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Sample records for nghin cu ci

  1. Geochemistry of CI chondrites: Major and trace elements, and Cu and Zn Isotopes

    Science.gov (United States)

    Barrat, J. A.; Zanda, B.; Moynier, F.; Bollinger, C.; Liorzou, C.; Bayon, G.

    2012-04-01

    In order to check the heterogeneity of the CI chondrites and determine the average composition of this group of meteorites, we analyzed a series of six large chips (weighing between 0.6 and 1.2 g) of Orgueil prepared from five different stones. In addition, one sample from each of Ivuna and Alais was analyzed. Although the sizes of the chips used in this study were “large”, our results show evidence for minor chemical heterogeneity in Orgueil, particularly for alkali elements and U. After removal of one outlier sample, the spread of the results is considerably reduced. For most of the 46 elements analyzed in this study, the average composition calculated for Orgueil is in very good agreement with previous CI estimates. This average, obtained with a “large” mass of samples, is analytically homogeneous and is suitable for normalization purposes. Finally, the Cu and Zn isotopic ratios are homogeneously distributed within the CI parent body with a spread of less than 100 ppm per atomic mass unit (amu).

  2. Functional and crystallographic characterization of Salmonella typhimurium Cu,Zn superoxide dismutase coded by the sodCI virulence gene

    NARCIS (Netherlands)

    Pesce, A; Battistoni, A; Stroppolo, ME; Polizio, F; Nardini, M; Kroll, JS; Langford, PR; O'Neill, P; Sette, M; Desideri, A; Bolognesi, M

    2000-01-01

    The functional and three-dimensional structural features of Cu,Zn superoxide dismutase coded by the Salmonella typhimurium sodCI gene, have been characterized. Measurements of the catalytic rate indicate that this enzyme is the most efficient superoxide dismutase analyzed so far, a feature that may

  3. Soldabilidad de fundiciones grises con materiales de aporte tipo RbCuZn-A, ErCuAl-A2 y ErNiFe-CI-A.

    Directory of Open Access Journals (Sweden)

    Jimy Unfried Silgado

    2004-01-01

    Full Text Available En esta investigación, a través de una propuesta experimental que incluye el diseño de un cuerpo de ensayo y por la selección de procedimientos de soldadura adecuados, se estudió la influencia de los materiales de aporte tipo: RBCuZn–A, ERNiFe-CI-A y ERCuAl-A2, aplicados sobre una fundición gris no aleada clasificada dentro de la especificación ASTM A-48. Dicha influencia se estudió a través de la extracción de probetas de ensayo que se usaron para la evaluación de propiedades mecánicas: tracción, dureza, microdureza y doblez; así como, a través de observaciones metalográficas de las uniones soldadas. Con esto se logró determinar la existencia o no de diferentes zonas y regiones en las juntas soldadas y la influencia de esta presencia sobre la Soldabilidad en el metal de base escogido.

  4. CI Implementation

    DEFF Research Database (Denmark)

    Jørgensen, Frances; Boer, Harry; Laugen, Bjørge Timenes

    2006-01-01

    There are a number of tools available for organizations wishing to measure and subsequently develop Continuous Improvement (CI). In this article, we review and evaluate a well-accepted CI development model, namely the CI Maturity Model (Bessant and Caffyn, 1997), against data collected from the 2nd...... Continuous Improvement Network Survey and a number of empirical cases described in the literature. While the CI Maturity Model suggests that CI maturation ought to be a linear process, the findings in this article suggest that there are feasible alternatives for companies to develop CI capability....

  5. Ci PERMIT

    CERN Multimedia

    Relations with the Host States Service

    1999-01-01

    The Swiss Permanent Mission to the International Organisations at Geneva recalls that only the spouses and children of members of personnel resident in Switzerland and in possession of a legitimation card of types 'B', 'C', 'D' or 'E' issued by the Swiss Federal Department of Foreign Affairs are entitled to benefit from a Ci Permit.The 'demande d'attestation de permis Ci' (request for a Ci permit attestation) can be sent to the Mission only through Personnel Division (Administrative Services, Office 33/1-025).Additional information on access by family members of CERN officials to the Swiss labour market are available to you on the Web site of the Relations with the Host States Service (cf. document entitled 'Employment in Switzerland for spouses and children of CERN officials' dated March 1996).Relations with the Host States Servicehttp://www.cern.ch/relations/Tel. 72848

  6. Ukaegbe, CI

    African Journals Online (AJOL)

    Ukaegbe, CI. Vol 11, No 1-2 (2012) - Articles Postpartum Depression Among Igbo Women In An Urban Mission Hospital, South East Nigeria Abstract. ISSN: 1597-1260. AJOL African Journals Online. HOW TO USE AJOL... for Researchers · for Librarians · for Authors · FAQ's · More about AJOL · AJOL's Partners · Terms and ...

  7. Application of Rqd-Number and Rqd-Volume Multifractal Modelling to Delineate Rock Mass Characterisation in Kahang Cu-Mo Porphyry Deposit, Central Iran / Zastosowanie Metod Modelowania Numerycznego Oraz Modelowania Fraktalnego do Analizy JAKOŚCI SKAŁ W Celu OKREŚLENIA Charakterystyki GÓROTWORU W Obszarze ZŁOŻA Cu-Mo W Kahang, ŚRODKOWY Iran

    Science.gov (United States)

    Yasrebi, Amir Bijan; Wetherelt, Andrew; Foster, Patrick J.; Afzal, Peyman; Coggan, John; Ahangaran, Dariush Kaveh

    2013-12-01

    Identification of rock mass properties in terms of Rock Quality Designation (RQD) plays a significant role in mine planning and design. This study aims to separate the rock mass characterisation based on RQD data analysed from 48 boreholes in Kahang Cu-Mo porphyry deposit situated in the central Iran utilising RQD-Volume (RQD-V) and RQD-Number (RQD-N) fractal models. The log-log plots for RQD-V and RQD-N models show four rock mass populations defined by RQD thresholds of 3.55, 25.12 and 89.12% and 10.47, 41.68 and 83.17% respectively which represent very poor, poor, good and excellent rocks based on Deere and Miller rock classification. The RQD-V and RQD-N models indicate that the excellent rocks are situated in the NW and central parts of this deposit however, the good rocks are located in the most parts of the deposit. The results of validation of the fractal models with the RQD block model show that the RQD-N fractal model of excellent rock quality is better than the RQD-V fractal model of the same rock quality. Correlation between results of the fractal and the geological models illustrates that the excellent rocks are associated with porphyric quartz diorite (PQD) units. The results reveal that there is a multifractal nature in rock characterisation with respect to RQD for the Kahang deposit. The proposed fractal model can be intended for the better understanding of the rock quality for purpose of determination of the final pit slope. Identyfikacja właściwości górotworu odgrywa zasadniczą rolę w planowaniu wydobycia i projektowaniu kopalni. Praca niniejsza ma na celu określenie charakterystyki górotworu w oparciu o dane o jakości skał zebrane na podstawie próbek uzyskanych z 48 odwiertów wykonanych w złożu porfiru Cu-Mo w Kahang, zalegającym w środkowym Iranie przy użyciu modeli fraktalnych RQD-V - Rock Quality Determination-Volume [Określenie jakości skał-objętość]) i RQD-N (Rock Quality Determination-Number [Określenie jakości ska

  8. Ciência global?

    OpenAIRE

    Abreu, Armando Trigo de

    2000-01-01

    No fim do séc. XX, poucas actividades podem reclamar um passado de universalidade tão longo e tão paradigmático como a ciência. Se eliminarmos ocasionais e limitados acessos de nacionalismo ou ideologismo mais destemperado que levaram à procura da ciência proletária ou da filosofia portuguesa, a história da ciência é uma história comum. Portugal está excepcionalmente bem situado para compreender esta característica da ciência universal. Três exemplos, apenas, podem ilustrar esta condição:...

  9. (Human) Resourcing For CI

    DEFF Research Database (Denmark)

    Jørgensen, Frances; S., Jacob; Kofoed, Lise Busk

    2005-01-01

    the change processes in which we are engaged?” Without a clear picture of the types of competencies required to implement CI, it is impossible for companies to make informed decisions regarding recruitment, hiring, and training of their workforce. The objective of this paper is therefore to define...... and characterize the types of competencies necessary for persons involved change implementation. Data collection involved interviews and observations in three longitudinal studies in five companies based in Denmark. From these data, a list of competencies that appeared to facilitate CI implementation was compiled...... challenging in organizations involved in change processes such as Continuous Improvement (CI), as the technical skills traditionally valued are no longer adequate. These companies are faced with the question: “What competencies should our employees possess in order to contribute to our success, given...

  10. Ciência no globo-ciência

    OpenAIRE

    Mendonça,Otávio Machado Lopes de

    1996-01-01

    O objetivo da presente pesquisa foi verificar as áreas de conhecimento científico que se fizeram presentes na programação do Globo-Ciência, veiculada pela Rede Globo de Televisão,verificando também as estratégias usadas e o material empregado como recursos didáticos. O material utilizado foi o catálogo da programação do Globo-Ciência-10 anos (1984-1994). Os resultados mostram que as Ciências Exatas e da Terra foi a mais apresentada no programa com 49,65%,havendo pouco espaço para as outras, v...

  11. The CI:Marketing interface

    OpenAIRE

    Wright, Sheila

    2005-01-01

    The potential for CI to inform and influence marketing decisions is increasing and this combination can deliver an enviable competitive advantage. Simply knowing more about competitors is not enough. It is what the firm does with that information and how it weaves it into its decision making process which makes the difference. In a large number of organisations, private or public, it is the Marketing Department which carries the responsibility for critical activities such as customer manageme...

  12. VELoCiRaPTORS.

    Science.gov (United States)

    Lundgren, J.; Esham, B.; Padalino, S. J.; Sangster, T. C.; Glebov, V.

    2007-11-01

    The Venting and Exhausting of Low Level Air Contaminants in the Rapid Pneumatic Transport of Radioactive Samples (VELoCiRaPTORS) system is constructed to transport radioactive materials quickly and safely at the NIF. A radioactive sample will be placed inside a carrier that is transported via an airflow system produced by controlled differential pressure. Midway through the transportation process, the carrier will be stopped and vented by a powered exhaust blower which will remove radioactive gases within the transport carrier. A Geiger counter will monitor the activity of the exhaust gas to ensure that it is below acceptable levels. If the radiation level is sufficient, the carrier will pass through the remainder of the system, pneumatically braking at the counting station. The complete design will run manually or automatically with control software. Tests were performed using an inactive carrier to determine possible transportation problems. The system underwent many consecutive trials without failure. VELoCiRaPTORS is a prototype of a system that could be installed at both the Laboratory for Laser Energetics at the University of Rochester and the National Ignition Facility at LLNL.

  13. The influence of dietary Cu and diabetes on tissue 67Cu retention kinetics in rats

    International Nuclear Information System (INIS)

    Uriu-Hare, J.Y.; Rucker, R.B.; Keen, C.L.

    1991-01-01

    Compared to controls, diabetes results in higher plasma, liver and kidney Cu concentrations. Since alterations in Cu metabolism may be associated with diabetic pathology, the authors investigated how Cu metabolism is affected by diabetes and dietary Cu intake. Nondiabetic and STZ diabetic rats were fed Cu suppl. or Cu def. diets for 5 wks. Rats were intubated with 28 μCi 67 Cu and killed after 8, 16, 24, 32, 64, or 128 h. There were marked effects of both diet and diabetes on 67 Cu metabolism. Independent of diabetes, deficient rats had a higher % of retained 67 Cu, in liver, plasma, RBC, muscle, spleen, brain, lung, uterus, and intestine than adequate Cu rats. Independent of dietary Cu, diabetic rats had a lower % of retained 67 Cu in liver, plasma, RBC, muscle, spleen, lung, bone, pancreas, skin, uterus and heart than controls. Differential effects were noted for kidney; adequate Cu diabetic rats had a higher % of retained 67 Cu than all other groups. Marked effects of both diet and diabetes were evident when tissue Cu turnover was examined. Compared to Cu suppl. rats, Cu def. rats had a slower turnover of 67 Cu, in liver, plasma, intestine, pancreas, eye, brain, muscle, spleen, lung and heart. Diabetic rats had a slower turnover of 67 Cu than nondiabetic rats in liver, plasma, intestine, pancreas, eye, kidney, RBC and uterus. The data imply that a focus on Cu metabolism with regard to cellular Cu trafficking and pathology may be warranted

  14. Zależność bodźcowości ciśnienia od cyrkulacji atmosferycznej w Warszawie

    Directory of Open Access Journals (Sweden)

    Katarzyna Rozbicka

    2016-09-01

    Full Text Available W pracy zbadano: czasowy rozkład ciśnienia atmosferycznego, bodźcowe oddziaływanie ciśnienia atmosferycznego o wartościach wyższych od 1015 hPa lub niższych od 985 hPa. Wyznaczono częstość i prawdopodobieństwo wystąpienia ciśnienia o oddziaływaniu bodźcowym oraz zanalizowano zależność zmian międzydobowych ciśnienia od typów cyrkulacji atmosferycznej według klasyfikacji Lityńskiego. Do obliczeń wykorzystano cogodzinne wartości ciśnienia atmosferycznego pochodzące ze stacji Ursynów SGGW z okresu 2011–2015. Na podstawie badań stwierdzono, że ciśnienie atmosferyczne o oddziaływaniu bodźcowym w Warszawie może wystąpić w każdym miesiącu z prawdopodobieństwem od 0,2% do 19,1%, w przypadku ciśnienia o wartościach wyższych niż 1015 hPa oraz od 0,1 do 3,4%, w przypadku ciśnienia niższego od 985 hPa, z wyjątkiem czerwca i sierpnia. Zmiany międzydobowe ciśnienia atmosferycznego mogą osiągać około 24 hPa, a częstość występowania bodźców „silnych” wywołanych tymi zmianami wyniosła w poszczególnych miesiącach od 1% do 16%, natomiast bodźców „bardzo silnych” od 2% do 8%. Spośród sytuacji synoptycznych największe znaczenie dla bodźcowości zmian ciśnienia mają sytuacje cyklonalne: szczególnie przy adwekcji powietrza z sektora północno-zachodniego (NWC.

  15. Nudności i wymioty

    Directory of Open Access Journals (Sweden)

    Anna Mokrowiecka

    2010-12-01

    Full Text Available Nudności są nieprzyjemnym, niebolesnym odczuciem silnej, nieodpartej potrzeby zwymiotowania, z kolei wymioty polegają na gwałtownym wydaleniu treści żołądka przez usta w wyniku silnych skurczów mięśni brzucha i klatki piersiowej. Nudności i wymioty mogą występować niezależnie od siebie, ale najczęściej są ze sobą powiązane. Nudności i wymioty powstają w odpowiedzi zarówno na bodźce fizjologiczne, jak i patologiczne. Zwykle jednak przewlekłe nudności i wymioty są objawem chorób przewodu pokarmowego lub innych narządów. Choroby przewodu pokarmowego i otrzewnej stanowią szeroką grupę chorób wywołujących nudności i wymioty, począwszy od nieżytu żołądkowo-jelitowego o ostrym infekcyjnym tle, przez zatrucie pokarmowe i nadwrażliwość pokarmową, do stanów ostrych – niedrożności jelita cienkiego lub/i grubego. Leki i toksyny, między innymi cytostatyki, są jedną z najczęstszych przyczyn nudności i wymiotów. Wśród innych przyczyn nudności i wymiotów można wymienić: choroby OUN prowadzące do zwiększenia ciśnienia śródczaszkowego, choroby endokrynologiczne i metaboliczne (mocznica, kwasica ketonowa w cukrzycy, choroby tarczycy i przytarczyc oraz choroba Addisona, zawał ściany dolnej mięśnia sercowego, nudności i wymioty pooperacyjne. Nudności i wymioty jako choroby czynnościowe zostały ujęte w III kryteriach rzymskich w punkcie „Choroby czynnościowe żołądka i dwunastnicy”. W diagnostyce różnicowej należy uwzględnić czas trwania wymiotów, czas pomiędzy posiłkiem a wystąpieniem wymiotów, a także charakter treści wymiocin i inne objawy towarzyszące. Wywiad i badanie fizykalne dostarczają zwykle wystarczających informacji do postawienia prawidłowej diagnozy i ustalenia leczenia u większości chorych cierpiących na nudności i wymioty. Niektórzy pacjenci wymagają jednak badań laboratoryjnych, obrazowych i endoskopowych przed zastosowaniem odpowiedniej

  16. "ESSAY ON CI" BY LI QINGZHAO

    Directory of Open Access Journals (Sweden)

    Anna Dashchenko

    2016-10-01

    Full Text Available The article presents the first Russian translation of "Essay on Ci" with detailed comments. It was written by the outstanding Chinese poetess Li Qingzhao and considered to be the first theoretical treatise dedicated to genre ci. The article revealed that the poetess used three strategies to make a genre demarcation: to legitimise, dichotomise and historicise. To legitimise means to justify that ci is a genre of poetry by identifying the same traits with official poetry shi (e.g. using the classical quotations and allusions. To dichotomise is to determine a core element of genre and oppose it to the other element identifying the similar genre (e.g. music separates ci from shi. To historicise is to develop or discover the unique historical past (e.g. the source of ci is in antiquity. The article also examined the strategy to invent classics: Li Qingzhao wrote the apophatic history of genre ci pointing not to the merits but weaknesses of her predecessors.

  17. ANALIZA NIEZAWODNOŚCI STACJI UZDATNIANIA WODY

    Directory of Open Access Journals (Sweden)

    Barbara TCHÓRZEWSKA-CIEŚLAK

    Full Text Available Systemy zbiorowego zaopatrzenia w wodę składają się z połączonych ze sobą elementów (podsystemów stanowiących integralna całość, współpracujących ze sobą w sposób ciągły w celu zapewnienia dla konsumentów wody o odpowiedniej jakości. W przypadku gdy jakość wody w źródle nie odpowiada normatywom stawianym wodzie przeznaczonej do spożycia przez ludzi, woda musi być poddana procesom uzdatniania. Niezawodność funkcjonowania stacji uzdatniania wody jest jednym z podstawowych elementów szeroko rozumianej analizy niezawodności i bezpieczeństwa całego systemu zbiorowego zaopatrzenia w wodę. Niezawodność dostawy wody polega na zapewnieniu stabilnych warunków, umożliwiających pokrycie bieżącego i perspektywicznego zapotrzebowania na wodę w odpowiedniej ilości i wymaganej jakości w dowolnym, dogodnym dla konsumentów wody czasie. W pracy przedstawiono podstawy analizy niezawodności, podano podstawowe miary oraz zasady wykorzystania struktur niezawodnościowych. Obliczenia wykonano dla stacji uzdatniania wody na podstawie schematu niezwodnościowego metodą jednoparametryczną. Na podstawie danych z eksploatacyjnych stacji uzdatniania wody (SUW wchodzącej w skład systemu zbiorowego zaopatrzenia w wodę miasta liczącego ok 80 tys. mieszkańców sporządzono schemat niewodności stacji oraz przeprowadzono obliczenia wskaźnika gotowości K. W metodzie wykorzystano podstawowe struktury niezawodnościowe. Wyznaczoną miarę niezawodności porównano z wartościami kryterialnymi.

  18. Language Practices in the Ci-Classroom

    DEFF Research Database (Denmark)

    Mourtou, Eleni

    2014-01-01

    Prelingually deafened children are nowadays likely to receive a cochlear implant (ci). As these children do their language acquisition with a cochlear implant they require a constant rehabilitation and support. Educational staff is instructed on how to work with children with ci in form...... of guidelines and workshops. This paper discusses language practices used in the setting of a school for cochlear-implanted children. These children encounter language and pronunciation problems that accompany prelingual deafness and hearing with a cochlear implant. I examine two practices, which are used...

  19.  Spis treści

    Directory of Open Access Journals (Sweden)

    Mieczysław Dobija

    2014-04-01

    Full Text Available  Od Zespołu Redakcyjnego ............................................................................... 5 Mieczysław Dobija – Rachunkowość w systemie pomiaru aktywności ekonomicznej państwa – Accounting as part of an economic activity measurement system ............... 7 Renata Dyląg, Ewelina Puchalska – Raportowanie zagadnień środowiskowych i społecznych – Reporting on social and environmental issues .............................................. 23 Jacek Gad – Sprawozdanie z wyniku całościowego jako źródło informacji na temat kapitałowych przychodów i kosztów – doświadczenia polskiego i niemieckiego rynku kapitałowego – Statement of comprehensive income as a source of information on capital income and expenses – experience of Polish and German capital markets...... 47 Piotr Luty – Ocena kondycji finansowej łączących się spółek na przykładzie jednostek z wybranych województw Polski Zachodniej – Assessment of financial position of merging companies based on selected provinces of Western Poland ............................................................................ 69 Irena Sobańska – Znaczenie dorobku naukowego Profesor Elżbiety Burzym dla rozwoju nauki i praktyki rachunkowości w Polsce – The importance of Professor Elżbieta Burzym’s contribution to the development of accounting theory, research and practice in Poland ........................ 83 Arleta Szadziewska – Rachunkowość jako źródło informacji na temat realizacji strategii społecznej odpowiedzialności biznesu – Accounting as a source of information for CSR strategy ............................. 95 Halina Waniak-Michalak – Informacja o pracy wolontariuszy w sprawozdaniach organizacji pożytku publicznego w Polsce – Information on volunteer labour in reports of public benefit organizations in Poland ............................................................................................................ 125

  20. Cognitivismo e ciência cognitiva

    Directory of Open Access Journals (Sweden)

    Marcos Barbosa de Oliveira

    1990-01-01

    Full Text Available O objetivo da comunicação é caracterizar uma escola de pensamento-o cognitivismo-e a disciplina a que ela deu origem. Depois de um breve apanhado das origens do cognitivismo descrevem-se os princípios ontológicos e metodológicos que o definem. Mostra-se a seguir a relação que há entre os computadores e a idéia funcionalista de considerar a mente como um sistema cujos elementos são caracterizados por suas funções, e não por sua constituição material. Discute-se finalmente a natureza e o nome da disciplina gerada pelo cognitivismo, sugerindo-se que se trata de uma proto-ciência, a qual deve ser denominada "Estudos Cognitivos" de preferência a "Ciência Cognitiva".

  1. Kierunki zmiansprawozdawczości finansowej

    Directory of Open Access Journals (Sweden)

    Zbigniew Luty

    2010-05-01

    Full Text Available W artykule wskazano na możliwe kierunki zmian w sprawozdawczości finansowej w najbliższych latach. Wymieńmy najważniejsze: 1 bazą jest informacja oparta na dokumentacji księgowej w ujęciu historycznym, 2 sprawozdania celowe (dedykowane, 3 informacja finansowa jako towar na specyficznym rynku sprawozdań, 4 prawo bilansowe tworzone z minimalnym wpływem lobbingu inwestorów.

  2.  Spis treści

    Directory of Open Access Journals (Sweden)

    ANNA BARTOSZEWICZ

    2015-03-01

    Full Text Available  Od Zespołu Redakcyjnego – Editorial .......................................................................................................... 7 Anna Bartoszewicz – Praktyczna realizacja Programu zapewnienia i poprawy jakości w komórkach audytu wewnętrznego na wybranych przykładach – Implementation of Quality Assurance and Improvement Program by internal audit teams on selected examples ................................................................ 9 Anna Białek-Jaworska, Natalia Nehrebecka – Struktura kapitałowa przedsiębiorstw w świetle wyników badań – Capital structure of companies in the light of research results ..................... 29 Magda Chraścina – Determinanty tworzenia rezerw oraz ich skutki bilansowo- -wynikowe na przykładzie spółek notowanych na Giełdzie Papierów Wartościowych w Warszawie – Determinants of creating provisions and their effect on the balance sheet and income statement on the example of companies listed on the Warsaw Stock Exchange .................................................................................................. 53 Małgorzata Garstka – Dobry obyczaj jako norma kształtująca zachowanie księgowych – Good practice as a norm shaping the behavior of accountants ...................... 73 Przemysław Kabalski, Joanna Szwajcar – Feminizacja studiów w zakresie rachunkowości w Polsce – przyczyny i skutki – Feminization of accounting studies in Poland – causes and consequences .. 85 Anna Kasperowicz – Znaki i kody rachunkowości w procesie komunikacji – Accounting signs and codes in the communication process .......................... 107 Marcin Kędzior – Dobrowolne stosowanie MSSF przez spółki giełdowe w wybranych krajach Europy Zachodniej – Voluntary adoption of IFRS by listed companies in selected Western European countries ................................................................................................. 123 Ewelina Zarzycka

  3. Kuhn e as ciências sociais

    Directory of Open Access Journals (Sweden)

    Jesus de Paula Assis

    1993-12-01

    Full Text Available No texto, são expostos os motivos básicos pelos quais o vocabulário emprestado de Thomas Kuhn - notadamente o termo paradigma - e o modelo de desenvolvimento científico exposto pelo autor em seu A estrutura das revoluções científicas foram tomados de empréstimo em textos que discutem a epistemologia das ciências sociais. A conclusão é que as supostas aplicações do modelo kuhniano às ciências sociais se baseiam em leitura que não encontra qualquer apoio no autor e, principalmente, obscurecem as implicações mais amplas de sua obra.The article shows for what reasons the vocabulary and the model for scientific growth of Thomas Kuhn were borrowed by epistemologists of the social sciences. The conclusion is that the texts produced in this vein are based in a shallow understanding of the author's main implications.

  4. O TOŻSAMOŚCI I POLITYCE

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    Katarzyna Warmińska

    2015-03-01

    Full Text Available Ostatnie dekady przyniosły znaczące zmiany w sferze stosunków etnicznych w Polsce. Można było zaob- serwować wzrastającą aktywność społeczności mniejszościowych, które stają się w coraz większym stopniu aktywnymi, coraz lepiej zorganizowanymi aktorami na scenie publicznej. W bardziej otwarty sposób komunikują swoje potrzeby, cele i wizje świata. Chcąc uchwycić istotę tych przemian postanowiłam zaaplikować, do ich analizy, koncepcję polityki tożsamości. Moim celem jest ukazanie swoistej „logiki” działania politycznego grup tożsamościowych, ze szczególnym uwzględnieniem jego wymiaru etnicznego z jednoczesnym wskazaniem na pożytek z zastosowania tego pojęcia do analizy zjawisk etnicznych w Polsce. Jako empiryczną egzemplifikację potraktowałam społeczność kaszubską.

  5. Natureza e ciências sociais

    Directory of Open Access Journals (Sweden)

    Gloria Maria Vargas

    2003-12-01

    Full Text Available A construção do sentido do termo natureza abrange diferentes áreas do conhecimento e tem sido objeto de reflexão tanto das ciências naturais quanto sociais. Nos desdobramentos do conhecimento produzido sobre esta temática existem diversas abordagens que, da perspectiva das ciências sociais, podem ser identificadas. O propósito deste artigo é considerar algumas dessas abordagens e relacioná-las com as novas práticas sociais que determinam formas de intervenção inéditas sobre a natureza, e que colocam questões para estas ciências, enquanto produtoras de conhecimento sobre o tema. De igual forma, explicita-se a substituição deste termo pelo de ambiente e, posteriormente, o aparecimento do desenvolvimento sustentável, como parte do cabedal conceitual com que a problemática em torno das relações naturezasociedade é abordada nas ciências sociais.La construcción del sentido del término naturaleza abarca diferentes áreas del conocimiento y ha sido objeto de reflexión tanto de las ciencias naturales como sociales. Los desdoblamientos del conocimiento producido sobre este tema muestran que existen diversos abordajes que pueden ser identificados desde la perspectiva de las ciencias sociales. El objetivo de este artículo es considerar algunos de esos abordajes y relacionarlos con las nuevas prácticas sociales que determinan formas de intervención inéditas sobre la naturaleza y que sugieren cuestionamientos para estas ciencias, como productoras de conocimiento sobre este tema. De igual manera, se explicita la substitución de este término por el de ambiente e, posteriormente, el aparecimiento del término desarrollo sostenible como parte del acervo conceptual con que es abordada la problemática alrededor de las relaciones naturaleza-sociedad en las ciencias sociales.The construction of the term nature involves different areas of knowledge and has been the object of inquiry of both natural and social sciences. The knowledge

  6. Static Code Analysis with Gitlab-CI

    CERN Document Server

    Datko, Szymon Tomasz

    2016-01-01

    Static Code Analysis is a simple but efficient way to ensure that application’s source code is free from known flaws and security vulnerabilities. Although such analysis tools are often coming with more advanced code editors, there are a lot of people who prefer less complicated environments. The easiest solution would involve education – where to get and how to use the aforementioned tools. However, counting on the manual usage of such tools still does not guarantee their actual usage. On the other hand, reducing the required effort, according to the idea “setup once, use anytime without sweat” seems like a more promising approach. In this paper, the approach to automate code scanning, within the existing CERN’s Gitlab installation, is described. For realization of that project, the Gitlab-CI service (the “CI” stands for "Continuous Integration"), with Docker assistance, was employed to provide a variety of static code analysers for different programming languages. This document covers the gene...

  7. Filosofia da ciência e ensino da ciência: uma analogia

    Directory of Open Access Journals (Sweden)

    Alberto Villani

    2001-01-01

    Full Text Available Neste trabalho, inicialmente explicitaremos nossa compreensão do debate entre Kuhn, Popper, Lakatos e Feyerabend na Conferencia Internacional sobre Filosofia da Ciência (1965, delineando as diferenças nas posições de nossos filósofos. Em seguida apresentaremos um quadro das posições sobre o ensino de ciências, assim como nos parecem caracterizar os último 30 anos de pesquisas na área. Finalmente tentaremos uma aproximação dos dois campos, procurando salientar as implicações que a problemática filosófica teve e tem para uma maior compreensão do ensino de ciências e matemática.

  8. Od ciężkości astmy do kontroli astmy. Metody oceny kontroli astmy

    Directory of Open Access Journals (Sweden)

    Joanna Mikołajczyk

    2009-09-01

    Full Text Available Według pierwszych wytycznych dotyczących postępowania w astmie leczenie astmy zależy od stopnia jej cięż- kości, określonej na podstawie objawów klinicznych i wskaźników czynności płuc. Ponieważ astma jest chorobą o zmiennym przebiegu, duże znaczenie ma jej ciągła ocena kliniczna i dostosowana do niej modyfikacja leczenia. Niestety, stopień ciężkości nie dopasowuje się elastycznie do odpowiedzi na leczenie. Biorąc ten fakt pod uwagę, światowi eksperci zalecają zmianę w postępowaniu z astmą, przedkładając uzyskanie klinicznej kontroli astmy nad ustaleniem stopnia jej ciężkości, wyróżniając astmę kontrolowaną, częściowo kontrolowaną i niekontrolowaną. Uzyskanie stanu pełnej kontroli astmy formułuje się w raporcie GINA 2006 jako główny cel leczenia. Kontrola astmy odnosi się do stopnia opanowania objawów i byłoby najlepiej, gdyby dotyczyła też markerów zapalenia i patofizjologicznych wykładników choroby. Określenie stopnia kontroli choroby zgodnie z obecnymi założeniami stanowi podstawę wyboru i modyfikacji leczenia – właściwe ustalenie stopnia kontroli astmy wpływa na skuteczność leczenia. Obecnie dostępnych jest wiele metod oceny kontroli astmy, wtym ocena parametrów klinicznych (objawy w ciągu dnia, objawy nocne, stosowanie leków rozszerzających oskrzela, ocena czynności płuc (PEF i FEV1, określenie zaawansowania zapalenia w drogach oddechowych (nieswoista nadreaktywność oskrzeli, stężenie tlenku azotu w powietrzu wydechowym, liczba eozynofili w plwocinie indukowanej. Dostępne są także subiektywnie oceniające kontrolę astmy kwestionariusze badawcze oraz szybkie testy kontroli astmy (ACT, ACQ, ATAQ. Z drugiej strony wciąż nie wypracowano jednoznacznego stanowiska, który z parametrów lub jakie połączenia parametrów najbardziej wiarygodnie określają kontrolę astmy. Ze względu na wieloczynnikową patogenezę astmy wydaje się, iż uzyskanie pe

  9. Particulate emissions from biodiesel fuelled CI engines

    International Nuclear Information System (INIS)

    Agarwal, Avinash Kumar; Gupta, Tarun; Shukla, Pravesh C.; Dhar, Atul

    2015-01-01

    Highlights: • Physical and chemical characterization of biodiesel particulates. • Toxicity of biodiesel particulate due to EC/OC, PAHs and BTEX. • Trace metals and unregulated emissions from biodiesel fuelled diesel engines. • Influence of aftertreatment devices and injection strategy on biodiesel particulates. • Characterization of biodiesel particulate size-number distribution. - Abstract: Compression ignition (CI) engines are the most popular prime-movers for transportation sector as well as for stationary applications. Petroleum reserves are rapidly and continuously depleting at an alarming pace and there is an urgent need to find alternative energy resources to control both, the global warming and the air pollution, which is primarily attributed to combustion of fossil fuels. In last couple of decades, biodiesel has emerged as the most important alternative fuel candidate to mineral diesel. Numerous experimental investigations have confirmed that biodiesel results in improved engine performance, lower emissions, particularly lower particulate mass emissions vis-à-vis mineral diesel and is therefore relatively more environment friendly fuel, being renewable in nature. Environmental and health effects of particulates are not simply dependent on the particulate mass emissions but these change depending upon varying physical and chemical characteristics of particulates. Particulate characteristics are dependent on largely unpredictable interactions between engine technology, after-treatment technology, engine operating conditions as well as fuel and lubricating oil properties. This review paper presents an exhaustive summary of literature on the effect of biodiesel and its blends on exhaust particulate’s physical characteristics (such as particulate mass, particle number-size distribution, particle surface area-size distribution, surface morphology) and chemical characteristics (such as elemental and organic carbon content, speciation of polyaromatic

  10. Combustion Stratification for Naphtha from CI Combustion to PPC

    KAUST Repository

    Vallinayagam, R.; Vedharaj, S.; An, Yanzhao; Dawood, Alaaeldin; Izadi Najafabadi, Mohammad; Somers, Bart; Johansson, Bengt

    2017-01-01

    This study demonstrates the combustion stratification from conventional compression ignition (CI) combustion to partially premixed combustion (PPC). Experiments are performed in an optical CI engine at a speed of 1200 rpm for diesel and naphtha (RON

  11. The configuration-driven table CI method and comparison with integral-driven CI procedures

    International Nuclear Information System (INIS)

    Buenker, R.J.

    1980-01-01

    A new configuration-driven CI algorithm is outlined which eliminates the need for explicit comparison of pairs of Slater determinants through the use of a series of compact tables. In this scheme each pair of configurations is either shown to be non-interacting or to fall into one of nine cases, each of which is characterized fully once certain orbital permutations are determined. The program is divided into three parts: a case structure analysis step including integral label generation, a sort of the required electron repulsion integrals, and finally a procedure in which the foregoing information is combined with tabulated directions for the evaluation of the necessary Hamiltonian matrix elements over spin-adapted functions. Timing improvements of up to more than a factor of four have been achieved with the new algorithm

  12. Do estilo em ciência e em história das ciências

    Directory of Open Access Journals (Sweden)

    Michel Paty

    2012-08-01

    Full Text Available Ao considerar o conhecimento científico como uma forma de pensamento simbólico, entende-se com isso não simples sistemas de signos, mas conteúdos de pensamento (expressos por conceitos ligados entre si e que fazem sentido, que são, no espaço das representações mentais, os substitutos do "dado objetivo" que se supõe subjazer à experiência que fazemos do "mundo" pelos sentidos e, nesse nível indissociavelmente, pelo entendimento. Esse pensamento simbólico adquire densidade e consistência pela "tecelagem" realizada graças ao trabalho dos pensamentos individuais que se comunicam, social e culturalmente, inscritos no tempo da história. Da tensão dinâmica entre o sujeito do conhecimento, que busca a inteligibilidade (pela operação de sua razão, e a objetividade dos conteúdos que ele se propõe (inicialmente dados, depois modificados ou produzidos, resulta o movimento do pensamento científico e a transformação dos conhecimentos. Esse trabalho do pensamento simbólico é marcado por um estilo próprio a cada um, mas que em parte pode ser comum em contextos, escolas ou tradições. Em ciência e em história das ciências, o estilo intervém em dois níveis: o da abordagem "objetal" da produção das obras pelos cientistas e o da abordagem "reflexiva" da história epistemológica e da filosofia, que se interrogam sobre a significação tanto dos próprios conteúdos de conhecimento quanto do pensamento racional, simbólico, cuja função é manifestá-los.By considering scientific knowledge as a form of symbolic thought, we do not mean by the latter simply systems of signs, but thought contents (expressed by concepts related between them and providing meaning ; they are, in the space of mental representations, the substitutes of the «objectively given» that one supposes to underly the experience of the «world» done through the senses and the understanding, both being indissociable at this level. This symbolic thought gets

  13. Structural Biology of CI from Phage TP901-1

    DEFF Research Database (Denmark)

    Rasmussen, Kim Krighaar

    (CTD), separated by a linker of various lengths. The NTD is responsible for DNA binding and the CTD is responsible for oligomerization of the CI protein. A Helix-turn-Helix motif is usually responsible for DNA binding. This thesis presents a structural characterization of the CI repressor from TP901...... condition of the CTD, responsible for the arrangement of the hexameric CI repressor. The arrangement of the CI repressor for TP901-1 has previously been described to have 32 point group symmetry based on SAXS studies. The CTD crystallizes with P3121 or P3221 symmetry with one molecule in the asymmetric unit......-length CI can only be answered unambiguously by solving the CTD crystal structure or by use of alternative techniques on the full-length CI....

  14. Nowe zasady działalności firm audytorskich

    Directory of Open Access Journals (Sweden)

    Kazimierz Sawicki

    2009-03-01

    Full Text Available W artykule przedstawiono zmiany, stanowiące implementację Dyrektywy 2006/43/WE Unii Europejskiej w części dotyczącej funkcjonowania firm audytorskich w Polsce. Zgłoszono uwagi popierające nowe rozwiązania, jak też zawierające wątpliwości dotyczące skuteczności ich stosowania w praktyce.

  15. Wrap it in rap! - Music Making with Adolescent CI Users

    DEFF Research Database (Denmark)

    Petersen, Bjørn; Sørensen, Stine Derdau; Pedersen, Ellen Raben

    2015-01-01

    The purpose of this study was to examine 1) the potential effects of an intensive musical ear training program on the perception of music and speech in prelingually hearing impaired adolescent cochlear implant (CI) users and 2) these adolescents’ music engagement. Eleven adolescent CI users parti...... and repetitive focus on language, articulation, rhythm and rhyme and might even represent a possible form of artistic expression for some of the young CI users....

  16. Filosofia das ciências sociais: temas atuais

    OpenAIRE

    Kincaid, Harold

    2014-01-01

    A filosofia das ciências sociais, concebida da maneira adequada, tem algo a oferecer aos que praticam as ciências sociais. Os cientistas sociais adotam em suas pesquisas, ainda que de forma implícita, alguma filosofia de sua ciência. Para evitar impasses, é melhor explicitar essa filosofia e ser criticamente consciente dos seus méritos. A filosofia das ciências sociais, por sua vez, não pode ser praticada sem um envolvimento íntimo com a pesquisa social. O artigo esboça alguns desenvolvimento...

  17. Characteristics and determinants of music appreciation in adult CI users.

    Science.gov (United States)

    Philips, Birgit; Vinck, Bart; De Vel, Eddy; Maes, Leen; D'Haenens, Wendy; Keppler, Hannah; Dhooge, Ingeborg

    2012-03-01

    The main objective of this study was to assess the associations between self-reported listening habits and perception of music and speech perception outcomes in quiet and noise for both unilateral cochlear implant (CI) users and bimodal (CI in one ear, hearing aid in contra-lateral ear) users. Information concerning music appreciation was gathered by means of a newly developed questionnaire. Moreover, audiological data (pure-tone audiometry, speech tests in noise and quiet) were gathered and the relationship between speech perception and music appreciation is studied. Bimodal users enjoy listening to music more in comparison with unilateral CI users. Also, music training within rehabilitation is still uncommon, while CI recipients believe that music training might be helpful to maximize their potential with current CI technology. Music training should not be exclusively reserved for the good speech performers. Therefore, a music training program (MTP) that consists of different difficulty levels should be developed. Hopefully, early implementation of MTP in rehabilitation programs can enable adult CI users to enjoy and appreciate music and to maximize their potential with commercially available technology. Furthermore, because bimodal users consider the bimodal stimulation to be the most enjoyable way to listen to music, CI users with residual hearing in the contra-lateral ear should be encouraged to continue wearing their hearing aid in that ear.

  18.  Dylematy harmonizacji rachunkowości

    Directory of Open Access Journals (Sweden)

    Jerzy Gierusz

    2015-06-01

    Full Text Available Harmonizacja rachunkowości finansowej jest procesem przynoszącym wiele korzyści, ale także generującym poważne zagrożenia. Wśród pozytywnych stron harmonizacji wymienić należy: wzmocnienie funkcji alokacyjnej rynków kapitałowych, wzrost zaufania inwestorów do sprawozdań finansowych, rozszerzenie możliwości pozyskiwania kapitału pożyczkowego, obniżenie kosztów funkcjonowania korporacji międzynarodowych. Towarzyszące harmonizacji zjawiska niepożądane to: wyeliminowanie porównywalności sprawozdań finansowych na poziomie krajowym, przekreślenie znacznej części dorobku szkoły kontynentalnej rachunkowości, ustanowienie monopolu w tworzeniu standardów, zanik normatywnego nurtu badań w rachunkowości.

  19. Spectral reflectance properties of carbonaceous chondrites: 1. CI chondrites

    Science.gov (United States)

    Cloutis, E. A.; Hiroi, T.; Gaffey, M. J.; Alexander, C. M. O.'D.; Mann, P.

    2011-03-01

    Existing reflectance spectra of CI chondrites (18 spectra of 3 CIs) have been augmented with new (18 spectra of 2 CIs) reflectance spectra to ascertain the spectral variability of this meteorite class and provide insights into their spectral properties as a function of grain size, composition, particle packing, and viewing geometry. Particle packing and viewing geometry effects have not previously been examined for CI chondrites. The current analysis is focused on the 0.3-2.5 μm interval, as this region is available for the largest number of CI spectra. Reflectance spectra of powdered CI1 chondrites are uniformly dark (IOM), as no other CI opaque phase appears able to produce concurrent darkening and bluing. Magnetite can also explain the presence of an absorption feature near 1 μm in some CI spectra. The most blue-sloped spectra are generally associated with the larger grain size samples. For incidence and emission angles <60°, increasing phase angle results in darker and redder spectra, particularly below ∼1 μm. At high incidence angles (60°), increasing emission angle results in brighter and redder spectra. More densely packed samples and underdense (fluffed) samples show lower overall reflectance than normally packed and flat-surface powdered samples. Some B-class asteroids exhibit selected spectral properties consistent with CI chondrites, although perfect spectral matches have not been found. Because many CI chondrite spectra exhibit absorption features that can be related to specific mineral phases, the search for CI parent bodies can fruitfully be conducted using such parameters.

  20. Implications of CI therapy for Visual Deficit Training

    Directory of Open Access Journals (Sweden)

    Edward eTaub

    2014-10-01

    Full Text Available We address here the question of whether the techniques of CI therapy, a family of treatments that has been employed in the rehabilitation of movement and language after brain damage might apply to the rehabilitation of such visual deficits as unilateral spatial neglect and visual field deficits. CI therapy has been used successfully for the upper and lower extremities after chronic stroke, cerebral palsy (CP, multiple sclerosis (MS, other CNS degenerative conditions, resection of motor areas of the brain, focal hand dystonia, and aphasia. Treatments making use of similar methods have proven efficacious for amblyopia.The CI therapy approach consists of four major components: intensive training, training by shaping, a transfer package to facilitate the transfer of gains from the treatment setting to everyday activities, and strong discouragement of compensatory strategies.CI therapy is said to be effective because it overcomes learned nonuse, a learned inhibition of movement that follows injury to the CNS. In addition, CI therapy produces substantial increases in the grey matter of motor areas on both sides of the brain. We propose here that these mechanisms are examples of more general processes: learned nonuse being considered parallel to sensory nonuse following damage to sensory areas of the brain, with both having in common diminished neural connections (DNC in the nervous system as an underlying mechanism. CI therapy would achieve its therapeutic effect by strengthening the diminished neural connections. Use-dependent cortical reorganization is considered to be an example of the more general neuroplastic mechanism of brain structure repurposing (BSR. If the mechanisms involved in these broader categories are involved in each of the deficits being considered, then it may be the principles underlying efficacious treatment in each case may be similar. The lessons learned during CI therapy research might then prove useful for the treatment of

  1. Hírpiacok szimulációja

    OpenAIRE

    Németh, András

    2005-01-01

    Hírtőzsdén olyan, általában elektronikus piacot értünk, ahol különféle jövőbeli eseményekre lehet fogadni. Mint azt már több vizsgálat is megmutatta, ezek a játéktőzsdék alkalmasak arra, hogy a résztvevők rendelkezésére álló elszórt részinformációkat összegyűjtsék, egyetlen árfolyammá alakítsák (információaggregáció), és ezzel előre jelezzék az eseményeket. Jelen tanulmány célja e hírtőzsdék és szereplőinek modellezése, valamint az információaggregáció vizsgálata. Ennek érdekében felépítünk e...

  2. A ideia de ciência em Karl Marx

    Directory of Open Access Journals (Sweden)

    Ricardo Luís Chaves Feijó

    2015-12-01

    ideias: a economia política clássica e o legado alemão. Em seguida, investiga-se o que seria a sua concepção particular de ciência, entendida como uma proposta de fundir esses dois legados. Avalia-se, em seguida, o caráter científico da contribuição marxiana, entendida como o fazer de uma ciência que se propõe positiva. Destarte, iremos examinar as razões que separam a tradição marxiana e o mainstream da economia atual, mostrando que a natureza peculiar de uma ciência de raízes alemãs gera dificuldades na comunicação entre uma e outra.

  3. Using the Web for Competitive Intelligence (CI) Gathering

    Science.gov (United States)

    Rocker, JoAnne; Roncaglia, George

    2002-01-01

    Businesses use the Internet as a way to communicate company information as a way of engaging their customers. As the use of the Web for business transactions and advertising grows, so too, does the amount of useful information for practitioners of competitive intelligence (CI). CI is the legal and ethical practice of information gathering about competitors and the marketplace. Information sources like company webpages, online newspapers and news organizations, electronic journal articles and reports, and Internet search engines allow CI practitioners analyze company strengths and weaknesses for their customers. More company and marketplace information than ever is available on the Internet and a lot of it is free. Companies should view the Web not only as a business tool but also as a source of competitive intelligence. In a highly competitive marketplace can any organization afford to ignore information about the other players and customers in that same marketplace?

  4. Cinema, ciência e percepção.

    Directory of Open Access Journals (Sweden)

    Márcio Barreto

    Full Text Available Resumo O cinema invoca a questão dos limites da percepção humana, pois modula o tempo em imagens tão reais quanto artificiais, revelando algo mais próximo de uma nova dimensão da realidade do que de sua representação. No início do século XX, a ciência modifica o real percebido através das lentes dos microscópios e das teorias da física moderna; o parentesco entre cinema e ciência está principalmente naquilo que excede o campo perceptivo e é explorado neste artigo para mostrar como a tensão entre o caráter estático da fotografia e a fluidez fugitiva do tempo revela a ciência sem seus estereótipos habituais.

  5. Evaluation of the Clinical Data Dictionary (CiDD)

    Science.gov (United States)

    Lee, Myung Kyung; Min, Yul Ha; Kim, Younglan; Min, Hyo Ki; Ham, Sung Woo

    2010-01-01

    Objectives The purpose of the study was to evaluate content coverage and data quality of the Clinical Data Dictionary (CiDD) developed by the Center for Interoperable EHR (CiEHR). Methods A total of 12,994 terms were collected from 98 clinical forms of a tertiary cancer center hospital with 500 beds. After data cleaning, 9,418 terms were mapped with the data items of the CiDD by the research team, and validated by 30 doctors and nurses at the research hospital. Results Mapping results were classified into five categories: lexically mapped; semantically mapped; mapped to either a broader term or a narrower term; mapped to more than one term and not mapped. In terms of coverage, out of 9,418 terms, 6,750 (71.7%) terms were mapped; 4,319 (45.9%) terms were lexically mapped; 2,431 (25.8%) were semantically mapped; 281 (3.0%) terms were mapped to a broader term; 43 (0.5%) were mapped to a narrower term; and 550 (5.8%) were mapped to more than one term. In terms of data quality, the CiDD has problems such as errors in concept namingand representation, redundancy in synonyms, inadequate synonyms, and ambiguity in meaning. Conclusions Although the CiDD has terms covering 72% of local clinical terms, the CiDD can be improved by cleaning up errors and redundancies, adding textual definitions or use cases of the concept, and arranging the concepts in a hierarchy. PMID:21818428

  6. Nauczanie sprawności komunikacyjnych w grupach ekonomicznych

    OpenAIRE

    Wielkiewicz-Jałmużna, Dorota

    2013-01-01

    Celem nauczania języka polskiego w grupach ekonomicznych jest przede wszystkim rozwijanie kompetencji uczących się. Kluczowe znaczenie mają umiejętności receptywne czyli rozumienie ze słuchu i czytanie. Istotne znaczenie ma również nauczanie sprawności produktywnych to jest mówienia i pisania. Kolejnymi sprawnościami językowymi, które uczniowie zdobywają pod nadzorem nauczyciela są: umiejętność interakcji i mediacji.

  7. Ciência e Direitos Humanos: direitos culturais e maternidade

    OpenAIRE

    Lopes, Allice Ferreira; Gomes, Ana Lucia de Abreu

    2018-01-01

    O objetivo desse artigo é analisar a ligação entre ciência e cultura bem como seu impacto entre as mulheres, especialmente durante a maternidade, destacando a recente conquista dos espaços públicos. Foi realizado levantamento bibliográfico sobre o tema dos Direitos Humanos das Mulheres e a visão sobre as mulheres na Ciência. Posteriormente é apresentada pesquisa sobre legislações e normativas disponíveis nos portais virtuais do Instituto do Patrimônio Histórico e Artístico Nacional, com desta...

  8. Ceux-ci ne sont pas : [luuletused] / Kalju Kruusa

    Index Scriptorium Estoniae

    Kruusa, Kalju, pseud., 1973-

    2003-01-01

    Sisu: Ceux-ci ne sont pas ; Köögivahet ; "Taara..." ; "Pakane pistab pisikesi ..." ; "Meri on kaet mattklaasiga ; Pydemise päivil ; "Toas muusika mängib ..." ; "Jäin juustu imetlema ; "Mu elu on mustikas ..." ; Hingepidetus ; ŁNo me gusta la cocina

  9. Por uma ciência do riso e da sabedoria

    Directory of Open Access Journals (Sweden)

    Paula Corrêa Henning

    2010-06-01

    Full Text Available

    O artigo busca problematizar a história das ciências, especialmente o ethos da Modernidade e Pós-modernidade. Para isso, utiliza autores que se anteciparam à Pós-modernidade como Friedrich Nietzsche e Michel Foucault. Na esteira dessa discussão busca uma problematização acerca da Ciência nos rastros da Modernidade e algumas fissuras e fragilidades produzidas na ciência num cenário contemporâneo. Apresenta ainda alguns discursos midiáticos acerca de propagandas televisivas que trazem o discurso científico como legítimo e inabalável. Traz para o campo de discussão uma ciência alegre, como aprendemos com Nietzsche ou prosaica por vezes, anunciando o riso e a sabedoria na produção do conhecimento científico.

     

  10. Calculation of particle dynamics in CI-10 cyclotron

    International Nuclear Information System (INIS)

    Samsonov, E.V.; Karamysheva, G.A.; Vorozhtsov, S.B.

    1999-01-01

    The calculations of beam dynamic characteristics of High-Intensity Cyclotron-Injector CI-10 for deuteron beam of 15 MeV energy are presented. Analytical estimations of space charge effects are given. In order to increase the intensity of the accelerator beam some ideas about the cyclotron design modification are given too. (author)

  11. Uwarunkowania skuteczności działania inkubatorów przedsiębiorczości

    OpenAIRE

    Świeszczak, Krzysztof

    2016-01-01

    Skłonność społeczeństwa do prowadzenia własnej działalności gospodarczej odgrywa istotną rolę w rozwoju krajowych gospodarek. Biorąc pod uwagę charakterystykę jednostek należących do sektora MSP, ich potrzeby oraz bariery, niekiedy uniemożliwiające egzystencję na rynku, warto zwrócić uwagę na konieczność kreowania narzędzi wspomagających przedsiębiorczość. Spośród licznych instrumentów wsparcia jednostek z sektora MSP na szczególną uwagę zasługują inkubatory przedsiębiorczości , których dział...

  12. BIOGRAMY POLSKICH MYŚLICIELI RACHUNKOWOŚCI

    Directory of Open Access Journals (Sweden)

    Renata Biadacz

    2009-09-01

    Full Text Available Fragmenty artykułu: Włodzimierz Brzezin (1926–2008, profesor zwyczajny, doktor habilitowany, urodził się 1 lipca 1926 r. w Wieluniu, zmarł 29 grudnia 2008 r. w Częstochowie. (... Bilans działalności i osiągnięć Profesora Brzezina jest bardzo bogaty i trudno go przedstawić w skrócie. Należy jednak zaznaczyć, że jedną z cech charakteryzujących całokształt Jego zainteresowań naukowych jest szeroki krąg tematyczny. Obejmuje zagadnienia teoretyczne i praktyczne rachunkowości, zarówno sensu stricte, jak i sensu largo, jak również problematykę teorii pomiaru, analizy finansowej, controllingu, polityki bilansowej, wykorzystania rachunku kosztów przez kadrę inżynierską. Zdzisław Kołaczyk (1927–2008 docent doktor, urodził się 15 czerwca 1927 r. w Częstochowie, zmarł 9 lipca 2008 r. w Poznaniu. (... Działalność naukowa doc. dr Z. Kołaczyka skupiała się głównie na rachunkowości finansowej. Początkowo Jego zainteresowania naukowe koncentrowały się na rachunku kosztów przedsiębiorstw przemysłowych i budowlanych. Z tego zakresu opublikował kilka interesujących artykułów naukowych, zamieszczonych w Ruchu Prawniczym, Ekonomicznym i Socjologicznym oraz w Zeszytach Naukowych WSE w Poznaniu. W kolejnych latach doc. dra Z. Kołaczyka interesował rozwój rachunkowości jako nauki i działalności praktycznej

  13. A ciência no espaço educacional da criança: do fazer ciência à ciência do fazer

    Directory of Open Access Journals (Sweden)

    Carolina Rodrigues de Souza

    2016-05-01

    Full Text Available This article aims to reflect on the possible articulations of the development of science in the education of children and their respective childhoods. While in Kindergarten and Elementary School students are, above all, children, and as such, subjects endowed with intelligence, emotions, and feelings. They are able to make observations, retain information, propose arguments, participate in discussions, and make choices that allow them to exercise free expression of theirs thoughts in many different languages. However, to ensure the effective participation of the child as a subject of today, not an intented being, it is necessary to reconsider the actions and relationships in the school environment. In this sense, this study highlights contributions on how the educational process of science can/should be thought in the process of children education. Also, we hope to provide access to scientific culture without detracting the childhoods. We highlight the possibility of using some powerful elements of science in the school environment to sharpen curiosity and improve new worldviews. Often different from the adult perspective, science in children education should emphasize issues such as the specificity of child logic, which encompasses creativity, imagination, fantasy, and desire. This article, in its theoretical nature, discusses notions such as childhood, children, and science in order to consider a type of early childhood education in which an educational routine with elements of scientific culture would enable the occurrence of childhood practice. Este artigo objetiva refletir sobre as possíveis articulações do desenvolvimento das ciências na educação das crianças e suas respectivas infâncias e parte da compreensão de que na Educação Infantil e nos primeiros anos do Ensino Fundamental, os estudantes antes de alunos são crianças, e como tais, são sujeitos completos, dotados de inteligência, emoções e sentimentos; capazes de

  14. Kontrowersje w leczeniu dietetycznym otyłości

    Directory of Open Access Journals (Sweden)

    Irena Białokoz-Kalinowska

    2009-03-01

    Full Text Available Otyłość jest zjawiskiem coraz częściej występującym na świecie. Szacuje się, że ponad połowę dorosłej populacji krajów uprzemysłowionych dotknęła nadwaga, a odsetek otyłości w niektórych krajach (USA, Wielka Brytania wzrasta do 30%. Ta niepokojąca tendencja obserwowana jest również w populacji dzieci i młodzieży. Epidemia otyłości rozpoczęła się w latach 80. i trwa nieprzerwanie do chwili obecnej, stając się poważnym problemem społeczno-medycznym współczesnego świata. Przyczyny tego zjawiska są złożone i wynikają z uwarunkowań biologicznych i środowiskowych, w szczególności z niedostatecznej codziennej aktywności fizycznej oraz złych nawyków żywieniowych. Do tej pory nie udało się wypracować w pełni efektywnej strategii leczenia otyłości. Promocja zdrowego stylu życia oraz właściwych nawyków żywieniowych adresowana do całej populacji stanowi podstawę prewencji i leczenia otyłości. Powszechnie stosowane różnego rodzaju diety odchudzające zawierają często sprzeczne zalecenia. Istniejące kontrowersje utrudniają wybór skutecznej diety w celu redukcji masy ciała, a ich mnogość i różnorodność wprowadzają swoisty chaos informacyjny. Efekty wielu diet są krótkotrwałe i obarczone efektem jo-jo. W wielu przypadkach brak jest jakichkolwiek przesłanek naukowych uzasadniających dane postępowanie dietetyczne. Właśnie dlatego wciąż istnieje potrzeba prowadzenia dalszych badań naukowych umożliwiających w sposób obiektywny ocenę skuteczności dietetycznych metod leczenia otyłości. W niniejszej pracy autorzy przedstawiają spotykane w praktyce różne dietetyczne podejścia do problemu otyłości, wskazując na ich efektywność i naukowe uzasadnienie.

  15. Transseksualizm – pytania i wątpliwości

    Directory of Open Access Journals (Sweden)

    Magdalena Radko

    2012-06-01

    Full Text Available Wiek dojrzewania jest czasem określania własnej tożsamości, odkrywania pragnień, dążeń, również w sferze sek‑ sualności. Poszukiwanie siebie, własnej orientacji seksualnej, znajdowanie pierwszych obiektów pożądania jest dla adolescenta nowym, ważnym przeżyciem, wyzwalającym silne emocje. Czasami jednak młody człowiek staje wo‑ bec dużych trudności, bowiem to, co odkrywa w sobie, nie znajduje umocowania w społecznych normach, nie jest akceptowane przez rodzinę i otoczenie, a w związku z tym dla samego adolescenta staje się ciężarem trudnym do uniesienia. Konsekwencją nieradzenia sobie z własną seksualnością, jej odbiorem rodzinnym lub społecznym mogą być zaburzenia depresyjne, lękowe, zaburzenia odżywiania oraz różnorodne formy autoagresji. W obliczu wysokie‑ go ryzyka występowania zaburzeń psychicznych u osób w wieku rozwojowym, u których seksualność kształtuje się w sposób odmienny, należy rozważać szerokie spektrum czynników mogących determinować takie, a nie inne oblicze seksualności. Intencją autorów pracy było przedstawienie, w oparciu o przypadek kliniczny, historii człowieka odkry‑ wającego swoją tożsamość płciową, biorąc pod uwagę zarówno osobnicze uwarunkowania, przebyte zdarzenia trau‑ matyczne, jak i kontekst rodzinny pacjenta oraz konsekwencje procesu coming out. Autorzy starali się zwrócić uwagę na złożoność i wielostopniowość procesu ujawniania się, który stał się możliwy dopiero po zapewnieniu adolescen‑ towi zrozumienia, wsparcia i akceptacji. Tym samym ukazano kluczową rolę środowiska, które może sprzyjać pro‑ cesowi odkrywania się i umożliwić go lub przeciwnie – utrudnić czy też całkowicie go zablokować. Transseksualizm w różnych środowiskach budzi sporo kontrowersji, pytań i wątpliwości. Historia hospitalizowanego pacjenta obrazu‑ je złożoność problemów, z którymi zmagają się osoby z zaburzeniami tożsamości

  16. DNA damage in isolated rat hepatocytes exposed to C.I. pigment orange 5 and C.I. pigment yellow 12 by the alkaline comet assay

    DEFF Research Database (Denmark)

    Møller, P; Wallin, Håkan; Grunnet, N

    1998-01-01

    The induction of DNA damage by commonly used printing ink pigments, C.I. pigment orange 5 (C.I. 12075) and C.I. pigment yellow 12 (C.I. 21090), was investigated in freshly isolated rat hepatocytes with the comet assay. C.I. pigment yellow 12 is a 3,3'-dichlorobenzidine-based diarylide pigment...

  17. Notas sobre o autotelismo discursivo em ciências humanas

    Directory of Open Access Journals (Sweden)

    Paulo Eduardo Lopes

    1994-12-01

    Full Text Available O Ateliê de Semiótica Discursiva, coordenado por Denis Bertrand, propôs focalizar, no ano letivo 1991-1992, a " Estética do Discurso Erudito", no quadro da temática "Estética da Ética" do Seminário de Semântica Geral, de A.J . Greimas, na Escola de Altos Estudos em Ciências Sociais de Paris (E. H. E. S. S.. Bertrand distribuiu cópias de trechos de textos célebres em ciências humanas (Lévi-Strauss, Deleuze e Guattari, Greimas, Barthes, Foucault e outros, sobre os quais os participantes deveriam realizar análises que tomassem como modelo, por exemplo, aquelas praticadas por Greimas e Landowski em lntroduction à L 'Analyse du Discours en Sciences Sociales ( 1979.

  18. Preparation of 1 Ci of europium 155 without carrier

    International Nuclear Information System (INIS)

    Falconi, N.; Radicella, R.

    1968-01-01

    High activity 'point' sources of 155 Eu are used for medical and industrial applications. For this purpose we have studied a method of obtaining I Ci of carrier free 155 Eu, with a solid residue smaller than 5 mg per Ci. In order to separate the 155 Eu from several grams of a 154 Sm enriched target we propose a procedure which is based on the work of Bouissieres and David, Onstott, and Takekoshi et al. The separation is carried out by electrolysis on a mercury cathode followed by purification on ion exchange resin. The yields of the europium separation and target recovery are 80 per cent and 90 per cent respectively. The time required for the procedure is three days. (authors) [fr

  19. Harnessing Neuroplasticity to Promote Rehabilitation: CI Therapy for TBI

    Science.gov (United States)

    2016-10-01

    occasions, magnetic resonance imaging ( MRI ), diffusion tensor imaging (DTI), and functional MRI (fMRI) of the brain will be carried out to determine changes...to which types of neuroplasticity-inducing pharmacological agents, when combined with CI therapy, are most likely to yield a superior treatment...were negotiated with the Birmingham VAMC, Denver VAMC, and Richmond VAMC. • The option of collecting MRI data using a 1.5T scanner was added for

  20. O Jornal Nacional e a Ciência

    Directory of Open Access Journals (Sweden)

    Diego Andres Salcedo

    2009-10-01

    Full Text Available Entendendo a informação científica como aquela capaz de contribuir para o desenvolvimento de uma cultura científica, analisamos neste trabalho aspectos relacionados à presença da informação sobre ciência no Jornal Nacional (JN, da Rede Globo de Televisão. A partir da observação do noticiário veiculado de 1º de janeiro a 31 de março de 2007, foi possível identificar 88 matérias que traziam informações relacionadas à ciência. O corpus nos permitiu categorizar os tipos de inserção da ciência no JN, esboçar o interesse do JN pelos temas científicos e discutir seu papel na formação de uma cultura científica do povo brasileiro.

  1. Skinner: sobre ciência e comportamento humano

    Directory of Open Access Journals (Sweden)

    Angelo Augusto Silva Sampaio

    Full Text Available Atualmente, não se pode pensar no estudo do comportamento humano sem considerar a abordagem científica a este objeto: o campo da Psicologia científica. Esse campo é disputado por diversos enfoques teóricos que divergem quanto ao modo como definem ciência e comportamento humano. A abordagem de B. F. Skinner foi bastante proeminente no século XX, mas ainda continua a ser mal-entendida. Partindo do desenvolvimento histórico de sua obra, o presente texto visa a iluminar alguns aspectos relacionados às noções de ciência e comportamento humano desse autor e ressaltar as transformações por que passaram. Analisam-se três tópicos da obra de Skinner: seu período inicial (de 1930 a cerca de 1938, a obra "Ciência e Comportamento Humano" de 1953, e as influências da Biologia. São enfatizados aspectos relevantes da sua teorização sobre o tema: busca por relações funcionais, ênfase nos dados empíricos, operacionismo, externalismo, multideterminação do comportamento, experimentalismo, previsão e controle, ética.

  2. /Cu-Al System

    Science.gov (United States)

    Kish, Orel; Froumin, Natalya; Aizenshtein, Michael; Frage, Nachum

    2014-05-01

    Wettability and interfacial interaction of the Ta2O5/Cu-Al system were studied. Pure Cu does not wet the Ta2O5 substrate, and improved spreading is achieved when relatively a high fraction of the active element (~40 at.% Al) was added. The Al2O3 and AlTaO4 phases were observed at the Ta2O5/Cu-Al interface. A thermodynamic evaluation allowed us to suggest that the lack of wetting bellow 40 at.% Al is due to the presence of a native oxide, which covers the drop. The conditions of the native oxide decomposition and the formation of the volatile Al2O suboxide strongly depend on the vacuum level during sessile drop experiments and the composition of the Cu-Al alloy. In our case, Al contents greater than 40% provides thermodynamic conditions for the formation of Al2O (as a result of Al reaction with Al2O3) and the drop spreading. It was suggested that the final contact angle in the Ta2O5/Cu-Al system (50°) is determined by Ta adsorption on the newly formed alumina interlayer.

  3. Beer improves copper metabolism and increases longevity in Cu-deficient rats

    International Nuclear Information System (INIS)

    Moore, R.J.; Klevay, L.M.

    1989-01-01

    Moderate consumption of alcoholic beverages decreases risk of death from ischemic heart disease (IHD). Evidence suggests that Cu-deficiency is important in the etiology and pathophysiology of IHD. The effect of beer (25 ng Cu/ml) drinking on the severity of Cu-deficiency was examined in weanling, male Sprague-Dawley rats fed a low Cu diet (0.84 μg Cu/g). Beer drinking increased median longevity to 204 or 299 d from 62 or 42 d respectively in rats drinking water in two experiments (15 rats/group). In experiment 3, a single dose of 67 Cu (3.3 μCi as chloride) was added to 1 g of feed and given to 12-h fasted rats 30 d after the start of the experiment. Whole body counting over 13 d showed apparent Cu absorption and t 1/2 (biological) were greater in Cu-deficient rats drinking beer than in similar rats drinking water. Plasma cholesterol was lower but hematocrit and liver Cu were higher in surviving rats drinking beer than in rats drinking water. Body weight was not affected by beer in any experiment. In experiment 4, a 4% aqueous ethanol solution had no effect on longevity of copper deficient rats. A non-alcohol component of beer alters Cu metabolism and mitigates the severity of nutritional Cu-deficiency in rats

  4. Filosofia da ciência, ensino de ciências e psicanálise: Explorando analogias

    Directory of Open Access Journals (Sweden)

    Alberto Villani

    2005-06-01

    Full Text Available Desenvolveremos um esquema referente às atitudes dos cientistas frente ao conhecimento científico, tendo como referência, de um lado, o debate entre Kuhn, Pepper, Lakatos e Feyerabend e, de outro, conceitos da psicanálise lacaniana. Em seguida, exploraremos esse esquema com uma analogia que nos permitirá elaborar novas interpretações para a educação em Ciências.

  5. BIOGRAMY POLSKICH MYŚLICIELI NIERUCHOMOŚCI

    Directory of Open Access Journals (Sweden)

    Edyta Łazarowicz

    2009-11-01

    Full Text Available Fragment artykułu: [b]Andrzej Bieniek[/b] (1895-1944, doktor, urodził się 17 października 1895 r. w Bratucicach (powiat Bochnia, rozstrzelany 26 lipca 1944 roku w ruinach getta w Warszawie. (...Doktor A. Bieniek zajmował się głównie problemami organizacji księgowości w przedsiębiorstwach oraz rachunkiem kosztów. Był autorem m.in. następujących publikacji: Polska metoda księgowości oparta na ekonomicznym systemie Taylora (Biblioteka Państwowej Szkoły Handlowej Męskiej w Łodzi, Łódź 1927, Kantor wzorowy w szkołach handlowych (Biblioteka Państwowej Szkoły Handlowej Męskiej w Łodzi, Warszawa-Łódź 1928, Księgowość w przedsiębiorstwach przemysłowych (Biblioteka Rady Głównej Zrzeszeń Księgowych i Rzeczoznawców Księgowości w Polsce, Warszawa 1935, Zasady inwentaryzacji i bilansowania (Związek Księgowych w Polsce, Warszawa 1936, Organizacja rachunkowości w przedsiębiorstwach przemysłowych ((Związek Księgowych w Polsce, Warszawa 1939, Zasady analizy bilansów (Stowarzyszenie Nauczycieli Szkół Zawodowych. Sekcja Główna Handlowa, Warszawa 1939. [b]Zygmunt Stefan Kossut[/b] (1922–1984 profesor doktor habilitowany, syn Wiktora Kossuta i Henryki Serafin, urodził się 16 kwietnia 1922 r. (.. Do dzisiaj znane jest profesjonalistom zdanie E. Terebuchy, że „on pierwszy (Z. Kossut – M.G. przeorał ugór w naszej nauce rachunkowości, wykonując próbę sformułowania nowych poglądów na metody badawcze w dziedzinie teorii rachunkowości.” [b]Kazimierz Sowa[/b] (1915–1972, profesor nadzwyczajny, doktor, urodził się 2 października 1915 roku w Krakowie w rodzinie chłopskiej, zmarł 17 grudnia 1972 r. w Krakowie. Był żonaty, bezdzietny. (... Okres pracy zawodowej Kazimiera Sowy (1938–1972 był bardzo zróżnicowany i przebiegał wielotorowo. Była to praca naukowo-dydaktyczna w szkolnictwie wyższym, praca redakcyjno-popularyzatorska, organizacyjno-kierownicza w Stowarzyszeniu Księgowych w

  6. CuO reduction induced formation of CuO/Cu2O hybrid oxides

    Science.gov (United States)

    Yuan, Lu; Yin, Qiyue; Wang, Yiqian; Zhou, Guangwen

    2013-12-01

    Reduction of CuO nanowires results in the formation of a unique hierarchical hybrid nanostructure, in which the parent oxide phase (CuO) works as the skeleton while the lower oxide (Cu2O) resulting from the reduction reaction forms as partially embedded nanoparticles that decorate the skeleton of the parent oxide. Using in situ transmission electron microscopy observations of the reduction process of CuO nanowires, we demonstrate that the formation of such a hierarchical hybrid oxide structure is induced by topotactic nucleation and growth of Cu2O islands on the parent CuO nanowires.

  7. Farmakogenetyczne uwarunkowania lekooporności w padaczce

    Directory of Open Access Journals (Sweden)

    Alicja Kozera-Kępniak

    2013-06-01

    Full Text Available Padaczka jest jedną z najczęstszych chorób ośrodkowego układu nerwowego, występującą u około 1% populacji na świecie. Charakteryzuje się występowaniem nawracających napadów o różnej symptomatologii. Szacuje się, że u 30% pacjentów mimo prowadzonego właściwego leczenia przeciwpadaczkowego nadal występują napady drgawkowe. Jest to tak zwane zjawisko lekooporności. W Polsce problem ten dotyczy około 100 000–120 000 chorych. Czynnikami predysponującymi do wystąpienia padaczki lekoopornej są: ujawnienie się choroby przed 1. rokiem życia, duża częstotliwość napadów przed rozpoczęciem leczenia oraz zmiany strukturalne mózgu, w tym wady rozwojowe kory mózgowej. Niekontrolowane napady padaczkowe pogarszają jakość życia chorych, zwiększając ryzyko urazów, wpływając negatywnie na samopoczucie fizyczne oraz funkcjonowanie psychospołeczne. Chociaż znane są potencjalne czynniki ryzyka, to nadal nie wiadomo, dlaczego u dwóch pacjentów z tym samym rodzajem padaczki lub tym samym typem napadów skuteczność leczenia lekami przeciwpadaczkowymi może być skrajnie różna. Wśród możliwych przyczyn tego zjawiska wymienia się czynniki genetyczne, zmieniające właściwości farmakodynamiczne i farmakokinetyczne stosowanych leków. Do grupy tych czynników zalicza się: genetycznie uwarunkowany polimorfizm niektórych enzymów mikrosomalnych (CYP2C9, CYP2C19, glikoproteiny P, białka MRP (multidrug resistance-associated protein oraz zaburzenia funkcji farmakodynamicznych receptorów GABA (GABAA i kana- łów jonowych. Wydaje się, że badania nad mechanizmami lekooporności mogą skutkować wprowadzeniem nowych strategii terapeutycznych. Niniejszy artykuł ma na celu przedstawienie wpływu powyżej wymienionych czynników genetycznych na brak skuteczności leczenia w padaczce.

  8. Combustion Stratification for Naphtha from CI Combustion to PPC

    KAUST Repository

    Vallinayagam, R.

    2017-03-28

    This study demonstrates the combustion stratification from conventional compression ignition (CI) combustion to partially premixed combustion (PPC). Experiments are performed in an optical CI engine at a speed of 1200 rpm for diesel and naphtha (RON = 46). The motored pressure at TDC is maintained at 35 bar and fuelMEP is kept constant at 5.1 bar to account for the difference in fuel properties between naphtha and diesel. Single injection strategy is employed and the fuel is injected at a pressure of 800 bar. Photron FASTCAM SA4 that captures in-cylinder combustion at the rate of 10000 frames per second is employed. The captured high speed video is processed to study the combustion homogeneity based on an algorithm reported in previous studies. Starting from late fuel injection timings, combustion stratification is investigated by advancing the fuel injection timings. For late start of injection (SOI), a direct link between SOI and combustion phasing is noticed. At early SOI, combustion phasing depends on both intake air temperature and SOI. In order to match the combustion phasing (CA50) of diesel, the intake air temperature is increased to 90°C for naphtha. The combustion stratification from CI to PPC is also investigated for various level of dilution by displacing oxygen with nitrogen in the intake. The start of combustion (SOC) was delayed with the increase in dilution and to compensate for this, the intake air temperature is increased. The mixture homogeneity is enhanced for higher dilution due to longer ignition delay. The results show that high speed image is initially blue and then turned yellow, indicating soot formation and oxidation. The luminosity of combustion images decreases with early SOI and increased dilution. The images are processed to generate the level of stratification based on the image intensity. The level of stratification is same for diesel and naphtha at various SOI. When O concentration in the intake is decreased to 17.7% and 14

  9. On the nature of the symbiotic binary CI Cygni

    International Nuclear Information System (INIS)

    Kenyon, S.J.; Oliversen, N.A.; Mikolajewska, J.; Mikolajewski, M.; Stencel, R.E.

    1991-01-01

    An analysis of ultraviolet and optical spectroscopy is presented for the symbiotic binary CI Cyg. This system contains an M5 II asymptotic branch giant Mg of about 1.5 solar mass, transfering material at a few times 0.00001 solar mass/yr into a large accretion disk surrounding a main-sequence star with Mh of about 0.5 solar mass. A boundary layer at the inner edge of the disk photoionizes a small nebula approximately confined to the Roche volume of the accreting star. An extended, more highly ionized region forms when material ejected from the disk interacts with the red giant wind. 115 refs

  10. Diversidade sexual e ensino de ciências: buscando sentidos

    Directory of Open Access Journals (Sweden)

    Leandro Jorge Coelho

    2015-12-01

    Full Text Available ResumoO objetivo desse estudo foi analisar os sentidos atribuídos por professores de Ciências e alunos à diversidade sexual. Foram utilizados: questionário, entrevista, produção de textos, análise documental e a técnica de grupo focal para a coleta de dados. De modo geral, os alunos possuem sentidos que reconhecem Lésbicas, Gays, Bissexuais e Transgêneros (LGBT como "estranhos", mesmo assim, acreditam que têm o dever de respeitar as escolhas de cada um. As travestis foram declaradamente apresentadas com repúdio por eles, sendo a homossexualidade e bissexualidade aparentemente mais aceitas. Os professores parecem manter aulas que não abordam estas questões, mesmo o Ensino de Ciências, sendo um momento privilegiado para problematizações sobre diversidade sexual e gênero. É necessário investir em discussões sobre esses temas na formação inicial e continuada de professores, buscando a construção de novos sentidos e práticas que se preocupem com o desvelamento de significados preconceituosos sobre gênero e diversidade sexual.

  11. The radiation shielding potential of CI and CM chondrites

    Science.gov (United States)

    Pohl, Leos; Britt, Daniel T.

    2017-03-01

    Galactic Cosmic Rays (GCRs) and Solar Energetic Particles (SEPs) pose a serious limit on the duration of deep space human missions. A shield composed of a bulk mass of material in which the incident particles deposit their energy is the simplest way to attenuate the radiation. The cost of bringing the sufficient mass from the Earth's surface is prohibitive. The shielding properties of asteroidal material, which is readily available in space, are investigated. Solution of Bethe's equation is implemented for incident protons and the application in composite materials and the significance of various correction terms are discussed; the density correction is implemented. The solution is benchmarked and shows good agreement with the results in literature which implement more correction terms within the energy ranges considered. The shielding properties of CI and CM asteroidal taxonomy groups and major asteroidal minerals are presented in terms of stopping force. The results show that CI and CM chondrites have better stopping properties than Aluminium. Beneficiation is discussed and is shown to have a significant effect on the stopping power.

  12. Lifetime broadening and CI-resonances observed in ESCA

    International Nuclear Information System (INIS)

    Svensson, S.; Maartensson, N.; Basilier, E.; Malmquist, P.Aa.; Gelius, U.; Siegbahn, K.

    1976-03-01

    The electron spectrum of the M 2 and M 3 levels in bromine and krypton have been studied by high resolution ESCA. The M 1 Msub(2,3) super Coster-Kronig transitions become energetically forbidden for Z >approximately 36 (Kr) and recent calculations therefore predict a decrease in the M 2 and M 3 natural linewidths around krypton in the periodic system. The experiment shows that the 3psub(3/2) linewidth is smaller in Kr than in Br. It is, however, also found that this decrease in linewidth is followed by configuration interaction (CI) between 3p 2 P and 3d 2 nl * 2 P states. Several discrete CI resonances are observed in the Kr 3p spectrum. Such resonances are also studied in the N shell for the elements from Te(Z=52) to Ba(Z=56). For these elements the effect is found to be much larger due to the strong collective character of 4d-nf* excitations. (Auth.)

  13. Estudos de Comunidade e ciências sociais no Brasil

    Directory of Open Access Journals (Sweden)

    Nemuel da Silva Oliveira

    2011-12-01

    Full Text Available O objetivo deste artigo é fazer um balanço da literatura sobre os Estudos de Comunidade (EC no Brasil, destacando o contexto intelectual em que foram produzidos e os debates que suscitaram, especialmente entre as décadas de 1940 e 1960. Método de pesquisa em comunidades, oriundo da Antropologia, em investigações sobre o processo de mudança social, os EC estiveram em voga nos Estados Unidos entre os anos 1920 e 1950, tendo papel fundamental na institucionalização das Ciências Sociais no Brasil. Destacamos três aspectos na produção desses estudos no país, iniciando com uma abordagem conceitual: definições, origem e sua relação com temáticas marcantes nos anos 1950. Em seguida, privilegiamos os aspectos relacionados ao papel dos EC na história das Ciências Sociais no Brasil, com destaque para o processo de institucionalização das Ciências Sociais. Por fim, revisitamos os debates que tais estudos geraram entre os cientistas sociais quanto ao padrão de trabalho sociológico a ser desenvolvido naquele momento.The purpose of this article is to examine the literature about Community Studies(CS in Brazil, highlighting their intellectual context of production and the debates evoked by them, especially between the 1940's and 1960's. As a research method arising from Anthropology on communities in social change process, CS was used in United States between 1920's and 1950's, and played a fundamental role in the institutionalization of Social Sciences in Brazil. Three aspects are highlighted on CS production: first, in a conceptual approach, we discuss their definitions, origins and relation to main topics in the 1950's. The second aspect is related to the role of CS in the history of Social Sciences, especially their institutionalization process. By the end, we revisit the debates between social scientists about the sociological work standard to be developed at that time.

  14. Korzyści karmienia piersią dla matki

    Directory of Open Access Journals (Sweden)

    Magdalena Gibas-Dorna

    2012-12-01

    Full Text Available Powszechnie wiadomo, że karmienie piersią pozytywnie wpływa na zdrowie dziecka oraz jego rozwój intelek‑ tualny. światowa Organizacja Zdrowia (World Health Organization, WHO zaleca rozpoczęcie karmienia piersią od pierwszej godziny po porodzie i jego kontynuację przez okres co najmniej 6 miesięcy, a w miarę urozmaicania diety dziecka rekomenduje utrzymanie tego sposobu żywienia mniej więcej do 2. roku życia, traktując mleko matki jako najlepszy jakościowo pokarm uzupełniający. Coraz częściej podkreśla się protek‑ cyjną rolę karmienia naturalnego w rozwoju różnych chorób u matek oraz potencjalne skutki unikania prze‑ dłużonej laktacji. Wydaje się, że korzyści dla matki mają charakter wczesny (podczas połogu oraz długofa‑ lowy. Tuż po porodzie karmienie piersią przyspiesza obkurczanie macicy, zapobiega nadmiernej utracie krwi, chroni przed niedokrwistością z niedoboru żelaza, przeciwdziała wystąpieniu depresji poporodowej, umacnia więź matka – dziecko oraz poprawia zaburzoną w tym okresie jakość snu. Korzyści długofalowe wiążą się z obniżeniem ryzyka wystąpienia niektórych chorób nowotworowych (rak sutka, rak endometrium, rak jajni‑ ka, chorób sercowo‑naczyniowych (choroba niedokrwienna serca, nadciśnienie tętnicze, zaburzeń metabo‑ licznych (cukrzyca, nietolerancja glukozy, otyłość, hiperlipidemia, hiperinsulinemia, reumatoidalnego zapa‑ lenia stawów czy osteoporozy. Przedłużenie okresu laktacji i karmienia piersią ma również wymierną korzyść ekonomiczną i stanowi darmową naturalną antykoncepcję. Poniższa praca podsumowuje aktualny stan wie‑ dzy na temat wpływu karmienia piersią na zdrowie matek karmiących.

  15. Rola aktywności ruchowej w zapobieganiu zaburzeniom poznawczym

    Directory of Open Access Journals (Sweden)

    Andrzej W. Ziemba

    2014-11-01

    Full Text Available Regularna aktywność ruchowa wywołuje szereg zmian adaptacyjnych, zwłaszcza w układzie krążenia i przemianie materii. W licznych pracach na temat pojedynczego wysiłku i wzmożonej aktywności fizycznej pojawia się coraz więcej potwierdzeń ich korzystnego wpływu na kształtowanie funkcji poznawczych. U podstaw mechanizmów związanych z tym wpływem leżą zmiany anatomiczne i funkcjonalne, m.in. zwiększenie przepływu krwi przez mózg, angiogenezy i neurogenezy, objętości istoty szarej w korze czołowej i skroniowej. Wysiłek pobudza wydzielanie czynników troficznych, wśród których dla procesów poznawczych, plastyczności synaptycznej, poprawy szlaków sygnałowych neurogenezy i funkcji naczyniowych kluczowe są czynnik troficzny pochodzenia mózgowego i insulinopodobny czynnik wzrostowy. Aktywność ruchowa wywołuje wzmożoną ekspresję czynnika troficznego pochodzenia mózgowego, co pozytywnie wpływa na procesy energetyczne i aktywuje w mózgu wiele układów energetycznych, które korzystnie modyfikują potencjał synaptyczny przetwarzania informacji ważnych w kształtowaniu funkcji poznawczych. Wysiłek redukuje stan zapalny przez obniżenie we krwi stężenia cytokin prozapalnych, mogących się przyczyniać do rozwoju procesów neurodegeneracyjnych. Redukuje czynniki ryzyka zespołu metabolicznego, a zwłaszcza nadciśnienie i insulinooporność, więc zmniejsza ryzyko wystąpienia zaburzeń czynności poznawczych, poprawia funkcjonowanie mózgu, opóźnia początek i spowalnia rozwój zaburzeń w chorobach neurodegeneracyjnych, a wśród nich w chorobie Alzheimera i chorobie Parkinsona. Za sprawą wymienionych mechanizmów aktywność ruchowa wydaje się niezbędna do zachowania prawidłowych funkcji poznawczych w każdym wieku.

  16. Alguns efeitos do discurso da ciência na atualidade

    Directory of Open Access Journals (Sweden)

    Cristóvão Giovani Burgarelli

    2010-08-01

    Full Text Available Este artigo pretende discutir um dos desdobramentos da ciência em especial: a tecnociência, considerada aqui como marca da contemporaneidade que dita o imperativo da técnica e de seu aparato como aquilo que, supostamente, a tudo responde, preenche e satisfaz. O meio acadêmico, inserido no contexto cultural atravessado pela lógica tecnocientífica, não está livre de seus efeitos e da dinâmica consumista que tende a considerar o saber como um bem de consumo. Ao contrário, tanto as escolas quanto as universidades aderem a essa lógica e expulsam de seu arcabouço a possibilidade de subjetivação, ou seja, o modo singular de um sujeito se haver, diferentemente, com as marcas que o constituem.

  17. Ciência da Computação

    Directory of Open Access Journals (Sweden)

    André Felipe Henriques Librantz

    2006-01-01

    Full Text Available Este trabalho apresenta um sistema de navegação autônoma de robôs construídos com kits Lego Mindstorms, para cálculo de trajetórias. Esse sistema pode ser utilizado como instrumento pedagógico multidisciplinar no curso de Ciência da Computação, uma vez que, para o seu desenvolvimento são necessários conhecimentos de algoritmos, linguagem de programação, lógica computacional, estrutura de dados, inteligência artificial (IA, redes de computadores, computação gráfica e robótica.

  18. PENGUASAAN KERAJAAN TARUMANEGARA TERHADAP KAWASAN HULU CI SADANE THE CONTROL OF TARUMANEGARA KINGDOM TO THE CI SADANE UPSTREAM AREA

    Directory of Open Access Journals (Sweden)

    Endang Widyastuti

    2016-06-01

    Full Text Available ABSTRACT As we know that the oldest kingdom in West Java is the Kingdom Tarumanegara. Authentic evidence of the existence of such is the kingdom of seven inscriptions, of which five were found in the upstream region is now administratively Cisadane including Bogor regency. Three of the five inscriptions indicate the possession of territory by Tarumanegara kingdom. This indicates that the upstream region Cisadane is an area that is quite important and has the potential to be controlled by Tarumanegara.   Key words:upstream of Ci Sadane, Tarumanegara kingdom, control area   ABSTRAK Sebagaimana diketahui bahwa kerajaan tertua di Jawa Barat adalah Kerajaan Tarumanegara. Bukti otentik mengenai keberadaan kerajaan tersebut adalah adanya tujuh prasasti, yang lima diantaranya ditemukan di kawasan Hulu Cisadane yang sekarang secara administratif termasuk wilayah Kabupaten Bogor. Tiga diantara kelima prasasti tersebut menunjukkan penguasaan wilayah tersebut oleh Kerajaan Tarumanegara. Hal ini mengindikasikan bahwa kawasan hulu cisadane merupakan kawasan yang cukup penting dan mempunyai potensi yang harus dikuasai oleh Tarumanegara.   Kata Kunci:hulu Ci Sadane, Kerajaan Tarumanegara, penguasaan wilayah.

  19. Convergências entre a Ciência da Informação e as Ciências Cognitivas

    Directory of Open Access Journals (Sweden)

    Aida Varela Varela

    2016-06-01

    Full Text Available Apresentam-se as convergências entre a Ciência da Informação e as Ciências Cognitivas, buscando argumentos, fundamentos para fomentar e produzir o saber e o fazer, potencializando estudos e aproximações. Para tal, reflete-se sobre conhecimentos e necessidades, os principais representantes das correntes cognitivas, como substrato aos processos de recuperação, compreensão, reflexão e criticidade essenciais à construção do conhecimento científico, com destaque para o domínio dos vários níveis de leitura para buscar e usar a informação. Utiliza-se como metodologia revisão bibliográfica, com estabelecimento de diálogos com autores clássicos e contemporâneos das áreas em questão. Conclui-se que é preciso se destacar o caráter paradigmático, bem como outras dimensões das construções conceituais e práticas das duas áreas em foco, principalmente os concentrar as pesquisas nos estudos cognitivos para subsidiar a busca da informação com autonomia e garantia de desenvolvimento pessoal, com maior contribuição num contexto de constantes mudanças.

  20. Fazer ciência: o lugar do conceito

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    Wilton Garcia

    2007-06-01

    Full Text Available Este texto visa abrir uma discussão acerca da pesquisa contemporânea, investindo o enfoque no discurso científico para uma abordagem dinâmica de estratégias discursivas. Tento realizar uma reflexão crítica sobre a produção do saber em alguns procedimentos conceituais. Neste caso, remeto o olhar a uma consideração teórico-metodológica que pretende contribuir à atualização do discurso da ciência, hoje, e permita propor maior flexibilidade e deslocamento diante das diferentes produções de conhecimento. Este trabalho, portanto, não pretende expor, diretamente, idéias sobre ciência, mas sobre o discurso dito científico. Nesta investigação crítica, apresento sucintamente a noção de pós-(desconstrução. Utilizo os estudos contemporâneos como eixo teórico-metodológico para este desenvolvimento argumentativo. Os estudos contemporâneos pesquisam as atualizações de conceitos, que se organizam mediante a produção de atualidades e vasculham uma (redimensão teórica e política, associada ao sistema flexível da linguagem. Essas atualizações esboçam a área dos estudos contemporâneos em sua intensidade descritiva, quando aciona um olhar investigativo sobre as inovações no discurso científico, hoje.

  1. Production of no-carrier-added 64Cu from zinc metal irradiated under boron shielding.

    Science.gov (United States)

    Zinn, K R; Chaudhuri, T R; Cheng, T P; Morris, J S; Meyer, W A

    1994-02-01

    Positron emission tomography offers advantages for radioimmunodiagnosis of cancer but requires radionuclides of appropriate half-life that have high specific activity and high radio-purity. This work was designed to develop a viable method to produce and purify 64Cu, which has high specific activity, for positron emission tomography. 64Cu was produced at the University of Missouri Research Reactor by the nuclear reaction, 64Zn(n,p)64Cu. Highly pure zinc metal (99.9999%) was irradiated in a specially designed boron nitrite lined container, which minimized thermal neutron reactions during irradiation. A new two-step procedure was developed to chemically separate the no-carrier-added 64Cu from the zinc metal target. 64Cu recovery for 24 runs averaged 0.393 (+/- 0.007) mCi per milligram of zinc irradiated. The boron-lined irradiation container reduced unwanted zinc radionuclides 14.3-fold. Zinc radionuclides and non-radioactive zinc were separated successfully from the 64Cu. The new separation technique was fast (2 hours total time) and highly efficient for removing the zinc. The zinc separation factor for this technique averaged 8.5 x 10(-8), indicating less than 0.0000085% of the zinc remained after separation. Thus far, the highest 64Cu specific activity at end of irradiation was 683 Ci/mg Cu, with an average of 512 Ci/mg Cu for the last six analyzed runs. The boron-lined irradiation container has sufficient capacity for 75-fold larger-sized zinc targets (up to 45 g). The new separation technique was excellent for separating 64Cu, which appears to be a radionuclide with great potential for positron emission tomography.

  2. Trophic analysis of the fish community in the Ciénega Churince, Cuatro Ciénegas, Coahuila

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    Ariana Hernández

    2017-09-01

    Full Text Available Fish diets were analyzed to evaluate the dynamic trophs of the fish community in the Churince wetland system of the Cuatro Ciénegas, where the fauna consists of nine species: endemic, native and introduced. In nine sampling events (between February 2011 and May 2014 556 specimens of all nine species were collected. Stomach contents were analyzed and the Relative Importance Index (IRI was calculated. The feed coefficient (Q of the diets and the accumulated trophic diversity (Hk, as well as the amplitude of the trophic niche were evaluated. Feeding strategies in the fish community were found to be eurifagic. The main foods in general were insects, crustaceans, gastropods, plants and teleosts. According to the average linkage method, four functional trophic groups were defined, with no higher consumption species; nevertheless all were regulators, mainly invertebrates. Therefore, the chain reaction in food control was higher from top to bottom, meaning a downwards dietary control.

  3. Culturas das Ciências Naturais Cultures of Natural Sciences

    Directory of Open Access Journals (Sweden)

    Maria Margaret Lopes

    2005-12-01

    Full Text Available Este artigo apresenta subsídios para o ensino de História das Ciências, considerando particularmente o campo da História da História Natural e das Ciências Naturais. Sem ser uma revisão completa da historiografia desses campos de conhecimento sobre o mundo natural, retoma alguns traços gerais desses longos processos de definição de campos disciplinares que se configuram desde a Renascença até o final do século XVIII. Considera diversas tradições culturais e historiográficas que contribuíram para os nossos entendimentos atuais, de como a História Natural do Renascimento foi abandonando seus antigos quadros conceituais, assumindo novas práticas e se constituindo nas tradições da História Natural do século XVIII. Comenta esses processos, em que tanto a Botânica, a Zoologia, a Mineralogia se individualizam como áreas de conhecimentos apoiadas em práticas locais e coleções globais, indo além de sua subordinação à utilidade médica; bem como suas organizações em áreas de conhecimento, por começarem a se colocar questões relativas à origem e à historicidade dos seres e processos naturais, dados os avanços das temáticas classificatórias e das discussões envolvendo temporalidades.This paper provides insights into the teaching of the History of Science, especially the field of the History of Natural History and Natural Sciences. Although not claiming to be a complete historiographic review of these areas of knowledge about the natural world, it outlines the general traits of the long process of definition of disciplines that were shaped from the Renaissance to the end of the XVIII century. It encompasses various cultural and historiographic traditions that contributed to our present understanding of how Renaissance Natural History abandoned its ancient conceptual frameworks and assumed new practices and shaped itself in the tradition of XVIII century Natural History. The paper comments on these processes by which

  4. Ética, ciência e tecnologia

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    Ivan Domingues

    2004-06-01

    Full Text Available O artigo visa pensar a relação entre ética, ciência e tecnologia, enfatizando o problema de sua revinculação depois da cisão entre os juízos de fato e os juízos de valor, ocorrida no início dos tempos modernos. Uma vez examinada a ética da aristocracia guerreira e a moral do santo, procura-se delinear o caminho tomando como referência a ética da responsabilidade, cujo protótipo é a moral do sábio, desaparecido no curso dos tempos modernos, em razão da fragmentação do saber e do advento do especialista. Ao fim do estudo, é discutida a relação entre a ética e a metafísica, com o intuito de ajustar a questão antropológica à perspectiva cosmológica, bem como de fornecer as bases de um novo humanismo, objetivando a humanização da técnica e a geração de um novo homem, alfabetizado em ciência, tecnologia e humanidades.The article aims at thinking the relation among ethics, science and technology, emphasizing the problem of their re-tying, after the division into judgments of fact and judgments of value, wich happened in the begininning of modern times. Since the warlike aristocracy's ethics and the saint man's moral are examined, it tries to outline its way, taking as a reference the ethics of responsability, whose prototype is the wise man's moral, which disappeared in the course of modern times, due to the fragmentation of knowing and the advent of the specialist. At the end of the study, the relationship between ethics and metaphysics is discussed, aiming at adjusting the anthropological question to the cosmological perspective, as well as at providing the bases of a new humanism, objectifying the humanization of the technique and the generation of a new man, literate at science, technology and the humanities.

  5. A Biblioteconomia e a Ciência da Informação na taxionomia das ciências de Charles Sanders Peirce

    Directory of Open Access Journals (Sweden)

    Carlos Cândido de Almeida

    2005-07-01

    Full Text Available Mostra a taxionomia das ciências desenvolvida por Charles Sanders Peirce (1839-1914 que divide as ciências em três ramos: ciências teóricas, ciências da revisão e ciências aplicadas. Detalha principalmente as ciências teóricas: a Matemática, a Filosofia e a Idioscopia. Discute também o conceito de Biblioteconomia e de Ciência da Informação e que segundo as definições e características, encontradas na literatura consultada, estão na condição de ciências aplicadas, direcionadas a problemas práticos da sociedade, ou seja, o problema de controle e disseminação da informação.

  6. Hydrodynamic evolution and jet energy loss in Cu + Cu collisions

    International Nuclear Information System (INIS)

    Schenke, Bjoern; Jeon, Sangyong; Gale, Charles

    2011-01-01

    We present results from a hybrid description of Cu + Cu collisions using (3 + 1)-dimensional hydrodynamics (music) for the bulk evolution and a Monte Carlo simulation (martini) for the evolution of high-momentum partons in the hydrodynamical background. We explore the limits of this description by going to small system sizes and determine the dependence on different fractions of wounded nucleon and binary collisions scaling of the initial energy density. We find that Cu + Cu collisions are well described by the hybrid description at least up to 20% central collisions.

  7. Magnetic Moment of $^{59}$Cu

    CERN Multimedia

    2002-01-01

    Experiment IS358 uses the intense and pure beams of copper isotopes provided by the ISOLDE RILIS (resonance ionization laser ion source). The isotopes are implanted and oriented in the low temperature nuclear orientation set-up NICOLE. Magnetic moments are measured by $\\beta$-NMR. Copper (Z=29), with a single proton above the proton-magic nickel isotopes provides an ideal testground for precise shell model calculations of magnetic moments and their experimental verification. In the course of our experiments we already determined the magnetic moments of $^{67}$Ni, $^{67}$Cu, $^{68g}$Cu, $^{69}$Cu and $^{71}$Cu which provide important information on the magicity of the N=40 subshell closure. In 2001 we plan to conclude our systematic investigations by measuring the magnetic moment of the neutron-deficient isotope $^{59}$Cu. This will pave the way for a subsequent study of the magnetic moment of $^{57}$Cu with a complementary method.

  8. Anti-tumour action of 64Cu-bleomycin on Ehrlich ascites tumour cells in vivo

    International Nuclear Information System (INIS)

    Maki, Hirotoshi; Kawai, Kenichi; Akaboshi, Mitsuhiko

    1979-01-01

    The anti-tumor action of the complex of Bleomycin (BLM) with high specific-radioactivity 64 Cu on Ehrlich ascites tumour (EAT) was studied in vivo. The 64 Cu-BLM was administered into intraperitoneal cavity of mice from 1 to 4 days after inoculation of EAT cells. The effect of 64 Cu-BLM to suppress the tumour growth as demonstrated by prolonging life span was observed. The amounts of 64 Cu-BLM (800 μCi-8 mg/Kg) were administered at 4, 8 and 16 times separately. Then, the shorter the time interval and the less the amounts of drugs at a time, the higher the suppressing effect for the tumour growth was. It was confirmed that anti-tumour action of 64 Cu-BLM was in all the cases higher than that of BLM alone. (author)

  9. Stability of Cu-Precipitates in Al-Cu Alloys

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    Torsten E. M. Staab

    2018-06-01

    Full Text Available We present first principle calculations on formation and binding energies for Cu and Zn as solute atoms forming small clusters up to nine atoms in Al-Cu and Al-Zn alloys. We employ a density-functional approach implemented using projector-augmented waves and plane wave expansions. We find that some structures, in which Cu atoms are closely packed on {100}-planes, turn out to be extraordinary stable. We compare the results with existing numerical or experimental data when possible. We find that Cu atoms precipitating in the form of two-dimensional platelets on {100}-planes in the fcc aluminum are more stable than three-dimensional structures consisting of the same number of Cu-atoms. The preference turns out to be opposite for Zn in Al. Both observations are in agreement with experimental observations.

  10. Beta decay of Cu-56

    NARCIS (Netherlands)

    Borcea, R; Aysto, J; Caurier, E; Dendooven, P; Doring, J; Gierlik, M; Gorska, M; Grawe, H; Hellstrom, M; Janas, Z; Jokinen, A; Karny, M; Kirchner, R; La Commara, M; Langanke, K; Martinez-Pinedo, G; Mayet, P; Nieminen, A; Nowacki, F; Penttila, H; Plochocki, A; Rejmund, M; Roeckl, E; Schlegel, C; Schmidt, K; Schwengner, R; Sawicka, M

    2001-01-01

    The proton-rich isotope Cu-56 was produced at the GSI On-Line Mass Separator by means of the Si-28(S-32, p3n) fusion-evaporation reaction. Its beta -decay properties were studied by detecting beta -delayed gamma rays and protons. A half-Life of 93 +/- 3 ms was determined for Cu-56. Compared to the

  11. Deuterium transport in Cu, CuCrZr, and Cu/Be

    Science.gov (United States)

    Anderl, R. A.; Hankins, M. R.; Longhurst, G. R.; Pawelko, R. J.

    This paper presents the results of deuterium implantation/permeation experiments and TMAP4 simulations for a CuCrZr alloy, for OFHC-Cu and for a Cu/Be bi-layered structure at temperatures from 700 to 800 K. Experiments used a mass-analyzed, 3-keV D 3+ ion beam with particle flux densities of 5 × 10 19 to 7 × 10 19 D/m 2 s. Effective diffusivities and surface molecular recombination coefficients were derived giving Arrhenius pre-exponentials and activation energies for each material: CuCrZr alloy, (2.0 × 10 -2 m 2/s, 1.2 eV) for diffusivity and (2.9 × x10 -14 m 4/s, 1.92 eV) for surface molecular recombination coefficients; OFHC Cu, (2.1 × 10 -6 m 2/s, 0.52 eV) for diffusivity and (9.1 × 10 -18 m 4/s, 0.99 eV) for surface molecular recombination coefficients. TMAP4 simulation of permeation data measured for a Cu/Be bi-layer sample was achieved using a four-layer structure (Cu/BeO interface/Be/BeO back surface) and recommended values for diffusivity and solubility in Be, BeO and Cu.

  12. Cu-Cr Literature Review

    Energy Technology Data Exchange (ETDEWEB)

    Need, Ryan F. [Los Alamos National Laboratory

    2012-08-09

    Cu-Cr alloys are part of a class of face-centered cubic (FCC)-body-centered cubic (BCC) composites that includes similar alloys, such as Cu-Nb and Cu-Ta. When heavily deformed, these FCC-BCC materials create 'in situ' composites with a characteristic structure-nanoscale BCC filaments in a ductile FCC matrix. The strength of these composites is vastly greater than predicted by the rule of mixtures, and has been shown to be inversely proportional to the filament spacing. Lower raw materials costs suggest that Cu-Cr alloys may offer more economical solution to high-strength, high-conductivity wire than either their Nb or Ta counterparts. However, Cr is also more brittle and soluble in Cu than Nb or Ta. These qualities necessitate thermal treatments to remove solute atoms from the Cu matrix, improve conductivity, and maintain the ductility of the Cr filaments. Through the use of different thermomechanical processing routes or the addition of select dopants, alloys with strength in excess of 1 GPa at 70% IACS have been achieved. To date, previous research on Cu-Cr alloys has focused on a relatively small number of alloy compositions and processing methods while the effects of dopants and ageing treatments have only been studied independently. Consequently, there remains considerable opportunity for the development and optimization of these alloys as a leading high-strength, high-conductivity material.

  13. Cu-ZSM-5, Cu-ZSM-11, and Cu-ZSM-12 Catalysts for Direct NO Decomposition

    DEFF Research Database (Denmark)

    Kustova, Marina; Kustov, Arkadii; Christiansen, Sofie E.

    2006-01-01

    Cu-ZSM-5 has for many years been recognized as a unique catalyst for direct NO decomposition. Here, it is discovered that both Cu-ZSM-11 and Cu-ZSM-12 are about twice as active as Cu-ZSM-5. This difference is attributed to the active sites located almost exclusively in the straight zeolite pores...

  14. Physical mechanisms of Cu-Cu wafer bonding

    International Nuclear Information System (INIS)

    Rebhan, B.

    2014-01-01

    Modern manufacturing processes of complex integrated semiconductor devices are based on wafer-level manufacturing of components which are subsequently interconnected. When compared with classical monolithic bi-dimensional integrated circuits (2D ICs), the new approach of three-dimensional integrated circuits (3D ICs) exhibits significant benefits in terms of signal propagation delay and power consumption due to the reduced metal interconnection length and allows high integration levels with reduced form factor. Metal thermo-compression bonding is a process suitable for 3D interconnects applications at wafer level, which facilitates the electrical and mechanical connection of two wafers even processed in different technologies, such as complementary metal oxide semiconductor (CMOS) and microelectromechanical systems (MEMS). Due to its high electrical conductivity, copper is a very attractive material for electrical interconnects. For Cu-Cu wafer bonding the process requires typically bonding for around 1 h at 400°C and high contact pressure applied during bonding. Temperature reduction below such values is required in order to solve issues regarding (i) throughput in the wafer bonder, (ii) wafer-to-wafer misalignment after bonding and (iii) to minimise thermo-mechanical stresses or device degradation. The aim of this work was to study the physical mechanisms of Cu-Cu bonding and based on this study to further optimise the bonding process for low temperatures. The critical sample parameters (roughness, oxide, crystallinity) were identified using selected analytical techniques and correlated with the characteristics of the bonded Cu-Cu interfaces. Based on the results of this study the impact of several materials and process specifications on the bonding result were theoretically defined and experimentally proven. These fundamental findings subsequently facilitated low temperature (LT) metal thermo-compression Cu-Cu wafer bonding and even room temperature direct

  15. As ciências naturais e as ciências do espírito na era da globalização

    Directory of Open Access Journals (Sweden)

    Jaeschke, Walter

    2006-01-01

    Full Text Available Este artigo, o autor apresenta, primeiramente, reflexões de cunho histórico sobre a relação entre as Ciências Naturais e as Ciências do Espírito, seguidas de observações, de caráter mais sistemático, sobre o conceito das próprias Ciências do Espírito. Com fundamento nessas observações, tece algumas reflexões sobre até que ponto podemos esperar da globalização efeitos sobre as Ciências Naturais e as Ciências do Espírito

  16. Renal Cu and Na excretion and hepatic Cu metabolism in both Cu acclimated and non acclimated rainbow trout (Oncorhynchus mykiss)

    DEFF Research Database (Denmark)

    Grosell, M.; Hogstrand, C.; Wood, C.M.

    1998-01-01

    protein depending on whether the Cu is derived from recent branchial uptake or is already present in the plasma prior to Cu-64 exposure. The plasma Cu pool derived from recent branchial uptake and the Cu pool present in the plasma prior to Cu-64 exposure is accessible to renal excretion to different...... Na+ efflux decreased by 40%, which was largely due to increased tubular Na+ reabsorption. Renal compensation for the impaired branchial Na+ uptake, seen during Cu exposure, thus seems to be involved in Cu acclimation in rainbow trout. (C) 1998 Elsevier Science B.V....

  17. Cu-62, Cu-64 and Cu-66 production with 4.2 MeV deuterons

    International Nuclear Information System (INIS)

    Avila, Mario; Morales, J.R.; Riquelme, H.O.

    1996-01-01

    Full text: The natural copper irradiation with deuterons produces the Cu-62, Cu-64 and Cu-66 radionuclides. Of two radioisotopes, those with deficiencies in neutrons, are applied in nuclear medicine diagnostic processes, mainly for the nuclear characteristic of the decay modes. The positron emitters, of short life mean Cu-62 (9.1 min, β + ) and Cu(12.7 h), are radionuclides applied in radio pharmacological preparation for brain, core, blood flux studies. The radiochemical process consists in the de solution of the irradiated metallic copper target, in acid medium. The result solution, can be neutralized with a base or a buffer at wished pH. Using a deuteron beam of 4,2 ± 0,1 MeV energy has been obtained total yields of 1,103 ± 0,011 μCl/μAh medium for 62 Cu and of 0,148 ± 0,015 μCl/μAh for 64 Cu

  18. Tailoring Graphene Morphology and Orientation on Cu(100), Cu(110), and Cu(111)

    Science.gov (United States)

    Jacobberger, Robert; Arnold, Michael

    2013-03-01

    Graphene CVD on Cu is phenomenologically complex, yielding diverse crystal morphologies, such as lobes, dendrites, stars, and hexagons, of various orientations. We present a comprehensive study of the evolution of these morphologies as a function of Cu surface orientation, pressure, H2:CH4, and nucleation density. Growth was studied on ultra-smooth, epitaxial Cu films inside Cu enclosures to minimize factors that normally complicate growth. With low H2:CH4, Mullins-Sekerka instabilities propagate to form dendrites, indicating transport limited growth. In LPCVD, the dendrites extend hundreds of microns in the 100, 111, and 110 directions on Cu(100), (110), and (111) and are perturbed by twin boundaries. In APCVD, multiple preferred dendrite orientations exist. With increasing H2:CH4, the dendritic nature of growth is suppressed. In LPCVD, square, rectangle, and hexagon crystals form on Cu(100), (110) and (111), reflecting the Cu crystallography. In APCVD, the morphology becomes hexagonal on each surface. If given ample time, every growth regime yields high-quality monolayers with D:G Raman ratio rationally tailor the graphene crystal morphology and orientation.

  19. Morphology and chemical composition of Cu/Sn/Cu and Cu(5 at-%Ni)/Sn/Cu(5 at-%Ni) interconnections

    NARCIS (Netherlands)

    Wierzbicka-Miernik, A.; Wojewoda-Budka, J.; Litynska-Dobrzynska, L.; Kodentsov, A.; Zieba, P.

    2012-01-01

    In the present paper, scanning and transmission electron microscopies as well as energy dispersive X-ray spectroscopy investigations were performed to describe the morphology and chemical composition of the intermetallic phases growing in Cu/Sn/Cu and Cu(Ni)/Sn/Cu(Ni) interconnections during the

  20. Compound cuing in free recall.

    Science.gov (United States)

    Lohnas, Lynn J; Kahana, Michael J

    2014-01-01

    According to the retrieved context theory of episodic memory, the cue for recall of an item is a weighted sum of recently activated cognitive states, including previously recalled and studied items as well as their associations. We show that this theory predicts there should be compound cuing in free recall. Specifically, the temporal contiguity effect should be greater when the 2 most recently recalled items were studied in contiguous list positions. A meta-analysis of published free recall experiments demonstrates evidence for compound cuing in both conditional response probabilities and interresponse times. To help rule out a rehearsal-based account of these compound cuing effects, we conducted an experiment with immediate, delayed, and continual-distractor free recall conditions. Consistent with retrieved context theory but not with a rehearsal-based account, compound cuing was present in all conditions, and was not significantly influenced by the presence of interitem distractors.

  1. Cu/Cu{sub 2}O/CuO nanoparticles: Novel synthesis by exploding wire technique and extensive characterization

    Energy Technology Data Exchange (ETDEWEB)

    Sahai, Anshuman [Department of Physics and Materials Science and Engineering, Jaypee Institute of Information Technology, A-10, Sector-62, Noida 201307 (India); Goswami, Navendu, E-mail: navendugoswami@gmail.com [Department of Physics and Materials Science and Engineering, Jaypee Institute of Information Technology, A-10, Sector-62, Noida 201307 (India); Kaushik, S.D. [UGC-DAE-Consortium for Scientific Research Mumbai Centre, R5 Shed, BARC, Mumbai 400085 (India); Tripathi, Shilpa [UGC-DAE Consortium for Scientific Research, Indore, M.P. (India)

    2016-12-30

    Highlights: The salient features of this research article are following: • Mixed phase synthesis of Cu/Cu{sub 2}O/CuO nanoparticles prepared by Exploding Wire Technique (EWT). • Predominant Cu/Cu{sub 2}O phases along with minor CuO phase revealed through XRD, TEM, Raman, FTIR, UV–Visible and PL analyses. • XPS analysis provided direct evidences of Cu{sup 2+} and Cu{sup +} along with O deficiency for prepared nanoparticles. • Room temperature weak ferromagnetic behaviour was demonstrated for Cu/Cu{sub 2}O/CuO nanoparticles. - Abstract: In this article, we explore potential of Exploding Wire Technique (EWT) to synthesize the copper nanoparticles using the copper metal in a plate and wire geometry. Rietveld refinement of X-ray diffraction (XRD) pattern of prepared material indicates presence of mixed phases of copper (Cu) and copper oxide (Cu{sub 2}O). Agglomerates of copper and copper oxide comprised of ∼20 nm average size nanoparticles observed through high resolution transmission electron microscope (HRTEM) and energy dispersive x-ray (EDX) spectroscopy. Micro-Raman (μR) and Fourier transform infrared (FTIR) spectroscopies of prepared nanoparticles reveal existence of additional minority CuO phase, not determined earlier through XRD and TEM analysis. μR investigations vividly reveal cubic Cu{sub 2}O and monoclinic CuO phases based on the difference of space group symmetries. In good agreement with μRaman analysis, FTIR stretching modes corresponding to Cu{sub 2}-O and Cu-O were also distinguished. Investigations of μR and FTIR vibrational modes are in accordance and affirm concurrence of CuO phases besides predominant Cu and Cu{sub 2}O phase. Quantum confinement effects along with increase of band gaps for direct and indirect optical transitions of Cu/Cu{sub 2}O/CuO nanoparticles are reflected through UV–vis (UV–vis) spectroscopy. Photoluminescence (PL) spectroscopy spots the electronic levels of each phase and optical transitions processes

  2. Oops, My Tests Broke the Build : An Explorative Analysis of Travis CI with GitHub

    NARCIS (Netherlands)

    Beller, M.M.; Gousios, Giorgos; Zaidman, A.E.

    2017-01-01

    AbContinuous Integration (CI) has become a best practice of modern software development. Yet, at present, we have a shortfall of insight into the testing practices that are common in CI-based software development. In particular, we
    seek quantifiable evidence on how central testing is to the CI

  3. La contaminación por metales pesados en la Ciénaga Grande de Santa Marta, Caribe colombiano La contaminación por metales pesados en la Ciénaga Grande de Santa Marta, Caribe colombiano

    Directory of Open Access Journals (Sweden)

    Campos C. Néstor Hernando

    1990-09-01

    Full Text Available Se dan los resultados de los estudios sobre la contaminación por metales pesados en la Ciénaga Grande de Santa Marta. Las determinaciones se realizaron en el material en suspensión, en los bivalvos Crassostrea rhizophorae e Isognomon alatus y en los peces Gathorops spixii y Ariopsis bonillai. Los análisis de los metales Cd, Zn y Cu en el material en suspensión permitieron determinar que las mayores descargas de estos metales se suceden principalmente desde el Río Magdalena a través del Canal del Clarín y de los ríos que fluyen del piedemonte de la Sierra Nevada de Santa Marta. La comparación de los contenidos en bivalvas permiten determinar la importancia de estos organismos como bioindicadores. Los análisis en las dos especies de peces mostraron una diferenciación en la capacidad de acumulación entre una y otra.  Al comparar los contenidos de metales entre los diferentes tipos de muestras con los cambios en los contenidos en el material en suspensión y la salinidad, se observó que estos dos parámetros son principalmente los que controlan la biodisponibilidad de los metales y además afectan los procesos fisiológicos de los organismos, aumentando o disminuyendo la capacidad de bioacumulación. Results of the studies of heavy metals pollution in the Ciénaga Grande de Santa Marta are provided. The determinations have been done on the suspended matter, on the bivalves Crassostrea rhizophorae and Isognomon alatus, and in the fishes Gathorops spixii and Ariopsis bonillai. The analysis of Cd, Zn and Cu in the suspended matter led to determine that the discharges come principally from the Río Magdalena through the Canal del Clarín and the rivers coming from the Sierra Nevada de Santa Marta. Comparisons of the concentration in bivalves show the importance of this organisms as bioindicators. The analysis in both fish species show a difference in their capacity of accumulation. Comparison of the metals contents between different types

  4. CI in the work place: does involving the HRM function make any difference?

    DEFF Research Database (Denmark)

    Hyland, Paul; Becker, Karen; Sload, Terry

    2008-01-01

    benefit the organisation's performance. The HRM function is often given the task of championing cultural change and managing aspects of training and learning, and it would appear that involvement of HRM professionals would enhance CI efforts and assist in the timely solution of issues within the CI......People are central to successful Continuous Improvement (CI), and in larger organisations a Human Resource Management (HRM) function is responsible for people related issues. Central to CI is learning and a culture that supports CI. Learning needs to be both individual and organisational, and must...

  5. Thermochemical properties of oxides in Y-Ba-Cu-O, Sr-Bi-O, Cu-Nb-O, Sr-Cu-O, Ca-Cu-O, Cu-O and Hg-Ba-Ca-Cu-O systems

    International Nuclear Information System (INIS)

    Moiseev, G.K.; Vatolin, N.A.; Il'inykh, N.I.

    2000-01-01

    Thermochemical properties (ΔH 0 298 , S 0 298 , H 0 298 -H 0 0 , C p (T), C p at T>T melt ) of complex oxides in Y-Ba-Cu-O, Sr-Bi-O, Cu-Nb-O, Sr-Cu-O, Ca-Cu-O, Cu-O and Hg-Ba-Ca-Cu-O systems obtained with application of calculation methods are presented. Nonexperimental methods of estimation, revision and correction of standard formation enthalpies of inorganic compounds are described [ru

  6. Comparative study of Cu-Zr and Cu-Ru alloy films for barrier-free Cu metallization

    International Nuclear Information System (INIS)

    Wang Ying; Cao Fei; Zhang Milin; Liu Yuntao

    2011-01-01

    The properties of Cu-Zr and Cu-Ru alloy films were comparatively studied to evaluate their potential use as alloying elements. Cu alloy films were deposited on SiO 2 /Si substrates by magnetron sputtering. Samples were subsequently annealed and analyzed by four-point probe measurement, X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy and Auger electron spectroscopy. X-ray diffraction data suggest that Cu film has preferential (111) crystal orientation and no extra peak corresponding to any compound of Cu, Zr, Ru, and Si. According to transmission electron microscopy results, Cu grains grow in size for both systems but the grain sizes of the Cu alloy films are smaller than that of pure Cu films. These results indicate that Cu-Zr film is suitable for advanced barrier-free metallization in terms of interfacial stability and lower resistivity.

  7. As tendências atuais dos paradigmas: ciência, tecnologia e sociedade e ensino de ciências indígena no VII ENPEC

    Directory of Open Access Journals (Sweden)

    Maria Delourdes Maciel

    2014-01-01

    Full Text Available O Encontro Nacional de Pesquisas em Educação em Ciências é um evento bianual organizada pelos pesquisadores do ensino de Ciências. O objetivo principal desse encontro é reunir os professores e pesquisadores da área, para socializarem os relatos de experiência e pesquisas no ensino de Ciências. Nesse presente trabalho, foi realizado um mapeamento dos artigos apresentados nas seções de comunicação oral do VII ENPEC, somando um total de 425 artigos selecionados, procurou-se identificar os relacionados com a abordagem Ciências, Tecnologia e Sociedade (CTS no ensino de Ciências sua estrutura de organização e o numero de pesquisadores dessa área do Ensino de Ciências. Para esse estudo foi realizado uma pesquisa qualitativa de caráter bibliográfico, e para a análise dos dados buscou-se subsídios teóricos em Fiorentini (2002 e Bardin (2006 porque assim seria possível comparar minuciosamente os diferentes resultados obtidos. Conclui-se que a linha de pesquisa com a temática CTS apresentou 28 trabalhos cerca de 7% de trabalhos apresentados, confirmando uma sinalização nessa área de pesquisa pelos pesquisadores do ensino de Ciências e a temática sobre ensino de ciências indígena representou cerca de 1% dos trabalhos apresentados.

  8. Spin dynamics in CuO and Cu[sub 1[minus][ital x

    Energy Technology Data Exchange (ETDEWEB)

    Carretta, P.; Corti, M.; Rigamonti, A. (Department of Physics Alessandro Volta,' ' University of Pavia, Via Bassi 6, 27100 Pavia (Italy))

    1993-08-01

    [sup 63]Cu nuclear quadrupole resonance (NQR), nuclear antiferromagnetic resonance (AFNMR), and spin-lattice relaxation, as well as [sup 7]Li NMR and relaxation measurements in CuO and in Cu[sub 1[minus][ital x

  9. Cu and Zn Isotopes as New Tracers of Early Solar Nebula and Asteroidal processes

    Science.gov (United States)

    LUCK, J.; BEN OTHMAN, D.; ALBAREDE, F.

    2001-12-01

    Cu and Zn isotopic variations are now identified in extra-terrestrial samples, as has been the case for terrestrial samples (1). The main parameters which may cause these variations are : redox state, temperature, biological activity (Earth), and volatility (extra-terrestrial samples). We report data for meteorites from various groups and classes, including carbonaceous chondrites, ordinary and diffentiated chondrites (iron meteorites, SNC and HED). All analyses have been duplicated (from powder aliquot to final measurement). Values are expressed as relative deviations from NIST and JMC standards for 65Cu/63Cu and 66Zn64Zn, respectively (deltas in permil). Carefull chemistry and MC-ICP-MS measurements allow an overall precision of +/-0.04 permil. I- Carbonaceous Chondrites A very important feature is that each group seems to exhibit a specific isotopic signature : Cu gets isotopically lighter from CI to CM to CO to CV, spanning an overall range of 1.5 permil. Zn shows a reverse order, getting heavier from CI to CM to CO. Zn in CV chondrites (whole rock) seems more variable. This order is the same as that observed for trace elements. Cu and Zn isotopic compositions are generally correlated to trace element content from one group to another, particularly those of similar volatility (e.g. Mn for Cu; Ge for Zn). Cu and Zn isotopic signatures exhibit remarkable relationships with Oxygen isotopes. Each group is well identified. Cu is linearly correlated with Oxygen, whereas Zn-O data display strong curvature : the difference in shape can be related to the nearly constant Cu content in all groups, and by the decreasing Zn content from CI to CO. Since Oxygen variations (from CV to CI) are thought to reflect progressive interaction of liquid water with initial solid (asteroid), Cu isotopic variations may also reflect this progressive alteration process. It may be so for Zn too, although its more volatile character might play a role. II-Allende Progressive leaching

  10. Direct Observation of Reduction of Cu(II) to Cu(I) by Terminal Alkynes

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Guanghui; Yi, Hong; Zhang, Guoting; Deng, Yi; Bai, Ruopeng; Zhang, Heng; Miller, Jeffrey T.; Kropf, Arthur J.; Bunel, Emilio E.; Lei, Aiwen

    2014-01-06

    ABSTRACT: X-ray absorption spectroscopy and in situ electron paramagnetic resonance evidence were provided for the reduction of Cu(II) to Cu(I) species by alkynes in the presence of tetramethylethylenediamine (TMEDA), in which TMEDA plays dual roles as both ligand and base. The structures of the starting Cu(II) species and the obtained Cu(I) species were determined as (TMEDA)- CuCl2 and [(TMEDA)CuCl]2 dimer, respectively.

  11. Controllable synthesis and enhanced photocatalytic properties of Cu2O/Cu31S16 composites

    International Nuclear Information System (INIS)

    Liu, Xueqin; Li, Zhen; Zhang, Qiang; Li, Fei

    2012-01-01

    Highlights: ► Facile sonochemical route. ► The content of Cu 31 S 16 in the Cu 2 O/Cu 31 S 16 can be easily controlled. ► Structure and optical properties of Cu 2 O/Cu 31 S 16 were discussed. ► Enhanced photocatalytic property of Cu 2 O/Cu 31 S 16 . ► Cu 2 O/Cu 31 S 16 core/shell structures were more stable than single Cu 2 O particles. -- Abstract: The controlled synthesis of Cu 2 O/Cu 31 S 16 microcomposites with hierarchical structures had been prepared via a convenient sonochemical route. Ultrasonic irradiation of a mixture of Cu 2 O and (NH 2 ) 2 CS in an aqueous medium yielded Cu 2 O/Cu 31 S 16 composites. The content of Cu 31 S 16 in the Cu 2 O/Cu 31 S 16 can be easily controlled by adjusting the synthesis time. The Cu 31 S 16 layer not only protected and stabilized Cu 2 O particles, but also prohibited the recombination of photogenerated electrons–holes pair between Cu 31 S 16 and Cu 2 O. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR) spectra, ultraviolet–visible (UV–Vis) spectroscopy and photoluminescence (PL) spectroscopy were used to characterize the products. Photocatalytic performance of the Cu 2 O/Cu 31 S 16 hierarchical structures was evaluated by measuring the decomposition rate of methyl orange solution under natural light. To the best of our knowledge, this is the first report on the preparation and photocatalytic activity of Cu 2 O/Cu 31 S 16 microcomposite. Additionally, the Cu 2 O/Cu 31 S 16 core/shell structures were more stable than single Cu 2 O particles during photocatalytic process since the photocatalytic activity of the second reused architecture sample was much higher than that of pure Cu 2 O. The Cu 2 O/Cu 31 S 16 microcomposites may be a good promising candidate for wastewater treatment.

  12. Dual inhibitory action of enadoline (CI977) on release of amino acids in the rat hippocampus.

    Science.gov (United States)

    Millan, M H; Chapman, A G; Meldrum, B S

    1995-06-06

    The effect of the kappa-opioid receptor agonist enadoline (CI977, (5R)-(5 alpha,7 alpha,8 beta)-N-methyl-N-[7-(1-pyrrilidinyl)-1-oxaspiro [4,5]dec-8-yl-4-benzofuranacetamide monohydrochloride), on the release of amino acids was studied in the hippocampus of freely moving rats. K+, 100 mM, or veratrine, 100 microM, were applied for 10 min via the dialysis probe, either alone (control groups) or together with CI977 (after a 10 min pretreatment with CI977 in the perfusion medium). To test the specificity of the response to CI977, nor-binaltorphimine, a selective kappa-opioid receptor antagonist, was delivered together with CI977 in two groups of animals. To test the effect of systemic injection, CI977 was given subcutaneously 30 min prior to either stimulus. K(+)-induced release of glutamate and aspartate was significantly reduced by CI977, 2.5 mM; release of gamma-aminobutyric acid (GABA) was reduced by 250 microM CI977 in the probe. The effect of CI977 on release of glutamate and aspartate, but not of GABA, was reversed by nor-binaltorphimine (45 microM). Systemic treatment with CI977, 1 or 10 mg/kg, did not reduce K(+)-induced release of glutamate. Veratrine-induced release of aspartate and glutamate was significantly inhibited by 25 microM and release of GABA by 250 microM CI977 in the probe, and this effect was not modified by nor-binaltorphimine (58 microM). Systemic injection of CI977 1 mg/kg significantly reduced veratrine-induced release of glutamate. These results indicate that CI977 regulates release of amino acids by two independent mechanisms.(ABSTRACT TRUNCATED AT 250 WORDS)

  13. Max Weber e a objetividade do conhecimento nas ciências da cultura: um breve guia para o texto A ‘Objetividade’ do Conhecimento na Ciência Social e na Ciência Política (1904

    Directory of Open Access Journals (Sweden)

    Jean Henrique Costa

    2011-05-01

    Full Text Available

    O presente artigo objetiva discutir o sentido da objetividade do conhecimento empírico-social na obra de Max Weber, especificamente no texto “A ‘Objetividade’ do Conhecimento na Ciência Social e na Ciência Política”, de 1904. Discute-se, no primeiro momento, a distinção entre conhecimento empírico e juízo de valor; no segundo momento, faz-se uma rápida crítica às idéias de “lei” e “conexão regular” nas ciências sociais para, em seguida, na terceira parte, discutir a estrutura da formação dos conceitos típico-ideais como recursos metodológicos, nos quais, para Weber, expressam a possibilidade da validade objetiva do conhecimento nas ciências da cultura.

  14. Photonuclear spallation reactions in Cu

    International Nuclear Information System (INIS)

    Shibata, S.; Imamura, M.; Miyachi, T.

    1986-06-01

    Formation yields of 24 radioactive nuclides by the interaction of bremsstrahlung in the maximum end-point energies of 100 MeV - 1 GeV with Cu have been measured by direct γ-ray counting of irradiated targets. The yields in the mass range of 42 to 60 except for 60 Cu were analysed by non-linear least-squares fit to construct the mass yield and charge dispersion curves in spallation reactions. From the parameter values obtained, the energy dependence of the slope of the mass yield curve and the relationship between target N/Z and the most probable product N/Z were investigated in comparison with the results of proton, α and heavy ion-induced spallations of Cu. The characteristics of photon-induced spallations are discussed. (author)

  15. Konwergencja rachunkowości finansowej i rachunkowości zarządczej w Polsce w świetle badań ankietowych

    Directory of Open Access Journals (Sweden)

    Przemysław Kabalski

    2018-03-01

    Full Text Available Celem artykułu jest określenie stopnia konwergencji rachunkowości finansowej i rachunkowości zarządczej w przedsiębiorstwach w Polsce. Do zbadania stopnia konwergencji wykorzystano metodę sondażową z zastosowaniem kwestionariusza ankiety. Okazało się, że poziom konwergencji rachunko- wości w badanych przedsiębiorstwach jest umiarkowany. Badania konwergencji rachunkowości na świecie nie są liczne, a w Polsce ‒ zupełnie wyjątkowe. Z tego względu badanie prezentowane w artykule jest istotne zarówno dla nauki, jak i praktyki rachunkowości. The aim of the article is to determine the level of convergence of financial accounting and management accounting in companies operating in Poland. In order to determine the level of the convergence, the survey method was used. It was found that the level of convergence of accounting in the companies examined is moderate. The number of studies on the convergence of accounting is very limited in the world, and in Poland they are quite unique. For this reason, the research presented in this article is rele- vant for both the science and the practice of accounting.

  16. Application of the graphical unitary group approach to the energy second derivative for CI wave functions via the coupled perturbed CI equations

    International Nuclear Information System (INIS)

    Fox, D.J.

    1983-10-01

    Analytic derivatives of the potential energy for Self-Consistent-Field (SCF) wave functions have been developed in recent years and found to be useful tools. The first derivative for configuration interaction (CI) wave functions is also available. This work details the extension of analytic methods to energy second derivatives for CI wave functions. The principal extension required for second derivatives is evaluation of the first order change in the CI wave function with respect to a nuclear perturbation. The shape driven graphical unitary group approach (SDGUGA) direct CI program was adapted to evaluate this term via the coupled-perturbed CI equations. Several iterative schemes are compared for use in solving these equations. The pilot program makes no use of molecular symmetry but the timing results show that utilization of molecular symmetry is desirable. The principles for defining and solving a set of symmetry adapted equations are discussed. Evaluation of the second derivative also requires the solution of the second order coupled-perturbed Hartree-Fock equations to obtain the correction to the molecular orbitals due to the nuclear perturbation. This process takes a consistently higher percentage of the computation time than for the first order equations alone and a strategy for its reduction is discussed

  17. CiOpt: a program for optimization of the frequency response of linear circuits

    OpenAIRE

    Miró Sans, Joan Maria; Palà Schönwälder, Pere

    1991-01-01

    An interactive personal-computer program for optimizing the frequency response of linear lumped circuits (CiOpt) is presented. CiOpt has proved to be an efficient tool in improving designs where the inclusion of more accurate device models distorts the desired frequency response, as well as in device modeling. The outputs of CiOpt are the element values which best match the obtained and the desired frequency response. The optimization algorithms used (the Fletcher-Powell and Newton's methods,...

  18. 21 CFR 73.3112 - C.I. Vat Orange 1.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 1 2010-04-01 2010-04-01 false C.I. Vat Orange 1. 73.3112 Section 73.3112 Food... COLOR ADDITIVES EXEMPT FROM CERTIFICATION Medical Devices § 73.3112 C.I. Vat Orange 1. (a) Identity. The color additive is C.I. Vat Orange 1, Colour Index No. 59105. (b) Uses and restrictions. (1) The...

  19. Diffusion of Cu+ in β-phase CuI

    International Nuclear Information System (INIS)

    Johansson, J.X.M.Z.; Skoeld, K.; Joergensen, J.E.

    1992-01-01

    Measurements of ionic diffusion of Cu + in solid CuI in the β-phase is carried out with a non-destructive radioactive tracer technique, utilizing coincidence counting of the annihilation gammas from the positron decay of 64 Cu. The diffusion coefficient and the activation energy for the diffusion are evaluated. The experimental results show distinct diffusion character in the β-phase which differs from those in the γ- and α-phases. The β-phase diffusion properties together with the previous results for γ-and α-phases will provide valuable guidance for MD calculations, in which the diffusion coefficients and activation energies have been overestimated and the γ-β phase transition does not appear. The ionic conductivity of CuI estimated from tracer diffusion results and the Nernst-Einstein relation are compared with values from electro-chemical methods. In all three phases the conductivities obtained from electro-chemical methods are much lower than those calculated from the measured tracer diffusion coefficients. (author). 7 refs.; 4 figs.; 2 tabs

  20. Cu/Cu2O/CuO nanoparticles: Novel synthesis by exploding wire technique and extensive characterization

    Science.gov (United States)

    Sahai, Anshuman; Goswami, Navendu; Kaushik, S. D.; Tripathi, Shilpa

    2016-12-01

    In this article, we explore potential of Exploding Wire Technique (EWT) to synthesize the copper nanoparticles using the copper metal in a plate and wire geometry. Rietveld refinement of X-ray diffraction (XRD) pattern of prepared material indicates presence of mixed phases of copper (Cu) and copper oxide (Cu2O). Agglomerates of copper and copper oxide comprised of ∼20 nm average size nanoparticles observed through high resolution transmission electron microscope (HRTEM) and energy dispersive x-ray (EDX) spectroscopy. Micro-Raman (μR) and Fourier transform infrared (FTIR) spectroscopies of prepared nanoparticles reveal existence of additional minority CuO phase, not determined earlier through XRD and TEM analysis. μR investigations vividly reveal cubic Cu2O and monoclinic CuO phases based on the difference of space group symmetries. In good agreement with μRaman analysis, FTIR stretching modes corresponding to Cu2-O and Cu-O were also distinguished. Investigations of μR and FTIR vibrational modes are in accordance and affirm concurrence of CuO phases besides predominant Cu and Cu2O phase. Quantum confinement effects along with increase of band gaps for direct and indirect optical transitions of Cu/Cu2O/CuO nanoparticles are reflected through UV-vis (UV-vis) spectroscopy. Photoluminescence (PL) spectroscopy spots the electronic levels of each phase and optical transitions processes occurring therein. Iterative X-ray photoelectron spectroscopy (XPS) fitting of core level spectra of Cu (2p3/2) and O (1s), divulges presence of Cu2+ and Cu+ in the lattice with an interesting evidence of O deficiency in the lattice structure and surface adsorption. Magnetic analysis illustrates that the prepared nanomaterial demonstrates ferromagnetic behaviour at room temperature.

  1. Bezpieczne formy aktywności fizycznej dla kobiet w ciąży = Secure forms of physical activity for pregnant women

    OpenAIRE

    Urtnowska, Katarzyna; Bułatowicz, Irena; Ludwikowski, Grzegorz; Zukow, Walery

    2016-01-01

    Urtnowska Katarzyna, Bułatowicz Irena, Ludwikowski Grzegorz, Zukow Walery. Bezpieczne formy aktywności fizycznej dla kobiet w ciąży = Secure forms of physical activity for pregnant women. Journal of Education, Health and Sport. 2016;6(5):291-297. eISSN 2391-8306. DOI http://dx.doi.org/10.5281/zenodo.51894 http://ojs.ukw.edu.pl/index.php/johs/article/view/3526 The journal has had 7 points in Ministry of Science and Higher Education parametric evaluation. Part B item 755 (23...

  2. Development and Analysis of Original UNIFAC-CI and Modified UNIFAC-CI Models for Prediction of VLE and SLE Systems

    DEFF Research Database (Denmark)

    Mustaffa, Azizul Azri; Kontogeorgis, Georgios; Kang, Jeong Won

    approach that is able to extend the application range of property models has been developed for mixture properties. This so-called GCPlus approach is a hybrid model which combines GC and valence connectivity indices (CI). The main idea is the use of CI to describe the molecular fragmentation that relates...... parameters are checked using a quality assessment algorithm which combines four widely used consistency tests (Herington, Van Ness, Point/Differential and Infinite Dilution tests) and also a check on the consistencies of the data with the pure component vapor pressures. The overall quality factors, QVLE...

  3. Exploring cued and non-cued motor imagery interventions in people with multiple sclerosis: a randomised feasibility trial and reliability study.

    Science.gov (United States)

    Seebacher, Barbara; Kuisma, Raija; Glynn, Angela; Berger, Thomas

    2018-01-01

    Motor imagery (MI) is increasingly used in neurorehabilitation to facilitate motor performance. Our previous study results demonstrated significantly improved walking after rhythmic-cued MI in people with multiple sclerosis (pwMS). The present feasibility study was aimed to obtain preliminary information of changes in walking, fatigue, quality of life (QoL) and MI ability following cued and non-cued MI in pwMS. The study further investigated the feasibility of a larger study and examined the reliability of a two-dimensional gait analysis system. At the MS-Clinic, Department of Neurology, Medical University of Innsbruck, Austria, 15 adult pwMS (1.5-4.5 on the Expanded Disability Status Scale, 13 females) were randomised to one of three groups: 24 sessions of 17 min of MI with music and verbal cueing (MVMI), with music alone (MMI), or non-cued (MI). Descriptive statistics were reported for all outcomes. Primary outcomes were walking speed (Timed 25-Foot Walk) and walking distance (6-Minute Walk Test). Secondary outcomes were recruitment rate, retention, adherence, acceptability, adverse events, MI ability (Kinaesthetic and Visual Imagery Questionnaire, Time-Dependent MI test), fatigue (Modified Fatigue Impact Scale) and QoL (Multiple Sclerosis Impact Scale-29). The reliability of a gait analysis system used to assess gait synchronisation with music beat was tested. Participants showed adequate MI abilities. Post-intervention, improvements in walking speed, walking distance, fatigue, QoL and MI ability were observed in all groups. Success of the feasibility criteria was demonstrated by recruitment and retention rates of 8.6% (95% confidence interval, CI 5.2, 13.8%) and 100% (95% CI 76.4, 100%), which exceeded the target rates of 5.7% and 80%. Additionally, the 83% (95% CI 0.42, 0.99) adherence rate surpassed the 67% target rate. Intra-rater reliability analysis of the gait measurement instruments demonstrated excellent Intra-Class Correlation coefficients for step

  4. Da possibilidade de uma Teoria Pura da Ciência da Informação: reflexões iniciais entre a Ciência da Informação e a Ciência do Direito

    Directory of Open Access Journals (Sweden)

    Max Cirino de Mattos

    Full Text Available O artigo discute a fragilidade epistemológica da Ciência da Informação, a partir da adoção de um termo polissêmico, como objeto científico, e a similaridade dessa situação com o contexto da criação da Teoria Pura do Direito de Hans Kelsen. Após a apresentação de algumas definições sobre o objeto da Ciência da Informação, discutem-se alguns reflexos relacionados à identidade científica e à fundamentação teórica derivadas de um objeto polissêmico. Apresenta-se uma breve introdução à Teoria Pura do Direito e algumas reflexões sobre a possibilidade de uma Teoria Pura da Ciência da Informação.

  5. CH{sub 4} dehydrogenation on Cu(1 1 1), Cu@Cu(1 1 1), Rh@Cu(1 1 1) and RhCu(1 1 1) surfaces: A comparison studies of catalytic activity

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Riguang; Duan, Tian [Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, Shanxi (China); Ling, Lixia [Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, Shanxi (China); Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, Shanxi (China); Wang, Baojun, E-mail: wangbaojun@tyut.edu.cn [Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, Shanxi (China)

    2015-06-30

    Highlights: • Adsorbed Rh atom on Cu catalyst exhibits better catalytic activity for CH{sub 4} dehydrogenation. • The adsorbed Rh atom is the reaction active center for CH{sub 4} dehydrogenation. • The morphology of Cu substrate has negligible effect on CH{sub 4} dehydrogenation. - Abstract: In the CVD growth of graphene, the reaction barriers of the dehydrogenation for hydrocarbon molecules directly decide the graphene CVD growth temperature. In this study, density functional theory method has been employed to comparatively probe into CH{sub 4} dehydrogenation on four types of Cu(1 1 1) surface, including the flat Cu(1 1 1) surface (labeled as Cu(1 1 1)) and the Cu(1 1 1) surface with one surface Cu atom substituted by one Rh atom (labeled as RhCu(1 1 1)), as well as the Cu(1 1 1) surface with one Cu or Rh adatom (labeled as Cu@Cu(1 1 1) and Rh@Cu(1 1 1), respectively). Our results show that the highest barrier of the whole CH{sub 4} dehydrogenation process is remarkably reduced from 448.7 and 418.4 kJ mol{sup −1} on the flat Cu(1 1 1) and Cu@Cu(1 1 1) surfaces to 258.9 kJ mol{sup −1} on RhCu(1 1 1) surface, and to 180.0 kJ mol{sup −1} on Rh@Cu(1 1 1) surface, indicating that the adsorbed or substituted Rh atom on Cu catalyst can exhibit better catalytic activity for CH{sub 4} complete dehydrogenation; meanwhile, since the differences for the highest barrier between Cu@Cu(1 1 1) and Cu(1 1 1) surfaces are smaller, the catalytic behaviors of Cu@Cu(1 1 1) surface are very close to the flat Cu(1 1 1) surface, suggesting that the morphology of Cu substrate does not obviously affect the dehydrogenation of CH{sub 4}, which accords with the reported experimental observations. As a result, the adsorbed or substituted Rh atom on Cu catalyst exhibit a better catalytic activity for CH{sub 4} dehydrogenation compared to the pure Cu catalyst, especially on Rh-adsorbed Cu catalyst, we can conclude that the potential of synthesizing high-quality graphene with the

  6. Compound Cuing in Free Recall

    Science.gov (United States)

    Lohnas, Lynn J.; Kahana, Michael J.

    2014-01-01

    According to the retrieved context theory of episodic memory, the cue for recall of an item is a weighted sum of recently activated cognitive states, including previously recalled and studied items as well as their associations. We show that this theory predicts there should be compound cuing in free recall. Specifically, the temporal contiguity…

  7. The effect of inducing uniform Cu growth on formation of electroless Cu seed layer

    International Nuclear Information System (INIS)

    Lim, Taeho; Kim, Myung Jun; Park, Kyung Ju; Kim, Kwang Hwan; Choe, Seunghoe; Lee, Young-Soo; Kim, Jae Jeong

    2014-01-01

    The uniformity of Cu growth on Pd nanocatalysts was controlled by using organic additives in the formation of electroless Cu seed layers. Polyethylene glycol (PEG, Mw. 8000) not only reduced the deposition rate but also improved the uniformity of Cu growth on each Pd nanocatalyst during the seed layer formation. The stronger suppression effect of PEG on Cu than on Pd reduced the difference in the deposition rate between the two surfaces, resulting in the uniform deposition. Meanwhile, bis(3-sulfopropyl) disulfide degraded the uniformity by strong and nonselective suppression. The sheet resistance measurement and atomic force microscopy imaging revealed that the uniform Cu growth by PEG was more advantageous for the formation of a thin and smooth Cu seed layer than the non-uniform growth. The uniform Cu growth also had a positive influence on the subsequent Cu electrodeposition: the 60-nm-thick electrodeposited Cu film on the Cu seed layer showed low resistivity (2.70 μΩ·cm), low surface roughness (6.98 nm), and good adhesion strength. - Highlights: • Uniform Cu growth on Pd was achieved in formation of electroless Cu seed layer. • PEG addition to electroless bath improved the uniformity of Cu growth on Pd. • A thin, smooth and continuous Cu seed layer was obtained with PEG. • Adhesion strength of the Cu seed layer was also improved with PEG. • The uniformity improvement positively affected subsequent Cu electrodeposition

  8. Punicalagin Green Functionalized Cu/Cu2O/ZnO/CuO Nanocomposite for Potential Electrochemical Transducer and Catalyst

    Science.gov (United States)

    Fuku, X.; Kaviyarasu, K.; Matinise, N.; Maaza, M.

    2016-09-01

    A novel ternary Punica granatum L-Cu/Cu2O/CuO/ZnO nanocomposite was successfully synthesised via green route. In this work, we demonstrate that the green synthesis of metal oxides is more viable and facile compare to other methods, i.e., physical and chemical routes while presenting a potential electrode for energy applications. The prepared nanocomposite was characterised by both microscopic and spectroscopic techniques. High-resolution scanning electron microscopy (HRSEM) and X-ray diffraction (XRD) techniques revealed different transitional phases with an average nanocrystallite size of 29-20 mm. It was observed that the nanocomposites changed from amorphous-slightly crystalline Cu/Cu2O to polycrystalline Cu/Cu2O/CuO/ZnO at different calcination temperatures (room temperature-RT- 600 °C). The Cu/Cu2O/ZnO/CuO metal oxides proved to be highly crystalline and showed irregularly distributed particles with different sizes. Meanwhile, Fourier transform infrared (FTIR) spectroscopy confirmed the purity while together with ultraviolet-visible (UV-Vis) spectroscopy proved the proposed mechanism of the synthesised nanocomposite. UV-Vis showed improved catalytic activity of the prepared metal oxides, evident by narrow band gap energy. The redox and electrochemical properties of the prepared nanocomposite were achieved by cyclic voltammetry (CV), electrochemical impedance (EIS) and galvanostatic charge-discharge (GCD). The maximum specific capacitance ( C s) was calculated to be 241 F g-1 at 50 mV s-1 for Cu/Cu2O/CuO/ZnO nanoplatelets structured electrode. Moreover, all the CuO nanostructures reveal better power performance, excellent rate as well as long term cycling stability. Such a study will encourages a new design for a wide spectrum of materials for smart electronic device applications.

  9. Dyskusja wokół celu sprawozdawczości finansowej opartej na MSSF

    Directory of Open Access Journals (Sweden)

    Edyta Łazarowicz

    2016-07-01

    Full Text Available Celem artykułu jest analiza i ocena propozycji zmian odnośnie do celu sprawozdawczości finansowej opartej na Międzynarodowych Standardach Sprawozdawczości Finansowej (MSSF przedstawionych w komentarzach do projektu Założeń koncepcyjnych sprawozdawczości finansowej (2015. Większość respondentów uważa, że w celu sprawozdawczości finansowej należy zwiększyć znaczenie dostarczania informacji o wypełnieniu funkcji powierniczej przez kierownictwo (stewardship. Ponadto proponują oni przedstawienie definicji stewardship w Założeniach koncepcyjnych oraz wskazanie konsekwencji zmiany celu sprawozdawczości finansowej dla przyszłego tworzenia standardów i dla sporządzania sprawozdań finansowych. Z analizy komentarzy i przeglądu literatury wynika, że cel sprawozdawczości finansowej powinien być zmieniony. Sprawą dyskusyjną pozostaje jednak, czy stewardship powinien być odrębnym celem. Niestety, jest za mało badań dotyczących relacji pomiędzy stewardship i użytecznością decyzyjną. Ich wyniki mogłyby wskazać twórcom standardów rachunkowości potencjalne kompromisy i konflikty między nimi.

  10. CiF-CK: An Architecture for Social NPCs in Commercial Games

    NARCIS (Netherlands)

    Guimaraes, Manuel; Santos, Pedro A.; Jhala, Arnav

    2018-01-01

    We present and describe CiF-CK — a social agent architecture that models reasoning about persistent social interactions to improve narrative engagement and play experience for human interactors. The architecture is inspired by McCoy et al’s Comme il-Faut (CiF) architecture that represented

  11. Detection of CI line emission towards the oxygen-rich AGB star omi Ceti

    Science.gov (United States)

    Saberi, M.; Vlemmings, W. H. T.; De Beck, E.; Montez, R.; Ramstedt, S.

    2018-05-01

    We present the detection of neutral atomic carbon CI(3P1-3P0) line emission towards omi Cet. This is the first time that CI is detected in the envelope around an oxygen-rich M-type asymptotic giant branch (AGB) star. We also confirm the previously tentative CI detection around V Hya, a carbon-rich AGB star. As one of the main photodissociation products of parent species in the circumstellar envelope (CSE) around evolved stars, CI can be used to trace sources of ultraviolet (UV) radiation in CSEs. The observed flux density towards omi Cet can be reproduced by a shell with a peak atomic fractional abundance of 2.4 × 10-5 predicted based on a simple chemical model where CO is dissociated by the interstellar radiation field. However, the CI emission is shifted by 4 km s-1 from the stellar velocity. Based on this velocity shift, we suggest that the detected CI emission towards omi Cet potentially arises from a compact region near its hot binary companion. The velocity shift could, therefore, be the result of the orbital velocity of the binary companion around omi Cet. In this case, the CI column density is estimated to be 1.1 × 1019 cm-2. This would imply that strong UV radiation from the companion and/or accretion of matter between two stars is most likely the origin of the CI enhancement. However, this hypothesis can be confirmed by high-angular resolution observations.

  12. Preparation of Cu Nanoclusters within Dendrimer Templates

    National Research Council Canada - National Science Library

    Zhao, M

    1998-01-01

    ... (16-atom Cu cluster in G4 and 64-atom Cu cluster in G6 dendrimers). The clusters remain trapped within the dendrimers for extended periods of time, do not agglomerate, and do not precipitate. The clusters can also be oxidized to yield dendrimer-encapsulated Cu(2+).

  13. Comparative evaluation of the two methods of fixed dose radioiodine therapy (5 mCi and 10 mCi) for the treatment of Graves' disease

    International Nuclear Information System (INIS)

    Fard Esfehani, A.; Dabbagh Kakhki, V.R.; Eftekhari, M.; Zarpak, B.; Fallahi Seyjani, B.; Saghari, M.

    2002-01-01

    Radioiodine therapy is the safest, simplest, least expensive and most effective method for treatment in most patients with Graves' disease. Due to complexity of methods for dose determination, the tendency is toward using fixed doses of I-131 for this purpose. As there is conflict for the best fixed dose, regarding it's efficiency and complication of hypothyroidism, standardized dose selection is of particular importance in treatment of Grave' disease. 59 patients with grave' disease, referred to the nuclear medicine center of Shariati Hospital from 78.5.25 were studied. In this clinical trial, the patients were randomized into two groups, one were treated with 5 mCi of 1-131 and the other received 10 mCi of the same agent. All patients were followed for two years, with 6-month intervals. Among 65 patients treated with I-131, 20 (33 9%) patients became euthyroid and 19(32.2%) became hypothyroid while relapse was noticed in 20 patients (33.9%) In The group treated by 5 mCi I-131 (33 patients), 10(30%) were euthyroid, 6(18.2%) were hypothyroid (overall cure of 48.5% while 17(51.5%) remained hyperthyroid by the end of the follow -up period(two years). From the 26 patients who were treated with 10 mCi, the euthyroid, hypothyroid and hypothyroid states were observed in 10(38.5%), 13(50%), 13(50%) and 3(11.5%) patients respectively (with an overall cure rate of 88.5%). No relationship was noted between the outcome and age, sex, size of the thyroid gland and thyroid uptake, but the relationship between the disease outcome and the amount of administered radioiodine was statistically significant (P=0.003). For most of the patients, age, sex, iodine uptake and even thyroid size play minor roles in dose selection. Although the incidence-rate of early hypothyroidism (by the end of 2 years) in the cases related with 5 mCi is less than those treated with 10 mCi, the incidence of relapse is greatly higher in the former group. In addition, it was found that long

  14. Wartości poznawcze sprawozdawczości regulacyjnej podmiotu świadczącego powszechne usługi pocztowe

    Directory of Open Access Journals (Sweden)

    Leszek Borowiec

    2018-03-01

    Full Text Available Ze względu na aspekty strategiczne, gospodarcze czy społeczne, niektóre obszary aktywności przedsiębiorstw w gospodarce rynkowej są organizowane w ramach tzw. rynków regulowanych. Regulacja danej części rynku najczęściej podlega dodatkowym rygorom sprawozdawczości. Celem artykułu jest próba oceny wartości poznawczych sprawozdawczości z rachunkowości regulacyjnej operatora wyznaczonego do świadczenia powszechnych usług pocztowych. W opracowaniu dokonano przeglądu uwarunkowań prawnych działania operatora wyznaczonego oraz scharakteryzowano zakres ujawnianych informacji w sprawozdawczości regulacyjnej, na przykładzie rynku pocztowych usług powszechnych. Podstawą analizy były sprawozdania regulacyjne składne przez operatora wyznaczonego, tj. Pocztę Polską. Wopracowaniu zastosowano takie metody badawcze jak: studia literaturowe, analiza aktów prawnych regulujących rynek usług pocztowych, wywiady oraz badanie poprzez działanie. Konkluzje skłaniają do stwierdzenia, iż sprawozdawczość regulacyjna, mimo swojej specyfiki, dla regulatora rynku stanowi istotne źródło informacji do oceny efektywności świadczonych usług. Jednocześnie ma bardzo wątpliwe walory poznawcze dla interesariuszy zewnętrznych, ze względu na szeroki zakres stosowania instytucji „tajemnicy przedsiębiorstwa”. Artykuł jest oryginalnym spojrzeniem autora na słabo rozpoznany od strony naukowej problem wartości informacyjnej dla interesariuszy sprawozdawczości podmiotów działających w sektorach regulowanych. For strategic, economic or social reasons, some areas of business activity in the market economy are organized under the so-called regulated markets. The regulation of a given part of the market is most often subject to additional reporting requirements. The aim of this article is to try to assess the cognitive value of reporting from the regulatory accounting of an operator designated to provide universal postal services. The

  15. Bezpieczne formy aktywności fizycznej dla kobiet w ciąży = Secure forms of physical activity for pregnant women

    Directory of Open Access Journals (Sweden)

    Katarzyna Urtnowska

    2016-05-01

    4Wydział Kultury Fizycznej, Zdrowia i Turystyki, Uniwersytet Kazimierza Wielkiego w Bydgoszczy           mgr Katarzyna Urtnowska1, dr n. med. Irena Bułatowicz2, dr hab. n. med. Grzegorz Ludwikowski3, dr hab. Walery Zukow4 1Uczestnik studiów dokotranckich z zakresu Nauk o Zdrowiu; Zakład Medycyny Rozdrodu i Andrologii, Collegium Medicum im. L. Rydygiera w Bydgoszczy Uniwersytet Mikołaja Kopernika w Toruniu 2Katedra Fizjoterapii - Zakład Fizjoterapii Klinicznej, Collegium Medicum im. L. Rydygiera w Bydgoszczy Uniwersytet Mikołaja Kopernika w Toruniu 3Zakład Medycyny Rozdrodu i Andrologii, Collegium Medicum im. L. Rydygiera w Bydgoszczy Uniwersytet Mikołaja Kopernika w Toruniu 4Wydział Kultury Fizycznej, Zdrowia i Turystyki, Uniwersytet Kazimierza Wielkiego w Bydgoszczy           Słowa kluczowe: ciąża, aktywność fizyczna, sport. Keywords: pregnancy, physical activity, sport.           Streszczenie Kobieta spodziewać się dziecka w dzisiejszych czasach ma wiele możliwości podjęcia bezpiecznej formy aktywności fizycznej. Z odrobiną racjonalnego podejścia może kontynuować uprawianie ulubionego sportu, lub uczestniczyć w zajęciach przygotowanych specjalnie dla ciężarnych. Aktywność fizyczna uprawiana regularnie w trakcie ciąży jest kluczowym czynnikiem wpływającym na zdrowie i samopoczucie matki. Ćwiczenia wpływają korzystnie na stan zdrowia poprzez zmniejszenie dolegliwości bólowych kręgosłupa, ogólną poprawę lub brak pogorszenia sprawności fizycznej, zapobieganie nadmiernemu przyrostowi masy ciała i poprawę samopoczucia ciężarnej. Dodatkowym, a zarazem najważniejszym efektem jest zwiększenie wydolności fizycznej niezbędnej do porodu siłami natury i skrócenie czasu jego przebiegu oraz czasu regeneracji organizmu w połogu, a co za tym idzie, szybszy powrót do formy sprzed ciąży.     Abstract A women expect a child a child today has a lot of possibilities for secure forms of physical activity. With

  16. Growth of intermetallics between Sn/Ni/Cu, Sn/Ag/Cu and Sn/Cu layered structures

    International Nuclear Information System (INIS)

    Horváth, Barbara; Illés, Balázs; Shinohara, Tadashi

    2014-01-01

    Intermetallic growth mechanisms and rates are investigated in Sn/Ni/Cu, Sn/Ag/Cu and Sn/Cu layer systems. An 8–10 μm thick Sn surface finish layer was electroplated onto a Cu substrate with a 1.5–2 μm thick Ni or Ag barrier layer. In order to induce intermetallic layer growth, the samples were aged in elevated temperatures: 50 °C and 125 °C. Intermetallic layer growth was checked by focused ion beam–scanning ion microscope. The microstructures and chemical compositions of the intermetallic layers were observed with a transmission electron microscope. It has been found that Ni barrier layers can effectively block the development of Cu 6 Sn 5 intermetallics. The intermetallic growth characteristics in the Sn/Cu and Sn/Ni/Cu systems are very similar. The intermetallic layer grows towards the Sn layer and forms a discrete layer. Differences were observed only in the growth gradients and surface roughness of the intermetallic layer which may explain the different tin whiskering properties. It was observed that the intermetallic layer growth mechanisms are completely different in the Ag barrier layers compared to the Ni layers. In the case of Sn/Ag/Cu systems, the Sn and Cu diffused through the Ag layer, formed Cu 6 Sn 5 intermetallics mainly at the Sn/Ag interface and consumed the Ag barrier layer. - Highlights: • Intermetallic growth was characterised in Sn/Ni/Cu, Sn/Ag/Cu and Sn/Cu layer systems. • Intermetallic growth rates and roughness are similar in the Sn/Cu and Sn/Ni/Cu systems. • Sn/Ni/Cu system contains the following intermetallic layer structure Sn–Ni3Sn4–Ni3Sn2–Ni3Sn–Ni. • In the case of Sn/Ag/Cu systems the Sn and Cu diffusion consumes the Ag barrier layer. • When Cu reaches the Sn/Ag interface a large amount of Cu 6 Sn 5 forms above the Ag layer

  17. Wpływ aktywności fizycznej w okresie ciąży na przebieg porodu = The influence of physical activity during pregnancy on childbirth

    Directory of Open Access Journals (Sweden)

    AGNIESZKA KONSTANCJA PAWŁOWSKA-MUC

    2015-09-01

    3 Ośrodek Kształcenia Podyplomowego Pielęgniarek i Położnych Radomski Szpital Specjalistyczny im. dr Tytusa Chałubińskiego w Radomiu, ul. Lekarska 4   Adres do korespondencji Grażyna Stadnicka Samodzielna Pracownia Umiejętności Położniczych, Wydział Nauk o Zdrowiu, Uniwersytet Medyczny 10-081 Lublin, ul. Staszica 4/6; e-mail:grazyna.stadnicka@umlub.pl   Streszczenie Aktywność fizyczna w czasie ciąży poprawia ogólną kondycję fizyczną i zapobiega dolegliwościom tego okresu. Celem pacy była ocena profilu społeczno-demograficznego kobiet rodzących oraz wpływu aktywności fizycznej w okresie ciąży na przebieg porodu. Materiał i metoda. Badania przeprowadzono wśród 150 rodzących. Narzędzie badawcze stanowiła ankieta własnego autorstwa, skala Borga oraz skala oceny bólu VAS. Wyniki. Badane były w wieku 19-41 lat,  średnia wieku wynosiła 28.7±5.3  lat. Najczęściej podejmowaną przez respondentki aktywnością fizyczną był spacer (n=29; 38.15%, fitness (n=21; 27.63%, joge (n=14; 18.42%, pilates (n=25; 32.89%.Korzystanie z aktywności ruchowej przez kobiety w ciąży było zależne od: wykształcenia (p=0.031, miejsca zamieszkania (p=0.13, statusu zawodowego (0.004 oraz wieku (p=0.042 badanych. Aktywności fizyczna w okresie ciąży miała znamienny statystycznie wpływ na sposób ukończenia ciąży (p=0.024 i wystąpienie samoistnej czynności skurczowej (p=0.001 oraz  bliski istotności statystycznej wpływ na częstość uszkodzenia krocza podczas porodu (0.049. Wnioski. Aktywność fizyczna podczas ciąży nie ma wpływu na częstotliwość okołoporodowych urazów kanału rodnego, w tym nacinania krocza. Natomiast warunkuje wystąpienie samoistnych skurczów porodowych, lepszą tolerancję bólu i wysiłku podczas porodu oraz zmniejsza liczbę cięć cesarskich.   Słowa kluczowe: ciąża, aktywność fizyczna, poród.   Abstract Physical activity during pregnancy, which improves overall physical condition and prevents

  18. Effect of Inhomogeneous Mixture Properties on CI Combustion in a Schnurle-Type Gasoline DI Engine

    Science.gov (United States)

    Kim, Seok-Woo; Moriyoshi, Yasuo

    The authors have performed experiments on compression-ignition (CI) for a single-cylinder Schnurle-type two-stroke gasoline direct injection (DI) engine which employs a variable exhaust port, area, and deduced two presumptions from the experimental results. Firstly, the spatial distributions of fuel concentration and in-cylinder gas temperature are indispensable to enable CI operation under stratified charge conditions, because CI operation is not possible in a DI system although the necessary conditions of the scavenging efficiency and the in-cylinder gas temperature for the initiation of CI in homogeneous charge conditions are satisfied. Secondly, it is possible that flame propagation occurs in stratified charge CI conditions, because the combustion period in the later stage after 80% mass burned becomes longer than that with homogeneous charge CI combustion. In this report, in order to verify the above two presumptions deduced from experiments, the gas exchange process and mixture formation process were numerically analyzed, and the initiation conditions of CI were estimated using a CHEMKIN application. As a result, in case of CI with a late injection timing in DI system, it was found that CI was possible because high temperature but no fuel region and low temperature but rich fuel region exist in the cylinder due to inhomogeneous spatial distributions of fuel and temperature. Also, in case of CI with a late injection timing, the flame propagation was possible in the low-temperature and diluted rich region. Thereby, the two presumptions deduced from the experimental results were validated from the numerical analysis results.

  19. Influence of Cu content on the cell biocompatibility of Ti–Cu sintered alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Erlin, E-mail: zhangel@atm.neu.edu.cn [Key Lab. for Anisotropy and Texture of Materials, Education Ministry of China, Northeastern University, Shenyang 110819 (China); Jiamusi University, Jiamusi 154007 (China); Zheng, Lanlan [Jiamusi University, Jiamusi 154007 (China); Liu, Jie [Key Lab. for Anisotropy and Texture of Materials, Education Ministry of China, Northeastern University, Shenyang 110819 (China); Dept. of Prosthodontics, The Affiliated Hospital of Medical College, Qingdao University, Qingdao 266003 (China); Bai, Bing [Dept. of Prosthodontics, School of Stomatology, China Medical University, Liaoning Institute of Dental Research, Shenyang 110001 (China); Liu, Cong [Jiamusi University, Jiamusi 154007 (China)

    2015-01-01

    The cell toxicity and the cell function of Ti–Cu sintered alloys with different Cu contents (2, 5, 10 and 25 wt.%, respectively) have been investigated in comparison with commercial pure titanium in order to assess the influence of Cu content on the cell biocompatibility of the Ti–Cu alloys. The cytotoxicity was studied by examining the MG63 cell response by CCK8 assessment. The cell morphology was evaluated by acridine orange/ethidium bromide (AO/EB) fluorescence and observed under scanning electronic microscopy (SEM). The cell function was monitored by measuring the AKP activity. It has been shown by the AO/EB morphology results that the cell death on both cp-Ti sample and Ti–Cu samples is due to apoptosis rather than necrosis. Although more apoptotic cells were found on the Ti–2Cu and Ti–5Cu samples, no evidence of Cu content dependent manner of apoptosis has been found. SEM observation indicated very good cell adhesion and spread on the cp-Ti sample and the Ti–Cu samples with different Cu contents. CCK8 results displayed that increase in the Cu content in Ti–Cu alloys does not bring about any difference in the cell viability. In addition, AKP test results indicated that no difference in the differentiation of MG63 was found between the cp-Ti and the Ti–Cu samples and among the Ti–Cu samples. All results indicated that Ti–Cu alloys exhibit very good cell biocompatibility and the Cu content up to 25 wt.% in the Ti–Cu alloys has no influence on the cell proliferation and differentiation. - Highlights: • The effect of Cu content on the cell biocompatibility has been investigated. • Cu content shows no influence on the cell proliferation. • Cu content shows no effect on the cell differentiation.

  20. Influence of Cu content on the cell biocompatibility of Ti–Cu sintered alloys

    International Nuclear Information System (INIS)

    Zhang, Erlin; Zheng, Lanlan; Liu, Jie; Bai, Bing; Liu, Cong

    2015-01-01

    The cell toxicity and the cell function of Ti–Cu sintered alloys with different Cu contents (2, 5, 10 and 25 wt.%, respectively) have been investigated in comparison with commercial pure titanium in order to assess the influence of Cu content on the cell biocompatibility of the Ti–Cu alloys. The cytotoxicity was studied by examining the MG63 cell response by CCK8 assessment. The cell morphology was evaluated by acridine orange/ethidium bromide (AO/EB) fluorescence and observed under scanning electronic microscopy (SEM). The cell function was monitored by measuring the AKP activity. It has been shown by the AO/EB morphology results that the cell death on both cp-Ti sample and Ti–Cu samples is due to apoptosis rather than necrosis. Although more apoptotic cells were found on the Ti–2Cu and Ti–5Cu samples, no evidence of Cu content dependent manner of apoptosis has been found. SEM observation indicated very good cell adhesion and spread on the cp-Ti sample and the Ti–Cu samples with different Cu contents. CCK8 results displayed that increase in the Cu content in Ti–Cu alloys does not bring about any difference in the cell viability. In addition, AKP test results indicated that no difference in the differentiation of MG63 was found between the cp-Ti and the Ti–Cu samples and among the Ti–Cu samples. All results indicated that Ti–Cu alloys exhibit very good cell biocompatibility and the Cu content up to 25 wt.% in the Ti–Cu alloys has no influence on the cell proliferation and differentiation. - Highlights: • The effect of Cu content on the cell biocompatibility has been investigated. • Cu content shows no influence on the cell proliferation. • Cu content shows no effect on the cell differentiation

  1. Porous HKUST-1 derived CuO/Cu2O shell wrapped Cu(OH)2 derived CuO/Cu2O core nanowire arrays for electrochemical nonenzymatic glucose sensors with ultrahigh sensitivity

    Science.gov (United States)

    Yu, Cuiping; Cui, Jiewu; Wang, Yan; Zheng, Hongmei; Zhang, Jianfang; Shu, Xia; Liu, Jiaqin; Zhang, Yong; Wu, Yucheng

    2018-05-01

    Self-supported CuO/Cu2O@CuO/Cu2O core-shell nanowire arrays (NWAs) are successfully fabricated by a simple and efficient method in this paper. Anodized Cu(OH)2 NWAs could in-situ convert to HKUST-1 at room temperature easily. Cu(OH)2 NWAs cores and HKUST-1 shells transform into CuO/Cu2O simultaneously after calcinations and form CuO/Cu2O@CuO/Cu2O core-shell NWAs. This smart configuration of the core-shell structure not only avoids the agglomeration of the traditional MOF-derived materials in particle-shape, but also facilitates the ion diffusion and increases the active sites. This novel structure is employed as substrate to construct nonenzymatic glucose sensors. The results indicate that glucose sensor based on CuO/Cu2O@CuO/Cu2O core-shell NWAs presents ultrahigh sensitivity (10,090 μA mM-1 cm-2), low detection limit (0.48 μM) and wide linear range (0.99-1,330 μM). In addition, it also shows excellent anti-interference ability toward uric acid, ascorbic acid and L-Cysteine co-existing with glucose, good reproducibility and superior ability of real sample analysis.

  2. Synthesis of Cu2O, CuCl, and Cu2OCl2 nanoparticles by ultrafast ...

    Indian Academy of Sciences (India)

    2014-02-13

    Feb 13, 2014 ... 800 nm and ∼2 ps laser pulses. Cu2O NPs exhibited two-photon absorption at lower peak intensities while three-photon absorption was observed at higher peak intensities. Other samples exhibited two-photon absorption at all peak intensities. Keywords. Picosecond; laser ablation; copper complex; ...

  3. Synthesis of Cu 2 O, CuCl, and Cu2OCl 2 nanoparticles by ultrafast ...

    Indian Academy of Sciences (India)

    2014-02-13

    Feb 13, 2014 ... We have also performed nonlinear optical studies of colloidal nanoparticles using Z-scan technique at 800 nm and ∼2 ps laser pulses. Cu2O NPs exhibited two-photon absorption at lower peak intensities while three-photon absorption was observed at higher peak intensities. Other samples exhibited ...

  4. Epitaxial growth of Cu on Cu(001): Experiments and simulations

    International Nuclear Information System (INIS)

    Furman, Itay; Biham, Ofer; Zuo, Jiang-Kai; Swan, Anna K.; Wendelken, John

    2000-01-01

    A quantitative comparison between experimental and Monte Carlo simulation results for the epitaxial growth of Cu/Cu(001) in the submonolayer regime is presented. The simulations take into account a complete set of hopping processes whose activation energies are derived from semiempirical calculations using the embedded-atom method. The island separation is measured as a function of the incoming flux and the temperature. A good quantitative agreement between the experiment and simulation is found for the island separation, the activation energies for the dominant processes, and the exponents that characterize the growth. The simulation results are then analyzed at lower coverages, which are not accessible experimentally, providing good agreement with theoretical predictions as well

  5. Preparation of conductive Cu patterns by directly writing using nano-Cu ink

    Energy Technology Data Exchange (ETDEWEB)

    Li, Wei [School of Materials Science and Engineering, Tianjin University, Tianjin 300072 (China); Li, Wenjiang; Wei, Jun [School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China); Tan, Junjun [School of Chemical and Materials and Engineering, Hubei University of Technology, Hubei 435003 (China); Chen, Minfang, E-mail: mfchentj@126.com [School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China)

    2014-07-01

    Conductive and air-stable Cu patterns were directly made on ordinary photo paper using a roller pen filled with nano-Cu ink, which was mainly composed of metallic Cu nanoparticles (NPs) capped with poly(N-vinylpyrrolidone) (PVP). The nano-Cu NPs were obtained via the reduction of Cu{sup 2+} ions by using an excess of hydrazine and PVP. The low sintering temperature (160 °C) in Ar atmosphere played an important role for the preparation of air-stable Cu patterns. The conductivity of a radio-frequency identification antenna made from nano-Cu ink was tested by a lamp, and its resistivity achieved 13.4 ± 0.4 μΩ cm. The Cu NPs were confirmed by means of X-ray powder diffraction and X-ray photoelectron spectra, and the Cu patterns were characterized by scanning electron microscopy and energy dispersive X-ray spectrometry. A mechanism for the high conductivity of the Cu pattern made from Cu NPs is proposed. - Highlights: • The synthesis of pure Cu is related to the reducing agent and capping agent. • The sintering under Ar atmosphere prevents Cu pattern's rapid oxidation. • The formation of the bulk Cu decreases the resistivity of the Cu pattern.

  6. Stability enhancement of Cu2S against Cu vacancy formation by Ag alloying

    Science.gov (United States)

    Barman, Sajib K.; Huda, Muhammad N.

    2018-04-01

    As a potential solar absorber material, Cu2S has proved its importance in the field of renewable energy. However, almost all the known minerals of Cu2S suffer from spontaneous Cu vacancy formation in the structure. The Cu vacancy formation causes the structure to possess very high p-type doping that leads the material to behave as a degenerate semiconductor. This vacancy formation tendency is a major obstacle for this material in this regard. A relatively new predicted phase of Cu2S which has an acanthite-like structure was found to be preferable than the well-known low chalcocite Cu2S. However, the Cu-vacancy formation tendency in this phase remained similar. We have found that alloying silver with this structure can help to reduce Cu vacancy formation tendency without altering its electronic property. The band gap of silver alloyed structure is higher than pristine acanthite Cu2S. In addition, Cu diffusion in the structure can be reduced with Ag doped in Cu sites. In this study, a systematic approach is presented within the density functional theory framework to study Cu vacancy formation tendency and diffusion in silver alloyed acanthite Cu2S, and proposed a possible route to stabilize Cu2S against Cu vacancy formations by alloying it with Ag.

  7. Highly charged swelling mica reduces Cu bioavailability in Cu-contaminated soils

    Energy Technology Data Exchange (ETDEWEB)

    Stuckey, Jason W. [Department of Crop and Soil Sciences, Pennsylvania State University, 116 ASI Building, University Park, PA 16802 (United States); Neaman, Alexander [Facultad de Agronomia, P. Universidad Catolica de Valparaiso, Centro Regional de Estudios en Alimentos Saludables (Chile); Ravella, Ramesh; Komarneni, Sridhar [Department of Crop and Soil Sciences, Pennsylvania State University, 116 ASI Building, University Park, PA 16802 (United States); Martinez, Carmen Enid [Department of Crop and Soil Sciences, Pennsylvania State University, 116 ASI Building, University Park, PA 16802 (United States)], E-mail: cem17@psu.edu

    2009-01-15

    This is the first test of a highly charged swelling mica's (Na-2-mica) ability to reduce the plant-absorbed Cu in Cu-contaminated soils from Chile. Perennial ryegrass (Lolium perenne L.) was grown in two acid soils (Sector 2: pH 4.2, total Cu = 172 mg Cu kg{sup -1} and Sector 3: pH 4.2, total Cu = 112 mg Cu kg{sup -1}) amended with 0.5% and 1% (w/w) mica, and 1% (w/w) montmorillonite. At 10 weeks of growth, both mica treatments decreased the shoot Cu of ryegrass grown in Sector 2 producing shoot Cu concentrations above 21-22 mg Cu kg{sup -1} (the phytotoxicity threshold for that species), yet the mica treatments did not reduce shoot Cu concentrations when grown in Sector 3, which were at a typical level. The mica treatments improved shoot growth in Sector 3 by reducing free and extractable Cu to low enough levels where other nutrients could compete for plant absorption and translocation. In addition, the mica treatments improved root growth in both soils, and the 1% mica treatment reduced root Cu in both soils. This swelling mica warrants further testing of its ability to assist re-vegetation and reduce Cu bioavailability in Cu-contaminated surface soils. - In situ remediation of Cu-contaminated soils with a synthetic mica (Na-2-mica) will aid in re-vegetative efforts.

  8. A modified CAS-CI approach for an efficient calculation of magnetic exchange coupling constants

    Science.gov (United States)

    Fink, Karin; Staemmler, Volker

    2013-09-01

    A modification of the conventional wavefunction-based CAS-CI method for the calculation of magnetic exchange coupling constants J in small molecules and transition metal complexes is presented. In general, CAS-CI approaches yield much too small values for J since the energies of the important charge transfer configurations are calculated with the ground state orbitals and are therefore much too high. In the present approach we improve these energies by accounting for the relaxation of the orbitals in the charge transfer configurations. The necessary relaxation energies R can be obtained in separate calculations using mononuclear or binuclear model systems. The method is applied to a few examples, small molecules, binuclear transition metal complexes, and bulk NiO. It allows to obtaining fairly reliable estimates for J at costs that are not higher than those of conventional CAS-CI calculations. Therefore, extended and very time-consuming perturbation theory (PT2), configuration interaction (CI), or coupled cluster (CC) schemes on top of the CAS-CI calculation can be avoided and the modified CAS-CI (MCAS-CI) approach can be applied to rather large systems.

  9. Complex coordinate rotation and relativistic Hylleraas-CI: helium isoelectronic series

    International Nuclear Information System (INIS)

    Pestka, G; Bylicki, M; Karwowski, J

    2007-01-01

    A combination of the Hylleraas-CI (Hy-CI) and complex coordinate rotation (CCR) methods has been applied to study the nuclear charge dependence of the eigenvalues of the Dirac-Coulomb (DC) Hamiltonian corresponding to the ground states of helium isoelectronic series atoms. It has been shown that the CCR, due to the separation of the localized states from the unphysical Brown-Ravenhall continuum, removes the instabilities of the bound-state eigenvalues observed in large-basis set Hy-CI results. The Hy-CI-CCR results are in very good agreement with the most accurate ones available in the literature. Surprisingly, the difference between the DC Hy-CI-CCR eigenvalues and the eigenvalues of the positive-energy projected no-pair Hamiltonian is equal, up to the numerical accuracy of the results, to (Zα) 3 /6π, i.e. to (Zα) 3 relativistic many-body perturbation theory contribution for electron-electron Coulomb interaction operator. An excellent agreement between the Hy-CI-CCR eigenvalues shifted by (Zα) 3 /6π and the no-pair ones confirms the very high accuracy achieved in both approaches. The numerical accuracy of the Hy-CI-CCR DC eigenvalues is estimated to eight significant figures

  10. Dylematy standaryzacjisprawozdawczości finansowej,wyceny i pomiaru ryzyka

    Directory of Open Access Journals (Sweden)

    Dorota Dobija

    2010-09-01

    Full Text Available W artykule zostały poruszone zagadnienia związane z istotą przejrzystości fi-nansowej organizacji. Przejrzystość ta jest jednym z elementów efektywnego systemu ładu korporacyjnego, dlatego tempo zmian w tym obszarze jest narzucone przez refor-my w systemach ładu korporacyjnego. W pierwszej części opracowania jest dyskuto-wana rola menedżerów w zapewnieniu przejrzystości finansowej organizacji. Kolejna część opracowania obejmuje krytyczną dyskusję trzech istotnych wątków teore-tycznych wpływających na jakość sprawozdawczości: postępującej standaryzacji w rachunkowości, problemów wyceny w rachunkowości oraz zagadnień pomiaru i sprawozdawczości ryzyka w organizacji.

  11. Nursing domain of CI governance: recommendations for health IT adoption and optimization.

    Science.gov (United States)

    Collins, Sarah A; Alexander, Dana; Moss, Jacqueline

    2015-05-01

    There is a lack of recommended models for clinical informatics (CI) governance that can facilitate successful health information technology implementation. To understand existing CI governance structures and provide a model with recommended roles, partnerships, and councils based on perspectives of nursing informatics leaders. We conducted a cross-sectional study through administering a survey via telephone to facilitate semistructured interviews from June 2012 through November 2012. We interviewed 12 nursing informatics leaders, across the United States, currently serving in executive- or director-level CI roles at integrated health care systems that have pioneered electronic health records implementation projects. We found the following 4 themes emerge: (1) Interprofessional partnerships are essential. (2) Critical role-based levels of practice and competencies need to be defined. (3) Integration into existing clinical infrastructure facilitates success. (4) CI governance is an evolving process. We described specific lessons learned and a model of CI governance with recommended roles, partnerships, and councils from the perspective of nursing informatics leaders. Applied CI work is highly interprofessional with patient safety implications that heighten the need for best practice models for governance structures, adequate resource allocation, and role-based competencies. Overall, there is a notable lack of a centralized CI group comprised of formally trained informaticians to provide expertise and promote adherence to informatics principles within EHR implementation governance structures. Our model of the nursing domain of CI governance with recommended roles, partnerships, and councils provides a starting point that should be further explored and validated. Not only can the model be used to understand, shape, and standardize roles, competencies, and structures within CI practice for nursing, it can be used within other clinical domains and by other informaticians

  12. Empiryczna weryfikacja hipotezy o przenośności modelu Altmana na warunki polskiej gospodarki oraz uniwersalności sektorowej modeli

    Directory of Open Access Journals (Sweden)

    Tomasz Iwanowicz

    2018-03-01

    Full Text Available Celem artykułu jest próba udzielenia odpowiedzi na pytanie, czy istnieje uzasadnienie dla mechanicznego przenoszenia modelu Altmana na warunki polskiej gospodarki oraz sprawdzenie, czy wśród testowanych modeli istnieje model wykazujący dla każdego typu przedsiębiorstwa (przemysłowe, handlowe, usługo- we najwyższą skuteczność i najlepsze wartości zastosowanych metod porównawczych. W artykule porównano trzynaście testowanych modeli używając macierzy klasyfikacji, ilorazu szans, krzywej kon- centracji CAP i wskaźnika dokładności Giniego, będących metodami oceny sprawności, oraz wskaźnika Briera będącego metodą oceny modeli z punktu widzenia kryterium kalibracji. Badania zostały przepro- wadzone na bazie 439 sprawozdań finansowych opublikowanych przez 139 spółek kapitałowych zarejestrowanych w warszawskich sądach okręgowych i rejonowych (w tym 79 spółek, które w rzeczywistości ogłosiły upadłość. Przeprowadzone badania obaliły mit o przenośności modelu Altmana na warunki polskiej gospodarki oraz uniwersalności sektorowej modeli. Wykazano, że sprawność modeli różni się dla spółek produkcyjnych, handlowych i usługowych oraz określono te sprawności. Ponadto udowodniono, że istnieją modele dyskryminacyjne różniące się zestawem zmiennych oraz współczynnikami wagowymi, które wykazują zbliżone skuteczności predykcyjne. The purpose of this paper is to answer the question about the validity of mechanical transfer of the Alt- man model to Polish economy and to check if among the tested models there is a model with the highest efficiency and best outcomes for the used comparative methods for each type of enterprise (manufactur- ing, trading, service. Thirteen tested models were compared using the classification matrix, odds ratio, CAP concentration curve and Gini accuracy index, which are efficiency evaluation methods, as well as using the Brier index, which is a method of evaluating models

  13. Copper interactions in TlCu7S4 and TlCu7Se4

    International Nuclear Information System (INIS)

    Noren, L.; Delaplane, R.G.; Berger, R.

    1999-01-01

    Complete text of publication follows. The copper chalcogenides ACu 7 S 4 (A=NH 4 + , Tl + , Rb + ) are quasi-one-dimensional metals at ambient and higher temperatures which is due to the high mobility of copper in these structures. TlCu 7 S 4 and TlCu 7 Se 4 are isostructural compounds, space group I4/m, which can be described on the basis of a TlX 8 cube with two different Cu sites, Cu(1) and Cu(2). Cu(2)-Cu(2) zigzag chains run along the c axis with only 3/4 occupation of the Cu(2) sites. However, these two compounds differ in behaviour on cooling. The sulphide shows a polymorphic first-order transition to the CsAg 7 S 4 type (P4/n) owing to ordering of the vacancies in the Cu(2)-Cu(2) chains. In order to study the nature of the Cu(2) order/disorder in the two title compounds, a series of neutron diffraction measurements (both Bragg and diffuse scattering) were made at several temperatures from 40 to 713 K on the instrument SLAD at Studsvik. The structure at each temperature was modelled using RMC techniques. The resulting configuration show that as the temperature increases, there is a marked increase in the mobility of the Cu atoms in the Cu(2)-Cu(2) chains for TlCu 7 S 4 but not for TlCu 7 Se 4 . This is due to the initial difference in the Cu(2)-Cu(2) distances, only 2.2A for the thiocuprate, but 2.7A in the selenocuprate which explains the relative ease for Cu(2) ordering in the latter case. (author)

  14. A ciência e a tecnologia para os estudantes brasileiros : percepções

    OpenAIRE

    da Cunha, Marcia Borin

    2013-01-01

    Nos anos de 2010 e 2011 realizamos uma pesquisa nacional para verificar as percepções dos estudantes brasileiros sobre temas relacionados à ciência e tecnologia. Esta investigação buscou averiguar como os jovens em idade escolar (Ensino Médio) percebem a ciência e a tecnologia em suas vidas, considerando-se que estas percepções têm influencia na formação dos conceitos científicos escolares e na forma como os jovens relacionam-se com a ciência (Teoria Sociocultural de Vygotsky). Os resultados ...

  15. Analyzing nitrogen concentration using carrier illumination (CI) technology for DPN ultra-thin gate oxide

    International Nuclear Information System (INIS)

    Li, W.S.; Wu, Bill; Fan, Aki; Kuo, C.W.; Segovia, M.; Kek, H.A.

    2005-01-01

    Nitrogen concentration in the gate oxide plays a key role for 90 nm and below ULSI technology. Techniques like secondary ionization mass spectroscopy (SIMS) and X-ray photoelectron spectroscopy (XPS) are commonly used for understanding N concentration. This paper describes the application of the carrier illuminationTM (CI) technique to measure the nitrogen concentration in ultra-thin gate oxides. A set of ultra-thin gate oxide wafers with different DPN (decoupled plasma nitridation) treatment conditions were measured using the CI technique. The CI signal has excellent correlation with the N concentration as measured by XPS

  16. Scyntygrafia kości w diagnostyce reumatoidalnego zapalenia stawów

    Directory of Open Access Journals (Sweden)

    Witold Tłustochowicz

    2010-04-01

    Full Text Available Celem pracy była ocena przydatności trójfazowej dynamicznejscyntygrafii kości w diagnostyce reumatoidalnego zapalenia stawów.Badaniem objęto 39 chorych hospitalizowanych i diagnozowanychz powodu dolegliwości stawowych. Przeprowadzono diagnostykęobejmującą: badanie podmiotowe, przedmiotowe, badania laboratoryjneoraz obrazowe, w tym trójfazową scyntygrafię kości z użyciemtechnetu 99m. Scyntygraficzne cechy zapalenia stawówstwierdzano, gdy obserwowano wzmożone gromadzenie znacznikawe wszystkich trzech fazach badania.Po ukończeniu diagnostyki rozpoznano u 13 chorych wczesne reumatoidalnezapalenie stawów, u 4 reumatoidalne zapalenie stawów(łącznie 17 pacjentów, a u 1 niezróżnicowane zapalenie stawów.Scyntygrafia kości wykazała cechy zapalenia stawów u 13spośród nich (72,2%, u 4 osób (22,2% wzmożone gromadzeniestwierdzono tylko w fazie statycznej, a u 1 pacjenta (5,6% uzyskanoprawidłowy wynik badania. U 21 chorych wykluczono chorobęzapalną stawów (u 19 rozpoznano fibromialgię, u 2 chorobęzwyrodnieniową. W grupie bez zapalenia stawów u 14 pacjentów(66,6% nie stwierdzono istotnych nieprawidłowości w obraziescyntygraficznym, u 6 (28,6% występowało wzmożone gromadzenieznacznika w badaniu statycznym, a u 1 chorego (4,8% opisanoscyntygraficzne cechy zapalenia stawów.Wbadanej grupie czułość scyntygrafii dynamicznej kości w wykrywaniuzapalenia stawów wynosiła 72,2% (95% CI: 57,5–76,8, a swoistość 95,2% (95% CI: 82,8–99,1. Dodatni wynik badaniadynamicznego wskazuje z dużym prawdopodobieństwem naobecność zapalenia stawów [PPV 92,9% (95% CI: 74,2–98,7].Mniej wiarygodny był ujemny wynik badania [NPV 80% (95% CI:69,5–83,3]. Wyniki niniejszej pracy wskazują, że trójfazowa scyntygrafia dynamicznakości może mieć zastosowanie w diagnostyce reumatoidalnegozapalenia stawów.

  17. An Experimental Research on the pCI Rule and Causal Judgment (in Chinese)

    OpenAIRE

    Shao, Z. F.; Wang, J.

    2005-01-01

    This research examined the precision of the pCI rule through three experiments. The results show that first , the tendency of the subjects’ casual judgments was basically similar to the pCI rule. But (a + d) / n predicted human’s casual judgments were even better; second, the increase of subjects’ casual judgments was milder than the pCI rule, and the subjects needed time to construct their own way of judging relationship; finally, different people had different ways of causal judgments, and ...

  18. Quantitative detection of RO2 radicals and other products from cyclohexene ozonolysis with ammonium-CI3-TOF and acetate-CI-API-TOF

    Science.gov (United States)

    Hansel, A.; Scholz, W.; Mentler, B.; Fischer, L.; Berndt, T.

    2017-12-01

    The performance of the novel ammonium-CI3-TOF utilizing NH4+ adduct ion chemistry to measure quantitatively first generation oxidized product molecules (OMs) as well as highly oxidized organic molecules (HOMs) was investigated for the first time. The gas-phase ozonolysis of cyclohexene served as a test system in order to evaluate the capability of the detection systems. Experiments have been carried out in the TROPOS free-jet flow system at close to atmospheric conditions. Product ion signals were simultaneously observed by the ammonium-CI3-TOF and the acetate-CI-API-TOF. Both instruments are in remarkable good agreement within a factor of two for HOMs. For OMs not containing an OOH group the acetate technique can considerably underestimate OM concentrations by 2-3 orders of magnitude. First steps of cyclohexene ozonolysis generate ten different (m/z product peaks) main products comprising 92% of observed OMs. The remaining 8% are distributed over several (m/z peaks) minor products that can be attributed to HOMs, predominately to highly oxidized RO2 radicals. Summing up, observed ammonium-CI3-TOF products yield 4.9 x 109 molecules cm-³ in excellent agreement with the amount of reacted cyclohexene of 5.0 x 109 molecules cm-³ for reactant concentrations of [O3] = 2.25 x 1012 molecules cm-³ and [cyclohexene] = 2.0 x 1012 molecules cm-³ and a reaction time of 7.9 s. NH4+ adduct ion chemistry based CIMS techniques offer a unique opportunity for complete detection of the whole product distribution, and consequently, for a much better understanding of atmospheric oxidation processes.

  19. Report on the effectiveness of flocculation for removal of 239Pu at concentrations of 1 pCi/L and 0.1 pCi/L

    International Nuclear Information System (INIS)

    Triay, I.R.; Bayhurst, G.K.; Mitchell, A.J.; Cisneros, M.R.; Efurd, D.W.; Roensch, F.R.; Rokop, D.J.; Aguilar, R.D.; Attrep, M.; Nuttall, H.E.

    1993-01-01

    The objective of this work is to assess the effectiveness of flocculation for the removal of Pu from Rocky Flats Plant (RFP) pond waters spiked with 239 Pu at the 1.0 and 0.1 pCi/L level. The flocculation treatment procedure is described in detail. Results are presented for treatment studies for the removal of Pu from C-2 pond water spiked with 239 Pu and from distilled water spiked with 239 Pu

  20. Random comparison study of the clinical response to 153Sm-EDTMP 1.0 mCi/kg and 1.5 mCi/kg

    International Nuclear Information System (INIS)

    Pan, Z.; Zhu, S.

    2001-01-01

    Sixty-seven patient with painful bone metastases were randomized to two groups. Group 1 (n=34) received 1.0 mCi/kg of 153 Sm-EDTMP and group II (n=33) received 1.5 mCi/kg. All of them met inclusion criteria and there was no significantly difference between the basic conditions of two groups. After receiving 153 Sm-EDTMP intravenously, all patients were kept in close follow-up weekly with blood counting, physician visiting and collecting patient's self-filling-in diary including pain score, Karnofsky performance scale and analgesic consumption. The follow-up duration was six weeks. The final overall condition assessed by physician were graded into no change (including worse), slight relief, significant relief and complete relief. Only significant relief and complete relief were considered as effectiveness for pain relief. Haematological toxicity grade was evaluated based on the nadir of WBC ad PLT counts. The results indicated that the higher dosage group had a higher effectiveness rate (75.76%) compared to the lower dosage group (67.65%), but without statistic significance (x 2 =0.5365, 0.25 153 Sm-EDTMP could be used for those patients with better haematological function and 1.0 mCi/kg used for those patients with poorer haematological function. (author)

  1. The Ciona intestinalis immune-related galectin genes (CiLgals-a and CiLgals-b) are expressed by the gastric epithelium.

    Science.gov (United States)

    Parrinello, Daniela; Sanfratello, Maria Antonietta; Vizzini, Aiti; Testasecca, Lelia; Parrinello, Nicolò; Cammarata, Matteo

    2017-03-01

    The transcription of two Ciona intestinalis galectin genes (CiLgals-a and CiLgals-b) is uparegulated by LPS in the pharynxis (hemocytes, vessel epithelium, endostilar zones) which is retained the main organ of the immunity. In this ascidian, for the first time we show, by immunohistochemistry and in situ hybridization methods, that these two immune-related genes are expressed in the gastric epithelium of naïve ascidians, whereas the galectins appear to be only contained in the intestine columnar epithelium. In addition, according to previous results on the pharynx, the genes are also expressed and galectins produced by hemocytes scattered in the connective tissue surrounding the gut. The genes expression and galectin localization in several tissues, including the previous findings on the transcription upregulation, the constitutive expression of these genes by endostylar zones and by the gastric epithelium suggest a potential multifunctional role of these galectins. In this respect, it is of interest to define where the CiLgals are normally found as related to the tissue functions. Such an approach should be a starting point for further investigations. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Cyclotron production of Cu-61

    Czech Academy of Sciences Publication Activity Database

    Lebeda, Ondřej; Ráliš, Jan; Seifert, Daniel

    2013-01-01

    Roč. 40, 2 Supplement (2013), S323-S323 ISSN 1619-7070. [Annual Congress of the European Association of Nuclear Medicine (EANM). 19.10.2013-23.10.2013, Lyon] R&D Projects: GA TA ČR TA02010797 Institutional support: RVO:61389005 Keywords : cyclotron U-120M * PET * Cu-61 Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders

  3. Synthesis of 3,5-diisopropyl[carboxy-14C]salicylic acid and its 67Cu complex

    International Nuclear Information System (INIS)

    Chidambaram, M.V.; Epperson, C.E.; Williams, S.; Gray, R.A.; Sorenson, J.R.J.

    1991-01-01

    The synthesis of 3,5-diisopropyl[carboxy- 14 C]salicylic acid was achieved via Kolbe-Schmitt carboxylation of potassium 2,4-di-isopropylphenolate. The yield of this acid was 81% based upon the weight of the product and 93% based upon radioactivity incorporated into the labeled acid which contains 98% 14 C in the carboxyl group (specific activity = 5.1 μCi/mg). The labeled acid was characterized by ultraviolet spectrophotometry and purity established by thin-layer chromatography, autoradiography, and liquid scintillation counting. A 90% yield of the double labeled 14 C, 67 Cu-complex (specific activity = 4.6 μCi 67 Cu/mg) was obtained using conditions developed with non-radioactive reactants. The presence of 67 Cu in this complex was established using γ-ray emission spectrophometry. (author)

  4. Cu diffusion as an alternative method for nanopatterned CuTCNQ film growth

    International Nuclear Information System (INIS)

    Capitán, M J; Álvarez, J; Miranda, R; Navío, C

    2016-01-01

    In this paper we show by means of ‘in situ’ x-ray diffraction studies that CuTCNQ formation from Cu(solid)–TCNQ(solid tetracyanoquinodimethane) goes through Cu diffusion at room temperature. The film quality depends on the TCNQ evaporation rate. At low evaporation rate we get a single phase-I CuTCNQ film very well crystallized and well oriented. The film has a CuTCNQ(0 2 0) orientation. The film is formed by CuTCNQ nanorods of a very homogeneous size. The film homogeneity has also been seen by atomic force microscopy (AFM). The electronic properties of the film have been measured by x-ray photoelectron spectroscopy (XPS) and ultra-violet photoelectron spectroscopy (UPS). Thus, the Cu-diffusion method has arisen as a very simple, clean and efficient method to grow localized CuTCNQ nanorods on Cu, opening up new insights for technological applications. (paper)

  5. A concepção de ciência de Popper e o ensino de ciências Popper's conception of science and the teaching of sciences

    Directory of Open Access Journals (Sweden)

    Carlos Alberto Rufatto

    2009-01-01

    Full Text Available Procurou-se identificar as consequências mais importantes da concepção de ciência de Popper, que deu origem a um rico debate na Filosofia das Ciências, para o Ensino de Ciências. O acompanhamento deste debate permite perceber a riqueza do processo científico, reconhecendo as contribuições daqueles que debateram com Popper; bem como a importância dos aspectos da ciência que Popper valorizou e procurou preservar. As críticas e os debates em torno das abordagens de mudança conceitual contribuíram para a percepção da riqueza e complexidade desse processo. Quando considerados os objetivos institucionais das escolas e as expectativas sociais em torno da compreensão adequada e da procura de superação dos paradigmas vigentes a manutenção de certos aspectos, inerentes ao processo de mudança conceitual, pode se mostrar relevante. Neste sentido, a obra de Popper pode oferecer importante apoio para valorizar aspectos racionais que poderiam presidir o processo de aprender Ciências.This work aimed at identifying the most important consequences of Popper's conception of science education, which started a fertile debate in the Philosophy of Science. By following this debate, it is possible to notice the richness of the cientific process, recognizing the contributions brought by those who debated with Popper, and the importance of aspects of science that Popper valued and attempted to preserve. The criticism and the debate over the approaches towards conceptual change contributed to the perception of the wide extent and complexity of this process. However, the maintenance of certain aspects, inherent in the process of conceptual change, may be relevant when the institutional objectives of the schools and the social expectations over the appropriate understanding and over the attempt to overcome current paradigms are considered. In this way, Popper's work may offer important support to valuing rational aspects that could inform the process

  6. Growth and characterisation of potentiostatically electrodeposited Cu2O and Cu thin films

    International Nuclear Information System (INIS)

    Wijesundera, R.P.; Hidaka, M.; Koga, K.; Sakai, M.; Siripala, W.

    2006-01-01

    Cuprous oxide and copper thin films were potentiostatically electrodeposited in an acetate bath. Voltammetric curves were used to investigate the growth parameters; deposition potential, pH and temperature of the bath. Deposition potential dependency on the structural, morphological, optical and electronic properties of the films were investigated by the X-ray diffraction measurements, scanning electron micrographs, absorption measurements and dark and light current-voltage characterisations. It was observed that single phase polycrystalline Cu 2 O can be deposited from 0 to - 300 mV Vs saturated calomel electrode (SCE) and co-deposition of Cu and Cu 2 O starts at - 400 mV Vs SCE. Further increase in deposition potential from - 700 mV Vs SCE produces single phase Cu thin films. Single phase polycrystalline Cu 2 O thin films with cubic grains of 1-2 μm can be possible within the very narrow potential domain around - 200 mV Vs SCE. Enhanced photoresponse in a photoelectrochemical cell is produced by the Cu 2 O thin film prepared at - 400 mV Vs SCE, where Cu is co-deposited with Cu 2 O with random distribution of Cu spheres on the Cu 2 O surface. This study reveals that a single deposition bath can be used to deposit both Cu and Cu 2 O separately and an admixture of Cu-Cu 2 O by controlling the deposition parameters

  7. New Production Routes for Medical Isotopes 64Cu and 67Cu Using Accelerator Neutrons

    Science.gov (United States)

    Kin, Tadahiro; Nagai, Yasuki; Iwamoto, Nobuyuki; Minato, Futoshi; Iwamoto, Osamu; Hatsukawa, Yuichi; Segawa, Mariko; Harada, Hideo; Konno, Chikara; Ochiai, Kentaro; Takakura, Kosuke

    2013-03-01

    We have measured the activation cross sections producing 64Cu and 67Cu, promising medical radioisotopes for molecular imaging and radioimmunotherapy, by bombarding a natural zinc sample with 14 MeV neutrons. We estimated the production yields of 64Cu and 67Cu by fast neutrons from \\text{natC(d,n) with 40 MeV 5 mA deuterons. We used the present result together with the evaluated cross section of Zn isotopes. The calculated 64Cu yield is 1.8 TBq (175 g 64Zn) for 12 h of irradiation; the yields of 67Cu by 67Zn(n,p)67Cu and 68Zn(n,x)67Cu were 249 GBq (184 g 67Zn) and 287 GBq (186 g 68Zn) at the end of 2 days of irradiation, respectively. From the results, we proposed a new route to produce 67Cu with very little radionuclide impurity via the 68Zn(n,x)67Cu reaction, and showed the 64Zn(n,p)64Cu reaction to be a promising route to produce 64Cu. Both 67Cu and 64Cu are noted to be produced using fast neutrons.

  8. Women in the United States Marine Corps CI/HUMINT Community

    National Research Council Canada - National Science Library

    Reese, Jackson L

    2008-01-01

    The purpose of the researchers Masters of Military Arts and Science thesis is to explore the possibility of including women in the Marine Corps CI/HUMINT community without diminishing the overall unit...

  9. Communication: CDFT-CI couplings can be unreliable when there is fractional charge transfer

    International Nuclear Information System (INIS)

    Mavros, Michael G.; Van Voorhis, Troy

    2015-01-01

    Constrained density functional theory with configuration interaction (CDFT-CI) is a useful, low-cost tool for the computational prediction of electronic couplings between pseudo-diabatic constrained electronic states. Such couplings are of paramount importance in electron transfer theory and transition state theory, among other areas of chemistry. Unfortunately, CDFT-CI occasionally fails significantly, predicting a coupling that does not decay exponentially with distance and/or overestimating the expected coupling by an order of magnitude or more. In this communication, we show that the eigenvalues of the difference density matrix between the two constrained states can be used as an a priori metric to determine when CDFT-CI are likely to be reliable: when the eigenvalues are near 0 or ±1, transfer of a whole electron is occurring, and CDFT-CI can be trusted. We demonstrate the utility of this metric with several illustrative examples

  10. PAT: From Western solid dosage forms to Chinese materia medica preparations using NIR-CI.

    Science.gov (United States)

    Zhou, Luwei; Xu, Manfei; Wu, Zhisheng; Shi, Xinyuan; Qiao, Yanjiang

    2016-01-01

    Near-infrared chemical imaging (NIR-CI) is an emerging technology that combines traditional near-infrared spectroscopy with chemical imaging. Therefore, NIR-CI can extract spectral information from pharmaceutical products and simultaneously visualize the spatial distribution of chemical components. The rapid and non-destructive features of NIR-CI make it an attractive process analytical technology (PAT) for identifying and monitoring critical control parameters during the pharmaceutical manufacturing process. This review mainly focuses on the pharmaceutical applications of NIR-CI in each unit operation during the manufacturing processes, from the Western solid dosage forms to the Chinese materia medica preparations. Finally, future applications of chemical imaging in the pharmaceutical industry are discussed. Copyright © 2015 John Wiley & Sons, Ltd.

  11. Communication: CDFT-CI couplings can be unreliable when there is fractional charge transfer

    Energy Technology Data Exchange (ETDEWEB)

    Mavros, Michael G.; Van Voorhis, Troy, E-mail: tvan@mit.edu [Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, Massachusetts 02139 (United States)

    2015-12-21

    Constrained density functional theory with configuration interaction (CDFT-CI) is a useful, low-cost tool for the computational prediction of electronic couplings between pseudo-diabatic constrained electronic states. Such couplings are of paramount importance in electron transfer theory and transition state theory, among other areas of chemistry. Unfortunately, CDFT-CI occasionally fails significantly, predicting a coupling that does not decay exponentially with distance and/or overestimating the expected coupling by an order of magnitude or more. In this communication, we show that the eigenvalues of the difference density matrix between the two constrained states can be used as an a priori metric to determine when CDFT-CI are likely to be reliable: when the eigenvalues are near 0 or ±1, transfer of a whole electron is occurring, and CDFT-CI can be trusted. We demonstrate the utility of this metric with several illustrative examples.

  12. Communication: CDFT-CI couplings can be unreliable when there is fractional charge transfer

    Science.gov (United States)

    Mavros, Michael G.; Van Voorhis, Troy

    2015-12-01

    Constrained density functional theory with configuration interaction (CDFT-CI) is a useful, low-cost tool for the computational prediction of electronic couplings between pseudo-diabatic constrained electronic states. Such couplings are of paramount importance in electron transfer theory and transition state theory, among other areas of chemistry. Unfortunately, CDFT-CI occasionally fails significantly, predicting a coupling that does not decay exponentially with distance and/or overestimating the expected coupling by an order of magnitude or more. In this communication, we show that the eigenvalues of the difference density matrix between the two constrained states can be used as an a priori metric to determine when CDFT-CI are likely to be reliable: when the eigenvalues are near 0 or ±1, transfer of a whole electron is occurring, and CDFT-CI can be trusted. We demonstrate the utility of this metric with several illustrative examples.

  13. Preparation and preliminary studies of [64Cu]-antiMUC-1 for breast cancer targeting

    Directory of Open Access Journals (Sweden)

    Behrouz Alirezapour

    2016-06-01

    Full Text Available PR81 is a monoclonal antibody that binds with high affinity to MUC1 that over expressed on breast tumors. PR81 is considered a suitable targeting molecule that was radiolabeled using Cu-64 for positron imaging studies. The monoclonal antibody was conjugated with DOTA moiety and after purification was evaluated for radiochemical purity, immunoreactivity, cell toxicity and structure integrity as well as biodistribution study in normal rats. The radiolabeled antibody prepared with acceptable radiochemical purity (> 93.2 ± 0.6 %, ITLC; specific activity; 4.6 µCi/µg, protein structure integration, significant cytotoxicity and significant immunoreactivity retention was assessed by radioimmunoassay (RIA. Animal biodistribution of the 64Cu-DOTA-PR81 was consistent with other radiolabeled antibodies. The results showed that 64Cu-DOTA-PR81 may be considered for tumor imaging for ultimate diagnosis and follow-up of MUC1 expression in oncology.

  14. Luz, arte, ciência... ação! Lights, art, science - action!

    Directory of Open Access Journals (Sweden)

    Thelma Lopes

    2005-01-01

    Full Text Available O principal objetivo do presente artigo é refletir sobre as principais interações entre teatro, ciência e tecnologia, ao longo da história do teatro, e discutir, a partir de nossa experiência no Ciência em Cena, espaço integrante do Museu da Vida, de que modos essas interações podem estar presentes no cotidiano de um museu de ciências. A palavra 'ciência' deve ser compreendida aqui em sentido amplo, englobando não apenas as ciências naturais, mas também as ciências humanas, assim como a palavra 'tecnologia' deve ser associada à ciência aplicada. Arte e ciência serão entendidas como processos criativos, como formas de representação do mundo e expressão do conhecimento humano.The article offers some reflections on the main interactions between theater, science, and technology down through the history of theater. Based on our experience at "Science in the Spotlight", part of the Casa de Oswaldo Cruz's Museum of Life, we discuss how these interactions can be part of a science museum's daily activities. We use the word 'science' in its broad sense, encompassing not only the natural but human sciences as well; likewise, we use the word 'technology' as it relates to applied science. Art and science are understood here as creative processes, as ways of representing the world and expressing human knowledge.

  15. Bimetallic AgCu/Cu2O hybrid for the synergetic adsorption of iodide from solution.

    Science.gov (United States)

    Mao, Ping; Liu, Ying; Liu, Xiaodong; Wang, Yuechan; Liang, Jie; Zhou, Qihang; Dai, Yuexuan; Jiao, Yan; Chen, Shouwen; Yang, Yi

    2017-08-01

    To further improve the capacity of Cu 2 O to absorb I - anions from solution, and to understand the difference between the adsorption mechanisms of Ag/Cu 2 O and Cu/Cu 2 O adsorbents, bimetallic AgCu was doped into Cu 2 O through a facile solvothermal route. Samples were characterized and employed to adsorb I - anions under different experimental conditions. The results show that the Cu content can be tuned by adding different volumes of Ag sols. After doping bimetallic AgCu, the adsorption capacity of the samples can be increased from 0.02 mmol g -1 to 0.52 mmol g -1 . Moreover, the optimal adsorption is reached within only 240 min. Meanwhile, the difference between the adsorption mechanisms of Ag/Cu 2 O and Cu/Cu 2 O adsorbents was verified, and the cooperative adsorption mechanism of the AgCu/Cu 2 O hybrid was proposed and verified. In addition, the AgCu/Cu 2 O hybrid showed excellent selectivity, e.g., its adsorption efficiencies are 85.1%, 81.9%, 85.9% and 85.7% in the presence of the Cl - , CO 3 2- , SO 4 2- and NO 3 - competitive anions, respectively. Furthermore, the AgCu/Cu 2 O hybrid can worked well in other harsh environments (e.g., acidic, alkaline and seawater environments). Therefore, this study is expected to promote the development of Cu 2 O into a highly efficient adsorbent for the removal of iodide from solution. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Semiempirical UNO-CAS and UNO-CI: method and applications in nanoelectronics.

    Science.gov (United States)

    Dral, Pavlo O; Clark, Timothy

    2011-10-20

    Unrestricted Natural Orbital-Complete Active Space Configuration Interaction, abbreviated as UNO-CAS, has been implemented for NDDO-based semiempirical molecular-orbital (MO) theory. A computationally more economic technique, UNO-CIS, in which we use a configuration interaction (CI) calculation with only single excitations (CIS) to calculate excited states, has also been implemented and tested. The class of techniques in which unrestricted natural orbitals (UNOs) are used as the reference for CI calculations is denoted UNO-CI. Semiempirical UNO-CI gives good results for the optical band gaps of organic semiconductors such as polyynes and polyacenes, which are promising materials for nanoelectronics. The results of these semiempirical UNO-CI techniques are generally in better agreement with experiment than those obtained with the corresponding conventional semiempirical CI methods and comparable to or better than those obtained with far more computationally expensive methods such as time-dependent density-functional theory. We also show that symmetry breaking in semiempirical UHF calculations is very useful for predicting the diradical character of organic compounds in the singlet spin state.

  17. Music Perception and Appraisal: Cochlear Implant Users and Simulated CI Listening

    Science.gov (United States)

    Wright, Rose; Uchanski, Rosalie M.

    2012-01-01

    Background The inability to hear music well may contribute to decreased quality of life for cochlear implant (CI) users. Researchers have reported recently on the generally poor ability of CI users’ to perceive music, and a few researchers have reported on the enjoyment of music by CI users. However, the relation between music perception skills and music enjoyment is much less explored. Only one study has attempted to predict CI users’ enjoyment and perception of music from the users’ demographic variables and other perceptual skills (Gfeller et al., 2008). Gfeller’s results yielded different predictive relationships for music perception and music enjoyment, and the relationships were weak, at best. Purpose The first goal of this study is to clarify the nature and relationship between music perception skills and musical enjoyment for CI users, by employing a battery of music tests. The second goal is to determine whether normal hearing (NH) subjects, listening with a CI-simulation, can be used as a model to represent actual CI users for either music enjoyment ratings or music perception tasks. Research Design A prospective, cross-sectional observational study. Original music stimuli (unprocessed) were presented to CI users, and music stimuli processed with CI-simulation software were presented to twenty NH listeners (CIsim). As a control, original music stimuli were also presented to five other NH listeners. All listeners appraised twenty-four musical excerpts, performed music perception tests, and filled out a musical background questionnaire. Music perception tests were the Appreciation of Music in Cochlear Implantees (AMICI), Montreal Battery for Evaluation of Amusia (MBEA), Melodic Contour Identification (MCI), and University of Washington Clinical Assessment of Music Perception (UW-CAMP). Study Sample Twenty-five NH adults (22 – 56 years old), recruited from the local and research communities, participated in the study. Ten adult CI users (46 – 80

  18. Rak piersi w ciąży - odmienności procesu diagnostyki i leczenia = Breast cancer during pregnancy - differences in diagnostic and treatment procedures

    Directory of Open Access Journals (Sweden)

    Magdalena Sowa

    2016-09-01

    85 -801 Bydgoszcz e – mail: magdalena.sowa@cm.umk.pl         Streszczenie Wprowadzenie: Rak piersi w ciąży jest rozpoznawany stosunkowo rzadko. W ostatnich dziesięciu latach w Europie można zauważyć wyraźną tendencję do odraczania macierzyństwa wśród młodych kobiet. Obecnie średnia wieku kobiet rodzących pierwsze dziecko wynosi 30 lat. Jednym z czynników ryzyka zachorowania na raka piersi jest wiek. Z uwagi na fakt, iż kobiety coraz później decydują się na macierzyństwo, a średnia wieku występowania raka piersi się obniża,  z tą szczególną sytuacją kliniczną lekarzom jak i kobietom przyjdzie się zmagać coraz częściej.  Cel pracy:Celem pracy była próba przybliżenia odmienności procesu diagnostyki i leczenia raka gruczołu piersiowego rozpoznanego w ciąży. Rozwinięcie:Z danych epidemiologicznych wynika, iż rak piersi jest najczęściej występującym nowotworem u kobiet ciężarnych.Szczególnie niebezpiecznym jest fakt, iż zmiany fizjologicznie zachodzące w organizmie kobiety już od pierwszych tygodni ciąży, mogą maskować pojawienie się guza i znacznie opóźniać wdrożenie procesu diagnostyki.  Choroba nowotworowa rozpoznana w czasie trwania ciąży jest zawsze dramatyczną i ogromnie stresującą sytuacją dla kobiety i jej najbliższych, dlatego proces diagnostyki i leczenia jest silnie zindywidualizowany, zaś maksymalny efekt terapeutyczny z jednoczesną ochroną nienarodzonego dziecka stanowi priorytet działań. Podsumowanie:Decyzje terapeutyczne podejmowane są po uwzględnieniu ogólnego stanu zdrowia pacjentki, stopnia zaawansowania klinicznego nowotworu, wieku ciążowego oraz postulatów samej pacjentki i jej najbliższych.W niniejszej pracy, posługując się metodą analizy piśmiennictwa szczegółowo omówiono odmienności w procesie diagnostyki i leczenia raka piersi u kobiet ciężarnych.   Słowa kluczowe: rak piersi, ciąża, diagnostyka, leczenie   Breast cancer during pregnancy

  19. IR and TPD studies of the interaction of alkenes with Cu + sites in CuNaY and CuNaX zeolites of various Cu content. The heterogeneity of Cu + sites

    Science.gov (United States)

    Datka, J.; Kukulska-Zajaç, E.; Kozyra, P.

    2006-08-01

    Cu + ions in zeolites activate organic molecules containing π electrons by π back donation, which results in a distinct weakening of multiple bonds. In this study, we followed the activation of alkenes (ethene and propene) by Cu + ions in CuY and CuX zeolites of various Cu content. We also studied the strength of bonding of alkenes to Cu + ions. IR studies have shown that there are two kinds of Cu + sites of various electron donor properties. We suppose that they could be attributed to the presence of Cu + ions of various number of oxygen atoms surrounding the cation. IR studies have shown that Cu ions introduced into Y and X zeolites in the first-order (at low Cu content) form Cu + ions of stronger electron donor properties (i.e. activate alkenes to larger extend) than Cu ions introduced in the next order (at higher Cu content). IR and TPD studies of alkenes desorption evidenced that Cu + ions of stronger electron donor properties bond alkenes stronger than less electron donor ones. It suggests that π back donation has more important contribution to the strength of bonding alkenes to cation than π donation.

  20. Ciąża i poród u chorych na stwardnienie rozsiane

    Directory of Open Access Journals (Sweden)

    Małgorzata Czernichowska-Kotiuszko

    2014-04-01

    Full Text Available Stwardnienie rozsiane (łac. sclerosis multiplex, SM jest główną przyczyną niepełnosprawności u młodych dorosłych i jak większość chorób autoimmunologicznych częściej dotyczy kobiet. Wpływ ciąży na przebieg SM wzbudza zainteresowanie od wielu lat, a w ostatnim okresie stanowi temat badań wieloośrodkowych. Ciąża to zwykle okres bardzo dobrego samopoczucia chorych, najczęściej bez rzutów. Wynika to ze zmiany reaktywności immunologicznej na korzyść reakcji przeciwzapalnych związanych z limfocytami Th2 i cytokinami antyzapalnymi (interleukina 4, 5, 6, 10, TGF-β. Po porodzie zmienia się reaktywność immunologiczna i aktywność choroby wzrasta. Większość badań nie wykazała ogólnego negatywnego wpływu ciąży na niesprawność długoterminową związaną z SM; stwardnienie rozsiane nie ma negatywnego wpływu na przebieg ciąży, porodu i stan dziecka, dlatego chore kobiety mogą planować potomstwo. Choroba nie zwiększa ryzyka powikłań w ciąży i podczas porodu ani wad wrodzonych u dziecka w porównaniu z populacją ogólną. Jednakże każda terapia immunomodulująca jest przeciwwskazana w ciąży. Jeśli pacjentka decyduje się na dziecko, powinna przerwać leczenie; zaleca się również przerwę od leków przed zajściem w ciążę. W pracy podsumowano dostępne informacje na temat klinicznych problemów dotyczących ciąży i porodu u chorych na SM oraz oceniono zagrożenia dla dziecka związane z podawaniem leków.

  1. Somatyczna determinacja płciowa w nadwadze i otyłości

    Directory of Open Access Journals (Sweden)

    Michał Zych

    2015-12-01

    Full Text Available Wstęp: Somatyczne wielkości, takie jak masa (Mc i wysokość ciała (Wc, są używane do wyliczania wskaźników wagowo--wzrostowych i stanowią pomoc w diagnozowaniu nadwagi i otyłości. Cel pracy: Celem pracy jest ocena nadwagi i otyłości kobiet i mężczyzn w świetle prostych wskaźników somatycznych. Materiał i metody: W prezentowanej pracy porównano wskaźniki somatyczne 179 kobiet i 181 mężczyzn z nadwagą i otyłością. Do oceny somatycznej badanych użyto: Mc, Wc oraz wskaźników wagowo-wzrostowych: Queteleta, BMI, Rohrera i smukłości. Wyniki: W badanych grupach kobiety i mężczyźni byli w zbliżonym wieku, grupy te różniły się istotnie omawianymi wskaźnikami somatycznymi. Porównania podgrup kobiet i mężczyzn o podobnej wielkości BMI wykazały, że są oni w podobnym wieku i różnią się w zakresie Mc, Wc oraz wskaźników: Queteleta, Rohrera i smukłości. Natomiast między podgrupami kobiet, jak i między podgrupami mężczyzn, występowały istotne różnice wiekowe, Mc oraz wskaźników: BMI, Queteleta, Rohrera i smukłości. Wnioski: Powyższe dane wskazują, że pomimo braku różnic wieku między badanymi kobietami i mężczyznami z podobnym lub różnym BMI istnieje wyraźna somatyczna determinacja płciowa, natomiast w obrębie tej samej płci, różniącej się wskaźnikiem BMI, wiek badanych jest czynnikiem determinacji somatycznej. Wykazano też, że badane wskaźniki somatyczne mają różną moc predykcyjną w zakresie oceny nadwagi i stopnia otyłości badanych kobiet i mężczyzn.

  2. O Museu de Ciência: espaço da história da ciência The Science Museum: a place of history of science

    Directory of Open Access Journals (Sweden)

    Maria Esther Alvarez Valente

    2005-04-01

    Full Text Available O artigo apresenta uma reflexão sobre o Museu de Ciência a partir de sua dimensão educativa. O que está em discussão é a abordagem sobre os temas científicos e a exploração dos objetos museológicos apresentados no sentido de facilitar o entendimento público da Ciência. Principalmente a partir da segunda metada do século XX, a comunicação nestes espaços, voltada para o público leigo, opta por estratégias que priorizam, quase exclusivamente, a apresentação de fenômenos científicos, construindo desta maneira saberes a-históricos. Com base na perspectiva da História da Ciência o esforço, hoje, é o de ampliar a interpretação dos temas e objetos, revelando a intangibilidade ligada a eles, e que compreendem o ato de criação científico, os processos de conhecimento da ciência e sua relação com o homem e a sociedade. Trata-se de uma abordagem que auxilia os indivíduos a dar significado aos conteúdos científicos.The article is bringsa reflection on the science museum focusinged on its educational dimension. The discussion is about the approach of the interpretation ofn scientific themes and objects, both presented in the museum's exhibitions, in order to promote the public's understanding of science. Starting mainly in the second half of the twentieth century, communication occurred in Science Museums and more precisely in Science Centres, with presentations focused, exclusively on the scientific phenomena. What results is a knowledge without historical foundations. Instead we propose another approach based on the history of science perspective. It opens up the interpretation ofn the intangible aspectsside of the objects as well asand the cold information. It emphasisesis the act of scientificce creation, the process of science knowledge and its relationship with man and society. The new approach will help people give significance to the scientific contents.

  3. Facile synthesis of dendritic Cu by electroless reaction of Cu-Al alloys in multiphase solution

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Ying; Liang, Shuhua, E-mail: liangxaut@gmail.com; Yang, Qing; Wang, Xianhui

    2016-11-30

    Highlights: • Nano- or micro-scale fractal dendritic copper (FDC) was synthesized by electroless immersing of Cu-Al alloys in CuCl{sub 2} + HCl. • FDC size increases with the increase of Al content in Cu-Al alloys immersed in CuCl{sub 2} + HCl solution. • Nanoscale Cu{sub 2}O was found at the edge of FDC. Nanoporous copper (NPC) can also be obtained by using Cu{sub 17}Al{sub 83} alloy. • The potential difference between CuAl{sub 2} and α-Al phase and the replacement reaction in multiphase solution are key factors. - Abstract: Two-dimensional nano- or micro-scale fractal dendritic coppers (FDCs) were synthesized by electroless immersing of Cu-Al alloys in hydrochloric acid solution containing copper chloride without any assistance of template or surfactant. The FDC size increases with the increase of Al content in Cu-Al alloys immersed in CuCl{sub 2} + HCl solution. Compared to Cu{sub 40}Al{sub 60} and Cu{sub 45}Al{sub 55} alloys, the FDC shows hierarchical distribution and homogeneous structures using Cu{sub 17}Al{sub 83} alloy as the starting alloy. The growth direction of the FDC is <110>, and all angles between the trunks and branches are 60°. Nanoscale Cu{sub 2}O was found at the edge of FDC. Interestingly, nanoporous copper (NPC) can also be obtained through Cu{sub 17}Al{sub 83} alloy. Studies showed that the formation of FDC depended on two key factors: the potential difference between CuAl{sub 2} intermetallic and α-Al phase of dual-phase Cu-Al alloys; a replacement reaction that usually occurs in multiphase solution. The electrochemical experiment further proved that the multi-branch dendritic structure is very beneficial to the proton transfer in the process of catalyzing methanol.

  4. Cu-Zr-Ag bulk metallic glasses based on Cu8Zr5 icosahedron

    International Nuclear Information System (INIS)

    Xia Junhai; Qiang Jianbing; Wang Yingmin; Wang Qing; Dong Chuang

    2007-01-01

    Based on the cluster line criterion, the Ag addition into the Cu 8 Zr 5 cluster composition is investigated for the search of ternary Cu-Zr-Ag bulk metallic glasses with high glass forming abilities. Two initial binary compositions Cu 0.618 Zr 0.382 and Cu 0.64 Zr 0.36 are selected. The former one corresponds to a deep eutectic point; it is also the composition of the Cu 8 Zr 5 icosahedron, which is derived from the Cu 8 Zr 3 structure. The latter one, which can be regarded as the Cu 8 Zr 5 cluster plus a glue atom Cu, is the best glass-forming composition in the Cu-Zr binary system. Two composition lines (Cu 0.618 Zr 0.382 ) 1-x Ag x and (Cu 0.64 Zr 0.36 ) 1-x Ag x are thus constructed in the Cu-Zr-Ag system by linking these two compositions with the third constitute Ag. A series of Cu-Zr-Ag bulk metallic glasses are found with 2-8 at.% Ag contents in both composition lines. The optimum composition (Cu 0.618 Zr 0.382 ) 0.92 Ag 0.08 within the searched region with the highest T g /T l = 0.633, is located along the cluster line (Cu 0.618 Zr 0.382 ) 1-x Ag x , where the deep eutectic Cu 0.618 Zr 0.382 exactly corresponds to the dense packing cluster Cu 8 Zr 5 . The alloying mechanism is discussed in the light of atomic size and electron concentration factors

  5. TPD IR studies of CO desorption from zeolites CuY and CuX

    Science.gov (United States)

    Datka, Jerzy; Kozyra, Paweł

    2005-06-01

    The desorption of CO from zeolites CuY and CuX was followed by TPD-IR method. This is a combination of temperature programmed desorption and IR spectroscopy. In this method, the status of activated zeolite (before adsorption), the process of adsorption, and the status of adsorbed molecules can be followed by IR spectroscopy, and the process of desorption (with linear temperature increase) can be followed both by IR spectroscopy and by mass spectrometry. IR spectra have shown two kinds of Cu + sites in both CuY and CuX. Low frequency (l.f.) band (2140 cm -1 in CuY and 2130 cm -1 in CuX) of adsorbed CO represents Cu + sites for which π back donation is stronger and σ donation is weaker whereas high frequency h.f. band (2160 cm -1 in CuY and 2155 cm -1 in CuX) represent Cu + sites for which π back donation is weaker and σ donation is stronger. The TPD-IR experiments evidenced that the Cu + sites represented by l.f. band bond CO more weakly than those represented by h.f. one, indicating that σ donation has more important impact to the strength of Cu +-CO bonding. On the contrary, π back donation has bigger contribution to the activation of adsorbed molecules.

  6. Identyfikacja wielokryterialnego modelu istotności pompowni melioracyjnych na terenie Polski

    Directory of Open Access Journals (Sweden)

    Wojciech Sałabun

    2015-09-01

    Full Text Available Niniejsza praca omawia istotny problem związany z klasyfikacją i właściwym zdefiniowaniem wielkości pompowni melioracyjnych. Podstawowa definicja wielkości jest bardzo szeroka, zatem ze względu na liczbę objaśniających ją parametrów wymaga precyzyjnego uściślenia. W dotychczasowych ocenach rozmiarów pompowni melioracyjnych posługiwano się na ogół wrażeniami osobistymi opartymi na subiektywnym odczuciu, które z kolei jest oparte na nieznanej liczbie parametrów. Pojawiające się przy tym trudności z określeniem przynależności obiektów do danej grupy wielkości wynikały głównie z luk informacyjnych dotyczących właściwej granicy podziału pomiędzy poszczególnymi grupami. W niniejszej pracy, do klasyfikacji i podziału pompowni według ich wielkości zastosowano takie ich parametry jak: moc nominalna pompowni P w kW, wydajność całkowita Q w m3 · s oraz zasięg oddziaływania pompowni Fp w ha, dla 270 losowo wybranych obiektów melioracyjnych w Polsce. Do rozwiązania problemu wykorzystano jedną z wielokryterialnych metod podejmowania decyzji (MCDM, opartą na mechanizmach logiki rozmytej, noszącą nazwę metody obiektów charakterystycznych (COMET.

  7. 40 CFR 60.4210 - What are my compliance requirements if I am a stationary CI internal combustion engine manufacturer?

    Science.gov (United States)

    2010-07-01

    ... I am a stationary CI internal combustion engine manufacturer? 60.4210 Section 60.4210 Protection of... CI internal combustion engine manufacturer? (a) Stationary CI internal combustion engine... certified to the standards in 40 CFR part 1039. (b) Stationary CI internal combustion engine manufacturers...

  8. Analysis of factors affecting the outcome of Graves disease patients treated with two regimens of fixed Iodine-131 doses (10 mCi and 15 mCi)

    International Nuclear Information System (INIS)

    Machado, Ana C.B.; Santos, Roberto B.; Chaves, Fatima R.; Romaldini, Joao H.; Ward, Laura S.

    2005-01-01

    Full text: The use of fixed doses of radioiodine ( 131 I) simplifies the approach to treatment for Graves' disease (GD) patients with potential cost savings. In order to evaluate factors that may affect the outcome of 2 different regimens of 131 I, we prospectively examined 128 patients with overt thyrotoxicosis from GD, as confirmed by suppressed serum TSH, presence of TRAb, increased serum T 3 and FT 4 values. Group 1 comprised 76 patients who received a fixed dose of 10 mCi and Group 2=52 patients who received a fixed dose of 15 mCi. 36 patients did not use any antithyroid drugs and 92 patients used methimazole that was withdrawn at least 5 days before radioiodine administration. Antithyroid drugs treatment was restarted at least 7 days following 131 I therapy when needed. Baseline serum TSH and FT 4 levels were measured at 3, 6, 9 and 12 months after treatment. The groups were similar concerning age, gender, smoke, eye disease, goiter size, serum T 3 , FT 4 , TRAb, anti-Tg and anti-TPO levels as well as 24-hour 131 I or Tec-uptake values and thyroid scan. Clinical outcome was evaluated at the end of 1-year follow-up and cure of hyperthyroidism was defined as clinical and laboratory evidence of either euthyroidism or hypothyroidism in the absence of antithyroid drugs. The cure rate obtained was similar in groups 1 and 2: 73.7% and 80.8%, respectively (p=0.35). Hypothyroidism was diagnosed in 56.5% and 71.15% of the patients from groups 1 and 2, respectively (p=0.13). There was no correlation between clinical features, thyroid uptake, antibodies, serum hormones and outcome. However, logistic regression analysis demonstrated that patients with larger thyroids (weight >60 g) that, consequently, received a lower dose of radioiodine in MBq/g, had 2.4 times less chance to cure (95% Cl=1.18-4.96). The use of fixed doses of radioiodine ( 131 I) simplifies the approach to treatment for Graves' disease (GD) patients with potential cost savings. In order to evaluate

  9. ANALIZA MOŻLIWOŚCI ZASTOSOWANIA ODPADOWEGO PYŁU BAZALTOWEGO W ZAPRAWIE CEMENTOWEJ

    Directory of Open Access Journals (Sweden)

    Magdalena DOBISZEWSKA

    2016-07-01

    Full Text Available Rosnące zapotrzebowanie na surowce naturalne do produkcji materiałów budowlanych, spowodowało intensyfikację badań dotyczących możliwości wykorzystania w produkcji budowlanej materiałów odpadowych. Powszechnie, jako dodatek mineralny do cementu stosowany jest granulowany żużel wielkopiecowy, popiół lotny, czy też pył krzemionkowy. Podczas obróbki kruszywa stosowanego do produkcji mas mineralno-asfaltowych (MMA powstają duże ilości odpadów pylastych. Utylizacja tych odpadów stanowi obecnie duży problem w wielu wytwórniach MMA. W pracy dokonano analizy możliwości zastosowania odpadowego pyłu bazaltowego do produkcji zaprawy cementowej. Najpierw zbadano właściwości fizyczne i chemiczne zastosowanego pyłu bazaltowego. Celem określenia wpływu dodatku pyłu bazaltowego na niektóre właściwości zapraw przygotowano cztery mieszanki, w których pył bazaltowy stanowił częściowy zamiennik piasku w ilości 0-30% masy piasku. Badania doświadczalne dotyczyły analizy wpływu pyłu na wytrzymałość zapraw na ściskanie i zginanie po 2, 28 i 56 dniach dojrzewania próbek, mrozoodporności, nasiąkliwość oraz zdolności do kapilarnego podciągania wody. Następnie przeprowadzono badania dotyczące wpływu dodatku pyłu bazaltowego na mikrostrukturę oraz porowatość zaprawy. Wyniki przeprowadzonych badań wskazują na to, że pył bazaltowy może być stosowany do produkcji zapraw cementowych, jako substytut piasku naturalnego. Zastąpienie części piasku w zaprawie cementowej przez pył bazaltowy pozwoli na zagospodarowanie odpadu przemysłowego oraz wpłynie na poprawę niektórych cech zaprawy cementowej.

  10. Purity of targets prepared on Cu substrates

    Science.gov (United States)

    Méens, A.; Rossini, I.; Sens, J. C.

    1993-09-01

    The purity of several elemental self-supporting targets usually prepared by evaporation onto soluble Cu substrates has been studied. The targets were analysed by Rutherford backscattering and instrumental neutron activation analysis. Because of the high percentage of Cu observed in some Si targets, further measurements, including transmission electron microscopy, have been performed on Si targets deposited by e-gun bombardment onto Cu and ion-beam sputtering onto betaine.

  11. AHRQ series on complex intervention systematic reviews-paper 7: PRISMA-CI elaboration and explanation.

    Science.gov (United States)

    Guise, Jeanne-Marie; Butler, Mary; Chang, Christine; Viswanathan, Meera; Pigott, Terri; Tugwell, Peter

    2017-10-01

    Complex interventions are widely used in health care, public health, education, criminology, social work, business, and welfare. They have increasingly become the subject of systematic reviews and are challenging to effectively report. The Complex Interventions Methods Workgroup developed an extension to the Preferred Reporting Items for Systematic Reviews and Meta-Analyses for Complex Interventions (PRISMA-CI). Following the EQUATOR Network guidance for Preferred Reporting Items for Systematic Reviews and Meta-Analysis extensions, this Explanation and Elaboration (EE) document accompanies the PRISMA-CI checklist to promote consistency in reporting of systematic reviews of complex interventions. The EE document explains the meaning and rationale for each unique PRISMA-CI checklist item and provides examples to assist systematic review authors in operationalizing PRISMA-CI guidance. The Complex Interventions Workgroup developed PRISMA-CI as an important start toward increased consistency in reporting of systematic reviews of complex interventions. Because the field is rapidly expanding, the Complex Interventions Methods Workgroup plans to re-evaluate periodically for the need to add increasing specificity and examples as the field matures. Copyright © 2017 The Authors. Published by Elsevier Inc. All rights reserved.

  12. Część I – ocena okoliczności i biomechaniki urazu

    Directory of Open Access Journals (Sweden)

    Grzegorz Teresiński

    2014-10-01

    Full Text Available Badania nad etiologią i zapobieganiem dystorsji kręgosłupa szyjnego pozostają od wielu lat w centrum zainteresowania badaczy związanych z przemysłem samochodowym i medycyną wypadkową, a także towarzystw ubezpieczeniowych. Etiopatogeneza zespołu dolegliwości związanych z tzw. whiplash (WAD budzi wciąż kontrowersje i jak dotychczas nie udało się w jednoznaczny sposób ustalić jego morfologicznych wykładników. Subiektywny charakter skarg powoduje bardzo duże trudności w obiektywizacji następstw urazu akceleracyjno- deceleracyjnego oraz weryfikacji zgłaszanych roszczeń. Celem pracy było przedstawienie  zależności biomechanicznych oraz okoliczności towarzyszących powstawaniu WAD wynikających z badań populacyjnych, statystyk firm ubezpieczeniowych oraz analizy zapisów rejestratorów zderzeń montowanych przez producentów samochodów. Znajomość technicznych aspektów okoliczności powstawania WAD może ułatwić medyczną ocenę tego rodzaju następstw.

  13. Isenção da ciência, neutralidade da análise

    Directory of Open Access Journals (Sweden)

    Daniel Menezes Coelho

    2012-01-01

    Full Text Available O artigo discute as relações entre a psicanálise e a ciência, especialmente no que tange aos seus métodos de investigação e trabalho. Para isso, tomamos como objeto a noção de neutralidade, tal como podemos apreendê-la na clínica da psicanálise, para confrontá-la com o que chamamos de isenção no campo da ciência, que não quer dizer outra coisa que a neutralidade proposta lá. Veremos que, apesar da clara filiação da noção psicanalítica para com a noção vinda da ciência, a neutralidade clínica da psicanálise toma outro rumo, que se pode mesmo opor ao sentido do termo na ciência. Enquanto em ciência o termo quer significar um processo de purificação e de seleção, em psicanálise ele surge como a exigência de nada selecionar.

  14. The Relation between Nonverbal IQ and Postoperative CI Outcomes in Cochlear Implant Users: Preliminary Result

    Directory of Open Access Journals (Sweden)

    Mina Park

    2015-01-01

    Full Text Available Objectives. This study assessed the correlation between performance intelligence and the postoperative cochlear implant (CI outcome in Korean-speaking children. In addition, the relationship between the performance intelligence subscales and the post-CI speech outcome was evaluated. Materials and Methods. Thirteen pediatric CI users (five males, eight females; median age at implantation 6.2 (range 1.3–14.2 years; median age at intelligence test 9.3 (range 5–16 years who were tested using the Korean Educational Development Institute-Wechsler Intelligence Scale for children were studied. The correlations between the intelligence scores and 1-2 years postoperative Categories of Auditory Performance (CAP scores and between subscales of performance and 1-2 years postoperative CAP scores were analyzed. Results. There was no correlation between the categories of verbal intelligence quotient (IQ and performance IQ for “mentally retarded” and “average,” respectively (Spearman’s rho = 0.42, P=0.15. There was a strong correlation between performance IQ and the postoperative CAP scale (Spearman’s rho = 0.8977, P=0.0008. “Picture arrangement” and “picture completion,” reflecting social cognition, were strongly correlated with the postoperative CAP scales. Conclusion. Performance intelligence, especially social cognition, was strongly related to the postoperative CI outcome of cochlear implant users. Therefore, auditory rehabilitation, including social rehabilitation, should maximize the postoperative CI outcomes.

  15. CiPA: Ongoing testing, future qualification procedures, and pending issues.

    Science.gov (United States)

    Cavero, Icilio; Holzgrefe, Henry

    2015-01-01

    The comprehensive in vitro proarrhythmia assay (CiPA) is a nonclinical, mechanism-based paradigm for assessing drug proarrhythmic liability. The first CiPA assay determines effects on cloned human cardiac ion channels. The second investigates whether the latter study-generated metrics engender proarrhythmic markers on a computationally reconstructed human ventricular action potential. The third evaluates conclusions from, and searches possibly missed effects by in silico analysis, in human stem cell-derived cardiomyocytes (hSC-CMs). CiPA ad hoc Expert-Working Groups have proposed patch clamp protocols for seven cardiac ion channels, a modified O'Hara-Rudy model for in silico analysis, detailed procedures for field (MEA) and action potential (VSD) measurements in hSC-CMs, and 29 reference drugs for CiPA assay testing and validation. CiPA adoption as drug development tool for identifying electrophysiological mechanisms conferring proarrhythmic liability to candidate drugs is a complex, multi-functional task requiring significant time, reflection, and efforts to be fully achieved. Copyright © 2015 Elsevier Inc. All rights reserved.

  16. Ciências Humanas e Sociais: ciências moles? A propósito do trabalho científico nesta contemporaneidade

    Directory of Open Access Journals (Sweden)

    Maria Adélia Aparecida de Souza

    2011-07-01

    Full Text Available Este ensaio busca atender uma velha e interminável discussão sobre uma questão que longe de ser científica é, sobretudo, política, qual seja a classificação das ciências. A Geografia tem oscilado nessas classificações: ora é uma ciência humana, social, ora é uma ciência da natureza. Este estímulo é o motivo principal da realização deste ensaio que, inspirado em uma interessante reflexão de Abraham Moles, prêmio Nobel de Matemática, quando sugere que reflitamos com seriedade científica e acadêmica sobre esse debate. Esse autor propõe corajosamente que as ciências humanas sejam elas sim consideradas “ciências duras”. Aqui é defendida a tese de que, dadas as características e dinâmicas do mundo do presente, as classificações carecem de um processo de discussão condizente com a essência do mundo de hoje, que reverte por vezes o conhecimento pré-estabelecido. Sugere-se, por exemplo, nesta perspectiva, que o espaço geográfico, por ser uma instância social, tal como a economia, a política e a cultura, seja considerado uma categoria social de análise e não um palco de realização da vida, como tem sido considerado pela geografia descritiva, completamente ultrapassada pela velocidade do mundo e pelos sistemas técnicos disponíveis. Resumé SCIENCES HUMAINES ET SOCIALES: SCIENCES "MOLLES"? A PROPOS DU TRAVAIL SCIENTIFIQUE DANS LA CONTEMRAINETÉ Ce teste cherche à participer d´une interminable discussion sur question du classement des sciences. Catte discussion, loin d'être scientifique ou académique est uni discussion politique. Une source d'inspiration de cette reflexion a été I'oeuvre de Abraham Moles, Prix Nobel de Mathématique. Eant la Géographie une science que parfois est classée comme science de la nature, parfois comme science humaine et sociale. Catte discussion a inspirée aussi cet article. II attire I' ATTENTION SUR LA necessité, pour cette de prendre en consideration les

  17. Bonding in [CuNRR′]4 type clusters

    Institute of Scientific and Technical Information of China (English)

    WANG Bingwu; XU Guangxian; CHEN Zhida

    2004-01-01

    Many polynuclear Cu(I) compounds have been synthesized, but the problem whether there is direct or no direct Cu-Cu bonding in these compounds is not clear. The electronic structure of [CuNRR′]4 type clusters was investigated by using density functional methods. The results of geometrical optimization are in good agreement with experiment, and the localization of MO's shows that there are four Cu-Cu ( bonds to form the square Cu4 ring in addition to the four bridging Cu-N-Cu bonds. A concept of the covalence of molecular fragments is proposed to describe the bonding in these clusters.

  18. Fabricación de películas delgadas de CU2 S mediante una reacción de sustitución iónica

    Directory of Open Access Journals (Sweden)

    Gerardo Gordillo Guzmán

    1990-01-01

    Full Text Available Se formaron películas delgadas de sulfuro cuproso (CU2S topotaxialmente sobre películas delgadas de sulfuro de cadmio (CdS mediante una reacción de intercambio de iones de Cu (I provenientes de una solución de CuCI con Iones de Cd (lI de la red de sulfuro de cadmio. Dos tipos diferentes de soluciones de CuCI fueron investigados y los resultados experimentales se evaluaron por medio de medidas de la característica corriente- voltaje (I-V de las celdas solares de CU2 S/CdS obtenidas. Eficiencias de conversión de 4.5% se lograron con dichas celdas solares.

  19. Spatial part-set cuing facilitation.

    Science.gov (United States)

    Kelley, Matthew R; Parasiuk, Yuri; Salgado-Benz, Jennifer; Crocco, Megan

    2016-07-01

    Cole, Reysen, and Kelley [2013. Part-set cuing facilitation for spatial information. Journal of Experimental Psychology: Learning, Memory, & Cognition, 39, 1615-1620] reported robust part-set cuing facilitation for spatial information using snap circuits (a colour-coded electronics kit designed for children to create rudimentary circuit boards). In contrast, Drinkwater, Dagnall, and Parker [2006. Effects of part-set cuing on experienced and novice chess players' reconstruction of a typical chess midgame position. Perceptual and Motor Skills, 102(3), 645-653] and Watkins, Schwartz, and Lane [1984. Does part-set cuing test for memory organization? Evidence from reconstructions of chess positions. Canadian Journal of Psychology/Revue Canadienne de Psychologie, 38(3), 498-503] showed no influence of part-set cuing for spatial information when using chess boards. One key difference between the two procedures was that the snap circuit stimuli were explicitly connected to one another, whereas chess pieces were not. Two experiments examined the effects of connection type (connected vs. unconnected) and cue type (cued vs. uncued) on memory for spatial information. Using chess boards (Experiment 1) and snap circuits (Experiment 2), part-set cuing facilitation only occurred when the stimuli were explicitly connected; there was no influence of cuing with unconnected stimuli. These results are potentially consistent with the retrieval strategy disruption hypothesis, as well as the two- and three-mechanism accounts of part-set cuing.

  20. Synthesis, Characterization and Catalytic Activity of Cu/Cu2O Nanoparticles Prepared in Aqueous Medium

    Directory of Open Access Journals (Sweden)

    Sayed M. Badawy

    2015-07-01

    Full Text Available Copper/Copper oxide (Cu/Cu2O nanoparticles were synthesized by modified chemical reduction method in an aqueous medium using hydrazine as reducing agent and copper sulfate pentahydrate as precursor. The Cu/Cu2O nanoparticles were characterized by X-ray Diffraction (XRD, Energy Dispersive X-ray Fluorescence (EDXRF, Scanning Electron Microscope (SEM, and Transmission Electron Microscope (TEM. The analysis revealed the pattern of face-centered cubic (fcc crystal structure of copper Cu metal and cubic cuprites structure for Cu2O. The SEM result showed monodispersed and agglomerated particles with two micron sizes of about 180 nm and 800 nm, respectively. The TEM result showed few single crystal particles of face-centered cubic structures with average particle size about 11-14 nm. The catalytic activity of Cu/Cu2O nanoparticles for the decomposition of hydrogen peroxide was investigated and compared with manganese oxide MnO2. The results showed that the second-order equation provides the best correlation for the catalytic decomposition of H2O2 on Cu/Cu2O. The catalytic activity of hydrogen peroxide by Cu/Cu2O is less than the catalytic activity of MnO2 due to the presence of copper metal Cu with cuprous oxide Cu2O. © 2015 BCREC UNDIP. All rights reservedReceived: 6th January 2015; Revised: 14th March 2015; Accepted: 15th March 2015How to Cite: Badawy, S.M., El-Khashab, R.A., Nayl, A.A. (2015. Synthesis, Characterization and Catalytic Activity of Cu/Cu2O Nanoparticles Prepared in Aqueous Medium. Bulletin of Chemical Reaction Engineering & Catalysis, 10 (2: 169-174. (doi:10.9767/bcrec.10.2.7984.169-174 Permalink/DOI: http://dx.doi.org/10.9767/bcrec.10.2.7984.169-174  

  1. Pomiar wiarygodności internetowych serwisów handlowych.

    OpenAIRE

    Garnik, Igor; Basińska, Beata

    2011-01-01

    Rozwój handlu internetowego jest odpowiedzią na zapotrzebowanie klientów na tę formę dystrybucji towarów i usług. Z tego powodu, zarządzanie witryną sklepu internetowego, w celu zwiększenia jej wiarygodności, a co za tym idzie – konkurencyjności, jest ważnym zadaniem stojącym przed podmiotami prowadzącymi działalność gospodarczą w sieci. Celem niniejszej pracy było zaproponowanie nowej metody oceny wiarygodności serwisów WWW. Badanie przeprowadzono w grupie 225 osób (83% doświadczonych i 17% ...

  2. Identyfikacja wielokryterialnego modelu istotności pompowni melioracyjnych na terenie Polski

    OpenAIRE

    Wojciech Sałabun; Michał Napierała; Jerzy Bykowski

    2015-01-01

    Niniejsza praca omawia istotny problem związany z klasyfikacją i właściwym zdefiniowaniem wielkości pompowni melioracyjnych. Podstawowa definicja wielkości jest bardzo szeroka, zatem ze względu na liczbę objaśniających ją parametrów wymaga precyzyjnego uściślenia. W dotychczasowych ocenach rozmiarów pompowni melioracyjnych posługiwano się na ogół wrażeniami osobistymi opartymi na subiektywnym odczuciu, które z kolei jest oparte na nieznanej liczbie parametrów. Pojawiające się przy...

  3. Seria a Metafísica Essencial à Ciência e ao Senso Comum?

    Directory of Open Access Journals (Sweden)

    Rafael Sandoval

    2017-02-01

    Full Text Available Uma das declarações mais consensuais da História da Filosofia é a que diz que a Metafísica não é ciência, mas pensamento. Neste artigo, procurar-se-á defender a tese que a Metafísica é condição para o senso comum e a ciência. Primeiro, é mostrado que os termos ao qual nós utilizamos diariamente refletem nossa imagem de mundo. Quando pensamos e fazemos previsões, fazemos o uso espontâneo de termos com significado universal. Depois, é procurado evidenciar que a ciência naturalmente faz uso de termos com significado universal quando faz previsões. Finalmente, buscará apresentar que a Metafísica é anterior às nossas hipóteses e especulações.

  4. Eclipse in the binary system of the CI Cyg symbiotic star

    Energy Technology Data Exchange (ETDEWEB)

    Belyakina, T S

    1979-01-01

    Photoelectric photometry and spectral observations of the symbiotic star CI Cyg were carried out at the Crimean Astrophysical Observatory from April, 1975 through December, 1976. The instrumental photometric system used was close to the UBV. Considerable light variations and spectral changes have been recorded during the period of the observations. Yellow, blue and ultraviolet amplitudes were equal to 2.3, 3.0 and 3sub(m).3 correspondingly. The brightness of CI Cyg reached maximal value in June - July, 1975 when spectrum was F5 with Hsub(..cap alpha..) and Hsub(..beta..) in emission. A sharp and deep minimum in the light curves of CI Cyg was observed during the period of the highest brightness. It was caused by the eclipse of the hot component by the cold one in the binary system.

  5. Korzyści z podejmowania regularnej aktywności fizycznej przez osoby starsze = The benefits of regular physical activity for the elderly

    Directory of Open Access Journals (Sweden)

    U. Kaźmierczak

    2015-01-01

    3Wydział Kultury Fizycznej, Zdrowia i Turystyki, Uniwersytet Kazimierza Wielkiego w Bydgoszczy   Słowa kluczowe: regularna aktywność fizyczna, osoby starsze.   Keywords: regular physical activity, elderly.   Abstrakt W państwach rozwiniętych i rozwijających się coraz większą grupę społeczeństw stanowią seniorzy. Świadomość problemu spowodowała podjęcie powszechnej dyskusji ekspertów i praktyków z dziedzin medycznych na temat konieczności działań niezbędnych dla zapewnienia społeczeństwom pomyślnej starości. Od dawna wskazuje się, że brak aktywności ruchowej jest dla zdrowia niebezpieczny. Starzeniu się układu sercowo-naczyniowego towarzyszy dużo niekorzystnych zmian strukturalnych, czynnościowych i biochemicznych. Za typowe dla tego okresu zmiany uważa się osłabienie możliwości relaksacji włókien mięśniowych, co może być przyczyną rozkurczowej niewydolności serca. Trening zdrowotny – jest rodzajem aktywności fizycznej wykonywanej z powodów medycznych. Celem jest uzyskanie efektów fizycznych oraz psychicznych przeciwdziałających zmniejszaniu się zdolności adaptacyjnych organizmu. Eksperci przekonują osoby starsze o korzyściach płynących z aktywnego fizycznie stylu życia. Bogate piśmiennictwo poruszające tematykę medycznych aspektów procesu starzenia, mówi o niezaprzeczalnym znaczeniu ruchu dla toczących się w ludzkim ciele procesów inwolucyjnych. Aktywność fizyczna odpowiednio dozowana jest w stanie wyraźnie zmniejszyć negatywny wpływ tych zmian i jak najdłużej pozwolić utrzymać zdrowie fizyczne, psychiczne i społeczne. Zauważono, że systematycznie dozowany wysiłek fizyczny zmniejsza ryzyko wystąpienia wielu chorób np. cukrzycy, miażdżycy, choroby niedokrwiennej serca. Liczne badania naukowe i bogate piśmiennictwo gerontologiczne przedstawiają najnowsze doniesienia specjalistów o tym, jak należy prawidłowo przygotować i prowadzić trening fizyczny z osobami starszymi

  6. Electronic structures of PtCu, PtAg, and PtAu molecules: a Dirac four-component relativistic study

    International Nuclear Information System (INIS)

    Abe, Minori; Mori, Sayaka; Nakajima, Takahito; Hirao, Kimihiko

    2005-01-01

    Relativistic four-component calculations at several correlated levels have been performed for diatomic PtCu, PtAg, and PtAu molecules. The ground state spectroscopic constants of PtCu were calculated using the four-component MP2 method, and show good agreement with experiment. We also performed calculations on the experimentally unknown species, PtAg and PtAu, and the mono-cationic systems, PtCu + , PtAg + , and PtAu + . The low-lying excited states of these diatomic molecules were also investigated using the four-component multi-reference CI method

  7. Expression, purification, and reconstitution of the voltage-sensing domain from Ci-VSP.

    Science.gov (United States)

    Li, Qufei; Jogini, Vishwanath; Wanderling, Sherry; Cortes, D Marien; Perozo, Eduardo

    2012-10-16

    The voltage-sensing domain (VSD) is the common scaffold responsible for the functional behavior of voltage-gated ion channels, voltage sensitive enzymes, and proton channels. Because of the position of the voltage dependence of the available VSD structures, at present, they all represent the activated state of the sensor. Yet in the absence of a consensus resting state structure, the mechanistic details of voltage sensing remain controversial. The voltage dependence of the VSD from Ci-VSP (Ci-VSD) is dramatically right shifted, so that at 0 mV it presumably populates the putative resting state. Appropriate biochemical methods are an essential prerequisite for generating sufficient amounts of Ci-VSD protein for high-resolution structural studies. Here, we present a simple and robust protocol for the expression of eukaryotic Ci-VSD in Escherichia coli at milligram levels. The protein is pure, homogeneous, monodisperse, and well-folded after solubilization in Anzergent 3-14 at the analyzed concentration (~0.3 mg/mL). Ci-VSD can be reconstituted into liposomes of various compositions, and initial site-directed spin labeling and electron paramagnetic resonance (EPR) spectroscopic measurements indicate its first transmembrane segment folds into an α-helix, in agreement with the homologous region of other VSDs. On the basis of our results and enhanced relaxation EPR spectroscopy measurement, Ci-VSD reconstitutes essentially randomly in proteoliposomes, precluding straightforward application of transmembrane voltages in combination with spectroscopic methods. Nevertheless, these results represent an initial step that makes the resting state of a VSD accessible to a variety of biophysical and structural approaches, including X-ray crystallography, spectroscopic methods, and electrophysiology in lipid bilayers.

  8. Expression, Purification and Reconstitution of the Voltage Sensing Domain from Ci-VSP

    Science.gov (United States)

    Li, Qufei; Jogini, Vishwanath; Wanderling, Sherry; Cortes, D. Marien; Perozo, Eduardo

    2013-01-01

    The voltage-sensing domain (VSD) is the common scaffold responsible for the functional behavior of voltage gated ion channels, voltage sensitive enzymes and proton channels. Because of the position of the voltage dependence of the available VSD structures, at present, they all represent the activated state of the sensor. Yet, in the absence of a consensus resting state structure, the mechanistic details of voltage sensing remain controversial. The voltage dependence of the VSD from Ci-VSP (Ci-VSD) is dramatically right shifted, so that at 0 mV It presumably populates the putative resting state. Appropriate biochemical methods are an essential prerequisite to generate sufficient amounts of Ci-VSD protein for high-resolution structural studies. Here, we present a simple and robust protocol for the Escherichia coli expression of eukaryotic Ci-VSD at milligram levels. The protein is pure, homogeneous, mono-disperse and well folded after solubilization in Anzergent 3-14 at the analyzed concentration (~ 0.3 mg/mL). Ci-VSD can be reconstituted into liposomes of various compositions and initial site-directed spin labeling and EPR spectroscopic measurements indicate its first transmembrane segment folds into an α-helix, in agreement to the homologous region of other VSDs. Based on current results and enhanced relaxation EPR spectroscopy measurement, Ci-VSD reconstitutes essentially randomly in proteo-liposomes, precluding straightforward application of transmembrane voltages in combination with spectroscopic methods. Nevertheless, the present results represent an initial step that makes the resting state of a VSD accessible to a variety of biophysical and structural approaches, including X-ray crystallography, spectroscopic methods and electrophysiology in lipid bilayers. PMID:22989304

  9. Badania jakości regeneratu ze zużytych mas ze spoiwem organicznym

    Directory of Open Access Journals (Sweden)

    R. Dańko

    2012-12-01

    Full Text Available W publikacji przedstawiono uzupełniające metody badań oraz aparaturę do oceny jakości regeneratu i tych właściwości masformierskich ze spoiwami utwardzanymi chemicznie, przygotowywanych z regeneratem, które są istotne dla kompleksowej oceny procesurecyklingu osnowy. Nowoczesne systemy oceny mas formierskich wymagają bardziej wnikliwego podejścia do czynników decydującychzarówno o ich przydatności technologicznej jak również o wpływie na otaczające środowisko naturalne. W tym kontekście pełna ocenajakości zregenerowanej osnowy wykracza poza zwyczajowo stosowane metody instrumentalne i wymaga ich uzupełnienia o bardziejzaawansowane aparaturowo metody badawcze. Pozwala to szerzej spojrzeć na ocenę zregenerowanej osnowy, zarówno w aspekcie jejużycia do sporządzania mas formierskich, jako substytutu świeżego piasku, ale także pod kątem ochrony środowiska. Do takichnowoczesnych metod można zaliczyć między innymi analizę ziarnową regeneratu za pomocą dyfrakcji laserowej, a także ocenęgazotwórczości masy formierskiej oraz identyfikację rodzaju emitowanych gazów i zawartości w nich gazów z grupy BTEX, które sąszczególnie niebezpieczne z punktu widzenia BHP.

  10. Giant Cu 2p Resonances in CuO Valence-Band Photoemission

    NARCIS (Netherlands)

    Tjeng, L.H.; Chen, C.T.; Ghijsen, J.; Rudolf, P.; Sette, F.

    1991-01-01

    We report the observation of a giant resonance in the Cu 2p resonant-photoemission spectra of CuO. The study allows the unambiguous identification of the local Cu 3d8 configuration in the valence-band photoemission spectrum, providing conclusive evidence for the charge-transfer nature of the

  11. Phase relationships in Cu-rich corner of the Cu-Cr-Zr phase diagram

    International Nuclear Information System (INIS)

    Zeng, K.J.; Haemaelaeinen, M.; Lilius, K.

    1995-01-01

    In the available experimental information on the Cu-Cr-Zr ternary system, there exist different opinions concerning the phase relationships in the Cu-rich corner of Cu-Cr-Zr phase diagram. Glazov et al. and Zakharov et al. investigated the Cu-rich corner of the Cu-Cr-Zr phase diagram within the composition range up to 3.5 Cr and 3.5 Zr (wt. %). A quasi-eutectic reaction L → (Cu) + αCr 2 Zr was observed to occur at 1,020 C and several isothermal sections were constructed within the temperature range from 600 to 1,000 C to show the (Cu)-αCr 2 Zr two phase equilibrium. Therefore, a pseudobinary Cu-Cr 2 Zr system was supposed. Afterwards, Dawakatsu et al, Fedorov et al, and Kuznetsov et al studied the cu-rich corner of the phase diagram in a wider composition range up to 5 Cr and 20 Zr (at.%). Contrary to Glazov et al. and Zakharov et al., they found no Cr 2 Zr phase in their samples. Hence, the pseudobinary Cu-Cr 2 Zr system does not exist. In this study an experimental investigation is presented on the phase relationships in Cu-rich corner of the Cu-Cr-Zr phase diagram at 940 C in order to clear up the confusion

  12. Coupled growth of Al-Al2Cu eutectics in Al-Cu-Ag alloys

    International Nuclear Information System (INIS)

    Hecht, U; Witusiewicz, V; Drevermann, A

    2012-01-01

    Coupled eutectic growth of Al and Al 2 Cu was investigated in univariant Al-Cu-Ag alloys during solidification with planar and cellular morphology. Experiments reveal the dynamic selection of small spacings, below the minimum undercooling spacing and show that distinct morphological features pertain to nearly isotropic or anisotropic Al-Al 2 Cu interfaces.

  13. Antiferromagnetic Coupling in the Polynuclear Compound [Cu(II) (Allopurinolate) (OH-)] n

    Science.gov (United States)

    Acevedo-Chávez, Rodolfo; Costas, María. Eugenia; Escudero-Derat, Roberto

    1994-11-01

    Synthetic, spectral, and magnetic studies of the Cu(II) polynuclear coordination compound [Cu(HL(OH-)]n with bridging OH- and HL (allopurinolate; C5H3N4O-) ligands are reported. The compound is obtained from aqueous media (at several pH values and from CI-, Br-, NO-3, SO2-4, ClO-4, and CH3CO-2 Cu(II) salts), from DMSO at ca. 70°C using several of the above salts, and under refluxing methanol employing Cu(SO4) or Cu(CH3CO2)2. The results suggest that the compound [Cu(HL)(OH-)]n has a polynuclear form in which the bridging allopurinolate is coordinated through the N(1) and N(2) atoms of the pyrazolic moiety. All attempts to grow crystals suitable for X-ray studies were unsuccessful, and an amorphous compound was always obtained. Magnetic studies show the existence of a strong antiferromagnetic coupling, which may be associated with a favorable structural arrangement between the metallic centers and the bridging ligands. This magnetic behavior is remarkable for a Cu(II) polynuclear coordination compound. Spectral and magnetic results together with the coordination modes of the bridging groups let us postulate as a possible arrangement a cyclic polynuclear structure presenting the allopurinolate and OH- bridging ligands in a mutually trans configuration. This work is the first EPR spectral and magnetic study reported for a coordination compound with the allopurinol heterocycle as a ligand and, thus for the first example of a polynuclear coordination compound combining allopurinolate and OH- as bridging groups.

  14. Contribuições para o estudo do ciúme excessivo

    OpenAIRE

    Andrea Lorena da Costa

    2010-01-01

    O ciúme romântico é um complexo de pensamentos, emoções e ações que visam proteger o relacionamento diante de uma ameaça percebida real ou imaginária e tem como objetivo eliminar os riscos da perda do objeto de amor. O ciúme excessivo (patológico) é uma preocupação infundada, irracional e irreal, composto de diversas emoções e pensamentos que provocam prejuízos significativos no funcionamento pessoal e relacional. O objetivo deste trabalho foi explorar a presença de transtornos psiquiátrico...

  15. Combustion Characteristics of CI Diesel Engine Fuelled With Blends of Jatropha Oil Biodiesel

    Science.gov (United States)

    Singh, Manpreet; Yunus Sheikh, Mohd.; Singh, Dharmendra; Nageswara rao, P.

    2018-03-01

    Jatropha Curcas oil is a non-edible oil which is used for Jatropha biodiesel (JBD) production. Jatropha biodiesel is produced using transesterification technique and it is used as an alternative fuel in CI diesel engine without any hardware modification. Jatropha biodiesel is used in CI diesel engine with various volumetric concentrations (blends) such as JBD5, JBD15, JBD25, JBD35 and JBD45. The combustion parameters such as in-cylinder pressure, rate of pressure rise, net heat release, cumulative heat release, mass fraction burned are analyzed and compared for all blends combustion data with mineral diesel fuel (D100).

  16. A inclusão na perspectiva do novo paradigma da ciência

    Directory of Open Access Journals (Sweden)

    Reinoldo Marqueza

    2011-12-01

    Full Text Available O estudo aborda o processo de transição paradigmática da ciência moderna para a ciência pós-moderna. Salienta as características do paradigma atual, a crise desse paradigma e aponta os contornos do paradigma emergente na perspectiva do sociólogo Boaventura Sousa Santos. Refere a Educação Inclusiva como um novo processo de produção e de apropriação do conhecimento e como uma nova forma de estar na relação.Palavras-chave: Paradigma. Conhecimento. Educação Inclusiva.

  17. Cu uptake and turnover in both Cu-acclimated and non-acclimated rainbow trout (Oncorhynchus mykiss)

    DEFF Research Database (Denmark)

    Grosell, M.; Hogstrand, C.; Wood, C.M.

    1997-01-01

    -acclimation clearly involves changes in copper accumulation kinetics in the plasma. The acclimated fish showed a 65% reduced Cu-64 accumulation after 65 h and an increased turnover of Cu in the plasma compared to the non-acclimated fish. Total Cu in the plasma increased by 59% after 3 h of exposure in the non...... aortic catheter. By measuring both Cu-64 accumulation and total Cu concentrations, we were able to analyse the ongoing uptake and turnover of ambient Cu, independent of any Cu already present in the fish. Plasma accounted for at least 90% of the Cu-64 labelled Cu present in the blood and Cu...... h of exposure. Acclimation did not have an unambiguous effect on branchial Cu uptake and differences in branchial uptake could not explain the reduced accumulation in the plasma. The rapidly exchangeable Cu pools were 54% in the gills and 33% in the liver, suggesting a considerable hepatic Cu...

  18. The structure of molten CuCl, CuI and their mixtures as investigated by using neutron diffraction

    International Nuclear Information System (INIS)

    Drewitt, James W E; Salmon, Philip S; Takeda, Shin'ichi; Kawakita, Yukinobu

    2009-01-01

    The structure of molten CuCl, CuI and their mixtures (CuCl) x (CuI) 1-x with x = 0.294, 0.576, 0.801 was studied by using neutron diffraction. The results are discussed by reference to the information that is available on the structure of CuCl and CuI from experiment, theory and computer simulation. The comparison points to a need for more realistic models for the CuCl-CuI system which should take into account the presence of chemical bonds that have been found in CuI by the application of ab initio molecular dynamics methods.

  19. Laser Photolytic Approach to Cu/polymer Sols and Cu/polymer Nanocomposites with Amorphous Cu Phase.

    Czech Academy of Sciences Publication Activity Database

    Pola, Josef; Ouchi, A.; Bakardjieva, Snejana; Urbanová, Markéta; Boháček, Jaroslav; Šubrt, Jan

    2007-01-01

    Roč. 192, 2-3 (2007) , s. 84-92 ISSN 1010-6030 Institutional research plan: CEZ:AV0Z40720504; CEZ:AV0Z40320502 Keywords : Cu-polymer nanocomposite * laser solution photolysis * amorphous Cu phase Subject RIV: CH - Nuclear ; Quantum Chemistry Impact factor: 1.911, year: 2007

  20. Dzieło sztuki na granicy przeszłości i przyszłości. Historia i patriotyzm w sztuce nieprofesjonalnej

    Directory of Open Access Journals (Sweden)

    Aleksandra Weronika Jarysz

    2016-01-01

    Full Text Available A work of art – a link between the present and the past. History and patriotism in non-professional art In her article, the author discusses art of non-professional artists who shape the national identity in an original way. In the former professional art, the works which illustrated and uplifted history were very popular. This phenomenon is still present among folk, naive, intuitive artists, generally speaking – non-professionals. The work of their hands and imagination is a tool serving the purpose of national values and ideas, and is sometimes the basis for broader considerations on the human condition. They balance between historical facts and ahistorical generalities. The martyrdom of the Polish nation with emphasis on the events of WWII has been inspiring artists, stimulating their imagination and artistic creation. Therefore numerous ‘monuments of patriotic art’ can be found in the wood sculpture, ceramics, painting, and glass painting works from the art collection of the Toruń Maria Znamierowska-Prüfferowa Ethnographic Museum.   Dzieło sztuki na granicy przeszłości i przyszłości. Historia i patriotyzm w sztuce nieprofesjonalnej W swoim artykule autorka prezentuje sztukę twórców nieprofesjonalnych, którzy w sposób oryginalny kształtują tożsamość narodową. W dawnej sztuce profesjonalnej dzieła, które ilustrowały i uwznioślały historię były bardzo popularne. To zjawisko jest nadal aktualne wśród twórców ludowych, naiwnych, intuicyjnych, ogólnie nazywając – nieprofesjonalnych. Dzieło ich rąk i wyobraźni jest narzędziem w służbie wartości i idei narodowych, a niekiedy stanowi podstawę do szerszych rozważań nad kondycją człowieka. Balansują oni między konkretem historycznym a ahistoryczną ogólnością. Martyrologia narodu polskiego z naciskiem na wydarzenia II wojny światowej inspirowała i inspiruje twórców, pobudza ich wyobraźnię i zmusza do twórczej kreacji. Stąd też zar

  1. Projeto Caminhão da Ciência: Popularização da Ciência no Oeste da Bahia

    Directory of Open Access Journals (Sweden)

    E. C. V. de Magalhães

    2014-11-01

    Full Text Available O Projeto Caminhão da Ciência tem por objetivo promover a divulgação científica em Escolas e espaços públicos da Região Oeste da Bahia. O projeto teve início no ano de 2009, com apoio do CNPq, ocorrendo a sua primeira apresentação no ano de 2010, na feira libre de Barreiras. Várias áreas do conhecimento são contempladas entre eles: Biologia, Física, Química, Matemática, Geologia e Engenharias. O projeto se fundamenta por apresentações de temáticas desenvolvidas por alunos de graduação, sob a orientação de professores da Universidade Federal do Oeste da Bahia-UFOB, envolvidos no projeto. Diversas temáticas são desenvolvidas na forma trabalhos interdisciplinares entre eles: elaboração de maquetes, experimentos com uso de materiais alternativos, vídeos, jogos e ainda informativos em websites e webblogs. Para as apresentações do projeto, são realizadas visitas nas escolas ou outros espaçoes e os materiais trasportados no Caminhão são montados no espaço físico disponibilizado, criando um cenário similar ao de uma feira de ciências. Neste trabalho são apresentados relatos de apresentações realizadas em Escolas, enfatizando os resultados obtidos que demonstram a socialização do conhecimento científico entre os monitores e a comunidade assistida, além da interação entre a Universidade e a sociedade.

  2. Antimicrobial Cu-bearing stainless steel scaffolds

    International Nuclear Information System (INIS)

    Wang, Qiang; Ren, Ling; Li, Xiaopeng; Zhang, Shuyuan; Sercombe, Timothy B.; Yang, Ke

    2016-01-01

    Copper-bearing stainless steel scaffolds with two different structures (Body Centered Cubic and Gyroid labyrinth) at two solid fractions (25% and 40%) were fabricated from both 316L powder and a mixture of 316L and elemental Cu powder using selective laser melting, and relative 316L scaffolds were served as control group. After processing, the antimicrobial testing demonstrated that the 316L-Cu scaffolds presented excellent antimicrobial activity against Escherichia coli and Staphylococcus aureus, and the cell viability assay indicated that there was no cytotoxic effect of 316L-Cu scaffolds on rat marrow mesenchymal stem cells. As such, these have the potential to reduce implant-associated infections. The Cu was also found to homogeneously distribute within the microstructure by scanning electronic microcopy. The addition of Cu would not significantly affect its strength and stiffness compared to 316L scaffold, and the stiffness of all the scaffolds (3-20GPa) is similar to that of bone and much less than that of bulk stainless steel. Consequently, fabrication of such low stiffness porous structures, especially coupled with the addition of antimicrobial Cu, may provide a new direction for medical stainless steels. - Highlights: • 316L-Cu scaffolds were fabricated by using selective laser melting (SLM). • 316L-Cu scaffolds showed satisfied antimicrobial activities. • 316L-Cu scaffolds have no cytotoxic effect on normal cells. • Other properties of 316L-Cu scaffolds were similar to 316L scaffolds. • 316L-Cu scaffolds have the potential to be used in orthopedic applications.

  3. Antimicrobial Cu-bearing stainless steel scaffolds

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Qiang, E-mail: mfqwang@163.com [School of Stomatology, China Medical University, Shenyang 110002 (China); Ren, Ling [Institute of Metal Research, Chinese Academy of Sciences (China); Li, Xiaopeng [School of Mechanical and Chemical Engineering, The University of Western Australia (Australia); Zhang, Shuyuan [Institute of Metal Research, Chinese Academy of Sciences (China); Sercombe, Timothy B., E-mail: tim.sercombe@uwa.edu.au [School of Mechanical and Chemical Engineering, The University of Western Australia (Australia); Yang, Ke, E-mail: kyang@imr.ac.cn [Institute of Metal Research, Chinese Academy of Sciences (China)

    2016-11-01

    Copper-bearing stainless steel scaffolds with two different structures (Body Centered Cubic and Gyroid labyrinth) at two solid fractions (25% and 40%) were fabricated from both 316L powder and a mixture of 316L and elemental Cu powder using selective laser melting, and relative 316L scaffolds were served as control group. After processing, the antimicrobial testing demonstrated that the 316L-Cu scaffolds presented excellent antimicrobial activity against Escherichia coli and Staphylococcus aureus, and the cell viability assay indicated that there was no cytotoxic effect of 316L-Cu scaffolds on rat marrow mesenchymal stem cells. As such, these have the potential to reduce implant-associated infections. The Cu was also found to homogeneously distribute within the microstructure by scanning electronic microcopy. The addition of Cu would not significantly affect its strength and stiffness compared to 316L scaffold, and the stiffness of all the scaffolds (3-20GPa) is similar to that of bone and much less than that of bulk stainless steel. Consequently, fabrication of such low stiffness porous structures, especially coupled with the addition of antimicrobial Cu, may provide a new direction for medical stainless steels. - Highlights: • 316L-Cu scaffolds were fabricated by using selective laser melting (SLM). • 316L-Cu scaffolds showed satisfied antimicrobial activities. • 316L-Cu scaffolds have no cytotoxic effect on normal cells. • Other properties of 316L-Cu scaffolds were similar to 316L scaffolds. • 316L-Cu scaffolds have the potential to be used in orthopedic applications.

  4. CI+MBPT calculations of Ar I energies, g factors, and transition line strengths

    Science.gov (United States)

    Savukov, I. M.

    2018-03-01

    Excited states of noble gas atoms present certain challenges to atomic theory for several reasons: first, relativistic effects are important and LS coupling is not optimal; second, energy intervals can be quite small, leading to strong mixing of states; third, many-body perturbation theory for hole states does not converge well. Previously, some attempts were made to solve this problem, using for example the all-order coupled-cluster approach and particle-hole configuration-interaction many-body perturbation theory (CI-MBPT) with modified denominators. However, while these approaches were promising, the accuracy was still limited. In this paper, we calculate Ar I energies, g factors, and transition amplitudes using ab initio CI-MBPT with eight valence electrons to avoid the problem of slow convergence of MBPT due to strong interaction between 3p and 3s states. We also included in CI many dominant states obtained by double excitations of the ground state configuration. Thus perturbation corrections were needed only for 1s, 2s, 2p core electrons non-included in valence-valence CI, which are quite small. We found that energy, g factors, and electric dipole matrix elements are in reasonable agreement with experiments. It is noteworthy that the theory agreed well with accurately measured g factors. Experimental oscillator strengths have large uncertainty, so in some cases we made a comparison with average values.

  5. The Role of Journals in Building up Communities: The Experience of "Ciência em Tela"

    Science.gov (United States)

    Martins, Isabel; de Souza Barros, Susana

    2015-01-01

    "Ciência em Tela" is an open access Brazilian science teacher education online journal that has been published twice a year since 2008 and which encourages the participation of professionals with different backgrounds and the submission of a variety of textual genres, besides research papers. Another feature is that the journal includes…

  6. Magnetic Dimer Excitations in Cs3Cr2CI9 Studied by Neutron Scattering

    DEFF Research Database (Denmark)

    Leuenberger, Bruno; Güdel, Hans U.; Kjems, Jørgen

    1985-01-01

    The energy dispersion of the singlet-triplet dimer excitation in Cs3Cr2CI9h as been studied by inelastic neutron scattering (INS) at temperatures down to 1.3 K. The results can be accounted for by using a completely isotropic Heisenberg Hamiltonian in the random phase approximation (RPA). Only...

  7. Ciências da Religião numa sociedade multicultural

    Directory of Open Access Journals (Sweden)

    Wolfgang Gruen

    2009-05-01

    Full Text Available Texto originalmente apresentado como aula inaugural do Programa de Pós-graduação em Ciências da Religião da PUC Minas. Trata da epistemologia e dos desafios da investigação em Ciências da Religião. Partindo do problema de base da religiosidade na Educação, do fenômeno religioso e sua dimensão profunda, o artigo segue uma densa investigação sobre os limites e horizontes das Ciências da Religião.Palavras-chave: Ciências da Religião; Religião; Religiosidade; Educação; Ensino religioso.ABSTRACTThis text was originally presented as the opening class of the Postgraduate Programme in Sciences of Religion of PUC Minas. It concerns the epistemology and challenges of investigation in Sciences of Religion. Starting from the fundamental question of religiosity in Education, of the religious phenomenon and its deep dimension, the article embarks on a close investigation into the limits and horizons of the Sciences of Religion.Key words: Sciences of religions; Religion; Religiosity; Education; Religious teaching.

  8. Ocena Nośności Konstrukcji Nawierzchni Lotniskowych Metodą Acn-Pcn

    Directory of Open Access Journals (Sweden)

    Wesołowski Mariusz

    2014-12-01

    Full Text Available Konstrukcje nawierzchni lotniskowych są projektowane na określony okres eksploatacji przy założeniu prognozowanego natężenia i struktury ruchu lotniczego. Bezpieczeństwo wykonywania operacji lotniczych przez statki powietrzne na nawierzchniach lotniskowych zależy przede wszystkim od stanu nośności ich konstrukcji. W związku z tym, kontrolne badania nośności należy przeprowadzać okresowo, gdyż informacja o aktualnym stanie eksploatacyjnym nawierzchni lotniskowej stanowi podstawę do podejmowania decyzji o rodzajach statków powietrznych dopuszczonych do ruchu, intensywności ruchu lotniczego oraz terminach rozpoczęcia prac remontowych lub modernizacyjnych. Aktualnie do oceny nośności nawierzchni lotniskowych stosuje się metodę ACN-PCN, która została wprowadzona przez Organizację Międzynarodowego Lotnictwa Cywilnego ICAO (International Civil Aviation Organization. W artykule przedstawiony został sposób wyznaczania i opisu wskaźnika PCN

  9. As diferentes faces da razão (II. Risco, ciência e peritos

    Directory of Open Access Journals (Sweden)

    C. M. Novais Madureira

    2012-10-01

    Full Text Available Em texto anterior argumentou-se contra os excessos do cientismo com que, na linha de Sokal e Bricmont, António Manuel Baptista ataca as análises sociológicas dos processos e produtos da ciência, nomeadamente as posições de Boaventura de Sousa Santos. Neste outro texto, pretende-se contestar AMB e os sokalistas no seu próprio campo, o da ciência pura e dura, mostrando que eles próprios não compreendem o estatuto das suas ciências, e tentando ponderar afirmações menos precisas, frequentes na análise da sociogénese da ciência. Trazendo a discussão para o nosso tempo, abordaremos também uma problemática não tratada no texto anterior, a do estatuto dos cientistas e tecnólogos enquanto peritos nas instâncias de decisão. Por último, tratará de analisar-se como as controvérsias entre peritos, hoje tão frequentes, são vividas no seio da comunidade científica e qual a evolução que geram na própria prática pericial.

  10. Visualization and prediction of porosity in roller compacted ribbonswith near infrared chemical imaging (NIR-CI)

    DEFF Research Database (Denmark)

    Khorasani, Milad Rouhi; Amigo Rubio, Jose Manuel; Sonnergaard, Jørn

    2015-01-01

    The porosity of roller compacted ribbon is recognized as an important critical quality attribute which has a huge impact on the final product quality. The purpose of this study was to investigate the use of near-infrared chemical imaging (NIR-CI) for porosity estimation of ribbons produced...... and control of continuously operating roller compaction line....

  11. CCI and CI Join Hands:A Better Supply Chain with More Innovations on Cotton Fabrics

    Institute of Scientific and Technical Information of China (English)

    Tom; Xue

    2010-01-01

    Cotton Council International("CCI")and Cotton Incorporated("CI") joined forces again,from October 19-22,2010 at Intertextile Shanghai,to promote natural fiber-U.S.cotton.As global textile strategic partners,both organizations were bringing together alliances through the cotton

  12. Coupling between the voltage-sensing and phosphatase domains of Ci-VSP.

    Science.gov (United States)

    Villalba-Galea, Carlos A; Miceli, Francesco; Taglialatela, Maurizio; Bezanilla, Francisco

    2009-07-01

    The Ciona intestinalis voltage sensor-containing phosphatase (Ci-VSP) shares high homology with the phosphatidylinositol phosphatase enzyme known as PTEN (phosphatase and tensin homologue deleted on chromosome 10). We have taken advantage of the similarity between these proteins to inquire about the coupling between the voltage sensing and the phosphatase domains in Ci-VSP. Recently, it was shown that four basic residues (R11, K13, R14, and R15) in PTEN are critical for its binding onto the membrane, required for its catalytic activity. Ci-VSP has three of the basic residues of PTEN. Here, we show that when R253 and R254 (which are the homologues of R14 and R15 in PTEN) are mutated to alanines in Ci-VSP, phosphatase activity is disrupted, as revealed by a lack of effect on the ionic currents of KCNQ2/3, where current decrease is a measure of phosphatase activity. The enzymatic activity was not rescued by the introduction of lysines, indicating that the binding is an arginine-specific interaction between the phosphatase binding domain and the membrane, presumably through the phosphate groups of the phospholipids. We also found that the kinetics and steady-state voltage dependence of the S4 segment movement are affected when the arginines are not present, indicating that the interaction of R253 and R254 with the membrane, required for the catalytic action of the phosphatase, restricts the movement of the voltage sensor.

  13. School performance and wellbeing of children with CI in different communicative-educational environments

    NARCIS (Netherlands)

    Langereis, M.C.; Vermeulen, A.M.

    2015-01-01

    OBJECTIVES: This study aimed to evaluate the long term effects of CI on auditory, language, educational and social-emotional development of deaf children in different educational-communicative settings. METHODS: The outcomes of 58 children with profound hearing loss and normal non-verbal cognition,

  14. Experimental and Numerical Investigation of Ethanol/Diethyl Ether Mixtures in a CI Engine

    KAUST Repository

    Sivasankaralingam, Vedharaj; Raman, Vallinayagam; Jaasim, Mohammed; Alfazazi, Adamu; Lu, Tianfeng; Im, Hong G.; Sarathy, Mani; Dibble, Robert W.

    2016-01-01

    ), were tested in a CI engine. While DE75 and DE50 auto-ignited at an inlet air pressure of 1.5 bar, DE25 failed to auto-ignite even at boosted pressure of 2 bar. The peak in-cylinder pressure for diesel and DE75 were comparable, while DE50 showed reduced

  15. SISTEM PENJUALAN SPARE PART TOKO AJM MOTOR MENGGUNAKAN CI BERBASIS ARSITEKTUR MVC

    Directory of Open Access Journals (Sweden)

    Ade Setiadi

    2016-11-01

    Full Text Available Saat ini penggunaan komputer dan perangkat lunak semakin banyak hingga ke berbagai kehidupan, bahkan sampai pada bidang ekonomi. Sistem Informasi merupakan peranan sangat penting dalam kegiatan bisnis di suatu perusahaan. Toko AJM Motor bergerak dalam bidang penjualan spare part mobil dan masih menggunakan cara yang konvensional dalam mengolah data tentang transaksi penjualan, untuk itu Toko AJM Motor membutuhkan sistem informasi yang dapat menunjang kelancaran dalam melakukan transaksi penjualannya. Dalam dunia teknologi khususnya pemrograman saat ini, baik itu desktop maupun web base semakin marak pengerjaannya menggunakan framework dan salah satu framework berbasis PHP yang banyak digunakan yaitu CodeIgniter (CI. Framework CI memang dikembangkan untuk memudahkan dalam developing aplikasi dengan struktur file source code-nya menggunakan pendekatan arsitektur Models-Views-Controller (MVC dan pemrograman berorientasi objek. Oleh sebab itu, kami menggunakan CI dalam developing aplikasi ini dengan metode Object Oriented Analysis and Design sebagai metode pengembangan system. Dengan dirancangnya sistem ini telah mempermudah pemilik toko dalam mengelola data pelanggan, supplier dan barang yang di beli dan di jual serta pembuatan laporan yang diperlukan untuk perhitungan penjualan dan dapat memberikan informasi yang berguna bagi pemilik toko secara up to date. Kata kunci: codeigniter (CI, models-views-controller (MVC, object oriented, penjualan.

  16. Regulation of notochord-specific expression of Ci-Bra downstream genes in Ciona intestinalis embryos.

    Science.gov (United States)

    Takahashi, Hiroki; Hotta, Kohji; Takagi, Chiyo; Ueno, Naoto; Satoh, Nori; Shoguchi, Eiichi

    2010-02-01

    Brachyury, a T-box transcription factor, is expressed in ascidian embryos exclusively in primordial notochord cells and plays a pivotal role in differentiation of notochord cells. Previously, we identified approximately 450 genes downstream of Ciona intestinalis Brachyury (Ci-Bra), and characterized the expression profiles of 45 of these in differentiating notochord cells. In this study, we looked for cisregulatory sequences in minimal enhancers of 20 Ci-Bra downstream genes by electroporating region within approximately 3 kb upstream of each gene fused with lacZ. Eight of the 20 reporters were expressed in notochord cells. The minimal enchancer for each of these eight genes was narrowed to a region approximately 0.5-1.0-kb long. We also explored the genome-wide and coordinate regulation of 43 Ci-Bra-downstream genes. When we determined their chromosomal localization, it became evident that they are not clustered in a given region of the genome, but rather distributed evenly over 13 of the 14 pairs of chromosomes, suggesting that gene clustering does not contribute to coordinate control of the Ci-Bra downstream gene expression. Our results might provide Insights Into the molecular mechanisms underlying notochord formation in chordates.

  17. Cu-Doping Effects in CdI(2) Nanocrystals: The Role of Cu-Agglomerates.

    Science.gov (United States)

    Miah, M Idrish

    2008-11-22

    Cu-doping effects in CdI(2) nanocrystals are studied experimentally. We use the photostimulated second harmonic generation (PSSHG) as a tool to investigate the effects. It is found that the PSSHG increases with increasing Cu content up to 0.6% and then decreases due to the formation of the Cu-agglomerates. The PSSHG for the crystal with Cu content higher than 1% reduces to that for the undoped CdI(2) crystal. The results suggest that a crucial role of the Cu-metallic agglomerates is involved in the processes as responsible for the observed effects.

  18. Cu-Doping Effects in CdI2Nanocrystals: The Role of Cu-Agglomerates

    Directory of Open Access Journals (Sweden)

    Miah M

    2008-01-01

    Full Text Available Abstract Cu-doping effects in CdI2nanocrystals are studied experimentally. We use the photostimulated second harmonic generation (PSSHG as a tool to investigate the effects. It is found that the PSSHG increases with increasing Cu content up to 0.6% and then decreases due to the formation of the Cu-agglomerates. The PSSHG for the crystal with Cu content higher than 1% reduces to that for the undoped CdI2crystal. The results suggest that a crucial role of the Cu-metallic agglomerates is involved in the processes as responsible for the observed effects.

  19. Atomistic models of Cu diffusion in CuInSe2 under variations in composition

    Science.gov (United States)

    Sommer, David E.; Dunham, Scott T.

    2018-03-01

    We construct an analytic model for the composition dependence of the vacancy-mediated Cu diffusion coefficient in undoped CuInSe2 using parameters from density functional theory. The applicability of this model is supported numerically with kinetic lattice Monte Carlo and Onsager transport tensors. We discuss how this model relates to experimental measurements of Cu diffusion, arguing that our results can account for significant contributions to the bulk diffusion of Cu tracers in non-stoichiometric CuInSe2.

  20. Combustion Homogeneity and Emission Analysis during the Transition from CI to HCCI for FACE I Gasoline

    KAUST Repository

    Vedharaj, S.

    2017-10-10

    Low temperature combustion concepts are studied recently to simultaneously reduce NOX and soot emissions. Optical studies are performed to study gasoline PPC in CI engines to investigate in-cylinder combustion and stratification. It is imperative to perform emission measurements and interpret the results with combustion images. In this work, we attempt to investigate this during the transition from CI to HCCI mode for FACE I gasoline (RON = 70) and its surrogate, PRF70. The experiments are performed in a single cylinder optical engine that runs at a speed of 1200 rpm. Considering the safety of engine, testing was done at lower IMEP (3 bar) and combustion is visualized using a high-speed camera through a window in the bottom of the bowl. From the engine experiments, it is clear that intake air temperature requirement is different at various combustion modes to maintain the same combustion phasing. While a fixed intake air temperature is required at HCCI condition, it varies at PPC and CI conditions between FACE I gasoline and PRF70. Three zones are identified 1) SOI = -180 to -80 CAD (aTDC) is HCCI zone 2) SOI = -40 to -20 CAD (aTDC) is PPC zone 3) After SOI = -15 CAD (aTDC) is CI zone. Combustion duration, ignition delay, start of combustion and CA90 (crank angle at which 90% of fuel burnt) are comparable between FACE I gasoline and PRF70. The combustion images show a prominent soot flame at CI condition, while only blue coloured premixed flames are visible at PPC condition for both the fuels. PRF70 seems to have a pronounced premixed effect when compared to FACE I gasoline at early injections, showing a decreased level of stratification. NOX emission and soot concentration decreases from CI condition and attains a constant zero value at HCCI condition for both FACE I gasoline and PRF70. CO and CO2 emissions matches between FACE I gasoline and PRF70 at PPC and CI condition, while CO emission is lower for PRF70 at HCCI condition.

  1. Combustion Homogeneity and Emission Analysis during the Transition from CI to HCCI for FACE I Gasoline

    KAUST Repository

    Vedharaj, S.; Vallinayagam, R; An, Yanzhao; Izadi Najafabadi, Mohammad; Somers, Bart; Chang, Junseok; Johansson, Bengt

    2017-01-01

    Low temperature combustion concepts are studied recently to simultaneously reduce NOX and soot emissions. Optical studies are performed to study gasoline PPC in CI engines to investigate in-cylinder combustion and stratification. It is imperative to perform emission measurements and interpret the results with combustion images. In this work, we attempt to investigate this during the transition from CI to HCCI mode for FACE I gasoline (RON = 70) and its surrogate, PRF70. The experiments are performed in a single cylinder optical engine that runs at a speed of 1200 rpm. Considering the safety of engine, testing was done at lower IMEP (3 bar) and combustion is visualized using a high-speed camera through a window in the bottom of the bowl. From the engine experiments, it is clear that intake air temperature requirement is different at various combustion modes to maintain the same combustion phasing. While a fixed intake air temperature is required at HCCI condition, it varies at PPC and CI conditions between FACE I gasoline and PRF70. Three zones are identified 1) SOI = -180 to -80 CAD (aTDC) is HCCI zone 2) SOI = -40 to -20 CAD (aTDC) is PPC zone 3) After SOI = -15 CAD (aTDC) is CI zone. Combustion duration, ignition delay, start of combustion and CA90 (crank angle at which 90% of fuel burnt) are comparable between FACE I gasoline and PRF70. The combustion images show a prominent soot flame at CI condition, while only blue coloured premixed flames are visible at PPC condition for both the fuels. PRF70 seems to have a pronounced premixed effect when compared to FACE I gasoline at early injections, showing a decreased level of stratification. NOX emission and soot concentration decreases from CI condition and attains a constant zero value at HCCI condition for both FACE I gasoline and PRF70. CO and CO2 emissions matches between FACE I gasoline and PRF70 at PPC and CI condition, while CO emission is lower for PRF70 at HCCI condition.

  2. Przyczynek do postrzegania struktury współczesnego systemu rachunkowości

    Directory of Open Access Journals (Sweden)

    Irena Sobańska

    2018-03-01

    Full Text Available Głównym celem artykułu jest objaśnienie procesu ewoluowania elementów systemu rachunkowości organizacji gospodarczej pod wpływem zmian zachodzących w różnicach informacji oczekiwanych przez odbiorców wewnętrznych i zewnętrznych. Dla zrealizowania tego celu przedstawiono zamęt regu- lacyjny w obszarze rachunkowości i jego skutki dla rozwoju systemów rachunkowości w praktyce w Polsce oraz przeanalizowano zmiany w potrzebach informacyjnych interesariuszy w kontekście wprowadzanych zmian w sprawozdaniach finansowych, zintegrowanych raportach biznesowych i zmian w stosowanych metodach rachunkowości zarządczej w organizacjach społecznie odpowiedzialnych. Następnie przedsta- wiona została autorska propozycja nowej struktury systemu rachunkowości odpowiadająca jego współczesnej funkcjonalności w warunkach obecnego poziomu rozwoju globalizacji, zmierzającego w kierun- ku zrównoważonej gospodarki oraz szereg wniosków ogólnych wynikających z przedstawionych rozwa- żań. W propozycji nowej struktury przyjęto, że system rachunkowości organizacji społecznie odpowie- dzialnej powinien być zbudowany z podsystemu rachunkowości biznesowej, emitującego zintegrowany raport biznesowy (sprawozdanie finansowe + raporty niefinansowe i wewnętrzne raporty dla zarządu oraz podsystemu rachunkowości podatkowej, emitującego informacje dla agend podatkowych. W opra- cowaniu artykułu zastosowano analizę treści i opinii autorów wybranych publikacji, metodę analizy dokumentów oraz wiedzę uzyskaną metodą obserwacji bezpośredniej i wyniki badań empirycznych innych autorów. The main goal of the article is to explain the process of evolution of the organization's accounting system elements as a result of changes taking place in information expected by internal and external users. To achieve this goal, regulatory uncertainties in the area of accounting and their consequences for the devel- opment of accounting systems in

  3. Rola otyłości w patogenezie chorób alergicznych

    Directory of Open Access Journals (Sweden)

    Anna Grad

    2009-09-01

    Full Text Available W ostatnich latach wzrosła zachorowalność na astmę i inne choroby alergiczne. Jednocześnie obserwuje się zwiększenie liczby pacjentów z nadmierną masą ciała i podwyższoną wartością wskaźnika wagowo-wzrostowego (BMI. Wydaje się, że mimo odmiennego patomechanizmu astmy i otyłości istnieje wspólne ogniwo patogenetyczne rozwoju tych chorób. Bierze się pod uwagę rolę czynników środowiskowych, dietetycznych, genetycznych i infekcyjnych. Wyniki większości badań epidemiologicznych potwierdzają związek nadwagi i otyłości z ryzykiem wystąpienia astmy zarówno u osób dorosłych, jak i u dzieci. Podkreśla się rolę wysokiej urodzeniowej masy ciała i większych przyrostów masy ciała w pierwszym roku życia. Natomiast występowanie alergicznego nieżytu nosa i alergicznego zapalenia spojówek koreluje ujemnie z masą ciała. Nie obserwowano związku otyłości z częstością występowania atopowego zapalenia skóry. Tkanka tłuszczowa jako narząd endokrynny produkuje dużo różnych cytokin, hormonów, czynników wzrostu. Jest źródłem czynników prozapalnych, między innymi IL-6, TNF-a, TGF-b, leptyny, rezystyny. Leptyna jest produkowana przez adipocyty, jej stężenie koreluje z masą tkanki tłuszczowej, może ona intensyfikować zapalenie oraz odgrywać ważną rolę w rozwoju płuc. Podwyższone stężenie leptyny w surowicy jest uważane za czynnik prognostyczny rozwoju astmy. Adiponektyna ma właściwości przeciwzapalne, jej stężenie maleje w otyłości i koreluje ujemnie ze wskaź- nikiem BMI. W rozwoju astmy u osób otyłych biorą również udział rezystyna, eotaksyna, białko aP2 oraz żeńskie hormony płciowe. Rola czynników genetycznych nie jest do końca poznana. Dotychczas wyodrębniono 4 regiony chromosomalne związane ze zwiększoną podatnością na zachorowanie na astmę i otyłość. Efekt ochronny mają czynniki dietetyczne, takie jak antyoksydanty i mikroelementy. Otyłość pogarsza

  4. Rola otyłości w patogenezie chorób alergicznych

    Directory of Open Access Journals (Sweden)

    Anna Grad

    2008-10-01

    Full Text Available W ostatnich latach wzrosła zachorowalność na astmę i inne choroby alergiczne. Jednocześnie obserwuje się zwiększenie liczby pacjentów z nadmierną masą ciała i podwyższoną wartością wskaźnika wagowo-wzrostowego (BMI. Wydaje się, że mimo odmiennego patomechanizmu astmy i otyłości istnieje wspólne ogniwo patogenetyczne rozwoju tych chorób. Bierze się pod uwagę rolę czynników środowiskowych, dietetycznych, genetycznych i infekcyjnych. Wyniki większości badań epidemiologicznych potwierdzają związek nadwagi i otyłości z ryzykiem wystąpienia astmy zarówno u osób dorosłych, jak i u dzieci. Podkreśla się rolę wysokiej urodzeniowej masy ciała i większych przyrostów masy ciała w pierwszym roku życia. Natomiast występowanie alergicznego nieżytu nosa i alergicznego zapalenia spojówek koreluje ujemnie z masą ciała. Nie obserwowano związku otyłości z częstością występowania atopowego zapalenia skóry. Tkanka tłuszczowa jako narząd endokrynny produkuje dużo różnych cytokin, hormonów, czynników wzrostu. Jest źródłem czynników prozapalnych, między innymi IL-6, TNF-a, TGF-b, leptyny, rezystyny. Leptyna jest produkowana przez adipocyty, jej stężenie koreluje z masą tkanki tłuszczowej, może ona intensyfikować zapalenie oraz odgrywać ważną rolę w rozwoju płuc. Podwyższone stężenie leptyny w surowicy jest uważane za czynnik prognostyczny rozwoju astmy. Adiponektyna ma właściwości przeciwzapalne, jej stężenie maleje w otyłości i koreluje ujemnie ze wskaź- nikiem BMI. W rozwoju astmy u osób otyłych biorą również udział rezystyna, eotaksyna, białko aP2 oraz żeń- skie hormony płciowe. Rola czynników genetycznych nie jest do końca poznana. Dotychczas wyodrębniono 4 regiony chromosomalne związane ze zwiększoną podatnością na zachorowanie na astmę i otyłość. Efekt ochronny mają czynniki dietetyczne, takie jak antyoksydanty i mikroelementy. Otyłość pogarsza

  5. Conversational Memory Employing Cued and Free Recall.

    Science.gov (United States)

    Benoit, Pamela J.; Benoit, William L.

    1988-01-01

    Tests two hypotheses: (1) that cued recall elicits significantly more conversational information than free recall; and (2) that conversational interactants recall more of their partner's utterances than their own. Finds cued recall produced significantly higher amounts of remembering than free recall. (MS)

  6. Adsorption Properties of the Cu(115) Surface

    DEFF Research Database (Denmark)

    Godowski, P. J.; Groso, A.; Hoffmann, S. V.

    2010-01-01

    The interfaces: K/Cu(115) and CO/Cu(115) have been characterized using surface sensitive techniques, including low energy electron diffraction and photoelectron spectroscopy. K adatoms show tendency to occupy the sites close to the step edges. At low temperature (near 125 K), after completion of ...

  7. Magnetic excitations in CuO

    International Nuclear Information System (INIS)

    Ain, M.; Reichardt, W.; Hennion, B.; Pepy, G.; Wanklyn, B.M.

    1989-01-01

    The authors have studied the magnetic excitations of CuO both in the ordered and the paramagnetic phase. Their results demonstrate the dominance of the magnetic interaction along the 10-1 Cu-O zigzag chains. In this direction the slope of the acoustic branch is 550 neV Angstrom

  8. In-cylinder Combustion and Soot Evolution in the Transition from Conventional CI mode to PPC

    KAUST Repository

    An, Yanzhao

    2018-01-09

    The present study intends to explore the in-cylinder combustion and evolution of soot emission during the transition from conventional compression ignition (CI) combustion to partially premixed combustion (PPC) at low load conditions. In-cylinder combustion images and engine-out emissions were measured in an optical engine fueled with low octane heavy naphtha fuel (RON = 50). Full cycle engine simulations were performed using a three-dimensional computational fluid dynamics code CONVERGETM, coupled with gas phase chemical kinetics, turbulence, and particulate size mimic soot model. The simulations were performed under low load conditions (IMEP ~ 2 to 3 bar) at an engine speed of 1200 rpm. The start of injection (SOI) was advanced from late (-10 CAD aTDC) to early fuel injection timings (-40 CAD aTDC) to realize the combustion transition from CI combustion to PPC. The simulation results of combustion and emission are compared with the experimental results at both CI and PPC combustion modes. The results of the study show a typical low-temperature stratified lean combustion at PPC mode, while high-temperature spray-driven combustion is evident at CI mode. The in-cylinder small intermediates species such as acetylene (C2H2), propargyl (C3H3), cyclopentadienyl (C5H5) and polycyclic aromatic hydrocarbons (PAHs) were significantly suppressed at PPC mode. Nucleation reaction of PAHs collision contributed to main soot mass production. The distribution of soot mass and particle number density was consistent with the distribution of high-temperature zones at CI and PPC combustion modes.

  9. O modelo de Karl Popper sob a ótica das Ciências Sociais Aplicadas

    Directory of Open Access Journals (Sweden)

    Milton de Abreu Campanario

    2012-04-01

    Full Text Available DOI: http://dx.doi.org/10.5007/2175-8077.2012v14n32p124 Karl Popper é o principal filósofo da ciência na modernidade, disputando com Thomas Kuhn a primazia de interpretação do método científico. Claramente há diferentes visões para uma leitura desse importante autor que cunhou o método chamado de dedutivo com teste. O texto reconhece a relevância da visão de Karl Popperno desenvolvimento de trabalhos científicos das ciências exatas e biológicas, onde é amplamente aceita. No entanto, nota-se que essa formulação é pouco sistematizada na área das ciências sociais aplicadas. Este é um ensaio que busca resgatar a sua contribuição, numa tentativa de traduzir os conceitos por ele desenvolvidos de forma didática. Para tanto, será feita uma introdução aos fundamentos da ciência como forma específica de conhecimento, buscando contrastar os métodos dedutivo e indutivo e os procedimentos da ciência formal, básica e aplicada. Uma tentativa de classificar a formulação de proposições a serem testadas ou falseadas é feita com a utilização de diferentes critérios, utilizando exemplos da administração e da economia para ilustração.

  10. Ocena efektywności podziału subwencji oświatowej dla gmin

    Directory of Open Access Journals (Sweden)

    Jan Herczyński

    2016-06-01

    Full Text Available Celem przedstawionych analiz jest ocena dopasowania podziału pomiędzy gminy części oświatowej subwencji ogólnej do kosztów dostarczania usług edukacyjnych. W artykule zarysowano problematykę związaną z podziałem subwencji oświatowej pomiędzy gminy, opisano wagi stosowane w algorytmie podziału subwencji oświatowej, skoncentrowano się na zmianach wprowadzonych do algorytmu w 2015 r. i omówiono konsekwencje wynikające ze stosowania wag wiejskich, które mają stosunkowo duży wpływ na podział środków. W ostatniej części wprowadzono miarę nieefektywności algorytmu podziału części oświatowej subwencji ogólnej i zastosowano ją do oceny podziału środków subwencyjnych pomiędzy gminy. Miara ta pozwala m.in. ilościowo ocenić efekt zmian wprowadzonych do algorytmu w 2015 r. Zaproponowano możliwe korekty wag algorytmu pozwalające na redukcję nieefektywności i zjawiska tzw. przewrotnej motywacji organów prowadzących szkoły. W podsumowaniu przedstawiono główne wnioski wynikające z analiz.

  11. Cu and Cu2O films with semi-spherical particles grown by electrochemical deposition

    International Nuclear Information System (INIS)

    Zheng, Jin You; Jadhav, Abhijit P.; Song, Guang; Kim, Chang Woo; Kang, Young Soo

    2012-01-01

    Cu and Cu 2 O films can be prepared on indium-doped tin oxide glass substrates by simple electrodeposition in a solution containing 0.1 M Cu(NO 3 ) 2 and 3 M lactic acid at different pH values. At low pH (pH = 1.2), the uniform Cu films were obtained; when pH ≥ 7, the pure Cu 2 O films can be deposited. Especially, at pH = 11, the deposited Cu 2 O films exhibited cubic surface morphology exposing mainly {100} plane; in contrast, the films consisting of semi-spherical particles were obtained when the solution was being stirred for 2 weeks prior to use. The possible growth process and mechanism were comparatively discussed. - Highlights: ► Cu and Cu 2 O films were prepared by facile electrodeposition. ► Electrodeposition was preformed in electrolyte at different pH values. ► Dendritic Cu films were obtained at 1.2 pH with relatively high deposition potential. ► Semi-spherical Cu 2 O films were obtained with solution at 11 pH and stirred for 2 weeks. ► The possible growth mechanism of semi-spherical Cu 2 O films was discussed.

  12. Synthesis of Cu2O from CuO thin films: Optical and electrical properties

    Directory of Open Access Journals (Sweden)

    Dhanya S. Murali

    2015-04-01

    Full Text Available Hole conducting, optically transparent Cu2O thin films on glass substrates have been synthesized by vacuum annealing (5×10−6 mbar at 700 K for 1 hour of magnetron sputtered (at 300 K CuO thin films. The Cu2O thin films are p-type and show enhanced properties: grain size (54.7 nm, optical transmission 72% (at 600 nm and Hall mobility 51 cm2/Vs. The bulk and surface Valence band spectra of Cu2O and CuO thin films are studied by temperature dependent Hall effect and Ultra violet photo electron Spectroscopy (UPS. CuO thin films show a significant band bending downwards (due to higher hole concentration than Cu2O thin films.

  13. Interfacial Reaction of Sn-Ag-Cu Lead-Free Solder Alloy on Cu: A Review

    Directory of Open Access Journals (Sweden)

    Liu Mei Lee

    2013-01-01

    Full Text Available This paper reviews the function and importance of Sn-Ag-Cu solder alloys in electronics industry and the interfacial reaction of Sn-Ag-Cu/Cu solder joint at various solder forms and solder reflow conditions. The Sn-Ag-Cu solder alloys are examined in bulk and in thin film. It then examines the effect of soldering conditions to the formation of intermetallic compounds such as Cu substrate selection, structural phases, morphology evolution, the growth kinetics, temperature and time is also discussed. Sn-Ag-Cu lead-free solder alloys are the most promising candidate for the replacement of Sn-Pb solders in modern microelectronic technology. Sn-Ag-Cu solders could possibly be considered and adapted in miniaturization technologies. Therefore, this paper should be of great interest to a large selection of electronics interconnect materials, reliability, processes, and assembly community.

  14. Synthesis of Cu Nanoparticles Using Copper Carbonate as Cu Source Toward Versatile Applications.

    Science.gov (United States)

    Yano, Kazuhisa; Ishizaki, Toshitaka; Sugiyama, Hidehiko

    2018-07-01

    Cu nanoparticles (NPs) coated with polyvinylpyrrolidone (PVP) were fabricated by polyol method using copper carbonate as a raw material. To increase the reaction temperature, glycol multimers such as diethylene glycol, triethylene glycol, or tetraethylene glycol were examined as a solvent. With increasing degree of multimerization, average diameter of Cu NPs decreased. The synthesis of Cu NPs was further investigated by changing reaction temperature, the amount and molecular weight of PVP in triethylene glycol as a solvent. Average diameter and standard deviation of Cu NPs were found to be highly dependent on those factors. As a result, fine Cu NPs ranging from 28 to 67 nm in average size with narrow size distribution (standard deviation: 16-28%) were obtained. The obtained Cu NPs were applied to a nanofluid, which showed higher thermal conductivity than the theoretical value. The antibacterial activity of Cu NPs was also demonstrated, and found to have strong antibacterial activity.

  15. The maternal genes Ci-p53/p73-a and Ci-p53/p73-b regulate zygotic ZicL expression and notochord differentiation in Ciona intestinalis embryos.

    Science.gov (United States)

    Noda, Takeshi

    2011-12-01

    I isolated a Ciona intestinalis homolog of p53, Ci-p53/p73-a, in a microarray screen of rapidly degraded maternal mRNA by comparing the transcriptomes of unfertilized eggs and 32-cell stage embryos. Higher expression of the gene in eggs and lower expression in later embryonic stages were confirmed by whole-mount in situ hybridization (WISH) and quantitative reverse transcription-PCR (qRT-PCR); expression was ubiquitous in eggs and early embryos. Knockdown of Ci-p53/p73-a by injection of antisense morpholino oligonucleotides (MOs) severely perturbed gastrulation cell movements and expression of notochord marker genes. A key regulator of notochord differentiation in Ciona embryos is Brachyury (Ci-Bra), which is directly activated by a zic-like gene (Ci-ZicL). The expression of Ci-ZicL and Ci-Bra in A-line notochord precursors was downregulated in Ci-p53/p73-a knockdown embryos. Maternal expression of Ci-p53/p73-b, a homolog of Ci-p53/p73-a, was also detected. In Ci-p53/p73-b knockdown embryos, gastrulation cell movements, expression of Ci-ZicL and Ci-Bra in A-line notochord precursors, and expression of notochord marker gene at later stages were perturbed. The upstream region of Ci-ZicL contains putative p53-binding sites. Cis-regulatory analysis of Ci-ZicL showed that these sites are involved in expression of Ci-ZicL in A-line notochord precursors at the 32-cell and early gastrula stages. These results suggest that p53 genes are maternal factors that play a crucial role in A-line notochord differentiation in C. intestinalis embryos by regulating Ci-ZicL expression. Copyright © 2011 Elsevier Inc. All rights reserved.

  16. Ocena możliwości implementacji standardów IPSAS do systemu rachunkowości podmiotów sektora publicznego w Polsce

    Directory of Open Access Journals (Sweden)

    Aleksandra Szewieczek

    2017-09-01

    Full Text Available Ocena możliwości implementacji standardów IPSAS do systemu rachunkowości podmiotów sektora publicznego w Polsce In recent years, there has been a noticeable increase in activity in the field of standardization of public sector accounting, which has an international scope and takes the form of the International Public Sector Accounting Standards (IPSAS. It has been planned that the EU Member States, and consequently Poland, will implement obligatory uniform accounting standards in the public sector – EPSAS – which are to be largely based on the content of IPSAS. The purpose of this paper is to assess the possibilities and factors of IPSAS implementation in the accounting system of public finance sector entities in Poland in relation to the currently applicable accounting regulations and the intelligibility criterion for potential users. The assessment was carried out based on a study of the foreign and domestic literature and existing legislation, while for the conclusions, the deductive and synthetic methods were used. The paper demonstrates that despite the relatively long period of operation of IPSAS, their level of implementation into the accounting system of public sector entities in Poland is negligible. The same applies to the works on the European standards, EPSAS, which have been significantly delayed in relation to the original assumptions. Knowledge of international standards is weak, and consequently their dissemination too. In spite of IPSAS implementation problems, there are still a number of reasons for their use. One of the arguments in favor of introducing uniform standards on the European market is the fact that the common market is in operation, and another one is the strong embedding of the need to consolidate the public sector’s international financial data at the central level of the Community. The conducted research confirmed the possibility of implementing IPSAS into Polish public sector entities’ accounting

  17. Olfactory cuing of autobiographical memory.

    Science.gov (United States)

    Rubin, D C; Groth, E; Goldsmith, D J

    1984-01-01

    In Experiment 1, subjects were presented with either the odors or the names of 15 common objects. In Experiment 2, subjects were presented with either the odors, photographs, or names of 16 common objects. All subjects were asked to describe an autobiographical memory evoked by each cue, to date each memory, and to rate each memory on vividness, pleasantness, and the number of times that the memory had been thought of and talked about prior to the experiment. Compared with memories evoked by photographs or names, memories evoked by odors were reported to be thought of and talked about less often prior to the experiment and were more likely to be reported as never having been thought of or talked about prior to the experiment. No other effects were consistently found, though there was a suggestion that odors might evoke more pleasant and emotional memories than other types of cues. The relation of these results to the folklore concerning olfactory cuing is discussed.

  18. ANALIZA PRACY INSTALACJI FOTOWOLTAICZNEJ W ZALEŻNOŚCI OD ORIENTACJI GEOGRAFICZNEJ

    Directory of Open Access Journals (Sweden)

    Ewelina KRAWCZAK

    Full Text Available Rynek odnawialnych źródeł energii z każdym dniem coraz bardziej się rozwija. Zapotrzebowanie na energię elektryczną wzrasta, przy czym zasoby konwencjonalnych i zarazem nieodnawialnych źródeł energii (paliw kopalnych ulegają zubożeniu. Alternatywą dla nich są odnawialne źródła energii (OZE, których rezerwy uzupełniane są w naturalnych procesach ekosystemu, co stanowi o ich niewyczerpalności. Zmiany legislacyjne w Polsce dotyczące OZE spowodowały duże zainteresowanie małymi instalacjami fotowoltaicznymi w wyniku czego dotychczasowy konsument zmienia się w prosumenta energii elektrycznej. Rozwój rynku odnawialnych źródeł energii stawia przed projektantami ciągłe wyzwania, ponieważ projektowanie instalacji fotowoltaicznych o wysokiej wydajności dla istniejących budynków, przy uwzględnieniu występujących lokalnych warunków oraz architektury budowli, jest niezwykle trudne. Uzysk energetyczny systemu słonecznego zależy od wielu czynników, jednym z najważniejszych jest wartość nasłonecznienia zależna od lokalizacji (szerokości geograficznej, a także orientacja projektowanego systemu względem kierunku azymutu. Narzędziem wspomagającym i usprawniającym projektowanie instalacji PV (Photovoltaics jest oprogramowanie DDS-CAD, pozwalające przeprowadzić symulację uzysków energii elektrycznej. Wyniki otrzymanych symulacji umożliwiają w krótkim czasie porównanie wielu wirtualnych modeli instalacji pod kątem wydajności, a co za tym idzie wybranie najkorzystniejszego wariantu dla istniejącej orientacji geograficznej. W niniejszej pracy poddane zostały analizie rezultaty symulacji wirtualnych modeli instalacji fotowoltaicznych pod względem liczby generatorów fotowoltaicznych oraz wielkości uzysku energii elektrycznej przy założeniu wykorzystania całej powierzchni dachu oraz uwzględnieniu zmiany kąta usytuowania modułów PV względem okapu połaci dachowej i kierunku azymutu.

  19. Entre "artes" e "ciências": a noção de performance e drama no campo das ciências socias

    Directory of Open Access Journals (Sweden)

    Rubens Alves da Silva

    2005-12-01

    Full Text Available Propõe-se neste artigo desenvolver uma reflexão teórica que está relacionada com as preocupações e propostas da área de estudos antropológicos das formas expressivas, focalizando, centralmente, a noção de performance e drama no campo das ciências sociais. Nesse sentido é que se busca, no momento, dialogar com os autores considerados representantes principais da discussão teórica em torno da noção de performance, drama e ritual no campo antropológico: Victor Turner, Clifford Geertz, Michael Taussig, Richard Schechner, John Dawsey - entre outros.This article attempts to develop a theoretical reflection on the aims and proposals in the area of the anthropological studies about the expressive forms, dealing with the concept of performance and drama in the social sciences. Taking this into consideration, this work intends to discuss the ideas of the most important authors in the theoretical debate concerning the concept of performance, drama and ritual in the anthropological field: Victor Turner, Clifford Geertz, Michael Taussig, Richard Schechner, John Dawsey - and others.

  20. Effect of 67Cu and 99Mo labeled tetrathiomolybdate on the distribution of 67Cu, Cu, and 99Mo in bile fractions in sheep

    International Nuclear Information System (INIS)

    Gooneratne, R.; Laarveld, B.; Christensen, D.

    1989-01-01

    The effect of intravenous administration of 67 Cu and 99 Mo labeled tetrathiomolybdate (TTM) on the appearance of 67 Cu, stable Cu, and 99 Mo in gel chromatographic fractions of bile was examined in sheep fed either 5 or 35 mg Cu kg-1 DM. Peak excretory periods of biliary 67 Cu, stable Cu, and 99 Mo were observed at 30 min-1.25 hr, 2-3 hr, and 11-13 hr after 67 Cu and after 99 Mo labeled TTM. Sephadex G-75 gel filtration of bile samples collected at 1, 3, and 12 hr after 67 Cu administration revealed two major protein peaks of molecular weights of greater than 80,000 (peak I) and 7,000 (peak II) containing both 67 Cu and Cu. But the ratio of 67 Cu in the two peaks varied with time of bile collection. The ratio of areas of peak I:II 1 hr after 67 Cu administration was approximately 0.48; at 3 hr, 0.62, and at 12 hr 1.35. Tetrathiomolybdate administration increased both 67 Cu and stable Cu in bile by severalfold and induced a major shift of Cu into the higher molecular weight protein fraction. The experiments confirm the effectiveness of TTM as a ''decoppering'' agent. Furthermore, TTM not only promoted bile Cu excretion, but it also increased the incorporation of Cu into the macromolecular fraction. This may limit enterohepatic circulation of biliary Cu and thereby cause an overall Cu depletion and a negative Cu balance

  1. Cu-62, Cu-64 and Cu-66 production with 4.2 MeV deuterons; Produccion de {sup 62} Cu y {sup 64} Cu con deuterones de 4,2 MeV

    Energy Technology Data Exchange (ETDEWEB)

    Avila, Mario; Morales, J R; Riquelme, H O [Chile Univ., Santiago (Chile). Facultad de Ciencias. Dept. de Fisica

    1997-12-31

    Full text: The natural copper irradiation with deuterons produces the Cu-62, Cu-64 and Cu-66 radionuclides. Of two radioisotopes, those with deficiencies in neutrons, are applied in nuclear medicine diagnostic processes, mainly for the nuclear characteristic of the decay modes. The positron emitters, of short life mean Cu-62 (9.1 min, {beta}{sup +}) and Cu(12.7 h), are radionuclides applied in radio pharmacological preparation for brain, core, blood flux studies. The radiochemical process consists in the de solution of the irradiated metallic copper target, in acid medium. The result solution, can be neutralized with a base or a buffer at wished pH. Using a deuteron beam of 4,2 {+-} 0,1 MeV energy has been obtained total yields of 1,103 {+-} 0,011 {mu}Cl/{mu}Ah medium for 62 Cu and of 0,148 {+-} 0,015 {mu}Cl/{mu}Ah for 64 Cu.

  2. Concurrent validity of the Wheeler signs of homosexuality in the Rorschach: P (Ci/Rj).

    Science.gov (United States)

    Stone, N M; Schneider, R E

    1975-12-01

    The Rorschach protocols of 43 males consecutively admitted to a university outpatient clinic were scored for frequency of the 20 Wheeler signs of homosexuality. Based on case history data, patients were assigned to homosexual, sex-role disturbed, or normal-control groups. In addition to the traditional group comparison the results were analyzed to yield P (Ci/Rj); that is, the probability of criterion group membership given test indicator. Both the homosexual and sex-role disturbed group displayed significantly more Wheeler signs than normals. Furthermore, given a Wheeler sign score of 15%, .75 of the predicted-homosexual group would be correctly classified compared to a .21 baserate prediction. It was suggested that expressing results as P (Ci/Rj) provides information more relevant to the clinician than is provided by the traditional practice of reporting significant differences between groups.

  3. Aktywność fizyczna w terapii otyłości

    Directory of Open Access Journals (Sweden)

    Joanna Zapolska

    2009-03-01

    Full Text Available Otyłość jest chorobą określaną jako patologiczne zwiększenie ilości tkanki tłuszczowej, która w nadmiernej ilości wpływa negatywnie na stan zdrowia, długość życia i sprawność psychofizyczną. Osoby z nadmierną masą ciała, w której zawartość tłuszczu stanowi proporcjonalnie wysoki odsetek, w porównaniu z osobami o niższej masie ciała są fizjologicznie mniej wydolni, a ich potencjał motoryczny jest niższy. W otyłości u osób dorosłych dochodzi przede wszystkim do zwiększenia rozmiarów komórek tłuszczowych. W przypadku dzieci obserwujemy przyrost liczby komórek tłuszczowych, które mogą się przyczynić do rozwoju otyłości w wieku dorosłym, gdyż zwiększenie liczby komórek jest procesem nieodwracalnym. Często rodzice aż do momentu wystąpienia znacznej otyłości nie postrzegają nadmiernej masy ciała dziecka w kategoriach problemu zdrowotnego. Istotna staje się więc rola służby zdrowia w prowadzeniu działań prewencyjnych, skierowanych na działania np. fitness clubów odpowiednio przygotowanych do podejmowania tego typu zadań. Ogólnie przyjęte zasady dawkowania ćwiczeń w treningu zdrowotnym fitness osób dorosłych oraz dzieci i młodzieży są podobne. Różnią się czasem trwania, częstotliwością podejmowania aktywności oraz stosowanymi obciążeniami. Treningi fitness obejmują głównie wytrzymałościowe formy ćwiczeń, takie jak ćwiczenia aerobowe na urządzeniach typu cardio mające za zadanie przede wszystkim uaktywnić i zredukować nadmiar tkanki tłuszczowej. Inną formą zajęć usprawniających powinny być ćwiczenia oporowe uwzględniające stosowanie urządzeń izotonicznych. Należy przy tym zwrócić szczególną uwagę na dobór ćwiczeń, obciążenie oraz kontrolę postępów. Równocześnie zaleca się stosowanie monitoringu zakresów HR każdej sesji treningu aerobowego i oporowego. Jako uzupełnienie proponowane są ćwiczenia gibkościowe wykonywane jako

  4. Biosorption of C.I. Direct Blue 199 from aqueous solution by nonviable Aspergillus niger

    Energy Technology Data Exchange (ETDEWEB)

    Xiong Xiaojing, E-mail: xiongxj@xmu.edu.cn [Environmental Science Research Center, State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen 361005 (China); Meng Xuejiao [Environmental Science Research Center, State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen 361005 (China); Zheng Tianling [Environmental Science Research Center, State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen 361005 (China); Key Laboratory of Ministry of Education for Coast and Wetland Ecosystems, School of Life Sciences, Xiamen University, Xiamen 361005 (China)

    2010-03-15

    The capacity and mechanism with which nonviable Aspergillus niger removed the textile dye, C.I. Direct Blue 199, from aqueous solution was investigated using different parameters, such as initial dye concentration, pH and temperature. In batch experiments, the biosorption capacity increased with decrease in pH, and the maximum dye uptake capacity of the biosorbent was 29.96 mg g{sup -1} at 400 mg L{sup -1} dye concentration and 45 deg. C. The Langmuir and Freundlich models were able to describe the biosorption equilibrium of C.I. Direct Blue 199 onto the fungal biomass. Biosorption followed a pseudo-second order kinetic model with high correlation coefficients (r{sup 2} > 0.99). Thermodynamic studies revealed that the biosorption process was successful, spontaneous and endothermic in nature.

  5. Narrativas históricas: gravidade, sistemas de mundo e natureza da ciência

    Directory of Open Access Journals (Sweden)

    Juliana M. Hidalgo F. Drummond

    2015-04-01

    Full Text Available http://dx.doi.org/10.5007/2175-7941.2015v32n1p99 De acordo com o entendimento de que o ensinar ciência e o ensinar sobre a ciência não devem estar dissociados, apresenta-se um conjunto de narrativas históricas para utilização no Ensino Médio, tecendo considerações sobre os recortes históricos procedidos e as escolhas implementadas em sua elaboração. Procura-se chamar a atenção para as potencialidades, possibilidades e limitações das narrativas. Esses pontos remetem explicitamente a reflexões relacionadas a uma utilização flexível, tendo em vista particularidades dos contextos educacionais.

  6. Biosorption of C.I. Direct Blue 199 from aqueous solution by nonviable Aspergillus niger

    International Nuclear Information System (INIS)

    Xiong Xiaojing; Meng Xuejiao; Zheng Tianling

    2010-01-01

    The capacity and mechanism with which nonviable Aspergillus niger removed the textile dye, C.I. Direct Blue 199, from aqueous solution was investigated using different parameters, such as initial dye concentration, pH and temperature. In batch experiments, the biosorption capacity increased with decrease in pH, and the maximum dye uptake capacity of the biosorbent was 29.96 mg g -1 at 400 mg L -1 dye concentration and 45 deg. C. The Langmuir and Freundlich models were able to describe the biosorption equilibrium of C.I. Direct Blue 199 onto the fungal biomass. Biosorption followed a pseudo-second order kinetic model with high correlation coefficients (r 2 > 0.99). Thermodynamic studies revealed that the biosorption process was successful, spontaneous and endothermic in nature.

  7. CI therapy is beneficial to patients which chronic low-functioning hemiparesis after stroke

    Directory of Open Access Journals (Sweden)

    Annette eSterr

    2014-10-01

    Full Text Available CI therapy is effective in patients with relatively good levels of residual arm function but its applicability to patients with low functioning hemiparesis is not entirely clear. In the present study we examined the feasibility and efficacy of the CI therapy concept in patients with very limited upper arm function prior to treatment, and further tested how the length of daily shaping training and constraining the good arm affects treatment outcome. In a baseline-controlled design, 65 chronic patients were treated with 2 weeks of modified CI therapy. Patients were randomly allocated to four treatment groups receiving 90 or 180 minutes of daily shaping training applied with or without constraint respectively. Outcome was measured through the Reliable Change Index, which was calculated for parameters of motor function, health and psychological wellbeing. Follow-up data were collected at 6 and 12 months. Two analyses were conducted, a whole-group analysis across all 65 participants and a subgroup analysis contrasting the four treatment variants.The whole-group analysis showed a significant treatment effect, which was largely sustained after one year. The subgroup analysis revealed a mixed picture: while improvements against the baseline period were observed in all four subgroups, 180 minutes of daily shaping training coupled with the constraint yielded better outcome on the MAL but not the WMFT, while for 90 minutes of training the level of improvement was similar for those who wore the constraint and those who did not. Together these results suggest that, at least in those patients available for follow up measures, modified CI therapy induces sustained improvements in motor function in patients with chronic low-functioning hemiparesis. The absence of clear differences between the four treatment variants points to a complex relationship between the length of daily shaping training and the constraint in this patient group which is likely to be

  8. Time course of auditory streaming: Do CI users differ from normal-hearing listeners?

    Directory of Open Access Journals (Sweden)

    Martin eBöckmann-Barthel

    2014-07-01

    Full Text Available In a complex acoustical environment with multiple sound sources the auditory system uses streaming as a tool to organize the incoming sounds in one or more streams depending on the stimulus parameters. Streaming is commonly studied by alternating sequences of signals. These are often tones with different frequencies. The present study investigates stream segregation in cochlear implant (CI users, where hearing is restored by electrical stimulation of the auditory nerve. CI users listened to 30-s long sequences of alternating A and B harmonic complexes at four different fundamental frequency separations, ranging from 2 to 14 semitones. They had to indicate as promptly as possible after sequence onset, if they perceived one stream or two streams and, in addition, any changes of the percept throughout the rest of the sequence. The conventional view is that the initial percept is always that of a single stream which may after some time change to a percept of two streams. This general build-up hypothesis has recently been challenged on the basis of a new analysis of data of normal-hearing listeners which showed a build-up response only for an intermediate frequency separation. Using the same experimental paradigm and analysis, the present study found that the results of CI users agree with those of the normal-hearing listeners: (i the probability of the first decision to be a one-stream percept decreased and that of a two-stream percept increased as Δf increased, and (ii a build-up was only found for 6 semitones. Only the time elapsed before the listeners made their first decision of the percept was prolonged as compared to normal-hearing listeners. The similarity in the data of the CI user and the normal-hearing listeners indicates that the quality of stream formation is similar in these groups of listeners.

  9. History of Met Lab Section C-I, May 1943 to April 1944

    International Nuclear Information System (INIS)

    Seaborg, G.T.

    1978-05-01

    This is part of a history of the research work of Seaborg and associates in the University of Chicago Metallurgical Laboratory, Chemistry Section C-I. The work was concerned with the development of chemical procedures for the extraction of plutonium, for the purification of plutonium, and for research on the isotopes of other heavy elements including other transuranium elements. The style of the history is that of a diary with footnotes giving additional information

  10. Experimental evaluation of C.I. engine performance using diesel blended with Jatropha biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Sunil [Mechanical Department, R. G. P. V. Bhopal (M.P.) (India); Chaube, Alok [Mechanical Department, Jabalpur Engineering College Jabalpur (M.P.) (India); Jain, Shashi Kumar [School of Energy and Environment Management, R.G.P.V. Bhopal (India)

    2012-07-01

    Costlier and depleting fossil fuels are prompting researchers to use edible as well as non-edible vegetable oils as promising alternative to petro-diesel. The higher viscosity of vegetable oils leads to problem in pumping, atomization and spray characteristics. The improper mixing of vegetable oils with air leads to incomplete combustion. The best way to use vegetable oils as fuel in compression ignition (CI) engines is to convert it into biodiesel. Biodiesel is a methyl or ethyl ester of fatty acids made from vegetable oils (both edible and non-edible) and animal fat. The main feedstock for biodiesel production can be non-edible oil obtained from Jatropha curcas plant. Jatropha curcas plant can be cultivated on different terrains in India under extreme climatic conditions. Biodiesel can be used in its pure form or as a blend with petro-diesel in different proportions. It is being used in CI engines because it has properties similar to petro-diesel. The aim of this paper is to analyze suitability of petro-diesel blended with biodiesel in varying proportions in CI engines. For this purpose, a stationary single-cylinder four-stroke CI engine was tested with diesel blended with Jatropha biodiesel in 0%, 5%, 20%, 50%, 80% and 100%. Comparative measures of specific fuel consumption (SFC), brake thermal efficiency, smoke opacity, HC, CO2, CO, O2, NOX have been presented and discussed. Engine performance in terms of comparable brake thermal efficiency and SFC with lower emissions (HC, CO2, CO) was observed with B20 fuel compared to petro-diesel. Volumetric efficiency showed almost no variation for all the blends. Important observations related to noise and vibrations during testing have also been discussed.

  11. Apical Polarity Protein PrkCi Is Necessary for Maintenance of Spinal Cord Precursors in Zebrafish

    OpenAIRE

    Roberts, Randolph K.; Appel, Bruce

    2009-01-01

    During development, neural precursors divide to produce new precursors and cells that differentiate as neurons and glia. In Drosophila, apicobasal polarity and orientation of the mitotic spindle play important roles in specifying the progeny of neural precursors for different fates. We examined orientation of zebrafish spinal cord precursors using time-lapse imaging and tested the function of protein kinase C, iota (PrkCi), a member of the Par complex of proteins necessary for apicobasal pola...

  12. Klozapina: między skutecznością a bezpieczeństwem

    Directory of Open Access Journals (Sweden)

    Tomasz Sobów

    2015-07-01

    Full Text Available Klozapina, choć uważana za bardzo skuteczny lek przeciwpsychotyczny, jest stosowana rzadziej, niż wynikałoby z przesłanek klinicznych wspierających jej stosowanie. Co najmniej 1/3 chorych ze schizofrenią spełnia kliniczne kryteria lekooporności, charakteryzuje się wysokim ryzykiem samobójstwa lub reaguje nasilonymi objawami pozapiramidowymi na inne leki przeciwpsychotyczne. Możliwym powodem relatywnie rzadkiego sięgania po klozapinę w praktyce klinicznej jest postrzeganie leku jako obarczonego poważnymi objawami niepożądanymi. Agranulocytoza i inne dyskrazje krwi są dobrze znane, a zasady prewencji – uporządkowane zaleceniami. O innych objawach niepożądanych, również tych potencjalnie niebezpiecznych (kardiomiopatia, zapalenia mięśnia sercowego, niedrożność jelit czy drgawki wiadomo mniej. Ryzyko wystąpienia groźnych powikłań kuracji klozapiną można jednak zminimalizować, a same powikłania – wykrywać i leczyć, pod warunkiem zachowania czujności diagnostycznej. Świadomość ryzyka i korzyści związanych ze stosowaniem klozapiny to warunek konieczny skutecznego i bezpiecznego użycia tego leku oraz pełnego wykorzystania jego niezwykłych właściwości.

  13. History of Met Lab Section C-I, May 1943 to April 1944

    Energy Technology Data Exchange (ETDEWEB)

    Seaborg, G.T.

    1978-05-01

    This is part of a history of the research work of Seaborg and associates in the University of Chicago Metallurgical Laboratory, Chemistry Section C-I. The work was concerned with the development of chemical procedures for the extraction of plutonium, for the purification of plutonium, and for research on the isotopes of other heavy elements including other transuranium elements. The style of the history is that of a diary with footnotes giving additional information. (DLC)

  14. TravisTorrent : Synthesizing Travis CI and GitHub for Full-Stack Research on Continuous Integration

    NARCIS (Netherlands)

    Beller, M.M.; Gousios, Giorgos; Zaidman, A.E.

    2017-01-01

    Continuous Integration (CI) has become a best practice of modern software development. Thanks in part to its tight integration with GitHub, Travis CI has emerged as arguably the most widely used CI platform for Open-Source Software (OSS) development. However, despite its prominent role in Software

  15. Preoperative apolipoprotein CI levels correlate positively with the proinflammatory response in patients experiencing endotoxemia following elective cardiac surgery

    NARCIS (Netherlands)

    Schippers, E.F.; Berbée, J.F.P.; Disseldorp, I.M. van; Versteegh, M.I.M.; Havekes, L.M.; Rensen, P.C.N.; Dissel, J.T. van

    2008-01-01

    Objective: Experimental models show that apolipoprotein CI (apoCI) binds and enhances the inflammatory response to endotoxin. We studied in patients undergoing cardiopulmonary bypass surgery (CPB) and experiencing endotoxemia during reperfusion whether plasma apoCI levels correlate with the

  16. Species dependence of [64Cu]Cu-Bis(thiosemicarbazone) radiopharmaceutical binding to serum albumins

    International Nuclear Information System (INIS)

    Basken, Nathan E.; Mathias, Carla J.; Lipka, Alexander E.; Green, Mark A.

    2008-01-01

    Introduction: Interactions of three copper(II) bis(thiosemicarbazone) positron emission tomography radiopharmaceuticals with human serum albumin, and the serum albumins of four additional mammalian species, were evaluated. Methods: 64 Cu-labeled diacetyl bis(N 4 -methylthiosemicarbazonato)copper(II) (Cu-ATSM), pyruvaldehyde bis(N 4 -methylthiosemicarbazonato)copper(II) (Cu-PTSM) and ethylglyoxal bis(thiosemicarbazonato)copper(II) (Cu-ETS) were synthesized and their binding to human, canine, rat, baboon and porcine serum albumins quantified by ultrafiltration. Protein binding was also measured for each tracer in human, porcine, rat and mouse serum. Results: The interaction of these neutral, lipophilic copper chelates with serum albumin is highly compound- and species-dependent. Cu-PTSM and Cu-ATSM exhibit particularly high affinity for human serum albumin (HSA), while the albumin binding of Cu-ETS is relatively insensitive to species. At HSA concentrations of 40 mg/ml, '% free' (non-albumin-bound) levels of radiopharmaceutical were 4.0±0.1%, 5.3±0.2% and 38.6±0.8% for Cu-PTSM, Cu-ATSM and Cu-ETS, respectively. Conclusions: Species-dependent variations in radiopharmaceutical binding to serum albumin may need to be considered when using animal models to predict the distribution and kinetics of these compounds in humans

  17. Facile synthesis of dendritic Cu by electroless reaction of Cu-Al alloys in multiphase solution

    Science.gov (United States)

    Wang, Ying; Liang, Shuhua; Yang, Qing; Wang, Xianhui

    2016-11-01

    Two-dimensional nano- or micro-scale fractal dendritic coppers (FDCs) were synthesized by electroless immersing of Cu-Al alloys in hydrochloric acid solution containing copper chloride without any assistance of template or surfactant. The FDC size increases with the increase of Al content in Cu-Al alloys immersed in CuCl2 + HCl solution. Compared to Cu40Al60 and Cu45Al55 alloys, the FDC shows hierarchical distribution and homogeneous structures using Cu17Al83 alloy as the starting alloy. The growth direction of the FDC is , and all angles between the trunks and branches are 60°. Nanoscale Cu2O was found at the edge of FDC. Interestingly, nanoporous copper (NPC) can also be obtained through Cu17Al83 alloy. Studies showed that the formation of FDC depended on two key factors: the potential difference between CuAl2 intermetallic and α-Al phase of dual-phase Cu-Al alloys; a replacement reaction that usually occurs in multiphase solution. The electrochemical experiment further proved that the multi-branch dendritic structure is very beneficial to the proton transfer in the process of catalyzing methanol.

  18. Species dependence of [{sup 64}Cu]Cu-Bis(thiosemicarbazone) radiopharmaceutical binding to serum albumins

    Energy Technology Data Exchange (ETDEWEB)

    Basken, Nathan E. [Division of Nuclear Pharmacy, Department of Industrial and Physical Pharmacy, Purdue University, West Lafayette, IN 47907 (United States)], E-mail: nbasken@purdue.edu; Mathias, Carla J. [Division of Nuclear Pharmacy, Department of Industrial and Physical Pharmacy, Purdue University, West Lafayette, IN 47907 (United States); Lipka, Alexander E. [Department of Statistics, Purdue University, West Lafayette, IN 47907 (United States); Green, Mark A. [Division of Nuclear Pharmacy, Department of Industrial and Physical Pharmacy, Purdue University, West Lafayette, IN 47907 (United States)], E-mail: magreen@purdue.edu

    2008-04-15

    Introduction: Interactions of three copper(II) bis(thiosemicarbazone) positron emission tomography radiopharmaceuticals with human serum albumin, and the serum albumins of four additional mammalian species, were evaluated. Methods: {sup 64}Cu-labeled diacetyl bis(N{sup 4}-methylthiosemicarbazonato)copper(II) (Cu-ATSM), pyruvaldehyde bis(N{sup 4}-methylthiosemicarbazonato)copper(II) (Cu-PTSM) and ethylglyoxal bis(thiosemicarbazonato)copper(II) (Cu-ETS) were synthesized and their binding to human, canine, rat, baboon and porcine serum albumins quantified by ultrafiltration. Protein binding was also measured for each tracer in human, porcine, rat and mouse serum. Results: The interaction of these neutral, lipophilic copper chelates with serum albumin is highly compound- and species-dependent. Cu-PTSM and Cu-ATSM exhibit particularly high affinity for human serum albumin (HSA), while the albumin binding of Cu-ETS is relatively insensitive to species. At HSA concentrations of 40 mg/ml, '% free' (non-albumin-bound) levels of radiopharmaceutical were 4.0{+-}0.1%, 5.3{+-}0.2% and 38.6{+-}0.8% for Cu-PTSM, Cu-ATSM and Cu-ETS, respectively. Conclusions: Species-dependent variations in radiopharmaceutical binding to serum albumin may need to be considered when using animal models to predict the distribution and kinetics of these compounds in humans.

  19. IOTA interferometer observations of the B[e] star/X-ray transient object CI Cam.

    Science.gov (United States)

    Thureau, N. D.; Traub, W.; Millan-Gabet, R.; Monnier, J. D.; Pedretti, E.; Berger, J.-P.; Schloerb, P.

    2005-12-01

    We present the results from an observing campaign on the star CI Cam carried out at the IOTA interferometer in November-December 2004 using the IONIC 3 telescope beam combiner in the H spectral band with projected baselines in the range 10-36m. CI Cam is a known B[e] star and X-ray transient source and has been intensively observed since its powerful X-ray, radio and optical outburst occurred in April 1998. Our visibility measurements put strong constraints on the nature of the source and we can rule out all existing SED models available in the literature. Our new results are in agreement with previous observations of CI Cam obtained with IOTA2 in the H and K' spectral bands in September-November 1998, indicating the infrared excess is long-lived and not directly associated with the outburst. We have explored new models that can better fit our observations. Additionally, we have measured small non-zero closure phases which are the signature of asymmetries in the brightness distribution function. Financial support for NDT is provided by the European Commission through a Marie Curie Outgoing International Fellowships MOIF-CT-2004-002990.

  20. Emission Characteristics of a CI Engine Running with a Range of Biodiesel Feedstocks

    Directory of Open Access Journals (Sweden)

    Belachew Tesfa

    2014-01-01

    Full Text Available Currently, alternative fuels are being investigated in detail for application in compression ignition (CI engines resulting in exciting potential opportunities to increase energy security and reduce gas emissions. Biodiesel is one of the alternative fuels which is renewable and environmentally friendly and can be used in diesel engines with little or no modifications. The objective of this study is to investigate the effects of biodiesel types and biodiesel fraction on the emission characteristics of a CI engine. The experimental work was carried out on a four-cylinder, four-stroke, direct injection (DI and turbocharged diesel engine by using biodiesel made from waste oil, rapeseed oil, corn oil and comparing them to normal diesel. The fuels used in the analyses are B10, B20, B50, B100 and neat diesel. The engine was operated over a range of engine speeds. Based on the measured parameters, detailed analyses were carried out on major regulated emissions such as NOx, CO, CO2, and THC. It has been seen that the biodiesel types (sources do not result in any significant differences in emissions. The results also clearly indicate that the engine running with biodiesel and blends have higher NOx emission by up to 20%. However, the emissions of the CI engine running on neat biodiesel (B100 were reduced by up to 15%, 40% and 30% for CO, CO2 and THC emissions respectively, as compared to diesel fuel at various operating conditions.

  1. Electro-chemical coupling in the voltage-dependent phosphatase Ci-VSP

    Science.gov (United States)

    Kohout, Susy C.; Bell, Sarah C.; Liu, Lijun; Xu, Qiang; Minor, Daniel L.; Isacoff, Ehud Y.

    2010-01-01

    In the voltage sensing phosphatase, Ci-VSP, a voltage sensing domain (VSD) controls a lipid phosphatase domain (PD). The mechanism by which the domains are allosterically coupled is not well understood. Using an in vivo assay, we find that the inter-domain linker that connects the VSD to the PD is essential for coupling the full-length protein. Biochemical assays show that the linker is also needed for activity in the isolated PD. We identify a late step of VSD motion in the full-length protein that depends on the linker. Strikingly, this VSD motion is found to require PI(4,5)P2, a substrate of Ci-VSP. These results suggest that the voltage-driven motion of the VSD turns the enzyme on by rearranging the linker into an activated conformation, and that this activated conformation is stabilized by PI(4,5)P2. We propose that Ci-VSP activity is self-limited because its decrease of PI(4,5)P2 levels decouples the VSD from the enzyme. PMID:20364128

  2. Performance and emission of CI engine fuelled with camelina sativa oil

    International Nuclear Information System (INIS)

    Kruczyński, Stanisław W.

    2013-01-01

    Highlights: ► Camelina sativa as a potential source of alternative fuel. ► Neat camelina sativa oil as a fuel for CI engine. ► The engine performance and emissions of CI engine fuelled with neat camelina sativa oil. ► Comparison of rate of heat release for camelina sativa oil and diesel oil. - Abstract: The paper describes the results of the tests of CI Perkins 1104C-44 engine fuelled with camelina sativa oil. The engine was not especially calibrated for fuelling with the vegetable fuel. During the test the engine performance and emissions were analysed. For comparison the same speed characteristic was examined for standard fuelling of the engine with diesel oil. In order to understand the engine performance and emission the mass fraction burnt and the rate of heat release was calculated and compared for the same energy provided to the engine cylinder with the injected fuels. The results show that there is possible to receive relatively good engine performance for fuelling the engine with camelina sativa oil but there is a need to change the calibration parameters of the engine fuel system when the engine is fuelled with this fuel.

  3. Structural and functional properties of chimeric EspA-FliCi filaments of EPEC.

    Science.gov (United States)

    Crepin, Valerie F; Martinez, Eric; Shaw, Robert K; Frankel, Gad; Daniell, Sarah J

    2008-04-18

    Enteropathogenic Escherichia coli utilise a filamentous type III secretion system to translocate effector proteins into host gut epithelial cells. The primary constituent of the extracellular component of the filamentous type III secretion system is EspA. This forms a long flexible helical conduit between the bacterium and host and has a structure almost identical to that of the flagella filament. We have inserted the D3 domain of FliCi (from Salmonella typhimurium) into the outer domain of EspA and have studied the structure and function of modified filaments when expressed in an enteropathogenic E. coli espA mutant. We found that the chimeric protein EspA-FliCi filaments were biologically active as they supported protein secretion and translocation [assessed by their ability to trigger actin polymerisation beneath adherent bacteria (fluorescent actin staining test)]. The expressed filaments were recognised by both EspA and FliCi antisera. Visualisation and analysis of the chimeric filaments by electron microscopy after negative staining showed that, remarkably, EspA filaments are able to tolerate a large protein insertion without a significant effect on their helical architecture.

  4. Determination of drug, excipients and coating distribution in pharmaceutical tablets using NIR-CI

    Directory of Open Access Journals (Sweden)

    Anna Palou

    2012-04-01

    Full Text Available The growing interest of the pharmaceutical industry in Near Infrared-Chemical Imaging (NIR-CI is a result of its high usefulness for quality control analyses of drugs throughout their production process (particularly of its non-destructive nature and expeditious data acquisition. In this work, the concentration and distribution of the major and minor components of pharmaceutical tablets are determined and the spatial distribution from the internal and external sides has been obtained. In addition, the same NIR-CI allowed the coating thickness and its surface distribution to be quantified. Images were processed to extract the target data and calibration models constructed using the Partial Least Squares (PLS algorithms. The concentrations of Active Pharmaceutical Ingredient (API and excipients obtained for uncoated cores were essentially identical to the nominal values of the pharmaceutical formulation. But the predictive ability of the calibration models applied to the coated tablets decreased as the coating thickness increased. Keywords: Near infrared Chemical Imaging (NIR-CI, Hyperspectral imaging, Component distribution, Tablet coating distribution, Partial Least Squares (PLS regression

  5. sobre la calidad del agua de la ciénaga

    Directory of Open Access Journals (Sweden)

    Diego Alejandro Chalarca Rodríguez

    2007-01-01

    Full Text Available En el municipio de Ayapel, departamento de Córdoba, se realizaron cuatro muestreos de campo con el fin de obtener información representativa de las variaciones horarias del agua residual del municipio como también de la calidad del agua en la zona de influencia de éstas en la ciénaga de Ayapel. En el sector donde se presentan las principales descargas del alcantarillado se determinaron las variables fisicoquímicas y microbiológicas del agua residual doméstica y de la ciénaga. Ello con el fin de determinar el posible impacto de las aguas residuales domésticas sobre la calidad del agua de un sector de la ciénaga de Ayapel.Los resultados del estudio permiten afirmar que existe un impacto de las aguas residuales sobre el complejo cenagoso, sin embargo estas descargas afectan principalmente la calidad ambiental de los sitios aledaños al casco urbano del municipio de Ayapel, principalmente en las épocas de aguas bajas incluyendo la zona pelágica del sector E0.

  6. Commercial mitigation techniques used in remediating a 2200 pCi/L public building

    International Nuclear Information System (INIS)

    Davidson, J.G.

    1990-01-01

    This paper reports on commercial mitigation techniques used in remediating a 2200 pCi/L public building. In March of 1989 EPA and Pa. DER officials were amazed to discover a school in Pennsylvania with levels in its library of 2200 pCi/L. The library was a 30 year old, three story slab-on-grade structure more like a commercial building than a typical school structure. It had three separate and complex HVAC systems. Initial diagnostics indicated radon levels under the slab at over 80,000 pCi/L. Further investigations revealed major entry routes and a HVAC system terribly out of balance. Remediation consisted of installing a complex sub-slab depressurization system with an exterior commercial fan unit, major entry route sealing, and working closely with a mechanical contractor to bring the HVAC systems back into balance. Initial post remediation testing showed a 99% drop in radon levels. Refinements to the system are still in progress

  7. Determination of Cu(III) and Cu(II)+Cu(III) in superconducting copper ceramics

    International Nuclear Information System (INIS)

    Nedelcheva, T.; Kostadinova, L.; Stoyanova-Ivanova, A.; Ivanova, I.

    1992-01-01

    Copper(III) and total copper in superconducting Y-Ba-Cu oxide and related compounds can be determinated by two successive iodimetric titrations after the sample has been dissolved under Ar in HCl/KI medium. First, the iodine equivalent to copper(III) is titrated with Na 2 S 2 O 3 solution at pH 4.8, copper(II) being masked with EDTA. The total copper is then determined in the same solution by demasking with acid and iodide, followed by iodimetric titration. The method is both accurate and reproducible. The relative standard deviations for 1.074% copper(III) and 23.37% total copper are 0.8% and 0.3%, respectively. (orig.)

  8. Grindability of cast Ti-Cu alloys.

    Science.gov (United States)

    Kikuchi, Masafumi; Takada, Yukyo; Kiyosue, Seigo; Yoda, Masanobu; Woldu, Margaret; Cai, Zhuo; Okuno, Osamu; Okabe, Toru

    2003-07-01

    The purpose of the present study was to evaluate the grindability of a series of cast Ti-Cu alloys in order to develop a titanium alloy with better grindability than commercially pure titanium (CP Ti), which is considered to be one of the most difficult metals to machine. Experimental Ti-Cu alloys (0.5, 1.0, 2.0, 5.0, and 10.0 mass% Cu) were made in an argon-arc melting furnace. Each alloy was cast into a magnesia mold using a centrifugal casting machine. Cast alloy slabs (3.5 mm x 8.5 mm x 30.5 mm), from which the hardened surface layer (250 microm) was removed, were ground using a SiC abrasive wheel on an electric handpiece at four circumferential speeds (500, 750, 1000, or 1250 m/min) at 0.98 N (100 gf). Grindability was evaluated by measuring the amount of metal volume removed after grinding for 1min. Data were compared to those for CP Ti and Ti-6Al-4V. For all speeds, Ti-10% Cu alloy exhibited the highest grindability. For the Ti-Cu alloys with a Cu content of 2% or less, the highest grindability corresponded to an intermediate speed. It was observed that the grindability increased with an increase in the Cu concentration compared to CP Ti, particularly for the 5 or 10% Cu alloys at a circumferential speed of 1000 m/min or above. By alloying with copper, the cast titanium exhibited better grindability at high speed. The continuous precipitation of Ti(2)Cu among the alpha-matrix grains made this material less ductile and facilitated more effective grinding because small broken segments more readily formed.

  9. Direct Simple Shear Test Data Analysis using Jupyter Notebooks on DesignSafe-CI

    Science.gov (United States)

    Eslami, M.; Esteva, M.; Brandenberg, S. J.

    2017-12-01

    Due to the large number of files and their complex structure, managing data generated during natural hazards experiments requires scalable and specialized tools. DesignSafe-CI (https://www.designsafe-ci.org/) is a web-based research platform that provides computational tools to analyze, curate, and publish critical data for natural hazards research making it understandable and reusable. We present a use case from a series of Direct Simple Shear (DSS) experiments in which we used DS-CI to post-process, visualize, publish, and enable further analysis of the data. Current practice in geotechnical design against earthquakes relies on the soil's plasticity index (PI) to assess liquefaction susceptibility, and cyclic softening triggering procedures, although, quite divergent recommendations on recommended levels of plasticity can be found in the literature for these purposes. A series of cyclic and monotonic direct simple shear experiments was conducted on three low-plasticity fine-grained mixtures at the same plasticity index to examine the effectiveness of the PI in characterization of these types of materials. Results revealed that plasticity index is an insufficient indicator of the cyclic behavior of low-plasticity fine-grained soils, and corrections for pore fluid chemistry and clay minerology may be necessary for future liquefaction susceptibility and cyclic softening assessment procedures. Each monotonic, or cyclic experiment contains two stages; consolidation and shear, which include time series of load, displacement, and corresponding stresses and strains, as well as equivalent excess pore-water pressure. Using the DS-CI curation pipeline we categorized the data to display and describe the experiment's structure and files corresponding to each stage of the experiments. Two separate notebooks in Python 3 were created using the Jupyter application available in DS-CI. A data plotter aids visualizing the experimental data in relation to the sensor from which it was

  10. Large magnetoresistance in intercalated Cu oxides

    OpenAIRE

    Grigoryan, L.; Furusawa, M.; Hori, H.; Tokumoto, M.

    1997-01-01

    Magnetism and electrical resistance as a function of magnetic field, temperature, and chemical composition are studied in Cu oxides intercalated with metal phthalocyanines MPc, where M is Fe or Ni, and Pc is C_H_N_. An unusually large positive magnetoresistance (MR) of ~ 1200% is observed in FePc-intercalated Bi_Sr_Ca_Cu_O_ samples with two Cu-O layers in the unit cell (n=2). The magnitude of the MR decreased to 40% and ~ 0% in the FePc-intercalated n=3 and n=4 samples, respectively, and to ~...

  11. High spin states in 62Cu

    International Nuclear Information System (INIS)

    Tsan Ung Chan; Agard, M.; Bruandet, J.F.; Giorni, A.; Glasser, F.; Longequeue, J.P.; Morand, C.

    1977-06-01

    The 62 Cu nucleus has been studied via the reactions 60 Ni(α,pnγ), 63 Cu(p,pnγ), 52 Cr( 14 N,2p2nγ) using different in beam γ-spectroscopy techniques. The intensity of the principal γ-lines observed in different reactions leading to the 62 Cu has been compared. A brief discussion is made in terms of the independent particle model. A level scheme including levels with spin up to 9 + is proposed [fr

  12. Preparation, quality control and biodistribution studies of [61Cu]-oxinate for PET tumor imaging

    International Nuclear Information System (INIS)

    Jalilian, A.R.; Yousefnia, H.; Garousi, J.; Shafaii, K.; Bolourinovin, F.; Zolghadri, S.; Faghihi, R.

    2009-01-01

    Targeting apoptosis is an interesting issue in molecular imaging and various modalities have been presented. However, recent experiences in nuclear pharmacy demonstrated the application of small tracer molecules is more desired. This work was conducted for production of a radiolabeled copper complex, i.e. Cu-oxinate as a potential PET tracer for apoptosis imaging in oncology. Cu-61 was prepared by natural zinc target irradiation with 22 MeV protons (150 μA) via the nat Zn(p, xn) 61 Cu nuclear reaction with a yield of 3.33 mCi/μAh. In order to obtain the best labeling method, optimization reactions were performed for pH, temperature and concentration followed by solid phase extraction. Biodistribution of the tracer was studied in wild-type and fibrosarcoma bearing mice. Under the optimized conditions, radio-thin-layer chromatography (RTLC) and HPLC showed radiochemical purities of 99.99% and 97% respectively (with a minimum specific activity of 16 Ci/mM). Biodistribution of the tracer in fibrosarcoma bearing mice demonstrated a significant tumor uptake after 3 h. Tumor:blood and tumor:muscle ratios were 2.0 and 6.0 after 3 h, respectively. (authors)

  13. Możliwości leczenia kamicy moczowodowej u dzieci

    Directory of Open Access Journals (Sweden)

    Ewa Straż-Żebrowska

    2010-09-01

    Full Text Available Kamicą układu moczowego nazywamy schorzenie, w którym wytwarzane są złogi w obrębie nerek lub dróg moczowych. Obecnie obserwuje się wzrost częstości występowania kamicy. Szacuje się, iż częstość występowania kamicy układu moczowego wynosi 0,5-5% w grupie dorosłych i 0,1-5% u dzieci. Istotnym problemem jest wykrywanie złogów u małych dzieci, również u niemowląt. Biorąc pod uwagę coraz częstsze wykrywanie kamicy układu moczowego, jej nawrotowość i powikłania, ważne jest wypracowanie schematów leczniczych skutecznych i jednocześnie bezpiecznych, nawet przy konieczności ich kilkukrotnego powtarzania. Postępowanie zachowawcze jest skuteczne w 80%, w przypadkach złogów o wielkości do 4 mm. Powszechnie stosowane do lat 80. XX wieku leczenie operacyjne związane z nacięciem miąższu nerki obecnie w większości przypadków zastępowane jest metodami mniej inwazyjnymi, takimi jak ESWL, PCNL, URSL, a wskazania do leczenia chirurgicznego kamicy zostały znacznie ograniczone. W niniejszej pracy przedstawiono przypadek pacjentki z kamicą układu moczowego leczonej kilkakrotnie metodą ESWL bez efektu, a następnie z uwagi na obecność złogów w moczowodzie za pomocą URSL. Jednym z powikłań po zabiegu ESWL może być „droga kamieni”. Po wykonaniu zabiegu ESWL pacjent wymaga monitorowania poprzez wykonywanie badań USG, co pozwala na szybkie uwidocznienie powikłania w postaci „drogi kamieni” i wdrożenie dodatkowego postępowania ułatwiającego wydalenie złogów. „Droga kamieni” może spowodować utrudnienie odpływu moczu, co może być przyczyną dolegliwości bólowych oraz różnego stopnia poszerzeń moczowodów i układów kielichowo-miedniczkowych. Często wymaga interwencji zabiegowej w trybie pilnym. W ciągu ostatnich dwudziestu lat nastą- piły w Polsce znaczne zmiany w sposobach leczenia kamicy moczowodowej. Rutynowo stosuje się URSL i ESWL, do rzadkości natomiast należy zak

  14. Direct synthesis of RGO/Cu{sub 2}O composite films on Cu foil for supercapacitors

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Xiangmao; Wang, Kun [Key Laboratory for Ultrafine Materials of the Ministry of Education, Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237 (China); Zhao, Chongjun, E-mail: chongjunzhao@ecust.edu.cn [Key Laboratory for Ultrafine Materials of the Ministry of Education, Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237 (China); Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong 2500 (Australia); Qian, Xiuzhen [Key Laboratory for Ultrafine Materials of the Ministry of Education, Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237 (China); Chen, Shi [School of Information Engineering, Wuhan University of Technology, Wuhan 430070 (China); Li, Zhen, E-mail: zhenl@uow.edu.au [Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong 2500 (Australia); Liu, Huakun; Dou, Shixue [Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong 2500 (Australia)

    2014-02-15

    Graphical abstract: RGO/Cu{sub 2}O/Cu composites were synthesized by simple hydrothermal treatment of copper foils with graphene oxide, in which the reduction of graphene oxide and the formation of Cu{sub 2}O nanoparticles simultaneously happened in one-pot reaction. These composites can be directly used as electrodes of supercapacitors with the highest specific capacitance of 98.5 F/g at 1 A g{sup −1}, which is much better than that of CuO or Cu{sub 2}O electrodes. -- Highlights: • The RGO/Cu{sub 2}O/Cu composites were obtained by a friendly method in one step. • Improved capacitance performance is realized by the hydrothermal treatment of graphene oxides with Cu foils. • RGO/Cu{sub 2}O/Cu-200 composites exhibit the largest specific capacitance of 98.5 F g{sup −1} at 1 A g{sup −1}. -- Abstract: Reduced graphene oxide/cuprous oxide (RGO/Cu{sub 2}O) composite films were directly synthesized on the surface of copper foil substrates through a straight redox reaction between GO and Cu foil via a hydrothermal approach. Characterization of the resultant composites with X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and field emission scanning electron microscope (FESEM) confirms the formation of Cu{sub 2}O and reduction of GO, in which Cu{sub 2}O nanoparticles were well covered by RGO. The resultant composites (referred to as RGO/Cu{sub 2}O/Cu) were directly used as electrodes for supercapacitors, and their electrochemical performance was assessed by cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectrometry (EIS) in 1 M KOH aqueous solution. A specific capacitance of 98.5 F g{sup −1} at 1 A g{sup −1} was obtained, which is much higher than that of pure Cu{sub 2}O prepared under the same conditions, due to the presence of RGO.

  15. Properties of the CuGaSe2 and CuInSe2 (001) surface

    International Nuclear Information System (INIS)

    Deniozou, T.

    2005-01-01

    The main task of this work was to investigate the (001) CuGaSe 2 and CuInSe 2 surface in dependence of preparation and stoichiometry. The knowledge of the atomic structure as well as other surface properties is important in respect to optimization of novel thin film solar cells. For the characterization of the layers mainly Auger electron Spectroscopy, low-energy electron diffraction and photoelectron spectroscopy were implemented. The development of an appropriate procedure with Ar + sputtering and annealing combined with decapping enabled the preparation of clean and well-ordered surfaces. Different surface structures were observed in dependence of the layer preparation and composition. A (4 x 1) reconstruction was observed for the first time on CuGaSe 2 layers grown with a moderate Cu-excess after preparation by sputtering and annealing. Similarly a (4 x 2) reconstruction was detected on CuInSe2 surfaces of Cu-poor layers. A reconstruction could be also observed on Cu-poorer layers, however the facets/steps could not be completely removed. Cu-richer layers were facet-free, however the observed reconstruction was also weaker. Thus it was shown that in contrary to recent expectations, according to which only the (112) surface is stable, also the (001) can be stable under particular conditions. The appearance of facets or steps is correlated with the presence of CuIn 3 Se 5 or CuGa 3 Se 5 phases. This information is furthermore important for the understanding of grain boundaries in polycrystalline CuGaSe 2 and CuInSe 2 . Binding energy shifts were observed for the first time on all Se3d, In4d, Ga3d, Cu3d core levels of the reconstructed surfaces. By comparison with results from the literature from the similar ZnSe (100) surface a modell for the (4 x 2) reconstruction was proposed. The surface components in the Se3d, In4d and Cu3d emission were attributed to Se dimers or In and Cu adatoms respectively. The x 1 periodicity of the (4 x 1) reconstruction of CuGaSe 2 is

  16. Cluster expansion of the wavefunction. Calculation of electron correlations in ground and excited states by SAC and SAC CI theories

    International Nuclear Information System (INIS)

    Nakatsuji, H.

    1979-01-01

    The SAC and SAC CI theories are formulated for actual calculations of singlet ground states and their excited states of arbitrary spin multiplicity. Approximations are considered for the variational methods since time-consuming terms are involved. The results of test calculations for singlet states have shown, with much smaller numbers of variables (sizes of the matrices involved), excellent agreement with the full CI and close-to-full CI results. This shows the utility of the SAC theory for ground states and especially of the SAC CI theory for excited states, since the slow convergence of the CI theory is much more critical for excited states than for ground states. (Auth.)

  17. Magnetic dipole moments of 58Cu and 59Cu by in-source laser spectroscopy

    International Nuclear Information System (INIS)

    Stone, N. J.; Koester, U.; Stone, J. Rikovska; Fedorov, D. V.; Fedoseyev, V. N.; Flanagan, K. T.; Hass, M.; Lakshmi, S.

    2008-01-01

    Online measurements of the magnetic dipole moments and isotope shifts of 58 Cu and 59 Cu by the in-source laser spectroscopy method are reported. The results for the magnetic moments are μ ( 58 Cu) =+0.52(8) μ N ,μ( 59 Cu) =+1.84(3) μ N and for the isotope shifts δν 59,65 =1.72(22) GHz and δν 58,65 =1.99(30) GHz in the transition from the 3d 10 4s 2 S 1/2 ground state to the 3d 10 4p 2 P 1/2 state in Cu I. The magnetic moment of 58 Cu is discussed in the context of the strength of the subshell closure at 56 Ni, additivity rules and large-scale shell model calculations

  18. Używki w ciąży – kofeina = Stimulants in pregnancy – caffeine

    Directory of Open Access Journals (Sweden)

    Agnieszka Konstancja Pawłowska-Muc

    2015-06-01

    3 Independent Obstetric Skills Workshop, Medical University of Lublin, ul. Staszica 4/6   Adres do korespondencji: mgr piel. Agnieszka Konstancja Pawłowska-Muc Ośrodek Kształcenia Podyplomowego Pielęgniarek i Położnych Radomski Szpital Specjalistyczny im. dr Tytusa Chałubińskiego w Radomiu, ul. Lekarska 4 tel. 48  3615616; fax: 48 3615437 e-mail: agmich@vp.pl   Używki w ciąży - kofeina Streszczenie Wprowadzenie. Kofeina należy do substancji psychoaktywnych, ogólnodostępnych i najbardziej rozpowszechnionych na całym świecie. Jej wpływ na zdrowie kobiet, przebieg ciąży i rozwój płodu jest od lat przedmiotem wielu dyskusji, sporów i dociekań naukowych. Cel pracy. Przegląd piśmiennictwa na temat wpływu działania kofeiny na organizm kobiety oraz skutków jej spożywania w okresie ciąży i laktacji. Skrócony opis stanu wiedzy. Działanie kofeiny na organizm kobiety oraz jej wpływ na przebieg ciąży i zdrowie dziecka nie zostały dotychczas w pełni poznane. Znajduje się ona w wielu produktach, a to sprawia, że jej całkowite, dzienne spożycie jest trudne do oceny.             Podsumowanie. Z przeglądu piśmiennictwa wynika, że duży odsetek kobiet ciężarnych ma zwyczaj codziennego picia herbaty i/lub kawy z kofeiną. Zakres embriotoksycznego działania tej substancji zależy od jej dawki, częstości spożywania oraz stanu zdrowia kobiety ciężarnej. Stanowiska  autorów, co do stosowania napojów zawierających kofeinę w tym czasie, a także ich skutków, są podzielone. Większość jednak podziela pogląd, iż w ciąży i w okresie laktacji należy ograniczyć, a najlepiej zaniechać, spożywanie takich napojów. Zasadne jest zatem, aby działania promujące i wspierające zdrowy styl życia kobiet w wieku rozrodczym dotyczyły, między innymi, tej kwestii. Słowa kluczowe: kofeina, ciężarna, zdrowie, ciąża, płód.   Stimulants in pregnancy - caffeine Summary Introduction. Caffeine belongs to the group of

  19. Electromigration in Cu(Al) and Cu(Mn) damascene lines

    Science.gov (United States)

    Hu, C.-K.; Ohm, J.; Gignac, L. M.; Breslin, C. M.; Mittal, S.; Bonilla, G.; Edelstein, D.; Rosenberg, R.; Choi, S.; An, J. J.; Simon, A. H.; Angyal, M. S.; Clevenger, L.; Maniscalco, J.; Nogami, T.; Penny, C.; Kim, B. Y.

    2012-05-01

    The effects of impurities, Mn or Al, on interface and grain boundary electromigration (EM) in Cu damascene lines were investigated. The addition of Mn or Al solute caused a reduction in diffusivity at the Cu/dielectric cap interface and the EM activation energies for both Cu-alloys were found to increase by about 0.2 eV as compared to pure Cu. Mn mitigated and Al enhanced Cu grain boundary diffusion; however, no significant mitigation in Cu grain boundary diffusion was observed in low Mn concentration samples. The activation energies for Cu grain boundary diffusion were found to be 0.74 ± 0.05 eV and 0.77 ± 0.05 eV for 1.5 μm wide polycrystalline lines with pure Cu and Cu (0.5 at. % Mn) seeds, respectively. The effective charge number in Cu grain boundaries Z*GB was estimated from drift velocity and was found to be about -0.4. A significant enhancement in EM lifetimes for Cu(Al) or low Mn concentration bamboo-polycrystalline and near-bamboo grain structures was observed but not for polycrystalline-only alloy lines. These results indicated that the existence of bamboo grains in bamboo-polycrystalline lines played a critical role in slowing down the EM-induced void growth rate. The bamboo grains act as Cu diffusion blocking boundaries for grain boundary mass flow, thus generating a mechanical stress-induced back flow counterbalancing the EM force, which is the equality known as the "Blech short length effect."

  20. Fabrication of new phosphors of NaCl: Cu and their thermoluminescent characterization to be exposed to beta radiation; Fabricacion de nuevos fosforos de NaCl: Cu y su caracterizacion termoluminiscente al ser expuestos a radiacion beta

    Energy Technology Data Exchange (ETDEWEB)

    Bernal, R.; Perez S, R.; Barboza F, M. [CIF, UNISON, A.P. 5-088, Hermosillo, Sonora (Mexico); Tostado G, W.C.; Cruz V, C. [UNISON, A.P. 130, Hermosillo, Sonora (Mexico)

    2004-07-01

    In this work, we report the fabrication of new NaCl:Cu phosphors manufactured by following a previously reported sintering method. The samples were made from mixtures of commercially available Na CI and Cu Cl high purity powders. Tl glow curves obtained after exposing the samples to beta radiation exhibit two main intense peaks at 117 and 310 when a 2 C/s heating rate is used. These peaks positions differ from those reported for NaCl:Cu monocrystals. The first peak vanishes in ca. 3 h, while the high temperature one remains with no meaningful changes. The position, as well as the remarkable stability of the high temperature peak indicates that this new phosphors have better properties than the monocrystals present to be applied as detectors and dosimeters of ionizing radiation. (Author)

  1. Crystallization and electrical resistivity of Cu2O and CuO obtained by thermal oxidation of Cu thin films on SiO2/Si substrates

    International Nuclear Information System (INIS)

    De Los Santos Valladares, L.; Salinas, D. Hurtado; Dominguez, A. Bustamante; Najarro, D. Acosta; Khondaker, S.I.; Mitrelias, T.; Barnes, C.H.W.; Aguiar, J. Albino; Majima, Y.

    2012-01-01

    In this work, we study the crystallization and electrical resistivity of the formed oxides in a Cu/SiO 2 /Si thin film after thermal oxidation by ex-situ annealing at different temperatures up to 1000 °C. Upon increasing the annealing temperature, from the X ray diffractogram the phase evolution CuCu + Cu 2 O → Cu 2 O → Cu 2 O + CuO → CuO was detected. Pure Cu 2 O films are obtained at 200 °C, whereas uniform CuO films without structural surface defects such as terraces, kinks, porosity or cracks are obtained in the temperature range 300–550 °C. In both oxides, crystallization improves with annealing temperature. A resistivity phase diagram, which is obtained from the current–voltage response, is presented here. The resistivity was expected to increase linearly as a function of the annealing temperature due to evolution of oxides. However, anomalous decreases are observed at different temperatures ranges, this may be related to the improvement of the crystallization and crystallite size when the temperature increases. - Highlights: ► The crystallization and electrical resistivity of oxides in a Cu films are studied. ► In annealing Cu films, the phase evolution Cu + Cu 2 O → Cu 2 O → Cu 2 O + CuO → CuO occurs. ► A resistivity phase diagram, obtained from the current–voltage response, is presented. ► Some decreases in the resistivity may be related to the crystallization.

  2. The Influence of Pyrolytic Temperature on Sorption Ability of Carbon Xerogel Based on 3-Aminophenol-formaldehyde Polymer for Cu(II) Ions and Phenol.

    Czech Academy of Sciences Publication Activity Database

    Veselá, P.; Slovák, V.; Zelenka, T.; Koštejn, Martin; Mucha, M.

    2016-01-01

    Roč. 121, SEP (2016), s. 29-40 ISSN 0165-2370 Institutional support: RVO:67985858 Keywords : temperature of pyrolysis * sorption mechanism * Cu(II) ions Subject RIV: CI - Industrial Chemistry , Chemical Engineering Impact factor: 3.471, year: 2016

  3. Cu(II), Zn(II)

    African Journals Online (AJOL)

    the kinetic parameters as order of decomposition reaction, activation energy and ..... Cu as anode material, K - alpha [Å] = 1.54060 and the generator settings 30 .... Calculated quantum chemical parameters for ligand and its metal complexes.

  4. Temperature stability of AgCu nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Sopoušek, Jiří, E-mail: sopousek@mail.muni.cz; Zobač, Ondřej; Vykoukal, Vít [Masaryk University, Department of Chemistry, Faculty of Science (Czech Republic); Buršík, Jiří; Roupcová, Pavla [Institute of Physics of Materials ASCR (Czech Republic); Brož, Pavel; Pinkas, Jiří [Masaryk University, Department of Chemistry, Faculty of Science (Czech Republic); Vřešťál, Jan [Masaryk University, Central European Institute of Technology, CEITEC (Czech Republic)

    2015-12-15

    The colloidal solutions of the Ag–Cu nanoparticles (NPs, 10–32 nm) were prepared by solvothermal reactions. The samples of dried AgCu NPs and the resulting microstructures after heat treatment in air were investigated by various methods including electron microscopy (TEM, SEM) and high-temperature X-ray powder diffraction (HTXRD). The AgCu randomly mixed, Cu-rich, and Ag-rich face centred cubic crystal lattices were detected during the experiments. The temperature induced sintering was observed experimentally by HTXRD at 250 °C. The phase transformations at high temperatures were monitored by differential scanning calorimetry. The formation of the Ag-rich grains during heating in air and evolution of copper oxide microstructure were detected.Graphical abstract.

  5. EPR of CU+2:Mb single crystal

    International Nuclear Information System (INIS)

    Nascimento, O.R.; Ribeiro, S.C.; Bemski, G.

    1976-01-01

    Copper introduced into met-myoglobin crystals occupies various sites as indicated by EPR parameters. CU 2+ (A) is probably liganded to histidine A10, lysine A14 and asparagine GH4 (Banaszak, 1965) and shows super-hyperfine interaction with a single (imidazole) nitrogen. Cu 2+ (B) and Cu 2+ (C) correspond to other anisotropic sites described with lesser details. Cu 2+ (A) exhibits a transition to an isotropic form with a transition temperature of 40.5 0 C. This transition is indicative of a conformational change in myoglobin and could correspond to a motion of A helix away from the GH section. The transition temperature is 7 0 C higher than the previously reported (Atanasov, 1971) one for myoglobin in solution

  6. Używki w ciąży – alcohol = Stimulants in pregnancy – alcohol

    Directory of Open Access Journals (Sweden)

    AGNIESZKA KONSTANCJA PAWŁOWSKA-MUC

    2015-08-01

    Używki w ciąży - alkohol Streszczenie Wprowadzenie. Spożywanie alkoholu kobiety w wieku rozrodczym jest problemem wielu krajów świata. Stwarza ono duże zagrożenie dla ich zdrowia prokreacyjnego, prawidłowego przebiegu ciąży, zdrowia noworodka i dziecka w późniejszym okresie jego życia. Cel pracy. Celem pracy było ukazanie skali problemu oraz skutków spożywania alkoholu przez kobiety w okresie ciąży. Skrócony opis stanu wiedzy. Z przeglądu piśmiennictwa wynika, iż skala problemu jest trudna do oszacowania. Negatywnych skutków jest zdecydowanie więcej niż pozytywnych. Dotychczas nie określono jeszcze bezpiecznej dawki alkoholu dla ciężarnych, a kobiet spożywających napoje alkoholowe w tym czasie jest wciąż za duża. Świadomość konsekwencji takich zachowań nie zawsze idzie w parze z całkowitą rezygnacją z picia alkoholu podczas ciąży. Podsumowanie. Istnieje potrzeba większego niż dotychczas angażowania się pracowników medycznych (lekarzy położników i położnych w działalność nie tylko informacyjną, lecz także edukacyjną i wspierającą.   Słowa kluczowe: alkohol, ciąża, płód, zdrowie.                                             Stimulants in pregnancy - alcohol Abstract Introduction. Alcohol consumption by women in the reproductive period is a current problem in many countries around the world. It poses a great threat to their reproductive health, the correct parturition, the health of the newborn and the child in the later part of its life. Aim. It was the aim of this work to present the scale of the problem as well as the results of women’s alcohol consumption during pregnancy. Brief description of the state of the art. The review of the bibliography indicates that the scale of the problem is hard to assess. Negative effects are much more prevalent than the positive ones. A safe unit dose for pregnant women has not yet been established and the number of women

  7. A metafísica na ciência moderna: uma discussão heideggeriana

    Directory of Open Access Journals (Sweden)

    Flávio Oliveira Silva

    2015-07-01

    Full Text Available O artigo apresenta duas teses de Heidegger: a interpretação da Crítica da Razão Pura como metafísica e a afirmação da permanência da metafísica na ciência moderna. Em seguida analisa as objeções que Loparic apresenta a essas teses no artigo A metafísica e o processo de objetificação,para enfim argumentar que suas contestações não se sustentam. Loparic afirma que  a Crítica da Razão Pura não se destina a investigar a quididade dos entes, mas as condições nas quais os juízos sintéticos a priori podem ser verdadeiros ou falsos, de modo que o problema tratado por Kant não seria ontológico, mas semântico. Loparic afirma ainda que a ciência moderna deixou o quadro ontológico da metafísica aristotélica, na medida em que não mais se destina a estudar os entes como tais, isto é, como uma coisa em si, mas tão somente investigar a resposta da natureza, mediante intervenção técnica no curso dos processos naturais e, portanto não há sequer resquício da metafísica na ciência moderna. Essas objeções apresentam dificuldades na medida em que o autor se utiliza do conceito tradicional de metafísica para tratar da filosofia de Heidegger. Argumenta-se que o sentido de metafísica para Heidegger não se restringe à concepção de metafísica da tradição, de modo que, constitui um equívoco analisar as teses heideggerianas em conformidade com a leitura da tradição.  Heidegger se pauta na indicação de que Kant se ocupa das condições de possibilidade da compreensão, isto é, do Dasein, enquanto o ente que coloca a pergunta sobre o ser e é nesta dimensão que a Crítica da Razão Pura é recepcionada como metafísica. No tocante à ciência, o filósofo afirma que, mesmo a ciência moderna tendo abandonado a representação de objetos, ela não renunciou e nem poderia renunciar à necessidade de a natureza fornecer dados que se possa calcular e de continuar sendo um sistema disponível de informação, de modo

  8. Extended analysis of Cu IV

    International Nuclear Information System (INIS)

    Meinders, E.; Uijlings, P.

    1980-01-01

    Wavelength data and classifications of 974 Cu IV lines in the region 750-1275 Angstroem are presented. Most of the lines have been classified as transitions from the previously unknown high even configurations 3d 7 5s and 3d 7 4d to 3d 7 4p. The configuration 3d 7 4d is seriously perturbed by 3d 6 4s 2 . The analysis resulted in the identification of 27 levels of 3d 7 5s and 113 levels of (3d 7 4d + 3d 6 4s 2 ) which are reported. The earlier published levels of 3d 7 4s and 3d 7 4p have to be shifted downward as a consequence of improved wavelength data. Radial paramter values, resulting from least-squares fits, are compared to Hartree-Fock values. The eigenvectors obtained in the parametric fitting are used to calculate transition probabilities in intermediate coupling. The relation between the observed intensities of the transitions 3d 7 4d-3d 7 4p and 3d 7 Ss-3d 7 4p is compared to the relation between theoretical values of the transition integrals obtained from Hartree-Fock calculations. A spectroscopic value for the ionization potentials is calculated from the 3d 7 ns configurations. (orig.)

  9. The activation energy for loop growth in Cu and Cu-Ni alloys

    International Nuclear Information System (INIS)

    Barlow, P.; Leffers, T.; Singh, B.N.

    1978-08-01

    The apparent activation energy for the growth of interstitial dislocation loops in copper, Cu-1%Ni, Cu-2%Ni, and Cu-5%Ni during high voltage electron microscope irradiation was determined. The apparent activation energy for loop growth in all these materials can be taken to be 0.34eV+-0.02eV. This value together with the corresponding value of 0.44eV+-0.02eV determined earlier for Cu-10%Ni is discussed with reference to the void growth rates observed in these materials. The apparent activation energy for loop growth in copper (and in Cu-1%Ni that has a void growth rate similar to that in pure copper) is interpreted as twice the vacancy migration energy (indicating that divacancies do not play any significant role). For the materials with higher Ni content (in which the void growth rate is much lower than that in Cu and Cu-1%Ni) the measured apparent activation energy is interpreted to be characteristic of loops positioned fairly close to the foil surface and not of loops in ''bulk material''. From the present results in combination with the earlier results for Cu-10%Ni it is concluded that interstitial trapping is the most likely explanation of the reduced void growth rate in Cu-Ni alloys. (author)

  10. Electromigration in 3D-IC scale Cu/Sn/Cu solder joints

    Energy Technology Data Exchange (ETDEWEB)

    Ho, Cheng-En, E-mail: ceho1975@hotmail.com; Lee, Pei-Tzu; Chen, Chih-Nan; Yang, Cheng-Hsien

    2016-08-15

    The electromigration effect on the three-dimensional integrated circuits (3D-IC) scale solder joints with a Cu/Sn(25–50 μm)/Cu configuration was investigated using a field-emission scanning electron microscope (FE–SEM) combined with electron backscatter diffraction (EBSD) analysis system. Electron current stressing for a few days caused the pronounced accumulation of Cu{sub 6}Sn{sub 5} in specific Sn grain boundaries (GBs). The EBSD analysis indicated that both the β-Sn crystallographic orientation and GB orientation play dominant roles in this accumulation. The dependencies of the Cu{sub 6}Sn{sub 5} accumulation on the two above factors (i.e., Sn grain orientation and GB orientation) can be well rationalized via a proposed mathematic model based on the Huntington and Grone's electromigration theory with the Cu anisotropic diffusion data in a β-Sn lattice. - Highlights: • Anisotropic Cu electromigration in the 3D-IC scale microelectronic solder joints. • Pronounced accumulation of Cu{sub 6}Sn{sub 5} intermetallic in specific Sn grain boundaries. • A linear dependence of Cu{sub 6}Sn{sub 5} accumulation over the current stressing time. • β-Sn and grain boundary orientations are the dominant factors in Cu{sub 6}Sn{sub 5} accumulation.

  11. Recycled tetrahedron-like CuCl from waste Cu scraps for lithium ion battery anode.

    Science.gov (United States)

    Hou, Hongying; Yao, Yuan; Liu, Song; Duan, Jixiang; Liao, Qishu; Yu, Chengyi; Li, Dongdong; Dai, Zhipeng

    2017-07-01

    The wide applications of metal Cu inevitably resulted in a large quantity of waste Cu materials. In order to recover the useful Cu under the mild conditions and reduce the environmental emission, waste Cu scraps were recycled in the form of CuCl powders with high economic value added (EVA) via the facile hydrothermal route. The recycled CuCl powders were characterized in terms of scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD). The results suggested that the recycled CuCl powders consisted of many regular tetrahedron-like micro-particles. Furthermore, in order to reduce the cost of lithium ion battery (LIB) anode and build the connection of waste Cu scraps and LIB, the recycled CuCl powders were evaluated as the anode active material of LIB. As expected, the reversible discharge capacity was about 171.8mAh/g at 2.0C even after 50 cycles, implying the satisfactory cycle stability. Clearly, the satisfactory results may open a new avenue to develop the circular economy and the sustainable energy industry, which would be very important in terms of both the resource recovery and the environmental protection. Copyright © 2017. Published by Elsevier Ltd.

  12. Effect of Cu content on wear resistance and mechanical behavior of Ti-Cu binary alloys

    Science.gov (United States)

    Yu, Feifei; Wang, Hefeng; Yuan, Guozheng; Shu, Xuefeng

    2017-04-01

    Arc melting with nonconsumable tungsten electrode and water-cooled copper crucible was used to fabricate Ti-Cu binary alloys with different Cu contents in an argon atmosphere. The compositions and phase structures of the fabricated alloys were investigated by glow discharge optical emission spectroscopy (GDOES) and X-ray diffraction (XRD). Nanoindentation tests through continuous stiffness measurement were then performed at room temperature to analyze the mechanical behaviors of the alloys. Results indicated that the composition of each Ti-Cu binary alloy was Ti(100- x) Cu x ( x = 43, 60, 69, and 74 at.%). The XRD analysis results showed that the alloys were composed of different phases, indicating that different Cu contents led to the variations in alloy hardness. The wear tests results revealed that elemental Cu positively affects the wear resistance properties of the Ti-Cu alloys. Nanoindentation testing results showed that the moduli of the Ti-Cu alloys were minimally changed at increasing Cu content, whereas their hardness evidently increased according to the wear test results.

  13. Effects of plasma cleaning of the Cu seed layer surface on Cu electroplating

    International Nuclear Information System (INIS)

    O, Jun Hwan; Lee, Seong Wook; Kim, Jae Bum; Lee, Chong Mu

    2001-01-01

    Effects of plasma pretreatment to Cu seed/tantalum nitride (TaN)/ borophosphosilicate glass (BPSG) samples on copper (Cu) electroplating were investigated. Copper seed layers were deposited by magnetron sputtering onto tantalum nitride barrier layers before electroplating copper in the forward pulsed mode. The Cu seed layer was cleaned by plasma H 2 and N 2 prior to electroplating a copper film. Cu films electroplated on the copper seed layer with plasma pretreatment showed better electrical and physical properties such as electrical resistivities, surface morphologies, levels of impurities, adhesion and surface roughness than those without plasma pretreatment. It is shown that carbon and metal oxide contaminants at the sputtered Cu seed/TaN surface could be effectively removed by plasma H 2 cleaning. The degree of the (111) prefered orientation of the Cu film with plasma H 2 pretreatment is as high as pulse plated Cu film without plasma pretreatment. Also, plasma H 2 precleaning is more effective in enhancing the Cu electroplating properties onto the Cu seed layer than plasma N 2 precleaning

  14. CuGaTe2-CuAlTe2 system

    International Nuclear Information System (INIS)

    Bodnar', I.V.

    2003-01-01

    The results of studies on the chemical interaction in the CuGaTe 2 -CuAlTe 2 as well as on the thermal and optical properties of the formed solid solutions are presented. It is shown, that continuous number of solid solutions are formed in the CuGaTe 2 -CuAlTe 2 system, which crystallize in the chalcopyrite structure. The diagram of state of this system is plotted. The thermal expansion of these materials is studied through the dilatometric method. The linear dependence of the thermal expansion coefficient on the composition is established. The concentration dependences of the forbidden zone width diverge from the linearity [ru

  15. Experimental and Numerical Investigation of Ethanol/Diethyl Ether Mixtures in a CI Engine

    KAUST Repository

    Sivasankaralingam, Vedharaj

    2016-10-17

    The auto-ignition characteristics of diethyl ether (DEE)/ethanol mixtures are investigated in compression ignition (CI) engines both numerically and experimentally. While DEE has a higher derived cetane number (DCN) of 139, ethanol exhibits poor ignition characteristics with a DCN of 8. DEE was used as an ignition promoter for the operation of ethanol in a CI engine. Mixtures of DEE and ethanol (DE), i.e., DE75 (75% DEE + 25% ethanol), DE50 (50% DEE + 50% ethanol) and DE25 (25% DEE + 75% ethanol), were tested in a CI engine. While DE75 and DE50 auto-ignited at an inlet air pressure of 1.5 bar, DE25 failed to auto-ignite even at boosted pressure of 2 bar. The peak in-cylinder pressure for diesel and DE75 were comparable, while DE50 showed reduced peak in-cylinder pressure with delayed start of combustion (SOC). Numerical simulations were conducted to study the engine combustion characteristics of DE mixture. A comprehensive detailed chemical kinetic model was created to represent the combustion of DE mixtures. The detailed mechanism was then reduced using standard direct relation graph (DRG-X) method and coupled with 3D CFD code, CONVERGE, to simulate the experimental data. The simulation results showed that the effects of physical properties on DE50 combustion are negligible. Simulations of DE50 mixture revealed that the combustion is nearly homogenous, while diesel (n-heptane used as a surrogate) and DE75 showed similar combustion behavior with flame liftoff and diffusion controlled combustion. Diesel exhibited auto-ignition at an equivalence ratio of 2, while DE75 and DE50 showed auto-ignition in the equivalence ratio range of 1-1.5 and 0-1, respectively. The experiments and numerical simulations demonstrate how the high reactivity of DEE supports the auto-ignition of ethanol, while ethanol acts as a radical scavenger.

  16. Technician-Supported Remote Interrogation of CIEDs: Initial Use in US Emergency Departments and Perioperative Areas.

    Science.gov (United States)

    Ahmed, Imdad; Patel, Amisha S; Balgaard, Timothy J; Rosenfeld, Lynda E

    2016-03-01

    Interrogation/interpretation of cardiac implantable electronic devices (CIEDs) is frequently required in the emergency department (ED) or perioperative areas (OR) where resources to do this are often not available. CareLink Express (CLE; Medtronic, plc, Mounds View, MN, USA) is a technician-supported real-time remote interrogation system for Medtronic CIEDs. Using data from 136 US locations, this retrospective study was designed to assess CLE efficiency compared to traditional device management, and examine its findings. All 7,044 US CLE transmissions from the ED and OR (January 2012-October 2014) were compared to 217 traditional requests where CIED interrogations/interpretations were performed by calling industry representatives to these sites. CLE reduced the time to device interrogation/interpretation by 78%: 100 ± 140-22 ± 14 minutes, P < 0.0001, improving response time and consistency; ED: 82 ± 103-23 ± 18 minutes, P, ≤ 0.01; OR: 127 ± 181-17 ± 10 minutes, P < 0.0001. Actionable events (AE) (arrhythmia, device/lead abnormalities) were infrequent: 9.1% overall (ED: 9.9%; OR: 4.1%). Only 6.5% of patients with syncope/presyncope and 13.6% with a perceived shock had AE. AEs were more common in those with suspected device problems (30.4%) or audible alerts (52.6%). They were more likely in patients not enrolled in long-term remote monitoring (23.9% vs 8.2%, P < 0.0001) and in those with older CIED systems (7.4% in year 1 vs 31.0% after 10 years). The many patients with CIEDs, and the ability to quickly identify the minority with high-risk AE from the no/low-risk majority, strongly support CLE use in the ED and OR, sites which are expensive and prioritize efficiency. © 2015 Wiley Periodicals, Inc.

  17. Spacecraft COst REduction Team (SCORE): TQM/CI on a massive scale

    Science.gov (United States)

    Bullard, Jerry D.

    1992-01-01

    The business of building satellites and space systems has matured. Few missions require, or can afford, excellent performance at any price. The new paradigm is doing more with less, providing quality systems at lower cost--in other words, doing our job 'Faster-Better-Cheaper.' The TRW Spacecraft COst REduction (SCORE) initiative was launched in 1990 by Daniel S. Goldin, then general manager of TRW's Space & Technology Group. The SCORE mission is to apply continuous improvement (CI) techniques to effect major reductions in the cost (our primary goal) and span time (as a corollary) required for the production of spacecraft. SCORE is a multi-year initiative that is having a profound effect on both the procedural and the cultural aspects of how we do business. The objectives of this initiative are being realized. The focus of this paper is not on the results of SCORE per se, but rather on the things we have leaned about how to do continuous improvement on a massive scale, with multilevel (hierarchical) CI teams. The following sections summarize the chronology of the SCORE initiative, from team formation to development of the year-end report for 1991. Lessons learned, the core of this presentation, are discussed--with particular focus on the unique aspects of SCORE. The SCORE initiative is continuing and, as a part of our evolving culture, will never end. It has resulted in profound insights into the way we do work and (the topic at hand) how to do CI for large and complex multidisciplinary development activities.

  18. Problem wolności w Internecie / The problem of freedom in Internet

    Directory of Open Access Journals (Sweden)

    Iwona Gleisner

    2013-07-01

    Full Text Available Artykuł jest próbą odpowiedzi na pytanie o granice wolności w Internecie. Dyskusje ten temat, toczące się na całym świecie od dawna, nie dały dotąd zadowalającej odpowiedzi. W ostatnich latach przybiera na sile spór pomiędzy zwolennikami pełnej swobody, a stronnikami prawnego ograniczania korzystania z zasobów globalnej sieci. Autorka przytacza argumenty obu stron konfliktu, zwracając uwagę na potrzebę znalezienia równowagi prawnej pomiędzy interesami twórców, a potrzebami odbiorców. Porusza ponadto istotne zagadnienie moralnej odpowiedzialności autorów za zamieszczane w Internecie treści.English abstractThis paper attempts to find an answer to the question about freedom in Internet. This issue has been discussed all over the world for long, however no satisfactory answer has yet been found. Recently, the dispute between the supporters of the full freedom and the ones voting for limiting the resources of the global network with legal means has been becoming more fierce. The author quotes arguments of both parties to the conflict, drawing attention to the need of finding a legal balance between the interests of the artists and the needs of the consumers. She also tackles with an important issue of moral responsibility of the authors for the contents placed in Internet. Normal 0 21 false false false PL X-NONE X-NONE

  19. A ciência nas utopias de Campanella, Bacon, Comenius, e Glanvill

    Directory of Open Access Journals (Sweden)

    Bernardo Jefferson de Oliveira

    2002-12-01

    Full Text Available Este artigo analisa comparativamente o papel que a ciência e a técnica ocupam nas sociedades descritas em A cidade do Sol de Tommasio Campanella, a Nova Atlântida de Francis Bacon, Panorthosia de Jan Amós Comenius e o Complemento à Nova Atlântida de Joseph Glanvill.This article evaluates the role that science and technology plays in the societies described by early modern utopias, making a comparative analysis of Tommasio Campanella's City of Sun, Francis Bacon's New Atlantis, Jan Amós Comenius' Panorthosia, and Joseph Glanvill's The summe of my lord Bacon's New Atlantis.

  20. Palenie papierosów w ciąży = Cigarette smoking in pregnancy

    Directory of Open Access Journals (Sweden)

    Agnieszka Konstancja Pawłowska-Muc

    2016-01-01

    4 Doctoral Candidate at the Department and Clinic of Gynaecology and Gynaecological Endocrinology, School of Health Studies, Medical University of Lublin, Al. Racławickie 23   Adres do korespondencji: mgr piel. Agnieszka Konstancja Pawłowska-Muc Ośrodek Kształcenia Podyplomowego Pielęgniarek i Położnych Radomski Szpital Specjalistyczny im. dr Tytusa Chałubińskiego w Radomiu, ul. Lekarska 4 tel. 48  3615616; fax: 48 3615437 e-mail: agmich@vp.pl   Streszczenie Wprowadzenie. Palenie papierosów jest dużym problemem zdrowotnym i społeczno – ekonomicznym. Stanowi zagrożenie dla rozrodu, przebiegu ciąży i zdrowia dziecka. Cel pracy. Ukazanie problemu palenia papierosów przez kobiety ciężarne na podstawie przeglądu piśmiennictwa.             Skrócony opis stanu wiedzy. W opracowaniu przedstawiono epidemiologię i skalę problemu oraz konsekwencje palenia w okresie ciąży, z uwzględnieniem podziału na przebieg ciąży i zdrowie dziecka. Omówiono też świadomość kobiet odnośnie negatywnych skutków takich zachowań. Podsumowanie. Z przeglądu piśmiennictwa wynika, że palenie papierosów przez kobiety ciężarne nie należy do rzadkości. Skala problemu nie jest łatwa do oceny, gdyż wiele z nich po prostu nie przyznaje się do tego. Negatywne konsekwencje palenia w ciąży są dość liczne i dotyczą zarówno jej przebiegu, jak i stanu noworodka oraz zdrowia dziecka w późniejszym okresie życia. Istnieje potrzeba kształtowania postaw antynikotynowych, zwłaszcza wśród dziewcząt i kobiet w wieku rozrodczym.   Słowa kluczowe: kobieta ciężarna, palenie papierosów w ciąży.                                                                   Summary Introduction. Smoking cigarettes is a major health and social-economical problem. It poses a threat to reproduction, parturition and the health of the baby. Aim. Illustrating the problem of smoking cigarettes by

  1. Pluralismo metodológico no ensino de ciências Methodological pluralism in science teaching

    Directory of Open Access Journals (Sweden)

    Carlos Eduardo Laburú

    2003-01-01

    Full Text Available Inspirados numa leitura epistemológica feyerabendiana, este trabalho sugere uma abordagem metodológica pluralista para o ensino das ciências. Defendemos que esse estratagema didático seja potencialmente mais eficaz para a aprendizagem, na medida em que procura dar conta do espectro de questões que se apresentam na sala de aula.Inspired by an epistemological reading of Feyerabend, this paper proposes a pluralist methodological approach to science teaching. We propose that this didactic strategy is potentially more effective in the learning process because it tries to account for the spectrum of questions that are presented in the classroom.

  2. Assessing precision, bias and sigma-metrics of 53 measurands of the Alinity ci system.

    Science.gov (United States)

    Westgard, Sten; Petrides, Victoria; Schneider, Sharon; Berman, Marvin; Herzogenrath, Jörg; Orzechowski, Anthony

    2017-12-01

    Assay performance is dependent on the accuracy and precision of a given method. These attributes can be combined into an analytical Sigma-metric, providing a simple value for laboratorians to use in evaluating a test method's capability to meet its analytical quality requirements. Sigma-metrics were determined for 37 clinical chemistry assays, 13 immunoassays, and 3 ICT methods on the Alinity ci system. Analytical Performance Specifications were defined for the assays, following a rationale of using CLIA goals first, then Ricos Desirable goals when CLIA did not regulate the method, and then other sources if the Ricos Desirable goal was unrealistic. A precision study was conducted at Abbott on each assay using the Alinity ci system following the CLSI EP05-A2 protocol. Bias was estimated following the CLSI EP09-A3 protocol using samples with concentrations spanning the assay's measuring interval tested in duplicate on the Alinity ci system and ARCHITECT c8000 and i2000 SR systems, where testing was also performed at Abbott. Using the regression model, the %bias was estimated at an important medical decisions point. Then the Sigma-metric was estimated for each assay and was plotted on a method decision chart. The Sigma-metric was calculated using the equation: Sigma-metric=(%TEa-|%bias|)/%CV. The Sigma-metrics and Normalized Method Decision charts demonstrate that a majority of the Alinity assays perform at least at five Sigma or higher, at or near critical medical decision levels. More than 90% of the assays performed at Five and Six Sigma. None performed below Three Sigma. Sigma-metrics plotted on Normalized Method Decision charts provide useful evaluations of performance. The majority of Alinity ci system assays had sigma values >5 and thus laboratories can expect excellent or world class performance. Laboratorians can use these tools as aids in choosing high-quality products, further contributing to the delivery of excellent quality healthcare for patients

  3. A l-nCi/g sensitivity transuranic waste assay system using pulsed neutron interrogation

    International Nuclear Information System (INIS)

    Kunz, W.E.; Atencio, J.D.; Caldwell, J.T.

    1980-01-01

    We have developed a pulsed thermal neutron interrogation system and have demonstrated a sub-1-nCi/g assay sensitivity for high density TRU wastes contained in 200-liter barrels. We detect prompt fission neutrons, resulting in greatly enhanced sensitivity compared to techniques in which delayed fission neutrons are detected. We observe a linear assay response over at least three orders of magnitude in 235 U (or 239 Pu) mass. We also have measured a flat (to +-10%) interrogation flux profile throughout the volume of a 200-liter barrel filled with 200 kg of sand and vermiculite, which indicates flatness of response to fissile material at different locations within the barrel

  4. Ciénaga (Magdalena, una región administrativa o municipio de enclave

    Directory of Open Access Journals (Sweden)

    Luis Humberto Hernández

    2006-01-01

    Full Text Available El análisis sobre las regiones de enclave, el caso del municipio de Ciénaga, en el Magdalena, nos permitió concluir que su proceso de modernización estuvo determinado por la presencia de la empresa multinacional bananera United Fruit Company. La multinacional bananera fue la que introdujo en la región el trabajo asalariado moderno, dislocando las formas serviles y premodernas existentes. Al atraer la mano de obra servil regional, que utilizaban las haciendas ganaderas, y convertirla en mano de obra asalariada, fundamentó sus procesos socioeconómicos y político administrativo modernos.

  5. A inteligência artificial no contexto das ciências cognitivas

    OpenAIRE

    Lira, Tércio Onofre de

    2011-01-01

    Atualmente existe uma vasta gama de aplicações na área da Inteligência Artificial, porém os progressos caminham a passos curtos no que diz respeito ao desenvolvimento de uma inteligência artificial forte. Esta dissertação busca elucidar a multidisciplinaridade das ciências cognitivas, à qual os estudos da inteligência artificial estão atrelados, por meio da apresentação sucinta, porém panorâmica, do histórico de cada especialidade ou área: neurociência cognitiva, filosofia da m...

  6. As ciências da psique no espiritismo brasileiro: C. 1900-C. 1960

    OpenAIRE

    Leite, Igor Alleoni Silveira

    2016-01-01

    As Ciências da Psique no período que abrange 1900 a 1960 envolvem concepções que remetem nomeadamente à Psiquiatria e a insipiente Psicologia, mas também outras correntes que geraram embates ou simpatizantes frente ao Espiritismo brasileiro, entre elas estaria a Parapsicologia. A região estudada envolve o estado de São Paulo, levando-se em consideração o tempo histórico em que fatores importantes ocorreram no período estabelecido, como os dados identificados na literatura que apontam os confl...

  7. A biotechnological project with a gamma radiation source of 100,000 Ci

    International Nuclear Information System (INIS)

    Lombardo, J.H.; Smolko, E.E.

    1990-01-01

    A project for the production of radiovaccines and other bio-medical products is presented which includes a radiation facility provided with a gamma ray source equivalent to 100,000 Ci of Co-60. The whole process incorporates novel basic features in virus production and inactivation steps. The former is carried out in animals previously subjected to immunodepression through electromagnetic radiation. The latter is obtained at low temperatures by using either electromagnetic or particle radiations. A vaccine manufacture process is shown to illustrate the utilization of ionizing radiations to obtain a foot and mouth disease virus (FMDV) vaccine with good antigenic quality and low cost. (author)

  8. Kriegsbeute-Ausstellung Posen 1917. Propagandowa wystawa dla szerokiej publiczności

    Directory of Open Access Journals (Sweden)

    Jakub Skutecki

    2014-01-01

    Full Text Available W zbiorach ikonograficznych Biblioteki Uniwersyteckiej w Poznaniu znajduje się seria widokówek dokumentujących zorganizowaną w 1917 roku Wystawę Zdobyczy Wojennych (Kriegsbeute-Ausstellung Posen 1917, jedną z serii propagandowych ekspozycji prezentujących sukcesy armii niemieckich na wszystkich frontach wielkiej wojny. W czasie trwania wystawy w pobliżu belgijskiego Passchendaele toczyła się jedna z najkrwawszych bitew, a w Poznaniu – codzienne życie w wojennej rzeczywistości.

  9. The eclipse of CI Cygni in 1980 on the objective prism spectra

    International Nuclear Information System (INIS)

    Mikolajewska, J.; Mikolajewski, M.

    1982-01-01

    The observations of CI Cyg were carried out with the Torun 60/90 cm Schmidt telescope with the objective prism giving a dispersion of 250 A/mm at H-gamma. Intensity traces of 20 selected spectra, made on the Kodak IIa-O plates, were made. The results were corrected for all instrumental effects and the interstellar extinction. The relative emission lines intensities have been obtained from the tracings after normalization to H-beta = 100. The spectra were typical for the quiet symbiotic star. So, all changes in the spectrum were caused by geometrical effects (eclipse). A preliminary analysis of the obtained spectra is presented. (Auth.)

  10. Filosofia da ciência como ferramenta microeconômica

    OpenAIRE

    Fabio Barbieri

    2006-01-01

    A teoria neoclássica pressupõe conhecimento perfeito. A crítica hayekiana a essa teoria, por sua vez, afirma que esse conhecimento é resultado do processo competitivo e, portanto, não pode ser considerado como dado. O "Problema de Hayek" investiga sob que condições o conhecimento do agente se aproxima dos reais fundamentos de uma economia. A fim de solucionar o "Problema de Hayek", o nosso artigo utiliza algumas idéias da literatura de metodologia da Ciência, conhecida como teoria do "crescim...

  11. High-spin states in 60Cu

    International Nuclear Information System (INIS)

    Tsan, U.C.; Agard, M.; Bruandet, J.F.; Dauchy, A.; Giorni, A.; Glasser, F.; Morand, C.; Chambon, B.; Drain, D.

    1981-04-01

    The 60 Cu nucleus has been studied via the 58 Ni(α, pnγ) reaction using different in-beam γ spectroscopy techniques. As for the other odd-odd Cu, the gsub(9/2) shell plays an important role for the explanation of observed high-spin states. Some of them (in particular 6 - and 9 + states) could be interpreted as two-nucleon states in the framework of a crude shell model

  12. BiCaSrCuO superconductors

    International Nuclear Information System (INIS)

    Polvi, V.M.; Niemi, K.J.

    1989-01-01

    BiCaSrCuO and BiPbCaSrCuO powders have been synthesized. Different research methods (SEM,EDS,XRF,SRD,DTA) have been used to characterize the bulk specimen and wires. Resistance and current density measured as a function of temperature are reported. The ceramic products contained several phases. Lead containing specimen gave the best results and the synthesis was easily reproducible

  13. Fabrication of new phosphors of NaCl: Cu and their thermoluminescent characterization to be exposed to beta radiation

    International Nuclear Information System (INIS)

    Bernal, R.; Perez S, R.; Barboza F, M.; Tostado G, W.C.; Cruz V, C.

    2004-01-01

    In this work, we report the fabrication of new NaCl:Cu phosphors manufactured by following a previously reported sintering method. The samples were made from mixtures of commercially available Na CI and Cu Cl high purity powders. Tl glow curves obtained after exposing the samples to beta radiation exhibit two main intense peaks at 117 and 310 when a 2 C/s heating rate is used. These peaks positions differ from those reported for NaCl:Cu monocrystals. The first peak vanishes in ca. 3 h, while the high temperature one remains with no meaningful changes. The position, as well as the remarkable stability of the high temperature peak indicates that this new phosphors have better properties than the monocrystals present to be applied as detectors and dosimeters of ionizing radiation. (Author)

  14. A nova convergência da ciência e da tecnologia

    Directory of Open Access Journals (Sweden)

    Esper A. Cavalheiro

    2007-07-01

    Full Text Available A ação sinérgica dos quatro campos científicos e tecnológicos que apresentaram crescimento acelerado nas últimas décadas - nanotecnologia, biotecnologia, tecnologias de comunicação e informação e ciências cognitivas (neurociência - tem sido intitulada Convergência Tecnológica. Este artigo faz uma revisão das principais discussões que vêm ocorrendo na comunidade científica internacional sobre o seu desenvolvimento e assinala a necessidade de uma abordagem mais ampla que inclua as ciências humanas e sociais e outros atores relevantes na sociedade contemporânea.The synergic combination of the scientific and technological fields that presented a rapid growth rate in the last few decades - nanotechnology, biotechnology, information and communication technologies, and cognitive science including neuroscience - is nowadays known as Convergent Technologies. This paper reviews its recent impact on the international scientific community and points out the need of amplifying the discussions to include humanities and social sciences and other important actors of contemporary society.

  15. Ultrasonic assisted dyeing: dyeing of acrylic fabrics C.I. Astrazon Basic Red 5BL 200%.

    Science.gov (United States)

    Kamel, M M; Helmy, H M; Mashaly, H M; Kafafy, H H

    2010-01-01

    The dyeing of acrylic fabrics using C.I. Astrazon Basic Red 5BL 200% has been studied with both conventional and ultrasonic techniques. The effect of dye concentration, dye bath pH, ultrasonic power, dyeing time and temperature were studied and the resulting shades obtained by dyeing with both techniques were compared. Colour strength values obtained were found to be higher with ultrasonic than with conventional heating. The results of fastness properties of the dyed fabrics were studied. X-ray and Scanning Electron Microscope SEM were carried out on dyed samples using both methods of dyeing to find out an explanation for the better dyeability of acrylic fabrics with (US) method. Dyeing kinetics of acrylic fabrics using C.I. Astrazon Basic Red 5BL 200% using conventional and ultrasonic conditions were compared. The time/dye-uptake isotherms are revealing the enhanced dye-uptake in the second phase of dyeing. The values of dyeing rate constant, half-time of dyeing and standard affinity and ultrasonic efficiency have been calculated and discussed.

  16. Filosofia da ciência como ferramenta microeconômica

    Directory of Open Access Journals (Sweden)

    Fabio Barbieri

    2009-06-01

    Full Text Available A teoria neoclássica pressupõe conhecimento perfeito. A crítica hayekiana a essa teoria, por sua vez, afirma que esse conhecimento é resultado do processo competitivo e, portanto, não pode ser considerado como dado. O “Problema de Hayek” investiga sob que condições o conhecimento do agente se aproxima dos reais fundamentos de uma economia. A fim de solucionar o “Problema de Hayek”, o nosso artigo utiliza algumas idéias da literatura de metodologia da Ciência, conhecida como teoria do “crescimento do conhecimento” (Popper, Kuhn, Lakatos e outros. Essas idéias são utilizadas para se compreender como evolui o conhecimento dos agentes econômicos, em especial o dos empresários. Estes são vistos como ativos formuladores de teorias empresariais conjecturais criticadas no processo competitivo, não como agentes passivos que maximizam funções já conhecidas da teoria convencional. Utiliza-se a Filosofia da Ciência não para analisar metodologicamente a microeconomia, mas, sim, como ferramenta analítica pertencente à própria teoria econômica.

  17. Masculinidade e ciúme na perspectiva da teoria da sedução generalizada

    Directory of Open Access Journals (Sweden)

    Paulo Carvalho Ribeiro

    2012-09-01

    Full Text Available Partindo das contribuições freudianas sobre as relações do ciúme com a projeção e a homossexualidade, propõe-se no presente artigo uma retomada do papel do masoquismo primário e da identificação feminina como elementos definidores do ciúme masculino patológico. As condições originárias de constituição do psiquismo, vistas sob o ângulo da Teoria da Sedução Generalizada, proposta por Jean Laplanche, são relacionadas tanto ao masoquismo primário quanto à identificação feminina. A situação assimétrica entre o adulto, portador de uma sexualidade inconsciente, e a criança, destituída de recursos psíquicos para lidar com as mensagens sexuais do adulto, caracteriza, segundo esse autor, a situação antropológica fundamental.

  18. Aprendizagem baseada em problemas no ensino de ciências: Mudando atitudes de alunos e professores

    Directory of Open Access Journals (Sweden)

    João Manoel da Silva Malheiro

    2008-06-01

    Full Text Available O aprendizado baseado em problemas (APB é apontado como ferramenta importante para ensinar os alunos a aprender com autonomia. O objetivo deste trabalho é comparar a forma habitual de ensinar Ciências e Biologia no Ensino Médio da Escola Pública com a metodologia da Aprendizagem Baseada em Problemas (ABP. Para tanto, dois Cursos de Férias frequentados por alunos e professores do ensino médio foram baseados na ABP e dedicados à redescoberta da anatomia do corpo de animais com estilos de vida contrastantes. Foram feitas análises qualitativas e quantitativas a partir de questionários aplicados antes e depois dos cursos a alunos e professores. Os resultados apontaram para maior motivação dos alunos e professores em ciências e biologia após os cursos de férias e para a possibilidade da utilização imediata da metodologia no ensino médio na escola pública a despeito das restrições atuais de infra-estrutura.

  19. A cobertura de ciência em três jornais paraenses: um estudo longitudinal

    Directory of Open Access Journals (Sweden)

    Vanessa Brasil de Carvalho

    Full Text Available Resumo Neste artigo, apresentamos uma proposta metodológica visando realizar um estudo longitudinal que fornecesse um panorama da cobertura de ciência em 130 anos, por três jornais importantes do Estado do Pará: A Província do Pará (1876-2002, Folha do Norte (1896-1974 e O Liberal (1946-atual. Analisamos um período de dois meses a cada dez anos, de 1876 a 2006, em cada jornal selecionado, de maneira que obtivemos um olhar em longo prazo que perpassou pela história dos periódicos e, portanto, por grande parte da história da imprensa no Pará e na Amazônia. Utilizamos análise de conteúdo e análise de frames da Mídia. Nossos dados mostram que houve ênfase na pesquisa em saúde, destaque para a ciência nacional e preocupação em contextualizar os fatos científicos. Controvérsias e incertezas científicas ganharam pouco espaço nos jornais analisados.

  20. Elastocaloric effect in CuAlZn and CuAlMn shape memory alloys under compression

    OpenAIRE

    Qian, Suxin; Geng, Yunlong; Wang, Yi; Pillsbury, Thomas E.; Hada, Yoshiharu; Yamaguchi, Yuki; Fujimoto, Kenjiro; Hwang, Yunho; Radermacher, Reinhard; Cui, Jun; Yuki, Yoji; Toyotake, Koutaro; Takeuchi, Ichiro

    2016-01-01

    This paper reports the elastocaloric effect of two Cu-based shape memory alloys: Cu68Al16Zn16 (CuAlZn) and Cu73Al15Mn12 (CuAlMn), under compression at ambient temperature. The compression tests were conducted at two different rates to approach isothermal and adiabatic conditions. Upon unloading at a strain rate of 0.1 s−1 (adiabatic condition) from 4% strain, the highest adiabatic temperature changes (ΔTad) of 4.0 K for CuAlZn and 3.9 K for CuAlMn were obtained. The maximum stress and hystere...

  1. Ustawodawstwo Unii Europejskiej wobec mniejszości narodowych i etnicznych - casus romski

    Directory of Open Access Journals (Sweden)

    Wojciech Marcin Stankiewicz

    2014-12-01

    of the Roma minority and replace it with another. That is why the European Union should develop a range of mechanisms and measures that may be accepted by the Roma.   Ustawodawstwo Unii Europejskiej wobec mniejszości narodowych i etnicznych - casus romski Unia Europejska znajduje się dopiero na etapie tworzenia systemu ochrony mniejszości narodowych i etnicznych, jednak niezbędne będzie podjęcie wielu starań, debat oraz działań, w które koniecznie zaangażowane muszą być wszystkie państwa członkowskie. Próby podejmowane przez Parlament Europejski w celu poprawy sytuacji mniejszości narodowych i etnicznych w Unii Europejskiej mogą być odpowiednim impulsem do wstępnych refleksji. Pomimo wielu starań Unii Europejskiej oraz wykorzystania funduszy unijnych sytuacja mniejszości romskiej nie uległa dużej poprawie. Głównymi przyczynami są niedostateczne działania ze strony Unii Europejskiej, korupcja urzędników, a także brak zainteresowania społecznością romską państw członkowskich. Dotychczas podjęte działania nie przyniosły zamierzonych rezultatów, dlatego konieczne jest poświęcenie większej uwagi tej kwestii. Unia Europejska potrzebuje mocnego wsparcia innych instytucji unijnych oraz społeczeństwa obywatelskiego.

  2. Jaką teorią jest Marksowska teoria wartości opartej na pracy?

    Directory of Open Access Journals (Sweden)

    Krzysztof Nowak-Posadzy

    2015-12-01

    Full Text Available Tak zwana teoria wartości opartej na pracy (odtąd LTV, niegdyś powód do dumy całego środowiska marksistowskiego, stawała się z upływem lat przedmiotem jego zakłopotania. Jej odrzucenie w ramach tradycji lewicowej, zarówno przez część filozofów, jak i ekonomistów, wpisuje się w szersze zjawisko zwane „kryzysem marksizmu”. Wówczas to filozoficzna część środowiska marksistowskiego, chcąc uwolnić marksizm od wad „ekonomizmu”, odcięła go także od zalet mogących płynąć z przyjęcia perspektywy ekonomii teoretycznej. Natomiast część ekonomiczna przywołanego środowiska, chcąc uwolnić ekonomię marksistowską od niedociągnięć tkwiących w LTV, odcięła ją także od szczególnego statusu przypisywanego w tej tradycji intelektualnej pojęciu pracy. Chociaż uniewinniono później LTV od zarzutu o domniemaną logiczną sprzeczność, to jedynie po to, aby skazać ją następnie na zapomnienie za jej rzekomą zbyteczność. W niniejszym artykule omówiona zostanie specyfika Marksowskiej wersji LTV. We wstępie podane zostaną cztery jakościowe założenia, które, zdaniem autora, przesądzają o charakterze Marksowskiej wersji LTV, W pierwszej części zarysowane zostanie miejsce LTV w historii myśli ekonomicznej. Druga część dotyczyć będzie losów Marksowskiej wersji LTV w ramach samej tradycji marksistowskiej. W trzeciej części omówiony zostanie problem wartości i jej pomiaru. Czwarta część zostanie poświęcona analizie problemu pracy i wyboru jednostki jej pomiaru, a także próbie zrekonstruowania Marksowskiej teorii reprodukcji pracowników za pomocą pracy. W części piątej podjęta zostanie kwestia tego, jak interpretuje się współcześnie status metodologiczny marksowskiej wersji LTV. Artykuł kończy podsumowanie.

  3. Magnetron sputtered Cu{sub 3}N/NiTiCu shape memory thin film heterostructures for MEMS applications

    Energy Technology Data Exchange (ETDEWEB)

    Kaur, Navjot; Choudhary, Nitin [Indian Institute of Technology Roorkee, Roorkee, Functional Nanomaterials Research Lab, Department of Physics and Centre of Nanotechnology (India); Goyal, Rajendra N. [Indian Institute of Technology, Roorkee, Department of Chemistry (India); Viladkar, S. [Indian Institute of Technology Roorkee, Roorkee, Functional Nanomaterials Research Lab, Department of Physics and Centre of Nanotechnology (India); Matai, I.; Gopinath, P. [Indian Institute of Technology, Roorkee, Centre for Nanotechnology (India); Chockalingam, S. [Indian Institute of Technology, Guwahati, Department of Biotechnology (India); Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in [Indian Institute of Technology Roorkee, Roorkee, Functional Nanomaterials Research Lab, Department of Physics and Centre of Nanotechnology (India)

    2013-03-15

    In the present study, for the first time, Cu{sub 3}N/NiTiCu/Si heterostructures were successfully grown using magnetron sputtering technique. Nanocrystalline copper nitride (Cu{sub 3}N with thickness {approx}200 nm) thin films and copper nanodots were subsequently deposited on the surface of 2-{mu}m-thick NiTiCu shape memory thin films in order to improve the surface corrosion and nickel release properties of NiTiCu thin films. Interestingly, the phase transformation from martensite phase to austenite phase has been observed in Cu{sub 3}N/NiTiCu heterostructures with corresponding change in texture and surface morphology of top Cu{sub 3}N films. Field emission scanning electron microscopy and atomic force microscope images of the heterostructures reveals the formation of 20-nm-sized copper nanodots on NiTiCu surface at higher deposition temperature (450 Degree-Sign C) of Cu{sub 3}N. Cu{sub 3}N passivated NiTiCu films possess low corrosion current density with higher corrosion potential and, therefore, better corrosion resistance as compared to pure NiTiCu films. The concentration of Ni released from the Cu{sub 3}N/NiTiCu samples was observed to be much less than that of pure NiTiCu film. It can be reduced to the factor of about one-ninth after the surface passivation resulting in smooth, homogeneous and highly corrosion resistant surface. The antibacterial and cytotoxicity of pure and Cu{sub 3}N coated NiTiCu thin films were investigated through green fluorescent protein expressing E. coli bacteria and human embryonic kidney cells. The results show the strong antibacterial property and non cytotoxicity of Cu{sub 3}N/NiTiCu heterostructure. This work is of immense technological importance due to variety of BioMEMS applications.

  4. Wykorzystanie informacji prospektywnychw sprawozdawczości finansowej zorientowanejna wartość na przykładzie MSR 36„Utrata wartości aktywów”

    Directory of Open Access Journals (Sweden)

    Irena Sobańska

    2009-12-01

    Full Text Available Autorzy artykułu wskazują na istotę i rosnące znaczenie informacji prospektywnych we współczesnych systemach sprawozdawczości finansowej opartej na MSSF. Ewolucja dokonująca się w sprawozdawczości finansowej, pod wpływem harmonizacji zasad rachunkowości wskutek ciągle zmieniających się MSSF, została przedstawiona na tle zmian dokonujących się w otoczeniu, w celach i w systemach zarządzania (orientacja strategiczna, wartość przedsiębiorstwa, jak również w systemach strategicznej rachunkowości zarządczej. Na podstawie szerokiego kontekstu analizy autorzy stawiają wniosek, że koncepcja wartości (przedsiębiorstwa stanowi istotny element systemu pomiaru i wyceny w systemie sprawozdawczości finansowej. Tworzy ona także spójną podstawę dla integracji rachunkowości zarządczej i rachunkowości finansowej w jeden system zapewniający użyteczne informacje zarówno dla użytkowników zewnętrznych, jak i wewnętrznych, których łączy wspólny cel – maksymalizacja wartości. Uwarunkowania tworzenia systemu sprawozdawczości opartego na informacjach prospektywnych, zorientowanego na wartość, jak również stopień dostosowania przedsiębiorstw do jego wdrożenia pokazano na przykładzie praktycznej realizacji postanowień MSR 36.

  5. Escrevendo em aulas de ciências Writing in science classes

    Directory of Open Access Journals (Sweden)

    Carla Marques Alvarenga de Oliveira

    2005-12-01

    Full Text Available Neste artigo, apresentamos uma análise dos registros escritos dos alunos do 3° ano do Ensino Fundamental nas aulas de Ciências, em que a professora utilizou as atividades de conhecimento físico, criadas pelo Laboratório de Pesquisa e Ensino de Física da Faculdade de Educação da Universidade de São Paulo. Os registros analisados foram coletados na Escola de Aplicação da Feusp, no ano de 2001, durante o acompanhamento de três aulas de Ciências: o problema do submarino, o problema do barquinho e o problema da pressão. O artigo procura mostrar um panorama de como aparecem os registros realizados pelos alunos, após uma aula de Ciências em que eles são levados a resolver situações problemáticas por meio da experimentação, argumentar e escrever sobre os fenômenos físicos. Durante a análise, levou-se em consideração os tipos de textos que os alunos escrevem, o uso da primeira pessoa, o uso de verbos de ação, o respeito à ordem cronológica dos eventos e quais os tipos de explicações os alunos atribuem aos fenômenos trabalhados.This article analyzed the written records of Third Grade students of Elementary School at Escola de Aplicação, Universidade de São Paulo, gathered during the Science classes of the 2001 school year, in which activities about physical understanding were used. Created by the Laboratory of Research and Teaching of Physics - LAPEF, of the College of Education of USP, the activities "The Problem of the Submarine", "The Problem of the Little Boat" and "The Problem of the Pressure" required the students to solve problematic situations through experimentation, developing arguments and write about the phenomena. The study developed a framework of how the records are presented by the students, considering the types of texts they produce, the use of the first person, the use of verbs of action, the respect of the chronological order of events and the types of explanations the students give for the

  6. Fałszywy znak równości

    Directory of Open Access Journals (Sweden)

    Efraim Zuroff

    2012-12-01

    Full Text Available The equivalency canard Efraim Zuroff's text, originally published in Haaretz magazine, is a review of Timothy Snyder's Bloodlands. Snyder distinguishes six main mass murders commited by Nazi Germany and Soviet Union during the period of the Third Reich's existence. In Zuroff's opinion there are some significant differences between these tragedies. Dubious comparisons proposed by Snyder made the Holocaust most affected. Describing the Shoah as one of the six equally horryfying mass murders, the author ignores its ideological roots. Roots that sentenced to death all Jews  - regardless of their political views, religious practicies or the level of identification with Jewish community. Moreover Snyder takes no notice of the georaphical scope of the Holocaust. He also does not notice the fact, that the Nazis effectively managed to make so many Europeans their accomplices, who actively supported the Shoah.   Fałszywy znak równości Tekst Efraima Zuroffa, który pierwotnie ukazał się w piśmie Haaretz, to recenzja książki Skrwawione ziemie Timothy Snydera. Snyder wyróżnia sześć głównych masowych mordów popełnionych przez Niemcy i Związek Radziecki w okresie, który odpowiada istnieniu Trzeciej Rzeszy. Istnieją jednak, zdaniem Zuroffa, znaczące różnice między tymi tragediami. Na wątpliwych porównaniach, które proponuje Snyder, najbardziej „ucierpiał” Holokaust. Opisując Shoah jako jeden z sześciu równie straszliwych, masowych mordów, autor pomija jego ideologiczne korzenie, które sprawiały, że na śmierć skazany był każdy bez wyjątku Żyd, niezależnie od jego poglądów politycznych, praktyk religijnych czy stopnia identyfikacji z żydowską wspólnotą. Ponadto Snyder ignoruje ogromny zasięg geograficzny Holokaustu. Nie zauważa także skuteczności, z jaką naziści potrafili uczynić swoimi wspólnikami tak wielu Europejczyków, którzy w konsekwencji aktywnie wspomagali Shoah.

  7. Improving Vegetable Oil Fueled CI Engine Characteristics Through Diethyl Ether Blending

    KAUST Repository

    Vedharaj, S.

    2016-12-01

    In this research, the flow and ignition properties of vegetable oil (VO) are improved by blending it with diethyl ether (DEE). DEE, synthesized from ethanol, has lower viscosity than diesel and VO. When DEE is blended with VO, the resultant DEEVO mixtures have favorable properties for compression ignition (CI) engine operation. As such, DEEVO20 (20% DEE + 80% VO) and DEEVO40 (40% DEE + 60% VO) were initially considered in the current study. The viscosity of VO is 32.4*10−6 m2/s; the viscosity is reduced with the increase of DEE in VO. In this study, our blends were limited to a maximum of 40% DEE in VO. The viscosity of DEEVO40 is 2.1*10−6 m2/s, which is comparable to that of diesel (2.3*10−6 m2/s). The lower boiling point and flash point of DEE improves the fuel spray and evaporation for DEEVO mixtures. In addition to the improvement in physical properties, the ignition quality of DEEVO mixtures is also improved, as DEE is a high cetane fuel (DCN = 139). The ignition characteristics of DEEVO mixtures were studied in an ignition quality tester (IQT). There is an evident reduction in ignition delay time (IDT) for DEEVO mixtures compared to VO. The IDT of VO (4.5 ms), DEEVO20 (3.2 ms) and DEEVO40 (2.7 ms) was measured in IQT. Accordingly, the derived cetane number (DCN) of DEEVO mixtures increased with the increase in proportion of DEE. The reported mixtures were also tested in a single cylinder CI engine. The start of combustion (SOC) was advanced for DEEVO20 and DEEVO40 compared to diesel, which is attributed to the high DCN of DEEVO mixtures. On the other hand, the peak heat release rate decreased for DEEVO mixtures compared to diesel. Gaseous emissions such as nitrogen oxide (NOX), total hydrocarbon (THC) and smoke were reduced for DEEVO mixtures compared to diesel. The physical and ignition properties of VO are improved by the addition of DEE, and thus, the need for the trans-esterification process is averted. Furthermore, this blending strategy is simpler

  8. Improving Vegetable Oil Fueled CI Engine Characteristics Through Diethyl Ether Blending

    KAUST Repository

    Vedharaj, S.; Vallinayagam, R.; Sarathy, Mani; Dibble, Robert W.

    2016-01-01

    In this research, the flow and ignition properties of vegetable oil (VO) are improved by blending it with diethyl ether (DEE). DEE, synthesized from ethanol, has lower viscosity than diesel and VO. When DEE is blended with VO, the resultant DEEVO mixtures have favorable properties for compression ignition (CI) engine operation. As such, DEEVO20 (20% DEE + 80% VO) and DEEVO40 (40% DEE + 60% VO) were initially considered in the current study. The viscosity of VO is 32.4*10−6 m2/s; the viscosity is reduced with the increase of DEE in VO. In this study, our blends were limited to a maximum of 40% DEE in VO. The viscosity of DEEVO40 is 2.1*10−6 m2/s, which is comparable to that of diesel (2.3*10−6 m2/s). The lower boiling point and flash point of DEE improves the fuel spray and evaporation for DEEVO mixtures. In addition to the improvement in physical properties, the ignition quality of DEEVO mixtures is also improved, as DEE is a high cetane fuel (DCN = 139). The ignition characteristics of DEEVO mixtures were studied in an ignition quality tester (IQT). There is an evident reduction in ignition delay time (IDT) for DEEVO mixtures compared to VO. The IDT of VO (4.5 ms), DEEVO20 (3.2 ms) and DEEVO40 (2.7 ms) was measured in IQT. Accordingly, the derived cetane number (DCN) of DEEVO mixtures increased with the increase in proportion of DEE. The reported mixtures were also tested in a single cylinder CI engine. The start of combustion (SOC) was advanced for DEEVO20 and DEEVO40 compared to diesel, which is attributed to the high DCN of DEEVO mixtures. On the other hand, the peak heat release rate decreased for DEEVO mixtures compared to diesel. Gaseous emissions such as nitrogen oxide (NOX), total hydrocarbon (THC) and smoke were reduced for DEEVO mixtures compared to diesel. The physical and ignition properties of VO are improved by the addition of DEE, and thus, the need for the trans-esterification process is averted. Furthermore, this blending strategy is simpler

  9. Branding Grenlandii formą ekspresji tożsamości narodowej?

    Directory of Open Access Journals (Sweden)

    Dominika Bartnik-Światek

    2016-01-01

    Full Text Available Branding Greenland as a form of expression of national identity? In the times of globalisation there is a tendency for countries to differentiate from others. More and more governments decide to launch professional nation branding campaigns in order to communicate to a broad public what a particular country has to offer as well as what values and images it wants to be associated with. Greenland is an example of a country that after a long period of colonisation and establishing self-government, in 2009 began to redefine its identity and reveal it to the world. A branding campaign has been implemented to communicate a newly defined image of Greenland. This campaign has been carried out using mainly social media and the tools that the Internet has to offer. The aim of this paper is to explore the concept of nation branding and to define the relation between nation branding and national identity. The purpose is also to analyse what images of Greenland as a brand are presented by “Pioneering nation” campaign.   Branding Grenlandii formą ekspresji tożsamości narodowej? W czasach globalizacji poszczególne państwa starają się wyróżnić na tle innych państw. Coraz więcej rządów decyduje się na przeprowadzenie profesjonalnych kampanii brandingowych, po to by podkreślić swoją wyjątkowość oraz to, że mają dużo do zaoferowania. Grenlandia to przykład państwa, które po długim okresie skolonizowania i po uzyskaniu autonomii w 2009 roku, zaczęło na nowo definiować swoją tożsamość i komunikować ją światu. W tym celu wdrożona została kampania, która wykorzystywała głównie media społecznościowe oraz inne narzędzia, które zapewnia internet. Celem niniejszego artykułu jest zbadanie zależności między brandingiem narodowym a tożsamością narodową, jak też analiza obrazu Grenlandii jako marki konstruowanej w kampanii „Pioneering nation”.

  10. Meta-analysis of Zn, Cu and Fe in the hair of Chinese children with recurrent respiratory tract infection.

    Science.gov (United States)

    Mao, Song; Zhang, Aihua; Huang, Songming

    2014-10-01

    Trace elements play an important role in maintaining the normal metabolic and immune function. The onset of recurrent respiratory tract infection (RRI) is associated with the immune function, genetic factors and nutritional status. However, the association between the levels of trace elements and RRI remains inconclusive. We aimed to investigate the alterations of hair levels of zinc (Zn), copper (Cu) and iron (Fe) in Chinese children with RRI by performing a meta-analysis. A predefined electronic databases search was performed to identify eligible studies for the analysis of hair Zn, Cu or Fe levels in Chinese children with RRI. Thirteen studies were included. RRI patients displayed significantly lower levels of hair Zn (13 studies, random effects SMD: - 1.215, 95% CI: - 1.704 to - 0.725, p SMD: - 0.384, 95% CI: - 0.717 to - 0.052, p = 0.023) and Fe (12 studies, random effects SMD: - 0.569, 95% CI: - 0.827 to - 0.312, p < 0.0001) compared with controls. No evidence of publication bias was observed. Sensitivity analysis did not change the results significantly. In conclusion, the deficiency of Zn, Cu and Fe may be contributing factors for the susceptibility of RRI in Chinese children. However, more studies in different ethnicities should be performed in the future.

  11. Cu/Cu{sub 2}O/CuO loaded on the carbon layer derived from novel precursors with amazing catalytic performance

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Xiaoli, E-mail: zhaoxiaoli_zxl@126.com [State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); Tan, Yixin [State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China); Wu, Fengchang, E-mail: wu_fengchang@126.com [State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); Niu, Hongyun [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China); Tang, Zhi [State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); Cai, Yaqi [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China); Giesy, John P. [State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); Department of Veterinary Biomedical Sciences and Toxicology Centre, University of Saskatchewan, Saskatoon, Saskatchewan (Canada)

    2016-11-15

    A simple, novel method for synthesis of Cu/Cu{sub 2}O/CuO on surfaces of carbon (Cu/Cu{sub 2}O/CuO@C) as a non-noble-metal catalyst for reduction of organic compounds is presented. Compared with noble metals, Cu/Cu{sub 2}O/CuO@C particles are more efficient and less expensive. Characterization of the Cu/Cu{sub 2}O/CuO@C composites by high-resolution transmission electron microscope (HRTEM), x-ray diffraction (XRD), infrared spectroscopy and Raman analysis, revealed that it was composed of graphitized carbon with numerous nanoparticles (100 nm in diameter) of Cu/CuO/Cu{sub 2}O that were uniformly distributed on internal and external surfaces of the carbon support. Gallic acid (GA) has been used as both organic ligand and carbon precursor with metal organic frameworks (MOFs) as the sacrificial template and metal oxide precursor in this green synthesis. The material combined the advantages of MOFs and Cu-containing materials, the porous structure provided a large contact area and channels for the pollutions, which results in more rapid catalytic degradation of pollutants and leads to greater efficiency of catalysis. The material gave excellent catalytic performance for organic dyes and phenols. In this study, Cu/Cu{sub 2}O/CuO@C was used as catalytic to reduce 4-NP, which has been usually adopted as a model reaction to check the catalytic ability. Catalytic experiment results show that 4-NP was degraded approximately 3 min by use of 0.04 mg of catalyst and the conversion of pollutants can reach more than 99%. The catalyst exhibited little change in efficacy after being utilized five times. Rates of degradation of dyes, such as Methylene blue (MB) and Rhodamine B (RhB) and phenolic compounds such as O-Nitrophenol (O-NP) and 2-Nitroaniline (2-NA) were all similar. - Highlights: • We present an effective catalyst for reductive degradation of organic dyes and phenols in water. • Compared with noble metals, Cu/Cu{sub 2}O/CuO@C particles are more efficient and less

  12. Behavior of CuP and OFHC Cu anodes under electrodeposition conditions

    Energy Technology Data Exchange (ETDEWEB)

    Frankel, G.S.; Schrott, A.G.; Horkans, J.; Andricacos, P.C. (International Business Machines Corp., Yorktown Heights, NY (United States). Thomas J. Watson Research Center); Isaacs, H.S. (Brookhaven National Lab., Upton, NY (United States))

    1992-01-01

    Films formed on CuP (with 0.05 wt % P) and OFHC Cu anodes in electroplating solutions were studied by X-ray Photoelectron Spectroscopy, X-ray Absorption Spectroscopy, electrochemical methods, and a newly developed gravimetric technique. The black film formed on CuP in Cl-containing solutions was found to resemble a porous sponge composed of CuCl but laden/with concentrated CuSO{sub 4} solution. The difference between the buoyancy-corrected measured mass change and the charge-equivalent mass change was found to have two components: a reversible part that comes and goes as the current is turned on and off, and an irreversible part that remains on the surface and increase in mass with time. The irreversible part results from the anodic film, which increases linearly with charge density but independent of current density. The reversible part of the mass change arises from the weight of the diffusion layer. In contrast to CuP, OFHC Cu releases much more Cu{sup +1} during anodic polarization and forms a poorly-adherent anodic film that is considerably heavier than the black film for a given charge density.

  13. Behavior of CuP and OFHC Cu anodes under electrodeposition conditions

    Energy Technology Data Exchange (ETDEWEB)

    Frankel, G.S.; Schrott, A.G.; Horkans, J.; Andricacos, P.C. [International Business Machines Corp., Yorktown Heights, NY (United States). Thomas J. Watson Research Center; Isaacs, H.S. [Brookhaven National Lab., Upton, NY (United States)

    1992-08-01

    Films formed on CuP (with 0.05 wt % P) and OFHC Cu anodes in electroplating solutions were studied by X-ray Photoelectron Spectroscopy, X-ray Absorption Spectroscopy, electrochemical methods, and a newly developed gravimetric technique. The black film formed on CuP in Cl-containing solutions was found to resemble a porous sponge composed of CuCl but laden/with concentrated CuSO{sub 4} solution. The difference between the buoyancy-corrected measured mass change and the charge-equivalent mass change was found to have two components: a reversible part that comes and goes as the current is turned on and off, and an irreversible part that remains on the surface and increase in mass with time. The irreversible part results from the anodic film, which increases linearly with charge density but independent of current density. The reversible part of the mass change arises from the weight of the diffusion layer. In contrast to CuP, OFHC Cu releases much more Cu{sup +1} during anodic polarization and forms a poorly-adherent anodic film that is considerably heavier than the black film for a given charge density.

  14. Synthesis and photocatalytic activity of carbon spheres loaded Cu2O/Cu composites

    International Nuclear Information System (INIS)

    Li, Yinhui; Zhao, Mengyao; Zhang, Na; Li, Ruijuan; Chen, Jianxin

    2015-01-01

    Highlights: • Carbon spheres loaded Cu 2 O/Cu composites are obtained by hydrothermal process. • Cu 2 O/Cu nanocrystals grow on the surface of carbon spheres. • The composites with core–shell structure show highly photo-catalytic activity. • The composites can degrade methyl orange under simulated solar light irradiation. • The composites can be used to treat dye wastewater or organic pollutants. - Abstract: In this work, using amylose as carbon source and cupric acetate as copper source, carbon spheres loaded Cu 2 O/Cu composites were obtained by hydrothermal synthesis. The effects of the molar ratios between glucose and Cu(II), and hydrothermal time on the morphology and sizes of the composites were investigated. The result of photocatalytic experiments demonstrated that the composites could degrade methyl orange in aqueous solution under simulated solar light irradiation. The highest degradation rate was achieved to 93.83% when the composites were prepared by hydrothermal synthesis at 180 °C for 16 h and the molar ratio between glucose and Cu(II) was 10/1. The composites, as new and promising materials, can be used to treat dye wastewater or other organic pollutants

  15. Strength and reliability of low temperature transient liquid phase bonded Cu-Sn-Cu interconnects

    DEFF Research Database (Denmark)

    Brincker, Mads; Söhl, Stefan; Eisele, Ronald

    2017-01-01

    As power electronic devices have tendencies to operate at higher temperatures and current densities, the demand for reliable and efficient packaging technologies are ever increasing. This paper reports the studies on application of transient liquid phase (TLP) bonding of CuSnCu systems...

  16. Impact parameter dependence of K-shell ionization in Cu-Cu collisions

    International Nuclear Information System (INIS)

    Frank, W.; Jaracz, P.; Kaun, K.-H.; Lenk, M.; Rudiger, J.; Stachura, Z.

    1980-01-01

    The impact parameter dependence of the yield of K-shell vacancy production in 1 MeV/ a.m.u. Cu-Cu collisions has been studied in an X-ray-scattered ion coincidence experiment. The results are compared with existing models for K-vacancy production

  17. Synthesis and magnetic properties of multilayer Ni/Cu and NiFe/Cu ...

    Indian Academy of Sciences (India)

    The diameter of wires can be easily varied by pore size of alumina, ranging ... saturated HgCl2 solution to remove the remaining Al, and then dipped in 5 wt% ... for NiFe alloy it is 1.3 V, that is higher than for Ni/Cu nanowires to diminish Cu.

  18. Low-Temperature Cu-Cu Bonding Using Silver Nanoparticles Fabricated by Physical Vapor Deposition

    Science.gov (United States)

    Wu, Zijian; Cai, Jian; Wang, Junqiang; Geng, Zhiting; Wang, Qian

    2018-02-01

    Silver nanoparticles (Ag NPs) fabricated by physical vapor deposition (PVD) were introduced in Cu-Cu bonding as surface modification layer. The bonding structure consisted of a Ti adhesive/barrier layer and a Cu substrate layer was fabricated on the silicon wafer. Ag NPs were deposited on the Cu surface by magnetron sputtering in a high-pressure environment and a loose structure with NPs was obtained. Shear tests were performed after bonding, and the influences of PVD pressure, bonding pressure, bonding temperature and annealing time on shear strength were assessed. Cu-Cu bonding with Ag NPs was accomplished at 200°C for 3 min under the pressure of 30 MPa without a post-annealing process, and the average bonding strength of 13.99 MPa was reached. According to cross-sectional observations, a void-free bonding interface with an Ag film thickness of around 20 nm was achieved. These results demonstrated that a reliable low-temperature short-time Cu-Cu bonding was realized by the sintering process of Ag NPs between the bonding pairs, which indicated that this bonding method could be a potential candidate for future ultra-fine pitch 3D integration.

  19. Influence of Cu Content on the Microstructure and Mechanical Properties of Cr-Cu-N Coatings

    Directory of Open Access Journals (Sweden)

    Ji Cheng Ding

    2018-01-01

    Full Text Available The Cr-Cu-N coatings with various Cu contents (0–25.18 (±0.17 at.% were deposited on Si wafer and stainless steel (SUS 304 substrates in reactive Ar+N2 gas mixture by a hybrid coating system combining pulsed DC and RF magnetron sputtering techniques. The influence of Cu content on the coating composition, microstructure, and mechanical properties was investigated. The microstructure of the coatings was significantly altered by the introduction of Cu. The deposited coatings exhibit solid solution structure with different compositions in all of the samples. Addition of Cu is intensively favored for preferred orientation growth along (200 direction by restricting in (111 direction. With increasing Cu content, the surface and cross-sectional morphology of coatings were changed from triangle cone-shaped, columnar feature to broccoli-like and compact glassy microstructure, respectively. The mechanical properties including the residual stress, nanohardness, and toughness of the coatings were explored on the basis of Cu content. The highest hardness was obtained at the Cu content of 1.49 (±0.10 at.%.

  20. Sulfur induced Cu4 tetramers on Cu(111)

    DEFF Research Database (Denmark)

    Foss, M.; Feidenhans'l, R.; Nielsen, M.

    1997-01-01

    The structures of the Cu(111) and the Cu(111)(root 7 x root 7)R19.1 degrees-S reconstructions have been studied by surface X-ray diffraction and two new structural models are proposed. Although the unit cells for the two structures are quite different, a high degree of similarity has been reveale...

  1. Plant Proteinase Inhibitor BbCI Modulates Lung Inflammatory Responses and Mechanic and Remodeling Alterations Induced by Elastase in Mice

    OpenAIRE

    Almeida-Reis, Rafael; Theodoro-Junior, Osmar A.; Oliveira, Bruno T. M.; Oliva, Leandro V.; Toledo-Arruda, Alessandra C.; Bonturi, Camila R.; Brito, Marlon V.; Lopes, Fernanda D. T. Q. S.; Prado, Carla M.; Florencio, Ariana C.; Martins, Mílton A.; Owen, Caroline A.; Leick, Edna A.; Oliva, Maria L. V.; Tibério, Iolanda F. L. C.

    2017-01-01

    Background. Proteinases play a key role in emphysema. Bauhinia bauhinioides cruzipain inhibitor (BbCI) is a serine-cysteine proteinase inhibitor. We evaluated BbCI treatment in elastase-induced pulmonary alterations. Methods.??C57BL/6 mice received intratracheal elastase (ELA group) or saline (SAL group). One group of mice was treated with BbCI (days 1, 15, and 21 after elastase instillation, ELABC group). Controls received saline and BbCI (SALBC group). After 28 days, we evaluated respirator...

  2. Approaching the limit of Cu(II)/Cu(I) mixed valency in a Cu(I)Br2-N-methylquinoxalinium hybrid compound.

    Science.gov (United States)

    Leblanc, Nicolas; Sproules, Stephen; Pasquier, Claude; Auban-Senzier, Pascale; Raffy, Helene; Powell, Annie K

    2015-08-18

    A novel 1D hybrid salt (MQ)[CuBr2]∞ (MQ = N-methylquinoxalinium) is reported. Structural, spectroscopic and magnetic investigations reveal a minimal Cu(II) doping of less than 0.1%. However it is not possible to distinguish Cu(I) and Cu(II). The unusually close packing of the organic moieties and the dark brown colour of the crystals suggest a defect electronic structure.

  3. Carbon Supported Oxide-Rich Pd-Cu Bimetallic Electrocatalysts for Ethanol Electrooxidation in Alkaline Media Enhanced by Cu/CuOx

    Directory of Open Access Journals (Sweden)

    Zengfeng Guo

    2016-04-01

    Full Text Available Different proportions of oxide-rich PdCu/C nanoparticle catalysts were prepared by the NaBH4 reduction method, and their compositions were tuned by the molar ratios of the metal precursors. Among them, oxide-rich Pd0.9Cu0.1/C (Pd:Cu = 9:1, metal atomic ratio exhibits the highest electrocatalytic activity for ethanol oxidation reaction (EOR in alkaline media. X-ray photoelectron spectroscopy (XPS and high resolution transmission electron microscopy (HRTEM confirmed the existence of both Cu and CuOx in the as-prepared Pd0.9Cu0.1/C. About 74% of the Cu atoms are in their oxide form (CuO or Cu2O. Besides the synergistic effect of Cu, CuOx existed in the Pd-Cu bimetallic nanoparticles works as a promoter for the EOR. The decreased Pd 3d electron density disclosed by XPS is ascribed to the formation of CuOx and the spill-over of oxygen-containing species from CuOx to Pd. The low Pd 3d electron density will decrease the adsorption of CH3COads intermediates. As a result, the electrocatalytic activity is enhanced. The onset potential of oxide-rich Pd0.9Cu0.1/C is negative shifted 150 mV compared to Pd/C. The oxide-rich Pd0.9Cu0.1/C also exhibited high stability, which indicated that it is a candidate for the anode of direct ethanol fuel cells (DEFCs.

  4. Measurements of the electric field gradient at cadmium in YBa2Cu3Ox, Y2BaCuO5 and Y2Cu2O5

    International Nuclear Information System (INIS)

    Saitovitch, H.; Silva, P.R.J.

    1990-01-01

    The electric Field Gradient (EFG) at diluted Cd sup(111) in YBa sub(2)Cu sub(3)O sub(x) was measured by Angular Correlation (AC). In order to determine the atom-probe localization, AC measurements were also, performed on Y sub(2)BaCuO sub(5). A nuclear electric quadrupole interaction frequency (NQIF) was associated with Cd sup(111) in YBa sub(2)Cu sub(3) O sub(x) Cu(1) site. (author)

  5. A comunicação nas ciências da linguagem

    Directory of Open Access Journals (Sweden)

    Geraldo Carlos do Nascimento

    2002-06-01

    Full Text Available Este trabalho situa a questão da comunicação na sua vertente relacionada com as ciências da linguagem, que ganham corpo, embora suas origens remontem a Saussure, a partir do ensaio de Roman Jakobson, Linguistic and Poetics (1960, no qual é apresentado um esquema básico da comunicação. As fragilidades deste esquema, ainda vinculado às noções da sociologia funcionalista (Laswell/Scharam, logo se fizeram notar, particularmente no que se refere à sua operacionalização; mas foi a partir de sua crítica, conforme se defende aqui, que a semiótica greimasiana pôde, ao articular comunicação e sentido, estabelecer bases mais consistentes para a discussão da noção de comunicação e se seu campo presumível.

  6. Photocatalytic Membrane Reactor for the Removal of C.I. Disperse Red 73

    Directory of Open Access Journals (Sweden)

    Valentina Buscio

    2015-06-01

    Full Text Available After the dyeing process, part of the dyes used to color textile materials are not fixed into the substrate and are discharged into wastewater as residual dyes. In this study, a heterogeneous photocatalytic process combined with microfiltration has been investigated for the removal of C.I. Disperse Red 73 from synthetic textile effluents. The titanium dioxide (TiO2 Aeroxide P25 was selected as photocatalyst. The photocatalytic treatment achieved between 60% and 90% of dye degradation and up to 98% chemical oxygen demand (COD removal. The influence of different parameters on photocatalytic degradation was studied: pH, initial photocatalyst loading, and dye concentration. The best conditions for dye degradation were pH 4, an initial dye concentration of 50 mg·L−1, and a TiO2 loading of 2 g·L−1. The photocatalytic membrane treatment provided a high quality permeate, which can be reused.

  7. Improvement of Waste Tire Pyrolysis Oil and Performance Test with Diesel in CI Engine

    Directory of Open Access Journals (Sweden)

    M. N. Islam

    2016-01-01

    Full Text Available The standard of living, quality of life, and development of a nation depend on its per capita energy consumption. Global energy supply that mainly depends on fossil fuel is decreasing day by day. It is estimated that the energy demand will be increased five times by the year 2021 from present scenario. Due to the fossil fuel crisis, the development of alternative fuel technologies has drawn more attraction to deliver the replacement of fossil fuel. Pyrolysis is one of the promising alternative fuel technologies which produces valuable oil, char, and gas product from organic waste. Early investigations report that tire pyrolysis oil extracted from vacuum pyrolysis method seemed to have properties similar to diesel fuel. The main concern of this paper is to produce and improve the properties of crude tire pyrolysis oil by desulfurizing, distilling, and utilizing it with diesel in CI engine to analyze the efficiency for various compositions.

  8. Fluctuations of Wigner-type random matrices associated with symmetric spaces of class DIII and CI

    Science.gov (United States)

    Stolz, Michael

    2018-02-01

    Wigner-type randomizations of the tangent spaces of classical symmetric spaces can be thought of as ordinary Wigner matrices on which additional symmetries have been imposed. In particular, they fall within the scope of a framework, due to Schenker and Schulz-Baldes, for the study of fluctuations of Wigner matrices with additional dependencies among their entries. In this contribution, we complement the results of these authors by explicit calculations of the asymptotic covariances for symmetry classes DIII and CI and thus obtain explicit CLTs for these classes. On the technical level, the present work is an exercise in controlling the cumulative effect of systematically occurring sign factors in an involved sum of products by setting up a suitable combinatorial model for the summands. This aspect may be of independent interest. Research supported by Deutsche Forschungsgemeinschaft (DFG) via SFB 878.

  9. Uwarunkowania rozwoju przedsiębiorczości na przykładzie miasta Szczecin

    OpenAIRE

    Klóska, Rafał

    2005-01-01

    W artykule sprecyzowano czynniki determinujące powstawanie przedsiębiorstw w Szczecinie i scharakteryzowano wybrane działania władz lokalnych na rzecz rozwoju przedsiębiorczości w mieście. Liczba ponad 60 tys. przedsiębiorstw prowadzących działalność gospodarczą w Szczecinie wydaje się być wystarczająca dla tej aglomeracji. Dalsze zakładanie i funkcjonowanie mikro i małych przedsiębiorstw zależy nie tylko od szans i zagrożeń stwarzanych przez rynek, lecz także od pomocy i wsparcia udzielanego...

  10. Miguel de Unamuno. Pomiędzy fikcją a rzeczywistością

    Directory of Open Access Journals (Sweden)

    Agnieszka Kłosińska-Nachin

    2007-11-01

    Full Text Available The article Miguel de Unamuno. Pomiędzy fikcją a rzeczywistością (Miguel de Unamuno. Between fiction and reality is an author's metalepsy analysis, a phenomenon described by Gerard Cenette (Mśtalepse. De la figurę k la fiction, 2004, in three texts by Miguel de Unamuno: Vida de Don Quijote y Sancho (1905, Niebla (1914 and Cómo se hace una novela (1927. Author's metalepsy, defined as transgression of the limits of fiction by an author, existentional metalepsy (understood as a vision of the world based on doubt, concerning the status of reality and reader's metalepsy (if he’s forced to transgression of the limits of fiction are the inseparable parts of Unamuno's writing.

  11. Mensurações em ciência Measurements in science

    Directory of Open Access Journals (Sweden)

    Harley Edson Amaral Bicas

    2003-08-01

    Full Text Available A natureza da mensuração, terminologias e importância de seus usos em ciência são comentados quanto a sistemas numéricos, representações logarítmicas, unidades (com aplicações a medidas do índice de refração, acuidade visual e ângulos, ordens de grandeza, escalas, sensibilidades, leituras e interpolações, algarismos significativos, precisão e exatidão, fidedignidade e significância (clínica e estatística.The nature of mensurations, terminologies and the importance of their uses are commented regarding numerical systems, logarithmic representations, units (with applications to measurements of the index of refraction, visual acuity and angles, orders of magnitude, scales, sensitivity, instrumental readings and interpolations, significant digits, precision and accuracy, reliability and significance (clinical and statistical.

  12. Near-infrared chemical imaging (NIR-CI) of 3D printed pharmaceuticals

    DEFF Research Database (Denmark)

    Khorasani, Milad; Edinger, Magnus; Raijada, Dharaben Kaushikkumar

    2016-01-01

    Hot-melt extrusion and 3D printing are enabling manufacturing approaches for patient-centred medicinal products. Hot-melt extrusion is a flexible and continuously operating technique which is a crucial part of a typical processing cycle of printed medicines. In this work we use hot-melt extrusion...... for manufacturing of medicinal films containing indomethacin (IND) and polycaprolactone (PCL), extruded strands with nitrofurantoin monohydrate (NFMH) and poly (ethylene oxide) (PEO), and feedstocks for 3D printed dosage forms with nitrofurantoin anhydrate (NFAH), hydroxyapatite (HA) and poly (lactic acid) (PLA......). These feedstocks were printed into a prototype solid dosage form using a desktop 3D printer. These model formulations were characterized using near-infrared chemical imaging (NIR-CI) and, more specifically, the image analytical data were analysed using multivariate curve resolution-alternating least squares (MCR...

  13. Uma abordagem sociológica da sociologia: a ciência como campo

    Directory of Open Access Journals (Sweden)

    Vívian Matias dos Santos

    2012-03-01

    Full Text Available O presente ensaio objetiva analisar como o conceito de campo de Pierre Bourdieu pode contribuir para uma abordagem sociológica da Sociologia. A discussão desdobra-se desde a reflexão mais geral de como se firma a ciência até as possibilidades de compreensão da Sociologia neste espaço. Para tanto, fez-se necessário abordar o “campo científico” por meio das relações entre sua estrutura e seus agentes - relações “multidimensionais” que podem representar uma exitosa tentativa de superação da dicotomia ação/estrutura; indivíduo/sociedade; micro e macroteorização.

  14. Kinetic-energy matrix elements for atomic Hylleraas-CI wave functions

    Energy Technology Data Exchange (ETDEWEB)

    Harris, Frank E., E-mail: harris@qtp.ufl.edu [Department of Physics, University of Utah, Salt Lake City, Utah 84112, USA and Quantum Theory Project, University of Florida, P.O. Box 118435, Gainesville, Florida 32611 (United States)

    2016-05-28

    Hylleraas-CI is a superposition-of-configurations method in which each configuration is constructed from a Slater-type orbital (STO) product to which is appended (linearly) at most one interelectron distance r{sub ij}. Computations of the kinetic energy for atoms by this method have been difficult due to the lack of formulas expressing these matrix elements for general angular momentum in terms of overlap and potential-energy integrals. It is shown here that a strategic application of angular-momentum theory, including the use of vector spherical harmonics, enables the reduction of all atomic kinetic-energy integrals to overlap and potential-energy matrix elements. The new formulas are validated by showing that they yield correct results for a large number of integrals published by other investigators.

  15. Udvikling af dialogisk kompetence hos børn med CI

    DEFF Research Database (Denmark)

    Dammeyer, Jesper Herup; Carstensen, Susanne; Karlshøj, Bente

    2011-01-01

    Der er relativ god viden om børn med CI’s sproglige udvikling, hvad angår sproglyde og ord. Derimod er der i den internationale forskning kun beskrevet meget lidt om den del af den sproglige udvikling, som ligger ud over sætningsniveauet. Denne artikel beskriver nogle af de resultater, der er...... fremkommet ved et fire år langt følgestudie af tre førskolebørn med CI. Børnenes sproglige udvikling er observeret og analyseret i forhold til dialogiske kompetencer. Resultaterne peger på, at børnene udvikler gode talesproglige kompetencer i løbet af den fireårige periode, men at børnene har brug for støtte...

  16. WERYFIKACJA MOŻLIWOŚCI ZASTOSOWANIA WSKAŹNIKA ITS DO OCENY STANU TROFICZNEGO ZBIORNIKA DOBCZYCKIEGO

    Directory of Open Access Journals (Sweden)

    Elena NEVEROVA-DZIOPAK

    2016-05-01

    Full Text Available W ostatnich latach problem eutrofizacji stał się powszechny nie tylko w wodach stojących ale także w płynących. Budzi on spore zainteresowanie zwłaszcza gdy zaczyna dotyczyć wód przeznaczonych do zaopatrzenia ludzi w wodę do spożycia. Zbiornik Dobczycki o którym traktuje artykuł jest właśnie takim rezerwuarem. Tu ujmowana jest woda dla mieszkańców Krakowa. W literaturze spotyka się stwierdzenia, że wody zbiornika zawsze były podatne na eutrofizację ze względu na ładunki biogenów które są wnoszone do niego przez Rabę. Problem oceny stopnia eutrofizacji Zbiornika Dobczyckiego został więc podjęty nie tyle ze względów poznawczych, co utylitarnych. Wymagał rzetelnej i szczegółowej analizy danych pomiarowych pochodzących z monitoringu. Do oceny zjawiska eutrofizacji wykorzystano integralny wskaźnik troficzności ITS. Jest on jednym z coraz powszechniej stosowanych obecnie zagregowanych wskaźników. Dostrzeżono że graniczne wartości pojedynczych parametrów niekoniecznie odzwierciedlają stan trofii i uprawniają do wnioskowania o zjawisku eutrofizacji. Zastosowanie wskaźnika ITS wiąże się z wykorzystaniem parametrów takich jak pH i nasycenie wody tlenem, które odzwierciedlają bilans gazowy w wodach, zmieniający się wraz ze zmianą bilansu procesów produkcji i rozkładu materii organicznej. Nie wymaga on więc szczegółowych oznaczeń monitoringowych, przez co może być wykorzystywany jako uniwersalny sposób oceny trofii. W artykule uzasadniono wybór wskaźnika ITS jako metody oceny trofii na podstawie analizy statystycznej danych monitoringu Zbiornika pochodzących z okresu wieloletniego. Uwiarygodniło to ocenę i pozwoliło dostrzec pewne prawidłowości procesu oraz jego dynamikę. Na jej podstawie możliwa jest prognoza prawdopodobnego scenariusza dalszego rozwoju zjawiska. Utrzymujący się w minionych 15 latach stan pograniczny zaawansowanej mezotrofii/eutrofii przy jednoczesnej dobrej

  17. Partnerstwo publiczno – prywatne w świetle Krajowego Standardu Rachunkowości nr 10

    Directory of Open Access Journals (Sweden)

    Dorota Adamek-Hyska

    2017-09-01

    Full Text Available Partnerstwo publiczno – prywatne w świetle Krajowego Standardu Rachunkowości nr 10 In Poland, the concept of public-private partnership generates many dilemmas in valuation, accounting records and the reporting of essential assets and liabilities. This issue is addressed by National Accounting Standard No. 10, which outlines the principles of PPP accounting in public and private accounting systems. The purpose of this paper is to analyze and evaluate the solutions adopted in National Accounting Standard No. 10 against the background of synthetic PPP characteristics. The research methods used are based on a critical analysis of national legislation, a comparative analysis of national and international accounting standards, and a literature analysis of public-private partnerships, public finances and financial accounting. The paper uses the conclusions from the observations of financial aspects of selected public-private partnership contracts as well as concession contracts for construction works and services in Poland

  18. Globalização: novo paradigma das ciências sociais

    OpenAIRE

    Ianni,Octavio

    1994-01-01

    As ciências sociais estão sendo desafiadas a pensar a globalização do mundo. No fim do século XX, quando se anuncia o XXI, elas se defrontam com os dilemas que se abrem com a globalização das coisas, gentes e idéias. Há processos e estruturas sociais, econômicos, políticos, culturais e outros que apenas começam a ser estudados. Além do que é local, nacional e regional, colocam-se problemas novos e fundamentais com a emergência da sociedade global. As fronteiras geográficas e históricas, cultu...

  19. Preparation of Uniform Hexapod Cu{sub 2}O and Hollow Hexapod CuO

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Youngsik; Huh, Youngduk [Dankook Univ., Yongin (Korea, Republic of)

    2013-10-15

    The filled hexapod Cu{sub 2}O precursors were also prepared under microwave irradiation for only 120 s using a commercial microwave oven. The optimal experimental conditions for the perfect and uniform hexapod-like Cu{sub 2}O precursors were examined. The control of the cooling rate by adding cold water was also examined for the elimination of further crystal growth at the end of the arm of the hexapod Cu{sub 2}O precursors due to the thermal diffusion in reaction medium. The uniform hollow structure and hexapod CuO products were also prepared from the direct thermal oxidation of the filled hexapod Cu{sub 2}O precursors. The morphology-dependent properties of inorganic materials, such as magnetic, photocatalytic, and antibacterial activities, is one of the most important experimental issues in inorganic technology. Many researchers have prepared uniform and specific shaped inorganic oxides to understand the morphology-dependent properties of inorganic oxides.

  20. Moisture barrier properties of single-layer graphene deposited on Cu films for Cu metallization

    Science.gov (United States)

    Gomasang, Ploybussara; Abe, Takumi; Kawahara, Kenji; Wasai, Yoko; Nabatova-Gabain, Nataliya; Thanh Cuong, Nguyen; Ago, Hiroki; Okada, Susumu; Ueno, Kazuyoshi

    2018-04-01

    The moisture barrier properties of large-grain single-layer graphene (SLG) deposited on a Cu(111)/sapphire substrate are demonstrated by comparing with the bare Cu(111) surface under an accelerated degradation test (ADT) at 85 °C and 85% relative humidity (RH) for various durations. The change in surface color and the formation of Cu oxide are investigated by optical microscopy (OM) and X-ray photoelectron spectroscopy (XPS), respectively. First-principle simulation is performed to understand the mechanisms underlying the barrier properties of SLG against O diffusion. The correlation between Cu oxide thickness and SLG quality are also analyzed by spectroscopic ellipsometry (SE) measured on a non-uniform SLG film. SLG with large grains shows high performance in preventing the Cu oxidation due to moisture during ADT.

  1. Spectroscopic study of the CuO chains in YBa2Cu3O7-x

    International Nuclear Information System (INIS)

    Edwards, H.; Derro, D.J.; Barr, A.L.; Markert, J.T.; de Lozanne, A.L.

    1996-01-01

    We interpret our previously published results obtained using a technique called current-imaging tunneling spectroscopy (CITS) to study the detailed electronic structure of the CuO chains in the high-temperature superconductor YBa 2 Cu 3 O 7-x near the Fermi level. Our CITS data comprise sequences of 32 simultaneously obtained images taken at bias voltages ranging from -78 to 72 mV. Cross sections of the CITS data, normalized-conductance analysis, and logarithmic-derivative analysis allow us to examine in detail the behavior of electronic modulations along the CuO chains and the energy gap in the CuO chains of YBa 2 Cu 3 O 7-x . This new analysis lends a strong foundation to our previous interpretation of the CITS data [H. L. Edwards et al., Phys. Rev. Lett. 75, 1387 (1995)]. copyright 1996 American Vacuum Society

  2. O que é Ciência da Informação?

    Directory of Open Access Journals (Sweden)

    Carlos Alberto Ávila Araújo

    2014-12-01

    Full Text Available Introdução: Apresenta um panorama da Ciência da Informação em três momentos. Inicialmente, seu surgimento e consolidação na década de 1960, como confluência de vários fatos: a distinção em relação à Arquivologia, à Biblioteconomia e à Museologia; a relação com a Documentação; a ocupação do espaço institucional da Biblioteconomia; as atividades dos primeiros “cientistas da informação”; as tecnologias da informação; e o uso da Teoria Matemática. Objetivo: Analisar a ampliação vivida nas décadas seguintes com o desenvolvimento de subáreas, das caracterizações do campo e da evolução do conceito de informação. Metodologia: Revisão de Literatura. Resultados: São apresentadas as tendências contemporâneas: as sistematizações da área, os três modelos para o estudo da informação e o desafio recente de diálogo com a Arquivologia, a Biblioteconomia e a Museologia. Conclusões: muitos processos e eventos aconteceram no campo da Ciência da Informação nestes últimos 45 anos. Diferentes subáreas foram formadas, conceitos formulados e reformulados, caracterizações problematizadas e discutidas, relações com outros campos de conhecimento tensionadas e concretizadas.

  3. Polska prasa tabletowa – modele biznesowe dystrybucji treści

    Directory of Open Access Journals (Sweden)

    Krzysztof Flasiński

    2012-02-01

    Full Text Available Autor przeanalizował aplikacje spełniające trzy warunki: przeznaczone na tablety marki iPad, dostępne w sklepie App Store oraz powiązane z polskojęzycznymi tytułami prasowymi. Artykuł przedstawia kompletną panoramę polskiej prasy tabletowej. Ujętych zostało 38 aplikacji dostępnych 30 września 2011 r. Po zbadaniu wszystkich programów utworzono „mapę modeli biznesowych dystrybucji treści”. Czynnikiem decydującym o umieszczeniu na niej aplikacji prasowych była forma dystrybucji treści (płatna/bezpłatna oraz  rodzaj udostępnianej treści (powiązana z wydaniem drukowanym/powiązana z wydaniem online. Z analizy wynika, że 11 redakcji udostępnia płatne wydanie print, 10 – bezpłatne wydanie online, 7 – bezpłatne wydanie print, 3 – bezpłatne wydanie online oraz płatne wydanie print, jedna – oba wydania bezpłatnie, i jedna – oba wydania płatnie. Wywód uzupełniają dodatkowe dane: chronologiczna lista aplikacji prasowych według daty ukazania, wykaz kosztów korzystania z poszczególnych aplikacji, aktywność wydawców prasowych w App Store w rozbiciu na miesiące oraz kwartały.

  4. Trudności we wprowadzaniu reformy gimnazjalnej na obszarach wiejskich

    Directory of Open Access Journals (Sweden)

    Aneta Sobotka

    2016-09-01

    Full Text Available Wprowadzone w 1999 r. gimnazja miały służyć wyrównywaniu szans edukacyjnych dzieci z terenów wiejskich. Jednym z założeń reformy było stworzenie dużych, samodzielnych i dobrze wyposażonych gimnazjów, w których wspólnie uczyliby się absolwenci wszystkich szkół podstawowych z terenu gminy. Po kilkunastu latach funkcjonowania gimnazja pod względem organizacyjnym bardzo się zróżnicowały – w niektórych gminach, zgodnie z założeniami reformatorów, ciągle funkcjonują duże i samodzielne gimnazja, jednak w części gmin bardzo małe gimnazja działają w zespole ze szkołą podstawową, gdzie uczniowie przez dziewięć lat nie zmieniają kolegów, nauczycieli i środowiska. Na podstawie ośmiu studiów przypadku gmin wiejskich pokazano w artykule proces kształtowania sieci gimnazjów w pierwszych latach reformy systemu szkolnego. Próbowano zrozumieć, jakie czynniki zadecydowały o wytworzeniu się tych dwóch modeli gimnazjum. Przedstawione studia przypadku pokazują, że sieć szkolna jest nie tyle wynikiem realizacji planów tworzenia sieci szkolnej przez władze lokalne, ile raczej wynikiem gry pomiędzy lokalnymi władzami a lokalnymi społecznościami.

  5. The functional significance of cortical reorganization and the parallel development of CI therapy

    Directory of Open Access Journals (Sweden)

    Edward eTaub

    2014-06-01

    Full Text Available For the 19th and the better part of the 20th centuries two correlative beliefs were strongly held by almost all neuroscientists and practitioners in the field of neurorehabilitation. The first was that after maturity the adult CNS was hardwired and fixed, and second that in the chronic phase after CNS injury no substantial recovery of function could take place no matter what intervention was employed. However, in the last part of the 20th century evidence began to accumulate that neither belief was correct. First, in the 1960s and 1970s, in research with primates given a surgical abolition of somatic sensation from a single forelimb, which rendered the extremity useless, it was found that behavioral techniques could convert the limb into an extremity that could be used extensively. Beginning in the late 1980s, the techniques employed with deafferented monkeys were translated into a rehabilitation treatment, termed Constraint Induced Movement therapy or CI therapy, for substantially improving the motor deficit of the upper and lower extremities in the chronic phase after stroke. CI therapy has been applied successfully to other types of damage to the CNS such as traumatic brain injury, cerebral palsy, multiple sclerosis, and spinal cord injury, and it has also been used to improve function in focal hand dystonia and for aphasia after stroke. As this work was proceeding, it was being shown during the 1980s and 1990s that sustained modulation of afferent input could alter the structure of the CNS and that this topographic reorganization could have relevance to the function of the individual. The alteration in these once fundamental beliefs has given rise to important recent developments in neuroscience and neurorehabilitation and holds promise for further increasing our understanding of CNS function and extending the boundaries of what is possible in neurorehabilitation.

  6. A Science Centre as a Geoturism promoter - the Lagos Ciência Viva examples (Portugal).

    Science.gov (United States)

    Azevedo Rodrigues, Luis; Leote, Catarina

    2017-04-01

    Science outreach and engagement are crucial core objectives of the Lagos Ciência Viva Science Centre (CCVL). By engaging audiences in the real world a link is made between their science centre experience and the environment in which they live. Therefore, it has been an option of the CCVL to offer geological outdoor activities, both in the natural environment and urban context. Dinosaurs are an appealing science subject for both students and tourists. Thus, the CCVL has a long tradition in organizing and guiding field trips to two dinosaur track sites - Salema and Santa beaches (Vila do Bispo, southwest Algarve). These sites, both from the Lower Cretaceous reveal at least two types of tracks - theropod and iguanodontian footprints. Often in combination with the paleontology field trips, the CCVL also offers different geological field trips both for formal (school) and informal (tourism) education. This allows students and tourists to be introduced to dinosaur paleobiology and ichnology and to the structural geology and stratigraphy of the area. Our science outreach is being further developed by contractual agreement with a regional tour operator, in which the CCVL is responsible for the scientific content and guidance of the visits. Aiming at an urban context, the CCVL produced three Urban Geology and Paleontology Guide Books for three Algarve cities (Lagos, Faro and Tavira), which can be acquired in the three Ciência Viva Science Centres shops as well as in the tourist information offices serving this way as a basis for guided urban tours also offered by the CCVL. Based on our experience, we review and contextualise these geoscience activities and their potential for science outreach, communication and tourism. We discuss and propose a classification of different possibilities in geoscience communication and outreach based on three vertices: Science, Heritage and Geotourism. Some particularities of these visits, such as the merge between geosciences and other

  7. Electronic structure of the Y Ba2 Cu3 O7-x high temperature superconductor ceramic

    International Nuclear Information System (INIS)

    Lima, G.A.R.

    1990-01-01

    We investigate the electronic structure of superconductor Y Ba 2 Cu 3 O 7-x through a molecular cluster approach. The calculations are performed self consistently through a semi empirical L.C.A.O. technique, where different charge states are considered. The correlation effects are taken into account by configuration interaction procedure (INDO/CI). The results for the larger cluster yield a density of states showing a strong p-d covalency resulting in a width of around 8,0 eV for the valence band. The optical excitations is analyzed in detail and compared with the experimental data. (author)

  8. Corrosion behavior of Cu during graphene growth by CVD

    International Nuclear Information System (INIS)

    Dong, Yuhua; Liu, Qingqing; Zhou, Qiong

    2014-01-01

    Highlights: • Graphene films were deposited on the Cu by chemical vapor deposition method. • Annealing affects the corrosion property of Cu. • Graphene films improve corrosion performance of Cu for a short period of time. - Abstract: The corrosion performance of Cu samples may be affected by annealing at high temperatures during graphene growth via the chemical vapor deposition method. In this study, multiple graphene films were deposited on Cu and characterized by Raman spectroscopy and transmission electron microscopy. The corrosion behavior of Cu immersed in 3.5 wt.% NaCl solution was investigated using electrochemical impedance spectroscopy. The Cu morphology was observed by optical microscopy and scanning electron microscopy. Results indicated that annealing affects the corrosion process of Cu. The presence of graphene films on the Cu substrate improved the corrosion performance of the material for a short period of time

  9. Decomposition of NO on Cu-loaded zeolites

    Energy Technology Data Exchange (ETDEWEB)

    Sepulveda-Escribano, A; Marquez-Alvarez, C; Rodriquez-Ramos, I; Fierro, J L.G. [Instituto de Catalisis y Petroleoquimica, Madrid (Spain); Guerrero-Ruiz, A [Departamento de Quimica Inorganica, UNED, Madrid (Spain)

    1993-05-26

    Two copper ion-exchanged zeolites, Cu/NaY and Cu/NaZSM-5 have been studied by several techniques (TPR, TPD of NO, IR spectroscopy of adsorbed NO and XPS) and their catalytic activity for NO-decomposition have been determined under dynamic conditions. The results obtained here show that copper is stabilized as Cu[sup +] in Cu/NaZSM-5 after calcination in air at 673K, while in Cu/NaY the initial Cu[sup +]-ions are easier oxidized to Cu[sup 2+], this leading to a completely different catalytic behavior in the reaction of NO-decomposition. So, whereas the Cu/NaZSM-5 exhibits a high NO-conversion at the reaction temperatures (573 and 873K), the parent Cu/NaY zeolite becomes deactivated in the first stages of reaction.

  10. Effects of CuO nanoparticles on Lemna minor.

    Science.gov (United States)

    Song, Guanling; Hou, Wenhua; Gao, Yuan; Wang, Yan; Lin, Lin; Zhang, Zhiwei; Niu, Qiang; Ma, Rulin; Mu, Lati; Wang, Haixia

    2016-12-01

    Copper dioxide nanoparticles (NPs), which is a kind of important and widely used metal oxide NP, eventually reaches a water body through wastewater and urban runoff. Ecotoxicological studies of this kind of NPs effects on hydrophyte are very limited at present. Lemna minor was exposed to media with different concentrations of CuO NPs, bulk CuO, and two times concentration of Cu 2+ released from CuO NPs in culture media. The changes in plant growth, chlorophyll content, antioxidant defense enzyme activities [i.e., peroxidase (POD), catalase (CAT), superoxide dismutase (SOD) activities], and malondialdehyde (MDA) content were measured in the present study. The particle size of CuO NPs and the zeta potential of CuO NPs and bulk CuO in the culture media were also analyzed to complementally evaluate their toxicity on duckweed. Results showed that CuO NPs inhibited the plant growth at lower concentration than bulk CuO. L. minor roots were easily broken in CuO NPs media under the experimental condition, and the inhibition occurred only partly because CuO NPs released Cu 2+ in the culture media. The POD, SOD, and CAT activities of L. minor increased when the plants were exposed to CuO NPs, bulk CuO NPs and two times the concentration of Cu 2+ released from CuO NPs in culture media, but the increase of these enzymes were the highest in CuO NPs media among the three kinds of materials. The MDA content was significantly increased compared with that of the control from 50 mg L -1 CuO NP concentration in culture media. CuO NPs has more toxicity on L. minor compared with that of bulk CuO, and the inhibition occurred only partly because released Cu 2+ in the culture media. The plant accumulated more reactive oxygen species in the CuO NP media than in the same concentration of bulk CuO. The plant cell encountered serious damage when the CuO NP concentration reached 50 mg L -1 in culture media. The toxicology of CuO NP on hydrophytes must be considered because that hydrophytes

  11. Loss of reserves of Cu in liver when Cu supplements are withdrawn from dairy herds in the Waikato region.

    Science.gov (United States)

    Hittmann, A R; Grace, N D; Knowles, S O

    2012-03-01

    To monitor the consequences of withdrawing mineral Cu supplements from two dairy herds with initially high concentrations of Cu in liver. Two herds were selected from dairy farms in the Waikato region of New Zealand that participated in an earlier survey of Cu supplementation practices and Cu status of dairy cows. The herds were fed pasture, grass and maize silage, plus palm kernel expeller (PKE) containing 25-30 mg Cu/kg dry matter (DM) fed at 2-4 kg/cow/day. No mineral Cu supplements were supplied from January 2009. Pasture samples were collected for mineral analysis in September 2008 and April 2009. Concentration of Cu in liver biopsies from the same 9-10 cows per herd was measured on three occasions between April 2009 and May 2010. Pastures on both farms contained 10 mg Cu/kg DM, 0.1-0.5 mg Mo/kg DM and 3.5-4.0 g S/kg DM. The initial herd mean concentrations of Cu in liver were 1,500 (SD 590) and 1,250 (SD 640) μmol Cu/kg fresh tissue. In the absence of mineral Cu supplements, those mean concentrations decreased over 12 months to 705 (SD 370) and 1,120 (SD 560) μmol Cu/kg fresh tissue, respectively. For cows in the first herd, the rate of depletion of liver Cu reserves was influenced by initial concentration of Cu, such that high concentration led to faster loss according to first-order kinetics. Mineral Cu supplementation was not necessary over 12 months for two dairy herds with mean concentrations of Cu in liver >1,250 μmol Cu/kg fresh tissue, grazing pastures containing 10 mg Cu/kg DM and concentrations of Mo <1 mg/kg DM. The quantity and particularly the duration of feeding PKE appeared to be a factor in whether or not the herd lost substantial reserves of Cu in liver during the year. However, the Cu status of both herds in this study was more than adequate to support late pregnancy and mating. CLINICAL REVELANCE: Copper status of the herd should be monitored and on-farm management of Cu nutrition should take into account all sources contributing to

  12. Novel CuCr_2O_4 embedded CuO nanocomposites for efficient photodegradation of organic dyes

    International Nuclear Information System (INIS)

    Mageshwari, K.; Sathyamoorthy, R.; Lee, Jeong Yong; Park, Jinsub

    2015-01-01

    Graphical abstract: - Highlights: • Novel CuO–CuCr_2O_4 nanocomposites synthesized by reflux condensation method. • Methyl orange and methylene blue dye degradation studied under UV light irradiation. • Nanocomposites characterized by XRD, FESEM, TEM, EDX, UV–vis DRS and PL. • CuCr_2O_4 loading effectively enhanced the catalytic activity of CuO. - Abstract: Novel photocatalyst based on CuO–CuCr_2O_4 nanocomposites was synthesized for different Cr"3"+ concentration by reflux condensation method, and their photocatalytic activity was evaluated by monitoring the photodegradation of methyl orange (MO) and methylene blue dyes (MB) under UV light irradiation. Phase evolution by X-ray diffraction showed monoclinic CuO and tetragonal CuCr_2O_4 as the components of the prepared nanocomposites. Morphological analysis by scanning electron microscope and transmission electron microscope revealed that the incorporation of Cr"3"+ in CuO lattice alters the morphology of CuO from microsphere to cluster shape. Photoluminescence spectra of CuO–CuCr_2O_4 nanocomposites exhibited reduced PL emissions compared to pure CuO, indicating the low recombination rate of photogenerated electrons and holes. As expected, the CuCr_2O_4 loaded CuO showed enhanced photocatalytic activity for MO and MB dyes, and the kinetic studies suggest that the degradation follows pseudo-first-order kinetics. The enhanced photocatalytic activity of CuO–CuCr_2O_4 nanocomposites can be attributed to the presence of CuCr_2O_4 as an electron acceptor, which improves the effective charge separation in CuO.

  13. Sprawozdawczość zintegrowana jako nowy obszar badań naukowych w rachunkowości

    Directory of Open Access Journals (Sweden)

    Joanna Krasodomska

    2015-06-01

    Full Text Available Celem artykułu jest przedstawienie sprawozdawczości zintegrowanej jako interesującego, nowego obszaru badań naukowych w rachunkowości. Zakłada ona publikację raportu prezentującego, jak przyjęte przez przedsiębiorstwo strategia, zasady zarządzania, wyniki działalności i perspektywy rozwoju prowadzą do tworzenia wartości. W artykule omówiono stanowiące podstawę sprawozdawczości zintegrowanej koncepcje modelu biznesu oraz sześciu kapitałów. Na podstawie dokonanego przeglądu literatury przedstawiono kierunki badań z zakresu sprawozdawczości zintegrowanej, prezentowane w artykułach naukowych indeksowanych w bazach EBSCO i Emerald oraz postulowane przez Międzynarodową Radę ds. Zintegrowanej Sprawozdawczości (International Integrated Reporting Council – IIRC we współpracy ze Stowarzyszeniem Dyplomowanych Biegłych Księgowych (Association of Chartered Certified Accountants – ACCA i Międzynarodowym Stowarzyszeniem Edukacji Rachunkowości i Badań (International Association for Accounting Education & Research – IAAER. Wskazano też tematy opracowań podejmujących ten problem, przyjętych do prezentacji na Kongresie Europejskiego Stowarzyszenia Rachunkowości (European Accounting Association – EAA w Glasgow w kwietniu 2015 r. Analizą objęto również dorobek polskich autorów podejmujących w swoich badaniach problematykę sprawozdawczości zintegrowanej. Przegląd literatury dotyczącej sprawozdawczości zintegrowanej oraz obecnie prowadzonych badań pozwolił na zidentyfikowanie luk badawczych i wskazanie problemów wartych naukowych dociekań. Zaliczono do nich m.in. zagadnienia związane z modelem biznesu, koncepcją wartości, sześcioma kapitałami, jakością i istotnością raportów zintegrowanych, zaspokajaniem przez raporty zintegrowane potrzeb informacyjnych użytkowników oraz rolą księgowych i biegłych rewidentów w opracowywaniu i weryfikacji sprawozdawczości zintegrowanej. 

  14. Cu mesh for flexible transparent conductive electrodes.

    Science.gov (United States)

    Kim, Won-Kyung; Lee, Seunghun; Hee Lee, Duck; Hee Park, In; Seong Bae, Jong; Woo Lee, Tae; Kim, Ji-Young; Hun Park, Ji; Chan Cho, Yong; Ryong Cho, Chae; Jeong, Se-Young

    2015-06-03

    Copper electrodes with a micromesh/nanomesh structure were fabricated on a polyimide substrate using UV lithography and wet etching to produce flexible transparent conducting electrodes (TCEs). Well-defined mesh electrodes were realized through the use of high-quality Cu thin films. The films were fabricated using radio-frequency (RF) sputtering with a single-crystal Cu target--a simple but innovative approach that overcame the low oxidation resistance of ordinary Cu. Hybrid Cu mesh electrodes were fabricated by adding a capping layer of either ZnO or Al-doped ZnO. The sheet resistance and the transmittance of the electrode with an Al-doped ZnO capping layer were 6.197 ohm/sq and 90.657%, respectively, and the figure of merit was 60.502 × 10(-3)/ohm, which remained relatively unchanged after thermal annealing at 200 °C and 1,000 cycles of bending. This fabrication technique enables the mass production of large-area flexible TCEs, and the stability and high performance of Cu mesh hybrid electrodes in harsh environments suggests they have strong potential for application in smart displays and solar cells.

  15. Infiltrated TiC/Cu composites

    International Nuclear Information System (INIS)

    Frage, N.; Froumin, N.; Rubinovich, L.; Dariel, M.P.

    2001-01-01

    One approach for the fabrication of ceramic-metal composites is based on the pressureless impregnation of a porous ceramic preform by a molten metal. Molten Cu does not react with TiC and the wetting angle is close to 90 o . Nonetheless, molten Cu readily impregnates partially sintered TiC preforms. A model that describes the dependence of the critical contact angle for spontaneous impregnation by molten metals in partially sintered preforms on the level of densification and on the morphology of the particles was developed. For high aspect ratios of the particles forming the preform, wetting angles close to 90 o still allow impregnation by the molten metal. The results of the model were confirmed by infiltration of partially sintered TiC preforms with molten Cu and by fabrication of the TiC/Cu composites with various ceramic-to metal ratios. Decreasing of the metal content in the composite from 50 vol.% to 10 vol.% leads to a hardness increase from 250 to 1800 HV, and to the decrease of the bending strength from 960 to 280 MPa. The resistivity of these TiC/Cu composites decreases from 142 ohm cm to 25 ohm cm. (author)

  16. Development of [⁶⁴Cu]-DOTA-PR81 radioimmunoconjugate for MUC-1 positive PET imaging.

    Science.gov (United States)

    Alirezapour, Behrouz; Rasaee, Mohammad Javad; Jalilian, Amir Reza; Rajabifar, Saeed; Mohammadnejad, Javad; Paknejad, Malihe; Maadi, Ehsan; Moradkhani, Sedigheh

    2016-01-01

    Breast cancer radioimmunoscintigraphy targeting MUC1 expression is a growing field of work in nuclear medicine research. PR81 is a monoclonal antibody that binds with high affinity to MUC1, which is over expressed on breast tumors. In this study, we report production, quality control and preclinical qualifications of a copper-64 labeled PR81 for PET imaging of breast cancer. PR81 was conjugated with DOTA-NHS-ester and purified by molecular filtration followed by chelate:mAb ratio determination by spectrophotometric method. DOTA-PR81 was labeled with (64)Cu followed by radiochemical purity, in vitro stability, in vitro internalization and immunoreactivity determination. The tissue biodistribution of the (64)Cu-DOTA-PR81 and (64)Cu-DOTA-hIgG was evaluated in BALB/c mice with breast carcinoma tumors using tissue counting and imaging. The radiochemical purity of radioimmunoconjugate was >95±1.9% (ITLC) (specific activity; 4.6 μCi/μg). The average number of chelators per antibody was 3.4±0.3:1. The (64)Cu-DOTA-PR81 showed immunoreactivity towards MUC1 antigen and MCF7 cell line with significant in vitro stability (>89% in PBS and 78±0.5% in human serum) over 48 h. Maximum internalized activity of radiolabeled PR81 in 4-8 h was 81.5%. The biodistribution and scintigraphy studies showed the accumulation of the complex at the site of tumors with high sensitivity and specificity compared to control probes. The results showed that (64)Cu-DOTA-PR81 may be considered as a potential PET tracer for diagnosis and follow-up of MUC1 expression in oncology. Copyright © 2015 Elsevier Inc. All rights reserved.

  17. High-temperature stability of Au/Pd/Cu and Au/Pd(P)/Cu surface finishes

    Science.gov (United States)

    Ho, C. E.; Hsieh, W. Z.; Lee, P. T.; Huang, Y. H.; Kuo, T. T.

    2018-03-01

    Thermal reliability of Au/Pd/Cu and Au/Pd(4-6 wt.% P)/Cu trilayers in the isothermal annealing at 180 °C were investigated by X-ray photoelectron spectroscopy (XPS), time-of-flight secondary ion mass spectrometry (TOF-SIMS), and transmission electron microscopy (TEM). The pure Pd film possessed a nanocrystalline structure with numerous grain boundaries, thereby facilitating the interdiffusion between Au and Cu. Out-diffusion of Cu through Pd and Au grain boundaries yielded a significant amount of Cu oxides (CuO and Cu2O) over the Au surface and gave rise to void formation in the Cu film. By contrast, the Pd(P) film was amorphous and served as a good diffusion barrier against Cu diffusion. The results of this study indicated that amorphous Pd(P) possessed better oxidation resistance and thermal reliability than crystalline Pd.

  18. Radiolabeling and biodistribution of 62Cu-dithiocarbamate

    International Nuclear Information System (INIS)

    Matsumoto, Kazuya; Fujibayashi, Yasuhisa; Yokoyama, Akira; Konishi, Junji.

    1990-01-01

    The newly developed 62 Zn/ 62 Cu generator system has made available the production of the short-lived 62 Cu (T 1/2 = 9.8 min) positron radionuclide, eluted as 62 Cu-glycine. In the search for 62 Cu labeled radiopharmaceuticals for positron CT (PET) brain diagnostic studies, two ligands N,N-diethyl- and N,N-dimethyl-dithiocarbamic acid (DDC and DmDC) were selected, based on their Cu chelating abilities and the neutral lipophilic character of their copper chelates. In the present work, an in vitro study with non-radioactive Cu-glycine showed that both ligands easily formed the stable, neutral Cu-DDC and Cu-DmDC chelates (1:2 metal-ligand complexes) based on the ligand exchange reaction. Then the 62 Zn/ 62 Cu generator eluate, the 62 Cu-glycine was used for the radiolabeling of DDC and DmDC. The following HPLC analysis revealed that the ligand exchange reaction proceeded rapidly; the radiochemical purities of 62 Cu-DDC and 62 Cu-DmDC were extremely high (non-detectable 62 Cu-glycine) and both chelates were more lipophilic than 62 Cu-glycine. The mouse biodistribution of both radiolabeled compounds, 62 Cu-DDC and 62 Cu-DmDC indicated a brain accumlation of 2.8 and 5.3 times higher than 62 Cu-glycine, 15 min post injection, respectively. The brain accumulation observed with both 62 Cu-DDC and 62 Cu-DmDC might be due to their stable, neutral and lipophilic character; the latter enhanced by the presence of the methylated side chains. The gathered results indicated the applicability of dithiocarbamic acid derivatives in the production of new 62 Cu-labeled compounds using the 62 Zn/ 62 Cu generator system based on the ligand exchange reaction with 62 Cu-glycine eluate. Further studies with Cu-dithiocarbamic acid derivatives for development of new generator-produced 62 Cu positron radiopharmaceuticals can be recalled. (author)

  19. The role of CI and learning in an organizational change process-Experiences from a longitudinal study of organizational change

    DEFF Research Database (Denmark)

    Kofoed, Lise; Gertsen, Frank; Jørgensen, Frances

    2002-01-01

    these situational barriers, CI, with an emphasis on imbedded learning, was introduced through an action research methodology in the context of an experimental learning lab ("experimentarium"). Contrary to prevailing theory that suggests that CI serves primarily to support and supplement existing radical changes...

  20. The interaction between dietary Fe, Cu and stress in Cu-67 retention and serum ceruloplasmin (Cp) activity in rats

    International Nuclear Information System (INIS)

    Pellett, L.; Kattelmann, K.; Zinn, K.; Trokey, D.; Forrester, I.; Gordon, D.T.

    1991-01-01

    The objectives of the study were to determine the effects of dietary Fe and stress on Cu-67 retention and serum Cp activity in the rat. A 2 x 2 x 2 factorial arrangement of treatments was utilized. Male Sprague Dawley weanling rats were fed AIN-76 diets ad lib containing 0.8 ppm Cu (CuD) or 5.7 ppm Cu (CuA) with 22.5 ppm Fe (FeA) or 280 ppm Fe (FeE). After 19 days, one-half of the animals of each treatment were stressed by an intramuscular injection of 0.1 ml turpentine/100 gm body weight. Forty-eight hours later, animals were gavaged with Cu-67 and counted over a 7 day period in a whole body high resolution gamma counter. Cu-67 retention was 20% higher in CuD rats compared to CuA rats. There were no significant effects caused by Fe or stress or the interaction between these variables on Cu-67 retention. In rats fed FeE-CuA diets, serum Cp activity was significantly depressed compared to rats fed FeA-CuA diets. These reductions in the acute phase protein Cp, were 85% and 70% in nonstressed and stressed rats, respectively. The results of this study suggest that the negative interaction effects of excess Fe on Cu utilization does not occur at the site of Cu absorption, but within the body and specifically in the liver

  1. RbCuFe(PO42

    Directory of Open Access Journals (Sweden)

    Mongi Ben Amara

    2013-08-01

    Full Text Available A new iron phosphate, rubidium copper(II iron(III bis(phosphate, RbCuFe(PO42, has been synthesized as single crystals by the flux method. This compound is isostructural with KCuFe(PO42 [Badri et al. (2011, J. Solid State Chem. 184, 937–944]. Its structure is built up from Cu2O8 units of edge-sharing CuO5 polyhedra, interconnected by FeO6 octahedra through common corners to form undulating chains that extend infinitely along the [011] and [01-1] directions. The linkage of such chains is ensured by the PO4 tetraedra and the resulting three-dimensional framework forms quasi-elliptic tunnels parallel to the [101] direction in which the Rb+ cations are located.

  2. Comets as parent bodies of CI1 carbonaceous meteorites and possible habitats of ice-microbes

    Science.gov (United States)

    Wickramasinghe, N. Chandra; Wickramasinghe, Janaki T.; Wallis, Jamie; Hoover, Richard B.; Rozanov, Alexei Y.

    2011-10-01

    Recent studies of comets and cometary dust have confirmed the presence of biologically relevant organic molecules along with clay minerals and water ice. It is also now well established by deuterium/hydrogen ratios that the CI1 carbonaceous meteorites contain indigenous extraterrestrial water. The evidence of extensive aqueous alteration of the minerals in these meteorites led to the hypothesis that water-bearing asteroids or comets represent the parent bodies of the CI1 (and perhaps CM2) carbonaceous meteorites. These meteorites have also been shown to possess a diverse array of complex organics and chiral and morphological biomarkers. Stable isotope studies by numerous independent investigators have conclusively established that the complex organics found in these meteorites are both indigenous and extraterrestrial in nature. Although the origin of these organics is still unknown, some researchers have suggested that they originated by unknown abiotic mechanisms and may have played a role in the delivery of chiral biomolecules and the origin of life on Early Earth. In this paper we review these results and investigate the thermal history of comets. We show that permanent as well as transient domains of liquid water can be maintained on a comet under a plausible set of assumptions. With each perihelion passage of a comet volatiles are preferentially released, and during millions of such passages the comet could shed crustal debris that may survive transit through the Earth's atmosphere as a carbonaceous meteorite. We review the current state of knowledge of comets and carbonaceous meteorites. We also present the results of recent studies on the long-term viability of terrestrial ice-microbiota encased in ancient glacial ice and permafrost. We suggest that the conditions which have been observed to prevail on many comets do not preclude either survivability (or even the active metabolism and growth) of many types of eukaryotic and prokaryotic microbial

  3. Life cycle impact assessment of biodiesel using the ReCiPe method

    Directory of Open Access Journals (Sweden)

    Kiss Ferenc E.

    2013-01-01

    Full Text Available This paper presents the life cycle impact assessment (LCIA results of biodiesel produced from rapeseed oil. The functional unit (FU is defined as 3750 km of distance traveled by a truck fuelled with biodiesel. The reference flow is 1000 kg of biodiesel. The LCIA method used in the study is the ReCiPe method. At midpoint level the ReCiPe method addresses environmental issues within 18 impact categories. Most of these midpoint impact categories are further converted and aggregated into 3 endpoint categories (damage to human health, damage to ecosystem diversity, damage to mineral resource availability. The total impact of biodiesel’s life cycle was estimated at 540 Pt/FU. The damage to ecosystem diversity (1.48E-04 species•year/FU, the damage to human health (7.48E-03 DALY/FU and the damage to mineral resource availability (8.11E+03 US$/FU are responsible for 63%, 27% and 10% of the total negative impact in the life cycle of biodiesel, respectively. The results have revealed that only 4 impact categories are responsible for most of the impacts within the specific endpoint categories. These are impacts associated with global warming (3000 kg CO2 ekv./FU, particulate matter formation (12.4 kg PM ekv./FU, agricultural land occupation (6710 m2a./FU and fossil fuel depletion (21168 MJ/FU. Greenhouse gases emitted in the life cycle of biodiesel (mainly N2O, CO2 are responsibly for 56% of the damage caused to human health and for 16% of the damage caused to ecosystem diversity. Airborne emissions which contribute to particulate matter formation (NOx, NH3, PM, SO2 are responsible for 43% of the damage caused to human health. Agricultural land occupation is responsible for 82% of the damage caused to the ecosystem diversity. Damage to mineral resource availability is almost entirely related to the depletion of fossil energy sources. The production chain of biodiesel and the combustion of biodiesel are responsible for 69% and 31% of the total impact of

  4. Capturing the Petermann Ice Island Flux With the CI2D3 Database

    Science.gov (United States)

    Crawford, A. J.; Crocker, G.; Mueller, D.; Saper, R.; Desjardins, L.; Carrieres, T.

    2017-12-01

    The Petermann Glacier ice tongue lost >460 km2 of areal extent ( 38 Gt of mass) due to three large calving events in 2008, 2010 and 2012, as well as three previously unrecorded events in 2011 and 2012. Hundreds of ice islands subsequently drifted south between Hall Basin and Newfoundland's Grand Banks, but no systematic data collection or analysis has been conducted for the full flux of fragments prior to the present study. To accomplish this, the Canadian Ice Service's extensive RADARSAT-1 and -2 synthetic aperture radar image archive was mined to create the Canadian Ice Island Drift, Deterioration and Detection (CI2D3) Database. Over 15000 fragments have been digitized in GIS software from 3200 SAR scenes. A unique characteristic of the database is the inclusion of the lineage (i.e., connecting repeat observations or mother-daughter fragments) for all tracked fragments with areas >0.25 km2. This genealogical information was used to isolate ice islands that were about to fracture in order to assess the environmental conditions and morphological characteristics that influence this deterioration mechanism. Fracture counts showed a significant relationship with sea ice concentration (r = -0.56). However, variations in relative thickness played a large role in fracturing likelihood regardless of sea ice conditions. The exceedance probability of the daughter fragment length was calculated, as is often conducted for offshore industry hazard assessment. Grounded ice islands, which are hazards to seafloor installations and disturb benthic ecology, were recognized from their negligible drift speeds and two grounding hot-spots were identified along the Coburg and eastern Baffin island coasts. Petermann ice islands have been noted to drift along specific isobaths due to the influence of bathymetry on ocean currents. 50% of observations occurred between the 100 and 300 m isobaths, and smaller ice islands were observed more frequently in deeper regions. The CI2D3 Database can

  5. Globalização: novo paradigma das ciências sociais

    Directory of Open Access Journals (Sweden)

    Octavio Ianni

    1994-08-01

    Full Text Available As ciências sociais estão sendo desafiadas a pensar a globalização do mundo. No fim do século XX, quando se anuncia o XXI, elas se defrontam com os dilemas que se abrem com a globalização das coisas, gentes e idéias. Há processos e estruturas sociais, econômicos, políticos, culturais e outros que apenas começam a ser estudados. Além do que é local, nacional e regional, colocam-se problemas novos e fundamentais com a emergência da sociedade global. As fronteiras geográficas e históricas, culturais e civilizatórias parecem modificar-se em direções e formas surpreendentes. Indivíduo, grupo, classe, coletividade e povo são colocados diante de outros horizontes. O próprio pensamento científico é desafiado a elaborar conceitos e interpretações para dar conta de realidades pouco conhecidas. As teorias da globalização, que começam a ser esboçadas, revelam o empenho das ciências sociais em explicar o que há de novo no que vai pelo mundo.Social sciences are now being challenged to think on the world's globalization. At the end of the twentieth century and dawn of the twenty first, they are faced with the dilemas that open up with the globalization of things, people and ideas: There are social, economical, political, cultural and other processes and structures that are just begining to be studied. Besides what is local, national and regional, new and fundamental problems appear with the rising global society. The geographic, historical, cultural and civilizatorian limits seem to change in surprising ways and directions. The individual, group, class, colectivity and people are put before other horizons. The scientific thinking itself is called upon to elaborate concepts and interpretations to account for little known realities. The globalization theories that are just being sketched show the efforts of Social Sciences to explain what is new going on in the world.

  6. Incognito ergo sum. O wytwarzaniu obojętności

    Directory of Open Access Journals (Sweden)

    Joanna Tokarska-Bakir

    2014-06-01

    Full Text Available Incognito ergo sum: on indifference  The present article is an analysis of various types of indifference of non-Jewish inhabitants of Warsaw to the plight of Jewish Poles. The words of Krzysztof Dunin-Wąsowicz, a historian and “Żegota” activist, provide the vantage point for the analysis: Dunin-Wąsowicz claimed that around 75 per cent of the inhabitants of Warsaw “were indifferent to what was taking place behind the Ghetto wall”. Thomas Kuhne hypothesised that it was Germans’ indifference to the Jewish – not hatred – that legitimised the Nazi racial policies of the 1930s. This statement might also apply to the “75 per cent of the inhabitants of Warsaw”. The article is mainly based on articles published by ZWZ-AK, in particular Biuletyn Informacyjny.   Incognito ergo sum. O wytwarzaniu obojętności Autorka analizuje różne odcienie obojętności nieżydowskich mieszkańców Warszawy w latach czterdziestych wobec losu żydowskich Polaków. Punktem wyjścia jest zdanie Krzysztofa Dunin-Wąsowicza, historyka i działacza „Żegoty”, który stwierdził, że dla około 75 procent mieszkańców Warszawy „obojętne było to, co działo się poza murem getta”. Powołując się na tezę Thomasa Kuhnego, że to właśnie obojętność Niemców wobec Żydów – a nie nienawiść w stosunku do nich – „spowodowała masowe poparcie nazistowskiej polityki rasowej w latach trzydziestych”, autorka zastanawia się, czy „podobnej opinii nie można by sformułować pod adresem” 75 procent mieszkańców Warszawy. Materiał do analizy stanowią w znacznej mierze publikacje prasy ZWZ-AK, w tym przede wszystkim „Biuletyn Informacyjny”.

  7. Gry w podmiot. Szkic o (wczesnej twórczości Mladena Stilinovicia

    Directory of Open Access Journals (Sweden)

    Magdalena Bogusławska

    2016-10-01

    Full Text Available Games of a subject: A sketch of the (early works of Mladen Stilinović The article concerns the conceptualization of the subject in the works of the contemporary Croatian visual artist Mladen Stilinović. The object of analysis are most of all works (collages, texts from the 1970s and early 1980s, when the artist formulated the basis for his creative philosophy and at the same time determined the directions of their research. His system of reference were the socialist state order and the traditionalist, academic system of artistic practice, which he criticized from the perspectives of Diogenes, philosophical Cynicism and constructive anarchism. Until this day, the attitude of resistance is the main creative principle for Stilinović’s art. He sets strong, conscious and autonomous creator’s “I” against symbolic violence of different systems (political, ideological, educational, etc.. This “I” is not so much the material and object of expression as a space of play based on concpetualism and self-irony.   Gry w podmiot. Szkic o (wczesnej twórczości Mladena Stilinovicia Artykuł dotyczy konceptualizacji podmiotu w twórczości współczesnego chorwackiego artysty wizualnego – Mladena Stilinovicia. Przedmiotem analizy są przede wszystkim prace (kolaże, teksty z lat 70. i początku 80. XX wieku, kiedy to artysta formułował podstawy filozofii twórczej i określał kierunki swych poszukiwań. Układem odniesienia były dla niego wówczas socjalistyczny porządek państwa i tradycjonalistyczny, akademicki system praktyki artystycz­nej, które poddawał konsekwentnej krytyce z pozycji rozumnego, diogenesowskiego cynizmu i konstruktywnego anarchizmu. Do dziś postawa oporu jest dla Stilinovicia podstawową zasadą twórczą. Przemocy symbolicznej wszelkich systemów (politycznych, ideologicznych, edukacyjnych itp. przeciwstawia mocne, świadome i niezależne „ja” twórcy. Jest tu ono nie tyle tworzywem i przedmiotem ekspresji

  8. Comets as Parent Bodies of CI1 Carbonaceous Meteorites and Possible Habitats of Ice-Microbiota

    Science.gov (United States)

    Wickramasinghe, N. Chandra; Wallis, Daryl H.; Rozanov, Alexei Yu.; Hoover, Richard B.

    2011-01-01

    Recent studies of comets and cometary dust have confirmed the presence of biologically relevant organic molecules along with clay minerals and water ice. It is also now well established by deuterium/hydrogen ratios that the CI1 carbonaceous meteorites contain indigenous extraterrestrial water. The evidence of extensive aqueous alteration of the minerals in these meteorites led to the hypothesis that water-bearing asteroids or comets represent the parent bodies of the CI1 (and perhaps CM2) carbonaceous meteorites. These meteorites have also been shown to possess a diverse array of complex organics and chiral and morphological biomarkers. Stable isotope studies by numerous independent investigators have conclusively established that the complex organics found in these meteorites are both indigenous and extraterrestrial in nature. Although the origin of these organics is still unknown, some researchers have suggested that they originated by unknown abiotic mechanisms and may have played a role in the delivery of chiral biomolecules and the origin of life on Early Earth. In this paper we review these results and investigate the thermal history of comets. We show that permanent as well as transient domains of liquid water can be maintained on a comet under a plausible set of assumptions. With each perihelion passage of a comet volatiles are preferentially released, and during millions of such passages the comet could shed crustal debris that may survive transit through the Earth s atmosphere as a carbonaceous meteorite. We review the current state of knowledge of comets and carbonaceous meteorites. We also present the results of recent studies on the long-term viability of terrestrial ice-microbiota encased in ancient glacial ice and permafrost. We suggest that the conditions which have been observed to prevail on many comets do not preclude either survivability (or even the active metabolism and growth) of many types of eukaryotic and prokaryotic microbial

  9. LHV predication models and LHV effect on the performance of CI engine running with biodiesel blends

    International Nuclear Information System (INIS)

    Tesfa, B.; Gu, F.; Mishra, R.; Ball, A.D.

    2013-01-01

    Highlights: • Lower heating values of neat biodiesel and its blends were measured experimentally. • Lower heating value prediction models were developed based on the density and viscosity values of the fuel. • The predication models were validated by measured values and previous models. • The prediction models were used to predict the lower heating value of 24 biodiesel feedstock types produced globally. • The effects of lower heating vale on brake specific fuel consumption and thermal efficiency were investigated. - Abstract: The heating value of fuel is one of its most important physical properties, and is used for the design and numerical simulation of combustion processes within internal combustion (IC) engines. Recently, there has been a significant increase in the use of dual fuel and blended fuels in compression ignition (CI) engines. Most of the blended fuels include biodiesel as one of the constituents and hence the objective of this study is to investigate the effect of biodiesel content to lower heating value (LHV) and to develop new LHV prediction models that correlate the LHV with biodiesel fraction, density and viscosity. Furthermore, this study also investigated the effects of the LHV on CI engines performance parameters experimentally. To achieve the above mentioned objectives density, viscosity and LHV of rapeseed oil biodiesel, corn oil biodiesel and waste oil biodiesel at different blend fraction values (B0, B5, B10, B20, B50, B75, and B100, where ‘B5’ denotes a blend of 5% biodiesel and 95% mineral diesel, etc.) were measured as per EN ISO 3675:1998, EN ISO 3104:1996 and DIN 51900 standards. The engine experimental work was conducted on a four-cylinder, four-stroke, direct injection (DI) and turbocharged diesel engine by using rapeseed oil and normal diesel blends. Based on the experimental results, models were developed which have the capability to predict the LHV corresponding to different fractions, densities and viscosities of

  10. Multicentre evaluation of the Naída CI Q70 sound processor: feedback from cochlear implant users and professionals

    Directory of Open Access Journals (Sweden)

    Jeanette Martin

    2016-12-01

    Full Text Available The aim of this survey was to gather data from both implant recipients and professionals on the ease of use of the Naída CI Q70 (Naída CI sound processor from Advanced Bionics and on the usefulness of the new functions and features available. A secondary objective was to investigate fitting practices with the new processor. A comprehensive user satisfaction survey was conducted in a total of 186 subjects from 24 centres. In parallel, 23 professional questionnaires were collected from 11 centres. Overall, there was high satisfaction with the Naída CI processor from adults, children, experienced and new CI users as well as from professionals. The Naída CI processor was shown as being easy to use by all ages of recipients and by professionals. The majority of experienced CI users rated the Naída CI processor as being similar or better than their previous processor in all areas surveyed. The Naída CI was recommended by the professionals for fitting in all populations. Features like UltraZoom, ZoomControl and DuoPhone would not be fitted to very young children in contrast to adults. Positive ratings were obtained for ease of use, comfort and usefulness of the new functions and features of the Naída CI sound processor. Seventy-seven percent of the experienced CI users rated the new processor as being better than their previous sound processor from a general point of view. The survey also showed that fitting practices were influenced by the age of the user.

  11. Plant Proteinase Inhibitor BbCI Modulates Lung Inflammatory Responses and Mechanic and Remodeling Alterations Induced by Elastase in Mice

    Directory of Open Access Journals (Sweden)

    Rafael Almeida-Reis

    2017-01-01

    Full Text Available Background. Proteinases play a key role in emphysema. Bauhinia bauhinioides cruzipain inhibitor (BbCI is a serine-cysteine proteinase inhibitor. We evaluated BbCI treatment in elastase-induced pulmonary alterations. Methods.  C57BL/6 mice received intratracheal elastase (ELA group or saline (SAL group. One group of mice was treated with BbCI (days 1, 15, and 21 after elastase instillation, ELABC group. Controls received saline and BbCI (SALBC group. After 28 days, we evaluated respiratory mechanics, exhaled nitric oxide, and bronchoalveolar lavage fluid. In lung tissue we measured airspace enlargement, quantified neutrophils, TNFα-, MMP-9-, MMP-12-, TIMP-1-, iNOS-, and eNOS-positive cells, 8-iso-PGF2α, collagen, and elastic fibers in alveolar septa and airways. MUC-5-positive cells were quantified only in airways. Results. BbCI reduced elastase-induced changes in pulmonary mechanics, airspace enlargement and elastase-induced increases in total cells, and neutrophils in BALF. BbCI reduced macrophages and neutrophils positive cells in alveolar septa and neutrophils and TNFα-positive cells in airways. BbCI attenuated elastic and collagen fibers, MMP-9- and MMP-12-positive cells, and isoprostane and iNOS-positive cells in alveolar septa and airways. BbCI reduced MUC5ac-positive cells in airways. Conclusions. BbCI improved lung mechanics and reduced lung inflammation and airspace enlargement and increased oxidative stress levels induced by elastase. BbCI may have therapeutic potential in chronic obstructive pulmonary disease.

  12. Cu and Cu-Based Nanoparticles: Synthesis and Applications in Catalysis.

    Science.gov (United States)

    Gawande, Manoj B; Goswami, Anandarup; Felpin, François-Xavier; Asefa, Tewodros; Huang, Xiaoxi; Silva, Rafael; Zou, Xiaoxin; Zboril, Radek; Varma, Rajender S

    2016-03-23

    The applications of copper (Cu) and Cu-based nanoparticles, which are based on the earth-abundant and inexpensive copper metal, have generated a great deal of interest in recent years, especially in the field of catalysis. The possible modification of the chemical and physical properties of these nanoparticles using different synthetic strategies and conditions and/or via postsynthetic chemical treatments has been largely responsible for the rapid growth of interest in these nanomaterials and their applications in catalysis. In addition, the design and development of novel support and/or multimetallic systems (e.g., alloys, etc.) has also made significant contributions to the field. In this comprehensive review, we report different synthetic approaches to Cu and Cu-based nanoparticles (metallic copper, copper oxides, and hybrid copper nanostructures) and copper nanoparticles immobilized into or supported on various support materials (SiO2, magnetic support materials, etc.), along with their applications in catalysis. The synthesis part discusses numerous preparative protocols for Cu and Cu-based nanoparticles, whereas the application sections describe their utility as catalysts, including electrocatalysis, photocatalysis, and gas-phase catalysis. We believe this critical appraisal will provide necessary background information to further advance the applications of Cu-based nanostructured materials in catalysis.

  13. Stark broadening in the laser-induced Cu I and Cu II spectra

    International Nuclear Information System (INIS)

    Skočić, M; Burger, M; Nikolić, Z; Bukvić, S; Djeniže, S

    2013-01-01

    In this work we present the Stark widths (W) of 22 neutral (Cu I) and 100 singly ionized (Cu II) copper spectral lines that have been measured at 18 400 K and 19 300 K electron temperatures and 6.3 × 10  22 m −3 and 2.1 × 10  23 m −3 electron densities, respectively. The experiment is conducted in the laser-induced plasma—the Nd:YAG laser, operating at 532 nm, was used to produce plasma from the copper sample in the residual air atmosphere at a pressure of 8 Pa. The electron temperature and density were estimated by the Boltzmann-plot method and from the Saha equation. The investigated Cu I lines belong to the 4s–4p′, 4s  2 –4p″ and 4p′–4d′ transitions while Cu II spectral lines belong to the 4s–4p, 4p–5s, 4p–4d, 4p–4s  2 , 4d–4f and 4d–v transitions. Comparison with existing experimental data was possible only in the case of 17 Cu II lines due to a lack of experimental and theoretical values. The rest of the data, Stark widths of 22 Cu I and 83 Cu II lines are published for the first time. (paper)

  14. Mechanochemical synthesis of Cu-Al and methyl orange intercalated Cu-Al layered double hydroxides

    Energy Technology Data Exchange (ETDEWEB)

    Qu, Jun, E-mail: forsjun@whut.edu.cn [School of Resources and Environmental Engineering, Wuhan University of Technology, Luoshi Road 122, Wuhan, Hubei 430070 (China); He, Xiaoman; Chen, Min; Hu, Huimin [School of Resources and Environmental Engineering, Wuhan University of Technology, Luoshi Road 122, Wuhan, Hubei 430070 (China); Zhang, Qiwu, E-mail: zhangqw@whut.edu.cn [School of Resources and Environmental Engineering, Wuhan University of Technology, Luoshi Road 122, Wuhan, Hubei 430070 (China); Liu, Xinzhong [College of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou 350118 China (China)

    2017-04-15

    In this study, a mechanochemical route to synthesize a Cu-Al layered double hydroxide (LDH) and a methyl orange (MO) intercalated one (MO-LDH) was introduced, in which basic cupric carbonate (Cu{sub 2}(OH){sub 2}CO{sub 3}) and aluminum hydroxide (Al(OH){sub 3}) with Cu/Al molar ratio at 2/1 was first dry ground for 2 h and then agitated in water or methyl orange solution for another 4 h to obtain the LDH and MO-LDH products without any heating operation. The prepared samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Thermogravimetry (TG), Differential scanning calorimetry (DSC) and Scanning electron microscopy (SEM). The products showed high crystallinity phase of Cu-Al and MO intercalated Cu-Al LDH with no evident impurities, proving that the craft introduced here was facile and effective. The new idea can be applied in other fields to produce organic-inorganic composites. - Highlights: • A facile mechanochemical route to synthesize Cu-Al and MO intercalated Cu-Al LDH. • The products possesses high crystalline of LDH phase with no impure phases. • The dry milling process induces the element substitution between the raw materials. • The agitation operation helps the grain growth of LDH.

  15. Mechanochemical synthesis of Cu-Al and methyl orange intercalated Cu-Al layered double hydroxides

    International Nuclear Information System (INIS)

    Qu, Jun; He, Xiaoman; Chen, Min; Hu, Huimin; Zhang, Qiwu; Liu, Xinzhong

    2017-01-01

    In this study, a mechanochemical route to synthesize a Cu-Al layered double hydroxide (LDH) and a methyl orange (MO) intercalated one (MO-LDH) was introduced, in which basic cupric carbonate (Cu_2(OH)_2CO_3) and aluminum hydroxide (Al(OH)_3) with Cu/Al molar ratio at 2/1 was first dry ground for 2 h and then agitated in water or methyl orange solution for another 4 h to obtain the LDH and MO-LDH products without any heating operation. The prepared samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Thermogravimetry (TG), Differential scanning calorimetry (DSC) and Scanning electron microscopy (SEM). The products showed high crystallinity phase of Cu-Al and MO intercalated Cu-Al LDH with no evident impurities, proving that the craft introduced here was facile and effective. The new idea can be applied in other fields to produce organic-inorganic composites. - Highlights: • A facile mechanochemical route to synthesize Cu-Al and MO intercalated Cu-Al LDH. • The products possesses high crystalline of LDH phase with no impure phases. • The dry milling process induces the element substitution between the raw materials. • The agitation operation helps the grain growth of LDH.

  16. Cu ion disordering in high ionic conductor Rb4Cu16I7Cl13

    International Nuclear Information System (INIS)

    Kawaji, Hitoshi; Atake, Tooru; Kanno, Ryoji; Izumi, Fujio; Yamamoto, Osamu.

    1993-01-01

    The properties of a high ionic conductor Rb 4 Cu 16 I 7+x Cl 13-x were studied by neutron and X-ray diffraction, and heat capacity measurements. The structure parameters of Rb 4 Cu 16 I 7.2 Cl 12.8 were obtained by the Rietveld analysis of TOF neutron diffraction data between 50 and 300 K, which showed gradual excitation of migration of Cu ions from Cu(3) site into Cu(2) site with increasing temperature from about 100 K to room temperature. The heat capacity was measured between 10 and 300 K using a high precision adiabatic calorimeter. An abnormal increase was observed in the heat capacity curve above about 100 K. The excess heat capacity showed a broad anomaly with a maximum at about 190 K. The measurements were also made of Rb 4 Cu 16 I 7 Cl 13 which showed slight different properties from Rb 4 Cu 16 I 7.2 Cl 12.8 . (author)

  17. Effect of Cu Salt Molarity on the Nanostructure of CuO Prolate Spheroid

    Science.gov (United States)

    Sabeeh, Sabah H.; Hussein, Hashim Abed; Judran, Hadia Kadhim

    Copper sulfate pentahydrate was used as a source of Cu ion with five different molarities (0.02, 0.05, 0.1, 0.15, 2 and 0.25M). XRD, FE-SEM and TEM techniques all showed that CuO samples have polycrystalline monoclinic structure. CuO prolate spheroid is assembled from nanoparticles as building units. It was demonstrated that the purity, morphology, size range of prolate spheroid and density of nano building units are significantly influenced by Cu precursor’s molarity. The pure phase of CuO prolate spheroid was produced via molarity of 0.2M with crystallite size of 15.1565nm while the particle size of building units ranges from 16nm to 21nm. The stability of CuO nanosuspension or nanofluid was evaluated by zeta potential analysis. The obtained properties of specific structure with large surface area of CuO prolate spheroid make it a promising candidate for wide range of potential applications as in nanofluids for cooling purposes.

  18. Virtual thermal expansion coefficient of Cu precipitated in the Fe95Cu5 alloy

    International Nuclear Information System (INIS)

    Koeszegi, L.; Somogyvari, Z.

    1999-01-01

    Complete text of publication follows. Precipitations on grain boundaries play very important role in the formation of material's characteristics like embrittlement, durability etc. It was already shown [1] that Cu precipitations are under different stress conditions than the bulk material. The situation is more complicated in the case when a construction is exposed to temperature changes as well. In that case not only the residual stresses during the fabrication but the different thermal expansion coefficients can produce additional problems. This situation was modelled using Fe 95 Cu 5 alloy where Cu precipitates on the grain boundaries. The alloy was produced by high-frequency melting and an extra heat treatment was used to produce a quasi-equilibrium state. Pure Cu was also measured to compare the behaviours. Cu(111) Bragg peak was measured at different temperatures by high resolution neutron diffraction. The measurements were carried out on the G5-2 spectrometer at LLB in Saclay. Measurements show that not only residual stress can be recognised on the Cu precipitates but the thermal expansion coefficient of these precipitates definitly differ from the ones of pure Cu. (author)

  19. Beta-decay of 56Cu

    International Nuclear Information System (INIS)

    Ramdhane, M.; Baumann, P.; Knipper, A.; Walter, G.; Janas, Z.; Plochocki, A.; Liu, W.; Grawe, H.; Hu, Z.; Kirchner, R.; Klepper, O.; Roeckl, E.; Gorska, M.; Fujita, Y.; Brown, B.A.

    1998-02-01

    By measuring positrons and β-delayed γ-rays emitted from mass-separated sources, the decay of 56 Cu(4 + ,T z =-1,T=1) to states in the doubly-magic nucleus 56 Ni was studied for the first time. The half-life of 56 Cu was measured to be 78(15) ms, and four β-delayed γ-rays were assigned to its decay. The resulting experimental data on Fermi and Gamow-Teller strength are compared with shell-model predictions. (orig.)

  20. Architectural Growth of Cu Nanoparticles Through Electrodeposition

    Directory of Open Access Journals (Sweden)

    Cheng Ching-Yuan

    2009-01-01

    Full Text Available Abstract Cu particles with different architectures such as pyramid, cube, and multipod have been successfully fabricated on the surface of Au films, which is the polycrystalline Au substrate with (111 domains, using the electrodeposition technique in the presence of the surface-capping reagents of dodecylbenzene sulfonic acid and poly(vinylpyrrolidone. Further, the growth evolution of pyramidal Cu nanoparticles was observed for the first time. We believe that our method might open new possibilities for fabricating nanomaterials of non-noble transition metals with various novel architectures, which can then potentially be utilized in applications such as biosensors, catalysis, photovoltaic cells, and electronic nanodevices.

  1. Beta-decay of {sup 56}Cu

    Energy Technology Data Exchange (ETDEWEB)

    Ramdhane, M.; Baumann, P.; Knipper, A.; Walter, G. [Institute de Recherches Subatomiques, 67 - Strasbourg (France); Janas, Z.; Plochocki, A. [Warsaw Univ. (Poland). Inst. of Experimental Physics; Aeystoe, J.; Dendooven, P.; Jokinen, A.; Oinonen, M.; Pentilae, H. [Jyvaeskylae Univ. (Finland); Liu, W.; Grawe, H.; Hu, Z.; Kirchner, R.; Klepper, O.; Roeckl, E. [Gesellschaft fuer Schwerionenforschung mbH, Darmstadt (Germany); Gorska, M. [Warsaw Univ. (Poland). Inst. of Experimental Physics]|[Gesellschaft fuer Schwerionenforschung mbH, Darmstadt (Germany); Fujita, Y. [Osaka Univ. (Japan); Brown, B.A. [Michigan State Univ., East Lansing, MI (United States)

    1998-02-01

    By measuring positrons and {beta}-delayed {gamma}-rays emitted from mass-separated sources, the decay of {sup 56}Cu(4{sup +},T{sub z}=-1,T=1) to states in the doubly-magic nucleus {sup 56}Ni was studied for the first time. The half-life of {sup 56}Cu was measured to be 78(15) ms, and four {beta}-delayed {gamma}-rays were assigned to its decay. The resulting experimental data on Fermi and Gamow-Teller strength are compared with shell-model predictions. (orig.)

  2. Isovector giant quadrupole resonance in 63Cu

    International Nuclear Information System (INIS)

    Wolynec, E.; Pastura, V.F.S.; Martins, M.N.

    1988-01-01

    The decay of the isovector E2 giant resonance in 63 Cu has been studied by measuring the (e,2n) cross section, in the incident electron energy range 22-45 MeV. The photodisintegration induced by bremsstrahlung was also measured. The electrodisintegration results have been analyzed using the distorted wave Born approximation E1 and E2 virtual photon spectra to obtain these multipole components in the corresponding (γ,2n) cross section. It is found that the isovector E2 giant resonance decays dominantly by two-neutron emission in 63 Cu. This decay channel exhausts 65 percent of the energy weighted E2 sum. (author0 [pt

  3. Synthesis of Cu/Cu2O nanoparticles by laser ablation in deionized water and their annealing transformation into CuO nanoparticles

    KAUST Repository

    Gondal, M. A.; Qahtan, Talal F.; Dastageer, Mohamed Abdulkader; Maganda, Yasin W.; Anjum, Dalaver H.

    2013-01-01

    Nano-structured Cupric Oxide (CuO) has been synthesized using pulsed laser ablation of pure copper in water using Q-switched pulsed laser beam of 532 nm wavelength and, 5 nanosecond pulse duration and laser pulse energy of 100 mJ/pulse. In the initial unannealed colloidal suspension, the nanoparticles of Copper (Cu) and Cuprious oxide (Cu2O) were identified. Further the suspension was dried and annealed at different temperatures and we noticed the product (Cu/Cu2O) was converted predominantly into CuO at annealing temperature of 300 'C for 3 hours. As the annealing temperature was raised from 300 to 900 'C, the grain sizes of CuO reduced to the range of 9 to 26 nm. The structure and the morphology of the prepared samples were investigated using X-ray diffraction and Transmission Electron Microscope. Photoluminescence and UV absorption spectrometrystudies revealed that the band gap and other optical properties of nano-structured CuO were changed due to post annealing. Fourier transform spectrometry also confirmed the transformation of Cu/Cu2O into CuO. Copyright © 2013 American Scientific Publishers All rights reserved.

  4. Characterization of p-CuI prepared by the SILAR technique on Cu-tape/n-CuInS2 for solar cells

    International Nuclear Information System (INIS)

    Sankapal, B.R.; Ennaoui, A.; Guminskaya, T.; Dittrich, Th.; Bohne, W.; Roehrich, J.; Strub, E.; Lux-Steiner, M.Ch.

    2005-01-01

    CuI has been synthesized at room temperature on Cu-tape/n-CuInS 2 by using the SILAR technique (successive ionic layer adsorption and reaction). The influence of wet chemical iodine treatment on the CuI has been investigated in more detail. The films were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), elastic recoil detection analysis (ERDA) and surface photovoltage (SPV) techniques. The CuI films contain the no. gammano. -phase of the Zinkblende structure. The crystallites are preferentially oriented in the (111) direction. After wet chemical iodine treatment, the fibrous surface morphology changed to a more dense CuI film with larger crystallites. Oxides could not be detected on the CuI surface. The density of surface states of CIS decreased after the CuI deposition. The importance of the wet chemical iodine treatment for the performance of Cu-tape/n-CuInS 2 /p-CuI solar cells has been demonstrated

  5. Characterization of p-CuI prepared by the SILAR technique on Cu-tape/n-CuInS{sub 2} for solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Sankapal, B.R. [Hahn-Meitner-Institut, Glienicker Strasse 100, D-14109, Berlin (Germany)]. E-mail: brsankapal@rediffmail.com; Ennaoui, A. [Hahn-Meitner-Institut, Glienicker Strasse 100, D-14109, Berlin (Germany); Guminskaya, T. [Hahn-Meitner-Institut, Glienicker Strasse 100, D-14109, Berlin (Germany); Dittrich, Th. [Hahn-Meitner-Institut, Glienicker Strasse 100, D-14109, Berlin (Germany); Bohne, W. [Hahn-Meitner-Institut, Glienicker Strasse 100, D-14109, Berlin (Germany); Roehrich, J. [Hahn-Meitner-Institut, Glienicker Strasse 100, D-14109, Berlin (Germany); Strub, E. [Hahn-Meitner-Institut, Glienicker Strasse 100, D-14109, Berlin (Germany); Lux-Steiner, M.Ch. [Hahn-Meitner-Institut, Glienicker Strasse 100, D-14109, Berlin (Germany)

    2005-06-01

    CuI has been synthesized at room temperature on Cu-tape/n-CuInS{sub 2} by using the SILAR technique (successive ionic layer adsorption and reaction). The influence of wet chemical iodine treatment on the CuI has been investigated in more detail. The films were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), elastic recoil detection analysis (ERDA) and surface photovoltage (SPV) techniques. The CuI films contain the no. gammano. -phase of the Zinkblende structure. The crystallites are preferentially oriented in the (111) direction. After wet chemical iodine treatment, the fibrous surface morphology changed to a more dense CuI film with larger crystallites. Oxides could not be detected on the CuI surface. The density of surface states of CIS decreased after the CuI deposition. The importance of the wet chemical iodine treatment for the performance of Cu-tape/n-CuInS{sub 2}/p-CuI solar cells has been demonstrated.

  6. Synthesis of Cu/Cu2O nanoparticles by laser ablation in deionized water and their annealing transformation into CuO nanoparticles

    KAUST Repository

    Gondal, M. A.

    2013-08-01

    Nano-structured Cupric Oxide (CuO) has been synthesized using pulsed laser ablation of pure copper in water using Q-switched pulsed laser beam of 532 nm wavelength and, 5 nanosecond pulse duration and laser pulse energy of 100 mJ/pulse. In the initial unannealed colloidal suspension, the nanoparticles of Copper (Cu) and Cuprious oxide (Cu2O) were identified. Further the suspension was dried and annealed at different temperatures and we noticed the product (Cu/Cu2O) was converted predominantly into CuO at annealing temperature of 300 \\'C for 3 hours. As the annealing temperature was raised from 300 to 900 \\'C, the grain sizes of CuO reduced to the range of 9 to 26 nm. The structure and the morphology of the prepared samples were investigated using X-ray diffraction and Transmission Electron Microscope. Photoluminescence and UV absorption spectrometrystudies revealed that the band gap and other optical properties of nano-structured CuO were changed due to post annealing. Fourier transform spectrometry also confirmed the transformation of Cu/Cu2O into CuO. Copyright © 2013 American Scientific Publishers All rights reserved.

  7. Chemical synthesis of Cu2Se nanoparticles at room temperature

    International Nuclear Information System (INIS)

    Rong, Fengxia; Bai, Yan; Chen, Tianfeng; Zheng, Wenjie

    2012-01-01

    Graphical abstract: The Cu 2 Se nanoparticles were synthesized by a simple and rapid method at room temperature. The TEM and SEM images show that the Cu 2 Se nanoparticles were spherical. Highlights: ► Cu 2 Se nanoparticles were synthesized by the reaction of nanoSe 0 sol with Cu + ions. ► The Cu 2 Se nanoparticles were spherical with cubic structure and well crystallized. ► Optical and electrochemical properties of Cu 2 Se nanoparticles were observed. ► The formation mechanism of Cu 2 Se nanoparticles was proposed. -- Abstract: A simple and rapid method has been developed to synthesize cuprous selenide (Cu 2 Se) nanoparticles by the reaction of selenium nanoparticles sol with copper sulfate solution containing ascorbic acid at room temperature. Cu 2 Se nanoparticles were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and energy dispersive X-ray analysis (EDX). The results indicated that Cu 2 Se nanoparticles were cubic crystal structure and spherical with the diameter about 75 nm. The ultraviolet–visible absorption spectrum (UV–vis) and cyclic voltammetry of Cu 2 Se nanoparticles were also investigated. The optical band gap energy of Cu 2 Se nanoparticles was 1.94 eV. On the basis of a series of experiments and characterizations, the formation mechanism of Cu 2 Se nanoparticles was discussed.

  8. Diffusion characteristics in the Cu-Ti system

    Energy Technology Data Exchange (ETDEWEB)

    Laik, Arijit; Kale, Gajanan Balaji [Bhabha Atomic Reseach Centre, Mumbai (India). Materials Science Div.; Bhanumurthy, Karanam [Bhabha Atomic Reseach Centre, Mumbai (India). Scientific Information Resource Div.; Kashyap, Bhagwati Prasad [Indian Institute of Technology Bombay, Mumbai (India). Dept. of Metallurgical Engineering

    2012-06-15

    The formation and growth of intermetallic compounds by diffusion reaction of Cu and Ti were investigated in the temperature range 720 - 860 C using bulk diffusion couples. Only four, out of the seven stable intermediate compounds of the Cu-Ti system, were formed in the diffusion reaction zone in the sequence CuTi, Cu{sub 4}Ti, Cu{sub 4}Ti{sub 3} and CuTi{sub 2}. The activation energies required for the growth of these compounds were determined. The diffusion characteristics of Cu{sub 4}Ti, CuTi and Cu{sub 4}Ti{sub 3} and Cu(Ti) solid solution were evaluated. The activation energies for diffusion in these compounds were 192.2, 187.7 and 209.2 kJ mol{sup -1} respectively, while in Cu(Ti), the activation energy increased linearly from 201.0 kJ mol{sup -1} to 247.5 kJ mol{sup -1} with increasing concentration of Ti, in the range 0.5 - 4.0 at.%. The impurity diffusion coefficient of Ti in Cu and its temperature dependence were also estimated. A correlation between the impurity diffusion parameters for several elements in Cu matrix has been established. (orig.)

  9. Corrosion and runoff rates of Cu and three Cu-alloys in marine environments with increasing chloride deposition rate.

    Science.gov (United States)

    Odnevall Wallinder, Inger; Zhang, Xian; Goidanich, Sara; Le Bozec, Nathalie; Herting, Gunilla; Leygraf, Christofer

    2014-02-15

    Bare copper sheet and three commercial Cu-based alloys, Cu15Zn, Cu4Sn and Cu5Al5Zn, have been exposed to four test sites in Brest, France, with strongly varying chloride deposition rates. The corrosion rates of all four materials decrease continuously with distance from the coast, i.e. with decreasing chloride load, and in the following order: Cu4Sn>Cu sheet>Cu15Zn>Cu5Al5Zn. The patina on all materials was composed of two main layers, Cu2O as the inner layer and Cu2(OH)3Cl as the outer layer, and with a discontinuous presence of CuCl in between. Additional minor patina constituents are SnO2 (Cu4Sn), Zn5(OH)6(CO3)2 (Cu15Zn and Cu5Al5Zn) and Zn6Al2(OH)16CO3·4H2O/Zn2Al(OH)6Cl·2H2O/Zn5Cl2(OH)8·H2O and Al2O3 (Cu5Al5Zn). The observed Zn- and Zn/Al-containing corrosion products might be important factors for the lower sensitivity of Cu15Zn and Cu5Al5Zn against chloride-induced atmospheric corrosion compared with Cu sheet and Cu4Sn. Decreasing corrosion rates with exposure time were observed for all materials and chloride loads and attributed to an improved adherence with time of the outer patina to the underlying inner oxide. Flaking of the outer patina layer was mainly observed on Cu4Sn and Cu sheet and associated with the gradual transformation of CuCl to Cu2(OH)3Cl of larger volume. After three years only Cu5Al5Zn remains lustrous because of a patina compared with the other materials that appeared brownish-reddish. Significantly lower release rates of metals compared with corresponding corrosion rates were observed for all materials. Very similar release rates of copper from all four materials were observed during the fifth year of marine exposure due to an outer surface patina that with time revealed similar constituents and solubility properties. Copyright © 2013 The Authors. Published by Elsevier B.V. All rights reserved.

  10. Identification of two CiGADs from Caragana intermedia and their transcriptional responses to abiotic stresses and exogenous abscisic acid.

    Science.gov (United States)

    Ji, Jing; Zheng, Lingyu; Yue, Jianyun; Yao, Xiamei; Chang, Ermei; Xie, Tiantian; Deng, Nan; Chen, Lanzhen; Huang, Yuwen; Jiang, Zeping; Shi, Shengqing

    2017-01-01

    Glutamate decarboxylase (GAD), as a key enzyme in the γ -aminobutyric acid (GABA) shunt, catalyzes the decarboxylation of L-glutamate to form GABA. This pathway has attracted much interest because of its roles in carbon and nitrogen metabolism, stress responses, and signaling in higher plants. The aim of this study was to isolate and characterize genes encoding GADs from Caragana intermedia , an important nitrogen-fixing leguminous shrub. Two full-length cDNAs encoding GADs (designated as CiGAD1 and CiGAD2 ) were isolated and characterized. Multiple alignment and phylogenetic analyses were conducted to evaluate their structures and identities to each other and to homologs in other plants. Tissue expression analyses were conducted to evaluate their transcriptional responses to stress (NaCl, ZnSO 4 , CdCl 2 , high/low temperature, and dehydration) and exogenous abscisic acid. The CiGAD s contained the conserved PLP domain and calmodulin (CaM)-binding domain in the C-terminal region. The phylogenetic analysis showed that they were more closely related to the GADs of soybean, another legume, than to GADs of other model plants. According to Southern blotting analysis, CiGAD1 had one copy and CiGAD2 -related genes were present as two copies in C. intermedia . In the tissue expression analyses, there were much higher transcript levels of CiGAD2 than CiGAD1 in bark, suggesting that CiGAD2 might play a role in secondary growth of woody plants. Several stress treatments (NaCl, ZnSO 4 , CdCl 2 , high/low temperature, and dehydration) significantly increased the transcript levels of both CiGAD s, except for CiGAD2 under Cd stress. The CiGAD1 transcript levels strongly increased in response to Zn stress (74.3-fold increase in roots) and heat stress (218.1-fold increase in leaves). The transcript levels of both CiGAD s significantly increased as GABA accumulated during a 24-h salt treatment. Abscisic acid was involved in regulating the expression of these two CiGAD s under salt

  11. Da metamatemática para a ciência cognitiva From metamathematics to Cognitive Science

    Directory of Open Access Journals (Sweden)

    Henrique de Morais Ribeiro

    1999-01-01

    Full Text Available Neste artigo, propõe-se uma configuração possível para a transição histórico-filosófica de temas investigados no domínio da metamatemática para o domínio da Ciência Cognitiva funcionalista neurocomputacional. A descrição de tal transição é feita por meio de uma breve análise das idéias de Post, Church, Gödel e Turing sobre a possibilidade de formalização do pensamento criador na matemática, enfatizando as contribuições deste último.In this article, it is suggested a possible profile for the historical and philosophical migration of several issues from the metamathematical domain to the domain of functionalist neuro-computational Cognitive Science. The description of such a transition is accomplished by an analysis of the ideas of Post, Church, Gödel, and, in particular, Turing on the possibility of formalization of creative thinking in Mathematics.

  12. Metabolic disposition of CI-924, a new lipid regulating agent, in laboratory animals

    International Nuclear Information System (INIS)

    Mertz, N.; Windsor, B.; Chang, T.

    1986-01-01

    The disposition of carbon-14 labeled CI-924 (I), 5,5'-[1,1-biphenyl]-2,5 diyl-bis(oxy)-bis-2,2'-dimethylpentanoic acid, was studied in beagle dogs and rats following single 10 mg/kg po doses. Serial plasma, urine and fecal samples were collected up to 168 hr and analyzed for total radioactivity. Peak 14 C plasma concentrations of 31 mcg/ml (dogs) and 66 mcg/ml (rats) were attained within 0.5 and 1.0 hr after dosing. The concentrations declined thereafter with estimated half life of 11 and 5 hr in rats and dogs, respectively. TLC radiochromatography revealed that I was the only component in circulating blood. Tissue distribution study in rats showed that the highest 14 C concentrations were found in plasma and liver with decreasing concentrations in lung, heart, kidney, skin, gonads, spleen, fat, muscle, adrenals, and brain. All tissue concentrations declined in parallel with plasma levels with half lives of 14-22 hr. Urinary and fecal excretion accounted for 1-3% and 92-96% of the dose, respectively. Balance study in bile duct cannulated rats showed that 90%, 1%, and 1% of the dose was excreted in bile, urine, and feces. Unchanged drug and varying amounts of its conjugate were the only products present in bile, urine or feces. These results indicate that I was completely absorbed and eliminated primarily by biliary excretion in the form of unchanged drug and its conjugate

  13. Biological, serological and molecular techniques to xanthomonas axonopodis pv. Ci tri Asymptomatic detection

    International Nuclear Information System (INIS)

    Peyrou, M.; Del Campo, R.; Russi, P.; Mara, H.; Rigamonti, N.; Larrechart, L.; Perez, E.

    2012-01-01

    Xanthomonas axonopodis pv. ci tri (X ac) produces citrus canker disease in all citrus commercial species. The bacteria can be disseminated through vegetative propagation material in asymptomatic form. To optimize bacteria detection techniques applicable to asymptomatic citrus plant tissue routine analysis, ELISA, Immunofluorescence, Pcr, qRT P CR and host plant inoculation (bioassay) diagnostic techniques were compared. Tests were made from decimal dilutions between 108 uf6.ml-1 and 102 ufc.mL-1 using a pure culture of 49b strain.The detection level obtained was 1.8 x 102 ufc.mL-1 using Inmunofluorescence; 1.8x104 ufc.mL-1 with indirect ELISA, 1.8 x 103 ufc.mL-1 by means of PCR; 10 ufc.mL-1 through of qRT P CR and 230 ufc.mL-1 in sour orange inoculated plants. The experiment was repeated at least three times for each technique. Considering this result, and taking into account that sensitivity, practicity and cost, are important when a great number of plants need to be tested, the PCR and inoculation in host plants were those that met the best characteristics to be evaluated in asymptomatic plant material

  14. Influence of operating parameters on electrocoagulation of C.I. disperse yellow 3

    Directory of Open Access Journals (Sweden)

    Djamel Ghernaout

    2014-12-01

    Full Text Available This work deals with the electrocoagulation (EC process for an organic dye removal. The chosen organic dye is C.I. disperse yellow 3 (DY which is used in textile industry. Experiments were performed in batch mode using Al electrodes and for comparison purposes Fe electrodes. The experimental set-up was composed of 1 L beaker, two identical electrodes which are separated 2 cm from each other. The main operating parameters influencing EC process were examined such as pH, supporting electrolyte concentration CNaCl, current density i, and DY concentration. High performance EC process was shown during 45 min for 200 mg/L dye concentration at i = 350 A m-2 (applied voltage 12 V and CNaCl = 1 g L-1 reaching 98 % for pHs 3 and 10 and 99 % for pH 6. After 10 min, DY was also efficiently removed (86 % showing that EC process may be conveniently applied for textile industry wastewater treatment. EC using Fe electrodes exhibited slightly lower performance comparing EC using Al electrodes.

  15. The role of journals in building up communities: the experience of Ciência em Tela

    Science.gov (United States)

    Martins, Isabel; de Souza Barros, Susana

    2015-12-01

    Ciência em Tela is an open access Brazilian science teacher education online journal that has been published twice a year since 2008 and which encourages the participation of professionals with different backgrounds and the submission of a variety of textual genres, besides research papers. Another feature is that the journal includes practicing schoolteachers not only as authors but also as reviewers, which not only provides those who submit contributions to the journal with an early feedback from their target audience but also helps empower schoolteachers by placing them in a discursive situation in which they are producers, as opposed to consumers, of discourses about science education. In this paper we describe the background to and main aspects of the journal's innovative editorial policy, which seeks to bridge gaps between communities and institutions linked to science education, as well as to discuss the challenges that arise from it, in particular, issues concerning internationalisation and funding, as well as the role of journals in times of colonisation and commodification of knowledge and of discourses.

  16. Sequence specificity of mutagenesis in the cI gene of bacteriophage lambda

    International Nuclear Information System (INIS)

    Skopek, T.R.; Wood, R.D.; Hutchinson, F.

    1985-01-01

    Studies of DNA base sequence alterations have shown that for every agent the mutagenic process is specific with respect to the types of base changes induced and the location of the changes in the DNA. Analysis of the types of mutations produced by mutagenic agents can provide insight into the mechanism of mutation and can suggest which DNA lesions may be involved in the actual mutagenic event. We have developed a system for the analysis of chemically induced base sequence alterations in the cI repressor gene of bacteriophage lambda using DNA sequencing techniques. To illustrate the utility of this type of analysis, we present the results obtained with ultraviolet light (UV). Irradiation of target DNA with UV alone, or UV followed by photoreactivating light (which removes dimers), produces mostly transitions at pyrimidine-pyrimidine sites. Conversely, irradiation with 313 nm light plus acetophenone (which produces only thymine dimers) produces mostly transversions at low efficiency. This and other evidence suggests that the actual premutagenic UV lesion in E. coli may not be pyrimidine-pyrimidine dimers, but rather pyr(6-4)pyo photoproducts

  17. Właściwości mechaniczne stopu AlSi7Mg modyfikowanego sodem

    Directory of Open Access Journals (Sweden)

    W. Orłowicz

    2008-03-01

    Full Text Available I'raca przcdstaivin ~vyniki bada6 wplywu rbwnoczcsncj mfinacji barbotahwvej argonem onz modyfikacji tytancm. horcm i sotlcm nnwtaci orw. rtydluknia. Na podsrawic badahstviedzono, ;r:c uzyskmn nfi wysokoSci od lcwu mikros~rutture rbknila sic parametrcrn strukturalnym kD o pnad 3 razy. El'chcm u6inicowancjrnikms!ruktury bylo zrrjinicuwanic wtaiciwoici mcchanicznych.

  18. PERFORMANCE AND EMISSION CHARACTERISTICS OF A CI ENGINE OPERATED ON VEGETABLE OILS AS ALTERNATIVE FUELS

    Directory of Open Access Journals (Sweden)

    K. Rajagopal

    2011-12-01

    Full Text Available An experimental analysis was done using a four-stroke, single cylinder, constant speed, water-cooled diesel engine, which was interfaced with Engine software. Performance and emission characteristics were evaluated for three non-edible vegetable oils, i.e. thumba, jojoba, neem oil, as well as jojoba methyl ester, to study the effect of injection pressure at 205, 220, 240 and 260 bar with a variation in injection timing at 23°bTDC and 28°bTDC. The performance of jojoba methyl ester improved with an increase in injection pressure. A maximum brake thermal efficiency of 29.72% was obtained with lower emissions compared to the other vegetable oils; this might be explained by low viscosity and better combustion. Further investigations were carried out with a new lubricant, SAE 5W-30, which improved the performance of the CI engine by 1.59%. All of the abovementioned investigations were fruitful and these results are expected to lead to substantial contributions in the development of a viable vegetable oil engine.

  19. Ciência & Saúde Coletiva: scientific production analysis and collaborative research networks.

    Science.gov (United States)

    Conner, Norma; Provedel, Attilio; Maciel, Ethel Leonor Noia

    2017-03-01

    The purpose of this metric and descriptive study was to identify the most productive authors and their collaborative research networks from articles published in Ciência & Saúde Coletiva between, 2005, and 2014. Authors meeting the cutoff criteria of at least 10 articles were considered the most productive authors. VOSviewer and Network Workbench technologies were applied for visual representations of collaborative research networks involving the most productive authors in the period. Initial analysis recovered 2511 distinct articles, with 8920 total authors with an average of 3.55 authors per article. Author analysis revealed 6288 distinct authors, 24 of these authors were identified as the most productive. These 24 authors generated 287 articles with an average of 4.31 authors per article, and represented 8 separate collaborative partnerships, the largest of which had 14 authors, indicating a significant degree of collaboration among these authors. This analysis provides a visual representation of networks of knowledge development in public health and demonstrates the usefulness of VOSviewer and Network Workbench technologies in future research.

  20. O Princípio da Euritmia nas Ciências Sociais e Humanas

    Directory of Open Access Journals (Sweden)

    Paulo Castro

    2017-02-01

    Full Text Available O Princípio da Euritmia é a afirmação de que os entes na natureza adoptam preferencialmente os comportamentos que preservam a sua integridade estrutural, estendendo a sua existência. Formulado no contexto de uma física não linear como alternativa ao paradigma de Niels Bohr, o Princípio surge como um dos desenvolvimentos fundamentais a partir das ideias de Louis de Broglie,  no âmbito da chamada  Escola de Lisboa. Reflecte-se sobre os conceitos de «Princípio», «Lei da Natureza» e «Emergência», tendo como objectivo estender o paradigma Eurítmico às Ciências Sociais e Humanas.  Propõe-se um processo dinâmico descrevendo as escolhas de um agente social de acordo com uma instanciação possível do Princípio. Usando uma simulação computacional desse processo, estudam-se os comportamentos  de  dois agentes sociais em interacção com o meio, entre si e com a totalidade do sistema que compõem. Define-se autómato não linear como conceito operativo fundamental no entendimento dos fenómenos de Emergência.

  1. A reconstrução da realidade nas Ciências Sociais

    Directory of Open Access Journals (Sweden)

    Florestan Fernandes

    2004-07-01

    Full Text Available Nota dos editores: O artigo "A reconstrução da realidade nas Ciências Sociais" foi publicado originalmente em duas partes. A primeira apareceu no número 82 da Revista Anhembi conforme a nota explicativa do texto. A segunda parte foi publicada no número 83 da mesma Revista, que saiu no mês de outubro de 1957. As duas partes do artigo foram publicadas como um capítulo do livro de Florestan Fernandes, "Fundamentos Empíricos da Explicação Sociológica", editado pela Cia. Ed. Nacional em 1959. A Editora Ática republicou o artigo completo no livro "Florestan Fernandes – Coleção Grandes Cientistas Sociais", organizado por Octavio Ianni em 1986. A Revista Mediações, mediante autorização, publica a primeira parte do artigo apresentado no número 82 da Revista Anhembi. As notas aparecem numeradas no texto entre parênteses.

  2. Do fabryki! Lenin Negriego i cięcie podmiotowe (1968-1973

    Directory of Open Access Journals (Sweden)

    Michael Hardt

    2016-06-01

    Full Text Available Tekst stanowi fragment doktoratu Michaela Hardta Sztuka organizacji: źródła ontologii politycznej u Gilles'a Deleuze'a i Antonio Negriego. Autor analizuje w nim dialog, jaki Antonio Negri podejmuje z pismami Włodzimierza Lenina w okresie intensywnych walk społecznych i przekształceń składu klasowego we Włoszech w latach 1968-1973. Doszukując się w tym spotkaniu kluczowego zwrotu teoretycznego w myśli włoskiego marksisty, Hardt przekonuje, że to właśnie w tekstach rosyjskiego rewolucjonisty Negri odnalazł narzędzia pozwalające mu wyjść poza ograniczenia krytycznego marksizmu, uznającego klasę robotniczą przede wszystkim za obiekt wyzysku, przez uczynienie kwestii jej podmiotowości centralnym zagadnieniem i punktem wyjścia teorii.

  3. Geneza reumatoidalnego zapalenia stawów a możliwości terapii

    Directory of Open Access Journals (Sweden)

    Stefan H. Mackiewicz

    2010-02-01

    Full Text Available Reumatoidalne zapalenie stawów należy do najbardziejzłożonych pod względem patogenetycznym chorób autoimmunologicznych.Czynniki (czynnik DR-β1 genetyczne i środowiskowestanowią o wrażliwości na chorobę. Nieznany mechanizm indukującypowoduje aktywację układu immunologicznego. Zakreszmian w różnych populacjach komórek i produkcja prozapalnychmediatorów chemicznych stwarza stan pewnego ,,chaosu biologicznego”.Kluczowe znaczenie ma derepresja genów w komórkachi przepływ sygnałów wewnątrz- i międzykomórkowych.Chorobę charakteryzuje bardzo indywidualny przebieg i nieprzewidywalnaodpowiedź na różne metody leczenia. Stosowane lekidziałają plejotropowo (metrotreksat – hamując proliferację aktywowanychkomórek bądź selektywnie na poszczególne elementyłańcucha patogenetycznego (antycytokiny.

  4. Studi Penerapan Inovasi Teknologi Informasi dengan Metode Technology Watch and Competitive Intelligent (Tw-Ci

    Directory of Open Access Journals (Sweden)

    Trisna Febriana

    2014-06-01

    Full Text Available The development of information technology creates a new way of many aspects in life. Innovations in this technology affect toward business environment, especially banking, which makes the business run dynamically. All of the transaction of a bank will be processed easily with the presence of computer. A bank needs all of the changes in order to compete with competitors, and that includes changes in information technology. The more expanding and complex facilities applied in a bank, the more complex and diverse technology adopted by a bank. The implementation of technology information in banking is not simple, it needs a long term planning and maintenance system so that all of the technology information facilities could run well and give a significant impact. Technology monitoring or benchmarking is one of the options that is taken by a bank to maintain its existence in facing the tight competition. To create technology innovation in banking need a monitoring technology method that is named TW-CI. This method is used to fulfill business needs in facing a competition to get and choose information that can be used to support a decision, so that the innovation applied by a bank is efficient and finally give an added value and also create entanglement between a bank and its consumer.

  5. Interaction between toxic azo dye C.I. Acid Red 88 and serum albumins

    International Nuclear Information System (INIS)

    Naveenraj, Selvaraj; Solomon, Rajadurai Vijay; Venuvanalingam, Ponnambalam; Asiri, Abdullah M.; Anandan, Sambandam

    2013-01-01

    Serum albumin-toxic dye interaction studies will be of paramount importance in the field of toxicology due to its relation towards the distribution and transportation of dye in blood. In this regard, the binding between C.I. Acid Red 88 (AR88) and serum albumins (HSA and BSA) was investigated by using combination of spectroscopic and molecular modeling methods. The fluorescence results revealed that AR88 interact with serum albumins through the combination of static and dynamic quenching mechanism. The distance “r” between serum albumin and AR88 was obtained according to the Forster resonance energy transfer (FRET) theory. Synchronous fluorescence and CD spectral results showed alterations in the microenvironment and conformation of serum albumins. The molecular docking method is also employed to understand the interaction of AR88 with serum albumins. All these studies confirm that BSA has more affinity towards AR88 than that of HSA which suggests that AR88 is more easily transported in the body of bovid than human and so it is more hazardous to bovids. -- Highlights: • AR88 interacts with serum albumin through the combination of both static and dynamic quenching mechanism. • The binding site of AR88 in serum albumins is nearer to tryptophan moiety. • Circular Dichroism spectra showed that AR88 alters α-helicity of serum albumin. • This interaction study could be greatly imperative for further investigations in toxicology

  6. The Cuatro Ciénegas Basin in Coahuila, Mexico: An Astrobiological Precambrian Park

    Science.gov (United States)

    Siefert, Janet L.; Escalante, Ana E.; Elser, James J.; Eguiarte, Luis E.

    2012-01-01

    Abstract The Cuatro Ciénegas Basin (CCB) is a rare oasis in the Chihuahuan Desert in the state of Coahuila, Mexico. It has a biological endemism similar to that of the Galapagos Islands, and its spring-fed ecosystems have very low nutrient content (nitrogen or phosphorous) and are dominated by diverse microbialites. Thus, it has proven to be a distinctive opportunity for the field of astrobiology, as the CCB can be seen as a proxy for an earlier time in Earth's history, in particular the late Precambrian, the biological frontier when prokaryotic life yielded at least partial dominance to eukaryotes and multicellular life. It is a kind of ecological time machine that provides abundant opportunities for collaborative investigations by geochemists, geologists, ecologists, and population biologists in the study of the evolutionary processes that structured Earth-based life, especially in the microbial realm. The CCB is an object of investigation for the identification of biosignatures of past and present biota that can be used in our search for extraterrestrial life. In this review, we summarize CCB research efforts that began with microbial ecology and population biology projects and have since been expanded into broader efforts that involve biogeochemistry, comparative genomics, and assessments of biosignatures. We also propose that, in the future, the CCB is sanctioned as a “Precambrian Park” for astrobiology. Key Words: Microbial mats—Stromatolites—Early Earth—Extremophilic microorganisms—Microbial ecology. Astrobiology 12, 641–647. PMID:22920514

  7. The Careful Puppet Master: Reducing risk and fortifying acceptance testing with Jenkins CI

    Science.gov (United States)

    Smith, Jason A.; Richman, Gabriel; DeStefano, John; Pryor, James; Rao, Tejas; Strecker-Kellogg, William; Wong, Tony

    2015-12-01

    Centralized configuration management, including the use of automation tools such as Puppet, can greatly increase provisioning speed and efficiency when configuring new systems or making changes to existing systems, reduce duplication of work, and improve automated processes. However, centralized management also brings with it a level of inherent risk: a single change in just one file can quickly be pushed out to thousands of computers and, if that change is not properly and thoroughly tested and contains an error, could result in catastrophic damage to many services, potentially bringing an entire computer facility offline. Change management procedures can—and should—be formalized in order to prevent such accidents. However, like the configuration management process itself, if such procedures are not automated, they can be difficult to enforce strictly. Therefore, to reduce the risk of merging potentially harmful changes into our production Puppet environment, we have created an automated testing system, which includes the Jenkins CI tool, to manage our Puppet testing process. This system includes the proposed changes and runs Puppet on a pool of dozens of RedHat Enterprise Virtualization (RHEV) virtual machines (VMs) that replicate most of our important production services for the purpose of testing. This paper describes our automated test system and how it hooks into our production approval process for automatic acceptance testing. All pending changes that have been pushed to production must pass this validation process before they can be approved and merged into production.

  8. Między pamięcią a zapomnieniem Shoah. Problem estetycznej neutralizacji przeszłości w myśleniu historycznym Saula Friedländera

    Directory of Open Access Journals (Sweden)

    Sawicki, Maciej

    2015-06-01

    Full Text Available W tekstach Saula Friedländera problem indywidualnej pamięci Shoahstanowił jedną z głównych granic dla dyskursu. Punktem krytycznym jego refleksji nad pamięcią stała się kwestia społecznego myślenia zbawczego, które stanowiło reakcję obronną wobec katastrofy. Fenomen ten ujawnił się szczególnie wyraźnie w publicznej formie pamięci, która z jednej strony domagała się prostoty i jasnej interpretacji, jako że jej zadaniem było oswojenie niekoherencji, wyeliminowanie bólu oraz rozbudzenie nadziei u współczesnych; z drugiej strony indywidualna pamięć głęboka ocalałych – nie znająca zasad – nie godziła się na formę pamięci publicznej, mimo że nie była w stanie jej się oprzeć. Według Friedländera ekspansja pamięci publicznej i zanikanie pamięci indywidualnej sprawia, iż "pamięć Shoah prawdopodobnie nie ucieknie przed całkowitą rytualizacją"1. W swoich rozważaniach częstokroć zwracał on uwagę na to, że sztuka nie może przeciwdziałać oswajaniu grozy, ponieważ musi wyrażać indywidualną pamięć przeszłości w pewnych prostych formach. Oprócz tego problematyczny stał się fakt, że same kategorie sztuki po Holokauście zostały zawładnięte przez przemysł kulturowy i politykę, przez co problem pamięci stał się środkiem przetargowym dla innych celów. Nawiązując za Friedländerem do aktualnego impasu wobec różnych oswajających mechanizmów pamięci, spróbuję poddać pod rozwagę kwestię granic i możliwości w tworzeniu estetycznego pomostu między teraźniejszością a przeszłością.

  9. A ciência e a tecnologia n’A Capital: da página de fait-divers à página de ciência

    OpenAIRE

    Fonseca, Rui Brito

    2009-01-01

    Durante muito tempo, a ciência e a tecnologia foram olhadas, pela população em geral, como mais um tema de entretenimento e curiosidade, a par de outros. Para a imprensa portuguesa, mormente a imprensa de cariz “popular”, a ciência e a tecnologia também foram durante algum tempo olhadas como um assunto de entretenimento e curiosidade. Partindo da análise, quantitativa e qualitativa, de cerca de 2000 artigos sobre ciência e tecnologia, publicados no jornal diário, pago e de c...

  10. Optimized preparation and preliminary evaluation of [64Cu]-DOTA-trastuzumab for targeting ErbB2/Neu expression

    International Nuclear Information System (INIS)

    Behrooz Alirezapour; Mohammad Javad Rasaee

    2013-01-01

    Breast cancer radioimmunoscintigraphy targeting HER2/neu expression is a growing field of work in nuclear medicine research. Trastuzumab is a monoclonal antibody that binds with high affinity to HER2/neu, which is over expressed on breast and other tumors. Developing new tracers for the detection of this cancer is of great interest. In this study, trastuzumab was successively labeled with [ 64 Cu]CuCl 2 after conjugation with DOTA-NHS-ester. The conjugate was purified by molecular filtration, the average number of DOTA conjugated per mAb was calculated and total concentration was determined by spectrophotometric method. DOTA-trastuzumab was labeled with 64 Cu produced by 68 Zn(p,αn) 64 Cu nuclear reaction (30 MeV protons at 180 μA). Radiochemical purity, integrity of protein after radiolabeling and immunoreactivity of radiolabeled mAb trastuzumab with HER2/neu antigen and SkBr3 cell line were performed by RIA. In vitro stability of radiolabeled mAb in human serum was determined by thin layer chromatography. In vitro internalization studies were performed with the SkBr3 cell line and the tissue biodistribution of the 64 Cu-DOTA-trastuzumab was evaluated in wild-type rat (90 ± 5.5 μCi, 2, 6, 12, 24 h p.i.). The radioimmunoconjugate was prepared with a radiochemical purity of higher than 96 ± 0.5 % (ITLC) and specific activity as high as 5.3 μCi/μg. The average number of chelators per antibody for the conjugate used in this study was 5.8/1. The sample was showed to have similar patterns of migration in the gel electrophoresis. The 64 Cu-DOTA-trastuzumab showed high immunoreactivity towards HER2/neu antigen and SkBr3 cell line. In vitro stability of the labeled product was found to be more than 94 % in PBS and 82 ± 0.5 % in human serum over 48 h. In vitro internalization studies of the 64 Cu-DOTA-trastuzumab showed that up to 11.5 % of the radioimmunoconjugate internalized after 10 h. The accumulation of the radiolabeled mAb in liver, skin, intestine, lung

  11. Density-functional study of the methoxy intermediates at Cu(111), Cu(110) and Cu(001) surfaces

    Czech Academy of Sciences Publication Activity Database

    Pick, Štěpán

    2010-01-01

    Roč. 22, č. 39 (2010), s. 395002 ISSN 0953-8984 Institutional research plan: CEZ:AV0Z40400503 Keywords : Cu surfaces * methoxy group CH3O- * physical chemistry Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.332, year: 2010

  12. Study of properties of Cu-Y and Cu-Y-Al system alloys

    International Nuclear Information System (INIS)

    Shparo, N.B.; Nikolaev, A.K.; Rozenberg, V.M.

    1978-01-01

    Investigated were the strength properties of alloys Cu(0-1.2)% Y and Cu-(10-0.5)% Al-(0-0.5)% Y after being treated under various heat conditions and tested at temperatures of 20, 400 and 600 deg C. Yttrium additions raise the temperature of recrystallization of copper and of copper-aluminium alloys. Small additions of yttrium (0.05%) increase considerably strength of Cu-Al alloys without increasing their electric resistance. Optimum properties are attained after hardening, deformation and ageing at 400 deg C

  13. Surface chemistry of 2-butanol and furfural on Cu, Au and Cu/Au single crystals

    OpenAIRE

    Megginson, Rory

    2016-01-01

    In this study, the adsorption of 2-butanol and furfural was investigated on Au (111), Cu (111) and Cu/Au (111) surfaces. It was hoped that by studying how these species adsorbed on these surfaces , insight would be provided into the roles of Cu and Au in the “hydrogen free” hydrogenation of furfural to furfuryl alcohol. This is a valuable process as currently furfuryl alcohol is derived from crude oil but it is possible to derive furfural from corn husk making it a greener process...

  14. Rytų baltų CiR tipo veiksmažodžiai

    Directory of Open Access Journals (Sweden)

    Dalia Pakalniškienė

    2011-12-01

    Full Text Available EASTERN BALTIC CiR TYPE VERBSSummaryThis article analyzes CiR type verbs in the Eastern Baltic languages and attempts to explain their origin and evolution. The criterion for inclusion as a subject for investigation – the root structure – allows for the discovery of general patterns in the history of verbs of the given structural type and the development of these verbs in the separate Baltic languages, and can provide a better definition of archaic features and innovations, because the root structure is closely related to the morphological structure and categorial semantics (especially in the Lithuanian language.According to various sources, there are approximately 30 CiR type verbs common to the Eastern Baltic languages (there are more in the Lithuanian language.In regard to morphological structure these are rather varied: a-stem, ia-stem, infix and sta-stem (the morphological structure also depends on the root final element: Cin are a-stem, Cir, Cil ia-stem or sto-stem, Cim are sta-stem.l. The largest group consists of infix and sta-stem verbs (15.1.1. The majority of these form diathetic pairs with ia-stem verbs (10. The categorial semantics of infix and sta-stem verbs – the mutative meaning – is opposed to the causative meaning of ia-stem verbs, e.g. Lith. bẽria / bỹra : Latv. ber̦u / bir̃stu. This opposition has not been documented in the Old Prussian language.1.2. Several of the verbs preserve Indo-European roots (5, but differ in morphological structure, these being infix and sta-stems or crossovers from a-stems, e.g.: Lith. mìršta : Latv. mir̃stu, Lith. gìmsta // gẽma : Latv. dzìmstu // dzemu.2. Only half as many ia-stem CiR type verbs have been discovered (7, e.g. Lith. skìria – skýrė : Latv. šķir̦u – šķîru.3. Eight Eastern Baltic a-stem verbs have CiR type roots.3.1. Mostly a-stem verbs with quantitative vowel changes were identified (6. In the Latvian language the preterite may occur without

  15. Soil solution dynamics of Cu and Zn in a Cu- and Zn-polluted soil as influenced by gamma-irradiation and Cu-Zn interaction.

    Science.gov (United States)

    Luo, Y M; Yan, W D; Christie, P

    2001-01-01

    A pot experiment was conducted to study soil solution dynamics of Cu and Zn in a Cu/Zn-polluted soil as influenced by gamma-irradiation and Cu-Zn interaction. A slightly acid sandy loam was amended with Cu and Zn (as nitrates) either singly or in combination (100 mg Cu and 150 mg Zn kg(-1) soil) and was then gamma-irradiated (10 kGy). Unamended and unirradiated controls were included, and spring barley (Hordeum vulgare L. cv. Forrester) was grown for 50 days. Soil solution samples obtained using soil moisture samplers immediately before transplantation and every ten days thereafter were used directly for determination of Cu, Zn, pH and absorbance at 360 nm (A360). Cu and Zn concentrations in the solution of metal-polluted soil changed with time and were affected by gamma-irradiation and metal interaction. gamma-Irradiation raised soil solution Cu substantially but generally decreased soil solution Zn. These trends were consistent with increased dissolved organic matter (A360) and solution pH after gamma-irradiation. Combined addition of Cu and Zn usually gave higher soil solution concentrations of Cu or Zn compared with single addition of Cu or Zn in gamma-irradiated and non-irradiated soils, indicating an interaction between Cu and Zn. Cu would have been organically complexed and consequently maintained a relatively high concentration in the soil solution under higher pH conditions. Zn tends to occur mainly as free ion forms in the soil solution and is therefore sensitive to changes in pH. The extent to which gamma-irradiation and metal interaction affected solubility and bioavailability of Cu and Zn was a function of time during plant growth. Studies on soil solution metal dynamics provide very useful information for understanding metal mobility and bioavailability.

  16. Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I–Cu(II Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand

    Directory of Open Access Journals (Sweden)

    Kenji Nakatani

    2015-04-01

    Full Text Available A new mixed-valence Cu(I–Cu(II 1D coordination polymer, [CuI4CuIIBr4(Cy2dtc2]n, with an infinite chain structure is synthesized by the reaction of Cu(Cy2dtc2 (Cy2dtc− = dicyclohexyl dithiocarbamate, C13H22NS2 with CuBr·S(CH32. The as-synthesized polymer consists of mononuclear copper(II units of CuII(Cy2dtc2 and tetranuclear copper(I cluster units, CuI4Br4. In the cluster unit, all the CuI ions have distorted trigonal pyramidal coordination geometries, and the CuI–CuI or CuI–CuII distances between the nearest copper ions are shorter than the sum of van der Waals radii for Cu–Cu.

  17. FUNKCJA SUM HARMONICZNYCH W SKRÓCONEJ PROCEDURZE OZNACZANIA ZESPOLONEGO MODUŁU SZTYWNOŚCI MMA

    Directory of Open Access Journals (Sweden)

    Andrzej POŻARYCKI

    2016-07-01

    Full Text Available W standardowej procedurze oznaczania sztywności mieszanek mineralno-asfalto-wych w funkcji częstotliwości obciążenia, powszechnie stosuje się metodę badań próbek obciążonych serią funkcji sinusoidalnych. W zależności od przyjętego wachlarza deklarowanych przez laboranta częstotliwości, procedura z serią badań stanowi procedurę inwazyjną, zwiększając jednocześnie prawdopodobieństwo wystąpienia zjawisk zmęczeniowych w badanych próbkach podczas realizowania testu. W pracy, w miejsce powszechnie stosowanej procedury zaproponowano obciążenie w formie funkcji utworzonej jako sumy funkcji harmonicznych. Na podstawie analizy wyników badań sztywności próbki belkowej wykazano, że proponowane podejście wyraźnie skraca czas procedury oznaczania zespolonego modułu sztywności, a różnice między standardowym ujęciem a tym proponowanym w pracy są w przeważającej większości mniejsze niż 2 %.

  18. Bioinformatic analysis of the distribution of inorganic carbon transporters and prospective targets for bioengineering to increase Ci uptake by cyanobacteria.

    Science.gov (United States)

    Gaudana, Sandeep B; Zarzycki, Jan; Moparthi, Vamsi K; Kerfeld, Cheryl A

    2015-10-01

    Cyanobacteria have evolved a carbon-concentrating mechanism (CCM) which has enabled them to inhabit diverse environments encompassing a range of inorganic carbon (Ci: [Formula: see text] and CO2) concentrations. Several uptake systems facilitate inorganic carbon accumulation in the cell, which can in turn be fixed by ribulose 1,5-bisphosphate carboxylase/oxygenase. Here we survey the distribution of genes encoding known Ci uptake systems in cyanobacterial genomes and, using a pfam- and gene context-based approach, identify in the marine (alpha) cyanobacteria a heretofore unrecognized number of putative counterparts to the well-known Ci transporters of beta cyanobacteria. In addition, our analysis shows that there is a huge repertoire of transport systems in cyanobacteria of unknown function, many with homology to characterized Ci transporters. These can be viewed as prospective targets for conversion into ancillary Ci transporters through bioengineering. Increasing intracellular Ci concentration coupled with efforts to increase carbon fixation will be beneficial for the downstream conversion of fixed carbon into value-added products including biofuels. In addition to CCM transporter homologs, we also survey the occurrence of rhodopsin homologs in cyanobacteria, including bacteriorhodopsin, a class of retinal-binding, light-activated proton pumps. Because they are light driven and because of the apparent ease of altering their ion selectivity, we use this as an example of re-purposing an endogenous transporter for the augmentation of Ci uptake by cyanobacteria and potentially chloroplasts.

  19. Atomic displacements due to interstitial hydrogen in Cu and Pd

    Indian Academy of Sciences (India)

    2015-11-27

    Nov 27, 2015 ... Atomic displacements; density functional theory; Kanzaki method. ... pseudopotentials for H, Cu and Pd are generated self-consistently. ... Both Cu and Pd lattices show lattice expansion due to the presence of hydrogen and ...

  20. Identification and Validation of Novel Hedgehog-Responsive Enhancers Predicted by Computational Analysis of Ci/Gli Binding Site Density

    Science.gov (United States)

    Richards, Neil; Parker, David S.; Johnson, Lisa A.; Allen, Benjamin L.; Barolo, Scott; Gumucio, Deborah L.

    2015-01-01

    The Hedgehog (Hh) signaling pathway directs a multitude of cellular responses during embryogenesis and adult tissue homeostasis. Stimulation of the pathway results in activation of Hh target genes by the transcription factor Ci/Gli, which binds to specific motifs in genomic enhancers. In Drosophila, only a few enhancers (patched, decapentaplegic, wingless, stripe, knot, hairy, orthodenticle) have been shown by in vivo functional assays to depend on direct Ci/Gli regulation. All but one (orthodenticle) contain more than one Ci/Gli site, prompting us to directly test whether homotypic clustering of Ci/Gli binding sites is sufficient to define a Hh-regulated enhancer. We therefore developed a computational algorithm to identify Ci/Gli clusters that are enriched over random expectation, within a given region of the genome. Candidate genomic regions containing Ci/Gli clusters were functionally tested in chicken neural tube electroporation assays and in transgenic flies. Of the 22 Ci/Gli clusters tested, seven novel enhancers (and the previously known patched enhancer) were identified as Hh-responsive and Ci/Gli-dependent in one or both of these assays, including: Cuticular protein 100A (Cpr100A); invected (inv), which encodes an engrailed-related transcription factor expressed at the anterior/posterior wing disc boundary; roadkill (rdx), the fly homolog of vertebrate Spop; the segment polarity gene gooseberry (gsb); and two previously untested regions of the Hh receptor-encoding patched (ptc) gene. We conclude that homotypic Ci/Gli clustering is not sufficient information to ensure Hh-responsiveness; however, it can provide a clue for enhancer recognition within putative Hedgehog target gene loci. PMID:26710299

  1. Concepções de ciência presentes na divulgação e prática de instituições não formais de ensino de ciências

    OpenAIRE

    Thayse Zambon Barbosa Aragão

    2013-01-01

    Esse trabalho tem como objetivo apresentar quais concepções de ciência estão presentes no discurso e prática de instituições de educação não formal. Para tanto investigaram-se quatro importantes instituições brasileiras integrantes deste universo, escolhidas a partir de indicações de seus pares: Museu da Vida (RJ), Espaço Ciência (PE), Museu de Ciência e Tecnologia da PUCRS (RS) e Estação Ciência (SP). Foram analisados os sites dessas instituições, utilizando-se como metodologia a análise ...

  2. As Ciências da Terra e a mundialização das sociedades

    Directory of Open Access Journals (Sweden)

    Umberto G. Cordani

    1995-12-01

    Full Text Available De acordo com os princípios da Agenda 21, o principal documento resultante da unced-92, a sociedade sustentável do futuro deverá mostrar um desenvolvimento econômico equilibrado, no mundo todo, em harmonia com os sistemas de suporte da vida, em nosso planeta. As Ciências da Terra têm um papel crucial, visto que elas têm a responsabilidade da busca e do gerenciamento dos recursos minerais e energéticos, da conservação, do gerenciamento dos solos e da água, do monitoramento contínuo dos processos dinâmicos do Sistema Terra e da prevenção e mitigação dos desastres naturais. Solidariedade social em nível global é necessária para o alcance futuro de uma sociedade sustentável realmente equitativa e preocupada com a justiça social. Entretanto, as tendências atuais da globalização, sob a égide dos grandes conglomerados transnacionais, são as de dar menor prioridade face a assuntos como preservação ambiental e desenvolvimento econômico do Terceiro Mundo. Tais tendências precisam ser invertidas, e os cientistas e profissionais das Ciências da Terra devem tornar-se proativos, em comunicar-se com políticos, educadores e o público em geral, no sentido de planejar adequadamente as atividades de desenvolvimento, evitando possíveis impactos desastrosos para o ambiente.Following the principles contained in the Agenda 21, the main agreement reached during the unced-92, the future sustainable society shall exhibit an equitable socio-economic development, all over the world, in harmony with the life support systems of our planet. The Earth sciences have a crucial role, because they have the responsibility of the search, provision and management of mineral and energetic resources, the conservation and management of soils and water, the continuous monitoring of the dynamic processes of the Earth system, and the prevention and mitigation of natural disasters. Solidarity among people is needed in order to achieve a truly equitable

  3. Perfil dos discentes ingressos do Centro de Ciências da Saúde UFPE

    Directory of Open Access Journals (Sweden)

    Ludmila Galindo França Gurgel

    Full Text Available A busca pelo conhecimento das características e da opinião dos estudantes do nível superior fornece importantes subsídios para o planejamento e reorganização do desenvolvimento acadêmico. Com o objetivo de traçar o perfil do aluno do Centro de Ciências da Saúde da Universidade Federal de Pernambuco (UFPE, foram distribuídos formulários aos acadêmicos do 2º período, contendo perguntas referentes aos seus aspectos socioeconômicos e pessoais. O perfil dos estudantes (n = 210 caracterizou-se por um predomínio feminino, com idades entre 19 e 21 anos, provenientes de escolas privadas e classes sociais economicamente mais favorecidas, que receberam grande influência do núcleo familiar na escolha da profissão. A maioria dos estudantes não estava matriculada nos cursos de primeira opção, porém possuía alta expectativa com relação ao curso, considerando-o correspondente às suas expectativas. Após formados pretendem realizar algum curso de pós-graduação e trabalhar no serviço público. No entanto, persiste um problema relativo à escolha da profissão, regulada pela condição socioeconômica e influência familiar.

  4. Reforms of a real estate cadastre in Poland / Reformy katastru nieruchomości w Polsce

    Science.gov (United States)

    Pietrzak, Ludmiła; Hopfer, Andrzej; Cegielski, Stanisław

    2012-11-01

    On May 7, 2010 the act dated March 4, 2010 on the spatial information infrastructure was published which transposes the European Parliament and the European Council Directive No 2007/2/WE dated March 14, 2007 established the spatial information infrastructure (INSPIRE) in the European Community. This act introduced basic changes to the binding Act, i.e. the Law of Geodesy and Cartography and, as the consequence, the demand to develop various administrative decrees occurred. The authors of the paper present the analysis of the existing conditions of the cadastre, the task of governmental and public government administration, related to demands concerning the cadastral reforms, following the act on the spatial information infrastructure and they discuss possibilities to perform such reforms at the local and national scales. W dniu 7 maja 2010 r. weszła w życie ustawa a dnia 4 marca 2012 r. o infrastrukturze informacji przestrzennej dokonująca transpozycji dyrektywy Parlamentu Europejskiego i Rady nr 2007/3/WE ustanawiającej infrastrukturę informacji przestrzennej w Europie. Ustawa to wprowadziła zasadnicze zmiany do obowiązującej ustawy prawo geodezyjne i kartograficzne, i w konsekwencji powstała konieczność opracowania nowych rozporządzeń wykonawczych. W chwili obecnej większość rozporządzeń jest już opracowana, część jest jeszcze konsultowana z organizacjami zawodowymi geodetów. W artykule autorzy dokonują analizy stanu istniejącego, zadań administracji rządowej i samorządowej związanych z koniecznością modernizacji katastru oraz podają zakres koniecznych do przeprowadzenie reform w skali kraju oraz w skali lokalnej.

  5. Prevalence of child abuse in school environment in Kerala, India: An ICAST-CI based survey.

    Science.gov (United States)

    Kumar, Manoj Therayil; Kumar, Sebind; Singh, Surendra P; Kar, Nilamadhab

    2017-08-01

    Very few studies focus on childhood abuse in developing countries and only a small fraction of such studies explicitly deal with abuse in a school environment. The purpose of this study was to estimate the prevalence of sexual, physical, and emotional abuse in a school environment in a developing country. Abuse history was collected using the International Society for the Prevention of Child Abuse and Neglect (ISPCAN) Child Abuse Screening Tool - Children's Institutional Version (ICAST-CI). Demographic variables were also collected. Student supportive measures were provided both during and after the survey. 6682 school attending adolescents in Thrissur, Kerala participated in this cross sectional self report study. One year and lifetime prevalence of physical (75.5%, 78.5%), emotional (84.5%, 85.7%) and sexual (21.0%, 23.8%) abuse was high. Abuse was considered to be present even if an individual item from these three categories was reported. Most abuse was reported as occurring 'sometimes' rather than 'many times'. More males than females reported being victims of abuse; figures for one-year prevalence were: physical abuse (83.4% vs. 61.7%), emotional abuse (89.5% vs. 75.7%), and sexual abuse (29.5% vs. 6.2%). Various factors significantly increase the likelihood of abuse-male gender, low socioeconomic status, regular use of alcohol and drugs by family member at home, and having other difficulties at school. Children tended to report abuse less frequently if they liked attending school and if they always felt safe at school. The results highlight the urgent need to address the issue of abuse in the school environment and minimize its impact. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Właściwości farmakologiczne i zastosowania kliniczne duloksetyny

    Directory of Open Access Journals (Sweden)

    Tomasz Sobów

    2015-12-01

    Full Text Available Duloksetyna jest lekiem z grupy selektywnych inhibitorów wychwytu zwrotnego serotoniny i noradrenaliny o bardziej zrównoważonym profilu farmakologicznego oddziaływania na transporter serotoninowy i noradrenergiczny niż powszechnie stosowana wenlafaksyna. W badaniach klinicznych udokumentowano jej skuteczność w leczeniu epizodów oraz zapobieganiu nawrotom depresji. Duloksetyna jest szczególnie interesującą opcją terapeutyczną u chorych depresyjnych z towarzyszącymi objawami bólowymi oraz lękowymi, została również przebadana w populacji chorych w wieku podeszłym. Poza leczeniem depresji lek może być stosowany w leczeniu uogólnionego zaburzenia lękowego, a poza psychiatrią także w leczeniu niektórych zaburzeń bólowych, zwłaszcza bolesnej neuropatii cukrzycowej. Choć w badaniach klinicznych weryfikowano kilka innych wskazań (takich jak fibromialgia, przewlekłe bóle pleców, bóle w przebiegu osteoarthritis czy wysiłkowe nietrzymanie moczu, nie mają one w Polsce statusu zarejestrowanych. Stosowanie duloksetyny nie wymaga podejmowania szczególnych środków ostrożności, z wyjątkiem pacjentów z chorobą alkoholową (lub innym uszkodzeniem wątroby, osób leczonych z powodu nadciśnienia tętniczego oraz chorych przyjmujących leki wpływające na hemostazę.

  7. Study for optimization of a 60 Co industrial irradiator of 250 k Ci

    International Nuclear Information System (INIS)

    Pina V, G.

    1995-01-01

    This work presents results of a benchmark between calculated and experimental absorbed dose values for a typical product, in a 60 Co industrial irradiator, located at ININ, Mexico. The goal of this work is to reach a ± 10 % approximation between both values. ININ 60 Co industrial irradiator is a two level, two layer system with overlapping product configuration, 56 irradiation positions with an activity of around 250 k Ci. Calculated values were obtained by QAD-CGGP code. This code uses a point kernel technique, build-up factors fitting was done by geometrical progression and combinatorial geometry was used for 3 D system description. Main code modifications were related with source simulation by punctual sources and energy spectrum (16 energy groups) and anisotropic emission were also considered. Experimental data were obtained from routine dosimetry which was done with red acrylic pellets; they were irradiated together the product in predetermined positions, for 36 maximum and minimum absorbed dose values. Typical product was polypropylene Petri dish packages, apparent density 0.13 g/cm 3 . It was chosen because regular geometry (2 packages per full irradiator container) and enough amount for considering homogeneous loading inside irradiation chamber. Required minimum dose was 15 kGy. Results showed a 8% variation between calculated and experimental values for maximum absorbed dose (18.2 kGy vs 16.8 kGy) and 3 % variation for minimum absorbed dose (13.8 kGy vs 14.3 kGy); these results fixed with the original proposal. (Author)

  8. Saberes docente para o ensino de ciências e biologia

    Directory of Open Access Journals (Sweden)

    Cibele Bender Raio

    2017-09-01

    Full Text Available Este trabalho apresenta os saberes que configuram um bom professor. Estes saberes, caracterizados pela mudança nos padrões de participação do professor na prática pedagógica, os quais não são construídos apenas durante o curso de formação inicial, mas sim ao longo da história de vida do educador. A partir dos conhecimentos de Paulo Freire e de Edgar Morin são sugeridos temas para possíveis práticas no ensino de ciências e de biologia. Dessa forma, uma educação em que o professor só deposita o conteúdo no aluno deve ser substituída por aquela que instiga a curiosidade, valoriza a opinião a sua opinião, considera seus sentimentos e promove a sua autonomia, ou seja, converte o educando em um agente transformador da sua própria realidade. Para isso, o professor precisa atuar com sentimentalidade, criticidade e autoridade, sem autoritarismo. Além disso, é papel do educador mostrar que não há conhecimento ileso ao erro ou a ilusão. Ele, também, precisa trabalhar o contexto local em relação a um conteúdo global. É um saber ensinar a condição do humano como unidade do universo e educar sobre a identidade terrena. Considerando, além disso, as incertezas dos acontecimentos e a ética humana. As discussões aqui apresentadas são sugestões para o desenvolvimento de práticas de ensino. No entanto, o professor deve elaborá-las de acordo com o seu ambiente de trabalho e seu público.

  9. Preferowanie podmiotów publicznych w niektórych rodzajach działalności gospodarczej

    OpenAIRE

    Sylwestrzak, Dorota

    2015-01-01

    Ustawodawca stwarza warunki zapewniające niedyskryminacyjne tratowanie podmiotów publicznych i prywatnych, ale zdarza się różnicowanie podmiotów, podyktowane zasadniczo przesłanką interesu publicznego i koniecznością ochrony wartości konstytucyjnych, Faworyzowanie podmiotów publicznych przejawia się głównie w zakresie stwarzania ułatwień w podejmowaniu działalności gospodarczej, w wyborze formy organizacyjno-prawnej, w której działalność gospodarcza może być prowadzona,...

  10. Fenomenologia e Ciência. Actas do IVº Congresso Internacional da AFFEN – IIIº Congresso Luso-Brasileiro de Fenomenologia

    OpenAIRE

    Borges-Duarte, Irene; Pardelha, Irene

    2014-01-01

    Este volume reune os textos apresentados ao IVº Congresso Internacional da AFFEN – IIIº Congresso Luso-Brasileiro de Fenomenologia, em 5 secções: Ciência, Técnica, Psicoterapia fenomenológica, Questões da Fenomenologia Husserliana e Outras fenomenologias. Tendo como temática unificadora «Fenomenologia e Ciência», integram-se trabalhos sobre aplicação da metodologia fenomenológica e hermenêutica às questões da ciência e da técnica, e a âmbitos científicos particulares como a Psicologia, a Soci...

  11. Inteligência Artificial, Tecnologias Informacionais E Seus Possíveis Impactos Sobre As Ciências Sociais

    OpenAIRE

    Dwyer T.

    2001-01-01

    Este artigo analisa algumas possibilidades de transformação das Ciências Sociais e, de maneira mais específica, na Sociologia, levantadas a partir do desenvolvimento e uso, nessas ciências, de tecnologias informacionais. Nas sociedades contemporâneas o aprofundamento do uso destas novas tecnologias pode trazer importantes conseqüências para as Ciências Sociais afetando, potencialmente, o ensino, a pesquisa e a construção de teoria. No Brasil podemos ver que um número crescente de informações ...

  12. Estudos cognitivos em ciência da informaçãoCognitive studies in information science

    Directory of Open Access Journals (Sweden)

    Gercina Ângela Borem de Oliveira Lima

    2003-05-01

    Full Text Available The study of the influences from Cognitive Sciences in the information Science. The Information Science has as objects of study the very basic concepts of information and knowledge. Since such concepts have an inherently trans-disciplinary character, the Information Science has been largely influenced by many disciplines, particularly the Cognitive Science. Regardless of this, it is observed that such concepts have not been properly discussed within the Information Science. To deal with this concern, it has been structured in the Escola de Ciência da Informação (ECI of the Universidade Federal de Minas Gerais (UFMG, a research group denoted “Cognitive Studies in Information Science”. This work aims to discuss the relationships between the Information Science and the Cognitive Science. In order to achieve this purpose, one formerly presents the major approaches within the Cognitive Science, contextualizing their aspects that mostly influence the Information Science, and then one discuss some perspectives for the future relationship of these two disciplines.O estudo da influência das Ciências Cognitivas na Ciência da Informação. A Ciência da Informação, que tem como objetos de estudo a informação e o conhecimento, discute-os sob vários pontos de vista, sendo um deles, o cognitivo. Observa-se que os conceitos não têm sido adequadamente discutidos à luz das Ciências Cognitivas, apesar da Ciência da Informação sofrer muitas influências daquela disciplina. Em função dessas questões, estruturou-se, na Escola de Ciência da Informação–ECI da Universidade Federal de Minas Gerais-UFMG, o Grupo de Pesquisa “Estudos Cognitivos em Ciência da Informação” – GECCI. Neste trabalho, marco inicial das discussões do grupo, tem-se o objetivo de discutir as relações da Ciência da Informação com as Ciências Cognitivas. Para melhor compreensão desse relacionamento, serão apresentadas as principais vertentes das ci

  13. Electroless deposition and electrical characterization of N- Cu 2 O ...

    African Journals Online (AJOL)

    This work describes the preparation of n-Cu2O layer by the electroless methods of boiling and immersion of copper plates in 0.001M CuSO4Electron Microscopy (SEM) have been used to characterize the oxide films deposited. XRD studies show, for the first time, that cuprous oxide (Cu2O) and cupric oxide (CuO) were ...

  14. Naród kontra lewactwo. Polityczne kategoryzacje rzeczywistości w folklorze internetowym

    Directory of Open Access Journals (Sweden)

    Michał Rauszer

    2016-01-01

    all features which exclude you from the community and your positive “national identity.”   Naród kontra lewactwo. Polityczne kategoryzacje rzeczywistości w folklorze internetowym W znanym eseju Dziecięca choroba lewicowości w komunizmie Lenin, na określenie naiwnej jego zdaniem polityki zachodnich partii komunistycznych, używa pojęcia „lievizna”. Zwykle tłumaczy się je jako „lewicowość”, termin ten jednak nie oddaje pogardy dla zachodnich partii komunistycznych, z jaką Lenin się o nich wypowiadał. W języku polskim wyraz ten był także niekiedy przekładany jako „lewactwo”, po to by służył ośmieszaniu działań niezgodnych z nomenklaturą Polskiej Zjednoczonej Partii Robotniczej (przykładem może być ruch ‘68 na Zachodzie. Współcześnie określenie „lewactwo” najczęściej jest używane w dyskursie ruchów prawicowych, aby pokazać każdy niezgodny z nimi projekt jako „dziecinny”. Wyrazem tym określa się nie tylko ruchy lewicowe, ale także wszystkie inne, które nie wpisują się w dyskurs prawicy narodowej. W swoim artykule staram się pokazać, w jaki sposób wyraz ten służy jako fantazmatyczna bariera, granica definiująca tożsamość narodową. Za materiał badawczy posłużył mi folklor internetowy taki, jak: memy, komentarze pod artykułami i zdjęciami, krótkie filmiki na portalu YouTube, a także oferta internetowych sklepów z odzieżą i gadżetami patriotycznymi (oferta tych sklepów jest ściśle oparta na takiej folklorystycznej interpretacji wydarzeń ujmowanych jako ważne. Pojęcie „lewactwa” funkcjonuje jako bariera wyznaczająca tożsamość narodową oraz jako przestrzeń fantazji. Ideologiczna praca tego pojęcia pokazuje, w jaki sposób w opozycji do tej bariery definiuje się i wyznacza pozytywny zbiór tego, co jest postrzegane jako „narodowe”, oraz tego, co „narodem” nie jest. Ponadto „lewactwo” jest także używane jako ekran fantazji, na której projektuje się cechy

  15. Cu(II) promotes amyloid pore formation

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Hangyu, E-mail: hangyuz@uw.edu [Weldon School of Biomedical Engineering, Purdue University, West Lafayette, IN 47907 (United States); Rochet, Jean-Christophe [Department of Medicinal Chemistry and Molecular Pharmacology, Purdue University, West Lafayette, IN 47907 (United States); Stanciu, Lia A. [Weldon School of Biomedical Engineering, Purdue University, West Lafayette, IN 47907 (United States); School of Materials Engineering, Purdue University, West Lafayette, IN 47907 (United States)

    2015-08-14

    The aggregation of α-synuclein is associated with dopamine neuron death in Parkinson's disease. There is controversy in the field over the question of which species of the aggregates, fibrils or protofibrils, are toxic. Moreover, compelling evidence suggested the exposure to heavy metals to be a risk of PD. Nevertheless, the mechanism of metal ions in promoting PD remains unclear. In this research, we investigated the structural basis of Cu(II) induced aggregation of α-synuclein. Using transmission electron microscopy experiments, Cu(II) was found to promote in vitro aggregation of α-synuclein by facilitating annular protofibril formation rather than fibril formation. Furthermore, neuroprotective baicalein disaggregated annular protofibrils accompanied by considerable decrease of β-sheet content. These results strongly support the hypothesis that annular protofibrils are the toxic species, rather than fibrils, thereby inspiring us to search novel therapeutic strategies for the suppression of the toxic annular protofibril formation. - Highlights: • Cu(II) promoted the annular protofibril formation of α-synuclein in vitro. • Cu(II) postponed the in vitro fibrillization of α-synuclein. • Neuroprotective baicalein disaggregated annular protofibrils.

  16. Cu(II) AND Zn(II)

    African Journals Online (AJOL)

    Preferred Customer

    SYNTHESIS OF 2,2-DIMETHYL-4-PHENYL-[1,3]-DIOXOLANE USING ZEOLITE. ENCAPSULATED Co(II), Cu(II) AND Zn(II) COMPLEXES. B.P. Nethravathi1, K. Rama Krishna Reddy2 and K.N. Mahendra1*. 1Department of Chemistry, Bangalore University, Bangalore-560001, India. 2Department of Chemistry, Government ...

  17. Cu(II) promotes amyloid pore formation

    International Nuclear Information System (INIS)

    Zhang, Hangyu; Rochet, Jean-Christophe; Stanciu, Lia A.

    2015-01-01

    The aggregation of α-synuclein is associated with dopamine neuron death in Parkinson's disease. There is controversy in the field over the question of which species of the aggregates, fibrils or protofibrils, are toxic. Moreover, compelling evidence suggested the exposure to heavy metals to be a risk of PD. Nevertheless, the mechanism of metal ions in promoting PD remains unclear. In this research, we investigated the structural basis of Cu(II) induced aggregation of α-synuclein. Using transmission electron microscopy experiments, Cu(II) was found to promote in vitro aggregation of α-synuclein by facilitating annular protofibril formation rather than fibril formation. Furthermore, neuroprotective baicalein disaggregated annular protofibrils accompanied by considerable decrease of β-sheet content. These results strongly support the hypothesis that annular protofibrils are the toxic species, rather than fibrils, thereby inspiring us to search novel therapeutic strategies for the suppression of the toxic annular protofibril formation. - Highlights: • Cu(II) promoted the annular protofibril formation of α-synuclein in vitro. • Cu(II) postponed the in vitro fibrillization of α-synuclein. • Neuroprotective baicalein disaggregated annular protofibrils

  18. Surface structure of AU3Cu(001)

    DEFF Research Database (Denmark)

    Eckstein, G.A.; Maupai, S.; Dakkouri, A.S.

    1999-01-01

    The surface morphology, composition, and structure of Au3Cu(001) as determined by scanning tunneling microscopy and surface x-ray diffraction are presented. Atomic resolution STM images reveal distinctive geometric features. The analysis of the surface x-ray diffraction data provides clear evidence...... for the surface structure. [S0163-1829(99)04535-X]....

  19. Operations and Performance of RHIC as a Cu-Cu Collider

    CERN Document Server

    Pilat, Fulvia Caterina; Bai, Mei; Barton, Donald; Beebe-Wang, Joanne; Blaskiewicz, Michael; Brennan, Joseph M; Bruno, Donald; Cameron, Peter; Connolly, Roger; De Long, Joseph; Drees, Angelika; Fischer, Wolfram; Ganetis, George; Gardner, Chris J; Glenn, Joseph; Harvey, Margaret; Hayes, Thomas; Hseuh Hsiao Chaun; Huang, Haixin; Ingrassia, Peter; Iriso, Ubaldo; Lee, Roger C; Litvinenko, Vladimir N; Luo, Yun; MacKay, William W; Marr, Gregory J; Marusic, Al; Michnoff, Robert; Montag, Christoph; Morris, John; Nicoletti, Tony; Oerter, Brian; Ptitsyn, Vadim; Roser, Thomas; Russo, Thomas; Sandberg, Jon; Satogata, Todd; Schultheiss, Carl; Tepikian, Steven; Tomas, Rogelio; Trbojevic, Dejan; Tsoupas, Nicholaos; Tuozzolo, Joseph; Vetter, Kurt; Zaltsman, Alex; Zeno, Keith; Zhang, S Y; Zhang, Wu

    2005-01-01

    The 5th year of RHIC operations, started in November 2004 and expected to last till June 2005, consists of a physics run with Cu-Cu collisions at 100 GeV/u followed by one with polarized protons at 100 GeV. We will address here overall performance of the RHIC complex used for the first time as a Cu-Cu collider, and compare it with previous operational experience with Au, PP and asymmetric d-Au collisions. We will also discuss operational improvements, such as a ?* squeeze to 85cm in the high luminosity interaction regions from the design value of 1m, system improvements and machine performance limitations, such as vacuum pressure rise, intra-beam scattering, and beam beam interaction.

  20. Computer simulations of nanoindentation in Mg-Cu and Cu-Zr metallic glasses

    DEFF Research Database (Denmark)

    Paduraru, Anca; Andersen, Ulrik Grønbjerg; Thyssen, Anders

    2010-01-01

    The formation of shear bands during plastic deformation of Cu0.50Zr0.50 and Mg0.85Cu0.15 metallic glasses is studied using atomic-scale computer simulations. The atomic interactions are described using realistic many-body potentials within the effective medium theory, and are compared with similar...... simulations using a Lennard-Jones description of the material. The metallic glasses are deformed both in simple shear and in a simulated nanoindentation experiment. Plastic shear localizes into shear bands with a width of approximately 5 nm in CuZr and 8 nm in MgCu. In simple shear, the shear band formation...... is very clear, whereas only incipient shear bands are seen in nanoindentation. The shear band formation during nanoindentation is sensitive to the indentation velocity, indenter radius and the cooling rate during the formation of the metallic glass. For comparison, a similar nanoindentation simulation...

  1. Thermodynamic analysis of the Cu2S-Cu2Te system using dissociation pressure data

    International Nuclear Information System (INIS)

    Glazov, V.M.; Pashinkin, A.S.; Burkhanov, A.S.; Saleeva, N.M.

    1978-01-01

    The Knudsen effusive method has been used for studying the dissociation pressure in the Cu 2 S-Cu 2 Te system, and on the basis of the experimental data obtained, the tellurium activity in the system and the mixing energy have been calculated. The dissociation pressure of pure components and alloys containing 10, 30, 50, 70, and 90 mol% of copper telluride within the temperature range of 750-1200 deg C has been studied. A smooth character of the concentration dependence of tellurium activity is observed, which points to the formation of a continuous series of solid solutions in the Cu 2 S-Cu 2 Te system within the temperature range studied. The data on the mixing energy in the system show a good agreement of the values obtained from the dissociation pressure with those determined from the fusibility diagram. The results indicate that the system in question is described well within the framework of the model of regular solutions

  2. The Y-Cu-Al system

    International Nuclear Information System (INIS)

    Krachan, T.; Stel'makhovych, B.; Kuz'ma, Yu.

    2003-01-01

    The phase diagram of the Y-Cu-Al system at 820 K has been constructed using X-ray powder diffraction. The existence of earlier known ternary aluminides has been confirmed and their homogeneity regions and atomic distributions in the structures have been determined: YCu 4.6-4.0 Al 7.4-8.0 (ThMn 12 -type R I =0.049), Y 2 Cu 12.0-10.5 Al 5.0-6.5 (Th 2 Zn 17 -type R I =0.092), YCu 1.0-1.1 Al 1.0-0.9 (Fe 2 P-type R I =0.068). It has been shown that the structure of Y(Cu,Al) 3 is characterized by an ordered distribution of the Cu and Al atoms and it should be referred as Ca 3 Cu 2 Al 7 structure type (R I =0.060) besides the PuNi 3 structure type with statistical occupancies of the smaller atoms. At the investigated temperature the compound YCu 1.0-0.25 Al 3.0-3.75 (BaAl 4 -type) was not observed. However, we found the ternary aluminide with composition Y 3 Cu 2.7-2.0 Al 8.3-9.0 and related La 3 Al 11 -type (space group Immm, a=0.4192-0.4228, b=1.2423-1.2557, c=0.9812-0.9895 nm, R I =0.069). The compounds YCu 6.8 Al 4.2 (space group Fddd, Tb(Cu 0.58 Al 0.42 ) 11 -type, a=1.42755, b=1.48587, c=0.65654 nm, R I =0.062) and YCu 6.5 Al 4.5 (space group I4 1 /amd, BaCd 11 -type, a=1.02774, c=0.65838 nm, R I =0.071) have been found and structurally refined for the first time

  3. Analysis on dynamic tensile extrusion behavior of UFG OFHC Cu

    Science.gov (United States)

    Park, Kyung-Tae; Park, Leeju; Kim, Hak Jun; Kim, Seok Bong; Lee, Chong Soo

    2014-08-01

    Dynamic tensile extrusion (DTE) tests with the strain rate order of ~105 s-1 were conducted on coarse grained (CG) Cu and ultrafine grained (UFG) Cu. ECAP of 16 passes with route Bc was employed to fabricate UFG Cu. DTE tests were carried out by launching the sphere samples to the conical extrusion die at a speed of ~475 m/sec in a vacuumed gas gun system. UFG Cu was fragmented into 3 pieces and showed a DTE elongation of ~340%. CG Cu exhibited a larger DTE elongation of ~490% with fragmentation of 4 pieces. During DTE tests, dynamic recrystallization occurred in UFG Cu, but not in CG Cu. In order to examine the DTE behavior of CG Cu and UFG Cu under very high strain rates, a numerical analysis was undertaken by using a commercial finite element code (LS-DYNA 2D axis-symmetric model) with the Johnson - Cook model. The numerical analysis correctly predicted fragmentation and DTE elongation of CG Cu. But, the experimental DTE elongation of UFG Cu was much smaller than that predicted by the numerical analysis. This difference is discussed in terms of microstructural evolution of UFG Cu during DTE tests.

  4. Synthesis and characterization of cupric oxide (CuO) nanoparticles ...

    African Journals Online (AJOL)

    In the present work, cupric oxide (CuO) nanoparticles (NPs) were prepared by adopting aqueous precipitation method using copper sulphate 5-hydrate as a precursor and NaOH as a stabilizing agent. This gives a large scale production of CuO-NPs which are utilized for the removal of methylene blue (MB) dye. The CuO ...

  5. Thermodynamic optimization of the Cu-Nd system

    International Nuclear Information System (INIS)

    Wang Peisheng; Zhou Liangcai; Du Yong; Xu Honghui; Liu Shuhong; Chen Li; Ouyang Yifang

    2011-01-01

    Research highlights: → The enthalpies of formation of the compounds Cu 6 Nd, Cu 5 Nd, Cu 2 Nd and αCuNd were calculated using DFT. → The thermodynamic constraints to eliminate the artificial phase relations were imposed during the thermodynamic optimization procedure. → The Cu-Nd system was optimized under the thermodynamic constraints. - Abstract: The thermodynamic constraints to eliminate artificial phase relations were introduced with the Cu-Nd system as an example. The enthalpies of formation of the compounds Cu 6 Nd, Cu 5 Nd, Cu 2 Nd and αCuNd are calculated using density functional theory. Taking into account all the experimental data and the first-principles calculated enthalpies of formation of these compounds, the thermodynamic optimization of the Cu-Nd system was performed under the proposed thermodynamic constraints. It is demonstrated that the thermodynamic constraints are critical to obtain a set of thermodynamic parameters for the Cu-Nd system, which can avoid the appearance of all the artificial phase relations.

  6. Wpływ regularnej aktywności fizycznej na skład ciała i ciśnienie tętnicze dzieci ze szkoły sportowej

    Directory of Open Access Journals (Sweden)

    Małgorzata Stańczyk

    2013-06-01

    Full Text Available Wstęp: Trening fizyczny uważany jest za czynnik wpływający na parametry antropometryczne i ciśnienie tęt‑ nicze. Twierdzi się, że osoby regularnie ćwiczące mają lepsze wskaźniki składu ciała oraz niższe wartości ciśnienia tętniczego krwi w porównaniu z osobami nieuprawiającymi sportu. Cel: Ocena wpływu regularnej rocznej aktywności fizycznej prowadzonej w szkole sportowej na skład ciała oraz wartości ciśnienia tętnicze‑ go u dzieci 14-letnich (II klasa gimnazjum. Materiał i metodyka: W badaniu wzięło udział 25 dzieci z gim‑ nazjum sportowego. Dzieci badano dwukrotnie w odstępie 12 miesięcy. Analizie poddano zmianę parame‑ trów antropometrycznych, składu ciała metodą impedancji bioelektrycznej oraz wartości ciśnienia krwi. Wyniki: W całej grupie zaobserwowano wzrost wartości centylowych ciśnienia skurczowego krwi (p < 0,05, przede wszystkim u chłopców. W zakresie ciśnienia rozkurczowego nie zanotowano istotnych różnic. Skład ciała zmienił się niekorzystnie u wszystkich badanych – wzrósł udział tłuszczu (13% vs 20%, p < 0,05, a przy‑ rost masy tłuszczowej był wyższy u dziewczynek (6% vs 3%, p < 0,05. Centyl BMI istotnie statystycznie wzrósł w grupie dziewczynek (37 vs 49, p < 0,05, u chłopców nie uległ zmianie. Wnioski: Aktywność fizyczna proponowana przez szkołę sportową nie poprawia stanu odżywienia 13–14-letnich dziewcząt i chłopców, u których obserwuje się istotne zwiększenie w organizmie zawartości tkanki tłuszczowej. Szkolna aktywność fizyczna nie powoduje obniżenia ciśnienia tętniczego wśród młodzieży w wieku 13–14 lat w odniesieniu do norm wiekowych. W zakresie ciśnienia skurczowego w grupie chłopców zaobserwowano nawet wyższe wartości centylowe.

  7. Local atomic structure of Zr-Cu and Zr-Cu-Al amorphous alloys investigated by EXAFS method

    International Nuclear Information System (INIS)

    Antonowicz, J.; Pietnoczka, A.; Zalewski, W.; Bacewicz, R.; Stoica, M.; Georgarakis, K.; Yavari, A.R.

    2011-01-01

    Research highlights: → Coordination number, interatomic distances and mean square atomic displacement in Zr-Cu and Zr-Cu-Al glasses. → Icosahedral symmetry in local atomic structure. → Deviation from random mixing behavior resulting from Al addition. - Abstract: We report on extended X-ray absorption fine structure (EXAFS) study of rapidly quenched Zr-Cu and Zr-Cu-Al glassy alloys. The local atomic order around Zr and Cu atoms was investigated. From the EXAFS data fitting the values of coordination number, interatomic distances and mean square atomic displacement were obtained for wide range of compositions. It was found that icosahedral symmetry rather than that of corresponding crystalline analogs dominates in the local atomic structure of Zr-Cu and Zr-Cu-Al amorphous alloys. Judging from bonding preferences we conclude that addition of Al as an alloying element results in considerable deviation from random mixing behavior observed in binary Zr-Cu alloys.

  8. Fabrication and tensile properties of rapidly solidified Cu-10wt. %Ni alloy. [Cu-10Ni

    Energy Technology Data Exchange (ETDEWEB)

    Baril, D; Angers, R; Baril, J [Dept. of Mining and Metallurgy, Laval Univ., Ste-Foy, Quebec (Canada)

    1992-10-15

    Cu-10wt.%Ni ribbons were produced by melt spinning and cut into small particles with a blade cutter mill. The powders were then hot consolidated to full density by hot pressing followed by hot extrusion. Tensile properties of the resulting pieces were measured. Cu-10wt.%Ni cast ingots were also hot extruded and mechanically tested to compare with the rapidly solidified alloy and to evaluate the possible benefits brought by the rapid solidification process.

  9. Damage behavior of SnAgCu/Cu solder joints subjected to thermomechanical cycling

    Energy Technology Data Exchange (ETDEWEB)

    Xiao, H., E-mail: xiaohui2013@yahoo.com.cn; Li, X.Y.; Hu, Y.; Guo, F.; Shi, Y.W.

    2013-11-25

    Highlights: •A creep–fatigue damage model based on CDM was proposed. •Designed system includes load frame, strain measure device and damage test device. •Damage evolution of solder joints was a function of accumulated inelastic strain. •Damage of solder joints is an interaction between creep and low-cycle fatigue. -- Abstract: Thermomechanical fatigue damage is a progressive process of material degradation. The objective of this study was to investigate the damage behavior of SnAgCu/Cu solder joints under thermomechanical cycling. A damage model was proposed based on continuum damage mechanics (CDM). Based upon an analysis of displacements for flip-chip solder joints subjected to thermal cycling, a special bimetallic loading frame with single-solder joint samples was designed to simulate the service conditions of actual joints in electronic packages. The assembly, which allowed for strain measurements of an individual solder joint during temperature cycling, was used to investigate the impact of stress–strain cycling on the damage behavior of SnAgCu/Cu solder joints. The characteristic parameters of the damage model were determined through thermomechanical cycling and strain measurement tests. The damage variable D = 1 − R{sub 0}/R was selected, and values for it were obtained using a four-probe method for the single-solder joint samples every dozen cycles during thermomechanical cycling tests to verify the model. The results showed that the predicted damage was in good agreement with the experimental results. The damage evolution law proposed here is a function of inelastic strain, and the results showed that the damage rate of SnAgCu/Cu solder joints increased as the range of the applied strain increased. In addition, the microstructure evolution of the solder joints was analyzed using scanning electron microscopy, which provided the microscopic explanation for the damage evolution law of SnAgCu/Cu solder joints.

  10. Damage behavior of SnAgCu/Cu solder joints subjected to thermomechanical cycling

    International Nuclear Information System (INIS)

    Xiao, H.; Li, X.Y.; Hu, Y.; Guo, F.; Shi, Y.W.

    2013-01-01

    Highlights: •A creep–fatigue damage model based on CDM was proposed. •Designed system includes load frame, strain measure device and damage test device. •Damage evolution of solder joints was a function of accumulated inelastic strain. •Damage of solder joints is an interaction between creep and low-cycle fatigue. -- Abstract: Thermomechanical fatigue damage is a progressive process of material degradation. The objective of this study was to investigate the damage behavior of SnAgCu/Cu solder joints under thermomechanical cycling. A damage model was proposed based on continuum damage mechanics (CDM). Based upon an analysis of displacements for flip-chip solder joints subjected to thermal cycling, a special bimetallic loading frame with single-solder joint samples was designed to simulate the service conditions of actual joints in electronic packages. The assembly, which allowed for strain measurements of an individual solder joint during temperature cycling, was used to investigate the impact of stress–strain cycling on the damage behavior of SnAgCu/Cu solder joints. The characteristic parameters of the damage model were determined through thermomechanical cycling and strain measurement tests. The damage variable D = 1 − R 0 /R was selected, and values for it were obtained using a four-probe method for the single-solder joint samples every dozen cycles during thermomechanical cycling tests to verify the model. The results showed that the predicted damage was in good agreement with the experimental results. The damage evolution law proposed here is a function of inelastic strain, and the results showed that the damage rate of SnAgCu/Cu solder joints increased as the range of the applied strain increased. In addition, the microstructure evolution of the solder joints was analyzed using scanning electron microscopy, which provided the microscopic explanation for the damage evolution law of SnAgCu/Cu solder joints

  11. Massive spalling of Cu-Zn and Cu-Al intermetallic compounds at the interface between solders and Cu substrate during liquid state reaction

    Science.gov (United States)

    Kotadia, H. R.; Panneerselvam, A.; Mokhtari, O.; Green, M. A.; Mannan, S. H.

    2012-04-01

    The interfacial intermetallic compound (IMC) formation between Cu substrate and Sn-3.8Ag-0.7Cu-X (wt.%) solder alloys has been studied, where X consists of 0-5% Zn or 0-2% Al. The study has focused on the effect of solder volume as well as the Zn or Al concentration. With low solder volume, when the Zn and Al concentrations in the solder are also low, the initial Cu-Zn and Al-Cu IMC layers, which form at the solder/substrate interface, are not stable and spall off, displaced by a Cu6Sn5 IMC layer. As the total Zn or Al content in the system increases by increasing solder volume, stable CuZn or Al2Cu IMCs form on the substrate and are not displaced. Increasing concentration of Zn has a similar effect of stabilizing the Cu-Zn IMC layer and also of forming a stable Cu5Zn8 layer, but increasing Al concentration alone does not prevent spalling of Al2Cu. These results are explained using a combination of thermodynamic- and kinetics-based arguments.

  12. Cu-capped surface alloys of Pt/Cu left brace 100 right brace

    CERN Document Server

    Alshamaileh, E; Wander, A

    2003-01-01

    The room-temperature deposition of 0.5 monolayer (ML) Pt on Cu left brace 100 right brace followed by annealing to 525 K results in a sharp c(2 x 2) low-energy electron diffraction (LEED) pattern. The structure of this surface alloy is investigated by means of symmetrized automated tensor low-energy electron diffraction (SATLEED) analysis and ab initio plane wave density functional calculations. The results are then compared with those for the similar system 0.5 ML Pd/Cu left brace 100 right brace. SATLEED results for the Pt/Cu left brace 100 right brace show that it consists of an ordered c(2 x 2) Cu-Pt second layer alloy capped with a pure Cu first layer. The first and second interlayer spacings are found to be expanded by +5.1 +- 1.7 and +3.5 +- 1.7% respectively (relative to the bulk Cu interlayer spacing of 1.807 A) due to the insertion of the 8% larger Pt atoms into the second layer. The ordered mixed layer is found to be rippled by 0.08 +- 0.06 A with Pt atoms rippled outwards towards the solid-vacuum ...

  13. Room temperature Cu-Cu direct bonding using surface activated bonding method

    International Nuclear Information System (INIS)

    Kim, T.H.; Howlader, M.M.R.; Itoh, T.; Suga, T.

    2003-01-01

    Thin copper (Cu) films of 80 nm thickness deposited on a diffusion barrier layered 8 in. silicon wafers were directly bonded at room temperature using the surface activated bonding method. A low energy Ar ion beam of 40-100 eV was used to activate the Cu surface prior to bonding. Contacting two surface-activated wafers enables successful Cu-Cu direct bonding. The bonding process was carried out under an ultrahigh vacuum condition. No thermal annealing was required to increase the bonding strength since the bonded interface was strong enough at room temperature. The chemical constitution of the Cu surface was examined by Auger electron spectroscope. It was observed that carbon-based contaminations and native oxides on copper surface were effectively removed by Ar ion beam irradiation for 60 s without any wet cleaning processes. An atomic force microscope study shows that the Ar ion beam process causes no surface roughness degradation. Tensile test results show that high bonding strength equivalent to bulk material is achieved at room temperature. The cross-sectional transmission electron microscope observations reveal the presence of void-free bonding interface without intermediate layer at the bonded Cu surfaces

  14. Prognozowanie i ujmowanie przychodóww przedsiębiorstwie postawionymw stan upadłości likwidacyjnej

    OpenAIRE

    Janusz Czerny

    2010-01-01

    W upadłości likwidacyjnej przedsiębiorstw mamy do czynienia z dwoma stru-mieniami przychodów, a mianowicie z przychodami dotyczącymi zbycia przedsię-biorstwa lub jego składników majątku oraz z przychodami związanymi z ewentual-nym kontynuowaniem działalności: Przychody ze sprzedaży przedsiębiorstwa powinny być prognozowane głównie na podstawie informacji płynących z systemu rachunkowości, co stanowi tzw. sta-tyczny aspekt upadłości, natomiast jej aspekt dynamiczny jest związany z zakre-sem...

  15. In-cylinder visualization and engine out emissions from CI to PPC for fuels with different properties

    KAUST Repository

    An, Yanzhao; Vallinayagam, R.; Vedharaj, S.; Masurier, Jean-Baptiste; Najafabadi, Mohammad Izadi; Somers, Bart; Johansson, Bengt

    2018-01-01

    This study investigated the transition from conventional Compression Ignition (CI) to Partially Premixed Combustion (PPC) in an optical engine for fuels with differing properties. Combustion stratification and emissions were measured with diesel

  16. Effects of Cu content on the photoelectrochemistry of Cu2ZnSnS4 nanocrystal thin films

    International Nuclear Information System (INIS)

    Khoshmashrab, Saghar; Turnbull, Matthew J.; Vaccarello, Daniel; Nie, Yuting; Martin, Spencer; Love, David A.; Lau, Po K.; Sun, Xuhui; Ding, Zhifeng

    2015-01-01

    Highlights: • Two compositions of CZTS were synthesized, one yielding Cu-poor and the other Cu-stoichiometric nanocrystals (NCs). • Physical and electronic properties of both films were probed using various analytical techniques. • Films comprised of Cu-poor CZTS showed tighter packing with less defects compared to those of stoichiometric-Cu. • Photoelectrochemical measurements exhibited increased photoconversion and increased photostability of the Cu-poor films. • Intensity modulated photocurrent spectroscopy showed that the Cu-deficient NCs had half the recombination rate as that of stoichiometric-Cu films. - Abstract: Cu 2 ZnSnS 4 (CZTS) nanocrystals (NCs) were prepared via a one-pot solvothermal method. Given that the composition affects the electronic properties of this p-type semiconductor, two compositional ratios were chosen from 10 designed and synthesized analogues, one yielding Cu-poor and the other Cu-stoichiometric CZTS. NCs in which the Cu concentration was slightly below stoichiometric yielded more uniform films with greater photovoltaic performance. The lower Cu content also lead to slightly better crystallinity within the film, as demonstrated by XRD, Raman spectroscopy and transmission electron microscopy. Chronophotoelectrochemical measurements indicated that both types of NC films displayed good stability; however, with a decrease in potential, an increase in resistance for the Cu-stoichiometric film was observed. As determined by intensity modulated photocurrent spectroscopy, the product separation rate of the photoinduced holes and electrons in the Cu-poor films were more than 3 times that of the Cu-stoichiometric, confirming that the lower Cu content led to an improved photoperformance

  17. Engineering of a genetically encodable fluorescent voltage sensor exploiting fast Ci-VSP voltage-sensing movements.

    Science.gov (United States)

    Lundby, Alicia; Mutoh, Hiroki; Dimitrov, Dimitar; Akemann, Walther; Knöpfel, Thomas

    2008-06-25

    Ci-VSP contains a voltage-sensing domain (VSD) homologous to that of voltage-gated potassium channels. Using charge displacement ('gating' current) measurements we show that voltage-sensing movements of this VSD can occur within 1 ms in mammalian membranes. Our analysis lead to development of a genetically encodable fluorescent protein voltage sensor (VSFP) in which the fast, voltage-dependent conformational changes of the Ci-VSP voltage sensor are transduced to similarly fast fluorescence read-outs.

  18. 40 CFR 721.9662 - Thieno[3,4-b]-1,4-dioxin, 2,3-dihydro- (9CI).

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Thieno[3,4-b]-1,4-dioxin, 2,3-dihydro... Specific Chemical Substances § 721.9662 Thieno[3,4-b]-1,4-dioxin, 2,3-dihydro- (9CI). (a) Chemical...-b]-1,4-dioxin, 2,3-dihydro- (9CI) (PMN P-95-1825; CAS No. 126213-50-1) is subject to reporting under...

  19. Endo-referência de uma ciência formalizada da natureza

    Directory of Open Access Journals (Sweden)

    Michel Paty

    1992-04-01

    Full Text Available O trabalho desenvolve as implicações da idéia de que quando uma teoria atinge um estágio abstrato de formalização, como é o caso de teorias físicas, da mecânica quântica, o significado de seus conceitos e proposições, objetivos para representação e inteligibilidade do mundo físico (realidade física em qualquer de suas acepções é obtido a partir da própria teoria. Em síntese, "é a própria que dita o significado de suas proposições", segundo Einstein e Heisenberg. Em seguida apresenta uma análise do significado de 'teoria formalizada' para o caso das ciências de conteúdo empírico como a física, concluindo que a acepção adotada não pode ser reduzida a um 'formalismo interpretado' nos moldes aceitos pelos elementos do Círculo de Viena. Aspectos dinâmicos das teorias são também discutidos. Finalmente, a partir das considerações acima, é introduzido o conceito de 'endo-referência' e discutidas as suas conexões com o conceito kantiano de sintético a priori.The paper develops epistemological implications of the idea that, when a theory is in state of abstract formalization (as to-day physical theory, quantum physics for instance is, the meaning of its concepts and propositions, which are aiming at the representation and intelligibility of the external physical world is however to be taken from within the theory itself. " It is the theory itself which dictates the physical significance of its propositions" in the words of Heisenberg and Einstein. It contains also the analysis of what is meant by " formalized theory" for a science with empirical content as physics and concludes that it cannot be reduced to a mere "interpreta formalism" in the sense of logical impiricism. Finaly it works on the sense of endoreference connctions with a kantian concept of a priori synthetic.

  20. Cloning and Functional Analysis of the MADS-box CiMADS9 Gene from Carya illinoinensis

    Directory of Open Access Journals (Sweden)

    Zhang Jiyu

    2015-07-01

    Full Text Available A MADS-box gene, CiMADS9, was cloned from the male flowers of Carya illinoinensis by rapid amplification of cDNA ends. The gene was 1 077 bp with a 768 bp open reading frame encoding 255 amino acids. Multiple sequence comparisons revealed that CiMADS9 is a typical MIKC-type MADS-box gene with a MADS-box domain and a K semi-conserved region. Phylogenetic analysis indicated that CiMADS9 belongs to the AGL15 group of the MADS-box gene family. Quantitative reverse transcription polymerase chain reaction analysis indicated that the expression levels in reproductive organs (i.e., flowers and young fruits were considerably higher than in vegetative tissues (i.e., leaves and branches. The highest expression levels were observed in male flowers. An overexpression vector for CiMADS9 was constructed and the gene was inserted into the Arabidopsis thaliana genome. CiMADS9 expression was confirmed in all transgenic lines. Compared with wild-type plants, transgenic A. thaliana plants overexpressing CiMADS9 exhibited delayed flowering and an increased number of leaves.