Potentiometric Surface of the Upper Floridan Aquifer in the St. Johns River Water Management District and Vicinity, Florida, May, 2004

Science.gov (United States)

Kinnaman, Sandra L.; Knowles, Leel

2004-01-01

INTRODUCTION This map depicts the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity in May 2001. Potentiometric contours are based on water-level measurements collected at 684 wells during the period May 2 - 30, near the end of the dry season. The shapes of some contours have been inferred from previous potentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate Upper Floridan aquifer responds mainly to rainfall, and more locally, to ground-water withdrawals. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground-water withdrawals locally have lowered the potentiometric surface. Ground water in the Upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours.

Potentiometric Surface of the Upper Floridan Aquifer in the St. Johns River Water Management District and Vicinity, Florida, September 2006

Science.gov (United States)

Kinnaman, Sandra L.; Dixon, Joann F.

2007-01-01

Introduction This map depicts the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity for September 2006. Potentiometric contours are based on water-level measurements collected at 571 wells during the period September 11-29, near the end of the wet season. Some contours are inferred from previouspotentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate Upper Floridan aquifer responds mainly to rainfall, and more locally, to ground-water withdrawals and spring flow. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground-water withdrawals locally have lowered the potentiometric surface. Ground water in the Upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours.

Potentiometric Surface of the Upper Floridan Aquifer in the St. Johns River Water Management District and Vicinity, Florida, May 2006

Science.gov (United States)

Kinnaman, Sandra L.

2006-01-01

Introduction: This map depicts the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity for May 2006. Potentiometric contours are based on water-level measurements collected at 599 wells during the period May 14-31, near the end of the dry season. Some contours are inferred from previous potentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate Upper Floridan aquifer responds mainly to rainfall, and more locally, to ground-water withdrawals and springflow. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground-water withdrawals locally have lowered the potentiometric surface. Ground water in the Upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours.

Potential for formation of disinfection by-products from storage of chlorinated surface water in the Basalt aquifer near Fallon, Nevada

Science.gov (United States)

Fram, Miranda S.; Maurer, Douglas K.; Lico, Michael S.

2005-01-01

Increased pumpage from a basalt aquifer near Fallon, Nevada, has caused its water levels to decline and has induced changes in the quality of water pumped from the basalt. The aquifer is the sole source of water for municipal supply to the city of Fallon, the Naval Air Station Fallon, and the Fallon Paiute-Shoshone Tribe. These changes may be mitigated by storage of surface water in the basalt for subsequent use. Because chlorination of the surface water may be required for storage, the U.S. Geological Survey, in cooperation with the Fallon Paiute-Shoshone Tribe, made laboratory tests using laboratory carbon-organic-free water, surface-water, ground-water, and basaltic-rock samples to determine the potential for formation of disinfection by-products. Experiments with water samples only (no rock and no chlorine) indicated no change in dissolved-organic-carbon (DOC) concentrations over a 20-day reaction period; whereas, all experiments using rock, water, and no chlorine indicated an increase in DOC concentrations. The greatest increase in DOC concentrations for all three water samples occurred in experiments with the rock samples from outcrops on Rattlesnake Hill. Experiments with water only and chlorine yielded a total trihalomethane (THM) concentration of 97.4 ?g/L for the ground-water sample and 347 ?g/L for the surface-water sample. Experiments with mixtures of water, rocks, and chlorine indicated that reactions with the rock consumed chlorine and released significant amounts of organic carbon from the rock, increasing the DOC concentration in the water. The organic carbon in the rocks likely is associated with the secondary clay minerals that line vesicles and fractures in the rocks. THM concentrations were greatest, from 335 to 909 ?g/L, for surface water equilibrated with rock samples from Rattlesnake Hill. However, the concentration of chlorine required to produce these high THM concentrations ranged from 18 to 84 mg/L. The results of the experiments suggest

Surface complexation modeling of groundwater arsenic mobility: Results of a forced gradient experiment in a Red River flood plain aquifer, Vietnam

DEFF Research Database (Denmark)

Jessen, Søren; Postma, Dieke; Larsen, Flemming

2012-01-01

, suggesting a comparable As(III) affinity of Holocene and Pleistocene aquifer sediments. A forced gradient field experiment was conducted in a bank aquifer adjacent to a tributary channel to the Red River, and the passage in the aquifer of mixed groundwater containing up to 74% channel water was observed......Three surface complexation models (SCMs) developed for, respectively, ferrihydrite, goethite and sorption data for a Pleistocene oxidized aquifer sediment from Bangladesh were used to explore the effect of multicomponent adsorption processes on As mobility in a reduced Holocene floodplain aquifer......(III) while PO43− and Fe(II) form the predominant surface species. The SCM for Pleistocene aquifer sediment resembles most the goethite SCM but shows more Si sorption. Compiled As(III) adsorption data for Holocene sediment was also well described by the SCM determined for Pleistocene aquifer sediment...

Potentiometric surface of the upper Floridan aquifer, west-central Florida, May 2011

Science.gov (United States)

Ortiz, Anita G.

2011-01-01

The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing freshwater are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in May 2011. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the dry season, when groundwater levels usually are at an annual low and withdrawals for agricultural use typically are high. The cumulative average rainfall of 45.74 inches for west-central Florida (from June 2010 through May 2011) was 6.85 inches below the historical cumulative average of 52.59 inches (Southwest Florida Water Management District, 2011). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September from 1975 through 2010. Water-level data are collected in May and September each year to

Elevated naturally occurring arsenic in a semiarid oxidizing system, Southern High Plains aquifer, Texas, USA

Science.gov (United States)

Scanlon, Bridget R.; Nicot, J.-P.; Reedy, R.C.; Kurtzman, D.; Mukherjee, A.; Nordstrom, D. Kirk

2009-01-01

Triassic Dockum aquifer. Mobilization of As in other semiarid oxidizing systems is caused by increased pH; however, pH in the SHP aquifer is near neutral (10–90 percentiles, 7.0–7.6). Although many processes, such as competitive desorption with SiO2, VO4, or PO4, could be responsible for local mobilization of As in the SHP aquifer, the most plausible explanation for the regional As distribution and correlation with TDS is the counterion effect caused by a change from Ca- to Na-rich, water as shown by the high correlation between As and Na/(Ca)0.5 ratios (ρ = 0.57). This change in chemistry is related to mixing with saline water that moves upward from the underlying Dockum aquifer. This counterion effect may mobilize other anions and oxyanion-forming elements that are correlated with As (F, V, Se, B, Mo and SiO2). Competition among the oxyanions for sorption sites may enhance As mobilization. The SHP case study has similar As sources to those of other semiarid, oxidizing systems (original volcanic ash source followed by sorption onto hydrous metal oxides) but contrasts with these systems by showing lack of evaporative concentration and pH mobilization of As but counterion mobilization of As instead in the SHP-S aquifer.

Potentiometric Surface of the Upper Floridan Aquifer, West-Central Florida, September 2006

Science.gov (United States)

Ortiz, A.G.

2007-01-01

The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing freshwater are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in September 2006. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the wet season, when ground-water levels usually are at an annual high and withdrawals for agricultural use typically are low. The cumulative average rainfall of 46.06 inches for west-central Florida (from October 2005 through September 2006) was 6.91 inches below the historical cumulative average of 52.97 inches (Southwest Florida Water Management District, 2006). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each

Potentiometric Surface of the Upper Floridan Aquifer, West-Central Florida, September 2007

Science.gov (United States)

Ortiz, A.G.

2008-01-01

The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing fresh water are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in September 2007. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the wet season, when ground-water levels usually are at an annual high and withdrawals for agricultural use typically are low. The cumulative average rainfall of 39.50 inches for west-central Florida (from October 2006 through September 2007) was 13.42 inches below the historical cumulative average of 52.92 inches (Southwest Florida Water Management District, 2007). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each

Potentiometric surface of the Upper Floridan aquifer, west-central Florida, September 2005

Science.gov (United States)

Ortiz, A.G.

2006-01-01

The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing freshwater are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public-supply, domestic use, irrigation, and brackish-water desalination in coastal communities (Southwest Florida Water Management District, 2000).This map report shows the potentiometric surface of the Upper Floridan aquifer measured in September 2005. The potentiometric surface is an imaginary surface, connecting points of equal altitude to which water will rise in tightly cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the wet season, when ground-water levels usually are at an annual high and withdrawals for agricultural use typically are low. The cumulative average rainfall of 55.19 inches for west-central Florida (from October 2004 through September 2005) was 2.00 inches above the historical cumulative average of 53.19 inches (Southwest Florida Water Management District, 2005). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District.This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year

Potentiometric Surface of the Upper Floridan Aquifer, West-Central Florida, May 2007

Science.gov (United States)

Ortiz, A.G.

2008-01-01

The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing fresh water are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in May 2007. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the dry season, when ground-water levels usually are at an annual low and withdrawals for agricultural use typically are high. The cumulative average rainfall of 41.21 inches for west-central Florida (from June 2006 through May 2007) was 11.63 inches below the historical cumulative average of 52.84 inches (Southwest Florida Water Management District, 2007). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year to show the

Uranium-isotope variations in groundwaters of the Floridan aquifer and boulder zone of South Florida

International Nuclear Information System (INIS)

Cowart, J.B.; Osmond, J.K.

1978-01-01

Water samples from four wells from the main Floridan aquifer (300-400 m below mean sea level) in southeast Florida exhibit 234 U/ 238 U activity ratios that are significantly lower than the secular equilibrium value of 1.00. Such anomalous values have been observed previously only in waters from sedimentary aquifers in the near-surface oxidizing environments. These four wells differ from six others, all producing from the same general horizon, in being located in cavernous highly transmissive zones

Impact of pH on hydrogen oxidizing redox processes in aquifers due to gas intrusions

Science.gov (United States)

Metzgen, Adrian; Berta, Marton; Dethlefsen, Frank; Ebert, Markus; Dahmke, Andreas

2017-04-01

Hydrogen production from excess energy and its storage can help increasing the efficiency of solar and wind in the energy mix. Therefore, hydrogen needs large-scale intermediate storage independent of the intended later use as hydrogen gas or as reactant to produce methane in the Sabatier process. A possible storage solution is using the geological subsurface such as caverns built in salt deposits or aquifers that are not used for drinking water production. However, underground storage of hydrogen gas potentially leads to accidental gas leakages into near-surface potable aquifers triggering subsequent geochemical processes. These leakages pose potential risks that are currently not sufficiently understood. To close this gap in knowledge, a high-pressure laboratory column system was used to simulate a hydrogen gas intrusion into a shallow aquifer. Water and sediment were gained from a sandy Pleistocene aquifer near Neumünster, Germany. In the first stage of the experiment, 100% hydrogen gas was used to simulate dissolved hydrogen concentrations between 800 and 4000 µM by varying pH2 between 2 and 15 bars. pH values rose to between 7.9 and 10.4, partly due to stripping CO2 from the groundwater used during H2 gas addition. In a second stage, the pH was regulated in a range of 6.7 to 7.9 by using a gas mixture of 99% H2 and 1% CO2 at 5 bars of total gas pressure. Observed processes included hydrogen oxidation, sulfate reduction, acetogenesis, formate production, and methanogenesis, which were independent of the hydrogen concentration. Hydrogen oxidation and sulfate reduction showed zeroth order reaction rates and rate constants (106 to 412 µM/h and 12 to 33 µM/h, respectively) in the pH range between 8 and 10. At pH levels between 7 and 8, both reactions started out faster near the column's inflow but then seemed limited towards the columns outflow, suggesting the dependence of sulfate reduction on the pH-value. Acetogenesis dominated the pH range between 8 and 10

Analysis of flow near a dug well in an unconfined aquifer

Science.gov (United States)

Sridharan, K.; Sathyanarayana, D.; Reddy, A. Siva

1990-11-01

A numerical analysis of flow to a dug well in an unconfined aquifer is made, taking into account well storage, elastic storage release, gravity drainage, anisotropy, partial penetration, vertical flow and seepage surface at the well face, and treating the water table in the aquifer and water level in the well as unknown boundaries. The pumped discharge is maintained constant. The solution is obtained by a two-level iterative scheme. The effects of governing parameters on the drawdown, development of seepage surface and contribution from aquifer flow to the total discharge are discussed. The degree of anisotropy and partial penetration are found to be the parameters which affect the flow characteristics most significantly. The effect of anisotropy on the development of seepage surface is very pronounced.

Potentiometric Surface of the Upper Floridan Aquifer in the St. Johns River Water Management District and Vicinity, Florida, May 2007

Science.gov (United States)

Kinnaman, Sandra L.; Dixon, Joann F.

2007-01-01

Introduction This map depicts the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity for May 2007. Potentiometric contours are based on water-level measurements collected at 566 wells during the period May 4-June 11 near the end of the dry season, however most of the water level data for this map were collected by the U.S. Geological Survey during the period May 21-25, 2007. Some contours are inferred from previous potentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate Upper Floridan aquifer responds mainly to rainfall, and more locally, to ground-water withdrawals and spring flow. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground-water withdrawals locally have lowered the potentiometric surface. Ground water in the Upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours.

Aquifer test at well SMW-1 near Moenkopi, Arizona

Science.gov (United States)

Carruth, Rob; Bills, Donald J.

2012-01-01

The Hopi villages of Lower Moencopi and Upper Moenkopi are on the Hopi Indian Reservation south of Tuba City in northern Arizona. These adjacent Hopi villages, located west and north of the confluence of Pasture Canyon Wash and Moenkopi Wash, are dependent on groundwater withdrawals from three wells that penetrate the N aquifer and from two springs that discharge from the N aquifer. The N aquifer is the principal aquifer in this region of northern Arizona and is composed of thick beds of sandstone between less permeable layers of siltstone and mudstone. The fine-grained character of the N aquifer inhibits rapid movement of water and large yields to wells; however, the aquifer is moderately productive at yields generally less than 25 gallons per minute in the study area. In recent years, the water level has declined in the three public-supply wells and the flow from the springs has decreased, causing concern that the current water supply will not be able to accommodate peak demand and allow for residential and economic growth. In addition to the challenge imposed by declining groundwater levels, the water-supply wells and springs are located about 2 miles downgradient from the Tuba City Landfill site where studies are ongoing to determine if uranium and other metals in groundwater beneath the landfill are higher than regional concentrations in the N aquifer. In August 2008, the U.S. Geological Survey, in cooperation with the Hopi Tribe, conducted an aquifer test on well SMW-1, designed to help the Hopi Tribe determine the potential yield and water quality of the N aquifer south of Moenkopi Wash as a possible source of additional water supply. Well SMW-1 was drilled south of Moenkopi Wash to a depth of 760 feet below land surface before being backfilled and cased to about 300 feet. The well penetrates, in descending order, the Navajo Sandstone and the Kayenta Formation, both units of the N aquifer. The pre-test water level in the well was 99.15 feet below land

The Difference Between the Potentiometric Surfaces of the Magothy Aquifer in Southern Maryland, September 1975 and September 2007

Science.gov (United States)

Curtin, Stephen E.; Andreasen, David C.; Staley, Andrew W.

2009-01-01

This report presents a map showing the change in the potentiometric surface of the Magothy aquifer in the Magothy Formation of Late Cretaceous age in Southern Maryland for September 1975 and September 2007. The map, based on water-level measurements in 51 wells, shows that during the 32-year period, the potentiometric surface had no change at the outcrop area, which is in the northernmost part of the study area, but declined 90 feet at Waldorf. Waldorf is located near the southwesternmost part of the study area, and approaches the downdip boundary of the aquifer.

Connectivity to the surface determines diversity patterns in subsurface aquifers of the Fennoscandian shield.

Science.gov (United States)

Hubalek, Valerie; Wu, Xiaofen; Eiler, Alexander; Buck, Moritz; Heim, Christine; Dopson, Mark; Bertilsson, Stefan; Ionescu, Danny

2016-10-01

Little research has been conducted on microbial diversity deep under the Earth's surface. In this study, the microbial communities of three deep terrestrial subsurface aquifers were investigated. Temporal community data over 6 years revealed that the phylogenetic structure and community dynamics were highly dependent on the degree of isolation from the earth surface biomes. The microbial community at the shallow site was the most dynamic and was dominated by the sulfur-oxidizing genera Sulfurovum or Sulfurimonas at all-time points. The microbial community in the meteoric water filled intermediate aquifer (water turnover approximately every 5 years) was less variable and was dominated by candidate phylum OD1. Metagenomic analysis of this water demonstrated the occurrence of key genes for nitrogen and carbon fixation, sulfate reduction, sulfide oxidation and fermentation. The deepest water mass (5000 year old waters) had the lowest taxon richness and surprisingly contained Cyanobacteria. The high relative abundance of phylogenetic groups associated with nitrogen and sulfur cycling, as well as fermentation implied that these processes were important in these systems. We conclude that the microbial community patterns appear to be shaped by the availability of energy and nutrient sources via connectivity to the surface or from deep geological processes.

Data-driven exploration of copper mineralogy and its application to Earth's near-surface oxidation

Science.gov (United States)

Morrison, S. M.; Eleish, A.; Runyon, S.; Prabhu, A.; Fox, P. A.; Ralph, J.; Golden, J. J.; Downs, R. T.; Liu, C.; Meyer, M.; Hazen, R. M.

2017-12-01

Earth's atmospheric composition has changed radically throughout geologic history.1,2 The oxidation of our atmosphere, driven by biology, began with the Great Oxidation Event (GOE) 2.5 Ga and has heavily influenced Earth's near surface mineralogy. Therefore, temporal trends in mineral occurrence elucidate large and small scale geologic and biologic processes. Cu, and other first-row transition elements, are of particular interest due to their variation in valance state and sensitivity to ƒO2. Widespread formation of oxidized Cu mineral species (Cu2+) would not have been possible prior to the GOE and we have found that the proportion of oxidized Cu minerals increased steadily with the increase in atmospheric O2 on Earth's surface (see Fig. 1). To better characterize the changes in Cu mineralogy through time, we have employed advanced analytical and visualization methods. These techniques rely on large and growing mineral databases (e.g., rruff.info, mindat.org, earthchem.org, usgs.gov) and allow us to quantify and visualize multi-dimensional trends.5

Potentiometric surface of the Upper Patapsco aquifer in southern Maryland, September 2009

Science.gov (United States)

Curtin, Stephen E.; Andreasen, David C.; Staley, Andrew W.

2010-01-01

This report presents a map showing the potentiometric surface of the upper Patapsco aquifer in the Patapsco Formation of Early Cretaceous age in Southern Maryland during September 2009. The map is based on water-level measurements in 65 wells. The highest measured water level was 118 feet above sea level near the northern boundary and outcrop area of the aquifer in northern Anne Arundel County. From this area, the potentiometric surface declined to the south toward a well field in the Annapolis-Arnold area, and from all directions toward three additional cones of depression. These cones are located in the Waldorf-La Plata area, Chalk Point, and the Leonardtown-Lexington Park area. The lowest measured groundwater levels were 26 feet below sea level at Annapolis, 108 feet below sea level south of Waldorf, 60 feet below sea level at Chalk Point, and 83 feet below sea level at Leonardtown. The map also shows well yield in gallons per day for 2008 at wells or well fields.

Surface complexation modeling of groundwater arsenic mobility: Results of a forced gradient experiment in a Red River flood plain aquifer, Vietnam

Science.gov (United States)

Jessen, Søren; Postma, Dieke; Larsen, Flemming; Nhan, Pham Quy; Hoa, Le Quynh; Trang, Pham Thi Kim; Long, Tran Vu; Viet, Pham Hung; Jakobsen, Rasmus

2012-12-01

Three surface complexation models (SCMs) developed for, respectively, ferrihydrite, goethite and sorption data for a Pleistocene oxidized aquifer sediment from Bangladesh were used to explore the effect of multicomponent adsorption processes on As mobility in a reduced Holocene floodplain aquifer along the Red River, Vietnam. The SCMs for ferrihydrite and goethite yielded very different results. The ferrihydrite SCM favors As(III) over As(V) and has carbonate and silica species as the main competitors for surface sites. In contrast, the goethite SCM has a greater affinity for As(V) over As(III) while PO43- and Fe(II) form the predominant surface species. The SCM for Pleistocene aquifer sediment resembles most the goethite SCM but shows more Si sorption. Compiled As(III) adsorption data for Holocene sediment was also well described by the SCM determined for Pleistocene aquifer sediment, suggesting a comparable As(III) affinity of Holocene and Pleistocene aquifer sediments. A forced gradient field experiment was conducted in a bank aquifer adjacent to a tributary channel to the Red River, and the passage in the aquifer of mixed groundwater containing up to 74% channel water was observed. The concentrations of As (SCM correctly predicts desorption for As(III) but for Si and PO43- it predicts an increased adsorption instead of desorption. The goethite SCM correctly predicts desorption of both As(III) and PO43- but failed in the prediction of Si desorption. These results indicate that the prediction of As mobility, by using SCMs for synthetic Fe-oxides, will be strongly dependent on the model chosen. The SCM based on the Pleistocene aquifer sediment predicts the desorption of As(III), PO43- and Si quite superiorly, as compared to the SCMs for ferrihydrite and goethite, even though Si desorption is still somewhat under-predicted. The observation that a SCM calibrated on a different sediment can predict our field results so well suggests that sediment based SCMs may be a

Hydrogeology and water quality of the Nanticoke Creek stratified-drift aquifer, near Endicott, New York

Science.gov (United States)

Kreitinger, Elizabeth A.; Kappel, William M.

2014-01-01

The Village of Endicott, New York, is seeking an alternate source of public drinking water with the potential to supplement their current supply, which requires treatment due to legacy contamination. The southerly-draining Nanticoke Creek valley, located north of the village, was identified as a potential water source and the local stratified-drift (valley fill) aquifer was investigated to determine its hydrogeologic and water-quality characteristics. Nanticoke Creek and its aquifer extend from the hamlet of Glen Aubrey, N.Y., to the village of Endicott, a distance of about 15 miles, where it joins the Susquehanna River and its aquifer. The glacial sediments that comprise the stratified-drift aquifer vary in thickness and are generally underlain by glacial till over Devonian-aged shale and siltstone. Groundwater is more plentiful in the northern part of the aquifer where sand and gravel deposits are generally more permeable than in the southern part of the aquifer where less-permeable unconsolidated deposits are found. Generally there is enough groundwater to supply most homeowner wells and in some cases, supply small public-water systems such as schools, mobile-home parks, and small commercial/industrial facilities. The aquifer is recharged by precipitation, runoff, and tributary streams. Most tributary streams flowing across alluvial deposits lose water to the aquifer as they flow off of their bedrock-lined channels and into the more permeable alluvial deposits at the edges of the valley. The quality of both surface water and groundwater is generally good. Some water wells do have water-quality issues related to natural constituents (manganese and iron) and several homeowners noted either the smell and (or) taste of hydrogen sulfide in their drinking water. Dissolved methane concentrations from five drinking-water wells were well below the potentially explosive value of 28 milligrams per liter. Samples from surface and groundwater met nearly all State and Federal

Technetium getters in the near surface environment

International Nuclear Information System (INIS)

Krumhansl, James L.; Zhang, Pengchu; Westrich, Henry R.; Bryan, Charles R.; Molecke, Martin A.

2000-01-01

Conventional performance assessments assume that radioactive 99 Tc travels as a non-sorbing component with an effective K d (distribution coefficient) of 0. This is because soil mineral surfaces commonly develop net negative surface charges and pertechnetate (TcO 4 ), with large ionic size and low electrical density, is not sorbed onto them. However, a variety of materials have been identified that retain Tc and may eventually lead to promising Tc getters. In assessing Tc getter performance it is important to evaluate the environment in which the getter is to function. In many contaminant plumes Tc will only leach slowly from the source of the contamination and significant dilution is likely. Thus, sub-ppb Tc concentrations are expected and normal groundwater constituents will dominate the aquifer chemistry. In this setting a variety of constituents were found to retard TcO 4 : imogolite, boehmite, hydrotalcite, goethite, copper sulfide and oxide and coal. Near leaking tanks of high level nuclear waste, Tc may be present in mg/L level concentrations and groundwater chemistry will be dominated by constituents from the waste. Both bone char, and to a lesser degree, freshly precipitated Al hydroxides may be effective Tc scavengers in this environment. Thus, the search for Tc getters is far from hopeless, although much remains to be learned about the mechanisms by which these materials retain Tc

Potentiometric Surface of the Upper Floridan Aquifer in the St. Johns River Water Management District and Vicinity, May 2008

Science.gov (United States)

Kinnaman, Sandra L.; Dixon, Joann F.

2008-01-01

This map depicts the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity for May 2008. Potentiometric contours are based on water-level measurements collected at 567 wells during the period May 6-May 27, near the end of the dry season. Some contours are inferred from previous potentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate Upper Floridan aquifer responds mainly to rainfall, and more locally, to ground-water withdrawals and spring flow. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground-water withdrawals locally have lowered the potentiometric surface. Ground water in the Upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours. Measured values of the potentiometric surface ranged from 7 feet below NGVD29 near Fernandina Beach, Florida, to 124 feet above NGVD29 in Polk County, Florida. The average water level of the network in May 2008 was about 1 foot lower than the average in September 2007 following below-average rainfall during the dry season of 2007-08. Seasonal differences in network average water levels generally range from 4 to 6 feet. For 457 wells with previous measurements, May 2008 levels ranged from about 19 feet below to about 11 feet above September 2007 water levels. The average water level of the network in May 2008 was about 1 foot higher than the average in May 2007. For 544 wells with previous measurements, May 2008 levels ranged from about 8 feet below to about 13 feet above May 2007 water levels. Long-term hydrographs of ground-water levels for continuous and periodic wells are available

Three-dimensional chemical structure of the INEL aquifer system near the Idaho Chemical Processing Plant

International Nuclear Information System (INIS)

McCurry, M.; Estes, M.; Fromm, J.; Welhan, J.; Barrash, W.

1994-01-01

Sampling and analysis from the Snake River Plain aquifer using a stainless-steel and teflon constructed straddle-packer system has established detailed vertical profiles of aquifer chemistry from three wells near a major source of low-level waste injection at the Idaho Chemical Processing Plant. Multiple intervals, varying from 4.6 to 6.1 m in length, were sampled between the water table (140.5 mbls - meters below land surface), and approximately 200 mbls to obtain a wide spectrum of metals, anions, radiological and organic components analyses. Measurements were also made at the well sites of important transient parameters (T, Eh, Fe 3+ , Fe 2+ , DO and SC). The principal purpose of this ongoing work is to improve our understanding of the third (i.e. vertical) dimension of aquifer chemistry at the INEL as a basis for critically evaluating site-wide monitoring procedures, and, ultimately, for improving fate and transport models for aquifer contaminants within basalt-hosted aquifers. Chemical and radiological data indicates that substantial systematic vertical and lateral variations occur in the aquifer hydrochemistry - in particular for conservative radiological nuclide concentrations. Radiological data define a three-layered zonation. Ground water within upper and lower zones contain up to 10 times higher concentrations of H-3 and I-129 than in the middle zone. Sr-90 activity is decoupled from H-3 and I-129-relatively high activity was detected within the upper zone nearest the ICPP, but activities elsewhere are very low. 27 refs., 4 figs., 1 tab

Groundwater and surface-water interactions near White Bear Lake, Minnesota, through 2011

Science.gov (United States)

Jones, Perry M.; Trost, Jared J.; Rosenberry, Donald O.; Jackson, P. Ryan; Bode, Jenifer A.; O'Grady, Ryan M.

2013-01-01

The U.S. Geological Survey, in cooperation with the White Bear Lake Conservation District, the Minnesota Pollution Control Agency, the Minnesota Department of Natural Resources, and other State, county, municipal, and regional planning agencies, watershed organizations, and private organizations, conducted a study to characterize groundwater and surface-water interactions near White Bear Lake through 2011. During 2010 and 2011, White Bear Lake and other lakes in the northeastern part of the Twin Cities Metropolitan Area were at historically low levels. Previous periods of lower water levels in White Bear Lake correlate with periods of lower precipitation; however, recent urban expansion and increased pumping from the Prairie du Chien-Jordan aquifer have raised the question of whether a decline in precipitation is the primary cause for the recent water-level decline in White Bear Lake. Understanding and quantifying the amount of groundwater inflow to a lake and water discharge from a lake to aquifers is commonly difficult but is important in the management of lake levels. Three methods were used in the study to assess groundwater and surface-water interactions on White Bear Lake: (1) a historical assessment (1978-2011) of levels in White Bear Lake, local groundwater levels, and their relation to historical precipitation and groundwater withdrawals in the White Bear Lake area; (2) recent (2010-11) hydrologic and water-quality data collected from White Bear Lake, other lakes, and wells; and (3) water-balance assessments for White Bear Lake in March and August 2011. An analysis of covariance between average annual lake-level change and annual precipitation indicated the relation between the two variables was significantly different from 2003 through 2011 compared with 1978 through 2002, requiring an average of 4 more inches of precipitation per year to maintain the lake level. This shift in the linear relation between annual lake-level change and annual precipitation

Potentiometric Surface of the Lower Patapsco Aquifer in Southern Maryland, September 2007

Science.gov (United States)

Curtin, Stephen E.; Andreasen, David C.; Staley, Andrew W.

2009-01-01

This report presents a map showing the potentiometric surface of the lower Patapsco aquifer in the Patapsco Formation of Early Cretaceous age in Southern Maryland during September 2007. The map is based on water-level measurements in 65 wells. The highest measured water level was 111 feet above sea level near the northwestern boundary and outcrop area of the aquifer in northern Prince George's County. From this area, the potentiometric surface declined towards well fields at Severndale and Arnold. The measured ground-water levels were 87 feet below sea level at Severndale, and 42 feet below sea level at Arnold. There was also a cone of depression covering a large area in Charles County that includes Waldorf, La Plata, Indian Head, and the Morgantown power plant. The ground-water levels measured were as low as 219 feet below sea level at Waldorf, 187 feet below sea level at La Plata, 106 feet below sea level at Indian Head, and 89 feet below sea level at the Morgantown power plant.

Potentiometric Surface of the Upper Patapsco Aquifer in Southern Maryland, September 2007

Science.gov (United States)

Curtin, Stephen E.; Andreasen, David C.; Staley, Andrew W.

2009-01-01

This report presents a map showing the potentiometric surface of the upper Patapsco aquifer in the Patapsco Formation of Early Cretaceous age in Southern Maryland during September 2007. The map is based on water-level measurements in 50 wells. The highest measured water level was 120 feet above sea level near the northern boundary and outcrop area of the aquifer in northern Anne Arundel County. From this area, the potentiometric surface declined to the south toward a well field in the Annapolis-Arnold area, and from all directions toward four cones of depression. These cones are located in the Waldorf-La Plata area, Chalk Point-Prince Frederick area, Swan Point subdivision in southern Charles County, and the Lexington Park-St. Inigoes area. The lowest measured ground-water level was 44 feet below sea level at Arnold, 106 feet below sea level south of Waldorf, 54 feet below sea level at Swan Point, 59 feet below sea level at Chalk Point, and 58 feet below sea level at Lexington Park.

Model-based analysis of δ34S signatures to trace sedimentary pyrite oxidation during managed aquifer recharge in a heterogeneous aquifer

Science.gov (United States)

Seibert, Simone; Descourvieres, Carlos; Skrzypek, Grzegorz; Deng, Hailin; Prommer, Henning

2017-05-01

The oxidation of pyrite is often one of the main drivers affecting groundwater quality during managed aquifer recharge in deep aquifers. Data and techniques that allow detailed identification and quantification of pyrite oxidation are therefore crucial for assessing and predicting the adverse water quality changes that may be associated with this process. In this study, we explore the benefits of combining stable sulphur isotope analysis with reactive transport modelling to improve the identification and characterisation of pyrite oxidation during an aquifer storage and recovery experiment in a chemically and physically heterogeneous aquifer. We characterise the stable sulphur isotope signal (δ34S) in both the ambient groundwater and the injectant as well as its spatial distribution within the sedimentary sulphur species. The identified stable sulphur isotope signal for pyrite was found to vary between -32 and +34‰, while the signal of the injectant ranged between +9.06 and +14.45‰ during the injection phase of the experiment. Both isotope and hydrochemical data together suggest a substantial contribution of pyrite oxidation to the observed, temporally variable δ34S signals. The variability of the δ34S signal in pyrite and the injectant were both found to complicate the analysis of the stable isotope data. However, the incorporation of the data into a numerical modelling approach allowed to successfully employ the δ34S signatures as a valuable additional constraint for identifying and quantifying the contribution of pyrite oxidation to the redox transformations that occur in response to the injection of oxygenated water.

Bacterial diversity and community structure of a sub-surface aquifer exposed to realistic low herbicide concentrations

DEFF Research Database (Denmark)

Lipthay, Julia R. de; Johnsen, Kaare; Albrechtsen, H.-J.

2004-01-01

contaminants. We examined the effect of in situ exposure to realistic low concentrations of herbicides on the microbial diversity and community structure of sub-surface sediments from a shallow aquifer near Vejen (Denmark). Three different community analyses were performed: colony morphology typing, sole...... community analyses. In contrast, no significant effect was found on the bacterial diversity, except for the culturable fraction where a significantly increased richness and Shannon index was found in the herbicide acclimated sediments. The results of this study show that in situ exposure of sub-surface...... aquifers to realistic low concentrations of herbicides may alter the overall structure of a natural bacterial community, although significant effects on the genetic diversity and carbon substrate usage cannot be detected. The observed impact was probably due to indirect effects. In future investigations...

Recovery of energetically overexploited urban aquifers using surface water

Science.gov (United States)

García-Gil, Alejandro; Vázquez-Suñé, Enric; Sánchez-Navarro, José Ángel; Mateo Lázaro, Jesús

2015-12-01

Shallow aquifers have an important role in reducing greenhouse gases through helping manage the temperature of urban environments. Nevertheless, the uncontrolled rapid use of shallow groundwater resources to heat or cool urban environments can cause thermal pollution that will limit the long term sustainability of the resource. Therefore, there is a need for appropriate mitigation/remediation strategies capable of recovering energetically overexploited aquifers. In this work, a novel remediation strategy based on surface water recharge into aquifers is presented. To evaluate the capabilities of such measures for effective remediation, this strategy is optimized for a management problem raised in the overheated "Urban Alluvial Aquifer of Zaragoza" (Spain). The application of a transient groundwater flow and heat transport model under 512 different mitigation scenarios has enabled to quantify and discuss the magnitude of the remediation effect as a respond to injection rates of surface water, seasonal schedule of the injection and location of injection. The quantification of the relationship between these variables together with the evaluation of the amount of surface water injected per year in each scenario proposed have provided a better understanding of the system processes and an optimal management alternative. This work also makes awareness of the magnitude of the remediation procedure which is in an order of magnitude of tenths of years.

The Difference Between the Potentiometric Surfaces of the Magothy Aquifer in Southern Maryland, September 1975 and September 2009

Science.gov (United States)

Curtin, Stephen E.; Andreasen, David C.; Staley, Andrew W.

2010-01-01

This report presents a map showing the change in the potentiometric surface of the Magothy aquifer in the Magothy Formation of Late Cretaceous age in Southern Maryland between September 1975 and September 2009. The map, based on water level differences obtained from 48 wells, shows that during the 34-year period, the potentiometric surface had little change at the outcrop area, which is in the northernmost part of the study area, but declined 75 feet at Waldorf. Waldorf is located near the southwesternmost part of the study area, and approaches the downdip boundary of the aquifer. The map also shows well yield in gallons per day for 2008 at wells or well fields.

Oxidation of naturally reduced uranium in aquifer sediments by dissolved oxygen and its potential significance to uranium plume persistence

Science.gov (United States)

Davis, J. A.; Smith, R. L.; Bohlke, J. K.; Jemison, N.; Xiang, H.; Repert, D. A.; Yuan, X.; Williams, K. H.

2015-12-01

The occurrence of naturally reduced zones is common in alluvial aquifers in the western U.S.A. due to the burial of woody debris in flood plains. Such reduced zones are usually heterogeneously dispersed in these aquifers and characterized by high concentrations of organic carbon, reduced mineral phases, and reduced forms of metals, including uranium(IV). The persistence of high concentrations of dissolved uranium(VI) at uranium-contaminated aquifers on the Colorado Plateau has been attributed to slow oxidation of insoluble uranium(IV) mineral phases found in association with these reducing zones, although there is little understanding of the relative importance of various potential oxidants. Four field experiments were conducted within an alluvial aquifer adjacent to the Colorado River near Rifle, CO, wherein groundwater associated with the naturally reduced zones was pumped into a gas-impermeable tank, mixed with a conservative tracer (Br-), bubbled with a gas phase composed of 97% O2 and 3% CO2, and then returned to the subsurface in the same well from which it was withdrawn. Within minutes of re-injection of the oxygenated groundwater, dissolved uranium(VI) concentrations increased from less than 1 μM to greater than 2.5 μM, demonstrating that oxygen can be an important oxidant for uranium in such field systems if supplied to the naturally reduced zones. Dissolved Fe(II) concentrations decreased to the detection limit, but increases in sulfate could not be detected due to high background concentrations. Changes in nitrogen species concentrations were variable. The results contrast with other laboratory and field results in which oxygen was introduced to systems containing high concentrations of mackinawite (FeS), rather than the more crystalline iron sulfides found in aged, naturally reduced zones. The flux of oxygen to the naturally reduced zones in the alluvial aquifers occurs mainly through interactions between groundwater and gas phases at the water table

Arsenic control during aquifer storage recovery cycle tests in the Floridan Aquifer.

Science.gov (United States)

Mirecki, June E; Bennett, Michael W; López-Baláez, Marie C

2013-01-01

Implementation of aquifer storage recovery (ASR) for water resource management in Florida is impeded by arsenic mobilization. Arsenic, released by pyrite oxidation during the recharge phase, sometimes results in groundwater concentrations that exceed the 10 µg/L criterion defined in the Safe Drinking Water Act. ASR was proposed as a major storage component for the Comprehensive Everglades Restoration Plan (CERP), in which excess surface water is stored during the wet season, and then distributed during the dry season for ecosystem restoration. To evaluate ASR system performance for CERP goals, three cycle tests were conducted, with extensive water-quality monitoring in the Upper Floridan Aquifer (UFA) at the Kissimmee River ASR (KRASR) pilot system. During each cycle test, redox evolution from sub-oxic to sulfate-reducing conditions occurs in the UFA storage zone, as indicated by decreasing Fe(2+) /H2 S mass ratios. Arsenic, released by pyrite oxidation during recharge, is sequestered during storage and recovery by co-precipitation with iron sulfide. Mineral saturation indices indicate that amorphous iron oxide (a sorption surface for arsenic) is stable only during oxic and sub-oxic conditions of the recharge phase, but iron sulfide (which co-precipitates arsenic) is stable during the sulfate-reducing conditions of the storage and recovery phases. Resultant arsenic concentrations in recovered water are below the 10 µg/L regulatory criterion during cycle tests 2 and 3. The arsenic sequestration process is appropriate for other ASR systems that recharge treated surface water into a sulfate-reducing aquifer. Published 2012. This article is a U.S. Government work and is in the public domain in the USA.

Site specificity of biosphere parameter values in performance assessments of near-surface repositories

International Nuclear Information System (INIS)

Zeevaert, Th.; Volckaert, G.; Vandecasleele

1993-01-01

The contribution is dealing with the performance assessment model for near surface repositories in Belgium. It consists of four submodels called: site, aquifer, biosphere and dose. For some characteristic radionuclides, results of the study are shown for a typical site, and differences in doses assessed with the generic approach discussed. Shortcomings are indicated

Potentiometric Surface of the Lower Patapsco Aquifer in Southern Maryland, September 2009

Science.gov (United States)

Curtin, Stephen E.; Andreasin, David C.; Staley, Andrew W.

2010-01-01

This report presents a map showing the potentiometric surface of the lower Patapsco aquifer in the Patapsco Formation of Early Cretaceous age in Southern Maryland during September 2009. The map is based on water-level measurements in 64 wells. The highest measured water level was 110 feet above sea level near the northwestern boundary and outcrop area of the aquifer in northern Prince George's County. From this area, the potentiometric surface declined towards well fields at Severndale, Broad Creek, and Arnold. The measured groundwater levels were 99 feet below sea level at Severndale, 50 feet below sea level at Broad Creek, and 36 feet below sea level at Arnold. There was also a cone of depression in Charles County that includes Waldorf, La Plata, Indian Head, and the Morgantown power plant. The groundwater levels measured were as low as 215 feet below sea level at Waldorf, 149 feet below sea level at La Plata, 121 feet below sea level at Indian Head, and 96 feet below sea level at the Morgantown power plant. The map also shows well yield in gallons per day for 2008 at wells or well fields.

Seasonal Influences on Ground-Surface Water Interactions in an Arsenic-Affected Aquifer in Cambodia

Science.gov (United States)

Richards, L. A.; Magnone, D.; Van Dongen, B.; Bryant, C.; Boyce, A.; Ballentine, C. J.; Polya, D. A.

2015-12-01

Millions of people in South and Southeast Asia consume drinking water daily which contains dangerous levels of arsenic exceeding health-based recommendations [1]. A key control on arsenic mobilization in aquifers in these areas has been controversially identified as the interaction of 'labile' organic matter contained in surface waters with groundwaters and sediments at depth [2-4], which may trigger the release of arsenic from the solid- to aqueous-phase via reductive dissolution of iron-(hyr)oxide minerals [5]. In a field site in Kandal Province, Cambodia, which is an arsenic-affected area typical to others in the region, there are strong seasonal patterns in groundwater flow direction, which are closely related to monsoonal rains [6] and may contribute to arsenic release in this aquifer. The aim of this study is to explore the implications of the high susceptibility of this aquifer system to seasonal changes on potential ground-surface water interactions. The main objectives are to (i) identify key zones where there are likely ground-surface water interactions, (ii) assess the seasonal impact of such interactions and (iii) quantify the influence of interactions using geochemical parameters (such as As, Fe, NO3, NH4, 14C, 3T/3He, δ18O, δ2H). Identifying the zones, magnitude and seasonal influence of ground-surface water interactions elucidates new information regarding potential locations/pathways of arsenic mobilization and/or transport in affected aquifers and may be important for water management strategies in affected areas. This research is supported by NERC (NE/J023833/1) to DP, BvD and CJB and a NERC PhD studentship (NE/L501591/1) to DM. References: [1] World Health Organization, 2008. [2] Charlet & Polya (2006), Elements, 2, 91-96. [3] Harvey et al. (2002), Science, 298, 1602-1606. [4] Lawson et al. (2013), Env. Sci. Technol. 47, 7085 - 7094. [5] Islam et al. (2004), Nature, 430, 68-71. [6] Benner et al. (2008) Appl. Geochem. 23(11), 3072 - 3087.

Potentiometric surface of the Upper Floridan aquifer in Florida and parts of Georgia, South Carolina, and Alabama, May – June 2010

Science.gov (United States)

Kinnaman, Sandra L.; Dixon, Joann F.

2011-01-01

The Floridan aquifer system covers nearly 100,000 square miles in the southeastern United States throughout Florida and in parts of Georgia, South Carolina, and Alabama, and is one of the most productive aquifers in the world (Miller, 1990). This sequence of carbonate rocks is hydraulically connected and is over 300 feet thick in south Florida and thins toward the north. Typically, this sequence is subdivided into the Upper Floridan aquifer, the middle confining unit, and the Lower Floridan aquifer. The majority of freshwater is contained in the Upper Floridan aquifer and is used for water supply (Miller, 1986). The Lower Floridan aquifer contains fresh to brackish water in northeastern Florida and Georgia, while in south Florida it is saline. The potentiometric surface of the Upper Floridan aquifer in May–June 2010 shown on this map was constructed as part of the U.S. Geological Survey Floridan Aquifer System Groundwater Availability Study (U.S. Geological Survey database, 2011). Previous synoptic measurements and regional potentiometric maps of the Upper Floridan aquifer were prepared for May 1980 (Johnston and others, 1981) and May 1985 (Bush and others, 1986) as part of the Floridan Regional Aquifer System Analysis.

Catalytic Activity and Stability of Oxides: The Role of Near-Surface Atomic Structures and Compositions.

Science.gov (United States)

Feng, Zhenxing; Hong, Wesley T; Fong, Dillon D; Lee, Yueh-Lin; Yacoby, Yizhak; Morgan, Dane; Shao-Horn, Yang

2016-05-17

Electrocatalysts play an important role in catalyzing the kinetics for oxygen reduction and oxygen evolution reactions for many air-based energy storage and conversion devices, such as metal-air batteries and fuel cells. Although noble metals have been extensively used as electrocatalysts, their limited natural abundance and high costs have motivated the search for more cost-effective catalysts. Oxides are suitable candidates since they are relatively inexpensive and have shown reasonably high activity for various electrochemical reactions. However, a lack of fundamental understanding of the reaction mechanisms has been a major hurdle toward improving electrocatalytic activity. Detailed studies of the oxide surface atomic structure and chemistry (e.g., cation migration) can provide much needed insights for the design of highly efficient and stable oxide electrocatalysts. In this Account, we focus on recent advances in characterizing strontium (Sr) cation segregation and enrichment near the surface of Sr-substituted perovskite oxides under different operating conditions (e.g., high temperature, applied potential), as well as their influence on the surface oxygen exchange kinetics at elevated temperatures. We contrast Sr segregation, which is associated with Sr redistribution in the crystal lattice near the surface, with Sr enrichment, which involves Sr redistribution via the formation of secondary phases. The newly developed coherent Bragg rod analysis (COBRA) and energy-modulated differential COBRA are uniquely powerful ways of providing information about surface and interfacial cation segregation at the atomic scale for these thin film electrocatalysts. In situ ambient pressure X-ray photoelectron spectroscopy (APXPS) studies under electrochemical operating conditions give additional insights into cation migration. Direct COBRA and APXPS evidence for surface Sr segregation was found for La1-xSrxCoO3-δ and (La1-ySry)2CoO4±δ/La1-xSrxCoO3-δ oxide thin films, and

Potentiometric Surface of the Upper Floridan Aquifer, West-Central Florida, May 2006

Science.gov (United States)

Ortiz, A.G.

2007-01-01

Introduction Hydrologic Conditions in West-Central Florida The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing fresh water are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in May 2006. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the dry season, when ground-water levels usually are at an annual low and withdrawals for agricultural use typically are high. The cumulative average rainfall of 50.23 inches for west-central Florida (from June 2005 through May 2006) was 2.82 inches below the historical cumulative average of 53.05 inches (Southwest Florida Water Management District, 2006). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water

Seismic-sequence stratigraphy and geologic structure of the Floridan aquifer system near "Boulder Zone" deep wells in Miami-Dade County, Florida

Science.gov (United States)

Cunningham, Kevin J.

2015-01-01

The U.S. Geological Survey, in cooperation with the Miami-Dade Water and Sewer Department, acquired, processed, and interpreted seismic-reflection data near the North and South District “Boulder Zone” Well Fields to determine if geologic factors may contribute to the upward migration of injected effluent into that upper part of the Floridan aquifer system designated by the U.S. Environmental Protection Agency as an underground source of drinking water. The depth of the Boulder Zone at the North and South District “Boulder Zone” Well Fields ranges from about 2,750 to 3,300 feet below land surface (ft bls), whereas overlying permeable zones used as alternative drinking water supply range in depth from about 825 to 1,580 ft bls at the North and South District “Boulder Zone” Well Fields. Seismic-sequence stratigraphy and geologic structures imaged on seismic-reflection profiles created for the study describe the part of the Floridan aquifer system overlying and within the Boulder Zone. Features of the Floridan aquifer system underlying the Boulder Zone were not studied because seismic-reflection profiles acquired near the North and South District “Boulder Zone” Well Fields lacked adequate resolution at such depths.

Use of borehole and surface geophysics to investigate ground-water quality near a road-deicing salt-storage facility, Valparaiso, Indiana

Science.gov (United States)

Risch, M.R.; Robinson, B.A.

2001-01-01

Borehole and surface geophysics were used to investigate ground-water quality affected by a road-deicing salt-storage facility located near a public water-supply well field. From 1994 through 1998, borehole geophysical logs were made in an existing network of monitoring wells completed near the bottom of a thick sand aquifer. Logs of natural gamma activity indicated a uniform and negligible contribution of clay to the electromagnetic conductivity of the aquifer so that the logs of electromagnetic conductivity primarily measured the amount of dissolved solids in the ground water near the wells. Electromagneticconductivity data indicated the presence of a saltwater plume near the bottom of the aquifer. Increases in electromagnetic conductivity, observed from sequential logging of wells, indicated the saltwater plume had moved north about 60 to 100 feet per year between 1994 and 1998. These rates were consistent with estimates of horizontal ground-water flow based on velocity calculations made with hydrologic data from the study area.

Geohydrologic units and water-level conditions in the Terrace alluvial aquifer and Paluxy Aquifer, May 1993 and February 1994, near Air Force Plant 4, Fort Worth area, Texas

Science.gov (United States)

Rivers, Glen A.; Baker, Ernest T.; Coplin, L.S.

1996-01-01

The terrace alluvial aquifer underlying Air Force Plant 4 and the adjacent Naval Air Station (formerly Carswell Air Force Base) in the Fort Worth area, Texas, is contaminated locally with organic and metal compounds. Residents south and west of Air Force Plant 4 and the Naval Air Station are concerned that contaminants might enter the underlying Paluxy aquifer, which provides water to the city of White Settlement, south of Air Force Plant 4, and to residents west of Air Force Plant 4. The U.S. Environmental Protection Agency has qualified Air Force Plant 4 for Superfund cleanup. The pertinent geologic units include -A~rom oldest to youngest the Glen Rose, Paluxy, and Walnut Formations, Goodland Limestone, and terrace alluvial deposits. Except for the Glen Rose Formation, all units crop out at or near Air Force Plant 4 and the Naval Air Station. The terrace alluvial deposits, which nearly everywhere form the land surface, range from 0 to about 60 feet thick. These deposits comprise a mostly unconsolidated mixture of gravel, sand, silt, and clay. Mudstone and sandstone of the Paluxy Formation crop out north, west, and southwest of Lake Worth and total between about 130 and about 175 feet thick. The terrace alluvial deposits and the Paluxy Formation comprise the terrace alluvial aquifer and the Paluxy aquifer, respectively. These aquifers are separated by the Goodland-Walnut confining unit, composed of the Goodland Limestone and (or) Walnut Formation. Below the Paluxy aquifer, the Glen Rose Formation forms the Glen Rose confining unit. Water-level measurements during May 1993 and February 1994 from wells in the terrace alluvial aquifer indicate that, regionally, ground water flows toward the east-southeast beneath Air Force Plant 4 and the Naval Air Station. Locally, water appears to flow outward from ground-water mounds maintained by the localized infiltration of precipitation and reportedly by leaking water pipes and sanitary and (or) storm sewer lines beneath the

Evolution of Near-Surface Internal and External Oxide Morphology During High-Temperature Selective Oxidation of Steels

Science.gov (United States)

Story, Mary E.; Webler, Bryan A.

2018-05-01

In this work we examine some observations made using high-temperature confocal scanning laser microscopy (HT-CSLM) during selective oxidation experiments. A plain carbon steel and advanced high-strength steel (AHSS) were selectively oxidized at high temperature (850-900°C) in either low oxygen or water vapor atmospheres. Surface evolution, including thermal grooving along grain boundaries and oxide growth, was viewed in situ during heating. Experiments investigated the influence of the microstructure and oxidizing atmosphere on selective oxidation behavior. Sequences of CSLM still frames collected during the experiment were processed with ImageJ to obtain histograms that showed a general darkening trend indicative of oxidation over time with all samples. Additional ex situ scanning electron microscopy and energy dispersive spectroscopy analysis supported in situ observations. Distinct oxidation behavior was observed for each case. Segregation, grain orientation, and extent of internal oxidation were all found to strongly influence surface evolution.

Catalytic Activity and Stability of Oxides: The Role of Near-Surface Atomic Structures and Compositions

KAUST Repository

Feng, Zhenxing

2016-05-05

Conspectus Electrocatalysts play an important role in catalyzing the kinetics for oxygen reduction and oxygen evolution reactions for many air-based energy storage and conversion devices, such as metal–air batteries and fuel cells. Although noble metals have been extensively used as electrocatalysts, their limited natural abundance and high costs have motivated the search for more cost-effective catalysts. Oxides are suitable candidates since they are relatively inexpensive and have shown reasonably high activity for various electrochemical reactions. However, a lack of fundamental understanding of the reaction mechanisms has been a major hurdle toward improving electrocatalytic activity. Detailed studies of the oxide surface atomic structure and chemistry (e.g., cation migration) can provide much needed insights for the design of highly efficient and stable oxide electrocatalysts. In this Account, we focus on recent advances in characterizing strontium (Sr) cation segregation and enrichment near the surface of Sr-substituted perovskite oxides under different operating conditions (e.g., high temperature, applied potential), as well as their influence on the surface oxygen exchange kinetics at elevated temperatures. We contrast Sr segregation, which is associated with Sr redistribution in the crystal lattice near the surface, with Sr enrichment, which involves Sr redistribution via the formation of secondary phases. The newly developed coherent Bragg rod analysis (COBRA) and energy-modulated differential COBRA are uniquely powerful ways of providing information about surface and interfacial cation segregation at the atomic scale for these thin film electrocatalysts. In situ ambient pressure X-ray photoelectron spectroscopy (APXPS) studies under electrochemical operating conditions give additional insights into cation migration. Direct COBRA and APXPS evidence for surface Sr segregation was found for La1–xSrxCoO3−δ and (La1–ySry)2CoO4±δ/La1–xSrxCoO3�

Creating a monthly time series of the potentiometric surface in the Upper Floridan aquifer, Northern Tampa Bay area, Florida, January 2000-December 2009

Science.gov (United States)

Lee, Terrie M.; Fouad, Geoffrey G.

2014-01-01

semivariograms decreased markedly between 2002 and 2003, timing that coincided with decreases in well-field pumping. Cross-validation results suggest that the kriging interpolation may smooth over the drawdown of the potentiometric surface near production wells. The groundwater monitoring network of 197 wells yielded an average kriging error in the potentiometric-surface elevations of 2 feet or less over approximately 70 percent of the map area. Additional data collection within the existing monitoring network of 260 wells and near selected well fields could reduce the error in individual months. Reducing the kriging error in other areas would require adding new monitoring wells. Potentiometric-surface elevations fluctuated by as much as 30 feet over the study period, and the spatially averaged elevation for the entire surface rose by about 2 feet over the decade. Monthly potentiometric-surface elevations describe the lateral groundwater flow patterns in the aquifer and are usable at a variety of spatial scales to describe vertical groundwater recharge and discharge conditions for overlying surface-water features.

Potential for saltwater intrusion into the lower Tamiami aquifer near Bonita Springs, southwestern Florida

Science.gov (United States)

Shoemaker, W. Barclay; Edwards, K. Michelle

2003-01-01

-density ground-water flow simulations suggest that upconing is of utmost concern, and lateral encroachment is of second-most concern. This interpretation is uncertain, however, because the predominance of saltwater intrusion through leaky artesian wells with connection to deeper, more saline, and higher pressure aquifers was difficult to establish. Effective management of ground-water resources in southwestern Florida requires an understanding of the potential extent of saltwater intrusion in the lower Tamiami aquifer near Bonita Springs. Variable-density, ground-water flow simulations suggest that when saltwater is at dynamic equilibrium with 1996 seasonal stresses, the extent of saltwater intrusion is about 100 square kilometers areally and 70,000 hectare-meters volumetrically. The volumetric extent of saltwater intrusion was most sensitive to changes in recharge, ground-water pumpage, sea level, salinity of the Gulf of Mexico, and the potentiometric surface of the sandstone aquifer, respectively.

Inference of Stream Network Fragmentation Patterns from Ground Water - Surface Water Interactions on the High Plains Aquifer

Science.gov (United States)

Chandler, D. G.; Yang, X.; Steward, D. R.; Gido, K.

2007-12-01

Stream networks in the Great Plains integrate fluxes from precipitation as surface runoff in discrete events and groundwater as base flow. Changes in land cover and agronomic practices and development of ground water resources to support irrigated agriculture have resulted in profound changes in the occurrence and magnitude of stream flows, especially near the Ogallala aquifer, where precipitation is low. These changes have demonstrably altered the aquatic habitat of western Kansas, with documented changes in fish populations, riparian communities and groundwater quality due to stream transmission losses. Forecasting future changes in aquatic and riparian ecology and groundwater quality requires a large scale spatially explicit model of groundwater- surface water interaction. In this study, we combine historical data on land use, stream flow, production well development and groundwater level observations with groundwater elevation modeling to support a geospatial framework for assessing changes in refugia for aquatic species in four rivers in western Kansas between 1965 and 2005. Decreased frequency and duration of streamflow occurred in all rivers, but the extent of change depended on the geomorphology of the river basin and the extent of groundwater development. In the absence of streamflow, refugia for aquatic species were defined as the stream reaches below the phreatic surface of the regional aquifer. Changes in extent, location and degree of fragmentation of gaining reaches was found to be a strong predictor of surface water occurrence during drought and a robust hydrological template for the analysis of changes in recharge to alluvial and regional aquifers and riparian and aquatic habitat.

Optical near-field lithography on hydrogen-passivated silicon surfaces

DEFF Research Database (Denmark)

Madsen, Steen; Müllenborn, Matthias; Birkelund, Karen

1996-01-01

by the optical near field, were observed after etching in potassium hydroxide. The uncoated fibers can also induce oxidation without light exposure, in a manner similar to an atomic force microscope, and linewidths of 50 nm have been achieved this way. (C) 1996 American Institute of Physics.......We report on a novel lithography technique for patterning of hydrogen-passivated amorphous silicon surfaces. A reflection mode scanning near-field optical microscope with uncoated fiber probes has been used to locally oxidize a thin amorphous silicon layer. Lines of 110 nm in width, induced...

Hydrogeologic appraisal of a stratified-drift aquifer near Smyrna, Chenango County, New York

Science.gov (United States)

Reynolds, R.J.; Brown, G.A.

1984-01-01

A broad, Y-shaped valley near Smyrna, New York, contains extensive water-table and confined aquifers that are largely hydraulically separated from the nearby Chenango River to the east. Accordingly, ground-water withdrawals from this valley would not appreciably decrease streamflow in the Chenango River by induced infiltration and could be used for specialized needs. The aquifers in the valley are capable of sustaining a long-term total withdrawal of about 12.7 million gallons per day during prolonged drought conditions. Larger withdrawals could be made on a short-term basis or during periods of normal or above-normal precipitation. Saturated thickness of undifferentiated stratified-drift deposits in the valley ranges from 20 feet in the northwestern part of the valley to more than 300 feet at its southern end. Direct areal recharge accounts for about 56 percent of the total recharge to the valley aquifer infiltration from streams accounts for 24 percent, and runoff from the adjacent till-mantled hillsides accounts for 20 percent. The water-table and confined aquifers within the valley hold at least 19.6 billion gallons of usable ground water in storage. (USGS)

A DOM Odyssey: The Tale of Molecular Transformations in an Aquifer near Bemidji, MN

Science.gov (United States)

Podgorski, D. C.; Zito, P.; Smith, D. F.; Cao, X.; Schmidt-Rohr, K.; Wagner, S.; Stubbins, A.; Aiken, G.; Cozzarelli, I.; Bekins, B. A.; Spencer, R. G.

2017-12-01

Analytical methods including fluorescence spectroscopy, NMR spectroscopy, and ultrahigh resolution mass spectrometry have significantly advanced the understanding of compositional controls on dissolved organic matter (DOM) processing and fate. Yet, we still heavily rely on extrapolation of chemical changes identified at the edges of the compositional continuum (i.e., endmembers) to assess DOM reactivity and stability. While extrapolation of chemical transformations is useful for determining relative changes in DOM composition, a comprehensive understanding of the underlying core structures and composition is required to develop advanced biogeochemical models. Studying DOM from natural systems is complicated by many variables associated with an open system including input from multiple sources, simultaneous photo-alteration and microbial processing, and obtaining samples that cover high spatial and temporal resolution. A 38-year biodegradation study at the National Crude Oil Spill Research site near Bemidji, MN provides a unique opportunity to monitor DOM in a relatively closed system. An extensively characterized 1 m thick oil body is confined to a 25 x 75 m2 area at the water table in the aquifer. Oxidized metabolites partition from the oil into the underlying aquifer increase the DOC concentration to > 100 ppm from molecular formulas with O/C and H/C similar to those associated with the `island of stability'. Samples collected spatially from the DOM plume between these two endmembers provide sufficient temporal resolution to model both DOC concentration and DOM composition as a result of biodegradation.

Electrical properties of polyimides containing a near-surface deposit of silver

Science.gov (United States)

Rancourt, J. D.; Porta, G. M.; Taylor, L. T.

1987-01-01

Films containing a surface or near-surface deposit of palladium, gold or copper metal as well as tin, cobalt, copper, or lithium oxides have been prepared by dissolving appropriate metal salts into poly(amide-acid)/N,N-dimethylacetamide solutions and curing the solvent cast films to temperatures up to 300 C. This preparation technique has been extended to evaluate the thermal, spectroscopic, and electrical characteristics of condensation polyimide films modified with silver nitrate. A near-surface deposit of metallic silver results but the reflective surface has high electrical resistivity (sheet resistivity) due to a polymer coating or overlayer above the metal. Details pertaining to the silver nitrate modified condensation polyimides are presented. Also, the applicability of the structural model and electrical model previously proposed for the cobalt oxide system are assessed.

Arsenic release during managed aquifer recharge (MAR)

Science.gov (United States)

Pichler, T.; Lazareva, O.; Druschel, G.

2013-12-01

The mobilization and addition of geogenic trace metals to groundwater is typically caused by anthropogenic perturbations of the physicochemical conditions in the aquifer. This can add dangerously high levels of toxins to groundwater, thus compromising its use as a source of drinking water. In several regions world-wide, aquifer storage and recovery (ASR), a form of managed aquifer recharge (MAR), faces the problem of arsenic release due to the injection of oxygenated storage water. To better understand this process we coupled geochemical reactive transport modeling to bench-scale leaching experiments to investigate and verify the mobilization of geogenic arsenic (As) under a range of redox conditions from an arsenic-rich pyrite bearing limestone aquifer in Central Florida. Modeling and experimental observations showed similar results and confirmed the following: (1) native groundwater and aquifer matrix, including pyrite, were in chemical equilibrium, thus preventing the release of As due to pyrite dissolution under ambient conditions; (2) mixing of oxygen-rich surface water with oxygen-depleted native groundwater changed the redox conditions and promoted the dissolution of pyrite, and (3) the behavior of As along a flow path was controlled by a complex series of interconnected reactions. This included the oxidative dissolution of pyrite and simultaneous sorption of As onto neo-formed hydrous ferric oxides (HFO), followed by the reductive dissolution of HFO and secondary release of adsorbed As under reducing conditions. Arsenic contamination of drinking water in these systems is thus controlled by the re-equilibration of the system to more reducing conditions rather than a purely oxidative process.

ORNL results for Test Case 1 of the International Atomic Energy Agency's research program on the safety assessment of Near-Surface Radioactive Waste Disposal Facilities

International Nuclear Information System (INIS)

Thorne, D.J.; McDowell-Boyer, L.M.; Kocher, D.C.; Little, C.A.; Roemer, E.K.

1993-01-01

The International Atomic Energy Agency (IAEA) started the Coordinated Research Program entitled '''The Safety Assessment of Near-Surface Radioactive Waste Disposal Facilities.'' The program is aimed at improving the confidence in the modeling results for safety assessments of waste disposal facilities. The program has been given the acronym NSARS (Near-Surface Radioactive Waste Disposal Safety Assessment Reliability Study) for ease of reference. The purpose of this report is to present the ORNL modeling results for the first test case (i.e., Test Case 1) of the IAEA NSARS program. Test Case 1 is based on near-surface disposal of radionuclides that are subsequently leached to a saturated-sand aquifer. Exposure to radionuclides results from use of a well screened in the aquifer and from intrusion into the repository. Two repository concepts were defined in Test Case 1: a simple earth trench and an engineered vault

Groundwater-level and storage-volume changes in the Equus Beds aquifer near Wichita, Kansas, predevelopment through January 2015

Science.gov (United States)

Whisnant, Joshua A.; Hansen, Cristi V.; Eslick, Patrick J.

2015-10-01

Development of the Wichita well field began in the 1940s in the Equus Beds aquifer to provide the city of Wichita, Kansas, a new water-supply source. After development of the Wichita well field began, groundwater levels began to decline. Extensive development of irrigation wells that began in the 1970s also contributed to substantial groundwater-level declines. Groundwater-level declines likely enhance movement of brine from past oil and gas production near Burrton, Kansas, and natural saline water from the Arkansas River into the Wichita well field. Groundwater levels reached a historical minimum in 1993 because of drought conditions, irrigation, and the city of Wichita’s withdrawals from the aquifer. In 1993, the city of Wichita adopted the Integrated Local Water Supply Program to ensure that Wichita’s water needs would be met through the year 2050 and beyond as part of its efforts to manage the part of the Equus Beds aquifer Wichita uses. A key component of the Integrated Local Water Supply Program was the Equus Beds Aquifer Storage and Recovery project. The Aquifer Storage and Recovery project’s goal is to store and eventually recover groundwater and help protect the Equus Beds aquifer from oil-field brine water near Burrton, Kansas, and saline water from the Arkansas River. Since 1940, the U.S. Geological Survey has monitored groundwater levels and storage-volume changes in the Equus Beds aquifer to provide data to the city of Wichita in order to better manage its water supply.

Delineation of the hydrogeologic framework of the Big Sioux aquifer near Sioux Falls, South Dakota, using airborne electromagnetic data

Science.gov (United States)

Valseth, Kristen J.; Delzer, Gregory C.; Price, Curtis V.

2018-03-21

The U.S. Geological Survey, in cooperation with the City of Sioux Falls, South Dakota, began developing a groundwater-flow model of the Big Sioux aquifer in 2014 that will enable the City to make more informed water management decisions, such as delineation of areas of the greatest specific yield, which is crucial for locating municipal wells. Innovative tools are being evaluated as part of this study that can improve the delineation of the hydrogeologic framework of the aquifer for use in development of a groundwater-flow model, and the approach could have transfer value for similar hydrogeologic settings. The first step in developing a groundwater-flow model is determining the hydrogeologic framework (vertical and horizontal extents of the aquifer), which typically is determined by interpreting geologic information from drillers’ logs and surficial geology maps. However, well and borehole data only provide hydrogeologic information for a single location; conversely, nearly continuous geophysical data are collected along flight lines using airborne electromagnetic (AEM) surveys. These electromagnetic data are collected every 3 meters along a flight line (on average) and subsequently can be related to hydrogeologic properties. AEM data, coupled with and constrained by well and borehole data, can substantially improve the accuracy of aquifer hydrogeologic framework delineations and result in better groundwater-flow models. AEM data were acquired using the Resolve frequency-domain AEM system to map the Big Sioux aquifer in the region of the city of Sioux Falls. The survey acquired more than 870 line-kilometers of AEM data over a total area of about 145 square kilometers, primarily over the flood plain of the Big Sioux River between the cities of Dell Rapids and Sioux Falls. The U.S. Geological Survey inverted the survey data to generate resistivity-depth sections that were used in two-dimensional maps and in three-dimensional volumetric visualizations of the Earth

Mercury mobilization and speciation linked to bacterial iron oxide and sulfate reduction: A column study to mimic reactive transfer in an anoxic aquifer.

Science.gov (United States)

Hellal, Jennifer; Guédron, Stéphane; Huguet, Lucie; Schäfer, Jörg; Laperche, Valérie; Joulian, Catherine; Lanceleur, Laurent; Burnol, André; Ghestem, Jean-Philippe; Garrido, Francis; Battaglia-Brunet, Fabienne

2015-09-01

Mercury (Hg) mobility and speciation in subsurface aquifers is directly linked to its surrounding geochemical and microbial environment. The role of bacteria on Hg speciation (i.e., methylation, demethylation and reduction) is well documented, however little data is available on their impact on Hg mobility. The aim of this study was to test if (i) Hg mobility is due to either direct iron oxide reduction by iron reducing bacteria (IRB) or indirect iron reduction by sulfide produced by sulfate reducing bacteria (SRB), and (ii) to investigate its subsequent fate and speciation. Experiments were carried out in an original column setup combining geochemical and microbiological approaches that mimic an aquifer including an interface of iron-rich and iron depleted zones. Two identical glass columns containing iron oxides spiked with Hg(II) were submitted to (i) direct iron reduction by IRB and (ii) to indirect iron reduction by sulfides produced by SRB. Results show that in both columns Hg was leached and methylated during the height of bacterial activity. In the column where IRB are dominant, Hg methylation and leaching from the column was directly correlated to bacterial iron reduction (i.e., Fe(II) release). In opposition, when SRB are dominant, produced sulfide induced indirect iron oxide reduction and rapid adsorption of leached Hg (or produced methylmercury) on neoformed iron sulfides (e.g., Mackinawite) or its precipitation as HgS. At the end of the SRB column experiment, when iron-oxide reduction was complete, filtered Hg and Fe concentrations increased at the outlet suggesting a leaching of Hg bound to FeS colloids that may be a dominant mechanism of Hg transport in aquifer environments. These experimental results highlight different biogeochemical mechanisms that can occur in stratified sub-surface aquifers where bacterial activities play a major role on Hg mobility and changes in speciation. Copyright © 2015 Elsevier B.V. All rights reserved.

Surface complexation modeling for predicting solid phase arsenic concentrations in the sediments of the Mississippi River Valley alluvial aquifer, Arkansas, USA

Science.gov (United States)

Sharif, M.S.U.; Davis, R.K.; Steele, K.F.; Kim, B.; Hays, P.D.; Kresse, T.M.; Fazio, J.A.

2011-01-01

The potential health impact of As in drinking water supply systems in the Mississippi River Valley alluvial aquifer in the state of Arkansas, USA is significant. In this context it is important to understand the occurrence, distribution and mobilization of As in the Mississippi River Valley alluvial aquifer. Application of surface complexation models (SCMs) to predict the sorption behavior of As and hydrous Fe oxides (HFO) in the laboratory has increased in the last decade. However, the application of SCMs to predict the sorption of As in natural sediments has not often been reported, and such applications are greatly constrained by the lack of site-specific model parameters. Attempts have been made to use SCMs considering a component additivity (CA) approach which accounts for relative abundances of pure phases in natural sediments, followed by the addition of SCM parameters individually for each phase. Although few reliable and internally consistent sorption databases related to HFO exist, the use of SCMs using laboratory-derived sorption databases to predict the mobility of As in natural sediments has increased. This study is an attempt to evaluate the ability of the SCMs using the geochemical code PHREEQC to predict solid phase As in the sediments of the Mississippi River Valley alluvial aquifer in Arkansas. The SCM option of the double-layer model (DLM) was simulated using ferrihydrite and goethite as sorbents quantified from chemical extractions, calculated surface-site densities, published surface properties, and published laboratory-derived sorption constants for the sorbents. The model results are satisfactory for shallow wells (10.6. m below ground surface), where the redox condition is relatively oxic or mildly suboxic. However, for the deep alluvial aquifer (21-36.6. m below ground surface) where the redox condition is suboxic to anoxic, the model results are unsatisfactory. ?? 2011 Elsevier Ltd.

Difference between the potentiometric surfaces of the Lower Patapsco aquifer in southern Maryland, September 1990 and September 2009

Science.gov (United States)

Curtin, Stephen E.; Andreasen, David C.; Staley, Andrew W.

2010-01-01

This report presents a map showing the change in the potentiometric surface of the lower Patapsco aquifer in the Patapsco Formation of Early Cretaceous age in Southern Maryland between September 1990 and September 2009. The map, based on water level differences obtained from 45 wells, shows that the change of the potentiometric surface during the 19-year period ranged from increases of 25 feet at Indian Head and 4 feet near the outcrop area in Glen Burnie, to declines of 35 feet at Arnold, 56 feet at Severndale, 28 feet at Crofton Meadows, 73 feet at Waldorf, 79 feet near La Plata, 35 feet at the Morgantown power plant, and 32 feet at Swan Point. The map also shows well yield in gallons per day for 2008 at wells or well fields.

Hydrogeology and water quality of the Floridan aquifer system and effect of Lower Floridan aquifer withdrawals on the Upper Floridan aquifer at Barbour Pointe Community, Chatham County, Georgia, 2013

Science.gov (United States)

Gonthier, Gerard; Clarke, John S.

2016-06-02

Two test wells were completed at the Barbour Pointe community in western Chatham County, near Savannah, Georgia, in 2013 to investigate the potential of using the Lower Floridan aquifer as a source of municipal water supply. One well was completed in the Lower Floridan aquifer at a depth of 1,080 feet (ft) below land surface; the other well was completed in the Upper Floridan aquifer at a depth of 440 ft below land surface. At the Barbour Pointe test site, the U.S. Geological Survey completed electromagnetic (EM) flowmeter surveys, collected and analyzed water samples from discrete depths, and completed a 72-hour aquifer test of the Floridan aquifer system withdrawing from the Lower Floridan aquifer.Based on drill cuttings, geophysical logs, and borehole EM flowmeter surveys collected at the Barbour Pointe test site, the Upper Floridan aquifer extends 369 to 567 ft below land surface, the middle semiconfining unit, separating the two aquifers, extends 567 to 714 ft below land surface, and the Lower Floridan aquifer extends 714 to 1,056 ft below land surface.A borehole EM flowmeter survey indicates that the Upper Floridan and Lower Floridan aquifers each contain four water-bearing zones. The EM flowmeter logs of the test hole open to the entire Floridan aquifer system indicated that the Upper Floridan aquifer contributed 91 percent of the total flow rate of 1,000 gallons per minute; the Lower Floridan aquifer contributed about 8 percent. Based on the transmissivity of the middle semiconfining unit and the Floridan aquifer system, the middle semiconfining unit probably contributed on the order of 1 percent of the total flow.Hydraulic properties of the Upper Floridan and Lower Floridan aquifers were estimated based on results of the EM flowmeter survey and a 72-hour aquifer test completed in Lower Floridan aquifer well 36Q398. The EM flowmeter data were analyzed using an AnalyzeHOLE-generated model to simulate upward borehole flow and determine the transmissivity of

Seasonal Hydrologic Controls on Uranium and Iron Biogeochemistry in a Riparian Aquifer

Science.gov (United States)

Wilkins, M.; Williams, K. H.; Danczak, R. E.; Yabusaki, S.; Fang, Y.; Hobson, C.

2015-12-01

The maintenance of geochemically reducing conditions is generally optimal for the formation and preservation of reduced metals and mineral phases that can limit contaminant fate and transport. At a riparian aquifer near Rifle, CO, we tracked over six months the biogeochemical response within the aquifer to an annual pulse of dissolved oxygen (DO) that results from snowmelt-driven changes in Colorado River stage. In reduced portions of the aquifer (naturally reduced zones; NRZs) the re-oxidation of abundant iron sulfide minerals was the dominant oxygen-consuming process, and resulted in little DO intrusion into the deeper aquifer. In less reduced areas, DO intruded through the entire vertical profile of the aquifer. Across both regions, these perturbations resulted in changes to the microbial community structure, and aqueous metal pools. Two potentially different mechanisms of uranium mobilization were observed; (1) re-oxidation of reduced U(IV) phases in response to DO intrusion, and (2) mobilization of U(VI) from the vadose zone during water table rise. This high-resolution, long-term monitoring of aquifer biogeochemistry at the Rifle site has revealed dynamic microbial and geochemical responses to predictable, annual hydrologic perturbations, and offers an opportunity to further refine modeling approaches for such regions.

Anoxic nitrate reduction coupled with iron oxidation and attenuation of dissolved arsenic and phosphate in a sand and gravel aquifer

Science.gov (United States)

Smith, Richard L.; Kent, Douglas B.; Repert, Deborah A.; Böhlke, J.K.

2017-01-01

Nitrate has become an increasingly abundant potential electron acceptor for Fe(II) oxidation in groundwater, but this redox couple has not been well characterized within aquifer settings. To investigate this reaction and some of its implications for redox-sensitive groundwater contaminants, we conducted an in situ field study in a wastewater-contaminated aquifer on Cape Cod. Long-term (15 year) geochemical monitoring within the contaminant plume indicated interacting zones with variable nitrate-, Fe(II)-, phosphate-, As(V)-, and As(III)-containing groundwater. Nitrate and phosphate were derived predominantly from wastewater disposal, whereas Fe(II), As(III), and As(V) were mobilized from the aquifer sediments. Multiple natural gradient, anoxic tracer tests were conducted in which nitrate and bromide were injected into nitrate-free, Fe(II)-containing groundwater. Prior to injection, aqueous Fe(II) concentrations were approximately 175 μM, but sorbed Fe(II) accounted for greater than 90% of the total reactive Fe(II) in the aquifer. Nitrate reduction was stimulated within 1 m of transport for 100 μM and 1000 μM nitrate additions, initially producing stoichiometric quantities of nitrous oxide (>300 μM N). In subsequent injections at the same site, nitrate was reduced even more rapidly and produced less nitrous oxide, especially over longer transport distances. Fe(II) and nitrate concentrations decreased together and were accompanied by Fe(III) oxyhydroxide precipitation and decreases in dissolved phosphate, As(III), and As(V) concentrations. Nitrate N and O isotope fractionation effects during nitrate reduction were approximately equal (ε15N/ε18O = 1.11) and were similar to those reported for laboratory studies of biological nitrate reduction, including denitrification, but unlike some reported effects on nitrate by denitrification in aquifers. All constituents affected by the in situ tracer experiments returned to pre-injection levels after several

Effect of Short-Circuit Pathways on Water Quality in Selected Confined Aquifers (Invited)

Science.gov (United States)

McMahon, P. B.

2010-12-01

Confined aquifers in the United States generally contain fewer anthropogenic contaminants than unconfined aquifers because confined aquifers often contain water recharged prior to substantial human development and redox conditions are more reducing, which favors degradation of common contaminants like nitrate and chlorinated solvents. Groundwater in a confined part of the High Plains aquifer near York, Nebraska had an adjusted radiocarbon age of about 2,000 years, and groundwater in a confined part of the Floridan aquifer near Tampa, Florida had apparent ages greater than 60 years on the basis of tritium measurements. Yet compounds introduced more recently into the environment (anthropogenic nitrate and volatile organic compounds) were detected in selected public-supply wells completed in both aquifers. Depth-dependent measurements of flow and chemistry in the pumping supply wells, groundwater age dating, numerical modeling of groundwater flow, and other monitoring data indicated that the confined aquifers sampled by the supply wells were connected to contaminated unconfined aquifers by short-circuit pathways. In the High Plains aquifer, the primary pathways appeared to be inactive irrigation wells screened in both the unconfined and confined aquifers. In the Floridan aquifer, the primary pathways were karst sinkholes and conduits. Heavy pumping in both confined systems exacerbated the problem by reducing the potentiometric surface and increasing groundwater velocities, thus enhancing downward gradients and reducing reaction times for processes like denitrification. From a broader perspective, several confined aquifers in the U.S. have experienced large declines in their potentiometric surfaces because of groundwater pumping and this could increase the potential for contamination in those aquifers, particularly where short-circuit pathways connect them to shallower, contaminated sources of water, such as was observed in York and Tampa.

Surface oxidization-reduction reactions in Columbia Plateau basalts

International Nuclear Information System (INIS)

White, A.F.; Yee, A.

1984-01-01

Results are presented which define principal oxidation-reduction reactions expected between ground water and iron in the Umtanum and Cohassett basalt flows of south central Washington. Data include kinetics of aqueous iron speciation, rates of O 2 uptake and nature of oxyhydroxide precipitates. Such data are important in predicting behavior of radionuclides in basalt aquifers including determination of valence states, speciation, solubility, sorption, and coprecipitation on iron oxyhydroxide substrates and colloids. Analyses of the basalt by XPS indicates that ferrous iron is oxidized to ferric iron on the surface and that the total iron decreases as a function of pH during experimental weathering. Iron oxyhydroxide phases did not form surface coating on basalt surfaces but rather nucleated as separate plases in solution. No significant increases in Cs or Sr sorption were observed with increased weathering of the basalt. Concurrent increases in Fe(II) and decreases in Fe(III) in slightly to moderately acid solutions indicated continued oxidization of ferrous iron in the basalt. At neutral to basic pH, Fe(II) was strongly sorbed onto the basalt surface (Kd = 6.5 x 10 -3 1 x m 2 ) resulting in low dissolved concentrations even under anoxic conditions. The rate of O 2 uptake increased with decreasing pH. Diffusion rates (-- 10 -14 cm 2 x s -1 ), calculated using a one-dimensional analytical model, indicate grain boundary diffusion. Comparisons of Eh values calculated by Pt electrode, dissolved O 2 and Fe(II)/Fe(III) measurements showed considerable divergence, with the ferric-ferrous couple being the preferred method of estimating Eh

Potentiometric Surface of the Alluvial Aquifer and Hydrologic Conditions in the Juana Diaz area, Puerto Rico, June 29 - July 1, 2005

Science.gov (United States)

Rodriguez, Jose M.; Santigo-Rivera, Luis; Gómez-Gómez, Fernando

2006-01-01

A synoptic survey of the hydrologic conditions in the Juana Diaz area, Puerto Rico, was conducted between June 29 and July 1, 2005, to define the spatial distribution of the potentiometric surface of the alluvial aquifer. The study area encompasses 21 square miles of the more extensive South Coastal Plain Alluvial Aquifer system and is bounded along the north by foothills of the Cordillera Central mountain chain, to the south by the Caribbean Sea, the east by the Rio Descalabrado and to the west by the Rio Inabon. Ground water in the Juana Diaz area is in the Quaternary-age alluvial deposits and the middle-Tertiary age Ponce Limestone and Juana Diaz Formation (Giusti, 1968). The hydraulic properties of the Ponce Limestone in the Juana Diaz area are unknown, and the Juana Diaz Formation is a unit of poor permeability due to its high clay content. Consequently, the Ponce Limestone and the Juana Diaz Formation are generally considered to be the base of the alluvial aquifer in the Juana Diaz area with ground-water flow occurring primarily within the alluvial deposits. The potentiometric-surface map of the alluvial aquifer was delineated using ground-water level measurements taken at existing wells. The water-level measurements were taken at wells that were either not pumping during the survey or were shut down for a brief period. In the latter case, a recovery period of 30 minutes was allowed for the drawdown in the wellbore to achieve a near static level position representative of the aquifer at the measurement point. Land-surface altitude from U.S. Geological Survey (USGS) 1:20,000 scale topographic maps (Playa de Ponce, Ponce, Rio Descalabrado, and Santa Isabel) were used to refer ground-water levels to mean sea level datum (National Geodetic Vertical Datum of 1929). In addition to the ground-water level measurements, the potentiometricsurface contours were delineated using hydrologic features, such as drainage ditches and saturated intermittent streams that were

Large fractions of CO2-fixing microorganisms in pristine limestone aquifers appear to be involved in the oxidation of reduced sulfur and nitrogen compounds

Science.gov (United States)

Herrmann, Martina; Rusznyák, Anna; Akob, Denise M.; Schulze, Isabel; Opitz, Sebastian; Totsche, Kai Uwe; Küsel, Kirsten

2015-01-01

The traditional view of the dependency of subsurface environments on surface-derived allochthonous carbon inputs is challenged by increasing evidence for the role of lithoautotrophy in aquifer carbon flow. We linked information on autotrophy (Calvin-Benson-Bassham cycle) with that from total microbial community analysis in groundwater at two superimposed—upper and lower—limestone groundwater reservoirs (aquifers). Quantitative PCR revealed that up to 17% of the microbial population had the genetic potential to fix CO2 via the Calvin cycle, with abundances of cbbM and cbbL genes, encoding RubisCO (ribulose-1,5-bisphosphate carboxylase/oxygenase) forms I and II, ranging from 1.14 × 103 to 6 × 106 genes liter−1 over a 2-year period. The structure of the active microbial communities based on 16S rRNA transcripts differed between the two aquifers, with a larger fraction of heterotrophic, facultative anaerobic, soil-related groups in the oxygen-deficient upper aquifer. Most identified CO2-assimilating phylogenetic groups appeared to be involved in the oxidation of sulfur or nitrogen compounds and harbored both RubisCO forms I and II, allowing efficient CO2 fixation in environments with strong oxygen and CO2 fluctuations. The genera Sulfuricellaand Nitrosomonas were represented by read fractions of up to 78 and 33%, respectively, within the cbbM and cbbL transcript pool and accounted for 5.6 and 3.8% of 16S rRNA sequence reads, respectively, in the lower aquifer. Our results indicate that a large fraction of bacteria in pristine limestone aquifers has the genetic potential for autotrophic CO2 fixation, with energy most likely provided by the oxidation of reduced sulfur and nitrogen compounds.

Neutron scattering study of the freezing of water near a cupric oxide surface

Science.gov (United States)

Torres, J.; Buck, Z. N.; Zhang, F. Z.; Chen, T.; Winholtz, R. A.; Kaiser, H.; Ma, H. B.; Taub, H.; Tyagi, M.

Oscillating heat pipes (OHP) offer promising two-phase heat transfer for a variety of applications, including cooling of electronic devices.2 Recently, it has been shown that a hydrophilic CuO coating on either the evaporator or condenser sections of a flat-plate OHP can significantly enhance its thermal performance.3 This finding has motivated us to assess the strength of the CuO/H2O interaction by investigating the freezing behavior of H2O in proximity to a CuO surface. Using the High-Flux Backscattering Spectrometer at NIST, we have measured the intensity of neutrons scattered elastically from a well-hydrated sample of CuO-coated Cu foils that mimic the oxide surfaces in a flat-plate OHP. We observe abrupt freezing of bulk-like H2O above the CuO surface at 270 K followed by continuous freezing of the interfacial H2O down to 265 K. This freezing behavior is qualitatively similar to that found for water near a zwitterionic single-supported bilayer lipid membrane.3 Further studies are planned to compare the diffusion coefficients of the interfacial water for the coated and uncoated OHPs.22F.Z. Zhang et al., submitted to J. Heat Transfer. 3M. Bai et al., Europhys. Lett. 98, 48006 (2012); Miskowiec et al., Europhys. Lett. 107, 28008 (2014). Supported by NSF Grant Nos. DMR-0944772 and DGE-1069091.

Water-level trends and potentiometric surfaces in the Nacatoch Aquifer in northeastern and southwestern Arkansas and in the Tokio Aquifer in southwestern Arkansas, 2014–15

Science.gov (United States)

Rodgers, Kirk D.

2017-09-20

The Nacatoch Sand in northeastern and southwestern Arkansas and the Tokio Formation in southwestern Arkansas are sources of groundwater for agricultural, domestic, industrial, and public use. Water-level altitudes measured in 51 wells completed in the Nacatoch Sand and 42 wells completed in the Tokio Formation during 2014 and 2015 were used to create potentiometric-surface maps of the two areas. Aquifers in the Nacatoch Sand and Tokio Formation are hereafter referred to as the Nacatoch aquifer and the Tokio aquifer, respectively.Potentiometric surfaces show that groundwater in the Nacatoch aquifer flows southeast toward the Mississippi River in northeastern Arkansas. Groundwater flow direction is towards the south and southeast in Hempstead, Little River, and Nevada Counties in southwestern Arkansas. An apparent cone of depression exists in southern Clark County and likely alters groundwater flow from a regional direction toward the depression.In southwestern Arkansas, potentiometric surfaces indicate that groundwater flow in the Tokio aquifer is towards the city of Hope. Northwest of Hope, an apparent cone of depression exists. In southwestern Pike, northwestern Nevada, and northeastern Hempstead Counties, an area of artesian flow (water levels are at or above land surface) exists.Water-level changes in wells were identified using two methods: (1) linear regression analysis of hydrographs from select wells with a minimum of 20 years of water-level data, and (2) a direct comparison between water-level measurements from 2008 and 2014–15 at each well. Of the six hydrographs analyzed in the Nacatoch aquifer, four indicated a decline in water levels. Compared to 2008 measurements, the largest rise in water levels was 35.14 feet (ft) in a well in Clark County, whereas the largest decline was 14.76 ft in a well in Nevada County, both located in southwestern Arkansas.Of the four hydrographs analyzed in the Tokio aquifer, one indicated a decline in water levels, while

Hydrogeology and results of aquifer tests in the vicinity of a hazardous-waste disposal site near Byron, Illinois

Science.gov (United States)

Kay, Robert T.; Olson, David N.; Ryan, Barbara J.

1989-01-01

The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, conducted an investigation of a Superfund Site near Byron, Illinois. The purpose of the investigation was to determine the hydrogeologic properties of the Galena-Platteville and St. Peter aquifers, the primary water-supply aquifers for domestic supply in the area. The Galena and Platteville Groups and older St. Peter Sandstone are separated by the Harmony Hill Shale Member of the Glenwood Formation. The Harmony Hill Shale Member is a semiconfining unit. Groundwater flow in the study area is from the site northwestward to the Rock River. Movement of groundwater in the dolomites is mainly through joints, fractures, and solution openings. Analysis of the Galena-Platteville aquifer-test data indicates that the calculated aquifer transmissivity ranges from 490 to 670 sq ft/day, and the calculated specific yield ranges from 0.017 to 0.140. Aquifer test data also indicate that the Galena-Platteville aquifer is heterogeneous and anisotropic. Analysis of the St. Peter aquifer-test data indicates that the calculated transmissivity of the aquifer ranges from 1,200 to 1 ,305 sq ft/day, storativity ranges from 0.000528 to 0.00128, horizontal hydraulic conductivity ranges from 2.9 to 3.1 ft/day, and leakage through the Harmony Hill Shale Member ranges from .000123 to .000217 ft/day/ft. (USGS)

Aquifer Storage Recovery (ASR) of chlorinated municipal drinking water in a confined aquifer

Science.gov (United States)

Izbicki, John A.; Petersen, Christen E.; Glotzbach, Kenneth J.; Metzger, Loren F.; Christensen, Allen H.; Smith, Gregory A.; O'Leary, David R.; Fram, Miranda S.; Joseph, Trevor; Shannon, Heather

2010-01-01

About 1.02 x 106 m3 of chlorinated municipal drinking water was injected into a confined aquifer, 94-137 m below Roseville, California, between December 2005 and April 2006. The water was stored in the aquifer for 438 days, and 2.64 x 106 m3 of water were extracted between July 2007 and February 2008. On the basis of Cl data, 35% of the injected water was recovered and 65% of the injected water and associated disinfection by-products (DBPs) remained in the aquifer at the end of extraction. About 46.3 kg of total trihalomethanes (TTHM) entered the aquifer with the injected water and 37.6 kg of TTHM were extracted. As much as 44 kg of TTHMs remained in the aquifer at the end of extraction because of incomplete recovery of injected water and formation of THMs within the aquifer by reactions with freechlorine in the injected water. Well-bore velocity log data collected from the Aquifer Storage Recovery (ASR) well show as much as 60% of the injected water entered the aquifer through a 9 m thick, high-permeability layer within the confined aquifer near the top of the screened interval. Model simulations of ground-water flow near the ASR well indicate that (1) aquifer heterogeneity allowed injected water to move rapidly through the aquifer to nearby monitoring wells, (2) aquifer heterogeneity caused injected water to move further than expected assuming uniform aquifer properties, and (3) physical clogging of high-permeability layers is the probable cause for the observed change in the distribution of borehole flow. Aquifer heterogeneity also enhanced mixing of native anoxic ground water with oxic injected water, promoting removal of THMs primarily through sorption. A 3 to 4-fold reduction in TTHM concentrations was observed in the furthest monitoring well 427 m downgradient from the ASR well, and similar magnitude reductions were observed in depth-dependent water samples collected from the upper part of the screened interval in the ASR well near the end of the extraction

Aquifer geochemistry at potential aquifer storage and recovery sites in coastal plain aquifers in the New York city area, USA

Science.gov (United States)

Brown, C.J.; Misut, P.E.

2010-01-01

The effects of injecting oxic water from the New York city (NYC) drinking-water supply and distribution system into a nearby anoxic coastal plain aquifer for later recovery during periods of water shortage (aquifer storage and recovery, or ASR) were simulated by a 3-dimensional, reactive-solute transport model. The Cretaceous aquifer system in the NYC area of New York and New Jersey, USA contains pyrite, goethite, locally occurring siderite, lignite, and locally varying amounts of dissolved Fe and salinity. Sediment from cores drilled on Staten Island and western Long Island had high extractable concentrations of Fe, Mn, and acid volatile sulfides (AVS) plus chromium-reducible sulfides (CRS) and low concentrations of As, Pb, Cd, Cr, Cu and U. Similarly, water samples from the Lloyd aquifer (Cretaceous) in western Long Island generally contained high concentrations of Fe and Mn and low concentrations of other trace elements such as As, Pb, Cd, Cr, Cu and U, all of which were below US Environmental Protection Agency (USEPA) and NY maximum contaminant levels (MCLs). In such aquifer settings, ASR operations can be complicated by the oxidative dissolution of pyrite, low pH, and high concentrations of dissolved Fe in extracted water.The simulated injection of buffered, oxic city water into a hypothetical ASR well increased the hydraulic head at the well, displaced the ambient groundwater, and formed a spheroid of injected water with lower concentrations of Fe, Mn and major ions in water surrounding the ASR well, than in ambient water. Both the dissolved O2 concentrations and the pH of water near the well generally increased in magnitude during the simulated 5-a injection phase. The resultant oxidation of Fe2+ and attendant precipitation of goethite during injection provided a substrate for sorption of dissolved Fe during the 8-a extraction phase. The baseline scenario with a low (0.001M) concentration of pyrite in aquifer sediments, indicated that nearly 190% more water

Potentiometric Surfaces in the Springfield Plateau and Ozark Aquifers of Northwestern Arkansas, Southeastern Kansas, Southwestern Missouri, and Northeastern Oklahoma, 2006

Science.gov (United States)

Gillip, Jonathan A.; Czarnecki, John B.; Mugel, Douglas N.

2008-01-01

The Springfield Plateau and Ozark aquifers are important sources of ground water in the Ozark Plateaus aquifer system. Water from these aquifers is used for agricultural, domestic, industrial, and municipal water sources. Changing water use over time in these aquifers presents a need for updated potentiometric-surface maps of the Springfield Plateau and Ozark aquifers. The Springfield Plateau aquifer consists of water-bearing Mississippian-age limestone and chert. The Ozark aquifer consists of Late Cambrian to Middle Devonian age water-bearing rocks consisting of dolostone, limestone, and sandstone. Both aquifers are complex with areally varying lithologies, discrete hydrologic units, varying permeabilities, and secondary permeabilities related to fractures and karst features. During the spring of 2006, ground-water levels were measured in 285 wells. These data, and water levels from selected lakes, rivers, and springs, were used to create potentiometric-surface maps for the Springfield Plateau and Ozark aquifers. Linear kriging was used initially to construct the water-level contours on the maps; the contours were subsequently modified using hydrologic judgment. The potentiometric-surface maps presented in this report represent ground-water conditions during the spring of 2006. During the spring of 2006, the region received less than average rainfall. Dry conditions prior to the spring of 2006 could have contributed to the observed water levels as well. The potentiometric-surface map of the Springfield Plateau aquifer shows a maximum measured water-level altitude within the study area of about 1,450 feet at a spring in Barry County, Missouri, and a minimum measured water-level altitude of 579 feet at a well in Ottawa County, Oklahoma. Cones of depression occur in Dade, Lawrence and Newton Counties in Missouri and Delaware and Ottawa Counties in Oklahoma. These cones of depression are associated with private wells. Ground water in the Springfield Plateau aquifer

Geoelectrical characterisation of basement aquifers: the case of Iberekodo, southwestern Nigeria

Science.gov (United States)

Aizebeokhai, Ahzegbobor P.; Oyeyemi, Kehinde D.

2018-03-01

Basement aquifers, which occur within the weathered and fractured zones of crystalline bedrocks, are important groundwater resources in tropical and subtropical regions. The development of basement aquifers is complex owing to their high spatial variability. Geophysical techniques are used to obtain information about the hydrologic characteristics of the weathered and fractured zones of the crystalline basement rocks, which relates to the occurrence of groundwater in the zones. The spatial distributions of these hydrologic characteristics are then used to map the spatial variability of the basement aquifers. Thus, knowledge of the spatial variability of basement aquifers is useful in siting wells and boreholes for optimal and perennial yield. Geoelectrical resistivity is one of the most widely used geophysical methods for assessing the spatial variability of the weathered and fractured zones in groundwater exploration efforts in basement complex terrains. The presented study focuses on combining vertical electrical sounding with two-dimensional (2D) geoelectrical resistivity imaging to characterise the weathered and fractured zones in a crystalline basement complex terrain in southwestern Nigeria. The basement aquifer was delineated, and the nature, extent and spatial variability of the delineated basement aquifer were assessed based on the spatial variability of the weathered and fractured zones. The study shows that a multiple-gradient array for 2D resistivity imaging is sensitive to vertical and near-surface stratigraphic features, which have hydrological implications. The integration of resistivity sounding with 2D geoelectrical resistivity imaging is efficient and enhances near-surface characterisation in basement complex terrain.

Stream-aquifer relations and the potentiometric surface of the Upper Floridan aquifer in the lower Apalachicola-Chattahoochee-Flint River basin in parts of Georgia, Florida, and Alabama, 1999-2000

Science.gov (United States)

Mosner, Melinda S.

2002-01-01

The Upper Floridan aquifer is the principal source of water for domestic and agricultural use in the lower Apalachicola-Chattahoochee-Flint (ACF) River Basin. Recent drought and increased water use have made understanding surface- and ground-water relations a priority for water-resource managers in the region. From July 1999 through August 2000, less than normal precipitation reduced streamflow in the area to less than 12 percent of average mean-daily streamflow and ground-water levels reached record or near-record lows. Effects of drought on stream-aquifer interactions in the basin were evaluated using baseflow estimation, ground-water seepage calculations, and potentiometric-surface maps. Ground-water discharge to streams, or baseflow, was estimated using three methods: field measurements, hydrograph separation, and linear regression analysis. Results were evaluated seasonally -- October 1999, April 2000, and August 2000 -- and for the period of record at four surface-water stations located on Kinchafoonee, Spring, Muckalee, and Turkey Creeks. Estimates of baseflow also were compared annually; ground-water discharge during the drought years, 1999 - 2000, was compared with ground-water discharge during a relatively wet year, 1994. Hydrograph separation indicated decreased base-flow of streams as the water level in the Upper Floridan aquifer declined. Mean-annual baseflow for Kinchafoonee, Spring, Muckalee, and Turkey Creeks ranged from 36 to 71 percent of total streamflow during the period of record. In 1994 baseflow accounted for only 37 to 56 percent of total streamflow, in 1999 baseflow comprised from 60 to 73 percent of total streamflow, and in 2000 baseflow comprised from 56 to 76 percent of streamflow. The percentage of total streamflow attributed to ground water increased during the drought, whereas other components of streamflow decreased (overland flow, interflow, and channel precipitation). Even though relative ground-water contributions were increased

Aquifer Thermal Energy Storage as an ecosystem service for Brussels, Belgium: investigating iron (hydr)oxide precipitation with reactive transport modeling

Science.gov (United States)

Anibas, Christian; Possemiers, Mathias; Huysmans, Marijke

2016-04-01

In an evolving energy system it is important that urbanized areas contribute to their own energy demands. To reduce greenhouse gas emissions sustainable energy systems with a high efficiency are required, e.g. using urban aquifers as an ecosystem service. Here the potential of seasonal aquifer thermal energy storage and recovery (ATES) for the Brussels-Capital Region, Belgium is investigated. An important shallow geologic formation in the Brussels Capital Region is the Brussels Sand formation, a 20-60 m thick phreatic aquifer. The Brussels Sand Formation is known for its potential for ATES systems, but also for its varying redox and hydraulic conditions. Important limiting factors for ATES systems in the Brussels Sand Formation therefore are the hydraulic conductivity and the geochemical composition of the groundwater. Near the redox boundary iron hydroxide precipitation can negatively influence ATES well performance due to clogging. The interactions between physical processes (e.g. particle transport and clogging in the wider proximity of the ATES well) and chemical processes (e.g. influence of the operation temperatures on precipitation processes) during ATES operation are complex but not well understood. Therefore we constructed numerical groundwater flow models in MODFLOW to estimate maximum pumping and injection rates of different hydraulic conditions and competing water uses in the Brussels Sand Formation. In further steps the thermal potential for ATES was quantified using MT3DMS and the reactive transport model PHT3D was applied to assess the effects of operating ATES systems near the redox boundary. Results show that initial mixing plays an important role in the development of iron(hydr)oxide precipitation around the ATES wells, with the highest concentrations around the cold wells. This behavior is enhanced by the temperature effect; temperature differences of ΔT≈10°C already influence the iron (hydr)oxide concentration. The initial injection into the

Using radon-222 to study coastal groundwater/surface-water interaction in the Crau coastal aquifer (southeastern France)

Science.gov (United States)

Mayer, Adriano; Nguyen, Bach Thao; Banton, Olivier

2016-11-01

Radon has been used to determine groundwater velocity and groundwater discharge into wetlands at the southern downstream boundary of the Crau aquifer, southeastern France. This aquifer constitutes an important high-quality freshwater resource exploited for agriculture, industry and human consumption. An increase in salinity occurs close to the sea, highlighting the need to investigate the water balance and groundwater behavior. Darcy velocity was estimated using radon activities in well waters according to the Hamada "single-well method" (involving comparison with radon in groundwater in the aquifer itself). Measurements done at three depths (7, 15 and 21 m) provided velocity ranging from a few mm/day to more than 20 cm/day, with highest velocities observed at the 15-m depth. Resulting hydraulic conductivities agree with the known geology. Waters showing high radon activity and high salinity were found near the presumed shoreline at 3,000 years BP, highlighting the presence of ancient saltwater. Radon activity has also been measured in canals, rivers and ponds, to trace groundwater discharges and evaluate water balance. A model of the radon spatial evolution explains the observed radon activities. Groundwater discharge to surface water is low in pond waters (4 % of total inputs) but significant in canals (55 l/m2/day).

Revised shallow and deep water-level and storage-volume changes in the Equus Beds Aquifer near Wichita, Kansas, predevelopment to 1993

Science.gov (United States)

Hansen, Cristi V.; Lanning-Rush, Jennifer L.; Ziegler, Andrew C.

2013-01-01

Beginning in the 1940s, the Wichita well field was developed in the Equus Beds aquifer in southwestern Harvey County and northwestern Sedgwick County to supply water to the city of Wichita. The decline of water levels in the aquifer was noted soon after the development of the Wichita well field began. Development of irrigation wells began in the 1960s. City and agricultural withdrawals led to substantial water-level declines. Water-level declines enhanced movement of brines from past oil and gas activities near Burrton, Kansas and enhanced movement of natural saline water from the Arkansas River into the well field area. Large chloride concentrations may limit use or require the treatment of water from the well field for irrigation or public supply. In 1993, the city of Wichita adopted the Integrated Local Water Supply Program (ILWSP) to ensure an adequate water supply for the city through 2050 and as part of its effort to effectively manage the part of the Equus Beds aquifer it uses. ILWSP uses several strategies to do this including the Equus Beds Aquifer Storage and Recovery (ASR) project. The purpose of the ASR project is to store water in the aquifer for later recovery and to help protect the aquifer from encroachment of a known oilfield brine plume near Burrton and saline water from the Arkansas River. As part of Wichita’s ASR permits, Wichita is prohibited from artificially recharging water into the aquifer in a Basin Storage area (BSA) grid cell if water levels in that cell are above the January 1940 water levels or are less than 10 feet below land surface. The map previously used for this purpose did not provide an accurate representation of the shallow water table. The revised predevelopment water-level altitude map of the shallow part of the aquifer is presented in this report. The city of Wichita’s ASR permits specify that the January 1993 water-level altitudes will be used as a lower baseline for regulating the withdrawal of artificial rechage

Long-distance electron transfer by cable bacteria in aquifer sediments

DEFF Research Database (Denmark)

Müller, Hubert; Bosch, Julian; Griebler, Christian

2016-01-01

recycling of sulfate by electron transfer over 1–2-cm distance. Sediments were taken from a hydrocarbon-contaminated aquifer, amended with iron sulfide and saturated with water, leaving the sediment surface exposed to air. Steep geochemical gradients developed in the upper 3 cm, showing a spatial separation...... recently been discovered in marine sediments to couple spatially separated redox half reactions over centimeter scales. Here we provide primary evidence that such sulfur-oxidizing cable bacteria can also be found at oxic–anoxic interfaces in aquifer sediments, where they provide a means for the direct...

Quantification of aquifer properties with surface nuclear magnetic resonance in the Platte River valley, central Nebraska, using a novel inversion method

Science.gov (United States)

Irons, Trevor P.; Hobza, Christopher M.; Steele, Gregory V.; Abraham, Jared D.; Cannia, James C.; Woodward, Duane D.

2012-01-01

Surface nuclear magnetic resonance, a noninvasive geophysical method, measures a signal directly related to the amount of water in the subsurface. This allows for low-cost quantitative estimates of hydraulic parameters. In practice, however, additional factors influence the signal, complicating interpretation. The U.S. Geological Survey, in cooperation with the Central Platte Natural Resources District, evaluated whether hydraulic parameters derived from surface nuclear magnetic resonance data could provide valuable input into groundwater models used for evaluating water-management practices. Two calibration sites in Dawson County, Nebraska, were chosen based on previous detailed hydrogeologic and geophysical investigations. At both sites, surface nuclear magnetic resonance data were collected, and derived parameters were compared with results from four constant-discharge aquifer tests previously conducted at those same sites. Additionally, borehole electromagnetic-induction flowmeter data were analyzed as a less-expensive surrogate for traditional aquifer tests. Building on recent work, a novel surface nuclear magnetic resonance modeling and inversion method was developed that incorporates electrical conductivity and effects due to magnetic-field inhomogeneities, both of which can have a substantial impact on the data. After comparing surface nuclear magnetic resonance inversions at the two calibration sites, the nuclear magnetic-resonance-derived parameters were compared with previously performed aquifer tests in the Central Platte Natural Resources District. This comparison served as a blind test for the developed method. The nuclear magnetic-resonance-derived aquifer parameters were in agreement with results of aquifer tests where the environmental noise allowed data collection and the aquifer test zones overlapped with the surface nuclear magnetic resonance testing. In some cases, the previously performed aquifer tests were not designed fully to characterize

Kinetics and Efficiency of H2O2 Activation by Iron-Containing Minerals and Aquifer Materials

Science.gov (United States)

Pham, Anh Le-Tuan; Doyle, Fiona M.; Sedlak, David L.

2014-01-01

To gain insight into factors that control H2O2 persistence and ˙OH yield in H2O2-based in situ chemical oxidation systems, the decomposition of H2O2 and transformation of phenol were investigated in the presence of iron-containing minerals and aquifer materials. Under conditions expected during remediation of soil and groundwater, the stoichiometric efficiency, defined as the amount of phenol transformed per mole of H2O2 decomposed, varied from 0.005 to 0.28%. Among the iron-containing minerals, iron oxides were 2 to 10 times less efficient in transforming phenol than iron-containing clays and synthetic iron-containing catalysts. In both iron-containing mineral and aquifer materials systems, the stoichiometric efficiency was inversely correlated with the rate of H2O2 decomposition. In aquifer materials systems, the stoichiometric efficiency was also inversely correlated with the Mn content, consistent with the fact that the decomposition of H2O2 on manganese oxides does not produce ˙OH. Removal of iron and manganese oxide coatings from the surface of aquifer materials by extraction with citrate-bicarbonate-dithionite slowed the rate of H2O2 decomposition on aquifer materials and increased the stoichiometric efficiency. In addition, the presence of 2 mM of dissolved SiO2 slowed the rate of H2O2 decomposition on aquifer materials by over 80% without affecting the stoichiometric efficiency. PMID:23047055

Transient flow between aquifers and surface water: analytically derived field-scale hydraulic heads and fluxes

Directory of Open Access Journals (Sweden)

G. H. de Rooij

2012-03-01

Full Text Available The increasing importance of catchment-scale and basin-scale models of the hydrological cycle makes it desirable to have a simple, yet physically realistic model for lateral subsurface water flow. As a first building block towards such a model, analytical solutions are presented for horizontal groundwater flow to surface waters held at prescribed water levels for aquifers with parallel and radial flow. The solutions are valid for a wide array of initial and boundary conditions and additions or withdrawals of water, and can handle discharge into as well as lateral infiltration from the surface water. Expressions for the average hydraulic head, the flux to or from the surface water, and the aquifer-scale hydraulic conductivity are developed to provide output at the scale of the modelled system rather than just point-scale values. The upscaled conductivity is time-variant. It does not depend on the magnitude of the flux but is determined by medium properties as well as the external forcings that drive the flow. For the systems studied, with lateral travel distances not exceeding 10 m, the circular aquifers respond very differently from the infinite-strip aquifers. The modelled fluxes are sensitive to the magnitude of the storage coefficient. For phreatic aquifers a value of 0.2 is argued to be representative, but considerable variations are likely. The effect of varying distributions over the day of recharge damps out rapidly; a soil water model that can provide accurate daily totals is preferable over a less accurate model hat correctly estimates the timing of recharge peaks.

The difference between the potentiometric surfaces of the lower Patapsco aquifer in southern Maryland, September 1990 and September 2007

Science.gov (United States)

Curtin, Stephen E.; Andreasen, David C.; Staley, Andrew W.

2009-01-01

This report presents a map showing the change in the potentiometric surface of the lower Patapsco aquifer in the Patapsco Formation of Early Cretaceous age in Southern Maryland for September 1990 and September 2007. The map, based on water-level measurements in 45 wells, shows that the change of the potentiometric surface during the 17-year period ranged from increases of 19 feet at Indian Head and 6 feet near the outcrop area in Glen Burnie, to declines of 41 feet at Arnold, 45 feet at Severndale, 68 feet at Crofton Meadows, 77 feet at Waldorf, 76 feet at La Plata, 28 feet at the Morgantown power plant, and 35 feet at the Swan Point subdivision south of Morgantown.

Methane oxidation and methane fluxes in the ocean surface layer and deep anoxic waters

Science.gov (United States)

Ward, B. B.; Kilpatrick, K. A.; Novelli, P. C.; Scranton, M. I.

1987-01-01

Measured biological oxidation rates of methane in near-surface waters of the Cariaco Basin are compared with the diffusional fluxes computed from concentration gradients of methane in the surface layer. Methane fluxes and oxidation rates were investigated in surface waters, at the oxic/anoxic interface, and in deep anoxic waters. It is shown that the surface-waters oxidation of methane is a mechanism which modulates the flux of methane from marine waters to the atmosphere.

Oxidation of hydrogen-passivated silicon surfaces by scanning near-field optical lithography using uncoated and aluminum-coated fiber probes

DEFF Research Database (Denmark)

Madsen, Steen; Bozhevolnyi, Sergey I.; Birkelund, Karen

1997-01-01

Optically induced oxidation of hydrogen-passivated silicon surfaces using a scanning near-field optical microscope was achieved with both uncoated and aluminum-coated fiber probes. Line scans on amorphous silicon using uncoated fiber probes display a three-peak profile after etching in potassium...... hydroxide. Numerical simulations of the electromagnetic field around the probe-sample interaction region are used to explain the experimental observations. With an aluminum-coated fiber probe, lines of 35 nm in width were transferred into the amorphous silicon layer. (C) 1997 American Institute of Physics....

Geologic framework, regional aquifer properties (1940s-2009), and spring, creek, and seep properties (2009-10) of the upper San Mateo Creek Basin near Mount Taylor, New Mexico

Science.gov (United States)

Langman, Jeff B.; Sprague, Jesse E.; Durall, Roger A.

2012-01-01

The U.S. Geological Survey, in cooperation with the U.S. Forest Service, examined the geologic framework, regional aquifer properties, and spring, creek, and seep properties of the upper San Mateo Creek Basin near Mount Taylor, which contains areas proposed for exploratory drilling and possible uranium mining on U.S. Forest Service land. The geologic structure of the region was formed from uplift of the Zuni Mountains during the Laramide Orogeny and the Neogene volcanism associated with the Mount Taylor Volcanic Field. Within this structural context, numerous aquifers are present in various Paleozoic and Mesozoic sedimentary formations and the Quaternary alluvium. The distribution of the aquifers is spatially variable because of the dip of the formations and erosion that produced the current landscape configuration where older formations have been exhumed closer to the Zuni Mountains. Many of the alluvial deposits and formations that contain groundwater likely are hydraulically connected because of the solid-matrix properties, such as substantive porosity, but shale layers such as those found in the Mancos Formation and Chinle Group likely restrict vertical flow. Existing water-level data indicate topologically downgradient flow in the Quaternary alluvium and indiscernible general flow patterns in the lower aquifers. According to previously published material and the geologic structure of the aquifers, the flow direction in the lower aquifers likely is in the opposite direction compared to the alluvium aquifer. Groundwater within the Chinle Group is known to be confined, which may allow upward migration of water into the Morrison Formation; however, confining layers within the Chinle Group likely retard upward leakage. Groundwater was sodium-bicarbonate/sulfate dominant or mixed cation-mixed anion with some calcium/bicarbonate water in the study area. The presence of the reduction/oxidation-sensitive elements iron and manganese in groundwater indicates reducing

The Thermodynamics of Selenium Minerals in Near-Surface Environments

Directory of Open Access Journals (Sweden)

Vladimir Krivovichev

2017-10-01

Full Text Available Selenium compounds are relatively rare as minerals; there are presently only 118 known mineral species. This work is intended to codify and systematize the data of mineral systems and the thermodynamics of selenium minerals, which are unstable (selenides or formed in near-surface environments (selenites, where the behavior of selenium is controlled by variations of the redox potential and the acidity of solutions at low temperatures and pressures. These parameters determine the migration of selenium and its precipitation as various solid phases. All selenium minerals are divided into four groups—native selenium, oxide, selenides, and oxysalts—anhydrous selenites (I and hydrous selenites and selenates (II. Within each of the groups, minerals are codified according to the minimum number of independent elements necessary to define the composition of the mineral system. Eh–pH diagrams were calculated and plotted using the Geochemist’s Workbench (GMB 9.0 software package. The Eh–pH diagrams of the Me–Se–H2O systems (where Me = Co, Ni, Fe, Cu, Pb, Zn, Cd, Hg, Ag, Bi, As, Sb, Al and Ca were plotted for the average contents of these elements in acidic waters in the oxidation zones of sulfide deposits. The possibility of the formation of Zn, Cd, Ag and Hg selenites under natural oxidation conditions in near surface environments is discussed.

Changes in the Regional Groundwater Aquifer and Potential Impacts on Surface Waters in Central Zealand, Denmark

DEFF Research Database (Denmark)

Thorn, Paul

The regional, confined aquifer on the island of Zealand, in eastern Denmark, is the primary aquifer used for large-scale abstraction for the supplies of all larger cities, including Roskilde and the greater Copenhagen metropolitan area. Large-scale groundwater abstraction from this aquifer...... in the area near Lejre Denmark (approximately 15km to the SW of Roskilde) began in 1937, exporting approximately 18 million m3 of water per year to supply the city of Copenhagen. After abstraction began, streams in the area were observed to go dry after extended periods without precipitation, where......, wetlands and lakes in the area. The results show that there was a significant impact on the regional groundwater aquifer in the Langvad river catchment, with groundwater as much as 17m lower in 1987 from 1936 (pre-abstraction). However, in the Elverdam river catchment, the levels remained virtually...

Comparing flowmeter, aquifer test, and surface nuclear magnetic resonance data in Central Nebraska

Science.gov (United States)

Irons, T.; Abraham, J. D.; Cannia, J. C.; Steele, G.; Hobza, C. M.; Li, Y.; McKenna, J. R.

2011-12-01

Traditionally the only means of estimating the hydraulic properties of aquifers has involved drilling boreholes. The logistical and economic requirements of aquifer tests has limited the ability of hydrologists to construct the detailed groundwater models needed for resource management. As such, water policy decisions are often based on sparse aquifer tests combined with geologic interpretation and extrapolation. When dealing with complicated groundwater systems these extrapolations are often not accurate at the scale required to characterize the groundwater system, and additional information is needed to make better informed resource decisions. Surface nuclear magnetic resonance (SNMR) is a geophysical technique which allows for non-invasive estimates of hydraulic permeability and transmissivity. Protons in a volume of liquid water form a weak bulk magnetic moment as they align and precess about the earth's magnetic field. This moment is too small to be measured directly but may be observed by tipping it away from equilibrium using radio-frequency pulses oscillating at the same frequency as its precession (the Larmor frequency). After a short tipping pulse, the moment continues to precess around the static field, although at a tipped angle, slowly returning to its equilibrium state. The decay of these spinning magnetic moments can be observed inductively using loops of wire on the surface of the earth. In the simplest experiment a time series is recorded after a single tipping pulse. By varying the strength of the tipping pulse, different regions of the subsurface can be probed. The amplitude of the signal is directly proportional to the amount of water in the investigated volume. The decay rate of the signal is related to pore geometry and interconnectivity and can be used to estimate hydraulic conductivity. However, this relationship cannot be universally defined as it is affected by additional factors including the mineralogy of the host rock and homogeneity of

Carbonate aquifers

Science.gov (United States)

Cunningham, Kevin J.; Sukop, Michael; Curran, H. Allen

2012-01-01

Only limited hydrogeological research has been conducted using ichnology in carbonate aquifer characterization. Regardless, important applications of ichnology to carbonate aquifer characterization include its use to distinguish and delineate depositional cycles, correlate mappable biogenically altered surfaces, identify zones of preferential groundwater flow and paleogroundwater flow, and better understand the origin of ichnofabric-related karst features. Three case studies, which include Pleistocene carbonate rocks of the Biscayne aquifer in southern Florida and Cretaceous carbonate strata of the Edwards–Trinity aquifer system in central Texas, demonstrate that (1) there can be a strong relation between ichnofabrics and groundwater flow in carbonate aquifers and (2) ichnology can offer a useful methodology for carbonate aquifer characterization. In these examples, zones of extremely permeable, ichnofabric-related macroporosity are mappable stratiform geobodies and as such can be represented in groundwater flow and transport simulations.

Evaluation of long-term water-level declines in basalt aquifers near Mosier, Oregon

Science.gov (United States)

Burns, Erick R.; Morgan, David S.; Lee, Karl K.; Haynes, Jonathan V.; Conlon, Terrence D.

2012-01-01

The Mosier area lies along the Columbia River in northwestern Wasco County between the cities of Hood River and The Dalles, Oregon. Major water uses in the area are irrigation, municipal supply for the city of Mosier, and domestic supply for rural residents. The primary source of water is groundwater from the Columbia River Basalt Group (CRBG) aquifers that underlie the area. Concerns regarding this supply of water arose in the mid-1970s, when groundwater levels in the orchard tract area began to steadily decline. In the 1980s, the Oregon Water Resources Department (OWRD) conducted a study of the aquifer system, which resulted in delineation of an administrative area where parts of the Pomona and Priest Rapids aquifers were withdrawn from further appropriations for any use other than domestic supply. Despite this action, water levels continued to drop at approximately the same, nearly constant annual rate of about 4 feet per year, resulting in a current total decline of between 150 and 200 feet in many wells with continued downward trends. In 2005, the Mosier Watershed Council and the Wasco Soil and Water Conservation District began a cooperative investigation of the groundwater system with the U.S. Geological Survey. The objectives of the study were to advance the scientific understanding of the hydrology of the basin, to assess the sustainability of the water supply, to evaluate the causes of persistent groundwater-level declines, and to evaluate potential management strategies. An additional U.S. Geological Survey objective was to advance the understanding of CRBG aquifers, which are the primary source of water across a large part of Oregon, Washington, and Idaho. In many areas, significant groundwater level declines have resulted as these aquifers were heavily developed for agricultural, municipal, and domestic water supplies. Three major factors were identified as possible contributors to the water-level declines in the study area: (1) pumping at rates that

Dynamics of arsenic adsorption in the targeted arsenic-safe aquifers in Matlab, south-eastern Bangladesh: Insight from experimental studies

International Nuclear Information System (INIS)

Robinson, Clare; Broemssen, Mattias von; Bhattacharya, Prosun; Haeller, Sara; Biven, Annelie; Hossain, Mohammed; Jacks, Gunnar; Ahmed, Kazi Matin; Hasan, M. Aziz; Thunvik, Roger

2011-01-01

Research highlights: → Adsorption behaviour of shallow oxidized sediments from Matlab Region in SE Bangladesh is investigated. → Oxidized sediments have a high capacity to adsorb arsenic. → Adsorption capacity will be reduced by high concentration of reactive organic C. → Monitoring of groundwater quality over 5 year period shows relatively stable water chemistry. - Abstract: Targeting shallow low-As aquifers based on sediment colour may be a viable solution for supplying As-safe drinking water to rural communities in some regions of Bangladesh and West Bengal in India. The sustainability of this solution with regard to the long-term risk of As-safe oxidized aquifers becoming enriched with As needs to be assessed. This study focuses on the adsorption behaviour of shallow oxidized sediments from Matlab Region, Bangladesh, and their capacity to attenuate As if cross-contamination of the oxidized aquifers occurs. Water quality analyses of samples collected from 20 tube-wells in the region indicate that while there may be some seasonal variability, the groundwater chemistry in the reduced and oxidized aquifers was relatively stable from 2004 to 2009. Although sediment extractions indicate a relatively low amount of As in the oxidized sediments, below 2.5 mg kg -1 , batch isotherm experiments show that the sediments have a high capacity to adsorb As. Simulations using a surface complexation model that considers adsorption to amorphous Fe(III) oxide minerals only, under-predict the experimental isotherms. This suggests that a large proportion of the adsorption sites in the oxidized sediments may be associated with crystalline Fe(III) oxides, Mn(IV) and Al(III) oxides, and clay minerals. Replicate breakthrough column experiments conducted with lactose added to the influent solution demonstrate that the high adsorption capacity of the oxidized sediments may be reduced if water drawn down into the oxidized aquifers contains high levels of electron donors such as

Important radionuclides and their sensitivity for groundwater pathway of a hypothetical near-surface disposal facility

Energy Technology Data Exchange (ETDEWEB)

Park, J. W.; Chang, K.; Kim, C. L. [Nuclear Enviroment Technology Institute, Taejon (Korea, Republic of)

2001-04-01

A radiological safety assessment was performed for a hypothetical near-surface radioactive waste repository as a simple screening calculation to identify important nuclides and to provide insights on the data needs for a successful demonstration of compliance. Individual effective doses were calculated for a conservative groundwater pathway scenario considering well drilling near the site boundary. Sensitivity of resulting ingestion dose to input parameter values was also analyzed using Monte Carlo sampling. Considering peak dose rate and assessment timescale, C-14 and I-129 were identified as important nuclides and U-235 and U-238 as potentially important nuclides. For C-14, the does was most sensitive to Darcy velocity in aquifer. The distribution coefficient showed high degree of sensitivity for I-129 release.

Important radionuclides and their sensitivity for groundwater pathway of a hypothetical near-surface disposal facility

International Nuclear Information System (INIS)

Park, J. W.; Chang, K.; Kim, C. L.

2001-01-01

A radiological safety assessment was performed for a hypothetical near-surface radioactive waste repository as a simple screening calculation to identify important nuclides and to provide insights on the data needs for a successful demonstration of compliance. Individual effective doses were calculated for a conservative groundwater pathway scenario considering well drilling near the site boundary. Sensitivity of resulting ingestion dose to input parameter values was also analyzed using Monte Carlo sampling. Considering peak dose rate and assessment timescale, C-14 and I-129 were identified as important nuclides and U-235 and U-238 as potentially important nuclides. For C-14, the does was most sensitive to Darcy velocity in aquifer. The distribution coefficient showed high degree of sensitivity for I-129 release

The difference between the potentiometric surfaces of the Upper Patapsco aquifer in southern Maryland, September 1990 and September 2009

Science.gov (United States)

Curtin, Stephen E.; Andreasen, David C.; Staley, Andrew W.

2010-01-01

This report presents a map showing the change in the potentiometric surface of the upper Patapsco aquifer in the Patapsco Formation of Early Cretaceous age in Southern Maryland between September 1990 and September 2009. The map, based on water level differences obtained from 33 wells, shows that during the 19-year period, the change in the potentiometric surface ranged from zero at the edge of the outcrop area in northern Anne Arundel County to a decline of 20 feet at Broad Creek, 16 feet near Arnold, 32 feet at Waldorf, 37 feet at the Chalk Point power plant, and 43 feet at Lexington Park. The map also shows well yield in gallons per day for 2008 at wells or well fields.

Ground-water quality of the surficial aquifer system and the upper Floridan Aquifer, Ocala National Forest and Lake County, Florida, 1990-99

Science.gov (United States)

Adamski, J.C.; Knowles, Leel

2001-01-01

Data from 217 ground-water samples were statistically analyzed to assess the water quality of the surficial aquifer system and Upper Floridan aquifer in the Ocala National Forest and Lake County, Florida. Samples were collected from 49 wells tapping the surficial aquifer system, 141 wells tapping the Upper Floridan aquifer, and from 27 springs that discharge water from the Upper Floridan aquifer. A total of 136 samples was collected by the U.S. Geological Survey from 1995 through 1999. These data were supplemented with 81 samples collected by the St. Johns River Water Management District and Lake County Water Resources Management from 1990 through 1998. In general, the surficial aquifer system has low concentrations of total dissolved solids (median was 41 milligrams per liter) and major ions. Water quality of the surficial aquifer system, however, is not homogeneous throughout the study area. Concentrations of total dissolved solids, many major ions, and nutrients are greater in samples from Lake County outside the Ocala National Forest than in samples from within the Forest. These results indicate that the surficial aquifer system in Lake County outside the Ocala National Forest probably is being affected by agricultural and (or) urban land-use practices. High concentrations of dissolved oxygen (less than 0.1 to 8.2 milligrams per liter) in the surficial aquifer system underlying the Ocala National Forest indicate that the aquifer is readily recharged by precipitation and is susceptible to surface contamination. Concentrations of total dissolved solids were significantly greater in the Upper Floridan aquifer (median was 182 milligrams per liter) than in the surficial aquifer system. In general, water quality of the Upper Floridan aquifer was homogeneous, primarily being a calcium or calciummagnesium- bicarbonate water type. Near the St. Johns River, the water type of the Upper Floridan aquifer is sodium-chloride, corresponding to an increase in total dissolved

Iron oxidation kinetics and phosphate immobilization along the flow-path from groundwater into surface water

Science.gov (United States)

van der Grift, B.; Rozemeijer, J. C.; Griffioen, J.; van der Velde, Y.

2014-11-01

The retention of phosphorus in surface waters through co-precipitation of phosphate with Fe-oxyhydroxides during exfiltration of anaerobic Fe(II) rich groundwater is not well understood. We developed an experimental field set-up to study Fe(II) oxidation and P immobilization along the flow-path from groundwater into surface water in an agricultural experimental catchment of a small lowland river. We physically separated tube drain effluent from groundwater discharge before it entered a ditch in an agricultural field. Through continuous discharge measurements and weekly water quality sampling of groundwater, tube drain water, exfiltrated groundwater, and surface water, we investigated Fe(II) oxidation kinetics and P immobilization processes. The oxidation rate inferred from our field measurements closely agreed with the general rate law for abiotic oxidation of Fe(II) by O2. Seasonal changes in climatic conditions affected the Fe(II) oxidation process. Lower pH and lower temperatures in winter (compared to summer) resulted in low Fe oxidation rates. After exfiltration to the surface water, it took a couple of days to more than a week before complete oxidation of Fe(II) is reached. In summer time, Fe oxidation rates were much higher. The Fe concentrations in the exfiltrated groundwater were low, indicating that dissolved Fe(II) is completely oxidized prior to inflow into a ditch. While the Fe oxidation rates reduce drastically from summer to winter, P concentrations remained high in the groundwater and an order of magnitude lower in the surface water throughout the year. This study shows very fast immobilization of dissolved P during the initial stage of the Fe(II) oxidation process which results in P-depleted water before Fe(II) is completely depleted. This cannot be explained by surface complexation of phosphate to freshly formed Fe-oxyhydroxides but indicates the formation of Fe(III)-phosphate precipitates. The formation of Fe(III)-phosphates at redox gradients

Iodine-129 in the Snake River Plain Aquifer at and Near the Idaho National Laboratory, Idaho, 2003 and 2007

Science.gov (United States)

Bartholomay, Roy C.

2009-01-01

From 1953 to 1988, wastewater containing approximately 0.94 curies of iodine-129 (129I) was generated at the Idaho National Laboratory (INL) in southeastern Idaho. Almost all of this wastewater was discharged at or near the Idaho Nuclear Technology and Engineering Center (INTEC) on the INL site. Most of the wastewater was discharged directly into the eastern Snake River Plain aquifer through a deep disposal well until 1984; however, some wastewater also was discharged into unlined infiltration ponds or leaked from distribution systems below the INTEC. In 2003, the U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, collected samples for 129I from 36 wells used to monitor the Snake River Plain aquifer, and from one well used to monitor a perched zone at the INTEC. Concentrations of 129I in the aquifer ranged from 0.0000066 +- 0.0000002 to 0.72 +- 0.051 picocuries per liter (pCi/L). Many wells within a 3-mile radius of the INTEC showed decreases of as much as one order of magnitude in concentration from samples collected during 1990-91, and all of the samples had concentrations less than the Environmental Protection Agency's Maximum Contaminant Level (MCL) of 1 pCi/L. The average concentration of 129I in 19 wells sampled during both collection periods decreased from 0.975 pCi/L in 1990-91 to 0.249 pCi/L in 2003. These decreases are attributed to the discontinuation of disposal of 129I in wastewater after 1988 and to dilution and dispersion in the aquifer. Although water from wells sampled in 2003 near the INTEC showed decreases in concentrations of 129I compared with data collected in 1990-91, some wells south and east of the Central Facilities Area, near the site boundary, and south of the INL showed slight increases. These slight increases may be related to variable discharge rates of wastewater that eventually moved to these well locations as a mass of water from a particular disposal period. In 2007, the USGS collected samples for

Flow of river water into a Karstic limestone aquifer. 1. Tracing the young fraction in groundwater mixtures in the Upper Floridan Aquifer near Valdosta, Georgia

International Nuclear Information System (INIS)

Plummer, L.N.; Busenberg, E.; McConnell, J.B.; Drenkard, S.; Schlosser, P.; Michel, R.L.

1998-01-01

The quality of water in the Upper Floridan aquifer near Valdosta, Georgia is affected locally by discharge of Withlacoochee River water through sinkholes in the river bed. Data on transient tracers and other dissolved substances, including Cl - , 3 H, tritiogenic helium-3 ( 3 He), chlorofluorocarbons (CFC-11, CFC-12, CFC-113), organic C (DOC), O 2 (DO), H 2 S, CH 4 , δ 18 O, δD, and 14 C were investigated as tracers of Withlacoochee River water in the Upper Floridan aquifer. The concentrations of all tracers were affected by dilution and mixing. Dissolved Cl - , δ 18 O, δD, CFC-12, and the quantity ( 3 H+ 3 He) are stable in water from the Upper Floridan aquifer, whereas DOC, DO, H 2 S, CH 4 , 14 C, CFC-11, and CFC-113 are affected by microbial degradation and other geochemical processes occurring within the aquifer. Groundwater mixing fractions were determined by using dissolved Cl - and δ 18 O data, recognizing 3 end-member water types in the groundwater mixtures: (1) Withlacoochee River water (δ 18 O=-2.5±0.3per thousand, Cl - =12.2±2 mg/l), (2) regional infiltration water (δ 18 O=-4.2±0.1per thousand, Cl - =2.3±0.1 mg/l), and (3) regional paleowater resident in the Upper Floridan aquifer (δ 18 O=-3.4±0.1per thousand, Cl - =2.6±0.1 mg/l) (uncertainties are ±1σ). Error simulation procedures were used to define uncertainties in mixing fractions. Fractions of river water in groundwater range from 0 to 72% and average 10%. The influence of river-water discharge on the quality of water in the Upper Floridan aquifer was traced from the sinkhole area on the Withlacoochee River 25 km SE in the direction of regional groundwater flow. Infiltration of water is most significant to the N and NW of Valdosta, but becomes negligible to the S and SE in the direction of general thickening of post-Eocene confining beds overlying the Upper Floridan aquifer. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

Flow of river water into a Karstic limestone aquifer. 1. Tracing the young fraction in groundwater mixtures in the Upper Floridan Aquifer near Valdosta, Georgia

Energy Technology Data Exchange (ETDEWEB)

Plummer, L.N.; Busenberg, E. [U.S. Geological Survey, 432 National Center, Reston, VA (United States); McConnell, J.B. [U.S. Geological Survey, 3039 Amwiler Rd., Atlanta, GA (United States); Drenkard, S.; Schlosser, P. [Lamont-Doherty Earth Observatory of Columbia University, 61 Route 9W, Palisades, NY (United States); Michel, R.L. [U.S. Geological Survey, Mail Stop 434, 345 Middlefield Road, Menlo Park, CA (United States)

1998-11-01

he quality of water in the Upper Floridan aquifer near Valdosta, Georgia is affected locally by discharge of Withlacoochee River water through sinkholes in the river bed. Data on transient tracers and other dissolved substances, including Cl{sup -}, {sup 3}H, tritiogenic helium-3 ({sup 3}He), chlorofluorocarbons (CFC-11, CFC-12, CFC-113), organic C (DOC), O{sub 2} (DO), H{sub 2}S, CH{sub 4}, {delta}{sup 18}O, {delta}D, and {sup 14}C were investigated as tracers of Withlacoochee River water in the Upper Floridan aquifer. The concentrations of all tracers were affected by dilution and mixing. Dissolved Cl{sup -}, {delta}{sup 18}O, {delta}D, CFC-12, and the quantity ({sup 3}H+{sup 3}He) are stable in water from the Upper Floridan aquifer, whereas DOC, DO, H{sub 2}S, CH{sub 4}, {sup 14}C, CFC-11, and CFC-113 are affected by microbial degradation and other geochemical processes occurring within the aquifer. Groundwater mixing fractions were determined by using dissolved Cl{sup -} and {delta}{sup 18}O data, recognizing 3 end-member water types in the groundwater mixtures: (1) Withlacoochee River water ({delta}{sup 18}O=-2.5{+-}0.3per thousand, Cl{sup -}=12.2{+-}2 mg/l), (2) regional infiltration water ({delta}{sup 18}O=-4.2{+-}0.1per thousand, Cl{sup -}=2.3{+-}0.1 mg/l), and (3) regional paleowater resident in the Upper Floridan aquifer ({delta}{sup 18}O=-3.4{+-}0.1per thousand, Cl{sup -}=2.6{+-}0.1 mg/l) (uncertainties are {+-}1{sigma}). Error simulation procedures were used to define uncertainties in mixing fractions. Fractions of river water in groundwater range from 0 to 72% and average 10%. The influence of river-water discharge on the quality of water in the Upper Floridan aquifer was traced from the sinkhole area on the Withlacoochee River 25 km SE in the direction of regional groundwater flow. Infiltration of water is most significant to theN and NW of Valdosta, but becomes negligible to the S and SE in the direction of general thickening of post-Eocene confining

VULNERABILITY AND RISK OF CONTAMINATION KARSTIC AQUIFERS

Directory of Open Access Journals (Sweden)

Yameli Aguilar

2013-08-01

Full Text Available Karstic systems occupy nearly 20% of the surface of the earth and are inhabited by numerous human communities. Karstic aquifers are the most exposed to pollution from human activities. Pollution of karstic aquifers is a severe environmental problem worldwide.  In order to face the vulnerability of karstic aquifers to pollution, researchers have created a diversity of study approaches and models, each one having their own strengths and weaknesses depending on the discipline from which they were originated, thus requiring a thorough discussion within the required multidisciplinary character. The objective of this article was to analyze the theoretical and methodological approaches applied to the pollution of karstic aquifers. The European hydrogeological, land evaluation, hydropedological and a geographic approach were analyzed. The relevance of a geomorphological analysis as a cartographic basis for the analysis of vulnerability and risks were emphasized. From the analysis of models, approaches and methodologies discussed the following recommendation is made: to form an interdisciplinary work team, to elaborate a conceptual model according to the site and the working scale and to e, apply and validate the model.

Aquifer Characterization from Surface Geo-electrical Method, western coast of Maharashtra, India

Science.gov (United States)

DAS, A.; Maiti, D. S.

2017-12-01

Knowledge of aquifer parameters are necessary for managing groundwater amenity. These parameters are evaluated through pumping tests bring off from bore wells. But it is quite expensive as well as time consuming to carry out pumping tests at various sites and sometimes it is difficult to find bore hole at every required site. Therefore, an alternate method is put forward in which the aquifer parameters are evaluated from surface geophysical method. In this method, vertical electrical sounding (VES) with Schlumberger configuration were accomplished in 85 stations over Sindhudurg district. Sindhudurg district is located in the Konkan region of Maharashtra state, India. The district is located between north latitude 15°37' and 16° 40' and east longitude 73° 19' and 74° 13'. The area is having hard rock and acute groundwater problem. In this configuration, we have taken the maximum current electrode spacing of 200 m for every vertical electrical sounding (VES). Geo-electrical sounding data (true resistivity and thickness) is interpreted through resistivity inversion approach. The required parameters are achieved through resistivity inversion technique from which the aquifer variables (D-Z parameters, mean resistivity, hydraulic conductivity, transmissivity, and coefficient of anisotropy) are calculated by using some empirical formulae. Cross-correlation investigation has been done between these parameters, which eventually used to characterize the aquifer over the study area. At the end, the contour plot for these aquifer parameters has been raised which reveals the detailed distribution of aquifer parameters throughout the study area. From contour plot, high values of longitudinal conductance, hydraulic conductivity and transmissivity are demarcate over Kelus, Vengurle, Mochemar and Shiroda villages. This may be due to intrusion of saline water from Arabian sea. From contour trends, the aquifers are characterized from which the groundwater resources could be

Digital surfaces and thicknesses of selected hydrogeologic units of the Floridan aquifer system in Florida and parts of Georgia, Alabama, and South Carolina

Science.gov (United States)

Williams, Lester J.; Dixon, Joann F.

2015-01-01

Digital surfaces and thicknesses of selected hydrogeologic units of the Floridan aquifer system were developed to define an updated hydrogeologic framework as part of the U.S. Geological Survey Groundwater Resources Program. The dataset contains structural surfaces depicting the top and base of the aquifer system, its major and minor hydrogeologic units and zones, geophysical marker horizons, and the altitude of the 10,000-milligram-per-liter total dissolved solids boundary that defines the approximate fresh and saline parts of the aquifer system. The thicknesses of selected major and minor units or zones were determined by interpolating points of known thickness or from raster surface subtraction of the structural surfaces. Additional data contained include clipping polygons; regional polygon features that represent geologic or hydrogeologic aspects of the aquifers and the minor units or zones; data points used in the interpolation; and polygon and line features that represent faults, boundaries, and other features in the aquifer system.

Combined geophysical methods for mapping infiltration pathways at the Aurora Water Aquifer recharge and recovery site

Science.gov (United States)

Jasper, Cameron A.

Although aquifer recharge and recovery systems are a sustainable, decentralized, low cost, and low energy approach for the reclamation, treatment, and storage of post- treatment wastewater, they can suffer from poor infiltration rates and the development of a near-surface clogging layer within infiltration ponds. One such aquifer recharge and recovery system, the Aurora Water site in Colorado, U.S.A, functions at about 25% of its predicted capacity to recharge floodplain deposits by flooding infiltration ponds with post-treatment wastewater extracted from river bank aquifers along the South Platte River. The underwater self-potential method was developed to survey self-potential signals at the ground surface in a flooded infiltration pond for mapping infiltration pathways. A method for using heat as a groundwater tracer within the infiltration pond used an array of in situ high-resolution temperature sensing probes. Both relatively positive and negative underwater self-potential anomalies are consistent with observed recovery well pumping rates and specific discharge estimates from temperature data. Results from electrical resistivity tomography and electromagnetics surveys provide consistent electrical conductivity distributions associated with sediment textures. A lab method was developed for resistivity tests of near-surface sediment samples. Forward numerical modeling synthesizes the geophysical information to best match observed self- potential anomalies and provide permeability distributions, which is important for effective aquifer recharge and recovery system design, and optimization strategy development.

Radon measurements over a natural-gas contaminated aquifer

International Nuclear Information System (INIS)

Palacios, D.; Fusella, E.; Avila, Y.; Salas, J.; Teixeira, D.; Fernández, G.; Salas, A.; Sajo-Bohus, L.; Greaves, E.; Barros, H.; Bolívar, M.; Regalado, J.

2013-01-01

Radon and thoron concentrations in soil pores in a gas production region of the Anzoategui State, Venezuela, were determined by active and passive methods. In this region, water wells are contaminated by natural gas and gas leaks exist in the nearby river. Based on soil gas Radon data surface hydrocarbon seeps were identified. Radon and thoron concentration maps show anomalously high values near the river gas leaks decreasing in the direction of water wells where natural gas is also detected. The area where the highest concentrations of 222 Rn were detected seems to indicate the surface projection of the aquifer contaminated with natural gas. The Radon/Thoron ratio revealed a micro-localized anomaly, indicating the area where the gas comes from deep layers of the subsoil. The radon map determined by the passive method showed a marked positive anomaly around abandoned gas wells. The high anomalous Radon concentration localized near the trails of ascending gas bubbles at the river indicates the zone trough where natural gases are ascending with greater ease, associated with a deep geological fault, being this the main source of methane penetration into the aquifer. It is suggested that the source of the natural gas may be due to leaks at deep sites along the structure of some of the abandoned wells located at the North-East of the studied area. - Highlights: ► High Radon/Thoron ratios were localized near the natural-gas emanations in a river. ► Natural gases are ascending trough a deep geological fault. ► Apparently, the radon anomaly shows the site where natural gas enters the aquifer. ► Natural gas source may be related to leaks in the structure of abandoned gas wells

Assessing the Vulnerability of Public-Supply Wells to Contamination: Floridan Aquifer System Near Tampa, Florida

Science.gov (United States)

Jagucki, Martha L.; Katz, Brian G.; Crandall, Christy A.; Eberts, Sandra M.

2009-01-01

This fact sheet highlights findings from the vulnerability study of a public-supply well in Temple Terrace, Florida, northeast of Tampa. The well selected for study typically produces water at the rate of 700 gallons per minute from the Upper Floridan aquifer. Water samples were collected at the public-supply well and at monitoring wells installed in or near the simulated zone of contribution to the supply well. Samples of untreated water from the public-supply wellhead contained the undesirable constituents nitrate, arsenic, uranium, radon-222, volatile organic compounds (VOCs), and pesticides, although all were detected at concentrations less than established drinking-water standards, where such standards exist. Overall, study findings point to four primary factors that affect the movement and fate of contaminants and the vulnerability of the public-supply well in Temple Terrace: (1) groundwater age (how long ago water entered, or recharged, the aquifer); (2) short-circuiting of contaminated water through sinkholes; (3) natural geochemical processes within the aquifer; and (4) pumping stress. Although the public-supply well is completed in the Upper Floridan aquifer, it produces water with concentrations of nitrate, VOCs, and the natural contaminant radon that are intermediate between the typical composition of water from the Upper Floridan aquifer and that of the overlying surficial aquifer system. Mixing calculations show that the water produced by the public-supply well could consist of upwards of 50 percent water from the surficial aquifer system mixed with water from the Upper Floridan aquifer. Anthropogenically affected water from the surficial aquifer system travels rapidly to depth through sinkholes that must be directly connected to the cavernous zone intersected by the public-supply well (and several other production wells in the region). Such solution features serve as fast pathways to the well and circumvent the natural attenuation of nitrate and

Geohydrology of the valley-fill aquifer in the Endicott-Johnson City area, Broome County, New York

Science.gov (United States)

Holecek, Thomas J.; Randall, A.D.; Belli, J.L.; Allen, R.V.

1982-01-01

This report is the tenth in a series of 11 map sets depicting geohydrologic conditions in selected aquifers in upstate New York. Geohydrologic data are compiled on five maps at 1:24,000 scale. Together, the maps provide a comprehensive overview of a major valley-fill aquifer in southwestern Broome County. The maps include surficial geology, geologic sections, aquifer thickness, water-infiltration potential of soil zone, potentiometric-surface altitude, and land use. The valley-fill deposits consist of alluvial silt and sand, glacial outwash (sand and gravel), ice-contact sand and gravel, till, and lacustrine silt and clay. The sand and gravel beds have relatively high permeabilities whereas the till, silt, and clay deposits have relatively low permeabilities. Water-table conditions are found in unconfined sand and gravel, whereas artesian conditions prevail within sand and gravel confined by silty deposits. Recharge occurs over the entire surface of the aquifer, due to permeable land-surface conditions, but is greatest along the margin of the valley, where runoff from the hillsides is concentrated, and near streams. The use of land overlying the aquifer is predominantly commercial and residential with lesser amounts of agricultural and industrial uses. (USGS)

Iron oxide surfaces

Science.gov (United States)

Parkinson, Gareth S.

2016-03-01

The current status of knowledge regarding the surfaces of the iron oxides, magnetite (Fe3O4), maghemite (γ-Fe2O3), haematite (α-Fe2O3), and wüstite (Fe1-xO) is reviewed. The paper starts with a summary of applications where iron oxide surfaces play a major role, including corrosion, catalysis, spintronics, magnetic nanoparticles (MNPs), biomedicine, photoelectrochemical water splitting and groundwater remediation. The bulk structure and properties are then briefly presented; each compound is based on a close-packed anion lattice, with a different distribution and oxidation state of the Fe cations in interstitial sites. The bulk defect chemistry is dominated by cation vacancies and interstitials (not oxygen vacancies) and this provides the context to understand iron oxide surfaces, which represent the front line in reduction and oxidation processes. Fe diffuses in and out from the bulk in response to the O2 chemical potential, forming sometimes complex intermediate phases at the surface. For example, α-Fe2O3 adopts Fe3O4-like surfaces in reducing conditions, and Fe3O4 adopts Fe1-xO-like structures in further reducing conditions still. It is argued that known bulk defect structures are an excellent starting point in building models for iron oxide surfaces. The atomic-scale structure of the low-index surfaces of iron oxides is the major focus of this review. Fe3O4 is the most studied iron oxide in surface science, primarily because its stability range corresponds nicely to the ultra-high vacuum environment. It is also an electrical conductor, which makes it straightforward to study with the most commonly used surface science methods such as photoemission spectroscopies (XPS, UPS) and scanning tunneling microscopy (STM). The impact of the surfaces on the measurement of bulk properties such as magnetism, the Verwey transition and the (predicted) half-metallicity is discussed. The best understood iron oxide surface at present is probably Fe3O4(100); the structure is

Iodine-129 in the eastern Snake River Plain aquifer at and near the Idaho National Laboratory, Idaho, 2010-12

Science.gov (United States)

Bartholomay, Roy C.

2013-01-01

From 1953 to 1988, approximately 0.941 curies of iodine-129 (129I) were contained in wastewater generated at the Idaho National Laboratory (INL) with almost all of this wastewater discharged at or near the Idaho Nuclear Technology and Engineering Center (INTEC). Most of the wastewater containing 129I was discharged directly into the eastern Snake River Plain (ESRP) aquifer through a deep disposal well until 1984; lesser quantities also were discharged into unlined infiltration ponds or leaked from distribution systems below the INTEC. During 2010–12, the U.S. Geological Survey in cooperation with the U.S. Department of Energy collected groundwater samples for 129I from 62 wells in the ESRP aquifer to track concentration trends and changes for the carcinogenic radionuclide that has a 15.7 million-year half-life. Concentrations of 129I in the aquifer ranged from 0.0000013±0.0000005 to 1.02±0.04 picocuries per liter (pCi/L), and generally decreased in wells near the INTEC, relative to previous sampling events. The average concentration of 129I in groundwater from 15 wells sampled during four different sample periods decreased from 1.15 pCi/L in 1990–91 to 0.173 pCi/L in 2011–12. All but two wells within a 3-mile radius of the INTEC showed decreases in concentration, and all but one sample had concentrations less than the U.S. Environmental Protection Agency maximum contaminant level of 1 pCi/L. These decreases are attributed to the discontinuation of disposal of 129I in wastewater and to dilution and dispersion in the aquifer. The decreases in 129I concentrations, in areas around INTEC where concentrations increased between 2003 and 2007, were attributed to less recharge near INTEC either from less flow in the Big Lost River or from less local snowmelt and anthropogenic sources. Although wells near INTEC sampled in 2011–12 showed decreases in 129I concentrations compared with previously collected data, some wells south and east of the Central Facilities Area

Quality of groundwater at and near an aquifer storage and recovery site, Bexar, Atascosa, and Wilson Counties, Texas, June 2004-August 2008

Science.gov (United States)

Otero, Cassi L.; Petri, Brian L.

2010-01-01

The U.S. Geological Survey, in cooperation with the San Antonio Water System, did a study during 2004-08 to characterize the quality of native groundwater from the Edwards aquifer and pre- and post-injection water from the Carrizo aquifer at and near an aquifer storage and recovery (ASR) site in Bexar, Atascosa, and Wilson Counties, Texas. Groundwater samples were collected and analyzed for selected physical properties and constituents to characterize the quality of native groundwater from the Edwards aquifer and pre- and post-injection water from the Carrizo aquifer at and near the ASR site. Geochemical and isotope data indicated no substantial changes in major-ion, trace-element, and isotope chemistry occurred as the water from the Edwards aquifer was transferred through a 38-mile pipeline to the aquifer storage and recovery site. The samples collected from the four ASR recovery wells were similar in major-ion and stable isotope chemistry compared to the samples collected from the Edwards aquifer source wells and the ASR injection well. The similarity could indicate that as Edwards aquifer water was injected, it displaced native Carrizo aquifer water, or, alternatively, if mixing of Edwards and Carrizo aquifer waters was occurring, the major-ion and stable isotope signatures for the Carrizo aquifer water might have been obscured by the signatures of the injected Edwards aquifer water. Differences in the dissolved iron and dissolved manganese concentrations indicate that either minor amounts of mixing occurred between the waters from the two aquifers, or as Edwards aquifer water displaced Carrizo aquifer water it dissolved the iron and manganese directly from the Carrizo Sand. Concentrations of radium-226 in the samples collected at the ASR recovery wells were smaller than the concentrations in samples collected from the Edwards aquifer source wells and from the ASR injection well. The smaller radium-226 concentrations in the samples collected from the ASR

Anchoring of alkyl chain molecules on oxide surface using silicon alkoxide

Energy Technology Data Exchange (ETDEWEB)

Narita, Ayumi, E-mail: narita.ayumi@jaea.go.jp [Quantum Beam Science Directorate, Japan Atomic Energy Agency, Tokai-mura, Naka-gun, Ibaraki-ken 319-1195 (Japan); Graduate School of Science and Engineering, Ibaraki University, Bunnkyo, Mito-shi, Ibaraki-ken 310-8512 (Japan); Baba, Yuji; Sekiguchi, Tetsuhiro; Shimoyama, Iwao; Hirao, Norie [Quantum Beam Science Directorate, Japan Atomic Energy Agency, Tokai-mura, Naka-gun, Ibaraki-ken 319-1195 (Japan); Yaita, Tsuyoshi [Quantum Beam Science Directorate, Japan Atomic Energy Agency, Tokai-mura, Naka-gun, Ibaraki-ken 319-1195 (Japan); Graduate School of Science and Engineering, Ibaraki University, Bunnkyo, Mito-shi, Ibaraki-ken 310-8512 (Japan)

2012-01-01

Chemical states of the interfaces between octadecyl-triethoxy-silane (ODTS) molecules and sapphire surface were measured by X-ray photoelectron spectroscopy (XPS) and near edge X-ray absorption fine structure (NEXAFS) using synchrotron soft X-rays. The nearly self-assembled monolayer of ODTS was formed on the sapphire surface. For XPS and NEXAFS measurements, it was elucidated that the chemical bond between silicon alkoxide in ODTS and the surface was formed, and the alkane chain of ODTS locates upper side on the surface. As a result, it was elucidated that the silicon alkoxide is a good anchor for the immobilization of organic molecules on oxides.

Dynamics of arsenic adsorption in the targeted arsenic-safe aquifers in Matlab, south-eastern Bangladesh: Insight from experimental studies

Energy Technology Data Exchange (ETDEWEB)

Robinson, Clare, E-mail: crobinson@eng.uwo.ca [Department of Civil and Environmental Engineering, University of Western Ontario, London, N6A 5B9 (Canada)] [NGO Forum for Drinking Water Supply and Sanitation, Lalmatia, Dhaka 1207 (Bangladesh); Broemssen, Mattias von [KTH-International Groundwater Arsenic Research Group, Department of Land and Water Resources Engineering, Royal Institute of Technology, SE-100 44 Stockholm (Sweden)] [Ramboell Sweden AB, Box 4205, SE-102 65 Stockholm (Sweden); Bhattacharya, Prosun; Haeller, Sara; Biven, Annelie [KTH-International Groundwater Arsenic Research Group, Department of Land and Water Resources Engineering, Royal Institute of Technology, SE-100 44 Stockholm (Sweden); Hossain, Mohammed [NGO Forum for Drinking Water Supply and Sanitation, Lalmatia, Dhaka 1207 (Bangladesh)] [KTH-International Groundwater Arsenic Research Group, Department of Land and Water Resources Engineering, Royal Institute of Technology, SE-100 44 Stockholm (Sweden); Jacks, Gunnar [KTH-International Groundwater Arsenic Research Group, Department of Land and Water Resources Engineering, Royal Institute of Technology, SE-100 44 Stockholm (Sweden); Ahmed, Kazi Matin; Hasan, M. Aziz [Department of Geology, University of Dhaka, Dhaka 1000 (Bangladesh); Thunvik, Roger [KTH-International Groundwater Arsenic Research Group, Department of Land and Water Resources Engineering, Royal Institute of Technology, SE-100 44 Stockholm (Sweden)

2011-04-15

Research highlights: {yields} Adsorption behaviour of shallow oxidized sediments from Matlab Region in SE Bangladesh is investigated. {yields} Oxidized sediments have a high capacity to adsorb arsenic. {yields} Adsorption capacity will be reduced by high concentration of reactive organic C. {yields} Monitoring of groundwater quality over 5 year period shows relatively stable water chemistry. - Abstract: Targeting shallow low-As aquifers based on sediment colour may be a viable solution for supplying As-safe drinking water to rural communities in some regions of Bangladesh and West Bengal in India. The sustainability of this solution with regard to the long-term risk of As-safe oxidized aquifers becoming enriched with As needs to be assessed. This study focuses on the adsorption behaviour of shallow oxidized sediments from Matlab Region, Bangladesh, and their capacity to attenuate As if cross-contamination of the oxidized aquifers occurs. Water quality analyses of samples collected from 20 tube-wells in the region indicate that while there may be some seasonal variability, the groundwater chemistry in the reduced and oxidized aquifers was relatively stable from 2004 to 2009. Although sediment extractions indicate a relatively low amount of As in the oxidized sediments, below 2.5 mg kg{sup -1}, batch isotherm experiments show that the sediments have a high capacity to adsorb As. Simulations using a surface complexation model that considers adsorption to amorphous Fe(III) oxide minerals only, under-predict the experimental isotherms. This suggests that a large proportion of the adsorption sites in the oxidized sediments may be associated with crystalline Fe(III) oxides, Mn(IV) and Al(III) oxides, and clay minerals. Replicate breakthrough column experiments conducted with lactose added to the influent solution demonstrate that the high adsorption capacity of the oxidized sediments may be reduced if water drawn down into the oxidized aquifers contains high levels of

Modelling the salinization of a coastal lagoon-aquifer system

Science.gov (United States)

Colombani, N.; Mastrocicco, M.

2017-08-01

In this study, a coastal area constituted by alternations of saline-brackish lagoons and freshwater bodies was studied and modelled to understand the hydrological processes occurring between the lagoons, the groundwater system of the Po River Delta (Italy) and the Adriatic Sea. The contribution of both evaporation and anthropogenic factors on groundwater salinization was assessed by means of soil, groundwater and surface water monitoring. Highresolution multi-level samplers were used to capture salinity gradients within the aquifer and surface water bodies. Data were employed to calibrate a density-dependent numerical transport model implemented with SEAWAT code along a transect perpendicular to the coast line. The results show that the lagoon is hydraulically well connected with the aquifer, which provides the major source of salinity because of the upcoming of paleo-seawater from the aquitard laying at the base of the unconfined aquifer. On the contrary, the seawater (diluted by the freshwater river outflow) creates only a limited saltwater wedge. The increase in groundwater salinity could be of serious concern, especially for the pinewood located in the dune near the coast, sensitive to salinity increases. This case study represents an interesting paradigm for other similar environmental setting, where the assumption of classical aquifer salinization from a saltwater wedge intruding from the sea is often not representative of the actual aquifer’s salinization mechanisms.

Surface-NMR measurements of the longitudinal relaxation time T1 in a homogeneous sandy aquifer in Skive, Denmark

Science.gov (United States)

Walbrecker, J.; Behroozmand, A.

2011-12-01

Efficient groundwater management requires reliable means of characterizing shallow groundwater aquifers. One key parameter in this respect is hydraulic conductivity. Surface nuclear magnetic resonance (NMR) is a geophysical exploration technique that can potentially provide this type of information in a noninvasive, cost-effective way. The technique is based on measuring the precession of nuclear spins of protons in groundwater molecules. It involves large loop antennas deployed on Earth's surface to generate electromagnetic pulses tuned to specifically excite and detect groundwater proton spins. Naturally, the excited state of spins is transitory - once excited, spins relax back to their equilibrium state. This relaxation process is strongly influenced by the spin environment, which, in the case of groundwater, is defined by the aquifer. By employing empirical relations, changes in relaxation behavior can be used to identify changes in aquifer hydraulic conductivity, making the NMR relaxation signal a very important piece of information. Particularly, efforts are made to record the longitudinal relaxation parameter T1, because it is known from laboratory studies that it often reliably correlates with hydraulic conductivity, even in the presence of magnetic species. In surface NMR, T1 data are collected by recording the NMR signal amplitude following two sequential excitation pulses as a function of the delay time τ between the two pulses. In conventional acquisition, the two pulses have a mutual phase shift of π. Based on theoretical arguments it was recently shown that T1 times acquired according to this conventional surface-NMR scheme are systematically biased. It was proposed that the bias can be minimized by cycling the phase of the two pulses between π and zero in subsequent double-pulse experiments, and subtracting the resulting signal amplitudes (phase-cycled pseudosaturation recovery scheme, pcPSR). We present the first surface-NMR T1 data set recorded

Variations of uranium concentrations in a multi-aquifer system under the impact of surface water-groundwater interaction

Science.gov (United States)

Wu, Ya; Li, Junxia; Wang, Yanxin; Xie, Xianjun

2018-04-01

Understanding uranium (U) mobility is vital to minimizing its concentrations in potential drinking water sources. In this study, we report spatial-seasonal variations in U speciation and concentrations in a multi-aquifer system under the impact of Sanggan River in Datong basin, northern China. Hydrochemical and H, O, Sr isotopic data, thermodynamic calculations, and geochemical modeling are used to investigate the mechanisms of surface water-groundwater mixing-induced mobilization and natural attenuation of U. In the study site, groundwater U concentrations are up to 30.2 μg/L, and exhibit strong spatial-seasonal variations that are related to pH and Eh values, as well as dissolved Ca2+, HCO3-, and Fe(III) concentrations. For the alkaline aquifers of this site (pH 7.02-8.44), U mobilization is due to the formation and desorption of Ca2UO2(CO3)30 and CaUO2(CO3)32- caused by groundwater Ca2+ elevation via mineral weathering and Na-Ca exchange, incorporated U(VI) release from calcite, and U(IV) oxidation by Fe(OH)3. U immobilization is linked to the adsorption of CaUO2(CO3)32- and UO2(CO3)34- shifted from Ca2UO2(CO3)30 because of HCO3- elevation and Ca2+ depletion, U(VI) co-precipitation with calcite, and U(VI) reduction by adsorbed Fe2+ and FeS. Those results are of great significance for the groundwater resource management of this and similar other surface water-groundwater interaction zones.

Experimental study on the artificial recharge of semiconfined aquifers involved in deep excavation engineering

Science.gov (United States)

Zheng, G.; Cao, J. R.; Cheng, X. S.; Ha, D.; Wang, F. J.

2018-02-01

Artificial recharge measures have been adopted to control the drawdown of confined aquifers and the ground subsidence caused by dewatering during deep excavation in Tianjin, Shanghai and other regions in China. However, research on recharge theory is still limited. Additionally, confined aquifers consisting of silt and silty sand in Tianjin have lower hydraulic conductivities than those consisting of sand or gravel, and the feasibility and effectiveness of recharge methods in these semiconfined aquifers urgently require investigation. A series of single-well and multiwell pumping and recharge tests was conducted at a metro station excavation site in Tianjin. The test results showed that it was feasible to recharge silt and silty sand semiconfined aquifers, and, to a certain extent, the hydrogeological parameters obtained from the pumping tests could be used to predict the water level rise during single-well recharge. However, the predicted results underestimated the water level rise near the recharge well (within 7 m) by approximately 10-25%, likely because the permeability coefficient around the well was reduced during the recharge process. Pressured recharge significantly improved the efficiency of the recharge process. Maintaining the recharge and pumping rates at a nearly equal level effectively controlled the surrounding surface and building settlement. However, the surrounding surface subsidence tended to rapidly develop when recharge stopped. Therefore, the recharge process should continue and gradually stop after the pumping stops. The twin-well combined recharge technique can be used to control the head loss of an aquifer when one of the recharge wells requires pumping to solve the associated clogging problems.

Formation of recent martian debris flows by melting of near-surface ground ice at high obliquity.

Science.gov (United States)

Costard, F; Forget, F; Mangold, N; Peulvast, J P

2002-01-04

The observation of small gullies associated with recent surface runoff on Mars has renewed the question of liquid water stability at the surface of Mars. The gullies could be formed by groundwater seepage from underground aquifers; however, observations of gullies originating from isolated peaks and dune crests question this scenario. We show that these landforms may result from the melting of water ice in the top few meters of the martian subsurface at high obliquity. Our conclusions are based on the analogy between the martian gullies and terrestrial debris flows observed in Greenland and numerical simulations that show that above-freezing temperatures can occur at high obliquities in the near surface of Mars, and that such temperatures are only predicted at latitudes and for slope orientations corresponding to where the gullies have been observed on Mars.

Iron oxidation kinetics and phosphorus immobilization at the groundwater-surface water interface

Science.gov (United States)

van der Grift, Bas; Rozemeijer, Joachim; Griffioen, Jasper; van der Velde, Ype

2014-05-01

, with Fe(II) oxidation taking place in the soil surrounding the ditch during summer and in the surface water during winter. The dynamics in Fe(II) oxidation did not affect the dissolved P concentrations. The dissolved P concentrations of the in-stream reservoirs water were an order of magnitude lower than observed in the groundwater and have no seasonal trend. Our data showed preferential binding of P during initial stage of the Fe(II) oxidation process, indicating the formation of Fe(III)-phosphate precipitates. The formation of Fe(III)-phosphates at the groundwater-surface water interface is an important geochemical mechanism in the transformation of dissolved phosphate to particulate phosphate and therefore a major control on the P retention in natural waters that drain anaerobic aquifers.

Delineation of the extent of milling-related contamination in a naturally contaminated aquifer system

International Nuclear Information System (INIS)

Downs, William F.; Storms, Erik F.

1992-01-01

Uranium mill tailings from the Susquehanna-Western mill near Falls City, Texas, were pumped to tailings ponds located in abandoned open pit uranium mines. The ores from these mines were oxidized. Uranium and the associated hazardous constituents were present in these ores as relatively soluble secondary minerals. Because the tailings piles are located on the outcrops of the units designated as the uppermost aquifer, there is no upgradient aquifer from which to establish 'background' water quality. The widespread mineralization in the area naturally imposes a large variability in water quality in these units. It was necessary to demonstrate to State and Federal regulators that selected downgradient wells were beyond the influence of milling operations, and to develop a series of 'indicator parameters' that could be used to differentiate milling contaminated groundwater from that native to the aquifer. (author)

Measuring surface-water loss in Honouliuli Stream near the ‘Ewa Shaft, O‘ahu, Hawai‘i

Science.gov (United States)

Rosa, Sarah N.

2017-05-30

The Honolulu Board of Water Supply is currently concerned with the possibility of bacteria in the pumped water of the ‘Ewa Shaft (State well 3-2202-21). Groundwater from the ‘Ewa Shaft could potentially be used to meet future potable water needs in the ‘Ewa area on the island of O‘ahu. The source of the bacteria in the pumped water is unknown, although previous studies indicate that surface water may be lost to the subsurface near the site. The ‘Ewa Shaft consists of a vertical shaft, started near the south bank of Honouliuli Stream at an altitude of about 161 feet, and two horizontal infiltration tunnels near sea level. The shaft extracts groundwater from near the top of the freshwater lens in the Waipahu-Waiawa aquifer system within the greater Pearl Harbor Aquifer Sector, a designated Water Management Area.The surface-water losses were evaluated with continuous groundwater-level data from the ‘Ewa Shaft and a nearby monitoring well, continuous stream-discharge data from U.S. Geological Survey streamflow-gaging station 16212490 (Honouliuli Stream at H-1 Freeway near Waipahu), and seepage-run measurements in Honouliuli Stream and its tributary. During storms, discharge at the Honouliuli Stream gaging station increases and groundwater levels at ‘Ewa Shaft and a nearby monitoring well also increase. The concurrent increase in water levels at ‘Ewa Shaft and the nearby monitoring well during storms indicates that regional groundwater-level changes related to increased recharge, reduced withdrawals (due to a decrease in demand during periods of rainfall), or both may be occurring; although these data do not preclude the possibility of local recharge from Honouliuli Stream. Discharge measurements from two seepage runs indicate that surface water in the immediate area adjacent to ‘Ewa Shaft infiltrates into the streambed and may later reach the groundwater system developed by the ‘Ewa Shaft. The estimated seepage loss rates in the vicinity of �

Quantitative assessment of radionuclide retention in the near-surface system at Forsmark. Development of a reactive transport model using Forsmark 1.2 data

International Nuclear Information System (INIS)

Grandia, Fidel; Sena, Clara; Arcos, David; Molinero, Jorge; Duro, Lara; Bruno, Jordi

2007-12-01

The main objective of this work is to assess the migration behaviour of selected long-lived radionuclides through the near-surface system of Forsmark, with special focus on the evaluation of the capacity of the Quaternary deposits and sediments for radionuclide retention. The work reported here is based on data and information from Forsmark Site Descriptive Model version 1.2. From the geological point of view, the near-surface systems in the Forsmark area consist of Quaternary deposits and sediments that overlay the granitic bedrock. Glacial till is the more abundant outcropping Quaternary deposit and the remainder is made of clayey deposits. These types of near-surface sediments show distinctive hydraulic and geochemical features. The main reactive mineral in the till deposits, for the time horizons considered in this work, is calcium carbonate together with minor amounts of clay minerals (e.g. illite). The till deposits forms aquifers with relatively high hydraulic conductivities. In contrast, glacial and post-glacial clays are basically composed of illite with low to very low amounts of calcium carbonate, and containing organic matter-rich layers (gyttja), which can promote reducing conditions in the porewaters. All these clays exhibits relatively low hydraulic conductivity values. Five radionuclides have been selected for conceptualization and qualitative evaluation of retention process: U as an actinide, Se as a redox-sensitive radionuclide, Cs as a monovalent cation, Sr as a divalent cation, and I as an anion radionuclide. Overall, radionuclide retention capacity in the surface systems at Forsmark can be provided by sorption on charged surfaces of clays and oxyhydroxides, co-precipitation with sulphates, sulphides, oxyhydroxides and carbonates, and sorption on organic matter. Two-dimensional coupled hydrogeological and reactive solute transport models have been developed to simulate the geochemical behaviour of U, Cs and Sr. These three radionuclides have

Tidal Pumping-Induced Nutrients Dynamics and Biogeochemical Implications in an Intertidal Aquifer

Science.gov (United States)

Liu, Yi; Jiao, Jiu Jimmy; Liang, Wenzhao; Luo, Xin

2017-12-01

Tidal pumping is a major driving force affecting water exchange between land and sea, biogeochemical reactions in the intertidal aquifer, and nutrient loading to the sea. At a sandy beach of Tolo Harbour, Hong Kong, the nutrient (NH4+, NO2-, NO3-, and PO43-) dynamic in coastal groundwater mixing zone (CGMZ) is found to be fluctuated with tidal oscillation. Nutrient dynamic is mainly controlled by tidal pumping-induced organic matter that serves as a reagent of remineralization in the aquifer. NH4+, NO2-, and PO43- are positively correlated with salinity. Both NH4+ and PO43- have negative correlations with oxidation/reduction potential. NH4+ is the major dissolved inorganic nitrogen species in CGMZ. The adsorption of PO43- onto iron oxides occurs at the deep transition zone with a salinity of 5-10 practical salinity unit (psu), and intensive N-loss occurs in near-surface area with a salinity of 10-25 psu. The biogeochemical reactions, producing PO43- and consuming NH4+, are synergistic effect of remineralization-nitrification-denitrification. In CGMZ, the annual NH4+ loss is estimated to be 4.32 × 105 mol, while the minimum annual PO43- production is estimated to be 2.55 × 104 mol. Applying these rates to the entire Tolo Harbour, the annual NH4+ input to the harbor through the remineralization of organic matters is estimated to be 1.02 × 107 mol. The annual NH4+ loss via nitrification is 1.32 × 107 mol, and the annual PO43- production is 7.76 × 105 mol.

A General Solution for Groundwater Flow in Estuarine Leaky Aquifer System with Considering Aquifer Anisotropy

Science.gov (United States)

Chen, Po-Chia; Chuang, Mo-Hsiung; Tan, Yih-Chi

2014-05-01

In recent years the urban and industrial developments near the coastal area are rapid and therefore the associated population grows dramatically. More and more water demand for human activities, agriculture irrigation, and aquaculture relies on heavy pumping in coastal area. The decline of groundwater table may result in the problems of seawater intrusion and/or land subsidence. Since the 1950s, numerous studies focused on the effect of tidal fluctuation on the groundwater flow in the coastal area. Many studies concentrated on the developments of one-dimensional (1D) and two-dimensional (2D) analytical solutions describing the tide-induced head fluctuations. For example, Jacob (1950) derived an analytical solution of 1D groundwater flow in a confined aquifer with a boundary condition subject to sinusoidal oscillation. Jiao and Tang (1999) derived a 1D analytical solution of a leaky confined aquifer by considered a constant groundwater head in the overlying unconfined aquifer. Jeng et al. (2002) studied the tidal propagation in a coupled unconfined and confined costal aquifer system. Sun (1997) presented a 2D solution for groundwater response to tidal loading in an estuary. Tang and Jiao (2001) derived a 2D analytical solution in a leaky confined aquifer system near open tidal water. This study aims at developing a general analytical solution describing the head fluctuations in a 2D estuarine aquifer system consisted of an unconfined aquifer, a confined aquifer, and an aquitard between them. Both the confined and unconfined aquifers are considered to be anisotropic. The predicted head fluctuations from this solution will compare with the simulation results from the MODFLOW program. In addition, the solutions mentioned above will be shown to be special cases of the present solution. Some hypothetical cases regarding the head fluctuation in costal aquifers will be made to investigate the dynamic effects of water table fluctuation, hydrogeological conditions, and

Ground-Water Age and Quality in the High Plains Aquifer near Seward, Nebraska, 2003-04

Science.gov (United States)

Stanton, Jennifer S.; Landon, Matthew K.; Turco, Michael J.

2007-01-01

interpret the results, the mean age and mixing fractions from the primary mixing models used were fairly similar. Relations of ground-water age and nitrate concentrations to depth were not consistent across the study area. In some well nests, more young water and nitrate were present near the bottom than in the middle of the aquifer. These results probably reflect pumping from irrigation and supply wells, which are screened primarily in the lower part of the aquifer, and draw younger water downward in the aquifer. Substantial mixing probably occurs because the aquifer is relatively thin (50 feet) and has a relatively high density of wells (about five pumping wells per square mile). The most reliable estimate of horizontal traveltimes based on differences in ground-water ages between a shallow monitoring well at the upgradient end of the northwest well transect and the deep well at the downgradient end of the well transect was 9 years to travel a distance of about 2 miles. The general similarity of ages at similar depths between different well nests is consistent with the fact that horizontal flow in the aquifer is relatively rapid. Concentrations of nitrate (as nitrogen) in untreated ground-water samples from supply wells in the well field were larger than the U.S. Environmental Protection Agency Maximum Contaminant Level for drinking water of 10 mg/L (milligrams per liter), ranging from 11.3 to 13.5 mg/L. It is unlikely that nitrate concentrations in the aquifer near the Seward west well field are decreased by denitrification in the aquifer due to oxic geochemical conditions that preclude this reaction. Nitrate concentrations coupled with water recharge dates were compared to historical estimated fertilizer application in an attempt to reconstruct historical trends in ground-water nitrate concentrations and their relation to land-use practices. Nitrate concentrations in young-water fractions, after adjustment for mixing, may be decreasing over apparent recharg

Evaluation of conceptual and numerical models for arsenic mobilization and attenuation during managed aquifer recharge.

Science.gov (United States)

Wallis, Ilka; Prommer, Henning; Simmons, Craig T; Post, Vincent; Stuyfzand, Pieter J

2010-07-01

Managed Aquifer Recharge (MAR) is promoted as an attractive technique to meet growing water demands. An impediment to MAR applications, where oxygenated water is recharged into anoxic aquifers, is the potential mobilization of trace metals (e.g., arsenic). While conceptual models for arsenic transport under such circumstances exist, they are generally not rigorously evaluated through numerical modeling, especially at field-scale. In this work, geochemical data from an injection experiment in The Netherlands, where the introduction of oxygenated water into an anoxic aquifer mobilized arsenic, was used to develop and evaluate conceptual and numerical models of arsenic release and attenuation under field-scale conditions. Initially, a groundwater flow and nonreactive transport model was developed. Subsequent reactive transport simulations focused on the description of the temporal and spatial evolution of the redox zonation. The calibrated model was then used to study and quantify the transport of arsenic. In the model that best reproduced field observations, the fate of arsenic was simulated by (i) release via codissolution of arsenopyrite, stoichiometrically linked to pyrite oxidation, (ii) kinetically controlled oxidation of dissolved As(III) to As(V), and (iii) As adsorption via surface complexation on neo-precipitated iron oxides.

Hydrogeological and biogeochemical constrains of arsenic mobilization in shallow aquifers from the Hetao basin, Inner Mongolia.

Science.gov (United States)

Guo, Huaming; Zhang, Bo; Li, Yuan; Berner, Zsolt; Tang, Xiaohui; Norra, Stefan; Stüben, Doris

2011-04-01

Little is known about the importance of drainage/irrigation channels and biogeochemical processes in arsenic distribution of shallow groundwaters from the Hetao basin. This investigation shows that although As concentrations are primarily dependent on reducing conditions, evaporation increases As concentration in the centre of palaeo-lake sedimentation. Near drainage channels, groundwater As concentrations are the lowest in suboxic-weakly reducing conditions. Results demonstrate that both drainage and irrigation channels produce oxygen-rich water that recharges shallow groundwaters and therefore immobilize As. Groundwater As concentration increases with a progressive decrease in redox potential along the flow path in an alluvial fan. A negative correlation between SO₄²⁻ concentrations and δ³⁴S values indicates that bacterial reduction of SO₄²⁻ occurs in reducing aquifers. Due to high concentrations of Fe (> 0.5 mg L⁻¹), reductive dissolution of Fe oxides is believed to cause As release from aquifer sediments. Target aquifers for safe drinking water resources are available in alluvial fans and near irrigation channels. Copyright © 2011 Elsevier Ltd. All rights reserved.

Occurrence of fecal indicator bacteria in surface waters and the subsurface aquifer in Key Largo, Florida.

Science.gov (United States)

Paul, J H; Rose, J B; Jiang, S; Kellogg, C; Shinn, E A

1995-01-01

Sewage waste disposal facilities in the Florida Keys include septic tanks and individual package plants in place of municipal collection facilities in most locations. In Key Largo, both facilities discharge into the extremely porous Key Largo limestone. To determine whether there was potential contamination of the subsurface aquifer and nearby coastal surface waters by such waste disposal practices, we examined the presence of microbial indicators commonly found in sewage (fecal coliforms, Clostridium perfringens, and enterococci) and aquatic microbial parameters (viral direct counts, bacterial direct counts, chlorophyll a, and marine vibriophage) in injection well effluent, monitoring wells that followed a transect from onshore to offshore, and surface waters above these wells in two separate locations in Key Largo in August 1993 and March 1994. Effluent and waters from onshore shallow monitoring wells (1.8- to 3.7-m depth) contained two or all three of the fecal indicators in all three samples taken, whereas deeper wells (10.7- to 12.2-m depth) at these same sites contained few or none. The presence of fecal indicators was found in two of five nearshore wells (i.e., those that were or = 2.1 to 5.7 miles [aquifer, parts of the nearshore aquifer, and certain surface waters has occurred.(ABSTRACT TRUNCATED AT 250 WORDS) PMID:7793943

Quantitative assessment of radionuclide retention in the near-surface system at Forsmark. Development of a reactive transport model using Forsmark 1.2 data

Energy Technology Data Exchange (ETDEWEB)

Grandia, Fidel; Sena, Clara; Arcos, David; Molinero, Jorge; Duro, Lara; Bruno, Jordi (Amphos XXI Consulting S.L., Barcelona (Spain))

2007-12-15

The main objective of this work is to assess the migration behaviour of selected long-lived radionuclides through the near-surface system of Forsmark, with special focus on the evaluation of the capacity of the Quaternary deposits and sediments for radionuclide retention. The work reported here is based on data and information from Forsmark Site Descriptive Model version 1.2. From the geological point of view, the near-surface systems in the Forsmark area consist of Quaternary deposits and sediments that overlay the granitic bedrock. Glacial till is the more abundant outcropping Quaternary deposit and the remainder is made of clayey deposits. These types of near-surface sediments show distinctive hydraulic and geochemical features. The main reactive mineral in the till deposits, for the time horizons considered in this work, is calcium carbonate together with minor amounts of clay minerals (e.g. illite). The till deposits forms aquifers with relatively high hydraulic conductivities. In contrast, glacial and post-glacial clays are basically composed of illite with low to very low amounts of calcium carbonate, and containing organic matter-rich layers (gyttja), which can promote reducing conditions in the porewaters. All these clays exhibits relatively low hydraulic conductivity values. Five radionuclides have been selected for conceptualization and qualitative evaluation of retention process: U as an actinide, Se as a redox-sensitive radionuclide, Cs as a monovalent cation, Sr as a divalent cation, and I as an anion radionuclide. Overall, radionuclide retention capacity in the surface systems at Forsmark can be provided by sorption on charged surfaces of clays and oxyhydroxides, co-precipitation with sulphates, sulphides, oxyhydroxides and carbonates, and sorption on organic matter. Two-dimensional coupled hydrogeological and reactive solute transport models have been developed to simulate the geochemical behaviour of U, Cs and Sr. These three radionuclides have

Atomic Scale Structure-Chemistry Relationships at Oxide Catalyst Surfaces and Interfaces

Science.gov (United States)

McBriarty, Martin E.

Oxide catalysts are integral to chemical production, fuel refining, and the removal of environmental pollutants. However, the atomic-scale phenomena which lead to the useful reactive properties of catalyst materials are not sufficiently understood. In this work, the tools of surface and interface science and electronic structure theory are applied to investigate the structure and chemical properties of catalytically active particles and ultrathin films supported on oxide single crystals. These studies focus on structure-property relationships in vanadium oxide, tungsten oxide, and mixed V-W oxides on the surfaces of alpha-Al2O3 and alpha-Fe2O 3 (0001)-oriented single crystal substrates, two materials with nearly identical crystal structures but drastically different chemical properties. In situ synchrotron X-ray standing wave (XSW) measurements are sensitive to changes in the atomic-scale geometry of single crystal model catalyst surfaces through chemical reaction cycles, while X-ray photoelectron spectroscopy (XPS) reveals corresponding chemical changes. Experimental results agree with theoretical calculations of surface structures, allowing for detailed electronic structure investigations and predictions of surface chemical phenomena. The surface configurations and oxidation states of V and W are found to depend on the coverage of each, and reversible structural shifts accompany chemical state changes through reduction-oxidation cycles. Substrate-dependent effects suggest how the choice of oxide support material may affect catalytic behavior. Additionally, the structure and chemistry of W deposited on alpha-Fe 2O3 nanopowders is studied using X-ray absorption fine structure (XAFS) measurements in an attempt to bridge single crystal surface studies with real catalysts. These investigations of catalytically active material surfaces can inform the rational design of new catalysts for more efficient and sustainable chemistry.

Geochemical detection of carbon dioxide in dilute aquifers

Directory of Open Access Journals (Sweden)

Aines Roger

2009-03-01

Full Text Available Abstract Background Carbon storage in deep saline reservoirs has the potential to lower the amount of CO2 emitted to the atmosphere and to mitigate global warming. Leakage back to the atmosphere through abandoned wells and along faults would reduce the efficiency of carbon storage, possibly leading to health and ecological hazards at the ground surface, and possibly impacting water quality of near-surface dilute aquifers. We use static equilibrium and reactive transport simulations to test the hypothesis that perturbations in water chemistry associated with a CO2 gas leak into dilute groundwater are important measures for the potential release of CO2 to the atmosphere. Simulation parameters are constrained by groundwater chemistry, flow, and lithology from the High Plains aquifer. The High Plains aquifer is used to represent a typical sedimentary aquifer overlying a deep CO2 storage reservoir. Specifically, we address the relationships between CO2 flux, groundwater flow, detection time and distance. The CO2 flux ranges from 103 to 2 × 106 t/yr (0.63 to 1250 t/m2/yr to assess chemical perturbations resulting from relatively small leaks that may compromise long-term storage, water quality, and surface ecology, and larger leaks characteristic of short-term well failure. Results For the scenarios we studied, our simulations show pH and carbonate chemistry are good indicators for leakage of stored CO2 into an overlying aquifer because elevated CO2 yields a more acid pH than the ambient groundwater. CO2 leakage into a dilute groundwater creates a slightly acid plume that can be detected at some distance from the leak source due to groundwater flow and CO2 buoyancy. pH breakthrough curves demonstrate that CO2 leaks can be easily detected for CO2 flux ≥ 104 t/yr within a 15-month time period at a monitoring well screened within a permeable layer 500 m downstream from the vertical gas trace. At lower flux rates, the CO2 dissolves in the aqueous phase

Geochemical detection of carbon dioxide in dilute aquifers.

Science.gov (United States)

Carroll, Susan; Hao, Yue; Aines, Roger

2009-03-26

Carbon storage in deep saline reservoirs has the potential to lower the amount of CO2 emitted to the atmosphere and to mitigate global warming. Leakage back to the atmosphere through abandoned wells and along faults would reduce the efficiency of carbon storage, possibly leading to health and ecological hazards at the ground surface, and possibly impacting water quality of near-surface dilute aquifers. We use static equilibrium and reactive transport simulations to test the hypothesis that perturbations in water chemistry associated with a CO2 gas leak into dilute groundwater are important measures for the potential release of CO2 to the atmosphere. Simulation parameters are constrained by groundwater chemistry, flow, and lithology from the High Plains aquifer. The High Plains aquifer is used to represent a typical sedimentary aquifer overlying a deep CO2 storage reservoir. Specifically, we address the relationships between CO2 flux, groundwater flow, detection time and distance. The CO2 flux ranges from 10(3) to 2 x 10(6) t/yr (0.63 to 1250 t/m2/yr) to assess chemical perturbations resulting from relatively small leaks that may compromise long-term storage, water quality, and surface ecology, and larger leaks characteristic of short-term well failure. For the scenarios we studied, our simulations show pH and carbonate chemistry are good indicators for leakage of stored CO2 into an overlying aquifer because elevated CO2 yields a more acid pH than the ambient groundwater. CO2 leakage into a dilute groundwater creates a slightly acid plume that can be detected at some distance from the leak source due to groundwater flow and CO2 buoyancy. pH breakthrough curves demonstrate that CO2 leaks can be easily detected for CO2 flux >or= 10(4) t/yr within a 15-month time period at a monitoring well screened within a permeable layer 500 m downstream from the vertical gas trace. At lower flux rates, the CO2 dissolves in the aqueous phase in the lower most permeable unit and does

Hydrogeological and biogeochemical constrains of arsenic mobilization in shallow aquifers from the Hetao basin, Inner Mongolia

International Nuclear Information System (INIS)

Guo Huaming; Zhang Bo; Li Yuan; Berner, Zsolt; Tang Xiaohui; Norra, Stefan; Stueben, Doris

2011-01-01

Little is known about the importance of drainage/irrigation channels and biogeochemical processes in arsenic distribution of shallow groundwaters from the Hetao basin. This investigation shows that although As concentrations are primarily dependent on reducing conditions, evaporation increases As concentration in the centre of palaeo-lake sedimentation. Near drainage channels, groundwater As concentrations are the lowest in suboxic-weakly reducing conditions. Results demonstrate that both drainage and irrigation channels produce oxygen-rich water that recharges shallow groundwaters and therefore immobilize As. Groundwater As concentration increases with a progressive decrease in redox potential along the flow path in an alluvial fan. A negative correlation between SO 4 2- concentrations and δ 34 S values indicates that bacterial reduction of SO 4 2- occurs in reducing aquifers. Due to high concentrations of Fe (>0.5 mg L -1 ), reductive dissolution of Fe oxides is believed to cause As release from aquifer sediments. Target aquifers for safe drinking water resources are available in alluvial fans and near irrigation channels. - Research highlights: → Low As groundwaters occur in alluvial fans. → We find low As groundwaters near irrigation and drainage channels. → Both hydrogeologic conditions and biogeochemical processes control As distribution. - Both hydrogeologic conditions and biogeochemical processes control As distribution of shallow groundwaters, which results in the occurrence of low As groundwater in alluvial fans and near irrigation channels and drainage channels.

Ogallala Aquifer Mapping Program

International Nuclear Information System (INIS)

1984-10-01

A computerized data file has been established which can be used efficiently by the contour-plotting program SURFACE II to produce maps of the Ogallala aquifer in 17 counties of the Texas Panhandle. The data collected have been evaluated and compiled into three sets, from which SURFACE II can generate maps of well control, aquifer thickness, saturated thickness, water level, and the difference between virgin (pre-1942) and recent (1979 to 1981) water levels. 29 figures, 1 table

Formation of ZnO at zinc oxidation by near- and supercritical water under the constant electric field

Science.gov (United States)

Shishkin, A. V.; Sokol, M. Ya.; Shatrova, A. V.; Fedyaeva, O. N.; Vostrikov, A. A.

2014-12-01

The work has detected an influence of a constant electric field (up to E = 300 kV/m) on the structure of a nanocrystalline layer of zinc oxide, formed on the surface of a planar zinc anode in water under supercritical (673 K and 23 MPa) and near-critical (673 K and 17. 5 MPa) conditions. The effect of an increase of zinc oxidation rate with an increase in E is observed under supercritical conditions and is absent at near-critical ones. Increase in the field strength leads to the formation of a looser structure in the inner part of the zinc oxide layer.

Modelling the effects of tides and storm surges on coastal aquifers using a coupled surface-subsurface approach.

Science.gov (United States)

Yang, Jie; Graf, Thomas; Herold, Maria; Ptak, Thomas

2013-06-01

Coastal aquifers are complex hydrologic systems because many physical processes interact: (i) variably saturated flow, (ii) spatial-temporal fluid density variations, (iii) tidal fluctuations, (iv) storm surges overtopping dykes, and (v) surface runoff of storm water. The HydroGeoSphere model is used to numerically simulate coastal flow dynamics, assuming a fully coupled surface-subsurface approach, accounting for all processes listed above. The diffusive wave approximation of the St. Venant equation is used to describe surface flow. Surface flow and salt transport are fully coupled with subsurficial variably saturated, variable-density flow and salt transport through mathematical terms that represent exchange of fluid mass and solute mass, respectively. Tides and storm surges induce a time-variant head that is applied to nodes of the surface domain. The approach is applied to real cases of tide and storm surge events. Tide simulation results confirm the existence of a recirculating zone, forming beneath the upper part of the intertidal zone. By monitoring the exchange fluid flux rates through the beach, it was found that the major inflow to the aquifer takes place at the upper part of the intertidal zone, which explains the formation of the recirculating zone. The recirculating zone is forming particularly during rising tide. Results from a storm surge simulation show that plume fingers develop below the flooded land surface. Natural remediation by seaward flowing freshwater is relatively slow, such that reducing the salt concentration in the aquifer down to drinking water standards takes up to 10 years. Copyright © 2013 Elsevier B.V. All rights reserved.

An evaluation of aquifer intercommunication between the unconfined and Rattlesnake Ridge aquifers on the Hanford Site

International Nuclear Information System (INIS)

Jensen, E.J.

1987-10-01

During 1986, Pacific Northwest Laboratory conducted a study of a portion of the Rattlesnake Ridge aquifer (confined aquifer) that lies beneath the B Pond - Gable Mountain Pond area of the Hanford Site. The purpose was to determine the extent of intercommunication between the unconfined aquifer and the uppermost regionally extensive confined aquifer, referred to as the Rattlesnake Ridge aquifer. Hydraulic head data and chemical data were collected from the ground water in the study area during December 1986. The hydraulic head data were used to determine the effects caused by water discharged to the ground from B Pond on both the water table of the unconfined aquifer and the potentiometric surface of the confined aquifer. The chemical data were collected to determine the extent of chemical constituents migrating from the unconfined aquifer to the confined aquifer. Analysis of chemical constituents in the Rattlesnake Ridge aquifer demonstrated that communication between the unconfined and confined aquifers had occurred. However, the levels of contaminants found in the Rattlesnake Ridge aquifer during this study were below the DOE Derived Concentration Guides

Function of a deltaic silt deposit as a repository and long-term source of sulfate and related weathering products in a glaciofluvial aquifer derived from organic-rich shale (North Dakota, USA)

Science.gov (United States)

Schuh, W. M.; Bottrell, S. H.

2014-05-01

A shallow unconfined glaciofluvial aquifer in North Dakota (USA) has largest groundwater sulfate concentrations near the bottom boundary. A deltaic silt layer underlying the aquifer, at >16 m, is the modern proximate sulfate source for the aquifer. The original sulfate source was pyrite in the organic-rich shale component of the aquifer and silt grain matrix. An oxidizing event occurred during which grain-matrix pyrite sulfur was oxidized to sulfate. Thereafter the silt served as a "conserving" layer, slowly feeding sulfate into the lower part of the aquifer and the underlying till. A method was developed for estimating the approximate initial sulfate concentration in the source layer and the redistribution time since the oxidizing event, using a semi-generic convection-dispersion model. The convection-dispersion model and a model for the evolution of modern sulfate δ 34S in silt-layer pore water from the initial grain-matrix pyrite δ 34S, both estimated that the oxidizing event occurred several thousand years ago, and was likely related to the dry conditions of the Hypsithermal Interval. The silt layer also serves as an arsenic source. Results indicate that deltaic silts derived from organic-rich shale parent materials in a glacial environment can provide long-term sources for sulfate and arsenic and possibly other related oxidative weathering products.

Approaches to surface complexation modeling of Uranium(VI) adsorption on aquifer sediments

Science.gov (United States)

Davis, J.A.; Meece, D.E.; Kohler, M.; Curtis, G.P.

2004-01-01

Uranium(VI) adsorption onto aquifer sediments was studied in batch experiments as a function of pH and U(VI) and dissolved carbonate concentrations in artificial groundwater solutions. The sediments were collected from an alluvial aquifer at a location upgradient of contamination from a former uranium mill operation at Naturita, Colorado (USA). The ranges of aqueous chemical conditions used in the U(VI) adsorption experiments (pH 6.9 to 7.9; U(VI) concentration 2.5 ?? 10-8 to 1 ?? 10-5 M; partial pressure of carbon dioxide gas 0.05 to 6.8%) were based on the spatial variation in chemical conditions observed in 1999-2000 in the Naturita alluvial aquifer. The major minerals in the sediments were quartz, feldspars, and calcite, with minor amounts of magnetite and clay minerals. Quartz grains commonly exhibited coatings that were greater than 10 nm in thickness and composed of an illite-smectite clay with occluded ferrihydrite and goethite nanoparticles. Chemical extractions of quartz grains removed from the sediments were used to estimate the masses of iron and aluminum present in the coatings. Various surface complexation modeling approaches were compared in terms of the ability to describe the U(VI) experimental data and the data requirements for model application to the sediments. Published models for U(VI) adsorption on reference minerals were applied to predict U(VI) adsorption based on assumptions about the sediment surface composition and physical properties (e.g., surface area and electrical double layer). Predictions from these models were highly variable, with results overpredicting or underpredicting the experimental data, depending on the assumptions used to apply the model. Although the models for reference minerals are supported by detailed experimental studies (and in ideal cases, surface spectroscopy), the results suggest that errors are caused in applying the models directly to the sediments by uncertain knowledge of: 1) the proportion and types of

Aging promotes todorokite formation from layered manganese oxide at near-surface conditions

Energy Technology Data Exchange (ETDEWEB)

Cui, Haojie [Chinese Academy of Sciences, Xiamen (China). Key Lab. of Urban Environment and Health; Huazhong Agricultural Univ., Ministry of Agriculture, Wuhan (China). Key Lab. of Subtropical Agricultural Resources and Environment; Liu, Fan; Feng, Xionghan; Tan, Wenfeng [Huazhong Agricultural Univ., Ministry of Agriculture, Wuhan (China). Key Lab. of Subtropical Agricultural Resources and Environment; Wang, Ming Kuang [National Taiwan Univ., Taipei (China). Dept. of Agricultural Chemistry

2010-12-15

atmospheric pressure, and it is more suitable to explore the origination of natural todorokite in Earth surface environments using aged layered manganese oxides. (orig.)

Modelling flow and heat transfer through unsaturated chalk - Validation with experimental data from the ground surface to the aquifer

Science.gov (United States)

Thiéry, Dominique; Amraoui, Nadia; Noyer, Marie-Luce

2018-01-01

During the winter and spring of 2000-2001, large floods occurred in northern France (Somme River Basin) and southern England (Patcham area of Brighton) in valleys that are developed on Chalk outcrops. The floods durations were particularly long (more than 3 months in the Somme Basin) and caused significant damage in both countries. To improve the understanding of groundwater flooding in Chalk catchments, an experimental site was set up in the Hallue basin, which is located in the Somme River Basin (France). Unsaturated fractured chalk formation overlying the Chalk aquifer was monitored to understand its reaction to long and heavy rainfall events when it reaches a near saturation state. The water content and soil temperature were monitored to a depth of 8 m, and the matrix pressure was monitored down to the water table, 26.5 m below ground level. The monitoring extended over a 2.5-year period (2006-2008) under natural conditions and during two periods when heavy, artificial infiltration was induced. The objective of the paper is to describe a vertical numerical flow model based on Richards' equation using these data that was developed to simulate infiltrating rainwater flow from the ground surface to the saturated aquifer. The MARTHE computer code, which models the unsaturated-saturated continuum, was adapted to reproduce the monitored high saturation periods. Composite constitutive functions (hydraulic conductivity-saturation and pressure-saturation) that integrate the increase in hydraulic conductivity near saturation and extra available porosity resulting from fractures were introduced into the code. Using these composite constitutive functions, the model was able to accurately simulate the water contents and pressures at all depths over the entire monitored period, including the infiltration tests. The soil temperature was also accurately simulated at all depths, except during the infiltrations tests, which contributes to the model validation. The model was used

Geohydrology of the valley-fill aquifer in the Corning area, Steuben County, New York

Science.gov (United States)

Miller, Todd S.; Belli, J.L.; Allen, R.V.

1982-01-01

This report is the seventh in a series of 11 map sets depicting geohydrologic conditions in selected aquifers in upstate New York. Geohydrologic data are compiled on six maps at 1:24,000 scale. Together, the maps provide a comprehensive overview of a major valley-fill aquifer in southeastern Steuben County. The maps include surficial geology, geologic sections, water-infiltration potential of soil zone, aquifer thickness, potentiometric-surface elevations, and land use. The valley-fill deposits consist of alluvial silt, sand, and gravel, glacial-outwash (sand and gravel), till, and lacustrine silt and clay. The sand and gravel beds have relatively high permeabilities, whereas the till and silt deposits have relatively low permeabilities. Water-table conditions prevail in unconfined sand and gravel along the valley margin. Artesian conditions are found locally in sand and gravel confined under silt and clay in the middle of the valley. Recharge occurs nearly everywhere on the valley floor, but principally along the margin of the valley, where highly permeable land surface conditions exist, and runoff from the hillsides is concentrated. The use of land overlying the aquifer is a mixture of residential, commercial, agricultural, and industrial uses. (USGS)

Thermally enhanced bioremediation of a gasoline-contaminated aquifer using toluene oxidizing bacteria

International Nuclear Information System (INIS)

Deeb, R.; Alvarez-Cohen, L.

1994-01-01

The combined application of steam injection and vacuum extraction has proved to be very effective for the in situ remediation of a gasoline contaminated aquifer. It is expected that the steam treated zone with its near-sterile nature, increased temperature, and decreased level of contaminant concentration will provide a superior environment for enhanced bioremediation, and will favor the survival of an introduced microbial culture for the destruction of residual gasoline hydrocarbons and especially BTEX compounds (Benzene, Toluene, Ethyl benzene, and Xylene). A mixed microbial culture seeded from the pre-steamed aquifer material was enriched in a laboratory chemostat on toluene, a major gasoline aromatic. Studies were conducted to determine the optimal conditions for microbial growth and activity. Growth rate studies conducted at different temperatures revealed that cell growth was optimal at 35 C, a temperature at which the aquifer can be maintained using the existing steam injection wells. The enriched culture was shown to degrade all BTEX compounds successfully both individually and in mixtures. Substrate toxicity was observed for some of the gasoline aromatics but at concentration levels well above those found in groundwater. When cells were exposed to mixtures of BTEX compounds, the biodegradation of xylene, the most recalcitrant aromatic among BTEX compounds, was stimulated. When cells were exposed to gasoline, BTEX degradation proceeded with no apparent inhibition by gasoline aliphatics; little aliphatic degradation took place, however, suggesting the absence of monooxygenase enzymes in the mixed culture. In mixtures of both toluene and propane enriched cultures, only dioxygenase activity was observed

Groundwater and surface-water interaction and effects of pumping in a complex glacial-sediment aquifer, phase 2, east-central Massachusetts

Science.gov (United States)

Eggleston, Jack R.; Zarriello, Phillip J.; Carlson, Carl S.

2015-12-31

The U.S. Geological Survey, in cooperation with the Town of Framingham, Massachusetts, has investigated the potential of proposed groundwater withdrawals at the Birch Road well site to affect nearby surface water bodies and wetlands, including Lake Cochituate, the Sudbury River, and the Great Meadows National Wildlife Refuge in east-central Massachusetts. In 2012, the U.S. Geological Survey developed a Phase 1 numerical groundwater model of a complex glacial-sediment aquifer to synthesize hydrogeologic information and simulate potential future pumping scenarios. The model was developed with MODFLOW-NWT, an updated version of a standard USGS numerical groundwater flow modeling program that improves solution of unconfined groundwater flow problems. The groundwater model and investigations of the aquifer improved understanding of groundwater–surface-water interaction and the effects of groundwater withdrawals on surface-water bodies and wetlands in the study area. The initial work also revealed a need for additional information and model refinements to better understand this complex aquifer system.

U-tube based near-surface environmental monitoring in the Shenhua carbon dioxide capture and storage (CCS) project.

Science.gov (United States)

Li, Qi; Song, Ranran; Shi, Hui; Ma, Jianli; Liu, Xuehao; Li, Xiaochun

2018-04-01

The CO 2 injected into deep formations during implementation of carbon dioxide (CO 2 ) capture and storage (CCS) technology may leak and migrate into shallow aquifers or ground surfaces through a variety of pathways over a long period. The leaked CO 2 can threaten shallow environments as well as human health. Therefore, almost all monitoring programs for CCS projects around the world contain near-surface monitoring. This paper presents a U-tube based near-surface monitoring technology focusing on its first application in the Shenhua CCS demonstration project, located in the Ordos Basin, Inner Mongolia, China. First, background information on the site monitoring program of the Shenhua CCS demonstration project was provided. Then, the principle of fluid sampling and the monitoring methods were summarized for the U-tube sampler system, and the monitoring data were analyzed in detail. The U-tube based monitoring results showed that the U-tube sampler system is accurate, flexible, and representative of the subsurface fluid sampling process. The monitoring indicators for the subsurface water and soil gas at the Shenhua CCS site indicate good stratification characteristics. The concentration level of each monitoring indicator decreases with increasing depth. Finally, the significance of this near-surface environmental monitoring technology for CO 2 leakage assessments was preliminarily confirmed at the Shenhua CCS site. The application potential of the U-tube based monitoring technology was also demonstrated during the subsurface environmental monitoring of other CCS projects.

Hydrochemical processes in a shallow coal seam gas aquifer and its overlying stream–alluvial system: implications for recharge and inter-aquifer connectivity

International Nuclear Information System (INIS)

Duvert, Clément; Raiber, Matthias; Owen, Daniel D.R.; Cendón, Dioni I.; Batiot-Guilhe, Christelle; Cox, Malcolm E.

2015-01-01

Highlights: • Major ions and isotopes used to study inter-aquifer mixing in a shallow CSG setting. • Considerable heterogeneity in the water composition of the coal-bearing aquifer. • Rapid recharge of the coal-bearing aquifer through highly fractured igneous rocks. • Potential mixing between the coal-bearing aquifer and downstream alluvial aquifer. • Need to consider the seasonal influences on inter-aquifer mixing in CSG settings. - Abstract: In areas of potential coal seam gas (CSG) development, understanding interactions between coal-bearing strata and adjacent aquifers and streams is of highest importance, particularly where CSG formations occur at shallow depth. This study tests a combination of hydrochemical and isotopic tracers to investigate the transient nature of hydrochemical processes, inter-aquifer mixing and recharge in a catchment where the coal-bearing aquifer is in direct contact with the alluvial aquifer and surface drainage network. A strong connection was observed between the main stream and underlying alluvium, marked by a similar evolution from fresh Ca–Mg–HCO 3 waters in the headwaters towards brackish Ca–Na–Cl composition near the outlet of the catchment, driven by evaporation and transpiration. In the coal-bearing aquifer, by contrast, considerable site-to-site variations were observed, although waters generally had a Na–HCO 3 –Cl facies and high residual alkalinity values. Increased salinity was controlled by several coexisting processes, including transpiration by plants, mineral weathering and possibly degradation of coal organic matter. Longer residence times and relatively enriched carbon isotopic signatures of the downstream alluvial waters were suggestive of potential interactions with the shallow coal-bearing aquifer. The examination of temporal variations in deuterium excess enabled detection of rapid recharge of the coal-bearing aquifer through highly fractured igneous rocks, particularly at the catchment

In situ treatment of arsenic contaminated groundwater by aquifer iron coating: Experimental study

Energy Technology Data Exchange (ETDEWEB)

Xie, Xianjun, E-mail: xjxie@cug.edu.cn [State Key Laboratory of Biogeology and Environmental Geology, School of Environmental Studies, China University of Geosciences, 430074 Wuhan (China); Wang, Yanxin, E-mail: yx.wang@cug.edu.cn [State Key Laboratory of Biogeology and Environmental Geology, School of Environmental Studies, China University of Geosciences, 430074 Wuhan (China); Pi, Kunfu [State Key Laboratory of Biogeology and Environmental Geology, School of Environmental Studies, China University of Geosciences, 430074 Wuhan (China); Liu, Chongxuan [State Key Laboratory of Biogeology and Environmental Geology, School of Environmental Studies, China University of Geosciences, 430074 Wuhan (China); Pacific Northwest National Laboratory, Richland, WA 99354 (United States); Li, Junxia; Liu, Yaqing; Wang, Zhiqiang; Duan, Mengyu [State Key Laboratory of Biogeology and Environmental Geology, School of Environmental Studies, China University of Geosciences, 430074 Wuhan (China)

2015-09-15

In situ arsenic removal from groundwater by an aquifer iron coating method has great potential to be a cost effective and simple groundwater remediation technology, especially in rural and remote areas where groundwater is used as the main water source for drinking. The in situ arsenic removal technology was first optimized by simulating arsenic removal in various quartz sand columns under anoxic conditions. The effectiveness was then evaluated in an actual high-arsenic groundwater environment. The arsenic removal mechanism by the coated iron oxide/hydroxide was investigated under different conditions using scanning electron microscopy (SEM)/X-ray absorption spectroscopy, electron probe microanalysis, and Fourier transformation infrared spectroscopy. Aquifer iron coating method was developed via a 4-step alternating injection of oxidant, iron salt and oxygen-free water. A continuous injection of 5.0 mmol/L FeSO{sub 4} and 2.5 mmol/L NaClO for 96 h can form a uniform goethite coating on the surface of quartz sand without causing clogging. At a flow rate of 7.2 mL/min of the injection reagents, arsenic (as Na{sub 2}HAsO{sub 4}) and tracer fluorescein sodium to pass through the iron-coated quartz sand column were approximately at 126 and 7 column pore volumes, respectively. The retardation factor of arsenic was 23.0, and the adsorption capacity was 0.11 mol As per mol Fe. In situ arsenic removal from groundwater in an aquifer was achieved by simultaneous injections of As(V) and Fe(II) reagents. Arsenic fixation resulted from a process of adsorption/co-precipitation with fine goethite particles by way of bidentate binuclear complexes. Therefore, the study results indicate that the high arsenic removal efficiency of the in situ aquifer iron coating technology likely resulted from the expanded specific surface area of the small goethite particles, which enhanced arsenic sorption capability and/or from co-precipitation of arsenic on the surface of goethite particles

In situ treatment of arsenic contaminated groundwater by aquifer iron coating: Experimental study

International Nuclear Information System (INIS)

Xie, Xianjun; Wang, Yanxin; Pi, Kunfu; Liu, Chongxuan; Li, Junxia; Liu, Yaqing; Wang, Zhiqiang; Duan, Mengyu

2015-01-01

In situ arsenic removal from groundwater by an aquifer iron coating method has great potential to be a cost effective and simple groundwater remediation technology, especially in rural and remote areas where groundwater is used as the main water source for drinking. The in situ arsenic removal technology was first optimized by simulating arsenic removal in various quartz sand columns under anoxic conditions. The effectiveness was then evaluated in an actual high-arsenic groundwater environment. The arsenic removal mechanism by the coated iron oxide/hydroxide was investigated under different conditions using scanning electron microscopy (SEM)/X-ray absorption spectroscopy, electron probe microanalysis, and Fourier transformation infrared spectroscopy. Aquifer iron coating method was developed via a 4-step alternating injection of oxidant, iron salt and oxygen-free water. A continuous injection of 5.0 mmol/L FeSO 4 and 2.5 mmol/L NaClO for 96 h can form a uniform goethite coating on the surface of quartz sand without causing clogging. At a flow rate of 7.2 mL/min of the injection reagents, arsenic (as Na 2 HAsO 4 ) and tracer fluorescein sodium to pass through the iron-coated quartz sand column were approximately at 126 and 7 column pore volumes, respectively. The retardation factor of arsenic was 23.0, and the adsorption capacity was 0.11 mol As per mol Fe. In situ arsenic removal from groundwater in an aquifer was achieved by simultaneous injections of As(V) and Fe(II) reagents. Arsenic fixation resulted from a process of adsorption/co-precipitation with fine goethite particles by way of bidentate binuclear complexes. Therefore, the study results indicate that the high arsenic removal efficiency of the in situ aquifer iron coating technology likely resulted from the expanded specific surface area of the small goethite particles, which enhanced arsenic sorption capability and/or from co-precipitation of arsenic on the surface of goethite particles. - Highlights: �

Neutron Reflectivity Measurement for Polymer Dynamics near Graphene Oxide Monolayers

Science.gov (United States)

Koo, Jaseung

We investigated the diffusion dynamics of polymer chains confined between graphene oxide layers using neutron reflectivity (NR). The bilayers of polymethylmetacrylate (PMMA)/ deuterated PMMA (d-PMMA) films and polystyrene (PS)/d-PS films with various film thickness sandwiched between Langmuir-Blodgett (LB) monolayers of graphene oxide (GO) were prepared. From the NR results, we found that PMMA diffusion dynamics was reduced near the GO surface while the PS diffusion was not significantly changed. This is due to the different strength of GO-polymer interaction. In this talk, these diffusion results will be compared with dewetting dynamics of polymer thin films on the GO monolayers. This has given us the basis for development of graphene-based nanoelectronics with high efficiency, such as heterojunction devices for polymer photovoltaic (OPV) applications.

Pharmaceutical removal during managed aquifer recharge with pretreatment by advanced oxidation

KAUST Repository

Lekkerkerker-Teunissen, Karin

2012-10-01

Organic micropollutants (OMPs) are detected in sources for drinking water and treatment possibilities are investigated. Innovative removal technologies are available such as membrane filtration and advanced oxidation, but also biological treatment should be considered. By combining an advanced oxidation process with managed aquifer recharge (MAR), two complementary processes are expected to provide a hybrid system for OMP removal, according to the multiple barrier approach. Laboratory scale batch reactor experiments were conducted to investigate the removal of dissolved organic carbon (DOC) and 14 different pharmaceutically active compounds (PhACs) from MAR influent water and water subjected to oxidation, under different process conditions. A DOC removal of 10% was found in water under oxic (aerobic) conditions for batch reactor experiments, a similar value for DOC removal was observed in the field. Batch reactor experiments for the removal of PhACs showed that the removal of pharmaceuticals ranged from negligible to more than 90%. Under oxic conditions, seven out of 14 pharmaceuticals were removed over 90% and 12 out of 14 pharmaceuticals were removed at more than 50% during 30 days of experiments. Under anoxic conditions, four out of 14 pharmaceuticals were removed over 90% and eight out of 14 pharmaceuticals were removed at more than 50% over 30 days\\' experiments. Carbamazepine and phenazone were persistent both under oxic and anoxic conditions. The PhACs removal efficiency with oxidized water was, for most compounds, comparable to the removal with MAR influent water. Copyright © IWA Publishing 2012.

Pharmaceutical removal during managed aquifer recharge with pretreatment by advanced oxidation

KAUST Repository

Lekkerkerker-Teunissen, Karin; Chekol, E. T.; Maeng, Sungkyu; Ghebremichael, Kebreab A.; Houtman, Corine J.; Verliefde, Arne R. D.; Verberk, J. Q J C; Amy, Gary L.; Van Dijk, Johannis C.

2012-01-01

Organic micropollutants (OMPs) are detected in sources for drinking water and treatment possibilities are investigated. Innovative removal technologies are available such as membrane filtration and advanced oxidation, but also biological treatment should be considered. By combining an advanced oxidation process with managed aquifer recharge (MAR), two complementary processes are expected to provide a hybrid system for OMP removal, according to the multiple barrier approach. Laboratory scale batch reactor experiments were conducted to investigate the removal of dissolved organic carbon (DOC) and 14 different pharmaceutically active compounds (PhACs) from MAR influent water and water subjected to oxidation, under different process conditions. A DOC removal of 10% was found in water under oxic (aerobic) conditions for batch reactor experiments, a similar value for DOC removal was observed in the field. Batch reactor experiments for the removal of PhACs showed that the removal of pharmaceuticals ranged from negligible to more than 90%. Under oxic conditions, seven out of 14 pharmaceuticals were removed over 90% and 12 out of 14 pharmaceuticals were removed at more than 50% during 30 days of experiments. Under anoxic conditions, four out of 14 pharmaceuticals were removed over 90% and eight out of 14 pharmaceuticals were removed at more than 50% over 30 days' experiments. Carbamazepine and phenazone were persistent both under oxic and anoxic conditions. The PhACs removal efficiency with oxidized water was, for most compounds, comparable to the removal with MAR influent water. Copyright © IWA Publishing 2012.

A long-term bench-scale investigation of permanganate consumption by aquifer materials.

Science.gov (United States)

Xu, Xiuyuan; Thomson, Neil R

2009-11-20

In situ chemical oxidation (ISCO) applications using permanganate involve the injection or release of permanganate into the subsurface to destroy various target contaminants. Naturally occurring reduced components associated with aquifer materials can exert a significant oxidant demand thereby reducing the amount of permanganate available for the destruction of contaminants as well as reducing the overall rate of oxidation. Quantification of this natural oxidant demand (NOD) is a requirement for site-specific assessment and the design of cost-effective oxidant delivery systems. To further our understanding of the interaction between permanganate and aquifer materials, aerobic and anaerobic aquifer materials from eight representative sites throughout North America were tested in a series of systematic bench-scale experiments. Various permanganate to aquifer solids mass loading ratios at different initial permanganate concentrations in well-mixed batch reactors were monitored for >300 days. All NOD temporal profiles demonstrated an initial fast consumption rate followed by a persistent slower consumption rate. The data generated show that the mass loading ratio, the initial permanganate concentration, and the nature and quantity of reduced aquifer material species are the main factors controlling permanganate consumption rates. A higher initial permanganate concentration or a larger mass loading ratio produced a larger fast NOD consumption rate and generated a corresponding higher maximum NOD value. Hence, both the NOD temporal profile and the maximum NOD are not single-valued but are heavily dependent on the experimental conditions. Predictive relationships were developed to estimate the maximum NOD and the NOD at 7 days based on aquifer material properties. The concentration of manganese oxides deposited on the aquifer solids was highly correlated with the mass of permanganate consumed suggesting that passivation of NOD reaction sites occurred due to the formation

Duplex sonography of the near-surface leg veins

International Nuclear Information System (INIS)

Mendoza, E.

2007-01-01

The book contains the following contributions: The ultrasonograph, selection of the ultrasonic transducer, anatomy of the near-surface vein system, physiology of the near-surface vein system, varicose status classification, systematics of the duplex sonography of near-surface leg veins, provocational maneuver for the duplex sonographic varicose diagnostics, exploration of vena saphena parva, perforans veins, side branches, phlebitis, sonography for varicose therapy, postsurgical sonography, deep leg veins, examination of near-surface leg veins for the pathology of the deep vein system, differential diagnostic clarification of leg oedema from the phlebologic-lymphological view, diagnostic side features along the near-surface leg veins

Near-surface land disposal

International Nuclear Information System (INIS)

Kittel, J.H.

1989-01-01

The Radioactive Waste Management Handbook provides a comprehensive, systematic treatment of nuclear waste management. Near-Surface Land Disposal, the first volume, is a primary and secondary reference for the technical community. To those unfamiliar with the field, it provides a bridge to a wealth of technical information, presenting the technology associated with the near-surface disposal of low or intermediate level wastes. Coverage ranges from incipient planning to site closure and subsequent monitoring. The book discusses the importance of a systems approach during the design of new disposal facilities so that performance objectives can be achieved; gives an overview of the radioactive wastes cosigned to near-surface disposal; addresses procedures for screening and selecting sites; and emphasizes the importance of characterizing sites and obtaining reliable geologic and hydrologic data. The planning essential to the development of particular sites (land acquisition, access, layout, surface water management, capital costs, etc.) is considered, and site operations (waste receiving, inspection, emplacement, closure, stabilization, etc.) are reviewed. In addition, the book presents concepts for improved confinement of waste, important aspects of establishing a monitoring program at the disposal facility, and corrective actions available after closure to minimize release. Two analytical techniques for evaluating alternative technologies are presented. Nontechnical issues surrounding disposal, including the difficulties of public acceptance are discussed. A glossary of technical terms is included

Flow of river water into a karstic limestone aquifer - 2. Dating the young fraction in groundwater mixtures in the Upper Floridan aquifer near Valdosta, Georgia

Science.gov (United States)

Plummer, Niel; Busenberg, E.; Drenkard, S.; Schlosser, P.; Ekwurzel, B.; Weppernig, R.; McConnell, J.B.; Michel, R.L.

1998-01-01

Tritium/helium-3 (3H/3He) and chlorofluorocarbon (CFCs, CFC-11, CFC-12, CFC-113) data are used to date the young fraction in groundwater mixtures from a karstic limestone aquifer near Valdosta, Georgia, where regional paleowater in the Upper Floridan aquifer receives recharge from two young sources the flow of Withlacoochee River water through sinkholes in the river bed, and leakage of infiltration water through post-Eocene semi-confining beds above the Upper Floridan aquifer. In dating the young fraction of mixtures using CFCs, it is necessary to reconstruct the CFC concentration that was in the young fraction prior to mixing. The 3H/3He age is independent of the extent of dilution with older (3H-free and 3He(trit)-free) water. The groundwater mixtures are designated as Type-I for mixtures of regional paleowater and regional infiltration water and Type-2 for mixtures containing more than approximately 4% of river water. The fractions of regional paleowater, regional infiltration water, and Withlacoochee River water in the groundwater mixtures were determined from Cl- and ??18O data for water from the Upper Floridan aquifer at Valdosta, Georgia The chlorofluorocarbons CFC-11 and CFC-113 are removed by microbial degradation and/or sorption processes in most allaerobic (Type-2) groundwater at Valdosta, but are present in some aerobic Type-I water. CFC-12 persists in both SO4-reducing and methanogenic water. The very low detection limits for CFCs (approximately 0.3 pg kg-1) permitted CFC-11 and CFC-12 dating of the fraction of regional infiltration water in Type-I mixtures, and CFC-12 dating of the river-water fraction in Type-2 mixtures. Overall, approximately 50% of the 85 water sam pies obtained from the Upper Floridan aquifer have CFC-12-based ages of the young traction that are consistent with the 3H concentration of the groundwater. Because of uncertainties associated with very low 3H and 3He content in dilute mixtures, 3H/3He dating is limited to the river

Cenomanian-Turonian aquifer of central Israel, its development and possible use as a storage reservoir

Science.gov (United States)

Schneider, Robert

1964-01-01

The Cenomanian-Turonian formations constitute a highly permeable dolomite and limestone aquifer in central Israel. The aquifer is on the west limb of an anticlinorium that trends north-northeast. In places it may be as much as 800 meters thick, but in the report area, largely the foothills of the Judean-Ephraim Mountains where the water development is most intensive, its thickness is generally considerably less. In some places the aquifer occurs at or near the land surface, or it is covered by sandy and gravelly coastal-plain deposits. However, in a large part of the area, it is overlain by as much as 400 meters of relatively impermeable strata, and it is probably underlain by less permeable Lower Cretaceous strata. In general the aquifer water is under artesian pressure. The porosity of the aquifer is characterized mainly by solution channels and cavities produced by jointing and faulting. In addition to the generally high permeability of the aquifer, some regions, which probably coincide with ancient drainage patterns and (or) fault zones, have exceptionally high permeabilities. The source of most of the water in the aquifer is believed to be rain that falls on the foothills area. The westward movement of ground water from the mountainous outcrop areas appears to be impeded by a zone of low permeability which is related to structural and stratigraphic conditions along the western side of the mountains. Gradients of the piezometric surface are small, and the net direction of water movement is westward and northwestward under natural conditions. Locally, however, the flow pattern may be in other directions owing to spatial variations in permeability in the aquifer, the location of natural discharge outlets, and the relation of the aquifer to adjacent geologic formations. There probably is also a large vertical component of flow. Pumping has modified the flow pattern by producing several irregularly shaped shallow depressions in the piezometric surface although, to

Application of Surface Geophysical Methods, With Emphasis on Magnetic Resonance Soundings, to Characterize the Hydrostratigraphy of the Brazos River Alluvium Aquifer, College Station, Texas, July 2006 - A Pilot Study

Science.gov (United States)

Shah, Sachin D.; Kress, Wade H.; Legchenko, Anatoly

2007-01-01

The U.S. Geological Survey, in cooperation with the Texas Water Development Board, used surface geophysical methods at the Texas A&M University Brazos River Hydrologic Field Research Site near College Station, Texas, in a pilot study, to characterize the hydrostratigraphic properties of the Brazos River alluvium aquifer and determine the effectiveness of the methods to aid in generating an improved ground-water availability model. Three non-invasive surface geophysical methods were used to characterize the electrical stratigraphy and hydraulic properties and to interpret the hydrostratigraphy of the Brazos River alluvium aquifer. Two methods, time-domain electromagnetic (TDEM) soundings and two-dimensional direct-current (2D-DC) resistivity imaging, were used to define the lateral and vertical extent of the Ships clay, the alluvium of the Brazos River alluvium aquifer, and the underlying Yegua Formation. Magnetic resonance sounding (MRS), a recently developed geophysical method, was used to derive estimates of the hydrologic properties including percentage water content and hydraulic conductivity. Results from the geophysics study demonstrated the usefulness of combined TDEM, 2D-DC resistivity, and MRS methods to reduce the need for additional boreholes in areas with data gaps and to provide more accurate information for ground-water availability models. Stratigraphically, the principal finding of this study is the relation between electrical resistivity and the depth and thickness of the subsurface hydrostratigraphic units at the site. TDEM data defined a three-layer electrical stratigraphy corresponding to a conductor-resistor-conductor that represents the hydrostratigraphic units - the Ships clay, the alluvium of the Brazos River alluvium aquifer, and the Yegua Formation. Sharp electrical boundaries occur at about 4 to 6 and 20 to 22 meters below land surface based on the TDEM data and define the geometry of the more resistive Brazos River alluvium aquifer

In situ treatment of arsenic contaminated groundwater by aquifer iron coating: Experimental study.

Science.gov (United States)

Xie, Xianjun; Wang, Yanxin; Pi, Kunfu; Liu, Chongxuan; Li, Junxia; Liu, Yaqing; Wang, Zhiqiang; Duan, Mengyu

2015-09-15

In situ arsenic removal from groundwater by an aquifer iron coating method has great potential to be a cost effective and simple groundwater remediation technology, especially in rural and remote areas where groundwater is used as the main water source for drinking. The in situ arsenic removal technology was first optimized by simulating arsenic removal in various quartz sand columns under anoxic conditions. The effectiveness was then evaluated in an actual high-arsenic groundwater environment. The arsenic removal mechanism by the coated iron oxide/hydroxide was investigated under different conditions using scanning electron microscopy (SEM)/X-ray absorption spectroscopy, electron probe microanalysis, and Fourier transformation infrared spectroscopy. Aquifer iron coating method was developed via a 4-step alternating injection of oxidant, iron salt and oxygen-free water. A continuous injection of 5.0 mmol/L FeSO4 and 2.5 mmol/L NaClO for 96 h can form a uniform goethite coating on the surface of quartz sand without causing clogging. At a flow rate of 7.2 mL/min of the injection reagents, arsenic (as Na2HAsO4) and tracer fluorescein sodium to pass through the iron-coated quartz sand column were approximately at 126 and 7 column pore volumes, respectively. The retardation factor of arsenic was 23.0, and the adsorption capacity was 0.11 mol As per mol Fe. In situ arsenic removal from groundwater in an aquifer was achieved by simultaneous injections of As(V) and Fe(II) reagents. Arsenic fixation resulted from a process of adsorption/co-precipitation with fine goethite particles by way of bidentate binuclear complexes. Therefore, the study results indicate that the high arsenic removal efficiency of the in situ aquifer iron coating technology likely resulted from the expanded specific surface area of the small goethite particles, which enhanced arsenic sorption capability and/or from co-precipitation of arsenic on the surface of goethite particles. Copyright © 2015

Potentiometric Surface in the Sparta-Memphis Aquifer of the Mississippi Embayment, Spring 2007

Science.gov (United States)

Schrader, T.P.

2008-01-01

-Memphis aquifer in the Mississippi embayment was about 540 million gallons per day (Mgal/d). Water use from the Sparta-Memphis aquifer was about 170 Mgal/d in Arkansas, about 68 Mgal/d in Louisiana, about 97 Mgal/d in Mississippi, and about 205 Mgal/d in Tennessee. The author acknowledges, with great appreciation, the efforts of the personnel in the U.S. Geological Survey Water Science Centers of Arkansas, Kentucky, Louisiana, Mississippi, Missouri, and Tennessee, and the Mississippi Department of Environmental Quality Office of Land and Water Resources that participated in the planning, water-level measurement, data evaluation, and review of the potentiometric-surface map. Without the contribution of data and the technical assistance of their staffs, this report would not have been completed.

Dust Dynamics Near Planetary Surfaces

Science.gov (United States)

Colwell, Joshua; Hughes, Anna; Grund, Chris

Observations of a lunar "horizon glow" by several Surveyor spacecraft in the 1960s opened the study of the dynamics of charged dust particles near planetary surfaces. The surfaces of the Moon and other airless planetary bodies in the solar system (asteroids, and other moons) are directly exposed to the solar wind and ionizing solar ultraviolet radiation, resulting in a time-dependent electric surface potential. Because these same objects are also exposed to bombardment by micrometeoroids, the surfaces are usually characterized by a power-law size distribution of dust that extends to sub-micron-sized particles. Individual particles can acquire a charge different from their surroundings leading to electrostatic levitation. Once levitated, particles may simply return to the surface on nearly ballistic trajectories, escape entirely from the moon or asteroid if the initial velocity is large, or in some cases be stably levitated for extended periods of time. All three outcomes have observable consequences. Furthermore, the behavior of charged dust near the surface has practical implications for planned future manned and unmanned activities on the lunar surface. Charged dust particles also act as sensitive probes of the near-surface plasma environment. Recent numerical modeling of dust levitation and transport show that charged micron-sized dust is likely to accumulate in topographic lows such as craters, providing a mechanism for the creation of dust "ponds" observed on the asteroid 433 Eros. Such deposition can occur when particles are supported by the photoelectron sheath above the dayside and drift over shadowed regions of craters where the surface potential is much smaller. Earlier studies of the lunar horizon glow are consistent with those particles being on simple ballistic trajectories following electrostatic launching from the surface. Smaller particles may be accelerated from the lunar surface to high altitudes consistent with observations of high altitude

Benzene dynamics and biodegradation in alluvial aquifers affected by river fluctuations.

Science.gov (United States)

Batlle-Aguilar, J; Morasch, B; Hunkeler, D; Brouyère, S

2014-01-01

The spatial distribution and temporal dynamics of a benzene plume in an alluvial aquifer strongly affected by river fluctuations was studied. Benzene concentrations, aquifer geochemistry datasets, past river morphology, and benzene degradation rates estimated in situ using stable carbon isotope enrichment were analyzed in concert with aquifer heterogeneity and river fluctuations. Geochemistry data demonstrated that benzene biodegradation was on-going under sulfate reducing conditions. Long-term monitoring of hydraulic heads and characterization of the alluvial aquifer formed the basis of a detailed modeled image of aquifer heterogeneity. Hydraulic conductivity was found to strongly correlate with benzene degradation, indicating that low hydraulic conductivity areas are capable of sustaining benzene anaerobic biodegradation provided the electron acceptor (SO4 (2-) ) does not become rate limiting. Modeling results demonstrated that the groundwater flux direction is reversed on annual basis when the river level rises up to 2 m, thereby forcing the infiltration of oxygenated surface water into the aquifer. The mobilization state of metal trace elements such as Zn, Cd, and As present in the aquifer predominantly depended on the strong potential gradient within the plume. However, infiltration of oxygenated water was found to trigger a change from strongly reducing to oxic conditions near the river, causing mobilization of previously immobile metal species and vice versa. MNA appears to be an appropriate remediation strategy in this type of dynamic environment provided that aquifer characterization and targeted monitoring of redox conditions are adequate and electron acceptors remain available until concentrations of toxic compounds reduce to acceptable levels. © 2013, National Ground Water Association.

Presence, distribution, and diversity of iron-oxidizing bacteria at a landfill leachate-impacted groundwater surface water interface

DEFF Research Database (Denmark)

Yu, R.; Gan, P.; Mackay, A.A.

2010-01-01

) were dominated by members of the Bradyrhizobiaceae and Comamonadaceae; clones from the deeper sediments were phylogenetically more diverse, dominated by members of the Rhodocyclaceae. The iron deposition profiles indicated that active iron oxidation occurred only within the near-to-surface GSI......We examined the presence of iron-oxidizing bacteria (IOB) at a groundwater surface water interface (GSI) impacted by reduced groundwater originating as leachate from an upgradient landfill. IOB enrichments and quantifications were obtained, at high vertical resolution, by an iron/oxygen opposing...... site mirrored the IOB distribution. Clone libraries from two separate IOB enrichments indicated a stratified IOB community with clear differences at short vertical distances. Alpha- and Betaproteobacteria were the dominant phylotypes. Clones from the near-surface sediment (1-2 cm below ground surface...

The Role of Science in Managed Aquifer Recharge--the Equus Beds aquifer near Wichita, Kansas Andrew Ziegler, Director Brian Kelly, Office Chief Michael Jacobs, Manager of Water Planning and Production Debra Ary, Engineer, Water Systems Planning (Invited)

Science.gov (United States)

Ziegler, A. C.; Jacobs, M.; Ary, D.; Kelly, B.

2013-12-01

Data collection and interpretation using statistical, geochemical, and numerical simulation tools are essential parts of a long-term cooperative study between the city of Wichita, U.S. Geological Survey, and others to describe water quantity and quality conditions in a 165 square-mile part of the Equus Beds aquifer and Arkansas and Little Arkansas Rivers. The Equus Beds aquifer, eastern part of the High Plains Aquifer in south-central Kansas, is a vital water resource for agriculture and city of Wichita. Withdrawals for public supply began in the 1940s and agricultural irrigation began in the 1950-60s. These withdrawals led to water-level declines of up to 40 feet (historic low in 1993), a storage loss of 250,000 acre feet compared to predevelopment, and may enhance movement of chloride contamination from a past oilfield disposal area near Burrton and from natural chloride along the Arkansas River. Monitoring data and modeling show chloride near Burrton moved about 3 miles in 45 years, is about 1 mile away from the nearest public supply wells, and will continue to move for decades to centuries making the water unusable for irrigation or water supply without treatment. These concerns led to development of Wichita's 1993 integrated local water-supply plan that increased use of Cheney Reservoir and implemented aquifer storage and recovery (ASR) within the aquifer using high flows from the Little Arkansas River. ASR benefits include replacing depleted storage and slowing chloride movement. Decreased withdrawals, increased precipitation, and artificial recharge increased water levels and added 100,000 acre feet of storage through 2010, but drought since 2011 has increased withdrawals. A calibrated model will be used to simulate transport of chloride under several withdrawal scenarios using MODFLOW coupled with SEAWAT. Since 1995, water-quality data collection for more than 400 organic and inorganic compounds in surface water, treated source water for artificial recharge

Oxidation feature and diffusion mechanism of Zr-based metallic glasses near the glass transition point

Science.gov (United States)

Hu, Zheng; Lei, Xianqi; Wang, Yang; Zhang, Kun

2018-03-01

The oxidation behaviors of as-cast, pre-deformed, and crystallized Zr47.9Ti0.3Ni3.1Cu39.3Al9.4 metallic glasses (MGs) were studied near the glass transition point. The oxidation kinetics of the crystallized MGs followed a parabolic-rate law, and the as-cast and pre-deformed MGs exerted a typical two-stage behavior above the glass transition temperature (T g). Most interesting, pre-deformed treatment can significantly improve the oxidation rate of MGs, as the initial oxidation appeared earlier than for the as-cast MGs, and was accompanied by much thicker oxide scale. The EDS and XPS results showed that the metal Al acted as the preferred scavenger that absorbed intrinsic oxygen in the near-surface region of as-cast MGs. However, a homogeneous mixed layer without Al was observed in the pre-deformed MGs. We speculated the accelerated diffusion of other elements in the MGs was due to the local increase in the free volume and significant shear-induced dilation of the local structure. The results from this study demonstrate that MGs exhibit controllable atomic diffusion during the oxidation process, which can facilitate use in super-cooled liquid region applications.

Comparison of physico-chemical parameters of groundwater from shallow aquifers near 2 thermal power plants in Punjab

International Nuclear Information System (INIS)

Gill, S.K.; Sahota, S.K.; Sahota, G.P.S.; Sahota, B.K.; Sahota, H.S.

1993-01-01

Physico-chemical parameters of groundwater from shallow aquifers near thermal power plants at Bathinda and Ropar have been measured. Increase in metallic content of water is noted in both the cases due to deposition of coal fly ash from the power plants on the soil. High values of calcium chloride, calcium carbonate and total dissolved solids are observed in Bathinda groundwater while Ropar groundwater is rich in ferric, fluoride and nitrate contents. (author). 8 refs., 1 fig., 1 tab

Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1

Energy Technology Data Exchange (ETDEWEB)

Bacon, Diana H.

2013-03-31

The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite

Ozark Aquifer

Data.gov (United States)

Kansas Data Access and Support Center — These digital maps contain information on the altitude of the base and top, the extent, and the potentiometric surface of the Ozark aquifer in Kansas. The Ozark...

Determining Changes in Groundwater Quality during Managed Aquifer Recharge

Science.gov (United States)

Gambhir, T.; Houlihan, M.; Fakhreddine, S.; Dadakis, J.; Fendorf, S. E.

2016-12-01

Managed aquifer recharge (MAR) is becoming an increasingly prevalent technology for improving the sustainability of freshwater supply. However, recharge water can alter the geochemical conditions of the aquifer, mobilizing contaminants native to the aquifer sediments. Geochemical alterations on deep (>300 m) injection of highly treated recycled wastewater for MAR has received limited attention. We aim to determine how residual disinfectants used in water treatment processes, specifically the strong oxidants chloramine and hydrogen peroxide, affect metal mobilization within deep injection wells of the Orange County Water District. Furthermore, as the treated recharge water has very low ionic strength (44.6 mg L-1 total dissolved solids), we tested how differing concentrations of magnesium chloride and calcium chloride affected metal mobilization within deep aquifers. Continuous flow experiments were conducted on columns dry packed with sediments from a deep injection MAR site in Orange County, CA. The effluent was analyzed for shifts in water quality, including aqueous concentrations of arsenic, uranium, and chromium. Interaction between the sediment and oxic recharge solution causes naturally-occurring arsenopyrite to repartition onto iron oxides. The stability of arsenic on the newly precipitated iron oxides is dependent on pH changes during recharge.

Estimating Groundwater Mounding in Sloping Aquifers for Managed Aquifer Recharge.

Science.gov (United States)

Zlotnik, Vitaly A; Kacimov, Anvar; Al-Maktoumi, Ali

2017-11-01

Design of managed aquifer recharge (MAR) for augmentation of groundwater resources often lacks detailed data, and simple diagnostic tools for evaluation of the water table in a broad range of parameters are needed. In many large-scale MAR projects, the effect of a regional aquifer base dip cannot be ignored due to the scale of recharge sources (e.g., wadis, streams, reservoirs). However, Hantush's (1967) solution for a horizontal aquifer base is commonly used. To address sloping aquifers, a new closed-form analytical solution for water table mound accounts for the geometry and orientation of recharge sources at the land surface with respect to the aquifer base dip. The solution, based on the Dupiuit-Forchheimer approximation, Green's function method, and coordinate transformations is convenient for computing. This solution reveals important MAR traits in variance with Hantush's solution: mounding is limited in time and space; elevation of the mound is strongly affected by the dip angle; and the peak of the mound moves over time. These findings have important practical implications for assessment of various MAR scenarios, including waterlogging potential and determining proper rates of recharge. Computations are illustrated for several characteristic MAR settings. © 2017, National Ground Water Association.

Effects of Subsurface Microbial Ecology on Geochemical Evolution of a Crude-Oil Contaminated Aquifer

Science.gov (United States)

Bekins, B. A.; Cozzarelli, I. M.; Godsy, E. M.; Warren, E.; Hostettler, F. D.

2001-12-01

We have identified several subsurface habitats for microorganisms in a crude oil contaminated located near Bemidji, Minnesota. These aquifer habitats include: 1) the unsaturated zone contaminated by hydrocarbon vapors, 2) the zones containing separate-phase crude oil, and 3) the aqueous-phase contaminant plume. The surficial glacial outwash aquifer was contaminated when a crude oil pipeline burst in 1979. We analyzed sediment samples from the contaminated aquifer for the most probable numbers of aerobes, iron reducers, fermenters, and three types of methanogens. The microbial data were then related to gas, water, and oil chemistry, sediment extractable iron, and permeability. The microbial populations in the various contaminated subsurface habitats each have special characteristics and these affect the aquifer and contaminant chemistry. In the eight-meter-thick, vapor-contaminated vadose zone, a substantial aerobic population has developed that is supported by hydrocarbon vapors and methane. Microbial numbers peak in locations where access to both hydrocarbons and nutrients infiltrating from the surface is maximized. The activity of this population prevents hydrocarbon vapors from reaching the land surface. In the zone where separate-phase crude oil is present, a consortium of methanogens and fermenters dominates the populations both above and below the water table. Moreover, gas concentration data indicate that methane production has been active in the oily zone since at least 1986. Analyses of the extracted separate-phase oil show that substantial degradation of C15 -C35 n-alkanes has occurred since 1983, raising the possibility that significant degradation of C15 and higher n-alkanes has occurred under methanogenic conditions. However, lab and field data suggest that toxic inhibition by crude oil results in fewer acetate-utilizing methanogens within and adjacent to the separate-phase oil. Data from this and other sites indicate that toxic inhibition of

Fate of Arsenic during Red River Water Infiltration into Aquifers beneath Hanoi, Vietnam.

Science.gov (United States)

Postma, Dieke; Mai, Nguyen Thi Hoa; Lan, Vi Mai; Trang, Pham Thi Kim; Sø, Helle Ugilt; Nhan, Pham Quy; Larsen, Flemming; Viet, Pham Hung; Jakobsen, Rasmus

2017-01-17

Recharge of Red River water into arsenic-contaminated aquifers below Hanoi was investigated. The groundwater age at 40 m depth in the aquifer underlying the river was 1.3 ± 0.8 years, determined by tritium-helium dating. This corresponds to a vertical flow rate into the aquifer of 19 m/year. Electrical conductivity and partial pressure of CO 2 (P CO 2 ) indicate that water recharged from the river is present in both the sandy Holocene and gravelly Pleistocene aquifers and is also abstracted by the pumping station. Infiltrating river water becomes anoxic in the uppermost aquifer due to the oxidation of dissolved organic carbon. Further downward, sedimentary carbon oxidation causes the reduction of As-containing Fe-oxides. Because the release of arsenic by reduction of Fe-oxides is controlled by the reaction rate, arsenic entering the solution becomes highly diluted in the high water flux and contributes little to the groundwater arsenic concentration. Instead, the As concentration in the groundwater of up to 1 μM is due to equilibrium-controlled desorption of arsenic, adsorbed to the sediment before river water started to infiltrate due to municipal pumping. Calculations indicate that it will take several decades of river water infiltration to leach arsenic from the Holocene aquifer to below the World Health Organization limit of 10 μg/L.

Fate of Arsenic during Red River Water Infiltration into Aquifers beneath Hanoi, Vietnam

Science.gov (United States)

2016-01-01

Recharge of Red River water into arsenic-contaminated aquifers below Hanoi was investigated. The groundwater age at 40 m depth in the aquifer underlying the river was 1.3 ± 0.8 years, determined by tritium–helium dating. This corresponds to a vertical flow rate into the aquifer of 19 m/year. Electrical conductivity and partial pressure of CO2 (PCO2) indicate that water recharged from the river is present in both the sandy Holocene and gravelly Pleistocene aquifers and is also abstracted by the pumping station. Infiltrating river water becomes anoxic in the uppermost aquifer due to the oxidation of dissolved organic carbon. Further downward, sedimentary carbon oxidation causes the reduction of As-containing Fe-oxides. Because the release of arsenic by reduction of Fe-oxides is controlled by the reaction rate, arsenic entering the solution becomes highly diluted in the high water flux and contributes little to the groundwater arsenic concentration. Instead, the As concentration in the groundwater of up to 1 μM is due to equilibrium-controlled desorption of arsenic, adsorbed to the sediment before river water started to infiltrate due to municipal pumping. Calculations indicate that it will take several decades of river water infiltration to leach arsenic from the Holocene aquifer to below the World Health Organization limit of 10 μg/L. PMID:27958705

Positron annihilation near fractal surfaces

International Nuclear Information System (INIS)

Lung, C.W.; Deng, K.M.; Xiong, L.Y.

1991-07-01

A model for positron annihilation in the sub-surface region near a fractal surface is proposed. It is found that the power law relationship between the mean positron implantation depth and incident positron energy can be used to measure the fractal dimension of the fractal surface in materials. (author). 10 refs, 2 figs

Spectroscopic investigation of oxidized solder surfaces

International Nuclear Information System (INIS)

Song, Jenn-Ming; Chang-Chien, Yu-Chien; Huang, Bo-Chang; Chen, Wei-Ting; Shie, Chi-Rung; Hsu, Chuang-Yao

2011-01-01

Highlights: → UV-visible spectroscopy is successfully used to evaluate the degree of discoloring of solders. → The surface oxides of solders can also be identified by UV-visible absorption spectra. → The discoloration of solder surface can be correlated with optical characterization of oxides. → A strategy against discoloring by alloying was also suggested. - Abstract: For further understanding of the discoloration of solder surfaces due to oxidation during the assembly and operation of electronic devices, UV-vis and X-ray photoelectron spectroscopic analyses were applied to evaluate the degree of discoloring and identify the surface oxides. The decrease in reflectance of the oxidized solder surface is related to SnO whose absorption band is located within the visible region. A trace of P can effectively depress the discoloration of solders under both solid and semi-solid states through the suppression of SnO.

Oxidation of Ethylene Carbonate on Li Metal Oxide Surfaces

DEFF Research Database (Denmark)

Østergaard, Thomas M.; Giordano, Livia; Castelli, Ivano Eligio

2018-01-01

Understanding the reactivity of the cathode surface is of key importance to the development of batteries. Here, density functional theory is applied to investigate the oxidative decomposition of the electrolyte component, ethylene carbonate (EC), on layered LixMO(2) oxide surfaces. We compare...

Temporal and spatial variations in groundwater quality resulting from policy-induced reductions in nitrate leaching to the Rabis Creek aquifer, Denmark

Science.gov (United States)

Jessen, Søren; Engesgaard, Peter; Thorling, Lærke; Müller, Sascha; Leskelä, Jari; Postma, Dieke

2016-04-01

Twenty-five years of annual groundwater quality monitoring data from the sandy unconfined Rabis Creek aquifer were used to assess the effects of political actions aimed to reduce nitrate leaching to the aquifer. Data were collected from eight multilevel samplers along a ˜3 km transect, which follows the general direction of groundwater flow. Each multilevel sampler comprises 20 screens placed with a 1 m vertical distance from near the water table downwards. The transect covers areas of livestock, plantation & heath, and agriculture. The history of nitrate leaching to the aquifer was assessed using data from screens close to the water table of multilevel samplers placed within agricultural areas. According to these data, nitrate concentrations of infiltrating 'agricultural' water peaked at 2-3 mM (120-180 mg/L) in the year 1989, and then gradually decreased and stabilized at 0.25-1.0 mM (15-60 mg/L) from year 2000. Local farmers declare having used the maximum fertilization rate allowed during the period. The timing of the observed decrease therefore suggests a direct link to the political action plans implemented in the same period. Parallel to the development in nitrate leaching, although with a transport time lag, the average concentration of nitrate in the oxic zone of the aquifer was roughly halved between 2000 and 2013. As a response to political initiatives of the late 1980'ies, part of the area covering the aquifer was changed from agriculture to non-fertilized grass for livestock; the data shows that this effectively remediated the aquifer underneath in less than 20 years, to become nitrate-free and attain background sulfate levels. The oxidized and pyritic reduced zone of the aquifer is separated by a <1 m redoxcline. Denitrification by the pyrite releases sulfate that is retained down-gradient as a tracer for historical nitrate loading to the aquifer. Thus sulfate concentrations currently increase in the multilevel samplers positioned furthest down

Characterizing groundwater/surface-water interactions in the interior of Jianghan Plain, central China

Science.gov (United States)

Du, Yao; Ma, Teng; Deng, Yamin; Shen, Shuai; Lu, Zongjie

2018-01-01

Quantifying groundwater/surface-water interactions is essential for managing water resources and revealing contaminant fate. There has been little concern on the exchange between streams and aquifers through an extensive aquitard thus far. In this study, hydrogeologic calculation and tritium modeling were jointly applied to characterize such interactions through an extensive aquitard in the interior of Jianghan Plain, an alluvial plain of Yangtze River, China. One groundwater simulation suggested that the lateral distance of influence from the river was about 1,000 m; vertical flow in the aquitard followed by lateral flow in the aquifer contributed significantly more ( 90%) to the aquifer head change near the river than lateral bank storage in the aquitard followed by infiltration. The hydrogeologic calculation produced vertical fluxes of the order 0.01 m/day both near and farther from the river, suggesting that similar shorter-lived (half-monthly) vertical fluxes occur between the river and aquitard near the river, and between the surface end members and aquitard farther from the river. Tritium simulation based on the OTIS model produced an average groundwater residence time of about 15 years near the river and a resulting vertical flux of the order 0.001 m/day. Another tritium simulation based on a dispersion model produced a vertical flux of the order 0.0001 m/day away from the river, coupled with an average residence time of around 90 years. These results suggest an order of magnitude difference for the longer-lived (decadal) vertical fluxes between surface waters and the aquifer near and away from the river.

Karst aquifer characterization using geophysical remote sensing of dynamic recharge events

Science.gov (United States)

Grapenthin, R.; Bilek, S. L.; Luhmann, A. J.

2017-12-01

Geophysical monitoring techniques, long used to make significant advances in a wide range of deeper Earth science disciplines, are now being employed to track surficial processes such as landslide, glacier, and river flow. Karst aquifers are another important hydrologic resource that can benefit from geophysical remote sensing, as this monitoring allows for safe, noninvasive karst conduit measurements. Conduit networks are typically poorly constrained, let alone the processes that occur within them. Geophysical monitoring can also provide a regionally integrated analysis to characterize subsurface architecture and to understand the dynamics of flow and recharge processes in karst aquifers. Geophysical signals are likely produced by several processes during recharge events in karst aquifers. For example, pressure pulses occur when water enters conduits that are full of water, and experiments suggest seismic signals result from this process. Furthermore, increasing water pressure in conduits during recharge events increases the load applied to conduit walls, which deforms the surrounding rock to yield measureable surface displacements. Measureable deformation should also occur with mass loading, with subsidence and rebound signals associated with increases and decreases of water mass stored in the aquifer, respectively. Additionally, geophysical signals will likely arise with turbulent flow and pore pressure change in the rock surrounding conduits. Here we present seismic data collected during a pilot study of controlled and natural recharge events in a karst aquifer system near Bear Spring, near Eyota, MN, USA as well as preliminary model results regarding the processes described above. In addition, we will discuss an upcoming field campaign where we will use seismometers, tiltmeters, and GPS instruments to monitor for recharge-induced responses in a FL, USA karst system with existing cave maps, coupling these geophysical observations with hydrologic and

Regional Variation of CH4 and N2 Production Processes in the Deep Aquifers of an Accretionary Prism.

Science.gov (United States)

Matsushita, Makoto; Ishikawa, Shugo; Nagai, Kazushige; Hirata, Yuichiro; Ozawa, Kunio; Mitsunobu, Satoshi; Kimura, Hiroyuki

2016-09-29

Accretionary prisms are mainly composed of ancient marine sediment scraped from the subducting oceanic plate at a convergent plate boundary. Large amounts of anaerobic groundwater and natural gas, mainly methane (CH4) and nitrogen gas (N2), are present in the deep aquifers associated with an accretionary prism; however, the origins of these gases are poorly understood. We herein revealed regional variations in CH4 and N2 production processes in deep aquifers in the accretionary prism in Southwest Japan, known as the Shimanto Belt. Stable carbon isotopic and microbiological analyses suggested that CH4 is produced through the non-biological thermal decomposition of organic matter in the deep aquifers in the coastal area near the convergent plate boundary, whereas a syntrophic consortium of hydrogen (H2)-producing fermentative bacteria and H2-utilizing methanogens contributes to the significant production of CH4 observed in deep aquifers in midland and mountainous areas associated with the accretionary prism. Our results also demonstrated that N2 production through the anaerobic oxidation of organic matter by denitrifying bacteria is particularly prevalent in deep aquifers in mountainous areas in which groundwater is affected by rainfall.

Flow of river water into a karstic limestone aquifer-2. Dating the young fraction in groundwater mixtures in the Upper Floridan aquifer near Valdosta, Georgia

Energy Technology Data Exchange (ETDEWEB)

Plummer, L.N.; Busenberg, E. [U.S. Geological Survey, 432 National Center, Reston, VA (United States); Drenkard, S.; Schlosser, P.; Ekwurzel, B.; Weppernig, R. [Lamont-Doherty Earth Observatory of Columbia University, 61 Route 9W, Palisades, NY (United States); McConnell, J.B. [U.S. Geological Survey, 3039 Amwiler Rd., Atlanta, GA (United States); Michel, R.L. [U.S. Geological Survey, Mail Stop 434, 345 Middlefield Road, Menlo Park, CA (United States)

1998-11-01

Tritium/helium-3 ({sup 3}H/{sup 3}He) and chlorofluorocarbon (CFCs, CFC-11, CFC-12, CFC-113) data are used to date the young fraction in groundwater mixtures from a karstic limestone aquifer near Valdosta, Georgia, where regional paleowater in the Upper Floridan aquifer receives recharge from two young sources-the flow of Withlacoochee River water through sinkholes in the river bed, and leakage of infiltration water through post-Eocene semi-confining beds above the Upper Floridan aquifer. In dating the young fraction of mixtures using CFCs, it is necessary to reconstruct the CFC concentration that was in the young fraction prior to mixing. The {sup 3}H/{sup 3}He age is independent of the extent of dilution with older ({sup 3}H-free and {sup 3}He{sub trit}-free) water. The groundwater mixtures are designated as Type-1 for mixtures of regional paleowater and regional infiltration water and Type-2 for mixtures containing more than approximately 4% of river water. The fractions of regional paleowater, regional infiltration water, and Withlacoochee River water in the groundwater mixtures were determined from Cl{sup -} and {delta}{sup 18}O data for water from the Upper Floridan aquifer at Valdosta, Georgia.The chlorofluorocarbons CFC-11 and CFC-113 are removed by microbial degradation and/or sorption processes in most anaerobic (Type-2) groundwater at Valdosta, but are present in some aerobic Type-1 water. CFC-12 persists in both SO{sub 4}-reducing and methanogenic water. The very low detection limits for CFCs (approximately 0.3 pg kg{sup -1}) permitted CFC-11 and CFC-12 dating of the fraction of regional infiltration water in Type-1 mixtures, and CFC-12 dating of the river-water fraction in Type-2 mixtures. Overall, approximately 50% of the 85 water samples obtained from the Upper Floridan aquifer have CFC-12-based ages of the young fraction that are consistent with the {sup 3}H concentration of the groundwater. Because of uncertainties associated with very low {sup 3}H

Flow of river water into a karstic limestone aquifer-2. Dating the young fraction in groundwater mixtures in the Upper Floridan aquifer near Valdosta, Georgia

International Nuclear Information System (INIS)

Plummer, L.N.; Busenberg, E.; Drenkard, S.; Schlosser, P.; Ekwurzel, B.; Weppernig, R.; McConnell, J.B.; Michel, R.L.

1998-01-01

Tritium/helium-3 ( 3 H/ 3 He) and chlorofluorocarbon (CFCs, CFC-11, CFC-12, CFC-113) data are used to date the young fraction in groundwater mixtures from a karstic limestone aquifer near Valdosta, Georgia, where regional paleowater in the Upper Floridan aquifer receives recharge from two young sources-the flow of Withlacoochee River water through sinkholes in the river bed, and leakage of infiltration water through post-Eocene semi-confining beds above the Upper Floridan aquifer. In dating the young fraction of mixtures using CFCs, it is necessary to reconstruct the CFC concentration that was in the young fraction prior to mixing. The 3 H/ 3 He age is independent of the extent of dilution with older ( 3 H-free and 3 He trit -free) water. The groundwater mixtures are designated as Type-1 for mixtures of regional paleowater and regional infiltration water and Type-2 for mixtures containing more than approximately 4% of river water. The fractions of regional paleowater, regional infiltration water, and Withlacoochee River water in the groundwater mixtures were determined from Cl - and δ 18 O data for water from the Upper Floridan aquifer at Valdosta, Georgia.The chlorofluorocarbons CFC-11 and CFC-113 are removed by microbial degradation and/or sorption processes in most anaerobic (Type-2) groundwater at Valdosta, but are present in some aerobic Type-1 water. CFC-12 persists in both SO 4 -reducing and methanogenic water. The very low detection limits for CFCs (approximately 0.3 pg kg -1 ) permitted CFC-11 and CFC-12 dating of the fraction of regional infiltration water in Type-1 mixtures, and CFC-12 dating of the river-water fraction in Type-2 mixtures. Overall, approximately 50% of the 85 water samples obtained from the Upper Floridan aquifer have CFC-12-based ages of the young fraction that are consistent with the 3 H concentration of the groundwater. Because of uncertainties associated with very low 3 H and 3 He content in dilute mixtures, 3 H/ 3 He dating is

Direct detection of near-surface faults by migration of back-scattered surface waves

KAUST Repository

Yu, Han; Guo, Bowen; Hanafy, Sherif; Lin, Fan-Chi; Schuster, Gerard T.

2014-01-01

We show that diffraction stack migration can be used to estimate the distribution of near-surface faults. The assumption is that near-surface faults generate detectable back-scattered surface waves from impinging surface waves. The processing steps

Sulfur cycling in contaminated aquifers: What can we learn from oxygen isotopes in sulfate? (Invited)

Science.gov (United States)

Knoeller, K.; Vogt, C.; Hoth, N.

2009-12-01

abandoned lignite mine. Due to the heterogeneous isotopic composition of the sulfate source (oxidation of sedimentary sulfide), sulfur isotopes alone are inappropriate for the recognition of BSR. Only the application of oxygen isotopes in sulfate provides clear evidence for the activity of sulfate reducing bacteria. However, the obtained small θ value indicates a significant influence of sulfide re-oxidation. In the second example we applied the dual isotope system to investigate the relevance of BSR for natural biodegradation in an aquifer contaminated with BTEX. Isotope fractionation parameters were determined in column experiments operated under near in situ conditions. The differences between field derived and experimental fractionation parameters revealed essential information on the occurrence of sulfur transformations competing with the actual biodegradation reactions. Most important of those processes is the re-oxidation of reduced sulfur species consuming electron acceptors that would be relevant for contaminant oxidation.

Surface and sub-surface thermal oxidation of thin ruthenium films

Energy Technology Data Exchange (ETDEWEB)

Coloma Ribera, R.; Kruijs, R. W. E. van de; Yakshin, A. E.; Bijkerk, F. [MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands); Kokke, S.; Zoethout, E. [FOM Dutch Institute for Fundamental Energy Research (DIFFER), P.O. Box 1207, 3430 BE Nieuwegein (Netherlands)

2014-09-29

A mixed 2D (film) and 3D (nano-column) growth of ruthenium oxide has been experimentally observed for thermally oxidized polycrystalline ruthenium thin films. Furthermore, in situ x-ray reflectivity upon annealing allowed the detection of 2D film growth as two separate layers consisting of low density and high density oxides. Nano-columns grow at the surface of the low density oxide layer, with the growth rate being limited by diffusion of ruthenium through the formed oxide film. Simultaneously, with the growth of the columns, sub-surface high density oxide continues to grow limited by diffusion of oxygen or ruthenium through the oxide film.

Hydrology of the Ferron sandstone aquifer and effects of proposed surface-coal mining in Castle Valley, Utah, with sections on stratigraphy and leaching of overburden

Science.gov (United States)

Lines, Gregory C.; Morrissey, Daniel J.; Ryer, Thomas A.; Fuller, Richard H.

1983-01-01

Coal in the Ferron Sandstone Member of the Mancos Shale of Cretaceous age has traditionally been mined by underground techniques in the Emery Coal Field in the southern end of Castle Valley in east-central Utah. However, approximately 99 million tons are recoverable by surface mining. Ground water in the Ferron is the sole source of supply for the town of Emery, but the aquifer is essentially untapped outside the Emery area.The Ferron Sandstone Member crops out along the eastern edge of Castle Valley and generally dips 2 ? to 10 ? to the northwest. Sandstones in the Ferron are enclosed between relatively impermeable shale in the Tununk and Blue Gate Members of the Mancos Shale. Along the outcrop, the Ferron ranges in thickness from about 80 feet in the northern part of Castle Valley to 850 feet in the southern part. The Ferron also generally thickens in the subsurface downdip from the outcrop. Records from wells and test holes indicate that the full thickness of the Ferron is saturated with water in most areas downdip from the outcrop area.Tests in the Emery area indicate that transmissivity of the Ferron sandstone aquifer ranges from about 200 to 700 feet squared per day where the Ferron is fully saturated. Aquifer transmissivity is greatest near the Paradise Valley-Joes Valley fault system where permeability has been increased by fracturing. Storage coefficient ranges from about 10 .6 to 10 -3 where the Ferron sandstone aquifer is confined and probably averages 5 x 10-2 where it is unconfined.

Bioremediation of a diesel fuel contaminated aquifer: simulation studies in laboratory aquifer columns

Science.gov (United States)

Hess, A.; Höhener, P.; Hunkeler, D.; Zeyer, J.

1996-08-01

The in situ bioremediation of aquifers contaminated with petroleum hydrocarbons is commonly based on the infiltration of groundwater supplemented with oxidants (e.g., O 2, NO 3-) and nutrients (e.g., NH 4+, PO 43-). These additions stimulate the microbial activity in the aquifer and several field studies describing the resulting processes have been published. However, due to the heterogeneity of the subsurface and due to the limited number of observation wells usually available, these field data do not offer a sufficient spatial and temporal resolution. In this study, flow-through columns of 47-cm length equipped with 17 sampling ports were filled with homogeneously contaminated aquifer material from a diesel fuel contaminated in situ bioremediation site. The columns were operated over 96 days at 12°C with artificial groundwater supplemented with O 2, NO 3- and PO 43-. Concentration profiles of O 2, NO 3-, NO 2-, dissolved inorganic and organic carbon (DIC and DOC, respectively), protein, microbial cells and total residual hydrocarbons were measured. Within the first 12 cm, corresponding to a mean groundwater residence time of < 3.6 h, a steep O 2 decrease from 4.6 to < 0.3 mg l -1, denitrification, a production of DIC and DOC, high microbial cell numbers and a high removal of hydrocarbons were observed. Within a distance of 24 to 40.5 cm from the infiltration, O 2 was below 0.1 mg l -1 and a denitrifying activity was found. In the presence and in the absence of O 2, n-alkanes were preferentially degraded compared to branched alkanes. The results demonstrate that: (1) infiltration of aerobic groundwater into columns filled with aquifer material contaminated with hydrocarbons leads to a rapid depletion of O 2; (2) O 2 and NO 3- can serve as oxidants for the mineralization of hydrocarbons; and (3) the modelling of redox processes in aquifers has to consider denitrifying activity in presence of O 2.

Hydrogeology and geochemistry of aquifers underlying the San Lorenzo and San Leandro areas of the East Bay Plain, Alameda County, California

Science.gov (United States)

Izbicki, John A.; Borchers, James W.; Leighton, David A.; Kulongoski, Justin T.; Fields, Latoya; Galloway, Devin L.; Michel, Robert L.

2003-01-01

The East Bay Plain, on the densely populated eastern shore of San Francisco Bay, contains an upper aquifer system to depths of 250 feet below land surface and an underlying lower aquifer system to depths of more than 650 feet. Injection and recovery of imported water has been proposed for deep aquifers at two sites within the lower aquifer system. Successful operation requires that the injected water be isolated from surface sources of poor-quality water during storage and recovery. Hydraulic, geochemical, and isotopic data were used to evaluate the isolation of deeper aquifers. Ground-water responses to tidal changes in the Bay suggest that thick clay layers present within these deposits effectively isolate the deeper aquifers in the northern part of the study area from overlying surficial deposits. These data also suggest that the areal extent of the shallow and deep aquifers beneath the Bay may be limited in the northern part of the study area. Despite its apparent hydraulic isolation, the lower aquifer system may be connected to the overlying upper aquifer system through the corroded and failed casings of abandoned wells. Water-level measurements in observation wells and downward flow measured in selected wells during nonpumped conditions suggest that water may flow through wells from the upper aquifer system into the lower aquifer system during nonpumped conditions. The chemistry of water from wells in the East Bay Plain ranges from fresh to saline; salinity is greater than seawater in shallow estuarine deposits near the Bay. Water from wells completed in the lower aquifer system has higher pH, higher sodium, chloride, and manganese concentrations, and lower calcium concentrations and alkalinity than does water from wells completed in the overlying upper aquifer system. Ground-water recharge temperatures derived from noble-gas data indicate that highly focused recharge processes from infiltration of winter streamflow and more diffuse recharge processes from

Tectonic overview map of Northern Switzerland and correlation of aquifer-seal pairs within the molasse basin

Energy Technology Data Exchange (ETDEWEB)

Naef, H.

2010-07-01

This short report for the Swiss Federal Office of Energy (SFOE) is one of a series of appendices dealing with the potential for geological sequestration of carbon dioxide in Switzerland. This report provides a graphical overview of the situation in Northern Switzerland and correlates aquifer-seal pairs within the molasse basin. The tectonic overview is based on published tectonic summary maps from Swisstopo and the Swiss National Cooperative for the Disposal of Radioactive Wastes (NAGRA). It shows the known large, near-surface structures that are relevant to CO{sub 2} sequestration. A second map shows the correlation of Aquifer-Seal pairs in the molasse basin, based on data from eight deep drillings, illustrating the lengths and thicknesses of the aquifer-seal formations evaluated for CO{sub 2} sequestration.

Analytical estimation show low depth-independent water loss due to vapor flux from deep aquifers

Science.gov (United States)

Selker, John S.

2017-06-01

Recent articles have provided estimates of evaporative flux from water tables in deserts that span 5 orders of magnitude. In this paper, we present an analytical calculation that indicates aquifer vapor flux to be limited to 0.01 mm/yr for sites where there is negligible recharge and the water table is well over 20 m below the surface. This value arises from the geothermal gradient, and therefore, is nearly independent of the actual depth of the aquifer. The value is in agreement with several numerical studies, but is 500 times lower than recently reported experimental values, and 100 times larger than an earlier analytical estimate.

Flow and sorption controls of groundwater arsenic in individual boreholes from bedrock aquifers in central Maine, USA

Science.gov (United States)

Yang, Qiang; Culbertson, Charles W.; Nielsen, Martha G.; Schalk, Charles W.; Johnson, Carole D.; Marvinney, Robert G.; Stute, Martin; Zheng, Yan

2014-01-01

To understand the hydrogeochemical processes regulating well water arsenic (As) evolution in fractured bedrock aquifers, three domestic wells with [As] up to 478 μg/L are investigated in central Maine. Geophysical logging reveals that fractures near the borehole bottom contribute 70-100% of flow. Borehole and fracture water samples from various depths show significant proportions of As (up to 69%) and Fe (93-99%) in particulates (>0.45 μm). These particulates and those settled after a 16-day batch experiment contain 560-13,000 g/kg of As and 14-35% weight/weight of Fe. As/Fe ratios (2.5-20 mmol/mol) and As partitioning ratios (adsorbed/dissolved [As], 20,000-100,000 L/kg) suggest that As is sorbed onto amorphous hydrous ferric oxides. Newly drilled cores also show enrichment of As (up to 1300 mg/kg) sorbed onto secondary iron minerals on the fracture surfaces. Pumping at high flow rates induces large decreases in particulate As and Fe, a moderate increase in dissolved [As] and As(III)/As ratio, while little change in major ion chemistry. The δD and δ18O are similar for the borehole and fracture waters, suggesting a same source of recharge from atmospheric precipitation. Results support a conceptual model invoking flow and sorption controls on groundwater [As] in fractured bedrock aquifers whereby oxygen infiltration promotes the oxidation of As-bearing sulfides at shallower depths in the oxic portion of the flow path releasing As and Fe; followed by Fe oxidation to form Fe oxyhydroxide particulates, which are transported in fractures and sorb As along the flow path until intercepted by boreholes. In the anoxic portions of the flow path, reductive dissolution of As-sorbed iron particulates could re-mobilize As. For exposure assessment, we recommend sampling of groundwater without filtration to obtain total As concentration in groundwater.

Imaging near-surface heterogeneities by natural migration of surface waves

KAUST Repository

Liu, Zhaolun; AlTheyab, Abdullah; Hanafy, Sherif M.; Schuster, Gerard T.

2016-01-01

We demonstrate that near-surface heterogeneities can be imaged by natural migration of backscattered surface waves in common shot gathers. No velocity model is required because the data are migrated onto surface points with the virtual Green

Oxide surfaces and metal/oxide interfaces studied by grazing incidence X-ray scattering

Science.gov (United States)

Renaud, Gilles

Experimental determinations of the atomic structure of insulating oxide surfaces and metal/oxide interfaces are scarce, because surface science techniques are often limited by the insulating character of the substrate. Grazing incidence X-ray scattering (GIXS), which is not subject to charge effects, can provide very precise information on the atomic structure of oxide surfaces: roughness, relaxation and reconstruction. It is also well adapted to analyze the atomic structure, the registry, the misfit relaxation, elastic or plastic, the growth mode and the morphology of metal/oxide interfaces during their growth, performed in situ. GIXS also allows the analysis of thin films and buried interfaces, in a non-destructive way, yielding the epitaxial relationships, and, by variation of the grazing incidence angle, the lattice parameter relaxation along the growth direction. On semi-coherent interfaces, the existence of an ordered network of interfacial misfit dislocations can be demonstrated, its Burger's vector determined, its ordering during in situ annealing cycles followed, and sometimes even its atomic structure can be addressed. Careful analysis during growth allows the modeling of the dislocation nucleation process. This review emphasizes the new information that GIXS can bring to oxide surfaces and metal/oxide interfaces by comparison with other surface science techniques. The principles of X-ray diffraction by surfaces and interfaces are recalled, together with the advantages and properties of grazing angles. The specific experimental requirements are discussed. Recent results are presented on the determination of the atomic structure of relaxed or reconstructed oxide surfaces. A description of results obtained during the in situ growth of metal on oxide surfaces is also given, as well as investigations of thick metal films on oxide surfaces, with lattice parameter misfit relaxed by an array of dislocations. Recent work performed on oxide thin films having

Geochemistry of aquifer sediments and arsenic-rich groundwaters from Kandal Province, Cambodia

International Nuclear Information System (INIS)

Rowland, Helen A.L.; Gault, Andrew G.; Lythgoe, Paul; Polya, David A.

2008-01-01

Elevated As is well known to be present in aquifers utilised for drinking water and irrigation in West Bengal and Bangladesh. This problem has also more recently been discovered in other parts of Asia, including Vietnam, Cambodia, Inner Mongolia and the Middle Ganges Plain. Analysis of groundwaters in Kandal Province of Cambodia found waters with comparable geochemistry to the As-rich groundwaters of the West Bengali Delta. Similarities included high but heterogeneous As distributions, predominantly in the form As(III), high Fe, moderate to high HCO 3 - , circumneutral pH, low SO 4 2- and geochemical components indicative of reducing conditions. Good positive correlations between As, Fe, HCO 3 - and NH 4 + , and dissolved organic C is consistent with As release predominantly via microbially mediated reductive dissolution of As bearing Fe(III) oxides. Further evidence for such a process is found from correlations between As, Fe and organic matter from analysis of aquifer sediments, by the presence of goethite in the finer fractions and from the association of As with amorphous, poorly crystalline and well crystallised hydrous Fe oxides. The presence of several high As, but low Fe, wells implies that microbes could have a more direct role in mediating As release via the direct utilisation of Fe(III) or As(V) as electron acceptors. The presence of elevated As in waters with short aquifer residence times (as indicated by their geochemical signature) highlights the possible vulnerability of these aquifers to the influx of surface derived waters, providing an additional source of labile organic C that could exacerbate As release by stimulating microbial activity

Modelling free surface aquifers to analyze the interaction between groundwater and sinuous streams

DEFF Research Database (Denmark)

Balbarini, Nicola; Boon, W. M.; Bjerg, Poul Løgstrup

and errors. In addition, when streams are sinuous, groundwater flow is truly 3-dimensional, with strong vertical flows and sharp changes in horizontal direction. Here 3 different approaches to simulating free surface aquifers are compared for simulating groundwater-stream interaction. The aim of the models......: a saturated-unsaturated flow model, moving mesh, and a new coordinate transformation. The saturated/unsaturated model couples the saturated groundwater flow equation with a solution of Richards equation. The moving mesh solves the saturated groundwater equation with a free surface and deformable numerical...... finite element mesh. Finally, the new coordinate transform method employs a coordinate transform so that the saturated groundwater flow equation is solved on a fixed finite element mesh with a stationary free surface. This paper describes in detail the new coordinate transform method. It employs...

Catalytic Activity and Stability of Oxides: The Role of Near-Surface Atomic Structures and Compositions

KAUST Repository

Feng, Zhenxing; Hong, Wesley T.; Fong, Dillon D.; Lee, Yueh-Lin; Yacoby, Yizhak; Morgan, Dane; Shao-Horn, Yang

2016-01-01

electrochemical operating conditions give additional insights into cation migration. Direct COBRA and APXPS evidence for surface Sr segregation was found for La1–xSrxCoO3−δ and (La1–ySry)2CoO4±δ/La1–xSrxCoO3−δ oxide thin films, and the physical origin

Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts

DEFF Research Database (Denmark)

Verdaguer Casadevall, Arnau; Li, Christina W.; Johansson, Tobias Peter

2015-01-01

CO electroreduction activity on oxide-derived Cu (OD-Cu) was found to correlate with metastable surface features that bind CO strongly. OD-Cu electrodes prepared by H-2 reduction of Cu2O precursors reduce CO to acetate and ethanol with nearly 50% Faradaic efficiency at moderate overpotential. Tem...

Conceptual model to determine maximum activity of radioactive waste in near-surface disposal facilities

International Nuclear Information System (INIS)

Iarmosh, I.; Olkhovyk, Yu.

2016-01-01

For development of the management strategy for radioactive waste to be placed in near - surface disposal facilities (NSDF), it is necessary to justify long - term safety of such facilities. Use of mathematical modelling methods for long - term forecasts of radwaste radiation impact and assessment of radiation risks from radionuclides migration can help to resolve this issue. The purpose of the research was to develop the conceptual model for determining the maximum activity of radwaste to be safely disposed in the NSDF and to test it in the case of Lot 3 Vector NSDF (Chornobyl exclusion zone). This paper describes an approach to the development of such a model. The conceptual model of "9"0 Sr migration from Lot 3 through aeration zone and aquifer soils was developed. The results of modelling are shown. The proposals on further steps for the model improvement were developed

Oxidation of scandium thin films on tungsten surface

International Nuclear Information System (INIS)

Gorodetskij, D.A.; Martynyuk, A.V.

1988-01-01

Presence of Sc on the surface of W in amounts larger than a monolayer coverage leads to a decrease of the work function at the initial oxidation stage, which is attributed to oxygen implantation into the surface layer of the metal. A subsequent oxidation is followed by the formation on the surface of a thin oxide layer and an increase of the work function. An increase of the amount of Sc deposited on the surface before the oxidation decreases the work function of the obtained oxide from 5.8 (clean W surface) down to 3.3 eV (thick Sc layer on W)

Assessing the vulnerability of public-supply wells to contamination—Edwards aquifer near San Antonio, Texas

Science.gov (United States)

Jagucki, Martha L.; Musgrove, MaryLynn; Lindgren, Richard J.; Fahlquist, Lynne; Eberts, Sandra M.

2011-01-01

This fact sheet highlights findings from the vulnerability study of a public-supply well field in San Antonio, Texas. The well field consists of six production wells that tap the Edwards aquifer. Typically, one or two wells are pumped at a time, yielding an average total of 20-21 million gallons per day. Water samples were collected from public-supply wells in the well field and from monitoring wells installed along general directions of flow to the well field. Samples from the well field contained some constituents of concern for drinking-water quality, including nitrate; the pesticide compounds atrazine, deethylatrazine, and simazine; and the volatile organic compounds tetrachloroethene (also called perchloroethene, or PCE), chloroform, bromoform, and dibromochloromethane. These constituents were detected in untreated water at concentrations much less than established drinking-water standards, where such standards exist. Overall, the study findings point to four primary factors that affect the movement and fate of contaminants and the vulnerability of the public-supply well field in San Antonio, Texas: (1) groundwater age (how long ago water entered, or recharged, the aquifer), (2) fast pathways for flow of groundwater through features formed or enlarged by dissolution of bedrock, (3) recharge characteristics of the aquifer, and (4) natural geochemical processes within the aquifer. A computer-model simulation of groundwater flow and transport was used to estimate the traveltime (or age) of water particles entering public-supply well W4 in the well field. Modeled findings show that almost half of the water reaching the public-supply well is less than 2 years old. Such a large percentage of very young water indicates that (1) contaminants entering the aquifer may be transported rapidly to the well, (2) there is limited time for chemical reactions to occur in the aquifer that may attenuate contaminants, and (3) should recharge water become contaminated with

Straddle-packer aquifer test analyses of the Snake River Plain aquifer at the Idaho National Engineering Laboratory

International Nuclear Information System (INIS)

Johnson, G.S.; Frederick, D.B.

1997-01-01

The State of Idaho INEL Oversight Program, with the University of Idaho, Idaho State University, Boise State University, and the Idaho Geologic Survey, used a straddle-packer system to investigate vertical variations in characteristics of the Snake River Plain aquifer at the Idaho National Engineering Laboratory in southeast Idaho. Sixteen single-well aquifer tests were conducted on.isolated intervals in three observation wells. Each of these wells has approximately 200 feet of open borehole below the water table, penetrating the E through G and I basalt flow groups and interbedded sediments of the Snake River Plain aquifer. The success of the aquifer tests was limited by the inability to induce measurable drawdown in several zones. Time-drawdown data from aquifer tests were matched to type curves for 8 of the 16 zones tested. A single aquifer test at the water table exhibited greater curvature than those at depth. The increased degree of curvature suggests an unconfined response and resulted in an estimate of specific yield of 0.03. Aquifer tests below the water table generally yielded time-drawdown graphs with a rapid initial response followed by constant drawdown throughout the duration of the tests; up to several hours in length. The rapid initial response implies that the aquifer responds as a confined system during brief pumping periods. The nearly constant drawdown suggests a secondary source of water, probably vertical flow from overlying and underlying aquifer layers. Three analytical models were applied for comparison to the conceptual model and to provide estimates of aquifer properties. This, Hantush-Jacob leaky aquifer, and the Moench double-porosity fractured rock models were fit to time-drawdown data. The leaky aquifer type curves of Hantush and Jacob generally provided the best match to observed drawdown. A specific capacity regression equation was also used to estimate hydraulic conductivity

The effects of Fe-oxidizing microorganisms on post-biostimulation permeability reduction and oxidative processes at the Rifle IFRC site

Energy Technology Data Exchange (ETDEWEB)

Chan, Clara Sze-Yue [Univ. of Delaware, Newark, DE (United States)

2015-07-02

Fe oxidation and biomineral formation is important in aquifers because the highly-reactive oxides can control the mobility of nutrients (e.g. phosphate, C) and metals (e.g. arsenic, uranium). Mineral formation also has the potential to affect hydrology, depending on the volume and distribution in pore spaces. In this exploratory study, we sought to understand how microbial Fe-oxidizers and their biominerals affect, and are affected by groundwater flow. As part of work at the Rifle aquifer in Colorado, we initially hypothesized that Fe-oxidizers were contributing to aquifer clogging problems associated with enhanced bioremediation. To demonstrate the presence of Fe-oxidizers in the Rifle aquifer, we enriched FeOM from groundwater samples, and isolated two novel chemolithotrophic, microaerophilic Fe-oxidizing Betaproteobacteria, Hydrogenophaga sp. P101 and Curvibacter sp. CD03. To image cells and biominerals in the context of pores, we developed a “micro-aquifer,” a sand-filled flow-through culture chamber that allows for imaging of sediment pore space with multiphoton confocal microscopy. Fe oxide biofilms formed on sand grains, demonstrating that FeOM produce Fe oxide sand coatings. Fe coatings are common on aquifer sands, and tend to sequester contaminants; however, it has never previously been shown that microbes are responsible for their formation. In contrast to our original hypothesis, the biominerals did not clog the mini-aquifer. Instead, Fe biofilm distribution was dynamic: they grew as coatings, then periodically sloughed off sand grains, with some flocs later caught in pore throats. This has implications for physical hydrology, including pore scale architecture, and element transport. The sloughing of coatings likely prevents the biominerals from clogging wells and aquifers, at least initially. Although attached biomineral coatings sequester Fe-associated elements (e.g. P, As, C, U), when biominerals detach, these elements are transported as particles

Interaction of Aquifer and River-Canal Network near Well Field.

Science.gov (United States)

Ghosh, Narayan C; Mishra, Govinda C; Sandhu, Cornelius S S; Grischek, Thomas; Singh, Vikrant V

2015-01-01

The article presents semi-analytical mathematical models to asses (1) enhancements of seepage from a canal and (2) induced flow from a partially penetrating river in an unconfined aquifer consequent to groundwater withdrawal in a well field in the vicinity of the river and canal. The nonlinear exponential relation between seepage from a canal reach and hydraulic head in the aquifer beneath the canal reach is used for quantifying seepage from the canal reach. Hantush's (1967) basic solution for water table rise due to recharge from a rectangular spreading basin in absence of pumping well is used for generating unit pulse response function coefficients for water table rise in the aquifer. Duhamel's convolution theory and method of superposition are applied to obtain water table position due to pumping and recharge from different canal reaches. Hunt's (1999) basic solution for river depletion due to constant pumping from a well in the vicinity of a partially penetrating river is used to generate unit pulse response function coefficients. Applying convolution technique and superposition, treating the recharge from canal reaches as recharge through conceptual injection wells, river depletion consequent to variable pumping and recharge is quantified. The integrated model is applied to a case study in Haridwar (India). The well field consists of 22 pumping wells located in the vicinity of a perennial river and a canal network. The river bank filtrate portion consequent to pumping is quantified. © 2014, National GroundWater Association.

Ground-water flow directions and estimation of aquifer hydraulic properties in the lower Great Miami River Buried Valley aquifer system, Hamilton Area, Ohio

Science.gov (United States)

Sheets, Rodney A.; Bossenbroek, Karen E.

2005-01-01

The Great Miami River Buried Valley Aquifer System is one of the most productive sources of potable water in the Midwest, yielding as much as 3,000 gallons per minute to wells. Many water-supply wells tapping this aquifer system are purposely placed near rivers to take advantage of induced infiltration from the rivers. The City of Hamilton's North Well Field consists of 10 wells near the Great Miami River, all completed in the lower Great Miami River Buried Valley Aquifer System. A well-drilling program and a multiple-well aquifer test were done to investigate ground-water flow directions and to estimate aquifer hydraulic properties in the lower part of the Great Miami River Buried Valley Aquifer System. Descriptions of lithology from 10 well borings indicate varying amounts and thickness of clay or till, and therefore, varying levels of potential aquifer confinement. Borings also indicate that the aquifer properties can change dramatically over relatively short distances. Grain-size analyses indicate an average bulk hydraulic conductivity value of aquifer materials of 240 feet per day; the geometric mean of hydraulic conductivity values of aquifer material was 89 feet per day. Median grain sizes of aquifer material and clay units were 1.3 millimeters and 0.1 millimeters, respectively. Water levels in the Hamilton North Well Field are affected by stream stage in the Great Miami River and barometric pressure. Bank storage in response to stream stage is evident. Results from a multiple-well aquifer test at the well field indicate, as do the lithologic descriptions, that the aquifer is semiconfined in some areas and unconfined in others. Transmissivity and storage coefficient of the semiconfined part of the aquifer were 50,000 feet squared per day and 5x10-4, respectively. The average hydraulic conductivity (450 feet per day) based on the aquifer test is reasonable for glacial outwash but is higher than calculated from grain-size analyses, implying a scale effect

Evaluation of availability of water from drift aquifers near the Pomme de Terre and Chippewa rivers, western Minnesota

Science.gov (United States)

Delin, G.N.

1987-01-01

Ground-water flow in the confined- and unconfined-drift aquifers near Appleton and Benson, Minnesota, was simulated with a three-dimensional finite-difference ground-water-flow model. Model results indicate that 98 percent of the total inflow to the modeled area is from precipitation. Of the total outflow, 38 percent is ground-water discharge to the Pom me de Terre and Chippewa Rivers, 36 percent is evapotranspiration, 17 percent is ground-water pumpage, and 8 percent is ground-water discharge to the Minnesota River.

Insights on surface-water/groundwater exchange in the upper Floridan aquifer, north-central Florida (USA), from streamflow data and numerical modeling

Science.gov (United States)

Sutton, James E.; Screaton, Elizabeth J.; Martin, Jonathan B.

2015-03-01

Surface-water/groundwater exchange impacts water quality and budgets. In karst aquifers, these exchanges also play an important role in dissolution. Five years of river discharge data were analyzed and a transient groundwater flow model was developed to evaluate large-scale temporal and spatial variations of exchange between an 80-km stretch of the Suwannee River in north-central Florida (USA) and the karstic upper Floridan aquifer. The one-layer transient groundwater flow model was calibrated using groundwater levels from 59 monitoring wells, and fluxes were compared to the exchange calculated from discharge data. Both the numerical modeling and the discharge analysis suggest that the Suwannee River loses water under both low- and high-stage conditions. River losses appear greatest at the inside of a large meander, and the former river water may continue across the meander within the aquifer rather than return to the river. In addition, the numerical model calibration reveals that aquifer transmissivity is elevated within this large meander, which is consistent with enhanced dissolution due to river losses. The results show the importance of temporal and spatial variations in head gradients to exchange between streams and karst aquifers and dissolution of the aquifers.

How to Recharge a Confined Aquifer: An Exploration of Geologic Controls on Groundwater Storage.

Science.gov (United States)

Maples, S.; Fogg, G. E.; Maxwell, R. M.; Liu, Y.

2017-12-01

Decreased snowpack storage and groundwater overdraft in California has increased interest in managed aquifer recharge (MAR) of excess winter runoff to the Central Valley aquifer system, which has unused storage capacity that far exceeds the state's surface reservoirs. Recharge to the productive, confined aquifer system remains a challenge due to the presence of nearly-ubiquitous, multiple silt and clay confining units that limit recharge pathways. However, previous studies have identified interconnected networks of sand and gravel deposits that bypass the confining units and accommodate rapid, high-volume recharge to the confined aquifer system in select locations. We use the variably-saturated, fully-integrated groundwater/surface-water flow code, ParFlow, in combination with a high-resolution, transition probability Markov-chain geostatistical model of the subsurface geologic heterogeneity of the east side of the Sacramento Valley, CA, to characterize recharge potential across a landscape that includes these geologic features. Multiple 180-day MAR simulations show that recharge potential is highly dependent on subsurface geologic structure, with a several order-of-magnitude range of recharge rates and volumes across the landscape. Where there are recharge pathways to the productive confined-aquifer system, pressure propagation in the confined system is widespread and rapid, with multi-kilometer lateral pressure propagation. Although widespread pressure propagation occurs in the confined system, only a small fraction of recharge volume is accommodated there. Instead, the majority of recharge occurs by filling unsaturated pore spaces. Where they outcrop at land surface, high-K recharge pathways fill rapidly, accommodating the majority of recharge during early time. However, these features become saturated quickly, and somewhat counterintuitively, the low-K silt and clay facies accommodate the majority of recharge volume during most of the simulation. These findings

Estimating Aquifer Properties Using Sinusoidal Pumping Tests

Science.gov (United States)

Rasmussen, T. C.; Haborak, K. G.; Young, M. H.

2001-12-01

We develop the theoretical and applied framework for using sinusoidal pumping tests to estimate aquifer properties for confined, leaky, and partially penetrating conditions. The framework 1) derives analytical solutions for three boundary conditions suitable for many practical applications, 2) validates the analytical solutions against a finite element model, 3) establishes a protocol for conducting sinusoidal pumping tests, and 4) estimates aquifer hydraulic parameters based on the analytical solutions. The analytical solutions to sinusoidal stimuli in radial coordinates are derived for boundary value problems that are analogous to the Theis (1935) confined aquifer solution, the Hantush and Jacob (1955) leaky aquifer solution, and the Hantush (1964) partially penetrated confined aquifer solution. The analytical solutions compare favorably to a finite-element solution of a simulated flow domain, except in the region immediately adjacent to the pumping well where the implicit assumption of zero borehole radius is violated. The procedure is demonstrated in one unconfined and two confined aquifer units near the General Separations Area at the Savannah River Site, a federal nuclear facility located in South Carolina. Aquifer hydraulic parameters estimated using this framework provide independent confirmation of parameters obtained from conventional aquifer tests. The sinusoidal approach also resulted in the elimination of investigation-derived wastes.

Defects at oxide surfaces

CERN Document Server

Thornton, Geoff

2015-01-01

This book presents the basics and characterization of defects at oxide surfaces. It provides a state-of-the-art review of the field, containing information to the various types of surface defects, describes analytical methods to study defects, their chemical activity and the catalytic reactivity of oxides. Numerical simulations of defective structures complete the picture developed. Defects on planar surfaces form the focus of much of the book, although the investigation of powder samples also form an important part. The experimental study of planar surfaces opens the possibility of applying the large armoury of techniques that have been developed over the last half-century to study surfaces in ultra-high vacuum. This enables the acquisition of atomic level data under well-controlled conditions, providing a stringent test of theoretical methods. The latter can then be more reliably applied to systems such as nanoparticles for which accurate methods of characterization of structure and electronic properties ha...

Mechanism and Thermochemistry of Coal Char Oxidation and Desorption of Surface Oxides

DEFF Research Database (Denmark)

Levi, Gianluca; Causà, Mauro; Lacovig, Paolo

2017-01-01

The present study investigates the coal char combustion by a combination of thermochemical and X-ray photoemission spectroscopy (XPS) analyses. Thermoanalytical methods (differential thermogravimetry, differential scanning calorimetry, and temperature-programmed desorption) are used to identify...... the key reactive steps that occur upon oxidation and heating of coal char (chemisorption, structural rearrangement and switchover of surface oxides, and desorption) and their energetics. XPS is used to reveal the chemical nature of the surface oxides that populate the char surface and to monitor...... functionalities prevail. The rearrangement of epoxy during preoxidation goes together with activation of the more stable and less reactive carbon sites. Results are in good agreement with semi-lumped kinetic models of carbon oxidation, which include (1) formation of "metastable" surface oxides, (2) complex...

Interactions between deep bedrock aquifers and surface water in function of recharge and topography: a numerical study

Science.gov (United States)

Goderniaux, P.; Davy, P.; Le Borgne, T.; Bresciani, E.; Jimenez-Martinez, J.

2011-12-01

In crystalline rock regions, such as Brittany (France), important reserves of groundwater into deep fractured aquifers are increasingly used and provide high quality water compared to shallow aquifers which can be subject to agricultural contamination. However, recharge processes of these deep aquifers and interactions with surface water are not yet fully understood. In some areas, intensive pumping is carried out without guarantee of the resource quantity and quality. Understanding these processes is crucial for sustainable management of the resource. In this study, we study how deep groundwater fluxes, pathways, ages, and river-aquifer interactions vary according to recharge. We assume that water flowing from the ground surface is distributed between shallow more permeable layers and deep layers. This repartition mostly depends on recharge rates. With high recharge, groundwater levels are high and subsurface streamlines are relatively short between recharge areas and existing draining rivers, which constitutes a very dense network. Therefore, most of the groundwater fluxes occur through the more permeable shallow layers. With low recharge, groundwater levels are lower, and river and shallow permeable levels are partly disconnected from each other. This induces a general increase of the groundwater streamlines length from the recharge areas to more sporadic discharge areas, and more fluxes occur through the deep layers. Recharge conditions and river-aquifer interactions have changed over the last thousands of years, due to change in precipitation, temperatures, existence of permafrost, etc. They have strongly influenced deep groundwater fluxes and can explain current groundwater age and flux distribution. To study these interactions, a regional-scale finite difference flow model was implemented. The model covers an area of 1400 km 2 , a depth of 1 km, and the topography is characteristic of Brittany. As rivers are mainly fed by groundwater drainage, seepages faces

Flow and sorption controls of groundwater arsenic in individual boreholes from bedrock aquifers in central Maine, USA

Energy Technology Data Exchange (ETDEWEB)

Yang, Qiang [Lamont-Doherty Earth Observatory of Columbia University, 61 Route 9 W, Palisades, NY 10964 (United States); School of Earth and Environmental Sciences, Queens College and Graduate Center, City University of New York, 65-30 Kissena Blvd., Flushing, NY 11367 (United States); Culbertson, Charles W.; Nielsen, Martha G.; Schalk, Charles W. [U.S. Geological Survey, Maine Water Science Center, 196 Whitten Road, Augusta, ME 04330 (United States); Johnson, Carole D. [U.S. Geological Survey, Branch of Geophysics, 11 Sherman Place, Unit 5015, University of Connecticut, Storrs, CT 06269 (United States); Marvinney, Robert G. [Maine Geological Survey, 93 State House Station, Augusta, ME 04333 (United States); Stute, Martin [Lamont-Doherty Earth Observatory of Columbia University, 61 Route 9 W, Palisades, NY 10964 (United States); Zheng, Yan, E-mail: yan.zheng@qc.cuny.edu [Lamont-Doherty Earth Observatory of Columbia University, 61 Route 9 W, Palisades, NY 10964 (United States); School of Earth and Environmental Sciences, Queens College and Graduate Center, City University of New York, 65-30 Kissena Blvd., Flushing, NY 11367 (United States)

2015-02-01

To understand the hydrogeochemical processes regulating well water arsenic (As) evolution in fractured bedrock aquifers, three domestic wells with [As] up to 478 μg/L are investigated in central Maine. Geophysical logging reveals that fractures near the borehole bottom contribute 70–100% of flow. Borehole and fracture water samples from various depths show significant proportions of As (up to 69%) and Fe (93–99%) in particulates (> 0.45 μm). These particulates and those settled after a 16-day batch experiment contain 560–13,000 mg/kg of As and 14–35% weight/weight of Fe. As/Fe ratios (2.5–20 mmol/mol) and As partitioning ratios (adsorbed/dissolved [As], 20,000–100,000 L/kg) suggest that As is sorbed onto amorphous hydrous ferric oxides. Newly drilled cores also show enrichment of As (up to 1300 mg/kg) sorbed onto secondary iron minerals on the fracture surfaces. Pumping at high flow rates induces large decreases in particulate As and Fe, a moderate increase in dissolved [As] and As(III)/As ratio, while little change in major ion chemistry. The δD and δ{sup 18}O are similar for the borehole and fracture waters, suggesting a same source of recharge from atmospheric precipitation. Results support a conceptual model invoking flow and sorption controls on groundwater [As] in fractured bedrock aquifers whereby oxygen infiltration promotes the oxidation of As-bearing sulfides at shallower depths in the oxic portion of the flow path releasing As and Fe; followed by Fe oxidation to form Fe oxyhydroxide particulates, which are transported in fractures and sorb As along the flow path until intercepted by boreholes. In the anoxic portions of the flow path, reductive dissolution of As-sorbed iron particulates could re-mobilize As. For exposure assessment, we recommend sampling of groundwater without filtration to obtain total As concentration in groundwater. - Highlights: • Most Fe and some As exist as particulates in the tested borehole and fracture water. �

Effect of Ge surface termination on oxidation behavior

Science.gov (United States)

Lee, Younghwan; Park, Kibyung; Cho, Yong Soo; Lim, Sangwoo

2008-09-01

Sulfur-termination was formed on the Ge(1 0 0) surface using (NH 4) 2S solution. Formation of Ge-S and the oxidation of the S-terminated Ge surface were monitored with multiple internal reflection Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. In the 0.5, 5, or 20% (NH 4) 2S solution, H-termination on the Ge(1 0 0) surface was substituted with S-termination in 1 min. When the S-terminated Ge(1 0 0) surface was exposed in air ambient, the oxidation was retarded for about 3600 min. The preservation time of the oxide layer up to one monolayer of S-terminated Ge(1 0 0) surface was about 120 times longer than for the H-terminated Ge(1 0 0) surface. However, the oxidation of S-terminated Ge(1 0 0) surface drastically increased after the threshold time. There was no significant difference in threshold time between S-terminations formed in 0.5, 5, and 20% (NH 4) 2S solutions. With the surface oxidation, desorption of S on the Ge surface was observed. The desorption behavior of sulfur on the S-terminated Ge(1 0 0) surface was independent of the concentration of the (NH 4) 2S solution that forms S-termination. Non-ideal S-termination on Ge surfaces may be related to drastic oxidation of the Ge surface. Finally, with the desulfurization on the S-terminated Ge(1 0 0) surface, oxide growth is accelerated.

Clay Mineralogy of AN Alluvial Aquifer in a Mountainous, Semiarid Terrain, AN Example from Rifle, Colorado

Science.gov (United States)

Elliott, W. C.; Lim, D.; Zaunbrecher, L. K.; Pickering, R. A.; Williams, K. H.; Navarre-Sitchler, A.; Long, P. E.; Noel, V.; Bargar, J.; Qafoku, N. P.

2015-12-01

Alluvial sediments deposited along the Colorado River corridor in the semi-arid regions of central to western Colorado can be important hosts for legacy contamination including U, V, As and Se. These alluvial sediments host aquifers which are thought to provide important "hot spots" and "hot moments" for microbiological activity controlling organic carbon processing and fluxes in the subsurface. Relatively little is known about the clay mineralogy of these alluvial aquifers and the parent alluvial sediments in spite of the fact that they commonly include lenses of silt-clay materials. These lenses are typically more reduced than coarser grained materials, but zones of reduced and more oxidized materials are present in these alluvial aquifer sediments. The clay mineralogy of the non-reduced parent alluvial sediments of the alluvial aquifer located in Rifle, CO (USA) is composed of chlorite, smectite, illite, kaolinite and quartz. The clay mineralogy of non-reduced fine-grained materials at Rifle are composed of the same suite of minerals found in the sediments plus a vermiculite-smectite intergrade that occurs near the bottom of the aquifer near the top of the Wasatch Formation. The clay mineral assemblages of the system reflect the mineralogically immature character of the source sediments. These assemblages are consistent with sediments and soils that formed in a moderately low rainfall climate and suggestive of minimal transport of the alluvial sediments from their source areas. Chlorite, smectite, smectite-vermiculite intergrade, and illite are the likely phases involved in the sorption of organic carbon and related microbial redox transformations of metals in these sediments. Both the occurrence and abundance of chlorite, smectite-vermiculite, illite and smectite can therefore exert an important control on the contaminant fluxes and are important determinants of biogeofacies in mountainous, semiarid terrains.

Atomic profile imaging of ceramic oxide surfaces

International Nuclear Information System (INIS)

Bursill, L.A.; Peng JuLin; Sellar, J.R.

1989-01-01

Atomic surface profile imaging is an electron optical technique capable of revealing directly the surface crystallography of ceramic oxides. Use of an image-intensifier with a TV camera allows fluctuations in surface morphology and surface reactivity to be recorded and analyzed using digitized image data. This paper reviews aspects of the electron optical techniques, including interpretations based upon computer-simulation image-matching techniques. An extensive range of applications is then presented for ceramic oxides of commercial interest for advanced materials applications: including uranium oxide (UO 2 ); magnesium and nickel oxide (MgO,NiO); ceramic superconductor YBa 2 Cu 3 O 6.7 ); barium titanate (BaTiO 3 ); sapphire (α-A1 2 O 3 ); haematite (α-Fe-2O 3 ); monoclinic, tetragonal and cubic monocrystalline forms of zirconia (ZrO 2 ), lead zirconium titanate (PZT + 6 mol.% NiNbO 3 ) and ZBLAN fluoride glass. Atomic scale detail has been obtained of local structures such as steps associated with vicinal surfaces, facetting parallel to stable low energy crystallographic planes, monolayer formation on certain facets, relaxation and reconstructions, oriented overgrowth of lower oxides, chemical decomposition of complex oxides into component oxides, as well as amorphous coatings. This remarkable variety of observed surface stabilization mechanisms is discussed in terms of novel double-layer electrostatic depolarization mechanisms, as well as classical concepts of the physics and chemistry of surfaces (ionization and affinity energies and work function). 46 refs., 16 figs

Monitoring Aquifer Depletion from Space: Case Studies from the Saharan and Arabian Aquifers

Science.gov (United States)

Ahmed, M.; Sultan, M.; Wahr, J. M.; Yan, E.

2013-12-01

absence across the remaining segments of the NSAS and the APAS suggest the aquifers are at near-steady conditions except for the DAS and SAS that are witnessing unsteady transient conditions. Implications for applying the methodologies advocated for assessment and optimum management of a large suite of fossil aquifers worldwide are clear.

Surface strontium enrichment on highly active perovskites for oxygen electrocatalysis in solid oxide fuel cells

KAUST Repository

Crumlin, Ethan J.; Mutoro, Eva; Liu, Zhi; Grass, Michael E.; Biegalski, Michael D.; Lee, Yueh-Lin; Morgan, Dane; Christen, Hans M.; Bluhm, Hendrik; Shao-Horn, Yang

2012-01-01

Perovskite oxides have high catalytic activities for oxygen electrocatalysis competitive to platinum at elevated temperatures. However, little is known about the oxide surface chemistry that influences the activity near ambient oxygen partial pressures, which hampers the design of highly active catalysts for many clean-energy technologies such as solid oxide fuel cells. Using in situ synchrotron-based, ambient pressure X-ray photoelectron spectroscopy to study the surface chemistry changes, we show that the coverage of surface secondary phases on a (001)-oriented La 0.8Sr 0.2CoO 3-δ (LSC) film becomes smaller than that on an LSC powder pellet at elevated temperatures. In addition, strontium (Sr) in the perovskite structure enriches towards the film surface in contrast to the pellet having no detectable changes with increasing temperature. We propose that the ability to reduce surface secondary phases and develop Sr-enriched perovskite surfaces of the LSC film contributes to its enhanced activity for O 2 electrocatalysis relative to LSC powder-based electrodes. © 2012 The Royal Society of Chemistry.

Water-table and potentiometric-surface altitudes in the upper glacial, Magothy, and Lloyd aquifers of Long Island, New York, April–May 2016

Science.gov (United States)

Como, Michael D.; Finkelstein, Jason S.; Rivera, Simonette L.; Monti, Jack; Busciolano, Ronald J.

2018-06-06

The U.S. Geological Survey, in cooperation with State and local agencies, systematically collects groundwater data at varying measurement frequencies to monitor the hydrologic conditions on Long Island, New York. Each year during April and May, the U.S. Geological Survey completes a synoptic survey of water levels to define the spatial distribution of the water table and potentiometric surfaces within the three main water-bearing units underlying Long Island—the upper glacial, Magothy, and Lloyd aquifers—and the hydraulically connected Jameco and North Shore aquifers. These data and the maps constructed from them are commonly used in studies of the hydrology of Long Island and are used by water managers and suppliers for aquifer management and planning purposes.Water-level measurements made in 424 monitoring wells (observation and supply wells), 13 streamgages, and 2 lake gages across Long Island during April–May 2016 were used to prepare the maps in this report. Groundwater measurements were made by the wetted-tape or electric-tape method to the nearest hundredth of a foot. Contours of water-table and potentiometric-surface altitudes were created using the groundwater measurements. The water-table contours were interpreted using water-level data collected from 275 observation wells and 1 supply well screened in the upper glacial aquifer and the shallow Magothy aquifer and 13 streamgages and 2 lake gages. The potentiometric-surface contours of the Magothy aquifer were interpreted from measurements at 88 wells (61 observation wells and 27 supply wells) screened in the middle to deep Magothy aquifer and the contiguous and hydraulically connected Jameco aquifer. The potentiometric-surface contours of the Lloyd aquifer were interpreted from measurements at 60 wells (55 observation wells and 5 supply wells) screened in the Lloyd aquifer and the contiguous and hydraulically connected North Shore aquifer. Many of the supply wells are in continuous operation and

Safety indicators used to prove the role of natural barrier for Saligny near surface disposal system

International Nuclear Information System (INIS)

Niculae, Ortenzia; Durdun, I.; Ionita, Gh.

2007-01-01

Full text: The siting process for a near surface repository suitable for the radioactive waste resulted from Cernavoda NPP operation and decommissioning (low level radioactive waste with small amounts of long lived radionuclides) started in 1992 and it included the collection of data from specific field and laboratory works for each site selection stage as well as different safety performance evaluation. According to the IAEA standards (Safety Guide No.111-G-3.1, 1994), the purpose of the siting process is not to get the best solution but to find out 'an acceptable solution, with sufficient safety reserves'. Since 1996, detailed field and investigation works were performed in Saligny preferred site including an experimental area to test the improvement method proposed for the foundation ground of repository, as well as detailed performance assessments using specific computer codes. The paper presents the results of recent performance assessments for the natural barrier of disposal system. The calculations were done using HYDRUS 2D, FEHM and AMBER computer codes. The endpoint of the Safety Report for Siting a Near Surface Repository at Saligny Site [CITON and SCN, Safety Report for Siting a Near Surface Repository at Saligny Site, 2007, pages 8.2.1-1 to 8.2.1-22 and 8-63 to 8-70] was the assessment of safety indicators. Individual annual effective dose for exposed peoples (both workers and general public) was the main safety indicator. In the same document, the radionuclide concentration in the disposal system compartments has been evaluated, as supplementary safety indicator of repository barriers (especially to confirm the natural barrier performance). The results confirmed the performance of natural barrier: the maximum extension of H-3 and Co-60 contaminant plume after repository closure remains more above underground water level. In the aquifer, iodine concentration reaches a value of 10 -15 mol/l, at the same magnitude order with the admitted limit from CFR

Mobilization of arsenic and other naturally occurring contaminants in groundwater of the Main Ethiopian Rift aquifers.

Science.gov (United States)

Rango, Tewodros; Vengosh, Avner; Dwyer, Gary; Bianchini, Gianluca

2013-10-01

This study investigates the mechanisms of arsenic (As) and other naturally occurring contaminants (F(-), U, V, B, and Mo) mobilization from Quaternary sedimentary aquifers of the Main Ethiopian Rift (MER) and their enrichment in the local groundwater. The study is based on systematic measurements of major and trace elements as well as stable oxygen and hydrogen isotopes in groundwater, coupled with geochemical and mineralogical analyses of the aquifer rocks. The Rift Valley aquifer is composed of rhyolitic volcanics and Quaternary lacustrine sediments. X-ray fluorescence (XRF) results revealed that MER rhyolites (ash, tuff, pumice and ignimbrite) and sediments contain on average 72 wt. % and 65 wt. % SiO2, respectively. Petrographic studies of the rhyolites indicate predominance of volcanic glass, sanidine, pyroxene, Fe-oxides and plagioclase. The As content in the lacustrine sediments (mean = 6.6 mg/kg) was higher than that of the rhyolites (mean: 2.5 mg/kg). The lacustrine aquifers of the Ziway-Shala basin in the northern part of MER were identified as high As risk zones, where mean As concentration in groundwater was 22.4 ± 33.5 (range of 0.60-190 μg/L) and 54% of samples had As above the WHO drinking water guideline value of 10 μg/L. Field As speciation measurements showed that most of the groundwater samples contain predominantly (~80%) arsenate-As(V) over arsenite-As(III) species. The As speciation together with field data of redox potential (mean Eh = +73 ± 65 mV) and dissolved-O2 (6.6 ± 2.2 mg/L) suggest that the aquifer is predominantly oxidative. Water-rock interactions, including the dissolution of volcanic glass produces groundwater with near-neutral to alkaline pH (range 6.9-8.9), predominance of Na-HCO3 ions, and high concentration of SiO2 (mean: 85.8 ± 11.3 mg/L). The groundwater data show high positive correlation of As with Na, HCO3, U, B, V, and Mo (R(2) > 0.5; p groundwater indicates that Fe-oxides and oxyhydroxides minerals were saturated

CO oxidation on PdO surfaces

DEFF Research Database (Denmark)

Hirvi, Janne T.; Kinnunen, Toni-Jani J.; Suvanto, Mika

2010-01-01

Density functional calculations were performed in order to investigate CO oxidation on two of the most stable bulk PdO surfaces. The most stable PdO(100) surface, with oxygen excess, is inert against CO adsorption, whereas strong adsorption on the stoichiometric PdO(101) surface leads to favorable...... oxidation via the Langmuir–Hinshelwood mechanism. The reaction with a surface oxygen atom has an activation energy of 0.66 eV, which is comparable to the lowest activation energies observed on metallic surfaces. However, the reaction rate may be limited by the coverage of molecular oxygen. Actually...... adsorption, following the Eley–Rideal mechanism and taking advantage of the reaction tunnel provided by the adjacent palladium atom, has an activation energy of only 0.24 eV. The reaction mechanism and activation energy for the palladium activated CO oxidation on the most stable PdO(100)–O surface...

Hydrogeology and water-quality characteristics of the Lower Floridan aquifer in east-central Florida

Science.gov (United States)

O'Reilly, Andrew M.; Spechler, Rick M.; McGurk, Brian E.

2002-01-01

surface of the Lower Floridan aquifer ranged from about 16 to 113 feet above sea level, and altitudes in May 1999 were about 2 to 7 feet lower than those measured in September 1998. The potentiometric surface of the Floridan aquifer system is constantly fluctuating, mainly in response to seasonal variations in rainfall and ground-water withdrawals. Seasonal fluctuations in the Lower Floridan aquifer typically range from about 2 to 10 feet. Water samples from 50 Lower Floridan aquifer wells were collected during this study. Most samples were analyzed in the field for temperature, pH, and specific conductance, and in the laboratory for major cations and anions. Specific conductance ranged from 147 to 6,710 microsiemens per centimeter. Chloride concentrations ranged from 3.0 to 2,188 milligrams per liter; sulfate concentrations ranged from 0.2 to 750 milli-grams per liter; and hardness ranged from 69 to 940 milligrams per liter. Water was least mineralized in the recharge areas of the Lower Floridan aquifer in the western part of the study area. The most mineralized water in the Lower Floridan aquifer occurred along parts of the Wekiva and St. Johns Rivers and in much of the eastern and southern parts of the study area. The altitude of the base of freshwater in the Floridan aquifer system (where chloride concentrations are equal to 250 milligrams per liter) is variable throughout the study area. The estimated position of the 250 milligram per liter isochlor surface is less than 200 feet below sea level in much of the eastern part of the study area, including the areas along the St. Johns River in Lake, Seminole, and Volusia Counties and near the Wekiva River in western Seminole County. The altitude of the 250 milligram per liter isochlor exceeds 3,000 feet below sea level in the extreme southwestern part of the study area.

Nominal Range Sensitivity Analysis of peak radionuclide concentrations in randomly heterogeneous aquifers

International Nuclear Information System (INIS)

Cadini, F.; De Sanctis, J.; Cherubini, A.; Zio, E.; Riva, M.; Guadagnini, A.

2012-01-01

Highlights: ► Uncertainty quantification problem associated with the radionuclide migration. ► Groundwater transport processes simulated within a randomly heterogeneous aquifer. ► Development of an automatic sensitivity analysis for flow and transport parameters. ► Proposal of a Nominal Range Sensitivity Analysis approach. ► Analysis applied to the performance assessment of a nuclear waste repository. - Abstract: We consider the problem of quantification of uncertainty associated with radionuclide transport processes within a randomly heterogeneous aquifer system in the context of performance assessment of a near-surface radioactive waste repository. Radionuclide migration is simulated at the repository scale through a Monte Carlo scheme. The saturated groundwater flow and transport equations are then solved at the aquifer scale for the assessment of the expected radionuclide peak concentration at a location of interest. A procedure is presented to perform the sensitivity analysis of this target environmental variable to key parameters that characterize flow and transport processes in the subsurface. The proposed procedure is exemplified through an application to a realistic case study.

Controls on Nitrous Oxide Production in, and Fluxes from a Coastal Aquifer in Long Island, NY, USA

Directory of Open Access Journals (Sweden)

Caitlin Young

2016-11-01

Full Text Available Nitrous oxide (N2O has 265 times greater greenhouse potential than carbon dioxide and its atmospheric concentration has increased by about 20% since industrialization; however, N2O production and emissions from aquatic systems are poorly constrained. To evaluate N2O fluxes associated with meteoric groundwater discharge to coastal zones, we measured N2O concentrations in May and October 2011 from two discharge points of the Upper Glacial aquifer on Long Island, NY, USA. One coastal zone contains only fresh water and the other contains an upper saline zone. N2O concentrations decreased by around 40% for the fresh water and a factor of two for the salt water from May to October, 2011. Fluxes were around 100 to 200 times greater from the freshwater (246 to 448 µmol/m shoreline/day than saltwater aquifer (26.1 to 26.5 µmol/m shoreline/day. N2O concentrations correlate positively with NO3− and dissolved oxygen concentrations and negatively with salinity, dissolved organic carbon (DOC and N2 denitrification concentrations. The smaller saltwater N2O export resulted from DOC enrichment in the upper saline zone, which appears to have driven denitrification to completion, removed N2O, and increased N2 denitrification. DOC concentrations should be considered in global N2O flux estimates for coastal aquifers.

Calculations of oxide formation on low-index Cu surfaces

Energy Technology Data Exchange (ETDEWEB)

Lian, Xin; Liu, Renlong, E-mail: lrl@cqu.edu.cn, E-mail: henkelman@utexas.edu [College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030 (China); Xiao, Penghao; Yang, Sheng-Che; Henkelman, Graeme, E-mail: lrl@cqu.edu.cn, E-mail: henkelman@utexas.edu [Department of Chemistry and the Institute for Computational and Engineering Sciences, University of Texas at Austin, Austin, Texas 78712-0165 (United States)

2016-07-28

Density-functional theory is used to evaluate the mechanism of copper surface oxidation. Reaction pathways of O{sub 2} dissociation on the surface and oxidation of the sub-surface are found on the Cu(100), Cu(110), and Cu(111) facets. At low oxygen coverage, all three surfaces dissociate O{sub 2} spontaneously. As oxygen accumulates on the surfaces, O{sub 2} dissociation becomes more difficult. A bottleneck to further oxidation occurs when the surfaces are saturated with oxygen. The barriers for O{sub 2} dissociation on the O-saturated Cu(100)-c(2×2)-0.5 monolayer (ML) and Cu(100) missing-row structures are 0.97 eV and 0.75 eV, respectively; significantly lower than those have been reported previously. Oxidation of Cu(110)-c(6×2), the most stable (110) surface oxide, has a barrier of 0.72 eV. As the reconstructions grow from step edges, clean Cu(110) surfaces can dissociatively adsorb oxygen until the surface Cu atoms are saturated. After slight rearrangements, these surface areas form a “1 ML” oxide structure which has not been reported in the literature. The barrier for further oxidation of this “1 ML” phase is only 0.31 eV. Finally the oxidized Cu(111) surface has a relatively low reaction energy barrier for O{sub 2} dissociation, even at high oxygen coverage, and allows for facile oxidation of the subsurface by fast O diffusion through the surface oxide. The kinetic mechanisms found provide a qualitative explanation of the observed oxidation of the low-index Cu surfaces.

Application of Near-Surface Remote Sensing and computer algorithms in evaluating impacts of agroecosystem management on Zea mays (corn) phenological development in the Platte River - High Plains Aquifer Long Term Agroecosystem Research Network field sites.

Science.gov (United States)

Okalebo, J. A.; Das Choudhury, S.; Awada, T.; Suyker, A.; LeBauer, D.; Newcomb, M.; Ward, R.

2017-12-01

The Long-term Agroecosystem Research (LTAR) network is a USDA-ARS effort that focuses on conducting research that addresses current and emerging issues in agriculture related to sustainability and profitability of agroecosystems in the face of climate change and population growth. There are 18 sites across the USA covering key agricultural production regions. In Nebraska, a partnership between the University of Nebraska - Lincoln and ARD/USDA resulted in the establishment of the Platte River - High Plains Aquifer LTAR site in 2014. The site conducts research to sustain multiple ecosystem services focusing specifically on Nebraska's main agronomic production agroecosystems that comprise of abundant corn, soybeans, managed grasslands and beef production. As part of the national LTAR network, PR-HPA participates and contributes near-surface remotely sensed imagery of corn, soybean and grassland canopy phenology to the PhenoCam Network through high-resolution digital cameras. This poster highlights the application, advantages and usefulness of near-surface remotely sensed imagery in agroecosystem studies and management. It demonstrates how both Infrared and Red-Green-Blue imagery may be applied to monitor phenological events as well as crop abiotic stresses. Computer-based algorithms and analytic techniques proved very instrumental in revealing crop phenological changes such as green-up and tasseling in corn. This poster also reports the suitability and applicability of corn-derived computer based algorithms for evaluating phenological development of sorghum since both crops have similarities in their phenology; with sorghum panicles being similar to corn tassels. This later assessment was carried out using a sorghum dataset obtained from the Transportation Energy Resources from Renewable Agriculture Phenotyping Reference Platform project, Maricopa Agricultural Center, Arizona.

Variable exchange between a stream and an aquifer in the Rio Grande Project Area

Science.gov (United States)

Sheng, Z.; Abudu, S.; Michelsen, A.; King, P.

2016-12-01

Both surface water and groundwater in the Rio Grande Project area in southern New Mexico and Far West Texas have been stressed by natural conditions such as droughts and human activities, including urban development and agricultural irrigation. In some area pumping stress in the aquifer becomes so great that it depletes the river flow especially during the irrigation season, typically from March through October. Therefore understanding such relationship between surface water and groundwater becomes more important in regional water resources planning and management. In this area, stream flows are highly regulated by the upstream reservoirs during the irrigation season and greatly influenced by return flows during non-irrigation season. During a drought additional groundwater pumping to supplement surface water shortage further complicates the surface water and groundwater interaction. In this paper the authors will use observation data and results of numerical models (MODFLOW) to characterize and quantify hydrological exchange fluxes between groundwater in the aquifers and surface water as well as impacts of groundwater pumping. The interaction shows a very interesting seasonal variation (irrigation vs. non-irrigation) as well as impact of a drought. Groundwater has been pumped for both municipal supplies and agricultural irrigation, which has imposed stresses toward both stream flows and aquifer storage. The results clearly show that historic groundwater pumping has caused some reaches of the river change from gaining stream to losing stream. Beyond the exchange between surface water and groundwater in the shallow aquifer, groundwater pumping in a deep aquifer could also enhance the exchanges between different aquifers through leaky confining layers. In the earlier history of pumping, pumping from the shallow aquifer is compensated by simple depletion of surface water, while deep aquifer tends to use the aquifer storage. With continued pumping, the cumulative

Changes in Chemical and Isotopic Composition of Groundwater During a Long Term Pumping Test in Brestovica Karst Aquifer

Energy Technology Data Exchange (ETDEWEB)

Mezga, K.; Urbanc, J. [Geological Survey of Slovenia, Department of Hydrogeology, Ljubljana (Slovenia)

2013-07-15

A pumping test of the Klarici water supply near Brestovica was performed in August 2008, in order to determine the karst groundwater resource capacity. Groundwater was pumped for a month with a total capacity of 470 L/s. During the experiment, sampling for chemical and isotopic composition of groundwater and surface water was carried out. Intensive pumping in dry meteorological conditions caused a lowering of the water table and changes in the chemical and isotopic composition of pumped water. Local meteoric waters are infiltrated into the aquifer at a lower mean altitude; therefore the {delta}{sup 18}O is enriched with the heavy oxygen isotope. The duration of pumping resulted in changes in the isotopic composition of oxygen due to a greater impact of the intergranular Soca River aquifer on the karst aquifer. On the basis of isotope composition it was possible to quantify the impact of the Soca River on the karst aquifer. (author)

Arsenic mobility in groundwater/surface water systems in carbonate-rich Pleistocene glacial drift aquifers (Michigan)

International Nuclear Information System (INIS)

Szramek, Kathryn; Walter, Lynn M.; McCall, Patti

2004-01-01

Within the Lower Peninsula of Michigan, groundwaters from the Marshall Formation (Mississippian) contain As derived from As-rich pyrites, often exceeding the World Heath Organization drinking water limit of 10 μg/L. Many Michigan watersheds, established on top of Pleistocene glacial drift derived from erosion of the underlying Marshall Formation, also have waters with elevated As. The Huron River watershed in southeastern Lower Michigan is a well characterized hydrogeochemical system of glacial drift deposits, proximate to the Marshall Fm. subcrop, which hosts carbonate-rich groundwaters, streams, and wetlands (fens), and well-developed soil profiles. Aqueous and solid phase geochemistry was determined for soils, soil waters, surface waters (streams and fens) and groundwaters from glacial drift aquifers to better understand the hydrogeologic and chemical controls on As mobility. Soil profiles established on the glacial drift exhibit enrichment in both Fe and As in the oxyhydroxide-rich zone of accumulation. The amounts of Fe and As present as oxyhydroxides are comparable to those reported from bulk Marshall Fm. core samples by previous workers. However, the As host in core samples is largely unaltered pyrite and arsenopyrite. This suggests that the transformation of Fe sulfides to Fe oxyhydroxides largely retains As and Fe at the oxidative weathering site. Groundwaters have the highest As values of all the waters sampled, and many were at or above the World Health limit. Most groundwaters are anaerobic, within the zones of Fe 3+ and As(V) reduction. Although reduction of Fe(III) oxyhydroxides is the probable source of As, there is no correlation between As and Fe concentrations. The As/Fe mole ratios in drift groundwaters are about an order of magnitude greater than those in soil profiles, suggesting that As is more mobile than Fe. This is consistent with the dominance of As(III) in these groundwaters and with the partitioning of Fe 2+ into carbonate cements. Soil

Effect of transient wave forcing on the behavior of arsenic in a sandy nearshore aquifer

Science.gov (United States)

Rakhimbekova, S.; O'Carroll, D. M.; Robinson, C. E.

2016-12-01

Waves cause large quantities of coastal water to recirculate across the groundwater-coastal water interface in addition to inducing complex groundwater flows in the nearshore aquifer. Due to the distinct chemical composition of recirculating coastal water compared with discharging terrestrial groundwater, wave-induced recirculations and flows can alter geochemical gradients in the nearshore aquifer which may subsequently affect the mobilization and transport of reactive pollutants (e.g., arsenic). The impact of seasonal geochemical and hydrological variability on the occurrence and mobility of arsenic near the groundwater-surface water interface has been shown previously in riverine settings, however, the impact of high frequency geochemical variations (e.g., varying wave conditions) on arsenic mobility in groundwater-surface water environments is unclear. The objective of the study was to assess the impact of intensified wave conditions on the behavior of arsenic in a nearshore aquifer to determine the factors regulating its mobility and transport to receiving coastal waters. Field investigations were conducted at a permeable beach on the Great Lakes during a period of intensified wave conditions (wave event). High spatial resolution pore water sampling captured the geochemical conditions in the nearshore aquifer prior to the wave event, immediately after the wave event and over a recovery period of 3 weeks following the wave event. Shifts in pH and redox potential (ORP) gradients in response to varying wave conditions caused shifts in the iron and arsenic distributions in the aquifer. Sediment analysis was combined with the pore water distributions to assess the release of sediment-bound arsenic in response to the varying wave conditions. Insight into the effect of transient forcing on arsenic mobility and transport in groundwater-surface water environments is important for evaluating the potential risks associated with this toxic metalloid. The findings of this

Oxidation behaviour of the near α-titanium alloy IMI 834

Indian Academy of Sciences (India)

Unknown

Oxidation behaviour of the near α-titanium alloy IMI 834 was investigated over a range of tem- peratures, from ... perties and adequate resistance against environmental degradation. ... the change of weight of the specimen. The oxidation data.

Localized sulfate-reducing zones in a coastal plain aquifer

Science.gov (United States)

Brown, C.J.; Coates, J.D.; Schoonen, M.A.A.

1999-01-01

High concentrations of dissolved iron in ground water of coastal plain or alluvial aquifers contribute to the biofouling of public supply wells for which treatment and remediation is costly. Many of these aquifers, however, contain zones in which microbial sulfate reduction and the associated precipitation of iron-sulfide minerals decreases iron mobility. The principal water-bearing aquifer (Magothy Aquifer of Cretaceous age) in Suffolk County, New York, contains localized sulfate-reducing zones in and near lignite deposits, which generally are associated with clay lenses. Microbial analyses of core samples amended with [14C]-acetate indicate that microbial sulfate reduction is the predominant terminal-electron-accepting process (TEAP) in poorly permeable, lignite-rich sediments at shallow depths and near the ground water divide. The sulfate-reducing zones are characterized by abundant lignite and iron-sulfide minerals, low concentrations of Fe(III) oxyhydroxides, and by proximity to clay lenses that contain pore water with relatively high concentrations of sulfate and dissolved organic carbon. The low permeability of these zones and, hence, the long residence time of ground water within them, permit the preservation and (or) allow the formation of iron-sulfide minerals, including pyrite and marcasite. Both sulfate-reducing bacteria (SRB) and iron-reducing bacteria (IRB) are present beneath and beyond the shallow sulfate-reducing zones. A unique Fe(III)-reducing organism, MD-612, was found in core sediments from a depth of 187 m near the southern shore of Long Island. The distribution of poorly permeable, lignite-rich, sulfate-reducing zones with decreased iron concentration is varied within the principal aquifer and accounts for the observed distribution of dissolved sulfate, iron, and iron sulfides in the aquifer. Locating such zones for the placement of production wells would be difficult, however, because these zones are of limited aerial extent.

Preliminary Analysis of the Role of Wetlands and Rivers in the Groundwater Discharge of the Guarani Aquifer System in NE Argentina

Energy Technology Data Exchange (ETDEWEB)

Vives, L., E-mail: lvives@faa.unicen.edu.ar [Instituto de Hidrologia de Llanuras, Universidad Nacional del Centro de la Provincia de Buenos Aires, Azul (Argentina); Rodriguez, L. [Centro de Estudios Hidroambientales, Facultad de Ingenieria y Ciencias Hidricas, Universidad Nacional del Litoral, Santa Fe (Argentina); Manzano, M. [Escuela de Ingenieria de Caminos y de Minas, Universidad Politecnica de Cartagena, Cartagena (Spain); Valladares, A. [Subsecretaria de Recursos Hidricos (Argentina); Aggarwal, P. K.; Araguas Araguas, L. [International Atomic Energy Angency, Vienna (Austria)

2013-07-15

The Guarani Aquifer System (GAS) is the largest aquifer in South America. Previous regional hydrochemical and isotopic studies suggested that discharge may occur at wetlands and reaches of the Parana and Uruguay Rivers. Preliminary findings of a project aimed at verifying the discharge hypothesis on the southern GAS region are presented. The hydrochemical- isotopic composition of 17 samples from surface and groundwater in that area were analysed. Some waters showed chemical facies and isotopic (stable isotope and carbon-14) signatures similar to the formerly identified as GAS+pre-GAS formations. Admixtures between modern and GAS+pre-GAS waters were found at depths between less than 100 m and 200 m. A 96 m deep well located near the Ibera lagoon showed chemical and isotopic composition indicating presence of GAS waters. The hydraulic gradient favours upward flow near the wetlands, but surface waters seem to originate from local recharge. Investigations continue, incorporating {sup 222}Rn and new sampling sites. (author)

Behaviour and fate of nine recycled water trace organics during managed aquifer recharge in an aerobic aquifer

Science.gov (United States)

Patterson, B. M.; Shackleton, M.; Furness, A. J.; Bekele, E.; Pearce, J.; Linge, K. L.; Busetti, F.; Spadek, T.; Toze, S.

2011-03-01

The fate of nine trace organic compounds was evaluated during a 12 month large-scale laboratory column experiment. The columns were packed with aquifer sediment and evaluated under natural aerobic and artificial anaerobic geochemical conditions, to assess the potential for natural attenuation of these compounds during aquifer passage associated with managed aquifer recharge (MAR). The nine trace organic compounds were bisphenol A (BPA), 17β-estradiol (E2), 17α-ethynylestradiol (EE2), N-nitrosodimethylamine (NDMA), N-nitrosomorpholine (NMOR), carbamazepine, oxazepam, iohexol and iodipamide. In the low organic carbon content Spearwood sediment, all trace organics were non-retarded with retardation coefficients between 1.0 and 1.2, indicating that these compounds would travel at near groundwater velocities within the aquifer. The natural aerobic geochemical conditions provided a suitable environment for the rapid degradation for BPA, E2, iohexol (half life NDMA and NMOR) did not degrade under either aerobic or anaerobic aquifer geochemical conditions (half life > 50 days). Field-based validation experiments with carbamazepine and oxazepam also showed no degradation. If persistent trace organics are present in recycled waters at concentrations in excess of their intended use, natural attenuation during aquifer passage alone may not result in extracted water meeting regulatory requirements. Additional pre treatment of the recycled water would therefore be required.

Behaviour and fate of nine recycled water trace organics during managed aquifer recharge in an aerobic aquifer.

Science.gov (United States)

Patterson, B M; Shackleton, M; Furness, A J; Bekele, E; Pearce, J; Linge, K L; Busetti, F; Spadek, T; Toze, S

2011-03-25

The fate of nine trace organic compounds was evaluated during a 12month large-scale laboratory column experiment. The columns were packed with aquifer sediment and evaluated under natural aerobic and artificial anaerobic geochemical conditions, to assess the potential for natural attenuation of these compounds during aquifer passage associated with managed aquifer recharge (MAR). The nine trace organic compounds were bisphenol A (BPA), 17β-estradiol (E2), 17α-ethynylestradiol (EE2), N-nitrosodimethylamine (NDMA), N-nitrosomorpholine (NMOR), carbamazepine, oxazepam, iohexol and iodipamide. In the low organic carbon content Spearwood sediment, all trace organics were non-retarded with retardation coefficients between 1.0 and 1.2, indicating that these compounds would travel at near groundwater velocities within the aquifer. The natural aerobic geochemical conditions provided a suitable environment for the rapid degradation for BPA, E2, iohexol (half life aquifer geochemical conditions (half life >50days). Field-based validation experiments with carbamazepine and oxazepam also showed no degradation. If persistent trace organics are present in recycled waters at concentrations in excess of their intended use, natural attenuation during aquifer passage alone may not result in extracted water meeting regulatory requirements. Additional pre treatment of the recycled water would therefore be required. Crown Copyright © 2010. Published by Elsevier B.V. All rights reserved.

Surface oxide formation during corona discharge treatment of AA 1050 aluminium surfaces

DEFF Research Database (Denmark)

Minzari, Daniel; Møller, Per; Kingshott, Peter

2008-01-01

process modifies aluminium AA 1050 surface, the oxide growth and resulting corrosion properties. The corona treatment is carried out in atmospheric air. Treated surfaces are characterized using XPS, SEM/EDS, and FIB-FESEM and results suggest that an oxide layer is grown, consisting of mixture of oxide...

contaminant migration in a sand aquifer near an inactive uranium tailings impoundment, Elliot Lake, Ontario

International Nuclear Information System (INIS)

Morin, K.A.; Cherry, J.A.

1982-01-01

An investigation of the movement of contaminated groundwater from inactive uranium tailings through a sand aquifer is being conducted at the Nordic Main tailings impoundment near Elliot Lake, Ontario. During 1979 and 1980, multilevel bundle-type piezometers were installed at several locations around the edge of the tailings impoundment. Chemical analysis of water samples from the bundle piezometers indicate that a major contaminant plume extends outward through a sand aquifer from the southeastern part of the Nordic Main impoundment dam. In the vincinity of the contaminant plume, the sand aquifer varies in thickness from about 9 to 15 m. The plume has two distinct segments, referred to as the inner core and the outer zone. The inner core, which has a pH of 4.3-5.0 and extends about 15 m from the foot of the tailings dam, contains several grams per litre of iron and sulfate, and tens of pCi/L of 226 Ra and 210 Pb. Water levels in piezometers within the inner core show that groundwater is moving horizontally, away from the tailings impoundment, with a velocity of up to several hundred metres per year. The outer zone, which extends a few hundred metres downgradient from the dam, is characterized by hundreds to thousands of milligrams per litre of iron and sulfate, less than 15pCi/L of 226 Ra, and a pH greater than 5.7. Comparison of 1979 and 1980 data shows that the front of the inner core is advancing a few metres per year, which is less than a few percent of the groundwater velocity. This retardation of movement of the inner core is caused by neutralization of the acidic water as a result of dissolution of calcium carbonate in the sand. With the rise in pH, precipitation of iron carbonate and possibly some iron hydroxide occurs and the contaminants of main concern such as 226 Ra, 210 Pb, and uranium are removed from solution by adsorption or coprecipitation

Restoration of Wadi Aquifers by Artificial Recharge with Treated Waste Water

KAUST Repository

Missimer, Thomas M.; Drewes, Jö rg E.; Amy, Gary L.; Maliva,, Robert G.; Keller, Stephanie

2012-01-01

, such as damage to sensitive nearshore marine environments and creation of high-salinity interior surface water areas. An investigation of the hydrogeology of wadi aquifers in Saudi Arabia revealed that these aquifers can be used to develop aquifer recharge

New methodology for aquifer influx status classification for single wells in a gas reservoir with aquifer support

Directory of Open Access Journals (Sweden)

Yong Li

2016-10-01

Full Text Available For gas reservoirs with strong bottom or edge aquifer support, the most important thing is avoiding aquifer breakthrough in a gas well. Water production in gas wells does not only result in processing problems in surface facilities, but it also explicitly reduces well productivity and reservoir recovery. There are a lot of studies on the prediction of water breakthrough time, but they are not completely practicable due to reservoir heterogeneity. This paper provides a new method together with three diagnostic curves to identify aquifer influx status for single gas wells; the aforementioned curves are based on well production and pressure data. The whole production period of a gas well can be classified into three periods based on the diagnostic curves: no aquifer influx period, early aquifer influx period, and middle-late aquifer influx period. This new method has been used for actual gas well analysis to accurately identify gas well aquifer influx status and the water breakthrough sequence of all wells in the same gas field. Additionally, the evaluation results are significantly beneficial for well production rate optimization and development of an effective gas field.

Erosion of surface and near surface disposal facilities

International Nuclear Information System (INIS)

1988-06-01

A literature search was undertaken to identify existing data and analytical procedures regarding the processes of gully erosion. The applicability of the available information to the problems of gully erosion potential at surface and near surface disposal sites is evaluated. It is concluded that the existing knowledge regarding gully erosion is insufficient to develop procedures to ensure the long-term stability of disposal sites. Recommendations for further research are presented. 46 refs

Identification of a Catalytically Highly Active Surface Phase for CO Oxidation over PtRh Nanoparticles under Operando Reaction Conditions

Science.gov (United States)

Hejral, U.; Franz, D.; Volkov, S.; Francoual, S.; Strempfer, J.; Stierle, A.

2018-03-01

Pt-Rh alloy nanoparticles on oxide supports are widely employed in heterogeneous catalysis with applications ranging from automotive exhaust control to energy conversion. To improve catalyst performance, an atomic-scale correlation of the nanoparticle surface structure with its catalytic activity under industrially relevant operando conditions is essential. Here, we present x-ray diffraction data sensitive to the nanoparticle surface structure combined with in situ mass spectrometry during near ambient pressure CO oxidation. We identify the formation of ultrathin surface oxides by detecting x-ray diffraction signals from particular nanoparticle facets and correlate their evolution with the sample's enhanced catalytic activity. Our approach opens the door for an in-depth characterization of well-defined, oxide-supported nanoparticle based catalysts under operando conditions with unprecedented atomic-scale resolution.

Recharge and Aquifer Response: Manukan Island’s Aquifer, Sabah, Malaysia

Directory of Open Access Journals (Sweden)

Sarva Mangala Praveena

2010-01-01

Full Text Available Manukan Island is a small island located in North-West of Sabah, Malaysia was used as a case study area for numerical modeling of an aquifer response to recharge and pumping rates. The results in this study present the variations of recharge into the aquifer under the prediction simulations. The recharge rate increases the water level as indicated by hydraulic heads. This shows that it can alter groundwater of Manukan Island which has been suffering from an overexploration in its unconfined the aquifer. The increase in recharge rate (from 600 mm/year to 750 mm/year increases the water level indicated by hydraulic heads. A reduction in pumping rate (from 0.072 m3/day to 0.058 m3/day not only increases the amount of water levels in aquifer but also reduces the supply hence a deficit in supply. The increase in hydraulic heads depends on the percentage reduction of pumping and recharges rates. The well water has 1978.3 mg/L chloride with current pumping (0.072 m3/day and recharge rates (600 mm/year. However, with an increased of recharge rate and current pumping rate it has decreased about 1.13%. In addition, reduction in pumping rate made the chloride concentration decreased about 2.8%. In general, a reduction in pumping with an increase in recharge rate leads to a decreased in chloride concentrations within the vicinity of cone of depression. Next, to further develop the numerical model, the model should focus on climate change variables such as consequences of climate change are increase in air temperature, increase in sea surface temperature, and more extreme weather conditions. These parameters are considered critical parameters for climate change impact modeling in aquifers. The behavior of the aquifer and its sustainable pumping rate can be done by applying a computer modeling component.

Status of Groundwater Levels and Storage Volume in the Equus Beds Aquifer Near Wichita, Kansas, January 2009

Science.gov (United States)

Hansen, Cristi V.

2009-01-01

Beginning in the 1940s, the Wichita well field was developed in the Equus Beds aquifer in southwestern Harvey County and northwestern Sedgwick County to supply water to the city of Wichita (Williams and Lohman, 1949). In addition to supplying drinking water to the largest city in Kansas, the other primary use of water from the Equus Beds aquifer is to irrigate crops in this agriculture-dominated part of south-central Kansas (Rich Eubank, Kansas Department of Agriculture, Division of Water Resources, oral commun., 2008). The decline of water levels in the aquifer were noted soon after the development of the Wichita well field began (Williams and Lohman, 1949). As water levels in the aquifer decline, the volume of water stored in the aquifer decreases and less water is available to supply future needs. For many years the U.S. Geological Survey (USGS), in cooperation with the city of Wichita, has monitored these changes in water levels and the resulting changes in storage volume in the Equus Beds aquifer as part of Wichita's effort to effectively manage this resource. In 2007, the city of Wichita began using Phase I of the Equus Beds Aquifer Storage and Recovery (ASR) project for large-scale artificial recharge of the Equus Beds aquifer. The ASR project uses water from the Little Arkansas River - either pumped from the river directly or from wells in the riverbank that obtain their water from the river by induced infiltration - as the source of artificial recharge to the Equus Beds aquifer (City of Wichita, 2009).

Sustainable Capture: Concepts for Managing Stream-Aquifer Systems.

Science.gov (United States)

Davids, Jeffrey C; Mehl, Steffen W

2015-01-01

Most surface water bodies (i.e., streams, lakes, etc.) are connected to the groundwater system to some degree so that changes to surface water bodies (either diversions or importations) can change flows in aquifer systems, and pumping from an aquifer can reduce discharge to, or induce additional recharge from streams, springs, and lakes. The timescales of these interactions are often very long (decades), making sustainable management of these systems difficult if relying only on observations of system responses. Instead, management scenarios are often analyzed based on numerical modeling. In this paper we propose a framework and metrics that can be used to relate the Theis concepts of capture to sustainable measures of stream-aquifer systems. We introduce four concepts: Sustainable Capture Fractions, Sustainable Capture Thresholds, Capture Efficiency, and Sustainable Groundwater Storage that can be used as the basis for developing metrics for sustainable management of stream-aquifer systems. We demonstrate their utility on a hypothetical stream-aquifer system where pumping captures both streamflow and discharge to phreatophytes at different amounts based on pumping location. In particular, Capture Efficiency (CE) can be easily understood by both scientists and non-scientist alike, and readily identifies vulnerabilities to sustainable stream-aquifer management when its value exceeds 100%. © 2014, National Ground Water Association.

Groundwaters of Florence (Italy): Trace element distribution and vulnerability of the aquifers

Energy Technology Data Exchange (ETDEWEB)

Bencini, A.; Ercolanelli, R.; Sbaragli, A. [Univ. of Florence (Italy)] [and others

1993-11-01

Geochemical and hydrogeological research has been carried out in Florence, to evaluate conductivity and main chemistry of groundwaters, the pattern of some possible pollutant chemical species (Fe, Mn, Cr, Cu, Pb, Zn, NO{sub 2}, NO{sub 3}), and the vulnerability of the aquifers. The plain is made up of Plio-Quaternary alluvial and lacustrine sediments for a maximum thickness of 600 m. Silts and clays, sometimes with lenses of sandy gravels, are dominant, while considerable deposits of sands, pebbles, and gravels occur along the course of the Arno river and its tributary streams, and represent the most important aquifer of the plain. Most waters show conductivity values around 1000-1200 {mu}S, and almost all of them have an alkaline-earth-bicarbonate chemical character. In western areas higher salt content of the groundwaters is evident. Heavy metal and NO{sub 2}, NO{sub 3} analyses point out that no important pollution phenomena affect the groundwaters; all mean values are below the maximum admissible concentration (MAC) for drinkable waters. Some anomalies of NO{sub 2}, NO{sub 3}, Fe, Mn, and Zn are present. The most plausible causes can be recognized in losses of the sewage system; use of nitrate compounds in agriculture; oxidation of well pipes. All the observations of Cr, Cu, and Pb are below the MAC; the median values of <3, 3.9, and 1.1 {mu}g/l, respectively, could be considered reference concentrations for groundwaters in calcareous lithotypes, under undisturbed natural conditions. Finally, a map of vulnerability shows that the areas near the Arno river are highly vulnerable, for the minimum thickness (or lacking) of sediments covering the aquifer. On the other hand, in the case of pollution, several factors not considered could significantly increase the self-purification capacity of the aquifer, such asdilution of groundwaters, bacteria oxidation of nitrogenous species, and sorption capacity of clay minerals and organic matter. 31 refs., 6 figs., 5 tabs.

Quality of groundwater in the Denver Basin aquifer system, Colorado, 2003-5

Science.gov (United States)

Musgrove, MaryLynn; Beck, Jennifer A.; Paschke, Suzanne; Bauch, Nancy J.; Mashburn, Shana L.

2014-01-01

Groundwater resources from alluvial and bedrock aquifers of the Denver Basin are critical for municipal, domestic, and agricultural uses in Colorado along the eastern front of the Rocky Mountains. Rapid and widespread urban development, primarily along the western boundary of the Denver Basin, has approximately doubled the population since about 1970, and much of the population depends on groundwater for water supply. As part of the National Water-Quality Assessment Program, the U.S. Geological Survey conducted groundwater-quality studies during 2003–5 in the Denver Basin aquifer system to characterize water quality of shallow groundwater at the water table and of the bedrock aquifers, which are important drinking-water resources. For the Denver Basin, water-quality constituents of concern for human health or because they might otherwise limit use of water include total dissolved solids, fluoride, sulfate, nitrate, iron, manganese, selenium, radon, uranium, arsenic, pesticides, and volatile organic compounds. For the water-table studies, two monitoring-well networks were installed and sampled beneath agricultural (31 wells) and urban (29 wells) land uses at or just below the water table in either alluvial material or near-surface bedrock. For the bedrock-aquifer studies, domestic- and municipal-supply wells completed in the bedrock aquifers were sampled. The bedrock aquifers, stratigraphically from youngest (shallowest) to oldest (deepest), are the Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers. The extensive dataset collected from wells completed in the bedrock aquifers (79 samples) provides the opportunity to evaluate factors and processes affecting water quality and to establish a baseline that can be used to characterize future changes in groundwater quality. Groundwater samples were analyzed for inorganic, organic, isotopic, and age-dating constituents and tracers. This report discusses spatial and statistical distributions of chemical constituents

Measurement of UO2 surface oxidation using grazing-incidence x-ray diffraction: Implications for nuclear forensics

Science.gov (United States)

Tracy, Cameron L.; Chen, Chien-Hung; Park, Sulgiye; Davisson, M. Lee; Ewing, Rodney C.

2018-04-01

Nuclear forensics involves determination of the origin and history of interdicted nuclear materials based on the detection of signatures associated with their production and trafficking. The surface oxidation undergone by UO2 when exposed to air is a potential signature of its atmospheric exposure during handling and transport. To assess the sensitivity of this oxidation to atmospheric parameters, surface sensitive grazing-incidence x-ray diffraction (GIXRD) measurements were performed on UO2 samples exposed to air of varying relative humidity (34%, 56%, and 95% RH) and temperature (room temperature, 50 °C, and 100 °C). Near-surface unit cell contraction was observed following exposure, indicating oxidation of the surface and accompanying reduction of the uranium cation ionic radii. The extent of unit cell contraction provides a measure of the extent of oxidation, allowing for comparison of the effects of various exposure conditions. No clear influence of relative humidity on the extent of oxidation was observed, with samples exhibiting similar degrees of unit cell contraction at all relative humidities investigated. In contrast, the thickness of the oxidized layers increased substantially with increasing temperature, such that differences on the order of 10 °C yielded readily observable crystallographic signatures of the exposure conditions.

Molecular characterization of organic matter mobilized from Bangladeshi aquifer sediment: tracking carbon compositional change during microbial utilization

Directory of Open Access Journals (Sweden)

L. E. Pracht

2018-03-01

Full Text Available Bioavailable organic carbon in aquifer recharge waters and sediments can fuel microbial reactions with implications for groundwater quality. A previous incubation experiment showed that sedimentary organic carbon (SOC mobilized off sandy sediment collected from an arsenic-contaminated and methanogenic aquifer in Bangladesh was bioavailable; it was transformed into methane. We used high-resolution mass spectrometry to molecularly characterize this mobilized SOC, reference its composition against dissolved organic carbon (DOC in surface recharge water, track compositional changes during incubation, and advance understanding of microbial processing of organic carbon in anaerobic environments. Organic carbon mobilized off aquifer sediment was more diverse, proportionately larger, more aromatic, and more oxidized than DOC in surface recharge. Mobilized SOC was predominately composed of terrestrially derived organic matter and had characteristics signifying that it evaded microbial processing within the aquifer. Approximately 50 % of identified compounds in mobilized SOC and in DOC from surface recharge water contained sulfur. During incubation, after mobilized SOC was converted into methane, new organosulfur compounds with high S-to-C ratios and a high nominal oxidation state of carbon (NOSC were detected. We reason that these detected compounds formed abiotically following microbial reduction of sulfate to sulfide, which could have occurred during incubation but was not directly measured or that they were microbially synthesized. Most notably, microbes transformed all carbon types during incubation, including those currently considered thermodynamically unviable for microbes to degrade in anaerobic conditions (i.e., those with a low NOSC. In anaerobic environments, energy yields from redox reactions are small and the amount of energy required to remove electrons from highly reduced carbon substrates during oxidation decreases the thermodynamic

Molecular characterization of organic matter mobilized from Bangladeshi aquifer sediment: tracking carbon compositional change during microbial utilization

Science.gov (United States)

Pracht, Lara E.; Tfaily, Malak M.; Ardissono, Robert J.; Neumann, Rebecca B.

2018-03-01

Bioavailable organic carbon in aquifer recharge waters and sediments can fuel microbial reactions with implications for groundwater quality. A previous incubation experiment showed that sedimentary organic carbon (SOC) mobilized off sandy sediment collected from an arsenic-contaminated and methanogenic aquifer in Bangladesh was bioavailable; it was transformed into methane. We used high-resolution mass spectrometry to molecularly characterize this mobilized SOC, reference its composition against dissolved organic carbon (DOC) in surface recharge water, track compositional changes during incubation, and advance understanding of microbial processing of organic carbon in anaerobic environments. Organic carbon mobilized off aquifer sediment was more diverse, proportionately larger, more aromatic, and more oxidized than DOC in surface recharge. Mobilized SOC was predominately composed of terrestrially derived organic matter and had characteristics signifying that it evaded microbial processing within the aquifer. Approximately 50 % of identified compounds in mobilized SOC and in DOC from surface recharge water contained sulfur. During incubation, after mobilized SOC was converted into methane, new organosulfur compounds with high S-to-C ratios and a high nominal oxidation state of carbon (NOSC) were detected. We reason that these detected compounds formed abiotically following microbial reduction of sulfate to sulfide, which could have occurred during incubation but was not directly measured or that they were microbially synthesized. Most notably, microbes transformed all carbon types during incubation, including those currently considered thermodynamically unviable for microbes to degrade in anaerobic conditions (i.e., those with a low NOSC). In anaerobic environments, energy yields from redox reactions are small and the amount of energy required to remove electrons from highly reduced carbon substrates during oxidation decreases the thermodynamic favorability of

Source, variability, and transformation of nitrate in a regional karst aquifer: Edwards aquifer, central Texas

Energy Technology Data Exchange (ETDEWEB)

Musgrove, M., E-mail: mmusgrov@usgs.gov [U.S. Geological Survey, 1505 Ferguson Lane, Austin, TX 78754 (United States); Opsahl, S.P. [U.S. Geological Survey, 5563 DeZavala, Ste. 290, San Antonio, TX 78249 (United States); Mahler, B.J. [U.S. Geological Survey, 1505 Ferguson Lane, Austin, TX 78754 (United States); Herrington, C. [City of Austin Watershed Protection Department, Austin, TX 78704 (United States); Sample, T.L. [U.S. Geological Survey, 19241 David Memorial Dr., Ste. 180, Conroe, TX 77385 (United States); Banta, J.R. [U.S. Geological Survey, 5563 DeZavala, Ste. 290, San Antonio, TX 78249 (United States)

2016-10-15

Many karst regions are undergoing rapid population growth and expansion of urban land accompanied by increases in wastewater generation and changing patterns of nitrate (NO{sub 3}{sup −}) loading to surface and groundwater. We investigate variability and sources of NO{sub 3}{sup −} in a regional karst aquifer system, the Edwards aquifer of central Texas. Samples from streams recharging the aquifer, groundwater wells, and springs were collected during 2008–12 from the Barton Springs and San Antonio segments of the Edwards aquifer and analyzed for nitrogen (N) species concentrations and NO{sub 3}{sup −} stable isotopes (δ{sup 15}N and δ{sup 18}O). These data were augmented by historical data collected from 1937 to 2007. NO{sub 3}{sup −} concentrations and discharge data indicate that short-term variability (days to months) in groundwater NO{sub 3}{sup −} concentrations in the Barton Springs segment is controlled by occurrence of individual storms and multi-annual wet-dry cycles, whereas the lack of short-term variability in groundwater in the San Antonio segment indicates the dominance of transport along regional flow paths. In both segments, longer-term increases (years to decades) in NO{sub 3}{sup −} concentrations cannot be attributed to hydrologic conditions; rather, isotopic ratios and land-use change indicate that septic systems and land application of treated wastewater might be the source of increased loading of NO{sub 3}{sup −}. These results highlight the vulnerability of karst aquifers to NO{sub 3}{sup −} contamination from urban wastewater. An analysis of N-species loading in recharge and discharge for the Barton Springs segment during 2008–10 indicates an overall mass balance in total N, but recharge contains higher concentrations of organic N and lower concentrations of NO{sub 3}{sup −} than does discharge, consistent with nitrification of organic N within the aquifer and consumption of dissolved oxygen. This study demonstrates

Source, variability, and transformation of nitrate in a regional karst aquifer: Edwards aquifer, central Texas

International Nuclear Information System (INIS)

Musgrove, M.; Opsahl, S.P.; Mahler, B.J.; Herrington, C.; Sample, T.L.; Banta, J.R.

2016-01-01

Many karst regions are undergoing rapid population growth and expansion of urban land accompanied by increases in wastewater generation and changing patterns of nitrate (NO 3 − ) loading to surface and groundwater. We investigate variability and sources of NO 3 − in a regional karst aquifer system, the Edwards aquifer of central Texas. Samples from streams recharging the aquifer, groundwater wells, and springs were collected during 2008–12 from the Barton Springs and San Antonio segments of the Edwards aquifer and analyzed for nitrogen (N) species concentrations and NO 3 − stable isotopes (δ 15 N and δ 18 O). These data were augmented by historical data collected from 1937 to 2007. NO 3 − concentrations and discharge data indicate that short-term variability (days to months) in groundwater NO 3 − concentrations in the Barton Springs segment is controlled by occurrence of individual storms and multi-annual wet-dry cycles, whereas the lack of short-term variability in groundwater in the San Antonio segment indicates the dominance of transport along regional flow paths. In both segments, longer-term increases (years to decades) in NO 3 − concentrations cannot be attributed to hydrologic conditions; rather, isotopic ratios and land-use change indicate that septic systems and land application of treated wastewater might be the source of increased loading of NO 3 − . These results highlight the vulnerability of karst aquifers to NO 3 − contamination from urban wastewater. An analysis of N-species loading in recharge and discharge for the Barton Springs segment during 2008–10 indicates an overall mass balance in total N, but recharge contains higher concentrations of organic N and lower concentrations of NO 3 − than does discharge, consistent with nitrification of organic N within the aquifer and consumption of dissolved oxygen. This study demonstrates that subaqueous nitrification of organic N in the aquifer, as opposed to in soils, might be a

Geochemistry of groundwater in the eastern Snake River Plain aquifer, Idaho National Laboratory and vicinity, eastern Idaho

Science.gov (United States)

Rattray, Gordon W.

2018-05-30

Nuclear research activities at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) in eastern Idaho produced radiochemical and chemical wastes that were discharged to the subsurface, resulting in detectable concentrations of some waste constituents in the eastern Snake River Plain (ESRP) aquifer. These waste constituents may pose risks to the water quality of the aquifer. In order to understand these risks to water quality the U.S. Geological Survey, in cooperation with the DOE, conducted a study of groundwater geochemistry to improve the understanding of hydrologic and chemical processes in the ESRP aquifer at and near the INL and to understand how these processes affect waste constituents in the aquifer.Geochemistry data were used to identify sources of recharge, mixing of water, and directions of groundwater flow in the ESRP aquifer at the INL. The geochemistry data were analyzed from 167 sample sites at and near the INL. The sites included 150 groundwater, 13 surface-water, and 4 geothermal-water sites. The data were collected between 1952 and 2012, although most data collected at the INL were collected from 1989 to 1996. Water samples were analyzed for all or most of the following: field parameters, dissolved gases, major ions, dissolved metals, isotope ratios, and environmental tracers.Sources of recharge identified at the INL were regional groundwater, groundwater from the Little Lost River (LLR) and Birch Creek (BC) valleys, groundwater from the Lost River Range, geothermal water, and surface water from the Big Lost River (BLR), LLR, and BC. Recharge from the BLR that may have occurred during the last glacial epoch, or paleorecharge, may be present at several wells in the southwestern part of the INL. Mixing of water at the INL primarily included mixing of surface water with groundwater from the tributary valleys and mixing of geothermal water with regional groundwater. Additionally, a zone of mixing between tributary valley water and

Controlling geological and hydrogeological processes in an arsenic contaminated aquifer on the Red River flood plain, Vietnam

International Nuclear Information System (INIS)

Larsen, Flemming; Nhan Quy Pham; Nhan Duc Dang; Postma, Dieke; Jessen, Soren; Viet Hung Pham; Nguyen, Thao Bach; Trieu, Huy Duc; Luu Thi Tran; Hoan Nguyen; Chambon, Julie; Hoan Van Nguyen; Dang Hoang Ha; Nguyen Thi Hue; Mai Thanh Duc; Refsgaard, Jens Christian

2008-01-01

Geological and hydrogeological processes controlling recharge and the mobilization of As were investigated in a shallow Holocene aquifer on the Red River flood plain near Hanoi, Vietnam. The geology was investigated using surface resistivity methods, geophysical borehole logging, drilling of boreholes and installation of more than 200 piezometers. Recharge processes and surface-groundwater interaction were studied using (i) time-series of hydraulic head distribution in surface water and aquifers, (ii) the stable isotope composition of waters and (iii) numerical groundwater modeling. The Red River and two of its distributaries run through the field site and control the groundwater flow pattern. For most of the year, there is a regional groundwater flow towards the Red River. During the monsoon the Red River water stage rises up to 6 m and stalls the regional groundwater flow. The two distributaries recharge the aquifer from perched water tables in the dry season, whilst in the flooding period surface water enters the aquifer through highly permeable bank sediments. The result is a dynamic groundwater flow pattern with rapid fluctuations in the groundwater table. A transient numerical model of the groundwater flow yields an average recharge rate of 60-100 mm/a through the confining clay, and a total recharge of approximately 200 mm/a was estimated from 3 H/ 3 He dating of the shallow groundwater. Thus in the model area, recharge of surface water from the river distributaries and recharge through a confining clay is of the same magnitude, being on average around 100 mm/a. The thickness of the confining clay varies between 2 and 10 m, and affects the recharge rate and the transport of electron acceptors (O 2 , NO 3 - and SO 4 2- ) into the aquifer. Where the clay layer is thin, an up to 2 m thick oxic zone develops in the shallow aquifer. In the oxic zone the As concentration is less than 1 μg/L but increases in the reduced zone below to 550 μg/L. In the Holocene

Graphene oxide based photoinduced charge transfer label-free near-infrared fluorescent biosensor for dopamine.

Science.gov (United States)

Chen, Jin-Long; Yan, Xiu-Ping; Meng, Kang; Wang, Shu-Feng

2011-11-15

While the super fluorescence quenching capacity of graphene and graphene oxide (GO) has been extensively employed to develop fluorescent sensors, their own unique fluorescence and its potential for chemo-/biosensing have seldom been explored. Here we report a GO-based photoinduced charge transfer (PCT) label-free near-infrared (near-IR) fluorescent biosensor for dopamine (DA). The multiple noncovalent interactions between GO and DA and the ultrafast decay at the picosecond range of the near-IR fluorescence of GO resulted in effective self-assembly of DA molecules on the surface of GO, and significant fluorescence quenching, allowing development of a PCT-based biosensor with direct readout of the near-IR fluorescence of GO for selective and sensitive detection of DA. The developed method gave a detection limit of 94 nM and a relative standard deviation of 2.0% for 11 replicate detections of 2.0 μM DA and was successfully applied to the determination of DA in biological fluids with quantitative recovery (98-115%).

Aquifers productivity in the Pan-African context

Indian Academy of Sciences (India)

, including 14 near existing boreholes for comparison. Aquifer parameters of hydraulic conductivity and transmissivity were obtained by analyzing pumping test data from existing boreholes. An empirical relationship between hydraulic ...

In-situ observation of oxidation of Ti(0001) surface by real-time photoelectron spectroscopy using synchrotron radiation

CERN Document Server

Takakuwa, Y; Yoshigoe, A; Teraoka, Y; Mizuno, Y; Tonda, H; Homma, T

2003-01-01

Temperature dependence of the initial oxidation kinetics of Ti(0001) surface was investigated by low energy electron diffraction (LEED) and real-time photoelectron spectroscopy using synchrotron radiation of surface- and bulk-sensitive photon energies. LEED observation revealed that oxide layers grow epitaxially with different surface structures depending on temperature: 1x1 at 200degC and sq root 3 x sq root 3 at 400degC. From the oxygen uptake curve measured by O 1s photo-electron intensity, it was clarified that oxygen diffusion through the epitaxially grown oxide layer is significantly enhanced with raising temperature, making the oxide layer thicker than 70A at 400degC. The chemical shift components observed for Ti 2p showed that TiO sub 2 becomes predominant at the subsurface with O sub 2 dose, while the stoichiometry of oxide near the interface is maintained as TiO and Ti sub 2 O sub 3 , for both cases at 200degC and 400degC. Thus it is concluded that the epitaxial growth of a very thin oxide on the Ti...

Oxidation and photo-oxidation of water on TiO2 surface

DEFF Research Database (Denmark)

Valdes, A.; Qu, Z.W.; Kroes, G.J.

2008-01-01

The oxidation and photo-oxidation of water on the rutile TiO2(110) surface is investigated using density functional theory (DFT) calculations. We investigate the relative stability of different surface terminations of TiO2 interacting with H2O and analyze the overpotential needed for the electrol...

Hydrology of coal-lease areas near Durango, Colorado

Science.gov (United States)

Brooks, Tom

1985-01-01

The U.S. Bureau of Land Management leases Federal lands and minerals for coal mining near Durango, Colorado. This report addresses the hydrologic suitability of those lands for coal leasing; the report describes the general hydrology of the Durango area and, more specifically, the hydrology of the Stollsteimer Creek study area 32 miles east of the Durango and the Hay Gulch study area, 12 miles southwest of Durango. The most productive aquifers in the Durango study area are Quaternary alluvium and the tertiary Animas Formation. Water wells completed in alluvium typically yield 5 to 20 gallons/min; wells completed is the Animas Formation yield as much as 50 gallons/min. Water quality in these aquifers is variable, but it generally is suitable for domestic use. The coal-bearing Cretaceous Fruitland and Menefee Formations are mined by surface methods at the Chimney Rock Mine in the Stollsteimer Creek study area and by underground methods at the National King Coal Mine in the Hay Gulch study area. Effects of surface mining in the Stollsteimer Creek area are: (1) Dewatering of an alluvial aquifer; and (2) Local degradation of alluvium water quality by spoil-pile effluent. Effects of underground mining in the Hay Gulch area are: (1) Introduction of water with greater dissolved-solids concentrations into the upper Hay Gulch alluvium from mine runoff; (2) Subsidence fracturing which could dewater streams and the alluvial aquifer. (USGS)

Ground-water levels in aquifers used for residential supply, Campton Township, Kane County, Illinois

Science.gov (United States)

Kay, Robert T.; Kraske, Kurt A.

1996-01-01

The U.S. Geological Survey, in cooperation with the Campton Township Board of Trustees, measured water levels in the aquifers used for residential supply in Campton Township, Kane County, Illinois. Aquifers used for residential supply are the shallow and deep aquifers in the glacial drift, composed of unconsolidated sand and gravels; the Alexandrian-Maquoketa aquifer, composed of dolomite and shale of the Alexandrian Series and the Maquoketa Group; the Galena-Platteville aquifer, composed of dolomite of the Platteville and Galena Groups; and the Ancell aquifer, composed of sandstones of the Glenwood Formation and the St. Peter Sanstone. Water-level altitudes in the shallow drift aquifers generally follow surface topography. Analysis of water-level data does not clearly indicate overutilization of these aquifers. Water-level altitudes in the deep drift aquifers decrease from west to east. Comparison of historical depth to water measurements with current (1995) measurements indicates large decreases in water levels in some areas. The deep drift aquifers may be overutilized at these locations. Water-level altitudes in the Alexandrian-Maquoketa aquifer generally decrease from west to east. The potentiometric surface of the aquifer follows the bedrock-surface topography in some locations. Localized low water-level altitudes and large decreases in water levels indicate the Alexandrian-Maquoketa aquifer is overutilized in several areas. Water-level altitudes in the wells finished in the Galena- Platteville aquifer vary by more than 300 feet. Large decreases in water levels in wells finished in the Galena-Platteville aquifer indicate the Galena-Platteville and Alexandrian-Maquoketa aquifers are overutilized in the northern part of the township. Water-level altitudes in the wells finished in the Ancell aquifer are also highly variable. There is no indication that the Ancell aquifer is overutilized.

Control of Surface and Edge Oxidation on Phosphorene.

Science.gov (United States)

Kuntz, Kaci L; Wells, Rebekah A; Hu, Jun; Yang, Teng; Dong, Baojuan; Guo, Huaihong; Woomer, Adam H; Druffel, Daniel L; Alabanza, Anginelle; Tománek, David; Warren, Scott C

2017-03-15

Phosphorene is emerging as an important two-dimensional semiconductor, but controlling the surface chemistry of phosphorene remains a significant challenge. Here, we show that controlled oxidation of phosphorene determines the composition and spatial distribution of the resulting oxide. We used X-ray photoemission spectroscopy to measure the binding energy shifts that accompany oxidation. We interpreted these spectra by calculating the binding energy shift for 24 likely bonding configurations, including phosphorus oxides and hydroxides located on the basal surface or edges of flakes. After brief exposure to high-purity oxygen or high-purity water vapor at room temperature, we observed phosphorus in the +1 and +2 oxidation states; longer exposures led to a large population of phosphorus in the +3 oxidation state. To provide insight into the spatial distribution of the oxide, transmission electron microscopy was performed at several stages during the oxidation. We found crucial differences between oxygen and water oxidants: while pure oxygen produced an oxide layer on the van der Waals surface, water oxidized the material at pre-existing defects such as edges or steps. We propose a mechanism based on the thermodynamics of electron transfer to interpret these observations. This work opens a route to functionalize the basal surface or edges of two-dimensional (2D) black phosphorus through site-selective chemical reactions and presents the opportunity to explore the synthesis of 2D phosphorene oxide by oxidation.

ISLSCP II Reanalysis Near-Surface Meteorology Data

Data.gov (United States)

National Aeronautics and Space Administration — This data set for the ISLSCP Initiative II data collection provides near surface meteorological variables, fluxes of heat, moisture and momentum at the surface, and...

Groundwater origin investigation with isotopic compositions for evaluation of high productive deep aquifers in Khon Kaen area, Northeast Thailand

International Nuclear Information System (INIS)

Buaphan, C.; Yangme, W.; Wannakao, L.; Sriboonlue, V.; Tassanasorn, A.; Buapeng, S.

1999-01-01

Investigation of groundwater origin by using isotopic compositions for evaluation of high productive deep aquifers in Khon Kaen Province is emphasized on hydrogeology and isotopes technique. The study area consists of Mesozoic sedimentary rocks and unconsolidated sediments of Quaternary. Phu Tok aquifers in the southern part of the study area are mainly confined in very well sorted, fine grained sandstone as well as in fractures and joints. They extend from Ban Tha Pra to Ban Phai covering area 500 km 2 . Depth to the aquifers is from 20 to 250 m, while their piezometric surface ranges from 0.35 m to 15 m from the ground surface. Their thickness range from 50 to 100 m. The transmissivity is from 0.45 to 1,047 m 2 /d on the pumping rate of 48-1,200 m 3 /d with drawdown of less than 10% and rough annual safe yield is 83.34x10 6 m 3 . The water is very good in quality for drinking, except for the TDS and total hardness around aquifer boundary. The groundwater and surface water are analysed for stable and radioactive isotopes, including 2 H, 18 O, 3 H and 14 C. The results show that the shallow groundwater of the depth less than 50 m is originated by direct recharge of rainfall between 180 and 6,820 a. The groundwater flow is relatively rapid from west to east and northwest to southeast, the high productive deep aquifer of Phu Tok flow radiate from recharging area to all direction. However, the groundwater flow rate based on 14 C analyses for Phu Tok is 2 to 3 m/a. Within some areas the flow is about 8 m/a, while the unconsolidated aquifers along the Phong River give flow rate about 4 m/a. The deeper aquifers also have direct rain recharge the same as the above aquifers but the flow rate are lower, especially the deepest aquifer at the depth of nearly 200 m indicated no direct rain recharge with age of more than 20 000 a, which is confirmed with the amount of tritium less than 1.0 TU. (author)

Inferring near surface soil temperature time series from different land uses to quantify the variation of heat fluxes into a shallow aquifer in Austria

Science.gov (United States)

Kupfersberger, Hans; Rock, Gerhard; Draxler, Johannes C.

2017-09-01

Different land uses exert a strong spatially distributed and temporal varying signal of heat fluxes from the surface in or out of the ground. In this paper we show an approach to quantify the heat fluxes into a groundwater body differentiating between near surface soil temperatures under grass, forest, asphalt, agriculture and surface water bodies and heat fluxes from subsurface structures like heated basements or sewage pipes. Based on observed time series of near surface soil temperatures we establish individual parameters (e.g. shift, moving average) of a simple empirical function that relates air temperature to soil temperature. This procedure is useful since air temperature time series are readily available and the complex energy flux processes at the soil atmosphere interface do not need to be described in detail. To quantify the heat flux from heated subsurface structures that have lesser depths to the groundwater table the 1D heat conduction module SoilTemp is developed. Based on soil temperature time series observed at different depths in a research lysimeter heat conduction and heat storage capacity values are calibrated disregarding their dependence on the water content. With SoilTemp the strong interaction between time series of groundwater temperature and groundwater level, near surface soil temperatures and the basement temperatures in heated buildings could be evaluated showing the dynamic nature of thermal gradients. The heat fluxes from urban areas are calculated considering the land use patterns within a spatial unit by mixing the heat fluxes from basements with those under grass and asphalt. The heat fluxes from sewage pipes and of sewage leakage are shown to be negligible for evaluated pipe diameters and sewage discharges. The developed methodology will allow to parameterize the upper boundary of heat transport models and to differentiate between the heat fluxes from different surface usages and their dynamics into the subsurface.

Quantum field theory near surfaces of discontinuity

International Nuclear Information System (INIS)

Onishi, H.T.

1981-01-01

This work deals with the problem of a quantized scalar field propagating near a surface of discontinuity. The proper time formalism is employed to express the Green's function and stress tensor as proper time integrals of a transformation function. The transformation function is calculated by a WKB approximation which exhibits the essential singularities generated by the high frequency behavior of waves propagating near the surface. Two singularities are present, the usual direct singularity and an additional reflected singularity generated by the high frequency behavior of waves reflected by the discontinuity. The stress tensor is calculated by dimensional continuation. The results are employed to analyze energy generated by the surface

Technology and economics of near-surface geothermal resources exploitation

Directory of Open Access Journals (Sweden)

Э. И. Богуславский

2017-04-01

Full Text Available The paper presents economic justification for applicability of near-surface geothermal installations in Luga region, based on results of techno-economic calculations as well as integrated technical and economic comparison of different prediction scenarios of heat supply, both conventional and using geothermal heat pumps (GHP. Construction costs of a near-surface geothermal system can exceed the costs of central heating by 50-100 %. However, operation and maintenance (O&M costs of heat production for geothermal systems are 50-70 % lower than for conventional sources of heating. Currently this technology is very important, it is applied in various countries (USA, Germany, Japan, China etc., and depending on the region both near-surface and deep boreholes are being used. World practice of near-surface geothermal systems application is reviewed in the paper.

Near-surface processing on AlGaN/GaN heterostructures: a nanoscale electrical and structural characterization

Directory of Open Access Journals (Sweden)

Greco Giuseppe

2011-01-01

Full Text Available Abstract The effects of near-surface processing on the properties of AlGaN/GaN heterostructures were studied, combining conventional electrical characterization on high-electron mobility transistors (HEMTs, with advanced characterization techniques with nanometer scale resolution, i.e., transmission electron microscopy, atomic force microscopy (AFM and conductive atomic force microscopy (C-AFM. In particular, a CHF3-based plasma process in the gate region resulted in a shift of the threshold voltage in HEMT devices towards less negative values. Two-dimensional current maps acquired by C-AFM on the sample surface allowed us to monitor the local electrical modifications induced by the plasma fluorine incorporated in the material. The results are compared with a recently introduced gate control processing: the local rapid thermal oxidation process of the AlGaN layer. By this process, a controlled thin oxide layer on surface of AlGaN can be reliably introduced while the resistance of the layer below increase locally.

Near-surface processing on AlGaN/GaN heterostructures: a nanoscale electrical and structural characterization.

Science.gov (United States)

Greco, Giuseppe; Giannazzo, Filippo; Frazzetto, Alessia; Raineri, Vito; Roccaforte, Fabrizio

2011-02-11

The effects of near-surface processing on the properties of AlGaN/GaN heterostructures were studied, combining conventional electrical characterization on high-electron mobility transistors (HEMTs), with advanced characterization techniques with nanometer scale resolution, i.e., transmission electron microscopy, atomic force microscopy (AFM) and conductive atomic force microscopy (C-AFM). In particular, a CHF3-based plasma process in the gate region resulted in a shift of the threshold voltage in HEMT devices towards less negative values. Two-dimensional current maps acquired by C-AFM on the sample surface allowed us to monitor the local electrical modifications induced by the plasma fluorine incorporated in the material.The results are compared with a recently introduced gate control processing: the local rapid thermal oxidation process of the AlGaN layer. By this process, a controlled thin oxide layer on surface of AlGaN can be reliably introduced while the resistance of the layer below increase locally.

Novel S-35 Intrinsic Tracer Method for Determining Groundwater Travel Time near Managed Aquifer Recharge Facilities

Science.gov (United States)

Urióstegui, S. H.; Bibby, R. K.; Esser, B. K.; Clark, J. F.

2013-12-01

Identifying groundwater travel times near managed aquifer recharge (MAR) facilities is a high priority for protecting public and environmental health. For MAR facilities in California that incorporate tertiary wastewater into their surface-spreading recharge practices, the target subsurface residence time is >9 months to allow for the natural inactivation and degradation of potential contaminants (less time is needed for full advanced treated water). Established intrinsic groundwater tracer techniques such as tritium/helium-3 dating are unable to resolve timescales of method using a naturally occurring radioisotope of sulfur, sulfur-35 (S-35). After its production in the atmosphere by cosmic ray interaction with argon, S-35 enters the hydrologic cycle as dissolved sulfate through precipitation The short half-life of S-35 (3 months) is ideal for investigating recharge and transport of MAR groundwater on the method, however, has not been applied to MAR operations because of the difficulty in measuring S-35 with sufficient sensitivity in high-sulfate waters. We have developed a new method and have applied it at two southern California MAR facilities where groundwater travel times have previously been characterized using deliberate tracers: 1) Rio Hondo Spreading Grounds in Los Angeles County, and 2) Orange County Groundwater Recharge Facilities in Orange County. Reasonable S-35 travel times of method also identified seasonal patterns in subsurface travel times, which may not be revealed by a deliberate tracer study that is dependent on the hydrologic conditions during the tracer injection period.

Compilation of geologic, hydrologic, and ground-water flow modeling information for the Spokane Valley-Rathdrum Prairie aquifer, Spokane County, Washington, and Bonner and Kootenai Counties, Idaho

Science.gov (United States)

Kahle, Sue C.; Caldwell, Rodney R.; Bartolino, James R.

2005-01-01

The U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources and Washington Department of Ecology compiled and described geologic, hydrologic, and ground-water flow modeling information about the Spokane Valley-Rathdrum Prairie (SVRP) aquifer in northern Idaho and northeastern Washington. Descriptions of the hydrogeologic framework, water-budget components, ground- and surface-water interactions, computer flow models, and further data needs are provided. The SVRP aquifer, which covers about 370 square miles including the Rathdrum Prairie, Idaho and the Spokane valley and Hillyard Trough, Washington, was designated a Sole Source Aquifer by the U.S. Environmental Protection Agency in 1978. Continued growth, water management issues, and potential effects on water availability and water quality in the aquifer and in the Spokane and Little Spokane Rivers have illustrated the need to better understand and manage the region's water resources. The SVRP aquifer is composed of sand, gravel, cobbles, and boulders primarily deposited by a series of catastrophic glacial outburst floods from ancient Glacial Lake Missoula. The material deposited in this high-energy environment is coarser-grained than is typical for most basin-fill deposits, resulting in an unusually productive aquifer with well yields as high as 40,000 gallons per minute. In most places, the aquifer is bounded laterally by bedrock composed of granite, metasedimentary rocks, or basalt. The lower boundary of the aquifer is largely unknown except along the margins or in shallower parts of the aquifer where wells have penetrated its entire thickness and reached bedrock or silt and clay deposits. Based on surface geophysics, the thickness of the aquifer is about 500 ft near the Washington-Idaho state line, but more than 600 feet within the Rathdrum Prairie and more than 700 feet in the Hillyard trough based on drilling records. Depth to water in the aquifer is greatest in the northern

Assessing the impact of managed aquifer recharge on seasonal low flows in a semi-arid alluvial river

Science.gov (United States)

Ronayne, M. J.; Roudebush, J. A.; Stednick, J. D.

2016-12-01

Managed aquifer recharge (MAR) is one strategy that can be used to augment seasonal low flows in alluvial rivers. Successful implementation requires an understanding of spatio-temporal groundwater-surface water exchange. In this study we conducted numerical groundwater modeling to analyze the performance of an existing MAR system in the South Platte River Valley in northeastern Colorado (USA). The engineered system involves a spatial reallocation of water during the winter months; alluvial groundwater is extracted near the river and pumped to upgradient recharge ponds, with the intent of producing a delayed hydraulic response that increases the riparian zone water table (and therefore streamflow) during summer months. Higher flows during the summer are required to improve riverine habitat for threatened species in the Platte River. Modeling scenarios were constrained by surface (streamflow gaging) and subsurface (well data) measurements throughout the study area. We compare two scenarios to analyze the impact of MAR: a natural base case scenario and an active management scenario that includes groundwater pumping and managed recharge. Steady-periodic solutions are used to evaluate the long-term stabilized behavior of the stream-aquifer system with and without pumping/recharge. Streamflow routing is included in the model, which permits quantification of the timing and location of streamflow accretion (increased streamflow associated with MAR). An analysis framework utilizing capture concepts is developed to interpret seasonal changes in head-dependent flows to/from the aquifer, including groundwater-surface water exchange that impacts streamflow. Results demonstrate that accretion occurs during the target low-flow period but is not limited to those months, highlighting an inefficiency that is a function of the aquifer geometry and hydraulic properties. The results of this study offer guidance for other flow augmentation projects that rely on water storage in shallow

Aquifer Sampling Tube Completion Report: 100 Area and Hanford Townsite Shorelines

International Nuclear Information System (INIS)

Peterson, R.E.; Borghese, J.V.; Erb, D.B.

1998-02-01

Groundwater contamination is known or suspected along the Hanford Site shoreline of the Columbia River adjacent to the retired reactor areas. Along the shoreline away from the reactor areas, where contamination is presumed to be absent, monitoring sites are frequently widely spaced or unavailable to confirm the presumption. Previous characterizations of contamination near the river have relied on data from a limited number of near-river wells, contaminant plume migration predictions, and river bank seepage sampling to anticipate shoreline conditions. In recent years, new methods have been developed to obtain groundwater samples from the aquifer near the groundwater/river water interface. These methods include using (1) divers to obtain samples of pore water from riverbed sediment and (2) sampling tubes that are driven into the aquifer at the shoreline. The latter method also permits sampling the aquifer at multiple depths, which helps to determine the thickness of the potentially contaminated groundwater layer that discharges into the river

Understanding the fate of sanitation-related nutrients in a shallow sandy aquifer below an urban slum area

Science.gov (United States)

Nyenje, P. M.; Havik, J. C. N.; Foppen, J. W.; Muwanga, A.; Kulabako, R.

2014-08-01

We hypothesized that wastewater leaching from on-site sanitation systems to alluvial aquifers underlying informal settlements (or slums) may end up contributing to high nutrient loads to surface water upon groundwater exfiltration. Hence, we conducted a hydro-geochemical study in a shallow sandy aquifer in Bwaise III parish, an urban slum area in Kampala, Uganda, to assess the geochemical processes controlling the transport and fate of dissolved nutrients (NO3, NH4 and PO4) released from on-site sanitation systems to groundwater. Groundwater was collected from 26 observation wells. The samples were analyzed for major ions (Ca, Mg, Na, Mg, Fe, Mn, Cl and SO4) and nutrients (o-PO4, NO3 and NH4). Data was also collected on soil characteristics, aquifer conductivity and hydraulic heads. Geochemical modeling using PHREEQC was used to determine the level of o-PO4 control by mineral solubility and sorption. Groundwater below the slum area was anoxic and had near neutral pH values, high values of EC (average of 1619 μS/cm) and high concentrations of Cl (3.2 mmol/L), HCO3 (11 mmol/L) and nutrients indicating the influence from wastewater leachates especially from pit latrines. Nutrients were predominantly present as NH4 (1-3 mmol/L; average of 2.23 mmol/L). The concentrations of NO3 and o-PO4 were, however, low: average of 0.2 mmol/L and 6 μmol/L respectively. We observed a contaminant plume along the direction of groundwater flow (NE-SW) characterized by decreasing values of EC and Cl, and distinct redox zones. The redox zones transited from NO3-reducing in upper flow areas to Fe-reducing in the lower flow areas. Consequently, the concentrations of NO3 decreased downgradient of the flow path due to denitrification. Ammonium leached directly into the alluvial aquifer was also partially removed because the measured concentrations were less than the potential input from pit latrines (3.2 mmol/L). We attributed this removal (about 30%) to anaerobic ammonium oxidation

IAEA KEN 7005 project: Evaluation of Surface and Groundwater Interaction of the Kilimanjaro Aquifer applying Isotope Techniques

International Nuclear Information System (INIS)

Opiyo, A.N.E.

2017-01-01

Mombasa City is the second largest city in Kenya, has inadequate water supply and experiences a chronic water shortage. Mombasa City and the other areas to its north are supplied with water from the Mzima springs and other systems. Mzima Springs is location in relation to Chyulu Hills and Mt. Kilimanjaro. This study therefore attempts to examine the relationship between Mzima Springs on one hand and Kilimanjaro Aquifer and Chyulu Hills aquifer/springs on the other. The overall objective of this project is to conduct water resources assessment to quantify water in the project area and establish the relationship between surface and groundwater resources in the Mt. Kilimanjaro, Lakes Jipe/Challa, Mzima and Chyulu Hills ecosystem. The Kilimanjaro aquifer includes the volcanic pyroclastic and volcanic alluvium deposits found at the base of Mount Kilimanjaro and extending across the Kenyan-Tanzanian border. Occurrence of groundwater in the surrounding basement plains is limited to faults, fractures and small parts of weathered zones and also to the bottom layers of wide alluvial valleys which are recharged by natural flood spreading. One of the achievement include establishment and equipping of the National Isotope Hydrology Laboratory

Ground-water quality in the carbonate-rock aquifer of the Great Basin, Nevada and Utah, 2003

Science.gov (United States)

Schaefer, Donald H.; Thiros, Susan A.; Rosen, Michael R.

2005-01-01

�g/L, with a median value of 9.6 μg/L. Factors affecting arsenic concentration in the carbonate-rock aquifer in addition to geothermal heating are its natural occurrence in the aquifer material and time of travel along the flow path.Most of the chemical analyses, especially for VOCs and nutrients, indicate little, if any, effect of overlying land-use patterns on ground-water quality. The water quality in recharge areas for the aquifer where human activities are more intense may be affected by urban and/or agricultural land uses as evidenced by pesticide detections. The proximity of the carbonate-rock aquifer at these sites to the land surface and the potential for local recharge to occur through the fractured rock likely results in the occurrence of these and other land-surface related contaminants in the ground water. Water from sites sampled near outcrops of carbonate-rock aquifer likely has a much shorter residence time resulting in a potential for detection of anthropogenic or land-surface related compounds. Sites located in discharge areas of the flow systems or wells that are completed at a great depth below the land surface generally show no effects of land-use activities on water quality. Flow times within the carbonate-rock aquifer, away from recharge areas, are on the order of thousands of years, so any contaminants introduced at the land surface that will not degrade along the flow path have not reached the sampled sites in these areas.

Successful Sampling Strategy Advances Laboratory Studies of NMR Logging in Unconsolidated Aquifers

Science.gov (United States)

Behroozmand, Ahmad A.; Knight, Rosemary; Müller-Petke, Mike; Auken, Esben; Barfod, Adrian A. S.; Ferré, Ty P. A.; Vilhelmsen, Troels N.; Johnson, Carole D.; Christiansen, Anders V.

2017-11-01

The nuclear magnetic resonance (NMR) technique has become popular in groundwater studies because it responds directly to the presence and mobility of water in a porous medium. There is a need to conduct laboratory experiments to aid in the development of NMR hydraulic conductivity models, as is typically done in the petroleum industry. However, the challenge has been obtaining high-quality laboratory samples from unconsolidated aquifers. At a study site in Denmark, we employed sonic drilling, which minimizes the disturbance of the surrounding material, and extracted twelve 7.6 cm diameter samples for laboratory measurements. We present a detailed comparison of the acquired laboratory and logging NMR data. The agreement observed between the laboratory and logging data suggests that the methodologies proposed in this study provide good conditions for studying NMR measurements of unconsolidated near-surface aquifers. Finally, we show how laboratory sample size and condition impact the NMR measurements.

Concentrations of 23 trace elements in ground water and surface water at and near the Idaho National Engineering Laboratory, Idaho, 1988--91

International Nuclear Information System (INIS)

Liszewski, M.J.; Mann, L.J.

1993-01-01

Analytical data for 23 trace elements are reported for ground- and surface-water samples collected at and near the Idaho National Engineering Laboratory during 1988--91. Water samples were collected from 148 wells completed in the Snake River Plain aquifer, 18 wells completed in discontinuous deep perched-water zones, and 1 well completed in an alluvial aquifer. Surface-water samples also were collected from three streams, two springs, two ponds, and one lake. Data are categorized by concentrations of total recoverable of dissolved trace elements. Concentrations of total recoverable trace elements are reported for unfiltered water samples and include results for one or more of the following: aluminum, arsenic, barium, beryllium, cadmium, chromium, cobalt, copper, iron, lead, manganese, mercury, nickel, selenium, silver, and zinc. Concentrations of dissolved trace elements are reported for water samples filtered through a nominal 0.45-micron filter and may also include bromide, fluoride, lithium, molybdenum, strontium, thallium, and vanadium. Concentrations of dissolved hexavalent chromium also are reported for many samples. The water samples were analyzed at the US Geological Survey's National Water Quality Laboratory in Arvada, Colorado. Methods used to collect the water samples and quality assurance instituted for the sampling program are described. Concentrations of chromium equaled or exceeded the maximum contaminant level at 12 ground-water quality monitoring wells. Other trace elements did not exceed their respective maximum contaminant levels

Concentrations of 23 trace elements in ground water and surface water at and near the Idaho National Engineering Laboratory, Idaho, 1988--91

Energy Technology Data Exchange (ETDEWEB)

Liszewski, M.J.; Mann, L.J.

1993-12-31

Analytical data for 23 trace elements are reported for ground- and surface-water samples collected at and near the Idaho National Engineering Laboratory during 1988--91. Water samples were collected from 148 wells completed in the Snake River Plain aquifer, 18 wells completed in discontinuous deep perched-water zones, and 1 well completed in an alluvial aquifer. Surface-water samples also were collected from three streams, two springs, two ponds, and one lake. Data are categorized by concentrations of total recoverable of dissolved trace elements. Concentrations of total recoverable trace elements are reported for unfiltered water samples and include results for one or more of the following: aluminum, arsenic, barium, beryllium, cadmium, chromium, cobalt, copper, iron, lead, manganese, mercury, nickel, selenium, silver, and zinc. Concentrations of dissolved trace elements are reported for water samples filtered through a nominal 0.45-micron filter and may also include bromide, fluoride, lithium, molybdenum, strontium, thallium, and vanadium. Concentrations of dissolved hexavalent chromium also are reported for many samples. The water samples were analyzed at the US Geological Survey`s National Water Quality Laboratory in Arvada, Colorado. Methods used to collect the water samples and quality assurance instituted for the sampling program are described. Concentrations of chromium equaled or exceeded the maximum contaminant level at 12 ground-water quality monitoring wells. Other trace elements did not exceed their respective maximum contaminant levels.

Flow and sorption controls of groundwater arsenic in individual boreholes from bedrock aquifers in central Maine, USA.

Science.gov (United States)

Yang, Qiang; Culbertson, Charles W; Nielsen, Martha G; Schalk, Charles W; Johnson, Carole D; Marvinney, Robert G; Stute, Martin; Zheng, Yan

2015-02-01

To understand the hydrogeochemical processes regulating well water arsenic (As) evolution in fractured bedrock aquifers, three domestic wells with [As] up to 478 μg/L are investigated in central Maine. Geophysical logging reveals that fractures near the borehole bottom contribute 70-100% of flow. Borehole and fracture water samples from various depths show significant proportions of As (up to 69%) and Fe (93-99%) in particulates (>0.45 μm). These particulates and those settled after a 16-day batch experiment contain 560-13,000 mg/kg of As and 14-35% weight/weight of Fe. As/Fe ratios (2.5-20 mmol/mol) and As partitioning ratios (adsorbed/dissolved [As], 20,000-100,000 L/kg) suggest that As is sorbed onto amorphous hydrous ferric oxides. Newly drilled cores also show enrichment of As (up to 1300 mg/kg) sorbed onto secondary iron minerals on the fracture surfaces. Pumping at high flow rates induces large decreases in particulate As and Fe, a moderate increase in dissolved [As] and As(III)/As ratio, while little change in major ion chemistry. The δD and δ(18)O are similar for the borehole and fracture waters, suggesting a same source of recharge from atmospheric precipitation. Results support a conceptual model invoking flow and sorption controls on groundwater [As] in fractured bedrock aquifers whereby oxygen infiltration promotes the oxidation of As-bearing sulfides at shallower depths in the oxic portion of the flow path releasing As and Fe; followed by Fe oxidation to form Fe oxyhydroxide particulates, which are transported in fractures and sorb As along the flow path until intercepted by boreholes. In the anoxic portions of the flow path, reductive dissolution of As-sorbed iron particulates could re-mobilize As. For exposure assessment, we recommend sampling of groundwater without filtration to obtain total As concentration in groundwater. Copyright © 2014 Elsevier B.V. All rights reserved.

Hydrogeology in the area of a freshwater lens in the Floridan aquifer system, northeast Seminole County, Florida

Science.gov (United States)

Phelps, G.G.; Rohrer, K.P.

1987-01-01

Northeast Seminole County, Florida, contains an isolated recharge area of the Floridan aquifer system that forms a freshwater lens completely surrounded by saline water. The freshwater lens covers an area of about 22 sq mi surrounding the town of Geneva, and generally is enclosed by the 25 ft land surface altitude contour. Thickness of the lens is about 350 ft in the center of the recharge area. The geohydrologic units in descending order consist of the post-Miocene sand and shell of the surficial aquifer; Miocene clay, sand, clay, and shell that form a leaky confining bed; and permeable Eocene limestones of the Floridan aquifer system. The freshwater lens is the result of local rainfall flushing ancient seawater from the Floridan aquifer system. Sufficient quantities of water for domestic and small public supply systems are available from the Floridan aquifer system in the Geneva area. The limiting factor for water supply in the area is the chemical quality of the water. Chloride concentrations range from recharge area to about 5,100 mg/L near the St. Johns River southeast of Geneva. Constituents analyzed included sulfate (range 1 to 800 mg/L), hardness (range 89 to 2,076 mg/L), and iron (range 34 to 6,600 mg/L). Because the freshwater lens results entirely from local recharge, the long-term sustained freshwater yield of the aquifer in the Geneva area depends on the local recharge rate. In 1982, recharge was about 13 inches (13.8 million gal/day). Average recharge for 1941 through 1970 was estimated to be about 11 inches (11.3 million gal/day). Freshwater that recharges the aquifer in the Geneva area is either pumped out or flows north and northeast to discharge near or in the St. Johns River. Average annual outflow from the lens is about 10 in/yr. No measurable change in the size or location of the freshwater lens has occurred since studies in the early 1950's. (Lantz-PTT)

Propagation of seasonal temperature signals into an aquifer upon bank infiltration.

Science.gov (United States)

Molina-Giraldo, Nelson; Bayer, Peter; Blum, Philipp; Cirpka, Olaf A

2011-01-01

Infiltrating river water carries the temperature signal of the river into the adjacent aquifer. While the diurnal temperature fluctuations are strongly dampened, the seasonal fluctuations are much less attenuated and can be followed into the aquifer over longer distances. In one-dimensional model with uniform properties, this signal is propagated with a retarded velocity, and its amplitude decreases exponentially with distance. Therefore, time shifts in seasonal temperature signals between rivers and groundwater observation points may be used to estimate infiltration rates and near-river groundwater velocities. As demonstrated in this study, however, the interpretation is nonunique under realistic conditions. We analyze a synthetic test case of a two-dimensional cross section perpendicular to a losing stream, accounting for multi-dimensional flow due to a partially penetrating channel, convective-conductive heat transport within the aquifer, and heat exchange with the underlying aquitard and the land surface. We compare different conceptual simplifications of the domain in order to elaborate on the importance of different system elements. We find that temperature propagation within the shallow aquifer can be highly influenced by conduction through the unsaturated zone and into the underlying aquitard. In contrast, regional groundwater recharge has no major effect on the simulated results. In our setup, multi-dimensionality of the flow field is important only close to the river. We conclude that over-simplistic analytical models can introduce substantial errors if vertical heat exchange at the aquifer boundaries is not accounted for. This has to be considered when using seasonal temperature fluctuations as a natural tracer for bank infiltration. Copyright © 2010 The Author(s). Journal compilation © 2010 National Ground Water Association.

Superresolution Near-field Imaging with Surface Waves

KAUST Repository

Fu, Lei; Liu, Zhaolun; Schuster, Gerard T.

2017-01-01

We present the theory for near-field superresolution imaging with surface waves and time reverse mirrors (TRMs). Theoretical formulas and numerical results show that applying the TRM operation to surface waves in an elastic half-space can achieve

Imaging near-surface heterogeneities by natural migration of surface waves

KAUST Repository

Liu, Zhaolun

2016-09-06

We demonstrate that near-surface heterogeneities can be imaged by natural migration of backscattered surface waves in common shot gathers. No velocity model is required because the data are migrated onto surface points with the virtual Green\\'s functions computed from the shot gathers. Migrating shot gathers recorded by 2D and 3D land surveys validates the effectiveness of detecting nearsurface heterogeneities by natural migration. The implication is that more accurate hazard maps can be created by migrating surface waves in land surveys.

Characterization of the inside and outside oxide surfaces of irradiated pressure tubes of Embalse nuclear power plant

International Nuclear Information System (INIS)

Bordoni, Roberto A.; Olmedo, Ana M.

2004-01-01

The inside and outside surfaces of two pressure tubes (PT) removed from Embalse nuclear power plant (CNE) after 10 of effective full power years (EFPY) were characterized. The oxide thickness of both faces, in different zones, was also measured. The inside surfaces of both PTs, B-102 (A-14) and B-298 (L-12), were covered with a black oxide that replicates the original PT surface. A network of microcracks perpendicular to the inside surface in contact with the coolant was found. In some cases, near the outlet of the PT, some spalling of the oxide was also found. These small microcracks and spalling do not affect the protective character of the oxide since a thickness about 5 or 6 μm of an undamaged oxide is found at the metal/oxide interface side. The oxide thickness changes between approximately 6 to 12 μm for B-102 tube and around 7 to 15 μm for B-298 tube. The average corrosion rate is 1.16 μm/10 4 HH for B-102 tube and 1.35 μm/10 4 HH for B-298 tube at 5.8 m position for both PTs. These corrosion rates show good corrosion behaviour of CNE PTs. The average corrosion rate of the inside surface of the PTs depends on the coolant temperature but not on fast neutron flux. The outside oxide film is black, shiny, compact and protective, replicating also the original surface. The oxide thickness changes between 2 to 6.5 μm in B-102 tube and between 1.8 to 3.7 μm B-298 tube. These oxide thicknesses are within the values reported for PTs in CANDU Stations. (author) [es

Reactions and reaction rates in the regional aquifer beneath the Pajarito Plateau, north-central New Mexico, USA

Science.gov (United States)

Hereford, Anne G.; Keating, Elizabeth H.; Guthrie, George D.; Zhu, Chen

2007-05-01

Reactions and reaction rates within aquifers are fundamental components of critical hydrological processes. However, reactions simulated in laboratory experiments typically demonstrate rates that are much faster than those observed in the field. Therefore, it is necessary to conduct more reaction rate analyses in natural settings. This study of geochemical reactions in the regional aquifer in the Pajarito Plateau near Los Alamos, New Mexico combines modeling with petrographic assessment to further knowledge and understanding of complex natural hydrologic systems. Groundwater geochemistry shows marked evolution along assumed flow paths. The flow path chosen for this study was evaluated using inverse mass balance modeling to calculate the mass transfer. X-ray diffraction and field emission gun scanning electron microscopy were used to identify possible reactants and products. Considering the mineralogy of the aquifer and saturation indices for the regional water refined initial interpretations. Calculations yielded dissolution rates for plagioclase on the order of 10-15 mol s-1 m-2 and for K-feldspar on the order of 10-17 mol s-1 m-2, orders of magnitude slower than laboratory rates. While these rates agree with other aquifer studies, they must be considered in the light of the uncertainty associated with geometric surface area estimates, 14C ages, and aquifer properties.

Estimating the fates of organic contaminants in an aquifer using QSAR.

Science.gov (United States)

Lim, Seung Joo; Fox, Peter

2013-01-01

The quantitative structure activity relationship (QSAR) model, BIOWIN, was modified to more accurately estimate the fates of organic contaminants in an aquifer. The predictions from BIOWIN were modified to include oxidation and sorption effects. The predictive model therefore included the effects of sorption, biodegradation, and oxidation. A total of 35 organic compounds were used to validate the predictive model. The majority of the ratios of predicted half-life to measured half-life were within a factor of 2 and no ratio values were greater than a factor of 5. In addition, the accuracy of estimating the persistence of organic compounds in the sub-surface was superior when modified by the relative fraction adsorbed to the solid phase, 1/Rf, to that when modified by the remaining fraction of a given compound adsorbed to a solid, 1 - fs.

Baseline geochemical characterisation of a vulnerable tropical karstic aquifer; Lifou, New Caledonia

Directory of Open Access Journals (Sweden)

Eric Nicolini

2016-03-01

Full Text Available Study region: Lifou Island, near the main island of New Caledonia. Study focus: Stable oxygen and hydrogen isotopes of groundwater and rainfall were used to characterise baseline values for the main fresh water aquifer of Lifou Island and describe its recharge. Other stable isotope parameters (nitrates and DIC were used to investigate the interaction between surface water (rainfall and groundwater, including anthropogenic effects from human activities. New hydrological insights for the region: This study represents the first baseline isotopic characterisation of Lifou Island’s groundwater aquifer composition and provides a reference for future investigative studies on groundwater quality and security. Groundwater sampled in June and October 2012 had nearly identical isotopic composition. Tap water sampled monthly between February 2012 and January 2014 also had a constant isotopic composition similar to the groundwater. Groundwater recharge was found to occur when monthly precipitation exceeded 140 mm, with the recharge cycle representing 20–30% of the annual rainfall. Relationships between HCO32− content, pH, soil δ13C DIC and satellite photo interpretation suggests a variance of soil pCO2, which is explained by different vegetation cover and higher water use efficiencies in forested areas (high pCO2, more negative δ13C isotope values. The δ15NNO3 values for most groundwater indicate they are uncontaminated with anthropogenic nitrates, although some samples taken in October (dry season showed a slight denitrification, possibly of natural origin. Keywords: Reef islands, Precipitation, Karstic aquifer, Hydrogeology, Stable isotopes, Nitrates

Effects of Sea Level Rise on Groundwater Flow Paths in a Coastal Aquifer System

Science.gov (United States)

Morrissey, S. K.; Clark, J. F.; Bennett, M. W.; Richardson, E.; Stute, M.

2008-05-01

Changes in groundwater flow in the Floridan aquifer system, South Florida, from the rise in sea level at the end of the last glacial period may be indicative of changes coastal aquifers will experience with continued sea level rise. As sea level rises, the hydraulic head near the coast increases. Coastal aquifers can therefore experience decreased groundwater gradients (increased residence times) and seawater intrusion. Stable isotopes of water, dissolved noble gas temperatures, radiocarbon and He concentrations were analyzed in water collected from 68 wells in the Floridan aquifer system throughout South Florida. Near the recharge area, geochemical data along groundwater flow paths in the Upper Floridan aquifer show a transition from recently recharged groundwater to glacial-aged water. Down gradient from this transition, little variation is apparent in the stable isotopes and noble gas recharge temperatures, indicating that most of the Upper Floridan aquifer contains groundwater recharged during the last glacial period. The rapid 120-meter rise in sea level marking the end of the last glacial period increased the hydraulic head in the Floridan aquifer system near the coast, slowing the flow of groundwater from the recharge area to the ocean and trapping glacial-aged groundwater. The raised sea level also flooded half of the Florida platform and caused seawater to intrude into the Lower Floridan. This circulation of seawater in the Lower Floridan continues today as our data indicate that the groundwater is similar to modern seawater with a freshwater component entering vertically from the recharge area to the Upper Floridan.

Assessments of aquifer sensitivity on Navajo Nation and adjacent lands and ground-water vulnerability to pesticide contamination on the Navajo Indian Irrigation Project, Arizona, New Mexico, and Utah

Science.gov (United States)

Blanchard, Paul J.

2002-01-01

The U.S. Environmental Protection Agency requested that the Navajo Nation conduct an assessment of aquifer sensitivity on Navajo Nation lands and an assessment of ground-water vulnerability to pesticide contamination on the Navajo Indian Irrigation Project. Navajo Nation lands include about 17,000 square miles in northeastern Arizona, northwestern New Mexico, and southeastern Utah. The Navajo Indian Irrigation Project in northwestern New Mexico is the largest area of agriculture on the Navajo Nation. The Navajo Indian Irrigation Project began operation in 1976; presently (2001) about 62,000 acres are available for irrigated agriculture. Numerous pesticides have been used on the Navajo Indian Irrigation Project during its operation. Aquifer sensitivity is defined by the U.S. Environmental Protection Agency as 'The relative ease with which a contaminant [pesticide] applied on or near a land surface can migrate to the aquifer of interest. Aquifer sensitivity is a function of the intrinsic characteristics of the geologic material in question, any underlying saturated materials, and the overlying unsaturated zone. Sensitivity is not dependent on agronomic practices or pesticide characteristics.' Ground-water vulnerability is defined by the U.S. Environmental Protection Agency as 'The relative ease with which a contaminant [pesticide] applied on or near a land surface can migrate to the aquifer of interest under a given set of agronomic management practices, pesticide characteristics, and aquifer sensitivity conditions.' The results of the aquifer sensitivity assessment on Navajo Nation and adjacent lands indicated relative sensitivity within the boundaries of the study area. About 22 percent of the study area was not an area of recharge to bedrock aquifers or an area of unconsolidated deposits and was thus assessed to have an insignificant potential for contamination. About 72 percent of the Navajo Nation study area was assessed to be in the categories of most potential

Biogeochemistry at a wetland sediment-alluvial aquifer interface in a landfill leachate plume

Science.gov (United States)

Lorah, M.M.; Cozzarelli, I.M.; Böhlke, J.K.

2009-01-01

The biogeochemistry at the interface between sediments in a seasonally ponded wetland (slough) and an alluvial aquifer contaminated with landfill leachate was investigated to evaluate factors that can effect natural attenuation of landfill leachate contaminants in areas of groundwater/surface-water interaction. The biogeochemistry at the wetland-alluvial aquifer interface differed greatly between dry and wet conditions. During dry conditions (low water table), vertically upward discharge was focused at the center of the slough from the fringe of a landfill-derived ammonium plume in the underlying aquifer, resulting in transport of relatively low concentrations of ammonium to the slough sediments with dilution and dispersion as the primary attenuation mechanism. In contrast, during wet conditions (high water table), leachate-contaminated groundwater discharged upward near the upgradient slough bank, where ammonium concentrations in the aquifer where high. Relatively high concentrations of ammonium and other leachate constituents also were transported laterally through the slough porewater to the downgradient bank in wet conditions. Concentrations of the leachate-associated constituents chloride, ammonium, non-volatile dissolved organic carbon, alkalinity, and ferrous iron more than doubled in the slough porewater on the upgradient bank during wet conditions. Chloride, non-volatile dissolved organic carbon (DOC), and bicarbonate acted conservatively during lateral transport in the aquifer and slough porewater, whereas ammonium and potassium were strongly attenuated. Nitrogen isotope variations in ammonium and the distribution of ammonium compared to other cations indicated that sorption was the primary attenuation mechanism for ammonium during lateral transport in the aquifer and the slough porewater. Ammonium attenuation was less efficient, however, in the slough porewater than in the aquifer and possibly occurred by a different sorption mechanism. A

Near-Surface Geophysical Character of a Holocene Fault Carrying Geothermal Flow Near Pyramid Lake, Nevada

Science.gov (United States)

Dudley, C.; Dorsey, A.; Louie, J. N.; Schwering, P. C.; Pullammanappallil, S.

2012-12-01

Lines of calcium carbonate tufa columns mark recent faults that cut 11 ka Lake Lahontan sediments at Astor Pass, north of Pyramid Lake, Nevada. Throughout the Great Basin, faults appear to control the location of geothermal resources, providing pathways for fluid migration. Reservoir-depth (greater than 1 km) seismic imaging at Astor Pass shows a fault that projects to one of the lines of tufa columns at the surface. The presence of the tufa deposits suggests this fault carried warm geothermal waters through the lakebed clay sediments in recent time. The warm fluids deposited the tufa when they hit cold Lake Lahontan water at the lakebed. Lake Lahontan covered this location to a depth of at least 60 m at 11 ka. In collaboration with the Pyramid Lake Paiute Tribe, an Applied Geophysics class at UNR investigated the near-surface geophysical characteristics of this fault. The survey comprises near-surface seismic reflection and refraction, nine near-surface refraction microtremor (SeisOpt® ReMi™) arrays, nine near-surface direct-current resistivity soundings, magnetic surveys, and gravity surveys at and near the tufa columns. The refraction microtremor results show shear velocities near tufa and faults to be marginally lower, compared to Vs away from the faults. Overall, the 30-m depth-averaged shear velocities are low, less than 300 m/s, consistent with the lakebed clay deposits. These results show no indication of any fast (> 500 m/s) tufa below the surface at or near the tufa columns. Vs30 averages were 274 ± 13 m/s on the fault, 287 ± 2 m/s at 150 m east of the fault, and 290 ± 15 m/s at 150 m west of the fault. The P-velocity refraction optimization results also show no indication of high-velocity tufa buried below the surface in the Lahontan sediments, reinforcing the idea that all tufa was deposited above the lakebed surface. The seismic results provide a negative test of the hypothesis that deposition of the lakebeds in the Quaternary buried and

Water resources of Rockland County, New York, 2005-07, with emphasis on the Newark Basin Bedrock Aquifer

Science.gov (United States)

Heisig, Paul M.

2011-01-01

Concerns over the state of water resources in Rockland County, NY, prompted an assessment of current (2005-07) conditions. The investigation included a review of all water resources but centered on the Newark basin aquifer, a fractured-bedrock aquifer over which nearly 300,000 people reside. Most concern has been focused on this aquifer because of (1) high summer pumping rates, with occasional entrained-air problems and an unexplained water-level decline at a monitoring well, (2) annual withdrawals that have approached or even exceeded previous estimates of aquifer recharge, and (3) numerous contamination problems that have caused temporary or long-term shutdown of production wells. Public water supply in Rockland County uses three sources of water in roughly equal parts: (1) the Newark basin sedimentary bedrock aquifer, (2) alluvial aquifers along the Ramapo and Mahwah Rivers, and (3) surface waters from Lake DeForest Reservoir and a smaller, new reservoir supply in the Highlands part of the county. Water withdrawals from the alluvial aquifer in the Ramapo River valley and the Lake DeForest Reservoir are subject to water-supply application permits that stipulate minimum flows that must be maintained downstream into New Jersey. There is a need, therefore, at a minimum, to prevent any loss of the bedrock-aquifer resource--to maintain it in terms of both sustainable use and water-quality protection. The framework of the Newark basin bedrock aquifer included characterization of (1) the structure and fracture occurrence associated with the Newark basin strata, (2) the texture and thickness of overlying glacial and alluvial deposits, (3) the presence of the Palisades sill and associated basaltic units on or within the Newark basin strata, and (4) the streams that drain the aquifer system. The greatest concern regarding sustainability of groundwater resources is the aquifer response to the seasonal increase in pumping rates from May through October (an average increase

Recharge and discharge areas of the Floridan Aquifer in the St. Johns River Water Management District and vicinity, Florida

Science.gov (United States)

Phelps, G.G.

1984-01-01

The Floridan aquifer is the principal source of most of the freshwater used in the St. Johns River Water Management District. An important step in managing water resources is the delineation of recharge and discharge areas. Geohydrologic factors to be considered when delineating recharge and discharge areas include: altitude and configuration of the potentiometric surface; direction and magnitude of the gradient between the water table and the potentiometric surface; and thickness and permeability of the overlying sediments. Recharge to the aquifer comes almost entirely from rainfall within the Water Management District. Significant recharge occurs where the aquifer is at or very near land surface, and where the overlying sediments are very permeable sand so that recharge takes place downward leakage. Recharge also occurs through sinkholes, sinkhole lakes, and other lakes that have a good connection to the aquifer. Major recharge areas are delineated on the map. Discharge occurs in areas of artesian flow (where the potentiometric surface is above land surface), primarily by diffuse upward leakage and by discharge from springs. Fifty-five springs, with total discharge of about 1,600 million gallons per day, are in the Water Management District. Areas of discharge and the location of springs are shown on the map. In 1980, total pumpage in the Water Management District was about 1,000 million gallons per day. Under predevelopment conditions, discharge by springs and upward leakage approximately balanced recharged. Additional discharge by pumpage may or may not be balanced by decreased spring discharge of increased downward leakage. Examination of long-term water level trends can indicate if recharge and discharge balance. Graphs of rainfall, water levels, and municipal pumpage for Jacksonville, Orlando, and Daytona Beach are shown on the map. (USGS)

Organic and inorganic carbon dynamics in a karst aquifer: Santa Fe River Sink-Rise system, north Florida, USA

Science.gov (United States)

Jin, Jin; Zimmerman, Andrew R.; Moore, Paul J.; Martin, Jonathan B.

2014-03-01

Spatiotemporal variations in dissolved organic carbon (DOC), dissolved inorganic carbon (DIC), major ions concentrations and other geochemical parameters including stable carbon isotopes of DIC (δ13CDIC), were measured in surface water and deep and shallow well water samples of the Santa Fe River Sink-Rise eogenetic karst system, north Florida, USA. Three end-member water sources were identified: one DOC-rich/DIC-poor/δ13CDIC-depleted, one DOC-poor/DIC-rich/δ13CDIC-enriched, and one enriched in major ions. Given their spatiotemporal distributions, they were presumed to represent soil water, upper aquifer groundwater, and deep aquifer water sources, respectively. Using assumed ratios of Na+, Cl, and SO42- for each end-member, a mixing model calculated the contribution of each water source to each sample. Then, chemical effects of biogeochemical reactions were calculated as the difference between those predicted by the mixing model and measured species concentrations. In general, carbonate mineral dissolution occurred throughout the Sink-Rise system, surface waters were net autotrophic and the subsurface was in metabolic balance, i.e., no net DOC or DIC production or consumption. However, there was evidence for chemolithoautotrophy, perhaps by hydrogen oxidizing microbes, at some deep aquifer sites. Mineralization of this autochthonous natural dissolved organic matter (NDOM) led to localized carbonate dissolution as did surface water-derived NDOM supplied to shallow well sites during the highest flow periods. This study demonstrates linkages between hydrology, abiotic and microbial processes and carbon dynamics and has important implications for groundwater quality, karst morphologic evolution, and hydrogeologic projects such as aquifer storage and recovery in karst systems.

Impact of leachable sulfate on the quality of groundwater in the Pocatello aquifer

International Nuclear Information System (INIS)

Meehan, C.; Welhan, J.

1994-01-01

During the summer of 1993, groundwaters and surface waters were found to have anomalous sulfate concentrations in the Southern Pocatello municipal aquifer in an area known as the Highway Ponds. Leach tests performed on a large pile of road aggregate stockpiled near the Highway Ponds have been identified as the most likely source for the sulfate. Correlating trends of sulfate and chloride concentrations can be found both in the main Pocatello aquifer and in Pocatello Creek groundwaters. The chloride contamination at Pocatello Creek has previously been suggested to be derived from road salt. It is hypothesized that aggregate used in roadbed construction may be responsible for elevated sulfate in the areas groundwater. Chemical modeling has eliminated carbonate precipitation/dissolution reactions in buffering the chemistry of sulfate-impacted groundwater. Ion-exchange with clays is hypothesized to be a more significant process and is being investigated further. 12 refs., 3 figs

Surface characterization of low-temperature grown yttrium oxide

Science.gov (United States)

Krawczyk, Mirosław; Lisowski, Wojciech; Pisarek, Marcin; Nikiforow, Kostiantyn; Jablonski, Aleksander

2018-04-01

The step-by-step growth of yttrium oxide layer was controlled in situ using X-ray photoelectron spectroscopy (XPS). The O/Y atomic concentration (AC) ratio in the surface layer of finally oxidized Y substrate was found to be equal to 1.48. The as-grown yttrium oxide layers were then analyzed ex situ using combination of Auger electron spectroscopy (AES), elastic-peak electron spectroscopy (EPES) and scanning electron microscopy (SEM) in order to characterize their surface chemical composition, electron transport phenomena and surface morphology. Prior to EPES measurements, the Y oxide surface was pre-sputtered by 3 kV argon ions, and the resulting AES-derived composition was found to be Y0.383O0.465C0.152 (O/Y AC ratio of 1.21). The SEM images revealed different surface morphology of sample before and after Ar sputtering. The oxide precipitates were observed on the top of un-sputtered Y oxide layer, whereas the oxide growth at the Ar ion-sputtered surface proceeded along defects lines normal to the layer plane. The inelastic mean free path (IMFP) characterizing electron transport was evaluated as a function of energy in the range of 0.5-2 keV from the EPES method. Two reference materials (Ni and Au) were used in these measurements. Experimental IMFPs determined for the Y0.383O0.465C0.152 and Y2O3 surface compositions, λ, were uncorrected for surface excitations and approximated by the simple function λ = kEp at electron energies E between 500 eV and 2000 eV, where k and p were fitted parameters. These values were also compared with IMFPs resulting from the TPP-2 M predictive equation for both oxide compositions. The fitted functions were found to be reasonably consistent with the measured and predicted IMFPs. In both cases, the average value of the mean percentage deviation from the fits varied between 5% and 37%. The IMFPs measured for Y0.383O0.465C0.152 surface composition were found to be similar to the IMFPs for Y2O3.

Application of hydrogeology and groundwater-age estimates to assess the travel time of groundwater at the site of a landfill to the Mahomet Aquifer, near Clinton, Illinois

Science.gov (United States)

Kay, Robert T.; Buszka, Paul M.

2016-03-02

The U.S. Geological Survey used interpretations of hydrogeologic conditions and tritium-based groundwater age estimates to assess the travel time of groundwater at a landfill site near Clinton, Illinois (the “Clinton site”) where a chemical waste unit (CWU) was proposed to be within the Clinton landfill unit #3 (CLU#3). Glacial deposits beneath the CWU consist predominantly of low-permeability silt- and clay-rich till interspersed with thin (typically less than 2 feet in thickness) layers of more permeable deposits, including the Upper and Lower Radnor Till Sands and the Organic Soil unit. These glacial deposits are about 170 feet thick and overlie the Mahomet Sand Member of the Banner Formation. The Mahomet aquifer is composed of the Mahomet Sand Member and is used for water supply in much of east-central Illinois.Eight tritium analyses of water from seven wells were used to evaluate the overall age of recharge to aquifers beneath the Clinton site. Groundwater samples were collected from six monitoring wells on or adjacent to the CLU#3 that were open to glacial deposits above the Mahomet aquifer (the upper and lower parts of the Radnor Till Member and the Organic Soil unit) and one proximal production well (approximately 0.5 miles from the CLU#3) that is screened in the Mahomet aquifer. The tritium-based age estimates were computed with a simplifying, piston-flow assumption: that groundwater moves in discrete packets to the sampled interval by advection, without hydrodynamic dispersion or mixing.Tritium concentrations indicate a recharge age of at least 59 years (pre-1953 recharge) for water sampled from deposits below the upper part of the Radnor Till Member at the CLU#3, with older water expected at progressively greater depth in the tills. The largest tritium concentration from a well sampled by this study (well G53S; 0.32 ± 0.10 tritium units) was in groundwater from a sand deposit in the upper part of the Radnor Till Member; the shallowest permeable unit

Potential for cometabolic biodegradation of 1,4-dioxane in aquifers with methane or ethane as primary substrates.

Science.gov (United States)

Hatzinger, Paul B; Banerjee, Rahul; Rezes, Rachael; Streger, Sheryl H; McClay, Kevin; Schaefer, Charles E

2017-12-01

The objective of this research was to evaluate the potential for two gases, methane and ethane, to stimulate the biological degradation of 1,4-dioxane (1,4-D) in groundwater aquifers via aerobic cometabolism. Experiments with aquifer microcosms, enrichment cultures from aquifers, mesophilic pure cultures, and purified enzyme (soluble methane monooxygenase; sMMO) were conducted. During an aquifer microcosm study, ethane was observed to stimulate the aerobic biodegradation of 1,4-D. An ethane-oxidizing enrichment culture from these samples, and a pure culture capable of growing on ethane (Mycobacterium sphagni ENV482) that was isolated from a different aquifer also biodegraded 1,4-D. Unlike ethane, methane was not observed to appreciably stimulate the biodegradation of 1,4-D in aquifer microcosms or in methane-oxidizing mixed cultures enriched from two different aquifers. Three different pure cultures of mesophilic methanotrophs also did not degrade 1,4-D, although each rapidly oxidized 1,1,2-trichloroethene (TCE). Subsequent studies showed that 1,4-D is not a substrate for purified sMMO enzyme from Methylosinus trichosporium OB3b, at least not at the concentrations evaluated, which significantly exceeded those typically observed at contaminated sites. Thus, our data indicate that ethane, which is a common daughter product of the biotic or abiotic reductive dechlorination of chlorinated ethanes and ethenes, may serve as a substrate to enhance 1,4-D degradation in aquifers, particularly in zones where these products mix with aerobic groundwater. It may also be possible to stimulate 1,4-D biodegradation in an aerobic aquifer through addition of ethane gas. Conversely, our results suggest that methane may have limited importance in natural attenuation or for enhancing biodegradation of 1,4-D in groundwater environments.

Direct detection of near-surface faults by migration of back-scattered surface waves

KAUST Repository

Yu, Han

2014-08-05

We show that diffraction stack migration can be used to estimate the distribution of near-surface faults. The assumption is that near-surface faults generate detectable back-scattered surface waves from impinging surface waves. The processing steps are to isolate the back-scattered surface waves, and then migrate them by diffraction migration using the surface wave velocity as the migration velocity. Instead of summing events along trial quasi-hyperbolas, surface wave migration sums events along trial quasi-linear trajectories that correspond to the moveout of back-scattered surface waves. A deconvolution filter derived from the data can be used to collapse a dispersive arrival into a non-dispersive event. Results with synthetic data and field records validate the feasibility of this method. Applying this method to USArray data or passively recorded exploration data might open new opportunities in mapping tectonic features over the extent of the array.

Aquifer recharging in South Carolina: radiocarbon in environmental hydrogeology

International Nuclear Information System (INIS)

Stone, P.A.; Knox, R.L.; Mathews, T.D.

1985-01-01

Radiocarbon activities of dissolved inorganic carbon (and tritium activities where infiltration rates are rapid and aquifers shallow) provide relatively unambiguous and inexpensive evidence for identification of significant recharge areas. Such evidence is for the actual occurrence of modern recharge in the aquifer and thus is less inferential than stratigraphic or potentiometric evidence. These underutilized isotopic techniques are neither arcane nor complex and have been more-or-less standardized by earlier researchers. In South Carolina, isotopic evidence has been used from both calcareous and siliceous sedimentary aquifers and fractured crystalline rock aquifers. The Tertiary limestone aquifer is shown not to be principally recharged in its subcrop area, unlike conditions assumed for many other sedimentary aquifers in southeastern United States, and instead receives considerable lateral recharge from interfingering updip Tertiary sand aquifers in the middle coastal plain. Induced recharging at Hilton Head Island is mixing ancient relict water and modern recharge water. Recharging to deeper portions of the Cretaceous Middendorf basal sand aquifer occurs at least as far coastward as the middle coastal plain, near sampling sites that stratigraphically appear to be confined. Pronounced mineralization of water in fractured rocks cannot be considered as evidence of ancient or relict ground water that is isolated from modern contaminants, some of these waters contain considerable radiocarbon and hydrogen-bomb tritium

Surface and sub-surface thermal oxidation of ruthenium thin films

NARCIS (Netherlands)

Coloma Ribera, R.; van de Kruijs, Robbert Wilhelmus Elisabeth; Zoethout, E.; Yakshin, Andrey; Bijkerk, Frederik

2014-01-01

For next generation Extreme UV photolithography, multilayer coatings may require protective capping layers against surface contamination. Ruthenium, as a low-oxidation metal, is often used as a reference material. The oxidation behaviour of Ru thin films has been studied using X-ray reflectometry

Modelling contaminant transport in saturated aquifers

International Nuclear Information System (INIS)

Lakshminarayana, V.; Nayak, T.R.

1990-01-01

With the increase in population and industrialization the problem of pollution of groundwater has become critical. The present study deals with modelling of pollutant transport through saturated aquifers. Using this model it is possible to predict the concentration distribution, spatial as well as temporal, in the aquifer. The paper also deals with one of the methods of controlling the pollutant movement, namely by pumping wells. A simulation model is developed to determine the number, location and rate of pumping of a number of wells near the source of pollution so that the concentration is within acceptable limits at the point of interest. (Author) (18 refs., 14 figs., tab.)

New Module to Simulate Groundwater-Surface Water Interactions in Small-Scale Alluvial Aquifer System.

Science.gov (United States)

Flores, L.

2017-12-01

Streamflow depletion can occur when groundwater pumping wells lower water table elevations adjacent to a nearby stream. Being able to accurately model the severity of this process is of critical importance in semi-arid regions where groundwater-surface water interactions affect water rights and the sustainability of water resource practices. The finite-difference flow model MODFLOW is currently the standard for estimating groundwater-surface water interactions in many regions in the western United States. However, certain limitations of the model persist when highly-resolved spatial scales are used to represent the stream-aquifer system, e.g. when the size of computational grid cells is much less than the river width. In this study, an external module is developed and linked with MODFLOW that (1) allows for multiple computational grid cells over the width of the river; (2) computes streamflow and stream stage along the length of the river using the one-dimensional (1D) steady (over a stress period) shallow water equations, which allows for more accurate stream stages when normal flow cannot be assumed or a rating curve is not available; and (3) incorporates a process for computing streamflow loss when an unsaturated zone develops under the streambed. Use of the module not only provides highly-resolved estimates of streamflow depletion, but also of streambed hydraulic conductivity. The new module is applied to the stream-aquifer alluvial system along the South Platte River south of Denver, Colorado, with results tested against field-measured groundwater levels, streamflow, and streamflow depletion.

Duplex sonography of the near-surface leg veins; Duplexsonographie der oberflaechlichen Beinvenen

Energy Technology Data Exchange (ETDEWEB)

Mendoza, E.

2007-07-01

The book contains the following contributions: The ultrasonograph, selection of the ultrasonic transducer, anatomy of the near-surface vein system, physiology of the near-surface vein system, varicose status classification, systematics of the duplex sonography of near-surface leg veins, provocational maneuver for the duplex sonographic varicose diagnostics, exploration of vena saphena parva, perforans veins, side branches, phlebitis, sonography for varicose therapy, postsurgical sonography, deep leg veins, examination of near-surface leg veins for the pathology of the deep vein system, differential diagnostic clarification of leg oedema from the phlebologic-lymphological view, diagnostic side features along the near-surface leg veins.

Understanding Uranium Behavior in a Reduced Aquifer

Science.gov (United States)

Janot, N.; Lezama-Pacheco, J. S.; Williams, K. H.; Bernier-Latmani, R.; Long, P. E.; Davis, J. A.; Fox, P. M.; Yang, L.; Giammar, D.; Cerrato, J. M.; Bargar, J.

2012-12-01

Uranium contamination of groundwater is a concern at several US Department of Energy sites, such Old Rifle, CO. Uranium transport in the environment is mainly controlled by its oxidation state, since oxidized U(VI) is relatively mobile, whereas U(IV) is relatively insoluble. Bio-remediation of contaminated aquifers aims at immobilizing uranium in a reduced form. Previous laboratory and field studies have shown that adding electron donor (lactate, acetate, ethanol) to groundwater stimulates the activity of metal- and sulfate-reducing bacteria, which promotes U(VI) reduction in contaminated aquifers. However, obtaining information on chemical and physical forms of U, Fe and S species for sediments biostimulated in the field, as well as kinetic parameters such as U(VI) reduction rate, is challenging due to the low concentration of uranium in the aquifers (typically bio-remediation experiment at the Old Rifle site, CO, from early iron-reducing conditions to the transition to sulfate-reducing conditions. Several in-well chromatographic columns packed with sediment were deployed and were sampled at different days after the start of bio-reduction. X-ray absorption spectroscopy and X-ray microscopy were used to obtain information on Fe, S and U speciation and distribution. Chemical extractions of the reduced sediments have also been performed, to determine the rate of Fe(II) and U(IV) accumulation.

Investigation of the near-surface electronic structure of Cr(001)

International Nuclear Information System (INIS)

Klebanoff, L.E.; Robey, S.W.; Liu, G.; Shirley, D.A.

1985-01-01

An angle-resolved photoelectron spectroscopy (ARPES) study of Cr(001) near-surface electronic structure is presented. Measurements are reported for energy-band dispersions along the [010] direction parallel to the crystal surface. The periodicity of these band dispersions indicates that the valence electrons experience and self-consistently establish antiferromagnetism in the near-surface layers of Cr(001). We also present highly-surface-sensitive ARPES measurements of the energy-band dispersions along the [001] direction normal to the surface. The results suggest that the surface magnetic moments, which couple ferromagnetically to each other within the surface layer, couple antiferromagnetically to the moments of the atoms in the second layer. Temperature-dependent studies are presented that reveal the persistence of near-surface antiferromagnetic order for temperatures up to 2.5 times the bulk Neel temperature. The temperature dependence of this antiferromagnetic order suggests that its thermal stability derives in part from the stability of the Cr(001) ferromagnetic surface phase

Polarization-Insensitive Surface Plasmon Polarization Electro-Absorption Modulator Based on Epsilon-Near-Zero Indium Tin Oxide

Science.gov (United States)

Jin, Lin; Wen, Long; Liang, Li; Chen, Qin; Sun, Yunfei

2018-02-01

CMOS-compatible plasmonic modulators operating at the telecom wavelength are significant for a variety of on-chip applications. Relying on the manipulation of the transverse magnetic (TM) mode excited on the metal-dielectric interface, most of the previous demonstrations are designed to response only for specific polarization state. In this case, it will lead to a high polarization dependent loss, when the polarization-sensitive modulator integrates to a fiber with random polarization state. Herein, we propose a plasmonic modulator utilizing a metal-oxide indium tin oxide (ITO) wrapped around the silicon waveguide and investigate its optical modulation ability for both the vertical and horizontal polarized guiding light by tuning electro-absorption of ITO with the field-induced carrier injection. The electrically biased modulator with electron accumulated at the ITO/oxide interface allows for epsilon-near-zero (ENZ) mode to be excited at the top or lateral portion of the interface depending on the polarization state of the guiding light. Because of the high localized feature of ENZ mode, efficient electro-absorption can be achieved under the "OFF" state of the device, thus leading to large extinction ratio (ER) for both polarizations in our proposed modulator. Further, the polarization-insensitive modulation is realized by properly tailoring the thickness of oxide in two different stacking directions and therefore matching the ER values for device operating at vertical and horizontal polarized modes. For the optimized geometry configuration, the difference between the ER values of two polarization modes, i.e., the ΔER, as small as 0.01 dB/μm is demonstrated and, simultaneously with coupling efficiency above 74%, is obtained for both polarizations at a wavelength of 1.55 μm. The proposed plasmonic-combined modulator has a potential application in guiding and processing of light from a fiber with a random polarization state.

Near-ground cooling efficacies of trees and high-albedo surfaces

Energy Technology Data Exchange (ETDEWEB)

Levinson, Ronnen M. [Univ. of California, Berkeley, CA (United States). Dept. of Mechanical Engineering

1997-05-01

Daytime summer urban heat islands arise when the prevalence of dark-colored surfaces and lack of vegetation make a city warmer than neighboring countryside. Two frequently-proposed summer heat island mitigation measures are to plant trees and to increase the albedo (solar reflectivity) of ground surfaces. This dissertation examines the effects of these measures on the surface temperature of an object near the ground, and on solar heating of air near the ground. Near-ground objects include people, vehicles, and buildings. The variation of the surface temperature of a near-ground object with ground albedo indicates that a rise in ground albedo will cool a near-ground object only if the object`s albedo exceeds a critical value. This critical value of object albedo depends on wind speed, object geometry, and the height of the atmospheric thermal boundary layer. It ranges from 0.15 to 0.37 for a person. If an object has typical albedo of 0.3, increasing the ground albedo by.

Protists from a sewage‐contaminated aquifer on cape cod, Massachusetts

Science.gov (United States)

Novarino, Gianfranco; Warren, Alan; Kinner, Nancy E.; Harvey, Ronald W.

1994-01-01

Several species of flagellates (genera Bodo, Cercomonas, Cryptaulax, Cyathomonas, Goniomonas, Spumella) have been identified in cultures from a plume of organic contamination (treated sewage effluent) within an aquifer on Cape Cod, Massachusetts. Amoebae and numerous unidentifiable 2‐ to 3‐μm flagellates have also been observed. As a rule, flagellates were associated with solid surfaces, or were capable of temporary surface attachment, corroborating earlier observations from in situ and column transport experiments suggesting that protists in the Massachusetts aquifer have a high propensity for association with sediment grain surfaces. Based on the fact that cultures from the uncontaminated part of the aquifer yielded only a few species of protists, it is hypothesized that the greater abundance and variety of food sources in the contaminant plume is capable of supporting a greater number of protistan species.

Hydro-geological properties of the Savian aquifer in the county Obrenovac

Directory of Open Access Journals (Sweden)

Stojadinović Dušan D.

2005-01-01

Full Text Available The paper presents a description of hydrogeological researches of alluvial layers of the Sava River in the area of the source "Vić Bare" near Obrenovac. This source supplies groundwater to that town. The depth of these layers amounts to 25 m. With regard to collecting capacity, the most significant are gravel-sand sediments of high filtration properties. Their average depth amounts to about 13 m with the underlying layer made of Pleistocene clays. Compact aquifer is formed within these sediments and it refills partly from the Sava River at places where river cuts its channel into the gravel-sand layer. The analysis of the groundwater regime in the riparian area points out that groundwater levels follow stages of the Sava River. Such an influence lessens with the distance. Established hydraulic connection between the river and the aquifer enables its permanent replenishment. On the other hand, due to certain pollutions this river flow might bring along, it represents a potential danger. Those pollutions could enter water-bearing layer of the aquifer as well as the exploitation well of the source. Such presumptions have been confirmed in the experiment of pollution transport carried out in the water-bearing layer. Unabsorbable chloride was used as a tracer whose movement velocity through exploitation well proved that there were real possibilities of intrusion of aggressive pollutants into the water-bearing layer and into the aquifer as well. Therefore, the protection of the source must be in the function of the protection of surface waters.

Secondary electron emission influenced by oxidation on the aluminum surface: the roles of the chemisorbed oxygen and the oxide layer

Science.gov (United States)

Li, Jiangtao; Hoekstra, Bart; Wang, Zhen-Bin; Qiu, Jie; Pu, Yi-Kang

2018-04-01

A relationship between the apparent secondary electron yield ({γ }{{se}}) and the oxygen coverage/oxide layer thickness on an aluminum cathode is obtained in an experiment under a controlled environment. The apparent secondary electron yield ({γ }{{se}}) is deduced from the breakdown voltage between two parallel plate electrodes in a 360 mTorr argon environment using a simple Townsend breakdown model with the assumption that the variation of the apparent secondary electron yield is dominated by the variation of the argon ion induced processes. The oxygen coverage/oxide layer thickness on the aluminum cathode is measured by a semi in situ x-ray photoemission spectroscopy equipment which is directly attached to the discharge chamber. It is found that three phases exist: (1) in the monomonolayer regime, as the oxygen coverage increases from 0 to 0.3, {γ }{{se}} decreases by nearly 40 % , (2) as the oxygen coverage increases from 0.3 to 1, {γ }{{se}} keeps nearly constant, (3) as the oxide layer thickness increases from about 0.3 nm to about 1.1 nm, {γ }{{se}} increases by 150 % . We propose that, in the submonolayer regime, the chemisorbed oxygen on the aluminum surface causes the decrease of {γ }{{se}} by creating a local potential barrier, which reduces the Auger neutralization rate and the energy gained by the Auger electrons. In the multilayer regime, as the oxide layer grows in thickness, there are three proposed mechanisms which cause the increase of {γ }{{se}}: (1) the work function decreases; (2) resonance neutralization and Auger de-excitation may exist. This is served as another channel for secondary electron production; (3) the kinetic energy of Auger electrons is increased on average, leading to a higher probability for electrons to overcome the surface potential barrier.

The growth and evolution of thin oxide films on delta-plutonium surfaces

Energy Technology Data Exchange (ETDEWEB)

Garcia Flores, Harry G [Los Alamos National Laboratory; Pugmire, David L [Los Alamos National Laboratory

2009-01-01

The common oxides of plutonium are the dioxide (PuO{sub 2}) and the sesquioxide (Pu{sub 2}O{sub 3}). The structure of an oxide on plutonium metal under air at room temperature is typically described as a thick PuO{sub 2} film at the gas-oxide interface with a thinner PuO{sub 2} film near the oxide-metal substrate interface. In a reducing environment, such as ultra high vacuum, the dioxide (Pu{sup 4+}; O/Pu = 2.0) readily converts to the sesquioxide (Pu{sup 3+}; O/Pu = 1.5) with time. In this work, the growth and evolution of thin plutonium oxide films is studied with x-ray photoelectron spectroscopy (XPS) under varying conditions. The results indicate that, like the dioxide, the sesquioxide is not stable on a very clean metal substrate under reducing conditions, resulting in substoichiometric films (Pu{sub 2}O{sub 3-y}). The Pu{sub 2}O{sub 3-y} films prepared exhibit a variety of stoichiometries (y = 0.2-1) as a function of preparation conditions, highlighting the fact that caution must be exercised when studying plutonium oxide surfaces under these conditions and interpreting resulting data.

Near Surface Stoichiometry in UO2: A Density Functional Theory Study

Directory of Open Access Journals (Sweden)

Jianguo Yu

2015-01-01

Full Text Available The mechanisms of oxygen stoichiometry variation in UO2 at different temperature and oxygen partial pressure are important for understanding the dynamics of microstructure in these crystals. However, very limited experimental studies have been performed to understand the atomic structure of UO2 near surface and defect effects of near surface on stoichiometry in which the system can exchange atoms with the external reservoir. In this study, the near (110 surface relaxation and stoichiometry in UO2 have been studied with density functional theory (DFT calculations. On the basis of the point-defect model (PDM, a general expression for the near surface stoichiometric variation is derived by using DFT total-energy calculations and atomistic thermodynamics, in an attempt to pin down the mechanisms of oxygen exchange between the gas environment and defected UO2. By using the derived expression, it is observed that, under poor oxygen conditions, the stoichiometry of near surface is switched from hyperstoichiometric at 300 K with a depth around 3 nm to near-stoichiometric at 1000 K and hypostoichiometric at 2000 K. Furthermore, at very poor oxygen concentrations and high temperatures, our results also suggest that the bulk of the UO2 prefers to be hypostoichiometric, although the surface is near-stoichiometric.

Prediction of iodide adsorption on oxides by surface complexation modeling with spectroscopic confirmation.

Science.gov (United States)

Nagata, Takahiro; Fukushi, Keisuke; Takahashi, Yoshio

2009-04-15

A deficiency in environmental iodine can cause a number of health problems. Understanding how iodine is sequestered by materials is helpful for evaluating and developing methods for minimizing human health effects related to iodine. In addition, (129)I is considered to be strategically important for safety assessment of underground radioactive waste disposal. To assess the long-term stability of disposed radioactive waste, an understanding of (129)I adsorption on geologic materials is essential. Therefore, the adsorption of I(-) on naturally occurring oxides is of environmental concern. The surface charges of hydrous ferric oxide (HFO) in NaI electrolyte solutions were measured by potentiometric acid-base titration. The surface charge data were analyzed by means of an extended triple-layer model (ETLM) for surface complexation modeling to obtain the I(-) adsorption reaction and its equilibrium constant. The adsorption of I(-) was determined to be an outer-sphere process from ETLM analysis, which was consistent with independent X-ray absorption near-edge structure (XANES) observation of I(-) adsorbed on HFO. The adsorption equilibrium constants for I(-) on beta-TiO(2) and gamma-Al(2)O(3) were also evaluated by analyzing the surface charge data of these oxides in NaI solution as reported in the literature. Comparison of these adsorption equilibrium constants for HFO, beta-TiO(2), and gamma-Al(2)O(3) based on site-occupancy standard states permitted prediction of I(-) adsorption equilibrium constants for all oxides by means of the Born solvation theory. The batch adsorption data for I(-) on HFO and amorphous aluminum oxide were reasonably reproduced by ETLM with the predicted equilibrium constants, confirming the validity of the present approach. Using the predicted adsorption equilibrium constants, we calculated distribution coefficient (K(d)) values for I(-) adsorption on common soil minerals as a function of pH and ionic strength.

The Importance of Microbial Iron Sulfide Oxidation for Nitrate Depletion in Anoxic Danish Sediments

DEFF Research Database (Denmark)

Vaclavkova, Sarka; Jacobsen, Ole Stig; Jørgensen, Christian Juncher

2014-01-01

of organic carbon in the sediment. An apparent salinity limitation to MISON was observed in the most brackish environment. Addition of high surface area synthetically precipitated iron sulfide (FeS x ) to the aquifer sediment with the lowest natural FeS x reactivity increased both the relative fraction of NO......Nitrate (NO3 −) reduction processes are important for depleting the NO3 − load from agricultural source areas before the discharge water reaches surface waters or groundwater aquifers. In this study, we experimentally demonstrate the co-occurrence of microbial iron sulfide oxidation by NO3 − (MISON......) and other NO3 −-depleting processes in a range of contrasting sediment types: sandy groundwater aquifer, non-managed minerotrophic freshwater peat and two brackish muddy sediments. Approximately 1/3 of the net NO3 − reduction was caused by MISON in three of the four environments despite the presence...

Decontamination of U-metal surface by an oxidation etching system

Energy Technology Data Exchange (ETDEWEB)

Stout, R.B.; Kansa, E.J.; Shaffer, R.J.; Weed, H.C. [California Univ., Livermore, CA (United States). Lawrence Livermore National Lab

2001-07-01

A surface treatment to remove surface contamination from uranium (U) metal and/or hydrides of uranium and heavy metals (HM) from U-metal parts is described. In the case of heavy metal atomic contamination on a surface, and potentially several atomic layers beneath, the surface oxidation treatment combines both chemical and chemically driven mechanical processes. The chemical process is a controlled temperature-time oxidation process to create a thin film of uranium oxide (UO{sub 2} and higher oxides) on the U-metal surface. The chemically driven mechanical process is strain induced by the volume increase as the U-metal surface transforms to a UO{sub 2} surface film. These volume strains are significantly large to cause surface failure spalling/scale formation and thus, removal of a U-oxide film that contains the HM-contaminated surface. The case of a HM-hydride surface contamination layer can be treated similarly by using inert hot gas to decompose the U-hydrides and/or HM-hydrides that are contiguous with the surface. A preliminary analysis to design and to plan for a sequence of tests is developed. The tests will provide necessary and sufficient data to evaluate the effective implementation and operational characteristics of a safe and reliable system. The following description is limited to only a surface oxidation process for HM-decontamination. (authors)

Photopatterning of self assembled monolayers on oxide surfaces for the selective attachment of biomolecules.

Science.gov (United States)

Hazarika, Pompi; Behrendt, Jonathan M; Petersson, Linn; Wingren, Christer; Turner, Michael L

2014-03-15

The immobilization of functional biomolecules to surfaces is a critical process for the development of biosensors for disease diagnostics. In this work we report the patterned attachment of single chain fragment variable (scFv) antibodies to the surface of metal oxides by the photodeprotection of self-assembled monolayers, using near-UV light. The photodeprotection step alters the functionality at the surface; revealing amino groups that are utilized to bind biomolecules in the exposed regions of the substrate only. The patterned antibodies are used for the detection of specific disease biomarker proteins in buffer and in complex samples such as human serum. © 2013 Elsevier B.V. All rights reserved.

Acid groundwater in an anoxic aquifer: Reactive transport modelling of buffering processes

International Nuclear Information System (INIS)

Franken, Gudrun; Postma, Dieke; Duijnisveld, Wilhelmus H.M.; Boettcher, Juergen; Molson, John

2009-01-01

The acidification of groundwater, due to acid rain, was investigated in a Quaternary sandy aquifer in the Fuhrberger Feld, near Hannover, Germany. The groundwater, recharged through an area covered by a coniferous forest, had a pH in the range 4-5 down to a depth of 5 m. The evolution in groundwater chemistry along the flow path was investigated in a transect of multisamplers. A 2D groundwater flow model was established delineating the groundwater flow field and a groundwater flow velocity of around 80 m/a along the flow path was derived. Speciation calculations showed the groundwater to be close to equilibrium with the mineral jurbanite (AlOHSO 4 ) over the pH range 4.0-6.5. This suggests an accumulation of acid rain derived SO 4 2- in the aquifer sediment during the decades with high atmospheric S deposition. The groundwater has a pH of around 4.5 in the upstream part of the flow path increasing to near 6 further downstream. 1D reactive transport modelling, using PHREEQC, was used to analyze different combinations of buffering processes. The first model contains ion exchange in combination with jurbanite dissolution. At the ion exchange front Al 3+ is adsorbed leading to the dissolution of jurbanite and an increase in pH. Comparison with field data showed that the simulated increases in pH and alkalinity are much lower than observed in the field. The second model includes organic matter degradation. In addition to ion exchange and jurbanite dissolution, the model included the reduction of SO 4 2- and Fe-oxides as well as the precipitation of Fe sulfide. This model matches the field data well and illustrates the importance of redox processes for pH buffering in the Fuhrberg aquifer. The current progress of the acidification front is about 4 m/a. This corresponds to an average value of 150 a of acid input, which covers large historical variations. Remediation is expected to take the same time span because it requires desorption and neutralization of adsorbed Al 3

Hydrogeology and ground-water flow of the drift and Platteville aquifer system, St Louis Park, Minnesota

Science.gov (United States)

Lindgren, R.J.

1995-01-01

Three aquifers and two confining units have been delineated within the drift underlying the area near the site of a former coal-tar distillation and wood-preserving plant in St. Louis Park, Minnesota. The hydrogeologic units of the drift, in descending order, are the upper drift aquifer, the upper drift confining unit, the middle drift aquifer, the lower drift confining unit. and the lower drift aquifer. A contamination plume consisting of coal-tar derivatives exists in the drift aquifers and in the Platteville aquifer underlying the southern part of the plant site and areas to the south and east of the plant site.

Spectroscopy and control of near-surface defects in conductive thin film ZnO

KAUST Repository

Kelly, Leah L; Racke, David A; Schulz, Philip; Li, Hong; Winget, Paul; Kim, Hyungchul; Ndione, Paul; Sigdel, Ajaya K; Bredas, Jean-Luc; Berry, Joseph J; Graham, Samuel; Monti, Oliver L A

2016-01-01

The electronic structure of inorganic semiconductor interfaces functionalized with extended π-conjugated organic molecules can be strongly influenced by localized gap states or point defects, often present at low concentrations and hard to identify spectroscopically. At the same time, in transparent conductive oxides such as ZnO, the presence of these gap states conveys the desirable high conductivity necessary for function as electron-selective interlayer or electron collection electrode in organic optoelectronic devices. Here, we report on the direct spectroscopic detection of a donor state within the band gap of highly conductive zinc oxide by two-photon photoemission spectroscopy. We show that adsorption of the prototypical organic acceptor C60 quenches this state by ground-state charge transfer, with immediate consequences on the interfacial energy level alignment. Comparison with computational results suggests the identity of the gap state as a near-surface-confined oxygen vacancy.

Spectroscopy and control of near-surface defects in conductive thin film ZnO

KAUST Repository

Kelly, Leah L

2016-02-12

The electronic structure of inorganic semiconductor interfaces functionalized with extended π-conjugated organic molecules can be strongly influenced by localized gap states or point defects, often present at low concentrations and hard to identify spectroscopically. At the same time, in transparent conductive oxides such as ZnO, the presence of these gap states conveys the desirable high conductivity necessary for function as electron-selective interlayer or electron collection electrode in organic optoelectronic devices. Here, we report on the direct spectroscopic detection of a donor state within the band gap of highly conductive zinc oxide by two-photon photoemission spectroscopy. We show that adsorption of the prototypical organic acceptor C60 quenches this state by ground-state charge transfer, with immediate consequences on the interfacial energy level alignment. Comparison with computational results suggests the identity of the gap state as a near-surface-confined oxygen vacancy.

Mapping Greenland's Firn Aquifer using L-band Microwave Radiometry

Science.gov (United States)

Miller, J.; Bringer, A.; Jezek, K. C.; Johnson, J. T.; Scambos, T. A.; Long, D. G.

2016-12-01

Greenland's recently discovered firn aquifer is one of the most interesting, yet still mysterious, components of the ice sheet system. Many open questions remain regarding timescales of refreezing and/or englacial drainage of liquid meltwater, and the connections of firn aquifers to the subglacial hydrological system. If liquid meltwater production at the surface of the Greenland ice sheet continues to increase, subsequent increases in the volume of mobile liquid meltwater retained within Greenland's firn aquifer may increase the possibility of crevasse-deepening via hydrofracture. Hydrofracture is an important component of supraglacial lake drainage leading to at least temporary accelerated flow velocities and ice sheet mass balance changes. Firn aquifers may also support hydrofracture-induced drainage and thus are potentially capable of significantly influencing ice sheet mass balance and sea level rise. Spaceborne L-band microwave radiometers provide an innovative tool for ice-sheet wide mapping of the spatiotemporal variability of Greenland's firn aquifer. Both refreezing and englacial drainage may be observable given the sensitivity of the microwave response to the upper surface of liquid meltwater retained within snow and firn pore space as well as the ability of L band instruments to probe the ice sheet from the surface to the firn-ice transition at pore close-off depth. Here we combine L-band (1.4 GHz) brightness temperature observations from multiple sources to demonstrate the potential of mapping firn aquifers on ice sheets using L-band microwave radiometry. Data sources include the interferometric MIRAS instrument aboard ESA's Soil Moisture and Ocean Salinity (SMOS) satellite mission and the radiometer aboard NASA's Soil Moisture Active Passive (SMAP) satellite mission. We will also present mulit-frequency L-band brightness temperature data (0.5-2 GHz) that will be collected over several firn aquifer areas on the Greenland ice sheet by the Ohio State

Surface morphology study on chromium oxide growth on Cr films by Nd-YAG laser oxidation process

International Nuclear Information System (INIS)

Dong Qizhi; Hu Jiandong; Guo Zuoxing; Lian Jianshe; Chen Jiwei; Chen Bo

2002-01-01

Grain sized (60-100 nm) Cr 2 O 3 thin films were prepared on Cr thin film surfaces by Nd-YAG laser photothermal oxidation process. Surface morphology study showed crack-free short plateau-like oxide films formed. Increase of dislocation density after pulsed laser irradiation was found. Thin film external surfaces, grain boundaries and dislocations are main paths of laser surface oxidation. Pinning and sealing of grain boundary was the reason that deeper oxidation did not produce. Grain growth and agglomeration of Cr sub-layer yielded tensile stress on the surface Cr 2 O 3 thin film. It was the reason that short plateau-like surface morphology formed and cracks appeared sometimes. In oxygen annealing at 700 deg. C, grain boundaries were considered not to be pinned at the surface, mixture diffusion was main mechanism in growth of oxide. Compression stress development in whole film led to extrusion of grains that was the reason that multiple appearances such as pyramid-like and nutshell-like morphology formed

Concentrations and speciation of arsenic along a groundwater flow-path in the Upper Floridan aquifer, Florida, USA

Science.gov (United States)

Haque, S. E.; Johannesson, K. H.

2006-05-01

Arsenic (As) concentrations and speciation were determined in groundwaters along a flow-path in the Upper Floridan aquifer (UFA) to investigate the biogeochemical “evolution“ of As in this relatively pristine aquifer. Dissolved inorganic As species were separated in the field using anion-exchange chromatography and subsequently analyzed by inductively coupled plasma mass spectrometry. Total As concentrations are higher in the recharge area groundwaters compared to down-gradient portions of UFA. Redox conditions vary from relatively oxic to anoxic along the flow-path. Mobilization of As species in UFA groundwaters is influenced by ferric iron reduction and subsequent dissolution, sulfate reduction, and probable pyrite precipitation that are inferred from the data to occur along distinct regions of the flow-path. In general, the distribution of As species are consistent with equilibrium thermodynamics, such that arsenate dominates in more oxidizing waters near the recharge area, and arsenite predominates in the progressively reducing groundwaters beyond the recharge area.

Photoinduced hydrophobic surface of graphene oxide thin films

International Nuclear Information System (INIS)

Zhang Xiaoyan; Song Peng; Cui Xiaoli

2012-01-01

Graphene oxide (GO) thin films were deposited on transparent conducting oxide substrates and glass slides by spin coating method at room temperature. The wettability of GO thin films before and after ultraviolet (UV) irradiation was characterized with water contact angles, which increased from 27.3° to 57.6° after 3 h of irradiation, indicating a photo-induced hydrophobic surface. The UV–vis absorption spectra, Raman spectroscopy, X-ray photoelectron spectroscopy, and conductivity measurements of GO films before and after UV irradiation were taken to study the mechanism of photoinduced hydrophobic surface of GO thin films. It is demonstrated that the photoinduced hydrophobic surface is ascribed to the elimination of oxygen-containing functional groups on GO molecules. This work provides a simple strategy to control the wettability properties of GO thin films by UV irradiation. - Highlights: ► Photoinduced hydrophobic surface of graphene oxide thin films has been demonstrated. ► Elimination of oxygen-containing functional groups in graphene oxide achieved by UV irradiation. ► We provide novel strategy to control surface wettability of GO thin films by UV irradiation.

Isotopic and microbiological signatures of pyrite-driven denitrification in a sandy aquifer

NARCIS (Netherlands)

Zhang, Y.-C.; Slomp, C.P.; Broers, H.P.; Bostick, B.; Passier, H.F.; Böttcher, M.E.; Omoregie, E.O.; Lloyd, J.R.; Polya, D.A.; Van Cappellen, P.

2012-01-01

Denitrificationdriven by pyrite oxidation can play a major role in the removal of nitrate from groundwater systems. As yet, limited information is available on the interactions between the micro-organisms and aqueous and mineral phases in aquifers where pyrite oxidation is occurring. In this study,

Joint TEM and MT aquifer study in the Atacama Desert, North Chile

Science.gov (United States)

Ruthsatz, Alexander D.; Sarmiento Flores, Alvaro; Diaz, Daniel; Reinoso, Pablo Salazar; Herrera, Cristian; Brasse, Heinrich

2018-06-01

The Atacama Desert represents one of the driest regions on earth, and despite the absence of sustainable clean water reserves the demand has increased drastically since 1970 as a result of growing population and expanding mining activities. Magnetotelluric (MT) and Transient Electromagnetic (TEM) measurements were carried out for groundwater exploration in late 2015 in the area of the Profeta Basin at the western margin of the Chilean Precordillera. Both methods complement each other: While MT in general attains larger penetration depths, TEM allows better resolution of near surface layers; furthermore TEM is free from galvanic distortion. Data were collected along three profiles, enabling a continuous resistivity image from the surface to at least several hundred meters depth. TEM data were inverted in a 1-D manner, consistently yielding a poorly conductive near-surface layer with a thickness of approximately 30 m and below a well-conducting layer which we interpret as the aquifer with resistivities around 10 Ωm. At marginal sites of the main SW-NE-profile the resistive basement was found in 150 m. These depths are confirmed by interpretation of the MT soundings. Those were firstly inverted with a 2-D approach and then by 3-D inversion as clear indications of three-dimensionality exist. Several modeling runs were performed with different combinations of transfer functions and smoothing parameters. Generally, MT and TEM results agree reasonably well and an overall image of the resistivity structures in the Profeta Basin could be achieved. The aquifer reaches depths of more than 500 m in parts and, by applying Archie's law, resistivities of 1 Ωm can be assumed, indicating highly saline fluids from the source region of the surrounding high Andes under persisting arid conditions.

Comparison of dissolved and particulate arsenic distributions in shallow aquifers of Chakdaha, India, and Araihazar, Bangladesh

Directory of Open Access Journals (Sweden)

Ahmed Kazi M

2008-01-01

Full Text Available Abstract Background The origin of the spatial variability of dissolved As concentrations in shallow aquifers of the Bengal Basin remains poorly understood. To address this, we compare here transects of simultaneously-collected groundwater and aquifer solids perpendicular to the banks of the Hooghly River in Chakdaha, India, and the Old Brahmaputra River in Araihazar, Bangladesh. Results Variations in surface geomorphology mapped by electromagnetic conductivity indicate that permeable sandy soils are associated with underlying aquifers that are moderately reducing to a depth of 10–30 m, as indicated by acid-leachable Fe(II/Fe ratios 5 mg L-1. More reducing aquifers are typically capped with finer-grained soils. The patterns suggest that vertical recharge through permeable soils is associated with a flux of oxidants on the banks of the Hooghly River and, further inland, in both Chakdaha and Araihazar. Moderately reducing conditions maintained by local recharge are generally associated with low As concentrations in Araihazar, but not systematically so in Chakdaha. Unlike Araihazar, there is also little correspondence in Chakdaha between dissolved As concentrations in groundwater and the P-extractable As content of aquifer particles, averaging 191 ± 122 ug As/L, 1.1 ± 1.5 mg As kg-1 (n = 43 and 108 ± 31 ug As/L, 3.1 ± 6.5 mg As kg-1 (n = 60, respectively. We tentatively attribute these differences to a combination of younger floodplain sediments, and therefore possibly more than one mechanism of As release, as well as less reducing conditions in Chakdaha compared to Araihazar. Conclusion Systematic dating of groundwater and sediment, combined with detailed mapping of the composition of aquifer solids and groundwater, will be needed to identify the various mechanisms underlying the complex distribution of As in aquifers of the Bengal Basin.

Geohydrology and water quality of the North Platte River alluvial aquifer, Garden County, Western Nebraska

Science.gov (United States)

Steele, Gregory V.; Cannia, James C.

1995-01-01

In 1993, a 3-year study was begun to describe the geohydrology and water quality of the North Platte River alluvial aquifer near Oshkosh, Garden County, Nebraska. The study's objectives are to evaluate the geohydrologic characteristics of the alluvial aquifer and to establish a network of observation wells for long-term monitoring of temporal variations and spatial distributions of nitrate and major-ion concentrations. Monitor wells were installed at 11 sites near Oshkosh. The geohydrology of the aquifer was characterized based on water-level measurements and two short-term aquifer tests. Bimonthly water samples were collected and analyzed for pH, specific conductivity, water temperature, dissolved oxygen, and nutrients that included dissolved nitrate. Concentrations of major ions were defined from analyses of semiannual water samples. Analyses of the geohydrologic and water-quality data indicate that the aquifer is vulnerable to nitrate contamination. These data also show that nitrate concentrations in ground water flowing into and out of the study area are less than the U.S. Environmental Protection Agency's Maximum Concentration Level of 10 milligrams per liter for drinking water. Ground water from Lost Creek Valley may be mixing with ground water in the North Platte River Valley, somewhat moderating nitrate concentrations near Oshkosh.

Estimating Poromechanical and Hydraulic Properties of Fractured Media Aquifers Using a Model of the Aquifer at Ploemeur France: Broad Applications and Future Uses

Science.gov (United States)

Wilson, M. W.; Burbey, T. J.

2017-12-01

Aquifers in fractured crystalline bedrock are located over half of the earth's surface and are vital civil and economic resources particularly in places where ample, safe surface water is not available. With fractured media aquifers providing large percentages of water for municipal, industrial, and agricultural use in many regions of the world. Distinguishing sustainable quantities of extraction is of paramount importance to the continuing viability of these important resources and the communities they serve. The fractured and faulted crystalline-rock aquifer system supporting the community of Ploemeur France has been providing one million cubic meters of water annually, resulting in a modest long-term drawdown of about 15m. To understand the sources and mechanisms of recharge that support this aquifer system, a three-dimensional ABAQUS model was developed using known geologic, water-level and geodetic (tiltmeters and GPS) data to simulate the natural aquifer system that is dominated by a permeable sub-vertical fault and an intersecting semi-horizontal contact zone. The model is used to constrain the poromechanical properties of the fault and contact zones relative to the host crystalline rocks and overlying saprolite by taking advantage of the tilt and seasonal GPS responses caused by municipal pumping along with water-level data for the area. A chief goal in this modeling effort is to assess the sources of recharge to this aquifer system that is atypically productive for a crystalline-rock setting. Preliminary results suggest that the source of water supplying this community is a combination of rapid localized recharge through the saprolite and fault zone and recharge along the contact zone, both from the north (older water) and where it is exposed to the south (younger water). The modeling effort also shows the importance of combining GPS and surface tiltmeter data with water-level measurements for constraining the properties of this complex aquifer system and

Superresolution Near-field Imaging with Surface Waves

KAUST Repository

Fu, Lei

2017-10-21

We present the theory for near-field superresolution imaging with surface waves and time reverse mirrors (TRMs). Theoretical formulas and numerical results show that applying the TRM operation to surface waves in an elastic half-space can achieve superresolution imaging of subwavelength scatterers if they are located less than about 1/2 of the shear wavelength from the source line. We also show that the TRM operation for a single frequency is equivalent to natural migration, which uses the recorded data to approximate the Green’s functions for migration, and only costs O(N4) algebraic operations for poststack migration compared to O(N6) operations for natural prestack migration. Here, we assume the sources and receivers are on an N × N grid and there are N2 trial image points on the free surface. Our theoretical predictions of superresolution are validated with tests on synthetic data. The field-data tests suggest that hidden faults at the near surface can be detected with subwavelength imaging of surface waves by using the TRM operation if they are no deeper than about 1/2 the dominant shear wavelength.

Delineating sources of groundwater recharge in an arsenic-affected Holocene aquifer in Cambodia using stable isotope-based mixing models

Science.gov (United States)

Richards, Laura A.; Magnone, Daniel; Boyce, Adrian J.; Casanueva-Marenco, Maria J.; van Dongen, Bart E.; Ballentine, Christopher J.; Polya, David A.

2018-02-01

Chronic exposure to arsenic (As) through the consumption of contaminated groundwaters is a major threat to public health in South and Southeast Asia. The source of As-affected groundwaters is important to the fundamental understanding of the controls on As mobilization and subsequent transport throughout shallow aquifers. Using the stable isotopes of hydrogen and oxygen, the source of groundwater and the interactions between various water bodies were investigated in Cambodia's Kandal Province, an area which is heavily affected by As and typical of many circum-Himalayan shallow aquifers. Two-point mixing models based on δD and δ18O allowed the relative extent of evaporation of groundwater sources to be estimated and allowed various water bodies to be broadly distinguished within the aquifer system. Model limitations are discussed, including the spatial and temporal variation in end member compositions. The conservative tracer Cl/Br is used to further discriminate between groundwater bodies. The stable isotopic signatures of groundwaters containing high As and/or high dissolved organic carbon plot both near the local meteoric water line and near more evaporative lines. The varying degrees of evaporation of high As groundwater sources are indicative of differing recharge contributions (and thus indirectly inferred associated organic matter contributions). The presence of high As groundwaters with recharge derived from both local precipitation and relatively evaporated surface water sources, such as ponds or flooded wetlands, are consistent with (but do not provide direct evidence for) models of a potential dual role of surface-derived and sedimentary organic matter in As mobilization.

Redox Conditions in Selected Principal Aquifers of the United States

Science.gov (United States)

McMahon, P.B.; Cowdery, T.K.; Chapelle, F.H.; Jurgens, B.C.

2009-01-01

Reduction/oxidation (redox) processes affect the quality of groundwater in all aquifer systems. Redox processes can alternately mobilize or immobilize potentially toxic metals associated with naturally occurring aquifer materials, contribute to the degradation or preservation of anthropogenic contami-nants, and generate undesirable byproducts, such as dissolved manganese (Mn2+), ferrous iron (Fe2+), hydrogen sulfide (H2S), and methane (CH4). Determining the kinds of redox processes that occur in an aquifer system, documenting their spatial distribution, and understanding how they affect concentrations of natural or anthropogenic contaminants are central to assessing and predicting the chemical quality of groundwater. This Fact Sheet extends the analysis of U.S. Geological Survey authors to additional principal aquifer systems by applying a framework developed by the USGS to a larger set of water-quality data from the USGS national water databases. For a detailed explanation, see the 'Introduction' in the Fact Sheet.

Trench infiltration for managed aquifer recharge to permeable bedrock

Science.gov (United States)

Heilweil, V.M.; Watt, D.E.

2011-01-01

Managed aquifer recharge to permeable bedrock is increasingly being utilized to enhance resources and maintain sustainable groundwater development practices. One such target is the Navajo Sandstone, an extensive regional aquifer located throughout the Colorado Plateau of the western United States. Spreading-basin and bank-filtration projects along the sandstone outcrop's western edge in southwestern Utah have recently been implemented to meet growth-related water demands. This paper reports on a new cost-effective surface-infiltration technique utilizing trenches for enhancing managed aquifer recharge to permeable bedrock. A 48-day infiltration trench experiment on outcropping Navajo Sandstone was conducted to evaluate this alternative surface-spreading artificial recharge method. Final infiltration rates through the bottom of the trench were about 0.5 m/day. These infiltration rates were an order of magnitude higher than rates from a previous surface-spreading experiment at the same site. The higher rates were likely caused by a combination of factors including the removal of lower permeability soil and surficial caliche deposits, access to open vertical sandstone fractures, a reduction in physical clogging associated with silt and biofilm layers, minimizing viscosity effects by maintaining isothermal conditions, minimizing chemical clogging caused by carbonate mineral precipitation associated with algal photosynthesis, and diminished gas clogging associated with trapped air and biogenic gases. This pilot study illustrates the viability of trench infiltration for enhancing surface spreading of managed aquifer recharge to permeable bedrock. ?? 2010.

Bacterial community and groundwater quality changes in an anaerobic aquifer during groundwater recharge with aerobic recycled water.

Science.gov (United States)

Ginige, Maneesha P; Kaksonen, Anna H; Morris, Christina; Shackelton, Mark; Patterson, Bradley M

2013-09-01

Managed aquifer recharge offers the opportunity to manage groundwater resources by storing water in aquifers when in surplus and thus increase the amount of groundwater available for abstraction during high demand. The Water Corporation of Western Australia (WA) is undertaking a Groundwater Replenishment Trial to evaluate the effects of recharging aerobic recycled water (secondary treated wastewater subjected to ultrafiltration, reverse osmosis, and ultraviolet disinfection) into the anaerobic Leederville aquifer in Perth, WA. Using culture-independent methods, this study showed the presence of Actinobacteria, Alphaproteobacteria, Bacilli, Betaproteobacteria, Cytophaga, Flavobacteria, Gammaproteobacteria, and Sphingobacteria, and a decrease in microbial diversity with an increase in depth of aquifer. Assessment of physico-chemical and microbiological properties of groundwater before and after recharge revealed that recharging the aquifer with aerobic recycled water resulted in elevated redox potentials in the aquifer and increased bacterial numbers, but reduced microbial diversity. The increase in bacterial numbers and reduced microbial diversity in groundwater could be a reflection of an increased denitrifier and sulfur-oxidizing populations in the aquifer, as a result of the increased availability of nitrate, oxygen, and residual organic matter. This is consistent with the geochemical data that showed pyrite oxidation and denitrification within the aquifer after recycled water recharge commenced. © 2013 Federation of European Microbiological Societies. Published by John Wiley & Sons Ltd. All rights reserved.

Effect of CO on surface oxidation of uranium metal

International Nuclear Information System (INIS)

Wang, X.; Fu, Y.; Xie, R.

1997-01-01

The surface reactions of uranium metal with carbon monoxide at 25 and 200 deg C have been studied by X-ray photoelectron spectroscopy (XPS);respectively. Adsorption of carbon monoxide on the surface layer of uranium metal leads to partial reduction of surface oxide and results in U4f photoelectron peak shifting to the lower binding energy. The content of oxygen in the surface oxide is decreased and O1s/O4f ratio decreases with increasing the exposure of carbon monoxide. The investigation indicates the surface layer of uranium metal has resistance to further oxidation in the atmosphere of carbon monoxide. (author)

Isotopic study of the Continental Intercalaire aquifer and its relationship with other aquifers of the northern Sahara

International Nuclear Information System (INIS)

Gonfiantini, R.; Sauzay, G.; Payne, B.R.; Conrad, G.; Fontes, J.Ch.

1974-01-01

The Northern Sahara contains several aquifers, the largest of which is that of the Continental Intercalaire formations. In its eastern part the aquifer is confined and presents a very homogeneous isotopic composition. The 14 C activity is low or zero except in the outcrop zones of the north (Saharan Atlas), the east (Dahar) and the south (Tinrhert), all of which are recharge zones. In these areas the isotopic composition does not differ appreciably from that of the old water in the confined part of the aquifer. In the western part, where the reservoir outcrops widely, the 14 C activities show the extent of the local recharge. The heavy isotope content indicates the overflow of the surface aquifer of the western Grand Erg into the Continental Intercalaire over the whole Gourara front. The mixtures thus formed pass under the Tademait and drain towards the Touat. In the resurgence zone of the Gulf of G abes in Tunisia the heavy-isotope content confirms the recharging of the aquifer of the Complex terminal by drainage of water from the Continental Intercalaire through the El-Hamma fault system. The water then runs eastwards, mixing with local contributions. The marine Miocene confined aquifer of Zarzis-Djerba in the Gulf of Gabes receives no contribution from the Continental Intercalaire. The water in the aquifer of the western Grand Erg indicates an evaporation mechanism, probably peculiar to the dune systems, which gives rise to heavy-isotope enrichment compared with the recharge of other types of formations. (author) [fr

Surface Chemistry and Spectroscopy of Chromium in Inorganic Oxides

NARCIS (Netherlands)

Weckhuysen, B.M.; Wachs, I.E.; Schoonheydt, R.A.

1996-01-01

Focuses on the surface chemistry and spectroscopy of chromium in inorganic oxides. Characterization of the molecular structures of chromium; Mechanics of hydrogenation-dehydrogenation reactions; Mobility and reactivity on oxidic surfaces.

Potentiometric-surface altitude of the confined aquifer, Wood River Valley aquifer system, south-central Idaho, October 2012.

Data.gov (United States)

Department of the Interior — Water levels in 93 wells completed in the Wood River Valley aquifer system were measured during October 22–24, 2012; these wells are part of a network established...

Surface functionalization of dopamine coated iron oxide nanoparticles for various surface functionalities

Energy Technology Data Exchange (ETDEWEB)

Sherwood, Jennifer; Xu, Yaolin; Lovas, Kira [Chemical and Biological Engineering, The University of Alabama, Tuscaloosa , AL 35487 (United States); Qin, Ying [Alabama Innovation and Mentoring of Entrepreneurs, The University of Alabama, Tuscaloosa, AL 35487 (United States); Bao, Yuping, E-mail: ybao@eng.ua.edu [Chemical and Biological Engineering, The University of Alabama, Tuscaloosa , AL 35487 (United States)

2017-04-01

We present effective conjugation of four small molecules (glutathione, cysteine, lysine, and Tris(hydroxymethyl)aminomethane) onto dopamine-coated iron oxide nanoparticles. Conjugation of these molecules could improve the surface functionality of nanoparticles for more neutral surface charge at physiological pH and potentially reduce non-specific adsorption of proteins to nanoparticles surfaces. The success of conjugation was evaluated with dynamic light scattering by measuring the surface charge changes and Fourier transform infrared spectroscopy for surface chemistry analysis. The stability of dopamine-coated nanoparticles and the ability of conjugated nanoparticles to reduce the formation of protein corona were evaluated by measuring the size and charge of the nanoparticles in biological medium. This facile conjugation method opens up possibilities for attaching various surface functionalities onto iron oxide nanoparticle surfaces for biomedical applications.

Surface functionalization of dopamine coated iron oxide nanoparticles for various surface functionalities

International Nuclear Information System (INIS)

Sherwood, Jennifer; Xu, Yaolin; Lovas, Kira; Qin, Ying; Bao, Yuping

2017-01-01

We present effective conjugation of four small molecules (glutathione, cysteine, lysine, and Tris(hydroxymethyl)aminomethane) onto dopamine-coated iron oxide nanoparticles. Conjugation of these molecules could improve the surface functionality of nanoparticles for more neutral surface charge at physiological pH and potentially reduce non-specific adsorption of proteins to nanoparticles surfaces. The success of conjugation was evaluated with dynamic light scattering by measuring the surface charge changes and Fourier transform infrared spectroscopy for surface chemistry analysis. The stability of dopamine-coated nanoparticles and the ability of conjugated nanoparticles to reduce the formation of protein corona were evaluated by measuring the size and charge of the nanoparticles in biological medium. This facile conjugation method opens up possibilities for attaching various surface functionalities onto iron oxide nanoparticle surfaces for biomedical applications.

Assessment of managed aquifer recharge from Sand Hollow Reservoir, Washington County, Utah, updated to conditions in 2010

Science.gov (United States)

Heilweil, Victor M.; Marston, Thomas M.

2011-01-01

Sand Hollow Reservoir in Washington County, Utah, was completed in March 2002 and is operated primarily for managed aquifer recharge by the Washington County Water Conservancy District. From 2002 through 2009, total surface-water diversions of about 154,000 acre-feet to Sand Hollow Reservoir have allowed it to remain nearly full since 2006. Groundwater levels in monitoring wells near the reservoir rose through 2006 and have fluctuated more recently because of variations in reservoir water-level altitude and nearby pumping from production wells. Between 2004 and 2009, a total of about 13,000 acre-feet of groundwater has been withdrawn by these wells for municipal supply. In addition, a total of about 14,000 acre-feet of shallow seepage was captured by French drains adjacent to the North and West Dams and used for municipal supply, irrigation, or returned to the reservoir.From 2002 through 2009, about 86,000 acre-feet of water seeped beneath the reservoir to recharge the underlying Navajo Sandstone aquifer. Water-quality sampling was conducted at various monitoring wells in Sand Hollow to evaluate the timing and location of reservoir recharge moving through the aquifer. Tracers of reservoir recharge include major and minor dissolved inorganic ions, tritium, dissolved organic carbon, chlorofluorocarbons, sulfur hexafluoride, and noble gases. By 2010, this recharge arrived at monitoring wells within about 1,000 feet of the reservoir.

Hydrological controls on transient aquifer storage in a karst watershed

Science.gov (United States)

Spellman, P.; Martin, J.; Gulley, J. D.

2017-12-01

While surface storage of floodwaters is well-known to attenuate flood peaks, transient storage of floodwaters in aquifers is a less recognized mechanism of flood peak attenuation. The hydraulic gradient from aquifer to river controls the magnitude of transient aquifer storage and is ultimately a function of aquifer hydraulic conductivity, and effective porosity. Because bedrock and granular aquifers tend to have lower hydraulic conductivities and porosities, their ability to attenuate flood peaks is generally small. In karst aquifers, however, extensive cave systems create high hydraulic conductivities and porosities that create low antecedent hydraulic gradients between aquifers and rivers. Cave springs can reverse flow during high discharges in rivers, temporarily storing floodwaters in the aquifer thus reducing the magnitude of flood discharge downstream. To date however, very few studies have quantified the magnitude or controls of transient aquifer storage in karst watersheds. We therefore investigate controls on transient aquifer storage by using 10 years of river and groundwater data from the Suwannee River Basin, which flows over the karstic upper Floridan aquifer in north-central Florida. We use multiple linear regression to compare the effects of three hydrological controls on the magnitude of transient aquifer storage: antecedent stage, recharge and slope of hydrograph rise. We show the dominant control on transient aquifer storage is antecedent stage, whereby lower stages result in greater magnitudes of transient aquifer storage. Our results suggest that measures of groundwater levels prior to an event can be useful in determining whether transient aquifer storage will occur and may provide a useful metric for improving predictions of flood magnitudes.

Research Note : Near-surface layer replacement for sparse data: Is interpolation needed?

NARCIS (Netherlands)

Sun, Yimin; Verschuur, D.J.; Luo, Yi

2017-01-01

Near-surface problem is a common challenge faced by land seismic data processing, where often, due to near-surface anomalies, events of interest are obscured. One method to handle this challenge is near-surface layer replacement, which is a wavefield reconstruction process based on downward

Surface-Water and Groundwater Interactions along the Withlacoochee River, West-Central Florida

Science.gov (United States)

Trommer, J.T.; Yobbi, D.K.; McBride, W.S.

2009-01-01

A study of the Withlacoochee River watershed in west-central Florida was conducted from October 2003 to March 2007 to gain a better understanding of the hydrology and surface-water and groundwater interactions along the river. The Withlacoochee River originates in the Green Swamp area in north-central Polk County and flows northerly through seven counties, emptying into the Gulf of Mexico. This study includes only the part of the watershed located between the headwaters in the Green Swamp and the U.S. Geological Survey gaging station near Holder, Florida. The Withlacoochee River within the study area is about 108 miles long and drains about 1,820 square miles. The Withlacoochee River watershed is underlain by thick sequences of carbonate rock that are covered by thin surficial deposits of unconsolidated sand and sandy clay. The clay layer is breached in many places because of the karst nature of the underlying limestone, and the degree of confinement between the Upper Florida aquifer and the surficial aquifer is highly variable throughout the watershed. The potential for movement of water from the surface or shallow deposits to deeper deposits, or from deeper deposits to the shallow deposits, exists throughout the Withlacoochee River watershed. Water levels were higher in deeper Upper Floridan aquifer wells than in shallow Upper Floridan aquifer wells or surficial aquifer wells at 11 of 19 paired or nested well sites, indicating potential for discharge to the surface-water system. Water levels were higher in shallow Upper Floridan aquifer or surficial aquifer wells than in deeper Upper Floridan aquifer wells at five other sites, indicating potential for recharge to the deeper Upper Floridan aquifer. Water levels in the surficial aquifer and Upper Floridan aquifer wells at the remaining three sites were virtually the same, indicating little or no confinement at the sites. Potentiometric-surface maps of the Upper Floridan aquifer indicate the pattern of groundwater

Hydrology and geochemistry of a surface coal mine in northwestern Colorado

Science.gov (United States)

Williams, R.S.; Clark, G.M.

1994-01-01

The hydrology and geochemistry of a reclaimed coal mine in northwestern Colorado were monitored during water years 1988 and 1989. Some data also were collected in water years 1987 and 1990. This report describes (1) the sources of hydrologic recharge to and discharge from reclaimed spoil, (2) the relative contributions of recharge to the reclaimed spoil aquifer from identified source waters and the rate of water movement from those sources to the reclaimed spoil, and (3) the geochemical reactions that control water quality in reclaimed spoil. The study area was at a dip-slope coal mine encompassing about 7 square miles with land slopes of varying aspect. The area was instrumented and monitored at five sites; two sites had unmined and reclaimed- spoil areas adjacent to each other and three sites were unmined. The mined areas had been reclaimed. Instrumentation at the study sites included 1 climate station, 3 rain gages, 19 soil-water access tubes, 2 lysimeters, 18 wells completed in bedrock, 7 wells completed in reclaimed spoil, and 2 surface- water gaging stations. The results of the study indicate that the reclaimed spoil is recharged from surface recharge and underburden aquifers. Discharge, as measured by lysimeters, was about 3 inches per year and occurred during and after snowmelt. Hydraulic-head measurements indicated a potential for ground-water movement from deeper to shallower aquifers. Water levels rose in the reclaimed-spoil aquifer and spring discharge at the toe of the spoil slopes increased rapidly in response to snowmelt. Water chemistry, stable isotopes, geochemical models, and mass-balance calculations indicate that surface recharge and the underburden aquifers each contribute about 50 percent of the water to the reclaimed-spoil aquifers. Geochemical information indicates that pyrite oxidation and dissolution of carbonate and efflorescent sulfate minerals control the water chemistry of the reclaimed-spoil aquifer.

Methodology for estimating aquifer recharge direct mfisurado system by the method of ripple of free (WTF) surface Mina Arenal departamento de Rivera

International Nuclear Information System (INIS)

Iardino, G.; González, G.; Montaño, J.

2010-01-01

The study area is framed in the so-called Crystal Island Rivera region of economic importance to Uruguay considering the gold occurrences . The company Uruguay Mineral Exploration Inc. (UME ) develops prospective exploration projects in the region since 1997 The discovery of a deposit of gold ore results in the opening of the Arenal mine near the town of Minas de Corrales, Department Rivera .Income groundwater to the quarry would affect the progress of the mineral extractive work to control this situation and monitors the evolution of a monitoring program is established with the potentiometric measurement levels and hydrological variables meteorelógicas.The data obtained allowed to estimate the direct recharge of the aquifer system in the area comprising the operational work of the Arenal mine, by applying the method of free surface fluctuation (WTF ) .The WTF method provides an estimate of groundwater recharge by analyzing water level fluctuations in observation wells

Isotopic and microbiological signatures of pyrite-driven denitrification in a sandy aquifer

NARCIS (Netherlands)

Zhang, Y.C.; Slomp, C.P.; Broers, H.P.; Bostick, B.; Passier, H.F.; Böttcher, M.E.; Omoregie, E.O.; Lloyd, J.R.; Polya, D.A.; Cappellen, P. van

2012-01-01

Denitrification driven by pyrite oxidation can play a major role in the removal of nitrate from groundwater systems. As yet, limited information is available on the interactions between the micro-organisms and aqueous and mineral phases in aquifers where pyrite oxidation is occurring. In this study,

Volcano Relations for Oxidation of Hydrogen Halides over Rutile Oxide Surfaces

DEFF Research Database (Denmark)

Toftelund, Anja; Man, Isabela C.; Hansen, Heine A.

2012-01-01

over a range of different rutile oxide surfaces. Based on the scaling relations, two descriptors are identified that describe the reactions uniquely. By combining scaling with the micro-kinetic model, activity volcanoes for the three different oxidation reactions are derived. It is found...

Groundwater vulnerability mapping of Qatar aquifers

Science.gov (United States)

Baalousha, Husam Musa

2016-12-01

Qatar is one of the most arid countries in the world with limited water resources. With little rainfall and no surface water, groundwater is the only natural source of fresh water in the country. Whilst the country relies mainly on desalination of seawater to secure water supply, groundwater has extensively been used for irrigation over the last three decades, which caused adverse environmental impact. Vulnerability assessment is a widely used tool for groundwater protection and land-use management. Aquifers in Qatar are carbonate with lots of fractures, depressions and cavities. Karst aquifers are generally more vulnerable to contamination than other aquifers as any anthropogenic-sourced contaminant, especially above a highly fractured zone, can infiltrate quickly into the aquifer and spread over a wide area. The vulnerability assessment method presented in this study is based on two approaches: DRASTIC and EPIK, within the framework of Geographical Information System (GIS). Results of this study show that DRASTIC vulnerability method suits Qatar hydrogeological settings more than EPIK. The produced vulnerability map using DRASTIC shows coastal and karst areas have the highest vulnerability class. The southern part of the country is located in the low vulnerability class due to occurrence of shale formation within aquifer media, which averts downward movement of contaminants.

Imaging near-surface heterogeneities by natural migration of backscattered surface waves: Field data test

KAUST Repository

Liu, Zhaolun; AlTheyab, Abdullah; Hanafy, Sherif M.; Schuster, Gerard T.

2017-01-01

We have developed a methodology for detecting the presence of near-surface heterogeneities by naturally migrating backscattered surface waves in controlled-source data. The near-surface heterogeneities must be located within a depth of approximately one-third the dominant wavelength λ of the strong surface-wave arrivals. This natural migration method does not require knowledge of the near-surface phase-velocity distribution because it uses the recorded data to approximate the Green’s functions for migration. Prior to migration, the backscattered data are separated from the original records, and the band-passed filtered data are migrated to give an estimate of the migration image at a depth of approximately one-third λ. Each band-passed data set gives a migration image at a different depth. Results with synthetic data and field data recorded over known faults validate the effectiveness of this method. Migrating the surface waves in recorded 2D and 3D data sets accurately reveals the locations of known faults. The limitation of this method is that it requires a dense array of receivers with a geophone interval less than approximately one-half λ.

Imaging near-surface heterogeneities by natural migration of backscattered surface waves: Field data test

KAUST Repository

Liu, Zhaolun

2017-03-06

We have developed a methodology for detecting the presence of near-surface heterogeneities by naturally migrating backscattered surface waves in controlled-source data. The near-surface heterogeneities must be located within a depth of approximately one-third the dominant wavelength λ of the strong surface-wave arrivals. This natural migration method does not require knowledge of the near-surface phase-velocity distribution because it uses the recorded data to approximate the Green’s functions for migration. Prior to migration, the backscattered data are separated from the original records, and the band-passed filtered data are migrated to give an estimate of the migration image at a depth of approximately one-third λ. Each band-passed data set gives a migration image at a different depth. Results with synthetic data and field data recorded over known faults validate the effectiveness of this method. Migrating the surface waves in recorded 2D and 3D data sets accurately reveals the locations of known faults. The limitation of this method is that it requires a dense array of receivers with a geophone interval less than approximately one-half λ.

Upper Basalt-Confined Aquifer System in the Southern Hanford Site

International Nuclear Information System (INIS)

Thorne, P.

1999-01-01

The 1990 DOE Tiger Team Finding GW/CF-202 found that the hydrogeologic regime at the Hanford Site was inadequately characterized. This finding also identified the need for completing a study of the confined aquifer in the central and southern portions of the Hanford Site. The southern portion of the site is of particular interest because hydraulic-head patterns in the upper basalt-confined aquifer system indicate that groundwater from the Hanford central plateau area, where contaminants have been found in the aquifer, flows southeast toward the southern site boundary. This results in a potential for offsite migration of contaminants through the upper basalt-confined aquifer system. Based on the review presented in this report, available hydrogeologic characterization information for the upper basalt-confined aquifer system in this area is considered adequate to close the action item. Recently drilled offsite wells have provided additional information on the structure of the aquifer system in and near the southern part of the Hanford Site. Information on hydraulic properties, hydrochemistry, hydraulic heads and flow directions for the upper basalt-confined aquifer system has been re-examined and compiled in recent reports including Spane and Raymond (1993), Spane and Vermeul ( 1994), and Spane and Webber (1995)

CO2/Brine transport into shallow aquifers along fault zones.

Science.gov (United States)

Keating, Elizabeth H; Newell, Dennis L; Viswanathan, Hari; Carey, J W; Zyvoloski, G; Pawar, Rajesh

2013-01-02

Unintended release of CO(2) from carbon sequestration reservoirs poses a well-recognized risk to groundwater quality. Research has largely focused on in situ CO(2)-induced pH depression and subsequent trace metal mobilization. In this paper we focus on a second mechanism: upward intrusion of displaced brine or brackish-water into a shallow aquifer as a result of CO(2) injection. Studies of two natural analog sites provide insights into physical and chemical mechanisms controlling both brackish water and CO(2) intrusion into shallow aquifers along fault zones. At the Chimayó, New Mexico site, shallow groundwater near the fault is enriched in CO(2) and, in some places, salinity is significantly elevated. In contrast, at the Springerville, Arizona site CO(2) is leaking upward through brine aquifers but does not appear to be increasing salinity in the shallow aquifer. Using multiphase transport simulations we show conditions under which significant CO(2) can be transported through deep brine aquifers into shallow layers. Only a subset of these conditions favor entrainment of salinity into the shallow aquifer: high aspect-ratio leakage pathways and viscous coupling between the fluid phases. Recognition of the conditions under which salinity is favored to be cotransported with CO(2) into shallow aquifers will be important in environmental risk assessments.

Formation of nanocrystalline surface layers in various metallic materials by near surface severe plastic deformation

Directory of Open Access Journals (Sweden)

Masahide Sato, Nobuhiro Tsuji, Yoritoshi Minamino and Yuichiro Koizumi

2004-01-01

Full Text Available The surface of the various kinds of metallic materials sheets were severely deformed by wire-brushing at ambient temperature to achieve nanocrystalline surface layer. The surface layers of the metallic materials developed by the near surface severe plastic deformation (NS-SPD were characterized by means of TEM. Nearly equiaxed nanocrystals with grain sizes ranging from 30 to 200 nm were observed in the near surface regions of all the severely scratched metallic materials, which are Ti-added ultra-low carbon interstitial free steel, austenitic stainless steel (SUS304, 99.99 wt.%Al, commercial purity aluminum (A1050 and A1100, Al–Mg alloy (A5083, Al-4 wt.%Cu alloy, OFHC-Cu (C1020, Cu–Zn alloy (C2600 and Pb-1.5%Sn alloy. In case of the 1050-H24 aluminum, the depth of the surface nanocrystalline layer was about 15 μm. It was clarified that wire-brushing is an effective way of NS-SPD, and surface nanocrystallization can be easily achieved in most of metallic materials.

Study on the surface oxidation of uranium in different gaseous atmospheres

International Nuclear Information System (INIS)

Wang Xiaoling; Fu Yibei; Xie Renshou

1996-03-01

The studying for the surface oxidation of uranium and oxide by X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES), secondary ion mass spectroscopy (SIMS), and the surface oxidation of uranium in different gaseous atmospheres such as O 2 , H 2 , CO, CO 2 , H 2 O(v) and air were reviewed. The surface oxidation of uranium is greatly influenced by a number of parameters including atmospheric temperature, pressure, diffusion of adsorbed gas atoms through the oxide layer, surface and interface chemical component, and defect structure and electron nature of the oxide layer. The initial oxidation mechanism and kinetics have been discussed. Suggestions for future work have also been presented. (32 refs., 7 figs., 5 tabs.)

Electrical resistivity and porosity structure of the upper Biscayne Aquifer in Miami-Dade County, Florida

Science.gov (United States)

Whitman, Dean; Yeboah-Forson, Albert

2015-12-01

Square array electrical soundings were made at 13 sites in the Biscayne Aquifer distributed between 1 and 20 km from the shoreline. These soundings were modeled to investigate how resistivity varies spatially and with depth in the upper 15 m of the aquifer. Porosity was estimated from the modeled formation resistivity and observed pore fluid resistivity with Archie's Law. The models were used to interpolate resistivity and porosity surfaces at -2, -5, -8, and -15 m elevations. Modeled resistivity in the unsaturated zone is generally higher than 300 Ω m with the resistivity at sites with thick unsaturated zones greater than 1000 Ω m. Resistivity in the saturated zone ranges from 30 to 320 Ω m. At many sites in the western portions of the study area, resistivity is constant or increases with depth whereas sites in the center of the Atlantic Coastal Ridge exhibit a distinct low resistivity zone (ρ aquifer. The estimated porosity ranges between 14% and 71% with modal values near 25%. The porosity structure varies both with depth and spatially. Western sites exhibit a high porosity zone at shallow depths best expressed in a NE-SW trending zone of 40-50% porosity situated near the western margin of the Atlantic Coastal Ridge. This zone roughly corresponds in depth with the Q5 chronostratigraphic unit of the Miami Fm. which constitutes the upper flow unit of the Biscayne Aquifer. The highest porosity (>50%) is seen at elevations below -5 m at sites in the center of the Atlantic Coastal Ridge and likely corresponds to solution features. The general NE-SW trend of the resistivity and porosity structure suggests a causal connection with the Pleistocene paleogeography and sedimentary environments.

Stream-water and groundwater quality in and near the Citizen Potawatomi Nation Tribal Jurisdictional Area, Pottawatomie County, Oklahoma, 2012-13

Science.gov (United States)

Becker, Carol J.

2014-01-01

The Citizen Potawatomi Nation needs to characterize their existing surface-water and groundwater resources in and near their tribal jurisdictional area to complete a water-resource management plan. Water resources in this area include surface water from the North Canadian and Little Rivers and groundwater from the terrace and alluvial aquifers and underlying bedrock aquifers. To assist in this effort, the U.S. Geological Survey (USGS), in cooperation with the Citizen Potawatomi Nation, collected water-quality samples at 4 sites on 3 streams and from 30 wells during 2012 and 2013 in and near the Citizen Potawatomi Nation Tribal Jurisdictional Area in central Oklahoma. Stream samples were collected eight times on the North Canadian River at the upstream USGS streamflow-gaging station North Canadian River near Harrah, Okla. (07241550); at the downstream USGS streamflow-gaging station North Canadian River at Shawnee, Okla. (07241800); and on the Little River at the USGS streamflow-gaging station Little River near Tecumseh, Okla., (07230500). Stream samples also were collected three times at an ungaged site, Deer Creek near McLoud, Okla. (07241590). Water properties were measured, and water samples were analyzed for concentrations of major ions, nutrients, trace elements, counts of fecal-indicator bacteria, and 69 organic compounds.

Groundwater availability of the Central Valley Aquifer, California

Science.gov (United States)

Faunt, Claudia C.

2009-01-01

California's Central Valley covers about 20,000 square miles and is one of the most productive agricultural regions in the world. More than 250 different crops are grown in the Central Valley with an estimated value of $17 billion per year. This irrigated agriculture relies heavily on surface-water diversions and groundwater pumpage. Approximately one-sixth of the Nation's irrigated land is in the Central Valley, and about one-fifth of the Nation's groundwater demand is supplied from its aquifers. The Central Valley also is rapidly becoming an important area for California's expanding urban population. Since 1980, the population of the Central Valley has nearly doubled from 2 million to 3.8 million people. The Census Bureau projects that the Central Valley's population will increase to 6 million people by 2020. This surge in population has increased the competition for water resources within the Central Valley and statewide, which likely will be exacerbated by anticipated reductions in deliveries of Colorado River water to southern California. In response to this competition for water, a number of water-related issues have gained prominence: conservation of agricultural land, conjunctive use, artificial recharge, hydrologic implications of land-use change, and effects of climate variability. To provide information to stakeholders addressing these issues, the USGS Groundwater Resources Program made a detailed assessment of groundwater availability of the Central Valley aquifer system, that includes: (1) the present status of groundwater resources; (2) how these resources have changed over time; and (3) tools to assess system responses to stresses from future human uses and climate variability and change. This effort builds on previous investigations, such as the USGS Central Valley Regional Aquifer System and Analysis (CV-RASA) project and several other groundwater studies in the Valley completed by Federal, State and local agencies at differing scales. The

Anaerobic oxidation of methane by sulfate in hypersaline groundwater of the Dead Sea aquifer

Science.gov (United States)

Avrahamov, N; Antler, G; Yechieli, Y; Gavrieli, I; Joye, S B; Saxton, M; Turchyn, A V; Sivan, O

2014-01-01

Geochemical and microbial evidence points to anaerobic oxidation of methane (AOM) likely coupled with bacterial sulfate reduction in the hypersaline groundwater of the Dead Sea (DS) alluvial aquifer. Groundwater was sampled from nine boreholes drilled along the Arugot alluvial fan next to the DS. The groundwater samples were highly saline (up to 6300 mm chlorine), anoxic, and contained methane. A mass balance calculation demonstrates that the very low δ13CDIC in this groundwater is due to anaerobic methane oxidation. Sulfate depletion coincident with isotope enrichment of sulfur and oxygen isotopes in the sulfate suggests that sulfate reduction is associated with this AOM. DNA extraction and 16S amplicon sequencing were used to explore the microbial community present and were found to be microbial composition indicative of bacterial sulfate reducers associated with anaerobic methanotrophic archaea (ANME) driving AOM. The net sulfate reduction seems to be primarily controlled by the salinity and the available methane and is substantially lower as salinity increases (2.5 mm sulfate removal at 3000 mm chlorine but only 0.5 mm sulfate removal at 6300 mm chlorine). Low overall sulfur isotope fractionation observed (34ε = 17 ± 3.5‰) hints at high rates of sulfate reduction, as has been previously suggested for sulfate reduction coupled with methane oxidation. The new results demonstrate the presence of sulfate-driven AOM in terrestrial hypersaline systems and expand our understanding of how microbial life is sustained under the challenging conditions of an extremely hypersaline environment. PMID:25039851

Aquifer thermal energy storage. International symposium: Proceedings

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-05-01

Aquifers have been used to store large quantities of thermal energy to supply process cooling, space cooling, space heating, and ventilation air preheating, and can be used with or without heat pumps. Aquifers are used as energy sinks and sources when supply and demand for energy do not coincide. Aquifer thermal energy storage may be used on a short-term or long-term basis; as the sole source of energy or as a partial storage; at a temperature useful for direct application or needing upgrade. The sources of energy used for aquifer storage are ambient air, usually cold winter air; waste or by-product energy; and renewable energy such as solar. The present technical, financial and environmental status of ATES is promising. Numerous projects are operating and under development in several countries. These projects are listed and results from Canada and elsewhere are used to illustrate the present status of ATES. Technical obstacles have been addressed and have largely been overcome. Cold storage in aquifers can be seen as a standard design option in the near future as it presently is in some countries. The cost-effectiveness of aquifer thermal energy storage is based on the capital cost avoidance of conventional chilling equipment and energy savings. ATES is one of many developments in energy efficient building technology and its success depends on relating it to important building market and environmental trends. This paper attempts to provide guidance for the future implementation of ATES. Individual projects have been processed separately for entry onto the Department of Energy databases.

NEAR-SURFACE GEOPHYSICAL CHARACTERIZATION OF A HOLOCENE FAULT CONDUCIVE TO GEOTHERMAL FLOW NEAR PYRAMID LAKE, NEVADA

Energy Technology Data Exchange (ETDEWEB)

Dorsey, Alison; Dudley, Colton; Louie, John [UNR; Schwering, Paul; Pullammanappallil, Satish [Optim

2013-06-30

Linear deposits of calcium carbonate tufa columns mark recent faults that cut 11 ka Lake Lahontan sediments at Astor Pass, north of Pyramid Lake, Nevada. Throughout the Great Basin, faults appear to control the location of geothermal resources by providing pathways for fluid migration. Reservoir-depth (greater than 1 km) seismic imaging at Astor Pass reveals a fault that projects to one of the lines of tufa columns at the surface. The presence of the tufa deposits suggests this fault carried warm geothermal waters through the lakebed clay sediments in recent time. The warm fluids deposited the tufa when they hit cold Lake Lahontan water at the lakebed. Lake Lahontan covered this location 11 ka to a depth of at least 60 m. In collaboration with the Pyramid Lake Paiute Tribe, an Applied Geophysics class at UNR investigated the near-surface geophysical characteristics of this fault. The survey at and near the tufa columns comprises near-surface Pwave seismic reflection and refraction, electrical resistivity tomography, nearsurface refraction microtremor arrays, nine near-surface direct-current resistivity soundings, magnetic surveys, and gravity surveys. The refraction microtremor results show shear velocities near tufa and faults to be marginally lower, compared to Vs away from the faults. Overall, the 30-m depth-averaged shear velocities are low, less than 300 m/s, consistent with the lakebed clay deposits. These results indicate that no seismically fast (> 500 m/s) tufa deposits are present below the surface at or near the tufa columns. Vs30 averages were for example 274 ± 13 m/s on the fault, 287 ± 2 m/s at 150 m east of the fault, and 290 ± 15 m/s at 150 m west of the fault. The P-velocity refraction optimization results similarly indicate a lack of high-velocity tufa buried below the surface in the Lahontan sediments, reinforcing the idea that all tufa was deposited above the lakebed surface. The seismic results provide a negative test of the hypothesis that

Quantifying Uncertainty in Near Surface Electromagnetic Imaging Using Bayesian Methods

Science.gov (United States)

Blatter, D. B.; Ray, A.; Key, K.

2017-12-01

Geoscientists commonly use electromagnetic methods to image the Earth's near surface. Field measurements of EM fields are made (often with the aid an artificial EM source) and then used to infer near surface electrical conductivity via a process known as inversion. In geophysics, the standard inversion tool kit is robust and can provide an estimate of the Earth's near surface conductivity that is both geologically reasonable and compatible with the measured field data. However, standard inverse methods struggle to provide a sense of the uncertainty in the estimate they provide. This is because the task of finding an Earth model that explains the data to within measurement error is non-unique - that is, there are many, many such models; but the standard methods provide only one "answer." An alternative method, known as Bayesian inversion, seeks to explore the full range of Earth model parameters that can adequately explain the measured data, rather than attempting to find a single, "ideal" model. Bayesian inverse methods can therefore provide a quantitative assessment of the uncertainty inherent in trying to infer near surface conductivity from noisy, measured field data. This study applies a Bayesian inverse method (called trans-dimensional Markov chain Monte Carlo) to transient airborne EM data previously collected over Taylor Valley - one of the McMurdo Dry Valleys in Antarctica. Our results confirm the reasonableness of previous estimates (made using standard methods) of near surface conductivity beneath Taylor Valley. In addition, we demonstrate quantitatively the uncertainty associated with those estimates. We demonstrate that Bayesian inverse methods can provide quantitative uncertainty to estimates of near surface conductivity.

Spent-fuel special-studies progress report: probable mechanisms for oxidation and dissolution of single-crystal UO2 surfaces

International Nuclear Information System (INIS)

Wang, R.

1981-03-01

Due to the complexity of the structural, microstructural and compositional characteristics of spent fuel, basic leaching and dissolution mechanisms were studied with UO 2 matrix material, specifically with single-crystal UO 2 , to isolate individual contributory factors. The effects of oxidation and oxidation-dissolution were investigated in different oxidation conditions, such as in air, oxygenated solutions and deionized water containing H 2 O 2 . In addition, the effects of temperature on dissolution of UO 2 were studied in autoclaves at 75 and 150 0 C. Also, oxidation and dissolution measurements were investigated via electrochemical methods to determine if those techniques could be applied to the characterization of leaching and dissolution of spent fuel in a hot cell. Finally, the effects of radiation were explored since the radiolysis of water may create a localized oxidizing condition at or near the spent fuel-solution interface, even in neutral or reducing conditions as commonly found in deep geological environments. The oxidation and oxidation-dissolution mechanisms for UO 2 are proposed as follows: The UO 2 surface is first oxidized in solution to form a UO/sub 2+x/ surface layer several angstroms thick. This oxidized surface has a high dissolution rate since the UO/sub 2+x/ reacts with the dissolved O 2 , or H 2 O 2 , to form uranyl complex ions in a U(VI) state. As the uranyl ions exceed the solubility limits in solution, they become hydrolyzed to form solid deposits and suspended particles of UO 3 hydrates. The thickness and porosity of the deposited UO 3 hydrate surface-film is dependent on temperature, pH and deposition time. A long-term dissolution rate is then determined by the nature of the surface film, such as porosity, solubility and mechanical properties

Arsenic transport in groundwater, surface water, and the hyporheic zone of a mine-influenced stream-aquifer system

OpenAIRE

Brown, Brendan

2005-01-01

We investigated the transport of dissolved arsenic in groundwater, surface water and the hyporheic zone in a stream-aquifer system influenced by an abandoned arsenopyrite mine. Mine tailing piles consisting of a host of arsenic-bearing minerals including arsenopyrite and scorodite remain adjacent to the stream and represent a continuous source of arsenic. Arsenic loads from the stream, springs, and groundwater were quantified at the study reach on nine dates from January to August 2005 and ...

ISLSCP II Reanalysis Near-Surface Meteorology Data

Data.gov (United States)

National Aeronautics and Space Administration — ABSTRACT: This data set for the ISLSCP Initiative II data collection provides near surface meteorological variables, fluxes of heat, moisture and momentum at the...

Discourse characteristics of ore-bearing aquifer of Chaidenghao in Husiliang area

International Nuclear Information System (INIS)

Zhou Bowen

2012-01-01

Call Sri Lanka article focuses primarily on wood board beam region trench features lots of ore-bearing aquifer, located in the ore-bearing aquifer under Zhiluo lower sub-section; A brief introduction to the work area's geology and stratigraphic structure, and a brief description of the main ore purpose of the lower layer Zhiluo under sub-section lithology; Shows aquifer top, bottom and described its characteristics, the two formed a 'watertight-water-impermeable' good hydrogeological structure of the ancient interlayer oxidation zone formation to create a favorable space. Based on the above description and analysis of the location of uranium mineralization in good condition, have a good vision of the mineralization. (author)

Unravelling aquifer-wetland interaction using CSAMT and gravity methods: the Mollina-Camorra aquifer and the Fuente de Piedra playa-lake, southern Spain

Science.gov (United States)

Pedrera, A.; Martos-Rosillo, S.; Galindo-Zaldívar, J.; Rodríguez-Rodríguez, M.; Benavente, J.; Martín-Rodríguez, J. F.; Zúñiga-López, M. I.

2016-06-01

The hydrological regime of Fuente de Piedra playa-lake (Málaga, southern Spain) has been significantly affected by the intensive exploitation of groundwater in the area. The playa-lake is situated above clays, marls, and gypsum, and under unaltered conditions received surface-subsurface runoff within the watershed as well as groundwater discharge from two carbonate aquifers. We have analyzed the structure of the main one, the Mollina-Camorra carbonate aquifer, by combining controlled source audio magnetotellurics (CSAMT), gravity prospecting, and time-domain electromagnetic (TDEM) soundings. This geophysical information, together with new structural and hydrogeological data, was gathered to develop a new conceptual hydrogeological model. This model allows the hydrological linkage of the carbonate aquifer with the playa-lake system to be established. Moreover, the intensive exploitation in the carbonate aquifer, even outside the watershed of the playa-lake, has affected the hydrological regime of the system. This multidisciplinary work demonstrates the potential of geophysical methods for understanding wetland-aquifer interaction, having important groundwater management implications.

Low temperature removal of surface oxides and hydrocarbons from Ge(100) using atomic hydrogen

Energy Technology Data Exchange (ETDEWEB)

Walker, M., E-mail: m.walker@warwick.ac.uk; Tedder, M.S.; Palmer, J.D.; Mudd, J.J.; McConville, C.F.

2016-08-30

Highlights: • Preparation of a clean, well-ordered Ge(100) surface with atomic hydrogen. • Surface oxide layers removed by AHC at room temperature, but not hydrocarbons. • Increasing surface temperature during AHC dramatically improves efficiency. • AHC with the surface heated to 250 °C led to a near complete removal of contaminants. • (2 × 1) LEED pattern from IBA and AHC indicates asymmetric dimer reconstruction. - Abstract: Germanium is a group IV semiconductor with many current and potential applications in the modern semiconductor industry. Key to expanding the use of Ge is a reliable method for the removal of surface contamination, including oxides which are naturally formed during the exposure of Ge thin films to atmospheric conditions. A process for achieving this task at lower temperatures would be highly advantageous, where the underlying device architecture will not diffuse through the Ge film while also avoiding electronic damage induced by ion irradiation. Atomic hydrogen cleaning (AHC) offers a low-temperature, damage-free alternative to the common ion bombardment and annealing (IBA) technique which is widely employed. In this work, we demonstrate with X-ray photoelectron spectroscopy (XPS) that the AHC method is effective in removing surface oxides and hydrocarbons, yielding an almost completely clean surface when the AHC is conducted at a temperature of 250 °C. We compare the post-AHC cleanliness and (2 × 1) low energy electron diffraction (LEED) pattern to that obtained via IBA, where the sample is annealed at 600 °C. We also demonstrate that the combination of a sample temperature of 250 °C and atomic H dosing is required to clean the surface. Lower temperatures prove less effective in removal of the oxide layer and hydrocarbons, whilst annealing in ultra-high vacuum conditions only removes weakly bound hydrocarbons. Finally, we examine the subsequent H-termination of an IBA-cleaned sample using XPS, LEED and ultraviolet