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Sample records for niobium surfaces relevant

  1. Surface preparation of niobium

    International Nuclear Information System (INIS)

    Kneisel, P.

    1980-01-01

    Any discussion of surface preparation for superconducting rf-surfaces is certainly connected with the question what is the best recipe for achieving high Q-values and high break-down fields. Since the break-down in a cavity is not understood so far and because several mechanisms play a role, it also is not possible to give one recipe which always works. Nevertheless in the past certain preparation techniques for niobium surfaces have been developed and certain rules for preparation can be applied. In the following the to-days state of the art will be described and it is attempted to give a short description of the surface in conjunction with the methods of surface treatments, which generally can be applied to niobium cavities. (orig./WTR)

  2. Enhanced Field Emission Studies on Niobium Surfaces Relevant to High Field Superconducting Radio-Frequency Devices

    International Nuclear Information System (INIS)

    Tong Wang

    2002-01-01

    Enhanced field emission (EFE) presents the main impediment to higher acceleration gradients in superconducting niobium (Nb) radio frequency cavities for particle accelerators. The strength, number and sources of EFE sites strongly depend on surface preparation and handling. The main objective of this thesis project is to systematically investigate the sources of EFE from Nb, to evaluate the best available surface preparation techniques with respect to resulting field emission, and to establish an optimized process to minimize or eliminate EFE. To achieve these goals, a scanning field emission microscope (SFEM) was designed and built as an extension to an existing commercial scanning electron microscope (SEM). In the SFEM chamber of ultra high vacuum, a sample is moved laterally in a raster pattern under a high voltage anode tip for EFE detection and localization. The sample is then transferred under vacuum to the SEM chamber equipped with an energy-dispersive x-ray spectrometer for individual emitting site characterization. Compared to other systems built for similar purposes, this apparatus has low cost and maintenance, high operational flexibility, considerably bigger scan area, as well as reliable performance. EFE sources from planar Nb have been studied after various surface preparation, including chemical etching and electropolishing, combined with ultrasonic or high-pressure water rinse. Emitters have been identified, analyzed and the preparation process has been examined and improved based on EFE results. As a result, field-emission-free or near field-emission-free surfaces at ∼140 MV/m have been consistently achieved with the above techniques. Characterization on the remaining emitters leads to the conclusion that no evidence of intrinsic emitters, i.e., no fundamental electric field limit induced by EFE, has been observed up to ∼140 MV/m. Chemically etched and electropolished Nb are compared and no significant difference is observed up to ∼140 MV

  3. Enhanced Field Emission Studies on Niobium Surfaces Relevant to High Field Superconducting Radio-Frequency Devices

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Tong [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)

    2002-09-18

    Enhanced field emission (EFE) presents the main impediment to higher acceleration gradients in superconducting niobium (Nb) radiofrequency cavities for particle accelerators. The strength, number and sources of EFE sites strongly depend on surface preparation and handling. The main objective of this thesis project is to systematically investigate the sources of EFE from Nb, to evaluate the best available surface preparation techniques with respect to resulting field emission, and to establish an optimized process to minimize or eliminate EFE. To achieve these goals, a scanning field emission microscope (SFEM) was designed and built as an extension to an existing commercial scanning electron microscope (SEM). In the SFEM chamber of ultra high vacuum, a sample is moved laterally in a raster pattern under a high voltage anode tip for EFE detection and localization. The sample is then transferred under vacuum to the SEM chamber equipped with an energy-dispersive x-ray spectrometer for individual emitting site characterization. Compared to other systems built for similar purposes, this apparatus has low cost and maintenance, high operational flexibility, considerably bigger scan area, as well as reliable performance. EFE sources from planar Nb have been studied after various surface preparation, including chemical etching and electropolishing, combined with ultrasonic or high-pressure water rinse. Emitters have been identified, analyzed and the preparation process has been examined and improved based on EFE results. As a result, field-emission-free or near field-emission-free surfaces at ~140 MV/m have been consistently achieved with the above techniques. Characterization on the remaining emitters leads to the conclusion that no evidence of intrinsic emitters, i.e., no fundamental electric field limit induced by EFE, has been observed up to ~140 MV/m. Chemically etched and electropolished Nb are compared and no significant difference is observed up to ~140 MV/m. To

  4. Hydrogen Contamination of Niobium Surfaces

    International Nuclear Information System (INIS)

    Viet Nguyen-Tuong; Lawrence Doolittle

    1993-01-01

    The presence of hydrogen is blamed for dramatic reductions in cavity Q's. Hydrogen concentration is difficult to measure, so there is a great deal of Fear, Uncertainty, and Doubt (FUD) associated with the problem. This paper presents measurements of hydrogen concentration depth profiles, commenting on the pitfalls of the methods used and exploring how material handling can change the amount of hydrogen in pieces of niobium. Hydrogen analysis was performed by a forward scattering experiment with Helium used as the primary beam. This technique is variously known as FRES (Forward Recoil Elastic Scattering), FRS, HFS (Hydrogen Forward Scattering), and HRA (Hydrogen Recoil Analysis). Some measurements were also made using SIMS (Secondary Ion Mass Spectrometry). Both HFS and SIMS are capable of measuring a depth profile of Hydrogen. The primary difficulty in interpreting the results from these techniques is the presence of a surface peak which is due (at least in part) to contamination with either water or hydrocarbons. With HFS, the depth resolution is about 30 nm, and the maximum depth profiled is about 300 nm. (This 10-1 ratio is unusually low for ion beam techniques, and is a consequence of the compromises that must be made in the geometry of the experiment, surface roughness, and energy straggling in the absorber foil that must be used to filter out the forward scattered helium.) All the observed HFS spectra include a surface peak which includes both surface contamination and any real hydrogen uptake by the niobium surface. Some contamination occurs during the analysis. The vacuum in the analysis chamber is typically a few times 10(sup -6) torr, and some of the contamination is in the form of hydrocarbons from the pumping system. Hydrocarbons normally form a very thin (less than a monolayer) film which is in equilibrium between arrival rate and the evaporation rate. In the presence of the incoming ion beam, however, these hydrocarbons crack on the surface into non

  5. Voltage breakdown on niobium and copper surfaces

    International Nuclear Information System (INIS)

    Werner, G.R.; Padamsee, H.; Betzwieser, J.C.; Liu, Y.G.; Rubin, K.H.R.; Shipman, J.E.; Ying, L.T.

    2003-01-01

    Experiments have shown that voltage breakdown in superconducting niobium RF cavities is in many ways similar to voltage breakdown on niobium cathodes in DC voltage gaps; most striking are the distinctive starburst patterns and craters that mark the site of voltage breakdown in both superconducting cavities and DC vacuum gaps. Therefore, we can learn much about RF breakdown from simpler, faster DC experiments. We have direct evidence, in the form of before'' and ''after'' pictures, that breakdown events caused by high surface electric fields occur with high probability at contaminant particles on surfaces. Although the pre-breakdown behavior (field emission) seems to depend mostly on the contaminant particles present and little on the substrate, the breakdown event itself is greatly affected by the substrate-niobium, heavily oxidized niobium, electropolished copper, and diamond-machined copper cathodes lead to different kinds of breakdown events. By studying DC voltage breakdown we hope to learn more details about the processes involved in the transition from field emission to catastrophic arcing and the cratering of the surface; as well as learning how to prevent breakdown, we would like to learn how to cause breakdown, which could be important when ''processing'' cavities to reduce field emission. (author)

  6. ROUGHNESS ANALYSIS OF VARIOUSLY POLISHED NIOBIUM SURFACES

    Energy Technology Data Exchange (ETDEWEB)

    Ribeill, G.; Reece, C.

    2008-01-01

    Niobium superconducting radio frequency (SRF) cavities have gained widespread use in accelerator systems. It has been shown that surface roughness is a determining factor in the cavities’ effi ciency and maximum accelerating potential achievable through this technology. Irregularities in the surface can lead to spot heating, undesirable local electrical fi eld enhancement and electron multipacting. Surface quality is typically ensured through the use of acid etching in a Buffered Chemical Polish (BCP) bath and electropolishing (EP). In this study, the effects of these techniques on surface morphology have been investigated in depth. The surface of niobium samples polished using different combinations of these techniques has been characterized through atomic force microscopy (AFM) and stylus profi lometry across a range of length scales. The surface morphology was analyzed using spectral techniques to determine roughness and characteristic dimensions. Experimentation has shown that this method is a valuable tool that provides quantitative information about surface roughness at different length scales. It has demonstrated that light BCP pretreatment and lower electrolyte temperature favors a smoother electropolish. These results will allow for the design of a superior polishing process for niobium SRF cavities and therefore increased accelerator operating effi ciency and power.

  7. Surface processing for bulk niobium superconducting radio frequency cavities

    Science.gov (United States)

    Kelly, M. P.; Reid, T.

    2017-04-01

    The majority of niobium cavities for superconducting particle accelerators continue to be fabricated from thin-walled (2-4 mm) polycrystalline niobium sheet and, as a final step, require material removal from the radio frequency (RF) surface in order to achieve performance needed for use as practical accelerator devices. More recently bulk niobium in the form of, single- or large-grain slices cut from an ingot has become a viable alternative for some cavity types. In both cases the so-called damaged layer must be chemically etched or electrochemically polished away. The methods for doing this date back at least four decades, however, vigorous empirical studies on real cavities and more fundamental studies on niobium samples at laboratories worldwide have led to seemingly modest improvements that, when taken together, constitute a substantial advance in the reproducibility for surface processing techniques and overall cavity performance. This article reviews the development of niobium cavity surface processing, and summarizes results of recent studies. We place some emphasis on practical details for real cavity processing systems which are difficult to find in the literature but are, nonetheless, crucial for achieving the good and reproducible cavity performance. New approaches for bulk niobium surface treatment which aim to reduce cost or increase performance, including alternate chemical recipes, barrel polishing and ‘nitrogen doping’ of the RF surface, continue to be pursued and are closely linked to the requirements for surface processing.

  8. Field dependent surface resistance of niobium on copper cavities

    Directory of Open Access Journals (Sweden)

    T. Junginger

    2015-07-01

    Full Text Available The surface resistance R_{S} of superconducting cavities prepared by sputter coating a niobium film on a copper substrate increases significantly stronger with the applied rf field compared to cavities of bulk material. A possible cause is that the thermal boundary resistance between the copper substrate and the niobium film induces heating of the inner cavity wall, resulting in a higher R_{S}. Introducing helium gas in the cavity, and measuring its pressure as a function of applied field allowed to conclude that the inner surface of the cavity is heated up by less than 120 mK when R_{S} increases with E_{acc} by 100  nΩ. This is more than one order of magnitude less than what one would expect from global heating. Additionally, the effects of cooldown speed and low temperature baking have been investigated in the framework of these experiments. It is shown that for the current state of the art niobium on copper cavities there is only a detrimental effect of low temperature baking. A fast cooldown results in a lowered R_{S}.

  9. Roughness analysis applied to niobium thin films grown on MgO(001) surfaces for superconducting radio frequency cavity applications

    OpenAIRE

    D. B. Beringer; W. M. Roach; C. Clavero; C. E. Reece; R. A. Lukaszew

    2013-01-01

    This paper describes surface studies to address roughness issues inherent to thin film coatings deposited onto superconducting radio frequency (SRF) cavities. This is particularly relevant for multilayered thin film coatings that are being considered as a possible scheme to overcome technical issues and to surpass the fundamental limit of ∼50  MV/m accelerating gradient achievable with bulk niobium. In 2006, a model by Gurevich [Appl. Phys. Lett. 88, 012511 (2006)APPLAB0003-695110.1063/1.2162...

  10. Investigation of niobium surface structure and composition for improvement of superconducting radio-frequency cavities

    Science.gov (United States)

    Trenikhina, Yulia

    Nano-scale investigation of intrinsic properties of niobium near-surface is a key to control performance of niobium superconducting radio-frequency cavities. Mechanisms responsible for the performance limitations and their empirical remedies needs to be justified in order to reproducibly control fabrication of SRF cavities with desired characteristics. The high field Q-slope and mechanism behind its cure (120°C mild bake) were investigated by comparison of the samples cut out of the cavities with high and low dissipation regions. Material evolution during mild field Q-slope nitrogen treatment was characterized using the coupon samples as well as samples cut out of nitrogen treated cavity. Evaluation of niobium near-surface state after some typical and novel cavity treatments was accomplished. Various TEM techniques, SEM, XPS, AES, XRD were used for the structural and chemical characterization of niobium near-surface. Combination of thermometry and structural temperature-dependent comparison of the cavity cutouts with different dissipation characteristics revealed precipitation of niobium hydrides to be the reason for medium and high field Q-slopes. Step-by-step effect of the nitrogen treatment processing on niobium surface was studied by analytical and structural characterization of the cavity cutout and niobium samples, which were subject to the treatment. Low concentration nitrogen doping is proposed to explain the benefit of nitrogen treatment. Chemical characterization of niobium samples before and after various surface processing (Electropolishing (EP), 800°C bake, hydrofluoric acid (HF) rinsing) showed the differences that can help to reveal the microscopic effects behind these treatments as well as possible sources of surface contamination.

  11. Study of the surface resistance of superconducting niobium films at 1.5 GHz

    CERN Document Server

    Benvenuti, Cristoforo; Campisi, I E; Darriulat, Pierre; Peck, M A; Russo, R; Valente, A M

    1999-01-01

    A systematic study of superconducting properties of niobium films sputtered on the inner wall of radiofrequency cavities is presented. The measured quantities include in particular the response to 1.5 GHz microwaves, the critical temperature, the penetration depth and the magnetic penetration field. In addition to films grown in different gas discharges (Xe, Kr, Ar and Ar/Ne mixtures) and to films grown on substrates prepared under different conditions, the study also includes bulk niobium cavities. The surface resistance is analysed in terms of its dependence on temperature, on RF field and, when relevant, on the density of trapped fluxons. A simple parameterisation is found to give a good fit to the data. Once allowance for the presence of impurities and defects is made by means of a single parameter, the electron mean free path, good agreement with BCS theory is observed. The fluxon-induced losses are studied in detail and their dependence on RF field, on temperature and on the density of trapped fluxons i...

  12. Surface analyses of electropolished niobium samples for superconducting radio frequency cavity

    International Nuclear Information System (INIS)

    Tyagi, P. V.; Nishiwaki, M.; Saeki, T.; Sawabe, M.; Hayano, H.; Noguchi, T.; Kato, S.

    2010-01-01

    The performance of superconducting radio frequency niobium cavities is sometimes limited by contaminations present on the cavity surface. In the recent years extensive research has been done to enhance the cavity performance by applying improved surface treatments such as mechanical grinding, electropolishing (EP), chemical polishing, tumbling, etc., followed by various rinsing methods such as ultrasonic pure water rinse, alcoholic rinse, high pressure water rinse, hydrogen per oxide rinse, etc. Although good cavity performance has been obtained lately by various post-EP cleaning methods, the detailed nature about the surface contaminants is still not fully characterized. Further efforts in this area are desired. Prior x-ray photoelectron spectroscopy (XPS) analyses of EPed niobium samples treated with fresh EP acid, demonstrated that the surfaces were covered mainly with the niobium oxide (Nb 2 O 5 ) along with carbon, in addition a small quantity of sulfur and fluorine were also found in secondary ion mass spectroscopy (SIMS) analysis. In this article, the authors present the analyses of surface contaminations for a series of EPed niobium samples located at various positions of a single cell niobium cavity followed by ultrapure water rinsing as well as our endeavor to understand the aging effect of EP acid solution in terms of contaminations presence at the inner surface of the cavity with the help of surface analytical tools such as XPS, SIMS, and scanning electron microscope at KEK.

  13. Surface analyses of electropolished niobium samples for superconducting radio frequency cavity

    Energy Technology Data Exchange (ETDEWEB)

    Tyagi, P. V.; Nishiwaki, M.; Saeki, T.; Sawabe, M.; Hayano, H.; Noguchi, T.; Kato, S. [GUAS, Tsukuba, Ibaraki 305-0801 (Japan); KEK, Tsukuba, Ibaraki 305-0801 (Japan); KAKEN Inc., Hokota, Ibaraki 311-1416 (Japan); GUAS, Tsukuba, Ibaraki 305-0801 (Japan) and KEK, Tsukuba, Ibaraki 305-0801 (Japan)

    2010-07-15

    The performance of superconducting radio frequency niobium cavities is sometimes limited by contaminations present on the cavity surface. In the recent years extensive research has been done to enhance the cavity performance by applying improved surface treatments such as mechanical grinding, electropolishing (EP), chemical polishing, tumbling, etc., followed by various rinsing methods such as ultrasonic pure water rinse, alcoholic rinse, high pressure water rinse, hydrogen per oxide rinse, etc. Although good cavity performance has been obtained lately by various post-EP cleaning methods, the detailed nature about the surface contaminants is still not fully characterized. Further efforts in this area are desired. Prior x-ray photoelectron spectroscopy (XPS) analyses of EPed niobium samples treated with fresh EP acid, demonstrated that the surfaces were covered mainly with the niobium oxide (Nb{sub 2}O{sub 5}) along with carbon, in addition a small quantity of sulfur and fluorine were also found in secondary ion mass spectroscopy (SIMS) analysis. In this article, the authors present the analyses of surface contaminations for a series of EPed niobium samples located at various positions of a single cell niobium cavity followed by ultrapure water rinsing as well as our endeavor to understand the aging effect of EP acid solution in terms of contaminations presence at the inner surface of the cavity with the help of surface analytical tools such as XPS, SIMS, and scanning electron microscope at KEK.

  14. Surfactant-assisted growth of anodic nanoporous niobium oxide with a grained surface

    Energy Technology Data Exchange (ETDEWEB)

    Yoo, Jeong Eun [Department of Chemical Engineering, Inha University, 253 Yonghyun Dong, Nam-Gu, Incheon 402-751 (Korea, Republic of); Choi, Jinsub, E-mail: jinsub@inha.ac.k [Department of Chemical Engineering, Inha University, 253 Yonghyun Dong, Nam-Gu, Incheon 402-751 (Korea, Republic of)

    2010-07-15

    Nanoporous niobium oxide film with a maximum thickness of 520 nm was prepared by anodizing niobium in a mixture of 1 wt% HF, 1 M H{sub 3}PO{sub 4}, and a small amount of Sodium Dodecyl Sulfate (SDS) surfactant. The porosity of the anodic niobium oxide prepared without SDS is irregular with the surface of the oxide suggesting a grained surface pattern rather than an ordered porous structure. A proper amount of SDS addition can prepare a pore arrangement with stripe patterns. The pore depth and surface pattern were strongly affected by the concentration of SDS and bath temperature. We found that the addition of SDS surfactant facilitated improvement in the chemical resistance of niobium oxide, leading to the formation of pores with a longer length compared to those prepared without a SDS surfactant. This can be in part ascribed to the protection of the surface by the physical adsorption of SDS on the surface due to a charge-charge interaction and be in part attributed to the formation of Nb=O bonding on the outermost oxide layer by SDS. When anodization was carried out for 4 h, the surface dissolution of niobium oxide was observed, which means that the maximum tolerance time against chemical dissolution was less than 4 h.

  15. Electron tunneling in tantalum surface layers on niobium

    International Nuclear Information System (INIS)

    Ruggiero, S.T.; Track, E.K.; Prober, D.E.; Arnold, G.B.; DeWeert, M.J.

    1986-01-01

    We have performed electron tunneling measurements on tantalum surface layers on niobium. The tunnel junctions comprise 2000-A-circle Nb base electrodes with 10--100-A-circle in situ--deposited Ta overlayers, an oxide barrier, and Ag, Pb, or Pb-Bi alloy counterelectrodes. The base electrodes were prepared by ion-beam sputter deposition. The characteristics of these junctions have been studied as a function of Ta-layer thickness. These include the critical current, bound-state energy, phonon structure, and oxide barrier shape. We have compared our results for the product I/sub c/R versus tantalum-layer thickness with an extended version of the Gallagher theory which accounts for both the finite mean free path in the Ta overlayers and suppression of the I/sub c/R product due to strong-coupling effects. Excellent fits to the data yield a value of the intrinsic scattering probability for electrons at the Ta/Nb interface of r 2 = 0.01. This is consistent with the value expected from simple scattering off the potential step created by the difference between the Fermi energies of Ta and Nb. We have found a universal empirical correlation in average barrier height phi-bar and width s in the form phi-bar = 6 eV/(s-10 A-circle) for measured junctions which holds both for our data and results for available data in the literature for oxide-barrier junctions. The latter are composed of a wide variety of base and counterelectrode materials. These results are discussed in the general context of oxide growth and compared with results for artificial tunnel barriers

  16. The effect of plasma etching on the surface topography of niobium superconducting radio frequency cavities

    Science.gov (United States)

    Radjenović, B.; Radmilović-Radjenović, M.

    2014-11-01

    In this letter the evolution of the surface topography of a niobium superconducting radio frequency cavity caused by different plasma etching modes (isotropic and anisotropic) is studied by the three-dimensional level set method. The initial rough surface is generated starting from an experimental power spectral density. The time dependence of the rms roughness is analyzed and the growth exponential factors β are determined for two etching modes (isotropic and anisotropic) assuming that isotropic etching is a much more effective mechanism of smoothing. The obtained simulation results could be useful for optimizing the parameters of the etching processes needed to obtain high quality niobium surfaces for superconducting radio frequency cavities.

  17. Surface Characterization of Impurities in Superconducting Niobium for Radio Frequency (RF) Cavities used in Particle Accelerators

    Science.gov (United States)

    Maheshwari, Prateek

    Niobium (Nb) is the material of choice for Superconducting Radio Frequency (SRF) Cavities used in particle accelerators owing to its high critical temperature (Tc = 9.2 K) and critical magnetic field (≈ 200mT). However, niobium tends to harbor interstitial impurities such as H, C, O and N, which are detrimental to cavity performance. Since the magnetic field penetration depth (lambda) of niobium is 40nm, it is important to characterize these impurities using surface characterization techniques. Also, it is known that certain heat treatments improve cavity efficiency via interstitial impurity removal from the surface of niobium. Thus, a systematic study on the effect of these heat treatments on the surface impurity levels is needed. In this work, surface analysis of both heat treated and non heat treated (120°C-1400°C) large grain (single crystal) bulk niobium samples was performed using secondary ion mass spectrometry (SIMS) and Transmission Electron Microscopy (TEM). Impurity levels were compared on the surface using SIMS after various types of heat treatments expected to improve cavity performance, and the effect of these heat treatments on the surface impurities were examined. SIMS characterization of ion implanted standards of C, N, O, D showed that quantification of C, N and O impurities in Nb is achievable and indicated that H is very mobile in Nb. It was hence determined that quantification of H in Nb is not possible using SIMS due to its high diffusivity in Nb. However, a comparative study of the high temperature heat treated (600°C-1400°C) and non heat treated (control) samples revealed that hydrogen levels decreased by upto a factor of 100. This is attributed to the dissociation of the niobium surface oxide layer, which acts as a passivating film on the surface, and subsequent desorption of hydrogen. Reformation of this oxide layer on cool down disallows any re-absorption of hydrogen, indicating that the oxide acts as a surface barrier for

  18. The HIE-ISOLDE Superconducting Cavities: Surface Treatment and Niobium Thin Film Coating

    CERN Document Server

    Lanza, G; Ferreira, L M A; Gustafsson, A E; Pasini, M; Trilhe, P; Palmieri, V

    2010-01-01

    CERN has designed and prepared new facilities for the surface treatment and niobium sputter coating of the HIE-ISOLDE superconducting cavities. We describe here the design choices, as well as the results of the first surface treatments and test coatings.

  19. Measurements of the anomalous RF surface resistance of niobium using a dielectric resonator

    International Nuclear Information System (INIS)

    Moffat, D.; Bolore, M.; Bonin, B.; Jacques, E.; Safa, H.

    1996-01-01

    The surface resistance of high and low residual resistance ratio (RRR) niobium plates at 4.2 K and 1.8 K has been measured as a function of many processing and testing parameters. A dielectric resonator was used instead of a resonant cavity. This resonator offered the ability to make many, sensitive measurements with an efficient use of time and helium. It was found that the surface resistance, R s , of RRR = 190 niobium increased noticeably from the theoretical value if the cooling rate was slower than ∼ 10 K/min. (author)

  20. Dependence of the microwave surface resistance of superconducting niobium on the magnitude of the rf field

    Energy Technology Data Exchange (ETDEWEB)

    Romanenko, A.; Grassellino, A. [Fermi National Accelerator Laboratory, Batavia, Illinois 60510 (United States)

    2013-06-24

    Utilizing difference in temperature dependencies we decoupled Bardeen-Cooper-Schrieffer (BCS) and residual components of the microwave surface resistance of superconducting niobium at all rf fields up to B{sub rf}{approx}115 mT. We reveal that the residual resistance decreases with field at B{sub rf} Less-Than-Or-Equivalent-To 40 mT and strongly increases in chemically treated niobium at B{sub rf}>80 mT. We find that BCS surface resistance is weakly dependent on field in the clean limit, whereas a strong and peculiar field dependence emerges after 120 Degree-Sign C vacuum baking.

  1. Effect of interstitial impurities on the field dependent microwave surface resistance of niobium

    Science.gov (United States)

    Martinello, M.; Grassellino, A.; Checchin, M.; Romanenko, A.; Melnychuk, O.; Sergatskov, D. A.; Posen, S.; Zasadzinski, J. F.

    2016-08-01

    Previous work has demonstrated that the radio frequency surface resistance of niobium resonators is dramatically reduced when nitrogen impurities are dissolved as interstitial in the material. This effect is attributed to the lowering of the Mattis-Bardeen surface resistance with increasing accelerating field; however, the microscopic origin of this phenomenon is poorly understood. Meanwhile, an enhancement of the sensitivity to trapped magnetic field is typically observed for such cavities. In this paper, we conduct a systematic study on these different components contributing to the total surface resistance as a function of different levels of dissolved nitrogen, in comparison with standard surface treatments for niobium resonators. Adding these results together, we are able to show which is the optimum surface treatment that maximizes the Q-factor of superconducting niobium resonators as a function of expected trapped magnetic field in the cavity walls. These results also provide insights on the physics behind the change in the field dependence of the Mattis-Bardeen surface resistance, and of the trapped magnetic vortex induced losses in superconducting niobium resonators.

  2. Surface polishing of niobium for superconducting radio frequency (SRF) cavity applications

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Liang [College of William and Mary, Williamsburg, VA (United States)

    2014-08-01

    Niobium cavities are important components in modern particle accelerators based on superconducting radio frequency (SRF) technology. The interior of SRF cavities are cleaned and polished in order to produce high accelerating field and low power dissipation on the cavity wall. Current polishing methods, buffered chemical polishing (BCP) and electro-polishing (EP), have their advantages and limitations. We seek to improve current methods and explore laser polishing (LP) as a greener alternative of chemical methods. The topography and removal rate of BCP at different conditions (duration, temperature, sample orientation, flow rate) was studied with optical microscopy, scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD). Differential etching on different crystal orientations is the main contributor to fine grain niobium BCP topography, with gas evolution playing a secondary role. The surface of single crystal and bi-crystal niobium is smooth even after heavy BCP. The topography of fine grain niobium depends on total removal. The removal rate increases with temperature and surface acid flow rate within the rage of 0~20 °C, with chemical reaction being the possible dominate rate control mechanism. Surface flow helps to regulate temperature and avoid gas accumulation on the surface. The effect of surface flow rate on niobium EP was studied with optical microscopy, atomic force microscopy (AFM), and power spectral density (PSD) analysis. Within the range of 0~3.7 cm/s, no significant difference was found on the removal rate and the macro roughness. Possible improvement on the micro roughness with increased surface flow rate was observed. The effect of fluence and pulse accumulation on niobium topography during LP was studied with optical microscopy, SEM, AFM, and PSD analysis. Polishing on micro scale was achieved within fluence range of 0.57~0.90 J/cm2, with pulse accumulation adjusted accordingly. Larger area treatment was proved possible by

  3. Dependence of the surface resistance of niobium coated copper cavities on the coating temperature

    International Nuclear Information System (INIS)

    Darriulat, P.; Durand, C.; Janot, P.; Rensing, N.; Weingarten, W.; Bosland, P.; Gobin, J.; Martignac, J.

    1996-01-01

    Six hydro-formed copper 1.5 GHz cavities have been baked and coated with niobium at different temperatures between 100 deg C and 200 deg C, while keeping the other discharge parameters unchanged. Their surface resistance has been measured as a function RF field and trapped magnetic field. Its dependence on deposition temperature confirms earlier indications obtained using 350 MHz LEP cavities that 150 deg C leads to optimal performances. The critical temperatures of Nb/Cu and bulk niobium cavities have also been measured. (author)

  4. Improving the work function of the niobium surface of SRF cavities by plasma processing

    International Nuclear Information System (INIS)

    Tyagi, P.V.; Doleans, M.; Hannah, B.; Afanador, R.; McMahan, C.; Stewart, S.; Mammosser, J.; Howell, M.; Saunders, J.; Degraff, B.; Kim, S.-H.

    2016-01-01

    Highlights: • An in situ plasma processing for SNS SRF cavities has been developed to remove hydrocarbons from cavity surface. • Reactive oxygen plasma is very effective to remove hydrocarbons from niobium top surface. • Reactive oxygen plasma processing increases the work function of niobium surface in the range of 0.5–1.0 eV. • It was observed that hydrocarbons can migrate at plasma cleaned top surface from near surface regions when waiting in vacuum at room temperature. • Multiple cycles of plasma processing with waiting periods in between was found beneficial to mitigate such hydrocarbons migration at plasma cleaned surface. - Abstract: An in situ plasma processing technique using chemically reactive oxygen plasma to remove hydrocarbons from superconducting radio frequency cavity surfaces at room temperature has been developed at the spallation neutron source, at Oak Ridge National Laboratory. To understand better the interaction between the plasma and niobium surface, surface studies on small samples were performed. In this article, we report the results from those surface studies. The results show that plasma processing removes hydrocarbons from top surface and improves the surface work function by 0.5–1.0 eV. Improving the work function of RF surface of cavities can help to improve their operational performance.

  5. Cleaning of niobium surface by plasma of diffuse discharge at atmospheric pressure

    Science.gov (United States)

    Tarasenko, V. F.; Erofeev, M. V.; Shulepov, M. A.; Ripenko, V. S.

    2017-07-01

    Elements composition of niobium surface before and after plasma treatment by runaway electron preionized diffuse discharge was investigated in atmospheric pressure nitrogen flow by means of an Auger electron spectroscopy. Surface characterizations obtained from Auger spectra show that plasma treatment by diffuse discharge after exposure of 120000 pulses provides ultrafine surface cleaning from carbon contamination. Moreover, the surface free energy of the treated specimens increased up to 3 times, that improve its adhesion property.

  6. Preparation of self-organized porous anodic niobium oxide microcones and their surface wettability

    International Nuclear Information System (INIS)

    Oikawa, Y.; Minami, T.; Mayama, H.; Tsujii, K.; Fushimi, K.; Aoki, Y.; Skeldon, P.; Thompson, G.E.; Habazaki, H.

    2009-01-01

    Porous anodic niobium oxide with a pore size of ∼10 nm was formed at 10 V in glycerol electrolyte containing 0.6 mol dm -3 K 2 HPO 4 and 0.2 mol dm -3 K 3 PO 4 at 433 K. After prolonged anodizing for 5.4 ks, niobium oxide microcones develop on the surface. X-ray diffraction patterns of the anodized specimens revealed that the initially formed anodic oxide is amorphous, but an amorphous-to-crystalline transition occurs during anodizing. As a consequence of the preferential chemical dissolution of the initially formed amorphous oxide, due to different solubility of the amorphous and crystalline oxides, crystalline oxide microcones appear on the film surface after prolonged anodizing. The surface is superhydrophilic. After coating with fluorinated alkylsilane, the surface becomes superhydrophobic with a contact angle of 158 o for water. The surface is also oil repellent, with a contact angle as high as 140 o for salad oil.

  7. Improving the work function of the niobium surface of SRF cavities by plasma processing

    Science.gov (United States)

    Tyagi, P. V.; Doleans, M.; Hannah, B.; Afanador, R.; McMahan, C.; Stewart, S.; Mammosser, J.; Howell, M.; Saunders, J.; Degraff, B.; Kim, S.-H.

    2016-04-01

    An in situ plasma processing technique using chemically reactive oxygen plasma to remove hydrocarbons from superconducting radio frequency cavity surfaces at room temperature has been developed at the spallation neutron source, at Oak Ridge National Laboratory. To understand better the interaction between the plasma and niobium surface, surface studies on small samples were performed. In this article, we report the results from those surface studies. The results show that plasma processing removes hydrocarbons from top surface and improves the surface work function by 0.5-1.0 eV. Improving the work function of RF surface of cavities can help to improve their operational performance.

  8. Surface studies of niobium chemically polished under conditions for superconducting radio frequency (SRF) cavity production

    Science.gov (United States)

    Tian, Hui; Reece, Charles E.; Kelley, Michael J.; Wang, Shancai; Plucinski, Lukasz; Smith, Kevin E.; Nowell, Matthew M.

    2006-11-01

    The performance of niobium superconducting radiofrequency (SRF) accelerator cavities is strongly impacted by the topmost several nanometers of the active (interior) surface, especially as influenced by the final surface conditioning treatments. We examined the effect of the most commonly employed treatment, buffered chemical polishing (BCP), on polycrystalline niobium sheet over a range of realistic solution flow rates using electron back scatter diffraction (EBSD), stylus profilometry, atomic force microscopy, laboratory XPS and synchrotron (variable photon energy) XPS, seeking to collect statistically significant datasets. We found that the predominant general surface orientation is (1 0 0), but others are also present and at the atomic-level details of surface plane orientation are more complex. The post-etch surface exhibits micron-scale roughness, whose extent does not change with treatment conditions. The outermost surface consists of a few-nm thick layer of niobium pentoxide, whose thickness increases with solution flow rate to a maximum of 1.3-1.4 times that resulting from static solution. The standard deviation of the roughness measurements is ±30% and that of the surface composition is ±5%.

  9. Surface studies of niobium chemically polished under conditions for superconducting radio frequency (SRF) cavity production

    Energy Technology Data Exchange (ETDEWEB)

    Tian Hui [Thomas Jefferson National Accelerator Facility and College of William and Mary (United States); Reece, Charles E. [Thomas Jefferson National Accelerator Facility and College of William and Mary (United States); Kelley, Michael J. [Thomas Jefferson National Accelerator Facility and College of William and Mary (United States)]. E-mail: mkelley@jlab.org; Wang Shancai [Department of Physics, Boston University (United States); Plucinski, Lukasz [Department of Physics, Boston University (United States); Smith, Kevin E. [Department of Physics, Boston University (United States); Nowell, Matthew M. [EDAX TSL (United States)

    2006-11-30

    The performance of niobium superconducting radiofrequency (SRF) accelerator cavities is strongly impacted by the topmost several nanometers of the active (interior) surface, especially as influenced by the final surface conditioning treatments. We examined the effect of the most commonly employed treatment, buffered chemical polishing (BCP), on polycrystalline niobium sheet over a range of realistic solution flow rates using electron back scatter diffraction (EBSD), stylus profilometry, atomic force microscopy, laboratory XPS and synchrotron (variable photon energy) XPS, seeking to collect statistically significant datasets. We found that the predominant general surface orientation is (1 0 0), but others are also present and at the atomic-level details of surface plane orientation are more complex. The post-etch surface exhibits micron-scale roughness, whose extent does not change with treatment conditions. The outermost surface consists of a few-nm thick layer of niobium pentoxide, whose thickness increases with solution flow rate to a maximum of 1.3-1.4 times that resulting from static solution. The standard deviation of the roughness measurements is {+-}30% and that of the surface composition is {+-}5%.

  10. Surface Studies of Niobium Chemically Polished Under Conditions for Superconducting Radio Frequency (SRF) Cavity Production

    Energy Technology Data Exchange (ETDEWEB)

    Tian,H.; Reece, C.; Kelley, M.; Wang, S.; Plucinski, L.; Smith, K.; Nowell, M.

    2006-01-01

    The performance of niobium superconducting radiofrequency (SRF) accelerator cavities is strongly impacted by the topmost several nanometers of the active (interior) surface, especially as influenced by the final surface conditioning treatments. We examined the effect of the most commonly employed treatment, buffered chemical polishing (BCP), on polycrystalline niobium sheet over a range of realistic solution flow rates using electron back scatter diffraction (EBSD), stylus profilometry, atomic force microscopy, laboratory XPS and synchrotron (variable photon energy) XPS, seeking to collect statistically significant datasets. We found that the predominant general surface orientation is (1 0 0), but others are also present and at the atomic-level details of surface plane orientation are more complex. The post-etch surface exhibits micron-scale roughness, whose extent does not change with treatment conditions. The outermost surface consists of a few-nm thick layer of niobium pentoxide, whose thickness increases with solution flow rate to a maximum of 1.3-1.4 times that resulting from static solution. The standard deviation of the roughness measurements is {+-}30% and that of the surface composition is {+-}5%.

  11. Advancement in the Understanding of the Field and Frequency Dependent Microwave Surface Resistance of Niobium

    Energy Technology Data Exchange (ETDEWEB)

    Martinello, M. [Fermilab; Aderhold, S. [Fermilab; Chandrasekaran, S. K. [Fermilab; Checchin, M. [Fermilab; Grassellino, A. [Fermilab; Melnychuk, O. [Fermilab; Posen, S. [Fermilab; Romanenko, A. [Fermilab; Sergatskov, D. A. [Fermilab

    2017-07-24

    The radio-frequency surface resistance of niobium resonators is incredibly reduced when nitrogen impurities are dissolved as interstitial in the material, conferring ultra-high Q-factors at medium values of accelerating field. This effect has been observed in both high and low temperature nitrogen treatments. As a matter of fact, the peculiar anti Q-slope observed in nitrogen doped cavities, i.e. the decreasing of the Q-factor with the increasing of the radio-frequency field, come from the decreasing of the BCS surface resistance component as a function of the field. Such peculiar behavior has been considered consequence of the interstitial nitrogen present in the niobium lattice after the doping treatment. The study here presented show the field dependence of the BCS surface resistance of cavities with different resonant frequencies, such as: 650 MHz, 1.3 GHz, 2.6 GHz and 3.9 GHz, and processed with different state-of-the-art surface treatments. These findings show for the first time that the anti Q-slope might be seen at high frequency even for clean Niobium cavities, revealing useful suggestion on the physics underneath the anti Q-slope effect.

  12. Improvement and protection of niobium surface superconductivity by atomic layer deposition and heat treatment

    Energy Technology Data Exchange (ETDEWEB)

    Proslier, T.; /IIT, Chicago /Argonne; Zasadzinski, J.; /IIT, Chicago; Moore, J.; Pellin, M.; Elam, J.; /Argonne; Cooley, L.; /Fermilab; Antoine, C.; /Saclay

    2008-11-01

    A method to treat the surface of Nb is described, which potentially can improve the performance of superconducting rf cavities. We present tunneling and x-ray photoemission spectroscopy measurements at the surface of cavity-grade niobium samples coated with a 3 nm alumina overlayer deposited by atomic layer deposition. The coated samples baked in ultrahigh vacuum at low temperature degraded superconducting surface. However, at temperatures above 450 C, the tunneling conductance curves show significant improvements in the superconducting density of states compared with untreated surfaces.

  13. Observation of Stable Low Surface Resistance in Large-Grain Niobium SRF Cavities

    Energy Technology Data Exchange (ETDEWEB)

    Geng, Rongli [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Huang, Shichun [Institute of Modern Physics (IMP)/Chinese Academy of Sciences (CAS), Lanzhou (China)

    2016-05-01

    Low surface resistance, or high unloaded quality factor (Q0), superconducting radio frequency (SRF) cavities are being pursued actively nowadays as their application in large-scale CW SRF accelerators can save capital and operational cost in cryogenics. There are different options in realization of such cavities. One of them is the large-grain (LG) niobium cavity. In this contribution, we present new experimental results in evaluation of LG niobium cavities cooled down in the presence of an external magnetic field. High Q0 values are achieved even with an ambient magnetic field of up to 100 mG. More over, it is observed that these high Q0 values are super-robust against repeated quench, literally not affected at all after the cavity being deliberately quenched for hundreds of times in the presence of an ambient magnetic field of up to 200 mG.

  14. Measurements of the anomalous RF surface resistance of niobium using a dielectric resonator

    International Nuclear Information System (INIS)

    Moffat, D.; Bolore, M.; Bonin, B.; Jacques, E.; Safa, H.

    1996-01-01

    The surface resistance of high and low RRR niobium plates at 4.2 K and 1.8 K has been measured as a function of many processing and testing parameters. A dielectric resonator was used instead of a resonant cavity. This resonator offered the ability to make many, sensitive measurements with an efficient use of time and helium. It was found that the surface resistance, R s , of RRR=190 niobium increased noticeably from the theoretical value if the cooling rate was slower than∼10 K/min. Fast-cooled plates subsequently warmed to 130 K, and the recooled, showed a larger increase in R s than plates warmed to either 100 K or 160 K. Both chemically polished, and electropolished RRR=190 plates showed the effects of the 'Q-virus'. A heat treatment of 200 deg C made the RRR=190 plates less susceptible to the 'Q-virus'. RRR=30 niobium plates did not show any increase in R s , regardless of treatment. (author)

  15. On the field dependent surface resistance of niobium on copper cavities

    CERN Document Server

    Junginger, Tobias

    2015-01-01

    The surface resistance Rs of superconducting cavities prepared by sputter coating a thin niobium film on a copper substrate increases significantly stronger with the applied RF field compared to cavities of bulk material. A possible cause is that due to the thermal boundary resistance between the copper substrate and the niobium film Rs is enhanced due to global heating of the inner cavity wall. Introducing helium gas in the cavity and measuring its pressure as a function of applied field allowed to conclude that the inner surface of the cavity is heated up by only 60+/-60 mK when Rs increases with Eacc by 100 nOhm. This is more than one order of magnitude less than what one would expect from global heating. Additionally the effect of cooldown speed and low temperature baking have been investigated in the framework of these experiments. It is shown that for current state of the art niobium on copper cavities there is only a detrimental effect of low temperature baking. A fast cooldown results in a lowered Rs.

  16. Laser Processing on the Surface of Niobium Superconducting Radio-Frequency Accelerator Cavities

    Science.gov (United States)

    Singaravelu, Senthilraja; Klopf, Michael; Krafft, Geoffrey; Kelley, Michael

    2011-03-01

    Superconducting Radio frequency (SRF) niobium cavities are at the heart of an increasing number of particle accelerators.~ Their performance is dominated by a several nm thick layer at the interior surface. ~Maximizing its smoothness is found to be critical and aggressive chemical treatments are employed to this end.~ We describe laser-induced surface melting as an alternative ``greener'' approach.~ Modeling guided selection of parameters for irradiation with a Q-switched Nd:YAG laser.~ The resulting topography was examined by SEM, AFM and Stylus Profilometry.

  17. Method for the manufacture of a superconductive Nb3Sn layer on a niobium surface for high frequency applications

    International Nuclear Information System (INIS)

    Martens, H.

    1978-01-01

    A manufacturing method for depositing an Nb 3 Sn layer on a niobium surface for high frequency applications comprising developing a tin vapor atmosphere which also contains a highly volatile tin compound in the gaseous state, and holding the portions of the surface which are to be provided with the Nb 3 Sn layer at a temperature of between 900 0 and 1500 0 C for a predetermined period of time to form the Nb 3 Sn layer permitting niobium surfaces of any shape to be provided with Nb 3 Sn layers of high uniformity and quality

  18. Surface ferromagnetism and superconducting properties of nanocrystalline niobium nitride

    International Nuclear Information System (INIS)

    Shipra, R.; Kumar, Nitesh; Sundaresan, A.

    2013-01-01

    Nanocrystalline δ-NbN x samples have been synthesized by reacting NbCl 5 and urea at three different temperatures. A comparison of their structural, magnetic, transport and thermal properties is reported in the present study. The size of the particles and their agglomeration extent increase with increasing reaction temperature. The sample prepared at 900 °C showed the highest superconducting transition temperature (T c ) of 16.2 K with a transition width, ∼1.8 K, as obtained from the resistivity measurement on cold-pressed bars. Above T c , magnetization measurements revealed the presence of surface ferromagnetism which coexists with superconductivity below T c . Heat capacity measurements confirm superconductivity with strong electron–phonon coupling constant. The sample prepared at 800 °C shows a lower T c (10 K) while that prepared at 700 °C exhibit no superconductivity down to the lowest temperature (3 K) measured. - Highlights: ► Synthesis of δ-NbN nanoparticles by urea nitridation of NbCl 5 . ► Superconducting transition temperature (T c ) is 16.2 K. ► Superconductivity and surface ferromagnetism coexist in the nanoparticles. ► Effect of size and agglomeration on the physical properties of nanoparticles

  19. Formation of laser-induced periodic surface structures on niobium by femtosecond laser irradiation

    International Nuclear Information System (INIS)

    Pan, A.; Dias, A.; Gomez-Aranzadi, M.; Olaizola, S. M.; Rodriguez, A.

    2014-01-01

    The surface morphology of a Niobium sample, irradiated in air by a femtosecond laser with a wavelength of 800 nm and pulse duration of 100 fs, was examined. The period of the micro/nanostructures, parallel and perpendicularly oriented to the linearly polarized fs-laser beam, was studied by means of 2D Fast Fourier Transform analysis. The observed Laser-Induced Periodic Surface Structures (LIPSS) were classified as Low Spatial Frequency LIPSS (periods about 600 nm) and High Spatial Frequency LIPSS, showing a periodicity around 300 nm, both of them perpendicularly oriented to the polarization of the incident laser wave. Moreover, parallel high spatial frequency LIPSS were observed with periods around 100 nm located at the peripheral areas of the laser fingerprint and overwritten on the perpendicular periodic gratings. The results indicate that this method of micro/nanostructuring allows controlling the Niobium grating period by the number of pulses applied, so the scan speed and not the fluence is the key parameter of control. A discussion on the mechanism of the surface topology evolution was also introduced

  20. Formation of laser-induced periodic surface structures on niobium by femtosecond laser irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Pan, A.; Dias, A.; Gomez-Aranzadi, M.; Olaizola, S. M. [CIC microGUNE, Goiru Kalea 9 Polo Innovación Garaia, 20500 Arrasate-Mondragón (Spain); CEIT-IK4 and Tecnun, University of Navarra, Manuel Lardizábal 15, 20018 San Sebastián (Spain); Rodriguez, A. [CIC microGUNE, Goiru Kalea 9 Polo Innovación Garaia, 20500 Arrasate-Mondragón (Spain)

    2014-05-07

    The surface morphology of a Niobium sample, irradiated in air by a femtosecond laser with a wavelength of 800 nm and pulse duration of 100 fs, was examined. The period of the micro/nanostructures, parallel and perpendicularly oriented to the linearly polarized fs-laser beam, was studied by means of 2D Fast Fourier Transform analysis. The observed Laser-Induced Periodic Surface Structures (LIPSS) were classified as Low Spatial Frequency LIPSS (periods about 600 nm) and High Spatial Frequency LIPSS, showing a periodicity around 300 nm, both of them perpendicularly oriented to the polarization of the incident laser wave. Moreover, parallel high spatial frequency LIPSS were observed with periods around 100 nm located at the peripheral areas of the laser fingerprint and overwritten on the perpendicular periodic gratings. The results indicate that this method of micro/nanostructuring allows controlling the Niobium grating period by the number of pulses applied, so the scan speed and not the fluence is the key parameter of control. A discussion on the mechanism of the surface topology evolution was also introduced.

  1. Effect of Different Cutting Techniques on the Surface Morphology and Composition of Niobium

    International Nuclear Information System (INIS)

    Cooper, C.A.; Wu, A.; Bauer, P.; Antoine, C.

    2009-01-01

    The surface morphology and chemical purity of superconducting radio frequency (SRF) niobium cavities are very important for proper accelerator operation. Typically on the order of 120 micrometers of niobium (Nb) is removed from cavities to remove damage done during the forming of Nb sheets and cavities. A study was done to find the effect of cutting or finishing Nb with a band saw, diamond saw, electrical discharge machining (EDM) wire, garnet water jet, sheer, and mill. Surface contamination of the samples was measured before and after buffered chemical polish (BCP) by secondary ion mass spectroscopy (SIMS), energy dispersive spectroscopy (EDS), and by measuring relative resistivity ratios (RRRs). Surface morphology was examined with a digital microscope, a surface profilometer and scanning electron microscope (SEM). It was found that all techniques altered the top 3-5 micrometers of the Nb. It was also found by SIMS that the water jet technique introduced the most hydrogen and oxygen to the Nb in the first 2.5 micrometers of the sample. The EDM wire cutting technique introduced the least amount of hydrogen to the Nb. After 5 micrometers were etched away by BCP on the various samples, no contaminants were found except on the water jet cut samples. Even after 20 micrometers of Nb removal silica could be seen on the surface with EDS. The water jet produced the roughest surface with 50-100 micrometer deep pits made from embedded garnet particles. It was found that the garnet water jet damages the surface to the point where even the typical 120 micrometers of BCP etching may not remove all the defects created

  2. Niobium, catalyst repair kit

    International Nuclear Information System (INIS)

    Tanabe, K.

    1991-01-01

    This paper reports that niobium oxides, when small amounts are added to known catalysts, enhance catalytic activity and selectivity and prolong catalyst life. Moreover, niobium oxides exhibit a pronounced effect as supports of metal or metal oxide catalysts. Recently we found that the surface acidity of hydrated niobium pentoxide, niobic acid (Nb 2 O 5 · nH 2 O), corresponds to the acidity of 70% sulfuric acid and exhibits high catalytic activity, selectivity, and stability for acid-catalyzed reactions in which water molecules participate. Although there are few differences in electronegativity and ionic radius between niobium and its neighbors in the periodic table, it is interesting that the promoter effect, support effect, and acidic nature of niobium compounds are quite different from those of compounds of the surrounding elements. Here we review what's known of niobium compounds from the viewpoint of their pronounced catalytic behavior

  3. Fluxon induced surface resistance and field emission in niobium films at 1.5 GHz

    CERN Document Server

    Benvenuti, Cristoforo; Darriulat, Pierre; Peck, M A; Valente, A M; Van't Hof, C A

    2001-01-01

    The surface resistance of superconducting niobium films induced by the presence of trapped magnetic flux, presumably in the form of a pinned fluxon lattice, is shown to be modified by the presence of a field emitting impurity or defect. The modification takes the form of an additional surface resistance proportional to the density of the fluxon lattice and increasing linearly with the amplitude of the microwave above a threshold significantly lower than the field emission threshold. Such an effect, a precursor of electron emission, is observed for the first time in a study using radiofrequency cavities operating at their fundamental 1.5 GHz frequency. The measured properties of the additional surface resistance severely constrain possible explanations of the observed effect. (23 refs).

  4. Roughness analysis applied to niobium thin films grown on MgO(001) surfaces for superconducting radio frequency cavity applications

    Science.gov (United States)

    Beringer, D. B.; Roach, W. M.; Clavero, C.; Reece, C. E.; Lukaszew, R. A.

    2013-02-01

    This paper describes surface studies to address roughness issues inherent to thin film coatings deposited onto superconducting radio frequency (SRF) cavities. This is particularly relevant for multilayered thin film coatings that are being considered as a possible scheme to overcome technical issues and to surpass the fundamental limit of ˜50MV/m accelerating gradient achievable with bulk niobium. In 2006, a model by Gurevich [Appl. Phys. Lett. 88, 012511 (2006)APPLAB0003-695110.1063/1.2162264] was proposed to overcome this limit that involves coating superconducting layers separated by insulating ones onto the inner walls of the cavities. Thus, we have undertaken a systematic effort to understand the dynamic evolution of the Nb surface under specific deposition thin film conditions onto an insulating surface in order to explore the feasibility of the proposed model. We examine and compare the morphology from two distinct Nb/MgO series, each with its own epitaxial registry, at very low growth rates and closely examine the dynamical scaling of the surface features during growth. Further, we apply analysis techniques such as power spectral density to the specific problem of thin film growth and roughness evolution to qualify the set of deposition conditions that lead to successful SRF coatings.

  5. Roughness analysis applied to niobium thin films grown on MgO(001 surfaces for superconducting radio frequency cavity applications

    Directory of Open Access Journals (Sweden)

    D. B. Beringer

    2013-02-01

    Full Text Available This paper describes surface studies to address roughness issues inherent to thin film coatings deposited onto superconducting radio frequency (SRF cavities. This is particularly relevant for multilayered thin film coatings that are being considered as a possible scheme to overcome technical issues and to surpass the fundamental limit of ∼50  MV/m accelerating gradient achievable with bulk niobium. In 2006, a model by Gurevich [Appl. Phys. Lett. 88, 012511 (2006APPLAB0003-695110.1063/1.2162264] was proposed to overcome this limit that involves coating superconducting layers separated by insulating ones onto the inner walls of the cavities. Thus, we have undertaken a systematic effort to understand the dynamic evolution of the Nb surface under specific deposition thin film conditions onto an insulating surface in order to explore the feasibility of the proposed model. We examine and compare the morphology from two distinct Nb/MgO series, each with its own epitaxial registry, at very low growth rates and closely examine the dynamical scaling of the surface features during growth. Further, we apply analysis techniques such as power spectral density to the specific problem of thin film growth and roughness evolution to qualify the set of deposition conditions that lead to successful SRF coatings.

  6. Roughness analysis applied to niobium thin films grown on MgO(001) surfaces for superconducting radio frequency cavity applications

    Energy Technology Data Exchange (ETDEWEB)

    Beringer, D. B. [College of William and Mary, Williamsburg, VA (United States). Dept. of Physics; Roach, W. M. [College of William and Mary, Williamsburg, VA (United States). Dept. of Applied Science; Clavero, C. [College of William and Mary, Williamsburg, VA (United States). Dept. of Applied Science; Reece, C. E. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Lukaszew, R. A. [College of William and Mary, Williamsburg, VA (United States). Dept. of Physics; College of William and Mary, Williamsburg, VA (United States). Dept. of Applied Science

    2013-02-05

    This paper describes surface studies to address roughness issues inherent to thin film coatings deposited onto superconducting radio frequency (SRF) cavities. This is particularly relevant for multilayered thin film coatings that are being considered as a possible scheme to overcome technical issues and to surpass the fundamental limit of ~500 MV/m accelerating gradient achievable with bulk niobium. In 2006, a model by Gurevich [ Appl. Phys. Lett. 88 012511 (2006)] was proposed to overcome this limit that involves coating superconducting layers separated by insulating ones onto the inner walls of the cavities. Thus, we have undertaken a systematic effort to understand the dynamic evolution of the Nb surface under specific deposition thin film conditions onto an insulating surface in order to explore the feasibility of the proposed model. We examine and compare the morphology from two distinct Nb/MgO series, each with its own epitaxial registry, at very low growth rates and closely examine the dynamical scaling of the surface features during growth. Further, we apply analysis techniques such as power spectral density to the specific problem of thin film growth and roughness evolution to qualify the set of deposition conditions that lead to successful SRF coatings.

  7. Calculating the Jc, B, T surface for commercial niobium tin conductors using a reduced state model

    International Nuclear Information System (INIS)

    Green, M.A.

    1993-07-01

    This report presents a method for calculating the J c , B, T critical surface for commercial grade niobium tin given an effective T c and B c2 and J c over a range of magnetic inductions B. Given the effective T c and B c2 and J c , one can estimate the J c over a range of magnetic inductions from 0.1 T to 0.8 times effective B c2 and a range of temperatures from 1.5 K to about 14 K. The effects of conductor strain can also be estimated using the method. A comparison between calculated values of J c and measurements is illustrated for a number of cases. The method presented in this report can be used to estimate the performance of niobium tin in magnets at temperatures different from those where measured data is available. The method of calculating the J c can also be used to estimate the effects of superconductor magnetization on the field quality at low fields

  8. Influence of surface effects on the performance of lead-niobium-germanate optical waveguides

    International Nuclear Information System (INIS)

    Munoz-Martin, D.; Gonzalo, J.; Fernandez-Navarro, J.M.; Siegel, J.; Afonso, C.N.

    2007-01-01

    Lead-niobium-germanate planar waveguides have been produced by pulsed laser deposition. The composition of the waveguides is found to be relatively weakly dependent on the laser fluence, while their surface morphology is affected dramatically. Smooth surfaces are obtained for a narrow fluence range centered at 2.0 J/cm 2 , while particulates having typical diameters of 2 , which is close to the value of the bulk glass, and remains constant at higher fluences. Propagation losses show instead a minimum (∼6.5 dB/cm) at 2.0 J/cm 2 . The characteristics of the ablation process that leads to the ejection of solid particulates or molten droplets as well as the increase of the waveguides density on increasing the fluence are discussed to be responsible for the observed optical behavior

  9. Experimental and Theoretical Studies on Corrosion Inhibition of Niobium and Tantalum Surfaces by Carboxylated Graphene Oxide

    Directory of Open Access Journals (Sweden)

    Valbonë Mehmeti

    2018-05-01

    Full Text Available The corrosion of two different metals, niobium and tantalum, in aqueous sulfuric acid solution has been studied in the presence and absence of carboxylated graphene oxide. Potentiodynamic measurements indicate that this nanomaterial inhibits corrosion due to its adsorption on the metal surfaces. The adsorbed layer of carboxylated graphene hinders two electrochemical reactions: the oxidation of the metal and the transport of metal ions from the metal to the solution but also hydrogen evolution reaction by acting as a protective barrier. The adsorption behavior at the molecular level of the carboxylated graphene oxide with respect to Nb, NbO, Ta, and TaO (111 surfaces is also investigated using Molecular Dynamic and Monte Carlo calculations.

  10. Three-dimensional simulations of the surface topography evolution of niobium superconducting radio frequency cavities

    Directory of Open Access Journals (Sweden)

    Rađenović Branislav M.

    2014-01-01

    Full Text Available This paper contains results of the three-dimensional simulations of the surface topography evolution of the niobium superconducting radio frequency cavities during isotropic and anisotropic etching modes. The initial rough surface is determined from the experimental power spectral density. The simulation results based on the level set method reveal that the time dependence of the root mean square roughness obeys Family-Viscek scaling law. The growth exponential factors b are determined for both etching modes. Exponential factor for the isotropic etching is 100 times lower than that for the anisotropic etching mode reviling that the isotropic etching is very useful mechanism of the smoothing. [Projekat Ministarstva nauke Republike Srbije, br. O171037 i br. III45006

  11. Study of the surface resistance of niobium sputter-coated copper cavities

    CERN Document Server

    Benvenuti, Cristoforo; Campisi, I E; Darriulat, Pierre; Peck, M A; Russo, R; Valente, A M

    1999-01-01

    A systematic study of the superconducting properties of niobium films deposited on the inner wall of copper radiofrequency cavities is presented. Films are grown by sputtering with different discharge gases (Xe, Kr, Ar and Ar/Ne mixtures) on substrates prepared under different conditions. The measured quantities include the surface resistance at 1.5 GHz, the critical temperature and the penetration depth. The surface resistance is analyzed in terms of its dependence on temperature, RF field and the density of trapped fluxons. Once allowance for electron scattering is made by means of a single mean free path parameter, good agreement with BCS theory is observed. The residual resistance is observed to be essentially noncorrelated with the superconducting properties, although influenced by specific coating conditions. On occasions, very low residual resistances, in the nano-ohm range, have been maintained over a broad range of RF field, indicating the absence of fundamental limitations specific to the film techn...

  12. A novel approach to characterizing the surface topography of niobium superconducting radio frequency (SRF) accelerator cavities

    Science.gov (United States)

    Tian, Hui; Ribeill, Guilhem; Xu, Chen; Reece, Charles E.; Kelley, Michael J.

    2011-03-01

    As superconducting niobium radio-frequency (SRF) cavities approach fundamental material limits, there is increased interest in understanding the details of topographical influences on realized performance limitations. Micro- and nano-roughness are implicated in both direct geometrical field enhancements as well as complications of the composition of the 50 nm surface layer in which the super-currents typically flow. Interior surface chemical treatments such as buffered chemical polishing (BCP) and electropolishing (EP) used to remove mechanical damage leave surface topography, including pits and protrusions of varying sharpness. These may promote RF magnetic field entry, locally quenching superconductivity, so as to degrade cavity performance. A more incisive analysis of surface topography than the widely used average roughness is needed. In this study, a power spectral density (PSD) approach based on Fourier analysis of surface topography data acquired by both stylus profilometry and atomic force microscopy (AFM) is introduced to distinguish the scale-dependent smoothing effects, resulting in a novel qualitative and quantitative description of Nb surface topography. The topographical evolution of the Nb surface as a function of different steps of well-controlled EP is discussed. This study will greatly help to identify optimum EP parameter sets for controlled and reproducible surface levelling of Nb for cavity production.

  13. A novel approach to characterizing the surface topography of niobium superconducting radio frequency (SRF) accelerator cavities

    International Nuclear Information System (INIS)

    Tian Hui; Ribeill, Guilhem; Xu Chen; Reece, Charles E.; Kelley, Michael J.

    2011-01-01

    As superconducting niobium radio-frequency (SRF) cavities approach fundamental material limits, there is increased interest in understanding the details of topographical influences on realized performance limitations. Micro- and nano-roughness are implicated in both direct geometrical field enhancements as well as complications of the composition of the 50 nm surface layer in which the super-currents typically flow. Interior surface chemical treatments such as buffered chemical polishing (BCP) and electropolishing (EP) used to remove mechanical damage leave surface topography, including pits and protrusions of varying sharpness. These may promote RF magnetic field entry, locally quenching superconductivity, so as to degrade cavity performance. A more incisive analysis of surface topography than the widely used average roughness is needed. In this study, a power spectral density (PSD) approach based on Fourier analysis of surface topography data acquired by both stylus profilometry and atomic force microscopy (AFM) is introduced to distinguish the scale-dependent smoothing effects, resulting in a novel qualitative and quantitative description of Nb surface topography. The topographical evolution of the Nb surface as a function of different steps of well-controlled EP is discussed. This study will greatly help to identify optimum EP parameter sets for controlled and reproducible surface levelling of Nb for cavity production.

  14. Integrated Surface Topography Characterization of Variously Polished Niobium for Superconducting Particle Accelerators

    International Nuclear Information System (INIS)

    Tian, Hui; Reece, Charles; Kelley, Michael; Ribeill, G.

    2009-01-01

    As superconducting niobium radio-frequency (SRF) cavities approach fundamental material limits, there is increased interest in understanding the details of topographical influences on realized performance limitations. Micro-and nano-roughness are implicated in both direct geometrical field enhancements as well as complications of the composition of the 50 nm surface layer in which the super-currents flow. Interior surface chemical polishing (BCP/EP) to remove mechanical damage leaves surface topography, including pits and protrusions of varying sharpness. These may promote RF magnetic field entry, locally quenching superconductivity, so as to degrade cavity performance. A more incisive analysis of surface topography than the widely-used average roughness is needed. In this study, a power spectral density (PSD) approach based on Fourier analysis of surface topography data acquired by both stylus profilometry and atomic force microscopy (AFM) is being used to distinguish the scale-dependent smoothing effects. The topographical evolution of the Nb surface as a function of different steps of EP is reported, resulting in a novel qualitative and quantitative description of Nb surface topography.

  15. Effect of non-uniform surface resistance on the quality factor of superconducting niobium cavity

    Science.gov (United States)

    Tan, Weiwei; Lu, Xiangyang; Yang, Ziqin; Zhao, Jifei; Yang, Deyu; Yang, Yujia

    2016-08-01

    The formula Rs = G /Q0 is commonly used in the calculation of the surface resistance of radio frequency niobium superconducting cavities. The applying of such equation is under the assumption that surface resistance is consistent over the cavity. However, the distribution of the magnetic field varies over the cavity. The magnetic field in the equator is much higher than that in the iris. According to Thermal Feedback Theory, it leads non-uniform distribution of the density of heat flux, which results in a different temperature distribution along the cavity inter surface. The BCS surface resistance, which depends largely on the temperature, is different in each local inner surface. In this paper, the effect of surface non-uniform resistance on the quality factor has been studied, through the calculation of Q0 in the original definition of it. The results show that it is necessary to consider the non-uniform distribution of magnetic field when the accelerating field is above 20 MV/m for TESLA cavities. Also, the effect of inhomogeneity of residual resistance on the quality factor is discussed. Its distribution barely affects the quality factor.

  16. Control of morphology and surface wettability of anodic niobium oxide microcones formed in hot phosphate-glycerol electrolytes

    International Nuclear Information System (INIS)

    Yang, Shu; Habazaki, Hiroki; Fujii, Takashi; Aoki, Yoshitaka; Skeldon, Peter; Thompson, George E.

    2011-01-01

    Highlights: → Anodic niobium oxide microcones with nanofiber morphology are formed simply by anodizing. → The cone size and its tip angle are controlled by anodizing condition. → The surface shows extremely high contact angle for water after coating with a fluoroalkyl layer. - Abstract: We report the fabrication of superhydrophobic surfaces with a hierarchical morphology by self-organized anodizing process. Simply by anodizing of niobium metal in hot phosphate-glycerol electrolyte, niobium oxide microcones, consisting of highly branched oxide nanofibers, develop on the surface. The size of the microcones and their tip angles are controlled by changing the applied potential difference in anodizing and the water content in the electrolyte. Reduction of the water content increases the size of the microcones, with the nanofibers changing to nanoparticles. The size of microcones is also reduced by increasing the applied potential difference, without influencing the tip angle. The hierarchical oxide surfaces are superhydrophilic, with static contact angles close to 0 o . Coating of the anodic oxide films with a monolayer of fluoroalkyl phosphate makes the surfaces superhydrophobic with a contact angle for water as high as 175 o and a very small contact angle hysteresis of only 2 o . The present results indicate that the larger microcones with smaller tip angles show the higher contact angle for water.

  17. Study of the surface crystallization and resistance to dissolution of niobium phosphate glasses for nuclear waste immobilization

    International Nuclear Information System (INIS)

    Vieira, Heveline

    2008-01-01

    The surface crystallization and the dissolution rate of three phosphate glass compositions containing different amounts of niobium oxide were studied. The glasses were named Nb30, Nb37, and Nb44 according to the nominal content of niobium oxide in the glass composition. The three compositions were evaluated keeping the P 2 O 5 /K 2 O ratio constant and varying the amount of Nb 2 O 5 . These glasses were produced by melting appropriate chemical compounds at 1500 deg C for 0.5 hour. The crystalline phases which were nucleated on the glass surface after heat treatment were determined by X-ray diffraction. The crystalline structures depend on the amount of niobium oxide in the glass composition. The crystal morphologies were observed by using an optical microscope, and their characteristics are specific for each kind of crystalline phase. The crystal growth rate and the surface nuclei density were determined for each glass composition, and they depend on each crystalline phase nucleated on the surface. From the differential thermal analysis curves it was determined that the Nb44 glass containing 46.5 mol por cent of niobium oxide is the most thermally stable against crystallization when compared to the Nb30 and Nb37 glasses. According to the activation energies determined for crystal growth on the surface of each glass type, the Nb44 glass can also be considered the most resistant one against crystallization. The dissolution rate for the Nb44 glass after 14 days immersed in an aqueous solution with pH equals to 7 at 90 deg C is the lowest (9.0 x 10 -7 g. cm -2 . day -1 ) when compared to the other two glass compositions. The dissolution rates in acidic and neutral solutions of all studied glasses meet the international standards for materials which can be used in the immobilization of nuclear wastes. (author)

  18. Etching of Niobium Sample Placed on Superconducting Radio Frequency Cavity Surface in Ar/CL2 Plasma

    International Nuclear Information System (INIS)

    Upadhyay, Janardan; Phillips, Larry; Valente, Anne-Marie

    2011-01-01

    Plasma based surface modification is a promising alternative to wet etching of superconducting radio frequency (SRF) cavities. It has been proven with flat samples that the bulk Niobium (Nb) removal rate and the surface roughness after the plasma etchings are equal to or better than wet etching processes. To optimize the plasma parameters, we are using a single cell cavity with 20 sample holders symmetrically distributed over the cell. These holders serve the purpose of diagnostic ports for the measurement of the plasma parameters and for the holding of the Nb sample to be etched. The plasma properties at RF (100 MHz) and MW (2.45 GHz) frequencies are being measured with the help of electrical and optical probes at different pressures and RF power levels inside of this cavity. The niobium coupons placed on several holders around the cell are being etched simultaneously. The etching results will be presented at this conference.

  19. Etching of Niobium Sample Placed on Superconducting Radio Frequency Cavity Surface in Ar/CL2 Plasma

    Energy Technology Data Exchange (ETDEWEB)

    Janardan Upadhyay, Larry Phillips, Anne-Marie Valente

    2011-09-01

    Plasma based surface modification is a promising alternative to wet etching of superconducting radio frequency (SRF) cavities. It has been proven with flat samples that the bulk Niobium (Nb) removal rate and the surface roughness after the plasma etchings are equal to or better than wet etching processes. To optimize the plasma parameters, we are using a single cell cavity with 20 sample holders symmetrically distributed over the cell. These holders serve the purpose of diagnostic ports for the measurement of the plasma parameters and for the holding of the Nb sample to be etched. The plasma properties at RF (100 MHz) and MW (2.45 GHz) frequencies are being measured with the help of electrical and optical probes at different pressures and RF power levels inside of this cavity. The niobium coupons placed on several holders around the cell are being etched simultaneously. The etching results will be presented at this conference.

  20. Investigation of the niobium-oxygen system under low pressure and between 550 K and 2350 K: solid solution, surface overlay and reactivity

    International Nuclear Information System (INIS)

    Jupille, Jacques

    1974-09-01

    This research thesis addresses the behaviour of transition metals when interacting with oxygen, more particularly in the case of phase formation, but also adsorption and desorption which occur in the case of interaction with low pressure oxygen. It focuses on the case of niobium in solid solution. After a description of phases present in the niobium-oxygen system, and a discussion of reactivities of oxygen and water vapour, the author describes the experimental methods (apparatus and installations, samples, measured values), discusses the study of the surface-volume transfer constant of the niobium-oxygen solution, and the niobium-oxygen interaction mechanisms at high (superior to 1700 K) and low (inferior to 1000 K) temperatures: oxide desorption, oxygen reaction kinetics

  1. Possible influence of surface oxides on the optical response of high-purity niobium material used in the fabrication of superconducting radio frequency cavity

    Science.gov (United States)

    Singh, Nageshwar; Deo, M. N.; Roy, S. B.

    2016-09-01

    We have investigated the possible influence of surface oxides on the optical properties of a high-purity niobium (Nb) material for fabrication of superconducting radio frequency (SCRF) cavities. Various peaks in the infrared region were identified using Fourier transform infrared and Raman spectroscopy. Optical response functions such as complex refractive index, dielectric and conductivity of niobium were compared with the existing results on oxides free Nb and Cu. It was observed that the presence of a mixture of niobium-oxides, and probably near other surface impurities, appreciably influence the conducting properties of the material causing deviation from the typical metallic characteristics. In this way, the key result of this work is the observation, identification of vibrational modes of some of surface complexes and study of its influences on the optical responses of materials. This method of spectroscopic investigation will help in understanding the origin of degradation of performance of SCRF cavities.

  2. Possible influence of surface oxides on the optical response of high-purity niobium material used in the fabrication of superconducting radio frequency cavity

    International Nuclear Information System (INIS)

    Singh, Nageshwar; Deo, M.N.; Roy, S.B.

    2016-01-01

    We have investigated the possible influence of surface oxides on the optical properties of a high-purity niobium (Nb) material for fabrication of superconducting radio frequency (SCRF) cavities. Various peaks in the infrared region were identified using Fourier transform infrared and Raman spectroscopy. Optical response functions such as complex refractive index, dielectric and conductivity of niobium were compared with the existing results on oxides free Nb and Cu. It was observed that the presence of a mixture of niobium-oxides, and probably near other surface impurities, appreciably influence the conducting properties of the material causing deviation from the typical metallic characteristics. In this way, the key result of this work is the observation, identification of vibrational modes of some of surface complexes and study of its influences on the optical responses of materials. This method of spectroscopic investigation will help in understanding the origin of degradation of performance of SCRF cavities.

  3. Possible influence of surface oxides on the optical response of high-purity niobium material used in the fabrication of superconducting radio frequency cavity

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Nageshwar [Magnetic and Superconducting Materials Section, Raja Ramanna Centre for Advanced Technology, Indore 452013, M.P. (India); Deo, M.N. [High Pressure & Synchrotron Radiation Physics Division, BARC, Mumbai 400085 (India); Roy, S.B. [Magnetic and Superconducting Materials Section, Raja Ramanna Centre for Advanced Technology, Indore 452013, M.P. (India)

    2016-09-11

    We have investigated the possible influence of surface oxides on the optical properties of a high-purity niobium (Nb) material for fabrication of superconducting radio frequency (SCRF) cavities. Various peaks in the infrared region were identified using Fourier transform infrared and Raman spectroscopy. Optical response functions such as complex refractive index, dielectric and conductivity of niobium were compared with the existing results on oxides free Nb and Cu. It was observed that the presence of a mixture of niobium-oxides, and probably near other surface impurities, appreciably influence the conducting properties of the material causing deviation from the typical metallic characteristics. In this way, the key result of this work is the observation, identification of vibrational modes of some of surface complexes and study of its influences on the optical responses of materials. This method of spectroscopic investigation will help in understanding the origin of degradation of performance of SCRF cavities.

  4. Behaviour of solvent extraction of niobium in nitric acid

    International Nuclear Information System (INIS)

    Lin Cansheng; Huang Meixin; Zhang Xianzi; Zhang Chonghai

    1988-01-01

    The behaviour of solvent extraction of niobium is discussed. The expractants, includding TBP, HDBP, H 2 MBP, TBP irradiated, HDEHP, TTA and Aliquat-7402, are used. The special influence of molybdenum and zirconium on solvent extraction of niobium and the extraction behaviur of niobium with TBP irradiated are described. The effect of fluorine and uranium in aqueous phase on extraction of niobium is mentioned. It is observed that the interfacial crud has not relevance to D Nb , but niobium-95 can be absorbed on it. The species of extractable niobium, extraction mechanism, and the reason brought niobum into organic phase are discussed. Finally, the idea of increasing decontamination factor for niobium is suggested

  5. Impact of nitrogen doping of niobium superconducting cavities on the sensitivity of surface resistance to trapped magnetic flux

    Science.gov (United States)

    Gonnella, Dan; Kaufman, John; Liepe, Matthias

    2016-02-01

    Future particle accelerators such as the SLAC "Linac Coherent Light Source-II" (LCLS-II) and the proposed Cornell Energy Recovery Linac require hundreds of superconducting radio-frequency (SRF) niobium cavities operating in continuous wave mode. In order to achieve economic feasibility of projects such as these, the cavities must achieve a very high intrinsic quality factor (Q0) to keep cryogenic losses within feasible limits. To reach these high Q0's in the case of LCLS-II, nitrogen-doping of niobium cavities has been selected as the cavity preparation technique. When dealing with Q0's greater than 1 × 1010, the effects of ambient magnetic field on Q0 become significant. Here, we show that the sensitivity to RF losses from trapped magnetic field in a cavity's walls is strongly dependent on the cavity preparation. Specifically, standard electropolished and 120 °C baked cavities show a sensitivity of residual resistance from trapped magnetic flux of ˜0.6 and ˜0.8 nΩ/mG trapped, respectively, while nitrogen-doped cavities show a higher sensitivity of residual resistance from trapped magnetic flux of ˜1 to 5 nΩ/mG trapped. We show that this difference in sensitivities is directly related to the mean free path of the RF surface layer of the niobium: shorter mean free paths lead to less sensitivity of residual resistance to trapped magnetic flux in the dirty limit (ℓ ≪ ξ0), while longer mean free paths lead to lower sensitivity of residual resistance to trapped magnetic flux in the clean limit (ℓ ≫ ξ0). These experimental results are also shown to have good agreement with recent theoretical predictions for pinned vortex lines oscillating in RF fields.

  6. Flux pinning by voids in surface-oxidized superconducting niobium and vanadium

    International Nuclear Information System (INIS)

    Meij, G.P. van der.

    1984-03-01

    The volume pinning force in several niobium and vanadium samples with voids is determined at various temperatures. Reasonable agreement is found with the collective pinning theory of Larkin and Ovchinnikov above the field of maximum pinning, if the flux line lattice is assumed to be amorphous in this region and if the elementary pinning force is calculated from the quasi-classical theory of Thuneberg, Kurkijaervi, and Rainer. Also some history and relaxation effects are studied in an alternating field. A qualitative explanation is given in terms of flux line dislocations, which reduce the shear strength of the flux line lattice. (Auth.)

  7. Flux pinning by voids in surface-oxidized superconducting niobium and vanadium

    International Nuclear Information System (INIS)

    Meij, G.P. van der.

    1984-01-01

    This thesis describes a study of flux pinning by small voids (roughly 10 nm) in the type II superconductors niobium and vanadium. These voids were created in rectangular foils (with typical dimensions of 30x3x0.2 mm) during an irradiation with fast neutrons in the High Flux Reactor at Petten at temperatures between 400 and 1000 0 C. The pinning force per unit volume is determined from the magnetic properties of the superconducting samples. The experiments were carried out in a slowly ramped magnetic field, as well as in a combination of a static and a much smaller alternating field. (Auth.)

  8. Plasma treatment of bulk niobium surface for superconducting rf cavities: Optimization of the experimental conditions on flat samples

    Directory of Open Access Journals (Sweden)

    M. Rašković

    2010-11-01

    Full Text Available Accelerator performance, in particular the average accelerating field and the cavity quality factor, depends on the physical and chemical characteristics of the superconducting radio-frequency (SRF cavity surface. Plasma based surface modification provides an excellent opportunity to eliminate nonsuperconductive pollutants in the penetration depth region and to remove the mechanically damaged surface layer, which improves the surface roughness. Here we show that the plasma treatment of bulk niobium (Nb presents an alternative surface preparation method to the commonly used buffered chemical polishing and electropolishing methods. We have optimized the experimental conditions in the microwave glow discharge system and their influence on the Nb removal rate on flat samples. We have achieved an etching rate of 1.7  μm/min⁡ using only 3% chlorine in the reactive mixture. Combining a fast etching step with a moderate one, we have improved the surface roughness without exposing the sample surface to the environment. We intend to apply the optimized experimental conditions to the preparation of single cell cavities, pursuing the improvement of their rf performance.

  9. Topographic power spectral density study of the effect of surface treatment processes on niobium for superconducting radio frequency accelerator cavities

    Science.gov (United States)

    Xu, Chen; Tian, Hui; Reece, Charles E.; Kelley, Michael J.

    2012-04-01

    Microroughness is viewed as a critical issue for attaining optimum performance of superconducting radio frequency accelerator cavities. The principal surface smoothing methods are buffered chemical polish (BCP) and electropolish (EP). The resulting topography is characterized by atomic force microscopy (AFM). The power spectral density (PSD) of AFM data provides a more thorough description of the topography than a single-value roughness measurement. In this work, one dimensional average PSD functions derived from topography of BCP and EP with different controlled starting conditions and durations have been fitted with a combination of power law, K correlation, and shifted Gaussian models to extract characteristic parameters at different spatial harmonic scales. While the simplest characterizations of these data are not new, the systematic tracking of scale-specific roughness as a function of processing is new and offers feedback for tighter process prescriptions more knowledgably targeted at beneficial niobium topography for superconducting radio frequency applications.

  10. Topographic power spectral density study of the effect of surface treatment processes on niobium for superconducting radio frequency accelerator cavities

    International Nuclear Information System (INIS)

    Reece, Charles; Tian, Hui; Kelley, Michael; Xu, Chen

    2012-01-01

    Microroughness is viewed as a critical issue for attaining optimum performance of superconducting radio frequency accelerator cavities. The principal surface smoothing methods are buffered chemical polish (BCP) and electropolish (EP). The resulting topography is characterized by atomic force microscopy (AFM). The power spectral density (PSD) of AFM data provides a more thorough description of the topography than a single-value roughness measurement. In this work, one dimensional average PSD functions derived from topography of BCP and EP with different controlled starting conditions and durations have been fitted with a combination of power law, K correlation, and shifted Gaussian models to extract characteristic parameters at different spatial harmonic scales. While the simplest characterizations of these data are not new, the systematic tracking of scale-specific roughness as a function of processing is new and offers feedback for tighter process prescriptions more knowledgably targeted at beneficial niobium topography for superconducting radio frequency applications.

  11. Niobium sputter deposition on quarter wave resonators

    CERN Document Server

    Viswanadham, C; Jayaprakash, D; Mishra, R L

    2003-01-01

    Niobium sputter deposition on quarter wave copper R.F resonators, have been taken up in our laboratory, An ultra high vacuum system was made for this purpose. Niobium exhibits superconducting properties at liquid Helium temperature. A uniform coating of about 1.5 mu m of niobium on the internal surfaces of the copper resonant cavities is desired. Power dissipation in the resonators can be greatly reduced by making the internal surfaces of the R.F cavity super conducting. (author)

  12. High surface area niobium oxides as catalysts for improved hydrogen sorption properties of ball milled MgH2

    International Nuclear Information System (INIS)

    Bhat, V.V.; Rougier, A.; Aymard, L.; Nazri, G.A.; Tarascon, J.-M.

    2008-01-01

    We report, high surface area (up to 200 m 2 /g) nanocrystalline niobium oxide (so called p-Nb 2 O 5 ) synthesized by 'chimie douce' route and its importance in enhancing the hydrogen sorption properties of MgH 2 . p-Nb 2 O 5 induces faster kinetics than commonly used commercial Nb 2 O 5 (c-Nb 2 O 5 ) when ball milled with MgH 2 (named (MgH 2 ) catalyst ) by reducing the time of desorption from 35 min in (MgH 2 ) c-Nb 2 O 5 to 12 min in (MgH 2 ) p-Nb 2 O 5 at 300 deg. C. The BET surface area of as-prepared Nb 2 O 5 was tuned by heat treatment and its effect on sorption properties was studied. Among them, both p-Nb 2 O 5 and Nb 2 O 5 :350 (p-Nb 2 O 5 heated to 350 deg. C with a BET specific surface area of 46 m 2 /g) desorb 5 wt.% within 12 min, exhibiting the best catalytic activity. Furthermore, thanks to the addition of high surface area Nb 2 O 5 , the desorption temperature was successfully lowered down to 200 deg. C, with a significant amount of desorbed hydrogen (4.5 wt.%). In contrast, the composite (MgH 2 ) c-Nb 2 O 5 shows no desorption at this 'low' temperature

  13. Niobium technological alternatives

    International Nuclear Information System (INIS)

    Pinatti, D.G.; Dainesi, C.R.

    1981-01-01

    The process-product matrix of Niobium is presented, through which the technological alternatives for Niobium are identified. It is shown that the three axes of Niobium application, steels, superalloys and metallic Niobium have a tendency to be economical by equivalent. The critical points where technological development of Niobium is needed are analyzed and results are presented on the following products: Nb 2 O 5 by volatilization, metalic Niobium, Niobium powder, bars and sheets, NbTi alloy, corrosion resistent Niobium alloys and superconductor cable and wires. (Author) [pt

  14. Behaviour of hydrogen in niobium

    International Nuclear Information System (INIS)

    Chuang, Y.C.; Tang, C.H.; Chuang, T.L.

    1982-01-01

    Polycrystalline niobium was charged electrolytically with hydrogen at room temperature. The behaviour of hydrogen in niobium has been investigated by optical microscopy, SEM, and ion microprobe analysis. It is shown that, when the hydrogen content in niobium is low, hydride tends to form at the grain boundary. As the hydrogen content is increased, precipitation of hydrides with domain structure takes place in the grain. The habit plane of the hydride formed in the vicinity of the grain boundary has been determined by Laue X-ray back reflection technique to be (130)c and (111)c. The structure of the hydride formed on the surface of niobium after 6 h hydrogen charging at room temperature (c.d. 0.2 A/cm 2 ) has been established to be identical to that of NbHsub(0.89). (orig.) [de

  15. Electrochemical and electrocatalytic studies of toluidine blue immobilized on a silica gel surface coated with niobium oxide

    Directory of Open Access Journals (Sweden)

    Santos Antonio S.

    2002-01-01

    Full Text Available The electrochemical behavior of toluidine blue (TB adsorbed on a silica surface modified with niobium oxide (SN was investigated using a modified carbon paste electrode. The presence of SN gave the electrode high stability, avoiding the leaching out of the mediator from the electrode surface. The formal potential (E0' of the adsorbed TB was --113 mV vs. SCE, indicating a shift of almost 100 mV towards more positive potential values, compared to TB dissolved in aqueous solution or adsorbed on carbon paste. The stability and formal potential remained constant upon changing the solution pH in the range 5 to 8. In these solution pH values the electrocatalytic activity remained almost constant with a sensitivity of 1.2 10-4 A L mol-1 cm-2 and a K Mapp of 4.9 10-5 mol L-1. A linear response range for NADH concentration between 2.0 10-4 and 4.0 10-3 mol L-1 at pH 7.0, with a detection limit of 3.4 10-5 mol L-1 was observed for the sensor. A response time of 2 s and a precision of 1.0 %, expressed as relative standard deviation for 10 replicates, were observed for the sensor developed.

  16. Interaction of Human Osteoblast-Like Saos-2 and MG-63 Cells with Thermally Oxidized Surfaces of a Titanium-Niobium Alloy

    Czech Academy of Sciences Publication Activity Database

    Vandrovcová, Marta; Jirka, Ivan; Novotná, Katarína; Lisá, Věra; Frank, Otakar; Kolská, Z.; Starý, V.; Bačáková, Lucie

    2014-01-01

    Roč. 9, č. 6 (2014), e100475 E-ISSN 1932-6203 R&D Projects: GA ČR(CZ) GAP108/10/1858; GA ČR(CZ) GAP107/12/1025; GA MPO FR-TI3/088 Institutional support: RVO:67985823 ; RVO:61388955 Keywords : thermally oxidized surface * titanium-niobium * TiO2 * osteoblast * macrophage Subject RIV: EI - Biotechnology ; Bionics Impact factor: 3.234, year: 2014

  17. Fabrication and photovoltaic performance of niobium doped TiO{sub 2} hierarchical microspheres with exposed {001} facets and high specific surface area

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yongqiang; Ran, Huili [School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001 (China); State Centre for International Cooperation on Designer Low-Carbon and Environmental Materials, Zhengzhou University, Zhengzhou 450001 (China); Fan, Jiajie, E-mail: fanjiajie@zzu.edu.cn [School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001 (China); State Centre for International Cooperation on Designer Low-Carbon and Environmental Materials, Zhengzhou University, Zhengzhou 450001 (China); Zhang, Xiaoli; Mao, Jing [School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001 (China); State Centre for International Cooperation on Designer Low-Carbon and Environmental Materials, Zhengzhou University, Zhengzhou 450001 (China); Shao, Guosheng [School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001 (China); State Centre for International Cooperation on Designer Low-Carbon and Environmental Materials, Zhengzhou University, Zhengzhou 450001 (China); Institute for Renewable Energy and Environmental Technologies, University of Bolton, Bolton BL3 5AB (United Kingdom)

    2017-07-15

    Highlights: • Nb-doped hierarchical TiO{sub 2} microsphere DSSCs show enhanced performance. • Nb{sup 5+} dopant replaces Ti{sup 4+} cation in TiO{sub 2} lattice. • Electrons transport was enhanced due to the down-shifted conduction band minimum. • Exposed (001) facets and high specific surface area allows high dye-loading. - Abstract: The niobium doped hierarchical anatase TiO{sub 2} microspheres, which are consist of a serried nano-thorns and plicate nano-ribbons with exposed {001} facets, were synthesized using hydrothermal method followed by heat treatment. The effects of niobium on the microstructures and photovoltaic performances of the dye-sensitized solar cells (DSSCs) were studied. The results revealed that Nb{sup 5+} doping replaces Ti{sup 4+} cations in TiO{sub 2} lattice, and the bandgap of the films varies with increasing Nb doping concentration because of the downshift of the conduction band minimum (CBM). The niobium-doped TiO{sub 2} DSSCs with moderate loadings show enhanced performance comparing with their pure TiO{sub 2} counterparts. Optimally, the conversion efficiency of the Nb-3.5 (Nb 3.5 mol%) DSSC is 4.99%. This is higher than that (4.39%) of pure TiO{sub 2} cells by 13.7%. This is due to the fact that the Nb-doped solar cells have increased the number of the photo-induced electrons because of their exposed (001) facets and higher specific surface area; and enhanced electrons collection and transport because of the downshifted CBM of the Nb-doped TiO{sub 2}. However, heavy Nb doping results in the decrease of the performance of the niobium-doped cells due to the excessive defects within the Nb-TiO{sub 2} samples resulting in enhanced charge recombination at defects.

  18. Direct Flotation of Niobium Oxide Minerals from Carbonatite Niobium Ores

    Science.gov (United States)

    Ni, Xiao

    Currently the recovery of niobium oxide minerals from carbonatite niobium ores relies on the use of non-selective cationic collectors. This leads to complicated process flowsheets involving multiple desliming and multiple reverse flotation stages, and low niobium recovery. In this research, anionic collectors that are capable of strong chemisorption on the niobium minerals were studied with the objective of directly floating the niobium oxide minerals from the carbonatite ores. In the flotation of both high purity minerals and Niobec ores, it was shown that the combination of hydroxamic acid and sodium metaphosphate was an effective reagent scheme for the direct flotation of niobium oxide from its ores. Batch flotation on the Niobec Mill Feed showed that over 95% of niobium oxide was recovered into a rougher concentrate that was less than 47% of the original feed mass. Preliminary cleaning tests showed that the reagent scheme could also be used to upgrade the rougher concentrate, although the depression of iron oxide minerals required further study. X-ray photoelectron spectroscopic (XPS) measurement results confirm that OHA (octyl hydroxamic acid) could chemisorb on pyrochlore surface while only physically adsorb on calcite, judging by the chemical shifts of electron binding energies in the elements in both OHA and the mineral surfaces. When hydroxamic acid was adsorbed on calcite surface, the binding energies of the N 1s electrons, at 400.3 eV, did not shift. However, after adsorption on pyrochlore, the N 1s binding energy peak split into two peaks, one at a binding energy of around 399 eV, representing chemically adsorbed OHA, the other at between 400 and 401 eV. The experimental data suggested a strong chemisorption of the OHA on pyrochlore surface in the form of a vertical head-on orientation of the OHA molecules so that the pyrochlore was strongly hydrophobized even at low OHA concentrations, followed by possibly randomly oriented physisorbed OHA molecules

  19. Microscopic investigation of RF surfaces of 3 GHz niobium accelerator cavities following RF processing

    International Nuclear Information System (INIS)

    Graber, J.; Barnes, P.; Flynn, T.; Kirchgessner, J.; Knobloch, J.; Moffat, D.; Muller, H.; Padamsee, H.; Sears, J.

    1993-01-01

    RF processing of Superconducting accelerating cavities is achieved through a change in the electron field emission (FE) characteristics of the RF surface. The authors have examined the RF surfaces of several single-cell 3 GHz cavities, following RF processing, in a Scanning Electron Microscope (SEM). The RF processing sessions included both High Peak Power (P ≤ 50 kW) pulsed processing, and low power (≤ 20 W) continuous wave processing. The experimental apparatus also included a thermometer array on the cavity outer wall, allowing temperature maps to characterize the emission before and after RF processing gains. Multiple sites have been located in cavities which showed improvements in cavity behavior due to RF processing. Several SEM-located sites can be correlated with changes in thermometer signals, indicating a direct relationship between the surface site and emission reduction due to RF processing. Information gained from the SEM investigations and thermometry are used to enhance the theoretical model of RF processing

  20. Niobium thin film deposition studies on copper surfaces for superconducting radio frequency cavity applications

    Energy Technology Data Exchange (ETDEWEB)

    W. M. Roach, D. B. Beringer, J. R. Skuza, W. A. Oliver, C. Clavero, C. E. Reece, R. A. Lukaszew

    2012-06-01

    Thin film coatings have the potential to increase both the thermal efficiency and accelerating gradient in superconducting radio frequency accelerator cavities. However, before this potential can be realized, systematic studies on structure-property correlations in these thin films need to be carried out since the reduced geometry, combined with specific growth parameters, can modify the physical properties of the materials when compared to their bulk form. Here, we present our systematic studies of Nb thin films deposited onto Cu surfaces to clarify possible reasons for the limited success that this process exhibited in previous attempts. We compare these films with Nb grown on other surfaces. In particular, we study the crystal structure and surface morphology and their effect on superconducting properties, such as critical temperature and lower critical field. We found that higher deposition temperature leads to a sharper critical temperature transition, but also to increased roughness indicating that there are competing mechanisms that must be considered for further optimization.

  1. Niobium thin film deposition studies on copper surfaces for superconducting radio frequency cavity applications

    International Nuclear Information System (INIS)

    Roach, W.M.; Beringer, D.B.; Skuza, J.R.; Oliver, W.A.; Clavero, C.; Reece, C.E.; Lukaszew, R.A.

    2012-01-01

    Thin film coatings have the potential to increase both the thermal efficiency and accelerating gradient in superconducting radio frequency accelerator cavities. However, before this potential can be realized, systematic studies on structure-property correlations in these thin films need to be carried out since the reduced geometry, combined with specific growth parameters, can modify the physical properties of the materials when compared to their bulk form. Here, we present our systematic studies of Nb thin films deposited onto Cu surfaces to clarify possible reasons for the limited success that this process exhibited in previous attempts. We compare these films with Nb grown on other surfaces. In particular, we study the crystal structure and surface morphology and their effect on superconducting properties, such as critical temperature and lower critical field. We found that higher deposition temperature leads to a sharper critical temperature transition, but also to increased roughness indicating that there are competing mechanisms that must be considered for further optimization.

  2. Damage of niobium surfaces caused by bombardment with 4He+ ions of different energies typical for T-20

    International Nuclear Information System (INIS)

    Guseva, M.I.; Gusev, V.; Martynenko, Yu.V.; Das, S.K.; Kaminsky, M.

    1979-01-01

    The aim of the present studies was to study surface damage due to blistering of both annealed and cold-worked niobium (a candidate first wall material for keV) irradiated sequentially with 4 He + ions with energies of 0.5 to 1800 keV for a total dose of 5.0 C/cm 2 . A typical surface of cold-worked Nb after irradiations with 4 He + ions with increasing energy from 0.5 to 90 keV is shown. The blister diameters range from 0.1 μm to 3 μm, and most of the blisters have exfoliated. The blisters fall into several size classes, the two most dominant ones having most probable blister diameters of approx. 0.27 μm and approx. 2.0 μm. The skin thickness of the larger blisters was measured to be approx. 0.23 μm. Also shown is the same area after irradiation with 150-1800-keV 4 He + irradiation for a dose of 0.66 C/cm 2 . A few additional blisters can be seen. A cold-worked Nb surface that was irradiated only with 150-1800-keV 4 He + ions is also shown. It is seen that prior irradiation with 0.5-90-keV 4 He + helped in significantly reducing blistering. For a total dose of 0.5 C/cm 2 , the erosion yield due to helium blistering of Nb ranges from (5.4 +- 2.0) x 10 -3 to (1.5 +- 0.7) x 10 -2 atoms/ion. For the cold-worked Nb target the results indicate clearly that the 4 He + implantations for the energy range from 0.5 to 90 keV help to reduce both the density and diameter of blisters formed by subsequent He-implantation for the energy ranging from 150 to 1800 keV. 2 figures

  3. Niobium thin film deposition studies on copper surfaces for superconducting radio frequency cavity applications

    Directory of Open Access Journals (Sweden)

    W. M. Roach

    2012-06-01

    Full Text Available Thin film coatings have the potential to increase both the thermal efficiency and accelerating gradient in superconducting radio frequency accelerator cavities. However, before this potential can be realized, systematic studies on structure-property correlations in these thin films need to be carried out since the reduced geometry, combined with specific growth parameters, can modify the physical properties of the materials when compared to their bulk form. Here, we present our systematic studies of Nb thin films deposited onto Cu surfaces to clarify possible reasons for the limited success that this process exhibited in previous attempts. We compare these films with Nb grown on other surfaces. In particular, we study the crystal structure and surface morphology and their effect on superconducting properties, such as critical temperature and lower critical field. We found that higher deposition temperature leads to a sharper critical temperature transition, but also to increased roughness indicating that there are competing mechanisms that must be considered for further optimization.

  4. On niobium sputter coated cavities

    International Nuclear Information System (INIS)

    Arnolds-Mayer, G.; Kaufmann, U.; Downar, H.

    1988-01-01

    To coat copper cavities with a thin film of niobium, facilities for electropolishing and sputter deposition have been installed at Dornier. Experiments have been performed on samples to optimize electropolishing and deposition parameters. In this paper, characteristics concerning surface properties, adhesion of the niobium film to the copper substrate, and film properties were studied on planar samples. A 1.5 GHz single cell cavity made from oxygen free high conductivity (OFHC) copper was sputter coated twice. First rf measurements were performed in the temperature range from 300 K to 2 K

  5. Niobium LEP 2 accelerating cavities

    CERN Multimedia

    An accelerating cavity from LEP. This could be cut open to show the layer of niobium on the inside. Operating at 4.2 degrees above absolute zero, the niobium is superconducting and carries an accelerating field of 6 million volts per metre with negligible losses. Each cavity has a surface of 6 m2. The niobium layer is only 1.2 microns thick, ten times thinner than a hair. Such a large area had never been coated to such a high accuracy. A speck of dust could ruin the performance of the whole cavity so the work had to be done in an extremely clean environment. These challenging requirements pushed European industry to new achievements. 256 of these cavities were used in an upgrade of the LEP accelerator to double the energy of the particle beams.

  6. Surface morphological structures and electrochemical activity properties of iridium–niobium binary alloy electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Matsumoto, Toru, E-mail: matsumoto.t@jemai.or.jp [Green Innovation Research Laboratories, NEC Corporation, 34 Miyukigaoka, Tsukuba, Ibaraki 305-8501 (Japan); Sata, Naoaki [Green Innovation Research Laboratories, NEC Corporation, 34 Miyukigaoka, Tsukuba, Ibaraki 305-8501 (Japan); Kobayashi, Kiyoshi [Advanced Ceramic Group, Advanced Materials Processing Unit, National Institute for Materials Science, Sengen 1-2-1, Tsukuba, Ibaraki 305-0047 (Japan); Yamabe-Mitarai, Yoko [High Temperature Materials Unit Functional Structure Materials Group, National Institute for Materials Science, Sengen 1-2-1, Tsukuba, Ibaraki 305-0047 (Japan)

    2013-10-01

    Highlights: • An Ir–23Nb alloy has the best oxidation capability among other Nb concentrations. • The reason is the Ir–23Nb has a large surface area which results from Ir + Ir{sub 3}Nb. • An Ir–23Nb glucose sensor detects glucose much better than an Ir glucose sensor. -- Abstract: The electrochemical activities of Ir–Nb binary alloys were investigated as functions of the alloy compositions, crystal structures, and surface morphologies for a hydrogen peroxide and ascorbic acid redox reaction. High activities for the redox reaction of hydrogen peroxide were observed when pure Ir and an alloy with a composition of 77 at% Ir–23 at% Nb (Ir–23Nb) were used. Tests on eight electrodes—Ir, Ir–13Nb, Ir–17Nb, Ir–23Nb, Ir–30Nb, Ir–43Nb, Ir–62Nb, and Nb—showed that at a constant potential difference of 0.7 V vs. Ag/AgCl, the Ir–23Nb electrode had the best hydrogen peroxide oxidation capability: 9.2 μA/mm{sup 2} for 2 mM hydrogen peroxide. Apart from Nb, Ir–23Nb gave the best performance in terms of preferential hydrogen peroxide oxidation against ascorbic acid. Subsequently, the Ir and Ir–23Nb electrodes were used for the fabrication of amperometric glucose sensors. We first coated the two electrodes with a γ-aminopropyltriethoxysilane membrane and then with a glucose oxidase membrane. Tests on the Ir and Ir–23Nb electrode glucose sensors showed that the latter had better glucose detection capability than the former: 0.226 μA/(mm{sup 2} mM) for the Ir–23Nb sensor with 1.67 mM glucose. We investigated the relationship between the electrode responses to both hydrogen peroxide and ascorbic acid and the electrode surface structures.

  7. Ion surface collisions on surfaces relevant for fusion devices

    International Nuclear Information System (INIS)

    Rasul, B.; Endstrasser, N.; Zappa, F.; Grill, V.; Scheier, P.; Mark, T.

    2006-01-01

    Full text: One of the great challenges of fusion research is the compatibility of reactor grade plasmas with plasma facing materials coating the inner walls of a fusion reactor. The question of which surface coating should be used is of particular interest for the design of ITER. The impact of energetic plasma particles leads to sputtering of wall material into the plasma. A possible solution for the coating of plasma facing walls would be the use of special carbon surfaces. Investigations of these various surfaces have been started at BESTOF ion-surface collision apparatus. Experiment beam of singly charged molecular ions of hydrocarbon molecules, i.e. C 2 H + 4 , is generated in a Nier-type electron impact ionization source at an electron energy of about 70 eV. In the first double focusing mass spectrometer the ions are mass and energy analyzed and afterwards refocused onto a surface. The secondary reaction products are monitored using a Time Of Flight mass spectrometer. The secondary ion mass spectra are recorded as a function of the collision energy for different projectile ions and different surfaces. A comparison of these spectra show for example distinct changes in the survival probability of the same projectile ion C 2 H + 4 for different surfaces. (author)

  8. The secondary electron yield of air exposed metal surfaces at the example of niobium

    CERN Document Server

    Scheuerlein, C; Taborelli, M

    2002-01-01

    The secondary electron yield (SEY) variation of atomically clean metal surfaces due to air exposures and during subsequent heat treatments is described with the example of a sputter-deposited Nb thin film. Corresponding variations of the surface chemical composition have been monitored using AES and SSIMS. On the basis of these results and of previously obtained SEY results on metals and metal oxides the origin of the SEY variations is discussed. The SEY increase, which is generally observed during long lasting air exposures of clean metals, is mainly caused by the adsorption of an airborne carbonaceous contamination layer. The estimated value of about 3 for the maximum SEY of this layer is higher than that of all pure metals. Only in some cases the air-formed oxide can contribute to the air exposure induced SEY increase while many oxides have a lower SEY than their parent metals. From the experimental data it can also be excluded that the SEY increase during air exposures is mainly due to an increased second...

  9. Materials and surface aspects in the development of SRF Niobium cavities

    CERN Document Server

    Antoine, C

    2012-01-01

    Foreword from author; When I joined the CEA Saclay SRF group in 1989, my initial background was physical chemistry and surface science, which I completed later on with solid state physics and metallurgy. Most accelerator physicists at that time had training in RF, plasma physics, nuclear or particle physics. We were very few with a background in material science. Working with people with a different background than yours reveals to be both challenging and funny: you can impress them with things you consider basic while they simply do not believe you for other things you consider so well admitted that you do not even remember where it comes from. At the end it obliges you to reconsider your basics and re-question many results, which opens many new and sometimes unexpected paths. Like usual in science, answering one question rises many new ones, and trying to improve cavities performance led to fascinating physics problems. Exploring some of these problems often requires techniques and expertise that are far be...

  10. Modification on surface oxide layer structure and surface morphology of niobium by gas cluster ion beam treatments

    International Nuclear Information System (INIS)

    Wu, A.T.; Swenson, D.R.; Insepov, Z.

    2010-01-01

    Recently, it was demonstrated that significant reductions in field emission on Nb surfaces could be achieved by means of a new surface treatment technique called gas cluster ion beam (GCIB). Further study as shown in this paper revealed that GCIB treatments could modify surface irregularities and remove surface asperities leading to a smoother surface finish as demonstrated through measurements using a 3D profilometer, an atomic force microscope, and a scanning electron microscope. These experimental observations were supported by computer simulation via atomistic molecular dynamics and a phenomenological surface dynamics. Measurements employing a secondary ion mass spectrometry found that GCIB could also alter Nb surface oxide layer structure. Possible implications of the experimental results on the performance of Nb superconducting radio frequency cavities treated by GCIB will be discussed. First experimental results on Nb single cell superconducting radio frequency cavities treated by GCIB will be reported.

  11. Corrosion of niobium and niobium alloys

    International Nuclear Information System (INIS)

    Yau, T.L.; Webster, R.T.

    1987-01-01

    Niobium and niobium alloys are used in several corrosion-resistant applications, principally rocket and jet engines, nuclear reactors, sodium vapor highway lighting, and chemical-processing equipment. Niobium has many of the same properties of tantalum, its sister metal, but has one half the density of tantalum (see the article ''Corrosion of Tantalum'' in this Volume). A common property of niobium and tantalum is the interaction with the reactive elements hydrogen, oxygen, nitrogen, and carbon at temperatures above 300 0 C (570 0 F). These reactions will cause severe embrittlement. Consequently, at elevated temperatures, the metal must be protectively coated or used in vacuum or inert atmospheres. Niobium resists a wide variety of corrosive environments, including concentrated mineral acids, organic acids, liquid metals (particularly sodium and lithium), metal vapors, and molten salts

  12. HIP bonding between niobium/copper/stainless steel materials

    International Nuclear Information System (INIS)

    Inoue, Hitoshi; Fujino, Takeo; Hitomi, Nobuteru; Saito, Kenji; Yamada, Masahiro; Shibuya, Junichi; Ota, Tomoko

    2000-01-01

    We have used niobium flanges for the niobium bulk superconducting RF cavities, however, they are expensive. Stainless steel flanges instead of the niobium flanges will be used in the future large scale production of sc cavities like the KEK/JAERI joint project. For a future R and D of the vacuum sealing related to the clean horizontal assembly method or development of cavities welded a helium vessel in the KEK/JAERI joint project, a converter section of niobium material to stainless steel is required. From these requirements we need to develop the converter. We have tried a HIP bonding method between niobium materials and stainless steel or copper material. It was made clear that the technology could offer an enough bonding strength even higher than niobium tensile strength in the joined surface between niobium and stainless steel or copper. (author)

  13. Degradation of ethyl alcohol on niobium hydraxide compounds

    International Nuclear Information System (INIS)

    Artem'eva, M.A.; Maslova, E.S.; Artem'ev, Yu.M.

    1992-01-01

    Samples of niobium hydroxide were prepared from niobium(5) chloride solutions in anhydrous ethanol. Niobium hydroxide groups were applied on the surface of dispersed silica-airsilogel. Pulse microcatalytic method was used to reveal, that synthesized hydroxide catalysed ethanol decomposition at 573 K only along the direction of dehydration with formation of ethylene. Ethylene was also the main product of alcohol degradation on applied samples, and procedure of dehydration reactions was noticeable. Spectra of temperature programmed surface reactions demonstrate the similarity of acidic surface properties of these two types of samples. Hydroxide compounds of niobium and bismuth were tested for correlation. They were active during ethyl alcohol dehydrogenation

  14. Biocompatibility of Niobium Coatings

    Directory of Open Access Journals (Sweden)

    René Olivares-Navarrete

    2011-09-01

    Full Text Available Niobium coatings deposited by magnetron sputtering were evaluated as a possible surface modification for stainless steel (SS substrates in biomedical implants. The Nb coatings were deposited on 15 mm diameter stainless steel substrates having an average surface roughness of 2 mm. To evaluate the biocompatibility of the coatings three different in vitro tests, using human alveolar bone derived cells, were performed: cellular adhesion, proliferation and viability. Stainless steel substrates and tissue culture plastic were also studied, in order to give comparative information. No toxic response was observed for any of the surfaces, indicating that the Nb coatings act as a biocompatible, bioinert material. Cell morphology was also studied by immune-fluorescence and the results confirmed the healthy state of the cells on the Nb surface. X-ray diffraction analysis of the coating shows that the film is polycrystalline with a body centered cubic structure. The surface composition and corrosion resistance of both the substrate and the Nb coating were also studied by X-ray photoelectron spectroscopy and potentiodynamic tests. Water contact angle measurements showed that the Nb surface is more hydrophobic than the SS substrate.

  15. RF Characterization of Niobium Films for Superconducting Cavities

    CERN Document Server

    Aull† , S; Doebert, S; Junginger, T; Ehiasarian, AP; Knobloch, J; Terenziani, G

    2013-01-01

    The surface resistance RS of superconductors shows a complex dependence on the external parameters such as temperature, frequency or radio-frequency (RF) field. The Quadrupole Resonator modes of 400, 800 and 1200 MHz allow measurements at actual operating frequencies of superconducting cavities. Niobium films on copper substrates have several advantages over bulk niobium cavities. HIPIMS (High-power impulse magnetron sputtering) is a promising technique to increase the quality and therefore the performance of niobium films. This contribution will introduce CERNs recently developed HIPIMS coating apparatus. Moreover, first results of niobium coated copper samples will be presented, revealing the dominant loss mechanisms.

  16. High temperature niobium alloys

    International Nuclear Information System (INIS)

    Wojcik, C.C.

    1991-01-01

    Niobium alloys are currently being used in various high temperature applications such as rocket propulsion, turbine engines and lighting systems. This paper presents an overview of the various commercial niobium alloys, including basic manufacturing processes, properties and applications. Current activities for new applications include powder metallurgy, coating development and fabrication of advanced porous structures for lithium cooled heat pipes

  17. Diffusion of oxygen in niobium during bake-out

    CERN Document Server

    Calatroni, Sergio; Ruzinov, V

    2001-01-01

    Bake-outs at temperatures between 100 C and 150 C for a duration up to two days have become customary for optimising the performance of bulk niobium cavities. This treatment results in the diffusion of oxygen, originating from the surface oxide, into the niobium. The theoretical oxygen profile has been simulated using the diffusion equations, and compared with some experimental results.

  18. Niobium based coatings for dental implants

    International Nuclear Information System (INIS)

    Ramirez, G.; Rodil, S.E.; Arzate, H.; Muhl, S.; Olaya, J.J.

    2011-01-01

    Niobium based thin films were deposited on stainless steel (SS) substrates to evaluate them as possible biocompatible surfaces that might improve the biocompatibility and extend the life time of stainless steel dental implants. Niobium nitride and niobium oxide thin films were deposited by reactive unbalanced magnetron sputtering under standard deposition conditions without substrate bias or heating. The biocompatibility of the surfaces was evaluated by testing the cellular adhesion and viability/proliferation of human cementoblasts during different culture times, up to 7 days. The response of the films was compared to the bare substrate and pieces of Ti6Al4V; the most commonly used implant material for orthopedics and osteo-synthesis applications. The physicochemical properties of the films were evaluated by different means; X-ray diffraction, Rutherford backscattering spectroscopy and contact angle measurements. The results suggested that the niobium oxide films were amorphous and of stoichiometric Nb 2 O 5 (a-Nb 2 O 5 ), while the niobium nitride films were crystalline in the FCC phase (c-NbN) and were also stoichiometric with an Nb to N ratio of one. The biological evaluation showed that the biocompatibility of the SS could be improved by any of the two films, but neither was better than the Ti6Al4V alloy. On the other hand, comparing the two films, the c-NbN seemed to be a better surface than the oxide in terms of the adhesion and proliferation of human cemetoblasts.

  19. Niobium ore OKA-1

    International Nuclear Information System (INIS)

    Steger, H.F.; Bowman, W.S.

    1981-01-01

    A 287-kg sample of a niobium ore, OKA-1, from Oka, Quebec, was prepared as a compositional reference material. OKA-1 was ground to minus 74 μm, blended in one lot, tested for homogeneity by X-ray fluorescence and chemical methods and bottled in 200-g units. In a 'free-choice' round-robin analytical program, 22 laboratories contributed results for niobium in each of two bottles of OKA-1. A statistical analysis of the data gave a recommended value of 0.37 +- 0.01% for niobium

  20. Study of the surface crystallization and resistance to dissolution of niobium phosphate glasses for nuclear waste immobilization; Estudo da cristalizacao superficial e da resistencia a dissolucao de vidros niobofosfatos visando a imobilizacao de rejeitos radioativos

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, Heveline

    2008-07-01

    The surface crystallization and the dissolution rate of three phosphate glass compositions containing different amounts of niobium oxide were studied. The glasses were named Nb30, Nb37, and Nb44 according to the nominal content of niobium oxide in the glass composition. The three compositions were evaluated keeping the P{sub 2}O{sub 5}/K{sub 2}O ratio constant and varying the amount of Nb{sub 2}O{sub 5}. These glasses were produced by melting appropriate chemical compounds at 1500 deg C for 0.5 hour. The crystalline phases which were nucleated on the glass surface after heat treatment were determined by X-ray diffraction. The crystalline structures depend on the amount of niobium oxide in the glass composition. The crystal morphologies were observed by using an optical microscope, and their characteristics are specific for each kind of crystalline phase. The crystal growth rate and the surface nuclei density were determined for each glass composition, and they depend on each crystalline phase nucleated on the surface. From the differential thermal analysis curves it was determined that the Nb44 glass containing 46.5 mol por cent of niobium oxide is the most thermally stable against crystallization when compared to the Nb30 and Nb37 glasses. According to the activation energies determined for crystal growth on the surface of each glass type, the Nb44 glass can also be considered the most resistant one against crystallization. The dissolution rate for the Nb44 glass after 14 days immersed in an aqueous solution with pH equals to 7 at 90 deg C is the lowest (9.0 x 10{sup -7} g. cm{sup -2} . day{sup -1}) when compared to the other two glass compositions. The dissolution rates in acidic and neutral solutions of all studied glasses meet the international standards for materials which can be used in the immobilization of nuclear wastes. (author)

  1. Effort towards symmetric removal and surface smoothening of 1.3-GHz niobium single-cell cavity in vertical electropolishing using a unique cathode

    Science.gov (United States)

    Chouhan, Vijay; Kato, Shigeki; Nii, Keisuke; Yamaguchi, Takanori; Sawabe, Motoaki; Hayano, Hitoshi; Ida, Yoshiaki

    2017-08-01

    A detailed study on vertical electropolishing (VEP) of a 1.3-GHz single-cell niobium coupon cavity, which contains six coupons and four viewports at different positions, is reported. The cavity was vertically electropolished using a conventional rod and three types of unique cathodes named as Ninja cathodes, which were designed to have four retractable blades made of either an insulator or a metal or a combination of both. This study reveals the effect of the cathodes and their rotation speed on uniformity in removal thickness and surface morphology at different positions inside the cavity. Removal thickness was measured at several positions of the cavity using an ultrasonic thickness gauge and the surface features of the coupons were examined by an optical microscope and a surface profiler. The Ninja cathode with partial metallic blades was found to be effective not only in reducing asymmetric removal, which is one of the major problems in VEP and might be caused by the accumulation of hydrogen (H2 ) gas bubbles on the top iris of the cavity, but also in yielding a smooth surface of the entire cavity. A higher rotation speed of the Ninja cathode prevents bubble accumulation on the upper iris, and might result in a viscous layer of similar thickness in the cavity cell. Moreover, a higher electric field at the equator owing to the proximity of partial metallic blades to the equator surface resulted in a smooth surface. The effects of H2 gas bubbles and stirring were also observed in lab EP experiments.

  2. Effort towards symmetric removal and surface smoothening of 1.3-GHz niobium single-cell cavity in vertical electropolishing using a unique cathode

    Directory of Open Access Journals (Sweden)

    Vijay Chouhan

    2017-08-01

    Full Text Available A detailed study on vertical electropolishing (VEP of a 1.3-GHz single-cell niobium coupon cavity, which contains six coupons and four viewports at different positions, is reported. The cavity was vertically electropolished using a conventional rod and three types of unique cathodes named as Ninja cathodes, which were designed to have four retractable blades made of either an insulator or a metal or a combination of both. This study reveals the effect of the cathodes and their rotation speed on uniformity in removal thickness and surface morphology at different positions inside the cavity. Removal thickness was measured at several positions of the cavity using an ultrasonic thickness gauge and the surface features of the coupons were examined by an optical microscope and a surface profiler. The Ninja cathode with partial metallic blades was found to be effective not only in reducing asymmetric removal, which is one of the major problems in VEP and might be caused by the accumulation of hydrogen (H_{2} gas bubbles on the top iris of the cavity, but also in yielding a smooth surface of the entire cavity. A higher rotation speed of the Ninja cathode prevents bubble accumulation on the upper iris, and might result in a viscous layer of similar thickness in the cavity cell. Moreover, a higher electric field at the equator owing to the proximity of partial metallic blades to the equator surface resulted in a smooth surface. The effects of H_{2} gas bubbles and stirring were also observed in lab EP experiments.

  3. Interlaboratory niobium dosimetry comparison

    International Nuclear Information System (INIS)

    Wille, P.

    1980-01-01

    For an interlaboratory comparison of neutron dosimetry using niobium the 93 sup(m)Nb activities of irradiated niobium monitors were measured. This work was performed to compare the applied techniques of dosimetry with Nb in different laboratories. The niobium monitors were irradiated in the fast breeder EBRII, USA and the BR2, Belgium. The monitors were dissolved and several samples were prepared. Their niobium contents were determined by the 94 Nb-count rates. since the original specific count rate was known. The KX radiations of the 93 sup(m)Nb of the samples and of a calibrated Nb-foil were compared. This foil was measured by PTB, Braunschweig and CBNM, Geel, which we additionally compared with the KX radiation of 88 Sr produced by a thin 88 Y source from a 88 Y-standard solution (PTB). (orig.) [de

  4. On niobium nitrilohalogenides

    International Nuclear Information System (INIS)

    Sinitsyna, S.M.

    1977-01-01

    Niobium nitrilhalogenides of the general formula [MNH]sub(n) and [MNH 2 ]sub(n) have been synthesized and their properties investigated. The effect of the ligand nature on the properties, structure, and nature of the chemical bond in niobium nitrilhalogenides has been shown. With an increase of electron-donor properties of the ligands F 2 -800 cm -1 , NbNCl 2 -740 cm -1 , NbNBr 2 -720 cm -1 , NbNI-725 cm -1 )

  5. Catalytic applications of niobium compounds

    International Nuclear Information System (INIS)

    Wright, C.J.; England, W.A.

    1984-01-01

    This article examines the potential uses of niobium, and its compounds, as catalysts in chemical processing. The word potential is deliberately chosen because in 1978 none of the world's twenty-five major catalysts (1) contained niobium. On the other hand, catalysts containing molybdenum and vanadium, neighbors of niobium in the periodic table, realized over 80 x 10 6 of sales in that same year. At the same time many of the patents for niobium catalysts cover applications in which niobium improves the activity of, or substitutes for, molybdenum based compounds. With favorable cost differentials and improvements in understanding, niobium may be able to replace molybdenum in some its traditional uses

  6. Hardening of niobium alloys at precrystallization annealing

    International Nuclear Information System (INIS)

    Vasil'eva, E.V.; Pustovalov, V.A.

    1989-01-01

    Niobium base alloys were investigated. It is shown that precrystallization annealing of niobium-molybdenum, niobium-vanadium and niobium-zirconium alloys elevates much more sufficiently their resistance to microplastic strains, than to macroplastic strains. Hardening effect differs sufficiently for different alloys. The maximal hardening is observed for niobium-vanadium alloys, the minimal one - for niobium-zirconium alloys

  7. Impurity composition effect on work function in cylindrical specimens of niobium and low zirconium niobium base alloys

    International Nuclear Information System (INIS)

    Kobyakov, V.P.

    2000-01-01

    A study is made into poly- and single crystal cylindrical niobium specimens, prepared by various methods as well as into polycrystalline specimens of niobium base alloys doped with 1.2 and 1.6 % Zr. Thermionic work function is measured using a full current method. Several techniques are applied to determine the content of substitutional and interstitial impurities in specimens. The phase composition of polished section surface is also investigated. A work function increase is observed when a considerable amount of carbide phases occurs at the surface. This increase is comparable with the effect of going from a polycrystalline niobium specimen to a single crystal with (110) surface orientation [ru

  8. Buffered Electrochemical Polishing of Niobium

    Energy Technology Data Exchange (ETDEWEB)

    Ciovati, Gianluigi [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Tian, Hui [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); College of William and Mary, Williamsburg, VA (United States); Corcoran, Sean [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)

    2011-03-01

    The standard preparation of superconducting radio-frequency (SRF) cavities made of pure niobium include the removal of a 'damaged' surface layer, by buffered chemical polishing (BCP) or electropolishing (EP), after the cavities are formed. The performance of the cavities is characterized by a sharp degradation of the quality factor when the surface magnetic field exceeds about 90 mT, a phenomenon referred to as 'Q-drop.' In cavities made of polycrystalline fine grain (ASTM 5) niobium, the Q-drop can be significantly reduced by a low-temperature (? 120 °C) 'in-situ' baking of the cavity if the chemical treatment was EP rather than BCP. As part of the effort to understand this phenomenon, we investigated the effect of introducing a polarization potential during buffered chemical polishing, creating a process which is between the standard BCP and EP. While preliminary results on the application of this process to Nb cavities have been previously reported, in this contribution we focus on the characterization of this novel electrochemical process by measuring polarization curves, etching rates, surface finish, electrochemical impedance and the effects of temperature and electrolyte composition. In particular, it is shown that the anodic potential of Nb during BCP reduces the etching rate and improves the surface finish.

  9. Niobium in gray cast iron

    International Nuclear Information System (INIS)

    Castello Branco, C.H.; Beckert, E.A.

    1984-03-01

    The potential for utilization of niobium in gray cast iron is appraised and reviewed. Experiments described in literature indicate that niobium provides structural refinement of the eutectic cells and also promotes pearlite formation. (Author) [pt

  10. Vitreous-enamel protective coatings for niobium and niobium alloys

    International Nuclear Information System (INIS)

    Kobyakov, V.P.; Sedmale, G.P.; Tsimdin', R.A.; Sedmalis, U.Ya.; Tsetskhladze, D.L.; Gosudarstvennyj Komitet po Ispol'zovaniyu Atomnoj Ehnergii SSSR, Sukhumi. Fiziko-Tekhnicheskij Inst.)

    1988-01-01

    Vitreous-enanel coatings to protect niobium and niobium alloys, used in oxidizing media at temperatures up to 1000degC, from embrittlement are developed on the basis of Al 2 O 3 -SiO 2 -P 2 O 5 -Ba vetrificating system. By means of microhardness measurement and IR-spectroscopy it is found, that at coating formation the intermediate ∼20 mkm width zone which prevents oxygen penetration in niobium is formed. Test of niobium pieces with ERS-1000 vitreous-enamel coating have shown, that coating provides niobium reliable protection in the air at 800degC and atmospheric pressure

  11. Method of removing niobium from uranium-niobium alloy

    International Nuclear Information System (INIS)

    Pollock, E.N.; Schlier, D.S.; Shinopulos, G.

    1992-01-01

    This patent describes a method of removing niobium from a uranium-niobium alloy. It comprises dissolving the uranium-niobium alloy metal pieces in a first aqueous solution containing an acid selected from the group consisting of hydrochloric acid and sulfuric acid and fluoboric acid as a catalyst to provide a second aqueous solution, which includes uranium (U +4 ), acid radical ions, the acids insolubles including uranium oxides and niobium oxides; adding nitric acid to the insolubles to oxidize the niobium oxides to yield niobic acid and to complete the solubilization of any residual uranium; and separating the niobic acid from the nitric acid and solubilized uranium

  12. Niobium and tantalum

    Science.gov (United States)

    Schulz, Klaus J.; Piatak, Nadine M.; Papp, John F.; Schulz, Klaus J.; DeYoung,, John H.; Seal, Robert R.; Bradley, Dwight C.

    2017-12-19

    Niobium and tantalum are transition metals that are almost always found together in nature because they have very similar physical and chemical properties. Their properties of hardness, conductivity, and resistance to corrosion largely determine their primary uses today. The leading use of niobium (about 75 percent) is in the production of high-strength steel alloys used in pipelines, transportation infrastructure, and structural applications. Electronic capacitors are the leading use of tantalum for high-end applications, including cell phones, computer hard drives, and such implantable medical devices as pacemakers. Niobium and tantalum are considered critical and strategic metals based on the potential risks to their supply (because current production is restricted to only a few countries) and the significant effects that a restriction in supply would have on the defense, energy, high-tech industrial, and medical sectors.The average abundance of niobium and tantalum in bulk continental crust is relatively low—8.0 parts per million (ppm) niobium and 0.7 ppm tantalum. Their chemical characteristics, such as small ionic size and high electronic field strength, significantly reduce the potential for these elements to substitute for more common elements in rock-forming minerals and make niobium and tantalum essentially immobile in most aqueous solutions. Niobium and tantalum do not occur naturally as pure metals but are concentrated in a variety of relatively rare oxide and hydroxide minerals, as well as in a few rare silicate minerals. Niobium is primarily derived from the complex oxide minerals of the pyrochlore group ((Na,Ca,Ce)2(Nb,Ti,Ta)2(O,OH,F)7), which are found in some alkaline granite-syenite complexes (that is, igneous rocks containing sodium- or potassium-rich minerals and little or no quartz) and carbonatites (that is, igneous rocks that are more than 50 percent composed of primary carbonate minerals, by volume). Tantalum is derived mostly from the

  13. Effect of low temperature baking on the RF properties of niobium superconducting cavities for particle accelerators

    International Nuclear Information System (INIS)

    Gianluigi Ciovati

    2004-01-01

    Radio-frequency superconducting (SRF) cavities are widely used to accelerate a charged particle beam in particle accelerators. The performance of SRF cavities made of bulk niobium has significantly improved over the last ten years and is approaching the theoretical limit for niobium. Nevertheless, RF tests of niobium cavities are still showing some ''anomalous'' losses that require a better understanding in order to reliably obtain better performance. These losses are characterized by a marked dependence of the surface resistance on the surface electromagnetic field and can be detected by measuring the quality factor of the resonator as a function of the peak surface field. A low temperature (100 C-150 C) ''in situ'' bake under ultra-high vacuum has been successfully applied as final preparation of niobium RF cavities by several laboratories over the last few years. The benefits reported consist mainly of an improvement of the cavity quality factor at low field and a recovery from ''anomalous'' losses (so-called ''Q-drop'') without field emission at higher field. A series of experiments with a CEBAF single-cell cavity have been carried out at Jefferson Lab to carefully investigate the effect of baking at progressively higher temperatures for a fixed time on all the relevant material parameters. Measurements of the cavity quality factor in the temperature range 1.37 K-280 K and resonant frequency shift between 6 K-9.3 K provide information about the surface resistance, energy gap, penetration depth and mean free path. The experimental data have been analyzed with the complete BCS theory of superconductivity. The hydrogen content of small niobium samples inserted in the cavity during its surface preparation was analyzed with Nuclear Reaction Analysis (NRA). The single-cell cavity has been tested at three different temperatures before and after baking to gain some insight on thermal conductivity and Kapitza resistance and the data are compared with different models

  14. Niobium in steels and alloys

    International Nuclear Information System (INIS)

    Lyakishev, N.P.; Tulin, N.A.; Pliner, Y.L.

    1984-01-01

    Data are presented on the reserves and processing of niobium raw materials followed by brief review of the current status and long-range trends in the commercial usage of niobium and its compounds. A survey is made of the physical properties of niobium and its chemical reactions with elements of direct concern in the manufacture of ferroalloys, quality steels and other products. Niobium minerals and ores, along with common ore processing practices are described briefly. Attention is paid to Brazilian niobium ores, and to the Araxa deposit specifically. Some emphasis has been given to methods of processing lean niobium ores not easily amenable to simple concentration. A systematic review is presented of the techniques used in the production of niobium ferroalloys. (E.G.) [pt

  15. Niobium based coatings for dental implants

    Energy Technology Data Exchange (ETDEWEB)

    Ramirez, G., E-mail: enggiova@hotmail.com [Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, Circuito Exterior s/n, CU, Mexico D.F. 04510 (Mexico); Facultad de Quimica, Departamento de Ingenieria Quimica, Universidad Nacional Autonoma de Mexico, Mexico D.F. 04510 (Mexico); Rodil, S.E. [Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, Circuito Exterior s/n, CU, Mexico D.F. 04510 (Mexico); Arzate, H. [Laboratorio de Biologia Celular y Molecular, Facultad de Odontologia, Universidad Nacional Autonoma de Mexico, CU, Mexico D.F. 04510 (Mexico); Muhl, S. [Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, Circuito Exterior s/n, CU, Mexico D.F. 04510 (Mexico); Olaya, J.J. [Unidad de Materiales, Departamento de Ingenieria Mecanica y Mecatronica, Universidad Nacional de Colombia, Cra. 30 45-03 Bogota (Colombia)

    2011-01-15

    Niobium based thin films were deposited on stainless steel (SS) substrates to evaluate them as possible biocompatible surfaces that might improve the biocompatibility and extend the life time of stainless steel dental implants. Niobium nitride and niobium oxide thin films were deposited by reactive unbalanced magnetron sputtering under standard deposition conditions without substrate bias or heating. The biocompatibility of the surfaces was evaluated by testing the cellular adhesion and viability/proliferation of human cementoblasts during different culture times, up to 7 days. The response of the films was compared to the bare substrate and pieces of Ti6Al4V; the most commonly used implant material for orthopedics and osteo-synthesis applications. The physicochemical properties of the films were evaluated by different means; X-ray diffraction, Rutherford backscattering spectroscopy and contact angle measurements. The results suggested that the niobium oxide films were amorphous and of stoichiometric Nb{sub 2}O{sub 5} (a-Nb{sub 2}O{sub 5}), while the niobium nitride films were crystalline in the FCC phase (c-NbN) and were also stoichiometric with an Nb to N ratio of one. The biological evaluation showed that the biocompatibility of the SS could be improved by any of the two films, but neither was better than the Ti6Al4V alloy. On the other hand, comparing the two films, the c-NbN seemed to be a better surface than the oxide in terms of the adhesion and proliferation of human cemetoblasts.

  16. Enlarging the surface area of an electrolytic capacitor of porous niobium by Mg−Ce eutectic liquid dealloying

    International Nuclear Information System (INIS)

    Kim, Joung Wook; Wada, Takeshi; Kim, Sung Gyoo; Kato, Hidemi

    2016-01-01

    To increase the surface area while decreasing the ligament size of an Nb anode pellet for use as a capacitor, we added Ce to an Mg melt; the dealloying reaction occurred at temperatures lower than 1023 K, the previously lowest recorded temperature for such a reaction. By analyzing the dealloying kinetics, we found the optimum dealloying conditions to produce a minimum ligament size of 100 nm in the Mg_9_5_._7Ce_4_._3 melt: 923 K for 420 s. Using these conditions, we increased the specific surface area of the Nb anode pellet to 4.3 m"2/g, which increased its mass-specific capacitance to 875,000 μFV/g.

  17. First-principles calculations of niobium hydride formation in superconducting radio-frequency cavities

    Science.gov (United States)

    Ford, Denise C.; Cooley, Lance D.; Seidman, David N.

    2013-09-01

    Niobium hydride is suspected to be a major contributor to degradation of the quality factor of niobium superconducting radio-frequency (SRF) cavities. In this study, we connect the fundamental properties of hydrogen in niobium to SRF cavity performance and processing. We modeled several of the niobium hydride phases relevant to SRF cavities and present their thermodynamic, electronic, and geometric properties determined from calculations based on density functional theory. We find that the absorption of hydrogen from the gas phase into niobium is exothermic and hydrogen becomes somewhat anionic. The absorption of hydrogen by niobium lattice vacancies is strongly preferred over absorption into interstitial sites. A single vacancy can accommodate six hydrogen atoms in the symmetrically equivalent lowest energy sites and additional hydrogen in the nearby interstitial sites affected by the strain field: this indicates that a vacancy can serve as a nucleation center for hydride phase formation. Small hydride precipitates may then occur near lattice vacancies upon cooling. Vacancy clusters and extended defects should also be enriched in hydrogen, potentially resulting in extended hydride phase regions upon cooling. We also assess the phase changes in the niobium-hydrogen system based on charge transfer between niobium and hydrogen, the strain field associated with interstitial hydrogen, and the geometry of the hydride phases. The results of this study stress the importance of not only the hydrogen content in niobium, but also the recovery state of niobium for the performance of SRF cavities.

  18. Diffusion of oxygen in niobium during bake-out

    International Nuclear Information System (INIS)

    Benvenuti, C.; Calatroni, S.; Ruzinov, V.

    2003-01-01

    Bake-outs at temperatures between 100 degC and 150 degC for duration up to two days have become customary for optimising the performance of bulk niobium cavities. This treatment results in the diffusion of oxygen, originating from the surface oxide, into the niobium. The theoretical oxygen profile has been simulated using the diffusion equations, and compared with some experimental results. (author)

  19. Damage of niobium surfaces caused by bombardment with 4He+ ions of different energies typical for T-20

    International Nuclear Information System (INIS)

    Guseva, M.I.; Gusev, V.; Martynenko, Yu.V.; Das, S.K.; Kaminsky, N.

    1979-01-01

    The surface damage of cold worked and annealed polycrystalline Nb irradiated at room temperature with He + ions sequentially at different energies over the range from 0.5 keV to 1.8 MeV has been investigated. The individual energy and the dose of the He + ion was chosen to match the theoretically calculated He + ion spectrum expected in the Tokamak T-20. In one set of irradiations, targets were irradiated at Kurchatov Institute starting with 0.5 keV 4 He + ions and extending up to 90 keV in eleven steps. Subsequently, the same area was irradiated at ANL starting at 150 keV and increased in eight steps up to 1.8 MeV. The irradiations were carried out for a total dose of 5.0 C/cm 2 . In another set of irradiations the sequence was reversed. Scanning electron microscopy results show formation of blisters and exfoliation. For the same dose the broad energy implant (due to sequential irradiation) appears to decrease the blister diameter and density as compared to irradiation with monoenergetic He + ions at a given energy (in the energy range considered). Some estimates of surface erosion yields due to blistering are given

  20. Surface Propensity of Atmospherically Relevant Amino Acids Studied by XPS.

    Science.gov (United States)

    Mocellin, Alexandra; Gomes, Anderson Herbert de Abreu; Araújo, Oscar Cardoso; de Brito, Arnaldo Naves; Björneholm, Olle

    2017-04-27

    Amino acids constitute an important fraction of the water-soluble organic nitrogen (WSON) compounds in aerosols and are involved in many processes in the atmosphere. In this work, we applied X-ray photoelectron spectroscopy (XPS) to study aqueous solutions of four amino acids, glycine, alanine, valine, and methionine, in their zwitterionic forms. We found that amino acids with hydrophilic side chains and smaller size, GLY and ALA, tend to stay in the bulk of the liquid, while the hydrophobic and bigger amino acids, VAL and MET, are found to concentrate more on the surface. We found experimental evidence that the amino acids have preferential orientation relative to the surface, with the hydrophobic side chain being closer to the surface than the hydrophilic carboxylate group. The observed amino acid surface propensity has implications in atmospheric science as the surface interactions play a central role in cloud droplet formation, and they should be considered in climate models.

  1. The surface oxidation kinetics of zirconium-niobium alloys and aα-Fe with prevailing cubical texture

    International Nuclear Information System (INIS)

    Mukhambetov, D.G.; Kargin, D.B.; Chalaya, O. V.; Berber, N.N.

    2002-01-01

    It is known, that the kinetics of oxidation of zirconium at formed heating is characterized by two consecutive stages. At the initial stage the thin protecting film will be derived. The relation of its depth from time h (t) is described predominantly by parabolic law. Some time later there can be a transition to the linear law of oxidation. The time moment divided these areas on the kinetic relation is called as a point of break. The film is formed at the second stage, has a developed grid of pores or cracks, can be flake away and be crumbled by losing its protective properties. At the oxidation of the surface shells of the heat generating elements and the technological channels of atomic boilers both stages are proceeded simultaneously. This phenomenon is called modular corrosion. Its consequences can be dangerous for the equipment. Its mechanism is not clear till now. Similar dependencies h(t), with the break point, beginning from which the thin film is transformed into the thick one were found by us at the oxidation α-Fe with prevailing cubical texture. The task of the work was to study the oxide film growth laws in order to clarify the mechanisms of transition of the thin film into the oxide layer on the α-Fe surface and Zr-Nb alloy modular corrosion emergence. Low-carbonate steel with contents 99.43 % of α-Fe was used as a model object of our research. In the texture of the steel surface planar direction [100] was prevalent. Its part accounted for about 40 %. The isothermal air oxidation was carried out in the interval of 450-500 deg. C . Phase composition of the film was determined with X-ray diffraction. The mathematical treatment of the dependencies h(t) obtained by experiment showed that the kinetics of the film growth can be conditionally divided into 4-stages. The initial stage is described by function logarithmic function, the other stages - by the power mode h n =A n ·t, namely, the second stage - is described by function close to cubical (n≅3

  2. Surface characterization of bacterial cells relevant to the mineral industry

    NARCIS (Netherlands)

    Sharma, PK; Rao, KH

    Bacteria belonging to the Acidithiobacilli group are widely used in the mineral processing industry in bioleaching and biobeneficiation operations. Paenibacillus polymyxa has also found application in biobeneficiation studies. Microbial adhesion to mineral surface is an essential step,for both

  3. Functionalization of niobium electrodes for the construction of impedimetric biosensors

    International Nuclear Information System (INIS)

    Helali, S.; Abdelghani, A.; Hafaiedh, I.; Martelet, C.; Prodromidis, M.I.; Albanis, T.; Jaffrezic-Renault, N.

    2008-01-01

    This paper describes the development of an impedimetric immunosensor, based on niobium/niobium oxide (Nb/NbOxHy) electrodes, for the detection of atrazine. Niobium oxide was anodically formed onto niobium electrodes at 25 V in 1 M H 2 SO 4 . Hydrous oxide layers were then silanized with APTES, and using glutaraldehyde as a cross linker, Fab fragment k47 antibody was covalently immobilized onto the surface of the electrodes. Electrochemical impedance spectroscopy (EIS) was used to characterize the building-up of the immunosensors as well as the binding of atrazine to its specific antibody. In presence of ferricyanide redox species and under a cathodic polarization voltage (- 1.2 V versus SCE), the relationship between the concentration of atrazine and the change of the electron transfer resistance value was studied

  4. Superconducting parameters of polycrystalline niobium films

    International Nuclear Information System (INIS)

    Kandyba, P.E.; Kolesnikov, D.P.; Tkachev, V.A.

    1978-01-01

    The niobium semi-crystalline films, having a thickness of 200-5,050 A have been studied. The films have been produced by the electron-beam evaporation in the oilless vacuum and by the ionic plasma spraying with diode and triode methods. Determined have been the coherence length, the magnetic field penetration depth and the Ginsburg-andau parameter. An attempt is made to determine the electron states density of the Fermi surface

  5. Micro-length anodic porous niobium oxide for lithium-ion thin film battery applications

    International Nuclear Information System (INIS)

    Yoo, Jeong Eun; Park, Jiyoung; Cha, Gihoon; Choi, Jinsub

    2013-01-01

    The anodization of niobium in an aqueous mixture of H 3 PO 4 and HF in the potential range from 2.5 to 30 V for 2 h at 5 °C was performed, demonstrating that anodic porous niobium oxide film with a thickness of up to 2000 nm, including a surface dissolution layer, can be obtained by controlling the applied potential and composition of the electrolytes. Specifically, surface dissolution-free porous niobium oxide film with a thickness of 800 nm can be prepared in a low electrolyte concentration. The surface dissolution is observed when the concentration ratio of HF (wt.%):H 3 PO 4 (M) was more than 2:1. The discontinuous layers in the niobium oxide film were observed when the thickness was higher than 500 nm, which was ascribed to the large volume expansion of the niobium oxide grown from the niobium metal. The anodic porous niobium oxide film was used as the cathode for lithium-ion batteries in the potential range from 1.2 to 3.0 V at a current density of 7.28 × 10 − 6 A cm −2 . The first discharge capacity of ca. 53 μA h cm − 2 was obtained in 800 nm thick niobium oxide without a surface dissolution layer. - Highlights: ► Anodic porous niobium oxide film with a thickness of 2000 nm was obtained. ► Surface dissolution-free porous niobium oxide film was prepared. ► The niobium oxide film was used as the cathode for lithium-ion batteries

  6. First-principles calculations of niobium hydride formation in superconducting radio-frequency cavities

    International Nuclear Information System (INIS)

    Ford, Denise C; Cooley, Lance D; Seidman, David N

    2013-01-01

    Niobium hydride is suspected to be a major contributor to degradation of the quality factor of niobium superconducting radio-frequency (SRF) cavities. In this study, we connect the fundamental properties of hydrogen in niobium to SRF cavity performance and processing. We modeled several of the niobium hydride phases relevant to SRF cavities and present their thermodynamic, electronic, and geometric properties determined from calculations based on density functional theory. We find that the absorption of hydrogen from the gas phase into niobium is exothermic and hydrogen becomes somewhat anionic. The absorption of hydrogen by niobium lattice vacancies is strongly preferred over absorption into interstitial sites. A single vacancy can accommodate six hydrogen atoms in the symmetrically equivalent lowest energy sites and additional hydrogen in the nearby interstitial sites affected by the strain field: this indicates that a vacancy can serve as a nucleation center for hydride phase formation. Small hydride precipitates may then occur near lattice vacancies upon cooling. Vacancy clusters and extended defects should also be enriched in hydrogen, potentially resulting in extended hydride phase regions upon cooling. We also assess the phase changes in the niobium–hydrogen system based on charge transfer between niobium and hydrogen, the strain field associated with interstitial hydrogen, and the geometry of the hydride phases. The results of this study stress the importance of not only the hydrogen content in niobium, but also the recovery state of niobium for the performance of SRF cavities. (paper)

  7. Catalytic properties of niobium compounds

    International Nuclear Information System (INIS)

    Tanabe, K.; Iizuka, T.

    1983-04-01

    The catalytic activity and selectivity of niobium compounds including oxides, salts, organometallic compounds and others are outlined. The application of these compounds as catalysts to diversified reactions is reported. The nature and action of niobium catalysts are characteristic and sometimes anomalous, suggesting the necessity of basic research and the potential use as catalysts for important processes in the chemical industry. (Author) [pt

  8. Nitrogen and argon doping of niobium for superconducting radio frequency cavities: a pathway to highly efficient accelerating structures

    Science.gov (United States)

    Grassellino, A.; Romanenko, A.; Sergatskov, D.; Melnychuk, O.; Trenikhina, Y.; Crawford, A.; Rowe, A.; Wong, M.; Khabiboulline, T.; Barkov, F.

    2013-10-01

    We report a surface treatment that systematically improves the quality factor of niobium radio frequency cavities beyond the expected limit for niobium. A combination of annealing in a partial pressure of nitrogen or argon gas and subsequent electropolishing of the niobium cavity surface leads to unprecedented low values of the microwave surface resistance, and an improvement in the efficiency of the accelerating structures up to a factor of 3, reducing the cryogenic load of superconducting cavities for both pulsed and continuous duty cycles. The field dependence of the surface resistance is reversed compared to standardly treated niobium.

  9. Large grain cavities from pure niobium ingot

    Science.gov (United States)

    Myneni, Ganapati Rao [Yorktown, VA; Kneisel, Peter [Williamsburg, VA; Cameiro, Tadeu [McMurray, PA

    2012-03-06

    Niobium cavities are fabricated by the drawing and ironing of as cast niobium ingot slices rather than from cold rolled niobium sheet. This method results in the production of niobium cavities having a minimum of grain boundaries at a significantly reduced cost as compared to the production of such structures from cold rolled sheet.

  10. Niobium and tantalum

    International Nuclear Information System (INIS)

    Polupanova, L.I.; Volkova, G.A.

    1983-01-01

    General mineralogical-geochemical and analytical characteristics of niobium and tantalum are presented. Potentialities of any analytical methods for determining these elements in various geologic samples are estimated. The following specific techniques are described: neutron + activation determination of Ta, fluorescence X-radiometric determination of Nb and Ta, fluorescence X-ray spectral determination of Nb and Ta, spectrographic determination of Nb and Ta, gravimetric determination of Nb and Ta, their extraction-photometric determination with various reagents (crystal violet, rhodamine 6 Y, butylrhodamine B)

  11. Effect of low-temperature baking on the radio-frequency properties of niobium superconducting cavities for particle accelerators

    International Nuclear Information System (INIS)

    Ciovati, Gianluigi

    2004-01-01

    Radio-frequency superconducting (SRF) cavities are widely used to accelerate a charged particle beam in particle accelerators. The performance of SRF cavities made of bulk niobium has significantly improved over the last ten years and is approaching the theoretical limit for niobium. Nevertheless, RF tests of niobium cavities are still showing some 'anomalous' losses that require a better understanding in order to reliably obtain better performance. These losses are characterized by a marked dependence of the surface resistance on the surface electromagnetic field and can be detected by measuring the quality factor of the resonator as a function of the peak surface field. A low-temperature (100-150 deg. C) 'in situ' bake under ultrahigh vacuum has been successfully applied as final preparation of niobium RF cavities by several laboratories over the last few years. The benefits reported consist mainly of an improvement of the cavity quality factor at low field and a recovery from 'anomalous' losses (so-called 'Q drop') without field emission at higher field. A series of experiments with a CEBAF single-cell cavity have been carried out at Jefferson Lab to carefully investigate the effect of baking at progressively higher temperatures for a fixed time on all the relevant material parameters. Measurements of the cavity quality factor in the temperature range 1.37-280 K and resonant frequency shift between 6-9.3 K provide information about the surface resistance, energy gap, penetration depth, and mean free path. The experimental data have been analyzed with the complete BCS theory of superconductivity. The hydrogen content of small niobium samples inserted in the cavity during its surface preparation was analyzed with nuclear reaction analysis. The single-cell cavity has been tested at three different temperatures before and after baking to gain some insight on thermal conductivity and Kapitza resistance and the data are compared with different models. This paper

  12. Effect of low-temperature baking on the radio-frequency properties of niobium superconducting cavities for particle accelerators

    Science.gov (United States)

    Ciovati, Gianluigi

    2004-08-01

    Radio-frequency superconducting (SRF) cavities are widely used to accelerate a charged particle beam in particle accelerators. The performance of SRF cavities made of bulk niobium has significantly improved over the last ten years and is approaching the theoretical limit for niobium. Nevertheless, RF tests of niobium cavities are still showing some "anomalous" losses that require a better understanding in order to reliably obtain better performance. These losses are characterized by a marked dependence of the surface resistance on the surface electromagnetic field and can be detected by measuring the quality factor of the resonator as a function of the peak surface field. A low-temperature (100-150°C) "in situ" bake under ultrahigh vacuum has been successfully applied as final preparation of niobium RF cavities by several laboratories over the last few years. The benefits reported consist mainly of an improvement of the cavity quality factor at low field and a recovery from "anomalous" losses (so-called "Q drop") without field emission at higher field. A series of experiments with a CEBAF single-cell cavity have been carried out at Jefferson Lab to carefully investigate the effect of baking at progressively higher temperatures for a fixed time on all the relevant material parameters. Measurements of the cavity quality factor in the temperature range 1.37-280K and resonant frequency shift between 6-9.3K provide information about the surface resistance, energy gap, penetration depth, and mean free path. The experimental data have been analyzed with the complete BCS theory of superconductivity. The hydrogen content of small niobium samples inserted in the cavity during its surface preparation was analyzed with nuclear reaction analysis. The single-cell cavity has been tested at three different temperatures before and after baking to gain some insight on thermal conductivity and Kapitza resistance and the data are compared with different models. This paper describes

  13. Studies of niobium and development of niobium resonant RF cavities for accelerator driven system

    International Nuclear Information System (INIS)

    Mondal, Jayanta

    2013-01-01

    The present approach for the fabrication of superconducting radio frequency (SRF) cavities is to roll and deep draw sheets of polycrystalline high-purity niobium. Jefferson Laboratory pioneered the use of large-grain/single-crystal Nb directly sliced from an ingot for the fabrication of single-crystal high-purity Nb SRF cavities. The large grain/single crystal niobium has several potential advantages over the polycrystalline niobium and has become a viable alternative to the standard fine grain (ASTM grain size>6 μm), high purity (RRR ≥ 250 ) niobium for the fabrication of high-performance SRF cavities for particle accelerators. The present study includes the prototype single cell low beta cavity design, fabrication, EB welding and low temperature RF test at 2K. In this study also the medium field Q-Slope has been analyzed with the help of an added non linear term in Heabel's analytical model and a linear increase of surface resistance Rs with the magnetic field

  14. Fatigue behavior of niobium--hydrogen alloys

    International Nuclear Information System (INIS)

    Chung, D.W.; Stoloff, N.S.

    1978-01-01

    The effects of hydrogen on room temperature fatigue behavior of niobium were investigated under both high frequency stress control and low frequency strain control conditions, in air. Hydrogen markedly improved the fatigue life in high frequency tests, while low frequency tests resulted in decreased fatigue life with increasing hydrogen content. Notches in hydrogen-charged alloys reduced high cycle life significantly but had little effect on low cycle tests. Fracture surfaces of annealed niobium mainly exhibited striations, with numerous cracks originating at troughs of striated bands in both stress and strain control tests. The fracture mode for alloys with hydrogen in solution was mixed, with striations interspersed with cleavage facets at high frequencies but generally cleavage steps at low frequencies. For the hydrided alloys, distinctive steps of mixed ductile-brittle appearance were revealed under high frequency conditions, but large cleavage facets only were observed for low frequency tests. The results are discussed in terms of the effects of hydrogen on the cyclic strain hardening rate, as well as on fatigue strength and ductility of niobium

  15. Influence of electropolishing and anodic oxidation on morphology, chemical composition and corrosion resistance of niobium

    Energy Technology Data Exchange (ETDEWEB)

    Sowa, Maciej; Greń, Katarzyna [Faculty of Chemistry, Silesian University of Technology, B. Krzywoustego Street 6, 44-100 Gliwice (Poland); Kukharenko, Andrey I. [Institute of Metal Physics, Russian Academy of Sciences-Ural Division, S. Kovalevskoi Street 18, 620990 Yekaterinburg (Russian Federation); Ural Federal University, Mira Street 19, 620002 Yekaterinburg, Mira str. 19 (Russian Federation); Korotin, Danila M. [Institute of Metal Physics, Russian Academy of Sciences-Ural Division, S. Kovalevskoi Street 18, 620990 Yekaterinburg (Russian Federation); Michalska, Joanna [Faculty of Materials Engineering and Metallurgy, Silesian University of Technology, Krasińskiego Street 8, 40-019 Katowice (Poland); Szyk-Warszyńska, Lilianna; Mosiałek, Michał [Jerzy Haber Institute of Catalysis and Surface Chemistry PAS, Niezapominajek Street 8, 30-239 Kraków (Poland); Żak, Jerzy [Faculty of Chemistry, Silesian University of Technology, B. Krzywoustego Street 6, 44-100 Gliwice (Poland); Pamuła, Elżbieta [AGH University of Science and Technology, Faculty of Materials Science and Ceramics, Mickiewicza Avenue 30, 30-059 Kraków (Poland); Kurmaev, Ernst Z. [Institute of Metal Physics, Russian Academy of Sciences-Ural Division, S. Kovalevskoi Street 18, 620990 Yekaterinburg (Russian Federation); Cholakh, Seif O. [Ural Federal University, Mira Street 19, 620002 Yekaterinburg, Mira str. 19 (Russian Federation); Simka, Wojciech, E-mail: wojciech.simka@polsl.pl [Faculty of Chemistry, Silesian University of Technology, B. Krzywoustego Street 6, 44-100 Gliwice (Poland)

    2014-09-01

    The work presents results of the studies performed on electropolishing of pure niobium in a bath that contained: sulphuric acid, hydrofluoric acid, ethylene glycol and acetanilide. After the electropolishing, the specimens were subjected to anodic passivation in a 1 mol dm{sup −3} phosphoric acid solution at various voltages. The surface morphology, thickness, roughness and chemical composition of the resulting oxide layers were analysed. Thusly prepared niobium samples were additionally investigated in terms of their corrosion resistance in Ringer's solution. The electropolished niobium surface was determined to be smooth and lustrous. The anodisation led to the growth of barrier-like oxide layers, which were enriched in phosphorus species. - Highlights: • Pure niobium was electropolished and subsequently anodised in a H{sub 3}PO{sub 4} solution. • Phosphorus was successfully introduced into the oxide layers after the treatment. • Corrosion resistance of niobium in Ringer's solution was improved after anodising.

  16. Morphology study of niobium pentoxide

    International Nuclear Information System (INIS)

    Romero, R.P.P.; Panta, P.C.; Araujo, A.O. de; Bergmann, C.P.

    2016-01-01

    Currently, Niobium pentoxide (Nb 2 O 5 ) has been studied due to physical properties and their use in obtaining electronic ceramics, optical lenses, pH sensors, special filters for TV receivers, among other applications. This study investigated the morphology of the niobium pentoxide obtained by hydrothermal synthesis from the precursor pentachloride niobium (NbCl 5 ), where the synthesis was carried out at a temperature of 150 and 200 °C for 130 min and the product obtained was calcined at temperatures 600, 800 and 1000 °C for 60 min. The following characterizations were performed for analysis of the material, among them, X-ray diffraction (XRD) for analysis of the crystal structure, thermal gravimetric analysis (TGA) for detecting the existing functional groups and scanning electron microscopy (SEM) for morphology of material. As a result, different morphologies were obtained and consequently different niobium pentoxide properties studied. (author)

  17. Quenching experiments on niobium

    International Nuclear Information System (INIS)

    Schwirtlich, I.A.; Schultz, H.; Max-Planck-Institut fuer Metallforschung, Stuttgart

    1980-01-01

    High-purity niobium wire specimens have been quenched in superfluid helium from near the melting point in order to obtain information on vacancies in this material. The quenched-in resistivity Δsub(pQ) for a quench from 2600 K was very small (approximately 0.3 x 10 -12 Ω m) and near the limit of detection. It is assumed that large quenching losses are responsible for the small quenched-in resistance. From the experimental cooling curve estimates have been made for the formation and migration enthalpies (Hsub(1V)sup(F), Hsub(1V)sup(M)), where Hsub(1V)sup(M)+Hsub(1V)sup(F)=Qsub(1V)sup(SD)=3.62 ev. For Ssub(1V)sup(F), the formation entropy, two different values were assumed. (author)

  18. Interaction of Cr-Ti-Si coating on VN-3 niobium alloy with air environment

    International Nuclear Information System (INIS)

    Lazarev, Eh.M.; Kozlov, A.T.; Monakhova, L.A.

    1985-01-01

    Investigation of heat-resistance, microstructure and phase composition of Cr-Ti-Si coating on VN-3 niobium alloy with air oxidation in the temperature interval of 1200-1600 deg C is conducted. Thermogravimetry, metallography, X-ray diffraction and microprobe analysis methods are used. It is ascertained that the coating is a dense niobium disilicide layer, luriched on the surface with chromium and titanium disilicides and separated and from the protected alloy by a narrow zone of the lowest niobium silicide Nb 5 Si 3 . The coating protective junctions are provided by a selective chromium and titanium disilicides oxidation as well as niobium disilicide oxidation at the temperature of 1600 deg C, and by the rates of niobium and silicon diffusion through Nb 5 SI 3 and NbSi 2 and oxygen diffusion through the amorphous SiO 2

  19. Microstructural evaluation of alumina-niobium and alumina- niobium-zircon ceramics for ballistic application

    International Nuclear Information System (INIS)

    Mota, Juliana Machado da; Lopes, Cristina Moniz Araujo; Melo, Francisco Lourenco Cristovao de

    2009-01-01

    This study aimed to evaluate the microstructural of Alumina- Niobium and Alumina- Niobium-Zircon ceramics. Samples with 3.5 x 4.5 x 34 mm dimensions were prepared by uniaxial pressure (50 MPa) followed by isostatic pressure (300 MPa). The samples were sintered at 1500 ° C for 1 hour. The ceramics obtained were characterized by scanning electron microscopy (SEM) and X-ray diffraction, to evaluate the phases and microstructures. In order to analyze the microstructure, by SEM the samples were prepared using two techniques: heat treatment (1350 ° C for 5 minutes) and thermochemical treatment (500 ° C for 8 minutes in a solution of NaOH and KOH) on polished and fractured surfaces. The results showed that despite differences between the two etchings, both were effective to analyze the microstructure. (author)

  20. Precipitation of hydrides in high purity niobium after different treatments

    Energy Technology Data Exchange (ETDEWEB)

    Barkov, F.; Romanenko, A.; Trenikhina, Y.; Grassellino, A.

    2013-01-01

    Precipitation of lossy non-superconducting niobium hydrides represents a known problem for high purity niobium in superconducting applications. Using cryogenic optical and laser confocal scanning microscopy we have directly observed surface precipitation and evolution of niobium hydrides in samples after different treatments used for superconducting RF cavities for particle acceleration. Precipitation is shown to occur throughout the sample volume, and the growth of hydrides is well described by the fast diffusion-controlled process in which almost all hydrogen is precipitated at $T=140$~K within $\\sim30$~min. 120$^{\\circ}$C baking and mechanical deformation are found to affect hydride precipitation through their influence on the number of nucleation and trapping centers.

  1. Synthesis of niobium nitride by pyrolysis of niobium pentachloride ammines

    International Nuclear Information System (INIS)

    Grebtsova, O.M.; Shulga, Y.M.; Troitskii, V.N.

    1986-01-01

    This paper investigates the conditions for the preparation of niobium nitride in the thermal decomposition of niobium nitride in the thermal decomposition of niobium pentachloride ammines. The synthesis of the ammines was accomplished by the reaction of powdered NbC1 5 with dry ammonia at 210 K. Thermography and x-ray diffraction, spectral, and chemical analyses were used to identify the ammonolysis products. It was established that the products of ammonolysis of NbC1 5 are a mixture of the x-ray-amorphous complex Nb (NH 2 ) /SUB 5-x/ - (NG 3 ) 3 CL 3 (x≅) and 2 moles of NH 4 C1. The steps in the thermal decomposition of this mixture were studied. The phase transition that is observed in the case of further vacuum heat treatment at 1100-1300 K is presented

  2. Niobium interaction with chloride-carbonate melts

    International Nuclear Information System (INIS)

    Kuznetsov, S.A.; Kuznetsova, S.V.

    1996-01-01

    Niobium interaction with chloride-carbonate melt NaCl-KCl-K 2 CO 3 (5 mass %) in the temperature range of 973-1123 K has been studied. The products and niobium corrosion rate have been ascertained, depending on the temperature of melt and time of allowance. Potentials of niobium corrosion have been measured. Refs. 11, figs. 3, tabs. 2

  3. Spectrographic determination of niobium in uranium - niobium alloys

    International Nuclear Information System (INIS)

    Charbel, M.Y.; Lordello, A.R.

    1984-01-01

    A method for the spectrographic determination of niobium in uranium-niobium alloys in the concentration range 1-10% has been developed. The metallic sample is converted to oxide by calcination in a muffle furnace at 800 0 C for two hours. The standards are prepared synthetically by dry-mixing. One part of the sample or standard is added to nineteen parts of graphite powder and the mixture is excited in a DC arc. Hafnium has been used as internal standard. The precision of the method is + - 4.8%. (Author) [pt

  4. Mechanical strenght and niobium and niobium-base alloys substructures

    International Nuclear Information System (INIS)

    Monteiro, W.A.; Andrade, A.H.P. de

    1986-01-01

    Niobium and some of its alloys have been used in several fields of technological applications such as the aerospace, chemical and nuclear industries. This is due to its excelent mechanical stringth at high temperatures and reasonable ductility at low temperatures. In this work, we review the main features of the relationship mechanical strength - substructure in niobium and its alloys, taking into account the presence of impurities, the influence of initial thermal and thermo - mechanical treatments as well as the irradiation by energetic particles. (Author) [pt

  5. Synthesis and Surface-Specific Analysis of Molecular Constituents Relevant to Biogenic Secondary Organic Aerosol Material

    Science.gov (United States)

    Be, A. G.; Upshur, M. A.; Chase, H. M.; Geiger, F.; Thomson, R. J.

    2017-12-01

    Secondary organic aerosol (SOA) particles formed from the oxidation of biogenic volatile organic compounds (BVOCs) remain a principal, yet elusive, class of airborne particulate matter that impacts the Earth's radiation budget. Given the characteristic molecular complexity comprising biogenic SOA particles, chemical information selective to the gas-aerosol interface may be valuable in the investigation of such systems, as surface considerations likely dictate the phenomena driving particle evolution mechanisms and climate effects. In particular, cloud activation processes may be parameterized using the surface tension depression that coincides with partitioning of surface-active organic species to the gas-droplet interface. However, the extent to which surface chemical processes, such as cloud droplet condensation, are influenced by the chemical structure and reactivity of individual surface-active molecules in SOA particles is largely unknown. We seek to study terpene-derived organic species relevant to the surfaces of biogenic SOA particles via synthesis of putative oxidation products followed by analysis using surface-selective physicochemical measurements. Using dynamic surface tension measurements, considerable differences are observed in the surface tension depression of aqueous pendant droplets that contain synthetically prepared ozonolysis products derived from abundant terpene precursors. Furthermore, sum frequency generation spectroscopy is utilized for comparison of the surface vibrational spectral responses of synthesized reference compounds with those observed for laboratory aerosol toward probing the surface composition of SOA material. Such ongoing findings highlight the underlying importance of molecular structure and reactivity when considering the surface chemistry of biogenic terpene-derived atmospheric aerosols.

  6. Niobium electrodeposition from molten fluorides

    International Nuclear Information System (INIS)

    Sartori, A.F.

    1987-01-01

    Niobium electrodeposition from molten alkali fluorides has been studied aiming the application of this technic to the processes of electrorefining and galvanotechnic of this metal. The effects of current density, temperature, niobium concentration in the bath, electrolysis time, substrate nature, ratio between anodic and cathodic areas, electrodes separation and the purity of anodes were investigated in relation to the cathodic current efficiency, electrorefining, electroplating and properties of the deposit and the electrolytic solution. The work also gives the results of the conctruction and operation of a pilot plant for refractory metals electrodeposition and shows the electrorefining and electroplating compared to those obtained at the laboratory scale. (author) [pt

  7. Formation and oxidation resistance of NbSi2 coatings on niobium by pack cementation

    International Nuclear Information System (INIS)

    Li Ming; Song Lixin; Le Jun; Zhang Xiaowei; Pei Baogen; Hu Xingfang

    2005-01-01

    NbSi 2 coatings were formed on niobium by halide-activated pack cementation process. The as-coated niobium samples were oxidized in air up to 1723 K by thermogravimetry method. The surface and cross-sectional morphology, phase composition and element distribution of the NbSi 2 coatings before and after oxidation were characterized by SEM, XRD and EPMA. The results show that the as-formed coatings consist of single phase of hexagonal NbSi 2 and the oxidation resistance of pure niobium can be greatly improved by pack siliconizing. (orig.)

  8. Radiation blistering of niobium in sequence irradiated by helium ions with different energy

    International Nuclear Information System (INIS)

    Das, S.K.; Kaminskij, M.S.; Guseva, M.I.; Gusev, V.M.; Krasulin, Yu.L.; Martynenko, Yu.V.; Rozina, I.A.

    1977-01-01

    The results of the investigation of the blistering of the surface of polycrystalline niobium foils subjected to successive irradiation by helium ions of energies of 3 to 50 keV are reported. The critical doses of irradiation, the types of blisters and the rate of erosion were determined. A comparative analysis of the formation of blisters on cold-rolled and annealed niobium has been made. On cold-rolled niobium the blistering is mainly due to ions with energies of 3 to 80 keV, on annealed niobium of 100 to 500 keV. The erosion of cold-rolled niobium takes place through blisters formed by the action of helium ions with energies of the order of 45 keV, and that of annealed niobium, through helium ions with energies of 100 to 500 keV. The observed differences in the formation of blisters on niobium irradiated with helium ions of a wide range of energies are explained by the change in the diffusion kinetics of implanted ions having a uniform distribution across the thickness of the target

  9. An evolutionary yield function based on Barlat 2000 yield function for the superconducting niobium sheet

    Science.gov (United States)

    Darbandi, Payam; Pourboghrat, Farhang

    2011-08-01

    Superconducting radio frequency (SRF) niobium cavities are widely used in high-energy physics to accelerate particle beams in particle accelerators. The performance of SRF cavities is affected by the microstructure and purity of the niobium sheet, surface quality, geometry, etc. Following optimum strain paths in the forming of these cavities can significantly control these parameters. To select these strain paths, however, information about the mechanical behavior, microstructure, and formability of the niobium sheet is required. In this study the Barlat 2000 yield function has been used as a yield function for high purity niobium. Results from this study showed that, due to intrinsic behavior, it is necessary to evolve the anisotropic coefficients of Barlat's yield function in order to properly model the plastic behavior of the niobium sheet. The accuracy of the newly developed evolutionary yield function was verified by applying it to the modeling of the hydrostatic bulging of the niobium sheet. Also, in a separate attempt crystal plasticity finite element method was use to model the behavior of the polycrystalline niobium sheet with a particular initial texture.

  10. An evolutionary yield function based on Barlat 2000 yield function for the superconducting niobium sheet

    International Nuclear Information System (INIS)

    Darbandi, Payam; Pourboghrat, Farhang

    2011-01-01

    Superconducting radio frequency (SRF) niobium cavities are widely used in high-energy physics to accelerate particle beams in particle accelerators. The performance of SRF cavities is affected by the microstructure and purity of the niobium sheet, surface quality, geometry, etc. Following optimum strain paths in the forming of these cavities can significantly control these parameters. To select these strain paths, however, information about the mechanical behavior, microstructure, and formability of the niobium sheet is required. In this study the Barlat 2000 yield function has been used as a yield function for high purity niobium. Results from this study showed that, due to intrinsic behavior, it is necessary to evolve the anisotropic coefficients of Barlat's yield function in order to properly model the plastic behavior of the niobium sheet. The accuracy of the newly developed evolutionary yield function was verified by applying it to the modeling of the hydrostatic bulging of the niobium sheet. Also, in a separate attempt crystal plasticity finite element method was use to model the behavior of the polycrystalline niobium sheet with a particular initial texture.

  11. Superconducting niobium cavities with high gradients

    International Nuclear Information System (INIS)

    Kneisel, P.; Saito, K.

    1992-01-01

    Present accelerator projects making use of superconducting cavity technology are constructed with design accelerating gradients E acc ranging between 5 MV/m and 8 MV/m and Q-values of several 10 9 . Future plans for upgrades of existing accelerators or for linear colliders call for gradients greater than 15 MV/m corresponding to peak surface electric fields above 30 MV/m. These demands challenge state-of-the-art production technology and require improvements in processing and handling of these cavities to overcome the major performance limitation of field emission loading. This paper reports on efforts to improve the performance of cavities made from niobium from different suppliers by using improved cleaning techniques after processing and ultrahigh vacuum annealing at temperatures of 1400 C. In single cell L-band cavities peak surface electric fields as high as 50 MV/m have been measured without significant field emission loading. (Author) 8 refs., fig

  12. Baking effect on Niobium superconducting RF cavities and its physical interpretation

    Energy Technology Data Exchange (ETDEWEB)

    Saito, K. [High Energy Accelerator Research Organization, Tsukuba, Ibaraki (Japan); Kneisel, P. [Thomas Jefferson Accelerator Facility, VA, (United States)

    2000-07-01

    Recently a very surprising phenomenon has been discovered at JLab and Saclay with chemically polished niobium cavities, which the baking during vacuum evacuation has benefits to improve the cavity performance: high Q and high gradient. We have confirmed the same effect on the electropolished niobium cavities. We have analyzed the temperature dependence of the surface resistance in order to understand this effect in the frame or BCS theory. In this paper these results will be presented. (author)

  13. Study on the relevance of some of the description methods for plateau-honed surfaces

    International Nuclear Information System (INIS)

    Yousfi, M; Mezghani, S; Demirci, I; El Mansori, M

    2014-01-01

    Much work has been undertaken in recent years into the determination of a complete parametric description of plateau-honed surfaces with the intention of making a link between the process conditions, the surface topography and the required functional performances. Different advanced techniques (plateau/valleys decomposition using the normalized Abbott–Firestone curve or morphological operators, multiscale decomposition using continuous wavelets transform, etc) were proposed and applied in different studies. This paper re-examines the current state of developments and addresses a discussion on the relevance of the different proposed parameters and characterization methods for plateau-honed surfaces by considering the control loop manufacturing-characterization-function. The relevance of appropriate characterization is demonstrated through two experimental studies. They consider the effect of the most plateau honing process variables (the abrasive grit size and abrasive indentation velocity in finish-honing and the plateau-honing stage duration and pressure) on cylinder liner surface textures and hydrodynamic friction of the ring-pack system. (paper)

  14. Study of niobium oxidation by photoelectron spectroscopy

    International Nuclear Information System (INIS)

    Durand, C.

    1985-01-01

    The chemical composition of thin oxide layers, grown on clean niobium, in low oxygen pressure, was studied by a surface analysis method: X-ray Photoelectron Spectroscopy. The purpose of this study was to find the best conditions for the building of Nb/Nb oxide/Pb Josephson junctions, and particularly to minimise the interface thickness during the formation of the insulator film (Nb 2 O 5 ) on the metal (Nb). This interface is essentially formed by the monoxide (NbO) and dioxide (NbO 2 ). Nb 3d XPS core level peak positions and area ratios (obtained by the signal decomposition) of the components of the total peak, were used to determine the presence of the different oxidation states II, IV and V, their relative abundance, oxide thicknesses and their depth distribution. All this information was extracted by a special numerical procedure [fr

  15. Producing titanium-niobium alloy by high energy beam

    Energy Technology Data Exchange (ETDEWEB)

    Sharkeev, Yu. P., E-mail: sharkeev@ispms.tsc.ru [Institute of Strength Physics and Materials Science, SB RAS, 2/4 Akademicheski Prosp., Tomsk, 634055 (Russian Federation); National Research Tomsk Polytechnic University, 30 Lenin Av., Tomsk, 634050 (Russian Federation); Golkovski, M. G., E-mail: golkoski@mail.ru [Budker Institute of Nuclear Physics, 11 Akademika Lavrentiev Prosp., Novosibirsk, 630090 (Russian Federation); Glukhov, I. A., E-mail: gia@ispms.tsc.ru; Eroshenko, A. Yu., E-mail: eroshenko@ispms.tsc.ru; Fortuna, S. V., E-mail: s-fortuna@mail.ru [Institute of Strength Physics and Materials Science, SB RAS, 2/4 Akademicheski Prosp., Tomsk, 634055 (Russian Federation); Bataev, V. A., E-mail: bataev@vadm.ustu.ru [Novosibirsk State Technical University, 20 K. Marx Prosp., Novosibirsk, 630073 (Russian Federation)

    2016-01-15

    The research is involved in producing a Ti-Nb alloy surface layer on titanium substrate by high energy beam method, as well as in examining their structures and mechanical properties. Applying electron-beam cladding it was possible to produce a Ti-Nb alloy surface layer of several millimeters, where the niobium concentration was up to 40% at. and the structure itself could be related to martensite quenching structure. At the same time, a significant microhardness increase of 3200-3400 MPa was observed, which, in its turn, is connected with the formation of martensite structure. Cladding material of Ti-Nb composition could be the source in producing alloys of homogeneous microhardness and desired concentration of alloying niobium element.

  16. BIOPHYSICAL PROPERTIES OF NUCLEIC ACIDS AT SURFACES RELEVANT TO MICROARRAY PERFORMANCE.

    Science.gov (United States)

    Rao, Archana N; Grainger, David W

    2014-04-01

    Both clinical and analytical metrics produced by microarray-based assay technology have recognized problems in reproducibility, reliability and analytical sensitivity. These issues are often attributed to poor understanding and control of nucleic acid behaviors and properties at solid-liquid interfaces. Nucleic acid hybridization, central to DNA and RNA microarray formats, depends on the properties and behaviors of single strand (ss) nucleic acids (e.g., probe oligomeric DNA) bound to surfaces. ssDNA's persistence length, radius of gyration, electrostatics, conformations on different surfaces and under various assay conditions, its chain flexibility and curvature, charging effects in ionic solutions, and fluorescent labeling all influence its physical chemistry and hybridization under assay conditions. Nucleic acid (e.g., both RNA and DNA) target interactions with immobilized ssDNA strands are highly impacted by these biophysical states. Furthermore, the kinetics, thermodynamics, and enthalpic and entropic contributions to DNA hybridization reflect global probe/target structures and interaction dynamics. Here we review several biophysical issues relevant to oligomeric nucleic acid molecular behaviors at surfaces and their influences on duplex formation that influence microarray assay performance. Correlation of biophysical aspects of single and double-stranded nucleic acids with their complexes in bulk solution is common. Such analysis at surfaces is not commonly reported, despite its importance to microarray assays. We seek to provide further insight into nucleic acid-surface challenges facing microarray diagnostic formats that have hindered their clinical adoption and compromise their research quality and value as genomics tools.

  17. BIOPHYSICAL PROPERTIES OF NUCLEIC ACIDS AT SURFACES RELEVANT TO MICROARRAY PERFORMANCE

    Science.gov (United States)

    Rao, Archana N.; Grainger, David W.

    2014-01-01

    Both clinical and analytical metrics produced by microarray-based assay technology have recognized problems in reproducibility, reliability and analytical sensitivity. These issues are often attributed to poor understanding and control of nucleic acid behaviors and properties at solid-liquid interfaces. Nucleic acid hybridization, central to DNA and RNA microarray formats, depends on the properties and behaviors of single strand (ss) nucleic acids (e.g., probe oligomeric DNA) bound to surfaces. ssDNA’s persistence length, radius of gyration, electrostatics, conformations on different surfaces and under various assay conditions, its chain flexibility and curvature, charging effects in ionic solutions, and fluorescent labeling all influence its physical chemistry and hybridization under assay conditions. Nucleic acid (e.g., both RNA and DNA) target interactions with immobilized ssDNA strands are highly impacted by these biophysical states. Furthermore, the kinetics, thermodynamics, and enthalpic and entropic contributions to DNA hybridization reflect global probe/target structures and interaction dynamics. Here we review several biophysical issues relevant to oligomeric nucleic acid molecular behaviors at surfaces and their influences on duplex formation that influence microarray assay performance. Correlation of biophysical aspects of single and double-stranded nucleic acids with their complexes in bulk solution is common. Such analysis at surfaces is not commonly reported, despite its importance to microarray assays. We seek to provide further insight into nucleic acid-surface challenges facing microarray diagnostic formats that have hindered their clinical adoption and compromise their research quality and value as genomics tools. PMID:24765522

  18. Effects of niobium additions on the structure, depth, and austenite grain size of the case of carburized 0.07% C steels

    Science.gov (United States)

    Islam, M. A.; Bepari, M. M. A.

    1996-10-01

    Carbon (0.07%) steel samples containing about 0.04% Nb singly and in combination with nitrogen were carburized in a natural Titas gas atmosphere at a temperature of 1223 K (950 °C) and a pressure of about 0.10 MPa for 1/2 to 4 h, followed by slow cooling in the furnace. Their microstructures were studied by optical microscopy. The austenite grain size of the case and the case depths were determined on baseline samples of low-carbon steels and also on niobium and (Nb + N) microalloyed steel samples. It was found that, when compared to the baseline steel, niobium alone or in combination with nitrogen decreased the thickness of cementite network near the surface of the carburized case of the steels. However, niobium in combination with nitrogen was more effective than niobium in reducing the thickness of cementite network. Niobium with or without nitrogen inhibited the formation of Widmanstätten cementite plates at grain boundaries and within the grains near the surface in the hypereutectoid zone of the case. It was also revealed that, when compared to the baseline steel, niobium decreased the case depth of the carburized steels, but that niobium with nitrogen is more effective than niobium alone in reducing the case depth. Niobium as niobium carbide (NbC) and niobium in the presence of nitrogen as niobium carbonitride, [Nb(C,N)] particles refined the austenite grain size of the carburized case, but Nb(C,N) was more effective than NbC in inhibiting austenite grain growth.

  19. Free energy of hydration of niobium oxide

    International Nuclear Information System (INIS)

    Plodinec, M.J.

    1996-01-01

    Some of the glasses being formulated by SRTC researchers contain niobium oxide. In this report, the free energy of hydration of the oxide is calculated from the free energies of formation of the oxide, the hydroxide, and water. This value can be used in calculations of the free energy of hydration of glasses containing niobium

  20. More Realistic Face Model Surface Improves Relevance of Pediatric In-Vitro Aerosol Studies.

    Science.gov (United States)

    Amirav, Israel; Halamish, Asaf; Gorenberg, Miguel; Omar, Hamza; Newhouse, Michael T

    2015-01-01

    Various hard face models are commonly used to evaluate the efficiency of aerosol face masks. Softer more realistic "face" surface materials, like skin, deform upon mask application and should provide more relevant in-vitro tests. Studies that simultaneously take into consideration many of the factors characteristic of the in vivo face are lacking. These include airways, various application forces, comparison of various devices, comparison with a hard-surface model and use of a more representative model face based on large numbers of actual faces. To compare mask to "face" seal and aerosol delivery of two pediatric masks using a soft vs. a hard, appropriately representative, pediatric face model under various applied forces. Two identical face models and upper airways replicas were constructed, the only difference being the suppleness and compressibility of the surface layer of the "face." Integrity of the seal and aerosol delivery of two different masks [AeroChamber (AC) and SootherMask (SM)] were compared using a breath simulator, filter collection and realistic applied forces. The soft "face" significantly increased the delivery efficiency and the sealing characteristics of both masks. Aerosol delivery with the soft "face" was significantly greater for the SM compared to the AC (pmasks was observed with the hard "face." The material and pliability of the model "face" surface has a significant influence on both the seal and delivery efficiency of face masks. This finding should be taken into account during in-vitro aerosol studies.

  1. Relevance of plastic limit loads to reference stress approach for surface cracked cylinder problems

    International Nuclear Information System (INIS)

    Kim, Yun-Jae; Shim, Do-Jun

    2005-01-01

    To investigate the relevance of the definition of the reference stress to estimate J and C* for surface crack problems, this paper compares finite element (FE) J and C* results for surface cracked pipes with those estimated according to the reference stress approach using various definitions of the reference stress. Pipes with part circumferential inner surface cracks and finite internal axial cracks are considered, subject to internal pressure and global bending. The crack depth and aspect ratio are systematically varied. The reference stress is defined in four different ways using (i) a local limit load (ii), a global limit load, (iii) a global limit load determined from the FE limit analysis, and (iv) the optimised reference load. It is found that the reference stress based on a local limit load gives overall excessively conservative estimates of J and C*. Use of a global limit load clearly reduces the conservatism, compared to that of a local limit load, although it can sometimes provide non-conservative estimates of J and C*. The use of the FE global limit load gives overall non-conservative estimates of J and C*. The reference stress based on the optimised reference load gives overall accurate estimates of J and C*, compared to other definitions of the reference stress. Based on the present findings, general guidance on the choice of the reference stress for surface crack problems is given

  2. High-flux He+ irradiation effects on surface damages of tungsten under ITER relevant conditions

    International Nuclear Information System (INIS)

    Liu, Lu; Liu, Dongping; Hong, Yi; Fan, Hongyu; Ni, Weiyuan; Yang, Qi; Bi, Zhenhua; Benstetter, Günther; Li, Shouzhe

    2016-01-01

    A large-power inductively coupled plasma source was designed to perform the continuous helium ions (He + ) irradiations of polycrystalline tungsten (W) under International Thermonuclear Experimental Reactor (ITER) relevant conditions. He + irradiations were performed at He + fluxes of 2.3 × 10 21 –1.6 × 10 22 /m 2  s and He + energies of 12–220 eV. Surface damages and microstructures of irradiated W were observed by scanning electron microscopy. This study showed the growth of nano-fuzzes with their lengths of 1.3–2.0 μm at He + energies of >70 eV or He + fluxes of >1.3 × 10 22 /m 2  s. Nanometer-sized defects or columnar microstructures were formed in W surface layer due to low-energy He + irradiations at an elevated temperature (>1300 K). The diffusion and coalescence of He atoms in W surface layers led to the growth and structures of nano-fuzzes. This study indicated that a reduction of He + energy below 12–30 eV may greatly decrease the surface damage of tungsten diverter in the fusion reactor.

  3. Synthesis, characterization, and catalytic application of ordered mesoporous carbon–niobium oxide composites

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Juan-Li; Gao, Shuang; Liu, Chun-Ling; Liu, Zhao-Tie; Dong, Wen-Sheng, E-mail: wsdong@snnu.edu.cn

    2014-11-15

    Graphical abstract: The ordered mesoporous carbon–niobium oxide composites have been synthesized by a multi-component co-assembly method associated with a carbonization process. - Highlights: • Ordered mesoporous carbon–niobium oxide composites were synthesized. • The content of Nb{sub 2}O{sub 5} in the composites could be tuned from 38 to 75%. • Niobium species were highly dispersed in amorphous carbon framework walls. • The composites exhibited good catalytic performance in the dehydration of fructose. - Abstract: Ordered mesoporous carbon–niobium oxide composites have been synthesized by a multi-component co-assembly method associated with a carbonization process using phenolic resol as carbon source, niobium chloride as precursor and amphiphilic triblock copolymer Pluronic F127 as template. The resulting materials were characterized using a combination of techniques including differential scanning calorimetry–thermogravimetric analysis, N{sub 2} physical adsorption, X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy. The results show that with increasing the content of Nb{sub 2}O{sub 5} from 38 to 75% the specific surface area decreases from 306.4 to 124.5 m{sup 2} g{sup −1}, while the ordered mesoporous structure is remained. Niobium species is well dispersed in the amorphous carbon framework. The mesoporous carbon–niobium oxide composites exhibit high catalytic activity in the dehydration of fructose to 5-hydroxymethylfurfural. A 100% conversion of fructose and a 76.5% selectivity of 5-hydroxymethylfurfural were obtained over the carbon–niobium oxide composite containing 75% Nb{sub 2}O{sub 5} under the investigated reaction conditions.

  4. Corrosion behavior of niobium coated 304 stainless steel in acid solution

    Energy Technology Data Exchange (ETDEWEB)

    Pan, T.J., E-mail: tjpan@cczu.edu.cn [School of Material Science and Engineering, Jiangsu Collaborative Innovation Center for Photovolatic Science and Engineering, Changzhou University, Changzhou 213164 (China); Jiangsu Key Laboratory of Material Surface Technology, Changzhou 213164 (China); Chen, Y.; Zhang, B. [School of Material Science and Engineering, Jiangsu Collaborative Innovation Center for Photovolatic Science and Engineering, Changzhou University, Changzhou 213164 (China); Hu, J. [School of Material Science and Engineering, Jiangsu Collaborative Innovation Center for Photovolatic Science and Engineering, Changzhou University, Changzhou 213164 (China); Jiangsu Key Laboratory of Material Surface Technology, Changzhou 213164 (China); Li, C. [Light Industry College of Liaoning University, Shenyang 110036 (China)

    2016-04-30

    Highlights: • The Nb coating produced by HEMAA offers good protection for 304SS in acid solution. • The coating increases corrosion potential and induces decrease of corrosion rate. • The protection of coating is ascribed to the stability of Nb in acid solution. - Abstract: The niobium coating is fabricated on the surface of AISI Type 304 stainless steel (304SS) by using a high energy micro arc alloying technique in order to improvecorrosion resistance of the steel against acidic environments. The electrochemical corrosion resistance of the niobium coating in 0.7 M sulfuric acid solutions is evaluated by electrochemical impedance spectroscopy, potentiodynamic polarization and the open circuit potential versus time. Electrochemical measurements indicate that the niobium coating increases the free corrosion potential of the substrate by 110 mV and a reduction in the corrosion rate by two orders of magnitude compared to the substrate alone. The niobium coating maintains large impedance and effectively offers good protection for the substrate during the long-term exposure tests, which is mainly ascribed to the niobium coating acting inhibiting permeation of corrosive species. Finally, the corresponding electrochemical impedance models are proposed to elucidate the corrosion resistance behavior of the niobium coating in acid solutions.

  5. Corrosion behavior of niobium coated 304 stainless steel in acid solution

    International Nuclear Information System (INIS)

    Pan, T.J.; Chen, Y.; Zhang, B.; Hu, J.; Li, C.

    2016-01-01

    Highlights: • The Nb coating produced by HEMAA offers good protection for 304SS in acid solution. • The coating increases corrosion potential and induces decrease of corrosion rate. • The protection of coating is ascribed to the stability of Nb in acid solution. - Abstract: The niobium coating is fabricated on the surface of AISI Type 304 stainless steel (304SS) by using a high energy micro arc alloying technique in order to improvecorrosion resistance of the steel against acidic environments. The electrochemical corrosion resistance of the niobium coating in 0.7 M sulfuric acid solutions is evaluated by electrochemical impedance spectroscopy, potentiodynamic polarization and the open circuit potential versus time. Electrochemical measurements indicate that the niobium coating increases the free corrosion potential of the substrate by 110 mV and a reduction in the corrosion rate by two orders of magnitude compared to the substrate alone. The niobium coating maintains large impedance and effectively offers good protection for the substrate during the long-term exposure tests, which is mainly ascribed to the niobium coating acting inhibiting permeation of corrosive species. Finally, the corresponding electrochemical impedance models are proposed to elucidate the corrosion resistance behavior of the niobium coating in acid solutions.

  6. Review of ingot niobium as a material for superconducting radiofrequency accelerating cavities

    Energy Technology Data Exchange (ETDEWEB)

    Kneisel, P., E-mail: kneisel@jlab.org [Jefferson Lab, Newport News, VA 23606 (United States); Ciovati, G.; Dhakal, P. [Jefferson Lab, Newport News, VA 23606 (United States); Saito, K. [Michigan State University, East Lansing, MI 48824 (United States); Singer, W.; Singer, X. [DESY, Notkestrasse 85, D-22607 Hamburg (Germany); Myneni, G.R., E-mail: rao@jlab.org [Jefferson Lab, Newport News, VA 23606 (United States)

    2015-02-21

    As a result of collaboration between Jefferson Lab and niobium manufacturer Companhia Brasileira de Metalurgia e Mineração (CBMM), ingot niobium was explored as a possible material for superconducting radiofrequency (SRF) cavity fabrication. The first single cell cavity from large-grain high purity niobium was fabricated and successfully tested at Jefferson Lab in 2004. This work triggered research activities in other SRF laboratories around the world. Large-grain (LG) niobium became not only an interesting alternative material for cavity builders, but also material scientists and surface scientists were eager to participate in the development of this technology. Many single cell cavities made from material of different suppliers have been tested successfully and several multi-cell cavities have shown performances comparable to the best cavities made from standard fine-grain niobium. Several 9-cell cavities fabricated by Research Instruments and tested at DESY exceeded the best performing fine grain cavities with a record accelerating gradient of E{sub acc}=45.6 MV/m. The quality factor of those cavities was also higher than that of fine-grain (FG) cavities processed with the same methods. Such performance levels push the state-of-the art of SRF technology and are of great interest for future accelerators. This contribution reviews the development of ingot niobium technology and highlights some of the differences compared to standard FG material and opportunities for further developments.

  7. The relevance of rooftops: Analyzing the microscale surface energy balance in the Chicago region

    Science.gov (United States)

    Khosla, Radhika

    interior through the roof, and the physical properties of the surface. These results hold particular relevance for urban heat island mitigation strategies. Based on the results of this work, recommendations are proposed for widespread adoption of various techniques that enhance building energy efficiency (particularly targeting rooftops), mitigate the negative impacts of the urban heat island, and overcome the current barriers to transforming the market.

  8. Hydroforming SRF Three-cell Cavity from Seamless Niobium Tube

    Energy Technology Data Exchange (ETDEWEB)

    Yamanaka, Masashi [KEK, Tsukuba; Dohmae, Takeshi [KEK, Tsukuba; Hocker, Andy [Fermilab; Inoue, Hitoshi [KEK, Tsukuba; Park, Gunn-Tae [KEK, Tsukuba; Tajima, Tsuyoshi [Los Alamos; Umemori, Kensei [KEK, Tsukuba

    2016-06-01

    We are developing the manufacturing method for superconducting radio frequency (SRF) cavities by using a hydroforming instead of using conventional electron beam welding. We expect higher reliability and reduced cost with hydroforming. For successful hydroforming, high-purity seamless niobium tubes with good formability as well as advancing the hydroforming technique are necessary. Using a seamless niobium tube from ATI Wah Chang, we were able to successfully hydroform a 1.3 GHz three-cell TESLA-like cavity and obtained an Eacc of 32 MV/m. A barrel polishing process was omitted after the hydroforming. The vertical test was carried out with very rough inside surface. We got amazing and interesting result.

  9. The Resonance Integral of Niobium

    Energy Technology Data Exchange (ETDEWEB)

    Hellstrand, E; Lundgren, G

    1962-08-15

    The resonance integral of niobium has been studied by both pile oscillator and activation techniques. A value of 8.15b {+-} 0.65 b was obtained for the infinitely dilute integral. In addition, the variation of the resonance integral with foil thickness has been measured for thicknesses in the range 0.06 mm to 1.36 mm. A separate study of the half-life of the isomeric state in {sup 94}Nb yielded a value T{sub 1/2} = 6.30 - 0.03 m which is about 5 % lower than the value given in literature.

  10. Influence of surface features of hydroxyapatite on the adsorption of proteins relevant to bone regeneration.

    Science.gov (United States)

    Fernández-Montes Moraleda, Belén; San Román, Julio; Rodríguez-Lorenzo, Luís M

    2013-08-01

    Protein-surface interaction may determine the success or failure of an implanted device. Not much attention have been paid to the specific surface parametes of hydroxyapatite (OHAp) that modulates and determines the formation and potential activity of the layer of proteins that is first formed when the material get in contact with the host tissue. the influence of specific surface area (SSA), crystallite size (CS) and particle size (PS) of OHAp on the adsorption of proteins relevant for bone regeneration is evaluated in this article. OHAp have been prepared by a wet chemical reaction of Ca(OH)2 with H3PO4. One set of reactions included poly acrylic acid in the reactant solution to modify the properties of the powder. Fibrinogen (Fg) Fraction I, type I: from Human plasma, (67% Protein), and Fibronectin (Fn) from Human plasma were selected to perform the adsorption experiments. The analysis of protein adsorption was carried out by UV/Vis spectrometry. A lower SSA and a different aspect ratio are obtained when the acrylic acid is included in the reaction badge. The deconvolution of the amide I band on the Raman spectra of free and adsorbed proteins reveals that the interaction apatite-protein happens through the carboxylate groups of the proteins. The combined analysis of CS, SSA and PS should be considered on the design of OHAp materials intended to interact with proteins. Copyright © 2013 Wiley Periodicals, Inc.

  11. Niobium stainless steel for implants

    International Nuclear Information System (INIS)

    Rollo, J.M.D.A.

    1983-01-01

    The materials that have often been used, during the last two or three decades, to carry out materials for implants are made according to the specifications: a)A.S.T.M. (F.55-76, F.56-76, F.138-76, F.139-76) stainless steel b)A.S.T.M. (F.75-76), cobalt-chromium-molybdenum alloys. c)A.S.T.M. (F.90-76), cobalt-chromium-tungsten-nickel alloys. d)A.S.T.M. (F.67-77), unalloyed titanium. e)A.S.T.M. (F.136-70), titanium alloys. It was the purpose of retaking them, toverify the niobium influence as alloy element in ANSI/ASTM F.55-76 classification stainless steels, usually for these materials elaboration. The problem by substituting molybdenum total or partially for niobium, by comparing the mechanical and corrosion properties, and biocompatibility is presented, by pointing out the variables of these substitutions, when we employ this new material to perform materials for implants. (Author) [pt

  12. Niobium Nb and tantalum Ta

    International Nuclear Information System (INIS)

    Busev, A.I.; Tiptsova, V.G.; Ivanov, V.M.

    1978-01-01

    The basic methods for determining niobium and tantalum in various objects are described. Nb and Ta are separated with the aid of N-benzoyl-N-phenylhydroxylamine by precipitating Nb(5) from a tartaric acid solution with subsequent precipitation of Ta from the filtrate. The gravimetric determination of Nb and Ta in steels is based on their quantitative separation from a diluted solution by way of hydrolysis with subsequent after-precipitation with phenylarsonic acid (in the absence of W). The gravimetric determination of Nb in the presence of W is carried out with the aid of Cupferron. To determine Nb in its carbide, Nb(5) reduced to Nb(3) is titrated with a solution of K 2 Cr 2 O 7 in the presence of phenyl-anthranilic acid. The photometric determination of Nb in tungsten-containing steels and in ores containing Ti, W, Mo and Cr is based on the rhodanide method. Nb is determined in alloys with Zr and Ti photometrically with the aid of 4-(2-pyridylazo)-resorcin and in alloyed steels with the aid of benzhydroxamic acid. The latter complex is extracted with chloroform. This method is used to determine Nb in rocks. The photometric determination of Ta in TiCl 4 is carried out with the aid of pyrogallol, in commercial niobium with the aid of methyl violet, and in steel with the aid of 4-(-pyridylazo)-resorcin. Also described is the polarographic determination of Nb in tantalum pentoxide

  13. Enhanced surface functionality via plasma modification and plasma deposition techniques to create more biologically relevant materials

    Science.gov (United States)

    Shearer, Jeffrey C.

    Functionalizing nanoparticles and other unusually shaped substrates to create more biologically relevant materials has become central to a wide range of research programs. One of the primary challenges in this field is creating highly functionalized surfaces without modifying the underlying bulk material. Traditional wet chemistry techniques utilize thin film depositions to functionalize nanomaterials with oxygen and nitrogen containing functional groups, such as --OH and --NHx. These functional groups can serve to create surfaces that are amenable to cell adhesion or can act as reactive groups for further attachment of larger structures, such as macromolecules or antiviral agents. Additional layers, such as SiO2, are often added between the nanomaterial and the functionalized coating to act as a barrier films, adhesion layers, and to increase overall hydrophilicity. However, some wet chemistry techniques can damage the bulk material during processing. This dissertation examines the use of plasma processing as an alternative method for producing these highly functionalized surfaces on nanoparticles and polymeric scaffolds through the use of plasma modification and plasma enhanced chemical vapor deposition techniques. Specifically, this dissertation will focus on (1) plasma deposition of SiO2 barrier films on nanoparticle substrates; (2) surface functionalization of amine and alcohol groups through (a) plasma co-polymerization and (b) plasma modification; and (3) the design and construction of plasma hardware to facilitate plasma processing of nanoparticles and polymeric scaffolds. The body of work presented herein first examines the fabrication of composite nanoparticles by plasma processing. SiOxC y and hexylamine films were coated onto TiO2 nanoparticles to demonstrate enhanced water dispersion properties. Continuous wave and pulsed allyl alcohol plasmas were used to produce highly functionalized Fe2 O3 supported nanoparticles. Specifically, film composition was

  14. Anomalous diffusion in niobium. Study of solute diffusion mechanism of iron in niobium

    International Nuclear Information System (INIS)

    Ablitzer, D.

    1977-01-01

    In order to explain anomalously high diffusion velocities observed for iron diffusion in niobium, the following parameters were measured: isotope effect, b factor (which expresses the effect of iron on niobium self-diffusion), self-diffusion coefficient of niobium, solute diffusion coefficient of iron in niobium. The results obtained show that neither pure vacancy models, nor diffusion in the lattice defects (dislocations, sub-boundaries, grain boundaries), nor pure interstitialy mechanisms, nor simple or cyclic exchange mechanisms agree with experiments. A mechanism is proposed which considers an equilibrium between substitution iron atoms and interstitial iron atoms. The diffusion of iron then occurs through interstitial vancancy pairs [fr

  15. Fabrication of superhydrophobic niobium pentoxide thin films by anodization

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Bong-Yong [Future Convergence Ceramic Division, Korea Institute of Ceramic Engineering and Technology, Seoul 153-801 (Korea, Republic of); Jung, Eun-Hye [Future Convergence Ceramic Division, Korea Institute of Ceramic Engineering and Technology, Seoul 153-801 (Korea, Republic of); Department of Chemical Engineering, Inha University, Incheon 402-024 (Korea, Republic of); Kim, Jin-Ho, E-mail: jhkim@kicet.re.kr [Electronic and Optic Materials Division, Korea Institute of Ceramic Engineering and Technology, Seoul 153-801 (Korea, Republic of)

    2014-07-01

    We report a simple method to fabricate a niobium oxide film with a lotus-like micro–nano surface structure. Self-assembled niobium pentoxide (Nb{sub 2}O{sub 5}) films with superhydrophobic property were fabricated by an anodization and a hydrophobic treatment. This process has several advantages such as low cost, simplicity and easy coverage of a large area. The surface of fabricated Nb{sub 2}O{sub 5} film was changed from hydrophilic to superhydrophobic surface by a treatment using fluoroaldyltrimethoxysilane (FAS) solution. This value is considered to be the lowest surface free energy of any solid, based on the alignment of -CF{sub 3} groups on the surface. In particular, among FAS coated surfaces, the micro–nano complex cone structured Nb{sub 2}O{sub 5} film showed the highest water-repellent property with a static contact angle of ca. 162°. This study gives promising routes from biomimetic superhydrophobic surfaces.

  16. Effect of passivation with CO on the electrochemical corrosion behavior of uranium-niobium alloy

    International Nuclear Information System (INIS)

    Fu Xiaoguo; Dai Lianxin; Zou Juesheng; Bai Chaomao; Wang Xiaolin

    2000-01-01

    Electrochemical studies are performed to investigate the corrosion resistance of uranium-niobium alloy before and after passivated with carbon monoxide. Using X-ray photoelectron spectroscopy (XPS), the surface composition of specimen passivated with carbon monoxide is determined. The corrosion resistance of uranium-niobium alloy is well improved because the passive layer (UC/UC x O y + Nb 2 O 5 + UO 2 ) on surface serves as passive film and increases the anodic impedance after the specimen is passivated with carbon monoxide

  17. Enhanced proton conductivity of niobium phosphates by interfacing crystal grains with an amorphous functional phase

    DEFF Research Database (Denmark)

    Huang, Yunjie; Yu, Lele; Li, Haiyan

    2016-01-01

    Niobium phosphate is an interesting proton conductor operational in the intermediate temperature range. In the present work two forms of phosphates were prepared: an amorphous one with high specific area and a crystalline one with low specific surface area. Both phosphates exhibited very low prot...... the high surface area amorphous phosphate was used as the precursor. At 250 °C thus obtained niobium phosphate showed a high and stable conductivity of 0.03 S cm−1 under dry atmosphere and of 0.06 S cm−1 at a water partial pressure of 0.12 atm....... conductivities. An activation process was developed to convert the phosphates into crystal grains with a phosphorus rich amorphous phase along the grain boundaries. As a result, the obtained niobium phosphates showed considerably enhanced and stable proton conductivities. The activation effect was prominent when...

  18. The electrodeposition of niobium on tungsten

    International Nuclear Information System (INIS)

    Taylor, R.G.

    1977-03-01

    The electrodeposition of niobium on a tungsten substrate has been demonstrated by electrolysis of an alkali metal fluoride melt. The deposit produced was non-porous, coherent and formed a good bond to the substrate. (author)

  19. Polarography of niobium in hydrochloric acid

    International Nuclear Information System (INIS)

    Henrion, G.; Adler, F.; Andreas, B.

    1978-01-01

    Dependence between the limiting current and the concentration of niobium and hydrochloric acid has been investigated. With the decrease of niobium concentration the hydrolysis and condensation reactions proceed slower. The time dependence of condensation is shown using ethylene glycol which delays the condensation because of complexation of Nb(5). Hydroxylamine hydrochloride increases the limiting current by a kinetic effect by one order of magnitude which was observed clearly by cyclic voltammetry. Even small amounts of ethylene glycol suppress the kinetic effect. Polarographic determination of niobium in HCl as a supporting electrolyte is possible in concentration above 10 M only. Addition of ethylene glycol and hydroxylamine hydrochloride enables determination of small amounts of niobium in 4 M HCl. (author)

  20. Hydride Olefin complexes of tantalum and niobium

    NARCIS (Netherlands)

    Klazinga, Aan Hendrik

    1979-01-01

    This thesis describes investigations on low-valent tantalum and niobium hydride and alkyl complexes, particularly the dicyclopentadienyl tantalum hydride olefin complexes Cp2Ta(H)L (L=olefin). ... Zie: Summary

  1. Ultrafast relaxation dynamics of a biologically relevant probe dansyl at the micellar surface.

    Science.gov (United States)

    Sarkar, Rupa; Ghosh, Manoranjan; Pal, Samir Kumar

    2005-02-01

    We report picosecond-resolved measurement of the fluorescence of a well-known biologically relevant probe, dansyl chromophore at the surface of a cationic micelle (cetyltrimethylammonium bromide, CTAB). The dansyl chromophore has environmentally sensitive fluorescence quantum yields and emission maxima, along with large Stokes shift. In order to study the solvation dynamics of the micellar environment, we measured the fluorescence of dansyl chromophore attached to the micellar surface. The fluorescence transients were observed to decay (with time constant approximately 350 ps) in the blue end and rise with similar timescale in the red end, indicative of solvation dynamics of the environment. The solvation correlation function is measured to decay with time constant 338 ps, which is much slower than that of ordinary bulk water. Time-resolved anisotropy of the dansyl chromophore shows a bi-exponential decay with time constants 413 ps (23%) and 1.3 ns (77%), which is considerably slower than that in free solvents revealing the rigidity of the dansyl-micelle complex. Time-resolved area-normalized emission spectroscopic (TRANES) analysis of the time dependent emission spectra of the dansyl chromophore in the micellar environment shows an isoemissive point at 21066 cm-1. This indicates the fluorescence of the chromophore contains emission from two kinds of excited states namely locally excited state (prior to charge transfer) and charge transfer state. The nature of the solvation dynamics in the micellar environments is therefore explored from the time-resolved anisotropy measurement coupled with the TRANES analysis of the fluorescence transients. The time scale of the solvation is important for the mechanism of molecular recognition.

  2. Mineral Resource of the Month: Niobium

    Science.gov (United States)

    Papp, John F.

    2014-01-01

    Niobium, also called columbium, is a transition metal with a very high melting point. It is in greatest demand in industrialized countries, like the United States, because of its defense-related uses in the aerospace, energy and transportation industries. Niobium is used mostly to make high-strength, low-alloy (HSLA) steel and stainless steel. HSLA steels are used in large-diameter pipes for oil and natural gas pipelines and automobile wheels.

  3. Superconductivity and electronic structure of superpure niobium. 3. Magnetoconductivity and magnetic breakdown in large magnetic fields

    International Nuclear Information System (INIS)

    Alekseevskij, N.E.; Nizhankovskij, V.I.; Bertel', K.-X.

    1976-01-01

    Measurements have been of electric conductivity and magnetoresistance of niobium monocrystals with various orientations in helium and hydrogen temperature regions in steady-state magnetic fields of up to 175 ke. At helium temperatures the resistance is shown to be proportional to the square of temperature. A significant longitudinal magnetoresistance of niobium has been established, depending on the sample orientation. Its initiation is attributed to the open nature of the niobium Fermi surface. As a result of studying the lateral magnetoresistance in fields of up to 92 ke, a stereographic projection of niobium open directions has been constructed. Open trajectories exist both in two-dimensional regions around the directions [100] and [111] and along the symmetry lines. Studies conducted in fields of up to 175 ke have revealed a magnetic break- own leading to the conversion of the open trajectories to the closed ones. A comprehensive picture of the magnetic break-down in niobium has been obtained, and on the basis of the coherent model an expression has been derived describing the impact of this break-down on the resistance. Comparison between experimental and theoretical dependences of the magnetoresistance on the field characteristics has provided the value of the break-down field H 0 =280 ke

  4. Loading rate and test temperature effects on fracture of in situ niobium silicide-niobium composites

    International Nuclear Information System (INIS)

    Rigney, J.D.; Lewandowski, J.J.

    1996-01-01

    Arc cast, extruded, and heat-treated in situ composites of niobium silicide (Nb 5 Si 3 ) intermetallic with niobium phases (primary--Nb p and secondary--Nb s ) exhibited high fracture resistance in comparison to monolithic Nb 5 Si 3 . In toughness tests conducted at 298 K and slow applied loading rates, the fracture process proceeded by the microcracking of the Nb 5 Si 3 and plastic deformation of the Nb p and Nb s phases, producing resistance-curve behavior and toughnesses of 28 MPa√m with damage zone lengths less than 500 microm. The effects of changes in the Nb p yield strength and fracture behavior on the measured toughnesses were investigated by varying the loading rates during fracture tests at both 77 and 298 K. Quantitative fractography was utilized to completely characterize each fracture surface created at 298 K in order to determine the type of fracture mode (i.e., dimpled, cleavage) exhibited by the Nb p . Specimens tested at either higher loading rates or lower test temperatures consistently exhibited a greater amount of cleavage fracture in the Nb p , while the Nb s always remained ductile. However, the fracture toughness values determined from experiments spanning six orders of magnitude in loading rate at 298 and 77 K exhibited little variation, even under conditions when the majority of Nb p phases failed by cleavage at 77 K. The changes in fracture mode with increasing loading rate and/or decreasing test temperature and their effects on fracture toughness are rationalized by comparison to existing theoretical models

  5. Involvement of hydrogen-vacancy complexes in the baking effect of niobium cavities

    Directory of Open Access Journals (Sweden)

    B. Visentin

    2010-05-01

    Full Text Available Baking is necessary to improve high accelerating gradient performances of superconducting niobium cavities. Ten years after this discovery in 1998, the understanding of this effect still resists a lot of theoretical explanations. For the first time, positron annihilation spectroscopy performed on niobium samples reveals the increase after baking of positrons trapped under the Nb surface. Presence of hydrogen-vacancy complexes and their dissociation by baking could both explain rf losses observed at high fields (Q drop and its cure (baking effect.

  6. Searches for fractional electric charge on niobium samples exposed to liquid helium

    International Nuclear Information System (INIS)

    Smith, P.F.; Homer, G.J.; Lewin, J.D.; Walford, H.E.; Jones, W.G.

    1986-01-01

    Levitation measurements at room temperature described in a previous paper did not confirm the apparent fractional electric charges reported by the Stanford Group for niobium samples at liquid helium temperature. To simulate possible effects of a low-temperature environment, both niobium and steel samples have been exposed to liquid helium for periods of typically 48 h, both with and without the assistance of electric fields to extract possible fractionally charged ions. Subsequent levitation tests show no indication of fractional charge. With some additional assumptions regarding ionic mobility and surface energy, an upper limit ∝10 -2 fractional charges/g is inferred for the liquid helium itself. (orig.)

  7. Understanding Quality Factor Degradation in Superconducting Niobium Cavities at Low Microwave Field Amplitudes

    Science.gov (United States)

    Romanenko, A.; Schuster, D. I.

    2017-12-01

    In niobium superconducting radio frequency (SRF) cavities for particle acceleration, a decrease of the quality factor at lower fields—a so-called low field Q slope or LFQS—has been a long-standing unexplained effect. By extending the high Q measurement techniques to ultralow fields, we discover two previously unknown features of the effect: (i) saturation at rf fields lower than Eacc˜0.1 MV /m ; (ii) strong degradation enhancement by growing thicker niobium pentoxide. Our findings suggest that the LFQS may be caused by the two level systems in the natural niobium oxide on the inner cavity surface, thereby identifying a new source of residual resistance and providing guidance for potential nonaccelerator low-field applications of SRF cavities.

  8. Kinetics and mechanisms of interactions of nitrogen and carbon monoxide with liquid niobium

    International Nuclear Information System (INIS)

    Park, H.G.

    1990-01-01

    The kinetics and mechanisms of interactions of N 2 and CO with liquid niobium were investigated in the temperature range of 2,700 to 3,000 K in samples levitated in N 2 /Ar and CO/Ar streams. The nitrogen absorption and desorption processes were found to be second-order with respect to nitrogen concentration, indicating that the rate controlling step is either the adsorption of nitrogen molecules on the liquid surface or dissociation of absorbed nitrogen molecules into adsorbed atoms. The carbon and oxygen dissolution in liquid niobium from CO gas is an exothermic process and the solubilities of carbon and oxygen (C Ce , C Oe in at%) are related to the temperature and the partial pressure of CO. The reaction CO → [C] + [O] along with the evaporation of niobium oxide takes place during C and O dissolution, whereas C and O desorption occurs via CO evolution only

  9. Kinetics and oxidation mechanisms of polycrystaline niobium

    International Nuclear Information System (INIS)

    Paschoal, J.O.A.

    1979-01-01

    The oxidation kinetics of annealed niobium was determined by thermogravimetric analysis between 450 and 800 0 C and for oxygen pressures varying from 20 to 700 mmHg. The oxidation kinetics of cold worked and/or irradiated niobium for temperatures between 500 and 700 0 C, with oxygen pressures varying from 100 to 300 mmHg. Was also determined. Using X-ray diffraction it was found that the oxide formed in the range of temperature and oxygen pressure considered in this research is γ-Nb 2 O 5 . Optical and scanning eletronic microscopy showed that for annealed niobium oxidized under 600 0 C there was formation of non-uniform oxide layers, containing cracks and pores, presenting very irregular metal/pentoxide interface. The presence of sub-oxide NbOsub(z) platelets was observed in this interface. This sub-oxide platelets where not observed in annealed oxidized niobium samples over 600 0 C; the oxide layers formed were compact. At 800 0 C and the beginning at 700 0 C the interfaces were quite regular. Through microhardness measurements for the metal near the metal/pentoxide interface, the formation of oxygen solid solution was found and the oxygen diffusion coefficient was calculated. The results showed that at 600 0 C the oxygen diffusion coefficient in cold worked niobium is three times larger than the value obtained for annealed niobium. The results suggest that the reaction between annealed niobium and oxygen undaer 600 0 C is controlled by reaction in interface where the oxide layers are not compacted, parcially due to Nb sub(z) platelets formation.(Author) [pt

  10. Sorption of niobium on boreal forest soil

    Energy Technology Data Exchange (ETDEWEB)

    Soederlund, Mervi; Hakanen, Martti; Lehto, Jukka [Helsinki Univ. (Finland). Lab. of Radiochemistry

    2015-07-01

    The sorption of niobium (Nb) was investigated on humus and mineral soil samples taken from various depths of a four-metre deep forest soil pit on Olkiluoto Island, southwestern Finland. Mass distribution coefficients, K{sub d}, were determined in batch sorption tests. The steady state of Nb sorption was observed in the mineral soil samples already after one week of equilibration, and sorption decreased with depth from a very high value of 185000 mL/g at 0.7 m to 54000 mL/g at 3.4 m. The reason behind this decrease is probably the tenfold reduction in the specific surface area of the soil at the same depth range. Distribution coefficients were clearly lower in the humus layer (1000 mL/g). The K{sub d} values determined in pure water at a pH range of 4.7-6.5 were at a high level (above 55000 mL/g), but decreased dramatically above pH 6.5, corresponding to the change in the major Nb species from the neutral Nb(OH){sub 5} to the low-sorbing anionic Nb(OH){sub 6}{sup -} and Nb(OH){sub 7}{sup 2-}. However, the K{sub d} values in the model soil solution were in the slightly alkaline range an order of magnitude higher than in pure water, which is probably caused by the formation of calcium niobate surface precipitate or electrostatic interaction between surface-sorbed calcium and solute Nb. Among nine soil constituent minerals kaolinite performed best in retaining Nb in both pure water and model soil solution at pH 8, whereas potassium feldspar showed the poorest sorption. The K{sub d} value for kaolinite was above 500000 mL/g in both solutions, while the respective potassium feldspar values were in the range of 120-220 mL/g.

  11. Catalysts Promoted with Niobium Oxide for Air Pollution Abatement

    Directory of Open Access Journals (Sweden)

    Wendi Xiang

    2017-05-01

    Full Text Available Pt-containing catalysts are currently used commercially to catalyze the conversion of carbon monoxide (CO and hydrocarbon (HC pollutants from stationary chemical and petroleum plants. It is well known that Pt-containing catalysts are expensive and have limited availability. The goal of this research is to find alternative and less expensive catalysts to replace Pt for these applications. This study found that niobium oxide (Nb2O5, as a carrier or support for certain transition metal oxides, promotes oxidation activity while maintaining stability, making them candidates as alternatives to Pt. The present work reports that the orthorhombic structure of niobium oxide (formed at 800 °C in air promotes Co3O4 toward the oxidation of both CO and propane, which are common pollutants in volatile organic compound (VOC applications. This was a surprising result since this structure of Nb2O5 has a very low surface area (about 2 m2/g relative to the more traditional Al2O3 support, with a surface area of 150 m2/g. The results reported demonstrate that 1% Co3O4/Nb2O5 has comparable fresh and aged catalytic activity to 1% Pt/γ-Al2O3 and 1% Pt/Nb2O5. Furthermore, 6% Co3O4/Nb2O5 outperforms 1% Pt/Al2O3 in both catalytic activity and thermal stability. These results suggest a strong interaction between niobium oxide and the active component—cobalt oxide—likely by inducing an oxygen defect structure with oxygen vacancies leading to enhanced activity toward the oxidation of CO and propane.

  12. Experimental Study of Plasma-Surface Interaction and Material Damage Relevant to ITER Type I Elms

    International Nuclear Information System (INIS)

    Makhlai, V.A.; Bandura, A.N.; Byrka, O.V. and others; Landman, I.; Neklyudov, I.M.

    2006-01-01

    The paper presents experimental investigations of main features of plasma surface interaction and energy transfer to the material surface in dependence on plasma heat loads. The experiments were performed with QSPA repetitive plasma pulses of the duration of 0.25 ms and the energy density up to 2.5 MJ/m 2 . Surface morphology of the targets exposed to QSPA plasma screams is analyzed. Relative contribution of the Lorentz force and plasma pressure gradient to the resulting surface profile is discussed. development of cracking on the tungsten surface and swelling of the surface are found to be in strong dependence on initial temperature of the target

  13. Superconductors made of niobium germanide

    International Nuclear Information System (INIS)

    Newkirk, L.R.; Valencia, F.A.

    1976-01-01

    This invention concerns the superconductors and particularly the mass coatings of niobium germanide (Nb 3 Ge) exhibiting superconductor properties, as well as the compositions enabling them to be obtained, having transition temperatures of around 20 0 K or more. The invention proposes a composition of a material of the general formula Nb 3 Ge, containing from around 1 to around 10 at. % oxygen. Preferably, the material contains around 5 at. % of oxygen. The invention also proposes fabricated articles in which the compositions described above are associated with and joined to a metallic substrate. Hence, for instance, the present studies involving a superconducting power transmission line for direct current make it possible to envisage the use of conductors placed in a double envelope, enabling the superconducting element transmitting the current to be carried, whilst containing the cryogenic coolant. In this type of design, the coat of superconducting material surrounds a tube containing liquid helium or possibly liquid hydrogen if a sufficiently high superconduction transition temperature can be reached. The tube must be a good heat and electricity conductor in order to achieve good stability of the superconducting coating [fr

  14. Sputtering of vanadium and niobium under 14.1 MeV neutron impact

    International Nuclear Information System (INIS)

    Kaminsky, M.; Das, S.K.

    1976-01-01

    The recent studies of particle emission from cold-rolled and annealed niobium under 14.1-MeV neutron impact were extended to a heavily etched, polycrystalline niobium surface and to cold worked vanadium surfaces with different degrees of microstructure. The type and amount of material released and deposited on collector surfaces facing the irradiated targets were determined by three analytical techniques. Two types of deposits were found for certain types of surfaces--one in the form of chunks; the other as a fractional atom layer covering the surface. The chunks vary significantly in size. The small number of chunks observed suggests that the ejection of chunks is a relatively rare event in comparison to the total number of primary knock-on events produced by 14-MeV neutrons in near surface regions. Estimates of the total sputtering yield based on the chunk deposits and on the fractional atom layer deposit will be given

  15. Study of niobium corrosion in alkaline medium

    International Nuclear Information System (INIS)

    Almeida, S.H. de.

    1987-01-01

    A comparative study of niobium electrochemical behaviour in NaOH and KOH solution, with concentrations between 0,5 and 6,1M is presented. The studies were done through electrochemicals assays, consisting in the corrosion potential and anodic and cathodic polarization curves, complemented by loss of mass experiments. The niobium anodic behaviour in alkaline medium is characterized by passivation occurrence, with a stable film formation. The Na oH solution in alkaline medium are more corrosible to niobium than the KOH solution. The loss of mass assays showed that the corrosion velocit is more dependente of hydroxide concentration in KOH medium than the NaOH medium. (C.G.C.) [pt

  16. Josephson tunnel junctions in niobium films

    International Nuclear Information System (INIS)

    Wiik, Tapio.

    1976-12-01

    A method of fabricating stable Josephson tunnel junctions with reproducible characteristics is described. The junctions have a sandwich structure consisting of a vacuum evaporated niobium film, a niobium oxide layer produced by the glow discharge method and a lead film deposited by vacuum evaporation. Difficulties in producing thin-film Josephson junctions are discussed. Experimental results suggest that the lower critical field of the niobium film is the most essential parameter when evaluating the quality of these junctions. The dependence of the lower critical field on the film thickness and on the Ginzburg-Landau parameter of the film is studied analytically. Comparison with the properties of the evaporated films and with the previous calculations for bulk specimens shows that the presented model is applicable for most of the prepared samples. (author)

  17. Radioactivity analysis in niobium activation foils

    Energy Technology Data Exchange (ETDEWEB)

    Mueller, G.E.

    1995-06-01

    The motivation for this study was to measure and analyze the activity of six (6) niobium (Nb) foils (the x-rays from an internal transition in Nb-93m) and apply this information with previously obtained activation foil data. The niobium data was used to determine the epithermal to MeV range for the neutron spectrum and fluence. The foil activation data was re-evaluated in a spectrum analysis code (STAY`SL) to provide new estimates of the exposure at the Los Alamos Spallation Radiation Effect Facility (LASREF). The activity of the niobium foils was measured and analyzed at the University of Missouri-Columbia (UMC) under the direction of Professor William Miller. The spectrum analysis was performed at the University of Missouri-Rolla (UMR) by Professor Gary Mueller.

  18. Molding of L band niobium superconductor cavity

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, Hitoshi; Funahashi, Yoshisato; Saito, Kenji; Noguchi, Shuichi; Koizumi, Susumu [National Lab. for High Energy Physics, Tsukuba, Ibaraki (Japan)

    1995-07-01

    A cavity to produce high accelerating electron field was developed. The L-band (1.3 GHz) niobium superconductor unit cell cavity was ellipsoid with {phi}217.3 mm outer diameter and 2.5 mm thickness and consisted of two pieces of half cell, two beam pipes and flange. A deep drawing process was adapted. In spite of the first trial manufacture, each good cavity was obtained. Characteristic properties of niobium materials, molding method of cavity, extension of sheet after molding, production of beam pipe, accuracy and the cost were explained. Niobium materials. showed tensile strength 15.6 kg/mm{sup 2}, load-carrying capacity 4.1 kg/mm{sup 2}, density 8.57, extension 42.5% and RRR (resistance residual ratio){>=}200. (S.Y.)

  19. Laser-pulsed Plasma Chemistry: Laser-initiated Plasma Oxidation Of Niobium

    OpenAIRE

    Marks R.F.; Pollak R.A.; Avouris Ph.; Lin C.T.; Thefaine Y.J.

    1983-01-01

    We report the first observation of the chemical modification of a solid surface exposed to an ambient gas plasma initiated by the interaction of laser radiation with the same surface. A new technique, which we designate laser-pulsed plasma chemistry (LPPC), is proposed for activating heterogeneous chemical reactions at solid surfaces in a gaseous ambient by means of a plasma initiated by laser radiation. Results for niobium metal in one atmosphere oxygen demonstrate single-pulse, self-limitin...

  20. Liquid-film assisted formation of alumina/niobium interfaces

    OpenAIRE

    Sugar, Joshua D.; McKeown, Joseph T.; Marks, Robert A.; Glaeser, Andreas M.

    2002-01-01

    Alumina has been joined at 1400 degrees C using niobium-based interlayers. Two different joining approaches were compared: solid-state diffusion bonding using a niobium foil as an interlayer, and liquid-film assisted bonding using a multilayer copper/niobium/copper interlayer. In both cases, a 127-(mu)m thick niobium foil was used; =1.4-(mu)m or =3-(mu)m thick copper films flanked the niobium. Room-temperature four-point bend tests showed that the introduction of a copper film had a significa...

  1. How to Select the most Relevant Roughness Parameters of a Surface: Methodology Research Strategy

    Science.gov (United States)

    Bobrovskij, I. N.

    2018-01-01

    In this paper, the foundations for new methodology creation which provides solving problem of surfaces structure new standards parameters huge amount conflicted with necessary actual floors quantity of surfaces structure parameters which is related to measurement complexity decreasing are considered. At the moment, there is no single assessment of the importance of a parameters. The approval of presented methodology for aerospace cluster components surfaces allows to create necessary foundation, to develop scientific estimation of surfaces texture parameters, to obtain material for investigators of chosen technological procedure. The methods necessary for further work, the creation of a fundamental reserve and development as a scientific direction for assessing the significance of microgeometry parameters are selected.

  2. Design for a superconducting niobium RFQ structure

    Energy Technology Data Exchange (ETDEWEB)

    Shepard, K W; Kennedy, W L; Sagalovsky, L [Argonne National Lab., IL (United States)

    1992-11-01

    This paper reports a design for a niobium superconducting RFQ operating at 192 Mhz. The structure is of the rod and post type, novel in that each of four rods is supported by two posts oriented radially with respect to the beam axis. Although the geometry has four-fold rotation symmetry, the dipole-quadrupole mode splitting is large, giving good mechanical tolerances. The simplicity of the geometry enables designing for good mechanical stability while minimizing tooling costs for fabrication with niobium. Results of MAFIA numerical modeling, measurements on a copper model, and plans for a beam test are discussed. (Author) fig., 7 refs.

  3. Design for a superconducting niobium RFQ structure

    International Nuclear Information System (INIS)

    Shepard, K.W.; Kennedy, W.L.; Sagalovsky, L.

    1992-01-01

    This paper reports a design for a niobium superconducting RFQ operating at 192 Mhz. The structure is of the rod and post type, novel in that each of four rods is supported by two posts oriented radially with respect to the beam axis. Although the geometry has four-fold rotation symmetry, the dipole-quadrupole mode splitting is large, giving good mechanical tolerances. The simplicity of the geometry enables designing for good mechanical stability while minimizing tooling cost for fabrication with niobium. Results of MAFIA numerical modeling, measurements on a copper model, and plans for a beam test are discussed

  4. Design for a superconducting niobium RFQ structure

    International Nuclear Information System (INIS)

    Shepard, K.W.; Kennedy, W.L.; Sagalovsky, L.

    1992-01-01

    This paper reports a design for a niobium superconducting RFQ operating at 192 Mhz. The structure is of the rod and post type, novel in that each of four rods is supported by two posts oriented radially with respect to the beam axis. Although the geometry has four-fold rotation symmetry, the dipole-quadrupole mode splitting is large, giving good mechanical tolerances. The simplicity of the geometry enables designing for good mechanical stability while minimizing tooling costs for fabrication with niobium. Results of MAFIA numerical modeling, measurements on a copper model, and plans for a beam test are discussed. (Author) fig., 7 refs

  5. Niobium-base grain refiner for aluminium

    International Nuclear Information System (INIS)

    Silva Pontes, P. da; Robert, M.H.; Cupini, N.L.

    1980-01-01

    A new chemical grain refiner for aluminium has been developed, using inoculation of a niobium-base compound. When a bath of molten aluminium is inoculated whith this refiner, an intermetallic aluminium-niobium compound is formed which acts as a powerful nucleant, producing extremely fine structure comparable to those obtained by means of the traditional grain refiner based on titanium and boron. It was found that the refinement of the structure depends upon the weight percentage of the new refiner inoculated as well as the time of holding the bath after inoculation and before pouring, but mainly on the inoculating temperature. (Author) [pt

  6. Investigation of superconducting niobium 1170 MHz cavities

    International Nuclear Information System (INIS)

    Anashin, V.V.; Bibko, S.I.; Fadeyev, E.I.

    1988-01-01

    The design, fabrication and experiments with superconducting L-band single cell cavities are described. These cavities model a cell of an accelerating RF structure. The cavities have been fabricated from technical grade and higher purity grade sheet niobium using deep-drawing, electron beam welding and chemical polishing. They have spherical geometry and are excited in the TM 010 mode. A computerized set-up was used for cavity tests. Qo=1.5 x 10 9 and E acc = 4.3 MV/m were obtained in the cavity made of higher purity grade niobium. 6 references, 8 figures, 3 tables

  7. Tool steel for cold worck niobium carbides

    International Nuclear Information System (INIS)

    Goldenstein, H.

    1984-01-01

    A tool steel was designed so as to have a microstructure with the matrix similar a cold work tool steel of D series, containing a dispersion of Niobium carbides, with no intention of putting Niobium in solution on the matrix. The alloy was cast, forged and heat treated. The alloy was easily forged; the primary carbide morfology, after forging, was faceted, tending to equiaxed. The hardness obtained was equivalent to the maximum hardness of a D-3 sttel when quenched from any temperature between 950 0 C, and 1200 0 , showing a very small sensitivy to the quenching temperature. (Author) [pt

  8. Design for a superconducting niobium RFQ structure

    Energy Technology Data Exchange (ETDEWEB)

    Shepard, K.W.; Kennedy, W.L.; Sagalovsky, L.

    1992-01-01

    This paper reports a design for a niobium superconducting RFQ operating at 192 Mhz. The structure is of the rod and post type, novel in that each of four rods is supported by two posts oriented radially with respect to the beam axis. Although the geometry has four-fold rotation symmetry, the dipole-quadrupole mode splitting is large, giving good mechanical tolerances. The simplicity of the geometry enables designing for good mechanical stability while minimizing tooling cost for fabrication with niobium. Results of MAFIA numerical modeling, measurements on a copper model, and plans for a beam test are discussed.

  9. Design for a superconducting niobium RFQ structure

    Energy Technology Data Exchange (ETDEWEB)

    Shepard, K.W.; Kennedy, W.L.; Sagalovsky, L.

    1992-09-01

    This paper reports a design for a niobium superconducting RFQ operating at 192 Mhz. The structure is of the rod and post type, novel in that each of four rods is supported by two posts oriented radially with respect to the beam axis. Although the geometry has four-fold rotation symmetry, the dipole-quadrupole mode splitting is large, giving good mechanical tolerances. The simplicity of the geometry enables designing for good mechanical stability while minimizing tooling cost for fabrication with niobium. Results of MAFIA numerical modeling, measurements on a copper model, and plans for a beam test are discussed.

  10. Muon spin rotation studies of niobium for superconducting rf applications

    Directory of Open Access Journals (Sweden)

    A. Grassellino

    2013-06-01

    Full Text Available In this work we investigate superconducting properties of niobium samples via application of the muon spin rotation/relaxation (μSR technique. We employ for the first time the μSR technique to study samples that are cut out from large and small grain 1.5 GHz radio frequency (rf single cell niobium cavities. The rf test of these cavities was accompanied by full temperature mapping to characterize the rf losses in each of the samples. Results of the μSR measurements show that standard cavity surface treatments like mild baking and buffered chemical polishing performed on the studied samples affect their surface pinning strength. We find an interesting correlation between high field rf losses and field dependence of the sample magnetic volume fraction measured via μSR. The μSR line width observed in zero-field-μSR measurements matches the behavior of Nb samples doped with minute amounts of Ta or N impurities. A lower and an upper bound for the upper critical field H_{c2} of these cutouts is found.

  11. Industrially relevant Al2O3 deposition techniques for the surface passivation of Si solar cells

    NARCIS (Netherlands)

    Schmidt, J.; Werner, F.; Veith, B.; Zielke, D.; Bock, R.; Tiba, M.V.; Poodt, P.; Roozeboom, F.; Li, A.; Cuevas, A.; Brendel, R.

    2010-01-01

    We present independently confirmed efficiencies of 21.4% for PERC cells with plasma-assisted atom-ic-layer-deposited (plasma ALD) Al2O3 rear passivation and 20.7% for cells with thermal ALD-Al2O3. Additionally, we evaluate three different industrially relevant techniques for the deposition of

  12. Thermal transport properties of niobium and some niobium-based alloys from 80 to 1600 K

    Energy Technology Data Exchange (ETDEWEB)

    Moore, J P; Graves, R S; Williams, R K [Oak Ridge National Lab., TN (USA)

    1980-01-01

    The electric resistivity, rho, and Seebeck coefficient, S, of 99.8 at% niobium, and Nb-4.8 at% W, Nb-5 at% Mo, Nb-10 at% Mo, and Nb-2.4 at% Mo-2.4 at% Zr alloys were measured from 80 to 1600 K, and the thermal conductivity, lambda, of the niobium and the Nb-5 at% W alloy was measured from 80 to 1300 K. A technique is described for measuring rho and S of a specimen during radial-heat-flow measurements of lambda. The transport property results, which had uncertainties of +-0.4% for rho and +-1.4% for lambda, showed the influence of tungsten and molybdenum solutes on the transport properties of niobium and were used to obtain the electronic Lorenz function of pure niobium, which was found to approach the Sommerfeld value at high temperatures.

  13. Thermal transport properties of niobium and some niobium base alloys from 80 to 16000K

    International Nuclear Information System (INIS)

    Moore, J.P.; Graves, R.S.; Williams, R.K.

    1980-01-01

    The electrical resistivities and absolute Seebeck coefficients of 99.8 at. % niobium with a RRR of 36, Nb-4.8 at. % W, Nb-5 at. % Mo, Nb-10 at. % Mo, and Nb-2.4 at. % Mo-2.4 at. % Zr were measured from 80 to 1600 0 K, and the thermal conductivities of the niobium and Nb-5 at. % W were measured from 80 to 1300 0 K. A technique is described for measuring the electrical resistivity and Seebeck coefficient of a specimen during radial heat flow measurements of the thermal conductivity. The transport property results, which had uncertainties of +-0.4%for electrical resistivity and +-1.4% for thermal conductivity, showed the influence of tungsten and molybdenum solutes on the transport properties of niobium and were used to obtain the electronic Lorenz function of pure niobium, which was found to approach the Sommerfeld value at high temperatures

  14. Developmental Testing of Liquid and Gaseous/Vaporous Decontamination on Bacterial Spores and Other Biological Warfare Agents on Military Relevant Surfaces

    Science.gov (United States)

    2016-02-11

    Vaporous Decontamination on Bacterial Spores and Other Biological Warfare Agents on Military-Relevant Surfaces 5a. CONTRACT NUMBER 5b. GRANT... DECONTAMINATION ON BACTERIAL SPORES AND OTHER BIOLOGICAL WARFARE AGENTS ON MILITARY-RELEVANT SURFACES Page Paragraph 1. SCOPE...surfaces before and after decontamination . The protocol in this TOP is based on the developed test methodologies from Edgewood Chemical Biological

  15. XPS studies of nitrogen doping niobium used for accelerator applications

    Science.gov (United States)

    Yang, Ziqin; Lu, Xiangyang; Tan, Weiwei; Zhao, Jifei; Yang, Deyu; Yang, Yujia; He, Yuan; Zhou, Kui

    2018-05-01

    Nitrogen doping study on niobium (Nb) samples used for the fabrication of superconducting radio frequency (SRF) cavities was carried out. The samples' surface treatment was attempted to replicate that of the Nb SRF cavities, which includes heavy electropolishing (EP), nitrogen doping and the subsequent EP with different amounts of material removal. The surface chemical composition of Nb samples with different post treatments has been studied by XPS. The chemical composition of Nb, O, C and N was presented before and after Gas Cluster Ion Beam (GCIB) etching. No signals of poorly superconducting nitrides NbNx was found on the surface of any doped Nb sample with the 2/6 recipe before GCIB etching. However, in the depth range greater than 30 nm, the content of N element is below the XPS detection precision scope even for the Nb sample directly after nitrogen doping treatment with the 2/6 recipe.

  16. Synthesis and characterization of niobium and iron phosphate glasses for U3O8 immobilization

    International Nuclear Information System (INIS)

    Ghussn, Luciana

    2005-01-01

    Niobium and iron phosphate glasses were produced by melting inorganic compound mixtures in electric furnaces and microwave ovens. The chemical durability was compared among niobium phosphate glasses produced by both processes, and equivalent results were obtained. Leaching tests were also performed to compare the chemical durability among monolithic glass blocks and sintered glasses. The glass transition, crystallization and melting temperatures as well the Hruby parameter (K H ) and the activation energy for crystallization were determined from differential thermal analysis of niobium phosphate glasses produced in electric furnaces. Niobium phosphate glasses are thermally more stable (K H =0.82 +- 0.04) than iron phosphate glasses (K H = 0.42 +- 0.03). Sintered glasses were produced from particles with different particle size distributions and sintering temperatures in the range of 720 - 800 deg C for niobium phosphate and 530 - 680 deg C for iron phosphate glasses. The sintering process was suitable because a glass with composition 37P 2 O 5 -23K 2 O-40Nb 2 O 5 showing leaching rate of 10 -6 g.cm -2 .d -1 , 99 % of the monolithic density and none crystalline phases was obtained. This glass only crystallizes itself after re heating at temperatures above 800 deg C , showing two crystalline phases identified as KNb 3 O 8 e K 3 NbP 2 O 9 . The activation energies for crystallization are 496 +- 7 kJ/mol and 513 +- 14 kJ/mol. Niobium phosphate sintered glasses are better densified than sintered iron phosphate glasses. The leaching rate of sintered glasses that show open porosity is higher than monolithic glass blocks. This effect is related to an increase of the surface area associated to open porous and, a correction of the value of the surface area used to calculate the leaching rate is required. A model was proposed based on the surface area of spherical porous to take in account that effect. Even after correcting the surface area, the leaching rates of sintered

  17. Modelling of niobium sorption on clay minerals in sodium and calcium perchlorate solutions

    Energy Technology Data Exchange (ETDEWEB)

    Ervanne, Heini; Hakanen, Martti; Lehto, Jukka [Helsinki Univ. (Finland). Laboratory of Radiochemistry

    2014-11-01

    The sorption behaviour of niobium on kaolinite and illite minerals in sodium and calcium perchlorate solutions was evaluated with use of the mass distribution coefficient, Rd, obtained in batch sorption experiments. Very high distribution coefficient values, about 100 m{sup 3}/kg, were obtained for both minerals in the neutral pH range between 6 and 8. Values were somewhat lower at pH 5. In NaClO{sub 4} solution, the sorption of niobium starts to decrease at pH higher than 8. This is in agreement with the increase, with pH, in the proportion of anionic niobate species, which are presumed to be low or non-sorbing. A similar decrease was not observed in Ca(ClO{sub 4}){sub 2} solution, probably owing to the influence of Ca on niobium solution speciation and surface species. The surface complexation model was applied to model the Rd values. The model fitted well for the NaClO{sub 4} solution but only at pH below 9 for the Ca(ClO{sub 4}){sub 2} solution. The discrepancy between the strong sorption of niobium in calcium-bearing solution at high pH and the calculated speciation is due in part to the non-inclusion of calcium niobate solution species and Ca-Nb compounds in the present NEA and other similar thermodynamic databases.

  18. Deposition of niobium plate on niobium-titanium from molten salts

    International Nuclear Information System (INIS)

    Matychenko, Eh.S.; Shevyrev, A.A.; Stolyarova, L.A.; Sukhorzhevskaya, S.L.

    1993-01-01

    A possibility of using Nb-Ti alloys (50 and 34 mas.% of Ti) as substrates for deposition of niobium coating of chloride-fluoride and fluoride molten salts is studied. Corrosion behaviour of alloys indicates in the electrolytic bath within 970-1070 K interval, coating structure and state of coating-substrate boundary are investigated. Chloride-fluoride molten salt usefullness for making products with niobium coatings is shown

  19. Surface Sampling-Based Decontamination Studies and Protocol for Determining Sporicidal Efficacy of Gaseous Fumigants on Military-Relevant Surfaces

    Science.gov (United States)

    2008-09-01

    non-porous surfaces is vital to decon protocol development. Spore density (spore number per unit area) can result in layering and clustering over a...1999, 281, 1735-1745. 9. AOAC International Method 966.04; Official Methods of Analisis , 21’t ed.; Chapter 6: AOAC International: Gaithersburg, MD

  20. Dislocation morphology in deformed and irradiated niobium

    International Nuclear Information System (INIS)

    Chang, C.P.

    1977-06-01

    Niobium foils of moderate purity were examined for the morphology of dislocations or defect clusters in the deformed or neutron-irradiated state by transmission electron microscopy. New evidence has been found for the dissociation of screw dislocations into partials on the (211) slip plane according to the Crussard mechanism: (a/2) [111] → (a/3) [111] + (a/6) [111

  1. Growth of anodic films on niobium

    International Nuclear Information System (INIS)

    Gomes, M.A.B.; Bulhoes, L.O.S.

    1988-01-01

    The analysis of the response of the galvanostatic growth of anodic films on niobium metal in aqueous solutions is shown. The first spark voltage showed a dependence upon value of current density that could be explained as the incorporation of anions into the film. (M.J.C.) [pt

  2. Review of tantalum and niobium alloy production

    International Nuclear Information System (INIS)

    Buckman, R.W. Jr.

    1984-01-01

    This paper concentrates on the current state of niobium- and tantalum-base alloy production. The materials requirements, alloy compositions of interest, and production status are discussed. Finally, a list of developments needed to support the SP-100 program will be identified. A bibliography is included

  3. Intercalated compounds of niobium and tantalum dicalcogenides

    International Nuclear Information System (INIS)

    Wypych, F.

    1988-01-01

    The synthesis of niobium and tantalum lamellar compounds and its intercalated derivatives is described. The intercalated compounds with lithium, with alkaline metal and with metals of the first-row transition are studied, characterized by X-ray diffraction. (C.G.C.) [pt

  4. Laser polishing of niobium for application to superconducting radio frequency cavities

    International Nuclear Information System (INIS)

    Singaravelu, Senthil; Klopf, John Michael; Xu, Chen; Krafft, Geoffrey; Kelley, Michael J.

    2012-01-01

    Superconducting radio frequency niobium cavities are at the heart of an increasing number of particle accelerators. Their performance is dominated by a several nanometer thick layer at the interior surface. Maximizing the smoothness of this surface is critical, and aggressive chemical treatments are now employed to this end. The authors describe laser-induced surface melting as an alternative 'greener' approach. Selection of laser parameters guided by modeling achieved melting that reduced the surface roughness from the fabrication process. The resulting topography was examined by scanning electron microscope and atomic force microscope (AFM). Plots of power spectral density computed from the AFM data give further insight into the effect of laser melting on the topography of the mechanically polished (only) niobium

  5. Nanoscale surface modifications of medically relevant metals: state-of-the art and perspectives

    Science.gov (United States)

    Variola, Fabio; Brunski, John B.; Orsini, Giovanna; Tambasco de Oliveira, Paulo; Wazen, Rima; Nanci, Antonio

    2011-02-01

    Evidence that nanoscale surface properties stimulate and guide various molecular and biological processes at the implant/tissue interface is fostering a new trend in designing implantable metals. Cutting-edge expertise and techniques drawn from widely separated fields, such as nanotechnology, materials engineering and biology, have been advantageously exploited to nanoengineer surfaces in ways that control and direct these processes in predictable manners. In this review, we present and discuss the state-of-the-art of nanotechnology-based approaches currently adopted to modify the surface of metals used for orthopedic and dental applications, and also briefly consider their use in the cardiovascular field. The effects of nanoengineered surfaces on various in vitro molecular and cellular events are firstly discussed. This review also provides an overview of in vivo and clinical studies with nanostructured metallic implants, and addresses the potential influence of nanotopography on biomechanical events at interfaces. Ultimately, the objective of this work is to give the readership a comprehensive picture of the current advances, future developments and challenges in the application of the infinitesimally small to biomedical surface science. We believe that an integrated understanding of the in vitro and particularly of the in vivo behavior is mandatory for the proper exploitation of nanostructured implantable metals and, indeed, of all biomaterials.

  6. Iron oxide and hydroxide precipitation from ferrous solutions and its relevance to Martian surface mineralogy

    Science.gov (United States)

    Posey-Dowty, J.; Moskowitz, B.; Crerar, D.; Hargraves, R.; Tanenbaum, L.

    1986-01-01

    Experiments were performed to examine if the ubiquitousness of a weak magnetic component in all Martian surface fines tested with the Viking Landers can be attributed to ferric iron precipitation in aqueous solution under oxidizing conditions at neutral pH. Ferrous solutions were mixed in deionized water and various minerals were added to separate liquid samples. The iron-bearing additives included hematite, goethite, magnetite, maghemite, lepidocrocite and potassium bromide blank at varying concentrations. IR spectroscopic scans were made to identify any precipitates resulting from bubbling oxygen throughout the solutions; the magnetic properties of the precipitates were also examined. The data indicated that the lepidocrocite may have been preferentially precipitated, then aged to maghemite. The process would account for the presumed thin residue of maghemite on the present Martian surface, long after abundant liquid water on the Martian surface vanished.

  7. Iron oxide and hydroxide precipitation from ferrous solutions and its relevance to Martian surface mineralogy

    International Nuclear Information System (INIS)

    Posey-Dowty, J.; Moskowitz, B.; Crerar, D.; Hargraves, R.; Tanenbaum, L.

    1986-01-01

    Experiments were performed to examine if the ubiquitousness of a weak magnetic component in all Martian surface fines tested with the Viking Landers can be attributed to ferric iron precipitation in aqueous solution under oxidizing conditions at neutral pH. Ferrous solutions were mixed in deionized water and various minerals were added to separate liquid samples. The iron-bearing additives included hematite, goethite, magnetite, maghemite, lepidocrocite and potassium bromide blank at varying concentrations. IR spectroscopic scans were made to identify any precipitates resulting from bubbling oxygen throughout the solutions; the magnetic properties of the precipitates were also examined. The data indicated that the lepidocrocite may have been preferentially precipitated, then aged to maghemite. The process would account for the presumed thin residue of maghemite on the present Martian surface, long after abundant liquid water on the Martian surface vanished. 40 references

  8. Unprecedented quality factors at accelerating gradients up to 45 MVm-1 in niobium superconducting resonators via low temperature nitrogen infusion

    Science.gov (United States)

    Grassellino, A.; Romanenko, A.; Trenikhina, Y.; Checchin, M.; Martinello, M.; Melnychuk, O. S.; Chandrasekaran, S.; Sergatskov, D. A.; Posen, S.; Crawford, A. C.; Aderhold, S.; Bice, D.

    2017-09-01

    We report the finding of new surface treatments that permits one to manipulate the niobium resonator nitrogen content in the first few nanometers in a controlled way, and the resonator fundamental Mattis-Bardeen surface resistance and residual resistance accordingly. In particular, we find surface ‘infusion’ conditions that systematically (a) increase the quality factor of these 1.3 GHz superconducting radio frequency (SRF) bulk niobium resonators, up to very high gradients; (b) increase the achievable accelerating gradient of the cavity compared to its own baseline with state-of-the-art surface processing. Cavities subject to the new surface process have more than two times the state-of-the-art Q at 2 K for accelerating fields >35 MVm-1. Moreover, very high accelerating gradients ˜45 MVm-1 are repeatedly reached, which correspond to peak magnetic surface fields of 190 mT, among the highest measured for bulk niobium cavities. These findings open the opportunity to tailor the surface impurity content distribution to maximize performance in Q and gradients, and have therefore very important implications on future performance and cost of SRF based accelerators. They also help deepen the understanding of the physics of the RF niobium cavity surface.

  9. Optical investigation of niobium properties: Electrical- and physical constants

    Science.gov (United States)

    Singh, Nageshwar; Deo, M. N.; Roy, S. B.

    2017-08-01

    In this paper, we report optical (reflectance) measurements and investigations of optical properties of electropolished (EP), buffered chemical polished (BCP), and as-received (AR) from vendor niobium (Nb) samples typically used for fabrication of superconducting radio frequency (SCRF) cavities. Optical conductivity (σ(0), approximated near zero frequency) of EP (σ(0) ∼ 9 × 103 Ω-1 cm-1) sample is one order of magnitude higher than that of BCP (σ(0) ∼ 7 × 102 Ω-1 cm-1) and AR (σ(0) ∼ 3 × 102 Ω-1 cm-1) niobium samples. Furthermore, physical constants of electropolished Nb-SCRF materials such as concentration of conduction electrons (∼ 1.8 × 1022 electrons/cm3), average velocity (∼ 5.9 × 107 cm/s) of the electrons on the Fermi surface, and mean free path (∼ 0.53 nm) were also found to be considerably higher than that of the BCP and the AR samples. The depth of electric field penetration (in low frequency region) in the electropolished Nb sample (∼ 80 nm) is appreciably lesser than the BCP (∼ 450 nm) and the AR (∼ 400 nm) samples.

  10. Solid-supported synthesis: From pharmacologically relevant heterocycles to biologically active surfaces

    DEFF Research Database (Denmark)

    Komnatnyy, Vitaly V.

    for solid-phase synthesis, methods for on - and off-bead screening of combinatorial libraries and their applic ation to various biological targets. The first part of the thesis is dedicated to the development of methodology for the synthesis of structurally diverse heterocyclic scaffolds via N...... methods for the controlled organo-functionalization of titanium, one of the most prominent materials in medicinal device industry, have been suggested . Initial acidic and oxidative treatment s of the metal surface genera te reactive hydroxyl moieties , which are subsequently modified with synthetically...... versatile amine -containing reagents. Subsequent applications in antimicrobial peptide synthesis, metal -catalysis, release from the surface, and polymer grafti ng, are also presented....

  11. Demonstrating electromagnetic control of free-surface, liquid-metal flows relevant to fusion reactors

    Science.gov (United States)

    Hvasta, M. G.; Kolemen, E.; Fisher, A. E.; Ji, H.

    2018-01-01

    Plasma-facing components (PFC’s) made from solid materials may not be able to withstand the large heat and particle fluxes that will be produced within next-generation fusion reactors. To address the shortcomings of solid PFC’s, a variety of liquid-metal (LM) PFC concepts have been proposed. Many of the suggested LM-PFC designs rely on electromagnetic restraint (Lorentz force) to keep free-surface, liquid-metal flows adhered to the interior surfaces of a fusion reactor. However, there is very little, if any, experimental data demonstrating that free-surface, LM-PFC’s can actually be electromagnetically controlled. Therefore, in this study, electrical currents were injected into a free-surface liquid-metal that was flowing through a uniform magnetic field. The resultant Lorentz force generated within the liquid-metal affected the velocity and depth of the flow in a controllable manner that closely matched theoretical predictions. These results show the promise of electromagnetic control for LM-PFC’s and suggest that electromagnetic control could be further developed to adjust liquid-metal nozzle output, prevent splashing within a tokamak, and alter heat transfer properties for a wide-range of liquid-metal systems.

  12. Surface coatings on quartz grains in bentonites and their relevance to human health

    International Nuclear Information System (INIS)

    Wendlandt, Richard F.; Harrison, Wendy J.; Vaughan, David J.

    2007-01-01

    The cytotoxicity of quartz in the human lung is recognized to be dependent on both the inherent properties of the silica dust and external factors related to the history of the dust and including the presence of surface contamination. In this study, the physical and chemical surface properties of quartz grains in commercial bentonite deposits from the western (South Dakota) and southern (Alabama) USA were investigated. Measured quartz contents of bentonites range from 1.9 to 8.5 wt% with the <10 μm size fraction comprising 6-45% of this total. Trace element contents (Fe-Ti-Al) of quartz grains from any given bentonite are similar, indicating a single origin for the quartz with little if any contamination from other sources. Surface coatings are pervasive on all quartz grains and resist removal by repeated vigorous washings and reaction with HCl. Textural attributes and XPS and EDS analyses of these coatings are consistent with most being montmorillonite and, less frequently, mixtures of montmorillonite and opaline silica. Opaline silica (opal-A and opal-CT) occurs in two texturally distinct generations: an early massive grain-coating event and as later lepispheres. Montmorillonite coating thicknesses range from <1 μm to more than 10 μm thick. Surfaces of plagioclase, K-feldspar, and biotite grains are conspicuously devoid of montmorillonite coatings, but may show sparse distributions of opal-CT lepispheres. HRTEM has not confirmed a topotactic relationship or atomic structural concordance between montmorillonite coatings and underlying quartz grains. Alternatively, a precursor volcanic glass phase that coats the quartz surfaces during volcanic eruption and/or preferential early precipitation of opaline silica on quartz may provide substrates for development of montmorillonite coatings. Estimations of montmorillonite biodurability under pulmonary pH conditions suggest possible prolonged sequestration of respired bentonite quartz grains from contact with lung

  13. New porous titanium–niobium oxide for photocatalytic degradation of bromocresol green dye in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Chaleshtori, Maryam Zarei, E-mail: mzarei@utep.edu [Materials Research and Technology Institute (MRTI), University of Texas at El Paso, 500W. University Ave., El Paso, TX 79968 (United States); Hosseini, Mahsa; Edalatpour, Roya [Materials Research and Technology Institute (MRTI), University of Texas at El Paso, 500W. University Ave., El Paso, TX 79968 (United States); Masud, S.M. Sarif [Department of Chemistry, University of Texas at El Paso, 500W. University Ave., El Paso, TX 79968 (United States); Chianelli, Russell R., E-mail: chianell@utep.edu [Materials Research and Technology Institute (MRTI), University of Texas at El Paso, 500W. University Ave., El Paso, TX 79968 (United States)

    2013-10-15

    Graphical abstract: The photocatalytic activity of different porous titanium–niobium oxides was evaluated toward degradation of bromocresol green (BG) under UV light. A better catalytic activity was observed for all samples at lower pH. Catalysts have a stronger ability for degradation of BG in acid media than in alkaline media. - Highlights: • Different highly structured titanium–niobium oxides have been prepared using improved methods of synthesis. • Photo-degradation of bromocresol green dye (BG) with nanostructure titanium–niobium oxide catalysts was carried out under UV light. • The photo-catalytic activity of all catalysts was higher in lower pH. • Titanium–niobium oxide catalysts are considerably stable and reusable. - Abstract: In this study, high surface area semiconductors, non porous and porous titanium–niobium oxides derived from KTiNbO{sub 5} were synthesized, characterized and developed for their utility as photocatalysts for decontamination with sunlight. These materials were then used in the photocatalytic degradation of bromocresol green dye (BG) in aqueous solution using UV light and their catalytic activities were evaluated at various pHs. For all catalysts, the photocatalytic degradation of BG was most efficient in acidic solutions. Results show that the new porous oxides have large porous and high surface areas and high catalytic activity. A topotactic dehydration treatment greatly improves catalyst performance at various pHs. Stability and long term activity of porous materials (topo and non-topo) in photocatalysis reactions was also tested. These results suggest that the new materials can be used to efficiently purify contaminated water.

  14. Optical monitoring of surface processes relevant to thin film growth by chemical vapour deposition

    International Nuclear Information System (INIS)

    Simcock, Michael Neil

    2002-01-01

    This thesis reports on the investigation of the use of reflectance anisotropy spectroscopy (RAS) as an in-situ monitor for the preparation and oxidation of GaAs(100) c(4x4) surfaces using a CVD 2000 MOCVD reactor. These surfaces were oxidised using air. It was found that it was possible to follow surface degradation using RA transients at 2.6eV and 4eV. From this data it was possible to speculate on the nature of the surface oxidation process. A study was performed into the rate of surface degradation under different concentrations of air, it was found that the relation between the air concentration and the surface degradation was complicated but that the behaviour of the first third of the degradation approximated a first order behaviour. An estimation of the activation energy of the process was then made, and an assessment of the potential use of the glove-box for STM studies which is an integral part of the MOCVD equipment was also made. Following this, a description is given of the construction of an interferometer for monitoring thin film growth. An investigation is also described into two techniques designed to evaluate the changes in reflected intensity as measured by an interferometer. The first technique uses an iteration procedure to determine the film thickness from the reflection data. This is done using a Taylor series expansion of the thin film reflection function to iterate for the thickness. Problems were found with the iteration when applied to noisy data, these were solved by using a least squares fit to smooth the data. Problems were also found with the iteration at the turning points these were solved using the derivative of the function and by anticipating the position of the turning points. The second procedure uses the virtual interface method to determine the optical constants of the topmost deposited material, the virtual substrate, and the growth rate. This method is applied by using a Taylor series expansion of the thin film reflection

  15. Niobium Nitride Thin Films and Multilayers for Superconducting Radio Frequency Cavities

    Science.gov (United States)

    Roach, William; Beringer, Douglas; Li, Zhaozhu; Clavero, Cesar; Lukaszew, Rosa

    2013-03-01

    Niobium nitride in thin film form has been considered for a number of applications including multi-layered coatings onto superconducting radio frequency cavities which have been proposed to overcome the fundamental accelerating gradient limit of ~50 MV/m in niobium based accelerators. In order to fulfill the latter application, the selected superconductor's thermodynamic critical field, HC, must be larger than that of niobium and separated from the Nb surface by an insulating layer in order to shield the Nb cavity from field penetration and thus allow higher field gradients. Thus, for the successful implementation of such multilayered stack it is important to consider not just the materials inherent properties but also how these properties may be affected in thin film geometry and also by the specific deposition techniques used. Here, we show the results of our correlated study of structure and superconducting properties in niobium nitride thin films and discuss the shielding exhibited in NbN/MgO/Nb multilayer samples beyond the lower critical field of Nb for the first time. This work was funded by the Defense Threat Reduction Agency (HDTRA-10-1-0072).

  16. Niobium films produced by magnetron sputtering using an Ar-He mixture as discharge gas

    CERN Document Server

    Schucan, G M; Calatroni, Sergio

    1995-01-01

    Superconducting RF accelerating cavities have been produced at CERN by sputter-coating, with a thin niobium layer, cavities made of copper. In the present work, the discharge behaviour and niobium film properties have been investigated when part of the argon sputtering gas is replaced with helium. Helium is chosen because of its low mass, which reduces the energy lost by the niobium atoms colliding with the sputter gas atoms. The higher niobium atom energy should lead to higher adatom mobility on the substrate and, hence, to a larger grain size, a feature which is highly desirable to reduce the cavity surface resistance. It has been found that helium addition effectively helps to maintain the discharge at considerably lower argon pressures, via metastable-neutral ionisation and high secondary electron yield. However, a large amount of helium is trapped in the film, amount which is proportional to the helium partial pressure during the discharge, resulting in a reduction of both Residual Resistivity Ratio and ...

  17. Niobium carbide synthesis by solid-gas reaction using a rotating cylinder reactor

    International Nuclear Information System (INIS)

    Fontes, F.A.O.; Gomes, K.K.P.; Oliveira, S.A.; Souza, C.P.; Sousa, J.F.; Rio Grande do Norte Univ., Natal, RN

    2004-01-01

    A rotating cylinder reactor was designed for the synthesis of niobium carbide powders at 1173 K. Niobium carbide, NbC, was prepared by carbothermal reduction starting from commercial niobium pentoxide powders. The reactor was heated using a custom-made, two-part, hinged, electric furnace with programmable temperature control. The design and operational details of the reactor are presented. The longitudinal temperature gradient inside the reactor was determined. Total reaction time was monitored by a gas chromatograph equipped with an FID detector for determination of methane concentrations. The results show that time of reaction depended on rotation speed. NbC was also prepared in a static-bed alumina reactor using the same conditions as in the previous case. The niobium carbide powders were characterized by X-ray diffraction and compared with commercially available products. Morphological, particle size distribution and surface area analyses were obtained using SEM, LDPS and BET, respectively. Therefore, the present study offers a significant technological contribution to the synthesis of NbC powders in a rotating cylinder reactor. (author)

  18. Surface Generation Modeling in Ball Nose End Milling: a review of relevant literature

    DEFF Research Database (Denmark)

    Bissacco, Giuliano

    One of the most common metal removal operation used in industry is the milling process. This machining process is well known since the beginning of last century and has experienced, along the years, many improvements of the basic technology, as concerns tools, machine tools, coolants...... to be adjusted afterwards. Nevertheless, many efforts have been done during the last 50 years in order to realize prediction tools for machining processes and particularly for conventional turning and milling operations. Most of these models aim at prediction of cutting forces tool wear and tool life. However...... been addressed in this direction. Among all the machining operations, ball nose end milling has shown great potentials, particularly in machining of sculptured surfaces with high requirements in terms of surface finish; this is due to the good spatial agreement of the mill shape with the geometry...

  19. Laboratory Studies of Ethane Ice Relevant to Outer Solar System Surfaces

    Science.gov (United States)

    Moore, Marla H.; Hudson, Reggie; Raines, Lily

    2009-01-01

    Oort Cloud comets, as well as TNOs Makemake (2045 FYg), Quaoar, and Pluto, are known to contain ethane. However, even though this molecule is found on several outer Solar System objects relatively little information is available about its amorphous and crystalline phases. In new experiments, we have prepared ethane ices at temperatures applicable to the outer Solar System, and have heated and ion-irradiated these ices to study phase changes and ethane's radiation chemistry using mid-IR spectroscopy (2.2 - 16.6 microns). Included in our work is the meta-stable phase that exists at 35 - 55 K. These results, including newly obtained optical constants, are relevant to ground-based observational campaigns, the New Horizons mission, and supporting laboratory work. An improved understanding of solid-phase ethane may contribute to future searches for this and other hydrocarbons in the outer Solar System.

  20. BIOPHYSICAL PROPERTIES OF NUCLEIC ACIDS AT SURFACES RELEVANT TO MICROARRAY PERFORMANCE

    OpenAIRE

    Rao, Archana N.; Grainger, David W.

    2014-01-01

    Both clinical and analytical metrics produced by microarray-based assay technology have recognized problems in reproducibility, reliability and analytical sensitivity. These issues are often attributed to poor understanding and control of nucleic acid behaviors and properties at solid-liquid interfaces. Nucleic acid hybridization, central to DNA and RNA microarray formats, depends on the properties and behaviors of single strand (ss) nucleic acids (e.g., probe oligomeric DNA) bound to surface...

  1. Hydrogen isotope transport across tungsten surfaces exposed to a fusion relevant He ion fluence

    Science.gov (United States)

    Baldwin, M. J.; Doerner, R. P.

    2017-07-01

    Tungsten targets are exposed to controlled sequences of D2 and He, and He and D2 plasma in the Pisces-A linear plasma device, with a view to studying the outward and inward transport of D across a He implanted surface, using thermal desorption mass spectrometry. Differences in transport are interpreted from changes in peak desorption temperature and amplitude for D2 release, compared against that of control targets exposed to just D2 plasma. Desorption data are modeled with Tmap-7 to infer the nature by which He leads to the ‘reduced inventory’ effect for H isotope uptake. A dual segment (surface-30 nm, bulk) W Tmap-7 model is developed, that simulates both plasma exposure and thermal desorption. Good agreement between desorption data and model is found for D2 release from control targets provided that the implanted flux is reduced, similar to that reported by others. For He affected release, the H isotope transport properties of the surface segment are adjusted away from control target bulk values during the computation. Modeling that examines outward D transport through the He implanted layer suggests that a permeation barrier is active, but bubble induced porosity is insufficient to fully explain the barrier strength. Moderately increased diffusional migration energy in the model over the He affected region, however, gives a barrier strength consistent with experiment. The same model, applied to inward transport, predicts the reduced inventory effect, but a further reduction in the implanted D flux is necessary for precise agreement.

  2. Evaluation of the ability of Acinetobacter baumannii to form biofilms on six different biomedical relevant surfaces.

    Science.gov (United States)

    Greene, C; Wu, J; Rickard, A H; Xi, C

    2016-10-01

    The human opportunistic pathogen, Acinetobacter baumannii, has the propensity to form biofilms and frequently cause medical device-related infections in hospitals. However, the physio-chemical properties of medical surfaces, in addition to bacterial surface properties, will affect colonization and biofilm development. The objective of this study was to compare the ability of A. baumannii to form biofilms on six different materials common to the hospital environment: glass, porcelain, stainless steel, rubber, polycarbonate plastic and polypropylene plastic. Biofilms were developed on material coupons in a CDC biofilm reactor. Biofilms were visualized and quantified using fluorescent staining and imaged using confocal laser scanning microscopy (CLSM) and by direct viable cell counts. Image analysis of CLSM stacks indicated that the mean biomass values for biofilms grown on glass, rubber, porcelain, polypropylene, stainless steel and polycarbonate were 0·04, 0·26, 0·62, 1·00, 2·08 and 2·70 μm(3) /μm(2) respectively. Polycarbonate developed statistically more biofilm mass than glass, rubber, porcelain and polypropylene. Viable cell counts data were in agreement with the CLSM-derived data. In conclusion, polycarbonate was the most accommodating surface for A. baumannii ATCC 17978 to form biofilms while glass was least favourable. Alternatives to polycarbonate for use in medical and dental devices may need to be considered. In the hospital environment, Acinetobacter baumannii is one of the most persistent and difficult to control opportunistic pathogens. The persistence of A. baumannii is due, in part, to its ability to colonize surfaces and form biofilms. This study demonstrates that A. baumannii can form biofilms on a variety of different surfaces and develops substantial biofilms on polycarbonate - a thermoplastic material that is often used in the construction of medical devices. The findings highlight the need to further study the in

  3. Tailoring of the PS surface with low energy ions: Relevance to growth and adhesion of noble metals

    International Nuclear Information System (INIS)

    Zaporojtchenko, V.; Zekonyte, J.; Wille, S.; Schuermann, U.; Faupel, F.

    2005-01-01

    Ion-polymer interaction induces different phenomena in the near surface layer of polymers, and promotes its adhesion to metals. Using XPS, TEM and AFM, polystyrene surface was examined after 1 keV ion-beam treatments with oxygen, nitrogen and argon ions in the ion fluence range from 10 12 to 10 16 cm -2 to clarify the following points: chemical reaction after treatment in vacuum and after exposure to air, identification of adsorption-relevant species for metal atoms, formation of cross-links in the outermost polymer layer. The early stages of metal-polymer interface formation during metallization play a crucial role in the metal-polymer adhesion. Therefore, the influence of the ion fluence and ion chemistry on the condensation of noble metals, film growth and peel strength were measured. The peel strength showed a maximum at a certain fluence depending on ion chemistry. For example, the surface treatment with very low fluence of oxygen ions improved the adhesion between copper and polystyrene by two orders of magnitude without significantly increasing the surface roughness measured with AFM. The locus of failure changed at the same time from interfacial failure for untreated polymer surfaces to cohesive failure in the polymer for modified surfaces. A multilayer model of the metal-polymer interface after ion treatment is suggested

  4. Relevance of leaf surface contamination for assessing chemical composition of bromeliads in a restinga forest

    Energy Technology Data Exchange (ETDEWEB)

    Elias, C; Fernandes, E A.N.; Franca, E J; Bacchi, M A; Tagliaferro, F S [Centro de Energia Nuclear na Agricultura, Universidade de Sao Paulo, Piracicaba, SP (Brazil)

    2008-11-15

    Resuspended soil and other airborne particles adhered to the leaf surface affect the chemical composition of the plant. A well-defined cleaning procedure is necessary to avoid this problem, providing a correct assessment of the inherent chemical composition of bromeliads. To evaluate the influence of a washing procedure, INAA was applied for determining chemical elements in the leaves of bromeliads from Vriesea carinata species, both non-washed and washed with Alconox, EDTA and bi-distilled water. Br, Ce, Hg, La, Sc, Se, Sm and Th showed higher mass fractions in nonwashed leaves. The washing procedure removed the exogenous material without leaching chemical elements from inside the tissues. (author)

  5. Molecule-surface interaction processes of relevance to gas blanket type fusion device divertor design

    Energy Technology Data Exchange (ETDEWEB)

    Snowdon, K.J. [Newcastle Univ. (United Kingdom). Dept. of Physics; Tawara, H.

    1997-01-01

    The mechanisms which may lead to the departure of molecular species from surfaces exposed to low energy (0.1-100 eV) particle or photon and electron irradiation are reviewed. Where possible, the charge and electronic state, angular, translational and internal energy distributions of the departing molecules are described and the physical origin of the nature of those distributions identified. The consequences, for the departing molecules, of certain material choices become apparent from such an analysis. Such information may help guide the choice of appropriate materials for plasma facing components of gas-blanket type divertors such as that recently proposed for the International Thermonuclear Experimental Reactor (ITER). (author). 71 refs.

  6. Relevance of sub-surface chip layers for the lifetime of magnetically trapped atoms

    DEFF Research Database (Denmark)

    Zhang, H. B.; Henkel, C; Haller, E.

    2005-01-01

    on the thickness of that layer, as long as the layers below have a much smaller conductivity; essentially the same magnetic noise would be obtained with a metallic membrane suspended in vacuum. Based on our theory we give general scaling laws of how to reduce the effect of surface magnetic noise on the trapped...... measurements where the center of a side guide trap is laterally shifted with respect to the current carrying wire using additional bias fields. Comparing the experiment to theory, we find a fair agreement and demonstrate that for a chip whose topmost layer is metallic, the magnetic noise depends essentially...

  7. Relevance of leaf surface contamination for assessing chemical composition of bromeliads in a restinga forest

    International Nuclear Information System (INIS)

    Elias, C.; Fernandes, E.A.N.; Franca, E.J.; Bacchi, M.A.; Tagliaferro, F.S.

    2008-01-01

    Resuspended soil and other airborne particles adhered to the leaf surface affect the chemical composition of the plant. A well-defined cleaning procedure is necessary to avoid this problem, providing a correct assessment of the inherent chemical composition of bromeliads. To evaluate the influence of a washing procedure, INAA was applied for determining chemical elements in the leaves of bromeliads from Vriesea carinata species, both non-washed and washed with Alconox, EDTA and bi-distilled water. Br, Ce, Hg, La, Sc, Se, Sm and Th showed higher mass fractions in nonwashed leaves. The washing procedure removed the exogenous material without leaching chemical elements from inside the tissues. (author)

  8. Provision of water by halite deliquescence for Nostoc commune biofilms under Mars relevant surface conditions

    Science.gov (United States)

    Jänchen, Jochen; Feyh, Nina; Szewzyk, Ulrich; de Vera, Jean-Pierre P.

    2016-04-01

    Motivated by findings of new mineral related water sources for organisms under extremely dry conditions on Earth we studied in an interdisciplinary approach the water sorption behaviour of halite, soil component and terrestrial Nostoc commune biofilm under Mars relevant environmental conditions. Physicochemical methods served for the determination of water sorption equilibrium data and survival of heterotrophic bacteria in biofilm samples with different water contents was assured by recultivation. Deliquescence of halite provides liquid water at temperatures <273 K and may serve as water source on Mars during the morning stabilized by the CO2 atmosphere for a few hours. The protecting biofilm of N. commune is rather hygroscopic and tends to store water at lower humidity values. Survival tests showed that a large proportion of the Alphaproteobacteria dominated microbiota associated to N. commune is very desiccation tolerant and water uptake from saturated NaCl solutions (either by direct uptake of brine or adsorption of humidity) did not enhance recultivability in long-time desiccated samples. Still, a minor part can grow under highly saline conditions. However, the salinity level, although unfavourable for the host organism, might be for parts of the heterotrophic microbiota no serious hindrance for growing in salty Mars-like environments.

  9. Characterization of high-purity niobium structures fabricated using the electron beam melting process

    Science.gov (United States)

    Terrazas Najera, Cesar Adrian

    Additive Manufacturing (AM) refers to the varied set of technologies utilized for the fabrication of complex 3D components from digital data in a layer-by-layer fashion. The use of these technologies promises to revolutionize the manufacturing industry. The electron beam melting (EBM) process has been utilized for the fabrication of fully dense near-net-shape components from various metallic materials. This process, catalogued as a powder bed fusion technology, consists of the deposition of thin layers (50 - 120microm) of metallic powder particles which are fused by the use of a high energy electron beam and has been commercialized by Swedish company Arcam AB. Superconducting radio frequency (SRF) cavities are key components that are used in linear accelerators and other light sources for studies of elemental physics. Currently, cavity fabrication is done by employing different forming processes including deep-drawing and spinning. In both of the latter techniques, a feedstock high-purity niobium sheet with a thickness ranging from 3-4 mm is mechanically deformed and shaped into the desired geometry. In this manner, half cavities are formed that are later joined by electron beam welding (EBW). The welding step causes variability in the shape of the cavity and can also introduce impurities at the surface of the weld interface. The processing route and the purity of niobium are also of utmost importance since the presence of impurities such as inclusions or defects can be detrimental for the SRF properties of cavities. The focus of this research was the use of the EBM process in the manufacture of high purity niobium parts with potential SRF applications. Reactor grade niobium was plasma atomized and used as the precursor material for fabrication using EBM. An Arcam A2 system was utilized for the fabrication. The system had all internal components of the fabrication chamber replaced and was cleaned to prevent contamination of niobium powder. A mini-vat, developed at

  10. Study of niobium V compounds in nitric medium

    International Nuclear Information System (INIS)

    Gue, J.-P.; Kikindai, Tivadar; CEA Centre d'Etudes Nucleaires de Fontenay-aux-Roses, 92

    1976-01-01

    Nitric solutions of niobium V were studied in the range of concentrations of 5.10 -6 M to 0,5.10 -3 M in niobium and 0,4 to 10N in nitric acid. Methods used were light scattering, electron microscopy, electrophoresis and ultracentrifugation. It is shown that niobium was in a colloidal hydroxide form. Solvent extraction studies were performed with dibutyl phosphoric acid diluted in dodecane. It appears that floculation of the sol occurs for weak organic acid concentrations. But if the concentration increases, the precipitated niobium compound is redissolved in the organic phase [fr

  11. Proposal of a new biokinetic model for niobium

    International Nuclear Information System (INIS)

    Oliveira, Roges

    2006-01-01

    There are two niobium isotopes generated in nuclear power plants: 95 Nb and 94 Nb. Workers and members of the public are subjects to intake these radionuclides in accident situation. For dose calculation purpose, it is very important to develop a model that describes in a more realistic way the kinetics of niobium inside of the human body. Presently the model adopted by ICRP (ICRP, 1989) is based on animal studies and describes the behavior of niobium in human being in a simple manner. The new model proposal describes the kinetics of the niobium from the intake into the blood until the excretion, doing this in a more realistic form and considering not only data from animals but data from human beings as well. For this objective, a workers group of a niobium extraction and processing industry exposed to stable niobium (93 Nb) in oxide insoluble form with associated uranium, was monitored for uranium and niobium determination in urinary and fecal excretion, by mass spectrometry. Based in the ratios of the niobium concentration in urinary and faecal excretion of this workers and animal data study, a new biokinetic model for niobium was proposed, with the followings modifications relative to ICRP model: a new compartment that represents muscular tissue; the fractions which are deposited into the compartment are modified; a third component in the retention equation of the bone tissue; introduction of recirculation between organs and blood. The new model was applied for a case of accidental intake and described adequately the experimental data

  12. Development of high purity niobium material for superconducting cavities

    International Nuclear Information System (INIS)

    Umezawa, Hiroaki; Takeuchi, Koichi; Sakita, Kohei; Suzuki, Takafusa; Saito, Kenji; Noguchi, Shuichi.

    1993-01-01

    For the superconducting niobium cavities, issues of thermal quench and field emission have to be solved to achieve a high field gradient (>25MV/m) for TESLA (TeV Energy Superconducting Linear Accelerator). In order to overcome the quench, upgrading of thermal conductivity of niobium material at the low temperature is very important. On the reduction of the field emission not only dust particles but also defect, impurity and inhomogeneity should be considered. Therefore development of high purity niobium material is very important to solve these issues. This paper describes the our latest R and D for high purity niobium material. (author)

  13. Impurity dependence of superconductivity in niobium

    International Nuclear Information System (INIS)

    Laa, C.

    1984-04-01

    Jump temperatures, the critical fields Hsubc and Hsubc 2 and specific heats were measured on niobium samples where the impurity content was systematically varied by loading with nitrogen. Quantities could thus be extrapolated to lattice perfection and absolute purity. Comparisons with theories were made and some parameters extracted. Agreement was found with Gorkov theory for small impurities. A new value of the Ginsburg-Landau parameter Ko was determined to be just above 1/sqrt2 which proves that niobium is an elementary Type II semiconductor. By comparisons with the BCS and the CLAC theory the values of the mean Fermi velocity, the London penetration depth, the BCS coherence length and the impurity parameter were extracted. (G.Q.)

  14. Niobium and hafnium grown on porous membranes

    International Nuclear Information System (INIS)

    Morant, C.; Marquez, F.; Campo, T.; Sanz, J.M.; Elizalde, E.

    2010-01-01

    In this work we report on a method for fabricating highly ordered nanostructures of niobium and hafnium metals by physical vapour deposition using two different templates: anodized aluminum oxide membranes (AAO) and zirconium onto AAO membranes (Zr/AAO). The growth mechanism of these metal nanostructures is clearly different depending on the material used as a template. A different morphology was obtained by using AAO or Zr/AAO templates: when the metal is deposited onto AAO membranes, nanospheres with ordered hexagonal regularity are obtained; however, when the metal is deposited onto a Zr/AAO template, highly ordered nanocones are formed. The experimental approach described in this work is simple and suitable for synthesizing nanospheres or nanoholes of niobium and hafnium metals in a highly ordered structure.

  15. High-Performance Supercapacitors from Niobium Nanowire Yarns.

    Science.gov (United States)

    Mirvakili, Seyed M; Mirvakili, Mehr Negar; Englezos, Peter; Madden, John D W; Hunter, Ian W

    2015-07-01

    The large-ion-accessible surface area of carbon nanotubes (CNTs) and graphene sheets formed as yarns, forests, and films enables miniature high-performance supercapacitors with power densities exceeding those of electrolytics while achieving energy densities equaling those of batteries. Capacitance and energy density can be enhanced by depositing highly pseudocapacitive materials such as conductive polymers on them. Yarns formed from carbon nanotubes are proposed for use in wearable supercapacitors. In this work, we show that high power, energy density, and capacitance in yarn form are not unique to carbon materials, and we introduce niobium nanowires as an alternative. These yarns show higher capacitance and energy per volume and are stronger and 100 times more conductive than similarly spun carbon multiwalled nanotube (MWNT) and graphene yarns. The long niobium nanowires, formed by repeated extrusion and drawing, achieve device volumetric peak power and energy densities of 55 MW·m(-3) (55 W·cm(-3)) and 25 MJ·m(-3) (7 mWh·cm(-3)), 2 and 5 times higher than that for state-of-the-art CNT yarns, respectively. The capacitance per volume of Nb nanowire yarn is lower than the 158 MF·m(-3) (158 F·cm(-3)) reported for carbon-based materials such as reduced graphene oxide (RGO) and CNT wet-spun yarns, but the peak power and energy densities are 200 and 2 times higher, respectively. Achieving high power in long yarns is made possible by the high conductivity of the metal, and achievement of high energy density is possible thanks to the high internal surface area. No additional metal backing is needed, unlike for CNT yarns and supercapacitors in general, saving substantial space. As the yarn is infiltrated with pseudocapacitive materials such as poly(3,4-ethylenedioxythiophene) (PEDOT), the energy density is further increased to 10 MJ·m(-3) (2.8 mWh·cm(-3)). Similar to CNT yarns, niobium nanowire yarns are highly flexible and show potential for weaving into textiles

  16. Defect studies of H+ implanted niobium

    Czech Academy of Sciences Publication Activity Database

    Prochazka, I.; Čížek, J.; Havránek, Vladimír; Anwand, W.

    2015-01-01

    Roč. 645, SI1 (2015), s. 69-71 ISSN 0925-8388. [14th International Symposium on Metal-Hydrogen Systems (MH). Salford, 20.07.2014-25.07.2014] R&D Projects: GA MŠk LM2011019 Institutional support: RVO:61389005 Keywords : Niobium * Hydrogen * defects * Positron annihilation Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.014, year: 2015

  17. Hydrogen solubility in polycrystalline - and nonocrystalline niobium

    International Nuclear Information System (INIS)

    Ishikawa, T.T.; Silva, J.R.G. da

    1981-01-01

    Hydrogen solubility in polycrystalline and monocrystalline niobium was measured in the range 400 0 C to 1000 0 C at one atmosphere hydrogen partial pressure. The experimental technique consists of saturation of the solvent metal with hydrogen, followed by quenching and analysis of the solid solution. It is presented solubility curves versus reciprocal of the absolute doping temperature, associated with their thermodynamical equation. (Author) [pt

  18. Spectroellipsometric detection of silicon substrate damage caused by radiofrequency sputtering of niobium oxide

    Science.gov (United States)

    Lohner, Tivadar; Serényi, Miklós; Szilágyi, Edit; Zolnai, Zsolt; Czigány, Zsolt; Khánh, Nguyen Quoc; Petrik, Péter; Fried, Miklós

    2017-11-01

    Substrate surface damage induced by deposition of metal atoms by radiofrequency (rf) sputtering or ion beam sputtering onto single-crystalline silicon (c-Si) surface has been characterized earlier by electrical measurements. The question arises whether it is possible to characterize surface damage using spectroscopic ellipsometry (SE). In our experiments niobium oxide layers were deposited by rf sputtering on c-Si substrates in gas mixture of oxygen and argon. Multiple angle of incidence spectroscopic ellipsometry measurements were performed, a four-layer optical model (surface roughness layer, niobium oxide layer, native silicon oxide layer and ion implantation-amorphized silicon [i-a-Si] layer on a c-Si substrate) was created in order to evaluate the spectra. The evaluations yielded thicknesses of several nm for the i-a-Si layer. Better agreement could be achieved between the measured and the generated spectra by inserting a mixed layer (with components of c-Si and i-a-Si applying the effective medium approximation) between the silicon oxide layer and the c-Si substrate. High depth resolution Rutherford backscattering (RBS) measurements were performed to investigate the interface disorder between the deposited niobium oxide layer and the c-Si substrate. Atomic resolution cross-sectional transmission electron microscopy investigation was applied to visualize the details of the damaged subsurface region of the substrate.

  19. Structural phase transitions in niobium oxide nanocrystals

    Science.gov (United States)

    Yuvakkumar, R.; Hong, Sun Ig

    2015-09-01

    Niobium oxide nanocrystals were successfully synthesized employing the green synthesis method. Phase formation, microstructure and compositional properties of 1, 4 and 7 days incubation treated samples after calcinations at 450 °C were examined using X-ray diffraction, Raman, photoluminescence (PL), infrared, X-ray photoelectron spectra and transmission electron microscopic characterizations. It was observed that phase formation of Nb2O5 nanocrystals was dependent upon the incubation period required to form stable metal oxides. The characteristic results clearly revealed that with increasing incubation and aging, the transformation of cubic, orthorhombic and monoclinic phases were observed. The uniform heating at room temperature (32 °C) and the ligation of niobium atoms due to higher phenolic constituents of utilized rambutan during aging processing plays a vital role in structural phase transitions in niobium oxide nanocrystals. The defects over a period of incubation and the intensities of the PL spectra changing over a period of aging were related to the amount of the defects induced by the phase transition.

  20. Electrical and electrochemical properties of niobium disulphide

    Energy Technology Data Exchange (ETDEWEB)

    Molenda, J.; Bak, T.; Marzec, J. [Academy of Min. and Metall., Cracow (Poland). Dept. of Chem. of Solids

    1996-07-16

    The electrical conductivity and thermoelectric power measurements of NbS{sub 2} pure and electrochemically doped with lithium, Li{sub x}NbS{sub 2}, were done as a function of temperature (77 to 300 K). The high absolute values of conductivity and their dependence on temperature together with low absolute values of thermoelectric power and their linear increase with temperature indicate metallic properties of niobium disulphide. In case of Li{sub x}NbS{sub 2} the obtained values of electrical conductivity are significantly lower as compared with the starting NbS{sub 2}. The temperature dependence of the thermo-electric power of intercalated niobium disulphide also indicates that metallic properties get worse as the concentration of lithium increases. The modification of the electronic structure of NbS{sub 2} due to lithium intercalation was proposed. The character of the discharge curves in the electrochemical Li/Li{sup +}/Li{sub x}NbS{sub 2} systems was correlated with the electronic properties of niobium disulphide. (orig.) 11 refs.

  1. The use of niobium based catalysts for liquid fuel production

    Directory of Open Access Journals (Sweden)

    Reguera Frank Martin

    2004-01-01

    Full Text Available The catalytic properties of niobium based catalysts were investigated in the conversion of oleic acid to liquid fuels at atmospheric pressure and at 623 K. The catalytic tests were performed in a fixed bed and continuous flow reactor using an acid to catalyst ratio equal to 4 and N2 as carrier gas. The reaction products were analyzed by gas chromatography and acidity measurements. NH3 temperature programmed desorption, N2 adsorption-desorption (BET method and Xray diffraction were also performed in order to determine the structural and acidic properties of the catalysts. From the catalytic tests, it was detected the formation of compounds in the range of gasoline, diesel and lubricant oils. Higher catalytic activity and selectivity for diesel fuel were observed for the catalysts NbOPO4 and H3PO4/Nb2O5 that possesses higher acidities and surface areas.

  2. Structural and superconducting properties of sputter-deposited niobium films for applications in RF accelerating cavities

    CERN Document Server

    Peck, M A

    2000-01-01

    The present work presents the results of a systematic study of superconducting and structural properties of niobium films sputter deposited onto the inner walls of radiofrequency copper resonators. The measured superconducting quantities include the surface resistance, the critical temperature, the penetration depth and the upper and lower critical fields. In addition to films grown with different discharge gases (Xe, Kr, Ar, Ne and Ar-Ne mixtures) and to films grown on substrates prepared under different conditions, the study also includes massive niobium cavities. The surface resistance is analysed in terms of its dependence on the temperature and on the rf field amplitude and, when possible, compared to theoretical predictions. In general, good agreement with BCS theory is observed. All experimental results are presented in the form of a simple, but adequate parameterisation. The residual resistance is observed to be essentially uncorrelated with the other variables, but strongly dependent on the macroscop...

  3. Evidence of preferential diffusion and segregation of impurities at grain boundaries in very pure niobium used for radiofrequency cavities

    International Nuclear Information System (INIS)

    Antoine, C.; Bonin, B.; Safa, H.; Berthier, B.; Tessier, E.; Trocelier, P.; Chevarier, A.; Chevarier, N.; Roux, B.

    1996-04-01

    In order to overcome dissipation due to impurity segregation at grain boundary, niobium cavities are submitted to a purification annealing (1300 deg C ± 200 deg C under vacuum) during which titanium is evaporated onto the Nb surface. The resulting titanium layer acts as a solid state getter reacting with light impurities (H, C, N, O), thereby removing these impurities from the bulk of the niobium. Evidence of preferential titanium diffusion and segregation at grain boundaries has been studied using PIXE analysis induced by proton microbeam. (author)

  4. Hydrological analysis relevant to surface water storage at Jabiluka. Supervising Scientist report 142

    International Nuclear Information System (INIS)

    Chiew, F.H.S.; Wang, Q.J.

    1999-01-01

    The report is prepared for the Supervising Scientist at Jabiru. It describes part of an investigation into hydrological issues relating to the water management system proposed for the Jabiluka project. Specifically, the objective is to estimate the water storage capacity required to store surface runoff and other water within the total containment zone (TCZ) of the Jabiluka project. The water storage volume is calculated for a range of probabilities up to 0.002% that the pond design volume would be exceeded over a 30-year mine life. In this study, 50 000 sets of 30 years of daily rainfall and monthly pan evaporation data are stochastically generated to simulate the storage water balance. The approach used by Kinhill and Energy Resources of Australia (ERA) is reviewed and the pond design compared with the estimates derived here. The Kinhill-ERA approach is described in the Jabiluka Mill Alternative Public Environment Report and the Jabiluka Mill Alternative Public Environment Report Technical Appendices (hereon referred to as Jabiluka PER Appendices) (1998). The two reports also provide background to many other issues. The structural design of the storage and other features of the mine site are not considered here. This study also assumes that the bunds and other drainage diversion structures will prevent all water outside the TCZ from entering the TCZ and vice versa. The storage water balance components are discussed in section 2. Some of the water inflows into the storage and losses from the storage are discussed in detail, while elsewhere, the values used by Kinhill-ERA are adopted. Section 3 describes the selection of the climate stations used here, the rainfall and pan evaporation characteristics in the area and the stochastic generation of 1.5 million years of daily rainfall and monthly pan evaporation data. Section 4 describes the approach used to estimate the storage capacity, and presents the storage capacity estimates for various probabilities of

  5. Flux pinning characteristics in cylindrical ingot niobium used in superconducting radio frequency cavity fabrication

    OpenAIRE

    Dhavale, Asavari S.; Dhakal, Pashupati; Polyanskii, Anatolii A.; Ciovati, Gianluigi

    2012-01-01

    We present the results of from DC magnetization and penetration depth measurements of cylindrical bulk large-grain (LG) and fine-grain (FG) niobium samples used for the fabrication of superconducting radio frequency (SRF) cavities. The surface treatment consisted of electropolishing and low temperature baking as they are typically applied to SRF cavities. The magnetization data were fitted using a modified critical state model. The critical current density Jc and pinning force Fp are calculat...

  6. Effect of the niobium additions in the passive films potentiostatically grown in a sulphate medium

    International Nuclear Information System (INIS)

    Kuri, S.E.; Martins, M.; D'Alkaine, C.V.

    1984-01-01

    The stability of passive films potentiostatically grown on stainless steel electrodes was studied in a 2 N sulfuric acid. The effect of Niobium contents in the base metal was considered. The reactivation time was measured using the method of Potential Decay Measurements under Open-Circuit Conditions after electrochemical aging in the passivity region, and its influence on the surface oxidation states, was discussed. (Author) [pt

  7. Secondary Electron Emission from Plasma Processed Accelerating Cavity Grade Niobium

    Energy Technology Data Exchange (ETDEWEB)

    Basovic, Milos [Old Dominion Univ., Norfolk, VA (United States)

    2016-05-01

    Advances in the particle accelerator technology have enabled numerous fundamental discoveries in 20th century physics. Extensive interdisciplinary research has always supported further development of accelerator technology in efforts of reaching each new energy frontier. Accelerating cavities, which are used to transfer energy to accelerated charged particles, have been one of the main focuses of research and development in the particle accelerator field. Over the last fifty years, in the race to break energy barriers, there has been constant improvement of the maximum stable accelerating field achieved in accelerating cavities. Every increase in the maximum attainable accelerating fields allowed for higher energy upgrades of existing accelerators and more compact designs of new accelerators. Each new and improved technology was faced with ever emerging limiting factors. With the standard high accelerating gradients of more than 25 MV/m, free electrons inside the cavities get accelerated by the field, gaining enough energy to produce more electrons in their interactions with the walls of the cavity. The electron production is exponential and the electron energy transfer to the walls of a cavity can trigger detrimental processes, limiting the performance of the cavity. The root cause of the free electron number gain is a phenomenon called Secondary Electron Emission (SEE). Even though the phenomenon has been known and studied over a century, there are still no effective means of controlling it. The ratio between the electrons emitted from the surface and the impacting electrons is defined as the Secondary Electron Yield (SEY). A SEY ratio larger than 1 designates an increase in the total number of electrons. In the design of accelerator cavities, the goal is to reduce the SEY to be as low as possible using any form of surface manipulation. In this dissertation, an experimental setup was developed and used to study the SEY of various sample surfaces that were treated

  8. Secondary electron emission from plasma processed accelerating cavity grade niobium

    Science.gov (United States)

    Basovic, Milos

    Advances in the particle accelerator technology have enabled numerous fundamental discoveries in 20th century physics. Extensive interdisciplinary research has always supported further development of accelerator technology in efforts of reaching each new energy frontier. Accelerating cavities, which are used to transfer energy to accelerated charged particles, have been one of the main focuses of research and development in the particle accelerator field. Over the last fifty years, in the race to break energy barriers, there has been constant improvement of the maximum stable accelerating field achieved in accelerating cavities. Every increase in the maximum attainable accelerating fields allowed for higher energy upgrades of existing accelerators and more compact designs of new accelerators. Each new and improved technology was faced with ever emerging limiting factors. With the standard high accelerating gradients of more than 25 MV/m, free electrons inside the cavities get accelerated by the field, gaining enough energy to produce more electrons in their interactions with the walls of the cavity. The electron production is exponential and the electron energy transfer to the walls of a cavity can trigger detrimental processes, limiting the performance of the cavity. The root cause of the free electron number gain is a phenomenon called Secondary Electron Emission (SEE). Even though the phenomenon has been known and studied over a century, there are still no effective means of controlling it. The ratio between the electrons emitted from the surface and the impacting electrons is defined as the Secondary Electron Yield (SEY). A SEY ratio larger than 1 designates an increase in the total number of electrons. In the design of accelerator cavities, the goal is to reduce the SEY to be as low as possible using any form of surface manipulation. In this dissertation, an experimental setup was developed and used to study the SEY of various sample surfaces that were treated

  9. Estimation of Surface Soil Moisture in Irrigated Lands by Assimilation of Landsat Vegetation Indices, Surface Energy Balance Products, and Relevance Vector Machines

    Directory of Open Access Journals (Sweden)

    Alfonso F. Torres-Rua

    2016-04-01

    Full Text Available Spatial surface soil moisture can be an important indicator of crop conditions on farmland, but its continuous estimation remains challenging due to coarse spatial and temporal resolution of existing remotely-sensed products. Furthermore, while preceding research on soil moisture using remote sensing (surface energy balance, weather parameters, and vegetation indices has demonstrated a relationship between these factors and soil moisture, practical continuous spatial quantification of the latter is still unavailable for use in water and agricultural management. In this study, a methodology is presented to estimate volumetric surface soil moisture by statistical selection from potential predictors that include vegetation indices and energy balance products derived from satellite (Landsat imagery and weather data as identified in scientific literature. This methodology employs a statistical learning machine called a Relevance Vector Machine (RVM to identify and relate the potential predictors to soil moisture by means of stratified cross-validation and forward variable selection. Surface soil moisture measurements from irrigated agricultural fields in Central Utah in the 2012 irrigation season were used, along with weather data, Landsat vegetation indices, and energy balance products. The methodology, data collection, processing, and estimation accuracy are presented and discussed.

  10. Mining, ore preparation and niobium alloys production at Araxa, Brazil

    International Nuclear Information System (INIS)

    Paraiso, O.S.; Fuccio Junior, R. de; Betz, E.W.

    1984-01-01

    A detailed description of the worlds major niobium producer is presented covering mining, concentration by froth flotation, leaching, and production of ferro-alloys. The present exploration of the Araxa deposit, its ore preparation and production of ferro-niobium is described. (E.G.) [pt

  11. Processing of Niobium-Lined M240 Machine Gun Barrels

    Science.gov (United States)

    2014-11-01

    Fig. 5 Finished niobium-lined M240 machine gun barrel with flash suppressor attached ..........11 Fig. 6 End of barrel 1 showing small amount of...the finished barrel is shown in Fig. 5. 11 Fig. 5 Finished niobium-lined M240 machine gun barrel with flash suppressor attached Firing tests

  12. Tunneling study of SRF cavity-grade niobium

    International Nuclear Information System (INIS)

    Proslier, T.; Zasadzinski, J.; Cooley, L.; Pellin, M.; Norem, J.; Elam, J.; Antonine, C. Z.; Rimmer, R.; Kneisel, P.

    2009-01-01

    Niobium, with its very high H C1 , has been used in superconducting radio frequency (SRF) cavities for accelerator systems for 40 years with continual improvement. The quality factor of cavities (Q) is governed by the surface impedance R BCS , which depends on the quasiparticle gap, delta, and the superfluid density. Both of these parameters are seriously affected by surface imperfections (metallic phases, dissolved oxygen, magnetic impurities). Loss mechanism and surface treatments of Nb cavities found to improve the Q factor are still unsolved mysteries. We present here an overview of the capabilities of the point contact tunneling spectroscopy and Atomic layer deposition methods and how they can help understanding the High field Q-drop and the mild baking effect. Tunneling spectroscopy was performed on Nb pieces from the same processed material used to fabricate SRF cavities. Air exposed, electropolished Nb exhibited a surface superconducting gap Delta = 1.55 meV, characteristic of clean, bulk Nb, however the tunneling density of states (DOS) was broadened significantly. Nb pieces treated with the same mild baking used to improve the Q-slope in SRF cavities revealed a much sharper DOS. Good fits to the DOS are obtained using Shiba theory suggesting that magnetic scattering of quasiparticles is the origin of the degraded surface superconductivity and the Q-slope problem of Nb SRF cavities

  13. Direct atomic absorption determination of silicon in metallic niobium

    International Nuclear Information System (INIS)

    Blinova, Eh.S.; Guzeev, I.D.; Nedler, V.V.; Khokhrin, V.M.

    1984-01-01

    Consideration is being given to realization of the basic advantage of non-flame atomizer-analysis of directly solid samples-for silicon determination in niobium for the content of the first one of less than 1x10 -3 mass %. Analysis technique is described. Diagrams of the dependences of atomic silicon absorption in graphite cells of usual type as well as lined by tungsten carbide and atomic silicon absorption on the value of niobium weighed amount are presented. It is shown that Si determination in metallic niobium according to aqueous reference solutions results in understatement of results 2.4 times. The optimal conditions for Si determination in niobium are the following: 2400 deg C temperature, absence of carbon and oxygen. Different niobium specimens with the known silicon content were used as reference samples

  14. Superconducting structure with layers of niobium nitride and aluminum nitride

    International Nuclear Information System (INIS)

    Murduck, J.M.; Lepetre, Y.J.; Schuller, I.K.; Ketterson, J.B.

    1989-01-01

    A superconducting structure is formed by depositing alternate layers of aluminum nitride and niobium nitride on a substrate. Deposition methods include dc magnetron reactive sputtering, rf magnetron reactive sputtering, thin-film diffusion, chemical vapor deposition, and ion-beam deposition. Structures have been built with layers of niobium nitride and aluminum nitride having thicknesses in a range of 20 to 350 Angstroms. Best results have been achieved with films of niobium nitride deposited to a thickness of approximately 70 Angstroms and aluminum nitride deposited to a thickness of approximately 20 Angstroms. Such films of niobium nitride separated by a single layer of aluminum nitride are useful in forming Josephson junctions. Structures of 30 or more alternating layers of niobium nitride and aluminum nitride are useful when deposited on fixed substrates or flexible strips to form bulk superconductors for carrying electric current. They are also adaptable as voltage-controlled microwave energy sources. 8 figs

  15. Self-diffusion dynamics processes relevant to 2D homoepitaxy growth of Ni adatom on Ni(111) surface

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Fusheng [College of Metallurgical Engineering, Hunan University of Technology, Zhuzhou 412007 (China); Chen, Yifeng, E-mail: yefengc63@sina.com [College of Metallurgical Engineering, Hunan University of Technology, Zhuzhou 412007 (China); Wang, Yufei, E-mail: yejin802@126.com [College of Metallurgical Engineering, Hunan University of Technology, Zhuzhou 412007 (China); Liu, Zhulin; Hu, Zhongliang [College of Metallurgical Engineering, Hunan University of Technology, Zhuzhou 412007 (China); Yang, Xiyuan [Department of Physics, Hunan University of Arts and Science, Changde 415000 (China); Luo, Wenhua [Department of Physics and Electronic Information Science, Hunan Institute of Science and Technology, Yueyang 414006 (China)

    2014-07-01

    Using molecular dynamics and modified analytic embedded atom methods, the atomic self-diffusion dynamics behaviors relevant to 2D crystal growth on Ni(111) surface have been studied between 150 and 600 K. On perfect Ni(111) surface, the activation energy and prefactor are 0.058±0.001 eV and 4.2×10{sup −4} cm{sup 2}/s between 150 and 350 K, and 0.082±0.003 eV and 7.8×10{sup −4} cm{sup 2}/s from 400 to 600 K. Ni adatom just hops along the directions of close-packed steps on stepped Ni(111) surface, the corresponding activation energies and prefactors are 0.188±0.002 eV and (3.8–4.4)×10{sup −3} cm{sup 2}/s along the direction of A-type step, 0.140±0.001 eV and (1.1–1.2)×10{sup −3} cm{sup 2}/s along the direction of B-type step, and both fitting lines of Arrhenius law intersect at T{sub c}=420–440 K. Our results show that the atomic growth dynamics under nonequilibrium conditions is gradually dominated by the prefactor with increasing temperature. In addition, the shape-change of the 2D nanometer-size island has been discussed on stepped Ni(111) surface in different temperature range.

  16. Fast fluence measurement for JOYO irradiation field using niobium dosimeter

    International Nuclear Information System (INIS)

    Ito, Chikara

    2004-03-01

    Neutron fluence and spectrum are key parameters in various irradiation tests and material surveillance tests so they need to be evaluated accurately. The reactor dosimetry test has been conducted by the multiple foil activation method, and a niobium dosimeter has been developed for measurement of fast neutron fluence in the experimental fast reactor JOYO. The inelastic scattering reaction of 93 Nb has a low threshold energy, about 30 keV, and the energy distribution of reaction cross section is similar to the displacement cross section for iron. Therefore, a niobium dosimeter is suitable for evaluation of the fast neutron fluence and the displacement per atom for iron. Moreover, a niobium dosimeter is suited to measure neutron fluence in long-term irradiation test because 93 Nb, which is produced by the reaction, has a long half-life (16.4 years). This study established a high precision measurement technique using the niobium reaction rate. The effect of self-absorption was decreased by the solution and evaporation to dryness of niobium dosimeter. The dosimeter weight was precisely measured using the inductively coupled plasma mass spectrometer. This technique was applied to JOYO dosimetry. The fast neutron fluences (E > 0.1 MeV) found by measuring the reaction rate in the niobium dosimeter were compared with the values evaluated using the multiple foil activation method. The ratio of measured fast neutron fluences by means of niobium dosimeter and multiple foil activation method range from 0.97 to 1.03 and agree within the experimental uncertainty. The measurement errors of fast neutron fluence by niobium dosimeter range from 4.5% (fuel region) to 10.1% (in-vessel storage rack). As a result of this study, the high precision measurement of fast neutron fluence by niobium dosimeters was confirmed. The accuracy of fast reactor dosimetry will be improved by application of niobium dosimeters to the irradiation tests in the JOYO MK-III core. (author)

  17. Electron heating by photon-assisted tunneling in niobium terahertz mixers with integrated niobium titanium nitride striplines

    NARCIS (Netherlands)

    Leone, B; Gao, [No Value; Klapwijk, TM; Jackson, BD; Laauwen, WM; de Lange, G

    2001-01-01

    We describe the gap voltage depression and current-voltage (I-V) characteristics in pumped niobium superconductor-insulator-superconductor junction with niobium titanium nitride tuning stripline by introducing an electron heating power contribution resulting from the photon-assisted tunneling

  18. A process for electrodeposition of layers of niobium, vanadium, molybdenum or tungsten, or of their alloys

    International Nuclear Information System (INIS)

    Diepers, H.; Schmidt, O.

    1977-01-01

    An improvement is proposed for the process for electrodeposition of layers of niobium, vanadium, molybdenum or tungsten or of their alloys from molten-salt electrolytes (fluorid melts) which is to increase the quality of layers in order to obtain regular thickness and smooth surfaces. According to the invention, a pre-separation is executed on an auxiliary cathode before the (preheated) cathode is immersed. The cathode is only charged for separation after the adjustment of a constant anode potential. It is an advantage that the auxiliary cathode is mechanically and electrically connected with the cathode. As an electrolyte, a mixture of niobium fluorides and a eustetic mixture of potassium fluorides, sodium fluorides and lithium fluorides are particularly suitable for the electrodeposition of miobium. (UWI) [de

  19. Electrochemical etching of a niobium foil in methanolic HF for electrolytic capacitor

    International Nuclear Information System (INIS)

    Kim, Kyungmin; Park, Jiyoung; Cha, Gihoon; Yoo, Jeong Eun; Choi, Jinsub

    2013-01-01

    Electrochemical etching of niobium foil in order to enlarge the surface area for the application in electrolytic capacitor was carried out in a methanolic electrolyte. We found that the pit density and depth are not linearly proportional to concentration of HF and applied potential: there is the optimal concentration of HF at each applied potential. The optimal etching condition was obtained at 50 V in 0.99 vol.% HF, which exhibited the capacitance of 350 μF cm −2 . Pit density and depth of pits on electrochemical etched Nb foil under different conditions were counted from SEM images and electrochemical impedance spectroscopy (EIS) of the etched Nb foils was carried out for the capacitance measurement. Equivalent circuit model showing less than 5% error was suggested for applying to the etched niobium foil. - Highlights: • Surface enlargement of Nb foil can be achieved by electrochemical etching in methanolic HF. • Electrolytic capacitor of etched niobium foil exhibits a capacitance of 350 μF cm −2 . • The method provides a way of developing commercially viable process

  20. Optical scattering characteristic of annealed niobium oxide films

    International Nuclear Information System (INIS)

    Lai Fachun; Li Ming; Wang Haiqian; Hu Hailong; Wang Xiaoping; Hou, J.G.; Song Yizhou; Jiang Yousong

    2005-01-01

    Niobium oxide (Nb 2 O 5 ) films with thicknesses ranging from 200 to 1600 nm were deposited on fused silica at room temperature by low frequency reactive magnetron sputtering system. In order to study the optical losses resulting from the microstructures, the films with 500 nm thickness were annealed at temperatures between 600 and 1100 deg. C, and films with thicknesses from 200 to 1600 nm were annealed at 800 deg. C. Scanning electron microscopy and atomic force microscopy images show that the root mean square of surface roughness, the grain size, voids, microcracks, and grain boundaries increase with increasing both the annealing temperature and the thickness. Correspondingly, the optical transmittance and reflectance decrease, and the optical loss increases. The mechanisms of the optical losses are discussed. The results suggest that defects in the volume and the surface roughness should be the major source for the optical losses of the annealed films by causing pronounced scattering. For samples with a determined thickness, there is a critical annealing temperature, above which the surface scattering contributes to the major optical losses. In the experimental scope, for the films annealed at temperatures below 900 deg. C, the major optical losses resulted from volume scattering. However, surface roughness was the major source for the optical losses when the 500-nm films were annealed at temperatures above 900 deg. C

  1. Evaluated nuclear-data file for niobium

    International Nuclear Information System (INIS)

    Smith, A.B.; Smith, D.L.; Howerton, R.J.

    1985-03-01

    A comprehensive evaluated nuclear-data file for elemental niobium is provided in the ENDF/B format. This file, extending over the energy range 10 -11 -20 MeV, is suitable for comprehensive neutronic calculations, particulary those dealing with fusion-energy systems. It also provides dosimetry information. Attention is given to the internal consistancy of the file, energy balance, and the quantitative specification of uncertainties. Comparisons are made with experimental data and previous evaluated files. The results of integral tests are described and remaining outstanding problem areas are cited. 107 refs

  2. Critical unpairing currents in narrow niobium films

    International Nuclear Information System (INIS)

    Gershenzon, M.E.; Gubankov, V.N.

    1979-01-01

    Investigated are the dependences of critical currents of narrow ( with the width of W=0.5-15 μm) superconducting niobium films on temperature and a magnetic field. The proposed method of film production with the width of the 1μm order and with small edge inhomogeneities ((<=500 A) permitted to realize the Ginsburg-Landau unpairing currents in the wide range of temperatures. The correct comparison with the theory showed that the unpairing currents are observed if W(< or approximately) 2delta, where delta is the effective depth of the penetration of the perpendicular magnetic field

  3. Germanium-overcoated niobium Dayem bridges

    International Nuclear Information System (INIS)

    Holdeman, L.B.; Peters, P.N.

    1976-01-01

    Overcoating constriction microbridges with semiconducting germanium provides additional thermal conductivity at liquid-helium temperatures to reduce the effects of self-heating in these Josephson junctions. Microwave-induced steps were observed in the I-V characteristics of an overcoated Dayem bridge fabricated in a 15-nm-thick niobium film; at 4.2 K (T/sub c/-T=2.6 K), at least 20 steps could be counted. No steps were observed in the I-V characteristics of the bridge prior to overcoating. In addition, the germanium overcoat can protect against electrical disturbances at room temperature

  4. Hydrogen in niobium-titanium alloys

    International Nuclear Information System (INIS)

    Silva, J.R.G. da; Cabral, F.A.O.; Florencio, O.

    1985-01-01

    High purity Nb-Ti polycrystalline alloys were doped with hydrogen in equilibrium with the gaseous atmosphere at a pressure of 80 torr. at different temperatures. The partial molar enthalpy and entropy of the hydrogen solution at high dilution, ΔH sup(-) 0 and ΔS sup(-) 0 , were calculated from the equilibrium solubility data. The ΔH sup(-) 0 values are compared with the electron screened proton model of metal-hydrogen solutions. The addition of titanium to niobium has the effect to increase the hydrogen solubility at a given equilibrium temperature. (Author) [pt

  5. Effect of niobium addition in support catalysts applied in satellite propulsion

    Energy Technology Data Exchange (ETDEWEB)

    Soares, M.S., E-mail: marciosteinmetz@hotmail.com.br [Space Research National Institute, Combustion & Propulsion Associated Laboratory (Brazil); University of São Paulo, Lorena Engineering School, Materials Engineering Dept. (Brazil); Barbosa, R.D. [Space Research National Institute, Combustion & Propulsion Associated Laboratory (Brazil); University of São Paulo, Lorena Engineering School, Chemical Engineering Dept. (Brazil); Cruz, G.M. da; Rodrigues, J.A.J. [Space Research National Institute, Combustion & Propulsion Associated Laboratory (Brazil); Ribeiro, S. [University of São Paulo, Lorena Engineering School, Materials Engineering Dept. (Brazil)

    2017-03-01

    Catalysts composed of iridium as the active phase dispersed in aluminum oxide (Ir/Al{sub 2}O{sub 3}) are used in propulsion systems that employ hydrazine as monopropellant in the control of satellite orbit and attitude. The aluminum oxide (Al{sub 2}O{sub 3}) utilized as support must present high values of specific surface area, pore volume, and crush strength. The niobium effect was evaluated in this work, in its oxide form (Nb{sub 2}O{sub 5}), by 3 different methods: with the employment of a NbCl{sub 5} precursor solution, by wet impregnation and dry impregnation of an alumina obtained from a mixture of gibbsite and boehmite and by physical mixing of gibbsite and hydrated niobium oxide, both autoclaved separately. Aluminum oxides were prepared in both cases containing Nb{sub 2}O{sub 5} contents of 10, 20, and 30% w/w. The acid impregnating NbCl{sub 5} solution in the wet impregnation method caused a strong attack to the Al{sub 2}O{sub 3} support, altering and compromising its initial structure and morphology. This process did not occur in the supports prepared by dry impregnation. However, results indicated that the use of this methodology with Nb{sub 2}O{sub 5} contents of 20% and 30%, caused an extensive coverage of the support by Nb{sub 2}O{sub 5}, modifying the nature and amount of alumina sites responsible for anchorage of the iridium precursor. In the case of supports prepared through physical mixture (Nb{sub 2}O{sub 5}-Al{sub 2}O{sub 3}) from aluminum hydroxide and niobium acid precursor compounds, with both being previously autoclaved separately, the 20% and 30% Nb{sub 2}O{sub 5} contents presented the most promising properties, since the binder effect caused by amorphous Nb{sub 2}O{sub 5} increased the crush strength of the support, without compromising the aluminum oxide morphology and texture. Despite of existence of stronger acid sites due to the addition of niobium oxide to aluminum oxide, no increase in the acidity of the materials was observed due

  6. Trends in Surface Level Ozone Observations from Human-health Relevant Metrics: Results from the Tropospheric Ozone Assessment Report (TOAR)

    Science.gov (United States)

    Fleming, Z. L.; von Schneidemesser, E.; Doherty, R. M.; Malley, C.; Cooper, O. R.; Pinto, J. P.; Colette, A.; Xu, X.; Simpson, D.; Schultz, M.; Hamad, S.; Moola, R.; Solberg, S.; Feng, Z.

    2017-12-01

    Ozone is an air pollutant formed in the atmosphere from precursor species (NOx, VOCs, CH4, CO) that is detrimental to human health and ecosystems. The global Tropospheric Ozone Assessment Report (TOAR) initiative has assembled a global database of surface ozone observations and generated ozone exposure metrics at thousands of measurement sites around the world. This talk will present results from the assessment focused on those indicators most relevant to human health. Specifically, the trends in ozone, comparing different time periods and patterns across regions and among metrics will be addressed. In addition, the fraction of population exposed to high ozone levels and how this has changed between 2000 and 2014 will also be discussed. The core time period analyzed for trends was 2000-2014, selected to include a greater number of sites in East Asia. Negative trends were most commonly observed at many US and some European sites, whereas many sites in East Asia showed positive trends, while sites in Japan showed more of a mix of positive and negative trends. More than half of the sites showed a common direction and significance in the trends for all five human-health relevant metrics. The peak ozone metrics indicate a reduction in exposure to peak levels of ozone related to photochemical episodes in Europe and the US. A considerable number of European countries and states within the US have shown a decrease in population-weighted ozone over time. The 2000-2014 results will be augmented and compared to the trend analysis for additional time periods that cover a greater number of years, but by necessity are based on fewer sites. Trends are found to be statistically significant at a larger fraction of sites with longer time series, compared to the shorter (2000-2014) time series.

  7. Low carbon manganese-nickel-niobium steel

    International Nuclear Information System (INIS)

    Heisterkamp, F.; Hulka, K.

    1983-11-01

    Experimental heats of a low carbon-manganese-0.5% nickel-0.15% niobium steel have been rolled to plates between 13.5 and 50 mm thickness and to a 16 mm hot strip. Various combinations of soaking temperatures form 1100 0 C to 1300 0 C and of finish rolling temperatures between 710 0 C and 930 0 C have been investigated. From mechanical properties obtained, one can conclude that the investigated steel composition provides very good properties e.g. for pipe steels X65 to X75. In particular, the toughness at low temperature is outstanding despite relaxed rolling conditions. Metalographic and special investigations such as electron microscopy, texture evaluation and chemical extraction, correlated with applied rolling schedules and the mechanical properties obtained resulted in a comprehensive understanding about the benefits of high niobium metallurgy combined with nickel addition. All practically applied welding processes generated mechanical properties, in particular toughness of the weldment, that meet arctic specifications.(Author) [pt

  8. Advance in Vertical Buffered Electropolishing on Niobium for Particle Accelerators

    International Nuclear Information System (INIS)

    Wu, A.T.; Jin, S.; Mammosser, J.D.; Reece, C.E.; Rimmer, R.A.; Lin, L.; Lu, X.Y.; Zhao, K.

    2011-01-01

    Niobium (Nb) is the most popular material that has been employed for making superconducting radio frequency (SRF) cavities to be used in various particle accelerators over the last couple of decades. One of the most important steps in fabricating Nb SRF cavities is the final chemical removal of 150 μm of Nb from the inner surfaces of the SRF cavities. This is usually done by either buffered chemical polishing (BCP) or electropolishing (EP). Recently a new Nb surface treatment technique called buffered electropolishing (BEP) has been developed at Jefferson Lab. It has been demonstrated that BEP can produce the smoothest surface finish on Nb ever reported in the literature while realizing a Nb removal rate as high as 10 μm/min that is more than 25 and 5 times quicker than those of EP and BCP(112) respectively. In this contribution, recent advance in optimizing and understanding BEP treatment technique is reviewed. Latest results from RF measurements on BEP treated Nb single cell cavities by our unique vertical polishing system will be reported.

  9. Aspects of chlorination and its potential to produce niobium pentoxide

    International Nuclear Information System (INIS)

    Brocchi, E.A.; Jeffes, J.H.E.

    1984-01-01

    Reduction chlorination of niobium pentoxide were carried out under different experimental conditions in order to study the effects of some variables of the process. In order to evaluate the efficiency of the recovery of niobium pentoxide which could be obtained as condensed material a group of experiments were also carried out with pyrochlore concentrate. The results showed that a balance of factors such as temperature, percentage of carbon in the initial charge and porosity cause the progress of the reaction to be controlled by different mechanisms and indicate that chlorination can be used to produce niobium pentoxide-especially if applied on rich starting material. (Author) [pt

  10. Effect of plastic deformation on the niobium thermal expansion

    International Nuclear Information System (INIS)

    Savitskij, E.M.; Bychkova, M.I.; Kanikovskij, V.B.

    1978-01-01

    Using dilatometric method the effect of plastic deformation on change of thermal expansion coefficient (TEC) of niobium of different purity was studied. It was shown that deformation affected the TEC in different ways. At first the deformation degree rising causes linear decrease of the TEC and then linear increase. Carbon intensifies the TEC decrease of deformed niobium. The linear correlation was established between the TEC and the value of macroscopic stresses in plastic deformed niobium. The expression indicating the metal TEC change under loading was defined for case of strain hardening

  11. Thermodynamic Calculation of Carbide Precipitate in Niobium Microalloyed Steels

    Institute of Scientific and Technical Information of China (English)

    XU Yun-bo; YU Yong-mei; LIU Xiang-hua; WANG Guo-dong

    2006-01-01

    On the basis of regular solution sublattice model, thermodynamic equilibrium of austenite/carbide in Fe-Nb-C ternary system was investigated. The equilibrium volume fraction, chemical driving force of carbide precipitates and molar fraction of niobium and carbon in solution at different temperatures were evaluated respectively. The volume fraction of precipitates increases, molar fraction of niobium dissolved in austenite decreases and molar fraction of carbon increases with decreasing the niobium content. The driving force increases with the decrease of temperature, and then comes to be stable at relatively low temperatures. The predicted ratio of carbon in precipitates is in good agreement with the measured one.

  12. Critical fields of niobium nitride films of various granularity

    International Nuclear Information System (INIS)

    Antonova, E.A.; Sukhov, V.A.

    1983-01-01

    The behaviour of lattice parameter, specific electrical resistivity, critical temperature, and temperature dependence of upper critical field near Tsub(cr) of sputtered niobium nitride films is investigated versus the substrate temperature and gas mixture composition in the process of reactive cathode sputtering. The relation between extrapolated value of the upper critical field and granularity of niobium nitride films, close as to composition to the stoichiometric one, has been found. Values of the kappa parameter of the Ginsburg-Landau theory and of the coherence length for niobium nitride films of various granularity are estimated in an approximation of uniform distribution of impurities in a sample

  13. Unprecedented quality factors at accelerating gradients up to 45 MVm -1 in niobium superconducting resonators via low temperature nitrogen infusion

    Energy Technology Data Exchange (ETDEWEB)

    Grassellino, A.; Romanenko, A.; Trenikhina, Y.; Checchin, M.; Martinello, M.; Melnychuk, O. S.; Chandrasekaran, S.; Sergatskov, D. A.; Posen, S.; Crawford, A. C.; Aderhold, S.; Bice, D.

    2017-08-14

    We report the finding of new surface treatments that permit to manipulate the niobium resonator nitrogen content in the first few nanometers in a controlled way, and the resonator fundamental Mattis-Bardeen surface resistance and residual resistance accordingly. In particular, we find surface infusion conditions that systematically a) increase the quality factor of these 1.3 GHz superconducting radio frequency (SRF) bulk niobium resonators, up to very high gradients; b) increase the achievable accelerating gradient of the cavity compared to its own baseline with state-of-the-art surface processing. Cavities subject to the new surface process have larger than two times the state of the art Q at 2K for accelerating fields > 35 MV/m. Moreover, very high accelerating gradients ~ 45 MV/m are repeatedly reached, which correspond to peak magnetic surface fields of 190 mT, among the highest measured for bulk niobium cavities. These findings open the opportunity to tailor the surface impurity content distribution to maximize performance in Q and gradients, and have therefore very important implications on future performance and cost of SRF based accelerators. They also help deepen the understanding of the physics of the RF niobium cavity surface.

  14. Crystallography and Morphology of Niobium Carbide in As-Cast HP-Niobium Reformer Tubes

    Science.gov (United States)

    Buchanan, Karl G.; Kral, Milo V.

    2012-06-01

    The microstructures of two as-cast heats of niobium-modified HP stainless steels were characterized. Particular attention was paid to the interdendritic niobium-rich carbides formed during solidification of these alloys. At low magnifications, these precipitates are grouped in colonies of similar lamellae. Higher magnifications revealed that the lamellae actually obtain two distinct morphologies. The type I morphology exhibits broad planar interfaces with a smooth platelike shape. Type II lamellae have undulating interfaces and an overall reticulated shape. To provide further insight into the origin of these two different morphologies, the microstructure and crystallography of each have been studied in detail using high resolution scanning electron microscopy, transmission electron microscopy, various electron diffraction methods (electron backscatter diffraction (EBSD), selected area diffraction (SAD), and convergent beam electron diffraction (CBED)), and energy dispersive X-ray spectroscopy.

  15. Relevant insight of surface characterization techniques to study covalent grafting of a biopolymer to titanium implant and its acidic resistance

    Science.gov (United States)

    D'Almeida, Mélanie; Amalric, Julien; Brunon, Céline; Grosgogeat, Brigitte; Toury, Bérangère

    2015-02-01

    Peri-implant bacterial infections are the main cause of complications in dentistry. Our group has previously proposed the attachment of chitosan on titanium implants via a covalent bond to improve its antibacterial properties while maintaining its biocompatibility. A better knowledge of the coating preparation process allows a better understanding of the bioactive coating in biological conditions. In this work, several relevant characterization techniques were used to assess an implant device during its production phase and its resistance in natural media at different pH. The titanium surface was functionalized with 3-aminopropyltriethoxysilane (APTES) followed by grafting of an organic coupling agent; succinic anhydride, able to form two covalent links, with the substrate through a Ti-O-Si bond and the biopolymer through a peptide bond. Each step of the coating synthesis as well as the presence confirmation of the biopolymer on titanium after saliva immersion was followed by FTIR-ATR, SEM, EDS, 3D profilometry, XPS and ToF-SIMS analyses. Results allowed to highlight the efficiency of each step of the process, and to propose a mechanism occurring during the chitosan coating degradation in saliva media at pH 5 and at pH 3.

  16. Niobium(V) chloride as catalyst in Diels-Alder reaction of furan ring

    International Nuclear Information System (INIS)

    Santos, Deborah A. dos; Rodrigues, Ludmila R.; Arpini, Bruno H.; Lacerda Junior, Valdemar; Greco, Sandro J.; Santos, Reginaldo B. dos; Neto, Alvaro C.; Castro, Eustaquio V.R. de

    2014-01-01

    According to the relevant literature, the Diels-Alder reaction of furan without a catalyst can last several weeks and shows a low yield due to the diene’s low reactivity. The use of Lewis acid catalysts or high pressures is described as an effective method for improving the reaction yields. This paper describes our recent study on the use of niobium pentachloride as the catalyst in Diels-Alder reactions between furan and several reactive dienophiles, among which methyl acrylate showed good yields, especially at lower temperatures. Other dienophiles have shown lower yields because of problems such as byproduct formation and the high reversibility of the reaction. (author)

  17. Niobium(V) chloride as catalyst in Diels-Alder reaction of furan ring

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Deborah A. dos; Rodrigues, Ludmila R.; Arpini, Bruno H.; Lacerda Junior, Valdemar; Greco, Sandro J.; Santos, Reginaldo B. dos; Neto, Alvaro C.; Castro, Eustaquio V.R. de, E-mail: vljuniorqui@gmail.com [Universidade Federal do Espirito Santo (UFES), Vitoria, ES (Brazil). Dept. de Quimica; Romao, Wanderson [Instituto Federal de Educacao, Ciencia e Tecnologia (IFES), Vila Velha, ES (Brazil)

    2014-05-15

    According to the relevant literature, the Diels-Alder reaction of furan without a catalyst can last several weeks and shows a low yield due to the diene’s low reactivity. The use of Lewis acid catalysts or high pressures is described as an effective method for improving the reaction yields. This paper describes our recent study on the use of niobium pentachloride as the catalyst in Diels-Alder reactions between furan and several reactive dienophiles, among which methyl acrylate showed good yields, especially at lower temperatures. Other dienophiles have shown lower yields because of problems such as byproduct formation and the high reversibility of the reaction. (author)

  18. A SRF niobium cylindrical cavity with a large silicon nitride niobium-coated membrane as one end-wall

    Science.gov (United States)

    Martinez, Luis; Castelli, Alessandro; Pate, Jacob; Thompson, Johnathon; Delmas, William; Sharping, Jay; Chiao, Raymond; Chiao Team; Sharping Team

    The development of large silicon nitride membranes and niobium film deposition techniques motivate new architectures in opto-mechanics and microwave devices that can exploit the extremely high Q's obtainable with superconducting radio frequency (SRF) niobium cavities. We present a X-band SRF cylindrical cavity-membrane system in which one end-wall of the cavity is replaced by a niobium coated centimeter-sized silicon nitride membrane. We report moderately high Q factors above 10 million. Experimental results characterizing the system and potential future applications for such schemes in microwave devices and optomechanics are discussed.

  19. An improved oxygen diffusion model to explain the effect of low-temperature baking on high field losses in niobium superconducting cavities

    Energy Technology Data Exchange (ETDEWEB)

    Ciovati, Gianluigi

    2006-07-01

    Radio-frequency (RF) superconducting cavities made of high purity niobium are widely used to accelerate charged particle beams in particle accelerators. The major limitation to achieve RF field values approaching the theoretical limit for niobium is represented by ''anomalous'' losses which degrade the quality factor of the cavities starting at peak surface magnetic fields of about 100 mT, in absence of field emission. These high field losses are often referred to as ''Q-drop''. It has been observed that the Q-drop is drastically reduced by baking the cavities at 120 C for about 48 h under ultrahigh vacuum. An improved oxygen diffusion model for the niobium-oxide system is proposed to explain the benefit of the low-temperature baking on the Q-drop in niobium superconducting rf cavities. The model shows that baking at 120 C for 48 h allows oxygen to diffuse away from the surface, and therefore increasing the lower critical field towards the value for pure niobium.

  20. Study of low energy thermal constraints for a copper-plated niobium structure carried out by thermal projection

    International Nuclear Information System (INIS)

    Gassot, H.; Durante, M.; Thiebault, A.; Vernay, E.

    1999-06-01

    In the framework of T.T.F. (Tesla Test Facility), the international collaboration on research and development of superconducting cavities, a study of a new method of manufacturing cavities was launched, which consists in deposing a metal (copper) or an alloy by thermal projection on niobium cavities in order to stiffen them. Analytical and numerical calculations showed that when cooled this bi-material cavities behave very differently in comparison with classical pure niobium cavities and strong thermal constraints do occur in niobium as well as in copper. These strong constraints may have important consequences upon the functioning of superconducting cavities. In addition these constraints may induce in time cracks in materials and interfaces. In this paper an experiment for measuring constraints at the temperature of cavity operation, i.e., at the liquid helium temperature, is proposed in order to compare the measured constraints with the calculated constraints. The sample studied has a cylindrical shape, rather representative for the geometrical shape of cavities, but easier to handle than a prototype cavity. The experimental approach consists in carrying out two deformation measurements. The first one, is done on single material sample (niobium and copper) to establish the laws of compensation of the constraint gauges as a function of temperature. The other measurement establishes the global deformations of a bi-metallic tube (Nb-Cu) when the interior surface (niobium) and the external surface (porous copper) of the tube are cooled. From these deformation data the thermal constraints of the bi-metallic tube at low temperature have been derived. The implementation of the entire setup of the methods of measuring the constraints at low temperature constitutes a new development in the field of superconducting cavities. The experiments have also indicated certain further developments which should be achieved if the plastic deformations induced by the freezing regime

  1. Plane strain forging of a niobium micro-alloyed steel

    International Nuclear Information System (INIS)

    Balancin, O.; Ferran L, G.; Rio de Janeiro Univ.

    1984-01-01

    Various termomechanical treatments were carried out on a niobium micro-alloyed steel and a low carbon steel as reference material, using an apparatus for hot phane strain forging. Control of processing variables and the presence of niobium strongly modify the austenite microstructure, which upon decomposition produces various phases such as polygonal and acicular ferrite and martensite, alone or together in variable proportions. Corresponding to this diversity of structures there is a wide variation in mechanical properties at room temperature: the initial yield point varies from 310 to 650 MPa and the reduction of area in uniaxial tension from 82 to 57% for the niobium steel. These results show that hot forging a niobium micro-alloyed steel may be a suitable manufacturing process for satisfying a wide range of specifications in a final product with low equivalent carbon. (Author) [pt

  2. An investigation of tantalum and niobium contents by nuclear technique

    International Nuclear Information System (INIS)

    Patmasiriwat, N.

    1981-01-01

    The objective of this experimental study was to find suitable nuclear techniques to determine the quantities of niobium and tantalum in columbite. The study has been performed by using radioisotope X-ray fluorescent technique (X RF) and neutron activation analysis (NAA). The results showed a good agreement between these two techniques. Nevertheless, with NAA, if there is uranium in the sample, the spectrum of niobium will be interfered. So practically, on the basis of accuracy and speed of determination, X-ray fluorescence is more suitable than NAA to determine the quantity of niobium while tantalum is preferable to use NAA. The detection limit of niobium and tantalum using the above techniques are 0.661% and 0.1 mg respectively

  3. Reactivity of niobium cluster anions with nitrogen and carbon monoxide

    Science.gov (United States)

    Mwakapumba, Joseph; Ervin, Kent M.

    1997-02-01

    Reactions of small niobium cluster anions, Nbn-(n = 2-7), with CO and N2 are investigated using a flow tube reactor (flowing afterglow) apparatus. Carbon monoxide chemisorption on niobium cluster anions occurs with faster reaction rates than nitrogen chemisorption on corresponding cluster sizes. N2 addition to niobium cluster anions is much more size-selective than is CO addition. These general trends follow those reported in the literature for reactions of neutral and cationic niobium clusters with CO and N2. Extensive fragmentation of the clusters is observed upon chemisorption. A small fraction of the larger clusters survive and sequentially add multiple CO or N2 units without fragmentation. However, chemisorption saturation is not reached at the experimentally accessible pressure and reagent concentration ranges. The thermochemistry of the adsorption processes and the nature of the adsorbed species, molecular or dissociated, are discussed.

  4. Diffusion of hydrogen, deuterium, and tritium in niobium

    International Nuclear Information System (INIS)

    Matusiewicz, G.R.

    1981-01-01

    The diffusion of hydrogen in niobium was investigated over the temperature range 148 to 500 degrees Kelvin, using measurements of the elastic after effect caused by long range diffusion (the Gorsky Effect). Relaxation curves for pure annealed niobium were generally not of the single exponential form expected from the Gorsky Effect theory, but were described well by a sum of two exponential curves with different amplitudes and relaxation times. The effects of oxygen and nitrogen interstitials on the diffusion were studied and were not in agreement with conventional trapping models. Deuterium and tritium diffusion in niobium were also studied, and a non-classical isotope effect was observed. Hydrogen diffusion coefficients in several Nb-Ta alloys were measured, and the diffusivity in all these alloys exhibited a non-Arrhenius temperature dependence. Experimental results were compared to several models for diffusion and trapping. A model is presented which can account for the form of the relaxation curves observed in pure, annealed niobium

  5. Alternative dissolution methods for analysis of niobium containing ...

    African Journals Online (AJOL)

    NICO

    2The South African Nuclear Energy Corporation Ltd. (Necsa), P.O. Box 582, Pretoria 0001, South Africa. ... Inductively coupled plasma optical emission spectrometry was applied for ..... Validation of the methods for niobium determination was.

  6. Electroplating and stripping copper on molybdenum and niobium

    Science.gov (United States)

    Power, J. L.

    1978-01-01

    Molybdenum and niobium are often electroplated and subsequently stripped of copper. Since general standard plating techniques produce poor quality coatings, general procedures have been optimized and specified to give good results.

  7. Fabrication of ultrashort niobium variable-thickness bridges

    International Nuclear Information System (INIS)

    Goto, T.

    1982-01-01

    A simple technique for the fabrication of niobium variable-thickness bridges of length approx.0.1 μm is described. The bridges are found to operate as ideal Josephson junctions over a wide temperature range

  8. Progress in the development of niobium alloyed high speed steel

    International Nuclear Information System (INIS)

    Guimaraes, J.R.C.

    1987-01-01

    The development of economy-grades of niobium alloyed high speed steel is described. Both the metallurgical concepts behind the steel design and the results of performance tests are presented. (Author) [pt

  9. Neutron data evaluation for natural niobium

    International Nuclear Information System (INIS)

    Ma Gonggui; Zou Yiming; Wang Shiming

    1992-01-01

    The complete neutron nuclear data for natural niobium were evaluated based on both experimental data measured up to 1989 and calculated data with program MUP2 and AUJP. The present work was done for CENDL-2 and supersedes the CENDL-1 (MAT = 1411) evaluation. The following neutron data are given for Nb in the energy range 10 -5 eV to 20 MeV (MAT = 2411): total, elastic, nonelastic, total inelastic, inelastic cross sections to 13 discrete levels, inelastic continuum, (n,2n), (n,3n), (n,n'α) + (n,αn'), (n,n'p) + (n,pn'),(n,n'd) + (n,dn'), (n,p), (n,d), (n,t), (n,α) and capture cross sections. Derived data for MT = 251, 252 and 253 are also included. Angular distributions and energy spectra of secondary neutron are also given inelastic continuum,

  10. Bragg projection ptychography on niobium phase domains

    Science.gov (United States)

    Burdet, Nicolas; Shi, Xiaowen; Clark, Jesse N.; Huang, Xiaojing; Harder, Ross; Robinson, Ian

    2017-07-01

    Bragg projection ptychography (BPP) is a coherent x-ray diffraction imaging technique which combines the strengths of scanning microscopy with the phase contrast of x-ray ptychography. Here we apply it for high resolution imaging of the phase-shifted crystalline domains associated with epitaxial growth. The advantages of BPP are that the spatial extent of the sample is arbitrary, it is nondestructive, and it gives potentially diffraction limited spatial resolution. Here we demonstrate the application of BPP for revealing the domain structure caused by epitaxial misfit in a nanostructured metallic thin film. Experimental coherent diffraction data were collected from a niobium thin film, epitaxially grown on a sapphire substrate as the beam was scanned across the sample. The data were analyzed by BPP using a carefully selected combination of refinement procedures. The resulting image shows a close packed array of epitaxial domains, shifted with respect to each other due to misfit between the film and its substrate.

  11. Developments in niobium steels for linepipe applications

    International Nuclear Information System (INIS)

    Heisterkamp, F.; Bergmann, B.; Chaussy, L.

    1982-11-01

    Current niobium containing steels being produced for line pipe applications, developed over the last ten years, demonstrate an excellent respoNse to heavy deformation at low temperatures, which results in an optimum balance of yield strength and toughness. However, it has long been recognized that excessive use of controlled rolling involves production penalties and contributes to the characteristic anisotropy present in rolled products. Thus, changes in rolling procedures would be desirable if they minimized delays or reduced directionality thereby resulting in further improvement of secondary properties, such as through thickness ductility and hydrogen induced cracking (HIC) tendency in sour gas environments. Present steel development is focused on transformation strengthening or increased precipitation hardening. Coupled with the trend to even lower carbon ( [pt

  12. Study on niobium carbide dispersed superconducting tapes

    Energy Technology Data Exchange (ETDEWEB)

    Wada, H; Tachikawa, K [National Research Inst. for Metals, Tokyo (Japan); Oh' asa, M [Science Univ. of Tokyo (Japan)

    1977-11-01

    Niobium carbide (NbC) dispersed superconducting tapes have been fabricated by two metallurgical processes. In the first process, Ni-Nb-C alloys are directly arc melted and hot worked in air and the NbC phase is distributed in the form of fine discrete particles. In the second process, Ni-Nb and Ni-Nb-Cu alloys are arc melted, hot worked and subjected to solid-state carburization. NbC then precipitates along the grain boundaries, forming a network. The highest superconducting transition temperature attained is about 11 K. Taken together with the lattice parameter measurement, this indicates that NbC with a nearly perfect NaCl structure is formed in both processes. Measured values of the upper critical field, the critical current density and the volume fraction of the NbC phase are also discussed.

  13. Thorium exposure in a niobium mine

    International Nuclear Information System (INIS)

    Fonseca, Adelaide M. Gondin da

    1995-01-01

    The workers involved in the mineral process to obtain Nb-Fe alloy are exposure to thorium. Internal contamination with radioactive materials is a common problem. This is caused by presence of U and Th and their natural decay series associated with the mine ore. The examples are the workers at the niobium mine located in the state of Goias. Twenty mine workers were evaluated using in vitro bioassay techniques. Samples of urine and feces from occupationally exposed mine workers were analyzed for thorium isotopes. The fecal samples corresponding to one complete excretion and urine sample corresponding to a 24 hours collection were analyzed using alpha spectrometry. The results of thorium excretion (feces) have shown that in all the samples the 228 Th excretions in high than 232 Th. Thorium concentration in all the urine samples were below limit of detection that is approximately 1 mBq/l. (author). 3 refs., 1 fig., 1 tab

  14. Mechanical properties of soldered joints of niobium base alloys

    International Nuclear Information System (INIS)

    Grishin, V.L.

    1980-01-01

    Mechanical properties of soldered joints of niobium alloys widely distributed in industry: VN3, VN4, VN5A, VN5AE, VN5AEP etc., 0.6-1.2 mm thick are investigated. It is found out that the usage of zirconium-vanadium, titanium-tantalum solders for welding niobium base alloys permits to obtain soldered joints with satisfactory mechanical properties at elevated temperatures

  15. Electrodeposition of niobium and titanium in molten salts

    International Nuclear Information System (INIS)

    Sartori, A.F.; Chagas, H.C.

    1988-01-01

    The electrodeposition of niobium and titanium in molten fluorides from the additions of fluorine niobates and fluorine titanates of potassium is described in laboratory and pilot scale. The temperature influence, the current density and the time deposition over the current efficiency, the deposits structure and the deposits purity are studied. The conditions for niobium coating over copper and carbon steel and for titanium coating over carbon steel are also presented. (C.G.C.) [pt

  16. Photochemical transformation of benzotriazole, relevant to sunlit surface waters: Assessing the possible role of triplet-sensitised processes

    Energy Technology Data Exchange (ETDEWEB)

    Bianco, Angelica [Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, F-63000 Clermont-Ferrand (France); Fabbri, Debora; Minella, Marco [Università degli Studi di Torino, Dipartimento di Chimica, Via P. Giuria 5, 10125 Turin (Italy); Brigante, Marcello, E-mail: marcello.brigante@univ-bpclermont.fr [Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, F-63000 Clermont-Ferrand (France); CNRS, UMR 6296, ICCF, BP 80026, F-63177 Aubière (France); Mailhot, Gilles [Clermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, F-63000 Clermont-Ferrand (France); CNRS, UMR 6296, ICCF, BP 80026, F-63177 Aubière (France); Maurino, Valter; Minero, Claudio [Università degli Studi di Torino, Dipartimento di Chimica, Via P. Giuria 5, 10125 Turin (Italy); Vione, Davide, E-mail: davide.vione@unito.it [Università degli Studi di Torino, Dipartimento di Chimica, Via P. Giuria 5, 10125 Turin (Italy); Università degli Studi di Torino, Centro Interdipartimentale NatRisk, Via L. Da Vinci 44, 10095 Grugliasco (Italy)

    2016-10-01

    The corrosion inhibitor 1H-benzotriazole (pK{sub a} = 8.4) can exist in two different forms in natural waters, and photochemical transformation is a potentially significant attenuation pathway for both of them. Depending on conditions, the modelled half-life times range from some days/weeks to several months. In sunlit water bodies, the acidic (neutral) form would undergo direct photolysis (accounting for up to 7% of total phototransformation) and, most notably, reaction with the hydroxyl radicals ({sup ·}OH) and the triplet states of chromophoric dissolved organic matter ({sup 3}CDOM*). The basic (anionic) form would undergo significant transformation with {sup ·}OH and {sup 3}CDOM*. The {sup ·}OH reactions would be more important at low dissolved organic carbon (DOC) and the {sup 3}CDOM* processes at high DOC. In the presence of highly reactive triplet-state model compounds, the two benzotriazole forms react with similar rate constants. In this case, they would show comparable half-life times in surface-water environments. With less reactive triplet states, the rate constant of the anionic form can be a couple of orders of magnitude higher than that of the neutral one. Under these circumstances, the neutral form could be considerably more photostable than the anionic one at high DOC. Therefore, depending on {sup 3}CDOM* reactivity, the solution pH may or may not play an important role in the photoattenuation kinetics of 1H-benzotriazole in sunlit natural waters, especially at high DOC. Both forms of benzotriazole yield hydroxyderivatives as their main transformation intermediates under all the relevant photochemical reaction pathways. These intermediates could be formed via {sup ·}OH-induced hydroxylation, or upon electron abstraction followed by reaction with water. Differently from UVC irradiation data reported in previous studies, the concentration of aniline upon excitation of 1H-benzotriazole under environmentally significant UV wavelengths was always

  17. Photochemical transformation of benzotriazole, relevant to sunlit surface waters: Assessing the possible role of triplet-sensitised processes

    International Nuclear Information System (INIS)

    Bianco, Angelica; Fabbri, Debora; Minella, Marco; Brigante, Marcello; Mailhot, Gilles; Maurino, Valter; Minero, Claudio; Vione, Davide

    2016-01-01

    The corrosion inhibitor 1H-benzotriazole (pK a = 8.4) can exist in two different forms in natural waters, and photochemical transformation is a potentially significant attenuation pathway for both of them. Depending on conditions, the modelled half-life times range from some days/weeks to several months. In sunlit water bodies, the acidic (neutral) form would undergo direct photolysis (accounting for up to 7% of total phototransformation) and, most notably, reaction with the hydroxyl radicals ( · OH) and the triplet states of chromophoric dissolved organic matter ( 3 CDOM*). The basic (anionic) form would undergo significant transformation with · OH and 3 CDOM*. The · OH reactions would be more important at low dissolved organic carbon (DOC) and the 3 CDOM* processes at high DOC. In the presence of highly reactive triplet-state model compounds, the two benzotriazole forms react with similar rate constants. In this case, they would show comparable half-life times in surface-water environments. With less reactive triplet states, the rate constant of the anionic form can be a couple of orders of magnitude higher than that of the neutral one. Under these circumstances, the neutral form could be considerably more photostable than the anionic one at high DOC. Therefore, depending on 3 CDOM* reactivity, the solution pH may or may not play an important role in the photoattenuation kinetics of 1H-benzotriazole in sunlit natural waters, especially at high DOC. Both forms of benzotriazole yield hydroxyderivatives as their main transformation intermediates under all the relevant photochemical reaction pathways. These intermediates could be formed via · OH-induced hydroxylation, or upon electron abstraction followed by reaction with water. Differently from UVC irradiation data reported in previous studies, the concentration of aniline upon excitation of 1H-benzotriazole under environmentally significant UV wavelengths was always below the detection limit of the analytical

  18. Field determination of microgram quantities of niobium in rocks

    Science.gov (United States)

    Ward, F.N.; Marranzino, A.P.

    1955-01-01

    A rapid, simple, and moderately accurate method was needed for the determination of traces of niobium in rocks. The method developed is based on the reaction of niobium(V) with thiocyanate ion in a 4M hydrochloric acid and 0.5M tartaric acid medium, after which the complex is extracted with ethyl ether. The proposed procedure is applicable to rocks containing from 50 to 2000 p.p.m. of niobium, and, with modifications, can be used on rocks containing larger amounts. Five determinations on two rocks containing 100 p.p.m. or less of niobium agree within 5 p.p.m. of the mean, and the confidence limits at the 95% level are, respectively, ??6 and ??4 p.p.m. The addition of acetone to the ether extract of the niobium thiocyanate inhibits the polymerization of the thiocyanate ion and stabilizes the solution for at least 20 hours. The proposed procedure permits the determination of 20 ?? of niobium in the presence of 1000 ?? of iron, titanium, or uranium; 500 ?? of vanadium; or 100 ?? of tungsten or molybdenum or both.

  19. Recent developments in high purity niobium metal production at CBMM

    International Nuclear Information System (INIS)

    Abdo, Gustavo Giovanni Ribeiro; Sousa, Clovis Antonio de Faria; Guimarães, Rogério Contato; Ribas, Rogério Marques; Vieira, Alaércio Salvador Martins; Menezes, Andréia Duarte; Fridman, Daniel Pallos; Cruz, Edmundo Burgos

    2015-01-01

    CBMM is a global supplier of high quality niobium products including pure niobium, the focus of this paper. CBMM’s position has been consolidated over three decades of producing high purity niobium metal ingots. The company supplies, among other products, commercial and reactor grade niobium ingots. One of the main uses of CBMM’s ingots is for the manufacture of particle accelerators (superconducting radio frequency – SRF – cavities), where the purity and homogeneity of niobium metal is essentially important for good performance. CBMM constantly strives to improve process controls and product quality, and is currently implementing innovations in production, research and development to further improve ingot quality. The main aim is to reduce the content of interstitial elements, such as nitrogen (N), oxygen (O), carbon (C), and hydrogen (H), starting with the raw materials through the final step of ingot production. CBMM held the first trial to produce the world’s largest-diameter niobium ingot (as cast 535 mm). The results of this initial trial presented very low levels of interstitial impurities (N, O, C, H), allowing the achievement of residual resistivity ratio (RRR) values very close to 300 in a six-melt process in an electron beam furnace. These values were reached with 850 ppm of tantalum. SRF cavities will be produced with this material in order to study the effect of low impurities and high RRR on the Q factor and accelerating gradient

  20. Process for the production of a tantalum and niobium bearing concentrate from a tantalum and niobium bearing ferro-alloy

    International Nuclear Information System (INIS)

    Deweck, J.; Van, H.

    1980-01-01

    In a process for the production of a tantalum and niobium bearing concentrate from a tantalum and niobium bearing ferro-alloy containing tantalum and niobium as carbide, by treating the ferro-alloy in molten state with a controlled amount of an oxidizing agent in order to slag at least most of the tantalum and at least part of the niobium and by separting the so obtained slag phase from the metal phase, the improvement which comprises using air, oxygen enriched air or oxygen as oxidizing agent and adjusting the iron content to the ferro-alloy by adding at least 70% by weight of iron prior to the step of forming the slag so that at least most of the tantalum carbide is dissolved in the molten ferro-alloy

  1. Study on thermo-oxide layers of uranium-niobium alloy

    International Nuclear Information System (INIS)

    Luo Lizhu; Yang Jiangrong; Zhou Ping

    2010-01-01

    Surface oxides structure of uranium-niobium alloys which were annealed under different temperatures (room temperature, 100, 200, 300 degree C, respectively)in air were studied by X-ray photoelectron spectroscopy (XPS) analysis and depth profile. Thickness of thermo-oxide layers enhance with the increasing oxide temperature, and obvious changes to oxides structure are observed. Under different delt temperatures, Nb 2 O 5 are detected on the initial surface of U-Nb alloys, and a layer of NbO mixed with some NbO x (0 2 O 5 and Nb metal. Dealing samples in air from room temperature to 200 degree C, non-stoichiometric UO 2+x (UO 2 + interstitial oxygen, P-type semiconductor) are found on initial surface of U-Nb alloys, which has 0.7 eV shift to lower binding energy of U 4f 7/2 characteristics comparing to that of UO 2 . Under room temperature, UO 2 are commonly detected in the oxides layer, while under temperature of 100 and 200 degree C, some P-type UO 2+x are found in the oxide layers,which has a satellite at binding energy of 396.6 eV. When annealing at 300 degree C, higher valence oxides, such as U 3 O 8 or UO x (2 5/2 and U 4f 7/2 peaks are 392.2 and 381.8 eV, respectively. UO 2 mixed uranium metal are the main compositions in the oxide layers. From the results, influence of temperature to oxidation of uranium is more visible than to niobium in uranium-niobium alloys. (authors)

  2. A Study of the Batch Annealing of Cold-Rolled HSLA Steels Containing Niobium or Titanium

    Science.gov (United States)

    Fang, Chao; Garcia, C. Isaac; Choi, Shi-Hoon; DeArdo, Anthony J.

    2015-08-01

    The batch annealing behavior of two cold-rolled, microalloyed HSLA steels has been studied in this program. One steel was microalloyed with niobium while the other with titanium. A successfully batch annealed steel will exhibit minimum variation in properties along the length of the coil, even though the inner and outer wraps experience faster heating and cooling rates and lower soaking temperatures, i.e., the so-called "cold spot" areas, than the mid-length portion of the coil, i.e., the so-called "hot spot" areas. The variation in strength and ductility is caused by differences in the extent of annealing in the different areas. It has been known for 30 years that titanium-bearing HSLA steels show more variability after batch annealing than do the niobium-bearing steels. One of the goals of this study was to try to explain this observation. In this study, the annealing kinetics of the surface and center layers of the cold-rolled sheet were compared. The surface and center layers of the niobium steel and the surface layer of the titanium steel all showed similar annealing kinetics, while the center layer of the titanium steel exhibited much slower kinetics. Metallographic results indicate that the stored energy of the cold-rolled condition, as revealed by grain center sub-grain boundary density, appeared to strongly influence the annealing kinetics. The kinetics were followed by the Kernel Average Misorientation reconstruction of the microstructure at different stages on annealing. Possible pinning effects caused by microalloy precipitates were also considered. Methods of improving uniformity and increasing kinetics, involving optimizing both hot-rolled and cold-rolled microstructure, are suggested.

  3. Fabrication and radio frequency test of large-area MgB2 films on niobium substrates

    Science.gov (United States)

    Ni, Zhimao; Guo, Xin; Welander, Paul B.; Yang, Can; Franzi, Matthew; Tantawi, Sami; Feng, Qingrong; Liu, Kexin

    2017-04-01

    Magnesium diboride (MgB2) is a promising candidate material for superconducting radio frequency (RF) cavities because of its higher transition temperature and critical field compared with niobium. To meet the demand of RF test devices, the fabrication of large-area MgB2 films on metal substrates is needed. In this work, high quality MgB2 films with 50 mm diameter were fabricated on niobium by using an improved HPCVD system at Peking University, and RF tests were carried out at SLAC National Accelerator Laboratory. The transition temperature is approximately 39.6 K and the RF surface resistance is about 120 μΩ at 4 K and 11.4 GHz. The fabrication processes, surface morphology, DC superconducting properties and RF tests of these large-area MgB2 films are presented.

  4. Study of the role of the interface between niobium films and copper RF resonators

    CERN Document Server

    Benvenuti, Cristoforo; Campisi, I E; Darriulat, Pierre; Peck, M A; Russo, R

    1997-01-01

    Niobium-coated copper resonators are usually produced with an oxide interface between the film and the substrate. This oxide has two sources: the passivation layer inevitably formed on the surface of the cavity after chemical preparation before coating, and the niobium oxide which builds up on the surface of the cathode when it is exposed to air, and is transferred to the cavity surface during coa ting. The oxide layer may influence both the purity and the structural properties of the film, and in turn its RF behaviour. To study its effect, some cavities have been coated with a special two-cath ode sputtering system, allowing for a complete removal of both oxide layers by sputter-etching. For comparison, a few cavities have also been produced with the same coating system without sputter-etch ing, or with a controlled oxidation of the copper surface of the cavity after sputter-etching. Two cavities have also been produced without oxide interface using Kr and Ne as sputter gas instead of Ar .

  5. The influence of chemical treatments on the superconducting properties of technical niobium materials and their effect on the performance of superconducting radio frequency cavities

    International Nuclear Information System (INIS)

    Roy, S B; Sahni, V C; Myneni, G R

    2009-01-01

    We present the results of a study of superconducting response in the niobium materials used in the fabrication of high accelerating gradient (>25 MV m -1 ) superconducting radio frequency (SC-RF) cavities. These results clearly show that the typical surface chemical treatment deployed during the fabrication of SC-RF cavities affects the superconducting properties of pure niobium materials. Such SC-RF cavities operating at 2 K are often found to show anomalous RF losses, causing either a strong degradation of the quality factor or a thermal breakdown for cavity magnetic fields between 1 and 1.5 kOe. The results of our study suggest a correlation between the field for the first flux-line penetration in these chemically treated technical niobium materials and the reported onset field of anomalous losses in the SC-RF cavities.

  6. The influence of chemical treatments on the superconducting properties of technical niobium materials and their effect on the performance of superconducting radio frequency cavities

    Science.gov (United States)

    Roy, S. B.; Myneni, G. R.; Sahni, V. C.

    2009-10-01

    We present the results of a study of superconducting response in the niobium materials used in the fabrication of high accelerating gradient (>25 MV m-1) superconducting radio frequency (SC-RF) cavities. These results clearly show that the typical surface chemical treatment deployed during the fabrication of SC-RF cavities affects the superconducting properties of pure niobium materials. Such SC-RF cavities operating at 2 K are often found to show anomalous RF losses, causing either a strong degradation of the quality factor or a thermal breakdown for cavity magnetic fields between 1 and 1.5 kOe. The results of our study suggest a correlation between the field for the first flux-line penetration in these chemically treated technical niobium materials and the reported onset field of anomalous losses in the SC-RF cavities.

  7. Investigation of the deuterium solubility in niobium using secondary ion mass spectrometry (SIMS)

    International Nuclear Information System (INIS)

    Zuechner, H.; Bruening, T.

    1991-01-01

    From SIMS measurements on deuterium charged niobium foils a pressure-composition isotherm was obtained. The plateau pressure of the α-β-two-phase region is in good agreement with that known from electrochemical p-n isotherm measurements. The solubility in the homogeneous α-phase measured by SIMS, however, is enhanced compared with the electrochemical p-n isotherm, i.e. the homogeneous α-phase is broadened. These results are due to the ion bombardment causing a lattice distortion within the near surface region during the SIMS experiment. (orig.)

  8. JACoW N-doped niobium accelerating cavities: Analyzing model applicability

    CERN Document Server

    Eichhorn, Ralf; Weingarten, Wolfgang

    2017-01-01

    The goal of this research was to analyse data from multiple cavities in order to test the viability of a model for surface resistance proposed previously. The model intends to describe the behaviour of the quality factor with respect to the RF field strength, while exploring the physical cause of this phenomenon; the model is pretty general, but will be checked here specifically for N-doped niobium cavities. The data were obtained from two single-cell 1.3 GHz cavities manufactured and tested at Jefferson Lab in Newport News, VA, USA.

  9. Kinetic parameters of nitridation of molybdenum and niobium alloys with various structure states

    International Nuclear Information System (INIS)

    Solodkin, G.A.; Bulgach, A.A.; Likhacheva, T.E.

    1985-01-01

    Effect of preliminary plastic strain under rolling on kinetic parameters of nitridation of VN-2AEh, VN-3 niobium alloys and molybdenum alloy with hafnium is investigated. Extreme character of dependence of kinetic parameters of nitridation on the degree of reduction under rolling is determined. Preliminary plastic strain at negligible reduction is shown to accelerate growth of the zone of internal nitridation and decelerates growth of the nitride zone. Nitrogen atom removal from the surface to the centre is retarded at the increase of the degree of reduction up to 50% and higher. The degree of deformations is the higher the lower nitridation temperature is

  10. Fabrication of MgAl2O4 spinel/niobium laminar composites by plasma spraying

    International Nuclear Information System (INIS)

    Boncoeur, M.; Lochet, N.; Miomandre, F.; Schnedecker, G.

    1994-01-01

    The feasibility of plasma spray manufacturing of laminar ceramic matrix composites made of alternate thin layers of a ceramic oxide and a metal is demonstrated with a composite made of 7 layers, each 0.2 mm thick, of MgAl 2 O 4 spinel and niobium. Microstructure and mechanical characteristics have been studied with both as-sprayed and heat-treated under vacuum at 1400 C conditions. It is shown that the as-sprayed composite is brittle but becomes pseudo-plastic after heat treatment. These laminar composites are very attractive for the manufacturing of large surface, few millimeter thick components. (from authors). 4 figs., 4 refs

  11. Evaluation of niobium dimethylamino-ethoxide for chemical vapour deposition of niobium oxide thin films

    International Nuclear Information System (INIS)

    Dabirian, Ali; Kuzminykh, Yury; Wagner, Estelle; Benvenuti, Giacomo; Rushworth, Simon; Hoffmann, Patrik

    2014-01-01

    Chemical vapour deposition (CVD) processes depend on the availability of suitable precursors. Precursors that deliver a stable vapour pressure are favourable in classical CVD processes, as they ensure process reproducibility. In high vacuum CVD (HV-CVD) process vapour pressure stability of the precursor is of particular importance, since no carrier gas assisted transport can be used. The dimeric Nb 2 (OEt) 10 does not fulfil this requirement since it partially dissociates upon heating. Dimethylamino functionalization of an ethoxy ligand of Nb(OEt) 5 acts as an octahedral field completing entity and leads to Nb(OEt) 4 (dmae). We show that Nb(OEt) 4 (dmae) evaporates as monomeric molecule and ensures a stable vapour pressure and, consequently, stable flow. A set of HV-CVD experiments were conducted using this precursor by projecting a graded molecular beam of the precursor onto the substrate at deposition temperatures from 320 °C to 650 °C. Film growth rates ranging from 8 nm·h −1 to values larger than 400 nm·h −1 can be obtained in this system illustrating the high level of control available over the film growth process. Classical CVD limiting conditions along with the recently reported adsorption–reaction limited conditions are observed and the chemical composition, and microstructural and optical properties of the films are related to the corresponding growth regime. Nb(OEt) 4 (dmae) provides a large process window of deposition temperatures and precursor fluxes over which carbon-free and polycrystalline niobium oxide films with growth rates proportional to precursor flux are obtained. This feature makes Nb(OEt) 4 (dmae) an attractive precursor for combinatorial CVD of niobium containing complex oxide films that are finding an increasing interest in photonics and photoelectrochemical water splitting applications. The adsorption–reaction limited conditions provide extremely small growth rates comparable to an atomic layer deposition (ALD) process

  12. Corrosion resistance of the substrates for the cryogenic gyroscope and electrodeposition of the superconductive niobium coatings

    Science.gov (United States)

    Dubrovskiy, A. R.; Okunev, M. A.; Makarova, O. V.; Kuznetsov, S. A.

    2017-05-01

    The interaction of different materials with the niobium containing melt was investigated. As substrate materials the ceramics, beryllium and carbopyroceram were chosen. Several spherical ceramic and beryllium samples were coated with protective molybdenum and niobium films by magnetron sputtering and PVD, respectively. After the experiment (exposition time 10 min) the exfoliation of molybdenum film from ceramic samples was observed due to interaction of the substrate with the melt. The niobium protective coatings reacted with the melt with niobium oxide formation. The beryllium samples regardless of the shape and the presence of the protective films were dissolved in the niobium containing melt due to more negative electrode potential comparing with niobium one. The carbopyroceram samples were exposed in the melt during 3 and 12 h. It was found that the carbopyroceram not corrodes in the niobium containing melt. The optimal regimes for electrodeposition of smooth uniform niobium coatings with the thickness up to 50 μm on carbopyroceram spheres were found.

  13. Characterization of etch pits found on a large-grain bulk niobium superconducting radio-frequency resonant cavity

    OpenAIRE

    Xin Zhao; G. Ciovati; T. R. Bieler

    2010-01-01

    The performance of superconducting radio-frequency (SRF) resonant cavities made of bulk niobium is limited by nonlinear localized effects. Surface analysis of regions of higher power dissipation is thus of intense interest. Such areas (referred to as “hotspots”) were identified in a large-grain single-cell cavity that had been buffered-chemical polished and dissected for examination by high resolution electron microscopy, electron backscattered diffraction microscopy (EBSD), and optical micro...

  14. Effect of high concentration of molybdenum on the structure and properties of niobium

    International Nuclear Information System (INIS)

    Trekina, M.I.; Vasil'eva, E.V.

    1989-01-01

    The effect of alloying of 20,25 and 30 % Mo on the structure and mechanical properties of niobium is studied. It is shown that niobium alloying with molybdenum in the studied concentration leads to grain grinding, which increases with the molybdenum content growth in the alloy. The effective energy values of recrystallization activation of the studied niobium and molybdenum alloys are determined. The high hardness level at some plasticity and deformability of niobium alloy with 20 % Mo is established

  15. Formation and Thermal Stability of Large Precipitates and Oxides in Titanium and Niobium Microalloyed Steel

    Institute of Scientific and Technical Information of China (English)

    ZHUO Xiao-jun; WOO Dae-hee; WANG Xin-hua; LEE Hae-geon

    2008-01-01

    As-cast CC slabs of microalloyed steels are prone to surface and sub-surface cracking. Precipitation phenomena in-itiated during solidification reduce ductility at high temperature. The unidirectional solidification unit is employed to sim-ulate the solidification process during continuous casting. Precipitation behavior and thermal stability are systemati-cally investigated. Samples of adding titanium and niobium to steels have been examined using field emission scanning electron microscope (FE-SEM), electron probe X-ray microanalyzer (EPMA), and transmission electron microscope (TEM). It has been found that the addition of titanium and niobium to high-strength low-alloyed (HSLA) steel resuited in undesirable large precipitation in the steels, i. e. , precipitation of large precipitates with various morphologies. The composition of the large precipitates has been determined. The effect of cooling rate on (Ti, Nb)(C, N) precipitate formation is investigated. With increasing the cooling rate, titanium-rich (Ti,Nb)(C, N) precipitates are transformed to niobium-rich (Ti,Nb)(C,N) precipitates. The thermal stability of these large precipitates and oxides have been assessed by carrying out various heat treatments such as holding and quenching from temperature at 800 and 1 200 ℃. It has been found that titanium-rich (Ti,Nb)(C,N) precipitate is stable at about 1 200 ℃ and niobi-um-rich (Ti,Nb)(C,N) precipitate is stable at about 800 ℃. After reheating at 1 200 ℃ for 1 h, (Ca, Mn)S and TiN are precipitated from Ca-Al oxide. However, during reheating at 800 ℃ for 1 h, Ca-Al-Ti oxide in specimens was stable. The thermodynamic calculation of simulating the thermal process is employed. The calculation results are in good agreement with the experimental results.

  16. Metabolic and environmental aspects of fusion reactor activation products: niobium

    International Nuclear Information System (INIS)

    Easterly, C.E.; Shank, K.E.

    1977-11-01

    A summary of the metabolic and environmental aspects of niobium is presented. The toxicological symptoms from exposure to niobium are given, along with lethal concentration values for acute and chronic exposures. Existing human data are presented; animal uptake and retention data are analyzed for various routes of administration. Recommended metabolic values are also presented along with comments concerning their use and appropriateness. The natural distribution of niobium is given for freshwater, seawater, and the biosphere. Concentration factors and retention of 95 Nb in the environment are discussed with reference to: plant retention via leaf absorption; plant retention via root uptake; uptake in terrestrial animals from plants; uptake in freshwater organisms; uptake in marine organisms; and movement in soil. Conclusions are drawn regarding needs for future work in these areas. This review was undertaken because niobium is expected to be a key metal in the development of commercial fusion reactors. It is recognized that niobium will likely not be used in the first generation reactors as a structural material but will appear as an alloy in such materials as superconducting wire

  17. Metabolic and environmental aspects of fusion reactor activation products: niobium

    Energy Technology Data Exchange (ETDEWEB)

    Easterly, C.E.; Shank, K.E.

    1977-11-01

    A summary of the metabolic and environmental aspects of niobium is presented. The toxicological symptoms from exposure to niobium are given, along with lethal concentration values for acute and chronic exposures. Existing human data are presented; animal uptake and retention data are analyzed for various routes of administration. Recommended metabolic values are also presented along with comments concerning their use and appropriateness. The natural distribution of niobium is given for freshwater, seawater, and the biosphere. Concentration factors and retention of /sup 95/Nb in the environment are discussed with reference to: plant retention via leaf absorption; plant retention via root uptake; uptake in terrestrial animals from plants; uptake in freshwater organisms; uptake in marine organisms; and movement in soil. Conclusions are drawn regarding needs for future work in these areas. This review was undertaken because niobium is expected to be a key metal in the development of commercial fusion reactors. It is recognized that niobium will likely not be used in the first generation reactors as a structural material but will appear as an alloy in such materials as superconducting wire.

  18. Development of technology of high-purity compounds of tantalum and niobium with octanol use

    International Nuclear Information System (INIS)

    Majorov, V.G.; Nikolaev, A.I.; Kopkov, V.K.; Baklanova, I.V.; Safonova, L.A.

    2001-01-01

    Effect of composition of solutions and extractant expenditure on tantalum and niobium distribution during extraction by octanol and purification of tantalum and niobium extracts from impurities was studied. Scheme was developed according to which samples of high-pure tantalum and niobium pentaoxides were prepared [ru

  19. Passive behaviour of zirconium, hafnium and niobium

    International Nuclear Information System (INIS)

    Hornkjoel, S.

    1990-01-01

    The paper deals mainly with the results of stationary and transient polarization measurements together with capacitance measurements on passive electrodes of Zr, Hf and Nb over the entire pH-scale. The passive current densities are exstremely low, and essentially both pH and potential independent, exept for Nb at high pH. The extrapolated potential of zero inverse capacitance seems to be different from the extrapolated potential of zero film thickness for Zr and Hf, but not for Nb. The potential versus time curves at constant current show a downwards bending for Zr and Hf. It is shown that the pitting potentials of Zr and Hf are dependent of the concentration of halide ions and the type of halide ion, but not on pH. It is also shown that the pitting induction is second-order stimulated by chloride ions and first-order hindered by sulphate ions. Results from electron transfer reactions on passive niobium are reported. 9 refs

  20. Mechanical niobium doping in barium titanate electroceramics

    Energy Technology Data Exchange (ETDEWEB)

    Velasco-Davalos, I.A., E-mail: ivan.velascodavalos@gmail.com [Departmento de Ingeniería Metalúrgica, Instituto Politécnico Nacional, Zacatenco, 07338 México D.F. (Mexico); INRS-EMT, 1650 Boul. Lionel-Boulet, Varennes J3X 1S2 (Canada); Ruediger, A. [INRS-EMT, 1650 Boul. Lionel-Boulet, Varennes J3X 1S2 (Canada); Cruz-Rivera, J.J. [Universidad Autónoma de San Luis Potosí, Av. Sierra Leona 550, Lomas, 78210 S.L.P. (Mexico); Gomez-Yanez, C. [Departmento de Ingeniería Metalúrgica, Instituto Politécnico Nacional, Zacatenco, 07338 México D.F. (Mexico)

    2013-12-25

    Highlights: •We demonstrate a new doping procedure by Mechanical Alloying (MA). •For small dopant concentrations, charge compensation of Nb is primarily attributed to free electrons. •At higher Nb concentrations cation vacancies prevail as compensation mechanism. -- Abstract: Niobium is a well-established donor dopant for semi-conducting BaTiO{sub 3} ceramics. The conventional procedure to dissolve Nb into BaTiO{sub 3} relies on thermal activation at high temperatures (up to 1500 °C) and even then, large dwell times are necessary due to the small diffusion coefficients of Nb{sup 5+}. In this work, we demonstrate a new doping procedure by Mechanical Alloying (MA), which has already proven its potential for the fabrication of conductive electroceramics. In a planetary mill, powders of BaTiO{sub 3} and Nb{sub 2}O{sub 5} were mixed for up to 540 min. The BaTiO{sub 3} unit cell volume increases with increasing Nb concentration. The electrical properties of conventional and mechanical alloyed samples as a function of Nb concentration are similar, however the mechanically alloyed samples shows a large conductivity that we attribute to a better homogeneity in the structure of MA-processed samples. For small dopant concentrations, charge compensation of the pentavalent Nb is primarily attributed to free electrons. At higher Nb concentrations cation vacancies prevail as compensation mechanism.

  1. Niobium Titanium and Copper wire samples

    CERN Multimedia

    2009-01-01

    Two wire samples, both for carrying 13'000Amperes. I sample is copper. The other is the Niobium Titanium wiring used in the LHC magnets. The high magnetic fields needed for guiding particles around the Large Hadron Collider (LHC) ring are created by passing 12’500 amps of current through coils of superconducting wiring. At very low temperatures, superconductors have no electrical resistance and therefore no power loss. The LHC is the largest superconducting installation ever built. The magnetic field must also be extremely uniform. This means the current flowing in the coils has to be very precisely controlled. Indeed, nowhere before has such precision been achieved at such high currents. Magnet coils are made of copper-clad niobium–titanium cables — each wire in the cable consists of 9’000 niobium–titanium filaments ten times finer than a hair. The cables carry up to 12’500 amps and must withstand enormous electromagnetic forces. At full field, the force on one metre of magnet is comparable ...

  2. Carbochlorination kinetics of tantalum and niobium pentoxides

    International Nuclear Information System (INIS)

    Allain, E.; Gaballah, I.; Garcia, F.; Ferreira, S.; Ayala, J. N.; Hernandez, A.

    1999-01-01

    The carbochlorination kinetics of pure Nb 2 O 5 and Ta 2 O 5 by gas mixture (CL 2 +CO+N 2 ) between 380 and 1,000 degree centigree is studied. A calculation of the standard free energy of the carbochlorination reactions is made. A diagram of the phases stability is drawn. The influence of the gas flow, temperature and the partial pressure of Cl 2 and Co at temperatures below 650 degree centigree on the reaction rate is studied. The apparent activation energy is approximately 75 and 110 kJ/mol for Nb 2 O 5 and Ta 2 O 5 , respectively. At temperatures above 650 degree centigree the Arrhenius diagram presents and anomaly which may be attributed to the decomposition of the COCL 2 formed in situ. The apparent reaction order of the carbochlorination of these oxides against Cl 2 +CO is approximately 2. The carbochlorination rates of these oxides are much greater than those of chlorination by Cl 2 +N 2 . The carbochlorination kinetics of tin furnace slag leaching concentrates containing tantalum and niobium compounds are also studied and compared with the carbochlorination kinetics of the pure oxides. (Author) 14 refs

  3. Radiation effects in uranium-niobium titanates

    International Nuclear Information System (INIS)

    Lian, J.; Wang, S.X.; Wang, L.M.; Ewing, R.C.

    2000-01-01

    Pyrochlore is an important actinide host phase proposed for the immobilization of high level nuclear wastes and excess weapon plutonium.[1] Synthetic pyrochlore has a great variety of chemical compositions due to the possibility of extensive substitutions in the pyrochlore structure.[2] During the synthesis of pyrochlore, additional complex titanate phases may form in small quantities. The response of these phases to radiation damage must be evaluated because volume expansion of minor phases may cause micro-fracturing. In this work, two complex uranium-niobium titanates, U 3 NbO 9.8 (U-rich titanate) and Nb 3 UO 10 (Nb-rich titanate) were synthesized by the alkoxide/nitrate route at 1300 deg. C under an argon atmosphere. The phase composition and structure were analyzed by EDS, BSE, XRD, EMPA and TEM techniques. An 800 KeVKr 2+ irradiation was performed using the IVEM-Tandem Facility at Argonne National Laboratory in a temperature range from 30 K to 973 K. The radiation effects were observed by in situ TEM

  4. Sample of superconducting wiring (Niobium Titanium)

    CERN Multimedia

    About NbTi cable: The cable consists of 36 strands of superconducting wire, each strand has a diameter of 0.825 mm and houses 6300 superconducting filaments of niobium-titanium (Nb-Ti, a superconducting alloy). Each filament has a diameter of about 0.006 mm, i.e. 10 times smaller than a typical human hair. The filaments are embedded in a high-purity copper matrix. Copper is a normal conducting material. The filaments are in the superconductive state when the temperature is below about -263ºC (10.15 K). When the filaments leave the superconductive state, the copper acts as conductor transports the electrical current. Each strand of The NbTi cable (at superconducting state) has a current density of up to above 2000 A/mm2 at 9 T and -271ºC (2.15 K). A cable transport a current of about 13000 A at 10 T and -271ºC (2.15 K). About LHC superconducting wiring: The high magnetic fields needed for the LHC can only be reached using superconductors. At very low temperatures, superconductors have no electrical resistan...

  5. Sample of superconducting wiring (Niobium Titanium)

    CERN Multimedia

    About NbTi cable: The cable consists of 36 strands of superconducting wire, each strand has a diameter of 0.825 mm and houses 6300 superconducting filaments of niobium-titanium (Nb-Ti, a superconducting alloy). Each filament has a diameter of about 0.006 mm, i.e. 10 times smaller than a typical human hair. The filaments are embedded in a high-purity copper matrix. Copper is a normal conducting material. The filaments are in the superconductive state when the temperature is below about -263ºC (10.15 K). When the filaments leave the superconductive state, the copper acts as conductor transports the electrical current. Each strand of The NbTi cable (at superconducting state) has a current density of up to above 2000 A/mm2 at 9 T and -271ºC (2.15 K). A cable transport a current of about 13000 A at 10 T and -271ºC (2.15 K). About LHC superconducting wiring: The high magnetic fields needed for the LHC can only be reached using superconductors. At very low temperatures, superconductors have no electrical resista...

  6. Detection of MM.-radiation with high current density submicron niobium-niobium Josephson junctions

    International Nuclear Information System (INIS)

    Daalmans, G.M.; Graauw, T. de; Lidholm, S.; Vliet, F. v.

    1980-01-01

    The rf-induced step heights in submicron niobium-niobium Josephson junctions are in good agreement with Russer theory at 230 and 240 GHz. At 115 and 460 GHz the agreement is less but still reasonably good. The junction noise without rf-bias is within a factor of two equal to the theoretical limit. With rf-bias applied it can be equal to the theoretical limit within a factor of two. The maximum conversion efficiency measured at 230 GHz was 0.18 and the lowest single side band mixer noise temperature at the same frequency was 380 K. Saturation effects are limiting the performance of the mixer. Improvements in eta and Tsub(M) of a factor of two can be expected by eliminating these saturation effects. The mixer which has been studied most extensively starting at 12-3-80 is still alive at 5-6-80 after many cooling cycles, storage at room temperature and soldering in and out of the dewar. The reliability of this type of junction cannot be questionable anymore. (orig.)

  7. The Influence of Surface and Deep Cues on Primary and Secondary School Students' Assessment of Relevance in Web Menus

    Science.gov (United States)

    Rouet, Jean-Francois; Ros, Christine; Goumi, Antonine; Macedo-Rouet, Monica; Dinet, Jerome

    2011-01-01

    Two experiments investigated primary and secondary school students' Web menu selection strategies using simulated Web search tasks. It was hypothesized that students' selections of websites depend on their perception and integration of multiple relevance cues. More specifically, students should be able to disentangle superficial cues (e.g.,…

  8. Parametrisation of the niobium thermal conductivity in the superconducting state

    International Nuclear Information System (INIS)

    Koechlin, F.; Bonin, B.

    1996-01-01

    Thermal conductivity measurements of niobium sheets manufactured for deep-drawing of superconducting cavities have been gathered. Due to various histories of the niobium samples and a wide range of metal purities (35< RRR<1750) the data offer a large scatter of thermal conductivities. An attempt is made to obtain an analytical expression with realistic parameters for the thermal conductivity between 1.8 K and 9.25 K. The set of parameters deduced from a least square fit of experimental data is not very different from those yielded by the theory of superconducting metals, taken as a starting point. This should make possible to obtain a reasonable guess of the thermal conductivity of niobium in this temperature range, once the RRR and the past history of the metal samples have been determined. (author)

  9. Compatibility of niobium, titanium, and vanadium metals with LMFBR cladding

    International Nuclear Information System (INIS)

    Wilson, C.N.

    1975-10-01

    A series of laboratory capsule annealing experiments were conducted to assess the compatibility of niobium, vanadium, and titanium with 316 stainless steel cladding in the temperature range of 700 to 800 0 C. Niobium, vanadium, and titanium are cantidate oxygen absorber materials for control of oxygen chemistry in LMFBR fuel pins. Capsule examination indicated good compatibility between niobium and 316 stainless steel at 800 0 C. Potential compatibility problems between cladding and vanadium or titanium were indicated at 800 0 C under reducing conditions. In the presence of Pu/sub 0.25/U/sub 0.75/O/sub 1.98/ fuel (Δanti G 02 congruent to -160 kcal/mole) no reaction was observed between vanadium or titanium and cladding at 800 0 C

  10. Characterization and sintering of niobium-ATR alumina

    International Nuclear Information System (INIS)

    Sibuya, N.H.; Iwasaki, H.; Suzuki, C.K.; Pinatti, D.G.

    1987-01-01

    In the niobium aluminothermy a slag is produced, composed mostly of alumina and other compounds such as niobium oxide and silica. The phase composition of this ATR alumina was characterized by X-ray powder diffractometry, and afterwards this alumina was subjected to leaching processes. It was noticed that the original content of 70% α-alumina in slag rose to 95% after the calcination. ATR alumina (leached and calcined, and without any treatment) was used to make pressed bodies which were fired in air at 1200 to 1400 0 C for 1 to 10,5 hours; and in vacuum at 1550 to 1800$0C for 2 hours. Characterization was done by density measurements, X-ray diffractometry and ultrasonic analysis. Ultrasonic analysis of some vacuum fired bodies showed londitudinal velocities close to the value found in literature. Correlation of several techniques measurements disclosed the niobium oxide interference in sintering. (Author) [pt

  11. Solid solutions of hydrogen in niobium, molybdenum and their alloys

    International Nuclear Information System (INIS)

    Ishikawa, T.T.

    1981-01-01

    The solubility of hydrogen in niobium, molybdenum and niobium-molybdenum alloys with varying atomic fraction of molybdenum from 0.15 to 0.75 was measured on the temperature range of 673 0 K to 1273 0 k for one atmosphere hydrogen pressure. The experimental technique involved the saturation of the solvent metal or alloy with hydrogen, followed by quenching and analysis of the solid solution. The results obtained of hydrogen solubility are consistent with the quasi-regular model for the dilute interstitial solid solutions. The partial molar enthalpy and partial molar entropy in excess of the dissolved hydrogen atoms were calculated from data of solubility versus reciprocal doping temperature. The variation of the relative partial molar enthalpy of hydrogen dissolved in niobium-molybdenum alloys, with the increase of molybdenum content of the alloy was analized. (Author) [pt

  12. Growth of anodic oxide films on oxygen-containing niobium

    Energy Technology Data Exchange (ETDEWEB)

    Habazaki, H. [Graduate School of Engineering, Hokkaido University, Sapporo 060-8628 (Japan)]. E-mail: habazaki@eng.hokudai.ac.jp; Ogasawara, T. [Graduate School of Engineering, Hokkaido University, Sapporo 060-8628 (Japan); Konno, H. [Graduate School of Engineering, Hokkaido University, Sapporo 060-8628 (Japan); Shimizu, K. [University Chemical Laboratory, Keio University, Yokohama 223-8522 (Japan); Asami, K. [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Saito, K. [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Nagata, S. [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Skeldon, P. [Corrosion and Protection Centre, School of Materials, The University of Manchester, P.O. Box 88, Manchester M60 1QD (United Kingdom); Thompson, G.E. [Corrosion and Protection Centre, School of Materials, The University of Manchester, P.O. Box 88, Manchester M60 1QD (United Kingdom)

    2005-09-20

    The present study is directed at understanding of the influence of oxygen in the metal on anodic film growth on niobium, using sputter-deposited niobium containing from about 0-52 at.% oxygen, with anodizing carried out at high efficiency in phosphoric acid electrolyte. The findings reveal amorphous anodic niobia films, with no significant effect of oxygen on the field strength, transport numbers, mobility of impurity species and capacitance. However, since niobium is partially oxidized due to presence of oxygen in the substrate, less charge is required to form the films, hence reducing the time to reach a particular film thickness and anodizing voltage. Further, the relative thickness of film material formed at the metal/film interface is increased by the incorporation of oxygen species into the films from the substrate, with an associated altered depth of incorporation of phosphorus species into the films.

  13. Low noise niobium dc SQUID with a planar input coil

    Science.gov (United States)

    de Waal, V. J.; van den Hamer, P.; Klapwijk, T. M.

    1983-02-01

    A practical all-niobium dc superconducting quantum interference device (SQUID) with a niobium spiral input coil has been developed. The SQUID utilizes submicron Josephson junctions. The best intrinsic energy resolution obtained with a 1-nH SQUID is 4×10-32 J/Hz. A 20-turn 1.2-μH input coil is coupled to a 2.3-nH SQUID with an efficiency of 0.5. The energy resolution with respect to the coil is 1×10-30 J/Hz.

  14. Low noise niobium dc SQUID with a planar input coil

    Energy Technology Data Exchange (ETDEWEB)

    de Waal, V.J.; van den Hamer, P.; Klapwijk, T.M.

    1983-02-15

    A practical all-niobium dc superconducting quantum interference device (SQUID) with a niobium spiral input coil has been developed. The SQUID utilizes submicron Josephson junctions. The best intrinsic energy resolution obtained with a 1-nH SQUID is 4 x 10/sup -32/ J/Hz. A 20-turn 1.2-..mu..H input coil is coupled to a 2.3-nH SQUID with an efficiency of 0.5. The energy resolution with respect to the coil is 1 x 10/sup -30/ J/Hz.

  15. Niobium-Matrix-Composite High-Temperature Turbine Blades

    Science.gov (United States)

    Kaplan, Richard B.; Tuffias, Robert H.; La Ferla, Raffaele; Heng, Sangvavann; Harding, John T.

    1995-01-01

    High-temperture composite-material turbine blades comprising mainly niobium matrices reinforced with refractory-material fibers being developed. Of refractory fibrous materials investigated, FP-AL(2)0(3), tungsten, and polymer-based SiC fibers most promising. Blade of this type hollow and formed in nearly net shape by wrapping mesh of reinforcing refractory fibers around molybdenum mandrel, then using thermal-gradient chemical-vapor infiltration (CVI) to fill interstices with niobium. CVI process controllable and repeatable, and kinetics of both deposition and infiltration well understood.

  16. Electromigration of hydrogen and deuterium in vanadium, niobium, and tantalum

    International Nuclear Information System (INIS)

    Jensen, C.L.

    1977-10-01

    The electric mobility and effective valence of hydrogen and deuterium in vanadium, niobium, tantalum and three niobium-tantalum alloys were measured. A resistance technique was used to directly determine the electric mobility of hydrogen and deuterium at 30 0 C while a steady-state method was used to measure the effective valence. The use of mass spectrographic techniques on a single specimen which contained both hydrogen and deuterium greatly increased the precision with which the isotope effect in the effective valence could be measured

  17. Thermal diffusivity of alumina-zirconia sintered with niobium additions

    International Nuclear Information System (INIS)

    Santos, W.N. dos; Paulin Filho, P.I.; Taylor, R.

    1994-01-01

    The effect of niobium oxide addition on the alumina-zirconia thermal diffusivity was investigated from 100 0 C to 1000 0 C by the laser flash method. It was observed that 4 to 6% addition of niobium oxide increases the thermal diffusivity when samples were sintered at 1450 0 C. This effect was due to elimination of porosity by formation of liquid please above 1420 0 C in the Al 2 O 3 - Nb 2 O 5 system. (author). 7 refs., 3 figs

  18. A low energy muon spin rotation and point contact tunneling study of niobium films prepared for superconducting cavities

    Science.gov (United States)

    Junginger, Tobias; Calatroni, S.; Sublet, A.; Terenziani, G.; Prokscha, T.; Salman, Z.; Suter, A.; Proslier, T.; Zasadzinski, J.

    2017-12-01

    Point contact tunneling and low energy muon spin rotation are used to probe, on the same samples, the surface superconducting properties of micrometer thick niobium films deposited onto copper substrates using different sputtering techniques: diode, dc magnetron and HIPIMS. The combined results are compared to radio-frequency tests performances of RF cavities made with the same processes. Degraded surface superconducting properties are found to correlate to lower quality factors and stronger Q-slope. In addition, both techniques find evidence for surface paramagnetism on all samples and particularly on Nb films prepared by HIPIMS.

  19. Density Functional Theory Study of Leaching Performance of Different Acids on Pyrochlore (100) Surface

    Science.gov (United States)

    Yang, Xiuli; Fang, Qing; Ouyang, Hui

    2018-06-01

    Pyrochlore leaching using hydrofluoric, sulfuric, and hydrochloric acids has been studied via experimental methods for years, but the interactions between niobium atoms on the pyrochlore surface and different acids have not been investigated. In this work, first-principles calculations based on density functional theory were used to elucidate the leaching performance of these three acids from the viewpoint of geometrical and electronic structures. The calculation results indicate that sulfate, chloride, and fluoride anions influence the geometric structure of pyrochlore (100) to different extents, decreasing in the order: sulfate, fluoride, chloride. Orbitals of O1 and O2 atoms of sulfate hybridized with those of surface niobium atom. Fluorine orbitals hybridized with those of surface niobium atoms. However, no obvious overlap exists between any orbitals of chlorine and surface niobium, revealing that chlorine does not interact chemically with surface niobium atoms.

  20. Effect of mild baking on superconducting niobium cavities investigated by sequential nanoremoval

    Directory of Open Access Journals (Sweden)

    A. Romanenko

    2013-01-01

    Full Text Available The near-surface nanostructure of niobium determines the performance of superconducting microwave cavities. Subtle variations in surface nanostructure lead to yet unexplained phenomena such as the dependence of the quality factor of these resonating structures on the magnitude of rf fields—an effect known as the “Q slopes”. Understanding and controlling the Q slopes is of great practical importance for particle accelerators. Here we investigate the mild baking effect—120°C vacuum baking for 48 hours—which strongly affects the Q slopes. We used a hydrofluoric acid rinse alternating with oxidation in water as a tool for stepwise material removal of about 2  nanometers/step from the surface of superconducting niobium cavities. Applying removal cycles on mild baked cavities and measuring the quality factor dependence on the rf fields after one or several such cycles allowed us to explore the distribution of lossy layers within the first several tens of nanometers from the surface. We found that a single HF rinse results in the increase of the cavity quality factor. The low field Q slope was shown to be mostly controlled by the material structure within the first six nanometers from the surface. The medium field Q slope evolution was fitted using linear (∝B peak surface magnetic field and quadratic (∝B^{2} terms in the surface resistance and it was found that best fits do not require the quadratic term. We found that about 10 nanometers of material removal are required to bring back the high field Q slope and about 20–50 nanometers to restore the onset field to the prebaking value.

  1. Kinetic effects on the propagation of surface waves and their relevance to the heating of the solar corona

    International Nuclear Information System (INIS)

    Kuperus, M.; Heyvaerts, J.

    1980-01-01

    The MHD oscillations of the Alfven type running along surfaces of discontinuity generate motions in the discontinuity region which come rapidly out of phase. It is shown how the mathematical theory of this phase detuning predicts that surface wave should suffer dissipationless damping. Real damping is actually achieved by viscosity or kinetic effects. When detuning has grown to a large enough level, however, oscillations must be described by kinetic theory. Kinetic Alfven waves differ from perfect MHD Alfven waves in that they are able to propagate across the field. A theory of kinetic type oscillations in a finite thickness boundary is described, which predicts that surface waves generate intense kinetic Alfven waves in this boundary. The subsequent dissipation of these waves may be a powerful heating mechanism [fr

  2. Variation of Mechanical Properties of High RRR And Reactor Grade Niobium With Heat Treatments

    Energy Technology Data Exchange (ETDEWEB)

    Ganapati Myneni; H. Umezawa

    2003-06-01

    Superconducting rf cavities used as accelerating structures in particle accelerators are made from high purity niobium with residual resistance ratios greater than 250. Reactor grade niobium is also used to make wave-guide and/or end group components for these accelerating structures. The major impurities in this type of niobium are interstitially dissolved gases such as hydrogen, nitrogen, and oxygen in addition to carbon. After fabricating the niobium accelerating structures, they are subjected to heat treatments for several hours in vacuum at temperatures of up to 900 C for degassing hydrogen or up to 1400 C for improving the thermal conductivity of niobium considerably. These heat treatments are affecting the mechanical properties of niobium drastically. In this paper the variation of the mechanical properties of high purity and reactor grade niobium with heat treatments in a vacuum of {approx} 10{sup -6} Torr and temperatures from 600 C to 1250 C for periods of 10 to 6 hours are presented.

  3. Deep drawing experiences of niobium disk for PEFP SRF cavity prototype

    International Nuclear Information System (INIS)

    Kim, Han Sung; An, Sun; Zhang, Liping; Tang, Yazhe; Li, Ying Min; Kwon, Hyeok Jung; Cho, Yong Sub

    2009-01-01

    A superconducting radio frequency (SRF) cavity with a geometrical beta of 0.42 has been designed to accelerate a proton beam after 100 MeV for an extension of Proton Engineering Frontier Project (PEFP). The designed cavity shape is an elliptical and the resonant frequency is 700 MHz. In order to confirm the RF and mechanical properties of the cavity, two prototypes of copper cavities have been fabricated and tested. Based on the experiences gained with the copper prototypes, two niobium prototypes have been designed. One is two-cell cavity and the other is five cell cavity. The two-cell cavity is for finalizing the niobium cavity production procedure and testing the cavity RF properties at a low temperature and moderate power level. The five-cell cavity is for checking the production quality and testing vertical test system in the future. Both of them are under fabrication. Through the fabrication of the niobium prototype, several issues such as deep drawing, electron beam welding and surface treatment will be addressed. The drawing of the PEPF SRF low beta cavity is shown in Fig. 1. Major parameters for the cavity are like following. - Frequency: 700 MHz - Operating mode: TM010 pi mode - Cavity type: Elliptical - Geometrical beta: 0.42 - Number of cells: 5 per cavity - Accelerating gradient: 8 MV/m - Epeak/Eacc: 3.71 - Bpeak/Eacc: 7.47 mT/(MV/m) - R/Q: 102.3 ohm - Epeak: 29.68 MV/m - Field flatness: 1.56 % - Cell to cell coupling: 1.41 % - Geometrical factor: 121.68 ohm - Cavity wall thickness: 4.3 mm - Lorentz force detuning: 0.4 Hz/(MV/m)2 - Stiffening structure: Double ring - Effective length: 0.45 m - External Q of FPC: 8.0E5 ±20 % - HOM load: less than 2 W - HOM Qext requirement: less than 3.0E5 At present, all the niobium disk and plates for cavity and NbTi flanges for beam pipe flange are prepared

  4. Atmospheric Constraints on the Surface UV Environment of Mars at 3.9 Ga Relevant to Prebiotic Chemistry

    Science.gov (United States)

    Ranjan, Sukrit; Wordsworth, Robin; Sasselov, Dimitar D.

    2017-08-01

    Recent findings suggest that Mars may have been a clement environment for the emergence of life and may even have compared favorably to Earth in this regard. These findings have revived interest in the hypothesis that prebiotically important molecules or even nascent life may have formed on Mars and been transferred to Earth. UV light plays a key role in prebiotic chemistry. Characterizing the early martian surface UV environment is key to understanding how Mars compares to Earth as a venue for prebiotic chemistry. Here, we present two-stream, multilayer calculations of the UV surface radiance on Mars at 3.9 Ga to constrain the surface UV environment as a function of atmospheric state. We explore a wide range of atmospheric pressures, temperatures, and compositions that correspond to the diversity of martian atmospheric states consistent with available constraints. We include the effects of clouds and dust. We calculate dose rates to quantify the effect of different atmospheric states on UV-sensitive prebiotic chemistry. We find that, for normative clear-sky CO2-H2O atmospheres, the UV environment on young Mars is comparable to young Earth. This similarity is robust to moderate cloud cover; thick clouds (τcloud ≥ 100) are required to significantly affect the martian UV environment, because cloud absorption is degenerate with atmospheric CO2. On the other hand, absorption from SO2, H2S, and dust is nondegenerate with CO2, meaning that, if these constituents build up to significant levels, surface UV fluence can be suppressed. These absorbers have spectrally variable absorption, meaning that their presence affects prebiotic pathways in different ways. In particular, high SO2 environments may admit UV fluence that favors pathways conducive to abiogenesis over pathways unfavorable to it. However, better measurements of the spectral quantum yields of these pathways are required to evaluate this hypothesis definitively.

  5. Technology of niobium and molybdenum refining by electron beam

    International Nuclear Information System (INIS)

    Conti, R.A.; Pinatti, D.G.; Sandim, H.R.Z.

    1988-01-01

    The uses of metals and alloys in superconductors (Nb46%Ti), aerospatial industry (Ti6Al4V), electroeletronic industry (Nb, Mo, W) and in surgical implants (Ti, Nb) are increasing nowadays. A refining process of niobium and molybdenum by electron beam technique, since the oxides reduction till the obtention of a high purity ingot is presented. (C.G.C.) [pt

  6. Solubility of nitrogen in iron alloys with vanadium and niobium

    International Nuclear Information System (INIS)

    Pomarin, Yu.M.; Grigorenko, G.M.; Lakomskij, V.I.

    1975-01-01

    The solubility of nitrogen in the concentration range under study in Fe-N-V and Fe-N-Nb systems is in compliance with Syverts' law. An equation has been set up so as to estimate the nitrogen solubility in the iron alloys containing up to 10 per cent of vanadium and niobium in the wide temperature range

  7. Preferred orientations in niobium determined by neutrons diffraction

    International Nuclear Information System (INIS)

    Ueno, S.I.N.

    1979-01-01

    Neutron diffraction has been utilized to study textures developed in polycrystalline niobium, cold rolled to 60%, 80% and 95% in tickness and cold rolled to 95% in thickness and annealed at 800 0 C for 15, 30, 60 and 120 minutes in a vacuum of 10 -4 TORR [pt

  8. Process of forming niobium and boron containing titanium aluminide

    International Nuclear Information System (INIS)

    Huang, S.C.

    1992-01-01

    This patent describes a method of forming a composition of titanium, aluminum, niobium, and boron of higher ductility comprising casting the following approximate composition: Ti 34-50.5 Al 43-48 Nb 6-16 B 0.5-2.0 and thermomechanically working the cast composition

  9. Mechanical behaviour of copper 15% volume niobium microcomposite wires

    Directory of Open Access Journals (Sweden)

    Marcello Filgueira

    2001-01-01

    Full Text Available Cu-Nb microcomposites are attractive in magnet pulsed field technology applications due to their anomalous mechanism of mechanical strength and high electrical conductivity. In this sense, recently it was conceived the use of Cu 15% vol. Nb wires to operate as a high tensile strength cable for a diamond cutting tool (diamond wires for marble and granite slabbing. The multifilamentary Cu 15% vol. Nb composite was obtained using a new processing route, starting with niobium bars bundled into copper tubes, without arc melting. Cold working techniques, such as swaging and wire drawing, combined with heat treatments such as sintering and annealing, and tube restacking were employed. The tensile property of the composite was measured as a function of the niobium filaments dimensions and morphology into the copper matrix, in the several processing steps. An ultimate tensile strength (UTS of 960 MPa was obtained for an areal reduction (R = Ao/A, with Ao-initial cross section area, and A-final cross section area of 4x10(8 X, in which the niobium filaments reached thickness less than 20 nm. The anomalous mechanical strength increase is attributed to the fact that the niobium filaments acts as a barrier to copper dislocations.

  10. High-Q superconducting niobium cavities for gravitational wave detectors

    International Nuclear Information System (INIS)

    De Paula, L A N; Furtado, S R; Aguiar, O D; N F Oliveira Jr, N F Oliveira Jr; Castro, P J; Barroso, J J

    2014-01-01

    The main purpose of this work is to optimize the electric Q-factor of superconducting niobium klystron cavities to be used in parametric transducers of the Mario Schenberg gravitational wave detector. Many cavities were manufactured from niobium with relatively high tantalum impurities (1420 ppm) and they were cryogenically tested to determine their resonance frequencies, unloaded electrical quality factors (Q 0 ) and electromagnetic couplings. These cavities were closed with a flat niobium plate with tantalum impurities below 1000 ppm and an unloaded electrical quality factors of the order of 10 5 have been obtained. AC conductivity of the order of 10 12 S/m has been found for niobium cavities when matching experimental results with computational simulations. These values for the Q-factor would allow the detector to reach the quantum limit of sensitivity of ∼ 10 −22 Hz −1/2 in the near future, making it possible to search for gravitational waves around 3.2 kHz. The experimental tests were performed at the laboratories of the National Institute for Space Research (INPE) and at the Institute for Advanced Studies (IEAv - CTA)

  11. Effect of substitution of titanium by magnesium and niobium on ...

    Indian Academy of Sciences (India)

    Administrator

    Effect of substitution of titanium by magnesium and niobium on structure and piezoelectric properties in (Bi1/2. Na1/2. )TiO3 ceramics. ZHOU CHANG-RONG*, LIU XIN-YU, LI WEI-ZHOU. † and YUAN CHANG-LAI. Department of Information Material Science and Engineering, Guilin University of Electronic Technology,. Guilin ...

  12. Quantitative analysis method for niobium in lead zirconate titanate

    International Nuclear Information System (INIS)

    Hara, Hideo; Hashimoto, Toshio

    1986-01-01

    Lead zirconate titanate (PZT) is a strong dielectric ceramic having piezoelectric and pyroelectric properties, and is used most as a piezoelectric material. Also it is a main component of lead lanthanum zirconate titanate (PLZT), which is a typical electrical-optical conversion element. Since these have been developed, the various electronic parts utilizing the piezoelectric characteristics have been put in practical use. The characteristics can be set up by changing the composition of PZT and the kinds and amount of additives. Among the additives, niobium has the action to make metallic ion vacancy in crystals, and by the formation of this vacancy, to ease the movement of domain walls in crystal grains, and to increase resistivity. Accordingly, it is necessary to accurately determine the niobium content for the research and development, quality control and process control. The quantitative analysis methods for niobium used so far have respective demerits, therefore, the authors examined the quantitative analysis of niobium in PZT by using an inductively coupled plasma emission spectro-analysis apparatus which has remarkably developed recently. As the result, the method of dissolving a specimen with hydrochloric acid and hydrofluoric acid, and masking unstable lead with ethylene diamine tetraacetic acid 2 sodium and fluoride ions with boric acid was established. The apparatus, reagents, the experiment and the results are reported. (Kako, I.)

  13. Fatigue crack growth behavior in niobium-hydrogen alloys

    International Nuclear Information System (INIS)

    Lin, M.C.C.; Salama, K.

    1997-01-01

    Near-threshold fatigue crack growth behavior has been investigated in niobium-hydrogen alloys. Compact tension specimens (CTS) with three hydrogen conditions are used: hydrogen-free, hydrogen in solid solution, and hydride alloy. The specimens are fatigued at a temperature of 296 K and load ratios of 0.05, 0.4, and 0.75. The results at load ratios of 0.05 and 0.4 show that the threshold stress intensity range (ΔK th ) decreases as hydrogen is added to niobium. It reaches a minimum at the critical hydrogen concentration (C cr ), where maximum embrittlement occurs. The critical hydrogen concentration is approximately equal to the solubility limit of hydrogen in niobium. As the hydrogen concentration exceeds C cr , ΔK th increases slowly as more hydrogen is added to the specimen. At load ratio 0.75, ΔK th decreases continuously as the hydrogen concentration is increased. The results provide evidence that two mechanisms are responsible for fatigue crack growth behavior in niobium-hydrogen alloys. First, embrittlement is retarded by hydride transformation--induced and plasticity-induced crack closures. Second, embrittlement is enhanced by the presence of hydrogen and hydride

  14. Thermodynamic analysis of reduction reactions of niobium oxides

    International Nuclear Information System (INIS)

    Takano, C.

    1981-01-01

    Reduction processes of niobium oxides by hydrogen, carbon and aluminium are analysed thermodinamically. It is shown that reduction by hydrogen is not technically feasible. High purity of raw materials is required. In the carbothermic process impurities which react to form high stability carbides should be avoided. (Author) [pt

  15. Manufacturing of the L band 9-cell niobium cavity

    International Nuclear Information System (INIS)

    Matsuoka, Masanori; Ohkubo, Kohichi; Yamanaka, Toshiyuki; Kako, Eiji; Saito, Kenji; Shishido, Toshio; Ono, Masaaki; Noguchi, Shuichi.

    1993-01-01

    Since 1990, L-band niobium superconducting cavities have been developed with collaboration between our company and National Laboratory for High Energy Physics (KEK). The manufacturing procedure and the performance of 9-cell superconducting cavity are presented. The maximum accelerating gradient of 12 MV/m was attained in a cold test. (author)

  16. Niobium substituted magnetite as a strong heterogeneous Fenton catalyst for wastewater treatment

    Energy Technology Data Exchange (ETDEWEB)

    Rahim Pouran, Shima, E-mail: rahimpooran@yahoo.com [Chemical Engineering Department, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur (Malaysia); Abdul Aziz, A.R., E-mail: azizraman@um.edu.my [Chemical Engineering Department, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur (Malaysia); Wan Daud, Wan Mohd Ashri, E-mail: ashri@um.edu.my [Chemical Engineering Department, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur (Malaysia); Embong, Zaidi, E-mail: zembong@gmail.com [Faculty of Science, Technology and Human Development, University Tun Hussein Onn Malaysia, 86400 Johor (Malaysia)

    2015-10-01

    Highlights: • A series of Nb substituted magnetite samples were prepared and characterized. • Samples had inverse spinel structure, good magnetic property, and durability. • Increased surface area resulted in higher adsorption capacity of the samples. • Nb incorporation enhanced degradation of methylene blue through Fenton reaction. • The activity of the catalysts increased by increment in Nb content of the samples. - Abstract: In this study, a series of Nb substituted magnetites; Fe{sub 3−x}Nb{sub x}O{sub 4} (x = 0.0, 0.022, 0.049, 0.099, and 0.19) were prepared and characterized by XRD, BET surface area, TEM, VSM, XPS, and chemical experiments. The magnetite inverse spinel structure and magnetic property were maintained in all the synthetized samples. A significant decrease in crystal size (≈two times) and increase in specific surface area (≈three times) were observed with increased Nb content, resulting in higher adsorption capacity of the samples. In addition, the reactivity of the synthetized samples was examined through degradation of methylene blue solution using Fenton-like reaction. It was found that the incorporation of niobium significantly improved the degradation of methylene blue of which total MB removal was achieved within 180 min at higher molar ratios of Nb (x = 0.19). This could be attributed to the generated oxygen vacancies on the surface of catalysts, the contribution of the introduced Nb cations in Fenton oxidation cycle for regeneration of Fe{sup 2+} cations, and increase in adsorption capacity of the samples due to larger surface area. The MB degradation through Fe{sub 2.79}Nb{sub 0.19}O{sub 4}/H{sub 2}O{sub 2} system was well described by the pseudo-first-order equation in kinetics. All samples showed good stability under the studied pH conditions. The amount of niobium leached was not detectable in neutral and basic solutions and the samples could be reused in oxidation process for several times without a significant

  17. The Impact of Biofilms upon Surfaces Relevant to an Intermediate Level Radioactive Waste Geological Disposal Facility under Simulated Near-Field Conditions

    Directory of Open Access Journals (Sweden)

    Christopher J. Charles

    2017-07-01

    Full Text Available The ability of biofilms to form on a range of materials (cementious backfill (Nirex Reference Vault Backfill (NRVB, graphite, and stainless steel relevant to potential UK intermediate level radioactive waste (ILW disposal concepts was investigated by exposing these surfaces to alkaliphilic flocs generated by mature biofilm communities. Flocs are aggregates of biofilm material that are able to act as a transport vector for the propagation of biofilms. In systems where biofilm formation was observed there was also a decrease in the sorption of isosaccharinic acids to the NRVB. The biofilms were composed of cells, extracellular DNA (eDNA, proteins, and lipids with a smaller polysaccharide fraction, which was biased towards mannopyranosyl linked carbohydrates. The same trend was seen with the graphite and stainless steel surfaces at these pH values, but in this case the biofilms associated with the stainless steel surfaces had a distinct eDNA basal layer that anchored the biofilm to the surface. At pH 13, no structured biofilm was observed, rather all the surfaces accumulated an indistinct organic layer composed of biofilm materials. This was particularly the case for the stainless steel coupons which accumulated relatively large quantities of eDNA. The results demonstrate that there is the potential for biofilm formation in an ILW-GDF provided an initiation source for the microbial biofilm is present. They also suggest that even when conditions are too harsh for biofilm formation, exposed surfaces may accumulate organic material such as eDNA.

  18. Noburnium: Systems design of niobium superalloys

    Science.gov (United States)

    Misra, Abhijeet

    2005-11-01

    A systems-based approach, integrating quantum mechanical calculations with efficient experimentation, was employed to design niobium-based superalloys. The microstructural concept of gamma-gamma' nickel-based superalloys was adopted, where, the coherent gamma ' aluminides act both as the strengthening phase and a source of aluminum for Al2O3 passivation. Building on previous research, the selected bcc-type ordered aluminide was L2 1 structured Pd2HfAl phase. Comprehensive phase relations were measured on Nb-Pd-Hf-Al prototype alloys, and key tie-tetrahedra were identified. Aluminide precipitation in a bcc matrix was demonstrated in designed Nb+Pd2HfAl alloys. Thermodynamic databases were developed by integrating first-principles calculations with measured phase relations. Atomic volume models were developed for the bcc matrix and the Pd2HfAl phase and matrix elements which would reduce lattice misfit were identified. An experimental 2-phase alloy demonstrated a misfit of 3%. A modified Wagner's model was used to predict the required transient properties to form external Al2O3. The principal oxidation design goal was to decrease the oxygen permeability ( NSOx DO ) divided by the aluminum diffusivity (DAl) by 5 orders of magnitude. A multicomponent mobility database was developed to predict the diffusivities. Guided by first-principles calculations the effect of alloying elements on the oxygen diffusivity in Nb was measured, and the mobility database was experimentally validated. Based on the mobility database, it was found that increasing Al solubility in the bcc matrix greatly increased Al diffusivity. Alloying elements were identified that would increase Al solubility in the bcc matrix. Prototype alloys were prepared and the best oxidation performance was exhibited by a bcc+Nb2Al Nb-Hf-Al alloy, which exhibited parabolic oxidation behavior at 1300°C. The alloy was shown to have achieved the required 5 orders of magnitude reduction in the design parameter. The

  19. MEASUREMENT OF RF LOSSES DUE TO TRAPPED FLUX IN A LARGE-GRAIN NIOBIUM CAVITY

    International Nuclear Information System (INIS)

    Gianluigi Ciovati; Alex Gurevich

    2008-01-01

    Trapped magnetic field in superconducting niobium is a well known cause of radio-frequency (RF) residual losses. In this contribution, we present the results of RF tests on a single-cell cavity made of high-purity large grain niobium before and after allowing a fraction of the Earth's magnetic field to be trapped in the cavity during the cooldown below the critical temperature Tc. This experiment has been done on the cavity before and after a low temperature baking. Temperature mapping allowed us to determine the location of hot-spots with high losses and to measure their field dependence. The results show not only an increase of the low-field residual resistance, but also a larger increase of the surface resistance for intermediate RF field (higher ''medium field Qslope''), which depends on the amount of the trapped flux. These additional field-dependent losses can be described as losses of pinned vortices oscillating under the applied RF magnetic field

  20. Susceptibility of cold-worked zirconium-2.5 wt% niobium alloy to delayed hydrogen cracking

    International Nuclear Information System (INIS)

    Coleman, C.E.

    1976-01-01

    Notched tensile specimens of cold-worked zirconium-2.5 wt% niobium alloy have been stressed at 350 K and 520 K. At 350 K, above a possible threshold stress of 200 MPa, specimens exhibited delayed failure which was attributed to hydride cracking. Metallography showed that hydrides accumulated at notches and tips of growing cracks. The time to failure appeared to be independent of hydrogen content over the range 7 to 100 ppm hydrogen. Crack growth rates of about 10 -10 m/s deduced from fractography were in the same range as those necessary to fracture pressure tubes. The asymptotic stress intensity for delayed failure, Ksub(1H), appeared to be about 5 MPa√m. With this low value of Ksub(1H) small surface flaws may propagate in pressure tubes which contain large residual stresses. Stress relieving and modified rolling procedures will reduce the residual stresses to such an extent that only flaws 12% of the wall thickness or greater will grow. At 520 K no failures were observed at times a factor of three greater than times to failure at 350 K. Zirconium-2.5 wt% niobium appears to be safe from delayed hydrogen cracking at the reactor operating temperature. (author)

  1. Oxidation behavior of niobium aluminide intermetallics protected by aluminide and silicide diffusion coatings

    International Nuclear Information System (INIS)

    Li, Y.; Soboyejo, W.; Rapp, R.A.

    1999-01-01

    The isothermal and cyclic oxidation behavior of a new class of damage-tolerant niobium aluminide (Nb 3 Al-xTi-yCr) intermetallics is studied between 650 C and 850 C. Protective diffusion coatings were deposited by pack cementation to achieve the siliciding or aluminizing of substrates with or without intervening Mo or Ni layers, respectively. The compositions and microstructures of the resulting coatings and oxidized surfaces were characterized. The isothermal and cyclic oxidation kinetics indicate that uncoated Nb-40Ti-15Al-based intermetallics may be used up to ∼750 C. Alloying with Cr improves the isothermal oxidation resistance between 650 C and 850 C. The most significant improvement in oxidation resistance is achieved by the aluminization of electroplated Ni interlayers. The results suggest that the high-temperature limit of niobium aluminide-based alloys may be increased to 800 C to 850 C by aluminide-based diffusion coatings on ductile Ni interlayers. Indentation fracture experiments also indicate that the ductile nickel interlayers are resistant to crack propagation in multilayered aluminide-based coatings

  2. Electrochemical Energy Storage Applications of CVD Grown Niobium Oxide Thin Films.

    Science.gov (United States)

    Fiz, Raquel; Appel, Linus; Gutiérrez-Pardo, Antonio; Ramírez-Rico, Joaquín; Mathur, Sanjay

    2016-08-24

    We report here on the controlled synthesis, characterization, and electrochemical properties of different polymorphs of niobium pentoxide grown by CVD of new single-source precursors. Nb2O5 films deposited at different temperatures showed systematic phase evolution from low-temperature tetragonal (TT-Nb2O5, T-Nb2O5) to high temperature monoclinic modifications (H-Nb2O5). Optimization of the precursor flux and substrate temperature enabled phase-selective growth of Nb2O5 nanorods and films on conductive mesoporous biomorphic carbon matrices (BioC). Nb2O5 thin films deposited on monolithic BioC scaffolds produced composite materials integrating the high surface area and conductivity of the carbonaceous matrix with the intrinsically high capacitance of nanostructured niobium oxide. Heterojunctions in Nb2O5/BioC composites were found to be beneficial in electrochemical capacitance. Electrochemical characterization of Nb2O5/BioC composites showed that small amounts of Nb2O5 (as low as 5%) in conjunction with BioCarbon resulted in a 7-fold increase in the electrode capacitance, from 15 to 104 F g(-1), while imparting good cycling stability, making these materials ideally suited for electrochemical energy storage applications.

  3. Anomalously deep penetration of hydrogen into niobium under action of pulse high temperature hydrogen plasma

    International Nuclear Information System (INIS)

    Didyk, A.Yu.

    2011-01-01

    The method of elastic recoil detection (ERD) has been used for the study of storage and redistribution processes of hydrogen atoms under the influence of pulse high temperature hydrogen plasma obtained using the 'Plasma Focus' PF-4 set-up in three high purity niobium foils. It was established that with an increase of number of PF-4 set-up pulses there occur spreading and transfer of implanted hydrogen atoms to large depths in three Nb-foils which are significantly larger than the projected range of hydrogen ions (with the velocity ∼ 10 8 cm/s). The maximum hydrogen concentration up to 60 at. % is reached in the nearest to Ph-4 surface of the third Nb-foil at 20 impulses of the Ph-4 set-up. The observed phenomenon can be described by transfer of implanted hydrogen atoms under the action of powerful shock waves, created by pulse hydrogen plasma and (or) by accelerating hydrogen atom diffusion under the influence of compression straining wave at the front of the shock wave at redistribution of hydrogen atoms at large depths. Similar behavior was discovered and described also in series of nickel, vanadium, niobium and tantalum foils (two or three foils and more in a series) including series of foils from heterogeneous (different) materials, which were studied, too

  4. Computational studies of atmospherically-relevant chemical reactions in water clusters and on liquid water and ice surfaces.

    Science.gov (United States)

    Gerber, R Benny; Varner, Mychel E; Hammerich, Audrey D; Riikonen, Sampsa; Murdachaew, Garold; Shemesh, Dorit; Finlayson-Pitts, Barbara J

    2015-02-17

    CONSPECTUS: Reactions on water and ice surfaces and in other aqueous media are ubiquitous in the atmosphere, but the microscopic mechanisms of most of these processes are as yet unknown. This Account examines recent progress in atomistic simulations of such reactions and the insights provided into mechanisms and interpretation of experiments. Illustrative examples are discussed. The main computational approaches employed are classical trajectory simulations using interaction potentials derived from quantum chemical methods. This comprises both ab initio molecular dynamics (AIMD) and semiempirical molecular dynamics (SEMD), the latter referring to semiempirical quantum chemical methods. Presented examples are as follows: (i) Reaction of the (NO(+))(NO3(-)) ion pair with a water cluster to produce the atmospherically important HONO and HNO3. The simulations show that a cluster with four water molecules describes the reaction. This provides a hydrogen-bonding network supporting the transition state. The reaction is triggered by thermal structural fluctuations, and ultrafast changes in atomic partial charges play a key role. This is an example where a reaction in a small cluster can provide a model for a corresponding bulk process. The results support the proposed mechanism for production of HONO by hydrolysis of NO2 (N2O4). (ii) The reactions of gaseous HCl with N2O4 and N2O5 on liquid water surfaces. Ionization of HCl at the water/air interface is followed by nucleophilic attack of Cl(-) on N2O4 or N2O5. Both reactions proceed by an SN2 mechanism. The products are ClNO and ClNO2, precursors of atmospheric atomic chlorine. Because this mechanism cannot result from a cluster too small for HCl ionization, an extended water film model was simulated. The results explain ClNO formation experiments. Predicted ClNO2 formation is less efficient. (iii) Ionization of acids at ice surfaces. No ionization is found on ideal crystalline surfaces, but the process is efficient on

  5. Highly smooth Nb surfaces fabricated by buffered electropolishing

    International Nuclear Information System (INIS)

    Wu, Andy T; John Mammossor; Phillips, H.; Jean Delayen; Charles Reece; Amy Wilkerson; David Smith; Robert Ike

    2005-01-01

    It is demonstrated that highly smooth Nb surfaces can be obtained through Buffered ElectroPolishing (BEP) employing an electrolyte consisting of lactic, sulfuric, and hydrofluoric acids. Parameters that control the polishing process are optimized to achieve the smoothest surface finish with the help of surface observations using a scanning electron microscope and a Metallographic Optical Microscope (MOM). The polishing rate of BEP is determined to be 0.646 (micro)m/min that is much higher than 0.381 (micro)m/min achieved by the conventional ElectroPolishing (EP) process widely used in the Superconducting Radio Frequency (SRF) community. A high precision and large scan area 3-D profilometer is used to view morphology of the treated Nb surfaces. Statistical data, such as, rms, total indicator runout, and arithmetic mean deviation of the Nb surfaces are extracted from the profilometer images. It is found that Nb surfaces treated by BEP are an order of magnitude smoother than those treated by the optimized EP process. The chemical composition of the Nb surfaces after BEP is analyzed by static and dynamic Secondary Ion Mass Spectrometer (SIMS) systems. Cracking patterns of the Nb surfaces under different primary ion sources of Ga + , Au + , and Ar + are reported. The depth profile of the surface niobium oxides is studied through continuously monitoring niobium and its relevant oxides' peaks as a function of time. Dynamic SIMS results imply that the surface oxide structure of Nb may be more complicated than what usually believed and can be inhomogeneous. Preliminary results of BEP on Nb SRF single cell cavities and half-cells are reported. It is shown that smooth and bright surfaces can be obtained in 30 minutes when the electric field inside a SRF cavity is uniform during a BEP process. This study reveals that BEP is a highly promising technique for surface treatment on Nb SRF cavities to be used in particle accelerators

  6. Effect of free stall surface on daily activity patterns in dairy cows with relevance to lameness prevalence.

    Science.gov (United States)

    Cook, N B; Bennett, T B; Nordlund, K V

    2004-09-01

    Differences in behavior of nonlame cows, slightly lame cows, and moderately lame cows in 6 free stall barns with sand bedding (SAND) vs. 6 free stall barns with rubber-crumb geotextile mattress surfaces (MAT) were documented in Wisconsin dairy herds. All lactating cows in the 12 herds were observed and given a locomotion score based on a 4-point scale: 1 = nonlame, 2 = slightly lame, 3 = moderately lame, and 4 = severely lame. Herd least square means +/-SE for prevalence of clinical lameness (locomotion scores = 3 and 4) were 11.1 vs. 24.0 +/- 1.7% for herds using SAND vs. MAT surfaces, respectively. Subsets of 10 cows per herd with locomotion scores of 1 to 3 were observed via video cameras for 24-h periods. Cows in MAT herds spent more time standing in free stalls per day than cows in SAND herds. Differences in standing times were 0.73 h/d for cows that were not lame, 2.32 h/d for cows that were slightly lame, and 4.31 h/d for cows that were moderately lame in MAT herds compared with equivalent cows in SAND herds. In MAT herds, the increase in time spent standing in the stall in moderately lame cows was associated with a significant reduction in stall use sessions per day, which impacted daily lying time. Although cause and effect are not clear, these findings have implications for housing, comfort, and care of cows in dairy herds with different types of free stall surfaces.

  7. Excavating the surface-associated and secretory proteome of Mycobacterium leprae for identifying vaccines and diagnostic markers relevant immunodominant epitopes.

    Science.gov (United States)

    Rana, Aarti; Thakur, Shweta; Bhardwaj, Nupur; Kumar, Devender; Akhter, Yusuf

    2016-12-01

    For centuries, Mycobacterium leprae, etiological agent of leprosy, has been afflicting mankind regardless of extensive use of live-attenuated vaccines and antibiotics. Surface-associated and secretory proteins (SASPs) are attractive targets against bacteria. We have integrated biological knowledge with computational approaches and present a proteome-wide identification of SASPs. We also performed computational assignment of immunodominant epitopes as coordinates of prospective antigenic candidates in most important class of SASPs, the outer membrane proteins (OMPs). Exploiting the known protein sequence and structural characteristics shared by the SASPs from bacteria, 17 lipoproteins, 11 secretory and 19 novel OMPs (including 4 essential proteins) were identified in M. leprae As OMPs represent the most exposed antigens on the cell surface, their immunoinformatics analysis showed that the identified 19 OMPs harbor T-cell MHC class I epitopes and class II epitopes against HLA-DR alleles (54), while 15 OMPs present potential T-cell class II epitopes against HLA-DQ alleles (6) and 7 OMPs possess T-cell class II epitopes against HLA-DP alleles (5) of humans. Additionally, 11 M. leprae OMPs were found to have B-cell epitopes and these may be considered as prime candidates for the development of new immunotherapeutics against M. leprae. © FEMS 2016. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  8. Homogeneous and Supported Niobium Catalysts as Lewis Acid and Radical Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Wayne Tikkanen

    2006-12-31

    The synthesis of tetrachlorotetraphenylcyclopentadienyl group 5 metal complexes has been accomplished through two routes, one a salt metathesis with lithiumtetraphenylcyclopentadiende and the other, reaction with trimethyltintetraphenylcyclopentadiene. The reactants and products have been characterized by {sup 1}H and {sup 13}C({sup 1}H) NMR spectroscopy. The niobium complex promotes the silylcyanation of butyraldehyde. The grafting of metal complexes to silica gel surfaces has been accomplished using tetrakisdimethylamidozirconium as the metal precursor. The most homogeneous binding as determined by CP-MAS {sup 13}C NMR and infrared spectroscopy was obtained with drying at 500 C at 3 mtorr vacuum. The remaining amido groups can be replaced by reaction with alcohols to generate surface bound metal alkoxides. These bound catalysts promote silylcyanation of aryl aldehydes and can be reused three times with no loss of activity.

  9. Etching mechanism of niobium in coaxial Ar/Cl2 radio frequency plasma

    International Nuclear Information System (INIS)

    Upadhyay, J.; Im, Do; Popović, S.; Vušković, L.; Valente-Feliciano, A.-M.; Phillips, L.

    2015-01-01

    The understanding of the Ar/Cl 2 plasma etching mechanism is crucial for the desired modification of inner surface of the three dimensional niobium (Nb) superconductive radio frequency cavities. Uniform mass removal in cylindrical shaped structures is a challenging task because the etch rate varies along the direction of gas flow. The study is performed in the asymmetric coaxial radio-frequency (rf) discharge with two identical Nb rings acting as a part of the outer electrode. The dependence of etch rate uniformity on pressure, rf power, dc bias, Cl 2 concentration, diameter of the inner electrode, temperature of the outer cylinder, and position of the samples in the structure is determined. To understand the plasma etching mechanisms, we have studied several factors that have important influence on the etch rate and uniformity, which include the plasma sheath potential, Nb surface temperature, and the gas flow rate

  10. Etching mechanism of niobium in coaxial Ar/Cl2 radio frequency plasma

    Energy Technology Data Exchange (ETDEWEB)

    Upadhyay, Janardan [Old Dominion Univ., Norfolk, VA (United States); Im, Do [Old Dominion Univ., Norfolk, VA (United States); Popovic, Svetozar [Old Dominion Univ., Norfolk, VA (United States); Valente-Feliciano, Anne -Marie [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Phillips, H. Larry [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Vuskovic, Leposova [Old Dominion Univ., Norfolk, VA (United States)

    2015-03-18

    The understanding of the Ar/Cl2 plasma etching mechanism is crucial for the desired modification of inner surface of the three dimensional niobium (Nb) superconductive radio frequency cavities. Uniform mass removal in cylindrical shaped structures is a challenging task because the etch rate varies along the direction of gas flow. The study is performed in the asymmetric coaxial radio-frequency (rf) discharge with two identical Nb rings acting as a part of the outer electrode. The dependence of etch rate uniformity on pressure, rf power, dc bias, Cl2 concentration, diameter of the inner electrode, temperature of the outer cylinder, and position of the samples in the structure is determined. Furthermore, to understand the plasma etching mechanisms, we have studied several factors that have important influence on the etch rate and uniformity, which include the plasma sheath potential, Nb surface temperature, and the gas flow rate.

  11. Investigation of the superconducting properties of niobium radio-frequency cavities

    Science.gov (United States)

    Ciovati, Gianluigi

    Radio-frequency (rf) superconducting cavities are widely used to increase the energy of a charged particle beam in particle accelerators. The maximum gradients of cavities made of bulk niobium have constantly improved over the last ten years and they are approaching the theoretical limit of the material. Nevertheless, rf tests of niobium cavities are still showing some "anomalous" losses (so-called "Q-drop"), characterized by a marked increase of the surface resistance at high rf fields, in absence of field emission. A low temperature "in-situ" baking under ultra-high vacuum has been successfully applied by several laboratories to reduce those losses and improve the cavity's quality factor. Several models have been proposed to explain the cause of the Q-drop and the baking effect. We investigated the effect of baking on niobium material parameters by measuring the temperature dependence of a cavity's surface impedance and comparing it with the Bardeen-Cooper-Schrieffer's theory of superconductivity. It was found that baking allows interstitial oxygen to diffuse from the surface deeper into the bulk. This produces a significant reduction of the normal electrons' mean free path, which causes an increase of the quality factor. The optimum baking parameters are 120°C for 24-48 h. We were also able to identify the origin of the Q-drop as due to a high magnetic field, rather then electric field, by measuring the quality factor of a cavity as function of the rf field in a resonant mode with only magnetic field present on the surface. With the aid of a thermometry system, we were able to localize the losses in the high magnetic field region. We measured the Q-drop in cavities which had undergone different treatments, such as anodization, electropolishing and post-purification, and with different metallurgical properties and we study the effectiveness of baking in each case. As a result, none of the models proposed so far can explain all the experimental observations. We

  12. Surface-supported Ag islands stabilized by a quantum size effect: Their interaction with small molecules relevant to ethylene epoxidation

    Energy Technology Data Exchange (ETDEWEB)

    Shao, Dahai [Iowa State Univ., Ames, IA (United States)

    2013-05-15

    This dissertation focuses on how QSE-stabilized, surface-supported Ag nanoclusters will interact with ethylene or oxygen. Experiments are performed to determine whether the QSE-mediated Ag islands react differently toward adsorption of ethylene or oxygen, or whether the adsorption of these small molecules will affect the QSE-mediated stability of Ag islands. Studies of the interaction of oxygen with Ag/Si(111)-7×7 were previously reported, but these studies were performed at a low Ag coverage where 3D Ag islands were not formed. So the study of such a system at a higher Ag coverage will be a subject of this work. The interaction of ethylene with Ag/Si(111)-7×7, as well as the interaction of oxygen with Ag/NiAl(110) are also important parts of this study.

  13. Surface mechanical attrition treatment of tungsten and its behavior under low energy deuterium plasma implantation relevant to ITER divertor conditions

    Energy Technology Data Exchange (ETDEWEB)

    Xu, H.Y.; Yuan, Y.; Fu, B.Q.; Godfrey, A.; Liu, W. [Tsinghua Univ.. Lab. of Advanced Materials, Beijing (China); Zhang, Y.B. [Technical Univ. og Denmark. DTU Risoe Campus, Roskilde (Denmark); Tao, N.R. [Chinese Academy of Sciences, Shenyang (China)

    2012-11-01

    In the light of a foreseen application for tungsten (W) as an ITER divertor material samples have been plastically deformed by a surface mechanical attrition treatment (SMAT) and by cold rolling. The resistance to blister formation by low energy deuterium implantation in these samples has been examined, with the result that the structure is significantly improved as the structural scale is reduced to the nanometer range in the SMAT sample. The distribution of blisters in this sample is however bimodal, due to the formation of several very large blisters, which are heterogeneously distributed. The observations suggest that process optimization must be a next step in the development with a view to the application of plastically deformed W in a fusion reactor. (Author)

  14. Titanium–35niobium alloy as a potential material for biomedical implants: In vitro study

    International Nuclear Information System (INIS)

    Perez de Andrade, Dennia; Marotta Reis de Vasconcellos, Luana; Chaves Silva Carvalho, Isabel; Ferraz de Brito Penna Forte, Lilibeth; Souza Santos, Evelyn Luzia de; Falchete do Prado, Renata; Santos, Dalcy Roberto dos; Alves Cairo, Carlos Alberto; Rodarte Carvalho, Yasmin

    2015-01-01

    Research on new titanium alloys and different surface topographies aims to improve osseointegration. The objective of this study is to analyze the behavior of osteogenic cells cultivated on porous and dense samples of titanium–niobium alloys, and to compare them with the behavior of such type of cells on commercial pure titanium. Samples prepared using powder metallurgy were characterized using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), and metallographic and profilometer analyses. Osteogenic cells from newborn rat calvaria were plated over different groups: dense or porous samples composed of Ti or Ti–35niobium (Nb). Cell adhesion, cell proliferation, MTT assay, cell morphology, protein total content, alkaline phosphatase activity, and mineralization nodules were assessed. Results from XRD and EDS analysis confirmed the presence of Ti and Nb in the test alloy. Metallographic analysis revealed interconnected pores, with pore size ranging from 138 to 150 μm. The profilometer analysis detected the greatest rugosity within the dense alloy samples. In vitro tests revealed similar biocompatibility between Ti–35Nb and Ti; furthermore, it was possible to verify that the association of porous surface topography and the Ti–35Nb alloy positively influenced mineralized matrix formation. We propose that the Ti–35Nb alloy with porous topography constitutes a biocompatible material with great potential for use in biomedical implants. - Highlights: • Powder metallurgy is effective in producing porous biomaterials. • Ti–35Nb alloy improved mineralized matrix formation. • Porous surface favored a multidirectional pattern of cell spreading. • Porous surface Ti–35Nb alloy appears to be more favorable to bone formation than existing alloys

  15. Titanium–35niobium alloy as a potential material for biomedical implants: In vitro study

    Energy Technology Data Exchange (ETDEWEB)

    Perez de Andrade, Dennia; Marotta Reis de Vasconcellos, Luana; Chaves Silva Carvalho, Isabel; Ferraz de Brito Penna Forte, Lilibeth; Souza Santos, Evelyn Luzia de [Department of Bioscience and Oral Diagnosis, Institute of Science and Technology, UNESP — Univ Estadual Paulista, State University of São Paulo (UNESP), Av. Engenheiro Francisco José Longo, 777, São José dos Campos 12245-000, SP (Brazil); Falchete do Prado, Renata, E-mail: renatafalchete@hotmail.com [Department of Bioscience and Oral Diagnosis, Institute of Science and Technology, UNESP — Univ Estadual Paulista, State University of São Paulo (UNESP), Av. Engenheiro Francisco José Longo, 777, São José dos Campos 12245-000, SP (Brazil); Santos, Dalcy Roberto dos; Alves Cairo, Carlos Alberto [Division of Materials, Air and Space Institute, CTA, Praça Mal. do Ar Eduardo Gomes, 14, São José dos Campos 12904-000, SP (Brazil); Rodarte Carvalho, Yasmin [Department of Bioscience and Oral Diagnosis, Institute of Science and Technology, UNESP — Univ Estadual Paulista, State University of São Paulo (UNESP), Av. Engenheiro Francisco José Longo, 777, São José dos Campos 12245-000, SP (Brazil)

    2015-11-01

    Research on new titanium alloys and different surface topographies aims to improve osseointegration. The objective of this study is to analyze the behavior of osteogenic cells cultivated on porous and dense samples of titanium–niobium alloys, and to compare them with the behavior of such type of cells on commercial pure titanium. Samples prepared using powder metallurgy were characterized using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), and metallographic and profilometer analyses. Osteogenic cells from newborn rat calvaria were plated over different groups: dense or porous samples composed of Ti or Ti–35niobium (Nb). Cell adhesion, cell proliferation, MTT assay, cell morphology, protein total content, alkaline phosphatase activity, and mineralization nodules were assessed. Results from XRD and EDS analysis confirmed the presence of Ti and Nb in the test alloy. Metallographic analysis revealed interconnected pores, with pore size ranging from 138 to 150 μm. The profilometer analysis detected the greatest rugosity within the dense alloy samples. In vitro tests revealed similar biocompatibility between Ti–35Nb and Ti; furthermore, it was possible to verify that the association of porous surface topography and the Ti–35Nb alloy positively influenced mineralized matrix formation. We propose that the Ti–35Nb alloy with porous topography constitutes a biocompatible material with great potential for use in biomedical implants. - Highlights: • Powder metallurgy is effective in producing porous biomaterials. • Ti–35Nb alloy improved mineralized matrix formation. • Porous surface favored a multidirectional pattern of cell spreading. • Porous surface Ti–35Nb alloy appears to be more favorable to bone formation than existing alloys.

  16. Phototransformation of the sunlight filter benzophenone-3 (2-hydroxy-4-methoxybenzophenone) under conditions relevant to surface waters

    International Nuclear Information System (INIS)

    Vione, Davide; Caringella, Rosalinda; De Laurentiis, Elisa; Pazzi, Marco; Minero, Claudio

    2013-01-01

    The UV filter benzophenone-3 (BP3) has UV photolysis quantum yield Φ BP3 = (3.1 ± 0.3) · 10 −5 and the following second-order reaction rate constants: with • OH, k BP3, • OH = (2.0 ± 0.4) · 10 10 M −1 s −1 ; with the triplet states of chromophoric dissolved organic matter ( 3 CDOM*), k BP3, 3 CDOM* = (1.1 ± 0.1) · 10 9 M −1 s −1 ; with 1 O 2 , k BP3, 1 O 2 = (2.0 ± 0.1) · 10 5 M −1 s −1 , and with CO 3 −• , k BP3,CO 3 −• 7 M −1 s −1 . These data allow the modelling of BP3 photochemical transformation, which helps filling the knowledge gap about the environmental persistence of this compound. Under typical surface-water conditions, direct photolysis and reactions with • OH and 3 CDOM* would be the main processes of BP3 phototransformation. Reaction with • OH would prevail at low DOC, direct photolysis at intermediate DOC (around 5 mg C L −1 ), and reaction with 3 CDOM* at high DOC. If the reaction rate constant with CO 3 −• is near the upper limit of experimental measures (5 · 10 7 M −1 s −1 ), the CO 3 −• degradation process could be somewhat important for DOC −1 . The predicted half-life time of BP3 in surface waters under summertime conditions would be of some weeks, and it would increase with increasing depth and DOC. BP3 transformation intermediates were detected upon reaction with • OH. Two methylated derivatives were tentatively identified, and they were probably produced by reaction between BP3 and fragments arising from photodegradation. The other intermediates were benzoic acid (maximum concentration ∼ 10% of initial BP3) and benzaldehyde (1%). Highlights: • Benzophenone-3 is mainly photodegraded by direct photolysis, • OH and 3 CDOM*. • Two methylated isomers, benzaldehyde and benzoic acid detected as intermediates. • Phototransformation would be faster in shallow and DOM-poor water. • Half-life times of benzophenone-3 are in the range of weeks to a couple of months.

  17. Carbochlorination kinetics of tantalum and niobium pentoxides

    Directory of Open Access Journals (Sweden)

    Allain, E.

    1999-08-01

    Full Text Available The carbochlorination kinetics of pure Nb2O5 and Ta2O5 by gas mixture (C12 + CO + N2 between 380 and 1,000 °C is studied. A calculation of the standard free energy of the carbochlorination reactions is made. A diagram of the phases stability is drawn. The influence of the gas flow, temperature and the pardal pressure of Cl2 and CO at temperatures below 650 °C on the reaction rate is studied. The apparent activation energy is approximately 75 and 110 kJ/mol for Nb2Os and Ta2O5, respectively. At temperatures above 650°C the Arrhenius diagram presents an anomaly which may be attributed to the decomposition of the COCl2 formed in situ. The apparent reaction order of the carbochlorination of these oxides against Cl2+CO is approximately 2. The carbochlorination rates of these oxides are much greater than those of chlorination by Cl2 + N2. The carbochlorination kinetics of tin furnace slag leaching concentrates containing tantalum and niobium compounds are also studied and compared with the carbochlorination kinetics of the pure oxides.

    En este trabajo se estudia la cinética de carbocloruración del Nb2O5 y del Ta2O5 por la mezcla de gases (Cl2 + CO + N2 entre 380 y 1000°C. Se hace un cálculo de la energía libre estándar de carbocloruración y se dibujan los diagramas de equilibrio de fases. Se estudia la influencia del flujo de gas, la temperatura y la presión parcial de Cl2 y CO a temperaturas por debajo de 650°C sobre la velocidad de reacción. La energía de activación es aproximadamente 75 y 110 kJ/mol para el Nb2O5 y el Ta2O5, respectivamente. A temperaturas por encima de 650°C, el diagrama de Arrhenius presenta una anomalía que puede ser atribuida a la

  18. Investigating the structure and biocompatibility of niobium and titanium oxides as coatings for orthopedic metallic implants

    Energy Technology Data Exchange (ETDEWEB)

    Pradhan, D.; Wren, A.W.; Misture, S.T.; Mellott, N.P., E-mail: mellott@alfred.edu

    2016-01-01

    Applying sol gel based coatings to orthopedic metallic implant materials can significantly improve their properties and lifespan in vivo. For this work, niobium (Nb{sub 2}O{sub 5}) and titanium (TiO{sub 2}) oxides were prepared via solution processing in order to determine the effect of atomic arrangement (amorphous/crystalline) on bioactivity. Thermal evaluation on the synthesized materials identified an endotherm for Nb{sub 2}O{sub 5} at 75 °C with 40% weight loss below 400 °C, and minimal weight loss between 400 and 850 °C. Regarding TiO{sub 2} an endotherm was present at 92 °C with 25% weight loss below 400 °C, and 4% between 400 and 850 °C. Phase evolution was determined using High Temperature X-ray Diffraction (HT-XRD) where amorphous-Nb{sub 2}O{sub 5} (450 °C), hexagonal-Nb{sub 2}O{sub 5} (525 °C), orthorhombic-Nb{sub 2}O{sub 5} (650 °C), amorphous-TiO{sub 2} (275 °C) and tetragonal TiO{sub 2} (500 °C) structures were produced. Simulated body fluid (SBF) testing was conducted over 1, 7 and 30 days and resulted in positive chemical and morphological changes for crystalline Nb{sub 2}O{sub 5} (525 °C) and TiO{sub 2} (500 °C) after 30 days of incubation. Rod-like CaP deposits were observed on the surfaces using Scanning Electron Microscopy (FE-SEM) and Grazing Incidence-X-ray Diffraction (GI-XRD) shows that the deposits were X-ray amorphous. Cell viability was higher with the TiO{sub 2} (122%) samples when compared to the growing cell population while Nb{sub 2}O{sub 5} samples exhibited a range of viability (64–105%), partially dependent on materials atomic structure. - Highlights: • Niobium and titanium oxides were prepared to determine the effect of structure on bioactivity. • Simulated body fluid testing resulted in positive surface chemical and morphological changes. • Amorphous, rod-like CaP deposits were observed on the surfaces. • Niobium oxide exhibited a range of viability partially dependent on materials atomic structure.

  19. Phototransformation of the sunlight filter benzophenone-3 (2-hydroxy-4-methoxybenzophenone) under conditions relevant to surface waters

    Energy Technology Data Exchange (ETDEWEB)

    Vione, Davide, E-mail: davide.vione@unito.it [Università degli Studi di Torino, Dipartimento di Chimica, Via P. Giuria 5, 10125 Torino (Italy); Università degli Studi di Torino, Centro Interdipartimentale NatRisk, Via L. Da Vinci 44, 10095 Grugliasco (Italy); Caringella, Rosalinda; De Laurentiis, Elisa; Pazzi, Marco; Minero, Claudio [Università degli Studi di Torino, Dipartimento di Chimica, Via P. Giuria 5, 10125 Torino (Italy)

    2013-10-01

    The UV filter benzophenone-3 (BP3) has UV photolysis quantum yield Φ{sub BP3} = (3.1 ± 0.3) · 10{sup −5} and the following second-order reaction rate constants: with {sup •} OH, k{sub BP3,{sup •}} {sub OH} = (2.0 ± 0.4) · 10{sup 10} M{sup −1} s{sup −1}; with the triplet states of chromophoric dissolved organic matter ({sup 3}CDOM*), k{sub BP3,{sup 3}CDOM*} = (1.1 ± 0.1) · 10{sup 9} M{sup −1} s{sup −1}; with {sup 1}O{sub 2}, k{sub BP3,{sup 1}O{sub 2}} = (2.0 ± 0.1) · 10{sup 5} M{sup −1} s{sup −1}, and with CO{sub 3}{sup −•} , k{sub BP3,CO{sub 3{sup −}{sup •}}} < 5 · 10{sup 7} M{sup −1} s{sup −1}. These data allow the modelling of BP3 photochemical transformation, which helps filling the knowledge gap about the environmental persistence of this compound. Under typical surface-water conditions, direct photolysis and reactions with {sup •} OH and {sup 3}CDOM* would be the main processes of BP3 phototransformation. Reaction with {sup •} OH would prevail at low DOC, direct photolysis at intermediate DOC (around 5 mg C L{sup −1}), and reaction with {sup 3}CDOM* at high DOC. If the reaction rate constant with CO{sub 3}{sup −•} is near the upper limit of experimental measures (5 · 10{sup 7} M{sup −1} s{sup −1}), the CO{sub 3}{sup −•} degradation process could be somewhat important for DOC < 1 mg C L{sup −1}. The predicted half-life time of BP3 in surface waters under summertime conditions would be of some weeks, and it would increase with increasing depth and DOC. BP3 transformation intermediates were detected upon reaction with {sup •} OH. Two methylated derivatives were tentatively identified, and they were probably produced by reaction between BP3 and fragments arising from photodegradation. The other intermediates were benzoic acid (maximum concentration ∼ 10% of initial BP3) and benzaldehyde (1%). Highlights: • Benzophenone-3 is mainly photodegraded by direct photolysis, {sup •} OH and {sup 3}CDOM*.

  20. Unusual Application Of Ion Beam Analysis For The Study Of Surface Layers On Materials Relevant To Cultural Heritage

    International Nuclear Information System (INIS)

    Mathis, F.; Salomon, J.; Aucouturier, M.; Trocellier, P.

    2006-01-01

    Recently a new thematic of research -- intentional patinas on antic copper-base objects -- lead the AGLAE (Accelerateur Grand Louvre pour l'Analyse Elementaire) team of the C2RMF (Centre de Recherche et de Restauration des Musees de France) to improve its methods of analyzing thin surface layers both in their elemental composition and in-depth elemental distribution. A new beam extraction set-up containing a particle detector has been developed in order to use a 6 MeV alpha beam both in PIXE and RBS mode and to monitor precisely the ion dose received by the sample. Both RBS and ionization cross sections were assessed in order to make sure that the analysis can be quantitative. This set up allows great progresses in the understanding of both nature and structure of this very particular oxide layer obtained in the antiquity by chemical treatment on copper alloys, containing gold and/or silver and presenting very interesting properties of color and stability.Besides the non destructive properties of the IBA in external beam mode, this method of analyzing allows the study of samples in interaction with its environment. This was used to study the high temperature oxidation of Cu-Sn alloys using a furnace developed in order to heat a sample and analyze it in RBS mode at the same time. This new way of studying the growth of oxide layers permits to understand the oxidation mechanism of this system and to propose an experimental model for the identification of oxide layers due to an exposition to a high temperature, model needed for a long time by curators in charge of the study and the conservation of archaeological bronzes

  1. Separation of niobium and tantalum by paper chromatography and their following spectrographic determination

    International Nuclear Information System (INIS)

    Moroshkina, T.M.; Peres Sanfiel', F.

    1975-01-01

    The paper presents the results of an investigation into the use of water-saturated furfural to separate niobium and tantalum in a 1:1 ratio by means of ascending paper chromatography. The influence of sulphuric acid, ammonium fluoride and hydrofluoric acid concentrations on the completeness of the niobium and tantalum separation was investigated, the extent of the separation being checked by a spectral method. The results indicate that the use of furfural creates favourable conditions for niobium and tantalum separation. The purest tantalum is obtained at concentrations of sulphuric acid 600 k/l, hydrofluoric acid 4.6% and ammonium fluoride 30 g/l. To obtain pure niobium the acid concentrations remain the same but the quantity of ammonium fluoride is doubled. The fluoride ion concentration has a significant effect on the completeness of niobium and tantalum separation. The variation coefficient for the niobium determination is 14%, for the tantalum determination 1O% (author)

  2. Investigation of a thermoplastic-powder metallurgy process for the fabrication of porous niobium rods

    International Nuclear Information System (INIS)

    Nordin, D.R.

    1978-06-01

    The feasibility of using a thermoplastic-powder metallurgy technique for the fabrication of porous niobium rods was investigated. Some early problems were overcome to successfully extrude the polymer coated niobium powder into long lengths. The effects of certain process variables were investigated. Residual porosity and extrusion pressure were found to be regulated by the polymer fraction. The procedures for taking the extruded polystyrene--niobium rods through the heat treatments to the final, tin infiltrated stage are explained

  3. Chemical methods for the use of niobium from pressure vessel cladding as a fast neutron dosimeter

    International Nuclear Information System (INIS)

    Karnani, Hari

    1986-08-01

    the steel samples from the cladding of a pressure vessel of an operating nuclear power reactor were obtained by scraping. The cladding material of the pressure vessel contained about 0.5 % niobium. It was desired to use the niobium as a dosimeter for estimating fast fluences at the pressure vessel. The weak radiation from the reaction product 93m Nb cannot be measured in the presence of other elements and interfering activities. A method was developed to separate niobium from other metals present; the concentration and yield of niobium were determined spectrophotometrically. The irradiated niobium was electrodeposited from aqueous solutions on copper discs. The amount of the deposited niobium was determined by a radiochemical method which makes use of its own radioactivity - measured with a liquid scintillation counter - and the known starting mass of niobium. It was possible to determine the deposited niobium masses (5 to 200 microgram) with a desired degree of accuracy. The absolute emission rate of X-rays could then be measured without any self-absorption or interference from other activities. The mass of niobium on each preparate and its X-ray emission rate, later on, were used as basic experimental data for the estimation of last neutron doses at the pressure vessel

  4. Extractive-photometric determination of niobium with N-benzoylphenylhydroxylamine and lumogallion in alloyed steels

    International Nuclear Information System (INIS)

    Patratij, Yu.V.; Pilipenko, A.T.

    1978-01-01

    An extractive-photometric method has been developed to determine niobium (5) present as a heteroligand complex with N-benzoylphenylhydroxylamine (BPH) and lumogallion in alloyed steels. The method is based on preliminary extraction of niobium in a complex with BPH from concentrated HCl and subsequent determination of niobium in a 5-n (with respect to HCl) solution with lumogallion added. Sensitivity of the method is 2.0 μg of niobium in 10 ml of extract. The method has been tested on standard steels specimens

  5. Determination of niobium in rocks by an isotope dilution spectrophotometric method

    Science.gov (United States)

    Greenland, L.P.; Campbell, E.Y.

    1970-01-01

    Rocks and minerals are fused with sodium peroxide in the presence of carrierfree 95Nb. The fusion cake is leached with water and the precipitate dissolved in hydrofluoric-sulfuric acid mixture. Niobium is extracted into methyl isobutyl ketone and further purified by ion exchange. The amount of niobium is determined spectrophotometrically with 4-(2-pyridylazo)-resorcinol, and the chemical yield of the separations determined by counting 95Nb. This procedure is faster and less sensitive to interferences than previously proposed methods for determining niobium in rocks.The high purity of the separated niobium makes the method applicable to nearly all matrices. ?? 1970.

  6. HIP bonding for the different material between Niobium and Stainless steel

    International Nuclear Information System (INIS)

    Inoue, H.; Saito, K.; Abe, K.; Fujino, T.; Hitomi, N.; Kobayashi, Y.

    2000-01-01

    In the future advanced cryomodule for superconducting RF cavities, a helium vessel made from titanium or stainless steel has to be welded directly to the niobium cavity wall in order to be simple structure. For that, we need a transformer from niobium to titanium or stainless steel. Stainless steel will have many benefits if the reliable bonding to the niobium is developed. We have tested the niobium/stainless steel bonding by HIP (Hot Isostatic Pressing) with the heat shock between 1023K and 2K. The bonding interface was also observed by SEM. These test results will be presented. (author)

  7. A new process of electron beam refining of niobium

    International Nuclear Information System (INIS)

    Pinatti, D.G.

    1981-01-01

    A review of thermodynamic equilibrium, the kinetic theory and experimental results of the metal-gas interaction in refractory metals is presented. N 2 , H 2 and CO absorption and desorption take place by a reversible process while O 2 takes place by a irreversible process with atom absorption and metal oxide desorption. A new technology of electron beam refining of Niobium is proposed based on four points: 1) preparation of the aluminothermic reduced electrode, 2) zone refining in the first melt, 3) kinetic theory of refining in the following melts and 4) design of a compact furnace. Experimental results in a pilot plant of 300 KW have shown complete agreement with the proposed technology yielding a productivity 2.4 times larger than the value predicted by the conventional technology of electron beam refining of Niobium. (Author) [pt

  8. Distribution of Stress in Deformation Zone of Niobium Microalloyed Steel

    Science.gov (United States)

    Jandrlić, Ivan; Rešković, Stoja; Brlić, Tin

    2018-07-01

    Microalloyed steels today represent a significant part of total world production and processing of steel. Although widely used, there are scarce data on the stress distribution in the deformation zone of these steels. Research was carried out on two steel grades, both low-carbon structural steels with the same basic chemical composition, with one of them additionally microalloyed with niobium. Differences in the stress distribution in the deformation zone between two tested steels were continuously observed and measured using the methods of digital image correlation and thermography. It has been found out that niobium microalloyed steel has significantly more complex material flow and stress distribution in the deformation zone when compared to the plain low carbon steel.

  9. Crystallization of amorphous phase in niobium alloys with oxygen

    International Nuclear Information System (INIS)

    Dekanenko, V.M.; Samojlenko, Z.A.; Revyakin, A.V.

    1982-01-01

    Crystallization and subsequent phase transformations of amorphous phase during annealings in the system Nb-O are studied. It is shown that quenching from liquid state of niobium alloys with oxygen with a rate of 10 5 -10 6 K/s results in partial crystallization of the melt. Phase transition from amorphous to crystal state at 670 K in all probability takes place without the change of chemical composition. After crystallization the decomposition of oversaturated solid solution on the basis of NbO takes place with the separation of low- temperature modification, γ-Nb 2 O 5 . Niobium pentoxide of both modifications during prolong annealings at 770 K and short- time annealings higher 1070 K disappears completely [ru

  10. Magnetic Property in Large Array Niobium Antidot Thin Films

    Science.gov (United States)

    Tinghui, Chen; Hsiang-Hsi, Kung; Wei-Li, Lee; Institute of Physics, Academia Sinica, Taipei, Taiwan Team

    2014-03-01

    In a superconducting ring, the total flux inside the ring is required to be an integer number of the flux quanta. Therefore, a supercurrent current can appear within the ring in order to satisfy this quantization rule, which gives rise to certain magnetic response. By using a special monolayer polymer/nanosphere hybrid we developed previously, we fabricated a series of superconducting niobium antidot thin films with different antidot diameters. The antidots form well-ordered triangular lattice with a lattice spacing about 200 nm and extend over an area larger than 1 cm2, which enables magnetic detections simply by a SQUID magnetometer. We observed magnetization oscillation with external magnetic field due to the supercurrent screening effect, where different features for large and small antidot thin films were found. Detailed size and temperature dependencies of the magnetization in niobium antidot nanostructures will be presented.

  11. Measurement of Microwave Parameters of a Superconducting Niobium Cavity

    Science.gov (United States)

    Azaryan, N. S.; Baturitskii, M. A.; Budagov, Yu. A.; Demin, D. L.; Dem‧yanov, S. E.; Karpovich, V. A.; Kniga, V. V.; Krivosheev, R. M.; Lyubetskii, N. V.; Maksimov, S. I.; Pobol‧, I. L.; Rodionova, V. N.; Shirkov, G. D.; Shumeiko, N. M.; Yurevich, S. V.

    2017-01-01

    This paper describes a method for direct measurement of the amplitude-frequency characteristics and the Q factor of empty superconducting niobium radio frequency Tesla-type cavities. An automated measuring complex that permits recording the superconductivity effect and measuring high Q values has been developed. Measurements have been made of the Q factors of the investigated objects (the first domestic 1.3-GHz niobium cavities) at a level no lower than 0.1·109 (with a maximum value of 1.2·1010) and a level of relative losses lower than 130 dB (with a minimum factor of 139.7 dB) at liquid nitrogen temperature.

  12. Implantation of D+ ions in niobium and deuterium gas reemission

    International Nuclear Information System (INIS)

    Pisarev, A.A.; Tel'kovskij, V.G.

    1975-01-01

    This is a study of the implanting and reflex gasoisolation of D ions in niobium. It has been discovered that deutrium scope and gasoisolation are defined by several processes. An assumption is made that in ion bombarding conditions the implanting solutions are possible to exist and that deutrium can be replaced on the basis of niobium and hydrid compounds NbxDy. The portion of the particles entrained in the metal in one or another way depends on the ion energy. The dependence of the scope coefficient of n D + ions from the target temperature in the range of 290-1500 K was registered. An increase of the scope coefficient of the ions at high temperature with an increase of the ion energy was discovered

  13. Vanadium and heat treatments effect on elastic characteristics of niobium

    International Nuclear Information System (INIS)

    Vasil'eva, E.V.; Tret'yakov, V.I.; Prokoshkin, D.A.; Pustovalov, V.A.

    1975-01-01

    The effect of vanadium content and of heat treatment conditions on the elastic properties of niobium at temperatures of 20 to 800 deg C was studied. Nb-V alloys were produced by binary vacuum remelting. The Nb-V alloys have been then subjected to thermal treatment. The total degree of deformation amounts to about 95%. The specimens were tested with a view to determine their microhardness, specific electric resistance, elasticity limit and modulus of elasticity. The elastic limit of niobium rises when alloyed with vanadium. With the increase of vanadium content the elastic limit of the alloy becomes greater. Pre-crystallization annealing at 600 - 700 deg C considerably increases the elastic limit, which is explained by development of the thermally activated processes leading to a decrease of dislocation mobility and thereby to a strengthening of the alloy

  14. Distribution of Stress in Deformation Zone of Niobium Microalloyed Steel

    Science.gov (United States)

    Jandrlić, Ivan; Rešković, Stoja; Brlić, Tin

    2018-03-01

    Microalloyed steels today represent a significant part of total world production and processing of steel. Although widely used, there are scarce data on the stress distribution in the deformation zone of these steels. Research was carried out on two steel grades, both low-carbon structural steels with the same basic chemical composition, with one of them additionally microalloyed with niobium. Differences in the stress distribution in the deformation zone between two tested steels were continuously observed and measured using the methods of digital image correlation and thermography. It has been found out that niobium microalloyed steel has significantly more complex material flow and stress distribution in the deformation zone when compared to the plain low carbon steel.

  15. Niobium superconducting rf cavity fabrication by electrohydraulic forming

    CERN Document Server

    Cantergiani, E.; Léaux, F.; Perez Fontenla, A.T.; Prunet, S.; Dufay-Chanat, L.; Koettig, T.; Bertinelli, F.; Capatina, O.; Favre, G.; Gerigk, F.; Jeanson, A. C.; Fuzeau, J.; Avrillaud, G.; Alleman, D.; Bonafe, J.; Marty, P.

    2016-01-01

    Superconducting rf (SRF) cavities are traditionally fabricated from superconducting material sheets or made of copper coated with superconducting material, followed by trim machining and electron-beam welding. An alternative technique to traditional shaping methods, such as deep-drawing and spinning, is electrohydraulicforming (EHF). InEHF, half-cells areobtainedthrough ultrahigh-speed deformation ofblank sheets, using shockwaves induced in water by a pulsed electrical discharge. With respect to traditional methods, such a highly dynamic process can yield interesting results in terms of effectiveness, repeatability, final shape precision, higher formability, and reduced springback. In this paper, the first results of EHFon high purity niobium are presented and discussed. The simulations performed in order to master the multiphysics phenomena of EHF and to adjust its process parameters are presented. The microstructures of niobium half- cells produced by EHFand by spinning have been compared in terms of damage...

  16. Niobium nitride Josephson tunnel junctions with magnesium oxide barriers

    International Nuclear Information System (INIS)

    Shoji, A.; Aoyagi, M.; Kosaka, S.; Shinoki, F.; Hayakawa, H.

    1985-01-01

    Niobium nitride-niobium nitride Josephson tunnel junctions have been fabricated using amorphous magnesium oxide (a-MgO) films as barriers. These junctions have excellent tunneling characteristics. For example, a large gap voltage (V/sub g/ = 5.1 mV), a large product of the maximum critical current and the normal tunneling resistance (I/sub c/R/sub n/ = 3.25 mV), and a small subgap leakage current (V/sub m/ = 45 mV, measured at 3 mV) have been obtained for a NbN/a-MgO/NbN junction. The critical current of this junction remains finite up to 14.5 K

  17. Rapid radiochemical separation of zirconium-95 and niobium-95

    International Nuclear Information System (INIS)

    Downey, D.M.; McLaughlin, C.L.

    1983-01-01

    A rapid method for the quantitative separation of 95 Zr and 95 Nb has been developed. The method is based on the ion flotation of cationic zirconium complex ions with sodium lauryl sulfate (NaLS) from niobium which is masked with hydrogen peroxide. The separation was applied to mixtures of 95 Zr and 95 Nb initially in oxalic acid solution and quantitative recoveries of the radiochemically pure radioisotopes were obtained. (orig.)

  18. Rapid radiochemical separation of zirconium-95 and niobium-95

    Energy Technology Data Exchange (ETDEWEB)

    Downey, D.M.; McLaughlin, C.L.

    1983-01-01

    A rapid method for the quantitative separation of /sup 95/Zr and /sup 95/Nb has been developed. The method is based on the ion flotation of cationic zirconium complex ions with sodium lauryl sulfate (NaLS) from niobium which is masked with hydrogen peroxide. The separation was applied to mixtures of /sup 95/Zr and /sup 95/Nb initially in oxalic acid solution and quantitative recoveries of the radiochemically pure radioisotopes were obtained.

  19. Electrical and thermal properties of niobium-base cermets

    International Nuclear Information System (INIS)

    Skidan, B.S.; Vlasov, A.S.; Alekseev, V.A.; Myl'nikova, T.S.; Ryzhkov, Yu.F.

    1979-01-01

    Behaviour of corundum-niobium cermets containing 16-70 vol.% metal was studied at low temperatures. It is found that the given materials are superconductors with Tsub(k) 6-7 K but their resistivity before their transfer into superconducting state is determined by the metal concentration and is found within 10 -2 -10 -4 Ohm. cm. The cermet heat conductivity is found to increase with the metal content

  20. Magnetization measurement of niobium for superconducting cavity material evaluation

    International Nuclear Information System (INIS)

    Wake, Masayoshi; Saito, Kenji.

    1995-05-01

    A series of magnetization measurements on niobium materials for superconducting cavities was performed, and the method was found to be very useful for material evaluation. The effects of annealing, chemical polishing and machining were clearly observed by this method. The material quality and the processing of the material can be properly evaluated by measuring the magnetization. An observation of the Q-disease effect indicates the possibility of using this method for the studies beyond material evaluation. (J.P.N)

  1. Prototype 350 MHz niobium spoke-loaded cavities

    International Nuclear Information System (INIS)

    Delayen, J. R.; Kedzie, M.; Mammosser, J.; Piller, C.; Shepard, K. W.

    1999-01-01

    This paper reports the development of 350 MHz superconducting cavities of a spoke-loaded geometry, intended for the velocity range 0.2 < v/c < 0.6. Two prototype single-cell cavities have been designed, one optimized for velocity v/c = 0.4, and the other for v/c = 0.29. Construction of the prototype niobium cavities is nearly complete. Details of the design and construction are discussed, along with the results of cold tests

  2. Prototype 350 MHz niobium spoke-loaded cavities.

    Energy Technology Data Exchange (ETDEWEB)

    Delayen, J. R.; Kedzie, M.; Mammosser, J.; Piller, C.; Shepard, K. W.

    1999-05-10

    This paper reports the development of 350 MHz superconducting cavities of a spoke-loaded geometry, intended for the velocity range 0.2 < v/c < 0.6. Two prototype single-cell cavities have been designed, one optimized for velocity v/c = 0.4, and the other for v/c = 0.29. Construction of the prototype niobium cavities is nearly complete. Details of the design and construction are discussed, along with the results of cold tests.

  3. Dislocations and related defects in niobium oxide structures

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, J S; Hutchinson, J L; Lincoln, F J [Oxford Univ. (UK). Inorganic Chemistry Lab.

    1977-01-07

    Lattice images of the niobium oxides, structures based on the linkage of octahedral groups in continuous networks, occasionally contain features recognizable as dislocations. Since lattice imaging enables the microstructure to be resolved in greater detail, at the level of local structural organization, it is possible to determine the configuration, and also to infer the chemical composition, of dislocated areas. By treating the niobium oxide 'block' structures as superstructures of the ReO/sub 3/ (DO/sub 9/) type, the topology of dislocations can be expressed by relations between the insertion (or deletion) of one or more half-planes of cations, or of oxygen atoms only, changes in the number of crystallographic shear plane interfaces between blocks or columns, changes in (idealized) dimensions and any requisite distortion in the third dimension. Mapping the structure around a dislocation, from the lattice image, is directly equivalent to plotting the Burgers' circuit. In this way, the precise nature of a dislocating perturbation and its implications for the local chemical composition of the crystal can be directly identified. The method is exemplified by analysis of dislocations and of related extended defects of several types, associated with twinning phenomena, semicoherent intergrowth between different ReO/sub 3/-type superstructures and arrays building up a low angle boundary. The essential features of the analysis are not restricted to structures of the niobium oxide type, but can be extended to other types of polyhedron networks.

  4. Steady-state oxygen-solubility in niobium

    International Nuclear Information System (INIS)

    Schulze, K.; Jehn, H.

    1977-01-01

    During annealing of niobium in oxygen in certain temperature and pressure ranges steady states are established between the absorption of molecular oxygen and the evaporation of volatile oxides. The oxygen concentration in the niobium-oxygen α-solid solution is a function of oxygen pressure and temperature and has been redetermined in the ranges 10 -5 - 10 -2 Pa O 2 and 2,070 - 2,470 K. It follows differing from former results the equation csub(o) = 9.1 x 10 -6 x sub(po2) x exp (502000/RT) with csub(o) in at.-ppm, sub(po2) in Pa, T in K, R = 8.31 J x mol -1 x K -1 . The existence of steady states is limited to a temperature range from 1870 to 2470 K and to oxygen concentrations below the solubility limit given by solidus and solvus lines in the T-c diagram. In the experiments high-purity niobium wires with a specific electrical ratio rho (273 K)/rho(4.2 K) > 5,000 have been gassed under isothermal-isobaric conditions until the steady state has been reached. The oxygen concentration has been determined analytically by vacuum fusion extraction with platinum-flux technique as well as by electrical residual resistivity measurements at 4.2 K. (orig.) [de

  5. Irradiation swelling in self-ion irradiated niobium

    International Nuclear Information System (INIS)

    Bajaj, R.; Shiels, S.A.; Hall, B.O.; Fenske, G.R.

    1987-01-01

    This paper presents initial results of an investigation of swelling mechanisms in a model body centered cubic (bcc) metal, niobium, irradiated at elevated temperatures (0.3 T/sub m/ to 0.6 T/sub m/) where T/sub m/ = melting point in K. The objective of this work is to achieve an understanding of the elevated temperature swelling in bcc metals, which are the prime candidate alloys and composite matrix materials for space reactor applications. Niobium was irradiated with 5.3 MeV Nb ++ ions, at temperatures ranging from 700 0 C to 1300 0 C, to a nominal dose of 50 dpa at a dose rate of 6 x 10 -3 dpas. Swelling was observed over a temperature range of 700 0 C to 1200 0 C, with a peak swelling of 7% at 900 0 C. The microstructural data, obtained from transmission electron microscopy, were compared to the predictions of the theoretical model developed during this program. A reasonable agreement was obtained between the experimental measurements of swelling and theoretical predictions by adjusting both the niobium-oxygen binding energy and the incubation dose for swelling to realistic values

  6. Magnesium diboride coated bulk niobium: a new approach to higher acceleration gradient

    Science.gov (United States)

    Civale, Leonardo; Tan, Teng; Wolak, M.; Xi, Xiaoxing; Tajima, Tsuyoshi

    Bulk niobium Superconducting Radio-Frequency cavities are a leading accelerator technology. Their performance is limited by the cavity loss and maximum acceleration gradient, which are negatively affected by vortex penetration into the superconductor when the peak magnetic field at the cavity wall surface exceeds the vortex penetration field (Hvp). It has been proposed that coating the inner wall of an SRF cavity with superconducting thin films increases Hvp. In this work, we utilized Nb ellipsoids to simulate an inverse SRF cavity and investigate the effect of coating it with magnesium diboride layer on the vortex penetration field. A significant enhancement of Hvp was observed. At 2.8 K, Hvp increased from 2100 Oe for an uncoated Nb ellipsoid to 2700 Oe for a Nb ellipsoid coated with 200 nm thick MgB2 thin film. This finding creates a new route towards achieving higher acceleration gradient in SRF cavity accelerator beyond the theoretical limit of bulk Nb.

  7. Flux pinning characteristics in cylindrical niobium samples used for superconducting radio frequency cavity fabrication

    Science.gov (United States)

    Dhavale, Asavari S.; Dhakal, Pashupati; Polyanskii, Anatolii A.; Ciovati, Gianluigi

    2012-06-01

    We present the results from DC magnetization and penetration depth measurements of cylindrical bulk large-grain (LG) and fine-grain (FG) niobium samples used for the fabrication of superconducting radio frequency (SRF) cavities. The surface treatment consisted of electropolishing and low-temperature baking as they are typically applied to SRF cavities. The magnetization data are analyzed using a modified critical state model. The critical current density Jc and pinning force Fp are calculated from the magnetization data and their temperature dependence and field dependence are presented. The LG samples have lower critical current density and pinning force density compared to FG samples, favorable to lower flux trapping efficiency. This effect may explain the lower values of residual resistance often observed in LG cavities than FG cavities.

  8. Flux pinning characteristics in cylindrical ingot niobium used in superconducting radio frequency cavity fabrication

    Energy Technology Data Exchange (ETDEWEB)

    Dhavale Ashavai, Pashupati Dhakal, Anatolii A Polyanskii, Gianluigi Ciovati

    2012-04-01

    We present the results of from DC magnetization and penetration depth measurements of cylindrical bulk large-grain (LG) and fine-grain (FG) niobium samples used for the fabrication of superconducting radio frequency (SRF) cavities. The surface treatment consisted of electropolishing and low temperature baking as they are typically applied to SRF cavities. The magnetization data were fitted using a modified critical state model. The critical current density Jc and pinning force Fp are calculated from the magnetization data and their temperature dependence and field dependence are presented. The LG samples have lower critical current density and pinning force density compared to FG samples which implies a lower flux trapping efficiency. This effect may explain the lower values of residual resistance often observed in LG cavities than FG cavities.

  9. High frequency study of a short niobium/lead alloy line

    International Nuclear Information System (INIS)

    Mazuer, J.; Gilchrist, J.

    1974-01-01

    The resonant Q-factors of coaxial lines 1.42 m in length, consisting of fine niobium wires in superconducting tubes, have been studied. The lines are either open-circuited at each end or else short-circuited at each end. In either case the fundamental resonance and odd harmonics up to the ninth were observed. Various surface treatments of the wire made no appreciable difference to the Q value of the open-circuited lines. The short-circuited lines had much lower Q values due to imperfect short-circuiting contacts, and were used mainly to study the effect of a superposed direct current. This was appreciable even when the current was much smaller than the current that the wire would support without resistive transition. The additional high-frequency loss caused by the current was attributed to flux penetration. (author)

  10. Flux pinning characteristics in cylindrical niobium samples used for superconducting radio frequency cavity fabrication

    International Nuclear Information System (INIS)

    Dhavale, Asavari S; Dhakal, Pashupati; Ciovati, Gianluigi; Polyanskii, Anatolii A

    2012-01-01

    We present the results from DC magnetization and penetration depth measurements of cylindrical bulk large-grain (LG) and fine-grain (FG) niobium samples used for the fabrication of superconducting radio frequency (SRF) cavities. The surface treatment consisted of electropolishing and low-temperature baking as they are typically applied to SRF cavities. The magnetization data are analyzed using a modified critical state model. The critical current density J c and pinning force F p are calculated from the magnetization data and their temperature dependence and field dependence are presented. The LG samples have lower critical current density and pinning force density compared to FG samples, favorable to lower flux trapping efficiency. This effect may explain the lower values of residual resistance often observed in LG cavities than FG cavities. (paper)

  11. Active gas adsorption-promoted evaporation of tungsten and niobium in strong electric fields

    International Nuclear Information System (INIS)

    Ksenofontov, V.A.; Kul'ko, V.B.; Mikhajlovskij, I.M.

    1980-01-01

    Field-ion methods and pulsed mass-spectrometeric analysis are used to study field evaporation of tungsten and niobium affected by nitrogen and hydrogen. Active gas-promoted evaporation is found to take place at field intensities high enough for the field ionization of active gases. The evaporating field intensity is established to increase from 1.45x10 8 to 5.5x10 8 V/cm while passing from continuous to pulsed conditions of evaporation, this testifies to the change of the mechanism of the promoted evaporation. Under the effect of active gases, the evaporation rate essentially depends on the surface state. It is shown that in the microcrystals irradiated with 1-3 kV helium ions, the dependence of the evaporation rate of Nb in hydrogen on the field intensity gets monotonous. The obtained results are in fair agreement with the recombination model of a promoted evaporation [ru

  12. INVESTIGATION OF 'HOT-SPOTS' AS A FUNCTION OF MATERIAL REMOVAL IN A LARGE-GRAIN NIOBIUM CAVITY

    International Nuclear Information System (INIS)

    Gianluigi Ciovati; Peter Kneisel

    2006-01-01

    Poster - The performance of a single-cell cavity made of RRR > 200 large-grain niobium has been investigated as a function of material removal by buffered chemical polishing. Temperature maps of the cavity surface at 1.7 and 2.0 K were taken for each step of chemical etching and revealed several 'hot-spots', which contribute to the degradation of the cavity quality factor as a function of the RF surface field, mostly at high field levels. It was found that the number of 'hot-spots' decreased for larger material removal. Interestingly, the losses of the 'hot-spots' at different locations evolved differently for successive material removal. The cavity achieved peak surface magnetic fields of about of 130 mT and was limited mostly by thermal quench. By measuring the temperature dependence of the surface resistance at low field between 4.2 K and 1.7 K, the variation of niobium material parameters as a function of material removal could also be investigated. This contribution shows the results of the RF tests along with the temperature maps and the analysis of the losses caused by the 'hot-spots'.

  13. Effect of residual gas on structural, electrical and mechanical properties of niobium films deposited by magnetron sputtering deposition

    Science.gov (United States)

    Wang, Lanruo; Zhong, Yuan; Li, Jinjin; Cao, Wenhui; Zhong, Qing; Wang, Xueshen; Li, Xu

    2018-04-01

    Magnetron sputtering is an important method in the superconducting thin films deposition. The residual gas inside the vacuum chamber will directly affect the quality of the superconducting films. In this paper, niobium films are deposited by magnetron sputtering under different chamber residual gas conditions. The influence of baking and sputtering process on residual gas are studied as well. Surface morphology, electrical and mechanical properties of the films are analysed. The residual gas analysis result before the sputtering process could be regarded as a reference condition to achieve high quality superconducting thin films.

  14. Raman and photoelectron spectroscopic investigation of high-purity niobium materials: Oxides, hydrides, and hydrocarbons

    Science.gov (United States)

    Singh, Nageshwar; Deo, M. N.; Nand, Mangla; Jha, S. N.; Roy, S. B.

    2016-09-01

    We present investigations of the presence of oxides, hydrides, and hydrocarbons in high-purity (residual resistivity ratio, ˜300) niobium (Nb) materials used in fabrication of superconducting radio frequency (SRF) cavities for particle accelerators. Raman spectroscopy of Nb materials (as-received from the vendor as well as after surface chemical- and thermal processing) revealed numerous peaks, which evidently show the presence of oxides (550 cm-1), hydrides (1277 and 1385 cm-1: ˜80 K temperature), and groups of hydrocarbons (1096, 2330, 2710, 2830, 2868, and 3080 cm-1). The present work provides direct spectroscopic evidence of hydrides in the electropolished Nb materials typically used in SRF cavities. Raman spectroscopy thus can provide vital information about the near-surface chemical species in niobium materials and will help in identifying the cause for the performance degradation of SRF cavities. Furthermore, photoelectron spectroscopy was performed on the Nb samples to complement the Raman spectroscopy study. This study reveals the presence of C and O in the Nb samples. Core level spectra of Nb (doublet 3d5/2 and 3d3/2) show peaks near 206.6 and 209.4 eV, which can be attributed to the Nb5+ oxidation state. The core level spectra of C 1 s of the samples are dominated by graphitic carbon (binding energy, 284.6 eV), while the spectra of O 1 s are asymmetrically peaked near binding energy of ˜529 eV, and that indicates the presence of metal-oxide Nb2O5. The valence-band spectra of the Nb samples are dominated by a broad peak similar to O 2p states, but after sputtering (for 10 min) a peak appears at ˜1 eV, which is a feature of the elemental Nb atom.

  15. Quantifying the mechanism of phosphate monoester hydrolysis in aqueous solution by evaluating the relevant ab initio QM/MM free-energy surfaces.

    Science.gov (United States)

    Plotnikov, Nikolay V; Prasad, B Ram; Chakrabarty, Suman; Chu, Zhen T; Warshel, Arieh

    2013-10-24

    Understanding the nature of the free-energy surfaces for phosphate hydrolysis is a prerequisite for understanding the corresponding key chemical reactions in biology. Here, the challenge has been to move to careful ab initio QM/MM (QM(ai)/MM) free-energy calculations, where obtaining converging results is very demanding and computationally expensive. This work describes such calculations, focusing on the free-energy surface for the hydrolysis of phosphate monoesters, paying special attention to the comparison between the one water (1W) and two water (2W) paths for the proton-transfer (PT) step. This issue has been explored before by energy minimization with implicit solvent models and by nonsystematic QM/MM energy minimization, as well as by nonsystematic free-energy mapping. However, no study has provided the needed reliable 2D (3D) surfaces that are necessary for reaching concrete conclusions. Here we report a systematic evaluation of the 2D (3D) free-energy maps for several relevant systems, comparing the results of QM(ai)/MM and QM(ai)/implicit solvent surfaces, and provide an advanced description of the relevant energetics. It is found that the 1W path for the hydrolysis of the methyl diphosphate (MDP) trianion is 6-9 kcal/mol higher than that the 2W path. This difference becomes slightly larger in the presence of the Mg(2+) ion because this ion reduces the pKa of the conjugated acid form of the phosphate oxygen that accepts the proton. Interestingly, the BLYP approach (which has been used extensively in some studies) gives a much smaller difference between the 1W and 2W activation barriers. At any rate, it is worth pointing out that the 2W transition state for the PT is not much higher that the common plateau that serves as the starting point of both the 1W and 2W PT paths. Thus, the calculated catalytic effects of proteins based on the 2W PT mechanistic model are not expected to be different from the catalytic effects predicted using the 1W PT mechanistic

  16. Effect of pH value and delayed-action time on catalytic activity of tartrate niobium(5) complexes

    International Nuclear Information System (INIS)

    Alekseeva, I.I.; Chernysheva, L.M.; Bobkova, M.V.; Solomonov, V.A.

    1987-01-01

    Results of thermokinetic study of catalytic activity of niobium (5) tartrate solutions in the oxidation of ascorbic acid with hydrogen peroxide are presented. Addition of tartrate-ions to a concentration of 1x10 -2 M and higher in niobium (5) diluted solution enhances the catalytic activity of Nb(5). Alkaline tartrate solutions of niobium (5) may be used as standard solutions in determination of niobium microquantities by kinetic method

  17. Aging of the HF-H2SO4 electrolyte used for the electropolishing of niobium superconducting radio frequency cavities: Origins and cure

    Science.gov (United States)

    Eozénou, F.; Berry, S.; Antoine, C.; Gasser, Y.; Charrier, J.-P.; Malki, B.

    2010-08-01

    Electropolishing (EP) in the HF-H2SO4 electrolyte is the most desirable surface treatment for niobium superconducting radio frequency cavities yet demonstrated, in terms of performance and surface finish. However, the efficiency of the electrolyte declines quickly with time (decrease in removal rate, deterioration of the niobium surface, increased sulfur generation). Previous studies at CEA Saclay have highlighted the impact of the water content in EP mixtures rather than the content of dissolved niobium. Knowledge of the electrochemical system was improved thanks to studies using a rotating disk electrode (RDE). Measurements with a RDE give precious information concerning mass transport of the different ionic groups present in the solution. The performed measurements prove that EP is controlled by the diffusion of fluorine ions and the value of the related diffusion coefficient DF- was estimated for different mixtures. Electrochemical impedance spectroscopy (EIS) measurements were also performed with different EP mixtures. Both volt ampere metric and EIS measurements prove the central role of fluorine during EP and show that EP mechanisms evolve with the aging of the bath. Another major problem related to electrolytes is the formation of impurities such as sulfur. We have proved that working at a reduced voltage of 5 V does not alter cavity performance and makes it possible to reduce the undesirable particulate contamination in electrolytes and to increase their lifetime.

  18. Aging of the HF-H_{2}SO_{4} electrolyte used for the electropolishing of niobium superconducting radio frequency cavities: Origins and cure

    Directory of Open Access Journals (Sweden)

    F. Eozénou

    2010-08-01

    Full Text Available Electropolishing (EP in the HF-H_{2}SO_{4} electrolyte is the most desirable surface treatment for niobium superconducting radio frequency cavities yet demonstrated, in terms of performance and surface finish. However, the efficiency of the electrolyte declines quickly with time (decrease in removal rate, deterioration of the niobium surface, increased sulfur generation. Previous studies at CEA Saclay have highlighted the impact of the water content in EP mixtures rather than the content of dissolved niobium. Knowledge of the electrochemical system was improved thanks to studies using a rotating disk electrode (RDE. Measurements with a RDE give precious information concerning mass transport of the different ionic groups present in the solution. The performed measurements prove that EP is controlled by the diffusion of fluorine ions and the value of the related diffusion coefficient D_{F-} was estimated for different mixtures. Electrochemical impedance spectroscopy (EIS measurements were also performed with different EP mixtures. Both volt ampere metric and EIS measurements prove the central role of fluorine during EP and show that EP mechanisms evolve with the aging of the bath. Another major problem related to electrolytes is the formation of impurities such as sulfur. We have proved that working at a reduced voltage of 5 V does not alter cavity performance and makes it possible to reduce the undesirable particulate contamination in electrolytes and to increase their lifetime.

  19. Influence of different grained powders and pellets made of Niobium and Ti-42Nb on human cell viability

    Energy Technology Data Exchange (ETDEWEB)

    Markhoff, Jana, E-mail: markhoffj@gmail.com [University Medicine Rostock, Department of Orthopedics, Biomechanics and Implant Technology Laboratory, Doberaner Strasse 142, 18057 Rostock (Germany); Weinmann, Markus [H.C. Starck Tantalum and Niobium GmbH, Im Schleeke 78-91, 38642 Goslar (Germany); Schulze, Christian; Bader, Rainer [University Medicine Rostock, Department of Orthopedics, Biomechanics and Implant Technology Laboratory, Doberaner Strasse 142, 18057 Rostock (Germany)

    2017-04-01

    Nowadays, biomaterials can be used to maintain or replace several functions of the human body if necessary. Titanium and its alloys, i.e. Ti6Al4V are the most common materials (70 to 80%) used for structural orthopedic implants due to their unique combination of good mechanical properties, corrosion resistance and biocompatibility. Addition of β-stabilizers, e.g. niobium, can improve the mechanical properties of such titanium alloys further, simultaneously offering excellent biocompatibility. In this in vitro study, human osteoblasts and fibroblasts were cultured on different niobium specimens (Nb Amperit, Nb Ampertec), Nb sheets and Ti-42Nb (sintered and 3D-printed by selective laser melting, SLM) and compared with forged Ti6Al4V specimens. Furthermore, human osteoblasts were incubated with particulates of the Nb and Ti-42Nb specimens in three concentrations over four and seven days to imitate influence of wear debris. Thereby, the specimens with the roughest surfaces, i.e. Ti-42Nb and Nb Ampertec, revealed excellent and similar results for both cell types concerning cell viability and collagen synthesis superior to forged Ti6Al4V. Examinations with particulate debris disclosed a dose-dependent influence of all powders with Nb Ampertec showing the highest decrease of cell viability and collagen synthesis. Furthermore, interleukin synthesis was only slightly increased for all powders. In summary, Nb Ampertec (sintered Nb) and Ti-42Nb materials seem to be promising alternatives for medical applications compared to common materials like forged or melted Ti6Al4V. - Highlights: • Titanium and its alloys most common materials used for structural orthopedic implants • Addition of β-stabilizers to improve mechanical properties • Roughest surfaces, Nb ampertec and Ti-42Nb, with excellent results concerning cell viability and collagen synthesis • No cell-specific differences between human osteoblasts and fibroblasts • Niobium based powders with dose- and partly

  20. On the stabilization of niobium(V) solutions by zirconium(IV) and hafnium(IV)

    DEFF Research Database (Denmark)

    Sørensen, E.; Bjerre, A.B.

    1992-01-01

    Niobium cannot be separated from zirconium or hafnium when these elements occur together in solution with common anions such as chloride and sulphate. This is ascribed to the co-polymerization of niobium(V) and the hydrolysed ionic species of zirconium(IV) and hafnium(IV) to form colloidal...

  1. Alloy formation during chromium electrodeposition at niobium cathode in molten salts

    International Nuclear Information System (INIS)

    Kuznetsov, S.A.; Glagolevskaya, A.L.

    1993-01-01

    Alloy formation during electrodeposition of chromium at niobium cathode is studied in salt melts. It is shown that during chromium electrodeposition at niobium support intermetallic compound Cr 2 Nb is formed. Thermodynamic characteristics of Cr 0.66 Nb 0.33 alloy are determined. 10 refs., 1 fig

  2. Electric resistance of nickel and niobium in the temperature range of 300-1300 K

    International Nuclear Information System (INIS)

    Novikov, I.I.; Roshchupkin, V.V.; Mozgovoj, A.G.; Semashko, N.A.

    1982-01-01

    The results of experimental investigation of nickel and niobium electric resistance on the wire samples by the potentiometric method in the temperature range of 300-1300 K are presented. Experimental data processing by the least square method is carried out; approximating equations of temperature dependence of the nickel and niobium electric resistance are prepared

  3. The influence of impurities on the recovery of radiation defects in niobium

    International Nuclear Information System (INIS)

    Petzold, J.

    1986-01-01

    Pure niobium and doped niobium are irradiated with electrons (3 MeV) at a temperature of 7-8 K. During annealing the influence of the different impurities and of their doping concentration on the recovery of the electric conductivity are investigated. (BHO)

  4. Use of niobium to substitute vanadium in the steel for hot work AISI H3

    International Nuclear Information System (INIS)

    Branco, J.R.T.; Jesus, B.G. de

    1984-01-01

    Experimental results on austenitic grain size, quenching hardness and response to tempering measured on a H13 tool steel modified by niobium additions are described. It is shown that the replacement of 25 and 50% percent of the total vanadium by 0,05% of niobium does not change the response to quenching and tempering. (Author) [pt

  5. The solubility and sorption of nickel and niobium under high pH conditions

    International Nuclear Information System (INIS)

    Pilkington, N.J.; Stone, N.S.

    1990-01-01

    The solubilities of nickel and niobium were measured in a range of cement-equilibrated waters. For nickel the effects of cellulose degradation products and of chloride were examined and the dependence of nickel solubility on pH was measured. The sorption of nickel and niobium on to cement representative of the ''near field'' of a radioactive waste repository was also measured. (author)

  6. DT fusion neutron irradiation of BPNL niobium nickel and 316 stainless steel at 1750C

    International Nuclear Information System (INIS)

    MacLean, S.C.

    1977-01-01

    The DT fusion neutron irradiation at 175 0 C of 17 niobium wires, one niobium foil, 14 316 stainless steel wires, one 316 stainless steel foil, nine nickel wires, and two nickel foils from BPNL is described. The sample position, beam-on time, neutron dose record, and neutron fluence are given

  7. Niobium-Doped Hydroxyapatite Bioceramics: Synthesis, Characterization and In Vitro Cytocompatibility

    Directory of Open Access Journals (Sweden)

    Nádia S. V. Capanema

    2015-07-01

    Full Text Available Doping calcium phosphates with ionic species can play an important role in biological responses promoting alkaline phosphatase activity, and, therefore inducing the generation of new bone. Thus, in this study, the synthesis of niobium-doped hydroxyapatite (Nb-HA nanosize particles obtained by the precipitation process in aqueous media followed by thermal treatment is presented. The bioceramics were extensively characterized by X-ray diffraction, wavelength dispersive X-ray fluorescence spectrometry, Fourier transform infrared spectroscopy, scanning electron microscopy/energy dispersive X-ray spectroscopy analysis, transmission electron microscopy, atomic force microscopy and thermal analysis regarding their chemical composition, structure and morphology. The results showed that the precipitate dried at 110 °C was composed of amorphous calcium phosphate and HA, with polidisperse particles ranging from micro to nano dimensions. After the thermal treatment at 900 °C, the bioceramic system evolved predominantly to HA crystalline phase, with evident features of particle sintering and reduction of surface area. Moreover, the addition of 10 mol% of niobium salt precursor during the synthesis indicated the complete incorporation of the Nb(V species in the HA crystals with detectable changes in the original lattice parameters. Furthermore, the incorporation of Nb ions caused a significant refinement on the average particle size of HA. Finally, the preliminary cytocompatibility response of the biomaterials was accessed by human osteoblast cell culture using MTT and resazurin assays, which demonstrated no cytotoxicity of the Nb-alloyed hydroxyapatite. Thus, these findings seem promising for developing innovative Nb-doped calcium phosphates as artificial biomaterials for potential use in bone replacements and repair.

  8. The Influence of Grain Boundaries on the Properties of Superconducting Radio Frequency Cavity Niobium

    Science.gov (United States)

    Sung, Zu Hawn

    Grain boundaries (GBs) in niobium are multiply connected defects that may be responsible for significant performance degradation in superconducting radio frequency (RF) cavities. Magneto optical (MO) studies show that early flux penetration often occurs at GBs. One possible mechanism is that a locally reduced superconducting gap (Delta) at the GB reduces the depairing current density (Jb) and thus leads to a local reduction of the critical field. Alternatively vortices may penetrate the GB preferentially because of field enhancement at a GB groove, or for other reasons. In all these cases, the effect of high RF fields is to produce additional power dissipation, which in turn produces a reduction in quality factor (Q 0) and leads to a premature quench of the cavity. To further our understanding of the superconducting properties of SRF-quality Nb, we made extensive superconducting characterizations by magneto-optical imaging, which allowed assessment of the uniformity of properties on scales down to about 5 microm and by direct transport voltage-current methods in single and bi-crystals treated by standard cavity optimization treatments of BCP (buffered chemical treatment) and EP (electropolishing). We correlated these superconducting characterizations to microstructural properties using scanning laser and scanning electron microscopy and then thinned some samples to examine them at the nanometer scale using analytical transmission electron microscopy (TEM). We also developed special metallographic sample preparation techniques that allowed us to apply these experimental approaches to very soft superconducting RF niobium in the polished conditions characteristics of a real inner cavity surface. Using MO imaging, we found that GBs can preferentially admit flux penetration when the plane of a GB is aligned parallel to the vector of the external magnetic field. In DC transport in the superconducting state, we found preferential flux flow at the GB and could detect the

  9. Qualification of niobium materials for superconducting radio frequency cavity applications: View of a condensed matter physicist

    Science.gov (United States)

    Roy, S. B.; Myneni, G. R.

    2015-12-01

    We address the issue of qualifications of the niobium materials to be used for superconducting radio frequency (SCRF) cavity fabrications, from the point of view of a condensed matter physicist/materials scientist. We focus on the particular materials properties of niobium required for the functioning a SCRF cavity, and how to optimize the same properties for the best SCRF cavity performance in a reproducible manner. In this way the niobium materials will not necessarily be characterized by their purity alone, but in terms of those materials properties, which will define the limit of the SCRF cavity performance and also other related material properties, which will help to sustain this best SCRF cavity performance. Furthermore we point out the need of standardization of the post fabrication processing of the niobium-SCRF cavities, which does not impair the optimized superconducting and thermal properties of the starting niobium-materials required for the reproducible performance of the SCRF cavities according to the design values.

  10. Spectrographic determination of impurities in high-purity tantalum oxide and niobium oxide

    International Nuclear Information System (INIS)

    Anderson, S.T.G.; Russell, G.M.

    1990-01-01

    The development of spectrographic methods by direct current arc excitation and carrier distillation for the determination of impurities in tantalum and niobium oxides are described. Iron, silicon, aluminium, titanium, calcium, silver, tin, magnesium, and manganese can be determined in tantalum oxide and niobium oxide in concentrations ranging from 3 to 300 p.p.m. Niobium can be determined in tantalum oxide in concentrations ranging from 10 to 300 p.p.m. Tantalum cannot be determined in niobium oxide, and tungsten cannot be determined in either matrix as a result of the absence of sensitive lines in the spectra of these elements. Relative standard deviations of analyte element concentrations are in the region of 0,18 for tantalum oxide samples, and 0,13 for niobium oxide samples. A detailed laboratory method is included. 4 figs., 4 tabs., 3 refs

  11. Qualification of niobium materials for superconducting radio frequency cavity applications: View of a condensed matter physicist

    Energy Technology Data Exchange (ETDEWEB)

    Roy, S. B., E-mail: sbroy@rrcat.gov.in [Magnetic & Superconducting Materials Section, Materials & Advanced Accelerator Sciences Division, Raja Ramanna Centre for Advanced Technology, Indore 452013 (India); Myneni, G. R., E-mail: rao@jlab.org [Thomas Jefferson National Accelerator Facility, Newport News, Virginia (United States)

    2015-12-04

    We address the issue of qualifications of the niobium materials to be used for superconducting radio frequency (SCRF) cavity fabrications, from the point of view of a condensed matter physicist/materials scientist. We focus on the particular materials properties of niobium required for the functioning a SCRF cavity, and how to optimize the same properties for the best SCRF cavity performance in a reproducible manner. In this way the niobium materials will not necessarily be characterized by their purity alone, but in terms of those materials properties, which will define the limit of the SCRF cavity performance and also other related material properties, which will help to sustain this best SCRF cavity performance. Furthermore we point out the need of standardization of the post fabrication processing of the niobium-SCRF cavities, which does not impair the optimized superconducting and thermal properties of the starting niobium-materials required for the reproducible performance of the SCRF cavities according to the design values.

  12. Qualification of niobium materials for superconducting radio frequency cavity applications: View of a condensed matter physicist

    International Nuclear Information System (INIS)

    Roy, S. B.; Myneni, G. R.

    2015-01-01

    We address the issue of qualifications of the niobium materials to be used for superconducting radio frequency (SCRF) cavity fabrications, from the point of view of a condensed matter physicist/materials scientist. We focus on the particular materials properties of niobium required for the functioning a SCRF cavity, and how to optimize the same properties for the best SCRF cavity performance in a reproducible manner. In this way the niobium materials will not necessarily be characterized by their purity alone, but in terms of those materials properties, which will define the limit of the SCRF cavity performance and also other related material properties, which will help to sustain this best SCRF cavity performance. Furthermore we point out the need of standardization of the post fabrication processing of the niobium-SCRF cavities, which does not impair the optimized superconducting and thermal properties of the starting niobium-materials required for the reproducible performance of the SCRF cavities according to the design values

  13. Research and development of an ultra clean surface for RF cavities

    International Nuclear Information System (INIS)

    Miwa, Hajime; Ikeda, Tokumi; Suzuki, Takafusa; Kurosawa, Kiyosi; Kako, Eiji; Noguchi, Shuichi; Saito, Kenji; Kneisel, P.

    1993-01-01

    Suppression of field emission is essentially important in order to attain higher accelerating gradients. Therefore, elimination of residual dust particles on the inner surface of RF cavities is necessary. Surface of a niobium cavity was simulated in silicon wafers, and analysis of dust particles was performed by a particle counter used for semiconductor industries. Experimental results in various surface treatments and applications to niobium cavities are described in this paper. (author)

  14. Superconducting niobium in high rf magnetic fields

    International Nuclear Information System (INIS)

    Mueller, G.

    1988-01-01

    The benefit of superconducting cavities for accelerator applications depends on the field and Q/sub 0/ levels which can be achieved reliably in mass producible multicell accelerating structures. The presently observed field and Q/sub 0/ limitations are caused by anomalous loss mechanisms which are not correlated with the intrinsic properties of the pure superconductor but rather due to defects or contaminants on the superconducting surface. The ultimate performance levels of clean superconducting cavities built from pure Nb will be given by the rf critical field and the surface resistance of the superconductor. In the first part of this paper a short survey is given of the maximum surface magnetic fields achieved in single-cell cavities. The results of model calculations for the thermal breakdown induced by very small defects and for the transition to the defect free case is discussed in part 2. In the last chapter, a discussion is given for the rf critical field of Nb on the basis of the Ginzburg-Landau Theory. It is shown that not only purity but also the homogeneity of the material should become important for the performance of superconducting Nb cavities at field levels beyond 100mT. Measurement results of the upper critical field for different grades of commercially available Nb sheet materials are given. 58 references, 20 figures, 1 table

  15. Suppression of hydride precipitates in niobium superconducting radio-frequency cavities

    Science.gov (United States)

    Ford, Denise C.; Cooley, Lance D.; Seidman, David N.

    2013-10-01

    Niobium hydride is a suspected contributor to degraded niobium superconducting radio-frequency (SRF) cavity performance by Q slope and Q disease. The concentration and distribution of hydrogen atoms in niobium can be strongly affected by the cavity processing treatments. This study provides guidance for cavity processing based on density functional theory calculations of the properties of common processing impurity species—hydrogen, oxygen, nitrogen, and carbon—in the body-centered cubic (bcc) niobium lattice. We demonstrate that some fundamental properties are shared between the impurity atoms, such as anionic character in niobium. The strain field produced, however, by hydrogen atoms is both geometrically different and substantially weaker than the strain field produced by the other impurities. We focus on the interaction between oxygen and hydrogen atoms in the lattice, and demonstrate that the elastic interactions between these species and the bcc niobium lattice cause trapping of hydrogen and oxygen atoms by bcc niobium lattice vacancies. We also show that the attraction of oxygen to a lattice vacancy is substantially stronger than the attraction of hydrogen to the vacancy. Additionally, hydrogen dissolved in niobium tetrahedral interstitial sites can be trapped by oxygen, nitrogen and possibly carbon atoms dissolved in octahedral interstitial sites. These results indicate that the concentration of oxygen in the bcc lattice can have a strong impact on the ability of hydrogen to form detrimental phases. Based on our results and a literature survey, we propose a mechanism for the success of the low-temperature annealing step applied to niobium SRF cavities. We also recommend further examination of nitrogen and carbon in bcc niobium, and particularly the role that nitrogen can play in preventing detrimental hydride phase formation.

  16. Nanostructural features degrading the performance of superconducting radio frequency niobium cavities revealed by transmission electron microscopy and electron energy loss spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Trenikhina, Y., E-mail: yuliatr@fnal.gov [Physics Department, Illinois Institute of Technology, Chicago, Illinois 60616 (United States); Fermi National Accelerator Laboratory, Batavia, Illinois 60510 (United States); Romanenko, A., E-mail: aroman@fnal.gov [Fermi National Accelerator Laboratory, Batavia, Illinois 60510 (United States); Kwon, J.; Zuo, J.-M. [Materials Science and Engineering Department, University of Illinois, Urbana, Illinois 61801 (United States); Zasadzinski, J. F. [Physics Department, Illinois Institute of Technology, Chicago, Illinois 60616 (United States)

    2015-04-21

    Nanoscale defect structure within the magnetic penetration depth of ∼100 nm is key to the performance limitations of niobium superconducting radio frequency cavities. Using a unique combination of advanced thermometry during cavity RF measurements, and TEM structural and compositional characterization of the samples extracted from cavity walls, we discover the existence of nanoscale hydrides in electropolished cavities limited by the high field Q slope, and show the decreased hydride formation in the electropolished cavity after 120 °C baking. Furthermore, we demonstrate that adding 800 °C hydrogen degassing followed by light buffered chemical polishing restores the hydride formation to the pre-120 °C bake level. We also show absence of niobium oxides along the grain boundaries and the modifications of the surface oxide upon 120 °C bake.

  17. Nanostructural features degrading the performance of superconducting radio frequency niobium cavities revealed by transmission electron microscopy and electron energy loss spectroscopy

    Science.gov (United States)

    Trenikhina, Y.; Romanenko, A.; Kwon, J.; Zuo, J.-M.; Zasadzinski, J. F.

    2015-04-01

    Nanoscale defect structure within the magnetic penetration depth of ˜100 nm is key to the performance limitations of niobium superconducting radio frequency cavities. Using a unique combination of advanced thermometry during cavity RF measurements, and TEM structural and compositional characterization of the samples extracted from cavity walls, we discover the existence of nanoscale hydrides in electropolished cavities limited by the high field Q slope, and show the decreased hydride formation in the electropolished cavity after 120 °C baking. Furthermore, we demonstrate that adding 800 °C hydrogen degassing followed by light buffered chemical polishing restores the hydride formation to the pre-120 °C bake level. We also show absence of niobium oxides along the grain boundaries and the modifications of the surface oxide upon 120 °C bake.

  18. Nanostructural features degrading the performance of superconducting radio frequency niobium cavities revealed by transmission electron microscopy and electron energy loss spectroscopy

    International Nuclear Information System (INIS)

    Trenikhina, Y.; Romanenko, A.; Kwon, J.; Zuo, J.-M.; Zasadzinski, J. F.

    2015-01-01

    Nanoscale defect structure within the magnetic penetration depth of ~100 nm is key to the performance limitations of niobium superconducting radio frequency cavities. Using a unique combination of advanced thermometry during cavity RF measurements, and TEM structural and compositional characterization of the samples extracted from cavity walls, we discover the existence of nanoscale hydrides in electropolished cavities limited by the high field Q slope, and show the decreased hydride formation in the electropolished cavity after 120°C baking. Furthermore, we demonstrate that adding 800°C hydrogen degassing followed by light buffered chemical polishing restores the hydride formation to the pre-120°C bake level. We also show absence of niobium oxides along the grain boundaries and the modifications of the surface oxide upon 120°C bake

  19. Development of rubidium and niobium containing plastic foams. Final report

    International Nuclear Information System (INIS)

    Botham, R.A.; McClung, C.E.; Schwendeman, J.I.

    1978-01-01

    Rubidium fluoride and niobium metal-containing foam samples (rods and sheets) were prepared using two foam sytems: (1) hydrophilic polyurethanes prepared from W.R. Grace Co.'s Hypol prepolymers and (2) polyimides prepared from Monsanto Company's Skybond polyimide resin. The first system was used only for preparation of rubidium fluoride-containing foams while the second was used for both rubidium fluoride and niobium-containing foams. The niobium metal could readily be incorporated into the polyimide foam during molding, to produce foam sheets of the required dimensions and density. The rubidium fluoride-containing polyimide foams were preferably prepared by first rendering the molded polyimide foam hydrophilic with a postcuring treatment, then absorbing the rubidium fluoride from water solution. Similarly, rubidium fluoride was absorbed into the hydrophilic polyurethanes from water solution. Since the high reactive rubidium metal could not be employed, rubidium fluoride, which is very hygroscopic, was used instead, primarily because of its high rubidium content (approximately 82 weight percent). This was important in view of the low total densities and the high weight percentage rubidium required in the foam samples. In addition, at the later request of LLL, a block of rigid Hypol hydrophilic polyurethane foam (with a density of approximately 0.04 g/cm 3 and cell sizes = or <0.2 mm) was prepared without any metal or metal compounds in it. Two shipments of foam samples, which met or closely approximated the project specifications, were submitted to LLL during the course of this project. Information on these samples is contained in Table 1. A complete description of their preparation is given in the Experimental Results and Discussion Section

  20. Examination of temperature-induced shape memory of uranium--5.3-to 6.9 weight percent niobium alloys

    International Nuclear Information System (INIS)

    Hemperly, V.C.

    1976-01-01

    The uranium-niobium alloy system was examined in the range of 5.3-to-6.9 weight percent niobium with respect to shape memory, mechanical properties, metallography, Coefficients of linear thermal expansion, and differential thermal analysis. Shape memory increased with increasing niobium levels in the study range. There were no useful correlations found between shape memory and the other tests. Coefficients of linear thermal expansion tests of as-quenched 5.8 and 6.2 weight percent niobium specimens, but not 5.3 and 6.9 weight percent niobium specimens, had a contraction component on heating, but the phenomenon was not a contributor to shape memory

  1. Evidence of high-field radio-frequency hot spots due to trapped vortices in niobium cavities

    Directory of Open Access Journals (Sweden)

    G. Ciovati

    2008-12-01

    Full Text Available Superconducting radio-frequency (rf cavities made of high-purity niobium exhibit strong anomalous rf losses starting at peak surface magnetic fields of about 90–100 mT in the gigahertz range. This phenomenon is referred to as “Q drop.” Temperature maps of the cavity surface have revealed the presence of “hot spots” in the high magnetic field region of the cavities. Several models have been proposed over the years to explain this phenomenon but there is still no experimental evidence on the mechanisms behind such hot spots. In this work we show that at least some of the hot spots are due to trapped vortices responsible for the anomalous losses. Here we report experiments in which a local thermal gradient was applied to the hot spot regions of a cavity in order to displace the vortices. Temperature maps measured before and after applying the thermal gradient unambiguously show that the hot spots do move and change their intensities, allowing us to determine changes in the hot spot positions and strengths and their effect on the cavity performance. Results on a large-grain niobium cavity clearly show a different distribution and in some cases a weakening of the intensity of the “hot spots,” suggesting new ways of improving the cavity performance without additional material treatments.

  2. Niobium nitride Josephson junctions with silicon and germanium barriers

    International Nuclear Information System (INIS)

    Cukauskas, E.J.; Carter, W.L.

    1988-01-01

    Niobium nitride based junctions with silicon, germanium, and composite silicon/germanium barriers were fabricated and characterized for several barrier compositions. The current-voltage characteristics were analyzed at several temperatures using the Simmons model and numerical integration of the WKB approximation for the average barrier height and effective thickness. The zero voltage conductance was measured from 1.5 K to 300 K and compared to the Mott hopping conductivity model and the Stratton tunneling temperature dependence. Conductivity followed Mott conductivity at temperatures above 60 K for junctions with less than 100 angstrom thick barriers

  3. Chlorination of niobium oxide in the presence of carbon monoxide

    International Nuclear Information System (INIS)

    Freitas, L.R. de

    1984-01-01

    The chlorination kinetics of niobium pentoxide in the presence of carbon monoxide between 500-800 0 C of temperature is studied. The following variable that influences on the reaction rate are analysed: gas flow, geometry and volume of the Nb 2 O 5 samples, reaction temperature and composition of the chlorinated mixture. At the same time, two other materials were studied: the CaO.Nb 2 O 5 (synthetized in laboratory) and pyrochlorine concentrates. The three materials are compared for the chlorination method used. (M.A.C.) [pt

  4. Solidification process of a tool steel with niobium

    International Nuclear Information System (INIS)

    Makray, E.T.; Bresciani Filho, E.; Martinez Nazar, A.M.

    1984-01-01

    The solidification process of M2 high speed steel where tungsten was totally substituted by niobium was analysed. It occurs through a eutectic type reaction, in four steps. It was verified that one can apply the Coupled Zone Concept to explain the solification mechanism of this alloy: there is a primary phase (NbC), which is envolved by the other phase (ferrite) as a halo in order to send the composition back to the coupled growth region, where the binary eutectic forms. The last step is the formation of other compounds at the grain boundary. (Author) [pt

  5. Superconducting accelerometer using niobium-on-sapphire rf resonator

    International Nuclear Information System (INIS)

    Blair, D.G.

    1979-01-01

    An accelerometer is described which uses a rf niobium-on-sapphire resonator as its sensor element. The accelerometer uses a magnetically levitated spool as a test mass and the spool modulates the inductance of the resonator; its position is servo controlled to maintain the resonator at the external rf excitation frequency. The accelerometer has high sensitivity over the full audio frequency range, but is optimized for frequencies between 100 Hz and 1 kHz, where the calculated displacement sensitivity approaches 10 -15 cm for a 1 Hz measurement bandwidth. The system noise sources are analyzed and possible improvements are discussed

  6. Experiments on high power EB evaporation of niobium

    International Nuclear Information System (INIS)

    Kandaswamy, E.; Bhardwaj, R.L.; Ram Gopal; Ray, A.K.; Kulgod, S.V.

    2002-01-01

    Full text: The versatility of electron beam evaporation makes the deposition of many new and unusual materials possible. This technique offers freedom from contamination and precise control. High power electron guns are especially used for obtaining high evaporation rates for large area coatings. This paper deals with the coating experiments carried out on an indigenously developed high power strip electron gun with niobium as evaporant at 40 kW on S.S. substrate. The practical problems of conditioning the gun and venting the vacuum system after the high power operation are also discussed. The coating rate was calculated by weight difference method

  7. Reduction kinetics of molecular nitrogen by niobium(3) hydroxide

    International Nuclear Information System (INIS)

    Denisov, N.T.; Shuvalova, N.I.; Shilov, A.E.

    1987-01-01

    Formation kinetics of hydrazine and ammonia durng nitrogen reduction by niobium(3) hydroxide at 284.5 - 334 K in water-methanol alkaline medium is studied. It is shown that the KOH concentration growth results in the rise of the N 2 H 4 formation rate and the decrease of the NH 3 formation rate. The sequence of reactions with respect to [Nb(3)] and [OH - ], as well as the value of activation energy of hydrazine formation of (50±4 kJ/mole) are determined

  8. Terahertz time-domain transmission and reflection spectroscopy of niobium

    International Nuclear Information System (INIS)

    Hong, Tae Yoon; Choi, Kyu Jin; Park, Byoung Cheol; Ha, Tae Woo; Sim, Kyung Ik; Kim, Jea Hoon; Ha, Dong Gwang; Chang, Yonuk

    2013-01-01

    We have developed a terahertz time-domain spectroscopy (THz-TDS) system for transmission and reflection measurements of metallic thin films. Using our THz-TDS system, we studied the conventional superconductor niobium (Nb) in the normal state in the spectral range from 5 to 50 cm -1 . Both the real and imaginary parts of the conductivity are acquired without Kramers-Kronig analysis. Nb exhibits a nearly frequency independent real conductivity spectrum in the terahertz range, with a very small imaginary part.

  9. First prototype Copper-Niobium RF Superconducting Cavity

    CERN Multimedia

    1983-01-01

    This is the first RF superconducting cavity made of copper with a very thin layer of pure niobium deposited on the inner wall by sputtering. This new developpment lead to a considerable increase of performance and stability of superconducting cavities and to non-negligible economy. The work was carried out in the ISR workshop. This technique was adopted for the LEP II accelerating cavities. At the centre is Cristoforo Benvenuti, inventor of this important technology, with his assistants, Nadia Circelli and Max Hauer, carrying the sputtering electrode. See also 8209255, 8312339.

  10. Biodegradation of hydrocarbon mixtures in surface waters at environmentally relevant levels - Effect of inoculum origin on kinetics and sequence of degradation.

    Science.gov (United States)

    Birch, Heidi; Hammershøj, Rikke; Comber, Mike; Mayer, Philipp

    2017-10-01

    Biodegradation is a dominant removal process for many organic pollutants, and biodegradation tests serve as tools for assessing their environmental fate within regulatory risk assessment. In simulation tests, the inoculum is not standardized, varying in microbial quantity and quality, thereby potentially impacting the observed biodegradation kinetics. In this study we investigated the effect of inoculum origin on the biodegradation kinetics of hydrocarbons for five inocula from surface waters varying in urbanization and thus expected pre-exposure to petroleum hydrocarbons. A new biodegradation method for testing mixtures of hydrophobic chemicals at trace concentrations was demonstrated: Aqueous solutions containing 9 hydrocarbons were generated by passive dosing and diluted with surface water resulting in test systems containing native microorganisms exposed to test substances at ng-μg/L levels. Automated Headspace Solid Phase Microextraction coupled to GC-MS was applied directly to these test systems to determine substrate depletion relative to abiotic controls. Lag phases were generally less than 8 days. First order rate constants were within one order of magnitude for each hydrocarbon in four of the five waters but lower in water from a rural lake. The sequence of degradation between the 9 hydrocarbons showed similar patterns in the five waters indicating the potential for using selected hydrocarbons for benchmarking between biodegradation tests. Degradation half-times were shorter than or within one order of magnitude of BioHCwin predictions for 8 of 9 hydrocarbons. These results showed that location choice is important for biodegradation kinetics and can provide a relevant input to aquatic exposure and fate models. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. The Rieti Land Reclamation Authority relevance in the management of surface waters for the irrigation purposes of the Rieti Plain (Central Italy

    Directory of Open Access Journals (Sweden)

    Lucio Martarelli

    2016-09-01

    Full Text Available The Rieti Plain is crowned by calcareous-marly reliefs (Rieti and Sabini Mountains and represents an intra-Apennine Plio- Quaternary alluvial and fluvial-lacustrine basin formed after multistage extensional tectonic processes. This territory presents huge amounts of water resources (Velino and Turano rivers; several springs; Lungo and Ripasottile lakes, relics of ancient Lacus Velinus. The aquifers occurring in the reliefs often have hydraulic continuity with the Rieti plain groundwater (detected at about 1-4 m below ground surface, which has general flow directions converging from the reliefs to the lake sector. Hydraulic exchanges between groundwater and surface waters are variable in space and time and play a relevant role for groundwater resource distribution. The Rieti Land Reclamation Authority was instituted in 1929 by Royal Decree N. 34171-3835, and integrates eight former authorities, dating the end of 1800s. It contributes to maintain the reclamation actions in the Rieti Plain, which started with the realization of the Salto and Turano artificial reservoirs, along two left tributaries of Velino River. The hydroelectric energy production purposes struggle with the reclamation and flood mitigation activities in the plain. The Land Reclamation Authority actuated the Integrated Reclamation General Project through the realization of pumping stations, connection and drainage canals, forestry-hydraulic works, rural roads, movable dams along Velino River and irrigation ditches. The irrigation activities, granted by the derivation of 5 m3/s from the Velino River, are carried out through 194,000 hectares within the territory of 42 municipalities of the Rieti Province. The Rieti Land Reclamation Authority contributes to the irrigation needs and to the environmental and hydrogeological protection and monitoring.

  12. Determination of hafnium, molybdenum, and vanadium in niobium and niobium-based alloys by atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Ide, Kunikazu; Kobayashi, Takeshi; Sudo, Emiko.

    1985-01-01

    The analytical procedure is as follows: Weigh 1 g of a sample and put it into a 100 cm 3 PTFE beaker. Add 5 ml of distilled water and 5 ml of hydrofluoric acid, and then heat the solution on a hot plate, adding 3 ml of nitric acid dropwise. Dilute the solution to 100 cm 3 with distilled water. When hafnium is determined, add 2 g of diammonium titanium hexafluoride ((NH 4 ) 2 TiF 6 )) before dilution. Working standard solutions are prepared by adding the stock standard solutions of hafnium, molybdenum, and vanadium into niobium solutions. When hafnium is determined, add 2 g of (NH 4 ) 2 TiF 6 and the alloying elements in amounts corresponding to those in sample solutions into the working standard solutions. The tolerable amounts of hydrofluoric acid were 2.9 M, 2.1 M, and 3.1 M and those of nitric acid were 1.0 M, 1.6 M, and 1.6 M for hafnium, molybdenum, and vanadium, respectively. It was found that (NH 4 ) 2 TiF 6 greatly increased the sensitivity for hafnium determination. Niobium showed minus effect for hafnium and plus effect for molybdenum and vanadium. The atomic absorption of molybdenum and vanadium were not influenced by the presence of 20 % of each alloying element, while the atomic absorption of hafnium was given plus effect by 20 % of zirconium, iron, cobalt, nickel, manganese, chromium or vanadium and minus effect by 20 % tungsten. The analytical values of hafnium, molybdenum, and vanadium in niobium-based alloys by this method showed a good agreement with those by X-ray fluorescence analysis. The lower limits of determination (S/N=2) were 0.05, 0.001, and 0.002 % and the relative standard deviation were 3, 1, and 1.5 % for hafnium, molybdenum, and vanadium, respectively. (author)

  13. Progress on a high current density low cost Niobium3Tin conductor scaleable to modern niobium titanium production

    Science.gov (United States)

    Zeitlin, Bruce A.; Pyon, Taeyoung; Gregory, Eric; Scanlan, R. M.

    2002-05-01

    A number of configurations of a mono element internal tin conductor (MEIT) were fabricated designed to explore the effect of local ratio, niobium content, and tin content on the overall current density. Critical current densities on four configurations were measured, two to 17T. Current density as a function of filament size was also measured with filaments sizes ranging from 1.8 to 7.1 microns. A Nb60wt%Ta barrier was also explored as a means to reduce the high cost of the Tantalum barrier. The effectiveness of radial copper channels in high Nb conductors is also evaluated. Results are used to suggest designs for more optimized conductors.

  14. Sources of nitrous oxide and other climate relevant gases on surface area in a dairy free stall barn with solid floor and outside slurry storage

    Science.gov (United States)

    Schmithausen, Alexander J.; Trimborn, Manfred; Büscher, Wolfgang

    2018-04-01

    Livestock production systems in agriculture are one of the major emitters of greenhouse gases. So far, the focus of research in the dairy farm sector was primarily on ruminal methane (CH4) emissions. Emissions of nitrous oxide (N2O) usually arise from solid manure or in deep litter free stall barns. Release of N2O occurs as a result of interactions between organic material, nitrogen and moisture. Data of N2O emissions from modern dairy barns and liquid manure management systems are rare. Thus, the goal of this research was to determine the main sources of trace gas emissions at the dairy farm level, including N2O. Areas such as the scraped surface area where dry and wet conditions alternate are interesting. Possible sources of trace gases within and outside the barn were localised by measuring trace gas concentration rates from different dairy farm areas (e.g., areas covered with urine and excrement or slurry storage system) via the closed chamber technique. The results indicate typical emission ratios of carbon dioxide (CO2), CH4 and N2O in the various areas to generate comparable equivalent values. Calculated on the basis of nitrogen excretion from dairy cows, total emissions of N2O were much lower from barns than typically measured in fields. However, there were also areas within the barn with individual events and unexpected release factors of N2O concentrations such as urine patches, polluted areas and cubicles. Emission factors of N2O ranged from 1.1 to 5.0 mg m-2 d-1, respectively, for cleaned areas and urine patches. By considering the release factors of these areas and their proportion of the entire barn, total emission rates of 371 CO2-eq. LU-1 a-1, 36 CO2-eq. LU-1 a-1, and 1.7 kg CO2-eq. LU-1 a-1 for CO2, CH4 and N2O, respectively, were measured for the whole barn surface area. The CH4 emissions from surface area were stronger climate relevant comparing to N2O emissions, but compared to CH4 emissions from slurry storage or ruminal fermentation (not

  15. Electrodeposition of some metals and niobium superconducting alloys from molten fluorides

    International Nuclear Information System (INIS)

    Cohen, U.

    1978-01-01

    The major goal of this thesis was to study the feasibility of electrodeposition from molten fluorides of the pure elements niobium, aluminium, tin, germanium and silicon, and the niboium superconducting intermetallic compounds with these elements, and to prepare and study films of these materials in the form of coherent and uniform coatings. Decomposition potential measurements with a gold anode were carried out on the alkali fluoride solvent and the fluoride salt solutions of niobium, aluminum, tin, and germanium to provide important initial thermodynamic data. Attempts to codeposit niobium and aluminum invariably failed, niobium being the exclusive deposit in all cases. Codeposition of niobium--tin alloys was demonstrated. Of the four intermetallic compounds of the niobium--germanium system, three were obtained as single-phase coatings. The superconducting compound (A15 phase) was not successfully electrodeposited in a single-phase form. It was obtained, however, in phase-mixture coatings. Application of alternating square wave pulses produced substantial changes in the morphology of niobium deposits. Silicon electrocrystallization epitaxy (ECE) was demonstrated for the first time. Uniform, coherent, and well adherent coatings of polycrystalline Si with a grain diameter of up to 40 to 50 μm were plated onto nonalloying metal substrates, such as silver and tungsten.These processes offer some attractive features for both integrated circuit technology and silicon solar cell fabrication. Aluminum, tin, and germanium were also electrodeposited from molten fluorides

  16. Shape memory effects in a uranium + 14 at. % niobium alloy

    International Nuclear Information System (INIS)

    Vandermeer, R.A.; Ogle, J.C.; Snyder, W.B. Jr.

    1978-01-01

    There is a class of alloys that, on cooling from elevated temperatures, experience a martensitic phase change. Some of these, when stressed in the martensitic state to an apparently plastic strain, recover their predeformed shape simply by heating. This striking shape recovery is known as the ''shape memory effect'' (SME). Up to a certain limiting strain, epsilon/sub L/, 100% shape recovery may be accomplished. This memory phenomenon seems to be attributable to the thermoelastic nature of and deformational modes associated with the phase transformation in the alloy. Thus, shape recovery results when a stress-biased martensite undergoes a heat-activated reversion back to the parent phase from which it originated. There are uranium alloys that demonstrate SME-behavior. Uranium-rich, uranium--niobium alloys were the first to be documented; New experimental observations of SME in a polycrystalline uranium--niobium alloy are presented. This alloy can exhibit a two-way memory under cetain circumstances. Additional indirect evidence is presented suggesting that the characteristics of the accompanying phase transformation in this alloy meet the criteria or ''selection rules'' deemed essential for SME

  17. Niobium superconducting rf cavity fabrication by electrohydraulic forming

    Science.gov (United States)

    Cantergiani, E.; Atieh, S.; Léaux, F.; Perez Fontenla, A. T.; Prunet, S.; Dufay-Chanat, L.; Koettig, T.; Bertinelli, F.; Capatina, O.; Favre, G.; Gerigk, F.; Jeanson, A. C.; Fuzeau, J.; Avrillaud, G.; Alleman, D.; Bonafe, J.; Marty, P.

    2016-11-01

    Superconducting rf (SRF) cavities are traditionally fabricated from superconducting material sheets or made of copper coated with superconducting material, followed by trim machining and electron-beam welding. An alternative technique to traditional shaping methods, such as deep-drawing and spinning, is electrohydraulic forming (EHF). In EHF, half-cells are obtained through ultrahigh-speed deformation of blank sheets, using shockwaves induced in water by a pulsed electrical discharge. With respect to traditional methods, such a highly dynamic process can yield interesting results in terms of effectiveness, repeatability, final shape precision, higher formability, and reduced springback. In this paper, the first results of EHF on high purity niobium are presented and discussed. The simulations performed in order to master the multiphysics phenomena of EHF and to adjust its process parameters are presented. The microstructures of niobium half-cells produced by EHF and by spinning have been compared in terms of damage created in the material during the forming operation. The damage was assessed through hardness measurements, residual resistivity ratio (RRR) measurements, and electron backscattered diffraction analyses. It was found that EHF does not worsen the damage of the material during forming and instead, some areas of the half-cell have shown lower damage compared to spinning. Moreover, EHF is particularly advantageous to reduce the forming time, preserve roughness, and to meet the final required shape accuracy.

  18. Niobium-base superalloys via powder metallurgy technology

    International Nuclear Information System (INIS)

    Loria, E.A.

    1987-01-01

    This paper provides some insight into an area that has been neglected, namely the possibility of developing high-strength, niobium-base alloys by improved oxidation resistance via the consolidation of rapidly solidified powders. Powder metallurgy (P/M) is an attractive processing technique because of its flexibility and versatility, and it may provide the alloys with properties and workability not obtainable via metal casting. A critical review of both U.S. and Russian literature is presented along with suggestions on the most promising compositions and processing techniques available to meet these competing goals. Previous work on many niobium alloys reveals that long term properties are retained well above those obtained on nickel-base superalloys. Cast and wrought alloys extend specific strength beyond 1200 0 C (2200 0 F), but lack oxidation resistance. Remarkable oxidation resistance is obtained, however, on miniature castings of certain ternary alloys which are too brittle for any processing. A better understanding of the oxidation mechanism is necessary before the proper P/M (RST) approach is taken on compositions which could provide compatibility between the two competing goals through grain refinement and a homogeneous distribution of the contributory phases. Finally, ways to up-scale production of Nb powder are discussed, including thermodynamic feasibility for the direct reduction of NbCl/sub 5/ in a 1.5 MW plasma reactor

  19. Niobium-based catalysts prepared by reactive radio-frequency magnetron sputtering and arc plasma methods as non-noble metal cathode catalysts for polymer electrolyte fuel cells

    International Nuclear Information System (INIS)

    Ohnishi, Ryohji; Katayama, Masao; Takanabe, Kazuhiro; Kubota, Jun; Domen, Kazunari

    2010-01-01

    Two vacuum methods, reactive radio-frequency (RF) magnetron sputtering and arc plasma deposition, were used to prepare niobium-based catalysts for an oxygen reduction reaction (ORR) as non-noble metal cathodes for polymer electrode fuel cells (PEFCs). Thin films with various N and O contents, denoted as NbO x and Nb-O-N, were prepared on glassy carbon plates by RF magnetron sputtering with controlled partial pressures of oxygen and nitrogen. Electrochemical measurements indicated that the introduction of the nitrogen species into the thin film resulted in improved ORR activity compared to the oxide-only film. Using an arc plasma method, niobium was deposited on highly oriented pyrolytic graphite (HOPG) substrates, and the sub-nanoscale surface morphology of the deposited particles was investigated using scanning tunneling microscopy (STM). To prepare practical cathode catalysts, niobium was deposited on carbon black (CB) powders by arc plasma method. STM and transmission electron microscopy observations of samples on HOPG and CB indicated that the prepared catalysts were highly dispersed at the atomic level. The onset potential of oxygen reduction on Nb-O-N/CB was 0.86 V vs. a reversible hydrogen electrode, and the apparent current density was drastically improved by the introduction of nitrogen.

  20. Reduction of Al2O3 in niobium--lithium systems at 10000C

    International Nuclear Information System (INIS)

    Selle, J.E.; DeVan, J.H.

    1977-07-01

    Various grades of aluminum oxide (Al 2 O 3 ) were sealed inside capsules of niobium and niobium-1% zirconium alloy which were then exposed to liquid lithium for 3000 hr at 1000 0 C. Similar unsealed capsules were exposed to a high vacuum. Reduction of the Al 2 O 3 occurred in the lithium-treated capsules, but no reaction occurred in the vacuum-treated capsules. Metallography and electron-microprobe analysis showed that reaction products in the form of compounds of niobium, aluminum, and zirconium were formed. Lithium acted as a sink for oxygen

  1. Photometric determination of niobium in materials with high content of phosphorus

    International Nuclear Information System (INIS)

    Navrotskaya, V.A.; Aleksandrova, E.I.; Kletenik, Yu.B.

    1982-01-01

    To determine niobium in various samples of niobium concentrates with a high phosphorus content, a photometric method with pyridylazoresorcinol (PAR) is used. It is shown that all the elements indicated (Fe, Si, Ti, Al, Ca) including phosphorus do not interfere with the niobium determination with the use of PAR. The method has been tried on artificial samples with different content of the base components. Variation coefficient constitutes 4.5%. No systematic errors, due to a high content of any concomitant element, are detected. The determination threshold is 10 - 2 %

  2. Technical assessment of niobium alloys data base for fusion reactor applications

    Energy Technology Data Exchange (ETDEWEB)

    Pionke, L J; Davis, J W

    1979-08-01

    Refractory metals are one class of material to be developed in the Alloy Development For Irradiation Performance (ADIP) program recently initiated. A principal purpose of the assessment reported herein is to establish the existing data base for niobium alloys in order to help guide the work to be performed in the ADIP program. Major ADIP decisions include alloy selection/modification and irradiated/unirradiated material testing. This Assessment addressed the topics of: (1) niobium alloy development history and niobium metallurgy, (2) unirradiated mechanical properties, (3) irradiated properties, (4) corrosion, and (5) environmental effects.

  3. Niobium effects on the austenitic grain growth and hardenability of steels for mechanical construction

    International Nuclear Information System (INIS)

    Vieira, R.R.; Arruda Camargo, L.M. de; Oliveira Junior, G.G. de; Dias Filho, A.G.C.

    1983-01-01

    The austenitic grain growth and hardenability of SAE 86XX and 5120 steels modified with 0,001 to 0,20 per-cent niobium content were studied when submitted to case hardening and quenching heat treatments. The results show that niobium controlS the austenite grain size better than molybdenum up to 950 0 C austenitization temperature. The hardenability, evaluated by the Jominy test which the modified SAE 8640 steels, is more strongly inflencied by the grain refining resulting from niobium addition than by any other supposed effect. (Author) [pt

  4. Particularities of the recombination electron emission of single crystals of tungsten and niobium

    International Nuclear Information System (INIS)

    Mashtakova, V.A.; Shishkin, B.B.

    1984-01-01

    The volt-ampere characteristics (vac) of vacuum diodes with metal single cr ystal electrodes are measured. Studied were: crystallographic plane (100) of a tungsten single crystal and (110) face of a niobium single crystal. Anomalies o n the initial portions of the vac of diodes with niobium ((110) face) electrodes are discovered. Anomalies appear at cathode temperatures t exceeding characteri stic thermoionic temperatures thetasub(the). The ''steps'' on the vac at t >thetasub(the) for tungsten are considered as voltage jumps. The ''steps'' on th e vac for niobium are considered as diode current jumps due to fluctuation processes resulting in the formation of small amount of slow electrons

  5. Investigation into kinetics of sorption of some radionuclides by mixed sorbents based on amorphous niobium phosphate

    International Nuclear Information System (INIS)

    Belkina, R.M.; Sukharev, Yu.I.; Egorov, Yu.V.; Plotnikov, V.I.

    1977-01-01

    A study has been made of kinetics of sorption of radionuclides 110 Ag, 60 Co, and 51 Cr by samples of amorphous stoichiometric niobium (5) phosphate. Ratios of the concentration conductivity to the mean radius of sorbent particles were calculated which are proportional to diffusivities. Increased specificity towards Cr 3+ ions of samples of ion exchangeable niobium phosphate containing cerium and treated with 0.1N HCl was established. This effect was explained by formation and subsequent destruction of the copolymer oxo-ol matrix of niobium and cerium, as a result of which a gel is formed with mosaic structure being favourable for sorption of three-charged ions

  6. Linkage of molecular units in the chemistry of niobium and tantalum cluster halides

    International Nuclear Information System (INIS)

    Perrin, C.; Sergent, M.

    1991-01-01

    In low valency niobium and tantalum halides, interunit linkages are observed between the (Me 6 X 12 )X 6 units. They are insulators and interesting magnetic properties are observed, due to the intrinsic potential magnetism of the Me 6 cluster and depending on the inserted cations, for instance rare earths in MM'Nb 6 Cl 18 (M = monovalent cation, M' = rare earth). Of special interest are the niobium iodides which exhibit (Me 6 X 8 )X 6 units, an exception in the niobium chemistry; interesting properties have been reported for some of these iodides

  7. Development of low angle grain boundaries in lightly deformed superconducting niobium and their influence on hydride distribution and flux perturbation

    Science.gov (United States)

    Sung, Z.-H.; Wang, M.; Polyanskii, A. A.; Santosh, C.; Balachandran, S.; Compton, C.; Larbalestier, D. C.; Bieler, T. R.; Lee, P. J.

    2017-05-01

    This study shows that low angle grain boundaries (LAGBs) can be created by small 5% strains in high purity (residual resistivity ratio ≥ 200) superconducting radio frequency (SRF)-grade single crystalline niobium (Nb) and that these boundaries act as hydrogen traps as indicated by the distribution of niobium hydrides (Nb1-xHx). Nb1-xHx is detrimental to SRF Nb cavities due to its normal conducting properties at cavity operating temperatures. By designing a single crystal tensile sample extracted from a large grain (>5 cm) Nb ingot slice for preferred slip on one slip plane, LAGBs and dense dislocation boundaries developed. With chemical surface treatments following standard SRF cavity fabrication practice, Nb1-xHx phases were densely precipitated at the LAGBs upon cryogenic cooling (8-10 K/min). Micro-crystallographic analysis confirmed heterogeneous hydride precipitation, which included significant hydrogen atom accumulation in LAGBs. Magneto-optical imaging analysis showed that these sites can then act as sites for both premature flux penetration and eventually flux trapping. However, this hydrogen related degradation at LAGBs did not completely disappear even after an 800 °C/2 h anneal typically used for hydrogen removal in SRF Nb cavities. These findings suggest that hydride precipitation at an LAGB is facilitated by a non-equilibrium concentration of vacancy-hydrogen (H) complexes aided by mechanical deformation and the hydride phase interferes with the recovery process under 800 °C annealing.

  8. Antisolvent Precipitation for the Synthesis of Monodisperse Mesoporous Niobium Oxide Spheres as Highly Effective Solid Acid Catalysts

    KAUST Repository

    Li, Cheng Chao; Dou, Jian; Chen, Luwei; Lin, Jianyi; Zeng, Hua Chun

    2012-01-01

    We have developed a low-cost reaction protocol to synthesize mesoporous Nb 2O 5-based solid acid catalysts with external shape control. In the synthesis, monodisperse glycolated niobium oxide spheres (GNOS) were prepared by means of a simple antisolvent precipitation approach and subsequently converted to mesoporous niobium oxide spheres (MNOS) with a large surface area of 312m 2g -1 by means of the hydrothermal treatment. The antisolvent acetone used to obtain GNOS was recovered through distillation at high purity. The obtained mesoporous MNOS were functionalized further with sulfate anions at different temperatures or incorporated with tungstophosphoric acid to obtain recyclable solid acid catalysts. These MNOS-based catalysts showed excellent performance in a wide range of acid-catalyzed reactions, such as Friedel-Crafts alkylation, esterification, and hydrolysis of acetates. As they are monodisperse spheres with diameters in the submicrometer range, the catalysts can be easily separated and reused. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Antisolvent Precipitation for the Synthesis of Monodisperse Mesoporous Niobium Oxide Spheres as Highly Effective Solid Acid Catalysts

    KAUST Repository

    Li, Cheng Chao

    2012-03-20

    We have developed a low-cost reaction protocol to synthesize mesoporous Nb 2O 5-based solid acid catalysts with external shape control. In the synthesis, monodisperse glycolated niobium oxide spheres (GNOS) were prepared by means of a simple antisolvent precipitation approach and subsequently converted to mesoporous niobium oxide spheres (MNOS) with a large surface area of 312m 2g -1 by means of the hydrothermal treatment. The antisolvent acetone used to obtain GNOS was recovered through distillation at high purity. The obtained mesoporous MNOS were functionalized further with sulfate anions at different temperatures or incorporated with tungstophosphoric acid to obtain recyclable solid acid catalysts. These MNOS-based catalysts showed excellent performance in a wide range of acid-catalyzed reactions, such as Friedel-Crafts alkylation, esterification, and hydrolysis of acetates. As they are monodisperse spheres with diameters in the submicrometer range, the catalysts can be easily separated and reused. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Detailed Geological Modelling in Urban Areas focused on Structures relevant to the Near Surface Groundwater Flow in the context of Climatic Changes

    Science.gov (United States)

    Bach, T.; Pallesen, T. M.; Jensen, N. P.; Mielby, S.; Sandersen, P.; Kristensen, M.

    2015-12-01

    This case demonstrates a practical example from the city of Odense (DK) where new geological modeling techniques has been developed and used in the software GeoScene3D, to create a detailed voxel model of the anthropogenic layer. The voxel model has been combined with a regional hydrostratigraphic layer model. The case is part of a pilot project partly financed by VTU (Foundation for Development of Technology in the Danish Water Sector) and involves many different datatypes such as borehole information, geophysical data, human related elements (landfill, pipelines, basements, roadbeds etc). In the last few years, there has been increased focus on detailed geological modeling in urban areas. The models serve as important input to hydrological models. This focus is partly due to climate changes as high intensity rainfalls are seen more often than in the past, and water recharge is a topic too. In urban areas, this arises new challenges. There is a need of a high level of detailed geological knowledge for the uppermost zone of the soil, which typically are problematic due to practically limitations, especially when using geological layer models. Furthermore, to accommodate the need of a high detail, all relevant available data has to be used in the modeling process. Human activity has deeply changed the soil layers, e.g. by constructions as roadbeds, buildings with basements, pipelines, landfill etc. These elements can act as barriers or pathways regarding surface near groundwater flow and can attribute to local flooding or mobilization and transport of contaminants etc. A geological voxel model is built by small boxes (a voxel). Each box can contain several parameters, ex. lithology, transmissivity or contaminant concentration. Human related elements can be implemented using tools, which gives the modeler advanced options for making detailed small-scale models. This case demonstrates the workflow and the resulting geological model for the pilot area.

  11. Critical current, pinning and resistive state of superconducting single-crystal niobium with different types of defect structure

    International Nuclear Information System (INIS)

    Sokolenko, V.I.; Starodubov, Ya.D.

    2005-01-01

    Critical current pinning and resistive state of single crystal niobium of texture orientation are studied for different structural states obtained by rolling at 20 K by 42% and polishing the surface layers. It is found that the heterogeneous structures typical of the strained sample even after its thinning down to approx 10% display a lower current-carrying capability due to an increase of the thermomagnetic instability within the fragmented structure sections in the near-surface layers. For a homogeneous defect structure of the sample core with the density of equilibrium distributed dislocations of 1.3 centre dot 10 11 cm -2 , a correlation between the normal current density and the critical current density in the resistive state is found, in agreement with the concepts of flux creep due to the scatter of local values of J c

  12. Production of Seamless Superconducting Radio Frequency Cavities from Ultra-fine Grained Niobium, Phase II Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Roy Crooks, Ph.D., P.E.

    2009-10-31

    The positron and electron linacs of the International Linear Collider (ILC) will require over 14,000, nine-cell, one meter length, superconducting radio frequency (SRF) cavities [ILC Reference Design Report, 2007]. Manufacturing on this scale will benefit from more efficient fabrication methods. The current methods of fabricating SRF cavities involve deep drawing of the halves of each of the elliptical cells and joining them by high-vacuum, electron beam welding, with at least 19 circumferential welds per cavity. The welding is costly and has undesirable effects on the cavity surfaces, including grain-scale surface roughening at the weld seams. Hydroforming of seamless tubes avoids welding, but hydroforming of coarse-grained seamless tubes results in strain-induced surface roughening. Surface roughness limits accelerating fields, because asperities prematurely exceed the critical magnetic field and become normal conducting. This project explored the technical and economic feasibility of an improved processing method for seamless tubes for hydroforming. Severe deformation of bulk material was first used to produce a fine structure, followed by extrusion and flow-forming methods of tube making. Extrusion of the randomly oriented, fine-grained bulk material proceeded under largely steady-state conditions, and resulted in a uniform structure, which was found to be finer and more crystallographically random than standard (high purity) RRR niobium sheet metal. A 165 mm diameter billet of RRR grade niobium was processed into five, 150 mm I.D. tubes, each over 1.8 m in length, to meet the dimensions used by the DESY ILC hydroforming machine. Mechanical properties met specifications. Costs of prototype tube production were approximately twice the price of RRR niobium sheet, and are expected to be comparable with economies of scale. Hydroforming and superconducting testing will be pursued in subsequent collaborations with DESY and Fermilab. SRF Cavities are used to construct

  13. Superconducting radio-frequency cavities made from medium and low-purity niobium ingots

    International Nuclear Information System (INIS)

    Ciovati, Gianluigi; Dhakal, Pashupati; Myneni, Ganapati R

    2016-01-01

    Superconducting radio-frequency cavities made of ingot niobium with residual resistivity ratio (RRR) greater than 250 have proven to have similar or better performance than fine-grain Nb cavities of the same purity, after standard processing. The high purity requirement contributes to the high cost of the material. As superconducting accelerators operating in continuous-wave typically require cavities to operate at moderate accelerating gradients, using lower purity material could be advantageous not only to reduce cost but also to achieve higher Q 0 -values. In this contribution we present the results from cryogenic RF tests of 1.3–1.5 GHz single-cell cavities made of ingot Nb of medium (RRR = 100–150) and low (RRR = 60) purity from different suppliers. Cavities made of medium-purity ingots routinely achieved peak surface magnetic field values greater than 70 mT with an average Q 0 -value of 2 × 10 10 at 2 K after standard processing treatments. The performances of cavities made of low-purity ingots were affected by significant pitting of the surface after chemical etching. (paper)

  14. Superconducting radio-frequency cavities made from medium and low-purity niobium ingots

    Science.gov (United States)

    Ciovati, Gianluigi; Dhakal, Pashupati; Myneni, Ganapati R.

    2016-06-01

    Superconducting radio-frequency cavities made of ingot niobium with residual resistivity ratio (RRR) greater than 250 have proven to have similar or better performance than fine-grain Nb cavities of the same purity, after standard processing. The high purity requirement contributes to the high cost of the material. As superconducting accelerators operating in continuous-wave typically require cavities to operate at moderate accelerating gradients, using lower purity material could be advantageous not only to reduce cost but also to achieve higher Q 0-values. In this contribution we present the results from cryogenic RF tests of 1.3-1.5 GHz single-cell cavities made of ingot Nb of medium (RRR = 100-150) and low (RRR = 60) purity from different suppliers. Cavities made of medium-purity ingots routinely achieved peak surface magnetic field values greater than 70 mT with an average Q 0-value of 2 × 1010 at 2 K after standard processing treatments. The performances of cavities made of low-purity ingots were affected by significant pitting of the surface after chemical etching.

  15. Effect of cathode shape on vertical buffered electropolishing for niobium SRF cavities

    Science.gov (United States)

    Jin, S.; Wu, A. T.; Lu, X. Y.; Rimmer, R. A.; Lin, L.; Zhao, K.; Mammosser, J.; Gao, J.

    2013-09-01

    This paper reports the research results of the effect of cathode shape during vertical buffered electropolishing (BEP) by employing a demountable single cell niobium (Nb) superconducting radio frequency (SRF) cavity. Several different cathode shapes such as, for instance, bar, ball, ellipsoid, and wheels of different diameters have been tested. Detailed electropolishing parameters including I-V characteristic, removal rate, surface roughness, and polishing uniformity at different locations inside the demountable cavity are measured. Similar studies are also done on conventional electropolishing (EP) for comparison. It is revealed that cathode shape has dominant effects for BEP especially on the obtaining of a suitable polishing condition and a uniform polishing rate in an Nb SRF single cell cavity. EP appears to have the same tendency. This paper demonstrates that a more homogeneous polishing result can be obtained by optimizing the electric field distribution inside the cavity through the modification of the cathode shape given the conditions that temperature and electrolyte flow are kept constant. Electric field distribution and electrolyte flow patterns inside the cavity are simulated via Poisson-Superfish and Solidworks respectively. With the optimal cathode shape, BEP shows a much faster polishing rate of ∼2.5 μm/min and is able to produce a smoother surface finish in the treatments of single cell cavities in comparison with EP.

  16. Etching of Niobium in an Argon-Chlorine Capacitively Coupled Plasma

    Science.gov (United States)

    Radovanov, Svetlana; Samolov, Ana; Upadhyay, Janardan; Peshl, Jeremy; Popovic, Svetozar; Vuskovic, Leposava; Applied Materials, Varian Semiconductor Team; Old Dominion University Team

    2016-09-01

    Ion assisted etching of the inner surfaces of Nb superconducting radio frequency (SRF) cavities requires control of incident ion energies and fluxes to achieve the desired etch rate and smooth surfaces. In this paper, we combine numerical simulation and experiment to investigate Ar /Cl2 capacitively coupled plasma (CCP) in cylindrical reactor geometry. Plasma simulations were done in the CRTRS 2D/3D code that self-consistently solves for CCP power deposition and electrostatic potential. The experimental results are used in combination with simulation predictions to understand the dependence of plasma parameters on the operating conditions. Using the model we were able to determine the ion current and flux at the Nb substrate. Our simulations indicate the relative importance of the current voltage phase shift and displacement current at different pressures and powers. For simulation and the experiment we have used a test structure with a pillbox cavity filled with niobium ring-type samples. The etch rate of these samples was measured. The probe measurements were combined with optical emission spectroscopy in pure Ar for validation of the model. The authors acknowledge Dr Shahid Rauf for developing the CRTRS code. Support DE-SC0014397.

  17. Effect of cathode shape on vertical buffered electropolishing for niobium SRF cavities

    International Nuclear Information System (INIS)

    Jin, S.; Wu, A.T.; Lu, X.Y.; Rimmer, R.A.; Lin, L.; Zhao, K.; Mammosser, J.; Gao, J.

    2013-01-01

    This paper reports the research results of the effect of cathode shape during vertical buffered electropolishing (BEP) by employing a demountable single cell niobium (Nb) superconducting radio frequency (SRF) cavity. Several different cathode shapes such as, for instance, bar, ball, ellipsoid, and wheels of different diameters have been tested. Detailed electropolishing parameters including I–V characteristic, removal rate, surface roughness, and polishing uniformity at different locations inside the demountable cavity are measured. Similar studies are also done on conventional electropolishing (EP) for comparison. It is revealed that cathode shape has dominant effects for BEP especially on the obtaining of a suitable polishing condition and a uniform polishing rate in an Nb SRF single cell cavity. EP appears to have the same tendency. This paper demonstrates that a more homogeneous polishing result can be obtained by optimizing the electric field distribution inside the cavity through the modification of the cathode shape given the conditions that temperature and electrolyte flow are kept constant. Electric field distribution and electrolyte flow patterns inside the cavity are simulated via Poisson–Superfish and Solidworks respectively. With the optimal cathode shape, BEP shows a much faster polishing rate of ∼2.5 μm/min and is able to produce a smoother surface finish in the treatments of single cell cavities in comparison with EP.

  18. Effects of Niobium Microalloying on Microstructure and Properties of Hot-Dip Galvanized Sheet

    Energy Technology Data Exchange (ETDEWEB)

    Mohrbacher, Hardy [NiobelCon bvba, Brussels (Belgium)

    2010-04-15

    Niobium microalloying is effective in hot-rolled and cold-rolled steels by providing a fine-grained microstructure resulting in increased strength. To optimize the strengthening effect, alloy design and hot-rolling conditions have to be adapted. As a key issue the dissolution and precipitation characteristics of Nb are discussed in particular with regard to the run-out table conditions. It is then considered how the hot-rolled microstructure and the solute state of Nb interact with the hot-dip galvanizing cycle. The adjusted conditions allow controlling the morphology and distribution of phases in the cold-rolled annealed material. Additional precipitation hardening can be achieved as well. The derived options can be readily applied to produce conventional HSLA and IF high strength steels as well as to modem multiphase steels. It will be explained how important application properties such as strength, elongation, bendability, weldability and delayed cracking resistance can be influenced in a controlled and favorable way. Examples of practical relevance and experience are given.

  19. Orientation-dependent forces between flux lines and crystal lattice in pure niobium

    International Nuclear Information System (INIS)

    Holzhauser, W.

    1976-01-01

    Torque measurements were performed with cylindrical niobium crystals, due to the very small pinning of the high-purity material. A torque that tries to align the flux lines along special directions of the crystal lattice was studied

  20. Tantalum(V) impurity extraction by octanol from niobium(V) fluoride solutions

    International Nuclear Information System (INIS)

    Majorov, V.G.; Nikolaev, A.I.; Kopkov, V.K.

    2002-01-01

    The conditions of the niobium and tantalum extraction separation by octanol in the fluoride solutions, depending on the metals and free hydrofluoric acid concentration as well as on the organic and water phases voluminous relation, are studied for the purpose of developing the technology of niobium deep purification from the tantalum impurities. The technological scheme of the niobium solutions(V) extraction purification from the tantalum impurities(V), which provides for obtaining the niobium oxide(V), containing less than 0.005 mass % Ta 2 O 5 , is proposed on the basis of the established optimal separation conditions. The possibility of using the developed technology by the pyrochlore reprocessing is indicated [ru