WorldWideScience

Sample records for monofilament clean-up project

  1. Project strategy for clean-up of sedimentary radioactive material in Fukushima bay areas using snake-like robotics

    Directory of Open Access Journals (Sweden)

    Cho Hyo Sung

    2015-01-01

    Full Text Available The snake-like robot is used for clean-up project in Fukushima nuclear disaster site. The contaminated water at the Fukushima Daiichi nuclear power plants has been purified by the water treatment system, called Advanced Liquid Processing System, co-developed by Japanese and international technologies. The system is used to remove most remaining radioactive contaminants in water that had to be stored at the facility. In this paper, a snake-like robot, incorporated with Advanced Liquid Processing System is introduced for the severe accident in the nuclear power plants in which human cannot control the cleaning-up in the sea where the radioactive materials have been submerged and some resolved in the sea water. The effective strategy of the cleaning-up is analyzed from the environmental protection aspect with the snake's biomechanics and radioactive hazards.

  2. Pollute first, clean up later?

    NARCIS (Netherlands)

    Azadi, Hossein; Verheijke, Gijs; Witlox, Frank

    2011-01-01

    There is a growing concern with regard to sustainability in emerging economies like China. The Chinese growth is characterized by a strategy which is known as "pollute first, clean up later". Here we show that based on this strategy, the pollution alarm can often be postponed by a tremendous economi

  3. 48 CFR 36.512 - Cleaning up.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 1 2010-10-01 2010-10-01 false Cleaning up. 36.512... CONTRACTING CONSTRUCTION AND ARCHITECT-ENGINEER CONTRACTS Contract Clauses 36.512 Cleaning up. The contracting officer shall insert the clause at 52.236-12, Cleaning Up, in solicitations and contracts when a...

  4. Cleaning up the Nalon, Caudal and Nora rivers: FEDER provide 1,000 million pesetas for the HUNOSA project. Saneamiento de los rios Nalon, Caudal y Nora. El FEDER aporta mil millones para un proyecto de HUNOSA

    Energy Technology Data Exchange (ETDEWEB)

    1990-09-01

    The Commission of the European Communities has recently approved aid from FEDER (European Regional Development Fund) for the HUNOSA project 'Cleaning discharge into public waterways from HUNOSA's coal washeries' to the value of 1,000 million pesetas. This is the maximum grant available from the Fund and equates to 45% of the total investment, estimated at 2,200 million pesetas. The project has been organised and carried out by HUNOSA and involves cleaning up the Nalon, Caudal and Nora rivers between 1990 and 1992. The project also includes a comprehensive study of the six washeries contributing to the pollution of the rivers and will apply to each the cheapest and most viable solution from an operational standpoint. 1 fig.

  5. Radioactive Waste and Clean-up: Introduction

    Energy Technology Data Exchange (ETDEWEB)

    Collard, G

    2000-07-01

    SCK-CEN's Radioactive Waste and Clean-up Division performs studies and develops strategies, techniques and technologies in the area of radioactive waste management, the decontamination and decommissioning of nuclear installations and the remediation of radioactive-contaminated sites. These activities are performed in the context of our responsibility towards the safety of present and future generations and contribute to achieve intrageneration equity.

  6. Rodent Control: Seal Up! Trap Up! Clean Up!

    Science.gov (United States)

    ... rodent food sources and nesting sites... Diseases from rodents Diseases directly transmitted by rodents Diseases indirectly transmitted by rodents Cleaning up after rodents Take precautions before and during clean up of ...

  7. 48 CFR 52.236-12 - Cleaning Up.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 2 2010-10-01 2010-10-01 false Cleaning Up. 52.236-12 Section 52.236-12 Federal Acquisition Regulations System FEDERAL ACQUISITION REGULATION (CONTINUED... Cleaning Up. As prescribed in 36.512, insert the following clause: Cleaning Up (APR 1984) The...

  8. Cockroaches probably cleaned up after dinosaurs.

    Science.gov (United States)

    Vršanský, Peter; van de Kamp, Thomas; Azar, Dany; Prokin, Alexander; Vidlička, L'ubomír; Vagovič, Patrik

    2013-01-01

    Dinosaurs undoubtedly produced huge quantities of excrements. But who cleaned up after them? Dung beetles and flies with rapid development were rare during most of the Mesozoic. Candidates for these duties are extinct cockroaches (Blattulidae), whose temporal range is associated with herbivorous dinosaurs. An opportunity to test this hypothesis arises from coprolites to some extent extruded from an immature cockroach preserved in the amber of Lebanon, studied using synchrotron X-ray microtomography. 1.06% of their volume is filled by particles of wood with smooth edges, in which size distribution directly supports their external pre-digestion. Because fungal pre-processing can be excluded based on the presence of large particles (combined with small total amount of wood) and absence of damages on wood, the likely source of wood are herbivore feces. Smaller particles were broken down biochemically in the cockroach hind gut, which indicates that the recent lignin-decomposing termite and cockroach endosymbionts might have been transferred to the cockroach gut upon feeding on dinosaur feces.

  9. Comparison of Piezoresistive Monofilament Polymer Sensors

    Directory of Open Access Journals (Sweden)

    Mark Melnykowycz

    2014-01-01

    Full Text Available The development of flexible polymer monofilament fiber strain sensors have many applications in both wearable computing (clothing, gloves, etc. and robotics design (large deformation control. For example, a high-stretch monofilament sensor could be integrated into robotic arm design, easily stretching over joints or along curved surfaces. As a monofilament, the sensor can be woven into or integrated with textiles for position or physiological monitoring, computer interface control, etc. Commercially available conductive polymer monofilament sensors were tested alongside monofilaments produced from carbon black (CB mixed with a thermo-plastic elastomer (TPE and extruded in different diameters. It was found that signal strength, drift, and precision characteristics were better with a 0.3 mm diameter CB/TPE monofilament than thick (~2 mm diameter based on the same material or commercial monofilaments based on natural rubber or silicone elastomer (SE matrices.

  10. 40 CFR 263.31 - Discharge clean up.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Discharge clean up. 263.31 Section 263.31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED... up. A transporter must clean up any hazardous waste discharge that occurs during transportation...

  11. Head to Toe Clean-Up

    Institute of Scientific and Technical Information of China (English)

    Li Li

    2013-01-01

    Concerted effort to rectify extravagance and corruption begins within Party's national leadership Since their election at the 18th National Congress of the Communist Party of China(CPC) last November,the new leaders of the CPC have engaged in projects to raise public satisfaction by fighting corruption,bringing leaders closer to

  12. Clean Up, Rehabilitation, Resettlement of Enewetak Atoll -Marshall Islands. Volume III.

    Science.gov (United States)

    The documentation is a summary of the Draft Environmental Impact Statement (DEIS) for a proposed project to clean up the Atoll of Enewetak and...resettle the Enewetak people on the Atoll . The summary has been prepared specifically for translation into the language of the Enewetak people.

  13. Clorox cleans up its light quality

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    2009-01-15

    Clorox Canada introduced a new lighting solution at its 300,000 square foot distribution centre in an effort to upgrade its energy management practices. High pressure sodium lamps were replaced with six-lamp T-8 high bay fixtures supplied by Nexstar Lighting. Light sensors were installed so that side aisles would only be lit when needed. Both cost savings and light quality were taken into account. The retrofit reduced energy use by 51 per cent and light levels were improved considerably. The payback period was 1.2 years for the entire project. In addition, maintenance costs are expected to decrease as the expected service life of a T-8 fixture is about 8 years. 2 figs.

  14. Continuous Sputter Deposition Coating of Long Monofilaments

    Science.gov (United States)

    2014-04-01

    of the monofilament, a narrow channel with a thin outer wall of copper would remain. That channel would be open for fluid flow, and also have a...Hart, S. D.; Benoit, G.; Kuriki, Y.; Viens, J. F.; Bayindir, M.; Joannopoulos, J. D.; Fink, Y. Hollow Multilayer Photonic Bandgap Fibers for NIR...strips of silicon were placed 0.4 in (1 cm) below the monofilament and later tested with Rutherford Backscattering Spectroscopy to measure the thickness

  15. Chlorine dioxide project allows Stora to clean up, use hardwoods

    Energy Technology Data Exchange (ETDEWEB)

    Butters, G.

    1988-10-01

    Effluent fouling into the Strait of Canso between Nova Scotia mainland and Cape Breton Island has caused Stora Forest Industries Ltd. to develop a $5.6 million solution to its chlorine and acid problems. In 1987, Stora produced about 160,000 tonnes of market pulp where their resource base increasingly consisted of hardwood. The company uses hardwood chips for a growing percentage of its annual pulp production and for its hog fuel boiler, but became faced with having to use more local hardwoods which contributes to the resin problem. Their solution was to construct a 12-tpd chlorine dioxide generator, a process using dry sodium chlorate added to concentrated H/sub 2/SO/sub 4/, The products are chlorine dioxide and highly concentrated sulphuric acid resulting from the elimination of water at the starting point. This will eliminate the acid effluent from the generator and the sulphuric acid will be recycled to the top of the chlorine dioxide generation process. In the new process, ClCO/sub 2/ replaces 70% of the chlorine in the first stage, with 100% substitution a goal. In addition to eliminating the chlorine, other benefits include an increase in pulp production, a nominal increase in pulp strength, lower production costs, and an economic incentive to harvest the area's mixed-wood stands.

  16. Sinopec offers HK$10m to clean up affected beaches

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    Sinopec has established a HK$10 million fund to assist green groups in cleaning up the millions of plastic pellets from a container ship that have been washed ashore on local beaches and fish farms. The 150 tons of polypropylene pellets were being shipped on board a freighter Yong Xin .lie 1 from Nansha Port to Shantou when signal l0 typhoon Vicente struck on ,luly 23. The pellets, in six containers, were blown into the sea. The pellets then washed onto the outlying islands of Hong Kong, stirring concerns over environmental damage to the ocean itself, as well as to marine life.

  17. Major clean-up effort in the ATLAS cavern

    CERN Multimedia

    Marzio Nessi

    On Tuesday 10 October, 58 ATLAS collaborators volunteered to give a hand for a major clean-up of the ATLAS detector prior to the toroid magnet ramp-up. This special task monopolised all of the technical coordination team and eight supervisors to oversee the volunteers who were assigned to two separate five-hour shifts. The volunteers removed all sorts of loose material inside and outside the detector, focusing mainly on potentially magnetic material lost inside the detector and dirt accumulated over several months, not to mention zillions of clipped cable ties! The technical crew provided 120 garbage bags and all were used. All sorts of material that had been lost inside the detector by various people was retrieved, in particular small tools which could potentially damage the detector, as well as metallic fillings hazardous for the electronics once the magnet will be ramped up. A more detailed inspection followed for all the inside of the detector, making sure the current on the magnet could be raised to 5KA ...

  18. PRP: The Proven Solution for Cleaning Up Oil Spills

    Science.gov (United States)

    2006-01-01

    The basic technology behind PRP is thousands of microcapsules, tiny balls of beeswax with hollow centers. Water cannot penetrate the microcapsule s cell, but oil is absorbed right into the beeswax spheres as they float on the water s surface. This way, the contaminants, chemical compounds that originally come from crude oil such as fuels, motor oils, or petroleum hydrocarbons, are caught before they settle. PRP works well as a loose powder for cleaning up contaminants in lakes and other ecologically fragile areas. The powder can be spread over a contaminated body of water or soil, and it will absorb contaminants, contain them in isolation, and dispose of them safely. In water, it is important that PRP floats and keeps the oil on the surface, because, even if oil exposure is not immediately lethal, it can cause long-term harm if allowed to settle. Bottom-dwelling fish exposed to compounds released after oil spills may develop liver disease, in addition to reproductive and growth problems. This use of PRP is especially effective for environmental cleanup in sensitive areas like coral reefs and mangroves.

  19. Using Phytoremediation to Clean Up Contamination at Military Installations

    Energy Technology Data Exchange (ETDEWEB)

    Zellmer, S.D.; Hinchman, R.R.; Negri, M.C.; Schneider, J.F. [Argonne National Lab., IL (United States); Gatliff, E.G. [Applied Natural Sciences, Inc., Fairfield, OH (United States)

    1997-07-01

    During and following World War II, wastes from the production of munitions and other military materials were disposed of using the best available practices acceptable at that time. However, these disposal methods often contaminated soil and groundwater with organic compounds and metals that require cleanup under current regulations. An emerging technology for cleaning contaminated soils and shallow groundwater is phytoremediation, an environmentally friendly, low- cost, and low-tech process. Phytoremediation encompasses all plant- influenced biological, chemical, and physical processes that aid in the uptake, degradation, and metabolism of contaminants by either plants or free-living organisms in the plant`s rhizosphere. A phytoremediation system can be viewed as a biological, solar-driven, pump-and-treat system with an extensive, self-extending uptake network (the root system) that enhances the soil and below-ground ecosystem for subsequent productive use. Argonne National Laboratory (ANL) has been conducting basic and applied research in phytoremediation since 1990. Initial greenhouse studies evaluated salt-tolerant wetland plants to clean UP and reduce the volume of salty `produced water` from petroleum wells. Results of these studies were used to design a bioreactor for processing produced water that is being demonstrated at a natural gas well in Oklahoma; this system can reduce produced water volume by about 75% in less than eight days, representing substantial savings in waste disposal cost. During 1994, ANL conducted a TNT plant uptake and in situ remediation study in a ridge-and-furrow area used for the disposal of pink water at the Joliet Army Ammunition Plant.

  20. Humidity affects the performance of von Frey monofilaments

    DEFF Research Database (Denmark)

    Werner, M U; Nielsen, Per Rotbøll; Ellehuus-Hilmersson, C

    2011-01-01

    Assessment of tactile and nociceptive thresholds of the skin with calibrated polyamide monofilaments is an established testing method both in animal and in human research. It is known that changes in relative humidity may affect the physical properties of the monofilaments. As this effect has only...

  1. [5.07 Monofilament: the use of this monofilament in outpatient offices by nurses in primary health care units].

    Science.gov (United States)

    Orihuela Casarra, Roser; Heras Tebar, Antonio; Pozo Gil, Maria

    2005-12-01

    A diabetic foot is the most important cause of disability and loss of life quality among diabetics. To inspect a diabetic's feet and to explore his/her protective sensibility capability with a 5.07 monofilament are efficient methods to detect the risk of lesions. The authors' objective was to discover if our Primary Health Care Unit utilizes this instrument; therefore, we carried out a poll among all the nurses in our unit. 79% of these nurses are aware of the 5.07 monofilament; 62% have this monofilament available for their use; 55% stated they utilize it. The primary reasons to not use this monofilament are its unavailability and a lack of knowledge regarding it. Priority must be given to facilitate the availability of this instrument and to promote among nurses an understanding how to correctly utilize a 5.07 monofilament.

  2. Cancer incidence and thyroid disease among Estonian Chernobyl clean-up workers

    Energy Technology Data Exchange (ETDEWEB)

    Auvinen, A.; Salomaa, S. [eds.] [Radiation and Nuclear Safety Authority, Helsinki (Finland); Rahu, M.; Veidebaum, T.; Tekkel, M. [eds.] [Inst. of Experimental and Clinical Medicine, Tallinn (Estonia); Hakulinen, T. [ed.] [Finnish Cancer Registry, Helsinki (Finland); Boice, J.D. Jr. [ed.] [Int. Epidemiology Inst., MD (United States)

    1998-09-01

    The report describes the development and summarizes the results of the project Cancer incidence and thyroid disease among Estonian Chernobyl clean-up workers. One of the goals of the report is to give research protocols and questionnaires for researchers involved in other studies. Eight previously published articles are also included summarizing the results. The development of the collaboration work of the project is described in the introduction of the report. Epidemiological methods are described in an article complemented by the protocol and English version of the questionnaire administered to all cleanup workers, as well as the data collection form of the thyroid study. The results from biological biodosimetry using both glycophorin A and FISH methods have shown that the radiation doses received by the Chernobyl cleanup workers were relatively low. Thyroid nodularity was not associated with any radiation exposure characteristic in the thyroid screening study. Estonian Chernobyl cleanup workers were followed up for cancer incidence through the Estonian Cancer Registry. No cases of leukemia or thyroid cancer were observed by the end of 1993. It is too early to observe possible effect on other types of cancer. However, mortality from suicides was increased compared with general population. Further follow-up and the extension to other Baltic countries in the future will undoubtedly strengthen the study. There are also plans for future projects covering areas from psychosocial factors to radiation biology

  3. Novel Sorbent to Clean Up Biogas for CHPs

    Energy Technology Data Exchange (ETDEWEB)

    Alptekin, Gökhan O. [TDA Research, Incorporated, Wheat Ridge, CO (United States); Jayataman, Ambalavanan [TDA Research, Incorporated, Wheat Ridge, CO (United States); Schaefer, Matthew [TDA Research, Incorporated, Wheat Ridge, CO (United States); Ware, Michael [TDA Research, Incorporated, Wheat Ridge, CO (United States); Hunt, Jennifer [FuelCell Energy, Inc., Danbury, CT (United States); Dobek, Frank [FuelCell Energy, Inc., Danbury, CT (United States)

    2015-05-30

    In this project, TDA Research Inc. (TDA) has developed low-cost (on a per unit volume of gas processed basis), high-capacity expendable sorbents that can remove both the H2S and organic sulfur species in biogas to the ppb levels. The proposed sorbents will operate downstream of a bulk desulfurization system as a polishing bed to provide an essentially sulfur-free gas to a fuel cell (or any other application that needs a completely sulfur-free feed). Our sorbents use a highly dispersed mixed metal oxides active phase with desired modifiers prepared over on a mesoporous support. The support structure allows the large organic sulfur compounds (such as the diethyl sulfide and dipropyl sulfide phases with a large kinetic diameter) to enter the sorbent pores so that they can be adsorbed and removed from the gas stream.

  4. Cleaning up

    DEFF Research Database (Denmark)

    Thomsen, Michael Kirkedal; Axelsen, Holger Bock; Glück, Robert

    2013-01-01

    Reversible logic is a computational model that ensure that no values are discarded or duplicated. This gives the connection to Landauer’s principle if and only if the underlying circuits are garbage-free. This paper shows how to describe and implement garbage-free reversible logic circuits...... in an easy and concise way. We use two domain-specific languages that are designed to describe reversible logic at different levels and garbage-free methods to translate between these. This approach relies heavily on programming language technology that is known and used for conventional functional languages....... Though the languages ensure reversibility of the logic descriptions, they are not guaranteed to be garbage- free. It is still an important task for the designer to find the correct embeddings....

  5. Clean-up and disposal process of polluted sediments from urban rivers

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In this paper, the discussion is concentrated on the properties of the polluted sediments and the combination of clean-up and disposal process for the upper layer heavily polluted sediments with good flowability. Based on the systematic analyses of various clean-up processes, a suitable engineering process has been evaluated and recommended. The process has been applied to the river reclamation in Yangpu District of Shanghai metropolis. An improved centrifuge is used for dewatering the dredged sludge,which plays an important role in the combination of clean-up and disposal process. The assessment of the engineering process shows its environmental and technical economy feasibility, which is much better than that of traditional dredging-disposal processes.

  6. The mental health of clean-up workers 18 years after the Chernobyl accident.

    Science.gov (United States)

    Loganovsky, K; Havenaar, J M; Tintle, N L; Guey, L T; Kotov, R; Bromet, E J

    2008-04-01

    The psychological aftermath of the Chernobyl accident is regarded as the largest public health problem unleashed by the accident to date. Yet the mental health of the clean-up workers, who faced the greatest radiation exposure and threat to life, has not been systematically evaluated. This study describes the long-term psychological effects of Chernobyl in a sample of clean-up workers in Ukraine. The cohorts were 295 male clean-up workers sent to Chernobyl between 1986 and 1990 interviewed 18 years after the accident (71% participation rate) and 397 geographically matched controls interviewed as part of the Ukraine World Mental Health (WMS) Survey 16 years after the accident. The World Health Organization (WHO) Composite International Diagnostic Interview (CIDI) was administered. We examined group differences in common psychiatric disorders, suicide ideation and severe headaches, differential effects of disorder on days lost from work, and in the clean-up workers, the relationship of exposure severity to disorder and current trauma and somatic symptoms. Analyses were adjusted for age in 1986 and mental health prior to the accident. Relatively more clean-up workers than controls experienced depression (18.0% v. 13.1%) and suicide ideation (9.2% v. 4.1%) after the accident. In the year preceding interview, the rates of depression (14.9% v. 7.1%), post-traumatic stress disorder (PTSD) (4.1% v. 1.0%) and headaches (69.2% v. 12.4%) were elevated. Affected workers lost more work days than affected controls. Exposure level was associated with current somatic and PTSD symptom severity. Long-term mental health consequences of Chernobyl were observed in clean-up workers.

  7. Dyscirculatory encephalopathy in Chernobyl disaster clean-up workers (a 20-year study).

    Science.gov (United States)

    Podsonnaya, I V; Shumakher, G I; Golovin, V A

    2010-05-01

    Results obtained over 20-years of following 536 Chernobyl clean-up workers and 436 control subjects are presented. Dyscirculatory encephalopathy developed more frequently in persons exposed to radiation at age 30 years. As compared with the control group, workers were characterized by early onset of disease, faster progression, stable symptomatology for 5-6 years, and further progression of disease in the form of autonomic dysfunction, psycho-organic syndrome, and epilepsy. Major strokes were also more common in clean-up workers.

  8. Data clean-up and management a practical guide for librarians

    CERN Document Server

    Hogarth, Margaret

    2012-01-01

    Data use in the library has specific characteristics and common problems. Data Clean-up and Management addresses these, and provides methods to clean up frequently-occurring data problems using readily-available applications. The authors highlight the importance and methods of data analysis and presentation, and offer guidelines and recommendations for a data quality policy. The book gives step-by-step how-to directions for common dirty data issues.focused towards libraries and practicing librariansdeals with practical, real-life issues and addresses common problems that all libraries faceoffe

  9. Porous monofilaments by continuous solid-state foaming

    NARCIS (Netherlands)

    Krause, B.; Kloth, M.; van der Vegt, N.F.A.; Wessling, Matthias

    2002-01-01

    We report a new semicontinuous process for the production of porous polyetherimide monofilaments. Dense, carbon-dioxide-saturated fibers are spun at rates up to 1 m/s, and porosity is introduced at the spinning head, which establishes the transition from the pressure cell to the heating bath. The pr

  10. Case Study: Using Microbe Molecular Biology for Gulf Oil Spill Clean Up

    Science.gov (United States)

    Jones, Daniel R.

    2011-01-01

    This case has the student actively investigate the regulation of expression of a novel bacterial gene in the context of attempts to solve a real world problem, clean up of the April 2010 Deep Water Horizon oil spill in the Gulf of Mexico. Although the case is fictitious, it is based on factual gene regulatory characteristics of oil-degrading…

  11. An alternative clean-up column for the determination of polychlorinated biphenyls in solid matrices.

    Science.gov (United States)

    Ndunda, Elizabeth N; Madadi, Vincent O; Mizaikoff, Boris

    2015-12-01

    The need for continuous monitoring of polychlorinated biphenyls (PCBs) has necessitated the development of analytical techniques that are sensitive and selective with minimal reagent requirement. In light of this, we developed a column for clean-up of soil and sediment extracts, which is less demanding in terms of the amount of solvent and sorbent. The dual-layer column consists of acidified silica gel and molecularly imprinted polymers (MIPs). MIPs were synthesized via aqueous suspension polymerization using PCB 15 as the dummy template, 4-vinylpyridine as the functional monomer and ethylene glycol dimethacrylate as the cross-linker and the obtained particles characterized via SEM, BET, and batch rebinding assays. Pre-concentration of the spiked real-world water sample using MISPE gave recoveries between 85.2 and 104.4% (RSD clean-up of extracts from complex matrices provided recoveries of 91.6-102.5% (RSD clean-up using acidified silica (70.4-90.5%; RSD clean-up procedure for continuous monitoring of PCBs. Method detection limits were 0.01-0.08 ng g(-1) and 0.002-0.01 ng mL(-1) for solid matrices and water, respectively.

  12. Refractive properties of separate erythrocytes of Chernobyl clean-up workers at different pH

    Science.gov (United States)

    Mazarevica, Gunta; Freivalds, Talivaldis; Bruvere, Ruta; Gabruseva, Natalija; Leice, Alevtine; Zvagule, Tija

    2000-04-01

    This study is focused on the modifications in erythrocytes of Chernobyl nuclear power plant accident clean-up workers as a late health effect of short-term impact of high level radioactive contamination. As a result, a new method based on erythrocyte refractive index properties at different pH has been elaborated.

  13. Improving the Quality of Conforming Triangular Meshes by Topological Clean up and DSI

    Institute of Scientific and Technical Information of China (English)

    MENGXian-hai; YANGQin; LIJl-gang; CHENQi-ming

    2004-01-01

    A new method as a post-processing step is presented to improve the shape quality of triangular meshes, which uses a topological clean up procedure and discrete smoothing interpolate (DSI) algorithm together. This method can improve the angle distribution of mesh element, while keeping the resulting meshes conform to the predefined constraints which are inputted as a PSLG.

  14. PCR inhibitor removal using the NucleoSpin® DNA Clean-Up XS kit.

    Science.gov (United States)

    Faber, Korie L; Person, Eric C; Hudlow, William R

    2013-01-01

    Forensic evidence samples are collected from an unlimited variety of substrates, which may contain compounds known to inhibit the polymerase chain reaction (PCR). These PCR inhibitors are co-extracted with the DNA sample and can negatively affect the DNA typing results, which can range from partial to complete inhibition of the short tandem repeat (STR) PCR. One potential solution is to remove the PCR inhibitors from the extracts prior to the STR PCR with the NucleoSpin(®) DNA Clean-Up XS kit. The kit contains a NucleoSpin(®) XS silica column that has a special funnel design of thrust rings along with a very small silica membrane, which allows for sample elution in a small volume that is appropriate for use with current STR typing kits. The NucleoSpin(®) DNA Clean-Up XS kit was optimized for the best possible DNA recovery and then evaluated for its ability to remove eight commonly encountered PCR inhibitors including: bile salt, collagen, hematin, humic acid, indigo, melanin, tannic acid and urea. Each of these PCR inhibitors was effectively removed by the NucleoSpin(®) DNA Clean-Up XS kit as demonstrated by generating more complete STR profiles from the cleaned up inhibitor samples than from the raw inhibitor samples. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.

  15. Proposals for intervention values for soil clean-up: Second series of chemicals

    NARCIS (Netherlands)

    Berg R van den; Bockting GJM; Crommentuijn GH; Jansen PJCM; LBG

    1994-01-01

    The thoroughly revised intervention values for soil clean-up have recently come into force. In this report, proposals will be presented for intervention values for other chemicals on the basis of an ecotoxicological and a human-toxicological evaluation. The proposals made have followed the procedure

  16. Efficiency of different protocols for enamel clean-up after bracket debonding: an in vitro study

    Science.gov (United States)

    Sigilião, Lara Carvalho Freitas; Marquezan, Mariana; Elias, Carlos Nelson; Ruellas, Antônio Carlos; Sant'Anna, Eduardo Franzotti

    2015-01-01

    Objective: This study aimed to assess the efficiency of six protocols for cleaning-up tooth enamel after bracket debonding. Methods: A total of 60 premolars were divided into six groups, according to the tools used for clean-up: 12-blade bur at low speed (G12L), 12-blade bur at high speed (G12H), 30-blade bur at low speed (G30L), DU10CO ORTHO polisher (GDU), Renew System (GR) and Diagloss polisher (GD). Mean roughness (Ra) and mean roughness depth (Rz) of enamel surface were analyzed with a profilometer. Paired t-test was used to assess Ra and Rz before and after enamel clean-up. ANOVA/Tukey tests were used for intergroup comparison. The duration of removal procedures was recorded. The association between time and variation in enamel roughness (∆Ra, ∆Rz) were evaluated by Pearson's correlation test. Enamel topography was assessed by scanning electron microscopy (SEM). Results: In Groups G12L and G12H, original enamel roughness did not change significantly. In Groups G30L, GDU, GR and GD, a smoother surface (p < 0.05) was found after clean-up. In Groups G30L and GD, the protocols used were more time-consuming than those used in the other groups. Negative and moderate correlation was observed between time and (∆Ra, ∆Rz); Ra and (∆Ra, ∆Rz); Rz (r = - 0.445, r = - 0.475, p < 0.01). Conclusion: All enamel clean-up protocols were efficient because they did not result in increased surface roughness. The longer the time spent performing the protocol, the lower the surface roughness. PMID:26560825

  17. Efficiency of different protocols for enamel clean-up after bracket debonding: an in vitro study

    Directory of Open Access Journals (Sweden)

    Lara Carvalho Freitas Sigilião

    2015-10-01

    Full Text Available Objective: This study aimed to assess the efficiency of six protocols for cleaning-up tooth enamel after bracket debonding.Methods:A total of 60 premolars were divided into six groups, according to the tools used for clean-up: 12-blade bur at low speed (G12L, 12-blade bur at high speed (G12H, 30-blade bur at low speed (G30L, DU10CO ORTHO polisher (GDU, Renew System (GR and Diagloss polisher (GD. Mean roughness (Ra and mean roughness depth (Rz of enamel surface were analyzed with a profilometer. Paired t-test was used to assess Ra and Rz before and after enamel clean-up. ANOVA/Tukey tests were used for intergroup comparison. The duration of removal procedures was recorded. The association between time and variation in enamel roughness (∆Ra, ∆Rz were evaluated by Pearson's correlation test. Enamel topography was assessed by scanning electron microscopy (SEM.Results:In Groups G12L and G12H, original enamel roughness did not change significantly. In Groups G30L, GDU, GR and GD, a smoother surface (p < 0.05 was found after clean-up. In Groups G30L and GD, the protocols used were more time-consuming than those used in the other groups. Negative and moderate correlation was observed between time and (∆Ra, ∆Rz; Ra and (∆Ra, ∆Rz; Rz (r = - 0.445, r = - 0.475, p < 0.01.Conclusion:All enamel clean-up protocols were efficient because they did not result in increased surface roughness. The longer the time spent performing the protocol, the lower the surface roughness.

  18. Radiological assessment in case of an incident at the hot cells clean-up

    Directory of Open Access Journals (Sweden)

    Dragolici Cristian A.

    2014-01-01

    Full Text Available The clean-up and decontamination of the hot cells will be performed in the second phase of the WWR-S research reactor decommissioning. Identification of possible incidents or accidents is the key element in radiological assessment and prevention. As major incident it was considered a fire burst that occurred during the progress of the clean-up operations. The postulated incident has, as a consequence, thick smoke generation from the burned radioactive material and the dispersion of this material in the environment through the technological ventilation system and the evacuation chimney. From the performed analysis it can be seen that in the case of an incident to the reactor hot cells, an operator engaged in intervention operations could take an effective dose of 5.29 Sv per event, coming from both external and internal exposure. Such an incident, if it happens, would be classified of level 3 on the INES scale.

  19. Process for cleaning up hard coal mines containing salt water. Verfahren zur Entsorgung von salzwasserfuehrenden Steinkohlenzechen

    Energy Technology Data Exchange (ETDEWEB)

    Hoelter, H.; Igelbuescher, H.; Gresch, H.; Dewert, H.

    1987-03-12

    The process for cleaning up pits with a great deal of salt water in them and the associated high proportion of flotation material is characterized by the fact that the pre-treated salt water content forms a mass with the flotation coal/rock mass, which is burnt to a residue in fluidized-bed combustion, where the residue as a building material containing salt is particularly suitable for building roads and paths secure against frost and for similar building processes.

  20. Coupling detergent lysis/clean-up methodology with intact protein fractionation for enhanced proteome characterization

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Ritin [ORNL; Dill, Brian [ORNL; Chourey, Karuna [ORNL; Shah, Manesh B [ORNL; Verberkmoes, Nathan C [ORNL; Hettich, Robert {Bob} L [ORNL

    2012-01-01

    The expanding use of surfactants for proteome sample preparations has prompted the need to systematically optimize the application and removal of these MS-deleterious agents prior to proteome measurements. Here we compare four different detergent clean-up methods (Trichloroacetic acid (TCA) precipitation, Chloroform/Methanol/Water (CMW) extraction, commercial detergent removal spin column method (DRS) and filter-aided sample preparation(FASP)) with respect to varying amounts of protein biomass in the samples, and provide efficiency benchmarks with respect to protein, peptide, and spectral identifications for each method. Our results show that for protein limited samples, FASP outperforms the other three clean-up methods, while at high protein amount all the methods are comparable. This information was used in a dual strategy of comparing molecular weight based fractionated and unfractionated lysates from three increasingly complex samples (Escherichia coli, a five microbial isolate mixture, and a natural microbial community groundwater sample), which were all lysed with SDS and cleaned up using FASP. The two approaches complemented each other by enhancing the number of protein identifications by 8%-25% across the three samples and provided broad pathway coverage.

  1. Oak Ridge Cleanup Vision: Moving to the Future by Cleaning Up the Past - 13291

    Energy Technology Data Exchange (ETDEWEB)

    Cange, Susan M. [DOE Oak Ridge, P.O. Box 2001, Oak Ridge, TN 37831 (United States); Wieland, Christopher C.; DePaoli, Susan M. [Pro2Serve, 1100 Bethel Valley Rd., Oak Ridge, TN 37830 (United States)

    2013-07-01

    successfully revised Program priorities and has received buy-in from the leadership in Headquarters, the regulators, and the community. Issues EM was facing in 2009 are presented. Resulting lessons learned and subsequent changes that the Office has gone through in the past several years in order to improve performance in the safe execution of work, relationships with external stakeholders, and communications both internally and externally are discussed. Results of these efforts are provided as a summary of Program accomplishments, including a strong focus on the future. EM's motto, Moving to the Future by Cleaning up the Past, will be demonstrated through the Program's mission, which includes protecting the region's health and environment; ensuring the continuation of ongoing vital missions being conducted by DOE on the Oak Ridge Reservation; and making clean land available for future use at all three sites, with a near-term focus on Re-industrialization of ETTP. (authors)

  2. Monitoring the clean-up operation of agricultural fields flooded with red mud in Hungary.

    Science.gov (United States)

    Uzinger, Nikolett; Rékási, Márk; Anton, Áron D; Koós, Sándor; László, Péter; Anton, Attila

    2016-12-01

    In the course of the clean-up operation after the red mud inundation in 2010, red mud was removed from the soil surface in places where the layer was more than 5 cm deep. Before its removal, the red mud seeped into the soil. In 2012, soil samples were taken from depths of 0 to 20 and 20 to 40 cm on some of the affected areas. The parameters investigated were pH, organic matter, salt%, and the total and mobile fractions of various elements. The values recorded in 2012 were compared with those measured immediately after the removal of the red mud in 2010 and with the background and clean-up target concentrations. The pH values remained below the designated limit, while the salt content only exhibited values in the weakly salty range on areas at the greatest distance from the dam. In the central part of the inundated area, total Na contents above the 900 mg/kg target value were observed, but the Na content in the 0-20-cm layer generally exhibited a decrease due to leaching. The pH and As concentration also showed a decline on several areas compared with the values recorded in 2010. Total As and Co contents in excess of the target values were recorded on the lowest-lying part of the flooded area, probably because the finest red mud particles were deposited the furthest from the dam, where they seeped into the soil. Nevertheless, the mobility and plant availability of both elements remained moderate. The total contents of both Co and Mo, however, exhibited a significant rise compared with both the background value and the 2010 data. The monitoring of the cleaned-up areas showed that after a 2-year period element concentrations that exceeded the target values and could be attributed to the red mud pollution were only detectable on the lowest-lying areas.

  3. Sol-gel immunoaffinity chromatography for the clean up of ochratoxin A contaminated grains.

    Science.gov (United States)

    Reiter, Elisabeth Viktoria; Cichna-Markl, Margit; Tansakul, Natthasit; Shim, Won-Bo; Chung, Duck-Hwa; Zentek, Jürgen; Razzazi-Fazeli, Ebrahim

    2011-10-21

    This paper describes the application of sol-gel immunoaffinity columns for clean up of ochratoxin A contaminated cereal crops. Monoclonal antibodies selective for OTA have been entrapped into the pores of a sol-gel matrix in order to prepare immunoaffinity columns. Different parameters such as amount of entrapped antibodies and loading conditions were optimized to obtain highest possible recoveries of OTA. The method has been found to be a suitable tool in sample preparation prior to HPLC-FLD determination and as selective as conventional commercially available immunoaffinity columns. In the clean up of different cereals mean recoveries of 82±5%, 90±6% and 91±3%, were obtained for wheat, barley and rye, respectively, with sol-gel columns containing 1mg of anti-OTA antibodies. The detection limit (signal-to-noise ratio, 3) was 0.5 μg/kg and the limit of quantification (signal-to-noise ratio, 10) determined to be 1 μg/kg. Sol-gel columns can be reused 7 times without significant loss of recovery. After 10 applications the recovery decreased to approx. 50%.

  4. Determination of amphetamines in hair by integrating sample disruption, clean-up and solid phase derivatization.

    Science.gov (United States)

    Argente-García, A; Moliner-Martínez, Y; Campíns-Falcó, P; Verdú-Andrés, J; Herráez-Hernández, R

    2016-05-20

    The utility of matrix solid phase dispersion (MSPD) for the direct analysis of amphetamines in hair samples has been evaluated, using liquid chromatography (LC) with fluorescence detection and precolumn derivatization. The proposed approach is based on the employment of MSPD for matrix disruption and clean-up, followed by the derivatization of the analytes onto the dispersant-sample blend. The fluorogenic reagent 9-fluorenylmethyl chloroformate (FMOC) has been used for derivatization. Different conditions for MSPD, analyte purification and solid phase derivatization have been tested, using amphetamine (AMP), methamphetamine (MET), ephedrine (EPE) and 3,4-methylenedioxymethamphetamine (MDMA) as model compounds. The results have been compared with those achieved by using ultrasound-assisted alkaline digestion and by MSPD combined with conventional solution derivatization. On the basis of the results obtained, a methodology is proposed for the analysis of amphetamines in hair which integrates sample disruption, clean-up and derivatization using a C18 phase. Improved sensitivity is achieved with respect to that obtained by the alkaline digestion or by the MSPD followed by solution derivatization methods. The method can be used for the quantification of the tested amphetamines within the 2.0-20.0ng/mg concentration interval, with limits of detection (LODs) of 0.25-0.75ng/mg. The methodology is very simple and rapid (the preparation of the sample takes less than 15min).

  5. Dosimetry for a study of low-dose radiation cataracts among Chernobyl clean-up workers.

    Science.gov (United States)

    Chumak, V V; Worgul, B V; Kundiyev, Y I; Sergiyenko, N M; Vitte, P M; Medvedovsky, C; Bakhanova, E V; Junk, A K; Kyrychenko, O Y; Musijachenko, N V; Sholom, S V; Shylo, S A; Vitte, O P; Xu, S; Xue, X; Shore, R E

    2007-05-01

    A cohort of 8,607 Ukrainian Chernobyl clean-up workers during 1986-1987 was formed to study cataract formation after ionizing radiation exposure. Study eligibility required the availability of sufficient exposure information to permit the reconstruction of doses to the lens of the eye. Eligible groups included civilian workers, such as those who built the "sarcophagus" over the reactor, Chernobyl Nuclear Power Plant Workers, and military reservists who were conscripted for clean-up work. Many of the official doses for workers were estimates, because only a minority wore radiation badges. For 106 military workers, electron paramagnetic resonance (EPR) measurements of extracted teeth were compared with the recorded doses as the basis to adjust the recorded gamma-ray doses and provide estimates of uncertainties. Beta-particle doses to the lens were estimated with an algorithm devised to take into account the nature and location of Chernobyl work, time since the accident, and protective measures taken. A Monte Carlo routine generated 500 random estimates for each individual from the uncertainty distributions of the gamma-ray dose and of the ratio of beta-particle to gamma-ray doses. The geometric mean of the 500 combined beta-particle and gamma-ray dose estimates for each individual was used in the data analyses. The median estimated lens dose for the cohort was 123 mGy, while 4.4% received >500 mGy.

  6. Obtaining the Dewey Decimal Classification Number from other databases: a catalog clean-up project

    National Research Council Canada - National Science Library

    Stefano Bargioni; Michele Caputo; Alberto Gambardella; Luigi Gentile

    2013-01-01

    .... Technical specifications have been developed to locate the records to be retrieved, to query external databases, to extract the Dewey decimal classification numbers and add them to the catalog...

  7. Obtaining the Dewey Decimal Classification Number from other databases: a catalog clean-up project

    Directory of Open Access Journals (Sweden)

    Stefano Bargioni

    2013-07-01

    Full Text Available The increasing availability of online catalogs and bibliographical databases allows not only for copy cataloging, but also for the retrieval of atomic information useful within the catalog. To this end, Dewey decimal numbers were imported from national and international sources by means of the unique identifier ISBN. Technical specifications have been developed to locate the records to be retrieved, to query external databases, to extract the Dewey decimal classification numbers and add them to the catalog. The exceptionally large amount of Dewey numbers added to the catalog has improved the semantic usability of the OPAC. The procedure established has also facilitated the collection of information on the use of the Dewey Decimal System in the various databases used and allowed to make certain comparisons between them. The tools employed can be used analogously for data-retrieval operations in the catalog, as an aid in the cataloging process, or to improve the OPAC in either a static or dynamic manner. Taking into account its virtually exclusive practical purpose, this work is characterized by practical rather than theoretical choices. However, the experience acquired opens up areas even in the field of academic research.

  8. Hazardous Waste Clean-Up Information (CLU-IN) On-line Characterization and Remediation Databases Fact Sheet

    Science.gov (United States)

    This fact sheet provides an overview of the 10 on-line characterization and remediation databases available on the Hazardous Waste Clean-Up Information (CLU-IN) website sponsored by the U.S. Environmental Protection Agency.

  9. Social and psychological state of the Chornobyl clean up workers. Risk factors for negative changes.

    Science.gov (United States)

    Buzunov, V O; Loganovsky, K N; Krasnikova, L I; Bomko, M O; Belyaev, Yu M; Yaroshenko, Zh S; Domashevska, T Ye

    2016-12-01

    It is generally recognized that the Chornobyl nuclear accident caused strong psychosocial stress affecting the entire population of Ukraine, primarily people involved in recovery operations. But what are the reasons? What is the struc ture of stressors? What are their social, medical and biological consequences, what are strategy and preventive meas ures? Issues that require special research and development. To study social and psychological state of the Chornobyl cleanup workers 1986-1987, and to determine regularities of changes and dangerous risk factors. On the basis of Polyclinic of Radiation Registry, NRCRM, we conducted sample epidemiolog ical study of social and psychological state of the Chornobyl clean up workers 1986-1987. We used method of inter viewing based on «questionnaire», specially developed for this purpose. The study was conducted in October 2013 - May 2015. The sample numbered 235 males aged 18-50 at the time of the accident. Their average age was (31.3 ± 5.3) years at the time of the accident and (58.9 ± 5.3) at the time of survey. The results revealed that the Chornobyl nuclear accident and its consequences caused strong social and psychological stress among clean up workers 1986-1987. We have identified a set of factors closely related to the Chornobyl accident, they have caused a sustainable development of mental syndrome - «Anxiety about their own health and the health of family members, especially children». The other set of stressors which are not closely relat ed to the Chornobyl accident but are the result of the social and economic, social and political situation in the coun try. However the former was found to be the cause of such a psychological state as «dissatisfaction with the com pleteness and quality of life». Social and psychological state of the Chornobyl clean up workers 1986-1987 is estimated as «poor» and it integrally can be characterized as a state of chronic psychosocial stress. Mental syndrome

  10. Improved exposure estimation in soil screening and clean-up criteria for volatile organic chemicals.

    Science.gov (United States)

    DeVaull, George E

    2017-02-18

    Soil clean-up criteria define acceptable concentrations of organic chemical constituents for exposed humans. These criteria sum the estimated soil exposure over multiple pathways. Assumptions for ingestion, dermal contact, and dust exposure generally presume a chemical persists in surface soils at a constant concentration level for the entire exposure duration. For volatile chemicals this is an unrealistic assumption. A calculation method is presented for surficial soil criteria which include volatile depletion of chemical for these uptake pathways. The depletion estimates compare favorably with measured concentration profiles and with field measurements of soil concentration. Corresponding volatilization estimates compare favorably with measured data for a wide range of volatile and semi-volatile chemicals, including instances with and without the presence of a mixed-chemical residual phase. Selected examples show application of the revised factors in estimating screening levels for benzene in surficial soils. This article is protected by copyright. All rights reserved.

  11. Sorbent biomaterials for cleaning up hydrocarbon spills on soil and bodies of water

    Directory of Open Access Journals (Sweden)

    Diana Paola Ortíz González

    2010-04-01

    Full Text Available This study was aimed at identifying and evaluating natural organic materials which could be used as sorbents in clean-up operations following hydrocarbons spills on both soils and bodies of water. The sorption capacity of three materials (sugarcane fibre, coco fibre and water Eichornia crassipies was evaluated with three hydrocarbons (35°, 30° and 25°API and two types of water (distilled and artificial marine water adopting the ASTM F-726 standard and following the methodology suggested in the “Oil spill sorbents: testing protocol and certification listing programme” Canadian protocol. It was found that the three materials being evaluated had a sorption capacity equal to or greater than that of the commercial material to which they were compared. It was observed that sorption capacity results depended on some variables such as hydrocarbon viscosity, granulometry (particle size in Tyler sieve and the structure of the material. Sugarcane fibre sorption in water showed the greatest hydrophobicity, different to Eichornia crassipies which is extremely hydrophilic. The materials’ sorption kinetics were determined and modelled with the three hydrocarbons (35°, 30° and 25°API. It was found that the materials became saturated in less than a minute, leading to a rapid alternative for cleaning-up and controlling hydrocarbon spills. Materials were also thermally treated for improving their hydrophobicity and behaviour during spills on bodies of water. Sugarcane fibre was the material which presented the best results with the thermal treatment, followed by water Eichornia crassipies. Coco fibre did not present any significant change in its hydrophobicity.

  12. Long term alterations of blood plasma albumin in Chernobyl clean-up workers

    Directory of Open Access Journals (Sweden)

    Inta Kalnina

    2014-09-01

    Full Text Available Albumin is the most generously represented protein in human blood plasma. Therefore it is important to follow and assess the transport function of albumin in clinic researches. Disturbances in structural/functional properties of albumin play an important role in the pathogenesis of various diseases and immune state in patients. Changes in albumin transformation can serve as a diagnostic and prognostic criterion in pathologies. ABM (3-aminobenzanthrone derivative developed at the Daugavpils University, Latvia has been previously shown as a potential biomarker for determination of the immune state of patients with different pathologies. The aim of this study was to determine the several aspects of plasma albumin alterations in the group of Chernobyl clean-up workers in long term period in relation with humans having no professional contact with radioactivity. The following parameters were examined: (1 spectral characteristics of ABM in blood plasma; (2 and #8216;effective and #8217; and total albumin (EA and TA concentration in blood plasma; (3 quantitative parameters of albumin auto-fluorescence; (4 albumin binding site characteristics. Screening of the individuals with a period of 25-26 years after the work in Chernobyl revealed two groups of patients differing in structural and functional albumin properties; first on conformations of plasma albumin, and second characteristics of tryptophanyl region of the molecule. The revealed structural modifications of albumin are dependent on radiation-induced factors. Concomitant diseases such as diabetes mellitus or cardio-vascular diseases reinforce radiation-induced effects. In conclusion, ABM is a sensitive probe for albumin alterations and can be used to elucidate the changes in protein systems. Significant differences in albumin dynamics exist between control (donors and groups of Chernobyl clean-up workers. [J Exp Integr Med 2014; 4(3.000: 165-170

  13. The integration of science and politics to clean up 50 years in the nuclear sandbox

    Energy Technology Data Exchange (ETDEWEB)

    Lyons, C.E.; Holeman, T.

    1999-07-01

    The Cold War was fought between world superpowers for approximately 40 years from the end of the second World War until the end of the 1980s. During that time, the US government devoted billions of dollars to the development and production of nuclear weapons. Now the Cold War is over and the US is left with numerous nuclear weapons factories, stockpiles of nuclear materials, and mountains of waste to decontaminate and decommission. In the heat of the Cold War, little or no thought was given to how the facilities building bombs would be dismantled. Far too little attention was paid to the potential human health and environmental impact of the weapons production. Now, dozens of communities across the country face the problems this negligence created. In many cases, the location, extent, and characteristics of the waste and contamination are unknown, due to negligence or due to intentional hiding of waste and associated problems. Water supplies are contaminated and threatened; air quality is degraded and threatened; workers and residents risk contamination and health impacts; entire communities risk disaster from potential nuclear catastrophe. The US government, in the form of the US Department of Energy (DOE), now accepts responsibility for creating and cleaning up the mess. But it is the local communities, the home towns of the bomb factories and laboratories, that carry a significant share of the burden of inventing the science and politics required to clean up 50 years in the nuclear sandbox. The purpose of this paper is to evaluate the role of the local community in addressing the cleanup of the US nuclear weapons complex. Local governments do not own nor are responsible for the environmental aftermath, but remain the perpetual neighbor to the facility, the hometown of workers, and long-term caretaker of the off-site impacts of the on-site contamination and health risks.

  14. Extraction and clean-up methods for organochlorine pesticides determination in milk.

    Science.gov (United States)

    Martins, Joana Gomes; Amaya Chávez, Araceli; Waliszewski, Stefan M; Colín Cruz, Arturo; García Fabila, María Magdalena

    2013-07-01

    Organochlorine pesticides (OCPs) can cause environmental damage and human health risks since they are lipophilic compounds with high resistance to degradation and long half-lives in humans. As most persistent OCPs have been banned years ago, it is expected to find these compounds at trace levels in environment. Therefore, increasingly sensitive and reliable analytical techniques are required to ensure effective monitoring of these compounds. The aim of this review is to discuss extraction and clean-up methods used to monitor OCP residues in milk, reported in the last 20 years. To carry out this review, an exhaustive bibliographic review was conducted. Despite the disadvantages of conventional extraction and clean-up methods, such as liquid-liquid, solid-phase or Soxhlet extractions, these procedures are still used due to their reliability. New extraction methods, like solid-phase microextraction, matrix solid-phase dispersion or QuEChERS, have not been thoroughly evaluated for OCP determination in milk. Almost all the methodologies analyzed in this review presented good performance characteristics according to the performance acceptability criteria set in SANCO's procedure. Comparison between limits of quantification (LOQ) and detection (LOD), for the reported methodologies, is not always possible due to the heterogeneity of the units. Thus, researchers should take into account an homogenization of LOD and LOQ units, according to the international regulations and MRLs established. Finally, more research is necessary to obtain the ideal methodology for OCPs determination in milk, which comprises the environmentally friendly characteristics of the new techniques and the reliability of the traditional methodologies. Copyright © 2013 Elsevier Ltd. All rights reserved.

  15. Enamel Surface Roughness after Debonding of Orthodontic Brackets and Various Clean-Up Techniques

    Directory of Open Access Journals (Sweden)

    Farzaneh Ahrari

    2013-01-01

    Full Text Available Objective: This study aimed to evaluate enamel roughness after adhesive removal using different burs and an Er:YAG laser.Materials and Methods: The buccal surfaces of forty human premolars were sealed by two layers of nail varnish, except for a circular area of 3 mm in diameter on the middle third. The enamel surfaces were initially subjected to profilometry analysis and four parameters of surface irregularity (Ra, Rq, Rt and Rz were recorded. Following bracket bonding and debonding, adhesive remnants were removed by tungsten carbide burs in low- or high- speed handpieces (group 1 and 2, respectively, an ultrafine diamond bur (group 3 or an Er:YAG laser (250 mJ, long pulse, 4 Hz (group 4, and surface roughness parameters were measured again. Then, the buccal surfaces were polished and the third profilometry measurements were performed.Results: The specimens that were cleaned with a low speed tungsten carbide bur showed no significant difference in surface irregularity between the different treatment stages (p>0.05. Surface roughness increased significantly after clean-up with the diamond bur and the Er:YAG laser (p<0.01. In comparison between groups, adhesive removal with tungsten carbide burs at slow- or high-speed handpieces produced the lowest, while enamel clean-up with the Er:YAG laser caused the highest values of roughness measurements (P<0.05.Conclusion: Under the study conditions, application of the ultrafine diamond bur or the Er:YAG laser caused irreversible enamel damage on tooth surface, and thus these methods could not be recommended for removing adhesive remnants after debonding of orthodontic brackets.

  16. Comparison of clean-up methods for ochratoxin A on wine, beer, roasted coffee and chili commercialized in Italy.

    Science.gov (United States)

    Prelle, Ambra; Spadaro, Davide; Denca, Aleksandra; Garibaldi, Angelo; Gullino, Maria Lodovica

    2013-10-22

    The most common technique used to detect ochratoxin A (OTA) in food matrices is based on extraction, clean-up, and chromatography detection. Different clean-up cartridges, such as immunoaffinity columns (IAC), molecular imprinting polymers (MIP), Mycosep™ 229, Mycospin™, and Oasis® HLB (Hydrophilic Lipophilic balance) as solid phase extraction were tested to optimize the purification for red wine, beer, roasted coffee and chili. Recovery, reproducibility, reproducibility, limit of detection (LOD) and limit of quantification (LOQ) were calculated for each clean-up method. IAC demonstrated to be suitable for OTA analysis in wine and beer with recovery rate >90%, as well as Mycosep™ for wine and chili. On the contrary, MIP columns were the most appropriate to clean up coffee. A total of 120 samples (30 wines, 30 beers, 30 roasted coffee, 30 chili) marketed in Italy were analyzed, by applying the developed clean-up methods. Twenty-seven out of 120 samples analyzed (22.7%: two wines, five beers, eight coffees, and 12 chili) resulted positive to OTA. A higher incidence of OTA was found in chili (40.0%) more than wine (6.6%), beers (16.6%) and coffee (26.6%). Moreover, OTA concentration in chili was the highest detected, reaching 47.8 µg/kg. Furthermore, three samples (2.5%), two wines and one chili, exceeded the European threshold.

  17. Comparison of Clean-Up Methods for Ochratoxin A on Wine, Beer, Roasted Coffee and Chili Commercialized in Italy

    Directory of Open Access Journals (Sweden)

    Ambra Prelle

    2013-10-01

    Full Text Available The most common technique used to detect ochratoxin A (OTA in food matrices is based on extraction, clean-up, and chromatography detection. Different clean-up cartridges, such as immunoaffinity columns (IAC, molecular imprinting polymers (MIP, Mycosep™ 229, Mycospin™, and Oasis® HLB (Hydrophilic Lipophilic balance as solid phase extraction were tested to optimize the purification for red wine, beer, roasted coffee and chili. Recovery, reproducibility, reproducibility, limit of detection (LOD and limit of quantification (LOQ were calculated for each clean-up method. IAC demonstrated to be suitable for OTA analysis in wine and beer with recovery rate >90%, as well as Mycosep™ for wine and chili. On the contrary, MIP columns were the most appropriate to clean up coffee. A total of 120 samples (30 wines, 30 beers, 30 roasted coffee, 30 chili marketed in Italy were analyzed, by applying the developed clean-up methods. Twenty-seven out of 120 samples analyzed (22.7%: two wines, five beers, eight coffees, and 12 chili resulted positive to OTA. A higher incidence of OTA was found in chili (40.0% more than wine (6.6%, beers (16.6% and coffee (26.6%. Moreover, OTA concentration in chili was the highest detected, reaching 47.8 µg/kg. Furthermore, three samples (2.5%, two wines and one chili, exceeded the European threshold.

  18. Comparison of Clean-Up Methods for Ochratoxin A on Wine, Beer, Roasted Coffee and Chili Commercialized in Italy

    Science.gov (United States)

    Prelle, Ambra; Spadaro, Davide; Denca, Aleksandra; Garibaldi, Angelo; Gullino, Maria Lodovica

    2013-01-01

    The most common technique used to detect ochratoxin A (OTA) in food matrices is based on extraction, clean-up, and chromatography detection. Different clean-up cartridges, such as immunoaffinity columns (IAC), molecular imprinting polymers (MIP), Mycosep™ 229, Mycospin™, and Oasis® HLB (Hydrophilic Lipophilic balance) as solid phase extraction were tested to optimize the purification for red wine, beer, roasted coffee and chili. Recovery, reproducibility, reproducibility, limit of detection (LOD) and limit of quantification (LOQ) were calculated for each clean-up method. IAC demonstrated to be suitable for OTA analysis in wine and beer with recovery rate >90%, as well as Mycosep™ for wine and chili. On the contrary, MIP columns were the most appropriate to clean up coffee. A total of 120 samples (30 wines, 30 beers, 30 roasted coffee, 30 chili) marketed in Italy were analyzed, by applying the developed clean-up methods. Twenty-seven out of 120 samples analyzed (22.7%: two wines, five beers, eight coffees, and 12 chili) resulted positive to OTA. A higher incidence of OTA was found in chili (40.0%) more than wine (6.6%), beers (16.6%) and coffee (26.6%). Moreover, OTA concentration in chili was the highest detected, reaching 47.8 µg/kg. Furthermore, three samples (2.5%), two wines and one chili, exceeded the European threshold. PMID:24152987

  19. Biochemical observations relating to oxidant stress injury in Chernobyl clean-up workers ("liquidators") from Latvia.

    Science.gov (United States)

    Skesters, Andrejs; Zvagule, T; Silova, A; Rusakova, N; Larmane, L; Reste, J; Eglite, M; Rainsford, K D; Callingham, B A; Bake, M-A; Lece, A

    2010-02-01

    To establish if there is further evidence for the long-term oxidant stress injury (as reported previously--Kumerova et al. in Biol Trace Elem Res 77:1-12, 2000) in surviving Chernobyl nuclear power plant (NPP) workers from Latvia. The overall objectives of this study have been to establish if there have been long-term systemic changes in the oxidant/antioxidant status of clean-up workers that might reflect adaptation to the progression of oxidative stress injury. Biochemical analyses of the circulating levels of endogenous oxidants and anti-oxidants were undertaken over two periods (Stage 1 in 1998-1999 and Stage 2 in 2005-2006) at approximately 6-7 years time interval, in order to establish if there have been time-dependent changes in the parameters that may be important for the health of the clean-up workers. The biochemical analyses included (a) plasma levels of the anti-oxidant, selenium, (b) blood and plasma levels of glutathione peroxidase, (c) red blood cell catalase, (d) plasma total oxidant status as lipid peroxides and hydroperoxides, (e) plasma ceruloplasmin, and (f) total blood levels of zinc and copper. The circulating content of lipid peroxides, plasma oxidisability, lipid peroxides, catalase, Zn, and Cu were elevated above normal values at both the stages of this study. Glutathione peroxidase was increased above normal values at Stage 1 but not at Stage 2. The most pronounced changes between Stage 1 and Stage 2 were (a) a reduction by about (1/2) in the content of lipid peroxides and lipid peroxidation, but not in the blood oxidisability and (b) increased plasma selenium. The data show that there may be a partial improvement in the anti-oxidant/oxidant status of the Chernobyl NPP workers over the 7-year period of investigation. The NPP patients may be undergoing progressive reduction in blood oxidants accompanied by adaptation to oxidant stress injury due to the increased anti-oxidant activity measured in their plasma and blood.

  20. Validation of extraction, clean-up and DR CALUX {sup registered} bioanalysis. Pt. I. Feedingstuff

    Energy Technology Data Exchange (ETDEWEB)

    Besselink, H.; Jonas, A.; Brouwer, B. [BioDetection Systems BV (BDS), Amsterdam (Netherlands); Pijnappels, M.; Swinkels, A. [Masterlab BV, Boxmeer (Netherlands)

    2004-09-15

    Feed safety is a high priority issue for the feed sector as it directly impacts at the beginning of the food-chain. Currently stringent EU limit values are in force for dioxins in feedingstuffs for animal and public health protection. Biodetection Systems BV's (BDS) DR CALUX {sup registered} bioassay is a cost-effective and rapid method to measure low levels of dioxins and dioxin-like compounds in various matrices. The use of bioassays for monitoring dioxins in feed allows the (pre)-selection of samples suspected of being contaminated above limit values with dioxins. To permit bioassays to be used for screening feedingstuffs for the presence of dioxins and related compounds, the EU has laid down general requirements for the determination of dioxins and dioxin-like PCBs in feedingstuffs and specific requirements for cell-based bioassays. To ensure reliability the DR CALUX {sup registered} bioassay, validated methods for extraction and DR CALUX {sup registered} analysis are necessary. Within the framework of the development of DR CALUX {sup registered} analysis methods, extraction and clean-up methods for 13 feedingstuffs were evaluated, selected and validated. In this paper we present the results of this substantive multi-matrix feedingstuffs validation study.

  1. Diving behaviour of wildlife impacted by an oil spill: A clean-up and rehabilitation success?

    Science.gov (United States)

    Chilvers, B L; Morgan, K M; Finlayson, G; Sievwright, K A

    2015-11-15

    The value of rehabilitating oiled wildlife is an on-going global debate. On October 5, 2011, the cargo vessel C/V Rena grounded on Astrolabe Reef, New Zealand (NZ), spilling over 300 tonnes of heavy fuel oil. As part of the Rena oil spill response, 383 little blue penguins (LBP, Eudyptula minor) were captured, cleaned, rehabilitated and released back into a cleaned environment. This research investigates foraging behaviour changes due either to the oil spill or by the rehabilitation process by comparing the diving behaviour of rehabilitated (n=8) and non-rehabilitated (n=6) LBPs and with LBP populations throughout NZ. Stabile isotope analysis of feathers was also used to investigate diet. There were no foraging behaviour differences between rehabilitated and non-rehabilitated LBPs and the overall diving behaviour of these LBPs have similar, if not less energetic, foraging behaviour than other LBPs in NZ. This suggests the rehabilitation process and clean-up undertaken after the Rena appears effective and helps justify the rehabilitation of oiled wildlife across the world.

  2. Hanford tank clean up: A guide to understanding the technical issues

    Energy Technology Data Exchange (ETDEWEB)

    Gephart, R.E.; Lundgren, R.E.

    1995-12-31

    One of the most difficult technical challenges in cleaning up the US Department of Energy`s (DOE) Hanford Site in southeast Washington State will be to process the radioactive and chemically complex waste found in the Site`s 177 underground storage tanks. Solid, liquid, and sludge-like wastes are contained in 149 single- and 28 double-shelled steel tanks. These wastes contain about one half of the curies of radioactivity and mass of hazardous chemicals found on the Hanford Site. Therefore, Hanford cleanup means tank cleanup. Safely removing the waste from the tanks, separating radioactive elements from inert chemicals, and creating a final waste form for disposal will require the use of our nation`s best available technology coupled with scientific advances, and an extraordinary commitment by all involved. The purpose of this guide is to inform the reader about critical issues facing tank cleanup. It is written as an information resource for the general reader as well as the technically trained person wanting to gain a basic understanding about the waste in Hanford`s tanks -- how the waste was created, what is in the waste, how it is stored, and what are the key technical issues facing tank cleanup. Access to information is key to better understanding the issues and more knowledgeably participating in cleanup decisions. This guide provides such information without promoting a given cleanup approach or technology use.

  3. Commissioning of the catalytic plasma exhaust clean-up facility caprice and first experimental results

    Energy Technology Data Exchange (ETDEWEB)

    Glugla, M.; Kraemer, R.; Penzhorn, R.D.; Le, T.L.; Simon, K.H.; Guenther, K.; Besserer, U.; Schaefer, P.; Hellriegel, W. [Research Center Karlsruhe (Germany); Geissler, H. [Kraftanlagen Heidelberg (Germany)

    1995-10-01

    A fuel clean-up process for all plasma exhaust gases from DT fusion machines, based on catalytic conversion reactions combined with permeation of hydrogen isotopes through palladium/silver, has been developed. The complete process has already been proven with relevant concentrations of tritium at laboratory scale. On the basis of the results obtained the technical facility `CAPRICE` was designed, and is now under tritium operation at the Tritium Laboratory Karlsruhe (TLK). The facility is being used to demonstrate the process on a target throughput of 10 mol/h DT and 1 mol/h tritiated and non-tritiated impurities. Full scale experiments with hydrogen and deuterium have been completed to verify the design parameters of the facility and to gain detailed knowledge on the performance of the different subsystems under a variety of experimental conditions. Decontamination factors were obtained from these experiments as well as from first tritium runs employing about 350 Ci (0.5%) tritium in deuterium. 4 refs., 6 figs., 1 tab.

  4. Reliability of the electrical perceptual threshold and Semmes-Weinstein monofilament tests of cutaneous sensibility

    National Research Council Canada - National Science Library

    Ellaway, P H; Catley, M

    2013-01-01

    ...) and Semmes-Weinstein monofilament (SWM) tests for cutaneous sensibility. EPT and SWM tests have potential as quantitative and sensitive adjuncts to the American Spinal Injuries Association (ASIA) Impairment Scale (AIS...

  5. Use of molecularly imprinted solid-phase extraction for the selective clean-up of clenbuterol from calf urine

    NARCIS (Netherlands)

    Berggren, C; Bayoudh, S; Sherrington, D; Ensing, K

    2000-01-01

    A feasibility study was performed in order to study the possibilities in using molecularly imprinted polymers (MIPs) as sorbent material in solid-phase extraction (MISPE) for clean-up of clenbuterol from urine. A binding study of clenbuterol in several solvents was performed on a clenbuterol imprint

  6. Methode van onderzoek voor residuen van bestrijdingsmiddelen na clean-up m.b.v. gelpermeatiechromatografie (GPC) (Multimethode 12)

    NARCIS (Netherlands)

    Greve PA

    1988-01-01

    In dit rapport wordt een methode gegeven voor de clean-up van extracten m.b.v. gelpermeatie-chromatografie (GPC) t.b.v. de bepaling van residuen van electroncaptieve en organofosforbestrijdingsmiddelen. Een oudere versie van de GPC-methode, die alleen de organochloorbestrijdingsmiddelen omvatte,

  7. Rapid and simple clean-up and derivatizaton procedure for the gas chromatographic determination of acidic drugs in plasma

    NARCIS (Netherlands)

    Roseboom, H.; Hulshoff, A.

    1979-01-01

    A rapid and simple clean-up and derivatization procedure that can be generally applied to the gas chromatographie (GC) determination of acidic drugs of various chemical and therapeutic classes is described. The drugs are extracted from acidified plasma with chloroform containing 5% of isopropanol, w

  8. Cleaning up: environmental services are bound to stay a growth industry

    Energy Technology Data Exchange (ETDEWEB)

    Stonehouse, D.

    2000-05-01

    Environmental protection regulations with particular regard for the oil and natural gas industry are reviewed. New flaring regulations will be reduced by 70 per cent within the next seven years and remaining flares will operate at nearly 100 per cent efficiency in burning harmful substances. The Canadian Council of Ministers of the Environment (CCME) is currently targeting other emission sources from oilfield equipment. Benzene emissions from glycol dehydrators will be reduced by 90 per cent by 2007. Soil remediation targets are also very ambitious. The standard is 1,000 parts per million of hydrocarbons. As an indication of the difficulties experienced by oil companies in land reclamation, one out of five topsoil replacement and revegetation applications have failed. As a result of these stringent regulations, a multi-billion dollar environmental industry has emerged, constantly searching for better and more cost effective ways to comply with rising standards. The most immediate challenge is to snuff out some 5,300 flare stacks. The science behind environmental protection is still weak and controversial, and satisfactory answers are still some years away; in the meantime oil companies must meet existing requirements, inventing new equipment and approaches in the process. Incineration may be one answer, but alternative approaches are also being investigated. Wellsite reclamation, cleaning up of exhausted fields, identifying and preserving wild animal habitats, protecting endangered species, accounting for human populations and their effects, greenhouse gas emissions and the complex issues of emissions trading and credits are just some of the issues that will ensure that environmental services will continue to be a growth industry.

  9. Bacterial adhesion to suture material in a contaminated wound model: Comparison of monofilament, braided, and barbed sutures.

    Science.gov (United States)

    Dhom, Jonas; Bloes, Dominik A; Peschel, Andreas; Hofmann, Ulf Krister

    2016-05-21

    Contaminated suture material plays an important role in the physiopathology of surgical site infections. Recently, suture material has been developed characterized by barbs projecting from a monofilament base. Claimed advantages for barbed sutures are a shortened wound closure time and reduced maximum wound tension. It has also been suggested that these sutures would be advantageous microbiologically. The aim of this study was to test the microbiological characteristics of the barbed Quill in comparison to the monofilament Ethilon II and the braided sutures Vicryl and triclosan-coated Vicryl Plus. In our study, sutures were cultivated on color-change agar with Staphylococcus aureus, Staphylococcus epidermidis, Enterococcus faecium, Escherichia coli, and Pseudomonas aeruginosa and the halo size was measured. In a second study arm with longer cultivation bacterial growth was followed by antibiotic treatment. Ethilon II and Quill showed good comparable results, whereas large halos were found around Vicryl. Vicryl Plus results depended on triclosan sensitivity. After longer bacterial cultivation and antibiotic treatment, halos were up to 3.6 times smaller on Quill than on Vicryl (P <.001), but 1.4 times larger than on Ethilon II (P <.001) regarding S. aureus. Confocal microscopy analysis showed bacterial colonization between the braided filaments on Vicryl and beneath the barbs on Quill. From a microbiological perspective, barbed sutures can be recommended in aseptic surgery, but should only be used carefully in septic surgery. This article is protected by copyright. All rights reserved.

  10. Policies to clean up toxic industrial contaminated sites of Gela and Priolo: a cost-benefit analysis.

    Science.gov (United States)

    Guerriero, Carla; Bianchi, Fabrizio; Cairns, John; Cori, Liliana

    2011-07-28

    Cost-benefit analysis is a transparent tool to inform policy makers about the potential effect of regulatory interventions, nevertheless its use to evaluate clean-up interventions in polluted industrial sites is limited. The two industrial areas of Gela and Priolo in Italy were declared "at high risk of environmental crisis" in 1990. Since then little has been done to clean the polluted sites and reduce the health outcomes attributable to pollution exposure. This study, aims to quantify the monetary benefits resulting from clean-up interventions in the contaminated sites of Gela and Priolo. A damage function approach was used to estimate the number of health outcomes attributable to industrial pollution exposure. Extensive one way analyses and probabilistic analyses were conducted to investigate the sensitivity of results to different model assumptions. It has been estimated that, on average, 47 cases of premature death, 281 cases of cancer and 2,702 cases of non-cancer hospital admission could be avoided each year by removing environmental exposure in these two areas. Assuming a 20 year cessation lag and a 4% discount rate we calculate that the potential monetary benefit of removing industrial pollution is €3,592 million in Priolo and €6,639 million in Gela. Given the annual number of health outcomes attributable to pollution exposure the effective clean-up of Gela and Priolo should be prioritised. This study suggests that clean-up policies costing up to €6,639 million in Gela and €3,592 million in Priolo would be cost beneficial. These two amounts are notably higher than the funds allocated thus far to clean up the two sites, €127.4 million in Gela and €774.5 million in Priolo, implying that further economic investments - even considerable ones - could still prove cost beneficial.

  11. Acetonitrile extraction and dual-layer solid phase extraction clean-up for pesticide residue analysis in propolis.

    Science.gov (United States)

    Oellig, Claudia

    2016-05-06

    Propolis is a very complex mixture of substances that is produced by honey bees and is known to be a rather challenging matrix for residue analysis. Besides resins, flavonoids and phenols, high amount of wax is co-extracted resulting in immense matrix effects. Therefore a suitable clean-up is crucial and indispensable. In this study, a reliable solid phase extraction (SPE) clean-up was developed for pesticide residue analysis in propolis. The clean-up success was quickly and easily monitored by high-performance thin-layer chromatography with different detection possibilities. The final method consists of the extraction of propolis with acetonitrile according to the QuEChERS method followed by an effective extract purification on dual-layer SPE cartridges with spherical hydrophobic polystyrene-divinylbenzene resin/primary secondary amine as sorbent and a mixture of toluene/acetone (95:5, v/v) for elution. Besides fat-soluble components like waxes, flavonoids, and terpenoids, more polar compounds like organic acids, fatty acids, sugars and anthocyanins were also removed to large extent. Method performance was assessed by recovery experiments at spiking levels of 0.5 and 1mg/kg (n=5) for fourteen pesticides that are relevant for propolis. Mean recoveries determined by HPLC-MS against solvent standards were between 40 and 101%, while calculation against matrix-matched standards provided recoveries of 79-104%. Precision of recovery, assessed by relative standard deviations, were below 9%. Thus, the developed dual-layer SPE clean-up enables the reliable pesticide residue analysis in propolis and provides a suitable alternative to time-consuming clean-up procedures proposed in literature.

  12. Experimental evaluation of horse hair as a nonabsorbable monofilament suture

    Directory of Open Access Journals (Sweden)

    Swati R Yedke

    2013-01-01

    Full Text Available Background: Success of surgery depends on wound closure and healing. Ancients had coated many suture materials from plant and animal origin. As the quest for natural nonabsorbable, monofilament surgical suture continues, horsehair has been taken for study, which is mentioned in ancient literature. Objectives: Aim of the study was to evaluate detail mechanical and biophysical properties of horsehair. Materials and Methods: Physical properties, that are diameter, straight pull and knot pull tensile strength, bioburden, sterility tests were performed. Visual and histological wound healing parameters were studied in experimental Wistar rat incision wound model. Two experimental wounds about 5 cm long were created on each side of dorsal midline. Each animal received two sutures-Horsehair 4-0 and Ethilon 4-0. The sutured areas were grossly examined on 3 rd and 7 th days for visual observations like congestion, edema, infection, wound disruption, and impression of suture material on healed wound and then subjected for histological study. Results: Revealed that horsehair has got diameter of 0.19 mm which complies with the 4-0 size USP standard. Straight pull tensile strength was found 0.5851 ± 0.122 kg and knot pull tensile strength was 0.3998 ± 0.078 kg, which complies with the standards of United State Pharmacopia for class II nonabsorbable suture materials. In vivo study revealed that there was no evidence of edema, congestion, and discharge in both the groups. Wounds healed with minimum impressions of suture material with minimum scar mark. Mean histological scoring shows very mild tissue reaction. Conclusion: Horsehair has got properties of standard suture material except low tensile strength and hence can be used in reconstructive, plastic surgeries, and ophthalmic surgeries.

  13. From conceptual model to remediation: bioavailability, a key to clean up heavy metal contaminated soils.

    Science.gov (United States)

    Petruzzelli, Gianniantonio; Pedron, Francesca; Pezzarossa, Beatrice

    2013-04-01

    Processes of metal bioavailability in the soil To know the bioavailability processes at site specific levels is essential to understand in detail the risks associated with pollution, and to support the decision-making process, i.e. description of the conceptual model and choice of clean up technologies. It is particularly important to assess how chemical, physical and biological processes in the soil affect the reactions leading to adsorption, precipitation or release of contaminants. The measurement of bioavailability One of the main difficulties in the practical application of the bioavailability concept in soil remediation is the lack of consensus on the method to be used to measure bioavailability. The best strategy is to apply a series of tests to assess bioavailability, since no applicable method is universally valid under all conditions. As an example, bioavailability tests for phytotechnology application should consider two distinct aspects: a physico-chemical driven solubilization process and a physiologically driven uptake process. Soil and plant characteristics strongly influence bioavailability. Bioavailability as a tool in remediation strategies Bioavailability can be used at all stages in remediation strategies: development of the conceptual model, evaluation of risk assessment, and selection of the best technology, considering different scenarios and including different environmental objectives. Two different strategies can be followed: the reduction and the increase of bioavailability. Procedures that reduce bioavailability aim to prevent the movement of pollutants from the soil to the living organisms, essentially by: i) removal of the labile phase of the contaminant, i.e. the fraction which is intrinsic to the processes of bioavailability (phytostabilization); ii) conversion of the labile fraction into a stable fraction (precipitation or adsorption); iii) increase of the resistance to mass transfer of the contaminants (inertization). Procedures

  14. HYDRAULIC ELEVATOR INSTALLATION ESTIMATION FOR THE WATER SOURCE WELL SAND-PACK CLEANING UP

    Directory of Open Access Journals (Sweden)

    V. V. Ivashechkin

    2016-01-01

    Full Text Available The article offers design of a hydraulic elevator installation for cleaning up water-source wells of sand packs. It considerers the installation hydraulic circuit according to which the normal pump feeds the high-level tank water into the borehole through two parallel water lines. The water-jet line with washing nozzle for destroying the sand-pack and the supply pipe-line coupled with the operational nozzle of the hydraulic elevator containing the inlet and the supply pipelines for respectively intaking the hydromixture and removing it from the well. The paper adduces equations for fluid motion in the supply and the water-jet pipelines and offers expressions for evaluating the required heads in them. For determining water flow in the supply and the water-jet pipe lines the author proposes to employ graphical approach allowing finding the regime point in Q–H chart by means of building characteristics of the pump and the pipe-lines. For calculating the useful vertical head, supply and dimensions of the hydraulic elevator the article employs the equation of motion quantity with consistency admission of the motion quantity before and after mixing the flows in the hydraulic elevator. The suggested correlations for evaluating the hydraulic elevator efficiency determine the sand pack removal duration as function of its sizes and the ejected fluid flow rate. A hydraulic-elevator installation parameters estimation example illustrates removing a sand pack from a water-source borehole of 41 m deep and 150 mm diameter bored in the village of Uzla of Myadelsk region, of Minsk oblast. The working efficiency of a manufactured and laboratory tested engineering prototype of the hydraulic elevator installation was acknowledged in actual tests at the indicated borehole site. With application of graphical approach, the suggested for the hydraulic elevator installation parameters calculation procedure allows selecting, with given depth and the borehole diameter

  15. Ultrasonic extraction followed by a novel filtration and clean-up device for screening of some polyphenols in tobaccos.

    Science.gov (United States)

    Gu, Xungang; Cai, Jibao; Yang, Jun; Su, Qingde

    2005-02-01

    A simple and efficient HPLC method using a diode array detector (DAD) was developed for simultaneous determination of six polyphenols in tobaccos. Ultrasonic extraction was employed at 25 degrees C to extract the polyphenols present in tobaccos into anhydrous methanol. A novel filtration device linked to a clean-up cartridge was designed for simultaneous extract filtration and clean-up. Optimized HPLC-DAD analysis, with multi-wavelength detection, was used for determination of the polyphenols. Because the content of some of the polyphenols is too low to be quantified directly, a concentration step was necessary. Anhydrous methanol was employed for extraction of the polyphenols because of its high extraction efficiency and its low boiling point in the concentration step. Using the proposed method, six polyphenols were quantified in tobaccos (Nicotina tobaccum L.).

  16. Analysis of polycyclic aromatic hydrocarbons in vegetable oils combining gel permeation chromatography with solid-phase extraction clean-up

    DEFF Research Database (Denmark)

    Fromberg, Arvid; Højgård, A.; Duedahl-Olesen, Lene

    2007-01-01

    of benzo[a]pyrene levels in foods laid down by the Commission of the European Communities. A survey of 69 vegetable oils sampled from the Danish market included olive oil as well as other vegetable oils such as rapeseed oil, sunflower oil, grape seed oil and sesame oil. Levels of benzo[a]pyrene in all......A semi-automatic method for the determination of polycyclic aromatic hydrocarbons (PAHs) in edible oils using a combined gel permeation chromatography/solid-phase extraction (GPC/SPE) clean-up is presented. The method takes advantage of automatic injections using a Gilson ASPEC XL sample handling...... system equipped with a GPC column (S-X3) and pre-packed silica SPE columns for the subsequent clean-up and finally gas chromatography-mass spectrometry (GC-MS) determination. The method was validated for the determination of PAHs in vegetable oils and it can meet the criteria for the official control...

  17. Clean-up of the sea bed in the North Sea 1996; Opprydding av havbunnen i Nordsjoeen 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-01-01

    The petroleum activities in the North Sea have inadvertently caused some conflict with fishermen getting their trawls etc. into trash from littering of the sea bed. In the present report, the Norwegian Petroleum Directorate describes a clean-up operation undertaken in 1996 and paid by the State. A clean-up area of 1000 km{sup 2} off Karmoey was selected. This area was mapped by side scan sonar along survey lines 300 m equidistant and a sonar range of 200 m. The sonar data were continuously interpreted by a geophysicist. Selected targets were then identified by ROV and eventually removed. Of the 59 targets examined, 11 were removed and dumped onshore. The largest part elevated was a chain cable of 9 tons. There is also a brief discussion of the compensation agreement with Norwegian fishermen. 4 figs.

  18. Long term evolution of recycled DIAMEX solvent properties under hydrolysis and radiolysis with or without solvent clean-up

    Energy Technology Data Exchange (ETDEWEB)

    Cames, B.; Saucerotte, B.; Faucon, M.; Rudloff, D.; Gastaldi, M.; Bisel, I

    2004-07-01

    As part of the SPIN program, CEA has developed DIAMEX process allowing co-extraction of actinides(III) and lanthanides(III) thanks to a diamide extractant, the Di-Methyl Di-Octyl Hexyl-Ethoxy Malonamide, symbolized by DMDOHEMA. Along the different process steps, diamide undergoes radiolytic and hydrolytic degradation leading to reaction products changing extraction performances and hydrodynamic behavior of the solvent. If to be industrially used, extractant has to be recycled. Therefore an alkaline solvent clean-up step has been defined to remove acidic degradation products whose modifying extraction properties. Nevertheless long-term recycling may allow accumulation of amounts of products which can influence process operating and separation performances. MARCEL is a laboratory scale bench mark, simulating chemical and radiolytic conditions of the process, designed for the long term evolution studies of the recycled solvent properties. Extraction, scrubbing and stripping are performed in mixer-settlers whereas centrifugal contactors are used for solvent clean-up. Different flow-sheets have been tested through various runs during about 200 hours each: - Hydrolysis with or without solvent clean-up; - Hydrolysis coupled with radiolysis with solvent clean-up. For each solvent cycle, DMDOHEMA undergoes a 2.5 hours hydrolysis at 40 deg C and, if radiolysis is studied, a 8.5 kGy exposure. Solvent properties have been followed-up by steady tests (viscosity, density, surface tension, refraction index, phase settling time ratio (RTD), distribution coefficients of several cations) and quantitative analysis of the degradation products. The efficiency and correct hydrodynamic behavior of the alkaline treatment has been shown, remaining hydrolysis and radiolysis degradation products having no significant influence on solvent properties. (authors)

  19. Evaluation of alternative PCB clean-up strategies using an individual-based population model of mink

    Energy Technology Data Exchange (ETDEWEB)

    Salice, Christopher J., E-mail: Chris.salice@ttu.edu [Department of Environmental Toxicology, Texas Tech University, Lubbock, TX 79410 (United States); Sample, Bradley E., E-mail: bsample@ecorisk.com [Ecological Risk Inc., Rancho Murieta, CA 95683 (United States); Miller Neilan, Rachael; Rose, Kenneth A.; Sable, Shaye [Department of Oceanography and Coastal Sciences, Energy, Coast and Environment Building, Louisiana State University, Baton Rouge, LA 70803 (United States)

    2011-12-15

    Population models can be used to place observed toxic effects into an assessment of the impacts on population-level endpoints, which are generally considered to provide greater ecological insight and relevance. We used an individual-based model of mink to evaluate the population-level effects of exposure to polychlorinated biphenyls (PCBs) and the impact that different remediation strategies had on mink population endpoints (population size and extinction risk). Our simulations indicated that the initial population size had a strong impact on mink population dynamics. In addition, mink populations were extremely responsive to clean-up scenarios that were initiated soon after the contamination event. In fact, the rate of PCB clean-up did not have as strong a positive effect on mink as did the initiation of clean-up (start time). We show that population-level approaches can be used to understand adverse effects of contamination and to also explore the potential benefits of various remediation strategies. - Highlights: > We used an individual-based model of mink to evaluate population-level impacts of PCB contamination. > The model was also used to explore the population responses to different PCB remediation strategies. > Population size had a large impact on whether mink populations persisted or went extinct. > Starting remediation sooner had a stronger positive effect on mink populations than did the rate of PCB clean-up. > Individual-based models are useful in understanding effects of contamination and different remediation strategies. - An individual-based model of mink showed strong population-level effects of PCB contamination and provided insight into optimal PCB remediation strategies.

  20. Mechanical comparison of monofilament nylon leader and orthopaedic wire for median sternotomy closure.

    Science.gov (United States)

    McCready, D J; Bell, J C; Ness, M G; Tarlton, J F

    2015-08-01

    To compare the mechanical properties of monofilament nylon leader and orthopaedic wire for median sternotomy closure in the dog. Median sternotomy was performed in 14 canine cadaver sternums with the manubrium intact. The sternotomy was closed with either 80 lb monofilament nylon leader or 20G orthopaedic stainless steel wire in a peristernal figure of 8 pattern. Constructs were loaded in a servohydraulic material testing machine. Load at yield, maximum load, stiffness, displacement and mode of failure were compared between constructs subjected to a single cycle load to failure. No significant differences were found in load at yield, maximum load, stiffness or displacement between the monofilament nylon leader and the stainless steel wire constructs. No implant failure was evident in the stainless steel wire constructs. Four of the monofilament nylon leader constructs failed by pulling of the nylon through the crimp. Monofilament nylon leader is mechanically comparable to stainless steel wire and potentially a suitable alternative for closure of median sternotomy in the dog. © 2015 British Small Animal Veterinary Association.

  1. Novel fracture technology proves marginal Viking prospect economic, part II: Well clean-up, flowback and testing

    Energy Technology Data Exchange (ETDEWEB)

    Haidar, S.; Rylance, M.; Tybero, G. [and others

    1996-12-31

    Having completed both fracture treatments as discussed in a companion paper, this paper continues on to describe the post fracture shut-in, clean-up and well testing operations that took place on the Viking Wx exploration well 49/17-12. These operations involved the removal of Resin Coated Proppant (RCP) from the wellbore, via Coiled Tubing (CT), through the use of a specially designed jetting nozzle. The RCP pack stability at a concentration of 3.0 lb/ft{sup 2} (as per planned design) had already been tested in a flowback cell. The use of a Surface Read-Out (SRO) gauge, combined with gas, water and proppant flow rates as well as the viscosity of fracturing fluids returns, enabled real time calculation of the drag forces, on the proppant pack, during clean-up. The flow rate, in the field, was controlled such that the calculated drag forces remained below those observed in the laboratory. Following the clean-up a flow and build-up test was conducted, to evaluate the fracture half length and fracture conductivity, from which a Pseudo-radial skin was calculated. The Non-Darcy effects in the fracture were also evaluated, and finally the short term and long term well deliverabilities were assessed.

  2. Evaluation of the persistence of functional and biological respiratory health effects in clean-up workers 6 years after the Prestige oil spill.

    NARCIS (Netherlands)

    Zock, J.P.; Rodríguez-Trigo, G.; Rodríguez-Rodríguez, E.; Souto-Alonso, A.; Espinosa, A.; Pozo-Rodríguez, F.; Gómez, F.P.; Fuster, C.; Castaño-Vinyals, G.; Antó, J.M.; Barberà, J.A.

    2014-01-01

    Fishermen who had participated in clean-up activities of the Prestige oil spill showed increased bronchial responsiveness and higher levels of respiratory biomarkers 2years later. We aimed to evaluate the persistence of these functional and biological respiratory health effects 6years after clean-up

  3. Environmental remediation 1991: ``Cleaning up the environment for the 21st Century``. Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Wood, D.E. [ed.] [Westinghouse Hanford Co., Richland, WA (United States)

    1991-12-31

    This report presents discussions given at a conference on environmental remediation, September 8--11, Pasco, Washington. Topics include: public confidence; education; in-situ remediation; Hanford tank operations; risk assessments; field experiences; standards; site characterization and monitoring; technology discussions; regulatory issues; compliance; and the UMTRA project. Individual projects are processed separately for the data bases.

  4. Absorbent pads for Containment, Neutralization, and Clean-Up of Environmental Spills Containing Chemically-Reactive Agents

    Science.gov (United States)

    Davis, Dennis D. (Inventor)

    1997-01-01

    A pad for cleaning up liquid spills is described which contains a porous surface covering, and an absorbent interior containing chemically reactive reagents for neutralizing noxious chemicals within the spilled liquid. The porous surface and the absorbent component would normally consist of chemically resistant materials allowing tentative spill to pass. The absorbent interior which contains the neutralizing reagents can but is not required to be chemically resilient and conducts the liquid chemical spill towards the absorbent interior containing the chemically reactive reagents where the dangerous and undesirable chemicals within the chemical spill are then neutralized as well as removed from the premises.

  5. Quantifying allodynia in patients suffering from unilateral neuropathic pain using Von Frey monofilaments

    NARCIS (Netherlands)

    Keizer, D.; van Wijhe, M.; Post, W.J.; Wierda, J.M.K.H.

    Objectives: The aim of this study is to investigate whether quantitative sensory testing with Von Frey monofilaments (VFMs) can be used for the quantification of allodynia in patients with chronic neuropathic pain, and how the pain threshold of affected skin differs from healthy skin. Methods: Using

  6. Quantifying allodynia in patients suffering from unilateral neuropathic pain using Von Frey monofilaments

    NARCIS (Netherlands)

    Keizer, D.; van Wijhe, M.; Post, W.J.; Wierda, J.M.K.H.

    2007-01-01

    Objectives: The aim of this study is to investigate whether quantitative sensory testing with Von Frey monofilaments (VFMs) can be used for the quantification of allodynia in patients with chronic neuropathic pain, and how the pain threshold of affected skin differs from healthy skin. Methods: Using

  7. Evaluation of early phase nuclear accident clean-up procedures for Nordic residential areas

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, K.G. [Risoe National Lab., Roskilde (Denmark)

    1996-12-01

    The work reported was carried out as a part of the EKO-5 project under the framework of the Nordic co-operative NKS programme. The project is aimed at giving guidelines relating to Nordic conditions for the reduction of external doses in the early phase of a major accidental airborne nuclear contamination (essentially with {sup 137}Cs) situation in urban areas. The material in this report describes the expected effects, in terms of immediate dose rate reduction and of reduction of the integrated doses over 70 years, of implementation of the methods which were considered to be feasible for early phase treatment of contaminated urban surfaces. Also given are estimates of the integrated doses if no action were taken. The given estimates were based on the experience obtained through large amounts of in situ measurements on different types of surface, mainly since the Chernobyl accident in 1986. The computer model URGENT, was used to apply the information on the migration of the radioactive material with time, together with the results of Monte Carlo photon transport calculations, for the time-integrated dose estimates. 66 data sheets describe the beneficial effects, costs and disadvantages of application of a feasible method for cleaning in the early phase of a specific type of surface in one of five different urban or suburban environments. These data form the foundation for the recommendations on guidelines, which are the ultimate goal of the EKO-5 project. References are given to recommended supplementary reading. (EG).

  8. Comparison of Two Procedures for Extraction and Clean-up of Organophosphorus and Pyrethroid Pesticides in Sediment

    Institute of Scientific and Technical Information of China (English)

    WANG Li-Gang; JIANG Xin; YAN Dong-Yun; S.FORSTER; D.MARTENS

    2004-01-01

    Two procedures were compared for extraction and clean-up of 20 organophosphorus and 19 pyrethroid pesticides in sediment to identify the more effective procedure for groups of pesticides or individual compounds. In Procedure Ⅰ,methanol/water and n-hexane were used for extraction,and 1:10 (v/v) dichloromethane in n-hexane and acetone were used as eluents for eluting the analyte through the cartridge,with one evaporating steps on a rotary evaporator and two eluting steps on the cartridge. n-hexane/acetone (2:1,v/v) was used for extraction and elution in Procedure Ⅱ with one evaporating step on a rotary evaporator and one eluting step on the cartridge. All extractions were performed under an ultrasonic bath and gas chromatography and mass spectrometry were utilized for measurements. Procedure Ⅱ was developed as a rapid,timesaving,less costly and safer substitute for Procedure Ⅰ which was an old method. Procedure Ⅱ was more effective for ahnost all the organophosphorus pesticides tested and 11 of the 19 pyrethroid pesticides,while Procedure Ⅰ was more appropriate for analysis of 5 pyrethroid pesticides. However,recoveries of most pyrethroid pesticides were fairly low. Thus,further studies should focus on adjustment and formulation of solvents for more efficient extraction and clean-up of pyrethroid pesticides from sediment samples.

  9. A novel polymer inclusion membrane based method for continuous clean-up of thiocyanate from gold mine tailings water.

    Science.gov (United States)

    Cho, Youngsoo; Cattrall, Robert W; Kolev, Spas D

    2018-01-05

    Thiocyanate is present in gold mine tailings waters in concentrations up to 1000mgL(-1) and this has a serious environmental impact by not allowing water reuse in the flotation of gold ore. This significantly increases the consumption of fresh water and the amount of wastewater discharged in tailings dams. At the same time thiocyanate in tailings waters often leads to groundwater contamination. A novel continuous membrane-based method for the complete clean-up of thiocyanate in concentrations as high as 1000mgL(-1) from its aqueous solutions has been developed. It employs a flat sheet polymer inclusion membrane (PIM) of composition 70wt% PVC, 20wt% Aliquat 336 and 10wt% 1-tetradecanol which separates counter-current streams of a feed thiocyanate solution and a 1M NaNO3 receiving solution. The PIM-based system has been operated continuously for 45days with 99% separation efficiency. The volume of the receiving solution has been drastically reduced by recirculating it and continuously removing thiocyanate by precipitating it with in-situ generated Cu(I). The newly developed PIM-based thiocyanate clean-up method is environmentally friendly in terms of reagent use and inexpensive with respect to both equipment and running costs. Copyright © 2017 Elsevier B.V. All rights reserved.

  10. Application of single immunoaffinity clean-up for simultaneous determination of regulated mycotoxins in cereals and nuts.

    Science.gov (United States)

    Vaclavikova, Marta; MacMahon, Shaun; Zhang, Kai; Begley, Timothy H

    2013-12-15

    A rapid and sensitive analytical strategy for the simultaneous determination of twelve mycotoxins (aflatoxins, fumonisins, zearalenon, deoxynivalenol, ochratoxin A, T-2 and HT-2 toxins) using ultra-high performance liquid chromatography coupled to tandem mass spectrometry (UHPLC-MS/MS) was developed and validated. The method was validated for peanuts, barley and maize-breakfast cereals; selected as they represent the matrices most often contaminated by mycotoxins. The method is designed for fast and reliable analyses of mycotoxins in regulatory, industrial and private laboratories. Multi-target immunoaffinity columns containing antibodies for all mycotoxins studied herein were used for sample clean-up. Method optimization was predominantly focused on the simplification of extraction and clean-up procedure recommended by column producers. This newly developed and simplified procedure decreased both the sample preparation time and the solvent volumes used for their processing. The analysis of all regulated mycotoxins was conducted by a newly developed UHPLC-MS/MS method with a sample run time of only ten minutes. The method trueness was tested with analytical spikes and certified reference materials, with recoveries ranging from 71% to 112% for all of the examined mycotoxins.

  11. In-Cell Clean-Up Pressurised Liquid Extraction Method to Determine Pesticides in Mushroom Compost by Gas Chromatography-Tandem Mass Spectrometry

    OpenAIRE

    María Teresa Tena; María Pilar Martínez-Moral; Patricia Labarta

    2012-01-01

    A fast, simple, and easily automated method for the determination of two insecticides, diazinon and deltamethrin, and two fungicides, iprodione and prochloraz, in mushroom cultivation compost samples, based on selective pressurised liquid extraction (SPLE) and gas chromatography coupled to tandem mass spectrometry, is presented. The proposed method integrates extraction and clean-up processes in one single step, by adding a clean-up sorbent into the extraction cell. SPLE variables were thorou...

  12. International Seminar on Gasification 2009 - Biomass Gasification, Gas Clean-up and Gas Treatment

    Energy Technology Data Exchange (ETDEWEB)

    2009-10-15

    During the seminar international and national experts gave presentations concerning Biomass gasification, Gas cleaning and gas treatment; and Strategy and policy issues. The presentations give an overview of the current status and what to be expected in terms of development, industrial interest and commercialization of different biomass gasification routes. The following PPT presentations are reproduced in the report: Black Liquor Gasification (Chemrec AB.); Gasification and Alternative Feedstocks for the Production of Synfuels and 2nd Generation Biofuels (Lurgi GmbH); Commercial Scale BtL Production on the Verge of Becoming Reality (Choren Industries GmbH.); Up-draft Biomass Gasification (Babcock and Wilcox Voelund A/S); Heterogeneous Biomass Residues and the Catalytic Synthesis of Alcohols (Enerkem); Status of the GoBiGas-project (Goeteborg Energi AB.); On-going Gasification Activities in Spain (University of Zaragoza,); Biomass Gasification Research in Italy (University of Perugia.); RDandD Needs and Recommendations for the Commercialization of High-efficient Bio-SNG (Energy Research Centre of the Netherlands.); Cleaning and Usage of Product Gas from Biomass Steam Gasification (Vienna University of Technology); Biomass Gasification and Catalytic Tar Cracking Process Development (Research Triangle Institute); Syngas Cleaning with Catalytic Tar Reforming (Franhofer UMSICHT); Biomass Gas Cleaning and Utilization - The Topsoee Perspective (Haldor Topsoee A/S); OLGA Tar Removal Technology (Dahlman); Bio-SNG - Strategy and Activities within E.ON (E.ON Ruhrgas AG); Strategy and Gasification Activities within Sweden (Swedish Energy Agency); 20 TWh/year Biomethane (Swedish Gas Association)

  13. Sorption Mechanisms for Mercury Capture in Warm Post-Gasification Gas Clean-Up Systems

    Energy Technology Data Exchange (ETDEWEB)

    Jost Wendt; Sung Jun Lee; Paul Blowers

    2008-09-30

    The research was directed towards a sorbent injection/particle removal process where a sorbent may be injected upstream of the warm gas cleanup system to scavenge Hg and other trace metals, and removed (with the metals) within the warm gas cleanup process. The specific objectives of this project were to understand and quantify, through fundamentally based models, mechanisms of interaction between mercury vapor compounds and novel paper waste derived (kaolinite + calcium based) sorbents (currently marketed under the trade name MinPlus). The portion of the research described first is the experimental portion, in which sorbent effectiveness to scavenge metallic mercury (Hg{sup 0}) at high temperatures (>600 C) is determined as a function of temperature, sorbent loading, gas composition, and other important parameters. Levels of Hg{sup 0} investigated were in an industrially relevant range ({approx} 25 {micro}g/m{sup 3}) although contaminants were contained in synthetic gases and not in actual flue gases. A later section of this report contains the results of the complementary computational results.

  14. Impact of oil spill and posterior clean-up activities on wrack-living talitrid amphipods on estuarine beaches

    Directory of Open Access Journals (Sweden)

    Carlos A. Borzone

    2009-12-01

    Full Text Available A geomorphological and faunistic seasonal study of six estuarine beaches on Paranaguá Bay, Brazil, was abruptly interrupted when the Chilean ship "Vicuña" exploded and sank, spilling 291 tons of bunker fuel oil. The beaches sampled twice before the accident were affected by the oil spill deposition and the posterior clean-up activities. Neither drastic reduction in abundances nor occurrences of oil-covered individuals were registered. Significant variation in both amount of debris and talitrid amphipod densities was directly related to beach clean-up activities. A short (1-3 month manual clean-up of polluted wrack resulted in an increase in talitrid abundances, with the local distribution expansion of one species, Platorchestia monodi, from three to six of the beaches sampled. The active migration and concentration of organisms at sites without wrack during cleaning activities and a massive and continuous recovery of new debris, characteristic of estuarine beaches, may contribute to the findings.Um estudo sazonal da geomorfologia e fauna de seis praias estuarinas na baia de Paranaguá, Brasil, foi interrompido bruscamente pela explosão e posterior afundamento do navio chileno Vicuña, que derramou 291 toneladas de óleo bunker. As praias que foram afetadas pela deposição de óleo e pelas posteriores atividades de limpeza, tinham sido amostradas duas vezes antes do acidente. Nas coletas posteriores ao acidente não foram registradas nem reduções drásticas das abundâncias nem indivíduos impregnados por óleo. As significativas variações tanto da quantidade de detrito quanto nas densidades de anfipodes talitrídeos foram relacionadas às atividades de limpeza. Uma limpeza manual e de curta duração (1 a 3 meses resultou num aumento das abundâncias dos talitrídeos, juntamente com o aumento da distribuição de uma das espécies, Platorchestia monodi, que de três passou a ser encontrada em seis praias amostradas.Os fatores que

  15. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    The SNRB{trademark} Flue Gas Cleanup Demonstration Project was cooperatively funded by the U.S. Department of Energy (DOE), the Ohio Coal Development Office (OCDO), B&W, the Electric Power Research Institute (EPRI), Ohio Edison, Norton Chemical Process Products Company and the 3M Company. The SNRB{trademark} technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. Development of the SNRB{trademark} process at B&W began with pilot testing of high-temperature dry sorbent injection for SO{sub 2} removal in the 1960`s. Integration of NO{sub x} reduction was evaluated in the 1970`s. Pilot work in the 1980`s focused on evaluation of various NO{sub x} reduction catalysts, SO{sub 2} sorbents and integration of the catalyst with the baghouse. This early development work led to the issuance of two US process patents to B&W - No. 4,309,386 and No. 4,793,981. An additional patent application for improvements to the process is pending. The OCDO was instrumental in working with B&W to develop the process to the point where a larger scale demonstration of the technology was feasible. This report represents the completion of Milestone M14 as specified in the Work Plan. B&W tested the SNRB{trademark} pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R. E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B&W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB{trademark} process. The SNRB{trademark} facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993.

  16. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    The SNRB{trademark} Flue Gas Cleanup Demonstration Project was cooperatively funded by the U.S. Department of Energy (DOE), the Ohio Coal Development Office (OCDO), B&W, the Electric Power Research Institute (EPRI), Ohio Edison, Norton Chemical Process Products Company and the 3M Company. The SNRB{trademark} technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. Development of the SNRB{trademark} process at B&W began with pilot testing of high-temperature dry sorbent injection for SO{sub 2} removal in the 1960`s. Integration of NO{sub x} reduction was evaluated in the 1970`s. Pilot work in the 1980`s focused on evaluation of various NO{sub x} reduction catalysts, SO{sub 2} sorbents and integration of the catalyst with the baghouse. This early development work led to the issuance of two US process patents to B&W - No. 4,309,386 and No. 4,793,981. An additional patent application for improvements to the process is pending. The OCDO was instrumental in working with B&W to develop the process to the point where a larger scale demonstration of the technology was feasible. This report represents the completion of Milestone M14 as specified in the Work Plan. B&W tested the SNRB{trademark} pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R. E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B&W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB{trademark} process. The SNRB{trademark} facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993.

  17. A systematic assessment of the state of hazardous waste clean-up technologies. Quarterly technical progress report, April 1--June 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Berg, M.T.; Reed, B.E.; Gabr, M.

    1993-07-01

    West Virginia University (WVU) and the US DOE Morgantown Energy Technology Center (METC) entered into a Cooperative Agreement on August 29, 1992 entitled ``Decontamination Systems Information and Research Programs.`` Stipulated within the Agreement is the requirement that WVU submit to METC a series of Technical Progress Report for Year 1 of the Agreement. This report reflects the progress and/or efforts performed on the following nine technical projects encompassed by the Year 1 Agreement for the period of April 1 through June 30, 1993: Systematic assessment of the state of hazardous waste clean-up technologies; site remediation technologies -- drain-enhanced soil flushing (DESF) for organic contaminants removal; site remediation technologies -- in situ bioremediation of organic contaminants; excavation systems for hazardous waste sites; chemical destruction of polychlorinated biphenyls; development of organic sensors -- monolayer and multilayer self-assembled films for chemical sensors; Winfield lock and dam remediation; Assessments of Technologies for hazardous waste site remediation -- non-treatment technologies and pilot scale test facility implementation; and remediation of hazardous sites with stream reforming.

  18. A new multiple-stage electrocoagulation process on anaerobic digestion effluent to simultaneously reclaim water and clean up biogas.

    Science.gov (United States)

    Liu, Zhiguo; Stromberg, David; Liu, Xuming; Liao, Wei; Liu, Yan

    2015-03-21

    A new multiple-stage treatment process was developed via integrating electrocoagulation with biogas pumping to simultaneously reclaim anaerobic digestion effluent and clean up biogas. The 1st stage of electrocoagulation treatment under the preferred reaction condition led to removal efficiencies of 30%, 81%, 37% and >99.9% for total solids, chemical oxygen demand, total nitrogen and total phosphorus, respectively. Raw biogas was then used as a reactant and pumped into the effluent to simultaneously neutralize pH of the effluent and remove H2S in the biogas. The 2nd stage of electrocoagulation treatment on the neutralized effluent showed that under the selected reaction condition, additional 60% and 10% of turbidity and chemical oxygen demand were further removed. The study concluded a dual-purpose approach for the first time to synergistically combine biogas purification and water reclamation for anaerobic digestion system, which well addresses the downstream challenges of anaerobic digestion technology.

  19. Effective clean-up and ultra high-performance liquid chromatography-tandem mass spectrometry for isoflavone determination in legumes.

    Science.gov (United States)

    Vila-Donat, Pilar; Caprioli, Giovanni; Maggi, Filippo; Ricciutelli, Massimo; Torregiani, Elisabetta; Vittori, Sauro; Sagratini, Gianni

    2015-05-01

    Legumes are an excellent source of macronutrients and phytochemicals as isoflavones. The aim of this work was to develop a new analytical method for determining five isoflavone compounds, three of which are aglycons, namely daidzein, genistein, biochanin A, and two of which, daidzin and genistin, are glycosilated, in lentils and other pulses, using an effective clean-up system and UHPLC-MS/MS (triple quadrupole) method. The recoveries obtained by spiking the lentil samples with a standard mixture of isoflavones at three levels of fortification (5, 25 and 100 μg kg(-1)) were in the range of 54.4-111.1%, 68.6-91.1%, and 84.4-114%, respectively. The method was applied to analyse 48 lentil samples from central Italy and pulses for determining the isoflavone content, which was found to range from 1.1 to 95.6 μg kg(-1).

  20. Application of zirconium dioxide nanoparticle sorbent for the clean-up step in post-harvest pesticide residue analysis.

    Science.gov (United States)

    Uclés, Ana; Herrera López, Sonia; Dolores Hernando, Maria; Rosal, Roberto; Ferrer, Carmen; Fernández-Alba, Amadeo R

    2015-11-01

    The use of yttria-stabilized zirconium dioxide nanoparticles as d-SPE clean-up sorbent for a rapid and sensitive liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS/MS) method for the determination of post-harvest fungicides (carbaryl, carbendazim, chlorpropham, diphenylamine, ethoxyquin, flutriafol, imazalil, iprodione, methomyl, myclobutanil, pirimiphos-methyl, prochloraz, pyrimethanil, thiabendazole, thiophanate-methyl and tolclofos-methyl) in orange and pear samples has been evaluated and validated. The sample preparation was a modification of the QuEChERS extraction method using yttria-stabilized zirconium dioxide and multi-walled carbon nanotubes (MWCNTs) nanoparticles as the solid phase extraction (d-SPE) clean-up sorbents prior to injecting the ten-fold diluted extracts into the LC system. By using the yttria-stabilized zirconium dioxide extraction method, more recoveries in the 70-120% range were obtained - thus this method was used for the validation. Quantification was carried out using a matrix-matched calibration curve which was linear in the 1-500 µg kg(-1) range for almost all the pesticides studied. The validated limit of quantification was 10 µg kg(-1) for most of the studied compounds, except chlorpropham, ethoxyquin and thiophanate-methyl. Pesticide recoveries at the 10 and 100 µg kg(-1) concentration levels were satisfactory, with values between 77% and 120% and relative standard deviations (RSD) lower than 10% (n=5). The developed method was applied for the determination of selected fungicides in 20 real orange and pear samples. Four different pesticide residues were detected in 10 of these commodities; 20% of the samples contained pesticide residues at a quantifiable level (equal to or above the LOQs) for at least one pesticide residue. The most frequently-detected pesticide residues were: carbendazim, thiabendazole and imazalil-all were below the MRL. The highest concentration found was imazalil at 1175 µg kg

  1. Evaluation of the persistence of functional and biological respiratory health effects in clean-up workers 6 years after the prestige oil spill.

    Science.gov (United States)

    Zock, Jan-Paul; Rodríguez-Trigo, Gema; Rodríguez-Rodríguez, Emma; Souto-Alonso, Ana; Espinosa, Ana; Pozo-Rodríguez, Francisco; Gómez, Federico P; Fuster, Carme; Castaño-Vinyals, Gemma; Antó, Josep Maria; Barberà, Joan Albert

    2014-01-01

    Fishermen who had participated in clean-up activities of the Prestige oil spill showed increased bronchial responsiveness and higher levels of respiratory biomarkers 2 years later. We aimed to evaluate the persistence of these functional and biological respiratory health effects 6 years after clean-up work. In 2008/2009 a follow-up study was done in 230 never-smoking fishermen who had been exposed to clean-up work in 2002/2003 and 87 non-exposed fishermen. Lung function and bronchial responsiveness testing and the determination of respiratory biomarkers in exhaled breath condensate were done identically as in the baseline survey in 2004/2005. Associations between participation in clean-up work and respiratory health parameters were assessed using linear and logistic regression analyses adjusting for sex and age. Information from 158 exposed (69%) and 57 non-exposed (66%) fishermen was obtained. Loss to follow-up in the non-exposed was characterised by less respiratory symptoms at baseline. During the 4-year follow-up period lung function, bronchial hyperresponsiveness and the levels of respiratory biomarkers of oxidative stress and growth factors had deteriorated notably more among non-exposed than among exposed. At follow-up, respiratory health indices were similar or better in clean-up workers than in non-exposed. No clear differences between highly exposed and moderately exposed clean-up workers were found. In conclusion, we could not detect long-term respiratory health effects in clean-up workers 6 years after the Prestige oil spill. Methodological issues that need to be considered in this type of studies include the choice of a non-exposed control group and limitation of follow-up to subgroups such as never smokers.

  2. Effect of Sizing on the Interfacial Shear Strength of Carbon Fiber/Epoxy Resin Monofilament Composite

    Institute of Scientific and Technical Information of China (English)

    YANG Yusong; ZHAO Yan; LI Ye; DONG Qi; CHEN Da

    2014-01-01

    The single fiber fragmentation test (SFFT) was used to measure the interfacial shear strength (IFSS) of sized and unsized CF800/epoxy resin monofilament composite in order to evaluate the effect of sizing respectively. Besides, the interfacial reinforcing mechanism was explored by analyzing the surface morphology of the carbon fibers, the wettability between the carbon fibers and the epoxy resin, and the chemical characteristics of the fiber surface. Moreover, the effect of sizing on heat and humidity resistance of interface was investigated by aging test. The results show that sizing improves IFSS of CF800/epoxy resin monofilament composite by 59% through increasing the functional groups containing oxygen and through enhancing wettability, while after sizing the heat and humidity resistance of interface is decreased.

  3. Multifunctional resistive-heating and color-changing monofilaments produced by a single-step coaxial melt-spinning process.

    Science.gov (United States)

    Laforgue, Alexis; Rouget, Geoffroy; Dubost, Sylvain; Champagne, Michel F; Robitaille, Lucie

    2012-06-27

    Multifunctional coaxial monofilaments were successfully produced by melt-spinning several polymer composites in a single-step. The external layer of the monofilaments was a thermochromic composite having a color-transition at 40 °C (above the ambient temperature) in order to avoid control interferences by the external temperature. The core layer of the monofilaments was a conductive polymer nanocomposite whose resistive heating properties were used to control the monofilament's temperature and therefore its color using electrical current. The careful selection of the materials and adequate formulation allowed to obtain a trilayer structure with enhanced compatibility between the layers. The mechanical properties of the monofilaments were improved by a solid-state stretching step while also decreasing their diameter. A 64 cm(2) prototype fabric was woven to characterize the resistive-heating and color-changing properties of the monofilaments. Exceptional thermal output levels were reached, with a temperature rising up to over 100 °C at voltages above 110 V. The reversible color change properties were also successfully demonstrated.

  4. Cleaning up dark matter

    CERN Multimedia

    Bignami, Giovanni Fabrizio

    2006-01-01

    "An experiment in Italy has found tantalizing but puzzling evidence for axions, one if the leading candidates for dark matter. The authors explain how a pair of spinning neutron stars should settle the issue once and for all." (3 pages)

  5. Application of boreal forest toxicity data in the decision-making process for contaminated soil clean-up remediation at oil and gas fields in Western Canada

    Energy Technology Data Exchange (ETDEWEB)

    Scroggins, R.; Princz, J. [Environment Canada, Ottawa, ON (Canada); Moody, M. [Saskatchewan Research Council, Regina, SK (Canada); Olsgard-Dumanski, M.; Haderlein, L. [WorleyParsons Canada, Calgary, AB (Canada); Moore, B. [Devon Canada Corp., Calgary, AB (Canada)

    2010-07-01

    This presentation reported on a multi-year research project in which a broad range of boreal forest test methods for assessing petroleum hydrocarbon (PHC) toxicity in contaminated soil were used to show that clean-up decisions can be made on a field-wide basis through focused biological testing of typical drill sump and flare pit locations within an oil and gas field. Remediation at most sites will likely be limited to the Alberta soil eco-contact guidelines for PHC F2 and F3 fractions. Since Tier 1 eco-contact guidelines are derived using toxicity data from fresh crude and using agricultural plant species, it was more logical to follow a Tier 2 eco-contact pathway approach because most contamination was related to drilling sumps and flare pits containing highly weathered PHCs and species native to the boreal eco-zone of Canada. The site-specific remedial objective (SSRO) option within the Tier 2 guideline was used because of the large number of sites requiring remediation, and the similarity of sites within pre-determined Risk Assessment Zones. For representative contaminated soils, a SSRO was derived from the twenty-fifth percentile of the estimated species sensitivity distribution of all acceptable boreal plant, earthworm, springtail and mite test endpoints. The purpose of the project was to reduce soil volumes sent to landfill during site remediation by showing that residual impacts from weathered PHC in soil do not have damaging effects on boreal forest receptors following remediation. Data was included to show the value of this approach and the variability between sites and their effect on regionalizing a Tier 2 eco-contact guideline.

  6. Electrical field assisted matrix solid phase dispersion as a powerful tool to improve the extraction efficiency and clean-up of fluoroquinolones in bovine milk.

    Science.gov (United States)

    da Silva, Mariana Cristina; Orlando, Ricardo Mathias; Faria, Adriana Ferreira

    2016-08-26

    This work presents a new method by electrical matrix solid phase dispersion for the extraction and clean-up of marbofloxacin, ofloxacin, norfloxacin, ciprofloxacin, enrofloxacin, difloxacin and sarafloxacin in bovine milk. Composition and pH of the eluent, applied electrical potential and polarity were optimized by experimental designs. The combination of the chromatographic and electrophoretic mechanisms allowed the extraction and clean-up in one step with low organic solvent consumption, high extraction throughput and elution automation. Linearity, precision, trueness and limit of quantification were evaluated and provided values in accordance with other methods recently developed for the analysis of fluoroquinolones in milk. This technique proved to be promising for the extraction and clean-up of ionizable analytes in different milk matrices. Copyright © 2016 Elsevier B.V. All rights reserved.

  7. Optimization of solid phase extraction clean up and validation of quantitative determination of corticosteroids in urine by liquid chromatography-tandem mass spectrometry

    DEFF Research Database (Denmark)

    Andersen, Jens Hinge; Hansen, Lene Gram; Pedersen, Mikael

    2008-01-01

    A solid phase extraction (SPE) method for extraction and clean up of 9 synthetic corticosteroids was optimized for quantification by reversed-phase high-performance liquid chromatography/negative electrospray ionisation mass spectrometry. Clean up was accomplished using a mixed mode polymeric...... strong anion exchange SPE column. The final method was validated according to EU regulations for determination of residues of veterinarian drugs in products of animal origin. Initial results showed a large difference in ion suppression between samples of porcine and bovine urine. The aim of optimisation...

  8. Mercury and Cyanide Contaminations in Gold Mine Environment and Possible Solution of Cleaning Up by Using Phytoextraction

    Directory of Open Access Journals (Sweden)

    NURIL HIDAYATI

    2009-09-01

    Full Text Available Water contamination with heavy metals, mainly mercury and cyanide (CN due to small scale of public mines and large scale of industrial mines have been in concern to residents around the area. Surveys of heavy metal contamination in aquatic environments, such as rivers and paddy fields over two gold mine areas in West Jawa were conducted and possible solution of using indigenous plants for phytoremediation was studied. The results showed that most of the rivers and other aquatic environments were affected by gold mine activities. Rivers, ponds, and paddy fields around illegal public mines were mostly contaminated by mercury in considerably high levels, such as paddy fields in two locations (Nunggul and Leuwijamang, Pongkor were contaminated up to 22.68 and 7.73 ppm of Hg, respectively. Whereas rivers located around large scale industrial mines were contaminated by CN. Possible solution of cleaning up by using green technology of phytoremediation was examined. Some plant species grew in the contaminated sites showed high tolerance and potentially effective in accumulating cyanide or mercury in their roots and above ground portions. Lindernia crustacea (L. F.M., Digitaria radicosa (Presl Miq, Paspalum conjugatum, Cyperus kyllingia accumulated 89.13, 50.93, 1.78, and 0.77 ppm of Hg, respectively. Whereas, Paspalum conjugatum, Cyperus kyllingia accumulated 16.52 and 33. 16 ppm of CN respectively.

  9. Physicochemical regeneration of high silica zeolite Y used to clean-up water polluted with sulfonamide antibiotics.

    Science.gov (United States)

    Braschi, I; Blasioli, S; Buscaroli, E; Montecchio, D; Martucci, A

    2016-05-01

    High silica zeolite Y has been positively evaluated to clean-up water polluted with sulfonamides, an antibiotic family which is known to be involved in the antibiotic resistance evolution. To define possible strategies for the exhausted zeolite regeneration, the efficacy of some chemico-physical treatments on the zeolite loaded with four different sulfonamides was evaluated. The evolution of photolysis, Fenton-like reaction, thermal treatments, and solvent extractions and the occurrence in the zeolite pores of organic residues eventually entrapped was elucidated by a combined thermogravimetric (TGA-DTA), diffractometric (XRPD), and spectroscopic (FT-IR) approach. The chemical processes were not able to remove the organic guest from zeolite pores and a limited transformation on embedded molecules was observed. On the contrary, both thermal treatment and solvent extraction succeeded in the regeneration of the zeolite loaded from deionized and natural fresh water. The recyclability of regenerated zeolite was evaluated over several adsorption/regeneration cycles, due to the treatment efficacy and its stability as well as the ability to regain the structural features of the unloaded material.

  10. Validation of an HPLC analytical method coupled to a multifunctional clean-up column for the determination of deoxynivalenol.

    Science.gov (United States)

    Sugita-Konsihi, Yoshiko; Tanaka, Toshitsugu; Tabata, Setsuko; Nakajima, Masahiro; Nouno, Masanori; Nakaie, Yoko; Chonan, Takao; Aoyagi, Mitsutoshi; Kibune, Nobuyuki; Mizuno, Kazutoshi; Ishikuro, Eiichi; Kanamaru, Naoki; Minamisawa, Masatoshi; Aita, Norio; Kushiro, Masayo; Tanaka, Kenji; Takatori, Kosuke

    2006-04-01

    To evaluate a method using a multifunctional clean-up column coupled with high performance liquid chromatography as an official analytical method for the determination of deoxynivalenol in wheat used as food or feed, an inter-laboratory study was performed in 12 laboratories using four naturally contaminated wheat samples and one spiked sample. The relative standard deviations for repeatability (RSDr) and reproducibility (RSDR) of naturally contaminated wheat were in the range 5.8-11.3% and 12.0-20.7%, respectively. The HORRAT was less than 1.0 in each sample. From the spiking test, the recovery rate, RSDr, RSDR and HORRAT value were 100.0%, 11.2%, 10.3% and 0.5, respectively. The limit of quantification is 0.10 mg/kg from the range obtained in a linear calibration. Thus, it should be useful as a sensitive and validated analytical method for the determination of deoxynivalenol in wheat intended for use in food and feed.

  11. Tackling the challenge of selective analytical clean-up of complex natural extracts: the curious case of chlorophyll removal.

    Science.gov (United States)

    Bijttebier, Sebastiaan; D'Hondt, Els; Noten, Bart; Hermans, Nina; Apers, Sandra; Voorspoels, Stefan

    2014-11-15

    Alkaline saponification is often used to remove interfering chlorophylls and lipids during carotenoids analysis. However, saponification also hydrolyses esterified carotenoids and is known to induce artifacts. To avoid carotenoid artifact formation during saponification, Larsen and Christensen (2005) developed a gentler and simpler analytical clean-up procedure involving the use of a strong basic resin (Ambersep 900 OH). They hypothesised a saponification mechanism based on their Liquid Chromatography-Photodiode Array (LC-PDA) data. In the present study, we show with LC-PDA-accurate mass-Mass Spectrometry that the main chlorophyll removal mechanism is not based on saponification, apolar adsorption or anion exchange, but most probably an adsorption mechanism caused by H-bonds and dipole-dipole interactions. We showed experimentally that esterified carotenoids and glycerolipids were not removed, indicating a much more selective mechanism than initially hypothesised. This opens new research opportunities towards a much wider scope of applications (e.g. the refinement of oils rich in phytochemical content).

  12. Temperature performance of portable radiation survey instruments used for environmental monitoring and clean-up activities in Fukushima

    Science.gov (United States)

    Saegusa, Jun; Yanagisawa, Kayo; Hasumi, Atsushi; Shimizu, Takenori; Uchita, Yoshiaki

    2017-08-01

    Following the Fukushima Dai-ichi Nuclear Power Plant accident in March 2011, extensive radiation monitoring and environmental clean-up activities have been conducted throughout the Fukushima region. Outside air temperatures there reach 40 °C in summer and -20 °C in winter, which are beyond the quoted operational range of many radiation survey instruments. Herein, temperature performance of four types of portable Japanese radiation survey instruments widely used in Fukushima was experimentally investigated using a temperature-controlled chamber. They included two ionization chamber type instruments, Fuji NHA1 and Aloka ICS-323C, and two NaI(Tl) scintillation type ones, Fuji NHC7 and Aloka TCS-172B. Experimental results showed significantly diverse characteristics on the temperature dependences from one type of instrument to another. For example, NHA1 overestimated the ambient dose-equivalent rate by as much as 17% at -30 °C and 10% at 40 °C, whereas the TCS-172B readings underestimated the rate by 30% at -30 °C and 7% at 40 °C.

  13. A probabilistic model estimating oil spill clean-up costs--a case study for the Gulf of Finland.

    Science.gov (United States)

    Montewka, Jakub; Weckström, Mia; Kujala, Pentti

    2013-11-15

    Existing models estimating oil spill costs at sea are based on data from the past, and they usually lack a systematic approach. This make them passive, and limits their ability to forecast the effect of the changes in the oil combating fleet or location of a spill on the oil spill costs. In this paper we make an attempt towards the development of a probabilistic and systematic model estimating the costs of clean-up operations for the Gulf of Finland. For this purpose we utilize expert knowledge along with the available data and information from literature. Then, the obtained information is combined into a framework with the use of a Bayesian Belief Networks. Due to lack of data, we validate the model by comparing its results with existing models, with which we found good agreement. We anticipate that the presented model can contribute to the cost-effective oil-combating fleet optimization for the Gulf of Finland. It can also facilitate the accident consequences estimation in the framework of formal safety assessment (FSA).

  14. The Development of an Automated Clean-up for Fat Extracts in the Routine Analysis of Organochlorine Compounds in Fish Meat

    Directory of Open Access Journals (Sweden)

    Ana Andreea CIOCA

    2017-05-01

    Full Text Available The present work describes the development of a new, automatic High Performance Liquid Chromatography (HPLC Clean-up step, in the methodology of sample preparation and multi-residue determination of organochlorine compounds (OCs in fish meat. 24 OCs were taken into study. In addition 7 Polychlorinated Biphenyls (PCBs, 7 chlorobenzene compounds and one 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD were investigated. The HPLC conditions were established in accordance with the validated traditional Clean-up step of the laboratory. The technique was applied on a dilution of analytes of interest in order to establish the period of time in which the compounds are eluted. Another set of experiments involved fish oil, in order to identify and separate the fat fraction from the analytes. To confirm the findings of the experiments mentioned above, extracts of fish samples obtained after Accelerated Solvent Extraction (ASE were examined. The samples were spiked with the analytes of interest before HPLC clean-up step and quantified through Gas Chromatography coupled with tandem Mass Spectrometry (GC-MS/MS. A HPLC clean-up technique lasting 38 minutes/sample was developed. The method is not suitable for OCs such as Endosulfansulfat and Endrine Ketone due to the very low recovery results.Â

  15. Multiplug filtration clean-up with multiwalled carbon nanotubes in the analysis of pesticide residues using LC-ESI-MS/MS.

    Science.gov (United States)

    Zhao, Pengyue; Fan, Sufang; Yu, Chuanshan; Zhang, Junyan; Pan, Canping

    2013-10-01

    A novel design for a rapid clean-up method was developed for the analysis of pesticide residues in fruit and vegetables followed by LC-ESI-MS/MS. The acetonitrile-based sample extraction technique was used to obtain the extracts, and further clean-up was carried out by applying the streamlined procedure on a multiplug filtration clean-up column coupled with a syringe. The sorbent used for clean-up in this research is multiwalled carbon nanotubes, which was mixed with anhydrous magnesium sulfate to remove water from the extracts. This method was validated on 40 representative pesticides and apple, cabbage, and potato sample matrices spiked at two concentration levels of 10 and 100 μg/kg. It exhibited recoveries between 71 and 117% for most pesticides with RSDs 0.995 for most studied pesticides between concentration levels of 10-500 μg/L. The LOQs for 40 pesticides ranged from 2 to 50 μg/kg. The developed method was successfully applied to the determination of pesticide residues in market fruit and vegetable samples.

  16. Molecular level insights to the interaction of toluene with ZrO2-based biomass gasification gas clean-up catalysts

    NARCIS (Netherlands)

    Viinikainen, T.; Kauppi, I.; Korhonen, S.; Lefferts, L.; Kanervo, J.; Lehtonen, J.

    2013-01-01

    Gasification of biomass, followed by ZrO2-catalyzed hot gas clean-up at 600–900 °C for the oxidation of impurities (such as tar), is an environmentally attractive way to produce heat and power or synthesis gas. The interaction of toluene (as a model compound for tar) with ZrO2-based gasification gas

  17. A LC/UV/Vis method for determination of cyanocobalamin in multivitamin dietary supplements with on-line sample clean-up

    Science.gov (United States)

    A HPLC-UV method using a two-column strategy with a switching valve for on-line sample clean-up was developed for the determination of cyanocobalamin (CN-CBL-vitamin B12, in dietary supplements. The method uses two columns, an Agilent Zorbax C8 (150 mm x 4.6 mm, 5 um particle) reversed-phase column...

  18. Analysis of sterigmatocystin in cereals, animal feed, seeds, beer and cheese by immunoaffinity column clean-up and HPLC and LC-MS/MS quantification.

    Science.gov (United States)

    Marley, Elaine; Brown, Phyllis; Mackie, Jennifer; Donnelly, Carol; Wilcox, Joyce; Pietri, Amedeo; Macdonald, Susan

    2015-01-01

    A method is reported for the analysis of sterigmatocystin in various food and feed matrices using a commercial sterigmatocystin immunoaffinity column (IAC) for sample clean-up prior to HPLC analysis by UV with mass spectrometric detection (LC-MS/MS). Cereals (wheat, oats, rye, maize and rice), sunflower seeds and animal feed were spiked with sterigmatocystin at levels from 0.75 to 50 µg kg(-1) to establish method performance. Using acetonitrile/water extraction followed by IAC clean-up, and analysis by HPLC with detection at 325 nm, recoveries ranged from 68% to 106%, with repeatability from 4.2% to 17.5%. The limit of quantification with UV detection in these matrices was 1.5 µg kg(-1). For the analysis of beer and cheese the sample preparation prior to IAC clean-up was changed to accommodate the different properties of the matrix, prior to analysis by LC-MS/MS. For beer and cheese spiked at 5.0 µg kg(-1) the recoveries were 94% and 104%, and precision (RSDs) were 1.9% and 2.9% respectively. The limits of quantification by LC-MS/MS in beer and cheese were 0.02 and 0.6 µg kg(-1) respectively. The sterigmatocystin IAC was demonstrated to provide an efficient clean-up of various matrices to enable this mycotoxin to be determined by either HPLC with UV detection or LC-MS/MS.

  19. Separation and determination of citrinin in corn using HPLC fluorescence detection assisted by molecularly imprinted solid phase extraction clean-up

    Science.gov (United States)

    A liquid chromatography based method to detect citrinin in corn was developed using molecularly imprinted solid phase extraction (MISPE) sample clean-up. Molecularly imprinted polymers were synthesized using 1,4-dihydroxy-2-naphthoic acid as the template and an amine functional monomer. Density func...

  20. Molecular level insights to the interaction of toluene with ZrO2-based biomass gasification gas clean-up catalysts

    NARCIS (Netherlands)

    Viinikainen, T.; Kauppi, I.; Korhonen, S.; Lefferts, Leonardus; Kanervo, J.; Lehtonen, J.

    2013-01-01

    Gasification of biomass, followed by ZrO2-catalyzed hot gas clean-up at 600–900 °C for the oxidation of impurities (such as tar), is an environmentally attractive way to produce heat and power or synthesis gas. The interaction of toluene (as a model compound for tar) with ZrO2-based gasification gas

  1. Human Genotoxic Study Carried Out Two Years after Oil Exposure during the Clean-up Activities Using Two Different Biomarkers

    Directory of Open Access Journals (Sweden)

    Gloria Biern

    2015-11-01

    Full Text Available Micronuclei, comet and chromosome alterations assays are the most widely used biomarkers for determining the genotoxic damage in a population exposed to genotoxic chemicals. While chromosome alterations are an excellent biomarker to detect short- and long-term genotoxic effects, the comet assay only measures early biological effects, and furthermore it is unknown whether nuclear abnormalies, such as those measured in the micronucleus test, remain detectable long-term after an acute exposure. In our previous study, an increase in structural chromosome alterations in fishermen involved in the clean-up of the Prestige oil spill, two years after acute exposure, was detected. The aim of this study is to investigate whether, in lymphocytes from peripheral blood, the nuclear abnormalies (micronucleus, nucleoplasmic bridges and nuclear buds have a similar sensitivity to the chromosome damage analysis for genotoxic detection two years after oil exposure in the same non-smoker individuals and in the same peripheral blood extraction. No significant differences in nuclear abnormalies frequencies between exposed and non-exposed individuals were found (p > 0.05. However, chromosome damage, in the same individuals, was higher in exposed vs. non-exposed individuals, especially for chromosome lesions (p < 0.05. These findings, despite the small sample size, suggest that nuclear abnormalities are probably less-successful biomarkers than are chromosome alterations to evaluate genotoxic effects two or more years after an exposure to oil. Due to the great advantage of micronucleus automatic determination, which allows for a rapid study of hundreds of individuals exposed to genotoxic chemical exposure, further studies are needed to confirm whether this assay is or is not useful in long-term genotoxic studies after the toxic agent is no longer present.

  2. A Membrane-Based Electro-Separation Method (MBES) for Sample Clean-Up and Norovirus Concentration.

    Science.gov (United States)

    Kang, Wei; Cannon, Jennifer L

    2015-01-01

    Noroviruses are the leading cause of acute gastroenteritis and foodborne illnesses in the United States. Enhanced methods for detecting noroviruses in food matrices are needed as current methods are complex, labor intensive and insensitive, often resulting in inhibition of downstream molecular detection and inefficient recovery. Membrane-based electro-separation (MBES) is a technique to exchange charged particles through a size-specific dialysis membrane from one solution to another using electric current as the driving force. Norovirus has a net negative surface charge in a neutrally buffered environment, so when placed in an electric field, it moves towards the anode. It can then be separated from the cathodic compartment where the sample is placed and then collected in the anodic compartment for downstream detection. In this study, a MBES-based system was designed, developed and evaluated for concentrating and recovering murine norovirus (MNV-1) from phosphate buffer. As high as 30.8% MNV-1 migrated from the 3.5 ml sample chamber to the 1.5 ml collection chamber across a 1 μm separation membrane when 20 V was applied for 30 min using 20 mM sodium phosphate with 0.01% SDS (pH 7.5) as the electrolyte. In optimization of the method, weak applied voltage (20 V), moderate duration (30 min), and low ionic strength electrolytes with SDS addition were needed to increase virus movement efficacy. The electric field strength of the system was the key factor to enhance virus movement, which could only be improved by shortening the electrodes distance, instead of increasing system applied voltage because of virus stability. This study successfully demonstrated the norovirus mobility in an electric field and migration across a size-specific membrane barrier in sodium phosphate electrolyte. With further modification and validation in food matrixes, a novel, quick, and cost-effective sample clean-up technique might be developed to separate norovirus particles from food

  3. 净化网络环境及其机制%On Cleaning up Network Environment and Developing its Mechanism

    Institute of Scientific and Technical Information of China (English)

    盛剑锋; 余凌

    2011-01-01

    我国互联网规模的高速发展给人们的工作、学习与生活带来了便利,但互联网的虚拟性、开放性和交互性等特征,使网络也成为一些人从事违法活动的场所。依法采取监管措施,规范净化网络环境,已成为世界各国的共识。我国在借鉴国外经验与方法的基础上,应结合我国国情,在开展打击整治网络色情等专项行动的同时,要不断完善网络立法、技术监控、行业自律、社会监督、国际合作等措施,建立健全防范和查处的长效管理机制。%With China's rapid development of the Internet in its scale, people's work, study and life are made easier, but the Internet is likely to be a venue for illegal activities because it is virtual, open and interactive. It has been a common practice in all the countries to take regulatory measures to regulate and clean up the network environment according to law. We need to borrow foreign practices and methods, and combine them with China's actual conditions. In the special campaign to crack down on the online pornography, we must constantly improve our work at the network legislation, technical monitoring, self-discipline of the network trades, social supervision, and international cooperation to establish a long-acting management mechanism for a sound prevention and investigation.

  4. Fibre-matrix interfaces in titanium matrix composites made with sigma monofilament

    Energy Technology Data Exchange (ETDEWEB)

    Shatwell, R.A. [DERA, Farnborough (United Kingdom). Struct. Mater. Centre

    1999-01-31

    A review of the development of coatings for sigma monofilament is given. The coating must protect the underlying silicon carbide before, during and after consolidation. This requires the coating outer surface to be under negative or zero residual stress at room temperature. The coating should also be well bonded to the SiC. It is shown that stoichiometric TiB{sub 2} is under a tensile stress of around 3 GPa under these conditions and hence is unsuitable. The boron-rich outer surface of SM1240 is essentially unstressed and the carbon surface of SM1140+ is under {approx}300 MPa axial compressive stress. Failure of monofilament in the composite initiates at the W-SiC interface, rather than at the metal-fibre interface characteristic of SCS-6. In order to ensure this behaviour, the coating in the composite must be thick enough to ensure that the stress concentration field arising from irregularities at the TiC-C boundary do not initiate fracture of the SiC. This requires a minimum thickness of around 1 {mu}m of carbon. (orig.) 10 refs.

  5. Tension free monofilament macropore polypropylene mesh (Gynemesh PS in female genital prolapse repair

    Directory of Open Access Journals (Sweden)

    Vicente Sola

    2006-08-01

    Full Text Available OBJECTIVES: To review intraoperative and postoperative complications associated to the correction of cystocele and rectocele with polypropylene mesh macropore monofilament (Gynemesh PS using transvaginal free tension technique. MATERIALS AND METHODS: Prospective study of patients that have been submitted to correction of cystocele and/or rectocele between November 2004 and August 2005 in the Urogynecology and Vaginal Surgery Unit of Gynecology and Obstetrics Department, Las Condes Clinic. Mesh was used in 31 patients: 9 for cystocele, 11 for rectocele, and 11 for concomitant meshes. Total mesh used 42. Media age 55 years old, weight 64 kilograms. In 7 patients we used a third mesh for correction of urinary incontinence by TVT-O technique. RESULTS: They did not present intraoperative complications, neither in immediate or delayed postoperative time. We did not observe hematoma, infection, erosion or exposition mesh. Healing of cystocele and rectocele was obtained in 100% of patients, with a pursuit between 1 and 8 months. DISCUSSION: The use of prosthetic polypropylene monofilament macropore mesh in the correction of cystocele and/or rectocele, by transvaginal route with tension free technique seems to be a safe and effective surgery procedure.

  6. A Membrane-Based Electro-Separation Method (MBES for Sample Clean-Up and Norovirus Concentration.

    Directory of Open Access Journals (Sweden)

    Wei Kang

    Full Text Available Noroviruses are the leading cause of acute gastroenteritis and foodborne illnesses in the United States. Enhanced methods for detecting noroviruses in food matrices are needed as current methods are complex, labor intensive and insensitive, often resulting in inhibition of downstream molecular detection and inefficient recovery. Membrane-based electro-separation (MBES is a technique to exchange charged particles through a size-specific dialysis membrane from one solution to another using electric current as the driving force. Norovirus has a net negative surface charge in a neutrally buffered environment, so when placed in an electric field, it moves towards the anode. It can then be separated from the cathodic compartment where the sample is placed and then collected in the anodic compartment for downstream detection. In this study, a MBES-based system was designed, developed and evaluated for concentrating and recovering murine norovirus (MNV-1 from phosphate buffer. As high as 30.8% MNV-1 migrated from the 3.5 ml sample chamber to the 1.5 ml collection chamber across a 1 μm separation membrane when 20 V was applied for 30 min using 20 mM sodium phosphate with 0.01% SDS (pH 7.5 as the electrolyte. In optimization of the method, weak applied voltage (20 V, moderate duration (30 min, and low ionic strength electrolytes with SDS addition were needed to increase virus movement efficacy. The electric field strength of the system was the key factor to enhance virus movement, which could only be improved by shortening the electrodes distance, instead of increasing system applied voltage because of virus stability. This study successfully demonstrated the norovirus mobility in an electric field and migration across a size-specific membrane barrier in sodium phosphate electrolyte. With further modification and validation in food matrixes, a novel, quick, and cost-effective sample clean-up technique might be developed to separate norovirus particles

  7. The role of peer review in responsive decisions - a case study of clean-up and safe long-term management of historic waste at Port Hope and Clarington

    Energy Technology Data Exchange (ETDEWEB)

    Hardy, D. [Hardy Stevenson and Associates Inc., Toronto, Ontario (Canada)

    2006-07-01

    'Full text:' The Municipalities of Port Hope and Clarington ('Municipalities') are committed to leading the clean- up and safe long-term management of historic low- level radioactive and hazardous wastes deposited in Port Granby (in the Municipality of Clarington) and several locations in the Municipality of Port Hope. They are supported by the Government of Canada through Atomic Energy of Canada Limited's (AECL) Low- Level Radioactive Waste Management Office (LLRWMO). The wastes are the result of radium and uranium processing in Port Hope by Eldorado since the 1930s. To establish the parameters of the clean- up, including the ability to veto the project, the local municipalities negotiated and signed a Legal Agreement with the Government of Canada in 2001. As a Responsible Authority, Natural Resources Canada has defined and approved the scope of the two projects. The LLRWMO is designated as the proponent. Accordingly, the LLRWMO is conducting the Environmental Assessment (EA) Studies and seeking approval of a preferred method of conducting the clean up for each municipality. The municipalities recognized that these large and complex environmental assessment studies would challenge the resources of citizens, municipal professional staff and politicians. Thus, the Legal Agreement specified that both municipalities would have funded staff to work together to coordinate and expedite the project. A Peer Review Team (PRT) would be retained by the municipalities and funded by the Government of Canada. The PRT is made up of experienced professionals led by Hardy Stevenson and Associates Limited in disciplines appropriate to the peer review tasks on hand. The PRT has brought a unique approach to the peer review. The PRT is headed by planners and social scientists trained to be sensitive to the 'people aspects' of the EA process as a major priority. They are supported by engineers and technical specialists. The team includes a physician

  8. The NucleoSpin® DNA Clean-up XS kit for the concentration and purification of genomic DNA extracts: an alternative to microdialysis filtration.

    Science.gov (United States)

    Hudlow, William R; Krieger, Robert; Meusel, Markus; Sehhat, Joshua C; Timken, Mark D; Buoncristiani, Martin R

    2011-06-01

    Traditionally, DNA extracts from biological evidence items have been concentrated and rinsed using microdialysis filtration units, including the Centricon(®) and Microcon(®) centrifugal filter devices. As an alternative to microdialysis filtration, we present an optimized method for using NucleoSpin(®) XS silica columns to concentrate and clean-up aqueous extracts from the organic extraction of DNA from biological samples. The method can be used with standard organic extraction and dithiothreitol (DTT)-based differential extraction methods with no modifications to these methods prior to the concentration and clean-up step. Extracts from laboratory-prepared bloodstains, saliva and semen stains have been successfully amplified with both qPCR and STR assays. Finally, the total time to process a set of samples with the NucleoSpin(®) XS column is approximately 30 min vs. approximately 1.5h with the Centricon(®) YM-100 filter device.

  9. A review of polymer nanofibres by electrospinning and their application in oil-water separation for cleaning up marine oil spills.

    Science.gov (United States)

    Sarbatly, Rosalam; Krishnaiah, Duduku; Kamin, Zykamilia

    2016-05-15

    The growths of oil and gas exploration and production activities have increased environmental problems, such as oil spillage and the resulting pollution. The study of the methods for cleaning up oil spills is a critical issue to protect the environment. Various techniques are available to contain oil spills, but they are typically time consuming, energy inefficient and create secondary pollution. The use of a sorbent, such as a nanofibre sorbent, is a technique for controlling oil spills because of its good physical and oil sorption properties. This review discusses about the application of nanofibre sorbent for oil removal from water and its current developments. With their unique physical and mechanical properties coupled with their very high surface area and small pore sizes, nanofibre sorbents are alternative materials for cleaning up oil spills.

  10. Technology for the oil spills clean-up which provides preliminary accumulation of sorbents into the area of emergence and localization oil spills

    Directory of Open Access Journals (Sweden)

    M.L.Soroka

    2012-12-01

    Full Text Available Introduction: The implementation of measures for the prevention and spill of dangerous goods is an important aspect of sustainable development of railway transport. oil spills accident are the most dangerous. They are accompanied by significant pollution of all environmental objects. Studying and development of oil localization and clean-up technologies of such accidents is an important problem of environmental protection to modern conditions of railway transport development. The purpose: to improve the effectiveness of traditional methods of oil spill elimination and the development of new clean-up technologies adapted to the real conditions of the railway transport of Ukraine. Methods: To achieve the research purposes was used analysis of material flows, typical for places emergence and localization of the oil spill on the railways. Results: Analysis of standard technological scheme for the oil spills eliminations has shown that the most difficult task of effective clean-up surfaces is the timely delivery of oil sorbents and special equipment to the area spill containment. The general effectiveness of the elimination activities specifies the time from the beginning contact of dangerous goods with environmental objects to the absorption it into the structure of sorbent . Us was developed the technological scheme of oil spill elimination. This scheme provide a permanent and fast access to the sorbents into the oil spill localization area. It was proposed to device that allows you to transport the sorbent into sorption booms directly on the tank for transportation of petroleum products. Conclusions: Preventative accumulation of sorbents to the oil spill elimination into the localization area provides the organizational and operational simplicity of all stages of clean-up technology. Technical and economic assessment shows that the proposed technology is effective, technologically feasible and economically competitive.

  11. Aptamer-affinity column clean-up coupled with ultra high performance liquid chromatography and fluorescence detection for the rapid determination of ochratoxin A in ginger powder.

    Science.gov (United States)

    Yang, Xihui; Kong, Weijun; Hu, Yichen; Yang, Meihua; Huang, Luqi; Zhao, Ming; Ouyang, Zhen

    2014-04-01

    Aptamers are single-stranded oligonucleotides with high affinity and specificity and are widely used in targets separation and enrichment. Here, an aptamer-affinity column (AAC) was firstly prepared in-house through a covalent immobilization strategy. Then, ochratoxin A (OTA) in ginger powder was absorbed and enriched using the new aptamer-based clean-up technology for the first time, and was further analyzed by ultra high performance liquid chromatography with fluorescence detection. After optimization, the average recoveries for blank samples spiked with OTA at 5, 15, and 45 μg/kg ranged from 85.36 to 96.83%. Furthermore, the AAC exhibited a similar accuracy as an immunoaffinity column to clean up OTA in ginger powder. Above all, it exhibited better reusability, twice that of the immunoaffinity column, had lower toxicity and cost, and took less time. Of 25 contaminated ginger powder samples, OTA contamination levels ranged from 1.51 to 4.31 μg/kg, which were lower than the European Union (EU) regulatory limits. All the positive samples were further confirmed by ultra-fast LC with MS/MS. In conclusion, the method of clean-up based on the AAC coupled to ultra-HPLC with fluorescence detection was rapid, specific, and sensitive for the quantitative analysis of OTA in a complex matrix.

  12. The Ability of Watercress (Nasturtiumofficinale and Pennyroyal (Menthapulegium in Clean up Excess Nitrate and Phosphate of Water

    Directory of Open Access Journals (Sweden)

    Z. Ahmadpoor

    2016-02-01

    Full Text Available Introduction: There is necessary to clean up the nitrate and phosphate from surface waters before effluence of them to environment and eutrophication formation because of water health importance and considering to nitrate and phosphate consequences. Nitrate and ammonium as the - forms of inorganic and nitrogen have been subjected to the center of issues related to environment pollutants and water resources in a long time. The nitrate is more important than other inorganic nitrogen forms such as ammonium because of various reasons such as high dynamics and causing diseases such as some of digestion system and lymph nodes cancers in adults and methemoglobinemia in infants. Therefore the maximum concentration of this ion in drinking water has been determined as 45 mg.Lit-1 by WHO. Regarding the importance of the water health and the complications due to existence of some compounds such as nitrate and phosphate, in this experiment, the possibility of elimination or decreasing excess nitrate and phosphate from water in hydroponic conditions using of two watercress and pennyroyal plants was evaluated. Watercress(Nasturtiumofficinale and pennyroyal (Menthapulegiumwere selected because of some properties such as adaptability with the most climates of Iranamd less requirements care. Materials and Methods: Two RCD factorial experiments were carried out to evaluate the ability of watercress and pennyroyal to biosorption of nitrate and phosphate from polluted water in hydroponic conditions. First factor was plant species including watercress and pennyroyal. Second factor included nitrate (50, 100, 150 Mg/L and phosphate (5, 10, 15 Mg/L in first and second experiment respectively.The final concentrations of nitrate and phosphate in water was measured using spectrophotometer in wavelength of 410 nm and 690 nm by sulphatebrucine and chloride methods , respectively, which are mentioned in Standard Methods for the Examination of Water and Wastewater. At the end

  13. Development of sample preparation method for auxin analysis in plants by vacuum microwave-assisted extraction combined with molecularly imprinted clean-up procedure.

    Science.gov (United States)

    Hu, Yuling; Li, Yuanwen; Zhang, Yi; Li, Gongke; Chen, Yueqin

    2011-04-01

    A novel sample preparation method for auxin analysis in plant samples was developed by vacuum microwave-assisted extraction (VMAE) followed by molecularly imprinted clean-up procedure. The method was based on two steps. In the first one, conventional solvent extraction was replaced by VMAE for extraction of auxins from plant tissues. This step provided efficient extraction of 3-indole acetic acid (IAA) from plant with dramatically decreased extraction time, furthermore prevented auxins from degradation by creating a reduced oxygen environment under vacuum condition. In the second step, the raw extract of VMAE was further subjected to a clean-up procedure by magnetic molecularly imprinted polymer (MIP) beads. Owing to the high molecular recognition ability of the magnetic MIP beads for IAA and 3-indole-butyric acid (IBA), the two target auxins in plants can be selectively enriched and the interfering substance can be eliminated by dealing with a magnetic separation procedure. Both the VMAE and the molecularly imprinted clean-up conditions were investigated. The proposed sample preparation method was coupled with high-performance liquid chromatogram and fluorescence detection for determination of IAA and IBA in peas and rice. The detection limits obtained for IAA and IBA were 0.47 and 1.6 ng/mL and the relative standard deviation were 2.3% and 2.1%, respectively. The IAA contents in pea seeds, pea embryo, pea roots and rice seeds were determined. The recoveries were ranged from 70.0% to 85.6%. The proposed method was also applied to investigate the developmental profiles of IAA concentration in pea seeds and rice seeds during seed germination.

  14. Efficient sample clean-up and online preconcentration for sensitive determination of melamine in milk samples by capillary electrophoresis with contactless conductivity detection.

    Science.gov (United States)

    Ji, Yan-ling; Chen, Xiao-wei; Zhang, Zhu-bao; Li, Jing; Xie, Tian-yao

    2014-10-01

    Based on an efficient sample clean-up and field-amplified sample injection online preconcentration technique in capillary electrophoresis with contactless conductivity detection, a new analytical method for the sensitive determination of melamine in milk samples was established. In order to remove the complex matrix interference, which resulted in a serious problem during field-amplified sample injection, liquid-liquid extraction was utilized. As a result, liquid-liquid extraction provides excellent sample clean-up efficiency when ethyl acetate was used as organic extraction by adjusting the pH of the sample solution to 9.5. Both inorganic salts and biological macromolecules are effectively removed by liquid-liquid extraction. The sample clean-up procedure, capillary electrophoresis separation parameters and field-amplified sample injection conditions are discussed in detail. The capillary electrophoresis separation was achieved within 5 min under the following conditions: an uncoated fused-silica capillary, 12 mM HAc + 10 mM NaAc (pH = 4.6) as running buffer, separation voltage of +13 kV, electrokinetic injection of +12 kV × 10 s. Preliminary validation of the method performance with spiked melamine provided recoveries >90%, with limits of detection and quantification of 0.015 and 0.050 mg/kg, respectively. The relative standard deviations of intra- and inter-day were below 6%. This newly developed method is sensitive and cost effective, therefore, suitable for screening of melamine contamination in milk products.

  15. Determination of mycophenolic acid in mest products using mixed mode reversed phase-anion exchange clean-up and liquid chromatography-high-resolution mass spectrometry

    DEFF Research Database (Denmark)

    Sørensen, Louise Marie; Nielsen, Kristian Fog; Jacobsen, Thomas

    2008-01-01

    A method for determination of mycophenolic acid (MPA) in dry-cured ham, fermented sausage and liver pate is described. MPA was extracted from meat with bicarbonate-acetonitrile, further cleaned-up by mixed mode reversed phase-anion exchange and detected using a LC-MS system with electrospray...... ionisation-time-of-flight detection. The limit of detection was 4 mu g/kg in sausage and 6 mu g/kg in ham and pate. The method was successfully used for quantification of MPA in dry-cured ham and liver pate artificially inoculated with Penicillium brevicompactum. Levels ranged from 190 mu g/kg in centre to I...

  16. Unidirectional barbed suture versus standard monofilament for urethrovesical anastomosis during robotic assisted laparoscopic radical prostatectomy

    Directory of Open Access Journals (Sweden)

    Marc Manganiello

    2012-02-01

    Full Text Available PURPOSE: V-LocTM180 (Covidien Healthcare, Mansfield, MA is a new unidirectional barbed suture that may reduce loss of tension during a running closure. We evaluated the use of the barbed suture for urethrovesical anastomosis (UVA during robotic assisted laparoscopic prostatectomy (RALP. Time to completion of UVA, post-operative anastomotic leak rate, and urinary incontinence were compared in patients undergoing UVA with 3-0 unidirectional-barbed suture vs. 3-0 MonocrylTM (Ethicon, Somerville, NJ. MATERIALS AND METHODS: Data were prospectively collected for 70 consecutive patients undergoing RALP for prostate cancer between November 2009 and October 2010. In the first 35 patients, the UVA was performed using a modified running van Velthoven anastomosis technique using two separate 3-0 monofilament sutures. In the subsequent 35 patients, the UVA was performed using two running novel unidirectional barbed sutures. At 7-12 days postoperatively, all patients were evaluated with a cystogram to determine anastomotic integrity. Urinary incontinence was assessed at two months and five months by total daily pad usage. Clinical symptoms suggestive of bladder neck contracture were elicited. RESULTS: Age, PSA, Gleason score, prostate size, estimated blood loss, body mass index, and clinical and pathologic stage between the 2 groups were similar. Comparing the monofilament group and V-LocTM180 cohorts, average time to complete the anastomosis was similar (27.4 vs. 26.4 minutes, p = 0.73 as was the rate of urinary extravasation on cystogram (5.7 % vs. 8.6%, p = 0.65. There were no symptomatic bladder neck contractures noted at 5 months of follow-up. At 2 months, the percentage of patients using 2 or more pads per day was lower in the V-LocTM180 cohort (24% vs. 44%, p < 0.02. At 5 months, this difference was no longer evident. CONCLUSIONS: Time to complete the UVA was similar in the intervention and control groups. Rates of urine leak were also comparable

  17. Normal threshold values for a monofilament sensory test in sural and radial cutaneous nerves in Indian and Nepali volunteers.

    Science.gov (United States)

    Wagenaar, Inge; Brandsma, Wim; Post, Erik; Richardus, Jan Hendrik

    2014-12-01

    The monofilament test (MFT) is a reliable method to assess sensory nerve function in leprosy and other neuropathies. Assessment of the radial cutaneous and sural nerves, in addition to nerves usually tested, can help improve diagnosis and monitoring of nerve function impairment (NFI). To enable the detection of impairments in leprosy patients, it is essential to know the monofilament threshold of these two nerves in normal subjects. The radial cutaneous, sural, ulnar, median and posterior tibial nerves of 245 volunteers were tested. All nerves were tested at three sites on both left and right sides. Normal monofilament thresholds were calculated per test-site and per nerve. We assessed 490 radial cutaneous and 482 sural nerves. The normal monofilament was 2 g (Filament Index Number (FIN) 4.31) for the radial cutaneous and 4 g (FIN 4.56) for the sural nerve, although heavy manual laborers demonstrated a threshold of 10 g (FIN 5.07) for the sural nerve. For median and ulnar nerves, the 200 mg (FIN 3.61) filament was confirmed as normal while the 4 g (FIN 4.56) filament was normal for the posterior tibial. Age and occupation have an effect on the mean touch sensitivity but do not affect the normal threshold for the radial cutaneous and sural nerves. The normal thresholds for the radial cutaneous and sural nerves are determined as the 2 g (FIN 4.31) and the 4 g (FIN 4.56) filaments, respectively. The addition of the radial cutaneous and sural nerve to sensory nerve assessment may improve the diagnosis of patients with impaired sensory nerve function.

  18. Study of tactile sensitivity by Semmes–Weinstein monofilaments in patients with carpal tunnel syndrome and healthy individuals

    Directory of Open Access Journals (Sweden)

    I. G. Mikhailyuk

    2014-01-01

    Full Text Available Surface sensitivity disorders are observed in many diseases of the central and peripheral nervous system. Surface sensitivity thresholds were estimated in healthy individuals and patients with carpal tunnel syndrome. There was a statistically significant (p < 0.001 increase in the sensitivity threshold in the distal phalanx of the index finger in patients with carpal tunnel syndrome as compared to healthy individuals, by evaluating the surface sensitivity by Semmes–Weinstein monofilaments.

  19. Validation and robustness testing of a HPLC method for the determination of avermectins and moxidectin in animal liver samples using an alumina column clean-up.

    Science.gov (United States)

    Danaher, M; O'Keeffe, M; Glennon, J D

    2000-10-01

    A multi-residue method has been developed for the quantitative determination of moxidectin, abamectin, doramectin and ivermectin in liver samples, with capability for qualitative identification of the presence of eprinomectin. Liver samples are extracted with isooctane, followed by clean-up on alumina-N solid phase extraction (SPE) cartridges. Extracts are derivatised and determined by high-performance liquid chromatography (HPLC) with fluorescence detection. The method was validated using bovine liver fortified at levels of 4 and 20 micrograms kg-1 with the drugs. The mean recovery from bovine liver ranged between 90 and 96%. The intra and inter-assay variations showed RSD typically of < 5% and < 10%, respectively. The procedure was applied also to ovine and porcine liver, giving similar results. A robustness study, carried out on the alumina clean-up step, indicated that the step is relatively insensitive to method changes. However, significant differences overall were found for the type of alumina and/or commercial SPE cartridge used. The limit of quantitation of the method is 2 micrograms kg-1 (ppb).

  20. [Simultaneous determination of zeranols and chloramphenicol in foodstuffs of animal origin by combination immunoaffinity column clean-up and liquid chromatography-tandem mass spectrometry].

    Science.gov (United States)

    Wang, Qing; Wang, Guomin; Xi, Cunxian; Li, Xianliang; Chen, Dongdong; Tang, Bobin; Zhang, Lei; Zhao, Hua

    2014-06-01

    A combination immunoaffinity column (IAC-CZ) clean-up and liquid chromatography-tandem mass spectrometry (LC-MS/MS) analytical method was successfully developed for zearalenol, beta-zearalenol and zearalenone) and chloramphenicol (CAP) in foodstuffs of animal origin. The samples (fish, liver, milk and honey) were enzymatically digested by beta-glucuronidase/sulfatase for about 16 h and then extracted with ether. The extracts were evaporated to dryness and then the residues were dissolved by 1.0 mL of 50% acetonitrile solution. After filtered and diluted with PBS buffer, the reconstituted solution were cleaned-up with a IAC-CZ and then analyzed by LC-MS/MS in multiple reaction monitoring (MRM) mode. The chromatographic separation was performed on a Shimadzu Shim-pack VP-ODS column with gradient elution by acetonitrile and 2 mmol/L ammonium acetate solution. The detection was carried out by electrospray negative ionization mass spectrometry in MRM mode. The proposed method was validated by the limit of detection (0.04-0.10 microg/kg), linearity (R2 > or = 0.999 0), average recoveries (70.9%-95.6%) and precisions (2.0% - 11.8%). The developed method is reliable, sensitive and has good applicability. The combination immunoaffinity column was proved to be an effective pretreatment technique to decrease the matrix effect, and it met the requirements of residue analysis of co-occurring zeranols and chloramphenicol.

  1. Determination of carbendazim, thiabendazole, and o-phenylphenol residues in lemons by HPLC following sample clean-up by ion-pairing.

    Science.gov (United States)

    Prousalis, Konstantinos P; Polygenis, Dimitris A; Syrokou, Alexandra; Lamari, Fotini N; Tsegenidis, Theodore

    2004-06-01

    An efficient analytical method is presented involving effective sample clean-up with solid-phase extraction and HPLC-UV analysis for the simultaneous determination of carbendazim, thiabendazole, and o-phenylphenol residues in lemons. Sample preparation involves extraction with acetonitrile acidified with trifluoroacetic acid and an ethyl acetate/petroleum ether mixture. Purification of the crude extract was carried out with liquid-liquid partitioning after addition of an aqueous ammonia solution. Final clean-up was performed on polymeric reversed-phase cartridges pretreated with sodium dodecyl sulfate. Chromatographic analysis was performed on a reversed-phase HPLC column isocratically eluted with an acetonitrile/water/ammonia mixture and UV detection at 254 nm. The chromatographic method is repeatable, reproducible, and sensitive. Fungicide recoveries from lemon samples fortified at levels of 5 and 1 mg kg(-1) were 81-85% for carbendazim, 96-98% for thiabendazole, and 81-106% for o-phenylphenol with coefficients of variation of 2.5-7.4%. Detection limits for carbendazim, thiabendazole, and o-phenylphenol in lemons were 0.21, 0.27, and 0.51 mg kg(-1), respectively.

  2. 移动互联网有害信息清理研究%Research on Cleaning up the Harmful Information on the Mobile Internet

    Institute of Scientific and Technical Information of China (English)

    文湘江; 马少武; 姜智峰; 唐雄燕

    2011-01-01

    With regard to the spread of harmful information which is hidden deeply and governed difficultly on the mobile internet,such as pornography,this paper provides the technical scheme and deployment scheme of cleaning up the harmful information,makes a comparative analysis on various network deployment modes,describes the steps and typical scenes of cleaning up the harmful information and finally proposes relevant suggestions of management.%针对在移动互联网上传播淫秽色情等有害信息具有隐蔽性大、治理难的问题,给出有害信息清理的技术方案,分析有害信息系统的网络部署方案,对几种系统的网络部署方式进行比较分析,描述了有害信息清理的步骤和典型场景,最后给出相应的监管建议。

  3. Simultaneous determination of multi-class veterinary drugs in chicken processed foods and muscle using solid-supported liquid extraction clean-up.

    Science.gov (United States)

    Yoshikawa, Souichi; Nagano, Chieko; Kanda, Maki; Hayashi, Hiroshi; Matsushima, Yoko; Nakajima, Takayuki; Tsuruoka, Yumi; Nagata, Marie; Koike, Hiroshi; Sekimura, Kotaro; Hashimoto, Tsuneo; Takano, Ichiro; Shindo, Tetsuya

    2017-07-01

    We developed a simultaneous determination method for 37 veterinary drugs in two chicken processed foods (deep-fried chicken and non-fried chicken cutlet) and muscle via liquid chromatography-mass spectrometry. The veterinary drugs belong to 7 different classes, including 4 antifolics, 4 benzimidazoles, 5 macrolides, 7 polyethers, 2 quinolones, 7 sulfonamides, and 8 other classes. The samples were extracted with ethyl acetate followed by acetonitrile with salt and buffers extraction. The two-step extraction enabled analyte extraction from highly lipid samples. The clean-up procedure, a solid-supported liquid extraction clean-up using a diatomaceous earth mini-cartridge, eliminated lipid co-extraction. The prepared sample matrix did not have an effect on the 36 analytes. The method was validated in accordance with the requirements of Japanese validation guidelines. Almost all targeted veterinary drugs successfully satisfied the guideline criteria in the three types of food matrices. The method exhibited recoveries of 70-105%, and the precision of repeatability and within-laboratory reproducibility ranged from 1 to 11% and 1 to 15%, respectively. The limits of quantification were estimated to range from 0.2 to 1.0μg/kg. Applying this method to samples commercially available in Tokyo, residues were detected in 3 out of 26 deep-fried chickens, 5 out of 20 non-fried chicken cutlets, and 17 out of 39 chicken muscles. Copyright © 2017 Elsevier B.V. All rights reserved.

  4. Comparison of solid phase extraction, saponification and gel permeation chromatography for the clean-up of microwave-assisted biological extracts in the analysis of polycyclic aromatic hydrocarbons.

    Science.gov (United States)

    Navarro, P; Cortazar, E; Bartolomé, L; Deusto, M; Raposo, J C; Zuloaga, O; Arana, G; Etxebarria, N

    2006-09-22

    The feasibility of different clean-up procedures was studied for the determination of polycyclic aromatic hydrocarbons (PAHs) in biota samples such as oysters, mussels and fish liver. In this sense, once the samples were extracted--essentially with acetone and in a microwave system--and before they could be analysed by gas chromatography-mass spectrometry (GC-MS), three different approaches were studied for the clean-up step: solid phase extraction (SPE), microwave-assisted saponification (MAS) and gel permeation chromatography (GPC). The main aim of this work was to maximise the recoveries of PAHs and to minimise the presence of interfering compounds in the last extract. In the case of SPE, Florisil cartridges of 1, 2 and 5 g, and silica cartridges of 5 g were studied. In that case, and with oysters and mussels, microwave-assisted extraction and 5 g Florisil cartridges provided good results. In addition, the concentrations obtained for Standard Reference Material (SRM) NIST 2977 (mussel tissue) were in good agreement with the certified values. In the case of microwave-assisted saponification, the extracts were not as clean as those obtained with 5 g Florisil and this fact lead to overestimate the concentration of the heaviest PAHs. Finally, the cleanest extracts were obtained by GPC. The method was successfully applied to mussels, oysters and hake liver, and the results obtained for NIST 2977 (mussel tissue) were within the confidence interval of the certified reference material for most of the certified analytes.

  5. Determination of Aflatoxin M1 in Milk Powder by Ultrasonic-Assisted Extraction and Dispersive Solid-Phase Clean-up.

    Science.gov (United States)

    Manoochehri, Mahboobeh; Asgharinezhad, Ali Akbar; Safaei, Mahdi

    2015-07-01

    This work describes the application of ultrasound-assisted dispersive solid-phase extraction (UA-DSPE) as a sample preparation approach for aflatoxin M1 (AFM1) and also its subsequent determination by HPLC-fluorescence detection. A Box-Behnken design in combination with response surface methodology was implemented to determine the variables affecting the extraction procedure. The effects of different variables, including type and quantity of clean-up phase, ultrasonication time, ultrasonication temperature, nature and volume of the leaching solvent, were investigated in the optimization study. Primary secondary amine (PSA) and acetonitrile were selected as the clean-up phase and the leaching solvent, respectively. The obtained optimized values were 30 mg of PSA, 10 min ultrasonication time, 32°C ultrasonication temperature and 10 mL of acetonitrile. Under the optimal conditions, the limit of detection and limit of quantification were 0.0012 and 0.0045 µg kg(-1), respectively. The recoveries of the UA-DSPE procedure ranged from 80 to 92%, with relative standard deviations lower than 10% in all cases. Eventually, this method was successfully applied to the extraction of AFM1 in milk powder samples. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  6. MonoMax Suture: A New Long-Term Absorbable Monofilament Suture Made from Poly-4-Hydroxybutyrate

    Directory of Open Access Journals (Sweden)

    Erich K. Odermatt

    2012-01-01

    Full Text Available A long-term absorbable monofilament suture was developed using poly-4-hydroxybutyrate (P4HB made from a biosynthetically produced homopolymer of the natural metabolite 4-hydroxybutyrate. The suture, called MonoMax, has prolonged strength retention. At 12 weeks, a size 3-0 MonoMax suture retains approximately 50% of its initial tensile strength in vivo and is substantially degraded in one year with minimal tissue reaction. In contrast, PDS II monofilament suture (Ethicon, Inc., Somerville, NJ has no residual strength in vivo after 12 weeks. In vivo, the MonoMax suture is hydrolyzed primarily by bulk hydrolysis, and is then degraded via the Krebs cycle. MonoMax is substantially more compliant than other monofilament sutures, and incorporates an element of elasticity. Its tensile modulus of 0.48 GPa is approximately one-third of the value of the PDS II fiber providing an exceptionally flexible and pliable fiber with excellent knot strength and security. These features are further enhanced by the fiber's elasticity, which also improves knot security and may help prevent wound dehiscence. Because of its performance advantages, this suture may find clinical utility in applications where prolonged strength retention, and greater flexibility are required, particularly in procedures like abdominal wall closure where wound dehiscence is still a significant post-surgical complication.

  7. The effect of a weak W/SiC interface on the strength of sigma silicon carbide monofilament

    Science.gov (United States)

    Dyos; Shatwell

    1999-11-01

    Fractography studies have shown that the strength-determining flaws in silicon carbide monofilaments are generally at the core/silicon carbide interface or in the vicinity of the outside, carbon-based coating. In tungsten-cored monofilaments like DERA Sigma, the W/SiC flaws primarily determine the strength. Fracture is accompanied by brittle failure of the tungsten. The crack propagates simultaneously outwards through the silicon carbide, inwards through the tungsten and also around the W/SiC interface before being deflected into the tungsten or out through the silicon carbide. Experiments depositing boundary layers between the tungsten and silicon carbide have resulted in significantly different fracture behaviour. The tungsten fails in a ductile manner and the strength-determining flaws are located predominantly at the outside surface of the silicon carbide. This behaviour is discussed in terms of models proposed by E. Martin and W. Curtin. It is thought that the work will ultimately lead to a significantly stronger, tungsten-based monofilament.

  8. Fabrication of thermally evaporated Al thin film on cylindrical PET monofilament for wearable computing devices

    Science.gov (United States)

    Liu, Yang; Kim, Eunju; Han, Jeong In

    2016-01-01

    During the initial development of wearable computing devices, the conductive fibers of Al thin film on cylindrical PET monofilament were fabricated by thermal evaporation. Their electrical current-voltage characteristics curves were excellent for incorporation into wearable devices such as fiber-based cylindrical capacitors or thin film transistors. Their surfaces were modified by UV exposure and dip coating of acryl or PVP to investigate the surface effect. The conductive fiber with PVP coating showed the best conductivities because the rough surface of the PET substrate transformed into a smooth surface. The conductivities of PET fiber with and without PVP were 6.81 × 103 Ω-1cm-1 and 5.62 × 103 Ω-1cm-1, respectively. In order to understand the deposition process of Al thin film on cylindrical PET, Al thin film on PET fiber was studied using SEM (Scanning Electron Microscope), conductivities and thickness measurements. Hillocks on the surface of conductive PET fibers were observed and investigated by AFM on the surface. Hillocks were formed and grown during Al thermal evaporation because of severe compressive strain and plastic deformation induced by large differences in thermal expansion between PET substrate and Al thin film. From the analysis of hillock size distribution, it turns out that hillocks grew not transversely but longitudinally. [Figure not available: see fulltext.

  9. Study of clean up procedures using Charcoal-Alumina-Celite column, immunoaffinity column and strata x column to determine deoxynivalenol by high performance liquid chromatography in wheat

    Directory of Open Access Journals (Sweden)

    Jacqueline Cea

    2011-04-01

    Full Text Available Fusarium graminearum is the most common toxic fungal species affecting grains in Uruguay. Since 1977, due to favorable climate conditions, there have been harvests with prominent Fusarium Head Blight in wheat. This were in 1984, 1990, 1993, 1996 and 2001.Natural Toxin Department of Technological Laboratory of Uruguay as National Reference Laboratory, is continuously improving the analytical methods in order to have a good response to the industry requirements and to the monitoring programs for import and exports commodities. The objective of this work was to compare different clean up methods in order to select the best one for routine determination of deoxynivalenol (DON in wheat (grain and flour.  Charcoal-alumina-celite (7+5+3,  immunoaffinity columns DONPREP R-Biopharm Rhone and Strata X 33 m polymeric sorbent  Phenomenex columns were used to perform the study. Considering as reference analytical method the internal protocol  PEC.TOX.063 accredited by United Kingdom Accreditation Service (UKAS  following the ISO 17025 requirements, and  based on AOAC method 986.17( chapter 49, 2002 for extraction and clean-up  and on J.AOAC 70(3, 1987:479-483 for the high performance liquid chromatography (HPLC detection, two more clean up methods were evaluated. In all of them PEC.TOX.063 detection procedure was carried out. PEC.TOX.063 used for the clean up an in house column chromatography prepared with charcoal-alumina-celite (7+5+3 . Extraction was performed using acetonitrile- water (84+16 and an aliquot of the extract was passed through the column. Extract was dryed under vacuum and DON detected by HPLC using photodiode array detector. For the method that used immunoaffinity columns, water was the extraction solvent, and manufacture protocol was followed up. An aliquot of the extract was passed through the column. Column was washed using water and DON eluated using methanol 100%. For the method that used Strata X column for the clean up, the

  10. Continuing Clean-up at Oak Ridge, Portsmouth and Paducah-Successes and Near-Term Plans

    Energy Technology Data Exchange (ETDEWEB)

    Fritz, L. L.; Houser, S. M.; Starling, D. A.

    2002-02-26

    This paper describes the complexities and challenges associated with the Oak Ridge Environmental Management (EM) cleanup program and the steps that DOE and Bechtel Jacobs Company LLC (the Oak Ridge EM team) have collaboratively taken to make significant physical progress and get the job done. Maintaining significant environmental cleanup progress is a daunting challenge for the Oak Ridge EM Team. The scale and span of the Oak Ridge Operations (ORO) cleanup is immense-five major half-century-old installations in three states (three installations are complete gaseous diffusion plants), with concurrent cleanup at the fully operational Oak Ridge National Laboratory and Y-12 National Security Complex, and with regulatory oversight from three states and two United States (US) Environmental Protection Agency (EPA) Regions. Potential distractions arising from funding fluctuations and color-of-money constraints, regulatory negotiations, stakeholder issues, or any one of a number of other potential delay phenomena can not reduce the focus on safely achieving project objectives to maintain cleanup momentum.

  11. Development and demonstration of a mobile reverse osmosis adsorption treatment system for environmental emergency clean-ups

    Energy Technology Data Exchange (ETDEWEB)

    1988-03-01

    A project was undertaken to develop and demonstrate a mobile reverse osmosis/adsorption system for treating water contaminated by organic chemicals. The system has two primary unit operations. The contaminated water is processed by reverse osmosis to produce a clean stream for discharge and a stream for further processing in which the organic contaminants have been concentrated up to 10 times their original concentration. The latter stream is treated in granular adsorbent columns where the contaminants are removed and an effluent suitable for discharge is produced. The contaminated water can be treated on-site and the contaminants can be removed from the site adsorbed on a relatively small amount of carbon. Field tests were conducted at two sites, one contaminated by leachate from a former chemical waste landfill and the other by drainage water from a petroleum and petrochemical transfer station. The 60-day demonstrations showed that reverse osmosis technology can be successfully used for treatment of water contaminated by toxic volatile organics and that granular activated carbon adsorption columns can be successfully used to remove those organics from the concentrate produced by reverse osmosis processing. However, the study also showed that the presence of significant quantities of suspended materials or Fe cause operational problems which limit the success of reverse osmosis processing under these conditions. These problems can be effectively addressed by adding an ultrafiltration pretreatment. 13 refs., 60 figs., 56 tabs.

  12. Dispersive solid-phase extraction as a simplified clean-up technique for biological sample extracts. Determination of polybrominated diphenyl ethers by gas chromatography-tandem mass spectrometry.

    Science.gov (United States)

    Fontana, Ariel R; Camargo, Alejandra; Martinez, Luis D; Altamirano, Jorgelina C

    2011-05-06

    Dispersive solid-phase extraction (DSPE) is proposed for the first time as a simplified, fast and low cost clean-up technique of biological sample extracts for polybrominated diphenyl ethers (PBDEs) determination. The combination of a traditional extraction technique, such as ultrasound-assisted leaching (USAL) with DSPE was successfully applied for sample preparation prior to gas chromatography-tandem mass spectrometry (GC-MS/MS) analysis. The analytes were first extracted from 1g homogenized sample in n-hexane:dichloromethane (8:2) by applying USAL technique and further cleaned-up using DSPE with 0.20 g C(18)-silica as sorbent material. Different solvent mixtures, sorbent type and amount, and lipid digestion procedures were evaluated in terms of clean-up and extraction efficiency. Under optimum conditions, the method detection limits (MDLs) for PBDEs, calculated as three times the signal-to-noise ratio (S/N) were within the range 9-44 pg g(-1) wet weight. The calibration graphs were linear within the concentration range of 53-500,000 pg g(-1), 66-500,000 pg g(-1), 89-500,000 pg g(-1) and 151-500,000 pg g(-1) for BDE-47, BDE-100, BDE-99 and BDE-153, respectively; and the coefficient of determination (r(2)) exceeded 0.9992 for all analytes. The proposed methodology was compared with a reference solid-phase extraction technique. The applicability of the methodology for the screening of PBDEs has been demonstrated by analyzing spiked and real samples of biological nature (fish, egg and chicken) with different lipid content as well as reference material (WELL-WMF-01). Recovery values ranged between 75% and 114% and the measured concentrations in certified material showed a reasonable agreement with the certified ones. BDE-47, BDE-100 and BDE-99 were quantified in three of the seven analyzed samples and the concentrations ranged between 91 and 140 pg g(-1). In addition, this work is the first description of PBDEs detected in fish of Argentinean environment.

  13. An exercise on clean-up actions in an urban environment after a nuclear accident. Report of the NKS EKO 4 programme

    Energy Technology Data Exchange (ETDEWEB)

    French, S. [ed.] [Leeds Univ. (United Kingdom). School of Computer Studies; Finck, R. [ed.] [Swedish Radiation Protection Inst., Stockholm (Sweden); Haemaelaeinen, R. [ed.] [Helsinki Univ. of Technology, Espoo (Finland); Naadland, E. [ed.] [Norwegian Radiation Protection Authority, Oesteraas (Norway); Roed, J. [ed.] [Risoe National Lab., Roskilde (Denmark); Salo, A. [ed.] [Helsinki (Finland); Sinkko, K. [ed.] [Finnish Centre for Radiation and Nuclear Safety, Helsinki (Finland)

    1996-03-01

    The EKO 4/c working group of the environmental effects and emergency preparedness programme (EKO) of the Nordic Nuclear Safety Research (NKS) organised a decision conference on August 30th and 31st, 1995 in Stockholm, Sweden. The meeting was designed to be attended by those responsible for planning and deciding on protective actions in the Nordic countries after a nuclear accident. Issues concerning clean-up strategies in an urban environment after a hypothetical and very severe reactor accident were discussed at the meeting. The objectives of the meeting were to provide a shared understanding between the decision makers and the radiation protection community on concerns and issues related to decision on protective actions after a nuclear accident. (6 refs., 2 figs., 3 tabs.).

  14. Determination of BPA, BPB, BPF, BADGE and BFDGE in canned energy drinks by molecularly imprinted polymer cleaning up and UPLC with fluorescence detection.

    Science.gov (United States)

    Gallo, Pasquale; Di Marco Pisciottano, Ilaria; Esposito, Francesco; Fasano, Evelina; Scognamiglio, Gelsomina; Mita, Gustavo Damiano; Cirillo, Teresa

    2017-04-01

    A new method for simultaneous determination of five bisphenols in canned energy drinks by UPLC with fluorescence detection, after clean up on molecularly imprinted polymers, is herein described. The method was validated at two concentration levels, calculating trueness, repeatability and within-laboratory reproducibility, specificity, linearity of detector response, the limits of quantifications and the limits of detection for each bisphenol. The method is specific, reliable and very sensitive, allowing for determination of bisphenol F diglycidyl ether (BFDGE), bisphenol A (BPA), bisphenol B (BPB), bisphenol F (BPF) and bisphenol A diglycidyl ether (BADGE) down to 0.50ng/mL; it was employed to determine contamination levels from these bisphenols in forty energy drinks of different brands, collected from the market in Naples. BPA was detected in 17 out of 40 samples (42.5%); in some energy drinks also BPF, BADGE and BFDGE were determined.

  15. On-line clean-up and screening of oxacillin and cloxacillin in human urine and plasma with a weak ion exchange monolithic column.

    Science.gov (United States)

    Yang, Gengliang; Feng, Sha; Liu, Haiyan; Yin, Junfa; Zhang, Li; Cai, Liping

    2007-07-01

    A weak ion exchange monolithic column prepared by modifying the GMA-MAA-EDMA (glycidyl methacrylate-methacrylic acid-ethylene glycol dimethacrylate) monoliths with ethylenediamine was applied to remove matrix compounds in biological fluid. Using this monolithic column, on-line clean-up and screening of oxacillin and cloxacillin in human urine and plasma samples had been investigated. Chromatography was performed by reversed-phase HPLC on a C(18) column with ultraviolet detection at 225 nm. Results showed that the ion exchange monolithic column could be used for deproteinization and retaining oxacillin and cloxacillin in human urine and plasma, which provided a simple and fast method for assaying drugs in human urine and plasma.

  16. Microwave-assisted extraction at atmospheric pressure coupled to different clean-up methods for the determination of organophosphorus pesticides in olive and avocado oil.

    Science.gov (United States)

    Fuentes, Edwar; Báez, María E; Díaz, Juan

    2009-12-18

    An effective extraction method was devised for the determination of organophosphorus pesticides (OPPs) in olive and avocado oil samples, using atmospheric pressure microwave-assisted liquid-liquid extraction (APMAE) and solid-phase extraction or low-temperature precipitation as clean-up step. A simple glass system equipped with an air-cooled condenser was designed as an extraction vessel. The pesticides were partitioned between acetonitrile and oil solution in hexane. Analytical determinations were carried out by gas chromatography-flame photometric detection and gas chromatography-tandem mass spectrometry, using a triple quadrupole mass analyzer, for confirmation purposes. Several factors influencing the extraction efficiency were investigated and optimized through fractional factorial design and Doehlert design. Under optimal conditions the recovery of pesticides from oil at 0.025 microg g(-1) ranged from 71% to 103%, except for fenthion in avocado oil, with RSDs avocado oils produced in Chile. Detectable residues of different OPPs were observed in 85% of samples.

  17. Simultaneous determination of four aflatoxins and ochratoxin A in ginger and related products by HPLC with fluorescence detection after immunoaffinity column clean-up and postcolumn photochemical derivatization.

    Science.gov (United States)

    Wen, Jing; Kong, Weijun; Wang, Jian; Yang, Meihua

    2013-12-01

    Ginger, a widely used spice and traditional Chinese medicine, is prone to be contaminated by mycotoxins. A simple, sensitive, and reproducible method based on immunoaffinity column clean-up coupled with HPLC and on-line postcolumn photochemical derivatization with fluorescence detection was developed for the simultaneous determination of aflatoxins (AFs) B1 , B2 , G1 , G2 , and ochratoxin A (OTA) in 25 batches of gingers and related products marketed in China for the first time. The samples were first extracted by ultrasonication with methanol/water (80:20, v/v) and then cleaned up with immunoaffinity columns for analysis. Under the optimized conditions, the LODs and LOQs for the five mycotoxins were 0.03-0.3 and 0.1-0.9 μg/kg, respectively. The average recoveries ranged from 81.3-100.8% for AFs and from 88.6-99.5% for OTA at three spiking levels. Good linearity was observed for the analytes with correlation coefficients all >0.9995. All moldy gingers were contaminated with at least one kind of the five investigated mycotoxins, while none of them were found in normal gingers. Ginger powder samples were contaminated slightly with the contamination levels below the LOQs, while ginger tea bags were mainly contaminated by OTA at 1.05-1.19 μg/kg and ginger black tea bags were mainly contaminated by AFs at 3.37-5.76 μg/kg. All the contamination levels were below the legally allowable limits.

  18. Determination of endocrine disrupting compounds in fish liver, brain, and muscle using focused ultrasound solid-liquid extraction and dispersive solid phase extraction as clean-up strategy.

    Science.gov (United States)

    Ros, Oihana; Vallejo, Asier; Olivares, Maitane; Etxebarria, Nestor; Prieto, Ailette

    2016-08-01

    This study describes a new method for the simultaneous extraction of several endocrine disrupting compounds, including alkylphenols (APs), estrogen, bisphenol-A (BPA) and one phthalate metabolite (mono-2-ethylhexyl ester, MEHP) in fish liver, brain, and muscle. Parameters affecting the extraction (extraction solvent and temperature) and the clean-up (dispersive phase nature and amount) steps were evaluated. The extraction was performed by means of focused ultrasound solid-liquid extraction (FUSLE) using 10 mL of n-hexane:acetone (50:50, v/v) for 5 min at ~0 °C, and the clean-up was done by means of dispersive solid phase extraction (dSPE) using 100 mg of ENVI-CARB and 100 mg of MgSO4 for the cleaning of brain and muscle extracts together with 100 mg of PSA in the case of liver extracts. Good apparent recoveries were obtained in the case of liver (62-132 %), brain (66-120 %), and muscle (74-129 %), relative standard deviation (RSD%) was always below 26 %, and the method detection limits (MDLs) were at low ng/g level. The developed method was applied to fish captured in Urdaibai estuary (Bay of Biscay) in December 2015, and the concentrations obtained were in the range MDL-1115 ng/g in brain, MDL-962 ng/g in muscle, and MDL-672 ng/g in liver. In general, the highest concentrations were measured in liver, followed by brain and muscle. In addition, diethylstilbestrol was only detected in fish brain. Graphical Abstract MS method scheme for the/MS method scheme for the determination of EDCs in fish liver, brain and muscle.

  19. Simultaneous analysis of organochlorinated pesticides (OCPs) and polychlorinated biphenyls (PCBs) from marine samples using automated pressurized liquid extraction (PLE) and Power Prep™ clean-up.

    Science.gov (United States)

    Helaleh, Murad I H; Al-Rashdan, Amal; Ibtisam, A

    2012-05-30

    An automated pressurized liquid extraction (PLE) method followed by Power Prep™ clean-up was developed for organochlorinated pesticide (OCP) and polychlorinated biphenyl (PCB) analysis in environmental marine samples of fish, squid, bivalves, shells, octopus and shrimp. OCPs and PCBs were simultaneously determined in a single chromatographic run using gas chromatography-mass spectrometry-negative chemical ionization (GC-MS-NCI). About 5 g of each biological marine sample was mixed with anhydrous sodium sulphate and placed in the extraction cell of the PLE system. PLE is controlled by means of a PC using DMS 6000 software. Purification of the extract was accomplished using automated Power Prep™ clean-up with a pre-packed disposable silica column (6 g) supplied by Fluid Management Systems (FMS). All OCPs and PCBs were eluted from the silica column using two types of solvent: 80 mL of hexane and a 50 mL mixture of hexane and dichloromethane (1:1). A wide variety of fish and shellfish were collected from the fish market and analyzed using this method. The total PCB concentrations were 2.53, 0.25, 0.24, 0.24, 0.17 and 1.38 ng g(-1) (w/w) for fish, squid, bivalves, shells, octopus and shrimp, respectively, and the corresponding total OCP concentrations were 30.47, 2.86, 0.92, 10.72, 5.13 and 18.39 ng g(-1) (w/w). Lipids were removed using an SX-3 Bio-Beads gel permeation chromatography (GPC) column. Analytical criteria such as recovery, reproducibility and repeatability were evaluated through a range of biological matrices. Copyright © 2012 Elsevier B.V. All rights reserved.

  20. Threshold for detection of diabetic peripheral sensory neuropathy using a range of research grade monofilaments in persons with Type 2 diabetes mellitus.

    Science.gov (United States)

    Thomson, Mary P; Potter, Julia; Finch, Paul M; Paisey, Richard B

    2008-09-11

    To identify the threshold of reduced sensory perception in Type 2 diabetes mellitus (Type 2 DM) using a range of research grade monofilaments. Three groups of participants were recruited into a between subject, cross-sectional study. Group 1(NEW), persons with Type 2 DM diagnosed for less than 2 years (n = 80); Group 2 (EST) persons with Type 2 DM diagnosed for more than 2 years (n = 91), and Group 3, a Comparison group without Type 2 DM (n = 73), resulted in a total study population, n = 244. Research grade monofilaments (2, 4, 6, 8 and 10-gram) were employed using standardised protocol, at 6 sites on the plantar aspect of both feet. The demographic and anthropometric measures of gender, age, height, weight, body mass index (BMI), blood pressure and duration of Type 2 DM since diagnosis (if applicable) of the participants were analysed. Perception of the research grade monofilaments differed significantly between the 3 groups (p threshold of normal perception, based on 90% of the Comparison group perceiving the 6-gram monofilament at all sites in contrast to 64% of NEW and 48% of EST groups. The 6-gram monofilament was identified as the threshold of normal sensory perception. Inability to perceive the 6-gram monofilament indicates, when using the method described in this study, that diminution of sensory perception is evident. Employing a range of monofilaments, 6, 8 and 10-grams in Type 2 DM foot screening would allow the clinical detection of deteriorating sensory perception and enable implementation of foot protection strategies at an earlier stage than is currently practised.

  1. Development of a simple extraction and clean-up procedure for determination of organochlorine pesticides in soil using gas chromatography-tandem mass spectrometry.

    Science.gov (United States)

    Rashid, A; Nawaz, S; Barker, H; Ahmad, I; Ashraf, M

    2010-04-23

    A procedure based on QuEChERS extraction and a simultaneous liquid-liquid partition clean-up was developed. The procedure involved extraction of hydrated soil samples using acetonitrile and clean-up by liquid-liquid partition into n-hexane. The hexane extracts produced were clean and suitable for determination using gas chromatography-tandem mass spectrometry (GC-MS/MS). The method was validated by analysis of soil samples, spiked at five levels between 1 and 200 microg kg(-1). The recovery values were generally between 70 and 100% and the relative standard deviation values (%RSDs) were at or below 20%. The procedure was validated for determination of 19 organochlorine (OC) pesticides. These were hexachlorobenzene (HCB), alpha-HCH, beta-HCH, gamma-HCH, heptachlor, heptachlor epoxide (trans), aldrin, dieldrin, chlordane (trans), chlordane (cis), oxychlordane, alpha-endosulfan, beta-endosulfan, endosulfan sulfate, endrin, p,p'-DDT, o,p'-DDT, p,p'-DDD and p,p'-DDE. The method achieved low limits of detection (LOD; typically 0.3 microg kg(-1)) and low limits of quantification (LOQ; typically 1.0 microg kg(-1)). The method performance was also assessed using five fortified soil samples with different physico-chemical properties and the method performance was consistent for the different types of soil samples. The proposed method was compared with an established procedure based on Soxtec extraction. This comparison was carried out using six soil samples collected from regions of Pakistan with a history of intensive pesticide use. The results of this comparison showed that the two procedures produced results with good agreement. The proposed method produced cleaner extracts and therefore led to lower limits of quantification. The proposed method was less time consuming and safer to use. The six samples tested during this comparison showed that soils from cotton growing regions contained a number of persistent OC residues at relatively low levels (<10 microg kg(-1)). These

  2. Biodegradation of 2,3,7,8 TCDD by anaerobic and aerobic microcosms collected from bioremediation treatments for cleaning up dioxin contaminated soils

    Energy Technology Data Exchange (ETDEWEB)

    Ha, Dang Thi; Tuan, Mai Anh; Viet, Nguyen Quoc; Sanh, Nguyen Thi [Vietnamese Academy of Science and Technology (VAST) (Viet Nam). Inst. of Biotechnology; Sau, Trinh Khac [Vietnam-Russian Tropical Center (Viet Nam); Papke, O. [ERGO Forschungsgesellschaft, Hamburg (Germany)

    2004-09-15

    There are many microbes that can degrade polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurants (PCDFs) and polychlorinated biphenyls (PCBs) have been isolated including purified bacteria, actinomycetes, white rods, filamentous fungi, anaerobes and also anaerobic and aerobic consortia. Bioremediation one of biological remediation has been studied as hopeful alternative to physical and chemical treatments that using for cleaning up PCDDs, PCDFs. In Vietnam for cleaning up ''hot spot'' of some former military air bases, bioremediation has been studying in different scales of Danang site. After 18 to 24 month treatments, the reduction of toxicity was significally detected. In order to study biodegradability by different groups and one of dominated strain that are existing microorganisms in our treatments, the investigation of 2,3,7,8 TCDD anaerobic and aerobic degradations was carried out in the laboratory condition. Anaerobic microbial consortium containing three different bacteria such as two Gram- negative vibrio and rod and one gram positive cocoides bacteria. This consortium could degrade 118 pg TEQ/ml 2,3,7,8 TCDD after 133 days under sulfate reduction. Concentration of 2,3,7,8 TCDD in the soil extract that adding to medium at starting point of cultivation was 144.6 pg TEQ/ml. About 81% toxicity was removed. Aerobic consortium containing all three Gram-negative bacteria and one fungal strain. After 9 day shaking at 180 rpm/min and 30 C, 85.6 % of 164.45 pg TEQ/ml 2,3,7,8 TCDD was removed. Other preliminary results of study of 2,3,7,8 TCDD biodegradation as sole carbon and energy by show that this strain FDN30 could remove 43,45 pg TEQ/ml (59%) of 73,1 pgTEQ/ml adding dioxin after two weeks. These findings explain why high concentration of contaminants in treated soil was decreased after two year treatment. Indigenous microorganisms play leading role in the detoxification of 2,3,7,8 TCDD in contaminated soils.

  3. Biodegradation of 2,3,7,8 TCDD by anaerobic and aerobic microcosms collected from bioremediation treatments for cleaning up dioxin contaminated soils

    Energy Technology Data Exchange (ETDEWEB)

    Ha, Dang Thi; Tuan, Mai Anh; Viet, Nguyen Quoc; Sanh, Nguyen Thi [Vietnamese Academy of Science and Technology (VAST) (Viet Nam). Inst. of Biotechnology; Sau, Trinh Khac [Vietnam-Russian Tropical Center (Viet Nam); Papke, O. [ERGO Forschungsgesellschaft, Hamburg (Germany)

    2004-09-15

    There are many microbes that can degrade polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurants (PCDFs) and polychlorinated biphenyls (PCBs) have been isolated including purified bacteria, actinomycetes, white rods, filamentous fungi, anaerobes and also anaerobic and aerobic consortia. Bioremediation one of biological remediation has been studied as hopeful alternative to physical and chemical treatments that using for cleaning up PCDDs, PCDFs. In Vietnam for cleaning up ''hot spot'' of some former military air bases, bioremediation has been studying in different scales of Danang site. After 18 to 24 month treatments, the reduction of toxicity was significally detected. In order to study biodegradability by different groups and one of dominated strain that are existing microorganisms in our treatments, the investigation of 2,3,7,8 TCDD anaerobic and aerobic degradations was carried out in the laboratory condition. Anaerobic microbial consortium containing three different bacteria such as two Gram- negative vibrio and rod and one gram positive cocoides bacteria. This consortium could degrade 118 pg TEQ/ml 2,3,7,8 TCDD after 133 days under sulfate reduction. Concentration of 2,3,7,8 TCDD in the soil extract that adding to medium at starting point of cultivation was 144.6 pg TEQ/ml. About 81% toxicity was removed. Aerobic consortium containing all three Gram-negative bacteria and one fungal strain. After 9 day shaking at 180 rpm/min and 30 C, 85.6 % of 164.45 pg TEQ/ml 2,3,7,8 TCDD was removed. Other preliminary results of study of 2,3,7,8 TCDD biodegradation as sole carbon and energy by show that this strain FDN30 could remove 43,45 pg TEQ/ml (59%) of 73,1 pgTEQ/ml adding dioxin after two weeks. These findings explain why high concentration of contaminants in treated soil was decreased after two year treatment. Indigenous microorganisms play leading role in the detoxification of 2,3,7,8 TCDD in contaminated soils.

  4. Recycling Facilities - Mine Drainage Treatment/Land Recycling Project Locations

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — Mine Drainage Treatment/Land Reclamation Locations are clean-up projects that are working to eliminate some form of abandoned mine. The following sub-facility types...

  5. Trivalent copper chelate-luminol chemiluminescence system for highly sensitive CE detection of dopamine in biological sample after clean-up using SPE.

    Science.gov (United States)

    Wang, Lin; Liu, Ying; Xie, Haoyue; Fu, Zhifeng

    2012-06-01

    A transition metal chelate unstable at a high oxidation state, diperiodatocuprate (III) (K₅[Cu(HIO₆)₂], DPC), was synthesized and applied in the luminol-based chemiluminescence (CL) system for highly sensitive CE end-column detection of dopamine (DA). This method was based on the fact that DA enhanced the CL emission resulting from the reaction between luminol and DPC in alkaline medium. The DPC-luminol-DA CL system showed very intensive emission and very fast kinetic characteristics, thus resulting in a high sensitivity in flow-through detection mode for CE. Under optimal conditions, the linear range was 1.0 × 10⁻⁸-5.0 × 10⁻⁵ g/mL (R² = 0.9984) with a limit of detection of 6.0 × 10⁻⁹ g/mL (S/N = 3). The RSDs of the peak height and the migration time were about 4.2 and 2.4% for a standard sample at 3.0 × 10⁻⁶ g/mL (n = 5), respectively. The presented method has been successfully used for the determination of DA in commercial preparation and human urine samples after clean-up using SPE.

  6. Results of the clean-up operation to reduce pollution on flooded agricultural fields after the red mud spill in Hungary.

    Science.gov (United States)

    Uzinger, Nikolett; Anton, Áron Dániel; Ötvös, Károly; Tamás, Péter; Anton, Attila

    2015-07-01

    In Hungary, the dam of a red mud reservoir breached shortly after noon on October 4, 2010. Approximately 0.7-1 million m(3) highly alkaline red mud with very low dry matter content flowed into the Torna Creek and the surrounding area, covering 1017 ha of agricultural land. Results of the risk assessment of the accident indicated that the red mud should be removed from the surface of fields where it formed a continuous layer of more than 5 cm. After the removal, samples were taken manually from depths of 0.0-0.2 m and 0.2-0.4 m in a sampling grid and background samples unaffected by red mud from the depth of 0.0-0.3 m. Total element contents (Ag, As, Ba, Cd, Co, Cr, Cu, Hg, Mo, Ni, Pb, Sn, Zn, and Na) and pH values were measured, and the results were analysed using correlation analysis and the Kruskal-Wallis probe. Dependence of the measured variables from elevation above sea level was studied using a 10 m by 10 m digital elevation model. Only ∼6.5% of the flooded area was temporarily designated as unsuitable for the production of food and fodder crops. In summary, the clean-up operation can be said to have been a success.

  7. Development of a bi-functional silica monolith for electro-osmotic pumping and DNA clean-up/extraction using gel-supported reagents in a microfluidic device.

    Science.gov (United States)

    Oakley, Jennifer A; Shaw, Kirsty J; Docker, Peter T; Dyer, Charlotte E; Greenman, John; Greenway, Gillian M; Haswell, Stephen J

    2009-06-07

    A silica monolith used to support both electro-osmotic pumping (EOP) and the extraction/elution of DNA coupled with gel-supported reagents is described. The benefits of the combined EOP extraction/elution system were illustrated by combining DNA extraction and gene amplification using the polymerase chain reaction (PCR) process. All the reagents necessary for both processes were supported within pre-loaded gels that allow the reagents to be stored at 4 degrees C for up to four weeks in the microfluidic device. When carrying out an analysis the crude sample only needed to be hydrodynamically introduced into the device which was connected to an external computer controlled power supply via platinum wire electrodes. DNA was extracted with 65% efficiency after loading lysed cells onto a silica monolith. Ethanol contained within an agarose gel matrix was then used to wash unwanted debris away from the sample by EOP (100 V cm(-1) for 5 min). The retained DNA was subsequently eluted from the monolith by water contained in a second agarose gel, again by EOP using an electric field of 100 V cm(-1) for 5 min, and transferred into the PCR reagent containing gel. The eluted DNA in solution was successfully amplified by PCR, confirming that the concept of a complete self-contained microfluidic device could be realised for DNA sample clean up and amplification, using a simple pumping and on-chip reagent storage methodology.

  8. Analysis of endocrine disruptor compounds in marine sediments by in cell clean up-pressurized liquid extraction-liquid chromatography tandem mass spectrometry determination.

    Science.gov (United States)

    Salgueiro-González, N; Turnes-Carou, I; Muniategui-Lorenzo, S; López-Mahía, P; Prada-Rodríguez, D

    2014-12-10

    A less time-, solvent- and sorbent-consuming analytical methodology for the determination of bisphenol A and alkylphenols (4-tert-octylphenol, 4-octylphenol, 4-n-nonylphenol, nonylphenol) in marine sediment was developed and validated. The method was based on selective pressurized liquid extraction (SPLE) with a simultaneous in cell clean up combined with liquid chromatography-electrospray ionization tandem mass spectrometry in negative mode (LC-ESI-MS/MS). The SPLE extraction conditions were optimized by a Plackett-Burman design followed by a central composite design. Quantitation was performed by standard addition curves in order to correct matrix effects. The analytical features of the method were satisfactory: relative recoveries varied between 94 and 100% and repeatability and intermediate precision were <6% for all compounds. Uncertainty assessment of measurement was estimated on the basis of an in-house validation according to EURACHEM/CITAC guide. Quantitation limits of the method (MQL) ranged between 0.17 (4-n-nonylphenol) and 4.01 ng g(-1) dry weight (nonylphenol). Sensitivity, selectivity, automaticity and fastness are the main advantages of this green methodology. As an application, marine sediment samples from Galicia coast (NW of Spain) were analysed. Nonylphenol and 4-tert-octylphenol were measured in all samples at concentrations between 20.1 and 1409 ng g(-1) dry weight, respectively. Sediment toxicity was estimated and no risk to aquatic biota was found.

  9. In-house validation of an improved sample extraction and clean-up method for GC determination of isomers of nervonic acid in meat products.

    Science.gov (United States)

    Agazzi, Marie-Elisabeth; Bau, Andrea; Barcarolo, Robertino; Luecker, Ernst; Barrero-Moreno, Josefa; Anklam, Elke

    2003-06-01

    An improved extraction and clean-up method for determination of brain-specific fatty acids, in particular lignoceric acid (C24:0) and the cis/ trans isomers of nervonic acid (15 c-t C24:1), in meat products has been developed. The method is based on isolation of the polar lipids of interest from the bulk lipids by solid-phase extraction. The fatty acids, derivatised to their fatty acid methyl esters, are quantified by GC in a DB5 column. Fresh meat samples were extracted by using a mixture of n-butanol:hexane (1:9) as solvent. The extract was loaded in a silica gel cartridge column previously equilibrated with hexane. The first fraction containing the major part of the fat was eluted with hexane while acetone and methanol allowed the elution of fatty acids bound to polar moieties such as nervonic and lignoceric acids. This second fraction containing the analyte was methylated and injected into the GC for quantification after addition octacosane (C(28)) as internal standard.

  10. In-cell clean-up pressurized liquid extraction and gas chromatography-tandem mass spectrometry determination of hydrophobic persistent and emerging organic pollutants in coastal sediments.

    Science.gov (United States)

    Pintado-Herrera, Marina G; González-Mazo, Eduardo; Lara-Martín, Pablo A

    2016-01-15

    The main goal of this work was to develop, optimize and validate a multi-residue method for the simultaneous determination of 97 contaminants, including fragrances, UV filters, repellents, endocrine disruptors, biocides, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), organophosphorus flame retardants, and several types of pesticides in marine sediment samples. Extraction and cleanup were integrated into the same step using pressurized liquid extraction (PLE) with in-cell clean-up (1g of alumina). The extraction was performed using dichloromethane at 100 °C, 1500 psi and 3 extraction cycles (5 min per cycle). Extracts were derivatized with N-(tert-butyldimethylsilyl)-N-methyltrifluoroacetamide (MTBSTFA) to improve the signal and sensitivity of some target compounds (i.e., triclosan, 2-hydroxybenzophenone). Separation, identification and quantification of analytes were carried out by gas chromatography (GC) coupled to tandem mass spectrometry. Under optimal conditions, the optimized protocol showed good recovery percentages (70-100%), linearity (>0.99) and limits of detection below 1 ng g(-1) for all compounds. Finally, the method was applied to the analysis of sediment samples from different coastal areas from Andalusia (Spain), where occurrence and distribution of emerging contaminants in sediments is very scarce. Twenty five compounds out of 98 were detected in all samples, with the endocrine disruptor nonylphenol and the fragrance galaxolide showing the highest concentrations, up to 377.6 ng g(-1) and 237.4 ng g(-1), respectively.

  11. Screening of pollution control and clean-up materials for river chemical spills using the multiple case-based reasoning method with a difference-driven revision strategy.

    Science.gov (United States)

    Liu, Rentao; Jiang, Jiping; Guo, Liang; Shi, Bin; Liu, Jie; Du, Zhaolin; Wang, Peng

    2016-06-01

    In-depth filtering of emergency disposal technology (EDT) and materials has been required in the process of environmental pollution emergency disposal. However, an urgent problem that must be solved is how to quickly and accurately select the most appropriate materials for treating a pollution event from the existing spill control and clean-up materials (SCCM). To meet this need, the following objectives were addressed in this study. First, the material base and a case base for environment pollution emergency disposal were established to build a foundation and provide material for SCCM screening. Second, the multiple case-based reasoning model method with a difference-driven revision strategy (DDRS-MCBR) was applied to improve the original dual case-based reasoning model method system, and screening and decision-making was performed for SCCM using this model. Third, an actual environmental pollution accident from 2012 was used as a case study to verify the material base, case base, and screening model. The results demonstrated that the DDRS-MCBR method was fast, efficient, and practical. The DDRS-MCBR method changes the passive situation in which the choice of SCCM screening depends only on the subjective experience of the decision maker and offers a new approach to screening SCCM.

  12. Eğirdir Gölü' nde Monofilament ve Multifilament Sade Uzatma Ağlarının Av ve Ekonomik Verimliliklerinin Karşılaştırılması

    Directory of Open Access Journals (Sweden)

    Mustafa İlker SÜRER

    2014-07-01

    Full Text Available The use of monofilament gill nets were prohibited from 2011 fishing period. Fishing efficiency of monofilament gill nets with multifilament gill nets were investigated effect on region fishing. In this study, catch efficiencies of the same features monofilament and multifilament 80, 90, 100, 110 and 120 mm mesh size gill nets compared within including from November 2009 to November 2010 in Egirdir Lake. As a result of this study, according to the fishing, productivity was found more plentiful in monofilament gill nets than multifilament gill nets. The highest fishing productivity of 90 mm monofilament gill net 15925 g (23.66% and the lowest 80 mm multifilament gill net 997 g (4.12% for caught most (%92,50 in total fishing of Prussian carp, Carassius gibelio, (Bloch, 1782 were found

  13. 3D characterization of thermal fatigue damage in monofilament reinforced copper for heat sink applications in fusion reactor systems; 3D-Charakterisierung von thermischer Ermuedungsschaedigung in Monofilament verstaerktem Kupfer zur Anwendung als Waermeleiter in Kernfusionsreaktorsystemen

    Energy Technology Data Exchange (ETDEWEB)

    Schoebel, Michael; Degischer, H. Peter [Vienna Univ. of Technology (Austria). Inst. of Materials Science and Technology; Brendel, Annegret [Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Harrer, Bernhard [Upper Austria Univ. of Applied Sciences, Wels (Austria); Di Michiel, Marco [European Synchrotron Radiation Facility (ESRF), 38 - Grenoble (France)

    2012-07-01

    Monofilament reinforced metals (MFRM) are developed as high temperature heat sink materials for fusion reactor applications. These composites combine the high thermal conductivity (TC) of a Cu matrix with low thermal expansion (CTE) of SiC or W filaments. The CTE mismatch between matrix and reinforcement lead to high micro stresses under operation conditions. Stress induced thermal fatigue damage such as interface delamination and fiber/matrix damage degrades the thermal properties of these composites. Different interface designs are developed for SiC as well as W filaments to improve bonding strength and increase the long term stability. Conventional as well as synchrotron tomography was applied on different MFRMs to characterize thermal fatigue damage and its propagation before, during and after thermal cycling. (orig.)

  14. Determination of ten steroid hormones in animal waste manure and agricultural soil using inverse and integrated clean-up pressurized liquid extraction and gas chromatography-tandem mass spectrometry

    DEFF Research Database (Denmark)

    Hansen, Martin; Krogh, Kristine A; Halling-Sørensen, Bent

    2011-01-01

    ... Martin Hansen , Kristine A. Krogh , Bent Halling ... in a 22 mL PLE cell : firstly by flushing the sample with heptane to remove unwanted matrix components (inverse- PLE , i- PLE ) and secondly, performing internal clean-up (ic- PLE ) and eluting the steroid hormones by attaching an ...

  15. Development of sample extraction and clean-up strategies for target and non-target analysis of environmental contaminants in biological matrices.

    Science.gov (United States)

    Baduel, Christine; Mueller, Jochen F; Tsai, Henghang; Gomez Ramos, Maria Jose

    2015-12-24

    Recently, there has been an increasing trend towards multi-targeted analysis and non-target screening methods as a means to increase the number of monitored analytes. Previous studies have developed biomonitoring methods which specifically focus on only a small number of analytes with similar physico-chemical properties. In this paper, we present a simple and rapid multi-residue method for simultaneous extraction of polar and non-polar organic chemicals from biological matrices, containing up to 5% lipid content. Our method combines targeted multi-residue analysis using gas chromatography triple quadrupole mass spectrometry (GC-QqQ-MS/MS) and a multi-targeted analysis complemented with non-target screening using liquid chromatography coupled to a quadrupole time of flight mass spectrometry (LC-QTOF-MS/MS). The optimization of the chemical extraction procedure and the effectiveness of different clean-up methods were evaluated for two biological matrices: fish muscle (lipid content ∼2%) and breast milk (∼4%). To extract a wide range of chemicals, the partition/extraction procedure used for the QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) approach was tested as the initial step for the extraction of 77 target compounds covering a broad compound domain. All the target analytes have different physico-chemical properties (log Kow ranges from -0.3 to 10) and cover a broad activity spectrum; from polar pesticides, pharmaceuticals, personal care products (PPCPs) to highly lipophilic chemicals such as polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and organochloride pesticides (OCPs). A number of options were explored for the clean-up of lipids, proteins and other impurities present in the matrix. Zirconium dioxide-based sorbents as dispersive solid-phase extraction (d-SPE) and protein-lipid removal filter cartridges (Captiva ND Lipids) provided the best results for GC-MS and LC-MS analysis

  16. Simultaneous pressurized enzymatic hydrolysis extraction and clean up for arsenic speciation in seafood samples before high performance liquid chromatography-inductively coupled plasma-mass spectrometry determination.

    Science.gov (United States)

    Moreda-Piñeiro, Jorge; Alonso-Rodríguez, Elia; Moreda-Piñeiro, Antonio; Moscoso-Pérez, Carmen; Muniategui-Lorenzo, Soledad; López-Mahía, Purificación; Prada-Rodríguez, Darío; Bermejo-Barrera, Pilar

    2010-10-29

    The feasibility of pressurized conditions to assist enzymatic hydrolysis of seafood tissues for arsenic speciation was novelty studied. A simultaneous in situ (in cell) clean-up procedure was also optimized, which speeds up the whole sample treatment. Arsenic species (As(III), MMA, DMA, As(V), AsB and AsC) were released from dried seafood tissues using pepsin as a protease, and the arsenic species were separated/quantified by anion exchange high performance liquid chromatography (HPLC) coupled to inductively coupled plasma-mass spectrometry (ICP-MS). Variables inherent to the enzymatic activity (pH, temperature and ionic strength), the amount of enzyme (pepsin), and factors affecting pressurization (pressure, static time, number of cycles and amount of dispersing agent, C-18) were fully evaluated. Pressurized assisted enzymatic hydrolysis (PAEH) with pepsin can be finished after few minutes (two cycles of 2 min each one plus 3 min to reach the hydrolysis temperature of 50 °C). A total sample solubilisation is not achieved after the procedure, however it is efficient enough for breaking down certain bonds of bio-molecules and for releasing arsenic species. The developed method has been found to be precise (RSDs lower than 6% for As(III), DMA and As(V); and 3% for AsB) and sensitive (LOQs of 18.1, 36.2, 35.7, 28.6, 20.6 and 22.5 ng/g for As(III), MMA, DMA, As(V), AsB and AsC, respectively). The optimized methodology was successfully applied to different certified reference materials (DORM-2 and BCR 627) which offer certified AsB and DMA contents, and also to different seafood products (mollusks, white fishes and cold water fishes).

  17. Development of molecularly imprinted poly(methacrylic acid)/silica for clean-up and selective extraction of cholesterol in milk prior to analysis by HPLC-UV.

    Science.gov (United States)

    Clausen, D N; Visentainer, J V; Tarley, C R T

    2014-10-07

    In the present paper the assessment of a novel molecularly imprinted polymer, poly(methacrylic acid)/silica, for clean-up and selective extraction of cholesterol in milk samples is described. The relative selectivity coefficient (k) values for cholesterol/5-α-cholestane and cholesterol/7-dehydrocholesterol systems were found to be 5.08 and 6.08, respectively, thus attesting the selectivity of the MIP for cholesterol under competitive adsorption with structurally analogous steroid compounds. The milk analysis was initially based on saponification followed by liquid-liquid extraction with n-hexane. Then, the protocol of molecularly imprinted solid phase extraction (MISPE) was carried out by loading the milk hexanic extract through 200 mg of MIP or NIP (non-imprinted polymer) packed into SPE cartridges at a flow rate of 0.6 mL min(-1). The washing step was performed by using n-hexane followed by further elution with ethanol and HPLC-UV analysis at 208 nm. From the breakthrough curve the maximum adsorption capacity of the MIP towards cholesterol was found to be 29.51 mg g(-1). The precision of the MISPE protocol was assessed as intra- and inter-days yielding RSD (relative standard deviations) lower than 4.10%. Cleaner HPLC chromatograms were obtained for milk samples submitted to the MISPE protocol in comparison to the solid phase extraction using the NIP or modified octadecyl silica (C18). Recoveries varying from 96.6 up to 102.2% for milk samples spiked with cholesterol were achieved, thus ensuring the accuracy of the proposed method.

  18. Deriving site-specific soil clean-up values for metals and metalloids: rationale for including protection of soil microbial processes.

    Science.gov (United States)

    Kuperman, Roman G; Siciliano, Steven D; Römbke, Jörg; Oorts, Koen

    2014-07-01

    Although it is widely recognized that microorganisms are essential for sustaining soil fertility, structure, nutrient cycling, groundwater purification, and other soil functions, soil microbial toxicity data were excluded from the derivation of Ecological Soil Screening Levels (Eco-SSL) in the United States. Among the reasons for such exclusion were claims that microbial toxicity tests were too difficult to interpret because of the high variability of microbial responses, uncertainty regarding the relevance of the various endpoints, and functional redundancy. Since the release of the first draft of the Eco-SSL Guidance document by the US Environmental Protection Agency in 2003, soil microbial toxicity testing and its use in ecological risk assessments have substantially improved. A wide range of standardized and nonstandardized methods became available for testing chemical toxicity to microbial functions in soil. Regulatory frameworks in the European Union and Australia have successfully incorporated microbial toxicity data into the derivation of soil threshold concentrations for ecological risk assessments. This article provides the 3-part rationale for including soil microbial processes in the development of soil clean-up values (SCVs): 1) presenting a brief overview of relevant test methods for assessing microbial functions in soil, 2) examining data sets for Cu, Ni, Zn, and Mo that incorporated soil microbial toxicity data into regulatory frameworks, and 3) offering recommendations on how to integrate the best available science into the method development for deriving site-specific SCVs that account for bioavailability of metals and metalloids in soil. Although the primary focus of this article is on the development of the approach for deriving SCVs for metals and metalloids in the United States, the recommendations provided in this article may also be applicable in other jurisdictions that aim at developing ecological soil threshold values for protection of

  19. Development of manufacturing process for large-diameter composite monofilaments by pyrolysis of resin-impregnated carbon-fiber bundles

    Science.gov (United States)

    Bradshaw, W. G.; Pinoli, P. C.; Vidoz, A. E.

    1972-01-01

    Large diameter, carbon-carbon composite, monofilaments were produced from the pyrolysis of organic precursor resins reinforced with high-strenght carbon fibers. The mechanical properties were measured before and after pyrolysis and the results were correlated with the properties of the constituents. The composite resulting from the combination of Thornel 75 and GW-173 resin precursor produced the highest tensile strength. The importance of matching strain-to-failure of fibers and matrix to obtain all the potential reinforcement of fibers is discussed. Methods are described to reduce, within the carbonaceous matrix, pyrolysis flaws which tend to reduce the composite strength. Preliminary studies are described which demonstrated the feasibility of fiber-matrix copyrolysis to alleviate matrix cracking and provide an improved matrix-fiber interfacial bonding.

  20. Operational waste volume projection

    Energy Technology Data Exchange (ETDEWEB)

    Koreski, G.M.

    1996-09-20

    Waste receipts to the double-shell tank system are analyzed and wastes through the year 2015 are projected based on generation trends of the past 12 months. A computer simulation of site operations is performed, which results in projections of tank fill schedules, tank transfers, evaporator operations, tank retrieval, and aging waste tank usage. This projection incorporates current budget planning and the clean-up schedule of the Tri-Party Agreement. Assumptions were current as of June 1996.

  1. Determination of cocaine in postmortem human liver exposed to overdose. Application of an innovative and efficient extraction/clean up procedure and gas chromatography-mass spectrometry analysis.

    Science.gov (United States)

    Magalhães, Elisângela Jaqueline; Ribeiro de Queiroz, Maria Eliana Lopes; Penido, Marcus Luiz de Oliveira; Paiva, Marco Antônio Ribeiro; Teodoro, Janaína Aparecida Reis; Augusti, Rodinei; Nascentes, Clésia Cristina

    2013-09-27

    A simple and efficient method was developed for the determination of cocaine in post-mortem samples of human liver via solid-liquid extraction with low temperature partitioning (SLE-LTP) and analysis by gas chromatography coupled to mass spectrometry (GC-MS). The extraction procedure was optimized by evaluating the influence of the following variables: pH of the extract, volume and composition of the extractor solvent, addition of a sorbent material (PSA: primary-secondary amine) and NaCl to clean up and increase the ionic strength of the extract. A bovine liver sample that was free of cocaine was used as a blank for the optimization of the SLE-LTP extraction procedure. The highest recovery was obtained when crushed bovine liver (2g) was treated with 2mL of ultrapure water plus 8mL of acetonitrile at physiological pH (7.4). The results also indicated no need for using PSA and NaCl. The complete analytical procedure was validated for the following figures of merit: selectivity, lower limit of quantification (LLOQ), calibration curve, recovery, precision and accuracy (for within-run and between-run experiments), matrix effect, dilution integrity and stability. The within-run and between-run precision (at four levels) varied from 2.1% to 9.4% and from 4.0% to 17.0%, respectively. A maximum deviation of 11.62% for the within-run and between-run accuracies in relation to the nominal concentrations was observed. Moreover, the LLOQ value for cocaine was 50.0ngg(-1) whereas no significant effects were noticed in the assays of dilution integrity and stability. To assess its overall performance, the optimized method was applied to the analysis of eight human liver samples collected from individuals who died due to the abusive consumption of cocaine. Due to the existence of a significant matrix effect, a blank human liver was used to construct a matrix-matched analytical curve. The concentrations of cocaine found in these samples ranged from 333.5 to 5969ngg(-1). Copyright

  2. Coal Mines, Reclamation Sites - Mine Drainage Treatment/Land Recycling Project Locations

    Data.gov (United States)

    NSGIC Education | GIS Inventory — Mine Drainage Treatment/Land Reclamation Locations are clean-up projects that are working to eliminate some form of abandoned mine. The following sub-facility types...

  3. The use of immunoaffinity columns connected in tandem for selective and cost-effective mycotoxin clean-up prior to multi-mycotoxin liquid chromatographic-tandem mass spectrometric analysis in food matrices.

    Science.gov (United States)

    Wilcox, Joyce; Donnelly, Carol; Leeman, David; Marley, Elaine

    2015-06-26

    This paper describes the use of two immunoaffinity columns (IACs) coupled in tandem, providing selective clean-up, based on targeted mycotoxins known to co-occur in specific matrices. An IAC for aflatoxins+ochratoxin A+fumonisins (AOF) was combined with an IAC for deoxynivalenol+zearalenone+T-2/HT-2 toxins (DZT); an IAC for ochratoxin A (O) was combined with a DZT column; and an aflatoxin+ochratoxin (AO) column was combined with a DZT column. By combining pairs of columns it was demonstrated that specific clean-up can be achieved as required for different matrices. Samples of rye flour, maize, breakfast cereal and wholemeal bread were analysed for mycotoxins regulated in the EU, by spiking at levels close to EU limits for adult and infant foods. After IAC clean-up extracts were analysed by LC-MS/MS with quantification using multiple reaction monitoring. Recoveries were found to be in range from 60 to 108%, RSDs below 10% depending on the matrix and mycotoxin combination and LOQs ranged from 0.1n g/g for aflatoxin B1 to 13.0 ng/g for deoxynivalenol. Surplus cereal proficiency test materials (FAPAS(®)) were also analysed with found levels of mycotoxins falling within the satisfactory range of concentrations (Z score ≤ ± 2), demonstrating the accuracy of the proposed multi-mycotoxin IAC methods.

  4. A microsurgical procedure for middle cerebral artery occlusion by intraluminal monofilament insertion technique in the rat: a special emphasis on the methodology.

    Science.gov (United States)

    Güzel, Aslan; Rölz, Roland; Nikkhah, Guido; Kahlert, Ulf D; Maciaczyk, Jaroslaw

    2014-01-01

    Although there are many experimental studies describing the methodology of the middle cerebral artery occlusion (MCAO) in the literature, only limited data on these distinct anatomical structures and the details of the surgical procedure in a step by step manner. The aim of the present study simply is to examine the surgical anatomy of MCAO model and its modifications in the rat. Forty Sprague-Dawley rats were used; 20 during the training phase and 20 for the main study. The monofilament sutures were prepared as described in the literature. All surgical steps of the study were performed under the operating microscope, including insertion of monofilament into middle cerebral artery through the internal carotid artery. After an extensive training period, we lost two rats in four weeks. The effects of MCAO were confirmed by the evidence of severe motor deficit during the recovery period, and histopathological findings of infarction were proved in all 18 surviving rats. In this study, a microsurgical guideline of the MCAO model in the rat is provided with the detailed description of all steps of the intraluminal monofilament insertion method with related figures.

  5. Usefulness of biodegradable stents constructed of poly-/-lactic acid monofilaments in patients with benign esophageal stenosis

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    AIM: To report 13 patients with benign esophageal stenosis treated with the biodegradable stent.METHODS: We developed a Ultraflex-type stent by knitting poly-l-lactic acid monofilaments.RESULTS: Two cases were esophageal stenosis caused by drinking of caustic liquid, 4 cases were due to surgical resection of esophageal cancers, and 7 cases were patients with esophageal cancer who received the preventive placement of biodegradable stents for postendoscopic mucosal dissection (ESD) stenosis. The preventive placement was performed within 2 to 3 d after ESD. In 10 of the 13 cases, spontaneous migration of the stents occurred between 10 to 21 d after placement. In these cases, the migrated stents were excreted with the feces, and no obstructive complications were experienced. In 3 cases, the stents remained at the proper location on d 21 after placement. No symptoms of re-stenosis were observed within the follow-up period of 7 mo to 2 years. Further treatment with balloon dilatation or replacement of the biodegradable stent was not required.CONCLUSION: Biodegradable stents were useful for the treatment of benign esophageal stenosis, particularly for the prevention of post-ESD stenosis.

  6. Combining the quick, easy, cheap, effective, rugged and safe approach and clean-up by immunoaffinity column for the analysis of 15 mycotoxins by isotope dilution liquid chromatography tandem mass spectrometry.

    Science.gov (United States)

    Desmarchelier, Aurélien; Tessiot, Sabine; Bessaire, Thomas; Racault, Lucie; Fiorese, Elisa; Urbani, Alessandro; Chan, Wai-Chinn; Cheng, Pearly; Mottier, Pascal

    2014-04-11

    Optimization and validation of a multi-mycotoxin method by LC-MS/MS is presented. The method covers the EU-regulated mycotoxins (aflatoxins, fumonisins, ochratoxin A, deoxynivalenol, zearalenone, T-2 and HT-2), as well as nivalenol and 3- and 15-acetyldeoxynivalenol for analysis of cereals, cocoa, oil, spices, infant formula, coffee and nuts. The proposed procedure combines two clean-up strategies: First, a generic preparation suitable for all mycotoxins based on the QuEChERS (for quick, easy, cheap, effective, rugged and safe) protocol. Second, a specific clean-up devoted to aflatoxins and ochratoxin A using immunoaffinity column (IAC) clean-up. Positive identification of mycotoxins in matrix was conducted according to the confirmation criteria defined in EU Commission Decision 2002/657/EC while quantification was performed by isotopic dilution using (13)C-labeled mycotoxins as internal standards. Limits of quantification were at or below the maximum levels set in the EC/1886/2006 document for all mycotoxin/matrix combinations under regulation. In particular, the inclusion of an IAC step allowed achieving LOQs as low as 0.05 and 0.25μg/kg in cereals for aflatoxins and ochratoxin A, respectively. Other performance parameters like linearity [(r)(2)>0.99], recovery [71-118%], precision [(RSDr and RSDiR)<33%], and trueness [78-117%] were all compliant with the analytical requirements stipulated in the CEN/TR/16059 document. Method ruggedness was proved by a verification process conducted by another laboratory. Copyright © 2014 Elsevier B.V. All rights reserved.

  7. 从宙斯轮案论燃油清污费用的责任限制问题%On the Limitation of Liability of Clean -up Costs of Bunker based on Zeus Case

    Institute of Scientific and Technical Information of China (English)

    庞凯华

    2015-01-01

    Maritime safety administration of sinking, killed, stranded ship compulsory clean-up measures to produce fuel oil clean-up costs, after the Supreme Court Zeus rounds a case as a nonrestrictive creditor' s rights, it is conform to the law, but also to ensure the maritime safety administration in the practice of sewage disposal cost of pay of full specified amount. For fuel oil clean-up fees shall apply for maritime claims limit judicial interpretation from the supreme people' s court "the 17th paragraph 1 and the oil from the supreme people' s court judicial interpretation" stipulated in article 20 as unrestricted claims. Take effect at the same time soon the Nairobi convention on international debris removal has important significance for China' s leg-islation.%海事局对沉没、遇难、搁浅船舶采取强制清污措施产生的燃油清污费用,最高院在宙斯轮一案中认定为非限制性债权.此举既符合法律规定,同时也保障了实践中海事局清污费用的足额偿付.对于燃油清污费用应适用《最高院海事赔偿限制司法解释》第17条1款和《最高院油污司法解释》第20条规定认定为非限制性债权.同时生效不久的《内罗毕国际残骸清除公约》对于我国立法具有重要借鉴意义.

  8. The Debrisoft(®) Monofilament Debridement Pad for Use in Acute or Chronic Wounds: A NICE Medical Technology Guidance.

    Science.gov (United States)

    Meads, Catherine; Lovato, Eleonora; Longworth, Louise

    2015-12-01

    As part of its Medical Technology Evaluation Programme, the National Institute for Health and Care Excellence (NICE) invited a manufacturer to provide clinical and economic evidence for the evaluation of the Debrisoft(®) monofilament debridement pad for use in acute or chronic wounds. The University of Birmingham and Brunel University, acting as a consortium, was commissioned to act as an External Assessment Centre (EAC) for NICE, independently appraising the submission. This article is an overview of the original evidence submitted, the EAC's findings and the final NICE guidance issued. The sponsor submitted a simple cost analysis to estimate the costs of using Debrisoft(®) to debride wounds compared with saline and gauze, hydrogel and larvae. Separate analyses were conducted for applications in home and applications in a clinic setting. The analysis took an UK National Health Service (NHS) perspective. It incorporated the costs of the technologies and supplementary technologies (such as dressings) and the costs of their application by a district nurse. The sponsor concluded that Debrisoft(®) was cost saving relative to the comparators. The EAC made amendments to the sponsor analysis to correct for errors and to reflect alternative assumptions. Debrisoft(®) remained cost saving in most analyses and savings ranged from £77 to £222 per patient compared with hydrogel, from £97 to £347 compared with saline and gauze, and from £180 to £484 compared with larvae depending on the assumptions included in the analysis and whether debridement took place in a home or clinic setting. All analyses were severely limited by the available data on effectiveness, in particular a lack of comparative studies and that the effectiveness data for the comparators came from studies reporting different clinical endpoints compared with Debrisoft(®). The Medical Technologies Advisory Committee made a positive recommendation for adoption of Debrisoft(®) and this has been published

  9. Histological Evaluation of the Local Soft Tissue Reaction After Implanting Resorbable and Non-resorbable Monofilament Fibers.

    Science.gov (United States)

    Żywicka, Bogusława; Szymonowicz, Maria; Bryła, Danuta; Rybak, Zbigniew

    2016-01-01

    The development of technologies and scientific disciplines connected with medical implantation devices is dynamically affecting modern treatments by contemporary medicine and veterinary medicine; it also entails a need to monitor their impact on living organisms. The aim of the study was to conduct a comparative histological evaluation of the response of soft tissues after implanting monofilament fibers from resorbable glyconate and from non-resorbable polypropylene (PP) and polyamide (PA) in rats. Non-resorbable polyamide-based fibers were applied to skin anastomoses in rats. Macroscopic and histological evaluations were performed on the 7th, 14th and 30th days. Non-resorbable polypropylene fibers and resorbable glyconate fibers (composed of 72% glycolide, 14% trimethylene carbonate and 4% caprolactone) were implanted in muscle tissue for periods of 7, 14, 30 and 90 days. A semi-quantitative and qualitative histological evaluation found different dynamics and degrees of intensification of cell and tissue response around the resorbable and non-resorbable fibers being tested. The resorption process of the glyconate threads caused a prolonged inflammatory cellular response compared to the non-resorbable threads; it passed, however, without the participation of giant cells. Around the non-resorbable threads the observed cellular response was less intensified, with the formation of single polymorphonuclear macrophages around the PP threads, along with a stronger degree of fibrosis and the presence of fatty infiltrate. During the early period, moderately intensified inflammatory cell response with the presence of single giant cells was observed around the non-degradable PA and PP fibers. In the late period, a band of fibrous connective tissue was present around the PP threads. Glyconate fibers underwent fragmentation and the process of resorption, which was associated with a weakly intensified inflammatory process lasting up to 90 days after implantation.

  10. Development and demonstration of a mobile reverse osmosis adsorption treatment system for environmental emergency clean-ups. Report No. EE-102

    Energy Technology Data Exchange (ETDEWEB)

    1988-01-01

    This study is concerned with the remedation of contaminated water resulting from the release of organic chemicals. Of particular concern is the cleanup of water contaminated by accidental spill of chemicals or petroleum products and the cleanup of water contaminated by oil chemicals disposed of in inadequately sealed or improperly designed landfills. This report presents the results of a project undertaken to develop and demonstrate a mobile reverse osmosis/adsorption system for treating water contaminated by organic chemicals.

  11. Optimization of ultrasonic extraction and clean-up protocol for the determination of polycyclic aromatic hydrocarbons in marine sediments by high-performance liquid chromatography coupled with fluorescence detection

    Science.gov (United States)

    Peng, Xuewei; Yan, Guofang; Li, Xianguo; Guo, Xinyun; Zhou, Xiao; Wang, Yan

    2012-09-01

    The procedures of ultrasonic extraction and clean-up were optimized for the determination of polycyclic aromatic hydrocarbons (PAHs) in marine sediments. Samples were ultrasonically extracted, and the extracts were purified with a miniaturized silica gel chromatographic column and analyzed with high performance liquid chromatography (HPLC) with a fluorescence detector. Ultrasonication with methanol-dichloromethane (2:1, v/v) mixture gave higher extraction efficiency than that with dichloromethane. Among the three elution solvents used in clean-up step, dichloromethane-hexane (2:3, v/v) mixture was the most satisfactory. Under the optimized conditions, the recoveries in the range of 54.82% to 94.70% with RSDs of 3.02% to 23.22% for a spiked blank, and in the range of 61.20% to 127.08% with RSDs of 7.61% to 26.93% for a spiked matrix, were obtained for the 15 PAHs studied, while the recoveries for a NIST standard reference SRM 1941b were in the range of 50.79% to 83.78% with RSDs of 5.24% to 21.38%. The detection limits were between 0.75 ng L-1 and 10.99 ng L-1for different PAHs. A sample from the Jiaozhou Bay area was examined to test the established methods.

  12. Evaluation of alternative sorbents for dispersive solid-phase extraction clean-up in the QuEChERS method for the determination of pesticide residues in rice by liquid chromatography with tandem mass spectrometry.

    Science.gov (United States)

    Cabrera, Liziara da C; Caldas, Sergiane S; Prestes, Osmar D; Primel, Ednei G; Zanella, Renato

    2016-05-01

    Many compounds are used for pest control during the production and storage of rice, making it necessary to employ multiclass methods for pesticide residues determination. For this purpose, QuEChERS-based methods are very efficient, fast and accurate, and improvements in the clean-up step are important, especially for complex matrices, like cereals. In this work, different sorbents such as chitosan, florisil(®) , alumina, diatomaceous earth, graphitized carbon black, besides the commonly used primary secondary amine and octadecylsilane, were evaluated for dispersive solid-phase extraction clean-up in acetate-buffered QuEChERS method for the determination of residues of 20 representative pesticides and one metabolite in rice by liquid chromatography coupled to tandem mass spectrometry. The sorbent C18 presented the best results, however, chitosan showed similar results, and the best performance among the unconventional sorbents evaluated. The method limit of quantification, attending accuracy (70-120% recovery) and precision (RSD ≤20%) criteria, ranged from 5 to 20 μg/kg. Results showed that chitosan is an effective alternative to reduce analysis costs, maintaining the method reliability and accuracy.

  13. Determination of brominated diphenyl ethers (from mono- to hexa- congeners) in indoor dust by pressurised liquid extraction with in-cell clean-up and gas chromatography-mass spectrometry.

    Science.gov (United States)

    Martínez, María Pilar; Carrillo, José David; Tena, María Teresa

    2010-05-01

    This study presents a selective pressurised liquid extraction (PLE) and gas chromatography-mass spectrometry/mass spectrometry method for the determination of brominated diphenyl ethers (BDEs) in indoor dust. Selective PLE consisted of the addition of Florisil mixed with the sample in order to perform an in-cell clean-up. This approach provided a cleaner and almost colourless extract, ready to be injected in the gas chromatograph. The PLE conditions were studied using an experimental design, firstly a 4 x 3 x 2 multifactor categorical design to screen sorbent, solvent and temperature and then a central composite design to optimise sorbent mass, temperature and time. Finally, the number of extraction cycles was studied. The selected conditions were 4 g of Florisil all mixed with the sample and no additional clean-up sorbent layer, 1:1 n-hexane-dichloromethane, 60% flush volume, 40 degrees C, 1,500 psi, 2-min static time and one cycle. The proposed method allowed accurate determination of BDEs, with recovery values between 82% and 101% and detection limits between 0.06 and 0.24 ng g(-1). It also has advantages over other existing methods in terms of simplicity, automation, analysis time and solvent consumption.

  14. Optimization of Ultrasonic Extraction and Clean-up Protocol for the Determination of Polycyclic Aromatic Hydrocarbons in Marine Sediments by High-performance Liquid Chromatography Coupled with Fluorescence Detection

    Institute of Scientific and Technical Information of China (English)

    PENG Xuewei; YAN Guofang; LI Xianguo; GUO Xinyun; ZHOU Xiao; WANG Yan

    2012-01-01

    The procedures of ultrasonic extraction and clean-up were optimized for the determination of polycyclic aromatic hydrocarbons(PAHs)in marine sediments.Samples were ultrasonically extracted,and the extracts were purified with a miniaturized silica gel chromatographic column and analyzed with high performance liquid chromatography(HPLC)with a fluorescence detector.Ultrasonication with methanol-dichloromethane(2:1,v/v)mixture gave higher extraction efficiency than that with dichloromethane.Among the three elution solvents used in clean-up step,dichloromethane-hexane(2:3,v/v)mixture was the most satisfactory.Under the optimized conditions,the recoveries in the range of 54.82% to 94.70% with RSDs of 3.02% to 23.22% for a spiked blank,and in the range of 61.20% to 127.08% with RSDs of 7.61% to 26.93% for a spiked matrix,were obtained for the 15 PAHs studied,while the recoveries for a NIST standard reference SRM 1941b were in the range of 50.79% to 83.78% with RSDs of 5.24% to 21.38%.The detection limits were between 0.75ngL-1 and 10.99ngL-1for different PAHs.A sample from the Jiaozhou Bay area was examined to test the established methods.

  15. QuEChERS-based extraction with dispersive solid phase extraction clean-up using PSA and ZrO2-based sorbents for determination of pesticides in bovine milk samples by HPLC-DAD.

    Science.gov (United States)

    Rejczak, Tomasz; Tuzimski, Tomasz

    2017-02-15

    In this study, a quick, easy, cheap, effective, rugged and safe (QuEChERS) extraction technique was adapted to develop a simple sample treatment for multi-residue pesticide analysis in milk samples. The proposed method is based on liquid-liquid partitioning with acetonitrile followed by dispersive solid phase extraction clean-up using primary secondary amine along with zirconia-coated silica particles for extract purification. Identification and quantification of 30 pesticides was conducted via high performance liquid chromatography with diode-array detection (HPLC-DAD). Recoveries were from 70 to 100% for the vast majority of the analytes, with relative standard deviations less than 20% being observed. HPLC-DAD provided suitable linearity, precision and accuracy. For 28 of 30 analytes in the study method limit of quantification values (mLOQs) comply with the most recent European Union guidelines for the maximum residue levels (MRLs) in milk. Negligible matrix effect was observed due to efficient extract clean-up with ZrO2-based sorbents.

  16. Erika: evaluation of residual sanitary risks linked to the beaches-going after cleaning-up; Erika: evaluation des risques sanitaires residuels lies a la frequentation des plages apres depollution

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    The aim of this study is to evaluate the sanitary risks for the populations frequenting the coast beaches affected by the fuel oils of the tanker Erika, after their cleaning up. This quantitative evaluation of sanitary risks is led according to a protocol developed jointly between the two institutes ( the national institute of industrial environment and risks, I.N.E.R.I.S., and the national institute of sanitary watch I.n.V.S.). It does not give the risks in function the residual pollution level of concerned beaches but supplies to the authorities elements of scientific information in order to allow them to choose criteria appropriate for the management of eventual residual risks. (N.C.)

  17. Simultaneous extraction and clean-up of polybrominated diphenyl ethers and polychlorinated biphenyls from sheep liver tissue by selective pressurized liquid extraction and analysis by gas chromatography-mass spectrometry.

    Science.gov (United States)

    Zhang, Zulin; Ohiozebau, Ehimai; Rhind, Stewart M

    2011-02-25

    We describe a selective pressurized liquid extraction (SPLE) method, followed by gas chromatography-mass spectrometry (GC-MS), for the simultaneous extraction and clean-up of polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) in sheep liver tissue samples. The on-line clean-up of liver tissue by SPLE was tested using differing amount of acid-modified silica (sulphuric acid:silica gel, 1:2, w/w), the most effective amount being 20 g. Different extraction solvents (iso-hexane and dichloromethane), either alone or in various combinations, were used to extract these target compounds from spiked liver samples. Variables affecting the SPLE extraction efficiency, including temperature, pressure, number of extraction cycles and static extraction time were studied; the optimum parameters were 80 °C, 10.3 MPa, 2 cycles and 5 min, respectively. The SPLE based method was compared with more traditional Soxhlet, off-line PLE, ultrasonic and heating extraction methods. Overall the mean percentage recoveries for all target chemicals using SPLE were 86-103% (n=3, SD extraction methods. The limits of detection of the proposed method were 5-96 pg g⁻¹ and 2-29 pg g⁻¹ for the different PBDE and PCB chemicals studied, respectively. The outputs of the proposed method were linear over the range from 0.02 to 30 ng g⁻¹, for all PCB and PBDE congeners except for PBDE 100 and 153 (0.05-30 ng g⁻¹) and PBDE 183 (0.1-30 ng g⁻¹). The method was successfully applied to sheep liver samples for the determination of the target PBDE and PCB compounds.

  18. Shoreline clean-up methods : biological treatments

    Energy Technology Data Exchange (ETDEWEB)

    Massoura, S.T. [Oil Spill Response Limited, Southampton (United Kingdom)

    2009-07-01

    The cleanup of oil spills in shoreline environments is a challenging issue worldwide. Oil spills receive public and media attention, particularly in the event of a coastal impact. It is important to evaluate the efficiency and effectiveness of cleanup methods when defining the level of effort and consequences that are appropriate to remove or treat different types of oil on different shoreline substrates. Of the many studies that have compared different mechanical, chemical and biological treatments for their effectiveness on various types of oil, biological techniques have received the most attention. For that reason, this paper evaluated the effectiveness and effects of shoreline cleanup methods using biological techniques. It summarized data from field experiments and oil spill incidents, including the Exxon Valdez, Sea Empress, Prestige, Grand Eagle, Nakhodka, Guanabara Bay and various Gulf war oil spills. Five major shoreline types were examined, notably rocky intertidal, cobble/pebble/gravel, sand/mud, saltmarsh, and mangrove/sea-grass. The biological techniques that were addressed were nutrient enrichment, hydrocarbon-utilizing bacteria, vegetable oil biosolvents, plants, surf washing, oil-particle interactions and natural attenuation. The study considered the oil type, volume and fate of stranded oil, location of coastal materials, extent of pollution and the impact of biological techniques. The main factors that affect biodegradation of hydrocarbons are the volume, chemical composition and weathering state of the petroleum product as well as the temperature, oxygen availability of nutrients, water salinity, pH level, water content, and microorganisms in the shoreline environment. The interaction of these factors also affect the biodegradation of oil. It was concluded that understanding the fate of stranded oil can help in the development of techniques that improve the weathering and degradation of oil on complex shoreline substrates. 39 refs.

  19. Clean-up at the ISR

    CERN Multimedia

    2001-01-01

    After six months of work, the part of the ISR coming under EP Division has been emptied and refurbished. The area is now ready to start building the LHC experiments. People who know the ISR from way back are likely to be surprised when they push open the doors to the old collider. Whereas the part of the tunnel allocated to EP (Experimental Physics) Division now stands empty, a few months ago, it was piled high with odds and ends. For more than 20 years, this part of the former Intersecting Storage Rings, a full quarter of the loop, had been used as storage space. Both items of value and pure junk had been dumped there, ranging from detector prototypes and 30 years old pumps with signs saying 'not to be thrown out', down to planks, a beautiful velvet armchair, and hundreds of electricity racks. Aloïs Girardoz, lost in the huge ISR hall, which will now be used for building the muon chambers of CMS. An audit carried out in 1996 on the research sector storage areas and accelerators signalled an end t...

  20. National Policies for cleaning up contaminated sites

    NARCIS (Netherlands)

    Veenman, S.A.

    2014-01-01

    Policies for the remediation of contaminated sites emerged relatively late as a subfield of environmental protection. The policy area is adjacent to other policies, such as waste policy, which often includes provisions on how to deal with waste dumps, as well as soil and groundwater protection polic

  1. Cleaning up the future of coal

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    @@ CAS is making efforts to seek green solutions to address the pollution problem of the traditional forms of coal utilization. For instance, as SONG Jianlan reports, a research team from the Taiyuan-based CAS Institute of Coal Chemistry has developed clean, efficient ways to convert coal into liquefied fuels.

  2. Slow clean-up for fast reactor

    Science.gov (United States)

    Banks, Michael

    2008-05-01

    The year 2300 is so distant that one may be forgiven for thinking of it only in terms of science fiction. But this is the year that workers at the Dounreay power station in Northern Scotland - the UK's only centre for research into "fast" nuclear reactors - term as the "end point" by which time the site will be completely clear of radioactive material. More than 180 facilities - including the iconic dome that housed the Dounreay Fast Reactor (DFR) - were built at at the site since it opened in 1959, with almost 50 having been used to handle radioactive material.

  3. Cleaning up the slop: Pt. 2

    Energy Technology Data Exchange (ETDEWEB)

    Goldman, G.K.; Idzqandar, A.B.; Paille, A.

    1999-12-01

    The paper describes how waste minimisation and recovery of saleable oil from slop emulsion sludges have achieved a BS and W of 0.00% for waxy crude. Tests on the new product (called 505-SD Slop Oil Dispersant or simply 505-SD) have shown that apart from being able to keep paraffin wax suspended in crude oil without separating out at ambient or lower temperature (the original purpose for developing the product), a modified form can be used as an additive to lube oil base stocks and reduce the cloud point of the base stocks by up to 15{sup o}C. The paper focuses on the use of 505-SD in waste minimisation. A two-step tank cleaning process is described. Two laboratory case studies demonstrated how oily emulsions were treated to successfully recover the hydrocarbon fraction. A pilot scale field study was also successful. The new technology is likely to lead to many new methods of utilising wax and sludge oil wastes that in the past were regarded as worthless.

  4. Progress and challenges in cleaning up Hanford

    Energy Technology Data Exchange (ETDEWEB)

    Wagoner, J.D. [Dept. of Energy, Richland, WA (United States)

    1997-08-01

    This paper presents captioned viewgraphs which briefly summarize cleanup efforts at the Hanford Site. Underground waste tank and spent nuclear fuel issues are described. Progress is reported for the Plutonium Finishing Plant, PUREX plant, B-Plant/Waste Encapsulation Storage Facility, and Fast Flux Test Facility. A very brief overview of costs and number of sites remediated and/or decommissioned is given.

  5. lnfluence of Trapping and Cleaning up Dead Pine Trees on the Amount of Monoehanusaternatus%诱捕和清理枯死松木对松墨天牛数量的影响

    Institute of Scientific and Technical Information of China (English)

    陈丽莉; 宋美兰; 范海元; 罗洪

    2016-01-01

    利用广东省林业科学研究院研制的A-3型松墨天牛引诱剂进行诱捕松墨天牛试验,结果表明,松墨天牛在江西省峡江县马尾松林区发生期为5月上旬至8月上旬,大量发生期为6月中下旬,在活动期内有一个明显的活动高峰期,并伴随着活动小高峰。而在清理枯死松木的林分,没有明显的活动高峰期,松墨天牛的种群密度少,只占未清理枯死松木松林的21.7%,松墨天牛种群密度减退十分明显。采用引诱剂诱捕的方法可以杀灭大量的松墨天牛,长期彻底清理枯死松木也可使松墨天牛种群数量大量减少,诱捕和清理结合可大大降低松材线虫病传播机率,从而控制松材线虫病蔓延。%A-3 researched and pro-duced by Guangdong Academy of Forestry was used to trap Monoehanusa ternatus. The results showed that M. ter-natus adult stage in Xiajiang County oc-curred from the early May to the early August, and the occurrence peak was the last 20 days of June. The population density of M. ternatus in the forest that cleaning up dead pine trees accounted for 21.7% of the forest that untreated dead pine trees. Therefore, trapping and cleaning up dead pine trees could great-ly reduce the population number of M. ternatus and the spreading of pine wood nematode disease.

  6. Pressurized liquid extraction with in-cell clean-up followed by gas chromatography-tandem mass spectrometry for the selective determination of parabens and triclosan in indoor dust.

    Science.gov (United States)

    Canosa, P; Pérez-Palacios, D; Garrido-López, A; Tena, M T; Rodríguez, I; Rubí, E; Cela, R

    2007-08-17

    A sample preparation method based on the use of pressurized liquid extraction is proposed for the determination of four alkyl parabens and triclosan in indoor dust. Extraction of analytes and removal of interfering species were achieved in the same step, by placing an appropriate sorbent in the extraction cell and by choosing a right combination of washing and elution solvents. Compounds, as silylated derivatives, were determined by gas chromatography in combination with tandem mass spectrometry (GC-MS/MS). Factors affecting the yield and selectivity of the sample preparation procedure were carefully evaluated. Under final conditions, dried samples (0.5 g of dust and 1g of sodium sulphate) were dispersed with 3g of Florisil and loaded into an 11 mL stainless-steel extraction cell containing 1g of the same material as clean-up sorbent. Non-polar species were removed with n-hexane under mild conditions (40 degrees C, 3.4 MPa) and then analytes were extracted with ethyl acetate. The best compromise extraction conditions were 103 degrees C, 13.8 MPa and 3 static extraction cycles of 1 min. The proposed method provided recoveries from 76 to 98%, relative standard deviations under 11% (operating under reproducibility conditions) and quantification limits from 1 to 4 ng/g. The analysis of dust samples from private houses and office buildings confirmed the ubiquitous presence of target bacteriocides in these environments.

  7. Liquid chromatography-high resolution mass spectrometry with immunoaffinity clean-up for the determination of the oxidative stress biomarker 8-iso-prostaglandin F2alpha in wastewater.

    Science.gov (United States)

    Ryu, Yeonsuk; Reid, Malcolm J; Thomas, Kevin V

    2015-08-28

    A reliable oxidative stress biomarker, 8-iso-prostaglandin F2α (8-iso-PGF2α), was for the first time quantitatively analysed in wastewater using an analytical method consisting of liquid chromatography-high resolution mass spectrometry coupled to immunoaffinity clean-up (IAC-LC-HRMS). Factors influencing the method's robustness were investigated, including analyte stability in sewage and enzymatic deconjugation with β-glucuronidase. The IAC-LC-HRMS method was linear over the range of 0.1-100ng/mL with correlation coefficient (R(2)) of 0.999. The quantification limits were sufficiently low to detect 8-iso-PGF2α in sewage (method quantification limit of 0.3ng/L) and precision, expressed as relative standard deviation was less than 7% and the accuracy expressed as relative recovery was in the 103-113% range. As a result, the application of the method to 24-h composite wastewater samples from Oslo showed 8-iso-PGF2α concentrations of 18.9-23.3ng/L for 8 days in March 2015. This study demonstrates a standard method to analyse 8-iso-PGF2α in sewage that will contribute to the further investigation of the potential use of 8-iso-PGF2α as a sewage biomarker for assessing the status of community health. Copyright © 2015 Elsevier B.V. All rights reserved.

  8. Ultra-fast liquid chromatography with tandem mass spectrometry determination of ochratoxin A in traditional Chinese medicines based on vortex-assisted solid-liquid microextraction and aptamer-affinity column clean-up.

    Science.gov (United States)

    Yang, Xihui; Hu, Yichen; Kong, Weijun; Chu, Xianfeng; Yang, Meihua; Zhao, Ming; Ouyang, Zhen

    2014-11-01

    A rapid, selective, and sensitive ultra-fast liquid chromatography with tandem mass spectrometry method was developed for the determination of ochratoxin A in traditional Chinese medicines based on vortex-assisted solid-liquid microextraction and aptamer-affinity column clean-up. Through optimizing the sample pretreatment procedures and chromatographic conditions, good linearity (r(2) ≥ 0.9993), low limit of detection (0.5-0.8 μg/kg), and satisfactory recovery (83.54-94.44%) expressed the good reliability and applicability of the established method in various traditional Chinese medicines. Moreover, the aptamer-affinity column, prepared in-house, showed an excellent feasibility owing to its specific identification of ochratoxin A in various kinds of selected traditional Chinese medicines. The maximum adsorption amount and applicability value were 188.96 ± 10.56 ng and 72.3%, respectively. The matrix effects were effectively eliminated, especially for m/z 404.2→358.0 of ochratoxin A. The application of the developed method for screening the natural contamination levels of ochratoxin A in 25 random traditional Chinese medicines on the market in China indicated that only eight samples were contaminated with low levels below the legal limit (5.0 μg/kg) set by the European Union. This study provided a preferred choice for the rapid and accurate monitoring of ochratoxin A in complex matrices.

  9. Application of ion-exchange cartridge clean-up in food analysis. VI. Determination of six penicillins in bovine tissues by liquid chromatography-electrospray ionization tandem mass spectrometry.

    Science.gov (United States)

    Ito, Yuko; Goto, Tomomi; Oka, Hisao; Matsumoto, Hiroshi; Takeba, Kazue

    2004-07-09

    A multiresidue analytical method was developed for the quantification of benzylpenicillin (PCG), phenoxymethylpenicillin (PCV), oxacillin (MPIPC), cloxacillin (MCIPC), nafcillin (NFPC) and dicloxacillin (MDIPC) in bovine tissues using liquid chromatography- electrospray ionization tandem mass spectrometry (LC-ESI MS/MS) with a multiple reaction monitoring technique. Using the deuterated PCG and NFPC as internal standard was effective for improvement of repeatability and accuracy. We chose [M-H-141]- as a monitor ion of MRM analysis and [M-H]- as a precursor ion for each penicillin. Combination of an ion-exchange cartridge clean-up and ion-pair LC enable us to determine the residual penicillins using the standard curves made from standard solutions without the influence of sample matrix on the MS. The average recoveries of PCG, PCV, MPIPC, MCIPC, NFPC and MDIPC from bovine liver, kidney and muscle at the same concentrations as the tolerance levels of PCG (50 microg/kg) ranged from 77 to 101% with the coefficients of variation ranging from 0.7 to 4.2% (n = 5). The limits of quantification for the six penicillins were 2-10 microg/kg in bovine muscle, liver and kidney (S/N ratio >10).

  10. Application of ion-exchange cartridge clean-up in food analysis III. Determination of benzylpenicillin, phenoxymethyl-penicillin, oxacillin, cloxacillin, nafcillin and dicloxacillin in bovine liver and kidney by liquid chromatography with ultraviolet detection.

    Science.gov (United States)

    Ito, Y; Ikai, Y; Oka, H; Matsumoto, H; Kagami, T; Takeba, K

    2000-06-02

    A multiresidue analytical method was developed for the simultaneous determination of benzylpenicillin (PCG), phenoxymethylpenicillin (PCV), oxacillin (MPIPC), cloxacillin (MCIPC), nafcillin (NFPC) and dicloxacillin (MDIPC) in bovine liver and kidney. The method involves the use of an ion-exchange cartridge for sample clean-up followed by ion-pair high-performance liquid chromatography with ultraviolet detection. The recoveries of PCG, PCV, MPIPC, MCIPC, NFPC and MDIPC from bovine liver spiked at levels of 0.5 mg/kg and 0.1 mg/kg were in the range of 73-91% and 83-96% with coefficients of variation of 1.4-4.2% and 3.4-8.7%, respectively. For bovine kidney spiked at levels of 0.5 mg/kg and 0.1 mg/kg, the recoveries of these compounds were 79-92% and 82-92% with RSDs of 1.8-5.9% and 2.7-7.8%, respectively. The detection limits for the six penicillins were 0.02-0.05 mg/kg in bovine liver and kidney.

  11. Borehole induction logging for the Dynamic Underground Stripping Project LLNL gasoline spill site

    Energy Technology Data Exchange (ETDEWEB)

    Boyd, S.; Newmark, R.; Wilt, M.

    1994-01-21

    Borehole induction logs were acquired for the purpose of characterizing subsurface physical properties and monitoring steam clean up activities at the Lawrence Livermore National Laboratory. This work was part of the Dynamic Underground Stripping Project`s demonstrated clean up of a gasoline spin. The site is composed of unconsolidated days, sands and gravels which contain gasoline both above and below the water table. Induction logs were used to characterize lithology, to provide ``ground truth`` resistivity values for electrical resistance tomography (ERT), and to monitor the movement of an underground steam plume used to heat the soil and drive volatile organic compounds (VOCs) to the extraction wells.

  12. Deriving site-specific clean-up criteria to protect ecological receptors (plants and soil invertebrates) exposed to metal or metalloid soil contaminants via the direct contact exposure pathway

    Science.gov (United States)

    Checkai, Ron; Van Genderen, Eric; Sousa, José Paulo; Stephenson, Gladys; Smolders, Erik

    2014-01-01

    Soil contaminant concentration limits for the protection of terrestrial plants and soil invertebrates are commonly based on thresholds derived using data from laboratory ecotoxicity tests. A comprehensive assessment has been made for the derivation of ecological soil screening levels (Eco-SSL) in the United States; however, these limits are conservative because of their focus on high bioavailability scenarios. Here, we explain and evaluate approaches to soil limit derivation taken by 4 jurisdictions, 2 of which allow for correction of data for factors affecting bioavailability among soils, and between spiked and field-contaminated soils (Registration Evaluation Authorisation and Restriction of Chemicals [REACH] Regulation, European Union [EU], and the National Environment Protection Council [NEPC], Australia). Scientifically advanced features from these methods have been integrated into a newly developed method for deriving soil clean-up values (SCVs) within the context of site-specific baseline ecological risk assessment. Resulting site-specific SCVs that account for bioavailability may permit a greater residual concentration in soil when compared to generic screening limit concentrations (e.g., Eco-SSL), while still affording acceptable protection. Two choices for selecting the level of protection are compared (i.e., allowing higher effect levels per species, or allowing a higher percentile of species that are potentially unprotected). Implementation of this new method is presented for the jurisdiction of the United States, with a focus on metal and metalloid contaminants; however, the new method can be used in any jurisdiction. A case study for molybdate shows the large effect of bioavailability corrections and smaller effects of protection level choices when deriving SCVs. Integr Environ Assess Manag 2014;10:346–357. PMID:24470189

  13. Improved method for the simultaneous determination of aflatoxins, ochratoxin A and Fusarium toxins in cereals and derived products by liquid chromatography-tandem mass spectrometry after multi-toxin immunoaffinity clean up.

    Science.gov (United States)

    Lattanzio, Veronica Maria Teresa; Ciasca, Biancamaria; Powers, Stephen; Visconti, Angelo

    2014-08-01

    An improved method for the quantitative determination of aflatoxins (B1, B2, G1, G2), ochratoxin A, fumonisins (B1, B2), zearalenone, deoxynivalenol, nivalenol, T-2 and HT-2 toxins in cereals and derived products, at levels comparable with EU maximum permitted levels, was developed. The effective co-extraction of the mycotoxins under investigation was achieved in 4min by a double extraction approach, using water followed by methanol. Clean up of the extract was performed by a new multi-toxin immunoaffinity column. Analytical performance characteristics were evaluated through single laboratory validation. Raw wheat and maize, corn flakes and maize snacks were chosen as representative matrices for method validation. The validation assay was carried out at 50, 100 and 150% of EU maximum permitted levels for each mycotoxin. Statistical analysis of the results (ANOVA) provided the within laboratory reproducibility and the error contributions from repeatability, between day effects, and influences from different matrix composition. Recoveries generally higher than 70% were obtained for all tested mycotoxins with relative standard deviation (within laboratory reproducibility) lesser than 37%. Limits of quantification (calculated as the lowest amount of each analyte which could be determined with a precision of 10%) ranged from 1μg/kg to 30μg/kg. The trueness of generated data was assessed by analysis of reference materials. The proposed method was proven to be suitable to assess, with a single analysis, compliance of the selected cereal based foods with the EU maximum permitted or recommended levels for all regulated mycotoxins.

  14. Association between health information, use of protective devices and occurrence of acute health problems in the Prestige oil spill clean-up in Asturias and Cantabria (Spain: a cross-sectional study

    Directory of Open Access Journals (Sweden)

    Rodríguez-Artalejo Fernando

    2006-01-01

    Full Text Available Abstract Background This paper examines the association between use of protective devices, frequency of acute health problems and health-protection information received by participants engaged in the Prestige oil spill clean-up in Asturias and Cantabria, Spain. Methods We studied 133 seamen, 135 bird cleaners, 266 volunteers and 265 paid workers selected by random sampling, stratified by type of worker and number of working days. Information was collected by telephone interview conducted in June 2003. The association of interest was summarized, using odds ratios (OR obtained from logistic regression. Results Health-protection briefing was associated with use of protective devices and clothing. Uninformed subjects registered a significant excess risk of itchy eyes (OR:2.89; 95%CI:1.21–6.90, nausea/vomiting/dizziness (OR:2.25; 95%CI:1.17–4.32 and throat and respiratory problems (OR:2.30; 95%CI:1.15–4.61. There was a noteworthy significant excess risk of headaches (OR:3.86: 95%CI:1.74–8.54 and respiratory problems (OR:2.43; 95%CI:1.02–5.79 among uninformed paid workers. Seamen, the group most exposed to the fuel-oil, were the worst informed and registered the highest frequency of toxicological problems. Conclusion Proper health-protection briefing was associated with greater use of protective devices and lower frequency of health problems. Among seamen, however, the results indicate poorer dissemination of information and the need of specific guidelines for removing fuel-oil at sea.

  15. Rapid estimation of readily leachable triazine residues in soils using automatic kinetic bioaccessibility assays followed by on-line sorptive clean-up as a front-end to liquid chromatography.

    Science.gov (United States)

    Vida, Ana C F; Cocovi-Solberg, David J; Zagatto, Elias A G; Miró, Manuel

    2016-08-15

    An automatic batchwise bioaccessibility test was proposed for on-line monitoring of readily mobile pools of ametryn and atrazine residues in agricultural soils with different physicochemical properties. A 0.01molL(-1) CaCl2 solution mimicking rainwater percolation through the soil profiles was used for the herbicide extractions. The extract aliquots were successively sampled at regular time intervals in order to investigate the extraction kinetics. For extract clean-up and retention of freely dissolved target species, 30mg of restricted-access like copolymer were used as in-line sorptive material followed by elution with methanol and on-line heart-cut injection towards a C18 silica reversed-phase monolithic column (100×4.6mm) in a liquid chromatographic system. A mathematical model emphasized that the readily available pools vs time can be in most instances described by a first-order exponential equation, thus an asymptotical value is approached. Consequently, the leaching assays can be performed without attaining chemical equilibrium. Enhancement factors and detection limits were 10.2 and 18.8, and 0.40 and 0.37mgkg(-1) for ametryn and atrazine, respectively. The automatic method features good repeatability for leaching tests (r.s.d.: 11.8-10.2% for sandy and 3.7-6.2% for clayey soil). Reliable data, demonstrated with relative recoveries in the soil leachates ranging from 86 to 104%, were achieved in less than 35min, thus avoiding the need for up to 24h as recommended by standard leaching methods.

  16. Improvement in the transport critical current density and microstructure of isotopic Mg11B2 monofilament wires by optimizing the sintering temperature

    Science.gov (United States)

    Qiu, Wenbin; Jie, Hyunseock; Patel, Dipak; Lu, Yao; Luzin, Vladimir; Devred, Arnaud; Somer, Mehmet; Shahabuddin, Mohammed; Kim, Jung Ho; Ma, Zongqing; Dou, Shi Xue; Hossain, Md. Shahriar Al

    2016-11-01

    Superconducting wires are widely used in fabricating magnetic coils in fusion reactors. In consideration of the stability of 11B against neutron irradiation and lower induced radio-activation properties, MgB2 superconductor with 11B serving as boron source is an alternative candidate to be used in fusion reactor with severe irradiation environment. In present work, a batch of monofilament isotopic Mg11B2 wires with amorphous 11B powder as precursor were fabricated using powder-in-tube (PIT) process at different sintering temperature, and the evolution of their microstructure and corresponding superconducting properties was systemically investigated. Accordingly, the best transport critical current density (Jc) = 2 × 104 A/cm2 was obtained at 4.2 K and 5 T, which is even comparable to multi-filament Mg11B2 isotope wires reported in other work. Surprisingly, transport Jc vanished in our wire which was heat-treated at excessively high temperature (800 °C). Combined with microstructure observation, it was found that lots of big interconnected microcracks and voids that can isolate the MgB2 grains formed in this whole sample, resulting in significant deterioration in inter-grain connectivity. The results can be a constructive guide in fabricating Mg11B2 wires to be used as magnet coils in fusion reactor systems such as ITER-type tokamak magnet.

  17. The Effect of Sintering Temperature on The Rolled Silver-Sheathed Monofilament Bi,Pb-Sr-Ca-Cu-O Superconducting Wire

    Science.gov (United States)

    Hendrik; Sebleku, P.; Siswayanti, B.; Pramono, A. W.

    2017-05-01

    The manufacture of high critical temperature (Tc) Bi, Pb-Sr-Ca-Cu-O (HTS BPSCCO) superconductor wire fabricated by power-in-tube (PIT) is a multi-step process. The main difficulty is that the value of Tc superconductor wire determined by various factors for each step. The objective of this research is to investigate the effect of sintering parameters on the properties of final rolled material. The fabrication process of 1 m rolled-silver sheath monofilament superconductor BPSCCO wire using mechanical deformation process including rolling and drawing has been carried out. The pure silver powders were melted and formed into pure silver (Ag) tube. The tube was 10 mm in diameter with a sheath material: superconductor powders ratio of about 6 : 1. Starting powders, containing the nominal composition of Bi2-Sr2-Cam-1-Cum-Oy, were inserted into the pure silver tube and rolled until it reached a diameter of 4 mm. A typical area reduction ratio of about 5% per step has been proposed to prevent microcracking during the cold-drawing process. The process of rolling of the silver tube was subsequently repeated to obtain three samples and then followed by heat-treated at 820 °C, 840 °C, and 860 °C, respectively. The surface morphology was analyzed by using SEM; the crystal structure was studied by using X-RD, whereas the superconductivity was investigated by using temperature dependence resistivity measurement by using four-point probe technique. SEM images showed the porosity of the cross-sectional surface of the samples. The sample with low heating temperature showed porosity more than the one with high temperature. The value of critical temperature (Tc) of the sample with a dwelling time of heating of 8 hours is 70 K. At above 70 K, it shows the behavior of conductor properties. However, the porosity increased as the heating time increased up to 24 hours. The critical temperature was difficult to be identified due to its porosity. According to XRD results, the Bi-2212

  18. A pilot project: Antioch Delta Cove, Antioch, California

    Energy Technology Data Exchange (ETDEWEB)

    Minder, M. [Antioch Diversified Development Associates, CA (United States)

    1994-12-31

    The project involves the restoration of the Hickmott cannery site, comprising approximately 15 acres (three five acre parcels) located on the Delta in inter-city Antioch. Hickmott Foods, Inc., operated a fruit and vegetable cannery between 1905 and the early 1970`s, during which time tomato skins, peach and apricot pits, and asparagus butts were discharged on the site. The decaying fruit pits have caused cyanide contamination. Additionally, the site contains some petroleum hydrocarbon contamination as well as gypsum board contamination, apparently from nearby manufacturing operations. The Antioch Delta Cove Pilot shows how interested parties can work together to clean up contaminated sites and use the clean up process to stimulate technology transfer. The Antioch project is a blueprint that can be replicated at other sites across California.

  19. The Environmental Protection Agency's program to close and clean up hazardous waste land disposal facilities. Hearing before the Environment, Energy, and Natural Resources Subcommittee of the Committee on Government Operations, House of Representatives, One Hundred Second Congress, Second Session, May 28, 1992

    Energy Technology Data Exchange (ETDEWEB)

    1993-01-01

    This hearing concerns the slow pace of EPA's actions to close and clean up most of the US hazardous waste land disposal facilities. Statements made personally to the subcommittee include Don R. Clay, Solid Waste and Emergency Response, EPA; Richard L. Hembra, Environmental Issues, Resources, Community, and Economic Development Division of the US General Accounting Office; Harold F. Reheis, Environmental Protection Division, Georgia Department of Natural Resources; Hon. Mike Synar, Chairman of the Subcommittee. Submitted for the record were 4 prepared documents from Don R. Clay, Richard L. Hembra; Sylvia Lowrance, Office of Solid Waste, EPA; Harold F. Reheis.

  20. A review on the clean-up, determination, toxicity and biodetoxification of deoxynivalenol and zearalenone from cereals%谷物中DON、ZEA毒素的净化、检测、毒性与生物脱毒技术的研究

    Institute of Scientific and Technical Information of China (English)

    吴丽; 王步军

    2014-01-01

    Fusarium graminearum colonizes cereals and produces toxic secondary metabolites, such as trichothecenes [deoxynivalenol (DON), nivalenol (NIV)] and zearalenone(ZEA). Mycotoxins contamination of cereal grains and cereal-based products is a major problem in agricultural grains production. Clean-up is necessary step for determining the mycotoxins extracted by solid-liquid extraction. There are kinds of clean-up methods applied to purify Fusarium toxins, including solid phase extraction (SPE) columns, such as specific immunoaffinity clean-up columns and mycosep multifunctional columns, as well as the cheap and effective QuEChERS-base method for cleaning-up complex samples. The determination of foods and feeds contaminated by mycotoxins, toxin-producing conditions, toxicity and biological detoxification of Fusarium graminearum toxins were also reviewed in this paper. It is crucial to develop and explore a safe, efficient and cost effective biological detoxification technology, with the purpose of supplying safety and high quality ce-reals and foods.%禾谷镰刀菌在侵染谷物过程中所产生的次生代谢产物——单端孢霉烯族毒素[脱氧雪腐镰刀菌烯醇(deoxynivalenol, DON)、雪腐镰刀菌烯醇(nivalenol, NIV)]以及玉米赤霉烯酮(zearalenone, ZEA)是世界上粮食安全的一个重大问题。毒素经固液萃取技术提取后,需要通过净化处理才能进行检测与分析。目前有多种净化技术用于毒素的净化,如免疫亲和柱、多功能净化柱等固相萃取柱等,以及广泛使用且简便经济的QuEChERS前处理技术。本文还介绍了禾谷镰刀菌毒素中DON、ZEA的检测方法、产毒条件、毒性以及生物脱毒技术等方面的研究进展,旨在开发与应用更安全、高效、经济的生物脱毒技术进行毒素的防御与去除,以提供安全、优质的粮食与食品。

  1. Uranium Mill Tailings Remedial Action Project fiscal year 1997 annual report to stakeholders

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    The fiscal year (FY) 1997 annual report is the 19th report on the status of the US Department of Energy`s (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project. In 1978, Congress directed the DOE to assess and clean up contamination at 24 designated former uranium processing sites. The DOE is also responsible for cleaning up properties in the vicinity of the sites where wind and water erosion deposited tailings or people removed them from the site for use in construction or landscaping. Cleanup has been undertaken in cooperation with state governments and Indian tribes within whose boundaries the sites are located. It is being conducted in two phases: the surface project and the groundwater project. This report addresses specifics about the UMTRA surface project.

  2. The international validation of bio- and chemical-anlaytical screening methods for dioxins and dioxin-like PCBs: the DIFFERENCE project rounds 1 and 2

    NARCIS (Netherlands)

    Loco, van J.; Leeuwen, van S.P.J.; Roos, P.; Carbonnelle, S.; Boer, de J.; Goeyens, L.; Beernaert, H.

    2004-01-01

    The European research project DIFFERENCE is focussed on the development, optimisation and validation of screening methods for dioxin analysis, including bio-analytical and chemical techniques (CALUX, GC-LRMS/MS, GC x GC-ECD) and on the optimisation and validation of new extraction and clean-up

  3. Water Integration Project Science Strategies White Paper

    Energy Technology Data Exchange (ETDEWEB)

    Alan K. Yonk

    2003-09-01

    This white paper has been prepared to document the approach to develop strategies to address Idaho National Engineering and Environmental Laboratory (INEEL) science and technology needs/uncertainties to support completion of INEEL Idaho Completion Project (Environmental Management [EM]) projects against the 2012 plan. Important Idaho Completion Project remediation and clean-up projects include the 2008 OU 10-08 Record of Decision, completion of EM by 2012, Idaho Nuclear Technology and Engineering Center Tanks, INEEL CERCLA Disposal Facility, and the Radioactive Waste Management Complex. The objective of this effort was to develop prioritized operational needs and uncertainties that would assist Operations in remediation and clean-up efforts at the INEEL and develop a proposed path forward for the development of science strategies to address these prioritized needs. Fifteen needs/uncertainties were selected to develop an initial approach to science strategies. For each of the 15 needs/uncertainties, a detailed definition was developed. This included extracting information from the past interviews with Operations personnel to provide a detailed description of the need/uncertainty. For each of the 15 prioritized research and development needs, a search was performed to identify the state of the associated knowledge. The knowledge search was performed primarily evaluating ongoing research. The ongoing research reviewed included Environmental Systems Research Analysis, Environmental Management Science Program, Laboratory Directed Research and Development, Inland Northwest Research Alliance, United States Geological Survey, and ongoing Operations supported projects. Results of the knowledge search are documented as part of this document.

  4. River Protection Project (RPP) Project Management Plan

    Energy Technology Data Exchange (ETDEWEB)

    NAVARRO, J.E.

    2001-03-07

    The Office of River Protection (ORP) Project Management Plan (PMP) for the River Protection Project (RPP) describes the process for developing and operating a Waste Treatment Complex (WTC) to clean up Hanford Site tank waste. The Plan describes the scope of the project, the institutional setting within which the project must be completed, and the management processes and structure planned for implementation. The Plan is written from the perspective of the ORP as the taxpayers' representative. The Hanford Site, in southeastern Washington State, has one of the largest concentrations of radioactive waste in the world, as a result of producing plutonium for national defense for more than 40 years. Approximately 53 million gallons of waste stored in 177 aging underground tanks represent major environmental, social, and political challenges for the U.S. Department of Energy (DOE). These challenges require numerous interfaces with state and federal environmental officials, Tribal Nations, stakeholders, Congress, and the US Department of Energy-Headquarters (DOE-HQ). The cleanup of the Site's tank waste is a national issue with the potential for environmental and economic impacts to the region and the nation.

  5. Time for the VA to clean up its act

    Directory of Open Access Journals (Sweden)

    Robbins RA

    2015-06-01

    Full Text Available No abstract available. Article truncated after 150 words. One year after a Veterans Affairs (VA scandal was ignited here in Phoenix, the number of veterans on wait lists is 50 percent higher than at the same time last year, according to VA data (1. The VA is also facing a nearly $3 billion budget shortfall. VA Secretary Bob McDonald has asked for “flexibility” to reallocate billions of dollars in clinical funds to cover the shortfall. Since the scandal broke last year, VA providers have increased their workloads, adding 2.7 million more appointments than the previous year. However, the VA has played "games" with patient eligibility for years. When money was plentiful VA administrators would open the doors to patients since the following years' budgets were based on the number of patients seen. However, when money was tight, the doors would be slammed shut leaving many patients in the lurch scrambling to obtain health care elsewhere. Now it appears ...

  6. Modeling Internet-Scale Policies for Cleaning up Malware

    CERN Document Server

    Hofmeyr, Steven; Forrest, Stephanie; Edwards, Benjamin; Stelle, George

    2012-01-01

    An emerging consensus among policy makers is that interventions undertaken by Internet Service Providers are the best way to counter the rising incidence of malware. However, assessing the suitability of countermeasures at this scale is hard. In this paper, we use an agent-based model, called ASIM, to investigate the impact of policy interventions at the Autonomous System level of the Internet. For instance, we find that coordinated intervention by the 0.2%-biggest ASes is more effective than uncoordinated efforts adopted by 30% of all ASes. Furthermore, countermeasures that block malicious transit traffic appear more effective than ones that block outgoing traffic. The model allows us to quantify and compare positive externalities created by different countermeasures. Our results give an initial indication of the types and levels of intervention that are most cost-effective at large scale.

  7. GaAs clean up studied with synchrotron radiation photoemission

    Science.gov (United States)

    Tallarida, Massimo; Adelmann, Christoph; Delabie, Annelies; van Elshocht, Sven; Caymax, Matty; Schmeisser, Dieter

    2012-12-01

    In this contribution we describe the chemical changes at the surface of GaAs upon adsorption of tri-methyl-aluminum (TMA). TMA is used to grow Al2O3 with atomic layer deposition (ALD) usually using H2O as oxygen source. Recently, it was pointed out that the adsorption of TMA on various III-V surfaces reduces the native oxide, allowing the growth of an abrupt III-V/High-K interface with reduced density of defects. Synchrotron radiation photoemission spectroscopy (SR-PES) is a powerful method to characterize surfaces and interfaces of many materials, as it is capable to determine their chemical composition as well as the electronic properties. We performed in-situ SR-PES measurements after exposing a GaAs surface to TMA pulses at about 250°C. Upon using the possibility of tuning the incident photon energy we compared the Ga3d spectra at 41 eV, 71 eV, 91 eV and 121 eV, as well as the As3d at 71 eV and 91 eV. Finally, we show that using SR-PES allows a further understanding of the surface composition, which is usually not accessible with other techniques.

  8. Nano-remediation: tiny particles cleaning up big environmental problems

    DEFF Research Database (Denmark)

    Grieger, Khara; Hjorth, Rune; Rice, Jacelyn;

    2015-01-01

    in clothes and food packaging may be rinsed off during washing, and for many ENMs it remains unclear whether current wastewater treatment systems can filter them out before releasing water back into the environment. Overall, this thematic group will focus on the potential impacts of ENMs in the environment...

  9. 75 FR 62923 - WRC-07 Table Clean-up Order

    Science.gov (United States)

    2010-10-13

    ... Table Frequency Nomenclature 1. In Radio Regulation No. 2.1 of the 2008 Edition of the ITU Radio Regulations, frequencies are expressed in kilohertz (kHz) up to and including ``3 000'' kHz (i.e., 3,000 kHz... limited to emission type 2K80J3E and as specified in Sec. 90.266. Also, although 20 frequencies...

  10. Comparison of extraction and clean-up techniques for the ...

    African Journals Online (AJOL)

    user

    cyclohexane, 2- propanol, methanol, acetonitrile and dichloromethane, were tested to select the most suitable solvent for ... carbon dioxide, hydrocarbon fragments are generated which can ... soxhlet) (Lopez-Avila et al., 1993) supercritical fluid extraction ... that it can produce good results within a short time with minimum ...

  11. Lawmakers Order EPA To Clean Up Work Environment

    Directory of Open Access Journals (Sweden)

    Nicole Ruediger

    2000-01-01

    Full Text Available Washington, Oct 6 — On Wednesday, members of Congress ordered the Environmental Protection Agency (EPA to do a “Superfund” cleanup of its own work environment. For 3 hours, lawmakers and the public listened as witnesses testified to patterns of intolerance, discrimination, and retaliation within the EPA — “This agency is run like a 21st century plantation and this has to stop,” said witness and EPA policy analyst Marsha Coleman-Adebayo.

  12. Bioenergy residues as novel sorbents to clean up pesticide pollution

    Science.gov (United States)

    Mukherjee, Santanu

    2016-04-01

    Worldwide, water contamination from agricultural use of pesticides has received increasing attention within the last decades. In general, sources of pesticide water pollution are categorized into diffuse (stemming from treated fields) and point sources (stemming from farmyards and spillages). Research has demonstrated that 40 to 90% of surface water pesticide contamination is due to point source pollution. To reduce point pollution from farm yards, where the spray equipment is washed, biobed or biofilter systems are used to treat the washing water. The organic material usually used in these systems is often not environmentally sustainable (e.g. peat) and incorporated organic material such as straw leads to a highly heterogeneous water flow, with negative effects on the retention and degradation behavior of the pesticides. Therefore, the objective of this study was to assess the suitability of alternative materials based on bioenergy residues (biochar and digestate) for use in biofilters. To this aim the sorption-desorption potential of three contrasting pesticides (bentazone, boscalid, and pyrimethanil) on mixtures of soil with digestate and/or biochar were investigated in laboratory batch equilibrium experiments. The results indicate that the mixture of digestate and biochar increased pesticide sorption potential, whereby in all cases, the Kd des / Kf des values were lower than the Kd ads / Kf ads values indicating that the retention of the pesticides was weak. Thus, as Kf des were lower than the Kf ads values and H values were below 1, it can be concluded that the biomixtures presented negative desorption (higher hysteresis) in those cases. A higher Kd (>78 L kg-1), Kf (>400 μM1-1/nf L1/nfkg-1) and KL (>40 L kg-1) was obtained for all pesticides for the digestate and biochar based mixtures, which had a higher organic matter content. However, lower sorption of the pesticides was observed in blank soil compared to the other biomixtures, which was attributed to the lower organic carbon content of the blank soil. Our results showed that boscalid and pyrimethanil are highly sorbed to the mixture of digestate and biochar. SUVA254 values justified the aromatic character of digestate (5%) and biochar (5%) mixture which showed highest Koc values among all mixtures for all pesticides. This mixture was found to be the most promising substrate amongst the tested ones for a biobed setup and can be used as an effective and alternative adsorbent for removing pesticides, because of its higher adsorption capacity.

  13. Recent developments in novel sorbents for flue gas clean up

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yan; Bisson, Teresa M.; Yang, Hongqun; Xu, Zhenghe [Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta (Canada)

    2010-10-15

    Coal combustion is one of the most important energy sources for electricity generation, but also produces airborne pollutants. The amount of SO{sub 2} and NO{sub x} for example, is in the order of hundreds to thousands of ppm, and tens to hundreds of ppm, respectively, while Hg in flue gases could be up to tens to hundreds of ppb. Flue gas desulphurization technology is already in place for SO{sub 2} removal, and new sorbents such as zeolites are being investigated for such an application. NO{sub x} can be removed by selective catalytic reduction with various catalysts. Mercury is the hardest to remove due to its persistent nature and relatively low concentration in flue gases. New sorbents have also been developed for mercury removal applications. A current trend in flue gas emission control is to remove Hg, NO{sub x} and SO{sub 2} simultaneously. Various catalytic sorbents have been investigated to remove two or more of these pollutants concurrently. This article reviews recent developments made for emission control of coal-fired power plant flue gases using novel sorbents to target individual or multiple pollutants. (author)

  14. Hot gas clean-up with ceramic filter elements

    Energy Technology Data Exchange (ETDEWEB)

    Christ, A.; Gross, R.; Renz, U. [Rheinisch-Westfaelische Technische Hochschule, Aachen (Germany). Lehrstuhl fuer Waermeuebertragung und Klimatechnik

    1998-12-31

    Hot gas cleanup is necessary during the combined cycle combustion of coal, ceramic filters are frequently used for filtration. Pressure and velocity measurements inside the filter elements during pulse cleaning of a single ceramic candle filter element were carried out. The experimental set-up is described and the results for filter element cleaning at {var_theta} = 25,500 and 900{degree}C and cleaning pressures of P{sub B} = 1.4, 1.9 and 2.8 bar are presented and discussed. Numerical simulations of filter element cleaning for the experimental conditions are presented and discussed as well. Regarding the good agreement of experimental results with numerical predictions it is proven that numerical simulations of the back-pulse cleaning should be employed as design tool for filter cleaning systems. 32 figs., 2 tabs.

  15. Cleaning up That Mess: A Framework for Classifying Educational Apps

    Science.gov (United States)

    Cherner, Todd; Dix , Judy; Lee, Corey

    2014-01-01

    As tablet technologies continue to evolve, the emergence of educational applications (apps) is impacting the work of teacher educators. Beyond online lists of best apps for education and recommendations from colleagues, teacher educators have few resources available to support their teaching of how to select educational apps. In response, this…

  16. Renewable Natural Gas Clean-up Challenges and Applications

    Science.gov (United States)

    2011-01-13

    removed including CO, CO2,CH4) Illustrative Process Flow Diagram for On-site H2 Supply System & SOFC Power Generation...day 1.5 to SOFC ) 13.2 scfm . 8.0 scfm Flow rate: ~ 2.9 scfm ( PSA: ~ 31.7scfm) Usable Heat Electricity 2 CO: ~0.5% H2: ~73.5 Total Flow...34.6 scfm SOFC : 17 t 18 Example Gas Cl eanup Sys em for WWDG > Configured a gas cleanup system utilizing a membrane module for CO

  17. News from Online: Cleaning Up--Soap, Detergent, and More.

    Science.gov (United States)

    Judd, Carolyn Sweeney

    2002-01-01

    Provides a guide to web resources on cleaning and hygiene. Answers the questions, What do you want to clean--your hair? your carpet? your rusty lawn furniture? Develops special products for different tasks. Focuses on products to use and the environmental impact of our choices. (MM)

  18. The 7% Solution - Cleaning Up After Fred Vine's Outstanding Successes

    Science.gov (United States)

    Hey, R. N.

    2013-12-01

    Fred Vine was the first & greatest of the wiggle pickers, founding the marine magnetic anomaly field with his 1963 Vine & Matthews paper. Two of his classic study areas were Juan de Fuca & the Reykjanes Ridge. In Juan de Fuca, he recognized the axial symmetry in the Raff & Mason data that had shown the existence of magnetic stripes on the seafloor, demonstrating the seafloor spreading there that Tuzo Wilson had predicted. Fred's iconic color figure of these anomalies perfectly correlated with the magnetic reversal time scale (after the discovery of the Jaramillo event) became the striking cover illustration of 'The History of the Earth's Crust', the symposium volume of the influential 1966 Goddard meeting that confirmed the reality of seafloor spreading & continental drift. Everything Fred did in Juan de Fuca was correct, but fortunately for me he didn't do everything. Some of the linear magnetic anomaly offsets there became a major puzzle in 1967 when Jason Morgan & Dan McKenzie discovered plate tectonics, because those offsets were oblique to the ridges & transforms & thus were incompatible with simple plate tectonics. Although the oblique anomaly offsets look like faults, they instead turned out to be propagating rift pseudofault wakes with no relative motion along them, an interpretation resulting from my analysis of Galapagos magnetic anomalies. Fred's other iconic color figure was his correlation of the Heirtzler et al. Reykjanes Ridge aeromagnetic data with the reversal timescale. This figure, showing the symmetry predicted by seafloor spreading & field reversals, was another key step in the scientific revolution. At the Goddard Symposium Fred was asked if he'd tested the symmetry statistically & he replied "I never touch statistics. I just deal with the facts'. Fred was trying to have a scientific revolution, & of course on that scale pretty symmetric seafloor spreading is a reality. However, fine-scale asymmetric spreading can be seen in his figure (the asymmetry increases towards Iceland where we had the great advantage of working), & contrary to conventional wisdom the V-shaped ridges, scarps & troughs (VSRs) discovered by Peter Vogt are not symmetric about the Reykjanes Ridge axis. Analysis of magnetic anomaly data from our 2007 expedition by Benediktsdóttir et al. shows these asymmetries were created by rift propagation both away from & towards Iceland, suggesting a tectonic alternative to the magmatic pulsing plume explanation for the VSRs. These results further suggest that the massive transform-eliminating North Atlantic plate boundary reorganization that created the linear obliquely-spreading Reykjanes Ridge might also be a propagating rift phenomenon instead of a thermal phenomenon as generally assumed, & we hope to present results from a new Reykjanes Ridge expedition later this summer designed to determine exactly how this reorganization is occurring. That so much research for several decades has resulted from the small (the 7% number in the title is made up - inspired by Fred I never did learn statistics) modification of Fred's results is a tribute to the overwhelming success of seafloor spreading & plate tectonics. Unfortunately for Vine, Morgan & McKenzie, this scientific revolution appears to have been too profound for Nobel Prizes.

  19. Wet-air oxidation cleans up black wastewater

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    Sterling Organics produces the analgesic paracetamol (acetaminophen) at its Dudley, England, plant. The wastewater from the batch process contains intermediates such as para-aminophenol (PAP) and byproducts such as thiosulfates, sulfites and sulfides. To stay ahead of increasingly strict environmental legislation, Sterling Organics installed a wet-air oxidation system at the Dudley facility in August 1992. The system is made by Zimpro Environmental Inc. (Rothschild, Wis.). Zimpro's wet-air oxidation system finds a way around the limitations of purely chemical or physical processes. In the process, compressed air at elevated temperature and pressure oxidizes the process intermediates and byproducts and removes the color from the wastewater.

  20. Nano-remediation: tiny particles cleaning up big environmental problems

    DEFF Research Database (Denmark)

    Grieger, Khara; Hjorth, Rune; Rice, Jacelyn

    2015-01-01

    Over the past decade, there has been an increased use of engineered nanomaterials (ENMs) in everything from consumer products to industrial manufacturing. Nanomaterials are substances which are less than 100 nanometres in size (a nanometre is one billionth of a metre). Although natural nanomateri......Over the past decade, there has been an increased use of engineered nanomaterials (ENMs) in everything from consumer products to industrial manufacturing. Nanomaterials are substances which are less than 100 nanometres in size (a nanometre is one billionth of a metre). Although natural...... nanomaterials exist, engineered nanomaterials are being designed with very specific properties, and the impacts to humans and ecosystem health are largely unknown. With the normal production, use, and disposal of these products, it is very likely that many ENMs will end up in the environment. ENMs contained...... in clothes and food packaging may be rinsed off during washing, and for many ENMs it remains unclear whether current wastewater treatment systems can filter them out before releasing water back into the environment. Overall, this thematic group will focus on the potential impacts of ENMs in the environment...

  1. Cleaning up That Mess: A Framework for Classifying Educational Apps

    Science.gov (United States)

    Cherner, Todd; Dix , Judy; Lee, Corey

    2014-01-01

    As tablet technologies continue to evolve, the emergence of educational applications (apps) is impacting the work of teacher educators. Beyond online lists of best apps for education and recommendations from colleagues, teacher educators have few resources available to support their teaching of how to select educational apps. In response, this…

  2. Growing Up and Cleaning Up: The Environmental Kuznets Curve Redux.

    Science.gov (United States)

    Franklin, Rachel S; Ruth, Matthias

    2012-01-01

    Borrowing from the Kuznets curve literature, researchers have coined the term "environmental Kuznets curve" or EKC to characterize the relationship between pollution levels and income: pollution levels will increase with income but some threshold of income will eventually be reached, beyond which pollution levels will decrease. The link between the original Kuznets curve, which posited a similar relationship between income and inequality, and its pollution-concerned offspring lies primarily with the shape of both curves (an upside-down U) and the central role played by income change. Although the EKC literature has burgeoned over the past several years, few concrete conclusions have been drawn, the main themes of the literature have remained constant, and no consensus has been reached regarding the existence of an environmental Kuznets curve. EKC research has used a variety of types of data and a range of geographical units to examine the effects of income levels on pollution. Changes in pollution levels might also be at least partly explained by countries' position in the demographic transition and their general population structure, however little research has included this important aspect in the analysis. In addition, few analyses confine themselves to an evaluation for one country of the long-term relationship between income and pollution. Using United States CO2 emissions as well as demographic, employment, trade and energy price data, this paper seeks to highlight the potential impact of population and economic structure in explaining the relationship between income and pollution levels.

  3. Cleaning up and standardizing a folktale corpus for humanities research

    NARCIS (Netherlands)

    Muiser, Iwe Everhardus Christiaan; Theune, Mariët; Meder, Theo; Mambrini, F.; Passarotti, M.; Sporleder, C.

    2012-01-01

    Recordings in the field of folk narrative have been made around the world for many decades. By digitizing and annotating these texts, they are frozen in time and are better suited for searching, sorting and performing research on. This paper describes the first steps of the process of standardizatio

  4. Pipeline clean-up : speed, environment drive pipelining equipment

    Energy Technology Data Exchange (ETDEWEB)

    Budd, G.

    2004-08-01

    Horizontal drilling technology is the single most important enhanced oil recovery technology which has resulted in a significant increase in pipeline utilization. Pipeline operators such as Calgary-based Denim Pipeline Construction Ltd. are responding by using the latest equipment, including excavation equipment, to avoid maintenance delays and downtime. The sales of Denim's horizontal pipe bending equipment have increased due to their attention to worker safety. Denim's horizontal bending machine does not require as much technical support, plus it is faster to install and speeds up production. The machine consists of 3 hydraulic jacks that move on a horizontal plate. Curved dies can be modified to accommodate various diameters of pipe. The bending operation is performed very near to the ground, thereby significantly reducing the risk of pipe injury. Environmental damage is minimized through the use of mechanized mulching which has replaced burning of unwanted trees and brush to clean for pipelines. 1 fig.

  5. Uranium Mill Tailings Remedial Action Project, Surface Project Management Plan. Revision 1

    Energy Technology Data Exchange (ETDEWEB)

    1994-12-01

    Title I of the Uranium Mill Tailings Radiation Control Act (UMTRCA) authorizes the US Department of Energy (DOE) to undertake remedial action at 24 designated inactive uranium processing sites and associated vicinity properties (VP) containing uranium mill tailings and related residual radioactive materials. The purpose of the Uranium Mill Tailings Remedial Action (UMTRA) Surface Project is to minimize or eliminate radiation health hazards to the public and the environment at the 24 sites and related VPs. This document describes the management organization, system, and methods used to manage the design, construction, and other activities required to clean up the designated sites and associated VPs, in accordance with the UMTRCA.

  6. Eğirdir Gölü'nde Gümüşi Havuz Balığı, Carassius gibelio (Bloch, 1782 Avcılığında Kullanılan Monofilament Fanyalı Ağların Seçiciliği

    Directory of Open Access Journals (Sweden)

    Bayram KORKMAZ

    2014-09-01

    Full Text Available In this study, it has been investigated that the characteristics of the selectivity of monofilament trammel nets having 50, 55, 60 mm bar length. This study was carried out on prussian carp Carassius gibelio (Bloch,1782 caught in Lake Eğirdir. An indirect method developed by Holt (1963 was used for determining the selectivity parameters. Common selection factor as SF=4.753 and common standard deviation as SD=2.347 were calculated for monofilament trammel nets. Common selection factor used of the optimum catch lengths of prussian carp in 50, 55 and 60 mm bar length were 23.77; 26.14 and 28.52 cm respectively. The optimum catch lengths were compared with lenghts at first maturity of prussian carp in Lake Eğirdir. Trammel nets of this study do not cause the overfishing on the prussian carp stock

  7. 权利博弈:国民政府省内机关的公产清理冲突与协调%Game of Power:Conflict and Coordination in the Cleaning up of Public Property within Departments of KMT Government at Provincial Level

    Institute of Scientific and Technical Information of China (English)

    冯兵

    2015-01-01

    After founding of KMT government, society and governments at all levels reconstructed the function of leadership and replaced the revolutionary politics to be dominant. The gradual development of economic construction, national education, health care, and social security was in extreme need of money. Financial reform, therefore, became an important channel for local governments to raise funds. Cleaning up public property left over by the predecessors as a part of the full-scale reforms was very much emphasized. The policies of cleaning up of public property were the authoritarian social value distribution plan, but as they were confined to interest reallocation and adjustment and restriction or change of personnel, the implementation of the policies were very complicated processes. Affected by many interest groups, pressure, tension, and conflict were common in implementation. As the cleaning-up work was carried out, the contradictions arising from public property management became increasingly obvious. The administrative offices at provincial level competed and fought against one another, the administrative offices against military offices, province-level offices against city-level offices; province-level against county-level units, all for the property management. They were all involved in a game of power by using equal power, rights and interests.%国民政府建立后,各级政府社会重构领导职能取代革命政治而成主导,经济建设、国民教育、医疗卫生、社会救济等事业渐次开展需款甚亟,财政改革成为各地政府筹措发展资金重要渠道,前代遗留公产的清理作为全方位财政改革组成部分备受重视,作为权威社会价值分配方案的公产清理政策,囿于其出台表现为利益重新分配与调整,对人事进行制约或改变,政策执行成为极度复杂之过程。受多方利益影响,执行过程压力、紧张与冲突成为常态。随着清理工作开展,围

  8. 免疫亲和柱净化-光化学柱后衍生高效液相色谱荧光法测定粮食中黄曲霉毒素%Determination of aflatoxin in cereal by immune-affinity column clean-up and HPLC-FLD with post-column photochemical derivation

    Institute of Scientific and Technical Information of China (English)

    方芳; 张旭; 郑睿行

    2012-01-01

    建立了粮食中黄曲霉毒素B1、B2、G1、G2的免疫亲和柱净化-光化学柱后衍生高效液相色谱荧光检测法.样品经甲醇-水提取,免疫亲和柱净化,高效液相色谱分离,光化学柱后衍生,荧光检测器测定.结果表明,黄曲霉毒素B1、B2、G1、G2的检出限分别为0.50、0.25、0.50、0.25μg/kg,回收率为67.2%~91.7%,RSD小于10%.该方法快速、准确、灵敏度高、重现性好,能满足我国对粮食中黄曲霉毒素限量的检测要求.%A method for determination of aflatoxin B1, B2, G1 and G2 by immune-affinity column clean-up and HPLC with post column photochemical derivation was developed. Samples were extracted with methanol- water solution and cleaned up by immune-affinity columns. Separation of aflatoxins was conducted by HPLC and the determination was carried out by fluorescence detector after photochemical derivatioa The results showed that the limits of detection of aflatoxin B1, B2 , G1 and G2 were 0. 5, 0. 25, 0. 5, 0. 25 μg/kg respectively ,and the recovery rates were from 67. 2% to 91. 7% ,RSD was below 10%. The method is quick, precise,high-sensitive and good-repeatabie,which is suitable for the determination of aflatoxin in cereals in China.

  9. 凝胶渗透色谱净化烟叶有机磷、拟除虫菊酯类农药残留的研究%Study on GPC Clean-up of Residues of organophosphorous Pesticides and Synthetic Pyrethroid Pesticides in Tobacco Leaf

    Institute of Scientific and Technical Information of China (English)

    方敦煌; 师君丽; 宋春满

    2011-01-01

    为确定凝胶渗透色谱(GPC)净化烟草有机磷和拟除虫菊酯农药残留的最佳收集时间,提高烟草有机磷和拟除虫菊酯农药残留的净化效果和回收率,进行了此项试验.采用添加3个浓度梯度农药标准品进行回收试验的方法,研究了烟叶中9种有机磷农药和7种拟除虫菊酯农药在GPC柱上的流出规律.结果表明,有机磷农药的最佳收集时间为26~68 min,拟除虫菊酯类农药的最佳收集时间为26~42 min.有机磷农药的回收率为80.28%~96.81%,相对标准偏差为4.44%~8.74%,拟除虫菊酯类农药回收率为76.39%~97.95%,相对标准偏差为2.69%~7.58%.GPC净化烟草有机磷和拟除虫菊酯农药残留的最佳收集时间与国家标准GB/T 13595不同,主要是因为农药品种不同而造成的,因此最佳收集时间必须根据具体试验来确定.%In order to determine the optimum collecting time of GPC clean-up organophosphorous and pyrethroid residue in tobacco, and improve of purificatory effect and recoveries of those pesticide residues, the test was in progress. According to recovery tests for 16 organophosphorous and pyrethroid pesticide standard spiked samples with 3 concentration gradients, elution behavior of from a gel permeation chromatography column (GPC) was determined for these pesticides in tobacco leaf. The results showed that the optimum collection time of 9 organophosphorous pesticides from GPC column was 26-68 min and that for 7 pyrethroid pesticides was 26-42 min. The recoveries of organophosphorous pesticides were 80.28%-96.81%, the relative standard deviation were 4.44%-8.74%, the recoveries of pyrethroid pesticides were 76.39%-97.95%, the relative standard deviation were 2.69%-7.58%. The optimum collecting time of GPC clean-up pesticide residue is different from GB/T 13595, so the optimum collecting time must be determined by test.

  10. Uranium Mill Tailings Remedial Action Project, fiscal year 1995 annual report to stakeholders

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-30

    In 1978, Congress authorized the DOE to assess and clean up contamination at 24 designated former uranium processing sites. The DOE is also responsible for cleaning up properties in the vicinity of the sites where wind and water erosion deposited tailings or people removed them from the site for use in construction or landscaping projects. Cleanup is being undertaken in cooperation with state governments and Indian tribes within whose boundaries the sites are located. It is being conducted in two phases: the surface project and the ground water project. This report addresses specifics about both phases of the UMTRA Project. DOE`s UMTRA Project is the world`s largest materials management project ever undertaken to reduce or eliminate risk to the general public from exposure to potentially hazardous and radioactive materials. With an estimated cost at completion of nearly $2 billion for both phases of the UMTRA Project, and with the responsibility for encapsulating and isolating almost one-fourth of all the uranium mill tailings generated across the entire US (more than 44 million cubic yards), the UMTRA Project and its people have achieved a long record of safely and effectively completing its mission. It continually enhances its national reputation through its diligent process and cost efficiency as well as its international recognition for its technological innovation.

  11. Clinical Study of the Value of PCT, ABI and 128 Hz Tuning Fork Combined with 10 g Monofilament in Evaluating the Prognosis of Diabetic Foot%PCT、 ABI、128 Hz音叉联合10克单丝对糖尿病足预后评估价值

    Institute of Scientific and Technical Information of China (English)

    刘强; 游东; 梁永

    2016-01-01

    目的:探讨降钙素原(PCT)、踝肱指数(ABI)、 Rydel-seifer分级音叉(128 Hz音叉)联合10 g单丝对糖尿病足预后评估的临床价值。方法选择243例糖尿病患者,其中观察组为糖尿病足患者50例,对照组为非糖尿病足183例,对其临床资料进行回顾性分析糖尿病足的相关因素。根据患者预后分为两组,比较其PCT水平、 ABI、128 Hz音叉联合10 g单丝结果。结果多因素 Logistic 回归分析显示,肥胖、空腹血糖、128 Hz音叉及PCT升高、 ABI、10 g单丝降低是糖尿病足的危险因素。截肢组患者PCT水平及128 Hz音叉结果高于非截肢组, ABI、10 g单丝结果低于非截肢组,两组比较,差异具有统计学意义, P<0.05。结论肥胖、空腹血糖、128 Hz音叉及PCT升高、 ABI、10 g单丝降低在糖尿病的进展过程中起着重要作用,应给予足够重视,积极对症治疗,降低其截肢率。%Objective To investigate the clinical value of procalcitonin (PCT), ankle brachial index (ABI) and Rydel-seifer tuning fork rating (128 Hz tuning fork) combined with 10 g monofilament in evaluating the prognosis of diabetic foot. Methods 243 cases of patients with diabetes were selected, the observation group of 50 patients with diabetic foot, compared with the control group of 183 cases of non diabetic foot. The clinical data were retrospectively analyzed and the related factors of diabetic foot were analyzed by SPSS19. 0 statistics software. The patients were divided into 2 groups according to the prognosis of the patients and the results of the level of PCT, ABI, and 128 Hz fork combined with 10g monofilament. Results Multivariate logistic regression analysis showed that the increase of obesity, fasting blood glucose, 128 Hz tuning fork and PCT and the decrease of ABI and 10 g monofilament were the risk factors for diabetic foot. The scores of the level of PCT level and 128 Hz tuning fork of the patients in amputation group

  12. Strategic Environmental Research and Development Project FY 1994: Assessing national remote sensing technologies for use in US Department of Energy Environmental Restoration Activities, Oak Ridge Solid Waste Storage Area 4 case study

    Energy Technology Data Exchange (ETDEWEB)

    King, A.L.; Smyre, J.L.; Evers, T.K.

    1995-02-01

    During FY 1994, the Oak Ridge Environmental Restoration (ER) Remote Sensing Program teamed with members of the Oak Ridge National Security Program Office (NSPO), the Environmental Research Institute of Michigan (ERIM) under contract to the National Exploitation Laboratory (NEL), the Oak Ridge Waste Area Group 4 (WAG 4) ER Program, and the US Department of Energy (DOE), Offices of Technology Development, Nonproliferation and National Security, and Environmental Restoration, to conduct a test and demonstration of the uses of national remote sensing technologies at DOE hazardous waste sites located in Oak Ridge, Tennessee. Objectives of the Oak Ridge study were to determine if national remote sensing technologies are useful in conducting prescreening, characterization, and/or monitoring activities to expedite the clean-up process at hazardous waste sites and to cut clean-up costs wherever possible. This project was sponsored by the Strategic Environmental Research and Development Project (SERDP).

  13. Investigation on Detection of Aflatoxins in Chinese Materia Medica and Pharmaceutical Intermediates Microbiological Contaminated by Immunoaffinity Column Clean-up Combined with Post-column Derivatization%免疫亲和柱净化HPLC柱后光化学衍生化法检测中药及染菌中药制剂中间体的黄曲霉毒素

    Institute of Scientific and Technical Information of China (English)

    胡一晨; 万丽; 范成杰; 吕维; 杨芳; 吉琅

    2012-01-01

    Objective; To establish a method to determine aflatoxins B,, B2, G1, G2 in Chinese Materia Medica and pharmaceutical intermediates microbiological contaminated by immunoaffinity column clean-up combined with post-column derivatization and HPLC-FD detection. Method: Using immunoaffinity column cleanup combined with post-column derivatization, the analytical method to detect aflatoxins B1 , B2, G,, G2 was established firstly, and then 14 kind of Chinese Materia Medica and pharmaceutical intermediates microbiological contaminated was detected respectively. Result: The method with the great linear concentration range of 0. 15-6.0 ng-mL-1 for aflatoxins G2, B2, and 0.5-20.0 ug·L-1'for G,, B, respectively, was stable and accurate. As a result, aflatoxins B,was detected in Chuanxiong Rhizoma and Platycladi Semen in the 14 kind of Chinese Materia Medica, while there were none of aflatoxins in the pharmaceutical intermediates made by Chuanxiong Rhizoma. Conclusion: The method established in this study was specific and accurate for the detection of aflatoxins in Chinese Materia Medica and pharmaceutical intermediates.%目的:采用免疫亲和柱净化,结合柱后光化学衍生化的高效液相色谱-荧光检测器建立同步检测常用中药材及染菌中药制剂中间体中的黄曲霉毒素B1,B2,G1,G2的方法.方法:采用免疫亲和柱净化洗脱结合柱后光化学衍生手段,建立黄曲霉毒素B1,B2,G1,G2的分析方法,并分别对14种中药材及染菌中药制剂中间体进行检测.结果:黄曲霉毒素B2和G2,B1和G1分别在0.15 ~ 6.0和0.5 ~20.0 ng·mL-1线性关系良好,方法准确稳定.所选的14种中药中川芎和柏子仁检测出黄曲霉毒素B1,而以染菌中药川芎所制备的5种提取物中均未检出黄曲霉毒素.结论:采用此方法检测常用中药材及其制剂中间体中的黄曲霉毒素无干扰性杂峰,结果准确可靠.

  14. 超滤离心净化-高效液相色谱法同时测定配方乳粉中的单糖、双糖和低聚果糖%Simultaneous determination of monosaccharides, disaccharides and fructo-oligosaccharides in milk powder by ultra-filtration clean up coupled with high performance liquid chromatography

    Institute of Scientific and Technical Information of China (English)

    许丽珠; 李秀英; 黄金凤; 陈晓丹; 邓伟恒; 黄伟乾; 冼燕萍; 曾庆祝; 郭新东

    2015-01-01

    ABSTRACT:Objective To establish a simple and rapid method based on ultra-filtration clean up method and high performance liquid chromatography (HPLC) to determine 7 kinds of carbohydrate compounds (fructose, glucose, sucrose, lactose, kestose, nystose and 1F-fructofuranosylnystose) in milk powder.Methods Milk powder sample was dissolved by water, and then treated with ultra-filtration centrifugal molecular weight cut-off 3000 tube to remove protein, nucleic acid and polysaccharide macromolecular substances by high-speed centrifugation. The separation was performed on a Luna NH2 column with isocratic elution of acetonitrile: water (75:25,v:v)as the mobile phase. The analytes were determined by a refractive index detector (RID). Results Under the optimal conditions, the calibration curves were linear in the range of 0.15 to 10.0 mg/mL with correlation coefficients larger than 0.999. The limits of detection (LODs) were from 0.039 to 0.087 g/100 g. The mean recoveries for milk powder sample at three spiked concentration levels of 0.50~2.0 g/100 g were in the range of 81.2% to 105%, and the relative standard deviations (RSD) ranged from 1.1% to 6.2% (n=6). Conclusion This method is simple, rapid, and it is suitable for the identification and quantification of monosaccharides, disaccharides and fructo-oligosaccharides in milk powder.%目的:采用超滤离心截留技术快速除杂,结合高效液相色谱仪,建立一种同时检测配方乳粉中7种糖类化合物(果糖、葡萄糖、蔗糖、乳糖、蔗果三糖、蔗果四糖、蔗果五糖)的分析方法。方法经实验优化,选用截留分子量3000的超滤离心管高速离心去除样品溶液中的蛋白质、核酸和多糖等大分子物质,以乙腈-水为流动相(75:25,v:v)等度洗脱, Luna氨基色谱柱分离,示差折光检测器检测。结果7种目标分析物在0.15~10.0 mg/mL范围内线性关系良好,相关系数大于0.999,方法检出限在0.039~0.087 g/100 g

  15. Determination of Tetrodotoxin in Human Urine and Plasma after Immunoaffinity Column Clean-up Using Ultra-Performanc Hydrophilic Interaction Chromatography Coupled with Triple Quadrupole Mass Spectrometry%免疫亲和柱净化-超高效亲水色谱-三重四极杆质谱联用法测定人尿液和血浆中河豚毒素

    Institute of Scientific and Technical Information of China (English)

    张秀尧; 蔡欣欣; 张晓艺; 李瑞芬

    2014-01-01

    Anultra-performancehydrophilicinteractionliquidchromatography-triplequadrupolemass spectrometric ( UPLC-MS/MS) method was developed for the determination of tetrodotoxin ( TTX) in human urine and plasma. After the sample was cleaned-up and concentrated by immunoaffinity column, the separation of the TTX was carried out on an Acquity UPLC BEH amide column (100 mm×2. 1 mm, 1. 7 μm) with gradient elution using mobile phases of 0. 1% ( V/V) formic acid in water and acetonitrile. The analyte was detected by positive electrospray ionization mass spectrometry in the multiple reaction monitoring ( MRM) mode, and quantified by external solvent standard calibration. The measuring ranges of TTX in urine and plasma were 0. 05-400 μg/L. The average recoveries were 92%-95% and 91%-96% for TTX respectively spiked in urine and plasma with relative standard deviations of 3 . 3%-7 . 2% and 3 . 9%-7 . 8% ( n=5 ) . The limits of detection (LOD, S/N=3) and limits of quantitation (LOQ, S/N=10) of TTX were 0. 02 μg/L and 0. 05μg/L for urine and plasma, respectively. This method is suitable for the detection of TTX in urine and plasma for both forensic and clinical purposes.%建立了测定人尿液和血浆中河豚毒素( TTX)的超高液相色谱-三重四极杆质谱联用分析方法。尿液和血浆样品经免疫亲和柱净化,以0.1%甲酸-乙腈和0.1%甲酸溶液作为流动相进行梯度洗脱,在UPLC BEH Amide柱上实现分离,正离子电喷雾多反应监测( MRM)模式检测,溶剂标准外标法定量。尿液和血浆中TTX的测量范围为0.05~400μg/L,平均加标回收率分别为92%~95%和91%~96%,相对标准偏差在3.3%~7.2%和3.9%~7.8%(n=5)之间,样品中 TTX的检出限(S/N=3)均为0.02μg/L,定量限(S/N=10)为0.05μg/L。本方法适用于尿液和血浆中TTX的中毒检测和临床监测。

  16. US Department of Energy Grand Junction Projects Office Remedial Action Project, final report of the decontamination and decommissioning of Building 36 at the Grand Junction Projects Office Facility

    Energy Technology Data Exchange (ETDEWEB)

    Widdop, M.R.

    1996-08-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJPO Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, also is the remedial action contractor. Building 36 was found to be radiologically contaminated and was demolished in 1996. The soil beneath the building was remediated in accordance with identified standards and can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  17. An Assessment of Stream Health in Urban Creeks with Community Led Improvement Projects

    Science.gov (United States)

    Sanchez, L.; Mercado, M.

    2016-12-01

    Small-scale restoration and improvement projects along urban creeks have become increasingly common and the need to assess their impact on stream health is necessary. Courtland and Peralta Creek have been subject to a variety of community, non-profit and city sponsored improvement projects. Assessment of nutrient contamination in the form of ammonia and nitrate indicate that these urban creeks have been impacted by human activity (Water Quality of Peralta and Courtland Creeks Oakland, CA, A. Ahumada). Continued assessment of the stream health through nitrate, ammonia and phosphate concentrations, benthic invertebrate derived biotic index and E. coli concentrations were used to assess site improvements. Youth and community site improvement project at Courtland Creek has resulted in the decline of nitrate contamination and an overall increase in benthic invertebrates species. Peralta Creek has a group of dedicated community volunteers that participate in clean up events but is just now implementing a planned restoration project increasing native plant diversity at the site.

  18. Project 2010 Project Management

    CERN Document Server

    Happy, Robert

    2010-01-01

    The ideal on-the-job reference guide for project managers who use Microsoft Project 2010. This must-have guide to using Microsoft Project 2010 is written from a real project manager's perspective and is packed with information you can use on the job. The book explores using Project 2010 during phases of project management, reveals best practices, and walks you through project flow from planning through tracking to closure. This valuable book follows the processes defined in the PMBOK Guide, Fourth Edition , and also provides exam prep for Microsoft's MCTS: Project 2010 certification.: Explains

  19. Tampa Electric Company Polk Power Station IGCC project: Project status

    Energy Technology Data Exchange (ETDEWEB)

    McDaniel, J.E.; Carlson, M.R.; Hurd, R.; Pless, D.E.; Grant, M.D. [Tampa Electric Co., FL (United States)

    1997-12-31

    The Tampa Electric Company Polk Power Station is a nominal 250 MW (net) Integrated Gasification Combined Cycle (IGCC) power plant located to the southeast of Tampa, Florida in Polk County, Florida. This project is being partially funded under the Department of Energy`s Clean Coal Technology Program pursuant to a Round II award. The Polk Power Station uses oxygen-blown, entrained-flow IGCC technology licensed from Texaco Development Corporation to demonstrate significant reductions of SO{sub 2} and NO{sub x} emissions when compared to existing and future conventional coal-fired power plants. In addition, this project demonstrates the technical feasibility of commercial scale IGCC and Hot Gas Clean Up (HGCU) technology. The Polk Power Station achieved ``first fire`` of the gasification system on schedule in mid-July, 1996. Since that time, significant advances have occurred in the operation of the entire IGCC train. This paper addresses the operating experiences which occurred in the start-up and shakedown phase of the plant. Also, with the plant being declared in commercial operation as of September 30, 1996, the paper discusses the challenges encountered in the early phases of commercial operation. Finally, the future plans for improving the reliability and efficiency of the Unit in the first quarter of 1997 and beyond, as well as plans for future alternate fuel test burns, are detailed. The presentation features an up-to-the-minute update on actual performance parameters achieved by the Polk Power Station. These parameters include overall Unit capacity, heat rate, and availability. In addition, the current status of the start-up activities for the HGCU portion of the plant is discussed.

  20. Environmental monitoring for the DOE coolside and LIMB demonstration extension projects

    Energy Technology Data Exchange (ETDEWEB)

    White, T.; Contos, L.; Adams, L. (Radian Corp., Research Triangle Park, NC (United States))

    1992-03-01

    The purpose of this document is to present environmental monitoring data collected during the US Department of Energy Limestone Injection Multistage Burner (DOE LIMB) Demonstration Project Extension at the Ohio Edison Edgewater Generating Station in Lorain, Ohio. The DOE project is an extension of the US Environmental Protection Agency's (EPA's) original LIMB Demonstration. The program is operated nuclear DOE's Clean Coal Technology Program of emerging clean coal technologies'' under the categories of in boiler control of oxides of sulfur and nitrogen'' as well as post-combustion clean-up.'' The objective of the LIMB program is to demonstrate the sulfur dioxide (SO{sub 2}) and nitrogen oxide (NO{sub x}) emission reduction capabilities of the LIMB system. The LIMB system is a retrofit technology to be used for existing coal-fired boilers equipped with electrostatic precipitators (ESPs).

  1. Simultaneous determination of 16 organophosphorous pesticides in vegetables,fruits and tea by gas chromatography coupled with clean-up by mesoporous alumina as solid-phase extraction adsorbent%介孔氧化铝净化-气相色谱法同时测定蔬菜、水果及茶叶中16种有机磷农药残留

    Institute of Scientific and Technical Information of China (English)

    胡业琴; 郗存显; 曹淑瑞; 王国民; 李贤良; 张雷; 张云怀

    2014-01-01

    A gas chromatographic method based on solid-phase extraction was developed for the simultaneous determination of 16 organophosphorous pesticides in vegetables,fruits and tea,including cabbage,lettuce,pumpkin,onion,tomato,turnip,apple,pear and tea. The samples were extracted with ethyl acetate,and clean-up with mesoporous alumina as solid-phase extraction adsorbent. The separation of target compounds was performed on a DB-1701 capillary column,and the quantitative analysis of the organophosphorous pesticides was carried out by gas chromatography with flame photometric detection. The results showed that the cali-bration curves of the 16 organophosphorous pesticides were linear in the range of 10-2 000μg/L with good correlation coefficients(R2﹥0. 997). The recoveries of the pesticides in differ-ent samples at three spiked levels ranged from 83. 2% to 103. 8% with the relative standard devi-ations of 2. 0%-9. 9%. This method has high sensitivity,high accuracy and good repeatability, and can be applied to the determination of the organophosphorus pesticide residues in vegeta-bles,fruits and tea.%利用气相色谱检测技术,建立了能应用于白菜、生菜、南瓜、洋葱、番茄、白萝卜、苹果、梨及茶叶等不同基质中16种有机磷农药残留的检测方法。样品采用乙酸乙酯提取,经以合成的介孔氧化铝作吸附剂的固相萃取柱净化, DB-1701毛细管柱分离,气相色谱-火焰光度检测器检测。结果表明,蔬菜、水果及茶叶基质中16种有机磷农药在10~2000μg/L范围内具有良好的线性关系( R2﹥0.997);平均回收率为83.2%~103.8%,相对标准偏差为2.0%~9.9%。该方法灵敏度高、准确度高、重复性好,可适用于蔬菜、水果及茶叶基质中16种有机磷残留量的同时测定。

  2. Project Notes

    Science.gov (United States)

    School Science Review, 1978

    1978-01-01

    Presents sixteen project notes developed by pupils of Chipping Norton School and Bristol Grammar School, in the United Kingdom. These Projects include eight biology A-level projects and eight Chemistry A-level projects. (HM)

  3. Cleaning Up the Joint: Command, Control, and Agency in American War Fighting

    Science.gov (United States)

    2012-01-01

    tapped a vein of American progressive thought that would come to motivate nearly every subsequent evolutionary step taken by the military establishment...included, at the time, Admiral Sir Dudley Pound, Field Marshall Sir John Dill, and Air Chief Marshall Sir Charles Portal . Though not organized into...describes Powell’s meeting with Bush in August 2002, during which he cautioned that the war would “suck the oxygen out of everything.” Woodward, Plan of

  4. Use of magnetic carbon composites from renewable resource materials for oil spill clean up and recovery

    Science.gov (United States)

    Viswanathan, Tito

    2014-02-11

    A method for separating a liquid hydrocarbon material from a body of water. In one embodiment, the method includes the steps of mixing a plurality of magnetic carbon-metal nanocomposites with a liquid hydrocarbon material dispersed in a body of water to allow the plurality of magnetic carbon-metal nanocomposites each to be adhered by an amount of the liquid hydrocarbon material to form a mixture, applying a magnetic force to the mixture to attract the plurality of magnetic carbon-metal nanocomposites each adhered by an amount of the liquid hydrocarbon material, and removing said plurality of magnetic carbon-metal nanocomposites each adhered by an amount of the liquid hydrocarbon material from said body of water while maintaining the applied magnetic force, wherein the plurality of magnetic carbon-metal nanocomposites is formed by subjecting one or more metal lignosulfonates or metal salts to microwave radiation, in presence of lignin/derivatives either in presence of alkali or a microwave absorbing material.

  5. Use of magnetic carbon composites from renewable resource materials for oil spill clean up and recovery

    Energy Technology Data Exchange (ETDEWEB)

    Viswanathan, Tito

    2015-10-27

    A method of separating a liquid hydrocarbon material from a body of water, includes: (a) mixing magnetic carbon-metal nanocomposites with a liquid hydrocarbon material dispersed in a body of water to allow the magnetic carbon-metal nanocomposites each to be adhered by the liquid hydrocarbon material to form a mixture; (b) applying a magnetic force to the mixture to attract the magnetic carbon-metal nanocomposites each adhered by the liquid hydrocarbon material; and (c) removing the body of water from the magnetic carbon-metal nanocomposites each adhered by the liquid hydrocarbon material while maintaining the applied magnetic force. The magnetic carbon-metal nanocomposites is formed by subjecting one or more metal lignosulfonates or metal salts to microwave radiation, in presence of lignin/derivatives either in presence of alkali or a microwave absorbing material, for a period of time effective to allow the carbon-metal nanocomposites to be formed.

  6. Re-injection accelerates groundwater clean up at Fernald, Fluor Fernald, Inc.

    Energy Technology Data Exchange (ETDEWEB)

    Dave Brettschneider; William Hertel; Ken Broberg

    2000-09-29

    A successful one year long, field scale demonstration of the use of groundwater re-infection at Fernald was recently completed bringing DOE one step closer to achieving an accelerated site remediation (DOE 2000). The demonstration marks the end of a several year effort to evaluate whether: re-injection could be conducted efficiently at Fernald, and if the approved aquifer remedy at Fernald would benefit by incorporating re-infection. Evaluation of re-injection technology involved not only technical considerations, but also participation and cooperation of regulators and stakeholders. The demonstration was considered to be unique in that it was integrated into the design of the current approved aquifer remedy and utilized the existing remediation infrastructure. Information collected during the demonstration indicated that re-injection wells could be operated efficiently at Fernald and that the current approved groundwater remedy should be modified to include the use of re-injection.

  7. High intensity magnetic separation for the clean-up of a site polluted by lead metallurgy.

    Science.gov (United States)

    Sierra, C; Martínez, J; Menéndez-Aguado, J M; Afif, E; Gallego, J R

    2013-03-15

    The industrial history in the district of Linares (Spain) has had a severe impact on soil quality. Here we examined soil contaminated by lead and other heavy metals in "La Cruz" site, a brownfield affected by metallurgical residues. Initially, the presence of contaminants mainly associated with the presence of lead slag fragments mixed with the soil was evaluated. The subsequent analysis showed a quasi-uniform distribution of the pollution irrespective of the grain-size fractions. This study was accompanied by a characterization of the lead slag behavior under the presence of a magnetic field. Two main magnetic components were detected: first a ferromagnetic and/or ferrimagnetic contribution, second a paramagnetic and/or antiferromagnetic one. It was also established that the slag was composed mainly of lead spherules and iron oxides embedded in a silicate matrix. Under these conditions, the capacity of magnetic separation to remove pollutants was examined. Therefore, two high intensity magnetic separators (dry and wet devices, respectively) were used. Dry separation proved to be successful at decontaminating soil in the first stages of a soil washing plant. In contrast, wet separation was found effective as a post-process for the finer fractions. Copyright © 2013 Elsevier B.V. All rights reserved.

  8. Effectiveness of phytoremediation technologies to clean up of metalloids using three plant species in Iran.

    Science.gov (United States)

    Nejatzadeh-Barandozi, Fatemeh; Gholami-Borujeni, Fathollah

    2014-01-01

    Phytoremediation is a potential, innovative, and cost-effective technology for non-destructive remediation of heavy-metal contaminated soils. A field trial was conducted to evaluate the phytoremediation efficiencies of three plants and the effects of ethylenediaminetetraacetic acid (EDTA) or ammonium addition [(NH4)2SO4 and NH4NO3] for assisting removal of heavy metals (Pb, Hg, and Cd) from contaminated soil. The tested plants include Amaranthus retroflexus, Sorghum bicolor, and Lolium perrene. Results showed that maximum concentration of Pb, Hg, and Cd were detected in shoots of A. retroflexus, S. bicolor, and L. perrene at high concentrations in pH=6.2. The application of EDTA as a chelating agent to soil was the most efficient to enhance the phytoavailability of Pb, Hg and Cd. The concentrations of Pb, Hg, and Cd in the shoots of A. retroflexus treated with EDTA were 57 mg/kg, 14.1 mg/kg, and 30 mg/kg, respectively. Results indicated that among the three plants, A. retroflexus had great potential in phytoremediation of contaminated soils.

  9. Phytoremediation--a novel and promising approach for environmental clean-up.

    Science.gov (United States)

    Suresh, B; Ravishankar, G A

    2004-01-01

    Phytoremediation is an eco friendly approach for remediation of contaminated soil and water using plants. Phytoremediation is comprised of two components, one by the root colonizing microbes and the other by plants themselves, which degrade the toxic compounds to further non-toxic metabolites. Various compounds, viz. organic compounds, xenobiotics, pesticides and heavy metals, are among the contaminants that can be effectively remediated by plants. Plant cell cultures, hairy roots and algae have been studied for their ability to degrade a number of contaminants. They exhibit various enzymatic activities for degradation of xenobiotics, viz. dehalogenation, denitrification leading to breakdown of complex compounds to simple and non-toxic products. Plants and algae also have the ability to hyper accumulate various heavy metals by the action of phytochelatins and metallothioneins forming complexes with heavy metals and translocate them into vacuoles. Molecular cloning and expression of heavy metal accumulator genes and xenobiotic degrading enzyme coding genes resulted in enhanced remediation rates, which will be helpful in making the process for large-scale application to remediate vast areas of contaminated soils. A few companies worldwide are also working on this aspect of bioremediation, mainly by transgenic plants to replace expensive physical or chemical remediation techniques. Selection and testing multiple hyperaccumulator plants, protein engineering ofphytochelatin and membrane transporter genes and their expression would enhance the rate of phytoremediation, making this process a successful one for bioremediation of environmental contamination. Recent years have seen major investments in the R&D, which have also resulted in competition of filing patents by several companies for economic gains. The details of science & technology related to phytoremediation have been discussed with a focus on future trends and prospects of global relevance.

  10. Biocomplementation of SVE to achieve clean up goals in soils contaminated with toluene and xylene

    DEFF Research Database (Denmark)

    Soares, Antonio; Pinho, Maria Teresa; Albergaria, José Tomás

    2013-01-01

    Soil vapor extraction (SVE) and bioremediation (BR) are two of the most common soil remediation technologies. Their application is widespread; however, both present limitations, namely related to the efficiencies of SVE on organic soils and to the remediation times of some BR processes. This work...

  11. Recent advance in Claus plant tail gas clean-up for air quality improvement

    Energy Technology Data Exchange (ETDEWEB)

    Benayoun, D.; Koskas, A. [Institut Francais du Petrole (IFP) (France)

    1996-12-31

    Overall sulphur recovery yields of 99.8% can be attained using Clauspol II technology, which is a tail gas treatment process. H{sub 2} S and SO{sub 2} in Claus effluents are removed in a simple, low capital operating cost process that uses no hydrogen and low utilities. The continuous withdrawal of product sulphur explains the high efficiency of the process. 2 figs., 1 tab.

  12. From cleaning up to helping out: parental socialization and children's early prosocial behavior.

    Science.gov (United States)

    Pettygrove, Dana M; Hammond, Stuart I; Karahuta, Erin L; Waugh, Whitney E; Brownell, Celia A

    2013-12-01

    Relations between parental socialization and infants' prosocial behavior were investigated in sixty three 18- and 30-month old children. Parents' socialization techniques (e.g., directives, negotiation, reasoning) differed for the two age groups, as did relations between socialization and different forms of emerging prosocial behavior (helping; sharing).

  13. Final Report, University Research Program in Robotics (URPR), Nuclear Facilities Clean-up

    Energy Technology Data Exchange (ETDEWEB)

    Tesar, Delbert; Kapoor, Chetan; Pryor, Mitch

    2005-03-31

    This final report describes the research activity at the University of Texas at Austin with application to EM needs at DOE. This research activity is divided in to two major thrusts and contributes to the overall University Research Program in Robotics (URPR) thrust by providing mechanically oriented robotic solutions based on modularity and generalized software. These thrusts are also the core strengths of the UTA program that has a 40-year history in machine development, 30 years specifically devoted to robotics. Since 1975, much of this effort has been to establish the general analytical and design infrastructure for an open (modular) architecture of systems with many degrees of freedom that are able to satisfy a broad range of applications for future production machines. This work has coalesced from two principal areas: standardized actuators and generalized software.

  14. Spreading, retention and clean-up of oil spills. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Jr, M P

    1976-05-01

    This study reviews and assesses the technology of oil spill spreading, retention and cleanup and proposes research needs in these areas. Sources of oil spills are analyzed and the difficulty of gathering meaningful statistics is discussed. Barrier technology is reviewed and problem areas analyzed. Natural and forced biodegradation and natural and chemical dispersion of oil spills are considered. Research recommendations are categorized under the following two headings (1) Preventive techniques and (2) Containment, Cleanup and Dispersion.

  15. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

  16. Unit 2 I’ll help to clean up the city parks

    Institute of Scientific and Technical Information of China (English)

    2016-01-01

    重点词汇1.cheer v.欢呼;喝彩cheer up(使)变得更高兴;振奋起来I wrote that song just to cheer myself up.我写那首歌是给我自己打气的。拓展cheer n.欢呼声;喝彩声2.volunteer v.义务做;自愿做n.志愿者volunteer to do sth自愿做某事Jack volunteered to carry water.杰克自愿去运水。I need one volunteer.我需要一名志愿者。3.notice n.通知;通告;注意v.注意到;意识到

  17. Legal aspects of the clean-up and reclamation of the manufactured gas plants

    Energy Technology Data Exchange (ETDEWEB)

    Joldzic, V. [Belgrade University, Belgrade (Yugoslavia). Inst. for Criminology and Sociological Research

    1995-12-31

    The laws associated with the cleanup of manufactured gas plants in Yugoslavia is described. These comprise the Environmental Protection Act; the Law about Space Planning and Organizing; Building Law; and Agricultural Land Use Law. Joint remedial action in the Danube Basin is discussed. 13 refs.

  18. Nonlinear beam clean-up using resonantly enhanced sum-frequency mixing

    DEFF Research Database (Denmark)

    Karamehmedovic, Emir; Pedersen, Christian; Jensen, Ole Bjarlin;

    2009-01-01

    We investigate the possibility of improving the beam quality and obtaining high conversion efficiency in nonlinear sum-frequency generation. A 765 nm beam from an external cavity tapered diode laser is single-passed through a nonlinear crystal situated in the high intracavity field of a 1342 nm Nd...

  19. TECHNICAL APPROACHES TO CHARACTERIZING AND CLEANING UP IRON AND STEEL MILL SITES UNDER THE BROWNFIELDS INITIATIVE

    Science.gov (United States)

    This document provides brownfields planners with an overview of the technical methods that can be used to achieve successful site assessment and cleanup which are two key components of the brownfields redevelopment process. No two brownfields sites are identical and planners will...

  20. Modern efficient methods of steel vertical oil tanks clean-up

    Directory of Open Access Journals (Sweden)

    Nekrasov Vladimir

    2016-01-01

    Full Text Available The legislative base of the Russian Federation operating in the field of operation of tanks and tank parks is considered, and consecutive stages of technological process of cleaning of vertical steel tanks from oil ground deposits are presented. In work shortcomings of existing most widespread electromechanical mixers are described when using a hydraulic method of removal and prevention of formation of ground deposits in tanks with oil and oil products. For the purpose of increase of efficiency, reliability and decrease in power consumption of washout of oil ground deposits in tanks the new design of system of funneled washout and prevention of formation of deposits is offered.

  1. Modern efficient methods of steel vertical oil tanks clean-up

    OpenAIRE

    Nekrasov Vladimir

    2016-01-01

    The legislative base of the Russian Federation operating in the field of operation of tanks and tank parks is considered, and consecutive stages of technological process of cleaning of vertical steel tanks from oil ground deposits are presented. In work shortcomings of existing most widespread electromechanical mixers are described when using a hydraulic method of removal and prevention of formation of ground deposits in tanks with oil and oil products. For the purpose of increase of efficien...

  2. Cleaning up the biogeography of Labroides dimidiatus using phylogenetics and morphometrics

    Science.gov (United States)

    Sims, C. A.; Riginos, C.; Blomberg, S. P.; Huelsken, T.; Drew, J.; Grutter, A. S.

    2014-03-01

    Cleaner fishes are some of the most conspicuous organisms on coral reefs due to their behaviour and prominent body pattern, consisting of a lateral stripe and blue/yellow colouration. All obligate cleaner fishes share this body stripe pattern, which is an important signal for attracting client fishes. However, variability in the cleaning signal of the cleaner fish Labroides dimidiatus has been documented across its range. Here, we investigate the geographic distribution of cleaner signal polymorphisms in L. dimidiatus and contrast this to phylogeographic variation in mitochondrial (mt) DNA. We used samples from 12 sites for genetic analyses, encompassing much of L. dimidiatus' range from the Red Sea to Fiji. We obtained morphometric measures of the cleaner signal body stripe width from individuals among six of the sites and qualitatively grouped tail stripe shape. mtDNA control region sequences were used for phylogenetic and population genetic analyses. We found that body stripe width was significantly correlated with tail stripe shape and geographical location, with Indian Ocean populations differing in morphology from western Pacific populations. L. dimidiatus haplotypes formed two reciprocally monophyletic clades, although in contrast to morphology, Japanese cleaner fish fell within the same clade as Indian Ocean cleaner fish and both clade types were sympatric in Papua New Guinea. An additional novel finding of our research was that the inclusion of two closely related cleaner fish species, Labroides pectoralis and Labroides bicolor, in the phylogenetic analysis rendered L. dimidiatus polyphyletic. Overall, the findings suggest the diversity within L. dimidiatus is underestimated.

  3. Microfluidic devices for sample clean-up and screening of biological samples

    NARCIS (Netherlands)

    Tetala, K.K.R.

    2009-01-01

    Analytical chemistry plays an important role in the separation and identification of analytes from raw samples (e.g. plant extracts, blood), but the whole analytical process is tedious, difficult to automate and time consuming. To overcome these drawbacks, the concept of μTAS (miniaturized total ana

  4. Microfluidic devices for sample clean-up and screening of biological samples

    NARCIS (Netherlands)

    Tetala, K.K.R.

    2009-01-01

    Analytical chemistry plays an important role in the separation and identification of analytes from raw samples (e.g. plant extracts, blood), but the whole analytical process is tedious, difficult to automate and time consuming. To overcome these drawbacks, the concept of μTAS (miniaturized total ana

  5. Contaminated land clean-up using composted wastes and impacts of VOCs on land.

    Science.gov (United States)

    Williamson, J C; Akinola, M; Nason, M A; Tandy, S; Healey, J R; Jones, D L

    2009-05-01

    This paper describes experiments that demonstrate the effects and potential for remediation of a former steelworks site in Wales polluted with polycyclic aromatic hydrocarbons (PAHs) and volatile organic compounds (VOCs). Under field conditions, PAH-contaminated soil was composted in-vessel, with or without organic feedstocks, receiving forced aeration for 80 days followed by 4 months maturation. Treatments compared PAH removal in contaminated soil to contaminated soil mixed with three different organic waste mixes after composting and after composts were spread to land. After composting, PAH concentrations declined in all treatments, by up to 38%. Sixteen months after the composts were landspread and vegetation was established, only those containing contaminated soil with organic additions exhibited further PAH removal, by up to 29%. Composting resulted in a decline in the relative concentration of small PAHs, whereas the landspreading-vegetation phase saw a decline in the relative concentration of medium PAHs in two of the three composts exhibiting PAH removal. Under controlled glasshouse conditions, vegetated soil columns of differing depths were exposed to VOCs from beneath. VOC vapour affected both shoot and root growth and soil microbial activity; effects varied with distance from the VOC source. This work demonstrated that on-site remediation of aged PAH-contaminated land can be successfully initiated by in-vessel co-composting followed by land spreading and vegetation, within a practical timeframe.

  6. status of pesticides and degradation products in soil after clean-up ...

    African Journals Online (AJOL)

    dell

    DDE 30200 mg kg-1 dw and 2,4'-DDE 3000 mg kg-1 dw. ... compounds was very slow and that no significant degradation had occurred to the DDT residues in soil .... D. E. F. G. H. I. J. K. CREW Offices. Former storage area. N. Figure 2:.

  7. WhoKnows? Evaluating Linked Data Heuristics with a Quiz that Cleans up DBpedia

    Science.gov (United States)

    Waitelonis, Jorg; Ludwig, Nadine; Knuth, Magnus; Sack, Harald

    2011-01-01

    Purpose: Linking Open Data (LOD) provides a vast amount of well structured semantic information, but many inconsistencies may occur, especially if the data are generated with the help of automated methods. Data cleansing approaches enable detection of inconsistencies and overhauling of affected data sets, but they are difficult to apply…

  8. Enamel Surface Roughness after Debonding of Orthodontic Brackets and Various Clean-Up Techniques

    OpenAIRE

    2013-01-01

    Objective: This study aimed to evaluate enamel roughness after adhesive removal using different burs and an Er:YAG laser. Materials and Methods: The buccal surfaces of forty human premolars were sealed by two layers of nail varnish, except for a circular area of 3 mm in diameter on the middle third. The enamel surfaces were initially subjected to profilometry analysis and four parameters of surface irregularity (Ra, Rq, Rt and Rz) were recorded. Following bracket bonding and debonding, adhesi...

  9. Tallinn passes regulations forcing taxi drivers to clean up their act / Joel Alas

    Index Scriptorium Estoniae

    Alas, Joel

    2006-01-01

    Uue Tallinna taksoveoeeskirja jõustumisel peab takso hinnakiri olema senisest suuremas kirjas kahes keeles. Rangemaks muutub ka kontroll taksomeetrite ja printerite töökorras oleku üle. Kommenteerib Tallinna Transpordiameti juhataja Andres Harjo

  10. Ground truth and detection threshold from WWII naval clean-up in Denmark

    Science.gov (United States)

    Larsen, Tine B.; Dahl-Jensen, Trine; Voss, Peter

    2013-04-01

    The sea bed below the Danish territorial waters is still littered with unexploded mines and other ammunition from World War II. The mines were air dropped by the RAF and the positions of the mines are unknown. As the mines still pose a potential threat to fishery and other marine activities, the Admiral Danish Fleet under the Danish Navy searches for the mines and destroy them by detonation, where they are found. The largest mines destroyed in this manner in 2012 are equivalent to 800 kg TNT each. The Seismological Service at the National Geological Survey of Denmark and Greenland is notified by the navy when ammunition in excess of 100 kg TNT is detonated. The notifications include information about position, detonation time and the estimated amount of explosives. The larger explosions are clearly registered not only on the Danish seismographs, but also on seismographs in the neighbouring countries. This includes the large seismograph arrays in Norway, Sweden, and Finland. Until recently the information from the Danish navy was only utilized to rid the Danish earthquake catalogue of explosions. But the high quality information provided by the navy enables us to use these ground truth events to assess the quality of our earthquake catalogue. The mines are scattered though out the Danish territorial waters, thus we can use the explosions to test the accuracy of the determined epicentres in all parts of the country. E.g. a detonation of 135 kg in Begstrup Vig in the central part of Denmark was located using Danish, Norwegian and Swedish stations with an accuracy of less than 2 km from ground truth. A systematic study of the explosions will sharpen our understanding of the seismicity in Denmark, and result in a more detailed understanding of the detection threshold. Furthermore the study will shed light on the sensitivity of the network to various seismograph outages.

  11. Bench-Scale Testing of Zinc Ferrite Sorbent for Hot Gas Clean-up

    Institute of Scientific and Technical Information of China (English)

    Meisheng Liang; Hongyan Xu; Kechang Xie

    2007-01-01

    Advanced integrated gasification combined cycle (IGCC) power generation systems require the development of high-temperature, regenerable desulfurization sorbents, which are capable of removing hydrogen sulfide from coal gasifier gas to very low levels. In this paper, zinc ferrites prepared by co-precipitation were identified as a novel coal gas desulfurization sorbent at high temperature. Preparation of zinc ferrite and effects of binders on pore volume, strength and desulfurization efficiency of zinc ferrite desulfurizer were studied. Moreover, the behavior of zinc ferrite sorbent during desulfurization and regeneration under the temperature range of 350-400 ℃ are investigated. Effects of binders on the pore volume, mechanical strength and desulfurization efficiency of zinc ferrite sorbents indicated that the addition of kaolinite to zinc ferrite desulfurizer seems to be superior to other binders under the experimental conditions.

  12. Learning and clean-up in a large scale music database

    DEFF Research Database (Denmark)

    Hansen, Lars Kai; Lehn-Schiøler, Tue; Petersen, Kaare Brandt;

    2007-01-01

    We have collected a database of musical features from radio broadcasts (N > 100.000). The database poses a number of hard modeling challenges including: Segmentation problems and missing metadata. We describe our efforts towards cleaning the database using signal processing and machine learning...

  13. Tallinn passes regulations forcing taxi drivers to clean up their act / Joel Alas

    Index Scriptorium Estoniae

    Alas, Joel

    2006-01-01

    Uue Tallinna taksoveoeeskirja jõustumisel peab takso hinnakiri olema senisest suuremas kirjas kahes keeles. Rangemaks muutub ka kontroll taksomeetrite ja printerite töökorras oleku üle. Kommenteerib Tallinna Transpordiameti juhataja Andres Harjo

  14. Relevance of Nuclear Weapons Clean-Up Experience to Dirty Bomb Response

    Energy Technology Data Exchange (ETDEWEB)

    Vantine, H C; Crites, T R

    2002-08-19

    During the past 50 years, the United States has experienced 32 major nuclear weapons accidents, nine of which released special nuclear material to the environment. Response to these accidents, coupled with recovery experience following the Russian satellite reentry and weapons test site cleanup, form the basis for determining actions that might be required following a nuclear terrorist event involving the release of radioactive material. Though valuable information has been gained following the recovery from various commercial accidents, most notably the Chernobyl nuclear power plant failure and the dismantled radiography source in the Brazilian city of Goi nia, this paper will focus on the lessons learned from the U.S. nuclear weapons program.

  15. Groundwater Contamination: DOD Uses and Develops a Range of Remediation Technologies to Clean Up Military Sites

    Science.gov (United States)

    2005-06-01

    DNAPL dense nonaqueous phase liquids DOD Department of Defense EPA Environmental Protection Agency ESTCP Environmental Security Technology Certification...copper, lead, mercury , selenium, silver, and zinc. eIncludes, but is not limited to, oxygen-bearing chemicals that can be added to fuel to bring...technology is applicable to both dense and light nonaqueous phase liquids ( DNAPL and LNAPL).3 Benefits of enhanced recovery approaches include the

  16. Superfund Reauthorization 1994: DoD’s Opportunity to Clean Up Its Hazardous Waste Act

    Science.gov (United States)

    1994-04-01

    House Comm. on Government Operations, 101st Cong., 1st Sess. 3 (1989) (testimony of Richard L. Hembra , Director, Environmental Protection Issues...Public Works and Transportation, 102d Cong., 2d Sess. 701 (1992) (statement of Richard Hembra , Director, Environmental Protection Issues, Resources

  17. NucleoSpin(®) XS Columns for DNA Concentration and Clean-Up.

    Science.gov (United States)

    Hudlow, William R

    2016-01-01

    The phenol-chloroform (organic) extraction method continues to be a preferred method for extraction of DNA from forensic evidence samples that may contain low quantities of DNA and polymerase chain reaction (PCR) inhibitors. The aqueous extracts from the organic extraction of DNA require subsequent concentration and cleanup, which has traditionally been performed with microdialysis filter units, including the Centricon(®) and Microcon(®) centrifugal filter devices. Here, we describe the use of the NucleoSpin(®) XS silica columns as an alternative for the concentration and purification of the aqueous extracts from the organic extraction and for the removal of PCR inhibitors from existing DNA extracts.

  18. Covalent organic polymer functionalization of activated carbon surfaces through acyl chloride for environmental clean-up

    DEFF Research Database (Denmark)

    Mines, Paul D.; Thirion, Damien; Uthuppu, Basil

    2017-01-01

    Nanoporous networks of covalent organic polymers (COPs) are successfully grafted on the surfaces of activated carbons, through a series of surface modification techniques, including acyl chloride formation by thionyl chloride. Hybrid composites of activated carbon functionalized with COPs exhibit...... a core-shell formation of COP material grafted to the outer layers of activated carbon. This general method brings features of both COPs and porous carbons together for target-specific environmental remediation applications, which was corroborated with successful adsorption tests for organic dyes...

  19. Cleaning up the streets : Newcastle-upon-Tyne’s night-time neighbourhood services team.

    OpenAIRE

    Shaw, Robert

    2014-01-01

    The streets of Britain’s city centres are busy at night: taxi drivers, ‘revellers’, fast food sellers, bouncers, policemen, street pastors, leafleteers and more take to the streets to promote, produce or consume the night-time economy. ‘Night-time economy studies’ has catalogued this vast range of activities associated with consumption in city centres at night, particularly within a British context. Roberts and Eldridge’s comprehensive overview of research across social science...

  20. Cockroach Clean-Up Tour . Urban Pest Management. Teaching Environmental Living Skills to Elementary Students.

    Science.gov (United States)

    Cowles, Kathleen Letcher

    Integrated Pest Management (IPM), a decision-making approach to pest control, is designed to help individuals decide if pest suppression treatments are necessary, when they should be initiated, where they should be applied, and what strategy/mix of tatics to use. IPM combines a variety of approaches with which to manage pests, including human…

  1. Battelle Research Outlook, Volume 2 Number 3. Cleaning Up the Atmosphere.

    Science.gov (United States)

    Westerman, Arthur B., Ed.

    "Outlook" publications focus on areas of science and technology in which research can be valuable to industry, government, and society as a whole. This issue deals with the problems of air pullution and air quality control. The first of six essays,". . . This Most Excellent Canopy, the Air," prognosticates the surge in atmospheric pollution and…

  2. THE ROLE OF LIQUID WASTE PRETREATMENT TECHNOLOGIES IN SOLVING THE DOE CLEAN-UP MISSION

    Energy Technology Data Exchange (ETDEWEB)

    Wilmarth, B; Sheryl Bush, S

    2008-10-31

    The objective of this report is to describe the pretreatment solutions that allow treatment to be tailored to specific wastes, processing ahead of the completion schedules for the main treatment facilities, and reduction of technical risks associated with future processing schedules. Wastes stored at Hanford and Savannah River offer challenging scientific and engineering tasks. At both sites, space limitations confound the ability to effectively retrieve and treat the wastes. Additionally, the radiation dose to the worker operating and maintaining the radiochemical plants has a large role in establishing the desired radioactivity removal. However, the regulatory requirements to treat supernatant and saltcake tank wastes differ at the two sites. Hanford must treat and remove radioactivity from the tanks based on the TriParty Agreement and Waste Incidental to Reprocessing (WIR) documentation. These authorizing documents do not specify treatment technologies; rather, they specify endstate conditions. Dissimilarly, Waste Determinations prepared at SRS in accordance with Section 3116 of the 2005 National Defense Authorization Act along with state operating permits establish the methodology and amounts of radioactivity that must be removed and may be disposed of in South Carolina. After removal of entrained solids and site-specific radionuclides, supernatant and saltcake wastes are considered to be low activity waste (LAW) and are immobilized in glass and disposed of at the Hanford Site Integrated Disposal Facility (IDF) or formulated into a grout for disposal at the Savannah River Site Saltstone Disposal Facility. Wastes stored at the Hanford Site or SRS comprise saltcake, supernate, and sludges. The supernatant and saltcake waste fractions contain primarily sodium salts, metals (e.g., Al, Cr), cesium-137 (Cs-137), technetium-99 (Tc-99) and entrained solids containing radionuclides such as strontium-90 (Sr-90) and transuranic elements. The sludges contain many of the transition metal hydroxides that precipitate when the spent acidic process solutions are rendered alkaline with sodium hydroxide. The sludges contain Sr-90 and transuranic elements. The wastes stored at each site have been generated and stored for over fifty years. Although the majority of the wastes were generated to support nuclear weapons production and reprocessing, the wastes differ substantially between the sites. Table 5 shows the volumes and total radioactivity (including decay daughters) of the waste phases stored in tanks at each site. At Hanford, there are 177 tanks that contain 56.5 Mgal of waste. SRS has 51 larger tanks, of which 2 are closed, that contain 36.5 Mgal. Mainly due to recovery operations, the waste stored at Hanford has less total curies than that stored at Savannah River. The total radioactivity of the Hanford wastes contains approximately 190 MCi, and the total radioactivity of the Savannah River wastes contains 400 MCi.

  3. Cleaning up our act: Alternatives for hazardous solvents used in cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Shoemaker, J.D.; Meltzer, M.; Miscovich, D.; Montoya, D.; Goodrich, P.; Blycker, G.

    1994-01-01

    Lawrence Livermore National Laboratory (LLNL) has studied more than 70 alternative cleaners as potential replacements for chlorofluorocarbons (CFCs), halogenated hydrocarbons (e.g., trichloroethylene and trichloroethane), hydrocarbons (e.g., toluene and Stoddard Solvent), and volatile organic compounds (e.g., acetone, alcohols). This report summarizes LLNL`s findings after testing more than 45 proprietary formulations on bench-scale testing equipment and in more than 60 actual shops and laboratories. Cleaning applications included electronics fabrication, machine shops, optical lenses and hardware, and general cleaning. Most of the alternative cleaners are safer than the solvents previously used and many are nonhazardous, according to regulatory criteria.

  4. Water compatible stir-bar devices imprinted with underivatised glyphosate for selective sample clean-up.

    Science.gov (United States)

    Gomez-Caballero, Alberto; Diaz-Diaz, Goretti; Bengoetxea, Olatz; Quintela, Amaia; Unceta, Nora; Goicolea, M Aranzazu; Barrio, Ramón J

    2016-06-17

    This paper reports the development of stir bars with a new MIP based coating, for the selective sorptive extraction of the herbicide glyphosate (GLYP). Molecular imprinting of the polymer has directly been carried out employing underivatised GLYP as the template molecule. Due to the poor solubility of the target compound in organic solvents, the MIP methodology has been optimised for rebinding in aqueous media, being the synthesis and the rebinding steps carried out in water:methanol mixtures and pure aqueous media. The coating has been developed by radical polymerisation initiated by UV energy, using N-allylthiourea and 2-dimethyl aminoethyl methacrylate as functional monomers and ethylene glycol dimethacrylate as the cross-linker. Mechanical stability of the coating has been improved using 1,3-divinyltetramethyldisiloxane in the polymerisation mixture. Under the optimised conditions, the MIP has demonstrated excellent selectivity for the target compound in the presence of structural analogues, including its major metabolites. The applicability of the proposed method to real matrices has also been assessed using river water and soil samples. Registered mean recoveries ranged from 90.6 to 97.3% and RSD values were below 5% in all cases, what confirmed the suitability of the described methodology for the selective extraction and quantification of GLYP.

  5. Reaching Part Per Trillion Clean-Up Criteria for Mercury in Water

    Energy Technology Data Exchange (ETDEWEB)

    Klasson, K. T.; Kosny, K.; Drescher, S. R.; Southworth, G. R.; Hensley, J. F.

    2003-02-24

    In the last couple of years, emphasis on environmental mercury contamination and elimination of mercury use has increased. The U.S. Department of Energy has for many decades maintained a stockpile of elemental mercury for operations and, as a consequence of its routine use, spills have occurred. These historical spills have resulted in some contamination of water streams and soils. In this work we examine a newly developed technique for removal of mercury from contaminated groundwater. In this application the mercury concentration was approximately 2.3 parts per billion and the treatment criterion was 200 parts per trillion. Several forms of mercury species contributed to the contamination. The treatment technique developed for this water was to convert all forms of mercury, through a series of fast chemical reactions, to elemental mercury, which was air-stripped from the water. This paper presents preliminary laboratory work on the method.

  6. Environmental monitoring for the DOE coolside and LIMB demonstration extension projects. Final report, May--August 1991

    Energy Technology Data Exchange (ETDEWEB)

    White, T.; Contos, L.; Adams, L. [Radian Corp., Research Triangle Park, NC (United States)

    1992-03-01

    The purpose of this document is to present environmental monitoring data collected during the US Department of Energy Limestone Injection Multistage Burner (DOE LIMB) Demonstration Project Extension at the Ohio Edison Edgewater Generating Station in Lorain, Ohio. The DOE project is an extension of the US Environmental Protection Agency`s (EPA`s) original LIMB Demonstration. The program is operated nuclear DOE`s Clean Coal Technology Program of ``emerging clean coal technologies`` under the categories of ``in boiler control of oxides of sulfur and nitrogen`` as well as ``post-combustion clean-up.`` The objective of the LIMB program is to demonstrate the sulfur dioxide (SO{sub 2}) and nitrogen oxide (NO{sub x}) emission reduction capabilities of the LIMB system. The LIMB system is a retrofit technology to be used for existing coal-fired boilers equipped with electrostatic precipitators (ESPs).

  7. River Protection Project Integrated safety management system phase II verification review plan - 7/29/99

    Energy Technology Data Exchange (ETDEWEB)

    SHOOP, D.S.

    1999-09-10

    The purpose of this review is to verify the implementation status of the Integrated Safety Management System (ISMS) for the River Protection Project (RPP) facilities managed by Fluor Daniel Hanford, Inc. (FDH) and operated by Lockheed Martin Hanford Company (LMHC). This review will also ascertain whether within RPP facilities and operations the work planning and execution processes are in place and functioning to effectively protect the health and safety of the workers, public, environment, and federal property over the RPP life cycle. The RPP ISMS should support the Hanford Strategic Plan (DOERL-96-92) to safely clean up and manage the site's legacy waste and deploy science and technology while incorporating the ISMS central theme to ''Do work safely'' and protect human health and the environment.

  8. US Department of Energy Grand Junction Projects Office Remedial Action Project. Final report of the decontamination and decommissioning of Building 52 at the Grand Junction Projects Office Facility

    Energy Technology Data Exchange (ETDEWEB)

    Krabacher, J.E.

    1996-08-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJPO Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, also was the remedial action contractor. Building 52 was found to be radiologically contaminated and was demolished in 1994. The soil area within the footprint of the building has been remediated in accordance with the identified standards and the area can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  9. Intending Projects

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Project name: 90,000t/a BR device and auxiliary projects Construction unit: Sinopec Beijing Yanshan Petrochemical Company Total investment: 2.257 billion yuan Project description: It will cover an area of 14. lha.

  10. Flow resistance of textile materials, Part I: Monofilament fabrics

    NARCIS (Netherlands)

    Gooijer, H.; Warmoeskerken, M.M.C.G.; Groot Wassink, J.

    2003-01-01

    This paper describes the relation between the flow resistance of a textile material and its geometry. A literature survey reveals that the orifice model is most suited to modeling the flow resistance of woven fabrics, but applications of this model were, until now, restricted to relatively open fabr

  11. Thermal cycling stresses in W-monofilament reinforced copper

    Energy Technology Data Exchange (ETDEWEB)

    Schoebel, Michael; Jonke, Johannes; Degischer, H. Peter [Institute of Materials Science and Technology, Vienna University of Technology (Austria); Herrmann, Aurelia; Brendel, Annegret [Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Wimpory, Robert [Helmholtz Zentrum Berlin, Wannsee (Germany); Buslaps, Thomas [European Synchrotron Radiation Facility, Grenoble (France)

    2011-08-15

    New materials have to be developed for fusion reactor systems to withstand the high thermal load and heavy irradiation under service conditions. The divertor element collects the residuals of the nuclear reaction and withdraws heat from the reaction chamber into a heat sink. A thermal flux of {approx}20 W mK{sup -1} can be expected in such components. A plasma facing W plate is attached to a CuCrZr heat sink suffering CTE mismatch stresses at the interface due to pulsed operation required for the Tokamak reactor design. Fiber reinforced metal matrix composites are applied as an interlayer to reduce macroscopic interfacial stresses in these components. W-wire reinforced copper is a promising material for this application due to a good fiber-matrix bonding strength which is further increased by surface etching or graded interface designs. Thermal stresses in between the matrix and the wires are responsible for thermal fatigue damage within the constituents and at their interface. Neutron and synchrotron diffraction was performed in situ during thermal cycling to determine the micro stress amplitudes and their changes under simulated service conditions. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  12. Contingency Airfield Construction: Mechanical Stabilization Using Monofilament and Fibrillated Fibers

    Science.gov (United States)

    1994-01-01

    geosynthetics in pavement design. Articles that provided "state-of-the-art" or otherwise noteworthy information were acqured by the WES library. The...Waterways Experiment Station, Vicksburg, MS. Dass, W. G. (1992). " Geosynthetics and fiber-reinforced materials for airfield pavements: a literature

  13. Pollution prevention in environmental restoration projects: communication, innovation, and implementation

    Energy Technology Data Exchange (ETDEWEB)

    Wilczek, T.A.

    1996-11-01

    With the change in US Department of Energy`s (DOE) primary mission from weapons production to complex clean-up, there is an increased emphasis to utilize proven tools and techniques that, when modified, will assist in this massive remediation effort. Tools and techniques which increase process efficiency while minimizing costs are highly attractive. The introduction of formalized Pollution Prevention (P2) practices into the DOE Environmental Restoration (ER) program should be encouraged to the measurable degree of success that P2 has obtained in DOE process operations. Most notably, the integration of Pollution Prevention Opportunity Assessments (PPOAs) into the ER process is highly recommended for three reasons: waste stream generation volumes will be minimized; the results of P2 implementation will be properly measured, quantified, and documented for use on other projects; and negative impacts to human health and the environment will be lessened. the application of P2 principles is encouraged as a Best Management Practice (BMP), in addition to minimizing waste generation to achieve DOE waste reduction goals. The challenge is how to apply P2 practices to ER projects and obtain quantifiable waster reductions.

  14. Project Management

    DEFF Research Database (Denmark)

    Project Management Theory Meets Practice contains the proceedings from the 1st Danish Project Management Research Conference (DAPMARC 2015), held in Copenhagen, Denmark, on May 21st, 2015.......Project Management Theory Meets Practice contains the proceedings from the 1st Danish Project Management Research Conference (DAPMARC 2015), held in Copenhagen, Denmark, on May 21st, 2015....

  15. Define Project

    DEFF Research Database (Denmark)

    Munk-Madsen, Andreas

    2005-01-01

    "Project" is a key concept in IS management. The word is frequently used in textbooks and standards. Yet we seldom find a precise definition of the concept. This paper discusses how to define the concept of a project. The proposed definition covers both heavily formalized projects and informally...... organized, agile projects. Based on the proposed definition popular existing definitions are discussed....

  16. Project Management

    DEFF Research Database (Denmark)

    Pilkington, Alan; Chai, Kah-Hin; Le, Yang

    2015-01-01

    This paper identifies the true coverage of PM theory through a bibliometric analysis of the International Journal of Project Management from 1996-2012. We identify six persistent research themes: project time management, project risk management, programme management, large-scale project management......, project success/failure and practitioner development. These differ from those presented in review and editorial articles in the literature. In addition, topics missing from the PM BOK: knowledge management project-based organization and project portfolio management have become more popular topics...

  17. Project Management

    DEFF Research Database (Denmark)

    Pilkington, Alan; Chai, Kah-Hin; Le, Yang

    2015-01-01

    This paper identifies the true coverage of PM theory through a bibliometric analysis of the International Journal of Project Management from 1996-2012. We identify six persistent research themes: project time management, project risk management, programme management, large-scale project management......, project success/failure and practitioner development. These differ from those presented in review and editorial articles in the literature. In addition, topics missing from the PM BOK: knowledge management project-based organization and project portfolio management have become more popular topics...

  18. Microbiological, Geochemical and Hydrologic Processes Controlling Uranium Mobility: An Integrated Field-Scale Subsurface Research Challenge Site at Rifle, Colorado, Quality Assurance Project Plan

    Energy Technology Data Exchange (ETDEWEB)

    Fix, N. J.

    2008-01-07

    The U.S. Department of Energy (DOE) is cleaning up and/or monitoring large, dilute plumes contaminated by metals, such as uranium and chromium, whose mobility and solubility change with redox status. Field-scale experiments with acetate as the electron donor have stimulated metal-reducing bacteria to effectively remove uranium [U(VI)] from groundwater at the Uranium Mill Tailings Site in Rifle, Colorado. The Pacific Northwest National Laboratory and a multidisciplinary team of national laboratory and academic collaborators has embarked on a research proposed for the Rifle site, the object of which is to gain a comprehensive and mechanistic understanding of the microbial factors and associated geochemistry controlling uranium mobility so that DOE can confidently remediate uranium plumes as well as support stewardship of uranium-contaminated sites. This Quality Assurance Project Plan provides the quality assurance requirements and processes that will be followed by the Rifle Integrated Field-Scale Subsurface Research Challenge Project.

  19. Mitigation and Monitoring Plan for impacted wetlands at the Gunnison UMTRA Project site, Gunnison, Colorado. Revision 1

    Energy Technology Data Exchange (ETDEWEB)

    1994-12-01

    The Gunnison, Colorado, abandoned uranium mill site is one site being cleaned up by the DOE under UMTRCA authority. This site`s contaminated material is being transported to a disposal site on US Bureau of Land Management (BLM) land east of Gunnison. Remedial action activities have temporarily disturbed 0.8 acre (ac) (0.3 hectares [ha]) of wetlands and permanently eliminated 4.3 ac (1.7 ha). As required by the Clean Water Act, the US Army Corps of Engineers (USACE) prepared a Section 404 Permit that addresses the loss of wetlands as a result of remedial action at the Gunnison UMTRA Project site. The 404 permit includes this report as an attachment and it describes the wetland mitigation and monitoring plan. The DOE formulated this plan in consultation with the BLM and the USACE. This report represents a revised version of the mitigation and monitoring plan (DOE, 1992b).

  20. Alzheimer's Project

    Science.gov (United States)

    ... state Home > News & Events > Upcoming Events > HBO Alzheimer’s Project In the News Walk to End Alzheimer's Upcoming ... Disease Awareness Month World Alzheimer's Month HBO Alzheimer’s Project MAKE A DONATION Your gift will help us ...

  1. Alzheimer's Project

    Medline Plus

    Full Text Available ... Momentum in Science, Part 2" (70 minutes) Be a part of something big. HBO's "THE ALZHEIMER'S PROJECT" ... vital research and services. "THE ALZHEIMER'S PROJECT" is a presentation of HBO Documentary Films and the National ...

  2. PROJECT REPORT

    African Journals Online (AJOL)

    Office 2004 Test Drive User

    report. Details on the background of the project, the fieldwork, the work completed, the projected end ... Studies, University of Ghana, with a starting date of 01/01/12 and an expected completion of ..... de Bondoukou. Paris: Editions Ernest Leroux.

  3. Alzheimer's Project

    Medline Plus

    Full Text Available ... Momentum in Science, Part 2" (70 minutes) Be a part of something big. HBO's "THE ALZHEIMER'S PROJECT" ... vital research and services. "THE ALZHEIMER'S PROJECT" is a presentation of HBO Documentary Films and the National ...

  4. Project Temporalities

    DEFF Research Database (Denmark)

    Tryggestad, Kjell; Justesen, Lise; Mouritsen, Jan

    2013-01-01

    into account. This may require investments in new project management technologies. Originality/value – This paper adds to the literatures on project temporalities and stakeholder theory by connecting them to the question of non-human stakeholders and to project management technologies.......Purpose – The purpose of this paper is to explore how animals can become stakeholders in interaction with project management technologies and what happens with project temporalities when new and surprising stakeholders become part of a project and a recognized matter of concern to be taken...... into account. Design/methodology/approach – The paper is based on a qualitative case study of a project in the building industry. The authors use actor-network theory (ANT) to analyze the emergence of animal stakeholders, stakes and temporalities. Findings – The study shows how project temporalities can...

  5. Project ethics

    CERN Document Server

    Jonasson, Haukur Ingi

    2013-01-01

    How relevant is ethics to project management? The book - which aims to demystify the field of ethics for project managers and managers in general - takes both a critical and a practical look at project management in terms of success criteria, and ethical opportunities and risks. The goal is to help the reader to use ethical theory to further identify opportunities and risks within their projects and thereby to advance more directly along the path of mature and sustainable managerial practice.

  6. Microsoft project

    OpenAIRE

    Markić, Lucija; Mandušić, Dubravka; Grbavac, Vitomir

    2005-01-01

    Microsoft Project je alat čije su prednosti u svakodnevnom radu nezamjenjive. Pomoću Microsoft Projecta omogućeno je upravljanje resursima, stvaranje izvještaja o projektima u vremenu, te analize različitih scenarija. Pojavljuje u tri verzije: Microsoft Project Professional, Microsoft Project Server i Microsoft Project Server Client Access Licenses. Upravo je trend da suvremeni poslovni ljudi zadatke povjeravaju Microsoft Projectu jer on znatno povećava produktivnost rada. Te prednos...

  7. Virtual projects

    DEFF Research Database (Denmark)

    Svejvig, Per; Commisso, Trine Hald

    2012-01-01

    that the best practice knowledge has not permeated sufficiently to the practice. Furthermore, the appropriate application of information and communication technology (ICT) remains a big challenge, and finally project managers are not sufficiently trained in organizing and conducting virtual projects......Virtual projects are common with global competition, market development, and not least the financial crisis forcing organizations to reduce their costs drastically. Organizations therefore have to place high importance on ways to carry out virtual projects and consider appropriate practices...

  8. Map Projection

    CERN Document Server

    Ghaderpour, Ebrahim

    2014-01-01

    In this paper, we introduce some known map projections from a model of the Earth to a flat sheet of paper or map and derive the plotting equations for these projections. The first fundamental form and the Gaussian fundamental quantities are defined and applied to obtain the plotting equations and distortions in length, shape and size for some of these map projections.

  9. International Projects

    CERN Document Server

    2002-01-01

    Description of co-operation projects implemented with the help of Sweden is presented. Information on performance of Phare and IAEA Regional and National Technical Cooperation projects is provided. Phare project 'Creation of Radiation Protection Infrastructure and Development of Supporting Services' was started in 2002

  10. Project STAY.

    Science.gov (United States)

    Smith, Bert Kruger

    Project STAY (Scholarships to Able Youth), located in the barrio of San Antonio, Texas, helps young people stay in school beyond the secondary grades. The project provides outreach services to meet the needs of the students. Its primary service is to act as an advocate for these young people. The project recruits all types of youth from families…

  11. Environmental monitoring for the DOE coolside and LIMB demonstration extension projects

    Energy Technology Data Exchange (ETDEWEB)

    White, T.; Contos, L.

    1991-09-01

    The purpose of this document is to present environmental monitoring data collected during the US Department of Energy Limestone Injection Multistage Burner (DOE LIMB) Demonstration Project Extension at the Ohio Edison Edgewater Generating Station in Lorain, Ohio. These data were collected by implementing the Environmental Monitoring Plan (EMP) for the DOE LIMB Demonstration Project Extension, dated August 1988. This document is the fifth EMP status report to be published and presents the data generated during November and December 1990, and January 1991. These reports review a three or four month period and have been published since the project's start in October 1989. The DOE project is an extension of the US Environmental Protection Agency's (EPA) original LIMB Demonstration. The program is operated under DOE's Clean Coal Technology Program of emerging clean coal technologies'' under the categories of in boiler control of oxides of sulfur and nitrogen'' as well as post-combustion clean-up.'' The objective of the LIMB program is to demonstrate the sulfur dioxide (SO{sub 2}) and nitrogen oxide (NO{sub x}) emission reduction capabilities of the LIMB system. The LIMB system is a retrofit technology to be used for existing coal-fired boilers equipped with electrostatic precipitators (ESPs). 5 figs., 12 tabs.

  12. Virtual projects

    DEFF Research Database (Denmark)

    Svejvig, Per; Commisso, Trine Hald

    2012-01-01

    Virtual projects are common with global competition, market development, and not least the financial crisis forcing organizations to reduce their costs drastically. Organizations therefore have to place high importance on ways to carry out virtual projects and consider appropriate practices...... for performing these projects. This paper compares best practices with practiced practices for virtual projects and discusses ways to bridge the gap between them. We have studied eleven virtual projects in five Danish organizations and compared them with a predefined list of best practices compiled from...... that the best practice knowledge has not permeated sufficiently to the practice. Furthermore, the appropriate application of information and communication technology (ICT) remains a big challenge, and finally project managers are not sufficiently trained in organizing and conducting virtual projects...

  13. Projecte Delorean

    OpenAIRE

    Rigual Martínez, Jaume

    2014-01-01

    The purpose of my project is to draw up a Business Plan to set up an audiovisual production company in partnership with my University Tecnocampus Mataró-Maresme. A production company which is intended for the formation of new professionals as well as the continued development of quality audiovisual projects. I want to make a feasibility project to show that this production company can be created and be a useful element for my University, particularly for students.

  14. Alzheimer's Project

    Medline Plus

    Full Text Available ... voluntary health organization in Alzheimer's care, support and research, the Alzheimer's Association has been an active partner in "THE ALZHEIMER'S PROJECT," ... (48 minutes) "Momentum ...

  15. Hanford isotope project strategic business analysis yttrium-90 (Y-90)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-01

    The purpose of this analysis is to address the short-term direction for the Hanford yttrium-90 (Y-90) project. Hanford is the sole DOE producer of Y-90, and is the largest repository for its source in this country. The production of Y-90 is part of the DOE Isotope Production and Distribution (IP and D) mission. The Y-90 is ``milked`` from strontium-90 (Sr-90), a byproduct of the previous Hanford missions. The use of Sr-90 to produce Y-90 could help reduce the amount of waste material processed and the related costs incurred by the clean-up mission, while providing medical and economic benefits. The cost of producing Y-90 is being subsidized by DOE-IP and D due to its use for research, and resultant low production level. It is possible that the sales of Y-90 could produce full cost recovery within two to three years, at two curies per week. Preliminary projections place the demand at between 20,000 and 50,000 curies per year within the next ten years, assuming FDA approval of one or more of the current therapies now in clinical trials. This level of production would incentivize private firms to commercialize the operation, and allow the government to recover some of its sunk costs. There are a number of potential barriers to the success of the Y-90 project, outside the control of the Hanford Site. The key issues include: efficacy, Food and Drug Administration (FDA) approval and medical community acceptance. There are at least three other sources for Y-90 available to the US users, but they appear to have limited resources to produce the isotope. Several companies have communicated interest in entering into agreements with Hanford for the processing and distribution of Y-90, including some of the major pharmaceutical firms in this country.

  16. LEX Project

    DEFF Research Database (Denmark)

    Damkilde, Lars; Larsen, Torben J.; Walbjørn, Jacob

    This document is aimed at helping all parties involved in the LEX project to get a common understanding of words, process, levels and the overall concept.......This document is aimed at helping all parties involved in the LEX project to get a common understanding of words, process, levels and the overall concept....

  17. LEX Project

    DEFF Research Database (Denmark)

    Damkilde, Lars; Larsen, Torben J.; Walbjørn, Jacob

    This document is aimed at helping all parties involved in the LEX project to get a common understanding of words, process, levels and the overall concept.......This document is aimed at helping all parties involved in the LEX project to get a common understanding of words, process, levels and the overall concept....

  18. Watchdog Project

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Rhett [Schweitzer Engineering Laboratories, Inc., Pullman, WA (United States); Campbell, Jack [CenterPoint Energy Houston Electric, TX (United States); Hadley, Mark [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-12-30

    The Watchdog Project completed 100% of the project Statement of Project Objective (SOPO). The Watchdog project was a very aggressive project looking to accomplish commercialization of technology that had never been commercialized, as a result it took six years to complete not the original three that were planned. No additional federal funds were requested from the original proposal and SEL contributed the additional cost share required to complete the project. The result of the Watchdog Project is the world’s first industrial rated Software Defined Network (SDN) switch commercially available. This technology achieved the SOPOO and DOE Roadmap goals to have strong network access control, improve reliability and network performance, and give the asset owner the ability to minimize attack surface before and during an attack. The Watchdog project is an alliance between CenterPoint Energy Houston Electric, Pacific Northwest National Laboratories (PNNL), and Schweitzer Engineering Laboratories, Inc. (SEL). SEL is the world’s leader in microprocessor-based electronic equipment for protecting electric power systems. PNNL performs basic and applied research to deliver energy, environmental, and national security for our nation. CenterPoint Energy is the third largest publicly traded natural gas delivery company in the U.S and third largest combined electricity and natural gas delivery company. The Watchdog Project efforts were combined with the SDN Project efforts to produce the entire SDN system solution for the critical infrastructure. The Watchdog project addresses Topic Area of Interest 5: Secure Communications, for the DEFOA- 0000359 by protecting the control system local area network itself and the communications coming from and going to the electronic devices on the local network. Local area networks usually are not routed and have little or no filtering capabilities. Combine this with the fact control system protocols are designed with inherent trust the control

  19. Freedom Project

    Directory of Open Access Journals (Sweden)

    Alejandra Suarez

    2014-02-01

    Full Text Available Freedom Project trains prisoners in nonviolent communication and meditation. Two complementary studies of its effects are reported in this article. The first study is correlational; we found decreased recidivism rates among prisoners trained by Freedom Project compared with recidivism rates in Washington state. The second study compared trained prisoners with a matched-pair control group and found improvement in self-reported anger, self-compassion, and certain forms of mindfulness among the trained group. Ratings of role-plays simulating difficult interactions show increased social skills among the group trained by Freedom Project than in the matched controls.

  20. TIARA project

    Science.gov (United States)

    Malecki, P.

    2013-10-01

    The aim of the Test Infrastructure and Accelerator Research Area - the TIARA project[1] is to consolidate and support the European R&D program in the field of physics and techniques of particle accelerators. This project, partially funded by the European Commission, groups 11 participants from 8 European countries, including Poland. Its present, threeyear (2011-2013) preparatory phase (PP) is shortly described in this paper. The project is divided into 9 work packages (WP). We will concentrate on four of them dedicated to governance, R&D infrastructures, joint R&D programming, and education and training, in which Polish participants are actively involved.

  1. 小断面盾构隧道塌方清理方案%Program in cleaning the collapsed in small cross-section shield-driven tunneling project

    Institute of Scientific and Technical Information of China (English)

    安冬云; 李建国; 廖潇; 寇宝庆; 张华芬

    2013-01-01

    Small cross-section shield-driven tunneling projects are characterized by minor diameters.Consequently,it is not possible to deploy large-scale equipment for excavation and cleaning-up operations.With consideration to pressurized slurry balance principles of shield machine,and with the background in clean-up of certain small cross-section collapse from shielddriven tunneling project,this paper reviews the techniques related to the cleaning-up of small cross-section collapse.In the newly developed program,sludge shall be agitated in water before pumping to sludge-water separator on ground surface.Upon completion of sludge separation,produced water shall be pumped back to the tunnel for reusing.The program involves water pumping by using vertical wells,water discharging through tunnels,sand discharging through upward and downward sections of tunnels,construction of safe doors in the tunnel and other techniques.The newly developed technique is applicable for cleaning up of materials with high solid contents and with uneven distribution of solid particles.In addition,the program is applicable to the working conditions with environmental humidity of 95 %,temperatures from-20 ℃ to 50 ℃ and with lower demands for human operators and water consumption.At the same time,the program may have high accessibility and applicability in cleaning-up operations in working conditions similar with limited spaces.%针对小断面盾构隧道直径小、无法采用大型机械设备挖掘清理的实际情况,借鉴盾构机泥水加压平衡模式原理,以某小断面盾构隧道塌方清理为工程背景,探讨了小断面盾构隧道塌方清理技术,制定了用水搅拌淤砂后由泵抽吸至地面泥水分离设备,析出淤砂后的水再返回隧道循环使用的清理方案,包括竖井抽水、隧道排水、隧道上下行段排砂以及设置隧道口安全门等措施.该技术适用于固体颗粒分布不均匀,固相含量较高

  2. Alzheimer's Project

    Medline Plus

    Full Text Available ... support vital research and services. "THE ALZHEIMER'S PROJECT" is a presentation of HBO Documentary Films and the ... Grandpa? by Maria Shriver Maria Shriver's children's book is about a grandparent with Alzheimer's. A great resource ...

  3. Alzheimer's Project

    Medline Plus

    Full Text Available ... Alzheimer's Gala A Night at Sardi's Alzheimer's Disease Awareness Month World Alzheimer's Month HBO Alzheimer’s Project MAKE ... for kids Learn how Maria Shriver is raising awareness FIND YOUR WALK Get help and support I ...

  4. Intending Projects

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    Project name:Jintan tire production base project (the first-phase project) Construction site:Jintan Economic Development Zone, Jiangsu Province Construction unit:Zhongce Rubber (Jintan) Co., Ltd. Total investment:RMB 2.42 billion yuan Project description:It is planned to cover an area of 3,000 mu. In the first phase, it will cover an area of 520.43 mu with designed staff of 4,500 people. It will mix 150,000 tons of rubber and produce 10 million u- nits of high-performance semi-steel-wire saloon car and light truck radial tires, 500,000 units of OTR tires and 100,000 tons of carbon black per year.

  5. Alzheimer's Project

    Medline Plus

    Full Text Available ... about the films on our message board . Watch films free online now "The Memory Loss Tapes" (85 ... ALZHEIMER'S PROJECT" is a presentation of HBO Documentary Films and the National Institute on Aging at the ...

  6. Alzheimer's Project

    Medline Plus

    Full Text Available ... 14, 2009 "The Alzheimer's Project" wins two Creative Arts Emmys Two installments of the multi-part HBO ... from the Alzheimer's Association and others, won Creative Arts Emmy awards. "The Memory Loss Tapes" was honored ...

  7. Alzheimer's Project

    Medline Plus

    Full Text Available ... Home > News & Events > Upcoming Events > HBO Alzheimer’s Project In the News Walk to End Alzheimer's Upcoming Events ... Memory Loss Tapes" was honored for Exceptional Merit in Nonfiction Filmmaking, while "Grandpa, Do You Know Who ...

  8. Alzheimer's Project

    Medline Plus

    Full Text Available ... Program. - Emmys.com As the leading voluntary health organization in Alzheimer's care, support and research, the Alzheimer's Association has been an active partner in "THE ALZHEIMER'S PROJECT," providing expert insight ...

  9. Alzheimer's Project

    Medline Plus

    Full Text Available | News | Events | Press | Contact 24/7 Helpline: 1.800.272.3900 Find your chapter: search by state Home > News & Events > Upcoming Events > HBO Alzheimer’s Project In the News ...

  10. Alzheimer's Project

    Medline Plus

    Full Text Available ... disease has on those with Alzheimer's and their families. September 14, 2009 "The Alzheimer's Project" wins two ... way Americans thinks about Alzheimer's disease. Tell your family and friends. Post info on your Web site . ...

  11. Alzheimer's Project

    Medline Plus

    Full Text Available ... HBO's "THE ALZHEIMER'S PROJECT" will expose the Alzheimer's crisis facing our nation and drive concerned citizens to ... Institute on Aging at the National Institutes of Health in association with the Alzheimer's Association, The Fidelity ® ...

  12. Alzheimer's Project

    Medline Plus

    Full Text Available ... 14, 2009 "The Alzheimer's Project" wins two Creative Arts Emmys Two installments of the multi-part HBO ... from the Alzheimer's Association and others, won Creative Arts Emmy awards. "The Memory Loss Tapes" was honored ...

  13. Alzheimer's Project

    Medline Plus

    Full Text Available ... their families. September 14, 2009 "The Alzheimer's Project" wins two Creative Arts Emmys Two installments of the ... you can help us change the way Americans thinks about Alzheimer's disease. Tell your family and friends. ...

  14. Alzheimer's Project

    Medline Plus

    Full Text Available ... disease has on those with Alzheimer's and their families. September 14, 2009 "The Alzheimer's Project" wins two ... way Americans thinks about Alzheimer's disease. Tell your family and friends. Post info on your Web site . ...

  15. Project Management

    DEFF Research Database (Denmark)

    Kampf, Constance

    2009-01-01

    In this video Associate Professor Constance Kampf talks about the importance project management. Not only as a tool in implementation, but also as a way of thinking, and as something that needs to be considered from idea conception......In this video Associate Professor Constance Kampf talks about the importance project management. Not only as a tool in implementation, but also as a way of thinking, and as something that needs to be considered from idea conception...

  16. Project Management

    DEFF Research Database (Denmark)

    Kampf, Constance

    2009-01-01

    In this video Associate Professor Constance Kampf talks about the importance project management. Not only as a tool in implementation, but also as a way of thinking, and as something that needs to be considered from idea conception......In this video Associate Professor Constance Kampf talks about the importance project management. Not only as a tool in implementation, but also as a way of thinking, and as something that needs to be considered from idea conception...

  17. LAPI project

    OpenAIRE

    Soler Vich, Josep Francesc

    2009-01-01

    This project carries out a part of a new location application. This service consists of location-based application that connects with a location server. That server provides the necessary location information to run the service. Then an interface between the location-based application and the location server is needed. That interface could be a Location Application Programming Interface (LAPI), and the development of one LAPI is the goal of this project.

  18. Lockheed Martin Hanford Corporation systems engineering project management

    Energy Technology Data Exchange (ETDEWEB)

    Baynes, P.A.

    1998-04-01

    Lockheed Martin Hanford Corporation is developing and implementing an integrated technical baseline for cleaning up environmental contamination at the Hanford Site in Washington State. The Hanford Site is located in Washington State and has been referred to as one of the largest Environmental Cleanup challenges in the US. It became contaminated with radioactive and dangerous wastes during the 40+ years it was being used to produce weapons grade plutonium in support of the US nuclear weapons program (See Figure 1). The US Department of Energy (US DOE) is responsible for cleanup of the Hanford Site with the Environmental Protection Agency (EPA) and the Washington State Department of Ecology (Ecology) both providing regulatory oversight. The US DOE, EPA and Ecology entered into an agreement in 1989 (Hanford Federal Facility Agreement and Consent Order, commonly referred to as the Tri-Party Agreement) that provides the framework for cleanup of the Hanford Site. However, since the inception of the Tri-Party Agreement, there have been numerous changes due to technical issues, funding issues, and priority changes within the cleanup mission. As a result, progress on the definition and execution of the cleanup work has been slower than anticipated and has resulted in some false starts, missed milestones, and milestones that have been completed that did not further the Site cleanup. The absence of a clearly defined mission resulted in a high percentage of projects that were canceled during construction or abandoned after completion and approximately $900 million spent on projects that did not bring cleanup or disposal any closer.

  19. Projection displays

    Science.gov (United States)

    Chiu, George L.; Yang, Kei H.

    1998-08-01

    Projection display in today's market is dominated by cathode ray tubes (CRTs). Further progress in this mature CRT projector technology will be slow and evolutionary. Liquid crystal based projection displays have gained rapid acceptance in the business market. New technologies are being developed on several fronts: (1) active matrix built from polysilicon or single crystal silicon; (2) electro- optic materials using ferroelectric liquid crystal, polymer dispersed liquid crystals or other liquid crystal modes, (3) micromechanical-based transducers such as digital micromirror devices, and grating light valves, (4) high resolution displays to SXGA and beyond, and (5) high brightness. This article reviews the projection displays from a transducer technology perspective along with a discussion of markets and trends.

  20. Echo project

    DEFF Research Database (Denmark)

    Gfader, Verina; Carson, Rebecca; Kraus, Chris

    Echo project (ed. by Verina Gfader and Ruth Höflich) is an online publication and community board that developed from a visit to the Los Angeles Art Book fair in January 2014. It was on the occasion of a prior book project, titled Prospectus, that the editorial team had been invited by the LAABF...... Intellect and Financialization sets a conceptual ground for rethinking subjective freedom; an encounter with Another LA opens out a multitude of cartographies - revealing more discreet and politically dynamic movements in the urban grid; there are glimpses of Machine Project’s events, a visual story around...

  1. LLAMA Project

    Science.gov (United States)

    Arnal, E. M.; Abraham, Z.; Giménez de Castro, G.; de Gouveia dal Pino, E. M.; Larrarte, J. J.; Lepine, J.; Morras, R.; Viramonte, J.

    2014-10-01

    The project LLAMA, acronym of Long Latin American Millimetre Array is very briefly described in this paper. This project is a joint scientific and technological undertaking of Argentina and Brazil on the basis of an equal investment share, whose mail goal is both to install and to operate an observing facility capable of exploring the Universe at millimetre and sub/millimetre wavelengths. This facility will be erected in the argentinean province of Salta, in a site located at 4830m above sea level.

  2. Infrastructure Mega projects and Spatial Polarization in Rio de Janeiro

    DEFF Research Database (Denmark)

    Silva, Victor; Ribeiro, Gustavo

    2008-01-01

    This paper looks at a prominent example of planning for sustainable development in Rio de Janeiro, namely the Guanabara Bay Clean-up Programme. We examine the role of the Guanabara Bay Clean-up Programme against the background of socio-economic and spatial trends in the last decade, identifying...... patterns of segregation and polarization on these levels. Beyond the fact that such patterns follow urban development tendencies under the impact of globalization which also have been documented elsewhere, we are interested here in looking at how the Guanabara Bay Clean-up Programme has contributed...... to reinforce existing trends of spatial and socio-economic segregation through the way in which sanitation infrastructure has been implemented in different areas of the city. In order to do that, we look here at two neighbourhoods located on opposite sides of the same, heavily polluted Guanabara Bay. The first...

  3. Alzheimer's Project

    Medline Plus

    Full Text Available ... Chicago National Alzheimer's Gala A Night at Sardi's Alzheimer's Disease Awareness Month World Alzheimer's Month HBO Alzheimer’s Project ... help us change the way Americans thinks about Alzheimer's disease. Tell your family and friends. Post info on ...

  4. Project Documerica

    Science.gov (United States)

    Journal of College Science Teaching, 1972

    1972-01-01

    The Environmental Protection Agency has started a project to actually picture the environmental movement in the United States. This is an attempt to make the public aware of the air pollution in their area or state and to acquaint them with the effects of air cleaning efforts. (PS)

  5. Alzheimer's Project

    Medline Plus

    Full Text Available ... A Night at Sardi's Alzheimer's Disease Awareness Month World Alzheimer's Month HBO Alzheimer’s Project MAKE A DONATION ... Alzheimer's Association ® . All rights reserved. Our vision: A world without Alzheimer's disease ® . Formed in 1980, the Alzheimer's ...

  6. Projection methods

    Science.gov (United States)

    Michael E. Goerndt; W. Keith Moser; Patrick D. Miles; Dave Wear; Ryan D. DeSantis; Robert J. Huggett; Stephen R. Shifley; Francisco X. Aguilar; Kenneth E. Skog

    2016-01-01

    One purpose of the Northern Forest Futures Project is to predict change in future forest attributes across the 20 States in the U.S. North for the period that extends from 2010 to 2060. The forest attributes of primary interest are the 54 indicators of forest sustainability identified in the Montreal Process Criteria and Indicators (Montreal Process Working Group, n.d...

  7. Project Avatar

    DEFF Research Database (Denmark)

    Juhlin, Jonas Alastair

    'Project Avatar' tager udgangspunkt i den efterretningsdisciplin, der kaldes Open Source Intelligence og indebærer al den information, som ligger frit tilgængeligt i åbne kilder. Med udbredelsen af sociale medier åbners der op for helt nye typer af informationskilder. Spørgsmålet er; hvor nyttig er...

  8. Alzheimer's Project

    Medline Plus

    Full Text Available ... families. September 14, 2009 "The Alzheimer's Project" wins two Creative Arts Emmys Two installments of the multi-part HBO documentary "The ... minutes) "Caregivers" (48 minutes) "Momentum in Science, Part 2" (70 minutes) Be a part of something big. ...

  9. THE PROJECT

    Directory of Open Access Journals (Sweden)

    P.M. Latyshev

    2008-09-01

    Full Text Available "Urals Industrial - Urals Polar" is the unique project and thus it will provide the economic security not only of the local territory but of the whole Russia in terms of several courses. This article is devoted to the main courses of these ones and their influence on the economy of the country.

  10. Project Baltia

    Index Scriptorium Estoniae

    2007-01-01

    Uus arhitektuuriajakiri "Project Baltia" tutvustab Baltimaade, Soome ja Peterburi regiooni arhitektuuri, linnaehitust ja disaini. Ilmub neli korda aastas inglise- ja venekeelsena. Väljaandja: kirjastus Balticum Peterburis koostöös Amsterdami ja Moskva kirjastusega A-Fond. Peatoimetaja Vladimir Frolov

  11. Projective mapping

    DEFF Research Database (Denmark)

    Dehlholm, Christian; Brockhoff, Per B.; Bredie, Wender Laurentius Petrus

    2012-01-01

    Projective Mapping (Risvik et.al., 1994) and its Napping (Pagès, 2003) variations have become increasingly popular in the sensory field for rapid collection of spontaneous product perceptions. It has been applied in variations which sometimes are caused by the purpose of the analysis and sometime...

  12. Project COLD.

    Science.gov (United States)

    Kazanjian, Wendy C.

    1982-01-01

    Describes Project COLD (Climate, Ocean, Land, Discovery) a scientific study of the Polar Regions, a collection of 35 modules used within the framework of existing subjects: oceanography, biology, geology, meterology, geography, social science. Includes a partial list of topics and one activity (geodesic dome) from a module. (Author/SK)

  13. Alzheimer's Project

    Medline Plus

    Full Text Available ... minutes) "Momentum in Science, Part 2" (70 minutes) Be a part of something big. HBO's "THE ALZHEIMER'S PROJECT" will expose the Alzheimer's crisis facing our nation and drive concerned citizens to take action. Here are three ways you ...

  14. Tedese Project

    Science.gov (United States)

    Buforn, E.; Davila, J. Martin; Bock, G.; Pazos, A.; Udias, A.; Hanka, W.

    The TEDESE (Terremotos y Deformacion Cortical en el Sur de España) project is a joint project of the Universidad Complutense de Madrid (UCM) and Real Instituto y Observatorio de la Armada de San Fernando, Cadiz (ROA) supported by the Spanish Ministerio de Ciencia y Tecnologia with the participation of the GeoforschungZen- trum, Potsdam (GFZ). The aim is to carry out a study of the characteristics of the oc- currence and mechanism of earthquakes together with measurements of crustal struc- ture and deformations in order to obtain an integrated evaluation of seismic risk in southern Spain from. As part of this project a temporal network of 10 broad-band seismological stations, which will complete those already existing in the zone, have been installed in southern Spain and northern Africa for one year beginning in October 2001. The objectives of the project are the study in detail of the focal mechanisms of earthquakes in this area, of structural in crust and upper mantle, of seismic anisotropy in crust and mantle as indicator for tectonic deformation processed and the measure- ments of crustal deformations using techniques with permanent GPS and SLR stations and temporary GPS surveys. From these studies, seismotectonic models and maps will be elaborated and seismic risk in the zone will be evaluated.

  15. Project Baltia

    Index Scriptorium Estoniae

    2007-01-01

    Uus arhitektuuriajakiri "Project Baltia" tutvustab Baltimaade, Soome ja Peterburi regiooni arhitektuuri, linnaehitust ja disaini. Ilmub neli korda aastas inglise- ja venekeelsena. Väljaandja: kirjastus Balticum Peterburis koostöös Amsterdami ja Moskva kirjastusega A-Fond. Peatoimetaja Vladimir Frolov

  16. Project Narrative

    Energy Technology Data Exchange (ETDEWEB)

    Driscoll, Mary C. [St. Bonaventure University, St Bonaventure, NY(United States)

    2012-07-12

    The Project Narrative describes how the funds from the DOE grant were used to purchase equipment for the biology, chemistry, physics and mathematics departments. The Narrative also describes how the equipment is being used. There is also a list of the positive outcomes as a result of having the equipment that was purchased with the DOE grant.

  17. SDN Project

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Rhett [Schweitzer Engineering Laboratories Inc, Pullman, WA (United States)

    2016-12-23

    The SDN Project completed on time and on budget and successfully accomplished 100% of the scope of work outlined in the original Statement of Project Objective (SOPO). The SDN Project formed an alliance between Ameren Corporation, University of Illinois Urbana- Champaign (UIUC), Pacific Northwest National Laboratories (PNNL), and Schweitzer Engineering Laboratories, Inc. (SEL). The objective of the SDN Project is to address Topic Area of Interest 2: Sustain critical energy delivery functions while responding to a cyber-intrusion under Funding Opportunity Announcement DE-FOA-0000797. The goal of the project is to design and commercially release technology that provides a method to sustain critical energy delivery functions during a cyber intrusion and to do this control system operators need the ability to quickly identify and isolate the affected network areas, and re-route critical information and control flows around. The objective of the SDN Project is to develop a Flow Controller that monitors, configures, and maintains the safe, reliable network traffic flows of all the local area networks (LANs) on a control system in the Energy sector. The SDN team identified the core attributes of a control system and produced an SDN flow controller that has the same core attributes enabling networks to be designed, configured and deployed that maximize the whitelisted, deny-bydefault and purpose built networks. This project researched, developed and commercially released technology that: Enables all field networks be to configured and monitored as if they are a single asset to be protected; Enables greatly improved and even precalculated response actions to reliability and cyber events; Supports pre-configured localized response actions tailored to provide resilience against failures and centralized response to cyber-attacks that improve network reliability and availability; Architecturally enables the right subject matter experts, who are usually the information

  18. Projective geometry and projective metrics

    CERN Document Server

    Busemann, Herbert

    2005-01-01

    The basic results and methods of projective and non-Euclidean geometry are indispensable for the geometer, and this book--different in content, methods, and point of view from traditional texts--attempts to emphasize that fact. Results of special theorems are discussed in detail only when they are needed to develop a feeling for the subject or when they illustrate a general method. On the other hand, an unusual amount of space is devoted to the discussion of the fundamental concepts of distance, motion, area, and perpendicularity.Topics include the projective plane, polarities and conic sectio

  19. Efficacy of Chicken Litter and Wood Biochars and Their Activated Counterparts in Heavy Metal Clean up from Wastewater

    Directory of Open Access Journals (Sweden)

    Isabel M. Lima

    2015-09-01

    Full Text Available It is known that properties of activated biochars are tightly associated with those of the original feedstock as well as pyrolysis and activation conditions. This study examined two feedstock types, pine wood shavings and chicken litter, to produce biochars at two different pyrolysis temperatures and subsequently activated by steam, acid or base. In order to measure activation efficiency, all materials were characterized for their properties and ability to remediate two well-known heavy metals of concern: copper and arsenic. Base activated biochars were superior in arsenic adsorption, to acid or steam activated samples, but increase in adsorption was not significant to warrant use. For wood biochars, significant increases of surface functionality as related to oxygen bearing groups and surface charge were observed upon acid activation which led to increased copper ion adsorption. However, oxygen bearing functionalities were not sufficient to explain why chicken litter biochars and steam activated biochars appeared to be significantly superior to wood shavings in positively charged metal ion adsorption. For chicken litter, functionality of respective biochars could be related to phosphate containing groups inherited from feedstock composition, favorably positioning this feedstock in metal ion remediation applications.

  20. Soil clean up by vapour extraction: parametrical study; Depollution des sols par extraction sous pression reduite: etude de quelques parametres

    Energy Technology Data Exchange (ETDEWEB)

    Dutheil, C.

    2003-05-15

    Soil vapour extraction is a treatment process for soils polluted by volatile organic compounds. Its principle relies on the circulation of gaseous flow in soil by the application of a depression of some hundreds milli-bars. A parametrical study has been led on a soil artificially polluted by tri-chloro-ethene. It shows that the gaseous flow rate has a slight influence on pollutants extraction yield. This is due to rate limited mass transfer processes. Soil moisture plays a negative role on treatment efficiency because of the reduction of the porosity available for the gas circulation. Tests have been performed on a soil polluted by a complex mixture of organic pollutants to elaborate a methodology of technical feasibility assessment. This methodology aims at identifying and limiting risks of site rehabilitation failure. Tests results show that soil vapour extraction was inadequate to treat the soil tested in this study because of the strong affinity between a dense organic phase (grease) and chlorinated solvents. (author)

  1. Trajectories of Scores on a Screening Instrument for PTSD Among World Trade Center Rescue, Recovery, and Clean-Up Workers.

    Science.gov (United States)

    Maslow, Carey B; Caramanica, Kimberly; Welch, Alice E; Stellman, Steven D; Brackbill, Robert M; Farfel, Mark R

    2015-06-01

    The longitudinal course of posttraumatic stress disorder (PTSD) over 8-9 years was examined among 16,488 rescue and recovery workers who responded to the events of September 11, 2001 (9/11) at the World Trade Center (WTC; New York, NY), and were enrolled in the World Trade Center Health Registry. Latent class growth analysis identified 5 groups of rescue and recovery workers with similar score trajectories at 3 administrations of the PTSD Checklist (PCL): low-stable (53.3%), moderate- stable (28.7%), moderate-increasing (6.4%), high-decreasing (7.7%), and high-stable (4.0%). Relative to the low-stable group, membership in higher risk groups was associated with 9/11-related exposures including duration of WTC work, with adjusted odds ratios ranging from 1.3 to 2.0, witnessing of horrific events (range = 1.3 to 2.1), being injured (range = 1.4 to 2.3), perceiving threat to life or safety (range = 2.2 to 5.2), bereavement (range = 1.6 to 4.8), and job loss due to 9/11 (range = 2.4 to 15.8). Within groups, higher PCL scores were associated with adverse social circumstances including lower social support, with B coefficients ranging from 0.2 to 0.6, divorce, separation, or widowhood (range = 0.4-0.7), and unemployment (range = 0.4-0.5). Given baseline, exposure-related, and contextual influences that affect divergent PTSD trajectories, screening for both PTSD and adverse circumstances should occur immediately, and at regular intervals postdisaster. © 2015 International Society for Traumatic Stress Studies.

  2. A three-phase microfluidic chip for rapid sample clean-up of alkaloids from plant extracts

    NARCIS (Netherlands)

    Tetala, K.K.R.; Swarts, J.W.; Chen, B.; Janssen, A.E.M.; Beek, van T.A.

    2009-01-01

    A three-phase microchip was developed for the rapid and efficient small-scale purification of alkaloids from plant extracts. As part of the development of such a three-phase microchip, first a two-phase microchip with two channels (3.2 cm and 9.3 cm) was used to study the extraction efficiency of st

  3. Cleaning up the Legacy of the Cold War: Plutonium Oxides and the Role of Synchrotron Radiation Research

    Energy Technology Data Exchange (ETDEWEB)

    Clark, David Lewis [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-01-21

    The deceptively simple binary formula of AnO2 belies an incredibly complex structural nature, and propensity to form mixed-valent, nonstoichiometric phases of composition AnO2±x. For plutonium, the very formation of PuO2+x has challenged a long-established dogma, and raised fundamental questions for long-term storage and environmental migration. This presentation covers two aspects of Los Alamos synchrotron radiation studies of plutonium oxides: (1) the structural chemistry of laboratory-prepared AnO2+x systems (An = U, Pu; 0 ≤ x ≤ 0.25) determined through a combination of x-ray absorption fine structure spectroscopy (XAFS) and x-ray scattering of laboratory prepared samples; and (2) the application of synchrotron radiation towards the decontamination and decommissioning of the Rocky Flats Environmental Technology Site. Making the case for particle transport mechanisms as the basis of plutonium and americium mobility, rather than aqueous sorption-desorption processes, established a successful scientific basis for the dominance of physical transport processes by wind and water. The scientific basis was successful because it was in agreement with general theory on insolubility of PuO2 in oxidation state IV, results of ultrafiltration analyses of field water/sediment samples, XAFS analyses of soil, sediment, and concrete samples, and was also in general agreement with on-site monitoring data. This understanding allowed Site contractors to rapidly move to application of soil erosion and sediment transport models as the means of predicting plutonium and americium transport, which led to design and application of site-wide soil erosion control technology to help control downstream concentrations of plutonium and americium in streamflow.

  4. The sociality of bioremediation: Hijacking the social lives of microbial populations to clean up heavy metal contamination

    OpenAIRE

    O'Brien, Siobhan; Buckling, Angus

    2015-01-01

    Bioremediation to remove toxic heavy metals from the environment relies on metal‐tolerant plants or microbes to do the job, but with varying degrees of success. Understanding the ecology and evolution of metal‐resistant bacterial societies could drastically improve the efficiency of microbial bioremediation.

  5. Clean up or mess up: the effect of sampling biases on measurements of degree distributions in mobile phone datasets

    CERN Document Server

    Decuyper, Adeline; Traag, Vincent; Blondel, Vincent D; Delvenne, Jean-Charles

    2016-01-01

    Mobile phone data have been extensively used in the recent years to study social behavior. However, most of these studies are based on only partial data whose coverage is limited both in space and time. In this paper, we point to an observation that the bias due to the limited coverage in time may have an important influence on the results of the analyses performed. In particular, we observe significant differences, both qualitatively and quantitatively, in the degree distribution of the network, depending on the way the dataset is pre-processed and we present a possible explanation for the emergence of Double Pareto LogNormal (DPLN) degree distributions in temporal data.

  6. Cleaning up the air: effectiveness of air quality policy for SO2 and NOx emissions in China

    Science.gov (United States)

    van der A, Ronald J.; Mijling, Bas; Ding, Jieying; Elissavet Koukouli, Maria; Liu, Fei; Li, Qing; Mao, Huiqin; Theys, Nicolas

    2017-02-01

    Air quality observations by satellite instruments are global and have a regular temporal resolution, which makes them very useful in studying long-term trends in atmospheric species. To monitor air quality trends in China for the period 2005-2015, we derive SO2 columns and NOx emissions on a provincial level with improved accuracy. To put these trends into perspective they are compared with public data on energy consumption and the environmental policies of China. We distinguish the effect of air quality regulations from economic growth by comparing them relatively to fossil fuel consumption. Pollutant levels, per unit of fossil fuel, are used to assess the effectiveness of air quality regulations. We note that the desulfurization regulations enforced in 2005-2006 only had a significant effect in the years 2008-2009, when a much stricter control of the actual use of the installations began. For national NOx emissions a distinct decreasing trend is only visible from 2012 onwards, but the emission peak year differs from province to province. Unlike SO2, emissions of NOx are highly related to traffic. Furthermore, regulations for NOx emissions are partly decided on a provincial level. The last 3 years show a reduction both in SO2 and NOx emissions per fossil fuel unit, since the authorities have implemented several new environmental regulations. Despite an increasing fossil fuel consumption and a growing transport sector, the effects of air quality policy in China are clearly visible. Without the air quality regulations the concentration of SO2 would be about 2.5 times higher and the NO2 concentrations would be at least 25 % higher than they are today in China.

  7. The application of mature dry storage technology and remote handling robotics to nuclear plant extension, clean-up and decommissioning

    Energy Technology Data Exchange (ETDEWEB)

    Blackwell, W.C. [GEC ALSTHOM Engineering Systems Ltd., Leicester (United Kingdom)

    1997-08-01

    This paper reviews a mature dry storage technology developed by GEC ALSTHOM Engineering Systems Limited (GAES) which offers a passive, economical and licensable method of providing irradiated fuel storage capacity at operational nuclear power stations. The evolution of the modular vault dry store (MVDS) technology has taken place over 25 years of operational experience, culminating in a product which meets all of the concerns of licensing authorities regarding safety and fuel integrity. The application of remote handling robotics to nuclear fuel and active component handling as a routine process rather than as an intervention technique is also reviewed. The growth of the application of this technology is governed by several factors which include: statutory requirements, safety assurance, risk reduction and economic pressures. The availability of a mature MVDS technology with an evolving process-capable robotics technology opens up opportunities for exploring proven UK products. (Author).

  8. Shoreline clean up during the Sea Empress incident: the role of surf washing (clay-oil flocculation), dispersants and bioremediation

    Energy Technology Data Exchange (ETDEWEB)

    Lunel, T. [AEA Technology, Culham (United Kingdom); Lee, K. [Department of Fisheries and Oceans, Mont-Joli, PQ (Canada). Inst. Maurice-Lamontagne; Swannell, R.; Wood, P.; Rusin, J.; Bailey, N.; Halliwell, C.; Davies, L.; Sommerville, M.; Dobie, A.; Mitchell, D.; McDonagh, M. [AEA Technology, Culham (United Kingdom)

    1996-09-01

    An outline of the at sea operations which took place in response to the Sea Empress oil spill, was presented. The grounding of the Sea Empress resulted in the release of 70,000 tonnes of blended crude oil into the environment. A qualitative account of the events which followed the incident were described. The early mobilization of a monitoring team has demonstrated the importance of scientific measurements to identify and maximize the efficiency of various cleanup operations. One of the important responses to this incident was the application of dispersants which by inducing flocculation, thereby reducing contact of oil directly with the substrate, and by reducing adhesion of the oil to the shoreline, contributed greatly to minimizing shoreline impact. 19 refs., 7 figs.

  9. Determination of acrylamide in coffee and coffee products by GC-MS using an improved SPE clean-up.

    Science.gov (United States)

    Soares, C; Cunha, S; Fernandes, J

    2006-12-01

    An improved gas chromatography-mass spectrometry (GC-MS) method to determine acrylamide (AA) in coffee and coffee products was developed. The method was based on two main purification steps: the first with ethanol and Carrez solutions in order to precipitate polysaccharides and proteins, respectively; and the second with a layered solid-phase extraction (SPE) column which proved to be efficient in the elimination of the main chromatographic interferences. The method is applicable to a wide range of coffee products. Twenty-six samples of different coffee products were analysed. The levels of AA were in the range 11.4-36.2 microg l-1 for 'espresso coffee' and 200.8-229.4 microg l-1 for coffee blends with cereals. The results indicate that the presence of cereals significantly increased the levels of AA.

  10. Reinventing Design Principles for Developing Low-Viscosity Carbon Dioxide-Binding Organic Liquids for Flue Gas Clean Up.

    Science.gov (United States)

    Malhotra, Deepika; Koech, Phillip K; Heldebrant, David J; Cantu, David C; Zheng, Feng; Glezakou, Vassiliki-Alexandra; Rousseau, Roger

    2017-02-08

    Anthropogenic CO2 emissions from point sources (e.g., coal fired-power plants) account for the majority of the greenhouse gases in the atmosphere. Water-lean solvent systems such as CO2 -binding organic liquids (CO2 BOLs) are being developed to reduce the energy requirement for CO2 capture. Many water-lean solvents such as CO2 BOLs are currently limited by the high viscosities of concentrated electrolyte solvents, thus many of these solvents have yet to move toward commercialization. Conventional standard trial-and-error approaches for viscosity reduction, while effective, are time consuming and economically expensive. We rethink the metrics and design principles of low-viscosity CO2 -capture solvents using a combined synthesis and computational modeling approach. We critically study the effects of viscosity reducing factors such as orientation of hydrogen bonding, introduction of higher degrees of freedom, and cation or anion charge solvation, and assess whether or how each factor affects viscosity of CO2 BOL CO2 capture solvents. Ultimately, we found that hydrogen bond orientation and strength is the predominant factor influencing the viscosity in CO2 BOL solvents. With this knowledge, a new CO2 BOL variant, 1-MEIPADM-2-BOL, was synthesized and tested, resulting in a solvent that is approximately 60 % less viscous at 25 mol % CO2 loading than our base compound 1-IPADM-2-BOL. The insights gained from the current study redefine the fundamental concepts and understanding of what influences viscosity in concentrated organic CO2 -capture solvents.

  11. Clean up procedure (GPC) voor de GC bepaling van de antioxidanten BHA, BHT en TBHQ in botervet

    NARCIS (Netherlands)

    Slangen, J.; Traag, W.; Kamp, van der H.; Hollman, P.

    1987-01-01

    Voor het opstellen van een normvoorschrift voor de bepaling van de antioxydanten BHA, BHT en TBHQ in botervet worden door werkgroep E43 van de "International Dairy Federation" methoden geëvalueerd. Uitgangspunt voor deze norm is de gaschromatografische bepaling beschreven in ISO 6463-1982. De wens

  12. LITERATURE REVIEW ON THE USE OF COMMERCIAL BIOREMEDIATION AGENTS FOR CLEAN-UP OF OIL-CONTAMINATED ESTUARINE ENVIRONMENTS

    Science.gov (United States)

    The objective of this document is to conduct a comprehensive review of the use of commercial bioremediation products treating oil spills in all environments, Literature assessed includes peer-reviewed articles, company reports, government reports, and reports by cleanup contracto...

  13. Human genotoxic study carried out two years after oil exposure during the clean-up activities using two different biomarkers.

    NARCIS (Netherlands)

    Biern, G.; Giraldo, J.; Zock, J.P.; Monyarch, G.; Espinosa, A.; Rodríguez-Trigo, G.; Gomez, F.; Pozo-Rodríguez, F.; Barberà, J.A.; Fuster, C.

    2015-01-01

    Micronuclei, comet and chromosome alterations assays are the most widely used biomarkers for determining the genotoxic damage in a population exposed to genotoxic chemicals. While chromosome alterations are an excellent biomarker to detect short- and long-term genotoxic effects, the comet assay only

  14. Clean-up plan for the Rioja region of Alava (Northern Spain); Plan de saneamiento de la Rioja Alavesa

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez Orue, J.M. [Servicio de Aguas Diputacion Foral de Alava, Vitoria (Spain); Nieves de la Vega Sedo, G.

    1996-08-01

    Requirements of wastewater discharges, in order to maintain and improve receiving water qualities, create a demand of means of wastewater management besides implementation of control systems, technical and economical management programs and financing. In this background, Direccion de Medio Ambiente of Diputacion Foral de Alava, through its Water Service, has settled the need of a integral planning for wastewater management in Rioja Alavesa. This job has been commanded to the engineering consulting AQUA/PLAN, S.A. (Author)

  15. A three-phase microfluidic chip for rapid sample clean-up of alkaloids from plant extracts

    NARCIS (Netherlands)

    Tetala, K.K.R.; Swarts, J.W.; Chen, B.; Janssen, A.E.M.; Beek, van T.A.

    2009-01-01

    A three-phase microchip was developed for the rapid and efficient small-scale purification of alkaloids from plant extracts. As part of the development of such a three-phase microchip, first a two-phase microchip with two channels (3.2 cm and 9.3 cm) was used to study the extraction efficiency of st

  16. Efficacy of chicken litter and wood biochars and their activated counterparts in heavy metal clean up from wastewater

    Science.gov (United States)

    It is known that properties of activated biochars are tightly associated with those of the original feedstock as well as pyrolysis and activation conditions. This study examined two feedstock types, pine wood shavings and chicken litter, to produce biochars at two different pyrolysis temperatures a...

  17. Thermoregulatory responses to layered personal protective clothing: practical implications for oil spill clean-up and remediation.

    Science.gov (United States)

    Sirikul, Bovorn; Bishop, Phillip A; Nevett, Michael E

    2011-01-01

    Many jobs in toxic environments and in less than ideal surroundings, such as oil spill remediation, require the use of 2 layers of personal protective equipment (PPE) to maximize worker safety. This study was designed to assess physiological and subjective responses while working in a single-layer (SL) or double-layer (DL) ensemble during a continuous work protocol in a hot environment of 31 °C WBGT. Eleven men in a repeated-measures design performed 2 counterbalanced work-bouts at a time-weighted work rate of 300 kcal/h. All tests were terminated when a rectal temperature (Tre) of 38.7 °C was attained. Total work time was significantly (P < 0.05) shorter in DL (60.5 ± 3.9 versus 66.4 ± 4.6 min in SL), and final microenvironmental temperature (MEt) (35.6 ± 0.9 °C vs 37.1 ± 0.3 °C) and humidity (MEh) (90.0 ± 4.0% vs 95.4 ± 1.1%) were higher in DL. There were no differences for Tre, mean skin temperature, or sweat rate over time. These data have practical implications in that although the physiological strain on workers in DL was not substantially greater than in SL, worker safety, and productivity can be reduced while working in layered PPE.

  18. Cleaning up the big muddy: A meta-synthesis of the research on the social impact of dams

    NARCIS (Netherlands)

    Kirchherr, Julian; Pohlner, Huw; Charles, Katrina J.

    Scholars have been exploring the social impacts of dams for over 50 years, but a lack of systematic approaches has resulted in many research gaps remaining. This paper presents the first systematic review of the literature on the social impacts of dams. For this purpose, we built a sample of 217

  19. LITERATURE REVIEW ON THE USE OF COMMERCIAL BIOREMEDIATION AGENTS FOR CLEAN-UP OF OIL-CONTAMINATED ESTUARINE ENVIRONMENTS

    Science.gov (United States)

    The objective of this document is to conduct a comprehensive review of the use of commercial bioremediation products treating oil spills in all environments, Literature assessed includes peer-reviewed articles, company reports, government reports, and reports by cleanup contracto...

  20. Reinventing Design Principles for Developing Low-Viscosity Carbon Dioxide-Binding Organic Liquids for Flue Gas Clean Up

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2017-01-11

    Anthropogenic carbon dioxide (CO2) emission from point sources, such as coal fired-power plants, account for the majority of the green houses gasses in the atmosphere. Capture, storage and utilization are required to mitigate adverse environmental effects. Aqueous amine-based CO2 capture solvents are currently considered the industry standard, but deployment to market is limited by their high regeneration energy demand. In that context, energy efficient and less-viscous water-lean transformational solvent systems known as CO2 Binding Organic Liquids (CO2BOLs) are being developed in our group to advance this technology to commercialization. Herein, we present a logical design approach based on fundamental concepts of organic chemistry and computer simulations aimed at lowering solvent viscosity. Conceptually, viscosity reduction would be achieved by systemmatic methods such as introduction of steric hindrance on the anion to minimize the intermolecular cation-anion interactions, fine tuning the electronics, hydrogen bonding orientation and strength, and charge solvation. Conventional standard trial-and-error approaches while effective, are time consuming and economically expensive. Herein, we rethink the metrics and design principles of low-viscosity CO2 capture solvents using a combined synthesis and computational modeling approach. We critically study the impacts of modyfying factors such as as orientation of hydrogen bonding, introduction of higher degrees of freedom and cation or anion charge solvation and assess if or how each factor impacts viscosity of CO2BOL CO2 capture solvents. Ultimately, we found that hydrogen bond orientation and strength is predominantly influencing the viscosity in CO2BOL solvents. With this knowledge, a new 1-MEIPADM-2-BOL CO2BOL variant was synthesized and tested, resulting in a solvent that is approximately 60% less viscous at 25 mol% CO2 loading with respect to our base compound 1-IPADM-2-BOL. The insights gained from the current study redefines the fundamental concepts and understanding of what influences viscosity in concentrated organic CO2 capture solvents.

  1. Evaluation of affinity-based serum clean-up in mass spectrometric analysis: Plastic vs monoclonal antibodies.

    Science.gov (United States)

    Rossetti, Cecilia; Levernæs, Maren C S; Reubsaet, Léon; Halvorsen, Trine G

    2016-11-04

    Mass spectrometric assays are now of great relevance for trace compound analysis in complex matrices such as serum and plasma samples. Especially in the quantification of low abundant protein-biomarkers, the choice of the sample preparation is crucial. In the present paper immunocapture and Molecular Imprinted Polymers (MIPs) have been applied in the determination of pro-gastrin-releasing peptide, a Small Cell Lung Cancer marker. These affinity-based techniques were compared in terms of matrix effect, limits of detection, repeatability and extraction specificity. In addition, protein precipitation was included for comparison as it is a typical sample preparation method of biological matrices. The results highlighted differences in the methods' performance and specificity, strongly affecting the outcome of the mass spectrometric determination. Plastic and monoclonal antibodies confirmed to be sensitive and specific sample preparations able to determine ProGRP at clinical relevant concentration, although only the use of monoclonal antibodies allowed the reliable quantification of ProGRP at reference levels (8pM). In addition better insight in the specificity of the three sample preparation techniques was gained. This might also be of interest for other biological applications.

  2. [Determination of phthalate plasticizers in foods by high performance liquid chromatography with gel permeation chromatographic clean-up].

    Science.gov (United States)

    Zhang, Chunyu; Wang, Hui; Zhang, Xiaohui; Ma, Zhongqiang; Deng, Wanmei; Hu, Ke; Ding, Mingyu

    2011-12-01

    A method of gel permeation chromatography-high performance liquid chromatography (GPC-HPLC) was established for the simultaneous determination of 5 main phthalate plasticizers in foods (edible oil, instant noodles, fried pastries, Saqima, etc.). The samples were extracted with petroleum ether in an ultrasonator, purified by a GPC column, and analyzed by HPLC. The chromatographic separation was achieved on a Labtech-C18 column (250 mm x 4.6 mm, 5 microm) using acetonitrile and water mixture as the mobile phases in a gradient elution mode. The developed method exhibited a linear correlation coefficient of more than 0.997 and the detection limits of 3.25 - 13.4 microg/L. The spike recoveries were between 70.4% and 113.6% with the relative standard deviations (RSDs, n = 3) of 0.3% - 5.8% at the spiked level of 50 mg/L. This method is simple, rapid and practical, and can be used for the simultaneous determination of PAEs in grease food samples.

  3. Synthesis of molecularly imprinted polymers for the application of selective clean-up vinblastine from Catharanthus roseus extract

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Molecularly imprinted polymers (MIPs) are synthetic tailor-made polymers with high selectivity towards a particular substance (template).An MIP using vinblastine (VLB) as the template molecule was synthesized and characterized.The presence of monomer-template complexes in a non-covalent way was confirmed by UV-vis spectrometry analysis.The polymerization was performed using methacrylic acid (MAA) as the functional monomer,ethylene glycol dimethacrylate (EGDMA) as the cross-linking agent,and toluene as the porogenic solvent by a thermo-polymerization method.The characterization of the obtained MIP was evaluated by scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) analysis.It was observed that the morphology of the MIP was more porous and rough,and the surface area had a significant increase compared with that of the non-imprinted polymer (NIP).This MIP was used as the sorbents of solid-phase extraction (SPE) to assess the selectivity of the MIP after optimization of the SPE protocol.VLB was specifically adsorbed on the MIP cartridge,while to vincristine (VCR),the chemical analog of VLB,almost no selective binding appeared.On the basis of the results,Catharanthus roseus extract was applied to the MIP cartridge for investigating its capability to extract VLB from the plant extract,and the capacity of the MIP cartridge was also evaluated.It was shown that the MIP could effectively enrich VLB from C.roseus extract and the recovery amounted to 93.8%.The solvents dissolving the samples had significant influence on the capacity of the MIP cartridge;it was 750 μg/g in toluene,625 μg/g in chloroform,and 250 μg/g in methanol.

  4. Supercritical fluid extraction as a clean-up method for the extraction of pesticides from wool wax. A preliminary approach

    Directory of Open Access Journals (Sweden)

    Crespi, M

    2007-06-01

    Full Text Available The work presented is a preliminary study for the development of a method for the extraction of pesticides from wax samples by means of superficial fluid extraction. The novelty of the study is the direct extraction of the pesticides from raw wool wax without any cleanup, as direct extraction has been considered almost impossible by many authors.Este trabajo es un estudio preliminar para el desarrollo de un método de extracción de pesticidas directamente de las muestras de cera mediante extracción con fluido supercrítico. La novedad del estudio consiste en la extracción directa de los pesticidas de la cera de lana cruda sin ninguna limpieza previa, cuando muchos autores han considerado casi imposible la extracción directa.

  5. Final report of the decontamination and decommissioning of Building 44 at the Grand Junction Projects Office Facility

    Energy Technology Data Exchange (ETDEWEB)

    Widdop, M.R.

    1996-07-01

    The U.S. Department of Energy (DOE) Junction Projects Office (GJPO) occupies a 61.7 acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the Grand Junction Projects Office Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, is also the remedial action contractor. Building 44 was radiologically contaminated and the building was demolished in 1994. The soil area within the footprint of the building was not contaminated; it complies with the identified standards and the area can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  6. Final report of the decontamination and decommissioning of Building 34 at the Grand Junction Projects Office Facility

    Energy Technology Data Exchange (ETDEWEB)

    Widdop, M.R.

    1996-08-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7 acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the Grand Junction Projects Office Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, was also the remedial action contractor. Building 34 was radiologically contaminated and the building was demolished in 1996. The soil area within the footprint of the building was analyzed and found to be not contaminated. The area can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual closeout report for each contaminated GJPO building.

  7. Project Prometheus

    Science.gov (United States)

    Johnson, Steve

    2003-01-01

    Project Prometheus will enable a new paradigm in the scientific exploration of the Solar System. The proposed JIMO mission will start a new generation of missions characterized by more maneuverability, flexibility, power and lifetime. Project Prometheus organization is established at NASA Headquarters: 1.Organization established to carry out development of JIMO, nuclear power (radioisotope), and nuclear propulsion research. 2.Completed broad technology and national capacity assessments to inform decision making on planning and technology development. 3.Awarded five NRA s for nuclear propulsion research. 4.Radioisotope power systems in development, and Plutonium-238 being purchased from Russia. 5.Formulated science driven near-term and long-term plan for the safe utilization of nuclear propulsion based missions. 6.Completed preliminary studies (Pre-Phase A) of JIMO and other missions. 7.Initiated JIMO Phase A studies by Contractors and NASA.

  8. PARTNER Project

    CERN Multimedia

    Ballantine, A; Dixon-Altaber, H; Dosanjh, M; Kuchina, L

    2011-01-01

    Hadrontherapy uses particle beams to treat tumours located near critical organs and tumours that respond poorly to conventional radiation therapy. It has become evident that there is an emerging need for reinforcing research in hadrontherapy and it is essential to train professionals in this rapidly developing field. PARTNER is a 4-year Marie Curie Training project funded by the European Commission with 5.6 million Euros aimed at the creation of the next generation of experts. Ten academic institutes and research centres and two leading companies are participating in PARTNER, that is coordinated by CERN, forming a unique multidisciplinary and multinational European network. The project offers research and training opportunities to 25 young biologists, engineers, physicians and physicists and is allowing them to actively develop modern techniques for treating cancer in close collaboration with leading European Institutions. For this purpose PARTNER relies on cutting edge research and technology development, ef...

  9. Hydropower Projects

    Energy Technology Data Exchange (ETDEWEB)

    None

    2015-04-02

    The Water Power Program helps industry harness this renewable, emissions-free resource to generate environmentally sustainable and cost-effective electricity. Through support for public, private, and nonprofit efforts, the Water Power Program promotes the development, demonstration, and deployment of advanced hydropower devices and pumped storage hydropower applications. These technologies help capture energy stored by diversionary structures, increase the efficiency of hydroelectric generation, and use excess grid energy to replenish storage reserves for use during periods of peak electricity demand. In addition, the Water Power Program works to assess the potential extractable energy from domestic water resources to assist industry and government in planning for our nation’s energy future. From FY 2008 to FY 2014, DOE’s Water Power Program announced awards totaling approximately $62.5 million to 33 projects focused on hydropower. Table 1 provides a brief description of these projects.

  10. Projection Methods

    DEFF Research Database (Denmark)

    Wagner, Falko Jens; Poulsen, Mikael Zebbelin

    1999-01-01

    When trying to solve a DAE problem of high index with more traditional methods, it often causes instability in some of the variables, and finally leads to breakdown of convergence and integration of the solution. This is nicely shown in [ESF98, p. 152 ff.].This chapter will introduce projection...... methods as a way of handling these special problems. It is assumed that we have methods for solving normal ODE systems and index-1 systems....

  11. Polytope projects

    CERN Document Server

    Iordache, Octavian

    2013-01-01

    How do you know what works and what doesn't? This book contains case studies highlighting the power of polytope projects for complex problem solving. Any sort of combinational problem characterized by a large variety of possibly complex constructions and deconstructions based on simple building blocks can be studied in a similar way. Although the majority of case studies are related to chemistry, the method is general and equally applicable to other fields for engineering or science.

  12. Burnet project.

    Science.gov (United States)

    Masellis, A; Atiyeh, B

    2009-12-31

    The BurNet project, a pilot project of the Eumedis initiative, has become true. The Eumedis (EUro MEDiterranean Information Society) initiative is part of the MEDA programme of the EU to develop the Information Society in the Mediterranean area. In the health care sector, the objective of Eumedis is: the deployment of network-based solutions to interconnect - using userfriendly and affordable solutions - the actors at all levels of the "health care system" of the Euro-Mediterranean region. The Bur Net project interconnects 17 Burn Centres (BC) in the Mediterranean Area through an information network both to standardize courses of action in the field of prevention, treatment, and functional and psychological rehabilitation of burn patients and to coordinate interactions between BC and emergency rooms in peripheral hospitals using training/information activities and telemedicine to optimize first aid provided to burn patients before referral to a BC. Shared procedure protocols for prevention and the care and rehabilitation of patients, both at individual and mass level, will help to create an international specialized database and a Webbased teleconsultation system.

  13. SUPERSITE PROJECT

    Directory of Open Access Journals (Sweden)

    Silvia Ferrari

    2010-04-01

    Full Text Available The project is focused on a detailed study of some chemical, physical and toxicological parameters and on health, epidemiological and environmental assessment by interpretative models, in the atmosphere of Emilia-Romagna (Italy. The project rises from the necessity to improve  knowledge about environmental and health aspects of fine and ultrafine particles, in primary and secondary components, in the atmosphere. The project, structured in 7 workpackages, is organized in two measurement programmes: the routine one that has a mainly daily time resolution, and the intensive one with high time resolution and a higher chemical speciation than the routine one. The sampling sites are five: three in urban areas (Bologna, Parma and Rimini, one in a rural area (San Pietro Capofiume and one in a remote area (Monte Cimone. Parallel to outdoor studies, a workpackage  is planned for indoor studies and chemical composition analysis with the  outdoor/indoor ratio for characterizing indoor human exposure to outdoor pollution.

  14. Project Exodus

    Science.gov (United States)

    1990-01-01

    Project Exodus is an in-depth study to identify and address the basic problems of a manned mission to Mars. The most important problems concern propulsion, life support, structure, trajectory, and finance. Exodus will employ a passenger ship, cargo ship, and landing craft for the journey to Mars. These three major components of the mission design are discussed separately. Within each component the design characteristics of structures, trajectory, and propulsion are addressed. The design characteristics of life support are mentioned only in those sections requiring it.

  15. FLOAT Project

    DEFF Research Database (Denmark)

    Sørensen, Eigil V.; Aarup, Bendt

    The objective of the FLOAT project is to study the reliability of high-performance fibre-reinforced concrete, also known as Compact Reinforced Composite (CRC), for the floats of wave energy converters. In order to reach a commercial breakthrough, wave energy converters need to achieve a lower price...... of energy produced, comparable to prices currently obtained from offshore wind power, and this can be done by the use of more suitable materials. The flotation device is a key part of converters, as it accounts for a considerable share of initial investment, up to 27% depending on the converter. CRC floats...

  16. PROJECT TEAM MOTIVATION IN PROJECT REALISATION

    OpenAIRE

    Perica Jankoviæ

    2014-01-01

    Managing a project team is an everyday activity when managing a project realization. In order to accomplish efficiency at work on a project, it is necessary for all the participants in the project to be motivated and interested, focused on accomplishing the project. To the end of providing greater motivation of the project team for the realization of the project, the project manager should be very well acquainted with the needs and motives of the people he/she is managing and should find the ...

  17. PORTNUS Project

    Energy Technology Data Exchange (ETDEWEB)

    Loyal, Rebecca E. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2015-07-14

    The objective of the Portunus Project is to create large, automated offshore ports that will the pace and scale of international trade. Additionally, these ports would increase the number of U.S. domestic trade vessels needed, as the imported goods would need to be transported from these offshore platforms to land-based ports such as Boston, Los Angeles, and Newark. Currently, domestic trade in the United States can only be conducted by vessels that abide by the Merchant Marine Act of 1920 – also referred to as the Jones Act. The Jones Act stipulates that vessels involved in domestic trade must be U.S. owned, U.S. built, and manned by a crew made up of U.S. citizens. The Portunus Project would increase the number of Jones Act vessels needed, which raises an interesting economic concern. Are Jones Act ships more expensive to operate than foreign vessels? Would it be more economically efficient to modify the Jones Act and allow vessels manned by foreign crews to engage in U.S. domestic trade? While opposition to altering the Jones Act is strong, it is important to consider the possibility that ship-owners who employ foreign crews will lobby for the chance to enter a growing domestic trade market. Their success would mean potential job loss for thousands of Americans currently employed in maritime trade.

  18. FLORAM project

    Energy Technology Data Exchange (ETDEWEB)

    Zulauf, W.E. [Sao Paolos Environmental Secretariat, Sao Paolo (Brazil); Goelho, A.S.R. [Riocell, S.A. (Brazil); Saber, A. [IEA-Instituto de Estudos Avancados (Brazil)] [and others

    1995-12-31

    The project FLORAM was formulated at the `Institute for Advanced Studies` of the University of Sao Paulo. It aims at decreasing the level of carbon dioxide in the atmosphere and thus curbing the green-house effect by way of a huge effort of forestation and reforestation. The resulting forests when the trees mature, will be responsible for the absorption of about 6 billion tons of excess carbon. It represents 5 % of the total amount of CO{sub 2} which is in excess in the earth`s atmosphere and represents 5 % of the available continental surfaces which can be forested as well. Therefore, if similar projects are implemented throughout the world, in theory all the exceeding CO{sub 2}, responsible for the `greenhouse effect`, (27 % or 115 billion tons of carbon) would be absorbed. Regarding this fact, there would be a 400 million hectar increase of growing forests. FLORAM in Brazil aims to plant 20.000.000 ha in 2 years at a cost of 20 billion dollars. If it reaches its goals that will mean that Brazil will have reforested an area almost half as big as France. (author)

  19. Project Explorer

    Science.gov (United States)

    Dannenberg, K. K.; Henderson, A.; Lee, J.; Smith, G.; Stluka, E.

    1984-01-01

    PROJECT EXPLORER is a program that will fly student-developed experiments onboard the Space Shuttle in NASA's Get-Away Special (GAS) containers. The program is co-sponsored by the Alabama Space and Rocket Center, the Alabama-Mississippi Section of the American Institute of Aeronautics and Astronautics, Alabama A&M University and requires extensive support by the University of Alabama in Huntsville. A unique feature of this project will demonstrate transmissions to ground stations on amateur radio frequencies in English language. Experiments Nos. 1, 2, and 3 use the microgravity of space flight to study the solidification of lead-antimony and aluminum-copper alloys, the growth of potassium-tetracyanoplatinate hydrate crystals in an aqueous solution, and the germination of radish seeds. Flight results will be compared with Earth-based data. Experiment No. 4 features radio transmission and will also provide timing for the start of all other experiments. A microprocessor will obtain real-time data from all experiments as well as temperature and pressure measurements taken inside the canister. These data will be transmitted on previously announced amateur radio frequencies after they have been converted into the English language by a digitalker for general reception.

  20. SISCAL project

    Science.gov (United States)

    Santer, Richard P.; Fell, Frank

    2003-05-01

    The first "ocean colour" sensor, Coastal Zone Color Scanner (CZCS), was launched in 1978. Oceanographers learnt a lot from CZCS but it remained a purely scientific sensor. In recent years, a new generation of satellite-borne earth observation (EO) instruments has been brought into space. These instruments combine high spectral and spatial resolution with revisiting rates of the order of one per day. More instruments with further increased spatial, spectral and temporal resolution will be available within the next years. In the meantime, evaluation procedures taking advantage of the capabilities of the new instruments were derived, allowing the retrieval of ecologically important parameters with higher accuracy than before. Space agencies are now able to collect and to process satellite data in real time and to disseminate them via the Internet. It is therefore meanwhile possible to envisage using EO operationally. In principle, a significant demand for EO data products on terrestrial or marine ecosystems exists both with public authorities (environmental protection, emergency management, natural resources management, national parks, regional planning, etc) and private companies (tourist industry, insurance companies, water suppliers, etc). However, for a number of reasons, many data products that can be derived from the new instruments and methods have not yet left the scientific community towards public or private end users. It is the intention of the proposed SISCAL (Satellite-based Information System on Coastal Areas and Lakes) project to contribute to the closure of the existing gap between space agencies and research institutions on one side and end users on the other side. To do so, we intend to create a data processor that automatically derives and subsequently delivers over the Internet, in Near-Real-Time (NRT), a number of data products tailored to individual end user needs. The data products will be generated using a Geographical Information System (GIS

  1. Surface and subsurface cleanup protocol for radionuclides, Gunnison, Colorado, UMTRA project processing site. Final [report

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    Surface and subsurface soil cleanup protocols for the Gunnison, Colorado, processing sits are summarized as follows: In accordance with EPA-promulgated land cleanup standards (40 CFR 192), in situ Ra-226 is to be cleaned up based on bulk concentrations not exceeding 5 and 15 pCi/g in 15-cm surface and subsurface depth increments, averaged over 100-m{sup 2} grid blocks, where the parent Ra-226 concentrations are greater than, or in secular equilibrium with, the Th-230 parent. A bulk interpretation of these EPA standards has been accepted by the Nuclear Regulatory Commission (NRC), and while the concentration of the finer-sized soil fraction less than a No. 4 mesh sieve contains the higher concentration of radioactivity, the bulk approach in effect integrates the total sample radioactivity over the entire sample mass. In locations where Th-230 has differentially migrated in subsoil relative to Ra-226, a Th-230 cleanup protocol has been developed in accordance with Supplemental Standard provisions of 40 CFR 192 for NRC/Colorado Department of Health (CDH) approval for timely implementation. Detailed elements of the protocol are contained in Appendix A, Generic Protocol from Thorium-230 Cleanup/Verification at UMTRA Project Processing Sites. The cleanup of other radionuclides or nonradiological hazards that pose a significant threat to the public and the environment will be determined and implemented in accordance with pathway analysis to assess impacts and the implications of ALARA specified in 40 CFR 192 relative to supplemental standards.

  2. Surface and subsurface cleanup protocol for radionuclides, Gunnison, Colorado, UMTRA project processing site. Final [report

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    Surface and subsurface soil cleanup protocols for the Gunnison, Colorado, processing sits are summarized as follows: In accordance with EPA-promulgated land cleanup standards (40 CFR 192), in situ Ra-226 is to be cleaned up based on bulk concentrations not exceeding 5 and 15 pCi/g in 15-cm surface and subsurface depth increments, averaged over 100-m{sup 2} grid blocks, where the parent Ra-226 concentrations are greater than, or in secular equilibrium with, the Th-230 parent. A bulk interpretation of these EPA standards has been accepted by the Nuclear Regulatory Commission (NRC), and while the concentration of the finer-sized soil fraction less than a No. 4 mesh sieve contains the higher concentration of radioactivity, the bulk approach in effect integrates the total sample radioactivity over the entire sample mass. In locations where Th-230 has differentially migrated in subsoil relative to Ra-226, a Th-230 cleanup protocol has been developed in accordance with Supplemental Standard provisions of 40 CFR 192 for NRC/Colorado Department of Health (CDH) approval for timely implementation. Detailed elements of the protocol are contained in Appendix A, Generic Protocol from Thorium-230 Cleanup/Verification at UMTRA Project Processing Sites. The cleanup of other radionuclides or nonradiological hazards that pose a significant threat to the public and the environment will be determined and implemented in accordance with pathway analysis to assess impacts and the implications of ALARA specified in 40 CFR 192 relative to supplemental standards.

  3. Final report of the decontamination and decommissioning of Building 1 at the Grand Junction Projects Office Facility

    Energy Technology Data Exchange (ETDEWEB)

    Widdop, M.R.

    1996-08-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJPO Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, also is the remedial action contractor. Building 1 was found to be radiologically contaminated and was demolished in 1996. The soil beneath and adjacent to the building was remediated in accordance with identified standards and can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  4. Final report of the decontamination and decommissioning of Building 18 at the Grand Junction Projects Office Facility

    Energy Technology Data Exchange (ETDEWEB)

    Widdop, M.R.

    1996-08-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJPO Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, also is the remedial action contractor. The soil beneath Building 18 was found to be radiologically contaminated; the building was not contaminated. The soil was remediated in accordance with identified standards. Building 18 and the underlying soil can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  5. ENVISION Project

    CERN Multimedia

    Ballantine, A; Dixon-Altaber, H; Dosanjh, M; Kuchina, L

    2011-01-01

    Hadrontherapy is a highly advanced technique of cancer radiotherapy that uses beams of charged particles (ions) to destroy tumour cells. While conventional X-rays traverse the human body depositing radiation as they pass through, ions deliver most of their energy at one point. Hadrontherapy is most advantageous once the position of the tumour is accurately known, so that healthy tissues can be protected. Accurate positioning is a crucial challenge for targeting moving organs, as in lung cancer, and for adapting the irradiation as the tumour shrinks with treatment. Therefore, quality assurance becomes one of the most relevant issues for an effective outcome of the cancer treatment. In order to improve the quality assurance tools for hadrontherapy, the European Commission is funding ENVISION, a 4-year project that aims at developing solutions for: real-• time non invasive monitoring • quantitative imaging • precise determination of delivered dose • fast feedback for optimal treatment planning • real-t...

  6. Infrastructure Mega projects and Spatial Polarization in Rio de Janeiro

    DEFF Research Database (Denmark)

    Silva, Victor; Ribeiro, Gustavo

    2008-01-01

    -way containing the main traffic towards Rio de Janeiro International Airport. The Guanabara Bay Clean-up Programme interventions in both areas have contributed to perpetuate and reinforce existing patterns of spatial segregation, both between neighbourhoods of different socio-economic status and between...... such neighbourhoods and potential environmental amenities....

  7. Project Success in Agile Development Software Projects

    Science.gov (United States)

    Farlik, John T.

    2016-01-01

    Project success has multiple definitions in the scholarly literature. Research has shown that some scholars and practitioners define project success as the completion of a project within schedule and within budget. Others consider a successful project as one in which the customer is satisfied with the product. This quantitative study was conducted…

  8. Project Success in Agile Development Software Projects

    Science.gov (United States)

    Farlik, John T.

    2016-01-01

    Project success has multiple definitions in the scholarly literature. Research has shown that some scholars and practitioners define project success as the completion of a project within schedule and within budget. Others consider a successful project as one in which the customer is satisfied with the product. This quantitative study was conducted…

  9. Ace Project as a Project Management Tool

    Science.gov (United States)

    Cline, Melinda; Guynes, Carl S.; Simard, Karine

    2010-01-01

    The primary challenge of project management is to achieve the project goals and objectives while adhering to project constraints--usually scope, quality, time and budget. The secondary challenge is to optimize the allocation and integration of resources necessary to meet pre-defined objectives. Project management software provides an active…

  10. Project Lyman

    CERN Document Server

    McCandliss, Stephan R; Blair, William P; Kaiser, Mary Elizabeth; Feldman, Paul D; Meurer, Gerhardt R; Dixon, William V; Sahnow, David J; Neufeld, David A; Lupu, Roxana E; Fleming, Brian; Smee, Stephen A; Andersson, B G; Moseley, Samuel H; Kutyrev, Alexander S; Li, Mary J; Sonneborn, George; Siegmund, Oswald H W; Vallerga, John V; Welsh, Barry Y; Stiavelli, Massimo; Windhorst, Rogier A; Shapley, Alice E

    2008-01-01

    We explore the design of a space mission, Project Lyman, which has the goal of quantifying the ionization history of the universe from the present epoch to a redshift of z ~ 3. Observations from WMAP and SDSS show that before a redshift of z >~ 6 the first collapsed objects, possibly dwarf galaxies, emitted Lyman continuum (LyC) radiation shortward of 912 A, reionizing most of the universe. How LyC escapes from galactic environments, whether it induces positive or negative feedback on the local and global collapse of structures, and the role played by clumping, molecules, metallicity and dust are major unanswered theoretical questions, requiring observational constraint. Numerous intervening Lyman limit systems, which frustrate the detection of LyC from high z objects, thin below z ~ 3 where there are a few objects with apparently very high fesc. At low z there are only controversial detections and a handful of upper limits. A wide-field multi-object spectroscopic survey with moderate spectral and spatial res...

  11. Storytelling in Projects

    DEFF Research Database (Denmark)

    Munk-Madsen, Andreas; Andersen, Peter Bøgh

    2006-01-01

    project managers should not only be concerned with project plans, but also with project stories. In this paper we explore some basic principles for transforming project plans into appealing stories. We discuss what may happen to stories once they are released into public space. And we illustrate how......Plans and stories are two different ways of communicating about projects. Project plans are formalized descriptions, primarily supporting coordination. Project stories are accounts whose primary function is emotional appeal. Project stories influence the projects’ chances of success. Therefore...... the possibilities of telling favorable stories may have repercussions on the project planning....

  12. Managing projects using a project management approach

    Directory of Open Access Journals (Sweden)

    Marko D. Andrejić

    2011-04-01

    Full Text Available Modern management theory treats all complex tasks and duties like projects and make these projects possible to be managed by a particular organizational-management concept in order to achieve a goal effectively. A large number of jobs and tasks performed in the system of defense or for defense purposes have the characteristics of projects. Project management is both a skill and a science of monitoring human, material, financial, energy and other resources to achieve required objectives within the given limits: deadlines, time, budget, possibility of realization and the satisfaction of the interests of all project participants. Project management is a traditional area of applied (or functional management focused on managing complex and uncertain situations with defined goals. Introduction In conditions of rapid change and high uncertainty, only adaptive organizations survive, i. e. those that are able not only to react quickly to changes but also to proactively take advantage of changes. Development of project management The biggest influence on the development of the area had complex jobs within the engineering profession. In parallel with the traditional approach new approaches began to develop, while the traditional one still remained in use. Contrary to the traditional engineering approach, a dynamic model first developed in order to respond to demands for greater control of costs. Project management Project management is a skill and knowledge of human and material resources to achieve set objectives within prescribed limits: deadlines, time, budget, possibility of realization, and the satisfaction of all participants in the project. In order to realize a project effectively, it is necessary to manage it rationally. Planning and project management A project plan is a document that allows all team members insight on where to go, when to start and when to arrive, what is necessary to be done in order to achieve the project objectives and what

  13. Capital projects coordination

    Directory of Open Access Journals (Sweden)

    Zubović Jovan

    2004-01-01

    Full Text Available This paper looks at the difficulties of managing modem capital projects and endeavors to reduce the complexities to simpler and more understandable terms. It examines the project environment, defines project management and discusses points of difference from traditional management. In the second part of the paper are presented fundamentals for project success for different types of projects.

  14. Integrated Project Management System description. [UMTRAP Project

    Energy Technology Data Exchange (ETDEWEB)

    1987-03-01

    The Uranium Mill Tailings Remedial Action (UMTRA) Project is a Department of Energy (DOE) designated Major System Acquisition (MSA). To execute and manage the Project mission successfully and to comply with the MSA requirements, the UMTRA Project Office ( Project Office'') has implemented and operates an Integrated Project Management System (IPMS). The Project Office is assisted by the Technical Assistance Contractor's (TAC) Project Integration and Control (PIC) Group in system operation. Each participant, in turn, provides critical input to system operation and reporting requirements. The IPMS provides a uniform structured approach for integrating the work of Project participants. It serves as a tool for planning and control, workload management, performance measurement, and specialized reporting within a standardized format. This system description presents the guidance for its operation. Appendices 1 and 2 contain definitions of commonly used terms and abbreviations and acronyms, respectively. 17 figs., 5 tabs.

  15. From project management to project leadership

    NARCIS (Netherlands)

    F. Braun; M. Avital

    2010-01-01

    It is virtually a truism that good leadership practices can help project managers with attaining the desired project outcome. However, a better understanding of which leadership practices enable project managers to be more effective warrants further investigation. Subsequently, in this study, we inv

  16. Managing Projects for Change: Contextualised Project Management

    Science.gov (United States)

    Tynan, Belinda; Adlington, Rachael; Stewart, Cherry; Vale, Deborah; Sims, Rod; Shanahan, Peter

    2010-01-01

    This paper will detail three projects which focussed on enhancing online learning at a large Australian distance education University within a School of Business, School of Health and School of Education. Each project had special funding and took quite distinctive project management approaches, which reflect the desire to embed innovation and…

  17. From project management to project leadership

    NARCIS (Netherlands)

    Braun, F.; Avital, M.

    2010-01-01

    It is virtually a truism that good leadership practices can help project managers with attaining the desired project outcome. However, a better understanding of which leadership practices enable project managers to be more effective warrants further investigation. Subsequently, in this study, we

  18. Microsoft Project 2007 bible

    National Research Council Canada - National Science Library

    Marmel, Elaine J

    2007-01-01

    "Take control of your projects with this in-depth guide Whether you're managing a project for a small team or supervising a corporate assignment involving hundreds, the power of Microsoft Project 2007...

  19. Information technology project management

    National Research Council Canada - National Science Library

    Schwalbe, Kathy

    2014-01-01

    ... (IT) projects that extend well beyond standard project management requirements. No book offers more up-to-the minute insights and software tools for IT project management success, including updates that reflect the latest PMBOKʼ...

  20. Information technology project management

    National Research Council Canada - National Science Library

    Schwalbe, Kathy

    2014-01-01

    ... (IT) projects that extend well beyond standard project management requirements. No book offers more up-to-the minute insights and software tools for IT project management success, including updates that reflect the latest PMBOK...

  1. Web Project Management

    OpenAIRE

    Suralkar, Sunita; Joshi, Nilambari; Meshram, B B

    2013-01-01

    This paper describes about the need for Web project management, fundamentals of project management for web projects: what it is, why projects go wrong, and what's different about web projects. We also discuss Cost Estimation Techniques based on Size Metrics. Though Web project development is similar to traditional software development applications, the special characteristics of Web Application development requires adaption of many software engineering approaches or even development of comple...

  2. MANAGING MULTICULTURAL PROJECT TEAMS

    OpenAIRE

    Scarlat, Cezar; Carmen-Laura ZARZU; Adriana PRODAN

    2014-01-01

    The article is based on literature review and authors’ own recent experience in managing multicultural project teams, in international environment. This comparative study considers two groups of projects: technical assistance (TA) projects versus information technology (IT) projects. The aim is to explore the size and structure of the project teams – according to the team formation and its lifecycle, and to identify some distinctive attributes of the project teams – both similarities and diff...

  3. Web Project Management

    OpenAIRE

    2013-01-01

    This paper describes about the need for Web project management, fundamentals of project management for web projects: what it is, why projects go wrong, and what's different about web projects. We also discuss Cost Estimation Techniques based on Size Metrics. Though Web project development is similar to traditional software development applications, the special characteristics of Web Application development requires adaption of many software engineering approaches or even development of comple...

  4. Report to Congress on the U.S. Department of Energy`s Environmental Management Science Program: Research funded and its linkages to environmental cleanup problems, and high out-year cost environmental management project descriptions. Volume 3 of 3 -- Appendix C

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-04-01

    The Department of Energy`s Environmental Management Science Program (EMSP) serves as a catalyst for the application of scientific discoveries to the development and deployment of technologies that will lead to reduction of the costs and risks associated with cleaning up the nation`s nuclear complex. Appendix C provides details about each of the Department`s 82 high cost projects and lists the EMSP research awards with potential to impact each of these projects. The high cost projects listed are those having costs greater than $50 million in constant 1998 dollars from the year 2007 and beyond, based on the March 1998 Accelerating Cleanup: Paths to Closure Draft data, and having costs of quantities of material associated with an environmental management problem area. The high cost project information is grouped by operations office and organized by site and project code. Each operations office section begins with a list of research needs associated with that operations office. Potentially related research awards are listed by problem area in the Index of Research Awards by Environmental Management Problem Area, which can be found at the end of appendices B and C. For projects that address high risks to the public, workers, or the environment, refer also the Health/Ecology/Risk problem area awards. Research needs are programmatic or technical challenges that may benefit from knowledge gained through basic research.

  5. Enhancing Effectiveness of EMSP Projects Through Strong Connections to Site Problems

    Energy Technology Data Exchange (ETDEWEB)

    Guillen, D. P.; Josephson, G. B.

    2002-02-25

    The Environmental Management Science Program (EMSP) funds basic science research that will lead to reduced remediation cost, schedule, technical uncertainties, and risk for DOE's environmental clean up. The Tanks Focus Area (TFA) has partnered with EMSP to accomplish those same objectives for DOE's largest and most expensive remediation effort--to retrieve and immobilize the highly radioactive wastes that are our nation's chief nuclear defense program legacy. TFA has been tasked to facilitate success of the EMSP investment. The key for EMSP projects to contribute to this remediation effort is communication. First, scientists need to understand much more about how their scientific results would be used than they could ever learn from the original EMSP solicitation or by reading the referenced DOE needs statements. Second, the scientists' results must be communicated to the site problem holders in a usable form and in a timely manner such that important information gaps can still be filled by the EMSP project. Research results can be used in a variety of ways besides deployment of new hardware or a new process. When results are USED the site problem holders become ''users''. The important aspect that research results are to be used is captured in the TFA lexicon for their clients, the DOE sites--''users''. This paper will show, through several examples, significant contributions EMSP scientists have made to solving DOE's high-level waste challenges through direct and enhanced communication with TFA and site users.

  6. USAID Anticorruption Projects Database

    Data.gov (United States)

    US Agency for International Development — The Anticorruption Projects Database (Database) includes information about USAID projects with anticorruption interventions implemented worldwide between 2007 and...

  7. Project 2010 For Dummies

    CERN Document Server

    Muir, Nancy C

    2010-01-01

    A friendly reference guide to Microsoft Project, the leading enterprise project management software. As project management software, Microsoft Project allows you to oversee your business activities effectively. You can manage resources, share project info, perform modeling and scenario analysis, and standardize reporting processes. This easy-to-understand guide is completely updated to cover the latest changes and newest enhancements to Project 2010 and shows you how to get Project 2010 to work for you. After an introduction to basic project management concepts, you'll discover the mechanics o

  8. Storytelling in Projects

    DEFF Research Database (Denmark)

    Munk-Madsen, Andreas; Andersen, Peter Bøgh

    2006-01-01

    project managers should not only be concerned with project plans, but also with project stories. In this paper we explore some basic principles for transforming project plans into appealing stories. We discuss what may happen to stories once they are released into public space. And we illustrate how...

  9. Standardizing Healthcare Projects

    NARCIS (Netherlands)

    Does, R.J.M.M.; Vermaat, T.M.B.; de Koning, H.; Bisgaard, S.; van den Heuvel, J.

    2006-01-01

    The project oriented deployment of teams to solve specific welldefined chronic problems is core to Six Sigma. Indeed, this capitalizes on J.M. Juran's wise observation that "quality problems are solved project by project and in no other way." It is well-known that poor project definitions and early

  10. IT Project Selection

    DEFF Research Database (Denmark)

    Pedersen, Keld

    2016-01-01

    Selecting the right IT projects is increasingly important for many organizations. Project portfolio managers play a key role during project selection, but even though they have a great impact on the selection process, we have little knowledge about how they decide which projects to recommend for ...

  11. Introduction to the Project

    DEFF Research Database (Denmark)

    Kuhn, Johan M.; Malchow-Møller, Nikolaj; Sørensen, Anders

    In this note a short introduction to the project “Employment Effects of Entrepreneurs” is presented. First, we describe the purpose of the project; second, we present the background; third, we briefly describe the three papers that constitute the output of the project, and fourth, we discuss two...... important qualifications for the understanding of the contributions and results established in the project....

  12. Project Decision Chain

    DEFF Research Database (Denmark)

    Rolstadås, Asbjørn; Pinto, Jeffrey K.; Falster, Peter

    2015-01-01

    To add value to project performance and help obtain project success, a new framework for decision making in projects is defined. It introduces the project decision chain inspired by the supply chain thinking in the manufacturing sector and uses three types of decisions: authorization, selection...

  13. Projects as value constellations

    DEFF Research Database (Denmark)

    Laursen, Markus

    Creating value has been outlined as very central to projects applying the organizational perspective to projects. It has been suggested that value is created in value constellations or project networks, where actors work together to create value. However, research on the value creation process...... in value constellations is scarce, and through an exploratory study of two project networks in a cultural setting we investigate how value is created in value constellations. We outline how each project may be a distinct type of value constellation, one project creates value for the partners of the network...... as a consortium, and the project creates value primarily for others as a facilitator....

  14. Modern project-management

    CERN Document Server

    CERN. Geneva

    2003-01-01

    This lecture will focus on the following issues: - The current state of the art in Project Management, especially the integration of Project Management with general management activities, and the integrated view of resources allocation. - Overview of the project life cycle, the phases and the deliverables - Necessity and limits of planning in a research environment - Organizational aspects of the projects the roles of the stakeholders - How to get the resources when they are needed - Risk Management in Projects - Earned value - How to keep a project on track (schedule and budget) - Management of the suppliers - Closing of the project

  15. IT Project Selection

    DEFF Research Database (Denmark)

    Pedersen, Keld

    2016-01-01

    Selecting the right IT projects is increasingly important for many organizations. Project portfolio managers play a key role during project selection, but even though they have a great impact on the selection process, we have little knowledge about how they decide which projects to recommend...... the development of methods that better fit current practice. The study is based on naturalistic decision-making theory and interviews with experienced project portfolio managers who, when selecting projects, primarily rely on political skills, experience and personal networks rather than on formal IT project...

  16. Project stakeholder management

    CERN Document Server

    Eskerod, Pernille

    2013-01-01

    Carrying out a project as planned is not a guarantee for success. Projects may fail because project management does not take the requirements, wishes and concerns of stakeholders sufficiently into account. Projects can only be successful though contributions from stakeholders. And in the end, it is the stakeholders that evaluate whether they find that the project is a success. To manage stakeholders effectively, you need to know your stakeholders, their behaviours and attitudes towards the project. In Project Stakeholder Management, the authors give guidance on how to adopt an analytical and s

  17. Introduction to the Project

    DEFF Research Database (Denmark)

    Kuhn, Johan M.; Malchow-Møller, Nikolaj; Sørensen, Anders

    In this note a short introduction to the project “Employment Effects of Entrepreneurs” is presented. First, we describe the purpose of the project; second, we present the background; third, we briefly describe the three papers that constitute the output of the project, and fourth, we discuss two ...... important qualifications for the understanding of the contributions and results established in the project.......In this note a short introduction to the project “Employment Effects of Entrepreneurs” is presented. First, we describe the purpose of the project; second, we present the background; third, we briefly describe the three papers that constitute the output of the project, and fourth, we discuss two...

  18. Submarine Combat Systems Engineering Project Capstone Project

    Science.gov (United States)

    2011-06-06

    Combat Systems Engineering Project Capstone Project by John Becker Denman Sweetman Shaun Cookinham Mark Wasilewski Shawn Goode Samuel D...This report was prepared by: John Becker Denman Sweetman Shaun Cookinham Mark Wasilewski Shawn Goode Samuel D. Winograd David Rhodes...ELEMENT NUMBER 6. AUTHOR(S) John Becker, Shaun Cookinham, Shawn Goode, David Rhodes 5d. PROJECT NUMBER Mark Wasilewski , Samuel Winograd 5e. TASK

  19. Project Phase Dependent Configuration of Project Management Information Systems

    OpenAIRE

    Bērziša, S; Grabis, J.

    2012-01-01

    Project management information systems ensure the collection and display of project information. The project information changes depend upon the project environment. According to project environment and requirements, the configuration of project management information system is ensured by means of an approach to configuration of project management information systems. However, topicality of information and access to it change during the project life cycle depending upo...

  20. Methodologies of Project Management

    Directory of Open Access Journals (Sweden)

    Wojciech Macek

    2011-07-01

    Full Text Available This paper presents comparison of three most popular project management standardsbelonging to a wider group of models (for example, PMBOK, Prince 2, CMMI, ISO 10006,BS 6079, IPMA Competence Baseline, European Commission Project Cycle ManagementGuidelines. The author discusses methods of project management according to PMBoK,Prince 2 and ISO 10006, some chosen criteria and fields of knowledge, such as generalregulations of standards, project range management, resources management, and processesconnected with risk, systems of project quality management.

  1. Project delivery system (PDS)

    CERN Document Server

    2001-01-01

    As business environments become increasingly competitive, companies seek more comprehensive solutions to the delivery of their projects. "Project Delivery System: Fourth Edition" describes the process-driven project delivery systems which incorporates the best practices from Total Quality and is aligned with the Project Management Institute and ISO Quality Standards is the means by which projects are consistently and efficiently planned, executed and completed to the satisfaction of clients and customers.

  2. A PROJECT WITHIN MICROSOFT PROJECT 2007

    Directory of Open Access Journals (Sweden)

    Emil COSMA

    2009-10-01

    Full Text Available The main purpose of this article is to emphasize the innumerable advantages of the Microsoft Project 2007 projecting environment that a project manager could benefit of. More exactly, Project Management stands for a function that is recognized within the majority of domains. A project is defined as “a temporary effort made for creating a product or a unique service”. A projects’ administrative programme within an informational system (such as Microsoft Project, Primavera Planner represents a “database that is in concordance with time”. It should help proceeding the required operations and, at the same time, to look and behave the same way other frequently utilized productive programmes. It keeps accounts of all information regarding the job requests, period and the project’s needed resources and visualizes the project’s plan in standard, well-defined formats, organizes the activities and resources consistently and efficiently,shares information regarding the project with all persons involved in an intranet or Internet network, and communicates efficiently with the resources and other involved persons, permitting at the same time the project manager to take the final control/decision as his/her responsibility.

  3. Overview about project planning

    Directory of Open Access Journals (Sweden)

    Catalin Drob

    2012-12-01

    Full Text Available The purpose of this article is to present the main aspects regarding project planning. This study is generally based on the fourth edition of the Guide to the Project Management Body of Knowledge (PMBOK Guide developed by the Project Management Institute (PMI in 2008. According to this edition of PMBOK, project planning involves a group of processes required to establish the scope of the project, refine the objectives, and define the actions that must be undertaken to attain the objectives of the project.

  4. Project management case studies

    CERN Document Server

    Kerzner, Harold R

    2013-01-01

    A new edition of the most popular book of project management case studies, expanded to include more than 100 cases plus a ""super case"" on the Iridium Project Case studies are an important part of project management education and training. This Fourth Edition of Harold Kerzner''s Project Management Case Studies features a number of new cases covering value measurement in project management. Also included is the well-received ""super case,"" which covers all aspects of project management and may be used as a capstone for a course. This new edition:Contains 100-plus case studies drawn from re

  5. Information systems project management

    CERN Document Server

    Olson, David

    2014-01-01

    Information Systems Project Management addresses project management in the context of information systems. It deals with general project management principles, with focus on the special characteristics of information systems. It is based on an earlier text, but shortened to focus on essential project management elements.This updated version presents various statistics indicating endemic problems in completing information system projects on time, within budget, at designed functionality. While successful completion of an information systems project is a challenge, there are some things that ca

  6. Project report - an overview of the project and experiences with project management

    DEFF Research Database (Denmark)

    Jørgensen, Michael Søgaard; Mikkelsen, Bent Egberg

    1996-01-01

    A collection of the project planning and the experiences with project management from the Catering 2000 project.As appendieces articles etc. from journals, newspapers etc. about the project.......A collection of the project planning and the experiences with project management from the Catering 2000 project.As appendieces articles etc. from journals, newspapers etc. about the project....

  7. Project Portfolio Management Software

    OpenAIRE

    Paul POCATILU

    2006-01-01

    In order to design a methodology for the development of project portfolio management (PPM) applications, the existing applications have to be studied. This paper describes the main characteristics of the leading project portfolio management software applications.

  8. Project Portfolio Management Software

    Directory of Open Access Journals (Sweden)

    Paul POCATILU

    2006-01-01

    Full Text Available In order to design a methodology for the development of project portfolio management (PPM applications, the existing applications have to be studied. This paper describes the main characteristics of the leading project portfolio management software applications.

  9. Project Weather and Water.

    Science.gov (United States)

    Hansen, Pal J. Kirkeby

    2000-01-01

    Introduces Project Weather and Water with the goal of developing and testing ideas of how to implement weather topics and water physics in an integrated way. Discusses teacher preparation, implementation, and evaluation of this project. (ASK)

  10. Farm Bill project report

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This report briefly summarizes projects completed and projects not completed with signed WEA's. Additionally, a table sharing the results of 1990 Canada good nesting...

  11. Earned value project management

    CERN Document Server

    Fleming, Quentin W

    2010-01-01

    Organizations that follow the principles of good Earned Value Management (EVM) create an environment that allows teams to successfully operate and thrive ? even in the face of challenges that could negatively impact their projects. Earned Value Project Management (EVPM) is a methodology used to measure and communicate the real physical progress of a project taking into account the work completed, the time taken and the costs incurred to complete that work. As a result, EVPM allows more educated and effective management decision-making, which helps evaluate and control project risk by measuring project progress in monetary terms. In the first two editions of Earned Value Project Management, Quentin W. Fleming and Joel M. Koppelman provided guidance for project management practitioners already familiar with EVPM, was well as those who were new to the use of this technique. The third edition expanded the information available on of EVPM for medium and smaller projects while still being relevant for larger projec...

  12. Successful project management

    CERN Document Server

    Young, Trevor L

    2016-01-01

    Successful Project Management, 5th edition, is an essential guide for anyone who wants to improve the success rate of their projects. It will help managers to maintain a balance between the demands of the customer, the project, the team and the organization. Covering the more technical aspects of a project from start to completion it contains practised and tested techniques, covering project conception and start-up, how to manage stake holders, effective risk management, project planning and launch and execution. Also including a brand new glossary of key terms, it provides help with evaluating your project as well as practical checklists and templates to ensure success for any ambitious project manager. With over one million copies sold, the hugely popular Creating Success series covers a wide variety of topic, with the latest editions including new chapters such as Tough Conversations and Treating People Right. This indispensable business skills collection is suited to a variety of roles, from someone look...

  13. CHP Project Development

    Science.gov (United States)

    Access information and tools to support the CHP project development process, including identifying if your facility is a good fit for CHP, the steps involved with CHP project development, and policies and incentives supportive of CHP.

  14. Collaborative Contracting in Projects

    NARCIS (Netherlands)

    Suprapto, M.

    2016-01-01

    Project practitioners have increasingly recognized the importance of collaborative relationships to ensure successful executions of projects. However, the ability to sustain and consistenly drive real collaborative attitudes and behavior for achieving the desired outcomes remains of enduring practic

  15. Collaborative Contracting in Projects

    NARCIS (Netherlands)

    Suprapto, M.

    2016-01-01

    Project practitioners have increasingly recognized the importance of collaborative relationships to ensure successful executions of projects. However, the ability to sustain and consistenly drive real collaborative attitudes and behavior for achieving the desired outcomes remains of enduring

  16. Project Tasks in Robotics

    DEFF Research Database (Denmark)

    Sørensen, Torben; Hansen, Poul Erik

    1998-01-01

    Description of the compulsary project tasks to be carried out as a part of DTU course 72238 Robotics......Description of the compulsary project tasks to be carried out as a part of DTU course 72238 Robotics...

  17. Architectural project and research

    DEFF Research Database (Denmark)

    Lotz, Katrine

    2005-01-01

    Discussion of criterias for research including the researchers or designers own project as theme.......Discussion of criterias for research including the researchers or designers own project as theme....

  18. Improved Mass Spectrometer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Improved Mass Spectrometer project will develop system requirements and analyze the path to space qualification.   The results of this project...

  19. The Alzheimer's Project

    Science.gov (United States)

    ... Navigation Bar Home Current Issue Past Issues The Alzheimer's Project Past Issues / Spring 2009 Table of Contents ... of this page please turn Javascript on. The Alzheimer's Project A 4-Part Documentary Series Starting May ...

  20. The "Old Dogs" Project.

    Science.gov (United States)

    Ehrlich, Robert; And Others

    1997-01-01

    Describes a low cost, easily emulated project designed to improve classroom teaching methods. Discusses the benefits of peer evaluation and lists the criteria used for selecting participants. Highlights lessons learned from the project. (JRH)

  1. MANAGING MULTICULTURAL PROJECT TEAMS

    Directory of Open Access Journals (Sweden)

    Cezar SCARLAT

    2014-06-01

    Full Text Available The article is based on literature review and authors’ own recent experience in managing multicultural project teams, in international environment. This comparative study considers two groups of projects: technical assistance (TA projects versus information technology (IT projects. The aim is to explore the size and structure of the project teams – according to the team formation and its lifecycle, and to identify some distinctive attributes of the project teams – both similarities and differences between the above mentioned types of projects. Distinct focus of the research is on the multiculturalism of the project teams: how the cultural background of the team members influences the team performance and team management. Besides the results of the study are the managerial implications: how the team managers could soften the cultural clash, and avoid inter-cultural misunderstandings and even conflicts – in order to get a better performance. Some practical examples are provided as well.

  2. RadWorks Project

    Data.gov (United States)

    National Aeronautics and Space Administration — For the first two years of the project (FY12-13), the RadWorks project has consisted of two top-level elements. The first element involved the prototype and...

  3. Pro web project management

    CERN Document Server

    Emond, Justin

    2012-01-01

    Caters to an under-served niche market of small and medium-sized web consulting projects Eases people's project management pain Uses a clear, simple, and accessible style that eschews theory and hates walls of text

  4. BioProject

    Data.gov (United States)

    U.S. Department of Health & Human Services — The BioProject database provides an organizational framework to access information about research projects with links to data that have been or will be deposited...

  5. Capital Projects Application (CPA)

    Data.gov (United States)

    General Services Administration — Capital Projects application (CPA) provides users with the ability to maintain project related financial data for Budget Activity (BA) 51, 55, 64, 01, 02, 03, 04....

  6. Targeting Newlands Project acquisitions

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This report is about the effects of the Newlands Project in Nevada and the ways in which the Project will impact water available for wetlands and irrigation. The...

  7. Architectural project and research

    DEFF Research Database (Denmark)

    Lotz, Katrine

    2005-01-01

    Discussion of criterias for research including the researchers or designers own project as theme.......Discussion of criterias for research including the researchers or designers own project as theme....

  8. El Dorado Micellar-Polymer Demonstration Project. Second annual report, July 1975--May 1976

    Energy Technology Data Exchange (ETDEWEB)

    Rosenwald, G.W. (ed.)

    1976-07-01

    Laboratory oil displacement tests were conducted using Shell Oil Co. and Union Oil Co. chemical formulations in both Berea and El Dorado Admire Sandstone cores. Total relative mobility of the oil-water bank created during chemical flooding was measured in Admire Sandstone cores. The values ranged from 0.018 to 0.065 reciprocal centipoise. Four observation wells were drilled, cored, and logged during the year. They were cased with fiberglass and are now being used to monitor fluid properties. A tracer test was conducted by injection of chemical tracers into each of the 18 injection wells. Results indicate that there is no gross channeling in the reservoir. The same conclusion was drawn from results of interference tests. Performance forecasting was utilized to show that maintaining the bottom-hole injection pressures at 400 psia and the producing pressures at 30 psia would increase throughput rates and result in acceptable project life for the 6.4-acre, five-spot patterns. Injection well rates relative to the central injector were computed. These rates will be used as a guide for the operation of injection wells. This plan corresponds to operation at constant bottom-hole pressures for a homogeneous reservoir of uniform thickness. Construction of the fresh water system and injection plant was completed. The injection plant has performed satisfactorily. Injection of pretreatment fluid was started in both patterns on November 18, 1975.Severe loss of injectivity was experienced during the first week of injection. Several likely causes were identified and corrective actions taken. More moderate injectivity problems have continued throughout this reporting period. Additional preventive measures have been undertaken to improve the quality of injected fluids. A procedure was developed to stimulate and clean-up wells damaged by the injection fluid. A preliminary evaluation indicates that combination solvent-acid treatments will increase injection rates to the desired level.

  9. Integrated project support environments the ASPECT project

    CERN Document Server

    Brown, Alan W

    1991-01-01

    A major part of software engineering developments involve the use of computing tools which facilitate the management, maintenance, security, and building of long-scale software engineer projects. Consequently, there have been a proliferation of CASE tools and IPSES. This book looks at IPSES in general and the ASPECT project in particular, providing design and implementation details, as well as locating ASPECT in IPSE developments.Survey of integrated project support environments for more efficient software engineering**Description of a large scale IPSE--ASPECT**Evaluation of formal methods in

  10. Agile & Distributed Project Management

    DEFF Research Database (Denmark)

    Pries-Heje, Jan; Pries-Heje, Lene

    2011-01-01

    Scrum has gained surprising momentum as an agile IS project management approach. An obvious question is why Scrum is so useful? To answer that question we carried out a longitudinal study of a distributed project using Scrum. We analyzed the data using coding and categorisation and three carefull...... and coordination mechanisms by allowing both local and global articulation of work in the project. That is why Scrum is especially useful for distributed IS project management and teamwork....

  11. Project Management Performance Drivers

    OpenAIRE

    Ra’ad, Mohammed A.; Najdawi, Mohammad K.

    2010-01-01

    The practice of project management has gained enormous importance over the past several years in various business industries. “In industries as diverse as pharmaceuticals, software, and aerospace, projects drive business” (Wheatley). This gain of importance can be attributed to the magnitude of the impact project performance results in terms of time, cost, and scope have over the project performing entity. “On the basis of data released by the Bureau of Economic Analysis, part of the US De...

  12. Methodologies of project management

    OpenAIRE

    Macek, Wojciech

    2010-01-01

    This paper presents comparison of three most popular project management standards belonging to a wider group of models (for example, PMBOK, Prince 2, CMMI, ISO 10006, BS 6079, IPMA Competence Baseline, European Commission Project Cycle Management Guidelines). The author discusses methods of project management according to PMBoK, Prince 2 and ISO 10006, some chosen criteria and fields of knowledge, such as general regulations of standards, project range management, resources management, and pr...

  13. Agile & Distributed Project Management

    DEFF Research Database (Denmark)

    Pries-Heje, Jan; Pries-Heje, Lene

    2011-01-01

    Scrum has gained surprising momentum as an agile IS project management approach. An obvious question is why Scrum is so useful? To answer that question we carried out a longitudinal study of a distributed project using Scrum. We analyzed the data using coding and categorisation and three carefully...... and coordination mechanisms by allowing both local and global articulation of work in the project. That is why Scrum is especially useful for distributed IS project management and teamwork....

  14. The USE Project

    DEFF Research Database (Denmark)

    Frøkjær, E.; Hornbæk, K.; Høegh, Rune Thaarup;

    2006-01-01

    This paper provides experience from activities in the USE project. The USE project is a research project that aims at bridging the gap between usability evaluation and user interface design. It is conducted from 2005 to 2008 in collaboration between researchers from Aalborg University...

  15. Building Project Competence

    DEFF Research Database (Denmark)

    Pemsel, Sofia; Wiewiora, Anna

    This research investigates the development of project competence, and particularly, three related dynamic capabilities (shifting, adapting, leveraging) that contribute to project competence development. In doing so, we make use of the emerging literature on knowledge governance and theorize how k...... of dynamic capability building promoting project competence development....

  16. Semi-projective modules

    Directory of Open Access Journals (Sweden)

    D. Döman

    1984-03-01

    Full Text Available It is well-known that the submodules of a projective module need not be projective. In this article we investigate a certain projectivity which is preserved under the taking of submodules. This property is used to characterize hereditary rings and QF rings.

  17. Projection: A Bibliography.

    Science.gov (United States)

    Pedrini, D. T.; Pedrini, Bonnie C.

    Sigmund Freud and his associates did much clinical work with the dynamic of projection, especially with regard to paranoid symptoms and syndromes. Much experimental work has also been done with projection. Sears evaluated the results of some of those studies. Murstein and Pryer sub-classified projection and reviewed typical studies. The…

  18. The Sidewalk Project

    Science.gov (United States)

    Church, William

    2005-01-01

    In this article, the author features "the sidewalk project" in Littleton High School. The sidewalk project is a collaboration of more than 40 high school physics students, 10 local mentors, and a few regional and national organizations who worked together to invent a way to heat a sidewalk with an alternative energy source. The project, which…

  19. The USE Project

    DEFF Research Database (Denmark)

    Frøkjær, E.; Hornbæk, K.; Høegh, Rune Thaarup

    2006-01-01

    This paper provides experience from activities in the USE project. The USE project is a research project that aims at bridging the gap between usability evaluation and user interface design. It is conducted from 2005 to 2008 in collaboration between researchers from Aalborg University...

  20. The Llama Project.

    Science.gov (United States)

    Ganzel, Candy; Stuglik, Jan

    2003-01-01

    At a suburban Indiana elementary school, the Project Approach serves as the basis of the curriculum in all Kindergarten classrooms. The four classes of 5- and 6-year-old children at this school chose to study llamas. This article discusses how the project evolved, describes the three phases of the project, and provides teachers' reflections on the…