WorldWideScience

Sample records for oiea se destinan

  1. Aplicación del código de práctica del OIEA para la validación de la dosis de esterilización por radiación gamma en aloinjertos de hueso

    OpenAIRE

    Castro, Emma

    2007-01-01

    En el Instituto Peruano de Energía Nuclear (IPEN) se esterilizan aloinjertos de hueso para implantes, procesados en Bancos de Tejidos a dosis estándar de 25 kGy. Esta dosis ha sido validada mediante la norma ISO/TR 13409:1996, para los mismos fines de validación puede aplicarse el “Código de Práctica para la Esterilización por Radiación de Aloinjertos de Tejidos: Requerimientos para la Validación y Control de Rutina” elaborado por el Organismo Internacional de Energía Atómica (OIEA) y específ...

  2. SE PREVENINDO?

    Directory of Open Access Journals (Sweden)

    Ana Débora Assis Moura

    2010-01-01

    Full Text Available Este estudio tuvo como objetivo verificar el comportamiento de las prostitutas en relación a la prevención de enfermedades de transmisión sexual y del Síndrome de Inmunodeficiencia Adquirida-SIDA, así como investigar cómo se previenen de esas enfermedades. Se trata de una investigación exploratoria, con enfoque cualitativo, llevada a cabo en la Asociación de las Prostitutas en Ceará, Brazil, en septiembre de 2008, a través de una encuesta con 25 prostitutas. El análisis de los datos se hizo según el análisis de contenido, después de ser agrupados en cuatro categorías: conocimiento sobre las enfermedades de transmisión sexual/SIDA; convivencia con la(s enfermedad(es; prevención de la enfermedad de transmisión sexual/SIDA; y el uso de drogas. Se concluyó que las prostitutas no usan preservativos en todas las relaciones sexuales, por lo tanto, las enfermedades de transmisión sexual representan una realidad; la desinformación sobre la(s enfermedad(es es notable; el consumo de drogas lícitas e ilícitas es frecuente entre ellas, factor que las expone a situaciones más vulnerables con relación al VIH/SIDA.

  3. Se los por se lo

    Directory of Open Access Journals (Sweden)

    José Luis Rivarola

    1985-12-01

    Full Text Available El sistema de la conjugación "objetiva" plantea interesantesproblemas que fueron tratados en parte por K. Heger (1966 en suestudio comparativo del francés y del español. De la comparaciónse desprende, por ejemplo, que en español hay un cierto número deambigüedades que no permiten establecer un "paradigma tan completo y unívoco" como en el caso del francés. Dentro de estas ambigüedades se encuentran las que propicia el gramema se: "El morfema [gramema] se funciona no sólo como pronombre reflexivo, sinotambién como variante combinatoria del pronombre personal complemento indirecto de la tercera persona.

  4. Contenha-se, se for capaz

    Directory of Open Access Journals (Sweden)

    Mirna Feitoza Pereira

    2008-11-01

    Full Text Available Em O Instinto da Linguagem, Steven Pinker discorre sobre sua célebre tese: a linguagem não é a mais prodigiosa invenção cultural humana. Ela é uma peça da constituição biológica do cérebro. A linguagem é uma habilidade complexa e especializada, que se desenvolve espontaneamente na criança, sem qualquer esforço consciente ou instrução formal, que se manifesta sem que se perceba sua lógica subjacente, que é qualitativamente a mesma em todo indiví­duo, e que difere de capacidades mais gerais de processamento de informações ou de comportamento inteligente. Para Pinker, a concepção de linguagem como um tipo de instinto transmite a idéia de que as pessoas sabem falar mais ou menos da mesma maneira que as aranhas sabem tecer suas teias. Ele apóia suas idéias em Darwin e Chomsky. Palavras-chave linguagem, gramática universal, evolução Abstract In Language Instinct, Steven Pinker argues about his famous thesis: language is not the most prodigious human cultural invention. It is a distinct piece of the biological constitution of the brain. Language is a complex, specialized skill, which develops spontaneously in the child, without conscious effort or formal instruction. It reveals itself without awareness of its underlying logic, which is qualitatively the same in every individual, and which is distinct from more general abilities of information processing of intelligent behavior. According to Pinker, the conception of language as a kind of instinct conveys the idea that people know how to talk in more or less the same way as spiders know how to spin webs. His thesis is founded in Darwin and Chomsky-s theories. Keywords language, universal grammar, evolution

  5. SE-FIT

    Science.gov (United States)

    Chen, Yongkang; Weislogel, Mark; Schaeffer, Ben; Semerjian, Ben; Yang, Lihong; Zimmerli, Gregory

    2012-01-01

    The mathematical theory of capillary surfaces has developed steadily over the centuries, but it was not until the last few decades that new technologies have put a more urgent demand on a substantially more qualitative and quantitative understanding of phenomena relating to capillarity in general. So far, the new theory development successfully predicts the behavior of capillary surfaces for special cases. However, an efficient quantitative mathematical prediction of capillary phenomena related to the shape and stability of geometrically complex equilibrium capillary surfaces remains a significant challenge. As one of many numerical tools, the open-source Surface Evolver (SE) algorithm has played an important role over the last two decades. The current effort was undertaken to provide a front-end to enhance the accessibility of SE for the purposes of design and analysis. Like SE, the new code is open-source and will remain under development for the foreseeable future. The ultimate goal of the current Surface Evolver Fluid Interface Tool (SEFIT) development is to build a fully integrated front-end with a set of graphical user interface (GUI) elements. Such a front-end enables the access to functionalities that are developed along with the GUIs to deal with pre-processing, convergence computation operation, and post-processing. In other words, SE-FIT is not just a GUI front-end, but an integrated environment that can perform sophisticated computational tasks, e.g. importing industry standard file formats and employing parameter sweep functions, which are both lacking in SE, and require minimal interaction by the user. These functions are created using a mixture of Visual Basic and the SE script language. These form the foundation for a high-performance front-end that substantially simplifies use without sacrificing the proven capabilities of SE. The real power of SE-FIT lies in its automated pre-processing, pre-defined geometries, convergence computation operation

  6. Photosensitive anisotype n-ZnSe/ p-InSe and n-ZnSe/ p-GaSe heterojunctions

    Science.gov (United States)

    Kudrynskyi, Z. R.; Kovalyuk, Z. D.

    2014-08-01

    Anisotype n-ZnSe/ p-InSe and n-ZnSe/ p-GaSe heterojunctions are obtained for the first time. They are grown on layered crystalline GaSe and InSe substrates by annealing in Zn vapor. It is found that these heterojunctions are sensitive to light in the near-infrared and visible spectral ranges.

  7. A literatura se ensina?

    OpenAIRE

    Cerdeira, Teresa Cristina

    2016-01-01

    Não sei se, na verdade, se ensina literatura. Mas qualquer coisa que se parecer com isto – ensinar literatura – tem que nascer de uma vibração conjunta de quem mostra e de quem vê pela primeira vez. Caminhar junto e descobrir sempre que as malhas do texto são infinitas. Venho portanto falar de sala de aula e de seminário, de circulação de saberes e de desejos, de uma atenção ao corpo sensível do texto que deve impactar, comprometer a linearidade da percepção, desalojar os sentidos prévios, en...

  8. ZnSe/ZnSeTe Superlattice Nanotips

    Directory of Open Access Journals (Sweden)

    Young SJ

    2010-01-01

    Full Text Available Abstract The authors report the growth of ZnSe/ZnSeTe superlattice nanotips on oxidized Si(100 substrate. It was found the nanotips exhibit mixture of cubic zinc-blende and hexagonal wurtzite structures. It was also found that photoluminescence intensities observed from the ZnSe/ZnSeTe superlattice nanotips were much larger than that observed from the homogeneous ZnSeTe nanotips. Furthermore, it was found that activation energies for the ZnSe/ZnSeTe superlattice nanotips with well widths of 16, 20, and 24 nm were 76, 46, and 19 meV, respectively.

  9. ZnSe/ZnSeTe Superlattice Nanotips

    Science.gov (United States)

    2010-01-01

    The authors report the growth of ZnSe/ZnSeTe superlattice nanotips on oxidized Si(100) substrate. It was found the nanotips exhibit mixture of cubic zinc-blende and hexagonal wurtzite structures. It was also found that photoluminescence intensities observed from the ZnSe/ZnSeTe superlattice nanotips were much larger than that observed from the homogeneous ZnSeTe nanotips. Furthermore, it was found that activation energies for the ZnSe/ZnSeTe superlattice nanotips with well widths of 16, 20, and 24 nm were 76, 46, and 19 meV, respectively. PMID:20672085

  10. Fe distribution in GaSe and InSe

    Energy Technology Data Exchange (ETDEWEB)

    Kovalyuk, Z.D.; Feichuk, P.I.; Shcherbak, L.P.; Zbykovskaya, N.I.

    1985-06-01

    In this paper, the authors use tagged atoms to determine the effective coefficients of Fe distribution in GaSe and InSe during crystallization of a doped melt by the Bridgman method. The distribution of Fe in GaSe and InSe was studied with the aid of Fe tagged with the radiosotopes VVFe + VZFe. Doping of the material was combined with the processes of synthesis and crystallization. Equations are presented for the calculation of the real impurity distribution in GaSe and InSe crystals.

  11. Electronic states of InSe/GaSe superlattice

    Science.gov (United States)

    Erkoç, Ş.; Allahverdi, K.; Ibrahim, Z.

    1994-06-01

    Analysis of recent publications revealed an increasing interest in epitaxial growth of InSe/GaSe superlattice. Within the effective mass theory we carried out self-consistent calculations of the confined and itinerant electronic states, potential profile and charge density distribution of InSe/GaSe superlattice, where the InSe layers are the well and the GaSe layers the barrier. Calculations were performed for three types of doping: uniform, modulated in the well, and modulated in the barrier. It has been found that the Coulomb interaction in the well and barrier forces the formation of localized states in the barrier region. The possibility of an insulator-metal transition in InSe/GaSe superlattice is predicted for modulation doping in the barrier and for a doping level n = 10 19cm-3. A decrease of the barrier height has been found for modulation doping in the well.

  12. Fe distribution in GaSe and InSe

    Energy Technology Data Exchange (ETDEWEB)

    Kovalyuk, Z.D.; Fejchuk, P.I.; Shcherbak, L.P.; Zbykovskaya, N.I.

    1985-01-01

    Radiometry was used to determine the effective coefficients of Fe distribution in GaSe and InSe during planar crystallization of melt with 5 x 10/sup 17/-6 x 10/sup 19/ at/cm/sup 3/ initial impurity concentration; concentration dependence of these cofficients was established. Equations for calculation of the real impurity distribution in GaSe and InSe crystals are presented.

  13. Labeling radiopharmaceuticals with Se-75: using Se-75 selenious acid

    Energy Technology Data Exchange (ETDEWEB)

    Sadek, S.A.; Basmadjian, G.P.; Ice, R.D. (Oklahoma Univ., Oklahoma City (USA). Health Sciences Center)

    1982-08-01

    A cheap, easy method of introducing high specific activity Se-75 into radiopharmaceuticals is described. Se-75 selenious acid is reduced with NaBH/sub 4/ producing the nucleophile NaHSe. Using this method, a fatty acid, cholesterol, estrogen and phenethylamine are all labelled with Se-75.

  14. TEST CELLS SE-5 - SE-8 - SE-10 IN THE ENGINE RESEARCH BUILDING ERB AND 117 HIGH ENERGY FUELS LABORAT

    Science.gov (United States)

    1963-01-01

    TEST CELLS SE-5 - SE-8 - SE-10 IN THE ENGINE RESEARCH BUILDING ERB AND 117 HIGH ENERGY FUELS LABORATORY HEFL - TRANSDUCER INSTRUMENTATION CONSOLE SE-10 - TEMPERATURE INSTRUMENTATION CONSOLE SE-10 - MODULE FUEL CELL EXPERIMENT SE-8 -

  15. Intraband Spectroscopy of GaSe Nanoparticles and InSe/GaSe Nanoparticle Heterojunctions

    Science.gov (United States)

    Kelley, David F.; Tu, Haohua; Chen, Xiang-Bai

    The spectroscopic and dynamical characteristics of electron and hole intraband transitions in several sizes of GaSe nanoparticles have been studied using polarized femtosecond transient absorption spectroscopy. Assignments of the observed absorptions are made in terms of the known GaSe band structure and a model in which the electron and hole states are described by particle-in-a-cylinder states. The results indicate that the transient absorption spectrum is due to a size-independent, z-polarized hole intraband transition, and in the smaller particles, an x,y-polarized electron transition. In InSe/GaSe mixed aggregates, direct electron transfer from InSe to GaSe nanoparticles occurs upon photoexcitation of a charge transfer band. An exciton on GaSe nanoparticles can undergo diffusion and charge separation the an InSe/GaSe heterojunction.

  16. Study of the heterointerfaces InSe on GaSe and GaSe on InSe

    Science.gov (United States)

    Fargues, D.; Brahim-Otsmane, L.; Eddrief, M.; Sébenne, C.; Balkanski, M.

    1993-03-01

    InSe and GaSe thin films are grown on freshly cleaved (00.1) substrates of GaSe and InSe, respectively, by molecular beam epitaxy. They are studied in situ by X-ray photoelectron spectroscopy (XPS) and reflection high energy electron diffraction (RHEED). From the attenuation curves of the XPS substrate core level peaks, the quasi layer-by-layer growth is shown during the first stages of deposition in agreement with RHEED results. But both interfaces are not totally symmetrical. For InSe on GaSe(00.1), the sharpness of the interface is shown and the conditions of growth are well established. For GaSe on InSe(00.1), the sharpness of the interface can also be suggested although it is less clear; this is related to the growth conditions.

  17. Epitaxial growth of ZnSe and ZnSe/CdSe nanowires on ZnSe

    Energy Technology Data Exchange (ETDEWEB)

    Bellet-Amalric, E.; Bounouar, S.; Kheng, K. [CEA-CNRS-UJF Group, Nanophysique et Semiconducteurs, CEA Grenoble, INAC, 17 rue des Martyrs, 38 054 Grenoble (France); Elouneg-Jamroz, M.; Bougerol, C.; Hertog, M. den; Genuist, Y.; Poizat, J.P.; Andre, R.; Tatarenko, S. [CEA-CNRS-UJF Group, Nanophysique et Semiconducteurs, Institut Neel, BP 166, 38 042 Grenoble (France)

    2010-06-15

    We report the molecular beam epitaxy (MBE) growth of ZnSe nanowires (NWs) on a ZnSe(100) epilayer assisted by gold catalyst. Gold dewetting assists in the formation of nanotrenches along the [0-1-1] direction in the ZnSe buffer layer. Nucleation of the gold catalyst in the trenches leads to the growth of NWs preferentially in directions orthogonal to the trenches. The wires adopt mostly the wurtzite type structure and grow along the c-axis. CdSe quantum dots were inserted in the ZnSe NWs. The CdSe insertions systematically adopt a cubic zinc-blende arrangement with a[111] growth axis, as confirmed by transmission electron microscopy. (copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  18. Sample Set (SE): SE12 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE12 Effect of agricultural films for spinach leaf metabolites Investigation of Spi...nacia oleracea leaf metabolites. 2 cultivars (Nihon and Wasesaradaakari), 2 growth conditions (normal film and UV film

  19. Sample Set (SE): SE30 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE30 Comparison of seed metabolites among soybean varieties Investigation of Glycin...e max. green seed metabolites. 3 varieties (Kamogawashichiri, Koitozairai, Tanbakuro) data are examined. Tak

  20. Sample Set (SE): SE26 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE26 Effect of compost for cabbage metabolites Investigation of Brassica oleracea v...ar. capitata YR Seisyun leaf metabolites. 2 growth conditions (with or without 6t compost treatment) and 3 r

  1. Sample Set (SE): SE20 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE20 Arabidopsis thaliana leaf metabolite analysis for a software test Investigatio...es that were investigated to optimize the parameters of PowerGet software for better metabolite annotation i

  2. Sample Set (SE): SE51 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE51 RIKEN tandem mass spectral database (ReSpect) for phytochemicals: A plant-spec...ochemicals was developed and named ReSpect (RIKEN tandem mass spectral database). Of the 3595 metabolites in

  3. Sample Set (SE): SE37 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE37 Medicago truncatula shoot metabolite analysis using stable isotopes Metabolite...formed to estimate the elemental composition with high reliability using the number of stable isotopes incor

  4. Sample Set (SE): SE28 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE28 Comparison of leaf metabolites among developmental stages of Hevea brasiliensi...s Investigation of Hevea brasiliensis leaf metabolites. 4 developmental stages and 6 replicates data are exa

  5. Sample Set (SE): SE48 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE48 Toward better annotation in plant metabolomics: isolation and structure elucidation of 36 special... elucidated the structures of specialized metabolites from rice by using MS/MS and NMR. Thirty-six compounds

  6. Sample Set (SE): SE55 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE55 AtMetExpress development: a phytochemical atlas of arabidopsis development We analyzed phytochem...idopsis produces various phytochemicals in a highly tissue-specific manner, which often accompanies the expr

  7. Sample Set (SE): SE10 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE10 Effect of phosphorus nutrition for cabbage metabolites Investigation of Brassi...ca oleracea var. capitata Hatukoi leaf metabolites. 3 growth conditions (high, low and no phosphorus nutrition

  8. Sample Set (SE): SE14 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE14 Effect of agricultural films for tomato fruit metabolites Investigation of Sol...anum lycopersicum fruit metabolites. 3 growth conditions (covered with normal or UV cut agricultural film or no agricultura

  9. Sample Set (SE): SE16 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE16 Effect of agricultural films for spinach leaf metabolites 2 Investigation of S...pinacia oleracea leaf metabolites. 3 growth conditions (covered with normal or UV cut agricultural film or no agricultura

  10. Sample Set (SE): SE19 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE19 Grobal triacylglycerol analysis in mouse liver and white adipose tissue (WAT) ...rol (TAG) molecular species from complex lipid mixtures of mouse liver and white adipose tissue (WAT) using

  11. Photophysics of GaSe/InSe nanoparticle heterojunctions.

    Science.gov (United States)

    Chen, Xiang-Bai; Kelley, David F

    2006-12-21

    The photophysics of mixed aggregates of GaSe/InSe nanoparticles have been studied using static and time-resolved absorption and emission spectroscopies. The results indicate that the GaSe/InSe interfaces form heterojunctions and exhibit photoinduced direct charge transfer from the GaSe valence band to the InSe conduction band. This results in the electrons and holes being localized separately in these two types of nanoparticles. The energy diagram of the nanoparticle heterojunction can be constructed from the static spectra, known bulk band offsets, and quantum confinement effects. These considerations accurately predict the energy of the observed charge-transfer band. Photoexcitation also produces excitons in the aggregates, away from the heterojunctions. These excitons can undergo diffusion and quench upon reaching a heterojunction. Time-resolved fluorescence kinetics can be modeled to extract an exciton diffusion coefficient. A value of 2.0 nm2/ns is obtained, which is in good agreement with values obtained from previous fluorescence anisotropy decay measurements.

  12. Vetenfinf se ha actualizado recientemente

    Directory of Open Access Journals (Sweden)

    Veterinaria.org

    2008-02-01

    Full Text Available ResumenSe trata de un sitio web alojado en el servidor de Veterinaria.org y mantenido por el Dr. Norberto Fondevila, del Instituto de Virologia CICVyA- INTA Cautelar de Argentina .

  13. Señas Mexicano

    Directory of Open Access Journals (Sweden)

    Juan F. García Mejía

    2007-01-01

    Full Text Available En este artículo se muestra un sistema que permite el estudio y práctica del Lenguaje de Señas Mexicano (LMS, el cual es el método de comunicación de las personas que padecen un trastorno de procesamiento auditivo. El sistema propuesto en este artículo consta de un guante de tela instrumentado con sensores de flexión, una etapa de acondicionamiento de señales y una tarjeta de adquisición de datos; que en su conjunto constituyen el Hardware. El software esta formado por un programa de adquisición de datos y una interfaz de usuario, ambos codificados en Visual Basic Net. El sistema propuesto se modela por medio del lenguaje de modelado unificado (UML, ya que Visual Basic es un lenguaje orientado a eventos.

  14. Porøse materialer

    DEFF Research Database (Denmark)

    Hansen, Ernst Jan de Place

    2000-01-01

    Dette undervisningsnotat er en samling af noter, der refererer til den indledende del af kurset Materialmekanik og Porøse materailer på Insitut for Bærende Konstruktiner og Materialer (BKM).......Dette undervisningsnotat er en samling af noter, der refererer til den indledende del af kurset Materialmekanik og Porøse materailer på Insitut for Bærende Konstruktiner og Materialer (BKM)....

  15. Sample Set (SE): SE27 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE27 Effect of agricultural films for cabbage leaf metabolites Investigation of Bra...ssica oleracea var. capitata YR Tenkuu leaf metabolites. 3 growth conditions (covered with normal or UV cut agricultura...l film or no agricultural film), 3 replicates data are examined. Takeshi Ara 1, Naoki Yamamoto 1,

  16. Sample Set (SE): SE56 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE56 MS/MS spectral tag-based annotation of non-targeted profile of plant secondary...sis, resulting in clarification of the functions of reported genes involved in glycosylation of flavonoids. Thus, non-target

  17. Sample Set (SE): SE50 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available oids We report that flavonoids with radical scavenging activity mitigate against ox...ress. These data confirm the usefulness of flavonoids for enhancing both biotic and abiotic stress tolerance...SE50 Enhancement of oxidative and drought tolerance in arabidopsis by overaccumulation of antioxidant flavon

  18. Sample Set (SE): SE58 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE58 Exploring matrix effects and quantification performance in metabolomics experiments using artificial...ificial biological gradients is a general and inexpensive tool for calibration that... the peaks but also highlights cases with strong background-dependent signal interference. Analysis of art

  19. Significados y funciones del "se"

    Directory of Open Access Journals (Sweden)

    Lidia Contreras

    2004-06-01

    Full Text Available En este artículo la autora se limita a comentar críticamente lo que la Real Academia Española de la Lengua (cit. Ac. dice en su "Gramática de la lengua española" de 1931 (Madrid, Espasa-Calpe, S. A. con respecto a los diversos tipos de "se" que ella toma en cuenta, comentario que pretende mostrar una mayor diversificación que la establecida en la mencionada obra. (In this article, its author offers a critical commentary of the position taken by The Spanish Royal Academy of Language (RAE in Gramática de la lengua española (1931 on the subject of "Uses of 'se'". The author intends to show a greater variety of uses than those proposed by RAE.

  20. Dealing with Pro Se Patrons

    Science.gov (United States)

    Pettinato, Tammy R.

    2008-01-01

    The problem of the "pro se" patrons (people who are representing themselves in a legal dispute or transaction) has received significant attention in the legal information literature, and many excellent suggestions have been offered to aid law librarians in dealing with this population group. However, these suggestions can be usefully applied in…

  1. Effect of doping on exciton states in InSe and GaSe lamellar semiconductors. [InSe:Dy; InSe:Ho; GaSe:Sn

    Energy Technology Data Exchange (ETDEWEB)

    Dzhafarova, S.Z.; Ragimova, N.A.; Abutalybov, G.I.; Guseinov, A.M.; Abdinov, A.S. (Inst. of Physics, Azerbaijan Academy of Sciences, Baku (Azerbaijan))

    1991-11-16

    Investigations of exciton luminescence and absorption spectra of InSe (GaSe) lamellar semiconductors doped with different kinds of compounds at T=1.8 K are carried out. It is found that changes in the luminescence intensity of free and bound excitons are due to screening of Coulomb interaction between electron and hole. Increase of free excitons luminescence intensity in InSe crystals activated by holmium ions is attributed to ''healing'' of metal and chalcogenide vacancies and also to interlaminar interaction increase due to exchange interaction of local formations, i.e. holmium ions. (orig.).

  2. ¿Se desindustrializa Brasil?

    Directory of Open Access Journals (Sweden)

    Fernando Mattos

    2014-01-01

    Full Text Available Este estudio pretende retomar algunos temas específicos del debate sobre la desindustrialización en Brasil, así como también, apunta a recordar algunos aspectos del debate teórico-histórico sobre la desindustrialización, presente en la literatura sobre desarrollo económico. En la primera parte, se destacan algunos elementos del referido debate presentes en la literatura especializada, discutiendo aspectos teóricos de la formulación kaldoriana que destacan el papel del crecimiento industrial y de la mudanza estructural en el crecimiento de las economías capitalistas. En la segunda, son organizados y analizados algunos indicadores recientes del desempeño del sector industrial brasileño. Finalmente, se ofrecen algunas breves notas conclusivas.

  3. Illa se iactet in aula!

    Directory of Open Access Journals (Sweden)

    Bertomeu, María Julia

    2010-06-01

    Full Text Available More than a few of Kant’s contemporaries, including some of his disciples, were sharply critical of the systematic character of his philosophy, and, markedly, of the philosophical prose in which this character was expressed. Others, on the contrary, found solace in the prospect of seeing the philosopher either isolated or trapped in the purely speculative realm of the academic room, in the good —or bad— company of all the metaphysical politicians of the time: «illa se iactet in aula!» However, fearful that the walls or the metaphorical bars of the room were not enough to contain the «popular» propagation of Kant’s ideas, they completed —in line with Burke— Virgilio’s poem, distinctly alluding to surely less symbolic bars: «Illa se iactet in aula Aeolus, et clauso ventorum carcere regnet». Kant replied in time, writing both to each group separately and to everyone at once. But he did it always from his fiercely held conviction about the importance of both a philosophical theory and a methodological discipline, which, even when «unpopular» in the beginning, he considered essential elements of a moral and political practice that was so hostile toward moral paternalism as it was to its counterpart, a (paternalistic political despotism.

    No pocos contemporáneos de Kant, incluidos algunos de sus discípulos, fueron pródigos en la crítica mordaz del carácter sistemático de su filosofía, y señaladamente, de la prosa filosófica en que ese carácter se expresaba. Otros, en cambio, no se privaron de manifestar el deseo de ver al filósofo aislado o acorralado en el recinto puramente especulativo del aula académica, en la buena —o en la mala— compañía de todos los políticos metafísicos de la época: «illa se iactet in aula!» Pero, temerosos de que los muros o los barrotes metafóricos del aula no bastaran a contener la propagación «popular» de las ideas del filósofo, completaron

  4. Standards and IAEA safety services; Las normas y los servicios de seguridad del OIEA

    Energy Technology Data Exchange (ETDEWEB)

    Gil, E.

    2009-07-01

    The International Atomic Energy Agency has the statutory mandate to develop safety standards applicable to all kind of nuclear and radiation practices and activities and to provide for its application Member States and in its own radiological practices and activities. since its inception in the mid-fifties, the IAEA has an active rulemaking program that reached full maturity in the mid-nineties and keeps today. This program is complemented by a wide variety of safety review services provided by the Agency to Member states that request it. (Author)

  5. El derecho costarricense se actualiza

    OpenAIRE

    Romero-Pérez, Jorge Enrique

    2014-01-01

    Durante muchos años el derecho costarricense se mantuvo estático, tranquilo frente a los cambios sociales, políticos, económicos, religiosos, etc. Parecía que el sistema jurídico era indiferente a la movilidad en las demás estructuras del Sistema Social. Esto, superficialmente, indujo a más de un observador, pétreo, reaccionario y resistente en las transformaciones operadas en el resto de la realidad del país. Sin embargo, tales cambios en las estructuras y en las relaciones globales paulatin...

  6. Buenas piezas. Cuando se siente

    OpenAIRE

    Martínez, Borja; Lo Siento; Molinero Domingo, Silvia

    2016-01-01

    Entrevista a Borja Martínez de Lo Siento Studio. Viajamos a Barcelona para conocer el espacio en el que Lo Siento desarrolla su trabajo. Se trata de un estudio reconocido por los proyectos de identidad gráfica, packaging, diseño editorial y especialmente valorados por la creación de atractivas tipografías. Han recibido varios Laus y Grand Laus, premios organizados por la Asociación de Diseñadores Gráficos y Directores de Arte (ADG-FAD), por ejemplo al álbum The Mill...

  7. Main: SE2PVGRP1 [PLACE

    Lifescience Database Archive (English)

    Full Text Available SE2PVGRP1 S000101 17-May-1998 (last modified) kehi SE2 (stem element 2) of bean (P.v.) GRP...1.8 gene; part of SE2 element; stem; SE2; GRP; GRP1; bean (Phaseolus vulgaris) TTNNNGTAGCTAGTGTATTTGTAT ...

  8. A transferable force field for CdS-CdSe-PbS-PbSe solid systems

    NARCIS (Netherlands)

    Fan, Zhaochuan; Koster, Rik S.; Wang, Shuaiwei; Fang, Changming; Yalcin, Anil O.; Tichelaar, Frans D.; Zandbergen, Henny W.; van Huis, Marijn A.; Vlugt, Thijs J. H.

    2014-01-01

    A transferable force field for the PbSe-CdSe solid system using the partially charged rigid ion model has been successfully developed and was used to study the cation exchange in PbSe-CdSe heteronanocrystals [A. O. Yalcin et al., "Atomic resolution monitoring of cation exchange in CdSe-PbSe heterona

  9. Se metallomics during lactic fermentation of Se-enriched yogurt.

    Science.gov (United States)

    Palomo, María; Gutiérrez, Ana M; Pérez-Conde, M Concepción; Cámara, Carmen; Madrid, Yolanda

    2014-12-01

    Selenium biotransformation by lactic acid bacteria during the preparation of Se-enriched yogurt was evaluated. The study focused on the distribution of selenium in the aqueous soluble protein fraction and the detection of selenoamino acids. Screening of selenium in Tris-buffer-urea soluble fraction was carried out by sodium dodecyl sulphate polyacrylamide gel electrophoresis after pre-fractionating with asymmetric field flow fractionation using inductively coupled plasma-mass spectrometry as the detector. Selenium-containing fractions were identified by peptide mapping using nano LC-ESI/LTQMS. Proteins such as thioredoxin, glutaredoxin, albumin, β-lactoglobulin, and lactoperoxidase were identified in the selenium-containing fraction. All these proteins were detected in both the control and the selenium-enriched yogurt except chaperones, which were only detected in the control samples. Chaperones are heat-shock proteins expressed in response to elevated temperature or other cellular stresses. Selenium may have an effect on chaperones expression in Lactobacillus. For the amino acids analysis, selenocysteine was the primary seleno-containing species.

  10. Se equivocó el masoreta ¿se equivocaba?

    Directory of Open Access Journals (Sweden)

    Fernández Tejero, Emilia

    2009-12-01

    Full Text Available This article has a didactic purpose; it is not aimed at scholars of the Masora but rather at researchers in closely associated areas. The editions of Hebrew Biblical manuscripts and critical studies that have been published recently are particularly useful tools for those who wish to delve into other areas of research such as the history of the Hebrew Biblical text, its exegesis or the origins of grammar. Here, the author concentrates on the analysis of three issues: variant formulations of a same information; coherence between a text and its Masorah, and the possible discrepancies among sources.

    Este artículo, de carácter didáctico, no está destinado a los estudiosos de la Masora, sino a investigadores de áreas cercanas. Las ediciones de manuscritos y los estudios publicados en los últimos años son instrumentos de gran utilidad para quienes deseen adentrarse en un campo de investigación con repercusión en otras áreas tales como la historia del texto bíblico hebreo, su exégesis o los inicios de la gramática. Se analizan tres cuestiones: distinta formulación para una misma noticia, coherencia entre un texto y su masora y posibles discrepancias entre las fuentes.

  11. Electrical and photovoltaic properties of Cu-doped p-GaSe/n-InSe heterojunction

    Science.gov (United States)

    Shigetomi, S.; Ikari, T.

    2000-08-01

    GaSe(Cu)/InSe heterojunctions have been formed by bringing the cleavage surface of undoped n-InSe and Cu-doped p-GaSe into direct contact. Transport and phototransport properties are studied by the measurements of capacitance-voltage, current-voltage, and the spectral response of short-circuit current. Moreover, the efficiency parameters under illumination are estimated by using the open-circuit voltage and short-circuit current. These characteristics of GaSe(Cu)/InSe heterojunctions are compared with those of GaSe(Un)/InSe heterojunctions fabricated by undoped p-GaSe and n-InSe. The series resistance of GaSe(Cu)/InSe heterojunctions is found, the value of which is about 103 times lower than the corresponding value of GaSe(Un)/InSe heterojunctions. A short-circuit current density of 9.0 mA/cm2 and an open-circuit voltage of 0.42 V on GaSe(Cu)/InSe heterojunctions are obtained under illumination of 120 mW/cm2 of a halogen lamp. The short-circuit current of GaSe(Cu)/InSe heterojunctions is about one order of magnitude lager than that of GaSe(Un)/InSe heterojunctions. These experimental results indicate that the low-resistivity of Cu-doped GaSe is effective for the electrical and photovoltaic properties of GaSe/InSe heterojunctions.

  12. Reaction kinetics of CuGaSe 2 formation from a GaSe/CuSe bilayer precursor film

    Science.gov (United States)

    Kim, W. K.; Payzant, E. A.; Kim, S.; Speakman, S. A.; Crisalle, O. D.; Anderson, T. J.

    2008-06-01

    The reaction pathway and kinetics of CuGaSe 2 formation were investigated by monitoring the phase evolution of temperature ramp annealed or isothermally soaked bilayer glass/GaSe/CuSe precursor film using time-resolved, in situ high-temperature X-ray diffraction. Bilayer GaSe/CuSe precursor films were deposited on alkali-free thin glass substrates in a migration-enhanced epitaxial deposition system. The initial CuSe phase begins to transform to β-Cu 2-xSe at around 230 °C, followed by CuGaSe 2 formation accompanied by a decrease in the β-Cu 2-xSe peak intensity at around 260 °C. Both the parabolic and Avrami diffusion-controlled reaction models represented the experimental data very well over the entire temperature range (280-370 °C) of the set of isothermal experiments with estimated activation energies of 115(±16) and 124(±19) kJ/mol, respectively. Transmission electron microscopy-energy-dispersive X-ray spectrometry (TEM-EDS) analysis suggests that CuGaSe 2 forms at the interface of the initial GaSe and CuSe layers.

  13. Heteroepitaxy of Layered Compound InSe and InSe/GaSe onto GaAs Substrates

    Science.gov (United States)

    Budiman, Maman; Yamada, Akira; Konagai, Makoto

    1998-07-01

    The van der Waals epitaxy of InSe films was performed on (111)GaAs surface at the growth temperature of 350°C. A spiral trigonal structure was observed on the surface of the InSe films. To improve crystal quality of the InSe films, their orientation control was investigated. The growth rate decreased rapidly as the growth temperature increased and no InSe films were obtained at growth temperatures higher than 480°C. At growth temperatures of 450°C and higher, a double-domain structure was observed, probably due to the coexistence of In4Se3 phase in the films. Therefore, the InSe film was directly grown on c-axis inclined GaSe, and it was revealed that InSe films were more easily grown on GaSe than on (001)GaAs surface, due to the same crystal structure. Furthermore, for fabrication of the quantum well structure, heteroepitaxial growth of GaSe/InSe/GaSe films on (001)GaAs substrate was investigated.

  14. Electron and hole dynamics in GaSe nanoparticles and GaSe-InSe nanoparticle heterojunctions.

    Science.gov (United States)

    Kelley, David F.; Tu, Haohua; Mogyorosi, Karoly; Chen, Xiang-Bai

    2006-08-01

    Femtosecond polarized transient absorption results are obtained for InSe and GaSe nanoparticles. The results indicate that the transient absorption spectrum of large GaSe particles is dominated by a size-independent, z-polarized hole intraband transition. The small particle spectra exhibit the same z-polarized hole transition and a much more intense x,y-polarized absorption that is assigned to a charge transfer transition from the conduction band to particle surface (edge) states. The intensity of this transition depends on the momentum state (Γ or M) of the electron, and Γ to M electron momentum relaxation results in a 15 ps absorption decay. These results are used to interpret analogous results obtained for mixed GaSe-InSe nanoparticle aggregates, also in the solution phase. The static absorption spectrum of the mixed aggregates exhibits a strong interparticle charge transfer absorption band at an energy slightly higher than the InSe bandgap. Photoexcitation of this band results in a polarized transient absorption spectrum and transient absorption kinetics characteristic of InSe valence band holes and GaSe conduction band electrons. This result indicates that with small GaSe particles, direct InSe to GaSe electron transfer occurs upon photoexcitation.

  15. Low temperature solution-phase growth of ZnSe and ZnSe/CdSe core/shell nanowires

    Science.gov (United States)

    Petchsang, Nattasamon; Shapoval, Liubov; Vietmeyer, Felix; Yu, Yanghai; Hodak, Jose H.; Tang, I.-Ming; Kosel, Thomas H.; Kuno, Masaru

    2011-08-01

    High quality ZnSe nanowires (NWs) and complementary ZnSe/CdSe core/shell species have been synthesized using a recently developed solution-liquid-solid (SLS) growth technique. In particular, bismuth salts as opposed to pre-synthesized Bi or Au/Bi nanoparticles have been used to grow NWs at low temperatures in solution. Resulting wires are characterized using transmission electron microscopy and possess mean ensemble diameters between 15 and 28 nm with accompanying lengths ranging from 4-10 μm. Subsequent solution-based overcoating chemistry results in ZnSe wires covered with CdSe nanocrystals. By varying the shell's growth time, different thicknesses can be obtained and range from 8 to 21 nm. More interestingly, the mean constituent CdSe nanocrystal diameter can be varied and results in size-dependent shell emission spectra.High quality ZnSe nanowires (NWs) and complementary ZnSe/CdSe core/shell species have been synthesized using a recently developed solution-liquid-solid (SLS) growth technique. In particular, bismuth salts as opposed to pre-synthesized Bi or Au/Bi nanoparticles have been used to grow NWs at low temperatures in solution. Resulting wires are characterized using transmission electron microscopy and possess mean ensemble diameters between 15 and 28 nm with accompanying lengths ranging from 4-10 μm. Subsequent solution-based overcoating chemistry results in ZnSe wires covered with CdSe nanocrystals. By varying the shell's growth time, different thicknesses can be obtained and range from 8 to 21 nm. More interestingly, the mean constituent CdSe nanocrystal diameter can be varied and results in size-dependent shell emission spectra. Electronic supplementary information (ESI) available. See DOI: 10.1039/c1nr10176e

  16. Turnover of Se in adequately fed chickens using Se-75 as a tracer.

    Science.gov (United States)

    Brandt-Kjelsen, A; Govasmark, E; Haug, A; Salbu, B

    2014-06-01

    Inorganic selenium (Se) in the form of selenite is applied to livestock to avoid Se deficiency. Selenite is, however, an artificial Se source in diets of unsupplemented chickens. It is therefore hypothesized that organic Se sources, such as Se-enriched yeast and wheat, could be a more suitable Se supply in animal nutrition, although information on the transition of Se from organic Se sources in fast-growing chickens is scarce. In this work, chickens were fed a low Se diet (0.27 ± 0.01 mg Se/kg, Se-enriched yeast) until 20 days of age, after which the Se concentration was increased to maximum concentration allowed by the poultry industry in Europe (0.5 p.p.m. Se). At the same time, a daily contribution of carrier-free (75)Se tracer from labelled wheat was administered from day 20 to 27. The chickens showed S and Se homeostasis, as the concentration of S and Se in liver, blood or kidney remained about constant, and steady state of S and Se in the other organs was reached 1 day after the diet shift. The uptake of (75)Se was readily seen in all organs. After 1 week, the depuration of the (75)Se tracer was followed, and biological half-lives and retention in individual organs were determined. The shortest biological half-lives were observed in major metabolic organs, the liver, kidney and pancreas with half-lives close to 4 days. There was a significant (p < 0.05) uptake in lung, brain and muscle that reached steady state when the administration of (75)Se was terminated. The half-life of (75)Se in heart was 9 days and 7 days in blood. The longest half-lives were observed in muscle (12 days), brain and lungs (13 days). All half-lives were shorter than in Se deplete animals.

  17. The reactivity of [PhP(Se)(mu-Se)]2 and (PhP)3Se2 towards acetylenes and cyanamides: X-ray crystal structures of some P-Se-C and P-Se-C-N heterocycles.

    Science.gov (United States)

    Bhattacharyya, Pravat; Slawin, Alexandra M Z; Woollins, J Derek

    2002-06-17

    Several unusual P-Se-C and P-Se-C-N heterocycles are formed by the reaction of [PhP(Se)(mu-Se)]2 or (PhP)3Se2 with alkynes or cyanamides, generated by the fragmentation of the organophosphorus-selenium compound and addition across the C identical to C or C identical to N triple bond of the organic substrate. X-ray crystallographic analysis reveals an unexpected diversity of structural motifs within these heterocyclic systems, including P2SeCN, P2C2Se and PC2Se2 rings.

  18. Defect studies of ZnSe nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Philipose, U; Saxena, Ankur; Ruda, Harry E [Centre for Nanotechnology, University of Toronto, 170 College Street, Toronto, ON, M5S 3E4 (Canada); Simpson, P J [Department of Physics and Astronomy, University of Western Ontario, London, ON, N6A 3K7 (Canada); Wang, Y Q; Kavanagh, K L [Department of Physics, Simon Fraser University, Burnaby, BC, V5A 1S6 (Canada)

    2008-05-28

    During the synthesis of ZnSe nanowires various point and extended defects can form, leading to observed stacking faults and twinning defects, and strong defect related emission in photoluminescence spectra. In this paper, we report on the development of a simple thermodynamic model for estimating the defect concentration in ZnSe nanowires grown under varying Se vapour pressure and for explaining the results of our experimental findings. Positron annihilation spectroscopy was used successfully for the first time for nanowires and the results support predictions from the defect model as well as agreeing well with our structural and optical characterization results. Under very high Se vapour pressure, Se nodules were observed to form on the sidewalls of the nanowire, indicating that beyond a limit, excess Se will begin to precipitate out of the liquid alloy droplet in the vapour-liquid-solid growth of nanowires.

  19. Excitons, biexcitons, and phonons in ultrathin CdSe/ZnSe quantum structures

    DEFF Research Database (Denmark)

    Gindele, F.; Woggon, Ulrike; Langbein, Wolfgang Werner

    1999-01-01

    The optical properties of CdSe nanostructures grown by migration-enhanced epitaxy of CdSe on ZnSe are studied by time-, energy-, and temperature-dependent photoluminescence and excitation spectroscopy, as well as by polarization-dependent four-wave mixing and two-photon absorption experiments....... The nanostructures consist of a coherently strained Zn1-xCdxSe/ZnSe quantum well with embedded islands of higher Cd content with sizes of a few nanometer due to strain-induced CdSe accumulation. The local increase in CdSe concentration results in a strong localization of the excitonic wave function, in an increase...

  20. Strain Compensation in Single ZnSe/CdSe Quantum Wells: Analytical Model and Experimental Evidence.

    Science.gov (United States)

    Rieger, Torsten; Riedl, Thomas; Neumann, Elmar; Grützmacher, Detlev; Lindner, Jörg K N; Pawlis, Alexander

    2017-03-08

    The lattice mismatch between CdSe and ZnSe is known to limit the thickness of ZnSe/CdSe quantum wells on GaAs (001) substrates to about 2-3 monolayers. We demonstrate that this thickness can be enhanced significantly by using In0.12Ga0.88As pseudo substrates, which generate alternating tensile and compressive strains in the ZnSe/CdSe/ZnSe layers resulting in an efficient strain compensation. This method enables to design CdSe/ZnSe quantum wells with CdSe thicknesses ranging from 1 to 6 monolayers, covering the whole visible spectrum. The strain compensation effect is investigated by high resolution transmission electron microscopy and supported by molecular statics simulations. The model approach with the supporting experimental measurements is sufficiently general to be also applied to other highly mismatched material combinations for the design of advanced strained heterostructures.

  1. Cs3Sm7Se12

    Directory of Open Access Journals (Sweden)

    Christof Schneck

    2012-01-01

    Full Text Available The title compound, tricaesium heptasamarium(III dodecaselenide, is setting a new starting point for realization of the channel structure of the Cs3M7Se12 series, now with M = Sm, Gd–Er. This Cs3Y7Se12-type arrangement is structurally based on the Z-type sesquiselenides M2Se3 adopting the Sc2S3 structure. Thus, the structural set-up of Cs3Sm7Se12 consists of edge- and vertex-connected [SmSe6]9− octahedra [dØ(Sm3+ – Se2− = 2.931 Å], forming a rock-salt-related network [Sm7Se12]3− with channels along [001] that are apt to take up monovalent cations (here Cs+ with coordination numbers of 7 + 1 for one and of 6 for the second cation. The latter cation has a trigonal–prismatic coordination and shows half-occupancy, resulting in an impossible short distance [2.394 (4 Å] between symmetrically coupled Cs+ cations of the same kind. While one Sm atom occupies Wyckoff position 2b with site symmetry ..2/m, all other 11 crystallographically different atoms (namely 2 × Cs, 3 × Sm and 6 × Se are located at Wyckoff positions 4g with site symmetry ..m.

  2. Cs(3)Sm(7)Se(12).

    Science.gov (United States)

    Schneck, Christof; Elbe, Andreas; Schurz, Christian M; Schleid, Thomas

    2012-01-01

    The title compound, tricaesium hepta-samarium(III) dodeca-selenide, is setting a new starting point for realization of the channel structure of the Cs(3)M(7)Se(12) series, now with M = Sm, Gd-Er. This Cs(3)Y(7)Se(12)-type arrangement is structurally based on the Z-type sesquiselenides M(2)Se(3) adopting the Sc(2)S(3) structure. Thus, the structural set-up of Cs(3)Sm(7)Se(12) consists of edge- and vertex-connected [SmSe(6)](9-) octa-hedra [d(Ø)(Sm(3+) - Se(2-)) = 2.931 Å], forming a rock-salt-related network [Sm(7)Se(12)](3-) with channels along [001] that are apt to take up monovalent cations (here Cs(+)) with coordination numbers of 7 + 1 for one and of 6 for the second cation. The latter cation has a trigonal-prismatic coordination and shows half-occupancy, resulting in an impossible short distance [2.394 (4) Å] between symmetrically coupled Cs(+) cations of the same kind. While one Sm atom occupies Wyckoff position 2b with site symmetry ..2/m, all other 11 crystallographically different atoms (namely 2 × Cs, 3 × Sm and 6 × Se) are located at Wyckoff positions 4g with site symmetry ..m.

  3. Doping of CdSe Nanocrystals

    Science.gov (United States)

    Jensen, John

    2003-10-01

    What happens to a nanocrystal when it is doped with electrons? We doped CdSe nanocrystals with potassium metal and sodium biphenyl, potassium and sodium acting as the charge carriers. In order to monitor the properties of the doped nanocrystals we used Electron Spin Resonance and luminescence techniques. In this poster we present findings and problems encountered in doping CdSe nanocrystals.

  4. Preparation of CdSe/ZnSe Core-shell Nanocrystal in One-step Reaction

    Institute of Scientific and Technical Information of China (English)

    FEI Xiao-fang; SHAN Gui-ye; KONG Xiang-gui; WANG Xin; ZENG Qing-hui; ZHANG You-lin

    2005-01-01

    High-quality Zn-doped CdSe core-shell nanocrystals were successfully prepared by incorporating a stoichiometric amount of Zn precursor into the CdSe reaction system, in which the Se precursor was excess and an Se-rich surface was formed. By injecting different amounts of Zn precursor, the core-shell nanocrystals demonstrated by the emission spectra were formed. The obtained Zn-doped CdSe nanocrystals exhibit a photoluminescence efficiency from 30% to 85%, which is comparable to those for the reported CdSe/ZnS, CdSe/CdS in the literature. In particular, a shell ZnSe layer with different thicknesses of ZnSe can be formed in this experiment by only changing the amount of Zn precursor added, which is simple and effective.

  5. One-step synthesis of PbSe-ZnSe composite thin film

    Science.gov (United States)

    2011-01-01

    This study investigates the preparation of PbSe-ZnSe composite thin films by simultaneous hot-wall deposition (HWD) from multiple resources. The XRD result reveals that the solubility limit of Pb in ZnSe is quite narrow, less than 1 mol%, with obvious phase-separation in the composite thin films. A nanoscale elemental mapping of the film containing 5 mol% PbSe indicates that isolated PbSe nanocrystals are dispersed in the ZnSe matrix. The optical absorption edge of the composite thin films shifts toward the low-photon-energy region as the PbSe content increases. The use of a phase-separating PbSe-ZnSe system and HWD techniques enables simple production of the composite package. PMID:21711822

  6. One-step synthesis of PbSe-ZnSe composite thin film

    Directory of Open Access Journals (Sweden)

    Abe Seishi

    2011-01-01

    Full Text Available Abstract This study investigates the preparation of PbSe-ZnSe composite thin films by simultaneous hot-wall deposition (HWD from multiple resources. The XRD result reveals that the solubility limit of Pb in ZnSe is quite narrow, less than 1 mol%, with obvious phase-separation in the composite thin films. A nanoscale elemental mapping of the film containing 5 mol% PbSe indicates that isolated PbSe nanocrystals are dispersed in the ZnSe matrix. The optical absorption edge of the composite thin films shifts toward the low-photon-energy region as the PbSe content increases. The use of a phase-separating PbSe-ZnSe system and HWD techniques enables simple production of the composite package.

  7. Synthesis and characterization of ZnSe:Fe/ZnSe core/shell nanocrystals

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Lin; Zhu, Jianguo, E-mail: yanglin_1028@163.com; Xiao, Dingquan

    2014-04-15

    High-quality ZnSe:Fe/ZnSe core/shell nanocrystals were prepared via a hydrothermal microemulsion technique. Effective surface passivation of monodisperse ZnSe:Fe nanocrystals is achieved by overcoating them with a ZnSe shell. The samples were characterized by means of XRD, EDX, TEM, PSD, XPS, photoluminescence, and Raman spectrum. The results show that the as-synthesized nanocrystals are cubic zinc blende ZnSe structure with high purity and the average particle size of ZnSe:Fe/ZnSe core/shell nanocrystal is larger than that of ZnSe:Fe core. The growth of ZnSe shell causes a small red shift in PL spectra, and then the PL quantum yield (QY) increases from 16% before shell growth to the maximum of 37% after increasing shell thickness up to 1.2 monolayers (ML). Moreover, both transverse optic (TO) and longitudinal optic (LO) phonon modes of ZnSe are shifted toward lower frequency as compared with the reported ones. -- Highlights: • ZnSe:Fe/ZnSe core/shell QDs were prepared by a hydrothermal microemulsion method. • ZnSe shell efficiently passivates surface defects by serving as a physical barrier. • The particle size and PL properties can be turned with the growth of ZnSe shell. • The luminescence efficiency and stability of QDs could be improved in this manner.

  8. Thermodynamic properties of SeS

    Energy Technology Data Exchange (ETDEWEB)

    Huang, M.D.

    1977-12-01

    Mass-spectrometry and Knudsen effusion experiments were used to study the equilibrium partial pressure of SeS formed by reaction of S/sub 2/ and Se/sub 2/ which were produced by thermally decomposing a mixture of In/sub 2/S/sub 3/ and In/sub 2/Se/sub 3/ in a Knudsen effusion cell. The heat of formation of SeS(g) was determined by the second law method to be -0.6 +- 3 kcal/mole. The entropy of formation of SeS(g) was calculated from spectrographic data in Ahmed and Barrow to be 1.5 cal/degree-mole at 298/sup 0/K.

  9. Cs2UPd3Se6

    Directory of Open Access Journals (Sweden)

    George N. Oh

    2011-02-01

    Full Text Available Dicaesium uranium(IV tripalladium(II hexaselenide, Cs2UPd3Se6, crystallizes in the space group Fmmm in the Ba2NaCu3O6 structure type. The asymmetric unit comprises the following atoms with site symmetries as shown: U1 (mm2, Cs1 (222, Cs2 (m2m, Pd1 (.m., Pd2 (2mm, Se1 (m.., and Se2 (1. This layered structure contains six edge-sharing square-planar [PdSe4] units that form a hexagon. These, in turn, edge-share with [USe6] trigonal–prismatic units, forming an extended layer parallel to (010. The layers are stacked along [010]. They are staggered, and are separated by the Cs atoms. The Cs atoms are either coordinated in a square antiprism of Se atoms or are ten-coordinate, with one square face and the opposite face hexagonal.

  10. One-step synthesis of PbSe-ZnSe composite thin film

    OpenAIRE

    2011-01-01

    Abstract This study investigates the preparation of PbSe-ZnSe composite thin films by simultaneous hot-wall deposition (HWD) from multiple resources. The XRD result reveals that the solubility limit of Pb in ZnSe is quite narrow, less than 1 mol%, with obvious phase-separation in the composite thin films. A nanoscale elemental mapping of the film containing 5 mol% PbSe indicates that isolated PbSe nanocrystals are dispersed in the ZnSe matrix. The optical absorption edge of the composite thin...

  11. A transferable force field for CdS-CdSe-PbS-PbSe solid systems

    OpenAIRE

    Fan, Zhaochuan; Koster, Rik S.; Wang, Shuaiwei; Fang, Changming; Anil O. Yalcin; Frans D. Tichelaar; Zandbergen, Henny W.; Van Huis, Marijn A.; Vlugt, Thijs J H

    2014-01-01

    A transferable force field for the PbSe-CdSe solid system using the partially charged rigid ion model has been successfully developed and was used to study the cation exchange in PbSe-CdSe heteronanocrystals [A. O. Yalcin et al., "Atomic resolution monitoring of cation exchange in CdSe-PbSe heteronanocrystals during epitaxial solid-solid-vapor growth," Nano Lett. 14, 3661-3667 (2014)]. In this work, we extend this force field by including another two important binary semiconductors, PbS and C...

  12. Al/CdSe/GaSe/C resonant tunneling thin film transistors

    Science.gov (United States)

    Qasrawi, A. F.; Kayed, T. S.; Elsayed, Khaled A.

    2017-02-01

    An Al/CdSe/GaSe/C thin film transistor device was prepared by the physical vapor deposition technique at a vacuum pressure of 10-5 mbar. The x-ray diffraction measurements demonstrated the polycrystalline nature of the surface of the device. The dc current-voltage characteristics recorded for the Al/CdSe/C and Al/CdSe/GaSe/C channels displayed a resonant tunneling diode features during the forward and reverse voltage biasing, respectively. In addition, the switching current ratio of the Al/CdSe/C increased from 18.6 to 9.62×103 as a result of the GaSe deposition on the CdSe surface. Moreover, the alternating electrical signal analyses in the frequency range of 1.0 MHz to 1.8 GHz, showed some remarkable properties of negative resistance and negative capacitance spectra of the Al/CdSe/GaSe/C thin film transistors. Two distinct resonance-antiresonance phenomena in the resistance spectra and one in the capacitance spectra were observed at 0.53, 1.04 and 1.40 GHz for the Al/CdSe/C channel, respectively. The respective resonating peak positions of the resistance spectra shift to 0.38 and 0.95 GHz when GaSe is interfaced with CdSe. These features of the thin film transistors are promising for use in high quality microwave filtering circuits and also for use as ultrafast switches.

  13. Injection of majority carriers through InSe-GaSe heterojunctions

    Energy Technology Data Exchange (ETDEWEB)

    Bakumenko, V.L.; Tagaev, V.G.

    1982-10-01

    Injection of majority carriers through heterojunction under intensive illumination conditions is discussed. Experimental results of injection of majority carriers through InSe-GaSe heterojunctions have been presented.

  14. Lattice dynamics of a simple GaSe-InSe superlattice

    Science.gov (United States)

    Schwarcz, R.; Kanehisa, M. A.

    1994-11-01

    A simple linear chain model is used to calculate the phonon dispersion curves for a superlattice composed of one layer of GaSe and one layer of InSe alternatively stacked along the c-axis. The resultant acoustic modes are essentially averages of the two constituents. Most optical modes are found to be confined in either GaSe layers of InSe layers. However, some low energy-optical modes have contributions from the two constituents.

  15. Structural and optical properties of ZnSe thin films stacked with PbSe submonolayers

    Science.gov (United States)

    Manonmani Parvathi, M.; Arivazhagan, V.; Rajesh, S.

    2014-09-01

    Structural and optical properties of Zinc Selenide (ZnSe) thin films stacked with multiple Lead Selenide (PbSe) submonolayers (ML) were studied. Thermal evaporation was preferred to produce ZnSe-PbSe thin films with the PbSe ML thickness ranges from 2.5 to 10 nm. Polycrystalline nature of the ZnSe was revealed through high resolution X-ray diffractometer measurement. The development of micro strain at the interfaces with increasing PbSe ML thickness was observed. A cross-sectional TEM image shows well-ordered periodicity and reproducibility of the layer thickness. The enhancement of optical absorption of ZnSe was identified upon stacking of PbSe ML. The evidence for quantum confinement in PbSe ML was revealed by the obtained red shift in band gap (2.5-1.8 eV) values as well as photoluminescence emission at 1,071 nm. The presence of tensile strain in the ZnSe layers upon staking of PbSe ML was discussed by the shift in LO phonon modes in Raman spectra.

  16. Thermal transport in monolayer InSe

    Science.gov (United States)

    Nissimagoudar, Arun S.; Ma, Jinlong; Chen, Yani; Li, Wu

    2017-08-01

    Two-dimensional InSe, a recently synthesized semiconductor having a moderate band gap, has gained attention due to its ultra high mobility and high photo-responsivity. In this work, we calculate the lattice thermal conductivity (κ) of monolayer InSe by solving the phonon Boltzmann transport equation (BTE) with first-principles calculated inter atomic force constants. κ of monolayer InSe is isotropic and found to be around 27.6 W m K-1 at room temperature along the in-plane direction. The size dependence of κ shows the size effect can persist up to 20 μm. Further, κ can be reduced to half by tuning the sample size to 300 nm. This low value suggests that κ might be a limiting factor for emerging nanoelectronic applications of monolayer InSe.

  17. The system SnSe-Bi

    Energy Technology Data Exchange (ETDEWEB)

    Alidzhanov, M.A.; Alizade, M.Z.; Aslanov, G.A.; Gurshumov, A.P.; Persakhova, A.Y.

    1986-10-01

    The authors study the system SnSe-Bi on annealed samples by methods of physicochemical analysis; x-ray phase, differential-thermal analysis, microstructural analysis, and measurements of the microhardness. It was established that the eutectic contains five mole % SnSe and melts at 260 C. A bounded region of the SnSe-based solid solutions exist, and the solubility of SnSe in bismuth was not observed. Anomalies in the temperature dependences of the thermo-emf and electrical conductivity of the solid solutions were determined by the phase transformations of tin monoselenide. The nature of the changes in the thermo-emf and the electrical conductivity as a function of the temperature is associated with the changes in the density and effective mass of the charge carriers.

  18. Solving the shape conundrum in $^{70}$Se

    CERN Multimedia

    We propose a multi-step Coulomb-excitation study of $^{70}$Se at HIE-ISOLDE using the $^{208}$Pb( $^{70}$Se, $^{70}$Se*)$^{208}$Pb* reaction at a safe energy of 5.0 MeV/u. We aim at a precise measurement of the $\\left \\langle 2^{+}_{1} \\hspace{0.1cm} || \\hspace{0.1cm}\\hat{E}2 \\hspace{0.1cm} || \\hspace{0.1cm}2^{+}_{ 1} \\right \\rangle$ diagonal matrix element as well as gaining information on additional matrix elements. Such information will shed light onto the shape conundrum of the 2$^{+}_{1}$ state in $^{70}$Se as well as foreseeing the opportunity for a more detailed understanding of the shape-coexistence phenomenon in this region.

  19. Optical anisotropy in GaSe

    Energy Technology Data Exchange (ETDEWEB)

    Seyhan, A.; Karabulut, O.; Akinoglu, B.G.; Aslan, B.; Turan, R. [Department of Physics, Middle East Technical University, 06531, Ankara (Turkey)

    2005-09-01

    Optical anisotropy of the layer semiconductor GaSe has been studied by photoluminescence (PL) and Fourier Transform Infrared Spectroscopy (FTIR). The PL spectra are dominated by two closely positioned emission bands resulting from the free exciton and the bound exciton connected direct band edge of GaSe. Photoluminescence and transmission spectra of GaSe crystals have been measured for two cases in which the propagation vector k is perpendicular (k perpendicular to c) and parallel to the c-axis (k//c). Peak position of the PL emission band and the onset of the transmission have been found to be significantly different for these two cases. This observed anisotropy is related to anisotropic band structure and the selection rules for the optical absorption in layered GaSe. FTIR transmission spectrum is in good agreement with PL results. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  20. Double electron capture searches in $^{74}$Se

    CERN Document Server

    Lehnert, B; Degering, D; Sommer, D; Wagner, L; Zuber, K

    2016-01-01

    A search for various double electron capture modes of $^{74}$Se has been performed using an ultralow background Ge-detector in the Felsenkeller laboratory, Germany. Especially for the potentially resonant transition into the 1204.2 keV excited state of $^{74}$Ge a lower half-life limit of $0.70\\cdot 10^{19}$ yr (90% credibility) has been obtained. Serious concerns are raised about the validity of obtained $^{74}$Se limits in some recent publications.

  1. Amphoteric CdSe nanocrystalline quantum dots.

    Science.gov (United States)

    Islam, Mohammad A

    2008-06-25

    The nanocrystal quantum dot (NQD) charge states strongly influence their electrical transport properties in photovoltaic and electroluminescent devices, optical gains in NQD lasers, and the stability of the dots in thin films. We report a unique electrostatic nature of CdSe NQDs, studied by electrophoretic methods. When we submerged a pair of metal electrodes, in a parallel plate capacitor configuration, into a dilute solution of CdSe NQDs in hexane, and applied a DC voltage across the pair, thin films of CdSe NQDs were deposited on both the positive and the negative electrodes. Extensive characterizations including scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier transform infrared (FTIR) and Raman studies revealed that the films on both the positive and the negative electrodes were identical in every respect, clearly indicating that: (1) a fraction (<1%) of the CdSe NQDs in free form in hexane solution are charged and, more importantly, (2) there are equal numbers of positive and negative CdSe NQDs in the hexane solution. Experiments also show that the number of deposited dots is at least an order of magnitude higher than the number of initially charged dots, indicating regeneration. We used simple thermodynamics to explain such amphoteric nature and the charging/regeneration of the CdSe NQDs.

  2. Compression of klockmannite, CuSe

    Science.gov (United States)

    Peiris, Suhithi M.; Pearson, Tania T.; Heinz, Dion L.

    1998-07-01

    Copper selenide (CuSe) was compressed in a diamond anvil cell at room temperature up to a pressure of 52 GPa and studied using energy dispersive x-ray diffraction and Raman spectroscopy. CuSe is nearly isostructural with copper sulfide (CuS), and a previous study indicates that copper sulfide undergoes reversible pressure-induced amorphization at 18 GPa. The intensity of the x-ray diffraction peaks for CuSe decrease slowly, however, they never completely disappear up to a pressure of 52 GPa. The third-order Birch-Murnaghan equation of state fit to the data yields K0=96.9±5.3 GPa and K0'=4.1±0.5. Vinet's universal equation of state yields essentially identical parameters. Raman spectroscopy demonstrates that upon compression, the S-S bond in CuS compresses differently than the Se-Se bond in CuSe, possibly accounting for the different high pressure behavior of these two very similar compounds.

  3. Sb2Se3 under pressure

    Science.gov (United States)

    Efthimiopoulos, Ilias; Zhang, Jiaming; Kucway, Melvin; Park, Changyong; Ewing, Rodney C.; Wang, Yuejian

    2013-01-01

    Selected members of the A2B3 (A = Sb, Bi; B = Se, Te) family are topological insulators. The Sb2Se3 compound does not exhibit any topological properties at ambient conditions; a recent high-pressure study, however, indicated that pressure transforms Sb2Se3 from a band insulator into a topological insulator above ~2 GPa; in addition, three structural transitions were proposed to occur up to 25 GPa. Partly motivated by these results, we have performed x-ray diffraction and Raman spectroscopy investigations on Sb2Se3 under pressure up to 65 GPa. We have identified only one reversible structural transition: the initial Pnma structure transforms into a disordered cubic bcc alloy above 51 GPa. On the other hand, our high-pressure Raman study did not reproduce the previous results; we attribute the discrepancies to the effects of the different pressure transmitting media used in the high-pressure experiments. We discuss the structural behavior of Sb2Se3 within the A2B3 (A = Sb, Bi; B = Se, Te) series. PMID:24045363

  4. Biomineralization of Se Nanoshpere by Bacillus Licheniformis

    Institute of Scientific and Technical Information of China (English)

    Yongqiang Yuan; Jianming Zhu; Congqiang Liu; Shen Yu; Lei Lei

    2015-01-01

    Biological dissimilatory reduction of selenite (SeO32-) to elemental selenium (Se0) is com-mon, but the mineral formation and the biogenic process remain uncertain. In this study, we examined the Se0 formation during the selenite bioreduction by Bacillus licheniformis SeRB-1 through transmis-sion electron microscope (TEM), energy-dispersive spectrometry (EDS) and X-ray absorption fine structure (XAFS) techniques. Results showed that the reduction process occurred mostly during the exponential phase and early stationary phase, whilst the elemental selenium was produced in these pe-riods. From the TEM images and polyacrylamide gel electropheresis, it is known that the Se0 granule formation is a biologically-induced type, and the cell envelopes are the main biomineralization positions, and particles may go through a process from nucleation to crystallization, under the control of mi-crobes. In fact, the minerals are spherical nanoparticles, occurring as a microcrystal or amorphous form. It is vital to recognize which kinds of proteins and/or polysaccharides act as a template to direct nanoparticle nucleation and growth? This should focus for further studies. This study may shed light on the process of formation of Se(0) nanosphere.

  5. Quando a escritura se quebra nas ondas

    Directory of Open Access Journals (Sweden)

    Cleonice Paes Barreto Mourão

    2005-12-01

    Full Text Available Desviando-se da estrutura tradicional do romance, Virginia Woolf, em As ondas, põe em cena seis vozes cujas falas executam um movimento contínuo de retração e distenção – movimento das ondas. As falas não estabelecem diálogo, apenas se tocam para um novo relance, revivem o passado contraído no presente e no futuro, cada uma delas marcada por pontos de intensidade, revivências que se repetem por não poderem ser substituídas. O cenário onde se desenrolam as falas é construído por uma narradora que limita o tempo aopercurso de um dia, sempre à beira-mar. Metáfora maior da escritura, o mar se derrama sobre as falas e aí produz um efeito de liquefação: desmancham-se os vetores do tempo, do espaço e das situações, para deixar na superfície a profusão de palavras que sobrenadam os acontecimentos revivenciados.

  6. Exciton-Phonon Scattering in CdSe/ZnSe Quantum Dots

    Institute of Scientific and Technical Information of China (English)

    张立功; 申德振; 范希武; 吕少哲

    2002-01-01

    A temperature-dependent photoluminescence measurement is performed in CdSe/ZnSe quantum dots with a ZnCdSe quantum well. We deduce the temperature dependence of the exciton linewidth and peak energy of the zero-dimensional exciton in the quantum dots and two-dimensional exciton in the CdSe wetting layer. The experimental data reveal a reduction of homogeneous broadening of the exciton line in the quantum dots in comparison with that in the two-dimensional wetting layer, which indicates the decrease of exciton and optical phonon coupling in the CdSe quantum dots.

  7. Atomistic Model of Physical Ageing in Se-rich As-Se Glasses

    Energy Technology Data Exchange (ETDEWEB)

    Golovchak,R.; Shpotyuk, O.; Kozdras, A.; Bureau, B.; Vlcek, M.; Ganjoo, A.; Jain, H.

    2007-01-01

    Thermal, optical, X-ray excited and magnetic methods were used to develop a microstructural model of physical ageing in Se-rich glasses. The glass composition As10Se90, possessing a typical cross-linked chain structure, was chosen as a model object for the investigations. The effect of physical ageing in this glass was revealed by differential scanning calorimetry, whereas the corresponding changes in its atomic arrangement were studied by extended X-ray absorption fine structure, Raman and solid-state 77Se nuclear magnetic resonance spectroscopy. Straightening-shrinkage processes are shown to be responsible for the physical ageing in this Se-rich As-Se glass.

  8. Structural Characterization Of CdSe and ZnSe Nanostructures

    Science.gov (United States)

    Bhattacharyya, B.; Kalita, P. K.; Datta, P.

    2010-10-01

    Chemically bath deposited CdSe and ZnSe powder possesses mixed type structures whereas it is hexagonal wurtzite type in thin film form. SEM images of CdSe symmetrically exhibit the growth of spherical, rod and the rose(flower) type microstructures. ZnSe shows fine grain structures. The growth of microstructures in these selenides according to the growth direction along c-axis of hexagonal wurtzite crystal. Photoluminescence shows strong blue luminescence at 414 and 437 nm in CdSe nanoparticles. ZnSe shows strong PL at 650 nm that is attributed to the strong d-native traps. The blue shifted band gap luminescence at 392 nm shows the quantum confinement in ZnSe nanoparticles.

  9. Effect of composition on optical properties of GeSe3–Sb2Se3–ZnSe thin films

    Indian Academy of Sciences (India)

    M R Balboul; H M Hosni; M A Soliman; S A Fayek

    2014-10-01

    Optical properties of the chalcogenides GeSe3, Sb2Se3, ZnSe, (GeSe3)80(Sb2Se3)20 and (GeSe3)70 (Sb2Se3)10(ZnSe)20 thin films are investigated. Incorporation of ZnSe into both GeSe3, Sb2Se3 results in amorphous (GeSe3)70(Sb2Se3)10(ZnSe)20 composition. The estimated optical energy gap, g, is found to decrease from 3.06 eV for ZnSe to 1.81 eV for (GeSe3)70(Sb2Se3)10(ZnSe)20. While, the band tail width, e, exhibits an opposite trend. The g behaviour is believed to be associated with cohesive energy, CE, as the incorporation of ZnSe lowers its value. The calculated number of the excess of Se–Se homopolar bonds is found to affect mainly the e values. The refractive index, , is discussed in terms of Wemple–DiDomenico single oscillator dispersion model in the normal dispersion region. The oscillator energy, o, and the dispersion energy, d, are determined for films under investigation.

  10. Paramagnetism in NiSe2

    Science.gov (United States)

    Inoue, Nozomu; Yasuoka, Hiroshi; Ogawa, Shinji

    1980-03-01

    The magnetic properties of a pyrite compound NiSe2 have been investigated by the 77Se NMR, the magnetic susceptibility and the specific heat measurements in the temperature range between 1.6 and 300 K. The electronic specific heat coefficient, γ, is obtained to be (8.5± 1.0) mJ/K2mol. The values of the magnetic susceptibility and the Knight shift are estimated to be 2.17× 10-4 emu/mol and +(1.0± 0.1)%, respectively, both being independent of temperature. The product of the nuclear spin-lattice relaxation time and temperature, T1T, is found to be constant with a value or 240 msec K. From these results, it is concluded that NiSe2 is one of the typical Pauli paramagnets and the usual Korringa relation holds with a relatively small exchange enhancement effect. Discussions of the origin of the hyperfine coupling constant of 77Se are also given in conjunction with the reported result of CoSe2.

  11. MoSe2 / Polyaniline Solar Cells

    Directory of Open Access Journals (Sweden)

    H.S. Patel

    2011-01-01

    Full Text Available Solar cells have been investigated since long for harnessing the solar energy. During this decade, a new direction has come up where in the polymers have been used in the fabrication of solar cells. Polyaniline is one of the polymers which has shown potential for its applications in heterostructure solar cells. This material is being used along with the semiconductors like InSe, TiO2, Si etc. to form the photosensitive interface. In this direction, we report our investigations on the use of Molybdenum diselenide (MoSe2 as photosensitive semiconducting material in MoSe2 / polyaniline solar cells. In this paper, the preparation of MoSe2 / polyaniline solar cells has been reported. Also, the photovoltage → photocurrent characteristics of this structure have been discussed in detail in this paper. The variation of different parameters of MoSe2 / polyaniline solar cells (like open circuit voltage, short circuit current, photoconversion efficiency and fill factor with the intensity of incident illuminations has been reported in this paper. In present case, the photocurrent density was found to be around 250 µA/cm2 with the photovoltage around 8.5 mV (which is low the photoconversion efficiency was found to be around 0.7 % along with the fill factor around 0.33. The efforts have been made to explain the low values of the photoconversion efficiency.

  12. PbSe Nanocrystal Excitonic Solar Cells

    KAUST Repository

    Choi, Joshua J.

    2009-11-11

    We report the design, fabrication, and characterization of colloidal PbSe nanocrystal (NC)-based photovoltaic test structures that exhibit an excitonic solar cell mechanism. Charge extraction from the NC active layer is driven by a photoinduced chemical potential energy gradient at the nanostructured heterojunction. By minimizing perturbation to PbSe NC energy levels and thereby gaining insight into the "intrinsic" photovoltaic properties and charge transfer mechanism of PbSe NC, we show a direct correlation between interfacial energy level offsets and photovoltaic device performance. Size dependent PbSe NC energy levels were determined by cyclic voltammetry and optical spectroscopy and correlated to photovoltaic measurements. Photovoltaic test structures were fabricated from PbSe NC films sandwiched between layers of ZnO nanoparticles and PEDOT:PSS as electron and hole transporting elements, respectively. The device current-voltage characteristics suggest a charge separation mechanism that Is distinct from previously reported Schottky devices and consistent with signatures of excitonic solar cells. Remarkably, despite the limitation of planar junction structure, and without film thickness optimization, the best performing device shows a 1-sun power conversion efficiency of 3.4%, ranking among the highest performing NC-based solar cells reported to date. © 2009 American Chemical Society.

  13. A transferable force field for CdS-CdSe-PbS-PbSe solid systems.

    Science.gov (United States)

    Fan, Zhaochuan; Koster, Rik S; Wang, Shuaiwei; Fang, Changming; Yalcin, Anil O; Tichelaar, Frans D; Zandbergen, Henny W; van Huis, Marijn A; Vlugt, Thijs J H

    2014-12-28

    A transferable force field for the PbSe-CdSe solid system using the partially charged rigid ion model has been successfully developed and was used to study the cation exchange in PbSe-CdSe heteronanocrystals [A. O. Yalcin et al., "Atomic resolution monitoring of cation exchange in CdSe-PbSe heteronanocrystals during epitaxial solid-solid-vapor growth," Nano Lett. 14, 3661-3667 (2014)]. In this work, we extend this force field by including another two important binary semiconductors, PbS and CdS, and provide detailed information on the validation of this force field. The parameterization combines Bader charge analysis, empirical fitting, and ab initio energy surface fitting. When compared with experimental data and density functional theory calculations, it is shown that a wide range of physical properties of bulk PbS, PbSe, CdS, CdSe, and their mixed phases can be accurately reproduced using this force field. The choice of functional forms and parameterization strategy is demonstrated to be rational and effective. This transferable force field can be used in various studies on II-VI and IV-VI semiconductor materials consisting of CdS, CdSe, PbS, and PbSe. Here, we demonstrate the applicability of the force field model by molecular dynamics simulations whereby transformations are initiated by cation exchange.

  14. Incorporation of HNO{sub 3} into GaSe and InSe

    Energy Technology Data Exchange (ETDEWEB)

    Nekrasov, O.V.; Zavrazhnov, A.Yu.; Semenov, V.N. [Voronezh State Univ. (Russian Federation)] [and others

    1994-06-01

    Gallium selenide is a congruently melting compound (T{sub m}=1100 K) with a layered hexagonal crystal structure built from consecutive Se-Ga-Ga-Se slabs. These slabs are bonded by van der Waals forces. In the literature, GaSe crystals are reported to exist in several modifications, among them {epsilon}- and {gamma}-polytypes differing in layer alternation were reliably identified. GaSe is an off-stoichiometric, cation-rich phase with a homogenity range of 47.5 - 49.5 at. % Se (at T=1113 K). The {epsilon}- and {gamma}- polytypes always coexist, and the higher is the Ga content, the stronger is the structural disorder, as evidenced by broadening of lines with non-zero index l in X-ray diffraction patterns of GaSe. Irrespective of preparation conditions, GaSe is a p-type semiconductor with a band gap of 2.03 eV. A high dislocation density (10{sup 9} - 10{sup 11} cm{sup -2}), observed by TEM, is characteristic for these crystals. In many respects, InSe is similar to GaSe. InSe is a narrow-gap semiconductor with N-type conductivity. The homogeneity range of this compound is much narrower than that of GaSe, but it is likewise displaced toward metal-rich compositions. Interlayer incorporation is known to accompany a great variety of reactions, among which the reaction of HNO{sub 3} with GaSe and InSe is of great interest.

  15. Improved photoluminescence quantum yield and stability of CdSe-TOP, CdSe-ODA-TOPO, CdSe/CdS and CdSe/EP nanocomposites

    Science.gov (United States)

    Wei, Shutian; Zhu, Zhilin; Wang, Zhixiao; Wei, Gugangfen; Wang, Pingjian; Li, Hai; Hua, Zhen; Lin, Zhonghai

    2016-07-01

    Size-controllable monodisperse CdSe nanocrystals with different organic capping were prepared based on the hot-injection method. The effective separation of nucleation and growth was achieved by rapidly mixing two highly reactive precursors. As a contrast, we prepared CdSe/CdS nanocrystals (NCs) successfully based on the selective ion layer adsorption and reaction (SILAR) technique. This inorganic capping obtained higher photoluminescence quantum yield (PLQY) of 59.3% compared with organic capping of 40.8%. Furthermore, the CdSe-epoxy resin (EP) composites were prepared by adopting a flexible ex situ method, and showed excellent stability in the ambient environment for one year. So the composites with both high PLQY of nanocrystals and excellent stability are very promising to device application.

  16. Lattice thermal conductivity of LaSe

    Energy Technology Data Exchange (ETDEWEB)

    Li, Wei, E-mail: tolwwt@163.com [School of Physics and Telecommunication Engineering, South China Normal University, 510006 Guangzhou (China); Pan, Zhong-liang; Chen, Jun-fang; He, Qin-yu [School of Physics and Telecommunication Engineering, South China Normal University, 510006 Guangzhou (China); Wang, Teng [School of Computer, South China Normal University, 510631 Guangzhou (China)

    2015-07-15

    The phonon dispersions and phonon density of states of LaSe are obtained, based on density functional perturbation theory and the norm-conserving pseudo-potential method. An anomaly in calculated phonon dispersion curves is presented and interpreted as a Kohn anomaly. The heat capacity of LaSe is calculated then. For the three-phonon process scattering, the lowest non-harmonic cubic terms of the interatomic potential are considered to obtain single-phonon relaxation rate by applying the Fermi's golden rule. For the boundary scattering, the average phonon relaxation time was obtained. Considering two kinds of phonon scattering mechanisms, we obtain the lattice thermal conductivity of LaSe.

  17. Tl2Mo9Se11

    Directory of Open Access Journals (Sweden)

    Patrick Gougeon

    2010-08-01

    Full Text Available The structure of Tl2Mo9Se11, dithallium nonamolybdenum undecaselenide, is isotypic with Tl2Mo9S11 [Potel et al. (1980. Acta Cryst. B36, 1319–1322]. The structural set-up is characterized by a mixture of Mo6Sei8Sea6 and Mo12Sei14Sea6 cluster units in a 1:1 ratio. Both components are interconnected through interunit Mo—Se bonds. The cluster units are centered at Wyckoff positions 3a and 3b (point-group symmetry overline{3}.. The two TlI atoms are situated in the voids of the three-dimensional arrangement. Two of the five independent Se atoms and the Tl atoms lie on sites with 3. symmetry (Wyckoff site 6c.

  18. Formation of CuInSe{sub 2} from Cu{sub 2}Se and In{sub 2}Se{sub 3} compounds

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Daigao [Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui (China); Wang, Deliang [Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui (China); CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui (China)

    2011-10-15

    Chalcopyrite {alpha}-CuInSe{sub 2} ({alpha}-CIS) was prepared from mixed powders of Cu{sub 2}Se and In{sub 2}Se{sub 3} by annealing in the Se- and the non-Se environments. The mechanically ground powders were in an overall amorphous state. The mechanical alloying produced Cu{sub 3}Se{sub 2} and CuSe compounds. At relatively low temperature, Cu{sub 3}Se{sub 2} decomposed, Cu{sub 2-x}Se and CuSe formed. The reaction for the formation of {alpha}-CuInSe{sub 2} occurred essentially at a temperature at {proportional_to}350 C in both the Se- and the non-Se environments. In the non-Se environment, reactions occurred by a solid-solid reaction and a certain amount of Se were released from the mixed powder, resulting in poor crystalline {alpha}-CuInSe{sub 2} powders. When annealed in the Se environment, low-melting Se-rich Cu-Se compounds were produced during reaction. The reactions occurred by a liquid-solid reaction above 450 C. Large-grained and good crystalline quality of chalcopyrite CIS with near stoichiometric atomic ratio was obtained above 450 C. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  19. Što se dogodilo gospodinu Davisonu

    Directory of Open Access Journals (Sweden)

    Una Krizmanić Ožegović

    2014-12-01

    Full Text Available Prije svega, dozvolite mi da kažem da svi osjećamo najiskreniju sućut zbog onoga što se dogodilo gospodinu Davidsonu. Naravno, nitko od nas nije mogao ni pomisliti da će sve tako završiti. To ne treba ni napominjati. Mislim, doista ne vjerujem da je bilo tko mogao predvidjeti posljedice onoga što se dogodilo. Daleko od toga da smo sjeli i proveli detaljnu analizu rizika kad smo odlučili djelovati u tome smjeru. Naravno da ne. Riječ je o spontanoj odluci, jednostavno nas je ponio trenutak. No, unatoč nedostatku podrobnije analize, mogu sa sigurnošću reći kako ovakav ishod nitko od nas nije mogao ni zamisliti. Mislim, očito da nije. Jednostavno, mi nismo takvi ljudi, nitko od nas. Mislim da se to podrazumijeva. Mislim da sa sigurnošću mogu reći kako se to uvriježilo među nekim ljudima koje je ovo pogodilo, u odnosu na kasniji tijek događaja. Uključujući i samoga gospodina Davidsona. S obzirom na sve što smo uspjeli zaključiti. Mislim, znate, neki od ljudi kojima se okružio bili su s pravom oprezni, s obzirom na ono što bismo mogli nazvati pristupom. Tako barem ja to, i dandanas, vidim: takav pristup u sadašnjem trenutku ne bi bio dobro prihvaćen, s obzirom na trenutačne okolnosti. Govorim s obzirom i u odnosu na treće strane, u ovome kontekstu. S obzirom da smo držali kako bi se izravan pristup protumačio kao neprimjeren, u odnosu na širi kontekst i povijest i tome slično.

  20. One-pot synthesis of hollow NiSe-CoSe nanoparticles with improved performance for hybrid supercapacitors

    Science.gov (United States)

    Chen, Haichao; Fan, Meiqiang; Li, Chao; Tian, Guanglei; Lv, Chunju; Chen, Da; Shu, Kangying; Jiang, Jianjun

    2016-10-01

    Hollow NiSe-CoSe samples have been synthesized for the first time via a one-pot solvothermal approach. The strategy is robust enough to synthesize NiSe-CoSe nanoparticles with different NiSe to CoSe ratios but with a similar hollow structure. Co ions in the NiSe-CoSe nanoparticles play decisive role for formation of the hollow structure; otherwise, the nanoparticles become solid for the NiSe sample. When used as the positive electroactive materials for energy storage, the NiSe-CoSe samples show excellent electrochemical activity in alkaline electrolyte. Using the synergistic effect between NiSe and CoSe, the electrochemical performance of NiSe-CoSe can be tuned by varying the NiSe to CoSe ratios. The NiSe-CoSe sample with a NiSe to CoSe ratio of 4:2 shows the best electrochemical performance in terms of superior specific capacity, improved rate capability and excellent cycling stability. In addition, the electrochemical performance of NiSe-CoSe sample with a NiSe to CoSe ratio of 4:2 is also evaluated via assembling hybrid supercapacitors with RGO, and the hybrid supercapacitor delivers both high power and energy densities (41.8 Wh kg-1 at 750 W kg-1 and 20.3 Wh kg-1 at 30 kW kg-1).

  1. Growth and structural characterizations of GaSe and GaSe:Cd single crystals

    Science.gov (United States)

    Ashkhasi, Afsoun; Gürbulak, Bekir; Şata, Mehmet; Turgut, Güven; Duman, Songül

    2017-02-01

    GaSe and GaSe:Cd single crystals used in this research were grown by using the Bridgman/Stockbarger method. All of the samples were freshly and gently cleaved with a razor blade from the grown ingots and no further polishing and cleaning treatments were required because of the natural mirror-like cleavage faces. The Samples were cleaved along the cleavage planes (001). The structure and lattice parameters of the undoped GaSe and GaSe:Cd semiconductors have been analyzed using a X-ray diffractometer (XRD), Scanning electron microscopy (SEM) and energy dispersive X-rays (EDX) techniques. It is found that GaSe and GaSe:Cd crystals have hexagonal structure, quite close 2θ peak values. XRD measurements indicate that there is an increase in peak intensities at specific annealing temperatures (500°C). Cd doping causes a significant decrease in the XRD peak intensity.

  2. {InSe}/{GaSe} heterointerfaces prepared by Van der Waals epitaxy

    Science.gov (United States)

    Lang, O.; Klein, A.; Schlaf, R.; Löher, T.; Pettenkofer, C.; Jaegermann, W.; Chevy, A.

    1995-01-01

    Epitaxial films of layered substrates can be prepared onto layered substrates even for large lattice mismatch, when the growth is attempted with the Van der Waals surfaces opposing each other (Van der Waals epitaxy). Thin epitaxial InSe(GaSe) films are prepared onto ultrahigh vacuum (UHV) cleaved GaSe(InSe) Van der Waals (0001) surfaces. The films and the heterointerface are characterized by photoelectron spectroscopy, electron diffraction and scanning tunneling microscopy (STM). High quality and stoichiometric films are obtained by direct InSe(GaSe) evaporation from a Knudsen cell at sample temperatures between 520 and 620 K. Despite a 6% lattice mismatch the deposited films are oriented with their c- and α-axis to the hexagonal substrate. The growth mostly follows the Frank-Van der Merwe mode. This rather ideal growth behaviour is related to the specific properties of the Van der Waals plane which contains no dangling bonds.

  3. El cielo se llena de santos mexicanos

    Directory of Open Access Journals (Sweden)

    Verónica Zárate Toscano

    2005-02-01

    Full Text Available Preliminares A fines del próximo mes de julio, si Dios le conserva la vida y su salud se lo permite, el Papa Juan Pablo II elevará a la categoría de Santo al indio Juan Diego en una ceremonia en la ciudad de México, culminando así un largo, discutido y tortuoso proceso de canonización. Suerte parecida corrió en su momento el criollo Felipe de Jesús; sin embargo, otros miembros de la corte celestial de origen mexicano se han elevado a los altares de manera casi vertiginosa, como es el caso de ...

  4. Dommere og religiøse symboler

    DEFF Research Database (Denmark)

    Holtug, Nils

    2012-01-01

    Om politiske kontroverser, der angår religiøse symboler i det offentlige rum i Danmark, og den måde, hvorpå idéer, der undfanges på den nationalistiske højrefløj......Om politiske kontroverser, der angår religiøse symboler i det offentlige rum i Danmark, og den måde, hvorpå idéer, der undfanges på den nationalistiske højrefløj...

  5. Synthesis of near-infrared-emitting CdTe/CdSe/ZnSe/ZnS heterostructure.

    Science.gov (United States)

    Yang, Ping

    2014-04-01

    Near-infrared-emitting quantum dots (QDs) were fabricated via organic synthesis strategies through constructing CdTe/CdSe/ZnSe/ZnS multishell heterostructure. An effective shell-coating route was developed for multishell growth on CdTe cores. Core/shell growth was monitored by absorption and photoluminescence (PL) spectroscopy and transmission electron microscopy observation. Yellow emitting CdTe cores were coated with a CdSe shell to generate type II structure. This yields core/shell QDs with red photoluminescence. The passivation by the ZnSe shell having a substantially wide bandgap confines the excitons within the CdTe/CdSe interface and isolates them from the solution environment and consequently improves the stability of the heterostructure. An additional ZnS shell was deposited around the outer layer of CdTe/CdSe/ZnSe QDs to form a heterostructure through the reaction between zinc oleate and trioctylphosphine sulfur in the crude CdTe/CdSe/ZnSe solution. By varying CdTe core size and each shell thickness, the PL wavelength of the obtained heterostructure can span from 580 to 770 nm. The PL efficiency is quenched in CdTe QDs in diluted solution but increases substantially up to 24% for CdTe/CdSe core/shell QDs. The PL efficiency of CdTe/CdSe/ZnSe/ZnS QDs with average diameter of 5.4 nm and a PL peak wavelength of 770 nm is 20%.

  6. Se activity and its effect on Cu(In,Ga)Se{sub 2} photovoltaic thin films

    Energy Technology Data Exchange (ETDEWEB)

    Contreras, Miguel A.; Repins, Ingrid; Metzger, Wyatt K.; Romero, Manuel [National Renewable Energy Laboratory, Golden, CO (United States); Abou-Ras, Daniel [Hahn-Meitner-Institut Berlin (Germany)

    2009-05-15

    We study some physical properties of CuIn{sub 1-x}Ga{sub x}Se{sub 2} thin-films fabricated by evaporation from elemental sources under various Selenium environments. Specifically, thin-films were fabricated under growth conditions such as Se deficiency, near stoichiometry and excess Se during coevaporation to investigate the impact of the Se environment on absorber film properties and ultimately the device performance. We determine the chemical activity of Se in the evaporation process has a strong influence on film macrostructure (prefered orientation) and microstructure, particularly at the grain and grain boundary level. It is shown that the optoelectronic properties at grain boundaries are affected by the Se environment used resulting in absorber thin-films with distinctive defect distribution and defect density. Consequently, the performance of the solar cells fabricated from those films is also affected by the Se environment. These effects on solar cell performance and absorber properties are reported in a (i) structural analysis of the CuIn{sub 1-x}Ga{sub x}Se{sub 2}/Mo/glass samples by X-ray and electron backscattering techniques; (ii) optolectronic radiative characteristics of the absorbers by cathode luminescence and photoluminescence studies and (iii) current-voltage, quantum efficiency and capacitance-voltage measurements for the solar cells made from the absorbers fabricated under the pre prescribed Se growth conditions. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  7. Inverse-photoemission spectroscopy of GaSe and InSe

    Science.gov (United States)

    Sporken, R.; Hafsi, R.; Coletti, F.; Debever, J. M.; Thiry, P. A.; Chevy, A.

    1994-04-01

    The lamellar semiconductors GaSe and InSe have been studied with k-resolved inverse-photoemission spectroscopy along two major symmetry directions (Γ¯ K¯ and Γ¯ M¯) of the surface Brillouin zone. Three bands with well-resolved features are observed from which the dispersion of the conduction bands can be determined with good precision. The minimum of the conduction band is found at M¯ in GaSe and at Γ¯ in InSe. These results are compared with theoretical studies using pseudopotential and tight-binding calculations.

  8. Y Se Repite = And It Repeats Itself

    Science.gov (United States)

    Katzew, Adriana

    2010-01-01

    In this article, the author discusses Y Se Repite [And It Repeats Itself], a project she conceptualized due to the growing number of Latino/a Mexican migrant workers in dairy farms in the state of Vermont. In 2006, approximately 2,000 Latinos/as--most of them undocumented Mexican migrant workers--worked throughout the state's dairy farms, yet…

  9. Enriched $^{82}$Se for the LUCIFER experiment

    CERN Document Server

    Beeman, J W; Benetti, P; Cardani, L; Casali, N; Chiesa, D; Clemenza, M; Dafinei, I; Di Domizio, S; Ferroni, F; Gironi, L; Giuliani, A; Gotti, C; Laubenstein, M; Maino, M; Nagorny, S; Nisi, S; Nones, C; Orio, F; Pagnanini, L; Pattavina, L; Pessina, G; Piperno, G; Pirro, S; Previtali, E; Rusconi, C; Schäffner, K; Tomei, C; Vignati, M

    2015-01-01

    The LUCIFER project aims at deploying the first array of enriched scintillating bolometers for the investigation of neutrinoless double-beta decay of $^{82}$Se. The matrix which embeds the source is an array of ZnSe crystals, where enriched $^{82}$Se is used as decay isotope. The radiopurity of the initial components employed for manufacturing crystals, that can be operated as bolometers, is crucial for achieving a null background level in the region of interest for double-beta decay investigations. In this work, we evaluated the radioactive content in 2.5 kg of 96.3% enriched $^{82}$Se metal, measured with a high-purity germanium detector at the Gran Sasso deep underground laboratory. The limits on internal contaminations of primordial decay chain elements of $^{232}$Th, $^{238}$U and $^{235}$U are respectively: $<$61 $\\mu$Bq/kg, $<$110 $\\mu$Bq/kg and $<$74 $\\mu$Bq/kg at 90% C.L.. The extremely low-background conditions in which the measurement was carried out and the high radiopurity of the $^{82}$...

  10. Electroreflectance study of RuSe 2

    Science.gov (United States)

    Huang, Y. S.; Lin, S. S.; Sheu, J. S.; Shen, W. M.; Pollak, Fred H.

    1990-12-01

    We report the first electrolyte-electroreflectance (EER) study of a RuSe 2 single crystal in the photon energy region of 0.9-5.5 eV. The EER spectrum exhibits differential like structure in the vicinity of interband transitions. The transition energies are determined accurately. A probable energy-band structure is constructed.

  11. VerSeDa: vertebrate secretome database

    Science.gov (United States)

    Cortazar, Ana R.; Oguiza, José A.

    2017-01-01

    Based on the current tools, de novo secretome (full set of proteins secreted by an organism) prediction is a time consuming bioinformatic task that requires a multifactorial analysis in order to obtain reliable in silico predictions. Hence, to accelerate this process and offer researchers a reliable repository where secretome information can be obtained for vertebrates and model organisms, we have developed VerSeDa (Vertebrate Secretome Database). This freely available database stores information about proteins that are predicted to be secreted through the classical and non-classical mechanisms, for the wide range of vertebrate species deposited at the NCBI, UCSC and ENSEMBL sites. To our knowledge, VerSeDa is the only state-of-the-art database designed to store secretome data from multiple vertebrate genomes, thus, saving an important amount of time spent in the prediction of protein features that can be retrieved from this repository directly. Database URL: VerSeDa is freely available at http://genomics.cicbiogune.es/VerSeDa/index.php PMID:28365718

  12. Biaxially Oriented CdSe Nanorod

    DEFF Research Database (Denmark)

    Breiby, Dag W.; Chin, Patrick T.K.; Andreasen, Jens Wenzel

    2009-01-01

    The shape, structure, and orientation of rubbing-aligned cadmium selenide (CdSe) nanorods on polymer coated glass substrates have been studied using transmission electron microscopy (TEM) and grazing incidence X-ray scattering combined with computer simulations. The nanorods are found to be of wu...

  13. VerSeDa: vertebrate secretome database.

    Science.gov (United States)

    Cortazar, Ana R; Oguiza, José A; Aransay, Ana M; Lavín, José L

    2017-01-01

    Based on the current tools, de novo secretome (full set of proteins secreted by an organism) prediction is a time consuming bioinformatic task that requires a multifactorial analysis in order to obtain reliable in silico predictions. Hence, to accelerate this process and offer researchers a reliable repository where secretome information can be obtained for vertebrates and model organisms, we have developed VerSeDa (Vertebrate Secretome Database). This freely available database stores information about proteins that are predicted to be secreted through the classical and non-classical mechanisms, for the wide range of vertebrate species deposited at the NCBI, UCSC and ENSEMBL sites. To our knowledge, VerSeDa is the only state-of-the-art database designed to store secretome data from multiple vertebrate genomes, thus, saving an important amount of time spent in the prediction of protein features that can be retrieved from this repository directly. VerSeDa is freely available at http://genomics.cicbiogune.es/VerSeDa/index.php.

  14. Señales en el agua

    Directory of Open Access Journals (Sweden)

    Helcías Martan Góngora

    1964-11-01

    Full Text Available La lluvia fue siempre compañera de la soledad. En su ámbito de música se mueve el pensamiento con monótono ritmo y el alma encuentra su centro de gravedad, mientras dura el imperio de su amada caricia.

  15. No todo lo que cuenta se cuenta

    NARCIS (Netherlands)

    van Rijckevorsel, J.

    2008-01-01

    En este trabajo publicado en "Insurance Economics" Nº 58 (Julio 2008), Jan van Rijckevorsel hace un profundo análisis del uso práctico de las estadísticas de seguros aplicadas a aspectos reales del quehacer institucional del sector, y señala varios campos (como el valor y calificación de la reputaci

  16. Reference: SE2PVGRP1 [PLACE

    Lifescience Database Archive (English)

    Full Text Available ter, domain A of the 35S promoter and the 35S2 promoter. Transgenic Res 4:388-396 (1995) PubMed: 7581519; ... ...SE2PVGRP1 Elmayan T, Tepfer M. Evaluation in tobacco of the organ specificity and strength of the rolD promo

  17. Ultra-Fast Synthesis for Ag2Se and CuAgSe Thermoelectric Materials

    Science.gov (United States)

    DUAN, H. Z.; LI, Y. L.; ZHAO, K. P.; QIU, P. F.; SHI, X.; CHEN, L. D.

    2016-10-01

    Ag2Se and CuAgSe have been recently reported as promising thermoelectric materials at room temperature. The traditional melting-annealing-sintering processes are used to grow Ag2Se and CuAgSe materials with the disadvantages of high costs of energy and time. In this work, phase-pure polycrystalline Ag2Se and CuAgSe compounds were synthesized from raw elemental powders directly by manual mixing followed by spark plasma sintering (MM-SPS) in a few minutes. The influence of SPS heating rate on the phase composition, microstructure, and thermoelectric properties, including Seebeck coefficient, electrical conductivity, and thermal conductivity, were investigated. The zTs of 0.8 at 390 K and 0.6 at 450 K are obtained for Ag2Se and CuAgSe, respectively, which is comparable with the values in the materials prepared by the traditional method. Furthermore, this ultrafast sample synthesis can significantly save material synthesis time and thus has the obvious advantage for large-scale production.

  18. Que se vea lo que se oye: a vueltas con los fonemas y las letras

    Directory of Open Access Journals (Sweden)

    Gómez del Estal Villarino, Mario

    2011-03-01

    Full Text Available Partiendo de lo que el refrán “La letra con sangre entra” viene a decir a quien se deje escucharlo, se abre una descripción de las diferencias radicales que se dan entre aprender a hablar y aprender a escribir. La relación entre ambas actividades no se puede entender sin analizar la tan extendida perversión que supone hablar lo que se escribe en vez de escribir lo que se habla. A continuación, se detallan algunos de los síntomas más frecuentes de dicha perversión, caracterizados todos por la intromisión de la conciencia en terrenos donde lo único que hace es estorbar, en especial la pronunciación pedantesca de ciertos finales silábicos o de palabra, como en traNSporte, aBStraKción, óPtico, oBjeto, fúTbol, libertaD, diGno o fraK, así como las distintas deformaciones que sufren las palabras que la ortografía académica prescribe que se escriban con la letra equis.

  19. Interaction induced dephasing of excitons in wide ZnSe/ZnMgSe single quantum wells

    DEFF Research Database (Denmark)

    Wagner, Hans Peter; Schätz, A.; Maier, R.;

    1998-01-01

    The dephasing of excitons in wide ZnSe/Zn0.94Mg0.06Se single quantum wells (SQW) is investigated by spectrally resolved, time integrated four-wave mixing (FWM). Simultaneous excitation of Is center-of-mass quantized heavy-hole and light-hole excition states leads to pronounced quantum beats. Pola...

  20. Dephasing and interaction of excitons CdSe/ZnSe islands

    DEFF Research Database (Denmark)

    Wagner, H. P.; Tranitz, H.-P.; Preis, H.;

    2000-01-01

    The dephasing of excitons in self-organized CdSe/ZnSe islands grown by molecular-beam epitaxy is investigated using spectrally resolved four-wave mixing. A distribution of dephasing times is observed, indicating the existence of localized excitons with different relaxation times at comparable...

  1. Exciton dephasing and biexciton binding in CdSe/ZnSe islands

    DEFF Research Database (Denmark)

    Wagner, Hans Peter; Tranitz, H.-P.; Preis, H;

    1999-01-01

    The dephasing of excitons and the formation of biexcitons in self-organized CdSe/ZnSe islands grown by molecular-beam epitaxy is investigated using spectrally resolved four-wave mixing. A distribution of exciton-exciton scattering efficiencies and dephasing times in the range of 0.5-10 ps...

  2. Dephasing and interaction of excitons CdSe/ZnSe islands

    DEFF Research Database (Denmark)

    Wagner, H. P.; Tranitz, H.-P.; Preis, H.

    2000-01-01

    The dephasing of excitons in self-organized CdSe/ZnSe islands grown by molecular-beam epitaxy is investigated using spectrally resolved four-wave mixing. A distribution of dephasing times is observed, indicating the existence of localized excitons with different relaxation times at comparable...

  3. Speciation of Se and DOC in soil solution and their relation to Se bioavailability.

    NARCIS (Netherlands)

    Weng, L.P.; Vega, F.A.; Supriatin, S.; Bussink, W.; Riemsdijk, van W.H.

    2011-01-01

    A 0.01 M CaCl2 extraction is often used to asses the bioavailability of plant nutrients in soils. However, almost no correlation was found between selenium (Se) in the soil extraction and Se content in grass. The recently developed anion Donnan membrane technique was used to analyze chemical speciat

  4. Optical detectors on GaSe and InSe layered crystals

    Science.gov (United States)

    Kyazym-Zade, A. G.; Agaeva, A. A.; Salmanov, V. M.; Mokhtari, A. G.

    2007-12-01

    Fast uncooled GaSe and InSe detectors that can record ultrashort (10-12 10-9 s) laser pulses in the visual and near-IR ranges are developed. The quick response of the detectors is due to rapid recombination channels with a high capture cross section present in the crystals.

  5. Isothermal currents in InSe, GaSe, and GaS single crystals

    Energy Technology Data Exchange (ETDEWEB)

    Micocci, G.; Rizzo, A.; Tepore, A.; Zuanni, F. (Lecce Univ. (Italy). Ist. di Fisica)

    1983-11-16

    Isothermal current-time measurements are performed on InSe, GaSe, and GaS single crystals. The results reveal the presence of trapping centres and their activation energies and capture cross-sections are determined. The limitations of this method for the determination of trapping parameters in crystals are also discussed.

  6. Ultrafast carrier dynamics in type II ZnSe/CdS/ZnSe nanobarbells.

    Science.gov (United States)

    Hewa-Kasakarage, Nishshanka N; El-Khoury, Patrick Z; Tarnovsky, Alexander N; Kirsanova, Maria; Nemitz, Ian; Nemchinov, Alexander; Zamkov, Mikhail

    2010-04-27

    We employ femtosecond transient absorption spectroscopy to get an insight into ultrafast processes occurring at the interface of type II ZnSe/CdS heterostructured nanocrystals fabricated via colloidal routes and comprising a barbell-like arrangement of ZnSe tips and CdS nanorods. Our study shows that resonant excitation of ZnSe tips results in an unprecedently fast transfer of excited electrons into CdS domains of nanobarbells (ZnSe tips (tau(h)= 95 ps). A qualitative thermodynamic description of observed electron processes within the classical limit of Marcus theory was used to identify a specific charge transfer regime associated with the ultrafast electron injection into CdS. Potential photocatalytic applications of the observed fast separation of carriers along the main axis of ZnSe/CdS barbells are discussed.

  7. 'Cold' crystallization in nanostructurized 80GeSe2-20Ga2Se3 glass.

    Science.gov (United States)

    Klym, Halyna; Ingram, Adam; Shpotyuk, Oleh; Calvez, Laurent; Petracovschi, Elena; Kulyk, Bohdan; Serkiz, Roman; Szatanik, Roman

    2015-01-01

    'Cold' crystallization in 80GeSe2-20Ga2Se3 chalcogenide glass nanostructurized due to thermal annealing at 380°C for 10, 25, 50, 80, and 100 h are probed with X-ray diffraction, atomic force, and scanning electron microscopy, as well as positron annihilation spectroscopy performed in positron annihilation lifetime and Doppler broadening of annihilation line modes. It is shown that changes in defect-related component in the fit of experimental positron lifetime spectra for nanocrystallized glasses testify in favor of structural fragmentation of larger free-volume entities into smaller ones. Nanocrystallites of Ga2Se3 and/or GeGa4Se8 phases and prevalent GeSe2 phase extracted mainly at the surface of thermally treated samples with preceding nucleation and void agglomeration in the initial stage of annealing are characteristic features of cold crystallization.

  8. Ab initio calculations of optical constants of GaSe and InSe layered crystals

    Science.gov (United States)

    Sarkisov, S. Yu.; Kosobutsky, A. V.; Brudnyi, V. N.; Zhuravlev, Yu. N.

    2015-09-01

    The dielectric functions, refractive indices, and extinction coefficients of GaSe and InSe layered crystals have been calculated within the density functional theory. The calculations have been performed for the values of theoretical structural parameters optimized using the exchange-correlation functional, which allows one to take into account the dispersion interactions. It has been found that optical functions are characterized by the most pronounced polarization anisotropy in the range of photon energies of ˜4-7 eV. The frequency dependences for InSe compound in the range up to 4 eV demonstrate the more pronounced anisotropy as compared to GaSe. The results obtained for GaSe crystal agree better with the experimental data as compared to the previous calculations.

  9. Anisotropy in CdSe quantum rods

    Energy Technology Data Exchange (ETDEWEB)

    Li, Liang-shi

    2003-09-01

    The size-dependent optical and electronic properties of semiconductor nanocrystals have drawn much attention in the past decade, and have been very well understood for spherical ones. The advent of the synthetic methods to make rod-like CdSe nanocrystals with wurtzite structure has offered us a new opportunity to study their properties as functions of their shape. This dissertation includes three main parts: synthesis of CdSe nanorods with tightly controlled widths and lengths, their optical and dielectric properties, and their large-scale assembly, all of which are either directly or indirectly caused by the uniaxial crystallographic structure of wurtzite CdSe. The hexagonal wurtzite structure is believed to be the primary reason for the growth of CdSe nanorods. It represents itself in the kinetic stabilization of the rod-like particles over the spherical ones in the presence of phosphonic acids. By varying the composition of the surfactant mixture used for synthesis we have achieved tight control of the widths and lengths of the nanorods. The synthesis of monodisperse CdSe nanorods enables us to systematically study their size-dependent properties. For example, room temperature single particle fluorescence spectroscopy has shown that nanorods emit linearly polarized photoluminescence. Theoretical calculations have shown that it is due to the crossing between the two highest occupied electronic levels with increasing aspect ratio. We also measured the permanent electric dipole moment of the nanorods with transient electric birefringence technique. Experimental results on nanorods with different sizes show that the dipole moment is linear to the particle volume, indicating that it originates from the non-centrosymmetric hexagonal lattice. The elongation of the nanocrystals also results in the anisotropic inter-particle interaction. One of the consequences is the formation of liquid crystalline phases when the nanorods are dispersed in solvent to a high enough

  10. Results of the IAEA's IRRS mission to Spain; Resultados de la Mision IRRS del OIEA a Espana

    Energy Technology Data Exchange (ETDEWEB)

    Lentijo Lentijo, J. C.; Mellado Jimenez, I.

    2008-07-01

    The technical directors of the CN, Isabel Mell ado and Juan Carlos Lentijo, present the detailed conclusions of the review of the Spanish regulatory system, carried out in early 2008 and published in Seville last November. (Author)

  11. Superconducting gap structure of FeSe.

    Science.gov (United States)

    Jiao, Lin; Huang, Chien-Lung; Rößler, Sahana; Koz, Cevriye; Rößler, Ulrich K; Schwarz, Ulrich; Wirth, Steffen

    2017-03-07

    The microscopic mechanism governing the zero-resistance flow of current in some iron-based, high-temperature superconducting materials is not well understood up to now. A central issue concerning the investigation of these materials is their superconducting gap symmetry and structure. Here we present a combined study of low-temperature specific heat and scanning tunnelling microscopy measurements on single crystalline FeSe. The results reveal the existence of at least two superconducting gaps which can be represented by a phenomenological two-band model. The analysis of the specific heat suggests significant anisotropy in the gap magnitude with deep gap minima. The tunneling spectra display an overall "U"-shaped gap close to the Fermi level away as well as on top of twin boundaries. These results are compatible with the anisotropic nodeless models describing superconductivity in FeSe.

  12. Chemical beam epitaxy of ZnSe

    Science.gov (United States)

    Kolodziejski, Leslie A.

    1990-10-01

    ZnSe, ZnTe, and ZnSe/ZnTe layered quantum well structures have room temperature direct energy bandgaps which span the blue/blue-green optical spectrum. These II-VI semiconductors possess significant technological potential for visible optoelectronic device applications. Both military and commercial applications are envisioned. Blue/blue-green semiconductor injection lasers for underwater to satellite communications, visible flat panel electroluminescent displays, optical disc recording using blue wavelengths to increase the density of recorded information, color laser printers, and short range domestic or industrial communications via polymer fibers are examples of frequently quoted potential markets. The magnitude in U.S. dollars offered by these varied and large commercial markets warrants substantial investment in both research time and funds to push these materials to their ultimate potential for optoelectronic device fabrication testing, and marketing. Substantial effort is currently underway in Japan and Europe with major investment in funds and manpower.

  13. Two-dimensional semiconductor HfSe{sub 2} and MoSe{sub 2}/HfSe{sub 2} van der Waals heterostructures by molecular beam epitaxy

    Energy Technology Data Exchange (ETDEWEB)

    Aretouli, K. E.; Tsipas, P.; Tsoutsou, D.; Marquez-Velasco, J.; Xenogiannopoulou, E.; Giamini, S. A.; Vassalou, E.; Kelaidis, N.; Dimoulas, A., E-mail: a.dimoulas@inn.demokritos.gr [Institute of Nanoscience and Nanotechnology, National Center for Scientific Research “Demokritos,” 15310, Aghia Paraskevi, Athens (Greece)

    2015-04-06

    Using molecular beam epitaxy, atomically thin 2D semiconductor HfSe{sub 2} and MoSe{sub 2}/HfSe{sub 2} van der Waals heterostructures are grown on AlN(0001)/Si(111) substrates. Details of the electronic band structure of HfSe{sub 2} are imaged by in-situ angle resolved photoelectron spectroscopy indicating a high quality epitaxial layer. High-resolution surface tunneling microscopy supported by first principles calculations provides evidence of an ordered Se adlayer, which may be responsible for a reduction of the measured workfunction of HfSe{sub 2} compared to theoretical predictions. The latter reduction minimizes the workfunction difference between the HfSe{sub 2} and MoSe{sub 2} layers resulting in a small valence band offset of only 0.13 eV at the MoSe{sub 2}/HfSe{sub 2} heterointerface and a weak type II band alignment.

  14. Forming Glasses from Se and Te

    Directory of Open Access Journals (Sweden)

    Pierre Lucas

    2009-10-01

    Full Text Available Despite being close neighbors on the Periodic Table, selenium and tellurium present a totally different abilities to form glasses. Se is a very good glass former, and gives rise to numerous glass compositions which are popular for their transparency in the infrared range and their stability against crystallization. These glasses can be shaped into sophisticated optical devices such as optical fibers, planar guides or lenses. Nevertheless, their transparencies are limited at about 12 μm (depending on the thickness of the optical systems due to the relatively small mass of the Se element. On the other hand, tellurium is heavier and its use in substitution for Se permits to shift the IR cutoff beyond 20 μm. However, the semimetallic nature of Te limits its glass formation ability and this glass family is known to be unstable and consequently has found application as phase change material in the Digital Versatile Disk (DVD technology. In this paper, after a review of selenide glasses and their applications, it will be shown how, in a recent past, it has been possible to stabilize tellurium glasses by introducing new elements like Ga or I in their compositions.

  15. Patrimonio cultural: lo intangible se hace tangible

    Directory of Open Access Journals (Sweden)

    William Heredia Orjuela

    2004-11-01

    Full Text Available Se presentan tres reflexiones a manera de ensayo, elaboradas por estudiantes de vii semestre de la Facultad de Administración de Empresas Turísticas y Hoteleras. El tema central que engloba los escritos es el de la responsabilidad frente al patrimonio cultural, su valoración y su relación con el turismo. En el ensayo La protección del patrimonio cultural como reflejo del ser humano, la estudiante cecilia hinosTrosa hace un llamado de atención frente al problema del tráfico ilícito de bienes que conlleva la pérdida de testimonios de la cultura humana. El escrito de la estudiante mariel cecilia hernández destaca las bondades de recuperar las tradiciones y de cómo éstas se pueden difundir a través del turismo. Por último, el estudiante William heredia hace una reflexión sobre la tangibilidad de lo intangible, en el ensayo Patrimonio Cultural: lo tangible se hace intangible, donde destaca la declaratoria del Carnaval de Barranquilla como patrimonio oral e intangible de la humanidad.

  16. Thermoelectric properties of SnSe compound

    Energy Technology Data Exchange (ETDEWEB)

    Guan, Xinhong [State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, P.O. Box 72, Beijing 100876 (China); Lu, Pengfei, E-mail: photon@bupt.edu.cn [State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, P.O. Box 72, Beijing 100876 (China); Wu, Liyuan; Han, Lihong [State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, P.O. Box 72, Beijing 100876 (China); Liu, Gang [School of Electronic Engineering, Beijing University of Posts and Telecommunications, Beijing 100876 (China); Song, Yuxin [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Wang, Shumin [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Photonics Laboratory, Department of Microtechnology and Nanoscience, Chalmers University of Technology, 41296 Gothenburg (Sweden)

    2015-09-15

    Highlights: • The electronic and thermoelectric properties of SnSe bulk material are studied. • The ZT can reach as high as 1.87 along yy and 1.6 along zz direction at 800k. • SnSe is an indirect-band material, and SOC has little effect on the band structure. • The high ZT can be attributed to the intrinsically ultralow thermal conductivity. - Abstract: A first-principles study and Boltzmann transport theory have been performed to evaluate the electronic structure and thermoelectric properties of SnSe compound. The energy band structure and density of states are studied in detail. The electronic transport coefficients are then calculated as a function of chemical potential or temperature within the assumption of the constant relaxation time. The figure of merit ZT is obtained with the use of calculated thermoelectric properties and can reach as high as 1.87 along yy and 1.6 along zz direction at 800 K. Our theoretical result agrees well with previous experimental data.

  17. Experience with the SE in Germany

    Directory of Open Access Journals (Sweden)

    Jochem Reichert

    2008-03-01

    Full Text Available A rather significant proportion of the Societas Europaeas (the European Company, or SE formed to date have had German roots. German corporate law has been enriched by an interesting alternative which meanwhile seems to have gained momentum. This contribution focuses on SEs incorporated by German entrepreneurs and provides an interesting account concerning the use of SEs in Germany in practice, such as Allianz, Fresenius, BASF and Porsche. Has the SE been used to circumvent rigid company law provisions or is it a more flexible and effective tool, perhaps, for company mobility? The practical motives behind setting up this company form are also reflected upon. These include: the facilitation of cross-border mergers; transfer of the registered office; the ‘European’ image; a more flexible form of co-determination in large companies (reduction of the number of supervisory board members; avoidance and freezing of co-determination for medium-sized enterprises; the appeal of the one-tier system and its endangerment by German co-determination; and flat and uniform structures for company groups. The author also briefly discusses some of the problems arising from the formation of SEs in Germany. He ultimately concludes that practice has shown that it is possible to work with the legal regime of the SE in Germany, which adds a new company form to those available in that Member State.

  18. One-pot synthesis of multicolor MnSe:ZnSe nanocrystals for optical coding.

    Science.gov (United States)

    Wang, Yanbin; Wang, Chunlei; Xu, Shuhong; Shao, Haibao; Jiang, Yuan; Bo, Fan; Wang, Zhuyuan; Cui, Yiping

    2014-02-01

    Though the investigation on controlling the fluorescence properties of nanocrystals (NCs) with single emission has been widely reported, few efforts were spent on adjusting the fluorescence properties of NCs with multiple emission peaks. In this work, we successfully synthesized multicolor MnSe:ZnSe NCs with multiple emission peaks and developed a simple and accurate method to realize photoluminescence (PL) spectra (or color) adjustment. The PL of MnSe:ZnSe NCs has two distinct emission peaks, the trap emission of ZnSe at 475nm and Mn(2+)-induced emission at 585nm. By adjusting the nucleation temperature, the emission color of the NCs can be encoded according to the ratio of the emission intensities at 475 and 585nm. With the nucleation temperature rising from 0 to 70°C, the PL ratio between trap emission and Mn(2+)-induced emission can be consecutively changed from (1, 3) to (1, 0.5). In addition, the trap state is deeply inside the NCs rather than on NCs surface so that the trap emission is stable during environment change. Thus, these MnSe:ZnSe NCs hold great promise as novel single-particle coding labels for biomedical imaging. Copyright © 2013 Elsevier Inc. All rights reserved.

  19. Generation of Se-fortified broccoli as functional food: impact of Se fertilization on S metabolism.

    Science.gov (United States)

    Hsu, Fu-Chen; Wirtz, Markus; Heppel, Simon C; Bogs, Jochen; Krämer, Ute; Khan, Muhammad Sayyar; Bub, Achim; Hell, Rüdiger; Rausch, Thomas

    2011-02-01

    Selenium (Se)-fortified broccoli (Brassica oleracea var. italica) has been proposed as a functional food for cancer prevention, based on its high glucosinolate (GSL) content and capacity for Se accumulation. However, as selenate and sulphate share the initial assimilation route, Se fertilization could interfere with sulphur metabolism and plant growth. Consequently, GSL accumulation could be compromised. To evaluate these potentially adverse effects of Se fertilization, we performed a comprehensive study on sand-grown young broccoli plants (weekly selenate applications of 0.8 µmol plant(-1) via the root) and field-grown adult broccoli plants during head formation (single foliar selenate application: 25.3 or 253 µmol plant(-1) ). The results show that under these conditions, Se application does not affect plant growth, contents of cysteine, glutathione, total GSL, glucoraphanin (major aliphatic GSL) or the expression of BoMYB28 (encoding a functionally confirmed master regulator for aliphatic GSL biosynthesis). Conversely, due to the changed expression of sulphate transporters (BoSULTR1;1, 1;2, 2;1, and 2;2), sulphate and total S contents increased in the shoot of young plants while decreasing in the root. We conclude that broccoli can be fertilized with Se without reduction in GSL content, even with Se accumulation exceeding the level recommended for human consumption.

  20. ZnCdSe/ZnSe quantum-dot semiconductor optical amplifiers

    Science.gov (United States)

    Al-Mossawi, Muwaffaq Abdullah

    2017-02-01

    Gain of CdZnSe quantum dot (QD) semiconductor optical amplifiers (SOAs) is studied theoretically using non-Markovian gain model including many-body effects. The calculations are done at three mole fractions. Spontaneous emission and noise figure of the amplifier are studied. The effect of shot noise is included. High gain, polarization independence, and low noise figure are characterize these QD-SOAs. A multi-mode gain appears for Zn0.69Cd0.31Se structure while the structure Zn0.6Cd0.4Se give a low noise.

  1. Optical nonlinearities in GaSe and InSe crystals upon laser excitation

    Science.gov (United States)

    Kyazym-zade, A. G.; Salmanov, V. M.; Guseinov, A. G.; Gasanova, L. G.; Mamedov, R. M.

    2014-04-01

    The nonlinear absorption of light and its temporal evolution in the vicinity of exciton resonance in layered GaSe and InSe crystals under high optical excitation have been experimentally investigated. The decisive factor for the observed temporal dependence of the absorption coefficient and its dependence on the excitation intensity is screening excitons by nonequilibrium-carrier plasma. It is shown that the increase in the transmittance in the absorption-band edge in GaSe with a simultaneous blue shift of the band edge is caused by filling the energy bands under high optical excitation.

  2. Highly luminescent CdSe/ZnSe core-shell quantum dots of one-pot preparation in octadecene

    NARCIS (Netherlands)

    Zeng, Q.; Kong, X.; Zhang, Y.; Zhang, H.

    2008-01-01

    CdSe/ZnSe core-shell quantum dots were synthesized using a new one-pot procedure where the core was prepared in octadecene. A ZnSe shell around a CdSe nanoparticle was formed by the reaction of selenium-richness on the surfaces of CdSe nanoparticles with Zn2+ from the injected zinc stearate precurso

  3. Highly luminescent CdSe/ZnSe core-shell quantum dots of one-pot preparation in octadecene

    NARCIS (Netherlands)

    Zeng, Q.; Kong, X.; Zhang, Y.; Zhang, H.

    2008-01-01

    CdSe/ZnSe core-shell quantum dots were synthesized using a new one-pot procedure where the core was prepared in octadecene. A ZnSe shell around a CdSe nanoparticle was formed by the reaction of selenium-richness on the surfaces of CdSe nanoparticles with Zn2+ from the injected zinc stearate

  4. 77Se nuclear magnetic resonance of topological insulator Bi2Se3

    Science.gov (United States)

    Georgieva, Nataliya M.; Rybicki, Damian; Guehne, Robin; Williams, Grant V. M.; Chong, Shen V.; Kadowaki, Kazuo; Garate, Ion; Haase, Jürgen

    2016-05-01

    Topological insulators constitute a new class of materials with an energy gap in the bulk and peculiar metallic states on the surface. We report on new features resulting from the bulk electronic structure, based on a comprehensive nuclear magnetic resonance (NMR) study of 77Se on Bi2Se3 and Cu0.15Bi2Se3 single crystals. First, we find two resonance lines and show that they originate from the two inequivalent Se lattice sites. Second, we observe unusual field-independent linewidths and attribute them to an unexpectedly strong internuclear coupling mediated by bulk electrons. In order to support this interpretation, we present a model calculation of the indirect internuclear coupling and show that the Bloembergen-Rowland coupling is much stronger than the Ruderman-Kittel-Kasuya-Yosida coupling. Our results call for a revision of earlier NMR studies and add information concerning the bulk electronic properties.

  5. Temperature dependence of excitonic transition in ZnSe/ZnCdSe quantum wells

    Institute of Scientific and Technical Information of China (English)

    GUO Zi-zheng; LIANG Xi-xia; BAN Shi-liang

    2005-01-01

    A theoretical calculation for the temperature dependence of the excitonic transition in ZnSe/ZnCdSe quantum wells is performed. The exciton binding energy is calculated with a variational technique by considering the temperature-dependence parameters. Our results show that the exciton binding energy reduces linearly with temperature increasing. We find that the strain due to lattice mismatch and differential thermal expansion decreases with the temperature increasing.

  6. Hjem og arbejde for hjemløse og arbejdsløse EU medborgere

    DEFF Research Database (Denmark)

    Ravnbøl, Camilla Ida

    2015-01-01

    belyses hvor meget arbejde og hjem betyder for denne gruppe af formelt hjemløse og arbejdsløse EU medborgere. Udgangspunktet er etnografisk materiale, som viser roma kvinder og mænds erfaringer med at opretholde hjemmet i Rumænien, skabe sig et trygt hjem på gaden samt at søge efter arbejde og arbejde med...

  7. Pintuco se internacionaliza en el mercado andino.

    Directory of Open Access Journals (Sweden)

    Carlos Enrique Ramírez R.

    2004-01-01

    Full Text Available La historia de la internacionalización de Pintuco está presentada en este trabajo. Es importante resaltar la valiosa información sobre el mercado mundial de pinturas lo cual despierta el interés del lector al mostrar el tamaño del mercado y la importancia económica del mismo. De igual forma, la introducción es muy expedita al señalar cuál es la tendencia de dicho mercado, pues con esto se puede hacer una idea de hacia dónde deberá ir Pintuco y cuáles serán sus principales retos a superar. Luego de dar un vistazo general de lo que son las pinturas y su impacto económico, el artículo continúa con la historia del Grupo Inversiones Mundial (GIM, ente económico que ha triunfado gracias a la tenacidad de sus directivos desde 1921. La estrategia utilizada por la empresa colombiana es explicada a través de los ejemplos de cómo empezó y se desarrolló en Venezuela y Ecuador, principalmente. Y es en esto, en lo que precisamente radica lo más importante del trabajo pues sirve como motivación y como ejemplo a seguir. Las empresas colombianas como Pintuco han entendido que una de las formas de amoldarse a las nuevas tendencias del mundo empresarial es la de competir con calidad, pero no sólo en su propio mercado, sino también en el mercado de origen de su competencia. Hoy en día las fronteras son cada vez más invisibles y eso, más que una amenaza, debería ser un atractivo.

  8. Conduction band offset determination between strained CdSe and ZnSe layers using DLTS

    Science.gov (United States)

    Rangel-Kuoppa, Victor-Tapio

    2013-12-01

    The conduction band offset between strained CdSe layers embedded in unintentionally n-type doped ZnSe is measured and reported. Two samples, consisting of thirty Ultra Thin Quantum Wells (UTQWs) of CdSe embedded in ZnSe, grown by Atomic Layer Epitaxy, are used for this study. The thicknesses of the UTQWs are one and three monolayers (MLs) in each sample, respectively. As expected, the sample with one ML UTQWs does not show any energy level in the UTQWs due to the small thickness of the UTQWs, while the thickness of the sample with 3 ML UTQWs is large enough to form an energy level inside the UTQWs. This energy level appears as a majority trap with an activation energy of 223.58 ± 9.54 meV. This corresponds to UTQWs with barrier heights (the conduction band offset) between 742 meV and 784 meV. These values suggest that the band gap misfit between strained CdSe and ZnSe is around 70.5 to 74 % in the conduction band.

  9. Conduction band offset determination between strained CdSe and ZnSe layers using DLTS

    Energy Technology Data Exchange (ETDEWEB)

    Rangel-Kuoppa, Victor-Tapio [Institute of Semiconductor and Solid State Physics, Johannes Kepler Universität, A-4040 Linz (Austria)

    2013-12-04

    The conduction band offset between strained CdSe layers embedded in unintentionally n-type doped ZnSe is measured and reported. Two samples, consisting of thirty Ultra Thin Quantum Wells (UTQWs) of CdSe embedded in ZnSe, grown by Atomic Layer Epitaxy, are used for this study. The thicknesses of the UTQWs are one and three monolayers (MLs) in each sample, respectively. As expected, the sample with one ML UTQWs does not show any energy level in the UTQWs due to the small thickness of the UTQWs, while the thickness of the sample with 3 ML UTQWs is large enough to form an energy level inside the UTQWs. This energy level appears as a majority trap with an activation energy of 223.58 ± 9.54 meV. This corresponds to UTQWs with barrier heights (the conduction band offset) between 742 meV and 784 meV. These values suggest that the band gap misfit between strained CdSe and ZnSe is around 70.5 to 74 % in the conduction band.

  10. Schilddrüse und Schwangerschaft

    Directory of Open Access Journals (Sweden)

    Zettinig G

    2009-01-01

    Full Text Available Kinderwunsch, Schwangerschaft und die Zeit nach einer Geburt sind besondere Lebensabschnitte bei Patientinnen mit Schilddrüsenerkrankungen. Bei jungen Frauen sind Autoimmunerkrankungen der Schilddrüse, die Einfluss auf die Fruchtbarkeit und die intellektuelle und körperliche Entwicklung des Fetus haben können, häufig. Schilddrüsenerkrankungen können sich in dieser Lebensphase auch erstmals manifestieren; besondere Beachtung verdient die Wechselwirkung von β-HCG mit dem TSH-Rezeptor. Diese Übersicht behandelt das aktuelle Management von Patientinnen mit Schilddrüsenerkrankungen bei Kinderwunsch, in der Schwangerschaft und Postpartalperiode.

  11. Patrimonio cultural: lo intangible se hace tangible

    OpenAIRE

    William Heredia Orjuela

    2004-01-01

    Se presentan tres reflexiones a manera de ensayo, elaboradas por estudiantes de vii semestre de la Facultad de Administración de Empresas Turísticas y Hoteleras. El tema central que engloba los escritos es el de la responsabilidad frente al patrimonio cultural, su valoración y su relación con el turismo. En el ensayo La protección del patrimonio cultural como reflejo del ser humano, la estudiante cecilia hinosTrosa hace un llamado de atención frente al problema del tráfico ilícito de bienes q...

  12. Leishmaniasis visceral: senderos que confluyen, se bifurcan

    OpenAIRE

    Oscar Daniel Salomón; Andrea Verónica Mastrángelo; María Soledad Santini; Silvina Ruvinsky; Tomás Orduna; Angel Sinagra; Concepción Luna; Adelina Riarte; Natalia Casas; Paola Amiotti

    2012-01-01

    La leishmaniasis visceral urbana es una zoonosis emergente en Argentina. En América es producida por Leishmania infantum, con el perro como reservorio principal e insectos flebotomíneos como vectores. En este artículo se presenta el conocimiento acumulado a partir de su emergencia y dispersión en el país, por los referentes del Programa Nacional de Leishmaniasis, en el diagnóstico clínico y de laboratorio, tratamiento, biología de vectores, manejo de reservorio, y el conflicto generado con la...

  13. Vacancy defects in epitaxial thin film CuGaSe2 and CuInSe2

    OpenAIRE

    Korhonen, E.; Kuitunen, K.; Tuomisto, Filip; Urbaniak, A.; Igalson, M.; Larsen, J.; Gutay, L; Siebentritt, S; Tomm, Y.

    2012-01-01

    Epitaxial thin film CuGaSe2 and CuInSe2 samples grown on GaAs substrates with varying [Cu]/[Ga,In] ratios were studied using positron annihilation Doppler-broadening spectroscopy and were compared to bulk crystals. We find both Cu monovacancies and Cu-Se divacancies in CuInSe2, whereas, in CuGaSe2, the only observed vacancy defect is the Cu-Se divacancy. Peer reviewed

  14. Lo que se debe a las cimentaciones

    Directory of Open Access Journals (Sweden)

    Oroviogoicoechea, Alberto

    1975-05-01

    Full Text Available This article describes: the problems that arise when the foundations has to act on soils with low consistency or when very narrow tolerances have to be met; the origin of the above mentioned problems; the requirements that are not really necessary, with suitable examples; the absolute and relative admissible magnitudes of differential settlements in concrete structures, walls, partitions and metal structures; the tolerances for mechanical installations; recommendations for projects and a table that sums up the proposed tolerances for relative foundations.En el artículo se describen: los problemas que surgen cuando la cimentación ha de actuar sobre terrenos poco consistentes o cuando se quieren cumplir tolerancias muy estrechas; de dónde provienen dichos problemas; las exigencias que no son realmente necesarias, con ejemplos apropiados; las magnitudes absolutas y relativas admisibles de asientos diferenciales, en estructuras de hormigón, muros, tabiques y estructuras metálicas; las tolerancias para instalaciones mecánicas; recomendaciones para proyecto, y una tabla que recoge las tolerancias propuestas para asientos relativos.

  15. Cuando la ciencia se adorna de colores

    Directory of Open Access Journals (Sweden)

    César Arana

    2013-05-01

    Full Text Available La conservación de la biodiversidad ha dejado de ser un tema de discusión únicamente en círculos científicos e intelectuales, para convertirse en un tema de noticia diaria. Esto ha llevado entre otras cosas a la creación de instrumentos de información para todos los agentes sociales de las áreas geográficas donde se pretende establecer proyectos de explotación de recursos, en particular para las comunidades campesinas e indígenas. La única manera de apreciar y valorar un recurso es conociéndolo, a pesar de ello la información de nuestra mayor riqueza, la biodiversidad, sólo se ha venido restringiendo a las comunicaciones especializadas que circulan en la comunidad científica, dejando de lado a los agentes sociales y políticos de los cuales dependen las decisiones sobre la explotación sustentable de los recursos. Es por esto que publicaciones como la comentada aquí tienen mucha importancia, porque teniendo como principal objetivo la divulgación, no dejan de ser importante fuente de información y herramienta de trabajo para futuros estudios, así como información básica para proyectos de manejo de recursos naturales y ecoturismo.

  16. Resepsies van Catullus se Carmen XLIX

    Directory of Open Access Journals (Sweden)

    J. Swanepoel

    1984-05-01

    Full Text Available Gaius Valerius Catullus (c. 84-c. 54 v.C., die Romeinse digter wat veral bekend is vir sy verse aan sy geliefde Lesbia, het benewens liefdesgedigte ook ’n hele aantal verse geskryf waarin van sy lydgenote figureer. Hierdie gedigie wat aan spesifieke persone gerig is, is wyd uiteenlopend en die toon en strekking daarvan wissel van toegeneentheid en liefde enersyds (vgl. Carmen IX tot felie invektief (Carmina CVIII, XCIII en spot (Carmen LXXXIV andersyds. Die leser kan gewoonlik maklik vasstel of hy in ’n gedig met vriend of vyand te doen liet. Maar daar is een uitsondering, en dit is Catullus se gedig aan die Romeinse staatsman, retor en skrywer, Marcus Tullius Cicero. Hierdie gedig, wat soos die meeste van Catullus se gedigte heel kort en kragtig is, is deur die eeue op uiteenlopende en botsende wyses geinterpreteer. Enersyds word dit beskou as ’n opregte dankbetuiging en lofprysing aan Cicero, terwyl ander lesers dit weer sien as ’n gedig wat ironies bedoel is.

  17. Leishmaniasis visceral: senderos que confluyen, se bifurcan

    Directory of Open Access Journals (Sweden)

    Oscar Daniel Salomón

    2012-01-01

    Full Text Available La leishmaniasis visceral urbana es una zoonosis emergente en Argentina. En América es producida por Leishmania infantum, con el perro como reservorio principal e insectos flebotomíneos como vectores. En este artículo se presenta el conocimiento acumulado a partir de su emergencia y dispersión en el país, por los referentes del Programa Nacional de Leishmaniasis, en el diagnóstico clínico y de laboratorio, tratamiento, biología de vectores, manejo de reservorio, y el conflicto generado con las acciones recomendadas en relación con los perros infectados. La detección temprana y el tratamiento precoz, con estrategias descentralizadas y horizontales, contribuirán a disminuir la morbimortalidad asociada a la leishmaniasis visceral. El control de su transmisión y dispersión requiere de un manejo ambiental integral y la tenencia responsable de perros. Se discuten los intereses y discursos en conflicto generados por la leishmaniasis visceral en el marco de la relación humano-perro, proponiendo la búsqueda de un discurso consensuado de riesgo.

  18. Se il filosofo ha un compito

    Directory of Open Access Journals (Sweden)

    Carmine Di Martino

    2011-01-01

    Full Text Available Il testo muove da una ricognizione dello “stile” complessivo dell’interrogazione filosofica contemporanea: stile decostruttivo, che si risolve in un’illustrazione del limite istitutivo e costitutivo di ogni dire filosofico (e non solo filosofico. In un secondo tempo del suo intervento, l’autore si chiede se una tale comprensione, puramente “negativa”, di quel limite e della validità della parola che ne discende, non sia essa stessa ideologica, e se non sia possibile frequentare una definizione positiva di tale limite, e una possibilità non soltanto autodecostruttiva della parola filosofica “dopo” Nietzsche, Heidegger, Derrida.

  19. Fabrication and characterization of CuInSe{sub 2} thin films from In{sub 2}Se{sub 3} and Cu{sub 2}Se precursors

    Energy Technology Data Exchange (ETDEWEB)

    Song, Jin Soo [Korea Inst. of Energy and Resources, Daeduk (Korea, Republic of); Huh, Gyung Jae; Kwon, Se Han; Ahn, Byung Tae [Korea Advanced Energy Research Inst., Daeduk-Danji (Korea, Republic of). Korea Nuclear Safety Center

    1995-12-01

    CuInSe{sub 2} this films as a light absorber layer were fabricated by vacuum evaporation using In{sub 2}Se{sub 3} and Cu{sub 2}Se precursors and their properties were analyzed. Indium selenide films of 0.5{mu}m thickness were first deposited by vacuum evaporation of In{sub 2}Se{sub 3} on a Corn ing 7059 glass substrate. The films deposited at susceptor temperature of 400 degree showed a flat surface morphology with densely packed grain structure. CuInSe{sub 2} films directly formed by evaporating Cu{sub 2}Se in the pre-deposited In{sub 2}Se{sub 2} films also showed a very flat surface when the susceptor temperature was 700 degree. Cu{sub 2}Se, a second phase in the CuInSe{sub 2} film, was removed by evaporating additional In{sub 2}Se{sub 3} on the CuInSe{sub 2} film at 700 degree. The grain size of 1.2{mu}m thick CuInSe{sub 2} film was about 2{mu}m and the film had a (112) preferred orientation. As the amount of deposited In{sub 2}Se{sub 3} increased, the electrical resistivity of CuInSe{sub 2} films increased because of the decrease of hole concentration. But the optical band gap was almost constant at the value of 1.04 eV. The CuInSe{sub 2} film grown in a Mo/glass substrate had a similar smooth microstructure compared to that on a glass substrate. A solar cell with ZnO/CdS/CuInSe{sub 2}/Mo structure may be realized based on the above CuInSe{sub 2} films. (author). 16 refs., 11 figs.

  20. Escuela para señoritas, Inglaterra

    Directory of Open Access Journals (Sweden)

    Stillman y Eastwlck-Field, Arquitectos

    1963-02-01

    Full Text Available The object was to design part of a new building which had been seriously damaged during the war, so that the old and new parts would blend into a pleasant whole, with a capacity for 600 girls. The new designs avoid the glass box style of school buildings, and glass walls have been adopted only on the ground floor, thus giving an impression of light and airiness to what used to be a partial basement. Classrooms have been designed in a simple manner, and give the impression of conventional rooms. Simple lines and materials have been chosen throughout. Strong contrasts in the external finish have been avoided, and colours provide a relaxing background to the intensive activities of the students. A constructional feature is the use of prefabricated concrete joists and supports. Outer walls consist of brick panels filling in the space between the visible concrete framework. Ceilings are of insulating boards, and the floors are covered with linoleum. Special attention has been devoted to the hall. In this case the roof is of white gypsum, and the only features are the grills covering the fluorescent lighting. The walls of this hall are of glass, and are covered with heavy velvet curtains. A balcony with hardwood posts adds a simple and friendly feature to the building. The furniture and drapery have been carefully chosen. Camden school has a rigid tradition of individualism and fine education, and the new building has succeeded in maintaining the exclusive quality of the older parts, as well as offering an overall impression of up to date construction.El problema consistía en proyectar un nuevo núcleo para un edificio que había sido seriamente bombardeado durante la guerra, de tal modo que las partes antiguas y nuevas formasen un conjunto agradable y con capacidad para más de 600 chicas. En la nueva construcción se ha evitado el carácter de «cajas de cristal» de las nuevas escuelas ordinarias y se han empleado muros de cristal solamente en la

  1. Bio-fortification and isotopic labelling of Se metabolites in onions and carrots following foliar application of Se and 77Se

    DEFF Research Database (Denmark)

    Kápolna, Emese; Laursen, Kristian H.; Husted, Søren;

    2012-01-01

    that foliar application of Se(IV) gave rise to bio-synthesis of a higher fraction of the desired organic Se species and was better tolerated by the plants than Se(VI). Based on these findings onions and carrots were bio-fortified by foliar application of a solution of 77Se(IV) that was enriched to 99.7% as 77...

  2. The CuInSe{sub 2}-CuGaSe{sub 2}-2CdSe system and crystal growth of the {gamma}-solid solutions

    Energy Technology Data Exchange (ETDEWEB)

    Marushko, L.P., E-mail: marushko777@mail.r [Department of General and Inorganic Chemistry, Volyn National University, Voli Ave 13, Lutsk 43009 (Ukraine); Romanyuk, Y.E. [Swiss Federal Laboratories for Materials Testing and Research, EMPA, Uberlandstrasse 129, CH-8600 Duebendorf (Switzerland); Piskach, L.V.; Parasyuk, O.V.; Olekseyuk, I.D. [Department of General and Inorganic Chemistry, Volyn National University, Voli Ave 13, Lutsk 43009 (Ukraine); Volkov, S.V.; Pekhnyo, V.I. [V.I. Vernadskii Institute for General and Inorganic Chemistry of the Ukrainian National Academy of Sciences, Palladina Ave 32-34, Kyiv 03680 (Ukraine)

    2010-08-27

    Phase equilibria in the CuInSe{sub 2}-CuGaSe{sub 2}-2CdSe system are studied using differential-thermal analysis and phase X-ray diffraction. An isothermal section of the system at 870 K, and phase diagrams of polythermal sections CuInSe{sub 2}-CuGaSe{sub 2} and 'CuCd{sub 2}InSe{sub 4}'-CuCd{sub 2}GaSe{sub 4} have been constructed. The 'CuCd{sub 2}InSe{sub 4}'-CuCd{sub 2}GaSe{sub 4} section is not quasi-binary and includes two solid solution regions with the wurtzite and sphalerite structure-types. Eleven crystals of the {gamma}-solid solutions with the sphalerite structure-type were grown by the Bridgman technique. The non-quasi-binary nature of the 'CuCd{sub 2}InSe{sub 4}'-CuCd{sub 2}GaSe{sub 4} section gives rise to compositional gradients for copper, cadmium, and gallium along the crystal growth direction so that the crystal tip is enriched with CdSe. Band gap of the grown crystals varies from 1.05 eV to {approx}1.30 eV.

  3. Seán MacDiarmada

    Directory of Open Access Journals (Sweden)

    Madden

    2016-12-01

    Full Text Available Seán MacDiarmada: Signatory to Proclamation – Executed after the Rising of 1916 - Leitrim to Kilmainham was written by Tom Madden to coincide with the 1916/2016 centenary commemorations. The play was first performed at the Mullagh Arts Festival in Cavan during September 2016 and provides a lively account of the background and activism of one the seven leaders of the Easter Rising of 1916. The action plays out over twelve scenes taking in MacDiarmada's journey from teacher to revolutionary activist culminating in a deeply flawed court-martial and his subsequent execution by a British Army firing squad on May 12th, 1916.

  4. Models of GexSe1-x

    Science.gov (United States)

    Malouin, Marc-André.; Mousseau, Normand

    2008-03-01

    We present numerical models of chalcogenide glasses constructed using the effective two and three body interaction potential developed by Mauro and Varshneya [1] combined with the activation-relaxation technique (ART nouveau) [2]. Structures are prepared starting from a random distribution, avoiding biases and crystalline remnants. Structural properties are studied mainly via characteristic system measurements including partial and total radial distribution functions, bond angle distributions, mean coordinations and bonds population. Results are shown for GexSe1-x for various x concentrations and compared to both experimental measurements and ab initio simulation results. [1] J.C. Mauro and A.K. Varshneya, J. Am. Ceram. Soc., 89 [7] 2323-6 (2006). [2] R. Malek and N. Mousseau, Phys. Rev. E 62, 7723 (2000).

  5. Ecuador: cuando la inestabilidad se vuelve estable

    Directory of Open Access Journals (Sweden)

    Pachano , Simón

    2005-09-01

    Full Text Available El presente artículo busca explicaciones para los derrocamientos de tres presidentes ecuatorianos, que han marcado los puntos culminantes de una década de inestabilidad. Lo hace indagando en el campo de las movilizaciones sociales que precedieron a cada uno de esos hechos, con especial referencia a su composición social y a los objetivos de sus integrantes. En la parte final se proponen algunas hipótesis acerca de la movilización en contra del gobierno de Gutiérrez. Sugiere que no son válidas las explicaciones de racismo y de temor clasista. Enlaza la explicación al surgimiento de reivindicaciones democráticas originadas tanto en los bajos rendimientos del sistema político como en el carácter dictatorial que iba tomando el último gobierno.

  6. Absorption Spectra of CuGaSe 2 and CuInSe 2 Semiconducting Nanoclusters

    KAUST Repository

    Mokkath, Junais Habeeb

    2015-10-01

    The structural and optical properties of the chalcopyrite CunGanSe2n and CunInnSe2n nanoclusters (n = 2, 4, 6, and 8) are investigated as a function of the size using a combination of basin-hopping global optimization and time-dependent density functional theory. Although the lowest energy structures are found to show almost random geometries, the band gaps and absorption spectra still are subject to systematic blue shifts for decreasing cluster size in the case of CunGanSe2n, indicating strong electron confinement. The applicability of the nanoclusters in photovoltaics is discussed. © 2015 American Chemical Society.

  7. Photo and electroluminescence of ZnSe: Sn and ZnSe:(Sn, Pr) phosphors

    Science.gov (United States)

    Mishra, A. K.; Mishra, S. K.; Pandey, S. P.; Lakshmi Mishra, Kshama

    2016-09-01

    We have prepared ZnSe (luminescent grade) phosphor doped with Sn and (Sn,Pr) with varying concentration in an inert atmosphere in a silica tubular furnace at temperature of (780 ± 20) °C for 1 hr to obtain ZnSe:Sn and ZnSe: (Sn,Pr) phosphors. The photo luminescence (PL) and electroluminescence (EL) spectra of these phosphors have been studied at room temperature and results were discussed in the light of existing models. Dependence of EL emission on the voltage frequency has also been carried out. It is found that the plot between the integrated light intensity versus 1/√Vrms is a straight line suggesting the existence of Mott-Schottky type barrier on the metal semiconductor interface.

  8. 2-Selenouridine triphosphate synthesis and Se-RNA transcription.

    Science.gov (United States)

    Sun, Huiyan; Jiang, Sibo; Caton-Williams, Julianne; Liu, Hehua; Huang, Zhen

    2013-09-01

    2-Selenouridine ((Se)U) is one of the naturally occurring modifications of Se-tRNAs ((Se)U-RNA) at the wobble position of the anticodon loop. Its role in the RNA-RNA interaction, especially during the mRNA decoding, is elusive. To assist the research exploration, herein we report the enzymatic synthesis of the (Se)U-RNA via 2-selenouridine triphosphate ((Se)UTP) synthesis and RNA transcription. Moreover, we have demonstrated that the synthesized (Se)UTP is stable and recognizable by T7 RNA polymerase. Under the optimized conditions, the transcription yield of (Se)U-RNA can reach up to 85% of the corresponding native RNA. Furthermore, the transcribed (Se)U-hammerhead ribozyme has the similar activity as the corresponding native, which suggests usefulness of (Se)U-RNAs in function and structure studies of noncoding RNAs, including the Se-tRNAs.

  9. Determination of dispersive optical constants of nanocrystalline CdSe (nc-CdSe) thin films

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Kriti; Al-Kabbi, Alaa S.; Saini, G.S.S. [Centre of Advanced Study in Physics, Department of Physics, Panjab University, Chandigarh 160014 (India); Tripathi, S.K., E-mail: surya@pu.ac.in [Centre of Advanced Study in Physics, Department of Physics, Panjab University, Chandigarh 160014 (India)

    2012-06-15

    Highlights: ► nc-CdSe thin films are prepared by thermal vacuum evaporation technique. ► TEM analysis shows NCs are spherical in shape. ► XRD reveals the hexagonal (wurtzite) crystal structure of nc-CdSe thin films. ► The direct optical bandgap of nc-CdSe is 2.25 eV in contrast to bulk (1.7 eV). ► Dispersion of refractive index is discussed in terms of Wemple–DiDomenico single oscillator model. -- Abstract: The nanocrystalline thin films of CdSe are prepared by thermal evaporation technique at room temperature. These thin films are characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), X-ray diffraction (XRD) and photoluminescence spectroscopy (PL). The transmission spectra are recorded in the transmission range 400–3300 nm for nc-CdSe thin films. Transmittance measurements are used to calculate the refractive index (n) and absorption coefficient (α) using Swanepoel's method. The optical band gap (E{sub g}{sup opt}) has been determined from the absorption coefficient values using Tauc's procedure. The optical constants such as extinction coefficient (k), real (ε{sub 1}) and imaginary (ε{sub 2}) dielectric constants, dielectric loss (tan δ), optical conductivity (σ{sub opt}), Urbach energy (E{sub u}) and steepness parameter (σ) are also calculated for nc-CdSe thin films. The normal dispersion of refractive index is described using Wemple–DiDomenico single-oscillator model. Refractive index dispersion is further analysed to calculate lattice dielectric constant (ε{sub L}).

  10. Optical properties of thermally annealed CdZnSe/ZnSe quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Margapoti, Emanuela

    2010-07-01

    To analyse the diffusion characteristics, photoluminescence (PL) spectroscopy has been carried out in extensive detail on single, as well as, ensembles of thermally annealed (TA) CdSe/ZnSe QDs. For a series of QD-ensembles, each annealed for t{sub A} = 30 s at temperatures from T{sub A} = 300-550 C, the change in the QD-composition has been calculated from the blue-shift of the exciton ground-state PL-emission, using a concentration function based on Fick's laws of diffusion. The diffusion length (L{sub D}) and the activation energy (E{sub A}) have been determined thereof. For the studied QDs, E{sub A} has been evaluated to be 2.2 eV. Additionally, TA results also in an enhancement of the PL-intensity and reduction of the full-width-at-half maximum (FWHM) of the spectra. This point towards an increased homogeneity of the QD-size and composition, and decrease in the concentration of defects around the QDs. For single CdSe/ZnSe QDs, TA has been varied from 100-240 C, in steps for 20 C, with t{sub A} kept fixed at 30 s. Finally, the evolution of the magneto-optic response with post-growth thermal annealing has been studied for both individual QDs and QD-ensembles. An external magnetic field, applied perpendicular to the plane of the QDs (Faraday configuration), results in Zeeman spin splitting of the ground exciton state. The emissions from the Zeeman-split states are left and right circularly polarized and from the degree of circular polarization (DCP), as well as, the spectral separation of the PL-peaks, the g-factor can be estimated. For CdSe/ZnSe QD-ensembles, the g-factor has been observed to change sign with TA. (orig.).

  11. Phosphine-free synthesis of high quality ZnSe, ZnSe/ZnS, and Cu-, Mn-doped ZnSe nanocrystals.

    Science.gov (United States)

    Shen, Huaibin; Wang, Hongzhe; Li, Xiaomin; Niu, Jin Zhong; Wang, Hua; Chen, Xia; Li, Lin Song

    2009-12-21

    High quality zinc blende ZnSe and ZnSe/ZnS core/shell nanocrystals have been synthesized by two converse injection methods (i.e. zinc precursor injection or selenium precursor injection) when Se-ODE complex was chosen as the phosphine-free selenium precursor. Absorption spectroscopy, fluorescence spectroscopy, X-ray diffraction (XRD), and transmission electron microscopy (TEM) were used to characterize the as-synthesized ZnSe and ZnSe/ZnS nanocrystals. The quality of the as-prepared ZnSe nanocrystals reached the same high level compared with the method using phosphine selenium precursors since the quantum yields were between 40 and 60% and photoluminescence (PL) full width at half-maximum (FWHM) was well controlled between 14 and 17 nm. The parameter window for the growth of high quality ZnSe nanocrystals was found to be much broader and monodisperse ZnSe nanocrystals were synthesized successfully even when the reaction temperature was set as low as 240 degrees C. As cores, such zinc blende ZnSe nanocrystals were also used to synthesize ZnSe/ZnS core/shell nanocrystals with high fluorescence quantum yields of 70%. Cu(2+) or Mn(2+) doped ZnSe nanocrystals were also synthesized by simply modifying this phosphine-free method. The emission range has been extended to 500 and 600 nm with the use of Cu(2+) and Mn(2+) dopants compared with the emission coverage of ZnSe at around 400 nm. This is the first totally "green approach" (i.e. phosphine-free synthesis) for the synthesis of high quality ZnSe, ZnSe/ZnS, and Cu(2+) or Mn(2+) doped ZnSe nanocrystals.

  12. Temperature-dependent exciton recombination in asymmetrical ZnCdSe/ZnSe double quantum wells

    CERN Document Server

    Yu Guang You; Zhang, J Y; Zheng, Z H; Yang, B J; Zhao Xiao Wei; Shen De Zhen; Kong Xiang Gui

    1999-01-01

    Temperature-dependent exciton recombination in asymmetrical ZnCdSe/ZnSe double quantum wells is studied by recording photoluminescence spectra and photoluminescence decay spectra. The exciton tunnelling from the wide well to the narrow well and the thermal dissociation of excitons are two factors that influence the exciton recombination in this structure. In the narrow well, both of the two processes decrease the emission intensity, whereas, in the wide well, these two processes have contrary influences on the exciton density. The change of the emission intensity depends on which is the stronger one. (author)

  13. In situ observation of the formation of FeSe

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude; Wulff, Anders Christian; Yue, Zhao;

    2011-01-01

    The formation of the FeSe compound from a mixture of Fe and Se powders encased in a composite Cu/Nb sheath was studied in situ by means of high-energy synchrotron x-ray diffraction. Tetragonal beta-FeSe does not seem to form directly from the starting elements. Instead, a sequence of FeSe2, Fe3Se4...

  14. CdSe quantum dot in vertical ZnSe nanowire and photonic wire for efficient single-photon emission

    DEFF Research Database (Denmark)

    Cremel, Thibault; Bellet-Amalric, Edith; Cagnon, Laurent;

    as a single photon source. We have grown vertically oriented ZnSe NWs (with typical diameter of 10 nm) by molecular beam epitaxy on a ZnSe(111)B buffer layer. The growth of a ZnMgSe passivating shell increases the (otherwise weak) ZnSe near-band-edge luminescence by two orders of magnitude. This has allowed...

  15. Improvement of dispersion stability and optical properties of CdSe/ZnSe structured quantum dots by polymer coating.

    Science.gov (United States)

    Kwon, Young-Tae; Eom, Nu Si A; Choi, Yo-Min; Kim, Bum-Sung; Kim, Taek-Soo; Lee, Chan-Gi; Lee, Kun-Jae; Choa, Yong-Ho

    2014-10-01

    In this study, CdSe core and CdSe/ZnSe core/shell quantum dots with a narrow size distribution were synthesized in a micro-reactor. A PMMA coating applied to the surface of CdSe/ZnSe core/shell QDs to prevent degradation gave improved dispersion stability compared to the CdSe core and CdSe/ZnSe core/shell. Many previous approaches to dispersion stability have not been quantitatively assessed. The dispersion stability was confirmed by multiple light scattering measurement. Additionally, the PMMA-coated CdSe/ZnSe QDs showed greatly improved optical properties with a photoluminescence quantum yield up to 80%. This structural motif is expected to prevent the degradation of QDs.

  16. Photoinduced aging and viscosity evolution in Se-rich Ge-Se glasses

    Energy Technology Data Exchange (ETDEWEB)

    Gueguen, Yann; Sangleboeuf, Jean-Christophe; Rouxel, Tanguy [LARMAUR ERL CNRS 6274, Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex (France); King, Ellyn A.; Lucas, Pierre [Department of Materials Science and Engineering, University of Arizona, 4715 E. Fort Lowell Road, Tucson, Arizona 85712 (United States); Keryvin, Vincent [LIMATB EA 4250, Université de Bretagne Sud, Rue de Saint Maudé, 56321 Lorient Cedex (France); Bureau, Bruno [Equipe Verres et Céramiques, UMR-CNRS 6226 Sciences Chimiques de Rennes, Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex (France)

    2013-08-21

    We propose here to investigate the non-equilibrium viscosity of Ge-Se glasses under and after light irradiation. Ge{sub 10}Se{sub 90} and Ge{sub 20}Se{sub 80} fibers have been aged in the dark and under ambient light, over months. During aging, both the relaxation of enthalpy and the viscosity have been investigated. The viscosity was measured by shear relaxation-recovery tests allowing the measurement of non-equilibrium viscosity. When Ge{sub 10}Se{sub 90} glass fibers are aged under irradiation, a relatively fast fictive temperature decrease is observed. Concomitantly, during aging under irradiation, the non-equilibrium viscosity increases and reaches an equilibrium after two months of aging. This viscosity increase is also observed in Ge{sub 20}Se{sub 80} fibers. Nevertheless, this equilibrium viscosity is far below the viscosity expected at the configurational equilibrium. As soon as the irradiation ceases, the viscosity increases almost instantaneously by about one order of magnitude. Then, if the fibers are kept in the dark, their viscosity slowly increases over months. The analysis of the shear relaxation functions shows that the aging is thermorheologically simple. On the other side, there is no simple relaxation between the shear relaxation functions measured under irradiation and those measured in the dark. These results clearly suggest that a very specific photoinduced aging process occurs under irradiation. This aging is due to photorelaxation. Nevertheless, the viscosity changes are not solely correlated to photoaging and photorelaxation. A scenario is proposed to explain all the observed viscosity evolutions under and after irradiation, on the basis of photoinduced transient defects.

  17. Phase diagram of the quasi-binary system TlInSe{sub 2}-SnSe{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Mozolyuk, M.Yu.; Piskach, L.V. [Department of Inorganic and Physical Chemistry, Lesya Ukrainka Volyn National University, Voli Ave 13, 43025 Lutsk (Ukraine); Fedorchuk, A.O. [Department of Inorganic and Organic Chemistry, Lviv National University of Veterinary Medicine and Biotechnologies, Pekarska St., 50, 79010 Lviv (Ukraine); Kityk, I.V. [Electrical Engineering Department, Czestochowa University of Technology, Al. Armii Krajowej 17/19, 42-200 Czestochowa (Poland); Olekseyuk, I.D. [Department of Inorganic and Physical Chemistry, Lesya Ukrainka Volyn National University, Voli Ave 13, 43025 Lutsk (Ukraine); Parasyuk, O.V., E-mail: oleg@univer.lutsk.ua [Department of Inorganic and Physical Chemistry, Lesya Ukrainka Volyn National University, Voli Ave 13, 43025 Lutsk (Ukraine)

    2011-02-10

    Research highlights: > The phase diagram of the quasi-binary system TlInSe{sub 2}-SnSe{sub 2} was investigated by X-ray powder diffraction and differential thermal analysis. > The system is of the eutectic type, with the invariant point at 63 mol.% SnSe{sub 2} and 788 K. The solid solution range of the ternary component extends to 28 mol.% SnSe{sub 2}. > The crystal structure of the solid solution alloy of 25 mol.% TlInSe{sub 2} was investigated (space group I4/mcm, a = 0.8091 nm, c = 0.6744 nm). A comparison with CuInSe{sub 2}-SnSe{sub 2} and AgInSe{sub 2}-SnSe{sub 2} systems is discussed. - Abstract: The TlInSe{sub 2}-SnSe{sub 2} quasibinary system was investigated using differential thermal and X-ray phase analysis methods. The phase diagram is of eutectic type (V type of the Rozeboom classification). The solid solution range of the ternary compound in the TlInSe{sub 2}-SnSe{sub 2} system extends to 28 mol.% SnSe{sub 2} at 670 K. The eutectic point coordinates are 63 mol.% SnSe{sub 2} and 788 K.

  18. Medikamentöse Therapie der Epilepsie

    Directory of Open Access Journals (Sweden)

    Gallmetzer P

    2009-01-01

    Full Text Available Durch neu zugelassene Antiepileptika wurde die medikamentöse Epilepsietherapie in den vergangenen Jahren entscheidend bereichert. Bei ca. 65 % der Epilepsiepatienten kann durch eine antiepileptische Therapie anhaltende Anfallsfreiheit erreicht werden, bei den übrigen 35 % entwickelt sich eine schwer behandelbare Epilepsie. Die wichtigsten Behandlungsziele sind neben der Anfallskontrolle die gute Verträglichkeit der medikamentösen Therapie, die Vermeidung chronischer Nebenwirkungen, die einfache Handhabung der Medikation für Arzt und Patient, die günstige Beeinflussung assoziierter Begleiterkrankungen sowie die Berücksichtigung der Bedürfnisse spezieller Patientengruppen. Generell sollte somit eine möglichst individualisierte Therapie erfolgen, die auf die Bedürfnisse des jeweiligen Patienten abgestimmt ist. Bei fehlender Anfallskontrolle sollte eine prächirurgische Epilepsiediagnostik erfolgen, um zu klären, ob der Patient ein Kandidat für einen epilepsiechirurgischen Eingriff ist. Mit Rufinamid, Stiripentol und Lacosamid sowie demnächst auch mit Eslicarbazepin stehen zur Behandlung schwer behandelbarer Epilepsiesyndrome neue Therapieoptionen zur Verfügung.

  19. Direct observation of a gap opening in topological interface states of MnSe/Bi2Se3 heterostructure

    Science.gov (United States)

    Matetskiy, A. V.; Kibirev, I. A.; Hirahara, T.; Hasegawa, S.; Zotov, A. V.; Saranin, A. A.

    2015-08-01

    High-quality MnSe(111) film was bilayer-by-bilayer grown epitaxially onto the Bi2Se3(111) surface using molecular beam epitaxy. Reversal scenario with quintuple layer-by-layer growth of Bi2Se3 onto the MnSe film was also realized. Angle-resolved photoemission spectroscopy measurements of Bi2Se3 capped with two bi-layers of MnSe revealed that an energy gap of about 90 meV appears at the Dirac point of the original Bi2Se3 surface, possibly due to breaking the time-reversal symmetry on the Bi2Se3 surface by magnetic proximity effect from MnSe.

  20. Freshwater flux to Sermilik Fjord, SE Greenland

    Directory of Open Access Journals (Sweden)

    S. H. Mernild

    2010-07-01

    Full Text Available Fluctuations in terrestrial surface freshwater flux to Sermilik Fjord, SE Greenland, were simulated and analyzed. SnowModel, a state-of-the-art snow-evolution, snow and ice melt, and runoff modeling system, was used to simulate the temporal and spatial terrestrial runoff distribution to the fjord based on observed meteorological data (1999–2008 from stations located on and around the Greenland Ice Sheet (GrIS. Simulated runoff was compared and verified against independent glacier catchment runoff observations (1999–2005. Modeled runoff to Sermilik Fjord was highly variable, ranging from 2.9×109 m3 y−1 in 1999 to 5.9×109 m3 y−1 in 2005. The uneven spatial runoff distribution produced an areally-averaged annual maximum runoff at the Helheim glacier terminus of more than 3.8 m w.eq. The sub-catchment runoff of the Helheim glacier region accounted for 25% of the total runoff to Sermilik Fjord. The runoff distribution from the different sub-catchments suggested a strong influence from the spatial variation in glacier coverage. To assess the Sermilik Fjord freshwater flux, simulated terrestrial runoff and net precipitation (precipitation minus evaporation and sublimation for the fjord area were combined with satellite-derived ice discharge and subglacial geothermal and frictional melting due to basal ice motion. A terrestrial freshwater flux of ~40.4×109 m3 y−1 was found for Sermilik Fjord, with an 11% contribution originated from surface runoff. For the Helheim glacier sub-catchment only 4% of the flux originated from terrestrial surface runoff.

  1. Freshwater flux to Sermilik Fjord, SE Greenland

    Directory of Open Access Journals (Sweden)

    S. H. Mernild

    2010-10-01

    Full Text Available Terrestrial inputs of freshwater flux to Sermilik Fjord, SE Greenland, were estimated, indicating ice discharge to be the dominant source of freshwater. A freshwater flux of 40.4 ± 4.9×109 m3 y−1 was found (1999–2008, with an 85% contribution originated from ice discharge (65% alone from Helheim Glacier, 11% from terrestrial surface runoff (from melt water and rain, 3% from precipitation at the fjord surface area, and 1% from subglacial geothermal and frictional melting due to basal ice motion. The results demonstrate the dominance of ice discharge as a primary mechanism for delivering freshwater to Sermilik Fjord. Time series of ice discharge for Helheim Glacier, Midgård Glacier, and Fenris Glacier were calculated from satellite-derived average surface velocity, glacier width, and estimated ice thickness, and fluctuations in terrestrial surface freshwater runoff were simulated based on observed meteorological data. These simulations were compared and bias corrected against independent glacier catchment runoff observations. Modeled runoff to Sermilik Fjord was variable, ranging from 2.9 ± 0.4×109 m3 y−1 in 1999 to 5.9 ± 0.9×109 m3 y−1 in 2005. The sub-catchment runoff of the Helheim Glacier region accounted for 25% of the total runoff to Sermilik Fjord. The runoff distribution from the different sub-catchments suggested a strong influence from the spatial variation in glacier coverage, indicating high runoff volumes, where glacier cover was present at low elevations.

  2. Cu2ZnSnSe4 thin-film solar cells fabricated using Cu2SnSe3 and ZnSe bilayers

    Science.gov (United States)

    Kim, Kang Min; Liao, Kuang Hsiang; Tampo, Hitoshi; Shibata, Hajime; Niki, Shigeru

    2015-04-01

    Evaporated Cu2SnSe3 (CTSe) and ZnSe bilayers are used as precursors for the fabrication of Cu2ZnSnSe4 (CZTSe) thin films. Large grains (i.e., >1 µm) in CZTSe were obtained at a relatively low annealing temperature of 500 °C. The stacking order of precursors strongly affected the chemical composition of CZTSe thin films even under identical growth conditions. Zn loss in CTSe/ZnSe/Mo precursors occurred during CTSe deposition, whereas ZnSe/CTSe/Mo precursors showed improved stability in composition. The CZTSe solar cells fabricated using ZnSe/CTSe bilayer precursors with annealing showed a conversion efficiency of over 7%.

  3. Tailoring ZnSe-CdSe colloidal quantum dots via cation exchange: from core/shell to alloy nanocrystals.

    Science.gov (United States)

    Groeneveld, Esther; Witteman, Leon; Lefferts, Merel; Ke, Xiaoxing; Bals, Sara; Van Tendeloo, Gustaaf; Donega, Celso de Mello

    2013-09-24

    We report a study of Zn(2+) by Cd(2+) cation exchange (CE) in colloidal ZnSe nanocrystals (NCs). Our results reveal that CE in ZnSe NCs is a thermally activated isotropic process. The CE efficiency (i.e., fraction of Cd(2+) ions originally in solution, Cdsol, that is incorporated in the ZnSe NC) increases with temperature and depends also on the Cdsol/ZnSe ratio. Interestingly, the reaction temperature can be used as a sensitive parameter to tailor both the composition and the elemental distribution profile of the product (Zn,Cd)Se NCs. At 150 °C ZnSe/CdSe core/shell hetero-NCs (HNCs) are obtained, while higher temperatures (200 and 220 °C) produce (Zn1-xCdx)Se gradient alloy NCs, with increasingly smoother gradients as the temperature increases, until homogeneous alloy NCs are obtained at T ≥ 240 °C. Remarkably, sequential heating (150 °C followed by 220 °C) leads to ZnSe/CdSe core/shell HNCs with thicker shells, rather than (Zn1-xCdx)Se gradient alloy NCs. Thermal treatment at 250 °C converts the ZnSe/CdSe core/shell HNCs into (Zn1-xCdx)Se homogeneous alloy NCs, while preserving the NC shape. A mechanism for the cation exchange in ZnSe NCs is proposed, in which fast CE takes place at the NC surface, and is followed by relatively slower thermally activated solid-state cation diffusion, which is mediated by Frenkel defects. The findings presented here demonstrate that cation exchange in colloidal ZnSe NCs provides a very sensitive tool to tailor the nature and localization regime of the electron and hole wave functions and the optoelectronic properties of colloidal ZnSe-CdSe NCs.

  4. Dipole strength in 80Se for s process and nuclear transmutation of 79Se

    Science.gov (United States)

    Makinaga, A.; Massarczyk, R.; Beard, M.; Schwengner, R.; Otsu, H.; Al-Abdullah, T.; Anders, M.; Bemmerer, D.; Hannaske, R.; John, R.; Junghans, A. R.; Müller, S. E.; Röder, M.; Schmidt, K.; Wagner, A.

    2016-10-01

    The dipole strength distribution of 80Se was studied in a photon-scattering experiment by using bremsstrahlung produced with an electron beam of energy 11.5 MeV at the linear accelerator ELBE. We identified 180 γ transitions up to an energy of 9.6 MeV, and analyzed the strength in the quasicontinuum of the spectrum. Simulations of statistical γ -ray cascades were performed to estimate intensities of inelastic transitions and to correct the intensities of the ground-state transitions for their branching ratios. The photoabsorption cross section below the neutron-separation energy derived in this way was combined with the photoabsorption cross section obtained from an earlier (γ ,n ) experiment and used as an input for the calculation of 79Se(n ,γ ) reaction rates on the basis of the statistical reaction model.

  5. Mechanical properties of layered InSe and GaSe single crystals

    Science.gov (United States)

    Mosca, D. H.; Mattoso, N.; Lepienski, C. M.; Veiga, W.; Mazzaro, I.; Etgens, V. H.; Eddrief, M.

    2002-01-01

    The mechanical properties of InSe and GaSe single crystals have been studied by means of nanoindentation tests. Both bulk crystals are well ordered and present a predominant γ-type interlayer stacking sequence as determined by x-ray diffraction and transmission electron microscopy measurements. The course of plastic deformation induced in the crystals by application of a definite shear stress through the penetration of a Berkovich tip indicates that the deformation occurs predominantly by pop-in events along easy slip directions having a fairly elastic character between displacements. Hardness anisotropy along crystal axes is clearly seen and the measured elastic modulus presents a discrepancy smaller than 5% in comparison with theoretical calculations performed using previous experimental values of the elastic constants.

  6. La desaceleración económica colombiana: se cosecha lo que se siembra

    Directory of Open Access Journals (Sweden)

    Carlos Humberto Ortiz

    2009-12-01

    Full Text Available La desaceleración económica que experimenta Colombia desde 1980 se explica por el estancamiento estructural de la economía y por la escalada de violencia relacionada con la expansión del narcotráfico. Los datos disponibles no rechazan esta hipótesis. El artículo plantea que la desindustrialización y el narcotráfico se forjaron en el mismo crisol: un modelo de desarrollo que ha integrado progresivamente la economía nacional a los mercados mundiales al tiempo que ha renunciado, también progresivamente, a la opción industrialista. Además, argumenta que la explosión del narcotráfico obedece a la profundización de la guerra contra las drogas en un contexto de demanda mundial creciente e inelástica.

  7. LETTER TO THE EDITOR: Raman investigation of InSe and GaSe single-crystals oxidation

    Science.gov (United States)

    Balitskii, O. A.; Savchyn, V. P.; Yukhymchuk, V. O.

    2002-02-01

    We discuss the Raman scattering of thermally oxidized gallium selenide (GaSe) and indium selenide (InSe) single crystals. It has been established that the oxidation mechanisms of these compounds are rather different. For InSe, an increase of the oxidation temperature leads to the formation of (SeO4) complexes. For GaSe, it is characteristic that only Ga2O3 is formed as an oxygen-containing phase during the oxidation. The presence of the Me2Se3 phase (where Me is Ga or In) in its own oxide is common for both of the semiconductors.

  8. Absorption and initial metabolism of 75Se-l-selenomethionine

    DEFF Research Database (Denmark)

    Grosse Ruse, Mareile; Søndergaard, Lasse R.; Ditlevsen, Susanne

    2015-01-01

    Selenomethionine (SeMet) is an important organic nutritional source of Se, but the uptake and metabolism of SeMet are poorly characterised in humans. Dynamic gamma camera images of the abdominal region were acquired from eight healthy young men after the ingestion of radioactive 75Se-l-SeMet (75Se...... to the plasma and 0·267 h–1 from the stomach to the plasma. The delay in the liver was 0·714 h. Gamma camera imaging provides data for use in compartmental modelling of 75Se-SeMet absorption and metabolism in humans. In clinical settings, the obtained rate constants and the delay in the liver may be useful...

  9. Por uma cidade que se move e se comunica: corpo, rua e improviso

    Directory of Open Access Journals (Sweden)

    Julia Saldanha Vieira de Aguiar

    2009-06-01

    Full Text Available Este trabalho trata da relação de um lugar com suas pessoas. A reflexão acontece a partir de um estudo de caso: o Camelódromo da Praça XV. O Camelódromo foi uma grande feira, que durante 40 anos ocupou um espaço importante no centro de Porto Alegre/RS. (Auto organizado e vivido principalmente pelo povo, o fenômeno se configurava em um lugar onde improviso e estética constituiam o modo de ser e agir no cotidiano da rua. Ironicamente, no início de 2009, o Camelódromo foi transferido para dentro de um prédio. Hoje, onde se desenrolava o espetáculo do imprevisível, encontra-se um estacionamento para carros. Este trabalho foi produzido nos últimos meses do Camelódromo; em um espírito de elogio à estética do improviso e à auto-organização. Buscamos articular idéias da teoria da complexidade, do urbanismo, das artes e da comunicação, para tentar compreender um pouco essa manifestação espontânea, tão característica da urbe no século XXI.

  10. SE-BGP:一种BGP安全机制%SE-BGP: An Approach for BGP Security

    Institute of Scientific and Technical Information of China (English)

    胡湘江; 朱培栋; 龚正虎

    2008-01-01

    BGP(border gateway protocol)协议的安全是Internet路由系统安全的关键.目前已提出多种BGP安全机制,但都未能得到部署.对BGP安全机制的部署问题进行深入分析,利用AS(autonomous system)结构的Rich-Club特性,提出AS联盟的概念,设计了一种BGP安全机制:SE-BGP(security enhanced BGP).SE-BGP采用基于AS联盟的安全体系结构,使用一种具有分布式认证中心的新的信任模型--TTM(translator trust model).设计了基于TTM模型的认证算法,给出了基于现有BGP协议的扩充实现方法.与已有的安全机制相比,SE-BGP在保证安全能力的同时,所需的证书规模大约为原有机制的1%,具有良好的可扩展性.

  11. Electronic structure of the GaSe/Si(111) and InSe/Si(111) heterojunctions

    Science.gov (United States)

    Camara, M. O.; Mauger, A.; Devos, I.

    2002-05-01

    A tight-binding calculation of the electronic properties of the semiconductor GaSe/Si(111) and InSe/Si(111) heterojunctions is performed in a charge-dependent tight binding approach where the only Coulomb effect is a shift of all the pseudoatomic levels of a given atom at site i by the same quantity Ui. The fitting parameters Ui are determined in the framework of constrained optimization techniques using the conjugate gradient method. The band offsets at the interfaces are determined and found to be in quantitative agreement with recent experiments on both heterojunctions. In addition, this optimization technique allows us to give more insight in the charge transfer between atomic planes at the heterojunction. As a result of the the strain induced by the lattice mismatch of the III-VI half layer grafted to the Si(111) surface the charge distribution does not match the simple charge neutrality condition in the case of InSe/Si(111).

  12. Luminescence of nanocrystalline ZnSe:Mn2+

    NARCIS (Netherlands)

    Suyver, J.F.; Wuister, S.F.; Kelly, J.J.; Meijerink, A.

    2000-01-01

    The luminescence properties of nanocrystalline ZnSe:Mn^(2+) prepared via an inorganic chemical synthesis are described. Photoluminescence spectra show distinct ZnSe and Mn^(2+) related emissions, both of which are excited via the ZnSe host lattice. The Mn^(2+) emission wavelength and the

  13. Calculation of half-life for 79Se decay

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The half-life for 79Se decay is calculated by using the Logf1ut systematics method. Based on the data analysis and comparison with experimental data the 79Se half-life is recommended. The scheme for 79Se decay is also shown and the radiation data are calculated in the text.

  14. Fluorescence relaxation dynamics of CdSe and CdSe/CdS core/shell quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Kaur, Gurvir; Kaur, Harmandeep [Centre of Advanced Study in Physics, Department of Physics, Panjab University, Chandigarh-160014 (India); Tripathi, S. K., E-mail: surya@pu.ac.in [Centre of Advanced Study in Physics, Panjab University, Chandigarh- 160014 (India)

    2014-04-24

    Time-resolved fluorescence spectra for colloidal CdSe and CdSe/CdS core/shell quantum dots have been investigated to know their electron relaxation dynamics at the maximum steady state fluorescence intensity. CdSe core and CdSe/CdS type I core-shell materials with different shell (CdS) thicknesses have been synthesized using mercaptoacetic acid as a capping agent. Steady state absorption and emission studies confirmed successful synthesis of CdSe and CdSe/CdS core-shell quantum dots. The fluorescence shows a tri-exponential decay with lifetimes 57.39, 7.82 and 0.96 ns for CdSe quantum dots. The lifetime of each recombination decreased with growth of CdS shell over the CdSe core, with maximum contribution to fluorescence by the fastest transition.

  15. Aqueous synthesis of CdSe and CdSe/CdS quantum dots with controllable introduction of Se and S sources

    Institute of Scientific and Technical Information of China (English)

    Xiao Long Rong; Qin Zhao; Guan Hong Tao

    2012-01-01

    A new and convenient route is developed to synthesize CdSe and core-shell CdSe/CdS quantum dots (QDs) in aqueous solution.The gaseous precursors,H2Se and H2S,generated on-line by reducing SeO32-with NaBH4 and the reaction between Na2S and diluted H2SO4,are used to form high-quality CdSe and CdSe/CdS QDs,respectively.The synthesized water-soluble CdSe and CdSe/CdS QDs possess high quantum yield (3% and 20%) and narrow full-width-at-half-maximum (43 nm and 38 nm).The synthesis process is easily reproducible with simple apparatus and low-toxic chemicals,and can be readily extended to the large-scale aqueous synthesis of QDs.(C) 2012 Guan Hong Tao.Published by Elsevier B.V.on behalf of Chinese Chemical Society.All rights reserved.

  16. Molecular and biochemical characterization of the selenocysteine Se-methyltransferase gene and Se-methylselenocysteine synthesis in broccoli.

    Science.gov (United States)

    Lyi, Sangbom M; Heller, Laurence I; Rutzke, Michael; Welch, Ross M; Kochian, Leon V; Li, Li

    2005-05-01

    Selenium (Se) plays an indispensable role in human nutrition and has been implicated to have important health benefits, including being a cancer preventative agent. While different forms of Se vary in their anticarcinogenic efficacy, Se-methylselenocysteine (SeMSC) has been demonstrated to be one of the most effective chemopreventative compounds. Broccoli (Brassica oleracea var. italica) is known for its ability to accumulate high levels of Se with the majority of the selenoamino acids in the form of Se-methylselenocysteine. Therefore, it serves as a good model to study the regulation of SeMSC accumulation in plants. A cDNA encoding selenocysteine Se-methyltransferase, the key enzyme responsible for SeMSC formation, was cloned from broccoli using a homocysteine S-methyltransferase gene probe from Arabidopsis (Arabidopsis thaliana). This clone, designated as BoSMT, was functionally expressed in Escherichia coli, and its identity was confirmed by its substrate specificity in the methylation of selenocysteine. The BoSMT gene represents a single copy sequence in the broccoli genome. Examination of BoSMT gene expression and SeMSC accumulation in response to selenate, selenite, and sulfate treatments showed that the BoSMT transcript and SeMSC synthesis were significantly up-regulated in plants exposed to selenate but were low in plants supplied with selenite. Simultaneous treatment of selenate with selenite significantly reduced SeMSC production. In addition, high levels of sulfate suppressed selenate uptake, resulting in a dramatic reduction of BoSMT mRNA level and SeMSC accumulation. Our results reveal that SeMSC accumulation closely correlated with the BoSMT gene expression and the total Se status in tissues and provide important information for maximizing the SeMSC production in this beneficial vegetable plant.

  17. Heterojunctions formed by annealing of GaSe and InSe layered crystals in zinc vapor

    OpenAIRE

    Kudrynskyi Z. R.; Kovalyuk Z. D.

    2012-01-01

    The article presents a method of creating heterojunc¬tions based on semiconductors with different lattice types. Substrates manufactured from GaSe and InSe layered crystals were annealed in Zn vapor. This way, n-ZnSe–p-GaSe and n-ZnSe–p-InSe heterojunctions were obtained. The obtained heterojunctions are photo¬sensitive in near and infrared spectral regions. This method opens up greate possibilities of producing heterostructures with a desired sensitivity band.

  18. Spectral anisotropy of a photoresponse from heterojunctions based on GaSe and InSe layered crystals

    Science.gov (United States)

    Katerinchuk, V. N.; Kudrynskyi, Z. R.; Kovalyuk, Z. D.

    2014-03-01

    The object of investigation is photoresponse spectra taken from the cleaved end face of heterojunctions formed by GaSe and InSe anisotropic crystals. Spectra taken from the as-prepared and chemically processed faces of the heterojunctions are compared. A modified method of growing GaSe crystals with a virgin end face is suggested, and the surface of GaSe crystals thus grown is examined by atomic force microscopy.

  19. Crystal Growth of Undoped and Doped ZnSe

    Science.gov (United States)

    Davis, Swanson L.; Chen, K.-T.; George, M. A.; Shi, D. T.; Collins, W. E.; Burger, Arnold

    1997-01-01

    The surface morphology of freshly cleaved ZnSe single crystal grown by the physical vapor transport (PVT) method was investigated by Atomic Force Microscopy (AFM) and the results were correlated with Differential Scanning Calorimetry (DSC) data. Selenium precipitates have been revealed in undoped doped ZnSe crystals having a size of about 50 nm. A transition temperature around 221 C in the DSC measurements is interpreted as the eutectic temperature of Se-saturated ZnSe. The AFM images of doped ZnSe also show that possible Cr clusters are uniformly distributed and they have an estimated size of about 6 nm.

  20. Air-Stable and Efficient PbSe Quantum-Dot Solar Cells Based upon ZnSe to PbSe Cation-Exchanged Quantum Dots

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sungwoo; Marshall, Ashley R.; Kroupa, Daniel M.; Miller, Elisa M.; Luther, Joseph M.; Jeong, Sohee; Beard, Matthew C.

    2015-08-25

    We developed a single step, cation-exchange reaction that produces air-stable PbSe quantum dots (QDs) from ZnSe QDs and PbX2 (X = Cl, Br, or I) precursors. The resulting PbSe QDs are terminated with halide anions and contain residual Zn cations. We characterized the PbSe QDs using UV–vis–NIR absorption, photoluminescence quantum yield spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy. Solar cells fabricated from these PbSe QDs obtained an overall best power conversion efficiency of 6.47% at one sun illumination. The solar cell performance without encapsulation remains unchanged for over 50 days in ambient conditions; and after 50 days, the National Renewable Energy Laboratory certification team certified the device at 5.9%.

  1. Atmospheric pressure chemical vapour deposition of SnSe and SnSe{sub 2} thin films on glass

    Energy Technology Data Exchange (ETDEWEB)

    Boscher, Nicolas D.; Carmalt, Claire J.; Palgrave, Robert G. [Department of Chemistry, University College London, 20 Gordon Street, London, WC1H OAJ (United Kingdom); Parkin, Ivan P. [Department of Chemistry, University College London, 20 Gordon Street, London, WC1H OAJ (United Kingdom)], E-mail: i.p.parkin@ucl.ac.uk

    2008-06-02

    Atmospheric pressure chemical vapour deposition of tin monoselenide and tin diselenide films on glass substrate was achieved by reaction of diethyl selenide with tin tetrachloride at 350-650 {sup o}C. X-ray diffraction showed that all the films were crystalline and matched the reported pattern for SnSe and/or SnSe{sub 2}. Wavelength dispersive analysis by X-rays show a variable Sn:Se ratio from 1:1 to 1:2 depending on conditions. The deposition temperature, flow rates and position on the substrate determined whether mixed SnSe-SnSe{sub 2}, pure SnSe or pure SnSe{sub 2} thin films could be obtained. SnSe films were obtained at 650 {sup o}C with a SnCl{sub 4} to Et{sub 2}Se ratio greater than 10. The SnSe films were silver-black in appearance and adhesive. SnSe{sub 2} films were obtained at 600-650 {sup o}C they had a black appearance and were composed of 10 to 80 {mu}m sized adherent crystals. Films of SnSe only 100 nm thick showed complete absorbtion at 300-1100 nm.

  2. Synthesis of CdSe/ZnSe/ZnS Core/Shell Structure Quantum Dots by Hydrothermal Method%水热法合成CdSe/ZnSe/ZnS核壳结构量子点

    Institute of Scientific and Technical Information of China (English)

    胥燕; 王新; 翟镇德; 刘敏; 苏秀荣

    2014-01-01

    In the study, 3-mercaptopropionic acid modified CdSe/ZnSe/ZnS core/shell structure quantum dots (QDs) with high fluorescence were prepared by hydrothermal method and characterized via transmission electron microscopy (TEM). The influence factors of the fluorescence intensity and the stability of QDs have been studied. Results showed that excellent CdSe/ZnSe/ZnS QDs with uniform diameter (5-8 nm) were obtained. The prepared CdSe/ZnSe/ZnS QDs emit blue-violet light (446 nm) when excited at 372 nm with low toxicity, high fluorescence intensity and excellent stability, endowing the synthesized CdSe/ZnSe/ZnS QDs applied in biochemical analysis.%本研究采用水热法合成了3-巯基丙酸稳定的具有高荧光活性的CdSe/ZnSe/ZnS核/壳结构量子点,并通过透射电镜对量子点的形貌进行了表征。研究了影响量子点荧光强度的因素,并分析了量子点的稳定性。结果表明,水热法合成的CdSe/ZnSe/ZnS量子点,分布均匀,粒径大小均匀,约为5~8 nm。当激发波长为372 nm时CdSe/ZnSe/ZnS量子点可发射蓝紫色(446 nm)荧光,荧光活性高、荧光稳定性好,毒性低,可用于生物荧光标记、组分测定等。

  3. Bent Polytypic ZnSe and CdSe Nanowires Probed by Photoluminescence.

    Science.gov (United States)

    Kim, Yejin; Im, Hyung Soon; Park, Kidong; Kim, Jundong; Ahn, Jae-Pyoung; Yoo, Seung Jo; Kim, Jin-Gyu; Park, Jeunghee

    2017-05-01

    Nanowires (NWs) have witnessed tremendous development over the past two decades owing to their varying potential applications. Semiconductor NWs often contain stacking faults due to the presence of coexisting phases, which frequently hampers their use. Herein, it is investigated how stacking faults affect the optical properties of bent ZnSe and CdSe NWs, which are synthesized using the vapor transport method. Polytypic zinc blende-wurtzite structures are produced for both these NWs by altering the growth conditions. The NWs are bent by the mechanical buckling of poly(dimethylsilioxane), and micro-photoluminescence (PL) spectra were then collected for individual NWs with various bending strains (0-2%). The PL measurements show peak broadening and red shifts of the near-band-edge emission as the bending strain increases, indicating that the bandgap decreases with increasing the bending strain. Remarkably, the bandgap decrease is more significant for the polytypic NWs than for the single phase NWs. This work provides insights into flexible electronic devices of 1D nanostructures by engineering the polytypic structures. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Inter-island transport in CdSe/ZnSe quantum heterostructures

    CERN Document Server

    Wachter, S; Baldauf, M; Schmidt, M; Kurtz, E; Klingshirn, C F; Kalt, H; Litvinov, D A; Gerthsen, D

    2001-01-01

    We report on localization dynamics of excitons in ensembles of self- organized CdSe islands embedded in ZnSe. The experimental methods employed are temperature-dependent, spatially resolved photoluminescence ( mu -PL), spatially integrated PL (macro-PL), as well as time-resolved PL (TRPL). We observe the well known non- monotonous shift of the PL maximum with temperature caused by redistribution of the excitons amongst the islands. The measured shift is compared with the exact shift of the bandgap deduced from mu -PL measurements and found to depend strongly on island size and distribution. These transport processes are recovered in the temporal evolution of the PL. The decaytime of the spectrally integrated PL reaches its maximum at exactly the same temperature at which the redshift of the macro-PL turns into a blueshift. In TRPL the PL- spectrum consists of two contributions. We put the emission on the high energy side down to excited states in the islands. (17 refs).

  5. Investigation of biocompatible and protein sensitive highly luminescent quantum dots/nanocrystals of CdSe, CdSe/ZnS and CdSe/CdS.

    Science.gov (United States)

    Ratnesh, R K; Mehata, Mohan Singh

    2017-02-16

    The size and shape dependent semiconductor quantum dots (0D nanoparticles) with color tunability demonstrating significant influence in a biological system and considered as ideal probes. Here, a non-coordinated colloidal approach was used for the synthesis of CdSe, CdSe/ZnS and CdSe/CdS core-shell quantum dots (QDs) of 3-4nm. The synthesized nanocrystals show a high crystallinity, examined by X-ray diffraction (XRD) and high-resolution electron microscopy (HRTEM). The core-shell semiconductor QDs exhibit stronger photoluminescence (PL) as compared to the core QDs. The strong PL with small full-width half maximum (FWHM) indicates that the prepared QDs have a nearly uniform size distribution and well dispersibility. The quantum yield (QY) of core-shell QDs increases due to the surface passivation. Further, the PL of BSA is quenched strongly by the presence of core-shell QDs and follows the well-known Stern-Volmer (S-V) relation, whereas the PL lifetime does not follow the S-V relation, demonstrating that the observed quenching is predominantly static in nature. Among CdSe core, CdSe/ZnS and CdSe/CdS core-shell QDs, the CdSe/ZnS QDs shows the least cytotoxicity and most biocompatibility. Thus, the prepared core-shell QDs are biocompatible and exhibit strong sensing ability.

  6. Resonant tunneling transport in ZnxBe1-xSe/ZnSe/ZnyBe1-ySe asymmetric quantum structures

    Science.gov (United States)

    Sirkeli, Vadim P.; Yilmazoglu, Oktay; Al-Daffaie, Shihab; Oprea, Ion; Ong, Duu Sheng; Küppers, Franko; Hartnagel, Hans L.

    2017-05-01

    II-VI compounds are promising materials for the fabrication of room-temperature terahertz devices due to their beneficial properties like as type-I conduction band alignment, high breakdown field strength ( 331 kV/cm for ZnSe vs. 80 kV/cm for GaAs), and higher values of the conduction band offset (1.5 eV for BeSe/ZnSe vs. 0.7 eV for AlAs/GaAs). In this paper we report on numerical study of the resonant tunneling transport in ZnBeSe/ZnSe/ZnBeSe symmetric and asymmetric resonant tunneling diodes (RTDs). The negative differential resistance feature is observed in the current-voltage characteristics of the ZnSe-based RTDs. It is found that the maximum of peak-to-valley ratio (PVR) of the current density is equal to 6.025 and 7.144 at 150 K, and to 1.120 and 1.105 at 300 K for the symmetric and asymmetric RTDs, respectively. The effect of barrier heights on the frequency and output power performance of RTD devices are studied and discussed.

  7. A dry method to synthesize dendritic Ag2Se nanostructures utilizing CdSe quantum dots and Ag thin films

    Science.gov (United States)

    Hu, Lian; Zhang, Bingpo; Xu, Tianning; Li, Ruifeng; Wu, Huizhen

    2015-01-01

    Dendritic Ag2Se nanostructures are synthesized in a dry environment by UV irradiating the hybrids composed of CdSe quantum dots (QDs) and silver (Ag). UV irradiation on CdSe QDs induces a photooxidation effect on the QD surface and leads to the formation of SeO2 components. Then SeO2 reacts with the Ag atoms in either Ag film or QD layer to produce the Ag2Se. The growth mechanism of Ag2Se dendrites on solid Ag films is explored and explained by a diffusion limited aggregation model in which the QD layer provides enough freedom for Ag2Se motion. Since the oxidation of the CdSe QDs is the critical step for the Ag2Se dendrites formation this dry chemical interaction between QDs and Ag film can be applied in the study of the QD surface chemical properties. With this dry synthesis method, the Ag2Se dendrites can also be facilely formed at the designed area on Ag substrates.

  8. SeP, ApoER2 and megalin as necessary factors to maintain Se homeostasis in mammals.

    Science.gov (United States)

    Krol, Magdalena Beata; Gromadzinska, Jolanta; Wasowicz, Wojciech

    2012-10-01

    Selenoprotein P (SeP) is an extracellular protein containing ten selenium atoms in the form of selenocysteine, secreted mainly from the liver. About 60% of the whole plasma selenium level is present in SeP, which makes it a useful biomarker of selenium nutritional status. The main functions of SeP are transport and storage of selenium in plasma. It is especially an important protein for the brain, testes and kidneys where the supplementation of the proper amount of Se ensures the synthesis of selenoenzymes with antioxidant properties.Recently, it has been found that SeP uptake in kidneys, testes and brain depends on the apolipoprotein receptor 2 (ApoER2) and lipoprotein megalin receptor (Lrp2). Megalin receptor represents a physiological SeP receptor in kidneys, mediating the re-uptake of secreted SeP from the primary urine. The absence of a functional megalin receptor causes a significant reduction of plasma selenium and the SeP levels as a result of Se excretion. ApoER2 is a SeP receptor in the brain and testes which uptakes Se from the extracellular fluid. Deletion of ApoER2 in mice leads to a lowered selenium level in the brain and testes, neurological dysfunction, production of abnormal spermatozoa, infertility and even death when the subjects are fed a low-selenium diet.

  9. Effect of ZnSe/GaAs interface treatment in ZnSe quality control for optoelectronic device applications

    Energy Technology Data Exchange (ETDEWEB)

    Park, Kwangwook; Beaton, Daniel; Steirer, Kenneth X.; Alberi, Kirstin

    2017-05-01

    We investigate the role of interface initiation conditions on the growth of ZnSe/GaAs heterovalent heterostructures. ZnSe epilayers were grown on a GaAs surface with various degrees of As-termination and the application of either a Zn or Se pre-treatment. Structural analysis revealed that Zn pre-treatment of an As-rich GaAs surface suppresses Ga2Se3 formation at the interface and promotes the growth of high crystal quality ZnSe. This is confirmed with low-temperature photoluminescence. However, moderation of Ga-Se bonding through a Se pre-treatment of an As-rich GaAs surface can prevent excessive intermixing at the interface and promote excitonic emission in the underlying GaAs layer. These results provide guidance on how best to prepare heterovalent interfaces for various applications.

  10. Effect of ZnSe/GaAs interface treatment in ZnSe quality control for optoelectronic device applications

    Science.gov (United States)

    Park, Kwangwook; Beaton, Daniel; Steirer, Kenneth X.; Alberi, Kirstin

    2017-05-01

    We investigate the role of interface initiation conditions on the growth of ZnSe/GaAs heterovalent heterostructures. ZnSe epilayers were grown on a GaAs surface with various degrees of As-termination and the application of either a Zn or Se pre-treatment. Structural analysis revealed that Zn pre-treatment of an As-rich GaAs surface suppresses Ga2Se3 formation at the interface and promotes the growth of high crystal quality ZnSe. This is confirmed with low-temperature photoluminescence. However, moderation of Ga-Se bonding through a Se pre-treatment of an As-rich GaAs surface can prevent excessive intermixing at the interface and promote excitonic emission in the underlying GaAs layer. These results provide guidance on how best to prepare heterovalent interfaces for various applications.

  11. Photoelectric properties of heterostructures based on thermo-oxidated GaSe and InSe crystals

    Energy Technology Data Exchange (ETDEWEB)

    Savchyn, V.P.; Kytsai, V.B. [Lviv Ivan Franko State Univ. (Ukraine). Phys. Dept.

    2000-02-21

    The thermal oxidation processes on cleaved surfaces of GaSe and InSe single crystals in the temperature ranges of 450-700 C and 300-600 C, respectively have been investigated. The photoelectric properties of the obtained heterostructures were studied. It was established that the photoconductivity peculiarities can be explained taking into consideration the nature of surface layers formed under definite conditions such as Ga{sub 2}O{sub 3} (for GaSe) and In{sub 2}(SeO{sub 4}){sub 3} or In{sub 2}O{sub 3} (for InSe) oxide phases for GaSe and InSe correspondingly. It is shown that heterostructure spectral photosensitivity can be varied in a wide range due to definite selection of treatment conditions of gallium and indium monoselenides crystals e.g. temperature and duration of oxidation in air atmosphere. (orig.)

  12. Synthesis of CdSe Quantum Dots Using Fusarium oxysporum

    Directory of Open Access Journals (Sweden)

    Takaaki Yamaguchi

    2016-10-01

    Full Text Available CdSe quantum dots are often used in industry as fluorescent materials. In this study, CdSe quantum dots were synthesized using Fusarium oxysporum. The cadmium and selenium concentration, pH, and temperature for the culture of F. oxysporum (Fusarium oxysporum were optimized for the synthesis, and the CdSe quantum dots obtained from the mycelial cells of F. oxysporum were observed by transmission electron microscopy. Ultra-thin sections of F. oxysporum showed that the CdSe quantum dots were precipitated in the intracellular space, indicating that cadmium and selenium ions were incorporated into the cell and that the quantum dots were synthesized with intracellular metabolites. To reveal differences in F. oxysporum metabolism, cell extracts of F. oxysporum, before and after CdSe synthesis, were compared using sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE. The results suggested that the amount of superoxide dismutase (SOD decreased after CdSe synthesis. Fluorescence microscopy revealed that cytoplasmic superoxide increased significantly after CdSe synthesis. The accumulation of superoxide may increase the expression of various metabolites that play a role in reducing Se4+ to Se2− and inhibit the aggregation of CdSe to make nanoparticles.

  13. Effect of Sn Content in a CuSnZn Metal Precursor on Formation of MoSe2 Film during Selenization in Se+SnSe Vapor

    OpenAIRE

    Liyong Yao; Jianping Ao; Ming-Jer Jeng; Jinlian Bi; Shoushuai Gao; Guozhong Sun; Qing He; Zhiqiang Zhou; Yun Sun; Liann-Be Chang

    2016-01-01

    The preparation of Cu2ZnSnSe4 (CZTSe) thin films by the selenization of an electrodeposited copper–tin–zinc (CuSnZn) precursor with various Sn contents in low-pressure Se+SnSex vapor was studied. Scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) measurements revealed that the Sn content of the precursor that is used in selenization in a low-pressure Se+SnSex vapor atmosphere only slightly affects the elemental composition of the formed CZTSe films. However, the Sn co...

  14. A method to synthesize CdSe nanocrystals

    Institute of Scientific and Technical Information of China (English)

    XIE Chuang; CHEN Wei; WANG Jingkang

    2007-01-01

    CdSe nanocrystals (NCs) have great application prospects in various fields due to their novel properties.Some high-cost and toxic materials such as tri-n-octylphosphine oxide (TOPO) are used in the popular method to synthesize CdSe NCs.Based on this,a new low-cost,environment-friendly and safe solvent was introduced in the synthesis of CdSe NCs in this paper.The prepared CdSe NCs were characterized by ultraviolet-visible spectra (UV-Vis),photoluminescence (PL),transmission electron micrograph (TEM),energy disperse X-ray spectra (EDX) and X-ray diffraction (XRD).The CdSe NCs obtained which show a good PL properry are monodisperse,size-tunable and of high crystallinity.It indicates that the new solvent A is a good substitute for the solvent used in the classic route and achieves a greener synthesis of CdSe NCs.

  15. Atomic Defects and Doping of Monolayer NbSe2.

    Science.gov (United States)

    Nguyen, Lan; Komsa, Hannu-Pekka; Khestanova, Ekaterina; Kashtiban, Reza J; Peters, Jonathan J P; Lawlor, Sean; Sanchez, Ana M; Sloan, Jeremy; Gorbachev, Roman V; Grigorieva, Irina V; Krasheninnikov, Arkady V; Haigh, Sarah J

    2017-02-24

    We have investigated the structure of atomic defects within monolayer NbSe2 encapsulated in graphene by combining atomic resolution transmission electron microscope imaging, density functional theory (DFT) calculations, and strain mapping using geometric phase analysis. We demonstrate the presence of stable Nb and Se monovacancies in monolayer material and reveal that Se monovacancies are the most frequently observed defects, consistent with DFT calculations of their formation energy. We reveal that adventitious impurities of C, N, and O can substitute into the NbSe2 lattice stabilizing Se divacancies. We further observe evidence of Pt substitution into both Se and Nb vacancy sites. This knowledge of the character and relative frequency of different atomic defects provides the potential to better understand and control the unusual electronic and magnetic properties of this exciting two-dimensional material.

  16. First Reported Case of Proliferative Retinopathy in Hemoglobin SE Disease

    Directory of Open Access Journals (Sweden)

    Paul Baciu

    2014-01-01

    Full Text Available We report the first case of proliferative sickle cell retinopathy in a patient with hemoglobin SE (Hb SE disease. Only a few dozen cases of Hb SE disease have been reported previously, and none had evidence of proliferative retinopathy. A 56-year-old African American man presented to our clinic for routine examination and was found to have sea-fan peripheral neovascularization bilaterally without maculopathy. Hemoglobin analysis revealed Hb SE heterozygosity. Sector laser photocoagulation to areas of nonperfusion in both eyes resulted in regression of the peripheral neovascularization over a period of 6 months. Although Hb SE disease is rare, the incidence of Hb SE disease is postulated to rise in the future. Awareness of its potential ocular complications is needed to appropriately refer these patients for screening.

  17. Timely resolved measurements on CdSe nanoparticles; Zeitaufgeloeste Messungen an CdSe Nanopartikeln

    Energy Technology Data Exchange (ETDEWEB)

    Holt, B.E. von

    2006-06-06

    By means of infrared spectroscopy the influence of the organic cover on structure and dynamics of CdSe nanoparticles was studied. First a procedure was developed, which allows to get from the static infrared spectrum informations on the quality of the organic cover and the binding behaviour of the ligands. On qualitatively high-grade and well characterized samples thereafter the dynamics of the lowest-energy electron level 1S{sub e} was time-resolvedly meausred in thew visible range. As reference served CdSe TOPO, which was supplemented by samples with the ligands octanthiole, octanic acid, octylamine, naphthoquinone, benzoquinone, and pyridine. The studied nanoparticles had a diameter of 4.86 nm. By means of the excitation-scanning or pump=probe procedure first measurements in the picosecond range were performed. The excitation wavelengths were thereby spectrally confined and so chosen that selectively the transitions 1S{sub 3/2}-1S-e and 1P{sub 3/2}-1P{sub e} but not the intermediately lyingt transition 2S{sub 3/2}-1S{sub e} were excited. The excitation energies were kept so low that the excitation of several excitons in one crystal could be avoided. The scanning wavelength in the infrared corresponded to the energy difference between the electron levels 1S{sub e} and 1P{sub e}. The transients in the picosecond range are marked by a steep increasement of the signal, on which a multi-exponential decay follows. The increasement, which reproduces the popiulation of the excited state, isa inependent on the choice of the ligands. The influence of the organic cover is first visible in the different decay times of the excited electron levels. the decay of the measurement signal of CdSe TOPO can be approximatively described by three time constants: a decay constant in the early picosecond region, a time constant around hundert picoseconds, and a time constant of some nanoseconds. At increasing scanning wavelength the decay constants become longer. By directed excitation

  18. Peculiarities of Properties of the GaSe (InSe Nanohybrids, Synthesized under Lighting

    Directory of Open Access Journals (Sweden)

    F.O. Ivashchyshyn

    2016-11-01

    Full Text Available In this paper, new technological approach to the synthesis of multilayered nanostructures was proposed. It increased sensory properties of these nanostructures and their application for highly efficient nonelectrochemical accumulation of electrical energy. In particular, it was shown, that the field of the light wave, imposed in the process of nanohybrid formation, significantly affected the changes, caused by encapsulation of thiourea, on impedance, spectrum of thermally stimulated depolarisation currents (TSD, loss tangent tg δ and dielectric constant ε. As a result, both the application of nanohybrids GaSe as highly effective photovaricap structures and accumulation of energy on the quantum level at infralowfrequency range were investigated. In addition, a huge negative photo-capacitive phenomenon and the appearance of electromotive force in a constant magnetic field («spin battery» phenomenon in nanohibryds were found.

  19. Cr:ZnSe guided wave lasers and materials

    Science.gov (United States)

    McDaniel, Sean; Lancaster, Adam; Stites, Ronald; Thorburn, Fiona; Kar, Ajoy; Cook, Gary

    2017-02-01

    We describe a variety of technological advances in the development of efficient, powerful, and continuously tunable Cr:ZnSe lasers operating in the 2.3-2.7 μm spectral region. This includes the development of compact "single chip" waveguide Cr:ZnSe lasers, waveguide mode-locked Cr:ZnSe lasers, and the creation of homogeneously broadened laser material.

  20. The synthesis and photocatalytic activity of ZnSe microspheres.

    Science.gov (United States)

    Cao, Huaqiang; Xiao, Yujiang; Zhang, Sichun

    2011-01-07

    This paper reports the synthesis of semiconductor ZnSe microspheres composed of nanoparticles via a solvothermal route between the organic molecule selenophene (C(4)H(4) Se) and ZnCl(2) without adding any surfactant. The ZnSe microspheres were characterized by x-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), specific surface area measurement, and photoluminescence (PL) spectra. A strong and broad blue PL emission at 443 nm in wavelength (∼2.79 eV in photon energy) is attributed to the near-band-edge (NBE) emission of ZnSe, while the 530 nm peak is a defect-related (DL) emission. The photocatalytic activity of the as-prepared ZnSe microspheres was evaluated by photodegradation of methyl orange (MO) dye under ultraviolet (UV) light and visible light irradiation. The degradations of MO reach 94% or 95.1%, close to 100%, in the presence of the as-synthesized ZnSe microspheres or commercial ZnSe powder after 7 or 10 h under UV irradiation, respectively. Meanwhile the degradations of MO reach 94.3% or 60.6% in the presence of the as-synthesized ZnSe microspheres or commercial ZnSe powder after 12 h, respectively. The degradation rate of ZnSe microspheres is twice that of ZnSe commercial powder under UV light irradiation, and three times under visible light irradiation. The degradation process of MO dye on ZnSe microspheres under UV or visible light is also discussed.

  1. The synthesis and photocatalytic activity of ZnSe microspheres

    Science.gov (United States)

    Cao, Huaqiang; Xiao, Yujiang; Zhang, Sichun

    2011-01-01

    This paper reports the synthesis of semiconductor ZnSe microspheres composed of nanoparticles via a solvothermal route between the organic molecule selenophene (C4H4 Se) and ZnCl2 without adding any surfactant. The ZnSe microspheres were characterized by x-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), specific surface area measurement, and photoluminescence (PL) spectra. A strong and broad blue PL emission at 443 nm in wavelength (~2.79 eV in photon energy) is attributed to the near-band-edge (NBE) emission of ZnSe, while the 530 nm peak is a defect-related (DL) emission. The photocatalytic activity of the as-prepared ZnSe microspheres was evaluated by photodegradation of methyl orange (MO) dye under ultraviolet (UV) light and visible light irradiation. The degradations of MO reach 94% or 95.1%, close to 100%, in the presence of the as-synthesized ZnSe microspheres or commercial ZnSe powder after 7 or 10 h under UV irradiation, respectively. Meanwhile the degradations of MO reach 94.3% or 60.6% in the presence of the as-synthesized ZnSe microspheres or commercial ZnSe powder after 12 h, respectively. The degradation rate of ZnSe microspheres is twice that of ZnSe commercial powder under UV light irradiation, and three times under visible light irradiation. The degradation process of MO dye on ZnSe microspheres under UV or visible light is also discussed.

  2. Crystal structures and 77Se NMR spectra of molybdenum(IV) areneselenolates having intramolecular NH...Se hydrogen bonds.

    Science.gov (United States)

    Okamura, Taka-Aki; Taniuchi, Kaku; Lee, Keonil; Yamamoto, Hitoshi; Ueyama, Norikazu; Nakamura, Akira

    2006-11-13

    Salts of the monooxomolybdenum(IV,V) areneselenolates having intramolecular NH...Se hydrogen bonds, [Mo(IV)O(Se-2-RCONHC6H4)4]2- (R = t-Bu, CH3, CF3) and [Mo(V)O(Se-2-t-BuCONHC6H4)4]-, were synthesized and characterized by 1H nuclear magnetic resonance (NMR), 77Se NMR, electron spin resonance (ESR), UV-visible spectra, X-ray analysis, and electrochemical measurements. 77Se-1H correlated spectroscopy (COSY) indicated a significant correlation between amide 1H and selenolate 77Se atoms through an NH...Se hydrogen bond with 1J(77Se-1H) = 5.4 Hz coupling. The hydrogen bonds contribute to the positive shift in the Mo(V)/Mo(IV) redox potential. In the crystal structure of (PPh4)2[Mo(IV)O(Se-2-CH3CONHC6H4)4], an NH...O=Mo hydrogen bond was found. Ab inito calculations support the presence of intramolecular NH...O=Mo and NH...Se hydrogen bonds.

  3. Ultrasonic spray pyrolysis deposition of SnSe and SnSe2 using a single spray solution

    Institute of Scientific and Technical Information of China (English)

    Jorge Sergio Narro-Rios; Manoj Ramachandran; Dalia Martínez-Escobar; Aarón Sánchez-Juárez

    2013-01-01

    Thin films of SnSe and SnSe2 have been deposited using the ultrasonic spray pyrolysis (USP) technique.To the best of our knowledge this is the first report of the deposition of SnSe and SnSe2 thin films using a single spray solution.The use of a single spray solution for obtaining both a p-type material,SnSe,and an n-type material,SnSe2,simplifies the deposition technique.The SnSe2 thin films have a bandgap of 1.1 eV and the SnSe thin films have a band gap of 0.9 eV.The Hall measurements were used to determine the resistivity of the thin films.The SnSe2 thin films show a resistivity of 36.73 Ω·cm and n-type conductivity while the SnSe thin films show a resistivity of 180 Ω·cm and p-type conductivity.

  4. Symmetry and optical anisotropy in CdSe/ZnSe quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Kiessling, Tobias

    2009-10-29

    The material system of choice for the investigations performed in the frame of this Thesis were self-assembled CdSe/ZnSe QDs. The reason for this choice is twofold. First, CdSe/ZnSe QDs can be grown with excellent optical quality, which is a prerequiste for optical studies. Second, due to the polar nature of II-VI compound semiconductors, optical anisotropies induced by various asymmetries are more pronounced than in their IIIV or element IV counterparts. Unlike in the III-V materials, where the self-organization of QDs is well described by the Stranski-Krastanow growth mode, the peculiarities of the QD formation are not entirely clear in II-VI alloys. For the purposes of the current work QDs emerging from two variants of Molecular Beam Epitaxy (MBE) growth were studied. In order to establish a clear connection between the optically observed anisotropies and the growth induced asymmetries in the QDs we start out by summarizing all available structural and morphological studies that were performed on the resultant QDs, including x-ray diffraction, atomic force microscopy, high resolution transmission electron microscopy and resonant Raman scattering. Extensive investigations by Photoluminescence (PL) and Photoluminescence Excitation (PLE) spectroscopy hence detail the resultant electronic structure of excitons confined to the above QDs as well as their energy relaxation across the latter. We find that for these small-sized strongly confining QDs k-vector conservation is entirely relaxed, which enables interaction of the excitons with a continuum of phonons and explains fast and efficient exciton capture by the QDs, even for excitation conditions far above the ground state. We demonstrate how this provides an alternative fast relaxation channel to Auger-like electron-hole scattering, that may also explain fast hole relaxation and adds to the understanding of the absence of a phonon bottleneck in the energy relaxation in these type of QDs. With the above analysis as a

  5. Symmetry and optical anisotropy in CdSe/ZnSe quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Kiessling, Tobias

    2009-10-29

    The material system of choice for the investigations performed in the frame of this Thesis were self-assembled CdSe/ZnSe QDs. The reason for this choice is twofold. First, CdSe/ZnSe QDs can be grown with excellent optical quality, which is a prerequiste for optical studies. Second, due to the polar nature of II-VI compound semiconductors, optical anisotropies induced by various asymmetries are more pronounced than in their IIIV or element IV counterparts. Unlike in the III-V materials, where the self-organization of QDs is well described by the Stranski-Krastanow growth mode, the peculiarities of the QD formation are not entirely clear in II-VI alloys. For the purposes of the current work QDs emerging from two variants of Molecular Beam Epitaxy (MBE) growth were studied. In order to establish a clear connection between the optically observed anisotropies and the growth induced asymmetries in the QDs we start out by summarizing all available structural and morphological studies that were performed on the resultant QDs, including x-ray diffraction, atomic force microscopy, high resolution transmission electron microscopy and resonant Raman scattering. Extensive investigations by Photoluminescence (PL) and Photoluminescence Excitation (PLE) spectroscopy hence detail the resultant electronic structure of excitons confined to the above QDs as well as their energy relaxation across the latter. We find that for these small-sized strongly confining QDs k-vector conservation is entirely relaxed, which enables interaction of the excitons with a continuum of phonons and explains fast and efficient exciton capture by the QDs, even for excitation conditions far above the ground state. We demonstrate how this provides an alternative fast relaxation channel to Auger-like electron-hole scattering, that may also explain fast hole relaxation and adds to the understanding of the absence of a phonon bottleneck in the energy relaxation in these type of QDs. With the above analysis as a

  6. Measuring SeHCAT retention: a technical note.

    Science.gov (United States)

    Notghi, Alp; O'Brien, Joseph; Low, Chen Sheng; Thomson, William

    2011-10-01

    TauroH-23-((75)Se)selena-25-homocholic acid (SeHCAT) retention has been used for the diagnosis of bile acid malabsorption since the early 1980s. Bile acid malabsorption has been increasingly recognized as an important cause of severe chronic diarroea with subsequent increase in the number of referrals for the SeHCAT test. In this study, we review and discuss the standard techniques for the measurement of SeHCAT retention and describe a simple and modified technique using a noncollimated whole-body scanner, suitable for most modern dual-headed cameras.

  7. Properties of the Mo-CuInSe2 interface

    Science.gov (United States)

    Russell, P. E.; Jamjoum, O.; Ahrenkiel, R. K.; Kazmerski, L. L.; Mickelsen, R. A.; Chen, W. S.

    1982-06-01

    Mo has been suggested and used as an ohmic back contact for CdS/p-CuInSe2 solar cells. The Mo-p-CuInSe2 interface has been studied for both polycrystalline and single-crystal CuInSe2, using electron beam induced current and capacitance-voltage techniques. The interface is found to form a Schottky barrier, thereby limiting the attainable voltage of a solar cell with Mo back contact. Au is the only known ohmic contact to p-CuInSe2.

  8. Synthesis of CdSe Quantum Dots Using Fusarium oxysporum

    OpenAIRE

    Takaaki Yamaguchi; Yoshijiro Tsuruda; Tomohiro Furukawa; Lumi Negishi; Yuki Imura; Shohei Sakuda; Etsuro Yoshimura; Michio Suzuki

    2016-01-01

    CdSe quantum dots are often used in industry as fluorescent materials. In this study, CdSe quantum dots were synthesized using Fusarium oxysporum. The cadmium and selenium concentration, pH, and temperature for the culture of F. oxysporum (Fusarium oxysporum) were optimized for the synthesis, and the CdSe quantum dots obtained from the mycelial cells of F. oxysporum were observed by transmission electron microscopy. Ultra-thin sections of F. oxysporum showed that the CdSe quantum dots were pr...

  9. Structure of 72,74Se at high spin

    Indian Academy of Sciences (India)

    R Palit; H C Jain; P K Joshi; J A Sheikh

    2001-07-01

    Lifetimes of high spin states up to =22+ in the yrast positive parity bands have been measured to investigate the shape evolution with increasing spin in 72,74Se. The t values derived from these measurements indicate that prolate shape stabilizes for 72Se, while a triaxial shape develops for 74Se at higher spins. Comparison of the observed trend in t with spin for 72,74Se with that of the corresponding kryptones isotones emphasizes the stability provided by = 38 prolate shell gap even at high rotational frequency.

  10. Ultraviolet-blue photoluminescence of ZnSe quantum dots.

    Science.gov (United States)

    Peng, Ling Ling; Wang, Yu Hua; Li, Cheng Yan

    2010-03-01

    Zinc blende, sphericity, monodisperse, high luminescence ZnSe quantum dots (QDs) were synthesized by a one-step mild hydrothermal route with Zn and Se dissolved in aqueous NaOH as the source material. The structure and the morphology of the sample were examined by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The results indicated that the products were cubic blende ZnSe ranging from 3.2 to 4.5 nm in size. TEM images showed that the QDs have very good dispersibility and distribution. The characteristic features of the absorption and photoluminescence spectra of ZnSe quantum dots were studied at room temperature. Compared with the bulk ZnSe, the absorption edges and luminescent peaks of ZnSe QDs were blue shifted to higher energies due to the quantum confinement effect. Photoluminescence at ultraviolet excitation showed the strong emission at 390 nm related to the higher excitonic states. ZnSe QDs exhibiting photoluminescence line widths as narrow as 40-60 nm. Meanwhile, we simply explored the theoretical mechanism of luminescence in ZnSe QDs and analogized the relation of various point defect concentrations of ZnSe.

  11. A novel method for the deposition of nanocrystalline Bi 2Se 3, Sb 2Se 3 and Bi 2Se 3-Sb 2Se 3 thin films — SILAR

    Science.gov (United States)

    Lokhande, C. D.; Sankapal, B. R.; Sartale, S. D.; Pathan, H. M.; Giersig, M.; Ganesan, V.

    2001-10-01

    The successive ionic layer adsorption and reaction (SILAR) method is relatively new, simple and less expensive. This method is employed to deposit nanocrystalline Bi 2Se 3, Sb 2Se 3 and Bi 2Se 3-Sb 2Se 3 thin films onto amorphous glass substrates at low temperature (300 K). The preparative parameters such as concentration of precursor solutions, rinsing time, immersion cycles and immersion time are optimized to get nanocrystalline films. These films are characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), high resolution transmission electron microscopy (HRTEM), energy dispersive X-ray analysis (EDAX), optical absorption and electrical measurement techniques.

  12. A reduction approach to prepare ZnSe nanocrystallites

    Institute of Scientific and Technical Information of China (English)

    JIANG Hai-qing; CHE Jun; LI Zhi-min; YAO Xi

    2006-01-01

    ZnSe nanocrystallites powders were successfully prepared by reduction method with H2SeO4 or H2SeO3 as selenium source and Zn(Ac)2·H2O as zinc source. The reaction mechanism was also discussed through XRD and DTA/TG analysis. In the process,ZnSeO4·H2O or ZnSeO3·H2O crystallites precipitated in organic solvent was prepared at first. Then the crystallites were reduced with carbon monoxide atmosphere. The XRD analysis reveals that the structure of ZnSe phase is sphalerite (cubic ZnS). The XPS results show that the atomic ratio of Se to Zn is 1-1 approximately. The TEM shows that the size of ZnSe crystallite is 30-50 nm. This method of synthesis of ZnSe nanocrystallites has the potential application in the preparation of optical composite thin films from sol-gel process.

  13. Cohort profile: Epidemiological Clinicopathological studies in Europe (EClipSE).

    Science.gov (United States)

    2009-01-01

    Epidemiological Clinicopathological Studies in Europe (EClipSE) is the harmonization of neuropathological and longitudinal clinical data from three population-based prospective longitudinal studies of aging. The EClipSE database (Version 1.0) comprises data from the first 970 people who donated their brain at death and this number will increase. EClipSE enables sociodemographic, health, cognitive, and genetic measures collected during life to be related to neuropathology at death, testing hypotheses which require more power than has been previously possible. EClipSE aims to help throw light on relationships between biological, health and psychological factors underlying ageing and the manifestation of clinical dementia.

  14. Defects and oxidation resilience in InSe

    Science.gov (United States)

    Xiao, K. J.; Carvalho, A.; Castro Neto, A. H.

    2017-08-01

    We use density functional theory to study intrinsic defects and oxygen related defects in indium selenide. We find that InSe is prone to oxidation, but however not reacting with oxygen as strongly as phosphorene. The dominant intrinsic defects in In-rich material are the In interstitial, a shallow donor, and the Se vacancy, which introduces deep traps. The latter can be passivated by oxygen, which is isoelectronic with Se. The dominant intrinsic defects in Se-rich material have comparatively higher formation energies.

  15. XAS Studies of Se Speciation in Selenite-Fed Rats

    Science.gov (United States)

    Weekley, Claire M.; Aitken, Jade B.; Witting, Paul K.; Harris, Hugh H.

    2014-01-01

    The biological activity of selenium is dependent on its chemical form. Therefore, knowledge of Se chemistry in vivo is required for efficacious use of selenium compounds in disease prevention and treatment. Using X-ray absorption spectroscopy, Se speciation in the kidney, liver, heart, spleen, testis and red blood cells of rats fed control (~0.3 ppm Se) or selenite-supplemented (1 ppm or 5 ppm Se) diets for 3 or 6 weeks, was investigated. X-ray absorption spectroscopy revealed the presence of Se–Se and Se–C species in the kidney and liver, and Se–S species in the kidney, but not the liver. X-ray absorption near edge structure (XANES) spectra showed that there was variation in speciation in the liver and kidneys, but Se speciation was much more uniform in the remaining organs. Using principal component analysis (PCA) to interpret the Se K-edge X-ray absorption spectra, we were able to directly compare the speciation of Se in two different models of selenite metabolism – human lung cancer cells and rat tissues. The effects of Se dose, tissue type and duration of diet on selenium speciation in rat tissues were investigated, and a relationship between the duration of the diet (3 weeks versus 6 weeks) and selenium speciation was observed. PMID:25363824

  16. Effect of Sn Content in a CuSnZn Metal Precursor on Formation of MoSe2 Film during Selenization in Se+SnSe Vapor

    Directory of Open Access Journals (Sweden)

    Liyong Yao

    2016-03-01

    Full Text Available The preparation of Cu2ZnSnSe4 (CZTSe thin films by the selenization of an electrodeposited copper–tin–zinc (CuSnZn precursor with various Sn contents in low-pressure Se+SnSex vapor was studied. Scanning electron microscope (SEM and energy dispersive spectroscopy (EDS measurements revealed that the Sn content of the precursor that is used in selenization in a low-pressure Se+SnSex vapor atmosphere only slightly affects the elemental composition of the formed CZTSe films. However, the Sn content of the precursor significantly affects the grain size and surface morphology of CZTSe films. A metal precursor with a very Sn-poor composition produces CZTSe films with large grains and a rough surface, while a metal precursor with a very Sn-rich composition procures CZTSe films with small grains and a compact surface. X-ray diffraction (XRD and SEM revealed that the metal precursor with a Sn-rich composition can grow a thicker MoSe2 thin film at CZTSe/Mo interface than one with a Sn-poor composition, possibly because excess Sn in the precursor may catalyze the formation of MoSe2 thin film. A CZTSe solar cell with an efficiency of 7.94%was realized by using an electrodeposited metal precursor with a Sn/Cu ratio of 0.5 in selenization in a low-pressure Se+SnSex vapor.

  17. Elucidation of two giants: challenges to thick-shell synthesis in CdSe/ZnSe and ZnSe/CdS core/shell quantum dots.

    Science.gov (United States)

    Acharya, Krishna P; Nguyen, Hue M; Paulite, Melissa; Piryatinski, Andrei; Zhang, Jun; Casson, Joanna L; Xu, Hongwu; Htoon, Han; Hollingsworth, Jennifer A

    2015-03-25

    Core/thick-shell giant quantum dots (gQDs) possessing type II electronic structures exhibit suppressed blinking and diminished nonradiative Auger recombination. We investigate CdSe/ZnSe and ZnSe/CdS as potential new gQDs. We show theoretically and experimentally that both can exhibit partial or complete spatial separation of an excited-state electron-hole pair (i.e., type II behavior). However, we reveal that thick-shell growth is challenged by competing processes: alloying and cation exchange. We demonstrate that these can be largely avoided by choice of shelling conditions (e.g., time, temperature, and QD core identity). The resulting CdSe/ZnSe gQDs exhibit unusual single-QD properties, principally emitting from dim gray states but having high two-exciton (biexciton) emission efficiencies, whereas ZnSe/CdS gQDs show characteristic gQD blinking suppression, though only if shelling is accompanied by partial cation exchange.

  18. Preparation of multiband structure with Cu2Se/Ga3Se2/In3Se2 thin films by thermal evaporation technique for maximal solar spectrum utilization

    Science.gov (United States)

    Mohan, A.; Rajesh, S.; Gopalakrishnan, M.

    2016-10-01

    The paper investigates and discusses the formation of multiband structure through the Cu2Se-Ga3Se-In3Se2 thin films for maximal solar spectrum utilization. Stacking different semiconductor materials with various band gaps were done by successive evaporation method. Based on the band gap values the layers are arranged (low to high bandgap from the substrate). The XRD results exhibits the formation of CIGS composites through this successive evaporation of Cu2Se/Ga3Se/In3Se2 and treating then with temperature. Scanning Electron Microscope images shows improved crystallinity with the reduction in the larger grain boundary scattering after annealing. Optical spectra shows the stronger absorption in an UV-Visible region and higher transmission in the infrared and near infrared region. The optical band gap values calculated for as prepared films is 2.20 eV and the band gap was split into 1.62, 1.92 eV and 2.27eV for annealed samples. This multiband structures are much needed to utilize the full solar spectrum.

  19. Phase equilibria and liquid phase epitaxy growth of PbSnSeTe lattice matched to PbSe

    Science.gov (United States)

    Mccann, Patrick J.; Fonstad, Clifton G.; Fuchs, Jacob; Feit, Ze'ev

    1987-01-01

    The necessary phase diagram data for growing lattice-matched layers of PbSnSeTe on PbSe are presented. Solid compounds of Pb(1-x)Sn(x)Se(1-y)Te(y) lattice-matched to PbSe were grown from liquid melts consisting of (Pb/1-x/Sn/x/)(1-z)(Se/1-y/Te/y/)(z); phase equilibria data were determined together with liquidus data for values of x(liquid) from 0 to 40 percent and y(liquid) from 0 to 40 percent for temperatures between 450 and 540 C. It was found that relatively large amounts of Te must be added to the melt to achieve lattice matching because of its low segregation coefficient relative to Se. A significant lattice-pulling effect was discovered for the 5-percent Sn case, and a similar effect is expected for the 10- and 20-percent Sn cases.

  20. Phonon softening in the CDW Systems NbSe{sub 2} and TiSe{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Hott, Roland; Heid, Rolf; Bohnen, Klaus-Peter [Karlsruhe Institute of Technology, Institute of Solid State Physics, Karlsruhe (Germany); Weber, Frank [Karlsruhe Institute of Technology, Institute of Solid State Physics, Karlsruhe (Germany); Materials Science Division, Argonne National Laboratory, Argonne, Illinois (United States); Rosenkranz, Stephan; Castellan, John-Paul; Osborn, Raymond [Materials Science Division, Argonne National Laboratory, Argonne, Illinois (United States); Egami, Takeshi [Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee (United States); Said, Ayman [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois (United States); Reznik, Dmitry [Karlsruhe Institute of Technology, Institute of Solid State Physics, Karlsruhe (Germany); Department of Physics, University of Colorado at Boulder, Boulder, Colorado (United States)

    2011-07-01

    We investigated the soft-mode behaviour of phonons in the charge density wave (CDW) systems NbSe{sub 2} and TiSe{sub 2} both theoretically in Density Functional Theory (DFT) based on ab-initio phonon calculations and experimentally by means of high resolution Inelastic X-ray Scattering (IXS). For both materials, the theoretical predictions for the phonon softening using the experimental lattice parameters coincide with the experimentally observed CDW instability behaviour. While TiSe{sub 2} shows a rather sharp phonon anomaly at T=190 K, the anomaly in NbSe{sub 2} at T=33 K is much broader than expected for a Fermi surface nesting driven CDW instability. For NbSe{sub 2}, we exclude Fermi surface nesting as main origin of the phonon softening. For TiSe{sub 2}, there is no need to go beyond DFT in order to describe the phonon softening.

  1. Phonon softening in the CDW systems NbSe{sub 2} and TiSe{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Hott, Roland; Heid, Rolf; Bohnen, Klaus-Peter [Karlsruhe Institute of Technology, Institute of Solid State Physics, Karlsruhe (Germany); Weber, Frank; Castellan, John-Paul [Karlsruhe Institute of Technology, Institute of Solid State Physics, Karlsruhe (Germany); Materials Science Division, Argonne National Laboratory, Argonne, IL (United States); Rosenkranz, Stephan; Osborn, Raymond [Materials Science Division, Argonne National Laboratory, Argonne, IL (United States); Egami, Takeshi [Department of Materials Science and Engineering, University of Tennessee, Knoxville, TN (United States); Said, Ayman [Advanced Photon Source, Argonne National Laboratory, Argonne, IL (United States); Reznik, Dmitry [Karlsruhe Institute of Technology, Institute of Solid State Physics, Karlsruhe (Germany); Department of Physics, University of Colorado at Boulder, Boulder, CO (United States)

    2013-07-01

    We present new results on the soft-mode behaviour of phonons in the Charge Density Wave (CDW) systems NbSe{sub 2} and TiSe{sub 2}. Our theoretical predictions from Density Functional Theory (DFT) based on ab-initio phonon calculations coincide with the CDW instability behaviour that we observed experimentally by means of high resolution Inelastic X-ray Scattering (IXS). While TiSe{sub 2} shows a rather sharp phonon anomaly at T=190 K, the anomaly in NbSe{sub 2} at T=33 K is much broader than expected for a Fermi surface nesting driven CDW instability. For NbSe{sub 2}, we exclude Fermi surface nesting as main origin of the phonon softening. For TiSe{sub 2}, the phonon softening seems to be well described within the framework of DFT.

  2. Electronic structure and superconductivity of FeSe-related superconductors.

    Science.gov (United States)

    Liu, Xu; Zhao, Lin; He, Shaolong; He, Junfeng; Liu, Defa; Mou, Daixiang; Shen, Bing; Hu, Yong; Huang, Jianwei; Zhou, X J

    2015-05-13

    FeSe superconductors and their related systems have attracted much attention in the study of iron-based superconductors owing to their simple crystal structure and peculiar electronic and physical properties. The bulk FeSe superconductor has a superconducting transition temperature (Tc) of ~8 K and it can be dramatically enhanced to 37 K at high pressure. On the other hand, its cousin system, FeTe, possesses a unique antiferromagnetic ground state but is non-superconducting. Substitution of Se with Te in the FeSe superconductor results in an enhancement of Tc up to 14.5 K and superconductivity can persist over a large composition range in the Fe(Se,Te) system. Intercalation of the FeSe superconductor leads to the discovery of the AxFe2-ySe2 (A = K, Cs and Tl) system that exhibits a Tc higher than 30 K and a unique electronic structure of the superconducting phase. A recent report of possible high temperature superconductivity in single-layer FeSe/SrTiO3 films with a Tc above 65 K has generated much excitement in the community. This pioneering work opens a door for interface superconductivity to explore for high Tc superconductors. The distinct electronic structure and superconducting gap, layer-dependent behavior and insulator-superconductor transition of the FeSe/SrTiO3 films provide critical information in understanding the superconductivity mechanism of iron-based superconductors. In this paper, we present a brief review of the investigation of the electronic structure and superconductivity of the FeSe superconductor and related systems, with a particular focus on the FeSe films.

  3. Photoelectric Material CuInSe2%光电材料CuInSe2薄膜

    Institute of Scientific and Technical Information of China (English)

    万斌; 敖建平; 龚军

    2003-01-01

    This paper gives a review of CuInSe2 solar cells techniques and recent developments in CuInSe2 materials, it is reported that solar cells based on CuInSe2 have demonstrated efficiency of 18%. It also introduces the characteristics of CuInSe2:the extraordinarily high absorption coefficient(>105 cm-1), the use of thin layers(1~2 μm), long-term stability. The understanding of CuInSe2 will be helpful to the research of thin-film solar cells with high conversion efficiency both at home and abroad.%概述了CuInSe2太阳能电池技术,CuInSe2材料的最新发展;同时也介绍了CuInSe2薄膜的特性:非常高的光吸收系数(>105 cm-1),可以将薄膜做的很薄(1~2 μm),长期的稳定性,抗辐射性等.对CuInSe2材料的认识、了解将有助于对高效、低成本的薄膜太阳能电池的研究.

  4. Formation of ZnSe/Bi2Se3 QDs by surface cation exchange and high photothermal conversion

    Directory of Open Access Journals (Sweden)

    Guozhi Jia

    2015-08-01

    Full Text Available Water-dispersed core/shell structure ZnSe/Bi2Se3 quantum dots were synthesized by ultrasonicwave-assisted cation exchange reaction. Only surface Zn ion can be replaced by Bi ion in ZnSe quantum dots, which lead to the ultrathin Bi2Se3 shell layer formed. It is significance to find to change the crystal of QDs due to the acting of ultrasonicwave. Cation exchange mechanism and excellent photothermal conversion properties are discussed in detail.

  5. Dynamical properties and their strain-dependence of ZnSe(ZnSe:N: Zinc-blende and wurtzite

    Directory of Open Access Journals (Sweden)

    Dandan Wang

    2014-06-01

    Full Text Available The lattice dynamical properties of ZnSe and ZnSe with substitutional N incorporation(ZnSe:N are investigated in both the zinc-blend(ZB and wurtzite(WZ structures using first-principles calculations. The optical phonon modes of ZB-ZnSe at the Γ-point locate at 250 cm−1 for LO and 213 cm−1 for TO. The characteristic E2 phonon modes at about 50 cm−1 and the E1 and another E2 phonon modes around 200 cm−1 of WZ-ZnSe are suggested to be the fingerprint for distinguishing the two polytypes of ZnSe. For substitutional N incorporated ZnSe, the N incorporation introduces three new high energy modes above 500 cm−1, and the splitting of them is much larger in the WZ phase than that in ZB phase. The strain dependence of phonon frequency which could be useful for corresponding spectroscopic strain characterization are also studied. The simple linear dependence is determined for ZB-ZnSe, while the situation for WZ-ZnSe looks more complicated.

  6. Se-precipitation in ZnSe under moderate-power laser-irradiation at high-pressure

    Science.gov (United States)

    Lindberg, G. P.; Tallman, R. E.; Lauck, R.; Cardona, M.; Weinstein, B. A.

    2011-03-01

    We report evidence for the formation of Se inclusions in ZnSe under laser-irradiation during pressure-Raman experiments. Spectra of high-quality 68 Zn 76 Se crystals are recorded at 300K for pressures of 0-13GPa using 647nm excitation at powers of 10 and 100 mW (focal spot ~ 50 μ m.) For runs at the higher power a new Raman peak appears at 1.8 GPa, and shifts to lower energy at the rate --3.5 cm-1 /GPa with further increase of pressure. Its frequency, 228 cm-1 at 1.8GPa, is within 7 cm-1 of the A1 and E'' Raman peaks in trigonal Se, which both exhibit negative, strongly non-linear, pressure shifts. In particular, the pressure-shift of the new ZnSe peak gives a reasonable fit to the average dependence of the Se A1 peak over the range 2-8 GPa. No assignment to any of the ZnSe acoustic modes (one- or two- phonon) that also soften with pressure is feasible for the new peak. It is most likely related to the Se A1-mode in Se-inclusions, whose tendency to precipitate appears to increase with pressure. W. Richter, et. al., phys. stat. sol. (b) 56, 223(1993); K. Aoki, et. al., J. Phys. Soc. Japan 48, 906 (1980).

  7. Heterojunctions formed by annealing of GaSe and InSe layered crystals in zinc vapor

    Directory of Open Access Journals (Sweden)

    Kudrynskyi Z. R.

    2012-12-01

    Full Text Available The article presents a method of creating heterojunc¬tions based on semiconductors with different lattice types. Substrates manufactured from GaSe and InSe layered crystals were annealed in Zn vapor. This way, n-ZnSe–p-GaSe and n-ZnSe–p-InSe heterojunctions were obtained. The obtained heterojunctions are photo¬sensitive in near and infrared spectral regions. This method opens up greate possibilities of producing heterostructures with a desired sensitivity band.

  8. Fabrication and characterization of PbSe nanostructures on van der Waals surfaces of GaSe layered semiconductor crystals

    Science.gov (United States)

    Kudrynskyi, Z. R.; Bakhtinov, A. P.; Vodopyanov, V. N.; Kovalyuk, Z. D.; Tovarnitskii, M. V.; Lytvyn, O. S.

    2015-11-01

    The growth morphology, composition and structure of PbSe nanostructures grown on the atomically smooth, clean, nanoporous and oxidized van der Waals (0001) surfaces of GaSe layered crystals were studied by means of atomic force microscopy, x-ray diffractometry, photoelectron spectroscopy and Raman spectroscopy. Semiconductor heterostructures were grown by the hot-wall technique in vacuum. Nanoporous GaSe substrates were fabricated by the thermal annealing of layered crystals in a molecular hydrogen atmosphere. The irradiation of the GaSe(0001) surface by UV radiation was used to fabricate thin Ga2O3 layers with thickness clusters with a square or rectangular symmetry on the clean low-energy (0001) GaSe surface, and (001)-oriented growth of PbSe thin films takes place on this surface. Using this growth technique it is possible to grow PbSe nanostructures with different morphologies: continuous epitaxial layers with thickness quantum dots with a high lateral density (more than 1011 cm-2) on the oxidized van der Waals (0001) surfaces and faceted square pillar-like nanostructures with a low lateral density (˜108 cm-2) on the nanoporous GaSe substrates. We exploit the ‘vapor-liquid-solid’ growth with low-melting metal (Ga) catalyst of PbSe crystalline branched nanostructures via a surface-defect-assisted mechanism.

  9. Wittgenstein og respekten for det religiøse

    DEFF Research Database (Denmark)

    Albinus, Lars

    2006-01-01

    Fremstilling af den tidlige og den sene Wittgensteins forhold til det religiøse med særligt henblik på tabet af umiddelbarhed.......Fremstilling af den tidlige og den sene Wittgensteins forhold til det religiøse med særligt henblik på tabet af umiddelbarhed....

  10. Visualisering og modeller: Kunsten at se det usynlige

    DEFF Research Database (Denmark)

    Sønderberg Petersen, L.; Bechgaard, K.; Feidenhans'l, R. (eds.)

    2001-01-01

    Atomer kan ikke ses med det almindelige lysmikroskop. Ved udnyttelse af stråler med kortere bølgelængder end lysets, dvs. elektron-, neutron- og røntgenstråling kan man "se" ting på nanoskalaen, og med scanning tunneling mikroskopet, der udnytter densåkaldte tunnelstrømeffekt, kan man "se" enkelte...

  11. The EU assessment of the SE corporate form

    NARCIS (Netherlands)

    Cremers, Jan

    2013-01-01

    Chapter 12, authored by Jan Cremers, examines the process of revising the SE legislation. As is typical in the EU, a procedure for reviewing the impact of new legislation and deliberating on the possible need for revision was built into the SE legislation. The first go at evaluation was characterize

  12. On the Use of "Por" Plus Agent with "Se" Construction

    Science.gov (United States)

    De Mello, George

    1978-01-01

    Two explanations for the role of "se" in such constructions as "Se construyen casas" are given by grammarians; one states that it is a passive interpretation ("Houses are built"), the other advocates an impersonal interpretation ("One builds houses"). Different views are presented and analyzed. (Author/NCR)

  13. Cr:ZnSe planar waveguide mid-IR laser

    Science.gov (United States)

    Willimas, J. E.; Martyshkin, D. V.; Fedorov, V. V.; Moskalev, I. S.; Camata, R. P.; Mirov, S. B.

    2011-02-01

    Middle infrared (mid-IR) chromium-doped zinc selenide (Cr:ZnSe) bulk lasers have attracted a lot of attention due to their unique combination of optical and laser properties facilitating a wide range of potential scientific, industrial, and medical applications. Utilization of thin film waveguide geometry enabling good thermal management and control of beam quality is a viable pathway for compact chip-integrated optical laser design. Cr:ZnSe thin films are also promising as saturable absorbers and mode-lockers of the cavities of solid state lasers operating over 1.3-2.1 μm. We recently reported the first successful demonstration of mid-IR Cr:ZnSe planar waveguide lasing at 2.6 μm under gain-switched short-pulse (5 ns) 1.56 μm excitation as well as the passive Q-switching of the cavity of a fiber-pumped Er:YAG laser operating at 1645 nm using a highly doped Cr:ZnSe thin film. PLD grown Cr:ZnSe waveguide were fabricated on sapphire substrates (Cr:ZnSe/sapphire) with chromium concentration of 1018-1019 cm-3. Further development of mid-IR lasing in the Cr:ZnSe planar waveguide under continuous wave excitation were investigated. In addition, deposition of Cr:ZnSe-based thin film structures on n-type GaAs substrates were also investigated for possible mid-IR electroluminescence.

  14. Studies on electrochemically grown Cd-Fe-Se thin films

    Energy Technology Data Exchange (ETDEWEB)

    Mahalingam, T. [Alagappa Univ., Karaikudi (India). Dept. of Physics; Ajou Univ., Suwon (Korea, Republic of). Dept. of Electrical and Computer Engineering; Thanikaikarasan, S.; Raja, M.; Sanjeeviraja, C. [Alagappa Univ., Karaikudi (India). Dept. of Physics; Lee, S.; Moon, H.; Kim, Y.D. [Ajou Univ., Suwon (Korea, Republic of). Dept. of Molecular Science and Technology; Sebastian, P.J. [CIE-UNAM, Temixco, Morelos (Mexico); Chipas Polytechnical Univ., Chipas (Mexico)

    2007-01-15

    This paper presented the results of a study that investigated the electrochemical, structural, compositional, morphological and photoelectrochemical properties of cadmium ferrous selenide (Cd-Fe-Se) semiconducting thin films electrodeposited onto conducted tin oxide (SnO{sub 2}) coated glass substrates at various cadmium sulfate concentrations in the deposition bath. Experimental details were provided along with results of typical cyclic voltammograms of Cd-Fe-Se thin film cathodically deposited from an acid solution containing CdSO{sub 4}, FeSO{sub 4} and SeO{sub 2} without any additives. Variations in film thickness were determined along with compositional analysis and morphological studies. Photoelectrochemical (PEC) solar cell studies were performed in a cell consisting of photoelectrode (Cd-Fe{sub S}e), a platinum counter electrode and a saturated dalomel reference electrode. A hot probe method identified the nature of the thin film to be n-type, while the structure was found to be hexagon for CdSe, tetragonal for {alpha}-FeSe and orthorhombic for FeSe{sub 2}. According to energy dispersive analysis of X-rays (EDAX), the stoichiometric values of Cd and Se are obtained at higher concentration of CdSO{sub 4}. The maximum concentration of CD{sup 2+} ions in the solution bath yielded thin films with smooth surfaces. 18 refs., 1 tab., 6 figs.

  15. Kristeva's Thérèse: Mysticism and Modernism

    National Research Council Canada - National Science Library

    Bové, Carol Mastrangelo

    2013-01-01

    This essay focuses on Julia Kristeva’s recent volume Thérèse mon amour: Sainte Thérèse d’Avila (2008), describing and placing this blend of novel, play, psychoanalytic cultural theory, and case history in the context of her work...

  16. Effect of Se treatment on the volatile compounds in broccoli.

    Science.gov (United States)

    Lv, Jiayu; Wu, Jie; Zuo, Jinhua; Fan, Linlin; Shi, Junyan; Gao, Lipu; Li, Miao; Wang, Qing

    2017-02-01

    Broccoli contains high levels of bioactive compounds but deteriorates and senesces easily. In the present study, freshly harvested broccoli was treated with selenite and stored at two different temperatures. The effect of selenite treatment on sensory quality and postharvest physiology were analyzed. Volatile components were assessed by HS-SPME combined with GC-MS and EN. The metabolism of Se and S was also examined. Results indicated that Se treatment had a significant effect on maintaining the sensory quality, suppressing the respiration intensity and ethylene production, as well as increasing the content of Se and decreasing the content of S. In particular, significant differences in the composition of volatile compounds were present between control and Se-treated. The differences were mainly due to differences in alcohols and sulfide compounds. These results demonstrate that Se treatment can have a positive effect on maintaining quality and enhancing its sensory quality through the release of volatile compounds.

  17. Oxidation-stability studies of CuInSe2

    Science.gov (United States)

    Kazmerski, L. L.; Ireland, P. J.; Jamjoum, O.; Deb, S. K.; Sheldon, P.; Mickelsen, R. A.; Chen, W.; Bachmann, K.

    The oxidation of p-type single-crystal and thin-film polycrystalline CuInSe2 is investigated using complementary Auger electron spectroscopy (AES), secondary ion mass spectroscopy (SIMS) and X-ray photoelectron spectroscopy (XPS). The compositions of the thermally-grown oxides over the 150-300 C temperature range are found to be primarily In2O3, with some SeO2, estimated to be less than 10% by quantitative AES and XPS. The interface between the oxide and CuInSe2 is examined using AES and SIMS depth-compositional profiling in conjunction with XPS. Cu(x)Se is found to form at the interface. Angular-resolved XPS with an in-situ oxidation process is utilized to evaluate the initial oxidation of this Cu-ternary semiconductor. These studies confirm that Cu(x)Se forms during oxide growth.

  18. Initial oxidation of CuInSe2

    Science.gov (United States)

    Kazmerski, L. L.; Jamjoum, O.; Ireland, P. J.; Deb, S. K.; Mickelsen, R. A.; Chen, W.

    1981-10-01

    The oxidation of p-type single-crystal and thin-film polycrystalline CuInSe2 is investigated using complementary Auger electron spectroscopy (AES), secondary ion mass spectroscopy (SIMS) and X-ray photoelectron spectroscopy (XPS). The compositions of the thermally-grown oxides over the 150-300 C temperature range are found to be primarily In2O3, with some SeO2, estimated to be less than 10% by quantitative AES and XPS. The interface between the oxide and CuInSe2 is examined using AES and SIMS depth-compositional profiling in conjunction with XPS. Cu(x)Se is found to form at the interface. Angular-resolved XPS with an in situ oxidation process is utilized to evaluate the initial oxidation of this Cu-ternary semiconductor. These studies confirm that Cu(x)Se forms during oxide growth.

  19. NQR study of chalcogenide glasses Ge-As-Se.

    Science.gov (United States)

    Glotova, Olga; Korneva, Irina; Sinyavsky, Nikolay; Ostafin, Michal; Nogaj, Boleslaw

    2011-07-01

    A three-component Ge-As-Se system is studied by the nuclear quadrupole resonance (NQR) method on (75)As nuclei and by the nutation NQR spectroscopy. The NQR (75)As spectra of the glasses Ge(0.021) As(0.375) Se(0.604), Ge(0.043) As(0.348) Se(0.609) and Ge(0.068) As(0.318) Se(0.614) reveal broad lines with two peaks assigned to the main structural unit of As(2)Se(3). With increasing average coordination number ( ̅r), the spectrum signals are shifted towards higher frequencies. At ̅r > 2.54, the spectrum becomes complex, which is a consequence of formation of more complex molecular structures in the glasses of high content of germanium. At fixed frequencies the asymmetry parameter η of the samples studied is determined.

  20. Anisotropic Differential Reflectance Spectroscopy of Thin GeSe

    Science.gov (United States)

    Matson, Joseph; Woods, Grace; Churchill, Hugh

    2017-01-01

    Atomically thin monochalcogenides are predicted to exhibit a two-dimensional structural phase transition. This phase transition could be useful for designing new phase change memory devices. The critical temperature is dependent on the material as well as the thickness, and is predicted to occur just above room temperature for monolayer GeSe. We used differential reflectance spectroscopy on thin samples of GeSe to measure changes in the optical anisotropy with temperature as a signature of this phase transition. We constructed an apparatus for temperature-depedendent spectroscopy of micro-scale GeSe samples, and measured anisotropic optical absorption of thin GeSe. We observed a decrease in optical anisotropy of GeSe at elevated temperatures, which may be a first indication of the continuous transition from a rectangular to a square lattice in that material. This work was supported by NSF REU Grant #EEC-1359306.

  1. Shell-Controlled Photoluminescence in CdSe/CNT Nanohybrids

    Directory of Open Access Journals (Sweden)

    Si Hua-Yan

    2009-01-01

    Full Text Available Abstract A new type of nanohybrids containing carbon nanotubes (CNTs and CdSe quantum dots (QDs was prepared using an electrostatic self-assembly method. The CdSe QDs were capped by various mercaptocarboxylic acids, including thioglycolic acid (TGA, dihydrolipoic acid (DHLA and mercaptoundecanoic acid (MUA, which provide shell thicknesses of ~5.2, 10.6 and 15.2 Å, respectively. The surface-modified CdSe QDs are then self-assembled onto aridine orange-modified CNTs via electrostatic interaction to give CdSe/CNT nanohybrids. The photoluminescence (PL efficiencies of the obtained nanohybrids increase significantly with the increase of the shell thickness, which is attributed to a distance-dependent photo-induced charge-transfer mechanism. This work demonstrates a simple mean for fine tuning the PL properties of the CdSe/CNT nanohybrids and gains new insights to the photo-induced charge transfer in such nanostructures.

  2. AgSbSe{sub 2} and AgSb(S,Se){sub 2} thin films for photovoltaic applications

    Energy Technology Data Exchange (ETDEWEB)

    Garza, J.G. [Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon, San Nicolas de los Garza, Nuevo Leon (Mexico); Shaji, S. [Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon, San Nicolas de los Garza, Nuevo Leon (Mexico); Facultad de Ingenieria Mecanica y Electrica, CIIDIT - Universidad Autonoma de Nuevo Leon, Apodaca, Nuevo Leon (Mexico); Rodriguez, A.C.; Das Roy, T.K. [Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon, San Nicolas de los Garza, Nuevo Leon (Mexico); Krishnan, B., E-mail: kbindu_k@yahoo.com [Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon, San Nicolas de los Garza, Nuevo Leon (Mexico); Facultad de Ingenieria Mecanica y Electrica, CIIDIT - Universidad Autonoma de Nuevo Leon, Apodaca, Nuevo Leon (Mexico)

    2011-10-01

    Silver antimony selenide (AgSbSe{sub 2}) thin films were prepared by heating sequentially deposited multilayers of antimony sulphide (Sb{sub 2}S{sub 3}), silver selenide (Ag{sub 2}Se), selenium (Se) and silver (Ag). Sb{sub 2}S{sub 3} thin film was prepared from a chemical bath containing SbCl{sub 3} and Na{sub 2}S{sub 2}O{sub 3}, Ag{sub 2}Se from a solution containing AgNO{sub 3} and Na{sub 2}SeSO{sub 3} and Se thin films from an acidified solution of Na{sub 2}SeSO{sub 3}, at room temperature on glass substrates. Ag thin film was deposited by thermal evaporation. The annealing temperature was 350 deg. C in vacuum (10{sup -3} Torr) for 1 h. X-ray diffraction analysis showed that the thin films formed were polycrystalline AgSbSe{sub 2} or AgSb(S,Se){sub 2} depending on selenium content in the precursor films. Morphology and elemental analysis of these films were done using scanning electron microscopy and energy dispersive X-ray spectroscopy. Optical band gap was evaluated from the UV-visible absorption spectra of these films. Electrical characterizations were done using Hall effect and photocurrent measurements. A photovoltaic structure: glass/ITO/CdS/AgSbSe{sub 2}/Al was formed, in which CdS was deposited by chemical bath deposition. J-V characteristics of this structure showed V{sub oc} = 435 mV and J{sub sc} = 0.08 mA/cm{sup 2} under illumination using a tungsten halogen lamp. Preparation of a photovoltaic structure using AgSbSe{sub 2} as an absorber material by a non-toxic selenization process is achieved.

  3. Sonochemical synthesis and mechanistic study of copper selenides Cu(2-x)Se, beta-CuSe, and Cu(3)Se(2).

    Science.gov (United States)

    Xie, Yi; Zheng, Xiuwen; Jiang, Xuchuan; Lu, Jun; Zhu, Liying

    2002-01-28

    Nanocrystallites of nonstoichiometric copper selenide (Cu(2-x)Se) and stoichiometric copper selenides (beta-CuSe and Cu(3)Se(2)) were synthesized in different solutions via sonochemical irradiation at room temperature. The influence of solvents, surfactants, and ultrasonic irradiation on the morphology and phase of products has been investigated. The morphological difference of the products was mainly affected by the solvents and surfactants, which can self-aggregate into lamellar structures or microemulsions, and then these unique structures can act as both supramolecular template and microreactor to direct the growth of copper selenides. On the other hand, it was also found that the sonochemical irradiation and solvents played an important role in the formation of different phases of copper selenides. The proposed formation mechanism of copper selenides is discussed.

  4. Synthesis and tribological properties of NbSe{sub 3} nanofibers and NbSe{sub 2} microsheets

    Energy Technology Data Exchange (ETDEWEB)

    Tang, Hua; Li, Changsheng [School of Materials Science and Eng., Jiangsu University, Zhenjiang 212013, Jiangsu Province (China); Jiangsu Key Laboratory of Material Tribology, Jiangsu University, Zhenjiang 212013, Jiangsu Province (China); Yang, Xiaofei; Mo, Chaochao; Cao, Kesheng [School of Materials Science and Eng., Jiangsu University, Zhenjiang 212013, Jiangsu Province (China); Yan, Fengyuan [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 73000 (China)

    2011-04-15

    NbSe{sub 3} nanofibers and NbSe{sub 2} sheets were prepared by solid state reaction. The as-prepared products are characterized by powder X-ray diffraction (XRD), and scanning electron microscopy (SEM). The results showed that the obtained NbSe{sub 3} nanofibers have a diameter in the range of 100-300 nm and length about 10 {mu}m, while the NbSe{sub 2} sheets have a hexagon structure. The tribological properties of the as-prepared NbSe{sub x} powders as additives in HVI500 base oil were investigated on UMT-2 multispecimen tribo-tester. The wear scars were measured by VEECO WYKO NT1100 non-contact optical profile testing instrument. It is found that the addition of both NbSe{sub x} nanofibers/sheets improves the tribological properties of base oil. Furthermore, NbSe{sub 2} sheets exhibit better friction reduction and wear resistance properties than NbSe{sub 3} nanofibers in HVI500 base oil. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  5. Production of 82Se enriched Zinc Selenide (ZnSe) crystals for the study of neutrinoless double beta decay

    Science.gov (United States)

    Dafinei, I.; Nagorny, S.; Pirro, S.; Cardani, L.; Clemenza, M.; Ferroni, F.; Laubenstein, M.; Nisi, S.; Pattavina, L.; Schaeffner, K.; di Vacri, M. L.; Boyarintsev, A.; Breslavskii, I.; Galkin, S.; Lalayants, A.; Rybalka, I.; Zvereva, V.; Enculescu, M.

    2017-10-01

    High purity Zinc Selenide (ZnSe) crystals are produced starting from elemental Zn and Se to be used for the search of the neutrinoless double beta decay (0νDBD) of 82Se. In order to increase the number of emitting nuclides, enriched 82Se is used. Dedicated production lines for the synthesis and conditioning of the Zn82Se powder in order to make it suitable for crystal growth were assembled compliant with radio-purity constraints specific to rare event physics experiments. Besides routine check of impurities concentration, high sensitivity measurements are made for radio-isotope concentrations in raw materials, reactants, consumables, ancillaries and intermediary products used for ZnSe crystals production. Indications are given on the crystals perfection and how it is achieved. Since very expensive isotopically enriched material (82Se) is used, a special attention is given for acquiring the maximum yield in the mass balance of all production stages. Production and certification protocols are presented and resulting ready-to-use Zn82Se crystals are described.

  6. Detection of Salmonella enterica serovar Enteritidis (SE) Antibodies in Serum Using A Polystyrene Bead/SE Flagella Agglutination Assay

    Science.gov (United States)

    Serologic screening of flocks can be an important method to detect Salmonella enteritidis (SE) infections but can be labor intensive or lack specificity. Our goal was to develop a rapid agglutination assay using SE flagella adsorbed to polystyrene beads as a simple, relatively specific test to dete...

  7. Dependence of energy levels and optical transitions on layer thicknesses in InSe/GaSe superlattices

    Science.gov (United States)

    Erkoç, Şakir; Katırcıoğlu, Şenay

    1998-01-01

    We have investigated the dependence of energy levels and optical transition matrix elements in InSe/GaSe superlattices on well and/or barrier widths. Self-consistent-field calculations have been performed within the effective-mass theory approximation.

  8. Colloidal CdSe and ZnSe/Mn quantum dots: Their cytotoxicity and effects on cell morphology

    Directory of Open Access Journals (Sweden)

    Anna O. Drobintseva

    2015-10-01

    Full Text Available The CdSe and ZnSe:Mn colloidal quantum dots (QDs have been synthesized in order to use them as a contrast agent for bioimaging. The synthesis of QDs was made in the aqueous solution. These compounds are fluorescent semiconductor nanoparticles and are held to be promising fluorophores which can be used as an important research tool in biology and medicine. They can be exploited to allocate the problematic biological tissues and individual cells. Their applicability to human examination was studied. For this purpose we investigated the morphological changes in the cells by reacting with the CdSe/l-Cys and ZnSe:Mn/MPA quantum dots. The cytotoxicity of CdSe/l-Cys in the line of breast carcinoma was examined using confocal microscopy. The results can be seen as encouraging.

  9. ¿Qué se juega al jugar un juego?

    Directory of Open Access Journals (Sweden)

    Kalejman, Cecilia

    2012-06-01

    Full Text Available En el presente artículo se considera el juego en relación a la niñez. Se indaga acerca del papel que juega el juego en la niñez intentando responder a diversas preguntas, entre ellas la más importante: ¿Qué significa jugar? A lo largo de esta etapa del desarrollo en que comienza a constituirse la subjetividad del individuo el juego constituye, sin dudas, un factor central, una herramienta fundamental en el desarrollo. Juego no es sólo el juego dramático, también consideramos para nuestro análisis aquellas modalidades de juego que se transmiten de generación en generación, juegos de construcción, los dibujos, teniendo en cuenta asimismo los objetos utilizados en los juegos, los contenidos de los mismos, los espacios en los que se desarrollan. Se piensa y se interpreta al juego, como un derecho y como un modo de expresión del niño, se finaliza este desarrollo con una conclusión acera del juego y el espacio que ocupa en la vida cotidiana.

  10. Synthesis of ZnSe and ZnSe:Cu quantum dots by a room temperature photochemical (UV-assisted) approach using Na2 SeO3 as Se source and investigating optical properties.

    Science.gov (United States)

    Khafajeh, R; Molaei, M; Karimipour, M

    2017-06-01

    In this study, ZnSe and ZnSe:Cu quantum dots (QDs) were synthesized using Na2 SeO3 as the Se source by a rapid and room temperature photochemical (UV-assisted) approach. Thioglycolic acid (TGA) was employed as the capping agent and UV illumination activated the chemical reactions. Synthesized QDs were successfully characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), photoluminescence (PL) and UV-visible (UV-vis) spectroscopy, Fourier transform-infrared (FT-IR), and energy dispersive X-ray spectroscopy (EDX). XRD analysis demonstrated the cubic zinc blend phase QDs. TEM images indicated that round-shaped particles were formed, most of which had a diameter of about 4 nm. The band gap of the ZnSe QDs was higher than that for ZnSe in bulk. PL spectra indicated an emission with three peaks related to the excitonic, surface trap states and deep level (DL) states. The band gap and QD emission were tunable only by UV illumination time during synthesis. ZnSe:Cu showed green emission due to transition of electrons from the Conduction band (CB) or surface trap states to the (2) T2 acceptor levels of Cu(2)(+) . The emission was increased by increasing the Cu(2)(+) ion concentration, such that the optimal value of PL intensity was obtained for the nominal mole ratio of Cu:Zn 1.5%. Copyright © 2016 John Wiley & Sons, Ltd.

  11. Novel mechanical behaviors of wurtzite CdSe nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Fu, Bing [Shanghai Normal University, Department of Physics (China); Chen, Li [MCPHS University, School of Arts and Sciences (United States); Xie, Yiqun; Feng, Jie; Ye, Xiang, E-mail: yexiang@shnu.edu.cn [Shanghai Normal University, Department of Physics (China)

    2015-09-15

    As an important semiconducting nanomaterial, CdSe nanowires have attracted much attention. Although many studies have been conducted in the electronic and optical properties of CdSe NWs, the mechanical properties of Wurtzite (WZ) CdSe nanowires remain unclear. Using molecular dynamics simulations, we have studied the tensile mechanical properties and behaviors of [0001]-oriented Wurtzite CdSe nanowires. By monitoring the stretching processes of CdSe nanowires, three distinct structures are found: the WZ wire, a body-centered tetragonal structure with four-atom rings (denoted as BCT-4), and a structure that consists of ten-atom rings with two four-atom rings (denoted as TAR-4) which is observed for the first time. Not only the elastic tensile characteristics are highly reversible under unloading, but a reverse transition between TAR-4 and BCT-4 is also observed. The stretching processes also have a strong dependence on temperature. A tubular structure similar to carbon nanotubes is observed at 150 K, a single-atom chain is formed at 300, 350 and 450 K, and a double-atom chain is found at 600 K. Our findings on tensile mechanical properties of WZ CdSe nanowires does not only provide inspiration to future study on other properties of CdSe nanomaterials but also help design and build efficient nanoscale devices.

  12. GaSe oxidation in air: from bulk to monolayers

    Science.gov (United States)

    Rahaman, Mahfujur; Rodriguez, Raul D.; Monecke, Manuel; Lopez-Rivera, Santos A.; Zahn, Dietrich R. T.

    2017-10-01

    Two-dimensional (2D) van derWaals semiconductors have been the subject of intense research due to their low dimensionality and tunable optoelectronic properties. However, the stability of these materials in air is one of the important issues that needs to be clarified, especially for technological applications. Here the time evolution of GaSe oxidation from monolayer to bulk is investigated by Raman spectroscopy, photoluminescence emission, and x-ray photoelectron spectroscopy. The Raman spectroscopy study reveals that GaSe monolayers become oxidized almost immediately after exposure to air. However, the oxidation is a self-limiting process taking roughly 5 h to penetrate up to 3 layers of GaSe. After oxidation, GaSe single-layers decompose into amorphous Se which has a strong Raman cross section under red excitation. The present study provides a clear picture of the stability of GaSe in air and will guide future research of GaSe from single- to few-layers for the appropriate development of novel technological applications for this promising 2D material.

  13. Investigation of Kinetics of crystallization Processes of S15-Se85, S15-Se81-Cu4 Chalcogenide glasses

    Science.gov (United States)

    Samudrala, Kavitha; Babu Devarasetty, Suresh

    2016-09-01

    In the present work, S15-Se85, S15-Se81-Cu4 chalcogenide glasses are prepared by using conventional melt quenching technique. The as-prepared samples are studied by experimental techniques like X-ray Diffraction (XRD), Differential Scanning Calorimetry (DSC). XRD studies have confirmed that the as-prepared samples are amorphous in nature. It is clear from DSC studies that the as-prepared samples are glassy in nature. Kinetic analysis of the crystallization process of as-prepared glasses is carried using DSC curves. Activation energy for glass transition and Activation energy for crystallization are determined using Kissinger method. Activation energy for glass transition of S15-Se85 and S15-Se81-Cu4 glasses is found to be 84.5076 and 275.801 KJ/Mole respectively. Activation energy for crystallization of S15-Se85 glass is found to be 106.2622 KJ/Mole for 1st peak while Activation energy for crystallization of S15-Se81-Cu4 glasses is found to be 97.93 KJ/Mole for 1st peak and 84.20 KJ/Mole for 2nd peak. Kauzmann temperature (Tk) is determined from the heating rate dependent glass transition and crystallization temperatures. Tk value for S15-Se85 glass sample is 236.680K (1st peak) and for S15-Se81-Cu4 is 283.530K (1st peak) and 286.330K (2n peak). Avrami Index (n) is also determined for as-prepared glasses. Avrami Index (n) value for S15-Se85 glass sample is 1.8 (1st peak) and for S15-Se81-Cu4 is 2.9 (1st peak) and 1.4 (2nd peak). The crystalline phases by thermal treatment of as-prepared glasses are identified using XRD patterns.

  14. Debye temperatures and Grueneisen parameters of chain TlSe and TlInSe{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Mamedov, Nazim; Orudzhev, Guseyn; Hamidov, Sadig; Jafarova, Vusala [Institute of Physics, Azerbaijan National Academy of Sciences, Baku (Azerbaijan); Wakita, Kazuki [Chiba Institute of Technology, Department of Electrical, Electronics and Computer Engineering, Narashino (Japan); Shim, YongGu; Kishigui, Koiru; Yamamoto, Nobuyuki [Osaka Prefecture University, Department of Physics and Electronics, Graduate School of Engineering, Sakai (Japan); Mimura, Kojiro [Osaka Prefecture University, Department of Mathematical Sciences, Graduate School of Engineering, Sakai (Japan); Schorr, Susan [Free University, Department of GeoSciences, Berlin (Germany)

    2009-05-15

    Debye temperatures and Grueneisen parameters of chain TlSe and TlInSe{sub 2} were calculated using our earlier obtained ab-initio results on phonon band structure and existed experimental data on thermal expansion coefficient. For both compounds, the values of heat capacity at constant volume (C{sub v}) were found to obey cubic law at temperatures less than 2 K. The Debye temperatures were determined to be 95 K and 96 K for TlSe and TInSe{sub 2}, respectively. The unit cells of TlSe and TInSe{sub 2} were relaxed by minimizing Hellman-Feynman forces and the total energy dependence on the unit cell volume was obtained. The bulk modulus (B{sub 0}) values in Murnaghan and Birch-Murnaghan equations of state were shown to be very close to each other. By using above B{sub 0} and C{sub v}, as well as available experimental data on linear expansion, the heat capacity at constant pressure (C{sub P}) was evaluated. Comparison with experimental C{sub P} in a wide temperature range showed a good agreement for TlInSe{sub 2} and a noticeable discrepancy for TlSe at temperatures above 170 K. The calculated Grueneisen parameter of TlInSe{sub 2} showed a tendency to saturation in a region above Debye temperature. The situation with TlSe is not clear because of the ambiguous character of the available experimental data on thermal expansion. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  15. Copper Selenidophosphates Cu4P2Se6, Cu4P3Se4, Cu4P4Se3, and CuP2Se, Featuring Zero-, One-, and Two-Dimensional Anions.

    Science.gov (United States)

    Kuhn, Alexander; Schoop, Leslie M; Eger, Roland; Moudrakovski, Igor; Schwarzmüller, Stefan; Duppel, Viola; Kremer, Reinhard K; Oeckler, Oliver; Lotsch, Bettina V

    2016-08-15

    Five new compounds in the Cu/P/Se phase diagram have been synthesized, and their crystal structures have been determined. The crystal structures of these compounds comprise four previously unreported zero-, one-, and two-dimensional selenidophosphate anions containing low-valent phosphorus. In addition to two new modifications of Cu4P2Se6 featuring the well-known hexaselenidohypodiphosphate(IV) ion, there are three copper selenidophosphates with low-valent P: Cu4P3Se4 contains two different new anions, (i) a monomeric (zero-dimensional) selenidophosphate anion [P2Se4](4-) and (ii) a one-dimensional selenidophosphate anion [Formula: see text], which is related to the well-known gray-Se-like [Formula: see text] Zintl anion. Cu4P4Se3 contains one-dimensional [Formula: see text] polyanions, whereas CuP2Se contains the 2D selenidophosphate [Formula: see text] polyanion. It consists of charge-neutral CuP2Se layers separated by a van der Waals gap which is very rare for a Zintl-type phase. Hence, besides black P, CuP2Se constitutes a new possible source of 2D oxidized phosphorus containing layers for intercalation or exfoliation experiments. Additionally, the electronic structures and some fundamental physical properties of the new compounds are reported. All compounds are semiconducting with indirect band gaps of the orders of around 1 eV. The phases reported here add to the structural diversity of chalcogenido phosphates. The structural variety of this family of compounds may translate into a variety of tunable physical properties.

  16. Structural transition of FeSe under high pressure

    Institute of Scientific and Technical Information of China (English)

    Li Wei; Chen Jun-Fang; He Qin-Yu; Wang Teng; Pan Zhong-Liang

    2011-01-01

    The density functional calculations of the energy band structure and density of state for the tetragonal PbO-type phase α-FeSe and hexagonal NiAs-type phase β-FeSe are reported in this paper. The structural phase transition from tetragonal to hexagonal FeSe under high pressure is investigated, it is found that the calculated transition pressure for the α→β phase transformation is 8.5 GPa. Some fluctuations in the transition pressure maybe occurred by different external factors such as temperature and stress condition. There is about 17% volume collapse accompanying the α→β phase transformation.

  17. Novell推出SuSE Linux 10.0

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    近日,Noveil宣布SuSE Linux 10.0于10月初上市。与当前诸多Linux产品相比,SuSE Linux 10.0设计独特。简单易用,并拥有一切Linux入门所需的功能和特性。SuSE Linux 10.0的桌面功能包括最新版的Firefox网页浏览器、最新版兼容Windows的OpenOffice.org 2.0套件、

  18. Se interlayer in CIGS absorption layer for solar cell devices

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Seung-Kyu; Sim, Jae-Kwan [Semiconductor Materials Process Laboratory, School of Advanced Materials Engineering, Research Center for Advanced Materials Development, Chonbuk National University, Deokjin-Dong 664-14, Jeonju 561-756 (Korea, Republic of); Kissinger, N.J. Suthan [Department of General Studies, Physics Group, Jubail University College, Royal Commission for Jubail, Jubail 10074 (Saudi Arabia); Song, Il-Seok; Kim, Jin-Soo; Baek, Byung-Joon [Semiconductor Materials Process Laboratory, School of Advanced Materials Engineering, Research Center for Advanced Materials Development, Chonbuk National University, Deokjin-Dong 664-14, Jeonju 561-756 (Korea, Republic of); Lee, Cheul-Ro, E-mail: crlee7@jbnu.ac.kr [Semiconductor Materials Process Laboratory, School of Advanced Materials Engineering, Research Center for Advanced Materials Development, Chonbuk National University, Deokjin-Dong 664-14, Jeonju 561-756 (Korea, Republic of)

    2015-06-05

    Highlights: • Se interlayer is deposited between the CuGa and CuIn/In/Mo/STS stacked layer. • Both CIG precursor layers were selenized at 500 °C for 1 h. • SIMS depth profile shows that Ga distribution is uniform by Se interlayer. • The efficiency was improved for the CIGS solar cell by Se interlayer. - Abstract: A CIGS absorber layer with high gallium contents in the space-charge region can reduce the carrier recombination and improve the open circuit voltage V{sub oc}. Therefore, controlling Ga grading on top of CIGS thin film solar cells is the main objective of this experiment. To reduce Selenium (Se) vacancy, it is important that the diffusion of Ga elements into Se vacancy between Mo back contact and CIGS absorption layer would be controlled. In order to reduce Se vacancy and confirm Ga inter-diffusion, two CIGS solar cells were fabricated by converting CIG precursor with and without Se interlayer. The copper-indium metallic precursors were fabricated corresponding to the sequence CuIn/In/Mo/STS on stainless steel (STS) substrates by sequential direct current magnetron sputtering while Se layer was evaporated by rapid thermal annealing (RTA) system to obtain a Se/CuIn/In/Mo/STS stack. CuGa precursor layer was also fabricated on the Se/CuIn/In/Mo/STS stack. Finally, both CuGa/Se/CuIn/In/Mo/STS and CuGa/CuIn/In/Mo/STS stacks were selenized at 500 °C for 1 h. It was clearly observed from the secondary ion mass spectroscopy (SIMS) and X-ray diffraction (XRD) that there was a change between the fabricated CIGS absorption layers and the amount of Ga elements. Furthermore, the Ga elements gradually decreased from the top to the bottom layer of the CIGS absorption layer. We also discussed the effect of Se interlayer in the CIGS absorption layer and its influence on the solar cell’s performance.

  19. Reversible ultrafast melting in bulk CdSe

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Wenzhi [School of Electronic Engineering, Heilongjiang University, Harbin 150080 (China); Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States); He, Feng; Wang, Yaguo, E-mail: yaguo.wang@austin.utexas.edu [Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States); The Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712 (United States)

    2016-02-07

    In this work, transient reflectivity changes in bulk CdSe have been measured with two-color femtosecond pump-probe spectroscopy under a wide range of pump fluences. Three regions of reflectivity change with pump fluences have been consistently revealed for excited carrier density, coherent phonon amplitude, and lattice temperature. For laser fluences from 13 to 19.3 mJ/cm{sup 2}, ultrafast melting happens in first several picoseconds. This melting process is purely thermal and reversible. A complete phase transformation in bulk CdSe may be reached when the absorbed laser energy is localized long enough, as observed in nanocrystalline CdSe.

  20. ZnSe scintillating bolometers for Double Beta Decay

    CERN Document Server

    Arnaboldi, C; Cremonesi, O; Gironi, L; Pavan, M; Pessina, G; Pirro, S

    2010-01-01

    ZnSe scintillating bolometers are good candidates for future Double Beta Decay searches, because of the 82Se high Q-value and thanks to the possibility of alpha background rejection on the basis of the scintillation signal. In this paper we report the characteristics and the anomalies observed in an extensive study of these devices. Among them, an unexpected high emission from alpha particles, accompanied with an unusual pattern of the light vs. heat scatter plot. The perspectives for the application of this kind of detectors to search for the Neutrinoless Double Beta Decay of 82Se are presented.

  1. Sobre las oraciones impersonales y pasivas con "se"

    Directory of Open Access Journals (Sweden)

    Germán F. Westphal

    1999-09-01

    Full Text Available Este ensayo defiende la hipótesis de que las oraciones impersonales y pasivas con "se" comparten la misma estructura, con el sintagma nominal que concuerda opcionalmente con el verbo en posición de objeto directo. El análisis del caso se desarrolla en el contexto del Programa Minimalista. (This essay defends the hypothesis that both impersonal and passive "se" sentences share the same structure, with the noun phrase that optionally triggers agreement on the verb in direct object position. The relevant analysis is argued for in the context of the Minimalist Program.

  2. Seši u Plitvičkim jezerima

    OpenAIRE

    Pasarić, Miroslava; Slaviček, Lasta

    2016-01-01

    Poduzeta su visokofrekventna mjerenja razine vode u dva najveća plitvička jezera, u Prošću i u Kozjaku, kako bi se istražili seši. Mjerenja su rađena s intervalom uzorkovanja od 1 minute tijekom perioda od 46 dana i to na dva suprotna kraja u svakom jezeru, što je dalo informaciju i o međusobnom odnosu faza. Izračunati su spektri snage kako bi se odredili periodi vlastitih modova. Opaženi maksimimi su interpretirani uz pomoć teorijskih rezultata, dobivenih jednostavnom numeričkom metodom Defa...

  3. Señales purinérgicas Purinergic signals

    OpenAIRE

    Lazarowski, Eduardo R.; Schwarzbaum, Pablo J.

    2009-01-01

    En la última década se ha aportado clara evidencia de que tanto nucleósidos como nucleótidos de adenina y uridina pueden funcionar como factores de señalización extracelular. Su acción es mediada por dos tipos principales de receptores de superficie denominados purinérgicos. Los receptores P1 se activan por adenosina, y son todos metabotrópicos, mientras que los receptores de nucleótidos (ATP, ADP, UTP y UDP) y nucleótidos-azúcares (UDP-glucosa y UDP-galactosa) pueden ser metabotrópicos (P2Y)...

  4. Quenching of coumarin emission by CdSe and CdSe/ZnS quantum dots: Implications for fluorescence reporting

    Energy Technology Data Exchange (ETDEWEB)

    Baride, Aravind [Department of Chemistry, University of South Dakota, Vermillion, SD 57069 (United States); Engebretson, Daniel [Biomedical Engineering, University of South Dakota, Vermillion, SD 57069 (United States); Berry, Mary T. [Department of Chemistry, University of South Dakota, Vermillion, SD 57069 (United States); Stanley May, P., E-mail: smay@usd.edu [Department of Chemistry, University of South Dakota, Vermillion, SD 57069 (United States)

    2013-09-15

    The photoinduced release of highly fluorescent 7-diethylamino coumarin (7DEAC) from CdSe quantum dots (QD) modified with a thiocinnamate ligand (11-mercapto undecyl-E-3-(4-(N,N-diethylamino)-2-hydroxy phenyl) propenoate, [4DEATC]) has been previously described. Coumarin fluorescence was used to ‘report’ the photochemical reaction. The current study quantifies the quenching effect of the QDs on the coumarin emission in this system. A systematic study is presented on the quenching of 7DEAC by CdSe and CdSe/ZnS quantum dots capped with 2-[2-(2-methoxyethoxy)ethoxy] ethanethiol (PEG-thiol). A new method for the functionalization of CdSe and CdSe/ZnS QDs with PEG-thiol was developed, which does not require isolation of the as-synthesized QDs. Stern–Volmer analysis was applied to quantify the effect of the PEG-CdSe and PEG-CdSe/ZnS on 7DEAC emission. The Stern–Volmer constant, K{sub SV}, was shown to be inversely proportional to temperature for quenching by PEG-CdSe, and the fluorescence lifetime of 7DEAC was shown to be independent of PEG-CdSe concentration. Room-temperature K{sub SV} values were similar for the PEG-CdSe and PEG-CdSe/ZnS quenchers. The large magnitude of K{sub SV}, the temperature dependence of K{sub SV}, the lifetime data, and the similarity of K{sub SV} values for the core and core–shell QD quenchers are all consistent with a static quenching mechanism. Assuming a static quenching mechanism, the temperature dependence of the coumarin-QD binding constant, K{sub b}, was used to estimate the ΔH and ΔS for the binding process. -- Highlights: • Quenching of a coumarin derivative by CdSe and CdSe/ZnS quantum dots is demonstrated • Stern–Volmer analysis is performed as a function of temperature • Fluorescence lifetime analysis was used to support Stern–Volmer analysis • Data overwhelmingly support quenching via a Static Mechanism • Quenching of coumarin by quantum dots is significant and must be considered in any release and report

  5. ¿Con humor se explica y se aprende una lengua mejor?

    Directory of Open Access Journals (Sweden)

    Ricard Morant

    2010-11-01

    Full Text Available Normal 0 21 false false false ES X-NONE X-NONE MicrosoftInternetExplorer4 /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Tabla normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin-top:0cm; mso-para-margin-right:0cm; mso-para-margin-bottom:10.0pt; mso-para-margin-left:0cm; line-height:115%; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:"Times New Roman"; mso-bidi-theme-font:minor-bidi;} En el siguiente artículo nos proponemos reflexionar sobre la importancia del humor como estrategia didáctica. Para plantear si “el enseñar contento y el aprender con alegría” pueden aumentar la eficacia en el proceso de enseñanza-aprendizaje presentaremos en el primer apartado las ideas de partida, mostraremos cómo a pesar de las múltiples ventajas que puede aportar el humor a las aulas, se omite su empleo por la existencia de ciertos prejuicios y temores. Seguidamente, y a modo de ejemplo, expondremos, un tema, el tabú lingüístico, en clave de humor con el propósito de acabar planteando si el género humorístico beneficia o perjudica la práctica docente al hablar sobre una lengua o al tratar de enseñarla.

  6. Optical parameters of In Se and In Se Te thin amorphous films prepared by pulsed laser deposition

    Science.gov (United States)

    Hrdlicka, M.; Prikryl, J.; Pavlista, M.; Benes, L.; Vlcek, M.; Frumar, M.

    2007-05-01

    The thin films of materials based on In Se are under study for their applicability in photovoltaic devices, solid-state batteries and phase-change memories. The amorphous thin films of In2Se3-xTex (x=0 1.5) and InSe were prepared by pulsed laser deposition method (PLD) using a KrF excimer laser beam (λ=248 nm, 0.5 J cm-2) from polycrystalline bulk targets. The compositions of films verified by energy-dispersive X-ray analysis (EDX) were close to the compositions of targets. The surfaces of PLD films containing small amount of droplets were viewed by optical and scanning electron microscopy (SEM). The optical properties (transmittance and reflectance spectra, spectral dependence of index of refraction, optical gap, single-oscillator energy, dispersion energy, dielectric constant) of the films were determined. The values of index of refraction increased with increasing substitution of Te for Se in In2Se3 films, the values of the optical gap decreased with increasing substitution of Te for Se in In2Se3 films.

  7. ZnSe hollow nanospheres in mechanically stable near-IR antireflection coatings for ZnSe substrates.

    Science.gov (United States)

    Li, Chao; Luo, Rui-Chun; Mao, Yong-Qiang; Du, Xi-Wen; Yang, Jing

    2016-09-09

    Though possessing low absorption throughout a wide infrared (IR) spectral regime, owing to a high refractive index, zinc selenide substrates are generally covered by antireflection coatings (ARCs) for practical optical uses. However, achieving a high transmission of ZnSe substrates in the near-IR (NIR) region is still challenging. Herein, for the first time, colloidal ZnSe hollow nanospheres (HNSs) smaller than 100 nm were prepared and adopted to assemble ARCs for ZnSe substrates. The voiding kinetics of the HNSs was found to agree well with the nanoscale Kirkendall effect, and the self-diffusion of the Zn ion in the core was faster than its diffusion through the ZnSe shell. With single-index ARCs, the transmission of ZnSe substrates was remarkably enhanced in the NIR region, with up to an 18% increase at 840 nm. Besides, the ZnSe HNS-based ARCs showed superior mechanical stability even under violent ultrasonication in organic solutions. We expect that ZnSe HNSs will make it possible to construct graded-index ARCs to realize omnidirectional and broadband antireflection in IR, through further tuning of HNSs' void fraction.

  8. High Efficiency CdS/CdSe Quantum Dot Sensitized Solar Cells with Two ZnSe Layers.

    Science.gov (United States)

    Huang, Fei; Zhang, Lisha; Zhang, Qifeng; Hou, Juan; Wang, Hongen; Wang, Huanli; Peng, Shanglong; Liu, Jianshe; Cao, Guozhong

    2016-12-21

    CdS/CdSe quantum dot sensitized solar cells (QDSCs) have been intensively investigated; however, most of the reported power conversion efficiency (PCE) is still lower than 7% due to serious charge recombination and a low loading amount of QDs. Therefore, suppressing charge recombination and enhancing light absorption are required to improve the performance of QDSCs. The present study demonstrated successful design and fabrication of QDSCs with a high efficiency of 7.24% based on CdS/CdSe QDs with two ZnSe layers inserted at the interfaces between QDs and TiO2 and electrolyte. The effects of two ZnSe layers on the performance of the QDSCs were systematically investigated. The results indicated that the inner ZnSe buffer layer located between QDs and TiO2 serves as a seed layer to enhance the subsequent deposition of CdS/CdSe QDs, which leads to higher loading amount and covering ratio of QDs on the TiO2 photoanode. The outer ZnSe layer located between QDs and electrolyte behaves as an effective passivation layer, which not only reduces the surface charge recombination, but also enhances the light harvesting.

  9. Observation of a charge delocalization from Se vacancies in Bi2Se3 : A positron annihilation study of native defects

    Science.gov (United States)

    Unzueta, I.; Zabala, N.; Marín-Borrás, V.; Muñoz-Sanjosé, V.; García, J. A.; Plazaola, F.

    2016-07-01

    By means of positron annihilation lifetime spectroscopy, we have investigated the native defects present in Bi2Se3 , which belongs to the family of topological insulators. We experimentally demonstrate that selenium vacancy defects (VSe1) are present in Bi2Se3 as-grown samples, and that their charge is delocalized as temperature increases. At least from 100 K up to room temperature both VSe10 and VSe1+ charge states coexist. The observed charge delocalization determines the contribution of VSe1 defects to the n -type conductivity of Bi2Se3 . These findings are supported by theoretical calculations, which show that vacancies of nonequivalent Se1 and Se2 selenium atoms are clearly differentiated by positron annihilation lifetime spectroscopy, enabling us to directly detect and quantify the most favorable type of selenium vacancy. In addition to open-volume defects, experimental data indicate the presence of defects that act as shallow traps, suggesting that more than one type of native defects coexist in Bi2Se3 . As will be discussed, the presence of a dislocation density around 1010cm-2 could be the source of the detected shallow traps. Understanding the one-dimensional defects and the origin of the charge delocalization that leads Bi2Se3 to be an n -type semiconductor will help in the development of high-quality topological insulators based on this material.

  10. Sample (S): SE3_S01 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE3_S01 Solanum lycopersicum Lovely ai fruit Solanum lycopersicum NCBI taxonomy:408...1 Solanum lycopersicum Lovely ai (ref: http://www.mikadokyowa.com/Seed/034_tomato/034_lovely_ai/034_lovely_a

  11. UČEČA SE ORGANIZACIJA V NOGOMETU

    OpenAIRE

    Abrić, Saša

    2016-01-01

    Koncept učeče se organizacije vodi dejansko k uspešnosti poslovanja podjetij, raznih skupin in organizacij. Pravtako v športu, ki je danes glavna postranska stvar, je nenehno prilagajanje spremembam še kako pomembno. Če želimo biti uspešni in učinkoviti, je skoraj nujno, da sledimo vsemu temu razvoju in se prilagajamo zahtevanim spremembam v okolju. Vse te spremembe pa terjajo od vsakega posameznika, da se prilagaja in uči. Cilj učeče se organizacije je hitrejše in učinkovitejše učenje. U...

  12. Fabrication and Photocatalytic Properties of ZnSe Nanorod Films

    Directory of Open Access Journals (Sweden)

    Jiajia Yin

    2016-01-01

    Full Text Available ZnSe nanorod films grown on fused quartz glass substrates via a simple two-step synthesis protocol were demonstrated to be environmentally safe and effective recyclable photocatalysts. These films showed greatly enhanced photocatalytic activity compared to pulsed laser deposition ZnSe films in the degradation of methyl orange dye solutions. The well-crystalized ZnSe nanorods had a length of 15 µm and a diameter of 200 nm and were densely grown on the substrate. The morphology, crystal structure, crystal phase, and photophysical properties of the ZnSe nanorod films were investigated using field-emission scanning electron microscopy (FE-SEM, UV-Vis spectroscopy, X-ray diffraction (XRD, transmission electron microscopy (TEM, and high resolution transmission electron microscopy (HRTEM.

  13. 2005 CNPC S&E International Seminar on Borehole Technology

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    @@ From 23rd to 24th in September, the 2005 CNPC S&E International Seminar on Borehole Technology was held in Beijing. Invited by CNPC S&E, 68 honorable guests from 14 countries in Central Asia, Africa, North and South Americas and Southeast Asia and more than 100 representatives for the embassies in the People's Republic of China from 13 countries discussed the trend,progress and utilization of borehole technology and the service strength of CNPC's borehole technology together.The honorable attendees can further know the technical strength of CNPC S&E through this communication,and therefore find out the best cooperation way to create a higher value for the oil company in one hand, and improve the force and popularity of CNPC S&E in the international market on the other hand.

  14. Sample Preparation (SS): SE55_SS01 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available 80℃ until analysis. The frozen tissues were homogenized in five volumes of 80% aqueous methanol containing 0...SE55_SS01 Metabolic profiling Collected sample tissues were weighed and stored at -

  15. Sample (S): SE41_S03 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE41_S03 Solanum lycopersicum KTP001 fruit, stage 3 Solanum lycopersicum NCBI taxon...omy:4081 Solanum lycopersicum KTP001 are grown in an agricultural field of KAGOME CO., LTD. ...

  16. Sample (S): SE40_S01 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE40_S01 Solanum lycopersicum KTP001 fruit Solanum lycopersicum NCBI taxonomy:4081 Solanum lycopersicum KTP0...01 are grown in greenhouses of Kagome Co., Ltd. from summer 2013 to spring 2014. ...

  17. Sample (S): SE41_S04 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE41_S04 Solanum lycopersicum KTP001 fruit, stage 4 Solanum lycopersicum NCBI taxon...omy:4081 Solanum lycopersicum KTP001 are grown in an agricultural field of KAGOME CO., LTD. ...

  18. Sample (S): SE41_S02 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE41_S02 Solanum lycopersicum KTP001 fruit, stage 2 Solanum lycopersicum NCBI taxon...omy:4081 Solanum lycopersicum KTP001 are grown in an agricultural field of KAGOME CO., LTD. ...

  19. Sample (S): SE41_S01 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE41_S01 Solanum lycopersicum KTP001 fruit, stage 1 Solanum lycopersicum NCBI taxon...omy:4081 Solanum lycopersicum KTP001 are grown in an agricultural field of KAGOME CO., LTD. ...

  20. Electronic Properties of Graphene–PtSe2 Contacts

    KAUST Repository

    Sattar, Shahid

    2017-04-26

    In this article, we study the electronic properties of graphene in contact with monolayer and bilayer PtSe2 using first-principles calculations. It turns out that there is no charge transfer between the components because of the weak van der Waals interaction. We calculate the work functions of monolayer and bilayer PtSe2 and analyze the band bending at the contact with graphene. The formation of an n-type Schottky contact with monolayer PtSe2 and a p-type Schottky contact with bilayer PtSe2 is demonstrated. The Schottky barrier height is very low in the bilayer case and can be reduced to zero by 0.8% biaxial tensile strain.

  1. Chemical bath ZnSe thin films: deposition and characterisation

    Science.gov (United States)

    Lokhande, C. D.; Patil, P. S.; Ennaoui, A.; Tributsch, H.

    1998-01-01

    The zinc selenide (ZnSe) thin films have been deposited by a simple and inexpensive chemical bath deposition (CBD) method. The selenourea was used as a selenide ion source. The ZnSe films have been characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDAX), Rutherford back scattering (RBS), and optical absorption. The as-deposited ZnSe films on various substrates are found to be amorphous and contain O2 and N2 in addition to Zn and Se. The optical band gap of the film is estimated to be 2.9 eV. The films are photoactive as evidenced by time resolved microwave conductivity (TRMC).

  2. Structural and optical properties of homogeneous Cu(In,Ga)Se2 thin films prepared by thermal reaction of InSe/Cu/GaSe alloys with elemental Se vapour

    Science.gov (United States)

    Dejene, F. B.; Alberts, V.

    2005-01-01

    In this study, thin films of Cu(In,Ga)Se2 were prepared by the controlled reaction of thermally evaporated InSe/Cu/GaSe precursors with elemental Se vapour in vacuum. We indicate that this classical two-step growth process can be utilized to produce homogeneous single-phase chalcopyrite absorber films with superior structural properties. X-ray diffraction studies indicated that the interplanar spacing d(112) decreases linearly with an increase in the Ga/[In + Ga] atomic ratio due to homogeneous incorporation of gallium into the chalcopyrite lattice. Optical studies revealed the expected systematic increase in the band gap with increasing gallium concentration, once again confirming the monophasic nature of the alloys.

  3. Structural and optical properties of homogeneous Cu(In,Ga)Se{sub 2} thin films prepared by thermal reaction of InSe/Cu/GaSe alloys with elemental Se vapour

    Energy Technology Data Exchange (ETDEWEB)

    Dejene, F B; Alberts, V [Department of Physics, Rand Afrikaans University, PO Box 524, Johannesburg (South Africa)

    2005-01-07

    In this study, thin films of Cu(In,Ga)Se{sub 2} were prepared by the controlled reaction of thermally evaporated InSe/Cu/GaSe precursors with elemental Se vapour in vacuum. We indicate that this classical two-step growth process can be utilized to produce homogeneous single-phase chalcopyrite absorber films with superior structural properties. X-ray diffraction studies indicated that the interplanar spacing d{sub (112)} decreases linearly with an increase in the Ga/[In + Ga] atomic ratio due to homogeneous incorporation of gallium into the chalcopyrite lattice. Optical studies revealed the expected systematic increase in the band gap with increasing gallium concentration, once again confirming the monophasic nature of the alloys.

  4. Sample (S): SE57_S08 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE57_S08 Lotus japonicus (accessions B129 gifu and MG20 miyakojima) Lotus japonicus... NCBI taxonomy:34305 Lotus japonicus accessions were a gift from Dr. Toshio Aoki (Nihon University, Japan). ...

  5. Sample (S): SE19_S2 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE19_S2 Mouse white adipose tissue (WAT) Mus musculus NCBI taxonomy:10090 Mice (C57...BL/6) were purchased from SLC, Shizuoka, Japan. White adipose tissue was extracted and used. ...

  6. Comparison of diffusivity data derived from electrochemical and NMR investigations of the SeCN¯/(SeCN)2/(SeCN)3¯ system in ionic liquids.

    Science.gov (United States)

    Solangi, Amber; Bond, Alan M; Burgar, Iko; Hollenkamp, Anthony F; Horne, Michael D; Rüther, Thomas; Zhao, Chuan

    2011-06-02

    Electrochemical studies in room temperature ionic liquids are often hampered by their relatively high viscosity. However, in some circumstances, fast exchange between participating electroactive species has provided beneficial enhancement of charge transport. The iodide (I¯)/iodine (I(2))/triiodide (I(3)¯) redox system that introduces exchange via the I¯ + I(2) ⇌ I(3)¯ process is a well documented example because it is used as a redox mediator in dye-sensitized solar cells. To provide enhanced understanding of ion movement in RTIL media, a combined electrochemical and NMR study of diffusion in the {SeCN¯-(SeCN)(2)-(SeCN)(3)¯} system has been undertaken in a selection of commonly used RTILs. In this system, each of the Se, C and N nuclei is NMR active. The electrochemical behavior of the pure ionic liquid, [C(4)mim][SeCN], which is synthesized and characterized here for the first time, also has been investigated. Voltammetric studies, which yield readily interpreted diffusion-limited responses under steady-state conditions by means of a Random Assembly of Microdisks (RAM) microelectrode array, have been used to measure electrochemically based diffusion coefficients, while self-diffusion coefficients were measured by pulsed field gradient NMR methods. The diffusivity data, derived from concentration and field gradients respectively, are in good agreement. The NMR data reveal that exchange processes occur between selenocyanate species, but the voltammetric data show the rates of exchange are too slow to enhance charge transfer. Thus, a comparison of the iodide and selenocyanate systems is somewhat paradoxical in that while the latter give RTILs of low viscosity, sluggish exchange kinetics prevent any significant enhancement of charge transfer through direct electron exchange. In contrast, faster exchange between iodide and its oxidation products leads to substantial electron exchange but this effect does not compensate sufficiently for mass transport

  7. Template free-solvothermaly synthesized copper selenide (CuSe, Cu 2- xSe, β-Cu 2Se and Cu 2Se) hexagonal nanoplates from different precursors at low temperature

    Science.gov (United States)

    Kumar, Pushpendra; Singh, Kedar; Srivastava, O. N.

    2010-09-01

    Nonstoichiometric (Cu 2- xSe) and stoichiometric (CuSe, β-Cu 2Se and Cu 2Se) copper selenide hexagonal nanoplates have been synthesized using different general and convenient copper sources, e.g. copper chloride, copper sulphate, copper nitrate, copper acetate, elemental copper with elemental selenium, friendly ethylene glycol and hydrazine hydrate in a defined amount of water at 100 °C within 12 h adopting the solvothermal method. Phase analysis, purity and morphology of the product have been well studied by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM) and energy dispersive X-ray diffraction (EDAX) techniques. The structural and compositional analysis revealed that the products were of pure phase with corresponding atomic ratios. SEM, TEM and HRTEM analyses revealed that the nanoplates were in the range 200-450 nm and the as-prepared products were uniform and highly crystallized. The nanoplates consisted of {0 0 1} facets of top-bottom surfaces and {1 1 0} facets of the other six side surfaces. This new approach encompasses many advantages over the conventional solvothermal method in terms of product quality (better morphology control with high yield) and reaction conditions (lower temperatures). Copper selenide hexagonal nanoplates obtained by the described method could be potential building blocks to construct functional devices and solar cell. This work may open up a new rationale on designing the solution synthesis of nanostructures for materials possessing similar intrinsic crystal symmetry. On the basis of the carefully controlled experiments mentioned herein, a plausible formation mechanism of the hexagonal nanoplates was suggested and discussed. To the best of our knowledge, this is the first report on nonstoichiometric (Cu 2- xSe) as well as stoichiometric (CuSe, β-Cu 2Se and Cu 2Se) copper selenide hexagonal nanoplates with

  8. Det monstrøse i Ezekiels vision

    DEFF Research Database (Denmark)

    Nielsen, Kirsten

    2011-01-01

    Artiklen viser, hvordan det monstrøse introduceres i Ezekiels Bog kap. 1 i form af nogle sammensatte levende væsener, der har træk hentet fra både menneske- og dyreverdenen. Det monstrøse består i denne overskridelse af de gængse grænser og problematiserer dermed de velkendte klassifikationer. Og...

  9. de drogas que se consumen en su medio

    Directory of Open Access Journals (Sweden)

    José F. Enríquez Bielma

    2006-01-01

    Full Text Available Las adicciones son un problema de salud pública. Se estima que en México 3.5 millones de personas entre 12 a los 65 años han consumido algún tipo de drogas. A pesar de los avances en los estudios, se ha dejado de lado el carácter cultural que tiene la adicción. Con este estudio, se deseba conocer qué saben los estudiantes de segundo de secundaria sobre cuáles son las drogas que se consumen en su medio. Se llevó a cabo un estudio observacional con un muestreo aleatorio, con múltiples etapas y proporcional al tamaño en escuelas públicas y privadas. En total se estudiaron 42 escuelas del municipio de León, Gto., México de las cuales el 76.2% lo conformaron las escuelas públicas y el resto las escuelas privadas. Refirieron que conocen que se consumen, en su medio, 11 tipos de drogas. El 88% mencionó a la cocaína en primer lugar, en segundo lugar con un 85% la marihuana, siguiendo las tachas en un 62% y el pegamento en un 49%. En cuanto a los nombres que los estudiantes le dan a las drogas, estos van desde 23 hasta los 4 nombres, siendo la marihuana a la que se le da el mayor número de nombres, seguidos de la cocaína y el éxtasis.

  10. Lattice Dynamic of Ag8SnSe6 Crystal

    Directory of Open Access Journals (Sweden)

    I.V. Semkiv

    2016-10-01

    Full Text Available The synthesis and structure properties of Ag8SnSe6 argyrodite are described. Argyrodite belongs to the orthorhombic space group Pmn21 with 15 atoms per primitive cell. Classification of the main phonon modes of crystal carried out. First-principles phonon-dispersion curves for argyrodite Ag8SnSe6 are calculated. Peak position in Raman spectra and IR-spectra was clarified.

  11. High pressure phase transitions for CdSe

    Indian Academy of Sciences (India)

    Bo Kong; Ti-Xian Zeng; Zhu-Wen Zhou; De-Liang Chen; Xiao-Wei Sun

    2014-05-01

    The structure and pressure-induced phase transitions for CdSe are investigated using first-principles calculations. The pressure-induced phase transition sequence WZ/ZB $\\to$ Rs $\\to$ $\\to$ CsCl for CdSe is drawn reasonably for the fist time, the corresponding transition pressures are 3.8, 29 and 107 GPa, respectively and the intermediate states between the structure and the CsCl structure should exist.

  12. Synthesis and Characterization of the CdSe/ZnSe/ZnS Multishell Quantum Dots%CdSe/ZnSe/ZnS多壳层结构量子点的制备与表征

    Institute of Scientific and Technical Information of China (English)

    张庆彬; 曾庆辉; 郑金桔; 孔祥贵; 曲玉秋; 宋凯

    2009-01-01

    展示了一种简捷的多壳层量子点合成路线.在含有过量Se源的CdSe体系中直接注入Zn源,"一步法"合成了CdSe/ZnSe量子点;进一步以CdSe/ZnSe为"核",表面外延生长ZnS壳层制备了核/壳/壳结构CdSe/ZnSe/ZnS量子点.相对于以往报道的多壳层结构量子点的制备方法,该方法通过减少壳层的生长步骤有效地简化了实验操作,缩短了实验周期,同时减少对原料的损耗.对量子点进行高温退火处理,能够大幅提高CdSe/ZnSe/ZnS量子点的发光量子产率.透射电镜、XRD以及光谱研究表明:所制备的量子点接近球形,核与壳层纳米晶均为闪锌矿结构,最终获得的CdSe/ZnSe/ZnS量子点的光致发光量子产率达到53%.为了实现量子点的表面生物功能化,通过巯基酸进行了表面配体交换修饰,使量子点表面具有水溶性的羧基功能团,并且能够维持较高的光致发光量子产率.

  13. Annotation Method (AM): SE1_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available base search. Peaks with no hit to these databases are then selected to secondary se...arch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are ma...SE1_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary data

  14. Annotation Method (AM): SE41_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available se search. Peaks with no hit to these databases are then selected to secondary sear...ch using EX-HR2 (http://webs2.kazusa.or.jp/mfsearcher/) databases. After the database search processes, each database...SE41_AM1 PowerGet annotation In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary databa

  15. Annotation Method (AM): SE9_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available base search. Peaks with no hit to these databases are then selected to secondary se...arch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are ma...SE9_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary data

  16. Annotation Method (AM): SE2_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available base search. Peaks with no hit to these databases are then selected to secondary se...arch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are ma...SE2_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary data

  17. Annotation Method (AM): SE3_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available base search. Peaks with no hit to these databases are then selected to secondary se...arch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are ma...SE3_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary data

  18. Annotation Method (AM): SE40_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available se search. Peaks with no hit to these databases are then selected to secondary sear...ch using EX-HR2 (http://webs2.kazusa.or.jp/mfsearcher/) databases. After the database search processes, each database...SE40_AM1 PowerGet annotation In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary databa

  19. Annotation Method (AM): SE7_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available base search. Peaks with no hit to these databases are then selected to secondary se...arch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are ma...SE7_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary data

  20. Annotation Method (AM): SE5_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available base search. Peaks with no hit to these databases are then selected to secondary se...arch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are ma...SE5_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary data

  1. Annotation Method (AM): SE6_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available base search. Peaks with no hit to these databases are then selected to secondary se...arch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are ma...SE6_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary data

  2. Annotation Method (AM): SE4_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available base search. Peaks with no hit to these databases are then selected to secondary se...arch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are ma...SE4_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary data

  3. Annotation Method (AM): SE8_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available base search. Peaks with no hit to these databases are then selected to secondary se...arch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are ma...SE8_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary data

  4. Hjemløse borgeres sygdom og brug af sundhedsydelser

    DEFF Research Database (Denmark)

    Benjaminsen, Lars; Birkelund, Jesper Fels; Enemark, Morten Holm

    borgere. Både skadestue, læge og vagtlæge bliver besøgt væsentligt oftere af de hjemløse borgere end af den resterende befolkning. Men selv om hjemløse borgere oftere bruger sundhedsydelser generelt, så er der også klinikker, hvor de ikke kommer så tit. Rapporten viser blandt andet, at de sjældent besøger...

  5. On the reversibility window in binary As-Se glasses

    Energy Technology Data Exchange (ETDEWEB)

    Golovchak, R. [Lviv Scientific Research Institute of Materials of SRC ' Carat' , 202 Stryjska str., Lviv UA-79031 (Ukraine); Institute of Physics of Jan Dlugosz University, 13/15 al. Armii Krajowej, Czestochowa PL-42201 (Poland); Faculty of Physics of Opole University of Technology, 75 Ozimska str., Opole PL-45370 (Poland); Shpotyuk, O. [Lviv Scientific Research Institute of Materials of SRC ' Carat' , 202 Stryjska str., Lviv UA-79031 (Ukraine); Institute of Physics of Jan Dlugosz University, 13/15 al. Armii Krajowej, Czestochowa PL-42201 (Poland)], E-mail: shpotyuk@novas.lviv.ua; Kozdras, A. [Faculty of Physics of Opole University of Technology, 75 Ozimska str., Opole PL-45370 (Poland)

    2007-10-29

    Physical ageing effects caused by prolonged natural storage are recorded for binary As{sub x}Se{sub 1-x} glasses with 0.2{<=}x<0.4. Their origin is associated with pure 'shrinkage' of under-constrained glass networks. It is shown that only stoichiometric As{sub 2}Se{sub 3} composition, which network is formed by a so-called self-organized phase, possesses the ideal non-ageing ability.

  6. Low temperature magnetic structure of MnSe

    Indian Academy of Sciences (India)

    J B C Efrem D'sa; P A Bhobe; K R Priolkar; A Das; P S R Krishna; P R Sarode; R B Prabhu

    2004-08-01

    In this paper we report low temperature neutron diffraction studies on MnSe in order to understand the anomalous behaviour of their magnetic and transport properties. Our study indicates that at low temperatures MnSe has two coexisting crystal structures, high temperature NaCl and hexagonal NiAs. NiAs phase appears below 266 K and is antiferromagnetically ordered at all temperatures while the NaCl phase orders antiferromagnetically at 130 K.

  7. Processing ambiguous Spanish se in a minimal chain.

    Science.gov (United States)

    Meseguer, Enrique; Acuña-Fariña, Carlos; Carreiras, Manuel

    2009-04-01

    The recovery of pieces of information that are not linguistically expressed is a constant feature of the process of language comprehension. In the processing literature, such missing information is generally referred to as "gaps". Usually, one resolves gaps by finding "fillers" in either the sentence or the context. For instance, in Peter seemed to be upset, Peter is really the subject of being upset but appears as surface subject of seems. Sometimes constituents move, leaving gaps behind. Various Romance languages such as Spanish or Italian have a grammatical particle se/si, which, as it is extremely ambiguous, licenses different sorts of gaps. In Spanish, se can encode at least reflexive, impersonal, and passive meanings. In an eye-tracking experiment we contrast reflexive structures containing postverbal subjects with impersonal structures with no subjects (GAP se vendó apresuradamente el corredor/"the runner bandaged himself hurriedly" vs. GAP se vendó apresuradamente al corridor/"(someone) bandaged the runner hurriedly"). In a second manipulation we contrast the presence of an extra argument with se-passives (GAP se vendó el tobillo el corredor/"the runner bandaged his ankle" vs. GAP se vendó el tobillo al corridor/"the runner's ankle was bandaged"). Our comparisons involve contrasting standard transitive structures with nonstandard word order (postverbal subject and a preverbal subject gap) against inherently complex and less habitual structures such as impersonals (with no subject) or se-passives (with subjects in canonical object position). We evaluate the minimal chain principle (de Vincenzi, 1991), according to which displacement is costly because it entails complex (derivational) "chains" that must be undone before phrasal packaging can commence. We show the minimal chain principle to be essentially correct when contrasting more complex but more frequent structures with less complex but less frequent structures. A noteworthy feature of this research

  8. Magnetotransport studies of FeSe under hydrostatic pressure

    Science.gov (United States)

    Tiwari, Brajesh; Jha, Rajveer; Awana, V. P. S.

    2014-06-01

    The discoveries of iron-based superconductors with relatively high transition temperature are under intense experimental and theoretical investigation. Here we present magnetotransport measurements on FeSe superconductor under hydrostatic pressure. We show that in Fe-deficient tetragonal FeSe binary compound, the onset of superconducting transition is almost doubled under 1.98 GPa pressure and the estimated upper critical field of 26.7 Tesla is increased to 47.5 Tesla.

  9. «Y se apagan las luces…»

    OpenAIRE

    Cotera, Liset

    2013-01-01

    En este artículo se reflexiona sobre el cine para niños como género cinematográfico, la importancia de acercar a los niños al cine y ofrecerles una opción cinematográfica y se comparte la experiencia de La Matatena, Asociación de Cine para Niñas y Niños, A.C., en México

  10. Investigation of CuGaSe2/CuInSe2 double heterojunction interfaces grown by molecular beam epitaxy

    OpenAIRE

    Sathiabama Thiru; Masaki Asakawa; Kazuki Honda; Atsushi Kawaharazuka; Atsushi Tackeuchi; Toshiki Makimoto; Yoshiji Horikoshi

    2015-01-01

    In-situ reflection high-energy electron diffraction (RHEED) observation and X-ray diffraction measurements were performed on heterojunction interfaces of CuGaSe2/CnInSe2/CuGaSe2 grown on GaAs (001) using migration-enhanced epitaxy. The streaky RHEED pattern and persistent RHEED intensity oscillations caused by the alternate deposition of migration-enhanced epitaxy sequence are observed and the growths of smooth surfaces are confirmed. RHEED observation results also confirmed constituent mater...

  11. MULTIPLE EXCITON GENERATIONSOLAR CELLS USING CdSe QUANTUM DOTS

    Directory of Open Access Journals (Sweden)

    HAFTOM MESFIN GEBRESLASSIE,

    2011-03-01

    Full Text Available Experimental and Simulation works of Nano structured Solar Cells Using CdSe Quantum Dots have been analyzed and investigated. CdSe quantum dots have been synthesized from non coordinating and highboiling solvent Octadecene and a series of increasing CdSe particle sizes are produced. The synthesized CdSe quantum dots are highly examined under a Transmission Electron Microscope and four images ofdifferent sizes of CdSe quantum dots (5.8 nm, 6.4 nm, 7.0 nm and 7.7 nm have been obtained. A 1.1x1.1cm2 TiO2 electrode is prepared using indium tin oxide conducting glass and TiO2 nanoparticles. The CdSe quantum dot (5.8nm was adsorbed on TiO2 photoelectrode and used as sensitizer. In this paper work, a sandwich type cell configuration which is made up of TiO2 photoelectrode, graphite coated counter electrode, an electrolyte of iodine and potassium iodide have been used. This sandwich type cell has been exposed to sun light and we have achieved 0.32 V and 0.2 mA

  12. PbSe nanocubes obtained by high-energy milling

    Energy Technology Data Exchange (ETDEWEB)

    Rojas-Chavez, H., E-mail: hrojasc@ipn.mx [Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada - IPN (Mexico); Reyes-Carmona, F. [Facultad de Quimica - UNAM (Mexico); Achimovicova, M. [Slovak Academy of Sciences, Institute of Geotechnics (Slovakia); Daneu, N. [Jozef Stefan Institute, Department for Nanostructured Materials (Slovenia); Jaramillo-Vigueras, D. [Centro de Investigacion e Innovacion Tecnologica - IPN (Mexico)

    2012-06-15

    In this study, PbSe nanocubes were obtained by high-energy milling, and their optical properties were investigated by measuring the UV-VIS-IR spectra in the range of 200-2,000 nm. The optical absorption of all samples showed a strong UV emission band at 1.45 eV. Previously, to obtain only PbSe nanocubes, an intermediate phase was identified, PbSeO{sub 3}. Although both PbSeO{sub 3} and PbSe were traced through this study, a major effort is devoted to characterize the latter. To trace how chemical transitions evolve from precursors to PbSe, X-ray diffraction and Rietveld refinement were carried out. Therefore, the following parameters were evaluated as a function of milling time: phase percentages, area-to-volume ratio, average crystallite dimensions, specific surface area, and morphology changes. To corroborate previous findings, nitrogen adsorption and transmission electron microscopy techniques were used. All the set experimental results unambiguously confirm that crystallites show a cubic morphology, with its average crystallite size distribution being around 24 nm.

  13. Preparation and characterization of polycrystalline n-CdSe photoelectrode

    Energy Technology Data Exchange (ETDEWEB)

    Bandyopadhyay, T.K.

    1979-01-01

    Thin layers of polycrystalline p-CdSe were prepared by the simultaneous eletrodeposition of cadmium and selenium from cadmium sulfate and selenious acid in a sulfuric acid solution at pH 0-1 on a titanium substrate. The adherence of the layers to the substrate, stoichiometric ratio of Cd:Se and photovoltaic property of the film depend upon the molar ratio of CdSO/sub 4/ and H/sub 2/SeO/sub 3/ and current density as well as on the pH and temperature of the electrolysis bath. On increasing the current density or the ratio of CdSO/sub 4/:H/sub 2/SeO/sub 3/ in the electrolysis bath, the Cd:Se of the electrodeposit increased. The semiconductor films so prepared were annealed at 550/sup 0/C in a nitrogen atmosphere, followed by etching in an acid solution and then used to construct the photo-electrochemical cell, Ti/CdSe/Na/sub 2/S-Na/sub 2/S/sub x/(aq.)/Pt, and the current-voltage curves have been studied. 11 references.

  14. Electron transport in stepped Bi2Se3 thin films

    Science.gov (United States)

    Bauer, S.; Bobisch, C. A.

    2017-08-01

    We analyse the electron transport in a 16 quintuple layer thick stepped Bi2Se3 film grown on Si(1 1 1) by means of scanning tunnelling potentiometry (STP) and multi-point probe measurements. Scanning tunnelling microscopy images reveal that the local structure of the Bi2Se3 film is dominated by terrace steps and domain boundaries. From a microscopic study on the nm scale by STP, we find a mostly linear gradient of the voltage on the Bi2Se3 terraces which is interrupted by voltage drops at the position of the domain boundaries. The voltage drops indicate that the domain boundaries are scatterers for the electron transport. Macroscopic resistance measurements (2PP and in-line 4PP measurement) on the µm scale support the microscopic results. An additional rotational square 4PP measurement shows an electrical anisotropy of the sheet conductance parallel and perpendicular to the Bi2Se3 steps of about 10%. This is a result of the anisotropic step distribution at the stepped Bi2Se3 surface while domain boundaries are distributed isotropically. The determined value of the conductivity of the Bi2Se3 steps of about 1000 S cm-1 verifies the value of an earlier STP study.

  15. Pseudodynamic imaging of the temporomandibular joint: SE versus GE sequences

    Energy Technology Data Exchange (ETDEWEB)

    Masui, Takayuki; Isoda, Haruo; Mochizuki, Takao [Hamamatsu Univ. School of Medicine, Hamamatsu City (Japan)] [and others

    1996-05-01

    Pseudodynamic MR imaging of the temporomandibular joints (TMJs) has been used for the evaluation of the functional aspects of the TMJs. To evaluate the value of T1-weighted spin-echo (SE) and gradient-echo (GE) techniques, both techniques were performed in 9 asymptomatic (mean 25.7 years, 22-32 years), and 25 symptomatic (mean 44.9 years, 20-71 years) subjects with signs and symptoms of internal derangement or osteoarthrosis of the TMJs. The imaging time for the SE (180 ms / 15 ms / 110{degrees} repetition time / echo time /flip angle) and GE (fast low angle shot; FLASH, 90 ms / 12 ms / 40{degrees}) sequences was 27 and 28 s, respectively. In asymptomatic and symptomatic subjects, the confidence of the identification of the meniscal position was better on SE than GE images (3.6 {+-} 0.6 vs. 2.9 {+-} 0.9, p < 0.01, 3.2 {+-} 0.8 vs. 2.8 {+-} 0.8, p < 0.05), respectively and the sizes of the menisci were bigger on SE than GE images. The delineation of the condylar cortex was better on GE than SE images. For pseudodynamic imaging display of the TMJs, the SE images might be better than GE images to provide the stable recognition of the menisci. 17 refs., 7 figs., 5 tabs.

  16. NaviSE: superenhancer navigator integrating epigenomics signal algebra.

    Science.gov (United States)

    Ascensión, Alex M; Arrospide-Elgarresta, Mikel; Izeta, Ander; Araúzo-Bravo, Marcos J

    2017-06-06

    Superenhancers are crucial structural genomic elements determining cell fate, and they are also involved in the determination of several diseases, such as cancer or neurodegeneration. Although there are pipelines which use independent pieces of software to predict the presence of superenhancers from genome-wide chromatin marks or DNA-interaction protein binding sites, there is not yet an integrated software tool that processes automatically algebra combinations of raw data sequencing into a comprehensive final annotated report of predicted superenhancers. We have developed NaviSE, a user-friendly streamlined tool which performs a fully-automated parallel processing of genome-wide epigenomics data from sequencing files into a final report, built with a comprehensive set of annotated files that are navigated through a graphic user interface dynamically generated by NaviSE. NaviSE also implements an 'epigenomics signal algebra' that allows the combination of multiple activation and repression epigenomics signals. NaviSE provides an interactive chromosomal landscaping of the locations of superenhancers, which can be navigated to obtain annotated information about superenhancer signal profile, associated genes, gene ontology enrichment analysis, motifs of transcription factor binding sites enriched in superenhancers, graphs of the metrics evaluating the superenhancers quality, protein-protein interaction networks and enriched metabolic pathways among other features. We have parallelised the most time-consuming tasks achieving a reduction up to 30% for a 15 CPUs machine. We have optimized the default parameters of NaviSE to facilitate its use. NaviSE allows different entry levels of data processing, from sra-fastq files to bed files; and unifies the processing of multiple replicates. NaviSE outperforms the more time-consuming processes required in a non-integrated pipeline. Alongside its high performance, NaviSE is able to provide biological insights, predicting cell

  17. Системи AgInSe2 – AgGaSe2 та AgInSe2 – Ag9GaSe6

    OpenAIRE

    Олексеюк, І. Д.; Іващенко, І. А.; Данилюк, І. В.; Olekseyuk, I. D.; I. A. Ivashchenko; Danylyuk, I. V.

    2010-01-01

    Враховуючи дані, отримані за результатами РФА, МСА, ДТА та поміру мікротвердості, було побудовано діаграми стану систем AgInSe2 – AgGaSe2 та AgInSe2 – Ag9GaSe6. У системі AgInSe2 – AgGaSe2 існує евтектична точка LE ↔ α + β при 1030 К та 24 мол. % AgGaSe2, де α – тверді розчини на основі високотемпературної модифікації (ВТМ) AgInSe2, β – тверді розчини на основі сполуки AgGaSe2 та низькотемпературної модифікації (НТМ) AgInSe2. Нескінченний ряд β-твердих розчинів кристалізується в с...

  18. Detection of a ZnSe secondary phase in coevaporated Cu2ZnSnSe4 thin films

    Science.gov (United States)

    Redinger, Alex; Hönes, Katja; Fontané, Xavier; Izquierdo-Roca, Victor; Saucedo, Edgardo; Valle, Nathalie; Pérez-Rodríguez, Alejandro; Siebentritt, Susanne

    2011-03-01

    Cu2ZnSnSe4 (CZTSe) thin films are grown by coevaporation. Composition depth profiles reveal that a Zn rich phase is present at the CZTSe/Mo interface. Raman measurements on the as grown films are used to study the near surface region and the CZTSe/Mo interface, after mechanically removing the thin film from the Mo coated glass. These measurements provide direct experimental evidence of the formation of a ZnSe phase at the CZTSe/Mo interface. While the Raman spectra at the surface region are dominated by CZTSe modes, those measured at the CZTSe/Mo interface are dominated by ZnSe and MoSe2 modes.

  19. Photoluminescence brightening via electrochemical trap passivation in ZnSe and Mn(2+)-doped ZnSe quantum dots.

    Science.gov (United States)

    Weaver, Amanda L; Gamelin, Daniel R

    2012-04-18

    Spectroelectrochemical experiments on wide-gap semiconductor nanocrystals (ZnSe and Mn(2+)-doped ZnSe) have allowed the influence of trap electrochemistry on nanocrystal photoluminescence to be examined in the absence of semiconductor band filling. Large photoluminescence electrobrightening is observed in both materials upon application of a reducing potential and is reversed upon return to the equilibrium potential. Electrobrightening is correlated with the transfer of electrons into nanocrystal films, implicating reductive passivation of midgap surface electron traps. Analysis indicates that the electrobrightening magnitude is determined by competition between electron trapping and photoluminescence (ZnSe) or energy transfer (Mn(2+)-doped ZnSe) dynamics within the excitonic excited state, and that electron trapping is extremely fast (k(trap) ≈ 10(11) s(-1)). These results shed new light on the complex surface chemistries of semiconductor nanocrystals. © 2012 American Chemical Society

  20. Phonon instability in the CDW systems 2H-NbSe{sub 2} and TiSe{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Hott, Roland; Heid, Rolf; Bohnen, Klaus-Peter [Karlsruhe Institute of Technology, Institute of Solid State Physics, P. O. Box. 3640, D-76021 Karlsruhe (Germany); Weber, Frank [Karlsruhe Institute of Technology, Institute of Solid State Physics, P. O. Box. 3640, D-76021 Karlsruhe (Germany); Materials Science Division, Argonne National Laboratory, Argonne, Illinois, 60439 (United States); Rosenkranz, Stephan; Castellan, John-Paul; Osborn, Raymond; Karapetrov, Goran [Materials Science Division, Argonne National Laboratory, Argonne, Illinois, 60439 (United States); Egami, Takeshi [Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee, 37996 (United States); Said, Ayman [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois, 60439 (United States); Reznik, Dmitry [Karlsruhe Institute of Technology, Institute of Solid State Physics, P. O. Box. 3640, D-76021 Karlsruhe (Germany); Department of Physics, University of Colorado at Boulder, Boulder, Colorado, 80309 (United States)

    2012-07-01

    Further investigations on the soft-mode behaviour of phonons in the Charge Density Wave (CDW) systems 2H-NbSe{sub 2} and TiSe{sub 2} have been performed both theoretically in Density Functional Theory (DFT) based on ab-initio phonon calculations as well as experimentally by means of high resolution Inelastic X-ray Scattering (IXS). For both materials, the theoretical predictions for the phonon softening coincide with the experimentally observed CDW instability behaviour. For 2H-NbSe{sub 2} the wave vector dependence of the electron-phonon coupling drives the CDW formation and determines its periodicity. For TiSe{sub 2}, electron-phonon-coupling is strong enough to stabilize the structural phase transition at finite temperatures.

  1. Anisotropy of chemical transformation from In2Se3 to CuInSe2 nanowires through solid state reaction.

    Science.gov (United States)

    Schoen, David T; Peng, Hailin; Cui, Yi

    2009-06-17

    In(2)Se(3) nanowires synthesized by the VLS technique are transformed by solid-state reaction with copper into high-quality single-crystalline CuInSe(2) nanowires. The process is studied by in situ transmission electron microscopy. The transformation temperature exhibits a surprising anisotropy, with In(2)Se(3) nanowires grown along their [0001] direction transforming at a surprisingly low temperature of 225 degrees C, while nanowires in a [11(2)0] orientation require a much higher temperature of 585 degrees C. These results offer a route to the synthesis of CuInSe(2) nanowires at a relatively low temperature as well as insight into the details of a transformation commonly used in the fabrication of thin-film solar cells.

  2. Nanocomposite Material Based on GaSe and InSe Layered Crystals Intercalated by RbNO3 Ferroelectric

    Directory of Open Access Journals (Sweden)

    Z.R. Kudrynskyi

    2013-10-01

    Full Text Available In the present study, we established for the first time that single-crystal samples of gallium GaSe and indium InSe selenides can be intercalated by molecules of RbNO3 ferroelectric salt rubidium nitrate. We investigated kinetics of the intercalation process at different temperature-time regimes. Structural properties of the intercalate nanocomposites were studied by X-ray diffraction. The studied structures can be presented as composite superlattices which consist of a lattice of anisotropic layered semiconductor with embedded ferroelectric layers. We established that GaSe nanocomposite material exhibits electric energy storage properties. Energy storage properties are associated with polarization of the intercalated ferroelectric under external electric field. We developed a solid state electric energy storage device on the basis of GaSe nanocomposite material.

  3. Resonant Raman scattering in GaSe and GaS/sub x/Se/sub 1-x/

    Energy Technology Data Exchange (ETDEWEB)

    Chiang, T.C.; Camassel, J.; Voitchovsky, J.P.; Shen, Y.R.

    1976-07-01

    Multiphonon resonant Raman scattering up to four phonons in GaSe and one and two phonon resonant Raman scattering in the mixed GaS/sub x/Se/sub 1 - x/ crystals with x less than or equal to 0.23 were investigated. The results can be explained by a simple theory in which the dispersion of the resonance behavior is mainly dominated by resonances with the 1s direct exciton state.

  4. CdSe quantum dot in a ZnSe nanowire as an efficient source of single photons

    Energy Technology Data Exchange (ETDEWEB)

    Tribu, A.; Aichele, T.; Kheng, K. [CEA/CNRS Group Nanophysique et Semi-Conducteurs, CEA/INAC/SP2M, Grenoble (France); Sallen, G.; Bougerol, C.; Andre, R.; Poizat, J.P.; Tatarenko, S. [CEA/CNRS Group Nanophysique et Semi-Conducteurs, Institut Neel CNRS, Universite J. Fourier Grenoble (France)

    2009-04-15

    We report on our development of fabrication of CdSe QD in ZnSe nanowire. We have been able to obtain high quality structures with very good optical properties. This has allowed us to measure photon emission from single quantum dots and to demonstrate photon antibunching. We show that this new type of II-VI quantum dot is very promising for high temperature operation. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  5. Sobre la forma de garantizar la trazabilidad metrológica en los sistemas hospitalarios

    OpenAIRE

    Fernández Sánchez, Alfonso Marín

    2016-01-01

    Dentro del equipamiento que existen en los hospitales, se realizan muy diversas actuaciones para el correcto funcionamiento de los equipos que se destinan, tanto a medir sobre el paciente o para tratamiento sobre estos mismos, el abanico de equipos que existen es muy grande, sin contar con los que directamente se instalan o, más correctamente, se implantan en el paciente. Los hospitales tienen establecidas pautas de mantenimiento tanto correctivo como preventivo, también de verificación relat...

  6. Distopie voor oë: Eben Venter se duister kuns

    Directory of Open Access Journals (Sweden)

    Harry Sewlall

    2016-03-01

    Full Text Available Sedert die verskyning van Joseph Conrad se novelle, Heart of Darkness, uitgegee as vervolgverhaal in 1899, was daar al verskeie pogings om Conrad se teks te ‘herskryf’, al was die verwantskap met die meesterteks dikwels gering of selfs twyfelagtig. Nog ’n herskrywing van Conrad se teks is Eben Venter se roman Trencherman, aanvanklik in Afrikaans uitgegee as Horrelpoot. Hierdie teks volg die meesterteks baie nougeset na, nie slegs deur aanhalings daaruit as motto’s vooraan elke hoofstuk te gebruik nie, maar ook deur beelde en woorde uit die oorspronklike teks op ooglopende of bedekte wyse in die narratief in te weef. Die vrae waarmee ’n leser soos ek, wat nie vertroud is met Afrikaans nie, gekonfronteer word, is of dit ’n geval van plagiaat is of ’n oefening in intertekstualiteit en ofdie boek eerder ’n poging is om sensasie te wek ten einde meer boeke te verkoop. Hierdie vraevorm die basis vir ’n intertekstuele verkenning van die twee tekste, wat neerkom op ’n stiplees van Conrad se teks langs Trencherman ten einde die intertekstuele skakels tussen die twee tekste te identifiseer. Teoreties is die artikel gebaseer op die werk van Kristeva en Barthes. Die ondersoek het bevestig dat Trencherman inderdaad ’n oefening in intertekstualiteit is, nie slegs as intertekstualiteit nie, maar eerder as ’n in-gesprek-tree met Conrad se meesterteks. Daaruit volg die slotsom dat Trencherman ’n geldige intertekstuele antwoord is op Heart of darkness wat Conrad se beroemde novelle dekonstrueer en die draaiboek daarvan transponeer na ’n distopiese, post-demokratiese Suid-Afrika.

  7. Formation of a Colloidal CdSe and ZnSe Quantum Dots via a Gamma Radiolytic Technique

    Directory of Open Access Journals (Sweden)

    Aeshah Salem

    2016-09-01

    Full Text Available Colloidal cadmium selenide (CdSe and zinc selenide (ZnSe quantum dots with a hexagonal structure were synthesized by irradiating an aqueous solution containing metal precursors, poly (vinyl pyrrolidone, isopropyl alcohol, and organic solvents with 1.25-MeV gamma rays at a dose of 120 kGy. The radiolytic processes occurring in water result in the nucleation of particles, which leads to the growth of the quantum dots. The physical properties of the CdSe and ZnSe nanoparticles were measured by various characterization techniques. X-ray diffraction (XRD was used to confirm the nanocrystalline structure, energy-dispersive X-ray spectroscopy (EDX was used to estimate the material composition of the samples, transmission electron microscopy (TEM was used to determine the morphologies and average particle size distribution, and UV-visible spectroscopy was used to measure the optical absorption spectra, from which the band gap of the CdSe and ZnSe nanoparticles could be deduced.

  8. Nonuniform Excitonic Charge Distribution Enhances Exciton-Phonon Coupling in ZnSe/CdSe Alloyed Quantum Dots.

    Science.gov (United States)

    Gong, Ke; Kelley, David F; Kelley, Anne Myers

    2017-02-02

    Zinc to cadmium cation exchange of ZnSe quantum dots has been used to produce a series of alloyed Zn1-xCdxSe quantum dots. As x increases and the lowest-energy exciton shifts to the red, the peak initially broadens and then sharpens as x approaches 1. Resonance Raman spectra obtained with excitation near the lowest excitonic absorption peak show a gradual shift of the longitudinal optical phonon peak from 251 cm(-1) in pure ZnSe to 210 cm(-1) in nearly pure CdSe with strong broadening at intermediate compositions. The LO overtone to fundamental intensity ratio, a rough gauge of exciton-phonon coupling strength, increases considerably for intermediate compositions compared with those of either pure ZnSe or pure CdSe. The results indicate that partial localization of the hole in locally Cd-rich regions of the alloyed particles increases the strengths of local internal electric fields, increasing the coupling between the exciton and polar optical phonons.

  9. Geochemistry of the Yutangba Se Deposit in Western Hubei, China

    Institute of Scientific and Technical Information of China (English)

    冯彩霞; 刘家军; 胡瑞忠; 刘燊

    2004-01-01

    The Yutangba Se deposit is a rare high-Se deposit in the world and it is well known for its high contents of Se, which reach 8590×10-6 . The ore-hosted rocks are dominated by cherts that have been well developed. Enrichment of selenium in Se-rich ores is obviously controlled by stratigraphic position and lithological character. The closer the rocks are to the Maokou Formation cherts, the more they contain selenium, but in case the stratigraphic horizons are close to one another, the enrichment of selenium would be controlled by lithological character. In the Se ores and abandoned stone coal pile at the Yutangba Se deposit there have been found large amounts of independent Se minerals, for instance, achavalite and a variety of forms of native selenium. Native selenium minerals present in the abandoned stone coal pile are the outcome of a combination of natural factors and anthropologic activities. For example, lime making will create a closed environment favoring the growth of native selenium, and the reduction of selenium will lead to its secondary enrichment. Starting with the study of ore-forming fluids. Systematic studies have been conducted on fluid inclusions separated from the main ore veins in the mining district for their homogenization temperatures, salinities and density, and the results show that fluid inclusions contained in ores from the Yutangba Se deposit are large in number and diverse in form, dominated by primary ones. The homogenization temperatures of two types of fluid inclusions are within the range of 173.2-247.5℃, individually up to 300℃ or even higher; the salinities of fluids in fluid inclusions in quartz and calcite are 5.9%-10.1% and 3.9%-4.5%, respectively; their densities vary from 0.79-0.93 g/cm3. Extensive discovery of Se minerals due to secondary enrichment of selenium in the stone coal provides important clues to the improvements on the metallurgical and recovery technologies for selenium in the black shale series of China

  10. Transition probabilities in neutron-rich Se,8684

    Science.gov (United States)

    Litzinger, J.; Blazhev, A.; Dewald, A.; Didierjean, F.; Duchêne, G.; Fransen, C.; Lozeva, R.; Sieja, K.; Verney, D.; de Angelis, G.; Bazzacco, D.; Birkenbach, B.; Bottoni, S.; Bracco, A.; Braunroth, T.; Cederwall, B.; Corradi, L.; Crespi, F. C. L.; Désesquelles, P.; Eberth, J.; Ellinger, E.; Farnea, E.; Fioretto, E.; Gernhäuser, R.; Goasduff, A.; Görgen, A.; Gottardo, A.; Grebosz, J.; Hackstein, M.; Hess, H.; Ibrahim, F.; Jolie, J.; Jungclaus, A.; Kolos, K.; Korten, W.; Leoni, S.; Lunardi, S.; Maj, A.; Menegazzo, R.; Mengoni, D.; Michelagnoli, C.; Mijatovic, T.; Million, B.; Möller, O.; Modamio, V.; Montagnoli, G.; Montanari, D.; Morales, A. I.; Napoli, D. R.; Niikura, M.; Pollarolo, G.; Pullia, A.; Quintana, B.; Recchia, F.; Reiter, P.; Rosso, D.; Sahin, E.; Salsac, M. D.; Scarlassara, F.; Söderström, P.-A.; Stefanini, A. M.; Stezowski, O.; Szilner, S.; Theisen, Ch.; Valiente Dobón, J. J.; Vandone, V.; Vogt, A.

    2015-12-01

    Reduced quadrupole transition probabilities for low-lying transitions in neutron-rich Se,8684 are investigated with a recoil distance Doppler shift (RDDS) experiment. The experiment was performed at the Istituto Nazionale di Fisica Nucleare (INFN) Laboratori Nazionali di Legnaro using the Cologne Plunger device for the RDDS technique and the AGATA Demonstrator array for the γ -ray detection coupled to the PRISMA magnetic spectrometer for an event-by-event particle identification. In 86Se the level lifetime of the yrast 21+ state and an upper limit for the lifetime of the 41+ state are determined for the first time. The results of 86Se are in agreement with previously reported predictions of large-scale shell-model calculations using Ni78-I and Ni78-II effective interactions. In addition, intrinsic shape parameters of lowest yrast states in 86Se are calculated. In semimagic 84Se level lifetimes of the yrast 41+ and 61+ states are determined for the first time. Large-scale shell-model calculations using effective interactions Ni78-II, JUN45, jj4b, and jj4pna are performed. The calculations describe B (E 2 ;21+→01+) and B (E 2 ;61+→41+) fairly well and point out problems in reproducing the experimental B (E 2 ;41+→21+) .

  11. Nanocrystalline Cr(2+)-doped ZnSe nanowires laser.

    Science.gov (United States)

    Feng, Guoying; Yang, Chao; Zhou, Shouhuan

    2013-01-09

    By using femtosecond laser pulses to ablate microsized targets that are dispersed in liquid media, nanocrystalline Cr(2+)-doped ZnSe nanowires have been successfully fabricated for the first time. The phase and stoichiometries of the original materials are preserved while the sizes are reduced down to 30-120 nm for these nanowires. X-ray diffraction results show that the products are nanocrystalline ZnSe with cubic sphalerite structure. Scanning electron microscope results indicate that the products be ZnSe nanowires. The nanowires are usually 30-120 nm in diameter and several tens of micrometers in length. Photoluminescence of the nanocrystalline Cr(2+)-doped ZnSe nanowires shows strong emission at around 2000-2500 nm under excitation of 1300-2250 nm wavelength at room temperature. By using the Cr(2+)-doped ZnSe multiple nanowires as the gain medium, mid-infrared oscillation at 2194 nm has been established. The oscillation wavelength of the multiple nanowires laser is 150 nm shifted to shorter wavelengths in comparison with that of microsized powder random laser.

  12. Thermoelectric properties of single-layered SnSe sheet.

    Science.gov (United States)

    Wang, Fancy Qian; Zhang, Shunhong; Yu, Jiabing; Wang, Qian

    2015-10-14

    Motivated by the recent study of inspiring thermoelectric properties in bulk SnSe [Zhao et al., Nature, 2014, 508, 373] and the experimental synthesis of SnSe sheets [Chen et al., J. Am. Chem. Soc., 2013, 135, 1213], we have carried out systematic calculations for a single-layered SnSe sheet focusing on its stability, electronic structure and thermoelectric properties by using density functional theory combined with Boltzmann transport theory. We have found that the sheet is dynamically and thermally stable with a band gap of 1.28 eV, and the figure of merit (ZT) reaches 3.27 (2.76) along the armchair (zigzag) direction with optimal n-type carrier concentration, which is enhanced nearly 7 times compared to its bulk counterpart at 700 K due to quantum confinement effect. Furthermore, we designed four types of thermoelectric couples by assembling single-layered SnSe sheets with different transport directions and doping types, and found that their efficiencies are all above 13%, which are higher than those of thermoelectric couples made of commercial bulk Bi2Te3 (7%-8%), suggesting the great potential of single-layered SnSe sheets for heat-electricity conversion.

  13. First-principles study of Se-intercalated graphite

    Energy Technology Data Exchange (ETDEWEB)

    BARTKOWIAK,M.; MODINE,NORMAND A.; SOFO,J.O.; MAHAN,G.D.

    2000-05-11

    Se-intercalated graphite compounds (Se-GICs) are considered as promising candidates for room-temperature thermoelectric cooling devices. Here the authors analyze the crystallographic structure and electronic properties of these materials within the framework of density-functional theory. First, the Adaptive-Coordinate Real-space Electronic Structure (ACRES) code is used to determine the stable structure of a representative stage-2 Se-GIC by relaxing atomic positions. The stable configuration is found to be a pendant-type structure, in which each selenium is bonded covalently to two atoms within the same carbon layer, causing a local distortion of the in-plane conjugation of the graphite. Then, they use the full potential linearized augmented plane wave (FP-LAPW) method to calculate the electronic band structure of the material and discuss its properties. Near the Fermi energy E{sub F}, there are wide bands originating from the host graphitic electronic structure and a few very narrow bands mainly of Se 4p character. The latter bands contribute to high peaks in the density of states close to E{sub F}. They show that this feature, although typical of many good thermoelectrics, does not necessarily imply high thermopower in the case of Se-GICs.

  14. Todo lo ilustrado se desvanece en los no lugares

    Directory of Open Access Journals (Sweden)

    Felipe Luis García

    2015-12-01

    Full Text Available A partir del proyecto de restauración del edificio de la Vieja Estación Terminal de la ciudad de Mar del Plata en el año 2009, se presentan múltiples tensiones en torno a cómo se pone en valor un patrimonio histórico y urbano-cultural de la comunidad. La operatoria que prevalece es la de las iniciativas privadas que marcan el rumbo de dicha refacción tendiente a la condensación de una lógica comercial salvaguardando vestigios culturales para dicho cometido. El siguiente informe se encarga de analizar información acerca del caso y conectarla del modo más integral posible con la portentosa amalgama conceptual que acarrea la tradición de la sociología cultural-urbana. Es decir, hilvanar un análisis exhaustivo partiendo de la proliferación de los no lugares como espacios de hiperrealidad en los que se interpele al ciudadano en tanto consumidor; dando por sentado en esta expansión de shoppings, la concepción de ciudad que por detrás se esconde.

  15. Self-Assembled PbSe Nanowire:Perovskite Hybrids.

    Science.gov (United States)

    Yang, Zhenyu; Yassitepe, Emre; Voznyy, Oleksandr; Janmohamed, Alyf; Lan, Xinzheng; Levina, Larissa; Comin, Riccardo; Sargent, Edward H

    2015-12-02

    Inorganic semiconductor nanowires are of interest in nano- and microscale photonic and electronic applications. Here we report the formation of PbSe nanowires based on directional quantum dot alignment and fusion regulated by hybrid organic-inorganic perovskite surface ligands. All material synthesis is carried out at mild temperatures. Passivation of PbSe quantum dots was achieved via a new perovskite ligand exchange. Subsequent in situ ammonium/amine substitution by butylamine enables quantum dots to be capped by butylammonium lead iodide, and this further drives the formation of a PbSe nanowire superlattice in a two-dimensional (2D) perovskite matrix. The average spacing between two adjacent nanowires agrees well with the thickness of single atomic layer of 2D perovskite, consistent with the formation of a new self-assembled semiconductor nanowire:perovskite heterocrystal hybrid.

  16. A Quaternary ZnCdSeTe Nanotip Photodetector

    Directory of Open Access Journals (Sweden)

    Cheng YC

    2009-01-01

    Full Text Available Abstract The authors report the growth of needle-like high density quaternary Zn0.87Cd0.13Se0.98Te0.02nanotips on oxidized Si(100 substrate. It was found that average length and average diameter of the nanotips were 1.3 μm and 91 nm, respectively. It was also found that the as-grown ZnCdSeTe nanotips exhibit mixture of cubic zinc-blende and hexagonal wurtzite structures. Furthermore, it was found that the operation speeds of the fabricated ZnCdSeTe nanotip photodetector were fast with turn-on and turn-off time constants both less than 2 s.

  17. Collectivity at N=50: 82Ge and 84Se

    CERN Document Server

    Gade, A; Bazin, D; Brown, B A; Campbell, C M; Glasmacher, T; Grinyer, G F; Honma, M; McDaniel, S; Meharchand, R; Otsuka, T; Ratkiewicz, A; Tostevin, J A; Walsh, K A; Weisshaar, D

    2010-01-01

    The neutron-rich N=50 isotones 82Ge and 84Se were investigated using intermediate-energy Coulomb excitation on a 197Au target and inelastic scattering on 9Be. As typical for intermediate-energy Coulomb excitation with projectile energies exceeding 70 MeV/nucleon, only the first 2^+ states were excited in 82Ge and 84Se. However, in the inelastic scattering on a 9Be target, a strong population of the first 4^+ state was observed for 84Se, while there is no indication of a similarly strong excitation of the corresponding state in the neighboring even-even isotone 82Ge. The results are discussed in the framework of systematics and shell-model calculations using three different effective interactions.

  18. Data-driven initialization of SParSE

    Science.gov (United States)

    Roh, Min K.; Proctor, Joshua L.

    2017-07-01

    Despite the ever-increasing affordability and availability of high performance computing platforms, computational analysis of stochastic biochemical systems remains an open problem. A recently developed event-based parameter estimation method, the stochastic parameter search for events (SParSE), is able to efficiently sample reaction rate parameter values that confer a user-specified target event with a given probability and error tolerance. Despite the substantial computational savings, the efficiency of SParSE can be further improved by intelligently generating new initial parameter sets based on previously computed trajectories. In this article, we propose a principled method which combines the efficiencies of SParSE with these geometric machine-learning methods to generate new initial parameters based on the previously collected data.

  19. Electrical conduction mechanism in GeSeSb chalcogenide glasses

    Indian Academy of Sciences (India)

    Vandana Kumari; Anusaiya Kaswan; D Patidar; Kananbala Sharma; N S Saxena

    2016-02-01

    Electrical conductivity of chalcogenide glassy system Ge$_{30−x}$Se$_{70}$Sb$_{x}$ ( = 10, 15, 20 and 25) prepared by melt quenching has been determined at different temperatures in bulk through the $I$–$V$ characteristic curves. It is quite evident from results that Poole–Frenkel conduction mechanisms hold good for conduction in these glasses in a given temperature range. The variation in electrical conductivity with composition was attributed to the Se–Sb bond concentration in the Se–Ge–Sb system. Results indicated that Ge$_5$Se$_{70}$Sb$_{25}$ showed the minimum resistance. In view of this the composition Ge$_5$Se$_{70}$Sb$_{25}$ may be coined as ‘critical composition’ in the proposed series. Also the activation energies of conduction of these glassy alloys have been calculated in higher and lower temperature range using the Arrhenius equation.

  20. Optical properties of ZnSe(Te) with ytterbium impurity.

    Science.gov (United States)

    Makhniy, Viktor P; Horley, Paul P; Vorobiev, Yuri V; Kinzerska, Oksana V

    2016-04-20

    We report the results on infrared transmission measurements of non-doped and tellurium-doped crystals of zinc selenide grown from the melt. It was found that non-doped samples feature high transmission (50%-60%) for the wavelengths of 1-22 μm. The efficient scintillating crystals of ZnSe(Te) are almost opaque for λ>7  μm. Doping these samples with ytterbium from the gas phase does not achieve any significant transmission increase for non-doped ZnSe samples in the spectral range of 1-22 μm. However, it considerably increases (up to 50%) transmission for doped ZnSe(Te) at the wavelengths λ>10  μm. These optical peculiarities were analyzed taking into account restructurization of point defect ensembles created by Te and Yb impurities.

  1. Linear polarization sensitivity of SeGA detectors

    CERN Document Server

    Miller, D; Moeller, V; Starosta, K; Vaman, C; Weisshaar, D

    2006-01-01

    Parity is a key observable in nuclear spectroscopy. Linear polarization measurements of $\\gamma$-rays are a probe to access the parities of energy levels. Utilizing the segmentation of detectors in the Segmented Germanium Array (SeGA) at the NSCL and analyzing the positions of interaction therein allows the detectors to be used as Compton polarimeters. Unlike other segmented detectors, SeGA detectors are irradiated from the side to utilize the transversal segmentation for better Doppler corrections. Sensitivity in such an orientation has previously been untested. A linear polarization sensitivity $Q \\approx 0.14$ has been measured in the 350-keV energy range for SeGA detectors using $\\alpha$-$\\gamma$ correlations from a \

  2. Teoria feminista: o desafio de tornar-se um paradigma

    Directory of Open Access Journals (Sweden)

    Mirian Santos Paiva

    1997-12-01

    Full Text Available Partindo da crise do paradigma tradicional e tendo como epicentro a crítica feminista, este trabalho tenta mostrar o desafio que enfrenta a teoria feminista para tornar-se um novo paradigma e para tanto realiza-se uma pesquisa bibliográfica, consubstanciada na literatura pertinente ao tema. Evidencia-se que o desafio de ser um paradigma em ascensão faz com que esta teoria enfrente problemas teóricos, conceituais e metodológicos que precisam de um esforço conjunto para serem aprofundados e resolvidos. Todavia, o desenvolvimento desta teoria não depende apenas do mundo acadêmico, mas está também atrelado a mudanças na estrutura social, pois, de uma sociedade mais igualitária, mais facilmente emergirá um conhecimento sem dominação de gênero.

  3. Linkages between Icelandic Low position and SE Greenland winter precipitation

    Science.gov (United States)

    Berdahl, M.; Rennermalm, A. K.; Hammann, A. C.; Mioduszewski, J.; Hameed, S.; Tedesco, M.; Stroeve, J. C.; Mote, T. L.

    2015-12-01

    Greenland's largest flux of precipitation occurs in its Southeast (SE) region. An understanding of the mechanisms controlling precipitation in this region is lacking despite its disproportionate importance in the mass balance of Greenland and the consequent contributions to sea level rise. We use weather station data from the Danish Meteorological Institute to reveal the governing influences on precipitation in SE Greenland during the winter and fall. We find that precipitation in the fall is significantly correlated to the longitude of the Icelandic Low and the NAO. Winter precipitation is correlated with the strength and longitude of the Icelandic Low, as well as the NAO. We show that in years of extreme high precipitation, onshore winds dominate, thereby advecting more moisture inland. In low precipitation years, winds are more westerly, approaching the stations from land. Understanding the controls of SE Greenland precipitation will help us predict how future precipitation in this key region may change in a warming climate.

  4. Optical properties of nanostructured InSe thin films

    Science.gov (United States)

    El-Nahass, M. M.; Saleh, Abdul-Basit A.; Darwish, A. A. A.; Bahlol, M. H.

    2012-03-01

    Thin films of InSe were prepared by thermal evaporation technique. The as-deposited films have nano-scale crystalline nature and the annealing enhanced the degree of crystallinity. The optical properties of nanocrystalline thin films of InSe were studied using spectrophotometric measurements of transmittance, T, and reflectance, R, at normal incidence of light in the wavelength range 200-2500 nm. The optical constants (refractive index, n, and absorption index, k) were calculated using a computer program based on Murmann's exact equations. The calculated optical constants are independent of the film thickness. The optical dispersion parameters have been analysed by single oscillator model. The type of transition in InSe films is indirect allowed with a value of energy gap equals to 1.10 eV, which increased to 1.23 eV upon annealing.

  5. As Pontes de Coimbra que se Afogaram no Rio

    OpenAIRE

    Encarnação, José d'

    2013-01-01

    Recensão crítica à obra de Jorge de Alarcão, com ilustrações de José Luís Madeira, intitulada «As Pontes de Coimbra que se Afogaram no Rio», editada, em 2012, pela Ordem dos Engenheiros (Região Centro), Coimbra, com o ISBN: 978-989-8152-08-4. Resume-se e comenta-se o interesse documental e histórico do estudo feito por Jorge de Alarcão acerca das pontes que atravessavam o Mondego junto à cidade de Coimbra e de que hoje apenas restam vestígios, que o autor miudamente analisa.

  6. Surface Morphology of Undoped and Doped ZnSe Films

    Science.gov (United States)

    George, T.; Hayes, M.; Chen, H.; Chattopadhyay, K.; Thomas E.; Morgan, S.; Burger, A.

    1998-01-01

    Rare-earth doped ions in polar II-VI semiconductors have recently played an important role in the optical properties of materials and devices. In this study, undoped ZnSe and erbium doped ZnSe films were grown by radio frequency (RF) magnetron sputtering method. Atomic Force Microscopy (AFM) was used together with optical microscopy and UV-Vis spectroscopy to characterize the films. Doped samples were found to have higher surface roughness and quite different surface morphology compared to that of undoped samples. The grown films generally show a relatively smooth and uniform surface indicating that they are of overall good quality. The impact of plasma etching on ZnSe:Er film examined under AFM is also discussed.

  7. Electrical properties of a-GeSe100-

    Indian Academy of Sciences (India)

    Abdolali Zolanvari; Navdeep Goyal; S K Tripathi

    2004-09-01

    In general, the conductivity in chalcogenide glasses at higher tempratures is dominated by band conduction (DC conduction). But, at lower tempratures, hoping conduction dominates over band conduction. A study at lower temprature can, eventually, provide useful information about the conduction mechanism and the defect states in the material. Therefore, the study of electrical properties of GeSe100- in the lower temperature region (room temperature) is interesting. Temperature and frequency dependence of GeSe100- ( = 15, 20 and 25) have been studied over different range of temperatures and frequencies. Am agreement between experimental and theoretical results suggested that the behaviour of germanium selenium system (GeSe100-) have been successfully explained by correlated barrier hopping (CBH) model.

  8. Self-Assembled PbSe Nanowire:Perovskite Hybrids

    KAUST Repository

    Yang, Zhenyu

    2015-12-02

    © 2015 American Chemical Society. Inorganic semiconductor nanowires are of interest in nano- and microscale photonic and electronic applications. Here we report the formation of PbSe nanowires based on directional quantum dot alignment and fusion regulated by hybrid organic-inorganic perovskite surface ligands. All material synthesis is carried out at mild temperatures. Passivation of PbSe quantum dots was achieved via a new perovskite ligand exchange. Subsequent in situ ammonium/amine substitution by butylamine enables quantum dots to be capped by butylammonium lead iodide, and this further drives the formation of a PbSe nanowire superlattice in a two-dimensional (2D) perovskite matrix. The average spacing between two adjacent nanowires agrees well with the thickness of single atomic layer of 2D perovskite, consistent with the formation of a new self-assembled semiconductor nanowire:perovskite heterocrystal hybrid.

  9. Señales y sistemas de tiempo discreto

    OpenAIRE

    2003-01-01

    El presente texto persigue un enfoque unificado de las herramientas básicas del Procesado Digital considerando su uso en aplicaciones tanto de Comunicaciones como de Control, abundando en ejemplos. Se ha procurado que, sin obviar los necesarios formalismos en una disciplina de este tipo, no tome un enfoque solamente orientado a la presentación de teoremas, propiedades y demostraciones. Para ello se van conectando a lo largo del libro los aspectos matemáticos con subsistemas electrónicos que ...

  10. On the symmetry of phosphorous doped ZnSe

    Indian Academy of Sciences (India)

    N Sankar; K Ramachandran

    2002-08-01

    The site symmetry of P doped ZnSe is analysed in detail here, as the recent experiments suggest two possible symmetries $T_d$ and $C_{3V}$. The reduction to $C_{3V}$ is attributed to the presence of natural impurity, Ga. Our calculations based on molecular model and Green’s functions suggest that the symmetry $C_{3V}$ is possible with ZnSe : P when Jahn Teller distortion of about ∼ 0.2 Å (towards one of Zn atom) is assumed. This has been supported by other experiments.

  11. Dentalmaterialer kan udløse orale allergiske reaktioner

    DEFF Research Database (Denmark)

    Røn Larsen, Kristine; Johansen, Jeanne Duus; Arenholt-Bindslev, Dorthe

    2013-01-01

    Mange af de materialer, der anvendes i forbindelse med diagnostik, profylakse og behandling af sygdomme i mundhulen (her betegnet dentalmaterialer), kan udløse akutte eller kroniske reaktioner, herunder egentlige allergiske reaktioner. I klinikken kan det være vanskeligt at skelne mundslimhindefo......Mange af de materialer, der anvendes i forbindelse med diagnostik, profylakse og behandling af sygdomme i mundhulen (her betegnet dentalmaterialer), kan udløse akutte eller kroniske reaktioner, herunder egentlige allergiske reaktioner. I klinikken kan det være vanskeligt at skelne...

  12. SE VINTE ANOS NÃO É NADA

    Directory of Open Access Journals (Sweden)

    Roberto Polanco - Carrasco

    2011-07-01

    Full Text Available Complexa tarefa a de escrever um editorial. Ainda mais quando se trata do editorial dos cinco anos de Cuadernos de Neuropsicología (CNPs.Não saberia dizer porque este quinto ano de CNPs deve ter um tom diferente dos anteriores. O certo é que um lustro não é um período de tempo banal, um lustro se celebra. Os romanos a cada cinco anos realizavam uma cerimônia pública de purificação geral através de um sacrifício: um lustrum,que quer dizer puro. De aí que lustro signifique quinquenio e lustrar limpar…Como os romanos então, festejamos este quinquenio, e como não! Se de variadas tentativas editoriais na psicologia chilena, são escassas aquelas revistas que superam os primeiro cinco anos de publicação, mas este será um tema para outro editorial.O nascimento de CNPs se produziu à margen de qualquer instituição, e isso definiu seu espirito e seu campo de ação. Durante anos a tarefa se desenvolveu independente da norma da academia e da sua servidão, o que não significa que quem escreve nesta revista comparta a mesmavisão ou distancia do âmbito académico e profissional. Sou responsável da visão (míope talvez que implica manter uma publicação deste nível a margen das pressões clássicas do competitivo mundo académico atual, o qual em ocasiões se esquece que se editamos é para ser lidos, e que essa leitura busca ser uma contribuição, uma voz que se soma a um coro de vozes diferentes (e não cacofônicas, que são o pilar do desenvolvimento de qualquer disciplina.Tudo o que pudesse

  13. El hombre como señor del tiempo

    OpenAIRE

    Haya, F. (Fernando)

    2008-01-01

    La denominación del ser personal como señor del tiempo significa que la esencia de la persona humana aparece en condición de anteposición esenáal con relación al tiempo. De acuerdo con ella, el ser humano dispone del tiempo en articulación presencial, la cual depende de la distinción real antropológica de esencia y ser. Se incluye el examen metafísico de los valores puros del antes y el después, e intentan resolverse las dificultades en orden al pensar puro del tiempo.

  14. Transcriptor de Lenguaje de Señas a Texto

    OpenAIRE

    Escalante Crespo, Perla Artemisa

    2006-01-01

    Este proyecto tiene como nombre "Transcriptor de Lenguaje de Señas a Texto" y tiene una orientación al procesamiento digital de imágenes. Nótese la aclaración de ser un transcriptor en lugar de traductor, el término es bien empleado, ya que traductor se aplica al significado de las palabras de un idioma a otro, y este proyecto es un transcriptor del lenguaje español signado a español, de ahí la diferencia. La acción de este proyecto viene implícita en su nombre, preci...

  15. Far-Infrared Absorption of PbSe Nanorods

    KAUST Repository

    Hyun, Byung-Ryool

    2011-07-13

    Measurements of the far-infrared absorption spectra of PbSe nanocrystals and nanorods are presented. As the aspect ratio of the nanorods increases, the Fröhlich sphere resonance splits into two peaks. We analyze this splitting with a classical electrostatic model, which is based on the dielectric function of bulk PbSe but without any free-carrier contribution. Good agreement between the measured and calculated spectra indicates that resonances in the local field factors underlie the measured spectra. © 2011 American Chemical Society.

  16. ¿Se debe criminalizar el consumo de drogas ilegales?

    OpenAIRE

    Nelson E. Alvarez Licona

    2010-01-01

    La política prohibicionista del consumo de las llamadas drogas ilegales, entre las que encontramos la mariguana, es consecuencia de la lucha por el control del mercado del opio que se da entre las grandes metrópolis europeas a mediados del siglo xix en Asia. La participación de Estados Unidos a principios del siglo xx, impulsada por las ideas puritanas, origina la política de lucha contra las drogas. Es en este contexto que el consumo de las drogas llamadas ilegales se criminaliza y su prácti...

  17. Varmetransport i evakuerede porøse materialer

    DEFF Research Database (Denmark)

    Schultz, Jørgen Munthe

    Indlægget omhandlede varmetransport i porøse materialer (ledning, konvektion og stråling) under atmosfæretryk og under vacuum. Specielt omhandlede præsentationen også silica aerogel som et eksempel på et højporøst isoleringsmateriale.......Indlægget omhandlede varmetransport i porøse materialer (ledning, konvektion og stråling) under atmosfæretryk og under vacuum. Specielt omhandlede præsentationen også silica aerogel som et eksempel på et højporøst isoleringsmateriale....

  18. Siglo XXI ¿Cómo se perfila la endodoncia?

    OpenAIRE

    Canalda Sahli, Carlos

    2000-01-01

    En los últimos 15 años del siglo XX la Endodoncia ha experimentado numerosos avances, de modo cada vez más acelerado, tanto en los conocimientos de la etiopatogenia y el diagnóstico de la enfermedad pulpar y periapical como en los aspectos clínicos y reparativos tras el tratamiento. A partir de los datos actuales se puede intuir hacia dónde puede encaminarse la Endodoncia. Se analizan aspectos de las ciencias básicas aplicadas a ella, el diagnóstico clínico, la preparación de los condµctos ra...

  19. “Mastitis” => Se solicita ayuda o consejo

    Directory of Open Access Journals (Sweden)

    Veterinaria.org

    2010-04-01

    Full Text Available ResumenPara nada la foto que se muestra se corresponde con una Mastitis felina, sino con una muy típica mastopatía, aunque no frecuente cuya denominación más común es Hiperplasia mamaria fibroadenomatosa o fibroepitelial, hipertrofia mamaria, hipertrofia mamaria fibroglandular (no adecuado ya que el común denominador es el estado súper proliferativo y no hipertrófico. Esa hiperplasia está dada por tejido mamario especialmente ductal con el agregado masivo de fibroblastos.

  20. Piezo-phototronic effect of CdSe nanowires.

    Science.gov (United States)

    Dong, Lin; Niu, Simiao; Pan, Caofeng; Yu, Ruomeng; Zhang, Yan; Wang, Zhong Lin

    2012-10-23

    The piezo-phototronic effect on transport properties of flexible CdSe NW devices is investigated. An optimum sensitivity of the flexible CdSe NW devices can be achieved by adjusting the applied strain and illumination intensity. The piezo-phototronic effect under compressive strain increases the internal electric field of the Schottky barrier, and assists the separation of the photo-excited electron-hole pairs, resulting in the increase of photocurrent. A trap-mediated mechanism is responsible for the decreased hole separation when the strain is larger than the critical strain.

  1. [{Cp2(tBuSe)Nb}2E] (E = O and Se) with bridging oxide or selenide ligands.

    Science.gov (United States)

    Hector, Andrew L; Jura, Marek; Levason, William; Reid, Gillian; Reid, Stuart D; Webster, Michael

    2008-10-01

    The title compounds, mu-oxido-bis[(tert-butylselenolato)bis(eta(5)-cyclopentadienyl)niobium(IV)] toluene solvate, [Nb(2)(C(5)H(5))(4)(C(4)H(9)Se)(2)O] x C(7)H(8), and mu-selenido-bis[(tert-butylselenolato)bis(eta(5)-cyclopentadienyl)niobium(IV)], [Nb(2)(C(5)H(5))(4)(C(4)H(9)Se)(2)Se], consist of niobium(IV) centres each bonded to two eta(5)-coordinated cyclopentadienyl groups and one tert-butylselenolate ligand and are the first organometallic niobium selenolates to be structurally characterized. A bridging oxide or selenide completes the niobium coordination spheres of the discrete dinuclear molecules. In the oxide, the O atom lies on an inversion centre, resulting in a linear Nb-O-Nb linkage, whereas the selenide has a bent bridging group [Nb-Se-Nb = 139.76 (2) degrees]. The difference is attributable to strong pi bonding in the oxide case, although the effects on the Nb-C and Nb-Se(t)Bu bond lengths are small.

  2. Exotic topological insulator states and topological phase transitions in Sb2Se3-Bi2Se3 heterostructures

    KAUST Repository

    Zhang, Qianfan

    2012-03-27

    Topological insulator is a new state of matter attracting tremendous interest due to its gapless linear dispersion and spin momentum locking topological states located near the surface. Heterostructures, which have traditionally been powerful in controlling the electronic properties of semiconductor devices, are interesting for topological insulators. Here, we studied the spatial distribution of the topological state in Sb 2Se 3-Bi 2Se 3 heterostructures by first-principle simulation and discovered that an exotic topological state exists. Surprisingly, the state migrates from the nontrivial Bi 2Se 3 into the trivial Sb 2Se 3 region and spreads across the entire Sb 2Se 3 slab, extending beyond the concept of "surface" state while preserving all of the topological surface state characteristics. This unusual topological state arises from the coupling between different materials and the modification of electronic structure near Fermi energy. Our study demonstrates that heterostructures can open up opportunities for controlling the real-space distribution of the topological state and inducing quantum phase transitions between topologically trivial and nontrivial states. © 2012 American Chemical Society.

  3. Formation and properties of epitaxial CdSe, ZnSe quantum dots. Conventional molecular beam epitaxy and related techniques

    Energy Technology Data Exchange (ETDEWEB)

    Mahapatra, Suddhasatta

    2008-01-16

    This thesis systematically investigates three such alternative approaches, along with conventional MBE, with emphasis on the formation-mechanism of QDs, and optimization of their morphological and optical attributes. it is shown here that no distinct 3D islands are formed in MBE growth of CdSe on ZnSe. While CdSe heteroepitaxy occurs in the multilayer-mode at T{sub G}=300 C, a reentrant recovery of the layer-by-layer mode is reported in this thesis, for growth at T{sub G}<{proportional_to}240 C. In the second variant technique, formation of large and distinct islands is demonstrated by deposition of amorphous selenium (a-Se) onto a 2D CdSe epilayer at room temperature and its subsequent desorption at a higher temperature (T{sub D}=230 C). The process steps of the third variant technique, developed in course of this work, are very similar to those of the previous one-the only alteration being the substitution of selenium with tellurium as the cap-forming-material. (orig.)

  4. Linear and NLO spectroscopy of GaSe and InSe nanoparticles formed via laser ablation

    Science.gov (United States)

    Pashayev, A.; Tunaboylu, B.; Allahverdiyev, K.; Salayev, E.; Tagiyev, B.

    2015-12-01

    Nanoparticles of layered GaSe, InSe were fabricated by laser ablation (LA) method (KrF laser, λ = 248 nm, 50 Hz, maximum energy 200 mJ, τ = 4 ns) and characterized by: •XRF •GDOES •SEM and TEM; •UV-, VIS-, and IRabsorption; •Raman and PL spectroscopy (also in confocal geometry). Results are discussed in relation to the particle size. Absorption spectra of particles with diameter 20 nm and less turned out to be blue shifted and is consisted with a weak confinement effect on Wannier-Mott type excitons. It is shown, that with decreasing the particle size the energy position of the low-frequency Raman active phonons in both compounds are shifted to lower frequencies (21 and 18 cm-1 in bulk GaSe and InSe and 8 and 7 cm-1 in particles with sizes 5 and 7 nm, respectively). From the low frequency Raman data, decrease of the force constants ca. 25 % (for GaSe) due to the formation of the nanoparticles are estimated, and the origin is suggested. Second harmonic generation (SHG) with 1064 nm line of a mode locked Nd : YAG laser was observed for nanoparticles ablated on different substrates. Potential for using these structures for laser light visualizators are discussed.

  5. S/Se In Sulfide Inclusion In Diamond

    Science.gov (United States)

    Thomassot, E.; Couffignal, F.; Lorand, J.; Bureau, H.; Cartigny, P.; Harris, J. W.

    2009-05-01

    Sulfides are among the most common minerals found as inclusions in diamonds. Being protected from any alteration after diamond formation, they likely represent the most pristine sulfide sample of mantle rocks. Their chemical composition in major and minor elements (mainly Ni, Cu and Cr), as determined using Electron Probe Micro Analyse (EPMA), is commonly used to determine the rock type in which the diamond formed. Here we propose to apply the same technique to the trace element abundance determination. We performed selenium (Se) on sulfide inclusion in diamonds. The S/Se value could help understanding whether the diamond formed in an eclogitic or peridotitic environment and may also constrain on the magmatic differentiation of diamonds host rock as well as provide a potential surface (hydrothermal) signature in diamond inclusions. A trace element measurement scheme has been developed by EPMA at the CAMPARIS centre (Paris). Se-abundance was obtained using a 30 kV accelerating voltage and 100nA probe current. Total counting time was 800s for peak (1.1 Å ) and 400s for background on both side of peak. Analyses were duplicated by μPIXE using the LPS nuclear microprobe facility (SIS2M CEA Saclay, France). Maps from 30x30 μm2 to 70x70 μm2 were obtained by scanning a 4x4 μm2 proton beam of 3MeV, 600 pA, (0.4 to 2 μC). The two techniques show good agreement and we conclude that EPMA is well suited for accurate and precise Se measurements. We analysed five samples; two monosulfide solid solution (MSS) (Ni>22wt%) typical of the peridotitic paragenesis (P-type), and three Ni-poor sulfides (Ni<7wt%) typical of the eclogitic paragenesis (E-type). In P-type sulfides, Se-content (260 ppm) is significantly higher than previously reported in sulfides from mantle-derived lherzolites (40-160 ppm), pyroxenites (25-45 ppm) or harzburgite. The value of S/Se in MSS is low (˜1400) compared to those of the primitive mantle reservoir (3,300; McDounough et al., 1995 Chemical Geology

  6. Surface half-metallicity of half-Heusler compound FeCrSe and interface half-metallicity of FeCrSe/GaP

    Science.gov (United States)

    Khalaf Al-zyadi, Jabbar M.; Jolan, Mudhahir H.; Yao, Kai-Lun

    2016-04-01

    Recent studies showed that half-Heusler FeCrSe exhibits half-metallic ferromagnetism (Huang et al. [20]). In this paper, we investigate extensively the electronic, magnetic, and half-metallic properties of the half-Heusler alloy FeCrSe (111) and (001) surfaces and the interface with GaP (111) substrate by using the first-principles calculations within the density functional theory. The atomic density of states demonstrates that the half-me tallicity verified in the bulk FeCrSe is maintained at the CrSe-terminated (001) and Se-terminated (111) surfaces, but lost at both Cr- and Fe-terminated (111) surfaces and the Fe-terminated (001) surface. Alternatively, for the interface of FeCrSe/GaP (111), the bulk half-metallicity is destroyed at Se-P configuration while Se-Ga interface and subinterface show nearly 100% spin polarization. Moreover, the calculated interfacial adhesion energies exhibit that Se-Ga shape is more stable than the Se-P one. The calculated magnetic moments of Se, Ga at the Se-Ga (111) interface and P at the Se-P (111) interface increase with respect to the corresponding bulk values while the atomic magnetic moment of Se atom at the Se-P (111) interface decreases. We also notice that the magnetic moments of subinterface Fe at both Se-Ga and Se-P (111) interfaces decrease compared to the bulk values.

  7. Investigation of CuGaSe2/CuInSe2 double heterojunction interfaces grown by molecular beam epitaxy

    Directory of Open Access Journals (Sweden)

    Sathiabama Thiru

    2015-02-01

    Full Text Available In-situ reflection high-energy electron diffraction (RHEED observation and X-ray diffraction measurements were performed on heterojunction interfaces of CuGaSe2/CnInSe2/CuGaSe2 grown on GaAs (001 using migration-enhanced epitaxy. The streaky RHEED pattern and persistent RHEED intensity oscillations caused by the alternate deposition of migration-enhanced epitaxy sequence are observed and the growths of smooth surfaces are confirmed. RHEED observation results also confirmed constituent material interdiffusion at the heterointerface. Cross-sectional transmission electron microscopy showed a flat and abrupt heterointerface when the substrate temperature is as low as 400 °C. These have been confirmed even by X-ray diffraction and photoluminescence measurements.

  8. Preparation of clean surfaces and Se vacancy formation in Bi2Se3 by ion bombardment and annealing

    Science.gov (United States)

    Zhou, Weimin; Zhu, Haoshan; Valles, Connie M.; Yarmoff, Jory A.

    2017-08-01

    Bismuth Selenide (Bi2Se3) is a topological insulator (TI) with a structure consisting of stacked quintuple layers. Single crystal surfaces are commonly prepared by mechanical cleaving. This work explores the use of low energy Ar+ ion bombardment and annealing (IBA) as an alternative method to produce reproducible and stable Bi2Se3 surfaces under ultra-high vacuum (UHV). It is found that a clean and well-ordered surface can be prepared by a single cycle of 1 keV Ar+ ion bombardment and 30 min of annealing. Low energy electron diffraction (LEED) and detailed low energy ion scattering (LEIS) measurements show no differences between IBA-prepared surfaces and those prepared by in situ cleaving in UHV. Analysis of the LEED patterns shows that the optimal annealing temperature is 450 °C. Angular LEIS scans reveal the formation of surface Se vacancies when the annealing temperature exceeds 520 °C.

  9. Zinc diffusion in polycrystalline Cu(In,Ga)Se2 and single-crystal CuInSe2 layers

    Science.gov (United States)

    Bastek, J.; Stolwijk, N. A.; Wuerz, R.; Eicke, A.; Albert, J.; Sadewasser, S.

    2012-08-01

    The diffusion behavior of Zn in solar-grade Cu(In,Ga)Se2 (CIGSe) is found to be similar to that in epitaxial CuInSe2 (CISe), which indicates that grain boundaries only play a minor role as segregation sites and fast-transport pathways. The diffusivity obeys the Arrhenius equation DZn = 3.8 × 10-3exp(-1.24 eV/kBT) cm2 s-1. Surprisingly, the Zn65 diffusion profiles obtained by the radiotracer technique exhibit anomalous shapes with a second maximum near the CI(G)Se-substrate interface. The observations may be indicative of an interstitial-substitutional diffusion mechanism.

  10. Crossover from 3D to 2D quantum transport in Bi2Se3/In2Se3 superlattices.

    Science.gov (United States)

    Zhao, Yanfei; Liu, Haiwen; Guo, Xin; Jiang, Ying; Sun, Yi; Wang, Huichao; Wang, Yong; Li, Han-Dong; Xie, Mao-Hai; Xie, Xin-Cheng; Wang, Jian

    2014-09-10

    The topological insulator/normal insulator (TI/NI) superlattices (SLs) with multiple Dirac channels are predicted to offer great opportunity to design novel materials and investigate new quantum phenomena. Here, we report first transport studies on the SLs composed of TI Bi2Se3 layers sandwiched by NI In2Se3 layers artificially grown by molecular beam epitaxy (MBE). The transport properties of two kinds of SL samples show convincing evidence that the transport dimensionality changes from three-dimensional (3D) to two-dimensional (2D) when decreasing the thickness of building block Bi2Se3 layers, corresponding to the crossover from coherent TI transport to separated TI channels. Our findings provide the possibility to realizing "3D surface states" in TI/NI SLs.

  11. Multifunctional "Se": Course of Development in Spanish Children.

    Science.gov (United States)

    Gathercole, Virginia C.

    A study explored the acquisition of "se" by Spanish-speaking children in Madrid, Spain, looking at: (1) acquisition of multifunctional forms; and (2) the course of acquisition for a linguistic expression that has both anaphoric and non-anaphoric functions, and its relevance to Binding Theory approaches to the acquisition of reflexives.…

  12. Social Set Visualizer (SoSeVi) II

    DEFF Research Database (Denmark)

    Flesch, Benjamin; Vatrapu, Ravi

    2016-01-01

    This paper reports the second iteration of the Social Set Visualizer (SoSeVi), a set theoretical visual analytics dashboard of big social data. In order to further demonstrate its usefulness in large-scale visual analytics tasks of individual and collective behavior of actors in social networks...

  13. Sample (S): SE59_S01 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE59_S01 Arabidopsis Arabidopsis thaliana NCBI taxonomy:3702 Arabidopsis (Col-0) pl...ants were used in this study. All plates were placed in a growth chamber at 22 °C with a relative humidity o

  14. Thermoelectric properties of SnSe2 monolayer

    Science.gov (United States)

    Li, Guanpeng; Ding, Guangqian; Gao, Guoying

    2017-01-01

    The 2H (MoS2-type) phase of 2D transition metal dichalcogenides (TMDCs) has been extensively studied and exhibits excellent electronic and optoelectronic properties, but the high phonon thermal conductivity is detrimental to the thermoelectric performances. Here, we use first-principles methods combined with Boltzmann transport theory to calculate the electronic and phononic transport properties of 1T (CdI2-type) SnSe2 monolayer, a recently realized 2D metal dichalcogenide semiconductor. The calculated band gap is 0.85 eV, which is a little larger than the bulk value. Lower phonon thermal conductivity and higher power factor are obtained in 1T-SnSe2 monolayer compared to 2H-TMDCs monolayers. The low phonon thermal conductivity (3.27 W mK-1 at room temperature) is mainly due to the low phonon frequency of acoustic modes and the coupling of acoustic modes with optical modes. We also find that the p-type has better thermoelectric performance than the n-type, and the figure of merit within p-type can reach 0.94 at 600 K for 1T-SnSe2 monolayer, which is higher than those of most 2H-TMDCs monolayers, making 1T-SnSe2 monolayer a promising candidate for thermoelectric applications.

  15. Dentalmaterialer kan udløse orale allergiske reaktioner

    DEFF Research Database (Denmark)

    Røn Larsen, Kristine; Johansen, Jeanne Duus; Arenholt-Bindslev, Dorthe;

    2013-01-01

    Mange af de materialer, der anvendes i forbindelse med diagnostik, profylakse og behandling af sygdomme i mundhulen (her betegnet dentalmaterialer), kan udløse akutte eller kroniske reaktioner, herunder egentlige allergiske reaktioner. I klinikken kan det være vanskeligt at skelne mundslimhindefo...

  16. Le Brésil se rapproche du CERN

    CERN Multimedia

    2002-01-01

    Brazil has a strong tradition of particle physics research. During a recent visit, the Brazilian Minister for Science and Technology, S.E. Ronaldo Mota Sardenberg, discussed with the Director General, Luciano Maiani, how the bonds between them could be strengthened (0.5 page)

  17. CdSe Quantum Dots for Solar Cell Devices

    Directory of Open Access Journals (Sweden)

    A. B. Kashyout

    2012-01-01

    Full Text Available CdSe quantum dots have been prepared with different sizes and exploited as inorganic dye to sensitize a wide bandgap TiO2 thin films for QDs solar cells. The synthesis is based on the pyrolysis of organometallic reagents by injection into a hot coordinating solvent. This provides temporally discrete nucleation and permits controlled growth of macroscopic quantities of nanocrystallites. XRD, HRTEM, UV-visible, and PL were used to characterize the synthesized quantum dots. The results showed CdSe quantum dots with sizes ranging from 3 nm to 6 nm which enabled the control of the optical properties and consequently the solar cell performance. Solar cell of 0.08% performance under solar irradiation with a light intensity of 100 mW/cm2 has been obtained. CdSe/TiO2 solar cells without and with using mercaptopropionic acid (MPA as a linker between CdSe and TiO2 particles despite a Voc of 428 mV, Jsc of 0.184 mAcm-2, FF of 0.57, and η of 0.05% but with linker despite a Voc of 543 mV, Jsc of 0.318 mAcm-2 , FF of 0.48, and η of 0.08%, respectively.

  18. Sample (S): SE37_S17 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE37_S17 PSEUDO: Unlabeled Medicago truncatula samples and a blank sample for the d...etection of reproducible metabolite peaks Medicago truncatula NCBI taxonomy:3880 This is a pseudo metadata p...repared for integrated analyses of multiple datasets. The Medicago samples (S01, S02, and S03) and a blank sample (S16) are included. ...

  19. The Crystal Structure of Cu4Bi4Se9

    DEFF Research Database (Denmark)

    Makovicky, E.; Søtofte, Inger; Karup-Møller, S.

    2002-01-01

    The crystal structure Of Cu4Bi4Se9,, synthesized at 400 degreesC, was determined from single crystal X-ray diffraction data and refined to the R, value of 0.05. The compound is orthorhombic, with a = 32.692 Angstrom, b = 4.120 Angstrom, and c = 12.202 Angstrom, space group Pnma. The structure...

  20. The Crystal Structure of Cu4Bi4Se9

    DEFF Research Database (Denmark)

    Makovicky, E.; Søtofte, Inger; Karup-Møller, S.

    2002-01-01

    The crystal structure Of Cu4Bi4Se9,, synthesized at 400 degreesC, was determined from single crystal X-ray diffraction data and refined to the R, value of 0.05. The compound is orthorhombic, with a = 32.692 Angstrom, b = 4.120 Angstrom, and c = 12.202 Angstrom, space group Pnma. The structure...

  1. Sample (S): SE40_S27 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE40_S27 Solanum lycopersicum Carol7 (Karin) fruit Solanum lycopersicum NCBI taxono...my:4081 Solanum lycopersicum Carol7 (Karin) were purchased at a local market of Kyoto city, (Kyoto, Japan) (November, 2015). Aichi-san. ...

  2. Exciton dephasing in ZnSe quantum wires

    DEFF Research Database (Denmark)

    Wagner, Hans Peter; Langbein, Wolfgang Werner; Hvam, Jørn Märcher

    1998-01-01

    The homogeneous linewidths of excitons in wet-etched ZnSe quantum wires of lateral sizes down to 23 nm are studied by transient four-wave mixing. The low-density dephasing time is found to increase with decreasing wire width. This is attributed mainly to a reduction of electron-exciton scattering...

  3. Pulsed laser deposition of ZnSe N epilayers

    CERN Document Server

    Boo, B H; Xu, N

    2000-01-01

    A high-quality epitaxial film of nitrogen-doped ZsSe has been grown on a GaAs(100) substrate by using pulsed laser deposition assisted by an atomic nitrogen beam produced by a supersonic nozzle beam source. Atomic force microscopy shows that the surface of the ZnSe epilayer grown on GaAs(100) at 2 x 10 sup - sup 3 Torr is flat and dense. It also shows that its roughness is approx = 1.6 nm, less than that of epilayers grown by using metalorganic vapor phase epitaxy. X-ray diffraction results show that this ZnSe epilayer is a single crystalline epitaxial film. X-ray photoelectron spectroscopy (XPS) indicates that the epilayer is composed of 84 % Zn and Se, 10 % N, and 6 % O; other impurities are rare. The XPS spectra involving the Zn(2p sub 3 sub / sub 2) and the N(1s) core levels also indicate that the concentration of doped nitrogen atoms is above 10 sup 2 sup 1 /cm sup 3.

  4. Sample (S): SE3_S02 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE3_S02 Solanum lycopersicum House Momotaro fruit Solanum lycopersicum NCBI taxonom...y:4081 Solanum lycopersicum House Momotaro (ref: http://www.e-taneya.com/item/914.html) are grown at agricultural field under normal film in natural conditions. ...

  5. Photoluminescence enhancement in thin films of PbSe nanocrystals

    NARCIS (Netherlands)

    Christova, C.G.; Stouwdam, J.W.; Eijkemans, T.J.; Silov, A.Y.; Van der Heijden, R.W.; Kemerink, M.; Janssen, R.A.J.; Salemink, H.W.M.

    2008-01-01

    Remarkable photoluminescence enhancement (PLE) in submonolayer films of PbSe nanocrystals (NCs) upon continuous illumination was observed. The intensity increase from films on InP substrates was highest in vacuum, while for films on Si/SiO2 substrates the PLE was stronger in air. The magnitude of th

  6. Nonlinear optical characteristics of monolayer MoSe{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Le, Chinh Tam; Ullah, Farman; Senthilkumar, Velusamy; Kim, Yong Soo [Department of Physics and Energy Harvest Storage Research Center, University of Ulsan (Korea, Republic of); Clark, Daniel J.; Jang, Joon I. [Department of Physics, Applied Physics and Astronomy, Binghamton University, Binghamton, NY (United States); Sim, Yumin; Seong, Maeng-Je [Department of Physics, Chung-Ang University, Seoul (Korea, Republic of); Chung, Koo-Hyun [School of Mechanical Engineering, University of Ulsan (Korea, Republic of); Park, Hyoyeol [Electronics, Communication and Semiconductor Applications Department, Ulsan College (Korea, Republic of)

    2016-08-15

    In this study, we utilized picosecond pulses from an Nd:YAG laser to investigate the nonlinear optical characteristics of monolayer MoSe{sub 2}. Two-step growth involving the selenization of pulsed-laser-deposited MoO{sub 3} film was employed to yield the MoSe{sub 2} monolayer on a SiO{sub 2}/Si substrate. Raman scattering, photoluminescence (PL) spectroscopy, and atomic force microscopy verified the high optical quality of the monolayer. The second-order susceptibility χ{sup (2)} was calculated to be ∝50 pm V{sup -1} at the second harmonic wavelength λ{sub SHG} ∝810 nm, which is near the optical gap of the monolayer. Interestingly, our wavelength-dependent second harmonic scan can identify the bound excitonic states including negatively charged excitons much more efficiently, compared with the PL method at room temperature. Additionally, the MoSe{sub 2} monolayer exhibits a strong laser-induced damage threshold ∝16 GW cm{sup -2} under picosecond-pulse excitation{sub .} Our findings suggest that monolayer MoSe{sub 2} can be considered as a promising candidate for high-power, thin-film-based nonlinear optical devices and applications. (copyright 2016 by WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  7. Photoacoustic characterization of n-RuSe2 semiconductor pellets

    Science.gov (United States)

    Bernal-Alvarado, J.; Vargas-Luna, M.; Solorza-Feria, O.; Mondragón, R.; Alonso-Vante, N.

    2000-09-01

    Using the open photoacoustic cell technique, a set of physical properties for a semiconductor (n-RuSe2) in powder form was measured. According to the Dramicanin theoretical model, charge carriers transport parameters (bulk and surface) and the effective thermal diffusivity were obtained.

  8. Pollen of Syzygium (Myrtaceae) from SE Asia, especially Thailand

    NARCIS (Netherlands)

    Parnell, J.

    2003-01-01

    Pollen of 57 species of Syzygium from SE Asia were surveyed by SEM. The grains are all ± triangular in polar view, uniformly small (mean diameter 10.4 μm) with few surface sculpturing features. All species examined exhibit a distinct apocolpium and, usually, apocolpial field. The presence of an apoc

  9. Sample (S): SE40_S24 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE40_S24 Solanum lycopersicum Kyotemari fruit Solanum lycopersicum NCBI taxonomy:40...81 Solanum lycopersicum Kyotemari fruit are grown in greenhouses of the Experimental Farm of Kyoto University (Takatsuki, Osaka, Japan) from winter 2013 to spring 2014. ...

  10. Photoluminescence enhancement in thin films of PbSe nanocrystals

    NARCIS (Netherlands)

    Christova, C.G.; Stouwdam, J.W.; Eijkemans, T.J.; Silov, A.Y.; Van der Heijden, R.W.; Kemerink, M.; Janssen, R.A.J.; Salemink, H.W.M.

    2008-01-01

    Remarkable photoluminescence enhancement (PLE) in submonolayer films of PbSe nanocrystals (NCs) upon continuous illumination was observed. The intensity increase from films on InP substrates was highest in vacuum, while for films on Si/SiO2 substrates the PLE was stronger in air. The magnitude of

  11. Introduction : A decade of experience with the SE

    NARCIS (Netherlands)

    Cremers, Jan; Cremers, Jan; Stollt, Michael; Vitols, Sigurt

    2013-01-01

    The first (introductory) chapter of this book describes the (legal) background, the definition of the European Company (SE) and the different articles of the legislation. The focus is on workers involvement and the relationship with national practices. It also summarizes the different contributions.

  12. Photoluminescence enhancement in thin films of PbSe nanocrystals

    NARCIS (Netherlands)

    Christova, C.G.; Stouwdam, J.W.; Eijkemans, T.J.; Silov, A.Y.; Van der Heijden, R.W.; Kemerink, M.; Janssen, R.A.J.; Salemink, H.W.M.

    2008-01-01

    Remarkable photoluminescence enhancement (PLE) in submonolayer films of PbSe nanocrystals (NCs) upon continuous illumination was observed. The intensity increase from films on InP substrates was highest in vacuum, while for films on Si/SiO2 substrates the PLE was stronger in air. The magnitude of th

  13. Mantle structure and tectonic history of SE Asia

    NARCIS (Netherlands)

    Hall, Robert; Spakman, Wim|info:eu-repo/dai/nl/074103164

    2015-01-01

    Seismic travel-time tomography of the mantle under SE Asia reveals patterns of subduction-related seismic P-wave velocity anomalies that are of great value in helping to understand the region's tectonic development. We discuss tomography and tectonic interpretations of an area centred on Indonesia

  14. Sample Preparation (SS): SE59_SS01 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE59_SS01 Drought stress Three-week-old plants vertically grown on GM plates were i...ncubated in 24-well plates (TPP, http://www.tpp.ch/index.php). Each plant was put in a well with 3 ml water. Three

  15. Chemistry in CESM-SE: Evaluation, Performance and Optimization

    Energy Technology Data Exchange (ETDEWEB)

    Lamarque, Jean-Francois [National Center for Atmospheric Research, Boulder, CO (United States); Conley, Andrew [National Center for Atmospheric Research, Boulder, CO (United States); Vitt, Francis [National Center for Atmospheric Research, Boulder, CO (United States); Drake, John [Univ. of Tennessee, Knoxville, TN (United States); Sun, Jian [Univ. of Tennessee, Knoxville, TN (United States)

    2016-01-06

    The purpose of the proposed work focused on development of chemistry representation within the Spectral Element (SE) dynamical core as implemented in the Community Earth System Model (CESM). More specifically, a main focus was on the ability of SE to accurately represent tracer transport. The proposed approach was to incrementally increase the complexity of the problem, starting from specified two-dimensional flow and tracers to simulations using specified dynamics and full chemistry. As demonstrated below, we have successfully studied all aspects of the proposed work, although only part of the work has been published in the refereed literature so far. Furthermore, because the SE dynamical core has been found to have several deficiencies that are still being investigated for solution, not all proposed tasks were finalized. In addition to the tests for SE performance, in an effort to decrease the computational burden of interactive chemistry, especially in the case of a large number of chemical species and chemical reactions, development on a faster chemical solver and implementation on GPUs has been implemented in CESM under the leadership of John Drake (U. Tennessee).

  16. Photon guiding characteristics of waveguide membranes coupled to a microdisk of ZnSe/(Zn,Mg)Se quantum well structures

    Science.gov (United States)

    Schmidt, G.; Rieger, T.; Trellenkamp, S.; Grützmacher, D.; Pawlis, A.

    2017-07-01

    Integrated optical devices composed of waveguides and microdisks emitting blue light were fabricated from ZnSe/(Zn,Mg)Se quantum well structures. Here we study the optical properties and photon guiding characteristics of such devices. The structures were fabricated by multi-step electron beam lithography and subsequent wet chemical etching. The transfer characteristic of photons through the waveguide was analyzed via spatial-resolved μ-photoluminescence spectroscopy. Spatial excitation of the microdisk revealed substantial overcoupling of photons from the microdisk into the waveguide.

  17. Effect of deformation on the valence shell occupancies of 74Ge, 76Ge, 76Se and 78Se

    Science.gov (United States)

    Elsharkawy, H. M.; Saleh Yousef, M.

    2017-03-01

    The set of BCS equations have been solved using both realistic and schematic separable forces to calculate the occupation probability amplitudes for protons and neutrons in the valence shells of 74Ge, 76Ge, 76Se and 78Se deformed nuclei. A comparison between the calculated occupation probabilities with the experimental measured values is introduced. A big difference is found between the occupation probabilities of protons with the experimental values, while for neutrons the agreement with the experimental values at high deformations is satisfactory.

  18. Electronic structure of the layer compounds GaSe and InSe in a tight-binding approach

    Science.gov (United States)

    Camara, M. O.; Mauger, A.; Devos, I.

    2002-03-01

    The three-dimensional band structure of the III-VI layer compounds GaSe and InSe has been investigated in the tight-binding approach. The pseudo-Hamiltonian matrix elements in the sp3s* basis are fit in order to reproduce the nonlocal pseudopotential band structure, in the framework of constrained optimization techniques using the conjugate gradient method. The results are in good agreement with the optical and photoemission experimental data. The scaling laws appropriate to the covalent bonding are violated by a fraction of eV only, which suggests that the interlayer interactions are not solely of the van der Waals type.

  19. Photoinduced interaction of CdSe quantum dot with coumarins

    Energy Technology Data Exchange (ETDEWEB)

    El-Kemary, Maged, E-mail: elkemary@sci.kfs.edu.eg [Nanotechnology Center, Faculty of Science, Kafrelsheikh University, 33516 Kafrelsheikh (Egypt); Gaber, Mohamed; El-Sayed, Y.S. [Chemistry Department, Faculty of Science, University of Tanta, Tanta (Egypt); Gheat, Youssef [Nanotechnology Center, Faculty of Science, Kafrelsheikh University, 33516 Kafrelsheikh (Egypt); Chemistry Department, Faculty of Science, University of Tanta, Tanta (Egypt)

    2015-03-15

    Cadmium selenide (CdSe) quantum dots (QDs) were synthesized with a cubic shape having a diameter of ∼5.24 nm. The prepared CdSe QDs were characterized by using UV–visible, Fourier transform infrared (FTIR), powder X-ray diffraction (XRD) and transmission electron microscope (TEM) measurements. The UV–visible absorption spectra indicate that the optical band gap of CdSe QDs is ∼622 nm and the peak shift can mainly be due to the quantum size effects. The fluorescence decay kinetics for the synthesized QDs was followed by time-resolved fluorescence spectroscopy, and the spectra were analyzed in regard to a bi-exponential model to identify two lifetime values, that is, shorter-lifetime 1.37 ns (55%) and longer-lifetime 6.58 ns (45%). The interaction of coumarin 152 (C152) and coumarin 153 (C153) with QDs surface brings about further considerable changes in the absorption and fluorescence patterns. The calculated binding constant from fluorescence quenching method matches well with that determined from the absorption spectral changes. The static quenching mechanism was confirmed by large magnitude of K{sub SV} and unaltered fluorescence lifetime. - Highlights: • CdSe QDs were synthesized with a cubic shape having a diameter of ∼5.24 nm. • The UV–visible absorption spectra indicate that the optical band gap of CdSe QDs is ∼622 nm. • Picosecond fluorescence measurements of the QDs suggest bi-exponential function. • The calculated binding constant from fluorescence quenching method matches well with that determined from the absorption spectral changes. • The static quenching mechanism was confirmed by large magnitude of K{sub SV} and unaltered fluorescence lifetime.

  20. High-conjugation-efficiency aqueous CdSe quantum dots.

    Science.gov (United States)

    Au, Giang H T; Shih, Wan Y; Shih, Wei-Heng

    2013-11-12

    Quantum dots (QDs) are photoluminescent nanoparticles that can be directly or indirectly coupled with a receptor such as an antibody to specifically image a target biomolecule such as an antigen. Recent studies have shown that QDs can be directly made at room temperature and in an aqueous environment (AQDs) with 3-mercaptopropionic acid (MPA) as the capping ligand without solvent and ligand exchange typically required by QDs made by the organic solvent routes (OQDs). In this study, we have synthesized CdSe AQDs and compared their conjugation efficiency and imaging efficacy with commercial carboxylated OQDs in HT29 colon cancer cells using a primary antibody-biotinylated secondary antibody-streptavidin (SA) sandwich. We showed that the best imaging condition for AQDs occurred when one AQD was bound with 3 ± 0.3 SA with a nominal SA/AQD ratio of 4 corresponding to an SA conjugation efficiency of 75 ± 7.5%. In comparison, for commercial CdSe-ZnS OQDs to achieve 2.7 ± 0.4 bound SAs per OQD for comparable imaging efficacy a nominal SA/OQD ratio of 80 was needed corresponding to an SA conjugation efficiency of 3.4 ± 0.5% for CdSe-ZnS OQDs. The more than 10 times better SA conjugation efficiency of the CdSe AQDs as compared to that of the CdSe-ZnS OQDs was attributed to more capping molecules on the AQD surface as a result of the direct aqueous synthesis. More capping molecules on the AQD surface also allowed the SA-AQD conjugate to be stable in cell culture medium for more than three days without losing their staining capability in a flowing cell culture medium. In contrast, SA-OQD conjugates aggregated in cell culture medium and in phosphate buffer saline solution over time.

  1. Sensor Exposure, Exploitation, and Experimentation Environment (SE4)

    Science.gov (United States)

    Buell, D.; Duff, F.; Goding, J.; Bankston, M.; McLaughlin, T.; Six, S.; Taylor, S.; Wootton, S.

    2011-09-01

    As the resident space object population increases from new launches and events such as the COSMOS/IRIDIUM collision, the maintenance of high-level Space Situational Awareness (SSA) has become increasingly difficult. To maintain situational awareness of the changing environment, new systems and methods must be developed. The Sensor Exposure, Exploitation and Experimentation Environment (SE4) provides a platform to illustrate “The Art of the Possible” that shows the potential benefit of enriched sensor data collections and real-time data sharing. Through modeling and simulation, and a net-centric architecture, SE4 shows the added value of sharing data in real-time and exposing new types of sensor data. The objective of SE4 is to develop an experimentation and innovation environment for sensor data exposure, composable sensor capabilities, reuse, and exploitation that accelerates the delivery of needed Command and Control, Intelligence, Surveillance, and Reconnaissance capabilities to the warfighter. Through modeling, simulation and rapid prototyping, the art of the possible for a fully-connected, net-centric space Command and Control (C2) and sensor enterprise can be demonstrated. This paper provides results that demonstrate the potential for faster cataloging of breakup events and additional event monitoring that are possible with data available today in the Space Surveillance Network (SSN). Demonstrating the art of the possible for the enterprise will guide net-centric requirements definition and facilitate discussions with stakeholder organizations on the Concept of Operations (CONOPS), policy, and Tactics, Techniques, and Procedures (TTP) evolution necessary to take full advantage of net-centric operations. SE4 aligns with direction from Secretary Gates and the Chairman Joint Chief of Staff that emphasizes the need to get the most out of our existing systems. Continuing to utilize SE4 will enable the enterprise by demonstrating the benefits of applying

  2. Effect of lattice disorder on the thermal conductivity of ZnBeSe, ZnMgSe and ZnBeMgSe crystals

    Energy Technology Data Exchange (ETDEWEB)

    Strzałkowski, K., E-mail: skaroll@fizyka.umk.pl

    2015-08-01

    Zn{sub 1−x−y}Be{sub x}Mg{sub y}Se mixed crystals investigated in this work were grown from the melt by the high pressure high temperature modified Bridgman method in the range of composition 0 < x,y < 0.33. Photopyroelectric (PPE) calorimetry in the back (BPPE) and front (FPPE) configuration was applied for thermal investigation of solid samples. The thermal diffusivity and effusivity of investigated crystals were derived from the experimental data. Since dynamic thermal parameters are connected with each other, thermal conductivity of the specimens was calculated from theoretical dependencies between them. The influence of the beryllium (x) and magnesium (y) content on thermal properties of these crystals have been presented and discussed. Order-disorder effects observed for these materials previously have been also taken into account. Finally, thermal diagrams, i.e. thermal conductivity versus composition were presented and discussed applying model given by Sadao Adachi. - Highlights: • Investigated II–VI crystals were obtained by a high pressure modified Bridgman method. • A complete thermal characterization of Zn{sub 1−x−y}Be{sub x}Mg{sub y}Se semiconductors was carried out. • The effect of lattice disorder on thermal properties was presented and discussed. • Obtained data were analyzed applying lattice thermal conductivity model. • Contribution to thermal resistivity arising from lattice disorder was calculated.

  3. Determination of the costs of the nuclear desalination using the DEEP code from IAEA; Determinacion de los costos de la desalacion nuclear utilizando el codigo DEEP del OIEA

    Energy Technology Data Exchange (ETDEWEB)

    Ramirez S, J.R.; Palacios H, J.C.; Alonso V, G. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)]. e-mail: jrrs@nuclear.inin.mx

    2005-07-01

    The desalination of seawater is being an important solution to satisfy the demands of drinking water to population's centers that have hydric resources very limited, like it is the case of some Arab countries and arid regions of the planet, in where they have settled desalination plants that use as energy source to those fossil fuels or nuclear energy plants. Taking into account that the desalination of seawater is a process that consumes a lot of thermal and/or electric energy, it is necessary to quantify the costs of the supply and that of the desalination plant for different options and technologies, looking for this way the but appropriate for the specific conditions of the region where it has planned the desalination of seawater. In this report the three technologies but promising for the desalination are described and by means of the DEEP code the costs of production of water and energy are evaluated, using as thermal source different types of power nuclear reactors. It was obtained according to DEEP that the costs of the electricity generation for the considered reactors are around 40 USD/MWh. With these costs of electric power generation and using the DEEP code is obtained that the costs of production of drinking water are around 1 USD/m{sup 3}. (Author)

  4. IAEA Mission on the Programme for the rehabilitation of contaminated areas in Japan; Mision del OIEA sobre el Programa de Rehabilitacion de Zonas Contaminadas en Japon

    Energy Technology Data Exchange (ETDEWEB)

    Lentijo, J. C.

    2011-07-01

    In October the International Atomic Energy Agency sent an expert mission to gain insight into and assess the rehabilitation programme implemented by the Japanese government to allow for the return of residents to certain areas affected by the accident that occurred at the Fukushima nuclear power plant. The results of this mission, which was led by the CSN Director of Radiological Protection, point to the viability, suitability and seriousness of the project and include suggestions for improvement. (Author)

  5. Alteraciones y manipulaciones de la contabilidad

    OpenAIRE

    Villarroya Lequericaonandia, María Begoña

    2001-01-01

    Se estudian las principales prácticas utilizadas por las empresas para manipular la información incluida en las Cuentas Anuales. En el primer capítulo se analizan los factores que provocan que los administradores de estas sociedades hagan uso o no de estas prácticas de manipulación. Los capítulos 2º y 3º se destinan a analizar la regulación mercantil, administrativa y penal relacionada tanto con las obligaciones en materia contable, como la derivada del incumplimiento de éstas. En el...

  6. Micro-Raman Study of Orientation Effects of CuxSe-Crystallites on Cu-rich CuGaSe2 Thin Films

    Science.gov (United States)

    Xue, C.; Papadimitriou, D.; Raptis, Y. S.; Richter, W.; Esser, N.; Siebentritt, S.; Lux-Steiner, M. Ch.

    2004-08-01

    The structural properties of copper selenide (CuxSe), formed as a secondary phase on the surface of CuGaSe2 films grown under Cu-rich conditions on GaAs (100) substrates, were studied by micro-Raman spectroscopy. Raman bands at 45 and 263cm-1, observed on crystallites dispersed on the CuGaSe2 film, are in agreement with the Raman modes of CuSe and Cu2Se. Polarization- and angular-dependent micro-Raman measurements reveal that the CuxSe-crystallites are grown with a preferential orientation on the CuGaSe2 surface.

  7. La estructura algebraica del espacio de señales unidimensionales

    Directory of Open Access Journals (Sweden)

    Marlio Paredes

    2005-01-01

    Full Text Available En este trabajo se describe la estructura matemática del espacio de señales unidimensionales usado en el procesamiento de señales. Se muestra cómo este espacio admite estructura de álgebra y se presentan varios de los operadores que actúan sobre el espacio que son usados en el procesamiento de señales. Particularmente se muestra que las matrices de todos estos operadores son matrices circulantes.

  8. Sobre el español que se habla en México

    OpenAIRE

    Romo-Gil, Cristina

    1987-01-01

    Texto sobre los libros “Diccionario Básico del Español de México” realizado por un equipo dirigido por Luis Fernando Lara; “Para saber lo que se dice”, de Arrigo Coen, y “Minucias del lenguaje”, de José G. Moreno de Alba. En las tres obras se trata el tema del español que se habla, se escribe, se inventa, se destroza y se oculta en México.

  9. Growth and characterization of van der Waals heterostuctures formed by the topological insulator Bi2Se3 and the trivial insulator SnSe2

    Science.gov (United States)

    Matetskiy, A. V.; Kibirev, I. A.; Zotov, A. V.; Saranin, A. A.

    2016-07-01

    The formation, structure and electronic properties of SnSe2-Bi2Se3 van der Waals heterostructures were studied. Both heterostructures, SnSe2 on Bi2Se3 and Bi2Se3 on SnSe2, were grown epitaxially with high crystallinity and sharp interfaces. Their electron band structures are of trivial and topological insulators, respectively. The Dirac surface states of Bi2Se3 survive under the SnSe2 overlayer. One triple layer of SnSe2 was found to be an efficient spacer for separating a Bi2Se3 topological-insulator slab into two and creating the corresponding topological surface states.

  10. Origin of the enhancement in transport properties on polycrystalline SnSe with compositing two-dimensional material MoSe2

    Science.gov (United States)

    Huang, Xue-Qin; Chen, Yue-Xing; Yin, Meijie; Feng, Dan; He, Jiaqing

    2017-03-01

    P-type SnSe compositing with 2D MoSe2 materials have been prepared by the solid solution method followed by the spark plasma sintering technique. The total thermal conductivities of SnSe/MoSe2 composites were found to be higher than for pristineSnSe at room temperature; and the disparity between them becomes smaller at higher temperatures, where the low thermal conductivities remained. Both the carrier concentration and the carrier mobility were significantly improved after MoSe2 was introduced into the SnSe matrix along the direction perpendicular to the pressing direction, leading to an extraordinary enhancement in electrical transport performance. The maximum ZT of 0.5 was obtained at 773 K for SnSe + 1.5%MoSe2 along the direction perpendicular to the pressing direction; this value is 1.5 times as large as that of the pristine SnSe.

  11. Influence of the stacking order on structural features of the Cu-In-Ga-Se precursors for formation of Cu(In,Ga)Se{sub 2} thin films prepared by thermal reaction of InSe/Cu/GaSe alloys to elemental Se vapor and diethylselenide gas

    Energy Technology Data Exchange (ETDEWEB)

    Dejene, F.B. [Physics Department, University of the Free State, Private Bag X13, Phuthaditjhaba (South Africa); Sugiyama, M.; Nakanishi, H. [Department of Electrical Engineering, Tokyo University of Science, 2641 Yamazaki, Noda 278-8510 (Japan); Alberts, V. [Department of Physics, University of Johannesburg, Johannesburg 2006 (South Africa); Chichibu, S.F. [Institute of Applied Physics and Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba 305-8573 (Japan)

    2006-09-15

    A novel partway for the fabrication of copper-indium (gallium) diselenide has been developed. This two-stage process consists of the formation of Cu-In-(Ga)-Se precursors and subsequent selenization to form CuIn(Ga)Se{sub 2}. In this work, we have investigated and compared the possible interactions in Cu-In-Ga-Se systems, using sequentially stacked precursors premixed with Se, in order to get a better understanding of the Cu(In,Ga)Se{sub 2} thin film formation. Comparison of these SEM micrographs clearly revealed that the surface morphologies and hence surface roughness of the resulting Cu(In,Ga)Se{sub 2} absorber films were significantly influenced by the structure of the precursor films prior to selenization. XRD analyses revealed the presence of a graded CuIn{sub 1-x}Ga{sub x}Se structure, irrespective of the stacking order during the precursor formation step for samples selenized using elemental Se vapor. It was established that distinct from the case of using Se vapor, a single-phase Cu(In,Ga)Se{sub 2} films were obtained by diethylselenide (DESe) selenization from Cu-In-Ga metal precursors premixed Se irrespective of the stacking order during the precursor formation step. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  12. Influence of the stacking order on structural features of the Cu-In-Ga-Se precursors for formation of Cu(In,Ga)Se2 thin films prepared by thermal reaction of InSe/Cu/GaSe alloys to elemental Se vapor and diethylselenide gas

    Science.gov (United States)

    Dejene, F. B.; Sugiyama, M.; Nakanishi, H.; Alberts, V.; Chichibu, S. F.

    2006-09-01

    A novel partway for the fabrication of copper-indium (gallium) diselenide has been developed. This two-stage process consists of the formation of Cu-In-(Ga)-Se precursors and subsequent selenization to form CuIn(Ga)Se2. In this work, we have investigated and compared the possible interactions in Cu-In-Ga-Se systems, using sequentially stacked precursors premixed with Se, in order to get a better understanding of the Cu(In,Ga)Se2 thin film formation. Comparison of these SEM micrographs clearly revealed that the surface morphologies and hence surface roughness of the resulting Cu(In,Ga)Se2 absorber films were significantly influenced by the structure of the precursor films prior to selenization. XRD analyses revealed the presence of a graded CuIn1-xGaxSe structure, irrespective of the stacking order during the precursor formation step for samples selenized using elemental Se vapor. It was established that distinct from the case of using Se vapor, a single-phase Cu(In,Ga)Se2 films were obtained by diethylselenide (DESe) selenization from Cu-In-Ga metal precursors premixed Se irrespective of the stacking order during the precursor formation step.

  13. Giant piezoelectricity of monolayer group IV monochalcogenides: SnSe, SnS, GeSe, and GeS

    Energy Technology Data Exchange (ETDEWEB)

    Fei, Ruixiang; Yang, Li, E-mail: lyang@physics.wustl.edu [Department of Physics, Washington University, St. Louis, Missouri 63130 (United States); Li, Wenbin [Research Laboratory of Electronics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Li, Ju [Department of Nuclear Science and Engineering and Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    2015-10-26

    We predict enormous, anisotropic piezoelectric effects in intrinsic monolayer group IV monochalcogenides (MX, M=Sn or Ge, X=Se or S), including SnSe, SnS, GeSe, and GeS. Using first-principle simulations based on the modern theory of polarization, we find that their piezoelectric coefficients are about one to two orders of magnitude larger than those of other 2D materials, such as MoS{sub 2} and GaSe, and bulk quartz and AlN which are widely used in industry. This enhancement is a result of the unique “puckered” C{sub 2v} symmetry and electronic structure of monolayer group IV monochalcogenides. Given the achieved experimental advances in the fabrication of monolayers, their flexible character, and ability to withstand enormous strain, these 2D structures with giant piezoelectric effects may be promising for a broad range of applications such as nano-sized sensors, piezotronics, and energy harvesting in portable electronic devices.

  14. Electron density distribution and bonding in ZnSe and PbSe using maximum entropy method (MEM)

    Indian Academy of Sciences (India)

    K S Syed Ali; R Saravanan; S Israel; R K Rajaram

    2006-04-01

    The study of electronic structure of materials and bonding is an important part of material characterization. The maximum entropy method (MEM) is a powerful tool for deriving accurate electron density distribution in crystalline materials using experimental data. In this paper, the attention is focused on producing electron density distribution of ZnSe and PbSe using JCPDS X-ray powder diffraction data. The covalent/ionic nature of the bonding and the interaction between the atoms are clearly revealed by the MEM maps. The mid bond electron densities between atoms in these systems are found to be 0.544 e/Å3 and 0.261 e/Å3, respectively for ZnSe and PbSe. The bonding in these two systems has been studied using two-dimensional MEM electron density maps on the (100) and (110) planes, and the one-dimensional electron density profiles along [100], [110] and [111] directions. The thermal parameters of the individual atoms have also been reported in this work. The algorithm of the MEM procedure has been presented.

  15. Synthesis and Magnetic Properties of NiSe, NiTe, CoSe, and CoTe

    Science.gov (United States)

    Umeyama, Norio; Tokumoto, Madoka; Yagi, Shota; Tomura, Masatoshi; Tokiwa, Kazuyasu; Fujii, Takenori; Toda, Ryo; Miyakawa, Nobuaki; Ikeda, Shin-Ichi

    2012-05-01

    Polycrystalline NiSe, NiTe, CoSe, and CoTe have been synthesized by two methods, i.e., (1) the solid-state reaction in an evacuated quartz ampoule (QA) and (2) the high-pressure (HP) technique (HP) in a Au capsule using a cubic anvil cell. All the obtained samples have the nickel arsenide-type hexagonal crystal structure, except CoTe (HP), and their estimated lattice parameters, a and c, show almost the same values within 0.8% in comparison between samples prepared by the QA method and those by the HP method. On the other hand, a distinct difference between samples prepared by QA and HP processes is found in the magnetization of NiSe and NiTe. In particular, for NiTe, the temperature dependence of magnetization indicates two transition temperatures at about 20 and 130 K in samples prepared by the HP process. However, samples of NiTex (x = 0.5, 0.66, 0.82, 1, 1.22, and 2) and NiTe containing Au prepared by QA process do not show similar magnetic orders in the temperature range between 2 and 300 K. Also, samples of NiSe (HP) show magnetic transition at ˜20 K, while those of NiSe (QA) show a magnetic inflection point at ˜10 K. To the best of our knowledge the remarkable difference in magnetic properties caused by the method of synthesis has not been reported. In this paper, we present comparative experimental results of magnetic, electric, and specific heat measurements of samples prepared by the two methods. A possible explanation for such a substantial difference in magnetic interaction will be discussed.

  16. Influence of Se concentrations and species in hydroponic cultures on Se uptake, translocation and assimilation in non-accumulator ryegrass.

    Science.gov (United States)

    Versini, Antoine; Di Tullo, Pamela; Aubry, Emmanuel; Bueno, Maïté; Thiry, Yves; Pannier, Florence; Castrec-Rouelle, Maryse

    2016-11-01

    The success of biofortification and phytoremediation practices, addressing Se deficiency and Se pollution issues, hinges crucially on the fate of selenium in the plant media in response to uptake, translocation and assimilation processes. We investigate the fate of selenium in root and shoot compartments after 3 and 6 weeks of experiment using a total of 128 plants grown in hydroponic solution supplied with 0.2, 2, 5, 20 and 100 mg L(-1) of selenium in the form of selenite, selenate and a mixture of both species. Selenate-treated plants exhibited higher root-to-shoot Se translocation and total Se uptake than selenite-treated plants. Plants took advantage of the selenate mobility and presumably of the storage capacity of leaf vacuoles to circumvent selenium toxicity within the plant. Surprisingly, 28% of selenate was found in shoots of selenite-treated plants, questioning the ability of plants to oxidize selenite into selenate. Selenomethionine and methylated organo-selenium amounted to 30% and 8% respectively in shoots and 35% and 9% in roots of the identified Se, suggesting that selenium metabolization occurred concomitantly in root and shoot plant compartments and demonstrating that non-accumulator plants can synthesize notable quantities of precursor compound for volatilization. The present study demonstrated that non-accumulator plants can develop the same strategies as hyper-accumulator plants to limit selenium toxicity. When both selenate and selenite were supplied together, plants used selenate in a storage pathway and selenite in an assimilation pathway. Plants might thereby benefit from mixed supplies of selenite and selenate by saving enzymes and energy required for selenate reduction. Copyright © 2016 Elsevier Masson SAS. All rights reserved.

  17. CdSe/ZnSe量子点的合成与荧光特性%Synthesis and photoluminescence properties of CdSe/ZnSe quantum dots

    Institute of Scientific and Technical Information of China (English)

    曲玉秋; 李美成

    2010-01-01

    采用低温成核生长与一步法相结合的方式合成了CdSe/ZnSe核壳结构量子点,并通过吸收光谱、荧光光谱、X射线衍射等分析手段证明了ZnSe壳层包覆成功.对加入空穴传输材料后CdSe/ZnSe量子点的荧光变化情况进行了深入的研究.稳态光谱结果表明.空穴传输材料对量子点发光有较强的淬灭作用;时间分辨光谱结果显示,随着空穴传输材料分子浓度的增加,量子点的荧光寿命明显缩短,其荧光淬灭过程可以解释为静态淬灭和动态淬灭过程.静态淬灭来源于量子点表面与空穴传输材料间的相互作用;而动态淬灭则来源于量子点到空穴传输材料的空穴转移过程.因此,量子点的壳层结构及空穴传输材料的种类对量子点的荧光淬灭起关键作用.

  18. seFitness - i form med ord og bogstaver

    DEFF Research Database (Denmark)

    Lemmergaard, Jeanette

    2013-01-01

    I kølvandet på overgangen fra industri- til videnssamfund følger enorme informationsmængder, som kan være svære at overskue for de fleste. Og det kan ligefrem være en uoverkommelig barriere for de medarbejdere, der ikke har tilstrækkelige læse-, skrive- og it-færdigheder......I kølvandet på overgangen fra industri- til videnssamfund følger enorme informationsmængder, som kan være svære at overskue for de fleste. Og det kan ligefrem være en uoverkommelig barriere for de medarbejdere, der ikke har tilstrækkelige læse-, skrive- og it-færdigheder...

  19. Trap levels in layered semiconductor Ga 2SeS

    Science.gov (United States)

    Aydinli, A.; Gasanly, N. M.; Aytekin, S.

    2004-12-01

    Trap levels in nominally undoped Ga 2SeS layered crystals have been characterized by thermally stimulated current (TSC) measurements. During the measurements, current was allowed to flow along the c-axis of the crystals in the temperature range of 10-300 K. Two distinct TSC peaks were observed in the spectra, deconvolution of which yielded three peaks. The results are analyzed by curve fitting, peak shape and initial rise methods. They all seem to be in good agreement with each other. The activation energies of three trapping centers in Ga 2SeS are found to be 72, 100 and 150 meV. The capture cross section of these traps are 6.7×10 -23, 1.8×10 -23 and 2.8×10 -22 cm 2 with concentrations of 1.3×10 12, 5.4×10 12 and 4.2×10 12 cm -3, respectively.

  20. Giant Seebeck effect in Ge-doped SnSe

    Science.gov (United States)

    Gharsallah, M.; Serrano-Sánchez, F.; Nemes, N. M.; Mompeán, F. J.; Martínez, J. L.; Fernández-Díaz, M. T.; Elhalouani, F.; Alonso, J. A.

    2016-06-01

    Thermoelectric materials may contribute in the near future as new alternative sources of sustainable energy. Unprecedented thermoelectric properties in p-type SnSe single crystals have been recently reported, accompanied by extremely low thermal conductivity in polycrystalline samples. In order to enhance thermoelectric efficiency through proper tuning of this material we report a full structural characterization and evaluation of the thermoelectric properties of novel Ge-doped SnSe prepared by a straightforward arc-melting method, which yields nanostructured polycrystalline samples. Ge does not dope the system in the sense of donating carriers, yet the electrical properties show a semiconductor behavior with resistivity values higher than that of the parent compound, as a consequence of nanostructuration, whereas the Seebeck coefficient is higher and thermal conductivity lower, favorable to a better ZT figure of merit.

  1. SE Asian Palms for Agroforestry and Home Gardens

    Directory of Open Access Journals (Sweden)

    Anders S. Barfod

    2015-12-01

    Full Text Available Throughout SE Asia, palms are important in agroforestry systems and homegardens. Most species are used for multiple purposes based on both physical and nutritional properties of the palms. Except for a few commodities of worldwide importance such as palm oil and coconut, many palm products either do not figure in trade statistics, or they are merged with other products in a way, which makes it difficult to assess their importance. Here we focus on these products that are not prominent in national trade statistics and we review their sustainability and economic importance in SE Asia. We rank the most important palms according to their versatility, which is an extremely important property, especially for smallholders who practice subsistence agriculture. We conclude by listing a number of recommendations for future research directions based on experiences from the recently completed EU 7th Framework project (EU-PALMS 2009-2013.

  2. Superconductivity and ferromagnetism in nanomaterial NbSe2

    Science.gov (United States)

    Gill, Raminder

    2017-07-01

    Finding of superconductivity (SC) in ultra thin layer of Niobium diselenide (NbSe2) caught the attention of each condensed matter physicist in the era of nanotechnology. The coexistence of SC and magnetism have been a topic of interesting research in solid-state physics since the discovery of superconductivity. Ferromagnetism induced in any compound could destroy superconductivity by disturbing the cooper pairing of electrons of the atoms. The interplay between ferromagnetism (FM) and SC in nanomaterial NBSe2 impressed to study and to know the exact mechanism behind this coexistence which can lead to a very interesting research: superconductivity at room temperature. In this paper, I have theoretically studied the coexistence of SC and FM in NbSe2 and how this material could be useful in finding many high Tc nanomaterials.

  3. Reversible devitrification in amorphous As2 Se3 under pressure

    DEFF Research Database (Denmark)

    Ahmad, Azkar Saeed; Lou, Hong Bo; Lin, Chuan Long

    2016-01-01

    In pressure-induced reversible structural transitions, the term "reversible" refers to the recovery of the virgin structure in a material upon complete decompression. Pressure-induced amorphous-to-crystalline transitions have been claimed to be reversible, but evidence that amorphous material...... recovers its virgin amorphous structure upon complete depressurization has been lacking. In amorphous As2Se3 (a-As2Se3) chalcogenide, however, we report a novel reversible amorphous-to-crystalline transition that provides compelling experimental evidence that upon complete decompression, the recovered...... amorphous phase is structurally the same as that of the virgin (as-cast) amorphous phase. Combining the experimental results with ab initio molecular dynamics simulations, we elucidate that the amorphization is mediated by a surplus of total free energy in the high-pressure face-centered cubic phase...

  4. Small-core As-Se fiber for Raman amplification.

    Science.gov (United States)

    Thielen, P A; Shaw, L B; Pureza, P C; Nguyen, V Q; Sanghera, J S; Aggarwal, I D

    2003-08-15

    We have demonstrated Raman small-core As-Se fiber. More than 20-dB of gain was observed in a 1.1-m length of fiber pumped by a nanosecond pulse of approximately 10.8-W peak power at 1.50 microm. The peak of the Raman gain occurred at a shift of approximately 240 cm(-1). The Raman gain coefficient is estimated to be approximately 2.3 x 10(-11) m/W, which is more than 300 times greater than that of silica. The large Raman gain coefficient coupled with the large IR transparency window of these fibers shows promise for development of As-Se Raman fiber lasers and amplifiers in the near-, mid-, and long-IR spectral regions.

  5. Structure and optical properties of CdSe chalcogenide semiconductors

    Science.gov (United States)

    Ganaie, Mohsin; Prince, Zulfequar, M.

    2015-08-01

    CdSe bulk sample has been prepared by melt-quenching technique and were characterized with XRD, SEM, FTIR, and electrical measurements. Thin films were deposited by thermal evaporation technique on ultra clean glass substrates under a high vacuum of 10-6 Torr. An XRD measurement reveals the coexistence of glassy and crystalline phase in bulk sample. SEM studies shows single phase, porous, and granular surface morphology of powder CdSe alloy. Optical properties (optical gap, absorption coefficient, extinction coefficient, refractive index) are calculated in the range of 190-1100nm. Analysis of the optical measurement shows that the non-direct transition is predominant and the band gap come outs to be 1.751eV. Dc conductivity measurement is thermally activated process which shows the semiconducting nature of the sample having activation energy 0.31eV.

  6. Suppression of superconductivity by twin boundaries in FeSe.

    Science.gov (United States)

    Song, Can-Li; Wang, Yi-Lin; Jiang, Ye-Ping; Wang, Lili; He, Ke; Chen, Xi; Hoffman, Jennifer E; Ma, Xu-Cun; Xue, Qi-Kun

    2012-09-28

    Low-temperature scanning tunneling microscopy and spectroscopy are employed to investigate twin boundaries in stoichiometric FeSe films grown by molecular beam epitaxy. Twin boundaries can be unambiguously identified by imaging the 90° change in the orientation of local electronic dimers from Fe site impurities on either side. Twin boundaries run at approximately 45° to the Fe-Fe bond directions, and noticeably suppress the superconducting gap, in contrast with the recent experimental and theoretical findings in other iron pnictides. Furthermore, vortices appear to accumulate on twin boundaries, consistent with the degraded superconductivity there. The variation in superconductivity is likely caused by the increased Se height in the vicinity of twin boundaries, providing the first local evidence for the importance of this height to the mechanism of superconductivity.

  7. Señales purinérgicas Purinergic signals

    Directory of Open Access Journals (Sweden)

    Eduardo R Lazarowski

    2009-04-01

    Full Text Available En la última década se ha aportado clara evidencia de que tanto nucleósidos como nucleótidos de adenina y uridina pueden funcionar como factores de señalización extracelular. Su acción es mediada por dos tipos principales de receptores de superficie denominados purinérgicos. Los receptores P1 se activan por adenosina, y son todos metabotrópicos, mientras que los receptores de nucleótidos (ATP, ADP, UTP y UDP y nucleótidos-azúcares (UDP-glucosa y UDP-galactosa pueden ser metabotrópicos (P2Y o ionotrópicos (P2X. La importancia y complejidad de este sistema de señalización se evidencia por la diversidad de mecanismos de liberación de nucleótidos al medio extracelular y por la distribución ubicua de varios grupos de ectonucleotidasas capaces de catalizar la degradación y conversión de nucleótidos. Hasta el momento se han descrito y clonado una veintena de estos receptores que modulan una variedad de respuestas, como el impulso nervioso, la respuesta inflamatoria, la secreción de insulina, la regulación del tono vascular y la percepción del dolor. En la presente revisión se describen las características estructurales y farmacológicas de los receptores purinérgicos y se analiza la interacción dinámica entre estos receptores, los nucleósidos y nucleótidos, y las ectonucleotidasas, con especial atención a la dinámica de la agregación plaquetaria, la respuesta inmune y la hidratación de las mucosas respiratorias.In the last decade evidence accumulated that nucleosides and nucleotides of both uridine and adenine can act as extracellular signaling factors. Their action is mediated by two main types of surface receptors commonly known as purinergic. P1 receptors are metabotropic and activated by adenosine, whereas receptors for nucleotides (ATP, ADP, UTP and UDP and nucleotide-sugars (UDP-glucose and UDP-galactose can be either metabotropic (P2Y or ionotropic (P2X. The importance and complexity of this signaling system

  8. High temperature XRD of Cu2GeSe3

    Science.gov (United States)

    Premkumar D., S.; Chetty, Raju; Malar, P.; Mallik, Ramesh Chandra

    2015-06-01

    The Cu2GeSe3 is prepared by solid state synthesis method. The high temperature XRD has been done at different temperature from 30 °C to 450 °C. The reitveld refinement confirms Cu2GeSe3 phase and orthorhombic crystal structure. The lattice constants are increasing with increase in the temperature and their rate of increase with respect to temperature are used for finding the thermal expansion coefficient. The calculation of the linear and volume coefficient of thermal expansion is done from 30 °C to 400 °C. Decrease in the values of linear expansion coefficients with temperature are observed along a and c axis. Since thermal expansion coefficient is the consequence of the distortion of atoms in the lattice; this can be further used to find the minimum lattice thermal conductivity at given temperature.

  9. Superconductivity in cubic noncentrosymmetric PdBiSe Crystal

    Science.gov (United States)

    Joshi, B.; Thamizhavel, A.; Ramakrishnan, S.

    2015-03-01

    Mixing of spin singlet and spin triplet superconducting pairing state is expected in noncentrosymmetric superconductors (NCS) due to the inherent presence of Rashba-type antisymmetric spin-orbit coupling. Unlike low symmetry (tetragonal or monoclinic) NCS, parity is isotropicaly broken in space for cubic NCS and can additionally lead to the coexistence of magnetic and superconducting state under certain conditions. Motivated with such enriched possibility of unconventional superconducting phases in cubic NCS we are reporting successful formation of single crystalline cubic noncentrosymmetric PdBiSe with lattice parameter a = 6.4316 Å and space group P21 3 (space group no. 198) which undergoes to superconducting transition state below 1.8 K as measured by electrical transport and AC susceptibility measurements. Significant strength of Rashba-type antisymmetric spin-orbit coupling can be expected for PdBiSe due to the presence of high Z (atomic number) elements consequently making it potential candidate for unconventional superconductivity.

  10. Cr(+2) Diffusion Doping in ZnSe

    Science.gov (United States)

    Journigan, Troy D.; Chen, K.-T.; Chen, H.; Burger, A.; Schaffers, K.; Page, R. H.; Payne, S. A.

    1997-01-01

    Chromium doped zinc selenides crystals have recently been demonstrated to be a promising material for near-IR room temperature tunable lasers which has an emission range of 2-3 pm. In this study, a new diffusion doping process has been developed for incorporation of Cr(+2) ion into ZnSe wafers. This process has been successfully performed under isothermal conditions, at temperatures above 800 degrees Celsius. Concentrations in excess of 10(exp 19) Cr(+2) ions/cu cm, an order of magnitude larger than previously reported in melt grown ZnSe material, have been obtained. The diffusivity was estimated to be about 10-* sq cm/sec using a classical diffusion model. Resistivity was derived from current-voltage measurements and in the 107-10(exp 16) Ohms-cm and increased as function of Cr concentration.

  11. Kristeva's Thérèse: Mysticism and Modernism

    Directory of Open Access Journals (Sweden)

    Carol Mastrangelo Bové

    2013-05-01

    Full Text Available This essay focuses on Julia Kristeva’s recent volume Thérèse mon amour:  Sainte Thérèse d’Avila (2008, describing and placing this blend of novel, play, psychoanalytic cultural theory, and case history in the context of her work.  I argue that the volume contributes to an understanding of religion’s impact—especially Catholic mysticism--on Western categories of women.  I address in particular Thérèse’s mysticism and modernist use of a feminine figure to subvert practices threatening the vitality of the psyche and of social relations.  As in Kristeva’s earlier writing, her psychoanalytic approach to Catholicism’s influence continues to raise questions concerning the apparent stereotypes the approach may feed, especially that of the masochistic woman.

  12. Epitaxial growth of CZT(S,Se) on silicon

    Energy Technology Data Exchange (ETDEWEB)

    Bojarczuk, Nestor A.; Gershon, Talia S.; Guha, Supratik; Shin, Byungha; Zhu, Yu

    2016-03-15

    Techniques for epitaxial growth of CZT(S,Se) materials on Si are provided. In one aspect, a method of forming an epitaxial kesterite material is provided which includes the steps of: selecting a Si substrate based on a crystallographic orientation of the Si substrate; forming an epitaxial oxide interlayer on the Si substrate to enhance wettability of the epitaxial kesterite material on the Si substrate, wherein the epitaxial oxide interlayer is formed from a material that is lattice-matched to Si; and forming the epitaxial kesterite material on a side of the epitaxial oxide interlayer opposite the Si substrate, wherein the epitaxial kesterite material includes Cu, Zn, Sn, and at least one of S and Se, and wherein a crystallographic orientation of the epitaxial kesterite material is based on the crystallographic orientation of the Si substrate. A method of forming an epitaxial kesterite-based photovoltaic device and an epitaxial kesterite-based device are also provided.

  13. User preferences in Stenløse Syd

    DEFF Research Database (Denmark)

    Munthe-Kaas, Peter; Quitzau, Maj-Britt; Hoffmann, Birgitte;

    2009-01-01

    the mar-ket for this type of buildings. The report is a delivery of work package 1 in the European Concerto project called ‘Class 1’. This project was launched on the basis of the experiences of the Danish municipality of Egedal who initiated an urban development project explicitly promoting energy...... of the low energy perspective. The report concludes that the residents generally are very positive towards low energy dwellings, and the low energy requirements posed in Stenløse Syd do not per se seem to discourage any potential buyers. However, the survey also concludes that the environment is just one...... about the environment during the building process. The report confirms the complexity of residents’ preferences in relation to their choice of dwelling and to the patterns of moving, and draws some interesting pictures of role of environmental aspects. As this has not been the focus of many...

  14. Electronically-driven orthorhombic distortion in FeSe

    Science.gov (United States)

    Watson, Matthew; Davies, Nathaniel; Haghighirad, Amir; Narayanan, Arjun; Kim, Timur; Hoersch, Moritz; Blake, Samuel; Coldea, Amalia

    2015-03-01

    FeSe is structurally the simplest of Fe-based superconductors, and exhibits a tetragonal-to-orthorhombic structural transition at ~ 90 K, but no long-range magnetism at any temperature. We report measurements of the resistivity anisotropy in FeSe above Ts finding a large and divergent response to an applied strain, with a comparable magnitude and temperature-dependence to measurements in Ba(Fe1-xCox)2As2, but opposite sign. We compare this data with literature reports on NMR and our own ARPES data, which taken together indicate that the structural transition is electronically-driven with orbital degrees of freedom playing a central role. This work was supported by EPSRC, UK (EP/I004475/1) and Diamond Light Source.

  15. Bien communiquer sur sa thèse, suite.

    Directory of Open Access Journals (Sweden)

    Philippe Heller

    2005-07-01

    Full Text Available Après une brève présentation sur lui-même, Edouard Paulino du Craft (Centre de recherche et d’appui pour la formation et ses technologies, qui travaille à l’ Epfl lance le débat : que signifie communiquer sur sa thèse ? Parmi le petit auditoire de doctorants présents, les questions-réponses fusent : à qui s’adresse-t-on ? Pourquoi ? Comment s’adapter à son auditoire ? Mais en fait qu’est-ce que communiquer ? Doit-on suivre forcément son plan de thèse ou ...

  16. Electrochemical synthesis and characterization of Cu2Se nanowires

    Science.gov (United States)

    Kaur, Harmanmeet; Kaur, Jaskiran; Singh, Lakhwant; Singh, Surinder

    2013-12-01

    Copper Selenide (Cu2Se) nanowires were successfully fabricated via potentiostatic electrodeposition using polycarbonate membranes (Whatmann, USA) with nominal pore diameter of 100 nm. The morphology of the so fabricated nanowires was examined by field emission scanning electron microscopy (FE-SEM). Later the samples were characterized for their structural, optical and electrical properties by XRD, UV-visible spectroscopy and I-V respectively.

  17. Production of Porous ZnSe by Electrochemical Etching Method

    Directory of Open Access Journals (Sweden)

    А.F. Dyadenchuk

    2013-10-01

    Full Text Available Here we describe the production features of a porous layer on the surface of n-type single-crystalline zinc selenide. The surface structure is investigated and the photomicrographs of porous layers of the treated ZnSe crystal are represented. Process of the mosaic structure formation depending on the etching time is considered. The value of the flat-band potential with respect to the used electrolyte is calculated.

  18. Structural characterization of vacuum evaporated ZnSe thin films

    Indian Academy of Sciences (India)

    Pradip Kr Kalita; B K Sarma; H L Das

    2000-08-01

    Thermally evaporated ZnSe thin films deposited on glass substrates within substrate temperatures (s) at 303 K–623 K are of polycrystalline nature having f.c.c. zincblende structure. The most preferential orientation is along [111] direction for all deposited films together with other abundant planes [220] and [311]. The lattice parameter, grain size, average internal stress, microstrain, dislocation density and degree of preferred orientation in the film are calculated and correlated with s.

  19. Suppression of Superconductivity by Twin Boundaries in FeSe

    OpenAIRE

    Hoffman, Jenny Eve; Song, Can-Li; Wang, Yi-Lin; Jiang, Ye-Ping; Wang, Lili; He, Ke; Chen, Xi; Ma, Xu-Cun; Xue, Qi-Kun

    2012-01-01

    Low-temperature scanning tunneling microscopy and spectroscopy are employed to investigate twin boundaries in stoichiometric FeSe films grown by molecular beam epitaxy. Twin boundaries can be unambiguously identified by imaging the 90{\\deg} change in the orientation of local electronic dimers from Fe site impurities on either side. Twin boundaries run at approximately 45{\\deg} to the Fe-Fe bond directions, and noticeably suppress the superconducting gap, in contrast with the recent experiment...

  20. Sample (S): SE37_S18 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE37_S18 PSEUDO: Unlabeled and labeled Medicago samples for metabolite annotation u...sing ShiftedIonsFinder This is a pseudo metadata prepared for integrated analyses of multiple datasets. The unlabel...ed Medicago samples and a blank sample (S17), Medicago samples labeled by 13C (S05), 15N (S07), 28O (S10), and 34S (S13) are included. ...

  1. Nematic antiferromagnetic states in bulk FeSe

    Science.gov (United States)

    Liu, Kai; Lu, Zhong-Yi; Xiang, Tao

    2016-05-01

    The existence of nematic order, which breaks the lattice rotational symmetry with nonequivalent a and b axes in iron-based superconductors, is a well-established experimental fact. An antiferromagnetic (AFM) transition is accompanying this order, observed in nearly all parent compounds, except bulk FeSe. The absence of the AFM order in FeSe casts doubt on the magnetic mechanism of iron-based superconductivity, since the nematic order is believed to be driven by the same interaction that is responsible for the superconducting pairing in these materials. Here we show, through systematic first-principles electronic structure calculations, that the ground state of FeSe is in fact strongly AFM correlated but without developing a magnetic long-range order. Actually, there are a series of staggered n -mer AFM states with corresponding energies below that of the single stripe AFM state, which is the ground state for the parent compounds of most iron-based superconductors. Here, the staggered n -mer (n any integer >1 ) means a set of n adjacent parallel spins on a line along the b axis with antiparallel spins between n -mers along both a and b axes. Moreover, different n -mers can antiparallelly mix with each other to coexist. Among all the states, we find that the lowest energy states formed by the staggered dimer, staggered trimer, and their random antiparallel aligned spin states along the b axis are quasidegenerate. The thermal average of these states does not show any magnetic long-range order, but it does possess a hidden one-dimensional AFM order along the a axis, which can be detected by elastic neutron scattering measurements. Our finding gives a natural account for the absence of long-range magnetic order and suggests that the nematicity is driven predominantly by spin fluctuations even in bulk FeSe, providing a unified description on the phase diagram of iron-based superconductors.

  2. Annotation Method (AM): SE30_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE30_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  3. Annotation Method (AM): SE33_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE33_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  4. Annotation Method (AM): SE28_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE28_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  5. Annotation Method (AM): SE20_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE20_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  6. Annotation Method (AM): SE26_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE26_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  7. Annotation Method (AM): SE25_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE25_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  8. Annotation Method (AM): SE35_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE35_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  9. Annotation Method (AM): SE27_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE27_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  10. Annotation Method (AM): SE15_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE15_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  11. Annotation Method (AM): SE31_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE31_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  12. Annotation Method (AM): SE29_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE29_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  13. Annotation Method (AM): SE10_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE10_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  14. Annotation Method (AM): SE17_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE17_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  15. Annotation Method (AM): SE12_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE12_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  16. Annotation Method (AM): SE13_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE13_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  17. Annotation Method (AM): SE32_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE32_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  18. Annotation Method (AM): SE36_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE36_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  19. Annotation Method (AM): SE16_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE16_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  20. Annotation Method (AM): SE11_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE11_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  1. Annotation Method (AM): SE34_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE34_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  2. Annotation Method (AM): SE14_AM1 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available abase search. Peaks with no hit to these databases are then selected to secondary s...earch using exactMassDB and Pep1000 databases. After the database search processes, each database hits are m...SE14_AM1 PowerGet annotation A1 In annotation process, KEGG, KNApSAcK and LipidMAPS are used for primary dat

  3. Vivência de mulheres que se submeteram à gastroplastia

    Directory of Open Access Journals (Sweden)

    Glenda Agra

    2009-12-01

    Full Text Available A gastroplastia reduz as co-morbidades e melhora a qualidade de vida, resgatando a auto-estima e inclusão social doobeso mórbido. O estudo teve como objetivo investigar a vivência de mulheres que se submeteram à gastroplastia, apartir de seus discursos. Trata-se de um estudo exploratório com abordagem qualitativa, do qual participaram 16pacientes mulheres que se submeteram à cirurgia bariátrica. Os dados foram coletados nos meses de junho a julho de2007, por meio da técnica de entrevista semi-estruturada, com a utilização do sistema de gravação, as quais foramanalisadas qualitativamente, à luz da técnica do Discurso do Sujeito Coletivo. Emergiram as seguintes idéias centrais:elevação da auto-estima e bem-estar psicológico; promoção de bem-estar físico; mudança negativa no pós-operatórioimediato e mediato; mudança positiva após a fase de adaptação; possibilidade de maior socialização; satisfaçãofamiliar e pessoal enquanto mulher e maior disposição, segurança e melhor estado de humor. Conclui-se, portanto,que, a gastroplastia é um tratamento cirúrgico para obesos mórbidos, que remete à perda ponderal, melhora a autoestima,mas que traz conseqüências negativas. Daí a importância do cuidar destas pacientes desde a decisão de sesubmeter à cirurgia até a total reabilitação.

  4. Los números y otras secuencias se representan espacialmente

    Directory of Open Access Journals (Sweden)

    Antonio González-Hernández

    2007-11-01

    Full Text Available El estudio de la línea numérica mental ha dado paso a toda una serie de investigaciones centradas en la representación de secuencias ordenadas en el cerebro humano. Los resultados de estas investigaciones demuestran que otros tipos de secuencias ordenadas tales como los meses, las letras, o los días se encuentran representados en nuestro erebro también de una manera espacial.

  5. /sup 75/Se selenomethionine in the diagnosis of hepatocellular carcinoma

    Energy Technology Data Exchange (ETDEWEB)

    Douglas, J.G.; Zambartas, C.N.; Sumerling, M.D.; Finlayson, N.D.C.

    1981-02-01

    A 74 year old man presented with cryptogenic liver cirrhosis and ascites. On /sup 99/Tcsup(m) sulphur colloid scanning he was found to have a filling defect in the right lobe of the liver which disappeared when the liver scan was repeated with /sup 75/Se selenomethionine. This lesion, initially thought to be a hepatoma, proved eventually at post mortem to be a hyperplastic hepatic nodule.

  6. Crystallization kinetics in glassy GexSe100 - x

    OpenAIRE

    Goel, S.; Tripathi, S.K.; Kumar, A

    1990-01-01

    Crystallization kinetics of glassy GexSe100 - x system is studied using isothermal technique, i.e., by studying amorphous to crystalline transformation during isothermal annealing at various temperatures between glass transition and melting temperature. DC conductivity is taken a characteristic quantity to measure the extent of crystallization during crystallization process. To calculate the activation energy of crystallization and the order parameter, the data is fitted to the Avrami's equat...

  7. Superior Gas Sensing Properties of Monolayer PtSe2

    KAUST Repository

    Sajjad, Muhammad

    2016-12-15

    First-principles calculations of the structural and electronic properties of monolayer 1T-PtSe2 with adsorbed (a) NO2, (b) NO, (c) NH3, (d) H2O, (e) CO2, and (f) CO molecules are discussed. The results point to great potential of the material in gas sensor applications. Superior sensitivity is demonstrated by transport calculations using the nonequilibrium Green\\'s function method.

  8. The phonon dispersion of wurtzite CdSe

    Science.gov (United States)

    Widulle, F.; Kramp, S.; Pyka, N. M.; Göbel, A.; Ruf, T.; Debernardi, A.; Lauck, R.; Cardona, M.

    1999-03-01

    We have measured the phonon dispersion of wurtzite CdSe along overlineΓA by inelastic neutron scattering at room temperature. The sample was grown with the very weakly neutron absorbing isotope 116Cd and natural selenium. These experiments extend the picture so far obtained from earlier measurements on 114CdS and deliver more information on the accuracy of theoretical models. The experimental data are compared with ab initio and shell model calculations.

  9. Experimental Conditions: SE17_S09_M01_D02 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available _S09 Spinacia oleracea Solomon Leaf SE17_S09_M01 6.7mg [MassBase ID] MDLC1_36302 SE17_MS1 LC-FT-ICR-MS ESI p...SE17_S09_M01_D02 SE17 Comparison of leaf metabolites among spinach varieties 2 SE17

  10. Experimental Conditions: SE17_S09_M03_D02 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available _S09 Spinacia oleracea Solomon Leaf SE17_S09_M03 6.7mg [MassBase ID] MDLC1_36304 SE17_MS1 LC-FT-ICR-MS ESI p...SE17_S09_M03_D02 SE17 Comparison of leaf metabolites among spinach varieties 2 SE17

  11. Experimental Conditions: SE17_S09_M02_D03 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available _S09 Spinacia oleracea Solomon Leaf SE17_S09_M02 6.7mg [MassBase ID] MDLC1_36303 SE17_MS1 LC-FT-ICR-MS ESI p...SE17_S09_M02_D03 SE17 Comparison of leaf metabolites among spinach varieties 2 SE17

  12. Experimental Conditions: SE17_S09_M03_D01 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available _S09 Spinacia oleracea Solomon Leaf SE17_S09_M03 6.7mg [MassBase ID] MDLC1_36304 SE17_MS1 LC-FT-ICR-MS ESI p...SE17_S09_M03_D01 SE17 Comparison of leaf metabolites among spinach varieties 2 SE17

  13. Experimental Conditions: SE17_S09_M03_D03 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available _S09 Spinacia oleracea Solomon Leaf SE17_S09_M03 6.7mg [MassBase ID] MDLC1_36304 SE17_MS1 LC-FT-ICR-MS ESI p...SE17_S09_M03_D03 SE17 Comparison of leaf metabolites among spinach varieties 2 SE17

  14. Experimental Conditions: SE17_S09_M01_D01 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available _S09 Spinacia oleracea Solomon Leaf SE17_S09_M01 6.7mg [MassBase ID] MDLC1_36302 SE17_MS1 LC-FT-ICR-MS ESI p...SE17_S09_M01_D01 SE17 Comparison of leaf metabolites among spinach varieties 2 SE17

  15. Experimental Conditions: SE17_S09_M01_D03 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available _S09 Spinacia oleracea Solomon Leaf SE17_S09_M01 6.7mg [MassBase ID] MDLC1_36302 SE17_MS1 LC-FT-ICR-MS ESI p...SE17_S09_M01_D03 SE17 Comparison of leaf metabolites among spinach varieties 2 SE17

  16. Experimental Conditions: SE17_S09_M02_D02 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available _S09 Spinacia oleracea Solomon Leaf SE17_S09_M02 6.7mg [MassBase ID] MDLC1_36303 SE17_MS1 LC-FT-ICR-MS ESI p...SE17_S09_M02_D02 SE17 Comparison of leaf metabolites among spinach varieties 2 SE17

  17. Experimental Conditions: SE17_S09_M02_D01 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available _S09 Spinacia oleracea Solomon Leaf SE17_S09_M02 6.7mg [MassBase ID] MDLC1_36303 SE17_MS1 LC-FT-ICR-MS ESI p...SE17_S09_M02_D01 SE17 Comparison of leaf metabolites among spinach varieties 2 SE17

  18. Experimental Conditions: SE3_S01_M03_D03 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE3_S01_M03_D03 SE3 Comparison of fruit metabolites among tomato varieties 1 SE3_S0...1 Solanum lycopersicum Lovely ai fruit SE3_S01_M03 6.7mg [MassBase ID] MDLC1_25528 SE3_MS1 LC-FT-ICR-MS ESI

  19. Experimental Conditions: SE3_S01_M03_D01 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE3_S01_M03_D01 SE3 Comparison of fruit metabolites among tomato varieties 1 SE3_S0...1 Solanum lycopersicum Lovely ai fruit SE3_S01_M03 6.7mg [MassBase ID] MDLC1_25528 SE3_MS1 LC-FT-ICR-MS ESI

  20. Experimental Conditions: SE3_S01_M03_D02 [Metabolonote[Archive

    Lifescience Database Archive (English)

    Full Text Available SE3_S01_M03_D02 SE3 Comparison of fruit metabolites among tomato varieties 1 SE3_S0...1 Solanum lycopersicum Lovely ai fruit SE3_S01_M03 6.7mg [MassBase ID] MDLC1_25528 SE3_MS1 LC-FT-ICR-MS ESI