the oxygen fugacity in the individual CO/CO2 controlled-atmosphere furnace. A BASIC computer program was developed to expedite this calculation.

CO2 Abatement In The Iron And Steel Industry

Energy Technology Data Exchange (ETDEWEB)

NONE

2012-01-15

The iron and steel industry is the largest industrial source of CO2 emissions due to the energy intensity of steel production, its reliance on carbon-based fuels and reductants, and the large volume of steel produced -- over 1414 Mt in 2010. With the growing concern over climate change, steel makers are faced with the challenge of finding ways of lowering CO2 emissions without seriously undermining process efficiency or considerably adding to costs. This report examines ways of abating CO2 emissions from raw materials preparation (coking, sintering and pelletising plants) through to the production of liquid steel in basic oxygen furnaces and electric arc furnaces. Direct reduction and smelting reduction processes are covered, as well as iron making in a blast furnace. A range of technologies and measures exist for lowering CO2 emissions including minimising energy consumption and improving energy efficiency, changing to a fuel and/or reducing agent with a lower CO2 emission factor (such as wood charcoal), and capturing the CO2 and storing it underground. Significant CO2 reductions can be achieved by combining a number of the available technologies. If carbon capture and storage is fitted than steel plants could become near zero emitters of CO2.

austenitic steel corrosion by oxygen-containing liquid sodium

International Nuclear Information System (INIS)

Rivollier, Matthieu

2017-01-01

France is planning to construct the 4. generation of nuclear reactors. They will use liquid sodium as heat transfer fluid and will be made of 316L(N) austenitic steel as structural materials. To guarantee optimal operation on the long term, the behavior of this steel must be verified. This is why corrosion phenomena of 316L(N) steel by liquid sodium have to be well-understood. Literature points out that several corrosion phenomena are possible. Dissolved oxygen in sodium definitely influences each of the corrosion phenomenon. Therefore, the austenitic steel corrosion in oxygen-containing sodium is proposed in this study. Thermodynamics data point out that sodium chromite formation on 316L(N) steel is possible in sodium containing roughly 10 μg.g -1 of oxygen for temperature lower than 650 C (reactor operating conditions).The experimental study shows that sodium chromite is formed at 650 C in the sodium containing 200 μg.g -1 of oxygen. At the same concentration and at 550 C, sodium chromite is clearly observed only for long immersion time (≥ 5000 h). Results at 450 C are more difficult to interpret. Furthermore, the steel is depleted in chromium in all cases.The results suggest the sodium chromite is dissolved in the sodium at the same time it is formed. Modelling of sodium chromite formation - approached by chromium diffusion in steel (in grain and grain boundaries -, and dissolution - assessed by transport in liquid metal - show that simultaneous formation and dissolution of sodium chromite is a possible mechanism able to explain our results. (author) [fr

FINDING WAYS OF RECYCLING DUST OF ARC STEEL FURNACES AT THE BELARUSIAN METALLURGIC PLANT

Directory of Open Access Journals (Sweden)

A. V. Demin

2015-01-01

Full Text Available The first part examines the theoretical possibility of recycling dust of arc steel furnaces. The different modes of dust disposal depending on the task of recycling are discussed: recycling at minimal cost; recycling with a maximum extraction of iron; recycling with maximum extraction of zinc. The results of laboratory studies providing information on the technical feasibility of recycling dust formed at the Belarusian metallurgic plant are provided.

Rheological Characterization of Warm-Modified Asphalt Mastics Containing Electric Arc Furnace Steel Slags

Directory of Open Access Journals (Sweden)

M. Pasetto

2016-01-01

Full Text Available The environmental sustainability of road materials and technologies plays a key role in pavement engineering. In this sense, the use of Warm Mix Asphalt (WMA, that is, a modified asphalt concrete that can be produced and applied at lower temperature, is considered an effective solution leading to environmental and operational benefits. The environmental sustainability of WMA can be further enhanced with the inclusion of steel slag in partial substitution of natural aggregates. Nevertheless, such innovative material applied at lower temperatures containing warm additives and steel slag should be able to guarantee at least the same performance of traditional hot mix asphalts, thus assuring acceptable mechanical properties and durability. Therefore, the purpose of this study is to investigate the rheological behaviour of bituminous mastics obtained combining a warm-modified binder and a filler (material passing to 0.063 mm coming from electric arc furnace steel slag. To evaluate the influence of both warm additive and steel slag, a plain binder and limestone filler were also used for comparison purposes. Complex modulus and permanent deformation resistance of bitumens and mastics were assessed using a dynamic shear rheometer. Experimental results showed that steel slag warm mastics assure enhanced performance demonstrating promising applicability.

Autoradiographic investigation of the removal of non-metallic inclusions in connection with the steel remelting process in vacuum furnaces

International Nuclear Information System (INIS)

Kolaski, H.; Siewierski, J.

1978-01-01

The labelled radioactive non-metallic inclusions in steel were obtained through deoxidation of steel with an activated aluminium alloy containing 1% rare earths. Quantity and distribution of the non-metallic inclusions in the steel were determined by applying autoradiography to the longitudinal and cross sections of the steel slabs. After remelting in an electronic furnace the distribution of non-metallic inclusions was determined by autoradiography of the lateral surfaces and the cross section of the slabs. It was found that 50 - 70% of the inclusions could be removed. The results obtained from autoradiographic investigation allow the exploration of the mechanism of the removal of inclusions. (author)

The influence of the structure of the metal load removal from liquid steel in electric arc furnaces

Science.gov (United States)

Pǎcurar, Cristina; Hepuť, Teodor; Crisan, Eugen

2016-06-01

One of the main technical and economic indicators in the steel industry and steel respectively the development it is the removal of liquid steel. This indicator depends on several factors, namely technology: the structure and the quality metal load, the degree of preparedness of it, and the content of non-metallic material accompanying the unit of drawing up, the technology for the elaboration, etc. research has been taken into account in drawing up steel electric arc furnace type spring EBT (Electric Bottom taping), seeking to load and removing components of liquid steel. Metal load has been composed of eight metal grades, in some cases with great differences in terms of quality. Data obtained were processed in the EXCEL spreadsheet programs and MATLAB, the results obtained being presented both graphically and analytically. On the basis of the results obtained may opt for a load optimal structure metal.

A Gibbs Energy Minimization Approach for Modeling of Chemical Reactions in a Basic Oxygen Furnace

Science.gov (United States)

Kruskopf, Ari; Visuri, Ville-Valtteri

2017-12-01

In modern steelmaking, the decarburization of hot metal is converted into steel primarily in converter processes, such as the basic oxygen furnace. The objective of this work was to develop a new mathematical model for top blown steel converter, which accounts for the complex reaction equilibria in the impact zone, also known as the hot spot, as well as the associated mass and heat transport. An in-house computer code of the model has been developed in Matlab. The main assumption of the model is that all reactions take place in a specified reaction zone. The mass transfer between the reaction volume, bulk slag, and metal determine the reaction rates for the species. The thermodynamic equilibrium is calculated using the partitioning of Gibbs energy (PGE) method. The activity model for the liquid metal is the unified interaction parameter model and for the liquid slag the modified quasichemical model (MQM). The MQM was validated by calculating iso-activity lines for the liquid slag components. The PGE method together with the MQM was validated by calculating liquidus lines for solid components. The results were compared with measurements from literature. The full chemical reaction model was validated by comparing the metal and slag compositions to measurements from industrial scale converter. The predictions were found to be in good agreement with the measured values. Furthermore, the accuracy of the model was found to compare favorably with the models proposed in the literature. The real-time capability of the proposed model was confirmed in test calculations.

Coal Combustion Behavior in New Ironmaking Process of Top Gas Recycling Oxygen Blast Furnace

Science.gov (United States)

Zhou, Zhenfeng; Xue, Qingguo; Tang, Huiqing; Wang, Guang; Wang, Jingsong

2017-10-01

The top gas recycling oxygen blast furnace (TGR-OBF) is a new ironmaking process which can significantly reduce the coke ratio and emissions of carbon dioxide. To better understand the coal combustion characteristics in the TGR-OBF, a three dimensional model was developed to simulate the lance-blowpipe-tuyere-raceway of a TGR-OBF. The combustion characteristics of pulverized coal in TGR-OBF were investigated. Furthermore, the effects of oxygen concentration and temperature were also analyzed. The simulation results show that the coal burnout increased by 16.23% compared to that of the TBF. The oxygen content has an obvious effect on the burnout. At 70% oxygen content, the coal burnout is only 21.64%, with a decrease of 50.14% compared to that of TBF. Moreover, the effect of oxygen temperature is also very obvious.

Experience in melting of high-quality chromium-nickel-molybdenum steel in oxygen converter

Energy Technology Data Exchange (ETDEWEB)

Kosoi, L F; Yaburov, S I; Shul' kin, M L; Vedernikov, G G; Bragin, E D; Filork' yan, B K

1978-10-01

Technology of melting high-quality medium-carbon constructional chromium-nickel-molybdenum steel has been developed and tested in 130-t converters. The technology envisages metal refinement in a casting laddle using synthetic lime-aluminous slag and argon blowing, as well as liquid ferroallys (master alloys) for steel deoxidation and alloying. Due to a smaller content of sulfur, phosphorus, arsenic and sulphide inclusions, and to a smaller grain size (N 11-12), the steel, produced according to this technology possesses higher plastic properties and impact strength than conventional open-hearth furnace metal after heat treatment for the same strength.

Waste and dust utilisation in shaft furnaces

Energy Technology Data Exchange (ETDEWEB)

Senk, D.; Babich, A.; Gudenau, H.W. [Rhein Westfal TH Aachen, Aachen (Germany)

2005-07-01

Wastes and dusts from steel industry, non-ferrous metallurgy and other branches can be utilised e.g. in agglomeration processes (sintering, pelletising or briquetting) and by injection into shaft furnaces. This paper deals with the second way. Combustion and reduction behaviour of iron- and carbon-rich metallurgical dusts and sludges containing lead, zinc and alkali as well as other wastes with and without pulverised coal (PC) has been studied when injecting into shaft furnaces. Following shaft furnaces have been examined: blast furnace, cupola furnace, OxiCup furnace and imperial-smelting furnace. Investigations have been done at laboratory and industrial scale. Some dusts and wastes under certain conditions can be not only reused but can also improve combustion efficiency at the tuyeres as well as furnace performance and productivity.

Operation of arc heating furnace on manufacturing gigantic ingots and segregation of gigantic ingots

International Nuclear Information System (INIS)

Niimi, Takayasu; Okamura, Masayoshi

1976-01-01

The techniques and procedure for manufacturing gigantic ingots heavier than 200 t are described. Especially, practical results of an arc heating furnace which plays an important role in the procedure and segregation of gigantic ingots are discussed in detail. By appropriate operations of the arc heating furnance, hydrogen and phosphorus are kept unchanged, and oxygen and sulphur decrease to very low levels. Furthermore, the temperature can be accurately controlled. The application of multipour technique reduces segregation and its degree is dependent on kinds of steel. V-segregation and inverted V-segregation in steel deoxidized with carbon in vacuum seem to be very slight. (auth.)

Advances in chemical and physical properties of electric arc furnace carbon steel slag by hot stage processing and mineral mixing.

Science.gov (United States)

Liapis, Ioannis; Papayianni, Ioanna

2015-01-01

Slags are recognised as a highly efficient, cost effective tool in the metal processing industry, by minimising heat losses, reducing metal oxidation through contact with air, removing metal impurities and protecting refractories and graphite electrodes. When compared to natural aggregates for use in the construction industry, slags have higher specific weight that acts as an economic deterrent. A method of altering the specific weight of EAFC slag by hot stage processing and mineral mixing, during steel production is presented in this article. The method has minimal interference with the production process of steel, even by limited additions of appropriate minerals at high temperatures. Five minerals are examined, namely perlite, ladle furnace slag, bauxite, diatomite and olivine. Measurements of specific weight are accompanied by X-ray diffraction (XRD) and fluorescence (XRF) analysis and scanning electron microscopy spectral images. It is also shown how altering the chemical composition is expected to affect the furnace refractory lining. Additionally, the process has been repeated for the most suitable mix in gas furnace and physical properties (FI, SI, LA, PSV, AAV, volume stability) examined. Alteration of the specific weight can result in tailoring slag properties for specific applications in the construction sector. Copyright © 2014 Elsevier B.V. All rights reserved.

Tendencies in development of radioactive isotopes application in investigations of cast iron and steels metallurgy in Hungary

International Nuclear Information System (INIS)

Shimon, Sh.

1979-01-01

Results have been presented of radioisotope investigations which had been done with the purpose to prove theoretical bases of metallurgic processes as well as to compute separate processes of cast iron and steel production. Results are considered of investigations of the process of going down of charge in a blast furnace and of the process of oxygen steel production as well as of lowering of oxygen inclusions content and creation of reduction and oxidation conditions for separate alloying elements of steel. On the base of the results listed for these investigations, tendencies of development have been presented [ru

Laboratory Study on Prevention of CaO-Containing ASTM "D-Type" Inclusions in Al-Deoxidized Low-Oxygen Steel Melts During Basic Slag Refining

Science.gov (United States)

Jiang, Min; Wang, Xin-Hua; Yang, Die; Lei, Shao-Long; Wang, Kun-Peng

2015-12-01

Present work was attempted to explore the possibility of preventing CaO-containing inclusions in Al-deoxidized low-oxygen special steel during basic slag refining, which were known as ASTM D-type inclusions. Based on the analysis on formation thermodynamics of CaO-containing inclusions, a series of laboratory experiments were designed and carried out in a vacuum induction furnace. During the experiments, slag/steel reaction equilibrium was intentionally suppressed with the aim to decrease the CaO contents in inclusions, which is different from ordinary concept that slag/steel reaction should be promoted for better control of inclusions. The obtained results showed that high cleanliness of steel was obtained in all the steel melts, with total oxygen contents varied between 0.0003 and 0.0010 pct. Simultaneously, formation of CaO-containing inclusions was successfully prohibited, and all the formed oxide inclusions were MgO-Al2O3 or/and Al2O3 in very small sizes of about 1 to 3 μm. And 90 pct to nearly 98 pct of them were wrapped by relative thicker MnS outer surface layers to produce dual-phased "(MgO-Al2O3) + MnS" or "Al2O3 + MnS" complex inclusions. Because of much better ductility of MnS, certain deformability of these complex inclusions can be expected which is helpful to improve fatigue resistance property of steel. Only very limited number of singular MnS inclusions were with sizes larger than 13 μm, which were formed during solidification because of. In the end, formation of oxide inclusions in steel was qualitatively evaluated and discussed.

INFLUENCE OF THE MODERN SYSTEMS OF THE BLAST STEEL-FURNACE ELECTRICAL PARAMETERS CONTROL ON CAPACITY AND TECHNICAL AND ECONOMICAL INDICES OF MELTING

Directory of Open Access Journals (Sweden)

D. N. Andrianov

2006-01-01

Full Text Available The reduction of time under the current, electric energy rate, electrodes rate at working of arc steel-furnace with new transformer of capacity 95 MBA and with regulating system SIMELT-AC-NEC are noted.

Mathematical modeling of thermal stresses in basic oxygen furnace hood tubes

Science.gov (United States)

Samarasekera, I. V.

1985-06-01

The stress-strain history of Basic Oxygen Furnace hood tubes during thermal cycling has been computed using heat flow and stress analyses. The steady-state temperature distribution in a transverse section of the tube was computed at a location where gas temperature in the hood could be expected to be a maximum. Calculations were performed for peak gas temperatures in the range 1950 to 2480 °C (3500 to 4500 °F). The stress-strain history of an element of material located at the center of the tube hot face was traced for three consecutive cycles using elasto-plastic finite-element analysis. It has been shown that the state of stress in the element alternates between compression and tension as the tube successively heats and cools. Yielding and plastic flow occurs at the end of each half of a given cycle. It was postulated that owing to repctitive yielding, plastic strain energy accumulates causing failure of the tubes by fatigue in the low cycle region. Using fatigue theory a conservative estimate for tube life was arrived at. In-plant observations support this mechanism of failure, and the number of cycles within which tube cracking was observed compares reasonably with model predictions. Utilizing the heat flow and stress models it was recommended that tube life could be enhanced by changing the tube material to ARMCO 17-4 pH or AISI 405 steel or alternatively reconstructing hoods with AISI 316L tubes of reduced thickness. These recommendations were based on the criterion that low-cycle fatigue failure could be averted if the magnitude of the cyclic strain could be reduced or if macroscopic plastic flow could be prevented.

Report of year 2000 version on basic study for promotion of joint implementation. Energy conservation by renovation of reheating furnace at 'SIDEX' S.A. Galati Steel Plant, Romania

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

The purpose of this project is to perform a feasibility study on energy conservation by renovation of reheating furnace at 'SIDEX' S.A. Galati Steel Plant, and discuss the possibility of the future joint implementation project. This project is intended to contribute to reduction in greenhouse effect gas emission in Romania through energy conservation in industries, and introduction of the Japanese energy saving technologies. Furthermore, this project would be capable of contributing to modernization of the industries to achieve sustainable economic growth in Romania, where the joint implementation will be performed in the future. The fuel consumption per ton in the conventionally used reheating furnaces is actually about three times as much as in the same furnaces in Japan. Speaking of electric power consumption, it is about four times as much. The renovation will result in reduction of fuel consumption to the same level as in steel mills in Japan. This will reduce the import of natural gas by 59 million Nm{sup 3} annually after the project will have been implemented, and reduction is expected in CO2 of about 170,000 tons (on the basis of conversion to petroleum). The second effect is reduction of oxidation scale on surfaces of steel products generated in the furnaces at 3% or more presently to about 1%, which corresponds to steel products of more than 20,000 tons. (NEDO)

Development of vacuum brazing furnace

International Nuclear Information System (INIS)

Singh, Rajvir; Yedle, Kamlesh; Jain, A.K.

2005-01-01

In joining of components where welding process is not possible brazing processes are employed. Value added components, high quality RF systems, UHV components of high energy accelerators, carbide tools etc. are produced using different types of brazing methods. Furnace brazing under vacuum atmosphere is the most popular and well accepted method for production of the above mentioned components and systems. For carrying out vacuum brazing successfully it is essential to have a vacuum brazing furnace with latest features of modern vacuum brazing technology. A vacuum brazing furnace has been developed and installed for carrying out brazing of components of copper, stainless steel and components made of dissimilar metals/materials. The above furnace has been designed to accommodate jobs of 700mm diameter x 2000mm long sizes with job weight of 500kgs up to a maximum temperature of 1250 degC at a vacuum of 5 x 10 -5 Torr. Oil diffusion pumping system with a combination of rotary and mechanical booster pump have been employed for obtaining vacuum. Molybdenum heating elements, radiation shield of molybdenum and Stainless Steel Grade 304 have been used. The above furnace is computer controlled with manual over ride facility. PLC and Pentium PC are integrated together to maneuver steps of operation and safety interlocks of the system. Closed loop water supply provides cooling to the system. The installation of the above system is in final stage of completion and it will be ready for use in next few months time. This paper presents insights of design and fabrication of a modern vacuum brazing furnace and its sub-system. (author)

Thermodynamic analysis of the conditions of deoxidation and secondary treatment of low-silicon steel grade

Directory of Open Access Journals (Sweden)

Євген Анатолійович Чичкарьов

2015-10-01

Full Text Available This article is concerned with analysis and production testing of technological solutions aimed at reducing the consumption of aluminium for steel deoxidation and reducing level of metal contamination by oxide non-metal inclusions, as well as preventing silicon reduction during out-of-furnace treatment. The conditions of low-silicon steel deoxidation and out-of-furnace treatment have been analysed. It has been found that the scope of oxygen activity variation in the converter before tapping increases while the mass fraction of carbon in the metal decreases. For the converter meltings with a mass fraction of carbon over the range 0,05-0,07 % [C] before tapping the real range of variation was 150-300 ppm. The effect of meltings carburizing on aluminium consumption and the degree of aluminium assimilation have been analysed. It has been shown that in fact the same specific consumption of ferromanganese and comparable changes within the metal oxidation change range before tapping (400-1100 ppm the addition of the carburizer decreases the consumption of aluminium by 0,15 kg/t (in amounts of pure aluminium. The variation interval of assimilation degree of aluminium, consumed for binding the dissolved oxygen in metal and for dissolution in metal has been found. It has been shown that in the melting of low-silicon steel with out- of-furnace treatment but without the use of furnace-ladle unit the rational limit of variation of mass fraction of magnesium oxide variation in the ladle slag is equal to- 6-8 % by weight

Nitrogen Control in Electric Arc Furnace Steelmaking by DRI (TRP 0009)

Energy Technology Data Exchange (ETDEWEB)

Dr. Gordon A. Irons

2004-03-31

Nitrogen is difficult to remove in electric arc furnace (EAF) steelmaking, requiring the use of more energy in the oxygen steelmaking route to produce low-nitrogen steel. The objective of this work was to determine if the injection of directly reduced iron (DRI) fines into EAFs could reduce the nitrogen content by creating fine carbon monoxide bubbles that rinse nitrogen from the steel. The proposed work included physical and chemical characterization of DRI fines, pilot-scale injection into steel, and mathematical modeling to aid in scale-up of the process. Unfortunately, the pilot-scale injections were unsuccessful, but some full-scale data was obtained. Therefore, the original objectives were met, and presented in the form of recommendations to EAF steelmakers regarding: (1) The best composition and size of DRI fines to use; (2) The amount of DRI fines required to achieve a specific reduction in nitrogen content in the steel; and (3) The injection conditions. This information may be used by steelmakers in techno-economic assessments of the cost of reducing nitrogen with this technology.

A Bottom-up Energy Efficiency Improvement Roadmap for China’s Iron and Steel Industry up to 2050

Energy Technology Data Exchange (ETDEWEB)

Zhang, Qi [Northeastern Univ., Shenyang (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Hasanbeigi, Ali [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Price, Lynn [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Lu, Hongyou [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Arens, Marlene [Fraunhofer Inst. for Systems and Innovation Research (ISI), Karlsruhe (Germany)

2016-09-01

Iron and steel manufacturing is energy intensive in China and in the world. China is the world largest steel producer accounting for around half of the world steel production. In this study, we use a bottom-up energy consumption model to analyze four steel-production and energy-efficiency scenarios and evaluate the potential for energy savings from energy-efficient technologies in China’s iron and steel industry between 2010 and 2050. The results show that China’s steel production will rise and peak in the year 2020 at 860 million tons (Mt) per year for the base-case scenario and 680 Mt for the advanced energy-efficiency scenario. From 2020 on, production will gradually decrease to about 510 Mt and 400 Mt in 2050, for the base-case and advanced scenarios, respectively. Energy intensity will decrease from 21.2 gigajoules per ton (G/t) in 2010 to 12.2 GJ/t and 9.9 GJ/t in 2050 for the base-case and advanced scenarios, respectively. In the near term, decreases in iron and steel industry energy intensity will come from adoption of energy-efficient technologies. In the long term, a shift in the production structure of China’s iron and steel industry, reducing the share of blast furnace/basic oxygen furnace production and increasing the share of electric-arc furnace production while reducing the use of pig iron as a feedstock to electric-arc furnaces will continue to reduce the sector’s energy consumption. We discuss barriers to achieving these energy-efficiency gains and make policy recommendations to support improved energy efficiency and a shift in the nature of iron and steel production in China.

Methods of forging steel

OpenAIRE

Pečoler, Primož

2014-01-01

The following work presents processes of steel forming, challenges when forging steel, forming machines suitable for forging and which choice of machine is most suitable for forging. We can separate steel forming to free forging and drop forging. Free forging can be divided to hand forging and machine forging. The correct choice of furnaces is also very important. We must reach correct temperature in the furnace for raw steel to melt with less scalings. In diploma I mentioned some machine...

Brazing open cell reticulated copper foam to stainless steel tubing with vacuum furnace brazed gold/indium alloy plating

Science.gov (United States)

Howard, Stanley R [Windsor, SC; Korinko, Paul S [Aiken, SC

2008-05-27

A method of fabricating a heat exchanger includes brush electroplating plated layers for a brazing alloy onto a stainless steel tube in thin layers, over a nickel strike having a 1.3 .mu.m thickness. The resultant Au-18 In composition may be applied as a first layer of indium, 1.47 .mu.m thick, and a second layer of gold, 2.54 .mu.m thick. The order of plating helps control brazing erosion. Excessive amounts of brazing material are avoided by controlling the electroplating process. The reticulated copper foam rings are interference fit to the stainless steel tube, and in contact with the plated layers. The copper foam rings, the plated layers for brazing alloy, and the stainless steel tube are heated and cooled in a vacuum furnace at controlled rates, forming a bond of the copper foam rings to the stainless steel tube that improves heat transfer between the tube and the copper foam.

Minimization of Blast furnace Fuel Rate by Optimizing Burden and Gas Distribution

Energy Technology Data Exchange (ETDEWEB)

Dr. Chenn Zhou

2012-08-15

The goal of the research is to improve the competitive edge of steel mills by using the advanced CFD technology to optimize the gas and burden distributions inside a blast furnace for achieving the best gas utilization. A state-of-the-art 3-D CFD model has been developed for simulating the gas distribution inside a blast furnace at given burden conditions, burden distribution and blast parameters. The comprehensive 3-D CFD model has been validated by plant measurement data from an actual blast furnace. Validation of the sub-models is also achieved. The user friendly software package named Blast Furnace Shaft Simulator (BFSS) has been developed to simulate the blast furnace shaft process. The research has significant benefits to the steel industry with high productivity, low energy consumption, and improved environment.

Energy-saving by the optimization of the operation conditions in the vinylcloride lining steel pipe baking furnace. Enbirainingu kokan yakitsukero no sogyo joken saitekika ni yoru sho energy

Energy Technology Data Exchange (ETDEWEB)

Kinoshita, Y. (Kawasaki Steel Corp., Tokyo (Japan))

1991-02-04

By the investigation of the operation conditions in the small experimental furnace, the improvement of the heat pattern of the steel pipes, and the remodeling and arrangement of the furnace, the progress of the yield and the productivity, and the reduction of the fuel unit were expected. In baking of a PVC pipe with a steel pipe, defects of PVC pipes as the blister of the inner surface occurred often. Accordingly the conditions when the blister occurred were investigated in the experimental furnace and optimized operation conditions when it does not occur were established. Next the flow rate of the hot air and the temperature distribution in the actual furnace were examined and the mechanism of occurrence of the defects of the blister of the inner surface was investigated. As a result, it was proved that the deviation of the hot air flux and the intrusion of the outer air cause it, and the places where the outer air intruded were closed by steel plates. After the improvements the rate of the defects of PVC pipes of the blister of the inner surface was decreased from 5% to 0.5%. Further, by the optimization of the operation conditions the fuel unit decreased and 31% of the rate of the energy-saving was achieved. The reduction of 10,414,000 yen a year was achieved. 29 figs., 4 tabs.

Improvement of methods of combustion of natural gas in steel furnaces. Usovershenstvovanie metodov szhiganiya prirodnogo gaza v staleplavil'nykh pechakh

Energy Technology Data Exchange (ETDEWEB)

Lisienko, V G; Kitaev, B I; Kokarev, N I

1977-01-01

An examination is made of the properties of various kinds of high-energy fuel used for steel-making furnaces (natural gas, new brands of fuel oils), and a description is given of designs for gas-fuel oil burners. A flare theory is presented and the principles of designing jet and gas-fuel oil burners are discussed. Results are given for industrial tests and recommendations are made for improving gas and fuel oil combustion in operating furnaces. Formulas are given for designing burner devices and spray burners. A description is given of research and industrial tests of new designs of natural gas reformers that make it possible to reduce the amount of fuel oil required in smelting high quality steel. The book is intended for engineering and technical personnel of metallurgical and machine-building plants and scientific-research and design institutes. It can also be used by senior students in metallurgical departments at higher institutions of learning, and particularly at evening and correspondent divisions. 273 references, 88 figures, 13 tables.

The Automation Control System Design of Walking Beam Heating Furnace

Directory of Open Access Journals (Sweden)

Hong-Yu LIU

2014-10-01

Full Text Available Combining the transformation project of certain strip steel rolling production line, the techniques process of walking beam heating furnace was elaborated in this paper. The practical application of LOS-T18-2ZC1 laser detector was elaborated. The network communication model of walking beam heating furnace control system was designed. The realization method of production process automation control was elaborated. The entire automation control system allocation picture and PLC power distribution system picture of walking beam heating furnace were designed. Charge machine movement process was elaborated. Walking beam movement process was elaborated. Extractor movement process was elaborated. The hydraulic station of walking mechanism was elaborated. Relative control circuit diagram was designed. The control function of parallel shift motor, uplifted and degressive motor was elaborated. The control circuit diagram of parallel shift motor of charge machine and extractor of first heating furnace was designed. The control circuit diagram of uplifted and degressive motor of charge machine and extractor of first heating furnace was designed. The realization method of steel blank length test function was elaborated. The realization method of tracking and sequence control function of heating furnace field roller were elaborated. The design provides important reference base for enhancing walking beam heating furnace control level.

Determination of oxygen content in steel using activation analysis with 14 MeV neutron

International Nuclear Information System (INIS)

Calado, C.E.

1978-01-01

In the quantitative analysis of oxygen in steel by fast neutron activation analysis the oxygen content is evaluated from the measured activity of 16 N produced. Steel s mples are irradiated in 14 MeV neutron flux. After irradiation the samples are pneumatically transfered to the counting terminal where activity is measured. Oxygen concentrations, are obtained by comparison with standards of specified oxygen content [pt

Numerical Investigation of Novel Oxygen Blast Furnace Ironmaking Processes

Science.gov (United States)

Li, Zhaoyang; Kuang, Shibo; Yu, Aibing; Gao, Jianjun; Qi, Yuanhong; Yan, Dingliu; Li, Yuntao; Mao, Xiaoming

2018-04-01

Oxygen blast furnace (OBF) ironmaking process has the potential to realize "zero carbon footprint" production, but suffers from the "thermal shortage" problem. This paper presents three novel OBF processes, featured by belly injection of reformed coke oven gas, burden hot-charge operation, and their combination, respectively. These processes were studied by a multifluid process model. The applicability of the model was confirmed by comparing the numerical results against the measured key performance indicators of an experimental OBF operated with or without injection of reformed coke oven gas. Then, these different OBF processes together with a pure OBF were numerically examined in aspects of in-furnace states and global performance, assuming that the burden quality can be maintained during the hot-charge operation. The numerical results show that under the present conditions, belly injection and hot charge, as auxiliary measures, are useful for reducing the fuel rate and increasing the productivity for OBFs but in different manners. Hot charge should be more suitable for OBFs of different sizes because it improves the thermochemical states throughout the dry zone rather than within a narrow region in the case of belly injection. The simultaneous application of belly injection and hot charge leads to the best process performance, at the same time, lowering down hot-charge temperature to achieve the same carbon consumption and hot metal temperature as that achieved when applying the hot charge alone. This feature will be practically beneficial in the application of hot-charge operation. In addition, a systematic study of hot-charge temperature reveals that optimal hot-charge temperatures can be identified according to the utilization efficiency of the sensible heat of hot burden.

Comprehensive Numerical Modeling of the Blast Furnace Ironmaking Process

Science.gov (United States)

Zhou, Chenn; Tang, Guangwu; Wang, Jichao; Fu, Dong; Okosun, Tyamo; Silaen, Armin; Wu, Bin

2016-05-01

Blast furnaces are counter-current chemical reactors, widely utilized in the ironmaking industry. Hot reduction gases injected from lower regions of the furnace ascend, reacting with the descending burden. Through this reaction process, iron ore is reduced into liquid iron that is tapped from the furnace hearth. Due to the extremely harsh environment inside the blast furnace, it is difficult to measure or observe internal phenomena during operation. Through the collaboration between steel companies and the Center for Innovation through Visualization and Simulation, multiple computational fluid dynamics (CFD) models have been developed to simulate the complex multiphase reacting flow in the three regions of the furnace, the shaft, the raceway, and the hearth. The models have been used effectively to troubleshoot and optimize blast furnace operations. In addition, the CFD models have been integrated with virtual reality. An interactive virtual blast furnace has been developed for training purpose. This paper summarizes the developments and applications of blast furnace CFD models and the virtual blast furnace.

International comparisons of energy efficiency in power, steel, and cement industries

International Nuclear Information System (INIS)

Oda, Junichiro; Akimoto, Keigo; Tomoda, Toshimasa; Nagashima, Miyuki; Wada, Kenichi; Sano, Fuminori

2012-01-01

Industrial energy efficiency is of paramount importance both for conserving energy resources and reducing CO 2 emissions. In this paper, we compare specific energy consumption among countries in fossil power generation, steel, and cement sectors. The evaluations were conducted using common system boundaries, allocation, and calculation methods. In addition, we disaggregate within sectors, such as with blast furnace–basic oxygen furnace (BF–BOF) steel and scrap-based electric arc furnace (Scrap-EAF) steel. The results reveal that characteristics vary by sub-sector. Regional differences in specific energy consumption are relatively large in the power, BF–BOF steel, and cement sectors. For coal power generation and BF–BOF steel production, continual maintenance and rehabilitation are of key importance. We confirm these key factors identified in the previous work on our estimated numerical values. In BF–BOF steel production, corrections for hot metal ratios (pig iron production per unit of BOF crude steel production) and quality of raw materials have a large effect on the apparent specific energy consumption. Available data is not yet sufficient for straightforward evaluation of the steel and cement sectors. - Highlights: ► We compare energy efficiency among countries in power, steel, and cement sectors. ► In steel and cement sectors, the results are provided in terms of specific energy consumption (GJ/ton of product). ► We distinguish BOF steel and EAF steel. ► New installation and continual maintenance are the key for energy efficiency. ► Corrections have a large impact on apparent specific energy consumption.

Furnace and Heat Recovery Area Design and Analysis for Conceptual Design of Supercritical O2-Based PC Boiler

International Nuclear Information System (INIS)

Andrew Seltzer

2006-01-01

The objective of the furnace and heat recovery area design and analysis task of the Conceptual Design of Supercritical Oxygen-Based PC Boiler study is to optimize the location and design of the furnace, burners, over-fire gas ports, and internal radiant surfaces. The furnace and heat recovery area were designed and analyzed using the FW-FIRE, Siemens, and HEATEX computer programs. The furnace is designed with opposed wall-firing burners and over-fire air ports. Water is circulated in the furnace by forced circulation to the waterwalls at the periphery and divisional wall panels within the furnace. Compared to the air-fired furnace, the oxygen-fired furnace requires only 65% of the surface area and 45% of the volume. Two oxygen-fired designs were simulated: (1) with cryogenic air separation unit (ASU) and (2) with oxygen ion transport membrane (OITM). The maximum wall heat flux in the oxygen-fired furnace is more than double that of the air-fired furnace due to the higher flame temperature and higher H 2 O and CO 2 concentrations. The coal burnout for the oxygen-fired case is 100% due to a 500 F higher furnace temperature and higher concentration of O 2 . Because of the higher furnace wall temperature of the oxygen-fired case compared to the air-fired case, furnace water wall material was upgraded from T2 to T92. Compared to the air-fired heat recovery area (HRA), the oxygen-fired HRA total heat transfer surface is 35% less for the cryogenic design and 13% less for the OITM design due to more heat being absorbed in the oxygen-fired furnace and the greater molecular weight of the oxygen-fired flue gas. The HRA tube materials and wall thickness are nearly the same for the air-fired and oxygen-fired design since the flue gas and water/steam temperature profiles encountered by the heat transfer banks are similar

Products of steel slags an opportunity to save natural resources.

Science.gov (United States)

Motz, H; Geiseler, J

2001-01-01

In Germany, and in the most industrial countries, the use of blast furnace and steel slags as an aggregate for civil engineering, for metallurgical use and as fertiliser has a very long tradition. Since the introduction of the basic oxygen steel making furnace (BOF) process and the electric arc furnace (EAF) process the German steel industry started extensive research on the development of fields of application for BOF and EAF slags. These investigations have been mainly performed by Forschungsgemeinschaft Eisenhüttenschlacken e. V. (FEhS), the Research Association for blast furnace and steel slags. Today steel slags are well characterised and long-term experienced materials mainly used as aggregates for road construction (e.g. asphaltic or unbound layers), as armour-stones for hydraulic engineering constructions (e.g. stabilisation of shores), and as fertiliser for agriculture purposes. These multifarious fields of application could only be achieved because the steelworks influence the quality of slags by a careful selection of raw materials and a suitable process route. Furthermore, subsequent procedures like a treatment of the liquid slag, an appropriate heat treatment and a suitable processing have been developed to ensure that the quality of steel slags is always adequate for the end use. Depending on the respective field of application, the suitability of steel slags has to be proven by determining the technical properties, as well as the environmental compatibility. For this reason test methods have been developed to evaluate the technical properties especially the volume stability and the environmental behaviour. To evaluate the volume stability a suitable test (steam test) has been developed and the results from laboratory tests were compared with the behaviour of steel slags under practical conditions, e.g. in a road. To determine the environmental behaviour leaching tests have been developed. In the meanwhile most of these test methods are drafted or

Fiscal 1999 survey report. Basic survey for promotion of joint implementations, etc. (Feasibility study of regenerative burner type heating furnaces for China's Shougang Corporation and Anshan Steel); 1999 nendo Chugoku shuto kotetsu Anshan kotetsu chikunetsu burner kanetsuro FS

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

Most of the steel heating furnaces now in operation in China are of the old type, consuming more than 40% more fuel than furnaces in general use for instance in Japan. In this survey, China's steel heating furnaces will be replaced by regenerative burners, developed in Japan recently and approaching practical application, for epoch-making enhancement of energy conservation and NOx reduction. Three plants are selected for study, which are the Shougang Corporation Plate Mill, the Qinhungdao Plate Mill, and the Anshan Steel Mill. Technical feasibility and economic profitability are studied for each of the projects for picking out projects that will link to CDM (clean development mechanism) in the future. In all the three mills, excellent energy conservation and economic profitability will result from technologically feasible introduction of regenerative burner heating furnaces. It is expected that their introduction will take place early enough. Full-scale diffusion of new furnaces will be dependent, however, on the progress of fuel gas cleaning study and China's assessment of the effects of energy conservation and environmental improvement. (NEDO)

Laboratory and gas-fired furnace performance tests of epoxy primers for intumescent coatings

DEFF Research Database (Denmark)

Nørgaard, Kristian Petersen; Dam-Johansen, Kim; Catala, Pere

2014-01-01

, either to ensure adhesion of the intumescent coating to the steel or to provide corrosion resistance. It is essential to document the performance of the intumescent coating together with the primer to ensure the overall quality of coating system. In the present work, two epoxy primers were used...... to a gas-fired furnace following the ISO834 fire curve (a so-called cellulosic fire), one of the primers selected performed well and the other poorly. From tests in the electrically heated oven, it was found that both primers were sensitive to the film thickness employed and the presence of oxygen....... At oxygen-rich conditions, higher primer thicknesses gave weaker performance. In addition, a color change from red to black was observed in nitrogen, while the color remained red in the oxygen-nitrogen mixture. In summary, the results suggest that an adequate choice of primer, primer thickness...

The change of steel surface chemistry regarding oxygen partial pressure and dew point

Science.gov (United States)

Norden, Martin; Blumenau, Marc; Wuttke, Thiemo; Peters, Klaus-Josef

2013-04-01

By investigating the surface state of a Ti-IF, TiNb-IF and a MnCr-DP after several series of intercritical annealing, the impact of the annealing gas composition on the selective oxidation process is discussed. On behalf of the presented results, it can be concluded that not the general oxygen partial pressure in the annealing furnace, which is a result of the equilibrium reaction of water and hydrogen, is the main driving force for the selective oxidation process. It is shown that the amounts of adsorbed gases at the strip surface and the effective oxygen partial pressure resulting from the adsorbed gases, which is mainly dependent on the water content of the annealing furnace, is driving the selective oxidation processes occurring during intercritical annealing. Thus it is concluded, that for industrial applications the dew point must be the key parameter value for process control.

Utilisation of steel furnace slag coarse aggregate in a low calcium fly ash geopolymer concrete

International Nuclear Information System (INIS)

Khan, M.S.H.; Castel, Arnaud; Akbarnezhad, A.; Foster, Stephen J.; Smith, Marc

2016-01-01

This paper evaluates the performance of steel furnace slag (SFS) coarse aggregate in blended slag and low calcium fly ash geopolymer concrete (GPC). The geopolymer binder is composed of 90% of low calcium fly ash and 10% of ground granulated blast furnace slag (GGBFS). Mechanical and physical properties, shrinkage, and detailed microstructure analysis were carried out. The results showed that geopolymer concrete with SFS aggregate offered higher compressive strength, surface resistivity and pulse velocity than that of GPC with traditional aggregate. The shrinkage results showed no expansion or swelling due to delayed calcium oxide (CaO) hydration after 320 days. No traditional porous interfacial transition zone (ITZ) was detected using scanning electron microscopy, indicating a better bond between SFS aggregate and geopolymer matrix. Energy dispersive spectroscopy results further revealed calcium (Ca) diffusion at the vicinity of ITZ. Raman spectroscopy results showed no new crystalline phase formed due to Ca diffusion. X-ray fluorescence result showed Mg diffusion from SFS aggregate towards geopolymer matrix. The incorporation of Ca and Mg into the geopolymer structure and better bond between SFS aggregate and geopolymer matrix are the most likely reasons for the higher compressive strength observed in GPC with SFS aggregate.

Corrosion behavior of steels in liquid lead bismuth with low oxygen concentrations

Science.gov (United States)

Kurata, Yuji; Futakawa, Masatoshi; Saito, Shigeru

2008-02-01

Corrosion tests in pots were conducted to elucidate corrosion behavior of various steels in liquid lead-bismuth for 3000 h under the condition of an oxygen concentration of 5 × 10 -8 wt% at 450 °C and an oxygen concentration of 3 × 10 -9 wt% at 550 °C, respectively. Significant corrosion was not observed at 450 °C for ferritic/martensitic steels, F82H, Mod.9Cr-1Mo steel, 410SS, 430SS except 2.25Cr-1Mo steel. Pb-Bi penetration into steels and dissolution of elements into Pb-Bi were severe at 550 °C even for ferritic/martensitic steels. Typical dissolution attack occurred for pure iron both at 550 °C without surface Fe 3O 4 and at 450 °C with a thin Fe 3O 4 film. Ferritization due to dissolution of Ni and Cr, and Pb-Bi penetration were recognized for austenitic stainless steels, 316SS and 14Cr-16Ni-2Mo steel at both temperatures of 450 °C and 550 °C. The phenomena were mitigated for 18Cr-20Ni-5Si steel. In some cases oxide films could not be a corrosion barrier in liquid lead-bismuth.

Statistical model for predicting correct amount of deoxidizer of Al-killed grade casted at slab continuous caster of Pakistan steel

International Nuclear Information System (INIS)

Siddiqui, A.R.; Khan, M.M.A.; Ismail, B.M.

1999-01-01

Oxygen is blown in Converter process to oxidize hot metal. This introduces dissolved oxygen in the metal, which may cause embrittlement, voids, inclusion and other undesirable properties in steel. The steel bath at the time of tapping contains 400 to 800 ppm oxygen. Deoxidation is carried out during tapping by adding into the tap ladle appropriate amounts of ferromanganese, ferrosilicon and/or aluminum or other special deoxidizers. In the research aluminum killed grade steel which are casted at the slab caster of Pakistan Steel were investigated. Amount of aluminum added is very critical because if we add lesser amount of aluminum then the required quantity then there will be an incomplete killing of oxygen which results uncleanness in steel. Addition of larger amount of aluminum not only increases the cost of the production but also results as higher amount of alumina, which results in nozzle clogging and increase, loses. The purpose of the research is to develop a statistical model which would predict correct amount of aluminum addition for complete deoxidation of aluminum killed grade casted at slab continuous caster of Pakistan Steel. In the model aluminum added is taken as dependent variable while tapping temperature, turn down carbon composition, turndown manganese composition and oxygen content in steel would be the independent variable. This work is based on operational practice on 130 tons Basic Oxygen furnace. (author)

Characterization Of Oxide Layers Produced On The AISI 321 Stainless Steel After Annealing

Directory of Open Access Journals (Sweden)

Bochnowski W.

2015-09-01

Full Text Available In this study, the structure, chemical composition and topography of oxide layers produced on the surface of the AISI 321 austenitic steel in the annealing process were analyzed. Heat treatment was done at 980°C temperature for 1 hour time in different conditions. The annealing was done in a ceramic furnace in oxidation atmosphere and in vacuum furnaces with cylindrical molybdenum and graphite chambers. The analysis was carried out using the following methods: a scanning electron microscope (SEM equipped with an energy-dispersive X-ray spectrometer (EDX, a transmission electron microscope (TEM equipped with an energy-dispersive X-ray spectrometer (EDX, an X-ray diffractometer (XRD, a secondary ion mass spectrometer with time-of-flight mass analyzer (TOF SIMS and an atomic force microscope (AFM. The oxide layer formed during annealing of the AISI 321 steel at 980°C consisted of sub-layers, diversified in the chemical composition. The thickness of the oxidized layer is depended on the annealing conditions. In a ceramic furnace in oxidation atmosphere, the thickness of the oxide layer was of 300-500 nm, in a vacuum furnace with molybdenum and graphite heating chambers, it ranged from 40 to 300 nm and from a few to 50 nm, respectively. TOF SIMS method allows to get average (for the surface of 100 μm × 100 μm depth profiles of concentration of particular elements and elements combined with oxygen. In oxide layers formed in vacuum furnaces there are no iron oxides. Titanium, apart from being bounded with carbon in carbides, is a component of the oxide layer formed on the surface of the AISI 321 steel.

An update on blast furnace granular coal injection

Energy Technology Data Exchange (ETDEWEB)

Hill, D.G. [Bethlehem Steel Corp., Burns Harbor, IN (United States); Strayer, T.J.; Bouman, R.W. [Bethlehem Steel Corp., PA (United States)

1997-12-31

A blast furnace coal injection system has been constructed and is being used on the furnace at the Burns Harbor Division of Bethlehem Steel. The injection system was designed to deliver both granular (coarse) and pulverized (fine) coal. Construction was completed on schedule in early 1995. Coal injection rates on the two Burns Harbor furnaces were increased throughout 1995 and was over 200 lbs/ton on C furnace in September. The injection rate on C furnace reached 270 lbs/ton by mid-1996. A comparison of high volatile and low volatile coals as injectants shows that low volatile coal replaces more coke and results in a better blast furnace operation. The replacement ratio with low volatile coal is 0.96 lbs coke per pound of coal. A major conclusion of the work to date is that granular coal injection performs very well in large blast furnaces. Future testing will include a processed sub-bituminous coal, a high ash coal and a direct comparison of granular versus pulverized coal injection.

Advances in chemical and physical properties of electric arc furnace carbon steel slag by hot stage processing and mineral mixing

International Nuclear Information System (INIS)

Liapis, Ioannis; Papayianni, Ioanna

2015-01-01

Highlights: • Addition of 10% perlite decreases specific weight of the slag by approx. 7.5%. • Slag-crucible interaction and thin coating layer result in variations in XRF. • XRD shows high glass content and smaller crystalline sizes due to rapid cooling. • SEM shows higher homogeneity and lower crystallisation for SiO 2 /CaO-rich samples. • Physical properties (LA, PSV, AAV) of modified slag show limited deterioration. - Abstract: Slags are recognised as a highly efficient, cost effective tool in the metal processing industry, by minimising heat losses, reducing metal oxidation through contact with air, removing metal impurities and protecting refractories and graphite electrodes. When compared to natural aggregates for use in the construction industry, slags have higher specific weight that acts as an economic deterrent. A method of altering the specific weight of EAFC slag by hot stage processing and mineral mixing, during steel production is presented in this article. The method has minimal interference with the production process of steel, even by limited additions of appropriate minerals at high temperatures. Five minerals are examined, namely perlite, ladle furnace slag, bauxite, diatomite and olivine. Measurements of specific weight are accompanied by X-ray diffraction (XRD) and fluorescence (XRF) analysis and scanning electron microscopy spectral images. It is also shown how altering the chemical composition is expected to affect the furnace refractory lining. Additionally, the process has been repeated for the most suitable mix in gas furnace and physical properties (FI, SI, LA, PSV, AAV, volume stability) examined. Alteration of the specific weight can result in tailoring slag properties for specific applications in the construction sector

Advances in chemical and physical properties of electric arc furnace carbon steel slag by hot stage processing and mineral mixing

Energy Technology Data Exchange (ETDEWEB)

Liapis, Ioannis, E-mail: iliapis@sidenor.vionet.gr [AEIFOROS SA, 12th km Thessaloniki-Veroia Rd, PO Box 59, 57008 Ionia, Thessaloniki (Greece); Papayianni, Ioanna [Laboratory of Building Materials, Department of Civil Engineering, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece)

2015-02-11

Highlights: • Addition of 10% perlite decreases specific weight of the slag by approx. 7.5%. • Slag-crucible interaction and thin coating layer result in variations in XRF. • XRD shows high glass content and smaller crystalline sizes due to rapid cooling. • SEM shows higher homogeneity and lower crystallisation for SiO{sub 2}/CaO-rich samples. • Physical properties (LA, PSV, AAV) of modified slag show limited deterioration. - Abstract: Slags are recognised as a highly efficient, cost effective tool in the metal processing industry, by minimising heat losses, reducing metal oxidation through contact with air, removing metal impurities and protecting refractories and graphite electrodes. When compared to natural aggregates for use in the construction industry, slags have higher specific weight that acts as an economic deterrent. A method of altering the specific weight of EAFC slag by hot stage processing and mineral mixing, during steel production is presented in this article. The method has minimal interference with the production process of steel, even by limited additions of appropriate minerals at high temperatures. Five minerals are examined, namely perlite, ladle furnace slag, bauxite, diatomite and olivine. Measurements of specific weight are accompanied by X-ray diffraction (XRD) and fluorescence (XRF) analysis and scanning electron microscopy spectral images. It is also shown how altering the chemical composition is expected to affect the furnace refractory lining. Additionally, the process has been repeated for the most suitable mix in gas furnace and physical properties (FI, SI, LA, PSV, AAV, volume stability) examined. Alteration of the specific weight can result in tailoring slag properties for specific applications in the construction sector.

Lowcost automated control for steel heat treatments

International Nuclear Information System (INIS)

Zambaldi, Edimilson; Magalhães, Ricardo R.; Barbosa, Bruno H.G.; Silva, Sandro P. da; Ferreira, Danton D.

2017-01-01

Highlights: • Control the furnace temperature measured by thermocouple and adjusts it. • Activating the furnace resistors through Pulse Width Modulation. • Appling heat treatments to steels by a low-cost controller. - Abstract: The aim of this paper is to propose a low cost, automated furnace control system for the heat treatment of steel. We used an open source electronic prototyping platform to control the furnace temperature, thus reducing human interaction during the heat process. The platform can be adapted to non-controlled commercial furnaces, which are often used by small businesses. A Proportional-Integral-Derivative (PID) controller was implemented to regulate the furnace temperature based on a defined heat treatment cycle. The embedded system activates the furnace resistors through Pulse Width Modulation (PWM), allowing for control of electrical power supplied to the furnace. Hardening and tempering were performed on standard steel samples using a traditional method (visual inspection without temperature control) as well the embedded system with PID feedback control. The results show that the proposed system can reproduce an arbitrary heat treatment curve with accuracy and provide the desired final hardness as inferred through metallographic analysis. In addition, we observed a 6% saving in energy consumption using the proposed control system. Furthermore, the estimated cost to implement the system is 42% lower than a commercial controller model implemented in commercial furnaces.

Influence of Atomic Oxygen Exposure on Friction Behavior of 321 Stainless Steel

Science.gov (United States)

Liu, Y.; Yang, J.; Ye, Z.; Dong, S.; Zhang, L.; Zhang, Z.

Atomic oxygen (AO) exposure testing has been conducted on a 321 stainless steel rolled 1 mm thick sheet to simulate the effect of AO environment on steel in low Earth orbit (LEO). An atomic oxygen exposure facility was employed to carry out AO experiments with the fluence up to ~1021 atom/cm2. The AO exposed specimens were evaluated in air at room temperature using a nanoindenter and a tribological system. The exposed surfaces were analyzed usign XPS technique.

Fluxless furnace brazing and its theoretical fundamentals

International Nuclear Information System (INIS)

Lison, R.

1979-01-01

In this paper the theoretical fundamental of fluxless furnace brazing are described. The necessary conditions for a wetting in the vacuum, under a inert-gas and with a reducing gas are discussed. Also other methods to reduce the oxygen partial pressure are described. Some applications of fluxless furnace brazing are outlined. (orig.) [de

Application of roof radiant burners in large pusher-type furnaces

Directory of Open Access Journals (Sweden)

A. Varga

2009-07-01

Full Text Available The paper deals with the application of roof flat-flame burners in the pusher-type steel slab reheating furnaces, after furnace reconstruction and replacement of conventional torch burners, with the objective to increase the efficiency of radiative heat transfer from the refractory roof to the charge. Based on observations and on measurements of the construction and process parameters under operating conditions, the advantages and disadvantages of indirectly oriented radiant heat transfer are analysed in relation to the heat transfer in classically fired furnaces.

Elements of the electric arc furnace's environmental management

Science.gov (United States)

Ioana, Adrian; Semenescu, Augustin; Costoiu, Mihnea; Marcu, Dragoş

2017-12-01

The paper presents a theoretical and experimental analysis of the polluting generating mechanisms for steel making in the Electric Arc Furnaces (EAF). The scheme for the environment's polluting system through the EAF is designed and presented in this paper. The ecological experimenting consisted of determining by specialized measures of the dust percentage in the evacuated gases from the EAF and of thereof gas pollutants. From the point of view of reducing the impact on the environment, the main problem of the electric arc furnace (EAF) is the optimization of the powder collecting from the process gases, both from the furnace and from the work-area. The paper deals with the best dependence between the aggregate's constructive, functional and technological factors, which are necessary for the furnace's ecologization and for its energetically-technologically performances increasing.

Corrosion resistant steel

International Nuclear Information System (INIS)

Zubchenko, A.S.; Borisov, V.P.; Latyshev, V.B.

1980-01-01

Corrosion resistant steel for production of sheets and tubes containing C, Mn, Cr, Si, Fe is suggested. It is alloyed with vanadium and cerium for improving tensile properties and ductility. The steel can be melted by a conventional method in electric-arc or induction furnaces. The mentioned steel is intended to be used as a substitute for nickel-bearing austenitic steels

Basic investigation on promotion of joint implementation in fiscal 2000. Energy saving projects at two steel making companies in Fushun City in China; 2000 nendo kyodo jisshi nado suishin kiso chosa hokokusho. Chugoku Fushun shi ni okeru tekko gaisha 2 sha no shoene project chosa hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

With an objective of saving energy and reducing greenhouse gas emission, investigations and discussions were given on two steel making companies in China. Discussions were given for Fushun Special Steel Co., Ltd. on abolishment and unification of four electric furnaces into two new electric furnaces, and for Fushun New Steel Co., Ltd. on installation of a granulation reinforcing facility, a segregation reinforcing device, and cooler waste heat recovery boilers for the sintering machine, installation of sensors including the waste gas oxygen concentration meter, adoption of a process computer, and optimization of the furnace temperature patterns for the heating furnace. As a result of the discussions, it was revealed that the unit requirement for electric power used at Fushun Special Steel can be reduced largely, and so can the fuel used at Fushun New Steel. The annual energy saving effect would be about 500 million yen relative to the investment amount of 2.8 billion yen at Fushun Special Steel, and about 400 million yen relative to the investment amount of about 400 million yen at Fushun New Steel. The greenhouse gas emission would be reduced annually by 40,000 t-CO2 and 60,000 t-CO2 respectively. Fushun Special Steel will execute an international bid in May this year. (NEDO)

Feasibility and economic analysis of solid desiccant wheel used for dehumidification and preheating in blast furnace: A case study of steel plant, Nanjing, China

International Nuclear Information System (INIS)

Guan, Yipeng; Zhang, Yufeng; Sheng, Ying; Kong, Xiangrui; Du, Song

2015-01-01

To overcome the shortcomings of huge energy consumption from conventional dehumidification using lithium bromide adsorption refrigerating (LBARD) system, a novel desiccant wheel dehumidification and preheating (DWDP) system using two-stage desiccant wheel for blast furnace is brought forward. The DWDP system was designed for dehumidification and preheating in blast furnace of steel plant. It takes waste heat in the slag flushing water as desiccant regeneration and preheating energy. To validate the feasibility of the new DWDP system, experimental studies were conducted based on a steel plant in Nanjing, China. The experiment was designed to use DWDP system in humid outdoor climates e.g. summer seasons. The experimental results indicate that the moisture removal capacity of DWDP system can reach 8.7 g/kg which will lead to the improvement of steel production by 0.9% and the coal is saved of about 2100 tons per year. With the DWDP system, the energy consumed by cooling tower of slag flushing water can decrease 7.3%. All of these energy saved equates to 10.3 million CNY annually. A comparison of initial investment and operating cost between DWDP system and LBRAD system was then carried out. The results show that the initial investment and operating cost of DWDP system is 37% and 57% of present LBARD system, and the payback period is shortened 66%. - Highlights: • A novel two-stage desiccant wheel dehumidification system for blast furnace is proposed. • Average moisture removal of 8.7 g/kg is achieved and dehumidification efficiency is 47%. • Outlet humidity ratio is less than 10 g/kg that satisfies the requirement of blast air. • Waste heat in slag flushing water is utilized and 61.4 million kJ is saved annually. • The investment and operating cost is 37% and 57% of former dehumidification system

Energy efficiency and emissions of arc furnaces in the steel industry; Energieeffizienz und Emissionen der Lichtbogenoefen in der Stahlindustrie

Energy Technology Data Exchange (ETDEWEB)

Kirschen, M.

2007-07-01

The operation of the electric arc furnace obeys economic constraints that require cost optimal use of the resources scrap, scrap substitutes, alloys, direct reduced iron, pig iron, oxygen, fuel gas, and energy. On the other hand, legal restrictions for minimum emissions must be observed. Comprehensive process models and strategies to optimize the EAF steel production require detailed knowledge about both energy flow rates and emissions. However, this data is often not available in the meltshop due to technical problems or high effort for maintenance of on-line off-gas analysis systems at the EAF. The Institute for Industrial Furnaces and Heat Engineering of RWTH Aachen University performed off-gas measurements at various EAFs during steel production. In some plant trials off-gas measurements were conducted simultaneously at two points in the dedusting system in order to determine the otherwise unknown volume flow rate of air at the gap between the EAF elbow and the hot gas duct. In this work, state-of-the-art off-gas analysis systems are presented. First hints for process development of particular EAFs are derived from off-gas data. Off-gas data complement the meltshop data, that are required for complete mass and energy balances. From recent energy balances, the EAF process is evaluated with respect to off-gas energy and energy efficiency. Recent energy balances from our measurements and from the literature of the last decade show total energy demand between 600 kWh/t and 850 kWh/t and energy efficiency values up to 70%. EAFs with scrap pre-heating technologies achieve highest energy efficiency values up to 70%. Measurements of off-gas and air volume flow rates monitor the efficiency of the EAF dedusting plant in combination with the EAF. With direct exhaust control based on furnace pressure measurement, the specific off-gas mass and energy is decreased significantly. Improvement of the analysis equipment for off-gas measurements at the EAF with focus on very

Characterization of airborne and bulk particulate from iron and steel manufacturing facilities.

Science.gov (United States)

Machemer, Steven D

2004-01-15

Characterization of airborne and bulk particulate material from iron and steel manufacturing facilities, commonly referred to as kish, indicated graphite flakes and graphite flakes associated with spherical iron oxide particles were unique particle characteristics useful in identifying particle emissions from iron and steel manufacturing. Characterization of airborne particulate material collected in receptor areas was consistent with multiple atmospheric release events of kish particles from the local iron and steel facilities into neighboring residential areas. Kish particles deposited in nearby residential areas included an abundance of graphite flakes, tens of micrometers to millimeters in size, and spherical iron oxide particles, submicrometer to tens of micrometers in size. Bulk kish from local iron and steel facilities contained an abundance of similar particles. Approximately 60% of blast furnace kish by volume consisted of spherical iron oxide particles in the respirable size range. Basic oxygen furnace kish contained percent levels of strongly alkaline components such as calcium hydroxide. In addition, concentrations of respirable Mn in airborne particulate in residential areas and at local iron and steel facilities were approximately 1.6 and 53 times the inhalation reference concentration of 0.05 microg/m3 for chronic inhalation exposure of Mn, respectively. Thus, airborne release of kish may pose potential respirable particulate, corrosive, or toxic hazards for human health and/or a corrosive hazard for property and the environment.

Study of non-metallic inclusion sources in steel

International Nuclear Information System (INIS)

Khons, Ya.; Mrazek, L.

1976-01-01

A study of potential inclusion sources was carried out at the Tvinec steel plant using an unified labelling procedure for different sources. A lanthanum oxide labelling method has been used for refractories with the subsequent La determination in steel by the neutron activation analysis. Samarium and cerium oxides and the 141 Ce radionuclide have been used in conjunction with the testing. The following sources of exogenous inclusions have been studied: 1)Refractory material comprising fireclay and corundum for steel-teeming trough in open-heart furnaces; 2) Fireclay bottom-pouring refractories; 3) Steel-teeming laddle lining; 4) Heat-insulating and exothermic compounds for steel ingots; 5) Vacuum treatment plant lining; 6) Open-hearth and electric arc furnace slag. The major oxide inclusion source in steel was found to be represented by the furnace slag, since it forms about 40 p.c. of all oxide inclusions. The contributions of the remaining sources did not exceede 5 p.c. each

Effect of the oxygen partial pressure on ferritic stainless steel AISI 441 at high temperatures

International Nuclear Information System (INIS)

Salgado, M.F.; Carvalho, I.S.; Santos, R.S.; Correa, O.V.; Ramanathan, L.V.

2014-01-01

Stainless steels can be exposed to aggressive gases at high temperatures. To understand the behavior of oxidation of the steel AISI 441 was made oxidation at temperatures between 850 ° C and 950 ° C, at two different atmospheres: synthetic air, using tubular furnace and Argon, containing 1ppm O_2, in thermobalance. The kinetics of oxidation of the films was established by measuring the mass gain per unit of area as a function of the oxidation time. The microstructure and chemical composition of the oxides were analyzed by SEM, EDS and XRD. Chemical analysis showed that films formed on steel AISI 441 had mostly chromium oxide and the following elements: Cr, Mn, Fe, Ti and Si. Regarding the kinetics of oxidation, it was observed that in synthetic air, the steel oxidation increased gradually with the temperature, but in argon, it showed the highest oxidation at 900 ° C and the lowest oxidation at 950 ° C. (author)

FY 1999 report on feasibility study of introduction of regenerative burner type furnaces into Shougang Corporation and Anshan Iron and Steel Group Company in China

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

This fiscal 1999 survey is to link to COP3 (Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change)joint implementations in the future. The regenerative burner type furnace is a new technology which is the fruit of one of Japan's national projects developed and put to practical use in the period fiscal 1993-1999. It reduces energy consumption and NOx emissions. The technology is separately applied to steel rollers at Shougang and Qinhungdao and to a new steel roller at Anshan. Their annual yields will be 550-thousand, 450-thousand, and 800-thousand tons, respectively. The amounts of annually conserved energy will be 159,500, 54,000, and 40,000 times 10{sup 6}kcal, respectively. Annual CO2 reduction rates are indicated to be 51, 26, 15%, and NOx reduction rates to be 82, 75, 74%. The amounts of initial investment are expected to be 800-million yen (furnace refurbishment), 250-million yen (burner improvement), and 150-million yen (additional construction of a new furnace). Investment recovery periods are calculated to be 3.3, 2.0, and 2.8 years. ROIs (returns on investment) are calculated to be 34, 54, and 40%. The project is economically feasible, with high profitability available at the present stage and in the future (with some problems to solve at Anshan). (NEDO)

Optical emission from a small scale model electric arc furnace in 250-600 nm region.

Science.gov (United States)

Mäkinen, A; Niskanen, J; Tikkala, H; Aksela, H

2013-04-01

Optical emission spectroscopy has been for long proposed for monitoring and studying industrial steel making processes. Whereas the radiative decay of thermal excitations is always taking place in high temperatures needed in steel production, one of the most promising environment for such studies are electric arc furnaces, creating plasma in excited electronic states that relax with intense characteristic emission in the optical regime. Unfortunately, large industrial scale electric arc furnaces also present a challenging environment for optical emission studies and application of the method is not straightforward. To study the usability of optical emission spectroscopy in real electric arc furnaces, we have developed a laboratory scale DC electric arc furnace presented in this paper. With the setup, optical emission spectra of Fe, Cr, Cr2O3, Ni, SiO2, Al2O3, CaO, and MgO were recorded in the wavelength range 250-600 nm and the results were analyzed with the help of reference data. The work demonstrates that using characteristic optical emission, obtaining in situ chemical information from oscillating plasma of electric arc furnaces is indeed possible. In spite of complications, the method could possibly be applied to industrial scale steel making process in order to improve its efficiency.

78 FR 19801 - 2013 Revisions to the Greenhouse Gas Reporting Rule and Proposed Confidentiality Determinations...

Science.gov (United States)

2013-04-02

... steel mills, steel companies, sinter plants, blast furnaces, basic oxygen process furnace shops. Lead...\\ IPCC Fourth Assessment Report (AR4), 2007. Climate Change 2007: The Physical Science Basis...

CoJet technology for oxygen injection injection in EAFS - industrial gases supply and customers productivity improvements; Tecnologia CoJet para injecao de oxigenio em FEAS - fornecimento de gases e aumento da produtividade dos clientes

Energy Technology Data Exchange (ETDEWEB)

Marques, Izaias Lucas; Zagury, Pedro Athias [White Martins Gases Industriais Ltda., Rio de Janeiro, RJ (Brazil)

2010-07-01

PRAXAIR is one of the largest industrial gases producers of the World, being present in more than 40 countries and strongly connected to the steel industry. PRAXAIR has experience to supply products and services to all kinds of steel mills. Several technologies developed by the Company, such as CoJet (a system to coherent oxygen jet injection in EAF and BOF furnaces), Slag Splashing (splashing slag to cover BOF furnaces walls increasing refractory wear campaign life), AOD (a process for specialty steel production) and others, are currently in commercial operation in different parts of the world. In Brazil, Praxair is the owner of White Martins, the largest industrial gases company in South America, present in nine countries of the continent. Company's portfolio includes atmospheric gases, carbonic gas production, acetylene, hydrogen, specialty and health and care gases, mixtures for welding, gas seamless steel cylinders, applications equipment, and storage and gases transportation. The Company also operates a natural gas liquefaction unit. In addition to technologies and process, Praxair / White Martins can also supply solutions for measurement, control and gases injection, according to strict safety and quality standards. The present work has the objective to show the benefits of the CoJet EAF System, oxygen injectors positioned in the furnace walls. In 2009, two systems have been installed in South American mills and the results achieved will be following discussed. (author)

Extracts from Kang-T'ieh (Steel), Issue Number 10 - Communist China

National Research Council Canada - National Science Library

1960-01-01

.... Big Drop in Pig Iron Consumption for converter steel production, 3. Surpass the Open-Hearth Furnace, Catch up with the electric furnace and struggle for high quality and varieties of products in converter steel production, 4...

Operation Indicators of the Rotating-Hearth Furnace in Restrictive Manufacturing Conditions

Directory of Open Access Journals (Sweden)

Črnko, J.

2007-01-01

Full Text Available The heating operation of the rotating-hearth furnace involving semi-finished steel products was analysed, and specific heat consumption was determined as a function of furnace productivity. The aim was to find out how a change in productivity, which is not accompanied by a modification of the thermal regime, can affect the heating quality and surface oxidation of products.

Quality of austenite chrome-nickel steel made by gas-oxygen refining

International Nuclear Information System (INIS)

Fel'dgandler, Eh.G.; Levin, F.L.; Moshkevich, E.A.; Shifrin, Eh.V.; Movshovich, V.S.; Pargamonov, E.A.

1991-01-01

Properties and structure were investigated of austenitic 03Kh18N11 and 08KhN10T steels melted at gas oxygen refining aggregates. It was established that mechanical and corrosion properties of rolling of such steels were in agreement with standard properties of metal of open melting. Sheet 08Kh18N10T steel has the level of strength and plasticity regulated for 12Kh18N10T steel. As steel of 08Kh18N10T holds the complex of high mechanical and corrosion properties, 08Kh18N10T is recommended to be replace by 12Kh18N10T with the aim of decrease of titanium usage and increase of process efficiency

Energy use in the U.S. steel industry: a historical perspective and future opportunities

Energy Technology Data Exchange (ETDEWEB)

Stubbles, John

2000-09-01

The U.S. steel industry has taken enormous strides over the past decades to reduce its energy consumption; since the end of World War II, the industry has reduced its energy intensity (energy use per shipped ton) by 60 percent. Between 1990 and 1998 alone, intensity has dropped from 20 to 18 million Btu (MBtu) per ton. This figure is projected to decrease to 15 MBtu/ton by 2010 with an asymptotic trend towards 14 MBtu/ton. Domestic shipments are projected to flatten out over the next decade to around 105 million tons which means that total energy consumption will also decrease. Historically, the steel industry has accounted for about 6 percent of U.S. energy consumption. Today, that figure is less than 2 percent and will decrease further to 1.5 percent by 2010. The primary causes for the decrease in energy consumption since WWII are: The use of pellets in the blast furnace and the application of new technology in the ironmaking process to further reduce fuel rates per net ton of hot metal (NTHM); The total replacement of the open hearth process by basic oxygen and electric furnaces; The almost total replacement of ingot casting by continuous casting (which improved yield dramatically and thus reduced the tons of raw steel required per ton of shipments); and The growth of the electric furnace sector of the industry at the expense of hot metal-based processes (which has also stimulated scrap recycling so that about 55 percent of ''new'' steel is now melted from scrap steel). This report focuses on the concept of good practices (i.e., those that are sustainable and can use today's technology). If all the industry could operate on this basis, the additional savings per ton could total 2 MBtu, As further restructuring occurs and the swing from hot metal-based to electric furnace-based production continues, the average consumption will approach the good practice energy per ton. Further savings will accrue through new technology, particularly in

Predictive control of thermal state of blast furnace

Science.gov (United States)

Barbasova, T. A.; Filimonova, A. A.

2018-05-01

The work describes the structure of the model for predictive control of the thermal state of a blast furnace. The proposed model contains the following input parameters: coke rate; theoretical combustion temperature, comprising: natural gas consumption, blasting temperature, humidity, oxygen, blast furnace cooling water; blast furnace gas utilization rate. The output parameter is the cast iron temperature. The results for determining the cast iron temperature were obtained following the identification using the Hammerstein-Wiener model. The result of solving the cast iron temperature stabilization problem was provided for the calculated values of process parameters of the target area of the respective blast furnace operation mode.

Optimization of a slab heating pattern for minimum energy consumption in a walking-beam type reheating furnace

International Nuclear Information System (INIS)

Jang, Jiin-Yuh; Huang, Jun-Bo

2015-01-01

A two-dimensional mathematical heat transfer model for the prediction of the temperature history of steel slabs was performed in order to obtain the optimal heating pattern of these slabs with minimum energy consumption in a walking-beam type reheating furnace. An algorithm developed with a simplified conjugated-gradient method combined with a shooting method, was used as an optimizer to design the furnace temperature distribution, including the preheating zone, heating zone and soaking zone temperatures. Comparison with the in-situ experimental data indicated that the present heat transfer model works well for the prediction of the thermal behavior of a slab in the reheating furnace. The effect of the furnace temperature distribution on the design requirements, such as energy required for heating a slab, slab temperature uniformity at the furnace exit and slab discharging temperature, were investigated. The parametric study results indicated that energy consumption significantly decreases with reductions in the preheating zone temperature. The optimal design also resulted in lower energy consumption for heating a slab as compared to the original operational conditions in the steel plant. - Highlights: • The heating process of steel slabs in a reheating furnace is numerically simulated. • An algorithm is developed to search for the optimal heating pattern of a slab. • Energy consumption decreases with reductions in the preheating zone temperature

Energy use in the U.S. steel industry: a historical perspective and future opportunities; TOPICAL

International Nuclear Information System (INIS)

Stubbles, John

2000-01-01

The U.S. steel industry has taken enormous strides over the past decades to reduce its energy consumption; since the end of World War II, the industry has reduced its energy intensity (energy use per shipped ton) by 60 percent. Between 1990 and 1998 alone, intensity has dropped from 20 to 18 million Btu (MBtu) per ton. This figure is projected to decrease to 15 MBtu/ton by 2010 with an asymptotic trend towards 14 MBtu/ton. Domestic shipments are projected to flatten out over the next decade to around 105 million tons which means that total energy consumption will also decrease. Historically, the steel industry has accounted for about 6 percent of U.S. energy consumption. Today, that figure is less than 2 percent and will decrease further to 1.5 percent by 2010. The primary causes for the decrease in energy consumption since WWII are: The use of pellets in the blast furnace and the application of new technology in the ironmaking process to further reduce fuel rates per net ton of hot metal (NTHM); The total replacement of the open hearth process by basic oxygen and electric furnaces; The almost total replacement of ingot casting by continuous casting (which improved yield dramatically and thus reduced the tons of raw steel required per ton of shipments); and The growth of the electric furnace sector of the industry at the expense of hot metal-based processes (which has also stimulated scrap recycling so that about 55 percent of ''new'' steel is now melted from scrap steel). This report focuses on the concept of good practices (i.e., those that are sustainable and can use today's technology). If all the industry could operate on this basis, the additional savings per ton could total 2 MBtu, As further restructuring occurs and the swing from hot metal-based to electric furnace-based production continues, the average consumption will approach the good practice energy per ton. Further savings will accrue through new technology, particularly in the areas of reduced blast

The Automation Control System Design of Walking Beam Heating Furnace

OpenAIRE

Hong-Yu LIU; Jun-Qing LIU; Jun-Jie XI

2014-01-01

Combining the transformation project of certain strip steel rolling production line, the techniques process of walking beam heating furnace was elaborated in this paper. The practical application of LOS-T18-2ZC1 laser detector was elaborated. The network communication model of walking beam heating furnace control system was designed. The realization method of production process automation control was elaborated. The entire automation control system allocation picture and PLC power distributio...

Influence of direct reduced iron on the energy balance of the electric arc furnace in steel industry

International Nuclear Information System (INIS)

Kirschen, Marcus; Badr, Karim; Pfeifer, Herbert

2011-01-01

A model of the EAF energy efficiency was developed based on a closed mass and energy balance of the EAF melting process. This model was applied to industrial EAFs in steel industry charged with scrap or with mixes of scrap and DRI. Complex mass and energy conversion in the EAF was simplified with the introduction of mass and energy conversion efficiencies for the conversion of oxygen and the energy conversion of electrical energy in the electric arcs, chemical energy from the oxidation reactions in the melt and energy from the combustion of burner gas. It turned out that close agreement with observed process parameters from 16 EAFs is obtained by slight variations of the efficiency values. Especially the sensitivity of the steel temperature from the energy conversion efficiency of the electric arc energy indicates the importance of efficient foaming slag operation in EAF steel making. Characteristics and process parameters of DRI charged EAFs are discussed. Model results for a series of case studies illustrate the correlations between DRI chemical composition, DRI portion, oxygen consumption, etc. with electrical energy demand in order to indentify cost-effective EAF process conditions. -- Highlights: → Energy demand and carbon dioxide emission figures of EAF steelmaking processes based on steel scrap and DRI. → Complete energy balance of the EAF process using various input materials. → Application of the model to industrial EAF in steel industry in 4 case studies and discussion of model results. → Comparison with other models, critical discussion.

Bioreducer use in blast furnace ironmaking in Finland:techno-economic assessment and CO₂ emission reduction potential

OpenAIRE

Suopajärvi, H. (Hannu)

2015-01-01

Abstract Most of the steel produced in the world is based on the integrated blast furnace-converter route, which is based on the use of virgin raw materials. Large amounts of fossil-based, carbon containing reductants are used in blast furnaces, which results in carbon dioxide emissions into the atmosphere. Fossil carbon dioxide emissions from steel production can be reduced by new technologies or moving from non-renewable to renewable energy sources. Biomass-based reductants could be one...

Analysis of ferritic stainless steel tube applied in radiation furnaces; Analise de tubos de aco inoxidavel ferritico para aplicacao em fornos de radiacao

Energy Technology Data Exchange (ETDEWEB)

Porto, P.C.R.; Spim, J.A. [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Centro de Tecnologia. Lab. de Fundicao], e-mail: spim@ufrgs.br; Santos, C.A. [Pontificia Universidade Catolica do Rio Grande do Sul (PUC-RS), Porto Alegre, RS (Brazil). Fac. de Engenharia. Programa de Pos-Graduacao em Engenharia e Tecnologia de Materiais (PGETEMA)

2006-07-01

The objective of this work was to evaluate the change in mechanic properties and phase transformations of ferritic stainless steel tube, ASTM 268 Gr 446, applied in high temperature conditions. The work has used tubes from radiation furnaces of the PETROBRAS Xisto Industrialization Unit. The samples used for comparison were obtained from new tubes and tubes already used in furnaces. The test analyses were optical metallography, scanning electron microscopy, energy dispersive spectrometer, hardness and microhardness test and tension test. Results have shown that the new tubes presented a ferritic matrix and in old tubes were observed a great quantity of sigma phase and carbides. Along with the thickness of the tubes it was verified that the inside region presented an increase of sulfate and the outside region an increase of carbides. (author)

Laser-oxygen cutting of mild steel: the thermodynamics of the oxidation reaction

Energy Technology Data Exchange (ETDEWEB)

Powell, J; Kaplan, A F H [Department of Applied Physics and Mechanical Engineering, Luleaa University of Technology, SE-971 87 Luleaa (Sweden); Petring, D [Fraunhofer-Institute for Laser Technology (ILT), Steinbachstrasse 15, Aachen (Germany); Kumar, R V [Department of Materials Science and Metallurgy, University of Cambridge, Cambridge CB2 3QZ (United Kingdom); Al-Mashikhi, S O; Voisey, K T [Department of Mechanical, Materials and Manufacturing Engineering, Faculty of Engineering, University of Nottingham, University Park, Nottingham NG7 2RD (United Kingdom)], E-mail: jpowell@laserexp.co.uk

2009-01-07

In a considerable proportion of the published work on the subject of laser-oxygen cutting of mild steel, the details of the oxidation reaction are overlooked or confused. For example, it is not uncommon for the oxidized material to be attributed with the physical characteristics of iron rather than iron oxide. Also, the fact that the oxidation reaction cannot take place above a certain temperature limit is usually overlooked. This paper presents, for the first time, an in-depth analysis of the Iron to FeO oxidation reaction in the context of laser-oxygen cutting of mild steel. The paper concludes by presenting a number of guidelines for future theoretical models.

Laser-oxygen cutting of mild steel: the thermodynamics of the oxidation reaction

International Nuclear Information System (INIS)

Powell, J; Kaplan, A F H; Petring, D; Kumar, R V; Al-Mashikhi, S O; Voisey, K T

2009-01-01

In a considerable proportion of the published work on the subject of laser-oxygen cutting of mild steel, the details of the oxidation reaction are overlooked or confused. For example, it is not uncommon for the oxidized material to be attributed with the physical characteristics of iron rather than iron oxide. Also, the fact that the oxidation reaction cannot take place above a certain temperature limit is usually overlooked. This paper presents, for the first time, an in-depth analysis of the Iron to FeO oxidation reaction in the context of laser-oxygen cutting of mild steel. The paper concludes by presenting a number of guidelines for future theoretical models.

NOx Emission in Iron and Steel Production: A Review of Control Measures for Safe and Eco-Friendly Environment

Directory of Open Access Journals (Sweden)

U. A. Mukhtar

2017-12-01

Full Text Available Iron and steel manufacturing involved preparation of raw materials through processes such as sintering, pelletizing and coke making. During these processes, pollutants such as Sulphur (iv oxides (SO2 Carbon II oxides (CO, Nitrogen oxides (NOX, Volatile organic compounds (VOC and Particulate matter (PM etc. are emitted. The present work is aimed at describing some mitigation technologies of controlling emissions in iron and steel production. The processes involved in the production of iron and steel using Blast Furnace (BF and Basic Oxygen Furnace (BOF has been described. The mitigation technologies of controlling emissions were analyzed and discussed with environmental impacts based on the economical and technical factors. In this work, the data presented is based on existing reviews. The combination of low NOX burner (LNB and Selective catalytic reduction (SCR is capable of reducing emission for up to 90% and above. Emissions of other pollutants into the atmosphere as a result of ammonia slip, formation of acids and other gases are harmful to the environment and causes damage to the SCR systems. Installation and operation cost are the major impacts of the SCR technology in the process of iron and steel production.

Biomass as blast furnace injectant – Considering availability, pretreatment and deployment in the Swedish steel industry

International Nuclear Information System (INIS)

Wang, Chuan; Mellin, Pelle; Lövgren, Jonas; Nilsson, Leif; Yang, Weihong; Salman, Hassan; Hultgren, Anders; Larsson, Mikael

2015-01-01

Highlights: • Injection of biofuels was modeled, using real blast furnace data as reference. • For charcoal, torrefied and pelletized biomass; a replacement limit was predicted. • As expected, reduced CO 2 emissions are possible, especially when using charcoal. • We also found that substantial energy savings can be made, using any of the biofuels. • Circumstances today and biomass availability tomorrow are encouraging for deployment. - Abstract: We have investigated and modeled the injection of biomass into blast furnaces (BF), in place of pulverized coal (PC) from fossil sources. This is the easiest way to reduce CO 2 emissions, beyond efficiency-improvements. The considered biomass is either pelletized, torrefied or pyrolyzed. It gives us three cases where we have calculated the maximum replacement ratio for each. It was found that charcoal from pyrolysis can fully replace PC, while torrefied material and pelletized wood can replace 22.8% and 20.0% respectively, by weight. Our energy and mass balance model (MASMOD), with metallurgical sub-models for each zone, further indicates that (1) more Blast Furnace Gas (BFG) will be generated resulting in reduced fuel consumption in an integrated plant, (2) lower need of limestone can be expected, (3) lower amount of generated slag as well, and (4) reduced fuel consumption for heating the hot blast is anticipated. Overall, substantial energy savings are possible, which is one of the main findings in this paper. Due to the high usage of PC in Sweden, large amounts of biomass is required if full substitution by charcoal is pursued (6.19 TWh/y). But according to our study, it is likely available in the long term for the blast furnace designated M3 (located in Luleå). Finally, over a year with almost fully used production capacity (2008 used as reference), a 28.1% reduction in on-site emissions is possible by using charcoal. Torrefied material and wood pellets can reduce the emissions by 6.4% and 5.7% respectively

Method of operating a centrifugal plasma arc furnace

International Nuclear Information System (INIS)

Kujawa, S.T.; Battleson, D.M.; Rademacher, E.L. Jr.; Cashell, P.V.; Filius, K.D.; Flannery, P.A.; Whitworth, C.G.

1998-01-01

A centrifugal plasma arc furnace is used to vitrify contaminated soils and other waste materials. An assessment of the characteristics of the waste is performed prior to introducing the waste into the furnace. Based on the assessment, a predetermined amount of iron is added to each batch of waste. The waste is melted in an oxidizing atmosphere into a slag. The added iron is oxidized into Fe 3 O 4 . Time of exposure to oxygen is controlled so that the iron does not oxidize into Fe 2 O 3 . Slag in the furnace remains relatively non-viscous and consequently it pours out of the furnace readily. Cooled and solidified slag produced by the furnace is very resistant to groundwater leaching. The slag can be safely buried in the earth without fear of contaminating groundwater. 3 figs

Distribution of radionuclides during melting of carbon steel

Energy Technology Data Exchange (ETDEWEB)

Thurber, W.C.; MacKinney, J.

1997-02-01

During the melting of steel with radioactive contamination, radionuclides may be distributed among the metal product, the home scrap, the slag, the furnace lining and the off-gas collection system. In addition, some radionuclides will pass through the furnace system and vent to the atmosphere. To estimate radiological impacts of recycling radioactive scrap steel, it is essential to understand how radionuclides are distributed within the furnace system. For example, an isotope of a gaseous element (e.g., radon) will exhaust directly from the furnace system into the atmosphere while a relatively non-volatile element (e.g., manganese) can be distributed among all the other possible media. This distribution of radioactive contaminants is a complex process that can be influenced by numerous chemical and physical factors, including composition of the steel bath, chemistry of the slag, vapor pressure of the particular element of interest, solubility of the element in molten iron, density of the oxide(s), steel melting temperature and melting practice (e.g., furnace type and size, melting time, method of carbon adjustment and method of alloy additions). This paper discusses the distribution of various elements with particular reference to electric arc furnace steelmaking. The first two sections consider the calculation of partition ratios for elements between metal and slag based on thermodynamic considerations. The third section presents laboratory and production measurements of the distribution of various elements among slag, metal, and the off-gas collection system; and the final section provides recommendations for the assumed distribution of each element of interest.

Effect of Mechanical Alloying Atmospheres and Oxygen Concentration on Mechanical Properties of ODS Ferritic Steels

International Nuclear Information System (INIS)

Noh, Sanghoon; Choi, Byoungkwon; Han, Changhee; Kim, Kibaik; Kang, Sukhoon; Chun, Youngbum; Kim, Taekyu

2013-01-01

Finely dispersed nano-oxide particles with a high number density in the homogeneous grain matrix are essential to achieve superior mechanical properties at high temperatures, and these unique microstructures can be obtained through the mechanical alloying (MA) and hot consolidation process. The microstructure and mechanical property of ODS steel significantly depends on its powder property and the purity after the MA process. These contents should be carefully controlled to improve the mechanical property at elevated temperature. In particular, appropriate the control of oxygen concentration improves the mechanical property of ODS steel at high temperature. An effective method is to control the mechanical alloying atmosphere by high purity inert gas. In the present study, the effects of mechanical alloying atmospheres and oxygen concentration on the mechanical property of ODS steel were investigated. ODS ferritic alloys were fabricated in various atmospheres, and the HIP process was used to investigate the effects of MA atmospheres and oxygen concentration on the microstructure and mechanical property. ODS ferritic alloys milled in an Ar-H 2 mixture, and He is effective to reduce the excess oxygen concentration. The YH 2 addition made an extremely reduced oxygen concentration by the internal oxygen reduction reaction and resulted in a homogeneous microstructure and superior creep strength

Study of reactions between nuclear fuel and cladding (316 stainless steel) in reactors. Influence of oxygen

International Nuclear Information System (INIS)

Otter, Monique.

1980-12-01

We have studied oxidation of 316 steel in close contact with oxides (Usub(0,74)Pusub(0,26)O 2 or UO 2 ), the stoichiometry of oxygen ranging from 2.00 to 2.5. Experiments are carried out either in a closed isothermal system or in an opened isothermal system with a fixed oxygen potential of uranium oxide. We have realized a potentiostatic device using a solid state electrotyte galvanic cell. In a closed system, the sensitized austenitic steel shows intergranular and volume oxidation probably enhanced by migration of steel components towards the fuel. Evidence of the usefulness of passivation have been obtained. We conclude that in a fast reactor sensitized cladding steel is oxydized by the constant potential of oxygen of UPuO 2 . Deposits observed in fuel can be explain by evaporation and cyclic transport phenomena that can be differents from VAN-ARKEL mechanism taking place through fission products [fr

The stress corrosion cracking of type 316 stainless steel in oxygenated and chlorinated high temperature water

International Nuclear Information System (INIS)

Congleton, J.; Shih, H.C.; Shoji, T.; Parkins, R.N.

1985-01-01

Slow strain rate stress corrosion tests have been performed on Type 316 stainless steel in 265 C water containing from 0 to 45 ppm oxygen and from < 0.1 to 1000 ppm chloride. The main difference between the present data and previously published results, the latter mainly for Type 304 stainless steel, is that as well as cracking occurring in water containing high oxygen and chloride, it is shown that a cracking regime exists at very low oxygen contents for a wide range of chloride contents. The type of cracking varies with the oxygen and chloride content of the water and the most severe cracking was of comparable extent in both the gauge length and the necked region of the specimen. The least severe cracking only caused cracks to occur in the necked region of the specimen and there was a range of oxygen and chloride contents in which no cracking occurred. The rest potential for annealed Type 316 stainless steel has been mapped for a wide range of oxygen and chloride content waters and it is shown that at 265 C the 'no-cracking' regime of the oxygen-chloride diagram corresponds to potentials in the range -200 to +150 mV(SHE). (author)

Research achievement report for fiscal 1998 on the development of high-performance industrial furnaces. Research and development of high-performance industrial furnaces and the like (2); 1998 nendo koseino kogyoro no kaihatsu ni kansuru kenkyu seika hokokusho. Koseino kogyoro nado ni kansuru kenkyu kaihatsu (2)

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-03-01

Volume 2 named above contains part of research achievement reports and individual research achievement reports. The aluminum melting furnace working group research achievement report covers aluminum melting furnace operating patterns, concentrated impinging flame mode and dispersed impinging flame mode, and honeycomb and ball structures in heat storing bodies. The tubular heater working group report mentions the application of this facility to oil heating furnaces, studies and investigations for the embodiment of real systems using the tubular heater, and tests conducted in a furnace with plural heating tube lines. The individual research achievement reports elaborate on the development of technologies of heat transfer optimization under unsteady conditions in the steel material heating process, research and development of high-efficiency heat transfer technologies, development of heating furnace geometry optimization technologies, research and development of a high-performance controlled atmosphere heat treatment furnace, development of high-efficiency heat transfer technologies in high-temperature jet flame heating, development of heat uniformity improvement technologies for example for the steel material heating process, construction of optimum combustion control technologies for the regenerative burner furnace, research concerning laser-aided measurement in industrial furnaces, etc. (NEDO)

Research report for fiscal 1998. Basic research for promoting joint implementation of energy use rationalization in Chinese steel industry (examination of introduction of scrap preheating system for electric furnaces); 1998 nendo chosa hokokusho. Chugoku tekkogyo ni okeru energy no shiyo gorika (denkiro scrap yonetsu system donyu kento)

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-03-01

Investigations are conducted on a project of introducing a scrap preheating system based on the central insertion movable shaft design into China's electric furnaces for the sake of energy saving and global warming gas reduction. Of the electric furnaces numbering approximately 3400 now in operation in China, most are small and antiquated, and are extremely low in energy efficiency when in operation. The percentage of electricity supplied by coal-fired facilities is high, and this causes the CO2 reduction problem. Investigations are conducted into four steel mills operating electric furnaces, and examinations are made on the applicability of a preheating system, which is the ultimate batch system developed by Nippon Steel Corporation. Studies are conducted for Wuyang Iron and Steel Co., Ltd., Tianjin Steel Pipe Co., Ltd., Budong Iron and Steel Co., Ltd., and Shanghai Five Steel Co., Ltd., and it is found that greenhouse gas will be reduced by 31,000 tons, 21,000 tons, 13,000 tons, and 11,000-tons at the said mills, respectively. It is learned that the cost to be invested will be retrieved in approximately 2.5 years, 2.8 years, 7.7 years, and 8.0 years, respectively. It is concluded that Shanghai Budong Iron and Steel (Group) Co., Ltd., is the best candidate to be equipped with the above-said system. (NEDO)

Combustion of Solid Fuel in a Vortex Furnace with Counter-swirling Flows

Directory of Open Access Journals (Sweden)

Redko A.A.

2017-12-01

Full Text Available The results of computer simulation of the processes of incineration of low-grade solid fuel-pulverized peat with a moisture content of 40%, an ash content of 6% are given. It has been determined the fields of distribution of temperature, velocity of gases and particles in the volume and at the outlet from the furnace. The three-dimensional temperature distribution in the combustion chamber indicates high-temperature combustion of peat particles at temperatures above 1700°C with liquid ash removal in the lower part of the furnace. It has been determined that when the furnace is cooled, it is not ensured combustion of the fuel completely. The value of the swirling flow rate at the outlet from the furnace (up to 370 m/s ensures the efficiency of separation of fuel particles, reducing heat losses from mechanical underburning. It is determined that the concentration of oxygen is close to zero over the entire height of the furnace, at an outlet from the furnace the oxygen concentration is 5...6%, since oxygen is supplied with excess (αв=1,2. The results of a numerical study showed that the diameter of peat particles affects the process of their combustion: coke particles with an initial diameter of 25 mkm to 250 mkm burn out by 96%. With an increase in particle diameter up to 1000 mkm, the degree of burn-out of coke decreases, but at the same time their removal decreases. It is shown that the furnace ensures the completeness of combustion of peat particles of peat 99.8%, volatiles is 100%.

Tracers application method for the quantitative determination of the source of oxygenic inclusions in steel

International Nuclear Information System (INIS)

Rewienska-Kosciukowa, B.; Dalecki, W.; Michalik, J.S.

1976-01-01

The sense and the possibility of radioactive and nonradioactive isotopic tracers application in investigations of the origin of oxygenic nonmetalic inclusions is presented. The discussed methods touch the investigations such as the origin of egzogenic inclusions which passed from external sources (fireproof lining, slag) to the steel or as the endogenic ones formed during the process of steel deoxidisation. The question of the tracers choice for refractory material and the further investigations concerned the determination of the origin of nonmetallic inclusions are discussed. The question of so called isotopic replacement tracers for the main steel deoxidizing agents is considered. The criterion of determination of oxygenic inclusions formed during the process of steel deoxidization is also discussed. Several results of laboratory and industrial investigations and also the examples of application of the discussed methods in the industrial scale are presented. (author)

Overall model of the dynamic behaviour of the steel strip in an annealing heating furnace on a hot-dip galvanizing line

Energy Technology Data Exchange (ETDEWEB)

Martinez-de-Pison, F.J.; Pernia, A.; Jimenez-Macias, E.; Fernandez, R.

2010-07-01

Predicting the temperature of the steel strip in the annealing process in a hot-dip galvanizing line (HDGL) is important to ensure the physical properties of the processed material. The development of an accurate model that is capable of predicting the temperature the strip will reach according to the furnaces variations in temperature and speed, its dimensions and the steels chemical properties, is a requirement that is being increasingly called for by industrial plants of this nature. This paper presents a comparative study made between several types of algorithms of Data Mining and Artificial Intelligence for the design of an efficient and overall prediction model that will allow determining the strips variation in temperature according to the physico-chemical specifications of the coils to be processed, and fluctuations in temperature and speed that are recorded within the annealing process. The ultimate goal is to find a model that is effectively applicable to coils of new types of steel or sizes that are being processed for the first time. This model renders it possible to fine-tune the control model in order to standardise the treatment in areas of the strip in which there is a transition between coils of different sizes or types of steel. (Author).

Method of making steel strapping and strip

Energy Technology Data Exchange (ETDEWEB)

Robert D. Reilly

2000-02-16

procedure would simulate proposed processing line conditions however variations in test results have necessitated further investigations into the nature of cold rolled steel vs. hot rolled steel and electric furnace steel vs. basic oxygen furnace steel as it may apply to heat treating procedures and selection of appropriate steel chemistry for the process.

A REVIEW OF MILD COMBUSTION AND OPEN FURNACE DESIGN CONSIDERATION

Directory of Open Access Journals (Sweden)

M.M. Noor

2012-12-01

Full Text Available Combustion is still very important to generate energy. Moderate or Intense Low-oxygen Dilution (MILD combustion is one of the best new technologies for clean and efficient combustion. MILD combustion has been proven to be a promising combustion technology in industrial applications with decreased energy consumption due to the uniformity of its temperature distribution. It is clean compared to traditional combustion due to producing low NOx and CO emissions. This article provides a review and discussion of recent research and developments in MILD. The issue and applications are summarized, with some suggestions presented on the upgrading and application of MILD in the future. Currently MILD combustion has been successfully applied in closed furnaces. The preheating of supply air is no longer required since the recirculation inside the enclosed furnace already self-preheats the supply air and self-dilutes the oxygen in the combustion chamber. The possibility of using open furnace MILD combustion will be reviewed. The design consideration for open furnace with exhaust gas re-circulation (EGR was discussed.

Analysis of oxygen content in steel by means of 14 MeV neutrons

International Nuclear Information System (INIS)

Chuang, L.S.; Wong, K.C.; Chiu, W.Y.

1975-01-01

A sealed-tube type 14 MeV neutron generator with maximum neutron output of 10 11 n/sec, incorporating a pneumatic sample transfer system of single-tube type and with a single rotation of the sample during neutron irradiation, is used to develop a method suitable for routine work in industrial applications. A pulse shape analyser system incorporating an organic scintillation detector is used for monitoring neutron flux level during the neutron irradiation of the sample. Polyethylene, of oxygen content 163 ppm determined by comparison with lucite, is used as the steel sample carrier. A 3 x 3 in. NaI(Tl) crystal is used with a single channel analyser to count the 6.1 and 7.1 MeV gamma rays emitted from 16 N as a result of the reaction 16 O(n,p) 16 N. As the present activation analysis makes use of the comparison method, a steel-mylar standard made of layered steel and mylar discs is prepared and a calibration curve constructed. A method of correcting the oxygen contribution in the polyethylene sample carrier is devised and the content of oxygen in the steel standard is determined. A survey of neutron flux distribution is also attempted and it is found that nearly symmetrical distribution of the flux, about the centre of the sample carrier which is placed with its axis in parallel to the plane of the disc-shaped target of the neutron-generating tube, is far from being flat. (Auth.)

Plasma arc and cold crucible furnace vitrification for medium level waste: a review

International Nuclear Information System (INIS)

Poitou, S.; Fiquet, O.; Bourdeloie, C.; Gramondi, P.; Rebollo, F.; Girold, C.; Charvillat, J.P.; Boen, R.; Jouan, A.; Ladirat, C.; Nabot, J.P.; Ochem, D.; Baronnet, J.M.

2001-01-01

Initially developed for high-level waste reprocessing, several vitrification processes have been under study since the 80's at the French Atomic Energy Commission (CEA) for other waste categories. According to the French law concerning waste management research passed on December 30, 1991, vitrification may be applied to mixed medium-level waste. A review of processes developed at CEA is presented: cold crucible furnace heated by induced current, refractory furnace heated by nitrogen transferred arc plasma torch, and coupling of cold crucible furnace with oxygen transferred plasma arc twin torch. Furthermore, gas post-combustion has been studied with an oxygen non-transferred plasma torch. (authors)

The effect of reduced oxygen content powder on the impact toughness of 316 steel powder joined to 316 steel by low temperature HIP

International Nuclear Information System (INIS)

Lind, Anders; Sundstroem, Johan; Peacock, Alan

2005-01-01

During the manufacture of the blanket modules, 316L steel powder is simultaneously consolidated and joined to tubes and blocks of 316L materials by hot isostatic pressing (HIP). The high processing temperature can detrimentally increase the grain size of the water-cooling tubes in the structure and the blocks reducing their strength. It is well known [L. Arnberg, A. Karlsson, Influence of powder surface oxidation on some properties of a HIPed martensitic chromium steel, Int. J. Powder Metall. 24 (2) (1988) 107-112] that surface oxides on the powder particles negatively influence the impact toughness of material and joints consolidated in this way. At a high HIP temperature, the oxides are at least partly transformed, thereby improving the impact toughness [L. Nyborg, I. Olefjord, Surface analysis of PM martensitic steel before and after consolidation. Part 2. Surface analysis of compacted material, Powder Metall. 31 (1) (1988) 40-44]. In order to get acceptable mechanical properties of materials produced at a low HIP temperature, the oxygen content on the powder surfaces needs to be reduced. In order to study the effect of reducing the powder oxygen content, it was reduced and the results were compared to those of specimens with ordinary oxygen content. The effect on the impact toughness and the tensile strength of low temperature (1020 and 1060 deg. C) HIP joints between steel blocks and powder consolidated material with low and ordinary oxygen content was measured

40 CFR 52.2036 - 1990 base year emission inventory.

Science.gov (United States)

2010-07-01

... Oxygen Furnace Shop, Blast Furnace Casthouse), submitted June 10, 1996, are approved. Sharon Steel... cars, flare stack, tuyeres) are 0.4 TPY and 49.3 TPY, respectively. The 1990 VOC and NOX emissions from the Basic Oxygen Furnace Shop (scrap preheating, ladle preheating and heaters) are 1.4 TPY and 39.6...

Material properties of the F82H melted in an electric arc furnace

Energy Technology Data Exchange (ETDEWEB)

Sakasegawa, Hideo, E-mail: sakasegawa.hideo@jaea.go.jp [Japan Atomic Energy Agency, Rokkasho, Aomori (Japan); Tanigawa, Hiroyasu [Japan Atomic Energy Agency, Rokkasho, Aomori (Japan); Kano, Sho; Abe, Hiroaki [Institute for Materials Research, Tohoku university, Sendai, Miyagi (Japan)

2015-10-15

Highlights: • We studied material properties of reduced activation ferritic/martensitic steel. • We melted F82H using a 20 tons electric arc furnace for the first time. • Mass effect likely affected material properties. • MX (M: Metal, C: Carbon and/or Nitrogen) precipitates mainly formed on grain and sub grain boundaries. - Abstract: Fusion DEMO reactor requires over 11,000 tons of reduced activation ferritic/martensitic steel. It is necessary to develop the manufacturing technology for fabricating such large-scale steel with appropriate mechanical properties. In this work, we focused fundamental mechanical properties and microstructures of F82H-BA12 heat which was melted using a 20 tons electric arc furnace followed by electroslag remelting process. Its raw material of iron was blast furnace iron, because the production volume of electrolytic iron which has been used in former heats, is limited. After melting and forging, this F82H-BA12 heat was heat-treated in four different conditions to consider their fluctuations and to optimize them, and tensile and Charpy impact tests were then performed. The result of these mechanical properties were comparable to those of former F82H heats less than 5 tons which were melted applying vacuum induction melting.

The effect of molybdenum addition on SCC susceptibility of stainless steels in oxygenated high temperature water

International Nuclear Information System (INIS)

Akashi, Masatsune; Kawamoto, Teruaki

1978-01-01

The effect of molybdenum addition on the SCC susceptibility of sensitized stainless steel in oxygenated high temperature water has been studied through the creviced bent beam SCC test (CBB test) and A262E intergranular corrosion test. The molybdenum addition improved the SCC susceptibility of sensitized stainless steels in oxygenated high temperature water not only by delaying the sensitization at lower temperatures but also by increasing the material resistance to the SCC under a given degree of sensitization. These laboratory test results reveal that the molybdenum addition is quite beneficial for improving the SCC susceptibility of stainless steel pipe weld joints in boiling water reactor environment. (auth.)

Oil injection into the blast furnace

Energy Technology Data Exchange (ETDEWEB)

Dongsheng Liao; Mannila, P.; Haerkki, J.

1997-12-31

Fuel injection techniques have been extensively used in the commercial blast furnaces, a number of publications concerning the fuels injection have been reported. This present report only summarizes the study achievements of oil injection due to the research need the of authors, it includes the following parts: First, the background and the reasons reducing coke rate of oil injection are analyzed. Reducing coke rate and decreasing the ironmaking costs are the main deriving forces, the contents of C, H and ash are direct reasons reducing coke rate. It was also found that oil injection had great effects on the state of blast furnace, it made operation stable, center gas flow develop fully, pressure drop increase, descent speed of burden materials decrease and generation of thermal stagnation phenomena, the quality of iron was improved. Based on these effects, as an ideal mean, oil injection was often used to adjust the state of blast furnace. Secondly, combustion behavior of oil in the raceway and tuyere are discussed. The distribution of gas content was greatly changed, the location of CO, H{sub 2} generation was near the tuyere; the temperature peak shifts from near the raceway boundary to the tuyere. Oxygen concentration and blast velocity were two important factors, it was found that increasing excess oxygen ratio 0.9 to 1.3, the combustion time of oil decreases 0.5 msec, an increase of the blast velocity results in increasing the flame length. In addition, the nozzle position and oil rate had large effects on the combustion of oil. Based on these results, the limit of oil injection is also discussed, soot formation is the main reason limiting to further increase oil injection rate, it was viewed that there were three types of soot which were generated under blast furnace operating conditions. The reason generating soot is the incomplete conversion of the fuel. Finally, three methods improving combustion of oil in the raceway are given: Improvement of oil

Dilute Oxygen Combustion Phase IV Final Report

Energy Technology Data Exchange (ETDEWEB)

Riley, M.F.

2003-04-30

Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations

EFFECT OF DEW POINT OF ATMOSPHERE OF CGL’S ANNEALING FURNACES ON THE QUALITY OF GA COATING ON BAKE HARDENABLE STEEL

Directory of Open Access Journals (Sweden)

Juliana Porto Guimarães

2013-10-01

Full Text Available The strip steel surface condition after continuous annealing of strip is extremely important to the quality of galvannealed coating (GA. The presence of oxides or precipitated can affect the reactions at the coating/substrate interface and decrease the zinc wettability on the steel surface, leading to various defects in the final product. To avoid oxidation of the material during continuous annealing, a protective atmosphere is used in the furnaces. Despite this atmosphere, it is possible the selective oxidation or precipitation of second phase particles, being the dew point of atmosphere one of the leading factors to reduce this occurrence. This study aims to evaluate the effect of the dew point on the quality of GA coatings applied to a bake hardenable steel. The continuous annealing under dew points of –60°C, 30°C and 0°C, as well as hot dip galvanizing, were performed in a Hot Dip Process Simulator. It is found that the dew point has a decisive influence on the amount, distribution and type of oxides formed, and the condition of –30°C provided the coating with less failures and better adhesion.

40 CFR 63.7852 - What definitions apply to this subpart?

Science.gov (United States)

2010-07-01

... the processes where hot metal transfer, hot metal desulfurization, slag skimming, and ladle metallurgy... means the location in a basic oxygen process furnace shop where molten iron (hot metal) is transferred...). Primary oxygen blow means the period in the steel production cycle of a basic oxygen process furnace...

Estimation of CO2 emission for each process in the Japanese steel industry: a process analysis

International Nuclear Information System (INIS)

Sakamoto, Y.; Tonooka, Y.

2000-01-01

The CO 2 emission for each process in the Japanese steel industry is estimated by a process analysis using statistical data in order to evaluate the possibility of reducing CO 2 emissions. The emission factor of CO 2 for each product and also for crude steel produced from an integrated steel plant route and an electric arc furnaces route is estimated and compared. The CO 2 emissions can be estimated from production amounts of products for each process and for crude steel. The CO 2 emission of blast furnaces is the largest and that of rolling and piping follows. The emission factor of CO 2 of crude steel produced from an integrated steel plant route is approximately 3.8 times as high as that produced via an electric arc furnace route. (Author)

Study on blast furnace cooling stave for various refractory linings based on numerical modeling

International Nuclear Information System (INIS)

Mohanty, T R; Sahoo, S K; Moharana, M K

2016-01-01

Cooling technology for refractory lining of blast furnace is very important for the metallurgical industry, because it can substantially increase output and operation life of furnaces. A three dimensional mathematical model for the temperature field of the blast furnace stave cooler with refractory lining has been developed and analyzed. The temperature and heat dissipated by stave cooler is examined by using the finite element method. The cast steel stave is studied and computational analysis is made to know the effect of the cooling water velocity, temperature, and the lining material on the maximum temperature of the stave hot surface. The refractory lining materials, which are used in this experiment, are high alumina bricks with different stave materials (copper, aluminum and cast iron). The obtained numerical calculations are compared with that obtained from experiments performed at Rourkela Steel Plant, Odisha taking a stave in belly zone having maximum heat load shows very good agreement. (paper)

The design of system for operative planning of blast furnace production process

Directory of Open Access Journals (Sweden)

Malindžák Dušan

1996-12-01

Full Text Available A system for operative planning of blast furnace production process is described in the paper. The suggested system is based on the use of a new hierarchy of operative plans, consisting of one-month plan, (7+3 days plan, and 24-hour plan. The system allows smoothing of production process at the blast furnace plant, and at the same time satisfies all requirements of the steel plant regarding to the amount of pig iron.

Simultaneously estimation for surface heat fluxes of steel slab in a reheating furnace based on DMC predictive control

International Nuclear Information System (INIS)

Li, Yanhao; Wang, Guangjun; Chen, Hong

2015-01-01

The predictive control theory is utilized for the research of a simultaneous estimation of heat fluxes through the upper, side and lower surface of a steel slab in a walking beam type rolling steel reheating furnace. An inverse algorithm based on dynamic matrix control (DMC) is established. That is, each surface heat flux of a slab is simultaneously estimated through rolling optimization on the basis of temperature measurements in selected points of its interior by utilizing step response function as predictive model of a slab's temperature. The reliability of the DMC results is enhanced without prior assuming specific functions of heat fluxes over a period of future time. The inverse algorithm proposed a respective regularization to effectively improve the stability of the estimated results by considering obvious strength differences between the upper as well as lower and side surface heat fluxes of the slab. - Highlights: • The predictive control theory is adopted. • An inversion scheme based on DMC is established. • Upper, side and lower surface heat fluxes of slab are estimated based DMC. • A respective regularization is proposed to improve the stability of results

Reports on research achievements in developing high-performance industrial furnaces in fiscal 1998 (Research and development of high-performance industrial furnaces). Volume 1; 1998 nendo koseino kogyoro nado ni kansuru kenkyu kaihatsu seika hokokusho. 1

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-03-01

From the reports on research achievements in developing high-performance industrial furnaces in fiscal 1998, the report volume 1 was prepared as a research achievement report of each working group, detailing fundamental researches, heating furnaces, and heat treatment furnaces. The fundamental researches have researched combustion evaluating technology, characteristics of the area in the vicinity of a combustor, characteristics of combustion of high-temperature air, heating characteristics of a furnace to investigate effect of local heat absorption, and combustion evaluation. For the heating furnaces, the following subjects were studied: development of an in-furnace combustion model, summary of an experiment for evaluating high-temperature air combustion, furnace height relative to combustion heat transfer characteristics, heat loss minimizing technology, combustion heat transfer characteristics of liquid fuels, optimal operation of the high-temperature air combustion, basic control in heating control, and steel piece heating control. Studies were performed for the heat treatment furnaces on the case of a direct firing furnace in evaluating the heat transfer characteristics, the case of a radiant tube furnace, application of thermal fluid simulation technology, furnace averaging technology, soot reducing technology, control technology, and trial design on a high-performance heat treatment furnace. (NEDO)

Numerical study of particle filtration in an induction crucible furnace

International Nuclear Information System (INIS)

Asad, Amjad; Kratzsch, Christoph; Dudczig, Steffen; Aneziris, Christos G.; Schwarze, Rüdiger

2016-01-01

Highlights: • Removing particles from a melt in an induction furnace by using a filter is introduced. • The effect of filter and its permeability on the melt flow is shown. • The impact of filter permeability and particle diameter on filter efficiency is studied. • The filter efficiency depends on filter position and number of the used filter. - Abstract: The present paper deals with a numerical investigation of the turbulent melt flow driven by the electromagnetic force in an induction furnace. The main scope of the paper is to present a new principle to remove non-metallic particles from steel melt in an induction furnace by immersing a porous filter in the melt. The magnetic field acting on the melt is calculated by using the open source software MaxFEM"®, while the turbulent flow is simulated by means of the open source computational fluid dynamics library OpenFOAM"®. The validation of the numerical model is accomplished by using experimental results for the flow without the immersed filter. Here it is shown that the time-averaged flow, obtained numerically is in a good quantitive agreement with the experimental data. Then, the validated numerical model is employed to simulate the melt flow with the immersed filter in the induction furnace of a new type of real steel casting simulator investigated at Technische Universität Bergakademie Freiberg. The considerable effect of the filter on the flow pattern is indicated in the present work. Moreover, it is shown that the filter permeability and its position have a significant influence on the melt flow in the induction furnace. Additionally, particles are injected in the flow domain and tracked by using Lagrangian framework. In this case, the efficiency of the used filter is determined in the present investigation depending on its permeability, its position and the particles diameter.

Furnace coking simulations in a laboratory apparatus

Energy Technology Data Exchange (ETDEWEB)

Eaton, Paul [Champion Technologies Inc (United States)], email: paul.eaton@champ-tech.com; Newman, Bruce [ConocoPhillips (United States)], email: Bruce.A.Newman@conocophillips.com; Gray, Murray; Kubis, Alan; Derakhshesh, Marzie; Holt, Chris; Mitlin, David [Department of Chemical and Materials Engineering, University of Alberta (Canada)

2010-07-01

This work deals with simulating fouling behavior of crude oil in a delayed coker furnace. Fouling on different heated metal probes was investigated; these were mainly stainless steel, iron, or mild steel probes. Heat transfer theory was used to calculate the system fouling factor, and this parameter was recorded as a function of time to model in-situ fouling intensity. Physical and chemical properties such as buildup thickness and composition were investigated using different measuring techniques, most important of which were extractive-iron-nickel ion chromatography, optical and scanning electron microscopy (SEM), and electron dispersion spectroscopy (EDS). Changes in surface layers of the metallic probe during coke formation along with microstructures of the coke were examined using a focused-ion beam (FIB). It was shown that the iron probe exhibited more buildups on its surface than stainless steels, and fouling of mild steel came in between. As for oils with different concentrations, fouling of diluted atmospheric tower bottom (ATB) was greater than that of undiluted ATP.

Theoretical and experimental investigations into rare earth oxides behaviour during out of furnace treatment

International Nuclear Information System (INIS)

Vishkarev, A.F.; Smirnov, B.V.; Krup, Yu.M.

1987-01-01

Theoretical model is developed and technology of metal desulfuration and modification by rear earth metals is tested during out of furnace vacuum treatment, the testing of which has demonstrated its high efficiency. 16KhN3MA steel was melted in 120-t open-hearth furnaces under tapping with treatment by synthetic lime-aluminous slag and subsequent ladle degassing by circulation technique. At the early stage of degassing process cerium oxides together with aluminium were introduced into the vacuum chamber in the quantities of 2.0 and 0.2 kg/t respectively. Two meltings ere performed. Sulfur content in steel reduced from 0.017 and 0.018 up to 0.007 and 0.006%

Basic survey project for Joint Implementation, etc. Blast furnace top pressure recovery turbine (TRT) project (Panzhihua Iron and Steel (Group) Company, People's Republic of China)

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

For the purpose of reducing greenhouse effect gas emissions, a feasibility study was conducted on the energy conservation at Panzhihua Iron and Steel Company in Sichuan Province, China. In this project, the pressure energy of blast furnace is to be recovered in the form of electric power by installing the blast furnace top pressure recovery turbine (TRT). In the project, the pressure-reducing valve was removed, and the dry dust collector/dry TRT were installed to make the scale of electric power production largest. A model of TRT was installed at No. 4 blast furnace and is now in operation. In this project, TRTs are to be installed at Nos. 1, 2 and 3 blast furnaces. As a result of the study, the investment totaled 5.46 billion yen. The capacity of power generation by TRT is 16,890 kW, and the generated output is 137,822 MWh/y. Moreover, the amount of energy conservation is 36,467 toe/y, and the reduction amount of greenhouse effect gas emissions is 112,830 CO2-ton/y. The term of investment recovery is 8.3 years. The effect of reduction in greenhouse effect gas emissions is 20.66 CO2-ton/y/million yen. (NEDO)

Stainless steel recycle FY94 progress report

International Nuclear Information System (INIS)

Imrich, K.J.

1994-01-01

The Materials Technology Section (MTS) of the Savannah River Technology Center (SRTC) was asked to demonstrate the practicality of recycling previously contaminated stainless steel components such as reactor heat exchanger heads, process water piping and slug buckets into 208 liters (55 gallon) drums and 2.8 cubic meter (100 ft 3 ) storage boxes. Radioactively contaminated stainless steel scrap will be sent to several industrial partners where it will be melted, decontaminated/cast into ingots, and rolled into plate and sheet and fabricated into the drums and boxes. As part of this recycle initiative, MTS was requested to demonstrate that radioactively contaminated Type 304L stainless steel could be remelted and cast to meet the applicable ASTM specification for fabrication of drums and boxes. In addition, MTS was requested to develop the technical basis of melt decontamination and establish practicality of using this approach for value added products. The findings presented in this investigation lead to the following conclusions: recycle of 18 wt% Cr-8 wt% Ni alloy can be achieved by melting Type 304 stainless steel in a air vacuum induction furnace; limited melt decontamination of the contaminated stainless steel was achieved, surface contamination was removed by standard decontamination techniques; carbon uptake in the as-cast ingots resulted from the graphite susceptor used in this experiment and is unavoidable with this furnace configuration. A new furnace optimized for melting stainless steel has been installed and is currently being tested for use in this program

Study of the instability of black slags from electric arc furnace steel industry

Directory of Open Access Journals (Sweden)

Frías, M.

2002-09-01

Full Text Available In Spain, the steel manufacture produces important quantities of by-products, representing between 15 and 20 % of total steel production. Most by-products are deposited on open air spaces causing serious economical and environmental problems, internationally, different recycling wais are studied, being the main alternative for these by-products as recycled aggregate. The possibility of recycling these by-products in construction sector depends on its possible volume instability because of the presence of some undesirable compounds. In current paper, two different black slags from electric arc furnace steel industry were chemically characterized, paying attention to some well-known compounds by theirs expansion effects, such as: free CaO, free MgO, chlorides and sulphates. The analytical results carried out in the current research detected the presence of insignificant or null amounts of harmful compounds. Therefore, they should not have any negative incidence on phenomena of volume instability.

En España la fabricación de acero produce grandes cantidades de residuos industriales, las cuales representan entre el 15-20 % de la producción total de acero, en su mayor parte se depositan en vertederos, causando serios problemas económicos y medioambientales a todos los sectores implicados. A nivel internacional, se están estudiando diferentes vías de reutilización, siendo su uso principal como árido de reciclado. La posibilidad de reutilizar estos subproductos industriales en el sector de la construcción se basa en su posible inestabilidad volumétrica, debido a la presencia de ciertos compuestos no deseados. En este trabajo se caracterizan químicamente 2 escorias negras de horno de arco eléctrico con diferente procedencia y se cuantifican algunos de los principales compuestos conocidos por sus efectos expansivos, como: cal libre, magnesia libre, cloruros y sulfatos. Los resultados analíticos de estas dos escorias negras muestran

Research report of fiscal 1997. Research on the projects on Activities Implemented Jointly Japan Program (feasibility research on energy saving by improving heat management for hot blast stoves and heating furnaces); 1997 nendo chosa hokokusho. `Kyodo jisshi katsudo Japan Program` ni kakawaru project chosa (neppuro, kanetsuro no netsukanri kaizen ni yoru sho energy kanosei chosa)

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-03-01

Research was made on joint implementation (JI) for preventing global climate changes in China. Since such the stove and furnace consume a large amount of energy, their improvement and energy saving are important for integrated iron plants. Maanshan iron plant was selected for the research. All the furnaces were manually operated without combustion control systems, and oxygen meters for exhaust gas frequently troubled. As measures for the stoves, operation at a proper air fuel ratio, improvement of over heat storage combustion, and dust cleaning for waste heat recovery gas heaters were proposed. For the furnaces, a proper oxygen content at the end of furnaces (reduction of invasion air) was proposed to improve exhaust gas loss up to that in Japan. For this target, reinforced instrument management and standardized combustion control are essential. JI of software improvement for operation and management can reduce annual greenhouse effect gas emission to 45,900t and 6,300t in carbon equivalent for the stove and furnace, respectively. CO2 reduction is also estimated to be 1,173,000t and 205,000t in China of 107,570,000t in raw steel production, respectively. 28 figs., 32 tabs.

Development of Next Generation Heating System for Scale Free Steel Reheating

Energy Technology Data Exchange (ETDEWEB)

Dr. Arvind C. Thekdi

2011-01-27

The work carried out under this project includes development and design of components, controls, and economic modeling tools that would enable the steel industry to reduce energy intensity through reduction of scale formation during the steel reheating process. Application of scale free reheating offers savings in energy used for production of steel that is lost as scale, and increase in product yield for the global steel industry. The technology can be applied to a new furnace application as well as retrofit design for conversion of existing steel reheating furnaces. The development work has resulted in the knowledge base that will enable the steel industry and steel forging industry us to reheat steel with 75% to 95% reduction in scale formation and associated energy savings during the reheating process. Scale reduction also results in additional energy savings associated with higher yield from reheat furnaces. Energy used for steel production ranges from 9 MM Btu/ton to 16.6 MM Btu/ton or the industry average of approximately 13 MM Btu/ton. Hence, reduction in scale at reheating stage would represent a substantial energy reduction for the steel industry. Potential energy savings for the US steel industry could be in excess of 25 Trillion Btu/year when the technology is applied to all reheating processes. The development work has resulted in new design of reheating process and the required burners and control systems that would allow use of this technology for steel reheating in steel as well as steel forging industries.

Waste and dust utilisation in shaft furnaces

Directory of Open Access Journals (Sweden)

Senk, D.

2005-12-01

Full Text Available Wastes and dusts from steel industry, non-ferrous metallurgy and other branches can be utilized e.g. in agglomeration processes (sintering, pelletizing or briquetting and by injection into shaft furnaces. This paper deals with the second way. Combustion and reduction behaviour of iron- and carbon-rich metallurgical dusts and sludges containing lead, zinc and alkali as well as other wastes with and without pulverized coal (PC has been studied when injecting into shaft furnaces. Following shaft furnaces have been examined: blast furnace, cupola furnace, OxiCup furnace and imperial-smelting furnace. Investigations have been done at laboratory and industrial scale. Some dusts and wastes under certain conditions can be not only reused but can also improve combustion efficiency at the tuyeres as well as furnace performance and productivity.

Los residuos y polvos de filtro provenientes de la industria siderúrgica, de la obtención de metales no ferrosos y de otras industrias, pueden ser utilizados, por ejemplo, en procesos de aglomeración como sintetizado, peletizado o briqueteado. En su caso, estos pueden ser inyectados en los hornos de cuba. Este artículo se enfoca a la inyección de estos materiales en los hornos de cuba. El comportamiento de la combustión y reducción de los polvos ricos en hierro y carbono y también lodos que contienen plomo, zinc y compuestos alcalinos y otros residuos con o sin carbón pulverizado (CP fue examinado, cuando se inyectaron en hornos de cuba. Los siguientes hornos de cuba fueron examinados: Horno alto, cubilote, OxiCup y horno de cuba Imperial Smelting. Las investigaciones se llevaron a cabo a escala de laboratorio e industrial. Algunos residuos y polvos bajo ciertas condiciones, no sólo pueden ser reciclados, sino también mejoran la eficiencia de combustión en las toberas, la operación y productividad del horno.

The fate of injectant coal in blast furnaces: The origin of extractable materials of high molecular mass in blast furnace carryover dusts

Energy Technology Data Exchange (ETDEWEB)

Dong, S.N.; Wu, L.; Paterson, N.; Herod, A.A.; Dugwell, D.R.; Kandiyoti, R. [University of London Imperial College of Science & Technology, London (United Kingdom). Dept. of Chemical Engineering

2005-07-01

The aim of the work was to investigate the fate of injectant coal in blast furnaces and the origin of extractable materials in blast furnace carryover dusts. Two sets of samples including injectant coal and the corresponding carryover dusts from a full sized blast furnace and a pilot scale rig have been examined. The samples were extracted using 1-methyl-2-pyrrolidinone (NMP) solvent and the extracts studied by size exclusion chromatography (SEC). The blast furnace carryover dust extracts contained high molecular weight carbonaceous material, of apparent mass corresponding to 10{sup 7}-10{sup 8} u, by polystyrene calibration. In contrast, the feed coke and char prepared in a wire mesh reactor under high temperature conditions did not give any extractable material. Meanwhile, controlled combustion experiments in a high-pressure wire mesh reactor suggest that the extent of combustion of injectant coal in the blast furnace tuyeres and raceways is limited by time of exposure and very low oxygen concentration. It is thus likely that the extractable, soot-like material in the blast furnace dust originated in tars is released by the injectant coal. Our results suggest that the unburned tars were thermally altered during the upward path within the furnace, giving rise to the formation of heavy molecular weight (soot-like) materials.

Thermal Analysis of an Industrial Furnace

Directory of Open Access Journals (Sweden)

Mirko Filipponi

2016-10-01

Full Text Available Industries, which are mainly responsible for high energy consumption, need to invest in research projects in order to develop new managing systems for rational energy use, and to tackle the devastating effects of climate change caused by human behavior. The study described in this paper concerns the forging industry, where the production processes generally start with the heating of steel in furnaces, and continue with other processes, such as heat treatments and different forms of machining. One of the most critical operations, in terms of energy loss, is the opening of the furnace doors for insertion and extraction operations. During this time, the temperature of the furnaces decreases by hundreds of degrees in a few minutes. Because the dispersed heat needs to be supplied again through the combustion of fuel, increasing the consumption of energy and the pollutant emissions, the evaluation of the amount of lost energy is crucial for the development of systems which can contain this loss. To perform this study, CFD simulation software was used. Results show that when the door opens, because of temperature and pressure differences between the furnace and the ambient air, turbulence is created. Results also show that the amount of energy lost for an opening of 10 min for radiation, convection and conduction is equal to 5606 MJ where convection is the main contributor, with 5020 MJ. The model created, after being validated, has been applied to perform other simulations, in order to improve the energy performance of the furnace. Results show that reducing the opening time of the door saves energy and limits pollutant emissions.

PERFECTING OF THE TECHNOLOGY OF THE OUT-OF-FUMACE PROCESSING OF STEEL AT RUP “BMZ” BY THE EXAMPLE OF ESPTS-1

Directory of Open Access Journals (Sweden)

V. Ju. Gunenkov

2004-01-01

Full Text Available There are achieved all production-technological figures, concerned with embedding of the out-of-furnace processing “bowl- furnace'' installation, i.e the casting duration in the steel-making furnace is reduced, the consumption of electrodes per one ton of good steel is reduced, and also the consumption of refractory bricks is reduced and metal overflows into furnace are excluded.

Increase in the efficiency of electric melting of pellets in an arc furnace with allowance for the energy effect of afterburning of carbon oxide in slag using fuel-oxygen burners

Science.gov (United States)

Stepanov, V. A.; Krakht, L. N.; Merker, E. E.; Sazonov, A. V.; Chermenev, E. A.

2015-12-01

The problems of increasing the efficiency of electric steelmaking using fuel-oxygen burners to supply oxygen for the afterburning of effluent gases in an arc furnace are considered. The application of a new energy-saving regime based on a proposed technology of electric melting is shown to intensify the processes of slag formation, heating, and metal decarburization.

Steel making

CERN Document Server

Chakrabarti, A K

2014-01-01

"Steel Making" is designed to give students a strong grounding in the theory and state-of-the-art practice of production of steels. This book is primarily focused to meet the needs of undergraduate metallurgical students and candidates for associate membership examinations of professional bodies (AMIIM, AMIE). Besides, for all engineering professionals working in steel plants who need to understand the basic principles of steel making, the text provides a sound introduction to the subject.Beginning with a brief introduction to the historical perspective and current status of steel making together with the reasons for obsolescence of Bessemer converter and open hearth processes, the book moves on to: elaborate the physiochemical principles involved in steel making; explain the operational principles and practices of the modern processes of primary steel making (LD converter, Q-BOP process, and electric furnace process); provide a summary of the developments in secondary refining of steels; discuss principles a...

Furnaces. Manufacturers become engineering offices; Les fours, le constructeur devient bureau d`ingenierie

Energy Technology Data Exchange (ETDEWEB)

Nivoche, C. [Salas SA (France)

1997-12-31

The example of Selas, a manufacturer of industrial furnaces for steel and glass industries, faced with the new european pollution regulations, is presented. It is shown how Selas has to develop optimal furnaces using low emission burners but also has to be involved in all the related aspects such as industrial implementation in the client`s plant, plant architecture, cooling systems, air conditioning, noise and vibration issues, operation procedures, safety, etc. Means for reducing NOx emissions are reviewed

Thermal design of a pressure electroslag remelting furnace applied for 5

International Nuclear Information System (INIS)

Cruz M, J.P.

1999-01-01

Actual work defines the thermal design methodology for pressure electroslag remelting furnaces (P ESR) of variable capacity, applied for 5 Kg. It begins with classification and description of secondary refining furnaces, after PESR process and the concept of thermal design are described. Next, in base of the steel weight to remelt (5 Kg); ingot, crucible and electrode dimensions are obtained. These elements will be inside of pressure vessel whose thickness are determined according to ASME Code (Section 8, Division 1, U G-27). It was developed a computer program, where the furnace capacity can be modified, so like other conditions, and display principal dimensions of the furnace. Current and voltage are obtained from the heat necessary to remelt the ingot and the heat transfer in the crucible, is analysed because of it is the most critical element. It was selected too the equipment to registry temperatures and pressure in base of thermocouple characteristics. (Author)

Modification of Non-Metallic Inclusions by Rare-Earth Elements in Microalloyed Steels

Directory of Open Access Journals (Sweden)

M. Opiela

2012-04-01

Full Text Available The modification of the chemical composition of non-metallic inclusions by rare-earth elements in the new-developed microalloyed steels was discussed in the paper. The investigated steels are assigned to production of forged elements by thermo- mechanical treatment. The steels were melted in a vaccum induction furnace and modification of non-metallic inclusions was carried out by the michmetal in the amount of 2.0 g per 1 kg of steel. It was found that using material charge of high purity and a realization of metallurgical process in vacuous conditions result in a low concentration of sulfur (0.004%, phosphorus (from 0.006 to 0.008% and oxygen (6 ppm. The high metallurgical purity is confirmed by a small fraction of non-metallic inclusions averaging 0.075%. A large majority of non-metallic inclusions are fine, globular oxide-sulfide or sulfide particles with a mean size 17m2. The chemical composition and morphology of non-metallic inclusions was modified by Ce, La and Nd, what results a small deformability of non- metallic inclusions during hot-working.

Modelling and prediction of pig iron variables in the blast furnace

Energy Technology Data Exchange (ETDEWEB)

Saxen, H.; Laaksonen, M.; Waller, M. [Aabo Akademi, Turku (Finland). Heat Engineering Lab.

1996-12-31

The blast furnace, where pig iron for steelmaking is produced, is an extremely complicated process, with heat and mass transfer and chemical reactions between several phases. Very few direct measurements on the internal state are available in the operation of the process. A main problem in on-line analysis and modelling is that the state of the furnace may undergo spontaneous changes, which alter the dynamic behaviour of the process. Moreover, large internal disturbances frequently occur, which affect the product quality. The work in this research project focuses on a central problem in the control of the blast furnace process, i.e., short-term prediction of pig iron variables. The problem is of considerable importance for fuel economy, product quality, and for an optimal decision making in integrated steel plants. The operation of the blast furnace aims at producing a product (hot metal) with variables maintained on a stable level (close to their setpoints) without waste of expensive fuel (metallurgical coke). The hot metal temperature and composition affect the downstream (steelmaking) processes, so fluctuations in the pig iron quality must be `corrected` in the steel plant. The goal is to develop a system which predicts the evolution of the hot metal variables (temperature, chemical composition) during the next few taps, and that can be used for decision-making in the operation of the blast furnace. Because of the complicated behaviour of the process, it is considered important to include both deterministic and stochastic components in the modelling: Mathematical models, which on the basis of measurements describe the physical state of the process, and statistical (black-box) models will be combined in the system. Moreover, different models will be applied in different domains in order to capture structural changes in the dynamics of the process SULA 2 Research Programme; 17 refs.

Modelling and prediction of pig iron variables in the blast furnace

Energy Technology Data Exchange (ETDEWEB)

Saxen, H; Laaksonen, M; Waller, M [Aabo Akademi, Turku (Finland). Heat Engineering Lab.

1997-12-31

The blast furnace, where pig iron for steelmaking is produced, is an extremely complicated process, with heat and mass transfer and chemical reactions between several phases. Very few direct measurements on the internal state are available in the operation of the process. A main problem in on-line analysis and modelling is that the state of the furnace may undergo spontaneous changes, which alter the dynamic behaviour of the process. Moreover, large internal disturbances frequently occur, which affect the product quality. The work in this research project focuses on a central problem in the control of the blast furnace process, i.e., short-term prediction of pig iron variables. The problem is of considerable importance for fuel economy, product quality, and for an optimal decision making in integrated steel plants. The operation of the blast furnace aims at producing a product (hot metal) with variables maintained on a stable level (close to their setpoints) without waste of expensive fuel (metallurgical coke). The hot metal temperature and composition affect the downstream (steelmaking) processes, so fluctuations in the pig iron quality must be `corrected` in the steel plant. The goal is to develop a system which predicts the evolution of the hot metal variables (temperature, chemical composition) during the next few taps, and that can be used for decision-making in the operation of the blast furnace. Because of the complicated behaviour of the process, it is considered important to include both deterministic and stochastic components in the modelling: Mathematical models, which on the basis of measurements describe the physical state of the process, and statistical (black-box) models will be combined in the system. Moreover, different models will be applied in different domains in order to capture structural changes in the dynamics of the process SULA 2 Research Programme; 17 refs.

Oxidation of ultra low carbon and silicon bearing steels

Energy Technology Data Exchange (ETDEWEB)

Suarez, Lucia [CTM - Technologic Centre, Materials Technology Area, Manresa, Barcelona (Spain)], E-mail: lucia.suarez@ctm.com.es; Rodriguez-Calvillo, Pablo [CTM - Technologic Centre, Materials Technology Area, Manresa, Barcelona (Spain)], E-mail: pablo.rodriguez@ctm.com.es; Houbaert, Yvan [Department of Materials Science and Engineering, University of Ghent (Belgium)], E-mail: Yvan.Houbaert@UGent.be; Colas, Rafael [Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon (Mexico)], E-mail: rcolas@mail.uanl.mx

2010-06-15

Oxidation tests were carried out in samples from an ultra low carbon and two silicon bearing steels to determine the distribution and morphology of the oxide species present. The ultra low carbon steel was oxidized for short periods of time within a chamber designed to obtain thin oxide layers by controlling the atmosphere, and for longer times in an electric furnace; the silicon steels were reheated only in the electric furnace. The chamber was constructed to study the behaviour encountered during the short period of time between descaling and rolling in modern continuous mills. It was found that the oxide layers formed on the samples reheated in the electric furnace were made of different oxide species. The specimens treated in the chamber had layers made almost exclusively of wustite. Selected oxide samples were studied by scanning electron microscopy to obtain electron backscattered diffraction patterns, which were used to identify the oxide species in the layer.

Development of nuclear grade stainless steels at KCSSL

International Nuclear Information System (INIS)

Balachandran, G.; Dhere, M.; Mahadik, A.; Hinge, N.M.; Balasubramanian, V.

2011-01-01

Kalyani Carpenter Special Steels Ltd is an alloy steel plant, where a variety of alloy steel grades are produced for automotive, defence, nuclear and aerospace applications. The plant has developed expertise in processing of several alloy steel grades of superior quality that meets stringent specifications. Primary steel is processed through a combination of electric arc furnace, ladle furnace and vacuum degassing where stringent control over dephosphorisation, desulphurization, deoxidation is effected to get a refined high quality steel. The molten steel is cast through continuous casting of slabs or ingot casting. In grades specific to nuclear application, the primary cast products are further subjected to electroslag remelting to achieve further freedom from inclusions and to achieve a favourable solidification grain structure, which ultimately improve the hot workability of the alloy steel. Appropriate choice of slag and operating parameters are needed for realising the required ingot quality. The present study would examine the processing and quality aspects of some important grades of steels used in nuclear industry namely ferritic 9Cr-1Mo steel, martensitic stainless steels 403, 410, precipitation hardenable 17-4 PH stainless steel and austenitic 321, 316LN stainless steel, which were made and supplied for applications to Indian nuclear industry. The expertise developed in processing the steels in terms of melting, heat treatment and their relationship to structural features and mechanical properties would be highlighted. (author)

A pilot plant study for CO{sub 2} capture by aqueous ammonia applied to blast furnace gas in iron and steel making process

Energy Technology Data Exchange (ETDEWEB)

Young Kim, J.; Han, K.; Dong Chun, H. [CO2 Project, Research Inst. of Industrial Science and Technology, Pohang (Korea, Republic of)

2009-07-01

This presentation reported on a study in which carbon dioxide (CO{sub 2}) was captured from a demonstration iron and steel plant using low concentration aqueous ammonia as the absorbent chemical. The pilot plant was designed to process 50 Nm{sup 3}/h of blast furnace gas (BFG). The feed gas contained more than 20 per cent CO{sub 2} at 35 to 60 degrees C. Test runs revealed that the absorption efficiency of CO{sub 2} exceeded 80 per cent with a CO{sub 2} purity of more than 90 per cent in the product stream. The process parameters are currently being studied along with the various salts needed to prevent salt precipitation. It was determined that the use of waste heat recovery technology in the iron and steel-making process can render ammonia-based CO{sub 2} capture technology more economically feasible for the reduction of CO{sub 2}.

Automated information system for analysis and prediction of production situations in blast furnace plant

Science.gov (United States)

Lavrov, V. V.; Spirin, N. A.

2016-09-01

Advances in modern science and technology are inherently connected with the development, implementation, and widespread use of computer systems based on mathematical modeling. Algorithms and computer systems are gaining practical significance solving a range of process tasks in metallurgy of MES-level (Manufacturing Execution Systems - systems controlling industrial process) of modern automated information systems at the largest iron and steel enterprises in Russia. This fact determines the necessity to develop information-modeling systems based on mathematical models that will take into account the physics of the process, the basics of heat and mass exchange, the laws of energy conservation, and also the peculiarities of the impact of technological and standard characteristics of raw materials on the manufacturing process data. Special attention in this set of operations for metallurgic production is devoted to blast-furnace production, as it consumes the greatest amount of energy, up to 50% of the fuel used in ferrous metallurgy. The paper deals with the requirements, structure and architecture of BF Process Engineer's Automated Workstation (AWS), a computer decision support system of MES Level implemented in the ICS of the Blast Furnace Plant at Magnitogorsk Iron and Steel Works. It presents a brief description of main model subsystems as well as assumptions made in the process of mathematical modelling. Application of the developed system allows the engineering and process staff to analyze online production situations in the blast furnace plant, to solve a number of process tasks related to control of heat, gas dynamics and slag conditions of blast-furnace smelting as well as to calculate the optimal composition of blast-furnace slag, which eventually results in increasing technical and economic performance of blast-furnace production.

Solid Fuel - Oxygen Fired Combustion for Production of Nodular Reduced Iron to Reduce CO2 Emissions and Improve Energy Efficiencies

Energy Technology Data Exchange (ETDEWEB)

Donald R. Fosnacht; Richard F. Kiesel; David W. Hendrickson; David J. Englund; Iwao Iwasaki; Rodney L. Bleifuss; Mathew A. Mlinar

2011-12-22

The current trend in the steel industry is an increase in iron and steel produced in electric arc furnaces (EAF) and a gradual decline in conventional steelmaking from taconite pellets in blast furnaces. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the market demands of the emerging steel industry while utilizing the existing infrastructure and materials handling capabilities. This demand creates opportunity to convert iron ore or other iron bearing materials to Nodular Reduced Iron (NRI) in a recently designed Linear Hearth Furnace (LHF). NRI is a metallized iron product containing 98.5 to 96.0% iron and 2.5 to 4% C. It is essentially a scrap substitute with little impurity that can be utilized in a variety of steelmaking processes, especially the electric arc furnace. The objective of this project was to focus on reducing the greenhouse gas emissions (GHG) through reducing the energy intensity using specialized combustion systems, increasing production and the use of biomass derived carbon sources in this process. This research examined the use of a solid fuel-oxygen fired combustion system and compared the results from this system with both oxygen-fuel and air-fuel combustion systems. The solid pulverized fuels tested included various coals and a bio-coal produced from woody biomass in a specially constructed pilot scale torrefaction reactor at the Coleraine Minerals Research Laboratory (CMRL). In addition to combustion, the application of bio-coal was also tested as a means to produce a reducing atmosphere during key points in the fusion process, and as a reducing agent for ore conversion to metallic iron to capture the advantage of its inherent reduced carbon footprint. The results from this study indicate that the approaches taken can reduce both greenhouse gas emissions and the associated energy intensity with the Linear Hearth Furnace process for converting

Environmental impacts of steel slag reused in road construction: A crystallographic and molecular (XANES) approach

Energy Technology Data Exchange (ETDEWEB)

Chaurand, Perrine [CEREGE, UMR 6635 CNRS, University Paul Cezanne, IFR 112 PMSE, Europole Mediterraneen de l' Arbois, BP 80, 13545 Aix en Provence Cedex 04 (France)]. E-mail: chaurand@cerege.fr; Rose, Jerome [CEREGE, UMR 6635 CNRS, University Paul Cezanne, IFR 112 PMSE, Europole Mediterraneen de l' Arbois, BP 80, 13545 Aix en Provence Cedex 04 (France); Briois, Valerie [LURE Laboratoire pour l' Utilisation du Rayonnement Electromagnetique, Universite Paris-Sud, Orsay (France); Olivi, Luca [Sincrotrone Trieste S.C.p.A. S.S., 14 Km 163.5, 34012 Basovizza Trieste (Italy); Hazemann, Jean-Louis [Laboratoire de Cristallographie, BP 166, 38042 Grenoble Cedex 09 (France); Proux, Olivier [Laboratoire de Geophysique Interne et de Tectonophysique, UMR CNRS Universite Joseph Fourier, 1381 rue de la piscine, Domaine Universitaire, 38400 St Martin d' Heres (France); Domas, Jeremie [INERIS, Domaine du petit Arbois, Batiment Laennec, BP 33, 13545 Aix en Provence Cedex 04 (France); Bottero, Jean-Yves [CEREGE, UMR 6635 CNRS, University Paul Cezanne, IFR 112 PMSE, Europole Mediterraneen de l' Arbois, BP 80, 13545 Aix en Provence Cedex 04 (France)

2007-01-31

Basic oxygen furnace (BOF) steel slag is a residue from the basic oxygen converter in steel-making operations, and is partially reused as an aggregate for road constructions. Although BOF slag is an attractive building material, its long-term behaviour and the associated environmental impacts must be taken into account. Indeed BOF slag is mainly composed of calcium, silicon and iron but also contains trace amounts of potential toxic elements, specifically chromium and vanadium, which can be released. The present research focuses (i) on the release of Cr and V during leaching and (ii) on their speciation within the bearing phase. Indeed the mobility and toxicity of heavy metals strongly depend on their speciation. Leaching tests show that only low amounts of Cr, present at relatively high concentration in steel slag, are released while the release of V is significantly high. X-ray absorption near-edge structure (XANES) spectroscopy indicates that Cr is present in the less mobile and less toxic trivalent form and that its speciation does not evolve during leaching. On the contrary, V which is predominantly present in the 4+ oxidation state seems to become oxidized to the pentavalent form (the most toxic form) during leaching.

Environmental impacts of steel slag reused in road construction: A crystallographic and molecular (XANES) approach

International Nuclear Information System (INIS)

Chaurand, Perrine; Rose, Jerome; Briois, Valerie; Olivi, Luca; Hazemann, Jean-Louis; Proux, Olivier; Domas, Jeremie; Bottero, Jean-Yves

2007-01-01

Basic oxygen furnace (BOF) steel slag is a residue from the basic oxygen converter in steel-making operations, and is partially reused as an aggregate for road constructions. Although BOF slag is an attractive building material, its long-term behaviour and the associated environmental impacts must be taken into account. Indeed BOF slag is mainly composed of calcium, silicon and iron but also contains trace amounts of potential toxic elements, specifically chromium and vanadium, which can be released. The present research focuses (i) on the release of Cr and V during leaching and (ii) on their speciation within the bearing phase. Indeed the mobility and toxicity of heavy metals strongly depend on their speciation. Leaching tests show that only low amounts of Cr, present at relatively high concentration in steel slag, are released while the release of V is significantly high. X-ray absorption near-edge structure (XANES) spectroscopy indicates that Cr is present in the less mobile and less toxic trivalent form and that its speciation does not evolve during leaching. On the contrary, V which is predominantly present in the 4+ oxidation state seems to become oxidized to the pentavalent form (the most toxic form) during leaching

The Synergistic Effect of Proteins and Reactive Oxygen Species on Electrochemical Behaviour of 316L Stainless Steel for Biomedical Applications

Science.gov (United States)

Simionescu, N.; Benea, L.; Dumitrascu, V. M.

2018-06-01

The stainless steels, especially 316L type is the most used metallic biomaterials for biomedical applications due to their good biocompatibility, low price, excellent corrosion resistance, availability, easy processing and high strength. Due to these favorable properties 316L stainless steel has become the most attractive biomaterial for dental implants, stents and orthopedic implants. However an implant material in the human body is exposed to an action effect of other molecules, including proteins (such as albumin) and reactive oxygen species (such as hydrogen peroxide - H2O2 ) produced by bacteria and immune cells. In the literature there are few studies to follow the effect of proteins and reactive oxygen species on 316L stainless steel used as implant material and are still unclear. The degree of corrosion resistance is the first criterion in the use of a metallic biomaterial in the oral or body environment. The aim of this research work is to investigate the influence of proteins (albumin) and reactive oxygen species (H2O2 ) in combination, taking into account the synergistic effect of these two factors on 316L stainless steel. Albumin is present in the body near implants and reactive oxygen species could appear in inflammatory processes as well. The study shows that the presence of albumin and reactive species influences the corrosion resistance of 316L stainless steel in biological solutions. In this research work the corrosion behavior of 316L stainless steel is analyzed by electrochemical methods such as: open circuit potential (OCP), Electrochemical Impedance Spectroscopy (EIS). It was found that, the electrochemical results are in a good agreement with micro photographs taken before and after corrosion assays. The albumin and reactive oxygen species have influence on 316L stainless steel behavior.

3-D Transient Heat Transfer Analysis of Slab Heating Characteristics in a Reheating Furnace in Hot Strip Mills

Science.gov (United States)

Jang, J. Y.; Lee, Y. W.; Lin, C. N.; Wang, C. H.

2016-05-01

A three-dimensional mathematical transient heat transfer model for the prediction of temperature distribution within the slab has been developed by considering the thermal radiation in the walking-beam-type reheating furnace chamber. The steel slabs are heated up through the non-firing, preheating, 1st-heating, 2nd-heating, and soaking zones in the furnace, respectively, where the furnace wall temperature is function of time. Comparison with the in-situ experimental data from Steel Company in Taiwan shows that the present heat transfer model works well for the prediction of thermal behavior of the slab in the reheating furnace. The effects of different skid button height (H=60mm, 90mm, and 120mm) and different gap distance between two slabs (S=50mm, 75mm, and 100mm) on the slab skid mark formation and temperature profiles are investigated. It is found that the skid mark severity decreases with an increase in the skid button height. The effect of gap distance is important only for the slab edge planes, while it is insignificant for the slab central planes.

AISI/DOE Technology Roadmap Program: Removal of Residual Elements in The Steel Ladle by a Combination of Top Slag and Deep Injection Practice

Energy Technology Data Exchange (ETDEWEB)

S. Street; K.S. Coley; G.A. Iron

2001-08-31

The objective of this work was to determine if tin could be removed from liquid steel by a combination of deep injection of calcium and a reducing top-slag practice. The work was carried out in three stages: injection of Ca wire into 35 Kg heats in an induction furnace under laboratory condition; a fundamental study of the solubility of Sn in the slag as a function of oxygen potential, temperature and slag composition; and, two full-scale plant trials. During the first stage, it was found that 7 to 50% of the Sn was removed from initial Sn contents of 0.1%, using 8 to 16 Kg of calcium per tonne of steel. The Sn solubility study suggested that low oxygen potential, high basicity of the slag and lower temperature would aid Sn removal by deep injection of Ca in the bath. However, two full-scale trials at the LMF station in Dofasco's plant showed virtually no Sn removal, mainly because of very low Ca consumption rates used (0.5 to 1.1 Kg/tonne vs. 8 to 16 Kg/tonne used during the induction furnace study in the laboratory). Based on the current price of Ca, addition of 8 to 16 Kg/tonne of steel to remove Sn is too cost prohibitive, and therefore, it is not worthwhile to pursue this process further, even though it may be technically feasible.

EFFECTS OF STEEL PLANTS WITH THREE-PHASE INDUCTION FURNACES ON POWER DISTRIBUTION QUALITY OF THE EXISTING 33 kV NETWORK IN NIGERIA

Directory of Open Access Journals (Sweden)

Saheed Lekan Gbadamosi

2015-08-01

Full Text Available This study aimed at evaluating and analyzing the voltage and current distortions on the introduction of a steel production plant in a typical 33 kV distribution system in Nigeria, with a view to assisting decisions made in the present system operation and planning effective service delivery in terms of quality. A three phase induction furnace was developed using MatLab Simulink software and the effects of steel plant loads on the quality of electric power system supply to electricity users on the same distribution network was analyzed in terms of total harmonic distortions of voltage and current. In order to evaluate voltage magnitude profile on the network, load flow computation and analyses were carried out on the 33 kV distribution network before and after the introduction of steel plant loads, using Successive Approximation Method. The results showed critical voltage magnitude profile below -5% of nominal voltage at the receiving end nodes. With the aid of the Matlab Simulink model, inadmissible voltage and current distortions of 15.47% and 10.35% were measured. Passive filter was proposed, designed and simulated, in order to mitigate these distortions caused by the steel production plant loads. By simulation, the installation of the designed passive filter gave a reduction of the distortions to permissible values. Further, for every 1 MW load increment when the steel plant is connected, network losses increased by 94%; however, for every of Mvar of filter capacity, loss reduction in the network is 5.1 MW.

Tribological effects of oxygen ion implantation into stainless steel

International Nuclear Information System (INIS)

Evans, P.J.; Vilaithong, T.; Yu, L.D.; Monteiro, O.R.; Yu, K.M.; Brown, I.G.

2000-01-01

The formation of sub-surface oxide layers by hybrid metal-gas co-implantation into steel and other metals can improve their tribological properties. In this report, we compare the wear and friction performance of previously studied Al + O hybrid implants with that produced by single species oxygen ion (O + ) implantation under similar conditions. The substrates were AISI 304L stainless steel discs polished to a final mirror finish using 1 μm diamond paste, and the ion implantation was done using a conventional swept-beam technique at ion energies of 70 or 140 keV and doses of up to 1x10 17 cm -2 . The wear and friction behaviour of the implanted and unimplanted material was measured with a pin-on-disc tribometer. Here we describe the experimental procedure and results, and discuss the improvement relative to that achieved with surface layers modified by metal-gas co-implantation

Effect of Microstructure on the Wear Behavior of Heat Treated SS-304 Stainless Steel

OpenAIRE

S. Kumar

2016-01-01

Sliding wear characteristics of some heat treated SS-304 stainless steel against EN-8 steel in dry condition have been studied in the present experimental work. Samples of SS-304 stainless steel have been heated in a muffle furnace in desired temperature and allowed to dwell for two hours. The heated specimen are then cooled in different media namely inside the furnace, open air, cutting grade oil (grade 44) and water at room temperature to obtain different grades of heat treatment. Microstr...

Innovation in electric arc furnaces scientific basis for selection

CERN Document Server

Toulouevski, Yuri N

2013-01-01

This book equips a reader with knowledge necessary for critical analysis of  innovations in electric arc furnaces and helps to select the most effective ones and for their successful implementation. The book also covers general issues related to history of development, current state and prospects of steelmaking in Electric Arc Furnaces. Therefore, it can be useful for everybody who studies metallurgy, including students of colleges and universities. The modern concepts of mechanisms of Arc Furnace processes are are discussed in the book at the level sufficient to solve practical problems: To help readers lacking knowledge required in the field of heat transfer as well as hydro-gas dynamics, it contains several chapters which provide the required minimum of information in these fields of science. In order to better assess different innovations, the book describes experience of the application of similar innovations in open-hearth furnaces and oxygen converters. Some promising ideas on key issues regarding int...

Oxygen and coke oven gas (COG) consumption optimization at hot stove of Usiminas blast furnace 3; Otimizacao do consumo de oxigenio e GCO nos regeneradores do alto forno 3 da Usiminas

Energy Technology Data Exchange (ETDEWEB)

Cervino, Marco Antonio; Bastos, Moises Hofer [Usiminas, Ipatinga, MG (Brazil)

2001-07-01

This paper presents the model developed for determination of the correlation between oxygen and coke oven gas (COG) consumption in the hot stove at Usiminas blast furnace 3, the applicability and results obtained. (author)

A Feasibility Study for Recycling Used Automotive Oil Filters In A Blast Furnace

Energy Technology Data Exchange (ETDEWEB)

Ralph M. Smailer; Gregory L. Dressel; Jennifer Hsu Hill

2002-01-21

This feasibility study has indicated that of the approximately 120,000 tons of steel available to be recycled from used oil filters (UOF's), a maximum blast furnace charge of 2% of the burden may be anticipated for short term use of a few months. The oil contained in the most readily processed UOF's being properly hot drained and crushed is approximately 12% to 14% by weight. This oil will be pyrolized at a rate of 98% resulting in additional fuel gas of 68% and a condensable hydrocarbon fraction of 30%, with the remaining 2% resulting as carbon being added into the burden. Based upon the writer's collected information and assessment, there appears to be no operational problems relating to the recycling of UOF's to the blast furnace. One steel plant in the US has been routinely charging UOF's at about 100 tons to 200 tons per month for many years. Extensive analysis and calculations appear to indicate no toxic consideration as a result of the pyrolysis of the small contained oil ( in the 'prepared' UOFs) within the blast furnace. However, a hydrocarbon condensate in the ''gasoline'' fraction will condense in the blast furnace scrubber water and may require additional processing the water treatment system to remove benzene and toluene from the condensate. Used oil filters represent an additional source of high quality iron units that may be effectively added to the charge of a blast furnace for beneficial value to the operator and to the removal of this resource from landfills.

Corrosion resistance of chromium-nickel steel containing rare earths

International Nuclear Information System (INIS)

Asatiani, G.N.; Mandzhgaladze, S.N.; Tavadze, L.F.; Chuvatina, S.N.; Saginadze, D.I.

1983-01-01

Effect of additional out-of-furnace treatment with complex alloy (foundry alloy) calcite-silicon-magnesium-rare earth metal on corrosion resistance of the 03Kh18N20M3D3C3B steel has been studied. It is shown that introduction of low additions of rare earths improves its corrosion resistance improves its corrosion resistance in agressive media (in 70% - sulfuric acid) in the range of transition from active to passive state. Effect of additional introduction of rare earth metals is not considerable, if potential of steel corrosion is in the range of stable passive state (32% - sulfuric acid). Additional out-of-furnace treatment with complex foundry alloy, containing rare earth metals, provides a possibility to use a steel with a lower content of Cr, Ni, Mo, than in conventional acid-resistant steels in highly agressive media

Solubility of corrosion products of plain steel in oxygen-containing water solutions at high parameters

International Nuclear Information System (INIS)

Martynova, O.I.; Samojlov, Yu.F.; Petrova, T.I.; Kharitonova, N.L.

1983-01-01

Technique for calculation of solubility of iron corrosion products in oxygen-containing aqueous solutions in the 298-573 K temperature range is presented. Solubility of corrosion products of plain steel in deeply-desalinizated water in the presence of oxygen for the such range of the temperatures is experimentally determined. Rather good convergence between calculated and experimental data is noted

Efficient use of power in electric arc furnaces

Energy Technology Data Exchange (ETDEWEB)

Freeman, E R; Medley, J E

1978-02-01

The maximum transfer of electric energy to the metal in an arc furnace depends on the length of arc and the impedance of the electrical supply system from the generators to the arc itself. The use of directly-reduced sponge iron by continuous feeding results in long periods of flat-bath operation, when it is particularly important to keep a short high-current arc to get the heat into the metal rather than to the refractories, which would suffer excessive wear. By reference to a 125 ton furnace, a method of assessing the optimum operating currents and power factors and the effects of differing power-supply systems is illustrated. The importance of a low-impedance power system is illustrated, and the possibility of being unable to use the maximum furnace power without excessive refractory wear is noted. The particular problems of connecting arc-furnace loads to electrical supply systems are reviewed, and consideration is given to the problem of voltage flicker. The use of compensators is discussed with reference to existing installations, in which strong supplies from the supply-authority system are not economically available. The furnace operating characteristics, which indicate the optimum points of working, have to be checked on commissioning, and the test procedures are outlined. The optimum points for each type of charge and steel can be assessed only during their actual production. The importance of proper recording of relevant data is stressed, and reference is made to the use of computers and automatic power-input controllers.

Simulation of a DC electric arc furnace for steelmaking: study in the arc and bath regions

International Nuclear Information System (INIS)

Ramirez Argaez, M. A.; Trapaga Martinez, L. G.

2001-01-01

A mathematical model was developed to describe fluid flow, heat transfer, and electromagnetic phenomena in the arc and bath regions of DC electric Arc Furnaces (DC-EAF). The model is used to examine the effect on flow patterns and temperature distribution in the bath, under the influence of both an arc and bottom argon injection in steel or steel/slag systems. Validation of the model employed experimental measurements from systems physically related to DC-EAF from literature. For the conditions analyzed, electromagnetic forces dominate the fluid motion in the bath. Buoyancy and shear forces from the arc have a negligible effect in driving the flow; however, they partially counteract the electromagnetic forces. Slag decreases fluid motion in the steel and enhances temperature stratification in the system. Stirring of the bath, using a 3-nozzle inert gas injection system, is found to promote temperature uniformity in the regions near the lateral wall of the furnace. (Author) 24 refs

Reduction of heat losses on the skid pipe system of reheating furnaces in the steel industry; Verringerung der Waermeverluste am Tragrohrsystem von Waermeoefen in der Stahlindustrie

Energy Technology Data Exchange (ETDEWEB)

Springer, Michael; Huegel, Frank [FBB Engineering GmbH, Moenchengladbach (Germany)

2011-06-15

New technology can improve the energy efficiency of thermo processing equipment, innovative technology can ultimately help to reduce CO{sub 2} emissions from existing facilities and simultaneously ensure that the equipment can also operate more economically. The result of consequent development at FBB ENGINEERING GmbH for insulation of skid pipe systems of reheating furnaces in steel industry (walking beam -, pusher type furnace) are efficient pre-fabricated shells made of ultra-light weight castable FLB-11/150-I1 with thermo technical optimized sandwich design that lead to significant and sustainable reduction of heat losses and are responsible for high energy saving potential. Thermo technical CFD simulations, laboratory tests, field trials and complete installations of skid pipe systems show that compared to dense castable heat loss in the skid pipe cooling systems can be reduced up to 30 % and more with pre-fabricated shells made of ultra-light weight castable FLB-11/150-I1. (orig.)

Theoretical-Experimental study on the electroslag remelting technology of high quality steels

International Nuclear Information System (INIS)

Robles P, E.F.

1993-01-01

This is a theoretical-experimental laboratory study on the Electroslag Remelting Technology (ESRT) of high quality steels. The objective of this study was to analyze the problems that this technology entails and thus facilitate its industrial application in Mexico. The study was carried out using a 1 Kg. capacity furnace, the behavior of different fluxes on the remelting of 1018 AISI carbon steel was established and a slag 70F/15/15 was selected for the remelting of H-13 AISI hot work tool steel. From the experimental results it was possible to establish a flux manufacture route, the electrode conditioning necessary for the experiments, and the critical points of the process. It was demonstrated that the crucible and electrode advance system are the more critical points in the furnace manufacture, that the start up is fundamental for the remelting continuity and that the CaF 2 base slags are more recommendable for special steels refining. It has been proven that it is possible to experiment with little laboratory electroslag furnaces. (Author)

Leaching of Carbothermic Reduced Titanium-bearing Blast Furnace Slag by Acid

Institute of Scientific and Technical Information of China (English)

ZHEN Yulan; ZHANG Guohua; CHOU Kuochih

2016-01-01

The kinetics of the leaching of carbothermic reduced titanium-bearing blast furnace slag in Panzhihua Iron and Steel Company with acid system under atmosphere pressure was studied. The results show that the temperature and concentration have significant influence on leaching of carbothermic reduced titanium-bearing blast furnace slag by ac-id. The experimental data of leaching indicate that the shrinking core model with chemical reaction controlled process is most applicable for the acid leaching. The apparent activation energy can be estimated to be from 23 to 32 kJ/mol. Fur-thermore, the main products are TiC and SiO2 after leaching.

Kinetics of steel slag leaching: Batch tests and modeling

International Nuclear Information System (INIS)

De Windt, Laurent; Chaurand, Perrine; Rose, Jerome

2011-01-01

Reusing steel slag as an aggregate for road construction requires to characterize the leaching kinetics and metal releases. In this study, basic oxygen furnace (BOF) steel slag were subjected to batch leaching tests at liquid to solid ratios (L/S) of 10 and 100 over 30 days; the leachate chemistry being regularly sampled in time. A geochemical model of the steel slag is developed and validated from experimental data, particularly the evolution with leaching of mineralogical composition of the slag and trace element speciation. Kinetics is necessary for modeling the primary phase leaching, whereas a simple thermodynamic equilibrium approach can be used for secondary phase precipitation. The proposed model simulates the kinetically-controlled dissolution (hydrolysis) of primary phases, the precipitation of secondary phases (C-S-H, hydroxide and spinel), the pH and redox conditions, and the progressive release of major elements as well as the metals Cr and V. Modeling indicates that the dilution effect of the L/S ratio is often coupled to solubility-controlled processes, which are sensitive to both the pH and the redox potential. A sensitivity analysis of kinetic uncertainties on the modeling of element releases is performed.

Zone modelling of the thermal performances of a large-scale bloom reheating furnace

International Nuclear Information System (INIS)

Tan, Chee-Keong; Jenkins, Joana; Ward, John; Broughton, Jonathan; Heeley, Andy

2013-01-01

This paper describes the development and comparison of a two- (2D) and three-dimensional (3D) mathematical models, based on the zone method of radiation analysis, to simulate the thermal performances of a large bloom reheating furnace. The modelling approach adopted in the current paper differs from previous work since it takes into account the net radiation interchanges between the top and bottom firing sections of the furnace and also allows for enthalpy exchange due to the flows of combustion products between these sections. The models were initially validated at two different furnace throughput rates using experimental and plant's model data supplied by Tata Steel. The results to-date demonstrated that the model predictions are in good agreement with measured heating profiles of the blooms encountered in the actual furnace. It was also found no significant differences between the predictions from the 2D and 3D models. Following the validation, the 2D model was then used to assess the impact of the furnace responses to changing throughput rate. It was found that the potential furnace response to changing throughput rate influences the settling time of the furnace to the next steady state operation. Overall the current work demonstrates the feasibility and practicality of zone modelling and its potential for incorporation into a model based furnace control system. - Highlights: ► 2D and 3D zone models of large-scale bloom reheating furnace. ► The models were validated with experimental and plant model data. ► Examine the transient furnace response to changing the furnace throughput rates. ► No significant differences found between the predictions from the 2D and 3D models.

Furnaces. The manufacturer turns to the engineering office; Les fours. Le constructeur devient bureau d`ingenierie

Energy Technology Data Exchange (ETDEWEB)

Nivoche, C. [Selas SA, 92 - Gennevilliers (France)

1997-12-31

This paper describes the actions carried out by the Selas company involved in the manufacturing of industrial furnaces in order to respect the environmental regulations of the French 2910 by-law: particularity of industrial furnaces, activities of the Selas company (surface cleaning process for iron and stainless steel sheets, quenching of glass panes), reduction of dust, SO{sub x}, NO{sub x} and organic compound emissions from combustion systems and burners. (J.S.)

Energy efficiency and the influence of gas burners to the energy related carbon dioxide emissions of electric arc furnaces in steel industry

International Nuclear Information System (INIS)

Kirschen, Marcus; Risonarta, Victor; Pfeifer, Herbert

2009-01-01

Determining the complete energy balance of an electric arc furnace (EAF) provides an appropriate method to examine energy efficiency and identify energy saving potentials. However, the EAF energy balance is complex due to the combined input of electrical energy and chemical energy resulting from natural gas (NG) combustion and oxidation reactions in the steel melt. In addition, furnace off-gas measurements and slag analysis are necessary to reliably determine energy sinks. In this paper 70 energy balances and energy efficiencies from multiple EAFs are presented, including data calculated from plant measurements and compiled from the literature. Potential errors that can be incorporated in these calculations are also highlighted. The total energy requirement of these modern EAFs analysed ranged from 510 to 880 kWh/t, with energy efficiency values (η = ΔH Steel /E Total ) of between 40% and 75%. Furthermore, the focus was placed on the total energy related CO 2 emissions of EAF processes comprising NG combustion and electrical energy input. By assessing multiple EAF energy balances, a significant correlation between the total energy requirement and energy related specific CO 2 emissions was not evident. Whilst the specific consumption of NG in the EAF only had a minor impact on the EAF energy efficiency, it decreased the specific electrical energy requirement and increased EAF productivity where transformer power was restricted. The analysis also demonstrated that complementing and substituting electrical energy with NG was beneficial in reducing the total energy related CO 2 emissions when a certain level of substitution efficiency was achieved. Therefore, the appropriate use of NG burners in modern EAFs can result in an increased EAF energy intensity, whilst the total energy related CO 2 emissions remain constant or are even decreased.

Creep-rupture tests on chromium-containing conventional and ODS steels in oxygen-controlled Pb and air at 650 °C

International Nuclear Information System (INIS)

Yurechko, Mariya; Schroer, Carsten; Wedemeyer, Olaf; Skrypnik, Aleksandr; Konys, Jürgen

2014-01-01

Highlights: • Generally superior creep performance of ODS steels with 12–14% Cr is indicated. • Strength of 9Cr-ODS at 650°C approaches conventional 9Cr steels at decreasing load. • ODS steels show brittle primary and ductile residual fracture. • Apparent link between secondary creep rate and fracture mode of ODS steels. • Clear impact of liquid Pb at low load, corresponding to long time-to-rupture. - Abstract: Conventional martensitic steels with 9 mass% chromium (Cr), namely T91 and P92, and ODS steels with 9, 12 and 14 mass% Cr, respectively, were subjected to creep-rupture tests in stagnant oxygen-controlled lead (Pb) at 650 °C and c o = 10 −6 mass% dissolved oxygen. The 9Cr conventional steels were tested in the liquid metal at static engineering stress in the range from 75 to 200 MPa. 12 and 14Cr ODS were tested at 190–400 MPa, and 9Cr ODS at 75–300 MPa. Reference tests in stagnant air were carried out in the same stress ranges. The ODS steels with 12 or 14 mass% Cr, mainly tested in oxygen containing Pb, clearly exhibit a change in the stress-dependence of secondary creep rate and appearance of fracture surface at 330–400 MPa. No such change has been observed for 9Cr ODS so far. The conventional martensitic steel P92 shows a significant drop in creep strength accompanied by reduced necking and a change from ductile to brittle fracture when tested in Pb at 75 MPa (time-to-rupture t R = 13,090 h)

Producción de aceros al carbono en hornos de arco eléctrico en condiciones de mineral de manganeso. // Steel production in electric arc furnaces in the condition of use of manganese.

Directory of Open Access Journals (Sweden)

E. E. Navas Medina

2007-05-01

Full Text Available El presente trabajo constituye una segunda etapa de investigación relacionada con la producción de acero en hornos de arcoeléctrico con revestimiento básico en condiciones de utilización de mineral de manganeso como sustituto del ferromanganeso.En la investigación se caracteriza el acero producido utilizando el mineral de manganeso en dos variantes tecnológicasdiferentes y se determinan parámetros importantes, tales como la estructura del acero obtenido, la influencia de lacomposición química y la temperatura en la reducción del Mn. Adicionalmente, se determina la composición química de laescoria, su basicidad e influencia en el aprovechamiento del Mn del mineral, así como, lo que significa la sustitución delFeMn en la problemática medioambiental.Palabras claves: Producción de aceros al carbono, hornos de arco eléctricos, mineral de manganeso.______________________________________________________________________________Abstract:This present work constitutes the second stage of investigation in relation with the steel production bymeans of electric arc furnaces in the condition of use of manganese ores as a substitute of theferromanganese. In the investigation, the steel manufactured is analyzed the manganese ore in twodifferent technological variants and some important parameters are determined such as: the chemicalcomposition's structure of the steel, the influence of temperature in the reduction of Mn. Moreover, ananalysis of the chemical composition of the slag and the influence in the environmental is realized.Key words: Carbon steel production, electric arc furnaces, manganese mineral.

Steel refining possibilities in LF

Science.gov (United States)

Dumitru, M. G.; Ioana, A.; Constantin, N.; Ciobanu, F.; Pollifroni, M.

2018-01-01

This article presents the main possibilities for steel refining in Ladle Furnace (LF). These, are presented: steelmaking stages, steel refining through argon bottom stirring, online control of the bottom stirring, bottom stirring diagram during LF treatment of a heat, porous plug influence over the argon stirring, bottom stirring porous plug, analysis of porous plugs disposal on ladle bottom surface, bottom stirring simulation with ANSYS, bottom stirring simulation with Autodesk CFD.

Effect of cast steel production metallurgy on the emergence of casting defects

Directory of Open Access Journals (Sweden)

L. Čamek

2016-10-01

Full Text Available The paper documents metallurgical possibilities of high alloy cast steel production in open induction medium frequency furnaces and an electric arc furnace in a gravity die casting foundry. The observation was focused on the emergence of gas defects in steel castings. The content of gases achieved during the metallurgical processes was evaluated for every unit of the production equipment and the casting ladle before casting into disposable sand moulds. The sand mould area was considered to be constant. The aim was to evaluate the current metallurgical possibilities of affecting the content of gases in high alloy cast steel in the current technical conditions of the foundry.

Computer simulation of processes in the dead–end furnace

International Nuclear Information System (INIS)

Zavorin, A S; Khaustov, S A; Zaharushkin, Russia N A

2014-01-01

We study turbulent combustion of natural gas in the reverse flame of fire–tube boiler simulated with the ANSYS Fluent 12.1.4 engineering simulation software. Aerodynamic structure and volumetric pressure fields of the flame were calculated. The results are presented in graphical form. The effect of the twist parameter for a drag coefficient of dead–end furnace was estimated. Finite element method was used for simulating the following processes: the combustion of methane in air oxygen, radiant and convective heat transfer, turbulence. Complete geometric model of the dead–end furnace based on boiler drawings was considered

Assessment of uniform temperature assumption in zoning on the numerical simulation of a walking beam reheating furnace

International Nuclear Information System (INIS)

Morgado, Tiago; Coelho, Pedro J.; Talukdar, Prabal

2015-01-01

The numerical simulation of the heating process of steel slabs in a walking beam reheating furnace is reported using two different models. In one model, the turbulent reactive flow in the furnace is simulated together with the heat conduction in the slabs. The calculations are performed using a commercial code and a user-defined function is used to simulate the periodic movement of the slabs by the walking beams in the furnace. Unsteady calculations are performed until a periodic transient solution is achieved. In the second model, the furnace is divided into a small number of zones and the average temperature and chemical composition are prescribed in every zone based on the results of the first model. The unsteady heating process of the slabs is modeled using the same software and accounting for radiative transfer in the furnace and heat conduction in the slabs. The results of the first model are taken as a benchmark for the second one. It is shown that the first model predicts radiative heat fluxes and temperatures of the slabs that are consistent with previous work. The two models yield volume average temperatures of the slabs leaving the furnace that differ by less than 3%, provided that accurate values of the temperature of the gases and walls are used. The second model is computationally more economical, requiring only about 5% of the computational time of the first one. - Highlights: • The heating process of steel slabs in a reheating furnace is numerically simulated. • Unsteady calculations accounting for the periodic movement of the slabs are reported. • We compare two models differing on how the thermochemical composition is obtained. • The models predict mean slab temperatures at the exit that differ by less than 3%. • The computational time of the fastest model is only about 5% of the slowest one

Final Environmental Impact Statement Permit Application by United States Steel Corp. Proposed Lake Front Steel Mill, Conneaut, Ohio. Volume 1,

Science.gov (United States)

1979-04-01

substrate (bottom) in an aquatic environment. Biochemical Oxygen Demand (BOD) - The amount of dissolved oxygen required to meet the metabolic needs of...Furnace & Ladle Lining Removal 6 Dempster Dinosaur Diesel Scrap Box Handling 1 Lift-A-Loft Propane Maintenance Scaffold 2 Breezewagon Furnace Cooling 1...10,000 lb Electric Miscellaneous (Battery) Roll Shop 2 Dempster Dinosaur 15 cu yd - Diesel Scale Handling 30 ton (incl. Plate Mill) 3 Motor Scooter 4

Process of coke less without waste treatment of direct vanadium allowing steel melting

International Nuclear Information System (INIS)

Lisienko, V.G.; Droujinina, O.G.; Morozova, V.A.; Ladigina, N.V.; Yusfin, Yu.S.; Parenkev, A.E.

2003-01-01

The development of new methods of steel production are now conducted with the purpose of energy consumption and harmful emissions reduction. The choice of technology and equipment in this case plays a marginal role. It is well known that vanadium alloying steel has increased service properties. The known classical scheme of vanadium steel melting is very power-intensive, as includes such power-intensive processes as blast furnace process and chemical processing of vanadium slag therewith sintering and by-product coke processes are accompanied by significant harmful emissions. In so doing the vanadium losses may run to 60%. In view of requests of environment protection and economical efficiency the new process of coke less without wastes processing of vanadium-bearing raw material with direct vanadium allowing of steel - LP-process is developed. Its purpose is the melting on the basis of vanadium-bearing titanomagnetite of vanadium allowing steel with increase of vanadium concentration in steel and diminution of vanadium losses without application coke and natural gas with use of any coals and carbon-bearing wastes. LP-process consists of three aggregates and corresponding processes: process of liquid-phase reduction, process of vanadium-bearing pellets metallization in the shaft furnace, and process of alloying steel melting in the arc electric furnace. The obtained results have shown, that the LP-process is more energy saving on a comparison with other methods of vanadium allowing steel production. (Original)

Technological indicators of operation of the rotating-hearth furnace in conditions of discontinued production

Directory of Open Access Journals (Sweden)

Lazić, L.

2008-04-01

Full Text Available Quality heating of the steel charge to be rolled into seamless tubes in the rotating-hearth furnace requires continuous operation of the pilger mill. Interruption of the charging schedule leads to impaired charge heating process. Prolonged heating time causes a rise in the charge temperature above the limit values, and that in turn brings to a larger quantity of scale formed on the charge surface. Final result is loss of metal and overheating of the charge accompanied by increased fuel consumption and lower furnace productivity.

General and localized corrosion of carbon and low-alloy steels in oxygenated high-temperature water. Final report

International Nuclear Information System (INIS)

Macdonald, D.D.; Smialowska, S.; Pednekar, S.

1983-02-01

The susceptibilities to stress corrosion cracking (SCC) of two carbon steels, SA106-grB and SA333-gr6, which are used in seamless BWR piping, and a low-alloy pressure vessel steel, A508-C12, were studied in high purity water as a function of oxygen concentration (0.16 to 8 ppM) and temperature (50 to 288 0 C) . The susceptibility to SCC was measured using the slow strain rate technique. The fracture surfaces of the test specimens were also examined using SEM to determine the mode of failure. In water containing 1 and 8 ppM oxygen and at temperatures above 135 0 C, transgranular stress corrosion cracking (TGSCC) was observed to occur in A508-C12, SA333-gr6 and SA106grB steels at very high stresses. The susceptibility to SCC increased with temperature

Heat-electrical regeneration way to intensive energy saving in an electric arc furnaces

Science.gov (United States)

Kartavtcev, S.; Matveev, S.; Neshporenko, E.

2018-03-01

Energy saving in steel production is of great significance for its large economical scale of 1500 mil t/year and high-energy consumption. Steady trend of last years is an increase of steel production in electric arc furnaces (EAF) with a very high consumption of electricity up to 750 kWh/ton. The intention to reduce so much energy consumption they can reach by many ways. One of such way is a transforming heat energy of liquid steel to electricity and destine it to steel electric arc process. Under certain conditions, it may lead to “zero” consumption of electric power in the process. The development of these conditions leads to the formation of energy-efficient heat schemes, with a minimum electricity consumption from the external network.

Effect of melting technique on grain size and heat resistance of the 12Kh1MF steel

International Nuclear Information System (INIS)

Lanskaya, K.A.; Kulikova, L.V.; Butneva, N.I.

1978-01-01

Investigated are the 12Kh1MF steel melted in open-hearth and arc furnaces (deoxidation by aluminium in 1.0 kg/t quantity) and then subjected to electroslag melting. The size of an austenitic grain depends on the residual contents of nitrogen and aluminium in steel. The open-hearth metal subjected to electroslag melting and containing a small quantity of nitrogen (0.006%) and aluminium (0.013%) has coarse austenitic grains and higher heat resistance compared to the steel melted in an arc furnace and also sub ected to electroslag melting. The nitride analysis of steel is carried out

Study of the decarburization of 18-8 stainless steel by oxygen at low pressure

International Nuclear Information System (INIS)

Armand, G.; Lapujoulade, J.

1964-01-01

The kinetic of the decarburization of a 18-8 stainless-steel by oxygen at low pressure has been studied between 1050 and 1200 C. The measurement of the carbon content of the sample is carried out by chemical analysis. Three mechanisms take place in that decarburization: diffusion of carbon in the steel; velocity at the superficial reaction C + 1/2 O 2 ↔ CO; pumping out of CO. The second mechanism seems to govern the overall kinetic. The activation energy of the phenomenon is 108 ± 24 Kcal/mole. (authors) [fr

Adsorption Study of Electric Arc Furnace Slag for the Removal of Manganese from Solution

OpenAIRE

C. L. Beh; Luqman Chuah; Thomas S.Y. Choong; Mohd. Z.B. Kamarudzaman; Khalina Abdan

2010-01-01

Problem statement: Steel making slag from Electric Arc Furnace (EAF) is an abundant by-product in Malaysia steel making industry. It has potential to be used for heavy metal removal from contaminated water or waste water. Approach: The aim of this study was to investigate the characteristic and behavior of manganese removal by using EAF slag for efficient metal removal. The removal characteristics of manganese were investigated in term of sorption kinetics and isotherm. The batch adsorption k...

A Simple Experiment To Measure the Content of Oxygen in the Air Using Heated Steel Wool

Science.gov (United States)

Vera, Francisco; Rivera, Rodrigo; Nunez, Cesar

2011-01-01

The typical experiment to measure the oxygen content in the atmosphere uses the rusting of steel wool inside a closed volume of air. Two key aspects of this experiment that make possible a successful measurement of the content of oxygen in the air are the use of a closed atmosphere and the use of a chemical reaction that involves the oxidation of…

Fiscal 1999 technical survey report. Model project implementation feasibility study in India on effective utilization of blast furnace gas pressure energy; 1999 nendo Indo ni okeru koro gas atsuryoku energy yuko riyo model jigyo jisshi kanosei chosa hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

From the viewpoint of energy utilization stated above, blast furnace top pressure recovery turbine (TRT) unit installability was studied at Bhilai Steel Works of Steel Authority of India, Ltd., Bokaro Steel Works of Steel Authority of India, Ltd., and Visakhapatnum Steel Works of Rashtriya Ispat Nigem. The energy consumption rate at an Indian steelmaking plant is 8Gcal/t-steel, which is larger than 5-6Gcal/t-steel of Japan and therefore needs improvement. Out of the blast furnaces in India, 26 are larger than 1,000m{sup 3}, and two of them are provided with a TRT device of now-defunct Soviet Union manufacture. The blast furnaces were examined for pressure at the top, amount of gas at the top, amount of dust, and safeness in operation. The No. 2 blast furnace of the Borkaro plant was selected for the project, and studies were made for a wet type TRT device. Improvements to be achieved by TRT device installation were calculated to be a TRT output of 5,900kW, power output of 49,100MWh/year, saved crude oil amount of 12,990toe/year, and CO2 reduction of 40,200 tons-CO2/year. (NEDO)

Thermal performance evaluation of a four pan jaggery processing furnace for improvement in energy utilization

Energy Technology Data Exchange (ETDEWEB)

Sardeshpande, Vishal R.; Shendage, D.J.; Pillai, Indu R. [Department of Energy Science and Engineering, Indian Institute of Technology, Bombay (India)

2010-12-15

The jaggery making from sugarcane is one of the traditional process industries contributing to the local employment and entrepreneurship opportunities to the rural population. Jaggery is a condensed form of sugarcane juice produced by evaporation of moisture. Bagasse which is internally generated during juice extraction from sugarcane is used as the fuel for evaporation in a jaggery furnace. Any efficiency improvement in the thermal performance of a jaggery furnace leads to bagasse saving which provides additional revenue for the jaggery manufacturer. A procedure for thermal evaluation using mass and energy balance for a jaggery furnace is proposed to establish furnace performance and loss stream analysis. The proposed method is used to investigate a four pan traditional jaggery furnace in India. The loss stream analysis indicates that the theoretical energy required for jaggery processing is only 29% of total energy supplied by bagasse combustion. The major loss is associated with heat carried in flue gas and wall losses. The air available for combustion depends upon the draft created by chimney in natural draft furnaces. The oxygen content in the flue gas is a measure of degree of combustion. A controlled fuel feeding based on the oxygen percentage in the flue gases is proposed and demonstrated. The traditional practice of fuel feeding rate is changed to control feeding rate leading to reduction in specific fuel consumption from 2.39 kg bagasse/kg jaggery to 1.73 kg bagasse/kg jaggery. This procedure can be used for evaluation of jaggery furnaces for identification and quantification of losses, which will help in improving thermal energy utilization. (author)

Electric Arc Furnace Modeling with Artificial Neural Networks and Arc Length with Variable Voltage Gradient

Directory of Open Access Journals (Sweden)

Raul Garcia-Segura

2017-09-01

Full Text Available Electric arc furnaces (EAFs contribute to almost one third of the global steel production. Arc furnaces use a large amount of electrical energy to process scrap or reduced iron and are relevant to study because small improvements in their efficiency account for significant energy savings. Optimal controllers need to be designed and proposed to enhance both process performance and energy consumption. Due to the random and chaotic nature of the electric arcs, neural networks and other soft computing techniques have been used for modeling EAFs. This study proposes a methodology for modeling EAFs that considers the time varying arc length as a relevant input parameter to the arc furnace model. Based on actual voltages and current measurements taken from an arc furnace, it was possible to estimate an arc length suitable for modeling the arc furnace using neural networks. The obtained results show that the model reproduces not only the stable arc conditions but also the unstable arc conditions, which are difficult to identify in a real heat process. The presented model can be applied for the development and testing of control systems to improve furnace energy efficiency and productivity.

Recycling of electric arc furnace dust

International Nuclear Information System (INIS)

Marques Sobrinho, Vicente de Paulo Ferreira; Oliveira, Jose Roberto de; Tenorio, Jorge Alberto Soares; Espinosa, Denise Crocce Romano

2010-01-01

This research aims to study the process of incorporation of the metal iron in electric arc furnace dust (EAFD), from a steel mill producing long steel by liquid iron in addition to the changing temperature of 1400 degrees Celsius of EAFD 'as received', the percentage of EAFD to be added (5, 10 and 20% of initial weight of sample pig iron) and the time of withdrawal of the sample of pig iron and slag (30 minutes after the addition of EAFD). Previously, the EAFD will be characterized using the following techniques: chemical analysis, size analysis, specific surface area, Xray diffraction, scanning electron microscopy (SEM) and Energy Dispersive Spectroscopy (EDS) microanalysis. . After characterization, the EAFD will be added to the bath of liquid pig iron. It is expected that the results obtained at the end of the research allow the evaluation of the iron metal incorporation of EAFD in pig iron bath. (author)

New heating schedule in hydrogen annealing furnace based on process simulation for less energy consumption

International Nuclear Information System (INIS)

Saboonchi, Ahmad; Hassanpour, Saeid; Abbasi, Shahram

2008-01-01

Cold rolled steel coils are annealed in batch furnaces to obtain desirable mechanical properties. Annealing operations involve heating and cooling cycles which take long due to high weight of the coils under annealing. To reduce annealing time, a simulation code was developed that is capable of evaluating more effective schedules for annealing coils during the heating process. This code is additionally capable of accurate determination of furnace turn-off time for different coil weights and charge dimensions. After studying many heating schedules and considering heat transfer mechanism in the annealing furnace, a new schedule with the most advantages was selected as the new operation conditions in the hydrogen annealing plant. The performance of all the furnaces were adjusted to the new heating schedule after experiments had been carried out to ensure the accuracy of the code and the fitness of the new operation condition. Comparison of similar yield of cold rolled coils over two months revealed that specific energy consumption of furnaces under the new heating schedule decreased by 11%, heating cycle time by 16%, and the hydrogen consumption by 14%

New heating schedule in hydrogen annealing furnace based on process simulation for less energy consumption

Energy Technology Data Exchange (ETDEWEB)

Saboonchi, Ahmad [Department of Mechanical Engineering, Isfahan University of Technology, Isfahan 84154 (Iran); Hassanpour, Saeid [Rayan Tahlil Sepahan Co., Isfahan Science and Technology Town, Isfahan 84155 (Iran); Abbasi, Shahram [R and D Department, Mobarakeh Steel Complex, Isfahan (Iran)

2008-11-15

Cold rolled steel coils are annealed in batch furnaces to obtain desirable mechanical properties. Annealing operations involve heating and cooling cycles which take long due to high weight of the coils under annealing. To reduce annealing time, a simulation code was developed that is capable of evaluating more effective schedules for annealing coils during the heating process. This code is additionally capable of accurate determination of furnace turn-off time for different coil weights and charge dimensions. After studying many heating schedules and considering heat transfer mechanism in the annealing furnace, a new schedule with the most advantages was selected as the new operation conditions in the hydrogen annealing plant. The performance of all the furnaces were adjusted to the new heating schedule after experiments had been carried out to ensure the accuracy of the code and the fitness of the new operation condition. Comparison of similar yield of cold rolled coils over two months revealed that specific energy consumption of furnaces under the new heating schedule decreased by 11%, heating cycle time by 16%, and the hydrogen consumption by 14%. (author)

Energy management system for an integrated steel plant

Energy Technology Data Exchange (ETDEWEB)

Perti, A.K.; Sankarasubramian, K.; Shivramakrishnan, J. (Bhilai Steel Plant, Bhilai (India))

1992-09-01

The cost of energy contributes 35 to 40% to the cost of steel production. Thus a lot of importance is being given to energy conservation in steel production. The paper outlines energy conservation measures at the Bhilai Steel Plant, India. Measures include: modifications to furnaces; partial briquetting of coal charge; and setting up an energy centre to integrate measurement and computer systems with despatches, engineers and managers of energy. 4 refs., 4 figs., 3 tabs.

Multiphase Modeling of Bottom-Stirred Ladle for Prediction of Slag-Steel Interface and Estimation of Desulfurization Behavior

Science.gov (United States)

Singh, Umesh; Anapagaddi, Ravikiran; Mangal, Saurabh; Padmanabhan, Kuppuswamy Anantha; Singh, Amarendra Kumar

2016-06-01

Ladle furnace is a key unit in which various phenomena such as deoxidation, desulfurization, inclusion removal, and homogenization of alloy composition and temperature take place. Therefore, the processes present in the ladle play an important role in determining the quality of steel. Prediction of flow behavior of the phases present in the ladle furnace is needed to understand the phenomena that take place there and accordingly control the process parameters. In this study, first a mathematical model is developed to analyze the transient three-phase flow present. Argon gas bottom-stirred ladle with off-centered plugs has been used in this study. Volume of fluid method is used in a computational fluid dynamics (CFD) model to capture the behavior of slag, steel, and argon interfaces. The results are validated with data from literature. Eye opening and slag-steel interfacial area are calculated for different operating conditions and are compared with experimental and simulated results cited in literature. Desulfurization rate is then predicted using chemical kinetic equations, interfacial area, calculated from CFD model, and thermodynamic data, obtained from the Thermo-Calc software. Using the model, it is demonstrated that the double plug purging is more suitable than the single plug purging for the same level of total flow. The advantage is more distinct at higher flow rates as it leads higher interfacial area, needed for desulfurization and smaller eye openings (lower oxygen/nitrogen pickup).

Unexpected water impacts of energy-saving measures in the iron and steel sector: Tradeoffs or synergies?

International Nuclear Information System (INIS)

Wang, Can; Zheng, Xinzhu; Cai, Wenjia; Gao, Xue; Berrill, Peter

2017-01-01

Highlights: •Associated water impacts of individual energy conservation measures were evaluated. •Water-energy tradeoffs exist in the production process adjustment of iron sector. •Considering the water impacts can change the priority ranks of technology choice. -- Abstract: Moving towards integrated governance of water and energy requires balancing tradeoffs and taking advantage of synergies through specific technology choice. However, the water-energy conservation relationships of individual conservation measures in industries other than the water and energy sectors have not been investigated in detail. This study develops a hybrid model to estimate the associated water impacts of individual energy conservation measures, using China’s iron and steel industry as a case study. The results reveal that water-energy tradeoffs exist in the production process adjustment, which is conventionally promoted as a key energy-saving measure in iron and steel industry. It is found that replacing the Blast Oxygen Furnace (BOF) process with the Electric Arc Furnace (EAF) in 2007 could save 131–156 kg coal equivalent (kgce) (13.2–15.7%) of embodied energy per ton of crude steel (tcs) at the expenses of an additional 2.5–3.9 m 3 /tcs (10.6–16.4%) of water footprint. Nineteen energy efficiency technologies are studied in this research, and most of them are identified as having water-saving synergies except for the Low Temperature Rolling Technology. Taking these water impacts into consideration can update the priority ranks of the technology choices and inform policy decisions. Although this study focuses on China’s iron and steel sector, the methods and analysis can be extended to other countries, sectors, technologies and environmental impacts.

Technical aspects of coal use in the Japanese steel industry

International Nuclear Information System (INIS)

Iguchi, T.

1991-01-01

Japan's crude steel production exceeded 100 million tons for the first time in fiscal 1972 and reached a peak of 120 million tons in fiscal 1973, as shown in this paper. The Japanese steel industry then switched from quantity to quality in line with production and market trends in the world. In fiscal 1987, all steelmakers announced future plans for reductions in steel production facilities on the assumption that Japan's crude steel production would hover around 90 million tons in response to the change in the country's production structure. Although steel production has held strong with the expansion in domestic steel demand triggered by the government's economic policy and the production plans that have eventually put their original production plans into practice. In its energy-saving activities prompted by 2 oil rises, the Japanese steel industry has dramatically improved its energy costs through energy conservation, waste heat recovery and process step consolidation, as represented by the reductions in blast furnace fuel rate and coke-oven heat consumption. During this period, the Japanese steel industry has won independence from oil and increased dependence on coal. This paper describes coal utilization technologies in coke ovens and blast furnaces, 2 major coal consuming processes in the steel industry. The environmental problems associated with the use of coal are discussed as well

Application of siliceous metal product for preliminary deoxidizing of metal in open-hearth furnaces

International Nuclear Information System (INIS)

Luk'yanenko, A.A.; Evdokimov, A.V.; Kornilov, V.N.; Il'in, V.I.; Kuleshov, Yu.V.

1995-01-01

Metal wastes of abrasive processes-concomitant product of synthetic corundum production containing approximately 10 % Si - were tested for preliminary deoxidizing of metal in furnace to reduce manganese loss in burning and to increase the steel deoxidizing. The technology of preliminary deoxidizing of metal by siliceous metal product was mastered in the course of low carbon steel melting (st3sp, st4sp). The results of the study has shown that the use of siliceous metal product permits reducing the consumption of manganese-containing ferroalloys. 1 tab

Control of the refractory lining wear in blast furnaces, using a radiotracer technique

International Nuclear Information System (INIS)

Carvalho, G.; Vieira, J.M.; Daltro, T.F.L.; Banados Perez, H.E.

1984-01-01

Small metal 60 Co sources, double encapsulated with quartz and alumina, were inserted (at different depths and levels) into the refractory bricks of the blast furnace walls, and the initial radioactivity emerging at each location recorded as a reference data for future measurements. The displacement of the charge inside the blast furnace originates a progressive wear of the refractory lining and after certain time, the inner sources will begin to be scaped off from the wall and then dissolved in the molten iron. By periodically monitoring the radiation level at the points where the sources were placed, it is possible to know if some of them was removed by the wearing process. This, in turn, will indicate the thickness of refractory material lost in each location making of the blast furnace, as a function of time. The practical application of this method in the Brazilian steel industry is reported. (Author) [pt

FY 1999 report on the results of the R and D on high performance industrial furnace, etc.; 1999 nendo koseino kogyoro no kaihatsu ni kansuru kenkyu seika hokokusho. Koseino kogyoro nado ni kansuru kenkyu kaihatsu

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

In the development of high performance industrial furnace, initial targets were achieved such as energy saving of 30%, downsizing of 20%, and a remarkable NOx reduction. To verify the achievement, the test field project is being worked on by NEDO. In FY 1998, 23 heating furnaces, 29 heat treat furnaces and 6 melting furnaces were under the project at energy saving effect of 52,000 kl converted to crude oil. In FY 1999, 18 heating furnaces, 26 heat treat furnaces and 7 melting furnaces are now under the project at energy saving effect of 57,000 kl. The project was awarded 'The 9th Nikkei Global Environmental Technology Prize.' The themes for the R and D are as follows: high efficiency exhaust heat utilization system, self-completion type high temperature/high radiation heating technology, technology to make heat transfer in steel heating suitable under non-stationary state, high efficiency heat transfer technology, technology to optimize the shape of heating furnace, high performance atmosphere heat treat furnace, high efficiency heat transfer technology by high temperature jet flame heating, technology of high efficiency aluminum melting furnace, technology to improve soaking degree in steel heating, high performance tubular heating furnace in oil refining, optimum combustion control technology of regenerative burner furnace, and laser measuring method inside industrial furnace. (NEDO)

Simulation of surface profile formation in oxygen laser cutting of mild steel due to combustion cycles

Energy Technology Data Exchange (ETDEWEB)

Ermolaev, G V; Kovalev, O B [Khristianovich Institute of Theoretical and Applied Mechanics, Siberian Branch of Russian Academy of Sciences, Institutskaya Str 4/1, Novosibirsk, 630090 (Russian Federation)

2009-09-21

A physicomathematical model of cyclic iron combustion in an oxygen flow during oxygen laser cutting of metal sheets is developed. The combustion front is set into motion by focused laser radiation and a heterogeneous oxidation reaction in oxygen. The burning rate is limited by oxygen supply from the gas phase towards the metal surface, and the interface motion depends on the local temperature. A 3D numerical simulation predicts wavy structures on the metal surface; their linear sizes depend on the scanning speed of the laser beam, the thickness of the produced liquid oxide film and the parameters of the oxygen jet flow. Simulation results help in understanding the mechanism of striation formation during oxygen gas-laser cutting of mild steel and are in qualitative agreement with experimental findings.

Coal char combustion under a CO{sub 2}-rich atmosphere: Implications for pulverized coal injection in a blast furnace

Energy Technology Data Exchange (ETDEWEB)

Borrego, A.G.; Casal, M.D. [Instituto Nacional del Carbon, CSIC. P.O. Box 73, 33080 Oviedo (Spain); Osorio, E.; Vilela, A.C.F. [Laboratorio de Siderurgia, DEMET/PPGEM - Universidade Federal do Rio Grande do Sul. P.O. Box 15021, 91501-970 Porto Alegre (Brazil)

2008-11-15

Pulverized coal injection (PCI) is employed in blast furnace tuyeres attempting to maximize the injection rate without increasing the amount of unburned char inside the stack of the blast furnace. When coal is injected with air through the injection lance, the resolidified char will burn in an atmosphere with a progressively lower oxygen content and higher CO{sub 2} concentration. In this study an experimental approach was followed to separate the combustion process into two distinct devolatilization and combustion steps. Initially coal was injected into a drop tube furnace (DTF) operating at 1300 C in an atmosphere with a low oxygen concentration to ensure the combustion of volatiles and prevent the formation of soot. Then the char was refired into the DTF at the same temperature under two different atmospheres O{sub 2}/N{sub 2} (typical combustion) and O{sub 2}/CO{sub 2} (oxy-combustion) with the same oxygen concentration. Coal injection was also performed under a higher oxygen concentration in atmospheres typical for both combustion and oxy-combustion. The fuels tested comprised a petroleum coke and coals currently used for PCI injection ranging from high volatile to low volatile bituminous rank. Thermogravimetric analyses and microscopy techniques were used to establish the reactivity and appearance of the chars. Overall similar burnouts were achieved with N{sub 2} and CO{sub 2} for similar oxygen concentrations and therefore no loss in burnout should be expected as a result of enrichment in CO{sub 2} in the blast furnace gas. The advantage of increasing the amount of oxygen in a reacting atmosphere during burnout was found to be greater, the higher the rank of the coal. (author)

Problems in steel industry for power engineering

International Nuclear Information System (INIS)

Dolbenko, E.T.; Kryanin, I.R.

1979-01-01

The main problems of steel industry in power engineering are considered. The effect of charge materials upon steel quality is analyzed. Radical dicision of the problem is the ensurance of power engineering plants with high quality original charge materials, which are quite pure according to impurities such as: iron melted from metallized charge or prereduced pellets. The usage of such materials considerably improves the complex of technological and service properties and structure of large responsible products: vessels of the reactor core, especially large shafts and others. For the most responsible power engineering dies it is necessary to smelt steel of 150-200 tons and above. The main direction of steel melting industry is quality steel melting in large 150-200 tons arc furnaces which are equipped with magnetic stirrer installations. It is marked that the branch of power engineering is equipped with unique installations of out-of-furnace steel refining. It is shown that further increase in the metal quality is possible when vacuum and electroslag technique of melting is used. It permits to reduce considerably the amount of sulphur, gases, nonmetallic inclusions, to increase the metal density, to remove zonal segregation in large steel ingots. The main problem in the field of usage of material, produced by new melting methods is the expansion of the product nomenclature and the development of technical conditions, reflecting the increase in material properties as a result of new technique application. Importance of development and introduction of new automation and testing methods in metallurgical processes is marked

Heat treatment furnace

Science.gov (United States)

Seals, Roland D; Parrott, Jeffrey G; DeMint, Paul D; Finney, Kevin R; Blue, Charles T

2014-10-21

A furnace heats through both infrared radiation and convective air utilizing an infrared/purge gas design that enables improved temperature control to enable more uniform treatment of workpieces. The furnace utilizes lamps, the electrical end connections of which are located in an enclosure outside the furnace chamber, with the lamps extending into the furnace chamber through openings in the wall of the chamber. The enclosure is purged with gas, which gas flows from the enclosure into the furnace chamber via the openings in the wall of the chamber so that the gas flows above and around the lamps and is heated to form a convective mechanism in heating parts.

Improved cooler design of electric arc furnace refractory in mining industry using thermal analysis modeling and simulation

International Nuclear Information System (INIS)

Istadi, I.; Bindar, Y.

2014-01-01

Production of steel and nickel using the electric arc furnace should be focused on the intensification of energy. Improvement of energy efficiency of the most consuming facilities was achieved by improving the use of alternative energy minimization such as reducing the heat lost of hot gases, minimizing the heat radiated through refractory linings of metallurgical furnaces, and cooling the highly thermally stressed components. The refractory of electric arc furnace should be modified to achieve the best cooling system of the furnace. In this physical modeling and simulation works, four modification scenarios of wall refractory designs were simulated, i.e. refractory with basic design, refractory with deep plate coolers, refractory with extra plate coolers, and refractory with wall falling film coolers. Finally, the use of deep plate cooler and the existing waffle cooler system was considered to be the best design of efficient electric arc furnace operationally. - Highlights: • Electric arc furnace design should be focused on the intensification of energy. • Refractory of electric arc furnace were modified to achieve the best cooling system. • Four modification scenarios of the wall refractory designs were simulated. • Use of deep plate cooler and existing waffle cooler system is the best cooling

Melting technique for vanadium containing steels

Energy Technology Data Exchange (ETDEWEB)

Grishanov, M P; Gutovskij, I B; Vakhrushev, A S

1980-04-28

To descrease cost price of high-quality vanadium steels a method of their melting in open-hearth furnaces with acid lining using slag-metal fraction of vanadium, which is loaded in the content of 2.1-4.7% of melting mass, is suggested. Introduction of slag-metal fraction of vanadium ensures the formation of slag with composition that guarantees the necessary content of vanadium in steel and does not require introduction of expensive vanadium-containing ferroalloys into the melt.

High Temperature Transparent Furnace Development

Science.gov (United States)

Bates, Stephen C.

1997-01-01

This report describes the use of novel techniques for heat containment that could be used to build a high temperature transparent furnace. The primary objective of the work was to experimentally demonstrate transparent furnace operation at 1200 C. Secondary objectives were to understand furnace operation and furnace component specification to enable the design and construction of a low power prototype furnace for delivery to NASA in a follow-up project. The basic approach of the research was to couple high temperature component design with simple concept demonstration experiments that modify a commercially available transparent furnace rated at lower temperature. A detailed energy balance of the operating transparent furnace was performed, calculating heat losses through the furnace components as a result of conduction, radiation, and convection. The transparent furnace shells and furnace components were redesigned to permit furnace operation at at least 1200 C. Techniques were developed that are expected to lead to significantly improved heat containment compared with current transparent furnaces. The design of a thermal profile in a multizone high temperature transparent furnace design was also addressed. Experiments were performed to verify the energy balance analysis, to demonstrate some of the major furnace improvement techniques developed, and to demonstrate the overall feasibility of a high temperature transparent furnace. The important objective of the research was achieved: to demonstrate the feasibility of operating a transparent furnace at 1200 C.

HYDRAULIC AND LEACHING BEHAVIOUR OF BELITE CEMENTS PRODUCED WITH ELECTRIC ARC FURNACE STEEL SLAG AS RAW MATERIAL

Directory of Open Access Journals (Sweden)

Iacobescu R. I.

2013-06-01

Full Text Available Three belite-rich cements consisting of a clinker made with 0 (BC, 5 (BC5 and 10 wt. % (BC10 electric arc furnace steel slag (EAFS as raw material, were studied for their hydraulic and leaching behaviour. Hydration behaviour was studied by FTIR, TG/DTG and SEM analyses. The cements with EAFS resulted in a higher C2S/C3S and C4AF/C3A ratio compared to the reference body. As a result, the rate of hydration was low at early days whereas the structure was porous with scattered AFm and C–S–H crystals. At 28 days, a comparable dense microstructure consisting largely of C–S–H is observed in all mortars. Leaching was studied for V and Cr by means of tank test according to standard NEN 7345. The results showed V release below 2 μg/l. Chromium release calculated per 24 h was 1.4 μg/l in BC5 and 2.4 μg/l in BC10, which is much lower than the parametric value of 50 μg/l specified by the European Directive for drinking water (98/83/EC.

Steel slag carbonation in a flow-through reactor system: the role of fluid-flux.

Science.gov (United States)

Berryman, Eleanor J; Williams-Jones, Anthony E; Migdisov, Artashes A

2015-01-01

Steel production is currently the largest industrial source of atmospheric CO2. As annual steel production continues to grow, the need for effective methods of reducing its carbon footprint increases correspondingly. The carbonation of the calcium-bearing phases in steel slag generated during basic oxygen furnace (BOF) steel production, in particular its major constituent, larnite {Ca2SiO4}, which is a structural analogue of olivine {(MgFe)2SiO4}, the main mineral subjected to natural carbonation in peridotites, offers the potential to offset some of these emissions. However, the controls on the nature and efficiency of steel slag carbonation are yet to be completely understood. Experiments were conducted exposing steel slag grains to a CO2-H2O mixture in both batch and flow-through reactors to investigate the impact of temperature, fluid flux, and reaction gradient on the dissolution and carbonation of steel slag. The results of these experiments show that dissolution and carbonation of BOF steel slag are more efficient in a flow-through reactor than in the batch reactors used in most previous studies. Moreover, they show that fluid flux needs to be optimized in addition to grain size, pressure, and temperature, in order to maximize the efficiency of carbonation. Based on these results, a two-stage reactor consisting of a high and a low fluid-flux chamber is proposed for CO2 sequestration by steel slag carbonation, allowing dissolution of the slag and precipitation of calcium carbonate to occur within a single flow-through system. Copyright © 2014. Published by Elsevier B.V.

[The electric furnace of Henri Moissan at one hundred years: connection with the electric furnace, the solar furnace, the plasma furnace?].

Science.gov (United States)

Royère, C

1999-03-01

The trace of Henri Moissan's pioneer work 100 years ago is clearly evidenced by an overview of achievements in high temperature devices; 1987: "Le four électrique" by Henri Moissan; 1948-1952: "High temperature heating in a cavity rotary kiln using focusing of solar radiation" by Félix Trombe; 1962: "The cavity rotary kiln using focused solar radiation jointly with a plasma gun" by Marc Foëx; 1970: "The rotary kiln with two plasma guns and arc transfer" by Marc Foëx; 1984: "The plasma furnace" by Electricité de France (EDF) at Renardières; 1997: "The plasma furnace" by the Atomic Energy Center (CEA) at Cadarache, the VULCANO program. The first part of this contribution is devoted to Henri Moissan. Re-reading his early book on the electric furnace, especially the first chapter and the sections on silica, carbon vapor and experiments performed in casting molten metal--the conclusions are outstanding--provides modern readers with an amazing insight into future developments. The last two parts are devoted to Félix Trombe and Marc Foëx, tracing the evolution of high temperature cavity processus leading to the solar furnace and the present day plasma furnace at the CEA. Focus is placed on research conducted by the French National Center for Scientific Research (CNRS) with the solar and plasma furnaces at Odeillo. The relationships with Henri Moissan's early work are amazing, offering a well deserved homage to this pioneer researcher.

Life prolongation and cost reduction of steel ladles with improving refractories and their structure; Taikabutsu zaishitsu to kozo kaizen ni yoru shuka taikabutsu no chojumyoka to kosuto teigen

Energy Technology Data Exchange (ETDEWEB)

Nakai, Masato; Kasahara, Hajime; Fukutani, Fujio; Imai, Hiroyuki [Nippon Steel Corp., Tokyo (Japan)

1999-06-01

Steel Making Plant, Hirohata Iron Works, Nippon Steel Corp. succeeded to reduce the cost of furnace materials by measures described below down to 49% compared to that in 1992. (1) For tuyre bricks, cleanability against oxygen was improved by compacting by vacuum cast forming. (2) For SL bricks, the cost was reduced by applying imported bricks and optimization of the range of use. (3) For alumina-magnesia amorphous refractories for side walls, low expansion and breaking resistance were improved by optimization of magnesia quantity and silica ultra fine powder quantity. (4) For side wall structure, improvement of tie-in between the ground part and the side wall and lining with efficient thickness were carried out. (NEDO)

Toward an understanding of coal combustion in blast furnace tuyere injection

Energy Technology Data Exchange (ETDEWEB)

John G. Mathieson; John S. Truelove; Harold Rogers [BlueScope Steel Research, Port Kembla, NSW (Australia)

2005-07-01

The former Broken Hill Proprietary Company Limited, along with its successors BlueScope Steel and BHP Billiton, like many of their iron and steel making counterparts, has had a long history of investigating pulverised coal injection and combustion under the conditions of blast furnace tuyere injection. A succession of pilot scale hot models and combustion test rigs have been constructed and operated at the company's Newcastle Laboratories beginning with the pilot scale hot raceway model in 1981. Each successive generation of test rig has attempted to provide a closer approximation to the actual blast furnace situation with the current test rig (1998 to present) seeking to promote an 'expanding' combusting coal plume. Test rig configuration is demonstrated to have a significant effect on coal burnout at a nominal transit time of 20 ms. The development of the combustion test rigs has been supported through the co-development of a range of sampling and measuring techniques and the application of a number of numerical combustion models. This paper reviews some of the milestones along the path of these investigations, the current understandings and what the future potentially holds. It's not solved yet! 17 refs., 11 figs.

A laser-based sensor for measurement of off-gas composition and temperature in basic oxygen steelmaking

International Nuclear Information System (INIS)

Ottesen, D.; Allendorf, S.; Ludowise, P.; Hardesty, D.; Miller, T.; Goldstein, D.; Smith, C.; Bonin, M.

1999-01-01

We are developing an optical sensor for process control in basic oxygen steelmaking. The sensor measures gas temperature and relative CO/CO 2 concentration ratios in the furnace off-gas by transmitting the laser probe beam directly above the furnace lip and below the exhaust hood during oxygen blowing. Dynamic off-gas information is being evaluated for optimizing variables such as lance height, oxygen flow, post-combustion control, and prediction of final melt-carbon content. The non-invasive nature of the optical sensor renders it robust and relatively maintenance-free. Additional potential applications of the method are process control for electric arc furnace and bottom-blown oxygen steelmaking processes. (author)

Evidence of enzymatic catalysis of oxygen reduction on stainless steels under marine biofilm.

Science.gov (United States)

Faimali, Marco; Benedetti, Alessandro; Pavanello, Giovanni; Chelossi, Elisabetta; Wrubl, Federico; Mollica, Alfonso

2011-04-01

Cathodic current trends on stainless steel samples with different surface percentages covered by biofilm and potentiostatically polarized in natural seawater were studied under oxygen concentration changes, temperature increases, and additions of enzymic inhibitors to the solution. The results showed that on each surface fraction covered by biofilm the oxygen reduction kinetics resembled a reaction catalyzed by an immobilised enzyme with high oxygen affinity (apparent Michaelis-Menten dissociation constant close to K(O(2))(M)  ≈ 10 μM) and low activation energy (W ≈ 20 KJ mole(-1)). The proposed enzyme rapidly degraded when the temperature was increased above the ambient (half-life time of ∼1 day at 25°C, and of a few minutes at 50°C). Furthermore, when reversible enzymic inhibitors (eg sodium azide and cyanide) were added, the cathodic current induced by biofilm growth was inhibited.

Development of a test set for adjustment of residential furnaces and boilers. Final report

Energy Technology Data Exchange (ETDEWEB)

1980-01-01

A program was undertaken to design and develop a portable test set for simplified field adjustment of residential furnaces and boilers to achieve peak operating efficiency. Advanced technology was applied to provide continuous analysis of flue gases and the display of temperature, oxygen concentrations, smoke value and furnace efficiency. Prototype models were constructed and delivered to Brookhaven National Laboratory for further testing. A survey of furnace dealers was conducted, and a commercialization plan was developed based on survey responses and the status of the equipment developed under the program. Goals for a marketable test set and development steps to achieve a projected energy savings were determined and recommended. Recommendations for specific areas of further development are included.

3-D Transient Heat Transfer Analysis of Slab Heating Characteristics in a Reheating Furnace in Hot Strip Mills

OpenAIRE

J. Y. Jang; Y. W. Lee; C. N. Lin; C. H. Wang

2015-01-01

The reheating furnace is used to reheat the steel slabs before the hot-rolling process. The supported system includes the stationary/moving beams, and the skid buttons which block some thermal radiation transmitted to the bottom of the slabs. Therefore, it is important to analyze the steel slab temperature distribution during the heating period. A three-dimensional mathematical transient heat transfer model for the prediction of temperature distribution within the slab ha...

Gas Furnace with Pulsed Feeding of the Heating Agent for Volume Precision Heat Treatment of CCM Rolls

Science.gov (United States)

Moroz, V. I.; Egorova, V. M.; Gusev, S. V.

2001-05-01

A standard chamber batch furnace of the Severstal' plant has been modified for precision heat treatment of CCM rolls. The certification tests of a charge of rolls from steel 24KhM1F have shown the technical and economical advantages of the new design.

A study on the effect of solution heat treatment on the corrosion resistance of super duplex stainless steels

International Nuclear Information System (INIS)

Park, Jee Yong; Park, Yong Soo; Kim, Soon Tae

2001-01-01

High temperature solution heat treatment(typically higher than 1100 .deg. C) is known generally to reduces the resistance to localized corrosion on super duplex stainless. This is attributed to the formation of zone depleted of alloying elements. In this study, the corrosion properties were investigated on super duplex stainless steels with various solution heat treatments. The corrosion resistance of these steels was evaluated in terms of critical pitting temperature and cyclic potentiodynamic polarization test. Chemical composition of the austenite and ferrite phases were analyzed by SEM-EDS. The following results were obtained. (1) By conducting furnace cooling, critical pitting temperature and repassivation potential increased. (2) By omitting furnace cooling, solution heat treatment produced Cr and Mo depleted zone in the phase boundary. (3) During furnace cooling, Cr and Mo rediffused through the phase boundary. This increased the corrosion resistance of super duplex stainless steels

The Influence of Calcium Carbonate Composition and Activated Carbon in Pack Carburizing Low Carbon Steel Process in The Review of Hardness and Micro Structure

Science.gov (United States)

Hafni; Hadi, Syafrul; Edison

2017-12-01

Carburizing is a way of hardening the surface by heating the metal (steel) above the critical temperature in an environment containing carbon. Steel at a temperature of the critical temperature of affinity to carbon. Carbon is absorbed into the metal form a solid solution of carbon-iron and the outer layer has high carbon content. When the composition of the activator and the activated charcoal is right, it will perfect the carbon atoms to diffuse into the test material to low carbon steels. Thick layer of carbon Depending on the time and temperature are used. Pack carburizing process in this study, using 1 kg of solid carbon derived from coconut shell charcoal with a variation of 20%, 10% and 5% calcium carbonate activator, burner temperature of 950 0C, holding time 4 hours. The test material is low carbon steel has 9 pieces. Each composition has three specimens. Furnace used in this study is a pack carburizing furnace which has a designed burner box with a volume of 1000 x 600 x 400 (mm3) of coal-fired. Equipped with a circulation of oxygen from the blower 2 inches and has a wall of refractory bricks. From the variation of composition CaCO3, microstructure formed on the specimen with 20% CaCO3, better diffusion of carbon into the carbon steel, it is seen by the form marten site structure after quenching, and this indicates that there has been an increase of or adding carbon to in the specimen. This led to the formation of marten site specimen into hard surfaces, where the average value of hardness at one point side (side edge) 31.7 HRC

Joint dissolution and oxidation behaviour of 316LN steel at 550 C. in liquid sodium containing low concentration of oxygen - 15417

International Nuclear Information System (INIS)

Courouau, J.L.; Rivollier, M.; Lorentz, V.; Tabarant, M.

2015-01-01

The sodium cooled fast reactor is selected in France as the 4. generation of nuclear power plant. 4. generation's reactor vessel, primary loop structures and heat exchangers will be made of austenitic stainless steels (316LN). To assess reactor service life time, corrosion of austenitic stainless steel by liquid sodium is studied in normal operating conditions as well as in transient conditions either expected or not. Oxygen, one of the main impurities, but present in trace amounts (1 to 10 μg/g or ppm weight), plays a major role on corrosion phenomena of the steel, although not totally understood yet. Literature reports an increased dissolution rate of steel or even of pure iron with increasing oxygen content although no thermodynamically stable iron oxide exists at low oxygen content. Oxygen is only known to form sodium chromite scale (NaCrO 2 ), those behaviour is, however, little documented. Based on corrosion tests performed in the static sodium test device (CorroNa) at 550 C. degrees for an oxygen content initially of about 1 ppm in weight or lower, and about 5-10 ppm after 4600 h of test, either a really small dissolution rate or small sodium chromite scale formation (NaCrO 2 ) are observed. Dissolution and carburation are observed for specimen immersed since the beginning of the test, while oxidation is the main feature observed for the specimen immersed during the last periods of the test. Some aspects of the morphologies of this oxide scale obtained by scanning electron microscopy (SEM) or transmission electron microscopy (TEM) as well as by Glow Discharge Optical Emission Spectroscopy (GD-OES) are presented. Discussions and explanations of these apparently opposing results are given based on thermodynamic analysis, as well as their possible consequences for reactor operation. (authors)

Banking the Furnace: Restructuring of the Steel Industry in Eight Countries.

Science.gov (United States)

Bain, Trevor

A study examined how the cross-national differences in the social contract among managers, unions, and government influenced adjustment strategies in steel. The restructuring process in eight major steel-producing countries was studied to determine who bore the costs of restructuring--employers, employees, or government--and which industrial…

Utilización del polvo de acería de horno de arco eléctrico. // Use of powder produced by electric arc furnaces at steel plants.

Directory of Open Access Journals (Sweden)

D. Tápanes Robau

2001-01-01

Full Text Available El polvo de las Acerías de Horno de Arco Eléctrico se produce como consecuencia de la producción de Acero, durante ladepuración de los gases, y, en menor medida, en sus equipos de captación de aire. Estos polvos deben ser captados por lossistemas de depuración del taller. Con el presente trabajo pretendemos darle utilidad a un producto de desecho como es elpolvo, mejorar las condiciones ambientales en el taller, elevar la calidad del pavimento u hormigón asfáltico mediante lavariación de sus propiedades y disminuir el costo de la tonelada de acero mediante la comercialización de estos productosde desecho.Palabras claves: Polvos, aglutinantes, composición química, pruebas realizadas._______________________________________________________________________________SummaryThe powder generated by electric arc furnaces at steel plants is the result of processes such as the production of steel, thepurification of gases and, capturing air equipment .This article shows a method for recycling waste material – powder in this case- which also contributes to improve the steelplant environment, provides the possibility of improving asphalt paving and makes the production of steel cheaper throughthe commercialization of waste materials.Key words: Powder, binder, tests, chemical composition.

Influence of Short Austenitization Treatments on the Mechanical Properties of Low-Alloy Steels for Hot Forming Applications

Science.gov (United States)

Holzweissig, Martin Joachim; Lackmann, Jan; Konrad, Stefan; Schaper, Mirko; Niendorf, Thomas

2015-07-01

The current work elucidates an improvement of the mechanical properties of tool-quenched low-alloy steel by employing extremely short austenitization durations utilizing a press heating arrangement. Specifically, the influence of different austenitization treatments—involving austenitization durations ranging from three to 15 seconds—on the mechanical properties of low-alloy steel in comparison to an industrial standard furnace process was examined. A thorough set of experiments was conducted to investigate the role of different austenitization durations and temperatures on the resulting mechanical properties such as hardness, bending angle, tensile strength, and strain at fracture. The most important finding is that the hardness, the bending angle as well as the tensile strength increase with shortened austenitization durations. Furthermore, the ductility of the steels exhibits almost no difference following the short austenitization durations and the standard furnace process. The enhancement of the mechanical properties imposed by the short heat treatments investigated, is related to a refinement of microstructural features as compared to the standard furnace process.

FY 1999 report on the fundamental investigation for promotion of Joint Implementation. Blast furnace top pressure recovery turbine (TRT) project for China's Panzhihua Iron and Steel (Group) Company; 1999 nendo Chugoku Panzhihua kotetsu (shudan) koji koro rochoatsu hatsuden setsubi (TRT) project

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

Feasibility study is conducted for introduction of a top pressure recovery turbine (TRT) in China's Panzhihua Iron and Steel (Group) Company, Sichuan Province, for the potential project to simultaneously contribute to abatement of the greenhouse effect gases and to sustainable economic development of the counterpart country. This project considers to adopt the TRTs in 3 blast furnaces (No.1 to 3) of the 4 furnaces in service at the works, producing 2,500,000 t/y of crude steel, where the No.4 furnace is already provided with the model system and not considered in this project. According to the feasibility study results, the total fund required is 5.46 billion yen (Japan-made facilities: 4.172 billion yen, and China-made facilities: 1.288 billion yen), energy-saving effect is 36,467 t/y as crude, greenhouse effect gas emission abatement effect: 112,830 t/y as CO2, and pay-off period is 8.3 years. This plan considers to adopt almost the same facilities as those for the model project on a commercial basis. The taxes will be applied to the Japan-made facilities at a rate of 30% or more, although they were free for the model project, which should squeeze the investment effects. For the TRT project to be realized, low-interest fund is essential, and environmental yen loans will be necessary. (NEDO)

40 CFR 60.141a - Definitions.

Science.gov (United States)

2010-07-01

... steel production cycle are also included when the hot metal transfer station or skimming station is an... Process Steelmaking Facilities for Which Construction is Commenced After January 20, 1983 § 60.141a... amended or in subpart A of this part. Basic oxygen process furnace (BOPF) means any furnace with a...

Hot metal temperature prediction and simulation by fuzzy logic in a blast furnace

International Nuclear Information System (INIS)

Romero, M. A.; Jimenez, J.; Mochon, J.; Formoso, A.; Bueno, F.; Menendez, J. L.

2000-01-01

This work describes the development and further validation of a model devoted to blast furnace hot metal temperature forecast, based on Fuzzy logic principles. The model employs as input variables, the control variables of an actual blast furnace: Blast volume, moisture, coal injection, oxygen addition, etc. and it yields as a result the hot metal temperature with a forecast horizon of forty minutes. As far as the variables used to develop the model have been obtained from data supplied by an actual blast furnaces sensors, it is necessary to properly analyse and handle such data. Especial attention was paid to data temporal correlation, fitting by interpolation the different sampling rates. In the training stage of the model the ANFIS (Adaptive Neuro-Fuzzy Inference System) and the Subtractive Clustering algorithms have been used. (Author) 9 refs

DEVELOPMENT AND TESTING OF COMPOUND FUEL CHAMBER WITHOUT A GRATE FOR HOUSEHOLD FURNACE

Directory of Open Access Journals (Sweden)

Shevyakov Vladimir Viktorovich

2018-02-01

Full Text Available In hearth furnaces, the firewood is burned more cleanly with less carbon monoxide at the outlet. The disadvantage of such fireboxes is a longer process of coal burnout than in grate-fired furnaces. In furnaces with a grate, the burnout time of coals is less, which makes it possible to finish the combustion process more quickly and close the outlet latch. This increases the efficiency of the furnace but to further reduce the time of burning out the coals they have to be raked and burned on the grate. This complicates the process of operating the furnace itself. The proposed design of the compound firebox allows us to improve characteristics of both the firebox itself and the entire furnace. Research objectives: creation and study of a compound firebox that increases the efficiency of the furnace and simplifies the furnace maintenance process with the values of carbon monoxide at the outlet comparable to hearth furnaces. Materials and methods: a detailed analysis of hearth fuel chambers ECO+ was carried out according to the amount of carbon monoxide at the outlet. The results of the analysis are used for comparison with compound fuel chamber. The structure of the compound firebox was chosen based on the results of preliminary tests of several fuel chambers proposed and tested by the author in the furnace PDKSh-2.0. A peculiarity of the structure of the compound firebox is the absence of a grate and the presence of a narrow slit in the lower part of the firebox through which the incoming air enters the firewood. Between the walls of the firebox and firewood, skids are installed, forming an air gap, through which the inlet air is uniformly supplied to the entire firewood supply. With gradual combustion of firewood and formation of coal, the firewood descends to the bottom of the firebox, where they intensively burn out in the maximum air flow. Compound firebox consists of several parts, it is made of steel with a thickness of 4.0 mm and installed

Mathematical modelling of striation formation in oxygen laser cutting of mild steel

Energy Technology Data Exchange (ETDEWEB)

Ermolaev, G V; Kovalev, O B; Orishich, A M; Fomin, V M [Institute of Theoretical and Applied Mechanics SB RAS, 4/1 Institutskaya Str., Novosibirsk 630090 (Russian Federation)

2006-10-07

A physicomathematical model is proposed for the phenomenon of formation of periodic striations in oxygen laser cutting of mild steel sheets. The mechanism of roughness origination is assumed to be caused by a cyclic reaction of iron-oxygen oxidation. The mathematical description is based on solving the adjoint problems of heat and mass transfer in the liquid phase and in the solid metal with nonlinear moving interfaces between the substances and phase changes. The motion of the boundaries occurs owing to metal melting under the action of focused laser radiation and the heterogeneous chemical reaction of iron oxidation in oxygen. The main feature of iron oxidation is the loss of protective properties of its oxide film due to melting. The general statement of the problem for the nonlinear heat-conduction equation with variable coefficients is formulated by the type of the Stefan problem solved with the use of the difference method with smoothing coefficients at the melting point and the fictitious domain method, which allows obtaining of the solution without explicit identification of the cut boundary and the phase-transition front. Results of numerical simulations of the shape and linear size of roughness as functions of the cutting velocity, purity of oxygen and thickness of the film of the iron oxide being formed are presented.

Laser-induced breakdown spectrometry — applications for production control and quality assurance in the steel industry

Science.gov (United States)

Noll, Reinhard; Bette, Holger; Brysch, Adriane; Kraushaar, Marc; Mönch, Ingo; Peter, Laszlo; Sturm, Volker

2001-06-01

Recent progress in sensitivity and signal processing opened a broad field of application for laser-induced breakdown spectrometry (LIBS) in the steel making and processing industry. Analyzed substances range from top gas of the blast furnace, via liquid steel up to finished products. This paper gives an overview of R&D activities and first routine industrial applications of LIBS. The continuous knowledge of the topgas composition yields information about the blast furnace process. An online monitoring method using LIBS is currently under investigation to measure alkali metals, which influence energy and mass flow in the furnace. Direct analysis of liquid steel reduces processing times in secondary metallurgy. By using sensitivity-enhanced LIBS, limits of detection of approximately 10 μg/g and below were achieved for light and heavy elements in liquid steel. The process control in steel production relies on the results from the chemical analysis of the slag. A prototype of an analytical system was developed using LIBS to analyze slag samples two times faster than with conventional methods. The cleanness of steel is a key issue in the manufacturing of spring steel, thin foils and wires. Microscopic inclusions have to be determined quickly. A scanning microanalysis system based on LIBS was developed with measuring frequencies up to 1 kHz and a spatial resolution of grade of pipe fittings, an inspection machine using LIBS was developed and introduced into routine industrial use to detect material mix-ups. More than 500 000 pipe fittings were inspected during the last 20 months.

Method for treating waste containing stainless steel

International Nuclear Information System (INIS)

Kujawa, S.T.; Battleson, D.M.; Rademacher, E.L. Jr.; Cashell, P.V.; Filius, K.D.; Flannery, P.A.; Whitworth, C.G.

1999-01-01

A centrifugal plasma arc furnace is used to vitrify contaminated soils and other waste materials. An assessment of the characteristics of the waste is performed prior to introducing the waste into the furnace. Based on the assessment, a predetermined amount of iron is added to each batch of waste. The waste is melted in an oxidizing atmosphere into a slag. The added iron is oxidized into Fe 3 O 4 . Time of exposure to oxygen is controlled so that the iron does not oxidize into Fe 2 O 3 . Slag in the furnace remains relatively non-viscous and consequently it pours out of the furnace readily. Cooled and solidified slag produced by the furnace is very resistant to groundwater leaching. The slag can be safely buried in the earth without fear of contaminating groundwater. 3 figs

Plasma sintering of ferritic steel reinforced with niobium carbide prepared by high energy milling

International Nuclear Information System (INIS)

Silva Junior, J.F. da; Almeida, E.O.; Gomes, U.U.; Alves Junior, C.; Messias, A.P.; Universidade Federal do Rio Grande do Norte

2010-01-01

Plasma is an ionized gas where ions are accelerated from anode to cathode surface, where the sample is placed. There are a lot of collisions on cathode surface by ions heating and sintering the sample. High energy milling (HEM) is often used to produce composite particles to be used on powder metallurgy. These particles can exhibit fine particles and high phase dispersion. This present work aim to study ferritic steels reinforced with 3%NbC prepared by HEM and sintered on plasma furnace. Ferritic steel and NbC powders were milled during 5 hours and characterized by SEM, XRD and laser scattering. Then, these composite powders were compacted in a cylindrical steel die and then sintered in a plasma furnace. Vickers microhardness tests and SEM and XRD analysis were performed on sintered samples. (author)

Metallurgy of mercury in Almaden: from aludel furnaces until Pacific furnaces

International Nuclear Information System (INIS)

Tejero-Manzanares, J.; Garrido Saenz, I.; Mata Cabrera, F.; Rubio Mesas, M. L.

2014-01-01

This paper shows the different types of furnaces for roasting cinnabar, used in the metallurgy of quicksilver over the centuries of exploitation of the Almaden Mines (Spain). Some of these techniques are part of our industrial heritage. They have contributed to name UNESCO World Heritage Site the vast technological legacy of these mines recently. This research contributes to close the long way of metallurgical activity from aludel furnaces until Pacif furnaces, first and lasted technology to produce on an industrial scale. It is delved into the most relevant aspects having to do with the type, evolution and number of furnaces existing on each of the periods. (Author)

Factors affecting stress assisted corrosion cracking of carbon steel under industrial boiler conditions

Science.gov (United States)

Yang, Dong

Failure of carbon steel boiler tubes from waterside has been reported in the utility boilers and industrial boilers for a long time. In industrial boilers, most waterside tube cracks are found near heavy attachment welds on the outer surface and are typically blunt, with multiple bulbous features indicating a discontinuous growth. These types of tube failures are typically referred to as stress assisted corrosion (SAC). For recovery boilers in the pulp and paper industry, these failures are particularly important as any water leak inside the furnace can potentially lead to smelt-water explosion. Metal properties, environmental variables, and stress conditions are the major factors influencing SAC crack initation and propagation in carbon steel boiler tubes. Slow strain rate tests (SSRT) were conducted under boiler water conditions to study the effect of temperature, oxygen level, and stress conditions on crack initation and propagation on SA-210 carbon steel samples machined out of boiler tubes. Heat treatments were also performed to develop various grain size and carbon content on carbon steel samples, and SSRTs were conducted on these samples to examine the effect of microstructure features on SAC cracking. Mechanisms of SAC crack initation and propagation were proposed and validated based on interrupted slow strain tests (ISSRT). Water chemistry guidelines are provided to prevent SAC and fracture mechanics model is developed to predict SAC failure on industrial boiler tubes.

Observer-based Coal Mill Control using Oxygen Measurements

DEFF Research Database (Denmark)

Andersen, Palle; Bendtsen, Jan Dimon; S., Tom

2006-01-01

This paper proposes a novel approach to coal flow estimation in pulverized coal mills, which utilizes measurements of oxygen content in the flue gas. Pulverized coal mills are typically not equipped with sensors that detect the amount of coal injected into the furnace. This makes control...... of the coal flow difficult, causing stability problems and limits the plant's load following capabilities. To alleviate this problem without having to rely on expensive flow measurement equipment, a novel observer-based approach is investigated. A Kalman filter based on measurements of combustion air flow led...... into the furnace and oxygen concentration in the flue gas is designed to estimate the actual coal flow injected into the furnace. With this estimate, it becomes possible to close an inner loop around the coal mill itself, thus giving a better disturbance rejection capability. The approach is validated against...

TiC reinforced cast Cr steels

Energy Technology Data Exchange (ETDEWEB)

Dogan, O.N.; Hawk, J.A.; Schrems, K.K.

2006-06-01

A new class of materials, namely TiC-reinforced cast chromium (Cr) steels, was developed for applications requiring high abrasion resistance and good fracture toughness. The research approach was to modify the carbide structure of commercial AISI 440C steel for better fracture resistance while maintaining the already high abrasion resistance. The new alloys contained 12Cr, 2.5–4.5Ti, and 1–1.5C (wt.%) and were melted in a vacuum induction furnace. Their microstructure was composed primarily of a martensitic matrix with a dispersion of TiC precipitates. Modification of TiC morphology was accomplished through changing the cooling rate during solidification. Wear rates of the TiC-reinforced Cr steels were comparable to that of AISI 440C steel, but the impact resistance was much improved.

TiC-reinforced cast Cr steels

Science.gov (United States)

Doğan, Ö. N.; Hawk, J. A.; Schrems, K. K.

2006-06-01

A new class of materials, namely TiC-reinforced cast chromium (Cr) steels, was developed for applications requiring high abrasion resistance and good fracture toughness. The research approach was to modify the carbide structure of commercial AISI 440C steel for better fracture resistance while maintaining the already high abrasion resistance. The new alloys contained 12Cr, 2.5-4.5Ti, and 1-1.5C (wt.%) and were melted in a vacuum induction furnace. Their microstructure was composed primarily of a martensitic matrix with a dispersion of TiC precipitates. Modification of TiC morphology was accomplished through changing the cooling rate during solidification. Wear rates of the TiC-reinforced Cr steels were comparable to that of AISI 440C steel, but the impact resistance was much improved.

Corrosion behavior of sensitized duplex stainless steel.

Science.gov (United States)

Torres, F J; Panyayong, W; Rogers, W; Velasquez-Plata, D; Oshida, Y; Moore, B K

1998-01-01

The present work investigates the corrosion behavior of 2205 duplex stainless steel in 0.9% NaCl solution after various heat-treatments, and compares it to that of 316L austenitic stainless steel. Both stainless steels were heat-treated at 500, 650, and 800 degrees C in air for 1 h, followed by furnace cooling. Each heat-treated sample was examined for their microstructures and Vickers micro-hardness, and subjected to the X-ray diffraction for the phase identification. Using potentiostatic polarization method, each heat-treated sample was corrosion-tested in 37 degrees C 0.9% NaCl solution to estimate its corrosion rate. It was found that simulated sensitization showed an adverse influence on both steels, indicating that corrosion rates increased by increasing the sensitization temperatures.

The Study for Recycling NORM - Contaminated Steel Scraps from Steel Industry

International Nuclear Information System (INIS)

Tsai, K. F.; Lee, Y. S.; Chao, H. E.

2003-01-01

Since 1994, most of the major steel industries in Taiwan have installed portal monitor to detect the abnormal radiation in metal scrap feed. As a result, the discovery of NORM (Naturally Occurring Radioactive Material) has increased in recent years. In order to save the natural resources and promote radiation protection, an experimental melting process for the NORM contaminated steel scraps was carried out by the Institute of Nuclear Energy Research (INER) Taiwan, ROC. The experimental melting process has a pretreatment step that includes a series of cutting and removal of scales, sludge, as well as combustible and volatile materials on/in the steel scraps. After pretreatment the surface of the steel scraps are relatively clean. Then the scraps are melted by a pilot-type induction furnace. This experiment finally produced seven ingots with a total weight of 2,849 kg and 96.8% recovery. All of the surface dose rates are of the background values. The activity concentrations of these ingots are also below the regulatory criteria. Thus, these NORM-bearing steel scraps are ready for recycling. This study has been granted by the regulatory authority

Metallurgy of steels for PWR pressure vessels

International Nuclear Information System (INIS)

Kepka, M.; Mocek, J.; Barackova, L.

1980-01-01

A survey and the chemical compositions are presented of reactor pressure vessel steels. The metallurgy is described of steel making for pressure vessels in Japan and the USSR. Both acidic and alkaline open-hearth steel is used for the manufacture of ingots. The leading world manufacturers of forging ingots for pressure vessels, however, exclusively use electric steel. Vacuum casting techniques are exclusively used. Experience is shown gained with the introduction of the manufacture of forging ingots for pressure vessels at SKODA, Plzen. The metallurgical procedure was tested utilizing alkaline open hearths, electric arc furnaces and facilities for vacuum casting of steel. Pure charge raw materials should be used for securing high steel purity. Prior to forging pressure vessel rings, not only should sufficiently big bottoms and heads be removed but also the ingot middle part should be scrapped showing higher contents of impurities and nonhomogeneous structure. (B.S.)

Metallurgy of steels for PWR pressure vessels

Energy Technology Data Exchange (ETDEWEB)

Kepka, M; Mocek, J; Barackova, L [Skoda, Plzen (Czechoslovakia)

1980-09-01

A survey and the chemical compositions are presented of reactor pressure vessel steels. The metallurgy is described of steel making for pressure vessels in Japan and the USSR. Both acidic and alkaline open-hearth steel is used for the manufacture of ingots. The leading world manufacturers of forging ingots for pressure vessels, however, exclusively use electric steel. Vacuum casting techniques are exclusively used. Experience is shown gained with the introduction of the manufacture of forging ingots for pressure vessels at SKODA, Plzen. The metallurgical procedure was tested utilizing alkaline open hearths, electric arc furnaces and facilities for vacuum casting of steel. Pure charge raw materials should be used for securing high steel purity. Prior to forging pressure vessel rings, not only should sufficiently big bottoms and heads be removed but also the ingot middle part should be scrapped showing higher contents of impurities and nonhomogeneous structure.

FY 2000 report on the basic survey to promote Joint Implementation, etc. Environmental improvement and energy conservation measures in Pakistan Steel, a state-run enterprise in Pakistan; 2000 nendo kyodo jisshi nado suishin kiso chosa hokokusho. Pakistan koku kokuei Pakistan Steel ni okeru kankyo kaizen sho energy taisaku

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

For the state-run plant of Pakistan Steel in Pakistan, an investigational study was conducted on energy conservation and reduction in greenhouse effect gas emission. In the project, energy conservation technology on the following was tried to be introduced: coke oven coal moisture control (CMC) equipment, sintering cooler waste heat recovery equipment, blast furnace hot stove waste heat recovery equipment, blast furnace pulverized coal injection (PCI) equipment, blast furnace top pressure recovery turbine (TRT) equipment, and hot strip mill heating furnace regenerative type burner equipment. Further, in the project on environmental improvement, studies were made on coke oven environmental improvement and blast furnace cast house dust collection. The results of the study indicated that economical effects of the energy conservation project were considered as low because the unit price of energy of Pakistan Steel is low. However, substitution of the low-priced domestic coal for the imported coal has a good effect, and energy conservation in the TRT power generation and by the regenerative type burner produces a highly economical effect. Therefore, Pakistan Steel also agrees to positively promote the project. Moreover, concerning the environmental improvement project, it was considered that the necessity of the project is high in the relation of the coke oven aimed at reducing emissions of toxic substances. (NEDO)

A heat transfer model for the analysis of transient heating of the slab in a direct-fired walking beam type reheating furnace

Energy Technology Data Exchange (ETDEWEB)

Kim, Man Young [School of Mechanical and Aerospace Systems Engineering, Research Center of Industrial Technology, Chonbuk National University, 664-14 Duckjin-Dong, Duckjin-Gu, Jeonju, Chonbuk 561-756 (Korea)

2007-09-15

A mathematical heat transfer model for the prediction of heat flux on the slab surface and temperature distribution in the slab has been developed by considering the thermal radiation in the furnace chamber and transient heat conduction governing equations in the slab, respectively. The furnace is modeled as radiating medium with spatially varying temperature and constant absorption coefficient. The steel slabs are moved on the next fixed beam by the walking beam after being heated up through the non-firing, charging, preheating, heating, and soaking zones in the furnace. Radiative heat flux calculated from the radiative heat exchange within the furnace modeled using the FVM by considering the effect of furnace wall, slab, and combustion gases is introduced as the boundary condition of the transient conduction equation of the slab. Heat transfer characteristics and temperature behavior of the slab is investigated by changing such parameters as absorption coefficient and emissivity of the slab. Comparison with the experimental work show that the present heat transfer model works well for the prediction of thermal behavior of the slab in the reheating furnace. (author)

FY 2000 Study report. Feasibility study on model project for effective utilization of sensible heat of off gas from hot stoves at blast furnaces in India; 2000 nendo Indo ni okeru koro netsufuro hai gas kennetsu yuko riyo model jigyo jisshi kanosei chosa hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

The feasibility study was conducted on a model project in India for the energy saving effect and reduction of the greenhouse gas emissions by introducing blast furnace hot stove waste heat recovery systems in steelworks. The blast furnaces studied are Blast Furnace G at Jamshedpur Steelworks of TISCO, the largest private steel maker in India, and No.7 Blast Furnace at Bhilai Steelworks of state-operated Steel Authority of India Ltd. (SAIL). The study results indicate that the annual energy-saving effects of 8,255 and 8,190 tons as heavy oil, and annual CO2 emission reduction of 25,543 and 25,342 tons are expected in the TISCO and SAIL blast furnaces, respectively, in the case of increasing blast temperature and reducing blast furnace fuel coke (increased iron production possible). The model project is applicable to both blast furnaces. There are a total of 46 blast furnaces in India in which the heat recovery systems can be introduced. The nation-wide annual energy saving and CO2 abatement would reach 126,202 tons as heavy oil and 390,501 tons, when all of these blast furnaces could be provided with the heat recovery systems. (NEDO)

Industrial study of iron oxide reduction by injection of carbon particles into the electric arc furnace

International Nuclear Information System (INIS)

Conejo, A. N.; Torres, R.; Cuellar, E.

1999-01-01

An industrial study was conducted in electric arc furnaces (EAF) employing 100% direct reduced iron to evaluate the oxidation level of the slag-metal system. Energy consumption is decreased by injecting gaseous oxygen, however, slag oxidation also increases. In order to reduce the extent of oxidation while keeping a high volume of the oxygen injected , it is required: a) to optimize the carbon injection practice, b) to increase the carbon concentration of sponge iron, c) to operate with soluble carbon in both the metal and the slag beyond a critical level and d) to employ a low temperature profile, on average 1,650 degree centigrade. A method to define the proper amount of carbon in sponge iron which considers their metallization as well as the amount of oxygen injected is proposed. The position of the lance is critical in order to optimize the practice of carbon injection and assure a better residence time of the carbon particles within the furnace. (Author) 23 refs

Basic survey project for joint implementation and CDM. Comprehensive investigation into introduction of blast furnace gas-firing combined cycle power plant and energy balance review at Krivorozhsky State Integrated Steel and Ironworks 'Krivorozhstal' Steel Works

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

Investigations and discussions were given on electric power generation facilities at the Krivorozhstal Steel Works in Ukraine with an aim of reducing the emission of global warming gases by means of the energy saving and petroleum substituting energy technologies. The discussions were made on the combined cycle power plant (CCPP) project that utilizes as fuel the blast-furnace gas being discharged into atmosphere. The project calls for starting the construction in fiscal 2003, and entering commercial operation in fiscal 2005. The total investment amount would be 160.65 million US dollars. In a case of producing steel and iron of 7,000 tons annually, profit would be obtained at 11.24%, which will make the project realization possible if low-interest finance can be obtained from Japan. The amount of carbon dioxide discharged from operating the facilities for eight years from 2005 to 2012 is estimated to be reduced by about 6.8 million tons. In addition, the project would contribute to enhancement in productivity of the factory by reducing the labor force. Furthermore, effect of reducing emission of sulfur dioxide can be expected. (NEDO)

Properties of structural steels melted out of high-purity charge

International Nuclear Information System (INIS)

Marchenko, V.N.; Sergeeva, T.K.; Kondakova, N.K.; Morozov, V.P.; Madorskij, L.L.

1993-01-01

A comparative evaluation has been made of impurities, mechanical properties and hydrogen embirittlement parameters for steels type 40Kh and 40KhS produced by electrometallurgical method with the use of direct reduced charge (DR-steels) and melted in an open-hearth furnace. Investigation results have shown that 40Kh and 40KhS Dr-steels have more coarse austenitic grains and experience more complete transformation of martensite into ferritic-pearlitic mixture on tempering. Threshold stresses increase 2.5 times due to purity enhancement at the expense of application of direct reduced charge

Analyse and research of nonmetallic inclusions for steel 100Cr6

Directory of Open Access Journals (Sweden)

I. Vitez

2009-01-01

Full Text Available Steel 100Cr6 belongs to a group of hardened steels, which are applicable for production of rolling element parts. Because of specific working conditions, a proper chemical composition is required with a minimum content of nonmetallic inclusion. In this paper, the research results of presence the nonmetallic inclusions and their chemical composition are presented for the steel produced in vacuum and open induction electric furnace and their influence on the prescribed properties for this steel. The optical and scanning electronic microscope are used to identify presence and the chemical compositions of nonmetallic inclusions.

Constructal design of a blast furnace iron-making process based on multi-objective optimization

International Nuclear Information System (INIS)

Liu, Xiong; Chen, Lingen; Feng, Huijun; Qin, Xiaoyong; Sun, Fengrui

2016-01-01

For the fixed total raw material cost and based on constructal theory and finite time thermodynamics, a BFIM (blast furnace iron-making) process is optimized by taking a complex function as optimization objective. The complex function is integrated with HM (hot metal) yield and useful energy of the BF (blast furnace). The optimal cost distribution of raw materials (namely “generalized optimal construct”) is obtained. The effects of some parameters, such as oxygen enrichment, blast temperature and pulverized coal dosage, on the optimization results are analyzed. The results show that the HM yield, useful energy and complex function are, respectively, increased by 3.13%, 2.66% and 2.90% after generalized constructal optimization. The utilization efficiencies of the BFG (blast furnace gas) and slag are 41.3% and 57.1%, respectively, which means that the utilization potentials of the BFG and slag can be further exploited. Increasing pulverized coal dosage and decreasing the agglomerate ratio can increase the complex function. The performance the BFIM process can be improved by adjusting the oxygen enrichment, blast temperature, blast dosage, pressure ratio of the Brayton cycle's air compressor and relative pressure drop of the air compressor inlet to their optimal values, respectively, which are new findings of this paper. - Highlights: • Constructal optimization of a blast furnace iron-making process is performed. • Finite time thermodynamic model of open Brayton cycle is adopted. • Weighting function is taken as optimization objective. • Optimal cost distribution of the raw materials is obtained.

Comparison of a burning mass ceramics coating in laboratory furnace and instrustrial furnace

International Nuclear Information System (INIS)

Soares, R.A.L.; Castro, J.R. de S.

2012-01-01

This work intends to analyze the differences obtained in the technological properties of a ceramic coating after firing in two distinct environments, laboratory furnace and industrial furnace. For this, was characterized a ceramic mass used in the production of porous coating. The analyzes were performed chemical, mineralogical and thermal mass in that. The specimens were obtained by compacting and burned in the maximum temperature of 1140 deg C in two furnaces, laboratory and industrial. The technological tests were performed linear shrinkage, water absorption, bulk density and mechanical strength. The microstructure was evaluated by ray-X diffraction and scanning electron microscopy. The results showed that both furnaces provided significant differences in analyzed specimens, such as increased strength and low water absorption in the fired samples in a laboratory furnace, for example. (author)

Study of the oxygen reduction reaction on stainless steel materials in natural seawater. Influence of the bio-film on corrosion processes

International Nuclear Information System (INIS)

Le Bozec, N.

2000-01-01

Bio-film development on stainless steels immersed in natural seawater can have prejudicial consequences on the resistance of these materials to corrosion. The goal of the present study was to get more precise information on the corrosion processes, and especially on the oxygen reduction reaction. As the reaction is linked to the stainless steel surface state, the characterisation of the oxides films (composition, structure, thickness...) is essential to understand the mechanisms and the oxygen reduction kinetic. The first aim of the study has been to correlate the oxygen reduction processes with the characteristics of the oxides layer as a function of the alloy surface treatment (mechanical polishing, electrochemical passivation and pre-reduction, chemical treatment with some acids or with hydrogen peroxide). The second stage has consisted in following the evolution of the oxygen reduction processes and of the characteristics of the oxides layer with the aging of stainless steels in natural and artificial sea-waters. One major bio-film effect appears to be the production of hydrogen peroxide at a concentration level which induces modifications of the oxides layers and, consequently, of the evolution of the oxygen reduction kinetics as well as of the open circuit potential. Electrochemical techniques (voltammetric analysis at rotating disk and ring-disk electrodes, coulometry) combined with a surface analytical method by X-ray photoelectron spectroscopy have been used. The characterisation of the bio-film required the use of microscopy (scanning electronic microscopy, epi-fluorescence microscopy) and microbiological methods (cultures). The in-situ detection of hydrogen peroxide formed inside the bio-film has been performed with a micro-electrode and the results were confirmed with enzymatic methods. (author)

Waste plastics as supplemental fuel in the blast furnace process: improving combustion efficiencies.

Science.gov (United States)

Kim, Dongsu; Shin, Sunghye; Sohn, Seungman; Choi, Jinshik; Ban, Bongchan

2002-10-14

The possibility of using waste plastics as a source of secondary fuel in a blast furnace has been of recent interest. The success of this process, however, will be critically dependent upon the optimization of operating systems. For instance, the supply of waste plastics must be reliable as well as economically attractive compared with conventional secondary fuels such as heavy oil, natural gas and pulverized coal. In this work, we put special importance on the improvement of the combustibility of waste plastics as a way to enhance energy efficiency in a blast furnace. As experimental variables to approach this target, the effects of plastic particle size, blast temperature, and the level of oxygen enrichment were investigated using a custom-made blast model designed to simulate a real furnace. Lastly, the combustion efficiency of the mixture of waste plastics and pulverized coal was tested. The observations made from these experiments led us to the conclusion that with the increase of both blast temperature and the level of oxygen enrichment, and with a decrease in particle size, the combustibility of waste polyethylene could be improved at a given distance from the tuyere. Also it was found that the efficiency of coal combustion decreased with the addition of plastics; however, the combustion efficiency of mixture could be comparable at a longer distance from the tuyere.

Radiotracers in Swedish Steel Industry

Energy Technology Data Exchange (ETDEWEB)

Eriksson, I.; Erwall, L. G. [Isotope Techniques Laboratory, Stockholm (Sweden); Nyquist, O. [Surahammars Bruks AB, Surahammar (Sweden)

1967-06-15

Recent tracer investigations in Swedish steel plants have mainly dealt with problems concerning uon-metallic inclusions, slag weight determination and - labelling of special steel qualities for identification. Suspected inclusion sources, such as furnace slag, ladle-bottom mortar and some brick materials as stopper, nozzle.and channel bricks have been labelled radioactively in different ways. The labelling technique has been studied for the different systems and a new method was developed for brick materials. This includes vacuum impregnation with an aqueous solution of the inactive tracer, reheating to 1300 Degree-Sign C and neutron-irradiation in a reactor. A sufficiently homogeneous labelling of the material was obtained in this way. The tracer used was terbium, which was added as the nitrate and then decomposed to oxide during the heating process. The oxide is strongly bound to the ceramic material. The number of radioactive inclusions was determined by.autoradiography, and related to the total number pf inclusions, obtained by visual slag-counting, to give the percentage of inclusions originating from the labelled object. Some investigations have been made using simultaneous labelling of two or more sources. It seems to be difficult, however, to measure separately more than two tracers: one short-lived (e.g. 140La) and one long-lived (e.g. {sup 160}Tb). The slag weight determinations were made using the isotope dilution technique with {sup 131}Ba and {sup 140}La as tracers. A difference in slag weight is sometimes obtained. An attempt is made to explain these deviations. The material transport through a blast furnace has been followed by using a piece of graphite, labelled with {sup 140}La{sub 2}O{sub 3}, and measuring the radiation intensity outside the furnace walls and in the tuyere. Studies have been made to determine suitable radiotracers for labelling of steel for subsequent identification. Up to three different isotopes can be used simultaneously

Corrosion Resistance of Steels and Armco-Fe in Lead Melt Saturated by Oxygen at 550 degree C

International Nuclear Information System (INIS)

Tsisar, V.P.; Fedirko, V.N.; Eliseeva, O.I.

2007-01-01

Corrosion resistance of stainless steels and Armco-Fe in static lead melt saturated by oxygen at 550 degree C for 2000 h was investigated. It was determined that double oxide layer was formed on the surface of investigated materials. Outer part of double oxide growths from the initial interface 'solid metal/liquid lead' towards the melt and consists of Fe 3 O 4 . Inner part of double oxide based on the matrix is composed of Fe 3 O 4 for Armco-Fe, Fe 1+x Cr 2-x O 4 for martensitic 0.2 C-13 Cr and ferritic-martensitic EP823 steels and Fe 1+x Cr 2- xO 4 +Ni for austenitic 18Cr-10Ni-1Ti. Lead did not penetrate into the matrix of tested materials and was detected only in the scale formed on austenitic steel

Power quality analysis of DC arc furnace operation using the Bowman model for electric arc

Science.gov (United States)

Gherman, P. L.

2018-01-01

This work is about a relatively new domain. The DC electric arc is superior to the AC electric arc and it’s not used in Romania. This is why we analyzed the work functions of these furnaces by simulation and model checking of the simulation results.The conclusions are favorable, to be carried is to develop a real-time control system of steel elaboration process.

Effect of Sulfur in Steel on Transient Evolution of Inclusions During Calcium Treatment

Science.gov (United States)

Liu, Yang; Zhang, Lifeng; Zhang, Ying; Duan, Haojian; Ren, Ying; Yang, Wen

2018-04-01

In the current study, the effect of S content in the molten steel on inclusions during calcium treatment was studied using an induction furnace. The calcium in steel decreased from 48 to 2 ppm, and the sulfur in steel changed a little with time. When sulfur content in steel was as low as 25 ppm during calcium treatment, inclusions shifted from CaO-Al2O3-CaS to Al2O3-CaO with about 35 pct CaO. When the sulfur increased over 90 ppm, more CaS-CaO formed just after the addition of calcium, and then the CaS content decreased from over 45 pct to lower than 15 pct and inclusions were mostly Al2O3-CaO-CaS and Al2O3-CaO with a high Al2O3 content. Thermodynamic calculation predicted the variation of the composition of inclusions, indicating good agreement with the measurement, while a certain deviation existed, especially for heats with 90 and 180 ppm sulfur. A reaction model was proposed for the formation of CaO and CaS, which considered the reaction between calcium vapor bubbles in the zone and the dissolved oxygen and sulfur in the molten steel, as described by a Langmuir-type adsorption isotherm with a reaction occurring on the remaining vacant sites. The variation of transient CaS inclusions was discussed based on the thermodynamic calculation and the morphology evolution of typical inclusions containing CaS.

Corrosion behavior of austenitic and ferritic/martensitic steels in oxygen-saturated liquid Pb-Bi eutectic at 450circC and 550circC

OpenAIRE

倉田 有司; 二川 正敏; 斎藤 滋

2005-01-01

Static corrosion tests of various austenitic and ferritic/martensitic steels were conducted in oxygen-saturated liquid Pb-Bi at 450circC and 550circC for 3000h to study the effects of temperature and alloying elements on corrosion behavior. Oxidation, grain boundary corrosion, dissolution and penetration were observed. The corrosion depth decreases at 450circC with increasing Cr content in steels regardless of ferritic/martensitic or austenitic steels. Appreciable dissolution of Ni and Cr doe...

The influence of cooling parameters on the speed of continuous steel casting

Science.gov (United States)

Tirian, G. O.; Gheorghiu, C. A.; Hepuţ, T.; Chioncel, C. P.

2018-01-01

This paper analyzes the cooling parameters of the continuous casting speed. In the researches carried out we aimed to establish some correlation equations between the parameters characterizing the continuous casting process, the temperature of the steel at the entrance to the crystallizer, the superheating of the steel and the flow of the cooling water in the crystallizer and different zones of the secondary cooling. Parallel to these parameters were also the values for the casting speed. The research was made for the casting of round ϕ270mm semi-finished steel products. The steel was developed in an electric EBT furnace with a capacity of 100t, treated in L.F. (Ladle - Furnace) and VD (Vacuum-Degassing) and poured in a 5-wire continuous casting plant. The obtained data was processed in MATLAB using three types of correlation equations. The obtained results are presented both in the analytical and graphical form, each correlation being analyzed from the technological point of view, indicating the optimal values for the independent parameters monitored. In the analysis we present a comparison between the results obtained after the three types of equations for each correlation.

Addition of electric arc furnace dust in hot metal changing the form of addition

International Nuclear Information System (INIS)

Marques Sobrinho, Vicente de Paulo Ferreira; Oliveira, Jose Roberto de; Vieira, Estefano Aparecido; Telles, Victor Bridi; Grillo, Felipe Fardin; Tenorio, Jorge Alberto Soares; Espinosa, Denise Crocce Romano

2014-01-01

This research aims to study the incorporation of the mass of electric arc furnace dust (EAFD), by addition in hot metal (1.78% Si) at a temperature of 1,400 degrees Celsius. The EAFD is from a steel plant producing long steel. The addition of the EAFD was as received, in the form of briquettes without agitation of the hot metal and in the form of briquettes with agitation of the hot metal. Previously, the EAFD was characterized using the following techniques: chemical analysis, size analysis, X-ray diffraction, scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) microanalysis. The achievement of fusion experiments in laboratory scale, took place in a vertical tubular furnace with temperature control. The fusion experiments to assess the incorporation of EAFD mass used graphite crucibles. After cooling, the hot metal and the slag, remaining in the crucible, were weighed to do a mass balance. A flow of inert gas (argon) was maintained inside the furnace during the experiments. Results show that the experiment with addition of EAFD as received presents the best result of incorporating the mass of the final hot metal (1.73%) combined with the lowest percentage of volatilized mass of EAFD (46.52%). The experiment addition of EAFD in the form of briquette with agitation of hot metal presents the lowest percentage of slag mass (4.58%). The zinc content of volatilized EAFD (64.30%) is higher than the zinc content of the imported ore concentrate (52%) and zinc content of the national ore concentrate (12% to 39%). The presence of lead and cadmium in the slag characterizing it as a hazardous solid waste. (author)

Exergo-Ecological Assessment Of Auxiliary Fuel Injection Into Blast-Furnace

Directory of Open Access Journals (Sweden)

Stanek W.

2015-06-01

Full Text Available Metallurgy represents complex technological chain supplied with different kinds of primary resources. Iron metallurgy based on blast-furnace process, dominates in world steel production. Metallurgical coke is the basic fuel in this case. Its production is connected with several environmental disadvantageous impacts. One of them is the extended production chain from primary energy to final energy. The reduction of coke consumption in the process can be achieved e.g. by injection of auxiliary fuels or increasing the thermal parameters in the process. In present injection of pulverised coal dominates while recirculation of top-gas seems to be future technology. However, the latter one requires the CO2 removal that additionally extended the production chain. The evaluation of resources management in complex energy-technological systems required application of advanced method based on thermodynamics. In the paper the system exergo-ecological assessment of pulverised coal injection into blast-furnace and top-gas recirculation has been applied. As a comparative criterion the thermo-ecological cost has been proposed.

Feasibility study of energy conservation at Vietnam Steel Corporation

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

Feasibility study was conducted of the project for energy conservation and reduction in greenhouse effect gas emission by introducing the honeycomb type heat storage burner technology to heating furnaces of Vietnam Steel Corporation (VSC). Furnaces for study are the bar mill furnace at Gia Sang plant of TISCO Steelorks, bar mill furnace at Thu Duc plant of SSC Steelworks, billet furnace at new bar mill of SSC Steelworks, slab furnace at new hot strip mill that VSC is now in the planning stage. As a result of the study, the energy conservation amount is 2,900 toe/y at TISCO Steelworks, 2,130 toe/y at SSC Steelworks, and 6,000 toe/y at VSC new hot strip mill, which totaled 11,030 toe/y. The amount of greenhouse effect gas reduction is 9,000 t-CO2/y at TISCO, 6,600 t-CO2/y at SSC, and 18,600 t-CO2/y at VSC, which totaled 34,200 t/y. The total investment amount is 0.23, 0.44, 1.32 and 1.99 billion yen for each. As to the profitability, the internal earning rate is 24%, 86%, 97% and 51% for each, which are all favorable. (NEDO)

The oxidation of stainless steels in water vapour-oxygen mixtures. Design and development of an original equipment

International Nuclear Information System (INIS)

Uller, Leonardo.

1981-02-01

A device including a thermobalance placed in a tight housing has been conceived and built. This apparatus is suitable to submit metallic samples to the action of dry oxygen, deoxygenated water vapour or mixtures of water vapour and oxygen. The first results obtained with this device, at 600 0 C, and for a 18-10 stainless steel are: - in the presence of deoxygenated water vapour, one observes very fast oxidation kinetics, with a roughly parabolic law (K approximately equal to 3x10 -2 mg 2 .cm -4 .h -1 ); - the addition of oxygen from about 10 vpm onwards, induces an important initial slowing down of the kinetics; - the duration of this 'induction' period rises with increasing the oxygen content of the water vapour, but the protection of the alloy due to the action of oxygen remains temporary; - in another way, experiments begun with water vapour, were continued with pure oxygen, and reciprocally. During these 'mixed' experiments, the weight increases were continually recorded. A swift slowing down has been observed in the first case and an important acceleration in the second one [fr

The effect of reduced oxygen content powder on the impact toughness of 316 steel powder joined to 316 steel by low temperature HIP

International Nuclear Information System (INIS)

Lind, Anders; Sundstroem, Johan

2004-11-01

During the manufacture of the blanket modules, 316L steel powder is simultaneously consolidated and joined to tubes and blocks of 316L materials by Hot Isostatic Pressing (HIP). The high processing temperature can detrimentally increase the grain size of the water cooling tubes in the structure and the blocks reducing their strength. It is well known that surface oxides on the powder particles negatively influence the impact toughness of material and joints consolidated in this way. By increasing the consolidation temperature the metallurgical bonding is improved, due to a redistribution of oxygen within the oxide layer towards more discrete oxide particles. In order to get acceptable mechanical properties of materials produced at a low HIP temperature the oxygen content on the powder surfaces needs to be reduced. The aim of this new techniques to reduce the oxygen content of the metal powder. The influence on Charpy impact energy and tensile strength were demonstrated

Basic survey project for Joint Implementation, etc., fiscal 1999. Survey of modernization of energy saving equipment at Southern Steel

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

For the purpose of reducing greenhouse effect gas emissions, a project was studied for the modernization of energy saving facilities at Southern Steel Co., Ltd. which is No. 2 iron/steel maker in Malaysia. Studies were made on scrap preheating equipment for electric furnace, direct hot charge rolling equipment (DHCR), and regenerative burner for billet heating furnace. The scrap preheating equipment recovers energy from the electric furnace exhaust gas, which saves energy of 70 kWh/t. The direct hot charge rolling equipment recovers the sensible heat of billets, of which energy saving of about 80 Mcal/t is expected. The generative burner, in which the ceramic heat exchanger is used, improves the heat recovery from exhaust gas by 20%. By adopting these technologies, an effect of energy saving of a total of 325 Mcal/t can be obtained. If the four major iron/steel making plants in Malaysia adopt the technologies, effects can be obtained of energy conservation of approximately 100,000 toe/y and reduction in greenhouse effect gas emissions by approximately 320,000 t-CO2/y. (NEDO)

Alkali activated slag mortars provide high resistance to chloride-induced corrosion of steel

Science.gov (United States)

Criado, Maria; Provis, John L.

2018-06-01

The pore solutions of alkali-activated slag cements and Portland-based cements are very different in terms of their chemical and redox characteristics, particularly due to the high alkalinity and high sulfide content of alkali-activated slag cement. Therefore, differences in corrosion mechanisms of steel elements embedded in these cements could be expected, with important implications for the durability of reinforced concrete elements. This study assesses the corrosion behaviour of steel embedded in alkali-activated blast furnace slag (BFS) mortars exposed to alkaline solution, alkaline chloride-rich solution, water, and standard laboratory conditions, using electrochemical techniques. White Portland cement (WPC) mortars and blended cement mortars (white Portland cement and blast furnace slag) were also tested for comparative purposes. The steel elements embedded in immersed alkali-activated slag mortars presented very negative redox potentials and high apparent corrosion current values; the presence of sulfide reduced the redox potential, and the oxidation of the reduced sulfur-containing species within the cement itself gave an electrochemical signal that classical electrochemical tests for reinforced concrete durability would interpret as being due to steel corrosion processes. However, the actual observed resistance to chloride-induced corrosion was very high, as measured by extraction and characterisation of the steel at the end of a 9-month exposure period, whereas the steel embedded in white Portland cement mortars was significantly damaged under the same conditions.

Furnace

Energy Technology Data Exchange (ETDEWEB)

Osintsev, V V; Khidiyatov, A M

1981-01-01

The purpose of the invention is to improve the operating efficiency of the furnace device containing prefurnaces connected to the main combustion chamber. For this purpose in the proposed furnace device is equipped with prefurnaces with burners, rectangular vertical chamber of combustion is equipped with central hearth projection. As indicated by studies, the hearth projection of the indicated projections promotes the development of transverse streams which guarantee effective mixing of the combustion products in the upper part of the combustion chamber 3. This reduces the nonuniformity of temperature at the outlet from the latter, decreases the probability of slagging and hot spots on the heating surface.

Production analysis of methanol and hydrogen of a modificated blast furnace gas using nuclear energy of the high temperature reactor

International Nuclear Information System (INIS)

Peschel, W.

1985-12-01

Modern blast furnaces are operated with a coke ration of 500 kg/t pig iron. The increase of the coke ratio to 1000 kg/t pig iron raises the content of carbon monoxide and hydrogen in the blast furnace gas. On the basis of a blast furnace gas modificated in such a way, the production of methanol and hydrogen is investigated under the coupling of current and process heat from the high temperature reactor. Moreover the different variants are discussed, for which respectively a material and energetic balance as well as an estimation of the production costs is performed. Regarding the subsequent treatment of the blast furnace gas it turns out favourably in principle to operate the blast furnace with a nitrogen-free wind consisting only of oxygen and steam. The production costs show a strong dependence on the raw material costs, whose influence is shown in a nomograph. (orig.) [de

New technologies and raw materials for iron and steel making

Energy Technology Data Exchange (ETDEWEB)

Holappa, L. [Helsinki Univ. of Technology, Otaniemi (Finland). Lab. of Metallurgy

1998-07-01

The current steelmaking is still mainly based on two alternatives routes. The first one is ore based production route via reduction in blast furnaces (BF) to produce carbon-rich hot metal which is then oxidised in basic oxygen converter process (BOF) to crude steel, then refined and alloyed in several secondary (ladle) metallurgical operations to its final composition, further followed by continuous casting and rolling operations. The second main steelmaking route starts from steel scrap as the main raw material, melting of scrap in electric furnaces to crude steel, the subsequent stages being corresponding to those in ore based steelmaking. Both these processes represent well-established and highly developed technologies. However, they have some drawbacks. Blast furnace process needs sinter or pellets and coke as its raw materials. That means erection of large integrates with high investment costs in the production units themselves as well as to avoid severe environmental issues. Scrap-based steelmaking is ideal from the viewpoint of recycling, but it is limited by the scrap availability and quality problems encountered by the noticeable metallic impurities in purchase scrap. Direct reduction of iron ore in solid state to produce direct reduced iron (DRI) has its roots in the early ironmaking history but was firstly commercialised on a modern concept at the end of the 1960's when the first Midrex installation was run into operation. Most of the DR-processes utilise natural gas as the reducing agent but also some processes utilising coal have been introduced and are used in industrial scale. The oil crises in the 1970's slowed down the progress of DRI production but during the last 15 years the production has steadily grown being nowadays about 35 Mton/year. That corresponds to roughly 10 pct of the total solid material input into the world steel production. No doubt, the growth will continue in the near future as well. Quite recently, a new process

Development and field testing of an alternative latrine design utilizing basic oxygen furnace slag as a treatment media for pathogen removal

Science.gov (United States)

Stimson, J.; Suhogusoff, A. V.; Blowes, D. W.; Hirata, R. A.; Ptacek, C. J.; Robertson, W. D.; Emelko, M. B.

2009-05-01

In densely-populated communities in developing countries, appropriate setback distances for pit latrines often cannot be met. An alternative latrine was designed that incorporates two permeable reactive media to treat pathogens and nitrate from effluent. Basic oxygen furnace (BOF) slag in contact with wastewater effluent elevates pH to levels (> 11) that inactivate pathogens. Saturated woodchip creates reducing conditions that encourage the growth of denitrifying bacteria which remove NO3-. The field application was constructed in Santo Antônio, a peri-urban community located 25 km south of the city of São Paulo, Brazil. A 2-m diameter pit was excavated to a depth of 4 m into the sandy-clay unsaturated zone. A geotextile liner was emplaced to create saturated conditions in the 0.5-m thick woodchip barrier. Above the woodchip barrier, a 1-m thick layer of BOF slag mixed with pea gravel and sand was emplaced. A series of filter layers, grading upward from coarse sand to fine gravel, where placed above the BOF layer, and gravel was also infilled around the outer perimeter of the excavation, to ensure O2 diffusion into the design, the formation of biofilm, and degradation of organic material. A control latrine, constructed with similar hydraulic characteristics and nonreactive materials, was constructed at a locality 100 m away, in the same geological materials. Total coliform, thermotolerant coliform, and E. coli are removed by approximately 4-5 log concentration units in less than one meter of vertical transport through the BOF slag media. In the control latrine, comparable reductions in these pathogenic indicators are observed over three meters of vertical transport. Removal of sulphur-reducing Clostridia, Clostridium perfrigens and somatic coliphage are also achieved in the alternative design, but initial concentrations in effluent are low. Some measurable concentrations of pathogen indicators are measured in lysimeters below the BOF layer, but are associated

Fatigue of carbon and low-alloy steels in LWR environments

International Nuclear Information System (INIS)

Chopra, O.K.; Michaud, W.F.; Shack, W.J.

1994-01-01

Fatigue tests have been conducted on A106-Gr B carbon steel and A533-Gr B low-alloy steel to evaluate the effects of an oxygenated-water environment on the fatigue life of these steels. For both steels, environmental effects are modest in PWR water at all strain rates. Fatigue data in oxygenated water confirm the strong dependence of fatigue life on dissolved oxygen (DO) and strain rate. The effect of strain rate on fatigue life saturates at some low value, e.g., between 0.0004 and 0.001%/s in oxygenated water with ∼0.8 ppm DO. The data suggest that the saturation value of strain rate may vary with DO and sulfur content of the steel. Although the cyclic stress-strain and cyclic-hardening behavior of carbon and low-alloy steels is distinctly different, the degradation of fatigue life of these two steels with comparable sulfur levels is similar. The carbon steel exhibits pronounced dynamic strain aging, whereas strain-aging effects are modest in the low-alloy steel. Environmental effects on nucleation of fatigue crack have also been investigated. The results suggest that the high-temperature oxygenated water has little or not effect on crack nucleation

Natural radioactivity in iron and steel materials by low-level gamma spectrometry

International Nuclear Information System (INIS)

Tanase, G.; Tanase, Maria

2003-01-01

High resolution low-level gamma spectrometry was applied to perform a radioactivity measurement in iron and steel raw materials (coal, coke, iron ore, pellets, manganese ore, limestone, dolomite), auxiliary materials (scorialite, oxide of Ti, bentonite), and some related final products (cast iron, slag, blast-furnace, flue dust) involved in iron making processing. We control the activity of materials in various kinds of samples and we investigate for transfer of radioactivity during the blast-furnace process. Artificial radioisotopes are rarely encountered. (authors)

Filterability of corrosion products formed between carbon steel and water. Influence of temperature and oxygen content

International Nuclear Information System (INIS)

Kelen, T.; Falk, I.

1975-09-01

A laboratory investigation has been made for the purpose of studying the influence of temperature and oxygen content on the filterability of corrosion products formed between carbon-steel and water. The experiments were performed in a high temperature loop where the water is initially heated in a pre-heater, then cooled and finally filtered. The corrosion products were transferred to thewater from a carbon-steel surface that had previously been neutron activated and the amount of iron present was determined from measurements of the γ-radiation emitted by Fe-59. Filterability was then computed as the ratio between the total amount of iron in the water phase and the amount of iron retained on the filter. The investigation covers a series of experiments at filtering temperatures of 20, 90 and 160 dec G, pre-heater temperatures up to 300 deg C and oxygen contents of 10 and 300 ppb O 2 . In addition the extent of iron deposition in the pre-heater and heat regulator has been determined after each series of experiments. Filterability exhibited a pronounced dependence upon both the filter and pre-heater temperatures and also upon the oxygen content. Among the conclusions to which the results lead is the observation that a strict comparison of filterability values for the fraction of corrosion products in cooled water samples is impossible when these are taken from 1) different sections of a high temperature system 2) a single sampling point while the system is being run up 3) two separate systems (e.g. steam boilers) operated at different temperatures 4) two separate systems operated at different oxygen contents. It accordingly appears advizable to restrict the use of cold-filtered samples from conventional steam-raising plants to the comparison of values relating to a single sampling point under constant operating conditions. (author)

Applications of radioisotopes for studying refractory wear-out in Bhilai Steel Plant

International Nuclear Information System (INIS)

Dubey, R.S.; Bose, U.P.; Shipstone, A.J.

1979-01-01

In Bhilai Steel Plant, investigations were carried out to study the refractory wear-out of (i) hearth bottom of blast furnaces, (ii) roof of open hearth furnaces, and (iii) hot metal mixer lining, by using radioisotope tracer techniques with a view to evaluate the life of the refractory lining at various locations and to help in planning its timely hot and cold repairs. The life of the refractory lining has the effective bearing on the overall production and hence on the economy of the plant. The two radiometric methods employed for studying the erosion of the refractory lining, by using isotope inserted bricks at various positions without damaging the lining are (i) based on recording the penetration of gamma rays emitting from the radioactive isotopes inserted at definite points of the brick lining and, (ii) by detecting the radioactivity of the pig iron or steel arising due to washing away of the respective radioactive isotopes previously inserted in the lining. In hot mixers also radioisotope sources were placed in the critical location of refractory lining and the washing out of radioisotope due to refractory brick wear out was detected by radiogauging at site. It has been found that radiotracer technique with periodic radiogauging is very useful method for tracing the radioisotope source if more than one refractory brick with isotope is placed, as in the case of open hearth furnaces. The results of radioanalysis revealed that radioactivity coming alongwith hot metal steel has been far below the permissible limit of concentration i.e. 20 micro-curie per ton of metal. Further, during dismantling of the residual refractory lining of open hearth furnaces or hot metal mixers, bricks containing radioisotopes have been successfully retrieved for safe disposal. (auth.)

Iron and steel research at CENIM

International Nuclear Information System (INIS)

Medina, S. F.; Lopez, F.; Morcillo, M.

2003-01-01

In 2002 the National Centre for Metallurgical Research (CENIM) celebrated its 39th anniversary. During this time, steel has been the most studied material of all the metals and alloys researched in the different projects funded by national science and technology plans, European metallurgical research programmes, and by the iron and steel making companies who over the years have placed their trust in the research work undertaken at CENIM. Two generations of researchers have dedicated their careers to studying the different aspects of steel, from primary metallurgy considering iron ores and enrichment processes, the thermodynamics of reactions in the blast furnace and in the ladle, thermal and thermomechanical treatments, the physical metallurgy of steels, their mechanical properties, and finally their deterioration in a wide range of media of different aggressivities. CENIM maintains its commitment to iron and steel research, drawing attention to the vast amount of research work undertaken and financed within the framework of the ECSC programme since Spain joined the European Community in January 1986. (Author) 3 refs

Effect of Microstructure on the Wear Behavior of Heat Treated SS-304 Stainless Steel

Directory of Open Access Journals (Sweden)

S. Kumar

2016-12-01

Full Text Available Sliding wear characteristics of some heat treated SS-304 stainless steel against EN-8 steel in dry condition have been studied in the present experimental work. Samples of SS-304 stainless steel have been heated in a muffle furnace in desired temperature and allowed to dwell for two hours. The heated specimen are then cooled in different media namely inside the furnace, open air, cutting grade oil (grade 44 and water at room temperature to obtain different grades of heat treatment. Microstructures and corresponding micro hardness of the samples have been measured along with Feritscopic studies. Wear characteristics have been studied in a multi tribo-tester (Ducom in dry sliding condition against EN-8 steel roller. Speed, load on job and duration of test run have been considered as the experimental parameters. The wear of the samples have been obtained directly from ‘Winducom 2006’ software. Mass loss of the samples before and after operation has also been considered as the measure of wear in the present study. All the samples have been slid against EN-8 steel roller with fixed experimental parameters. The data have been plotted, compared and analyzed. Effect of microstructures as well as micro hardness on the wear behavior has been studied and concluded accordingly.

Overview of Steel Slag Application and Utilization

Directory of Open Access Journals (Sweden)

Lim J.W.

2016-01-01

Full Text Available Significant quantities of steel slag are generated as waste material or byproduct every day from steel industries. Slag is produced from different types of furnaces with different operating conditions. Slag contains Ferrous Oxide, Calcium Oxide, Silica etc. Physical and chemical properties of slag are affected by different methods of slag solidification such as air cooled, steam, and injection of additives. Several material characterization methods, such as X-ray Diffraction (XRD, Scanned Electron Microscopy (SEM and Inductive Coupled Plasma (ICP-OES are used to determine elemental composition in the steel slag. Therefore, slags can become one of the promising materials in various applications such as in transportation industry, construction, cement production, waste water and water treatment. The various applications of steel slag indicate that it can be reused and utilized rather than being disposed to the landfill. This paper presents a review of its applications and utilization.

A Study on the Waste Water Treatment Technology for Steel Industry: Recycle And Reuse.

OpenAIRE

Sanjeev Kumar Sinha; Vikas Kumar Sinha; Samir Kr. Pandey; Anup Tiwari

2016-01-01

The steel industry is one of the most important and vital Industry of the present and the future. It is the asset of a nation. Steel plants use a tremendous amount of water for waste transfer, cooling and dust control. The steel plants have sintering mills, coke plants, blast furnaces, chemical byproducts and chemical processes, water cooled rolls, pumps, extrusion experiment, transfer lines for sludges and slurries. All these plants use a tremendous amount of water to cool the pr...

Stress corrosion cracking of austenitic stainless steels in high temperature water and alternative stainless steel

International Nuclear Information System (INIS)

Yonezawa, T.

2015-01-01

In order to clarify the effect of SFE on SCC resistance of austenitic stainless steels and to develop the alternative material of Type 316LN stainless steel for BWR application, the effect of chemical composition and heat treatment on SFE value and SCCGR in oxygenated high temperature water were studied. The correlation factors between SFE values for 54 heats of materials and their chemical compositions for nickel, molybdenum, chromium, manganese, nitrogen, silicon and carbon were obtained. From these correlation factors, original formulae for SFE values calculation of austenitic stainless steels in the SHTWC, SHTFC and AGG conditions were established. The maximum crack length, average crack length and cracked area of the IGSCC for 33 heats were evaluated as IGSCC resistance in oxygenated high temperature water. The IGSCC resistance of strain hardened nonsensitized austenitic stainless steels in oxygenated high temperature water increases with increasing of nickel contents and SFE values. From this study, it is suggested that the SFE value is a key parameter for the IGSCC resistance of non-sensitized strain hardened austenitic stainless steels. As an alternative material of Type 316LN stainless steel, increased SFE value material, which is high nickel, high chromium, low silicon and low nitrogen material, is recommendable. (author)

Alkaline carbonates in blast furnace process

Directory of Open Access Journals (Sweden)

P. Besta

2014-10-01

Full Text Available The production of iron in blast furnaces is a complex of physical, chemical and mechanical processes. The input raw materials contain not only metallic components, but also a number of negative elements. The most important negative elements include alkaline carbonates. They can significantly affect the course of the blast furnace process and thus the overall performance of the furnace. As a result of that, it is essential to accurately monitor the alkali content in the blast furnace raw materials. The article analyzes the alkali content in input and output raw materials and their impact on the blast furnace process.

Industrial furnace with improved heat transfer

Energy Technology Data Exchange (ETDEWEB)

Hoetzl, M.; Lingle, T.M.

1992-07-07

This patent describes an industrial furnace for heating work which emits volatiles during heating. It comprises a generally cylindrical, closed end furnace section defining a sealable heat transfer chamber for heating work disposed therein; fan means for directing furnace atmosphere as a swirling wind mass about the interior of the furnace section over a portion thereof; heat means for heating the wind mass within the fan chamber; and an incineration track formed as a circumferentially extending groove about the exterior of the furnace section and in heat transfer relationship with and situated at least to extend about a portion of the fan chamber.

Liquid Phase Sintering of Highly Alloyed Stainless Steel

DEFF Research Database (Denmark)

Mathiesen, Troels

1996-01-01

Liquid phase sintering of stainless steel is usually applied to improve corrosion resistance by obtaining a material without an open pore system. The dense structure normally also give a higher strength when compared to conventional sintered steel. Liquid phase sintrering based on addition...... of boride to AISI 316L type steels have previously been studied, but were found to be sensitive to intergranular corrosion due to formation of intermetallic phases rich in chromium and molybdenum. In order to improve this system further, new investigations have focused on the use of higher alloyed stainless...... steel as base material. The stainless base powders were added different amounts and types of boride and sintered in hydrogen at different temperatures and times in a laboratory furnace. During sintering the outlet gas was analyzed and subsequently related to the obtained microstructure. Thermodynamic...

Automated, High Temperature Furnace for Glovebox Operation

International Nuclear Information System (INIS)

Neikirk, K.

2001-01-01

The Plutonium Immobilization Project (PIP), to be located at the Savannah River Site SRS, is a combined development and testing effort by Lawrence Livermore National Laboratory (LLNL), Westinghouse Savannah River Company (WSRC), Pacific Northwest National Laboratory (PNNL), Argonne National Laboratory (ANL), and the Australian National Science and Technology Organization (ANSTO). The Plutonium Immobilization process involves the disposition of excess plutonium by incorporation into ceramic pucks. As part of the immobilization process, furnaces are needed for sintering the ceramic pucks. The furnace being developed for puck sintering is an automated, bottom loaded furnace with insulating package and resistance heating elements located within a nuclear glovebox. Other furnaces types considered for the application include retort furnaces and pusher furnaces. This paper, in part, will discuss the furnace technologies considered and furnace technology selected to support reliable puck sintering in a glovebox environment

Calculations in furnace technology

CERN Document Server

Davies, Clive; Hopkins, DW; Owen, WS

2013-01-01

Calculations in Furnace Technology presents the theoretical and practical aspects of furnace technology. This book provides information pertinent to the development, application, and efficiency of furnace technology. Organized into eight chapters, this book begins with an overview of the exothermic reactions that occur when carbon, hydrogen, and sulfur are burned to release the energy available in the fuel. This text then evaluates the efficiencies to measure the quantity of fuel used, of flue gases leaving the plant, of air entering, and the heat lost to the surroundings. Other chapters consi

Incinerator performance: effects of changes in waste input and furnace operation on air emissions and residues

DEFF Research Database (Denmark)

Astrup, Thomas; Riber, Christian; Pedersen, Anne Juul

2011-01-01

Waste incineration can be considered a robust technology for energy recovery from mixed waste. Modern incinerators are generally able to maintain relatively stable performance, but changes in waste input and furnace operation may affect emissions. This study investigated how inorganic air emissions...... including ‘as-large-as-possible’ changes in furnace operation (oxygen levels, air supply and burnout level) only using normal MSW as input. The experiments showed that effects from the added waste materials were significant in relation to: air emissions (in particular As, Cd, Cr, Hg, Sb), element transfer...... coefficients, and residue composition (As, Cd, Cl, Cr, Cu, Hg, Mo, Ni, Pb, S, Sb, Zn). Changes in furnace operation could not be directly linked to changes in emissions and residues. The results outlined important elements in waste which should be addressed in relation to waste incinerator performance. Likely...

Blast furnace top gas and dusts; Masuunin huippukaasu ja poelyt

Energy Technology Data Exchange (ETDEWEB)

Lohi, T.K.; Mannila, P.; Karjalahti, T.; Haerkki, J.

1997-12-31

This report is related to the `Gas Phase Reactions in a Blast Furnace` project. The aim of the project is to clarify the behaviour of gas phase in a blast furnace with high oil injection rate. The effect of blast furnace operation, iron reduction reactions, the amount of oil injected, alkalis, zinc and sulfur on the formation of top gas and dusts has been examined in this work. In addition, the gas cleaning system, i.e. the dust sack, gas scrubber, venturi scrubbers and an electric filter, of the blast furnaces of Rautaruukki Oy is presented. The composition of the top gas as well as the amount and composition of the dust from the gas cleaners were investigates in the experimental part of the research. The work has been focused on the analysis of carbon, iron, zinc, sulfur and alkalis. In addition to this, possible systematic variations caused by the discharge of hot metal were investigated. The experiments were made at blast furnaces no 1 and 2 of Rautaruukki Raahe Steel. The relationship between dust quantity and composition in the dust sack and the quantity of oil injected was analyzed on the basis of collected data. On the basis of experimental results, hot metal discharge has no effect on the composition or quantity of the top gas and dust. The composition of the dust varied between different gas cleaners. The coarsest and heaviest material remains in the dust sack. The lightest material separates at the electric filter. The main components at every gas cleaner were iron (9.4 - 38.1 %) and carbon (31.5 - 63.7 %). Particles with zinc and sulfur were separated at the venturi scrubbers (Zn = 3.0 % and S = 2.2 %) and the electric filter (Zn = 3.2 % and S = 2.6 %). Particles with alkalis were separated at the end of the gas cleaning process. The amount of sodium at the venturi scrubbers and the electric filter was 1.0 % on average. The average amount of potassium was 0.5 % at the venturi scrubber and 1.4 % at the electric filter 28 refs., 31 figs.

[Measurement of chemical agents in metallurgy field: electric steel plant].

Science.gov (United States)

Cottica, D; Grignani, E; Ghitti, R; Festa, D; Apostoli, P

2012-01-01

The steel industry maintains its important position in the context of the Italian production involving thousands of workers. The iron and steel processes are divided into primary steel industry, production of intermediate minerals, and secondary steel, scrap from the production of semi-finished industrial and consumer sector (metal inserted into components and metal used for dissipative uses, primarily coatings) and industrial waste. The paper presents the results of environmental monitoring carried out in some electric steel plant for the measurement of airborne chemicals that characterize the occupational exposure of workers employed in particular area like electric oven, to treatment outside the furnace, continuous casting area. For the sampling of the pollutants were used both personal and in fixed positions samplers. The pollutants measured are those typical of steel processes inhalable dust, metals, respirable dust, crystalline silica, but also Polycyclic Aromatic Hydrocarbons (PAH), polychlorinated dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs).

Passive neutralization of acid mine drainage using basic oxygen furnace slag as neutralization material: experimental and modelling.

Science.gov (United States)

Zvimba, John N; Siyakatshana, Njabulo; Mathye, Matlhodi

2017-03-01

This study investigated passive neutralization of acid mine drainage using basic oxygen furnace slag as neutralization material over 90 days, with monitoring of the parameters' quality and assessment of their removal kinetics. The quality was observed to significantly improve over time with most parameters removed from the influent during the first 10 days. In this regard, removal of acidity, Fe(II), Mn, Co, Ni and Zn was characterized by fast kinetics while removal kinetics for Mg and SO 4 2- were observed to proceed slowly. The fast removal kinetics of acidity was attributed to fast release of alkalinity from slag minerals under mildly acidic conditions of the influent water. The removal of acidity through generation of alkalinity from the passive treatment system was also observed to generally govern the removal of metallic parameters through hydroxide formation, with overall percentage removals of 88-100% achieved. The removal kinetics for SO 4 2- was modelled using two approaches, yielding rate constant values of 1.56 and 1.53 L/(day mol) respectively, thereby confirming authenticity of SO 4 2- removal kinetics experimental data. The study findings provide insights into better understanding of the potential use of slags and their limitations, particularly in mine closure, as part of addressing this challenge in South Africa.

A novel estimation of electrical and cooling losses in electric arc furnaces

International Nuclear Information System (INIS)

Trejo, Eder; Martell, Fernando; Micheloud, Osvaldo; Teng, Lidong; Llamas, Armando; Montesinos-Castellanos, Alejandro

2012-01-01

A method to calculate electrical losses and a heat transfer model of a conventional Electric Arc Furnace (EAF) are presented. The application of a novel power theory for the EAF was used to compute electrical losses and it was compared with conventional power calculations. The electrical losses and electrical variables were used as input parameters to the proposed heat transfer model. Chemical energy sources were included as energy inputs to estimate the overall heat transferred including the heat losses in the cooling system. In the heat transfer model the furnace was divided in 11 inner surfaces and the radiation view factors between them were estimated by a commercial finite element software. Variations of the view factors for different arc coverage were evaluated. Different scenarios for cooling panels losses, with respect to arc coverage and thickness of slag layers adhered to cooling system panels, were analyzed. The approach presented in this work allows calculation of energy balances in electrical arc furnaces with low computational resources. Finally, the contribution of this research work is to define a framework for further research oriented to improve both the electrical and thermal energy efficiencies to increase productivity and reduce energy consumption in steel plants. -- Highlights: ► Radiation view factors for the electric arc furnace are estimated. ► Potential reduction in cooling losses is estimated to be 60 kWh/ton. ► Electrical losses are calculated based in the randomness power theory. ► The new approach yields an increase of 10% in the electrical losses. ► An analytic model is used to estimate the radiation mechanism.

Electrostatic Levitation Furnace for the ISS

Science.gov (United States)

Murakami, Keiji; Koshikawa, Naokiyo; Shibasaki, Kohichi; Ishikawa, Takehiko; Okada, Junpei; Takada, Tetsuya; Arai, Tatsuya; Fujino, Naoki; Yamaura, Yukiko

2012-01-01

JAXA (Japan Aerospace Exploration Agency) has just started the development of Electrostatic Levitation Furnace to be launched in 2014 for the ISS. This furnace can control the sample position with electrostatic force and heat it above 2000 degree Celsius using semiconductor laser from four different directions. The announcement of Opportunity will be issued soon for this furnace. In this paper, we will show the specifications of this furnace and also the development schedule

Ferronickel Preparation from Nickeliferous Laterite by Rotary Kiln-Electric Furnace Process

Science.gov (United States)

Li, Guanghui; Jia, Hao; Luo, Jun; Peng, Zhiwei; Zhang, Yuanbo; Jiang, Tao

Nickel is an important strategic metal, which is mainly used for stainless steel production. In the recent years, ferronickel has been used as a substitute for electrolytic nickel for alleviating the cost of stainless steel production. Rotary kiln-electric furnace (RKEF) smelting is currently the world-wide mainstreaming process for ferronickel production from nickeliferous laterite ore, in spite of the high power consumption. In this study, aiming to provide some meaningful guidance for ferronickel production of RKEF smelting, reductive roasting followed by smelting process was carried out. The conditions including reducing parameters (roasting temperature and time) and smelting parameters (coke dosage, CaO dosage, melting temperature and time) were ascertained. The metal recovery ratios, as well as Ni, Fe, S and P content of ferronickel were considered. The results showed that a ferronickel containing 10. 32 wt. % Ni was obtained from a laterite with 1. 85 wt. % Ni, the nickel recovery ratio was about 99%.

Use of soil-steel slag-class-C fly ash mixtures in subgrade applications.

Science.gov (United States)

2012-12-07

In Indiana, large quantities of recyclable : materials - such as steel slag, blast furnace : slag and fly ash - are generated each year as : by-products of various industries. Instead of : disposing these by-products into landfills, : we can recycle ...

Arsenic removal using steel manufacturing byproducts as permeable reactive materials in mine tailing containment systems.

Science.gov (United States)

Ahn, Joo Sung; Chon, Chul-Min; Moon, Hi-Soo; Kim, Kyoung-Woong

2003-05-01

Steel manufacturing byproducts were tested as a means of treating mine tailing leachate with a high As concentration. Byproduct materials can be placed in situ as permeable reactive barriers to control the subsurface release of leachate from tailing containment systems. The tested materials had various compositions of elemental Fe, Fe oxides, Ca-Fe oxides and Ca hydroxides typical of different steel manufacturing processes. Among these materials, evaporation cooler dust (ECD), oxygen gas sludge (OGS), basic oxygen furnace slag (BOFS) and to a lesser degree, electrostatic precipitator dust (EPD) effectively removed both As(V) and As(III) during batch experiments. ECD, OGS and BOFS reduced As concentrations to <0.5mg/l from 25mg/l As(V) or As(III) solution in 72 h, exhibiting higher removal capacities than zero-valent iron. High Ca concentrations and alkaline conditions (pH ca. 12) provided by the dissolution of Ca hydroxides may promote the formation of stable, sparingly soluble Ca-As compounds. When initial pH conditions were adjusted to 4, As reduction was enhanced, probably by adsorption onto iron oxides. The elution rate of retained As from OGS and ECD decreased with treatment time, and increasing the residence time in a permeable barrier strategy would be beneficial for the immobilization of As. When applied to real tailing leachate, ECD was found to be the most efficient barrier material to increase pH and to remove As and dissolved metals.

Accelerated Carbonation of Steel Slag Compacts: Development of High-Strength Construction Materials

Energy Technology Data Exchange (ETDEWEB)

Quaghebeur, Mieke; Nielsen, Peter, E-mail: peter.nielsen@vito.be; Horckmans, Liesbeth [Sustainable Materials Management, VITO, Mol (Belgium); Van Mechelen, Dirk [RECMIX bvba, Genk (Belgium)

2015-12-17

Mineral carbonation involves the capture and storage of carbon dioxide in carbonate minerals. Mineral carbonation presents opportunities for the recycling of steel slags and other alkaline residues that are currently landfilled. The Carbstone process was initially developed to transform non-hydraulic steel slags [stainless steel (SS) slag and basic oxygen furnace (BOF) slags] in high-quality construction materials. The process makes use of accelerated mineral carbonation by treating different types of steel slags with CO{sub 2} at elevated pressure (up to 2 MPa) and temperatures (20–140°C). For SS slags, raising the temperature from 20 to 140°C had a positive effect on the CO{sub 2} uptake, strength development, and the environmental properties (i.e., leaching of Cr and Mo) of the carbonated slag compacts. For BOF slags, raising the temperature was not beneficial for the carbonation process. Elevated CO{sub 2} pressure and CO{sub 2} concentration of the feed gas had a positive effect on the CO{sub 2} uptake and strength development for both types of steel slags. In addition, the compaction force had a positive effect on the strength development. The carbonates that are produced in situ during the carbonation reaction act as a binder, cementing the slag particles together. The carbonated compacts (Carbstones) have technical properties that are equivalent to conventional concrete products. An additional advantage is that the carbonated materials sequester 100–150 g CO{sub 2}/kg slag. The technology was developed on lab scale by the optimization of process parameters with regard to compressive strength development, CO{sub 2} uptake, and environmental properties of the carbonated construction materials. The Carbstone technology was validated using (semi-)industrial equipment and process conditions.

Out-of-pile experiments of fuel-cladding chemical interaction, (2)

International Nuclear Information System (INIS)

Konashi, Kenji; Yato, Tadao; Kaneko, Hiromitsu; Honda, Yutaka

1980-01-01

Cesium seems to be one of the most important fission products in the fuel-cladding chemical interaction of fuel pins for LMFBRs. However the FCCI under irradiation cannot always be explained by considering only cesium-oxygen system as the corrosive, since attack does not occur in the cesium-oxygen system unless oxygen potential is sufficiently high. Cesium-tellurium-oxygen system has been proposed to account for heavy cladding attack which was sometimes found in hypostoichiometric mixed oxide fuel pins. In this paper, the experiment on the reaction of liquid tellurium with stainless steel is reported. The type 316 stainless steel claddings for Monju type fuel pins were used as the test specimens. Tellurium was contained into the cladding tubes with end plugs. The temperature dependence of the attack by tellurium was examined in the range from 450 to 900 deg C for 30 min, and the heating time dependence was examined from 5 min to 200 hr at 725 deg C. An infrared lamp furnace was used for the experiment within 7 hr, and a resistance furnace for longer experiment. The character of corrosion was matrix attack, and the reaction products on the stainless steel surfaces consisted of chrome rich inner phase and iron and nickel rich outer phase. The results are reported. (Kako, I.)

Thermal design of a pressure electroslag remelting furnace applied for 5; Diseno termico de un horno presurizado de refusion por electroescoria de 5 Kg

Energy Technology Data Exchange (ETDEWEB)

Cruz M, J P

1999-07-01

Actual work defines the thermal design methodology for pressure electroslag remelting furnaces (P ESR) of variable capacity, applied for 5 Kg. It begins with classification and description of secondary refining furnaces, after PESR process and the concept of thermal design are described. Next, in base of the steel weight to remelt (5 Kg); ingot, crucible and electrode dimensions are obtained. These elements will be inside of pressure vessel whose thickness are determined according to ASMECode (Section 8, Division 1, U G-27). It was developed a computer program, where the furnace capacity can be modified, so like other conditions, and display principal dimensions of the furnace. Current and voltage are obtained from the heat necessary to remelt the ingot and the heat transfer in the crucible, is analysed because of it is the most critical element. It was selected too the equipment to registry temperatures and pressure in base of thermocouple characteristics. (Author)

Fiscal 1998 research report on the feasibility study on energy conservation of Zaporozhye steelworks; Zaporozhye seitetsusho sho energy 1998 nendo chosa hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-03-01

For the Japan-Russia joint project, this report summarizes the feasibility study results on improvement of waste heat recovery at blast furnace hot stoves (recovery of sensible heat of exhaust gas by water or other heat media, and use of preheating combustion air and fuel gas), improvement of the thermal efficiency of slabbing soaking furnaces (optimization of burner combustion by improving control of an air fuel ratio, and heat patterns in heating), and other operational improvement for Zaporozhye steelworks, Ukraine (2,370,000t/y in crude steel production). As the field survey result, various other energy-saving issues were found in addition to the above 2 themes. 9 projects thus were identified in blast furnace, steel making, rolling and energy fields as follows: improvement of combustion control at hot stoves, waste heat recovery equipment for hot stoves, blast furnace top pressure recovery turbine (TRT) power generation equipment, blast furnace top gas recovery equipment, changeover from an open hearth furnace to a basic oxygen furnace, adoption of continuous casting, improvement of slab yield in slabbing, shortening of a track time, drop of insertion temperature in direct hot charge rolling, and the gas turbine cogeneration plant. (NEDO)

Microstructure and Hardness of High Temperature Gas Nitrided AISI 420 Martensitic Stainless Steel

Directory of Open Access Journals (Sweden)

Ibrahim Nor Nurulhuda Md.

2014-07-01

Full Text Available This study examined the microstructure and hardness of as-received and nitrided AISI 420 martensitic stainless steels. High temperature gas nitriding was employed to treat the steels at 1200°C for one hour and four hours using nitrogen gas, followed by furnace cooled. Chromium nitride and iron nitride were formed and concentrated at the outmost surface area of the steels since this region contained the highest concentration of nitrogen. The grain size enlarged at the interior region of the nitrided steels due to nitriding at temperature above the recrystallization temperature of the steel and followed by slow cooling. The nitrided steels produced higher surface hardness compared to as-received steel due to the presence of nitrogen and the precipitation of nitrides. Harder steel was produced when nitriding at four hours compared to one hour since more nitrogen permeated into the steel.

Incorporation of ladle furnace slag in ceramic formulations: study of extrusion zones

International Nuclear Information System (INIS)

Feitosa, E.F.; Santana, C.M.; Luna, D.S.; Santos, D.M.S.; Silva, G.S.; Noleto, L.T.; Almeida, N.C.; Rabelo, A.A.; Fagury Neto, E.

2016-01-01

This study aimed to investigate the effect of incorporation of ladle furnace slag (LFS) in two clays with higher and lower plasticity, used for the manufacture of structural ceramics. The LFS from a local steel making plant was added to ceramic compositions in proportions of 8 %, 14 % and 16 %. The formulations were tested in appropriate equipment that measures the liquid limit and plastic limit. The property examined was the plasticity index, in order to make a study of the extrusion zones. Results showed that the addition of slag into clay mixtures alters the plasticity; however, the extrusion process was not hampered. (author)

Greener durable concretes through geopolymerisation of blast furnace slag

International Nuclear Information System (INIS)

Rajamane, N P; Nataraja, M C; Jeyalakshmi, R; Nithiyanantham, S

2015-01-01

The eco-friendliness of concrete is quantified by parameters such as ‘embodied energy’ (EE) and ‘embodied CO 2 emission’ (ECO 2 e), besides duration of designed ‘service life’. It may be noted that ECO 2 e is also referred as carbon footprint (CF) in the literature. Geopolymer (GP) is an inorganic polymeric gel, a type of amorphous alumino-silicate product, which can be synthesised by polycondensation reactions. The concrete reported in this paper was prepared using industrial wastes in the form of blast furnace slag, fly ash as geopolymeric source materials and sodium silicate and sodium hydroxide as activators. Many mechanical properties such as compressive strength, chloride diffusion, steel corrosion, rapid chloride permeability test and rapid migration test are compared with Portland cement. (paper)

Automated, High Temperature Furnace for Glovebox Operation

International Nuclear Information System (INIS)

Neikirk, K.

2001-01-01

The U.S. Department of Energy will immobilize excess plutonium in the proposed Plutonium Immobilization Plant (PIP) at the Savannah River Site (SRS) as part of a two track approach for the disposition of weapons usable plutonium. As such, the Department of Energy is funding a development and testing effort for the PIP. This effort is being performed jointly by Lawrence Livermore National Laboratory (LLNL), Westinghouse Savannah River Company (WSRC), Pacific Northwest National Laboratory (PNNL), and Argonne National Laboratory (ANL). The Plutonium Immobilization process involves the disposition of excess plutonium by incorporation into ceramic pucks. As part of the immobilization process, furnaces are needed for sintering the ceramic pucks. The furnace being developed for puck sintering is an automated, bottom loaded furnace with insulting package and resistance heating elements located within a nuclear glovebox. Other furnaces considered for the application include retort furnaces and pusher furnaces. This paper, in part, will discuss the furnace technologies considered and furnace technology selected to support reliable puck sintering in a glovebox environment. Due to the radiation levels and contamination associated with the plutonium material, the sintering process will be fully automated and contained within nuclear material gloveboxes. As such, the furnace currently under development incorporates water and air cooling to minimize heat load to the glovebox. This paper will describe the furnace equipment and systems needed to employ a fully automated puck sintering process within nuclear gloveboxes as part of the Plutonium Immobilization Plant

Characterization of Iron and Steel Industry Slags to be Recycled under Ecological Aspects as a Recycling Concept for Waste Treatment

International Nuclear Information System (INIS)

Khalil, T.K.; Aly, H.F.; Bossert, J.

1999-01-01

The recycling and final disposal of different types of industrial waste play an important role in decreasing environmental pollution all over the world. Three different solid waste slags from steel industries situated in the Helwan area (Cairo-Egypt), namely blast furnace slags, oxygen converter slags arc furnace slags were studied. The morphology of the collected slag powders was examined using scanning electron microscopy (SEM). Surface characteristics of the slag powders were measured through nitrogen gas adsorption and application of the BET equation at 77 K. The thermal behaviour of the slag powders was studied with the help of differential thermal analysis (DTA) and thermogravimetry(TG)> Due to the presence of some changes in the DTA base lines, possibly as a result of phase transformations, X-ray diffraction was applied to identify these phases. The sintering behaviour of the compact slag powders after isostatic pressing was evaluated using dilatometry. The sintering and melting temperature of the studied samples were determined using heating microscopy. The effect of changing sintering temperature and of applying different isostatic pressures on the density and porosity of the slag powder compacts was investigated

Using ferrosilicon production slags for reduction of open-hearth steel

International Nuclear Information System (INIS)

Grabeklis, A.A.; Vlasov, N.N.; Fadeev, I.G.; Zajchenko, M.V.; Aksenovich, V.I.

1976-01-01

Slags from the production of electric furnace ferrosilicon contain a considerable amount of silicon in recovered form (regulus and SiC) and can be used instead of standard ferroalloys (FS18, FS25 and FS45) for deoxidation with silicon in the furnace during the smelting of a number of carbon and alloyed steels. Test open-hearth heats show that highly dispersed SiC in the composition of this slag ensures active diffusion deoxidation and rapid suppression of bath boiling. The test metal can be compared with the conventional one in all the quality aspects, the recovery of phosphorus during deoxidation and tapping slightly increases

Using ferrosilicon production slags for reduction of open-hearth steel

Energy Technology Data Exchange (ETDEWEB)

Grabeklis, A A; Vlasov, N N; Fadeev, I G; Zaichenko, M V; Aksenovich, V I [Ural' skij Nauchno-Issledovatel' skij Inst. Chernykh Metallov, Sverdlovsk (USSR)

1976-05-01

Slags from the production of electric furnace ferrosilicon contain a considerable amount of silicon in recovered form (regulus and SiC) and can be used instead of standard ferroalloys (FS18, FS25 and FS45) for deoxidation with silicon in the furnace during the smelting of a number of carbon and alloyed steels. Test open-hearth heats show that highly dispersed SiC in the composition of this slag ensures active diffusion deoxidation and rapid suppression of bath boiling. The test metal can be compared with the conventional one in all the quality aspects, the recovery of phosphorus during deoxidation and tapping slightly increases.

ABOUT RATIONING MAXIMUM ALLOWABLE DEFECT DEPTH ON THE SURFACE OF STEEL BILLETS IN PRODUCTION OF HOT-ROLLED STEEL

Directory of Open Access Journals (Sweden)

PARUSOV E. V.

2017-01-01

Full Text Available Formulation of the problem. Significant influence on the quality of rolled steel have various defects on its surface, which in its turn inherited from surface defects of billet and possible damage to the surface of rolled steel in the rolling mill line. One of the criteria for assessing the quality indicators of rolled steel is rationing of surface defects [1; 2; 3; 6; 7]. Current status of the issue. Analyzing the different requirements of regulations to the surface quality of the rolled high-carbon steels, we can conclude that the maximum allowable depth of defects on the surface of billet should be in the range of 2.0...5.0 mm (depending on the section of the billet, method of its production and further the destination Purpose. Develop a methodology for calculating the maximum allowable depth of defects on the steel billet surface depending on the requirements placed on the surface quality of hot-rolled steel. Results. A simplified method of calculation, allowing at the rated depth of defects on the surface of the hot-rolled steel to make operatively calculation of the maximum allowable depth of surface defects of steel billets before heating the metal in the heat deformation was developed. The findings shows that the maximum allowable depth of surface defects is reduced with increasing diameter rolled steel, reducing the initial section steel billet and degrees of oxidation of the metal in the heating furnace.

Quality of structural steel melted by single-slag process

International Nuclear Information System (INIS)

Levin, A.M.; Andreev, V.I.; Monastyrskij, A.V.; Drozdova, M.F.; Pashchenko, V.E.; Orzhekh, M.B.

1982-01-01

The 40Kh and 12KhN3A steels were used to compare the quality of the metal manufactured according to several variants of a single-slag process with the metal of a conventional melting technology. Investigation results show, that a single-slag process metal has higher sulfides and oxides contents as well as an increased anisotropy of mechanical properties while its tendency to flake formation is weaker due to a less degree of gas saturation. It is marked that anisotropy in the properties and a sulfide content may be decreased by out-of-furnace treatment of steels

The analysis of irradiated nuclear fuel and cladding materials, determination of carbon, hydrogen and oxygen/metal ratio

International Nuclear Information System (INIS)

Jones, I.G.

1976-02-01

Equipment has been developed for the determination of carbon, hydrogen and oxygen/metal ratio on irradiated fuels, of carbon in stainless steel cladding materials and in graphite rich deposits, and of hydrogen in zircaloy. Carbon is determined by combustion to carbon dioxide which is collected and measured manometrically, hydrogen by vacuum extraction followed by diffusion through a palladium thimble, and oxygen/metal ratio by CO/CO 2 equilibration. A single set of equipment was devised in order to minimise the time and work involved in changing to a different set of equipment in a separate box, for each type of analysis. For each kind of analysis, alterations to the apparatus are involved but these can be carried out with the basic set in position in a shielded cell, although to do so it is necessary to obtain access via the gloves on the fibre-glass inner glove box. This requires a removal of samples emitting radiation, by transfer to an adjoining cell. A single vacuum system is employed. This is connected through a plug in the lead wall of the shielded cell, and couplings in the glove box wall to the appropriate furnaces. Carbon may be determined, in stainless steel containing 400 to 800 ppm C, with a coefficient of variation of +- 2%. On deposits containing carbon, the coefficient of variation is better than +- 1% for 2 to 30 mg of carbon. Hydrogen, at levels between 30 and 200 ppm in titanium can be determined with a coefficient of variation of better than +- 5%. Titanium has been used in lieu of zircaloy since standardised zircaloy specimens are not available. The precision for oxygen/metal ratio is estimated to be +- 0.001 Atoms oxygen. Sample weights of 200 mg are adequate for most analyses. (author)

Improved Casting Furnace Conceptual Design

Energy Technology Data Exchange (ETDEWEB)

Fielding, Randall Sidney [Idaho National Lab. (INL), Idaho Falls, ID (United States); Tolman, David Donald [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2017-02-01

In an attempt to ensure more consistent casting results and remove some schedule variance associated with casting, an improved casting furnace concept has been developed. The improved furnace uses the existing arc melter hardware and glovebox utilities. The furnace concept was designed around physical and operational requirements such as; a charge sized of less than 30 grams, high heating rates and minimal additional footprint. The conceptual model is shown in the report as well as a summary of how the requirements were met.

Airborne heavy metal pollution in the environment of a danish steel plant

DEFF Research Database (Denmark)

Vestergaard, N. K.; Stephansen, U.; Rasmussen, L.

1986-01-01

A survey of heavy metal deposition was carried out in the vicinity of a Danish steel plant. Bulk precipitation and transplanted lichen (Hypogymnia physodes (L.) Nyl.) were sampled at 12 stations in the environment before and after the production had been converted from open-hearth furnaces...

Recycling of electric arc furnace dust; Reciclagem de poeira de aciaria eletrica

Energy Technology Data Exchange (ETDEWEB)

Marques Sobrinho, Vicente de Paulo Ferreira; Oliveira, Jose Roberto de, E-mail: vicente@ifes.edu.b [Instituto Federal de Ciencia e Tecnologia do Espirito Santo (IFES), Vitoria, ES (Brazil); Tenorio, Jorge Alberto Soares; Espinosa, Denise Crocce Romano [Universidade de Sao Paulo (EPUSP), SP (Brazil). Escola Politecnica

2010-07-01

This research aims to study the process of incorporation of the metal iron in electric arc furnace dust (EAFD), from a steel mill producing long steel by liquid iron in addition to the changing temperature of 1400 degrees Celsius of EAFD 'as received', the percentage of EAFD to be added (5, 10 and 20% of initial weight of sample pig iron) and the time of withdrawal of the sample of pig iron and slag (30 minutes after the addition of EAFD). Previously, the EAFD will be characterized using the following techniques: chemical analysis, size analysis, specific surface area, Xray diffraction, scanning electron microscopy (SEM) and Energy Dispersive Spectroscopy (EDS) microanalysis. . After characterization, the EAFD will be added to the bath of liquid pig iron. It is expected that the results obtained at the end of the research allow the evaluation of the iron metal incorporation of EAFD in pig iron bath. (author)

Industrial and process furnaces principles, design and operation

CERN Document Server

Jenkins, Barrie

2014-01-01

Furnaces sit at the core of all branches of manufacture and industry, so it is vital that these are designed and operated safely and effi-ciently. This reference provides all of the furnace theory needed to ensure that this can be executed successfully on an industrial scale. Industrial and Process Furnaces: Principles, 2nd Edition provides comprehensive coverage of all aspects of furnace operation and design, including topics essential for process engineers and operators to better understand furnaces. This includes: the combustion process and its control, furnace fuels, efficiency,

Behavior of coke in large blast furnaces

Energy Technology Data Exchange (ETDEWEB)

Nakamura, N

1978-01-01

Three blast furnaces were quenched in operation and the contents were examined; the temperature distribution was also measured, using Tempil pellets. The furnaces examined included a low productivity one, which was examined to see what was wrong. Changes in the quality of coke as it descends in the furnace, and coke behavior in the raceway and hearth are reported. The functions required of coke, and the effects of poor coke quality, are explained, together with the coke quality required in large blast furnaces. A theoretical study of the role of coke in large blast furnaces is included.

A combined arc-melting and tilt-casting furnace for the manufacture of high-purity bulk metallic glass materials.

Science.gov (United States)

Soinila, E; Pihlajamäki, T; Bossuyt, S; Hänninen, H

2011-07-01

An arc-melting furnace which includes a tilt-casting facility was designed and built, for the purpose of producing bulk metallic glass specimens. Tilt-casting was chosen because reportedly, in combination with high-purity processing, it produces the best fatigue endurance in Zr-based bulk metallic glasses. Incorporating the alloying and casting facilities in a single piece of equipment reduces the amount of laboratory space and capital investment needed. Eliminating the sample transfer step from the production process also saves time and reduces sample contamination. This is important because the glass forming ability in many alloy systems, such as Zr-based glass-forming alloys, deteriorates rapidly with increasing oxygen content of the specimen. The challenge was to create a versatile instrument, in which high purity conditions can be maintained throughout the process, even when melting alloys with high affinity for oxygen. Therefore, the design provides a high-vacuum chamber to be filled with a low-oxygen inert atmosphere, and takes special care to keep the system hermetically sealed throughout the process. In particular, movements of the arc-melting electrode and sample manipulator arm are accommodated by deformable metal bellows, rather than sliding O-ring seals, and the whole furnace is tilted for tilt-casting. This performance of the furnace is demonstrated by alloying and casting Zr(55)Cu(30)Al(10)Ni(5) directly into rods up to ø 10 mm which are verified to be amorphous by x-ray diffraction and differential scanning calorimetry, and to exhibit locally ductile fracture at liquid nitrogen temperature.

A system dynamics analysis of energy consumption and corrective policies in Iranian iron and steel industry

International Nuclear Information System (INIS)

Ansari, Nastaran; Seifi, Abbas

2012-01-01

Iron and steel industry is the most energy intensive industrial sector in Iran. Long time subsidized energy has led to low energy efficiency in this industry. The sudden subsidy reform of energy prices in Iran is expected to have a great impact on steel production and energy consumption. A system dynamics model is presented in this paper to analyze steel demand, production and energy consumption in an integrated framework. A co-flow structure is used to show how subsidy reform affects energy consumption in the long run. The main focus of this paper is on direct and indirect natural gas consumption in the steel industry. Scrap based Electric Arc Furnace technology has been evaluated as an energy efficient way for steel making. The energy consumption in steel industry is estimated under various steel production and export scenarios while taking into account new energy prices to see the outlook of possible energy demand in steel industry over next 20 years. For example it is shown that under reference production scenario, potential reduction in gas consumption forced by complete removal of energy subsidy and utilizing scrap could lead to 85 billion cubic meters of gas saving over the next 20 years. -- Highlights: ► We develop a system dynamics model to analyze steel demand, production and energy consumption in Iran. ► Various scenarios have been simulated to see the energy demand of Iranian steel industry over the next 20 years. ► A co-flow structure is used to show how subsidy reform would affect energy consumption in the long run. ► A co-flow structure has been built into the SD model to formulate consumers' behavior in response to energy prices. ► Scrap based Electric Arc Furnace technology has been evaluated as an energy efficient alternative for steel making.

Volatile release and particle formation characteristics of injected pulverized coal in blast furnaces

International Nuclear Information System (INIS)

Chen, Wei-Hsin; Du, Shan-Wen; Yang, Tsung-Han

2007-01-01

Volatiles release and particle formation for two kinds of pulverized coals (a high volatile bituminous coal and a low volatile bituminous coal) in a drop tube furnace are investigated to account for the reactions of pulverized coal injected in blast furnaces. Two different sizes of feed particles are considered; one is 100-200 mesh and the other is 200-325 mesh. By evaluating the R-factor, the devolatilization extent of the larger feed particles is found to be relatively poor. However, the swelling behavior of individual or two agglomerated particles is pronounced, which is conducive to gasification of the chars in blast furnaces. In contrast, for the smaller feed particles, volatiles liberated from the coal particles can be improved in a significant way as a result of the amplified R-factor. This enhancement can facilitate the performance of gas phase combustion. Nevertheless, the residual char particles are characterized by agglomeration, implying that the reaction time of the char particles will be lengthened, thereby increasing the possibility of furnace instability. Double peak distributions in char particle size are observed in some cases. This possibly results from the interaction of the plastic state and the blowing effect at the particle surface. Considering the generation of tiny aerosols composed of soot particles and tar droplets, the results indicate that their production is highly sensitive to the volatile matter and elemental oxygen contained in the coal. Comparing the reactivity of the soot to that of the unburned char, the former is always lower than the latter. Consequently, the lower is the soot formation, the better is the blast furnace stability

Study of cast and thermo-mechanically strengthened chromium-nickel nitrogen-containing steel

International Nuclear Information System (INIS)

Prokoshkina, V.G.; Kaputkina, L.M.; Svyazhin, A.G.

2000-01-01

The effect of nitrogen on the structure and strength of corrosion-resistant chromium-nickel steels after thermal and thermomechanical treatment is studied. The 06Kh15N7AD and 07Kh15N7DAMB steels alloying by nitrogen was accomplished through the basic composition steels remelting in the molecular nitrogen atmosphere under the pressure of 0.1-2.5 MPa. The 02Kh15N5DAF and 05Kh15N5DAM steels ingots were obtained through melting in a plasma furnace under the nitrogen pressure of 0.4MPA. The high-temperature thermomechanical treatment (HTMT) was performed by rolling with preliminary blanks heating up to 1050 deg C and the rolling end temperature not below 950 deg C. It is shown, that the HTMT of the nitrogen-containing steels makes it possible to obtain strength characteristics by 1.5 times exceeding the properties of traditionally applicable corrosion-resistant steels, whereby sufficiently high plasticity of the nitrogen-containing steel is retained [ru

Research, Development, and Field Testing of Thermochemical Recuperation for High Temperature Furnace

Energy Technology Data Exchange (ETDEWEB)

Kurek, Harry; Kozlov, Aleksandr

2014-03-31

Gas Technology Institute (GTI) evaluated the technical and economic feasibility of utilizing a non-catalytic ThermoChemical Recuperation System (TCRS) to recover a significant amount of energy from the waste gases of natural gas fired steel reheat furnaces. The project was related to DOE-AMO’s (formerly known as ITP) one of the technical areas of interest: Technologies to improve energy efficiency and reduce the carbon footprint of equipment currently used in energy-intensive industries such as iron and steel, and reduce by at least 30% energy consumption and carbon dioxide emission compared to the conventional technologies. ThermoChemical Recuperation (TCR) is a technique that recovers sensible heat in the exhaust gas from an industrial process, furnace, engine etc., when a hydrocarbon fuel is used for combustion. TCR enables waste heat recovery by both combustion air preheat and hydrocarbon fuel (natural gas, for example) reforming into a higher calorific fuel. The reforming process uses hot flue gas components (H2O and CO2) or steam to convert the fuel into a combustible mixture of hydrogen (H2), carbon monoxide (CO), and some unreformed hydrocarbons (CnHm). Reforming of natural gas with recycled exhaust gas or steam can significantly reduce fuel consumption, CO2 emissions and cost as well as increase process thermal efficiency. The calorific content of the fuel can be increased by up to ~28% with the TCR process if the original source fuel is natural gas. In addition, the fuel is preheated during the TCR process adding sensible heat to the fuel. The Research and Development work by GTI was proposed to be carried out in three Phases (Project Objectives). • Phase I: Develop a feasibility study consisting of a benefits-derived economic evaluation of a ThermoChemical Recuperation (TCR) concept with respect to high temperature reheat furnace applications within the steel industry (and cross-cutting industries). This will establish the design parameters and

Laser Welding of Coated Press-hardened Steel 22MnB5

Science.gov (United States)

Siltanen, Jukka; Minkkinen, Ari; Järn, Sanna

The press-hardening process is widely used for steels that are used in the automotive industry. Using ultra-high-strength steels enables car manufacturers to build lighter, stronger, and safer vehicles at a reduced cost and generating lower CO2 emissions. In the study, laser welding properties of the coated hot stamped steel 22BMn5 were studied. A constant 900 °C temperature was used to heat the steel plates, and two different furnace times were used in the press-hardening, being 300 and 740 seconds. Some of the plates were shot blasted to see the influence of the partly removed oxide layer on the laser welding and quality. The welding set-up, welding, and testing of the weld specimens complied with the automotive testing code SEP 1220.

Characterization of electric arc furnace dust aiming reuse

International Nuclear Information System (INIS)

Grillo, F.F.; Oliveira, E.B.G.; Oliveira, J.R. de; Telles, V.B.; Tenorio, J.A.S.

2010-01-01

This work aims to study the characterize of steelmaking dust, from the primary refining of steel in Electric Arc Furnace, in order to verify feasibility of reuse through the addition of hot metal in the form of briquette. The techniques used to characterize the dust was chemical analyses, size separation tests, X-ray diffraction analyses (XRD), Scanning Electron Microscopy (SEM). After characterization, was the calculation of reductant considering the complete reduction of iron oxides and then to briquetting. The waste sample is composed essentially of spherical particles and has a very small particle size (85% below 10 μm). The XRD has presented compounds such as ZnFe 2 O 4 , Fe 3 O 4 , ZnO e SiO 2 . This work showed that its possible recovery approximately 92% of metal iron from dust generated during steelmaking.This (author)

Effect of recycling blast furnace flue dust as pellets on the sintering performance

Directory of Open Access Journals (Sweden)

El-Hussiny N.A.

2010-01-01

Full Text Available The Egyptian Iron and Steel Company generates a great amount of blast furnace flue dust. The recovery of metals and carbon from this flue dust becomes a very important demand due to the increase of the price of coke breeze and the decrease of the primary source of metals. At the same time, it make the environment more safe by decreasing pollution. Introducing these dust fines in the sintering process proves to be very harmful for different operating parameters. Thus, this study aims at investigating the production of pellets resulting from these fines, using molasses as organic binder and its application in sintering of iron ore. The sintering experiments were performed using flue dust as pellets as a substitute of coke breeze. The results revealed that, sintering properties such as inter strength increases with using the flue dust pellets, while productivity of both the sinter machine and sinter machine at blast furnace yard decreases. Also the vertical velocity of the sinter machine and the weight loss during the reduction of produced the sinter by hydrogen decrease.

A computational study of the supersonic coherent jet

International Nuclear Information System (INIS)

Jeong, Mi Seon; Kim, Heuy Dong

2003-01-01

In steel-making process of iron and steel industry, the purity and quality of steel can be dependent on the amount of CO contained in the molten metal. Recently, the supersonic oxygen jet is being applied to the molten metal in the electric furnace and thus reduces the CO amount through the chemical reactions between the oxygen jet and molten metal, leading to a better quality of steel. In this application, the supersonic oxygen jet is limited in the distance over which the supersonic velocity is maintained. In order to get longer supersonic jet propagation into the molten metal, a supersonic coherent jet is suggested as one of the alternatives which are applicable to the electric furnace system. It has a flame around the conventional supersonic jet and thus the entrainment effect of the surrounding gas into the supersonic jet is reduced, leading to a longer propagation of the supersonic jet. In this regard, gasdynamics mechanism about why the combustion phenomenon surrounding the supersonic jet causes the jet core length to be longer is not yet clarified. The present study investigates the major characteristics of the supersonic coherent jet, compared with the conventional supersonic jet. A computational study is carried out to solve the compressible, axisymmetric Navier-Stokes equations. The computational results of the supersonic coherent jet are compared with the conventional supersonic jets

Assessing dust exposure in an integrated iron and steel manufacturing plant in South India.

Science.gov (United States)

Ravichandran, B; Krishnamurthy, V; Ravibabu, K; Raghavan, S; Rajan, B K; Rajmohan, H R

2008-01-01

A study to monitor and estimate respirable particulate matter (RPM), toxic trace metal concentrations in the work environment was carried out in different sections of an integrated steel manufacturing industry. The average RPM concentration observed varied according to the section blast furnace was 2.41 mg/m;{3}; energy optimization furnace, 1.87 mg/m;{3}; sintering plant, 0.98 mg/m;{3}; continuous casting machine, 1.93 mg/m;{3}. The average trace metal concentration estimated from the RPM samples like iron, manganese, lead and chromium did not exceed ACGIH prescribed levels.

Large-Scale Consumption and Zero-Waste Recycling Method of Red Mud in Steel Making Process

Directory of Open Access Journals (Sweden)

Guoshan Ning

2018-03-01

Full Text Available To release the environmental pressure from the massive discharge of bauxite residue (red mud, a novel recycling method of red mud in steel making process was investigated through high-temperature experiments and thermodynamic analysis. The results showed that after the reduction roasting of the carbon-bearing red mud pellets at 1100–1200 °C for 12–20 min, the metallic pellets were obtained with the metallization ratio of ≥88%. Then, the separation of slag and iron achieved from the metallic pellets at 1550 °C, after composition adjustment targeting the primary crystal region of the 12CaO·7Al2O3 phase. After iron removal and composition adjustment, the smelting-separation slag had good smelting performance and desulfurization capability, which meets the demand of sulfurization flux in steel making process. The pig iron quality meets the requirements of the high-quality raw material for steel making. In virtue of the huge scale and output of steel industry, the large-scale consumption and zero-waste recycling method of red mud was proposed, which comprised of the carbon-bearing red mud pellets roasting in the rotary hearth furnace and smelting separation in the electric arc furnace after composition adjustment.

Research regarding the vacuuming of liquid steel on steel degassing

Science.gov (United States)

Magaon, M.; Radu, M.; Şerban, S.; Zgripcea, L.

2018-01-01

When the liquid steel comes in contact with the atmosphere of the elaboration aggregates, a process of gas diffusion into the metal bath takes place on the one hand, and on the other hand a process that allows them to pass from the metal bath into the atmosphere. The meaning of these processes is determined by a number of factors as follows: the quality of raw and auxiliary materials (moisture content, oils, etc.), the boiling intensity, the evacuation duration, the properties of used slags, the values of the casting ladle processing parameters (bubbling, vacuuming, etc.). The research was carried out at an electrical steelwork, equipped with an electric arc furnace type EBT (Electric Bottom Tapping) capacity 100t, LF (Ladle-Furnace) and VD (Vacuum Degassing) facilities, establishing some correlations between the vacuuming parameters from the V.D.facility and the amounts of hydrogen and nitrogen removed from the metal bath, as well as their removal efficiency, were taken into consideration. The obtained data was processed in MATLAB calculation program, the established correlations form was presented both in analytical and graphical form. The validity of these correlations was verified in practice, being particularly useful in research.

The use of oxygen in hazardous waste incineration

International Nuclear Information System (INIS)

Ho, M.D.; Ding, M.G.

1989-01-01

The use of advanced oxygen combustion technologies in hazardous waste (such as PCBs and hydrocarbons) incineration has emerged in the last two years as one of the most significant breakthroughs among all the competing treatment technologies. For many years, industrial furnaces have used oxygen enrichment of the combustion air and oxygen-fuel burners, but with conventional technologies a high oxygen level generally poses problems. The flame temperature is high, leading to high NOx formation and local overeating. Different technical approaches to overcome these problems and their respective effectiveness will be reviewed. Previously, commercial oxygen enrichment in incinerators was limited to a rather modest level applications of much higher oxygen enrichment levels in hazardous waste incinerators

Novel Membranes and Processes for Oxygen Enrichment

Energy Technology Data Exchange (ETDEWEB)

Lin, Haiqing

2011-11-15

The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions

Refractory of Furnaces to Reduce Environmental Impact

International Nuclear Information System (INIS)

Hanzawa, Shigeru

2011-01-01

The energy load of furnaces used in the manufacturing process of ceramics is quite large. Most of the environmental impact of ceramics manufacturing is due to the CO 2 produced from this high energy load. To improve this situation, R and D has focused on furnace systems and techniques of control in order to reduce energy load. Since furnaces are comprised of refractory, consideration of their mechanical and thermal characteristics is important. Herein are described several refractory types which were chosen through comparison of the characteristics which contribute to heat capacity reduction, heat insulating reinforcement and high emissivity, thereby improving thermal radiation heat transfer efficiency to the ceramic articles. One selected refractory material which will reduce the environmental impact of a furnace, chosen considering low heat capacity and high emissivity characteristics, is SiC. In this study, thermal radiation heat transfer efficiency improvement and its effect on ceramic articles in the furnace and oxidation behaviour were investigated at 1700K. A high density SiC refractory, built into the furnace at construction, has relatively high oxidation durability and has the ability to reduce environmental impact-CO 2 by 10 percent by decreasing the furnace's energy load. However, new oxidation prevention techniques for SiC will be necessary for long-term use in industrial furnaces, because passive to active oxidation transition behaviour of commercial SiC refractory is coming to close ideal.

Refractory of Furnaces to Reduce Environmental Impact

Science.gov (United States)

Hanzawa, Shigeru

2011-10-01

The energy load of furnaces used in the manufacturing process of ceramics is quite large. Most of the environmental impact of ceramics manufacturing is due to the CO2 produced from this high energy load. To improve this situation, R&D has focused on furnace systems and techniques of control in order to reduce energy load. Since furnaces are comprised of refractory, consideration of their mechanical and thermal characteristics is important. Herein are described several refractory types which were chosen through comparison of the characteristics which contribute to heat capacity reduction, heat insulating reinforcement and high emissivity, thereby improving thermal radiation heat transfer efficiency to the ceramic articles. One selected refractory material which will reduce the environmental impact of a furnace, chosen considering low heat capacity and high emissivity characteristics, is SiC. In this study, thermal radiation heat transfer efficiency improvement and its effect on ceramic articles in the furnace and oxidation behaviour were investigated at 1700K. A high density SiC refractory, built into the furnace at construction, has relatively high oxidation durability and has the ability to reduce environmental impact-CO2 by 10 percent by decreasing the furnace's energy load. However, new oxidation prevention techniques for SiC will be necessary for long-term use in industrial furnaces, because passive to active oxidation transition behaviour of commercial SiC refractory is coming to close ideal.

Model based energy benchmarking for glass furnace

International Nuclear Information System (INIS)

Sardeshpande, Vishal; Gaitonde, U.N.; Banerjee, Rangan

2007-01-01

Energy benchmarking of processes is important for setting energy efficiency targets and planning energy management strategies. Most approaches used for energy benchmarking are based on statistical methods by comparing with a sample of existing plants. This paper presents a model based approach for benchmarking of energy intensive industrial processes and illustrates this approach for industrial glass furnaces. A simulation model for a glass furnace is developed using mass and energy balances, and heat loss equations for the different zones and empirical equations based on operating practices. The model is checked with field data from end fired industrial glass furnaces in India. The simulation model enables calculation of the energy performance of a given furnace design. The model results show the potential for improvement and the impact of different operating and design preferences on specific energy consumption. A case study for a 100 TPD end fired furnace is presented. An achievable minimum energy consumption of about 3830 kJ/kg is estimated for this furnace. The useful heat carried by glass is about 53% of the heat supplied by the fuel. Actual furnaces operating at these production scales have a potential for reduction in energy consumption of about 20-25%

Effect of incorporation of fly ash and granulated blast furnace in the electrochemical behavior of concretes of commercial cement

International Nuclear Information System (INIS)

Gutierrez-Junco, O. J.; Pineda-Triana, Y.; Vera-Lopez, E.

2015-01-01

This paper presents the findings of the research properties evaluation pastes of commercial cement (CPC), mixed with fly ash (FA) and granulated blast furnace slag (GBFS). Initially, the sample of 30 combinations were evaluated in terms of compressive strength to establish the optimal proportions from raw material. After that, four optimized blends were characterized during the setting and hardening process. Electrochemical tests were performed on concrete cylinders samples prepared with cementitious materials and a structural steel rod placed in the center of the specimen. With the objective to evaluate the performance before corrosion, thermodynamic and kinetic aspects were taken into consideration. The findings showed that commercial cements blended with fly ash and blast furnace slag as the ones used in this research presents a decreased behavior in mechanical and corrosion strength regarding to CPC. (Author)

Solar Convective Furnace for Metals Processing

Science.gov (United States)

Patidar, Deepesh; Tiwari, Sheetanshu; Sharma, Piyush; Pardeshi, Ravindra; Chandra, Laltu; Shekhar, Rajiv

2015-11-01

Metals processing operations, primarily soaking, heat treatment, and melting of metals are energy-intensive processes using fossil fuels, either directly or indirectly as electricity, to operate furnaces at high temperatures. Use of concentrated solar energy as a source of heat could be a viable "green" option for industrial heat treatment furnaces. This paper introduces the concept of a solar convective furnace which utilizes hot air generated by an open volumetric air receiver (OVAR)-based solar tower technology. The potential for heating air above 1000°C exists. Air temperatures of 700°C have already been achieved in a 1.5-MWe volumetric air receiver demonstration plant. Efforts to retrofit an industrial aluminium soaking furnace for integration with a solar tower system are briefly described. The design and performance of an OVAR has been discussed. A strategy for designing a 1/15th-scale model of an industrial aluminium soaking furnace has been presented. Preliminary flow and thermal simulation results suggest the presence of recirculating flow in existing furnaces that could possibly result in non-uniform heating of the slabs. The multifarious uses of concentrated solar energy, for example in smelting, metals processing, and even fuel production, should enable it to overcome its cost disadvantage with respect to solar photovoltaics.

Energy Saving in Industrial Annealing Furnaces

Directory of Open Access Journals (Sweden)

Fatma ÇANKA KILIÇ

2018-03-01

Full Text Available In this study, an energy efficiency studies have been carried out in a natural gas-fired rolling mill annealing furnace of an industrial establishment. In this context, exhaust gas from the furnace has been examined in terms of waste heat potential. In the examinations that have been made in detail; waste heat potential was found as 3.630,31 kW. Technical and feasibility studies have been carried out to realize electricity production through an Organic Rankine Cycle (ORC system for evaluating the waste heat potential of the annealing furnace. It has been calculated that 1.626.378,88 kWh/year of electricity can be generated by using the exhaust gas waste heat of the annealing furnace through an ORC system to produce electric energy with a net efficiency of 16%. The financial value of this energy was determined as 436.032,18 TL/year and the simple repayment period of the investment was 8,12 years. Since the annealing period of the annealing furnace is 2800 hours/year, the investment has not been found to be feasible in terms of the feasibility studies. However, the investment suitability can be assured when the annealing furnace is operating at full capacity for 8,000 hours or more annually.

Development of technology and properties investigation of steel/bronze joints proposed for ITER HHF components manufacturing

International Nuclear Information System (INIS)

Kalinin, G.; Krestnikov, N.S.; Strebkov, Y.S.; Abramov, V.Y.; Gervash, A.; Mazul, I.; Zolotarev, V.B.; Fabritsiev, S.A.

2007-01-01

Full text of publication follows: During the development of ITER HHF components manufacturing it is necessary to provide reliable joints between heat sink material made of CuCrZr bronze and the supporting construction made of austenitic steel. Four different methods have been tried out: - Hot Isostatic Pressing (HIP), - HIP assisted brazing, - furnace assisted brazing, - Casting. The investigation of structure and properties of joints show that HIP and casting provide the better results than the other technologies. However, HIP is relatively expensive technology, and big size HIP furnace is required for the full scale components manufacturing that are not available n RF now. Therefore, casting was selected as a reference manufacturing technology for the primary wall of ITER modules n RF. The paper summarizes the results of bronze/steel joints manufacturing and investigation of their properties. (authors)

A study on direct alloying with molybdenum oxides by feed wire method

Directory of Open Access Journals (Sweden)

Jingjing Zou

2018-04-01

Full Text Available Direct alloying with molybdenum oxides has been regarded in years; the main addition methods are adding to the bottom of electric arc furnace (EAF with scrap, adding to the ladle during the converter tapping and mixing molybdenum oxide, lime and reductant to prepare pellet added to basic oxygen furnace (BOF. In this paper, a new method for direct alloying with molybdenum trioxide is proposed, adding molybdenum trioxide molten steel by feeding wire method in ladle furnace (LF refining process. The feasibility of molybdenum oxide reduction, the influence rules of bottom-blown on liquid steel fluidity and the yield of molybdenum by feeding wire method were analyzed. Results show that molybdenum oxide can be reduced by [Al], [Si], [C], and even [Fe] in molten steel. Bottom blowing position has a significant influence on the flow of molten steel when the permeable brick is located in 1/2 radius. The yields of Mo are higher than 97% for the experiments with feed wire method, the implementation of direct alloying with molybdenum trioxide by feed wire method works even better than that uses of ferromolybdenum in the traditional process.

Design and Development of Tilting Rotary Furnace

Science.gov (United States)

Sai Varun, V.; Tejesh, P.; Prashanth, B. N.

2018-02-01

Casting is the best and effective technique used for manufacturing products. The important accessory for casting is furnace. Furnace is used to melt the metal. A perfect furnace is one that reduces the wastage of material, reduces the cost of manufacturing and there by reduces the cost of production. Of all the present day furnaces there may be wastage of material, and the chances of increasing the time of manufacturing as the is continuous need of tilting of the furnace for every mould and then changing the moulds. Considering these aspects, a simple and least expensive tilting rotary furnace is designed and developed. The Tilting and Rotary Furnace consists of mainly melting chamber and the base. The metal enters the melting chamber through the input door that is provided on the top of the melting chamber. Inside the melting chamber there is a graphite furnace. The metal is melted in the graphite crucible. An insulation of ceramic fibre cloth is provided inside the furnace. The metal is melted using Propane gas. The propane gas is easily available and economic. The gas is burned using a pilot burner. The pilot burner is more efficient that other burners. The pilot burner is lit with a push button igniter. The pilot burner is located at the bottom of the combustion chamber. This enables the uniform heating of the metal inside the crucible. The temperature inside the melting chamber is noted using a temperature sensor. The gas input is cut-off if the temperature is exceeding a specific temperature. After the melting of the metal is done the furnace is tilted and after the mould is filled it is rotated. The external gears are used to controlling the tilting. The results of studies carried out for the design & development of low cost, simple furnace that can be mounted anywhere on the shop floor and this can be very much useful for the education purposes and small scale manufacturing. The furnace can be rotated in 360 degrees and can help in reducing the time taken

The behaviour of concrete under attack of liquid steel

International Nuclear Information System (INIS)

Schneider, U.; Ehm, C.; Diederichs, U.

1983-01-01

Investigations were carried out to study the interaction between concrete and liquid steel. Different types and different forms of concrete were investigated at temperatures of liquid steel between 1.600 and 2.600 0 C. The liquid steel of 1.600 0 C was produced in an induction furnace, the liquid steel of 2.600 0 C was produced in concrete crucibles by metallothermic reactions. The reactions occuring during the interaction of concrete and liquid steel may be summarized as follows: - Concrete reacts violently upon sudden loading with high temperatures and high heat fluxes. Great quantities of steam and gases are generated. The mechanical strength decreases rapidly with increasing temperature. -At about 1.200 0 C concrete begins to melt. First the cement matrix melts, than the aggregates melt. The melts of different concretes consist of different constituents and their reactions with liquid steel vary. The temperature of the liquid steel significantly influences the intensity of the reactions and the erosion rates. - The erosion rates amounted to 30 mm/min, when liquid steel was produced in concrete crucibles. When cylindrical concrete specimens were immersed in molten steel the rate of melting off amounted up to 66 mm/min. - The dissipation of heat during the interaction brings about that the reactions between concrete and liquid steel vanish gradually, if no additional energy is fed into the system. (orig.)

Combustion and emission formation in a biomass fueled grate furnace - measurements and modelling

International Nuclear Information System (INIS)

Lindsjoe, H.

1997-06-01

A study of turbulent combustion with special emphasis on the formation of nitrous oxide emissions in a biomass fueled grate furnace has been conducted with the aid of measurements, literature studies and CFD-computations. The literature study covers nitrous oxide formation and the pyrolysis, gasification and combustion of biomass fuel. The measurements were conducted inside the furnace and at the outlet, and temperature and some major species were measured. A tool for the treatment of the bed processes (pyrolysis, gasification and combustion) has been developed. The measurements show significantly higher concentrations of oxygen above the fuel bed than expected. The gas production in the bed was shown to be very unevenly distributed over the width of the furnace. The measured temperatures were relatively low and in the same order as reported from other, similar measurements. The computational results are in good quantitative agreement with the measurements, even for the nitrous oxide emissions. It was necessary to include tar as one of the combustible species to achieve reasonable results. The computations point out that the fuel-NO mechanism is the most important reaction path for the formation of nitrous oxide in biomass combustion in grate furnaces. The thermal NO mechanism is responsible for less than 10% of the total amount of NO-emissions. Although the results are quantitatively in good agreement with the measurements, a sensitivity study showed that the fuel-NO model did not respond to changes in the distribution of secondary air as the measurements indicate. The results from this work have lead to some guidelines on how the furnace should be operated to achieve minimum NO-emissions. Some proposals of smaller changes in the construction are also given. 33 refs, 37 figs, 7 tabs

Comparison of stainless and mild steel welding fumes in generation of reactive oxygen species

Directory of Open Access Journals (Sweden)

Frazer David

2010-11-01

Full Text Available Abstract Background Welding fumes consist of a wide range of complex metal oxide particles which can be deposited in all regions of the respiratory tract. The welding aerosol is not homogeneous and is generated mostly from the electrode/wire. Over 390,000 welders were reported in the U.S. in 2008 while over 1 million full-time welders were working worldwide. Many health effects are presently under investigation from exposure to welding fumes. Welding fume pulmonary effects have been associated with bronchitis, metal fume fever, cancer and functional changes in the lung. Our investigation focused on the generation of free radicals and reactive oxygen species from stainless and mild steel welding fumes generated by a gas metal arc robotic welder. An inhalation exposure chamber located at NIOSH was used to collect the welding fume particles. Results Our results show that hydroxyl radicals (.OH were generated from reactions with H2O2 and after exposure to cells. Catalase reduced the generation of .OH from exposed cells indicating the involvement of H2O2. The welding fume suspension also showed the ability to cause lipid peroxidation, effect O2 consumption, induce H2O2 generation in cells, and cause DNA damage. Conclusion Increase in oxidative damage observed in the cellular exposures correlated well with .OH generation in size and type of welding fumes, indicating the influence of metal type and transition state on radical production as well as associated damage. Our results demonstrate that both types of welding fumes are able to generate ROS and ROS-related damage over a range of particle sizes; however, the stainless steel fumes consistently showed a significantly higher reactivity and radical generation capacity. The chemical composition of the steel had a significant impact on the ROS generation capacity with the stainless steel containing Cr and Ni causing more damage than the mild steel. Our results suggest that welding fumes may cause acute

Control of the Gas Flow in an Industrial Directional Solidification Furnace for Production of High Purity Multicrystalline Silicon Ingots

Directory of Open Access Journals (Sweden)

Lijun Liu

2015-01-01

Full Text Available A crucible cover was designed as gas guidance to control the gas flow in an industrial directional solidification furnace for producing high purity multicrystalline silicon. Three cover designs were compared to investigate their effect on impurity transport in the furnace and contamination of the silicon melt. Global simulations of coupled oxygen (O and carbon (C transport were carried out to predict the SiO and CO gases in the furnace as well as the O and C distributions in the silicon melt. Cases with and without chemical reaction on the cover surfaces were investigated. It was found that the cover design has little effect on the O concentration in the silicon melt; however, it significantly influences CO gas transport in the furnace chamber and C contamination in the melt. For covers made of metal or with a coating on their surfaces, an optimal cover design can produce a silicon melt free of C contamination. Even for a graphite cover without a coating, the carbon concentration in the silicon melt can be reduced by one order of magnitude. The simulation results demonstrate a method to control the contamination of C impurities in an industrial directional solidification furnace by crucible cover design.

Sealed rotary hearth furnace with central bearing support

Science.gov (United States)

Docherty, James P.; Johnson, Beverly E.; Beri, Joseph

1989-01-01

The furnace has a hearth which rotates inside a stationary closed chamber and is supported therein on vertical cylindrical conduit which extends through the furnace floor and is supported by a single center bearing. The charge is deposited through the furnace roof on the rim of the hearth as it rotates and is moved toward the center of the hearth by rabbles. Externally generated hot gases are introduced into the furnace chamber below the hearth and rise through perforations in the hearth and up through the charge. Exhaust gases are withdrawn through the furnace roof. Treated charge drops from a center outlet on the hearth into the vertical cylindrical conduit which extends downwardly through the furnace floor to which it is also sealed.

Utilizing of the metallurgical slag for production of cementless concrete mixtures

Directory of Open Access Journals (Sweden)

D. Baricová

2012-10-01

Full Text Available In process of pig iron, steel and cast iron production besides main product, also secondary products are formed, that have character of secondary raw materials and industrial wastes. The most abundant secondary product originating in the metallurgical process is furnace slag. Total amount of accured slag, also its chemical, mineralogical, physical – chemical properties and similarity with natural stones predestinate its utilisation in different fields of industry. The contribution deals with production of cementless concrete mixtures, where the main parts were formed by blast furnace granulated slag grinded and different gravel slag from blast furnace, oxygen converter and electric arc furnace. As activators of solidification different kinds of water glass were tested.

Current status of iron and steelmaking technology at Tata Steel

Energy Technology Data Exchange (ETDEWEB)

Pandey, B.D.; Poddar, M.N.; Chandra, S. [Tata Steel, Jamshedpur (India)

2002-07-01

Tata Steel was set up in the early years of the 20th century and over the years the plant has grown into one of the most modern steel plants in the world. The philosophy of phase-wise modernisation on a continuing basis was adopted by Tata Steel with great advantage for the modernisation of the two million tonne Jamshedpur Steel Works. Four phases of the modernisation programme have already been successfully completed and their gains consolidated. Adoption and absorption of the latest technologies, fundamental changes in the operating philosophy and setting of stretch performance targets have brought about this remarkable transformation. The recently commissioned state of the art 1.2 Mtpa Cold Rolling Mill Complex is an example of Tata Steel remaining in harmony with times. Another is the use of pulverised coal injection in blast furnaces. The paper highlights some of the important technological developments in integrated steel plants, particularly those being practiced at Tata Steel, in the areas of ironmaking, steelmaking, casting and rolling for retaining its competitive position in the global market with regard to cost, customer and change. 9 refs., 21 figs., 2 tabs.

Treatment of petroleum-hydrocarbon contaminated soils using hydrogen peroxide oxidation catalyzed by waste basic oxygen furnace slag

International Nuclear Information System (INIS)

Tsai, T.T.; Kao, C.M.

2009-01-01

The contamination of subsurface soils with petroleum hydrocarbons is a widespread environmental problem. The objective of this study was to evaluate the potential of applying waste basic oxygen furnace slag (BOF slag) as the catalyst to enhance the Fenton-like oxidation to remediate fuel oil or diesel contaminated soils. The studied controlling factors that affect the removal efficiency of petroleum hydrocarbons included concentrations of H 2 O 2 , BOF slag dosages, types of petroleum hydrocarbons (e.g., fuel oil and diesel), and types of iron mineral. Experimental results indicate that oxidation of petroleum hydrocarbon via the Fenton-like process can be enhanced with the addition of BOF slag. Results from the X-ray powder diffraction analysis reveal that the major iron type of BOF slag/sandy loam system was iron mineral (e.g., α-Fe 2 O 3 and α-FeOOH). Approximately 76% and 96% of fuel oil and diesel removal were observed (initial total petroleum hydrocarbon (TPH) concentration = 10,000 mg kg -1 ), respectively, with the addition of 15% of H 2 O 2 and 100 g kg -1 of BOF slag after 40 h of reaction. Because BOF slag contains extractable irons such as amorphous iron and soluble iron, it can act as an iron sink to supply iron continuously for Fenton-like oxidation. Results demonstrate that Fenton-like oxidation catalyzed by BOF slag is a potential method to be able to remediate petroleum-hydrocarbon contaminated soils efficiently and effectively.

Emission spectroscopy for coal-fired cyclone furnace diagnostics

Energy Technology Data Exchange (ETDEWEB)

Wehrmeyer, J.A.; Boll, D.E.; Smith, R. [Vanderbilt University, Nashville, TN (United States). Dept. of Mechanical Engineering

2003-08-01

Using a spectrograph and charge-coupled device (CCD) camera, ultraviolet and visible light emission spectra were obtained from a coal-burning electric utility's cyclone furnaces operating at either fuel-rich or fuel-lean conditions. The aim of this effort is to identify light emission signals that can be related to a cyclone furnace's operating condition in order to adjust its air/fuel ratio to minimize pollutant production. Emission spectra at the burner and outlet ends of cyclone furnaces were obtained. Spectra from all cyclone burners show emission lines for the trace elements Li, Na, K, and Rb, as well as the molecular species OH and CaOH. The Ca emission line is detected at the burner end of both the fuel-rich and fuellean cyclone furnaces but is not detected at the outlet ends of either furnace type. Along with the disappearance of Ca is a concomitant increase in the CaOH signal at the outlet end of both types of furnaces. The OH signal strength is in general stronger when viewing at the burner end rather than the exhaust end of both the fuel-rich and fuel-lean cyclone furnaces, probably due to high, non-equilibrium amounts of OH present inside the furnace. Only one molecular species was detected that could be used as a measure of air/fuel ratio: MgOH. It was detected at the burner end of fuel-rich cyclone furnaces but not detected in fuel-lean cyclone furnaces. More direct markers of air/fuel ratio, such as CO and 02 emission, were not detected, probably due to the generally weak nature of molecular emission relative to ambient blackbody emission present in the cyclone furnaces, even at ultraviolet wavelengths.

AUTOMATION OF GLASS TEMPERING FURNACE BY USING PLC

Directory of Open Access Journals (Sweden)

Abdullah BÜYÜKYILDIZ

2007-02-01

Full Text Available In this study, a furnace which is used for observation of environments under high temperature, and also used for manufacturing of glasses which are resisted to high temperature has been designed and implemented. Automation of this system has been done by using PLC. Operating parameters of furnace such as materials entering, the furnace, the local temperature control of furnace, cooling control and materials outing have been sensed with Hall Effect Sensor. Furthermore, the observation of parameters of furnace on screen has been provided with SCADA software. Obtained products have been shown the system works successfully.

3D Numerical Analysis of the Arc Plasma Behavior in a Submerged DC Electric Arc Furnace for the Production of Fused MgO

International Nuclear Information System (INIS)

Wang Zhen; Wang Ninghui; Li Tie; Cao Yong

2012-01-01

A three dimensional steady-state magnetohydrodynamic model is developed for the arc plasma in a DC submerged electric arc furnace for the production of fused MgO. The arc is generated in a small semi-enclosed space formed by the graphite electrode, the molten bath and unmelted raw materials. The model is first used to solve a similar problem in a steel making furnace, and the calculated results are found to be in good agreement with the published measurements. The behavior of arcs with different arc lengths is also studied in the furnace for MgO production. From the distribution of the arc pressure on the bath surface it is shown that the arc plasma impingement is large enough to cause a crater-like depression on the surface of the MgO bath. The circulation of the high temperature air under the electrode may enhance the arc efficiency, especially for a shorter arc.

A cylindrical furnace for absorption spectral studies

Indian Academy of Sciences (India)

A cylindrical furnace with three heating zones, capable of providing a temperature of 1100°C, has been fabricated to enable recording of absorption spectra of high temperature species. The temperature of the furnace can be controlled to ± 1°C of the set temperature. The salient feature of this furnace is that the material ...

Risk management of energy efficiency projects in the industry - sample plant for injecting pulverized coal into the blast furnaces

OpenAIRE

Jovanović Filip P.; Berić Ivana M.; Jovanović Petar M.; Jovanović Aca D.

2016-01-01

This paper analyses the applicability of well-known risk management methodologies in energy efficiency projects in the industry. The possibilities of application of the selected risk management methodology are demonstrated within the project of the plants for injecting pulverized coal into blast furnaces nos. 1 and 2, implemented by the company US STEEL SERBIA d.o.o. in Smederevo. The aim of the project was to increase energy efficiency through the reductio...

Radiative heat transfer in coal-fired furnaces and oxycoal retrofit considerations

Energy Technology Data Exchange (ETDEWEB)

Erfurth, Jens

2012-07-01

Oxycoal combustion is the combustion of coal using a mixture of oxygen and cooled recycled flue gas in place of air. In the last years it has gained interest as a means of CO{sub 2} capture from stationary point sources. In particular, under emission mitigation regimes the retrofit of existing coal-fired power plants may help avoid ''stranded assets'' through lower emissions and thus costs if certain technical criteria can be met. Among these is the need to keep total heat transfer in the boiler constant while not raising the furnace exit temperature. The altered gas composition in oxycoal combustion leads to changes in both convective and radiative heat transfer, of which the latter, while of overwhelming importance in the furnace, poses a particular challenge to modellers. This work is thus primarily concerned with the simulation of radiative heat transfer. After a short introduction to oxycoal combustion, a general discussion of Computational Fluid Dynamics (CFD) models for coal combustion is given. Emphasis is placed on the physics of molecular gas band radiation, respective modelling approaches and their application within a CFD context. Based on this analysis, it is concluded that for the purposes of this work, a non-grey CFD implementation of the Exponential Wide Band Model is most suitable. Then the results of CFD simulations of the furnace of a state-of-the-art coal-fired USC boiler with a thermal power of 1,210 MW are presented, which were carried out using the commercial software FLUENT {sup registered} 6.3, combined with some User-Defined Functions. In addition to air combustion, the cases studied include variations of the burner oxygen concentration and the mode of flue gas recycling (wet and dry), the two additional parameters that present themselves in oxycoal combustion to meet the retrofit criteria. The same burner geometry optimised for oxycoal combustion was used in all cases, while the overall boiler geometry designed for air

Modeling and Simulation of Claus Unit Reaction Furnace

Directory of Open Access Journals (Sweden)

Maryam Pahlavan

2016-01-01

Full Text Available Reaction furnace is the most important part of the Claus sulfur recovery unit and its performance has a significant impact on the process efficiency. Too many reactions happen in the furnace and their kinetics and mechanisms are not completely understood; therefore, modeling reaction furnace is difficult and several works have been carried out on in this regard so far. Equilibrium models are commonly used to simulate the furnace, but the related literature states that the outlet of furnace is not in equilibrium and the furnace reactions are controlled by kinetic laws; therefore, in this study, the reaction furnace is simulated by a kinetic model. The predicted outlet temperature and concentrations by this model are compared with experimental data published in the literature and the data obtained by PROMAX V2.0 simulator. The results show that the accuracy of the proposed kinetic model and PROMAX simulator is almost similar, but the kinetic model used in this paper has two importance abilities. Firstly, it is a distributed model and can be used to obtain the temperature and concentration profiles along the furnace. Secondly, it is a dynamic model and can be used for analyzing the transient behavior and designing the control system.

Steels for nuclear power. I

International Nuclear Information System (INIS)

Bohusova, O.; Brumovsky, M.; Cukr, B.; Hatle, Z.; Protiva, K.; Stefec, R.; Urban, A.; Zidek, M.

1976-01-01

The principles are listed of nuclear reactor operation and the reactors are classified by neutron energy, fuel and moderator designs, purpose and type of moderator. The trend and the development of light-water reactor applications are described. The fundamental operating parameters of the WWER type reactors are indicated. The effect is discussed of neutron radiation on reactor structural materials. The characteristics are described of steel corrosion due to the contact of the steel with steam or sodium in the primary coolant circuit. The reasons for stress corrosion are given and the effects of radiation on corrosion are listed. The requirements and criteria are given for the choice of low-alloy steel for the manufacture of pressure vessels, volume compensators, steam generators, cooling conduits and containment. A survey is given of most frequently used steels for pressure vessels and of the mechanical and structural properties thereof. The basic requirements for the properties of steel used in the primary coolant circuit are as follows: sufficient strength in operating temperature, toughness, good weldability, resistance to corrosion and low brittleness following neutron irradiation. The materials are listed used for the components of light-water and breeder reactors. The production of corrosion-resistant steels is discussed with a view to raw materials, technology, steel-making processes, melting processes, induction furnace steel-making, and to selected special problems of the chemical composition of steels. The effects are mainly discussed of lead, bismuth and tin as well as of some other elements on hot working of high-alloy steels and on their structure. The problems of corrosion-resistant steel welding and of pressure vessel cladding are summed up. Also discussed is the question of the concept and safeguards of the safety of nuclear installation operation and a list is presented of most commonly used nondestructive materials testing methods. The current

40 CFR 60.145a - Compliance provisions.

Science.gov (United States)

2010-07-01

... station is an affected facility, the steel production cycle also includes the hot metal transfer or... Basic Oxygen Process Steelmaking Facilities for Which Construction is Commenced After January 20, 1983... shut down one furnace, he shall be allowed a reasonable time period to adjust his production schedule...

A Goal Programming Optimization Model for The Allocation of Liquid Steel Production

Science.gov (United States)

Hapsari, S. N.; Rosyidi, C. N.

2018-03-01

This research was conducted in one of the largest steel companies in Indonesia which has several production units and produces a wide range of steel products. One of the important products in the company is billet steel. The company has four Electric Arc Furnace (EAF) which produces liquid steel which must be procesed further to be billet steel. The billet steel plant needs to make their production process more efficient to increase the productvity. The management has four goals to be achieved and hence the optimal allocation of the liquid steel production is needed to achieve those goals. In this paper, a goal programming optimization model is developed to determine optimal allocation of liquid steel production in each EAF, to satisfy demand in 3 periods and the company goals, namely maximizing the volume of production, minimizing the cost of raw materials, minimizing maintenance costs, maximizing sales revenues, and maximizing production capacity. From the results of optimization, only maximizing production capacity goal can not achieve the target. However, the model developed in this papare can optimally allocate liquid steel so the allocation of production does not exceed the maximum capacity of the machine work hours and maximum production capacity.

Cyclic oxidation of stainless steel ferritic AISI 409, AISI 439 and AISI 441

International Nuclear Information System (INIS)

Salgado, Maria de Fatima; Santos, Diego Machado dos; Oliveira, Givanilson Brito de; Lins, Vanessa de Freitas Cunha

2014-01-01

Stainless steels have many industrial applications. The cyclic oxidation of ferritic stainless steels technical and scientific importance presents, because they are less susceptible to peeling the austenitic alloys. For the purpose of investigating the behavior of these steels under thermal cycling, cyclic oxidation of AISI 409, AISI 441 and AISI 439 was carried out in a tubular furnace under two different conditions: oxidation by dipping the steel in the synthetic condensate for 10h and without oxidation immersion in the condensate, for up to 1500h at 300° C temperature. Using techniques: SEM, EDS and XRD revealed a microstructure with increased oxidation in the samples were immersed in the condensate. The oxide film remained intact during oxidation for steels 439 and 441 409 The Steel immersed in the condensate was rupture of the film after the 20th cycle of oxidation. The chemical characterization of the films allowed the identification of elements: Chromium, Iron, Aluminium and Silicon To a great extent, Cr_2O_3. (author)

Design of a rotating-hearth furnace

Energy Technology Data Exchange (ETDEWEB)

Behrens, H A [Verein Deutscher Eisenhuettenleute (VDEh), Duesseldorf (Germany, F.R.)

1979-10-01

Presented in two parts, this paper is intended to provide an outline of the theoretical fundamentals for the design of rotating-hearth furnaces for heating round stock and deals with the characteristic design features of such furnaces.

Glass: Rotary Electric Glass Furnace

Energy Technology Data Exchange (ETDEWEB)

Recca, L.

1999-01-29

Compared to conventional gas-fired furnaces, the new rotary electric furnace will increase energy efficiency while significantly reducing air emissions, product turnaround time, and labor costs. As this informative new fact sheet explains, the thousand different types of glass optical blanks produced for the photonics industry are used for lasers, telescopes, cameras, lights, and many other products.

Apparatus of irradiation of steel test pieces in the Marcoule pile G 1

International Nuclear Information System (INIS)

Marinot, R.; Wallet, Ph.

1960-01-01

Test pieces of steel were irradiated in the reactor G1 at Marcoule, in convectors replacing fuel elements, and in vertical channels in furnace-heated containers. The apparatus designed for this irradiation is described: containers, converter-rods, suspension fixtures and clamps, temperature measurement devices, lead castles and unloading set-ups. (author) [fr

Industrial furnace with improved heat transfer

Energy Technology Data Exchange (ETDEWEB)

Hoetzl, M.; Lingle, T.M.

1993-07-20

A method is described for effecting improved heat transfer with in an industrial furnace having a cylindrical furnace section, a door at one end of the furnace section, an end plate at the opposite end of the section a circular fan plate concentrically positioned within the furnace section to define a cylindrical fan chamber between the plate and the end section with a fan there between and a heat treat chamber between the plate and the door, the fan plate defining a non-orificing annular space extending between the interior of the cylindrical furnace section and the outer edge of the plate, the plate having a centrally located under-pressure opening extending there through and a plurality of circumferentially spaced tubular heating elements extending through the annular space into the heat treating chamber, the method comprising the steps of: (a) heating the heating elements to a temperature which is hotter that the temperature of the work within the heat treating chamber; (b) rotating the fan at a speed sufficient to form a portion of the furnace atmosphere as a wind mass swirling about the fan chamber; (c) propagating the wind mass through the annular space into the heat treating chamber as a swirling wind mass in the form of an annulus, the wind mass impinging the heating elements to establish heat transfer contact therewith while the mass retains its annulus shape until contacting the door and without any significant movement of the wind mass into the center of the heat treating chamber; (d) drawing the wind mass through the under-pressure zone after the wind mass comes into heat transfer contact with the work in the heat treating chamber; and (e) thereafter heating the work by radiation from the beating elements at high furnace temperatures in excess of about 1,600 F.

Optical cavity furnace for semiconductor wafer processing

Science.gov (United States)

Sopori, Bhushan L.

2014-08-05

An optical cavity furnace 10 having multiple optical energy sources 12 associated with an optical cavity 18 of the furnace. The multiple optical energy sources 12 may be lamps or other devices suitable for producing an appropriate level of optical energy. The optical cavity furnace 10 may also include one or more reflectors 14 and one or more walls 16 associated with the optical energy sources 12 such that the reflectors 14 and walls 16 define the optical cavity 18. The walls 16 may have any desired configuration or shape to enhance operation of the furnace as an optical cavity 18. The optical energy sources 12 may be positioned at any location with respect to the reflectors 14 and walls defining the optical cavity. The optical cavity furnace 10 may further include a semiconductor wafer transport system 22 for transporting one or more semiconductor wafers 20 through the optical cavity.

Tensile Fracture Behavior of 316L Austenitic Stainless Steel Manufactured by Hot Isostatic Pressing

Science.gov (United States)

Cooper, A. J.; Brayshaw, W. J.; Sherry, A. H.

2018-02-01

Herein we investigate how the oxygen content in hot isostatically pressed (HIP'd) 316L stainless steel affects the mechanical properties and tensile fracture behavior. This work follows on from previous studies, which aimed to understand the effect of oxygen content on the Charpy impact toughness of HIP'd steel. We expand on the work by performing room-temperature tensile testing on different heats of 316L stainless steel, which contain different levels of interstitial elements (carbon and nitrogen) as well as oxygen in the bulk material. Throughout the work we repeat the experiments on conventionally forged 316L steel as a reference material. The analysis of the work indicates that oxygen does not contribute to a measureable solution strengthening mechanism, as is the case with carbon and nitrogen in austenitic stainless steels (Werner in Mater Sci Eng A 101:93-98, 1988). Neither does oxygen, in the form of oxide inclusions, contribute to precipitation hardening due to the size and spacing of particles. However, the oxide particles do influence fracture behavior; fractography of the failed tension test specimens indicates that the average ductile dimple size is related to the oxygen content in the bulk material, the results of which support an on-going hypothesis relating oxygen content in HIP'd steels to their fracture mechanisms by providing additional sites for the initiation of ductile damage in the form of voids.

Quantification of the degradation of steels exposed to liquid lead-bismuth eutectic

International Nuclear Information System (INIS)

Schroer, C.; Voss, Z.; Novotny, J.; Konys, J.

2006-05-01

Metallographic and gravimetric methods of measuring the degradation of steels are introduced and compared, with emphasis on the quantification of oxidation in molten lead-bismuth eutectic (LBE). In future applications of LBE or other molten lead alloys, additions of oxygen should prevent the dissolution of steel constituents in the liquid heavy metal. Therefore, also the amount of steel constituents transferred between the steel (including the oxide scale formed on the surface) and the LBE has to be assessed, in order to evaluate the efficiency of oxygen additions with respect to preventing dissolution of the steel. For testing the methods of quantification, specimens of martensitic steel T91 were exposed for 1500 h to stagnant, oxygen-saturated LBE at 550 C, whereby, applying both metallographic and gravimetric measurements, the recession of the cross-section of sound material deviated by ± 3 μm for a mean value of 11 μm. Although the transfer of steel constituents between the solid phases and the LBE is negligible under the considered exposure conditions, the investigation shows that a gravimetric analysis is most promising for quantifying such a mass transfer. For laboratory experiments on the behaviour of steels in oxygen-containing LBE, it is suggested to make provisions for both metallographic and gravimetric measurements, since both types of methods have specific benefits in the characterisation of the oxidation process. (Orig.)

Optimal Recycling of Steel Scrap and Alloying Elements: Input-Output based Linear Programming Method with Its Application to End-of-Life Vehicles in Japan.

Science.gov (United States)

Ohno, Hajime; Matsubae, Kazuyo; Nakajima, Kenichi; Kondo, Yasushi; Nakamura, Shinichiro; Fukushima, Yasuhiro; Nagasaka, Tetsuya

2017-11-21

Importance of end-of-life vehicles (ELVs) as an urban mine is expected to grow, as more people in developing countries are experiencing increased standards of living, while the automobiles are increasingly made using high-quality materials to meet stricter environmental and safety requirements. While most materials in ELVs, particularly steel, have been recycled at high rates, quality issues have not been adequately addressed due to the complex use of automobile materials, leading to considerable losses of valuable alloying elements. This study highlights the maximal potential of quality-oriented recycling of ELV steel, by exploring the utilization methods of scrap, sorted by parts, to produce electric-arc-furnace-based crude alloy steel with minimal losses of alloying elements. Using linear programming on the case of Japanese economy in 2005, we found that adoption of parts-based scrap sorting could result in the recovery of around 94-98% of the alloying elements occurring in parts scrap (manganese, chromium, nickel, and molybdenum), which may replace 10% of the virgin sources in electric arc furnace-based crude alloy steel production.

Pyrometallurgical processing for raw materials of heavy non-ferrous metals and furnace for carrying it out. Pyrometallurgisches Verarbeitungsverfahren fuer Rohstoffe schwerer Buntmetalle und Ofen zu dessen Realisierung

Energy Technology Data Exchange (ETDEWEB)

Vanjukov, A V; Metschev, V V; Bystrov, V P; Eschov, E I; Vasiliev, M G; Zaitsev, V Y; Romenets, V A; Ivanov, V V; Golik, S Y; Grin-Gnatovsky, E S

1980-06-04

Pyrometallurgical processing is described, by which non-ferrous metals are obtained from a melt. The pneumatic mixing of melt material and the oxidation of sulphide and oxide starting material is done by blowing a flow of gas with more than 35% oxygen content into it. The layers of slag, ore and raw metal formed in the furnace can be separated. The construction of the furnace is described in detail. 4 examples complete the description.

Methodological differences behind energy statistics for steel production – Implications when monitoring energy efficiency

International Nuclear Information System (INIS)

Morfeldt, Johannes; Silveira, Semida

2014-01-01

Energy efficiency indicators used for evaluating industrial activities at the national level are often based on statistics reported in international databases. In the case of the Swedish iron and steel sector, energy consumption statistics published by Odyssee, Eurostat, the IEA (International Energy Agency), and the United Nations differ, resulting in diverging energy efficiency indicators. For certain years, the specific energy consumption for steel is twice as high if based on Odyssee statistics instead of statistics from the IEA. The analysis revealed that the assumptions behind the allocation of coal and coke used in blast furnaces as energy consumption or energy transformation are the major cause for these differences. Furthermore, the differences are also related to errors in the statistical data resulting from two different surveys that support the data. The allocation of coal and coke has implications when promoting resource as well as energy efficiency at the systems level. Eurostat's definition of energy consumption is more robust compared to the definitions proposed by other organisations. Nevertheless, additional data and improved energy efficiency indicators are needed to fully monitor the iron and steel sector's energy system and promote improvements towards a greener economy at large. - Highlights: • Energy statistics for the iron and steel sector diverge in international databases. • Varying methods have implications when monitoring energy and resource efficiency. • Allocation of blast furnaces as transformation activities is behind the differences. • Different statistical surveys and human error also contribute to diverging results

Energy efficiency technologies in cement and steel industry

Science.gov (United States)

Zanoli, Silvia Maria; Cocchioni, Francesco; Pepe, Crescenzo

2018-02-01

In this paper, Advanced Process Control strategies aimed at energy efficiency achievement and improvement in cement and steel industry are proposed. A flexible and smart control structure constituted by several functional modules and blocks has been developed. The designed control strategy is based on Model Predictive Control techniques, formulated on linear models. Two industrial control solutions have been developed, oriented to energy efficiency and process control improvement in cement industry clinker rotary kilns (clinker production phase) and in steel industry billets reheating furnaces. Tailored customization procedures for the design of ad hoc control systems have been executed, based on the specific needs and specifications of the analysed processes. The installation of the developed controllers on cement and steel plants produced significant benefits in terms of process control which resulted in working closer to the imposed operating limits. With respect to the previous control systems, based on local controllers and/or operators manual conduction, more profitable configurations of the crucial process variables have been provided.

Engineering study for a melting, casting, rolling and fabrication facility for recycled contaminated stainless steel

International Nuclear Information System (INIS)

1994-01-01

This Preliminary Report is prepared to study the facilities required for recycling contaminated stainless steel scrap into plate which will be fabricated into boxes suitable for the storage of contaminated wastes and rubble. The study is based upon the underlying premise that the most cost effective way to produce stainless steel is to use the same processes employed by companies now in production of high quality stainless steel. Therefore, the method selected for this study for the production of stainless steel plate from scrap is conventional process using an Electric Arc Furnace for meltdown to hot metal, a Continuous Caster for production of cast slabs, and a Reversing Hot Mill for rolling the slabs into plate. The fabrication of boxes from the plate utilizes standard Shears, Punch Presses and welding equipment with Robotic Manipulators. This Study presumes that all process fumes, building dusts and vapors will be cycled through a baghouse and a nuclear grade HEPA filter facility prior to discharge. Also, all process waste water will be evaporated into the hot flue gas stream from the furnace utilizing a quench tank; so there will be no liquid discharges from the facility and all vapors will be processed through a HEPA filter. Even though HEPA filters are used today in controlling radioactive contamination from nuclear facilities there is a sparsity of data concerning radioactivity levels and composition of waste that may be collected from contaminated scrap steel processing. This report suggests some solutions to these problems but it is recommended that additional study must be given to these environmental problems

Identifying the origins of local atmospheric deposition in the steel industry basin of Luxembourg using the chemical and isotopic composition of the lichen Xanthoria parietina.

Science.gov (United States)

Hissler, Christophe; Stille, Peter; Krein, Andreas; Geagea, Majdi Lahd; Perrone, Thierry; Probst, Jean-Luc; Hoffmann, Lucien

2008-11-01

Trace metal atmospheric contamination was assessed in one of the oldest European industrial sites of steel production situated in the southern part of the Grand-Duchy of Luxembourg. Using elemental ratios as well as Pb, Sr, and Nd isotopic compositions as tracers, we found preliminary results concerning the trace metal enrichment and the chemical/isotopic signatures of the most important emission sources using the lichen Xanthoria parietina sampled at 15 sites along a SW-NE transect. The concentrations of these elements decreased with increasing distance from the historical and actual steel-work areas. The combination of the different tracers (major elements, Rare Earth Element ratios, Pb, Sr and Nd isotopes) enabled us to distinguish between three principal sources: the historical steel production (old tailings corresponding to blast-furnace residues), the present steel production (industrial sites with arc electric furnace units) and the regional background (baseline) components. Other anthropogenic sources including a waste incinerator and major roads had only weak impacts on lichen chemistry and isotopic ratios. The correlation between the Sr and Nd isotope ratios indicated that the Sr-Nd isotope systems represented useful tools to trace atmospheric emissions of factories using scrap metal for steel production.

Water requirements of the iron and steel industry

Science.gov (United States)

Walling, Faulkner B.; Otts, Louis Ethelbert

1967-01-01

Twenty-nine steel plants surveyed during 1957 and 1958 withdrew from various sources about 1,400 billion gallons of water annually and produced 40.8 million tons of ingot steel. This is equivalent to about 34,000 gallons of water per ton of steel. Fifteen iron ore mines and fifteen ore concentration plants together withdrew annually about 89,000 million gallons to produce 15 million tons of iron ore concentrate, or 5,900 gallons per ton of concentrate. About 97 percent of the water used in the steel plants came from surface sources, 2.2 percent was reclaimed sewage, and 1.2 percent was ground water. Steel plants supplied about 96 percent of their own water requirements, although only three plants used self-supplied water exclusively. Water used by the iron ore mines and concentration plants was also predominantly self supplied from surface source. Water use in the iron and steel industry varied widely and depended on the availability of water, age and condition of plants and equipment, kinds of processes, and plant operating procedures. Gross water use in integrated steel plants ranged from 11,200 to 110,000 gallons per ton of steel ingots, and in steel processing plants it ranged from 4,180 to 26,700 gallons per ton. Water reuse also varied widely from 0 to 18 times in integrated steel plants and from 0 to 44 times in steel processing plants. Availability of water seemed to be the principal factor in determining the rate of reuse. Of the units within steel plants, a typical (median) blast furnace required 20,500 gallons of water per ton of pig iron. At the 1956-60 average rate of pig iron consumption, this amounts to about 13,000 gallons per ton of steel ingots or about 40 percent of that required by a typical integrated steel plant 33,200 gallons per ton. Different processes of iron ore concentration are devised specifically for the various kinds of ore. These processes result in a wide range of water use from 124 to 11,300 gallons of water per ton of iron ore

Energy conservation in flame-heated hearth furnaces in aluminium foundries. Pt. 1

Energy Technology Data Exchange (ETDEWEB)

Moser, R

1981-01-01

There are two fields for energy saving: The aluminium foundries obtain the electrolytic metal in liquid form and therefore also excessive heat. This must be used. The furnaces must be designed and operated so that they use as little energy as possible. Both subjects are investigated by considering 59 existing plants in Europe. They are compared regarding energy consumption and heat balance. A series of possibilities for improved use of fuel, such as improvement of the burner setting, automatic regulation of excess air and use of combustion with enriched oxygen supply are given.

Model of Draining of the Blast Furnace Hearth with an Impermeable Zone

Science.gov (United States)

Saxén, Henrik

2015-02-01

Due to demands of lower costs and higher productivity in the steel industry, the volume of operating blast furnaces has grown during the last decades. As the height is limited by the allowable pressure drop, the hearth diameter has grown considerably and, along with this, also draining-related problems. In this paper a mathematical model is developed for simulating the drainage in the case where an impermeable region exists in the blast furnace hearth. The model describes the quasi-stationary drainage process of a hearth with two operating tapholes, where the communication between the two pools of molten slag and iron can be controlled by parameterized expressions. The model also considers the case where the buoyancy of the liquids is sufficient for lifting the coke bed. The implications of different size of the liquid pools, communication between the pools, bed porosity, etc. are studied by simulation, and conclusions concerning their effect on the drainage behavior and evolution of the liquid levels in the hearth are drawn. The simulated liquid levels are finally demonstrated to give rise to a pressure profile acting on the hearth which agrees qualitatively with signals from strain gauges mounted in the hearth wall of an industrial ironmaking process.

Alternative fuels for multiple-hearth furnaces

Energy Technology Data Exchange (ETDEWEB)

Bracket, B D; Lawson, T U

1980-04-01

Results are described of a feasibility study on the use of refuse-derived fuel, shredded paper, wood waste, coal, and waste oil in multiple-hearth furnaces at the Lower Molonglo Water Quality Control Centre in Australia. An assessment of waste fuel availability and characteristics is given, and a summary is made of the technical and economic aspects of using these alternative fuels and of minimizing furnace fuel requirements by reducing sludge moisture. The recommended method of reducing fuel oil consumption in the furnace is shown to be sludge drying, using process exhaust heat in a rotary dryer.

Competitive adsorption of copper(II), cadmium(II), lead(II) and zinc(II) onto basic oxygen furnace slag

International Nuclear Information System (INIS)

Xue Yongjie; Hou Haobo; Zhu Shujing

2009-01-01

Polluted and contaminated water can often contain more than one heavy metal species. It is possible that the behavior of a particular metal species in a solution system will be affected by the presence of other metals. In this study, we have investigated the adsorption of Cd(II), Cu(II), Pb(II), and Zn(II) onto basic oxygen furnace slag (BOF slag) in single- and multi-element solution systems as a function of pH and concentration, in a background solution of 0.01 M NaNO 3 . In adsorption edge experiments, the pH was varied from 2.0 to 13.0 with total metal concentration 0.84 mM in the single element system and 0.21 mM each of Cd(II), Cu(II), Pb(II), and Zn(II) in the multi-element system. The value of pH 50 (the pH at which 50% adsorption occurs) was found to follow the sequence Zn > Cu > Pb > Cd in single-element systems, but Pb > Cu > Zn > Cd in the multi-element system. Adsorption isotherms at pH 6.0 in the multi-element systems showed that there is competition among various metals for adsorption sites on BOF slag. The adsorption and potentiometric titrations data for various slag-metal systems were modeled using an extended constant-capacitance surface complexation model that assumed an ion-exchange process below pH 6.5 and the formation of inner-sphere surface complexes at higher pH. Inner-sphere complexation was more dominant for the Cu(II), Pb(II) and Zn(II) systems

Competitive adsorption of copper(II), cadmium(II), lead(II) and zinc(II) onto basic oxygen furnace slag

Energy Technology Data Exchange (ETDEWEB)

Xue Yongjie [School of Resource and Environment Science, Wuhan University, Hubei, Wuhan (China); Wuhan Kaidi Electric Power Environmental Protection Co. Ltd., Hubei, Wuhan (China)], E-mail: xueyj@mail.whut.edu.cn; Hou Haobo; Zhu Shujing [School of Resource and Environment Science, Wuhan University, Hubei, Wuhan (China)

2009-02-15

Polluted and contaminated water can often contain more than one heavy metal species. It is possible that the behavior of a particular metal species in a solution system will be affected by the presence of other metals. In this study, we have investigated the adsorption of Cd(II), Cu(II), Pb(II), and Zn(II) onto basic oxygen furnace slag (BOF slag) in single- and multi-element solution systems as a function of pH and concentration, in a background solution of 0.01 M NaNO{sub 3}. In adsorption edge experiments, the pH was varied from 2.0 to 13.0 with total metal concentration 0.84 mM in the single element system and 0.21 mM each of Cd(II), Cu(II), Pb(II), and Zn(II) in the multi-element system. The value of pH{sub 50} (the pH at which 50% adsorption occurs) was found to follow the sequence Zn > Cu > Pb > Cd in single-element systems, but Pb > Cu > Zn > Cd in the multi-element system. Adsorption isotherms at pH 6.0 in the multi-element systems showed that there is competition among various metals for adsorption sites on BOF slag. The adsorption and potentiometric titrations data for various slag-metal systems were modeled using an extended constant-capacitance surface complexation model that assumed an ion-exchange process below pH 6.5 and the formation of inner-sphere surface complexes at higher pH. Inner-sphere complexation was more dominant for the Cu(II), Pb(II) and Zn(II) systems.

Competitive adsorption of copper(II), cadmium(II), lead(II) and zinc(II) onto basic oxygen furnace slag.

Science.gov (United States)

Xue, Yongjie; Hou, Haobo; Zhu, Shujing

2009-02-15

Polluted and contaminated water can often contain more than one heavy metal species. It is possible that the behavior of a particular metal species in a solution system will be affected by the presence of other metals. In this study, we have investigated the adsorption of Cd(II), Cu(II), Pb(II), and Zn(II) onto basic oxygen furnace slag (BOF slag) in single- and multi-element solution systems as a function of pH and concentration, in a background solution of 0.01M NaNO(3). In adsorption edge experiments, the pH was varied from 2.0 to 13.0 with total metal concentration 0.84mM in the single element system and 0.21mM each of Cd(II), Cu(II), Pb(II), and Zn(II) in the multi-element system. The value of pH(50) (the pH at which 50% adsorption occurs) was found to follow the sequence Zn>Cu>Pb>Cd in single-element systems, but Pb>Cu>Zn>Cd in the multi-element system. Adsorption isotherms at pH 6.0 in the multi-element systems showed that there is competition among various metals for adsorption sites on BOF slag. The adsorption and potentiometric titrations data for various slag-metal systems were modeled using an extended constant-capacitance surface complexation model that assumed an ion-exchange process below pH 6.5 and the formation of inner-sphere surface complexes at higher pH. Inner-sphere complexation was more dominant for the Cu(II), Pb(II) and Zn(II) systems.

Treatment of petroleum-hydrocarbon contaminated soils using hydrogen peroxide oxidation catalyzed by waste basic oxygen furnace slag

Energy Technology Data Exchange (ETDEWEB)

Tsai, T.T. [Institute of Environmental Engineering, National Sun Yat-Sen University, Kaohsiung 804, Taiwan (China); Kao, C.M., E-mail: jkao@mail.nsysu.edu.tw [Institute of Environmental Engineering, National Sun Yat-Sen University, Kaohsiung 804, Taiwan (China)

2009-10-15

The contamination of subsurface soils with petroleum hydrocarbons is a widespread environmental problem. The objective of this study was to evaluate the potential of applying waste basic oxygen furnace slag (BOF slag) as the catalyst to enhance the Fenton-like oxidation to remediate fuel oil or diesel contaminated soils. The studied controlling factors that affect the removal efficiency of petroleum hydrocarbons included concentrations of H{sub 2}O{sub 2}, BOF slag dosages, types of petroleum hydrocarbons (e.g., fuel oil and diesel), and types of iron mineral. Experimental results indicate that oxidation of petroleum hydrocarbon via the Fenton-like process can be enhanced with the addition of BOF slag. Results from the X-ray powder diffraction analysis reveal that the major iron type of BOF slag/sandy loam system was iron mineral (e.g., {alpha}-Fe{sub 2}O{sub 3} and {alpha}-FeOOH). Approximately 76% and 96% of fuel oil and diesel removal were observed (initial total petroleum hydrocarbon (TPH) concentration = 10,000 mg kg{sup -1}), respectively, with the addition of 15% of H{sub 2}O{sub 2} and 100 g kg{sup -1} of BOF slag after 40 h of reaction. Because BOF slag contains extractable irons such as amorphous iron and soluble iron, it can act as an iron sink to supply iron continuously for Fenton-like oxidation. Results demonstrate that Fenton-like oxidation catalyzed by BOF slag is a potential method to be able to remediate petroleum-hydrocarbon contaminated soils efficiently and effectively.

Quality and energetic evaluation of the charcoal made of babassu nut residues used in the steel industry

OpenAIRE

Protásio, Thiago de Paula; Trugilho, Paulo Fernando; Mirmehdi, Seyedmohammad; Silva, Marcela Gomes da

2014-01-01

Brazil is the only country in the world that uses large scale charcoal in steel-making blast furnaces. Meantime, the monoculture plantations of Eucalyptus are not able to meet the demand for charcoal from the steel industries.Therefore, research is necessary, in order to use lignocellulosic residues for the production of charcoal with technological properties which are suitable for the reduction of iron ore. Given the above, the objective of this study was to evaluate the quality of charcoal ...

Estimation of slagging in furnaces; Kuonaavuuden ennustaminen kivihiilen poelypoltossa

Energy Technology Data Exchange (ETDEWEB)

Jacobson, T; Jaeaeskelaeinen, K; Oeini, J; Koskiahde, A; Jokiniemi, J; Pyykkoenen, J [Imatran Voima Oy, Vantaa (Finland)

1997-10-01

Understanding and estimation of slagging in furnaces is essential in the design of new power plants with high steam values or in modifications like low-NO{sub x} retrofits in existing furnaces. Major slagging yields poor efficiency, difficult operation and high maintenance costs of the plant. The aim of the project is to develop a computational model for slagging in pulverized coal combustion. The model is based on Computer Controlled Scanning Electron Microscopy (CCSEM) analysis of mineral composition of the coal and physical models for behaviour of minerals inside a furnace. The analyzed mineral particles are classified to five composition classes and distributed to calculational coal particles if internal minerals of coal. The calculational coal particles and the external minerals are traced in the furnace to find out the behaviour of minerals inside the furnace. If the particle tracing indicates that the particle hits the heat transfer surface of the furnace the viscosity of the particle is determined to see if particle is sticky. The model will be implemented to 3D computational fluid dynamics based furnace simulation environment Ardemus which predicts the fluid dynamics, heat transfer and combustion in a furnace. (orig.)

Influence of fuel composition on the non-oxidizing heating of steel in a waste gas atmosphere

Energy Technology Data Exchange (ETDEWEB)

Minkler, W [LOI Industrieofenanlagen G.m.b.H., Essen (Germany, F.R.)

1979-04-01

On the basis of a number of graphs and data on theoretical combustion temperatures and the difference between the heating value of the fuel and the waste gas in respect of 1 m/sup 3/ of waste gas, the author demonstrates the influence of fuel composition on the non-oxidizing heating of steel in a waste gas atmosphere derived from five different fuels. A rotary-hearth furnace is described for the non-oxidizing heating of pressings from plain carbon and alloy steel.

Fiscal 1999 research report. Basic research for promotion of joint implementation programs (Basic research on energy efficiency at Novolipetsk Iron and Steel Works); 1999 nendo Novolipetsk seitetsushosho energy kihon chosa hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

A survey is conducted about whether energy efficiency improving facilities will be appropriately accommodated by the sintering process, blast furnace process, steelmaking process, and the energy process that consume energy in large quantities at the Novolipetsk Iron and Steel Works which represents Russia's steelmaking plants, which is for scouting out a project to develop into a joint implementation activity in the future. The result shows that the amount of natural gas for domestic power generators in the steelworks or the amount of power to be purchased will be reduced when large-scale exhaust heat recovery facilities are adopted. A study of the energy profile shows that there is no problem to impede the implementation of this program. Regarding the introduction of energy saving measures into the respective processes, the results of investigations conducted into the respective processes are subjected to a macroscopic study. The facilities involved include a sintering cooler exhaust heat recovery facility, hot blast furnace waste heat recovery facility, TRT (power generation by blast furnace top-pressure recovery turbines) facility, and an LDG (basic oxygen gas) recovery facility. Upon adoption of all these facilities, there will be a reduction in green effect gas (CO2) emissions of approximately 410,000 tons/year, for which a total of 20.9-billion yen will have to be invested. (NEDO)

The Iron and Steel Industry in Asia: Development and Restructuring

OpenAIRE

Sato, Hajime

2009-01-01

The paper examines the development and restructuring of the iron and steel industryin Asian countries. Studying countries that have integrated steelworks with largeblast furnaces (South Korea, Taiwan, China and India) and countries without(Thailand, Indonesia and Malaysia), the paper shows the difference in thedevelopment processes across the countries and across time, and points to thediversity of the development experience of these countries. The paper argues thatsignificant differences in ...

Dynamics and control of a gas-fired furnace

NARCIS (Netherlands)

Roffel, B.; Rijnsdorp, J.E.

1974-01-01

A non-linear model has been developed for a gas-fired furnace in which oil is heated. The model is applicable from minimum to maximum heat load of the furnace. The dynamics of the model have been compared to experimental results, which were obtained for a pilot-scale furnace. They are in good

Nitride alloy layer formation of duplex stainless steel using nitriding process

Science.gov (United States)

Maleque, M. A.; Lailatul, P. H.; Fathaen, A. A.; Norinsan, K.; Haider, J.

2018-01-01

Duplex stainless steel (DSS) shows a good corrosion resistance as well as the mechanical properties. However, DSS performance decrease as it works under aggressive environment and at high temperature. At the mentioned environment, the DSS become susceptible to wear failure. Surface modification is the favourable technique to widen the application of duplex stainless steel and improve the wear resistance and its hardness properties. Therefore, the main aim of this work is to nitride alloy layer on the surface of duplex stainless steel by the nitriding process temperature of 400°C and 450°C at different time and ammonia composition using a horizontal tube furnace. The scanning electron microscopy and x-ray diffraction analyzer are used to analyse the morphology, composition and the nitrided alloy layer for treated DSS. The micro hardnesss Vickers tester was used to measure hardness on cross-sectional area of nitrided DSS. After nitriding, it was observed that the hardness performance increased until 1100 Hv0.5kgf compared to substrate material of 250 Hv0.5kgf. The thickness layer of nitride alloy also increased from 5μm until 100μm due to diffusion of nitrogen on the surface of DSS. The x-ray diffraction results showed that the nitride layer consists of iron nitride, expanded austenite and chromium nitride. It can be concluded that nitride alloy layer can be produced via nitriding process using tube furnace with significant improvement of microstructural and hardness properties.

Interim fatigue design curves for carbon, low-alloy, and austenitic stainless steels in LWR environments

International Nuclear Information System (INIS)

Majumdar, S.; Chopra, O.K.; Shack, W.J.

1993-01-01

Both temperature and oxygen affect fatigue life; at the very low dissolved-oxygen levels in PWRs and BWRs with hydrogen water chemistry, environmental effects on fatigue life are modest at all temperatures (T) and strain rates. Between 0.1 and 0.2 ppM, the effect of dissolved-oxygen increases rapidly. In oxygenated environments, fatigue life depends strongly on strain rate and T. A fracture mechanics model is developed for predicting fatigue lives, and interim environmentally assisted cracking (EAC)-adjusted fatigue curves are proposed for carbon steels, low-alloy steels, and austenitic stainless steels

Holden gas-fired furnace baseline data. Revision 1

International Nuclear Information System (INIS)

Weatherspoon, K.A.

1996-11-01

The Holden gas-fired furnace is used in the enriched uranium recovery process to dry and combust small batches of combustibles. The ash is further processed. The furnace operates by allowing a short natural gas flame to burn over the face of a wall of porous fire brick on two sides of the furnace. Each firing wall uses two main burners and a pilot burner to heat the porous fire brick to a luminous glow. Regulators and orifice valves are used to provide a minimum gas pressure of 4 in. water column at a rate of approximately 1,450 scf/h to the burners. The gas flow rate was calculated by determining the gas flow appropriate for the instrumentation in the gas line. Observed flame length and vendor literature were used to calculate pilot burner gas consumption. Air for combustion, purging, and cooling is supplied by a single blower. Rough calculations of the air-flow distribution in piping entering the furnace show that air flow to the burners approximately agrees with the calculated natural gas flow. A simple on/off control loop is used to maintain a temperature of 1,000 F in the furnace chamber. Hoods and glove boxes provide contamination control during furnace loading and unloading and ash handling. Fan EF-120 exhausts the hoods, glove boxes, and furnace through filters to Stack 33. A review of the furnace safety shows that safety is ensured by design, interlocks, procedure, and a safety system. Recommendations for safety improvements include installation of both a timed ignition system and a combustible-gas monitor near the furnace. Contamination control in the area could be improved by redesigning the loading hood face and replacing worn gaskets throughout the system. 33 refs., 16 figs

Steel reinforced composite silicone membranes and its integration to microfluidic oxygenators for high performance gas exchange.

Science.gov (United States)

Matharoo, Harpreet; Dabaghi, Mohammadhossein; Rochow, Niels; Fusch, Gerhard; Saraei, Neda; Tauhiduzzaman, Mohammed; Veldhuis, Stephen; Brash, John; Fusch, Christoph; Selvaganapathy, P Ravi

2018-01-01

Respiratory distress syndrome (RDS) is one of the main causes of fatality in newborn infants, particularly in neonates with low birth-weight. Commercial extracorporeal oxygenators have been used for low-birth-weight neonates in neonatal intensive care units. However, these oxygenators require high blood volumes to prime. In the last decade, microfluidics oxygenators using enriched oxygen have been developed for this purpose. Some of these oxygenators use thin polydimethylsiloxane (PDMS) membranes to facilitate gas exchange between the blood flowing in the microchannels and the ambient air outside. However, PDMS is elastic and the thin membranes exhibit significant deformation and delamination under pressure which alters the architecture of the devices causing poor oxygenation or device failure. Therefore, an alternate membrane with high stability, low deformation under pressure, and high gas exchange was desired. In this paper, we present a novel composite membrane consisting of an ultra-thin stainless-steel mesh embedded in PDMS, designed specifically for a microfluidic single oxygenator unit (SOU). In comparison to homogeneous PDMS membranes, this composite membrane demonstrated high stability, low deformation under pressure, and high gas exchange. In addition, a new design for oxygenator with sloping profile and tapered inlet configuration has been introduced to achieve the same gas exchange at lower pressure drops. SOUs were tested by bovine blood to evaluate gas exchange properties. Among all tested SOUs, the flat design SOU with composite membrane has the highest oxygen exchange of 40.32 ml/min m 2 . The superior performance of the new device with composite membrane was demonstrated by constructing a lung assist device (LAD) with a low priming volume of 10 ml. The LAD was achieved by the oxygen uptake of 0.48-0.90 ml/min and the CO 2 release of 1.05-2.27 ml/min at blood flow rates ranging between 8 and 48 ml/min. This LAD was shown to increase the

Liquid steel analysis by laser-induced plasma spectroscopy

International Nuclear Information System (INIS)

Gruber, J.

2002-11-01

When a nanosecond pulsed laser is focused onto a sample and the intensity exceeds a certain threshold, material is vaporized and a plasma is formed above the sample surface. The laser-light becomes increasingly absorbed by inverse bremsstrahlung and by photo-excitation and photo-ionization of atoms and molecules. The positive feedback, by which the number of energetic electrons for ionization is increased in an avalanche-like manner under the influence of laser-light, is the so-called optical breakdown. Radiating excited atoms and ions within the expanding plasma plume produce a characteristic optical emission spectrum. A spectroscopic analysis of this optical emission of the laser-induced plasma permits a qualitative and quantitative chemical analysis of the investigated sample. This technique is therefore often called laser-induced plasma spectroscopy (LIPS) or laser-induced breakdown spectroscopy (LIBS). LIPS is a fast non-contact technique, by which solid, liquid or gaseous samples can be analyzed with respect to their chemical composition. Hence, it is an appropriate tool for the rapid in-situ analysis of not easily accessible surfaces for process control in industrial environments. In this work, LIPS was studied as a technique to determine the chemical composition of solid and liquid steel. A LIPS set-up was designed and built for the remote and continuous in-situ analysis of the steel melt. Calibration curves were prepared for the LIPS analysis of Cr, Mn, Ni and Cu in solid steel using reference samples with known composition. In laboratory experiments an induction furnace was used to melt steel samples in crucibles, which were placed at a working distance of 1.5 m away from the LIPS apparatus. The response of the LIPS system was monitored on-line during the addition of pure elements to the liquid steel bath within certain concentration ranges (Cr: 0.11 - 13.8 wt%, Cu: 0.044 - 0.54 wt%, Mn: 1.38 - 2.5 wt%, Ni: 0.049 - 5.92 wt%). The analysis of an element

The use of blast furnace slag

Directory of Open Access Journals (Sweden)

V. Václavík

2012-10-01

Full Text Available The paper presents the results of experimental research that dealt with the substitution of finely ground blast furnace slag for Portland cement in the course of simple concrete manufacturing. Physical and mechanical properties of experimental concrete mixtures based on finely ground blast furnace slag were observed.

Furnace for treating bituminous material

Energy Technology Data Exchange (ETDEWEB)

Klotzer, M

1922-04-28

A furnace with saw-teeth-like profiled hearth, which by means of a kind of shaking slide executes a backward and forward motion, for carrying out the process according to Patent 422,391. It is characterized in that the stroke of the hearth moving in the furnace is smaller than the length of the profile tooth and the height of the feed is held less than the tooth height.

Study of the oxygen reduction reaction on stainless steel materials in natural seawater. Influence of the bio-film on corrosion processes; Reaction de reduction de l'oxygene sur les aciers inoxydables en eau de mer naturelle. Influence du biofilm sur les processus de corrosion

Energy Technology Data Exchange (ETDEWEB)

Le Bozec, N

2000-01-15

Bio-film development on stainless steels immersed in natural seawater can have prejudicial consequences on the resistance of these materials to corrosion. The goal of the present study was to get more precise information on the corrosion processes, and especially on the oxygen reduction reaction. As the reaction is linked to the stainless steel surface state, the characterisation of the oxides films (composition, structure, thickness...) is essential to understand the mechanisms and the oxygen reduction kinetic. The first aim of the study has been to correlate the oxygen reduction processes with the characteristics of the oxides layer as a function of the alloy surface treatment (mechanical polishing, electrochemical passivation and pre-reduction, chemical treatment with some acids or with hydrogen peroxide). The second stage has consisted in following the evolution of the oxygen reduction processes and of the characteristics of the oxides layer with the aging of stainless steels in natural and artificial sea-waters. One major bio-film effect appears to be the production of hydrogen peroxide at a concentration level which induces modifications of the oxides layers and, consequently, of the evolution of the oxygen reduction kinetics as well as of the open circuit potential. Electrochemical techniques (voltammetric analysis at rotating disk and ring-disk electrodes, coulometry) combined with a surface analytical method by X-ray photoelectron spectroscopy have been used. The characterisation of the bio-film required the use of microscopy (scanning electronic microscopy, epi-fluorescence microscopy) and microbiological methods (cultures). The in-situ detection of hydrogen peroxide formed inside the bio-film has been performed with a micro-electrode and the results were confirmed with enzymatic methods. (author)

Study of the oxygen reduction reaction on stainless steel materials in natural seawater. Influence of the bio-film on corrosion processes; Reaction de reduction de l'oxygene sur les aciers inoxydables en eau de mer naturelle. Influence du biofilm sur les processus de corrosion

Energy Technology Data Exchange (ETDEWEB)

Le Bozec, N

2000-01-15

Bio-film development on stainless steels immersed in natural seawater can have prejudicial consequences on the resistance of these materials to corrosion. The goal of the present study was to get more precise information on the corrosion processes, and especially on the oxygen reduction reaction. As the reaction is linked to the stainless steel surface state, the characterisation of the oxides films (composition, structure, thickness...) is essential to understand the mechanisms and the oxygen reduction kinetic. The first aim of the study has been to correlate the oxygen reduction processes with the characteristics of the oxides layer as a function of the alloy surface treatment (mechanical polishing, electrochemical passivation and pre-reduction, chemical treatment with some acids or with hydrogen peroxide). The second stage has consisted in following the evolution of the oxygen reduction processes and of the characteristics of the oxides layer with the aging of stainless steels in natural and artificial sea-waters. One major bio-film effect appears to be the production of hydrogen peroxide at a concentration level which induces modifications of the oxides layers and, consequently, of the evolution of the oxygen reduction kinetics as well as of the open circuit potential. Electrochemical techniques (voltammetric analysis at rotating disk and ring-disk electrodes, coulometry) combined with a surface analytical method by X-ray photoelectron spectroscopy have been used. The characterisation of the bio-film required the use of microscopy (scanning electronic microscopy, epi-fluorescence microscopy) and microbiological methods (cultures). The in-situ detection of hydrogen peroxide formed inside the bio-film has been performed with a micro-electrode and the results were confirmed with enzymatic methods. (author)

Effect of Dissolved Oxygen and Immersion Time on the Corrosion Behaviour of Mild Steel in Bicarbonate/Chloride Solution

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Gaius Debi Eyu

2016-09-01

Full Text Available The electrochemical behavior of mild steel in bicarbonate solution at different dissolved oxygen (DO concentrations and immersion times has been studied under dynamic conditions using electrochemical techniques. The results show that both DO and immersion times influence the morphology of the corrosion products. In comparative tests, the corrosion rate was systematically found to be lower in solutions with lower DO, lower HCO3− concentrations and longer immersion time. The SEM analyses reveal that the iron dissolution rate was more severe in solutions containing higher DO. The decrease in corrosion rate can be attributed to the formation of a passive layer containing mainly α -FeO (OH and ( γ -Fe2O3/Fe3O4 as confirmed by the X-ray diffractometry (XRD and X-ray photoelectron spectroscopy (XPS. Passivation of mild steel is evident in electrochemical test at ≈ −600 mVSCE at pH ≥ 8 in dearated ( ≤ 0.8 ppm DO chloride bicarbonate solution under dynamic conditions.

Plasma sintering of ferritic steel reinforced with niobium carbide prepared by high energy milling; Sinterizacao a plasma de aco ferritico reforcado com carbeto de niobio preparado por moagem de alta energia

Energy Technology Data Exchange (ETDEWEB)

Silva Junior, J.F. da; Almeida, E.O.; Gomes, U.U.; Alves Junior, C.; Messias, A.P. [Universidade Federal do Rio Grande do Norte (UFRN), Natal (Brazil). Lab. de Materiais Ceramicos e Metais Especiais; Universidade Federal do Rio Grande do Norte (UFRN), Natal (Brazil). Lab. de Processamento de Materiais por Plasma

2010-07-01

Plasma is an ionized gas where ions are accelerated from anode to cathode surface, where the sample is placed. There are a lot of collisions on cathode surface by ions heating and sintering the sample. High energy milling (HEM) is often used to produce composite particles to be used on powder metallurgy. These particles can exhibit fine particles and high phase dispersion. This present work aim to study ferritic steels reinforced with 3%NbC prepared by HEM and sintered on plasma furnace. Ferritic steel and NbC powders were milled during 5 hours and characterized by SEM, XRD and laser scattering. Then, these composite powders were compacted in a cylindrical steel die and then sintered in a plasma furnace. Vickers microhardness tests and SEM and XRD analysis were performed on sintered samples. (author)

Nitrogen oxide emissions from a kraft recovery furnace

International Nuclear Information System (INIS)

Prouty, A.L.; Stuart, R.C.; Caron, A.L.

1993-01-01

Nitrogen Oxide (NOx) emissions from a rebuilt kraft recovery furnace slightly exceeded the specified limit of 1.1 lb/ton (0.55 kg/metric ton) of black-liquor solids. Mill trials were undertaken to determine whether NOx emissions could be minimized by modifying furnace operation. NOx emissions increased when secondary air was shifted to tertiary ports. NOx emissions fell when the amounts of primary and total air were decreased, but this increased emissions of other pollutants. After demonstrating that best operation of the furnace could not meet the permit with an emissions limit that matched the furnace's performance at best operation

Hydrogen effect on different melts of steel 03Cr10Ni10Mo2(Ti,Al)

International Nuclear Information System (INIS)

Hruby, J.; Novosad, P.; Axamit, R.

1984-01-01

The effect of hydrogen on martensitic 03Cr10Ni10Mo2(Ti,Al) steel was studied following vacuum induction melting and electroslag remelting with and without the effect of radiation. Under the influence of hydrogen and under the same parameters of catodic hydrogen charging of steel after vacuum induction melting shows a 20 - 30% reduction in total ductility. Steels after electroslag remelting show a higher reduction in total ductility - within the range of 26 - 33%, i.e., 33 - 43% for different melts, and contraction Z shows a reduction of 23 - 59%. Electroslag remelted steels show a greater reduction in plasticity owing to hydrogen than steels melted in vacuum induction furnaces. The reduction of the yield point and the breaking strength owing to hydrogen are more explicit than in steel after vacuum melting. In non-irradiated hydrogenated samples a higher yield point was evident. (B.S.)

Fiscal 1999 report on result on the model project for systematization of high-efficiency combustion of by-product gas in ironworks. Part 2/2; 1999 nendo seitetsusho fukusei gas kokoritsu nensho system ka model jigyo. 2/2

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-09-01

For the purpose of reducing energy consumption of the steel industry, a large energy consuming industry in China, a model project was carried out for systematization of high-efficiency combustion of by-product gasses in ironworks, with the fiscal 1999 results compiled in the form of detailed design/documents, and the like. This project is intended for demonstration and dissemination of technologies for improving energy consumption efficiency, by controlling mixed gas calorie and oxygen content, in the reheating furnaces that consume as fuels various combustible gasses produced in iron and steel making processes. Arranged in the detailed design documentation were numerous drawings including a list of mixed gas equipment, design drawing of mixed gas orifice, specification of mixed gas control valves, list of reheating furnace equipment and devices for No.1 small plant, specification of control valves of reheating furnace for No.1 plant, list of reheating equipment and devices for slab plant, specification of calorimeter, specification of oxygen concentration meter, No.1 mixed gas wiring system diagram, and No.3 mixed gas piping/assembling manual. Also prepared were a manual for pre-shipment inspection and report on inspection findings, as well as notes on transportation, program for receiving Chinese engineers, schedule for dispatching engineers, etc. (NEDO)

The compatibility of various austenitic steels with molten sodium (1963)

International Nuclear Information System (INIS)

Champeix, L.; Sannier, J.; Darras, R.; Graff, W.; Juste, P.

1963-01-01

Various techniques for studying corrosion by molten sodium have been developed and applied to the case of 18/10 austenitic steels. The results obtained are discussed as a function of various parameters: type of steel, temperature, oxygen content of the sodium, surface treatment, welds, mechanical strain. In general, these steels have an excellent resistance to sodium when the oxygen content is limited by a simple purification system of the 'cold trap' type, and when an attempt is made to avoid cavitation phenomena which are particularly dangerous, as is shown by the example given. (authors) [fr

The effect of blast furnace slag on the microstructure of the cement paste/steel interface

International Nuclear Information System (INIS)

Onabolu, O.A.; Pratt, P.L.

1988-01-01

The microstructures of steel reinforced ordinary Portland cement mortar samples, and those containing 40% and 70% slag as cement replacement, have been studied by electron optical techniques, after exposure to stagnant sea-water at 23 0 C for 320 days. Fracture surfaces along the interface with steel were examined using secondary electron imaging in the SEM. This revealed differences between the OPC and slag specimens as regards the morphology of the phases and the amounts of calcium hydroxide present. The microstructure at the interface with steel was studied by means of back scattered electron imaging combined with quantitative image analysis. Chloride concentrations at sections around the interface were determined by means of an EDXA facility linked to the SEM. Even after 320 days immersion in sea-water, there was some calcium hydroxide present in the interfacial zone

The use of nuclear heat in the steel industry

International Nuclear Information System (INIS)

Coche, L.

1976-01-01

It is possible, but not easy, to use nuclear energy for steelmaking: low temperature level, and difficulty to get a continuous energy supply, are the main limiting factors. Practically, the nuclear reactor and the steel making units will not be coupled. Among the various possible systems, the most practical one for the near future consists in using nuclear heat to produce hydrogen (using natural gas or oil products as a feedstock) and electric power. Hydrogen is used to reduce iron ore in units such as Midrex, Hyl, Armco or Purofer. Steel is produced from this reduced material in electric arc furnaces. Industrial development will be slow, since economical conditions are presently pretty far from making such a process economically competitive [fr

Multiple hearth furnace for reducing iron oxide

Science.gov (United States)

Brandon, Mark M [Charlotte, NC; True, Bradford G [Charlotte, NC

2012-03-13

A multiple moving hearth furnace (10) having a furnace housing (11) with at least two moving hearths (20) positioned laterally within the furnace housing, the hearths moving in opposite directions and each moving hearth (20) capable of being charged with at least one layer of iron oxide and carbon bearing material at one end, and being capable of discharging reduced material at the other end. A heat insulating partition (92) is positioned between adjacent moving hearths of at least portions of the conversion zones (13), and is capable of communicating gases between the atmospheres of the conversion zones of adjacent moving hearths. A drying/preheat zone (12), a conversion zone (13), and optionally a cooling zone (15) are sequentially positioned along each moving hearth (30) in the furnace housing (11).

Dissolution mechanism of austenitic stainless steels in lead-bismuth eutectic at 500 deg. C

International Nuclear Information System (INIS)

Roy, M.

2012-01-01

In the framework of the future nuclear power plants studies, lead-bismuth eutectic (LBE) is foreseen as a coolant in the primary or the secondary circuit in three nuclear systems. The use of this liquid alloy induces corrosion issues for structural steels. In liquid lead alloys, steels can undergo two corrosion phenomena: dissolution or oxidation depending on the temperature and the dissolved oxygen content in LBE. The goal of this study is to identify the dissolution mechanisms of austenitic steels in LBE at 500 deg. C. Four Fe-Cr-Ni model austenitic steels, the 316L steel and five other industrial steels were corroded in LBE up to, respectively, 3000, 6000 and 200 h. The dissolution mechanism is identical for all steels: it starts by a preferential dissolution of chromium and nickel. This dissolution leads to the formation of a ferritic corrosion layer penetrated by LBE and containing between 5 and 10 at% of chromium and almost no nickel. This study demonstrates that dissolutions of nickel and chromium are linked. Otherwise, the corrosion kinetics is linear whatever the tested austenitic steel. The controlling steps of the austenitic steels' corrosion rates have been identified. Natural convection in the LBE bath leads to the formation of a diffusion boundary layer at the steel surface. Chromium diffusion in this diffusion boundary layer seems to control the corrosion rates of the model and industrial austenitic steels except the 316L steel. Indeed, the corrosion rate of the 316L steel is controlled by an interfacial reaction which is either the simultaneous dissolution of nickel and chromium in Ni, Cr compounds or the nickel and chromium dissolution catalyzed by the dissolved oxygen in LBE. This study has permitted to highlight the major role of chromium on the corrosion mechanisms and the corrosion rates of austenitic steels: the corrosion rate increases when chromium activity increases. Finally, the impact of the dissolved oxygen and the minor alloying

Determinação de fósforo em aços por espectrometria de absorção atômica no forno de grafite Determination of phosphorus in steel samples by graphite furnace atomic absorption spectrometry

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Adilson José Curtius

1998-06-01

Full Text Available A method for the determination of phosphorus in steel samples by graphite furnace atomic absorption spectrometry, using the Zeeman effect background correction and the STPF conditions is proposed. The effect of iron (III on the phosphorus signal was studied. It was verified, through the pyrolysis temperature curves, that iron (III is an efficient chemical modifier, thermically stabilizing phosphorus up to 1400ºC. The phosphorus signal increases with the iron (III concentration, but in the range, which corresponds to the usual concentrations of iron in the sample solutions, the increase is small. Phosphorus was determined in three standard reference materials, after its dissolution in a mixture of hydrochloric and perchloric acids in a PTFE bomb. The agreement with the certified concentration values was excellent. Iron (III was added to the reference analytical solutions prepared in the blank of the dissolution, while the sample solutions were measured directly, since they already contained the modifier. The detection limit (k = 2 was 0.0042% of phosphorus in the steel sample.

The influence of low oxygen and contaminated sodium environments on the fatigue behavior of solution treated AISI 316 stainless steel

Energy Technology Data Exchange (ETDEWEB)

Marshall, P [CEGB, BNL, Berkeley (United Kingdom)

1977-07-01

The influence of air and sodium environments on the fatigue properties of solution treated AISI 316 steel was studied by predictive methods and by conducting tests in air, in high temperature sodium, or following pre-exposure to sodium. The sodium environments studied included contaminated sodium or the products of sodium/water flames possibly typical of fast reactor fault conditions, and low oxygen sodium more appropriate to normal plant operation. Generally, fatigue properties were reduced by contaminated sodium or the products of sodium/water flames and improved by low oxygen sodium when compared with similar tests conducted in air. However, complex effects were observed with respect to crack initiation. The experimental results are discussed and generally follow trends predicted by physically based fatigue models. (author)

[Characteristic of Mercury Emissions and Mass Balance of the Typical Iron and Steel Industry].

Science.gov (United States)

Zhang, Ya-hui; Zhang, Cheng; Wang, Ding-yong; Luo, Cheng-zhong; Yang, Xi; Xu, Feng

2015-12-01

To preliminarily discuss the mercury emission characteristics and its mass balance in each process of the iron and steel production, a typical iron and steel enterprise was chosen to study the total mercury in all employed materials and estimate the input and output of mercury during the steel production process. The results showed that the mercury concentrations of input materials in each technology ranged 2.93-159.11 µg · kg⁻¹ with the highest level observed in ore used in blast furnace, followed by coal of sintering and blast furnace. The mercury concentrations of output materials ranged 3.09-18.13 µg · kg⁻¹ and the mercury concentration of dust was the highest, followed by converter slag. The mercury input and the output in the coking plant were 1346.74 g · d⁻¹ ± 36.95 g · d⁻¹ and 177.42 g · d⁻¹ ± 13.73 g · d⁻¹, respectively. In coking process, mercury mainly came from the burning of coking coal. The sintering process was the biggest contributor for mercury input during the iron and steel production with the mercury input of 1075. 27 g · d⁻¹ ± 60.89 g · d⁻¹ accounting for 68.06% of the total mercury input during this production process, and the ore powder was considered as the main mercury source. For the solid output material, the output in the sintering process was 14.15 g · d⁻¹ ± 0.38 g · d⁻¹, accounting for 22.61% of the total solid output. The mercury emission amount from this studied iron and steel enterprise was estimated to be 553.83 kg in 2013 with the emission factor of 0.092 g · t⁻¹ steel production. Thus, to control the mercury emissions, iron and steel enterprises should combine with production practice, further reduce energy consumption of coking and sintering, or improve the quality of raw materials and reduce the input of mercury.

Hydration of dicalcium silicate and diffusion through neo-formed calcium-silicate-hydrates at weathered surfaces control the long-term leaching behaviour of basic oxygen furnace (BOF) steelmaking slag.

Science.gov (United States)

Stewart, Douglas I; Bray, Andrew W; Udoma, Gideon; Hobson, Andrew J; Mayes, William M; Rogerson, Mike; Burke, Ian T

2018-04-01

Alkalinity generation and toxic trace metal (such as vanadium) leaching from basic oxygen furnace (BOF) steel slag particles must be properly understood and managed by pre-conditioning if beneficial reuse of slag is to be maximised. Water leaching under aerated conditions was investigated using fresh BOF slag at three different particle sizes (0.5-1.0, 2-5 and 10 × 10 × 20 mm blocks) and a 6-month pre-weathered block. There were several distinct leaching stages observed over time associated with different phases controlling the solution chemistry: (1) free-lime (CaO) dissolution (days 0-2); (2) dicalcium silicate (Ca 2 SiO 4 ) dissolution (days 2-14) and (3) Ca-Si-H and CaCO 3 formation and subsequent dissolution (days 14-73). Experiments with the smallest size fraction resulted in the highest Ca, Si and V concentrations, highlighting the role of surface area in controlling initial leaching. After ~2 weeks, the solution Ca/Si ratio (0.7-0.9) evolved to equal those found within a Ca-Si-H phase that replaced dicalcium silicate and free-lime phases in a 30- to 150-μm altered surface region. V release was a two-stage process; initially, V was released by dicalcium silicate dissolution, but V also isomorphically substituted for Si into the neo-formed Ca-Si-H in the alteration zone. Therefore, on longer timescales, the release of V to solution was primarily controlled by considerably slower Ca-Si-H dissolution rates, which decreased the rate of V release by an order of magnitude. Overall, the results indicate that the BOF slag leaching mechanism evolves from a situation initially dominated by rapid hydration and dissolution of primary dicalcium silicate/free-lime phases, to a slow diffusion limited process controlled by the solubility of secondary Ca-Si-H and CaCO 3 phases that replace and cover more reactive primary slag phases at particle surfaces.

Application of Carbon Composite Bricks for Blast Furnace Hearth

Science.gov (United States)

Zuo, Haibin; Wang, Cong; Zhang, Jianliang; Zhao, Yongan; Jiao, Kexin

Traditional refractory materials for blast furnace hearth lining are mainly composed of carbon bricks and the ceramic cup. However, these materials can't meet the demands for long service life design of blast furnaces. In this paper, a new refractory called carbon composite brick (CCB) was introduced, which combined the advantages of carbon bricks and the ceramic cup. In this case, the resistance of the CCB against corrosion was equal to the ceramic cup and the thermal conductivity of the CCB was equal to carbon bricks. From the results of more than 20 blast furnaces, the CCB could be well used in small blast furnaces and large blast furnaces. In the bad condition of low grade burden and high smelting intensity, the CCB gave full play to the role of cooling system, and effectively resisted the erosion of hot metal to improve the service life of blast furnaces.

Effects of the Nanostructured Fe-V-Nb Modificators on the Microstructure and Mechanical Properties of Si-Mn Steel

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Tiebao Wang

2012-01-01

Full Text Available The nanostructured Fe-V-Nb master alloy was prepared in vacuum rapid quenching furnace and then was added in the steel melts as modificators before casting. Next, the effects of the nanostructured Fe-V-Nb modificators on the microstructure and mechanical properties of the steel were studied. The results show that the grain size of the steel has been effectively refined, which is mainly because the dispersed nanoscale particles can produce more nucleation sites during the solidification of the liquid steel. Tensile properties and fracture morphology reveal that the yield strength and toughness of the steel modified by nanostructured Fe-V-Nb modificators are better than that of the microalloyed steel. TEM analysis shows that vanadium and niobium in the modificators exist in the form of (V, Nb C which effectively increases the nucleation rate and leads to better mechanical properties of the steel.

A possible recycling method for high grade steels EAFD in polymer composites.

Science.gov (United States)

Niubó, M; Fernández, A I; Chimenos, J M; Haurie, L

2009-11-15

This work evaluates the feasibility of incorporating electric arc furnace dust (EAFD), as filler in a polymer matrix, to obtain a moldable heavyweight sheet, useful for acoustic insulation in automotive industry. For this purpose EAFD from a steel factory that manufactures high quality steels, was characterized and different formulations of composites were prepared. Physical and mechanical properties, as well as fire behaviour were tested and compared with a polymer composite compounded with common mineral fillers. Optimum formulation with 25% EAFD fulfils the RoHs Directive used by automotive industry to regulate heavy metals content. Leaching test was also performed on prepared composites to classify the material after use.

MATHEMATICAL SIMULATION OF ARGON MIXING PROCESSES AND STEEL SATURATION WITH CARBON IN LADLE

Directory of Open Access Journals (Sweden)

A. N. Chichko

2006-01-01

Full Text Available The mathematical model for dissolution process of a powder material in steel melt is proposed in the paper. The model permits to take into account mixing hydrodynamics on the basis of the Navier-Stokes equations. One of the industrial out-of-furnace treatment schemes taken as an example demonstrates the opportunities to model a carbon dissolution in a ladle.

Development of models and online diagnostic monitors of the high-temperature corrosion of refractories in oxy/fuel glass furnaces : final project report.

Energy Technology Data Exchange (ETDEWEB)

Griffiths, Stewart K.; Gupta, Amul (Monofrax Inc., Falconer, NY); Walsh, Peter M.; Rice, Steven F.; Velez, Mariano (University of Missouri, Rolla, MO); Allendorf, Mark D.; Pecoraro, George A. (PPG Industries, Inc., Pittsburgh, PA); Nilson, Robert H.; Wolfe, H. Edward (ANH Refractories, Pittsburgh, PA); Yang, Nancy Y. C.; Bugeat, Benjamin () American Air Liquide, Countryside, IL); Spear, Karl E. (Pennsylvania State University, University Park, PA); Marin, Ovidiu () American Air Liquide, Countryside, IL); Ghani, M. Usman (American Air Liquide, Countryside, IL)

2005-02-01

This report summarizes the results of a five-year effort to understand the mechanisms and develop models that predict the corrosion of refractories in oxygen-fuel glass-melting furnaces. Thermodynamic data for the Si-O-(Na or K) and Al-O-(Na or K) systems are reported, allowing equilibrium calculations to be performed to evaluate corrosion of silica- and alumina-based refractories under typical furnace operating conditions. A detailed analysis of processes contributing to corrosion is also presented. Using this analysis, a model of the corrosion process was developed and used to predict corrosion rates in an actual industrial glass furnace. The rate-limiting process is most likely the transport of NaOH(gas) through the mass-transport boundary layer from the furnace atmosphere to the crown surface. Corrosion rates predicted on this basis are in better agreement with observation than those produced by any other mechanism, although the absolute values are highly sensitive to the crown temperature and the NaOH(gas) concentration at equilibrium and at the edge of the boundary layer. Finally, the project explored the development of excimer laser induced fragmentation (ELIF) fluorescence spectroscopy for the detection of gas-phase alkali hydroxides (e.g., NaOH) that are predicted to be the key species causing accelerated corrosion in these furnaces. The development of ELIF and the construction of field-portable instrumentation for glass furnace applications are reported and the method is shown to be effective in industrial settings.

Novel sintered ceramic materials incorporated with EAF carbon steel slag

Science.gov (United States)

Karayannis, V.; Ntampegliotis, K.; Lamprakopoulos, S.; Papapolymerou, G.; Spiliotis, X.

2017-01-01

In the present research, novel sintered clay-based ceramic materials containing electric arc furnace carbon steel slag (EAFC) as a useful admixture were developed and characterized. The environmentally safe management of steel industry waste by-products and their valorization as secondary resources into value-added materials towards circular economy have attracted much attention in the last years. EAF Carbon steel slag in particular, is generated during the manufacture of carbon steel. It is a solid residue mainly composed of rich-in- Fe, Ca and Si compounds. The experimental results show that the beneficial incorporation of lower percentages of EAFC up to 6%wt. into ceramics sintered at 950 °C is attained without significant variations in sintering behavior and physico-mechanical properties. Further heating up to 1100 °C strongly enhances the densification of the ceramic microstructures, thus reducing the porosity and strengthening their mechanical performance. On the other side, in terms of thermal insulation behavior as well as energy consumption savings and production cost alleviation, the optimum sintering temperature appears to be 950 °C.

Quality and energetic evaluation of the charcoal made of babassu nut residues used in the steel industry

Directory of Open Access Journals (Sweden)

Thiago de Paula Protásio

2014-10-01

Full Text Available Brazil is the only country in the world that uses large scale charcoal in steel-making blast furnaces. Meantime, the monoculture plantations of Eucalyptus are not able to meet the demand for charcoal from the steel industries.Therefore, research is necessary, in order to use lignocellulosic residues for the production of charcoal with technological properties which are suitable for the reduction of iron ore. Given the above, the objective of this study was to evaluate the quality of charcoal which was made with babassu nut shell and designed for utilization in the steel industry in the function of the final carbonization temperature. All three layers of babassu nut shell (epicarp, mesocarp and endocarp were used together. The initial temperature of the test was 100ºC and the final temperatures were: 450ºC, 550ºC, 650ºC, 750ºC and 850ºC. For the charcoals produced, the following properties were determined: apparent relative density, energy density and fixed carbon stock, in addition to chemical compositions (immediate and elemental and heating values (higher and lower. Charcoal made of babassu nut shell showed high values of apparent density and energy density, and has a potential to replace coal and wood charcoal in the steel industry. The effect of the final carbonization temperature was expressed for all characteristics evaluated, except for the nitrogen content. Babassu nut shell must be carbonized at temperatures higher than 550ºC, so that the charcoal produced can be used in steel-making blast furnaces.

System and method for air temperature control in an oxygen transport membrane based reactor

Science.gov (United States)

Kelly, Sean M

2016-09-27

A system and method for air temperature control in an oxygen transport membrane based reactor is provided. The system and method involves introducing a specific quantity of cooling air or trim air in between stages in a multistage oxygen transport membrane based reactor or furnace to maintain generally consistent surface temperatures of the oxygen transport membrane elements and associated reactors. The associated reactors may include reforming reactors, boilers or process gas heaters.

CO2 Mineralization and Utilization using Steel Slag for Establishing a Waste-to-Resource Supply Chain.

Science.gov (United States)

Pan, Shu-Yuan; Chung, Tai-Chun; Ho, Chang-Ching; Hou, Chin-Jen; Chen, Yi-Hung; Chiang, Pen-Chi

2017-12-08

Both steelmaking via an electric arc furnace and manufacturing of portland cement are energy-intensive and resource-exploiting processes, with great amounts of carbon dioxide (CO 2 ) emission and alkaline solid waste generation. In fact, most CO 2 capture and storage technologies are currently too expensive to be widely applied in industries. Moreover, proper stabilization prior to utilization of electric arc furnace slag are still challenging due to its high alkalinity, heavy metal leaching potentials and volume instability. Here we deploy an integrated approach to mineralizing flue gas CO 2 using electric arc furnace slag while utilizing the reacted product as supplementary cementitious materials to establish a waste-to-resource supply chain toward a circular economy. We found that the flue gas CO 2 was rapidly mineralized into calcite precipitates using electric arc furnace slag. The carbonated slag can be successfully utilized as green construction materials in blended cement mortar. By this modulus, the global CO 2 reduction potential using iron and steel slags was estimated to be ~138 million tons per year.