Simulation of non-Newtonian oil-water core annular flow through return bends
Jiang, Fan; Wang, Ke; Skote, Martin; Wong, Teck Neng; Duan, Fei
2017-07-01
The volume of fluid (VOF) model is used together with the continuum surface force (CSF) model to numerically simulate the non-Newtonian oil-water core annular flow across return bends. A comprehensive study is conducted to generate the profiles of pressure, velocity, volume fraction and wall shear stress for different oil properties, flow directions, and bend geometries. It is revealed that the oil core may adhere to the bend wall under certain operating conditions. Through the analysis of the total pressure gradient and fouling angle, suitable bend geometric parameters are identified for avoiding the risk of fouling.
MASS TRANSFER COEFFICIENTS FOR A NON-NEWTONIAN FLUID AND WATER WITH AND WITHOUT ANTI-FOAM AGENTS
Energy Technology Data Exchange (ETDEWEB)
Leishear, R.
2009-09-09
Mass transfer rates were measured in a large scale system, which consisted of an 8.4 meter tall by 0.76 meter diameter column containing one of three fluids: water with an anti-foam agent, water without an anti-foam agent, and AZ101 simulant, which simulated a non-Newtonian nuclear waste. The testing contributed to the evaluation of large scale mass transfer of hydrogen in nuclear waste tanks. Due to its radioactivity, the waste was chemically simulated, and due to flammability concerns oxygen was used in lieu of hydrogen. Different liquids were used to better understand the mass transfer processes, where each of the fluids was saturated with oxygen, and the oxygen was then removed from solution as air bubbled up, or sparged, through the solution from the bottom of the column. Air sparging was supplied by a single tube which was co-axial to the column, the decrease in oxygen concentration was recorded, and oxygen measurements were then used to determine the mass transfer coefficients to describe the rate of oxygen transfer from solution. Superficial, average, sparging velocities of 2, 5, and 10 mm/second were applied to each of the liquids at three different column fill levels, and mass transfer coefficient test results are presented here for combinations of superficial velocities and fluid levels.
Ilyasov, A. M.; Bulgakova, G. T.
2016-08-01
This paper describes a mathematical model of the main fracture isolation in porous media by water-based mature gels. While modeling injection, water infiltration from the gel pack through fracture walls is taking into account, due to which the polymer concentration changes and the residual water resistance factor changes as a consequence. The salutation predicts velocity and pressure fields of the non-Newtonian incompressible fluid filtration for conditions of a non-deformable formation as well as a gel front trajectory in the fracture. The mathematical model of agent injection into the main fracture is based on the fundamental laws of continuum mechanics conservation describing the flow of non-Newtonian and Newtonian fluids separated by an interface plane in a flat channel with permeable walls. The mathematical model is based on a one-dimensional isothermal approximation, with dynamic parameters pressure and velocity, averaged over the fracture section.
Structural Optimization of Non-Newtonian Rectifiers
DEFF Research Database (Denmark)
Jensen, Kristian Ejlebjærg; Okkels, Fridolin
. In this context it is natural to look for other sources of non-linearity and one possibility is to introduce a non-Newtonian working fluid. Non-Newtonian properties are due to stretching of large particles/molecules in the fluid and this is commonly seen for biological samples in “lab-on-a-chip” systems....... The strength of non-Newtonian effects does not depend on the device size. Furthermore a non-Newtonian working fluid removes symmetry properties such that geometry influence is reintroduced, and indeed non-Newtonian effects have been used in experimentally realized microfluidic rectitifiers[1]. The rectifiers...... optimization, which is a kind of design optimization where nothing is assumed about the topology of the design. We will apply a high-level implementation of topology optimization using the density method in a commercial finite element package[2]. However, the modeling of non-Newtonian fluids remains a major...
Numerical analysis of non-Newtonian rheology effect on hydrocyclone flow field
Directory of Open Access Journals (Sweden)
Lin Yang
2015-03-01
Full Text Available In view of the limitations of the existing Newton fluid effects on the vortex flow mechanism study, numerical analysis of non Newton fluid effects was presented. Using Reynolds stress turbulence model (RSM and mixed multiphase flow model (Mixture of FLUENT (fluid calculation software and combined with the constitutive equation of apparent viscosity of non-Newtonian fluid, the typical non-Newtonian fluid (drilling fluid, polymer flooding sewage and crude oil as medium and Newton flow field (water as medium were compared by quantitative analysis. Based on the research results of water, the effects of non-Newtonian rheology on the key parameters including the combined vortex motion index n and tangential velocity were analyzed. The study shows that: non-Newtonian rheology has a great effect on tangential velocity and n value, and tangential velocity decreases with non-Newtonian increasing. The three kinds of n values (constant segment are: 0.564(water, 0.769(polymer flooding sewage, 0.708(drilling fluid and their variation amplitudes are larger than Newtonian fluid. The same time, non-Newtonian rheology will lead to the phenomenon of turbulent drag reduction in the vortex flow field. Compared with the existing formula calculation results shown, the calculation result of non-Newtonian rheology is most consistent with the simulation result, and the original theory has large deviations. The study provides reference for theory research of non-Newtonian cyclone separation flow field.
Rheology and non-Newtonian fluids
Irgens, Fridtjov
2014-01-01
This book gives a brief but thorough introduction to the fascinating subject of non-Newtonian fluids, their behavior and mechanical properties. After a brief introduction of what characterizes non-Newtonian fluids in Chapter 1 some phenomena characteristic of non-Newtonian fluids are presented in Chapter 2. The basic equations in fluid mechanics are discussed in Chapter 3. Deformation kinematics, the kinematics of shear flows, viscometric flows, and extensional flows are the topics in Chapter 4. Material functions characterizing the behavior of fluids in special flows are defined in Chapter 5. Generalized Newtonian fluids are the most common types of non-Newtonian fluids and are the subject in Chapter 6. Some linearly viscoelastic fluid models are presented in Chapter 7. In Chapter 8 the concept of tensors is utilized and advanced fluid models are introduced. The book is concluded with a variety of 26 problems. Solutions to the problems are ready for instructors.
DiSalvo, Roberto; Deaconu, Stelu; Majumdar, Alok
2006-01-01
One of the goals of this program was to develop the experimental and analytical/computational tools required to predict the flow of non-Newtonian fluids through the various system components of a propulsion system: pipes, valves, pumps etc. To achieve this goal we selected to augment the capabilities of NASA's Generalized Fluid System Simulation Program (GFSSP) software. GFSSP is a general-purpose computer program designed to calculate steady state and transient pressure and flow distributions in a complex fluid network. While the current version of the GFSSP code is able to handle various systems components the implicit assumption in the code is that the fluids in the system are Newtonian. To extend the capability of the code to non-Newtonian fluids, such as silica gelled fuels and oxidizers, modifications to the momentum equations of the code have been performed. We have successfully implemented in GFSSP flow equations for fluids with power law behavior. The implementation of the power law fluid behavior into the GFSSP code depends on knowledge of the two fluid coefficients, n and K. The determination of these parameters for the silica gels used in this program was performed experimentally. The n and K parameters for silica water gels were determined experimentally at CFDRC's Special Projects Laboratory, with a constant shear rate capillary viscometer. Batches of 8:1 (by weight) water-silica gel were mixed using CFDRC s 10-gallon gelled propellant mixer. Prior to testing the gel was allowed to rest in the rheometer tank for at least twelve hours to ensure that the delicate structure of the gel had sufficient time to reform. During the tests silica gel was pressure fed and discharged through stainless steel pipes ranging from 1", to 36", in length and three diameters; 0.0237", 0.032", and 0.047". The data collected in these tests included pressure at tube entrance and volumetric flowrate. From these data the uncorrected shear rate, shear stress, residence time
Geophysical Aspects of Non-Newtonian Fluid Mechanics
Balmforth, N. J.; Craster, R. V.
Non-Newtonian fluid mechanics is a vast subject that has several journals partly, or primarily, dedicated to its investigation (Journal of Non-Newtonian Fluid Mechanics, Rheologica Acta, Journal of Fluid Mechanics, Journal of Rheology, amongst others). It is an area of active research, both for industrial fluid problems and for applications elsewhere, notably geophysically motivated issues such as the flow of lava and ice, mud slides, snow avalanches and debris flows. The main motivati on for this research activity is that, apart from some annoyingly common fluids such as air and water, virtually no fluid is actually Newtonian (that is, having a simple linear relation between stress and strain-rate characterized by a constant viscosity). Several textbooks are useful sources of information; for example, [1-3] are standard texts giving mathematical and engineering perspectives upon the subject. In these lecture notes, Ancey's chapter on rheology (Chap. 3) gives further introduction.
Aspects of non-Newtonian flow and displacement in porous media
Energy Technology Data Exchange (ETDEWEB)
Shah, C.; Yortsos, Y.C.
1993-02-01
The rheology of many heavy oils has been shown to be non-Newtonian, Bingham plastics being one manifestation of heavy oil flow. In EOR applications, non-Newtonian fluids such as low concentration polymer solutions, emulsions, gels etc. are simultaneously injected to increase the viscosity of driving agents that displace oil. Such rheologically complex fluids are used to improve sweep efficiencies, divert displacing fluids and block swept zones. The present study has been undertaken to understand the flow of non-Newtonian fluids through porous media. The work considered involves the numerical (pore network) modeling of both single and multiphase flow of power-law and Bingham plastic fluids in network-like porous media. We consider aspects of both single- and multi-phase flow and displacement. Section 2 describes elementary aspects of non-Newtonian flow and some simple models for porous media. Viscoelastic effects in the flow of non-Newtonian fluids are also discussed. The section includes a brief literature review on non-Newtonian flow in porous media. Section 3 describes single-phase flow.
PKN problem for non-Newtonian fluid
Linkov, Alexander
2012-01-01
The paper presents analytical solution for hydraulic fracture driven by a non-Newtonian fluid and propagating under plane strain conditions in cross sections parallel to the fracture front. Conclusions are drawn on the influence of the fluid properties on the fracture propagation.
The Future of Aerospace Propulsion: Visco-elastic non-Newtonian liquids
Directory of Open Access Journals (Sweden)
Nicole Arockiam
2011-01-01
Full Text Available Aerospace propulsion often involves the spray and combustion of liquids. When a liquid is sprayed, large drops form first, in a process known as primary atomization. Then, each drop breaks up into smaller droplets, in a process known as secondary atomization. This determines final drop sizes, which affect the liquid’s evaporation and mixing rates and ultimately influence combustor efficiency. Little has been published concerning the secondary atomization of visco-elastic non-Newtonian liquids, such as gels. These substances have special potential as aerospace propellants, because they are safer to handle than their Newtonian liquid counterparts, such as water. Additionally, they can be injected at varying rates, allowing for more control than solid propellants. To learn more about the atomization process of these liquids, a liquid drop generator and a high-speed camera were used to create and measure the conditions at which different breakup modes occurred, as well as the time required for the process. These results were compared to experimental and theoretical results for Newtonian liquids. Based on the data, one can conclude that solutions that are more elastic require higher shear forces to break up. In addition, while Newtonian liquids form droplets as they atomize, visco-elastic non-Newtonian solutions form ligaments. As a result, a combustion system utilizing these types of propellants must be capable of generating these forces. It may also be necessary to find a way to transform the ligaments into more spherically-shaped droplets to increase combustion efficiency.
Electrokinetics of non-Newtonian fluids: a review.
Zhao, Cunlu; Yang, Chun
2013-12-01
This work presents a comprehensive review of electrokinetics pertaining to non-Newtonian fluids. The topic covers a broad range of non-Newtonian effects in electrokinetics, including electroosmosis of non-Newtonian fluids, electrophoresis of particles in non-Newtonian fluids, streaming potential effect of non-Newtonian fluids and other related non-Newtonian effects in electrokinetics. Generally, the coupling between non-Newtonian hydrodynamics and electrostatics not only complicates the electrokinetics but also causes the fluid/particle velocity to be nonlinearly dependent on the strength of external electric field and/or the zeta potential. Shear-thinning nature of liquids tends to enhance electrokinetic phenomena, while shear-thickening nature of liquids leads to the reduction of electrokinetic effects. In addition, directions for the future studies are suggested and several theoretical issues in non-Newtonian electrokinetics are highlighted.
Electroosmotic mobilities of non-Newtonian fluids
Zhao, Cunlu
2010-01-01
Owing to frequent processing of biofluids in Lab-on-a-chip microfluidic devices, electroosmotic mobilities of non-Newtonian fluids are investigated numerically. The general Cauchy momentum equation governing the electroosmotic velocity is simplified by incorporation of the Gouy-Chapman solution of the Poisson-Boltzmann equation and the Carreau fluid constitutive model. Then the finite element method for solving the simplified version of Cauchy momentum equation is validated through comparisons with two exact solutions, i.e., Newtonian fluids and power-law fluids. Analyses shows that different from Newtonian fluids with a constant dimensionless electroosmotic mobility of unit one, dimensionless electroosmotic mobilities for non-Newtonian Carreau fluids are dependent on four dimensionless groups, such as dimensionless surface zeta potential , Weissenberg number Wi, fluid power-law exponent n and transitional parameter {\\beta}. It is found out that with increasing and decreasing of n and {\\beta}, electroosmotic ...
Non newtonian annular alloy solidification in mould
Energy Technology Data Exchange (ETDEWEB)
Moraga, Nelson O.; Garrido, Carlos P. [Universidad de La Serena, Departamento de Ingenieria Mecanica, La Serena (Chile); Castillo, Ernesto F. [Universidad de Santiago de Chile, Departamento de Ingenieria Mecanica, Santiago (Chile)
2012-08-15
The annular solidification of an aluminium-silicon alloy in a graphite mould with a geometry consisting of horizontal concentric cylinders is studied numerically. The analysis incorporates the behavior of non-Newtonian, pseudoplastic (n=0.2), Newtonian (n=1), and dilatant (n=1.5) fluids. The fluid mechanics and heat transfer coupled with a transient model of convection diffusion are solved using the finite volume method and the SIMPLE algorithm. Solidification is described in terms of a liquid fraction of a phase change that varies linearly with temperature. The final results make it possible to infer that the fluid dynamics and heat transfer of solidification in an annular geometry are affected by the non-Newtonian nature of the fluid, speeding up the process when the fluid is pseudoplastic. (orig.)
Non-Newtonian mechanics of oscillation centers
Dodin, I. Y.; Fisch, N. J.
2008-10-01
Classical particles oscillating in high-frequency or static fields effectively exhibit a modified rest mass meff which determines the oscillation center motion. Unlike the true mass, meff depends on the field parameters and can be a nonanalytic function of the particle average velocity and the oscillation energy; hence non-Newtonian "metaplasmas" that permit a new type of plasma maser, signal rectification, frequency doubling, and one-way walls.
Huang, Y; Wang, Y L; Wong, T N
2017-08-22
Monodispersity and fast generation are innate advantages of microfluidic droplets. Other than the normally adopted simple Newtonian fluids such as a water/oil emulsion system, fluids with complex rheology, namely, non-Newtonian fluids, which are being widely adopted in industries and bioengineering, have gained increasing research interest on the microscale. However, challenges occur in controlling the dynamic behavior due to their complex properties. In this sense, the AC electric field with merits of fast response and easiness in fulfilling "Lab on a chip" has attracted our attention. We design and fabricate flow-focusing microchannels with non-contact types of electrodes for the investigation. We firstly compare the formation of a non-Newtonian droplet with that of a Newtonian one under an AC electric field and discover that viscoelasticity contributes to the discrepancies significantly. Then we explore the effect of AC electric fields on the filament thinning and droplet formation dynamics of one non-Newtonian fluid which has a similar rheological behavior to bio samples, such as DNA or blood samples. We investigate the dynamics of the thinning process of the non-Newtonian filament under the influence of an AC electric field and implement a systematic exploration of the non-Newtonian droplet generation influenced by parameters such as the flow conditions (flow rate Q, capillary number Ca), fluid property (Weissenberg number Wi), applied voltage (U) and frequency (f) of the AC electric field. We present the dependencies of the flow condition and electric field on the non-Newtonian droplet formation dynamics, and conclude with an operating diagram, taking into consideration all the above-mentioned parameters. Results show that the electric field plays a critical role in controlling the thinning process of the filament and the size of the generated droplet. Furthermore, for the first time, we quantitatively measure the flow field of the non-Newtonian droplet
Inline Ultrasonic Rheometry of a Non-Newtonian Waste Simulant
Energy Technology Data Exchange (ETDEWEB)
Pfund, David M.; Pappas, Richard A.
2004-03-31
This is a discussion of non-invasive determination of the viscosity of a non-Newtonian fluid in laminar pipe flow over the range of shear rates present in the pipe. The procedure requires knowledge of the flow profile in and the pressure drop along the long straight run of pipe. The profile is determined by using a pulsed ultrasonic Doppler velocimeter. This approach is ideal for making non-invasive, real-time measurements for monitoring and control. Rheograms of a shear thinning, thixotropic gel which is often used as a Hanford waste simulant are presented. The operating parameters and limitations of the ultrasound based instrument will be discussed. The component parts of the instrument have been packaged into a unit for field use. The presentation also discusses the features and engineering optimizations done to enhance field usability of the instrument.
Air Sparging for Mixing Non-Newtonian Slurries
Energy Technology Data Exchange (ETDEWEB)
Bamberger, Judith A.; Enderlin, Carl W.; Tzemos, Spyridon
2010-01-01
The mechanics of air sparger systems have been primarily investigated for aqueous-based Newtonian fluids. Tilton et al. (1982) [1] describes the fluid mechanics of air sparging systems in non-Newtonian fluids as having two primary flow regions. A center region surrounding the sparger, referred to as the region of bubbles (ROB), contains upward flow due to the buoyant driving force of the rising bubbles. In an annular region, outside the ROB, referred to as the zone of influence (ZOI), the fluid flow is reversed and is opposed to the direction of bubble rise. Outside the ZOI the fluid is unaffected by the air sparger system. The flow regime in the ROB is often turbulent, and the flow regime in the ZOI is laminar; the flow regime outside the ZOI is quiescent. Tests conducted with shear thinning non-Newtonian fluid in a 34-in. diameter tank showed that the ROB forms an approximately inverted cone that is the envelop of the bubble trajectories. The depth to which the air bubbles reach below the sparger nozzle is a linear function of the air-flow rate. The recirculation time through the ZOI was found to vary proportionally with the inverse square of the sparging air-flow rate. Visual observations of the ROB were made in both water and Carbopol®. The bubbles released from the sparge tube in Carbopol® were larger than those in water
Numerical Modelling of Non-Newtonian Fluid in a Rotational Cross-Flow MBR
DEFF Research Database (Denmark)
Bentzen, Thomas Ruby; Ratkovich, Nicolas Rios; Rasmussen, Michael R.
2011-01-01
. Validation of the CFD model was made against LDA tangential velocity measurements (error less than 8 %) using water a fluid. The shear stress over the membrane surface was inferred from the CFD simulations for water. However, activated sludge is a non-Newtonian liquid, for which the CFD model was modified...... incorporating the non-Newtonian behaviour of activated sludge. Shear stress and area-weighted average shear stress relationships were made giving error less that 8 % compared to the CFD results. An empirical relationship for the area-weighted average shear stress was developed for water and activated sludge...
Effect of a Non-Newtonian Load on Signature S2 for Quartz Crystal Microbalance Measurements
Directory of Open Access Journals (Sweden)
Jae-Hyeok Choi
2014-01-01
Full Text Available The quartz crystal microbalance (QCM is increasingly used for monitoring the interfacial interaction between surfaces and macromolecules such as biomaterials, polymers, and metals. Recent QCM applications deal with several types of liquids with various viscous macromolecule compounds, which behave differently from Newtonian liquids. To properly monitor such interactions, it is crucial to understand the influence of the non-Newtonian fluid on the QCM measurement response. As a quantitative indicator of non-Newtonian behavior, we used the quartz resonator signature, S2, of the QCM measurement response, which has a consistent value for Newtonian fluids. We then modified De Kee’s non-Newtonian three-parameter model to apply it to our prediction of S2 values for non-Newtonian liquids. As a model, we chose polyethylene glycol (PEG400 with the titration of its volume concentration in deionized water. As the volume concentration of PEG400 increased, the S2 value decreased, confirming that the modified De Kee’s three-parameter model can predict the change in S2 value. Collectively, the findings presented herein enable the application of the quartz resonator signature, S2, to verify QCM measurement analysis in relation to a wide range of experimental subjects that may exhibit non-Newtonian behavior, including polymers and biomaterials.
Applying Tiab’s direct synthesis technique to dilatant non-Newtonian/Newtonian fluids
Directory of Open Access Journals (Sweden)
Javier Andrés Martínez
2011-08-01
Full Text Available Non-Newtonian fluids, such as polymer solutions, have been used by the oil industry for many years as fracturing agents and drilling mud. These solutions, which normally include thickened water and jelled fluids, are injected into the formation to enhanced oil recovery by improving sweep efficiency. It is worth noting that some heavy oils behave non-Newtonianly. Non-Newtonian fluids do not have direct proportionality between applied shear stress and shear rate and viscosity varies with shear rate depending on whether the fluid is either pseudoplastic or dilatant. Viscosity decreases as shear rate increases for the former whilst the reverse takes place for dilatants. Mathematical models of conventional fluids thus fail when applied to non-Newtonian fluids. The pressure derivative curve is introduced in this descriptive work for a dilatant fluid and its pattern was observed. Tiab’s direct synthesis (TDS methodology was used as a tool for interpreting pressure transient data to estimate effective permeability, skin factors and non-Newtonian bank radius. The methodology was successfully verified by its application to synthetic examples. Also, comparing it to pseudoplastic behavior, it was found that the radial flow regime in the Newtonian zone of dilatant fluids took longer to form regarding both the flow behavior index and consistency factor.
Non-Newtonian Properties of Relativistic Fluids
Koide, Tomoi
2010-01-01
We show that relativistic fluids behave as non-Newtonian fluids. First, we discuss the problem of acausal propagation in the diffusion equation and introduce the modified Maxwell-Cattaneo-Vernotte (MCV) equation. By using the modified MCV equation, we obtain the causal dissipative relativistic (CDR) fluid dynamics, where unphysical propagation with infinite velocity does not exist. We further show that the problems of the violation of causality and instability are intimately related, and the relativistic Navier-Stokes equation is inadequate as the theory of relativistic fluids. Finally, the new microscopic formula to calculate the transport coefficients of the CDR fluid dynamics is discussed. The result of the microscopic formula is consistent with that of the Boltzmann equation, i.e., Grad's moment method.
Structural Optimization of non-Newtonian Microfluidics
DEFF Research Database (Denmark)
Jensen, Kristian Ejlebjærg
2013-01-01
Many of the biological fluids analyzed in Lab-on-a-Chip systems contain elastic components, which gives the fluids elastic character. Such fluids are said to be non-Newtonian or, more precisely, viscoelastic. They can give rise to exotic effects on the macroscale, which are never seen for fluids...... with components relying on viscoelastic effects, but the non-intuitive nature of these fluids complicates the design process. This thesis combines the method of topology optimization with differential constitutive equations, which govern the flow of viscoelastic fluids. The optimization method iteratively...... experimentally, and compared the results with the established hyperbolic designs. We found superior performance in the parameter regime of the optimization as well as similar optimal performance [P3]. The cross-slot geometry is known to exhibit bistability for viscoelastic fluids. We studied this geometry...
Hachmon, Guy; Mamet, Noam; Sasson, Sapir; Barkai, Tal; Hadar, Nomi; Abu-Horowitz, Almogit; Bachelet, Ido
2016-01-01
New types of robots inspired by biological principles of assembly, locomotion, and behavior have been recently described. In this work we explored the concept of robots that are based on more fundamental physical phenomena, such as fluid dynamics, and their potential capabilities. We report a robot made entirely of non-Newtonian fluid, driven by shear strains created by spatial patterns of audio waves. We demonstrate various robotic primitives such as locomotion and transport of metallic loads-up to 6-fold heavier than the robot itself-between points on a surface, splitting and merging, shapeshifting, percolation through gratings, and counting to 3. We also utilized interactions between multiple robots carrying chemical loads to drive a bulk chemical synthesis reaction. Free of constraints such as skin or obligatory structural integrity, fluid robots represent a radically different design that could adapt more easily to unfamiliar, hostile, or chaotic environments and carry out tasks that neither living organisms nor conventional machines are capable of.
The Rayleigh-Taylor instability of Newtonian and non-Newtonian fluids
Doludenko, A. N.; Fortova, S. V.; Son, E. E.
2016-10-01
Along with Newtonian fluids (for example, water), fluids with non-Newtonian rheology are widespread in nature and industry. The characteristic feature of a non-Newtonian fluid is the non-linear dependence between the shear stress and shear rate tensors. The form of this relation defines the types of non-Newtonian behavior: viscoplastic, pseudoplastic, dilatant and viscoelastic. The present work is devoted to the study of the Rayleigh-Taylor instability in pseudoplastic fluids. The main aim of the work is to undertake a direct three-dimensional numerical simulation of the mixing of two media with various rheologies and obtain the width of the mixing layer and the kinetic energy spectra, depending on the basic properties of the shear thinning liquids and the Atwood number. A theoretical study is carried out on the basis of the Navier-Stokes equation system for weakly compressible media.
STUDIES OF THE REDUCTION OF PIPE FRICTION WITH THE NON-NEWTONIAN ADDITIVE CMC,
water can remarkably reduce the frictional resistance to flow. The material sodium carboxymethylcellulose was added to fresh water and subjected to...pipe friction tests under a wide range of shear rates, additive concentration, and temperature conditions. The frictional data are characterized by application of the power law expression for non-Newtonian fluids. (Author)
Dean vortex membrane microfiltration non-Newtonian viscosity effects
Schutyser, M.A.I.; Belfort, G.
2002-01-01
Many industrial feeds behave as non-Newtonian fluids, and little understanding exists as to their influence on cross-flow microfiltration (CMF) performance. The viscosity effects of a model non-Newtonian shear-thickening fluid were investigated in CMF with and without suspended silica particles in t
Dean vortex membrane microfiltration non-Newtonian viscosity effects
Schutyser, M.A.I.; Belfort, G.
2002-01-01
Many industrial feeds behave as non-Newtonian fluids, and little understanding exists as to their influence on cross-flow microfiltration (CMF) performance. The viscosity effects of a model non-Newtonian shear-thickening fluid were investigated in CMF with and without suspended silica particles in
Spreading of Non-Newtonian and Newtonian Fluids on a Solid Substrate under Pressure
Dutta Choudhury, Moutushi; Chandra, Subrata; Nag, Soma; Das, Shantanu; Tarafdar, Sujata
2011-09-01
Strongly non-Newtonian fluids namely, aqueous gels of starch, are shown to exhibit visco-elastic behavior, when subjected to a load. We study arrowroot and potato starch gels. When a droplet of the fluid is sandwiched between two glass plates and compressed, the area of contact between the fluid and plates increases in an oscillatory manner. This is unlike Newtonian fluids, where the area increases monotonically in a similar situation. The periphery moreover, develops an instability, which looks similar to Saffman Taylor fingers. This is not normally seen under compression. The loading history is also found to affect the manner of spreading. We attempt to describe the non-Newtonian nature of the fluid through a visco-elastic model incorporating generalized calculus. This is shown to reproduce qualitatively the oscillatory variation in the surface strain.
Spreading of Non-Newtonian and Newtonian Fluids on a Solid Substrate under Pressure
Energy Technology Data Exchange (ETDEWEB)
Choudhury, Moutushi Dutta; Chandra, Subrata; Nag, Soma; Tarafdar, Sujata [Condensed Matter Physics Research Centre, Physics Department, Jadavpur University, Kolkata 700032 (India); Das, Shantanu, E-mail: mou15july@gmail.com [Reactor Control Division, Bhabha Atomic Research Center, Trombay, Mumbai 400085 (India)
2011-09-15
Strongly non-Newtonian fluids namely, aqueous gels of starch, are shown to exhibit visco-elastic behavior, when subjected to a load. We study arrowroot and potato starch gels. When a droplet of the fluid is sandwiched between two glass plates and compressed, the area of contact between the fluid and plates increases in an oscillatory manner. This is unlike Newtonian fluids, where the area increases monotonically in a similar situation. The periphery moreover, develops an instability, which looks similar to Saffman Taylor fingers. This is not normally seen under compression. The loading history is also found to affect the manner of spreading. We attempt to describe the non-Newtonian nature of the fluid through a visco-elastic model incorporating generalized calculus. This is shown to reproduce qualitatively the oscillatory variation in the surface strain.
Coupling electrokinetics and rheology: Electrophoresis in non-Newtonian fluids.
Khair, Aditya S; Posluszny, Denise E; Walker, Lynn M
2012-01-01
We present a theoretical scheme to calculate the electrophoretic motion of charged colloidal particles immersed in complex (non-Newtonian) fluids possessing shear-rate-dependent viscosities. We demonstrate that this non-Newtonian rheology leads to an explicit shape and size dependence of the electrophoretic velocity of a uniformly charged particle in the thin-Debye-layer regime, in contrast to electrophoresis in Newtonian fluids. This dependence is caused by non-Newtonian stresses in the bulk (electroneutral) fluid outside the Debye layer, whose magnitude is naturally characterized in an electrophoretic Deborah number.
Non-Newtonian Aspects of Artificial Intelligence
Zak, Michail
2016-05-01
The challenge of this work is to connect physics with the concept of intelligence. By intelligence we understand a capability to move from disorder to order without external resources, i.e., in violation of the second law of thermodynamics. The objective is to find such a mathematical object described by ODE that possesses such a capability. The proposed approach is based upon modification of the Madelung version of the Schrodinger equation by replacing the force following from quantum potential with non-conservative forces that link to the concept of information. A mathematical formalism suggests that a hypothetical intelligent particle, besides the capability to move against the second law of thermodynamics, acquires such properties like self-image, self-awareness, self-supervision, etc. that are typical for Livings. However since this particle being a quantum-classical hybrid acquires non-Newtonian and non-quantum properties, it does not belong to the physics matter as we know it: the modern physics should be complemented with the concept of the information force that represents a bridge to intelligent particle. As a follow-up of the proposed concept, the following question is addressed: can artificial intelligence (AI) system composed only of physical components compete with a human? The answer is proven to be negative if the AI system is based only on simulations, and positive if digital devices are included. It has been demonstrated that there exists such a quantum neural net that performs simulations combined with digital punctuations. The universality of this quantum-classical hybrid is in capability to violate the second law of thermodynamics by moving from disorder to order without external resources. This advanced capability is illustrated by examples. In conclusion, a mathematical machinery of the perception that is the fundamental part of a cognition process as well as intelligence is introduced and discussed.
Effect of non-Newtonian fluid properties on bovine sperm motility.
Hyakutake, Toru; Suzuki, Hiroki; Yamamoto, Satoru
2015-09-18
The swimming process by which mammal spermatozoa progress towards an egg within the reproductive organs is important in achieving successful internal fertilization. The viscosity of oviductal mucus is more than two orders of magnitude greater than that of water, and oviductal mucus also has non-Newtonian properties. In this study, we experimentally observed sperm motion in fluids with various fluid rheological properties and investigated the influence of varying the viscosity and whether the fluid was Newtonian or non-Newtonian on the sperm motility. We selected polyvinylpyrrolidone and methylcellulose as solutes to create solutions with different rheological properties. We used the semen of Japanese cattle and investigated the following parameters: the sperm velocity, the straight-line velocity and the amplitude from the trajectory, and the beat frequency from the fragellar movement. In a Newtonian fluid environment, as the viscosity increased, the motility of the sperm decreased. However, in a non-Newtonian fluid, the straight-line velocity and beat frequency were significantly higher than in a Newtonian fluid with comparable viscosity. As a result, the linearity of the sperm movement increased. Additionally, increasing the viscosity brought about large changes in the sperm flagellar shape. At low viscosities, the entire flagellum moved in a curved flapping motion, whereas in the high-viscosity, only the tip of the flagellum flapped. These results suggest that the bovine sperm has evolved to swim toward the egg as quickly as possible in the actual oviduct fluid, which is a high-viscosity non-Newtonian fluid.
Stability Analysis of Non-Newtonian Rimming Flow
Fomin, Sergei; Haine, Peter
2015-01-01
The rimming flow of a viscoelastic thin film inside a rotating horizontal cylinder is studied theoretically. Attention is given to the onset of non-Newtonian free-surface instability in creeping flow. This non-inertial instability has been observed in experiments, but current theoretical models of Newtonian fluids can neither describe its origin nor explain its onset. This study examines two models of non Newtonian fluids to see if the experimentally observed instability can be predicted analytically. The non-Newtonian viscosity and elastic properties of the fluid are described by the Generalized Newtonian Fluid (GNF) and Second Order Viscoelastic Fluid (SOVF) constitutive models, respectively. With linear stability analysis, it is found that, analogously to the Newtonian fluid, rimming flow of viscous non-Newtonian fluids (modeled by GNF) is neutrally stable. However, the viscoelastic properties of the fluid (modeled by SOVF) are found to contribute to the flow destabilization. The instability is shown to in...
Experiments on densely-loaded non-Newtonian slurries in laminar and turbulent pipe flows
Park, J. T.; Mannheimer, R. J.; Grimley, T. A.; Morrow, T. B.
1988-05-01
An experimental description of the flow structure of non-Newtonian slurries in the laminar, transitional, and full turbulent pipe flow regimes is the primary objective of this research. Measurements include rheological characterization of the fluid and local fluid velocity measurements with a Laser Doppler Velocimeter (LDV). Optical access to the flow is gained through a test section and model slurry which are both transparent. The model slurry is formulated from silica gel particles and hydrocarbon liquid mixture whose indices of refraction are matched so that light is not scattered from the particles. Experiments are being conducted in a large-scale pipe slurry. Flow measurements including turbulence quantities such as Reynolds stress were measured with a two-component two-color LDV. The present research indicates that non-Newtonian slurries are possible with concentrations of a few percent by weight of small particles whose sizes are two microns or less. A non-Newtonian slurry from small particles could maintain large particles (one millimeter size) at high concentrations in suspension almost indefinitely. Such a slurry would prevent particle fallout and its associated problems.
Physiological non-Newtonian blood flow through single stenosed artery
Mamun, Khairuzzaman; Rahman, Mohammad Matiur; Akhter, Most. Nasrin; Ali, Mohammad
2016-07-01
A numerical simulation to investigate the Non-Newtonian modelling effects on physiological flows in a three dimensional idealized artery with a single stenosis of 85% severity. The wall vessel is considered to be rigid. Oscillatory physiological and parabolic velocity profile has been imposed for inlet boundary condition. Where the physiological waveform is performed using a Fourier series with sixteen harmonics. The investigation has a Reynolds number range of 96 to 800. Low Reynolds number k - ω model is used as governing equation. The investigation has been carried out to characterize two Non-Newtonian constitutive equations of blood, namely, (i) Carreau and (ii) Cross models. The Newtonian model has also been investigated to study the physics of fluid. The results of Newtonian model are compared with the Non-Newtonian models. The numerical results are presented in terms of pressure, wall shear stress distributions and the streamlines contours. At early systole pressure differences between Newtonian and Non-Newtonian models are observed at pre-stenotic, throat and immediately after throat regions. In the case of wall shear stress, some differences between Newtonian and Non-Newtonian models are observed when the flows are minimum such as at early systole or diastole.
Dynamic viscosity measurement in non-Newtonian graphite nanofluids.
Duan, Fei; Wong, Ting Foong; Crivoi, Alexandru
2012-07-02
: The effective dynamic viscosity was measured in the graphite water-based nanofluids. The shear thinning non-Newtonian behavior is observed in the measurement. On the basis of the best fitting of the experimental data, the viscosity at zero shear rate or at infinite shear rate is determined for each of the fluids. It is found that increases of the particle volume concentration and the holding time period of the nanofluids result in an enhancement of the effective dynamic viscosity. The maximum enhancement of the effective dynamic viscosity at infinite rate of shear is more than 24 times in the nanofluids held for 3 days with the volume concentration of 4% in comparison with the base fluid. A transmission electron microscope is applied to reveal the morphology of aggregated nanoparticles qualitatively. The large and irregular aggregation of the particles is found in the 3-day fluids in the drying samples. The Raman spectra are extended to characterize the D and G peaks of the graphite structure in the nanofluids. The increasing intensity of the D peak indicates the nanoparticle aggregation growing with the higher concentration and the longer holding time of the nanofluids. The experimental results suggest that the increase on effective dynamic viscosity of nanofluids is related to the graphite nanoparticle aggregation in the fluids.
Smart Fluids in Hydrology: Use of Non-Newtonian Fluids for Pore Structure Characterization
Abou Najm, M. R.; Atallah, N. M.; Selker, J. S.; Roques, C.; Stewart, R. D.; Rupp, D. E.; Saad, G.; El-Fadel, M.
2015-12-01
Classic porous media characterization relies on typical infiltration experiments with Newtonian fluids (i.e., water) to estimate hydraulic conductivity. However, such experiments are generally not able to discern important characteristics such as pore size distribution or pore structure. We show that introducing non-Newtonian fluids provides additional unique flow signatures that can be used for improved pore structure characterization while still representing the functional hydraulic behavior of real porous media. We present a new method for experimentally estimating the pore structure of porous media using a combination of Newtonian and non-Newtonian fluids. The proposed method transforms results of N infiltration experiments using water and N-1 non-Newtonian solutions into a system of equations that yields N representative radii (Ri) and their corresponding percent contribution to flow (wi). This method allows for estimating the soil retention curve using only saturated experiments. Experimental and numerical validation comparing the functional flow behavior of different soils to their modeled flow with N representative radii revealed the ability of the proposed method to represent the water retention and infiltration behavior of real soils. The experimental results showed the ability of such fluids to outsmart Newtonian fluids and infer pore size distribution and unsaturated behavior using simple saturated experiments. Specifically, we demonstrate using synthetic porous media that the use of different non-Newtonian fluids enables the definition of the radii and corresponding percent contribution to flow of multiple representative pores, thus improving the ability of pore-scale models to mimic the functional behavior of real porous media in terms of flow and porosity. The results advance the knowledge towards conceptualizing the complexity of porous media and can potentially impact applications in fields like irrigation efficiencies, vadose zone hydrology, soil
Perrin, Christian L; Tardy, Philippe M J; Sorbie, Ken S; Crawshaw, John C
2006-03-15
The in situ rheology of polymeric solutions has been studied experimentally in etched silicon micromodels which are idealizations of porous media. The rectangular channels in these etched networks have dimensions typical of pore sizes in sandstone rocks. Pressure drop/flow rate relations have been measured for water and non-Newtonian hydrolyzed-polyacrylamide (HPAM) solutions in both individual straight rectangular capillaries and in networks of such capillaries. Results from these experiments have been analyzed using pore-scale network modeling incorporating the non-Newtonian fluid mechanics of a Carreau fluid. Quantitative agreement is seen between the experiments and the network calculations in the Newtonian and shear-thinning flow regions demonstrating that the 'shift factor,'alpha, can be calculated a priori. Shear-thickening behavior was observed at higher flow rates in the micromodel experiments as a result of elastic effects becoming important and this remains to be incorporated in the network model.
Non-Newtonian Viscosity Modeling of Crude Oils—Comparison Among Models
Ramírez-González, Patsy V.; Aguayo, Juan Pablo; Quiñones-Cisneros, Sergio E.; Deiters, Ulrich K.
2009-04-01
The presence of precipitated wax or even just low temperatures may induce non-Newtonian rheological behavior in crude oils. Such behavior can be found at operating conditions, for instance, in reservoirs at deep-water conditions. Therefore, reliable rheological models for crude oils applicable over the wide range of conditions the fluid may encounter are essential for a large number of oil technology applications. Such models must also be composition dependent, as many applications require predicting the rheological behavior of the fluid under strong compositional changes, e.g., recovery applications such as vapor extraction (VAPEX) processes or blending of fluids for improved rheological characteristics for piping, among many other applications. In this study, a comparative analysis between some published models applicable to the description of the non-Newtonian behavior of crude oils is carried out. Emphasis is placed on the stability of the model predictions within the wide range of conditions that may be encountered.
The effect of the expansion ratio on a turbulent non-Newtonian recirculating flow
Energy Technology Data Exchange (ETDEWEB)
Pereira, A.S. [Departamento de Engenharia Quimica Instituto Superior de Engenharia do Porto (Portugal); Pinho, F.T. [Centro de Estudos de Fenomenos de Transporte, DEMEGI, Faculdade de Engenharia, Universidade do Porto (Portugal)
2002-04-01
Measurements of the mean and turbulent flow characteristics of shear-thinning moderately elastic 0.1% and 0.2% xanthan gum aqueous solutions were carried out in a sudden expansion having a diameter ratio of 2. The inlet flow was turbulent and fully developed, and the results were compared with data for water in the same geometry and with previous published Newtonian and non-Newtonian data in a smaller expansion of diameter ratio equal to 1.538. An increase in expansion ratio led to an increase in the recirculation length and in the axial normal Reynolds stress at identical normalised locations, but the difference between Newtonian and non-Newtonian characteristics was less intense than in the smaller expansion. An extensive comparison of mean and turbulent flow characteristics was carried out in order to understand the variation of flow features. (orig.)
The Inveterate Tinkerer: 5. Experiments with Non-Newtonian Fluids
Indian Academy of Sciences (India)
Chirag kalelkar
2017-07-01
In this series of articles, the authors discuss various phenomenain fluid dynamics, which may be investigated via tabletopexperiments using low-cost or home-made instruments.The fifth article in this series is about some fascinating experimentswith non-Newtonian fluids.
Pressure Drop of Non-Newtonian Liquid Flow Through Elbows
Institute of Scientific and Technical Information of China (English)
无
2000-01-01
Experimental data on the pressure drop across different types of elbow for non-Newtonian pseudoplastic liquid flow in laminar condition have been presented. A generalized correlation has been developed for predicting the frictional pressure drop across the elbows in the horizontal plane.
Numerical Simulation of Bubble Evolution in Non-Newtonian Fluid
Institute of Scientific and Technical Information of China (English)
唐亦农; 陈耀松; 陈文芳
1994-01-01
In this paper the bubble issuing from an orifice at the bottom of the boundary evolution in a finite Non-Newtonian fluid(such as Maxwell fluid,Carreu fluid)is numerically simulated The effects of the rheological behavior,physical parameters and circumstantial conditions are discussed in detail
Flow Curve Determination for Non-Newtonian Fluids.
Tjahjadi, Mahari; Gupta, Santosh K.
1986-01-01
Describes an experimental program to examine flow curve determination for non-Newtonian fluids. Includes apparatus used (a modification of Walawender and Chen's set-up, but using a 50cc buret connected to a glass capillary through a Tygon tube), theoretical information, procedures, and typical results obtained. (JN)
On preconditioning incompressible non-Newtonian flow problems
He, X.; Neytcheva, M.; Vuik, C.
2013-01-01
This paper deals with fast and reliable numerical solution methods for the incompressible non-Newtonian Navier-Stokes equations. To handle the nonlinearity of the governing equations, the Picard and Newton methods are used to linearize these coupled partial differential equations. For space discreti
Inelastic non-Newtonian flow over heterogeneously slippery surfaces
Haase, A. Sander; Wood, Jeffery A.; Sprakel, Lisette M.J.; Lammertink, Rob G.H.
2017-01-01
In this study, we investigated inelastic non-Newtonian fluid flow over heterogeneously slippery surfaces. First, we simulated the flow of aqueous xanthan gum solutions over a bubble mattress, which is a superhydrophobic surface consisting of transversely positioned no-slip walls and no-shear gas bub
Increasing heat transfer of non-Newtonian nanofluid in rectangular microchannel with triangular ribs
Shamsi, Mohammad Reza; Akbari, Omid Ali; Marzban, Ali; Toghraie, Davood; Mashayekhi, Ramin
2017-09-01
In this study, computational fluid dynamics and the laminar flow of the non-Newtonian fluid have been numerically studied. The cooling fluid includes water and 0.5 wt% Carboxy methyl cellulose (CMC) making the non-Newtonian fluid. In order to make the best of non-Newtonian nanofluid in this simulation, solid nanoparticles of Aluminum Oxide have been added to the non-Newtonian fluid in volume fractions of 0-2% with diameters of 25, 45 and 100 nm. The supposed microchannel is rectangular and two-dimensional in Cartesian coordination. The power law has been used to speculate the dynamic viscosity of the cooling nanofluid. The field of numerical solution is simulated in the Reynolds number range of 5 ribs with angle of attacks of 30°, 45° and 60° is studied on flow parameters and heat transfer due to the fluid flow. The results show that an increase in the volume fraction of nanoparticles as well as the use for nanoparticles with smaller diameters lead to greater heat transfer. Among all the studied forms, the triangular rib from with an angle of attack 30° has the biggest Nusselt number and the smallest pressure drop along the microchannel. Also, an increase in the angle of attack and as a result of a sudden contact between the fluid and the ribs and also a reduction in the coflowing length (length of the rib) cause a cut in heat transfer by the fluid in farther parts from the solid wall (tip of the rib).
Modeling and prediction of non-Newtonian viscosity of crude oils
Energy Technology Data Exchange (ETDEWEB)
Ramirez-Gonzalez, P.V. [Univ. Nacional Autonoma de Mexico (Mexico). Dept. de Ingenieria Quimica; Quinones-Cisneros, S.E.; Manero, O. [Univ. Nacional Autonoma de Mexico (Mexico). Dept. de Reologia, Inst. de Investigaciones en Materiales; Creek, J. [Chevron Energy Technology Co., Houston, TX (United States); Deiters, U.K. [Cologne Univ., Cologne (Germany). Inst. of Physical Chemistry
2008-07-01
Non-Newtonian rheological behaviour in crude oils can be induced by the presence of precipitated wax in reservoir fluids or by low ambient temperatures in heavy oils. This type of behaviour exists at low temperature operating conditions in deep-water production, or in the case of vapor extraction (VAPEX) processes of heavy oils involving strong compositional related changes to the already non-Newtonian viscosity of the oil. Reliable rheological models are needed for crude oils over the wide range of conditions that the fluid may encounter. The models should be of a compositional nature because the rheological behaviour of the fluid must be predicted in many applications, including VAPEX processes or fluid blending for piping. This study compared some published models that describe the non-Newtonian behaviour of crude oils. The emphasis was on the stability of the models predictions within the wide range of conditions that may be encountered. The study also evaluated the prediction potential of the analyzed models.
CFD simulation of non-Newtonian fluid flow in anaerobic digesters.
Wu, Binxin; Chen, Shulin
2008-02-15
A general mathematical model that predicts the flow fields in a mixed-flow anaerobic digester was developed. In this model, the liquid manure was assumed to be a non-Newtonian fluid, and the flow governed by the continuity, momentum, and k-epsilon standard turbulence equations, and non-Newtonian power law model. The commercial computational fluid dynamics (CFD) software, Fluent, was applied to simulate the flow fields of lab-scale, scale-up, and pilot-scale anaerobic digesters. The simulation results were validated against the experimental data from literature. The flow patterns were qualitatively compared for Newtonian and non-Newtonian fluids flow in a lab-scale digester. Numerical simulations were performed to predict the flow fields in scale-up and pilot-scale anaerobic digesters with different water pump power inputs and different total solid concentration (TS) in the liquid manure. The optimal power inputs were determined for the pilot-scale anaerobic digester. Some measures for reducing dead and low velocity zones were proposed based upon the CFD simulation results.
Journal Bearings Lubrication Aspect Analysis Using Non-Newtonian Fluids
Directory of Open Access Journals (Sweden)
Abdessamed Nessil
2013-01-01
Full Text Available The aim of this work is related to an analysis of journal bearings lubrication using non-Newtonian fluids which are described by a power-law model. The performance characteristics of the journal bearings are determined for various values of the non-Newtonian power-law index “” which is equal to: 0.9, 1, and 1.1. Obtained numerical results show that for the dilatant fluids (, the load-carrying capacity, the pressure, the temperature, and the frictional force increased while for the pseudo-plastic fluids ( they decreased. The influence of the thermal effects on these characteristics is important at higher values of the flow behavior index “.” Obtained results are compared to those obtained by others. Good agreement is observed between the different results.
Verification of vertically rotating flume using non-newtonian fluids
Huizinga, R.J.
1996-01-01
Three tests on non-Newtonian fluids were used to verify the use of a vertically rotating flume (VRF) for the study of the rheological properties of debris flow. The VRF is described and a procedure for the analysis of results of tests made with the VRF is presented. The major advantages of the VRF are a flow field consistent with that found in nature, a large particle-diameter threshold, inexpensive operation, and verification using several different materials; the major limitations are a lack of temperature control and a certain error incurred from the use of the Bingham plastic model to describe a more complex phenomenon. Because the VRF has been verified with non-Newtonian fluids as well as Newtonian fluids, it can be used to measure the rheological properties of coarse-grained debris-flow materials.
Non--Newtonian gravity and coherence properties of light
Camacho, A
2001-01-01
In this work the possibility of detecting a non--Newtonian contribution to the gravitational potential by means of its effects upon the first and second--order coherence properties of light is analyzed. It will be proved that, in principle, the effects of a fifth force upon the correlation functions of electromagnetic radiation could be used to detect the existence of new forces. Some constraints upon the experimental parameters will also be deduced.
Non-Newtonian ink transfer in gravure-offset printing
Energy Technology Data Exchange (ETDEWEB)
Ghadiri, Fatemeh; Ahmed, Dewan Hasan [Department of Mechanical Engineering, KAIST, 291 Daehak-ro, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Sung, Hyung Jin, E-mail: hjsung@kaist.ac.k [Department of Mechanical Engineering, KAIST, 291 Daehak-ro, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Shirani, Ebrahim [Department of Mechanical Engineering, Isfahan University of Technology, 841568311, Isfahan (Iran, Islamic Republic of)
2011-02-15
The inks used in gravure-offset printing are non-Newtonian fluids with higher viscosities and lower surface tensions than Newtonian fluids. This paper examines the transfer of a non-Newtonian ink between a flat plate and a groove when the plate is moved upward with a constant velocity while the groove is held fixed. Numerical simulations were carried out with the Carreau model to explore the behavior of this non-Newtonian ink in gravure-offset printing. The volume of fluid (VOF) method was implemented to capture the interface during the ink transfer process. The effects of varying the contact angle of the ink on the flat plate and groove walls and geometrical parameters such as the groove angle and the groove depth on the breakup time of the liquid filament that forms between the plate and the groove and the ink transfer ratio were determined. Our results indicate that increasing the groove contact angle and decreasing the flat plate contact angle enhance the ink transfer ratio and the breakup time. However, increasing the groove depth and the groove angle decreases the transfer ratio and the breakup time. By optimizing these parameters, it is possible to achieve an ink transfer from the groove to the flat plate of approximately 92%. Moreover, the initial width and the vertical velocity of the neck of the ink filament have significant influences on the ink transfer ratio and the breakup time.
Influence of Non-Newtonian rheology on magma degassing
Divoux, Thibaut; Ripepe, Maurizio; Géminard, Jean-Christophe
2011-01-01
Many volcanoes exhibit temporal changes in their degassing process, from rapid gas puffing to lava fountaining and long-lasting quiescent passive degassing periods. This range of behaviors has been explained in terms of changes in gas flux and/or magma input rate. We report here a simple laboratory experiment which shows that the non- Newtonian rheology of magma can be responsible, alone, for such intriguing behavior, even in a stationary gas flux regime. We inject a constant gas flow-rate Q at the bottom of a non-Newtonian fluid column, and demonstrate the existence of a critical flow rate Q* above which the system spontaneously alternates between a bubbling and a channeling regime, where a gas channel crosses the entire fluid column. The threshold Q* depends on the fluid rheological properties which are controlled, in particular, by the gas volume fraction (or void fraction) {\\phi}. When {\\phi} increases, Q* decreases and the degassing regime changes. Non-Newtonian properties of magma might therefore play a...
Akbari, Omid Ali; Toghraie, Davood; Karimipour, Arash; Marzban, Ali; Ahmadi, Gholam Reza
2017-02-01
In this investigation, the behavior of non-Newtonian nanofluid hydrodynamic and heat transfer are simulated. In this study, we numerically simulated a laminar forced non-Newtonian nanofluid flow containing a 0.5 wt% carboxy methyl cellulose (CMC) solutionin water as the base fluid with alumina at volume fractions of 0.5 and 1.5 as the solid nanoparticle. Numerical solution was modelled in Cartesian coordinate system in a two-dimensional microchannel in Reynolds number range of 10≤Re≤1000. The analyzed geometrical space here was a rectangular part of whose upper and bottom walls was influenced by a constant temperature. The effect of volume fraction of the nanoparticles, Reynolds number and non-Newtonian nanofluids was studied. In this research, the changes pressure drop, the Nusselt number, dimensionless temperature and heat transfer coefficient, caused by the motion of non-Newtonian nanofluids are described. The results indicated that the increase of the volume fraction of the solid nanoparticles and a reduction in the diameter of the nanoparticles would improve heat transfer which is more significant in Reynolds number. The results of the introduced parameters in the form of graphs drawing and for different parameters are compared.
Smart Fluids in Hydrology: Use of Non-Newtonian Fluids for Pore Structure Characterization
Abou Najm, Majdi; Atallah, Nabil; Selker, John; Roques, Clément; Stewart, Ryan; Rupp, David; Saad, George; El-Fadel, Mutasem
2016-04-01
Classic porous media characterization relies on typical infiltration experiments with Newtonian fluids (i.e., water) to estimate hydraulic conductivity. However, such experiments are generally not able to discern important characteristics such as pore size distribution or pore structure. We show that introducing non-Newtonian fluids provides additional unique flow signatures that can be used for improved pore structure characterization. We present a new method that transforms results of N infiltration experiments using water and N-1 non-Newtonian solutions into a system of equations that yields N representative radii (Ri) and their corresponding percent contribution to flow (wi). Those radii and weights are optimized in terms of flow and porosity to represent the functional hydraulic behavior of real porous media. The method also allows for estimating the soil retention curve using only saturated experiments. Experimental and numerical validation revealed the ability of the proposed method to represent the water retention and functional infiltration behavior of real soils. The experimental results showed the ability of such fluids to outsmart Newtonian fluids and infer pore size distribution and unsaturated behavior using simple saturated experiments. Specifically, we demonstrate using synthetic porous media composed of different combinations of sizes and numbers of capillary tubes that the use of different non-Newtonian fluids enables the prediction of the pore structure. The results advance the knowledge towards conceptualizing the complexity of porous media and can potentially impact applications in fields like irrigation efficiencies, vadose zone hydrology, soil-root-plant continuum, carbon sequestration into geologic formations, soil remediation, petroleum reservoir engineering, oil exploration and groundwater modeling.
Non-Newtonian steady shear flow characteristics of waxy crude oil
Institute of Scientific and Technical Information of China (English)
黄树新; 陈鑫; 鲁传敬; 侯磊; 范毓润
2008-01-01
The experimental research on the non-Newtonian flow characteristic of a waxy crude oil was conducted through a rotational parallel-plates rheometer system.The test temperature is about 6.5 ℃ higher than its gel point.The shear stress and viscosity of the waxy crude oil show sophisticate non-Newtonian characteristics in the shear rate of 10-4-102 s-1,in which the shear stress can be divided into three parts qualitatively,i.e.stress-up region,leveling-off region,and stress-up region.This indicates that there is a yielding process in shearing for the waxy crude oil at the experimental temperature,which is similar to the yield phenomenon in thixotropy-loop test discussed by CHANG and BOGER.Furthermore,the steady shear experiment after the pre-shear process shows that the stress leveling-off region at low shear rate disappears for the waxy crude oil and the stress curve becomes a monotonic climbing one,which demonstrates that the internal structure property presenting through yielding stress at low shear rate can be changed by shearing.The experimental results also show that the internal structure of waxy crude oil presenting at low shear rate has no influence on the shear viscosity obtained at the shear rate higher than 0.1 s-1.The generalized Newtonian model is adopted to describe the shear-thinning viscosity property of the waxy crude oil at high shear rate.
Directory of Open Access Journals (Sweden)
Roozbeh Mollaabbasi
2016-01-01
Full Text Available This research deals with experimental work on solid suspension and dispersion in stirred tank reactors that operate with complex fluids. Only suspended speed (Njs throughout the vessel was characterized using Gamma-Ray Densitometry. The outcomes of this study help to understand solid suspension mechanisms involving changes the rheology of the fluid and provide engineering data for designing stirred tanks. All experiments were based on classic radial and axial flow impellers, i.e., Rushton Turbine (RT and Pitched Blade Turbine in down pumping mode (PBT-D. Three different liquids (water, water+CMC, and water+PAA were employed in several concentrations. The CMC solution introduced as a pseudo plastic fluid and PAA solution was applied as a Herschel Bulkley fluid. The rheological properties of these fluids were characterized separately. According to the findings, the critical impeller speeds for solid suspension for non-Newtonian fluids were more eminent than those for water. Experiments were performed to characterize the effects of solid loading, impeller clearance and viscosity on Njs. Also the PSO method is employed to find suitable parameters of Zwietering's correlation for prediction of Njs in Non Newtonian fluids.
In defense of a non-newtonian economic analysis
Filip, Diana; Piatecki, Cyrille
2014-01-01
The double-entry bookkeeping promoted by Luca Pacioli in the fifteenth century could be considered a strong argument in behalf of the multiplicative calculus which can be developed from the Grossman and Katz non-newtonian calculus concept. In order to emphasize this statement we present a brief history of the accountancy in its early time and we make the point of Ellerman's research concerning the double-entry bookkeeping.; La comptabilité en partie double présentée par Luca Pacioli au quinzi...
Memory Effects and Transport Coefficients for Non-Newtonian Fluids
Kodama, T
2008-01-01
We discuss the roles of viscosity in relativistic fluid dynamics from the point of view of memory effects. Depending on the type of quantity to which the memory effect is applied, different terms appear in higher order corrections. We show that when the memory effect applies on the extensive quantities, the hydrodynamic equations of motion become non-singular. We further discuss the question of memory effect in the derivation of transport coefficients from a microscopic theory. We generalize the application of the Green-Kubo-Nakano (GKN) to calculate transport coefficients in the framework of projection operator formalism, and derive the general formula when the fluid is non-Newtonian.
Static stability of collapsible tube conveying non-Newtonian fluid
Yushutin, V S
2014-01-01
The global static stability of a Starling Resistor conveying non-Newtonian fluid is considered. The Starling Resistor consists of two rigid circular tubes and axisymmetric collapsible tube mounted between them. Upstream and downstream pressures are the boundary condition as well as external to the collapsible tube pressure. Quasi one-dimensional model has been proposed and a boundary value problem in terms of nondimensional parameters obtained. Nonuniqueness of the boundary value problem is regarded as static instability. The analytical condition of instability which defines a surface in parameter space has been studied numerically. The influence of fluid rheology on stability of collapsible tube is established.
Heat Transfer for Power Law Non-Newtonian Fluids
Institute of Scientific and Technical Information of China (English)
ZHENG Lian-Cun; ZHANG Xin-Xin; LU Chun-Qing
2006-01-01
We present a theoretical analysis for heat transfer in power law non-Newtonian fluid by assuming that the thermal diffusivity is a function of temperature gradient. The laminar boundary layer energy equation is considered as an example to illustrate the application. It is shown that the boundary layer energy equation subject to the corresponding boundary conditions can be transformed to a boundary value problem of a nonlinear ordinary differential equation when similarity variables are introduced. Numerical solutions of the similarity energy equation are presented.
Controlling and minimizing fingering instabilities in non-Newtonian fluids.
Fontana, João V; Dias, Eduardo O; Miranda, José A
2014-01-01
The development of the viscous fingering instability in Hele-Shaw cells has great practical and scientific importance. Recently, researchers have proposed different strategies to control the number of interfacial fingering structures, or to minimize as much as possible the amplitude of interfacial disturbances. Most existing studies address the situation in which an inviscid fluid displaces a viscous Newtonian fluid. In this work, we report on controlling and minimizing protocols considering the situation in which the displaced fluid is a non-Newtonian, power-law fluid. The necessary changes on the controlling schemes due to the shear-thinning and shear thickening nature of the displaced fluid are calculated analytically and discussed.
Random Attractors of Stochastic Non-Newtonian Fluids
Institute of Scientific and Technical Information of China (English)
Chun-xiao GUO; Bo-ling GUO; Yong-qian HAN
2012-01-01
The present paper investigates the asymptotic behavior of solutions for stochastic non-Newtonian fluids in a two-dimensional domain.Firstly,we prove the existence of random attractors AH(ω) in H; Secondly,we prove the existence of random attractors Av(ω) in V.Then we verify regularity of the random attractors by showing that AH(ω) =Av(ω),which implies the smoothing effect of the fluids in the sense that solution becomes eventually more regular than the initial data.
Test of non-Newtonian gravitational force at micrometer range
Luo, Pengshun; Guan, Shengguo; Wu, Wenjie; Tian, Zhaoyang; Yang, Shanqing; Shao, Chenggang; Luo, Jun
2016-01-01
We report an experimental test of non-Newtonian gravitational forces at mi- crometer range. To experimentally subtract off the Casimir force and the electrostatic force background, differential force measurements were performed by sensing the lateral force between a gold sphere and a density modulated source mass using a soft cantilever. The current sensitivity is limited by the patch electrostatic force, which is further improved by two dimensional (2D) force mapping. The preliminary result sets a model independent constraint on the Yukawa type force at this range.
Experimental study on the special shear thinning process of a kind of non-Newtonian fluid
Institute of Scientific and Technical Information of China (English)
CHEN HaoSheng; CHEN DaRong; WANG JiaDao; LI YongJian
2007-01-01
To study the effect of long chain molecule and surface active agent on non-Newtonian fluid properties, rheological experiments on two different fluids have been done. The first group of the fluid is the hydroxyethyl cellulose water solution, and the second is the water solution containing the mixture of dodecyltriethyl ammonium bromide and lauryl sodium sulfate. With the increasing shear rate, shear thinning phenomenon appears in the first group of solution, and a special shear thickening-shear thinning phenomenon appears in the second group. It is considered that the special rheological phenomenon is caused by the difference between the aggregating and the departing speed of the colloidal particles formed in the fluid. The difference between the two speeds relates with the shear rate. The experiment results indicate that the rheological properties can be designed by choosing proper additives at a certain shear rate, and such a fluid with special viscosity variation should be included in the classification of the non-Newtonian fluid.
Experimental study on the special shear thinning process of a kind of non-Newtonian fluid
Institute of Scientific and Technical Information of China (English)
2007-01-01
To study the effect of long chain molecule and surface active agent on non-Newtonian fluid properties, rheological experiments on two different fluids have been done. The first group of the fluid is the hydroxyethyl cellulose water solution, and the second is the water solution containing the mixture of dodecyl- triethyl ammonium bromide and lauryl sodium sulfate. With the increasing shear rate, shear thinning phenomenon appears in the first group of solution, and a spe- cial shear thickening-shear thinning phenomenon appears in the second group. It is considered that the special rheological phenomenon is caused by the difference between the aggregating and the departing speed of the colloidal particles formed in the fluid. The difference between the two speeds relates with the shear rate. The experiment results indicate that the rheological properties can be designed by choosing proper additives at a certain shear rate, and such a fluid with special vis- cosity variation should be included in the classification of the non-Newtonian fluid.
Electro-osmotic mobility of non-Newtonian fluids.
Zhao, Cunlu; Yang, Chun
2011-03-23
Electrokinetically driven microfluidic devices are usually used to analyze and process biofluids which can be classified as non-Newtonian fluids. Conventional electrokinetic theories resulting from Newtonian hydrodynamics then fail to describe the behaviors of these fluids. In this study, a theoretical analysis of electro-osmotic mobility of non-Newtonian fluids is reported. The general Cauchy momentum equation is simplified by incorporation of the Gouy-Chapman solution to the Poisson-Boltzmann equation and the Carreau fluid constitutive model. Then a nonlinear ordinary differential equation governing the electro-osmotic velocity of Carreau fluids is obtained and solved numerically. The effects of the Weissenberg number (Wi), the surface zeta potential (ψ¯s), the power-law exponent(n), and the transitional parameter (β) on electro-osmotic mobility are examined. It is shown that the results presented in this study for the electro-osmotic mobility of Carreau fluids are quite general so that the electro-osmotic mobility for the Newtonian fluids and the power-law fluids can be obtained as two limiting cases.
Intermittent outgassing through a non-Newtonian fluid.
Divoux, Thibaut; Bertin, Eric; Vidal, Valérie; Géminard, Jean-Christophe
2009-05-01
We report an experimental study of the intermittent dynamics of a gas flowing through a column of a non-Newtonian fluid. In a given range of the imposed constant flow rate, the system spontaneously alternates between two regimes: bubbles emitted at the bottom either rise independently one from the other or merge to create a winding flue which then connects the bottom air entrance to the free surface. The observations are reminiscent of the spontaneous changes in the degassing regime observed on volcanoes and suggest that, in the nature, such a phenomenon is likely to be governed by the non-Newtonian properties of the magma. We focus on the statistical distribution of the lifespans of the bubbling and flue regimes in the intermittent steady state. The bubbling regime exhibits a characteristic time whereas, interestingly, the flue lifespan displays a decaying power-law distribution. The associated exponent, which is significantly smaller than the value 1.5 often reported experimentally and predicted in some standard intermittency scenarios, depends on the fluid properties and can be interpreted as the ratio of two characteristic times of the system.
Dynamics of Non-Newtonian Liquid Droplet Collision
Chen, Xiaodong; Yang, Vigor
2012-11-01
Collision of Newtonian liquid droplets has been extensively investigated both experimentally and numerically for decades. Limited information, however, is available about non-Newtonian droplet collision dynamics. In the present work, high-fidelity numerical simulations were performed to study the situation associated with shear-thinning non-Newtonian liquids. The formulation is based on a complete set of conservation equations for the liquid and the surrounding gas phases. An improved volume-of-fluid (VOF) method, combined with an innovative topology-oriented adaptive mesh refinement (TOAMR) technique, was developed and implemented to track the interfacial dynamics. The complex evolution of the droplet surface over a broad range of length scales was treated accurately and efficiently. In particular, the thin gas film between two approaching droplets and subsequent breakup of liquid threads were well-resolved. Various types of droplet collision were obtained, including coalescence, bouncing, and reflexive and stretching separations. A regime diagram was developed and compared with that for Newtonian liquids. Fundamental mechanisms and key parameters that dictate droplet behaviors were identified. In addition, collision-induced atomization was addressed. This work was sponsored by the U.S. Army Research Office under the Multi-University Research Initiative under contract No. W911NF-08-1-0124. The support and encouragement provided by Dr. Ralph Anthenien are gratefully acknowledged.
Steady flow of a non-Newtonian fluid through a contraction
Gatski, T. B.; Lumley, J. L.
1978-01-01
A steady-state analysis is conducted to examine the basic flow structure of a non-Newtonian fluid in a domain including an inflow region, a contraction region, and an outflow region. A Cartesian grid system is used throughout the entire flow domain, including the contraction region, thus creating an irregular grid cell structure adjacent to the curved boundary. At node points adjacent to the curved boundary symmetry conditions are derived for the different flow variables in order to solve the governing difference equations. Attention is given to the motion and non-Newtonian constitutive equations, the boundary conditions, the numerical modeling of the non-Newtonian equations, the stream function contour lines for the non-Newtonian fluid, the vorticity contour lines for the non-Newtonian fluid, the velocity profile across the contraction, and the shear stress contour lines for the non-Newtonian fluid.
CFD simulation of gas and non-Newtonian fluid two-phase flow in anaerobic digesters.
Wu, Binxin
2010-07-01
This paper presents an Eulerian multiphase flow model that characterizes gas mixing in anaerobic digesters. In the model development, liquid manure is assumed to be water or a non-Newtonian fluid that is dependent on total solids (TS) concentration. To establish the appropriate models for different TS levels, twelve turbulence models are evaluated by comparing the frictional pressure drops of gas and non-Newtonian fluid two-phase flow in a horizontal pipe obtained from computational fluid dynamics (CFD) with those from a correlation analysis. The commercial CFD software, Fluent12.0, is employed to simulate the multiphase flow in the digesters. The simulation results in a small-sized digester are validated against the experimental data from literature. Comparison of two gas mixing designs in a medium-sized digester demonstrates that mixing intensity is insensitive to the TS in confined gas mixing, whereas there are significant decreases with increases of TS in unconfined gas mixing. Moreover, comparison of three mixing methods indicates that gas mixing is more efficient than mixing by pumped circulation while it is less efficient than mechanical mixing.
Effects of non Newtonian spiral blood flow through arterial stenosis
Hasan, Md. Mahmudul; Maruf, Mahbub Alam; Ali, Mohammad
2016-07-01
The spiral component of blood flow has both beneficial and detrimental effects in human circulatory system. A numerical investigation is carried out to analyze the effect of spiral blood flow through an axisymmetric three dimensional artery having 75% stenosis at the center. Blood is assumed as a Non-Newtonian fluid. Standard k-ω model is used for the simulation with the Reynolds number of 1000. A parabolic velocity profile with spiral flow is used as inlet boundary condition. The peak values of all velocity components are found just after stenosis. But total pressure gradually decreases at downstream. Spiral flow of blood has significant effects on tangential component of velocity. However, the effect is mild for radial and axial velocity components. The peak value of wall shear stress is at the stenosis zone and decreases rapidly in downstream. The effect of spiral flow is significant for turbulent kinetic energy. Detailed investigation and relevant pathological issues are delineated throughout the paper.
Laminar boundary-layer flow of non-Newtonian fluid
Lin, F. N.; Chern, S. Y.
1979-01-01
A solution for the two-dimensional and axisymmetric laminar boundary-layer momentum equation of power-law non-Newtonian fluid is presented. The analysis makes use of the Merk-Chao series solution method originally devised for the flow of Newtonian fluid. The universal functions for the leading term in the series are tabulated for n from 0.2 to 2. Equations governing the universal functions associated with the second and the third terms are provided. The solution together with either Lighthill's formula or Chao's formula constitutes a simple yet general procedure for the calculation of wall shear and surface heat transfer rate. The theory was applied to flows over a circular cylinder and a sphere and the results compared with published data.
Dynamic wetting with viscous Newtonian and non-Newtonian fluids.
Wei, Y; Rame, E; Walker, L M; Garoff, S
2009-11-18
We examine various aspects of dynamic wetting with viscous Newtonian and non-Newtonian fluids. Rather than concentrating on the mechanisms that relieve the classic contact line stress singularity, we focus on the behavior in the wedge flow near the contact line which has the dominant influence on wetting with these fluids. Our experiments show that a Newtonian polymer melt composed of highly flexible molecules exhibits dynamic wetting behavior described very well by hydrodynamic models that capture the critical properties of the Newtonian wedge flow near the contact line. We find that shear thinning has a strong impact on dynamic wetting, by reducing the drag of the solid on the fluid near the contact line, while the elasticity of a Boger fluid has a weaker impact on dynamic wetting. Finally, we find that other polymeric fluids, nominally Newtonian in rheometric measurements, exhibit deviations from Newtonian dynamic wetting behavior.
Energy Technology Data Exchange (ETDEWEB)
Edited by Guenther, Chris; Garg, Rahul
2013-08-19
The Department of Energy’s (DOE) National Energy Technology Laboratory (NETL) sponsored a workshop on non-Newtonian multiphase slurry at NETL’s Morgantown campus August 19 and 20, 2013. The objective of this special two-day meeting of 20-30 invited experts from industry, National Labs and academia was to identify and address technical issues associated with handling non-Newtonian multiphase slurries across various facilities managed by DOE. Particular emphasis during this workshop was placed on applications managed by the Office of Environmental Management (EM). The workshop was preceded by two webinars wherein personnel from ORP and NETL provided background information on the Hanford WTP project and discussed the critical design challenges facing this project. In non-Newtonian fluids, viscosity is not constant and exhibits a complex dependence on applied shear stress or deformation. Many applications under EM’s tank farm mission involve non-Newtonian slurries that are multiphase in nature; tank farm storage and handling, slurry transport, and mixing all involve multiphase flow dynamics, which require an improved understanding of the mechanisms responsible for rheological changes in non-Newtonian multiphase slurries (NNMS). To discuss the issues in predicting the behavior of NNMS, the workshop focused on two topic areas: (1) State-of-the-art in non-Newtonian Multiphase Slurry Flow, and (2) Scaling up with Confidence and Ensuring Safe and Reliable Long-Term Operation.
Crossover phenomena in non-Newtonian viscous fingers at a finite viscosity ratio
Nagatani, Takashi
1990-04-01
A viscous fingering of non-Newtonian fluids at a finite viscosity ratio is considered in order to study the effect of non-Newtonian fluid on crossover phenomena. The crossover from the fractal pattern to the dense structure is investigated by using a two-parameter position-space renormalization-group method. The global flow diagrams in two-parameter space are obtained. It is found that there are two nontrivial fixed points: the fractal point and the Eden point. When the viscosity ratio is finite, the pattern must eventually cross over to the dense structure. The dependences of the crossover phenomena on the parameter k, which describes the different non-Newtonian fluids, are shown. It is found that the non-Newtonian fluids have important effects on the fractal point and the crossover line but the crossover exponent is independent of the non-Newtonian property.
Non-Newtonian Behavior of Diblock and Triblock Copolymer Solutions
Watanabe, Hiroshi
2006-03-01
Non-Newtonian flow behavior was examined for butadiene-styrene (BS) diblock and BSB triblock copolymers dissolved in a S-selective solvent, dibutyl phthalate (DBP). Spherical domains of the non-solvated B blocks were arranged on a bcc lattice in both solutions at equilibrium, as revealed from SANS. The solutions exhibited significant thinning under steady flow, which was well correlated with the disruption of the bcc lattice detected with SANS. The lattice disruption was most prominent at a shear rate comparable to the frequency of B/S concentration fluctuation. For the BS/DBP solution, the recovery of the lattice structure after cessation of flow was the slowest for the most heavily disrupted lattice, as naturally expected. In contrast, for the BSB/DBP solution, the recovery rate was insensitive to the magnitude of lattice disruption. This peculiar behavior of the BSB solution suggests that the rate-determining step of the recovery in this solution is the transient B/S mixing required for reformation of the S bridges connecting the B domains.
Inelastic non-Newtonian flow over heterogeneously slippery surfaces
Haase, A. Sander; Wood, Jeffery A.; Sprakel, Lisette M. J.; Lammertink, Rob G. H.
2017-02-01
In this study, we investigated inelastic non-Newtonian fluid flow over heterogeneously slippery surfaces. First, we simulated the flow of aqueous xanthan gum solutions over a bubble mattress, which is a superhydrophobic surface consisting of transversely positioned no-slip walls and no-shear gas bubbles. The results reveal that for shear-thinning fluids wall slip can be increased significantly, provided that the system is operated in the shear-thinning regime. For a 0.2 wt% xanthan gum solution with a power-law index of n =0.4 , the numerical results indicate that wall slip can be enhanced 3.2 times when compared to a Newtonian liquid. This enhancement factor was also predicted from a theoretical analysis, which gave an expression for the maximum slip length that can be attained over flat, heterogeneously slippery surfaces. Although this equation was derived for a no-slip/no-shear unit length that is much larger than the typical size of the system, we found that it can also be used to predict the enhancement in the regime where the slip length is proportional to the size of the no-shear region or the bubble width. The results could be coupled to the hydrodynamic development or entrance length of the system, as maximum wall slip is only reached when the fluid flow can fully adapt to the no-slip and no-shear conditions at the wall.
The Construction of Hilbert Spaces over the Non-Newtonian Field
Uğur Kadak; Hakan Efe
2014-01-01
Although there are many excellent ways to present the principle of the classical calculus, the novel presentations probably lead most naturally to the development of the non-Newtonian calculi. In this paper we introduce vector spaces over real and complex non-Newtonian field with respect to the *-calculus which is a branch of non-Newtonian calculus. Also we give the definitions of real and complex inner product spaces and study Hilbert spaces which are special type of normed space and complet...
Generalized Runge-Kutta Method with respect to the Non-Newtonian Calculus
Uğur Kadak; Muharrem Özlük
2015-01-01
Theory and applications of non-Newtonian calculus have been evolving rapidly over the recent years. As numerical methods have a wide range of applications in science and engineering, the idea of the design of such numerical methods based on non-Newtonian calculus is self-evident. In this paper, the well-known Runge-Kutta method for ordinary differential equations is developed in the frameworks of non-Newtonian calculus given in generalized form and then tested for different generating functio...
A Generalization on Weighted Means and Convex Functions with respect to the Non-Newtonian Calculus
Directory of Open Access Journals (Sweden)
Uğur Kadak
2016-01-01
Full Text Available This paper is devoted to investigating some characteristic features of weighted means and convex functions in terms of the non-Newtonian calculus which is a self-contained system independent of any other system of calculus. It is shown that there are infinitely many such useful types of weighted means and convex functions depending on the choice of generating functions. Moreover, some relations between classical weighted mean and its non-Newtonian version are compared and discussed in a table. Also, some geometric interpretations of convex functions are presented with respect to the non-Newtonian slope. Finally, using multiplicative continuous convex functions we give an application.
Convex functions and some inequalities in terms of the Non-Newtonian Calculus
Unluyol, Erdal; Salas, Seren; Iscan, Imdat
2017-04-01
Differentiation and integration are basic operations of calculus and analysis. Indeed, they are many versions of the subtraction and addition operations on numbers, respectively. From 1967 till 1970 Michael Grossman and Robert Katz [1] gave definitions of a new kind of derivative and integral, converting the roles of subtraction and addition into division and multiplication, and thus establish a new calculus, called Non-Newtonian Calculus. So, in this paper, it is investigated to the convex functions and some inequalities in terms of Non-Newtonian Calculus. Then we compare with the Newtonian and Non-Newtonian Calculus.
Sinking of spherical slablets through a non-Newtonian mantle
Crameri, Fabio; Stegman, Dave; Petersen, Robert; Tackley, Paul
2014-05-01
The dominant driving force for plate tectonics is slab pull, in which sinking slabs pull the trailing plate. Forward plate velocities are typically similar in magnitude (7 cm/yr) as estimates for sinking velocities of slabs through the upper mantle. However, these estimates are based on data for slabs that are coherent into the transition zone as well as models that considered the upper mantle to be entirely Newtonian. Dislocation creep in the upper mantle can strongly influence mantle flow, and is likely activated for flow around vertically sinking slabs in the uppermost mantle. Thus, it is possible that in some scenarios, a non-Newtonian mantle will have an influence on plate motions but it is unclear to what degree. To address this question, we investigate how the non-Newtonian rheology modifies the sinking velocities of slablets (spherical, negatively buoyant and highly viscous blobs). The model set-up is similar to a Stokes sphere sinking, but is in 2-D cartesian with temperature-and stress-dependent rheology. For these numerical models, we use the Stag-YY code (e.g., Tackley 2008) and apply a pseudo-free surface using the 'sticky-air' approach (Matsumoto and Tomoda 1983; Schmeling et al, 2008, Crameri et al., 2012). The sinking blob is both highly viscous and compositionally dense, but is the same temperature as the background fluid which eliminates thermal diffusion and associated variations in thermal buoyancy. The model domain is 2x1 or 4x1 and allows enough distance to the sidewalls so that sinking velocities are not influenced by the boundary conditions. We compare our results with those previously obtained for salt diapirs rising through a power-law rheology mantle/crust (Weinberg, 1993; Weinberg and Podladchikov, 1994), which provided both numerical and analytic results. Previous results indicate a speed-up of an order of magnitude is possible. Finally, we then extend the models and analysis to mantle convection systems that include for single
Lubrication performances of short journal bearings operating with non-Newtonian ferrofluids
Energy Technology Data Exchange (ETDEWEB)
Lin, Jaw-Ren [Taoyuan Innovation Inst. of Tech., Jhongli, TW (China). Dept. of Mechanical Engineering; Li, Po-Jui [National Taipei Univ. of Technology, Taipei, TW (China). Dept. of Inst. of Mechatronic Engineering; Hung, Tzu-Chen [National Taipei Univ. of Technology, Taipei, TW (China). Dept. of Mechanical Engineering
2013-03-15
The lubrication performances of short journal bearings operating with non-Newtonian ferrofluids have been investigated in the present study. Based upon the ferrofluid model of Shliomis and the micro-continuum theory of Stokes, a two-dimensional modified Reynolds equation is derived by taking into account the effects of rotation of ferromagnetic particles and the effects of non-Newtonian properties. As an application, the short-bearing approximation is illustrated. Comparing with the conventional non-ferrofluid case, the short journal bearings with ferrofluids in the presence of magnetic fields result in a higher load capacity. Comparing with the Newtonian ferrofluid case, the non-Newtonian effects of couple stresses provide an enhancement in the load capacity, as well as a reduction in the friction parameter. The inclusion of non-Newtonian couple stresses signifies an improvement in performance characteristics of ferrofluid journal bearings. (orig.)
Certain Spaces of Functions over the Field of Non-Newtonian Complex Numbers
Directory of Open Access Journals (Sweden)
Ahmet Faruk Çakmak
2014-01-01
Full Text Available This paper is devoted to investigate some characteristic features of complex numbers and functions in terms of non-Newtonian calculus. Following Grossman and Katz, (Non-Newtonian Calculus, Lee Press, Piegon Cove, Massachusetts, 1972, we construct the field ℂ* of *-complex numbers and the concept of *-metric. Also, we give the definitions and the basic important properties of *-boundedness and *-continuity. Later, we define the space C*(Ω of *-continuous functions and state that it forms a vector space with respect to the non-Newtonian addition and scalar multiplication and we prove that C*(Ω is a Banach space. Finally, Multiplicative calculus (MC, which is one of the most popular non-Newtonian calculus and created by the famous exp function, is applied to complex numbers and functions to investigate some advance inner product properties and give inclusion relationship between C*(Ω and the set of C*′(Ω*-differentiable functions.
Generalized Runge-Kutta Method with respect to the Non-Newtonian Calculus
Directory of Open Access Journals (Sweden)
Uğur Kadak
2015-01-01
Full Text Available Theory and applications of non-Newtonian calculus have been evolving rapidly over the recent years. As numerical methods have a wide range of applications in science and engineering, the idea of the design of such numerical methods based on non-Newtonian calculus is self-evident. In this paper, the well-known Runge-Kutta method for ordinary differential equations is developed in the frameworks of non-Newtonian calculus given in generalized form and then tested for different generating functions. The efficiency of the proposed non-Newtonian Euler and Runge-Kutta methods is exposed by examples, and the results are compared with the exact solutions.
Institute of Scientific and Technical Information of China (English)
Zhao Caidi; Jia Xiaolin; Yang Xinbo
2011-01-01
This paper is joint with [27].The authors prove in this article the existence and reveal its structure of uniform attractor for a two-dimensional nonautonomous incompressible non-Newtonian fluid with a new class of external forces.
H 2-regularity random attractors of stochastic non-Newtonian fluids with multiplicative noise
Institute of Scientific and Technical Information of China (English)
Chun-xiao GUO; Bo-ling GUO; Hui YANG
2014-01-01
In this paper, the authors study the long time behavior of solutions to stochastic non-Newtonian fluids in a two-dimensional bounded domain, and prove the existence of H 2-regularity random attractor.
Upper Semicontinuity of Attractors for a Non-Newtonian Fluid under Small Random Perturbations
Directory of Open Access Journals (Sweden)
Jianxin Luo
2014-01-01
Full Text Available This paper investigates the limiting behavior of attractors for a two-dimensional incompressible non-Newtonian fluid under small random perturbations. Under certain conditions, the upper semicontinuity of the attractors for diminishing perturbations is shown.
Effect of non-Newtonian viscosity on the fluid-dynamic characteristics in stenotic vessels
Huh, Hyung Kyu; Ha, Hojin; Lee, Sang Joon
2015-08-01
Although blood is known to have shear-thinning and viscoelastic properties, the effects of such properties on the hemodynamic characteristics in various vascular environments are not fully understood yet. For a quantitative hemodynamic analysis, the refractive index of a transparent blood analogue needs to be matched with that of the flowing conduit in order to minimize the errors according to the distortion of the light. In this study, three refractive index-matched blood analogue fluids with different viscosities are prepared—one Newtonian and two non-Newtonian analogues—which correspond to healthy blood with 45 % hematocrit (i.e., normal non-Newtonian) and obese blood with higher viscosity (i.e., abnormal non-Newtonian). The effects of the non-Newtonian rheological properties of the blood analogues on the hemodynamic characteristics in the post-stenosis region of an axisymmetric stenosis model are experimentally investigated using particle image velocimetry velocity field measurement technique and pathline flow visualization. As a result, the centerline jet flow from the stenosis apex is suppressed by the shear-thinning feature of the blood analogues when the Reynolds number is smaller than 500. The lengths of the recirculation zone for abnormal and normal non-Newtonian blood analogues are 3.67 and 1.72 times shorter than that for the Newtonian analogue at Reynolds numbers smaller than 200. The Reynolds number of the transition from laminar to turbulent flow for all blood analogues increases as the shear-thinning feature increases, and the maximum wall shear stresses in non-Newtonian fluids are five times greater than those in Newtonian fluids. However, the shear-thinning effect on the hemodynamic characteristics is not significant at Reynolds numbers higher than 1000. The findings of this study on refractive index-matched non-Newtonian blood analogues can be utilized in other in vitro experiments, where non-Newtonian features dominantly affect the flow
A Generalization on Weighted Means and Convex Functions with respect to the Non-Newtonian Calculus
Uğur Kadak; Yusuf Gürefe
2016-01-01
This paper is devoted to investigating some characteristic features of weighted means and convex functions in terms of the non-Newtonian calculus which is a self-contained system independent of any other system of calculus. It is shown that there are infinitely many such useful types of weighted means and convex functions depending on the choice of generating functions. Moreover, some relations between classical weighted mean and its non-Newtonian version are compared and discussed in a table...
Certain Spaces of Functions over the Field of Non-Newtonian Complex Numbers
Ahmet Faruk Çakmak; Feyzi Başar
2014-01-01
This paper is devoted to investigate some characteristic features of complex numbers and functions in terms of non-Newtonian calculus. Following Grossman and Katz, (Non-Newtonian Calculus, Lee Press, Piegon Cove, Massachusetts, 1972), we construct the field ${\\Bbb C}^{\\ast}$ of ${\\ast}$ -complex numbers and the concept of ${\\ast}$ -metric. Also, we give the definitions and the basic important properties of ${\\ast}$ -boundedness and ${\\ast}$ -continuity. Later, we define the space ${C}_{\\ast}(...
Determination of the Köthe-Toeplitz Duals over the Non-Newtonian Complex Field
Uğur Kadak
2014-01-01
The important point to note is that the non-Newtonian calculus is a self-contained system independent of any other system of calculus. Therefore the reader may be surprised to learn that there is a uniform relationship between the corresponding operators of this calculus and the classical calculus. Several basic concepts based on non-Newtonian calculus are presented by Grossman (1983), Grossman and Katz (1978), and Grossman (1979). Following Grossman and Katz, in the present paper, we introdu...
Decay of solutions to equations modelling incompressible bipolar non-newtonian fluids
Directory of Open Access Journals (Sweden)
Bo-Qing Dong
2005-11-01
Full Text Available This article concerns systems of equations that model incompressible bipolar non-Newtonian fluid motion in the whole space $mathbb{R}^n$. Using the improved Fourier splitting method, we prove that a weak solution decays in the $L^2$ norm at the same rate as $(1+t^{-n/4}$ as the time $t$ approaches infinity. Also we obtain optimal $L^2$ error-estimates for Newtonian and Non-Newtonian flows.
Time Decay Rates of the Isotropic Non-Newtonian Flows in Rn
Institute of Scientific and Technical Information of China (English)
Bo-Qing Dong
2007-01-01
This paper is concerned with time decay rates for weak solutions to a class system of isotropic incompressible non-Newtonian fluid motion in Rn. With the use of the spectral decomposition methods of Stokes operator, the optimal decay estimates of weak solutions in L2 norm are derived under the different conditions on the initial velocity. Moreover, the error estimates of the difference between non-Newtonian flow and Navier-Stokes flow are also investigated.
Gravity driven instabilities in miscible non-Newtonian fluid displacements in porous media
Freytes, V. M.; D'Onofrio, A.; Rosen, M.; Allain, C.; Hulin, J. P.
2001-02-01
Gravity driven instabilities in model porous packings of 1 mm diameter spheres are studied by comparing the broadening of the displacement front between fluids of slightly different densities in stable and unstable configurations. Water, water-glycerol and water-polymer solutions are used to vary independently viscosity and molecular diffusion and study the influence of shear-thinning properties. Both injected and displaced solutions are identical but for a different concentration of NaNO 3 salt used as an ionic tracer and to introduce the density contrast. Dispersivity in stable configuration increases with polymer concentration - as already reported for double porosity packings of porous grains. Gravity-induced instabilities are shown to develop below a same threshold Péclet number Pe for water and water-glycerol solutions of different viscosities and result in considerable increases of the dispersivity. Measured threshold Pe values decrease markedly on the contrary with polymer concentration. The quantitative analysis demonstrates that the development of the instabilities is controlled by viscosity through a characteristic gravity number G (ratio between hydrostatic and viscous pressure gradients). A single threshold value of G accounts for results obtained on Newtonian and non-Newtonian solutions.
Mathematical analysis of non-Newtonian blood flow in stenosis narrow arteries.
Sriyab, Somchai
2014-01-01
The flow of blood in narrow arteries with bell-shaped mild stenosis is investigated that treats blood as non-Newtonian fluid by using the K-L model. When skin friction and resistance of blood flow are normalized with respect to non-Newtonian blood in normal artery, the results present the effect of stenosis length. When skin friction and resistance of blood flow are normalized with respect to Newtonian blood in stenosis artery, the results present the effect of non-Newtonian blood. The effect of stenosis length and effect of non-Newtonian fluid on skin friction are consistent with the Casson model in which the skin friction increases with the increase of either stenosis length or the yield stress but the skin friction decreases with the increase of plasma viscosity coefficient. The effect of stenosis length and effect of non-Newtonian fluid on resistance of blood flow are contradictory. The resistance of blood flow (when normalized by non-Newtonian blood in normal artery) increases when either the plasma viscosity coefficient or the yield stress increases, but it decreases with the increase of stenosis length. The resistance of blood flow (when normalized by Newtonian blood in stenosis artery) decreases when either the plasma viscosity coefficient or the yield stress increases, but it decreases with the increase of stenosis length.
Amiri Delouei, A.; Nazari, M.; Kayhani, M. H.; Kang, S. K.; Succi, S.
2016-04-01
In the current study, a direct-forcing immersed boundary-non-Newtonian lattice Boltzmann method (IB-NLBM) is developed to investigate the sedimentation and interaction of particles in shear-thinning and shear-thickening fluids. In the proposed IB-NLBM, the non-linear mechanics of non-Newtonian particulate flows is detected by combination of the most desirable features of immersed boundary and lattice Boltzmann methods. The noticeable roles of non-Newtonian behavior on particle motion, settling velocity and generalized Reynolds number are investigated by simulating benchmark problem of one-particle sedimentation under the same generalized Archimedes number. The effects of extra force due to added accelerated mass are analyzed on the particle motion which have a significant impact on shear-thinning fluids. For the first time, the phenomena of interaction among the particles, such as Drafting, Kissing, and Tumbling in non-Newtonian fluids are investigated by simulation of two-particle sedimentation and twelve-particle sedimentation. The results show that increasing the shear-thickening behavior of fluid leads to a significant increase in the kissing time. Moreover, the transverse position of particles for shear-thinning fluids during the tumbling interval is different from Newtonian and the shear-thickening fluids. The present non-Newtonian particulate study can be applied in several industrial and scientific applications, like the non-Newtonian sedimentation behavior of particles in food industrial and biological fluids.
Analysis of non-Newtonian effects on Low-Density Lipoprotein accumulation in an artery.
Iasiello, Marcello; Vafai, Kambiz; Andreozzi, Assunta; Bianco, Nicola
2016-06-14
In this work, non-Newtonian effects on Low-Density Lipoprotein (LDL) transport across an artery are analyzed with a multi-layer model. Four rheological models (Carreau, Carreau-Yasuda, power-law and Newtonian) are used for the blood flow through the lumen. For the non-Newtonian cases, the arterial wall is modeled with a generalized momentum equation. Convection-diffusion equation is used for the LDL transport through the lumen, while Staverman-Kedem-Katchalsky, combined with porous media equations, are used for the LDL transport through the wall. Results are presented in terms of filtration velocity, Wall Shear Stresses (WSS) and concentration profiles. It is shown that non-Newtonian effects on mass transport are negligible for a healthy intramural pressure value. Non-Newtonian effects increase slightly with intramural pressure, but Newtonian assumption can still be considered reliable. Effects of arterial size are also analyzed, showing that Newtonian assumption can be considered valid for both medium and large arteries, in predicting LDL deposition. Finally, non-Newtonian effects are also analyzed for an aorta-common iliac bifurcation, showing that Newtonian assumption is valid for mass transport at low Reynolds numbers. At a high Reynolds number, it has been shown that a non-Newtonian fluid model can have more impact due to the presence of flow recirculation.
De Vita, F.; de Tullio, M. D.; Verzicco, R.
2016-04-01
This work focuses on the comparison between Newtonian and non-Newtonian blood flows through a bileaflet mechanical heart valve in the aortic root. The blood, in fact, is a concentrated suspension of cells, mainly red blood cells, in a Newtonian matrix, the plasma, and consequently its overall behavior is that of a non-Newtonian fluid owing to the action of the cells' membrane on the fluid part. The common practice, however, assumes the blood in large vessels as a Newtonian fluid since the shear rate is generally high and the effective viscosity becomes independent of the former. In this paper, we show that this is not always the case even in the aorta, the largest artery of the systemic circulation, owing to the pulsatile and transitional nature of the flow. Unexpectedly, for most of the pulsating cycle and in a large part of the fluid volume, the shear rate is smaller than the threshold level for the blood to display a constant effective viscosity and its shear thinning character might affect the system dynamics. A direct inspection of the various flow features has shown that the valve dynamics, the transvalvular pressure drop and the large-scale features of the flow are very similar for the Newtonian and non-Newtonian fluid models. On the other hand, the mechanical damage of the red blood cells (hemolysis), induced by the altered stress values in the flow, is larger for the non-Newtonian fluid model than for the Newtonian one.
Directory of Open Access Journals (Sweden)
Yonghui Xie
2015-01-01
Full Text Available Flow characteristics and heat transfer performances in rectangular tubes with protrusions are numerically investigated in this paper. The thermal heat transfer enhancement of composite structures and flow resistance reduction of non-Newtonian fluid are taken advantage of to obtain a better thermal performance. Protrusion channels coupled with different CMC concentration solutions are studied, and the results are compared with that of smooth channels with water flow. The comprehensive influence of turbulence effects, structural effects, and secondary flow effects on the CMC’s flow in protrusion tubes is extensively investigated. The results indicate that the variation of flow resistance parameters of shear-thinning power-law fluid often shows a nonmonotonic trend, which is different from that of water. It can be concluded that protrusion structure can effectively enhance the heat transfer of CMC solution with low pressure penalty in specific cases. Moreover, for a specific protrusion structure and a fixed flow velocity, there exists an optimal solution concentration showing the best thermal performance.
Helton, Kristen L; Yager, Paul
2007-11-01
As part of a project to develop an integrated microfluidic biosensor for the detection of small molecules in saliva, practical issues of extraction of analytes from non-Newtonian samples using an H-filter were explored. The H-filter can be used to rapidly and efficiently extract small molecules from a complex sample into a simpler buffer. The location of the interface between the sample and buffer streams is a critical parameter in the function of the H-filter, so fluorescence microscopy was employed to monitor the interface position; this revealed apparently anomalous fluorophore diffusion from the samples into the buffer solutions. Using confocal microscopy to understand the three-dimensional distribution of the fluorophore, it was found that the interface between the non-Newtonian sample and Newtonian buffer was both curved and unstable. The core of the non-Newtonian sample extended into the Newtonian buffer and its position was unstable, producing a fluorescence intensity profile that gave rise to the apparently anomalously fast fluorophore transport. These instabilities resulted from the pairing of rheologically dissimilar fluid streams and were flowrate dependent. We conclude that use of non-Newtonian fluids, such as saliva, in the H-filter necessitates pretreatment to reduce viscoelasticity. The interfacial variation in position, stability and shape caused by the non-Newtonian samples has substantial implications for the use of biological samples for quantitative analysis and analyte extraction in concurrent flow extraction devices.
Entropy Generation in Flow of Highly Concentrated Non-Newtonian Emulsions in Smooth Tubes
Directory of Open Access Journals (Sweden)
Rajinder Pal
2014-10-01
Full Text Available Entropy generation in adiabatic flow of highly concentrated non-Newtonian emulsions in smooth tubes of five different diameters (7.15–26.54 mm was investigated experimentally. The emulsions were of oil-in-water type with dispersed-phase concentration (Φ ranging from 59.61–72.21% vol. The emulsions exhibited shear-thinning behavior in that the viscosity decreased with the increase in shear rate. The shear-stress (τ versus shear rate (˙γ data of emulsions could be described well by the power-law model: τ=K˙γn. The flow behavior index n was less than 1 and it decreased sharply with the increase in Φ whereas the consistency index K increased rapidly with the increase in Φ . For a given emulsion and tube diameter, the entropy generation rate per unit tube length increased linearly with the increase in the generalized Reynolds number ( Re_n on a log-log scale. For emulsions with Φ ≤65.15 % vol., the entropy generation rate decreased with the increase in tube diameter. A reverse trend in diameter-dependence was observed for the emulsion with Φ of 72.21% vol. New models are developed for the prediction of entropy generation rate in flow of power-law emulsions in smooth tubes. The experimental data shows good agreement with the proposed models.
Influence of Droplet Size on Exergy Destruction in Flow of Concentrated Non-Newtonian Emulsions
Directory of Open Access Journals (Sweden)
Rajinder Pal
2016-04-01
Full Text Available The influence of droplet size on exergy destruction rate in flow of highly concentrated oil-in-water emulsions was investigated experimentally in a cone and plate geometry. The oil concentration was fixed at 74.5% by volume. At this dispersed-phase (oil concentration, two different droplet size emulsions were prepared: fine and coarse emulsions. The fine and coarse emulsions were mixed in different proportions to vary the droplet size distribution. Although the dispersed and matrix phases of the emulsions were Newtonian in nature, the emulsions exhibited a non-Newtonian (shear-thinning behavior due to the high droplet concentration. The shear stress—shear rate data of the emulsions could be described adequately by a power law model. At low shear rates, the exergy destruction rate per unit volume of emulsion exhibited a minimum at a fine emulsion proportion of 35%. The results from the cone and plate geometry were used to simulate exergy loss in pipeline flow of emulsions. The pumping of emulsions becomes more efficient thermodynamically upon mixing of fine and coarse emulsions provided that the flow regime is maintained to be laminar and that the Reynolds number is kept at a low to moderate value. In the turbulent regime, the exergy loss generally increases upon mixing the fine and coarse emulsions.
Rabbi, Khan Md.; Shuvo, Moinuddin; Kabir, Rabiul Hasan; Mojumder, Satyajit; Saha, Sourav
2016-07-01
Mixed convection in a lid-driven square enclosure with a rotating cylinder inside has been analyzed using non-Newtonian ferrofluid (Fe3O4-water). Left vertical wall is heated while the right vertical wall is kept cold. Bottom wall and cylinder surface are assumed to be adiabatic. Top wall has a moving lid with a constant velocity U0. Galerkin method of finite element analysis has been used to solve the governing equations. Numerical accuracy of solution is ensured by the grid independency test. A variety of Richardson number (Ri = 0.1 - 10) at a governing Reynolds number (Re = 100), power law index (n = 0.5 - 1.5), rotational speed (Ω = 0 - 15) and solid volume fraction of ferrous particles (φ = 0 - 0.05) are employed for this present problem. To illustrate flow and thermal field, streamline and isotherms are included. Average Nusselt number plots are shown to show overall heat transfer rate. It is observed that better heat transfer is achieved at higher rotational speed (Ω), Richardson number (Ri) and power law index (n). This paper also concludes significant variation in streamline and isotherm patterns for higher solid volume fraction (φ) of non-Newtonian ferrofluid.
The Construction of Hilbert Spaces over the Non-Newtonian Field
Directory of Open Access Journals (Sweden)
Uğur Kadak
2014-01-01
the novel presentations probably lead most naturally to the development of the non-Newtonian calculi. In this paper we introduce vector spaces over real and complex non-Newtonian field with respect to the *-calculus which is a branch of non-Newtonian calculus. Also we give the definitions of real and complex inner product spaces and study Hilbert spaces which are special type of normed space and complete inner product spaces in the sense of *-calculus. Furthermore, as an example of Hilbert spaces, first we introduce the non-Cartesian plane which is a nonlinear model for plane Euclidean geometry. Secondly, we give Euclidean, unitary, and sequence spaces via corresponding norms which are induced by an inner product. Finally, by using the *-norm properties of complex structures, we examine Cauchy-Schwarz and triangle inequalities.
Determination of the Köthe-Toeplitz Duals over the Non-Newtonian Complex Field
Directory of Open Access Journals (Sweden)
Uğur Kadak
2014-01-01
Full Text Available The important point to note is that the non-Newtonian calculus is a self-contained system independent of any other system of calculus. Therefore the reader may be surprised to learn that there is a uniform relationship between the corresponding operators of this calculus and the classical calculus. Several basic concepts based on non-Newtonian calculus are presented by Grossman (1983, Grossman and Katz (1978, and Grossman (1979. Following Grossman and Katz, in the present paper, we introduce the sets of bounded, convergent, null series and p-bounded variation of sequences over the complex field C* and prove that these are complete. We propose a quite concrete approach based on the notion of Köthe-Toeplitz duals with respect to the non-Newtonian calculus. Finally, we derive some inclusion relationships between Köthe space and solidness.
Determination of the Köthe-Toeplitz duals over the non-Newtonian complex field.
Kadak, Uğur
2014-01-01
The important point to note is that the non-Newtonian calculus is a self-contained system independent of any other system of calculus. Therefore the reader may be surprised to learn that there is a uniform relationship between the corresponding operators of this calculus and the classical calculus. Several basic concepts based on non-Newtonian calculus are presented by Grossman (1983), Grossman and Katz (1978), and Grossman (1979). Following Grossman and Katz, in the present paper, we introduce the sets of bounded, convergent, null series and p-bounded variation of sequences over the complex field C* and prove that these are complete. We propose a quite concrete approach based on the notion of Köthe-Toeplitz duals with respect to the non-Newtonian calculus. Finally, we derive some inclusion relationships between Köthe space and solidness.
Study on Forced Convective Heat Transfer of Non-Newtonian Nanofluids
Institute of Scientific and Technical Information of China (English)
Yurong He; Yubin Men; Xing Liu; Huilin Lu; Haisheng Chen; Yulong Ding
2009-01-01
This paper is concerned with the forced convective heat transfer of dilute liquid suspensions of nanoparticles (nanofluids) flowing through a straight pipe under laminar conditions. Stable nanofluids are formulated by using the high shear mixing and ultrasonication methods. They are then characterised for their size, surface charge, thermal and rheological properties and tested for their convective heat transfer behaviour. Mathematical model-ling is performed to simulate the convective heat transfer of nanofluids using a single phase flow model and con-sidering nanofluids as both Newtonian and non-Newtonian fluid. Both experiments and mathematical modelling show that nanofluids can substantially enhance the convective heat transfer. Analyses of the results suggest that the non-Newtonian character of nanofluids influences the overall enhancement, especially for nanofluids with an obvious non-Newtonian character.
COMPUTER SIMULATION OF NON-NEWTONIAN FLOW AND MASS TRANSPORT THROUGH CORONARY ARTERIAL STENOSIS
Institute of Scientific and Technical Information of China (English)
李新宇; 温功碧; 李丁
2001-01-01
A numerical analysis of Newtonian and non-Newtonian flow in an axi-symmetric tube with a local constriction simulating a stenosed artery under steady and pulsatile flow conditions was carried out. Based on these results, the concentration fields of LDL ( low density lipoprotein ) and Albumin were discussed. According to the results, in great details the macromolecule transport influences of wall shear stress, non-Newtonian fluid character and the scale of the molecule etc are given. The results of Newtonian fluid flow and non Newtonian fluid flow , steady flow and pulsatile flow are compared. These investigations can provide much valuable information about the correlation between the flow properties, the macromolecule transport and the development of atherosclerosis.
Stability analysis of slot-entry hybrid journal bearings operating with non-newtonian lubricant
Directory of Open Access Journals (Sweden)
H.C. Garg
2015-09-01
Full Text Available This paper presents theoretical investigations of rheological effects of lubricant on stability parameters of various configurations of slot-entry hybrid journal bearing system. FEM has been used to solve Reynolds equation governing flow of lubricant in bearing clearance space along with restrictor flow equation using suitable iterative technique. The non-Newtonian lubricant has been assumed to follow cubic shear stress law. The stability parameters in terms of stiffness coefficients, damping coefficients, threshold speed and whirl frequency of different configurations of slot-entry hybrid journal bearing have been computed and presented for wide range of external load while operating with Newtonian and Non-Newtonian lubricants. The computed results reveal that variation of viscosity due to non-Newtonian behavior of lubricant affects bearing stability quite significantly. The results are presented in graphical form and logical conclusions are drawn to identify best possible configuration from stability point of view.
2011-01-01
Many experiments have been conducted to study the hydrodynamic characteristics of column reactors and loop reactors. In this present work, a novel combined loop airlift fluidized bed reactor was developed to study the effect of superficial gas and liquid velocities, particle diameter, fluid properties on gas holdup by using Newtonian and non-Newtonian liquids. Compressed air was used as gas phase. Water, 5% n-butanol, various concentrations of glycerol (60 and 80%) were used as Newtonian liqu...
Beyond the Virtual Intracranial Stenting Challenge 2007: non-Newtonian and flow pulsatility effects.
Cavazzuti, Marco; Atherton, Mark; Collins, Michael; Barozzi, Giovanni
2010-09-17
The Virtual Intracranial Stenting Challenge 2007 (VISC'07) is becoming a standard test case in computational minimally invasive cerebrovascular intervention. Following views expressed in the literature and consistent with the recommendations of a report, the effects of non-Newtonian viscosity and pulsatile flow are reported. Three models of stented cerebral aneurysms, originating from VISC'07 are meshed and the flow characteristics simulated using commercial computational fluid dynamics (CFD) software. We conclude that non-Newtonian and pulsatile effects are important to include in order to discriminate more effectively between stent designs.
Applied holography for drop formation of non-Newtonian fluids in centrifugal atomizers
Timko, J. J.
Holography made possible the analysis of drop formation in Newtonian and non-Newtonian fluids. The drops were illuminated at the moment of their formation with an impulse ruby laser, and from the holograms the whole spray was reconstructed with a closed-circuit TV loop. From the pictures taken from different planes of the spray, the size and the spatial distribution of the drops were determined with an electrooptical analyzer. The holographic measuring method provided quantitative data phenomena which were qualitatively observable on high-speed films. The experiments also verified an equation involving dimensionless criteria, deduced fo the atomization of non-Newtonian substances.
A fractional model for time-variant non-Newtonian flow
Directory of Open Access Journals (Sweden)
Yang Xu
2017-01-01
Full Text Available This work applies a fractional flow model to describe a time-variant behavior of non-Newtonian substances. Specifically, we model the physical mechanism underlying the thixotropic and anti-thixotropic phenomena of non-Newtonian flow. This study investigates the behaviors of cellulose suspensions and SMS pastes under constant shear rate. The results imply that the presented model with only two parameters is adequate to fit experimental data. Moreover, the parameter of fractional order is an appropriate index to characterize the state of given substances. Its value indicates the extent of thixotropy and anti-thixotropy with positive and negative order respectively.
Stagnation point flow of an non-Newtonian visco-elastic fluid
Energy Technology Data Exchange (ETDEWEB)
Teipel, I. [Univ. of Hannover, Inst. of Mechanics, Hannover (Germany)
1985-07-01
In this paper the flow near a two-dimensional stagnation point for a particular non-Newtonian fluid has been studied. Non-Newtonian fluids form a wide class of different materials, which will be used very often in chemical industries. From a practical point of view it is of great importance to obtain some results for example concerning the flow rate and the losses in a tube, the drag and the separation point of a boundary layer flow etc. for such fluids. Therefore it is necessary to assume a particular constitutive equation to calculate various aspects. (author)
Stretch flow of confined non-Newtonian fluids: nonlinear fingering dynamics.
Brandão, Rodolfo; Fontana, João V; Miranda, José A
2013-12-01
We employ a weakly nonlinear perturbative scheme to investigate the stretch flow of a non-Newtonian fluid confined in Hele-Shaw cell for which the upper plate is lifted. A generalized Darcy's law is utilized to model interfacial fingering formation in both the weak shear-thinning and weak shear-thickening limits. Within this context, we analyze how the interfacial finger shapes and the nonlinear competition dynamics among fingers are affected by the non-Newtonian nature of the stretched fluid.
Validation of computational non-Newtonian fluid model for membrane bioreactor
DEFF Research Database (Denmark)
Sørensen, Lasse; Bentzen, Thomas Ruby; Skov, Kristian
2015-01-01
for optimizing MBR-systems is computational fluid dynamics (CFD) modelling, giving the ability to describe the flow in the systems. A parameter which is often neglected in such models is the non-Newtonian properties of active sludge, which is of great importance for MBR systems since they operate at sludge...... concentrations up to a factor 10 compared to conventional activated sludge (CAS) systems, resulting in strongly shear thinning liquids. A CFD-model is validated against measurements conducted in a system with rotating cross flow membranes submerged in non-Newtonian liquids, where tangential velocities...
Entropy generation in non-Newtonian ﬂuid ﬂow in a slider bearing
Indian Academy of Sciences (India)
M Pakdemirli; B S Yilbas; M Yurusoy
2004-12-01
In the present study, entropy production in ﬂow ﬁelds due to slider bearings is formulated. The rate of entropy generation is computed for different ﬂuid properties and geometric conﬁgurations of the slider bearing. In order to account for the non-Newtonian effect, a special type of third-grade ﬂuid is considered. It is found that the rate of entropy generation is inﬂuenced signiﬁcantly by the height of the bearing clearance and the non-Newtonian parameter of the ﬂuid.
Experimental model for non-Newtonian fluid viscosity estimation: Fit to mathematical expressions
Directory of Open Access Journals (Sweden)
Guillem Masoliver i Marcos
2017-01-01
Full Text Available The construction process of a viscometer, developed in collaboration with a final project student, is here presented. It is intended to be used by first year's students to know the viscosity as a fluid property, for both Newtonian and non-Newtonian flows. Viscosity determination is crucial for the fluids behaviour knowledge related to their reologic and physical properties. These have great implications in engineering aspects such as friction or lubrication. With the present experimental model device three different fluids are analyzed (water, kétchup and a mixture with cornstarch and water. Tangential stress is measured versus velocity in order to characterize all the fluids in different thermal conditions. A mathematical fit process is proposed to be done in order to adjust the results to expected analytical expressions, obtaining good results for these fittings, with R2 greater than 0.88 in any case.
The wall shear rate in non-Newtonian turbulent pipe flow
Trinh, K T
2010-01-01
This paper presents a method for calculating the wall shear rate in pipe turbulent flow. It collapses adequately the data measured in laminar flow and turbulent flow into a single flow curve and gives the basis for the design of turbulent flow viscometers. Key words: non-Newtonian, wall shear rate, turbulent, rheometer
Pulsatile Non-Newtonian Laminar Blood Flows through Arterial Double Stenoses
Directory of Open Access Journals (Sweden)
Mir Golam Rabby
2014-01-01
Full Text Available The paper presents a numerical investigation of non-Newtonian modeling effects on unsteady periodic flows in a two-dimensional (2D pipe with two idealized stenoses of 75% and 50% degrees, respectively. The governing Navier-Stokes equations have been modified using the Cartesian curvilinear coordinates to handle complex geometries. The investigation has been carried out to characterize four different non-Newtonian constitutive equations of blood, namely, the (i Carreau, (ii Cross, (iii Modified Casson, and (iv Quemada models. The Newtonian model has also been analyzed to study the physics of fluid and the results are compared with the non-Newtonian viscosity models. The numerical results are represented in terms of streamwise velocity, pressure distribution, and wall shear stress (WSS as well as the vorticity, streamlines, and vector plots indicating recirculation zones at the poststenotic region. The results of this study demonstrate a lower risk of thrombogenesis at the downstream of stenoses and inadequate blood supply to different organs of human body in the Newtonian model compared to the non-Newtonian ones.
Free surface flow of a suspension of rigid particles in a non-Newtonian fluid
DEFF Research Database (Denmark)
Svec, Oldrich; Skocek, Jan; Stang, Henrik
2012-01-01
A numerical framework capable of predicting the free surface flow of a suspension of rigid particles in a non-Newtonian fluid is described. The framework is a combination of the lattice Boltzmann method for fluid flow, the mass tracking algorithm for free surface representation, the immersed...
Application of the homotopy method for analytical solution of non-Newtonian channel flows
Energy Technology Data Exchange (ETDEWEB)
Roohi, Ehsan [Department of Aerospace Engineering, Sharif University of Technology, PO Box 11365-8639, Azadi Avenue, Tehran (Iran, Islamic Republic of); Kharazmi, Shahab [Department of Mechanical Engineering, Sharif University of Technology, PO Box 11365-8639, Azadi Avenue, Tehran (Iran, Islamic Republic of); Farjami, Yaghoub [Department of Computer Engineering, University of Qom, Qom (Iran, Islamic Republic of)], E-mail: roohi@sharif.edu
2009-06-15
This paper presents the homotopy series solution of the Navier-Stokes and energy equations for non-Newtonian flows. Three different problems, Couette flow, Poiseuille flow and Couette-Poiseuille flow have been investigated. For all three cases, the nonlinear momentum and energy equations have been solved using the homotopy method and analytical approximations for the velocity and the temperature distribution have been obtained. The current results agree well with those obtained by the homotopy perturbation method derived by Siddiqui et al (2008 Chaos Solitons Fractals 36 182-92). In addition to providing analytical solutions, this paper draws attention to interesting physical phenomena observed in non-Newtonian channel flows. For example, it is observed that the velocity profile of non-Newtonian Couette flow is indistinctive from the velocity profile of the Newtonian one. Additionally, we observe flow separation in non-Newtonian Couette-Poiseuille flow even though the pressure gradient is negative (favorable). We provide physical reasoning for these unique phenomena.
On line and double integrals in the non-Newtonian sense
ćakmak, Ahmet Faruk; Başar, Feyzi
2014-08-01
This paper is devoted to line and double integrals in the sense of non-Newtonian calculus (*-calculus). Moreover, in the sense of *-calculus, the fundamental theorem of calculus for line integrals and double integrals are stated and proved, and some applications are presented.
Binous, Housam
2007-01-01
We study four non-Newtonian fluid mechanics problems using Mathematica[R]. Constitutive equations describing the behavior of power-law, Bingham and Carreau models are recalled. The velocity profile is obtained for the horizontal flow of power-law fluids in pipes and annuli. For the vertical laminar film flow of a Bingham fluid we determine the…
Revisiting Newtonian and Non-Newtonian Fluid Mechanics Using Computer Algebra
Knight, D. G.
2006-01-01
This article illustrates how a computer algebra system, such as Maple[R], can assist in the study of theoretical fluid mechanics, for both Newtonian and non-Newtonian fluids. The continuity equation, the stress equations of motion, the Navier-Stokes equations, and various constitutive equations are treated, using a full, but straightforward,…
HARNACK ESTIMATES FOR WEAK SOLUTIONSOFEQUATIONS OF NON-NEWTONIAN POLYTROPIC FILTRATION
Institute of Scientific and Technical Information of China (English)
无
2001-01-01
An intrinsic Harnack estimate and some sup-estimates are established for nonnegative weak solutions of equations of non-Newtonian polytropic filtration ut -div(｜Dum ｜p-2Dum) =0, m(p- 1) ＜ 1, m＞0, p＞ 1.
RANDOM ATTRACTOR FOR A TWO-DIMENSIONAL INCOMPRESSIBLE NON-NEWTONIAN FLUID WITH MULTIPLICATIVE NOISE
Institute of Scientific and Technical Information of China (English)
Zhao Caidi; Li Yongsheng; Zhou Shengfan
2011-01-01
This article proves that the random dynamical system generated by a two- dimensional incompressible non-Newtonian fluid with multiplicative noise has a global random attractor, which is a random compact set absorbing any bounded nonrandom subset of the phase space.
Modeling of flow of particles in a non-Newtonian fluid using lattice Boltzmann method
DEFF Research Database (Denmark)
Skocek, Jan; Svec, Oldrich; Spangenberg, Jon
2011-01-01
is necessary. In this contribution, the model at the scale of aggregates is introduced. The conventional lattice Boltzmann method for fluid flow is enriched with the immersed boundary method with direct forcing to simulate the flow of rigid particles in a non- Newtonian liquid. Basic ingredients of the model...
Learning about Non-Newtonian Fluids in a Student-Driven Classroom
Dounas-Frazer, D. R.; Lynn, J.; Zaniewski, A. M.; Roth, N.
2013-01-01
We describe a simple, low-cost experiment and corresponding pedagogical strategies for studying fluids whose viscosities depend on shear rate, referred to as "non-Newtonian fluids." We developed these materials teaching for the Compass Project, an organization that fosters a creative, diverse, and collaborative community of science…
Unsteady Non-Newtonian Solver on Unstructured Grid for the Simulation of Blood Flow
Directory of Open Access Journals (Sweden)
Guojie Li
2013-01-01
Full Text Available Blood is in fact a suspension of different cells with yield stress, shear thinning, and viscoelastic properties, which can be represented by different non-Newtonian models. Taking Casson fluid as an example, an unsteady solver on unstructured grid for non-Newtonian fluid is developed to simulate transient blood flow in complex flow region. In this paper, a steady solver for Newtonian fluid is firstly developed with the discretization of convective flux, diffusion flux, and source term on unstructured grid. For the non-Newtonian characteristics of blood, the Casson fluid is approximated by the Papanastasiou's model and treated as Newtonian fluid with variable viscosity. Then considering the transient property of blood flow, an unsteady non-Newtonian solver based on unstructured grid is developed by introducing the temporal term by first-order upwind difference scheme. Using the proposed solver, the blood flows in carotid bifurcation of hypertensive patients and healthy people are simulated. The result shows that the possibility of the genesis and development of atherosclerosis is increased, because of the increase in incoming flow shock and backflow areas of the hypertensive patients, whose WSS was 20~87.1% lower in outer vascular wall near the bifurcation than that of the normal persons and 3.7~5.5% lower in inner vascular wall downstream the bifurcation.
Binous, Housam
2007-01-01
We study four non-Newtonian fluid mechanics problems using Mathematica[R]. Constitutive equations describing the behavior of power-law, Bingham and Carreau models are recalled. The velocity profile is obtained for the horizontal flow of power-law fluids in pipes and annuli. For the vertical laminar film flow of a Bingham fluid we determine the…
Revisiting Newtonian and Non-Newtonian Fluid Mechanics Using Computer Algebra
Knight, D. G.
2006-01-01
This article illustrates how a computer algebra system, such as Maple[R], can assist in the study of theoretical fluid mechanics, for both Newtonian and non-Newtonian fluids. The continuity equation, the stress equations of motion, the Navier-Stokes equations, and various constitutive equations are treated, using a full, but straightforward,…
A Colorful Mixing Experiment in a Stirred Tank Using Non-Newtonian Blue Maize Flour Suspensions
Trujilo-de Santiago, Grissel; Rojas-de Gante, Cecillia; García-Lara, Silverio; Ballesca´-Estrada, Adriana; Alvarez, Marion Moise´s
2014-01-01
A simple experiment designed to study mixing of a material of complex rheology in a stirred tank is described. Non-Newtonian suspensions of blue maize flour that naturally contain anthocyanins have been chosen as a model fluid. These anthocyanins act as a native, wide spectrum pH indicator exhibiting greenish colors in alkaline environments, blue…
Heat Transfer of Non-Newtonian Dilatant Power Law Fluids in Square and Rectangular Cavities
Directory of Open Access Journals (Sweden)
I. Vinogradov
2011-01-01
Full Text Available Steady two-dimensional natural convection in fluid filled cavities is numerically investigated for the case of non- Newtonian shear thickening power law liquids. The conservation equations of mass, momentum and energy under the assumption of a Newtonian Boussinesq fluid have been solved using the finite volume method for Newtonian and non-Newtonian fluids. The computations were performed for a Rayleigh number, based on cavity height, of 105 and a Prandtl number of 100. In all of the numerical experiments, the channel is heated from below and cooled from the top with insulated side-walls and the inclination angle is varied. The simulations have been carried out for aspect ratios of 1 and 4. Comparison between the Newtonian and the non-Newtonian cases is conducted based on the dependence of the average Nusselt number on angle of inclination. It is shown that despite significant variation in heat transfer rate both Newtonian and non-Newtonian fluids exhibit similar behavior with the transition from multi-cell flow structure to a single-cell regime.
Directory of Open Access Journals (Sweden)
Sivakumar Venkatachalam
2011-09-01
Full Text Available Many experiments have been conducted to study the hydrodynamic characteristics of column reactors and loop reactors. In this present work, a novel combined loop airlift fluidized bed reactor was developed to study the effect of superficial gas and liquid velocities, particle diameter, fluid properties on gas holdup by using Newtonian and non-Newtonian liquids. Compressed air was used as gas phase. Water, 5% n-butanol, various concentrations of glycerol (60 and 80% were used as Newtonian liquids, and different concentrations of carboxy methyl cellulose aqueous solutions (0.25, 0.6 and 1.0% were used as non-Newtonian liquids. Different sizes of spheres, Bearl saddles and Raschig rings were used as solid phases. From the experimental results, it was found that the increase in superficial gas velocity increases the gas holdup, but it decreases with increase in superficial liquid velocity and viscosity of liquids. Based on the experimental results a correlation was developed to predict the gas hold-up for Newtonian and non-Newtonian liquids for a wide range of operating conditions at a homogeneous flow regime where the superficial gas velocity is approximately less than 5 cm/s
Studying mixing in Non-Newtonian blue maize flour suspensions using color analysis.
Trujillo-de Santiago, Grissel; Rojas-de Gante, Cecilia; García-Lara, Silverio; Ballescá-Estrada, Adriana; Alvarez, Mario Moisés
2014-01-01
Non-Newtonian fluids occur in many relevant flow and mixing scenarios at the lab and industrial scale. The addition of acid or basic solutions to a non-Newtonian fluid is not an infrequent operation, particularly in Biotechnology applications where the pH of Non-Newtonian culture broths is usually regulated using this strategy. We conducted mixing experiments in agitated vessels using Non-Newtonian blue maize flour suspensions. Acid or basic pulses were injected to reveal mixing patterns and flow structures and to follow their time evolution. No foreign pH indicator was used as blue maize flours naturally contain anthocyanins that act as a native, wide spectrum, pH indicator. We describe a novel method to quantitate mixedness and mixing evolution through Dynamic Color Analysis (DCA) in this system. Color readings corresponding to different times and locations within the mixing vessel were taken with a digital camera (or a colorimeter) and translated to the CIELab scale of colors. We use distances in the Lab space, a 3D color space, between a particular mixing state and the final mixing point to characterize segregation/mixing in the system. Blue maize suspensions represent an adequate and flexible model to study mixing (and fluid mechanics in general) in Non-Newtonian suspensions using acid/base tracer injections. Simple strategies based on the evaluation of color distances in the CIELab space (or other scales such as HSB) can be adapted to characterize mixedness and mixing evolution in experiments using blue maize suspensions.
Studying mixing in Non-Newtonian blue maize flour suspensions using color analysis.
Directory of Open Access Journals (Sweden)
Grissel Trujillo-de Santiago
Full Text Available BACKGROUND: Non-Newtonian fluids occur in many relevant flow and mixing scenarios at the lab and industrial scale. The addition of acid or basic solutions to a non-Newtonian fluid is not an infrequent operation, particularly in Biotechnology applications where the pH of Non-Newtonian culture broths is usually regulated using this strategy. METHODOLOGY AND FINDINGS: We conducted mixing experiments in agitated vessels using Non-Newtonian blue maize flour suspensions. Acid or basic pulses were injected to reveal mixing patterns and flow structures and to follow their time evolution. No foreign pH indicator was used as blue maize flours naturally contain anthocyanins that act as a native, wide spectrum, pH indicator. We describe a novel method to quantitate mixedness and mixing evolution through Dynamic Color Analysis (DCA in this system. Color readings corresponding to different times and locations within the mixing vessel were taken with a digital camera (or a colorimeter and translated to the CIELab scale of colors. We use distances in the Lab space, a 3D color space, between a particular mixing state and the final mixing point to characterize segregation/mixing in the system. CONCLUSION AND RELEVANCE: Blue maize suspensions represent an adequate and flexible model to study mixing (and fluid mechanics in general in Non-Newtonian suspensions using acid/base tracer injections. Simple strategies based on the evaluation of color distances in the CIELab space (or other scales such as HSB can be adapted to characterize mixedness and mixing evolution in experiments using blue maize suspensions.
Entropy generation in a pipe due to non-Newtonian ﬂuid ﬂow: Constant viscosity case
Indian Academy of Sciences (India)
M Pakdemirli; B S Yilbas
2006-02-01
Non-Newtonian ﬂuid ﬂow in a pipe system is considered and a third grade non-Newtonian ﬂuid is employed in the analysis. The velocity and temperature distributions across the pipe are presented. Entropy generation number due to heat transfer and ﬂuid friction is formulated. The inﬂuences of non-Newtonian parameter and Brinkman number on entropy generation number are examined. It is found that increasing the non-Newtonian parameter reduces the ﬂuid friction in the region close to the pipe wall. This in turn results in low entropy generation with increasing non-Newtonian parameter. Increasing Brinkman number enhances the ﬂuid friction and heat transfer rates; in which case, entropy number increases with increasing Brinkman number.
A modelling and experimental study of the bubble trajectory in a non-Newtonian crystal suspension
Energy Technology Data Exchange (ETDEWEB)
Hassan, N M S [Process Engineering and Light Metals (PELM) Centre, Faculty of Sciences, Engineering and Health, CQUniversity, Rockhampton, QLD 4702 (Australia); Khan, M M K; Rasul, M G, E-mail: m.rasul@cqu.edu.a [School of Engineering and Built Environment, Faculty of Sciences, Engineering and Health, CQUniversity, Rockhampton, QLD 4702 (Australia)
2010-12-15
This paper presents an experimental and computational study of air bubbles rising in a massecuite-equivalent non-Newtonian crystal suspension. The bubble trajectory inside the stagnant liquid of a 0.05% xanthan gum crystal suspension was investigated and modelled using the computational fluid dynamics (CFD) model to gain an insight into the bubble flow characteristics. The CFD code FLUENT was used for numerical simulation, and the bubble trajectory calculations were performed through a volume of fluid (VOF) model. The influences of the Reynolds number (Re), the Weber number (We) and the bubble aspect ratio (E) on the bubble trajectory are discussed. The conditions for the bubbles' path oscillations are identified. The experimental results showed that the path instability for the crystal suspension was less rapid than in water. The trajectory analysis indicated that 5.76 mm diameter bubbles followed a zigzag motion in the crystal suspension. Conversely, the smaller bubbles (5.76 mm) followed a path of least horizontal movement and larger bubbles (21.21 mm) produced more spiral motion within the crystal suspension. Path instability occurred for bubbles of 15.63 and 21.21 mm diameter, and they induced both zigzag and spiral trajectories within the crystal suspension. At low Re and We, smaller bubbles (5.76 mm) produced a zigzag trajectory, whereas larger bubbles (15.63 and 21.21 mm) showed both zigzag and spiral trajectories at intermediate and moderately high Re and We in the crystal suspension. The simulation results illustrated that a repeating pattern of swirling vortices was created for smaller bubbles due to the unstable wake and unsteady flow of these bubbles. This is the cause of the smaller bubbles moving in a zigzag way. Larger bubbles showed two counter-rotating trailing vortices at the back of the bubble. These vortices induced a velocity component to the gas-liquid interface and caused a deformation. Hence, the larger bubbles produced a path
Energy Technology Data Exchange (ETDEWEB)
Mey, Paula; Varges, Priscilla R.; Mendes, Paulo R. de Souza [Dept. of Mechanical Engineering. Pontificia Universidade Catolica do RJ (PUC-Rio), RJ (Brazil)], e-mails: prvarges@puc-rio.br, pmendes@puc-rio.br
2010-07-01
This research looked for a method to determine the binary diffusion coefficient D of salts in liquids (especially in drilling fluids) not only accurately, but in a reasonable time. We chose to use the Taylor Dispersion Method. This technique has been used for measuring binary diffusion coefficients in gaseous, liquid and supercritical fluids, due to its simplicity and accuracy. In the method, the diffusion coefficient is determined by the analysis of the dispersion of a pulse of soluble material in a solvent flowing laminarly through a tube. This work describes the theoretical basis and the experimental requirements for the application of the Taylor Dispersion Method, emphasizing the description of our experiment. A mathematical formulation for both Newtonian and non-Newtonian fluids is presented. The relevant sources of errors are discussed. The experimental procedure and associated analysis are validated by applying the method in well known systems, such as NaCl in water.D of salts in liquids (especially in drilling fluids) not only accurately, but in a reasonable time. We chose to use the Taylor Dispersion Method. This technique has been used for measuring binary diffusion coefficients in gaseous, liquid and supercritical fluids, due to its simplicity and accuracy. In the method, the diffusion coefficient is determined by the analysis of the dispersion of a pulse of soluble material in a solvent flowing laminarly through a tube. This work describes the theoretical basis and the experimental requirements for the application of the Taylor Dispersion Method, emphasizing the description of our experiment. A mathematical formulation for both Newtonian and non-Newtonian fluids is presented. The relevant sources of errors are discussed. The experimental procedure and associated analysis are validated by applying the method in well known systems, such as NaCl in water. (author)
Newtonian to non-Newtonian flow transition in lung surfactants
Sadoughi, Amir; Hirsa, Amir; Lopez, Juan
2010-11-01
The lining of normal lungs is covered by surfactants, because otherwise the surface tension of the aqueous layer would be too large to allow breathing. A lack of functioning surfactants can lead to respiratory distress syndrome, a potentially fatal condition in both premature infants and adults, and a major cause of death in the US and world-wide. We use a home-built Brewster angle microscope on an optically accessible deep channel viscometer to simultaneously observe the mesoscale structures of DPPC, the primary constituent of lung surfactant, on water surface and measure the interfacial velocity field. The measured interfacial velocity is compared to Navier-Stokes computations with the Boussinesq-Scriven surface model. Results show that DPPC monolayer behaves i) purely elastically at low surface pressures on water, ii) viscoelastically at modest surface pressures, exhibiting non-zero surface shear viscosity that is independent of the shear rate and flow inertia, and iii) at surface pressures approaching film collapse, DPPC loses its fluid characteristics, and a Newtonian surface model no longer captures its hydrodynamics.
Golykh, R. N.
2016-06-01
Progress of technology and medicine dictates the ever-increasing requirements (heat resistance, corrosion resistance, strength properties, impregnating ability, etc.) for non-Newtonian fluids and materials produced on their basis (epoxy resin, coating materials, liquid crystals, etc.). Materials with improved properties obtaining is possible by modification of their physicochemical structure. One of the most promising approaches to the restructuring of non-Newtonian fluids is cavitation generated by high-frequency acoustic vibrations. The efficiency of cavitation in non-Newtonian fluid is determined by dynamics of gaseous bubble. Today, bubble dynamics in isotropic non-Newtonian fluids, in which cavitation bubble shape remains spherical, is most full investigated, because the problem reduces to ordinary differential equation for spherical bubble radius. However, gaseous bubble in anisotropic fluids which are most wide kind of non-Newtonian fluids (due to orientation of macromolecules) deviates from spherical shape due to viscosity dependence on shear rate direction. Therefore, the paper presents the mathematical model of gaseous bubble dynamics in anisotropic non-Newtonian fluids. The model is based on general equations for anisotropic non-Newtonian fluid flow. The equations are solved by asymptotic decomposition of fluid flow parameters. It allowed evaluating bubble size and shape evolution depending on rheological properties of liquid and acoustic field characteristics.
Wall effects on the terminal velocity of spherical particles in Newtonian and non-Newtonian fluids
Directory of Open Access Journals (Sweden)
ATAÍDE C. H.
1999-01-01
Full Text Available The objective of this work is to study the effect of confining walls on the free settling of spherical particles along the axes of five vertical cylindrical tubes in Newtonian and non-Newtonian liquids. Experimental results were predominantly obtained in the particle flow region between the Stokes and the Newton regimes (intermediate region and displayed Reynolds numbers in the ranges 0.7
On predicting the onset of transient convection in porous media saturated with Non-Newtonian liquid
Tan, K. K.; Pua, S. Y.; Yang, A.
2017-06-01
The onset of transient convection in non-Newtonian liquid immersing porous media was simulated using a Computational Fluid Dynamics (CFD) package for the thermal boundary condition of Fixed Surface Temperature (FST). Most of the simulated values of stability criteria were found to be in good agreement with the predicted and theoretical values of transient critical Rayleigh number for non-Newtonian liquid defined by Tan and Thorpe (1992) for power-law fluids. The critical transient Rayleigh numbers for convection in porous media were found to be in good agreement with theoretical values by using apparent viscosity µapp at zero shear. The critical time and critical depth for transient heat conduction were then determined accurately that
FDA's nozzle numerical simulation challenge: non-Newtonian fluid effects and blood damage.
Trias, Miquel; Arbona, Antonio; Massó, Joan; Miñano, Borja; Bona, Carles
2014-01-01
Data from FDA's nozzle challenge-a study to assess the suitability of simulating fluid flow in an idealized medical device-is used to validate the simulations obtained from a numerical, finite-differences code. Various physiological indicators are computed and compared with experimental data from three different laboratories, getting a very good agreement. Special care is taken with the derivation of blood damage (hemolysis). The paper is focused on the laminar regime, in order to investigate non-Newtonian effects (non-constant fluid viscosity). The code can deal with these effects with just a small extra computational cost, improving Newtonian estimations up to a ten percent. The relevance of non-Newtonian effects for hemolysis parameters is discussed.
Gupta, Renu; Bansal, Ajay
2013-08-01
Axial dispersion is an important parameter in the performance of packed bed reactors. A lot of fluids exhibit non-Newtonian behaviour but the effect of rheological parameters on axial dispersion is not available in literature. The effect of rheology on axial dispersion has been analysed for viscoinelastic and viscoelastic non-Newtonian fluids. Aqueous solutions of carboxymethyl cellulose and polyacrylamide have been chosen to represent viscoinelastic and viscoelastic liquid-phases. Axial dispersion has been measured in terms of BoL number. The single parameter axial dispersion model has been applied to analyse RTD response curve. The BoL numbers were observed to increase with increase in liquid flow rate and consistency index 'K' for viscoinelastic as well as viscoelastic fluids. Bodenstein correlation for Newtonian fluids proposed has been modified to account for the effect of fluid rheology. Further, Weissenberg number is introduced to quantify the effect of viscoelasticity.
Turbulent Characteristic of Liquid Around a Chain of Bubbles in Non-Newtonian Fluid
Institute of Scientific and Technical Information of China (English)
李少白; 马友光; 朱春英; 付涛涛; 李怀志
2012-01-01
The turbulence behavior of gas-liquid two-phase flow plays an important role in heat transfer and mass transfer in many chemical processes. In this work, a 2D particle image velocimetry (PIV) was used to investigate the turbulent characteristic of fluid induced by a chain of bubbles rising in Newtonian and non-Newtonian fluids. The instantaneous flow field, turbulent kinetic energy (TKE) and TKE dissipation rate were measured. The results demonstrated that the TKE profiles were almost symmetrical along the column center and showed higher values in the central region of the column. The TKE was enhanced with the increase of gas flow and decrease of liquid viscosity. The maximum TKE dissipation rate appeared on both sides of the bubble chain, and increased with the increase of gas flow rate or liquid viscosity. These results provide an understanding for gas-liquid mass transfer in non-Newtonian fluids.
A comparison of numerical methods for non-Newtonian fluid flows in a sudden expansion
Ilio, G. Di; Chiappini, D.; Bella, G.
2016-06-01
A numerical study on incompressible laminar flow in symmetric channel with sudden expansion is conducted. In this work, Newtonian and non-Newtonian fluids are considered, where non-Newtonian fluids are described by the power-law model. Three different computational methods are employed, namely a semi-implicit Chorin projection method (SICPM), an explicit algorithm based on fourth-order Runge-Kutta method (ERKM) and a Lattice Boltzmann method (LBM). The aim of the work is to investigate on the capabilities of the LBM for the solution of complex flows through the comparison with traditional computational methods. In the range of Reynolds number investigated, excellent agreement with the literature results is found. In particular, the LBM is found to be accurate in the prediction of the fluid flow behavior for the problem under consideration.
Non-Newtonian ﬂuid ﬂow in annular pipes and entropy generation: Temperature-dependent viscosity
Indian Academy of Sciences (India)
M Yürüsoy; B S Yilbaş; M Pakdemirli
2006-12-01
Non-Newtonian ﬂuid ﬂow in annular pipes is considered and the entropy generation due to ﬂuid friction and heat transfer in them is formulated. A third-grade ﬂuid is employed to account for the non-Newtonian effect, while the Reynolds model is accommodated for temperature-dependent viscosity. Closed-form solutions for velocity, temperature, and entropy ﬁelds are presented. It is found that entropy generation number increases with reducing non-Newtonian parameter, while it is the reverse for the viscosity parameter, which is more pronounced in the region close to the annular pipe inner wall.
Directory of Open Access Journals (Sweden)
Yan Zhang
2011-01-01
Full Text Available The problem of steady, laminar, thermal Marangoni convection flow of non-Newtonian power law fluid along a horizontal surface with variable surface temperature is studied. The partial differential equations are transformed into ordinary differential equations by using a suitable similarity transformation and analytical approximate solutions are obtained by an efficient transformation, asymptotic expansion and Padé approximants technique. The effects of power law index and Marangoni number on velocity and temperature profiles are examined and discussed.
Matrix Transformations between Certain Sequence Spaces over the Non-Newtonian Complex Field
Uğur Kadak; Hakan Efe
2014-01-01
In some cases, the most general linear operator between two sequence spaces is given by an infinite matrix. So the theory of matrix transformations has always been of great interest in the study of sequence spaces. In the present paper, we introduce the matrix transformations in sequence spaces over the field C* and characterize some classes of infinite matrices with respect to the non-Newtonian calculus. Also we give the necessary and sufficient conditions on an infinite matrix ...
Oscillatory Spreading and Surface Instability of a Non-Newtonian Fluid under Compression
Choudhury, Moutushi Dutta; Chandra, Subrata; Nag, Soma; Das, Shantanu; Tarafdar, Sujata
2010-01-01
Starch solutions, which are strongly non-Newtonian, show a surface instability, when subjected to a load. A droplet of the fluid is sandwiched between two glass plates and a weight varying from 1 to 5 kgs. is placed on the top plate. The area of contact between the fluid and plate increases in an oscillatory manner, unlike Newtonian fluids in a similar situation. The periphery moreover, develops a viscous fingering like instability, which is not expected under compression. We attempt to model...
Non-Newtonian Momentum Transfer past an Isothermal Stretching Sheet with Applied Suction
Veena, P. H.; Suresh, B.; Pravin, V. K.; Goud, A. M.
2017-08-01
The paper discusses the flow of an incompressible non-Newtonian fluid due to stretching of a plane elastic surface in a saturated porous medium in the approximation of boundary layer theory. An exact analytical solution of non-linear MHD momentum equation governing the self-similar flow is given. The skin friction co-efficient decreases with an increase in the visco-elastic parameter k1 and increase in the values of both the magnetic parameter and permeability parameter.
Simulation of Non-Newtonian Blood Flow by Lattice Boltzman Method
Institute of Scientific and Technical Information of China (English)
JI Yu-Pin; KANG Xiu-Ying; LIU Da-He
2010-01-01
@@ Blood flow under various conditions of vessel is simulated as a non-Newtonian fluid by the two-dimensional Lattice Boltzmann method,in which the Casson model is used to express the relationship between viscosity and shear rate of the blood.The flow field distributions at certain sites near the narrowing and bifurcation of the vessel explain the hemodynamic mechanism of the preclilection of the atherosclerotic lesions for these sites which are consistent with that found by medical studies.
Flow non-normality-induced transient growth in superposed Newtonian and non-Newtonian fluid layers
Ridolfi, Luca; Camporeale, Carlo Vincenzo
2009-01-01
In recent years non-normality and transient growths have attracted much interest in fluid mechanics. Here, we investigate these topics with reference to the problem of interfacial instability in superposed Newtonian and non-Newtonian fluid layers. Under the hypothesis of the lubrication theory, we demonstrate the existence of significant transient growths in the parameter space region where the dynamical system is asymptotically stable, and show how they depend on the main physical parameters...
Classical XY model with conserved angular momentum is an archetypal non-Newtonian fluid.
Evans, R M L; Hall, Craig A; Simha, R Aditi; Welsh, Tom S
2015-04-03
We find that the classical one-dimensional XY model, with angular-momentum-conserving Langevin dynamics, mimics the non-Newtonian flow regimes characteristic of soft matter when subjected to counterrotating boundaries. An elaborate steady-state phase diagram has continuous and first-order transitions between states of uniform flow, shear-banding, solid-fluid coexistence and slip planes. Results of numerical studies and a concise mean-field constitutive relation offer a paradigm for diverse nonequilibrium complex fluids.
BLOW-UP ESTIMATES FOR A NON-NEWTONIAN FILTRATION SYSTEM
Institute of Scientific and Technical Information of China (English)
杨作东; 陆启韶
2001-01-01
The prior estimate and decay property of positive solutions are derived for a system of quasi-linear elliptic differential equations first. Hence, the result of non-existence for differential equation system of radially nonincreasing positive solutions is implied. By using this non-existence result, blow-up estimates for a class quasi-linear reaction-diffusion systems (non-Newtonian filtration systems ) are established, which extends the result of semi- linear reaction- diffusion ( Fujita type ) systems .
Institute of Scientific and Technical Information of China (English)
Zhongping LI; Wanjuan DU; Chunlai MU
2013-01-01
In this paper,we first find finite travelling-wave solutions,and then investigate the short time development of interfaces for non-Newtonian diffusion equations with strong absorption.We show that the initial behavior of the interface depends on the concentration of the mass of u(x,0) near x =0.More precisely,we find a critical value of the concentration,which separates the heating front of interfaces from the cooling front of them.
Theoretical aspects of non-newtonian fluids flow simulation in food technologies
Directory of Open Access Journals (Sweden)
E. Biletskii
2015-05-01
Full Text Available Introduction. The problems of simulating viscoplastic longitudinal and cross-sectional flow of non-Newtonian fluids are overviewed. Materials and methods. For the first time the superposition method by expressing the components of the stress tensor for building flow fields with higher dimension from flow fields with lower dimension with various boundary conditions when rheological parameters change depending on pressure was used. The flows in the channel are categorized by velocity and pressure values in each point of the section. Results.The theoretical methods for simulating flows of non-Newtonian fluids in channels of different geometry with moving bounds and pressure drop on channel edges with respect to functional connections between main process parameters are described using the superposition method. It is shown that longitudinal and cross-sectional are reduced to the collection of one-dimensional longitudinal flows of the same type which allow to describe three-dimensional isothermal in rectangular channel and two-dimensional flows in flat channels with different channel aspect ratio. The received theoretical two- and three-dimensional model of viscous flows in channels with basic geometry allow to research main regularities of the process and to establish optimal macro-kinetic and macro-dynamic flow characteristics of non-Newtonian materials which are aimed at reducing energy costs and material consumption of food processing equipment. Conclusion.The developed and theoretically reasonable three-dimensional models flows of non-Newtonian fluids in channels allow to perform qualitatively new design of food processing equipment which allows to reduce energy costs and material consumption.
Investigating the impact of non-Newtonian blood models within a heart pump.
Al-Azawy, Mohammed G; Turan, A; Revell, A
2017-01-01
A detailed computational fluid dynamics (CFD) study of transient, turbulent blood flow through a positive displacement left ventricular assist device is performed. Two common models for non-Newtonian blood flow are compared to the Newtonian model to investigate their impact on predicted levels of shear rate and wall shear stress. Given that both parameters are directly relevant to the evaluation of risk from thrombus and haemolysis, there is a need to assess the sensitivity to modelling non-Newtonian flow effects within a pulsatile turbulent flow, in order to identify levels of uncertainly in CFD. To capture the effects of turbulence, the elliptic blending Reynolds stress model is used in the present study, on account of superior performance of second moment closure schemes previously identified by the present authors. The CFD configuration includes two cyclically rotating valves and a moving pusher plate to periodically vary the chamber volume. An overset mesh algorithm is used for each instance of mesh motion, and a zero gap technique was employed to ensure full valve closure. The left ventricular assist device was operated at a pumping rate of 86 BPM (beats per minute) and a systolic duration of 40% of the pumping cycle, in line with existing experimental data to which comparisons are made. The sensitivity of the variable viscosity models is investigated in terms of mean flow field, levels of turbulence and global shear rate, and a non-dimensional index is used to directly evaluate the impact of non-Newtonian effects. The clinical relevance of the results is reported along with a discussion of modelling uncertainties, observing that the turbulent kinetic energy is generally predicted to be higher in non-Newtonian flow than that observed in Newtonian flow. Copyright © 2016 John Wiley & Sons, Ltd.
Simulation of non-Newtonian ink transfer between two separating plates for gravure-offset printing
Energy Technology Data Exchange (ETDEWEB)
Ahmed, Dewan Hasan [Department of Mechanical Engineering, Korea Advanced Institute of Science and Technology, 373-1, Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Sung, Hyung Jin, E-mail: hjsung@kaist.ac.k [Department of Mechanical Engineering, Korea Advanced Institute of Science and Technology, 373-1, Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Kim, Dong-Soo [Nano-Mechanical Systems Research Division, Korea Institute of Machinery and Materials, 171, Jang-dong, Yuseong-gu, Daejeon 305-343 (Korea, Republic of)
2011-02-15
The inks used in gravure-offset printing are non-Newtonian fluids with higher viscosities and lower surface tensions compared to Newtonian fluids. This paper examines the transfer of a non-Newtonian ink between two parallel plates when the top plate is moved upward with a constant velocity while the bottom plate is held fixed. Numerical simulations were carried out using the Carreau model to explore the behavior of a non-Newtonian ink in gravure-offset printing. The volume of fluid (VOF) model was adopted to demonstrate the stretching and break-up behaviors of the ink. The results indicate that the ink transfer ratio is greatly influenced by the contact angle, especially the contact angle at the upper plate ({alpha}). For lower values of {alpha}, oscillatory or unstable behavior of the position of minimum thickness of the ink between the two parallel plates during the stretching period is observed. This oscillation gradually diminishes as the contact angle at the upper plate is increased. Moreover, the number of satellite droplets increases as the velocity of the upper plate is increased. The surface tension of the conductive ink shows a positive impact on the ink transfer ratio to the upper plate. Indeed, the velocity of the upper plate has a significant influence on the ink transfer in gravure-offset printing when the Capillary number (Ca) is greater than 1 and the surface tension dominates over the ink transfer process when Ca is less than 1.
Studies on heat transfer to Newtonian and non-Newtonian fluids in agitated vessel
Triveni, B.; Vishwanadham, B.; Venkateshwar, S.
2008-09-01
Heat transfer studies to Newtonian and non-Newtonian fluids are carried out in a stirred vessel fitted with anchor/turbine impeller and a coil for heating/cooling with an objective of determining experimentally the heat transfer coefficient of few industrially important systems namely castor oil and its methyl esters, soap solution, CMC and chalk slurries. The effect of impeller geometry, speed and aeration is investigated. Generalized Reynolds and Prandtl numbers are calculated using an apparent viscosity for non-Newtonian fluids. The data is correlated using a Sieder-Tate type equation. A trend of increase in heat transfer coefficient with RPM in presence and absence of solids has been observed. Relatively high values of Nusselt numbers are obtained for non-Newtonian fluids when aeration is coupled with agitation. The contribution of natural convection to heat transfer has been accounted for by incorporating the Grashof number. The correlations developed based on these studies are applied for design of commercial scale soponification reactor. Power per unit volume resulted in reliable design of a reactor.
Transfer of Microparticles across Laminar Streams from Non-Newtonian to Newtonian Fluid.
Ha, Byunghang; Park, Jinsoo; Destgeer, Ghulam; Jung, Jin Ho; Sung, Hyung Jin
2016-04-19
Engineering inertial lift forces and elastic lift forces is explored to transfer microparticles across laminar streams from non-Newtonian to Newtonian fluid. A co-stream of non-Newtonian flow loaded with microparticles (9.9 and 2.0 μm in diameter) and a Newtonian carrier medium flow in a straight rectangular conduit is devised. The elastic lift forces present in the non-Newtonian fluid, undeterred by particle-particle interaction, successfully pass most of the larger (9.9 μm) particles over to the Newtonian fluid. The Newtonian fluid takes over the larger particles and focus them on the equilibrium position, separating the larger particles from the smaller particles. This mechanism enabled processing of densely suspended particle samples. The method offers dilution-free (for number densities up to 10,000 μL(-1)), high throughput (6700 beads/s), and highly efficient (>99% recovery rate, >97% purity) particle separation operated over a wide range of flow rate (2 orders of magnitude).
Are Non-Newtonian Effects Important in Hemodynamic Simulations of Patients With Autogenous Fistula?
Javid Mahmoudzadeh Akherat, S M; Cassel, Kevin; Boghosian, Michael; Dhar, Promila; Hammes, Mary
2017-04-01
Given the current emphasis on accurate computational fluid dynamics (CFD) modeling of cardiovascular flows, which incorporates realistic blood vessel geometries and cardiac waveforms, it is necessary to revisit the conventional wisdom regarding the influences of non-Newtonian effects. In this study, patient-specific reconstructed 3D geometries, whole blood viscosity data, and venous pulses postdialysis access surgery are used as the basis for the hemodynamic simulations of renal failure patients with native fistula access. Rheological analysis of the viscometry data initially suggested that the correct choice of constitutive relations to capture the non-Newtonian behavior of blood is important because the end-stage renal disease (ESRD) patient cohort under observation experience drastic variations in hematocrit (Hct) levels and whole blood viscosity throughout the hemodialysis treatment. For this purpose, various constitutive relations have been tested and implemented in CFD practice, namely Quemada and Casson. Because of the specific interest in neointimal hyperplasia and the onset of stenosis in this study, particular attention is placed on differences in nonhomeostatic wall shear stress (WSS) as that drives the venous adaptation process that leads to venous geometric evolution over time in ESRD patients. Surprisingly, the CFD results exhibit no major differences in the flow field and general flow characteristics of a non-Newtonian simulation and a corresponding identical Newtonian counterpart. It is found that the vein's geometric features and the dialysis-induced flow rate have far greater influence on the WSS distribution within the numerical domain.
Khojasteh, Danial; Mousavi, Seyed Mahmood; Kamali, Reza
2016-11-01
In the present study, the behaviors of Newtonian and shear-thinning non-Newtonian droplets impinging on heated hydrophilic and hydrophobic surfaces have been investigated numerically using Ansys-Fluent. In this context, the volume-of-fluid technique is applied to track the free-surface of the liquid, and variable time-step is also utilized to control the Courant number. Furthermore, we have considered the dependence of viscosity, density and surface tension on temperature during the simulation. The results are compared to available experimental data at the same conditions, such as boundary conditions. The results demonstrate that there is a good agreement between the obtained results and the experimental trends, concerning normalized diameter profiles at various Weber numbers. Therefore, the focus of the present study is an assessment of the effects of variations in Weber number, contact angle and surface temperature for Newtonian and non-Newtonian liquids on dynamics behavior of droplet in collision with hydrophobic and hydrophilic surfaces. The results represent that the behaviors of Newtonian and non-Newtonian droplets are totally different, indicating the droplet sensitivity to the working parameters.
Mixed convection heat transfer from a vertical plate to non-Newtonian fluids
Wang, T.-Y.
1995-02-01
The nonsimilar boundary-layer analysis of steady laminar mixed-convection heat transfer between a vertical plate and non-Newtonian fluids is extended and unified. A mixed-convection parameter zeta is proposed to replace the conventional Richardson number, Gr/Re(exp 2/(2 - n)) and to serve as a controlling parameter that determines the relative importance of the forced and the free convection. The value of mixed-convection parameter lies between 0 and 1. In addition, the power-law model is used for non-Newtonian fluids with exponent n less than 1 for pseudoplastics; n = 1 for Newtonian fluids; and n greater than 1 for dilatant fluids. Furthermore, the coordinates and dependent variables are transformed to yield computationally efficient numerical solutions that are valid over the entire range of mixed convection, from the pure forced-convection limit to the pure free-convection limit, and the whole domain of non-Newtonian fluids, from pseudoplastics to dilatant fluids. The effects of the mixed-convection parameter, the power-law viscosity index, and the generalized Prandtl number on the velocity profiles, the temperature profiles, as well as on the wall skin friction and heat transfer rate are clearly illustrated for both cases of buoyancy assisting and opposing flow conditions.
Pore-Scale Modeling of Non-Newtonian Flow in Porous Media
Sochi, Taha
2010-01-01
The thesis investigates the flow of non-Newtonian fluids in porous media using pore-scale network modeling. Non-Newtonian fluids show very complex time and strain dependent behavior and may have initial yield stress. Their common feature is that they do not obey the simple Newtonian relation of proportionality between stress and rate of deformation. They are generally classified into three main categories: time-independent, time-dependent and viscoelastic. Two three-dimensional networks representing a sand pack and Berea sandstone were used. An iterative numerical technique is used to solve the pressure field and obtain the flow rate and apparent viscosity. The time-independent category is investigated using two fluid models: Ellis and Herschel-Bulkley. The analysis confirmed the reliability of the non-Newtonian network model used in this study. Good results are obtained, especially for the Ellis model, when comparing the network model results to experimental data sets found in the literature. The yield-stres...
Directory of Open Access Journals (Sweden)
J. Javorova
2016-06-01
Full Text Available The purpose of this paper is to study the performance of a finite length journal bearing, taking into account effects of non-Newtonian Rabinowitsch flow rheology and elastic deformations of the bearing liner. According to the Rabinowitsch fluid model, the cubic-stress constitutive equation is used to account for the non-Newtonian effects of pseudoplastic and dilatant lubricants. Integrating the continuity equation across the film, the nonlinear non-Newtonian Reynolds-type equation is derived. The elasticity part of the problem is solved on the base of Vlassov model of an elastic foundation. The numerical solution of the modified Reynolds equation is carried out by using FDM with over-relaxation technique. The results for steady state bearing performance characteristics have been calculated for various values of nonlinear factor and elasticity parameters. It was concluded that in comparison with the Newtonian lubricants, higher values of film pressure and load carrying capacity have been obtained for dilatant lubricants, while the case was reversed for pseudoplastic lubricants.
Water-gel for gating graphene transistors.
Kim, Beom Joon; Um, Soong Ho; Song, Woo Chul; Kim, Yong Ho; Kang, Moon Sung; Cho, Jeong Ho
2014-05-14
Water, the primary electrolyte in biology, attracts significant interest as an electrolyte-type dielectric material for transistors compatible with biological systems. Unfortunately, the fluidic nature and low ionic conductivity of water prevents its practical usage in such applications. Here, we describe the development of a solid state, megahertz-operating, water-based gate dielectric system for operating graphene transistors. The new electrolyte systems were prepared by dissolving metal-substituted DNA polyelectrolytes into water. The addition of these biocompatible polyelectrolytes induced hydrogelation to provide solid-state integrity to the system. They also enhanced the ionic conductivities of the electrolytes, which in turn led to the quick formation of an electric double layer at the graphene/electrolyte interface that is beneficial for modulating currents in graphene transistors at high frequencies. At the optimized conditions, the Na-DNA water-gel-gated flexible transistors and inverters were operated at frequencies above 1 MHz and 100 kHz, respectively.
Directory of Open Access Journals (Sweden)
Hailong Ye
2015-04-01
Full Text Available Uniqueness of self-similar very singular solutions with compact support are proved for the non-Newtonian polytropic filtration equation with gradient absorption $$ \\frac{\\partial u}{\\partial t} =\\hbox{div}(|\
NUMERICAL ANALYSIS OF THE NON-NEWTONIAN BLOOD FLOW IN THE NON-PLANAR ARTERY WITH BIFURCATION
Institute of Scientific and Technical Information of China (English)
CHEN Jie; LU Xi-yun; ZHUANG Li-xian; WANG Wen
2004-01-01
A numerical analysis of non-Newtonian fluid flow in non-planar artery with bifurcation was performed by using a finite element method to solve the three-dimensional Navier-Stokes equations coupled with the non-Newtonian constitutive models, including Carreau,Cross and Bingham models. The objective of this study is to investigate the effects of the non-Newtonian properties of blood as well as curvature and out-of-plane geometry in the non-planar daughter vessels on the velocity distribution and wall shear stress. The results of this study support the view that the non-planarity of blood vessels and the non-Newtonian properties of blood are of important in hemodynamics and play a significant role in vascular biology and pathophysiology.
Martin, A.H.; Bakhuizen, E.; Ersch, C.; Urbonaite, V.; Jongh, H.H.J. de; Pouvreau, L.
2016-01-01
To understand the origin of water holding of mixed protein gels, a study was performed on water exudation from mixed whey protein (WP)-gelatin gels upon applied pressure. Mixed gels were prepared with varying WP and gelatin concentration and gelatin type to obtain gels with a wide range of gel
Numerical Solution of Hydrodynamics Lubrications with Non-Newtonian Fluid Flow
Osman, Kahar; Sheriff, Jamaluddin Md; Bahak, Mohd. Zubil; Bahari, Adli; Asral
2010-06-01
This paper focuses on solution of numerical model for fluid film lubrication problem related to hydrodynamics with non-Newtonian fluid. A programming code is developed to investigate the effect of bearing design parameter such as pressure. A physical problem is modeled by a contact point of sphere on a disc with certain assumption. A finite difference method with staggered grid is used to improve the accuracy. The results show that the fluid characteristics as defined by power law fluid have led to a difference in the fluid pressure profile. Therefore a lubricant with special viscosity can reduced the pressure near the contact area of bearing.
Non-Newtonian Couette-Poiseuille flow of a dilute gas
Tij, Mohamed; Santos, Andrés
2010-01-01
The steady state of a dilute gas enclosed between two infinite parallel plates in relative motion and under the action of a uniform body force parallel to the plates is considered. The Bhatnagar-Gross-Krook model kinetic equation is analytically solved for this Couette-Poiseuille flow to first order in the force and for arbitrary values of the Knudsen number associated with the shear rate. This allows us to investigate the influence of the external force on the non-Newtonian properties of the...
Matrix transformations between certain sequence spaces over the non-Newtonian complex field.
Kadak, Uğur; Efe, Hakan
2014-01-01
In some cases, the most general linear operator between two sequence spaces is given by an infinite matrix. So the theory of matrix transformations has always been of great interest in the study of sequence spaces. In the present paper, we introduce the matrix transformations in sequence spaces over the field ℂ(*) and characterize some classes of infinite matrices with respect to the non-Newtonian calculus. Also we give the necessary and sufficient conditions on an infinite matrix transforming one of the classical sets over ℂ(*) to another one. Furthermore, the concept for sequence-to-sequence and series-to-series methods of summability is given with some illustrated examples.
An overview on the non-newtonian calculus and its potential applications to economics
Filip, Diana; Piatecki, Cyrille
2014-01-01
20; Until now, non-newtonian calculus, multiplicative calculus in particular, has been presented as a curiosity and is nearly ignored for the social scientists field. In this paper, after a brief presentation of this calculus, we try to show how it could be used to re-explore from another perspective classical economic theory, more particularly the economic growth and in the maximum likelihood method from statistics.; Jusqu'à présent, le calcul non-newtonien, calcul multiplicatif en particuli...
Learning about non-Newtonian fluids in a student-driven classroom
Dounas-Frazer, D R; Zaniewski, A M; Roth, N
2012-01-01
We describe a simple, low-cost experiment and corresponding pedagogical strategies for studying fluids whose viscosities depend on shear rate, referred to as non-Newtonian fluids. We developed these materials teaching for the Compass Project, an organization that fosters a creative, diverse, and collaborative community of science students at UC Berkeley. Incoming freshmen worked together in a week-long, residential program to explore physical phenomena through a combination of conceptual model-building and hands-on experimentation. During the program, students were exposed to three major aspects of scientific discovery: developing a model, testing the model, and investigating deviations from the model.
Zhu, W.; Aitken, B. G.; Sen, S.
2017-02-01
All families of inorganic glass-forming liquids display non-Newtonian rheological behavior in the form of shear thinning at high shear rates. Experimental evidence is presented to demonstrate the existence of remarkable universality in this behavior, irrespective of chemical composition, structure, topology, and viscosity. However, contrary to intuition, in all cases the characteristic shear rates that mark the onset of shear thinning in these liquids are orders of magnitude slower than the global shear relaxation rates. Attempt is made to reconcile such differences within the framework of the cooperative structural relaxation model of glass-forming liquids.
Non-Newtonian behavior and molecular structure of Cooee bitumen under shear flow
DEFF Research Database (Denmark)
Lemarchand, Claire; Bailey, Nicholas; Daivis, Peter
2015-01-01
The rheology and molecular structure of a model bitumen (Cooee bitumen) under shear are investigated in the non-Newtonian regime using non-equilibrium molecular dynamics simulations. The shear viscosity, normal stress differences, and pressure of the bitumen mixture are computed at different shear...... rates and different temperatures. The model bitumen is shown to be a shear-thinning fluid at all temperatures. In addition, the Cooee model is able to reproduce experimental results showing the formation of nanoaggregates composed of stacks of flat aromatic molecules in bitumen. These nanoaggregates...
Weak solutions for a non-Newtonian diffuse interface model with different densities
Abels, Helmut; Breit, Dominic
2016-11-01
We consider weak solutions for a diffuse interface model of two non-Newtonian viscous, incompressible fluids of power-law type in the case of different densities in a bounded, sufficiently smooth domain. This leads to a coupled system of a nonhomogenouos generalized Navier-Stokes system and a Cahn-Hilliard equation. For the Cahn-Hilliard part a smooth free energy density and a constant, positive mobility is assumed. Using the {{L}∞} -truncation method we prove existence of weak solutions for a power-law exponent p>\\frac{2d+2}{d+2} , d = 2, 3.
Pullback Asymptotic Behavior of Solutions for a 2D Non-autonomous Non-Newtonian Fluid
Liu, Guowei
2016-10-01
This paper studies the pullback asymptotic behavior of solutions for the non-autonomous incompressible non-Newtonian fluid in 2D bounded domains. Firstly, with a little high regularity of the force, the semigroup method and ɛ -regularity method are used to establish the existence of compact pullback absorbing sets. Then, with a minimal regularity of the force, by verifying the flattening property also known as the "Condition (C)", the author proves the existence of pullback attractors for the universe of fixed bounded sets and for the another universe given by a tempered condition. Furthermore, the regularity of pullback attractors is given.
Hodographic study of non-Newtonian MHD aligned steady plane fluid flows
Directory of Open Access Journals (Sweden)
P. V. Nguyen
1990-01-01
Full Text Available A study is made of non-Newtonian HHD aligned steady plane fluid flows to find exact solutions for various flow configurations. The equations of motion have been transformed to the hodograph plane. A Legendre-transform function is used to recast the equations in the hodograph plane in terms of this transform function. Solutions for various flow configurations are obtained. Applications are investigated for the fluids of finite and infinite electrical conductivity bringing out the similarities and contrasts in the solutions of these types of fluids.
Non-Newtonian Liquid Flow through Small Diameter Piping Components: CFD Analysis
Bandyopadhyay, Tarun Kanti; Das, Sudip Kumar
2016-10-01
Computational Fluid Dynamics (CFD) analysis have been carried out to evaluate the frictional pressure drop across the horizontal pipeline and different piping components, like elbows, orifices, gate and globe valves for non-Newtonian liquid through 0.0127 m pipe line. The mesh generation is done using GAMBIT 6.3 and FLUENT 6.3 is used for CFD analysis. The CFD results are verified with our earlier published experimental data. The CFD results show the very good agreement with the experimental values.
A Lagrangian finite element method for the simulation of flow of non-newtonian liquids
DEFF Research Database (Denmark)
Hassager, Ole; Bisgaard, C
1983-01-01
A Lagrangian method for the simulation of flow of non-Newtonian liquids is implemented. The fluid mechanical equations are formulated in the form of a variational principle, and a discretization is performed by finite elements. The method is applied to the slow of a contravariant convected Maxwell...... liquid around a sphere moving axially in a cylinder. The simulations show that the friction factor for a sphere in a narrow cylinder is a rapidly decreasing function of the Deborah number, while the friction factor for a sphere in a very wide cylinder is not significantly affected by fluid elasticity...
Flow non-normality-induced transient growth in superposed Newtonian and non-Newtonian fluid layers.
Camporeale, C; Gatti, F; Ridolfi, L
2009-09-01
In recent years non-normality and transient growths have attracted much interest in fluid mechanics. Here, we investigate these topics with reference to the problem of interfacial instability in superposed Newtonian and non-Newtonian fluid layers. Under the hypothesis of the lubrication theory, we demonstrate the existence of significant transient growths in the parameter space region where the dynamical system is asymptotically stable, and show how they depend on the main physical parameters. In particular, the key role of the density ratio is highlighted.
Institute of Scientific and Technical Information of China (English)
Yang Yongkuang; Yang Rongtai; Ho Minghsiung; Jheng Mingchang
2004-01-01
A novel numerical method to lubricate a conventional finite diameter conical(cylindrical bearing with a non-Newtonian lubricant, while adhering to the power-law model, is presented. The elastic deformation of bearing and varied viscosity of lubrication due to the pressure distribution of film thickness are also considered. Simulation results indicate that the normal load carrying capacity is more pronounced for higher values of flow behavior index n, higher eccentricity ratios and larger misalignment factors. It is found that the viscosity-pressure to the effect of lubricant viscosity is significant.
Nonlinear shear wave in a non Newtonian visco-elastic medium
Energy Technology Data Exchange (ETDEWEB)
Banerjee, D.; Janaki, M. S.; Chakrabarti, N. [Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Calcutta 700 064 (India); Chaudhuri, M. [Max-Planck-Institut fuer extraterrestrische Physik, 85741 Garching (Germany)
2012-06-15
An analysis of nonlinear transverse shear wave has been carried out on non-Newtonian viscoelastic liquid using generalized hydrodynamic model. The nonlinear viscoelastic behavior is introduced through velocity shear dependence of viscosity coefficient by well known Carreau-Bird model. The dynamical feature of this shear wave leads to the celebrated Fermi-Pasta-Ulam problem. Numerical solution has been obtained which shows that initial periodic solutions reoccur after passing through several patterns of periodic waves. A possible explanation for this periodic solution is given by constructing modified Korteweg de Vries equation. This model has application from laboratory to astrophysical plasmas as well as in biological systems.
Structure of a binary mixture under shear: non-Newtonian effects from computer simulation
Energy Technology Data Exchange (ETDEWEB)
Hanley, H.J.M.; Evans, D.J.; Hess, S.
1983-02-01
A binary equimolar dense fluid mixture is subjected to a shear. The orientational distribution of particles of type i around particles of type j (i, j = 1, 2) and the distortion of the radial distribution function is discussed for planar Couette flow. Results are presented in terms of a mixture of soft spheres, for which one species differs substantially in size and mass from the other, simulated on the computer using the technique of shear nonequilbrium molecular dynamics. Transport coefficients, including those associated with normal pressure differences, are given for the mixture and for the species in the mixture. Non-Newtonian phenomena are observed.
Nonlinear Shear Wave in a Non Newtonian Visco-elastic Medium
Janaki, D Banerjee M S; Chaudhuri, M
2013-01-01
An analysis of nonlinear transverse shear wave has been carried out on non-Newtonian viscoelastic liquid using generalized hydrodynamic(GH) model. The nonlinear viscoelastic behavior is introduced through velocity shear dependence of viscosity coefficient by well known Carreau -Bird model. The dynamical feature of this shear wave leads to the celebrated Fermi-Pasta-Ulam (FPU) problem. Numerical solution has been obtained which shows that initial periodic solutions reoccur after passing through several patterns of periodic waves. A possible explanation for this periodic solution is given by constructing modified Korteweg de Vries (mKdV) equation. This model has application from laboratory to astrophysical plasmas as well as biological systems.
OPTIMAL MIXED H- P FINITE ELEMENT METHODS FOR STOKES AND NON-NEWTONIAN FLOW
Institute of Scientific and Technical Information of China (English)
Ping-bing Ming; Zhong-ci Shi
2001-01-01
Based upon a new mixed variational formulation for the three-field Stokes equations and linearized Non-Newtonian flow, an h -p finite element method is presented with or without a stabilization. As to the variational formulation without stabilization, optimal error bounds in h as well as in p are obtained. As with stabilization, optimal error bounds are obtained which is optimal in h and one order deterioration in p for the pressure, that is consistent with numerical results in [9, 12] and therefore solved the problem therein.Moreover, we proposed a stabilized formulation which is optimal in both h and p.
Non-newtonian flow and pressure drop of pineapple juice in a plate heat exchanger
CABRAL, R. A. F.; GUT, J. A. W.; V. R. N. Telis; Telis-Romero, J. [UNESP
2010-01-01
The study of non-Newtonian flow in plate heat exchangers (PHEs) is of great importance for the food industry. The objective of this work was to study the pressure drop of pineapple juice in a PHE with 50º chevron plates. Density and flow properties of pineapple juice were determined and correlated with temperature (17.4 < T < 85.8ºC) and soluble solids content (11.0 < Xs < 52.4 ºBrix). The Ostwald-de Waele (power law) model described well the rheological behavior. The friction factor for non-...
Yeylaghi, Shahab; Moa, Belaid; Buckham, Bradley; Oshkai, Peter; Vasquez, Jose; Crawford, Curran
2017-09-01
A comprehensive modeling of landslide generated waves using an in-house parallel Incompressible Smoothed Particle Hydrodynamics (ISPH) code is presented in this paper. The study of landslide generated waves is challenging due to the involvement of several complex physical phenomena, such as slide-water interaction, turbulence and complex free surface profiles. A numerical tool that can efficiently calculate both slide motion, impact with the surface and the resulting wave is needed for ongoing study of these phenomena. Mesh-less numerical methods, such as Smoothed Particle Hydrodynamics (SPH), handle the slide motion and the complex free surface profile with ease. In this paper, an in-house parallel explicit ISPH code is used to simulate both subaerial and submarine landslides in 2D and in more realistic 3D applications. Both rigid and deformable slides are used to generate the impulsive waves. A landslide case is simulated where a slide falls into a non-Newtonian reservoir fluid (water-bentonite mixture). A new technique is also proposed to calculate the motion of a rigid slide on an inclined ramp implicitly, without using the prescribed motion in SPH. For all the test cases, results generated from the proposed ISPH method are compared with available experimental data and show good agreement.
Squeeze film lubrication for non-Newtonian fluids with application to manual medicine.
Chaudhry, Hans; Bukiet, Bruce; Roman, Max; Stecco, Antonio; Findley, Thomas
2013-01-01
In this paper, we computed fluid pressure and force on fascia sheets during manual therapy treatments using Squeeze Film Lubrication theory for non-Newtonian fluids. For this purpose, we developed a model valid for three dimensional fluid flow of a non-Newtonian liquid. Previous models considered only one-dimensional flows in two dimensions. We applied this model to compare the one-dimensional flow of HA, considered as a lubricating fluid, around or within the fascia during sliding, vibration, and back-and-forth sliding manipulation treatment techniques. The fluid pressure of HA increases dramatically as fascia is deformed during manual therapies. The fluid force increases more during vertical vibratory manipulation treatment than in constant sliding, and back and forth motion. The variation of fluid pressure/force causes HA to flow near the edges of the fascial area under manipulation in sliding and back and forth motion which may result in greater lubrication. The fluid pressure generated in manual therapy techniques may improve sliding and permit muscles to work more efficiently.
Numerical Well Test Analysis for Polymer Flooding considering the Non-Newtonian Behavior
Directory of Open Access Journals (Sweden)
Jia Zhichun
2015-01-01
Full Text Available Well test analysis for polymer flooding is different from traditional well test analysis because of the non-Newtonian properties of underground flow and other mechanisms involved in polymer flooding. Few of the present works have proposed a numerical approach of pressure transient analysis which fully considers the non-Newtonian effect of real polymer solution and interprets the polymer rheology from details of pressure transient response. In this study, a two-phase four-component fully implicit numerical model incorporating shear thinning effect for polymer flooding based on PEBI (Perpendicular Bisection grid is developed to study transient pressure responses in polymer flooding reservoirs. Parametric studies are conducted to quantify the effect of shear thinning and polymer concentration on the pressure transient response. Results show that shear thinning effect leads to obvious and characteristic nonsmoothness on pressure derivative curves, and the oscillation amplitude of the shear-thinning-induced nonsmoothness is related to the viscosity change decided by shear thinning effect and polymer concentration. Practical applications are carried out with shut-in data obtained in Daqing oil field, which validates our findings. The proposed method and the findings in this paper show significant importance for well test analysis for polymer flooding and the determination of the polymer in situ rheology.
Study on local resistance of non-Newtonian power law fluid in elbow pipes
Zhang, Hao; Xu, Tiantian; Zhang, Xinxin; Wang, Yuxiang; Wang, Yuancheng; Liu, Xueting
2016-06-01
This paper focuses on the flow characteristic and local resistance of non-Newtonian power law fluid in a curved 90° bend pipe with circular cross-sections, which are widely used in industrial applications. By employing numerical simulation and theoretical analysis the properties of the flow and local resistance of power law fluid under different working conditions are obtained. To explore the change rule the experiment is carried out by changing the Reynolds number, the wall roughness and different diameter ratio of elbow pipe. The variation of the local resistance coefficient with the Reynolds number, the diameter ratio and the wall roughness is presented comprehensively in the paper. The results show that the local resistance force coefficient hardly changes with Reynolds number of the power law fluid; the wall roughness has a significant impact on the local resistance coefficient. As the pipe wall roughness increasing, the coefficient of local resistance force will increase. The main reason of the influence of the roughness on the local resistance coefficient is the increase of the eddy current region in the power law fluid flow, which increases the kinetic energy dissipation of the main flow. This paper provides theoretical and numerical methods to understand the local resistance property of non-Newtonian power law fluid in elbow pipes.
Zhao, Cunlu
2010-01-01
Numerical analyses of transient electro-osmosis of a typical non-Newtonian liquid induced by DC and AC electric fields in a rectangular microchannel are conducted in the framework of continuum fluid mechanics. The famous power-law constitutive model is used to express the fluid dynamic viscosity in terms of the velocity gradient. Transient start-up characteristics of electro-osmotic power-law liquid flow in rectangular microchannels are simulated by using finite element method. Under a DC electric field, it is found out and the fluid is more inert to the external electric field and the steady-state velocity profile becomes more plug-like with decrease of the flow behavior index of the power-law liquids. The numerical calculations also confirm the validity of the generalized Smoluchowski slip velocity which can serve as the counterpart for the classic Smoluchowski slip velocity when dealing with electrokinetic flow of non-Newtonian power-law fluids. Under AC electric fields, the fluid is more obviously acceler...
Generation of Oil Droplets in a Non-Newtonian Liquid Using a Microfluidic T-Junction
Directory of Open Access Journals (Sweden)
Enrico Chiarello
2015-11-01
Full Text Available We have compared the formation of oil drops in Newtonian and non-Newtonian fluids in a T-junction microfluidic device. As Newtonian fluids, we used aqueous solutions of glycerol, while as non-Newtonian fluids we prepared aqueous solutions of xanthan, a stiff rod-like polysaccharide, which exhibit strong shear-thinning effects. In the squeezing regime, the formation of oil droplets in glycerol solutions is found to scale with the ratio of the dispersed flow rate to the continuous one and with the capillary number associated to the continuous phase. Switching to xanthan solutions does not seem to significantly alter the droplet formation process. Any quantitative difference with respect to the Newtonian liquid can be accounted for by a suitable choice of the capillary number, corresponding to an effective xanthan viscosity that depends on the flow rates. We have deduced ample variations in the viscosity, on the order of 10 and more, during normal operation conditions of the T-junction. This allowed estimating the actual shear rates experienced by the xanthan solutions, which go from tens to hundreds of s−1.
Single-Phase Flow of Non-Newtonian Fluids in Porous Media
Sochi, Taha
2009-01-01
The study of flow of non-Newtonian fluids in porous media is very important and serves a wide variety of practical applications in processes such as enhanced oil recovery from underground reservoirs, filtration of polymer solutions and soil remediation through the removal of liquid pollutants. These fluids occur in diverse natural and synthetic forms and can be regarded as the rule rather than the exception. They show very complex strain and time dependent behavior and may have initial yield-stress. Their common feature is that they do not obey the simple Newtonian relation of proportionality between stress and rate of deformation. Non-Newtonian fluids are generally classified into three main categories: time-independent whose strain rate solely depends on the instantaneous stress, time-dependent whose strain rate is a function of both magnitude and duration of the applied stress and viscoelastic which shows partial elastic recovery on removal of the deforming stress and usually demonstrates both time and str...
Experimental Investigation and Pore-Scale Modeling of Non-Newtonian Fluid Flow in Porous Media
Hauswirth, S.; Dye, A. L.; Miller, C. T.; Tapscott, C.; Schultz, P. B.
2015-12-01
Systems involving the flow of non-Newtonian fluids in porous media arise in a number of settings, including hydraulic fracturing, enhanced oil recovery, contaminant remediation, and biological systems. Development of accurate macroscale models of such systems requires an understanding of the relationship between the fluid and medium properties at the microscale and averaged macroscale properties. This study investigates the flow of aqueous solutions of guar gum, a major component of hydraulic fracturing fluids that exhibits Cross model rheological behavior. The rheological properties of solutions containing varying concentrations of guar gum were characterized using a rotational rheometer and the data were fit to a model relating viscosity to shear rate and concentration. Flow experiments were conducted in a porous medium-packed column to measure the pressure response during the flow of guar gum solutions at a wide range of flow rates and determine apparent macroscale viscosities and shear rates. To investigate the relationship between the fluid rheology, microscale physics, and the observed macroscale properties, a lattice Boltzmann pore scale simulator incorporating non-Newtonian behavior was developed. The model was validated, then used to simulate systems representative of the column experiments, allowing direct correlation of detailed microscale physics to the macroscale observations.
Gas holdup in a reciprocating plate bioreactor: Non-Newtonian - liquid phase
Directory of Open Access Journals (Sweden)
Naseva Olivera S.
2002-01-01
Full Text Available The gas holdup was studied in non-newtonian liquids in a gas-liquid and gas-liquid-solid reciprocating plate bioreactor. Aqueous solutions of carboxy methyl cellulose (CMC; Lucel, Lučane, Yugoslavia of different degrees of polymerization (PP 200 and PP 1000 and concentration (0,5 and 1%, polypropylene spheres (diameter 8.3 mm; fraction of spheres: 3.8 and 6.6% by volume and air were used as the liquid, solid and gas phase. The gas holdup was found to be dependent on the vibration rate, the superficial gas velocity, volume fraction of solid particles and Theological properties of the liquid ohase. Both in the gas-liquid and gas-liquid-solid systems studied, the gas holdup increased with increasing vibration rate and gas flow rate. The gas holdup was higher in three-phase systems than in two-phase ones under otter operating conditions being the same. Generally the gas holdup increased with increasing the volume fraction of solid particles, due to the dispersion action of the solid particles, and decreased with increasing non-Newtonian behaviour (decreasing flow index i.e. with increasing degree of polymerization and solution concentration of CMC applied, as a result of gas bubble coalescence.
Non-Newtonian fluid model incorporated into elastohydrodynamic lubrication of rectangular contacts
Jacobson, B. O.; Hamrock, B. J.
1984-01-01
A procedure is outlined for the numerical solution of the complete elastohydrodynamic lubrication of rectangular contacts incorporating a non-Newtonian fluid model. The approach uses a Newtonian model as long as the shear stress is less than a limiting shear stress. If the shear stress exceeds the limiting value, the shear stress is set equal to the limiting value. The numerical solution requires the coupled solution of the pressure, film shape, and fluid rheology equations from the inlet to the outlet. Isothermal and no-side-leakage assumptions were imposed in the analysis. The influence of dimensionless speed, load, materials, and sliding velocity and limiting-shear-strength proportionality constant on dimensionless minimum film thickness was investigated. Fourteen cases were used in obtaining the minimum-film-thickness equation for an elastohydrodynamically lubricated rectangular contact incorporating a non-Newtonian fluid model. Computer plots are also presented that indicate in detail pressure distribution, film shape, shear stress at the surfaces, and flow throughout the conjunction.
Spreading of completely wetting, non-Newtonian fluids with non-power-law rheology.
Min, Qi; Duan, Yuan-Yuan; Wang, Xiao-Dong; Liang, Zhan-Peng; Lee, Duu-Jong; Su, Ay
2010-08-01
Spreading non-Newtonian liquids with non-power-law rheology on completely wetting surfaces are seldom investigated. This study assessed the wetting behavior of polydimethylsiloxane (PDMS), a Newtonian fluid, two carboxymethylcellulose (CMC) sodium solutions, a PDMS+2%w/w silica nanoparticle suspension and three polyethylene glycol (PEG400)+5-10%w/w silica nanoparticle suspensions (non-power-law fluids) on a mica surface. The theta(D)-U and R-t data for spreading drops of the six tested, non-power-law fluids can be described by power-law wetting models. We propose that this behavior is attributable to a uniform shear rate (a few tens to a few hundreds of s(-1)) distributed over the thin-film regime that controls spreading dynamics. Estimated film thickness was below the resolution of an optical microscope for direct observation. Approximating a general non-Newtonian fluid spreading as a power-law fluid greatly simplifies theoretical analysis and data interpretation.
Validation of computational non-Newtonian fluid model for membrane bioreactor.
Sørensen, Lasse; Bentzen, Thomas Ruby; Skov, Kristian
2015-01-01
Membrane bioreactor (MBR) systems are often considered as the wastewater treatment method of the future due to their high effluent quality. One of the main problems with such systems is a relative large energy consumption, compared to conventional activated sludge (CAS) systems, which has led to further research in this specific area. A powerful tool for optimizing MBR-systems is computational fluid dynamics (CFD) modelling, which gives researchers the ability to describe the flow in the systems. A parameter which is often neglected in such models is the non-Newtonian properties of active sludge, which is of great importance for MBR systems since they operate at sludge concentrations up to a factor of 10 compared to CAS systems, resulting in strongly shear thinning liquids. A CFD-model is validated against measurements conducted in a system with rotating cross-flow membranes submerged in non-Newtonian liquids, where tangential velocities are measured with a Laser Doppler Anemometer (LDA). The CFD model is found to be capable of modelling the correct velocities in a range of setups, making CFD models a powerful tool for optimization of MBR systems.
Pressure falloff behavior in vertically fractured wells: Non-Newtonian power-law fluids
Energy Technology Data Exchange (ETDEWEB)
Vongvuthipornchai, S.; Raghauan, R.; Reynolds, A.C.
1984-09-01
This paper examines pressure falloff behavior in fractured wells following the injection of a non-Newtonian power-law fluid. Results are presented in a form suitable for field application. Responses at wells intercepting infinite-conductivity and uniformflux fractures are considered. Procedures to identify flow regimes are discussed. The solutions presented here are new and to our knowledge not available in the literature. The consequences of neglecting the non-Newtonian characteristics of the injected fluid are examined. The results of this work were obtained by a finite difference model. Procedures to compute the apparent viscosity of power-law fluids for twodimensional flow through porous media are discussed. The formulation given here avoids numerical problems (multiple solutions, cross over, etc.) reported in other studies. Although, the main objective of the work is to examine pressure falloff behavior at fractured wells, the authors also examine responses at unfractured wells. The main objective of this part of a study is to examine the validity of using the superposition principle to analyze pressure falloff data. (The pressure distribution for this problem is governed by a nonlinear partial differential equation.) If the solutions given in the literature are used, then correction factors are needed to analyze pressure falloff data. The results of this phase of the work can also be used to analyze data in fractured wells provided that pseudoradial flow conditions exist.
Non-Newtonian flow of an ultralow-melting chalcogenide liquid in strongly confined geometry
Energy Technology Data Exchange (ETDEWEB)
Wang, Siyuan; Jain, Chhavi; Wondraczek, Katrin; Kobelke, Jens [Leibniz Institute of Photonic Technology, Albert-Einstein-Str. 9, 07745 Jena (Germany); Wondraczek, Lothar [Otto Schott Institute of Material Research (OSIM), Friedrich Schiller University Jena, Fraunhoferstr. 6, 07743 Jena (Germany); Troles, Johann; Caillaud, Celine [Université de Rennes I, Equipe Verres et Céramiques, UMR 6226 Sciences Chimiques de Rennes, Campus de Beaulieu, 35042 Rennes (France); Schmidt, Markus A., E-mail: markus.schmidt@ipht-jena.de [Leibniz Institute of Photonic Technology, Albert-Einstein-Str. 9, 07745 Jena (Germany); Otto Schott Institute of Material Research (OSIM), Friedrich Schiller University Jena, Fraunhoferstr. 6, 07743 Jena (Germany)
2015-05-18
The flow of high-viscosity liquids inside micrometer-size holes can be substantially different from the flow in the bulk, non-confined state of the same liquid. Such non-Newtonian behavior can be employed to generate structural anisotropy in the frozen-in liquid, i.e., in the glassy state. Here, we report on the observation of non-Newtonian flow of an ultralow melting chalcogenide glass inside a silica microcapillary, leading to a strong deviation of the shear viscosity from its value in the bulk material. In particular, we experimentally show that the viscosity is radius-dependent, which is a clear indication that the microscopic rearrangement of the glass network needs to be considered if the lateral confinement falls below a certain limit. The experiments have been conducted using pressure-assisted melt filling, which provides access to the rheological properties of high-viscosity melt flow under previously inaccessible experimental conditions. The resulting flow-induced structural anisotropy can pave the way towards integration of anisotropic glasses inside hybrid photonic waveguides.
Experiments on densely-loaded non-Newtonian slurries in laminar and turbulent pipe flows
Park, Joel T.; Mannheimer, Richard J.; Grimley, Terrence A.; Morrow, Thomas B.
1989-06-01
An experimental description of the flow structure of non-Newtonian slurries in the laminar, transitional, and fully-developed turbulent pipe flow regimes was the primary objective of this research. Experiments were conducted in a large-scale pipe slurry flow facility with an inside diameter of 51 mm (2 inches). Approximately, 550 liters (145 gal) of slurry were necessary in the operation of the loop. Detailed velocity profile measurements by a two-color, two-component laser Doppler anemometer (LDA) were accomplished in a transparent test section with an optically transparent slurry. These velocity measurements were apparently the first ever reported for a non-Newtonian slurry with a yield value. The transparent slurry was formulated for these experiments from silica with a particle size of one to two microns, mineral oil, and Stoddard solvent. From linear regression analysis of concentric-cylinder viscometer data, the slurry exhibited yield-power-law behavior with a yield stress of 100 dynes/cm(sup 2), and an exponent of 0.630 for a solids concentration of 5.65 percent by weight. Good agreement was attained with rheological data derived from the pressure drop data in the flow loop under laminar flow conditions. The rheological properties of the transparent slurry were similar to many industrial slurries, including coal slurries, which have a yield value.
Directory of Open Access Journals (Sweden)
Jamshid M. Nouri
2008-03-01
Full Text Available Mean and rms velocity characteristics of two Newtonian flows at Reynolds numbers of 12,800 (glycerin solution and 48,000 (water and of a non-Newtonian flow (0.2% CMC solution, at a power number similar to the Newtonian glycerin flow in a mixing vessel stirred by a 60° pitched blade impeller have been measured by laser Doppler velocimetry (LDV. The velocity measurements, resolved over 360° and 1.08° of impeller rotation, showed that the mean flow of the two power number matched glycerin and CMC flows were similar to within 3% of the impeller tip velocity and the turbulence intensities generally lower in the CMC flow by up to 5% of the tip velocity. The calculated mean flow quantities showed similar discharge coefficient and pumping efficiency in all three flows and similar strain rate between the two power number matched glycerin and CMC flows; the strain rate of the higher Reynolds number Newtonian flow was found to be slightly higher. The energy balance around the impeller indicated that the CMC flow dissipated up to 9% more of the total input power and converted 7% less into the turbulence compared to the glycerin flow with the same power input which could lead to less effective mixing processes where the micro-mixing is important.
Minale, Mario; Caserta, Sergio; Guido, Stefano
2010-01-05
In this work, the microconfined shear deformation of a droplet in an equiviscous non-Newtonian immiscible fluid is investigated by modeling and experiments. A phenomenological model based on the assumption of ellipsoidal shape and taking into account wall effects is proposed for systems made of non-Newtonian second-order fluids. The model, without any adjustable parameters, is tested by comparison with experiments under simple shear flow performed in a sliding plate apparatus, where the ratio between the distance between the confining walls and the droplet radius can be varied. The agreement between model predictions and experimental data is good both in steady state shear and in transient drop retraction upon cessation of flow. The results obtained in this work are relevant for microfluidics applications where non-Newtonian fluids are used.
Directory of Open Access Journals (Sweden)
MM Movahedi
2008-03-01
Full Text Available Background: There is considerable evidence that vascular fluid dynamics plays an important role in the developmentand prevalence of atherosclerosis which is one of the most widespread disease in humans .The onset and prevalence of atherosclerosis hemodynamic parameter are largely affected by geometric parameters. If any obstacle interferes with the blood flow, the above parameters change dramatically. Most of the arterial diseases, such as atherosclerosis, occur in the arteries with complex patterns of fluid flow where the blood dynamics plays an important role. Arterial stenosis mostly occurs in an area with a complex pattern of fluid flow, such as coronary artery, aorta bifurcation, carotid and vessels of lower limbs. During the past three decades, many experimental studies have been performed on the hemodynamic role of the blood in forming sediment in the inner wall of the vessels. It has been shown that forming sediment in the inner wall of vessels depends on the velocity of fluid and also on the amount of wall shear stress.Methods: We have examined the effect on the blood flow of local stenosis in carotid artery in numerical form using the incompressible Navier-Stockes equations. The profile of the velocity in different parts and times in the pulsatile cycle, separation and reattachment points on the wall, the distance stability of flow and also alteration caused by the wall shear stress in entire vessel were shown and compared with two behaviors flow (Newtonian and Non-Newtonian.Finally we describe the influence of the severity of the stenosis on the separation and reattachmentpoints for a Non-Newtonian fuid. Results: In the present study, we have pointed very low and high oscillating WSS (Wall Shear Stress values play a significant role in the development of forming sediment in the inner wall of vessels. Also, we obtain this probability is higher for Newtonian than Non-Newtonian fluid behavior.Conclusion: Based on our results, the
Apparao, Siddangouda; Biradar, Trimbak Vaijanath; Naduvinamani, Neminath Bhujappa
2014-01-01
Theoretical study of non-Newtonian effects of second-order fluids on the performance characteristics of inclined slider bearings is presented. An approximate method is used for the solution of the highly nonlinear momentum equations for the second-order fluids. The closed form expressions for the fluid film pressure, load carrying capacity, frictional force, coefficient of friction, and centre of pressure are obtained. The non-Newtonian second order fluid model increases the film pressure, load carrying capacity, and frictional force whereas the center of pressure slightly shifts towards exit region. Further, the frictional coefficient decreases with an increase in the bearing velocity as expected for an ideal fluid.
Dynamical behaviour of non newtonian spiral blood flow through arterial stenosis
Ali, Mohammad; Mahmudul Hasan, Md.; Alam Maruf, Mahbub
2017-04-01
The spiral component of blood flow has both beneficial and detrimental effects in human circulatory system. A numerical investigation is carried out to analyze the effects of spiral blood flow through an axisymmetric three dimensional artery having 75% stenosis at the center. Blood is assumed as a non-Newtonian fluid. Standard k-ω model is used for the simulation with the Reynolds number of 1000. A parabolic velocity profile with spiral flow is used as inlet boundary condition. The peak values of all velocity components are found just after stenosis. But total pressure gradually decreases at downstream. Spiral flow of blood has significant effects on tangential component of velocity. However, the effect is mild for radial and axial velocity components. The peak value of wall shear stress is at the stenosis zone and decreases rapidly in downstream. The effect of spiral flow is significant for turbulent kinetic energy. Detailed investigation and relevant pathological issues are delineated throughout the paper.
Rheological non-Newtonian behaviour of ethylene glycol-based Fe2O3 nanofluids
Directory of Open Access Journals (Sweden)
Pastoriza-Gallego María
2011-01-01
Full Text Available Abstract The rheological behaviour of ethylene glycol-based nanofluids containing hexagonal scalenohedral-shaped α-Fe2O3 (hematite nanoparticles at 303.15 K and particle weight concentrations up to 25% has been carried out using a cone-plate Physica MCR rheometer. The tests performed show that the studied nanofluids present non-Newtonian shear-thinning behaviour. In addition, the viscosity at a given shear rate is time dependent, i.e. the fluid is thixotropic. Finally, using strain sweep and frequency sweep tests, the storage modulus G', loss modulus G″ and damping factor were determined as a function of the frequency showing viscoelastic behaviour for all samples.
Viscosity bio reducer Influence in a non-Newtonian fluid horizontal pipeline pressure gradient
Directory of Open Access Journals (Sweden)
Edgardo Jonathan Suarez-Dominguez
2014-03-01
Full Text Available Due to increased production of heavy and extra heavy crude in Mexico, it has led to the necessity touse chemicals to facilitate the transport in the pipe of our country. Experimental study was conductedto analyze the influence of a viscosity reducer of biological origin (BRV, on the rheological behaviorof heavy oil in the northern region of Mexico, finding that it exhibits a non-Newtonian viscoelasticbehavior, where a concentration increase of BRV leads to a consistency decrease and an increasedflow order, where dilatant behavior was observed in high temperatures. From these results it wasestimated the pressure losses by friction in a horizontal pipe for single phase and two phase flow. Wefound that in all cases the increase in the concentration of BRV reduces these losses.
Chen, Xiaodong
2012-01-01
In this video, Ray-tracing data visualization technique was used to obtain realistic and detailed flow motions during droplet collision. The differences of collision outcome between Newtonian and non-Newtonian were compared. Various types of droplet collision were presented, including bouncing, coalescence, and stretching separation. Because of the reducing of equivalent viscosity caused by shear stress, the gas film between shear-thinning droplet is thinner than Newtonian liquid. Since thinner gas film promotes coalescence, shear thinning liquid has smaller area of bouncing regime in the diagram of Weber number and impact parameter. During the ligament/thread breakup process of stretching separation, two kinds of instabilities are identified, helical and buckling instabilities. Helical instability is analogous to a viscous rotating liquid jet, while the buckling instability is analogous to electrically charged liquid jets of polymer solutions.
Magnetohydrodynamic third-grade non-Newtonian nanofluid flow through a porous coaxial cylinder
Sadikin, Zubaidah; Kechil, Seripah Awang
2015-10-01
The convective flow of third grade non-Newtonian nanofluid through porous coaxial cylinders with inclined magnetic field is investigated. The governing partial differential equations are transformed to a system of nonlinear ordinary differential equations using the non-dimensional quantities. The transformed system of nonlinear ordinary differential equations is solved numerically using the fourth-order Runge-Kutta method. The viscosity of the nanofluid is considered as a function of temperature in form of Vogel's model. Numerical solutions are obtained for the velocity, temperature and nanoparticles concentration. The effects of the some physical parameters particularly the angle of inclination, the magnetic, Brownian motion and thermophoresis parameters on non-dimensional velocity, temperature and nanoparticles concentration are analyzed. It is found that as the angle of inclination of magnetic field increases, the velocity decreases. The results also show that increasing the thermophoresis parameter and Brownian motion, the temperature increases. By increasing the Brownian motion or decreasing the thermophoresis parameter, nanoparticles concentration increases.
Coalescence of drops and bubbles rising through a non-Newtonian fluid in a tube.
Al-Matroushi, Eisa; Borhan, Ali
2009-04-01
We conducted an experimental study of the interaction and coalescence of two drops (of the same fluid) or bubbles translating under the action of buoyancy in a cylindrical tube. The close approach of two Newtonian fluid particles of different size in a non-Newtonian continuous phase was examined using image analysis, and measurements of the coalescence time are reported for various particle size ratios, Bond numbers, and particle-to-suspending-fluid viscosity ratios. The flow disturbance behind the leading bubble and the viscoelastic nature of the continuous phase seemed to retard bubble coalescence. The time scale for coalescence of liquid drops in highly elastic continuous phase was influenced by the relative motion of the drops and their coalescence behavior.
Acoustic waveform of continuous bubbling in a non-Newtonian fluid.
Vidal, Valérie; Ichihara, Mie; Ripepe, Maurizio; Kurita, Kei
2009-12-01
We study experimentally the acoustic signal associated with a continuous bubble bursting at the free surface of a non-Newtonian fluid. Due to the fluid rheological properties, the bubble shape is elongated, and, when bursting at the free surface, acts as a resonator. For a given fluid concentration, at constant flow rate, repetitive bubble bursting occurs at the surface. We report a modulation pattern of the acoustic waveform through time. Moreover, we point out the existence of a precursor acoustic signal, recorded on the microphone array, previous to each bursting. The time delay between this precursor and the bursting signal is well correlated with the bursting signal frequency content. Their joint modulation through time is driven by the fluid rheology, which strongly depends on the presence of small satellite bubbles trapped in the fluid due to the yield stress.
Mathematical simulation of nonisothermal filling of plane channel with non-Newtonian fluid
Borzenko, E.; Ryltseva, K.; Frolov, O.; Shrager, G.
2016-10-01
In this paper, the fountain flow of a non-Newtonian fluid during the filling of a plane vertical channel with due account of dissipative heating is investigated. The rheological features of the medium are defined by Ostwald de Waele power-law with exponential temperature dependence of viscosity. The numerical solution of the problem is obtained using a finite-difference method, based on the SIMPLE algorithm, and the method of invariants for compliance with the natural boundary conditions on free surface. It was shown that the flow separates into a two-dimensional flow zone in the vicinity of the free surface and a onedimensional flow zone away from it. The parametrical investigations of kinematic and thermophysical properties of the flow and the dependence of the free surface behavior on the basic criteria and rheological parameters are implemented.
Existence for a Class of Non-Newtonian Fluids with a Nonlocal Friction Boundary Condition
Institute of Scientific and Technical Information of China (English)
L.CONSIGLIERI
2006-01-01
We deal with a variational inequality describing the motion of incompressible fluids, whose viscous stress tensors belong to the subdifferential of a functional at the point given by the symmetric part of the velocity gradient, with a nonlocal friction condition on a part of the boundary obtained by a generalized mollification of the stresses. We establish an existence result of a solution to the nonlocal friction problem for this class of non-Newtonian flows. The result is based on the Faedo-Galerkin and Moreau-Yosida methods, the duality theory of convex analysis and the Tychonov-Kakutani-Glicksberg fixed point theorem for multi-valued mappings in an appropriate functional space framework.
Non-newtonian fluid flow through three-dimensional disordered porous media.
Morais, Apiano F; Seybold, Hansjoerg; Herrmann, Hans J; Andrade, José S
2009-11-06
We investigate the flow of various non-newtonian fluids through three-dimensional disordered porous media by direct numerical simulation of momentum transport and continuity equations. Remarkably, our results for power-law (PL) fluids indicate that the flow, when quantified in terms of a properly modified permeability-like index and Reynolds number, can be successfully described by a single (universal) curve over a broad range of Reynolds conditions and power-law exponents. We also study the flow behavior of Bingham fluids described in terms of the Herschel-Bulkley model. In this case, our simulations reveal that the interplay of (i) the disordered geometry of the pore space, (ii) the fluid rheological properties, and (iii) the inertial effects on the flow is responsible for a substantial enhancement of the macroscopic hydraulic conductance of the system at intermediate Reynolds conditions.
Similarity solutions for non-Newtonian power-law fluid flow
Institute of Scientific and Technical Information of China (English)
D.M.WEI; S.AL-ASHHAB
2014-01-01
The problem of the boundary layer flow of power law non-Newtonian fluids with a novel boundary condition is studied. The existence and uniqueness of the solutions are examined, which are found to depend on the curvature of the solutions for different values of the power law index n. It is established with the aid of the Picard-Lindel¨of theorem that the nonlinear boundary value problem has a unique solution in the global domain for all values of the power law index n but with certain conditions on the curva-ture of the solutions. This is done after a suitable transformation of the dependent and independent variables. For 0 1, the solution has a negative or zero curvature on some part of the global domain. Some solutions are presented graphically to illustrate the results and the behaviors of the solutions.
Generalized multiscale finite element method for non-Newtonian fluid flow in perforated domain
Chung, E. T.; Iliev, O.; Vasilyeva, M. V.
2016-10-01
In this work, we consider a non-Newtonian fluid flow in perforated domains. Fluid flow in perforated domains have a multiscale nature and solution techniques for such problems require high resolution. In particular, the discretization needs to honor the irregular boundaries of perforations. This gives rise to a fine-scale problems with many degrees of freedom which can be very expensive to solve. In this work, we develop a multiscale approach that attempt to solve such problems on a coarse grid by constructing multiscale basis functions. We follow Generalized Multiscale Finite Element Method (GMsFEM) [1, 2] and develop a multiscale procedure where we identify multiscale basis functions in each coarse block using snapshot space and local spectral problems [3, 4]. We show that with a few basis functions in each coarse block, one can accurately approximate the solution, where each coarse block can contain many small inclusions.
A numerical solution for the entrance region of non-newtonian flow in annuli
Directory of Open Access Journals (Sweden)
Maia M.C.A.
2003-01-01
Full Text Available Continuity and momentum equations applied to the entrance region of an axial, incompressible, isothermal, laminar and steady flow of a power-law fluid in a concentric annulus, were solved by a finite difference implicit method. The Newtonian case was solved used for validation of the method and then compared to reported results. For the non-Newtonian case a pseudoplastic power-law model was assumed and the equations were transformed to obtain a pseudo-Newtonian system which enabled its solution using the same technique as that used for the Newtonian case. Comparison of the results for entrance length and pressure drop with those available in the literature showed a qualitative similarity, but significant quantitative differences. This can be attributed to the differences in entrance geometries and the definition of asymptotic entrance length.
Exact Solutions for Stokes' Flow of a Non-Newtonian Nanofluid Model: A Lie Similarity Approach
Aziz, Taha; Aziz, A.; Khalique, C. M.
2016-07-01
The fully developed time-dependent flow of an incompressible, thermodynamically compatible non-Newtonian third-grade nanofluid is investigated. The classical Stokes model is considered in which the flow is generated due to the motion of the plate in its own plane with an impulsive velocity. The Lie symmetry approach is utilised to convert the governing nonlinear partial differential equation into different linear and nonlinear ordinary differential equations. The reduced ordinary differential equations are then solved by using the compatibility and generalised group method. Exact solutions for the model equation are deduced in the form of closed-form exponential functions which are not available in the literature before. In addition, we also derived the conservation laws associated with the governing model. Finally, the physical features of the pertinent parameters are discussed in detail through several graphs.
The Non-Newtonian Rheology of Real Magmas: insights into 3D microstructures
Pistone, M.; Caricchi, L.; Ulmer, P.; Reusser, E.; Marone, F.; Burlini, L.
2010-12-01
We present high-resolution 3D microstructures of three-phase magmas composed of melt, bubbles and crystals in different proportions deformed at magmatic pressure and temperature conditions. This study aims to constrain the dependence of rheological and physical properties of magmas on the viscosity of the silicate melt, the applied deformation rate, the relative contents of crystals and bubbles and on the interactions between these phases. The starting material is composed of a hydrous haplogranitic melt containing H2O (2.26 wt%) and CO2 (624 ppm) and different proportions of quartz crystals (between 24 and 65 vol%; 63-125 μm in diameter) and bubbles (between 9 and 12 vol%; 5-150 μm in diameter). Experiments were performed in simple shear using a HT-HP internally-heated Paterson-type rock deformation apparatus (Paterson and Olgaard, 2000) at strain rates ranging between 5×10-5 s-1 and 4×10-3 s-1, at a constant pressure of 200 MPa and temperatures ranging between 723 and 1023 K. Synchrotron based X-ray tomographic microscopy performed at the TOMCAT beamline (Stampanoni et al., 2006) at the Swiss Light Source enabled quantitative evaluation of the 3D microstructure. At high temperature and low strain rate conditions the silicate melt behaves as a Newtonian liquid (Webb and Dingwell, 1990). Higher deformation rates and the contemporary presence of gas bubbles and solid crystals make magma rheology more complex and non-Newtonian behaviour occurs. In all experimental runs two different non-Newtonian effects were observed: shear thinning (decrease of viscosity with increasing strain rate) in high crystal-content magmas (55-65 vol% crystals; 9-10 vol% bubbles) and shear thickening (increase of viscosity with increasing strain rate) in magmas at lower degree of crystallinity (24 vol% crystals; 12 vol% bubbles). Both behaviours were observed at intermediate crystal-content (44 vol% crystals; 12 vol% bubbles), with an initial thickening that subsequently gives way to
Geometry of elastic hydrofracturing by injection of an over pressured non-Newtonian Fluid
Cerca, Mariano; Barrientos, Bernardino; Soto, Enrique; Mares, Carlos
2009-01-01
The nucleation and propagation of hydrofractures by injection of over pressured fluids in an elastic and isotropic medium are studied experimentally. Non-Newtonian fluids are injected inside a gelatine whose mechanical properties are assumed isotropic at the experimental strain rates. Linear elastic theory predicts that plastic deformation associated to breakage of gelatin bonds is limited to a small zone ahead of the tip of the propagating fracture and that propagation will be maintained while the fluid pressure exceeds the normal stress to the fracture walls (Ch\\'avez-\\'Alvarez,2008) (i.e., the minimum compressive stress), resulting in a single mode I fracture geometry. However, we observed the propagation of fractures type II and III as well as nucleation of secondary fractures, with oblique to perpendicular trajectories with respect to the initial fracture. In the Video (http://hdl.handle.net/1813/14122) experimental evidence shows that the fracture shape depends on the viscoelastic properties of gelatine...
Non-newtonian flow and pressure drop of pineapple juice in a plate heat exchanger
Directory of Open Access Journals (Sweden)
R. A. F. Cabral
2010-12-01
Full Text Available The study of non-Newtonian flow in plate heat exchangers (PHEs is of great importance for the food industry. The objective of this work was to study the pressure drop of pineapple juice in a PHE with 50º chevron plates. Density and flow properties of pineapple juice were determined and correlated with temperature (17.4 < T < 85.8ºC and soluble solids content (11.0 < Xs < 52.4 ºBrix. The Ostwald-de Waele (power law model described well the rheological behavior. The friction factor for non-isothermal flow of pineapple juice in the PHE was obtained for diagonal and parallel/side flow. Experimental results were well correlated with the generalized Reynolds number (20 < Re g < 1230 and were compared with predictions from equations from the literature. The mean absolute error for pressure drop prediction was 4% for the diagonal plate and 10% for the parallel plate.
ON THE FILTRATION OF NON-NEWTONIAN FLUID IN POROUS MEDIA WITH A MULTIPLE PARAMETER MODEL
Institute of Scientific and Technical Information of China (English)
无
2001-01-01
A multiple parameter model to describe the Non-Newtonianproperties of fluid filtration in porous media is presented with regard to the pressure gradient expression in terms of the velocity of filtration, where the multiple parameters should be determined by measurements. Based on such a model, an analysis was furnished to deduce the formula for the rate of production of a oil well, and the governing equations for single phase Non-Newtonian fluid fritration. In order to examine the effects of model parameters, the governing equations were numerically solved with the method of cross-diagonal decomposition ZG method. It is found that, for constant rate of production, the power index n of the model influences the pressure distribution considerably, particularly in the vicinity of a single well. The well-bore pressure of Leibenzonian fluid is lower than that of the power-law fluid in the case of the same parameter B and the power index n = 0.5.
Free surface flow of a suspension of rigid particles in a non-Newtonian fluid
DEFF Research Database (Denmark)
Svec, Oldrich; Skocek, Jan; Stang, Henrik
2012-01-01
efficient, allowing simulations of tens of thousands of rigid particles within a reasonable computational time. Furthermore, the framework does not require any fitting constants or parameters devoid of a clear physical meaning and it is stable, robust and can be easily generalized to a variety of problems......A numerical framework capable of predicting the free surface flow of a suspension of rigid particles in a non-Newtonian fluid is described. The framework is a combination of the lattice Boltzmann method for fluid flow, the mass tracking algorithm for free surface representation, the immersed...... boundary method for two-way coupled interactions between fluid and rigid particles and an algorithm for the dynamics and mutual interactions of rigid particles. The framework is able to simulate the flow of suspensions at the level of the largest suspended particles and, at the same time, the model is very...
Modeling of flow of particles in a non-Newtonian fluid using lattice Boltzmann method
DEFF Research Database (Denmark)
Skocek, Jan; Svec, Oldrich; Spangenberg, Jon
2011-01-01
To predict correctly the castings process of self compacting concrete a numerical model capable of simulating flow patterns at the structural scale and at the same time the impact of the varying volume fraction of aggregates and other phenomena at the scale of aggregates on the flow evolution...... is necessary. In this contribution, the model at the scale of aggregates is introduced. The conventional lattice Boltzmann method for fluid flow is enriched with the immersed boundary method with direct forcing to simulate the flow of rigid particles in a non- Newtonian liquid. Basic ingredients of the model...... are presented and discussed with the emphasis on a newly developed algorithm for the dynamics of particles whose interactions strongly depend on velocities of particles. The application of the model is demonstrated by a parametric study with varying volume fractions of aggregates and speed of shearing used...
Force effects on rotor of squeeze film damper using Newtonian and non-Newtonian fluid
Dominik, Šedivý; Petr, Ferfecki; Simona, Fialová
2017-09-01
This article presents the evaluation of force effects on rotor of squeeze film damper. Rotor is eccentric placed and its motion is translate-circular. The amplitude of rotor motion is smaller than its initial eccentricity. The force effects are calculated from pressure and viscous forces which were gained by using computational modeling. Two types of fluid were considered as filling of damper. First type of fluid is Newtonian (has constant viscosity) and second type is magnetorheological fluid (does not have constant viscosity). Viscosity of non-Newtonian fluid is given using Bingham rheology model. Yield stress is a function of magnetic induction which is described by many variables. The most important variables of magnetic induction are electric current and gap width which is between rotor and stator. Comparison of application two given types of fluids is shown in results.
Numerical simulation of pulsatile non-Newtonian flow in the carotid artery bifurcation
Fan, Yubo; Jiang, Wentao; Zou, Yuanwen; Li, Jinchuan; Chen, Junkai; Deng, Xiaoyan
2009-04-01
Both clinical and post mortem studies indicate that, in humans, the carotid sinus of the carotid artery bifurcation is one of the favored sites for the genesis and development of atherosclerotic lesions. Hemodynamic factors have been suggested to be important in atherogenesis. To understand the correlation between atherogenesis and fluid dynamics in the carotid sinus, the blood flow in artery was simulated numerically. In those studies, the property of blood was treated as an incompressible, Newtonian fluid. In fact, however, the blood is a complicated non-Newtonian fluid with shear thinning and viscoelastic properties, especially when the shear rate is low. A variety of non-Newtonian models have been applied in the numerical studies. Among them, the Casson equation was widely used. However, the Casson equation agrees well only when the shear rate is less than 10 s-1. The flow field of the carotid bifurcation usually covers a wide range of shear rate. We therefore believe that it may not be sufficient to describe the property of blood only using the Casson equation in the whole flow field of the carotid bifurcation. In the present study, three different blood constitutive models, namely, the Newtonian, the Casson and the hybrid fluid constitutive models were used in the flow simulation of the human carotid bifurcation. The results were compared among the three models. The results showed that the Newtonian model and the hybrid model had very similar distributions of the axial velocity, secondary flow and wall shear stress, but the Casson model resulted in significant differences in these distributions from the other two models. This study suggests that it is not appropriate to only use the Casson equation to simulate the whole flow field of the carotid bifurcation, and on the other hand, Newtonian fluid is a good approximation to blood for flow simulations in the carotid artery bifurcation.
Numerical simulation of pulsatile non-Newtonian flow in the carotid artery bifurcation
Institute of Scientific and Technical Information of China (English)
Yubo Fan; Wentao Jiang; Yuanwen Zou; Jinchuan Li; Junkai Chen; Xiaoyan Deng
2009-01-01
Both clinical and post mortem studies indicate that, in humans, the carotid sinus of the carotid artery bifurcation is one of the favored sites for the genesis and development of atherosclerotic lesions. Hemodynamic factors have been suggested to be important in atherogenesis. To understand the correlation between atherogenesis and fluid dynamics in the carotid sinus, the blood flow in artery was simulated numerically. In those studies, the property of blood was treated as an incompressible, Newtonian fluid. In fact,however, the blood is a complicated non-Newtonian fluid with shear thinning and viscoelastic properties, especially when the shear rate is low. A variety of non-Newtonian models have been applied in the numerical studies. Among them,the Casson equation was widely used. However, the Casson equation agrees well only when the shear rate is less than 10s-1. The flow field of the carotid bifurcation usually covers a wide range of shear rate. We therefore believe that it may not be sufficient to describe the property of blood only using the Casson equation in the whole flow field of the carotid bifurcation. In the present study, three different blood constitutive models, namely, the Newtonian, the Casson and the hybrid fluid constitutive models were used in the flow simulation of the human carotid bifurcation. The results were compared among the three models. The results showed that the Newtonian model and the hybrid model had very similar distributions of the axial velocity, secondary flow and wall shear stress, but the Casson model resulted in significant differences in these distributions from the other two models. This study suggests that it is not appropriate to only use the Casson equation to simulate the whole flow field of the carotid bifurcation, and on the other hand, Newtonian fluid is a good approximation to blood for flow simulations in the carotid artery bifurcation.
Break-up of a non-Newtonian jet injected downwards in a Newtonian liquid
Indian Academy of Sciences (India)
Absar M Lakdawala; Rochish Thaokar; Atul Sharma
2015-05-01
The present work on downward injection of non-Newtonian jet is an extension of our recent work (Lakdawala et al, Int. J. Multiphase Flow. 59: 206–220, 2014) on upward injection of Newtonian jet. The non-Newtonian rheology of the jet is described by a Carreau type generalized Newtonian fluid (GNF) model, which is a phenomenological constitutive equation that accounts for both rate-thinning and rate-thickening. Level set method based numerical study is done for Newtonian as well as various types of shear thinning and thickening jet fluid. Effect of average injection velocity ($V_{av,i}$) is studied at a constant Reynolds number Re = 14.15, Weber number W e = 1, Froude number F r = 0.25, density ratio $\\chi$ = 0.001 and viscosity ratio $\\eta$ = 0.01. CFD analysis of the temporal variation of interface and jet length ($L_{j}$) is done to propose different types of jet breakup regimes. At smaller, intermediate and larger values of $V_{av,i}$, the regimes found are periodic uniform drop (P-UD), quasi-periodic non-uniform drop (QP-NUD) and no breakup (NB) regimes for a shear thinning jet; and periodic along with Satellite Drop (P+S), jetting (J) and no breakup (NB) regimes for a shear thickening jet, respectively. This is presented as a drop-formation regime map. Shear thickening (thinning) is shown to produce long (short) jet length. Diameter of the primary drop increases and its frequency of release decreases, due to increase in stability of the jet for shear thickening as compared to thinning fluid.
2011-09-21
... Forest Service Information Collection; Qualified Products List for Water Enhancers (Gels) for Wildland... Products List for Water Enhancers (Gels) for Wildland Firefighting. DATES: Comments must be received in.... SUPPLEMENTARY INFORMATION: Title: Qualified Products List for Water Enhancers (Gels) for Wildland...
Sojka, Paul E.; Rodrigues, Neil S.
2015-11-01
The current study investigates the drop characteristics of three Carboxymethylcellulose (CMC) sprays produced by the impingement of two liquid jets. The three water-based solutions used in this work (0.5 wt.-% CMC-7MF, 0.8 wt.-% CMC-7MF, and 1.4 wt.-% CMC-7MF) exhibited strong shear-thinning, non-Newtonian behavior - characterized by the Bird-Carreau rheological model. A generalized Bird-Carreau jet Reynolds number was used as the primary parameter to characterize the drop size and the drop velocity, which were measured using Phase Doppler Anemometry (PDA). PDA optical configuration enabled a drop size measurement range of approximately 2.3 to 116.2 μm. 50,000 drops were measured at each test condition to ensure statistical significance. The arithmetic mean diameter (D10) , Sauter mean diameter (D32) , and mass median diameter (MMD) were used as representative diameters to characterize drop size. The mean axial drop velocity Uz -mean along with its root-mean square Uz -rms were used to characterize drop velocity. Incredibly, measurements for all three CMC liquids and reference DI water sprays seemed to follow a single curve for D32 and MMD drop diameters in the high generalized Bird-Carreau jet Reynolds number range considered in this work (9.21E +03
Sun, Kai; Wang, Tianyou; Zhang, Peng; Law, Chung K
2015-02-01
The coalescence of two initially stationary droplets of shear-thinning fluids in a gaseous environment is investigated numerically using the lattice Boltzmann method, with particular interest in non-Newtonian flow effects on the internal mixing subsequent to coalescence. Coalescence of equal-sized droplets, with one being Newtonian while the other is non-Newtonian, leads to the non-Newtonian droplet wrapping around the Newtonian one and hence minimal fine-scale mixing. For unequal-sized droplets, mixing is greatly promoted if both droplets are shear-thinning. When only one of the droplets is shear-thinning, the non-Newtonian effect from the smaller droplet is found to be significantly more effective than that from the larger droplet in facilitating internal jetlike mixing. Parametric study with the Carreau-Yasuda model indicates that the phenomena are universal to a wide range of shear-thinning fluids, given that the extent of shear thinning reaches a certain level, and the internal jet tends to be thicker and develops more rapidly with increasing extent of the shear-thinning effect.
On the rheology of refractive-index-matched, non-Newtonian blood-analog fluids for PIV experiments
Najjari, Mohammad Reza; Hinke, Jessica A.; Bulusu, Kartik V.; Plesniak, Michael W.
2016-06-01
Four commonly used refractive-index (RI)-matched Newtonian blood-analog fluids are reviewed, and different non-Newtonian blood-analogs, with RI of 1.372-1.495, are investigated. Sodium iodide (NaI), sodium thiocyanate (NaSCN) and potassium thiocyanate are used to adjust the RI of blood-analogs to that of test sections for minimizing optical distortions in particle image velocimetry data, and xanthan gum (XG) is added to the fluids to give them non-Newtonian properties (shear thinning and viscoelasticity). Our results support the general belief that adding NaI to Newtonian fluids matches the RI without changing the kinematic viscosity. However, in contrast to claims made in a few studies that did not measure rheology, our investigation revealed that adding NaI or NaSCN to XG-based non-Newtonian fluids changes the viscosity of the fluids considerably and reduces the shear-thinning property. Therefore, the RI of non-Newtonian blood-analog fluids with XG cannot be adjusted easily by varying the concentration of NaI or NaSCN and needs more careful rheological study.
Energy Technology Data Exchange (ETDEWEB)
Lipscombe, T C [Johns Hopkins University, 2715 North Charles Street, Baltimore, MD 21218 (United States)], E-mail: tcl@press.jhu.edu
2010-03-15
We solve exactly the Poiseuille and Couette flows of a non-Newtonian fluid discussed by Roohi et al (2009 Phys. Scr. 79 065009) and thereby show that the approximate analytical solutions provided by the homotopy method must be used with caution.
Boundary layer flow on a moving surface in otherwise quiescent pseudo-plastic non-Newtonian fluids
Institute of Scientific and Technical Information of China (English)
Liancun Zheng; Liu Ting; Xinxin Zhang
2008-01-01
A theoretical analysis for the boundary layer flow over a continuous moving surface in an otherwise quiescent pseudo-plastic non-Newtonian fluid medium was presented. The types of potential flows necessary for similar solutions to the boundary layer equations were determined and the solutions were numerically presented for different values of power law exponent.
Marrero, Victor; Sahni, Onkar; Jansen, Kenneth; Tichy, John; Taylor, Charles
2008-11-01
In recent years the methods of computational fluid dynamics (CFD) have been applied to the human cardiovascular system to better understand the relationship between arterial blood flow and the disease process, for example in an abdominal aortic aneurysm (AAA). Obviously, the technical challenges associated with such modeling are formidable. Among the many problems to be addressed, in this paper we add yet another complication -- the known non-Newtonian nature of blood. In this preliminary study, we used a patient-based AAA model with rigid walls. The pulsatile nature of the flow and the RCR outflow boundary condition are considered. We use the Carreau-Yasuda model to describe the non-Newtonian viscosity variation. Preliminary results for 200K, 2M, and 8M elements mesh are presented for the Newtonian and non-Newtonian cases. The broad fundamental issue we wish to eventually resolve is whether or not non-Newtonian effects in blood flow are sufficiently strong in unhealthy vessels that they must be addressed in meaningful simulations. Interesting differences during the flow cycle shed light on the problem, but further research is needed.
DEFF Research Database (Denmark)
Jabbaribehnam, Mirmasoud; Spangenberg, Jon; Hattel, Jesper Henri
2016-01-01
In this paper, the migration of secondary particles in a non-Newtonian ceramic slurry inthe tape casting process is investigated with the purpose of understanding the particle distribution patterns along the casting direction. The Ostwald-de Waele power law model for the non-Newtonian flow...
Walker, Andrew M; Johnston, Clifton R; Rival, David E
2012-11-01
Although deployed in the vasculature to expand vessel diameter and improve blood flow, protruding stent struts can create complex flow environments associated with flow separation and oscillating shear gradients. Given the association between magnitude and direction of wall shear stress (WSS) and endothelial phenotype expression, accurate representation of stent-induced flow patterns is critical if we are to predict sites susceptible to intimal hyperplasia. Despite the number of stents approved for clinical use, quantification on the alteration of hemodynamic flow parameters associated with the Gianturco Z-stent is limited in the literature. In using experimental and computational models to quantify strut-induced flow, the majority of past work has assumed blood or representative analogs to behave as Newtonian fluids. However, recent studies have challenged the validity of this assumption. We present here the experimental quantification of flow through a Gianturco Z-stent wire in representative Newtonian and non-Newtonian blood analog environments using particle image velocimetry (PIV). Fluid analogs were circulated through a closed flow loop at physiologically appropriate flow rates whereupon PIV snapshots were acquired downstream of the wire housed in an acrylic tube with a diameter characteristic of the carotid artery. Hemodynamic parameters including WSS, oscillatory shear index (OSI), and Reynolds shear stresses (RSS) were measured. Our findings show that the introduction of the stent wire altered downstream hemodynamic parameters through a reduction in WSS and increases in OSI and RSS from nonstented flow. The Newtonian analog solution of glycerol and water underestimated WSS while increasing the spatial coverage of flow reversal and oscillatory shear compared to a non-Newtonian fluid of glycerol, water, and xanthan gum. Peak RSS were increased with the Newtonian fluid, although peak values were similar upon a doubling of flow rate. The introduction of the
Sharifi, Alireza; Niazmand, Hamid
2015-10-01
Carotid siphon is known as one of the risky sites among the human intracranial arteries, which is prone to formation of atherosclerotic lesions. Indeed, scientists believe that accumulation of low density lipoprotein (LDL) inside the lumen is the major cause of atherosclerosis. To this aim, three types of internal carotid artery (ICA) siphon have been constructed to examine variations of hemodynamic parameters in different regions of the arteries. Providing real physiological conditions, blood considered as non-Newtonian fluid and real velocity and pressure waveforms have been employed as flow boundary conditions. Moreover, to have a better estimation of risky sites, the accumulation of LDL particles has been considered, which has been usually ignored in previous relevant studies. Governing equations have been discretized and solved via open source OpenFOAM software. A new solver has been built to meet essential parameters related to the flow and mass transfer phenomena. In contrast to the common belief regarding negligible effect of blood non-Newtonian behavior inside large arteries, current study suggests that the non-Newtonian blood behavior is notable, especially on the velocity field of the U-type model. In addition, it is concluded that neglecting non-Newtonian effects underestimates the LDL accumulation up to 3% in the U-type model at the inner side of both its bends. However, in the V and C type models, non-Newtonian effects become relatively small. Results also emphasize that the outer part of the second bend at the downstream is also at risk similar to the inner part of the carotid bends. Furthermore, from findings it can be implied that the risky sites strongly depend on the ICA shape since the extension of the risky sites are relatively larger for the V-type model, while the LDL concentrations are higher for the C-type model.
Steady-state leaching of tritiated water from silica gel
DEFF Research Database (Denmark)
Das, H.A.; Hou, Xiaolin
2009-01-01
Aqueous leaching of tritium from silica gel, loaded by absorption of water vapor, makes part of reactor de-commissioning. It is found to follow the formulation of steady-state diffusion.......Aqueous leaching of tritium from silica gel, loaded by absorption of water vapor, makes part of reactor de-commissioning. It is found to follow the formulation of steady-state diffusion....
Steady-state leaching of tritiated water from silica gel
DEFF Research Database (Denmark)
Das, H.A.; Hou, Xiaolin
2009-01-01
Aqueous leaching of tritium from silica gel, loaded by absorption of water vapor, makes part of reactor de-commissioning. It is found to follow the formulation of steady-state diffusion.......Aqueous leaching of tritium from silica gel, loaded by absorption of water vapor, makes part of reactor de-commissioning. It is found to follow the formulation of steady-state diffusion....
Mechanism of Concentration Dependence of Water Diffusivity in Polyacrylate Gels
Mani, Sriramvignesh; Khabaz, Fardin; Khare, Rajesh
Membrane based separation processes offer an energy efficient alternative to traditional distillation based separation processes. In this work, we focus on the molecular mechanisms underlying the process of separation of dilute ethanol-water mixture using polyacrylate gels as pervaporation membranes. The diffusivities of the components in swollen gels exhibit concentration dependence. We have used molecular dynamics (MD) simulations to study the correlation between the dynamics of solvent (water and ethanol) molecules, polymer dynamics and solvent structure in the swollen gel systems as a function of solvent concentration. Three different polyacrylate gels were studied: (1) poly n-butyl acrylate (PBA), (2) copolymer of butyl acrylate and 2-hydroxyethyl acrylate P(BA50-HEA50), and (3) poly 2-hydroxyethyl acrylate (PHEA). Simulation results show that solvent concentration has a significant effect on local structure of the solvent molecules and chain dynamics; these factors (local structure and chain dynamics), in turn, affect the diffusivity of these molecules. At low concentration, solvent molecules are well dispersed in the gel matrix and form hydrogen bonds with the polymer. Solvent mobility is correlated with polymer mobility in this configuration and consequently water and ethanol molecules exhibit slower dynamics, this effect is especially significant in PHEA gel. At high solvent concentration, water molecules form large clusters in the system accompanied by enhancement in mobility of both the gel network and the solvent molecules.
Experimental investigation of non-Newtonian/Newtonian liquid-liquid flow in microchannel
Roumpea, Eynagelia-Panagiota; Weheliye, Weheliye; Chinaud, Maxime; Angeli, Panagiota; Lyes Kahouadji Collaboration; Omar. K. Matar Collaboration
2015-11-01
Plug flow of an organic phase and an aqueous non-Newtonian solution was investigated experimentally in a quartz microchannel with I.D. 200 μm. The aqueous phase was a glycerol solution where 1000 and 2000 ppm of xanthan gum was added while the organic phase was silicon oil with 155 and 5 cSt viscosity. The two phases were brought together in a T-junction and their flowrates varied from 0.3 to 6 ml/hr. High speed imaging was used to study the characteristics of the plugs and the effect of the liquid properties on the flow patterns while a two-colour micro-PIV technique was used to investigate velocity profiles and circulation patterns within the plugs. The experimental results revealed that plug length was affected by both flowrate and viscosity. In all cases investigated, a film of the continuous phase always surrounded the plugs and its thickness was compared with existing literature models. Circulation patterns inside plugs were obtained by subtracting the plug velocity and found to be depended on the plug length and the amount of xanthan gum in the aqueous phase. Finally, the dimensionless circulation time was calculated and plotted as a function of the plug length. Department of Chemical Engineering South Kensington Campus Imperial College London SW7 2AZ.
Ochowiak, Marek; Matuszak, Magdalena; Włodarczak, Sylwia
2017-08-01
The article contains results of the experimental studies on atomization process of inhaled drugs and aqueous solutions of glycerol with aqueous solutions of glycerol polyacrylamide (Rokrysol WF1) in pneumatic nebulizers. In experiments, the different concentration of aqueous solutions of glycerol polyacrylamide have been tested. In addition, the effect of nebulizer design on atomization process has been determined. The one of the main elements of medical pneumatic nebulizer is nebulizer cup. The experiment with this scope is new and is very important from the point of view of aerosol therapy. The results have been obtained by the use of the digital microphotography technique. In order to determine a physicochemical properties of tested liquids, a rheological measurements and measurements of the surface tension were carried out. The differences between characteristics of aerosol for the liquids have been observed. The analysis of the droplets size distributions shows that the different diameters of droplets for Newtonian and non-Newtonian fluids have been formed during atomization in pneumatic nebulizers equipped with different nebulizer cups. The effect of the mouthpiece location on the droplets diameters has been shown. Precise design of nebulizer and nebulizer cups, and also physicochemical properties of atomized liquids are of high importance in order to the effectiveness of drug delivery to patient's respiratory tracts.
Mass transport in a porous microchannel for non-Newtonian fluid with electrokinetic effects.
Mondal, Sourav; De, Sirshendu
2013-03-01
Quantification of mass transfer in porous microchannel is of paramount importance in several applications. Transport of neutral solute in presence of convective-diffusive EOF having non-Newtonian rheology, in a porous microchannel was presented in this article. The governing mass transfer equation coupled with velocity field was solved along with associated boundary conditions using a similarity solution method. An analytical solution of mass transfer coefficient and hence, Sherwood number were derived from first principles. The corresponding effects of assisting and opposing pressure-driven flow and EOF were also analyzed. The influence of wall permeation, double-layer thickness, rheology, etc. on the mass transfer was also investigated. Permeation at the wall enhanced the mass transfer coefficient more than five times compared to impervious conduit in case of pressure-driven flow assisting the EOF at higher values of κh. Shear thinning fluid exhibited more enhancement of Sherwood number in presence of permeation compared to shear thickening one. The phenomenon of stagnation was observed at a particular κh (∼2.5) in case of EOF opposing the pressure-driven flow. This study provided a direct quantification of transport of a neutral solute in case of transdermal drug delivery, transport of drugs from blood to target region, etc.
Wu, Binxin
2010-12-01
In this paper, 12 turbulence models for single-phase non-newtonian fluid flow in a pipe are evaluated by comparing the frictional pressure drops obtained from computational fluid dynamics (CFD) with those from three friction factor correlations. The turbulence models studied are (1) three high-Reynolds-number k-ε models, (2) six low-Reynolds-number k-ε models, (3) two k-ω models, and (4) the Reynolds stress model. The simulation results indicate that the Chang-Hsieh-Chen version of the low-Reynolds-number k-ε model performs better than the other models in predicting the frictional pressure drops while the standard k-ω model has an acceptable accuracy and a low computing cost. In the model applications, CFD simulation of mixing in a full-scale anaerobic digester with pumped circulation is performed to propose an improvement in the effective mixing standards recommended by the U.S. EPA based on the effect of rheology on the flow fields. Characterization of the velocity gradient is conducted to quantify the growth or breakage of an assumed floc size. Placement of two discharge nozzles in the digester is analyzed to show that spacing two nozzles 180° apart with each one discharging at an angle of 45° off the wall is the most efficient. Moreover, the similarity rules of geometry and mixing energy are checked for scaling up the digester.
Study on Flow Characteristic of Non-Newtonian fluid in Eccentric Annulus
Directory of Open Access Journals (Sweden)
Li Mingzhong
2013-08-01
Full Text Available This study studied the flow characteristic of non-newtonian in eccentric annulus of highly-deviated well. On the basis of dimensionless analysis of motion equations and continuity equation, Hele-Shaw model suitable for fluid flow in the annulus was derived. Combined with H-B rheological model, velocity and stream distribution model were founded and calculated by numerical method. Furthermore, two-dimensional flow characteristic in eccentric annulus was got and the influence of different factors (such as yield stress, pressure gradient or eccentricity on velocity distribution in condition of laminar flow was analyzed. Width of flow core in the annular is proportional to yield stress and inversely proportional to pressure gradient. In eccentric annulus, eccentricity influences the stream distribution remarkably: with the increment of eccentricity, the contour lines of stream function gradually centralize in the widest annular gap, however distribute the most loosely in the narrowest annular gap. Axial velocity is the largest in the widest gap. The larger eccentricity is, the larger contrast of axial velocity between in the widest gap and in the narrowest gap is. There is the largest azimuthal velocity in an annular gap of a certain azimuthal angle, however which equals to zero in the widest and narrowest annular gap separately. The larger eccentricity is, the more homogeneous azimuthal velocity is. The velocity contrast in the entire annulus can be smoothed by increasing pressure gradient, power law index or decreasing yield stress.
Viscoelastic fluid-structure interaction between a non-Newtonian fluid flow and flexible cylinder
Dey, Anita; Modarres-Sadeghi, Yahya; Rothstein, Jonathan
2016-11-01
It is well known that when a flexible or flexibly-mounted structure is placed perpendicular to the flow of a Newtonian fluid, it can oscillate due to the shedding of separated vortices at high Reynolds numbers. If the same flexible object is placed in non-Newtonian flows, however, the structure's response is still unknown. Unlike Newtonian fluids, the flow of viscoelastic fluids can become unstable at infinitesimal Reynolds numbers due to a purely elastic flow instability. In this talk, we will present a series of experiments investigating the response of a flexible cylinder placed in the cross flow of a viscoelastic fluid. The elastic flow instabilities occurring at high Weissenberg numbers can exert fluctuating forces on the flexible cylinder thus leading to nonlinear periodic oscillations of the flexible structure. These oscillations are found to be coupled to the time-dependent state of viscoelastic stresses in the wake of the flexible cylinder. The static and dynamic responses of the flexible cylinder will be presented over a range of flow velocities, along with measurements of velocity profiles and flow-induced birefringence, in order to quantify the time variation of the flow field and the state of stress in the fluid.
Non-Newtonian fluids: Frictional pressure loss prediction for fully-developed flow in straight pipes
1991-10-01
ESDU 91025 discusses models used to describe the rheology of time independent pseudohomogeneous non-Newtonian fluids (power-law, Bingham, Herschel-Bulkley and a generalized model due to Metzner and Reed); they are used to calculate the laminar flow pressure drop (which is independent of pipe roughness in this regime). Values of a generalized Reynolds number are suggested to define transitional and turbulent flow. For turbulent flow in smooth pipes, pressure loss is estimated on the basis of an experimentally determined rheogram using either the Dodge-Metzner or Bowen approach depending on the available measurements. Bowen requires results for at least two pipe diameters. The choice of Dodge-Metzner when data are limited is discussed; seven possible methods are assessed against five sets of experimental results drawn from the literature. No method is given for transitional flow, which it is suggested should be avoided, but the turbulent correlation is recommended because it will yield an overestimate. Suggestions are made for the treatment of roughness effects. Several worked examples illustrate the use of the methods and a flowchart guides the user through the process from experimentally characterizing the behavior of the fluid to determining the pressure drop. A computer program, ESDUpac A9125, is also provided.
The effect of non-Newtonian viscosity on the stability of the Blasius boundary layer
Griffiths, P. T.; Gallagher, M. T.; Stephen, S. O.
2016-07-01
We consider, for the first time, the stability of the non-Newtonian boundary layer flow over a flat plate. Shear-thinning and shear-thickening flows are modelled using a Carreau constitutive viscosity relationship. The boundary layer equations are solved in a self-similar fashion. A linear asymptotic stability analysis, that concerns the lower-branch structure of the neutral curve, is presented in the limit of large Reynolds number. It is shown that the lower-branch mode is destabilised and stabilised for shear-thinning and shear-thickening fluids, respectively. Favourable agreement is obtained between these asymptotic predictions and numerical results obtained from an equivalent Orr-Sommerfeld type analysis. Our results indicate that an increase in shear-thinning has the effect of significantly reducing the value of the critical Reynolds number, this suggests that the onset of instability will be significantly advanced in this case. This postulation, that shear-thinning destabilises the boundary layer flow, is further supported by our calculations regarding the development of the streamwise eigenfunctions and the relative magnitude of the temporal growth rates.
Directory of Open Access Journals (Sweden)
Jingya Sun
2014-01-01
Full Text Available Dampers are widely applied to protect devices or human body from severe impact or harmful vibration circumstances. Considering that dampers with low velocity exponent have advantages in energy absorption, they have been widely used in antiseismic structures and shock buffering. Non-Newtonian fluid with strong shear-thinning effect is commonly adopted to achieve this goal. To obtain the damping mechanism and find convenient methods to design the nonlinear fluid damper, in this study, a hydraulic damper is filled with 500,000 cSt silicone oil to achieve a low velocity exponent. Drop hammer test is carried out to experimentally obtain its impact and buffering characteristics. Then a coupling model is built to analyze its damping mechanism, which consists of a model of impact system and a computational fluid dynamics (CFD model. Results from the coupling model can be consistent with the experiment results. Simulation method can help design non-Newtonian fluid dampers more effectively.
Jin, Guang Lin; Ahn, Won-Gi; Kim, See Jo; Nam, Jaewook; Jung, Hyun Wook; Hyun, Jae Chun
2016-05-01
In this study, a strategy for designing optimal shim configuration inside a slot die is suggested to assure the uniform coating flow distribution of various non-Newtonian shear-thinning liquids at the die exit in a slot coating system. Flow patterns of non-Newtonian liquids inside the slot die, via three-dimensional computations, have been compared using various shim geometries which can adjust the flow region in a slot manifold. The rather non-uniform (parabolic) velocity distributions of shear-thinning liquids at the die exit under the basic shim condition could be effectively flattened by the modification of shim geometry without the change of die manifold structure. Dimensions of hybrid shims for controlling flow features at edge and center regions within slit channel are positively tuned, according to the shear-thinning level of coating liquids.
Institute of Scientific and Technical Information of China (English)
Mizue MUNEKATA; Hidefumi TAKAKI; Hideki OHBA; Kazuyoshi MATSUZAKI
2005-01-01
Effects of non-Newtonian viscosity for surfactant solution on the vortex characteristics and drag-reducing rate in a swirling pipe flow are investigated by pressure drop measurements, velocity profile measurements and viscosity measurements. Non-Newtonian viscosity is represented by power-law model (τ = kD n). Surfactant solution used has shear-thinning viscosity with n ＜ 1.0. The swirling flow in this study has decay of swirl and vortex-type change from Rankin's combined vortex to forced vortex. It is shown that the effect of shear-thinning viscosity on the decay of swirl intensity is different by vortex category and the critical swirl number with the vortex-type change depends on shear-thinning viscosity.
Morphological stability of an interface between two non-Newtonian fluids moving in a Hele-Shaw cell.
Martyushev, L M; Birzina, A I
2015-01-01
The problem of the morphological stability of an interface in the case of the displacement of one non-Newtonian fluid by another non-Newtonian fluid in a radial Hele-Shaw cell has been considered. Both fluids have been described by the two-parameter Ostwald-de Waele power-law model. The nonzero viscosity of the displacing fluid has been taken into account. A generalized Darcy's law for the system under consideration, as well as an equation for the determination of the critical size of morphological stability with respect to harmonic perturbations (linear analysis), has been derived. Morphological phase diagrams have been constructed, and the region of the parameters in which nonequilibrium reentrant morphological transitions are possible has been revealed.
Energy Technology Data Exchange (ETDEWEB)
Lin, Jaw-Ren; Hung, Chi-Ren; Lu, Rong-Fang [Nanya Institute of Technology, Jhongli, Taiwan (China). Dept. of Mechanical Engineering; Chu, Li-Ming [I-Shou Univ., Kaohsiung, Taiwan (China). Dept. of Mechanical and Automation Engineering
2011-08-15
According to the experimental work of C. Barus in Am. J. Sci. 45, 87 (1893), the dependency of liquid viscosity on pressure is exponential. Therefore, we extend the study of squeeze film problems of long partial journal bearings for Stokes non-Newtonian couple stress fluids by considering the pressure-dependent viscosity in the present paper. Through a small perturbation technique, we derive a first-order closed-form solution for the film pressure, the load capacity, and the response time of partial-bearing squeeze films. It is also found that the non-Newtonian couple-stress partial bearings with pressure-dependent viscosity provide better squeeze-film characteristics than those of the bearing with constant-viscosity situation. (orig.)
Lin, Jaw-Ren; Chu, Li-Ming; Hung, Chi-Ren; Lu, Rong-Fang
2011-09-01
According to the experimental work of C. Barus in Am. J. Sci. 45, 87 (1893) [1], the dependency of liquid viscosity on pressure is exponential. Therefore, we extend the study of squeeze film problems of long partial journal bearings for Stokes non-Newtonian couple stress fluids by considering the pressure-dependent viscosity in the present paper. Through a small perturbation technique, we derive a first-order closed-form solution for the film pressure, the load capacity, and the response time of partial-bearing squeeze films. It is also found that the non-Newtonian couple-stress partial bearings with pressure-dependent viscosity provide better squeeze-film characteristics than those of the bearing with constant-viscosity situation.
Sahebi, S. A. R.; Pourziaei, H.; Feizi, A. R.; Taheri, M. H.; Rostamiyan, Y.; Ganji, D. D.
2015-12-01
In this paper, natural convection of non-Newtonian bio-nanofluids flow between two vertical flat plates is investigated numerically. Sodium Alginate (SA) and Sodium Carboxymethyl Cellulose (SCMC) are considered as the base non-Newtonian fluid, and nanoparticles such as Titania ( TiO2 and Alumina ( Al2O3 were added to them. The effective thermal conductivity and viscosity of nanofluids are calculated through Maxwell-Garnetts (MG) and Brinkman models, respectively. A fourth-order Runge-Kutta numerical method (NUM) and three Weighted Residual Methods (WRMs), Collocation (CM), Galerkin (GM) and Least-Square Method (LSM) and Finite-Element Method (FEM), are used to solve the present problem. The influence of some physical parameters such as nanofluid volume friction on non-dimensional velocity and temperature profiles are discussed. The results show that SCMC- TiO2 has higher velocity and temperature values than other nanofluid structures.
Li, Jin
2011-01-01
In this paper we consider the Stochastic isothermal, nonlinear, incompressible bipolar viscous fluids driven by a genuine cylindrical fractional Bronwnian motion with Hurst parameter $H \\in (1/4,1/2)$ under Dirichlet boundary condition on 2D square domain. First we prove the existence and regularity of the stochastic convolution corresponding to the stochastic non-Newtonian fluids. Then we obtain the existence and uniqueness results for the stochastic non-Newtonian fluids. Under certain condition, the random dynamical system generated by non-Newtonian fluids has a random attractor.
Institute of Scientific and Technical Information of China (English)
TONG Dengke; WANG Ruihe
2004-01-01
In this paper, fractional order derivative, fractal dimension and spectral dimension are introduced into the seepage flow mechanics to establish the relaxation models of non-Newtonian viscoelastic fluids with the fractional derivative in fractal reservoirs. A new type integral transform is introduced, and the flow characteristics of non-Newtonian viscoelastic fluids with the fractional order derivative through a fractal reservoir are studied by using the integral transform, the discrete Laplace transform of sequential fractional derivatives and the generalized Mittag-Leffler function. Exact solutions are obtained for arbitrary fractional order derivative. The long-time and short-time asymptotic solutions for an infinite formation are also obtained. The pressure transient behavior of non-Newtonian viscoelastic fluids flow through an infinite fractal reservoir is studied by using the Stehfest's inversion method of the numerical Laplace transform. It is shown that the clearer the viscoelastic characteristics of the fluid, the more the fluid is sensitive to the order of the fractional derivative. The new type integral transform provides a new analytical tool for studying the seepage mechanics of fluid in fractal porous media.
Adam, Saad; Premnath, Kannan
2016-11-01
Fluid mechanics of non-Newtonian fluids, which arise in numerous settings, are characterized by non-linear constitutive models that pose certain unique challenges for computational methods. Here, we consider the lattice Boltzmann method (LBM), which offers some computational advantages due to its kinetic basis and its simpler stream-and-collide procedure enabling efficient simulations. However, further improvements are necessary to improve its numerical stability and accuracy for computations involving broader parameter ranges. Hence, in this study, we extend the cascaded LBM formulation by modifying its moment equilibria and relaxation parameters to handle a variety of non-Newtonian constitutive equations, including power-law and Bingham fluids, with improved stability. In addition, we include corrections to the moment equilibria to obtain an inertial frame invariant scheme without cubic-velocity defects. After preforming its validation study for various benchmark flows, we study the physics of non-Newtonian flow over pairs of circular and square cylinders in a tandem arrangement, especially the wake structure interactions and their effects on resulting forces in each cylinder, and elucidate the effect of the various characteristic parameters.
Akbarzadeh, Pooria
2016-04-01
In this paper, the unsteady pulsatile magneto-hydrodynamic blood flows through porous arteries concerning the influence of externally imposed periodic body acceleration and a periodic pressure gradient are numerically simulated. Blood is taken into account as the third-grade non-Newtonian fluid. Besides the numerical solution, for small Womersley parameter (such as blood flow through arterioles and capillaries), the analytical perturbation method is used to solve the nonlinear governing equations. Consequently, analytical expressions for the velocity profile, wall shear stress, and blood flow rate are obtained. Excellent agreement between the analytical and numerical predictions is evident. Also, the effects of body acceleration, magnetic field, third-grade non-Newtonian parameter, pressure gradient, and porosity on the flow behaviors are examined. Some important conclusions are that, when the Womersley parameter is low, viscous forces tend to dominate the flow, velocity profiles are parabolic in shape, and the center-line velocity oscillates in phase with the driving pressure gradient. In addition, by increasing the pressure gradient, the mean value of the velocity profile increases and the amplitude of the velocity remains constant. Also, when non-Newtonian effect increases, the amplitude of the velocity profile.
Lu, Gui; Wang, Xiao-Dong; Duan, Yuan-Yuan
2016-10-01
Dynamic wetting is an important interfacial phenomenon in many industrial applications. There have been many excellent reviews of dynamic wetting, especially on super-hydrophobic surfaces with physical or chemical coatings, porous layers, hybrid micro/nano structures and biomimetic structures. This review summarizes recent research on dynamic wetting from the viewpoint of the fluids rather than the solid surfaces. The reviewed fluids range from simple Newtonian fluids to non-Newtonian fluids and complex nanofluids. The fundamental physical concepts and principles involved in dynamic wetting phenomena are also reviewed. This review focus on recent investigations of dynamic wetting by non-Newtonian fluids, including the latest experimental studies with a thorough review of the best dynamic wetting models for non-Newtonian fluids, to illustrate their successes and limitations. This paper also reports on new results on the still fledgling field of nanofluid wetting kinetics. The challenges of research on nanofluid dynamic wetting is not only due to the lack of nanoscale experimental techniques to probe the complex nanoparticle random motion, but also the lack of multiscale experimental techniques or theories to describe the effects of nanoparticle motion at the nanometer scale (10(-9) m) on the dynamic wetting taking place at the macroscopic scale (10(-3) m). This paper describes the various types of nanofluid dynamic wetting behaviors. Two nanoparticle dissipation modes, the bulk dissipation mode and the local dissipation mode, are proposed to resolve the uncertainties related to the various types of dynamic wetting mechanisms reported in the literature.
The effects of non-Newtonian viscosity on the deformation of red blood cells in a shear flow
Sesay, Juldeh
2005-11-01
The analyses of the effects of non-Newtonian viscosity on the membrane of red blood cells (RBCs) suspended in a shear flow are presented. The specific objective is to investigate the mechanical deformation on the surfaces of an ellipsoidal particle model. The hydrodynamic stresses and other forces on the surface of the particle are used to determine the cell deformation. We extended previous works, which were based on the Newtonian fluid models, to the non-Newtonian case, and focus on imposed shear rate values between 1 and 100 per second. Two viscosity models are investigated, which respectively correspond to a normal person and a patient with cerebrovascular accident (CVA). The results are compared with those obtained assuming a Newtonian model. We observed that the orientation of the cell influences the deformation and the imposed shear rate drives the local shear rate distribution along the particle surface. The integral particle deformation for the non-Newtonian models in the given shear rate regime is higher than that for the Newtonian reference model. Finally, the deformation of the cell surface decreases as the dissipation ratio increases.
Physics of Life: A Model for Non-Newtonian Properties of Living Systems
Zak, Michail
2010-01-01
This innovation proposes the reconciliation of the evolution of life with the second law of thermodynamics via the introduction of the First Principle for modeling behavior of living systems. The structure of the model is quantum-inspired: it acquires the topology of the Madelung equation in which the quantum potential is replaced with the information potential. As a result, the model captures the most fundamental property of life: the progressive evolution; i.e. the ability to evolve from disorder to order without any external interference. The mathematical structure of the model can be obtained from the Newtonian equations of motion (representing the motor dynamics) coupled with the corresponding Liouville equation (representing the mental dynamics) via information forces. All these specific non-Newtonian properties equip the model with the levels of complexity that matches the complexity of life, and that makes the model applicable for description of behaviors of ecological, social, and economical systems. Rather than addressing the six aspects of life (organization, metabolism, growth, adaptation, response to stimuli, and reproduction), this work focuses only on biosignature ; i.e. the mechanical invariants of life, and in particular, the geometry and kinematics of behavior of living things. Living things obey the First Principles of Newtonian mechanics. One main objective of this model is to extend the First Principles of classical physics to include phenomenological behavior on living systems; to develop a new mathematical formalism within the framework of classical dynamics that would allow one to capture the specific properties of natural or artificial living systems such as formation of the collective mind based upon abstract images of the selves and non-selves; exploitation of this collective mind for communications and predictions of future expected characteristics of evolution; and for making decisions and implementing the corresponding corrections if
On Laminar Flow of Non-Newtonian Fluids in Porous Media
Fayed, Hassan E.
2015-10-20
Flow of generalized Newtonian fluids in porous media can be modeled as a bundle of capillary tubes or a pore-scale network. In general, both approaches rely on the solution of Hagen–Poiseuille equation using power law to estimate the variations in the fluid viscosity due to the applied shear rate. Despite the effectiveness and simplicity, power law tends to provide unrealistic values for the effective viscosity especially in the limits of zero and infinite shear rates. Here, instead of using power law, Carreau model (bubbles, drops, and particles in non-Newtonian fluids. Taylor & Francis Group, New York, 2007) is used to determine the effective viscosity as a function of the shear strain rate. Carreau model can predict accurately the variation in the viscosity at all shear rates and provide more accurate solution for the flow physics in a single pore. Using the results for a single pore, normalized Fanning friction coefficient has been calculated and plotted as a function of the newly defined Reynolds number based on pressure gradient. For laminar flow, the variation in the friction coefficient with Reynolds number has been plotted and scaled. It is observed that generalized Newtonian fluid flows show Newtonian nature up to a certain Reynolds number. At high Reynolds number, deviation from the Newtonian behavior is observed. The main contribution of this paper is to present a closed-form solution for the flow in a single pore using Carreau model, which allows for fast evaluation of the relationship between flux and pressure gradient in an arbitrary pore diameter. In this way, we believe that our development will open the perspectives for using Carreau models in pore-network simulations at low computational costs to obtain more accurate prediction for generalized Newtonian fluid flows in porous media.
Mounding of a non-Newtonian jet impinging on a solid substrate.
Energy Technology Data Exchange (ETDEWEB)
Schunk, Peter Randall; Grillet, Anne Mary; Roberts, Scott A.; Baer, Thomas A. (Procter & Gamble, Cincinnati, OH); Rao, Rekha Ranjana
2010-06-01
When a fluid jet impinges on a solid substrate, a variety of behaviors may occur around the impact region. One example is mounding, where the fluid enters the impact region faster than it can flow away, forming a mound of fluid above the main surface. For some operating conditions, this mound can destabilize and buckle, entraining air in the mound. Other behaviors include submerging flow, where the jet impinges into an otherwise steady pool of liquid, entraining a thin air layer as it enters the pool. This impact region is one of very high shear rates and as such, complex fluids behave very differently than do Newtonian fluids. In this work, we attempt to characterize this range of behavior for Newtonian and non-Newtonian fluids using dimensionless parameters. We model the fluid as a modified Bingham-Carreau-Yasuda fluid, which exhibits the full range of pseudoplastic flow properties throughout the impact region. Additionally, we study viscoelastic effects through the use of the Giesekus model. Both 2-D and 3-D numerical simulations are performed using a variety of finite element method techniques for tracking the jet interface, including Arbitrary Lagrangian Eulerian (ALE), diffuse level sets, and a conformal decomposition finite element method (CDFEM). The presence of shear-thinning characteristics drastically reduces unstable mounding behavior, yet can lead to air entrainment through the submerging flow regime. We construct an operating map to understand for what flow parameters mounding and submerging flows will occur, and how the fluid rheology affects these behaviors. This study has many implications in high-speed industrial bottle filling applications.
Simultaneous pulsatile flow and oscillating wall of a non-Newtonian liquid
Herrera-Valencia, E. E.; Sánchez-Villavicencio, M. L.; Calderas, F.; Pérez-Camacho, M.; Medina-Torres, L.
2016-11-01
In this work, analytical predictions of the rectilinear flow of a non-Newtonian liquid are given. The fluid is subjected to a combined flow: A pulsatile time-dependent pressure gradient and a random longitudinal vibration at the wall acting simultaneously. The fluctuating component of the combined pressure gradient and oscillating flow is assumed to be of small amplitude and can be adequately represented by a weakly stochastic process, for which a quasi-static perturbation solution scheme is suggested, in terms of a small parameter. This flow is analyzed with the Tanner constitutive equation model with the viscosity function represented by the Ellis model. According to the coupled Tanner-Ellis model, the flow enhancement can be separated in two contributions (pulsatile and oscillating mechanisms) and the power requirement is always positive and can be interpreted as the sum of a pulsatile, oscillating, and the coupled systems respectively. Both expressions depend on the amplitude of the oscillations, the perturbation parameter, the exponent of the Ellis model (associated to the shear thinning or thickening mechanisms), and the Reynolds and Deborah numbers. At small wall stress values, the flow enhancement is dominated by the axial wall oscillations whereas at high wall stress values, the system is governed by the pulsating noise perturbation. The flow transition is obtained for a critical shear stress which is a function of the Reynolds number, dimensionless frequency and the ratio of the two amplitudes associated with the pulsating and oscillating perturbations. In addition, the flow enhancement is compared with analytical and numerical predictions of the Reiner-Phillipoff and Carreau models. Finally, the flow enhancement and power requirement are predicted using biological rheometric data of blood with low cholesterol content.
The stretching of an electrified non-Newtonian jet: A model for electrospinning
Feng, J. J.
2002-11-01
Electrospinning uses an external electrostatic field to accelerate and stretch a charged polymer jet, and may produce ultrafine "nanofibers." Many polymers have been successfully electrospun in the laboratory. Recently Hohman [et al.] [Phys. Fluids, 13, 2201 (2001)] proposed an electrohydrodynamic model for electrospinning Newtonian jets. A problem arises, however, with the boundary condition at the nozzle. Unless the initial surface charge density is zero or very small, the jet bulges out upon exiting the nozzle in a "ballooning instability," which never occurs in reality. In this paper, we will first describe a slightly different Newtonian model that avoids the instability. Well-behaved solutions are produced that are insensitive to the initial charge density, except inside a tiny "boundary layer" at the nozzle. Then a non-Newtonian viscosity function is introduced into the model and the effects of extension thinning and thickening are explored. Results show two distinct regimes of stretching. For a "mildly stretched" jet, the axial tensile force in the fiber resists stretching, so that extension thinning promotes stretching and thickening hinders stretching. For a "severely stretched" jet, on the other hand, the tensile force enhances stretching at the beginning of the jet and suppresses it farther downstream. The effects of extensional viscosity then depend on the competition between the upstream and downstream dynamics. Finally, we use an empirical correlation to simulate strain hardening typical of polymeric liquids. This generally steepens the axial gradient of the tensile stress. Stretching is more pronounced at the beginning but weakens later, and ultimately thicker fibers are produced because of strain hardening.
Ali, N; Asghar, Z; Anwar Bég, O; Sajid, M
2016-05-21
Gliding bacteria are an assorted group of rod-shaped prokaryotes that adhere to and glide on certain layers of ooze slime attached to a substratum. Due to the absence of organelles of motility, such as flagella, the gliding motion is caused by the waves moving down the outer surface of these rod-shaped cells. In the present study we employ an undulating surface model to investigate the motility of bacteria on a layer of non-Newtonian slime. The rheological behavior of the slime is characterized by an appropriate constitutive equation, namely the Carreau model. Employing the balances of mass and momentum conservation, the hydrodynamic undulating surface model is transformed into a fourth-order nonlinear differential equation in terms of a stream function under the long wavelength assumption. A perturbation approach is adopted to obtain closed form expressions for stream function, pressure rise per wavelength, forces generated by the organism and power required for propulsion. A numerical technique based on an implicit finite difference scheme is also employed to investigate various features of the model for large values of the rheological parameters of the slime. Verification of the numerical solutions is achieved with a variational finite element method (FEM). The computations demonstrate that the speed of the glider decreases as the rheology of the slime changes from shear-thinning (pseudo-plastic) to shear-thickening (dilatant). Moreover, the viscoelastic nature of the slime tends to increase the swimming speed for the shear-thinning case. The fluid flow in the pumping (generated where the organism is not free to move but instead generates a net fluid flow beneath it) is also investigated in detail. The study is relevant to marine anti-bacterial fouling and medical hygiene biophysics.
The numerical analysis of non-Newtonian blood flow in human patient-specific left ventricle.
Doost, Siamak N; Zhong, Liang; Su, Boyang; Morsi, Yosry S
2016-04-01
Recently, various non-invasive tools such as the magnetic resonance image (MRI), ultrasound imaging (USI), computed tomography (CT), and the computational fluid dynamics (CFD) have been widely utilized to enhance our current understanding of the physiological parameters that affect the initiation and the progression of the cardiovascular diseases (CVDs) associated with heart failure (HF). In particular, the hemodynamics of left ventricle (LV) has attracted the attention of the researchers due to its significant role in the heart functionality. In this study, CFD owing its capability of predicting detailed flow field was adopted to model the blood flow in images-based patient-specific LV over cardiac cycle. In most published studies, the blood is modeled as Newtonian that is not entirely accurate as the blood viscosity varies with the shear rate in non-linear manner. In this paper, we studied the effect of Newtonian assumption on the degree of accuracy of intraventricular hemodynamics. In doing so, various non-Newtonian models and Newtonian model are used in the analysis of the intraventricular flow and the viscosity of the blood. Initially, we used the cardiac MRI images to reconstruct the time-resolved geometry of the patient-specific LV. After the unstructured mesh generation, the simulations were conducted in the CFD commercial solver FLUENT to analyze the intraventricular hemodynamic parameters. The findings indicate that the Newtonian assumption cannot adequately simulate the flow dynamic within the LV over the cardiac cycle, which can be attributed to the pulsatile and recirculation nature of the flow and the low blood shear rate.
Characterising the rheology of non-Newtonian fluids using PFG-NMR and cumulant analysis.
Blythe, T W; Sederman, A J; Mitchell, J; Stitt, E H; York, A P E; Gladden, L F
2015-06-01
Conventional rheological characterisation using nuclear magnetic resonance (NMR) typically utilises spatially-resolved measurements of velocity. We propose a new approach to rheometry using pulsed field gradient (PFG) NMR which readily extends the application of MR rheometry to single-axis gradient hardware. The quantitative use of flow propagators in this application is challenging because of the introduction of artefacts during Fourier transform, which arise when realistic sampling strategies are limited by experimental and hardware constraints and when particular spatial and temporal resolution are required. The method outlined in this paper involves the cumulant analysis of the acquisition data directly, thereby preventing the introduction of artefacts and reducing data acquisition times. A model-dependent approach is developed to enable the pipe-flow characterisation of fluids demonstrating non-Newtonian power-law rheology, involving the use of an analytical expression describing the flow propagator in terms of the flow behaviour index. The sensitivity of this approach was investigated and found to be robust to the signal-to-noise ratio (SNR) and number of acquired data points, enabling an increase in temporal resolution defined by the SNR. Validation of the simulated results was provided by an experimental case study on shear-thinning aqueous xanthan gum solutions, whose rheology could be accurately characterised using a power-law model across the experimental shear rate range of 1-100 s(-1). The flow behaviour indices calculated using this approach were observed to be within 8% of those obtained using spatially-resolved velocity imaging and within 5% of conventional rheometry. Furthermore, it was shown that the number of points sampled could be reduced by a factor of 32, when compared to the acquisition of a volume-averaged flow propagator with 128 gradient increments, without negatively influencing the accuracy of the characterisation, reducing the
Energy Technology Data Exchange (ETDEWEB)
Yokuda, Satoru T.; Poloski, Adam P.; Adkins, Harold E.; Casella, Andrew M.; Hohimer, Ryan E.; Karri, Naveen K.; Luna, Maria; Minette, Michael J.; Tingey, Joel M.
2009-05-11
The External Flowsheet Review Team (EFRT) has identified the issues relating to the Waste Treatment and Immobilization Plant (WTP) pipe plugging. Per the review’s executive summary, “Piping that transports slurries will plug unless it is properly designed to minimize this risk. This design approach has not been followed consistently, which will lead to frequent shutdowns due to line plugging.” To evaluate the potential for plugging, testing was performed to determine critical velocities for the complex WTP piping layout. Critical velocity is defined as the point at which a moving bed of particles begins to form on the pipe bottom during slurry-transport operations. Pressure drops across the fittings of the test pipeline were measured with differential pressure transducers, from which the critical velocities were determined. A WTP prototype flush system was installed and tested upon the completion of the pressure-drop measurements. We also provide the data for the overflow relief system represented by a WTP complex piping geometry with a non-Newtonian slurry. A waste simulant composed of alumina (nominally 50 μm in diameter) suspended in a kaolin clay slurry was used for this testing. The target composition of the simulant was 10 vol% alumina in a suspending medium with a yield stress of 3 Pa. No publications or reports are available to confirm the critical velocities for the complex geometry evaluated in this testing; therefore, for this assessment, the results were compared to those reported by Poloski et al. (2008) for which testing was performed for a straight horizontal pipe. The results of the flush test are compared to the WTP design guide 24590-WTP-GPG-M-0058, Rev. 0 (Hall 2006) in an effort to confirm flushing-velocity requirements.
Microporous silica gels from alkylsilicate-water two phase hydrolysis
Energy Technology Data Exchange (ETDEWEB)
Chu, L.; Tejedor-Tejedor, M.I.; Anderson, M.A. [Univ. of Wisconsin, Madison, WI (United States). Water Chemistry Program
1994-12-31
Microporous silica gels have been synthesized through a nano-particulate sol-gel route. These gels have uniformly distributed and extremely small pores(< 15 {angstrom} in diameter). Hydrolysis and condensation reactions leading to these gels were carried out in an alkyl silicate-water (ammonia) two phase system. These reactions took place at the alkyl silicate droplet-water interfacial boundary. No alcohol was added. A clear, stable and uniformly distributed colloidal silica suspension having an average particle size less than 6 nm was prepared by this method. Fast hydrolysis, slow condensation and low solubility all contribute to a high supersaturation level and result in the formation of small particles. This process is consistent with classic nucleation theory. When the particles are produced under acidic rather than under basic reaction conditions, smaller particles are formed due to the slower condensation rate and lower solubility of these silica particles in acidic conditions. At the same pH, alkylsilicates having smaller alkyl groups react faster with water leading to smaller primary particles. Homogeneous nucleation conditions are achieved when the water/alkylsilicate ratio is high.
Widmer Soyka, René P; López, Alejandro; Persson, Cecilia; Cristofolini, Luca; Ferguson, Stephen J
2013-11-01
Fluids present or used in biology, medicine and (biomedical) engineering are often significantly non-Newtonian. Furthermore, they are chemically complex and can interact with the porous matrix through which they flow. The porous structures themselves display complex morphological inhomogeneities on a wide range of length scales. In vertebroplasty, a shear-thinning fluid, e.g. poly(methyl methacrylate) (PMMA), is injected into the cavities of vertebral trabecular bone for the stabilization of fractures and metastatic lesions. The main objective of this study was therefore to provide a protocol for numerically investigating the rheological properties of PMMA-based bone cements to predict its spreading behavior while flowing through vertebral trabecular bone. A numerical upscaling scheme based on a dimensionless formulation of the Navier-Stokes equation is proposed in order to relate the pore-scale rheological properties of the PMMA that were experimentally estimated using a plate rheometer, to the continuum-scale. On the pore length scale, a viscosity change on the order of one magnitude was observed whilst the shear-thinning properties caused a viscosity change on the order of only 10% on the continuum length scale and in a flow regime that is relevant for vertebroplasty. An experimental validation, performed on human cadaveric vertebrae (n=9), showed a significant improvement of the cement spreading prediction accuracy with a non-Newtonian formulation. A root mean square cement surface prediction error of 1.53mm (assuming a Newtonian fluid) and 1.37mm (assuming a shear-thinning fluid) was found. Our findings highlight the importance of incorporating the non-Newtonian fluids properties in computational models of porous media at the appropriate length scale.
Electro-osmosis of non-Newtonian fluids in porous media using lattice Poisson-Boltzmann method.
Chen, Simeng; He, Xinting; Bertola, Volfango; Wang, Moran
2014-12-15
Electro-osmosis in porous media has many important applications in various areas such as oil and gas exploitation and biomedical detection. Very often, fluids relevant to these applications are non-Newtonian because of the shear-rate dependent viscosity. The purpose of this study was to investigate the behaviors and physical mechanism of electro-osmosis of non-Newtonian fluids in porous media. Model porous microstructures (granular, fibrous, and network) were created by a random generation-growth method. The nonlinear governing equations of electro-kinetic transport for a power-law fluid were solved by the lattice Poisson-Boltzmann method (LPBM). The model results indicate that: (i) the electro-osmosis of non-Newtonian fluids exhibits distinct nonlinear behaviors compared to that of Newtonian fluids; (ii) when the bulk ion concentration or zeta potential is high enough, shear-thinning fluids exhibit higher electro-osmotic permeability, while shear-thickening fluids lead to the higher electro-osmotic permeability for very low bulk ion concentration or zeta potential; (iii) the effect of the porous medium structure depends significantly on the constitutive parameters: for fluids with large constitutive coefficients strongly dependent on the power-law index, the network structure shows the highest electro-osmotic permeability while the granular structure exhibits the lowest permeability on the entire range of power law indices considered; when the dependence of the constitutive coefficient on the power law index is weaker, different behaviors can be observed especially in case of strong shear thinning.
García Pinar, Alberto; Solano Fernández, Juan Pedro; Viedma Robles, Antonio; Martínez Hernández, David Sebastián
2010-01-01
This work presents an experimental study on the heat transfer enhancement by means of a tube with wire-coil insert,for non-Newtonian laminar and transitional flow. The dimensionless pitch and wire diameter (based on the plain tube inner diameter) were chosen as p/D= 1 and e/D=0.09. Two pseudoplastic test fluids have been used: 1% by weight aqueous solutions of carboxymethyl cellulose (CMC) with high viscosity and medium viscosity. A wide range of flow conditions has been covered: Reynolds ...
Wen, Jianping; Jia, Xiaoqiang; Cheng, Xianrui; Yang, Peng
2005-05-01
Hydrodynamic and gas-liquid mass transfer characteristics, such as liquid velocity, gas holdup, solid holdup and gas-liquid volumetric mass transfer coefficient, in the riser and downcomer of the gas-liquid-solid three-phase internal loop airlift bioreactors with complete gas recirculation for non-Newtonian fluids, were investigated. A mathematical model for the description of flow behavior and gas-liquid mass transfer of these bioreactors was developed. The predicted results of this model agreed well with the experimental data.
Hayat, Tasawar; Awais, Muhammad; Imtiaz, Amna
2016-01-01
This communication deals with the properties of heat source/sink in a magneto-hydrodynamic flow of a non-Newtonian fluid immersed in a porous medium. Shrinking phenomenon along with the permeability of the wall is considered. Mathematical modelling is performed to convert the considered physical process into set of coupled nonlinear mathematical equations. Suitable transformations are invoked to convert the set of partial differential equations into nonlinear ordinary differential equations which are tackled numerically for the solution computations. It is noted that dual solutions for various physical parameters exist which are analyzed in detail.
Digilov, Rafael M
2008-12-02
The impact of non-Newtonian behavior and the dynamic contact angle on the rise dynamics of a power law liquid in a vertical capillary is studied theoretically and experimentally for quasi-steady-state flow. An analytical solution for the time evolution of the meniscus height is obtained in terms of a Gaussian hypergeometric function, which in the case of a Newtonian liquid reduces to the Lucas-Washburn equation modified by the dynamic contact angle correction. The validity of the solution is checked against experimental data on the rise dynamics of a shear-thinning cmc solution in a glass microcapillary, and excellent agreement is found.
Institute of Scientific and Technical Information of China (English)
无
2011-01-01
This paper studies mixed convection,double dispersion and chemical reaction effects on heat and mass transfer in a non-Darcy non-Newtonian fluid over a vertical surface in a porous medium under the constant temperature and concentration.The governing boundary layer equations,namely,momentum,energy and concentration,are converted to ordinary differential equations by introducing similarity variables and then are solved numerically by means of fourth-order Runge-Kutta method coupled with double-shooting techn...
SOLUTION OF THE RAYLEIGH PROBLEM FOR A POWER-LAW NON-NEWTONIAN CONDUCTING FLUID VIA GROUP METHOD
Institute of Scientific and Technical Information of China (English)
Mina B.Abd-el-Malek; Nagwa A.Badran; Hossam S.Hassan
2002-01-01
An investigation is made of the magnetic Rayleigh problem where a semi-infinite plate is given an impulsive motion and thereafter moves with constant velocity in a nonNewtonian power law fluid of infinite extent. The solution of this highly non-linear problem is obtained by means of the transformation group theoretic approach. The one-parameter group transformation reduces the number of independent variables by one and the governing partial differential equation with the boundary conditions reduce to an ordinary differential equation with the appropriate boundary conditions. Effect of the some parameters on the velocity u ( y, t) has been studied and the results are plotted.
MHD flow and heat transfer from continuous surface in uniform free stream of non-Newtonian fluid
Institute of Scientific and Technical Information of China (English)
无
2007-01-01
An analysis is carried out to study the steady flow and heat transfer characteristics from a continuous flat surface moving in a parallel free stream of an electrically conducting non-Newtonian viscoelastic fluid. The flow is subjected to a transverse uniform magnetic field. The constitutive equation of the fluid is modeled by that for a second grade fluid. Numerical results are obtained for the distribution of velocity and temperature profiles. The effects of various physical parameters like viscoelastic parameter, magnetic parameter and Prandtl number on various momentum and heat transfer characteristics are discussed in detail and shown graphically.
Data on the mixing of non-Newtonian fluids by a Rushton turbine in a cylindrical tank.
Khapre, Akhilesh; Munshi, Basudeb
2016-09-01
The paper focuses on the data collected from the mixing of shear thinning non-Newtonian fluids in a cylindrical tank by a Rushton turbine. The data presented are obtained by using Computational Fluid Dynamics (CFD) simulation of fluid flow field in the entire tank volume. The CFD validation data for this study is reported in the research article 'Numerical investigation of hydrodynamic behavior of shear thinning fluids in stirred tank' (Khapre and Munshi, 2015) [1]. The tracer injection method is used for the prediction of mixing time and mixing efficiency of a Rushton turbine impeller.
Data on the mixing of non-Newtonian fluids by a Rushton turbine in a cylindrical tank
Directory of Open Access Journals (Sweden)
Akhilesh Khapre
2016-09-01
Full Text Available The paper focuses on the data collected from the mixing of shear thinning non-Newtonian fluids in a cylindrical tank by a Rushton turbine. The data presented are obtained by using Computational Fluid Dynamics (CFD simulation of fluid flow field in the entire tank volume. The CFD validation data for this study is reported in the research article ‘Numerical investigation of hydrodynamic behavior of shear thinning fluids in stirred tank’ (Khapre and Munshi, 2015 [1]. The tracer injection method is used for the prediction of mixing time and mixing efficiency of a Rushton turbine impeller.
Deposition Velocities of Newtonian and Non-Newtonian Slurries in Pipelines
Energy Technology Data Exchange (ETDEWEB)
Poloski, Adam P. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Adkins, Harold E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Abrefah, John [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Casella, Andrew M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hohimer, Ryan E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Nigl, Franz [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Minette, Michael J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Toth, James J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Tingey, Joel M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Yokuda, Satoru T. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
2009-03-01
correlation used in the WTP design guide has been shown to be inaccurate for Hanford waste feed materials. The use of the Thomas (1979) correlation in the design guide is not conservative—In cases where 100% of the particles are smaller than 74 μm or particles are considered to be homogeneous due to yield stress forces suspending the particles the homogeneous fraction of the slurry can be set to 100%. In such cases, the predicted critical velocity based on the conservative Oroskar and Turian (1980) correlation is reduced to zero and the design guide returns a value from the Thomas (1979) correlation. The measured data in this report show that the Thomas (1979) correlation predictions often fall below that measured experimental values. A non-Newtonian deposition velocity design guide should be developed for the WTP— Since the WTP design guide is limited to Newtonian fluids and the WTP expects to process large quantities of such materials, the existing design guide should be modified address such systems. A central experimental finding of this testing is that the flow velocity required to reach turbulent flow increases with slurry rheological properties due to viscous forces dampening the formation of turbulent eddies. The flow becomes dominated by viscous forces rather than turbulent eddies. Since the turbulent eddies necessary for particle transport are not present, the particles will settle when crossing this boundary called the transitional deposition boundary. This deposition mechanism should be expected and designed for in the WTP.
Energy Technology Data Exchange (ETDEWEB)
Broniarz-Press, Lubomira; Rozanska, Sylwia [Department of Chemical Engineering and Equipment, Faculty of Chemical Technology, Poznan University of Technology, pl. M. Sklodowskiej-Curie 2, PL 60-965 Poznan (Poland)
2008-02-15
In the study the results of the friction factor in boundary layer and the distribution of heat transfer coefficient in non-Newtonian liquid agitated by different impellers, have been presented. It has been established that for studies in Na-CMC and guar gum aqueous solutions by the electrochemical method the following solution of 0.005 (kmol m{sup -3}) K{sub 3}[Fe(CN){sub 6}], 0.005 (kmol m{sup -3}) K{sub 4}[Fe(CN){sub 6}] and 0.3 (kmol m{sup -3}) K{sub 2}SO{sub 4} can be recommended. The common relationship (for a given type of an impeller) between local values of friction coefficient and heat transfer coefficient and Reynolds number proposed by Metzner and Otto [A.B. Metzner, R.E. Otto, Agitation of non-Newtonian fluids, AIChe J. 3 (1957) 3-10] for all power-law fluids, have been obtained. (author)
Lin, Weikang; Chen, Lie-Wen; Wen, De-Hua; Xu, Jun
2013-01-01
A thorough understanding of many astrophysical phenomena and objects requires reliable knowledge about both the equation of state (EOS) of super-dense nuclear matter and the theory of ultra-strong gravity simultaneously because of the EOS-gravity degeneracy. Currently, deviations of the neutron star (NS) mass-radius correlation predicted by various gravity theories are larger than its uncertainties due to the poorly known NS matter content and its EOS. At least two independent observables are required to break the EOS-gravity degeneracy. Using model EOSs for hybrid stars and a Yukawa-type non-Newtonian gravity, we investigate both the mass-radius correlation and pulsating frequencies of NSs. While the maximum mass of NSs increases with increasing strength of the Yukawa-type non-Newtonian gravity, the frequencies of the $f$, $p_1$, $p_2$, and $w_I$ pulsating modes are found to decrease with it, providing a useful reference for future determination simultaneously of both the gravitational theory and the supranu...
Bandopadhyay, Aditya; Chakraborty, Suman
2015-03-21
By considering an ion moving inside an imaginary sphere filled with a power-law fluid, we bring out the implications of the fluid rheology and the influence of the proximity of the other ions towards evaluating the conduction current in an ionic solution. We show that the variation of the conductivity as a function of the ionic concentration is both qualitatively and quantitatively similar to that predicted by the Kohlrausch law. We then utilize this consideration for estimating streaming potentials developed across narrow fluidic confinements as a consequence of the transport of ions in a convective medium constituting a power-law fluid. These estimates turn out to be in sharp contrast to the classical estimates of streaming potential for non-Newtonian fluids, in which the effect of rheology of the solvent is merely considered to affect the advection current, disregarding its contributions to the conduction current. Our results have potential implications of devising a new paradigm of consistent estimation of streaming potentials for non-Newtonian fluids, with combined considerations of the confinement effect and fluid rheology in the theoretical calculations.
Institute of Scientific and Technical Information of China (English)
朱春英; 付涛涛; 高习群; 马友光
2011-01-01
On the basis of Navier-Stockes equation and convection-diffusion equation, combined with surface tension and penetration models, the equations of moment and mass transfer between bubble and the ambient non-Newtonian liquid were established. The formation of a single bubble from a submersed nozzle of 1.0 mm diameter and the mass transfer from an artificially fixed bubble into the ambient liquid were simulated by the volume-of-fluid （VOF） method. Good agreement between simulation results and experimental data confirmed the validity of the numerical method. Furthermore, the concentration distribution around rising bubbles in shear thinning non-Newtonian fluid was simulated. When the process of a single ellipsoidal bubble with the bubble deformation rate below 2.0 rises, the concentration distribution is a single-tail in the bubble＇s wake, but it is fractal when thebubble deformation rate is greater than 2.0. For the overtaking of two in-line rising bubbles, the concentration distribution area between two bubbles broadens gradually and then coalescence occurs. The bifurcation of concentration distribution appears in the rear of the resultant bubble.
Secondary flow in a curved artery model with Newtonian and non-Newtonian blood-analog fluids
Najjari, Mohammad Reza; Plesniak, Michael W.
2016-11-01
Steady and pulsatile flows of Newtonian and non-Newtonian fluids through a 180°-curved pipe were investigated using particle image velocimetry (PIV). The experiment was inspired by physiological pulsatile flow through large curved arteries, with a carotid artery flow rate imposed. Sodium iodide (NaI) and sodium thiocyanate (NaSCN) were added to the working fluids to match the refractive index (RI) of the test section to eliminate optical distortion. Rheological measurements revealed that adding NaI or NaSCN changes the viscoelastic properties of non-Newtonian solutions and reduces their shear-thinning property. Measured centerline velocity profiles in the upstream straight pipe agreed well with an analytical solution. In the pulsatile case, secondary flow structures, i.e. deformed-Dean, Dean, Wall and Lyne vortices, were observed in various cross sections along the curved pipe. Vortical structures at each cross section were detected using the d2 vortex identification method. Circulation analysis was performed on each vortex separately during the systolic deceleration phase, and showed that vortices split and rejoin. Secondary flow structures in steady flows were found to be morphologically similar to those in pulsatile flows for sufficiently high Dean number. supported by the George Washington University Center for Biomimetics and Bioinspired Engineering.
Nam, Jeonghun; Lim, Hyunjung; Kim, Dookon; Jung, Hyunwook; Shin, Sehyun
2012-04-07
Pure separation and sorting of microparticles from complex fluids are essential for biochemical analyses and clinical diagnostics. However, conventional techniques require highly complex and expensive labeling processes for high purity separation. In this study, we present a simple and label-free method for separating microparticles with high purity using the elasto-inertial characteristic of a non-Newtonian fluid in microchannel flow. At the inlet, particle-containing sample flow was pushed toward the side walls by introducing sheath fluid from the center inlet. Particles of 1 μm and 5 μm in diameter, which were suspended in viscoelastic fluid, were successfully separated in the outlet channels: larger particles were notably focused on the centerline of the channel at the outlet, while smaller particles continued flowing along the side walls with minimal lateral migration towards the centerline. The same technique was further applied to separate platelets from diluted whole blood. Through cytometric analysis, we obtained a purity of collected platelets of close to 99.9%. Conclusively, our microparticle separation technique using elasto-inertial forces in non-Newtonian fluid is an effective method for separating and collecting microparticles on the basis of size differences with high purity.
Directory of Open Access Journals (Sweden)
A Mahdy
2016-01-01
Full Text Available In this contribution a numerical study is carried out to analyze the effect of slip at the boundary of unsteady two-dimensional MHD flow of a non-Newtonian fluid over a stretching surface having a prescribed surface temperature in the presence of suction or blowing at the surface. Casson fluid model is used to characterize the non-Newtonian fluid behavior. With the help of similarity transformations, the governing partial differential equations corresponding to the momentum and heat transfer are reduced to a set of non-linear ordinary differential equations, which are then solved for local similar solutions using the very robust computer algebra software MATLAB. The flow features and heat transfer characteristics for different values of the governing parameters are graphically presented and discussed in detail. Comparison with available results for certain cases is excellent. The effect of increasing values of the Casson parameter is seen to suppress the velocity field. But the temperature is enhanced with increasing Casson parameter. For increasing slip parameter, velocity increases and thermal boundary layer becomes thinner in the case of suction or blowing.
Rabbi, Khan Md.; Rakib, Tawfiqur; Das, Sourav; Mojumder, Satyajit; Saha, Sourav
2016-07-01
This paper demonstrates magneto-hydrodynamic (MHD) mixed convection flow through a channel with a rectangular obstacle at the entrance region using non-Newtonian power law fluid. The obstacle is kept at uniformly high temperature whereas the inlet and top wall of the channel are maintained at a temperature lower than obstacle temperature. Poiseuille flow is implemented as the inlet velocity boundary condition. Grid independency test and code validation are performed to justify the computational accuracy before solving the present problem. Galerkin weighted residual method has been appointed to solve the continuity, momentum and energy equations. The problem has been solved for wide range of pertinent parameters like Richardson number (Ri = 0.1 - 10) at a constant Reynolds number (Re = 100), Hartmann number (Ha = 0 - 100), power index (n = 0.6 - 1.6). The flow and thermal field have been thoroughly discussed through streamline and isothermal lines respectively. The heat transfer performance of the given study has been illustrated by average Nusselt number plots. It is observed that increment of Hartmann number (Ha) tends to decrease the heat transfer rate up to a critical value (Ha = 20) and then let increase the heat transfer performance. Thus maximum heat transfer rate has been recorded for higher Hartmann number and Rayleigh number in case of pseudo-plastic (n = 0.6) non-Newtonian fluid flow.
Gas storage in "dry water" and "dry gel" clathrates.
Carter, Benjamin O; Wang, Weixing; Adams, Dave J; Cooper, Andrew I
2010-03-02
"Dry water" (DW) is a free-flowing powder prepared by mixing water, hydrophobic silica particles, and air at high speeds. We demonstrated recently that DW can be used to dramatically enhance methane uptake rates in methane gas hydrate (MGH). Here, we expand on our initial work, demonstrating that DW can be used to increase the kinetics of formation of gas clathrates for gases other than methane, such as CO(2) and Kr. We also show that the stability of the system toward coalescence can be increased via the inclusion of a gelling agent to form a "dry gel", thus dramatically improving the recyclability of the material. For example, the addition of gellan gum allows effective reuse over at least eight clathration cycles without the need for reblending. DW and its "dry gel" modification may represent a potential platform for recyclable gas storage or gas separation on a practicable time scale in a static, unmixed system.
Directory of Open Access Journals (Sweden)
Mehrvar M.
2013-05-01
Full Text Available The identification of non-ideal flows in a continuous-flow mixing of non-Newtonian fluids is a challenging task for various chemical industries: plastic manufacturing, water and wastewater treatment, and pulp and paper manufacturing. Non-ideal flows such as channelling, recirculation, and dead zones significantly affect the performance of continuous-flow mixing systems. Therefore, the main objective of this paper was to develop an identification protocol to measure non-ideal flows in the continuous-flow mixing system. The extent of non-ideal flows was quantified using a dynamic model that incorporated channelling, recirculation, and dead volume in the mixing vessel. To estimate the dynamic model parameters, the system was excited using a frequency-modulated random binary input by injecting the saline solution (as a tracer into the fresh feed stream prior to being pumped into the mixing vessel. The injection of the tracer was controlled by a computer-controlled on-off solenoid valve. Using the trace technique, the extent of channelling and the effective mixed volume were successfully determined and used as mixing quality criteria. Such identification procedures can be applied at various areas of chemical engineering in order to improve the mixing quality.
Patel, D.; Ein-Mozaffari, F.; Mehrvar, M.
2013-05-01
The identification of non-ideal flows in a continuous-flow mixing of non-Newtonian fluids is a challenging task for various chemical industries: plastic manufacturing, water and wastewater treatment, and pulp and paper manufacturing. Non-ideal flows such as channelling, recirculation, and dead zones significantly affect the performance of continuous-flow mixing systems. Therefore, the main objective of this paper was to develop an identification protocol to measure non-ideal flows in the continuous-flow mixing system. The extent of non-ideal flows was quantified using a dynamic model that incorporated channelling, recirculation, and dead volume in the mixing vessel. To estimate the dynamic model parameters, the system was excited using a frequency-modulated random binary input by injecting the saline solution (as a tracer) into the fresh feed stream prior to being pumped into the mixing vessel. The injection of the tracer was controlled by a computer-controlled on-off solenoid valve. Using the trace technique, the extent of channelling and the effective mixed volume were successfully determined and used as mixing quality criteria. Such identification procedures can be applied at various areas of chemical engineering in order to improve the mixing quality.
Sultanov, Renat A; Engelbrekt, Brent; Blankenbecler, Richard
2008-01-01
Methods of Computational Fluid Dynamics are applied to simulate pulsatile blood flow in human vessels and in the aortic arch. The non-Newtonian behaviour of the human blood is investigated in simple vessels of actual size. A detailed time-dependent mathematical convergence test has been carried out. The realistic pulsatile flow is used in all simulations. Results of computer simulations of the blood flow in vessels of two different geometries are presented. For pressure, strain rate and velocity component distributions we found significant disagreements between our results obtained with realistic non-Newtonian treatment of human blood and widely used method in literature: a simple Newtonian approximation. A significant increase of the strain rate and, as a result, wall sear stress distribution, is found in the region of the aortic arch. We consider this result as theoretical evidence that supports existing clinical observations and those models not using non-Newtonian treatment underestimate the risk of disru...
Directory of Open Access Journals (Sweden)
Jun Xie
2016-01-01
Full Text Available A weakly compressible moving particle semi-implicit (WC-MPS method is utilized to simulate non-Newtonian free surface flows due to the advantages of particle methods with respect to handling large deformation and fragmentation. The Cross rheology equation was selected in order to capture the viscous features of the mixture flows. To numerically implement the Cross equation, an experiment-based method was proposed to determine the four rheology parameters in the equation. The method of using a WC-MPS model to study non-Newtonian dam break flow problems was then adopted. The capabilities of the proposed method were tested by simulating different materials with the proposed method in modeling non-Newtonian free surface flows. Significant viscous features were reproduced by the proposed model.
Khali, S; Nebbali, R; Ameziani, D E; Bouhadef, K
2013-05-01
In this work the instability of the Taylor-Couette flow for Newtonian and non-Newtonian fluids (dilatant and pseudoplastic fluids) is investigated for cases of finite aspect ratios. The study is conducted numerically using the lattice Boltzmann method (LBM). In many industrial applications, the apparatuses and installations drift away from the idealized case of an annulus of infinite length, and thus the end caps effect can no longer be ignored. The inner cylinder is rotating while the outer one and the end walls are maintained at rest. The lattice two-dimensional nine-velocity (D2Q9) Boltzmann model developed from the Bhatnagar-Gross-Krook approximation is used to obtain the flow field for fluids obeying the power-law model. The combined effects of the Reynolds number, the radius ratio, and the power-law index n on the flow characteristics are analyzed for an annular space of finite aspect ratio. Two flow modes are obtained: a primary Couette flow (CF) mode and a secondary Taylor vortex flow (TVF) mode. The flow structures so obtained are different from one mode to another. The critical Reynolds number Re(c) for the passage from the primary to the secondary mode exhibits the lowest value for the pseudoplastic fluids and the highest value for the dilatant fluids. The findings are useful for studies of the swirling flow of non-Newtonians fluids in axisymmetric geometries using LBM. The flow changes from the CF to TVF and its structure switches from the two-cells to four-cells regime for both Newtonian and dilatant fluids. Contrariwise for pseudoplastic fluids, the flow exhibits 2-4-2 structure passing from two-cells to four cells and switches again to the two-cells configuration. Furthermore, the critical Reynolds number presents a monotonic increase with the power-law index n of the non-Newtonian fluid, and as the radius ratio grows, the transition flow regimes tend to appear for higher critical Reynolds numbers.
Directory of Open Access Journals (Sweden)
Nabil T. M. Eldabe
2014-01-01
Full Text Available This paper is devoted to the study of the peristaltic motion of non-Newtonian fluid with heat and mass transfer through a porous medium in the channel under the effect of magnetic field. A modified Casson non-Newtonian constitutive model is employed for the transport fluid. A perturbation series’ method of solution of the stream function is discussed. The effects of various parameters of interest such as the magnetic parameter, Casson parameter, and permeability parameter on the velocity, pressure rise, temperature, and concentration are discussed and illustrated graphically through a set of figures.
Directory of Open Access Journals (Sweden)
A. Zaman
2015-03-01
Full Text Available A two-dimensional model is used to analyze the unsteady pulsatile flow of blood through a tapered artery with stenosis. The rheology of the flowing blood is captured by the constitutive equation of Carreau model. The geometry of the time-variant stenosis has been used to carry out the present analysis. The flow equations are set up under the assumption that the lumen radius is sufficiently smaller than the wavelength of the pulsatile pressure wave. A radial coordinate transformation is employed to immobilize the effect of the vessel wall. The resulting partial differential equations along with the boundary and initial conditions are solved using finite difference method. The dimensionless radial and axial velocity, volumetric flow rate, resistance impedance and wall shear stress are analyzed for normal and diseased artery with particular focus on variation of these quantities with non-Newtonian parameters.
Lemarchand, Claire A; Todd, Billy D; Daivis, Peter J; Hansen, Jesper S
2015-01-01
The rheology and molecular structure of a model bitumen (Cooee bitumen) under shear is investigated in the non-Newtonian regime using non-equilibrium molecular dynamics simulations. The shear viscosity and normal stress differences of the bitumen mixture are computed at different shear rates and different temperatures. The model bitumen is shown to be a shear-thinning fluid. The corresponding molecular structure is studied at the same shear rates and temperatures. The Cooee bitumen is able to reproduce experimental results showing the formation of nanoaggregates composed of stacks of flat aromatic molecules. These nanoaggregates are immersed in a solvent of saturated hydrocarbon molecules. The nanoaggregates are shown to break up at very high shear rates, leading only to a minor effect on the viscosity of the mixture. At low shear rates, bitumen can be seen as a colloidal suspension of nanoaggregates in a solvent. The slight anisotropy of the whole sample due to the nanoaggregates is considered and quantified...
Hydromagnetic Non-Darcian Free-Convective Flow of a Non-Newtonian Fluid with Temperature Jump
Directory of Open Access Journals (Sweden)
Ahmed M. Salem
2013-01-01
Full Text Available In the present study, the effect of viscous dissipation on magnetohydrodynamic (MHD non-Darcian free-convection flow of a non-Newtonian power-law fluid past a vertical flat plate in a saturated porous medium with variable viscosity and temperature jump is considered. The fluid is permeated by a transverse magnetic field imposed perpendicularly to the plate on the assumption of a small magnetic Reynolds number. The fluid viscosity is assumed to vary as a reciprocal of linear function of temperature. The governing boundary layer equations and boundary conditions are cast into a dimensionless form and simplified by using a similarity transformation into a system of nonlinear ordinary differential equations and solved numerically. The effects of the governing parameters on the flow fields and heat transfer are shown in graphs and tabular form.
El-Amin, Mohamed
2012-06-02
The problem of thermal dispersion effects on unsteady free convection from an isothermal horizontal circular cylinder to a non-Newtonian fluid saturating a porous medium is examined numerically. The Darcy-Brinkman-Forchheimer model is employed to describe the flow field. The thermal diffusivity coefficient has been assumed to be the sum of the molecular diffusivity and the dynamic diffusivity due to mechanical dispersion. The simultaneous development of the momentum and thermal boundary layers are obtained by using finite difference method. The stability conditions are determined for each difference equation. Using an explicit finite difference scheme, solutions at each time-step have been found and then stepped forward in time until reaching steady state solution. Velocity and temperature profiles are shown graphically. It is found that as time approaches infinity, the values of friction factor and heat transfer coefficient approach the steady state values.
Nabwey, Hossam A.; Boumazgour, Mohamed; Rashad, A. M.
2017-03-01
The group method analysis is applied to study the steady mixed convection stagnation-point flow of a non-Newtonian nanofluid towards a vertical stretching surface. The model utilized for the nanofluid incorporates the Brownian motion and thermophoresis effects. Applying the one-parameter transformation group which reduces the number of independent variables by one and thus, the system of governing partial differential equations has been converted to a set of nonlinear ordinary differential equations, and these equations are then computed numerically using the implicit finite-difference scheme. Comparison with previously published studies is executed and the results are found to be in excellent agreement. Results for the velocity, temperature, and the nanoparticle volume fraction profiles as well as the local skin-friction coefficient and local Nusselt number are presented in graphical and tabular forms, and discussed for different values of the governing parameters to show interesting features of the solutions.
Directory of Open Access Journals (Sweden)
A. O. Morais
2015-06-01
Full Text Available AbstractEnhanced heat transfer in tubes under laminar flow conditions can be found in coils or corrugated tubes or in the presence of high wall relative roughness, curves, pipe fittings or mechanical vibration. Modeling these cases can be complex because of the induced secondary flow. A modification of the Graetz problem for non-Newtonian power-law flow is proposed to take into account the augmented heat transfer by the introduction of an effective radial thermal diffusivity. The induced mixing was modeled as an increased radial heat transfer in a straight tube. Three experiments using a coiled tube and a tubular heat exchanger with high relative wall roughness are presented in order to show how this parameter can be obtained. Results were successfully correlated with Reynolds number. This approach can be useful for modeling laminar flow reactors (LFR and tubular heat exchangers available in the chemical and food industries.
Institute of Scientific and Technical Information of China (English)
HE Wen-zhi; LI Guang-ming; JIANG Zhao-hua; SUO Quan-ling
2007-01-01
Liquids to be broken up using a prefilming airblast atomizer are usually Newton liquids with relatively low viscosities. While in some industrial processes, such as spray drying, liquids to be atomized are high concentration suspensions or non-Newtonian fluids with high viscosities. In this paper, non-Newtonian fluids with viscosity up to 4. 4 Pa · s were effectively atomized using a specially designed prefilming airblast atomizer. The atomizer enabled liquid to extend to a thickness-adjustable film and forced the atomizing air stream to swirl with 30° or 45° through gas distributors with spiral slots. The liquid film was impinged by the swirling air stream resulting in the disintegration of the film into drops. Drop sizes were measured using a laser diffraction technique.An improved four-parameter mathematical model was established to relate the Sauter mean diameter of drops to the atomization conditions in terms of power dependencies on three dimensionless groups: Weber number,Ohnesorge number and air liquid mass ratio. The friction on the surface of the 1iquid film made by swirling air stream played an important role in the prefilming atomization at the conditions of low air velocity and low liquid viscosity. In this case, the liquid film was disintegrated into drops according to the classical wavy-sheet mechanism, thus thinner liquid films and high swirl levels of the atomizing air produced smaller drops. With the increase of the air velocity and the liquid viscosity, the effect of the friction on the prefilming atomization relatively weakened, whereas the impingement on the liquid film made by atomizing air stream in a direction normal to the liquid film and corresponding momentum transfer gradually strengthened and eventually dominated the disruption of liquid into drops, which induced that the initial thickness of the liquid film and the swirl of atomizing air stream exercised a minor influence on the drop sizes.
INVESTIGATION OF THE INTERACTIONS BETWEEN WATER AND MODIFIED SILICA GEL BY IGC AND TPD
Institute of Scientific and Technical Information of China (English)
LI Xin; LI Zhong; XIA Qibin; XI Hongxia
2006-01-01
In this work, the thermodynamic parameters for the adsorption of water vapor on untreated silica gel and silica gel treated with hygroscopic salts and silane coupling agent were determined by Inverse Gas Chromatography (IGC) in the infinite dilution region. The desorption activation energies of the water vapor on virgin and modified silica gels were estimated by using the Temperature Programmed Desorption (TPD) technique. The interactions between the water and the virgin and modified silica gels were discussed. Results showed that the thermodynamic parameters and desorption activation energy of water vapour on the silica gels increase with decreasing pore size and increasing the surface hydrophilic properties. The desorption activation energy of virgin and modified silica gels was found to increase with increasing the thermodynamic parameters. The larger the adsorption parameters and the desorption activation energy were, the interactions between water and virgin and modified silica gels were.
Directory of Open Access Journals (Sweden)
Ziye Ling
2017-01-01
Full Text Available In this paper, an aqueous solution of xanthan gum (XG at a weight fraction as high as 0.2% was elected as the non-Newtonian base liquid, the multi-walled carbon nanotubes (MWCNTs dispersed into non-Newtonian XG aqueous at different weight factions of MWCNTs was prepared. Convection heat transfer of non-Newtonian nanofluids in the shell side of helical baffled heat exchanger combined with elliptic tubes has been investigated experimentally and numerically using single-phase flow model. Results showed that the enhancement of the convective heat transfer coefficient increases with an increase in the Reynolds number and the nanoparticle concentration. For nanofluids with 0.2 wt %, 0.5 wt % and 1.0 wt % MWCNTs, the Nusselt number, respectively, increases by 11%, 21% and 35% on average at the same Reynolds number, while the comprehensive thermal performance factors are 3%–5%, 15%–17% and 24%–26% higher than that of base fluid at the same volume rate. A remarkable heat transfer enhancement can be obtained by adding MWCNTs into XG aqueous solution based on thermal resistance analysis. Correlations have been suggested for the shell-side Nusselt number and friction factor of non-Newtonian nanofluids in the helical baffled heat exchanger with elliptic tubes. Good agreements existed between corrections and experimental data.
Directory of Open Access Journals (Sweden)
K. Mehala
2016-12-01
Full Text Available The hydrodynamic bearings are stressed by severe workings conditions, such as speed, load, and the oil will be increasingly solicit by pressure and shear. The Newtonian behavior is far from being awarded in this case, the most loaded bearings operating at very high speeds; the shear rate of the oil is of higher order. A numerical analysis of the behavior of non-Newtonian fluid for plain cylindrical journal bearing finite dimension coated with antifriction material with a high tin content, for to facilitate the accommodation of the surfaces and save the silk of the shaft in the case of a contact. this analyses is implemented using the code-ANSYS CFX, by solving the energy equation with the finite difference method, considering that laminar regime and the fluid is non Newtonian by using the power law Ostwald model, the coefficient n is equal to 1.25 and for different model such as Bingham, cross and Hereshek-Bulkley model. This study aims to better predict the non-Newtonian behavior of the oil film in bearings operating under more severe conditions. The purpose conducted during this study is to predict the effect of non-Newtonian behavior of the film; the journal bearing operating under severe conditions, the speed of rotation varies from 1000 to 9000 rpm and the bearing working under radial load 2 to 10 kN. Temperature and the pressure within the fluid film assumed non-Newtonian are high, with a coefficient n greater than 1 that is to say for viscoelastic fluids.
Codoni, Doroty; Belton, Peter; Qi, Sheng
2015-06-01
Highly complex, multicomponent gels and water-containing soft materials have varied applications in biomedical, pharmaceutical, and food sciences, but the characterization of these nanostructured materials is extremely challenging. The aim of this study was to use stearoyl macrogol-32 glycerides (Gelucire 50/13) gels containing seven different species of glycerides, PEG, and PEG-esters, as model, complex, multicomponent gels, to investigate the effect of water content on the micro- and nanoarchitecture of the gel interior. Thermal analysis and NMR relaxometry were used to probe the thermal and diffusional behavior of water molecules within the gel network. For the highly concentrated gels (low water content), the water activity was significantly lowered due to entrapment in the dense gel network. For the gels with intermediate water content, multiple populations of water molecules with different thermal responses and diffusion behavior were detected, indicating the presence of water in different microenvironments. This correlated with the network architecture of the freeze-dried gels observed using SEM. For the gels with high water content, increased quantities of water with similar diffusion characteristics as free water could be detected, indicating the presence of large water pockets in these gels. The results of this study provide new insights into structure of Gelucire gels, which have not been reported before because of the complexity of the material. They also demonstrate that the combination of thermal analysis and NMR relaxometry offers insights into the structure of soft materials not available by the use of each technique alone. However, we also note that in some instances the results of these measurements are overinterpreted and we suggest limitations of the methods that must be considered when using them.
NMR imaging and hydrodynamic analysis of neutrally buoyant non-Newtonian slurry flows
Bouillard, J. X.; Sinton, S. W.
The flow of solids loaded suspension in cylindrical pipes has been the object of intense experimental and theoretical investigations in recent years. These types of flows are of great interest in chemical engineering because of their important use in many industrial manufacturing processes. Such flows are for example encountered in the manufacture of solid-rocket propellants, advanced ceramics, reinforced polymer composites, in heterogeneous catalytic reactors, and in the pipeline transport of liquid-solids suspensions. In most cases, the suspension microstructure and the degree of solids dispersion greatly affect the final performance of the manufactured product. For example, solid propellant pellets need to be extremely-well dispersed in gel matrices for use as rocket engine solid fuels. The homogeneity of pellet dispersion is critical to allow good uniformity of the burn rate, which in turn affects the final mechanical performance of the engine. Today's manufacturing of such fuels uses continuous flow processes rather than batch processes. Unfortunately, the hydrodynamics of such flow processes is poorly understood and is difficult to assess because it requires the simultaneous measurements of liquid/solids phase velocities and volume fractions. Due to the recent development in pulsed Fourier Transform NMR imaging, NMR imaging is now becoming a powerful technique for the non intrusive investigation of multi-phase flows. This paper reports and exposes a state-of-the-art experimental and theoretical methodology that can be used to study such flows. The hydrodynamic model developed for this study is a two-phase flow shear thinning model with standard constitutive fluid/solids interphase drag and solids compaction stresses. this model shows good agreement with experimental data and the limitations of this model are discussed.
Di Federico, V.; Ciriello, V.
2011-12-01
Non-Newtonian fluid flow in porous media is of considerable interest in hydrology, chemical and petroleum engineering, and biofluid mechanics. We consider an infinite porous domain of plane (d=1), cylindrical (d=2) or semi-spherical geometry (d=3), having uniform permeability k and porosity Φ, initially at uniform pressure and saturated by a weakly compressible non-Newtonian fluid, and analyze the dynamics of the pressure variation generated within the domain by an instantaneous mass injection m0 in its origin. The fluid is described by a rheological power-law model of given consistency index H and flow behavior index n; the flow law is a modified Darcy's law depending on H, Φ, n. Coupling flow law and mass balance equations yields the nonlinear partial differential equation governing the pressure field; an analytical solution is derived in space r and time t as a function of a self-similar variable η=r/tβ(n). We revisit and expand the work in previous papers by providing a dimensionless general formulation and solution to the problem for d=1,2,3. When a shear-thinning fluid (nfluids; the front velocity is proportional to t(n-2)/2 in plane geometry, t(2n-3)/(3-n) in cylindrical geometry, and t(3n-4)/(4-2n) in semi-spherical geometry. The front position is a markedly increasing function of n and is inversely dependent on d; the pressure front advances at a slower rate for larger values of compressibility, higher injected mass and lower porosity. When pressure is considered, it is seen that an increase in d from 1 to 3 brings about an order of magnitude reduction. An increase in compressibility implies a significant decrease in pressure, especially at early times. To reflect the uncertainty inherent in values of the problem parameters, we then consider selected properties of fluid (flow behavior index n) and porous domain (permeability k, porosity Φ, and medium compressibility cp) as independent random variables with uniform probability distribution. The
Di Federico, V.; Longo, S.; Ciriello, V.; Chiapponi, L.
2015-12-01
A theoretical and experimental analysis of non-Newtonian gravity-driven flow in porous media with spatially variable properties is presented. The motivation for our study is the rheological complexity exhibited by several environmental contaminants (wastewater sludge, oil pollutants, waste produced by the minerals and coal industries) and remediation agents (suspensions employed to enhance the efficiency of in-situ remediation). Natural porous media are inherently heterogeneous, and this heterogeneity influences the extent and shape of the porous domain invaded by the contaminant or remediation agent. To grasp the combined effect of rheology and spatial heterogeneity, we consider: a) the release of a thin current of non-Newtonian power-law fluid into a 2-D, semi-infinite and saturated porous medium above a horizontal bed; b) perfectly stratified media, with permeability and porosity varying along the direction transverse (vertical) or parallel (horizontal) to the flow direction. This continuous variation of spatial properties is described by two additional parameters. In order to represent several possible spreading scenarios, we consider: i) instantaneous injection with constant mass; ii) continuous injection with time-variable mass; iii) instantaneous release of a mound of fluid, which can drain freely out of the formation at the origin (dipole flow). Under these assumptions, scalings for current length and thickness are derived in self similar form. An analysis of the conditions on model parameters required to avoid an unphysical or asymptotically invalid result is presented. Theoretical results are validated against multiple sets of experiments, conducted for different combinations of spreading scenarios and types of stratification. Two basic setups are employed for the experiments: I) direct flow simulation in an artificial porous medium constructed superimposing layers of glass beads of different diameter; II) a Hele-Shaw (HS) analogue made of two parallel
Hubler, B.; Cornaz, A.; Kündig, W.
1995-04-01
The gravitational constant G has been determined at two effective interaction distances 88 m and 112 m, respectively. The 1/r2 dependence of the Newtonian gravitational force law is tested by comparing these results with the currently accepted laboratory determination of G. A high-precision balance was used to measure the weight difference of two 1-kg stainless steel masses as a function of the variable water level of a pumped-storage lake. Water-level changes up to 44 m produced a maximum weight difference of 1390 μg, which could be measured with a resolution of 0.5 μg. The difference measurement was carried out to diminish several systematic effects; e.g., tides and balance drifts become negligible. Basically, the measurement directly yields the gravitational interaction between the test masses and the locally moved mass (water and air). Data of weight difference and water level were recorded over several months of the last three years. They yield values for G of (6.669+/-0.005)×10-11 m3 kg-1 s-2 at 112 m and (6.678+/-0.007)×10-11 m3 kg-1 s-2 at 88 m, both in agreement with laboratory determinations. New constraints on the strength and range of a composition-independent fifth force are set.
Effects of water,Na+ and Ca2+ on stress-relaxation properties of surimi gel
Institute of Scientific and Technical Information of China (English)
刘友明; 栗瑞娟; 赵思明; 熊善柏
2008-01-01
Surimi gel was made from silver carp(hypophthalmichthys molitrix).Texture analyzer was adopted to measure stress-relaxation curve to study the effects of water,Na+ and Ca2+ on relaxation properties of surimi gel,so as to provide the basic data for development of surimi gel products.Micromodel of gel based on continuous phase of protein network with water embed and dispersed phase of myofibril was established.Stress-relaxation properties of the gel were imitated by use of five-element relaxation mathematical model,with high fitted precision.The results show that addition of water can reduce hardness of gel;Na+ and Ca2+ can improve the viscoelasticity of gel.
Linking the fractional derivative and the Lomnitz creep law to non-Newtonian time-varying viscosity
Pandey, Vikash; Holm, Sverre
2016-09-01
Many of the most interesting complex media are non-Newtonian and exhibit time-dependent behavior of thixotropy and rheopecty. They may also have temporal responses described by power laws. The material behavior is represented by the relaxation modulus and the creep compliance. On the one hand, it is shown that in the special case of a Maxwell model characterized by a linearly time-varying viscosity, the medium's relaxation modulus is a power law which is similar to that of a fractional derivative element often called a springpot. On the other hand, the creep compliance of the time-varying Maxwell model is identified as Lomnitz's logarithmic creep law, making this possibly its first direct derivation. In this way both fractional derivatives and Lomnitz's creep law are linked to time-varying viscosity. A mechanism which yields fractional viscoelasticity and logarithmic creep behavior has therefore been found. Further, as a result of this linking, the curve-fitting parameters involved in the fractional viscoelastic modeling, and the Lomnitz law gain physical interpretation.
Directory of Open Access Journals (Sweden)
M. H. Yazdi
2014-01-01
Full Text Available In the present study, the first and second law analyses of power-law non-Newtonian flow over embedded open parallel microchannels within micropatterned permeable continuous moving surface are examined at prescribed surface temperature. A similarity transformation is used to reduce the governing equations to a set of nonlinear ordinary differential equations. The dimensionless entropy generation number is formulated by an integral of the local rate of entropy generation along the width of the surface based on an equal number of microchannels and no-slip gaps interspersed between those microchannels. The velocity, the temperature, the velocity gradient, and the temperature gradient adjacent to the wall are substituted into this equation resulting from the momentum and energy equations obtained numerically by Dormand-Prince pair and shooting method. Finally, the entropy generation numbers, as well as the Bejan number, are evaluated. It is noted that the presence of the shear thinning (pseudoplastic fluids creates entropy along the surface, with an opposite effect resulting from shear thickening (dilatant fluids.
Directory of Open Access Journals (Sweden)
M. Rahimi-Gorji
2015-06-01
Full Text Available An analytical investigation is applied for unsteady motion of a rigid spherical particle in a quiescent shear-thinning power-law fluid. The results were compared with those obtained from Collocation Method (CM and the established Numerical Method (Fourth order Runge–Kutta scheme. It was shown that CM gave accurate results. Collocation Method (CM and Numerical Method are used to solve the present problem. We obtained that the CM which was used to solve such nonlinear differential equation with fractional power is simpler and more accurate than series method such as HPM which was used in some previous works by others but the new method named Akbari-Ganji’s Method (AGM is an accurate and simple method which is slower than CM for solving such problems. The terminal settling velocity—that is the velocity at which the net forces on a falling particle eliminate—for three different spherical particles (made of plastic, glass and steel and three flow behavior index n, in three sets of power-law non-Newtonian fluids was investigated, based on polynomial solution (CM. Analytical results obtained indicated that the time of reaching the terminal velocity in a falling procedure is significantly increased with growing of the particle size that validated with Numerical Method. Further, with approaching flow behavior to Newtonian behavior from shear-thinning properties of flow (n → 1, the transient time to achieving the terminal settling velocity is decreased.
A constitutive framework for the non-Newtonian pressure tensor of a simple fluid under planar flows.
Hartkamp, Remco; Todd, B D; Luding, Stefan
2013-06-28
Non-equilibrium molecular dynamics simulations of an atomic fluid under shear flow, planar elongational flow, and a combination of shear and elongational flow are unified consistently with a tensorial model over a wide range of strain rates. A model is presented that predicts the pressure tensor for a non-Newtonian bulk fluid under a homogeneous planar flow field. The model provides a quantitative description of the strain-thinning viscosity, pressure dilatancy, deviatoric viscoelastic lagging, and out-of-flow-plane pressure anisotropy. The non-equilibrium pressure tensor is completely described through these four quantities and can be calculated as a function of the equilibrium material constants and the velocity gradient. This constitutive framework in terms of invariants of the pressure tensor departs from the conventional description that deals with an orientation-dependent description of shear stresses and normal stresses. The present model makes it possible to predict the full pressure tensor for a simple fluid under various types of flows without having to produce these flow types explicitly in a simulation or experiment.
Entropy analysis of convective MHD flow of third grade non-Newtonian fluid over a stretching sheet
Directory of Open Access Journals (Sweden)
M.M. Rashidi
2017-03-01
Full Text Available The purpose of this article is to study and analyze the convective flow of a third grade non-Newtonian fluid due to a linearly stretching sheet subject to a magnetic field. The dimensionless entropy generation equation is obtained by solving the reduced momentum and energy equations. The momentum and energy equations are reduced to a system of ordinary differential equations by a similarity method. The optimal homotopy analysis method (OHAM is used to solve the resulting system of ordinary differential equations. The effects of the magnetic field, Biot number and Prandtl number on the velocity component and temperature are studied. The results show that the thermal boundary-layer thickness gets decreased with increasing the Prandtl number. In addition, Brownian motion plays an important role to improve thermal conductivity of the fluid. The main purpose of the paper is to study the effects of Reynolds number, dimensionless temperature difference, Brinkman number, Hartmann number and other physical parameters on the entropy generation. These results are analyzed and discussed.
Drag Force of Non-newtonian Fluid on a Continuous Moving Surface with Strong Suction/Blowing
Institute of Scientific and Technical Information of China (English)
郑连存; 张欣欣; 赫冀成
2003-01-01
A theoretical analysis for the laminar boundary layer flow of a non-Newtonian fluid on a continuous moving flat plate with surface strong suction/blowing is made. The types of potential flows necessary for similar solutions to the boundary layer are determined and both analytical and numerical solutions are presented. It is shown that the solution of the boundary layer problem depends not only on the ratio of the velocity of the plate to the velocity of the free stream, but also on the suction/blowing parameter. The skin friction decreases with increasing the parameters of power law and blowing. In the case of existing suction, the shear force decreases with the increases of tangential velocity, the largest shear force occurs at wall and the smallest shear force occurs at the edge of the boundary layer. However, in the case of existing surface blowing, the shear force initially increases with tangentialvelocity and the biggest shear force occurs at the interior of the boundary layer, the skin friction approaches to zero as the blowing rate approaches the critical value.
Lemarchand, Claire A.; Bailey, Nicholas P.; Todd, Billy D.; Daivis, Peter J.; Hansen, Jesper S.
2015-06-01
The rheology and molecular structure of a model bitumen (Cooee bitumen) under shear are investigated in the non-Newtonian regime using non-equilibrium molecular dynamics simulations. The shear viscosity, normal stress differences, and pressure of the bitumen mixture are computed at different shear rates and different temperatures. The model bitumen is shown to be a shear-thinning fluid at all temperatures. In addition, the Cooee model is able to reproduce experimental results showing the formation of nanoaggregates composed of stacks of flat aromatic molecules in bitumen. These nanoaggregates are immersed in a solvent of saturated hydrocarbon molecules. At a fixed temperature, the shear-shinning behavior is related not only to the inter- and intramolecular alignments of the solvent molecules but also to the decrease of the average size of the nanoaggregates at high shear rates. The variation of the viscosity with temperature at different shear rates is also related to the size and relative composition of the nanoaggregates. The slight anisotropy of the whole sample due to the nanoaggregates is considered and quantified. Finally, the position of bitumen mixtures in the broad literature of complex systems such as colloidal suspensions, polymer solutions, and associating polymer networks is discussed.
Castellanos, Maria Monica; Pathak, Jai A; Leach, William; Bishop, Steven M; Colby, Ralph H
2014-07-15
A monoclonal antibody solution displays an increase in low shear rate viscosity upon aggregation after prolonged incubation at 40°C. The morphology and interactions leading to the formation of the aggregates responsible for this non-Newtonian character are resolved using small-angle neutron scattering. Our data show a weak repulsive barrier before proteins aggregate reversibly, unless a favorable contact with high binding energy occurs. Two types of aggregates were identified after incubation at 40°C: oligomers with radius of gyration ∼10 nm and fractal submicrometer particles formed by a slow reaction-limited aggregation process, consistent with monomers colliding many times before finding a favorable strong interaction site. Before incubation, these antibody solutions are Newtonian liquids with no increase in low shear rate viscosity and no upturn in scattering at low wavevector, whereas aggregated solutions under the same conditions have both of these features. These results demonstrate that fractal submicrometer particles are responsible for the increase in low shear rate viscosity and low wavevector upturn in scattered intensity of aggregated antibody solutions; both are removed from aggregated samples by filtering.
Chemical and rheological aspects of gel formation in the California Mastitis Test.
Whyte, David; Walmsley, Michael; Liew, Alvin; Claycomb, Rod; Mein, Graeme
2005-02-01
The rheological properties of the CMT gel were analysed. Data are presented to demonstrate that the gel is a non-homogenous, visco-elastic, non-Newtonian fluid with rheopectic, and rheodestructive behaviour. The fundamental chemistry of the CMT is reviewed and a modified theory of gel formation is presented. The implications of the rheological properties and modified theory of gel formation for an automatic sensor are discussed.
Phase Distribution of Nitrogen/Non-Newtonian Flow at Micro-T-Junction%T形微通道内氮气/非牛顿流体两相流相分配
Institute of Scientific and Technical Information of China (English)
周云龙; 刘博; 孙科
2013-01-01
以氮气作为气相工质,以纯水和浓度分别为0.10wt％、0.25wt％、0.50wt％的PAAm水溶液分别为液相工质,在当量直径为178μm的T形微通道内进行气液两相流相分配的实验.实验结果表明:非牛顿流体的性质对两相流相分配特性有着重要的影响.当液体的有效黏度增加时,弹状流和环状流的液相采出分率增加.通过对弹状流与环状流两种流型的对比,发现环状流的液相采出分率受非牛顿流体性质影响较大,而弹状流受其影响较小.%With air as the gas test fluid and both pure water and PAAm aqueous solution with 0.01wt％,0.25wt％ and 0.50wt％ as the test fluid,an experimental investigation into phase distribution of gas-liquid flow through a T-junction with 178μm hydraulic diameter was conducted.The experimental results show that the property of non-Newtonian fluid in micro-T-junction can influence the phase distribution,and the decrease in liquid effective viscosity makes liquid' s taking off of both slug and annular flow reduced.Comparing the flow pattern of slug and annular flow shows that the property of non-Newtonian fluid can influence liquid' s taking-off much of the annular flow and does little on that of slug flow.
Coalescence dynamics of a Non-Newtonian drop in a Hele-Shaw cell
Angeli, Panagiota; Voulgaropoulos, Victor; Chinaud, Maxime
2016-11-01
In this study, the quasi-2D coalescence of an aqueous droplet with a flat interface is studied. The two immiscible liquids used in the coalescence experiments are a water/glycerol mixture and low viscosity oil. Experiments are conducted in a Hele-Shaw cell with an aspect ratio of 14 by 8 by 0.125 cm while time resolved velocity fields are obtained by using high-speed bright field Particle Image Velocimetry measurements. The aim of the present study is to investigate the effect of a polymer (i.e. xanthan gum), which results in a shear-thinning behaviour of the aqueous phase. It was found that the time evolution of the neck at the initial stages of coalescence follows a linear trend, which suggests that the shear-thinning behaviour at the neck region at this stage of coalescence can be considered quasi-constant in time. In addition, velocity and vorticity fields are computed inside the coalescing droplet and the bulk homophase. It is found that two pair of counter rotating vortices are generated just after the rupture of the film which separates the drop from the homophase. Furthermore, the polymer addition reduced the magnitude of the corresponding vorticity peaks in the drop and slowed down the coalescence dynamics. Project funded under the UK Engineering and Physical Sciences Research Council (EPSRC) Programme Grant MEMPHIS.
Deposition Velocities of Non-Newtonian Slurries in Pipelines: Complex Simulant Testing
Energy Technology Data Exchange (ETDEWEB)
Poloski, Adam P.; Bonebrake, Michael L.; Casella, Andrew M.; Johnson, Michael D.; Toth, James J.; Adkins, Harold E.; Chun, Jaehun; Denslow, Kayte M.; Luna, Maria; Tingey, Joel M.
2009-07-01
One of the concerns expressed by the External Flowsheet Review Team (EFRT) is about the potential for pipe plugging at the Waste Treatment and Immobilization Plant (WTP). Per the review’s executive summary, “Piping that transports slurries will plug unless it is properly designed to minimize this risk. This design approach has not been followed consistently, which will lead to frequent shutdowns due to line plugging.” To evaluate the potential for plugging, deposition-velocity tests were performed on several physical simulants to determine whether the design approach is conservative. Deposition velocity is defined as the velocity below which particles begin to deposit to form a moving bed of particles on the bottom of a straight horizontal pipe during slurry-transport operations. The deposition velocity depends on the system geometry and the physical properties of the particles and fluid. An experimental program was implemented to test the stability-map concepts presented in WTP-RPT-175 Rev. 01. Two types of simulant were tested. The first type of simulant was similar to the glass-bead simulants discussed in WTP-RPT-175 Rev. 0 ; it consists of glass beads with a nominal particle size of 150 µm in a kaolin/water slurry. The initial simulant was prepared at a target yield stress of approximately 30 Pa. The yield stress was then reduced, stepwise, via dilution or rheological modifiers, ultimately to a level of <1 Pa. At each yield-stress step, deposition-velocity testing was performed. Testing over this range of yield-stress bounds the expected rheological operating window of the WTP and allows the results to be compared to stability-map predictions for this system. The second simulant was a precipitated hydroxide that simulates HLW pretreated sludge from Hanford waste tank AZ-101. Testing was performed in a manner similar to that for the first simulant over a wide range of yield stresses; however, an additional test of net-positive suction-head required (NPSHR
El-Amin, Mohamed
2011-05-14
In this paper, a finite difference scheme is developed to solve the unsteady problem of combined heat and mass transfer from an isothermal curved surface to a porous medium saturated by a non-Newtonian fluid. The curved surface is kept at constant temperature and the power-law model is used to model the non-Newtonian fluid. The explicit finite difference method is used to solve simultaneously the equations of momentum, energy and concentration. The consistency of the explicit scheme is examined and the stability conditions are determined for each equation. Boundary layer and Boussinesq approximations have been incorporated. Numerical calculations are carried out for the various parameters entering into the problem. Velocity, temperature and concentration profiles are shown graphically. It is found that as time approaches infinity, the values of wall shear, heat transfer coefficient and concentration gradient at the wall, which are entered in tables, approach the steady state values.
Directory of Open Access Journals (Sweden)
Macha Madhu
2015-01-01
Full Text Available Two-dimensional MHD mixed convection boundary layer flow of heat and mass transfer stagnation-point flow of a non-Newtonian power-law nanofluid towards a stretching surface in the presence of thermal radiation and heat source/sink is investigated numerically. The non-Newtonian nanofluid model incorporates the effects of Brownian motion and thermophoresis. The basic transport equations are made dimensionless first and the complete nonlinear differential equations with associated boundary conditions are solved numerically by finite element method (FEM. The numerical calculations for velocity, temperature, and nanoparticles volume fraction profiles for different values of the physical parameters to display the interesting aspects of the solutions are presented graphically and discussed. The skin friction coefficient, the local Nusslet number and the Sherwood number are exhibited and examined. Our results are compatible with the existing results for a special case.
Institute of Scientific and Technical Information of China (English)
闻建平; 贾晓强; 毛国柱
2004-01-01
A small scale isotropic mass transfer model was developed for the local liquid side mass transfer coefficients in gas-liquid-solid three-phase flow airlift loop reactor for Newtonian and non-Newtonian fluids. It is based on Higbie's penetration theory and Kolmogoroff's theory of isotropic turbulence with kl=3√2D∈11/3/π(η1-1/3-λf-1/3)where e1 is local rate of energy dissipation, Af is the local microscale, r/l is the local Kolmogoroff scale and D is the diffusion coefficient. The capability of the proposed model is discussed in the light of experimental data obtained from 12 L gas-liquid-solid three-phase flow airlift loop reactor using Newtonian and non-Newtonian fluids. Good agreement with the experimental data was obtained over a wide range of conditions suggesting a general applicability of the proposed model.
Diffusion Coefficients of L-arginine in Non-Newtonian Fluid%L-精氨酸在非牛顿流体中的扩散系数
Institute of Scientific and Technical Information of China (English)
朱春英; 马友光; 季喜燕
2008-01-01
L-Arginine is an important component of amino acid injection. Its diffusion in body fluid and blood is of key importance to understand drug diffusion and drug release. As a fundamental demand for study and being a considerably valuable reference for application, in this study, the diffusion coefficients of L-arginine in polyacryla-mide(PAM) aqueous solution used as non-Newtonian fluid similar to blood and body fluid were measured using a holographic interferometer. The effects of interaction among molecules and solution concentration on diffusion were analyzed and discussed, respectively. Based on the obstruction-scaling model, a novel modified model was presented for predicting diffusivity of solute in non-Newtonian fluid. Good agreement was achieved between the calculated value and the experimental data.
Directory of Open Access Journals (Sweden)
Salama Faiza A.
2011-01-01
Full Text Available An analysis is carried out to study the effect of heat and mass transfer on a non-Newtonian-fluid between two infinite parallel walls, one of them moving with a uniform velocity under the action of a transverse magnetic field. The moving wall moves with constant velocity in the direction of fluid flow while the free stream velocity is assumed to follow the exponentially increasing small perturbation law. Time-dependent wall suction is assumed to occur at permeable surface. The governing equations for the flow are transformed into a system of nonlinear ordinary differential equations by perturbation technique and are solved numerically by using the shooting technique with fourth order Runge-Kutta integration scheme. The effect of non-Newtonian parameter, magnetic pressure parameter, Schmidt number, Grashof number and modified Grashof number on velocity, temperature, concentration and the induced magnetic field are discussed. Numerical results are given and illustrated graphically for the considered Problem.
Hundertmark-Zaušková, A.; Lukáčová-Medviďová, M.; Nečasová, Š. (Šárka)
2016-01-01
We study the existence of weak solution for unsteady fluid-structure interaction problem for shear-thickening flow. The time dependent domain has at one part a flexible elastic wall. The evolution of fluid domain is governed by the generalized string equation with action of the fluid forces. The power-law viscosity model is applied to describe shear-dependent non-Newtonian fluids.
Deyranlou, Amin; Niazmand, Hamid; Sadeghi, Mahmood-Reza; Mesri, Yaser
2016-06-01
Blood non-Newtonian behavior on low-density lipoproteins (LDL) accumulation is analyzed numerically, while fluid-multilayered arteries are adopted for nonstenotic and 30%-60% symmetrical stenosed models. Present model considers non-Newtonian effects inside the lumen and within arterial layers simultaneously, which has not been examined in previous studies. Navier-Stokes equations are solved along with the mass transport convection-diffusion equations and Darcy’s model for species transport inside the luminal flow and across wall layers, respectively. Carreau model for the luminal flow and the modified Darcy equation for the power-law fluid within arterial layers are employed to model blood rheological characteristics, appropriately. Results indicate that in large arteries with relatively high Reynolds number Newtonian model estimates LDL concentration patterns well enough, however, this model seriously incompetent for regions with low WSS. Moreover, Newtonian model for plasma underestimates LDL concentration especially on luminal surface and across arterial wall. Therefore, applying non-Newtonian model seems essential for reaching to a more accurate estimation of LDL distribution in the artery. Finally, blood flow inside constricted arteries demonstrates that LDL concentration patterns along the stenoses inside the luminal flow and across arterial layers are strongly influenced as compared to the nonstenotic arteries. Additionally, among four stenosis severity grades, 40% stenosis is prone to more LDL accumulation along the post-stenotic regions.
Amiri Delouei, A; Nazari, M; Kayhani, M H; Succi, S
2014-05-01
In this study, the immersed boundary-thermal lattice Boltzmann method has been used to simulate non-Newtonian fluid flow over a heated circular cylinder. The direct-forcing algorithm has been employed to couple the off-lattice obstacles and on-lattice fluid nodes. To investigate the effect of boundary sharpness, two different diffuse interface schemes are considered to interpolate the velocity and temperature between the boundary and computational grid points. The lattice Boltzmann equation with split-forcing term is applied to consider the effects of the discrete lattice and the body force to the momentum flux, simultaneously. A method for calculating the Nusselt number based on diffuse interface schemes is developed. The rheological and thermal properties of non-Newtonian fluids are investigated under the different power-law indices and Reynolds numbers. The effect of numerical parameters on the accuracy of the proposed method has been investigated in detail. Results show that the rheological and thermal properties of non-Newtonian fluids in the presence of a heated immersed body can be suitably captured using the immersed boundary thermal lattice Boltzmann method.
Kim, Chang-Beom; Lim, Jaeho; Hong, Hyobong; Kresh, J. Yasha; Wootton, David M.
2015-07-01
Detailed knowledge of the blood velocity distribution over the cross-sectional area of a microvessel is important for several reasons: (1) Information about the flow field velocity gradients can suggest an adequate description of blood flow. (2) Transport of blood components is determined by the velocity profiles and the concentration of the cells over the cross-sectional area. (3) The velocity profile is required to investigate volume flow rate as well as wall shear rate and shear stress which are important parameters in describing the interaction between blood cells and the vessel wall. The present study shows the accurate measurement of non-Newtonian blood velocity profiles at different shear rates in a microchannel using a novel translating-stage optical method. Newtonian fluid velocity profile has been well known to be a parabola, but blood is a non-Newtonian fluid which has a plug flow region at the centerline due to yield shear stress and has different viscosities depending on shear rates. The experimental results were compared at the same flow conditions with the theoretical flow equations derived from Casson non-Newtonian viscosity model in a rectangular capillary tube. And accurate wall shear rate and shear stress were estimated for different flow rates based on these velocity profiles. Also the velocity profiles were modeled and compared with parabolic profiles, concluding that the wall shear rates were at least 1.46-3.94 times higher than parabolic distribution for the same volume flow rate.
Afify, Ahmed A.; El-Aziz, Mohamed Abd
2017-02-01
The steady two-dimensional flow and heat transfer of a non-Newtonian power-law nanofluid over a stretching surface under convective boundary conditions and temperature-dependent fluid viscosity has been numerically investigated. The power-law rheology is adopted to describe non-Newtonian characteristics of the flow. Four different types of nanoparticles, namely copper (Cu), silver (Ag), alumina (Al 2 O 3) and titanium oxide (TiO 2) are considered by using sodium alginate (SA) as the base non-Newtonian fluid. Lie symmetry group transformations are used to convert the boundary layer equations into non-linear ordinary differential equations. The transformed equations are solved numerically by using a shooting method with fourth-order Runge-Kutta integration scheme. The results show that the effect of viscosity on the heat transfer rate is remarkable only for relatively strong convective heating. Moreover, the skin friction coefficient and the rate of heat transfer increase with an increase in Biot number.
Nandy, S; Tarbell, J M
1987-01-01
Wall shear stress has been measured by flush-mounted hot film anemometry distal to an Ionescu-Shiley tri-leaflet valve under pulsatile flow conditions. Both Newtonian (aqueous glycerol) and non-Newtonian (aqueous polyacrylamide) blood analog fluids were investigated. Significant differences in the axial distribution of wall shear stress between the two fluids are apparent in flows having nearly identical Reynolds numbers. The Newtonian fluid exhibits a (peak) wall shear rate which is maximized near the valve seat (30 mm) and then decays to a fully developed flow value (by 106 mm). In contrast, the shear rate of the non-Newtonian fluid at 30 mm is less than half that of the Newtonian fluid and at 106 mm is more than twice that of the Newtonian fluid. It is suggested that non-Newtonian rheology influences valve flow patterns either through alterations in valve opening associated with low shear separation zones behind valve leaflets, or because of variations in the rate of jet spreading. More detailed studies are required to clarify the mechanisms. The Newtonian wall shear stresses for this valve are low. The highest value observed anywhere in the aortic chamber was 2.85 N/m2 at a peak Reynolds number of 3694.
Indian Academy of Sciences (India)
AHMED A AFIFY; MOHAMED ABD EL-AZIZ
2017-02-01
The steady two-dimensional flow and heat transfer of a non-Newtonian power-law nanofluid over a stretching surface under convective boundary conditions and temperature-dependent fluid viscosity has been numerically investigated. The power-law rheology is adopted to describe non-Newtonian characteristics of the flow. Four different types of nanoparticles, namely copper (Cu), silver (Ag), alumina (Al$_2$O$_3$) and titanium oxide (TiO$_2$) are considered by using sodium alginate (SA) as the base non-Newtonian fluid. Lie symmetry group transformations are used to convert the boundary layer equations into non-linear ordinary differential equations. The transformed equations are solved numerically by using a shooting method with fourth-order Runge–Kutta integration scheme. The results show that the effect of viscosity on the heat transfer rate is remarkable only for relatively strong convective heating. Moreover, the skin friction coefficient and the rate of heat transfer increasewith an increase in Biot number.
Gray, J. D.; Owen, I.; Escudier, M. P.
2007-10-01
Dimensional analysis has been applied to an unsteady pulsatile flow of a shear-thinning power-law non-Newtonian liquid. An experiment was then designed in which both Newtonian and non-Newtonian liquids were used to model blood flow through a large-scale (38.5 mm dia.), simplified, rigid arterial junction (a distal anastomosis of a femorodistal bypass). The flow field within the junction was obtained by Particle Imaging Velocimetry and near-wall velocities were used to calculate the wall shear stresses. Dimensionless wall shear stresses were obtained at different points in the cardiac cycle for two different but dynamically similar non-Newtonian fluids; the good agreement between the measured dimensionless wall shear stresses confirm the validity of the dimensional analysis. However, blood exhibits a constant viscosity at high-shear rates and to obtain complete dynamic similarity between large-scale experiments and life-scale flows, the high-shear viscosity also needs to be included in the analysis. How this might be done is discussed in the paper.
Shaw, Sachin; Murthy, P V S N
2010-09-01
The present investigation deals with finding the trajectories of the drug dosed magnetic carrier particle in a microvessel with two-phase fluid model which is subjected to the external magnetic field. The radius of the microvessel is divided into the endothelial glycocalyx layer in which the blood is assumed to obey Newtonian character and a core and plug regions where the blood obeys the non-Newtonian Herschel-Bulkley character which is suitable for the microvessel of radius 50 microm. The carrier particles, bound with nanoparticles and drug molecules are injected into the vascular system upstream from malignant tissue, and captured at the tumor site using a local applied magnetic field. The applied magnetic field is produced by a cylindrical magnet positioned outside the body and near the tumor position. The expressions for the fluidic force for the carrier particle traversing in the two-phase fluid in the microvessel and the magnetic force due to the external magnetic field are obtained. Several factors that influence the magnetic targeting of the carrier particles in the microvasculature, such as the size of the carrier particle, the volume fraction of embedded magnetic nanoparticles, and the distance of separation of the magnet from the axis of the microvessel are considered in the present problem. An algorithm is given to solve the system of coupled equations for trajectories of the carrier particle in the invasive case. The trajectories of the carrier particle are found for both invasive and noninvasive targeting systems. A comparison is made between the trajectories in these cases. Also, the present results are compared with the data available for the impermeable microvessel with single-phase fluid flow. Also, a prediction of the capture of therapeutic magnetic nanoparticle in the impermeable microvasculature is made for different radii, distances and volume fractions in both the invasive and noninvasive cases.
Sampling tritiated water vapor from the atmosphere by an active system using silica gel
Energy Technology Data Exchange (ETDEWEB)
Herranz, M. [Department of Nuclear Engineering and Fluid Mechanics, E.T.S.I. de Bilbao, University of the Basque Country (UPV/EHU), Alameda de Urquijo, s/n 48013 Bilbao (Spain); Alegria, N., E-mail: natalia.alegria@ehu.es [Department of Nuclear Engineering and Fluid Mechanics, E.T.S.I. de Bilbao, University of the Basque Country (UPV/EHU), Alameda de Urquijo, s/n 48013 Bilbao (Spain); Idoeta, R.; Legarda, F. [Department of Nuclear Engineering and Fluid Mechanics, E.T.S.I. de Bilbao, University of the Basque Country (UPV/EHU), Alameda de Urquijo, s/n 48013 Bilbao (Spain)
2011-11-15
Among the different methods used to collect the tritiated water vapor (HTO) contained in the atmosphere, one of the most worldwide used is its collection using an air pump, which forces the air to pass through a dry silica gel trap. The silica gel is then distilled to remove the water collected, which is measured in a liquid scintillation counting system. In this paper, an analysis of the water collection efficiency of the silica gel has been done as a function of the temperatures involved, the dimensions of the pipe driving the air into the silica gel traps, the air volume passing through the trap and the flow rates used. Among the obtained conclusions, it can be pointed out that placing the traps inside a cooled container, the amount of silica gel needed to collect all the water contained in the air passing through these traps can be estimated using a weather forecast and a psychometric chart. To do this, and as thermal equilibrium between incoming and open air should be established, a suitable design of the sampling system is proposed. - Highlights: > To recollect the atmosphere air tritiated water vapor, an active system was used. > The system is an air pump and three traps with silica gel connected by a rubber pipe. > The silica gel retention depends on the meteorological conditions and the flow rate. > The amount of water collected and the mass of silica gel need were calculated, F.
Kabinejadian, Foad; Ghista, Dhanjoo N
2012-09-01
We have recently developed a novel design for coronary arterial bypass surgical grafting, consisting of coupled sequential side-to-side and end-to-side anastomoses. This design has been shown to have beneficial blood flow patterns and wall shear stress distributions which may improve the patency of the CABG, as compared to the conventional end-to-side anastomosis. In our preliminary computational simulation of blood flow of this coupled sequential anastomoses design, the graft and the artery were adopted to be rigid vessels and the blood was assumed to be a Newtonian fluid. Therefore, the present study has been carried out in order to (i) investigate the effects of wall compliance and non-Newtonian rheology on the local flow field and hemodynamic parameters distribution, and (ii) verify the advantages of the CABG coupled sequential anastomoses design over the conventional end-to-side configuration in a more realistic bio-mechanical condition. For this purpose, a two-way fluid-structure interaction analysis has been carried out. A finite volume method is applied to solve the three-dimensional, time-dependent, laminar flow of the incompressible, non-Newtonian fluid; the vessel wall is modeled as a linearly elastic, geometrically non-linear shell structure. In an iteratively coupled approach the transient shell equations and the governing fluid equations are solved numerically. The simulation results indicate a diameter variation ratio of up to 4% and 5% in the graft and the coronary artery, respectively. The velocity patterns and qualitative distribution of wall shear stress parameters in the distensible model do not change significantly compared to the rigid-wall model, despite quite large side-wall deformations in the anastomotic regions. However, less flow separation and reversed flow is observed in the distensible models. The wall compliance reduces the time-averaged wall shear stress up to 32% (on the heel of the conventional end-to-side model) and somewhat
Stotesbury, Theresa; Illes, Mike; Wilson, Paul; Vreugdenhil, Andrew J
2017-06-01
This work investigates the spreading dynamics of three candidate sol-gel solutions, of ranging viscosities, surface tensions and densities, and compares them with water and two commercial blood substitute products. Droplets were created with different sizes (10 to75μL) and impact velocities (1.4 to 6.0m/s) to strike 176gsm cardstock. Over 2200 droplets were created using the six different fluids and their final dried stain diameter was measured. Droplet spread was plotted using the Scheller and Bousfield correlation and uses effective viscosity as a parameter for non-Newtonian fluids. Comparing the results to an expected whole human blood range validated the spread of the candidate FBS sol-gel material in passive drip bloodstain pattern simulation. These findings complement the practical application of the material as a safe substitute for demonstrating droplet spread under controlled conditions on hard paper surfaces. Copyright © 2017 Elsevier B.V. All rights reserved.
A Remark on the Time Decay of Non-Newtonian Flows in R3%关于非牛顿流体衰减性的一个注记
Institute of Scientific and Technical Information of China (English)
殷谷良
2009-01-01
In the study of long time asymptotic behaviors of the solutions to a class system of the incompressible non-Newtonian fluid flows in R3, it is proved that the weak solutions decay in L2 norm at (1+t) and the error of difference between non-Newtonian fluid and linear equation is also investigated. The findings are mainly based on the classic Fourier splitting methods.
Energy Technology Data Exchange (ETDEWEB)
Gorjiara, Tina; Hill, Robin; Kuncic, Zdenka; Bosi, Stephen; Davies, Justin B; Baldock, Clive, E-mail: clive.baldock@sydney.edu.au [Institute of Medical Physics, School of Physics, University of Sydney, NSW 2006 (Australia)
2011-08-07
The genipin radiochromic gel offers enormous potential as a three-dimensional dosimeter in advanced radiotherapy techniques. We have used several methods (including Monte Carlo simulation), to investigate the water equivalency of genipin gel by characterizing its radiological properties, including mass and electron densities, photon interaction cross sections, mass energy absorption coefficient, effective atomic number, collisional, radiative and total mass stopping powers and electron mass scattering power. Depth doses were also calculated for clinical kilovoltage and megavoltage x-ray beams as well as megavoltage electron beams. The mass density, electron density and effective atomic number of genipin were found to differ from water by less than 2%. For energies below 150 keV, photoelectric absorption cross sections are more than 3% higher than water due to the strong dependence on atomic number. Compton scattering and pair production interaction cross sections for genipin gel differ from water by less than 1%. The mass energy absorption coefficient is approximately 3% higher than water for energies <60 keV due to the dominance of photoelectric absorption in this energy range. The electron mass stopping power and mass scattering power differ from water by approximately 0.3%. X-ray depth dose curves for genipin gel agree to within 1% with those for water. Our results demonstrate that genipin gel can be considered water equivalent for kilovoltage and megavoltage x-ray beam dosimetry. For megavoltage electron beam dosimetry, however, our results suggest that a correction factor may be needed to convert measured dose in genipin gel to that of water, since differences in some radiological properties of up to 3% compared to water are observed. Our results indicate that genipin gel exhibits greater water equivalency than polymer gels and PRESAGE formulations.
Water holding as determinant for the elastically stored energy in protein-based gels
Pouvreau, L.A.M.; Wijlen, van Emke; Klok, Jan; Urbonaite, V.; Munialo, C.D.; Jongh, de H.H.J.
2016-01-01
To evaluate the importance of the water holding capacity for the elastically stored energy of protein gels, a range of gels were created from proteins from different origin (plant: pea and soy proteins, and animal: whey, blood plasma, egg white proteins, and ovalbumin) varying in network morphology
Mani, Sriramvignesh; Khabaz, Fardin; Godbole, Rutvik V; Hedden, Ronald C; Khare, Rajesh
2015-12-10
The ability to tune the hydrophilicity of polyacrylate copolymers by altering their composition makes these materials attractive candidates for membranes used to separate alcohol-water mixtures. The separation behavior of these polyacrylate membranes is governed by a complex interplay of factors such as water and alcohol concentrations, water structure in the membrane, polymer hydrophilicity, and temperature. We use molecular dynamics simulations to investigate the effect of polymer hydrophilicity and water concentration on the structure and dynamics of water molecules in the polymer matrix. Samples of poly(n-butyl acrylate) (PBA), poly(2-hydroxyethyl acrylate) (PHEA), and a 50/50 copolymer of BA and HEA were synthesized in laboratory, and their properties were measured. Model structures of these systems were validated by comparing the simulated values of their volumetric properties with the experimental values. Molecular simulations of polyacrylate gels swollen in water and ethanol mixtures showed that water exhibits very different affinities toward the different (carbonyl, alkoxy, and hydroxyl) functional groups of the polymers. Water molecules are well dispersed in the system at low concentrations and predominantly form hydrogen bonds with the polymer. However, water forms large clusters at high concentrations along with the predominant formation of water-water hydrogen bonds and the acceleration of hydrogen bond dynamics.
Analysis of Rheological Behavior of Some Aqueous PEO Gels under Thermal Treatment
Institute of Scientific and Technical Information of China (English)
M.Todica; C.V.Pop
2009-01-01
Evolution of viscosity of some aqueous poly (ethylene oxide) gels is observed as functions of polymeric concen-tration and temperature for samples subjected to thermal shock. The experimental data are analyzed following an appropriate algorithm, and reveal the transient effect from Newtonian to non-Newtonian flow as a function of the polymeric concentration.
Effect of Water Concentration on the Molecular Structure of Polyacrylate Gels
Mani, Sriramvignesh; Khabaz, Fardin; Khare, Rajesh
2015-03-01
Recent studies have suggested pervaporation to be a promising alternative method for separation of aqueous solution of alcohol compared to distillation based separation processes. The ability to tune the hydrophobic/hydrophilic character makes polyacrylate gels attractive candidate materials for separating water-alcohol mixture by pervaporation. Experimentally, it is observed that the amount of water absorbed in the gel i.e. the degree of swelling of the gel shows a large variation with polymer chemistry. Relatively few studies exist highlighting the effects of water concentration on the membrane separation efficiency which in turn is directly related to the internal molecular structure of the water rich membranes. In this regard, an all-atom molecular dynamics (MD) simulation is employed to study water structure in polyacrylate gels. As a first step, polyacrylate copolymer systems with varying degree of hydrophobicity are prepared using the simulated annealing polymerization technique. Atomistic structures of gels containing different amounts of water are also prepared. Effect of water content on the acrylate-water system microstructure is determined by characterizing the packing of water molecules as well as the hydrogen bonding in these systems. In addition, the change in dynamics of water molecules due to the interactions with polymer is captured by monitoring the auto-correlation function of their dipole vector.
Initial experiments with gel-water: towards MRI-linac dosimetry and imaging.
Alnaghy, Sarah J; Gargett, Maegan; Liney, Gary; Petasecca, Marco; Begg, Jarrad; Espinoza, Anthony; Newall, Matthew K; Duncan, Mitchell; Holloway, Lois; Lerch, Michael L F; Lazea, Mircea; Rosenfeld, Anatoly B; Metcalfe, Peter
2016-12-01
Tracking the position of a moving radiation detector in time and space during data acquisition can replicate 4D image-guided radiotherapy (4DIGRT). Magnetic resonance imaging (MRI)-linacs need MRI-visible detectors to achieve this, however, imaging solid phantoms is an issue. Hence, gel-water, a material that provides signal for MRI-visibility, and which will in future work, replace solid water for an MRI-linac 4DIGRT quality assurance tool, is discussed. MR and CT images of gel-water were acquired for visualisation and electron density verification. Characterisation of gel-water at 0 T was compared to Gammex-RMI solid water, using MagicPlate-512 (M512) and RMI Attix chamber; this included percentage depth dose, tissue-phantom ratio (TPR20/10), tissue-maximum ratio (TMR), profiles, output factors, and a gamma analysis to investigate field penumbral differences. MR images of a non-powered detector in gel-water demonstrated detector visualisation. The CT-determined gel-water electron density agreed with the calculated value of 1.01. Gel-water depth dose data demonstrated a maximum deviation of 0.7% from solid water for M512 and 2.4% for the Attix chamber, and by 2.1% for TPR20/10 and 1.0% for TMR. FWHM and output factor differences between materials were ≤0.3 and ≤1.4%. M512 data passed gamma analysis with 100% within 2%, 2 mm tolerance for multileaf collimator defined fields. Gel-water was shown to be tissue-equivalent for dosimetry and a feasible option to replace solid water.
Khan, M O; Steinman, D A; Valen-Sendstad, K
2017-07-01
Computational fluid dynamics (CFD) shows promise for informing treatment planning and rupture risk assessment for intracranial aneurysms. Much attention has been paid to the impact on predicted hemodynamics of various modelling assumptions and uncertainties, including the need for modelling the non-Newtonian, shear-thinning rheology of blood, with equivocal results. Our study clarifies this issue by contextualizing the impact of rheology model against the recently demonstrated impact of CFD solution strategy on the prediction of aneurysm flow instabilities. Three aneurysm cases were considered, spanning a range of stable to unstable flows. Simulations were performed using a high-resolution/accuracy solution strategy with Newtonian and modified-Cross rheology models and compared against results from a so-called normal-resolution strategy. Time-averaged and instantaneous wall shear stress (WSS) distributions, as well as frequency content of flow instabilities and dome-averaged WSS metrics, were minimally affected by the rheology model, whereas numerical solution strategy had a demonstrably more marked impact when the rheology model was fixed. We show that point-wise normalization of non-Newtonian by Newtonian WSS values tended to artificially amplify small differences in WSS of questionable physiological relevance in already-low WSS regions, which might help to explain the disparity of opinions in the aneurysm CFD literature regarding the impact of non-Newtonian rheology. Toward the goal of more patient-specific aneurysm CFD, we conclude that attention seems better spent on solution strategy and other likely "first-order" effects (eg, lumen segmentation and choice of flow rates), as opposed to "second-order" effects such as rheology. Copyright © 2016 John Wiley & Sons, Ltd.
Energy Technology Data Exchange (ETDEWEB)
Al-Sharji, H.H.; Grattoni, C.A.; Zimmerman, R.W. [T.H. Huxley School of Environment, Earth Sciences and Engineering, Imperial College of Science, Technology and Medecine, London (United Kingdom); Dawe, R.A. [West Indies Univ., Dept. of Chemical Engineering, Mona (Jamaica)
2001-07-01
High water production is one of the major problems faced by the petroleum industry. One method of controlling water production is to inject polymer gels into the near-wellbore formation. Unfortunately, polymer gel injections are not always successful, in part because the exact mechanisms by which they reduce water permeability more than oil permeability (i.e., Disproportionate Permeability Reduction. DPR) are not understood. We have conducted a series of experiments on flow of water and oil through bulk polymer gels and through polymer- filled micro-models to elucidate the fundamental mechanisms involved in DPR. Flow experiments of oil and water through weak polyacrylamide-based gels have been per,formed to obtain the gel permeabilities under different test conditions. Oil and water permeabilities through the gel were each found to vary with flow rate according to a power-law, but with different pre-factors and exponents. The micro-scale flow experiments were conducted in transparent glass models to visualize clearly the flow events. Our observations enabled us to discount many previously-proposed explanations, and identify the fact that the oil and water can travel through the same pore channels, but in ways that differ, particularly at the pore scale. Water flows through the gel matrix as if flowing by diffusive flow through a porous medium, whereas the oil pushes its way In the form of immiscible drops or filaments. This difference in flow regime gives rise to the measured disproportionate permeability reduction. (authors)
Directory of Open Access Journals (Sweden)
S.Jothimani
2014-08-01
Full Text Available This paper investigates the MHD flow and heat transfer of an electrically conducting non-newtonian power-law fluid over a non-linearly stretching surface along with porous plate in porous medium. The governing equations are reduced to non-linear ordinary differential equations by means of similarity transformations. These equations are then solved numerically with the help ofRunge – Kutta shooting method. The effect of various flow parameters in the form of dimensionless quantities on the flow field are discussed and presented graphically.
Directory of Open Access Journals (Sweden)
J. Siva Ram Prasad
2016-01-01
Full Text Available We analyzed in this paper the problem of mixed convection along a vertical plate in a non-Newtonian fluid saturated non-Darcy porous medium in the presence of melting and thermal dispersion-radiation effects for aiding and opposing external flows. Similarity solution for the governing equations is obtained for the flow equations in steady state. The equations are numerically solved by using Runge-kutta fourth order method coupled with shooting technique. The effects of melting (M, thermal dispersion (D, radiation (R, magnetic field (MH, viscosity index (n and mixed convection (Ra/Pe on fluid velocity and temperature are examined for aiding and opposing external flows.
Directory of Open Access Journals (Sweden)
Muhammad Tufail
2016-01-01
Full Text Available The present article examines the flow, heat and mass transfer of a non-Newtonian fluid known as Casson fluid over a stretching surface in the presence of thermal radiations effects. Lie Group analysis is used to reduce the governing partial differential equations into non-linear ordinary differential equations. These equations are then solved by an analytical technique known as Homotopy Analysis Method (HAM. A comprehensive study of the problem is being made for various parameters involving in the equations through tables and graphs.
Directory of Open Access Journals (Sweden)
M.A. Bosse
2001-03-01
Full Text Available The problem of the effect of Joule heating generation on the hydrodynamic profile and the solute transport found in electrophoretic devices is addressed in this article. The research is focused on the following two problems: The first one is centered around the effect of Joule heating on the hydrodynamic velocity profile and it is referred to as "the carrier fluid problem." The other one is related to the effect of Joule heating on the solute transport inside electrophoretic cells and it is referred to as "the solute problem". The hydrodynamic aspects were studied first to yield the velocity profiles required for analysis of the solute transport problem. The velocity profile obtained in this study is analytical and the results are valid for non-Newtonian fluids carriers. To this end, the power-law model was used to study the effect of the rheology of the material in conjunction with the effect of Joule heating generation inside batch electrophoretic devices. This aspect of the research was then effectively used to study the effect of Joule heating generation on the motion of solutes (such as macromolecules under the influence of non-Newtonian carriers. This aspect of the study was performed using an area-averaging approach that yielded analytical results for the effective diffusivity of the device.
Thandlam, Anil Kumar; Das, Chiranjib; Majumder, Subrata Kumar
2016-08-01
Investigation of wall-liquid mass transfer and heat transfer phenomena with gas-Newtonian and non-Newtonian fluids in vertically helical coil reactor have been reported in this article. Experiments were conducted to investigate the effect of various dynamic and geometric parameters on mass and heat transfer coefficients in the helical coil reactor. The flow pattern-based heat and mass transfer phenomena in the helical coil reactor are highlighted at different operating conditions. The study covered a wide range of geometric parameters such as diameter of the tube (d t ), diameter of the coil (D c ), diameter of the particle (d p ), pitch difference (p/D c ) and concentrations of non-Newtonian liquid. The correlation models for the heat and mass transfer coefficient based on the flow pattern are developed which may be useful in process scale-up of the helical coil reactor for industrial application. The frictional drag coefficient was also estimated and analyzed by mass transfer phenomena based on the electrochemical method.
Jianping; Ping; Lin; Yunlin
2000-07-01
The local overall volumetric gas-liquid mass transfer coefficients at the specified point in a gas-liquid-solid three-phase reversed flow jet loop bioreactor (JLB) with a non-Newtonian fluid was experimentally investigated by a transient gassing-in method. The effects of liquid jet flow rate, gas jet flow rate, particle density, particle diameter, solids loading, nozzle diameter and CMC concentration on the local overall volumetric gas-liquid mass transfer coefficient (K(L)a) profiles were discussed. It was observed that local overall K(L)a profiles in the three-phase reversed flow JLB with non-Newtonian fluid increased with the increase of gas jet flow rate, liquid jet flow rate, particle density and particle diameter, but decreased with the increase of the nozzle diameter and CMC concentration. The presence of solids at a low concentration increased the local overall K(L)a profiles, and the optimum of solids loading for a maximum profile of the local overall K(L)a was found to be 0.18x10(-3)m(3) corresponding to a solids volume fraction, varepsilon(S)=2.8%.
Yang, Chun; Tang, Dalin; Yuan, Chun; Hatsukami, Thomas S; Zheng, Jie; Woodard, Pamela K
2007-01-01
It has been recognized that fluid-structure interactions (FSI) play an important role in cardiovascular disease initiation and development. However, in vivo MRI multi-component FSI models for human carotid atherosclerotic plaques with bifurcation and quantitative comparisons of FSI models with fluid-only or structure-only models are currently lacking in the literature. A 3D non-Newtonian multi-component FSI model based on in vivo/ex vivo MRI images for human atherosclerotic plaques was introduced to investigate flow and plaque stress/strain behaviors which may be related to plaque progression and rupture. Both artery wall and plaque components were assumed to be hyperelastic, isotropic, incompressible and homogeneous. Blood flow was assumed to be laminar, non-Newtonian, viscous and incompressible. In vivo/ex vivo MRI images were acquired using histologically-validated multi-spectral MRI protocols. The 3D FSI models were solved and results were compared with those from a Newtonian FSI model and wall-only/fluid-only models. A 145% difference in maximum principal stresses (Stress-P(1)) between the FSI and wall-only models and 40% difference in flow maximum shear stress (MSS) between the FSI and fluid-only models were found at the throat of the plaque using a severe plaque sample (70% severity by diameter). Flow maximum shear stress (MSS) from the rigid wall model is much higher (20-40% in maximum MSS values, 100-150% in stagnation region) than those from FSI models.
Deyranlou, Amin; Niazmand, Hamid; Sadeghi, Mahmood-Reza
2015-09-18
Low-density lipoprotein (LDL), which is recognized as bad cholesterol, typically has been regarded as a main cause of atherosclerosis. LDL infiltration across arterial wall and subsequent formation of Ox-LDL could lead to atherogenesis. In the present study, combined effects of non-Newtonian fluid behavior and fluid-structure interaction (FSI) on LDL mass transfer inside an artery and through its multilayer arterial wall are examined numerically. Navier-Stokes equations for the blood flow inside the lumen and modified Darcy's model for the power-law fluid through the porous arterial wall are coupled with the equations of mass transfer to describe LDL distributions in various segments of the artery. In addition, the arterial wall is considered as a heterogeneous permeable elastic medium. Thus, elastodynamics equation is invoked to examine effects of different wall elasticity on LDL distribution in the artery. Findings suggest that non-Newtonian behavior of filtrated plasma within the wall enhances LDL accumulation meaningfully. Moreover, results demonstrate that at high blood pressure and due to the wall elasticity, endothelium pores expand, which cause significant variations on endothelium physiological properties in a way that lead to higher LDL accumulation. Additionally, results describe that under hypertension, by increasing angular strain, endothelial junctions especially at leaky sites expand more dramatic for the high elastic model, which in turn causes higher LDL accumulation across the intima layer and elevates atherogenesis risk.
Malkus, David S.
1989-01-01
This project concerned the development of a new fast finite element algorithm to solve flow problems of non-Newtonian fluids such as solutions or melts of polymers. Many constitutive theories for such materials involve single integrals over the deformation history of the particle at the stress evaluation point; examples are the Doi-Edwards and Curtiss-Bird molecular theories and the BKZ family derived from continuum arguments. These theories are believed to be among the most accurate in describing non-Newtonian effects important to polymer process design, effects such as stress relaxation, shear thinning, and normal stress effects. This research developed an optimized version of the algorithm which would run a factor of two faster than the pilot algorithm on scalar machines and would be able to take full advantage of vectorization on machines. Significant progress was made in code vectorization; code enhancement and streamlining; adaptive memory quadrature; model problems for the High Weissenberg Number Problem; exactly incompressible projection; development of multimesh extrapolation procedures; and solution of problems of physical interest. A portable version of the code is in the final stages of benchmarking and testing. It interfaces with the widely used FIDAP fluid dynamics package.
Ramachandra Prasad, V.; Gaffar, S. Abdul; Keshava Reddy, E.; Bég, O. Anwar
2014-07-01
Polymeric enrobing flows are important in industrial manufacturing technology and process systems. Such flows are non-Newtonian. Motivated by such applications, in this article we investigate the nonlinear steady state boundary layer flow, heat, and mass transfer of an incompressible Jefferys non-Newtonian fluid past a vertical porous plate in a non-Darcy porous medium. The transformed conservation equations are solved numerically subject to physically appropriate boundary conditions using a versatile, implicit, Keller-box finite-difference technique. The numerical code is validated with previous studies. The influence of a number of emerging non-dimensional parameters, namely Deborah number (De), Darcy number (Da), Prandtl number (Pr), ratio of relaxation to retardation times (λ), Schmidt number (Sc), Forchheimer parameter (Λ), and dimensionless tangential coordinate (ξ) on velocity, temperature, and concentration evolution in the boundary layer regime are examined in detail. Furthermore, the effects of these parameters on surface heat transfer rate, mass transfer rate, and local skin friction are also investigated. It is found that the boundary layer flow is decelerated with increasing De and Forchheimer parameter, whereas temperature and concentration are elevated. Increasing λ and Da enhances the velocity but reduces the temperature and concentration. The heat transfer rate and mass transfer rates are found to be depressed with increasing De and enhanced with increasing λ. Local skin friction is found to be decreased with a rise in De, whereas it is elevated with increasing λ. An increasing Sc decreases the velocity and concentration but increases temperature.
The effect of sucrose on unfrozen water and syneresis of acidified sodium caseinate-xanthan gels.
Braga, A L M; Cunha, R L
2005-07-01
The influence of the ingredients of acidified Na caseinate-xanthan-sucrose gels on thermophysical properties and syneresis of the gels was studied. Sucrose concentration affected all of the gel equilibrium properties and the rate of syneresis. The positive effect of sucrose on syneresis and unfrozen water (UFW) values was attributed to different effects. The amount of UFW was governed mainly by the colligative properties of sucrose whereas the equilibrium syneresis behaviour was associated with the changes in network dynamics caused by the kosmotropic properties of sucrose. The latter could enhance xanthan-sucrose association or favour xanthan-protein interactions.
Polymer gels for water control: NMR and CT scan studies
Al-Muntasheri, G.A.
2008-01-01
As oil and gas reservoirs mature, larger volumes of water are produced. These large volumes of produced water need to be separated, processed, treated and re-injected into the reservoir. All of these processes impose extra costs to the hydrocarbon production. Water rates can increase until productio
DEVELOPMENT OF POLYMER GEL SYSTEMS TO IMPROVE VOLUMETRIC SWEEP AND REDUCE PRODUCING WATER/OIL RATIOS
Energy Technology Data Exchange (ETDEWEB)
G. Paul Willhite; Stan McCool; Don W. Green; Min Cheng; Rajeev Jain; Tuan Nguyen
2003-11-01
Gelled polymer treatments are applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report describes the results of the first year of a three-year research program that is aimed at the understanding of the chemistry of gelation and the fundamental mechanisms that alter the flows of oil and water in reservoir rocks after a gel treatment. Work has focused on a widely-applied system in field applications, the partially hydrolyzed polyacrylamide-chromium acetate gel. Gelation occurs by network formation through the crosslinking of polyacrylamide molecules as a result of reaction with chromium acetate. The initial reaction between chromium acetate and one polymer is referred to as the uptake reaction. The uptake reaction was studied as functions of chromium and polymer concentrations and pH values. Experimental data were regressed to determine a rate equation that describes the uptake reaction of chromium by polyacrylamide. Pre-gel aggregates form and grow as the reactions between chromium acetate and polyacrylamide proceed. A statistical model that describes the growth of pre-gel aggregates was developed using the theory of branching processes. The model gives molecular weight averages that are expressed as functions of the conversion of the reactive sites on chromium acetate or on the polymer molecule. Results of the application of the model correlate well with experimental data of viscosity and weight-average molecular weight and gives insights into the gelation process. A third study addresses the flow of water and oil in rock material after a gel treatment. Previous works have shown that gel treatments usually reduce the permeability to water to a greater extent than the permeability to oil is reduced. This phenomenon is referred to as disproportionate permeability reduction (DPR). Flow experiments were conducted to determine the effect of polymer and chromium concentrations on
Rathod, Maureen L.
Initially 3D FEM simulation of a simplified mixer was used to examine the effect of mixer configuration and operating conditions on dispersive mixing of a non-Newtonian fluid. Horizontal and vertical velocity magnitudes increased with increasing mixer speed, while maximum axial velocity and shear rate were greater with staggered paddles. In contrast, parallel paddles produced an area of efficient dispersive mixing between the center of the paddle and the barrel wall. This study was expanded to encompass the complete nine-paddle mixing section using power-law and Bird-Carreau fluid models. In the center of the mixer, simple shear flow was seen, corresponding with high [special character omitted]. Efficient dispersive mixing appeared near the barrel wall at all flow rates and near the barrel center with parallel paddles. Areas of backflow, improving fluid retention time, occurred with staggered paddles. The Bird-Carreau fluid showed greater influence of paddle motion under the same operating conditions due to the inelastic nature of the fluid. Shear-thinning behavior also resulted in greater maximum shear rate as shearing became easier with decreasing fluid viscosity. Shear rate distributions are frequently calculated, but extension rate calculations have not been made in a complex geometry since Debbaut and Crochet (1988) defined extension rate as the ratio of the third to the second invariant of the strain rate tensor. Extension rate was assumed to be negligible in most studies, but here extension rate is shown to be significant. It is possible to calculate maximum stable bubble diameter from capillary number if shear and extension rates in a flow field are known. Extension rate distributions were calculated for Newtonian and non-Newtonian fluids. High extension and shear rates were found in the intermeshing region. Extension is the major influence on critical capillary number and maximum stable bubble diameter, but when extension rate values are low shear rate has
Institute of Scientific and Technical Information of China (English)
葛雄; 张根广; 颜婷; 王华伟
2011-01-01
There are many differences between the Newtonian fluid and the non-Newtonian fluid, and there is a few or even not teaching apparatus to demonstrate the behavior differences between the Newtonian fluid and the non-Newtonian fluid. To strengthen understanding of the Newtonian fluid and the non-Newtonian fluid, a teaching apparatus to demonstrate the velocity distribution differences in laminar flow between the Newtonian fluid and the non-Newtonian fluid was designed and made based on the flow characteristics differences. The movement behaviors of the Newtonian fluid and the non-Newtonian fluid were displayed by the tracer liquid developed by us. The velocity distribution differences at laminar flow between the Newtonian fluid and the non-Newtonian fluid can be found easily and directly in the demonstration apparatus.%牛顿流体和非牛顿流体存在着较大的差异，有关牛顿流体和非牛顿流体特性差异方面的教学演示仪器还较少，有些还处于空白。为了加强学生对牛顿流体和非牛顿流体的认识，本文根据牛顿流体与非牛顿流体流动特性差异，设计制作了表现牛顿流体和非牛顿流体层流流速分布差异的演示仪器;利用自行研制的示踪液体演示了非牛顿流体和牛顿流体运动过程，直观的展示了牛顿流体与非牛顿流体层流流速分布的差异。
Miyawaki, Osato; Omote, Chiaki; Matsuhira, Keiko
2015-12-01
Sol-gel transition of gelatin was analyzed as a multisite stoichiometric reaction of a gelatin molecule with water and solute molecules. The equilibrium sol-gel transition temperature, Tt , was estimated from the average of gelation and melting temperature measured by differential scanning calorimetry. From Tt and the melting enthalpy, ΔHsol , the equilibrium sol-to-gel ratio was estimated by the van't Hoff equation. The reciprocal form of the Wyman-Tanford equation, which describes the sol-to-gel ratio as a function of water activity, was successfully applied to obtain a good linear relationship. From this analysis, the role of water activity on the sol-gel transition of gelatin was clearly explained and the contributions of hydration and solute binding to gelatin molecules were separately discussed in sol-gel transition. The general solution for the free energy for gel-stabilization in various solutions was obtained as a simple function of solute concentration.
Chen, Long; Tian, Yaoqi; Tong, Qunyi; Zhang, Zipei; Jin, Zhengyu
2017-01-01
The effects of pullulan on the water distribution, microstructure and textural properties of rice starch gels during cold storage were investigated by low field-nuclear magnetic resonance (LF-NMR), scanning electron microscope (SEM), and texture profile analysis (TPA). The addition of pullulan reduced the transversal relaxation time of rice starch gels during cold storage. The microstructure of rice starch gel with 0.5% pullulan was denser and more uniform compared with that of rice starch without pullulan in each period of storage time. With regard to textural properties, 0.01% pullulan addition did not significantly change the texture of rice starch gels, while 0.5% pullulan addition appeared to reduce the hardness and retain the springiness of rice starch gels (P⩽0.05). The restriction effects of pullulan on water mobility and starch retrogradation were hypothesized to be mainly responsible for the water retention, gel structure maintenance, and modification of the textural attributes of rice starch gels.
Directory of Open Access Journals (Sweden)
Macha Madhu
2016-07-01
Full Text Available Magnetohydrodynamic mixed convection boundary layer flow of heat and mass transfer stagnation-point flow of a non-Newtonian power-law nanofluid towards a stretching surface in the presence of thermal radiation is investigated numerically. The non-Newtonian nanofluid model incorporates the effects of Brownian motion and thermophoresis. The basic transport equations are made dimensionless first and the coupled non linear differential equations are solved by finite element method. The numerical calculations for velocity, temperature and concentration profiles for different values of the physical parameters presented graphically and discussed. As well as for skin friction coefficient, local Nusselt and Sherwood numbers exhibited and examined.
Study on flow field characteristics of Non-Newtonian fluid in hydrocyclone%非牛顿流体在分离旋流器内流场特性研究
Institute of Scientific and Technical Information of China (English)
艾志久; 汪利霞; 刘晓明
2011-01-01
运用计算流体动力学(CFD)方法分别对旋流器内非牛顿流体与牛顿流体的流场分别进行数值模拟.分析采用RSM(SSG)雷诺应力模型,得到非牛顿流体与牛顿流体的速度场、压力场以及表观粘度分布规律.研究结果揭示了非牛顿流体在分离旋流器内的流场特性:由于受非牛顿流体表现粘度随剪切速率变化的影响,在同一位置处,非牛顿流体的静压力、轴向速度以及径向速度都大于牛顿流体,而切向速度小于牛顿流体；同时,旋流器内非牛顿流体的零轴速包络面(LZVV)比牛顿流体更加靠近器壁,这导致旋流器中非牛顿流体在同等条件下比牛顿流体的分离效率低；以上这些特性为进一步充分认识用于分离非牛顿流体的旋流器分离机理提供依据.%The method of Computational Fluid Dynamics was used to simulate the fluid field of the non-Newtonian fluid and the Newtonian fluid in the hydrocyclone. The Analysis was operated by reynolds stress model and obtained the velocity field,the pressure field as well as the apparent viscosity distribution of non-Newtonian fluid and the Newtonian fluid. The results revealed the Flow field Characteristics of the non-Newtonian fluids in the hydrocyclone: In the same position .with the effect of apparent viscosity changes of non-Newtonian fluid,the static pressure,the axial velocity as well as radial velocity of non-Newtonian fluid were bigger than Newtonian fluid's.and the radial velocity was less; The locus of zero vertical velocity of hydrocyclone of non-Newtonian was closer to the wall;these characteristics led to lower separation efficiency of non-Newtonian fluid than Newtonian fluid's under the same conditions. This study provided the evidence for new understand of the separation mechanism of non-Newtonian fluid.
Najjari, Mohammad Reza; Plesniak, Michael W.
2016-06-01
Steady flow and physiological pulsatile flow in a rigid 180° curved tube are investigated using particle image velocimetry. A non-Newtonian blood-analog fluid is used, and in-plane primary and secondary velocity fields are measured. A vortex detection scheme ( d 2-method) is applied to distinguish vortical structures. In the pulsatile flow case, four different vortex types are observed in secondary flow: deformed-Dean, Dean, Wall and Lyne vortices. Investigation of secondary flow in multiple cross sections suggests the existence of vortex tubes. These structures split and merge over time during the deceleration phase and in space as flow progresses along the 180° curved tube. The primary velocity data for steady flow conditions reveal additional vortices rotating in a direction opposite to Dean vortices—similar to structures observed in pulsatile flow—if the Dean number is sufficiently high.
Kishan, N.; Shashidar Reddy, B.
2013-06-01
The problem of a magneto-hydro dynamic flow and heat transfer to a non-Newtonian power-law fluid flow past a continuously moving flat porous plate in the presence of sucion/injection with heat flux by taking into consideration the viscous dissipation is analysed. The non-linear partial differential equations governing the flow and heat transfer are transformed into non-linear ordinary differential equations using appropriate transformations and then solved numerically by an implicit finite difference scheme. The solution is found to be dependent on various governing parameters including the magnetic field parameter M, power-law index n, suction/injection parameter ƒw, Prandtl number Pr and Eckert number Ec. A systematical study is carried out to illustrate the effects of these major parameters on the velocity profiles, temperature profile, skin friction coefficient and rate of heat transfer and the local Nusslet number.
Energy Technology Data Exchange (ETDEWEB)
Hady, F. M.; Ibrahim, F. S. [Assiut University, Assiut (Egypt); Abdel-Gaied, S. M.; Eid, M. R. [Assiut University, The New Valley (Egypt)
2011-08-15
The effect of yield stress on the free convective heat transfer of dilute liquid suspensions of nanofluids flowing on a vertical plate saturated in porous medium under laminar conditions is investigated considering the nanofluid obeys the mathematical model of power-law. The model used for non-Newtonian nanofluid incorporates the effects of Brownian motion and thermophoresis. The governing boundary- layer equations are cast into dimensionless system which is solved numerically using a deferred correction technique and Newton iteration. This solution depends on yield stress parameter {Omega}, a power-law index n, Lewis number Le, a buoyancy-ratio number Nr, a Brownian motion number Nb, and a thermophoresis number Nt. Analyses of the results found that the reduced Nusselt and Sherwood numbers are decreasing functions of the higher yield stress parameter for each dimensionless numbers, n and Le, except the reduced Sherwood number is an increasing function of higher Nb for different values of yield stress parameter.
Directory of Open Access Journals (Sweden)
SUBBARAO ANNASAGARAM
2016-01-01
Full Text Available The laminar boundary layer flow and heat transfer of Casson non-Newtonian fluid from an inclined (solar collector plate in the presence of thermal and hydrodynamic slip conditions is analysed. The inclined plate surface is maintained at a constant temperature. The boundary layer conservation equations, which are parabolic in nature, are normalized into non-similar form and then solved numerically with the well-tested, efficient, implicit, stable Keller-box finite-difference scheme. Increasing velocity slip induces acceleration in the flow near the inclined plate surface. Increasing velocity slip consistently enhances temperatures throughout the boundary layer regime. An increase in thermal slip parameter strongly decelerates the flow and also reduces temperatures in the boundary layer regime. An increase in Casson rheological parameter acts to elevate considerably the velocity and this effect is pronounced at higher values of tangential coordinate. Temperatures are however very slightly decreased with increasing values of Casson rheological parameter.
Directory of Open Access Journals (Sweden)
Muhammad Mubashir Bhatti
2017-01-01
Full Text Available In this article, entropy generation on non-Newtonian Eyring-Powell nanofluid has been analysed through a permeable stretching sheet. The governing flow problem is based on linear momentum, thermal energy, and nanoparticle concentration equation which are simplified with the help of similarity transformation variables. The resulting coupled nonlinear ordinary differential equations are solved numerically with the help of Successive Linearization method (SLM and Chebyshev Spectral collocation method. The novel characteristics of all the physical parameters are discussed with the help of graphs and tables. The expression for local Nusselt number and local Sherwood number is also taken into account. It is observed that velocity profile increases due to the greater influence of suction parameter. Moreover, Brownian motion and thermophoresis parameter significantly enhance the temperature profile, however Brownian motion parameter shows converse behaviour on nanoparticle concentration profile. Entropy profile acts as an increasing function of all the pertinent parameters.
Directory of Open Access Journals (Sweden)
J. L. Vieira Neto
2014-12-01
Full Text Available Helical flow in an annular space occurs during oil drilling operations. The correct prediction of flow of drilling fluid in an annular space between the wellbore wall and the drill pipe is essential to determine the variation in fluid pressure within the wellbore. This paper presents experimental and CFD simulation results of the pressure drop in the flow of non-Newtonian fluids through a concentric annular section and another section with fixed eccentricity (E = 0.75, using aqueous solutions of two distinct polymers (Xanthan Gum and Carboxymethylcellulose. The hydrodynamic behavior in this annular system was analyzed based on the experimental and CFD results, providing important information such as the formation of zones with preferential flows and stagnation regions.
Directory of Open Access Journals (Sweden)
K.C. Saha
2015-04-01
Full Text Available The effects of MHD free convection heat and mass transfer of power-law Non-Newtonian fluids along a stretching sheet with viscous dissipation has been analyzed. This has been done under the simultaneous action of suction, thermal radiation and uniform transverse magnetic field. The stretching sheet is assumed to continuously moving with a power-law velocity and maintaining a uniform surface heat-flux. The governing non-linear partial differential equations are transformed into non-linear ordinary differential equations, using appropriate similarity transformations and the resulting problem is solved numerically using Nachtsheim-Swigert shooting iteration technique along with sixth order Runge-Kutta integration scheme. A parametric study of the parameters arising in the problem such as the Eckert number due to viscous dissipation, radiation number, buoyancy parameter, Schmidt number, Prandtl number etc are studied and the obtained results are shown graphically and the physical aspects of the problem are discussed.
Wang, Zheng; Neves, Marcos A; Kobayashi, Isao; Uemura, Kunihiko; Nakajima, Mitsutoshi
2013-01-01
Soybean oil-in-water (O/W) emulsion-agar gel samples were prepared and their digestibility evaluated by using an in vitro gastrointestinal digestion model. Emulsion-agar sols were obtained by mixing the prepared O/W emulsions with a 1.5 wt % agar solution at 60 °C, and their subsequent cooling at 5 °C for 1 h formed emulsion-agar gels. Their gel strength values increased with increasing degree of polymerization of the emulsifiers, and the relative gel strength increased in the case of droplets with an average diameter smaller than 700 nm. Flocculation and coalescence of the released emulsion droplets depended strongly on the emulsifier type; however, the emulsifier type hardly affected the ζ-potential of emulsion droplets released from the emulsion-agar gels during in vitro digestion. The total FFA content released from each emulsion towards the end of the digestion period was nearly twice that released from the emulsion-agar gel, indicating that gelation of the O/W emulsion may have delayed lipid hydrolysis.
Energy Technology Data Exchange (ETDEWEB)
Gorjiara, Tina; Hill, Robin; Kuncic, Zdenka; Bosi, Stephen; Baldock, Clive, E-mail: clive.baldock@sydney.edu.a
2010-11-01
Genipin gel is a radiochromic gel with the potential to be used as a three dimensional (3D) dosimeter. An ideal dosimeter should present radiologically water equivalent properties. In this work, we have evaluated the water equivalency of genipin gel by calculating its radiological properties, such as mass and electron density, effective atomic number, fractional interaction probabilities, mass energy absorption coefficient and mass stopping powers as well as depth doses for kilovoltage x-ray and megavoltage electron beams. Based on the results of this study, we conclude that genipin gel is a water equivalent dosimeter.
Stotesbury, Theresa; Illes, Mike; Wilson, Paul; Vreugdenhil, Andrew J
2017-01-01
Solution-gelation chemistry has promising applications in forensic synthetic blood substitute development. This research offers a silicon-based sol-gel approach to creating stable materials that share similar rheological properties to that of whole human blood samples. Room temperature, high water content, silicon sol-gels were created using the organosilane precursors 3-glycidoxypropyltrimethoxysilane and tetraethylorthosilicate along with various concentrations of filler and pigment. Shear-thinning non-Newtonian properties were observed within most formulations of the presented materials. The effects of colloidal concentration, temperature, age and filler addition on the viscosity of the sol-gels were investigated. SEM-EDS analysis was used to identify the behavior of the fillers within the film and support their inclusion for basic bloodstain pattern simulation. A final proposed candidate sol-gel was assessed using a previously reported passive drip simulation test on a hard, dry surface and passed. This works represents encouraging development in providing safe material alternatives to using whole human blood for forensic training and research. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.
NMR relaxation and water self-diffusion studies in whey protein solutions and gels.
Colsenet, Roxane; Mariette, François; Cambert, Mireille
2005-08-24
The changes in water proton transverse relaxation behavior induced by aggregation of whey proteins are explained in terms of the simple molecular processes of diffusion and chemical exchange. The water self-diffusion coefficient was measured in whey protein solutions and gels by the pulsed field gradient NMR method. As expected, water self-diffusion was reduced with increased protein concentrations. Whatever the concentration, the water molecules were free to diffuse over distances varying from 15 to 47 mum. Water diffusion was constant over these distances, demonstrating that no restrictions were found to explain the water hindrance. The modification in protein structure by gelation induced a decrease in water diffusion. The effects of protein concentration on water diffusion are discussed and modeled. Two approaches were compared, the obstruction effect induced by a spherical particle and the cell model, which considered two water compartments with specific self-diffusion coefficients.
Tan, Yunkai; He, Zhenbin; Xu, Tao; Fang, Xiaoming; Gao, Xuenong; Zhang, Zhengguo
2017-09-01
An aqueous solution of Xanthan Gum (XG) at a weight fraction as high as 0.2% was used as the base liquid, the stable MWCNTs-dispersed non-Newtonian nanofluids at different weight factions of MWCNTs was prepared. The base fluid and all nanofluids show pseudoplastic (shear-thinning) rheological behavior. Experiments were performed to compare the shell-side forced convective heat transfer coefficient and pressure drop of non-Newtonian nanofluids to those of non-Newtonian base fluid in an integrally helical baffle heat exchanger with low-finned tubes. The experimental results showed that the enhancement of the convective heat transfer coefficient increases with an increase in the Peclet number and the nanoparticle concentration. For nanofluids with 1.0, 0.5 and 0.2 wt% of multi-walled carbon nanotubes (MWCNTs), the heat transfer coefficients respectively augmented by 24.3, 13.2 and 4.7% on average and the pressure drops become larger than those of the base fluid. The comprehensive thermal performance factor is higher than one and increases with an increasing weight fraction of MWCNTs. A remarkable heat transfer enhancement in the shell side of helical baffle heat exchanger with low-finned tubes can be obtained by adding MWCNTs into XG aqueous solution based on thermal resistance analysis. New correlations have been suggested for the shell-side friction coefficient and the Nusselt numbers of non-Newtonian nanofluids and give very good agreement with experimental data.
Development of Polymer Gel Systems to Improve Volumetric Sweep and Reduce Producing Water/Oil Ratios
Energy Technology Data Exchange (ETDEWEB)
G. Paul Willhite; Stan McCool; Don W. Green; Min Cheng; Feiyan Chen
2005-12-31
Gelled polymer treatments are applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report describes the results of a 42-month research program that focused on the understanding of gelation chemistry and the fundamental mechanisms that alter the flows of oil and water in reservoir rocks after a gel treatment. Work was conducted on a widely applied system in the field, the partially hydrolyzed polyacrylamide-chromium acetate gel. Gelation occurs by network formation through the crosslinking of polyacrylamide molecules as a result of reaction with chromium acetate. Pre-gel aggregates form and grow as reactions between chromium acetate and polyacrylamide proceed. A rate equation that describes the reaction between chromium acetate and polymer molecules was regressed from experimental data. A mathematical model that describes the crosslinking reaction between two polymer molecules as a function of time was derived. The model was based on probability concepts and provides molecular-weight averages and molecular-weight distributions of the pre-gel aggregates as a function of time and initial system conditions. Average molecular weights of pre-gel aggregates were measured as a function of time and were comparable to model simulations. Experimental methods to determine molecular weight distributions of pre-gel aggregates were unsuccessful. Dissolution of carbonate minerals during the injection of gelants causes the pH of the gelant to increase. Chromium precipitates from solution at the higher pH values robbing the gelant of crosslinker. Experimental data on the transport of chromium acetate solutions through dolomite cores were obtained. A mathematical model that describes the transport of brine and chromium acetate solutions through rocks containing carbonate minerals was used to simulate the experimental results and data from literature. Gel treatments usually reduce the permeability
Energy Technology Data Exchange (ETDEWEB)
Takahashi, Chisato; Shirai, Takashi [Ceramics Research Laboratory, Nagoya Institute of Technology, 3-101-1, Honmachi, Tajimi, Gifu 507-0033 (Japan); Fuji, Masayoshi, E-mail: fuji@nitech.ac.jp [Ceramics Research Laboratory, Nagoya Institute of Technology, 3-101-1, Honmachi, Tajimi, Gifu 507-0033 (Japan)
2012-03-15
Highlights: Black-Right-Pointing-Pointer The mechanism of SEM observation of agar gel using ionic liquid was investigated. Black-Right-Pointing-Pointer Weak hydrogen bond between ionic liquid and water exist even under vacuum condition. Black-Right-Pointing-Pointer Ionic liquid binding ability with water is useful for observing wet material using FE-SEM. Black-Right-Pointing-Pointer We could optimize the water concentrations of sample of IL and wet material mixtures. Black-Right-Pointing-Pointer SEM observation of fine morphology of agar gel in optimum water content. - Abstract: In the present study, an attempt is made to understand the mechanism of field emission electron microscopy (FE-SEM) observation of wet agar gel using a typical hydrophilic ionic liquid (IL) 1-butyl-3-methylimidazolium tetrafluoroborate; [BMIM][BF{sub 4}]. The IL interaction with water molecules within agar gel during sample preparation condition for FE-SEM observation was investigated using Raman spectroscopy. Results showed that water molecules within agar gel form weak hydrogen bond such as BF{sub 4}{sup -} Midline-Horizontal-Ellipsis HOH Midline-Horizontal-Ellipsis BF{sub 4}{sup -} by interaction with BF{sub 4}{sup -} of IL, and, it remained stable even under vacuum condition at 60 Degree-Sign C, 24 h. This interaction was found to be helpful for IL displacement of the water molecules within agar gel. From this study, it was found that the exact morphology of gel materials in FE-SEM condition can be observed by optimization of water concentrations of IL and gel mixtures. Thus, using IL, agar gel or any other material under wet condition can be observed without drying in FE-SEM chamber, and, present result gives an insight to the mechanism of FE-SEM observation of agar gel using IL without any conducting coating.
Adsorption Characteristics of Water and Silica Gel System for Desalination Cycle
Cevallos, Oscar R.
2012-07-01
An adsorbent suitable for adsorption desalination cycles is essentially characterized by a hydrophilic and porous structure with high surface area where water molecules are adsorbed via hydrogen bonding mechanism. Silica gel type A++ possesses the highest surface area and exhibits the highest equilibrium uptake from all the silica gels available in the market, therefore being suitable for water desalination cycles; where adsorbent’s adsorption characteristics and water vapor uptake capacity are key parameters in the compactness of the system; translated as feasibility of water desalination through adsorption technologies. The adsorption characteristics of water vapor onto silica gel type A++ over a temperature range of 30 oC to 60 oC are investigated in this research. This is done using water vapor adsorption analyzer utilizing a constant volume and variable pressure method, namely the Hydrosorb-1000 instrument by Quantachrome. The experimental uptake data is studied using numerous isotherm models, i. e. the Langmuir, Tóth, generalized Dubinin-Astakhov (D-A), Dubinin-Astakhov based on pore size distribution (PSD) and Dubinin-Serpinski (D-Se) isotherm for the whole pressure range, and for a pressure range below 10 kPa, proper for desalination cycles; isotherms type V of the International Union of Pure and Applied Chemistry (IUPAC) classification were exhibited. It is observed that the D-A based on PSD and the D-Se isotherm models describe the best fitting of the experimental uptake data for desalination cycles within a regression error of 2% and 6% respectively. All isotherm models, except the D-A based on PSD, have failed to describe the obtained experimental uptake data; an empirical isotherm model is proposed by observing the behavior of Tóth and D-A isotherm models. The new empirical model describes the water adsorption onto silica gel type A++ within a regression error of 3%. This will aid to describe the advantages of silica gel type A++ for the design of
DEFF Research Database (Denmark)
Bentzen, Thomas Ruby; Ratkovich, Nicolas Rios; Madsen, S.;
2012-01-01
Fouling is the main bottleneck of the widespread use of MBR systems. One way to decrease and/or control fouling is by process hydrodynamics. This can be achieved by the increase of liquid cross- ﬂow velocity. In rotational cross-ﬂow MBR systems, this is attained by the spinning of, for example, i......-weighted average shear stress was developed for water and AS as a function of the angular velocity and the total suspended solids concentration. These relationships can be linked to the energy consumption of this type of systems.......Fouling is the main bottleneck of the widespread use of MBR systems. One way to decrease and/or control fouling is by process hydrodynamics. This can be achieved by the increase of liquid cross- ﬂow velocity. In rotational cross-ﬂow MBR systems, this is attained by the spinning of, for example......, impellers. Validation of the CFD (computational ﬂuid dynamics) model was made against laser Doppler anemometry (LDA) tangential velocity measurements (error less than 8%) using water as a ﬂuid. The shear stress over the membrane surface was inferred from the CFD simulations for water. However, activated...
Khurana, Meenakshi; Rana, Puneet; Srivastava, Sangeet
2016-12-01
In the present paper, we present both linear and nonlinear analyses to investigate thermal instability on a rotating non-Newtonian viscoelastic nanofluid layer under the influence of a magnetic field. In the linear stability analysis, the stationary and oscillatory modes of convection are obtained for various controlling parameters using the normal mode technique. Both Nusselt and Sherwood numbers are calculated after employing the minimal truncated Fourier series to steady and unsteady state. The main findings conclude that rotation and strain retardation parameter increase the value of the critical Rayleigh number in the neutral stability curve which delays the onset of convection in the nanofluid layer while the stress relaxation parameter enhances the convection. The magnetic field stabilizes the system for low values of the Taylor number (rotation) but an inverse trend is observed for high Taylor number. Both Nusselt and Sherwood numbers initially oscillate with time until the steady state prevails and they decrease with both Chandrasekhar and Taylor numbers. The magnitude of the streamlines and the contours of both isotherms and iso-nanohalines concentrate near the boundaries for large values of Ra, indicating an increase in convection.
Energy Technology Data Exchange (ETDEWEB)
Guerrero, H; Charles Crawford, C; Mark Fowley, M
2008-08-07
Gas holdup tests were performed in bench-scale and small-scale mechanically-agitated mixing systems at the Savannah River National Laboratory (SRNL) for a simulant of waste from the Hanford Tank 241-AZ-101. These featured additions of DOW Corning Q2-3183A anti-foam agent. Results indicated that this anti-foam agent (AFA) increased gas holdup in the waste simulant by about a factor of four and, counter-intuitively, that the holdup increased as the non-newtonian simulant shear strength decreased (apparent viscosity decreased). Such results raised the potential of increased flammable gas retention in Hanford Waste Treatment and Immobilization Plant (WTP) vessels mixed by air sparging and pulse-jet mixers (PJMs) during a Design Basis Event (DBE). Additional testing was performed to determine the effects of simulant properties, composition of alternate AFAs, and presence of trace noble metals. Key results are that: (1) Increased gas holdup resulting from addition of Q2-3183A is due to a decrease in surface tension that supports small bubbles which have low rise velocities. (2) Dow Corning 1520-US AFA shows it to be a viable replacement to Dow Corning Q2-3183A AFA. This alternative AFA, however, requires significantly higher dosage for the same anti-foam function. (3) Addition of noble metals to the AZ-101 waste simulant does not produce a catalytic gas retention effect with the AFA.
Directory of Open Access Journals (Sweden)
M. Umamaheswar
2016-09-01
Full Text Available A numerical investigation is carried out on an unsteady MHD free convection flow of a well-known non-Newtonian visco elastic second order Rivlin-Erickson fluid past an impulsively started semi-infinite vertical plate in the presence of homogeneous chemical reaction, thermal radiation, thermal diffusion, radiation absorption and heat absorption with constant mass flux. The presence of viscous dissipation is also considered at the plate under the influence of uniform transverse magnetic field. The flow is governed by a coupled nonlinear system of partial differential equations which are solved numerically by using finite difference method. The effects of various physical parameters on the flow quantities viz. velocity, temperature, concentration, Skin friction, Nusselt number and Sherwood number are studied numerically. The results are discussed with the help of graphs. We observed that the velocity decreases with an increase in magnetic field parameter, Schmidt number, and Prandtl number while it increases with an increase in Grashof number, modified Grashof number, visco-elastic parameter and Soret number. Temperature increases with an increase in radiation absorption parameter, Eckert number and visco-elastic parameter while it decreases with increasing values of radiation parameter, Prandtl number and heat absorption parameter. Concentration increases with increase in Soret number while it decreases with an increase in Schmidt number and chemical reaction parameter.
Almazmumy, Mariam; Ebaid, Abdelhalim
2017-08-01
In this article, the flow and heat transfer of a non-Newtonian nanofluid between two coaxial cylinders through a porous medium has been investigated. The velocity, temperature, and nanoparticles concentration of the present mathematical model are governed by a system of nonlinear ordinary differential equations. The objective of this article is to obtain new exact solutions for the temperature and the nanoparticles concentration and, therefore, compare them with the previous approximate results in the literature. Moreover, the velocity equation has been numerically solved. The effects of the pressure gradient, thermophoresis, third-grade, Brownian motion, and porosity parameters on the included phenomena have been discussed through several tables and plots. It is found that the velocity profile is increased by increasing the pressure gradient parameter, thermophoresis parameter (slightly), third-grade parameter, and Brownian motion parameter (slightly); however, it decreases with an increase in the porosity parameter and viscosity power index. In addition, the temperature and the nanoparticles concentration reduce with the strengthen of the Brownian motion parameter, while they increase by increasing the thermophoresis parameter. Furthermore, the numerical solution and the physical interpretation in the literature for the same problem have been validated with the current exact analysis, where many remarkable differences and errors have been concluded. Therefore, the suggested analysis may be recommended with high trust for similar problems.
Matthys, E. F.
The convective heat transfer, friction, and rheological properties of various types of nonNewtonian fluid in circular tube flows were investigated. If an apparent Reynolds number is used and if the temperature and degradation effects are properly taken into account, the reduced turbulent friction and heat transfer results, respectively, are then shown to be well correlated by the same expressions for different fluids, regardless of the nature of the fluids and whether they are shear-thinning or shear-thickening. This representation can also separate the reductions in turbulent heat transfer and friction that are induced by viscoelasticity from those induced by pseudoplasticity. Polyacrylamide solutions inducing asymptotic and intermediate drag reduction regimes were investigated over a broad range of Reynolds numbers. A kerosene-based antimisting polymer solution was also studied. Suspensions of bentonite of various concentrations were investigated in laminar and turbulent regimes, and the results for fully developed and entrance flows were well correlated by Newtonian relationships when an adequate wall viscosity concept was used.
Directory of Open Access Journals (Sweden)
Rahman Abdel-Gamal M.
2013-01-01
Full Text Available The unsteady flow and heat transfer in an incompressible laminar, electrically conducting and non-Newtonian fluid over a non-isothermal stretching sheet with the variation in the viscosity and thermal conductivity in a porous medium by the influence of an external transverse magnetic field have been obtained and studied numerically. By using similarity analysis the governing differential equations are transformed into a set of non-linear coupled ordinary differential equations which are solved numerically. Numerical results were presented for velocity and temperature profiles for different parameters of the problem as power law parameter, unsteadiness parameter, radiation parameter, magnetic field parameter, porous medium parameter, temperature buoyancy parameter, Prandtl parameter, modified Eckert parameter, Joule heating parameter , heat source/sink parameter and others. A comparison with previously published work has been carried out and the results are found to be in good agreement. Also the effects of the pertinent parameters on the skin friction and the rate of heat transfer are obtained and discussed numerically and illustrated graphically.
Shintaku, Hirofumi; Yonemura, Tsubasa; Tsuru, Kazuaki; Isoyama, Takashi; Yambe, Tomoyuki; Kawano, Satoyuki
In this study, we construct an experimental apparatus for a prototype artificial heart and lung (AHL) by installing hollow fibers into the cylindrical tube of the vibrating flow pump (VFP). The oxygenation characteristics are investigated both by experiments using bovine blood and by numerical analyses based on the computational fluid dynamics. The analyses are carried out at the Reynolds numbers Re ranged from O(1) to O(103), which are determined based on the experimental conditions. The blood flow and the diffusion of oxygen gas are analyzed based on the Newtonian/non-Newtonian, unsteady, incompressible and axisymmetric Navier-Stokes equations, and the advection-diffusion equation. The results show that the oxygenation rate increases in proportion to Re1/3, where the phenomenon corresponds to the decreasing thickness of the concentration boundary layer with Re. Although the effects of the vibrating flow and the rheology of the blood are clearly appeared on the velocity field, their effects on the gas exchange are relatively small at the ranges of prescribed Reynolds numbers. Furthermore, the numerical results in terms of the oxygenation rate are compared with the experimental ones. The basic design data of VFP were accumulated for the development of AHL in the clinical applications.
Energy Technology Data Exchange (ETDEWEB)
Herranz, M.; Pinilla, J. L.; Alegria, N.; Idoeta, R.; Legarda, F.
2011-07-01
Among the various sampling systems tritium content in the atmosphere as water vapor, one of the most basic and, therefore, of widespread use in the environmental field, is the retention on silica gel. However, the behavior of the collection efficiency of silica gel under varying conditions of air temperature and relative humidity makes it difficult to define the amount of this necessary for proper completion of sampling, especially in situations of prolonged sampling. This paper presents partial results obtained in a study on the analysis of these efficiencies under normal conditions of sampling. (Author)
Thermal properties and water repellency of cotton fabric prepared through sol-gel method
Directory of Open Access Journals (Sweden)
Gu Jia-Li
2016-01-01
Full Text Available Cotton fabrics were treated by one-step sol-gel method. The pure silica hydrosol and phosphorus-doped hydrosol were prepared with the addition of a hydrophobic hexadecyltrimethoxysilane to decrease the surface energy of cotton fabric. The thermal properties and water repellency of treated cotton fabric were characterized by thermo-gravimetric analysis, micro combustion, limiting oxygen index, and contact angle measurement. The results showed that cotton fabric treated by phosphorus-doped silica hydrosol had excellent flame retardance, and the water repellence was apparently improved with the addition of hexadecyltrimethoxysilane.
Sun, Yan; Chen, Jing; He, An-qi; Huang, Kun; Yu, Lei; Liu, Cui-ge; Wei, Yong-ju; Zhai, Yan-jun; Xu, Yi-zhuang; Wu, Jin-guang
2010-10-01
Gels are gaining extensive interest owing to their versatile applications in fields such as drug delivery, tissue engineering, cosmetics, templated materials and food industry. Surfactants have an ability to self-assemble into a variety of supramolecular aggregate structures and morphologies. Of particular interest in resent years are surfactant-based gels, one special class of materials due to surfactant assemblies resulting in viscoelastic solid-like rheological behaviors. Up to now, there is only limited understanding on the mechanism of gel formation, especially on the interaction among water, organic solvents and surfactant during thegel formation. In this study we prepare a Low-molecule-gel that is composed of cetyl trimethyl ammonium bromide (CTAB), water and carbon tetrachloride. Based on the experimental result of XRD and titration, the authors find that CTAB in gel are more than in saturated CTAB solution but CTAB is not solide in gel. CTAB is not solvented in CCl4. The solubility of CTAB in saturated CTAB solution is limited. So the authors suppose that CTAB is a synergistically solubilized by water and CCl4 in the gel. In addition, both NMR and FTIR spectroscopic results demonstrate that CTAB cations form a quasi-ordered structure in the gel.
Rheology of the gel formed in the California Mastitis Test.
Verbeek, C Johan R; Xia, Stephen S; Whyte, David
2008-11-01
The California Mastitis Test has previously been adapted for use in an inline, cow-side sensor and relies on the fact that the viscosity of the gel formed during the test is proportional to the somatic cell concentration. In this paper, the use of capillary and rotational viscometry was compared in light of the expected rheology of the gel formed during the test. It was found that the gel is non-Newtonian, but the initial phase of viscosity increase was not due to shear dependence, but rather due to the gelation reaction. The maximum apparent viscosity of the gel was shear dependent while the time it took to reach the maximum was not truly shear dependent, but was rather dependent on the degree of mixing during gelation. This was confirmed by introducing a delay time prior to viscosity measurement, in both capillary and rotational viscometry. It was found that by mixing the reagent and infected milk, then delaying viscosity measurement for 30 s, shortened the time it took to reach maximum viscosity by more than 60 s. The maximum apparent viscosity, however, was unaffected. It was found that capillary viscometry worked well to correlate relative viscosity with somatic cell count, but that it was sensitive to the reagent concentration. It can therefore be deduced that the rheology of the gel is complicated not only by it being non-Newtonian, but also by the strong dependence on test conditions. These make designing a successful sensor much more challenging.
Energy Technology Data Exchange (ETDEWEB)
Lee, Sang Hyuk; Girault, Hubert H.; Lee, Hye Jin [Kyungpook National Univ., Daegu (Korea, Republic of); Kim, Hyungi [Gyeongbuk Technopark, Gyeongsan (Korea, Republic of); Girault, Hubert H. [Ecole Polytechnique Federale de Lausanne, Lausanne (Switzerland)
2013-09-15
A novel stick-shaped portable sensing device featuring a microhole array interface between the polyvinylchloride-2-nitrophenyloctylether (PVC-NPOE) gel and water phase was developed for in-situ sensing of perchlorate ions in real water samples. Perchlorate sensitive sensing responses were obtained based on measuring the current changes with respect to the assisted transfer reaction of perchlorate ions by a perchlorate selective ligand namely, bis(dibenzoylmethanato)Ni(II) (Ni(DBM){sub 2}) across the polarized microhole array interface. Cyclic voltammetry was used to characterize the assisted transfer reaction of perchlorate ions by the Ni(DBM){sub 2} ligand when using the portable sensing device. The current response for the transfer of perchlorate anions by Ni(DBM){sub 2} across the micro-water/gel interface linearly increased as a function of the perchlorate ion concentration. The technique of differential pulse stripping voltammetry was also utilized to improve the sensitivity of the perchlorate anion detection down to 10 ppb. This was acquired by preconcentrating perchlorate anions in the gel layer by means of holding the ion transfer potential at 0 mV (vs. Ag/AgCl) for 30 s followed by stripping the complexed perchlorate ion with the ligand. The effect of various potential interfering anions on the perchlorate sensor was also investigated and showed an excellent selectivity over Br{sup -}, NO{sub 2}{sup -}, NO{sub 3}{sup -}, CO{sub 3}{sup 2-}, CH{sub 3}COO{sup -} and SO{sub 4}{sup 2-} ions. As a final demonstration, some regional water samples from the Sincheon river in Daegu city were analyzed and the data was verified with that of ion chromatography (IC) analysis from one of the Korean-certified water quality evaluation centers.
DEVELOPMENT OF POLYMER GEL SYSTEMS TO IMPROVE VOLUMETRIC SWEEP AND REDUCE PRODUCING WATER/OIL RATIOS
Energy Technology Data Exchange (ETDEWEB)
G. Paul Willhite; Don W. Green; Stan McCool; Min Cheng; Feiyan Chen
2004-02-01
The objectives of the research are to improve the effectiveness of polymer gels to increase volumetric sweep efficiency of fluid displacement processes and to reduce water production in production wells. The research is based on experimental data and conceptual and mathematical models developed from interpretation of experimental data. This report describes two types of mathematical models that were developed. One model type simulates the chemical reactions where polymer molecules are crosslinked to form a 3-dimensional network or gel. The model is based on statistical probabilities of reactions and yields molecular weights averages and distributions as functions of conversion. The second model type simulates the transport of chromium acetate, a common polymer crosslinker, through porous dolomite rock and includes the mechanisms of dolomite dissolution and chromium precipitation. The chromium transport model reasonably agreed with experimental data.
Water jet with adjunct chlorhexidine gel for nonsurgical treatment of peri-implantitis.
Levin, Liran; Frankenthal, Shai; Joseph, Livia; Rozitsky, Doron; Levi, Guy; Machtei, Eli E
2015-02-01
Peri-implant disease following successful integration of an endosseous implant is the result of an imbalance between bacterial load and host defense, which may affect not only the peri-implant mucosa but also involve the supporting bone. The aim of this study was to evaluate the adjunctive effect of a dental water jet rinse mixed with chlorhexidine gel to the nonsurgical treatment for peri-implantitis. A prospective randomized interventional cohort study was conducted. Forty consecutive patients presenting with peri-implantitis were recruited and randomly assigned into two treatment groups. Initially all patients received scaling/surface debridement and oral hygiene instruction. Patients in the study group received a water jet device containing chlorhexidine gel (Silonite®) for home use twice daily while the control group performed the recommended oral hygiene measures with no water jet usage. Three months following baseline visit, patients were reevaluated clinically and radiographically. In total, 39 patients completed the study and were available for final examination. Three months following baseline visit the test group exhibited greater mean probing depth reduction (0.75 mm vs 0.27 mm; P = .029) as well as greater reduction in the number of sites presenting with bleeding on probing (2.26 vs 0.45 sites; P = .011). No significant change in bone level was observed at 3 months (mean bone gain was 0.18 mm). Water jet mixed with chlorhexidine gel might supplement the response to nonsurgical treatment for peri-implantitis lesions. Further, larger-cohort studies are warranted.
Sliding behavior of water drops on sol-gel derived hydrophobic silica films
Energy Technology Data Exchange (ETDEWEB)
Latthe, Sanjay S.; Dhere, Sunetra L. [Air Glass Laboratory, Department of Physics, Shivaji University, Kolhapur 416 004, Maharashtra (India); Kappenstein, Charles [University of Poitiers, Laboratory of Catalysis in Organic Chemistry, LA CCO, UMR CNRS 6503, Poitiers-86000 (France); Imai, Hiroaki [Faculty of Science and Technology, Keio University, 3-14-1, Hiyoshi, Kohoku-ku, Yokohama 223-8522 (Japan); Ganesan, V. [CSR, Indore Centre, University Campus, Khandwa Road, Indore- 452 017, Madhyapradesh (India); Rao, A. Venkateswara, E-mail: avrao2012@gmail.com [Air Glass Laboratory, Department of Physics, Shivaji University, Kolhapur 416 004, Maharashtra (India); Wagh, Pratap B.; Gupta, Satish C. [Applied Physics Division, Bhabha Atomic Research Centre (BARC), Trombay, Mumbai 400 085 (India)
2010-03-01
Control on the wettability of solid state materials is a classical and key issue in surface engineering. Optically transparent methyltriethoxysilane (MTES)-based silica films with water sliding angle as low as 9{sup o} were successfully prepared by two-step sol-gel co-precursor method. The emphasis is given to the effect of trimethylethoxysilane (TMES) as a co-precursor on water sliding behavior of silica films. The coating sol was prepared with molar ratio of methyltriethoxysilane (MTES), methanol (MeOH), acidic water (0.01 M, oxalic acid) and basic water (12 M, NH{sub 4}OH) kept constant at 1:12.73:3.58:3.58 respectively, and the molar ratio of TMES/MTES (M) was varied from 0 to 0.22. The static water contact angle as high as 120{sup o} and the water sliding angle as low as 9{sup o} was obtained by keeping the molar ratio (M) of TMES/MTES at 0.22. When the modified films were cured at temperature higher than 280 deg. C, the films became superhydrophilic. Further, the humidity study was carried out at a relative humidity of 90% at 30 deg. C over 60 days. We characterized the water repellent silica films by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), % of optical transmission, humidity tests and static and dynamic water contact angle (CA) measurements.
Rheology of the gelation process of silica gel
Filho, O. K.; Aegerter, Michel A.
1988-01-01
The rheology of silica sols prepared from mixtures of tetramethoxysilane (TMOS)-methanol-water under basic neutral conditions has been studied at 25, 40 and 60 ° C during the gelation process. The sols show non-Newtonian pseudoplastic behavior from the time of preparation with the appearance of yield stress near the gelation point. The results are analysed using rheological equations of state and the concept of the point of gelation is discussed. For neutral sols an apparent activation energy...
Infrared intensity of 1-monolaurin-water systems in the gel phase
Kanesaka, Isao; Ishizaka, Makiko; Shimizu, Kunihiko
2000-11-01
The infrared spectra of 1-monolaurin-water systems, where KSCN is added as the intensity standard, were observed and the infrared intensity of the bands due to acyl groups measured relatively to that of the CN stretching. The infrared intensities of the bands parallel and perpendicular to the paraffin chains decrease and increase, respectively, on going from the crystalline β phase to the gel phase, confirming that these intensity changes result from the long-range interaction among oscillating dipoles. The infrared spectra with no CH 2 rocking and the splitting of the CH 2 rocking are also discussed with the same interaction model.
Water-based thixotropic polymer gel electrolyte for dye-sensitized solar cells.
Park, Se Jeong; Yoo, Kichoen; Kim, Jae-Yup; Kim, Jin Young; Lee, Doh-Kwon; Kim, Bongsoo; Kim, Honggon; Kim, Jong Hak; Cho, Jinhan; Ko, Min Jae
2013-05-28
For the practical application of dye-sensitized solar cells (DSSCs), it is important to replace the conventional organic solvents based electrolyte with environmentally friendly and stable ones, due to the toxicity and leakage problems. Here we report a noble water-based thixotropic polymer gel electrolyte containing xanthan gum, which satisfies both the environmentally friendliness and stability against leakage and water intrusion. For application in DSSCs, it was possible to infiltrate the prepared electrolyte into the mesoporous TiO2 electrode at the fluidic state, resulting in sufficient penetration. As a result, this electrolyte exhibited similar conversion efficiency (4.78% at 100 mW cm(-2)) and an enhanced long-term stability compared to a water-based liquid electrolyte. The effects of water on the photovoltaic properties were examined elaborately from the cyclic voltammetry curves and impedance spectra. Despite the positive shift in the conduction band potential of the TiO2 electrode, the open-circuit voltage was enhanced by addition of water in the electrolyte due to the greater positive shift in the I(-)/I3(-) redox potential. However, due to the dye desorption and decreased diffusion coefficient caused by the water content, the short-circuit photocurrent density was reduced. These results will provide great insight into the development of efficient and stable water-based electrolytes.
Study of a novel silica gel-water adsorption chiller. Part II. Experimental study
Energy Technology Data Exchange (ETDEWEB)
Wang, D.C.; Wu, J.Y.; Xia, Z.Z.; Zhai, H.; Wang, R.Z. [Institute of Refrigeration and Cryogenics, Shanghai Jiaotong University, Shanghai 200030 (China); Dou, W.D. [Jiangsu Shuangliang Air Conditioning Equipment Co., Ltd, Jiangsu 214444 (China)
2005-11-01
The prototype of a novel silica gel-water adsorption chiller is built and its performance is tested in detail. The experimental results show that the refrigerating capacity (RC) and COP of the chiller are 7.15 and 0.38kW, respectively, when the hot water temperature is 84.8{sup o}C, the cooling water temperature is 30.6{sup o}C, and the chilled water outlet temperature is 11.7{sup o}C. The RC will reach 6kW under the condition of 65{sup o}C hot water temperature, 30.5{sup o}C cooling water temperature and 17.6{sup o}C chilled water temperature. The results confirm that this kind of adsorption chiller is an effective refrigerating machine though its performance is not as fine as the prediction results. Also it is well effectively driven by a low-grade heat source. Therefore, its applications to the low-grade heat source are much attractive. (author)
Augmentation of Cooling Output by Silica Gel-Water Adsorption Cycle Utilizing the Waste Heat of GHP
Homma, Hiroki; Araki, Nobuyuki
The GHP (Gas engine Heat Pump) system is expected to have high energy-efficiency in utilizing the waste heat exhausted from a gas engine. In summer season, a silica gel-water adsorption cooling unit driven by the exhaust heat is considered as a cooling system for saving energy. In this work, an attempt was made to improve the COP of a silica gel-water adsorption cooling system by enhancing heat and mass transfer in the silica gel adsorption layer. A unit cell was introduced as a simplified model of adsorber for analyzing the phenomena of heat and mass transfer in the adsorbent. This cell was composed of a single tube with a silica gel layer bonded on its external surface. Optimization of heat and mass transfer characteristics for the unit cell was carried out by experimental and analytical approach.
Institute of Scientific and Technical Information of China (English)
WANG Dechang; WU Jingyi; WANG Ruzhu; DOU Weidong
2007-01-01
A novel silica gel-water adsorption chiller consisting of two adsorption/desorption chambers and an evaporator with one heat-pipe working chamber is experimentally studied.The dynamic operating characteristics of the chiller and the thermodynamic characteristics of the adsorber are obtained.The experimental results show that the dynamic operating characteristics of the chiller and the thermodynamic characteristics of the adsorber are satisfactory and that the cycle is a novel and effective adsorption cycle.A mass recovery process increases the cyclic adsorption capacity of the system and improves adaptability of the chiller to a lowgrade heat source.In addition,the experiment indicates that this novel chiller is highly suitable for an air conditioning system with a low dehumidification requirement or a system with a large cycle flowrate and an industrial cooling water system.
An edible, gelatinous water-insoluble coating surrounds the young leaves of the water plant, Brasenia schreberi. This mucilage is a polysaccharide of galactose, mannose, fucose and other monosaccharides. In order to determine if this edible gel has cholesterol lowering properties, we fed male hams...
Wang, Lixia; Zhuang, Yuanhong; Li, Jingliang; Pang, Jie; Liu, Xiangyang
2016-12-01
Konjac glucomannan - tungsten (KGM-T) gels were successfully prepared under DC electric fields, in the presence of sodium tungstate. The textural properties and microstructure of the gels were investigated by Texture Analyzer, Rheometer and SEM. Based on the response surface methodology (RSM) results, the optimum conditions for KGM-T gel springiness is 0.32% sodium tungstate concentration, 0.54% KGM concentration, 24.66V voltage and 12.37min treatment time. Under these conditions, the maximum springiness value of KGM-T gel is 1.21mm. Steady flow measurement indicated that KGM-T gel showed characteristic non-Newtonian pseudoplastic behaviour, with low flow behaviour indexes in the shear thinning region. SEM demonstrated the porosity of the freeze-dried samples. These findings may pave the way to use DC electric fields for the design and development of KGM gels and to apply KGM gels for practical applications.
Alam, Mohammad Mydul; Ushiyama, Kousuke; Aramaki, Kenji
2009-01-01
We investigated the phase behavior, formation, and rheology of the cubic phase (I(1)) and related O/I(1) gel emulsion in water/Tween 80/oil systems using squalane, liquid paraffin (LP), and decane as oil components. In the phase behavior study, the phase sequences were similar for squalane and LP systems, while a lamellar liquid crystal (L(alpha)) was observed for decane system. In all the systems the addition of oil to W(m) or H(1) phase induced the I(1) phase, which can solubilize some amounts of oil followed by the appearance of I(1)+O phase. The formation of the O/I(1) gel emulsion has been studied at a fixed w/s (50/50) and we found that 30 wt% decane, 70 wt% squalane, and 60 wt% LP can form the gel emulsion. The water/Tween 80/squalane system has been taken as a model system to study viscoelastic properties of the I(1) phase and O/I(1) gel emulsion. The I(1) phase shows a typical hard gel cubic structure under the frequency and the values of the complex viscosity, /eta*/ and the elastic modulus, G ' increase with the addition of squalane, which could be due to the neighboring micellar interaction. On the other hand, the decreasing values of the viscoelastic parameters in the O/I(1) gel emulsion simply relate to the volume fraction of the I(1) phase in the system.
Water repellent porous silica films by sol-gel dip coating method.
Rao, A Venkateswara; Gurav, Annaso B; Latthe, Sanjay S; Vhatkar, Rajiv S; Imai, Hiroaki; Kappenstein, Charles; Wagh, P B; Gupta, Satish C
2010-12-01
The wetting of solid surfaces by water droplets is ubiquitous in our daily lives as well as in industrial processes. In the present research work, water repellent porous silica films are prepared on glass substrate at room temperature by sol-gel process. The coating sol was prepared by keeping the molar ratio of methyltriethoxysilane (MTES), methanol (MeOH), water (H(2)O) constant at 1:12.90:4.74, respectively, with 2M NH(4)OH throughout the experiments and the molar ratio (M) of MTES/Ph-TMS was varied from 0 to 0.22. A simple dip coating technique is adopted to coat silica films on the glass substrates. The static water contact angle as high as 164° and water sliding angle as low as 4° was obtained for silica film prepared from M=0.22. The surface morphological studies of the prepared silica film showed the porous structure with pore sizes typically ranging from 200nm to 1.3μm. The superhydrophobic silica films prepared from M=0.22 retained their superhydrophobicity up to a temperature of 285°C and above this temperature the films became superhydrophilic. The porous and water repellent silica films are prepared by proper alteration of the Ph-TMS in the coating solution. The prepared silica films were characterized by surface profilometer, scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier Transform Infrared (FT-IR) spectroscopy, humidity tests, chemical aging tests, static and dynamic water contact angle measurements.
Theoretical study of simultaneous water and VOCs adsorption and desorption in a silica gel rotor
DEFF Research Database (Denmark)
Zhang, G.; Zhang, Y.F.; Fang, Lei
2008-01-01
One-dimensional partial differential equations were used to model the simultaneous water and VOC (Volatile Organic Compound) adsorption and desorption in a silica gel rotor which was recommended for indoor air cleaning. The interaction among VOCs and moisture in the adsorption and desorption...... by the temperatures of the rotor and the air stream. The VOC transfer equations were solved by discretizing them into explicit up-wind finite differential equations. The model was validated with experimental data. The calculated results suggested that the regeneration time designed for dehumidification may...... process was neglected in the model as the concentrations of VOC pollutants in typical indoor environment were much lower than that of moisture and the adsorbed VOCs occupied only a minor portion of adsorption capacity of the rotor. Consequently VOC transfer was coupled with heat and moisture transfer only...
Study of Solar Driven Silica gel-Water based Adsorption Chiller
Habib, K.; Assadi, M. K.; Zainudin, M. H. B.
2015-09-01
In this study, a dynamic behaviour of a solar powered single stage four bed adsorption chiller has been analysed designed for Malaysian climate. Silica gel and water have been used as adsorbent-refrigerant pair. A simulation program has been developed for modeling and performance evaluation of the chiller using the meteorological data of Kuala Lumpur. The optimum cooling capacity and coefficient of performance (COP) are calculated in terms of adsorption/desorption cycle time and regeneration temperature. Results indicate that the chiller is feasible even when low temperature heat source is available. Results also show that the adsorption cycle can achieve a cooling capacity of 14 kW when the heat source temperature is about 85°C.
Jeong, Hye-Jeong; Kim, Dong-Kwon; Lee, Soo-Bok; Kwon, Soo-Han; Kadono, Kohei
2001-03-01
Coating films on glass substrate were prepared by sol-gel process using alkoxide solutions containing perfluoroalkylsilane (PFAS) and tetraethoxysilane (TEOS). The physical properties of the coating films were characterized by SEM, FT-IR, and XRD. And their surface properties were investigated by measuring contact angles and atomic compositions. Transparent coating films with smooth surface and uniform thickness could be obtained. The contact angles of the coating films for water and methylene iodide are extremely high, at 118 degrees and 97 degrees, respectively, and their surface free energies are about 9.7 dyn/cm. It was found that the water-repellent glass prepared is very hydrophobic and exhibits excellent water-repellency. Hydrophobic perfluoroalkyl groups are preferentially enriched to the outermost layer at the coating film-air interface, and two layers probably exist in the coating film. The upper layer oriented toward the air is composed of mainly perfluoroalkyl groups originating from PFAS, and the lower layer is composed of mainly -OSiO- groups originating from TEOS. The heat treatment after drying step cannot influence the surface enrichment of the perfluoroalkyl group. The hydrolysis reaction should be more completely done before the dip coating step to obtain lower surface free energy. The burning temperature should be less than 300 degrees C because the perfluoroalkyl group begins to decompose from this temperature. Copyright 2001 Academic Press.
[Effect of water on silica gel adsorption of blood plasma components].
Gall', L N; Malakhova, M Ia; Melenevskaia, E Iu; Podosenova, N G; Sharonova, L V
2011-01-01
In this work, the study of properties of silica gel as an adsorbent for plasmasorption has been performed. Investigations have been realized of the effect of silica gel preliminary treatment conditions and a period of plasma with silica gel contact on plasmasorption characteristics of human blood plasma components, such as protein, triglycerides, cholesterol (high-density and low-density one). The results obtained can be used for variation of silica gel adsorption properties, in situ at the adsorbent preparation process. For explanation of the experimental concentration and kinetic (temporal) characteristics of plasmasorption, the model of silica gel grains charging at the hydration was used.
Tomsic, Matija; Prossnigg, Florian; Glatter, Otto
2008-06-01
Sol-gel and gel-sol thermal transition of methylcellulose/water, kappa-carrageenan/water and methylcellulose/kappa-carrageenan/water mixtures was investigated utilizing small-angle X-ray scattering (SAXS), differential scanning calorimetry (DSC) and oscillatory rheological experiments in temperature regime from 20 to 80 degrees C. Methylcellulose (E461) and kappa-carrageenan (E407) are well-known additives used for gelation in various nutrition and other products. The formulation and characterization of a mixed thermoreversible methylcellulose/kappa-carrageenan/water gel with very interesting double thermal transition gel-sol-gel upon heating was possible. This specific thermal behavior provides a liquid state of the system between the low-temperature and high-temperature gel-state and at the same time allows for the easy temperature tuning of the system's state. As such this system is suggested to be further tested as potential carrier for various functional colloidal systems.
Cheng, Chong Sage; Deng, Jie; Lei, Bei; He, Ai; Zhang, Xiang; Ma, Lang; Li, Shuang; Zhao, Changsheng
2013-12-15
Recent studies showed that graphene oxide (GO) presented high adsorption capacities to various water contaminants. However, the needed centrifugation after adsorption and the potential biological toxicity of GO restricted its applications in wastewater treatment. In this study, a facile method is provided by using biopolymers to mediate and synthesize 3D GO based gels. The obtained hybrid gels present well-defined and interconnected 3D porous network, which allows the adsorbate molecules to diffuse easily into the adsorbent. The adsorption experiments indicate that the obtained porous GO-biopolymer gels can efficiently remove cationic dyes and heavy metal ions from wastewater. Methylene blue (MB) and methyl violet (MV), two cationic dyes, are chosen as model adsorbates to investigate the adsorption capability and desorption ratio; meanwhile, the influence of contacting time, initial concentration, and pH value on the adsorption capacity of the prepared GO-biopolymer gels are also studied. The GO-biopolymer gels displayed an adsorption capacity as high as 1100 mg/g for MB dye and 1350 mg/g for MV dye, respectively. Furthermore, the adsorption kinetics and isotherms of the MB were studied in details. The experimental data of MB adsorption fitted well with the pseudo-second-order kinetic model and the Langmuir isotherm, and the results indicated that the adsorption process was controlled by the intraparticle diffusion. Moreover, the adsorption data revealed that the porous GO-biopolymer gels showed good selective adsorbability to cationic dyes and metal ions.
Energy Technology Data Exchange (ETDEWEB)
Khan, Asif Ali, E-mail: asifkhan42003@yahoo.com; Shaheen, Shakeeba, E-mail: shakeebashaheen@ymail.com
2014-01-15
Highlights: • PU–Si gel is new anion exchanger material synthesized and characterized. • This material used as anion exchange membrane is applied for electroanalytical studies. • The method for detection and determination of AsO{sub 4}{sup 3−} in traces amounts discussed. • The results are also verified from arsenic analyzer. -- Abstract: Polyurethane (PU)–silica (Si gel) based fibrous anion exchanger composites were prepared by solid–gel polymerization of polyurethane in the presence of different amounts of silica gel. The formation of PU–Si gel fibrous anion exchanger composite was characterized by Fourier transform infra-red spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA-DTA), scanning electron microscopy (SEM) and elemental analysis. The membrane having a composition of 5:3 (PU:Si gel) shows best results for water content, porosity, thickness and swelling. Our studies show that the present ion selective membrane electrode is selective for arsenic, having detection limit (1 × 10{sup −8} M to 1 × 10{sup −1} M), response time (45 s) and working pH range (5–8). The selectivity coefficient values for interfering ions indicate good selectivity for arsenate (AsO{sub 4}{sup 3−}) over interfering anions. The accuracy of the detection limit results was compared by PCA-Arsenomat.
Directory of Open Access Journals (Sweden)
Hu Jia
2016-03-01
Full Text Available Water shutoff in ultralow temperature reservoirs has received great attention in recent years. In previous study, we reported a phenol-formaldehyde-based gel formula with ammonium salt which can provide a gelation time between 2 hrs and 2 days at 25 °C. However, systematic evaluation and field recommendations of this gel formula when encountering complex reservoirs environment are not addressed. In this paper, how and why such practical considerations as water composition, temperature, pH, weight ratio of formaldehyde to resorcinol and contaminant Fe3+ to affect the gelation performance are examined. Brookfield DV-III and scanning electron microscopy (SEM are employed respectively for viscosity measurement and microstructure analysis. SEM results further illustrate the mechanism of the effect of salinity on gelation performance. It reveals that crosslinking done by covalent bond has great advantage for gel stability under high salinity environment. The target gel formula can provide desirable gelation time below 60 °C, perfect for 15–45 °C, while it is unfeasible to use high salinity to delay gelation at 60 °C. We summarized the effect of salinity on gelation performance of different gel formulas from the present study and published literature. The summarized data can provide important guideline for gel formula design before conducting any kinds of experiments. The variation of gelation performance at different salinity may be dominated by the interaction between crosslinker-salt-polymer, not only limited to “charge-screening effect” and “ion association” proposed by several authors. We hope the analysis encouraging further investigations. Some recommendations for field application of this gel are given in the end of this paper.
Goldaev, Sergey; Khushvaktov, Alisher
2015-01-01
A quantitative analysis of the diffusion model dehumidifying air in the steam circuit of TPP, with a layer of silica gel. Showed that such an approximation, supplemented the experimental value of the coefficient of free diffusion identified by the developed method gives reliable values for the concentration of water vapor absorption over time.
RADICAL GRAFTING REACTIONS ONTO STARCH AND OTHER WATER-SOLUBLE COPOLYMERS IN ISOLATED GEL DROPLETS
Institute of Scientific and Technical Information of China (English)
ZHANG Liansheng; A.F.Johnson
1993-01-01
A novel radical grafting copolymerization process has been designed for water-soluble polymers which avoids the problems of conducting grafting reactions in highly viscous polymerization media.A variety of water-soluble graft copolymers having starch or dextran as the backbone chain with grafted side chains of polyacrylamide (-AM-),poly (acrylic acid) (-AA-),poly (acrylamide-co-acrylic acid) (-AM-NH4AA-) or poly (acrylamide-co-2-acrylamido-2-methyl-1-propanesulphinic acid)(-AM-AMPS-) have been synthesized in gel droplets using a ceric sulphate redox initiator,and their properties compared.The reaction conditions were optimized taking into account reaction kinetic data and the observed properties of the products produced under different reaction conditions.The effects of the ratios of [backbone]/[graft monomer],[AM]/[AA]/[AMPS],[Ce4+]/[S2O8=] and pH value on the reaction rate,conversion,grafting degree,grafted chain length and the product molecular weight have been investigated.
有机凝胶控水及堵水技术研究%Research on Water Control and Water Shutoff Technologies of Organic-Gel
Institute of Scientific and Technical Information of China (English)
贾虎; 蒲万芬
2013-01-01
This paper gives an update review on the progress of researches on organic-gel used for water shutoff and confor-mance control. Five kinds of popular gel systems such as bulk gel,organosilicon gel,thermosensitive/salt-sensitive/pH sensitive gel,in-situ polymer gel and polymeric microsphere are included. This paper introduces the working mechanism,merits and demerits and field application of each gel system. Polyethyleneimine(PEI)cross-linking gel system has advantages of being low toxic,high-temperature and high salinity tolerant etc. This gel system can be used for water shutoff in hardness reservoirs. From the tendency of water control of chemical methods,synthesizing various functional polymeric microsphere which can match with pore throat will receive great attention in the next decades. This paper has achieved some research progress in organic-gel used for water shutoff and conformance control,which can offer favourable reference for related work and field application.%对国内外有机凝胶调剖堵水的研究成果进行了综述，从聚合物本体凝胶、有机硅凝胶、热/盐/pH敏感性凝胶、就地聚合凝胶以及聚合物微球五大类体系进行了阐述。介绍了各种体系的作用机理、优缺点和现场应用情况。其中聚乙烯亚胺（PEI）交联凝胶体系有低毒、抗温、抗盐等许多优点，可用于恶劣油藏堵水作业。从化学调剖堵水技术发展趋势来看，合成孔喉尺度匹配的各种功能性聚合物微球将是未来深部调驱技术的重点发展方向。在有机凝胶调剖堵水方面取得了一定的研究进展，将对今后相关研究工作和现场应用具有参考价值和指导意义。
Directory of Open Access Journals (Sweden)
Adriana Morales-Ortega
2014-03-01
Full Text Available Due to their porous structure, aqueous environment and dietary fiber nature arabinoxylan (AX gels could have potential applications for colon-specific therapeutic molecule delivery. In addition, prebiotic and health related effects of AX have been previously demonstrated. It has been also reported that cross-linked AX can be degraded by bacteria from the intestinal microbiota. However, AX gels have not been abundantly studied as carrier systems and there is no information available concerning their capability to entrap cells. In this regard, probiotic bacteria such as Bifidobacterium longum have been the focus of intense research activity lately. The objective of this research was to investigate the entrapment of probiotic B. longum in AX gels. AX solution at 2% (w/v containing B. longum (1 × 107 CFU/cm formed gels induced by laccase as cross-linking agent. The entrapment of B. longum decreased gel elasticity from 31 to 23 Pa, probably by affecting the physical interactions taking place between WEAX chains. Images of AX gels containing B. longum viewed under a scanning electron microscope show the gel network with the bacterial cells entrapped inside. The microstructure of these gels resembles that of an imperfect honeycomb. The results suggest that AX gels can be potential candidates for the entrapment of probiotics.
Preliminary study of sand jets in water-capped artificial and real MFT
Energy Technology Data Exchange (ETDEWEB)
Cai, J.; Zhu, D.; Rajaratnam, N. [Alberta Univ., Edmonton, AB (Canada). Dept. of Civil and Environmental Engineering
2008-07-01
A preliminary study of sand jets in water-capped artificial and real MFT was presented. Background information on oil sands tailing reclamation including water capping and sand capping were first discussed, followed by background information to the study, including non-Newtonian fluids and laponite clay, the artificial clay used mainly in small amounts as a rheology modifier in industrial fluids and materials. Although laponite clay is insoluble in water, it hydrates to make a clear and colourless colloidal, which is thixotropic and also behaves as a Bingham plastic fluid. The benefit of using gels made from laponite is the ability to see through to observe the physical processes in it. The objectives of the study were to examine the dynamics of sand jets in water-capped laponite gel and real MFT; improve the understanding of physical processes related to MFT and sand/slurry operations in tailings ponds; and find potential applications in recycling processed water and decommissioning of tailings ponds. It was concluded that it is much more difficult for jets to penetrate water-capped MFT due to larger yield stress in MFT. Future studies will focus on density correction, viscosity adjustment, and sensitivity analysis. tabs., figs.
Khan, Asif Ali; Shaheen, Shakeeba
2014-01-15
Polyurethane (PU)-silica (Si gel) based fibrous anion exchanger composites were prepared by solid-gel polymerization of polyurethane in the presence of different amounts of silica gel. The formation of PU-Si gel fibrous anion exchanger composite was characterized by Fourier transform infra-red spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA-DTA), scanning electron microscopy (SEM) and elemental analysis. The membrane having a composition of 5:3 (PU:Si gel) shows best results for water content, porosity, thickness and swelling. Our studies show that the present ion selective membrane electrode is selective for arsenic, having detection limit (1×10(-8)M to 1×10(-1)M), response time (45s) and working pH range (5-8). The selectivity coefficient values for interfering ions indicate good selectivity for arsenate (AsO4(3-)) over interfering anions. The accuracy of the detection limit results was compared by PCA-Arsenomat.
Static Analysis of Double Effect Adsorption Refrigeration Cycle Using Silica gel/Water Pair
Marlinda; Miyazaki, Takahiko; Ueda, Yuki; Akisawa, Atsushi
In this paper,a static analysis of double effect adsorption refrigeration cycle utilizing condensation heat is discussed. Double effect adsorption refrigeration cycle consists of two cycles, High Temperature Cycle (HTC) which is driven from external heat sources, and Low Temperature Cycle (LTC) which is driven by condensation heat from HTC. Both of HTC and LTC are using silica gel and water as working pairs. The effect of heat source temperature on cycle performance was investigated in terms of coefficient of performance (COP) and specific cooling energy (SCE). Results showed that double effect cycle would produce higher COP than single effect cycle for driving temperature observed between 80-150°C with the same operating condition. However, the value of SCE is lower than single effect, despite that the SCE of double effect cycle is improved with heat source temperature higher than 100°C. Further, it was also observed that adsorbent mass ratio of HTC and LTC affected performance of chiller. When adsorbent mass ratio of HTC and LTC was unity, it was found that SCE and COP took the maximum.
Computational Analysis of Silica gel-Water Adsorption Refrigeration Cycle with Mass Recovery
Akahira, Akira; Alam, K. C. Amanul; Hamamoto, Yoshinori; Akisawa, Atsushi; Kashiwagi, Takao
The study aims at clarifying the performance of silica gel-water adsorption refrigeration cycle with mass recovery process.Two kinds of heat exchanger were examined and the performances were compared with each other. One type of heat exchanger was a spiral tube and it was immersed in a low temperature thermostatic bath. The other was coil-shaped double tube heat exchanger using two tubes. The emulsion was circulated to make ice continuously. These systems were operated under various cooling conditions (flow rates of the emulsion and brine temperatures). The effects of the tube materials (fluororesin and non-fluororesin) and thickness were also examined. Slurry ice was formed continuously without adhesion of ice to the cooling wall under certain conditions. Using the fluororesin tube prevented ice from the adhesion and it enlarged the range of the cooling conditions under which slurry ice was formed continuously. Furthermore, by making thickness of the tube thinner and increasing the heat transfer coefficient on the outside of the tube, ice was made continuously without lowering the rate of ice formation at a higher brine temperature.
Mullite long fibres prepared by sol-gel method using water solvent systems
Energy Technology Data Exchange (ETDEWEB)
Okada, K.; Yasohama, S.; Hayashi, S.; Yasumori, A. [Tokyo Inst. of Tech. (Japan). Dept. of Inorganic Materials
1997-12-31
Mullite long fibres, which are a candidate for high temperature applications were prepared by sol-gel method from water solvent systems. They were synthesized from three different combinations of raw materials as follows: (1):Al(O{sub 1}C{sub 3}H{sub 7}){sub 3}, Al-nitrate and Si(OC{sub 2}H{sub 5}){sub 4} (TEOS), (2):Al metal, Al-chloride and TEOS, (3):Al metal, Al-nitrate and TEOS. In the methods (1) and (2), very fine SiO{sub 2} aerosol particles were also used partially replacing TEOS. The prepared solutions were condensed and examined the spinability by a hand drawing method. Dense and crack free mullite fibres were prepared from the methods (1) and (3) by firing up to 1100 C. Whereas the fibres prepared from the method (2) were less SiO{sub 2} than mullite composition and were porous by the firing due to evaporation of residual Cl ions at high temperature. (orig.) 10 refs.
Wang, Peng; Wei, Xiao-An; He, Weidong
2014-05-01
A water gel explosive using expired single-base propellant grains as the ingredient was prepared by a simple process coupled with a new gelling system. The thermal stability and output energy of the explosive were studied using an accelerating rate calorimeter (ARC) and underwater blast test, respectively. The effects of oxygen balance, shape and size of the propellant, and storage time on the output energy of the explosive were investigated. It is shown that the initial decomposition temperature of the explosive was 418.24 K under adiabatic conditions. The underwater output energy increased with the increase in the oxygen balance of the explosive. The mass fraction and specific surface area of the propellant had effects on the output energy of the explosive. In addition, this water gel explosive was proven to have a stable storage performance after it had been stored for 6 months.
Sol-Gel Derived Adsorbents with Enzymatic and Complexonate Functions for Complex Water Remediation
Directory of Open Access Journals (Sweden)
Roman P. Pogorilyi
2017-09-01
Full Text Available Sol-gel technology is a versatile tool for preparation of complex silica-based materials with targeting functions for use as adsorbents in water purification. Most efficient removal of organic pollutants is achieved by using enzymatic reagents grafted on nano-carriers. However, enzymes are easily deactivated in the presence of heavy metal cations. In this work, we avoided inactivation of immobilized urease by Cu (II and Cd (II ions using magnetic nanoparticles provided with additional complexonate (diethylene triamine pentaacetic acid or DTPA functions. Obtained nanomaterials were characterized by Fourier transform infrared spectroscopy (FTIR, thermogravimetric analysis (TGA, and scanning electron microscopy (SEM. According to TGA, the obtained Fe3O4/SiO2-NH2-DTPA nanoadsorbents contained up to 0.401 mmol/g of DTPA groups. In the concentration range Ceq = 0–50 mmol/L, maximum adsorption capacities towards Cu (II and Cd (II ions were 1.1 mmol/g and 1.7 mmol/g, respectively. Langmuir adsorption model fits experimental data in concentration range Ceq = 0–10 mmol/L. The adsorption mechanisms have been evaluated for both of cations. Crosslinking of 5 wt % of immobilized urease with glutaraldehyde prevented the loss of the enzyme in repeated use of the adsorbent and improved the stability of the enzymatic function leading to unchanged activity in at least 18 cycles. Crosslinking of 10 wt % urease on the surface of the particles allowed a decrease in urea concentration in 20 mmol/L model solutions to 2 mmol/L in up to 10 consequent decomposition cycles. Due to the presence of DTPA groups, Cu2+ ions in concentration 1 µmol/L did not significantly affect the urease activity. Obtained magnetic Fe3O4/SiO2-NH2-DTPA-Urease nanocomposite sorbents revealed a high potential for urease decomposition, even in presence of heavy metal ions.
Bernini, Roberta; Cacchi, Sandro; Fabrizi, Giancarlo; Forte, Giovanni; Petrucci, Francesco; Prastaro, Alessandro; Niembro, Sandra; Shafir, Alexandr; Vallribera, Adelina
2009-06-07
The utilization of perfluoro-tagged palladium nanoparticles immobilized on fluorous silica gel through fluorous-fluorous interactions (Pd(np)-/FSG) or linked to silica gel by covalent bonds (Pd(np)-) in the alkynylation of terminal alkynes with aryl halides under aerobic, copper- and phosphine-free conditions in water, and their recovery and re-utilization, is described.
Nakamura, Yukinobu; Migita, Koshiro; Okitani, Akihiro; Matsuishi, Masanori
2014-05-01
Water-holding capacity (WHC) of heat-induced pork gels was examined. The heat-induced gels were obtained from meat homogenates prepared by adding nine volumes of 0.3-0.5 mol/L NaCl solutions containing 9-36 mmol/L disodium inosine-5'-monophosphate (IMP) or 9 mmol/L tetrapotassium pyrophosphate (KPP) to minced pork. IMP at 36 mmol/L enhanced the WHC to the same level as attained by KPP. Physical and sensory properties of heat-induced gels were also examined. The heat-induced gels were prepared from porcine meat homogenates containing 0.3 mol/L NaCl and 9-36 mmol/L IMP or 9 mmol/L KPP. IMP at 36 mmol/L enhanced the values of hardness, cohesiveness, gumminess and springiness, measured with a Tensipresser, and several organoleptic scores to the same level as the score attained by KPP. Thus, it is concluded that IMP is expected to be a practical substitute for pyrophosphates to improve the quality of sausages.
Rafiee-Tehrani, M; Mehramizi, A
2000-04-01
The importance of piroxicam, a therapeutic anti-inflammatory drug, is well known. Because of gastrointestinal disorders, dermatological dosage forms are recommended most. In our first studies, oil-in-water (O/W) creams of piroxicam (1% concentration) were prepared using glyceryl monostearate (GMS), stearic acid, and triethanolamine as additive ingredients. In our second studies, hydroalcoholic transparent gel formulations of this drug in a 0.5% concentration were prepared using hydroxypropylcellulose (HPC) as the gelling agent. The release of piroxicam from all formulations via dialysis through a cellulose membrane into phosphate buffer pH 6.8 at 37 degrees C was studied. The effects of additives such as propylene glycol and 2-propanol on the drug release were also investigated. The release profiles from the standpoint of diffusion-controlled processes, as well as zero-order and first-order kinetics, were evaluated, and relevant parameters, such as diffusion coefficient, permeability coefficient, and partition coefficient, were calculated. The release obeys both the diffusion mechanism and first-order kinetics. The drug release from gel formulations containing 10%, 20%, and 30% propylene glycol was decreased due to the enhancement of viscosity. However, the limpidity of these formulations was improved. Moreover, the release of drug from gel formulations containing 15% and 20% of 2-propanol was increased. These results show that a hydroalcoholic gel formulation with HPC is a more suitable preparation of piroxicam when compared with an O/W cream formulation.
Directory of Open Access Journals (Sweden)
Yongpeng Sun
2017-07-01
Full Text Available Mature oilfields usually encounter the problem of high watercut. It is practical to use chemical methods for water-shutoff in production wells, however conventional water-shutoff agents have problems of long gelation time, low gel strength, and poor stability under low temperature and high salinity conditions. In this work a novel polymer gel for low temperature and high salinity reservoirs was developed. This water-shutoff agent had controllable gelation time, adjustable gel strength and good stability performance. The crosslinking process of this polymer gel was studied by rheological experiments. The process could be divided into an induction period, a fast crosslinking period, and a stable period. Its gelation behaviors were investigated in detail. According to the Gel Strength Code (GSC and vacuum breakthrough method, the gel strength was displayed in contour maps. The composition of the polymer gel was optimized to 0.25~0.3% YG100 + 0.6~0.9% resorcinol + 0.2~0.4% hexamethylenetetramine (HMTA + 0.08~0.27% conditioner (oxalic acid. With the concentration increase of the polymer gel and temperature, the decrease of pH, the induction period became shorter and the crosslinking was more efficient, resulting in better stability performance. Various factors of the gelation behavior which have an impact on the crosslinking reaction process were examined. The relationships between each impact factor and the initial crosslinking time were described with mathematical equations.
Institute of Scientific and Technical Information of China (English)
Zheng Haimin; Huang Qiyu; Wang Changhui; Wang Xi
2015-01-01
Some crude oils with high water cut have the capability to lfow below the oil gel point, while the oil particles ad-here to the pipe wall in the form of paste, also called “wall sticking”. Wall sticking is a serious problem during the pipeline transportation, leading to partial or total blockage of the pipeline and energy wastage. In this paper, a series of laboratory lfow loop experiments were conducted to observe the wall sticking characteristics of crude oil with high water cut, high viscosity and high gel point at low transportation temperatures. The effects of shear stress and water cut on the wall sticking rate and occurrence temperature were investigated. Experimental results indicated that the wall sticking rate and occurrence temperature were lower under stronger shear stress and higher water cut conditions. A criterion of wall sticking occurrence temperature (WSOT) and a regression model of wall sticking rate were then established. Finally, the software was developed to calculate the pressure drop along the pipelines of crude oils with high water-cut. It was able to predict the wall sticking thickness of gelled oil and then calculate the pressure drop along the pipelines. A typical case study indicated that the predic-tion results obtained from the software were in agreement with actual measured values.
Energy Technology Data Exchange (ETDEWEB)
Sadeghi, S. [Department of Chemistry, Faculty of Science, Birjand University, Birjand (Iran, Islamic Republic of)], E-mail: ssadeghi@birjand.ac.ir; Sheikhzadeh, E. [Department of Chemistry, Faculty of Science, Birjand University, Birjand (Iran, Islamic Republic of)
2009-04-30
Murexide was chemically bonded to silica gel surface immobilized 3-aminopropyl trimethoxysilane (APMS) to produce the new sorbent. A solid phase extraction method using the new sorbent has been developed to separate and concentrate trace amount of uranium (VI) from aqueous samples for the measurement by spectrophotometry method using Arsenazo III reagent. The influences of some analytical parameters on the quantitative recoveries of the analyte were investigated both in batch and column methods. Quantitative recovery of U(VI) was achieved by stripping with 0.1 mol L{sup -1} HCl. The maximum sorption capacity of the modified silica gel was 1.13 mmol g{sup -1} U(VI). A high preconcentration factor value of 400 with a lower limit of detection of 1 {mu}g L{sup -1} was obtained for U(VI). The practical applicability of the developed sorbent was examined using synthetic and real samples such as sea/ground water samples.
Sadeghi, S; Sheikhzadeh, E
2009-04-30
Murexide was chemically bonded to silica gel surface immobilized 3-aminopropyl trimethoxysilane (APMS) to produce the new sorbent. A solid phase extraction method using the new sorbent has been developed to separate and concentrate trace amount of uranium (VI) from aqueous samples for the measurement by spectrophotometry method using Arsenazo III reagent. The influences of some analytical parameters on the quantitative recoveries of the analyte were investigated both in batch and column methods. Quantitative recovery of U(VI) was achieved by stripping with 0.1 mol L(-1) HCl. The maximum sorption capacity of the modified silica gel was 1.13 mmol g(-1) U(VI). A high preconcentration factor value of 400 with a lower limit of detection of 1 microg L(-1) was obtained for U(VI). The practical applicability of the developed sorbent was examined using synthetic and real samples such as sea/ground water samples.
Mixing whey and soy proteins: Consequences for the gel mechanical response and water holding
Jose, J.; Pouvreau, L.A.M.; Martin, Anneke
2016-01-01
To design food products based on mixtures of proteins from animal and plant sources, understanding of how the structural and mechanical properties of mixed protein systems can benefit from selectively mixing is essential. Heat-induced gels were prepared from mixtures of whey proteins (WP) and soy pr
Uyaguari-Diaz, Miguel I; Slobodan, Jared R; Nesbitt, Matthew J; Croxen, Matthew A; Isaac-Renton, Judith; Prystajecky, Natalie A; Tang, Patrick
2015-04-17
Next-generation sequencing of environmental samples can be challenging because of the variable DNA quantity and quality in these samples. High quality DNA libraries are needed for optimal results from next-generation sequencing. Environmental samples such as water may have low quality and quantities of DNA as well as contaminants that co-precipitate with DNA. The mechanical and enzymatic processes involved in extraction and library preparation may further damage the DNA. Gel size selection enables purification and recovery of DNA fragments of a defined size for sequencing applications. Nevertheless, this task is one of the most time-consuming steps in the DNA library preparation workflow. The protocol described here enables complete automation of agarose gel loading, electrophoretic analysis, and recovery of targeted DNA fragments. In this study, we describe a high-throughput approach to prepare high quality DNA libraries from freshwater samples that can be applied also to other environmental samples. We used an indirect approach to concentrate bacterial cells from environmental freshwater samples; DNA was extracted using a commercially available DNA extraction kit, and DNA libraries were prepared using a commercial transposon-based protocol. DNA fragments of 500 to 800 bp were gel size selected using Ranger Technology, an automated electrophoresis workstation. Sequencing of the size-selected DNA libraries demonstrated significant improvements to read length and quality of the sequencing reads.
Bai, Ruiliang; Basser, Peter J; Briber, Robert M; Horkay, Ferenc
2014-03-15
Water self-diffusion coefficients and longitudinal relaxation rates in sodium polyacrylate solutions and gels were measured by NMR, as a function of polymer content and structure in a physiological concentration range of monovalent and divalent cations, Ca(2+) and Na(+). Several physical models describing the self-diffusion of the solvent were applied and compared. A free-volume model was found to be in good agreement with the experimental results over a wide range of polymer concentrations. The longitudinal relaxation rate exhibited linear dependence on polymer concentration below a critical concentration and showed non-linear behavior at higher concentrations. Both the water self-diffusion and relaxation were less influenced by the polymer in the gel state than in the uncrosslinked polymer solutions. The effect of Na(+) on the mobility of water molecules was practically undetectable. By contrast, addition of Ca(2+) strongly increased the longitudinal relaxation rate while its effect on the self-diffusion coefficient was much less pronounced.
Surface aspects of sol-gel derived hematite films for the photoelectrochemical oxidation of water.
Herrmann-Geppert, Iris; Bogdanoff, Peter; Radnik, Jörg; Fengler, Steffen; Dittrich, Thomas; Fiechter, Sebastian
2013-02-07
α-Fe(2)O(3) (hematite) photoanodes for the oxygen evolution reaction (OER) were prepared by a cost-efficient sol-gel procedure. Due to low active photoelectrochemical properties observed, it is assumed that the sol-gel procedure leads to hematite films with defects and surface states on which generated charge carriers are recombined or immobilized in trap processes. Electrochemical activation was proven to diminish unfavourable surface groups to some extent. More efficiently, a plasma treatment improves significantly the photoelectrochemical properties of the OER. X-ray photoelectron spectroscopy (XPS) analysis reveals an oxygen enriched surface layer with new oxygen species which may be responsible for the improved electrochemical activity. Due to surface photovoltage an increased fraction of transferred charge carriers from these newly produced surface defects are identified.
Adsorption of Basic Brown and Chrysophenine from Water Solution by Magnesium Silicate Gel
Directory of Open Access Journals (Sweden)
Zhun Zhao
2015-01-01
Full Text Available Noncrystalline, high surface area magnesium silicate gel was successfully prepared by hydrothermal method. Such product was characterized by BET and XRD to determine surface area 576.4 m2·g−1, average pore width 2.76 nm, and amorphous surface. The adsorption behaviors of Basic Brown and Chrysophenine on magnesium silicate gel were investigated through changing initial concentration, adsorbent dosage, solution pH, contact time, and temperature. The experimental data was analyzed by the adsorption isotherms and kinetics. The results showed the adsorption progress was fast for Basic Brown, and the adsorption equilibrium was finished in 2 h, while the adsorption equilibrium of Chrysophenine was finished in 7 h. Freundlich isotherm model and second-order kinetic models described the adsorption process very well.
低气速条件下CO2在牛顿及非牛顿流体中气含率%Gas holdup of CO2 in Newtonian and non-Newtonian fluid at low gas velocity
Institute of Scientific and Technical Information of China (English)
李少白; 马友光; 付涛涛; 朱春英
2012-01-01
实验测定了低气速下CO2气泡群在牛顿流体、剪切变稀流体及黏弹性流体中的气含率.讨论了流体的流变性、质量分数及表观气速对气含率的影响.结果表明:在3种不同性质的流体中,气含率均随表观气速的增大而增大.同时发现流体性质对气含率具有不同的影响:对于牛顿流体,表观气速较低时,质量分数对气含率影响可忽略；对于非牛顿流体,气含率随着流动指数n的减小而减小,即剪切变稀效应对气含率有负作用,而黏弹性对气含率的影响可忽略.气含率是气液传质过程设计中最重要的参数,因此研究结果为进一步研究CO2气泡群在非牛顿流体中的传质奠定了一定基础.%The gas holdups of CO2 bubble swarm at low superficial gas velocity in Newtonian fluid, shear thinned fluid and viscoelastic fl uid were measured. The influences of rheological property, mass fraction and superficial gas velocity on the gas holdup were investigated. The results show that the gas holdups in three fluids all increase with the increase of superficial gas velocity, and different fluid has different effects on the gas holdup. The effect of mass fraction on the gas holdup in Newtonian fluid at low superficial gas velocity is negligible. For non-Newtonian fluid, the gas holdup decreases with the decrease of flow index n, that is, shear thinning effect has negative impact on the gas holdup, and the influence of viscoelasticity on the gas holdup is negligible. The gas holdup is the most important parameter for the gas-liquid mass transfer process design, and it provides a solid foundation for the research on mass transfer of CO2 bubble swarm in non-Newtonian fluid.
Institute of Scientific and Technical Information of China (English)
丁立; 郑强
2015-01-01
在考虑半对数应力应变关系的基础上，引入非牛顿指数描述的非达西渗流模型，建立一维固结方程，采用有限差分法求其数值解，并与Terzaghi解答和Davis解答对比验证数值方法的有效性。据此，分析土体应力应变非线性和渗流的非达西特性对饱和粘土一维固结的影响。结果表明，非牛顿指数i0越大，土层厚度与地基平均竖向总应力的等效水头的比值越大，固结速率越低；地面荷载越大，孔压消散速率和地基沉降速率都越快，按沉降定义的固结度要略大于按孔压定义的固结度；压缩指数与渗透指数的比值越大，固结速率越慢；初始有效应力越大，固结速率越快。%Considering Davis’s semilog stress-strain relationship,we introducce non Newtonian index to describe non-darcy seepage flow model,and derive the one-dimensional consolidation equation. And its numerical solution analysis is performed by using the finite difference method. In order to verify the effectiveness of the numerical method,the calculating solution by the present method is compared with the analytical solution based on the nonlinear consolidation theory proposed by Davis and Raymond. Accordingly,the effect of stress and strain nonlinearity of soil and seepage non-Darcy characteristics on one-dimensional consolidation of saturated clay is analyzed. The results show that the greater the non-Newtonian index i0 is,the greater the equivalent head ration of soil layer thickness and the foundation of the total average vertical stress would be,and the consolidation rate is lower is. The greater the ground load is,the greater the pore pressure dissipation rate and ground subsidence rate would be. The definition of degree of consolidation by settlement is slightly greater than the definition of degree of consolidation by pore water pressure. The greater the ratio of compression and penetration index is ,the slower the consolidation
Formation process of a strong water-repellent alumina surface by the sol-gel method
Energy Technology Data Exchange (ETDEWEB)
Feng Libang, E-mail: lepond@hotmail.com [School of Mechatronic Engineering, Lanzhou Jiaotong University, 88 West Anning Road, Lanzhou 730070 (China); Li Hui; Song Yongfeng; Wang Yulong [School of Mechatronic Engineering, Lanzhou Jiaotong University, 88 West Anning Road, Lanzhou 730070 (China)
2010-03-01
A novel strong water-repellent alumina thin film is fabricated by chemically adsorbing stearic acid (STA) layer onto the porous and roughened aluminum film coated with polyethyleneimine (PEI). The formation process and the structure of the strong water-repellent alumina film are investigated by means of contact angle measurement and atomic force microscope (AFM). Results show that the water contact angles for the alumina films increase with the increase of the immersion time in the boiling water, and meanwhile, the roughness of the alumina films increases with the dissolution of the boehmite in the boiling water. Finally, the strong water-repellent film with a high water contact angle of 139.1 deg. is obtained when the alumina films have distinct roughened morphology with some papillary peaks and porous structure. Moreover, both the roughened structure and the hydrophobic materials of the STA endow the alumina films with the strong water-repellence.
Formation process of a strong water-repellent alumina surface by the sol-gel method
Feng, Libang; Li, Hui; Song, Yongfeng; Wang, Yulong
2010-03-01
A novel strong water-repellent alumina thin film is fabricated by chemically adsorbing stearic acid (STA) layer onto the porous and roughened aluminum film coated with polyethyleneimine (PEI). The formation process and the structure of the strong water-repellent alumina film are investigated by means of contact angle measurement and atomic force microscope (AFM). Results show that the water contact angles for the alumina films increase with the increase of the immersion time in the boiling water, and meanwhile, the roughness of the alumina films increases with the dissolution of the boehmite in the boiling water. Finally, the strong water-repellent film with a high water contact angle of 139.1° is obtained when the alumina films have distinct roughened morphology with some papillary peaks and porous structure. Moreover, both the roughened structure and the hydrophobic materials of the STA endow the alumina films with the strong water-repellence.
Otoni, Caio G; Avena-Bustillos, Roberto J; Chiou, Bor-Sen; Bilbao-Sainz, Cristina; Bechtel, Peter J; McHugh, Tara H
2012-09-01
Cold- and warm-water fish gelatin granules were exposed to ultraviolet-B radiation for doses up to 29.7 J/cm(2). Solutions and films were prepared from the granules. Gel electrophoresis and refractive index were used to examine changes in molecular weight of the samples. Also, the gel strength and rheological properties of the solutions as well as the tensile and water vapor barrier properties of the films were characterized. SDS-PAGE and refractive index results indicated cross-linking of gelatin chains after exposure to radiation. Interestingly, UV-B treated samples displayed higher gel strengths, with cold- and warm-water fish gelatin having gel strength increases from 1.39 to 2.11 N and from 7.15 to 8.34 N, respectively. In addition, both gelatin samples exhibited an increase in viscosity for higher UV doses. For gelatin films, the cold-water fish gelatin samples made from irradiated granules showed greater tensile strength. In comparison, the warm-water gelatin films made from irradiated granules had lower tensile strength, but better water vapor barrier properties. This might be due to the UV induced cross-linking in warm-water gelatin that disrupted helical structures.
Chin, Koo B; Go, Mi Y; Xiong, Youling L
2009-03-01
Functional properties of heat-induced gels prepared from microbial transglutaminase (TG)-treated porcine myofibrillar protein (MP) containing sodium caseinate with or without konjac flour (KF) under various salt concentrations (0.1, 0.3 and 0.6MNaCl) were evaluated. The mixed MP gels with KF exhibited improved cooking yields at all salt concentrations. TG treatment greatly enhanced gel strength and elasticity (storage modulus, G') at 0.6M NaCl, but not at lower salt concentrations. The combination of KF and TG improved the gel strength at 0.1 and 0.3M NaCl and G' at all salt concentrations, when compared with non-TG controls. Incubation of MP suspensions (sols) with TG promoted the disappearance of myosin heavy chain and the production of polymers. The TG-treated MP mixed gels had a compact structure, compared to those without TG, and the KF incorporation modified the gel matrix and increased its water-holding capacity. Results from differential scanning calorimetry suggested possible interactions of MP with KF, which may explain the changes in the microstructure of the heat-induced gels.
Directory of Open Access Journals (Sweden)
Luminita Predoana
2009-06-01
Full Text Available In the present work the LaCoO3 formation from gel precursors obtained by water-based sol-gel method with citric acid was studied. As precursors La and Co nitrates were used. The obtained gels were analyzed by TG/DTA and TG/EGA. The decomposition of the gels takes place in two main steps with the evolution of the same volatile compounds (H2O, CO2 and NO2 leading to the conclusion that two types of bonding of the components in the gels occurred. The decomposition of the gels takes place up to 400°C. The gels thermally treated at 600°C lead to single pure perovskite rhombohedral phase of lanthanum cobalt oxide (LaCoO3. Some electrical properties of LaCoO3 measured in “operando” conditions, i.e. in gas ﬂ ow, at atmospheric pressure (by using the differential step technique DST are presented and discussed.
Lee, Pilhwa; Wolgemuth, Charles W.
2016-01-01
The swimming of microorganisms typically involves the undulation or rotation of thin, filamentary objects in a fluid or other medium. Swimming in Newtonian fluids has been examined extensively, and only recently have investigations into microorganism swimming through non-Newtonian fluids and gels been explored. The equations that govern these more complex media are often nonlinear and require computational algorithms to study moderate to large amplitude motions of the swimmer. Here, we develop an immersed boundary method for handling fluid-structure interactions in a general two-phase medium, where one phase is a Newtonian fluid and the other phase is viscoelastic (e.g., a polymer melt or network). We use this algorithm to investigate the swimming of an undulating, filamentary swimmer in 2D (i.e., a sheet). A novel aspect of our method is that it allows one to specify how forces produced by the swimmer are distributed between the two phases of the fluid. The algorithm is validated by comparing theoretical predictions for small amplitude swimming in gels and viscoelastic fluids. We show how the swimming velocity depends on material parameters of the fluid and the interaction between the fluid and swimmer. In addition, we simulate the swimming of Caenorhabditis elegans in viscoelastic fluids and find good agreement between the swimming speeds and fluid flows in our simulations and previous experimental measurements. These results suggest that our methodology provides an accurate means for exploring the physics of swimming through non-Newtonian fluids and gels.
Unaffected microscopic dynamics of macroscopically arrested water in dilute clay gels
Seydel, Tilo; Wiegart, Lutz; Juranyi, Fanni; Struth, Bernd; Schober, Helmut
2008-12-01
Adequate clay minerals considerably affect the macroscopic mechanical behavior of water even at concentrations of a few percent. Thus when 2wt.% laponite clay mineral nanoparticles are added to water, the resulting colloidal suspension after some time takes on the semisolid characteristics of a jellylike material at room temperature. Cold neutron time-of-flight spectroscopy data are in agreement with the assumption that notwithstanding this macroscopic change, the mobility of the water molecules on intermolecular and intramolecular length scales remains largely unaffected. This observation is discussed in the context of the properties and the role of water in different more or less dilute ionic environments. The result contributes to the ongoing debate of the properties and role of water in living cells.
Directory of Open Access Journals (Sweden)
Hsiao-Yuan Ma
2016-03-01
Full Text Available Organic-inorganic hybrid sols (Ti–O–Si precursor were first synthesized by the sol-gel method at low addition of water, and were then employed to prepare a highly refractive hybrid optical film. This film was obtained by blending the Ti–O–Si precursor with 2-phenylphenoxyethyl acrylate (OPPEA to perform photo-polymerization by ultraviolet (UV irradiation. Results show that the film transparency of poly(Ti–O–Si precursor-co-OPPEA film is higher than that of a pure poly(Ti–O–Si precursor film, and that this poly(Ti–O–Si precursor-co-OPPEA hybrid film exhibits a high transparency of ~93.7% coupled with a high refractive index (n of 1.83 corresponding to a thickness of 2.59 μm.
Kuo, Chun Wei; Hao Huang, Kuan; Hsu, Bing Mu; Tsai, Hsien Lung; Tseng, Shao Feng; Kao, Po Min; Shen, Shu Min; Chou Chiu, Yi; Chen, Jung Sheng
2013-04-01
Salmonella is one of the most important pathogens of waterborne diseases with outbreaks from contaminated water reported worldwide. In addition, Salmonella spp. can survive for long periods in aquatic environments. To realize genotypes and serovars of Salmonella in aquatic environments, we isolated the Salmonella strains by selective culture plates to identify the serovars of Salmonella by serological assay, and identify the genotypes by Multilocus sequence typing (MLST) based on the sequence data from University College Cork (UCC), respectively. The results show that 36 stream water samples (30.1%) and 18 drinking water samples (23.3%) were confirmed the existence of Salmonella using culture method combined PCR specific invA gene amplification. In this study, 24 cultured isolates of Salmonella from water samples were classified to fifteen Salmonella enterica serovars. In addition, we construct phylogenetic analysis using phylogenetic tree and Minimum spanning tree (MST) method to analyze the relationship of clinical, environmental, and geographical data. Phylogenetic tree showed that four main clusters and our strains can be distributed in all. The genotypes of isolates from stream water are more biodiversity while comparing the Salmonella strains genotypes from drinking water sources. According to MST data, we can found the positive correlation between serovars and genotypes of Salmonella. Previous studies revealed that the result of Pulsed field gel electrophoresis (PFGE) method can predict the serovars of Salmonella strain. Hence, we used the MLST data combined phylogenetic analysis to identify the serovars of Salmonella strain and achieved effectiveness. While using the geographical data combined phylogenetic analysis, the result showed that the dominant strains were existed in whole stream area in rainy season. Keywords: Salmonella spp., MLST, phylogenetic analysis, PFGE
Mehta, Shyam B; Lewus, Rachael; Bee, Jared S; Randolph, Theodore W; Carpenter, John F
2015-04-01
The formation of viscoelastic gels by a monoclonal antibody (mAb) at the silicone oil-water interface was studied using interfacial shear rheology. At a concentration of 50 μg/mL, the mAb formed gels in less than 1 h, and the gelation time decreased with increasing protein concentration. To probe the effects of mechanical rupture of the interfacial gel layers, a layer of silicone oil was overlaid on the surface of aqueous solutions of mAb, and the interface was ruptured periodically with a needle. Rupture of the interfacial gel resulted in formation of subvisible particles and substantial losses of mAb monomer, which were detected by microflow imaging and quantified by size-exclusion chromatography, respectively. Resonance mass measurement showed that levels of both protein particles and silicone oil droplets increased as the gel was repeatedly ruptured with a needle. In contrast, in samples wherein the interfacial gels were not ruptured, much lower levels of aggregates and particles were detected. Addition of nonionic surfactants (polysorbate 20 or polysorbate 80) protected against aggregation and protein particle formation, with increased protection seen with increasing surfactant levels, and with the greatest inhibition observed in samples containing polysorbate 80.
Pintado, T; Ruiz-Capillas, C; Jiménez-Colmenero, F; Carmona, P; Herrero, A M
2015-10-15
This paper reports on the development of olive oil-in-water emulsion gels containing chia (Salvia hispanica L.) (flour or seed) and cold gelling agents (transglutaminase, alginate or gelatin). The technological and structural characteristics of these emulsion gels were evaluated. Both structural and technological changes in emulsion gels resulting from chilled storage were also determined. The color and texture of emulsion gels depend on both the cold gelling agents used and chilled storage. Lipid oxidation increased (p < 0.05) during storage in emulsion gels containing transglutaminase or alginate. Analyses of the half-bandwidth of the 2923 cm(-1) band and the area of the 3220 cm(-1) band suggest that the order/disorder of the oil lipid chain related to lipid interactions and droplet size in the emulsion gels could be decisive in determining their textural properties. The half-bandwidth of 2923 cm(-1) band and area of 3220 cm(-1) band did not show significant differences during chilled storage.
CONFORMANCE IMPROVEMENT USING GELS
Energy Technology Data Exchange (ETDEWEB)
Randall S. Seright
2003-09-01
This report describes work performed during the second year of the project, ''Conformance Improvement Using Gels.'' The project has two objectives. The first objective is to identify gel compositions and conditions that substantially reduce flow through fractures that allow direct channeling between wells, while leaving secondary fractures open so that high fluid injection and production rates can be maintained. The second objective is to optimize treatments in fractured production wells, where the gel must reduce permeability to water much more than that to oil. Pore-level images from X-ray computed microtomography were re-examined for Berea sandstone and porous polyethylene. This analysis suggests that oil penetration through gel-filled pores occurs by a gel-dehydration mechanism, rather than a gel-ripping mechanism. This finding helps to explain why aqueous gels can reduce permeability to water more than to oil. We analyzed a Cr(III)-acetate-HPAM gel treatment in a production well in the Arbuckle formation. The availability of accurate pressure data before, during, and after the treatment was critical for the analysis. After the gel treatment, water productivity was fairly constant at about 20% of the pre-treatment value. However, oil productivity was stimulated by a factor of 18 immediately after the treatment. During the six months after the treatment, oil productivity gradually decreased to approach the pre-treatment value. To explain this behavior, we proposed that the fracture area open to oil flow was increased substantially by the gel treatment, followed by a gradual closing of the fractures during subsequent production. For a conventional Cr(III)-acetate-HPAM gel, the delay between gelant preparation and injection into a fracture impacts the placement, leakoff, and permeability reduction behavior. Formulations placed as partially formed gels showed relatively low pressure gradients during placement, and yet substantially reduced the
Structural Optimization of non-Newtonian Microfluidics
DEFF Research Database (Denmark)
Jensen, Kristian Ejlebjærg; Okkels, Fridolin
2011-01-01
a filter on the design variables based on a Helmholtz-type differential equation and we try to vary the filter length throughout the optimization in order to ensure compatibility with a convex interpolation between the inverse permeability and the design variables, which is popular within topology...
Non-Newtonian viscosity in magnetized plasma
Johnson, Robert W
2007-01-01
The particle and momentum balance equations can be solved on concentric circular flux surfaces to determine the effective viscous drag present in a magnetized tokamak plasma in the low aspect ratio limit. An analysis is developed utilizing the first-order Fourier expansion of the poloidal variation of quantities on the flux surface akin to that by Stacey and Sigmar [Phys. Fluids, 28, 9 (1985)]. Expressions to determine the poloidal variations of density, poloidal velocity, toroidal velocity, radial electric field, poloidal electric field, and other radial profiles are presented in a multi-species setting. Using as input experimental data for the flux surface averaged profiles of density, temperature, toroidal current, toroidal momentum injection, and the poloidal and toroidal rotations of at least one species of ion, one may solve the equations numerically for the remaining profiles. The resultant effective viscosities are compared to those predicted by Stacey and Sigmar and Shaing, et al., [Nuclear Fusion, 2...
Permeability of gels is set by the impulse applied on the gel
Urbonaite, V.; Jongh, de H.H.J.; Linden, van der E.; Pouvreau, L.A.M.
2015-01-01
To better understand sensory perception of foods, water exudation studies on protein-based gels are of a high importance. It was aimed to study the interplay of gel coarseness and gel stiffness on water holding (WH) and water flow kinetics from the gel once force is applied onto the material. Ovalbu
Mihajlovic, V.; Garcia Molina, G.; Peuscher, J
2011-01-01
Recent technological advances in the field of skin electrodes and on-body sensors indicate a possibility of having an alternative to the traditionally used conductive gel electrodes for measuring electrical signals of the brain (electroencephalogram, EEG). This paper evaluates whether water-based an
Cellulose gel dispersion: From pure hydrogel suspensions to encapsulated oil-in-water emulsions.
Napso, Sofia; Rein, Dmitry M; Khalfin, Rafail; Kleinerman, Olga; Cohen, Yachin
2016-01-01
Cellulose hydrogel particles were fabricated from molecularly-dissolved cellulose/IL solutions. The characteristics of the formed hydrogels (cellulose content, particles' size and porosity) were determined as a function of cellulose concentration in the precursor solutions. There is a significant change in the hydrogel structure when the initial cellulose solution concentration increases above about 7-9%wt. These changes include increase of the cellulose content in the hydrogel, and decrease in its pore size. The finest cellulose particle dispersions can be obtained using low concentration cellulose/IL solutions (cellulose concentration in dispersion less than 2%wt.) or hydrogels (concentration less than 1%wt.) in a dispersing medium consisting of IL with no more than 20%wt. water. Stable paraffin oil-in-water emulsions are achieved by mixing oil and water with cellulose/IL solutions. The optimal conditions for obtaining the finest particles (about 20μm in diameter) are attained using cellulose solutions of concentration between 0.7 and 4%wt. at temperature of 70°C and oil/cellulose mass ratios between 1 and 1.5.
Energy Technology Data Exchange (ETDEWEB)
Kauder, K.; Deipenwisch, R. [Dortmund Univ. (Germany). FG Fluidenergiemaschinen
1998-12-31
The model of the calculation of the friction losses caused by oil described in this report delivers a starting point for the integration of the design parameter `oil` for oil injected screw-type engines. The use of non newtonian oils with a shear thinning behaviour lead to a decrease of energy consumption over a broad speed range of screw-type compressors. The decrease is mainly caused by the shear indicated lower viscosity in the clearances of the compressor. A difficulty through the use of this oils is the estimation of the conditions in the clearances. The rate of shear in the single clearance is influenced by the relative speed of the boundaries and by the height of the clearance during operation. Up to now only cold heights were used in the model. To improve the quality of the model the clearances of a running screw compressor were measured. The losses which were determined at the screw compressor test plant are the summation of all losses including the losses caused by the power transmission and in the bearings. Experiments at a model rotor test stand make the determination of the friction losses and the losses by the acceleration of the oil in the clearances possible. A better calculation model shall deliver the conditions to describe the influence of the oil on the energy efficiency and to define the optimal oil for every screw compressor. (orig.) [Deutsch] Das beschriebene Modell zur Berechnung der hydraulischen Verluste in der nasslaufenden Schraubenmaschine liefert Ansaetze, um das Oel schon bei der Auslegung der Schraubenkompressoren als Konstruktionselement mit einzubeziehen. Sinnvoll ist die Nutzung eines nicht-newtonschen Oeles immer dann, wenn eine deutliche scherindizierte Viskositaetserniedrigung in dem Schergeschwindigkeitsbereich, der in den Spalten des Schraubenkompressors vorliegt, erreicht werden kann. Beim Einsatz dieser Oele besteht die Schwierigkeit darin, den Schergeschwindigkeitsbereich vorherzubestimmen, der waehrend des Betriebs in dem
Energy Technology Data Exchange (ETDEWEB)
Wankhede, Ruchi Grover, E-mail: 123.ruchi@gmail.com [IITB-Monash Research Academy, Mumbai 400076 (India); Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai 400076 (India); Morey, Shantaram [Dow Chemicals (India); Khanna, A.S. [Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai 400076 (India); Birbilis, N. [Department of Materials Engineering, Monash University, Victoria 3800 (Australia)
2013-10-15
The development of an organic–inorganic sol–gel coating system (thickness ∼ 2 μm) on aluminum is reported. The coating uses glycidoxytrimethoxysilane (GPTMS) and methyltrimethoxysilane (MTMS) as silane precursors, crosslinked with hexamethylmethoxymelamine (HMMM) and followed by hydrophobic modification using a water base short chain per-fluoro emulsion (FE). Such coating resulted in enhanced hydrophobicity with a contact angle of about 120° and sliding angle of 25° for a 20 μL water droplet. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements showed reduced corrosion upon coated substrates than the bare; correlated with both a higher degree of water repellency and formation of low permeable crosslinked sol–gel network. The structure of the coatings deposited was analyzed using Fourier transform infrared (FTIR) and X-ray photoelectron (XPS) spectroscopy, revealing replacement of hydrophillic surface hydroxyls groups with low energy per-fluoro groups.
Energy Technology Data Exchange (ETDEWEB)
Baytak, Sitki [Harran University, Arts and Science Faculty, Department of Chemistry, Sanliurfa (Turkey); Kocyigit, Abdurrahim [Harran University, Faculty of Medicine, Department of Biochemistry, Sanliurfa (Turkey); Rehber Tuerker, Ali [Gazi University, Arts and Science Faculty, Department of Chemistry, Ankara (Turkey)
2007-12-15
A method for the determination of Fe(III), Pb(II), and Ni(II) by flame atomic absorption spectrometry (FAAS) after preconcentrating on a column containing Aspergillus niger loaded on silica gel 60 (Biosorbent) is described. The effect of experimental parameters such as pH, flow rate of sample solution, and volume of sample solution were investigated on the recovery of the analytes. The effect of interfering ions on the recovery of the analytes has also been investigated. Recoveries of Fe(III), Pb(II), and Ni(II) were (98 {+-} 2), (98 {+-} 3), (99 {+-} 2)% at the 95% confidence level, respectively. For the analytes, 50-fold preconcentration was obtained. The analytical detection limits for Fe(III), Pb(II), and Ni(II) were 1.7, 5.2, and 1.6 ng/mL, respectively. The proposed method was applied to the determination of trace metals in various water and vegetable samples. The analytes have been determined with relative error lower than 7%. (Abstract Copyright [2007], Wiley Periodicals, Inc.)
Boyce, J M; Kelliher, S; Vallande, N
2000-07-01
To compare the frequency of skin irritation and dryness associated with using an alcoholic-hand-gel regimen for hand antisepsis versus using soap and water for hand washing. Prospective randomized trial with crossover design. Irritation and dryness of nurses' hands were evaluated by self-assessment and by visual assessment by a study nurse. Epidermal water content of the dorsal surface of nurses' hands was estimated by measuring electrical capacitance of the skin. Miriam Hospital, a 200-bed university-affiliated teaching hospital. Thirty-two nurses working on three hospital wards participated in the trial, which lasted 6 weeks. Self-assessment scores of skin irritation and dryness decreased slightly during the 2 weeks when nurses used the alcoholic-hand-gel regimen (mean baseline score, 2.72; mean final score, 2.0; P=.08) but increased substantially during the 2 weeks when nurses used soap and water (mean baseline score, 2.0; mean final score, 4.8; Phand-gel regimen was used (mean baseline and final scores were both 0.55), but scores increased substantially when nurses used soap and water (baseline score, 0.59; mean final score, 1.21; P=.05). Epidermal water content of the dorsal surface of nurses' hands changed little when the alcoholic-hand-gel regimen was used (mean+/-standard deviation baseline electrical capacitance reading, 24.8+/-6.8; mean final reading, 25.7+/-7.3), but decreased significantly (skin became dryer) with soap-and-water hand washing (mean baseline, 25.9+/-7.5; mean final reading, 20.5+/-5.4; P=.0003). Hand antisepsis with an alcoholic-hand-gel regimen was well tolerated and did not result in skin irritation and dryness of nurses' hands. In contrast, skin irritation and dryness increased significantly when nurses washed their hands with the unmedicated soap product available in the hospital. Newer alcoholic hand gels that are tolerated better than soap may be more acceptable to staff and may lead to improved hand-hygiene practices.
Institute of Scientific and Technical Information of China (English)
LIU Xiu-dong; YU Wei-ting; LIN Jun-zhang; MA Xiao-jun; YUAN Quan
2007-01-01
Alginate has been widely used in cell microencapsulation and drug delivery systems in the form of gel beads or microcapsules. Although an alternative novel emulsification-internal gelation technology has been established and both the properties and the potential applications of the beads in drug delivery systems have been studied, the mechanism has not been well understood compared with the traditional droplet method( external gelation technology). On the basis of our previous knowledge that the novel technology is composed of complicatedly consecutive processes with multistep diffusion and re action, and the diffusion of acetic acid across oil/water interface being the prerequisite that determines the occurrence and rate for the reactions and the structures and properties of final produced gel beads, a special emphasis was placed on the diffusion process. With the aid of diffusion modeling and simple experimental design, the diffusion rate constant and diffusion coefficient of acetic acid across oil/water interface were determined to be in the orders of magnitude of 10-6 and 10-16, respectively. This knowledge will be of particular importance in understanding and interpreting the formation, structure of the gel beads and the relationship between the structure and properties and guiding the preparation and quality control of the gel beads.
Jin, Tingting; Cheng, Jing; Cai, Cuicui; Cheng, Min; Wu, Shiju; Zhou, Hongbin
2016-07-29
In this paper, graphene oxide was coated onto a stainless steel wire through sol-gel technique and it was used as a solid phase microextraction (SPME) fiber. The prepared fiber was characterized by scanning electron microscopy (SEM), which displayed that the fiber had crinkled surface and porous structure The application of the fiber was evaluated through the headspace SPME of nine organophosphate ester flame retardants (OPFRs) with different characteristics in water samples followed by gas chromatography and nitrogen-phosphorous detector (GC/NPD). The major factors influencing the extraction efficiency, including the extraction and desorption conditions, were studied and optimized. Under the optimum conditions, the proposed method was evaluated, and applied to the analysis of organophosphate ester flame retardants in real environmental water samples. The results demonstrated the HS-SPME method based on GO sol-gel fiber had good linearity (R>0.9928), and limits of detection (1.4-135.6ngL(-1)), high repeatability (RSDsol-gel fiber displayed bigger extraction capability than the commercial PDMS fiber and the pure sol-gel fiber for both polar and apolar organophosphate esters, especially for the OPFRs containing benzene rings.
Tang, Chuan-He; Chen, Ling; Foegeding, Edward Allen
2011-04-27
The mechanical properties, water-holding capacities (WHC), and microstructures of emulsion gels, induced by glucono-δ-lactone (GDL), CaCl(2), and microbial transglutaminase (MTGase) from unheated and heated soy protein isolate (SPI)-stabilized emulsions (at protein concentration 5%, w/v; oil volume fraction, 20%, w/v), were investigated and compared. The influence of thermal pretreatments (at 90 °C for 5 min) before and/or after emulsification was evaluated. Considerable differences in mechanical, water-holding, and microstructural properties were observed among various emulsion gels. The thermal pretreatment after emulsification increased the strength of the emulsion gels induced by GDL and CaCl(2), whereas in the case of MTGase, thermal pretreatments before and/or after emulsification on the contrary greatly inhibited gel network formation. The application of the enzyme coagulant exhibited much higher potential to form SPI-stabilized emulsion gels with higher mechanical strength than that of the other two coagulants. The WHC of the emulsion gels seemed to be not directly related to their gel network strength. Confocal laser scanning microscope analyses indicated that the network microstructure of the formed emulsion gels, mainly composed of aggregated protein-stabilized oil droplets and protein aggregate clumps, varied with the type of applied coagulants and emulsions. The differences in microstructure were basically consistent with the differences in mechanical properties of the gels. These results could provide valuable information for the formation of cold-set soy protein-stabilized emulsion gels.
Conformance Improvement Using Gels
Energy Technology Data Exchange (ETDEWEB)
Seright, Randall S.; Schrader, Richard; II Hagstrom, John; Wang, Ying; Al-Dahfeeri, Abdullah; Gary, Raven; Marin; Amaury; Lindquist, Brent
2002-09-26
This research project had two objectives. The first objective was to identify gel compositions and conditions that substantially reduce flow through fractures that allow direct channeling between wells, while leaving secondary fractures open so that high fluid injection and production rates can be maintained. The second objective was to optimize treatments in fractured production wells, where the gel must reduce permeability to water much more than that to oil.
Ebrahimi, Mahmoud; Es'haghi, Zarrin; Samadi, Fatemeh; Hosseini, Mohammad-Saeid
2011-11-18
An ionic liquid mediated sol-gel sorbents for hollow fiber solid-phase microextraction (HF-SPME) was developed for extraction of the pesticides: diazinon, fenitrothion, malathion, fenvalerate, phosalone and tridemorph from human hair and water samples. The analytes were subsequently analyzed with high performance liquid chromatography and diode array detection (HPLC-DAD). Preliminary experiments were carried out in order to study experimental conditions for pesticides' extraction from spiked hair and water samples with HF-SPME using hollow fiber-supported ionic liquid mediated sol-gel sorbent. The sol-gel nanocomposites were reinforced with nanoparticles such as carboxylic functionalized multi-walled carbon nanotubes (COOH-MWCNTs), amino functionalized multi-walled carbon nanotubes (NH(2)-MWCNTs), nano SiO(2), nano TiO(2) and nano MgO comparatively to promote extraction efficiency. In this device, the innovative solid sorbents were developed by the sol-gel method via the reaction of tetraethylorthosilicate (TEOS) with 2-amino-2-hydroxymethyl-propane-1,3-diol (TRIS). In the basic condition (pH 10-11), the gel growth process in the presence of ionic liquid and nanoparticles was initiated. Then, the sol was injected into a polypropylene hollow fiber segment for in situ gelation process. Parameters affecting the efficiency of HF-SPME were thoroughly investigated. Linearity was observed over a range of 0.01-25,000 ng/mL with detection limits between 0.004 and 0.095 ng/mL for the pesticides in the aqueous matrices and 0.003-0.080 ng/mL in the hair matrices. The relative recoveries in the real samples ranged from 82.0% to 94.0% for the pesticides store seller's hair and the work researchers' hair. Results are showing the great possibilities of HF-SPME-HPLC-PDA for analysis of pesticides in biological and environmental samples.
Energy Technology Data Exchange (ETDEWEB)
Quevedo, A; Nicolucci, P [University of Sao Paulo, Ribeirao Preto, SP (Brazil)
2014-06-01
Purpose: Analyse the water-equivalence of MAGIC-f polymer gel for {sup 60}Co and {sup 192}Ir clinical brachytherapy sources, through dose distributions simulated with PENELOPE Monte Carlo code. Methods: The real geometry of {sup 60} (BEBIG, modelo Co0.A86) and {sup 192}192Ir (Varian, model GammaMed Plus) clinical brachytherapy sources were modelled on PENELOPE Monte Carlo simulation code. The most probable emission lines of photons were used for both sources: 17 emission lines for {sup 192}Ir and 12 lines for {sup 60}. The dose distributions were obtained in a cubic water or gel homogeneous phantom (30 × 30 × 30 cm{sup 3}), with the source positioned in the middle of the phantom. In all cases the number of simulation showers remained constant at 10{sup 9} particles. A specific material for gel was constructed in PENELOPE using weight fraction components of MAGIC-f: wH = 0,1062, wC = 0,0751, wN = 0,0139, wO = 0,8021, wS = 2,58×10{sup −6} e wCu = 5,08 × 10{sup −6}. The voxel size in the dose distributions was 0.6 mm. Dose distribution maps on the longitudinal and radial direction through the centre of the source were used to analyse the water-equivalence of MAGIC-f. Results: For the {sup 60} source, the maximum diferences in relative doses obtained in the gel and water were 0,65% and 1,90%, for radial and longitudinal direction, respectively. For {sup 192}Ir, the maximum difereces in relative doses were 0,30% and 1,05%, for radial and longitudinal direction, respectively. The materials equivalence can also be verified through the effective atomic number and density of each material: Zef-MAGIC-f = 7,07 e .MAGIC-f = 1,060 g/cm{sup 3} and Zef-water = 7,22. Conclusion: The results showed that MAGIC-f is water equivalent, consequently being suitable to simulate soft tissue, for Cobalt and Iridium energies. Hence, gel can be used as a dosimeter in clinical applications. Further investigation to its use in a clinical protocol is needed.
CONFORMANCE IMPROVEMENT USING GELS
Energy Technology Data Exchange (ETDEWEB)
Randall S. Seright
2004-09-30
This report describes work performed during the third and final year of the project, ''Conformance Improvement Using Gels.'' Corefloods revealed throughput dependencies of permeability reduction by polymers and gels that were much more prolonged during oil flow than water flow. This behavior was explained using simple mobility ratio arguments. A model was developed that quantitatively fits the results and predicts ''clean up'' times for oil productivity when production wells are returned to service after application of a polymer or gel treatment. X-ray computed microtomography studies of gels in strongly water-wet Berea sandstone and strongly oil-wet porous polyethylene suggested that oil penetration through gel-filled pores occurs by a gel-dehydration mechanism, rather than gel-ripping or gel-displacement mechanisms. In contrast, analysis of data from the University of Kansas suggests that the gel-ripping or displacement mechanisms are more important in more permeable, strongly water-wet sandpacks. These findings help to explain why aqueous gels can reduce permeability to water more than to oil under different conditions. Since cement is the most commonly used material for water shutoff, we considered when gels are preferred over cements. Our analysis and experimental results indicated that cement cannot be expected to completely fill (top to bottom) a vertical fracture of any width, except near the wellbore. For vertical fractures with apertures less than 4 mm, the cement slurry will simply not penetrate very far into the fracture. For vertical fractures with apertures greater than 4 mm, the slurry may penetrate a substantial distance into the bottom part of the fracture. However, except near the wellbore, the upper part of the fracture will remain open due to gravity segregation. We compared various approaches to plugging fractures using gels, including (1) varying polymer content, (2) varying placement (extrusion) rate
Li, Bin; Xu, Jingjing; Hall, Andrew J; Haupt, Karsten; Tse Sum Bui, Bernadette
2014-09-01
Molecularly imprinted polymers (MIPs) for salicylic acid were synthesized and evaluated in aqueous environments in the aim to apply them as drug delivery carriers. One organic MIP and one inorganic MIP based on the sol-gel process were synthesized. The organic MIP was prepared by radical polymerization using the stoichiometric functional monomer, 1-(4-vinylphenyl)-3-(3,5-bis(trifluoromethyl)phenyl)urea, which can establish strong electrostatic interactions with the -COOH of salicylic acid. The sol-gel MIP was prepared with 3-(aminopropyl)triethoxysilane and trimethoxyphenylsilane, as functional monomers and tetraethyl orthosilicate as the crosslinker. While the organic MIPs bound the target specifically in acetonitrile, they exhibited lower binding in the presence of water, although the imprinting factor increased under these conditions, due to reduced non-specific binding. The sol-gel MIP has a high specificity and capacity for the drug in ethanol, a solvent compatible with drug formulation and biomedical applications. In vitro release profiles of the polymers in water were evaluated, and the results were modelled by Fick's law of diffusion and the power law. Analysis shows that the release mechanism was predominantly diffusion-controlled.
Directory of Open Access Journals (Sweden)
Meisam Shokraneh
2016-11-01
Full Text Available Aim: The risk of bacteria resistance to specific antibiotics possibly by continuous subtherapeutical administration of antibiotic growth promoters (AGPs in poultry feed led to a ban on the use of AGP in poultry production. As a result of this ban, alternative substances for poultry growth promotion and disease prevention are being investigated, among which phytogenic and herbal products have received increased attention as natural additives because they have been accepted by consumers as natural additives. The effect of water supplementation of Aloe vera (AV as an AGP substitute on performance, intestinal microflora, and immune responses of broilers. Materials and Methods: The five experimental treatments were allocated to four replicates. The following treatments were applied (1 a basal broiler diet (C and normal drinking water, (2 0.5% AV gel in drinking water, (3 0.75% AV gel in drinking water, (4 1% AV gel in drinking water, and (5 diet C supplemented with flavophospholipol at 4.5 mg/kg and drinking normal water. Vaccines against influenza disease and sheep red blood cell (SRBC were administrated to immunological stimuli. The populations of Lactobacilli spp. and coliforms were enumerated in ileum. Results: Body weight of broilers supplemented with different levels of AV increased compared with control group (p<0.05. Birds supplemented with antibiotic had the best feed-to-gain ratio (F:G in different periods. Supplementation of 0.5% and 0.75% AV improved F:G entire experimental period compared with control group (p<0.05. Coliform bacteria were reduced in broilers supplemented with different levels of AV or antibiotic (p<0.05. The Lactobacilli spp. population in birds supplemented with 0.75%, 1% AV or antibiotic significantly was higher than other groups (p<0.05. Supplementation with 1% AV led to greater antibody titers against SRBC compared with other groups (p<0.05. Conclusion: These findings demonstrated a possibility of supplementing
Shokraneh, Meisam; Ghalamkari, Gholamreza; Toghyani, Majid; Landy, Nasir
2016-01-01
Aim: The risk of bacteria resistance to specific antibiotics possibly by continuous subtherapeutical administration of antibiotic growth promoters (AGPs) in poultry feed led to a ban on the use of AGP in poultry production. As a result of this ban, alternative substances for poultry growth promotion and disease prevention are being investigated, among which phytogenic and herbal products have received increased attention as natural additives because they have been accepted by consumers as natural additives. The effect of water supplementation of Aloe vera (AV) as an AGP substitute on performance, intestinal microflora, and immune responses of broilers. Materials and Methods: The five experimental treatments were allocated to four replicates. The following treatments were applied (1) a basal broiler diet (C) and normal drinking water, (2) 0.5% AV gel in drinking water, (3) 0.75% AV gel in drinking water, (4) 1% AV gel in drinking water, and (5) diet C supplemented with flavophospholipol at 4.5 mg/kg and drinking normal water. Vaccines against influenza disease and sheep red blood cell (SRBC) were administrated to immunological stimuli. The populations of Lactobacilli spp. and coliforms were enumerated in ileum. Results: Body weight of broilers supplemented with different levels of AV increased compared with control group (p<0.05). Birds supplemented with antibiotic had the best feed-to-gain ratio (F:G) in different periods. Supplementation of 0.5% and 0.75% AV improved F: G entire experimental period compared with control group (p<0.05). Coliform bacteria were reduced in broilers supplemented with different levels of AV or antibiotic (p<0.05). The Lactobacilli spp. population in birds supplemented with 0.75%, 1% AV or antibiotic significantly was higher than other groups (p<0.05). Supplementation with 1% AV led to greater antibody titers against SRBC compared with other groups (p<0.05). Conclusion: These findings demonstrated a possibility of supplementing broiler
Institute of Scientific and Technical Information of China (English)
闻建平; 贾晓强; 毛国柱
2004-01-01
A small scale isotropic mass transfer model was developed for the local liquid side mass transfer coefficients in gas-liquid-solid three-phase flow airlift loop reactor for Newtonian and non-Newtonian fluids.It is based on Higbie's penetration theory and Kolmogoroff's theory of isotropic turbulence with k1 = 3√2Dε1/3 1/π(η-1/3 1 -λ-1/3 f),where ε1 is local rate of energy dissipation,λf is the local microscale,η1 is the local Kolmogoroff scale and D is the diffusion coefficient.The capability of the proposed model is discussed in the light of experimental data obtained from 12 L gas-liquid-solid three-phase flow airlift loop reactor using Newtonian and non-Newtonian fluids.Good agreement with the experimental data was obtained over a wide range of conditions suggesting a general applicability of the proposed model.
Factors influencing alginate gel biocompatibility.
Tam, Susan K; Dusseault, Julie; Bilodeau, Stéphanie; Langlois, Geneviève; Hallé, Jean-Pierre; Yahia, L'Hocine
2011-07-01
Alginate remains the most popular polymer used for cell encapsulation, yet its biocompatibility is inconsistent. Two commercially available alginates were compared, one with 71% guluronate (HiG), and the other with 44% (IntG). Both alginates were purified, and their purities were verified. After 2 days in the peritoneal cavity of C57BL/6J mice, barium (Ba)-gel and calcium (Ca)-gel beads of IntG alginate were clean, while host cells were adhered to beads of HiG alginate. IntG gel beads, however, showed fragmentation in vivo while HiG gel beads stayed firm. The physicochemical properties of the sodium alginates and their gels were thoroughly characterized. The intrinsic viscosity of IntG alginate was 2.5-fold higher than that of HiG alginate, suggesting a greater molecular mass. X-ray photoelectron spectroscopy indicated that both alginates were similar in elemental composition, including low levels of counterions in all gels. The wettabilities of the alginates and gels were also identical, as measured by contact angles of water on dry films. Ba-gel beads of HiG alginate resisted swelling and degradation when immersed in water, much more than the other gel beads. These results suggest that the main factors contributing to the biocompatibility of gels of purified alginate are the mannuronate/guluronate content and/or intrinsic viscosity.
Saraji, Mohammad; Jafari, Mohammad Taghi; Sherafatmand, Hossein
2015-02-01
A novel solid-phase microextraction (SPME) fiber coated with a sol-gel/nanoclay composite was prepared by the sol-gel technique involving the hydrolysis reaction of alkoxysilanes and the subsequent condensation reaction with hydroxyl groups of the nanoclay on a stainless steel wire. A method based on direct immersion SPME and gas chromatography-corona discharge ion mobility spectrometry was developed for the determination of four organophosphorus pesticides in aqueous samples. The effect of different experimental parameters on the extraction efficiency of the method was investigated. The sol-gel/nanoclay fiber showed higher extraction performance for the organophosphorus pesticides compared with Ppy/nanoclay, sol-gel coating, and three commercial fibers (polydimethylsiloxane (PDMS), PDMS/divinylbenzene (DVB), and polyacrylate (PA)). Limits of detection (LOD) and quantitation (LOQ) of the method were in the range of 0.003-0.012 and 0.01-0.02 μg L(-1), respectively. The calibration curves were linear in a concentration range from 0.01 to 2.0 μg L(-1) (r (2) > 0.995). The relative standard deviations for intra- and inter-day precision were 3.3-5.6 and 6.4-8.4 %, respectively. Fiber-to-fiber reproducibility for three prepared fibers was 7.4-10.2 %. Finally, the method was successfully applied for the extraction of the studied compounds from water samples. The relative recovery obtained for the spiked real-water samples were 86-104 %.
Screening effect on nanostructure of charged gel
DEFF Research Database (Denmark)
Sugiyama, M; Annaka, M; Hino, M
2004-01-01
Charge screening effects on nanostructures of N-isopropylacrylamide-sodium acrylate (NIPA-SA) and -acrylic acid (NIPA-AAc) gels are investigated with small-angle neutron scattering. The NIPA-SA and NIPA-AAc gels with low water content exhibit microphase separations with different dimensions....... The dehydrated NIPA-SA gel also makes the microphase separation but the dehydrated NIPA-AAc gel does not. These results indicate that ionic circumstance around charged bases strongly affects the nanostructures both of the dehydrated gel and the gel with low water content. (C) 2004 Elsevier B. V. All rights...
Nielsen, Kim; Vorum, Henrik; Ehlers, Niels; Aagaard, Nicolaj; Hjortdal, Jesper; Honoré, Bent
2015-11-01
Tear film proteins adhere to the surface of contact lenses (CLs). While the proteins in the tears have been extensively studied with various proteomic techniques, adhered proteins to CLs are less studied. In this pilot study, we have separated proteins with 2D gel electrophoresis prior to the conventional mass spectrometry (MS) in order to analyse the deposited proteins on hydrogel CLs from myopic patients. pHEMA and PVA hydrogel CLs worn by 3 patients for different time lengths were analysed. After wear, the CLs were frozen at -20°C. Proteins were extracted in lysis buffer, separated on 12% polyacrylamide gels and silver-stained. Protein spots were excised and identified with liquid chromatography - tandem MS. Deposited proteins were extracted with a yield of 26-66 μg and separated by 2D gel electrophoresis. The silver-stained gels showed similar protein patterns independent of the patient, hydrogel type and wear time. Seventy-two spots were analysed with MS, representing at least 12 different tear film proteins or protein fragments. Deposited tear film proteins from a single set of CLs worn for 1 day can successfully be analysed first with 2D gel electrophoresis and subsequently with MS, thus making examination of individual patients possible. The protein composition appeared homogeneous between the test persons which is a necessity for additional comparison analysis. The molecular masses of the identified proteins indicate that protein degradation occurs only as a minor event. Myopic patients were investigated in this pilot study, but the combined techniques can easily be applied to other eye diseases. © 2015 Acta Ophthalmologica Scandinavica Foundation. Published by John Wiley & Sons Ltd.
Sannino, Filomena; Marocco, Antonello; Garrone, Edoardo; Esposito, Serena; Pansini, Michele
2015-01-01
In this work, we studied the removal of simazine from both a model and well water by adsorption on two different adsorbents: zeolite H-Y and a porous silica made in the laboratory by using the sol-gel technique. The pH dependence of the adsorption process and the isotherms and pseudo-isotherms of adsorption were studied. Moreover, an iterative process of simazine removal from both the model and well water, which allowed us to bring the residual simazine concentration below the maximum concentration (0.05 mg L(-1)) of agrochemicals in wastewater to be released in surface waters or in sink allowed by Italian laws, was proposed. The results obtained were very interesting and the conclusions drawn from them partly differed from what could reasonably be expected.
Krishnaiah, Y S R; Bhaskar, P; Satyanarayana, V
2004-01-01
The aim of this investigation was to find the effect of the ethanol-water solvent system and the ethanolic solution of carvone on the permeation of nimodipine across rat abdominal skin in order to select a suitable solvent system and optimal concentration of carvone for the development of membrane-moderated transdermal therapeutic system of nimodipine. The solubility of nimodipine in water, ethanol, and ethanol-water cosolvent systems, or the selected concentration of carvone [2% (w/w) to 12% (w/w)] in 60:40 (v/v) ethanol-water were determined. The effect of these solvents or cosolvent systems on the transdermal permeation of nimodipine was also studied using in vitro permeability studies across the rat abdominal skin. The co-solvent system containing 60:40 (v/v) of ethanol-water showed highest permeability across the rat abdominal skin. Further, the effect of ethanolic solution [60% (v/v) ethanol-water] of carvone [2% (w/w) to 12% (w/w)] on the in vitro permeation of nimodipine across the rat abdominal skin from 2% (w/w) hydroxypropyl methylcellulose (HPMC) gel was also investigated. The transdermal permeability of nimodipine across rat abdominal skin was enhanced further by the addition of carvone to HPMC gel prepared with 60% (v/v) of ethanol. There was a steady effect on the flux of nimodipine (161.02 +/- 4.14 microg/cm2/hr) with an enhancement ratio of 4.56 when carvone was incorporated at a concentration of 10% (w/w) in HPMC gels prepared with 60% (v/v) ethanol. The Fourier transform infrared data indicated that ethanolic solution of carvone increased the transdermal permeability of nimodipine across the rat abdominal skin by partial extraction of lipids in the stratum corneum. The results suggest that 10% (w/w) of carvone in 60% (v/v) ethanol-water, along with HPMC as antinucleating agent may be useful for enhancing the skin permeability of nimodipine from the membrane-moderated transdermal therapeutic system.
Directory of Open Access Journals (Sweden)
You Q.
2011-11-01
Full Text Available For drilling and water shutoff of oil and gas reservoirs containing hydrogen sulfide (H2S, the effects of H2S on widely used gel as water shutoff agents are studied. The gels include Na2Cr2O7/Na2SO3/HPAM gel, Na2Cr2O7/(NH22CS/HPAM gel, Cr(III-acetate & Cr(III-lactate/HPAM gel and phenol formaldehyde resin/HPAM gel. The results show that: for Na2Cr2O7/Na2SO3/HPAM gel and Na2Cr2O7/(NH22CS/HPAM gel, the H2S as reducing agent (the reducibility is more efficient than that of Na2SO3and (NH22CS can reduce Cr(VI into Cr(III and accelerate crosslinking reaction with HPAM in low concentration of H2S, while it can react with Cr(III generating Cr2S3 precipitation in high concentration of H2S, for which the bulk gel can not form without Cr(III; for Cr(III-acetate & Cr(III-lactate/HPAM gel, H2S can prolong the gelation time and reduce the gel strength by decreasing pH value; for phenol formaldehyde resin/HPAM gel, H2S can slightly prolong the gelation time and slightly reduce the gel strength by decreasing pH value. Therefore, according to the comprehensive investigations of the effects of H2S on gel as water shutoff agents, the phenol formaldehyde resin/HPAM gel is recommended as the water shutoff agents suitable for oil and gas reservoir containing H2S. Pour le forage et le traitement des venues d’eau dans des réservoirs d’huile et de gaz contenant du sulfure d’hydrogène (H2S, les effets de l’H2S sur les gels couramment utilisés pour le traitement des venues d’eau sont étudiés. Les gels incluent un gel de Na2Cr2O7/Na2SO3/HPAM, un gel de Na2Cr2O7/(NH22CS/HPAM, un gel d’acétate de Cr(III & lactate de Cr(III/HPAM et un gel à base de résine de phénol formaldéhyde/HPAM. Les résultats montrent que : pour un gel de Na2Cr2O7/Na2SO3/HPAM et un gel de Na2Cr2O7/(NH22CS/HPAM, l’H2S en tant qu’agent réducteur (la réductibilité est plus efficace que celle du Na2SO3et du (NH22CS peut réduire le Cr(VI en Cr(III et accélérer la réaction de
Gandra, Sarath C R; Nguyen, Sanko; Nazzal, Sami; Alayoubi, Alaadin; Jung, Rose; Nesamony, Jerry
2015-01-01
The aim of this study was to develop thermosensitive gels using poloxamers for topical delivery of fluconazole (FLZ). Eight different formulations containing 1% FLZ in poloxamer and a particular co-solvent (propylene glycol (PG) or Transcutol-P) of various concentrations were prepared. The gels were characterized for transition temperatures, rheological and mechanical properties. FLZ permeability and antifungal effect of the gels were also evaluated. Except for one formulation, all gels exhibited thermosensitive property, i.e. transformed from Newtonian (liquid-like) behavior at 20 °C to non-Newtonian (gel-like) behavior at 37 °C. Transcutol-P increased the transition temperature of the formulations, while the opposite effect was observed for PG. At 37 °C, formulations with high poloxamer concentrations (17%) resulted in high viscosity, compressibility and hardness. Formulations containing 17% poloxamer and 20% Transcutol-P and 10% PG, respectively, exhibited high adhesiveness. No significant differences in the in vitro antifungal activity of FLZ were observed among the formulations suggesting that the gel vehicles did not influence the biological effect of FLZ. FLZ permeability decreased with increasing poloxamer concentration. Formulations containing 17% poloxamer and 20% Transcutol-P and 10% PG seemed to be promising in situ gelling systems for the topical delivery of FLZ.
Energy Technology Data Exchange (ETDEWEB)
Ramezani, Maedeh, E-mail: m.ramezani@merc.ac.ir [Division of Nanotechnology and Advanced Materials, Materials and Energy Research Center, P.O. Box 31787-316, Karaj (Iran, Islamic Republic of); Vaezi, Mohammad Reza [Division of Nanotechnology and Advanced Materials, Materials and Energy Research Center, P.O. Box 31787-316, Karaj (Iran, Islamic Republic of); Kazemzadeh, Asghar [Division of Semiconductors, Materials and Energy Research Center, P.O. Box 31787-316, Karaj (Iran, Islamic Republic of)
2015-01-30
Graphical abstract: - Highlights: • Transparent, hydrophobic, uniform silica film by sol–gel co-precursor process. • Preparation of silica coatings from ETES and Iso-OTMS in different molar ratios. • Decreasing in hydrophobicity of the films with increasing in Iso-TMS molar ratio. • By changing the molar ratio of component, different size of particles was obtained. - Abstract: In this paper, we used one-step sol–gel process to prepare the hydrophobic silica films on the glass substrate from the ethyltriethoxysilane (ETES) as a precursor and iso-octyltrimethoxysilane (Iso-OTMS) as a hydrophobic agent. In order to study the effect of the hydrophobic agent on the water repellent properties of the silica films, the alcosol was prepared by keeping constant the molar ratio of ETES:EtOH:H{sub 2}O at 1:36.2:6.3, with 6 M ammonium hydroxide and Iso-OTMS/ETES molar ratio varied from 0.2 to 1.4. Also, we investigated the influence of the other sol–gel reaction parameters, such as catalyst, solvent and water content and their effect on the morphology and hydrophobic properties of the silica films. The results revealed that by altering the molar ratio of NH{sub 4}OH, EtOH and H{sub 2}O, different sizes of silica nanoparticles from 41.24 to 86.16 nm were obtained. The silica films were characterized by atomic force microscopy (AFM), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FE-SEM) images, contact angle measurement (CA) and percentage of optical transmission.
Directory of Open Access Journals (Sweden)
Hassan Zohair Hassan
2014-10-01
Full Text Available In the present study, dynamic analysis and performance evaluation of a solar-powered continuous operation adsorption chiller are introduced. The adsorption chiller uses silica gel and water as the working pair. The developed mathematical model represents the heat and mass transfer within the reactor coupled with the energy balance of the collector plate and the glass cover. Moreover, a non-equilibrium adsorption kinetic model is taken into account by using the linear driving force equation. The variation of solar radiation, wind speed, and atmospheric temperature along a complete cycle are considered for a more realistic simulation. Based on the case studied and the baseline parameters, the chiller is found to acquire a coefficient of performance of 0.402. The average thermal efficiency of the solar collector is estimated to be 62.96% and the average total efficiency approaches a value of 50.91%. Other performance parameters obtained are 363.8 W and 1.82 W/kg for the cooling capacity and the specific cooling power of the chiller, respectively. Furthermore, every 1 kg of silica gel inside the adsorption reactor produces a daily chilled water mass of 3 kg at a temperature of 10 ◦C. In addition, the cooling system harnesses 25.35% of the total available solar radiation and converts it to a cooling effect.
Jung, Sang Chul; Bae, Young Chan
2012-02-23
The influence of phase separation on swelling behavior was investigated based on the thermodynamic framework of reswelling phenomena. The cloud-point for a ternary system of water(1)-tetrahydrofuran (THF)(2)-poly(N-isopropylacrylamide)(3) was examined by thermo-optical analysis (TOA). Nanometer-sized N-isopropylacrylamide (NIPA) gel particles were prepared by precipitation polymerization, and their swelling behaviors were determined using photon correlation spectroscopy (PCS). NIPA gel particles underwent reswelling when the ratio of water to THF was varied. First, the modified double lattice model (MDL) was employed to determine ternary interaction energy parameters for the liquid-liquid equilibrium (LLE) of linear poly-NIPA in a water-THF cosolvent system. The reentrant swelling equilibria of the NIPA gel in the water-THF system were then calculated using the interaction energy parameters. © 2012 American Chemical Society
Energy Technology Data Exchange (ETDEWEB)
Inoue, M.; Nakayama, A. [Shizuoka University, Shizuoka (Japan). Faculty of Engineering
1996-09-25
Three-dimensional numerical calculations have been performed to simulate the viscous and porous inertia effects on the pressure drop in a non-Newtonian fluid flow through a porous medium. Cubes placed in an infinite space have been proposed as a three-dimensional model of microscopic porous structure. A full set of three-dimensional momentum equations is solved along with the continuity equation at a pore scale, so as to simulate a flow through an infinite number of obstacles arranged in a regular pattern. The microscopic numerical results, thus obtained, are processed to extract the macroscopic relationship between the pressure gradient-mass flow rate. Comparing the results based on the two- and three-dimensional models, it has been found that only the three-dimensional model can capture the porous inertia effects on the pressure drop correctly. 13 refs., 6 figs.