Spiro K. Antiochos Receives 2013 John Adam Fleming Medal: Citation

Science.gov (United States)

Klimchuk, James A.

2014-01-01

The John Adam Fleming Medal is awarded for "original research and technical leadership in geomagnetism, atmospheric electricity, aeronomy, space physics, and related sciences." Originality and technical leadership are exactly the characteristics that distinguish the research of Spiro K. Antiochos. Spiro possesses a truly unique combination of physical insight, creativity, and mastery of the concepts and mathematical and numerical tools of space physics. These talents have allowed him to develop completely original theories for major observational problems and to test and refine those theories using sophisticated numerical simulation codes that he himself helped to develop. Spiro's physical insight is especially impressive. He has an uncanny ability to identify the fundamental aspects of complex problems and to see physical connections where others do not. This can sometimes involve ideas that may initially seem counterintuitive to those with less creativity. Many of Spiro's revolutionary advances have opened up whole new areas of study and shaped the course of space physics. Examples include the breakout model for coronal mass ejections (CMEs), the S-web model for the slow solar wind, and the thermal nonequilibrium model for solar prominences. The breakout model is of special significance to AGU as it strives to promote science for the betterment of humanity. CMEs are enormous explosions on the Sun that can have major "space weather" impacts here on Earth. They affect technologies ranging from communication and navigation systems to electrical power grids. Breakout is the leading theory for why CMEs occur and may one day be the foundation for more accurate space weather forecasting.

Study on optoelectronic properties of Spiro-CN for developing an efficient OLED

Science.gov (United States)

Mishra, Ashok Kumar

2018-05-01

There are a class of organic molecules and polymers which exhibit semiconductor behavior because of nearly free conjugate π-electrons. Hopping of these electrons in molecules forms different excited singlet and triplet states named as excitons. Some of these organic molecules can be set to emit photons by triplet-singlet excitonic transition via a process called Thermally Activated Delayed Fluorescence (TADF) which is exploited for designing the Organic Light Emitting diode (OLED.) Spiro-CN (spirobifluorene skeletons) Spiro is one of these reported noble metal-free TADF molecules which offers unique optical and electronic properties arising from the efficient transition and reverse intersystem crossing between the lowest singlet (S) and triplet (T) excited states. Its ability to harvest triplet excitons for fluorescence through facilitated reverse intersystem crossing (T→S) could directly impact their properties and performances, which is attractive for a wide variety of low-cost optoelectronic device. In the present study, the Spiro-CN compounds have been taken up for the investigation of various optoelectronic properties including the thermally activated delayed fluorescence (TADF) by using the Koopmans Method and Density Functional Theory. The present study discusses the utility of the Spiro-CN organic semiconductor as a suitable TADF material essential for developing an efficient Organic Light Emitting Diode (OLED).

29 CFR 1917.119 - Portable ladders.

Science.gov (United States)

2010-07-01

... Requirements for Portable Reinforced Plastic Ladders (d) Standards for job-made portable ladders. Job-made... usage. (1) Ladders made by fastening rungs or devices across a single rail are prohibited. (2) Ladders...

Shelf life stability comparison in air for solution processed pristine PDPP3T polymer and doped spiro-OMeTAD as hole transport layer for perovskite solar cell

Directory of Open Access Journals (Sweden)

Ashish Dubey

2016-06-01

Full Text Available This data in brief includes forward and reverse scanned current density–voltage (J–V characteristics of perovskite solar cells with PDPP3T and spiro-OMeTAD as HTL, stability testing conditions of perovskite solar cell shelf life in air for both PDPP3T and spiro-OMeTAD as HTL as per the description in Ref. [1], and individual J–V performance parameters acquired with increasing time exposed in ambient air are shown for both type of devices using PDPP3T and spiro-OMeTAD as HTL. The data collected in this study compares the device stability with time for both PDPP3T and spiro-OMeTAD based perovskite solar cells and is directly related to our research article “solution processed pristine PDPP3T polymer as hole transport layer for efficient perovskite solar cells with slower degradation” [2].

Antibacterial properties of 3 H-spiro[1-benzofuran-2,1'-cyclohexane] derivatives from Heliotropium filifolium.

Science.gov (United States)

Urzúa, Alejandro; Echeverría, Javier; Rezende, Marcos C; Wilkens, Marcela

2008-10-01

A re-examination of cuticular components of Heliotropium filifolium allowed the isolation of four new compounds: 3'-hydroxy-2',2',6'-trimethyl-3H-spiro[1-benzo-furan-2,1'-cyclohexane]-5-carboxylic acid(2), methyl 3'-acetyloxy-2',2',6'-trimethyl-3H-spiro[1-benzofuran-2,1'-cyclohexane]-5-carboxylate (3), methyl 3'-isopentanoyloxy-2',2',6'-trimethyl-3H-spiro[1-benzofuran-2,1'-cyclohexane]-5-carboxylate (4) and methyl 3'-benzoyloxy-2',2',6'-trimethyl-3H-spiro[1-benzofuran-2,1'-cyclohexane]-5-carboxylate (5).Compounds 2-5 were identified by their spectroscopic analogies with filifolinol (1), and their structures confirmed by chemical correlation with 1. The antimicrobial properties of the compounds were tested against Gram positive and Gram negative bacteria. Some of them proved to be active against Gram positive, but inactive against Gram negative bacteria. In searching for structure-activity relationships from the obtained MIC values, lipophilicity was shown to be an important variable.

Synthesis of Racemic β-Chamigrene, a Spiro[5.5]undecane Sequiterpene

Directory of Open Access Journals (Sweden)

Simen Antonsen

2014-12-01

Full Text Available The present paper describes a total synthesis of racemic β-chamigrene (1, a sesquiterpene with a spiro[5.5]undecane carbon framework. Compared with previously reported β-chamigrene syntheses, we were able to reduce the total number of reaction steps, which also resulted in a significant improvement of the overall yield. The commercially available ketone 6-methylhept-5-en-2-one was transformed by known simple procedures into 3,3-dimethyl-2-methylenecyclohexanone. This reacted with isoprene by a Diels-Alder reaction to give a spiro ketone. An olefination reaction on this compound gave the target molecule.

Microwave mediated synthesis of spiro-(indoline-isoxazolidines): mechanistic study and biological activity evaluation

DEFF Research Database (Denmark)

Raunak, R.; Kumar, Vineet; Mukherjee, Shubhasish

2005-01-01

Regioisomeric spiro-(indoline-isoxazolidines) have been synthesized in moderate yields by the cycloaddition reaction between ethyl (3-indolylidene)acetate and various substituted α,N-diphenylnitrones, using environmentally benign microwave technology. A novel concerted reaction mechanism is descr......Regioisomeric spiro-(indoline-isoxazolidines) have been synthesized in moderate yields by the cycloaddition reaction between ethyl (3-indolylidene)acetate and various substituted α,N-diphenylnitrones, using environmentally benign microwave technology. A novel concerted reaction mechanism...

Structure and stability of spiro-cyclic water clusters

Indian Academy of Sciences (India)

Administrator

Abstract. The structure and stability of spiro-cyclic water clusters containing up to 32 water molecules have been ... due to its importance in various real life systems. 1–8. High level ... It is well-known from the crystal structure data- base that the ...

Microwave Assisted Synthesis of Some New Heterocyclic Spiro-Derivatives with Potential Antimicrobial and Antioxidant Activity

Directory of Open Access Journals (Sweden)

Mohamed Mohamed Youssef

2010-12-01

Full Text Available Homophthalic anhydride reacts with different aromatic amines to produce N-substituted homophthalimides. Bromination of the latter produces 4,4-dibromo-homophthalimide derivatives that can be used as precursors for spiro-derivatives. The dibromo derivatives react with different binucleophilic reagents to produce several spiro-isoquinoline derivatives. Reaction of the dibromo derivatives with malononitrile produces dicyanomethylene derivatives which react with different binucleophiles to produce new spiro-derivatives. Structures of the newly synthesized compounds are proved using spectroscopic methods such as IR, 1H-NMR and 13C-NMR. The newly synthesized compounds were tested for their antimicrobial and antioxidant activities, showing weak or no antimicrobial activity. On the other hand select compounds showed promising antioxidant activities.

29 CFR 1915.72 - Ladders.

Science.gov (United States)

2010-07-01

...). (b) Construction of portable wood cleated ladders up to 30 feet in length. (1) Wood side rails shall... shall be at least 25/32×33/4 inches in cross section. (c) Construction of portable wood cleated ladders... split side rails, or other faulty or defective construction is prohibited. When ladders with such...

Production of monodispersed Oil-in Water Emulsion Using Crossflow-Type Silicon Microchannel Plate

Energy Technology Data Exchange (ETDEWEB)

Kawakatsu, Takahiro.; Komori, Hideaki.; Yonemoto, Toshikuni. [Tohoku University, Miyagi (Japan). Chemical Engineering Department; Nakajima, Mitsutoshi.; Kikuchi, Yuji. [National Food Research Institute, Ibaraki (Japan)

1999-04-01

A novel method for continuous productin of monodispersed oil-in-water (O/W) emulsion is developed using acrossflow-type silicaon microchannel plate. On the single crystal silicon plate, a liquid flow path for continuous phase was made, and at each side of th wall of the path an array of regular-sized slits was precisely fabricated. A flat glass plate was tightly attached on the microchannel plate to cover the top of the slits to form the array of microchannels. Regular-sized oil (triolein) droplets were generated by squeezing the oil through the microchannels into the continuous-phase water (0.3 wt% sodium lauryl sulfate solutin) flowing in the liquid path. Oil droplet size is significantly dependent on the microchannel structure, which is identified with the microchannel width, height, and the length of the terrace (a flat area at the microchannel outlet). Three types of microchannel plates having different microchannel structures generate monodispersed emulsions of different average droplet sizes, 16,20, and 48 {mu}m at the watr flow rate of 1.4x10{sup -2}mL{center_dot}min{sup -1}. For the microchannel plate which generates large droplets of 48 {mu}m, increasing the flow rate causes decreasing droplet size. However, for the microchannel plate which generates small droplets of 16 or 20 {mu}m, the size is not affected by the flow rate within the range from 1.4x10{sup -2}to 2.4 mL{center_dot}min{sup -1}. In every case, the droplet size distribution is narrow, and the geometric standard deviation is 1.03 or less. (author)

Implementability of two-qubit unitary operations over the butterfly network and the ladder network with free classical communication

Energy Technology Data Exchange (ETDEWEB)

Akibue, Seiseki [Department of Physics, Graduate School of Science, The University of Tokyo, Tokyo (Japan); Murao, Mio [Department of Physics, Graduate School of Science, The University of Tokyo, Tokyo, Japan and NanoQuine, The University of Tokyo, Tokyo (Japan)

2014-12-04

We investigate distributed implementation of two-qubit unitary operations over two primitive networks, the butterfly network and the ladder network, as a first step to apply network coding for quantum computation. By classifying two-qubit unitary operations in terms of the Kraus-Cirac number, the number of non-zero parameters describing the global part of two-qubit unitary operations, we analyze which class of two-qubit unitary operations is implementable over these networks with free classical communication. For the butterfly network, we show that two classes of two-qubit unitary operations, which contain all Clifford, controlled-unitary and matchgate operations, are implementable over the network. For the ladder network, we show that two-qubit unitary operations are implementable over the network if and only if their Kraus-Cirac number do not exceed the number of the bridges of the ladder.

Implementability of two-qubit unitary operations over the butterfly network and the ladder network with free classical communication

International Nuclear Information System (INIS)

Akibue, Seiseki; Murao, Mio

2014-01-01

We investigate distributed implementation of two-qubit unitary operations over two primitive networks, the butterfly network and the ladder network, as a first step to apply network coding for quantum computation. By classifying two-qubit unitary operations in terms of the Kraus-Cirac number, the number of non-zero parameters describing the global part of two-qubit unitary operations, we analyze which class of two-qubit unitary operations is implementable over these networks with free classical communication. For the butterfly network, we show that two classes of two-qubit unitary operations, which contain all Clifford, controlled-unitary and matchgate operations, are implementable over the network. For the ladder network, we show that two-qubit unitary operations are implementable over the network if and only if their Kraus-Cirac number do not exceed the number of the bridges of the ladder

Aerosol fabrication methods for monodisperse nanoparticles

Science.gov (United States)

Jiang, Xingmao; Brinker, C Jeffrey

2014-10-21

Exemplary embodiments provide materials and methods for forming monodisperse particles. In one embodiment, the monodisperse particles can be formed by first spraying a nanoparticle-containing dispersion into aerosol droplets and then heating the aerosol droplets in the presence of a shell precursor to form core-shell particles. By removing either the shell layer or the nanoparticle core of the core-shell particles, monodisperse nanoparticles can be formed.

Assembly procedure for the silicon pixel ladder for PHENIX silicon vertex tracker

International Nuclear Information System (INIS)

Onuki, Y.; Akiba, Y.; En'yo, H.; Fujiwara, K.; Haki, Y.; Hashimoto, K.; Ichimiya, R.; Kasai, M.; Kawashima, M.; Kurita, K.; Kurosawa, M.; Mannel, E.J.; Nakano, K.; Pak, R.; Sekimoto, M.; Sondheim, W.E.; Taketani, A.; Togawa, M.; Yamamoto, Y.

2009-01-01

The silicon vertex tracker (VTX) will be installed in the summer of 2010 to enhance the physics capabilities of the Pioneering High Energy Nuclear Interaction eXperiment (PHENIX) experiment at Brookhaven National Laboratory. The VTX consists of two types of silicon detectors: a pixel detector and a strip detector. The pixel detector consists of 30 pixel ladders placed on the two inner cylindrical layers of the VTX. The ladders are required to be assembled with high precision, however, they should be assembled in both cost and time efficient manner. We have developed an assembly bench for the ladder with several assembly fixtures and a quality assurance (Q/A) system using a 3D measurement machine. We have also developed an assembly procedure for the ladder, including a method for dispensing adhesive uniformly and encapsulation of bonding wires. The developed procedures were adopted in the assembly of the first pixel ladder and satisfy the requirements.

Nanostructured TiO2/CH3NH3PbI3 heterojunction solar cells employing spiro-OMeTAD/Co-complex as hole-transporting material

KAUST Repository

Noh, Jun Hong

2013-01-01

For using 2,2′,7,7′-tetrakis(N,N′-di-p- methoxyphenylamine)-9,9′-spirobifluorene (spiro-OMeTAD) as a hole conductor in solar cells, it is necessary to improve its charge-transport properties through electrochemical doping. With the aim of fabricating efficient mesoscopic TiO2/CH3NH3PbI3 heterojunction solar cells, we used tris[2-(1H-pyrazol-1-yl)-4-tert- butylpyridine)cobalt(iii) tris(bis(trifluoromethylsulfonyl) imide)] (FK209) as a p-dopant for spiro-OMeTAD. The mixture of spiro-OMeTAD, FK209, lithium bis(trifluoromethylsulfonyl)imide (Li-TFSI), and 4-tert-butylpyridine (TBP) exhibited significantly higher performance than mixtures of pristine spiro-OMeTAD, spiro-OMeTAD, and FK209, and spiro-OMeTAD, Li-TFSI, and TBP. Such a synergistic effect between the Co-complex and Li-TFSI in conjunction with spiro-OMeTAD effectively improved the power conversion efficiency (PCE) of the fabricated solar cells. As a result, we achieved PCE of 10.4%, measured under standard solar conditions (AM 1.5G, 100 mW cm-2). © 2013 The Royal Society of Chemistry.

new spiro (thio) barbiturates based on cyclohexanone and bicyclo

African Journals Online (AJOL)

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condensation can be operated with the aid of strong acids or bases [2, 13]. Several catalytic methods have been achieved for crossed-aldol condensation [4, 14-31]. Several spiro-(thio)barbituric acid derivatives in which the active methylene carbon of. (thio)barbituric acid is substituted by an unsubstituted cyclobutane or ...

Ladder variational autoencoders

DEFF Research Database (Denmark)

Sønderby, Casper Kaae; Raiko, Tapani; Maaløe, Lars

2016-01-01

Variational autoencoders are powerful models for unsupervised learning. However deep models with several layers of dependent stochastic variables are difficult to train which limits the improvements obtained using these highly expressive models. We propose a new inference model, the Ladder...... Variational Autoencoder, that recursively corrects the generative distribution by a data dependent approximate likelihood in a process resembling the recently proposed Ladder Network. We show that this model provides state of the art predictive log-likelihood and tighter log-likelihood lower bound compared...

Ladder Variational Autoencoder

DEFF Research Database (Denmark)

Sønderby, Casper Kaae; Raiko, Tapani; Maaløe, Lars

2016-01-01

Variational autoencoders are powerful models for unsupervised learning. However deep models with several layers of dependent stochastic variables are difficult to train which limits the improvements obtained using these highly expressive models. We propose a new inference model, the Ladder...... Variational Autoencoder, that recursively corrects the generative distribution by a data dependent approximate likelihood in a process resembling the recently proposed Ladder Network. We show that this model provides state of the art predictive log-likelihood and tighter log-likelihood lower bound compared...

De optimale sportafstand voor de ladder van de glazenwasser

NARCIS (Netherlands)

Reijneveld, C.N.; Looze, M.P. de; Hoozemans, M.J.M.; Grinten, M.P. van der; Korte, E.M. de; Kingma, I.

2002-01-01

Voor de glazenwasser die werkt met staande ladder, is een goede ladder zeer belangrijk. Hij loopt en werkt op en verplaatst de ladder veelvuldig. Er is veel discussie over ladders en de optimale sportafstand bij staande ladders. De meeste glazenwassers geven de voorkeur aan een sportafstand van 35

Anti-proliferative, Cytotoxic and NF-ĸB Inhibitory Properties of Spiro(Lactone-Cyclohexanone) Compounds in Human Leukemia.

Science.gov (United States)

Bouhenna, Mustapha M; Orlikova, Barbora; Talhi, Oualid; Schram, Ben; Pinto, Diana C G A; Taibi, Nadia; Bachari, Khaldoun; Diederich, Marc; Silva, Artur M S; Mameri, Nabil

2017-09-01

NF-ĸB affects most aspects of cellular physiology. Deregulation of NF-ĸB signaling is associated with inflammatory diseases and cancer. In this study, we evaluated the cytotoxic and NF-ĸB inhibition potential of new spiro(lactone-cyclohexanone) compounds in two different human leukemia cell lines (U937 and K562). The anti-proliferative effects of the spiro(lactone-cyclohexanone) compounds on human K562 and U937 cell lines was evaluated by trypan blue staining, as well as their involvement in NF-kB regulation were analyzed by luciferase reporter gene assay, Caspase-3/7 activities were evaluated to analyze apoptosis induction. Both spiro(coumarin-cyclohexanone) 4 and spiro(6- methyllactone-cyclohexanone) 9 down-regulated cancer cell viability and proliferation. Compound 4 inhibited TNF-α-induced NF-ĸB activation in a dose-dependent manner and induced caspase-dependent apoptosis in both leukemia cell lines. Results show that compound 4 and compound 9 have potential as anti-cancer agents. In addition, compound 4 exerted NF-kB inhibition activity in leukemia cancer cells. Copyright© 2017, International Institute of Anticancer Research (Dr. George J. Delinasios), All rights reserved.

New insights into canted spiro carbon interstitial in graphite

Science.gov (United States)

EL-Barbary, A. A.

2017-12-01

The self-interstitial carbon is the key to radiation damage in graphite moderator nuclear reactor, so an understanding of its behavior is essential for plant safety and maximized reactor lifetime. The density functional theory is applied on four different graphite unit cells, starting from of 64 carbon atoms up to 256 carbon atoms, using AIMPRO code to obtain the energetic, athermal and mechanical properties of carbon interstitial in graphite. This study presents first principles calculations of the energy of formation that prove its high barrier to athermal diffusion (1.1 eV) and the consequent large critical shear stress (39 eV-50 eV) necessary to shear graphite planes in its presence. Also, for the first time, the gamma surface of graphite in two dimensions is calculated and found to yield the critical shear stress for perfect graphite. Finally, in contrast to the extensive literature describing the interstitial of carbon in graphite as spiro interstitial, in this work the ground state of interstitial carbon is found to be canted spiro interstitial.

Transport properties of magnetic atom bridges controlled by a scanning tunneling microscope

International Nuclear Information System (INIS)

Nakanishi, H.; Kishi, T.; Kasai, H.; Komori, F.; Okiji, A.

2003-01-01

We have investigated the transport and magnetic properties of the atom bridge made from magnetic materials, which is the atom-scale wire constructed between a scanning tunneling microscope (STM) tip and a solid surface, by the use of ab initio calculations. In the case of the twisted ladder structure atom bridge made of Fe, we have found that the magnetic state of the bridge changes from ferromagnetic to paramagnetic, as we compress the bridge in length. We report the spin dependent quantized conductance of the bridge. And we discuss the origin of a change in transport properties as we compress the bridge in length

Synthesis and properties of nitrogenous heterocycles containing a spiro-fused cyclopropane fragment

International Nuclear Information System (INIS)

Tomilov, Yury V; Nefedov, Oleg M; Kostyuchenko, Irina V

2000-01-01

The published data on the methods of synthesis and chemical transformations of nitrogenous heterocyclic compounds spiro-fused with a cyclopropane fragment are described systematically and generalised. The bibliography includes 146 references.

The effect of span length and girder type on bridge costs

Directory of Open Access Journals (Sweden)

Batikha Mustafa

2017-01-01

Full Text Available Bridges have an important role in impacting the civilization, growth and economy of cities from ancient time until these days due to their function in reducing transportation cost and time. Therefore, development of bridges has been a knowledge domain in civil engineering studies in terms of their types and construction materials to confirm a reliable, safe, economic design and construction. Girder-bridge of concrete deck and I-beam girder has been used widely for short and medium span bridges because of ease and low-cost of fabrication. However, many theoretical and practical investigations are still undertaken regarding the type of beam girder; i.e steel composite or prestressed concrete. This paper evaluates the effect of bridge span and the type of girder on the capital cost and life cycle costs of bridges. Three types of girders were investigated in this research: steel composite, pre-tensioned pre-stressed concrete and post-tensioned pre-stressed concrete. The structural design was analyzed for 5 span lengths: 20, 25, 30, 35 and 40m. Then, the capital construction cost was accounted for 15 bridges according to each span and construction materials. Moreover, the maintenance required for 50 years of bridge life was evaluated and built up as whole life costs for each bridge. As a result of this study, the influence of both span length and type of girder on initial construction cost and maintenance whole life costs were assessed to support the decision makers and designers in the selection process for the optimum solution of girder bridges.

Production of Monodisperse Nanoparticles and Application of Discrete-Monodisperse Model in Plasma Reactors

International Nuclear Information System (INIS)

Kim, Dong-Joo; Kim, Kyo-Seon; Zhao, Qian-Qiu

2003-01-01

The particle growth in plasma reactor were investigated by using the discrete-monodisperse (D-M) model for various process conditions. The monodisperse large sized particle distribution predicted by the D-M model are in good agreement with the large sized particles by the discrete-sectional model and also in the experiments by Shiratani et al. (1996). Some fractions of the small size particles are in a neutral state or even charged positively, but most of the large sized monodisperse particles are charged negatively. As the mass generation rate of monomers increases, the large sized particles grow more quickly and the production rate of nanoparticles of 100nm by plasma reactor increases. As the initial electron concentration or the monomer diameter increases, it takes longer time for the large sized particles to grow up to 100nm, but the large sized particle concentration of 100nm increases and the resulting production rate of large sized particles of 100nm increases. As the residence time increases, the time for the large sized particles to grow up to 100nm decreases and the large sized particle concentration of 100nm increases and, as a result, the production rate of large sized particles of 100nm increases. We propose that the plasma reactor can be a good candidate to produce monodisperse nanoparticles

Multicomponent synthesis, biological evaluation and molecular docking of new spiro-oxindole derivatives

Directory of Open Access Journals (Sweden)

M. Sapnakumari

2017-11-01

Full Text Available A new series of spiro-oxindoles that were identified based upon their ability to inhibit methionine tRNA synthase (PDB ID: 1PFV and glucosamine-6-phosphate synthase (PDB ID: 1JXA enzymes in virtual screening was synthesized by a three-component 1,3-dipolar cycloaddition method. The reaction proceeds through the formation of azomethine ylides generated in situ by the decarboxylative condensation of isatin and amino acids with dipolarophile chalcones. These compounds are active against Staphylococcus aureus, Escherichia coli, Aspergillus niger and Aspergillus flavus, supporting the in silico screening. In addition, their antitubercular activity was assessed using the MABA method. The compounds 3′-[(4-fluorophenylcarbonyl]-4′-phenylspiro[indole-3,2′-pyrrolidin]-2(1H-one 3a, 4′-(4-bromophenyl-3′-[(4-fluorophenylcarbonyl]-5′-(hydroxymethyl spiro[indole-3,2′-pyrrolidin]-2(1H-one 3e and 4′-(4-chlorophenyl-3′-[(4-fluorophenylcarbonyl]-5′-(2-methylpropylspiro[indole-3,2′-pyrrolidin]-2(1H-one 3g are potent molecules with MIC of 0.8 μg/mL. In the DPPH radical scavenging assay, compounds 4′-(4-chlorophenyl-3′-[(4-fluorophenylcarbonyl]spiro[indole-3,2′-pyrrolidin]-2(1H-one 3b, 4′-(4-chlorophenyl-3′-[(4-fluorophenylcarbonyl]-5′-(hydroxymethylspiro[indole-3,2′-pyrrolidin]-2(1H-one 3d and 4′-(4-bromophenyl-3′-[(4-fluorophenylcarbonyl]-5′-(hydroxymethylspiro[indole-3,2′-pyrrolidin]-2(1H-one 3e exhibited significant radical scavenging capacity. Keywords: Chalcone, Spiro-oxindole, Azomethine ylide, Antimicrobial activity, Molecular docking

29 CFR 1917.118 - Fixed ladders.

Science.gov (United States)

2010-07-01

... tubular scaffold framing; and (4) Ladders used only for fire-fighting or emergency purposes. (b... of equipment. (3) Ladder safety device means a support system limiting an employee's drop or fall...

CHEMISRTY OF NOVEL SPIRO OXAZOLO-THIADIAZOLES DERIVATIVES – SYNTHESIS, CHARACTERIZATION AND BIOLOGICAL EVALUATION CHEMISRTY NEUARTIGER SPIRO oxazolo-Thiadiazole DERIVATE - Synthese, Charakterisierung und biologische Bewertung

OpenAIRE

Vijay V. Dabholkar, Abhishek Karekar, Prem Naik & N. B. Shinde

2012-01-01

A series of novel 2-N-acetyl hydrazino,4-acetyl,7-phenyl,9-(substitutedbenzylidine),1-thia, 3,4,8,triaza,6-oxa Spiro[4.4] nona-2,7-diene (4) were synthesized and screened for their antibacterial activity. The structures of the products were confirmed by IR, 1H,13C NMR and elemental analysis.

Action–angle variables, ladder operators and coherent states

International Nuclear Information System (INIS)

Campoamor-Stursberg, R.; Gadella, M.; Kuru, Ş.; Negro, J.

2012-01-01

This Letter is devoted to the building of coherent states from arguments based on classical action–angle variables. First, we show how these classical variables are associated to an algebraic structure in terms of Poisson brackets. In the quantum context these considerations are implemented by ladder type operators and a structure known as spectrum generating algebra. All this allows to generate coherent states and thereby the correspondence of classical–quantum properties by means of the aforementioned underlying structure. This approach is illustrated with the example of the one-dimensional Pöschl–Teller potential system. -- Highlights: ► We study the building of coherent states from classical action–angle variables arguments. ► The classical variables are associated to an algebraic structure in terms of Poisson brackets. ► In the quantum context these considerations are implemented by ladder type operators. ► All this allows to formulate coherent states and the correspondence of classical–quantum properties.

Perspective on rainbow-ladder truncation

International Nuclear Information System (INIS)

Eichmann, G.; Alkofer, R.; Krassnigg, A.; Cloeet, I. C.; Roberts, C. D.

2008-01-01

Prima facie the systematic implementation of corrections to the rainbow-ladder truncation of QCD's Dyson-Schwinger equations will uniformly reduce in magnitude those calculated mass-dimensioned results for pseudoscalar and vector meson properties that are not tightly constrained by symmetries. The aim and interpretation of studies employing rainbow-ladder truncation are reconsidered in this light

Evolution of the low-energy excitation spectrum from the pure Hubbard ladder to the SO(5) ladder: A numerical study

International Nuclear Information System (INIS)

Duffy, D.; Haas, S.; Kim, E.

1998-01-01

The Hubbard Hamiltonian on a two-leg ladder is studied numerically using quantum Monte Carlo and exact diagonalization techniques. A rung interaction, V, is turned on such that the resulting model has an exact SO(5) symmetry when V=-U. The evolution of the low-energy excitation spectrum is presented from the pure Hubbard ladder to the SO(5) ladder. It is shown that the low-energy excitations in the pure Hubbard ladder have an approximate SO(5) symmetry. copyright 1998 The American Physical Society

Passage and behaviour of cultured Lake Sturgeon in a prototype side-baffle fish ladder: I. Ladder hydraulics and fish ascent

Science.gov (United States)

Kynard, B.; Pugh, D.; Parker, T.

2011-01-01

Research and development of a fish ladder for sturgeons requires understanding ladder hydraulics and sturgeon behaviour in the ladder to insure the ladder is safe and provides effective passage. After years of research and development, we designed and constructed a full-scale prototype side-baffle ladder inside a spiral flume (38.3m long??1m wide??1m high) on a 6% (1:16.5) slope with a 1.92-m rise in elevation (bottom to top) to test use by sturgeons. Twenty-eight triangular side baffles, each extending part way across the flume, alternated from inside wall to outside wall down the ladder creating two major flow habitats: a continuous, sinusoidal flow down the ladder through the vertical openings of side-baffles and an eddy below each side baffle. Ascent and behaviour was observed on 22 cultured Lake Sturgeon=LS (Acipenser fulvescens) repeatedly tested in groups as juveniles (as small as 105.1cm TL, mean) or as adults (mean TL, 118cm) during four periods (fall 2002 and 2003; spring 2003 and 2007). Percent of juveniles entering the ladder that ascended to the top was greater in spring (72.7%) than in fall (40.9-45.5%) and 90.9% of 11 adults, which ascended as juveniles, ascended to the top. Six LS (27.3%) never swam to the top and seven (31.8%) swam to the top in all tests, indicating great variability among individuals for ascent drive. Some LS swam directly to the top in <1min, but most rested in an eddy during ascent. Juveniles swimming through outside wall baffle slots (mean velocity, 1.2ms-1) swam at 1.8-2.2body lengthss-1 and 3.2-3.3tail beatss-1, either at or approaching prolonged swimming speed. The side-baffle ladder was stream-like and provided key factors for a sturgeon ladder: a continuous flow and no full cross-channel walls, abundant eddies for resting, an acceptable water depth, and a water velocity fish could ascend swimming 2bls-1. A side-baffle ladder passes LS and other moderate-swimming fishes. ?? 2011 Blackwell Verlag, Berlin.

Novel Rearrangements in the Reactions Directed Toward Preparation of Spiro-N,N-ketals: Reactions of Naphthalene-1,8-diamine with Ninhydrin and Isatin

Directory of Open Access Journals (Sweden)

Keiji Kobayashi

2012-11-01

Full Text Available Spiro-N,N-ketal 5, consisting of a phthaloperine heterocyclic ring and a naphtha[1,8-ef][1,4]diazepine ring, was obtained along with spiro-N,N-ketal 2 via 2,2-condensation in the reaction of ninhydrin with naphthalene-1,8-diamine. Their molecular structures were elucidated by X-ray crystal structural analysis. Aside from these spiro compounds, the diazapleiadiene compound 3 formed by 1,2-condensation and the 1,4-isoquinolinedione compound 4 arising from ring expansion were isolated. When isatin was reacted with naphthalene-1,8-diamine, spiro-N,N-ketal 6 and the two 1H-perimidine-based compounds 7 and 8 were isolated. Compound 8 was revealed to undergo a fast dynamic prototropic tautomerization in solution. Plausible mechanisms of the formation of the products are proposed.

Career ladder program for registered nurses in ambulatory care.

Science.gov (United States)

Nelson, Joan; Sassaman, Becky; Phillips, Alison

2008-01-01

RN ladder programs are designed to inspire and reward clinical excellence. Kaiser Permanente Colorado's (KPCO) career ladder program emerged as a result of a labor-management partnership. Career ladder point assignments are reflective of the organization's priorities and values. KPCO's career ladder point tool awards RNs for formal and continuing education, professional presentations, organizational experience and experience as an RN, certifications and active professional memberships, leadership activities, research and publications, and nursing-related volunteer work. Participation in the RN career ladder requires that the nurse achieve a self-determined, manager-approved, measurable goal that will improve patient care. Career ladder nurses at KPCO were significantly more involved in leadership and interdisciplinary activities, quality improvement projects, and preceptorship.

Spiro-OMeTAD single crystals: Remarkably enhanced charge-carrier transport via mesoscale ordering

KAUST Repository

Shi, Dong; Qin, X.; Li, Yuan; He, Yao; Zhong, Cheng; Pan, Jun; Dong, H.; Xu, Wei; Li, T.; Hu, W.; Bredas, Jean-Luc; Bakr, Osman

2016-01-01

bottleneck for advancing cell efficiencies. We devised an antisolvent crystallization strategy to grow single crystals of spiro-OMeTAD, which allowed us to experimentally elucidate its molecular packing and transport properties. Electronic structure

New spiro (thio barbiturates based on cyclohexanone and bicyclo [3.1.1]heptan-6-one by nonconcerted [1+5] cycloaddition reaction and their conformational structures

Directory of Open Access Journals (Sweden)

N. N. Pesyan

2014-09-01

Full Text Available Crossed-aldol condensation reaction of aromatic aldehydes with ketones such as; acetone and cyclohexanone leads to the efficient formation of cross conjugated α,β-unsaturated ketones in excellent yield. The intermolecular and then intramolecular Michael addition reaction of α,β-unsaturated ketones derived from acetone and cyclohexanone with (thiobarbituric acids lead to synthesis new type of 7,11-diaryl-2,4-diazaspiro[5.5]undecane-1,3,5,9-tetraone and 2,4-diaryl-1'H-spiro[bicyclo[3.3.1]nonane-3,5'-pyrimidine]-2',4',6',9(3'H-tetraone, respectively in good yield. Structure elucidation is carried out by 1H NMR, 13C NMR, FT-IR, UV-Visible, mass spectroscopy and X-ray crystallography techniques. A possible mechanism of the formation is discussed. The structural conformation also demonstrated by coupling constants derived from dihedral angles between vicinal and geminal protons. The 1H NMR spectra of NH protons of spiro compounds derived from barbituric acid show a broad singlet peak instead, these protons in the spiro compounds derived from thiobarbituric acid show two distinct peaks. DOI: http://dx.doi.org/10.4314/bcse.v28i3.12

Energy-efficient hydrogen separation by AB-type ladder-polymer molecular sieves

KAUST Repository

Ghanem, Bader

2014-07-19

The synthesis, microstructures, and exceptional gas transport properties of two new soluble ladder polymers, polymers of intrinsic microporosity (TPIM-1 and TPIM-2) containing triptycene moieties substituted with branched isopropyl and linear propyl chains at the 9,10-bridgeheads were reported. The precursor A-B monomers were modified with an o -difluoride functionality for enhanced activation for nucleophilic aromatic substitution. In a Schlenk tube, a mixture of the A-B monomer, 18-crown-6, anhydrous DMF and anhydrous potassium carbonate was stirred at 155 °C under nitrogen atmosphere for 20 min followed by the addition of toluene. The reaction was continued for another 45 min and more toluene was added. After another 45 min the reaction mixture was cooled to room temperature and poured into methanol. Slow evaporation of filtered, dilute 3-5 wt% chloroform solutions from a leveled glass plate yielded isotropic polymer films. Dry membranes were soaked in methanol for 24 h, air-dried, and then heated at 120°C for 24 h under high vacuum to remove any traces of residual solvent. TPIM-1 exhibits simultaneous boosts in permeability and selectivity, which highlights the significant potential of an isopropyl-substituted triptycene moiety as a contortion center for ladder PIMs.

Energy-efficient hydrogen separation by AB-type ladder-polymer molecular sieves

KAUST Repository

Ghanem, Bader; Swaidan, Raja; Ma, Xiaohua; Litwiller, Eric; Pinnau, Ingo

2014-01-01

The synthesis, microstructures, and exceptional gas transport properties of two new soluble ladder polymers, polymers of intrinsic microporosity (TPIM-1 and TPIM-2) containing triptycene moieties substituted with branched isopropyl and linear propyl chains at the 9,10-bridgeheads were reported. The precursor A-B monomers were modified with an o -difluoride functionality for enhanced activation for nucleophilic aromatic substitution. In a Schlenk tube, a mixture of the A-B monomer, 18-crown-6, anhydrous DMF and anhydrous potassium carbonate was stirred at 155 °C under nitrogen atmosphere for 20 min followed by the addition of toluene. The reaction was continued for another 45 min and more toluene was added. After another 45 min the reaction mixture was cooled to room temperature and poured into methanol. Slow evaporation of filtered, dilute 3-5 wt% chloroform solutions from a leveled glass plate yielded isotropic polymer films. Dry membranes were soaked in methanol for 24 h, air-dried, and then heated at 120°C for 24 h under high vacuum to remove any traces of residual solvent. TPIM-1 exhibits simultaneous boosts in permeability and selectivity, which highlights the significant potential of an isopropyl-substituted triptycene moiety as a contortion center for ladder PIMs.

Edge currents in frustrated Josephson junction ladders

Science.gov (United States)

Marques, A. M.; Santos, F. D. R.; Dias, R. G.

2016-09-01

We present a numerical study of quasi-1D frustrated Josephson junction ladders with diagonal couplings and open boundary conditions, in the large capacitance limit. We derive a correspondence between the energy of this Josephson junction ladder and the expectation value of the Hamiltonian of an analogous tight-binding model, and show how the overall superconducting state of the chain is equivalent to the minimum energy state of the tight-binding model in the subspace of one-particle states with uniform density. To satisfy the constraint of uniform density, the superconducting state of the ladder is written as a linear combination of the allowed k-states of the tight-binding model with open boundaries. Above a critical value of the parameter t (ratio between the intra-rung and inter-rung Josephson couplings) the ladder spontaneously develops currents at the edges, which spread to the bulk as t is increased until complete coverage is reached. Above a certain value of t, which varies with ladder size (t = 1 for an infinite-sized ladder), the edge currents are destroyed. The value t = 1 corresponds, in the tight-binding model, to the opening of a gap between two bands. We argue that the disappearance of the edge currents with this gap opening is not coincidental, and that this points to a topological origin for these edge current states.

Transport properties of a ladder with two random dimer chains

International Nuclear Information System (INIS)

Hu Dong-Sheng; Zhu Chen-Ping; Zhang Yong-Mei

2011-01-01

We investigate the transport properties of a ladder with two random dimer (RD) chains. It is found that there are two extended states in the ladder with identical RD chains and a critical state regarded as an extended state in the ladder with pairing RD chains. Such a critical state is caused by the chiral symmetry. The ladder with identical RD chains can be decoupled into two isolated RD chains and the ladder with pairing RD chains can not. The analytic expressions of the extended states are presented for the ladder with identical RD chains. (condensed matter: electronic structure, electrical, magnetic, and optical properties)

Transformation of Zwitterionic Pyridine Derivatives to a Spiro-Fused Ring System: Azoniabenzo[de]fluorine. Synthesis and Mechanistic Rationalization.

Science.gov (United States)

Palkó, Roberta; Egyed, Orsolya; Rokob, Tibor András; Bombicz, Petra; Riedl, Zsuzsanna; Hajós, György

2015-01-02

Reaction of aryl- and benzylsulfanopyridinium amidates bearing a methyl group in position 6 with 2 equiv of diphenylketene afforded a spiro-fused ring system: azoniabenzo[de]fluorine. By use of an excess amount of ketene, a distinct reaction was observed via which a 1H-pyrrolo[3,2-b]pyridin-2(3H)-one derivative was furnished. The structure of the tetracyclic spiro-fused ring system was unambiguously confirmed by X-ray diffraction, and its formation was rationalized by DFT calculations.

Explaining choice option attractiveness by beliefs elicited by the laddering method

DEFF Research Database (Denmark)

Grunert, Klaus G.; Bech-Larsen, Tino

2005-01-01

option. The laddering method is used to elicit beliefs of all three types for a choice between conventional and organic pork. As a benchmark, beliefs were also elicited in the traditional way advocated by Ajzen and Fishbein. Using both sets of beliefs in a subsequent survey, it was shown that the beliefs...... elicited by the laddering method increase explanatory power with regard to choice option attractiveness beyond the beliefs elicited by the Ajzen and Fishbein method, and that this additional explanatory power was due to those beliefs which relate the choice option to concepts with a higher level...

Ground Radio Operator Career Ladder AFSC 293X3.

Science.gov (United States)

1981-07-01

formal resident training, OJT, and ,her Air Force management decisions . The structure of jobs within the Ground ! odio Operatoi career ladder was...33 ADJUST ANTENNA TUNING UNITS 33 TYPE RECORDS, REPORTS, OR FORMS :33 OPERATE AUXILLARY GENERATORS 33 A8 ’iT’ TASKS PERFORMED BY SUPERVISORS AND

Laughlin-like States in Bosonic and Fermionic Atomic Synthetic Ladders

Directory of Open Access Journals (Sweden)

Marcello Calvanese Strinati

2017-06-01

Full Text Available The combination of interactions and static gauge fields plays a pivotal role in our understanding of strongly correlated quantum matter. Cold atomic gases endowed with a synthetic dimension are emerging as an ideal platform to experimentally address this interplay in quasi-one-dimensional systems. A fundamental question is whether these setups can give access to pristine two-dimensional phenomena, such as the fractional quantum Hall effect, and how. We show that unambiguous signatures of bosonic and fermionic Laughlin-like states can be observed and characterized in synthetic ladders. We theoretically diagnose these Laughlin-like states focusing on the chiral current flowing in the ladder, on the central charge of the low-energy theory, and on the properties of the entanglement entropy. Remarkably, Laughlin-like states are separated from conventional liquids by Lifschitz-type transitions, characterized by sharp discontinuities in the current profiles, which we address using extensive simulations based on matrix-product states. Our work provides a qualitative and quantitative guideline towards the observability and understanding of strongly correlated states of matter in synthetic ladders. In particular, we unveil how state-of-the-art experimental settings constitute an ideal starting point to progressively tackle two-dimensional strongly interacting systems from a ladder viewpoint, opening a new perspective for the observation of non-Abelian states of matter.

Modeling the Sliding/Falling Ladder Paradox

Science.gov (United States)

Fox, William P.; Fox, James B.

2003-01-01

Recently we were presented with an interesting twist to the sliding ladder problem viewed in the related rates section of most calculus textbooks. Our problem concerning a sliding ladder that eventually hits the ground. At first, those attempting this problem fell into the calculus trap using only related rates. Previous work for this problem…

5 CFR 335.104 - Eligibility for career ladder promotion.

Science.gov (United States)

2010-01-01

... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Eligibility for career ladder promotion... REGULATIONS PROMOTION AND INTERNAL PLACEMENT General Provisions § 335.104 Eligibility for career ladder promotion. No employee shall receive a career ladder promotion unless his or her current rating of record...

"Ladder" structure in tonal noise generated by laminar flow around an airfoil.

Science.gov (United States)

Chong, Tze Pei; Joseph, Phillip

2012-06-01

The presence of a "ladder" structure in the airfoil tonal noise was discovered in the 1970s, but its mechanism hitherto remains a subject of continual investigation in the research community. Based on the measured noise results and some numerical analysis presented in this letter, the variations of four types of airfoil tonal noise frequencies with the flow velocity were analyzed individually. The ladder structure is proposed to be caused by the acoustic/hydrodynamic frequency lag between the scattering of the boundary layer instability noise and the discrete noise produced by an aeroacoustic feedback loop.

Doped spin ladders under magnetic field

International Nuclear Information System (INIS)

Roux, G.

2007-07-01

This thesis deals with the physics of doped two-leg ladders which are a quasi one-dimensional and unconventional superconductor. We particularly focus on the properties under magnetic field. Models for strongly correlated electrons on ladders are studied using exact diagonalization and density-matrix renormalization group (DMRG). Results are also enlightened by using the bosonization technique. Taking into account a ring exchange it highlights the relation between the pairing of holes and the spin gap. Its influence on the dynamics of the magnetic fluctuations is also tackled. Afterwards, these excitations are probed by the magnetic field by coupling it to the spin degree of freedom of the electrons through Zeeman effect. We show the existence of doping-dependent magnetization plateaus and also the presence of an inhomogeneous superconducting phase (FFLO phase) associated with an exceeding of the Pauli limit. When a flux passes through the ladder, the magnetic field couples to the charge degree of freedom of the electrons via orbital effect. The diamagnetic response of the doped ladder probes the commensurate phases of the t-J model at low J/t. Algebraic transverse current fluctuations are also found once the field is turned on. Lastly, we report numerical evidences of a molecular superfluid phase in the 3/2-spin attractive Hubbard model: at a density low enough, bound states of four fermions, called quartets, acquire dominant superfluid fluctuations. The observed competition between the superfluid and density fluctuations is connected to the physics of doped ladders. (author)

Synthesis of novel synthetic intermediates from the reaction of benzimidazole and triazole carbenes with ketenimines and their application in the construction of spiro-pyrroles.

Science.gov (United States)

Mo, Jun-Ming; Ma, Yang-Guang; Cheng, Ying

2009-12-07

2-(2-Alkoxycarbonyl-1-arylamino-1-propenyl)benzimidazolium and 5-(2-alkoxycarbonyl-1-arylamino-1-propenyl)triazolium salts were synthesized in good yields from the reaction of benzimidazole and triazole carbenes with ketenimines. Upon treatment with a base, both salts were converted into novel 1,3-dipoles which underwent [3+2] cycloaddition reactions with electron-deficient alkynes and allenes to produce benzimidazole-spiro-pyrroles or triazole-spiro-pyrroles. This work provides novel synthons for the construction of multifunctional spiro-pyrrole derivatives that are not easy accessible by other synthetic methods and are potentially amenable to further transformations.

The Static Ladder Problem with Two Sources of Friction

Science.gov (United States)

Bennett, Jonathan; Mauney, Alex

2011-01-01

The problem of a ladder leaning against a wall in static equilibrium is a classic example encountered in introductory mechanics texts. Most discussions of this problem assume that the static frictional force between the ladder and wall can be ignored. A few authors consider the case where the static friction coefficients between ladder/wall…

Superconductivity in doped two-leg ladder cuprates

International Nuclear Information System (INIS)

Qin Jihong; Yuan Feng; Feng Shiping

2006-01-01

Within the t-J ladder model, superconductivity with a modified d-wave symmetry in doped two-leg ladder cuprates is investigated based on the kinetic energy driven superconducting mechanism. It is shown that the spin-liquid ground-state at the half-filling evolves into the superconducting ground-state upon doping. In analogy to the doping dependence of the superconducting transition temperature in the planar cuprate superconductors, the superconducting transition temperature in doped two-leg ladder cuprates increases with increasing doping in the underdoped regime, and reaches a maximum in the optimal doping, then decreases in the overdoped regime

Quantifying Ladder Fuels: A New Approach Using LiDAR

Science.gov (United States)

Heather Kramer; Brandon Collins; Maggi Kelly; Scott Stephens

2014-01-01

We investigated the relationship between LiDAR and ladder fuels in the northern Sierra Nevada, California USA. Ladder fuels are often targeted in hazardous fuel reduction treatments due to their role in propagating fire from the forest floor to tree crowns. Despite their importance, ladder fuels are difficult to quantify. One common approach is to calculate canopy base...

Elongational viscosity of monodisperse and bidisperse polystyrene melts

DEFF Research Database (Denmark)

Nielsen, Jens Kromann; Rasmussen, Henrik K.; Hassager, Ole

2006-01-01

The start-up and steady uniaxial elongational viscosity have been measured for two monodisperse polystyrene melts with molecular weights of 52 and 103 kg/mole, and for three bidisperse polystyrene melts. The monodisperse melts show a maximum in the steady elongational viscosity vs. the elongational...

Selectivity of fish ladders: a bottleneck in Neotropical fish movement

Directory of Open Access Journals (Sweden)

Carlos Sérgio Agostinho

Full Text Available Although dozens of fish ladders have been constructed at dams of Brazilian reservoirs, there are few studies evaluating their efficiency as a tool for the conservation of Neotropical ichthyofauna, especially for migratory species. Therefore, the present study evaluated the selectivity of the species that entered and ascended the fish ladder located next to Lajeado Dam (Luis Eduardo Magalhães Hydroelectric Power Plant on the Tocantins River. Samples were taken monthly from November, 2002 through October, 2003, in the resting pools of the ladder, using cast nets, and in the downstream stretch, using gillnets. The selectivity of the ladder in attracting fish was evaluated by comparing the occurrence, relative abundance, dominance and the congruence of abundance ranks of migratory and non-migratory species in the ladder and in the stretch of river immediately downstream. Species richness and fish abundance in the resting pools were used to evaluate selectivity along the ladder. The effects on selectivity by temporal variations in water level downriver and maximum flow velocity in the fish ladder were also analyzed. Out of the 130 species recorded downriver, 62.3% were caught in the ladder, and migratory species were clearly favored. However, more than 2/3 of the catch belonged to only three species (Rhaphiodon vulpinus, Psectrogaster amazonica and Oxydoras niger. Although the majority of the species that entered the ladder were able to reach its top, there was a sharp reduction in abundance of individuals towards the top. Temporal variations in the water level below the dam influenced richness and abundance of fish concentrated downstream and in the ladder, with lower values during periods of low water. In the ladder, a maximum flow velocity of 2.3 m/s, although also selective, proved to be more appropriate for fish ascension than a velocity of 2.8 m/s. It was concluded that the entry and ascension of the fish in the ladder were not congruent with

The beneficial effects of mixing spiro-OMeTAD with n-butyl-substituted copper phthalocyanine for perovskite solar cells

International Nuclear Information System (INIS)

Nouri, Esmaiel; Wang, Yu-Long; Chen, Qian; Xu, Jia-Ju; Dracopoulos, Vassilios; Sygellou, Lamprini; Xu, Zong-Xiang; Mohammadi, Mohammad Reza; Lianos, Panagiotis

2016-01-01

Highlights: • Soluble n-butyl substituted copper phthalocyanine. • Mixture with spiro-OMeTAD and employment in perovskite solar cells. • Impressive improvement of perovskite solar cell efficiency. • n-Butyl derivative gives better results than tert-butyl derivative - Abstract: Perovskite solar cells have been constructed under ambient conditions by using 2,2',7,7'-Tetrakis-(N,N-di-4-methoxyphenylamino)-9,9'-spirobifluorene (spiro-OMeTAD) mixed with a small quantity of soluble tetra-n-butyl substituted copper phthalocyanine as hole transporting material. The introduction of the phthalocyanine derivative resulted in an impressive increase of cell efficiency, which changed from 10.4% in the absence to 15.4% in the presence of phthalocyanine. This effect is related to the creation of deep traps in the hole transporting phase which block back-travelling electrons as well as to the improvement of the structural quality of the spiro-OMeTAD film in the presence of phthalocyanine. Both functionalities decrease shunt paths within the hole transporting phase resulting in increasing the fill factor and the open-circuit voltage of the cell.

Synthesis of spiro[indolo-1,5-benzodiazepines] from 3-acetyl ...

Indian Academy of Sciences (India)

Unknown

also as potent virucides and non-nucleoside inhibi- tors of HIV-1 reverse transcriptase.2 Beside this,. 1,5-benzodiazepines ... printed circuits.8 Here we report the synthesis of spiro ... 3d. 5,6-Benzo 1727. 1701. 1672. 3218 3382. 4⋅22 (d, 2H, J = 17⋅91 Hz), 3⋅81 (d, 2H,. J = 17⋅8 .... R1 = R2 = CH3 show 88⋅88% inhibition.

The snakes and ladders of FM service excellence

OpenAIRE

Price, Ilfryn; Mccarroll, Patricia

2015-01-01

A report to accompany a workshop and gamification event at EFMC 2015 in Glasgow.\\ud \\ud Snakes and Ladders is an ancient Indian board game regarded today as a worldwide classic. The historic version had its root in morality lessons, where a player's progression up the board represented a life journey complicated by virtues (ladders) and vices (snakes). Our version brings back the morality element by associating each ladder and snake with enablers or barriers to service excellence in FM all id...

Hopping ladder and power relaxation due to donor-acceptor pairs

International Nuclear Information System (INIS)

Kostadinov, I.Z.

1985-11-01

Hopping between donor-acceptor pairs leads to peculiar temperature dependence of the conductivity and the photoconductivity under subband gap illumination in the form of non-linear activation energies ladder. The correlated and uncorrelated distributions of pairs are considered and the conditions for the ladder existence are determined. The relaxation of the carrier concentration fluctuations is studied and power type decay is found. The temperature dependence of the exponent is calculated in agreement with the non-exponential decay of the pulse excited luminescence observed by Dean et al. The temperature dependence of the luminescence intensity also shows variable activation energy as found here. The exponent value α=1.316 is also in agreement with the data for crystalline and amorphous materials. (author)

Baryons and ladders

International Nuclear Information System (INIS)

Ball, R.D.

1990-01-01

By formal manipulation of the QCD functional integral we arrive at a relativistic low energy effective theory of non-local color singlet mesons and baryons, which at tree level sums up ladders of effective glue exchange between constituent quarks. (orig.)

Understanding the Behaviour of Infinite Ladder Circuits

Science.gov (United States)

Ucak, C.; Yegin, K.

2008-01-01

Infinite ladder circuits are often encountered in undergraduate electrical engineering and physics curricula when dealing with series and parallel combination of impedances, as a part of filter design or wave propagation on transmission lines. The input impedance of such infinite ladder circuits is derived by assuming that the input impedance does…

Gluing Ladder Feynman Diagrams into Fishnets

International Nuclear Information System (INIS)

Basso, Benjamin; Dixon, Lance J.; Stanford University, CA; University of California, Santa Barbara, CA

2017-01-01

We use integrability at weak coupling to compute fishnet diagrams for four-point correlation functions in planar Φ "4 theory. Our results are always multilinear combinations of ladder integrals, which are in turn built out of classical polylogarithms. The Steinmann relations provide a powerful constraint on such linear combinations, which leads to a natural conjecture for any fishnet diagram as the determinant of a matrix of ladder integrals.

Intelligent control for braking-induced longitudinal vibration responses of floating-type railway bridges

Science.gov (United States)

Qu, Wei-Lian; Qin, Shun-Quan; Tu, Jian-Weia; Liu, Jia; Zhou, Qiang; Cheng, Haibin; Pi, Yong-Lin

2009-12-01

This paper presents an intelligent control method and its engineering application in the control of braking-induced longitudinal vibration of floating-type railway bridges. Equations of motion for the controlled floating-type railway bridges have been established based on the analysis of the longitudinal vibration responses of floating-type railway bridges to train braking and axle-loads of moving trains. For engineering applications of the developed theory, a full-scale 500 kN smart magnetorheologic (MR) damper has been designed, fabricated and used to carry out experiments on the intelligent control of braking-induced longitudinal vibration. The procedure for using the developed intelligent method in conjunction with the full-scale 500 kN MR dampers has been proposed and used to control the longitudinal vibration responses of the deck of floating-type railway bridges induced by train braking and axle-loads of moving trains. This procedure has been applied to the longitudinal vibration control of the Tian Xingzhou highway and railway cable-stayed bridge over the Yangtze River in China. The simulated results have shown that the intelligent control system using the smart MR dampers can effectively control the longitudinal response of the floating-type railway bridge under excitations of braking and axle-loads of moving trains.

Intelligent control for braking-induced longitudinal vibration responses of floating-type railway bridges

International Nuclear Information System (INIS)

Qu, Wei-Lian; Tu, Jian-Weia; Liu, Jia; Zhou, Qiang; Qin, Shun-Quan; Cheng, Haibin; Pi, Yong-Lin

2009-01-01

This paper presents an intelligent control method and its engineering application in the control of braking-induced longitudinal vibration of floating-type railway bridges. Equations of motion for the controlled floating-type railway bridges have been established based on the analysis of the longitudinal vibration responses of floating-type railway bridges to train braking and axle-loads of moving trains. For engineering applications of the developed theory, a full-scale 500 kN smart magnetorheologic (MR) damper has been designed, fabricated and used to carry out experiments on the intelligent control of braking-induced longitudinal vibration. The procedure for using the developed intelligent method in conjunction with the full-scale 500 kN MR dampers has been proposed and used to control the longitudinal vibration responses of the deck of floating-type railway bridges induced by train braking and axle-loads of moving trains. This procedure has been applied to the longitudinal vibration control of the Tian Xingzhou highway and railway cable-stayed bridge over the Yangtze River in China. The simulated results have shown that the intelligent control system using the smart MR dampers can effectively control the longitudinal response of the floating-type railway bridge under excitations of braking and axle-loads of moving trains

Fish ladders: safe fish passage or hotspot for predation?

Directory of Open Access Journals (Sweden)

Angelo Antonio Agostinho

Full Text Available Fish ladders are a strategy for conserving biodiversity, as they can provide connectivity between fragmented habitats and reduce predation on shoals that accumulate immediately below dams. Although the impact of predation downstream of reservoirs has been investigated, especially in juvenile salmonids during their downstream movements, nothing is known about predation on Neotropical fish in the attraction and containment areas commonly found in translocation facilities. This study analysed predation in a fish passage system at the Lajeado Dam on the Tocantins River in Brazil. The abundance, distribution, and the permanence (time spent of large predatory fish along the ladder, the injuries imposed by piranhas during passage and the presence of other vertebrate predators were investigated. From December 2002 to October 2003, sampling was conducted in four regions (downstream, along the ladder, in the forebay, and upstream of the reservoir using gillnets, cast nets and counts or visual observations. The captured fish were tagged with thread and beads, and any mutilations were registered. Fish, birds and dolphins were the main predator groups observed, with a predominance of the first two groups. The entrance to the ladder, in the downstream region, was the area with the highest number of large predators and was the only region with relevant non-fish vertebrates. The main predatory fish species were Rhaphiodon vulpinus, Hydrolycus armatus, and Serrasalmus rhombeus. Tagged individuals were detected predating along the ladder for up to 90 days. Mutilations caused by Serrasalmus attacks were noted in 36% of species and 4% of individuals at the top of the ladder. Our results suggested that the high density of fish in the restricted ladder environment, which is associated with injuries suffered along the ladder course and the presence of multiple predator groups with different predation strategies, transformed the fish corridor into a hotspot for

The su(1, 1) dynamical algebra from the Schroedinger ladder operators for N-dimensional systems: hydrogen atom, Mie-type potential, harmonic oscillator and pseudo-harmonic oscillator

International Nuclear Information System (INIS)

Martinez, D; Flores-Urbina, J C; Mota, R D; Granados, V D

2010-01-01

We apply the Schroedinger factorization to construct the ladder operators for the hydrogen atom, Mie-type potential, harmonic oscillator and pseudo-harmonic oscillator in arbitrary dimensions. By generalizing these operators we show that the dynamical algebra for these problems is the su(1, 1) Lie algebra.

Optical properties of monodispersive FePt nanoparticle films

Energy Technology Data Exchange (ETDEWEB)

Lee, S.J.; Lo, C.C.H. [Ames Laboratory, Iowa State University, Ames, IA 50011 (United States); Yu, A.C.C. [Sony Corporation, Sendai Technology Center, 3-4-1 Sakuragi, Miyagi 985-0842 (Japan); Fan, M. [Center for Sustainable Environmental Technologies, Iowa State University, Ames, IA 50011 (United States)

2004-10-01

The optical properties of monodispersive FePt nanoparticle films were investigated using spectroscopic ellipsometry in the energy range of 1.5 to 5.5 eV. The monodispersive FePt nanoparticle film was stabilized on a Si substrate by means of an organosilane coupling film, resulting in the formation of a (Si/SiO{sub 2}/APTS/FePt nanoparticles monolayer) structure. Multilayer optical models were employed to study the contribution of the FePt nanoparticles to the measured optical properties of the monodispersive FePt nanoparticle film, and to estimate the optical properties of the FePt nanoparticle layer. (copyright 2004 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

A balanced intervention ladder: promoting autonomy through public health action.

Science.gov (United States)

Griffiths, P E; West, C

2015-08-01

The widely cited Nuffield Council on Bioethics 'Intervention Ladder' structurally embodies the assumption that personal autonomy is maximized by non-intervention. Consequently, the Intervention Ladder encourages an extreme 'negative liberty' view of autonomy. Yet there are several alternative accounts of autonomy that are both arguably superior as accounts of autonomy and better suited to the issues facing public health ethics. We propose to replace the one-sided ladder, which has any intervention coming at a cost to autonomy, with a two-sided 'Balanced Intervention Ladder,' where intervention can either enhance or diminish autonomy. We show that not only the alternative, richer accounts of autonomy but even Mill's classic version of negative liberty puts some interventions on the positive side of the ladder. Crown Copyright © 2015. Published by Elsevier Ltd. All rights reserved.

Spiro[pyrrolidine-3,3′-oxindoles] and Their Indoline Analogues as New 5-HT6 Receptor Chemotypes

Directory of Open Access Journals (Sweden)

Ádám A. Kelemen

2017-12-01

Full Text Available Synthetic derivatives of spiro[pyrrolidinyl-3,3′-oxindole] alkaloids (coerulescine analogues were investigated as new ligands for aminergic G-protein coupled receptors (GPCRs. The chemical starting point 2′-phenylspiro[indoline-3,3′-pyrrolidin]-2-one scaffold was identified by virtual fragment screening utilizing ligand- and structure based methods. As a part of the hit-to-lead optimization a structure-activity relationship analysis was performed to explore the differently substituted 2′-phenyl-derivatives, introducing the phenylsulphonyl pharmacophore and examining the corresponding reduced spiro[pyrrolidine-3,3′-indoline] scaffold. The optimization process led to ligands with submicromolar affinities towards the 5-HT6 receptor that might serve as viable leads for further optimization.

Adaptation of a ladder beam walking task to assess locomotor recovery in mice following spinal cord injury

Science.gov (United States)

Cummings, Brian J.; Engesser-Cesar, Christie; Anderson, Aileen J.

2007-01-01

Locomotor impairments after spinal cord injury (SCI) are often assessed using open-field rating scales. These tasks have the advantage of spanning the range from complete paralysis to normal walking; however, they lack sensitivity at specific levels of recovery. Additionally, most supplemental assessments were developed in rats, not mice. For example, the horizontal ladder beam has been used to measure recovery in the rat after SCI. This parametric task results in a videotaped archival record of the event, is easily administered, and is unambiguously scored. Although a ladder beam apparatus for mice is available, its use in the assessment of recovery in SCI mice is rare, possibly because normative data for uninjured mice and the type of step misplacements injured mice exhibit is lacking. We report the development of a modified ladder beam instrument and scoring system to measure hindlimb recovery in vertebral T9 contusion spinal cord injured mice. The mouse ladder beam allows for the use of standard parametric statistical tests to assess locomotor recovery. Ladder beam performance is consistent across four strains of mice, there are no sex differences, and inter-rater reliability between observers is high. The ladder beam score is proportional to injury severity and can be used to easily separate mice capable of weight-supported stance up to mice with consistent forelimb to hindlimb coordination. Critically, horizontal ladder beam testing discriminates between mice that score identically in terms of stepping frequency in open-field testing. PMID:17197044

Adaptation of a ladder beam walking task to assess locomotor recovery in mice following spinal cord injury.

Science.gov (United States)

Cummings, Brian J; Engesser-Cesar, Christie; Cadena, Gilbert; Anderson, Aileen J

2007-02-27

Locomotor impairments after spinal cord injury (SCI) are often assessed using open-field rating scales. These tasks have the advantage of spanning the range from complete paralysis to normal walking; however, they lack sensitivity at specific levels of recovery. Additionally, most supplemental assessments were developed in rats, not mice. For example, the horizontal ladder beam has been used to measure recovery in the rat after SCI. This parametric task results in a videotaped archival record of the event, is easily administered, and is unambiguously scored. Although a ladder beam apparatus for mice is available, its use in the assessment of recovery in SCI mice is rare, possibly because normative data for uninjured mice and the type of step misplacements injured mice exhibit is lacking. We report the development of a modified ladder beam instrument and scoring system to measure hindlimb recovery in vertebral T9 contusion spinal cord injured mice. The mouse ladder beam allows for the use of standard parametric statistical tests to assess locomotor recovery. Ladder beam performance is consistent across four strains of mice, there are no sex differences, and inter-rater reliability between observers is high. The ladder beam score is proportional to injury severity and can be used to easily separate mice capable of weight-supported stance up to mice with consistent forelimb to hindlimb coordination. Critically, horizontal ladder beam testing discriminates between mice that score identically in terms of stepping frequency in open-field testing.

Boat boarding ladder placement

Science.gov (United States)

1998-04-01

Presented in three volumes; 'Boat Boarding Ladder Placement,' which explores safety considerations including potential for human contact with a rotating propeller; 'Boat Handhold Placement,' which explores essential principles and methods of fall con...

Resonant two-photon absorption and electromagnetically induced transparency in open ladder-type atomic system.

Science.gov (United States)

Moon, Han Seb; Noh, Heung-Ryoul

2013-03-25

We have experimentally and theoretically studied resonant two-photon absorption (TPA) and electromagnetically induced transparency (EIT) in the open ladder-type atomic system of the 5S(1/2) (F = 1)-5P(3/2) (F' = 0, 1, 2)-5D(5/2) (F″ = 1, 2, 3) transitions in (87)Rb atoms. As the coupling laser intensity was increased, the resonant TPA was transformed to EIT for the 5S(1/2) (F = 1)-5P(3/2) (F' = 2)-5D(5/2) (F″ = 3) transition. The transformation of resonant TPA into EIT was numerically calculated for various coupling laser intensities, considering all the degenerate magnetic sublevels of the 5S(1/2)-5P(3/2)-5D(5/2) transition. From the numerical results, the crossover from TPA to EIT could be understood by the decomposition of the spectrum into an EIT component owing to the pure two-photon coherence and a TPA component caused by the mixed term.

Designing and Implementing Performance-Based Career Ladder Plans.

Science.gov (United States)

Hawley, Willis D.

1985-01-01

Reviews the factors that any teacher motivation plan must incorporate to be effective and outlines 11 principles that should be followed in designing career ladder plans to meet teacher needs, increase teacher competence, and facilitate effective instruction. Warns against potential pitfalls in career ladder plans. (PGD)

Simple and inexpensive microfluidic devices for the generation of monodisperse multiple emulsions

KAUST Repository

Li, Erqiang

2013-12-16

Droplet-based microfluidic devices have become a preferred versatile platform for various fields in physics, chemistry and biology. Polydimethylsiloxane soft lithography, the mainstay for fabricating microfluidic devices, usually requires the usage of expensive apparatus and a complex manufacturing procedure. Here, we report the design and fabrication of simple and inexpensive microfluidic devices based on microscope glass slides and pulled glass capillaries, for generating monodisperse multiple emulsions. The advantages of our method lie in a simple manufacturing procedure, inexpensive processing equipment and flexibility in the surface modification of the designed microfluidic devices. Different types of devices have been designed and tested and the experimental results demonstrated their robustness for preparing monodisperse single, double, triple and multi-component emulsions. © 2014 IOP Publishing Ltd.

Improved Performance and Reproducibility of Perovskite Solar Cells by Well-Soluble Tris(pentafluorophenyl)borane as a p-Type Dopant.

Science.gov (United States)

Ye, Tengling; Wang, Junhai; Chen, Wenbo; Yang, Yulin; He, Dongqing

2017-05-31

In this work, well-soluble tris(pentafluorophenyl)borane (BCF) is introduced for the first time into 2,2',7,7'-tetrakis(N,N'-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD) as a p-dopant. The conductivity of spiro-OMeTAD films is dramatically enhanced. When the BCF-doped spiro-OMeTAD film is used as a hole-transport layer (HTL) in perovskite solar cells (PSCs), nearly double increase in power conversion efficiency (PCE) is obtained compared to that of the PSCs based on a pristine spiro-OMeTAD HTL. By the introduction of lithium bis(trifluoromethanesulfonyl)imide and 4-tert-butylpyridine into the BCF-doped spiro-OMeTAD film, the conductivity of spiro-OMeTAD film can be further enhanced, and an optimum PCE of 14.65% is obtained. In addition, the average efficiency of the device and the reproducibility of BCF-based PSCs are better than those of FK209-based PSCs. The working mechanism of the BCF doping effect on spiro-OMeTAD is studied in detail. The strong electron-accepting ability, excellent solubility in common organic solvents, and the low cost make BCF a very attractive p-type dopant for spiro-OMeTAD.

Characterization of pore-filling of spiro-MeOTAD in solid-state dye-sensitized solar cells and its consequence in device performance

KAUST Repository

Ding, I-Kang

2009-08-27

In this paper, the pore filling of spiro-MeOTAD (2,2\\',7,7\\'-tetrakis-(N,N-di-p-methoxyphenylamine)9, 9\\'-spirobifluorene) in mesoporous TiO2 films is quantified for the first time using XPS depth profiling and UVVis absorption spectroscopy. We show that spiro-OMeTAD can penetrate the entire depth of the film, and its concentration is constant throughout the film. We determine that in a 2.5-•m-thick film, the volume of the pores is 60-65% filled. The pores become less filled when thicker films are used. Such filling fraction is much higher than the solution concentration because the excess solution on top of the film can act as a reservoir during the spin coating process. Lastly, we demonstrate that by using a lower spin coating speed and higher spiro-OMeTAD solution concentration, we can increase the filling fraction and consequently the efficiency of the device

Measuring a Country's Product Ladder and Technology Level based on Trade Flow

Directory of Open Access Journals (Sweden)

Jong-il Kim

2006-06-01

Full Text Available This study tries to quantify the technology level of products based on the concept of product ladder. While many studies on country technology competitiveness use the aggregate indices such as total factor productivity and revealed comparative advantage, this study estimates the ranking of about 2000 products in product ladder by using SITC 5 digit level export data. Based on the product ladder, this study measures the country and industry ranking and explores the characteristics of the ranking. It provides the international comparison of inter-industry and intra-industry ranking differences in product ladder. The statistical relationships between the ranking in product ladder and the determinants of technology level such as R&D and physical capital investment and wage, confirms that the measured ranking in product ladder could be regarded as an indirect indicator of technology level. The product ladder is applied to the estimation of production function to see the effect of the product differentiation on labor productivity.

MAFIA simulation and cold model test of three types of bridge coupler

International Nuclear Information System (INIS)

Chang, C.R.; Yao, C.G.; Swenson, D.A.; Funk, L.W.; Raparia, D.

1992-01-01

In the new design of the SSC CCL, the total number of bridge couplers has increased from 50 to 63, and their maximum length increased from 37.2 to 46.1 cm. Choosing a bridge coupler that gives maximum coupling, minimum power flow, phase shift and fabrication cost becomes important. The conventional TM010 single cavity bridge coupler used in LAMPF and Fermilab will have severe mode mixing problem when the bridge length is over 30 cm, and the coupling is very weak. Three types of bridge coupler have been proposed: (1) TM012 single cavity bridge coupler; (2) electrically coupled multi-cavity bridge coupler and (3) magnetically coupled multi-cavity bridge coupler. This paper presents both MAFIA simulations and cold model tests results. Each bridge coupler has its unique characteristics with advantages and disadvantages, but all three are superior to the conventional coupler. (Author) 6 figs., tab., 2 refs

Dipoles on a Two-leg Ladder

DEFF Research Database (Denmark)

Gammelmark, Søren; Zinner, Nikolaj Thomas

2013-01-01

We study polar molecules with long-range dipole-dipole interactions confined to move on a two-leg ladder for different orientations of the molecular dipole moments with respect to the ladder. Matrix product states are employed to calculate the many-body ground state of the system as function...... that there is a critical angle at which ordering disappears. This angle is slightly larger than the angle at which the dipoles are non-interacting along a single leg. This behavior should be observable using current experimental techniques....

PT-symmetric ladders with a scattering core

Energy Technology Data Exchange (ETDEWEB)

D' Ambroise, J. [Department of Mathematics, Amherst College, Amherst, MA 01002-5000 (United States); Lepri, S. [CNR – Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, via Madonna del piano 10, I-50019 Sesto Fiorentino (Italy); Istituto Nazionale di Fisica Nucleare, Sezione di Firenze, via G. Sansone 1, I-50019 Sesto Fiorentino (Italy); Malomed, B.A. [Department of Physical Electronics, School of Electrical Engineering, Faculty of Engineering, Tel Aviv University, Tel Aviv 69978 (Israel); Kevrekidis, P.G. [Department of Mathematics and Statistics, University of Massachusetts, Amherst, MA 01003-9305 (United States)

2014-08-01

We consider a PT-symmetric chain (ladder-shaped) system governed by the discrete nonlinear Schrödinger equation where the cubic nonlinearity is carried solely by two central “rungs” of the ladder. Two branches of scattering solutions for incident plane waves are found. We systematically construct these solutions, analyze their stability, and discuss non-reciprocity of the transmission associated with them. To relate the results to finite-size wavepacket dynamics, we also perform direct simulations of the evolution of the wavepackets, which confirm that the transmission is indeed asymmetric in this nonlinear system with the mutually balanced gain and loss. - Highlights: • We model a PT-symmetric ladder system with cubic nonlinearity on two central rungs. • We examine non-reciprocity and stability of incident plane waves. • Simulations of wavepackets confirm our results.

Development of ultra-light pixelated ladders for an ILC vertex detector

CERN Document Server

Chon-Sen, N.; Claus, G.; De Masi, R.; Deveaux, M.; Dulinski, W.; Goffe, M.; Goldstein, J.; Gregor, I.-M.; Hu-Guo, Ch.; Imhoff, M.; Muntz, C.; Nomerotski, A.; Santos, C.; Schrader, C.; Specht, M.; Stroth, J.; Winter, M.

2010-01-01

The development of ultra-light pixelated ladders is motivated by the requirements of the ILD vertex detector at ILC. This paper summarizes three projects related to system integration. The PLUME project tackles the issue of assembling double-sided ladders. The SERWIETE project deals with a more innovative concept and consists in making single-sided unsupported ladders embedded in an extra thin plastic enveloppe. AIDA, the last project, aims at building a framework reproducing the experimental running conditions where sets of ladders could be tested.

Pore-Filling of Spiro-OMeTAD in Solid-State Dye Sensitized Solar Cells: Quantification, Mechanism, and Consequences for Device Performance

KAUST Repository

Ding, I-Kang; Té treault, Nicolas; Brillet, Jé ré mie; Hardin, Brian E.; Smith, Eva H.; Rosenthal, Samuel J.; Sauvage, Fré dé ric; Grä tzel, Michael; McGehee, Michael D.

2009-01-01

In this paper, the pore filling of spiro-OMeTAD (2,2′,7,7′- tetrakis-(N,N-di-p-methoxyphenylamine)9,9′-spirobtfIuorene) in mesoporous TiO2 films is quantified for the first time using XPS depth profiling and UV-Vis absorption spectroscopy. It is shown that spiro-OMeTAD can penetrate the entire depth of the film, and its concentration is constant throughout the film. We determine that in a 2.5-μm-thick film, the volume of the pores is 60-65% filled. The pores become less filled when thicker films are used. Such filling fraction is much higher than the solution concentration because the excess solution on top of the film can act as a reservoir during the spin coating process. Lastly, we demonstrate that by using a lower spin coating speed and higher spiro-OMeTAD solution concentration, we can increase the filling fraction and consequently the efficiency of the device. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA.

Pore-Filling of Spiro-OMeTAD in Solid-State Dye Sensitized Solar Cells: Quantification, Mechanism, and Consequences for Device Performance

KAUST Repository

Ding, I-Kang

2009-08-10

In this paper, the pore filling of spiro-OMeTAD (2,2′,7,7′- tetrakis-(N,N-di-p-methoxyphenylamine)9,9′-spirobtfIuorene) in mesoporous TiO2 films is quantified for the first time using XPS depth profiling and UV-Vis absorption spectroscopy. It is shown that spiro-OMeTAD can penetrate the entire depth of the film, and its concentration is constant throughout the film. We determine that in a 2.5-μm-thick film, the volume of the pores is 60-65% filled. The pores become less filled when thicker films are used. Such filling fraction is much higher than the solution concentration because the excess solution on top of the film can act as a reservoir during the spin coating process. Lastly, we demonstrate that by using a lower spin coating speed and higher spiro-OMeTAD solution concentration, we can increase the filling fraction and consequently the efficiency of the device. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA.

The latrine ownership ladder

DEFF Research Database (Denmark)

Obeng, Peter Appiah; Keraita, Bernard; Oduro-Kwarteng, Sampson

2015-01-01

the challenges that undermine sanitation uptake in low-income peri-urban areas and the prospects of various levels of facility sharing as conceived in the latrine ownership ladder approach. Findings – The authors argue that the infrastructural and other socio-economic challenges of low-income peri-urban areas...... to the promotion of household latrines. The paper identifies provision of special concessions for peri-urban areas in policy formulation, education and technical support to households, regulation and enforcement of sanitation by-laws among complimentary policy interventions to make the latrine ownership ladder...... approach more effective. Originality/value – The paper provides an insight into the debate on redefining improved sanitation in the post-2015 era of the Millennium Development Goals and offers policy alternatives to policy makers in low-income countries seeking to accelerate the uptake of improved latrines...

Role of Structural Asymmetry in Controlling Drop Spacing in Microfluidic Ladder Networks

Science.gov (United States)

Wang, William; Maddala, Jeevan; Vanapalli, Siva; Rengasamy, Raghunathan

2012-02-01

Manipulation of drop spacing is crucial to many processes in microfluidic devices including drop coalescence, detection and storage. Microfluidic ladder networks ---where two droplet-carrying parallel channels are connected by narrow bypass channels through which the motion of drops is forbidden---have been proposed as a means to control relative separation between pairs of drops. Prior studies in microfluidic ladder networks with vertical bypasses, which possess fore-aft structural symmetry, have revealed that pairs of drops can only undergo reduction in drop spacing at the ladder exit. We investigate the dynamics of drops in microfluidic ladder networks with both vertical and slanted bypasses. Our analytical results indicate that unlike symmetric ladder networks, structural asymmetry introduced by a single slanted bypass can be used to modulate the relative spacing between drops, enabling them to contract, synchronize, expand or even flip at the ladder exit. Our experiments confirm all the behaviors predicted by theory. Numerical analysis further shows that ladders containing several identical bypasses can only linearly transform the input drop spacing. Finally, we find that ladders with specific combinations of vertical and slanted bypasses can generate non-linear transformation of input drop spacing, despite the absence of drop decision-making events at the bypass junctions.

Towards automatic verification of ladder logic programs

OpenAIRE

Zoubek , Bohumir; Roussel , Jean-Marc; Kwiatkowska , Martha

2003-01-01

International audience; Control system programs are usually validated by testing prior to their deployment. Unfortunately, testing is not exhaustive and therefore it is possible that a program which passed all the required tests still contains errors. In this paper we apply techniques of automatic verification to a control program written in ladder logic. A model is constructed mechanically from the ladder logic program and subjected to automatic verification against requirements that include...

The massless supersymmetric ladder with L rungs

International Nuclear Information System (INIS)

Rossi, G.C.; Stanev, Ya.S.

2009-01-01

We show that in the massless N=1 supersymmetric Wess-Zumino theory it is possible to devise a computational strategy by which the x-space calculation of the ladder 4-point correlators can be carried out without introducing any regularization. As an application we derive a representation valid at all loop orders in terms of conformal invariant integrals. We obtain an explicit expression of the 3-loop ladder diagram for collinear external points

Magnetic susceptibilities of integrable quantum ladders

International Nuclear Information System (INIS)

Park, Soo A; Lee, K.

2001-01-01

As an extension of previous studies, we consider the magnetic susceptibilities of a coupled spin chain model at low temperature and of a more realistic model at low temperature and of a more realistic model having a t-J ladder structure at zero temperature. The magnetic susceptibilities for both models are obtained numerically when the coupling constant is greater than its critical value. In this region, the ladders behave as a single chain for H c and as two independent chains for H>H c , showing a divergence at H c . This divergence is expected to smear out at a finite temperature

Model Comparison Exercise Circuit Training Game and Circuit Ladder Drills to Improve Agility and Speed

Directory of Open Access Journals (Sweden)

Susilaturochman Hendrawan Koestanto

2017-11-01

Full Text Available The purpose of this study was to compare: (1 the effect of circuit training game and circuit ladder drill for the agility; (2 the effect of circuit training game and circuit ladder drill on speed; (3 the difference effect of circuit training game and circuit ladder drill for the speed (4 the difference effect of circuit training game and circuit ladder drill on agility. The type of this research was quantitative with quasi-experimental methods. The design of this research was Factorial Design, with analysing data using ANOVA. The process of data collection was done by using 30 meters sprint speed test and shuttle run test during the pretest and posttest. Furthermore, the data was analyzed by using SPSS 22.0 series. Result: The circuit training game exercise program and circuit ladder drill were significant to increase agility and speed (sig 0.000 < α = 0.005 Group I, II, III had significant differences (sig 0.000 < α = 0.005. The mean of increase in speed of group I = 0.20 seconds, group II = 0.31 seconds, and group III = 0.11 seconds. The average increase agility to group I = 0.34 seconds group II = 0.60 seconds, group III = 0.13 seconds. Based on the analysis above, it could be concluded that there was an increase in the speed and agility of each group after being given a training.

Preparation of Novel Fused Ring Spiro[benzotetraphene-fluorene] Derivatives and Application for Deep-Blue Host Materials

Energy Technology Data Exchange (ETDEWEB)

Kim, Minji; Lee, Chilwon; Gong, Myoungseon [Dankook Univ., Yongin (Korea, Republic of)

2014-06-15

A series of novel fused-ring spiro compounds, spiro[benzo[ij]tetraphene-7,9'-fluorene] derivatives containing an end-capping aryl substituent at both the C3 and C10-positions has been designed and synthesized via multi-step Suzuki coupling reactions. 3-(1-Naphthyl)-10-phenyl, 3-(2-naphthyl)-10-phenyl and 3-[4-(1-naphthyl)phenyl]-10-phenyl showed improved glass transition temperatures (T{sub g}) with good thermal stability. Their photophysical, electrochemical, and electroluminescent properties were investigated and were used to construct blue organic light emission diodes (OLEDs). The typical OLED devices showed excellent performance; the based device exhibited highly efficient deep blue-light emission with a maximum efficiency of 5.27 cd/A (EQE, 4.63%) with CIE (x = 0.133, y = 0.144). According to these characteristics, these deep-blue light emitting materials have sufficient potential for fluorescent OLED applications.

Ladder Ising spin configurations. Pt. 1. Heat capacity

International Nuclear Information System (INIS)

Mejdani, R.; Lambros, A.

1996-01-01

We consider a ladder Ising spin model (with two coupled Ising spin chains), characterized by two couplings (interchain and intrachain couplings), to study in detail, in an analytical way, its thermal behaviour and particularly the variation of the specific heat versus temperature, the ratio of interaction constants, and the magnetic field. It is interesting that when the competition between interchain and intrachain interactions is strong the specific heat exhibits a double peak and when the competition is not so strong the specific heat has a single peak. Further, without entering into details, we give, in a numerical way, some similar results for more complicated ladder configurations (with more than two linear Ising chains). The spin-1/2 ladders or systems of spin chains may be realized in nature by vanadyl pyrophosphate ((VO) 2 P 2 O 7 ) or similar materials. All these intermediate systems are today important to gain further insight into the physics of one-dimensional spin chains and two-dimensional high-T c spin systems, both of which have shown interesting and unusual magnetic and superconducting properties. It is plausible that experimental and theoretical studies of ladders may lead to other interesting physical phenomena. (orig.)

Discussing Laddering Application by the Means-End Chain Theory

Science.gov (United States)

Veludo-de-Oliveira, Tania Modesto; Ikeda, Ana Akemi; Campomar, Marcos Cortez

2006-01-01

This article aims at analyzing laddering as a technique of qualitative research, emphasizing the procedures for data collection, analysis and interpretation, and its main limitations as well. "Laddering refers to an in-depth, one-on-one interviewing technique used to develop an understanding of how consumers translate the attributes of products…

Biomechanical analysis of loading/unloading a ladder on a truck.

Science.gov (United States)

Moriguchi, Cristiane Shinohara; Carnaz, Leticia; de Miranda, Luiz Carlos; Marklin, Richard William; Coury, Helenice Jane Cote Gil

2012-01-01

Loading/unloading a ladder on vehicles are frequent tasks and involve overhead handling that may expose workers to risk factors of shoulder musculoskeletal disorders. The objective of the present study was to evaluate posture, forces required and perceived exertion when loading and unloading the ladder on a utility truck. Thirteen male overhead line workers from an electric utility in Brazil participated in this study. Shoulder elevation angle was measured using inclinometers. The required force to load/unload the ladder was measured by dynamometer. Subjective assessment of the perceived exertion was recorded to compare the exertion reported during the test conditions to the field conditions. The task of loading/unloading the ladder presented risks of shoulder musculoskeletal disorders (MSDs) to workers because it requires high levels of force (approximately 60% of the maximal force) combined with overhead posture of the shoulders (more than 100° from the neutral posture). Age and height presented to interfere in biomechanical risks presented in load/unload task. There was no significant difference between the subjective exertion during the test conditions and handling the ladder in the field. Ergonomic intervention is recommended to reduce these risks for shoulder MSDs.

Commutation-relation-preserving ladder operators for propagating optical fields in nonuniform lossy media

DEFF Research Database (Denmark)

Partanen, Mikko; Häyrynen, Teppo; Tulkki, Jukka

2015-01-01

We have recently developed a quantized fluctuational electrodynamics (QFED) formalism to describe the quantum aspects of local thermal balance formation and to formulate the electromagnetic field ladder operators so that they no longer exhibit the anomalies reported for resonant structures. Here we...... show how the QFED can be used to resolve between the left and right propagating fields to bridge the QFED and the quantum optical input-output relations commonly used to describe selected quantum aspects of resonators. The generalized model introduces a density of states concept describing interference...... effects, which is instrumental in allowing an unambiguous separation of the fields and related quantum operators into left and right propagating parts. In addition to providing insight on the quantum treatment of interference, our results also provide the conclusive resolution of the long-standing enigma...

Magneto-optical polarization rotation in a ladder-type atomic system for tunable offset locking

Energy Technology Data Exchange (ETDEWEB)

Parniak, Michał, E-mail: michal.parniak@fuw.edu.pl; Leszczyński, Adam; Wasilewski, Wojciech [Institute of Experimental Physics, Faculty of Physics, University of Warsaw, Pasteura 5, 02-093 Warsaw (Poland)

2016-04-18

We demonstrate an easily tunable locking scheme for stabilizing frequency-sum of two lasers on a two-photon ladder transition based on polarization rotation in warm rubidium vapors induced by magnetic field and circularly polarized drive field. Unprecedented tunability of the two-photon offset frequency is due to strong splitting and shifting of magnetic states in external field. In our experimental setup, we achieve two-photon detuning of up to 700 MHz.

46 CFR 72.05-20 - Stairways, ladders, and elevators.

Science.gov (United States)

2010-10-01

... 46 Shipping 3 2010-10-01 2010-10-01 false Stairways, ladders, and elevators. 72.05-20 Section 72.05-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) PASSENGER VESSELS CONSTRUCTION AND ARRANGEMENT Structural Fire Protection § 72.05-20 Stairways, ladders, and elevators. (a)(1) Except as further noted the provisions of this...

Nonlinear Stress Relaxation of ``Quasi-monodisperse'' Miscible Blends of cis-Polyisoprene and Poly(ptert-butylstyrene)

Science.gov (United States)

Watanabe, Hiroshi; Matsumiya, Yumi

Viscoelastic relaxation was examined for entangled miscible blends of cis-polyisoprene (PI) and poly(ptert-butylstyrene) (PtBS). The terminal relaxation times of PI and PtBS therein, τPI and τPtBS, changed with the composition wPI and the molecular weights MPI and MPtBS. This ratio became unity when the wPI, MPI, and MPtBS values were chosen adequately. For example, in a blend with wPI = 0.75, MPI = 321k, and MPtBS = 91k at T = 40ûC, τPI/τPtBS = 1 and M/Me = 55 and 8.3 for PI and PtBS. Under small strains, this blend exhibited sharp, single-step terminal relaxation as similar to monodisperse homopolymers, thereby behaving as a ``quasi-monodisperse'' material. Under large step strains, the blend exhibited moderate nonlinear damping known as the type-A damping for entangled monodisperse homopolymers. Nevertheless, PI had M/Me = 55 in that blend, and homopolymers having such a large M/Me ratio exhibit very strong type-C damping. Thus, as compared to homopolymers, the nonlinearity was suppressed in the PI/PtBS blend having the large M/Me ratio. This suppression is discussed in relation to the slow Rouse retraction of the coexisting PtBS chains (having M/Me = 8.3 in the blend).

Topological phases in frustrated synthetic ladders with an odd number of legs

Science.gov (United States)

Barbarino, Simone; Dalmonte, Marcello; Fazio, Rosario; Santoro, Giuseppe E.

2018-01-01

The realization of the Hofstadter model in a strongly anisotropic ladder geometry has now become possible in one-dimensional optical lattices with a synthetic dimension. In this work, we show how the Hofstadter Hamiltonian in such ladder configurations hosts a topological phase of matter which is radically different from its two-dimensional counterpart. This topological phase stems directly from the hybrid nature of the ladder geometry and is protected by a properly defined inversion symmetry. We start our analysis by considering the paradigmatic case of a three-leg ladder which supports a topological phase exhibiting the typical features of topological states in one dimension: robust fermionic edge modes, a degenerate entanglement spectrum, and a nonzero Zak phase; then, we generalize our findings—addressable in the state-of-the-art cold-atom experiments—to ladders with a higher number of legs.

Triptycene-based ladder monomers and polymers, methods of making each, and methods of use

KAUST Repository

Pinnau, Ingo

2015-02-05

Embodiments of the present disclosure provide for a triptycene-based A-B monomer, a method of making a triptycene-based A-B monomer, a triptycene-based ladder polymer, a method of making a triptycene-based ladder polymers, a method of using triptycene-based ladder polymers, a structure incorporating triptycene-based ladder polymers, a method of gas separation, and the like.

Alkylated selenophene-based ladder-type monomers via a facile route for high performance thin-film transistor applications

KAUST Repository

Fei, Zhuping; Han, Yang; Gann, Eliot; Hodsden, Thomas; Chesman, Anthony; McNeill, Christopher R.; Anthopoulos, Thomas D.; Heeney, Martin

2017-01-01

We report the synthesis of two new selenophene containing ladder-type monomers, cyclopentadiselenophene (CDS) and indacenodiselenophene (IDSe), via a twofold and fourfold Pd catalyzed coupling with a 1,1-diborylmethane derivative. Co-polymers with benzothiadiazole (BT) were prepared in high yield by Suzuki polymerization to afford co-polymers which exhibited excellent solubility in a range of non-chlorinated solvents. The CDS co-polymer exhibited a band gap of just 1.18 eV, which is amongst the lowest reported for donor-acceptor polymers. Thin-film transistors were fabricated using environmentally benign, non-chlorinated solvents with the CDS and IDSe co-polymers exhibiting hole mobility up to 0.15 and 6.4 cm2 /Vs, respectively. This high performance was achieved without the undesirable peak in mobility often observed at low gate voltages due to parasitic contact resistance.

Alkylated selenophene-based ladder-type monomers via a facile route for high performance thin-film transistor applications

KAUST Repository

Fei, Zhuping

2017-05-26

We report the synthesis of two new selenophene containing ladder-type monomers, cyclopentadiselenophene (CDS) and indacenodiselenophene (IDSe), via a twofold and fourfold Pd catalyzed coupling with a 1,1-diborylmethane derivative. Co-polymers with benzothiadiazole (BT) were prepared in high yield by Suzuki polymerization to afford co-polymers which exhibited excellent solubility in a range of non-chlorinated solvents. The CDS co-polymer exhibited a band gap of just 1.18 eV, which is amongst the lowest reported for donor-acceptor polymers. Thin-film transistors were fabricated using environmentally benign, non-chlorinated solvents with the CDS and IDSe co-polymers exhibiting hole mobility up to 0.15 and 6.4 cm2 /Vs, respectively. This high performance was achieved without the undesirable peak in mobility often observed at low gate voltages due to parasitic contact resistance.

Frequency Modulation and Absorption Improvement of THz Micro-bolometer with Micro-bridge Structure by Spiral-Type Antennas.

Science.gov (United States)

Gou, Jun; Niu, Qingchen; Liang, Kai; Wang, Jun; Jiang, Yadong

2018-03-05

Antenna-coupled micro-bridge structure is proven to be a good solution to extend infrared micro-bolometer technology for THz application. Spiral-type antennas are proposed in 25 μm × 25 μm micro-bridge structure with a single separate linear antenna, two separate linear antennas, or two connected linear antennas on the bridge legs, in addition to traditional spiral-type antenna on the support layer. The effects of structural parameters of each antenna on THz absorption of micro-bridge structure are discussed for optimized absorption of 2.52 THz wave radiated by far infrared CO 2 lasers. The design of spiral-type antenna with two separate linear antennas for wide absorption peak and spiral-type antenna with two connected linear antennas for relatively stable absorption are good candidates for high absorption at low absorption frequency with a rotation angle of 360*n (n = 1.6). Spiral-type antenna with extended legs also provides a highly integrated micro-bridge structure with fast response and a highly compatible, process-simplified way to realize the structure. This research demonstrates the design of several spiral-type antenna-coupled micro-bridge structures and provides preferred schemes for potential device applications in room temperature sensing and real-time imaging.

PROVIDING SERVICEABILITY OF STRUCTURAL BEARING TYPES FOR ROADWAY BRIDGES

Directory of Open Access Journals (Sweden)

R. I. Polyuga

2010-03-01

Full Text Available In the article the description of structural bearing types for roadway bridges and their classification is given. Special attention is paid to effective bearings with elastomeric materials – rubber, pot, spherical ones. Characteristic defects of structural bearings and demands of serviceability are noticed.

Antibacterial Properties of 3 H-Spiro[1-benzofuran-2,1’-cyclohexane] Derivatives from Heliotropium filifolium

Directory of Open Access Journals (Sweden)

Marcela Wilkens

2008-10-01

Full Text Available A re-examination of cuticular components of Heliotropium filifolium allowed the isolation of four new compounds: 3’-hydroxy-2’,2’,6’-trimethyl-3H-spiro[1-benzo-furan-2,1’-cyclohexane]-5-carboxylic acid(2, methyl 3’-acetyloxy-2’,2’,6’-trimethyl-3H-spiro[1-benzofuran-2,1’-cyclohexane]-5-carboxylate (3, methyl 3’-isopentanoyloxy-2’,2’,6’-trimethyl-3H-spiro[1-benzofuran-2,1’-cyclohexane]-5-carboxylate (4 and methyl 3’-benzoyloxy-2’,2’,6’-trimethyl-3H-spiro[1-benzofuran-2,1’-cyclohexane]-5-carboxylate (5.Compounds 2-5 were identified by their spectroscopic analogies with filifolinol (1, and their structures confirmed by chemical correlation with 1. The antimicrobial properties of the compounds were tested against Gram positive and Gram negative bacteria. Some of them proved to be active against Gram positive, but inactive against Gram negative bacteria. In searching for structure-activity relationships from the obtained MIC values, lipophilicity was shown to be an important variable.

The oxidation of 2,2,5-three methyl-6-spiro cyclo hexane di hydro pyranol-5(X CI)

International Nuclear Information System (INIS)

Nikitin, V.I.

1961-01-01

In this chapter of book author as a result of oxidation of 2,2,5-three methyl-6-spiro cyclo hexane di hydro pyranol-5 evolved acetone, cyclopentanone, formic acid, acetic acid, oxalic acid, α-oxi isobutyric acid and adipinic acids

Bethe-Salpeter equation for fermion-antifermion system in the ladder approximation

International Nuclear Information System (INIS)

Fukui, Ichio; Seto, Noriaki; Yoshida, Toshihiro.

1977-01-01

The Bethe-Salpeter (B-S) equation is important for studying hadron physics. Especially intensive investigation on the fermion-antifermion B-S equation is indispensable for the phenomenological studies of hardrons. However, many components of the B-S amplitude and the Wick-rotated integral kernel of non-Fredholm type have prevented from knowing details the solutions even in the ladder approximation. Some particular solutions are known in case of the vanishing four-momenta of bound states. The B-S equation for the bound state of fermion-anti-fermion system interacting through vector (axial-vector) particle exchange was studied in the ladder approximation with Feynman gauge. The reduced equations were obtained for suitably decomposed amplitude, and it is shown that, in the S-wave case, the coupled equations separate into two parts. In the nonrelativistic limit, large components of the amplitude satisfy the Wick-Cutkosky equation, and small components are expressed in terms of the large ones. Equations are derived for the equal-time amplitudes. (Kobatake, H.)

SUSY’s Ladder: reframing sequestering at Large Volume

Energy Technology Data Exchange (ETDEWEB)

Reece, Matthew [Department of Physics, Harvard University,Cambridge, MA 02138 (United States); Xue, Wei [Center for Theoretical Physics, Massachusetts Institute of Technology,Cambridge, MA 02139 (United States)

2016-04-07

Theories with approximate no-scale structure, such as the Large Volume Scenario, have a distinctive hierarchy of multiple mass scales in between TeV gaugino masses and the Planck scale, which we call SUSY’s Ladder. This is a particular realization of Split Supersymmetry in which the same small parameter suppresses gaugino masses relative to scalar soft masses, scalar soft masses relative to the gravitino mass, and the UV cutoff or string scale relative to the Planck scale. This scenario has many phenomenologically interesting properties, and can avoid dangers including the gravitino problem, flavor problems, and the moduli-induced LSP problem that plague other supersymmetric theories. We study SUSY’s Ladder using a superspace formalism that makes the mysterious cancelations in previous computations manifest. This opens the possibility of a consistent effective field theory understanding of the phenomenology of these scenarios, based on power-counting in the small ratio of string to Planck scales. We also show that four-dimensional theories with approximate no-scale structure enforced by a single volume modulus arise only from two special higher-dimensional theories: five-dimensional supergravity and ten-dimensional type IIB supergravity. This gives a phenomenological argument in favor of ten dimensional ultraviolet physics which is different from standard arguments based on the consistency of superstring theory.

Movements of adult Atlantic salmon in relation to a hydroelectric dam and fish ladder

International Nuclear Information System (INIS)

Gowans, A.R.D.; Priede, I.G.

1999-01-01

The movements of adult Atlantic salmon were recorded as they approached, entered and ascended the pool-and-orifice fish ladder at Pitlochry Dam, Scotland. Thirty-nine returning salmon were captured in the River Tummel by rod-and-line angling, radio-tagged and released near where they were caught. The subsequent movements of each fish were then monitored. An electronic fish counter collected additional data on movements of untagged fish past a fixed point in the ladder. Of the 39 fish that were radio-tagged, 29 individuals were recorded approaching and ascending the ladder. The remaining fish either did not approach the dam (three fish), approached the dam after detailed tracking had ended (two fish), were recaptured by anglers (three fish), or the radio tags failed (two fish). Salmon released earlier in the year delayed longer before first approaching the dam. Delays between first approaching the dam and ascent of the ladder were greater for fish that approached the dam earlier. The majority of salmon visited the ladder entrance more than once (maximum 10 visits) before ascending. Having entered, all but four salmon ascended the fish ladder successfully on their first attempt. The four individuals that failed to do so succeeded on their second attempt. The rate at which salmon ascended the ladder was related directly to temperature. The shortest ascent time of a radio-tagged salmon was 5.25 h. Movements of eight of 11 tagged fish through the ladder ceased with the onset of darkness but continued on the following morning. No radio-tagged fish entered the ladder at temperatures below 9 o C. Similarly, few untagged fish were recorded ascending the ladder by the electronic fish counter at water temperatures below 8.5 o C. Records from the fish counter indicated that 92% of upstream movements were made during daylight. (author)

Work-related falls from ladders--a follow-back study of US emergency department cases.

Science.gov (United States)

Lombardi, David A; Smith, Gordon S; Courtney, Theodore K; Brennan, Melanye J; Kim, Jae Young; Perry, Melissa J

2011-11-01

Ladder falls comprise 16% of all US workplace fall-related fatalities, and ladder use may be particularly hazardous among older workers. This follow-back study of injured workers from a nationally representative sample of US emergency departments (ED) focused on factors related to ladder falls in three domains of the work environment: work equipment, work practices, and worker-related factors. Risk factors for fractures, the most frequent and severe outcome, were also evaluated. Workers injured from a ladder fall, treated in one of the 65 participating ED in the occupational National Electronic Injury Surveillance System (NEISS) were asked to participate. The questionnaire included worker demographics, injury, ladder and work equipment and environment characteristics, work tasks, and activities. Multivariate logistic regression models estimated odds ratios and 95% confidence intervals of a work-related fracture. Three-hundred and six workers experiencing an injury from an--on average--7.5-foot-fall from a step, extension, or straight ladder were interviewed primarily from construction, installation, maintenance, and repair professions. Injuries were most frequently to the arm, elbow or shoulder; head, neck, or face with diagnoses were primarily fracture, strain, sprain, contusion or abrasion. Workers were most frequently standing or sitting on the ladder while installing, hanging an item, or performing a repair when they fell. Ladder movement was the mechanism in 40% of falls. Environmental conditions played a role in cases. There was a significant association between fracture risk and fall height while working on the ladder that was also influenced by older work age. This study advances knowledge of falls from ladders to support those who specify means and methods, select equipment, and plan, supervise, or manage the performance of employees working at heights.

Phase transitions and magnetization of the mixed-spin Ising–Heisenberg double sawtooth frustrated ladder

Science.gov (United States)

Arian Zad, Hamid; Ananikian, Nerses

2018-04-01

The mixed spin-(1,1/2) Ising–Heisenberg double sawtooth ladder containing a mixture of both spin-1 and spin-1/2 nodal atoms, and the spin-1/2 interstitial dimers are approximately solved by the transfer-matrix method. Here, we study in detail the ground-state phase diagrams, also influences of the bilinear exchange coupling on the rungs and cyclic four-spin exchange interaction in square plaquette of each block on the magnetization and magnetic susceptibility of the suggested ladder at low temperature. Such a double sawtooth ladder may be found in a Shastry-Sutherland lattice-type. In spite of the spin ordering of odd and even blocks being different from each other, due to the commutation relation between all different block Hamiltonians, phase diagrams, magnetization behavior and thermodynamic properties of the model are the same for odd and even blocks. We show that at low temperature, both exchange couplings can change the quality and quantity of the magnetization plateaus versus the magnetic field changes. Specially, we find a new magnetization plateau M/Ms= 5/6 for this model. Besides, we examine the magnetic susceptibility and specific heat of the model in detail. It is proven that behaviors of the magnetization and the magnetic susceptibility coincide at low temperature. The specific heat displays diverse temperature dependencies, which include a Schottky-type peak at a special temperature interval. We observe that with increase of the bilinear exchange coupling on the rungs, second peak temperature dependence grows.

O3 fast and simple treatment-enhanced p-doped in Spiro-MeOTAD for CH3NH3I vapor-assisted processed CH3NH3PbI3 perovskite solar cells

Institute of Scientific and Technical Information of China (English)

En-Dong Jia; Xi Lou; Chun-Lan Zhou; Wei-Chang Hao; Wen-Jing Wang

2017-01-01

We demonstrate a simple and fast post-deposition treatment with high process compatibility on the hole transport material (HTM) Spiro-MeOTAD in vapor-assisted solution processed methylammonium lead triiodide (CH3NH3PbI3)-based solar cells.The prepared Co-doped p-type Spiro-MeOTAD films are treated by O3 at room temperature for 5 min,10 min,and 20 min,respectively,prior to the deposition of the metal electrodes.Compared with the traditional oxidation of Spiro-MeOTAD films overnight in dry air,our fast O3 treatment of HTM at room temperature only needs just 10 min,and a relative 40.3％ increment in the power conversion efficiency is observed with respect to the result of without-treated perovskite solar cells.This improvement of efficiency is mainly attributed to the obvious increase of the fill factor and short-circuit current density,despite a slight decrease in the open-circuit voltage.Ultraviolet photoelectron spectroscopy (UPS) and Hall effect measurement method are employed in our study to determine the changes of properties after O3 treatment in HTM.It is found that after the HTM is exposed to O3,its p-type doping level is enhanced.The enhancement of conductivity and Hall mobility of the film,resulting from the improvement in p-doping level of HTM,leads to better performances of perovskite solar cells.Best power conversion efficiencies (PCEs) of 13.05％ and 16.39％ are achieved with most properly optimized HTM via CH3NH3I vapor-assisted method and traditional single-step method respectively.

Single-particle potential from resummed ladder diagrams

International Nuclear Information System (INIS)

Kaiser, N.

2013-01-01

A recent work on the resummation of fermionic in-medium ladder diagrams to all orders is extended by calculating the complex single-particle potential U(p, k f ) + i W(p, k f ) p > k f . The on-shell single-particle potential is constructed by means of a complex-valued in-medium loop that includes corrections from a test particle of momentum vector p added to the filled Fermi sea. The single-particle potential U(k f , k f ) at the Fermi surface as obtained from the resummation of the combined particle and hole ladder diagrams is shown to satisfy the Hugenholtz-Van-Hove theorem. The perturbative contributions at various orders a n in the scattering length are deduced and checked against the known analytical results at order a 1 and a 2 . The limit a → ∞ is studied as a special case and a strong momentum dependence of the real (and imaginary) single-particle potential is found. This feature indicates an instability against a phase transition to a state with an empty shell inside the Fermi sphere such that the density gets reduced by about 5%. The imaginary single-particle potential vanishes linearly at the Fermi surface. For comparison, the same analysis is performed for the resummed particle-particle ladder diagrams alone. In this truncation an instability for hole excitations near the Fermi surface is found at strong coupling. For the set of particle-hole ring diagrams the single-particle potential is calculated as well. Furthermore, the resummation of in-medium ladder diagrams to all orders is studied for a two-dimensional Fermi gas with a short-range two-body contact interaction. (orig.)

Excitation spectrum of Heisenberg spin ladders

International Nuclear Information System (INIS)

Barnes, T.; Dagotto, E.; Riera, J.; Swanson, E.S.

1993-01-01

Heisenberg antiferromagnetic spin ''ladders'' (two coupled spin chains) are low-dimensional magnetic systems which for S=1/2 interpolate between half-integer-spin chains, when the chains are decoupled, and effective integer-spin one-dimensional chains in the strong-coupling limit. The spin-1/2 ladder may be realized in nature by vanadyl pyrophosphate, (VO) 2 P 2 O 7 . In this paper we apply strong-coupling perturbation theory, spin-wave theory, Lanczos techniques, and a Monte Carlo method to determine the ground-state energy and the low-lying excitation spectrum of the ladder. We find evidence of a nonzero spin gap for all interchain couplings J perpendicular >0. A band of spin-triplet excitations above the gap is also analyzed. These excitations are unusual for an antiferromagnet, since their long-wavelength dispersion relation behaves as (k-k 0 ) 2 (in the strong-coupling limit J perpendicular much-gt J, where J is the in-chain antiferromagnetic coupling). Their band is folded, with a minimum energy at k 0 =π, and a maximum between k 1 =π/2 (for J perpendicular =0) and 0 (for J perpendicular =∞). We also give numerical results for the dynamical structure factor S(q,ω), which can be determined in neutron scattering experiments. Finally, possible experimental techniques for studying the excitation spectrum are discussed

Non-ladder extended renormalization group analysis of the dynamical chiral symmetry breaking

Energy Technology Data Exchange (ETDEWEB)

Aoki, Ken-Ichi; Takagi, Kaoru; Terao, Haruhiko; Tomoyose, Masashi [Kanazawa Univ., Inst. for Theoretical Physics, Kanazawa, Ishikawa (Japan)

2000-04-01

The order parameters of dynamical chiral symmetry breaking in QCD, the dynamical mass of quarks and the chiral condensates, are evaluated by numerically solving the non-perturbative renormalization group (NPRG) equations. We employ an approximation scheme beyond 'the ladder', that is, beyond the (improved) ladder Schwinger-Dyson equations. The chiral condensates are enhanced in comparison with the ladder approximation, which is phenomenologically favorable. The gauge dependence of the order parameters is reduced significantly in this scheme. (author)

Non-ladder extended renormalization group analysis of the dynamical chiral symmetry breaking

International Nuclear Information System (INIS)

Aoki, Ken-Ichi; Takagi, Kaoru; Terao, Haruhiko; Tomoyose, Masashi

2000-01-01

The order parameters of dynamical chiral symmetry breaking in QCD, the dynamical mass of quarks and the chiral condensates, are evaluated by numerically solving the non-perturbative renormalization group (NPRG) equations. We employ an approximation scheme beyond 'the ladder', that is, beyond the (improved) ladder Schwinger-Dyson equations. The chiral condensates are enhanced in comparison with the ladder approximation, which is phenomenologically favorable. The gauge dependence of the order parameters is reduced significantly in this scheme. (author)

Laddering em pesquisa de marketing

Directory of Open Access Journals (Sweden)

Tânia Modesto Veludo-de-Oliveira

Full Text Available O artigo discute a técnica de pesquisa laddering em marketing, considerando a proposta de renovação de conhecimentos sobre metodologia na área. Para isso investiga diversos estudos, artigos e pesquisas que tratam do assunto em nível nacional e internacional. O conceito de cadeias meios-fins é abordado pela estrutura teórica que fundamenta a técnica, ligando atributos, conseqüências percebidas do consumo e valores pessoais relativos a um produto. O artigo segue com a explicação dos procedimentos de campo, como a entrevista e a análise dos dados. A laddering é um instrumento de pesquisa qualitativa bastante útil e poderoso, mas ainda pouco utilizado tanto por acadêmicos como por profissionais de mercado, no Brasil, provavelmente por desconhecimento e pouca divulgação. Cabe, portanto, uma maior disseminação de seu uso.

Nested Bethe Ansatz for Spin Ladder Model with Open Boundary Conditions

International Nuclear Information System (INIS)

Wu Junfang; Zhang Chunmin; Yue Ruihong; Li Runling

2005-01-01

The nested Bethe ansatz (BA) method is applied to find the eigenvalues and the eigenvectors of the transfer matrix for spin-ladder model with open boundary conditions. Based on the reflection equation, we find the general diagonal solution, which determines the general boundary interaction in the Hamiltonian. We introduce the spin-ladder model with open boundary conditions. By finding the solution K ± of the reflection equation which determines the nontrivial boundary terms in the Hamiltonian, we diagonalize the transfer matrix of the spin-ladder model with open boundary conditions in the framework of nested BA.

A co-flow-focusing monodisperse microbubble generator

KAUST Repository

Zhang, Jiaming; Li, Erqiang; Thoroddsen, Sigurdur T

2014-01-01

We use a simple and inexpensive microfluidic device, which is based on microscope glass slides and two tapered glass capillaries, to produce monodisperse microbubbles. The innermost capillary used for transporting the gas is inserted into the second capillary, with its 2 μm sharp tip aligned with the center of the converging-diverging throat of the second capillary. This configuration provides a small and smooth gas flow rate, and a high velocity gradient at the tube outlet. Highly monodisperse microbubbles with diameters ranging from 3.5 to 60 microns have been successfully produced at a rate of up to 40 kHz. A simple scaling law, which is based on the capillary number and liquid-to-gas flow rate ratio, successfully predicts the bubble size. © 2014 IOP Publishing Ltd.

A co-flow-focusing monodisperse microbubble generator

KAUST Repository

Zhang, Jiaming

2014-02-14

We use a simple and inexpensive microfluidic device, which is based on microscope glass slides and two tapered glass capillaries, to produce monodisperse microbubbles. The innermost capillary used for transporting the gas is inserted into the second capillary, with its 2 μm sharp tip aligned with the center of the converging-diverging throat of the second capillary. This configuration provides a small and smooth gas flow rate, and a high velocity gradient at the tube outlet. Highly monodisperse microbubbles with diameters ranging from 3.5 to 60 microns have been successfully produced at a rate of up to 40 kHz. A simple scaling law, which is based on the capillary number and liquid-to-gas flow rate ratio, successfully predicts the bubble size. © 2014 IOP Publishing Ltd.

Corrosion Control Specialist Career Ladder AFSC 53530, 53550, 53570, and 53690. Occupational Survey Report.

Science.gov (United States)

Air Force Occupational Measurement Center, Lackland AFB, TX.

The report describes the results of a detailed occupational survey of the corrosion control career ladder. Responses to a 457-task, time rating inventory from 1,015 personnel (representing 64 percent of the career field) were analyzed to produce seven specific findings and the career ladder structure. The career ladder includes a variety of jobs…

The chiral Ward-Takahashi identity in the ladder approximation

International Nuclear Information System (INIS)

Kugo, Taichiro; Mitchard, M.G.

1992-01-01

We show that the ladder approximation to the Schwinger-Dyson and Bethe-Salpeter equations preserves the Ward-Takahashi identity for the axial vector vertex if and only if we use the gluon momentum as the argument of the running coupling constant. However, in the usual Landau gauge this is inconsistent with the vector Ward identity. We propose a new method for making the ladder approximation scheme consistent with both vector and axial vector Ward identities. (orig.)

Improved Photoresponse Performance of Self-Powered ZnO/Spiro-MeOTAD Heterojunction Ultraviolet Photodetector by Piezo-Phototronic Effect.

Science.gov (United States)

Shen, Yanwei; Yan, Xiaoqin; Si, Haonan; Lin, Pei; Liu, Yichong; Sun, Yihui; Zhang, Yue

2016-03-09

Strain-induced piezoelectric potential (piezopotential) within wurtzite-structured ZnO can engineer the energy-band structure at a contact or a junction and, thus, enhance the performance of corresponding optoelectronic devices by effectively tuning the charge carriers' separation and transport. Here, we report the fabrication of a flexible self-powered ZnO/Spiro-MeOTAD hybrid heterojunction ultraviolet photodetector (UV PD). The obtained device has a fast and stable response to the UV light illumination at zero bias. Together with responsivity and detectivity, the photocurrent can be increased about 1-fold upon applying a 0.753% tensile strain. The enhanced performance can be attributed to more efficient separation and transport of photogenerated electron-hole pairs, which is favored by the positive piezopotential modulated energy-band structure at the ZnO-Spiro-MeOTAD interface. This study demonstrates a promising approach to optimize the performance of a photodetector made of piezoelectric semiconductor materials through straining.

Ladder physics in the spin fermion model

Science.gov (United States)

Tsvelik, A. M.

2017-05-01

A link is established between the spin fermion (SF) model of the cuprates and the approach based on the analogy between the physics of doped Mott insulators in two dimensions and the physics of fermionic ladders. This enables one to use nonperturbative results derived for fermionic ladders to move beyond the large-N approximation in the SF model. It is shown that the paramagnon exchange postulated in the SF model has exactly the right form to facilitate the emergence of the fully gapped d -Mott state in the region of the Brillouin zone at the hot spots of the Fermi surface. Hence, the SF model provides an adequate description of the pseudogap.

Ladder physics in the spin fermion model

International Nuclear Information System (INIS)

Tsvelik, A. M.

2017-01-01

A link is established between the spin fermion (SF) model of the cuprates and the approach based on the analogy between the physics of doped Mott insulators in two dimensions and the physics of fermionic ladders. This enables one to use nonperturbative results derived for fermionic ladders to move beyond the large-N approximation in the SF model. Here, it is shown that the paramagnon exchange postulated in the SF model has exactly the right form to facilitate the emergence of the fully gapped d-Mott state in the region of the Brillouin zone at the hot spots of the Fermi surface. Hence, the SF model provides an adequate description of the pseudogap.

Template synthesis of highly crystalline and monodisperse iron oxide pigments of nanosize

International Nuclear Information System (INIS)

Sreeram, Kalarical Janardhanan; Indumathy, Ramasamy; Rajaram, Ananthanarayanan; Nair, Balachandran Unni; Ramasami, Thirumalachari

2006-01-01

Synthesis of highly crystalline and monodisperse iron oxide nanoparticles is reported. The separation of Fe centers through site-specific binding to a polysaccharide-alginate matrix enables the generation of particles with a monodisperse or narrow size distribution character, resulting in transparent pigments. Site-specific interactions coupled with gel like character of alginate is proposed as the mechanism behind generation of lower particle sizes. Alginate-Fe complexes developed were subjected to heat treatment to provide for crystalline character and development of hematite (α-Fe 2 O 3 ). Conditions most ideal for achieving monodispersity and lower sizes have been optimized and confirmed through microscopic and photon correlation spectroscopic measurements

Dynamic parameterization and ladder operators for the Kratzer molecular potential

International Nuclear Information System (INIS)

Devi, O Babynanda; Singh, C Amuba

2014-01-01

Introducing independent parameters k and δ to represent the strength of the attractive and repulsive components, respectively, we write the Kratzer molecular potential as V(k,δ)=(ℏ 2 /2 m)(−k/r+δ(δ−1)/r 2 ). This parameterisation is not only natural, but also convenient for the construction of ladder operators for the system. Adopting the straightforward method of deriving recurrence relations among confluent hypergeometric functions, we construct seven pairs of ladder operators for the Kratzer potential system. Detailed analysis of the laddering actions of these operators is given to show that they connect eigenstates of equal energy but belong to a hierarchy of Kratzer potential systems corresponding to different values of the parameters k and δ. Significantly, it is pointed out that it may not be possible to construct, in the position representation, a ladder operator which would connect different eigenstates belonging to the same potential V(k,δ). Transition to the hydrogen atom case is discussed. A number (14 altogether) of functional relations among the confluent hypergeometric functions have been derived and reported separately in an appendix. (paper)

Estimating Ladder Fuels: A New Approach Combining Field Photography with LiDAR

Directory of Open Access Journals (Sweden)

Heather A. Kramer

2016-09-01

Full Text Available Forests historically associated with frequent fire have changed dramatically due to fire suppression and past harvesting over the last century. The buildup of ladder fuels, which carry fire from the surface of the forest floor to tree crowns, is one of the critical changes, and it has contributed to uncharacteristically large and severe fires. The abundance of ladder fuels makes it difficult to return these forests to their natural fire regime or to meet management objectives. Despite the importance of ladder fuels, methods for quantifying them are limited and imprecise. LiDAR (Light Detection and Ranging, a form of active remote sensing, is able to estimate many aspects of forest structure across a landscape. This study investigates a new method for quantifying ladder fuel in the field (using photographs with a calibration banner and remotely (using LiDAR data. We apply these new techniques in the Klamath Mountains of Northern California to predict ladder fuel levels across the study area. Our results demonstrate a new utility of LiDAR data to identify fire hazard and areas in need of fuels reduction.

Dynamic analysis of maritime gasbag-type floating bridge subjected to moving loads

Directory of Open Access Journals (Sweden)

Huan-huan Wang

2016-03-01

Full Text Available This paper studied the dynamic response of a new gasbag-type floating bridge under the effect of a moving load. The arbitrary Lagrangian-Eulerian (ALE method was used to simulate the movement of seawater and air, and the penalty-based method was used to study the coupling between gasbags and fluid. A three-dimensional finite element model of the floating bridge was established, and the numerical model was verified by comparing with the experimental results. In order to prevent resonance, the natural frequencies and flexural mode shapes were analyzed. Based on the initial state analysis, the dynamic responses of the floating bridge subjected to different moving loads were investigated. Vertical displacements and radial deformations of gasbags under different loads were compared, and principal stress distributions of gasbags were researched while driving. The hinge forces between adjacent modules were calculated to ensure the connection strength. Besides, the floating bridge under wave impacting was analyzed. Those results can provide references for the analysis and design of this new floating bridge.

Evaluation through research of a three-track career ladder program for registered nurses.

Science.gov (United States)

Korman, Carol; Eliades, Aris Beoglos

2010-01-01

A descriptive study design was employed to survey registered nurse participants in a career ladder program comprising of three tracks: clinical, education, and management. Findings indicate that participation allows nurses of varying education preparation and roles to demonstrate professional development. Implications for staff development include efficacy of the online survey technique, provision of a reliable tool to evaluate a career ladder, and evaluation of a career ladder that includes the staff development educator.

Synthesis of Monodisperse Iron Oxide Nanoparticles without Surfactants

Directory of Open Access Journals (Sweden)

Xiao-Chen Yang

2014-01-01

Full Text Available Monodisperse iron oxide nanoparticles could be successfully synthesized with two kinds of precipitants through a precipitation method. As-prepared nanoparticles in the size around 10 nm with regular spherical-like shape were achieved by adjusting pH values. NaOH and NH3·H2O were used as two precipitants for comparison. The average size of nanoparticles with NH3·H2O precipitant got smaller and represented better dispersibility, while nanoparticles with NaOH precipitant represented better magnetic property. This work provided a simple method without using any organic solvents, organic metal salts, or surfactants which could easily obtain monodisperse nanoparticles with tunable morphology.

Development of a new-type super-long bridge; Chochotaikyo ni tekigoshita shinkeishiki kyoryo no kaihatsu

Energy Technology Data Exchange (ETDEWEB)

Ogawa, K.; Shimodoio, H.; Saito, T.; Nogami, C.; Oryu, T.; Morikawa, M. [Kawasaki Heavy Industries, Ltd., Kobe (Japan)

1998-12-20

In order to realize large strait-crossing projects in the near future, it is necessary to develop a new type of super-long span bridge, which has a superior aerodynamic stability and is cost effective. We have been proposed a new type of suspension bridge using a 2-box and 1-box combined girder to apply to such a project And this time, we propose the cable stayed suspension bridge using a 2- box and 1-box combined girder aiming for improvement of aerodynamic stability with increase of torsional rigidity. This paper describes the performance of this cable stayed suspension bridge obtained from aerodynamic analysis. As a result, it can be confirmed that this newly developed cable stayed suspension system has fine characteristics and shows more potential for economical construction than the early proposed suspension system. (author)

Dissipation, Voltage Profile and Levy Dragon in a Special Ladder Network

Science.gov (United States)

Ucak, C.

2009-01-01

A ladder network constructed by an elementary two-terminal network consisting of a parallel resistor-inductor block in series with a parallel resistor-capacitor block sometimes is said to have a non-dispersive dissipative response. This special ladder network is created iteratively by replacing the elementary two-terminal network in place of the…

Dynamic Behaviour of Different Types of Cable-Stayed Bridges Due to Earthquake Loads

Directory of Open Access Journals (Sweden)

Alireza Mirza Goltabar Roshan

2016-12-01

Full Text Available Construction of large-scale structures has been considered as one of the human's main achievements.  With their suitable view and high economical aspects, High-strength steel cables have been developed for analysis and erection of cable-stayed bridges in light of high speed development in computer technology. This type of bridges, while providing different behavior due to cable flexibility, has been recognized as one of the most practical choices for mid to large span bridges. This paper studies the non-linear dynamic behavior of cable bridges and the effect of some parameters (such as cable arrangement and shape of pylon on them. For this purpose, CSI Bridge software with the direct integration method of dynamic analysis has been used and the behavior of structure under different earthquake components has been analyzed for various conditions of cable arrangements and pylon shapes. Results indicate that the most suitable behavior would be for cable bridges with H-shape pylons arranged in series and also with A-shape pylons in radial arrangement.

3+ and [Sb13Se16Br2] 5+ - Double and quadruple spiro cubanes from ionic liquids

KAUST Repository

Ahmed, Ejaz

2014-01-08

The reaction of antimony and selenium in the bromine-rich Lewis acidic ionic liquid [BMIm]Br·4.7AlBr3 (BMIm: 1-butyl-3- methylimidazolium) in the presence of a small amount of NbCl5 at 160 °C yielded dark-red crystals of [Sb7Se8Br 2][AlX4]3. For X = Cl0.15(1)Br 0.85(1), the compound is isostructural to [Sb7S 8Br2][AlCl4]3 [P212 121, a = 12.5132(5) Å, b = 17.7394(6) Å, c = 18.3013(6) Å]. For a higher chlorine content, X = Cl 0.58(1)Br0.42(1), a slightly disordered variant with a bisected unit cell is found [P21212, a = 12.3757(3) Å, b = 17.4116(5) Å, c = 9.0420(2) Å]. The [Sb 7Se8Br2]3+ heteropolycation (C 2 symmetry) is a spiro double-cubane with an antimony atom on the shared corner. From this distorted octahedrally coordinated central atom, tricoordinate selenium and antimony atoms alternate in the bonding sequence. The terminal antimony atoms each bind to a bromine atom. Quantum chemical calculations confirm polar covalent Sb-Se bonding within the cubes and indicate three-center, four-electron bonds for the six-coordinate spiro atoms. The calculated charge distribution reflects the electron-donor role of the antimony atoms. The use of a chlorine-rich ionic liquid resulted in the formation of triclinic [Sb13Se16Br2][AlX4] 5 with X = Cl0.80(1)Br0.20(1) [P$\\\\bar {1}$, a = 9.0842(5) Å, b = 19.607(1) Å, c = 21.511(1) Å, α = 64.116(6), β = 79.768(7), γ = 88.499(7)]. The cationic cluster [Sb13Se16Br2]5+ is a bromine-terminated spiro quadruple-cubane. This 31 atom concatenation of four cubes is assumed to be the largest known discrete main group polycation. A similar reaction in a chloride-free system yielded [Sb7Se 8Br2][Sb13Se16Br2] [AlBr4]8. In its monoclinic structure [P2/c, a = 27.214(5) Å, b = 9.383(2) Å, c = 22.917(4) Å, β = 101.68(1)], the two types of polycations alternate in layers along the a axis. In the series [Sb4+3nSe4+4nBr2](2+n)+, these cations are the members with n = 1 and 3. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGa

Convergence and periodic solutions for the input impedance of a standard ladder network

International Nuclear Information System (INIS)

Ucak, C; Acar, C

2007-01-01

The input impedance of an infinite ladder network is computed by using the recursive relation and by assuming that the input impedance does not change when a new block is added to the network. However, this assumption is not true in general and standard textbooks do not always treat these networks correctly. This paper develops a general solution to obtain the input impedance of a standard ladder network of impedances and admittances for any number of blocks. Then, this result is used to provide the convergence condition for the infinite ladder network. The conditions which lead to periodic input impedance are exploited. It is shown that there are infinite numbers of periodic points and no paradoxical behaviour exists in the standard ladder network

Application of monodisperse fibers and discs to evaluation of the aerodynamic particle sizer

International Nuclear Information System (INIS)

Hoover, M.D.; Lipowicz, P.J.; Hanson, R.W.; Yeh, H.C.; Casalnuovo, S.A.

1988-01-01

Monodisperse fibers, μm in width and lengths of 5, 10, 20, and 40 μm, as well as monodisperse discs, 2 4 8, or 12 μm in diameter, were prepared using an integrated circuit microchip fabrication technique. Particles were silicon dioxide with thickness of 1 μm. Examination of the particles using a scanning electron microscope showed that they were uniform in shape, with well-defined edges. The particles were suspended in distilled water and aerosolized with a Lovelace nebullizer. The monodisperse particles were used to evaluate the TSI Aerodynamic Particle Sizer (APS). Carbon fibers that were monodisperse in diameter (count median diameter 3.42 μm, geometric standard deviation 1.06) and polydisperse in length (count median length = 28 μm, geometric standard deviation 2.2) were also used. The APS was found to be insensitive to fiber length and only weakly sensitive to disc diameter. (author)

A Review and Modern Approach to LC Ladder Synthesis

Directory of Open Access Journals (Sweden)

Alexander J. Casson

2011-01-01

Full Text Available Ultra low power circuits require robust and reliable operation despite the unavoidable use of low currents and the weak inversion transistor operation region. For analogue domain filtering doubly terminated LC ladder based filter topologies are thus highly desirable as they have very low sensitivities to component values: non-exact component values have a minimal effect on the realised transfer function. However, not all transfer functions are suitable for implementation via a LC ladder prototype, and even when the transfer function is suitable the synthesis procedure is not trivial. The modern circuit designer can thus benefit from an updated treatment of this synthesis procedure. This paper presents a methodology for the design of doubly terminated LC ladder structures making use of the symbolic maths engines in programs such as MATLAB and MAPLE. The methodology is explained through the detailed synthesis of an example 7th order bandpass filter transfer function for use in electroencephalogram (EEG analysis.

Controlled parity switch of persistent currents in quantum ladders

Science.gov (United States)

Filippone, Michele; Bardyn, Charles-Edouard; Giamarchi, Thierry

2018-05-01

We investigate the behavior of persistent currents for a fixed number of noninteracting fermions in a periodic quantum ladder threaded by Aharonov-Bohm and transverse magnetic fluxes Φ and χ . We show that the coupling between ladder legs provides a way to effectively change the ground-state fermion-number parity, by varying χ . Specifically, we demonstrate that varying χ by 2 π (one flux quantum) leads to an apparent fermion-number parity switch. We find that persistent currents exhibit a robust 4 π periodicity as a function of χ , despite the fact that χ →χ +2 π leads to modifications of order 1 /N of the energy spectrum, where N is the number of sites in each ladder leg. We show that these parity-switch and 4 π periodicity effects are robust with respect to temperature and disorder, and outline potential physical realizations using cold atomic gases and photonic lattices, for bosonic analogs of the effects.

A one-dimensional ladder-like coordination polymer: poly[[hexa-aqua-bis(μ-5-nitro-benzene-1,3-dicarboxyl-ato-κO,O',O'')(μ-oxalato-κO,O':O'',O''')diyttrium(III)] trihydrate].

Science.gov (United States)

Fu, Zhong; Lin, Ying; Zhou, Yun-You; Zhang, Hong-Tao

2007-12-06

In the crystal structure of the title one-dimensional coordination polymer, [Y(2)(C(8)H(3)NO(6))(2)(C(2)O(4))(H(2)O)(6)]·3H(2)O, each Y(III) ion is bridged to its neighbours by two 5-nitro-benzene-1,3-dicarboxyl-ate (nbdc) dianions and one oxalate dianion (located on an inversion centre) to form a ladder-like polymeric structure. The two carboxylate groups of nbdc assume different modes of coordination, one is chelating whereas the other is monodentate. Three water mol-ecules coordinate to the Y(III) ion to complete an eight-coordinate distorted dodecahedral geometry. The ladder-like polymers are assembled together by hydrogen bonding and π-π stacking [centrio-centriod distance = 3.819 (9) Å] in the crystal structure.

Flow and Failure in Extension of Monodisperse Polymer Melts

DEFF Research Database (Denmark)

Rasmussen, Henrik K.

is commonly referred to be of either brittle (e.g. cohesive type) or of liquid (e.g. necking type) nature. Here the focus will be on monodisperse polymers, to study numerically the sample flow dynamics in dual wind-up extensional rheometers. The computations are within the ideas of the microstructural......It is well known that failure or rupture phenomenon appears in the extension of polymer melts. These appear not only as failure in extension rheometers, but also as sharkskin, developments of holes in thin polymeric films etc. Sometime these ruptures appear spontaneous as well. The rupture...... 'interchain pressure' theory based on the molecular stress function constitutive model for the polymer melt flow. The purpose is twofold. Primarily to present to what extend the experimentally observed failure, appearing during or after (e.g. as a spontaneous failure) extension, can be explained within...

Dynamic analysis of maritime gasbag-type floating bridge subjected to moving loads

OpenAIRE

Huan-huan Wang; Xian-long Jin

2016-01-01

This paper studied the dynamic response of a new gasbag-type floating bridge under the effect of a moving load. The arbitrary Lagrangian-Eulerian (ALE) method was used to simulate the movement of seawater and air, and the penalty-based method was used to study the coupling between gasbags and fluid. A three-dimensional finite element model of the floating bridge was established, and the numerical model was verified by comparing with the experimental results. In order to prevent resonance, the...

A spiro-bifluorene based 3D electron acceptor with dicyanovinylene substitution for solution-processed non-fullerene organic solar cells

KAUST Repository

Xia, Debin

2015-04-20

A novel electron acceptor, namely 2,2′-(12H,12′H-10,10′-spirobi[indeno[2,1-b]fluorene]-12,12′-diylidene)dimalononitrile (4CN-spiro), exhibiting a three-dimensional molecular structure was synthesized and its thermal, photophysical, electrochemical, crystal, and photovoltaic properties were investigated. The novel acceptor exhibits excellent thermal stability with a decomposition temperature of 460 °C, an absorption extending to 600 nm, and a LUMO level of −3.63 eV. Solution processed bulk-heterojunction (BHJ) organic solar cells were fabricated using 4CN-spiro as an acceptor and polythieno[3,4-b]-thiophene-co-benzodithiophene (PTB7) as a donor polymer. The effect of the donor-to-acceptor ratio and processing conditions on the device performance was investigated. A device processed from tetrachloroethane with a donor to acceptor weight ratio of 1 : 1 yielded a power conversion efficiency (PCE) of 0.80%.

High-speed monodisperse droplet generation by ultrasonically controlled micro-jet breakup

Science.gov (United States)

Frommhold, Philipp Erhard; Lippert, Alexander; Holsteyns, Frank Ludwig; Mettin, Robert

2014-04-01

A liquid jet that is ejected from a nozzle into air will disintegrate into drops via the well-known Plateau-Rayleigh instability within a certain range of Ohnesorge and Reynolds numbers. With the focus on the micrometer scale, we investigate the control of this process by superimposing a suitable ultrasonic signal, which causes the jet to break up into a very precise train of monodisperse droplets. The jet leaves a pressurized container of liquid via a small orifice of about 20 μm diameter. The break-up process and the emerging droplets are recorded via high-speed imaging. An extended parameter study of exit speed and ultrasonic frequency is carried out for deionized water to evaluate the jet's state and the subsequent generation of monodisperse droplets. Maximum exit velocities obtained reach almost 120 m s-1, and frequencies have been applied up to 1.8 MHz. Functionality of the method is confirmed for five additional liquids for moderate jet velocities 38 m s-1. For the uncontrolled jet disintegration, the drop size spectra revealed broad distributions and downstream drop growth by collision, while the acoustic control generated monodisperse droplets with a standard deviation less than 0.5 %. By adjustment of the acoustic excitation frequency, drop diameters could be tuned continuously from about 30 to 50 μm for all exit speeds. Good agreement to former experiments and theoretical approaches is found for the relation of overpressure and jet exit speed, and for the observed stability regions of monodisperse droplet generation in the parameter plane of jet speed and acoustic excitation frequency. Fitting of two free parameters of the general theory to the liquids and nozzles used is found to yield an even higher precision. Furthermore, the high-velocity instability limit of regular jet breakup described by von Ohnesorge has been superseded by more than a factor of two without entering the wind-induced instability regime, and monodisperse droplet generation was

ABC of ladder operators for rationally extended quantum harmonic oscillator systems

Science.gov (United States)

Cariñena, José F.; Plyushchay, Mikhail S.

2017-07-01

The problem of construction of ladder operators for rationally extended quantum harmonic oscillator (REQHO) systems of a general form is investigated in the light of existence of different schemes of the Darboux-Crum-Krein-Adler transformations by which such systems can be generated from the quantum harmonic oscillator. Any REQHO system is characterized by the number of separated states in its spectrum, the number of ‘valence bands’ in which the separated states are organized, and by the total number of the missing energy levels and their position. All these peculiarities of a REQHO system are shown to be detected and reflected by a trinity (A^+/- , B^+/- , C^+/-) of the basic (primary) lowering and raising ladder operators related between themselves by certain algebraic identities with coefficients polynomially-dependent on the Hamiltonian. We show that all the secondary, higher-order ladder operators are obtainable by a composition of the basic ladder operators of the trinity which form the set of the spectrum-generating operators. Each trinity, in turn, can be constructed from the intertwining operators of the two complementary minimal schemes of the Darboux-Crum-Krein-Adler transformations.

29 CFR 1910.27 - Fixed ladders.

Science.gov (United States)

2010-07-01

...) All rungs shall have a minimum diameter of three-fourths inch for metal ladders, except as covered in... appurtenances shall be painted or otherwise treated to resist corrosion and rusting when location demands... areas under floors, are frequently located in an atmosphere that causes corrosion and rusting. To...

Hadron structure in the ladder model

International Nuclear Information System (INIS)

Soper, D.E.

1979-01-01

The (flavor non-singlet) Green's function to find a far-off-shell quark in a hadron is obtained in the renormalization group improved ladder model for QCD in the space-like axial gauge. Particular attention is paid to the role of the singularity in the gluon propagator. 4 figures

A one-dimensional ladder-like coordination polymer: poly[[hexaaquabis(μ-5-nitrobenzene-1,3-dicarboxylato-κ3O,O′,O′′(μ-oxalato-κ4O,O′:O′′,O′′′diyttrium(III] trihydrate

Directory of Open Access Journals (Sweden)

Zhong Fu

2008-01-01

Full Text Available In the crystal structure of the title one-dimensional coordination polymer, [Y2(C8H3NO62(C2O4(H2O6]·3H2O, each YIII ion is bridged to its neighbours by two 5-nitrobenzene-1,3-dicarboxylate (nbdc dianions and one oxalate dianion (located on an inversion centre to form a ladder-like polymeric structure. The two carboxylate groups of nbdc assume different modes of coordination, one is chelating whereas the other is monodentate. Three water molecules coordinate to the YIII ion to complete an eight-coordinate distorted dodecahedral geometry. The ladder-like polymers are assembled together by hydrogen bonding and π–π stacking [centrio–centriod distance = 3.819 (9 Å] in the crystal structure.

DUNDRUM Restriction-Intrusion of Liberty Ladders (DRILL) Audit Toolkit

LENUS (Irish Health Repository)

Kennedy, Harry G

2011-09-01

This series of rating \\'ladders\\' is intended to allow a quantitative and qualitative analysis of the use of restrictive and intrusive interventions as part of the therapeutic management of violence and aggression in psychiatric hospital settings. This is an evolving handbook. The ladders are currently organised to facilitate a behavioural analysis. Context, antecedents, behaviour, interventions, consequences are conceptualised as a series of events organised in temporal sequence so that causes, interactions and effects can be considered. The complexity of analysis possible is limited by the statistical power of the numbers of cases and events available. \\r\

A Continuous Game of Sankes and Ladders

Indian Academy of Sciences (India)

Home; Journals; Resonance – Journal of Science Education; Volume 14; Issue 8. The Control of Tuberculosis: A Continuous Game of Sankes and Ladders. T Ramakrishnan P Chandrasekhar. Classics Volume 14 Issue 8 August 2009 pp 820-834 ...

Double-resonance optical-pumping effect and ladder-type electromagnetically induced transparency signal without Doppler background in cesium atomic vapour cell

International Nuclear Information System (INIS)

Yang Bao-Dong; Gao Jing; Liang Qiang-Bing; Wang Jie; Zhang Tian-Cai; Wang Jun-Min

2011-01-01

In a Doppler-broadened ladder-type cesium atomic system (6S 1/2 -6P 3/2 -8S 1/2 ), this paper characterizes electromagnetically induced transparency (EIT) in two different experimental arrangements, and investigates the influence of the double-resonance optical-pumping (DROP) effect on EIT in both arrangements. When the probe laser is weak, DROP is explicitly suppressed. When the probe laser is moderate, population of the intermediate level (6P 3/2 F' = 5) is remarkable, therefore DROP is mixed with EIT. An interesting bimodal spectrum with the broad component due to DROP and the narrow part due to EIT has been clearly observed in cesium 6S 1/2 F = 4−6P 3/2 F' = 5−8S 1/2 F″ = 4 transitions. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

CERN Library | Sandrine Saison-Marsollier, Corinne Pralavorio and Michel Spiro present "Si tu devais me dessiner l’Univers…" | 10 December

CERN Multimedia

CERN Library

2015-01-01

Sandrine Saison-Marsollier, Corinne Pralavorio and Michel Spiro present Si tu devais me dessiner l’Univers… Thursday, 10 December 2015 at 3.30 p.m. at the Library, Building 52-1-052 Tea and coffee will be served at 3 p.m. In 2014, CERN launched an art competition for local primary schools. Children were asked to come up with questions about the universe, matter and working as a researcher. The initiative was so successful that it has been turned into a book that teachers can explore with their pupils, discussing the questions and discovering the answers together. The book is laid out in double-page spreads, with the child’s illustration on one page and the question and its answer opposite. The answers take the form of a short text written by Michel Spiro, the competition’s scientific advisor, together with a cultural quotation whose purpose is to highlight the close association between science, literature and philosophy. The questions include: What was there...

Cavity-induced artificial gauge field in a Bose-Hubbard ladder

Science.gov (United States)

Halati, Catalin-Mihai; Sheikhan, Ameneh; Kollath, Corinna

2017-12-01

We consider theoretically ultracold interacting bosonic atoms confined to quasi-one-dimensional ladder structures formed by optical lattices and coupled to the field of an optical cavity. The atoms can collect a spatial phase imprint during a cavity-assisted tunneling along a rung via Raman transitions employing a cavity mode and a transverse running wave pump beam. By adiabatic elimination of the cavity field we obtain an effective Hamiltonian for the bosonic atoms, with a self-consistency condition. Using the numerical density-matrix renormalization-group method, we obtain a rich steady-state diagram of self-organized steady states. Transitions between superfluid to Mott-insulating states occur, on top of which we can have Meissner, vortex liquid, and vortex lattice phases. Also a state that explicitly breaks the symmetry between the two legs of the ladder, namely, the biased-ladder phase, is dynamically stabilized. We investigate the influence that a trapping potential has on the stability of the self-organized phases.

Extracellular biosynthesis of monodispersed gold nanoparticles by a SAM capping route

International Nuclear Information System (INIS)

Wen Li; Lin Zhonghua; Gu Pingying; Zhou Jianzhang; Yao Bingxing; Chen Guoliang; Fu Jinkun

2009-01-01

Monodispersed gold nanoparticles capped with a self-assembled monolayer of dodecanethiol were biosynthesized extracellularly by an efficient, simple, and environmental friendly procedure, which involved the use of Bacillus megatherium D01 as the reducing agent and the use of dodecanethiol as the capping ligand at 26 o C. The kinetics of gold nanoparticle formation was followed by transmission electron microscope (TEM) and UV-vis spectroscopy. It was shown that reaction time was an important parameter in controlling the morphology of gold nanoparticles. The effect of thiol on the shape, size, and dispersity of gold nanoparticles was also studied. The results showed that the presence of thiol during the biosynthesis could induce the formation of small size gold nanoparticles (<2.5 nm), hold the shape of spherical nanoparticles, and promote the monodispersity of nanoparticles. Through the modulation of reaction time and the use of thiol, monodispersed spherical gold nanoparticles capped with thiol of 1.9 ± 0.8 nm size were formed by using Bacillus megatherium D01.

Extracellular biosynthesis of monodispersed gold nanoparticles by a SAM capping route

Energy Technology Data Exchange (ETDEWEB)

Wen Li [Xiamen University, Department of Chemistry, College of Chemistry and Chemical Engineering (China); Lin Zhonghua [Xiamen University, State Key Laboratory of Physical Chemistry of Solid Surfaces (China); Gu Pingying [Xiamen University, Department of Chemistry, College of Chemistry and Chemical Engineering (China); Zhou Jianzhang [Xiamen University, State Key Laboratory of Physical Chemistry of Solid Surfaces (China); Yao Bingxing [Xiamen University, School of Life Sciences (China); Chen Guoliang; Fu Jinkun, E-mail: wenli_1976@163.co [Xiamen University, Department of Chemistry, College of Chemistry and Chemical Engineering (China)

2009-02-15

Monodispersed gold nanoparticles capped with a self-assembled monolayer of dodecanethiol were biosynthesized extracellularly by an efficient, simple, and environmental friendly procedure, which involved the use of Bacillus megatherium D01 as the reducing agent and the use of dodecanethiol as the capping ligand at 26 {sup o}C. The kinetics of gold nanoparticle formation was followed by transmission electron microscope (TEM) and UV-vis spectroscopy. It was shown that reaction time was an important parameter in controlling the morphology of gold nanoparticles. The effect of thiol on the shape, size, and dispersity of gold nanoparticles was also studied. The results showed that the presence of thiol during the biosynthesis could induce the formation of small size gold nanoparticles (<2.5 nm), hold the shape of spherical nanoparticles, and promote the monodispersity of nanoparticles. Through the modulation of reaction time and the use of thiol, monodispersed spherical gold nanoparticles capped with thiol of 1.9 {+-} 0.8 nm size were formed by using Bacillus megatherium D01.

Estimating ladder fuels: a new approach combining field photography with LiDAR

Science.gov (United States)

Heather Kramer; Brandon Collins; Frank Lake; Marek Jakubowski; Scott Stephens; Maggi Kelly

2016-01-01

Forests historically associated with frequent fire have changed dramatically due to fire suppression and past harvesting over the last century. The buildup of ladder fuels, which carry fire from the surface of the forest floor to tree crowns, is one of the critical changes, and it has contributed to uncharacteristically large and severe fires. The abundance of ladder...

Arch-Axis Coefficient Optimization of Long-Span Deck-Type Concrete-Filled Steel Tubular Arch Bridge

Science.gov (United States)

Liu, Q. J.; Wan, S.; Liu, H. C.

2017-11-01

This paper is based on Nanpuxi super major bridge which is under construction and starts from Wencheng Zhejiang province to Taishun highway. A finite element model of the whole bridge is constructed using Midas Civil finite element software. The most adverse load combination in the specification is taken into consideration to determine the method of calculating the arch-axis coefficient of long-span deck-type concrete-filled steel tubular arch bridge. By doing this, this paper aims at providing references for similar engineering projects.

Crossflow type silicon microchannel substrate monodispersion oil-in-water emulsion manufacture; Kurosufuro gata shirikon maikuro chaneru kiban wo mochiita tanbunsan suchuyu emarushon no sakusei

Energy Technology Data Exchange (ETDEWEB)

Kawakatsu, Takahiro [Tohoku University, Miyagi (Japan). Graduate School; Komori, Hideai; Najima, Mitsutashi; Kikuchi, Yuji; Yonemoto, Toshikuni

1999-05-05

The new technique, which continuously produced the monodispersion oil-in-water (0/W) emulsion using the crossflow type silicon microchannel substrate, was developed. On the silicon monocrystal substrate, the watercourse as the liquid of the continuous phase flowed was produced, and the column of the equal slit of the size in both walls of the watercourse was precisely processed. By closing the upper part in the slit by the clamp of the flat glass board in the microchannel substrate, the microchannel column was formed. Through the microchannel, the oil droplet in which the size was even was formed by sending out the oil (triolein) in the water (0.3wt% sodium lauryl sulfate aqueous solution) of continuous phase which is flowing in respect of the watercourse. The size of the oil droplet is greatly dependent on the structure of the microchannel regulated by microchannel width, microchannel height and terrace length (the even part of which the microchannel exit was equipped). Monodispersion emulsion of 16,20 and 48 {mu}m at the average droplet diameter was formed by using microchannel substrate of the three types of which the structure differs. Droplet diameter decreased, when the substrate which formed large droplet of 48 {mu}m in which the water current quantity is 1.4x10{sup -2}mLmin{sup -1} was used, when the flow rate increased. However, there was no a flow rate at droplet diameter, even if it was made to change from 1.4x10{sup -2} to 2.4mLmin{sup -1}, 16 {mu}m 20 {mu}m small change. In all cases, the droplet size distribution was narrow, and the geometry standard deviation was under 1.03. (translated by NEDO)

Spiro annulation of cage polycycles via Grignard reaction and ring-closing metathesis as key steps

Directory of Open Access Journals (Sweden)

Sambasivarao Kotha

2015-08-01

Full Text Available A simple synthetic strategy to C2-symmetric bis-spiro-pyrano cage compound 7 involving ring-closing metathesis is reported. The hexacyclic dione 10 was prepared from simple and readily available starting materials such as 1,4-naphthoquinone and cyclopentadiene. The synthesis of an unprecedented octacyclic cage compound through intramolecular Diels–Alder (DA reaction as a key step is described. The structures of three new cage compounds 7, 12 and 18 were confirmed by single crystal X-ray diffraction studies.

Synthesis and electrochemical properties of a new benzimidazole derivative as the acceptor unit in donor–acceptor–donor type polymers

International Nuclear Information System (INIS)

Ozelcaglayan, Ali Can; Sendur, Merve; Akbasoglu, Naime; Apaydin, Dogukan Hazar; Cirpan, Ali; Toppare, Levent

2012-01-01

A new benzimidazole unit, 4′-(tert-butyl)spiro[benzo[d]imidazole-2,1′-cyclohexane] was synthesized and coupled with different donor units like 3-hexylthiophene and 3,4-ethylenedioxythiophene (EDOT) via Stille coupling. The donor–acceptor–donor (D–A–D) type monomers, 4′-(tert-butyl)-4,7-bis(4-hexylthiophen-2-yl) spiro[benzo[d]imidazole-2,1′-cyclohexane] (BIHT) and 4′-(tert-butyl)-4,7-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl) spiro[benzo[d]imidazole-2,1′-cyclohexane] (BIED) were electrochemically polymerized, their electrochemical and optical properties were investigated by cyclic voltammetry, UV–vis-NIR spectroscopy techniques. Effect of donor groups on the optical and electronic properties of polymer was studied.

Facile and Scalable Synthesis of Monodispersed Spherical Capsules with a Mesoporous Shell

KAUST Repository

Qi, Genggeng

2010-05-11

Monodispersed HMSs with tunable particle size and shell thickness were successfully synthesized using relatively concentrated polystyrene latex templates and a silica precursor in a weakly basic ethanol/water mixture. The particle size of the capsules can vary from 100 nm to micrometers. These highly engineered monodispersed capsules synthesized by a facile and scalable process may find applications in drug delivery, catalysis, separationm or as biological and chemical microreactors. © 2010 American Chemical Society.

Analysis of an "off-ladder" allele at the Penta D short tandem repeat locus.

Science.gov (United States)

Yang, Y L; Wang, J G; Wang, D X; Zhang, W Y; Liu, X J; Cao, J; Yang, S L

2015-11-25

Kinship testing of a father and his son from Guangxi, China, the location of the Zhuang minority people, was performed using the PowerPlex® 18D System with a short tandem repeat typing kit. The results indicated that both the father and his son had an off-ladder allele at the Penta D locus, with a genetic size larger than that of the maximal standard allelic ladder. To further identify this locus, monogenic amplification, gene cloning, and genetic sequencing were performed. Sequencing analysis demonstrated that the fragment size of the Penta D-OL locus was 469 bp and the core sequence was [AAAGA]21, also called Penta D-21. The rare Penta D-21 allele was found to be distributed among the Zhuang population from the Guangxi Zhuang Autonomous Region of China; therefore, this study improved the range of DNA data available for this locus and enhanced our ability for individual identification of gene loci.

Quantum entanglement and thermal reduced density matrices in fermion and spin systems on ladders

International Nuclear Information System (INIS)

Chen, Xiao; Fradkin, Eduardo

2013-01-01

Numerical studies of the reduced density matrix of a gapped spin-1/2 Heisenberg antiferromagnet on a two-leg ladder find that it has the same form as the Gibbs density matrix of a gapless spin-1/2 Heisenberg antiferromagnetic chain at a finite temperature determined by the spin gap of the ladder. We investigate this interesting result by considering a model of free fermions on a two-leg ladder (gapped by the inter-chain tunneling operator) and in spin systems on a ladder with a gapped ground state using exact solutions and several controlled approximations. We calculate the reduced density matrix and the entanglement entropy for a leg of the ladder (i.e. a cut made between the chains). In the fermionic system we find the exact form of the reduced density matrix for one of the chains and determine the entanglement spectrum explicitly. Here we find that in the weak tunneling limit of the ladder the entanglement entropy of one chain of the gapped ladder has a simple and universal form dictated by conformal invariance. In the case of the spin system, we consider the strong coupling limit by using perturbation theory and get the reduced density matrix by the Schmidt decomposition. The entanglement entropies of a general gapped system of two coupled conformal field theories (in 1 + 1 dimensions) are discussed using the replica trick and scaling arguments. We show that (1) for a system with a bulk gap the reduced density matrix has the form of a thermal density matrix, (2) the long-wavelength modes of one subsystem (a chain) of a gapped coupled system are always thermal, (3) the von Neumann entropy equals the thermodynamic entropy of one chain, and (4) the bulk gap plays the role of effective temperature. (paper)

Strength Analysis on Ship Ladder Using Finite Element Method

Science.gov (United States)

Budianto; Wahyudi, M. T.; Dinata, U.; Ruddianto; Eko P., M. M.

2018-01-01

In designing the ship’s structure, it should refer to the rules in accordance with applicable classification standards. In this case, designing Ladder (Staircase) on a Ferry Ship which is set up, it must be reviewed based on the loads during ship operations, either during sailing or at port operations. The classification rules in ship design refer to the calculation of the structure components described in Classification calculation method and can be analysed using the Finite Element Method. Classification Regulations used in the design of Ferry Ships used BKI (Bureau of Classification Indonesia). So the rules for the provision of material composition in the mechanical properties of the material should refer to the classification of the used vessel. The analysis in this structure used program structure packages based on Finite Element Method. By using structural analysis on Ladder (Ladder), it obtained strength and simulation structure that can withstand load 140 kg both in static condition, dynamic, and impact. Therefore, the result of the analysis included values of safety factors in the ship is to keep the structure safe but the strength of the structure is not excessive.

Spirocyclopropane-type sesquiterpene hydrocarbons from Schinus terebinthifolius Raddi.

Science.gov (United States)

Richter, Rita; von Reuss, Stephan H; König, Wilfried A

2010-08-01

The essential oil of Schinus terebinthifolius fruits was reinvestigated using GC and GC-MS techniques. Apart from several known compounds three sesquiterpene hydrocarbons with a carbon skeleton exhibiting the rare spiro(cyclopropane) moiety could be isolated by a combination of column chromatography and GLC. Structure assignments were carried out by NMR spectroscopy. These natural products are 9-spiro(cyclopropa)-4,4,8-trimethyl-2-methylenbicyclo[4.3.0]non-1(6)-ene (terebanene), 9-spiro(cyclopropa)-2,4,4,8-tetramethylbicyclo[4.3.0]nona-1,5-diene (teredenene), and (6R*,8R*)-9-spiro(cyclopropa)-2,4,4,8-tetramethylbicyclo[4.3.0]non-1-ene (terebinthene). Copyright 2010 Elsevier Ltd. All rights reserved.

Syringe-vacuum microfluidics: A portable technique to create monodisperse emulsions.

Science.gov (United States)

Abate, Adam R; Weitz, David A

2011-03-16

We present a simple method for creating monodisperse emulsions with microfluidic devices. Unlike conventional approaches that require bulky pumps, control computers, and expertise with device physics to operate devices, our method requires only the microfluidic device and a hand-operated syringe. The fluids needed for the emulsion are loaded into the device inlets, while the syringe is used to create a vacuum at the device outlet; this sucks the fluids through the channels, generating the drops. By controlling the hydrodynamic resistances of the channels using hydrodynamic resistors and valves, we are able to control the properties of the drops. This provides a simple and highly portable method for creating monodisperse emulsions.

Triptycene-based ladder monomers and polymers, methods of making each, and methods of use

KAUST Repository

Pinnau, Ingo; Ghanem, Bader; Swaidan, Raja

2015-01-01

Embodiments of the present disclosure provide for a triptycene-based A-B monomer, a method of making a triptycene-based A-B monomer, a triptycene-based ladder polymer, a method of making a triptycene-based ladder polymers, a method of using

Using career ladders to motivate and retain employees: an implementation success story.

Science.gov (United States)

Garletts, Joseph A

2002-01-01

In October 2000, Phoenix-based Sonora Quest Laboratories, LLC (SQL), commissioned The Gelfond Group to survey SQL employees. Responding to negative survey scores, SQL developed and implemented an entry-level career ladder for line staff of the specimen management/referral testing department. The program was piloted in February 2001, and was implemented fully shortly thereafter. The ladder was designed to provide job enrichment opportunities through company-conducted training and advancement provisions. It contained requirements for productivity and quality of work performed in addition to increasingly rigorous training and competency documentation. Employees were accountable for their own advancement and for ensuring that all documentation was complete. Advancement was automatic once requirements were completed. Pay increases accompanied each advancement on a predetermined scale. At the end of 12 months, employee turnover dropped from 39% to less than 20% annually. Both productivity and morale improved, and results on a second employee survey indicated dramatic improvement in five key areas. The career ladder concept has been replicated successfully in several other departments, including phlebotomy, and a six-tiered ladder is under development for the clinical laboratory. It will encompass CLA, MLT, and MT positions from entry level to technical coordinator.

Flexural and Shear Behavior of FRP Strengthened AASHTO Type Concrete Bridge Girders

Directory of Open Access Journals (Sweden)

Nur Yazdani

2016-01-01

Full Text Available Fiber-reinforced polymers (FRP are being increasingly used for the repair and strengthening of deteriorated or unsafe concrete structures, including structurally deficient concrete highway bridges. The behavior of FRP strengthened concrete bridge girders, including failure modes, failure loads, and deflections, can be determined using an analytical finite element modeling approach, as outlined in this paper. The differences in flexural versus shear FRP strengthening and comparison with available design guidelines are also beneficial to design professionals. In this paper, a common AASHTO type prestressed concrete bridge girder with FRP wrapping was analyzed using the ANSYS FEM software and the ACI analytical approach. Both flexural and shear FRP applications, including vertical and inclined shear strengthening, were examined. Results showed that FRP wrapping can significantly benefit concrete bridge girders in terms of flexure/shear capacity increase, deflection reduction, and crack control. The FRP strength was underutilized in the section selected herein, which could be addressed through decrease of the amount of FRP and prestressing steel used, thereby increasing the section ductility. The ACI approach produced comparable results to the FEM and can be effectively and conveniently used in design.

Access to unusual polycyclic spiro-enones from 2,2'-bis(allyloxy)-1,1'-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence.

Science.gov (United States)

Piedra, Estefanía; Francos, Javier; Nebra, Noel; Suárez, Francisco J; Díez, Josefina; Cadierno, Victorio

2011-07-21

Treatment of 2,2'-bis(allyloxy)-1,1'-binaphthyls with the first-generation Grubbs' carbene under MW-irradiation results in the formation of new polycyclic spiro-enones through an unprecedented RCM/Claisen sequence.

Characteristics of ITO electrode grown by linear facing target sputtering with ladder type magnetic arrangement for organic light emitting diodes

International Nuclear Information System (INIS)

Jeong, Jin-A; Kim, Han-Ki; Lee, Jae-Young; Lee, Jung-Hwan; Bae, Hyo-Dae; Tak, Yoon-Heung

2009-01-01

The preparation and characteristics of indium tin oxide (ITO) electrodes grown using a specially designed linear facing target sputtering (LFTS) system with a ladder type magnet arrangement for organic light emitting diodes (OLED) are described. It was found that the electrical and optical properties of the ITO electrode were critically dependent on the Ar/O 2 flow ratio, while its structural and surface properties remained fairly constant regardless of the Ar/O 2 flow ratio, due to the low substrate temperature during the plasma damage-free sputtering. Under the optimized conditions, we obtained an ITO electrode with the lowest sheet resistance of 39.4 Ω/sq and high transmittance of 90.1% (550 nm wavelength) at room temperature. This suggests that LFTS is a promising low temperature and plasma damage free sputtering technology for preparing high-quality ITO electrodes for OLEDs and flexible OLEDs at room temperature.

Logarithmic Exchange Kinetics in Monodisperse Copolymeric Micelles

Science.gov (United States)

García Daza, Fabián A.; Bonet Avalos, Josep; Mackie, Allan D.

2017-06-01

Experimental measurements of the relaxation kinetics of copolymeric surfactant exchange for micellar systems unexpectedly show a peculiar logarithmic decay. Several authors use polydispersity as an explanation for this behavior. However, in coarse-grained simulations that preserve microscopic details of the surfactants, we find evidence of the same logarithmic behavior. Since we use a strictly monodisperse distribution of chain lengths such a relaxation process cannot be attributed to polydispersity, but has to be caused by an inherent physical process characteristic of this type of system. This is supported by the fact that the decay is specifically logarithmic and not a power law with an exponent inherited from the particular polydispersity distribution of the sample. We suggest that the degeneracy of the energy states of the hydrophobic block in the core, which is broken on leaving the micelle, can qualitatively explain the broad distribution of energy barriers, which gives rise to the observed nonexponential relaxation.

One-particle versus two-particle crossover in weakly coupled Hubbard chains and ladders: perturbative renormalization group approach

International Nuclear Information System (INIS)

Kishine, Jun-Ichiro; Yonemitsu, Kenji

1998-01-01

Physical nature of dimensional crossovers in weakly coupled Hubbard chains and ladders has been discussed within the framework of the perturbative renormalization-group (PRG) approach. The difference between these two cases originates from different universality classes which the corresponding isolated systems belong to. In the present work, we discuss the nature of the dimensional crossovers in the weakly coupled chains and ladders, with emphasis on the difference between the two cases within the framework of the PRG approach. The difference of the universality class of the isolated chain and ladder profoundly affects the relevance or irrelevance of the inter-chain/ladder one-particle hopping. The strong coupling phase of the isolated ladder makes the one-particle process irrelevant so that the d-wave superconducting transition can be induced via the two-particle crossover in the weakly coupled ladders. The weak coupling phase of the isolated chain makes the one-particle process relevant so that the two-particle crossover can hardly be realized in the coupled chains. (Copyright (1998) World Scientific Publishing Co. Pte. Ltd)

BIOACTIVITIES AND MECHANISM OF SPIRO ENOL ETHER ANALOGUES AGAINST PIERIS RAPAE

Institute of Scientific and Technical Information of China (English)

Zhi-xiangZhang; Dong-meiCheng; Han-hongXu; Yu-linWu; andJun-faFan

2004-01-01

Nineteen kinds of spiro enol ether analogues were screened with larvae of Pieris rapae for antifeedant activity. The results showed that the antifeedant activity of compounds No.20 and No.12 was higher than others. In non-choice test, AFC50 values within 24 h of compounds No.20 and No.12 against 3rd instar larvae of P. rapae were 226.93ug/mL and 370.00ug/mL, and that in choice test against 4th larvae were 280.54 ug/mL and 398.88 ug/mL, respectively. Compd. No.20 could prolong the eggs hatch time and reduce the haemolymph content and the protein content in haemolymph of 4th instar larvae obviously. Compd. No.20 could protect tested leaves and control larvae of P. rapae effectively.

Synthesis of 5α-Androstane-17-spiro-δ-lactones with a 3-Keto, 3-Hydroxy, 3-Spirocarbamate or 3-Spiromorpholinone as Inhibitors of 17β-Hydroxysteroid Dehydrogenases

Directory of Open Access Journals (Sweden)

Donald Poirier

2013-01-01

Full Text Available We synthesized two series of androstane derivatives as inhibitors of type 3 and type 5 17β-hydroxysteroid dehydrogenases (17β-HSDs. In the first series, four monospiro derivatives at position C17 were prepared from androsterone (ADT or epi-ADT. After the protection of the alcohol at C3, the C17-ketone was alkylated with the lithium acetylide of tetrahydro-2-(but-3-ynyl-2-H-pyran, the triple bond was hydrogenated, the protecting groups hydrolysed and the alcohols oxidized to give the corresponding 3-keto-17-spiro-lactone derivative. The other three compounds were generated from this keto-lactone by reducing the ketone at C3, or by introducing one or two methyl groups. In the second series, two dispiro derivatives at C3 and C17 were prepared from epi-ADT. After introducing a spiro-δ-lactone at C17 and an oxirane at C3, an aminolysis of the oxirane with L-isoleucine methyl ester provided an amino alcohol, which was treated with triphosgene or sodium methylate to afford a carbamate- or a morpholinone-androstane derivative, respectively. These steroid derivatives inhibited 17β-HSD3 (14–88% at 1 μM; 46–94% at 10 μM and 17β-HSD5 (54–73% at 0.3 μM; 91–92% at 3 μM. They did not produce any androgenic activity and did not bind steroid (androgen, estrogen, glucocorticoid and progestin receptors, suggesting a good profile for prostate cancer therapy.

Spiro(phosphoamidite) ligand (SIPHOS)/Cu(OTf)2-catalyzed highly regio-and stereo-selective hydroborations of internal alkynes with diborane in water

Institute of Scientific and Technical Information of China (English)

Qing-Qing Xuan; Ya-Hui Wei; Qiu-Ling Song

2017-01-01

The highly regio-and stereoselective hydroborations of unactivated internal alkynes with diboron compound catalyzed by Cu(OTf)2 with spiro(phosphoamidite) as ligand in the presence of Cs2CO3 in water was developed.This protocol was applied efficiently in the aqueous synthesis of multi-substituted vinylboranes.

Selection of an experimental fish ladder located at the dam of the Itaipu Binacional, Paraná River, Brazil

Directory of Open Access Journals (Sweden)

Domingo Rodriguez Fernandez

2004-08-01

Full Text Available The specific selection of a weir and orifice type experimental fish ladder in the dam of the Itaipu Reservoir (Paraná River was evaluated by samplings in the river downstream and at two points along the ladder (at heights of 10 m and 27 m during 28 months. Among the 65 species recorded in the river (immediate downstream of the dam, 27 were captured on the ladder. The species that showed highest density on the ladder, the majority migratory, were moderately, or only slightly, abundant downstream. Among the most abundant species downstream, only one, non-migratory, was recorded in the ladder. The structure presented a negative selection in relation to large migratory pimelodids that might be overcome by enlarging the scale of its design. The sampling demonstrated a moderate selection of species along the ladder and its hydraulic model proved satisfactory regarding the attraction and efficient ascent of the fishes.A seleção específica de uma escada de peixes do tipo seqüência de tanques, com passagem de fundo (tipo weir and orifice, na barragem da hidrelétrica de Itaipu (rio Paraná, foi avaliada através de amostragens no rio a jusante (amostragem trimestral em 1997 e em dois pontos ao longo da escada (10 e 27m de altura; nov/94 a jan/97 e nov/94 a fev/97, respectivamente. Das 65 espécies registradas no rio imediatamente a jusante da barragem, 27 foram capturadas na escada. As espécies com maior densidade na escada, em sua maioria migradoras, tiveram abundância moderada ou baixa a jusante. Entre as mais abundantes a jusante, apenas uma, não migradora, foi registrada na escada. A escada apresentou seleção negativa aos grandes pimelodídeos migradores que pode ser superada com a ampliação na escala do projeto. As amostragens evidenciaram baixa seletividade específica ao longo da escada, sendo seu modelo hidráulico satisfatório na atração e eficiente na ascensão de peixes.

Construction and test of the first Belle II SVD ladder implementing the origami chip-on-sensor design

International Nuclear Information System (INIS)

Irmler, C.; Bauer, A.; Bergauer, T.; Adamczyk, K.; Bacher, S.; Aihara, H.; Angelini, C.; Batignani, G.; Bettarini, S.; Bosi, F.; Aziz, T.; Babu, V.; Bahinipati, S.; Barberio, E.; Baroncelli, Ti.; Baroncelli, To.; Basith, A.K.; Behera, P.K.; Bhuyan, B.; Bilka, T.

2016-01-01

The Belle II Silicon Vertex Detector comprises four layers of double-sided silicon strip detectors (DSSDs), consisting of ladders with two to five sensors each. All sensors are individually read out by APV25 chips with the Origami chip-on-sensor concept for the central DSSDs of the ladders. The chips sit on flexible circuits that are glued on the top of the sensors. This concept allows a low material budget and an efficient cooling of the chips by a single pipe per ladder. We present the construction of the first SVD ladders and results from precision measurements and electrical tests

Fermion-boson scattering in ladder approximation

International Nuclear Information System (INIS)

Jafarov, R.G.; Hadjiev, S.A.

1992-10-01

A method of calculation of forward scattering amplitude for fermions and scalar bosons with exchanging of scalar particle is suggested. The Bethe-Salpeter ladder equation for the imaginary part of the amplitude is constructed and a solution in Regge asymptotical form is found and the corrections to the amplitude due to the exit from mass shell are calculated. (author). 8 refs

The laddering method in service innovation research

DEFF Research Database (Denmark)

Grünbaum, Niels Nolsøe

2017-01-01

The laddering method is a qualitative interview technique applied in a situation with one interviewer and one informant with the aim of creating an understanding of the value that business-to-consumer (B2C) customers extract from product attributes. Thus, this methodology aims to depict a mental ...

A robustification of the chain-ladder method

NARCIS (Netherlands)

Verdonck, T.; van Wouwe, M.; Dhaene, J.

2009-01-01

In a non-life insurance business an insurer often needs to build up a reserve to able to meet his or her future obligations arising from incurred but not reported completely claims. To forecast these claims reserves, a simple but generally accepted algorithm is the classical chain-ladder method.

Doped spin ladders under magnetic field; Echelles de spins dopees sous champ magnetique

Energy Technology Data Exchange (ETDEWEB)

Roux, G

2007-07-15

This thesis deals with the physics of doped two-leg ladders which are a quasi one-dimensional and unconventional superconductor. We particularly focus on the properties under magnetic field. Models for strongly correlated electrons on ladders are studied using exact diagonalization and density-matrix renormalization group (DMRG). Results are also enlightened by using the bosonization technique. Taking into account a ring exchange it highlights the relation between the pairing of holes and the spin gap. Its influence on the dynamics of the magnetic fluctuations is also tackled. Afterwards, these excitations are probed by the magnetic field by coupling it to the spin degree of freedom of the electrons through Zeeman effect. We show the existence of doping-dependent magnetization plateaus and also the presence of an inhomogeneous superconducting phase (FFLO phase) associated with an exceeding of the Pauli limit. When a flux passes through the ladder, the magnetic field couples to the charge degree of freedom of the electrons via orbital effect. The diamagnetic response of the doped ladder probes the commensurate phases of the t-J model at low J/t. Algebraic transverse current fluctuations are also found once the field is turned on. Lastly, we report numerical evidences of a molecular superfluid phase in the 3/2-spin attractive Hubbard model: at a density low enough, bound states of four fermions, called quartets, acquire dominant superfluid fluctuations. The observed competition between the superfluid and density fluctuations is connected to the physics of doped ladders. (author)

Elongational viscosity of monodisperse and bidisperse polystyrene melts

DEFF Research Database (Denmark)

Nielsen, Jens Kromann; Rasmussen, Henrik Koblitz; Hassager, Ole

2005-01-01

The startup and steady uniaxial elongational viscosity have been measured for two monodisperse polystyrene melts with molecular weights of 52 kg/mole (PS52K) and 103 kg/mole (PS103K), and for three bidisperse polystyrene melts. The bidisperse melts consist of PS103K or PS52K and a monodisperse...... (closed loop proportional regulator) using the laser in such a way that the stretch rate at the neck is kept constant. The rheometer has been described in more detail in (A. Bach, H.K. Rasmussen and O. Hassager, Journal of Rheology, 47 (2003) 429). PS390K show a decrease in the steady viscosity as a power......-law function of the elongational rate (A. Bach, K. Almdal, H.K. Rasmussen and O. Hassager, Macromolecules 36 (2003) 5174). PS52K and PS103K show that the steady viscosity has a maximum that is respectively 100% and 50% above 3 times the zero-shear-rate viscosity. The bidisperse melts show a significant...

Characterization of pore-filling of spiro-MeOTAD in solid-state dye-sensitized solar cells and its consequence in device performance

KAUST Repository

Ding, I-Kang; Té treault, Nicolas; Hardin, Brian E.; Smith, Eva H.; Grä tzel, Michael; McGehee, Michael D.

2009-01-01

that spiro-OMeTAD can penetrate the entire depth of the film, and its concentration is constant throughout the film. We determine that in a 2.5-•m-thick film, the volume of the pores is 60-65% filled. The pores become less filled when thicker films are used

Long-term Evaluation of Type 2 Thyroplasty with Titanium Bridges for Adductor Spasmodic Dysphonia.

Science.gov (United States)

Sanuki, Tetsuji; Yumoto, Eiji

2017-07-01

Objectives Standard treatments of adductor spasmodic dysphonia (AdSD) provide temporary relief of symptoms. Type 2 thyroplasty offers a long-term solution; however, long-term voice outcome data are lacking. The objective of this study was to assess the long-term voice outcomes of type 2 thyroplasty with titanium bridges through use of a validated voice questionnaire. Study Design Case series with chart review. Setting University hospital. Subjects and Methods Forty-seven consecutively enrolled patients with AdSD underwent type 2 thyroplasty with titanium bridges between August 2006 and November 2014. Questionnaires were completed during regularly scheduled follow-ups and, in some cases, were sent to patients who missed follow-up appointments. In 2015, questionnaires were mailed to all 47 patients and included a Voice Handicap Index-10 evaluation, as well as questions on postoperative vocal symptoms, surgical site, and status of the implanted titanium bridges. Results Of 47 patients with AdSD, 31 (66%) completed the questionnaires. The average follow-up interval was 41.3 months. No patient reported experiencing an adverse event around the surgical site, and almost all were satisfied with their voices postoperatively. The mean postoperative (>3 years) Voice Handicap Index-10 score improved significantly, from 26.3 to 9.4 (n = 17, P = .0009). Conclusions Type 2 thyroplasty for AdSD significantly improved patient quality of life and voice symptoms and continued to do so long after the surgery. The results of this study suggest that type 2 thyroplasty provides relief from vocal symptoms in patients with AdSD for >3 years.

Cobalt Ion Promoted Redox Cascade: A Route to Spiro Oxazine-Oxazepine Derivatives and a Dinuclear Cobalt(III) Complex of an N-(1,4-Naphthoquinone)-o-aminophenol Derivative.

Science.gov (United States)

Mondal, Sandip; Bera, Sachinath; Maity, Suvendu; Ghosh, Prasanta

2017-11-06

The study discloses that the redox activity of N-(1,4-naphthoquinone)-o-aminophenol derivatives (L R H 2 ) containing a (phenol)-NH-(1,4-naphthoquinone) fragment is notably different from that of a (phenol)-NH-(phenol) precursor. The former is a platform for a redox cascade. L R H 2 is redox noninnocent and exists in Cat-N-(1,4-naphthoquinone)(2-) (L R 2- ) and SQ-N-(1,4-naphthoquinone) (L R •- ) states in the complexes. Reactions of L R H 2 with cobalt(II) salts in MeOH in air promote a cascade affording spiro oxazine-oxazepine derivatives ( OX L R ) in good yields, when R = H, Me, t Bu. Spiro oxazine-oxazepine derivatives are bioactive, and such a molecule has so far not been isolated by a schematic route. In this context this cascade is significant. Dimerization of L R H 2 → OX L R in MeOH is a (6H + + 6e) oxidation reaction and is composed of formations of four covalent bonds and 6-exo-trig and 7-endo-trig cyclization based on C-O coupling reactions, where MeOH is the source of a proton and the ester function. It was established that the active cascade precursor is [(L Me •- )Co III Cl 2 ] (A). Notably, formation of a spiro derivative was not detected in CH 3 CN and the reaction ends up furnishing A. The route of the reaction is tunable by R, when R = NO 2 , it is a (2e + 4H + ) oxidation reaction affording a dinuclear L R 2- complex of cobalt(III) of the type [(L NO2 2- ) 2 Co III 2 (OMe) 2 (H 2 O) 2 ] (1) in good yields. No cascade occurs with zinc(II) ion even in MeOH and produces a L Me •- complex of type [(L Me •- )Zn II Cl 2 ] (2). The intermediate A and 2 exhibit strong EPR signals at g = 2.008 and 1.999, confrming the existence of L Me •- coordinated to low-spin cobalt(III) and zinc(II) ions. The intermediates of L R H 2 → OX L R conversion were analyzed by ESI mass spectrometry. The molecular geometries of OX L R and 1 were confirmed by X-ray crystallography, and the spectral features were elucidated by TD DFT calculations.

Utilization of the fish ladder at the Engenheiro Sergio Motta Dam, Brazil, by long distance migrating potamodromous species

Directory of Open Access Journals (Sweden)

Sérgio Makrakis

Full Text Available Utilization of the fish ladder installed at the Engenheiro Sergio Motta Dam (also known as Porto Primavera on the Paraná River, Southern Brazil, by long-distance migrating potamodromous species (sampling Protocol I, and ascending and descending movements (Protocol II were evaluated. Three pools along the fish ladder (designated as lower, middle, and upper were sampled monthly between December, 2004 and March, 2005 to determine the abundance of species in the ladder. The ascending and descending movements of the species in the ladder were also analyzed in the same period. In the samples for both protocols, 37 species representing 17 families and 5 orders (Characiformes, Siluriformes, Perciformes, Gymnotiformes, and Myliobatiformes were recorded. Characiformes were represented by 21 species. Long- distance migratory species (11 species predominated in the ladder (60% of the total number of individuals, with high abundance of Rhinelepis aspera (5645 individuals. For protocol I, mean abundance varied greatly among the months and pools, with lowest values in December and March for all pools, and highest in January for the lower pool due to high capture of R. aspera. Fish abundance declined from the lower to the upper pool, especially for R. aspera and Rhaphiodon vulpinus. For Protocol II, 17 species were recorded ascending the ladder, where Astyanax altiparanae and Leporinus friderici were the most abundant species (684 and 111 individuals, respectively. However, 18 species showed descending movements, with high captures of Metynnis maculatus and A. altiparanae (339 and 319 individuals, respectively. Twelve species (52% moved in both directions, and among the seven migratory species sampled, four were recorded ascending and descending, and three species only ascending the ladder. The fish ladder appears to selectively favor species with high swimming capabilities. A discussion is presented on the requirements for future research on attraction to the

Peniciadametizine A, a Dithiodiketopiperazine with a Unique Spiro[furan-2,7'-pyrazino[1,2-b][1,2]oxazine] Skeleton, and a Related Analogue, Peniciadametizine B, from the Marine Sponge-Derived Fungus Penicillium adametzioides

Directory of Open Access Journals (Sweden)

Yang Liu

2015-06-01

Full Text Available Peniciadametizine A (1; a new dithiodiketopiperazine derivative possessing a unique spiro[furan-2,7'-pyrazino[1,2-b][1,2]oxazine] skeleton, together with a highly oxygenated new analogue, peniciadametizine B (2; as well as two known compounds, brasiliamide A (3; and viridicatumtoxin (4, were isolated and identified from Penicillium adametzioides AS-53, a fungus obtained from an unidentified marine sponge. The unambiguous assignment of the relative and absolute configuration for the spiro center C-2 of compound 1 was solved by the combination of NMR and ECD measurements with Density-Functional Theory (DFT conformational analysis and Time-Dependent Density-Functional Theory-Electronic Circular Dichroism (TDDFT-ECD calculations. The spiro[furan-2,7'-pyrazino[1,2-b][1,2]oxazine] skeleton of 1 has not been reported yet among natural products and the biosynthetic pathway for 1 and 2 was discussed. Compounds 1 and 2 showed inhibitory activity against the pathogenic fungus Alternaria brassicae.

Segmented block copolymers with monodisperse aramide end-segments

NARCIS (Netherlands)

Araichimani, A.; Gaymans, R.J.

2008-01-01

Segmented block copolymers were synthesized using monodisperse diaramide (TT) as hard segments and PTMO with a molecular weight of 2 900 g · mol-1 as soft segments. The aramide: PTMO segment ratio was increased from 1:1 to 2:1 thereby changing the structure from a high molecular weight multi-block

Fish ladder of Lajeado Dam: migrations on one-way routes?

Directory of Open Access Journals (Sweden)

Angelo Antônio Agostinho

Full Text Available Fish ladders are generally conceived to reestablish connectivity among critical habitats for migratory species, thus mitigating the impacts of the blockage of migration routes by dams. If this management tool is to be meaningful for conserving fish species, it must provide a fully permeable connection and assure both upward and downward movements. However, because reservoirs have very different hydrodynamics than the original river, it is expected that, at least in the inner area, they may constitute an additional barrier to this movement, especially for descending fish. Thus, the present study sought to determine if migratory fish and their offspring disperse downstream from the dam after ascending a ladder and spawning in the upper reaches of a basin. To achieve this purpose, we evaluated the limitation imposed by lentic areas to the descent of eggs, larvae and adults of migratory species; we also determined the abundance and composition of larvae present in the plankton near the dam, and compared the intensity of the upward and downward movements of adult fish. Samples of ichthyoplankton were taken upriver, inside the reservoir, in the river downstream from the dam, and in the forebay of the Lajeado Dam on the Tocantins River (Luis Eduardo Magalhães Hydroelectric Plant, from October, 1999 through September, 2004. The densities of fish ascending and descending the ladder were determined experimentally on eight occasions, from June, 2004 to March, 2005. Due to difficulties in identifying the true fish origin (up or down in the environments connected by the fish passage system, the evaluation of the distribution of migratory fish in reservoirs was based on the landings of the commercial fishery conducted along the Itaipu Reservoir during the four years preceding (2001 through 2003 the construction of the lateral channel (fish-passage mechanism. Fish eggs and larvae drifting down the Tocantins River did not appear in samples taken in the lower

Nano-ZnO Catalyzed Multicomponent One-Pot Synthesis of Novel Spiro(indoline-pyranodioxine Derivatives

Directory of Open Access Journals (Sweden)

Harshita Sachdeva

2014-01-01

Full Text Available A simple catalytic protocol for the synthesis of novel spiro[indoline-pyranodioxine] derivatives has been developed using ZnO nanoparticle as an efficient, green, and reusable catalyst. The derivatives are obtained in moderate to excellent yield by one-pot three-component reaction of an isatin, malononitrile/ethylcyanoacetate, and 2,2-dimethyl-1,3-dioxane-4,6-dione in absolute ethanol under conventional heating and microwave irradiation. The catalyst was recovered by filtration from the reaction mixture and reused during five consecutive runs without any apparent loss of activity for the same reaction. The mild reaction conditions and recyclability of the catalyst make it environmentally benign synthetic procedure.

49 CFR 214.519 - Floors, decks, stairs, and ladders of on-track roadway maintenance machines.

Science.gov (United States)

2010-10-01

... roadway maintenance machines. 214.519 Section 214.519 Transportation Other Regulations Relating to... SAFETY On-Track Roadway Maintenance Machines and Hi-Rail Vehicles § 214.519 Floors, decks, stairs, and ladders of on-track roadway maintenance machines. Floors, decks, stairs, and ladders of on-track roadway...

A case of bilateral vocal fold mucosal bridges, bilateral trans-vocal fold type III sulci vocales, and an intracordal polyp.

Science.gov (United States)

Tan, Melin; Pitman, Michael J

2011-07-01

We present a patient with a novel finding of bilateral mucosal bridges, bilateral type III trans-vocal fold sulci vocales, and a vocal fold polyp. Although sulci and mucosal bridges occur in the vocal folds, it is rare to find multiples of these lesions in a single patient, and it is even more uncommon when they occur in conjunction with a vocal fold polyp. To our knowledge, this is the first description of a vocal fold polyp in combination with multiple vocal fold bridges and multiple type III sulci vocales in a single patient. To describe and visually present the diagnosis and treatment of a patient with an intracordal polyp, bilateral mucosal bridges, as well as bilateral type III trans-vocal fold sulci vocales. Presentation of a set of high definition intraoperative photos displaying the extent of the vocal fold lesions and the resection of the intracordal polyp. This patient presented with only 6 months of significant dysphonia. It was felt that the recent change in voice was because of the polyp and not the bridges or sulci vocales. Considering the patient's presentation and the possible morbidity of resection of mucosal bridges and sulci, only the polyp was excised. Postoperatively, the patient's voice returned to his acceptable mild baseline dysphonia, and the benefit has persisted 6 months postoperatively. The combination of bilateral mucosal bridges, bilateral type III sulcus vocalis, and an intracordal polyp in one patient is rare if not novel. Treatment of the polyp alone returned the patient's voice to his lifelong baseline of mild dysphonia. Copyright © 2011 The Voice Foundation. Published by Mosby, Inc. All rights reserved.

Nanostructured TiO2/CH3NH3PbI3 heterojunction solar cells employing spiro-OMeTAD/Co-complex as hole-transporting material

KAUST Repository

Noh, Jun Hong; Jeon, Nam Joong; Choi, Yong Chan; Nazeeruddin, Md. K.; Grä tzel, Michael; Seok, Sang Il

2013-01-01

For using 2,2′,7,7′-tetrakis(N,N′-di-p- methoxyphenylamine)-9,9′-spirobifluorene (spiro-OMeTAD) as a hole conductor in solar cells, it is necessary to improve its charge-transport properties through electrochemical doping. With the aim

Phase diagram of a bosonic ladder with two coupled chains

International Nuclear Information System (INIS)

Luthra, Meetu Sethi; Mishra, Tapan; Pai, Ramesh V.; Das, B. P.

2008-01-01

We study a bosonic ladder with two coupled chains using the finite-size density-matrix renormalization group method. We show that in a commensurate bosonic ladder the critical on-site interaction (U C ) for the superfluid to Mott insulator transition gets larger as the interchain hopping (t perpendicular ) increases. We analyze this quantum phase transition and obtain the phase diagram in the t perpendicular -U plane. We also consider the asymmetric case where the on-site interactions are different in the two chains and have shown that the system as a whole will not be in the Mott insulator phase unless both the chains have on-site interactions greater than the critical value

DNA typing by capillary electrophoresis

Energy Technology Data Exchange (ETDEWEB)

Zhang, N.

1997-10-08

Capillary electrophoresis is becoming more and more important in nucleic acid analysis including DNA sequencing, typing and disease gene measurements. This work summarized the background of DNA typing. The recent development of capillary electrophoresis was also discussed. The second part of the thesis showed the principle of DNA typing based on using the allelic ladder as the absolute standard ladder in capillary electrophoresis system. Future work will be focused on demonstrating DNA typing on multiplex loci and examples of disease diagnosis in the on-line format of PCR-CE. Also capillary array electrophoresis system should allow high throughput, fast speed DNA typing. Only the introduction and conclusions for this report are available here. A reprint was removed for separate processing.

The search for competing charge orders in frustrated ladder systems

International Nuclear Information System (INIS)

Lal, Siddhartha; Laad, Mukul S.

2007-08-01

A recent study revealed the dynamics of the charge sector of a one-dimensional quarter- filled electronic system with extended Hubbard interactions to be that of an effective pseudospin transverse-field Ising model (TFIM) in the strong coupling limit. With the twin motivations of studying the co-existing charge and spin order found in strongly correlated chain systems and the effects of inter-chain couplings, we investigate the phase diagram of coupled effective (TFIM) systems. A bosonisation and RG analysis for a two-leg TFIM ladder yields a rich phase diagram showing Wigner/Peierls charge order and Neel/dimer spin order. In a broad parameter regime, the orbital antiferromagnetic phase is found to be stable. An intermediate gapless phase of finite width is found to lie in between two charge-ordered gapped phases. Kosterlitz-Thouless transitions are found to lead from the gapless phase to either of the charge-ordered phases. Low energy effective Hamiltonian analyses of a strongly coupled 2-chain ladder system confirm a phase diagram with in-chain CO, rung-dimer, and orbital antiferromagnetic ordered phases with varying interchain couplings as well as superconductivity upon hole-doping. Our work is potentially relevant for a unified description of a class of strongly correlated, quarter-filled chain and ladder systems. (autor)

Resonance self-shielding calculation with regularized random ladders

Energy Technology Data Exchange (ETDEWEB)

Ribon, P.

1986-01-01

The straightforward method for calculation of resonance self-shielding is to generate one or several resonance ladders, and to process them as resolved resonances. The main drawback of Monte Carlo methods used to generate the ladders, is the difficulty of reducing the dispersion of data and results. Several methods are examined, and it is shown how one (a regularized sampling method) improves the accuracy. Analytical methods to compute the effective cross-section have recently appeared: they are basically exempt from dispersion, but are inevitably approximate. The accuracy of the most sophisticated one is checked. There is a neutron energy range which is improperly considered as statistical. An examination is presented of what happens when it is treated as statistical, and how it is possible to improve the accuracy of calculations in this range. To illustrate the results calculations have been performed in a simple case: nucleus /sup 238/U, at 300 K, between 4250 and 4750 eV.

Synthesis of monodisperse silver nanoparticles for ink-jet printed flexible electronics

Energy Technology Data Exchange (ETDEWEB)

Zhang Zhiliang; Zhang Xingye; Xin Zhiqing; Deng Mengmeng; Wen Yongqiang; Song Yanlin, E-mail: zhangxy@iccas.ac.cn, E-mail: ylsong@iccas.ac.cn [Beijing National Laboratory for Molecular Sciences (BNLMS), Key Lab of Organic Solids, Laboratory of New Materials, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)

2011-10-21

In this study, monodisperse silver nanoparticles were synthesized with a new reduction system consisting of adipoyl hydrazide and dextrose at ambient temperature. By this facile and rapid approach, high concentration monodisperse silver nanoparticles were obtained on a large scale at low protectant/AgNO{sub 3} mass ratio which was highly beneficial to low cost and high conductivity. Based on the synthesized monodisperse silver nanoparticles, conductive inks were prepared with water, ethanol and ethylene glycol as solvents, and were expected to be more environmentally friendly. A series of electrocircuits were fabricated by ink-jet printing silver nanoparticle ink on paper substrate with a commercial printer, and they had low resistivity in the range of 9.18 x 10{sup -8}-8.76 x 10{sup -8} {Omega} m after thermal treatment at 160 {sup 0}C for 30 min, which was about five times that of bulk silver (1.586 x 10{sup -8} {Omega} m). Moreover, a radio frequency identification (RFID) antenna was fabricated by ink-jet printing, and 6 m wireless identification was realized after an Alien higgs-3 chip was mounted on the printed antenna by the flip-chip method. These flexible electrocircuits produced by ink-jet printing would have enormous potential for low cost electrodes and sensor devices.

Synthesis of monodisperse silver nanoparticles for ink-jet printed flexible electronics

International Nuclear Information System (INIS)

Zhang Zhiliang; Zhang Xingye; Xin Zhiqing; Deng Mengmeng; Wen Yongqiang; Song Yanlin

2011-01-01

In this study, monodisperse silver nanoparticles were synthesized with a new reduction system consisting of adipoyl hydrazide and dextrose at ambient temperature. By this facile and rapid approach, high concentration monodisperse silver nanoparticles were obtained on a large scale at low protectant/AgNO 3 mass ratio which was highly beneficial to low cost and high conductivity. Based on the synthesized monodisperse silver nanoparticles, conductive inks were prepared with water, ethanol and ethylene glycol as solvents, and were expected to be more environmentally friendly. A series of electrocircuits were fabricated by ink-jet printing silver nanoparticle ink on paper substrate with a commercial printer, and they had low resistivity in the range of 9.18 x 10 -8 -8.76 x 10 -8 Ω m after thermal treatment at 160 0 C for 30 min, which was about five times that of bulk silver (1.586 x 10 -8 Ω m). Moreover, a radio frequency identification (RFID) antenna was fabricated by ink-jet printing, and 6 m wireless identification was realized after an Alien higgs-3 chip was mounted on the printed antenna by the flip-chip method. These flexible electrocircuits produced by ink-jet printing would have enormous potential for low cost electrodes and sensor devices.

Infiltration of Spiro-MeOTAD hole transporting material into nanotubular TiO{sub 2} electrode for solid-state dye-sensitized solar cells

Energy Technology Data Exchange (ETDEWEB)

Kuzmych, Oleksandr, E-mail: alexkuzmych@gmail.com [Faculty of Chemistry, Laboratory of Electrochemistry, University of Warsaw, 02-093 Warsaw (Poland); Johansson, Erik M.J.; Nonomura, Kazuteru [Department of Physical and Analytical Chemistry, Uppsala University, Box 259, 751 05 Uppsala (Sweden); Nyberg, Tomas [The Angstrom Laboratory, Uppsala University, Box 534, 751 21 Uppsala (Sweden); Skompska, Magdalena [Faculty of Chemistry, Laboratory of Electrochemistry, University of Warsaw, 02-093 Warsaw (Poland); Hagfeldt, Anders [Department of Physical and Analytical Chemistry, Uppsala University, Box 259, 751 05 Uppsala (Sweden)

2014-09-15

Highlights: • We report infiltration of Spiro-MeOTAD into pores of TiO{sub 2} nanotube (TNT) arrays. • Surface amount of D35 is diffusion limited for TiO{sub 2} mesoporous film but not for TNTs. • Performance of liquid and solid-state solar cells based on TNTs is compared. - Abstract: TiO{sub 2} nanotubes grown by anodic oxidation of Ti thin film deposited on conducting transparent fluoride-doped tin oxide (FTO) substrate were used as a unique geometrically organized template to study the infiltration of Spiro-MeOTAD hole transporting material (HTM) inside straight pores. The TiO{sub 2} nanotube (TNT) array electrode was compared with a mesoporous one in terms of loading with an organic dye of high extinction coefficient. It was shown that it is possible to build a working solid state dye sensitized solar cell device with such a combination of materials and its performance was compared with a device in which the solid state HTM was replaced by a liquid state electrolyte.

High-energy, large-momentum-transfer processes: Ladder diagrams in var-phi 3 theory

International Nuclear Information System (INIS)

Newton, C.L.J.

1990-01-01

Relativistic quantum field theories may help one to understand high-energy, large-momentum-transfer processes, where the center-of-mass energy is much larger than the transverse momentum transfers, which are in turn much larger than the masses of the participating particles. With this possibility in mind, the author studies ladder diagrams in var-phi 3 theory. He shows that in the limit s much-gt |t| much-gt m 2 , the scattering amplitude for the N-rung ladder diagram takes the form s -1 |t| -N+1 times a homogeneous polynomial of degree 2N - 2 and ln s and ln |t|. This polynomial takes different forms depending on the relation of ln |t| to ln s. More precisely, the asymptotic formula for the N-rung ladder diagram has points of non-analytically when ln |t| = γ ln s for γ = 1/2, 1/3, hor-ellipsis, 1/N-2

Characterization of a monodispersed aerosol exposure system for beagle dogs

International Nuclear Information System (INIS)

Cannon, W.C.; Herring, J.P.; Craig, D.K.

1978-01-01

A monodispersed aerosol exposure system for dogs is described and data are presented on aerosol depositions in the exposure system which could affect the aerosol presented to the animals by reducing the concentration and changing the particle size distribution

A general approach for monodisperse colloidal perovskites, Chemistry of Materials

NARCIS (Netherlands)

Demirors, A.F.; Imhof, A.

2009-01-01

We describe a novel general method for synthesizing monodisperse colloidal perovskite particles at room temperature by postsynthesis addition of metal hydroxides to amorphous titania colloids. In previous work, we used titania particles to synthesize homogenously mixed silica-titania composite

Massive 3-loop ladder diagrams for quarkonic local operator matrix elements

International Nuclear Information System (INIS)

Ablinger, Jakob; Blümlein, Johannes; Hasselhuhn, Alexander; Klein, Sebastian; Schneider, Carsten; Wißbrock, Fabian

2012-01-01

3-loop diagrams of the ladder-type, which emerge for local quarkonic twist-2 operator matrix elements, are computed directly for general values of the Mellin variable N using Appell-function representations and applying modern summation technologies provided by the package Sigma and the method of hyperlogarithms. In some of the diagrams generalized harmonic sums with ξ∈{1,1/2,2} emerge beyond the usual nested harmonic sums. As the asymptotic representation of the corresponding integrals shows, the generalized sums conspire giving well behaved expressions for large values of N. These diagrams contribute to the 3-loop heavy flavor Wilson coefficients of the structure functions in deep-inelastic scattering in the region Q 2 ≫m 2 .

Template-directed synthesis of linear porphyrin oligomers: classical, Vernier and mutual Vernier† †Electronic supplementary information (ESI) available: Synthesis and characterization of new compounds, ladder complexes, UV-vis-NIR titrations and binding data for reference compounds and for the formation of linear oligomer complexes, calculation of effective molarities, analytical GPC calibration and molar absorption coefficients. See DOI: 10.1039/c6sc05355f Click here for additional data file.

Science.gov (United States)

Kamonsutthipaijit, Nuntaporn

2017-01-01

Three different types of template-directed syntheses of linear porphyrin oligomers are presented. In the classical approach the product has the same number of binding sites as the template, whereas in Vernier reactions the product has the lowest common multiple of the numbers of binding sites in the template and the building block. Mutual Vernier templating is like Vernier templating except that both strands of the Vernier complex undergo coupling simultaneously, so that it becomes impossible to say which is the ‘template’ and which is the ‘building block’. The template-directed synthesis of monodisperse linear oligomers is more difficult than that of cyclic oligomers, because the products of linear templating have reactive ends. All three types of templating are demonstrated here, and used to prepare a nickel(ii) porphyrin dodecamer with 4-pyridyl substituents on all twelve porphyrin units. The stabilities and cooperativities of the double-strand complexes involved in these reactions were investigated by UV-vis-NIR titration. The four-rung ladder duplex has a stability constant of about 2 × 1018 M–1 in dichloromethane at 298 K. PMID:28553508

Healthcare organization-education partnerships and career ladder programs for health care workers.

Science.gov (United States)

Dill, Janette S; Chuang, Emmeline; Morgan, Jennifer C

2014-12-01

Increasing concerns about quality of care and workforce shortages have motivated health care organizations and educational institutions to partner to create career ladders for frontline health care workers. Career ladders reward workers for gains in skills and knowledge and may reduce the costs associated with turnover, improve patient care, and/or address projected shortages of certain nursing and allied health professions. This study examines partnerships between health care and educational organizations in the United States during the design and implementation of career ladder training programs for low-skill workers in health care settings, referred to as frontline health care workers. Mixed methods data from 291 frontline health care workers and 347 key informants (e.g., administrators, instructors, managers) collected between 2007 and 2010 were analyzed using both regression and fuzzy-set qualitative comparative analysis (QCA). Results suggest that different combinations of partner characteristics, including having an education leader, employer leader, frontline management support, partnership history, community need, and educational policies, were necessary for high worker career self-efficacy and program satisfaction. Whether a worker received a wage increase, however, was primarily dependent on leadership within the health care organization, including having an employer leader and employer implementation policies. Findings suggest that strong partnerships between health care and educational organizations can contribute to the successful implementation of career ladder programs, but workers' ability to earn monetary rewards for program participation depends on the strength of leadership support within the health care organization. Copyright © 2014 Elsevier Ltd. All rights reserved.

Phase diagram and re-entrant fermionic entanglement in a hybrid Ising-Hubbard ladder

Science.gov (United States)

Sousa, H. S.; Pereira, M. S. S.; de Oliveira, I. N.; Strečka, J.; Lyra, M. L.

2018-05-01

The degree of fermionic entanglement is examined in an exactly solvable Ising-Hubbard ladder, which involves interacting electrons on the ladder's rungs described by Hubbard dimers at half-filling on each rung, accounting for intrarung hopping and Coulomb terms. The coupling between neighboring Hubbard dimers is assumed to have an Ising-like nature. The ground-state phase diagram consists of four distinct regions corresponding to the saturated paramagnetic, the classical antiferromagnetic, the quantum antiferromagnetic, and the mixed classical-quantum phase. We have exactly computed the fermionic concurrence, which measures the degree of quantum entanglement between the pair of electrons on the ladder rungs. The effects of the hopping amplitude, the Coulomb term, temperature, and magnetic fields on the fermionic entanglement are explored in detail. It is shown that the fermionic concurrence displays a re-entrant behavior when quantum entanglement is being generated at moderate temperatures above the classical saturated paramagnetic ground state.

Nestling diets and provisioning rates of sympatric Golden-fronted and Ladder-backed Woodpeckers

Science.gov (United States)

Schroeder, Evonne L.; Boal, Clint W.; Glasscock, Selma N.

2013-01-01

We examined comparative food use and provisioning of Golden-fronted (Melanerpes aurifrons) and Ladder-backed (Picoides scalaris) woodpeckers at the Rob and Bessie Welder Wildlife Foundation Refuge, in San Patricio County, Texas. We combined video surveillance and direct observations to monitor provisioning rates and identify items delivered by adult woodpeckers to nestlings. We collected 328 hours of data at Ladder-backed Woodpecker nest cavities and 230 hours of data at Golden-fronted Woodpecker nest cavities. Ladder-backed Woodpecker nestling diets consisted of 100% animal matter, comprised of invertebrate larvae (99%) and invertebrate adults (nestlings were also high in animal matter (77%) with more invertebrate adults (55%) and fewer invertebrate larvae (27%), but also included vegetable matter (16%). Morisita's measure of overlap suggested a relatively low dietary overlap of 31% between nestlings of these two sympatric woodpecker species. Foraging methods used by these species may explain their low dietary overlap and facilitate their coexistence.

Room temperature vortex fluidic synthesis of monodispersed amorphous proto-vaterite.

Science.gov (United States)

Peng, Wenhong; Chen, Xianjue; Zhu, Shenmin; Guo, Cuiping; Raston, Colin L

2014-10-11

Monodispersed particles of amorphous calcium carbonate (ACC) 90 to 200 nm in diameter are accessible at room temperature in ethylene glycol and water using a vortex fluidic device (VFD). The ACC material is stable for at least two weeks under ambient conditions.

Ultrasound-driven Megahertz Faraday Waves for Generation of Monodisperse Micro Droplets and Applications

Science.gov (United States)

Tsai, Chen S.; Mao, Rong W.; Lin, Shih K.; Tsai, Shirley C.; Boss, Gerry; Brenner, Matt; Smaldone, Gerry; Mahon, Sari; Shahverdi, Kaveh; Zhu, Yun

Our theoretical findings on instability of Faraday waves at megahertz (MHz) drive frequency and realization of silicon-based MHz multiple-Fourier horn ultrasonic nozzles (MFHUNs) together have enabled generation of mono-disperse droplets of controllable diameter (2.5-6.0 μm) at very low electrical drive power (generator has imminent application to pulmonary (inhalation) drug delivery and other potential applications. Here an update of advances on analysis and design of the MHz MFHUNs and the underlying physical mechanism for generation of mono-disperse micro droplets, and the nebulizer platform for application to detoxification of cyanide poisoning are presented.

THE COMPARISON OF USING SNAKE LADDERS AND SCRABBLE MEDIA TOWARDS VOCABULARY MASTERY OF STUDENTS

Directory of Open Access Journals (Sweden)

Eka Pra Setiawati

2017-02-01

Full Text Available Vocabulary is an essential component in learning English. It influences four English skills; they are listening, speaking, reading, and writing, for getting a good result in English. In teaching learning process, the teacher often implements the less interesting method, technique, or even media of vocabulary mastery in teaching and learning process which make the students to be bored, inactive, an uniterested in memorizing English vocabulary. Some media can be interested as the solutions in vocabulary mastery, they are Snake Ladders media and Scrabble media. The investigation was undergone by quantitative research. The researcher applied experimental research. This research underwent pre-test post-test control group design. To analyze data, t-test formula is used to measure the result of collected data. From the t-test measurement, it showed that t-test is 3.15 and t-table is 2.66. It means that t-hit > t-table. Based on the collected data, there is different result of using Snake Ladders from Scrabble media toward students’ vocabulary mastery. It was found that the students who are taught by using Snake Ladders resulted significant outcome than those are instructed by Scrabble media. It means that Snake Ladders is effective to improve the students’ vocabulary mastery.

Means-end chains and laddering: An inventory of problems and an agenda for research

DEFF Research Database (Denmark)

Grunert, Klaus G.; Grunert, Suzanne C.; Sørensen, Elin

Executive summary 1. Means-end chains are a device used to understand how consumers mentally link products to self-relevant consequences. Means-end chains are usually measured by a method called laddering. 2. Means-end chains may fall short of tapping all relevant aspects of how consumers think...... about products. Specifically, nonverbal imagery, episodic information, and procedural knowledge are not included in means-end chains. 3. A number of methodological problems can be identified in the collection of means-end chain data. Major problems, which should be addressed in research, are methods...... to elicit the product attributes the laddering is to start with, the integration of a usage situation in the interview, and the basic decision on how much direct the respondent. 4. Concerning the coding of laddering data, a higher degree of transparency of the coding process would be desirable. 5...

Means-end chains and laddering: An inventory of problems and an agenda for research

DEFF Research Database (Denmark)

Grunert, Klaus G.; Beckmann, Suzanne C.; Sørensen, Elin

2001-01-01

and unconscious (or, at least, semiconscious) factors. It is intuitively appealing to the practitioner but has, likewise, attracted academic research. Increased acceptance and use of a new approach inevitably leads to the detection of unresolved issues and problems. Many of these unresolved issues are related...... to the collection and analysis of laddering data. However, many of these also point at problems of a more theoretical nature. In this chapter presented are some of the issues regarded as unresolved and suggested research that could help in solving these problems. The mayor part of this chapter deals...... with methodological problems of the interview technique called laddering, og coding laddering data, and of analysing the coded data. However, also shown, methodological and theoretical issues are partly interlinked: resolutions of methodological problems may require theoretical progress or at least a clarification...

Analytical recursive method to ascertain multisite entanglement in doped quantum spin ladders

Science.gov (United States)

Roy, Sudipto Singha; Dhar, Himadri Shekhar; Rakshit, Debraj; SenDe, Aditi; Sen, Ujjwal

2017-08-01

We formulate an analytical recursive method to generate the wave function of doped short-range resonating valence bond (RVB) states as a tool to efficiently estimate multisite entanglement as well as other physical quantities in doped quantum spin ladders. We prove that doped RVB ladder states are always genuine multipartite entangled. Importantly, our results show that within specific doping concentration and model parameter regimes, the doped RVB state essentially characterizes the trends of genuine multiparty entanglement in the exact ground states of the Hubbard model with large on-site interactions, in the limit that yields the t -J Hamiltonian.

In-line digital holography with phase-shifting Greek-ladder sieves

Science.gov (United States)

Xie, Jing; Zhang, Junyong; Zhang, Yanli; Zhou, Shenlei; Zhu, Jianqiang

2018-04-01

Phase shifting is the key technique in in-line digital holography, but traditional phase shifters have their own limitations in short wavelength regions. Here, phase-shifting Greek-ladder sieves with amplitude-only modulation are introduced into in-line digital holography, which are essentially a kind of diffraction lens with three-dimensional array diffraction-limited foci. In the in-line digital holographic experiment, we design two kinds of sieves by lithography and verify the validity of their phase-shifting function by measuring a 1951 U.S. Air Force resolution test target and three-dimensional array foci. With advantages of high resolving power, low cost, and no limitations at shorter wavelengths, phase-shifting Greek-ladder sieves have great potential in X-ray holography or biochemical microscopy for the next generation of synchrotron light sources.

The snakes and ladders of National Health Service management in England.

Science.gov (United States)

Powell, Martin

2014-01-01

This article explores managerial careers in the National Health Service (NHS) through the lens of talent management, particularly focusing on how managers view barriers (snakes) and facilitators (ladders) to career progression. There is a significant literature on enablers and barriers to career progression, but much of this focuses on specific groups such as black and minority ethnic and female workers, and there is relatively little material on the general workforce of the NHS. The research design is a mixed method quantitative (questionnaire) and qualitative (interview and focus group) approach consisting of a quasi-probability element that focuses on a maximum variety sample and a purposive element that seeks policy views at central and strategic health authority level, and examines talent management in high-performing NHS organisations. Ladders are identified as follows: volunteering, secondment, networking, mentoring, academic qualifications, development, good role models/managers and appraisal/personal development plan. Snakes are identified as managing expectations; identity and cognitive diversity; location; sector; NHS toxic and favouritism culture; poor talent spotting; credentialism; exclusive approach to talent; and sustainability. It concludes that while previous conceptual and empirical work is fairly clear on any ladders, it is less clear on snakes. Copyright © 2013 John Wiley & Sons, Ltd.

Track-Bridge Longitudinal Interaction of Continuous Welded Rails on Arch Bridge

Directory of Open Access Journals (Sweden)

Rong Chen

2013-01-01

Full Text Available Taking arch bridges, including deck, half-through, and through arch bridges (short for DAB, HTAB, and TAB as examples, mechanics analysis models of longitudinal interaction between continuously welded rails (short for CWRs and arch bridges are established. Based on the finite element method (FEM, the longitudinal interaction calculation software of CWR on arch bridges has been developed. Focusing on an HTAB, the tension, compression, and deflection conditions are calculated and analyzed. The results show that the mechanics analysis models of three types of arch bridges can truly reflect the real state of the structure; the calculation software can be used for systematic research of the CWR on arch bridge; as for HTAB, temperature difference of arch rib has a small effect on rail tension/compression, and arch bridge can be simplified as a continuous beam for rail tension/compression additional force calculation; in calculation of deflection conditions of HTAB, it is suggested that train loads are arranged on half span and full span and take the direction of load entering bridge into account. Additionally, the deflection additional force variation of CFST basket handle arch bridge is different from that of ordinary bridge.

Emulsifier-free emulsion polymerization produces highly charged, monodisperse particles for near infrared photonic crystals.

Science.gov (United States)

Reese, Chad E; Asher, Sanford A

2002-04-01

We have developed emulsifier-free, emulsion polymerization recipes for the synthesis of highly charged, monodisperse latex particles of diameters between 500 and 1100 nm. These latexes consist of poly[styrene-(co-2-hydroxyethyl methacrylate)] spherical particles whose surfaces are functionalized with sulfate and carboxylic acid groups. These highly charged, monodisperse particles readily self-assemble into robust, three-dimensionally ordered crystalline colloidal array photonic crystals that Bragg diffract light in the near infrared spectral region. By altering the particle number density, the diffraction wavelength can be tuned from approximately 1000 to approximately 4000 nm.

High-Performance and Simply-Synthesized Ladder-Like Structured Methacrylate Siloxane Hybrid Material for Flexible Hard Coating

Directory of Open Access Journals (Sweden)

Yun Hyeok Kim

2018-04-01

Full Text Available A high performance ladder-like structured methacrylate siloxane hybrid material (LMSH was fabricated via simple hydrolytic sol–gel reaction, followed by free-radical polymerization. A structurally ordered siloxane backbone, the ladder-like structure, which is an essential factor for high performance, could be achieved by a short period of sol–gel reaction in only 4 h. This results in superior optical (Transmittance > 90% at 550 nm, thermal (T5 wt % decomposition > 400 ℃ , mechanical properties(elastic recovery = 0.86, hardness = 0.6 GPa compared to the random- and even commercialized cage-structured silsesquioxane, which also has ordered structure. It was investigated that the fabricated ladder-like structured MSH showed the highest overall density of organic/inorganic co-networks that are originated from highly ordered siloxane network, along with high conversion rate of polymerizable methacrylate groups. Our findings suggest a potential of the ladder-like structured MSH as a powerful alternative for the methacrylate polysilsesquioxane, which can be applied to thermally stable and flexible optical coatings, even with an easier and simpler preparation process.

Chemodiversity of Ladder-Frame Prymnesin Polyethers in Prymnesium parvum

DEFF Research Database (Denmark)

Rasmussen, Silas Anselm; Meier, Sebastian; Andersen, Nikolaj Gedsted

2016-01-01

Blooms of the microalga Prymnesium parvum cause devastating fish kills worldwide, which are suspected to be caused by the supersized ladder-frame polyether toxins prymnesin-1 and -2. These toxins have, however, only been detected from P. parvum in rare cases since they were originally described two...

The resonance self-shielding calculation with regularized random ladders

International Nuclear Information System (INIS)

Ribon, P.

1986-01-01

The straightforward method for calculation of resonance self-shielding is to generate one or several resonance ladders, and to process them as resolved resonances. The main drawback of Monte Carlo methods used to generate the ladders, is the difficulty of reducing the dispersion of data and results. Several methods are examined, and it is shown how one (a regularized sampling method) improves the accuracy. Analytical methods to compute the effective cross-section have recently appeared: they are basically exempt from dispersion, but are inevitably approximate. The accuracy of the most sophisticated one is checked. There is a neutron energy range which is improperly considered as statistical. An examination is presented of what happens when it is treated as statistical, and how it is possible to improve the accuracy of calculations in this range. To illustrate the results calculations have been performed in a simple case: nucleus 238 U, at 300 K, between 4250 and 4750 eV. (author)

Groundstate fidelity phase diagram of the fully anisotropic two-leg spin-½ XXZ ladder

Science.gov (United States)

Li, Sheng-Hao; Shi, Qian-Qian; Batchelor, Murray T.; Zhou, Huan-Qiang

2017-11-01

The fully anisotropic two-leg spin-\\tfrac{1}{2} XXZ ladder model is studied in terms of an algorithm based on the tensor network (TN) representation of quantum many-body states as an adaptation of projected entangled pair states to the geometry of translationally invariant infinite-size quantum spin ladders. The TN algorithm provides an effective method to generate the groundstate wave function, which allows computation of the groundstate fidelity per lattice site, a universal marker to detect phase transitions in quantum many-body systems. The groundstate fidelity is used in conjunction with local order and string order parameters to systematically map out the groundstate phase diagram of the ladder model. The phase diagram exhibits a rich diversity of quantum phases. These are the ferromagnetic, stripe ferromagnetic, rung singlet, rung triplet, Néel, stripe Néel and Haldane phases, along with the two XY phases XY1 and XY2.

Creating a Professional Ladder for Interpreters for Improvement of Care.

Science.gov (United States)

Marshall, Lori; Fischer, Anna; Noyes Soeller, Allison; Cordova, Richard; Gutierrez, Yvonne R; Alford, Luis

2016-01-01

Children's Hospital Los Angeles (CHLA), a metropolitan academic medical center, recognized limitations in how the professional interpreters from the Diversity Services Department were used to support effective patient-provider communication across the organization. Given the importance of mitigating language and communication barriers, CHLA sought to minimize clinical and structural barriers to health care for limited English proficiency populations through a comprehensive restructuring of the Diversity Services Department. This approach entailed a new delivery model for hospital language assistance and cultural consultancy resources. The intervention focused on restructuring the Diversity Services Department, redefining priorities, reallocating resources, and redefining the roles of the language staff positions in the department. The language staff role was redesigned to fit a four-level professional career ladder modeled after the professional career ladders commonly used in hospitals for the RN role and other professional disciplines. The approach involved creating new levels of language specialist, each with progressive requirements for performance, leadership, and accountability for patient care outcomes. Language staff in the inpatient, clinic, and emergency department settings worked alongside nurses, physicians, and other disciplines to care for a specific set of patients. The result of this work was a positive culture change resulting in service efficiencies, care improvements, and improved access to language services. A professional career ladder for language staff contributed to improving the quality and access of language services and advancing the interpreting profession by incorporating care coordination support, vital document translation, and cultural consultancy.

Role of Modular Polyketide Synthases in the Production of Polyether Ladder Compounds in Ciguatoxin-Producing Gambierdiscus polynesiensis and G. excentricus (Dinophyceae).

Science.gov (United States)

Kohli, Gurjeet S; Campbell, Katrina; John, Uwe; Smith, Kirsty F; Fraga, Santiago; Rhodes, Lesley L; Murray, Shauna A

2017-09-01

Gambierdiscus, a benthic dinoflagellate, produces ciguatoxins that cause the human illness Ciguatera. Ciguatoxins are polyether ladder compounds that have a polyketide origin, indicating that polyketide synthases (PKS) are involved in their production. We sequenced transcriptomes of Gambierdiscus excentricus and Gambierdiscus polynesiensis and found 264 contigs encoding single domain ketoacyl synthases (KS; G. excentricus: 106, G. polynesiensis: 143) and ketoreductases (KR; G. excentricus: 7, G. polynesiensis: 8) with sequence similarity to type I PKSs, as reported in other dinoflagellates. In addition, 24 contigs (G. excentricus: 3, G. polynesiensis: 21) encoding multiple PKS domains (forming typical type I PKSs modules) were found. The proposed structure produced by one of these megasynthases resembles a partial carbon backbone of a polyether ladder compound. Seventeen contigs encoding single domain KS, KR, s-malonyltransacylase, dehydratase and enoyl reductase with sequence similarity to type II fatty acid synthases (FAS) in plants were found. Type I PKS and type II FAS genes were distinguished based on the arrangement of domains on the contigs and their sequence similarity and phylogenetic clustering with known PKS/FAS genes in other organisms. This differentiation of PKS and FAS pathways in Gambierdiscus is important, as it will facilitate approaches to investigating toxin biosynthesis pathways in dinoflagellates. © 2017 The Author(s) Journal of Eukaryotic Microbiology © 2017 International Society of Protistologists.

Highly Selective Synthesis of Catalytically Active Monodisperse Rhodium Nanocubes

Energy Technology Data Exchange (ETDEWEB)

Zhang, Y.; Grass, M.E.; Kuhn, J.N.; Tao, F.; Habas, S.E.; Huang, W.; Yang, P.; Somorjai, G.A.

2009-02-21

Synthesis of monodisperse and shape-controlled colloidal inorganic nanocrystals (NCs) is of increasing scientific interest and technological significance. Recently, shape control of Pt, Pd, Ag, Au, and Rh NCs has been obtained by tuning growth kinetics in various solution-phase approaches, including modified polyol methods, seeded growth by polyol reduction, thermolysis of organometallics, and micelle techniques. Control of reduction kinetics of the noble metal precursors and regulation of the relative growth rates of low-index planes (i.e. {l_brace}100{r_brace} and {l_brace}111{r_brace}) via selective adsorption of selected chemical species are two keys for achieving shape modification of noble metal NCs. One application for noble metal NCs of well-defined shape is in understanding how NC faceting (determines which crystallographic planes are exposed) affects catalytic performance. Rh NCs are used in many catalytic reactions, including hydrogenation, hydroformylation, hydrocarbonylation, and combustion reactions. Shape manipulation of Rh NCs may be important in understanding how faceting on the nanoscale affects catalytic properties, but such control is challenging and there are fewer reports on the shape control of Rh NCs compared to other noble metals. Xia and coworkers obtained Rh multipods exhibiting interesting surface plasmonic properties by a polyol approach. The Somorjai and Tilley groups synthesized crystalline Rh multipods, cubes, horns and cuboctahedra, via polyol seeded growth. Son and colleagues prepared catalytically active monodisperse oleylamine-capped tetrahedral Rh NCs for the hydrogenation of arenes via an organometallic route. More recently, the Somorjai group synthesized sizetunable monodisperse Rh NCs using a one-step polyol technique. In this Communication, we report the highly selective synthesis of catalytically active, monodisperse Rh nanocubes of < 10 nm by a seedless polyol method. In this approach, Br{sup -} ions from trimethyl

Massive 3-loop ladder diagrams for quarkonic local operator matrix elements

Energy Technology Data Exchange (ETDEWEB)

Ablinger, Jakob; Schneider, Carsten [Johannes Kepler Univ., Linz (Austria). Research Inst. for Symbolic Computation; Bluemlein, Johannes; Hasselhuhn, Alexander; Wissbrock, Fabian [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany); Klein, Sebastian [Technische Hochschule Aachen (Germany). Inst. fuer Theoretische Physik

2012-06-15

3-loop diagrams of the ladder-type, which emerge for local quarkonic twist-2 operator matrix elements, are computed directly for general values of the Mellin variable N using Appell-function representations and applying modern summation technologies provided by the package Sigma and the method of hyperlogarithms. In some of the diagrams generalized harmonic sums with {xi} element of {l_brace}1,1/2,2{r_brace} emerge beyond the usual nested harmonic sums. As the asymptotic representation of the corresponding integrals shows, the generalized sums conspire giving well behaved expressions for large values of N. These diagrams contribute to the 3-loop heavy flavor Wilson coefficients of the structure functions in deep-inelastic scattering in the region Q{sup 2} >> m{sup 2}.

Massive 3-loop ladder diagrams for quarkonic local operator matrix elements

Energy Technology Data Exchange (ETDEWEB)

Ablinger, Jakob [Research Institute for Symbolic Computation (RISC), Johannes Kepler University, Altenbergerstrasse 69, A-4040 Linz (Austria); Bluemlein, Johannes, E-mail: johannes.bluemlein@desy.de [Deutsches Elektronen-Synchrotron, DESY, Platanenallee 6, D-15738 Zeuthen (Germany); Hasselhuhn, Alexander [Deutsches Elektronen-Synchrotron, DESY, Platanenallee 6, D-15738 Zeuthen (Germany); Klein, Sebastian [Research Institut fuer Theoretische Physik E, RWTH Aachen University, D-52056 Aachen (Germany); Schneider, Carsten [Research Institute for Symbolic Computation (RISC), Johannes Kepler University, Altenbergerstrasse 69, A-4040 Linz (Austria); Wissbrock, Fabian [Deutsches Elektronen-Synchrotron, DESY, Platanenallee 6, D-15738 Zeuthen (Germany)

2012-11-01

3-loop diagrams of the ladder-type, which emerge for local quarkonic twist-2 operator matrix elements, are computed directly for general values of the Mellin variable N using Appell-function representations and applying modern summation technologies provided by the package Sigma and the method of hyperlogarithms. In some of the diagrams generalized harmonic sums with {xi} Element-Of {l_brace}1,1/2,2{r_brace} emerge beyond the usual nested harmonic sums. As the asymptotic representation of the corresponding integrals shows, the generalized sums conspire giving well behaved expressions for large values of N. These diagrams contribute to the 3-loop heavy flavor Wilson coefficients of the structure functions in deep-inelastic scattering in the region Q{sup 2} Much-Greater-Than m{sup 2}.

Monitoring system of arch bridge for safety network management

Science.gov (United States)

Joo, Bong Chul; Yoo, Young Jun; Lee, Chin Hyung; Park, Ki Tae; Hwang, Yoon Koog

2010-03-01

Korea has constructed the safety management network monitoring test systems for the civil infrastructure since 2006 which includes airport structure, irrigation structure, railroad structure, road structure, and underground structure. Bridges among the road structure include the various superstructure types which are Steel box girder bridge, suspension bridge, PSC-box-girder bridge, and arch bridge. This paper shows the process of constructing the real-time monitoring system for the arch bridge and the measured result by the system. The arch type among various superstructure types has not only the structural efficiency but the visual beauty, because the arch type superstructure makes full use of the feature of curve. The main measuring points of arch bridges composited by curved members make a difference to compare with the system of girder bridges composited by straight members. This paper also shows the method to construct the monitoring system that considers the characteristic of the arch bridge. The system now includes strain gauges and thermometers, and it will include various sensor types such as CCTV, accelerometers and so on additionally. For the long term and accuracy monitoring, the latest optical sensors and equipments are applied to the system.

Michel Spiro is appointed director of the IN2P3 and the Department of Nuclear and Particle Physics of the CNRS

CERN Multimedia

2003-01-01

"Michel Spiro was appointed director of the IN2P3, by order of the Minister of Youth, National Education and Research and the Minister of Research and New Technologies on February 17, 2003. He was also appointed director of the Department of Nuclear and Particle Physics of the CNRS by decision of the CNRS Director General on February 21, 2003" (1/2 page).

High-energy, large-momentum-transfer processes: Ladder diagrams in φ3 theory. Pt. 1

International Nuclear Information System (INIS)

Osland, P.; Wu, T.T.; Harvard Univ., Cambridge, MA

1987-01-01

Relativistic quantum field theories may give us useful guidance to understanding high-energy, large-momentum-transfer processes, where the center-of-mass energy is much larger than the transverse momentum transfers, which are in turn much larger than the masses of the participating particles. With this possibility in mind, we study the ladder diagrams in φ 3 theory. In this paper, some of the necessary techniques are developed and applied to the simplest cases of the fourth- and sixth-order ladder diagrams. (orig.)

Experimental investigation of different fill materials in arch bridges with particular focus on Pearl-Chain Bridges

DEFF Research Database (Denmark)

Lund, Mia Schou Møller; Hansen, Kurt Kielsgaard; Hertz, Kristian Dahl

2016-01-01

Pearl-Chain Bridge technology is a recently developed prefabricated arch solution for road and railway bridges allowing faster, more environmentally friendly, and cheaper bridge construction. This study compared the strength and durability properties of three different types of fill material...

Breathers in Josephson junction ladders: Resonances and electromagnetic wave spectroscopy

DEFF Research Database (Denmark)

Miroshnichenko, A. E.; Flach, S.; Fistul, M.

2001-01-01

We present a theoretical study of the resonant interaction between dynamical localized states (discrete breathers) and linear electromagnetic excitations (EE's) in Josephson junction ladders. By making use of direct numerical simulations we find that such an interaction manifests itself by resonant...

29 CFR Appendix A to Subpart X of... - Ladders

Science.gov (United States)

2010-07-01

... 29 Labor 8 2010-07-01 2010-07-01 false Ladders A Appendix A to Subpart X of Part 1926 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR... designed and built in accordance with the applicable national consensus standards, as set forth below, will...

46 CFR 116.438 - Stairtowers, stairways, ladders, and elevators.

Science.gov (United States)

2010-10-01

... 46 Shipping 4 2010-10-01 2010-10-01 false Stairtowers, stairways, ladders, and elevators. 116.438 Section 116.438 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) SMALL PASSENGER VESSELS CARRYING MORE THAN 150 PASSENGERS OR WITH OVERNIGHT ACCOMMODATIONS FOR MORE THAN 49 PASSENGERS CONSTRUCTION AND ARRANGEMENT Fire Protection §...

The self-assembly of monodisperse nanospheres within microtubes

International Nuclear Information System (INIS)

Zheng Yuebing; Juluri, Bala Krishna; Huang, Tony Jun

2007-01-01

Self-assembled monodisperse nanospheres within microtubes have been fabricated and characterized. In comparison with colloidal crystals formed on planar substrates, colloidal nanocrystals self-assembled in microtubes demonstrate high spatial symmetry in their optical transmission and reflection properties. The dynamic self-assembly process inside microtubes is investigated by combining temporal- and spatial-spectrophotometric measurements. The understanding of this process is achieved through both experimentally recorded reflection spectra and finite difference time domain (FDTD)-based simulation results

Geometric Summary of the 9 Chip Ladder for the D0 Silicon Tracker

International Nuclear Information System (INIS)

Ratzmann, P.; Cooper, W.; Goloskie, D.; Kowalski, J.; Lipton, R.; Rapidis, P.; Serritella, C.

1997-01-01

Two hybrids types are required to accomodate the flipping of ladders within each bulkhead layer, in order to account for the pigtail routing. Left and right versions are shown below, following the definitions laid out by Mike Matulik. These drawings are not to proper scale in the sketches below. The dimensionally correct versions of the 9 chip hybrids are stored in DCS under drawing number 3823.112-MD-317803 for the lefthanded version, and 3823.112-MD-317804 for the right handed version. Handedness of the hybrids are designated as shown in the figures and table below. There are long and short versions of both the left and the right, for four total 9 chip hdi designs. The pigtail lengths of the long and short are shown in a table in the hybrid drawings which reside in DCS. The chamfer in the hybrid corners (N side) is placed in order to enable the hybrid to be glued to the beryllium substrate, whereas the rectangular cuttout on the same side is to allow direct gluing of a temperature sensor to the substrate metal. The oblong shape on the N side of both hybrids is a 'stay-clear' region (defined in the final drawings) where pressure will be applied to the hybrid during the second stage of ladder construction.

Monodisperse Magneto-Fluorescent Bifunctional Nanoprobes for Bioapplications

Science.gov (United States)

Zhang, Hongwang; Huang, Heng; Pralle, Arnd; Zeng, Hao

2013-03-01

We present the work on the synthesis of dye-doped monodisperse Fe/SiO2 core/shell nanoparticles as bifunctional probes for bioapplications. Magnetic nanoparticles (NP) have been widely studied as nano-probes for bio-imaging, sensing as well as for cancer therapy. Among all the NPs, Fe NPs have been the focus because they have very high magnetization. However, Fe NPs are usually not stable in ambient due to the fast surface oxidation of the NPs. On the other hand, dye molecules have long been used as probes for bio-imaging. But they are sensitive to environmental conditions. It requires passivation for both so that they can be stable for applications. In this work, monodisperse Fe NPs with sizes ranging from 13-20 nm have been synthesized through the chemical thermal-decomposition in a solution. Silica shells were then coated on the Fe NPs by a two-phase oil-in-water method. Dye molecules were first bonded to a silica precursor and then encapsulated into the silica shell during the coating process. The silica shells protect both the Fe NPs and dye molecules, which makes them as robust probes. The dye doped Fe/SiO2 core/shell NPs remain both highly magnetic and highly fluorescent. The stable dye doped Fe/SiO2NPs have been used as a dual functional probe for both magnetic heating and local nanoscale temperature sending, and their performance will be reported. Research supported by NSF DMR 0547036, DMR1104994.

Hybrid macrocycle formation and spiro annulation on cis-syn-cis-tricyclo[6.3.0.02,6]undeca-3,11-dione and its congeners via ring-closing metathesis

Directory of Open Access Journals (Sweden)

Sambasivarao Kotha

2015-07-01

Full Text Available We have developed a simple methodology to transform cis-syn-cis-triquinane derivative 2 into the diindole based macrocycle 6 involving Fischer indolization and ring-closing metathesis (RCM. Various spiro-polyquinane derivatives have been assembled via RCM as a key step.

Cutting and dismantling of the South West ladder of the Atucha I nuclear power plant

International Nuclear Information System (INIS)

Anasco, Roberto

2006-01-01

The metallic ladder built in stainless steel was used originally to check the welding of the reactor pressure vessel. It was located between the thermal insulation and reactor pressure vessel. Because of a failure in the mechanism, which let the ladder runs around the vessel, it had to be removed. A special tool remotely operated was designed to make different cuts in the bottom of the structure in a very high radioactive location [es

Steel-soil composite bridge

DEFF Research Database (Denmark)

Du, Guangli; Pettersson, Lars; Karoumi, Raid

2017-01-01

viability, while their environmental performance is overlooked. Today’s designers are urged to seek new design options to reduce the environmental burdens. Sweden owns more than 24574 bridges and most of them are short spans. Among them, the slab frame bridge (CFB) is a common solution. Soil steel composite...... bridge (SSCB), alternatively, is a functionally equivalent solution to CFB and shows advantages in low cost and easy construction. This paper compares the environmental performance between these two bridge types based on life cycle assessment (LCA). The analysis and result shows that, the SSCB...

Synthetic Polymers at Interfaces: Monodisperse Emulsions Multiple Emulsions and Liquid Marbles

Science.gov (United States)

Sun, Guanqing

The adsorption of polymeric materials at interfaces is an energetically favorable process which is investigated in much diversified fields, such as emulsions, bubbles, foams, liquid marbles. Pickering emulsion, which is emulsion stabilized by solid particles has been investigated for over one century and preparation of Pickering emulsion with narrow size distribution is crucial for both the theoretical study of the stabilization mechanism and practical application, such as templated fabrication of colloidosomes. The precise control over the size and functionality of polymer latices allows the preparation of monodisperse Pickering emulsions with desired sizes through SPG membrane emulsification at rather rapid rate compared to microfludic production. Double or multiple emulsions have long been investigated but its rapid destabilization has always been a major obstacle in applying them into practical applications. The modern living polymerization techniques allow us to prepare polymers with designed structure of block copolymers which makes it possible to prepare ultra-stable multiple emulsions. The precise tuning of the ratio of hydrophobic part over the hydrophilic can unveil the stabilization mechanism. Liquid marble is a new type of materials of which liquid droplets are coated by dry particles. The coating of an outer layer of dry particles renders the liquid droplets non-sticky at solid surface which is useful in transportation of small amount of liquid without leakage at extreme low friction force. The property of liquid marbles relies largely on the stabilizers and the drying condition of polymeric latices is shown to have great influence on the property of liquid marbles. Firstly, an introduction to the interfacial and colloidal science with special attention to topics on emulsions, multiple emulsion and liquid marbles is given in Chapter 1. The unique features of an interface and a discussion on the definition of colloids are introduced prior to the

New insights into the origin of ladder dikes: Implications for punctuated growth and crystal accumulation in the Cathedral Peak granodiorite

Science.gov (United States)

Wiebe, R. A.; Jellinek, A. M.; Hodge, K. F.

2017-04-01

Ladder dikes are steep tabular bodies, typically a meter or less thick, composed of moderately dipping, concave upward, alternating dark (i.e. schlieren) and light bands oriented roughly perpendicular to the ladder dike margins. These structures occur widely but sparsely in granitic rocks and are found prominently in the Cathedral Peak granodiorite (CPG) of the Tuolumne Intrusive suite. Previous studies have interpreted that ladder dikes form as a result of processes including the downward flow of crystal mush in cracks within strong crystal mush or by upward flow in steep tubes that migrate within a strong crystal mush. Our new observations indicate that ladder dikes formed by downward flow of crystal mush in troughs or valleys, in a manner potentially comparable to trough bands in mafic layered intrusions. Extensions of the schlieren outward and upward away from the ladder dike margins into the host granite demonstrate that the host granite was deposited as mounds on both sides at the same time as the ladder dikes. Ladder dikes, therefore, record lateral flows of crystal mush on a magma chamber floor. Vertical exposures suggest these flows are on the order of ten meters thick. Some steep exposures on granite domes indicate multiple ladder dikes (and flows) over a stratigraphic height of 80-100 m. Later (stratigraphically higher) flows commonly deform and erode the top of an earlier flow, and granitic material rich in K-feldspar megacrysts has locally engulfed large blocks of ladder dikes, demonstrating that the megacrysts were also transported in flows. Flows in the CPG are directed away from the center of the pluton toward the western and eastern margins and apparently spread along a strong crystal mush floor and into a rheologically complex CPG magma. Whereas established dynamical models for spreading (single phase) gravity currents with simple and complex rheologies explain the elongate geometry, spacing and orientation of the tabular bodies, the origin and

Seismic Performance of Multi-Span RC Railway Bridges

DEFF Research Database (Denmark)

Georgakis, Christos; Barrau, Xavier

2008-01-01

Presently, there is no clear method for determining the optimal railway bridge design for a particular ground type and expected seismic intensity. Four main types of RC bridge dominate the current multi-span railway bridge design trends – the Simply Supported Beam, Continuous Box-Girder (CBG), CBG...

Sonochemical synthesis of (3-aminopropyl)triethoxysilane-modified monodispersed silica nanoparticles for protein immobilization

International Nuclear Information System (INIS)

Shen, Shou-Cang; Ng, Wai Kiong; Chia, Leonard; Dong, Yuan-Cai; Tan, Reginald B.H.

2011-01-01

Graphical abstract: 3-Aminopropyltriethoxysilane modified monodispersed silica nanoparticles were synthesized by rapid sonochemical co-condensation to achieve high capability for protein immobilization. Highlights: → Amino-modified monodispersed silica nanoparticles were synthesized by rapid co-condensation. → Strong positive charge was created by aminopropyl-modification. → Capability for immobilization of negatively charged protein was enhanced. → Electrostatic interaction between proteins and surface contributed to the enhanced adsorption. -- Abstract: 3-Aminopropyltriethoxysilane modified monodispersed silica nanoparticles were synthesized by a rapid sonochemical co-condensation synthesis procedure. The chemical nature of surface organic modifier on the obtained modified silica nanoparticle was characterized by 13 C and 29 Si MAS Nuclear Magnetic Resonance (NMR) spectroscopies, Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA)- differential scanning calorimetry (DSC). Due to the strengthened positive surface charge of the silica nanoparticles by the modification with aminopropyl groups, the capability for bovine serum albumin (BSA) adsorption was significantly increased as compared with bare silica nanoparticles. 80 mg/g BSA was adsorbed on modified silica nanoparticles, whereas only 20 mg/g BSA could be loaded on pure silica nanoparticles. The enhanced positive surface charge repelled proteins with net positive charge and the modified silica nanoparticles exhibited negligible adsorption of lysozyme, thus a selective adsorption of proteins could be achieved.

Sonochemical synthesis of (3-aminopropyl)triethoxysilane-modified monodispersed silica nanoparticles for protein immobilization

Energy Technology Data Exchange (ETDEWEB)

Shen, Shou-Cang, E-mail: shen_shoucang@ices.a-star.edu.sg [Institute of Chemical and Engineering Sciences, A-STAR (Agency for Science, Technology and Research), 1 Pesek Road, Jurong Island, Singapore 627833 (Singapore); Ng, Wai Kiong; Chia, Leonard; Dong, Yuan-Cai [Institute of Chemical and Engineering Sciences, A-STAR (Agency for Science, Technology and Research), 1 Pesek Road, Jurong Island, Singapore 627833 (Singapore); Tan, Reginald B.H., E-mail: reginald_tan@ices.a-star.edu.sg [Institute of Chemical and Engineering Sciences, A-STAR (Agency for Science, Technology and Research), 1 Pesek Road, Jurong Island, Singapore 627833 (Singapore); Department of Chemical and Biomolecular Engineering, The National University of Singapore, 4 Engineering Drive 4, Singapore 117576 (Singapore)

2011-10-15

Graphical abstract: 3-Aminopropyltriethoxysilane modified monodispersed silica nanoparticles were synthesized by rapid sonochemical co-condensation to achieve high capability for protein immobilization. Highlights: {yields} Amino-modified monodispersed silica nanoparticles were synthesized by rapid co-condensation. {yields} Strong positive charge was created by aminopropyl-modification. {yields} Capability for immobilization of negatively charged protein was enhanced. {yields} Electrostatic interaction between proteins and surface contributed to the enhanced adsorption. -- Abstract: 3-Aminopropyltriethoxysilane modified monodispersed silica nanoparticles were synthesized by a rapid sonochemical co-condensation synthesis procedure. The chemical nature of surface organic modifier on the obtained modified silica nanoparticle was characterized by {sup 13}C and {sup 29}Si MAS Nuclear Magnetic Resonance (NMR) spectroscopies, Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA)- differential scanning calorimetry (DSC). Due to the strengthened positive surface charge of the silica nanoparticles by the modification with aminopropyl groups, the capability for bovine serum albumin (BSA) adsorption was significantly increased as compared with bare silica nanoparticles. 80 mg/g BSA was adsorbed on modified silica nanoparticles, whereas only 20 mg/g BSA could be loaded on pure silica nanoparticles. The enhanced positive surface charge repelled proteins with net positive charge and the modified silica nanoparticles exhibited negligible adsorption of lysozyme, thus a selective adsorption of proteins could be achieved.

Simple and inexpensive microfluidic devices for the generation of monodisperse multiple emulsions

KAUST Repository

Li, Erqiang; Zhang, Jiaming; Thoroddsen, Sigurdur T

2013-01-01

of expensive apparatus and a complex manufacturing procedure. Here, we report the design and fabrication of simple and inexpensive microfluidic devices based on microscope glass slides and pulled glass capillaries, for generating monodisperse multiple emulsions

“Why Caipirinha?”- The Online via Chat Laddering Technique CAN Answer

Directory of Open Access Journals (Sweden)

Bruno Bordeaux-Rego

2011-04-01

Full Text Available As customers are becoming increasingly connected to the internet, this means that they are available for online interviews, thus opening up a space for investigating research methods, especially qualitative research, in an attempt to identify how to adapt data collecting instruments to the so-called “connected customer era”. In this context, the focus of this article is on the application viability analysis of the laddering technique used online and in real-time chat by asking the following question: “Why caipirinha?”. Conducting online in-depth interviews through the MSN Messenger and Skype (the most commonly used chat tools in Brazil, 23 attributes, 22 consequences and 13 values were identified, resulting in 133 ladders, 71 of which reached the value level. Along with friends/mates, Integration, Entertainment and Fun, in addition to Alcohol, Insouciance/ relaxation and Pleasure constitute the most frequent ladders. Concerning the application itself, the participants gave positive feedback, even though some of them did not feel satisfied because they became tired. Convenience, objectivity, disinhibition, easy scheduling and flexibility were identified. The viability of online in-depth interviewing via real-time chats was confirmed, raising the question of the possibility of it achieving other qualitative research techniques.

High performance of visible-NIR broad spectral photocurrent application of monodisperse PbSe nanocubes decorated on rGO sheets

Science.gov (United States)

Ghorban Shiravizadeh, A.; Elahi, S. M.; Sebt, S. A.; Yousefi, Ramin

2018-02-01

In this work, the photoresponse performance of monodisperse PbSe nanocubes in the range of visible and near-infrared (NIR) (400-1500 nm) regions was enhanced by reduced graphene oxide (rGO). A simple cost-effective method is presented to synthesize monodisperse PbSe nanocubes (NCs) that are decorated on the rGO sheets. By the addition of PbSe/rGO nanocomposites with different rGO concentrations, pristine PbSe NCs were synthesized with the same method. Microscopy images showed that the size of NCs was smaller than the exciton Bohr radius (46 nm) of PbSe bulk. Therefore, the UV-Vis-IR spectroscopy result revealed that the PbSe/rGO samples had absorption peaks in the NIR region around 1650 nm and showed a blue shift compared to the absorption peak of the PbSe bulk. J-V measurements of the samples indicated that monodisperse PbSe/rGO nanocomposites had a higher resistance than the other samples under dark condition. On the other hand, the resistance of the monodisperse PbSe/rGO nanocomposites decreased under different light source illuminations while the resistance of the other samples was increased under illumination. Photodetector measurements indicated that the monodisperse morphology of the PbSe NCs enhanced the photoresponse speed and photocurrent intensity. In addition, responsivity (R) and detectivity (D*) of the samples were higher in the NIR region.

Copper-catalyzed difunctionalization of activated alkynes by radical oxidation-tandem cyclization/dearomatization to synthesize 3-trifluoromethyl spiro[4.5]trienones.

Science.gov (United States)

Hua, Hui-Liang; He, Yu-Tao; Qiu, Yi-Feng; Li, Ying-Xiu; Song, Bo; Gao, Pin; Song, Xian-Rong; Guo, Dong-Hui; Liu, Xue-Yuan; Liang, Yong-Min

2015-01-19

A copper-catalyzed difunctionalizing trifluoromethylation of activated alkynes with the cheap reagent sodium trifluoromethanesulfinate (NaSO2CF3 or Langlois' reagent) has been developed incorporating a tandem cyclization/dearomatization process. This strategy affords a straightforward route to synthesis of 3-(trifluoromethyl)-spiro[4.5]trienones, and presents an example of difunctionalization of alkynes for simultaneous formation of two carbon-carbon single bonds and one carbon-oxygen double bond. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Generalized ladder operators for the Dirac-Coulomb problem via SUSY QM

International Nuclear Information System (INIS)

Rodrigues, R. de Lima; Universidade Federal de Campina Grande, PB

2003-12-01

The supersymmetry in quantum mechanics and shape invariance condition are applied as an algebraic method to solving the Dirac-Coulomb problem. The ground state and the excited states are investigated via new generalized ladder operators. (author)

3′,6′-Bis(diethylamino-3H-spiro[2-benzothiophene-1,9′-xanthene]-3-thione

Directory of Open Access Journals (Sweden)

Bing-Yuan Su

2008-11-01

Full Text Available The title compound, C28H30N2OS2, was obtained by thionation of 3′,6′-bis(diethylamino-3H-spiro[isobenzofuran-1,9′-xanthene]-3-one with 2,4-bis(p-methoxyphenyl-1,3-dithiadiphosphetane disulfide (Lawesson's reagent. The planes of the two benzene rings of the xanthene system are inclined at a dihedral angle of 17.4 (1°, and the plane of the dithiophthalide group and the planes through the two benzene rings of the xanthene system make dihedral angles of 80.2 (1 and 82.8 (1°, respectively.

Orbital currents and charge density waves in a generalized Hubbard ladder

International Nuclear Information System (INIS)

Fjaerestad, J.O.; Marston, J.B.; Schollwoeck, U.

2006-01-01

We study a generalized Hubbard model on the two-leg ladder at zero temperature, focusing on a parameter region with staggered flux (SF)/d-density wave (DDW) order. To guide our numerical calculations, we first investigate the location of a SF/DDW phase in the phase diagram of the half-filled weakly interacting ladder using a perturbative renormalization group (RG) and bosonization approach. For hole doping δ away from half-filling, finite-system density-matrix renormalization-group (DMRG) calculations are used to study ladders with up to 200 rungs for intermediate-strength interactions. In the doped SF/DDW phase, the staggered rung current and the rung electron density both show periodic spatial oscillations, with characteristic wavelengths 2/δ and 1/δ, respectively, corresponding to ordering wavevectors 2k F and 4k F for the currents and densities, where 2k F = π (1 - δ). The density minima are located at the anti-phase domain walls of the staggered current. For sufficiently large dopings, SF/DDW order is suppressed. The rung density modulation also exists in neighboring phases where currents decay exponentially. We show that most of the DMRG results can be qualitatively understood from weak-coupling RG/bosonization arguments. However, while these arguments seem to suggest a crossover from non-decaying correlations to power-law decay at a length scale of order 1/δ, the DMRG results are consistent with a true long-range order scenario for the currents and densities

Organic inorganic hybrid coating (poly(methyl methacrylate)/monodisperse silica)

Science.gov (United States)

Rubio, E.; Almaral, J.; Ramírez-Bon, R.; Castaño, V.; Rodríguez, V.

2005-04-01

Polymethylmethacrylate-silica hybrid coatings were prepared from methyl methacrylate and monodisperse colloidal silica prepared by the Stöber method. The surfaces of the spheres were successfully modified by chemical reaction with 3-(trimethoxysilyl) propyl methacrylate (TMSPM) to compatibilise the organic and inorganic components of the precursor solution mixture. The coatings were deposited by dip-coating on glass substrates. They result with good properties of homogeneity, optical transparence, hardness and adhesion.

Metal Fe3+ ions assisted synthesis of highly monodisperse Ag/SiO2 nanohybrids and their antibacterial activity

International Nuclear Information System (INIS)

Zhang, Nianchun; Xue, Feng; Yu, Xiang; Zhou, Huihua; Ding, Enyong

2013-01-01

Graphical abstract: TEM images of the Ag/SiO 2 -2 nanohybrids. The homogeneous and more mono-disperse Ag nanoparticles deposit on SiO 2 spheres. Through this method, Ag nanoparticles are easily formed on the surface of SiO 2 compared to other methods. Highlights: ► We prepared homogeneous and mono-dispersed Ag/SiO 2 -2 nanohybrids by adding Fe 3+ ions. ► The Ag/SiO 2 -2 nanohybrids had core(SiO 2 )-shell(Ag) structure. ► The Ag/SiO 2 -2 nanohybrids exhibited excellent antibacterial activity against bacteria. ► The reaction temperature was lower and the yield of Ag/SiO 2 -2 nanohybrids were higher. - Abstract: Highly monodispersed Ag/SiO 2 nanohybrids with excellent antibacterial property were synthesized by using DMF as a reducing agent and employing an additional redox potential of metal Fe 3+ ion as a catalytic agent. The obtained Ag/SiO 2 -2 nanohybrids of about 240 nm were highly monodispersity and uniformity by adding trace Fe 3+ ions into the reaction which Ag + reacted with N,N-dimethyl formamide (DMF) at 70 °C. Compared to the conventional techniques, which need long time and high temperature for silica coating of Ag nanoparticles, this new method was capable of synthesizing monodispersed, uniform, high yield Ag/SiO 2 nanohybrids. The electron was transferred from the Fe 2+ ion to the Ag + ion to accelerate the nucleation of silver nanoparticles. The chemical structures, morphologies and properties of the Ag/SiO 2 nanohybrids were characterized by X-ray diffraction (XRD), (High-resolution, Scanning transmission) transmission electron microscopy (TEM, HRTEM and STEM), and X-ray photoelectron spectroscopy (XPS), and UV–vis spectroscopy (UV–vis) and test of antibacterial. The results demonstrated that the silver nanoparticles supported on the surface of SiO 2 spheres in Ag/SiO 2 -2 nanohybrids structure, the Ag nanoparticles were homogeneous and monodispersed. The results also indicated that the Ag/SiO 2 -2 nanohybrid had excellent antibacterial.

Integral Abutment and Jointless Bridges

Directory of Open Access Journals (Sweden)

Cristian-Claudiu Comisu

2005-01-01

Full Text Available Integral bridges, or integral abutment and jointless bridges, as they are more commonly known in the USA, are constructed without any movement joints between spans or between spans and abutments. Typically these bridges have stub-type abutments supported on piles and continuous bridge deck from one embankment to the other. Foundations are usually designed to be small and flexible to facilitate horizontal movement or rocking of the support. Integrally bridges are simple or multiple span ones that have their superstructure cast integrally with their substructure. The jointless bridges cost less to construct and require less maintenance then equivalent bridges with expansion joints. Integral bridges present a challenge for load distribution calculations because the bridge deck, piers, abutments, embankments and soil must all be considered as single compliant system. This paper presents some of the important features of integral abutment and jointless bridge design and some guidelines to achieve improved design. The goal of this paper is to enhance the awareness among the engineering community to use integral abutment and jointless bridges in Romania.

Wireless Smart Sensor Network System Using SmartBridge Sensor Nodes for Structural Health Monitoring of Existing Concrete Bridges

Science.gov (United States)

Gaviña, J. R.; Uy, F. A.; Carreon, J. D.

2017-06-01

There are over 8000 bridges in the Philippines today according to the Department of Public Works and Highways (DPWH). Currently, visual inspection is the most common practice in monitoring the structural integrity of bridges. However, visual inspections have proven to be insufficient in determining the actual health or condition of a bridge. Structural Health Monitoring (SHM) aims to give, in real-time, a diagnosis of the actual condition of the bridge. In this study, SmartBridge Sensor Nodes were installed on an existing concrete bridge with American Association of State Highway and Transportation Officials (AASHTO) Type IV Girders to gather vibration of the elements of the bridge. Also, standards on the effective installation of SmartBridge Sensor Nodes, such as location and orientation was determined. Acceleration readings from the sensor were then uploaded to a server, wherein they are monitored against certain thresholds, from which, the health of the bridge will be derived. Final output will be a portal or webpage wherein the information, health, and acceleration readings of the bridge will be available for viewing. With levels of access set for different types of users, the main users will have access to download data and reports. Data transmission and webpage access are available online, making the SHM system wireless.

New type of thermal analyzer with a micro-air-bridge heater

Science.gov (United States)

Kimura, Mitsuteru; Hayasaka, Junichi

1997-11-01

Miniaturized sensor for thermal analysis is fabricated using micromachining technique and its fundament al characteristics are obtained. This device fabricated in a Si substrate consists of monolithically integrated components of an air-bridge type microheater, a thin film thermocouple and a sample-holder. Boiling points of liquid samples, water and methanol, are observed in the heating curve and the heating-rate curve, and sudden decrease of the temperature at the dropping time of the liquid samples at room temperature due to the effect of evaporation heat is also observed. Loss of the sample due to the evaporation during heating was theoretically discussed.

Synthesis of highly monodisperse particles composed of a magnetic core and fluorescent shell.

Science.gov (United States)

Nagao, Daisuke; Yokoyama, Mikio; Yamauchi, Noriko; Matsumoto, Hideki; Kobayashi, Yoshio; Konno, Mikio

2008-09-02

Highly monodisperse particles composed of a magnetic silica core and fluorescent polymer shell were synthesized with a combined technique of heterocoagulation and soap-free emulsion polymerization. Prior to heterocoagulation, monodisperse, submicrometer-sized silica particles were prepared with the Stober method, and magnetic nanoparticles were prepared with a modified Massart method in which a cationic silane coupling agent of N-trimethoxysilylpropyl- N, N, N-trimethylammonium chloride was added just after coprecipitation of Fe (2+) and Fe (3+). The silica particles with negative surface potential were heterocoagulated with the magnetic nanoparticles with positive surface potential. The magnetic silica particles obtained with the heterocoagulation were treated with sodium silicate to modify their surfaces with silica. In the formation of a fluorescent polymer shell onto the silica-coated magnetic silica cores, an amphoteric initiator of 2,2'-azobis[ N-(2-carboxyethyl)-2-2-methylpropionamidine] (VA-057) was used to control the colloidal stability of the magnetic cores during the polymer coating. The polymerization of St in the presence of a hydrophobic fluorophore of pyrene could coat the cores with fluorescent polymer shells, resulting in monodisperse particles with a magnetic silica core and fluorescent polymer shell. Measurements of zeta potential for the composite particles in different pH values indicated that the composite particles had an amphoteric property originating from VA-057 initiator.

75 FR 62181 - Annual Materials Report on New Bridge Construction and Bridge Rehabilitation

Science.gov (United States)

2010-10-07

... INFORMATION CONTACT: Ms. Ann Shemaka, Office of Bridge Technology, HIBT-30, (202) 366-1575, or Mr. Thomas Everett, Office of Bridge Technology, HIBT-30, (202) 366-4675, Federal Highway Administration, 1200 New... is categorized by the following material types, which are identified in the NBI: steel, concrete, pre...

76 FR 55160 - Annual Materials Report on New Bridge Construction and Bridge Rehabilitation

Science.gov (United States)

2011-09-06

... INFORMATION CONTACT: Ms. Ann Shemaka, Office of Bridge Technology, HIBT-30, (202) 366-1575, or Mr. Thomas Everett, Office of Bridge Technology, HIBT-30, (202) 366-4675, Federal Highway Administration, 1200 New... is categorized by the following material types, which are identified in the NBI: steel, concrete, pre...

Determination of vertical pressures on running wheels of freight trolleys of bridge type cranes

Science.gov (United States)

Goncharov, K. A.; Denisov, I. A.

2018-03-01

The problematic issues of the design of the bridge-type trolley crane, connected with ensuring uniform load distribution between the running wheels, are considered. The shortcomings of the existing methods of calculation of reference pressures are described. The results of the analytical calculation of the pressure of the support wheels are compared with the results of the numerical solution of this problem for various schemes of trolley supporting frames. Conclusions are given on the applicability of various methods for calculating vertical pressures, depending on the type of metal structures used in the trolley.

End States, Ladder Compounds, and Domain-Wall Fermions

International Nuclear Information System (INIS)

Creutz, M.

1999-01-01

A magnetic field applied to a cross-linked ladder compound can generate isolated electronic states bound to the ends of the chain. After exploring the interference phenomena responsible, I discuss a connection to the domain-wall approach to chiral fermions in lattice gauge theory. The robust nature of the states under small variations of the bond strengths is tied to chiral symmetry and the multiplicative renormalization of fermion masses. copyright 1999 The American Physical Society

Synthesis of spiro-4H-pyrazole-oxindoles and fused 1H-pyrazoles via divergent, thermally induced tandem cyclization/migration of alkyne-tethered diazo compounds.

Science.gov (United States)

Zhang, Cheng; Dong, Shanliang; Zheng, Yang; He, Ciwang; Chen, Jiaolong; Zhen, Jingsen; Qiu, Lihua; Xu, Xinfang

2018-01-31

A thermally induced, substrate-dependent reaction of alkynyl diazo compounds has been developed. This transformation produces spiro-4H-pyrazole-oxindoles and fused 1H-pyrazoles in good to high yields from the corresponding alpha-cyano and alpha-sulfonyl diazo compounds. The salient features of this reaction include excellent chemoselectivity and atom-economy, mild reaction conditions, simple purification and potential for large scale production.

Development of inspection robots for bridge cables.

Science.gov (United States)

Yun, Hae-Bum; Kim, Se-Hoon; Wu, Liuliu; Lee, Jong-Jae

2013-01-01

This paper presents the bridge cable inspection robot developed in Korea. Two types of the cable inspection robots were developed for cable-suspension bridges and cable-stayed bridge. The design of the robot system and performance of the NDT techniques associated with the cable inspection robot are discussed. A review on recent advances in emerging robot-based inspection technologies for bridge cables and current bridge cable inspection methods is also presented.

Laboratory evaluation of a vibrating orifice monodisperse aerosol generator

International Nuclear Information System (INIS)

Everitt, N.M.; Snelling, K.W.

1985-02-01

The Berglund-Liu vibrating orifice aerosol generator is capable of producing monodisperse particles in the diameter range 5 to 50 μm. Experiments have been carried out to set up and evaluate such a generator for the preparation of standard liquid (olive oil) and solid (methylene blue) aerosols in the size range 8 to 13 μm. Modifications have been made to the apparatus to improve its performance and increase its particle output. (author)

Optimization of a simple technique for preparation of monodisperse poly(lactide-co-glycolide) nanospheres

Energy Technology Data Exchange (ETDEWEB)

Ito, Fuminori, E-mail: fuminoito@spice.ocn.ne.jp [Tokyo Metropolitan University, Department of Applied Chemistry, Graduate School of Urban Environmental Sciences (Japan)

2016-09-15

In this study, we report the optimization of a solvent evaporation technique for preparing monodisperse poly-(lactide-co-glycolide) (PLGA) nanospheres, from a mixture of solvents composed of ethanol and PVA solution. Various experimental conditions were investigated in order to control the particle size and size distribution of the nanospheres. In addition, nanospheres containing rifampicin (RFP, an antituberculosis drug), were prepared using PLGA of various molecular weights, to study the effects of RFP as a model hydrophobic drug. The results showed that a higher micro-homogenizer stirring rate facilitated the preparation of monodisperse PLGA nanospheres with a low coefficient of variation (~20 %), with sizes below 200 nm. Increasing the PLGA concentration from 0.1 to 0.5 g resulted in an increase in the size of the obtained nanospheres from 130 to 174 nm. The molecular weight of PLGA had little effect on the particle sizes and particle size distributions of the nanospheres. However, the drug loading efficiencies of the obtained RFP/PLGA nanospheres decreased when the molecular weight of PLGA was increased. Based on these experiments, an optimized technique was established for the preparation of monodisperse PLGA nanospheres, using the method developed by the authors.Graphical Abstract.

Gluon ladders in pp (pp-bar) collisions

International Nuclear Information System (INIS)

Machado, Magno Valerio Trindade; Ducati, Maria Beatriz Gay

2000-01-01

Full text follows: We study the contribution of a finite sum of gluon ladders to the hadronic processes showing that a reliable description is obtained using two order on perturbation theory. The pp(pp-bar) total cross sections are described with good agreement, consistent with unitarity bound. We also calculate the elastic scattering amplitude at non zero momentum transfer t, introducing two distinct Ansatz for the proton impact factor. As a by product the elastic differential cross section is obtained at small t approximation and compared with the data. (author)

Interband optical absorption in the Wannier-Stark ladder under the electron-LO-phonon resonance condition

International Nuclear Information System (INIS)

Govorov, A.O.

1993-08-01

Interband optical absorption in the Wannier-Stark ladder in the presence of the electron-LO-phonon resonance is investigated theoretically. The electron-LO-phonon resonance occurs when the energy spacing between adjacent Stark-ladder levels coincides with the LO-phonon energy. We propose a model describing the polaron effect in a superlattice. Calculations show that the absorption line shape is strongly modified due to the polaron effect under the electron-LO-phonon resonance condition. We consider optical phenomena in a normal magnetic field that leads to enhancement of polaron effects. (author). 17 refs, 5 figs

Low-Field Bi-Skyrmion Formation in a Noncentrosymmetric Chimney Ladder Ferromagnet

Science.gov (United States)

Takagi, R.; Yu, X. Z.; White, J. S.; Shibata, K.; Kaneko, Y.; Tatara, G.; Rønnow, H. M.; Tokura, Y.; Seki, S.

2018-01-01

The real-space spin texture and the relevant magnetic parameters were investigated for an easy-axis noncentrosymmetric ferromagnet Cr11 Ge19 with Nowotny chimney ladder structure. Using Lorentz transmission electron microscopy, we report the formation of bi-Skyrmions, i.e., pairs of spin vortices with opposite magnetic helicities. The quantitative evaluation of the magnetocrystalline anisotropy and Dzyaloshinskii-Moriya interaction (DMI) proves that the magnetic dipolar interaction plays a more important role than the DMI on the observed bi-Skyrmion formation. Notably, the critical magnetic field value required for the formation of bi-Skyrmions turned out to be extremely small in this system, which is ascribed to strong easy-axis anisotropy associated with the characteristic helix crystal structure. The family of Nowotny chimney ladder compounds may offer a unique material platform where two distinctive Skyrmion formation mechanisms favoring different topological spin textures can become simultaneously active.

Two-leg ladder systems with dipole–dipole Fermion interactions

Science.gov (United States)

Mosadeq, Hamid; Asgari, Reza

2018-05-01

The ground-state phase diagram of a two-leg fermionic dipolar ladder with inter-site interactions is studied using density matrix renormalization group (DMRG) techniques. We use a state-of-the-art implementation of the DMRG algorithm and finite size scaling to simulate large system sizes with high accuracy. We also consider two different model systems and explore stable phases in half and quarter filling factors. We find that in the half filling, the charge and spin gaps emerge in a finite value of the dipole–dipole and on-site interactions. In the quarter filling case, s-wave superconducting state, charge density wave, homogenous insulating and phase separation phases occur depend on the interaction values. Moreover, in the dipole–dipole interaction, the D-Mott phase emerges when the hopping terms along the chain and rung are the same, whereas, this phase has been only proposed for the anisotropic Hubbard model. In the half filling case, on the other hand, there is either charge-density wave or charged Mott order phase depends on the orientation of the dipole moments of the particles with respect to the ladder geometry.

Development of Inspection Robots for Bridge Cables

Directory of Open Access Journals (Sweden)

Hae-Bum Yun

2013-01-01

Full Text Available This paper presents the bridge cable inspection robot developed in Korea. Two types of the cable inspection robots were developed for cable-suspension bridges and cable-stayed bridge. The design of the robot system and performance of the NDT techniques associated with the cable inspection robot are discussed. A review on recent advances in emerging robot-based inspection technologies for bridge cables and current bridge cable inspection methods is also presented.

Synthesis of Monodispersed Spherical Single Crystalline Silver Particles by Wet Chemical Process; Shisshiki kagakuho ni yoru tanbunsankyujo tankesshoginryushi no gose

Energy Technology Data Exchange (ETDEWEB)

Ueyama, Ryousuke.; Harada, Masahiro.; Ueyama, Tamotsu.; Harada, Akio. [Daiken Chemistry Industry Corporation, Osaka (Japan); Yamamoto, Takashi. [National Defence Academy, Kanagawa (Japan). Dept. of Electrical Engineering; Shiosaki, Tadashi. [Nara Institute of Science and Technology, Nara (Japan). Graduate School of Materials Science; Kuribayashi, Kiyoshi. [Teikyo University of Science and Technology, Yamanashi (Japan). Dept. of Materials

1999-01-01

Ultrafine silver monodispersed particle were prepared by wet chemical process. To decrease the reduction speed, an important factor in generating monodispersed particles is to control the following three factors: synthesis temperature, concentration of aggregation-relaxing agent added, and concentration of silver nitrate solution. Synthesis of monodispersed spherical Ag particles, used as metal powders for electrode, became possible using the nucleus grouwth reaction method. This process also allowed the control of the diameter of the powder particles. The silver particles were distributed in ta narrow particle diameter range with on average of 0.5 {mu}m. Transmission electron microscopy (TEM) revealed that single-crystalline silver particles were prepared by the present method. (author)

Monodispersed macroporous architecture of nickel-oxide film as an anode material for thin-film lithium-ion batteries

International Nuclear Information System (INIS)

Wu, Mao-Sung; Lin, Ya-Ping

2011-01-01

A nickel-oxide film with monodispersed open macropores was prepared on a stainless-steel substrate by electrophoretic deposition of a polystyrene-sphere monolayer followed by anodic electrodeposition of nickel oxy-hydroxide. The deposited films convert to cubic nickel oxide after annealing at 400 o C for 1 h. Galvanostatic charge and discharge results indicate that the nickel-oxide film with monodispersed open macropores is capable of delivering a higher capacity than the bare nickel-oxide film, especially in high-rate charge and discharge processes. The lithiation capacity of macroporous nickel oxide reaches 1620 mA h g -1 at 1 C current discharge and decreases to 990 mA h g -1 at 15 C current discharge. The presence of monodispersed open macropores in the nickel-oxide film might facilitate the electrolyte penetration, diffusion, and migration. Electrochemical reactions between nickel oxide and lithium ions are therefore markedly improved by this tailored film architecture.

Recurrent variational approach to the two-leg Hubbard ladder

International Nuclear Information System (INIS)

Kim, E.H.; Sierra, G.; Duffy, D.

1999-01-01

We applied the recurrent variational approach to the two-leg Hubbard ladder. At half filling, our variational ansatz was a generalization of the resonating valence-bond state. At finite doping, hole pairs were allowed to move in the resonating valence-bond background. The results obtained by the recurrent variational approach were compared with results from density matrix renormalization group. copyright 1999 The American Physical Society

New iridium complex as additive to the spiro-OMeTAD in perovskite solar cells with enhanced stability

Directory of Open Access Journals (Sweden)

Laura Badia

2014-08-01

Full Text Available A new iridium complex, IrCp*Cl(PyPyz[TFSI], has been synthesized and used as additive for the hole transporter material, spiro-OMeTAD, in perovskite solar cells. The cells prepared with this Ir additive present higher efficiency than reference cells, and similar to cells prepared with Co additive. We have determined that the presence of metal complexes as additives decreases the recombination rate, as it has been observed by impedance spectroscopy. Very interestingly, while the efficiency after 3 months decreases by 22% and 70% for reference cell and cell with Co additive, respectively, the efficiency of devices containing the Ir additive is only decreased by a 4%.

A one-dimensional ladder-like coordination polymer: poly[[hexa­aqua­bis(μ-5-nitro­benzene-1,3-dicarboxyl­ato-κ3 O,O′,O′′)(μ-oxalato-κ4 O,O′:O′′,O′′′)diyttrium(III)] trihydrate

OpenAIRE

Fu, Zhong; Lin, Ying; Zhou, Yun-You; Zhang, Hong-Tao

2007-01-01

In the crystal structure of the title one-dimensional coordination polymer, [Y2(C8H3NO6)2(C2O4)(H2O)6]·3H2O, each YIII ion is bridged to its neighbours by two 5-nitrobenzene-1,3-dicarboxylate (nbdc) dianions and one oxalate dianion (located on an inversion centre) to form a ladder-like polymeric structure. The two carboxylate groups of nbdc assume different modes of coordination, one is chelating whereas the other is monodentate. Three water molecules coordinate to the YIII ion to comple...

Resonant states and wavepacket super-diffusion in intra-chain correlated ladders with diluted disorder

International Nuclear Information System (INIS)

De Moura, F A B F; Leao, F F S; Lyra, M L

2011-01-01

In this work, we study a tight-binding Hamiltonian model system of a binary correlated ladder with diluted disorder. We introduce intra-chain correlations between the on-site potentials by imposing that ε i, s = - ε i,-s where s = ± 1 indexes the two ladder chains. Further, we consider each ladder chain as composed of inter-penetrating ordered and random sub-chains. We show that the presence of a random on-site distribution in one of the inter-penetrating chains leads to Anderson localization except at a specific symmetric pair of energy eigenmodes. Further, by integrating the time-dependent Schroedinger equation, we follow the time-evolution of an initially localized one-electron wavepacket. We report that the remaining delocalized resonant modes are responsible for a super-diffusive spread of the wavepacket dispersion while the wavepacket participation function remains finite. A scaling analysis of the wavepacket distribution shows that it obeys a universal scaling form with the development of a power-law tail followed by a super-diffusively evolving cutoff. We obtain three exponents characterizing this super-diffusive dynamics and show that they satisfy a simple scaling relation.

Modification of the Ladder Rung Walking Task—New Options for Analysis of Skilled Movements

Directory of Open Access Journals (Sweden)

Iwa Antonow-Schlorke

2013-01-01

Full Text Available Method sensitivity is critical for evaluation of poststroke motor function. Skilled walking was assessed in horizontal, upward, and downward rung ladder walking to compare the demands of the tasks and test sensitivity. The complete step sequence of a walk was subjected to analysis aimed at demonstrating the walking pattern, step sequence, step cycle, limb coordination, and limb interaction to complement the foot fault scoring system. Rats (males, n=10 underwent unilateral photothrombotic lesion of the motor cortex of the forelimb and hind limb areas. Locomotion was video recorded before the insult and at postischemic days 7 and 28. Analysis of walking was performed frame-by-frame. Walking along the rung ladder revealed different results that were dependent on ladder inclination. Horizontal walking was found to discriminate lesion-related motor deficits in forelimb, whereas downward walking demonstrates hind limb use most sensitively. A more frequent use of the impaired forelimb that possibly supported poststroke motor learning in rats was shown. The present study provides a novel system for a detailed analysis of the complete walking sequence and will help to provide a better understanding of how rats deal with motor impairments.

Progress in Preparation of Monodisperse Polymer Microspheres

Science.gov (United States)

Zhang, Hongyan

2017-12-01

The monodisperse crosslinked polymer microspheres have attracted much attention because of their superior thermal and solvent resistance, mechanical strength, surface activity and adsorption properties. They are of wide prospects for using in many fields such as biomedicine, electronic science, information technology, analytical chemistry, standard measurement and environment protection etc. Functional polymer microspheres prepared by different methods have the outstanding surface property, quantum size effect and good potential future in applications with its designable structure, controlled size and large ratio of surface to volume. Scholars of all over the world have focused on this hot topic. The preparation method and research progress in functional polymer microspheres are addressed in the paper.

Multi-material size optimization of a ladder frame chassis

Science.gov (United States)

Baker, Michael

The Corporate Average Fuel Economy (CAFE) is an American fuel standard that sets regulations on fuel economy in vehicles. This law ultimately shapes the development and design research for automakers. Reducing the weight of conventional cars offers a way to improve fuel efficiency. This research investigated the optimality of an automobile's ladder frame chassis (LFC) by conducting multi-objective optimization on the LFC in order to reduce the weight of the chassis. The focus of the design and optimization was a ladder frame chassis commonly used for mass production light motor vehicles with an open-top rear cargo area. This thesis is comprised of two major sections. The first looked to perform thickness optimization in the outer walls of the ladder frame. In the second section, many multi-material distributions, including steel and aluminium varieties, were investigated. A simplified model was used to do an initial hand calculation analysis of the problem. This was used to create a baseline validation to compare the theory with the modeling. A CAD model of the LFC was designed. From the CAD model, a finite element model was extracted and joined using weld and bolt connectors. Following this, a linear static analysis was performed to look at displacement and stresses when subjected to loading conditions that simulate harsh driving conditions. The analysis showed significant values of stress and displacement on the ends of the rails, suggesting improvements could be made elsewhere. An optimization scheme was used to find the values of an all steel frame an optimal thickness distribution was found. This provided a 13% weight reduction over the initial model. To advance the analysis a multi-material approach was used to push the weight savings even further. Several material distributions were analyzed and the lightest utilized aluminium in all but the most strenuous subjected components. This enabled a reduction in weight of 15% over the initial model, equivalent to

THE PAN-STARRS 1 PHOTOMETRIC REFERENCE LADDER, RELEASE 12.01

International Nuclear Information System (INIS)

Magnier, E. A.; Tonry, J. L.; Burgett, W. S.; Chambers, K. C.; Flewelling, H. A.; Kaiser, N.; Kudritzki, R.-P.; Morgan, J. S.; Sweeney, W. E.; Schlafly, E.; Finkbeiner, D.; Juric, M.; Stubbs, C. W.; Price, P. A.

2013-01-01

As of 2012 January 21, the Pan-STARRS 1 3π Survey has observed the 3/4 of the sky visible from Hawaii with a minimum of 2 and mean of 7.6 observations in five filters, g P1 , r P1 , i P1 , z P1 , y P1 . Now at the end of the second year of the mission, we are in a position to make an initial public release of a portion of this unprecedented data set. This article describes the PS1 Photometric Ladder, Release 12.01. This is the first of a series of data releases to be generated as the survey coverage increases and the data analysis improves. The Photometric Ladder has rungs every hour in right ascension and at four intervals in declination. We will release updates with increased area coverage (more rungs) from the latest data set until the PS1 survey and the final re-reduction are completed. The currently released catalog presents photometry of ∼1000 objects per square degree in the rungs of the ladder. Saturation occurs at g P1 , r P1 , i P1 ∼ 13.5; z P1 ∼ 13.0; and y P1 ∼ 12.0. Photometry is provided for stars down to g P1 , r P1 , i P1 ∼ 19.1 in the AB system. This data release depends on the rigid 'Ubercal' photometric calibration using only the photometric nights, with systematic uncertainties of (8.0, 7.0, 9.0, 10.7, 12.4) mmag in (g P1 , r P1 , i P1 , z P1 , y P1 ). Areas covered only with lower quality nights are also included, and have been tied to the Ubercal solution via relative photometry; photometric accuracy of the non-photometric regions is lower and should be used with caution.

Direct observation of magnon fractionalization in the quantum spin ladder

NARCIS (Netherlands)

Thielemann, B.; Rüegg, C.; Rønnow, H.M.; Läuchli, A.M.; Caux, J.S.; Normand, B.; Biner, D.; Krämer, K.W.; Güdel, H.U.; Stahn, J.; Habicht, K.; Kiefer, K.; Boehm, M.; McMorrow, D.F.; Mesot, J.

2009-01-01

We measure by inelastic neutron scattering the spin excitation spectra as a function of applied magnetic field in the quantum spin-ladder material (C5H12N)2CuBr4. Discrete magnon modes at low fields in the quantum disordered phase and at high fields in the saturated phase contrast sharply with a

Improving energy and carbon management in construction and civil engineering companies—evaluating the impacts of the CO2 Performance Ladder

NARCIS (Netherlands)

Rietbergen, Martijn G.; Opstelten, Ivo J.; Blok, Kornelis

In the Netherlands, the CO2 Performance Ladder has been introduced as an energy management programme to facilitate continuous energy efficiency and carbon performance improvement in non-industrial sectors. This paper addresses the question: ‘What is the impact of the CO2 Performance Ladder on

Thermally Reduced Graphene Oxide Electrochemically Activated by Bis-Spiro Quaternary Alkyl Ammonium for Capacitors.

Science.gov (United States)

He, Tieshi; Meng, Xiangling; Nie, Junping; Tong, Yujin; Cai, Kedi

2016-06-08

Thermally reduced graphene oxide (RGO) electrochemically activated by a quaternary alkyl ammonium-based organic electrolytes/activated carbon (AC) electrode asymmetric capacitor is proposed. The electrochemical activation process includes adsorption of anions into the pores of AC in the positive electrode and the interlayer intercalation of cations into RGO in the negative electrode under high potential (4.0 V). The EA process of RGO by quaternary alkyl ammonium was investigated by X-ray diffraction and electrochemical measurements, and the effects of cation size and structure were extensively evaluated. Intercalation by quaternary alkyl ammonium demonstrates a small degree of expansion of the whole crystal lattice (d002) and a large degree of expansion of the partial crystal lattice (d002) of RGO. RGO electrochemically activated by bis-spiro quaternary alkyl ammonium in propylene carbonate/AC asymmetric capacitor exhibits good activated efficiency, high specific capacity, and stable cyclability.

Efficiency snakes and energy ladders: A (meta-)frontier demand analysis of electricity consumption efficiency in Chinese households

International Nuclear Information System (INIS)

Broadstock, David C.; Li, Jiajia; Zhang, Dayong

2016-01-01

Policy makers presently lack access to quantified estimates – and hence an explicit understanding – of energy consumption efficiency within households, creating a potential gap between true efficiency levels and the necessarily assumed efficiency levels that policy makers adopt in designing and implementing energy policy. This paper attempts to fill this information gap by empirically quantifying electricity consumption efficiency for a sample of more than 7,000 households. Adopting the recently introduced ‘frontier demand function’ due to Filippini and Hunt (2011) but extending it into the metafrontier context – to control for structural heterogeneity arising from location type – it is shown that consumption efficiency is little more than 60% on average. This implies huge potential for energy reduction via the expansion of schemes to promote energy efficiency. City households, which are the wealthiest in the sample, are shown to define the metafrontier demand function (and hence have the potential to be the most efficient households), but at the same time exhibit the largest inefficiencies. These facts together allow for a potential refinement on the household energy ladder concept, suggesting that wealth affords access to the best technologies thereby increasing potential energy efficiency (the ‘traditional view of the household energy ladder), but complementary to this these same households are most inefficient. This has implications for numerous areas of policy, including for example the design of energy assistance schemes, identification of energy education needs/priorities as well more refined setting of subsidies/tax-credit policies. - Highlights: •Frontier demand functions are estimated for a sample of 7102 Chinese households. •Metafrontier methods capture heterogeneity arising from urban form (e.g. cities, towns and villages). •Wealthier houses have higher efficiency potential, but are in fact less efficient in their consumption of

Parents' Participation on School Councils Analysed through Arnstein's Ladder of Participation

Science.gov (United States)

Stelmach, Bonnie

2016-01-01

Although parent school councils are the archetypal arrangement for engaging parents in school improvement planning, their effectiveness is negligible when it comes to building parents' capacity for and confidence in educational decision-making. Using Arnstein's ladder of citizen participation, this qualitative case study investigated the nature…

Self-diffusion in monodisperse three-dimensional magnetic fluids by molecular dynamics simulations

Energy Technology Data Exchange (ETDEWEB)

Dobroserdova, A.B. [Ural Federal University, Lenin Av. 51, Ekaterinburg (Russian Federation); Kantorovich, S.S., E-mail: alla.dobroserdova@urfu.ru [Ural Federal University, Lenin Av. 51, Ekaterinburg (Russian Federation); University of Vienna, Sensengasse 8, Vienna (Austria)

2017-06-01

In the present work we study the self-diffusion behaviour in the three-dimensional monodisperse magnetic fluids using the Molecular Dynamics Simulation and Density Functional Theory. The peculiarity of computer simulation is to study two different systems: dipolar and soft sphere ones. In the theoretical method, it is important to choose the approximation for the main structures, which are chains. We compare the theoretical results and the computer simulation data for the self-diffusion coefficient as a function of the particle volume fraction and magnetic dipole-dipole interaction parameter and find the qualitative and quantitative agreement to be good. - Highlights: • The paper deals with the study of the self-diffusion in monodisperse three-dimensional magnetic fluids. • The theoretical approach contains the free energy density functional minimization. • Computer simulations are performed by the molecular dynamics method. • We have a good qualitative and quantitative agreement between the theoretical results and computer simulation data.

Analytical model and design of spoke-type permanent-magnet machines accounting for saturation and nonlinearity of magnetic bridges

Science.gov (United States)

Liang, Peixin; Chai, Feng; Bi, Yunlong; Pei, Yulong; Cheng, Shukang

2016-11-01

Based on subdomain model, this paper presents an analytical method for predicting the no-load magnetic field distribution, back-EMF and torque in general spoke-type motors with magnetic bridges. Taking into account the saturation and nonlinearity of magnetic material, the magnetic bridges are equivalent to fan-shaped saturation regions. For getting standard boundary conditions, a lumped parameter magnetic circuit model and iterative method are employed to calculate the permeability. The final field domain is divided into five types of simple subdomains. Based on the method of separation of variables, the analytical expression of each subdomain is derived. The analytical results of the magnetic field distribution, Back-EMF and torque are verified by finite element method, which confirms the validity of the proposed model for facilitating the motor design and optimization.

Spin ordering in three-leg ladders in Ludwigite systems

International Nuclear Information System (INIS)

Vallejo, E.; Avignon, M.

2007-01-01

We study the spin ordering in a three-leg ladder present in Ludwigite systems formed of localized spins interacting with an extra electron per rung. We also consider the competition with super exchange interactions resulting in a very rich phase diagram. Among the phases we find the possibility of ferromagnetic rungs ordered antiferromagnetically and a zigzag spin ordering linked to the formation of a charge ordering as observed

Evaluating the life cycle environmental impact of short span bridges

DEFF Research Database (Denmark)

Du, Guangli; Pettersson, Lars; Karoumi, Raid

2016-01-01

impact of the construction sector. Life cycle assessment (LCA) is a systematic method for assessing the environmental impact of products and systems, but its application in bridges is scarce. In Swede, most of the bridges are short spans and the type of concrete slab-frame bridge (CFB) accounts...... for a large share. Soil steel composite bridge (SSCB) is a functional equivalent solution for CFB. In order to mitigate the environmental burdens of short span bridges, this paper performed a comparative LCA study between these two types of bridge. The results indicate that the initial material consumption...

A comprehensive evaluation of potential lung function associated genes in the SpiroMeta general population sample.

Directory of Open Access Journals (Sweden)

Ma'en Obeidat

Full Text Available Lung function measures are heritable traits that predict population morbidity and mortality and are essential for the diagnosis of chronic obstructive pulmonary disease (COPD. Variations in many genes have been reported to affect these traits, but attempts at replication have provided conflicting results. Recently, we undertook a meta-analysis of Genome Wide Association Study (GWAS results for lung function measures in 20,288 individuals from the general population (the SpiroMeta consortium.To comprehensively analyse previously reported genetic associations with lung function measures, and to investigate whether single nucleotide polymorphisms (SNPs in these genomic regions are associated with lung function in a large population sample.We analysed association for SNPs tagging 130 genes and 48 intergenic regions (+/-10 kb, after conducting a systematic review of the literature in the PubMed database for genetic association studies reporting lung function associations.The analysis included 16,936 genotyped and imputed SNPs. No loci showed overall significant association for FEV(1 or FEV(1/FVC traits using a carefully defined significance threshold of 1.3×10(-5. The most significant loci associated with FEV(1 include SNPs tagging MACROD2 (P = 6.81×10(-5, CNTN5 (P = 4.37×10(-4, and TRPV4 (P = 1.58×10(-3. Among ever-smokers, SERPINA1 showed the most significant association with FEV(1 (P = 8.41×10(-5, followed by PDE4D (P = 1.22×10(-4. The strongest association with FEV(1/FVC ratio was observed with ABCC1 (P = 4.38×10(-4, and ESR1 (P = 5.42×10(-4 among ever-smokers.Polymorphisms spanning previously associated lung function genes did not show strong evidence for association with lung function measures in the SpiroMeta consortium population. Common SERPINA1 polymorphisms may affect FEV(1 among smokers in the general population.

Measurement of the Rise-Time in a Single Sided Ladder Detector

International Nuclear Information System (INIS)

Gerber, C.E.

1997-01-01

In this note we report on the measurement of the preamplifier output rise time for a SVXII chip mounted on a D0 single sided ladder. The measurements were performed on the ladder 001-883-L, using the laser test stand of Lab D. The rise time was measured for different values of the response (or bandwidth) of the preamplifier. As a bigger bandwidth results in longer rise times and therefore in less noise, the largest possible bandwidth consistent with the time between bunch crossings should be chosen to operate the detectors. The rise time is defined as the time elapsed between 10% and 90% of the charge is collected. It is also interesting to measure the time for full charge collection and the percentage of charge collected in 132 ns and 396 ns. The results are shown in table 1, for bandwidths between 2 and 63 (binary numbers). The uncertainty on the time measurement is considered to be ∼ 10 ns. Figure 1 schematically defines the four quantities measured: rise time, time of full charge collection, and percentage of charge collected in 132 ns and 396 ns. Figures 2 to 8 are the actual measurements for bandwidths of 2, 4, 8, 12, 24, 32 and 63. Figure 9 is a second measurement for BW=24, used as a consistency check of the system and the time measurement performed on the plots. The data indicate that the single sided ladders can be operated at BW=63 for 396 ns and BW=12 for 132 ns, achieving full charge collection. This will result in smaller noise than originally anticipated.

New types of time domain reflectometry sensing waveguides for bridge scour monitoring

Science.gov (United States)

Lin, Chih-Ping; Wang, Kai; Chung, Chih-Chung; Weng, Yu-Wen

2017-07-01

Scour is a major threat to bridge safety, especially in harsh fluvial environments. Real-time monitoring of bridge scour is still very limited due to the lack of robust and economic scour monitoring device. Time domain reflectometry (TDR) is an emerging waveguide-based technique holding great promise to develop more durable scour monitoring devices. This study presents new types of TDR sensing waveguides in forms of either sensing rod or sensing wire, taking into account of the measurement range, durability, and ease of field installation. The sensing rod is composed of a hollow grooved steel rod paired up with a metal strip on the insulating groove, while the sensing wire consists of two steel strands with one of them coated with an insulating jacket. The measurement sensitivity is inevitably sacrificed when other properties such as the measurement range, field durability, and installation easiness are enhanced. Factors affecting the measurement sensitivity were identified and experimentally evaluated for better arranging the waveguide conductors. A data reduction method for scour-depth estimation without the need for identifying the sediment/water reflection and a two-step calibration procedure for rating propagation velocities were proposed to work with the new types of TDR sensing waveguides. Both the calibration procedure and the data reduction method were experimentally validated. The test results indicated that the new TDR sensing waveguide provides accurate scour depth measurements regardless of the sacrificed sensitivity. The insulating coating of the new TDR sensing waveguide was also demonstrated to be effective in extending the measurement range up to at least 15 m.

Surface Acoustic Analog of Bloch Oscillations, Wannier-Stark Ladders and Landau-Zener Tunneling

Science.gov (United States)

de Lima, M. M.; Kosevich, Yu. A.; Santos, P. V.; Cantarero, A.

2011-12-01

In this contribution, we discuss the recent experimental demonstration of Wannier-Stark ladders, Bloch Oscillations and Landau Zener tunneling in a solid by means of surface acoustic waves propagating through perturbed grating structures.

Electric field induced localization phenomena in a ladder network with superlattice configuration: Effect of backbone environment

Energy Technology Data Exchange (ETDEWEB)

Dutta, Paramita; Karmakar, S. N. [Condensed Matter Physics Division, Saha Institute of Nuclear Physics, Sector-I, Block-AF, Bidhannagar, Kolkata-700 064 (India); Maiti, Santanu K., E-mail: santanu.maiti@isical.ac.in [Physics and Applied Mathematics Unit, Indian Statistical Institute, 203 Barrackpore Trunk Road, Kolkata-700 108 (India)

2014-09-15

Electric field induced localization properties of a tight-binding ladder network in presence of backbone sites are investigated. Based on Green's function formalism we numerically calculate two-terminal transport together with density of states for different arrangements of atomic sites in the ladder and its backbone. Our results lead to a possibility of getting multiple mobility edges which essentially plays a switching action between a completely opaque to fully or partly conducting region upon the variation of system Fermi energy, and thus, support in fabricating mesoscopic or DNA-based switching devices.

Using a familiar risk comparison within a risk ladder to improve risk understanding by low numerates: a study of visual attention.

Science.gov (United States)

Keller, Carmen

2011-07-01

Previous experimental research provides evidence that a familiar risk comparison within a risk ladder is understood by low- and high-numerate individuals. It especially helps low numerates to better evaluate risk. In the present study, an eye tracker was used to capture individuals' visual attention to a familiar risk comparison, such as the risk associated with smoking. Two parameters of information processing-efficiency and level-were derived from visual attention. A random sample of participants from the general population (N= 68) interpreted a given risk level with the help of the risk ladder. Numeracy was negatively correlated with overall visual attention on the risk ladder (r(s) =-0.28, p= 0.01), indicating that the lower the numeracy, the more the time spent looking at the whole risk ladder. Numeracy was positively correlated with the efficiency of processing relevant frequency (r(s) = 0.34, p improving risk communication formats. © 2011 Society for Risk Analysis.

Fabrication of monodisperse magnetic nanoparticles released in solution using a block copolymer template

Science.gov (United States)

Morcrette, Mélissa; Ortiz, Guillermo; Tallegas, Salomé; Joisten, Hélène; Tiron, Raluca; Baron, Thierry; Hou, Yanxia; Lequien, Stéphane; Bsiesy, Ahmad; Dieny, Bernard

2017-07-01

This paper describes a fabrication process of monodisperse magnetic nanoparticles released in solution, based on combined ‘top-down’ and ‘bottom-up’ approaches. The process involves the use of a self-assembled PS-PMMA block copolymer formed on a sacrificial layer. Such an approach was so far mostly explored for the preparation of patterned magnetic media for ultrahigh density magnetic storage. It is here extended to the preparation of released monodisperse nanoparticles for biomedical applications. A special sacrificial layer had to be developed compatible with the copolymer self-organization. The resulting nanoparticles exhibit very narrow size dispersion (≈7%) and can be good candidates as contrast agents for medical imaging i.e. magnetic resonance imaging or magnetic particle imaging. The approach provides a great freedom in the choice of the particles shapes and compositions. In particular, they can be made of biocompatible magnetic material.

Fabrication of monodisperse magnetic nanoparticles released in solution using a block copolymer template

International Nuclear Information System (INIS)

Morcrette, Mélissa; Ortiz, Guillermo; Joisten, Hélène; Dieny, Bernard; Tallegas, Salomé; Baron, Thierry; Bsiesy, Ahmad; Tiron, Raluca; Hou, Yanxia; Lequien, Stéphane

2017-01-01

This paper describes a fabrication process of monodisperse magnetic nanoparticles released in solution, based on combined ‘top-down’ and ‘bottom-up’ approaches. The process involves the use of a self-assembled PS-PMMA block copolymer formed on a sacrificial layer. Such an approach was so far mostly explored for the preparation of patterned magnetic media for ultrahigh density magnetic storage. It is here extended to the preparation of released monodisperse nanoparticles for biomedical applications. A special sacrificial layer had to be developed compatible with the copolymer self-organization. The resulting nanoparticles exhibit very narrow size dispersion (≈7%) and can be good candidates as contrast agents for medical imaging i.e. magnetic resonance imaging or magnetic particle imaging. The approach provides a great freedom in the choice of the particles shapes and compositions. In particular, they can be made of biocompatible magnetic material. (paper)

A Comparison of Limb-Socket Kinematics of Bone-Bridging and Non-Bone-Bridging Wartime Transtibial Amputations

Science.gov (United States)

2012-05-16

each successive loading interval. Subset analysis was performed on the basis of amputation type (bone bridging or non bone bridging) and suspension...fitting, patient care. Washington, DC: US Government Printing Office; 1969. 2. Ertl J. Uber amputationsstumpfe. Chirurg. 1949;20:218 24. 3. Pinto MA

Acute effects of Resistance exercise performed on ladder on energy metabolism, stress, and muscle damage in rats

Directory of Open Access Journals (Sweden)

João Guilherme Oliveira Silvestre

2017-05-01

Full Text Available Abstract AIMS To evaluate the acute effects of a resistance exercise session performed on ladder on energy metabolism, stress, and muscle damage in rats. METHODS Male Wistar rats were randomly distributed in Exercise (E (n=30 and Control (C (n = 20 groups. The E group performed a resistance exercise session on a vertical ladder with weights on their tails. Blood samples were collected at rest and after each climb to analyze lactate levels and ten minutes after the last climb to analyze lactate dehydrogenase (LDH, creatine kinase (CK, and corticosterone levels. RESULTS Blood lactate levels remained stable during exercise. Serum corticosterone, blood glucose, LDH and CK levels increased and glycogen content decreased in the E group, when compared to the C group. CONCLUSION These results suggest that resistance exercise performed on ladder is a model of high-intensity exercise. However, the stabilization of lactate during the session suggests that the aerobic metabolism is an important factor during the intervals between climbs.

SEISMIC BEHAVIOR OF STEEL MONORAIL BRIDGES UNDER TRAIN LOAD DURING STRONG EARTHQUAKES

OpenAIRE

KIM, C. W.; KAWATANI, M.; KANBARA, T.; NISHIMURA, N.

2013-01-01

This paper investigated dynamic responses of steel monorail bridges incorporating train-bridge interaction under strong earthquakes. Two types of steel monorail bridges were considered in the study: a conventional type with steel track-girder; an advanced type with composite track-girder and simplified lateral bracing system. During strong earthquakes, monorail train was assumed standing on the track-girder of monorail bridges. Observations through the analytical study showed that considering...

New regioselective multicomponent reaction: one pot synthesis of spiro heterobicyclic aliphatic rings.

Science.gov (United States)

Byk, G; Gottlieb, H E; Herscovici, J; Mirkin, F

2000-01-01

In the context of our high-throughput organic synthesis program, we have studied the reactivity of special beta-keto esters toward the Biginelli reaction. We have found that a cyclic beta-keto ester reacts with one molecule of urea and two molecules of aldehyde to give a new family of spiro heterobicyclic aliphatic rings in good yields. Interestingly, the Biginelli product was not detected. After analysis of products using HPLC, 1H NMR, and 13C NMR, we have found that the reaction is driven by a regio-specific condensation of two molecules of aldehyde with the other reagents to afford only products harboring substituents exclusively in cis configuration. Monte Carlo minimization studies using MM2 force field suggest that cis products are energetically more stable than the trans counterparts. Together with previously reported data, these results suggest that the trans products were not obtained as result of steric hindrance produced by the equatorial position of one of the ring substituents. This new reaction is useful for high-throughput organic synthesis. Indeed, the new scaffold can be used to introduce additional groups in the molecules through remaining functional groups by a "domino strategy".

Ground-state and spectral properties of an asymmetric Hubbard ladder

Science.gov (United States)

Abdelwahab, Anas; Jeckelmann, Eric; Hohenadler, Martin

2015-04-01

We investigate a ladder system with two inequivalent legs, namely, a Hubbard chain and a one-dimensional electron gas. Analytical approximations, the density-matrix renormalization group method, and continuous-time quantum Monte Carlo simulations are used to determine ground-state properties, gaps, and spectral functions of this system at half-filling. Evidence for the existence of four different phases as a function of the Hubbard interaction and the rung hopping is presented. First, a Luttinger liquid exists at very weak interchain hopping. Second, a Kondo-Mott insulator with spin and charge gaps induced by an effective rung exchange coupling is found at moderate interchain hopping or strong Hubbard interaction. Third, a spin-gapped paramagnetic Mott insulator with incommensurate excitations and pairing of doped charges is observed at intermediate values of the rung hopping and the interaction. Fourth, the usual correlated band insulator is recovered for large rung hopping. We show that the wave numbers of the lowest single-particle excitations are different in each insulating phase. In particular, the three gapped phases exhibit markedly different spectral functions. We discuss the relevance of asymmetric two-leg ladder systems as models for atomic wires deposited on a substrate.

Nutrigenetics: bridging two worlds to understand type 2 diabetes.

Science.gov (United States)

Harrington, Janas M; Phillips, Catherine M

2014-04-01

The increasing global prevalence of type 2 diabetes mellitus (T2DM) is a major public health concern. Accumulating data provides strong evidence of the shared contribution of genetic and environmental factors to T2DM risk. Genome-wide association studies have hugely improved our understanding of the genetic basis of T2DM. However, it is obvious that genetics only partly account for an individuals' predisposition to T2DM. The dietary environment has changed remarkably over the last century. Examination of individual macronutrients and more recently of foods and dietary patterns is becoming increasingly important in terms of developing public health strategies. Nutrigenetics offers the potential to improve diet-related disease prevention and therapy, but is not without its own challenges. In this review we present evidence on the dietary environment and genetics as risk factors for T2DM and bridging the 2 disciplines we highlight some key gene-nutrient interactions.

Preparation of monodisperse curcumin-imprinted polymer by precipitation polymerization and its application for the extraction of curcuminoids from Curcuma longa L.

Science.gov (United States)

Kitabatake, Tomoko; Tabo, Hiromi; Matsunaga, Hisami; Haginaka, Jun

2013-08-01

A monodisperse molecularly imprinted polymer (MIP) for curcumin was first prepared by precipitation polymerization using methacrylamide (MAM) and 4-vinylpyridine as functional co-monomers, divinylbenzene as a crosslinker, and a mixture of acetonitrile and toluene as a porogen. The use of MAM as the co-monomer resulted in the formation of a monodisperse MIP and non-imprinted polymer (NIP). MIP and NIP, respectively, were monodispersed with a narrow particle size distribution (3.3 ± 0.09 and 3.5 ± 0.10 μm). In addition to shape recognition, hydrophobic and hydrogen-bonding interactions affected the retention and molecular-recognition of curcumin on the MIP. The MIP for curcumin could extract curcuminoids (curcumin, demethoxycurcumin, and bisdemethoxycurcumin) in Curcuma longa L.

Exciting test of a floating type cable stayed bridge and its response observation under the typhoon; Furotiingu keishiki shachokyo (Utagenkabashi) no kishinki shiken to taifuji oto kansoku

Energy Technology Data Exchange (ETDEWEB)

Uno, K. [Kyushu Kyoritsu Univ., Kitakyushu (Japan). Faculty of Engineering; Aso, T. [Yamaguchi Univ., Ube (Japan). Faculty of Engineering; Kitagawa, S. [Kyushu International Univ., Kitakyushu (Japan). Faculty of Economy; Kabashima, S.

1995-09-20

Recently, in case of the planning and designing of bridges, of course its practicality and execution stability are considered, but consideration for landscape also is a large problem. In particular, the selection of the bridge type is very important in order to protect the beautiful natural landscape. The cable stayed bridge has become to be executed often, owing to its elegant style, however, it becomes important theme clarify the antiseismic and wind stability because of its complicated structure system and very slender girder. In this paper, the results of the dynamic characteristics of a floating type cable stayed bridge (length 292.1 m and width 14.9 m) and the observation of its dynamic behavior under the typhoon are reported. Microtremor measurement was performed to determine the dynamic characteristics of the bridge under construction. After the construction of the bridge, the excitation test was carried out in order to confirm its natural frequencies, vibration modes and damping constants. From the results of the observation of the dynamic behavior of the girder and cables under the typhoon, the wind stability of this bridge was confirmed. 10 refs., 13 figs., 9 tabs.

Analytical model and design of spoke-type permanent-magnet machines accounting for saturation and nonlinearity of magnetic bridges

Energy Technology Data Exchange (ETDEWEB)

Liang, Peixin; Chai, Feng [State Key Laboratory of Robotics and System, Harbin Institute of Technology, Harbin 150001 (China); Department of Electrical Engineering, Harbin Institute of Technology, Harbin 150001 (China); Bi, Yunlong [Department of Electrical Engineering, Harbin Institute of Technology, Harbin 150001 (China); Pei, Yulong, E-mail: peiyulong1@163.com [Department of Electrical Engineering, Harbin Institute of Technology, Harbin 150001 (China); Cheng, Shukang [State Key Laboratory of Robotics and System, Harbin Institute of Technology, Harbin 150001 (China); Department of Electrical Engineering, Harbin Institute of Technology, Harbin 150001 (China)

2016-11-01

Based on subdomain model, this paper presents an analytical method for predicting the no-load magnetic field distribution, back-EMF and torque in general spoke-type motors with magnetic bridges. Taking into account the saturation and nonlinearity of magnetic material, the magnetic bridges are equivalent to fan-shaped saturation regions. For getting standard boundary conditions, a lumped parameter magnetic circuit model and iterative method are employed to calculate the permeability. The final field domain is divided into five types of simple subdomains. Based on the method of separation of variables, the analytical expression of each subdomain is derived. The analytical results of the magnetic field distribution, Back-EMF and torque are verified by finite element method, which confirms the validity of the proposed model for facilitating the motor design and optimization. - Highlights: • The no-load magnetic field of poke-type motors is firstly calculated by analytical method. • The magnetic circuit model and iterative method are employed to calculate the permeability. • The analytical expression of each subdomain is derived.. • The proposed method can effectively reduce the predesign stages duration.

Analytical model and design of spoke-type permanent-magnet machines accounting for saturation and nonlinearity of magnetic bridges

International Nuclear Information System (INIS)

Liang, Peixin; Chai, Feng; Bi, Yunlong; Pei, Yulong; Cheng, Shukang

2016-01-01

Based on subdomain model, this paper presents an analytical method for predicting the no-load magnetic field distribution, back-EMF and torque in general spoke-type motors with magnetic bridges. Taking into account the saturation and nonlinearity of magnetic material, the magnetic bridges are equivalent to fan-shaped saturation regions. For getting standard boundary conditions, a lumped parameter magnetic circuit model and iterative method are employed to calculate the permeability. The final field domain is divided into five types of simple subdomains. Based on the method of separation of variables, the analytical expression of each subdomain is derived. The analytical results of the magnetic field distribution, Back-EMF and torque are verified by finite element method, which confirms the validity of the proposed model for facilitating the motor design and optimization. - Highlights: • The no-load magnetic field of poke-type motors is firstly calculated by analytical method. • The magnetic circuit model and iterative method are employed to calculate the permeability. • The analytical expression of each subdomain is derived.. • The proposed method can effectively reduce the predesign stages duration.

Frustrated quantum magnetism in the Kondo lattice on the zigzag ladder

Science.gov (United States)

Peschke, Matthias; Rausch, Roman; Potthoff, Michael

2018-03-01

The interplay between the Kondo effect, indirect magnetic interaction, and geometrical frustration is studied in the Kondo lattice on the one-dimensional zigzag ladder. Using the density-matrix renormalization group, the ground-state and various short- and long-range spin- and density-correlation functions are calculated for the model at half filling as a function of the antiferromagnetic Kondo interaction down to J =0.3 t , where t is the nearest-neighbor hopping on the zigzag ladder. Geometrical frustration is shown to lead to at least two critical points: Starting from the strong-J limit, where almost local Kondo screening dominates and where the system is a nonmagnetic Kondo insulator, antiferromagnetic correlations between nearest-neighbor and next-nearest-neighbor local spins become stronger and stronger, until at Jcdim≈0.89 t frustration is alleviated by a spontaneous breaking of translational symmetry and a corresponding transition to a dimerized state. This is characterized by antiferromagnetic correlations along the legs and by alternating antiferro- and ferromagnetic correlations on the rungs of the ladder. A mechanism of partial Kondo screening that has been suggested for the Kondo lattice on the two-dimensional triangular lattice is not realized in the one-dimensional case. Furthermore, within the symmetry-broken dimerized state, there is a magnetic transition to a 90∘ quantum spin spiral with quasi-long-range order at Jcmag≈0.84 t . The quantum-critical point is characterized by a closure of the spin gap (with decreasing J ) and a divergence of the spin-correlation length and of the spin-structure factor S (q ) at wave vector q =π /2 . This is opposed to the model on the one-dimensional bipartite chain, which is known to have a finite spin gap for all J >0 at half filling.

A Demonstration of Helping Adolescents with Mild Intellectual Disability Climb Ladders

Science.gov (United States)

Chan, Kok Hoe Anthony; Varahan, Jayashree Lakshmi; Loh, Peng Loong Daniel; Tan, Sey Ing

2011-01-01

A research team at a vocational school in Singapore, catering mainly to students between the ages of 17-21 with mild intellectual disability, studied how to best address the challenge of enabling students to learn how to climb ladders (a skill necessary at many job placements). They documented the approach used and suggested extrapolations and…

Topic Order in Introductory Physics and its Impact on the STEM Curricular Ladder

Directory of Open Access Journals (Sweden)

Teresa L Larkin

2017-02-01

Full Text Available Introductory physics courses are an important rung on the curricular ladder in STEM. These courses help to strengthen students critical thinking and problem solving skills while simultaneously introducing them to many topics they will explore in more detail in later courses in physics and engineering. For these reasons, introductory physics is a required element on the curricular ladder. Most often, introductory physics is offered as a two-semester sequence with basic mechanics being taught in the first semester and electricity and magnetism in the second. In fact, this curricular sequence has not been altered in decades. Is there a reason for this? There are many other enduring questions that arise pertaining to these foundation courses in physics. These questions include: Does taking the introductory course sequence “out of order” have an impact on student learning in physics? What topics should be taught? When should these topics be taught? What topics could be left out? The list of questions is essentially endless. This paper will address some of these questions in part, through a brief discussion on student learning in a second-semester algebra-based physics course. Connections will also be made to the broader curricular ladder in STEM. To this end, an illustration that makes connections to an engineering statics course will be presented. This discussion will conclude by presenting some broader implications for the larger STEM communities.

29 CFR 1910.29 - Manually propelled mobile ladder stands and scaffolds (towers).

Science.gov (United States)

2010-07-01

... HEALTH ADMINISTRATION, DEPARTMENT OF LABOR OCCUPATIONAL SAFETY AND HEALTH STANDARDS Walking-Working... edges, burrs or other safety hazards. (3) Work levels. (i) The maximum work level height shall not... rigid platforms at each work level. (iv) The steps of ladder stands shall be fabricated from slip...

Design of monodisperse and well-defined polypeptide-based polyvalent inhibitors of anthrax toxin.

Science.gov (United States)

Patke, Sanket; Boggara, Mohan; Maheshwari, Ronak; Srivastava, Sunit K; Arha, Manish; Douaisi, Marc; Martin, Jacob T; Harvey, Ian B; Brier, Matthew; Rosen, Tania; Mogridge, Jeremy; Kane, Ravi S

2014-07-28

The design of polyvalent molecules, presenting multiple copies of a specific ligand, represents a promising strategy to inhibit pathogens and toxins. The ability to control independently the valency and the spacing between ligands would be valuable for elucidating structure-activity relationships and for designing potent polyvalent molecules. To that end, we designed monodisperse polypeptide-based polyvalent inhibitors of anthrax toxin in which multiple copies of an inhibitory toxin-binding peptide were separated by flexible peptide linkers. By tuning the valency and linker length, we designed polyvalent inhibitors that were over four orders of magnitude more potent than the corresponding monovalent ligands. This strategy for the rational design of monodisperse polyvalent molecules may not only be broadly applicable for the inhibition of toxins and pathogens, but also for controlling the nanoscale organization of cellular receptors to regulate signaling and the fate of stem cells. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Long-term behavior of integral abutment bridges : [technical summary].

Science.gov (United States)

2011-01-01

Integral abutment bridges, a type of jointless bridge, are the construction option of choice when designing highway bridges in many parts of the country. Rather than providing an expansion joint to separate the substructure from the superstructure to...

A novel type of peptidoglycan-binding domain highly specific for amidated D-Asp cross-bridge, identified in Lactobacillus casei bacteriophage endolysins.

Science.gov (United States)

Regulski, Krzysztof; Courtin, Pascal; Kulakauskas, Saulius; Chapot-Chartier, Marie-Pierre

2013-07-12

Peptidoglycan hydrolases (PGHs) are responsible for bacterial cell lysis. Most PGHs have a modular structure comprising a catalytic domain and a cell wall-binding domain (CWBD). PGHs of bacteriophage origin, called endolysins, are involved in bacterial lysis at the end of the infection cycle. We have characterized two endolysins, Lc-Lys and Lc-Lys-2, identified in prophages present in the genome of Lactobacillus casei BL23. These two enzymes have different catalytic domains but similar putative C-terminal CWBDs. By analyzing purified peptidoglycan (PG) degradation products, we showed that Lc-Lys is an N-acetylmuramoyl-L-alanine amidase, whereas Lc-Lys-2 is a γ-D-glutamyl-L-lysyl endopeptidase. Remarkably, both lysins were able to lyse only Gram-positive bacterial strains that possess PG with D-Ala(4)→D-Asx-L-Lys(3) in their cross-bridge, such as Lactococcus casei, Lactococcus lactis, and Enterococcus faecium. By testing a panel of L. lactis cell wall mutants, we observed that Lc-Lys and Lc-Lys-2 were not able to lyse mutants with a modified PG cross-bridge, constituting D-Ala(4)→L-Ala-(L-Ala/L-Ser)-L-Lys(3); moreover, they do not lyse the L. lactis mutant containing only the nonamidated D-Asp cross-bridge, i.e. D-Ala(4)→D-Asp-L-Lys(3). In contrast, Lc-Lys could lyse the ampicillin-resistant E. faecium mutant with 3→3 L-Lys(3)-D-Asn-L-Lys(3) bridges replacing the wild-type 4→3 D-Ala(4)-D-Asn-L-Lys(3) bridges. We showed that the C-terminal CWBD of Lc-Lys binds PG containing mainly D-Asn but not PG with only the nonamidated D-Asp-containing cross-bridge, indicating that the CWBD confers to Lc-Lys its narrow specificity. In conclusion, the CWBD characterized in this study is a novel type of PG-binding domain targeting specifically the D-Asn interpeptide bridge of PG.

Clarifying the Hubble constant tension with a Bayesian hierarchical model of the local distance ladder

Science.gov (United States)

Feeney, Stephen M.; Mortlock, Daniel J.; Dalmasso, Niccolò

2018-05-01

Estimates of the Hubble constant, H0, from the local distance ladder and from the cosmic microwave background (CMB) are discrepant at the ˜3σ level, indicating a potential issue with the standard Λ cold dark matter (ΛCDM) cosmology. A probabilistic (i.e. Bayesian) interpretation of this tension requires a model comparison calculation, which in turn depends strongly on the tails of the H0 likelihoods. Evaluating the tails of the local H0 likelihood requires the use of non-Gaussian distributions to faithfully represent anchor likelihoods and outliers, and simultaneous fitting of the complete distance-ladder data set to ensure correct uncertainty propagation. We have hence developed a Bayesian hierarchical model of the full distance ladder that does not rely on Gaussian distributions and allows outliers to be modelled without arbitrary data cuts. Marginalizing over the full ˜3000-parameter joint posterior distribution, we find H0 = (72.72 ± 1.67) km s-1 Mpc-1 when applied to the outlier-cleaned Riess et al. data, and (73.15 ± 1.78) km s-1 Mpc-1 with supernova outliers reintroduced (the pre-cut Cepheid data set is not available). Using our precise evaluation of the tails of the H0 likelihood, we apply Bayesian model comparison to assess the evidence for deviation from ΛCDM given the distance-ladder and CMB data. The odds against ΛCDM are at worst ˜10:1 when considering the Planck 2015 XIII data, regardless of outlier treatment, considerably less dramatic than naïvely implied by the 2.8σ discrepancy. These odds become ˜60:1 when an approximation to the more-discrepant Planck Intermediate XLVI likelihood is included.

Long-term voice handicap index after type II thyroplasty using titanium bridges for adductor spasmodic dysphonia.

Science.gov (United States)

Sanuki, Tetsuji; Yumoto, Eiji; Kodama, Narihiro; Minoda, Ryosei; Kumai, Yoshihiko

2014-06-01

To determine the long-term functional outcomes of type II thyroplasty using titanium bridges for adductor spasmodic dysphonia (AdSD) by perceptual analysis using the Voice Handicap Index-10 (VHI-10) and by acoustic analysis. Fifteen patients with AdSD underwent type II thyroplasty using titanium brides between August 2006 and February 2011. VHI-10 scores, a patient-based survey that quantifies a patient's perception of his or her vocal handicap, were determined before and at least 2 years after surgery. Concurrent with the VHI-10 evaluation, acoustic parameters were assessed, including jitter, shimmer, harmonic-to-noise ratio (HNR), standard deviation of F0 (SDF0), and degree of voice breaks (DVB). The average follow-up interval was 30.1 months. No patient had strangulation of the voice, and all were satisfied with the voice postoperatively. In the perceptual analysis, the mean VHI-10 score improved significantly, from 26.7 to 4.1 two years after surgery. All patients had significantly improved each score of three different aspects of VHI-10, representing improved functional, physical, and emotional well-being. All acoustic parameters improved significantly 2 years after surgery. The treatment of AdSD with type II thyroplasty significantly improved the voice-related quality of life and acoustic parameters 2 years after surgery. The results of the study suggest that type II thyroplasty using titanium bridges provides long-term relief of vocal symptoms in patients with AdSD. Copyright © 2013 Elsevier Ireland Ltd. All rights reserved.

Tris(2-(1 H -pyrazol-1-yl)pyridine)cobalt(III) as p-Type Dopant for Organic Semiconductors and Its Application in Highly Efficient Solid-State Dye-Sensitized Solar Cells

KAUST Repository

Burschka, Julian

2011-11-16

Chemical doping is an important strategy to alter the charge-transport properties of both molecular and polymeric organic semiconductors that find widespread application in organic electronic devices. We report on the use of a new class of Co(III) complexes as p-type dopants for triarylamine-based hole conductors such as spiro-MeOTAD and their application in solid-state dye-sensitized solar cells (ssDSCs). We show that the proposed compounds fulfill the requirements for this application and that the discussed strategy is promising for tuning the conductivity of spiro-MeOTAD in ssDSCs, without having to rely on the commonly employed photo-doping. By using a recently developed high molar extinction coefficient organic D-π-A sensitizer and p-doped spiro-MeOTAD as hole conductor, we achieved a record power conversion efficiency of 7.2%, measured under standard solar conditions (AM1.5G, 100 mW cm -2). We expect these promising new dopants to find widespread applications in organic electronics in general and photovoltaics in particular. © 2011 American Chemical Society.

Hydrophilic segmented block copolymers based on poly(ethylene oxide) and monodisperse amide segments

NARCIS (Netherlands)

Husken, D.; Feijen, Jan; Gaymans, R.J.

2007-01-01

Segmented block copolymers based on poly(ethylene oxide) (PEO) flexible segments and monodisperse crystallizable bisester tetra-amide segments were made via a polycondensation reaction. The molecular weight of the PEO segments varied from 600 to 4600 g/mol and a bisester tetra-amide segment (T6T6T)

Microwave Josephson generation in thin film superconducting bridges

International Nuclear Information System (INIS)

Gubankov, V.N.; Koshelets, V.P.; Ovsyannikov, G.A.

1975-01-01

Thin-film bridges have some advantage over other types of superconducting weak links: good definition of electromagnetic parameters and of weak region geometry. Up to now Josephson properties of bridges have been investigated by using indirect methods (the effect of magnetic field on the critical current I 0 , the bridge behavior in a microwave field, etc.). Direct experimental observation of Josephson radiation from autonomous thin film bridges is reported. Microwave radiation in tin bridges of 'variable' thickness has been investigated where the thickness of the film forming the bridge is far less than the thickness of the bank films. (Auth.)

Electron spin resonance modes in a strong-leg ladder in the Tomonaga-Luttinger liquid phase

Science.gov (United States)

Ozerov, M.; Maksymenko, M.; Wosnitza, J.; Honecker, A.; Landee, C. P.; Turnbull, M. M.; Furuya, S. C.; Giamarchi, T.; Zvyagin, S. A.

2015-12-01

Magnetic excitations in the strong-leg quantum spin ladder compound (C7H10N) 2CuBr4 (known as DIMPY) in the field-induced Tomonaga-Luttinger spin-liquid phase are studied by means of high-field electron spin resonance (ESR) spectroscopy. The presence of a gapped ESR mode with unusual nonlinear frequency-field dependence is revealed experimentally. Using a combination of analytic and exact-diagonalization methods, we compute the dynamical structure factor and identify this mode with longitudinal excitations in the antisymmetric channel. We argue that these excitations constitute a fingerprint of the spin dynamics in a strong-leg spin-1/2 Heisenberg antiferromagnetic ladder and owe their ESR observability to the uniform Dzyaloshinskii-Moriya interaction.

Resin-Bonded Bridges in vitro and in vivo

NARCIS (Netherlands)

Veen, Johannes Hilbrandt van der

1988-01-01

In this thesis in vitro and in vivo studies on the clinical application of resin-bonded bridges are described and discussed. The development of different types of resin-bonded bridges is described in chapter 1. The bridges are often made by boding a cast metal retainer fitted with and artificial

[Ladder step strategy for surgical repair of congenital concealed penis in children].

Science.gov (United States)

Wang, Fu-Ran; Zhong, Hong-Ji; Chen, Yi; Zhao, Jun-Feng; Li, Yan

2016-11-01

To assess the feasibility of the ladder step strategy in surgical repair of congenital concealed penis in children. This study included 52 children with congenital concealed penis treated in the past two years by surgical repair using the ladder step strategy, which consists of five main steps: cutting the narrow ring of the foreskin, degloving the penile skin, fixing the penile skin at the base, covering the penile shaft, and reshaping the prepuce. The perioperative data of the patients were prospectively collected and statistically described. Of the 52 patients, 20 needed remodeling of the frenulum and 27 received longitudinal incision in the penoscrotal junction to expose and deglove the penile shaft. The advanced scrotal flap technique was applied in 8 children to cover the penile shaft without tension, the pedicled foreskin flap technique employed in 11 to repair the penile skin defect, and excision of the webbed skin of the ventral penis performed in another 44 to remodel the penoscrotal angle. The operation time, blood loss, and postoperative hospital stay were 40－100 minutes, 5－30 ml, and 3－6 days, respectively. Wound bleeding and infection occurred in 1 and 5 cases, respectively. Follow-up examinations at 3 and 6 months after surgery showed that all the children had a satisfactory penile appearance except for some minor complications (2 cases of penile retraction, 2 cases of redundant ventral skin, and 1 case of iatrogenic penile curvature). The ladder step strategy for surgical repair of congenital concealed penis in children is a simple procedure with minor injury and satisfactory appearance of the penis.

Hydroxyl-substituted ladder polyethers via selective tandem epoxidation/cyclization sequence.

Science.gov (United States)

Czabaniuk, Lara C; Jamison, Timothy F

2015-02-20

A new and highly selective method for the synthesis of hydroxyl-substituted tetrahydropyrans is described. This method utilizes titanium(IV) isopropoxide and diethyl tartrate to perform a diastereoselective epoxidation followed by in situ epoxide activation and highly selective endo-cyclization to form the desired tetrahydropyran ring. The HIJ ring fragment of the marine ladder polyether yessotoxin was synthesized using this two-stage tactic that proceeds with high efficiency and excellent regioselectivity.

Prestressed concrete cable-stayed bridge; PC shachokyo `Tajiri sky bridge` no seko

Energy Technology Data Exchange (ETDEWEB)

Kaida, Y.; Tsujino, F. [Osaka Prefectural Government Office, Osaka (Japan); Yamamoto, T.; Hishiki, Y.; Saito, K.

1995-01-30

The outline on the execution of PC cable-stayed bridge `Tajiri Sky Bridge` which was built at the opposite coast of Kansai International Airport was reported. This bridge is a double-sided suspension PC cable-stayed bridge with a tower height of 93.6 m having a main beam which is 26.3 m wide, featuring H-type main tower with one side beam, a smooth main beam structure, the leg top part with a large section, etc. A large-capacity factory manufacturing type non-grout cable with a pull strength of 1,900 ton class was adopted for the diagonal bracing. The leg top part is in a massive concrete structure so that, for avoiding the crack of cement due to temperature, a low heat build-up furnace cement was adopted, the water reducing agent was used, pre-cooling and side-clamping PC steel material were adopted and moderate pre-stress was introduced. In the execution of the connection part of the main beam, for preventing the deflection fluctuation due to the change of the main beam/main tower/diagonal bracing due to temperature and vibration due to wind, the earth anchor was used to tentatively fix the extended part. During execution, the wind velocity was strong reaching 25 m/s, which did not produce any problems. 1 ref., 24 figs., 3 tabs.

Monodisperse microbeads of hypercrosslinked polystyrene for liquid and supercritical fluid chromatography

Science.gov (United States)

Tsyurupa, M. P.; Blinnikova, Z. K.; Il'in, M. M.; Davankov, V. A.; Parenago, O. O.; Pokrovskii, O. I.; Usovich, O. I.

2015-11-01

Monodisperse styrene-divinylbenzene (1 wt %) copolymer microbeads are obtained via the elaborate method of high-productivity precipitation polymerization. The crosslinking of this copolymer with chloromethyl methyl ether in the presence of Friedel-Crafts catalyst yields porous hypercrosslinked polymers with degrees of crosslinking that range from 200 to 500%. Microbead sorbents are shown to be suited for selective stationary phases for high-performance liquid chromatography and supercritical fluid chromatography.

Indirect effects of impoundment on migrating fish: temperature gradients in fish ladders slow dam passage by adult Chinook salmon and steelhead.

Directory of Open Access Journals (Sweden)

Christopher C Caudill

Full Text Available Thermal layering in reservoirs upstream from hydroelectric dams can create temperature gradients in fishways used by upstream migrating adults. In the Snake River, Washington, federally-protected adult salmonids (Oncorhynchus spp. often encounter relatively cool water in dam tailraces and lower ladder sections and warmer water in the upstream portions of ladders. Using radiotelemetry, we examined relationships between fish passage behavior and the temperature difference between the top and bottom of ladders (∆T at four dams over four years. Some spring Chinook salmon (O. tshawytscha experienced ∆T ≥ 0.5 °C. Many summer and fall Chinook salmon and summer steelhead (O. mykiss experienced ∆T ≥ 1.0 °C, and some individuals encountered ΔT > 4.0°C. As ΔT increased, migrants were consistently more likely to move down fish ladders and exit into dam tailraces, resulting in upstream passage delays that ranged from hours to days. Fish body temperatures equilibrated to ladder temperatures and often exceeded 20°C, indicating potential negative physiological and fitness effects. Collectively, the results suggest that gradients in fishway water temperatures present a migration obstacle to many anadromous migrants. Unfavorable temperature gradients may be common at reservoir-fed fish passage facilities, especially those with seasonal thermal layering or stratification. Understanding and managing thermal heterogeneity at such sites may be important for ensuring efficient upstream passage and minimizing stress for migratory, temperature-sensitive species.

Assembly of Fe3O4 nanoparticles on SiO2 monodisperse spheres

Indian Academy of Sciences (India)

Assembly of Fe3O4 nanoparticles on SiO2 monodisperse spheres. K C BARICK and D BAHADUR*. Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay,. Mumbai 400 076, India. Abstract. The assembly of superparamagnetic Fe3O4 nanoparticles on submicroscopic SiO2 ...

Measuring subjective meaning structures by the laddering method: Theoretical considerations and methodological problems

DEFF Research Database (Denmark)

Grunert, Klaus G.; Grunert, Suzanne C.

1995-01-01

Starting from a general model of measuring cognitive structures for predicting consumer behaviour, we discuss laddering as a possible method to obtain estimates of consumption-relevant cognitive structures which will have predictive validity. Four criteria for valid measurement are derived and ap...

Bound states in weakly disordered spin ladders

Energy Technology Data Exchange (ETDEWEB)

Arlego, M. [Departamento de Fisica, Universidad Nacional de La Plata, CC 67 (1900) La Plata (Argentina)]. E-mail: arlego@venus.fisica.unlp.edu.ar; Brenig, W. [Institut fuer Theoretische Physik, Technische Universitaet Braunschweig (Germany); Cabra, D.C. [Laboratoire de Physique Theorique, Universite Louis Pasteur Strasbourg (France); Heidrich-Meisner, F. [Institut fuer Theoretische Physik, Technische Universitaet Braunschweig (Germany); Honecker, A. [Institut fuer Theoretische Physik, Technische Universitaet Braunschweig (Germany); Rossini, G. [Departamento de Fisica, Universidad Nacional de La Plata, CC 67 (1900) La Plata (Argentina)

2005-04-30

We study the appearance of bound states in the spin gap of spin-12 ladders induced by weak bond disorder. Starting from the strong-coupling limit, i.e., the limit of weakly coupled dimers, we perform a projection on the single-triplet subspace and derive the position of bound states for the single impurity problem of one modified coupling as well as for small impurity clusters. The case of a finite concentration of impurities is treated with the coherent-potential approximation (CPA) in the strong-coupling limit and compared with numerical results. Further, we analyze the details in the structure of the density of states and relate their origin to the influence of impurity clusters.

Magnetic phase diagram of a frustrated spin ladder

Science.gov (United States)

Sugimoto, Takanori; Mori, Michiyasu; Tohyama, Takami; Maekawa, Sadamichi

2018-04-01

Frustrated spin ladders show magnetization plateaux depending on the rung-exchange interaction and frustration defined by the ratio of first and second neighbor exchange interactions in each chain. This paper reports on its magnetic phase diagram. Using the variational matrix-product state method, we accurately determine phase boundaries. Several kinds of magnetization plateaux are induced by the frustration and the strong correlation among quasiparticles on a lattice. The appropriate description of quasiparticles and their relevant interactions are changed by a magnetic field. We find that the frustration differentiates the triplet quasiparticle from the singlet one in kinetic energy.

Synthesis and characterization of monodispersed silver nanoparticles

Science.gov (United States)

Jegatha Christy, A.; Umadevi, M.

2012-09-01

Synthesis of silver nanoparticles (NPs) has become a fascinating and important field of applied chemical research. In this paper silver NPs were prepared using silver nitrate (AgNO3), gelatin, and cetyl trimethyl ammonium bromide (CTAB). The prepared silver NPs were exposed under the laser ablation. In our photochemical procedure, gelatin acts as a biopolymer and CTAB acts as a reducing agent. The appearance of surface plasmon band around 410 nm indicates the formation of silver NPs. The nature of the prepared silver NPs in the face-centered cubic (fcc) structure are confirmed by the peaks in the x-ray diffraction (XRD) pattern corresponding to (111), (200), (220) and (311) planes. Monodispersed, stable, spherical silver NPs with diameter about 10 nm were obtained and confirmed by high-resolution transmission electron microscope (HRTEM).

Synthesis and characterization of monodispersed silver nanoparticles

International Nuclear Information System (INIS)

Christy, A Jegatha; Umadevi, M

2012-01-01

Synthesis of silver nanoparticles (NPs) has become a fascinating and important field of applied chemical research. In this paper silver NPs were prepared using silver nitrate (AgNO 3 ), gelatin, and cetyl trimethyl ammonium bromide (CTAB). The prepared silver NPs were exposed under the laser ablation. In our photochemical procedure, gelatin acts as a biopolymer and CTAB acts as a reducing agent. The appearance of surface plasmon band around 410 nm indicates the formation of silver NPs. The nature of the prepared silver NPs in the face-centered cubic (fcc) structure are confirmed by the peaks in the x-ray diffraction (XRD) pattern corresponding to (111), (200), (220) and (311) planes. Monodispersed, stable, spherical silver NPs with diameter about 10 nm were obtained and confirmed by high-resolution transmission electron microscope (HRTEM). (paper)

Optimum Maintenance Strategies for Highway Bridges

DEFF Research Database (Denmark)

Frangopol, Dan M.; Thoft-Christensen, Palle; Das, Parag C.

As bridges become older and maintenance costs become higher, transportation agencies are facing challenges related to implementation of optimal bridge management programs based on life cycle cost considerations. A reliability-based approach is necessary to find optimal solutions based on minimum...... expected life-cycle costs or maximum life-cycle benefits. This is because many maintenance activities can be associated with significant costs, but their effects on bridge safety can be minor. In this paper, the program of an investigation on optimum maintenance strategies for different bridge types...... is described. The end result of this investigation will be a general reliability-based framework to be used by the UK Highways Agency in order to plan optimal strategies for the maintenance of its bridge network so as to optimize whole-life costs....

Relationship between Antimalarial Activity and Heme Alkylation for Spiro- and Dispiro-1,2,4-Trioxolane Antimalarials▿

Science.gov (United States)

Creek, Darren J.; Charman, William N.; Chiu, Francis C. K.; Prankerd, Richard J.; Dong, Yuxiang; Vennerstrom, Jonathan L.; Charman, Susan A.

2008-01-01

The reaction of spiro- and dispiro-1,2,4-trioxolane antimalarials with heme has been investigated to provide further insight into the mechanism of action for this important class of antimalarials. A series of trioxolanes with various antimalarial potencies was found to be unreactive in the presence of Fe(III) hemin, but all were rapidly degraded by reduced Fe(II) heme. The major reaction product from the heme-mediated degradation of biologically active trioxolanes was an alkylated heme adduct resulting from addition of a radical intermediate. Under standardized reaction conditions, a correlation (R2 = 0.88) was found between the extent of heme alkylation and in vitro antimalarial activity, suggesting that heme alkylation may be related to the mechanism of action for these trioxolanes. Significantly less heme alkylation was observed for the clinically utilized artemisinin derivatives compared to the equipotent trioxolanes included in this study. PMID:18268087

Aqueous dispersion of monodisperse magnetic iron oxide nanocrystals through phase transfer

International Nuclear Information System (INIS)

Yu, William W; Chang, Emmanuel; Sayes, Christie M; Drezek, Rebekah; Colvin, Vicki L

2006-01-01

A facile method was developed for completely transferring high quality monodisperse iron oxide nanocrystals from organic solvents to water. The as-prepared aqueous dispersions of iron oxide nanocrystals were extremely stable and could be functionalized for bioconjugation with biomolecules. These iron oxide nanocrystals showed negligible cytotoxicity to human breast cancer cells (SK-BR-3) and human dermal fibroblast cells. This method is general and versatile for many organic solvent-synthesized nanoparticles, including fluorescent semiconductor nanocrystals

Quark-gluon vertex dressing and meson masses beyond ladder-rainbow truncation

International Nuclear Information System (INIS)

Matevosyan, Hrayr H.; Thomas, Anthony W.; Tandy, Peter C.

2007-01-01

We include a generalized infinite class of quark-gluon vertex dressing diagrams in a study of how dynamics beyond the ladder-rainbow truncation influences the Bethe-Salpeter description of light-quark pseudoscalar and vector mesons. The diagrammatic specification of the vertex is mapped into a corresponding specification of the Bethe-Salpeter kernel, which preserves chiral symmetry. This study adopts the algebraic format afforded by the simple interaction kernel used in previous work on this topic. The new feature of the present work is that in every diagram summed for the vertex and the corresponding Bethe-Salpeter kernel, each quark-gluon vertex is required to be the self-consistent vertex solution. We also adopt from previous work the effective accounting for the role of the explicitly non-Abelian three-gluon coupling in a global manner through one parameter determined from recent lattice-QCD data for the vertex. Within the current model, the more consistent dressed vertex limits the ladder-rainbow truncation error for vector mesons to be never more than 10% as the current quark mass is varied from the u/d region to the b region

Tri-block copolymers with mono-disperse crystallizable diamide segments: synthesis, analysis and rheological properties

NARCIS (Netherlands)

Araichimani, A.; Gaymans, R.J.

2008-01-01

Tri-block copolymers with polyether mid-segments and mono-disperse amide end segments were synthesized, analyzed and some properties studied. The end segment was an aromatic diamide (diaramide, TΦB). The polyether mid-segment was a difunctional poly(tetramethylene oxide) (PTMO, 1000 and 2900 g/mol).

Production of monodisperse respirable aerosols of 241AmO2 and evaluation of in vitro dissolution

International Nuclear Information System (INIS)

Boyd, H.A.; Raabe, O.G.; Peterson, P.K.

1974-01-01

A method is described for production of monodisperse (sigma//sub g/ less than 1.2) particles of 241 AmO 2 for use in inhalation experiments with dogs and rodents. The effects of physical and chemical factors on the production of polydisperse aerosols of 241 AmO 2 were studied and evaluated. The best aerosol was achieved when a suspension of americium hydroxide with 2.5 mg Am/ml at pH = 7.3 was aerosolized and passed through two heating columns in succession, the first at 300 0 C and the second at 1050 0 C. The particles were roughly spherical and had densities near 8 gm/cm 3 ; the aerosol AMAD and sigma/sub g/ were about 1.5 μm and 1.7, respectively. Monodisperse particles were separated and collected with the Lovelace Aerosol Particle Separator (LAPS) and subsequently suspended in deionized water with pH adjusted to 10.2 with NH 3 for nebulization to produce monodisperse aerosols for inhalation exposures. Particles collected on filters during inhalation experiments were used for evaluation of in vitro dissolution rates with two systems and various forms of a lung fluid simulant. The important role of phosphate ions in such dissolution systems was demonstrated, suggesting the potential for the equally important role of free phosphate in retarding dissolution of AmO 2 particles in the lung. (U.S.)

Lock and Key Colloids through Polymerization-Induced Buckling of Monodispersed Silicon Oil Droplets

Science.gov (United States)

Sacanna, Stefano; Irvine, William T. M.; Chaikin, Paul M.; Pine, David J.

2010-03-01

Colloidal particles can spontaneously associate into larger structured aggregates when driven by selective and directional interactions. Colloidal organization can be programmed by engineering shapes and interactions of basic building blocks in a manner similar to molecular self-assembly. Examples of successful strategies that allow non-trivial assembly of particles include template-directed patterning, capillary forces and, most commonly, the functionalization of the particle surfaces with ``sticky patches'' of biological or synthetic molecules. The level of complexity of the realizable assemblies, increases when particles with well defined shape anisotropies are used. In particular depletion forces and specific surface treatments in combination with non spherical particles have proven to be powerful tools to self-assembly complex microstructures. We describe a simple, high yield, synthetic pathway to fabricate monodisperse hybrid silica spheres with well defined cavities. Because the particle morphologies are reproducible and tunable with precision, the resulting particles can be used as basic building blocks in the assembly of larger monodisperse clusters. This is demonstrated using depletion to drive the self-assembly.

Non-local electron transport through normal and topological ladder-like atomic systems

Science.gov (United States)

Kurzyna, Marcin; Kwapiński, Tomasz

2018-05-01

We propose a locally protected ladder-like atomic system (nanoconductor) on a substrate that is insensitive to external perturbations. The system corresponds to coupled atomic chains fabricated on different surfaces. Electron transport properties of such conductors are studied theoretically using the model tight-binding Su-Schriffer-Hegger (SSH) Hamiltonian and Green's function formalism. We have found that the conductance of the system is almost insensitive to single adatoms and oscillates as a function of the side chain length with very large periods. Non-local character of the electron transport was observed also for topological SSH chains where nontrivial end states survive in the presence of disturbances as well as for different substrates. We have found that the careful inspection of the density of states or charge waves can provide the information about the atom energy levels and hopping amplitudes. Moreover, the ladder-like geometry allows one to distinguish between normal and topological zero-energy states. It is important that topological chains do not reveal Friedel oscillations which are observed in non-topological chains.

Telecast of Astronauts Armstrong and Aldrin by the Lunar Module ladder

Science.gov (United States)

1969-01-01

Astronauts Neil A. Armstrong (on left), commander; and Edwin E. Aldrin Jr., lunar module pilot, are seen standing by the Lunar Module ladder in this black and white reproduction taken from a telecast by the Apollo 11 lunar surface television camera during the Apollo 11 extravehicular activity. This picture was made from a televised image received at the Deep Space Network tracking station at Goldstone, California.

Facile Synthesis of Monodispersed Polysulfide Spheres for Building Structural Colors with High Color Visibility and Broad Viewing Angle.

Science.gov (United States)

Li, Feihu; Tang, Bingtao; Wu, Suli; Zhang, Shufen

2017-01-01

The synthesis and assembly of monodispersed colloidal spheres are currently the subject of extensive investigation to fabricate artificial structural color materials. However, artificial structural colors from general colloidal crystals still suffer from the low color visibility and strong viewing angle dependence which seriously hinder their practical application in paints, colorimetric sensors, and color displays. Herein, monodispersed polysulfide (PSF) spheres with intrinsic high refractive index (as high as 1.858) and light-absorbing characteristics are designed, synthesized through a facile polycondensation and crosslinking process between sodium disulfide and 1,2,3-trichloropropane. Owing to their high monodispersity, sufficient surface charge, and good dispersion stability, the PSF spheres can be assembled into large-scale and high-quality 3D photonic crystals. More importantly, high structural color visibility and broad viewing angle are easily achieved because the unique features of PSF can remarkably enhance the relative reflectivity and eliminate the disturbance of scattering and background light. The results of this study provide a simple and efficient strategy to create structural colors with high color visibility, which is very important for their practical application. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

ESR modes in a Strong-Leg Ladder in the Tomonaga-Luttinger Liquid Phase

Science.gov (United States)

Zvyagin, S.; Ozerov, M.; Maksymenko, M.; Wosnitza, J.; Honecker, A.; Landee, C. P.; Turnbull, M.; Furuya, S. C.; Giamarchi, T.

Magnetic excitations in the strong-leg quantum spin ladder compound (C7H10N)2CuBr4 (known as DIMPY) in the field-induced Tomonaga-Luttinger spin liquid phase are studied by means of high-field electron spin resonance (ESR) spectroscopy. The presence of a gapped ESR mode with unusual non-linear frequency-field dependence is revealed experimentally. Using a combination of analytic and exact diagonalization methods, we compute the dynamical structure factor and identify this mode with longitudinal excitations in the antisymmetric channel. We argue that these excitations constitute a fingerprint of the spin dynamics in a strong-leg spin-1/2 Heisenberg antiferromagnetic ladder and owe its ESR observability to the uniform Dzyaloshinskii-Moriya interaction. This work was partially supported by the DFG and Helmholtz Gemeinschaft (Germany), Swiss SNF under Division II, and ERC synergy UQUAM project. We acknowledge the support of the HLD at HZDR, member of the European Magnetic Field Laboratory (EMFL).

Strength monitoring of bridge constructions and features of its application. Part 2. Continuous monitoring of bridge construction status

Directory of Open Access Journals (Sweden)

Ovchinnikov Igor Georgievich

2014-06-01

Full Text Available The article describes a system of continuous monitoring of bridge constructions — a system of observation over the operating conditions and behavior of the bridge structure, which is aimed at ensuring the preservation of its functional application properties within the specified limits, realized on the continuous, long-term basis with the use of instrumentation and ensures on-line presentation of information on the status of structure. To illustrate, one may consider the existing systems of continuous monitoring for a number of bridge constructions in the United States, Japan, Europe, South Korea, Greece and Russia. The article suggests to examine the systems of continuous monitoring of «Commodore John Barry» truss bridge, «Akashi-Kaikyo» suspension bridge, «Siggenthal» reinforced-concrete arch bridge, «Nimhe» suspension bridge, «Jindo»cable-stayed bridge, «Yandzhon» suspension bridge, «Banghwa» bridge, «Seohae» bridge and «Rio-Antirrio» bridge. In addition one may consider monitoring of the longitudinal launching of the bridge superstructures over the Volga River near the village Pristannoye in Saratov region. Finally, it was drawn the conclusion that monitoring of bridge constructions from the standpoint of their consumers is aimed at solving such important problems as preservation of bridge structures, increase in service life of bridge structures through timely detection of faults and their elimination, as well as preservation of bridge structure carrying capacity by controlling their behavior during the operation and improving the efficiency of expenditure of monetary resources for repair activities by correct determination of time and type of the necessary repair.

Bridge and steel structures. History and vision on bridge erection; Kyoryo kokozobutsu. Kasetsu gijutsu no shorai

Energy Technology Data Exchange (ETDEWEB)

Mukai, S.; Hayashi, T. [Sumitomo Heavy Industries, Ltd., Tokyo (Japan)

1998-08-20

This paper describes the progress of bridge erection technology. It introduces the results of cable erection, rotated/extruded erection, and cantilever erection. The cable erection is a multi point suspension erection using cables. For the rotated/extruded erection, the monolithic construction is conducted on a working yard set in a right angle to the construction position, and the horizontal beams of the bridge piers (corbel girders) are constructed by the rotated method using a slewing base incorporated around the bridge piers at one side. For the construction of stiffening girders of Innoshima-ohashi Bridge of Honshu-Shikoku Joint Bridge in 1978, trussed face bar blocks were extruded from the main tower in order using a travel crane. For the suspension bridges and cable stayed bridges, main towers were erected using various types of cranes. The erection of Tamashima-ohashi Bridge with a weight of 500 ton using an offshore floating crane is introduced as a large block method. Analysis methods and measurement techniques at the site are used in order to analyze the shape in each step under the erection and to ensure the accurate final complete shape. Reduction of the construction cost, improvement of erection technology, and technology development for large-scale projects are subjects in the future. 22 refs., 8 figs., 1 tab.

On the effect of nuclear bridge modes on donor-acceptor electronic coupling in donor-bridge-acceptor molecules

International Nuclear Information System (INIS)

Davis, Daly; Toroker, Maytal Caspary; Speiser, Shammai; Peskin, Uri

2009-01-01

We report a theoretical study of intra-molecular electronic coupling in a symmetric DBA (donor-bridge-acceptor) complex, in which a donor electronic site is coupled to an acceptor site by way of intervening orbitals of a molecular bridge unit. In the off-resonant (deep tunneling) regime of electronic transport, the lowest unoccupied molecular orbitals (MO's) of the DBA system are split into distinguishable donor/acceptor and bridge orbitals. The effect of geometrical changes at the bridge on the donor/acceptor electronic energy manifold is studied for local stretching and bending modes. It is demonstrated that the energy splitting in the manifold of donor/acceptor unoccupied MOs changes in response to such changes, as assumed in simple McConnell-type models. Limitations of the simple models are revealed where the electronic charging of the bridge orbitals correlates with increasing donor/acceptor orbital energy splitting only for stretching but not for bending bridge modes.

Two-loop ladder diagram contributions to Bhabha scattering. III

International Nuclear Information System (INIS)

Bjoerkevoll, K.S.; Osland, P.; Faeldt, G.

1992-01-01

The authors evaluate, in the high-energy limit, the sum of the Feynman amplitudes corresponding the six two-loop ladder-like diagrams in Bhabha scattering. This is the limit where s→∞, while t, the electron mass m and the photon mass λ are all being held fixed. In this limit the sum of the six Feynman amplitudes does not depend on the electron mass. When specialized to the region s>>t>>m 2 >>λ 2 , this result complements the one previously obtained. The connection with Φ 3 theory is also investigated. 6 refs

Ising versus S U (2) 2 string-net ladder

Science.gov (United States)

Vidal, Julien

2018-03-01

We consider the string-net model obtained from S U (2) 2 fusion rules. These fusion rules are shared by two different sets of anyon theories. In this paper, we study the competition between the two corresponding non-Abelian quantum phases in the ladder geometry. A detailed symmetry analysis shows that the nontrivial low-energy sector corresponds to the transverse-field cluster model that displays a critical point described by the s o (2) 1 conformal field theory. Other sectors are obtained by freezing spins in this model.

Application of bridging-law concepts to short-fibre composites

DEFF Research Database (Denmark)

Lindhagen, J.E.; Gamstedt, Kristofer; Berglund, L.A.

2000-01-01

This is the third paper in a series of four where notch sensitivity, fracture energy and bridging laws are studied in short-fibre polymer composites. Here, bridging laws are derived from experimental crack-opening profiles in centre-hole notched tensile specimens. The materials studied are three...... types of commercial glass-mat composites with different reinforcement structures and matrices. The materials have softening bridging laws and the calculated fracture energies from bridging laws are in good agreement with values determined directly by experiment. The calculated maximum local bridging...

Synthesis of Monodisperse CdSe QDs using Controlled Growth Temperatures

International Nuclear Information System (INIS)

Noor Razinah Rahmat; Akrajas Ali Umar; Muhammad Yahya; Muhamad Mat Salleh; Mohammad Hafizuddin Jumali

2011-01-01

The effect of growth temperatures on size of CdSe quantum dots (QDs) has been investigated. CdSe QDs were synthesized using thermolysis of organometallics precursor route using wet chemical method. The growth temperature was varied from 260-310 degree Celsius with growth period fixed at 60 s. As the growth temperature increased, the monodispersed CdSe QDs with diameter in the range 3-7 nm were obtained. Both absorption and PL spectra of the QDs revealed a strong red-shift supporting the increment size of QDs with the rise of growth temperature. (author)

47 CFR 80.1007 - Bridge-to-bridge radiotelephone installation.

Science.gov (United States)

2010-10-01

... 47 Telecommunication 5 2010-10-01 2010-10-01 false Bridge-to-bridge radiotelephone installation. 80.1007 Section 80.1007 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) SAFETY AND... Bridge-to-Bridge Act § 80.1007 Bridge-to-bridge radiotelephone installation. Use of the bridge-to-bridge...

Advanced materials for control of post-earthquake damage in bridges

International Nuclear Information System (INIS)

Shrestha, Kshitij C; Saiidi, M Saiid; Cruz, Carlos A

2015-01-01

This paper presents analytical modeling to study the seismic response of bridge systems with conventional and advanced details. For validation, a 33 m quarter-scale model of a four-span bridge incorporating innovative materials and details seismically tested on the shake tables at the University of Nevada, Reno was taken. The bridge specimen involved use of advanced materials and details to reduce damage at plastic hinges and minimize residual displacements. A three-dimensional, nonlinear model incorporating the response of the innovative materials was developed to study the bridge response using the finite-element software OpenSees. Existing finite-element formulations were used to capture the response of the advanced materials used in the bridge. The analytical model was found to be able to reproduce comparable bent displacements and bent shear forces within reasonable accuracy. The validated model was further used to study different types of bridges under suite of scaled bi-directional near-fault ground motions. Comparisons were made on behavior of five different bridge types, first conventional reinforced concrete bridge, second post-tensioned column bridge, third bridge with elastomeric rubber elements at the plastic hinge zone, fourth bridge with nickel–titanium superelastic shape memory alloy (SMA) reinforcing bar and fifth bridge with CuAlMn superelastic SMA reinforcing bar. Both the SMA used bridges also utilized engineered cementitious composite element at the plastic hinge zone. The results showed effectiveness of the innovative interventions on the bridges in providing excellent recentering capabilities with minimal damage to the columns. (paper)

New conceptual design of portable bamboo bridge for emergency purposes

Science.gov (United States)

Musthaffa, A. A.; Nor, N. M.; Yusof, M. A.; Yuhazri, M. Y.

2018-02-01

Portable bridges serve as routes for troops during the military operations and the disaster relief operation. Nowadays, bamboo has been regarded as one of the alternative construction materials for building and bridge structures. This paper presents the conceptual design of the portable bridge. Several types of portable bridges and bamboo bridges are reviewed in the current work. The characteristics, capability and method of construction of each bridge are discussed. Finally, the conceptual of the portable bamboo bridge for emergency purposes is presented. The idea of producing portable bridge is proposed in the current work as it is crucial for providing route for communities affected by natural disasters.

Control of Porosity in Ladder Polymers by Solvent-induced Aggregation

Science.gov (United States)

Brady, Michael; Gamo, Eri; Wang, Cheng; Xia, Yan

Porous polymers hold promise as materials for gas absorption, membranes, and organic electronics. In all of these applications, attaining in-plane ordering of backbones and thus porous free volume impacts the ability to adsorb gas, selectively filter molecules, and conduct charges. In this work, hard and soft x-ray scattering and soft x-ray spectroscopy are of focus to study the pore structure, induced by the solution-driven aggregation of ladder polymer thin films made of LP-1 and LP-2. Using GISAXS and AFM it is shown that thermal annealing drives the growth of crystallites in thin films. Due to the completely sp2nature of the ladder polymer backbones, it is expected that backbones are extremely stiff and thus preventing them from packing once left in a metastable state following casting. Therefore, the combination of GIWAXS and GISAXS will be shown to be critical in correctly understanding how pores develop in this 700 m2/g sorbent (N2). Finally, application in CO2/N2 separation membranes towards carbon sequestration will be presented that show gas selectivity is achieved through heteroatom incorporation and polymer blending. In this talk, focus will be placed on state-of-the-art x-ray scattering and spectroscopy, highlighting the importance of chemically sensitive structural information enabled by the combination of spectroscopy and scattering at play with the use of resonant soft x-rays.

In-site synthesis of monodisperse, oleylamine-capped Ag nanoparticles through microemulsion approach

Science.gov (United States)

Chen, Shun; Ju, Yanyun; Guo, Yi; Xiong, Chuanxi; Dong, Lijie

2017-03-01

Ag NPs were in-site synthesized through microemulsion method by reducing silver acetate with oleylamine-mediated at 70 °C with highly monodisperse and narrow size from 10 to 20 nm. The synthesis of Ag NPs was aided by oleylamine and the role of oleylamine was researched. This in-site synthesis approach to Ag NPs was reproducibility and high yield more than 80% with stable store about 6 months.

Magnetic properties of the two-leg zig-zag ladder in quantum spin system NH4CuCl3

International Nuclear Information System (INIS)

Raksa, Teguh Yoga; Kurniawan, Budhy

2002-01-01

Numerical analysis of the two-leg zig-zag ladder as a single chain with next-nearest neighbour interactions has been formulated by Cabra (1999) with the following Hamiltonian. Other formulation for two leg zig-zag ladder with dimerized chains and coupling between the chains. From these formulations, we study the closing of the gap at zero magnetization by means of the fine-tuning mechanism and disappearance of the 1/2 plateau (gap) at finite by alternating dimerization of the chains along the rungs. We also described NH 4 CuCI 3 under high magnetic fields in a two-leg system

Laser ablation synthesis of monodispersed magnetic alloy nanoparticles

International Nuclear Information System (INIS)

Seto, Takafumi; Koga, Kenji; Akinaga, Hiroyuki; Takano, Fumiyoshi; Orii, Takaaki; Hirasawa, Makoto

2006-01-01

Monodispersed CoPt alloy nanoparticles were synthesized by a pulsed laser ablation (PLA) technique coupled with a low-pressure operating differential mobility analyzer (LP-DMA). The CoPt alloy nanoparticles were generated by laser ablating a solid Co-Pt target. In CoPt alloy nanoparticles synthesized from a target with a Co composition of 75 at%, the nanoparticle surfaces were covered by an oxide layer and exhibited a core-shell structure. In contrast, no shell was observed in particles generated from a target with a Co:Pt ratio of 50:50 at%. According to an EDX analysis, the compositions of the individual nanoparticles were almost the same as that of the target material. Finally, the magnetic hysteresis loops of the CoPt alloy nanoparticles exhibited ferromagnetism

Laser ablation synthesis of monodispersed magnetic alloy nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Seto, Takafumi, E-mail: t.seto@aist.go.jp; Koga, Kenji; Akinaga, Hiroyuki; Takano, Fumiyoshi; Orii, Takaaki; Hirasawa, Makoto [National Institute of Advanced Industrial Science and Technology (AIST), Research Consortium for Synthetic Nano-Function Materials Project (SYNAF) (Japan)

2006-08-15

Monodispersed CoPt alloy nanoparticles were synthesized by a pulsed laser ablation (PLA) technique coupled with a low-pressure operating differential mobility analyzer (LP-DMA). The CoPt alloy nanoparticles were generated by laser ablating a solid Co-Pt target. In CoPt alloy nanoparticles synthesized from a target with a Co composition of 75 at%, the nanoparticle surfaces were covered by an oxide layer and exhibited a core-shell structure. In contrast, no shell was observed in particles generated from a target with a Co:Pt ratio of 50:50 at%. According to an EDX analysis, the compositions of the individual nanoparticles were almost the same as that of the target material. Finally, the magnetic hysteresis loops of the CoPt alloy nanoparticles exhibited ferromagnetism.

Salt bridges: geometrically specific, designable interactions.

Science.gov (United States)

Donald, Jason E; Kulp, Daniel W; DeGrado, William F

2011-03-01

Salt bridges occur frequently in proteins, providing conformational specificity and contributing to molecular recognition and catalysis. We present a comprehensive analysis of these interactions in protein structures by surveying a large database of protein structures. Salt bridges between Asp or Glu and His, Arg, or Lys display extremely well-defined geometric preferences. Several previously observed preferences are confirmed, and others that were previously unrecognized are discovered. Salt bridges are explored for their preferences for different separations in sequence and in space, geometric preferences within proteins and at protein-protein interfaces, co-operativity in networked salt bridges, inclusion within metal-binding sites, preference for acidic electrons, apparent conformational side chain entropy reduction on formation, and degree of burial. Salt bridges occur far more frequently between residues at close than distant sequence separations, but, at close distances, there remain strong preferences for salt bridges at specific separations. Specific types of complex salt bridges, involving three or more members, are also discovered. As we observe a strong relationship between the propensity to form a salt bridge and the placement of salt-bridging residues in protein sequences, we discuss the role that salt bridges might play in kinetically influencing protein folding and thermodynamically stabilizing the native conformation. We also develop a quantitative method to select appropriate crystal structure resolution and B-factor cutoffs. Detailed knowledge of these geometric and sequence dependences should aid de novo design and prediction algorithms. Copyright © 2010 Wiley-Liss, Inc.

THE EFFECT OF PLAYING SNAKE AND LADDER TOWARD THE RESULT STUDY OF ARITHMETIC ADDITION FOR STUDENT WITH MENTALLY RETARDED STUDENT

Directory of Open Access Journals (Sweden)

Arianti Iman Sari

2016-12-01

Full Text Available The purpose of this research were to describe: (1 the study result of arithmetic addition operation for fourth grade student with mentally retarded in SDLB before playing the Snake and Ladder activity (2 the study result of arithmetic addition operation for fourth grade student with mentally retarded in SDLB after playing the Snake and Ladder activity (3 the effect of Snake and Ladder playing toward the result study of arithmetic addition for fourth grade student with mentally retarded SDLB. This research used SSR (Single Subject Research with A-B-A design. Collecting the data was done by using assessment instrument, tests and observations. The result of this research showed that playing Snake and Ladder affected the study result of arithmetic addition operation for fourth-grade children with mentally retarded student in SDLB. Tujuan penelitian ini adalah mendeskripsikan (1 Hasil belajar penjumlahan siswa kelas 4 SDLB sebelum melakukan kegiatan bermain Ular Tangga (2 Hasil belajar penjumlahan siswa kelas 4 SDLB sesudah melakukan kegiatan bermain Ular Tangga (3 Pengaruh bermain Ular Tangga terhadap hasil belajar penjumlahan siswa kelas 4 SDLB. Penelitian ini menggunakan rancangan penelitian SSR (Single Subject Research dengan desain A-B-A. Pengumpulan data menggunakan instrumen assesmen, tes dan observasi. Hasil penelitian menunjukkan bermain ular tangga berpengaruh terhadap hasil belajar penjumlahan siswa tunagrahita kelas 4 SDLB.

Comparative DNA isolation behaviours of silica and polymer based sorbents in batch fashion: monodisperse silica microspheres with bimodal pore size distribution as a new sorbent for DNA isolation.

Science.gov (United States)

Günal, Gülçin; Kip, Çiğdem; Eda Öğüt, S; İlhan, Hasan; Kibar, Güneş; Tuncel, Ali

2018-02-01

Monodisperse silica microspheres with bimodal pore-size distribution were proposed as a high performance sorbent for DNA isolation in batch fashion under equilibrium conditions. The proposed sorbent including both macroporous and mesoporous compartments was synthesized 5.1 μm in-size, by a "staged shape templated hydrolysis and condensation method". Hydrophilic polymer based sorbents were also obtained in the form of monodisperse-macroporous microspheres ca 5.5 μm in size, with different functionalities, by a developed "multi-stage microsuspension copolymerization" technique. The batch DNA isolation performance of proposed material was comparatively investigated using polymer based sorbents with similar morphologies. Among all sorbents tried, the best DNA isolation performance was achieved with the monodisperse silica microspheres with bimodal pore size distribution. The collocation of interconnected mesoporous and macroporous compartments within the monodisperse silica microspheres provided a high surface area and reduced the intraparticular mass transfer resistance and made easier both the adsorption and desorption of DNA. Among the polymer based sorbents, higher DNA isolation yields were achieved with the monodisperse-macroporous polymer microspheres carrying trimethoxysilyl and quaternary ammonium functionalities. However, batch DNA isolation performances of polymer based sorbents were significantly lower with respect to the silica microspheres.

Study on load test of 100m cross-reinforced deck type concrete box arch bridge

Science.gov (United States)

Shi, Jing Xian; Cheng, Ying Jie

2018-06-01

Found in the routine quality inspection of highway bridge that many vertical fractures on the main beam (10mT beam) of the steel reinforced concrete arch bridge near the hydropower station. In order to grasp the bearing capacity of this bridge under working conditions with cracks, the static load and dynamic load test of box arch bridge are carried out. The Midas civil theory is calculated by using the special plate trailer - 300 as the calculation load, and the deflection and stress of the critical section are tested by the equivalent cloth load in the test vehicle. The pulsation test, obstacles and no obstacle driving test were carried out. Experimental results show that the bridge under the condition of the test loads is in safe condition, main bearing component of the strength and stiffness meet the design requirements, the crack width does not increase, in the process of loading bridge overall work performance is good.

4-bit digital to analog converter using R-2R ladder and binary weighted resistors

Science.gov (United States)

Diosanto, J.; Batac, M. L.; Pereda, K. J.; Caldo, R.

2017-06-01

The use of a 4-bit digital-to-analog converter using two methods; Binary Weighted Resistors and R-2R Ladder is designed and presented in this paper. The main components that were used in constructing both circuits were different resistor values, operational amplifier (LM741) and single pole double throw switches. Both circuits were designed using MULTISIM software to be able to test the circuit for its ideal application and FRITZING software for the layout designing and fabrication to the printed circuit board. The implementation of both systems in an actual circuit benefits in determining and comparing the advantages and disadvantages of each. It was realized that the binary weighted circuit is more efficient DAC, having lower percentage error of 0.267% compared to R-2R ladder circuit which has a minimum of percentage error of 4.16%.

New type of metal targets

International Nuclear Information System (INIS)

Bukharov, A.V.; Ankudinov, V.B.; Ogorodnikov, V.P.; Marukhin, Y.A.

2014-01-01

Now the technologies based on interaction of high-intensity beams with substance of a target are being intensively developed. As a target it is possible to use the new type of monodisperse metal targets. The principal advantages of new targets type are: target cooling isn't required; there is no induced activity: the target can be used many times; small dispersion on the speed, the size and interaction points with a beam. The basis of a target is the jet of molten metal, following in the vacuum chamber .Under the influence of the special disturbance superimposed on the liquid jet, the jet disintegrated into identical drops. In the vacuum chamber the drops freeze and form into the solid granules. It is possible to receive monodisperse targets from different metals, alloys and salts (diameter of targets is from 30 .m to 1.5 mm). Dispersion by the sizes and speed is less than 1%. The technique allows to receive not only continuous targets, but also hollow targets with dispersion on thickness of wall within 1...2%.

Damage Identification for Prestressed Adjacent Box-Beam Bridges

Directory of Open Access Journals (Sweden)

Kenneth K. Walsh

2014-01-01

Full Text Available Structural health monitoring (SHM has gained considerable attention as a tool for monitoring the health of civil infrastructure. For bridge infrastructure, previous methods have focused on the detection of localized damage through modal parameters extracted from the longitudinal direction of the structure. This paper investigates a new damage detection method based on the change in the first vertical mode extracted from the transverse direction of the bridge. The mode is determined through application of modal curve fitting to frequency response functions (FRFs that are formed using vertical response data obtained in the direction perpendicular to the bridge’s longitudinal axis. Using this method, both local damage and global damage in the bridge reveal themselves as having a localized effect on the bridge response. Furthermore, damage is revealed in such a way that it enables differentiation of the damage types. To demonstrate the effectiveness of the method, modal parameters were extracted from acceleration data obtained from a finite element model of a full bridge. Analysis of the modal parameters showed that the proposed approach could not only detect both local and global bridge damage, but could also differentiate between damage types using only one mode shape. The proposed method was compared to a previously developed SHM method.

In-site synthesis of monodisperse, oleylamine-capped Ag nanoparticles through microemulsion approach

Energy Technology Data Exchange (ETDEWEB)

Chen, Shun; Ju, Yanyun [Wuhan University of Technology, School of Materials Science and Engineering (China); Guo, Yi [Wuhan University of Technology, Center for Materials Research and Analysis (China); Xiong, Chuanxi; Dong, Lijie, E-mail: dong@whut.edu.cn [Wuhan University of Technology, School of Materials Science and Engineering (China)

2017-03-15

Ag NPs were in-site synthesized through microemulsion method by reducing silver acetate with oleylamine-mediated at 70 °C with highly monodisperse and narrow size from 10 to 20 nm. The synthesis of Ag NPs was aided by oleylamine and the role of oleylamine was researched. This in-site synthesis approach to Ag NPs was reproducibility and high yield more than 80% with stable store about 6 months.

Precast Pearl-Chain concrete arch bridges

DEFF Research Database (Denmark)

Halding, Philip Skov; Hertz, Kristian Dahl; Schmidt, Jacob Wittrup

2015-01-01

A Pearl-Chain Bridge is a closed-spandrel arch bridge consisting of a number of straight pre-fabricated so called Super-Light Deck elements put together in an arch shape by post-tensioning cables. Several Pearl-Chain arches can be positioned adjacent to each other by a crane to achieve a bridge...... of a desired width. On top of the arch is a filling material to level out the surface of the above road. The filling only transfers vertical loads to the arch. The geometry and material properties of Super-Light Decks are presented, and we refer to several fullscale tests of Pearl-Chain arches where...... the technology was used. We also study other important components and details in the Pearl-Chain Bridge concept and review the effects of different types of loads. A theoretical case study of a circular 30 m span Pearl-Chain Bridge is presented showing the influence of a number of parameters: The number of post...

Bridge joint fabrication and validation for SST-1 PF coil winding pack

International Nuclear Information System (INIS)

Prasad, Upendra; Sharma, A.N.; Patel, D.; Doshi, K.; Varmora, P.; Khristi, Y.; Pradhan, S.

2014-01-01

Highlights: • Prototype of bridge type joints fabricated and validated successfully. • Bridge type joints fabricated and validated on one of the SST-1 PF#3T coil successfully. • Joint resistance was measured with precision nano volt meter and PXI based data acquisition system. • Leak tightness of joint box was better than 3 × 10 −6 Pa m 3 s −1 . • The measured joint resistance of bridge type joint was ∼1.6 nano ohm. - Abstract: A novel concept of bridge joint for Poloidal field (PF) magnet of SST-1 with damaged winding pack has been realized. This joint has been fabricated on 5th and 6th layers of PF#3T coil winding pack (WP) after validation at 10 kA at liquid helium temperature of 4.2 K in current lead test chamber. The joint resistance of bridge joint was measured ∼1.6 nΩ at flat top DC current of 10 kA. This type of joint could be economically useful for revival of a shorted and damaged WP superconducting PF magnets of Tokamaks. In this paper, details of bridge joint design, fabrication and validations are discussed

An alternative route towards monodisperse CdS quantum dots for hybrid solar cells

International Nuclear Information System (INIS)

Cao, Fengfeng; Wang, Hao; Xia, Zhouhui; Dai, Xiao; Cong, Shan; Dong, Chao; Sun, Baoquan; Lou, Yanhui; Sun, Yinghui; Zhao, Jie; Zou, Guifu

2015-01-01

Monodisperse CdS quantum dots (QDs) are synthesized by thermal decomposition of organic complexes in the system of the cost-effective commercial 0 # diesel at 200 °C. The prepared CdS QDs have a good dispersion and high crystallization. When the CdS QDs are doped into the blends of poly(3-hexylthiophene) (P3HT) and 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6, 6)C61 (PCBM) for hybrid solar cells (HSCs), the HSCs achieve about 25% increase of power conversion efficiency in comparison to the reference device without the CdS QDs. The improvement of the cell performance mainly attributes to the increased short-circuit current density arising from the absorption enhancement in the wavelength range of 350–550 nm by introducing the synthesized CdS QDs into the P3HT: PCBM active layer. - Highlights: • Monodisperse CdS quantum dots. • A cost-effective route to synthesize crystalline CdS quantum dots. • CdS quantum dots based hybrid solar cells with power conversion efficiency enhancement

An alternative route towards monodisperse CdS quantum dots for hybrid solar cells

Energy Technology Data Exchange (ETDEWEB)

Cao, Fengfeng; Wang, Hao [College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215006 (China); Xia, Zhouhui [Institute of Functional Nano and Soft Materials, Soochow University, Suzhou 215123 (China); Dai, Xiao; Cong, Shan [College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215006 (China); Dong, Chao [Department of Chemistry and Biology, University of New Mexico, ABQ 87120 (United States); Sun, Baoquan [Institute of Functional Nano and Soft Materials, Soochow University, Suzhou 215123 (China); Lou, Yanhui, E-mail: yhlou@suda.edu.cn [College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215006 (China); Sun, Yinghui; Zhao, Jie [College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215006 (China); Zou, Guifu, E-mail: zouguifu@suda.edu.cn [College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215006 (China)

2015-01-15

Monodisperse CdS quantum dots (QDs) are synthesized by thermal decomposition of organic complexes in the system of the cost-effective commercial 0{sup #} diesel at 200 °C. The prepared CdS QDs have a good dispersion and high crystallization. When the CdS QDs are doped into the blends of poly(3-hexylthiophene) (P3HT) and 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6, 6)C61 (PCBM) for hybrid solar cells (HSCs), the HSCs achieve about 25% increase of power conversion efficiency in comparison to the reference device without the CdS QDs. The improvement of the cell performance mainly attributes to the increased short-circuit current density arising from the absorption enhancement in the wavelength range of 350–550 nm by introducing the synthesized CdS QDs into the P3HT: PCBM active layer. - Highlights: • Monodisperse CdS quantum dots. • A cost-effective route to synthesize crystalline CdS quantum dots. • CdS quantum dots based hybrid solar cells with power conversion efficiency enhancement.

Ultra-wideband ladder filters using zero-th shear mode plate wave in ultrathin LiNbO3 plate with apodized interdigital transducers

Science.gov (United States)

Kadota, Michio; Tanaka, Shuji

2016-07-01

There are two kinds of plate waves propagating in a thin plate, Lamb and shear horizontal (SH) waves. The former has a velocity higher than 15,000 m/s when the plate is very thin. On the contrary, 0th SH (SH0) mode plate wave in an ultrathin LiNbO3 plate has an electro-mechanical coupling factor larger than 50%. Authors fabricated an ultra-wideband T-type ladder filter with a relative bandwidth (BW) of 41% using the SH0 mode plate wave. Although the BW of the filter fully covers the digital TV band in Japan, it does not have sufficient margin at the lower and higher end of BW. Besides, periodic small ripples due to transverse mode in pass-band of the filter were observed. In this study π-type ladder filters were fabricated by changing the pitch ratio of interdigital transducer (IDT) of parallel and series arm resonators (PR(IDT)) to control the BW, and by apodizing IDTs to improve the periodic small ripples due to transverse mode. Ultra-wideband filters without periodic small transverse mode with ultrawide bandwidth from 41 to 49% were fabricated. The BWs fully cover ultrawide digital television bands in Japan and U.S.A. These filters with an ultrawide BW and a steep characteristic show the possibility to be applied to a reported cognitive radio system and other communication systems requiring an ultrawide BW.

Exact solutions and ladder operators for a new anharmonic oscillator

International Nuclear Information System (INIS)

Dong Shihai; Sun Guohua; Lozada-Cassou, M.

2005-01-01

In this Letter, we propose a new anharmonic oscillator and present the exact solutions of the Schrodinger equation with this oscillator. The ladder operators are established directly from the normalized radial wave functions and used to evaluate the closed expressions of matrix elements for some related functions. Some comments are made on the general calculation formula and recurrence relation for off-diagonal matrix elements. Finally, we show that this anharmonic oscillator possesses a hidden symmetry between E(r) and E(ir) by substituting r->ir

Implantable bladder volume sensor based on resistor ladder network composed of conductive hydrogel composite.

Science.gov (United States)

Mi Kyung Kim; Hyojung Kim; Jung, Yeon Su; Adem, Kenana M A; Bawazir, Sarah S; Stefanini, Cesare; Lee, Hyunjoo J

2017-07-01

An accurate bladder volume monitoring system is a critical component in diagnosis and treatment of urological disorders. Here, we report an implantable bladder volume sensor with a multi-level resistor ladder which estimates the bladder volume through discrete resistance values. Discretization allows the sensor output to be resilient to the long-term drift, hysteresis, and degradation of the sensor materials. Our sensor is composed of biocompatible polypyrrole/agarose hydrogel composite. Because Young's modulus of this composite is comparable to that of the bladder wall, the effect of mechanical loading of the sensor on the bladder movement is minimized which allows more accurate volume monitoring. We also demonstrate the patterning and molding capability of this material by fabrication various structures. Lastly, we successfully demonstrate the functionality of the multi-level resistor ladder sensor as a bladder volume sensor by attaching the sensor on the pig's bladder and observing the impedance change of the sensor.

Short-distance behavior of the Bethe--Salpeter wave function in the ladder approximation

International Nuclear Information System (INIS)

Guth, A.H.; Soper, D.E.

1975-01-01

We investigate the short-distance behavior of the (Wick-rotated) Bethe--Salpeter wave function for the two spin-1/2 quarks bound by the exchange of a massive vector meson. We use the ladder-model kernel, which has the same p -4 scaling behavior as the true kernel in a theory with a fixed point of the renormalization group at g not equal to 0. For a bound state with the quantum numbers of the pion, the leading asymptotic behavior is chi (q/sup μ/) approx. cq/sup -4 + epsilon(g)/γ 5 , where epsilon (g) =1- (1-g 2 /π 2 ) 1 / 2 . Our method also provides the full asymptotic series, although it should be noted that the nonleading terms will depend on the nonleading behavior of the ladder-model kernel. A general term has the form cq - /sup a/(lnq)/sup n/phi (q/sup μ/), where c is an unknown constant, a may be integral or nonintegral, n is an integer, and phi (q/sup μ/) is a representation function of the rotation group in four dimensions

Nonlinear seismic analysis of continuous RC bridge

Directory of Open Access Journals (Sweden)

Čokić Miloš M.

2017-01-01

Full Text Available Nonlinear static analysis, known as a pushover method (NSPA is oftenly used to study the behaviour of a bridge structure under the seismic action. It is shown that the Equivalent Linearization Method - ELM, recommended in FEMA 440, is appropriate for the response analysis of the bridge columns, with different geometric characteristics, quantity and distribution of steel reinforcement. The subject of analysis is a bridge structure with a carriageway plate - a continuous beam with three spans, with the 24 + 40 + 24 m range. Main girder is made of prestressed concrete and it has a box cross section of a constant height. It is important to study the behaviour, not only in the transverse, but also in the longitudinal direction of the bridge axis, when analysing the bridge columns exposed to horizontal seismic actions. The columns were designed according to EN1992, parts 1 and 2. Seismic action analysis is conducted according to EN 1998: 2004 standard. Response spectrum type 1, for the ground type B, was applied and the analysis also includes 20% of traffic load. The analysis includes the values of columns displacement and ductility. To describe the behaviour of elements under the earthquake action in both - longitudinal and transverse direction, pushover curves were formed.

PARAMETRIC STUDY OF SKEW ANGLE ON BOX GIRDER BRIDGE DECK

OpenAIRE

Shrikant D. Bobade *, Dr. Valsson Varghese

2016-01-01

Box girder bridge deck, is the most common type of bridges in world and India, it consists of several Slab or girders. The span in the direction of the roadway and connected across their tops and bottoms by a thin continuous structural stab, the longitudinal box girders can be made of steel or concrete. The Simple supported single span concrete bridge deck is presented in present study. Skewed bridges are suitable in highway design when the geometry of straight bridges is not possible. The sk...

Seismic Analysis for a Crane System

Energy Technology Data Exchange (ETDEWEB)

Kim, Kang Soo; Lee, Chung Young; Ryu, Jeong Soo [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2012-05-15

The operation bridge used for an open-pool type research reactor is a crane system with a working deck for the handling of in-pool parts such as fuels, reactor components and reactor utilization facilities. The operation bridge allows operators to access the top of the reactor in the reactor pool and the fuel storage racks in the service pool. The operation bridge contains an operating platform mounted on a truck travelling on rails. Upright members are mounted on the truck to support the upper structure and two hoist monorails. The operation bridge consists of two hoists, upper girder frames, legs, cables, saddle frames, upper deck frames, lower deck frames, and the ladder. Static and dynamic analyses are performed to evaluate the structural integrity for the operation bridge for the required design loadings. The response spectrum analysis is employed as a dynamic analysis method

Seismic Analysis for a Crane System

International Nuclear Information System (INIS)

Kim, Kang Soo; Lee, Chung Young; Ryu, Jeong Soo

2012-01-01

The operation bridge used for an open-pool type research reactor is a crane system with a working deck for the handling of in-pool parts such as fuels, reactor components and reactor utilization facilities. The operation bridge allows operators to access the top of the reactor in the reactor pool and the fuel storage racks in the service pool. The operation bridge contains an operating platform mounted on a truck travelling on rails. Upright members are mounted on the truck to support the upper structure and two hoist monorails. The operation bridge consists of two hoists, upper girder frames, legs, cables, saddle frames, upper deck frames, lower deck frames, and the ladder. Static and dynamic analyses are performed to evaluate the structural integrity for the operation bridge for the required design loadings. The response spectrum analysis is employed as a dynamic analysis method

47 CFR 80.331 - Bridge-to-bridge communication procedure.

Science.gov (United States)

2010-10-01

... 47 Telecommunication 5 2010-10-01 2010-10-01 false Bridge-to-bridge communication procedure. 80..., Alarm, Urgency and Safety Procedures § 80.331 Bridge-to-bridge communication procedure. (a) Vessels subject to the Bridge-to-Bridge Act transmitting on the designated navigational frequency must conduct...

Influence of Icing on Bridge Cable Aerodynamics

DEFF Research Database (Denmark)

Koss, Holger; Frej Henningsen, Jesper; Olsen, Idar

2013-01-01

In recent years the relevance of ice accretion for wind-induced vibration of structural bridge cables has been recognised and became a subject of research in bridge engineering. Full-scale monitoring and observation indicate that light precipitation at moderate low temperatures between zero and -5......°C may lead to large amplitude vibrations of bridge cables under wind action. For the prediction of aerodynamic instability quasi-steady models have been developed estimating the cable response magnitude based on structural properties and aerodynamic force coefficients for drag, lift and torsion...... forces of different bridge cables types. The experiments were conducted in a wind tunnel facility capable amongst others to simulate incloud icing conditions....

Monodisperse Silver Nanoparticles Synthesized by a Microwave-Assisted Method

International Nuclear Information System (INIS)

Shao-Peng, Zhu; Shao-Chun, Tang; Xiang-Kang, Meng

2009-01-01

Silver nanoparticles with an average size of about 20 nm are synthesized in a colloidal solution with the aid of microwave irradiation. Neither additional reductant nor stabilizer is required in this microwave-assisted method. The color of the colloidal solution is found to be dark green, different from the characteristic yellow of silver colloidal solutions. The silver nanoparticles in the colloidal solution have a narrow size distribution and large yield quantity. UV-visible absorption spectroscopy analysis reveals that the as-synthesized monodisperse silver nanoparticles have exceptional optical properties. Raman spectroscopy measurements demonstrate that these silver nanoparticles exhibit a notable surface-enhanced Raman scattering ability. (cross-disciplinary physics and related areas of science and technology)

Dynamics of polyelectrolyte adsorption and colloidal flocculation upon mixing studied using mono-dispersed polystyrene latex particles

NARCIS (Netherlands)

Feng, Lili; Cohen Stuart, Martien; Adachi, Yasuhisa

2015-01-01

The dynamic behavior of polyelectrolytes just after their encounter with the surface of bare colloidal particles is analyzed, using the flocculation properties of mono-dispersed polystyrene latex (PSL) particles. Applying a Standardized Colloid Mixing (SCM) approach, effects of ionic strength and

Environmental life cycle assessment of railway bridge materials using UHPFRC

Science.gov (United States)

Bizjak, Karmen Fifer; Šajna, Aljoša; Slanc, Katja; Knez, Friderik

2016-10-01

The railway infrastructure is a very important component of the world's total transportation network. Investment in its construction and maintenance is significant on a global scale. Previously published life cycle assessment (LCA) studies performed on road and rail systems very seldom included infrastructures in detail, mainly choosing to focus on vehicle manufacturing and fuel consumption. This article presents results from an environmental study for railway steel bridge materials for the demonstration case of the Buna Bridge in Croatia. The goal of these analyses was to compare two different types of remediation works for railway bridges with different materials and construction types. In the first part, the environmental impact of the classical concrete bridge construction was calculated, whereas in the second one, an alternative new solution, namely, the strengthening of the old steel bridge with ultra-high-performance fibre-reinforced concrete (UHPFRC) deck, was studied. The results of the LCA show that the new solution with UHPFRC deck gives much better environmental performance. Up to now, results of LCA of railway open lines, railway bridges and tunnels have been published, but detailed analyses of the new solution with UHPFRC deck above the old bridge have not previously been performed.

Photoelectrochemical performance of DSSC with monodisperse and polydisperse ZnO SPs

Energy Technology Data Exchange (ETDEWEB)

Wahyuono, Ruri Agung, E-mail: r-agung-w@ep.its.ac.id; Risanti, Doty D., E-mail: r-agung-w@ep.its.ac.id [Department of Engineering Physics, Institut Teknologi Sepuluh Nopember (Indonesia); Shirosaki, Tomohiro; Nagaoka, Shoji [Kumamoto Industrial Research Institute (Japan); Takafuji, Makoto; Ihara, Hirotaka [Department of Applied Chemistry and Biochemistry, Kumamoto University (Japan)

2014-02-24

Zinc oxide, ZnO, is one of oxide semiconductors being used in DSSC. ZnO is promising material for having fairly higher energy band gap and much higher bulk electron mobility than that of anatase TiO{sub 2}, the most widely used semiconductor for DSSC photoelectrode. This study introduces the synthesis of ZnO by precipitation method. The synthesis involves ZnAc dihydrate and diethylene glycol (DEG) for the chemicals. Various size of ZnO spherical particles (SPs) are obtained in polydisperse and monodisperse particles. Monolayer and bilayer DSSCs are fabricated in sandwich structure and sensitized with N719 dye for 3 and 5 hours. Monolayer DSSC using monodisperse particles (422 nm) is able to generate highest conversion efficiency of 0.569% (V{sub oc} = 541.3 mV, J{sub sc} = 1.92 mA/cm{sup 2}, and fill factor of 54.78%). Bilayer DSSC, i.e. combined 422 - 185 nm ZnO layer, can optimize the photocurrent action spectra in UV regime leading to high conversion efficiency of 0.568 (V{sub oc} = 568.2 mV, J{sub sc} = 2.22 mA/cm{sup 2}, and fill factor of 47.25%). The longer sensitizing time does not always produce better conversion efficiency since it can induce the dissolution of Zn atoms and formation of Zn{sup 2+} - dye resisting the electron transport from dye to ZnO photoelectrode.

Characterization of Monodispersed Iron Oxide Nanocrystals by XAS and MCD measurement

International Nuclear Information System (INIS)

Kim, J.-Y.; Noh, H.-J.; Park, B.-G.; Kim, T.-Y.; Park, J.-H.; Hyeon, T.; Park, J.; Kang, E.

2004-01-01

Full text: Nanoparticles have attracted so much attention because of their potential technological applications and abundance of scientifically interesting issues. In particular, magnetic nanoparticles are considered to be applicable to various magnetic devices such as terabit memory, ferrofluids, magnetocaloric refrigeration systems, blood cells, etc. With the development of nano-technology, variation of physical properties as a function of particle size is one of the most important issues, but has been rarely explored because of difficulty of the size control in synthesizing nanoparticles. Recently, some of us successfully synthesized high crystalline and monodisperse maghemite nanoparticles without a size selection process and research in this field seems to be promoted by one step. In this report, we present a systematic characterization of the monodispersed nanocrystalline γ - Fe 2 O 3 with the diameter of 13, 8 and 4 nm by measuring the x-ray absorption spectroscopy (XAS) and the x-ray magnetic circular dichroism(XMCD) spectra on Fe L edge. The spectra of the 4 nm nanoparticles are very similar to those of maghemite (γ - Fe 2 O 3 ). However, the spectra become close to those of magnetite (Fe 3 O 4 ) as the particle size becomes 8 and 13 nm. Considering that the maghemite and magnetite have the same spinel structure with different Fe vacancies, these results can be explained that the surface of nanoparticles has more vacancies than the core part, indicating that surface disorder increases as the particle size decreases

Growth of monodisperse mesoscopic metal-oxide colloids under constant monomer supply

Science.gov (United States)

Nozawa, Koh; Delville, Marie-Hélène; Ushiki, Hideharu; Panizza, Pascal; Delville, Jean-Pierre

2005-07-01

In closed systems, control over the size of monodisperse metal-oxide colloids is generally limited to submicrometric dimensions. To overcome this difficulty, we explore the formation and growth of silica particles under constant monomer supply. The monomer source is externally driven by the progressive addition into the system of one of the precursors. Monodisperse spherical particles are produced up to a mesoscopic size. We analyze their growth versus the monomer addition rate at different temperatures. Our results show that in the presence of a continuous monomer addition, growth is limited by diffusion over the investigated temporal window. Using the temperature variation of the growth rate, we prove that rescaling leads to a data reduction onto a single master curve. Contrary to the growth process, the final particle’s size reached after the end of the reagent supply strongly depends on the addition rate. The variation of the final particle size versus addition rate can be deduced from an analogy with crystal formation in jet precipitation. Within this framework, and using the temperature dependences of both the particle growth law and the final size, we determine the value of the molecular heat of dissolution associated to the silica solubility. These observations support the fact that classical theories of phase-ordering dynamics can be extended to the synthesis of inorganic particles. The emergence of a master behavior in the presence of continuous monomer addition also suggests the extension of these theories to open systems.

Field-controlled magnetic order in the quantum spin-ladder system (Hpip)2CuBr4

DEFF Research Database (Denmark)

Thielemann, B.; Rüegg, C.; Kiefer, K.

2009-01-01

Neutron diffraction is used to investigate the field-induced, antiferromagnetically ordered state in the two-leg spin-ladder material (Hpip)(2)CuBr4. This "classical" phase, a consequence of weak interladder coupling, is nevertheless highly unconventional: its properties are influenced strongly...

Third-order differential ladder operators and supersymmetric quantum mechanics

International Nuclear Information System (INIS)

Mateo, J; Negro, J

2008-01-01

Hierarchies of one-dimensional Hamiltonians in quantum mechanics admitting third-order differential ladder operators are studied. Each Hamiltonian has associated three-step Darboux (pseudo)-cycles and Painleve IV equations as a closure condition. The whole hierarchy is generated applying some operations on the cycles. These operations are investigated in the frame of supersymmetric quantum mechanics and mainly involve algebraic manipulations. A consistent geometric representation for the hierarchy and cycles is built that also helps in understanding the operations. Three kinds of hierarchies are distinguished and a realization based on the harmonic oscillator Hamiltonian is supplied, giving an interpretation for the spectral properties of the Hamiltonians of each hierarchy

Simulation of TunneLadder traveling-wave tube cold-test characteristics: Implementation of the three-dimensional, electromagnetic circuit analysis code micro-SOS

Science.gov (United States)

Kory, Carol L.; Wilson, Jeffrey D.

1993-01-01

The three-dimensional, electromagnetic circuit analysis code, Micro-SOS, can be used to reduce expensive time-consuming experimental 'cold-testing' of traveling-wave tube (TWT) circuits. The frequency-phase dispersion characteristics and beam interaction impedance of a TunneLadder traveling-wave tube slow-wave structure were simulated using the code. When reasonable dimensional adjustments are made, computer results agree closely with experimental data. Modifications to the circuit geometry that would make the TunneLadder TWT easier to fabricate for higher frequency operation are explored.

The Earnings Ladder. Who's at the Bottom? Who's at the Top? Statistical Brief.

Science.gov (United States)

Bureau of the Census (DOC), Washington, DC. Economics and Statistics Administration.

Data collected by the March Current Population Survey were used to identify which groups of year-round, full-time civilian workers aged 16 and older were most likely to be at the top and bottom of the earnings ladder. Women, young workers, less-educated individuals, and Hispanics were most likely to earn less than $13,091 (1992 constant dollars),…

Simplified Analytical Model for a Queen-Post Covered Timber Bridge

Science.gov (United States)

F Fanous; D. Rammer; T. Wipf

2013-01-01

During the 19th century, the economic material to build bridges was timber due to its abundant availability, cost, and ease of construction. Many of the well-known timber bridge types are the Burr arch, Town lattice, Howe, Queen and King type of trusses. This paper summarizes an investigation that was sponsored by the Federal Highway Administration and the USDA Forest...

Wind tunnel test of musi VI bridge

Science.gov (United States)

Permata, Robby; Andika, Matza Gusto; Syariefatunnisa, Risdhiawan, Eri; Hermawan, Budi; Noordiana, Indra

2017-11-01

Musi VI Bridge is planned to cross the Musi River in Palembang City, South Sumatera Province, Indonesia. The main span is a steel arch type with 200 m length and side span length is 75 m. Finite element analysis results showed that the bridge has frequency ratio for torsional and heaving mode (torsional frequency/heaving frequency)=1.14. This close to unity value rises concern about aerodynamic behaviour and stability of the bridge deck under wind loading. Sectional static and free vibration wind tunnel test were performed to clarify this phenomena in B2TA3 facility in Serpong, Indonesia. The test followed the draft of Guide of Wind Tunnel Test for Bridges developed by Indonesian Ministry of Public Works. Results from wind tunnel testing show that the bridge is safe from flutter instability and no coupled motion vibration observed. Therefore, low value of frequency ratio has no effect to aerodynamic behaviour of the bridge deck. Vortex-induced vibration in heaving mode occurred in relatively low wind velocity with permissible maximum amplitude value.

Disorder effects in the S=1 antiferromagnetic spin ladder CaV{sub 2}O{sub 4}

Energy Technology Data Exchange (ETDEWEB)

Guitarra, S.R. [Colegio de Ciencias e Ingeniería, Universidad San Francisco de Quito, Quito (Ecuador); Caneiro, A. [Instituto Balseiro - Centro Atómico Bariloche, 8400 Bariloche (Argentina); Niebieskikwiat, D., E-mail: dniebieskikwiat@usfq.edu.ec [Colegio de Ciencias e Ingeniería, Universidad San Francisco de Quito, Quito (Ecuador)

2015-10-15

We study the physical properties of the antiferromagnetic spin ladder CaV{sub 2}O{sub 4} (CVO) and the Y-doped related compound Ca{sub 0.9}Y{sub 0.1}V{sub 2}O{sub 4}. In the latter, X-ray diffraction demonstrates the segregation of a small amount of a vanadium–perovskite impurity phase, leading to the formation of V vacancies within the main CVO-type structure. The 1D character of this calcium–vanadite enhances the influence of the vacancies on the electric and magnetic properties of Ca{sub 0.9}Y{sub 0.1}V{sub 2}O{sub 4}. Electrical transport is characterized by a variable-range hopping mechanism determined by the charging energy of nm-sized segments of V chains delimited by V vacancies, i.e. a Coulomb gap is formed at the Fermi level. These vacancies also locally affect the magnetic correlations, breaking the long-range AFM order observed in CaV{sub 2}O{sub 4} and producing exchange bias when the Y-doped sample is cooled with an applied magnetic field. - Highlights: • We study disorder effects in the quasi-1D antiferromagnetic spin ladder CaV{sub 2}O{sub 4}. • V vacancies in CaV{sub 2}O{sub 4} lead to variable-range hopping electrical transport. • The charging energy of nm-sized V chains determine the transport mechanism exponents. • V vacancies break the long-range AFM order of CaV{sub 2}O{sub 4}. • Local magnetic correlations in the vicinity of the defects produce exchange bias.

Monodisperse, submicrometer-scale platinum colloidal spheres with high electrocatalytic activity

Energy Technology Data Exchange (ETDEWEB)

Zhang, Lixue; Wang, Liang; Guo, Shaojun; Zhai, Junfeng; Dong, Shaojun; Wang, Erkang [State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Graduate School of the Chinese Academy of Sciences, 130022 Jilin, Changchun (China)

2009-02-15

Monodisperse, submicrometer-scale platinum (Pt) colloidal spheres were prepared through a simple direct chemical reduction of p-phenylenediamine (PPD)-chloroplatinic acid (H{sub 2}PtCl{sub 6}) coordination polymer colloids. It was found that the prepared Pt colloids had the similar size and morphology with their coordination polymer precursors, and the prepared Pt colloids with rough surfaces were three-dimensional (3D) structured assemblies of high-density small Pt nanoparticles. The electrochemical experiments confirmed that the prepared Pt colloids possessed a high electrocatalytic activity towards mainly four-electron reduction of dioxygen to water, making the prepared Pt colloids potential candidates for the efficient cathode material in fuel cells. (author)

Self-charging of 198Au-labeled monodisperse gold aerosols studied with a miniature electrical mobility spectrometer

International Nuclear Information System (INIS)

Yeh, H.C.; Newton, G.J.; Raabe, O.G.; Boor, D.R.

1976-01-01

Knowledge of the electrostatic character of an aerosol may be essential in assessing its potential inhalation hazard. In inhalation studies with radioactive aerosols, the aerosol charge state may change in the course of transport due to the emission of α, β or γ radiations. This paper describes an experimental study of the self-charging of 198 Au-labeled aerosols of monodisperse gold spheres by β emission. A miniature aerosol electrical mobility spectrometer, suitable for use in inhalation studies with radioactive aerosols, was developed and used in this study. This device is relatively inexpensive, easy to manufacture and its contamination by radioactive material has been minimized. Using polystyrene latex spheres, ranging in diameter from 0.176 to 1.18 μm, the spectrometer was calibrated with flow rates ranging from 400 to 4800 ml/min. Experiments with two sizes of 198 Au-labeled monodisperse gold aerosols were performed. Results indicate that the radioactivity of an aerosol can cause self-charging and affect the charge distribution. (author)

Academic Profile of Bachelor of Technical Teacher Education Ladder I Students as Ba sis for an Intervention Program

Directory of Open Access Journals (Sweden)

Arly B. Balingbing

2017-05-01

Full Text Available This study aimed to determine: the academic profile of Bachelor of Technical Teacher Education ( BTTE Ladder 1 students in terms of entrance examination, GWM in GEC subjects and TESDA Competency Assessment; their strengths and weaknesses along TESDA Assessment; the significant relationship between Entrance Examination & GWA, GWA & TESDA Competency and Entrance Examination & TESDA Compe tency, the significant interrelationship among the three variables; and the program or intervention which could be proposed to improve their academic performance. Data were gathered from one hundred fifty eight ( 158 BTTE Ladder 1 graduates of SY 2014 - 2016 through a questionnaire and documentary analysis and were statistically treated using percentage, weighted mean, Spearman’s rho and multiple coefficients. The researcher concluded that BTTE Ladder 1 students are competent as assessed by TESDA despite bein g low in entrance examination. Their weaknesses lie along communication and comprehension but they prove to be capable also on the condition that Filipino language is used and questions are repeated or rephrased. They also lack exposure to the tools and eq uipment used their field. Their strength is evident in performing the task but not in explaining the process. Both the Entrance Examination & GWA, GWM & TESDA Competency and Entrance Exam & TESDA Competency are significantly interrelated.

Simplified Analytical Model of a Covered Burr-Arch-Truss Timber Bridge

Science.gov (United States)

F. Fanous; D. Rammer; T. Wipf

2013-01-01

Due to the importance of historical timber covered bridges throughout history, their preservation is necessary. However, conducting an accurate structural evaluation of these types of bridges has always caused difficulties to bridge engineers. This paper summarizes an investigation that was sponsored by the Federal Highway Administration and the USDA Forest Products...

MASH Test 3-11 on the T131RC Bridge Rail

Science.gov (United States)

2012-10-01

Texas Department of Transportation (TxDOT) currently uses the TxDOT Type T101RC Bridge Rail, : a steel post and beam bridge rail anchored to the top of concrete curbs. The T101RC Bridge Rail is : 27 inches in height and can be anchored to the top of ...

Environmental life cycle assessment of railway bridge materials using UHPFRC

Directory of Open Access Journals (Sweden)

Bizjak Karmen Fifer

2016-10-01

Full Text Available The railway infrastructure is a very important component of the world’s total transportation network. Investment in its construction and maintenance is significant on a global scale. Previously published life cycle assessment (LCA studies performed on road and rail systems very seldom included infrastructures in detail, mainly choosing to focus on vehicle manufacturing and fuel consumption. This article presents results from an environmental study for railway steel bridge materials for the demonstration case of the Buna Bridge in Croatia. The goal of these analyses was to compare two different types of remediation works for railway bridges with different materials and construction types. In the first part, the environmental impact of the classical concrete bridge construction was calculated, whereas in the second one, an alternative new solution, namely, the strengthening of the old steel bridge with ultra-high-performance fibre-reinforced concrete (UHPFRC deck, was studied. The results of the LCA show that the new solution with UHPFRC deck gives much better environmental performance. Up to now, results of LCA of railway open lines, railway bridges and tunnels have been published, but detailed analyses of the new solution with UHPFRC deck above the old bridge have not previously been performed.

Myocardial Bridge

Science.gov (United States)

... Center > Myocardial Bridge Menu Topics Topics FAQs Myocardial Bridge En español Your heart is made of muscle, ... surface of the heart. What is a myocardial bridge? A myocardial bridge is a band of heart ...

Droplet size effects on NO/x/ formation in a one-dimensional monodisperse spray combustion system

Science.gov (United States)

Sarv, H.; Nizami, A. A.; Cernansky, N. P.

1982-01-01

A one-dimensional monodisperse aerosol spray combustion facility is described and experimental results of post flame NO/NO(x) emissions are presented. Four different hydrocarbon fuels were studied: isopropanol, methanol, n-heptane, and n-octane. The results indicate an optimum droplet size in the range of 48-58 microns for minimizing NO/NO(x) production for all of the test fuels. This NO(x) behavior is associated with droplet interactions and the transition from diffusive type of spray burning to that of a prevaporized and premixed case. Decreasing the droplet size results in a trend of increasing droplet interactions, which suppresses temperatures and reduces NO(x). This trend continues until prevaporization effects begin to dominate and the system tends towards the premixed limit. The occurrence of the minimum NO(x) point at different droplet diameters for the different fuels appears to be governed by the extent of prevaporization of the fuel in the spray, and is consistent with theoretical calculations based on each fuel's physical properties.

Fatigue-Prone Details in Steel Bridges

Directory of Open Access Journals (Sweden)

Mohsen Heshmati

2012-11-01

Full Text Available This paper reviews the results of a comprehensive investigation including more than 100 fatigue damage cases, reported for steel and composite bridges. The damage cases are categorized according to types of detail. The mechanisms behind fatigue damage in each category are identified and studied. It was found that more than 90% of all reported damage cases are of deformation-induced type and generated by some kind of unintentional or otherwise overlooked interaction between different load-carrying members or systems in the bridge. Poor detailing, with unstiffened gaps and abrupt changes in stiffness at the connections between different members were also found to contribute to fatigue cracking in many details.

Planning of Tatara Bridge. Chodai shachokyo-Tataraohashi-no keikaku gaiyo

Energy Technology Data Exchange (ETDEWEB)

Okukawa, A. (Honshu-Shikoku Bridge Authority, Tokyo (Japan))

1991-12-05

The outline of the Tatara Bridge is given to introduce the features of the entire structural system and fundamental problems concerning the construction of the huge cable stayed bridge. The central span of the bridge is 890m. The topography and geological features of the bridging point are reviewed, and social conditions such as being in a national park, safety for sailing, etc. are taken into consideration for various technological studies on the construction of the huge bridge. Bridge piers are provided in the side spans and appropriate counter weight is loaded to design a more economical bridge which is more suitable for the topography as compared with a suspension bridge. The cable stayed bridge requires no anchorage which is necessary for a suspension bridge with very little topological alteration, and an excellent result is obtained both in cost and term of construction as compared with a suspension bridge. The rigidity of the cable stayed bridge is high, and the stability of the resistance to wind of the structure is also very satisfactory. As a result, it is concluded that the bridge can be designed and constructed using currently available technologies, and a cable stayed bridge is selected in August, 1990 as the type for the Tatara Bridge. 9 figs., 1 tab.

Environmentally friendly synthesis of highly monodisperse biocompatible gold nanoparticles with urchin-like shape.

Science.gov (United States)

Lu, Lehui; Ai, Kelong; Ozaki, Yukihiro

2008-02-05

We report a facile and environmentally friendly strategy for high-yield synthesis of highly monodisperse gold nanoparticles with urchin-like shape. A simple protein, gelatin, was first used for the control over shape and orientation of the gold nanoparticles. These nanoparticles, ready to use for biological systems, are promising in the optical imaging-based disease diagnostics and therapy because of their tunable surface plasmon resonance (SPR) and excellent surface-enhanced Raman scattering (SERS) activity.

Telecast of Astronaut Neil Armstrong descending ladder to surface of the moon

Science.gov (United States)

1969-01-01

Astronaut Neil A. Armstrong, Apollo 11 commander, descends the ladder of the Apollo 11 Lunar Module prior to making the first step by man on the moon. This view is a black and white reproduction taken from a telecast by the Apollo 11 lunar surface camera during extravehicular activity. The black bar running through the center of the picture is an anamoly in the television ground data system at the Goldstone Tracking Station.

Structure and dynamics of particle-accumulation in thermocapillary liquid bridges

International Nuclear Information System (INIS)

Kuhlmann, Hendrik C; Mukin, Roman V; Sano, Tomoaki; Ueno, Ichiro

2014-01-01

The accumulation of small mono-disperse heavy particles in thermocapillary liquid bridges is investigated experimentally and numerically. We consider particle accumulation near the center of the toroidal vortex, the so-called toroidal core of particles (COP), and the particle-depletion zone near the axis of the liquid bridge. Based on the acceleration and deceleration of the tangential flow along the thermocapillary free surface it is argued that the interaction of the particles with the free surface is of key importance for the fast particle accumulation within a few characteristic momentum diffusion times. The experimentally determined particle-accumulation times are compared with time-scale estimates for accumulation due to either particle free-surface interaction or due to inertia of particles which are heavier than the liquid. We show that the experimental accumulation times are compatible with the accumulation times predicted by the particle–free-surface interaction (PSI) while the time-scale estimates based on the inertia of the particles are too large to explain the fast de-mixing observed in experiments. The shape of the COP resembles certain KAM tori of the incompressible flow of a hydrothermal wave. Two scenarios are proposed to explain the structure and the dynamics of the COP depending on the existence or non-existence of suitable KAM structures. The shape of the experimental particle-depletion zone agrees well with the release surface which is defined by the particle–free-surface interaction process. The favorable comparison of the dynamics and structure of experimental and numerical accumulation patterns provides strong evidence for the existence and relevance of the PSI as the most rapid physical accumulation mechanism. (paper)

Experimental mixture design as a tool for the synthesis of antimicrobial selective molecularly imprinted monodisperse microbeads.

Science.gov (United States)

Benito-Peña, Elena; Navarro-Villoslada, Fernando; Carrasco, Sergio; Jockusch, Steffen; Ottaviani, M Francesca; Moreno-Bondi, Maria C

2015-05-27

The effect of the cross-linker on the shape and size of molecular imprinted polymer (MIP) beads prepared by precipitation polymerization has been evaluated using a chemometric approach. Molecularly imprinted microspheres for the selective recognition of fluoroquinolone antimicrobials were prepared in a one-step precipitation polymerization procedure using enrofloxacin (ENR) as the template molecule, methacrylic acid as functional monomer, 2-hydroxyethyl methacrylate as hydrophilic comonomer, and acetonitrile as the porogen. The type and amount of cross-linker, namely ethylene glycol dimethacrylate, divinylbenzene or trimethylolpropane trimethacrylate, to obtain monodispersed MIP spherical beads in the micrometer range was optimized using a simplex lattice design. Particle size and morphology were assessed by scanning electron microscopy, dynamic light scattering, and nitrogen adsorption measurements. Electron paramagnetic resonance spectroscopy in conjunction with a nitroxide as spin probe revealed information about the microviscosity and polarity of the binding sites in imprinted and nonimprinted polymer beads.

Micro-bridge defects: characterization and root cause analysis

Science.gov (United States)

Santoro, Gaetano; Van den Heuvel, Dieter; Braggin, Jennifer; Rosslee, Craig; Leray, Philippe J.; Cheng, Shaunee; Jehoul, Christiane; Schreutelkamp, Robert; Hillel, Noam

2010-03-01

Defect review of advanced lithography processes is becoming more and more challenging as feature sizes decrease. Previous studies using a defect review SEM on immersion lithography generated wafers have resulted in a defect classification scheme which, among others, includes a category for micro-bridges. Micro-bridges are small connections between two adjacent lines in photo-resist and are considered device killing defects. Micro-bridge rates also tend to increase as feature sizes decrease, making them even more important for the next technology nodes. Especially because micro-bridge defects can originate from different root causes, the need to further refine and split up the classification of this type of defect into sub groups may become a necessity. This paper focuses on finding the correlation of the different types of micro-bridge defects to a particular root cause based on a full characterization and root cause analysis of this class of defects, by using advanced SEM review capabilities like high quality imaging in very low FOV, Multi Perspective SEM Imaging (MPSI), tilted column and rotated stage (Tilt&Rotation) imaging and Focused Ion Beam (FIB) cross sectioning. Immersion lithography material has been mainly used to generate the set of data presented in this work even though, in the last part of the results, some EUV lithography data will be presented as part of the continuing effort to extend the micro-bridge defect characterization to the EUV technology on 40 nm technology node and beyond.

Fish passage post-construction issues: analysis of distribution, attraction and passage efficiency metrics at the Baguari Dam fish ladder to approach the problem

Directory of Open Access Journals (Sweden)

Luiz Gustavo Martins da Silva

Full Text Available Fish passages are considered the oldest management tool used to minimize the impact of blocking fish migratory routes by hydroelectric power plants. However, fish passages are being installed without specific criteria in Brazil, with severe consequences to the conservation of the local fish fauna. Therefore, basic data gathered for fish passages already constructed could contribute to define operational rules, in addition to offer subsidies to decision-making and design of future facilities. Thus, the fish ladder of Baguari Dam was evaluated regarding temporal distribution, attraction, and ascension of the local fish fauna. A total of 20 fish samples were conducted immediately downstream of the dam and inside the fish ladder, from January 2010 to June 2011. Seasonal variation in fish abundance and richness was registered below the dam and inside the passage, with higher number of migratory fish in the reproductive season (Kruskall-Wallis, p = 0.04 and p = 0.05. Furthermore, higher concentration of migratory allochthonous and non-migratory species was registered for the spill bay (Wilcoxon, p = 0.009 and p = 0.006 compared to the tailrace, where the fish ladder entrance is located. This result suggests low efficiency of the attraction system of the mechanism during the reproductive period. Once entering the fish ladder, migratory species apparently ascend the facility due to the similar distribution throughout different stretches. Generally, the results showed that an operational rule for the Baguari Dam fish ladder should consider running the facility only during the reproductive period, unless the objectives of the passage are well defined. The attraction system must be more precisely evaluated, using technologies such as radiotelemetry. Similarly, fish ascension also should be better analyzed to evaluate the time spent to ascend and its influence in the reproductive biology of the species using the ladder. Pit-tag system could be used to

SU(3)_C× SU(2)_L× U(1)_Y( × U(1)_X ) as a symmetry of division algebraic ladder operators

Science.gov (United States)

Furey, C.

2018-05-01

We demonstrate a model which captures certain attractive features of SU(5) theory, while providing a possible escape from proton decay. In this paper we show how ladder operators arise from the division algebras R, C, H, and O. From the SU( n) symmetry of these ladder operators, we then demonstrate a model which has much structural similarity to Georgi and Glashow's SU(5) grand unified theory. However, in this case, the transitions leading to proton decay are expected to be blocked, given that they coincide with presumably forbidden transformations which would incorrectly mix distinct algebraic actions. As a result, we find that we are left with G_{sm} = SU(3)_C× SU(2)_L× U(1)_Y / Z_6. Finally, we point out that if U( n) ladder symmetries are used in place of SU( n), it may then be possible to find this same G_{sm}=SU(3)_C× SU(2)_L× U(1)_Y / Z_6, together with an extra U(1)_X symmetry, related to B-L.

5′-Methylsulfanyl-4′-oxo-7′-phenyl-3′,4′-dihydro-1′H-spiro[cyclohexane-1,2′-quinazoline]-8′-carbonitrile dimethylformamide monosolvate

Directory of Open Access Journals (Sweden)

Xuan Liu

2011-08-01

Full Text Available In the title compound, C21H21N3OS·C3H7NO, the carbonitrile molecule is built up of two fused six-membered rings and one six-membered ring linked through a spiro C atom. The 1,3-diaza ring adopts an envelope conformation and the cyclohexane ring adopts a chair conformation. The dihedral angle between the aromatic rings is 46.7 (3°. In the crystal, the components are linked by N—H...O hydrogen bonds.

Energy harvesting on highway bridges.

Science.gov (United States)

2011-01-01

A concept for harvesting energy from the traffic-induced loadings on a highway bridge using piezoelectric : materials to generate electricity was explored through the prototype stage. A total of sixteen lead-zirconate : titanate (PZT) Type 5A piezoel...

Highly sensitive glucose sensor based on monodisperse palladium nickel/activated carbon nanocomposites.

Science.gov (United States)

Koskun, Yağmur; Şavk, Aysun; Şen, Betül; Şen, Fatih

2018-06-20

Glucose enzyme biosensors have been used for a variety of applications such as medical diagnosis, bioprocess engineering, beverage industry and environmental scanning etc. and there is still a growing interest in glucose sensors. For this purpose, addressed herein, as a novel glucose sensor, highly sensitive activated carbon (AC) decorated monodisperse nickel and palladium alloy nanocomposites modified glassy carbon electrode (Ni-Pd@AC/GCE NCs) have been synthesized by in-situ reduction technique. Raman Spectroscopy (RS), X-ray Photoelectron Spectroscopy (XPS), X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM), cyclic voltammetry (CV) and chronoamperometry (CA) were used for the characterization of the prepared non-enzymatic glucose sensor. The characteristic sensor properties of the Ni-Pd@AC/GCE electrode were compared with Ni-Pd NCs/GCE, Ni@AC/GCE and Pd@AC/GCE and the results demonstrate that the AC is very effective in the enhancement of the electrocatalytic properties of sensor. In addition, the Ni-Pd@AC/GCE nanocomposites showed a very low detection limit of 0.014 μM, a wide linear range of 0.01 mM-1 mM and a very high sensitivity of 90 mA mM -1  cm -2 . Furthermore, the recommended sensor offer the various advantageous such as facile preparation, fast response time, high selectivity and sensitivity. Lastly, monodisperse Ni-Pd@AC/GCE was utilized to detect glucose in real sample species. Copyright © 2018 Elsevier B.V. All rights reserved.

Phase transitions and thermal entanglement of the distorted Ising-Heisenberg spin chain: topology of multiple-spin exchange interactions in spin ladders

Science.gov (United States)

Arian Zad, Hamid; Ananikian, Nerses

2017-11-01

We consider a symmetric spin-1/2 Ising-XXZ double sawtooth spin ladder obtained from distorting a spin chain, with the XXZ interaction between the interstitial Heisenberg dimers (which are connected to the spins based on the legs via an Ising-type interaction), the Ising coupling between nearest-neighbor spins of the legs and rungs spins, respectively, and additional cyclic four-spin exchange (ring exchange) in the square plaquette of each block. The presented analysis supplemented by results of the exact solution of the model with infinite periodic boundary implies a rich ground state phase diagram. As well as the quantum phase transitions, the characteristics of some of the thermodynamic parameters such as heat capacity, magnetization and magnetic susceptibility are investigated. We prove here that among the considered thermodynamic and thermal parameters, solely heat capacity is sensitive versus the changes of the cyclic four-spin exchange interaction. By using the heat capacity function, we obtain a singularity relation between the cyclic four-spin exchange interaction and the exchange coupling between pair spins on each rung of the spin ladder. All thermal and thermodynamic quantities under consideration should be investigated by regarding those points which satisfy the singularity relation. The thermal entanglement within the Heisenberg spin dimers is investigated by using the concurrence, which is calculated from a relevant reduced density operator in the thermodynamic limit.

Feature of extradosed PC bridge and its design; Daihenshin keburu PC kyo no tokucho to sono sekkei

Energy Technology Data Exchange (ETDEWEB)

Komiya, M. [Japan Bridge and Structure Institute Inc., Tokyo (Japan)

1997-03-31

A PC bridge with the eccentricity of the external cable increased by protruding the deviated member to the outside of the beam for more effective use of the external cable is called a `PC bridge with tendons of large eccentricity.` The extradosed bridge of main beam/cable joint type is a PC bridge with the external cable arranged via a tower-shaped eccentric member provided at the intermediate support, and resembles morphologically a cable stayed bridge having a very low tower. There are two types of extradosed bridges, i.e. a type with concrete coated external cable (cable stayed slab bridge) and the other with non-coated external cable (external cable stayed bridge). Features, structural planning and designing of the general external cable stayed bridge are shown. The features are the possession of intermediate characteristics of those of the PC beam bridge and the PC cable stayed bridge from the viewpoints of structural property, workability, economic efficiency, and scenic property. Outline of the plan, selection of structural data, design of the external cable, and structural characteristics in the ultimate state are discussed. 19 refs., 18 figs., 15 tabs.

Nonthermal plasma synthesis of size-controlled, monodisperse, freestanding germanium nanocrystals

International Nuclear Information System (INIS)

Gresback, Ryan; Holman, Zachary; Kortshagen, Uwe

2007-01-01

Germanium nanocrystals may be of interest for a variety of electronic and optoelectronic applications including photovoltaics, primarily due to the tunability of their band gap from the infrared into the visible range of the spectrum. This letter discusses the synthesis of monodisperse germanium nanocrystals via a nonthermal plasma approach which allows for precise control of the nanocrystal size. Germanium crystals are synthesized from germanium tetrachloride and hydrogen entrained in an argon background gas. The crystal size can be varied between 4 and 50 nm by changing the residence times of crystals in the plasma between ∼30 and 440 ms. Adjusting the plasma power enables one to synthesize fully amorphous or fully crystalline particles with otherwise similar properties

Online measurement of mental representations of complex spatial decision problems : comparison of CNET and hard laddering

NARCIS (Netherlands)

Horeni, O.; Arentze, T.A.; Dellaert, B.G.C.; Timmermans, H.J.P.

2014-01-01

This paper introduces the online Causal Network Elicitation Technique (CNET), as a technique for measuring components of mental representations of choice tasks and compares it with the more common technique of online 'hard' laddering (HL). While CNET works in basically two phases, one in open

Preparation of monodisperse porous silica particles using poly(glycidyl methacrylate) microspheres as a template

Czech Academy of Sciences Publication Activity Database

Grama, Silvia; Horák, Daniel

2015-01-01

Roč. 64, Suppl. 1 (2015), S11-S17 ISSN 0862-8408 R&D Projects: GA MŠk(CZ) EE2.3.30.0029; GA MŠk(CZ) ED1.1.00/02.0109 Institutional support: RVO:61389013 Keywords : microspheres * monodisperse * silica Subject RIV: EB - Genetics ; Molecular Biology Impact factor: 1.643, year: 2015 http://www.biomed.cas.cz/physiolres/pdf/64%20Suppl%201/64_S11.pdf

Influence of seasonal, diel, lunar, and other environmental factors on upstream fish passage in the igarapava fish ladder, Brazil

Science.gov (United States)

Bizzotto, P.M.; Godinho, Alexandre L.; Vono, V.; Kynard, B.; Godinho, Hugo P.

2009-01-01

Upstream fish passage was evaluated during 12 months in the vertical-slot Igarapava Fish Ladder constructed around Igarapava Dam, in the heavily dammed Grande River, Southeast Brazil. A video monitoring system was used to observe 61,621 fish that passed the ladder, of which 93.5% were identified to 15 taxa. Among the migratory species, the most abundant were Pimelodus maculatus (33.6% of all fish), Leporinus octofasciatus (31.4%), Leporinus friderici (4.5%), and Prochilodus lineatus (3.1%). Seven taxa were classified as nonmigratory, and of these taxa, the small Bryconamericus stramineus was the most abundant (12.7%) of all fishes. Passage of the 'nonmigratory' taxa upstream in the ladder shows they are migratory in this system and have a strong behavioural drive to move to upstream habitat. Passage of most taxa had a strong seasonal pattern. While some species passed primarily during the day, others showed a distinct nocturnal pattern. Lunar phase and water temperature also strongly affected passage of some taxa. Rainfall and dam discharge had a small or null influence on most taxa; perhaps due to the fairly small catchment area of the reservoir and the highly regulated discharge at Igarapava Dam. ?? 2009 John Wiley & Sons A/S.

The Akashi Kaikyo Bridge and the Storebælt Bridge

DEFF Research Database (Denmark)

Gimsing, Niels Jørgen

1999-01-01

With the completion of the Akashi Kaikyo Bridge and the Storebælt East Bridge the development of the suspension bridge technology in the 20th century has manifested itself in two impressive structures. With the present echnology may bridges of similar (and also more modest) dimensions...... will undoubtedly be built far into the next century. For bridges going beyond the spans of existing bridges it is, however, likely that new concepts will be developed....

Pennsylvania hardwood timber bridges : field performance after 10 years

Science.gov (United States)

James P. Wacker; Carlito Calil

2004-01-01

Several hardwood demonstration timber bridges were built by the Pennsylvania Department of Transportation in the early nineteen nineties. These bridge superstructures are of the recently developed stress-laminated deck design-type using Red Oak lumber laminations that were pressure-treated with creosote preservatives. This paper will describe the data acquisition...

Rapid Synthesis of Highly Monodisperse Au x Ag 1− x Alloy Nanoparticles via a Half-Seeding Approach

KAUST Repository

Chng, Ting Ting; Polavarapu, Lakshminarayana; Xu, Qing Hua; Ji, Wei; Zeng, Hua Chun

2011-01-01

Gold-silver alloy AuxAg1-x is an important class of functional materials promising new applications across a wide array of technological fields. In this paper, we report a fast and facile synthetic protocol for preparation of highly monodisperse Aux

Microfluidic preparation and self diffusion PFG-NMR analysis of monodisperse water-in-oil-in-water double emulsions.

Science.gov (United States)

Hughes, Eric; Maan, Abid Aslam; Acquistapace, Simone; Burbidge, Adam; Johns, Michael L; Gunes, Deniz Z; Clausen, Pascal; Syrbe, Axel; Hugo, Julien; Schroen, Karin; Miralles, Vincent; Atkins, Tim; Gray, Richard; Homewood, Philip; Zick, Klaus

2013-01-01

Monodisperse water-in-oil-in-water (WOW) double emulsions have been prepared using microfluidic glass devices designed and built primarily from off the shelf components. The systems were easy to assemble and use. They were capable of producing double emulsions with an outer droplet size from 100 to 40 μm. Depending on how the devices were operated, double emulsions containing either single or multiple water droplets could be produced. Pulsed-field gradient self-diffusion NMR experiments have been performed on the monodisperse water-in-oil-in-water double emulsions to obtain information on the inner water droplet diameter and the distribution of the water in the different phases of the double emulsion. This has been achieved by applying regularization methods to the self-diffusion data. Using these methods the stability of the double emulsions to osmotic pressure imbalance has been followed by observing the change in the size of the inner water droplets over time. Copyright © 2012 Elsevier Inc. All rights reserved.

Antisolvent Precipitation for the Synthesis of Monodisperse Mesoporous Niobium Oxide Spheres as Highly Effective Solid Acid Catalysts

KAUST Repository

Li, Cheng Chao; Dou, Jian; Chen, Luwei; Lin, Jianyi; Zeng, Hua Chun

2012-01-01

We have developed a low-cost reaction protocol to synthesize mesoporous Nb 2O 5-based solid acid catalysts with external shape control. In the synthesis, monodisperse glycolated niobium oxide spheres (GNOS) were prepared by means of a simple antisolvent precipitation approach and subsequently converted to mesoporous niobium oxide spheres (MNOS) with a large surface area of 312m 2g -1 by means of the hydrothermal treatment. The antisolvent acetone used to obtain GNOS was recovered through distillation at high purity. The obtained mesoporous MNOS were functionalized further with sulfate anions at different temperatures or incorporated with tungstophosphoric acid to obtain recyclable solid acid catalysts. These MNOS-based catalysts showed excellent performance in a wide range of acid-catalyzed reactions, such as Friedel-Crafts alkylation, esterification, and hydrolysis of acetates. As they are monodisperse spheres with diameters in the submicrometer range, the catalysts can be easily separated and reused. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Antisolvent Precipitation for the Synthesis of Monodisperse Mesoporous Niobium Oxide Spheres as Highly Effective Solid Acid Catalysts

KAUST Repository

Li, Cheng Chao

2012-03-20

We have developed a low-cost reaction protocol to synthesize mesoporous Nb 2O 5-based solid acid catalysts with external shape control. In the synthesis, monodisperse glycolated niobium oxide spheres (GNOS) were prepared by means of a simple antisolvent precipitation approach and subsequently converted to mesoporous niobium oxide spheres (MNOS) with a large surface area of 312m 2g -1 by means of the hydrothermal treatment. The antisolvent acetone used to obtain GNOS was recovered through distillation at high purity. The obtained mesoporous MNOS were functionalized further with sulfate anions at different temperatures or incorporated with tungstophosphoric acid to obtain recyclable solid acid catalysts. These MNOS-based catalysts showed excellent performance in a wide range of acid-catalyzed reactions, such as Friedel-Crafts alkylation, esterification, and hydrolysis of acetates. As they are monodisperse spheres with diameters in the submicrometer range, the catalysts can be easily separated and reused. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bridge Management Systems

DEFF Research Database (Denmark)

Thoft-Christensen, Palle

In this paper bridge management systems are discussed with special emphasis on management systems for reinforced concrete bridges. Management systems for prestressed concrete bridges, steel bridges, or composite bridges can be developed in a similar way....

Generation and stabilization of whey-based monodisperse naoemulsions using ultra-high pressure homogenization and small amphipathic co-emulsifier combinations

Science.gov (United States)

Ultra-high-pressure homogenization (UHPH) was used to generate monodisperse stable peanut oil nanoemulsions within a desired nanosize range (whey protein concentrate (WPC), sodium dodecyl sulfate, Triton X-100 (X100), and zwitterionic sulfobetaine-base...

Effects of Irregular Bridge Columns and Feasibility of Seismic Regularity

Science.gov (United States)

Thomas, Abey E.

2018-05-01

Bridges with unequal column height is one of the main irregularities in bridge design particularly while negotiating steep valleys, making the bridges vulnerable to seismic action. The desirable behaviour of bridge columns towards seismic loading is that, they should perform in a regular fashion, i.e. the capacity of each column should be utilized evenly. But, this type of behaviour is often missing when the column heights are unequal along the length of the bridge, allowing short columns to bear the maximum lateral load. In the present study, the effects of unequal column height on the global seismic performance of bridges are studied using pushover analysis. Codes such as CalTrans (Engineering service center, earthquake engineering branch, 2013) and EC-8 (EN 1998-2: design of structures for earthquake resistance. Part 2: bridges, European Committee for Standardization, Brussels, 2005) suggests seismic regularity criterion for achieving regular seismic performance level at all the bridge columns. The feasibility of adopting these seismic regularity criterions along with those mentioned in literatures will be assessed for bridges designed as per the Indian Standards in the present study.

Salt bridge as a gatekeeper against partial unfolding.

Science.gov (United States)

Hinzman, Mark W; Essex, Morgan E; Park, Chiwook

2016-05-01

Salt bridges are frequently observed in protein structures. Because the energetic contribution of salt bridges is strongly dependent on the environmental context, salt bridges are believed to contribute to the structural specificity rather than the stability. To test the role of salt bridges in enhancing structural specificity, we investigated the contribution of a salt bridge to the energetics of native-state partial unfolding in a cysteine-free version of Escherichia coli ribonuclease H (RNase H*). Thermolysin cleaves a protruding loop of RNase H(*) through transient partial unfolding under native conditions. Lys86 and Asp108 in RNase H(*) form a partially buried salt bridge that tethers the protruding loop. Investigation of the global stability of K86Q/D108N RNase H(*) showed that the salt bridge does not significantly contribute to the global stability. However, K86Q/D108N RNase H(*) is greatly more susceptible to proteolysis by thermolysin than wild-type RNase H(*) is. The free energy for partial unfolding determined by native-state proteolysis indicates that the salt bridge significantly increases the energy for partial unfolding by destabilizing the partially unfolded form. Double mutant cycles with single and double mutations of the salt bridge suggest that the partially unfolded form is destabilized due to a significant decrease in the interaction energy between Lys86 and Asp108 upon partial unfolding. This study demonstrates that, even in the case that a salt bridge does not contribute to the global stability, the salt bridge may function as a gatekeeper against partial unfolding that disturbs the optimal geometry of the salt bridge. © 2016 The Protein Society.

Online measurement of mental representations of complex spatial decision problems : Comparison of CNET and hard laddering

NARCIS (Netherlands)

O. Horeni (Oliver); T.A. Arentze (Theo); B.G.C. Dellaert (Benedict); H.J.P. Timmermans (Harry)

2013-01-01

textabstractThis paper introduces the online Causal Network Elicitation Technique (CNET), as a technique for measuring components of mental representations of choice tasks and compares it with the more common technique of online ‘hard’ laddering (HL). While CNET works in basically two phases, one in

Facile Synthesis of Mono-Dispersed Polystyrene (PS/Ag Composite Microspheres via Modified Chemical Reduction

Directory of Open Access Journals (Sweden)

Wen Zhu

2013-12-01

Full Text Available A modified method based on in situ chemical reduction was developed to prepare mono-dispersed polystyrene/silver (PS/Ag composite microspheres. In this approach; mono-dispersed PS microspheres were synthesized through dispersion polymerization using poly-vinylpyrrolidone (PVP as a dispersant at first. Then, poly-dopamine (PDA was fabricated to functionally modify the surfaces of PS microspheres. With the addition of [Ag(NH32]+ to the PS dispersion, [Ag(NH32]+ complex ions were absorbed and reduced to silver nanoparticles on the surfaces of PS-PDA microspheres to form PS/Ag composite microspheres. PVP acted both as a solvent of the metallic precursor and as a reducing agent. PDA also acted both as a chemical protocol to immobilize the silver nanoparticles at the PS surface and as a reducing agent. Therefore, no additional reducing agents were needed. The resulting composite microspheres were characterized by TEM, field emission scanning electron microscopy (FESEM, energy-dispersive X-ray spectroscopy (EDS, XRD, UV-Vis and surface-enhanced Raman spectroscopy (SERS. The results showed that Ag nanoparticles (NPs were homogeneously immobilized onto the PS microspheres’ surface in the presence of PDA and PVP. PS/Ag composite microspheres were well formed with a uniform and compact shell layer and were adjustable in terms of their optical property.

Microwave Synthesized Monodisperse CdS Spheres of Different Size and Color for Solar Cell Applications

Directory of Open Access Journals (Sweden)

Carlos A. Rodríguez-Castañeda

2015-01-01

Full Text Available Monodisperse CdS spheres of size of 40 to 140 nm were obtained by microwave heating from basic solutions. It is observed that larger CdS spheres were formed at lower solution pH (8.4–8.8 and smaller ones at higher solution pH (10.8–11.3. The color of CdS products changed with solution pH and reaction temperature; those synthesized at lower pH and temperature were of green-yellow color, whereas those formed at higher pH and temperature were of orange-yellow color. A good photovoltage was observed in CdS:poly(3-hexylthiophene solar cells with spherical CdS particles. This is due to the good dispersion of CdS nanoparticles in P3HT solution that led to a large interface area between the organic and inorganic semiconductors. Higher photocurrent density was obtained in green-yellow CdS particles of lower defect density. The efficient microwave chemistry accelerated the hydrolysis of thiourea in pH lower than 9 and produced monodisperse spherical CdS nanoparticles suitable for solar cell applications.

Development and validation of a nursing professionalism evaluation model in a career ladder system.

Science.gov (United States)

Kim, Yeon Hee; Jung, Young Sun; Min, Ja; Song, Eun Young; Ok, Jung Hui; Lim, Changwon; Kim, Kyunghee; Kim, Ji-Su

2017-01-01

The clinical ladder system categorizes the degree of nursing professionalism and rewards and is an important human resource tool for managing nursing. We developed a model to evaluate nursing professionalism, which determines the clinical ladder system levels, and verified its validity. Data were collected using a clinical competence tool developed in this study, and existing methods such as the nursing professionalism evaluation tool, peer reviews, and face-to-face interviews to evaluate promotions and verify the presented content in a medical institution. Reliability and convergent and discriminant validity of the clinical competence evaluation tool were verified using SmartPLS software. The validity of the model for evaluating overall nursing professionalism was also analyzed. Clinical competence was determined by five dimensions of nursing practice: scientific, technical, ethical, aesthetic, and existential. The structural model explained 66% of the variance. Clinical competence scales, peer reviews, and face-to-face interviews directly determined nursing professionalism levels. The evaluation system can be used for evaluating nurses' professionalism in actual medical institutions from a nursing practice perspective. A conceptual framework for establishing a human resources management system for nurses and a tool for evaluating nursing professionalism at medical institutions is provided.

Temperature dependence of exchange anisotropy in monodisperse cobalt nanoparticles with a cobalt oxide shell

International Nuclear Information System (INIS)

Spasova, M.; Wiedwald, U.; Farle, M.; Radetic, T.; Dahmen, U.; Hilgendorff, M.; Giersig, M.

2004-01-01

Exchange anisotropy was studied by SQUID magnetometry on an array of monodisperse colloidal nanoparticles consisting of a 7-8 nm diameter FCC Co core covered with a 2-2.5 nm thick FCC CoO shell. Temperature-dependent measurements of the exchange bias field show that the exchange anisotropy vanishes when a magnetic field was applied during cooling below 150 K. The suppression of exchange anisotropy is due to uncompensated interfacial antiferromagnetic spins

Railroad Bridges

Data.gov (United States)

Department of Homeland Security — Bridges-Rail in the United States According to The National Bridge Inspection Standards published in the Code of Federal Regulations (23 CFR 650.3), a bridge isA...

Special Fluid Viscous Dampers For The Messina Strait Bridge

International Nuclear Information System (INIS)

Colato, Gian Paolo; Infanti, Samuele; Castellano, Maria Gabriella

2008-01-01

The Messina Strait Bridge would be the world's longest suspension bridge, with a design earthquake characterised by a PGA value of 0.58 g and a distance between the ipocenter and the bridge of 15 km. Said critical structure of course would need a suitable restraint system for traffic braking loads, wind and seismic actions. Each type of load requires a specific behaviour of the restraint system, making its design a big challenge.The restraint system comprises special types of fluid viscous dampers, installed both in longitudinal and transverse direction, both at the towers and at the anchorages. In seismic conditions they behave as viscous dampers, to reduce the forces on the structural elements and the movements of the bridge deck. But in service dynamic conditions, e.g. under traffic or wind load, the devices shall behave like shock transmission units, thus preventing the longitudinal and transverse movements of the deck.FIP Industriale cooperated with the selected General Contractor, a consortium lead by Impregilo, in the design of said viscous dampers. This paper describes the main features of said devices

Symmetry-broken states in a system of interacting bosons on a two-leg ladder with a uniform Abelian gauge field

Science.gov (United States)

Greschner, S.; Piraud, M.; Heidrich-Meisner, F.; McCulloch, I. P.; Schollwöck, U.; Vekua, T.

2016-12-01

We study the quantum phases of bosons with repulsive contact interactions on a two-leg ladder in the presence of a uniform Abelian gauge field. The model realizes many interesting states, including Meissner phases, vortex fluids, vortex lattices, charge density waves, and the biased-ladder phase. Our work focuses on the subset of these states that breaks a discrete symmetry. We use density matrix renormalization group simulations to demonstrate the existence of three vortex-lattice states at different vortex densities and we characterize the phase transitions from these phases into neighboring states. Furthermore, we provide an intuitive explanation of the chiral-current reversal effect that is tied to some of these vortex lattices. We also study a charge-density-wave state that exists at 1/4 particle filling at large interaction strengths and flux values close to half a flux quantum. By changing the system parameters, this state can transition into a completely gapped vortex-lattice Mott-insulating state. We elucidate the stability of these phases against nearest-neighbor interactions on the rungs of the ladder relevant for experimental realizations with a synthetic lattice dimension. A charge-density-wave state at 1/3 particle filling can be stabilized for flux values close to half a flux quantum and for very strong on-site interactions in the presence of strong repulsion on the rungs. Finally, we analytically describe the emergence of these phases in the low-density regime, and, in particular, we obtain the boundaries of the biased-ladder phase, i.e., the phase that features a density imbalance between the legs. We make contact with recent quantum-gas experiments that realized related models and discuss signatures of these quantum states in experimentally accessible observables.

Development of a numerical model for vehicle-bridge interaction analysis of railway bridges

Science.gov (United States)

Kim, Hee Ju; Cho, Eun Sang; Ham, Jun Su; Park, Ki Tae; Kim, Tae Heon

2016-04-01

In the field of civil engineering, analyzing dynamic response was main concern for a long time. These analysis methods can be divided into moving load analysis method and moving mass analysis method, and formulating each an equation of motion has recently been studied after dividing vehicles and bridges. In this study, the numerical method is presented, which can consider the various train types and can solve the equations of motion for a vehicle-bridge interaction analysis by non-iteration procedure through formulating the coupled equations for motion. Also, 3 dimensional accurate numerical models was developed by KTX-vehicle in order to analyze dynamic response characteristics. The equations of motion for the conventional trains are derived, and the numerical models of the conventional trains are idealized by a set of linear springs and dashpots with 18 degrees of freedom. The bridge models are simplified by the 3 dimensional space frame element which is based on the Euler-Bernoulli theory. The rail irregularities of vertical and lateral directions are generated by PSD functions of the Federal Railroad Administration (FRA).

One-Particle vs. Two-Particle Crossover in Weakly Coupled Hubbard Chains and Ladders: Perturbative Renormalization Group Approach

OpenAIRE

Kishine, Jun-ichiro; Yonemitsu, Kenji

1997-01-01

Physical nature of dimensional crossovers in weakly coupled Hubbard chains and ladders has been discussed within the framework of the perturbative renormalization-group approach. The difference between these two cases originates from different universality classes which the corresponding isolated systems belong to.

Implementation of Bridge Management System on Interurban Bridge in Maluku Province

Directory of Open Access Journals (Sweden)

Erwin Marasabessy

2015-05-01

Full Text Available Bridges as transport infrastructures play a vital role in smoothing traffic flows. The success of a bridge in playing its role and serving its function depends on its management. The Directorate General of Highways of the Ministry of Public Work has used a system to manage bridges known as the Bridge Management System (BMS. The system allows a systematic plan and provides a uniform procedure for all bridge operation activities on the national and provincial level. Data from Implementation Agency of National Inter-Urban Roads of Area IX, Northern Maluku in 2011 indicates that the total length of national roads in Maluku Province is 15,238.01 M, with a total of 562 bridges. In Ambon Island, especially, there are 52 bridges totaling 1,176.25 m in length. The study was conducted at several inter-urban bridges in Maluku Province of Ambon Island: Wai Batu Merah, Wai Ruhu, Wai Lawa, Wai Yari and Wai Tua bridges. Assessment of bridge structure conditions was conducted visually to determine the conditions of the existing bridges comprehensively by referring to the Bridge Management System (BMS complemented with a computer-based Bridge Management Information System (BMIS. Condition scores for the five bridges—Wai Batu Merah, Wai Ruhu, Wai Lawa, Wai Yari, and Wai Tua, according to Bridge Management System, are 2, 1, 2, 1, and 2 respectively. The scores of the five bridges indicate that their physical condition can be categorized as good or with minor defects. Based on technical screening, the proposed treatment for Wai Batu Merah, Wai Ruhu, Wai Lawa, dan Wai Tua bridges is the rehabilitation of their sub-elements. As for the Wai Yari Bridge, the treatment will be maintained regularly. The defect repair costs are IDR 149,138,238.00, IDR 81,048,000.00, IDR 174,579,106.10, IDR 79,233,324.01 and IDR 238,323,258.60 for Wai Batu, Wai Ruhu, Wai Lawa, Wai Yari, and Wai Tua Bridges, respectively.

Charge Transport in Spiro-OMeTAD Investigated through Space-Charge-Limited Current Measurements

Science.gov (United States)

Röhr, Jason A.; Shi, Xingyuan; Haque, Saif A.; Kirchartz, Thomas; Nelson, Jenny

2018-04-01

Extracting charge-carrier mobilities for organic semiconductors from space-charge-limited conduction measurements is complicated in practice by nonideal factors such as trapping in defects and injection barriers. Here, we show that by allowing the bandlike charge-carrier mobility, trap characteristics, injection barrier heights, and the shunt resistance to vary in a multiple-trapping drift-diffusion model, a numerical fit can be obtained to the entire current density-voltage curve from experimental space-charge-limited current measurements on both symmetric and asymmetric 2 ,2',7 ,7' -tetrakis(N ,N -di-4-methoxyphenylamine)-9 ,9' -spirobifluorene (spiro-OMeTAD) single-carrier devices. This approach yields a bandlike mobility that is more than an order of magnitude higher than the effective mobility obtained using analytical approximations, such as the Mott-Gurney law and the moving-electrode equation. It is also shown that where these analytical approximations require a temperature-dependent effective mobility to achieve fits, the numerical model can yield a temperature-, electric-field-, and charge-carrier-density-independent mobility. Finally, we present an analytical model describing trap-limited current flow through a semiconductor in a symmetric single-carrier device. We compare the obtained charge-carrier mobility and trap characteristics from this analytical model to the results from the numerical model, showing excellent agreement. This work shows the importance of accounting for traps and injection barriers explicitly when analyzing current density-voltage curves from space-charge-limited current measurements.

Plasma-assisted synthesis of monodispersed and robust Ruthenium ultrafine nanocatalysts for organosilane oxidation and oxygen evolution reactions

NARCIS (Netherlands)

Gnanakumar, E.S.; Ng, W.; Filiz, B.C.; Rothenberg, G.; Wang, S.; Xu, H.; Pastor-Pérez, L.; Pastor-Blas, M.M.; Sepúlveda-Escribano, A.; Yan, N.; Shiju, N.R.

2017-01-01

We report a facile and general approach for preparing ultrafine ruthenium nanocatalysts by using a plasma-assisted synthesis at <100 °C. The resulting Ru nanoparticles are monodispersed (typical size 2 nm) and remain that way upon loading onto carbon and TiO2 supports. This gives robust catalysts

Production and characterization of monodisperse uranium particles for nuclear safeguards applications

International Nuclear Information System (INIS)

Knott, Alexander

2016-01-01

Environmental sampling is a very effective measure to detect undeclared nuclear activities. Generally, samples are taken as swipe samples on cotton. These swipes contain minute quantities of particulates which have an inherent signature of their production and release scenario. These inspection samples are assessed for their morphology, elemental composition and their isotopic vectors. Mass spectrometry plays a crucial role in determining the isotopic ratios of uranium. Method validation and instrument calibration with well-characterized quality control (QC)-materials, reference materials (RMs) and certified reference materials (CRMs) ensures reliable data output. Currently, the availability of suitable well defined microparticles containing uranium and plutonium reference materials is very limited. Primarily, metals, oxides and various uranium and plutonium containing solutions are commercially available. Therefore, the IAEA's Safeguards Analytical Services (SGAS) cooperates with the Institute of Nuclear Waste Management and Reactor Safety (IEK-6) at the Forschungszentrum Juelich GmbH in a joint task entitled ''Production of Particle Reference Materials''. The work presented in this thesis has been partially funded by the IAEA, Forschungszentrum Juelich GmbH and the Federal Ministry of Economic Affairs and Energy (BMWi) through the ''Joint Program on the Technical Development and Further Improvement of IAEA Safeguards between the Government of the Federal Republic of Germany and the IAEA''. The first step towards monodisperse microparticles was the development of pure uranium oxide particles made from certified reference materials. The focus of the dissertation is (1) the implementation of a working setup to produce monodisperse uranium oxide particles and (2) the characterization of these particles towards the application as QC-material. Monodisperse uranium oxide particles were produced by spray pyrolysis. It was demonstrated that the particle size can be

Production and characterization of monodisperse uranium particles for nuclear safeguards applications

Energy Technology Data Exchange (ETDEWEB)

Knott, Alexander

2016-07-01

Environmental sampling is a very effective measure to detect undeclared nuclear activities. Generally, samples are taken as swipe samples on cotton. These swipes contain minute quantities of particulates which have an inherent signature of their production and release scenario. These inspection samples are assessed for their morphology, elemental composition and their isotopic vectors. Mass spectrometry plays a crucial role in determining the isotopic ratios of uranium. Method validation and instrument calibration with well-characterized quality control (QC)-materials, reference materials (RMs) and certified reference materials (CRMs) ensures reliable data output. Currently, the availability of suitable well defined microparticles containing uranium and plutonium reference materials is very limited. Primarily, metals, oxides and various uranium and plutonium containing solutions are commercially available. Therefore, the IAEA's Safeguards Analytical Services (SGAS) cooperates with the Institute of Nuclear Waste Management and Reactor Safety (IEK-6) at the Forschungszentrum Juelich GmbH in a joint task entitled ''Production of Particle Reference Materials''. The work presented in this thesis has been partially funded by the IAEA, Forschungszentrum Juelich GmbH and the Federal Ministry of Economic Affairs and Energy (BMWi) through the ''Joint Program on the Technical Development and Further Improvement of IAEA Safeguards between the Government of the Federal Republic of Germany and the IAEA''. The first step towards monodisperse microparticles was the development of pure uranium oxide particles made from certified reference materials. The focus of the dissertation is (1) the implementation of a working setup to produce monodisperse uranium oxide particles and (2) the characterization of these particles towards the application as QC-material. Monodisperse uranium oxide particles were produced by spray pyrolysis. It was

Investigation of Aerodynamic Interference between Twin Deck Bridges

Energy Technology Data Exchange (ETDEWEB)

Sitek, M. A. [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division. Transportation Research and Analysis Computing Center (TRACC); Bojanowski, C. [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division. Transportation Research and Analysis Computing Center (TRACC); Lottes, S. A. [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division. Transportation Research and Analysis Computing Center (TRACC)

2016-05-01

of various cross-sections, gap-to-width ratios, wind speed and direction using three-dimensional CFD simulations. After verification with wind tunnel test results, this type of analysis could become a powerful tool for future designs as well as for monitoring of existing bridges.

Toxicity of inhaled 238PuO2 in Beagle dogs: A. Monodisperse 1.5 μm AMAD particles. B. Monodisperse 3.0 μm particles. XV

International Nuclear Information System (INIS)

Mewhinney, J.A.; Gillett, N.A.; Muggenburg, B.A.; Hahn, F.F.; Diel, J.H.; Mauderly, J.L.; Boecker, B.B.; McClellan, R.O.

1988-01-01

Beagle dogs inhaled one of two sizes of monodisperse aerosols of 238 PuO 2 that resulted in graded levels of 238 Pu in the lung. All dogs are being studied for their life span. One hundred and thirty-seven dogs that had initial lung burdens ranging from 0.01 to 1.5 μCi 238 Pu/kg body weight (0.37 to 56 kBq/kg) have died, 8 with radiation pneumonitis and pulmonary fibrosis, 8 with lung tumors, 88 with bone tumors, 10 with liver tumors, and 25 of miscellaneous causes. Eighteen control dogs have died. Observations are being continued on 8 exposed and 6 control dogs alive at 4577-5274 days after exposure. (author)

Long-term bridge performance high priority bridge performance issues.

Science.gov (United States)

2014-10-01

Bridge performance is a multifaceted issue involving performance of materials and protective systems, : performance of individual components of the bridge, and performance of the structural system as a whole. The : Long-Term Bridge Performance (LTBP)...

Phase dynamics of a Josephson junction ladder driven by modulated currents

International Nuclear Information System (INIS)

Kawaguchi, T.

2011-01-01

Phase dynamics of disordered Josephson junction ladders (JJLs) driven by external currents which are spatially and temporally modulated is studied using a numerical simulation based on a random field XY model. This model is considered theoretically as an effective model of JJLs with structural disorder in a magnetic field. The spatiotemporal modulation of external currents causes peculiar dynamical effects of phases in the system under certain conditions, such as the directed motion of phases and the mode-locking in the absence of dc currents. We clarify the details of effects of the spatiotemporal modulation on the phase dynamics.

Magnetic field effects of tow-leg Heisenberg antiferromagnetic ladders: Thermodynamic properties

International Nuclear Information System (INIS)

Wang Xiaoqun; Yu Lu

2000-05-01

Using the recently developed transfer-matrix renormalization group method, we have studied the thermodynamic properties of two-leg antiferromagnetic ladders in the magnetic field. Based on different behavior of magnetization, we found disordered spin liquid, Luttinger liquid, spin-polarized phases and a classical regime depending on magnetic field and temperature. Our calculations in Luttinger liquid regime suggest that both the divergence of the NMR relaxation rate and the anomalous specific heat behavior observed on Cu 2 (C 5 H 12 N 2 ) 2 Cl 4 are due to quasi-one-dimensional effect rather than three-dimensional ordering. (author)

Cable-stayed bridge No. 1 Hikihara bridge'' ( Karauko bridge'') for Kinki construction bureau, ministry of construction. Kensetsusho kinki chiho kensetsukyoku (Hikihara 1 gobashi (Karauko ohashi))no shiko

Energy Technology Data Exchange (ETDEWEB)

1991-11-01

This paper summarizes the design, fabrication and erection of a back-anchor integrated single span cable suspension bridge (178 m long and 9.7 m wide) constructed over an ordinary road crossing a reservoir. This type of structure was adopted because the locational condition does not allow a bridge pier to be erected in the center of the pond, and the topography in the construction starting side has steep slopes and many places having fragile ground beds. This bridge employed precast floor plates using the Compo-Slab (manufactured by Ishikawajima Building Material Company). Main points which require attentions are listed in designing and fabricating the main towers (48 m high), main girders, and cables, as well as fabricating the precast cast floor plates (a panel has a length of 9.7 m, maximum width of 2 m, and maximum weight of 10 tons). The main towers were erected using 160-tf truck cranes, and the main girders were erected by the overhang method using 20-tf gate-type travel cranes. 3 refs., 14 figs.

Observations on the bony bridging of the jugular foramen in man.

Science.gov (United States)

Dodo, Y

1986-02-01

The anatomical nature and pattern of incidence of bony bridging of the jugular foramen was investigated using 64 fetal crania aged nine months to term and 222 adult crania of Japanese. In addition, the region of the jugular foramen of an adult cadaver was carefully dissected in order to clarify the relationship between the cranial nerves passing through the jugular foramen and the intrajugular processes of the jugular foramen. The general conclusions concerning the anatomical nature of the bony bridging of the jugular foramen were as follows. (1) The intrajugular process of the temporal bone is situated posterior to the triangular depression (as described in Gray's Anatomy) of the petrous part. (2) The bony bridging of the jugular foramen is established by the contact of the intrajugular process of the temporal bone with the bony process of the occipital bone projecting either from just above the hypoglossal canal (Type I) or from posterior to the hypoglossal canal (Type III). (3) If both the processes of the occipital bone reach the intrajugular process of the temporal bone simultaneously, the jugular foramen is divided into three compartments. (4) In the case of Type I bridging, the anteromedial compartment transmits the glossopharyngeal nerve, while the posterolateral compartment gives passage to the vagus nerve, the accessory nerve and the internal jugular vein. (5) In the case of Type II bridging, the anteromedial compartment contains the glossopharyngeal, vagus and accessory nerves, and the posterolateral compartment transmits the internal jugular vein. (6) When tripartite division of the jugular foramen occurs, the anteromedial compartment transmits the glossopharyngeal nerve, the middle compartment contains the vagus and accessory nerves, and the posterolateral compartment transmits the internal jugular vein. Concerning the pattern of incidence of jugular foramen bridging in the Japanese fetal and adult cranial series, this is similar to that of the bony

47 CFR 80.163 - Operator requirements of the Bridge-to-Bridge Act.

Science.gov (United States)

2010-10-01

... 47 Telecommunication 5 2010-10-01 2010-10-01 false Operator requirements of the Bridge-to-Bridge... Requirements § 80.163 Operator requirements of the Bridge-to-Bridge Act. Each ship subject to the Bridge-to-Bridge Act must have on board a radio operator who holds a restricted radiotelephone operator permit or...

Bridge health monitoring metrics : updating the bridge deficiency algorithm.

Science.gov (United States)

2009-10-01

As part of its bridge management system, the Alabama Department of Transportation (ALDOT) must decide how best to spend its bridge replacement funds. In making these decisions, ALDOT managers currently use a deficiency algorithm to rank bridges that ...

Long-Term Effects of Super Heavy-Weight Vehicles on Bridges

OpenAIRE

Wood, Scott M.; Akinci, Necip Onder; Liu, Judy; Bowman, Mark D

2007-01-01

A permit truck which exceeds the predefined limit of 108 kips is defined as a superload in Indiana. This study was conducted to examine the long-term effects of superload trucks on the performance of typical slab-on-girder bridges and to assess the likelihood of causing immediate damage. Typical steel and prestressed concrete slab-on-girder type bridges were analyzed using both beam line analysis and detailed finite element models. Furthermore, one prestressed concrete bridge and one steel br...

Extension of POA based on Fiber Element to Girder Bridge

International Nuclear Information System (INIS)

Li Zhenxin; Qiang Shizhong

2010-01-01

Because of its main advantage of simplicity, practicality, lower computational cost and relative good results Pushover analysis (POA) has become an effective analytical tool during the last decade for the seismic assessment of buildings. But such work on bridges has been very limited. Hence, the aim of this study is to adapt POA for nonlinear seismic analysis of girder bridges, and investigate its applicability in the case of an existing river-spanning approach bridge. To three different types bridge models the nonlinear POA, which adopts fiber model nonlinear beam-column element based on flexibility approach, with return period about 2500 years is carried out. It can be concluded that POA is applicable for bridges, with some shortcomings associated with the method in general, even when it is applied for buildings. Finally the applicable selection for monitoring point and lateral load pattern is suggested according to dynamic characteristic of girder bridges.

Linear theory on temporal instability of megahertz faraday waves for monodisperse microdroplet ejection.

Science.gov (United States)

Tsai, Shirley C; Tsai, Chen S

2013-08-01

A linear theory on temporal instability of megahertz Faraday waves for monodisperse microdroplet ejection based on mass conservation and linearized Navier-Stokes equations is presented using the most recently observed micrometer- sized droplet ejection from a millimeter-sized spherical water ball as a specific example. The theory is verified in the experiments utilizing silicon-based multiple-Fourier horn ultrasonic nozzles at megahertz frequency to facilitate temporal instability of the Faraday waves. Specifically, the linear theory not only correctly predicted the Faraday wave frequency and onset threshold of Faraday instability, the effect of viscosity, the dynamics of droplet ejection, but also established the first theoretical formula for the size of the ejected droplets, namely, the droplet diameter equals four-tenths of the Faraday wavelength involved. The high rate of increase in Faraday wave amplitude at megahertz drive frequency subsequent to onset threshold, together with enhanced excitation displacement on the nozzle end face, facilitated by the megahertz multiple Fourier horns in resonance, led to high-rate ejection of micrometer- sized monodisperse droplets (>10(7) droplets/s) at low electrical drive power (<;1 W) with short initiation time (<;0.05 s). This is in stark contrast to the Rayleigh-Plateau instability of a liquid jet, which ejects one droplet at a time. The measured diameters of the droplets ranging from 2.2 to 4.6 μm at 2 to 1 MHz drive frequency fall within the optimum particle size range for pulmonary drug delivery.

47 CFR 80.309 - Watch required by the Bridge-to-Bridge Act.

Science.gov (United States)

2010-10-01

... 47 Telecommunication 5 2010-10-01 2010-10-01 false Watch required by the Bridge-to-Bridge Act. 80... Safety Watches § 80.309 Watch required by the Bridge-to-Bridge Act. In addition to the watch requirement contained in § 80.148, all vessels subject to the Bridge-to-Bridge Act must keep a watch on the designated...

A novel bridge coupler for SSC coupled cavity linac

International Nuclear Information System (INIS)

Yao, C.G.; Chang, C.R.; Funk, W.

1992-01-01

A novel magnetically coupled multi-cavity bridge coupler is proposed for SSC Coupled-Cavity-Linac (CCL). The bridge coupler is a five cell disc-loaded waveguide with a small central aperture used for measurement and two large curved coupling slots near the edge on each disc. The two coupling slots on the adjacent disc are rotated 90 degrees in orientation to reduce the direct coupling. This type of structure is capable of producing very large coupling (>10% in our longest bridge coupler). Also because of the small opening on the discs, the high-order-modes are very far (> 300 MHz) above the operating mode. Thus for long bridge couplers, the magnetic coupled structure should provide maximum coupling with minimum mode mixing problems. In this paper both physics and engineering issues of this new bridge coupler are presented. (Author) 5 refs., 2 tabs., 6 figs

Towers and ladders: Infinite parameter symmetries in Kaluza-Klein theories

International Nuclear Information System (INIS)

Aulakh, C.S.

1984-05-01

We introduce a class of infinite dimensional algebras with a 'generalized loop structure' by considering the global symmetries of the four dimensional Lagrangian obtained by compactifying general relativity coupled to Yang-Mills in six dimensions down to M 4 xS 2 . The generalization to arbitrary dimensions is then obvious. We show by explicit construction that such algebras possess an infinite number of finite sub-algebras. Among which, for the six dimensional case, is so(1,3) realized on S 2 with vanishing Casimir invariants. This so(1,3) may be interpreted, in accord with a previous conjecture of Salam and Strathdee [Ann. Phys. 141, 316(1982)], as the 'ladder' symmetry for the Kaluza-Klein towers. (author)

Filament to filament bridging and its influence on developing high critical current density in multifilamentary Bi2Sr2CaCu2Ox round wires

International Nuclear Information System (INIS)

Shen, T; Jiang, J; Kametani, F; Trociewitz, U P; Larbalestier, D C; Schwartz, J; Hellstrom, E E

2010-01-01

Increasing the critical current density (J c ) of the multifilamentary round wire Ag/Bi 2 Sr 2 CaCu 2 O x (2212) requires understanding its complicated microstructure, in which extensive bridges between filaments are prominent. In this first through-process quench study of 2212 round wire, we determined how its microstructure develops during a standard partial-melt process and how filament bridging occurs. We found that filaments can bond together in the melt state. As 2212 starts to grow on subsequent cooling, we observed that two types of 2212 bridges form. One type, which we call Type-A bridges, forms within filaments that bonded in the melt; Type-A bridges are single grains that span multiple bonded filaments. The other type, called Type-B bridges, form between discrete filaments through 2212 outgrowths that penetrate into the Ag matrix and intersect with other 2212 outgrowths from adjacent filaments. We believe the ability of these two types of bridges to carry inter-filament current is intrinsically different: Type-A bridges are high- J c inter-filament paths whereas Type-B bridges contain high-angle grain boundaries and are typically weak linked. Slow cooling leads to more filament bonding, more Type-A bridges and a doubling of J c without changing the flux pinning. We suggest that Type-A bridges create a 3D current flow that is vital to developing high J c in multifilamentary 2212 round wire.

Field performance of timber bridges. 7, Connell Lake stress-laminated deck bridge

Science.gov (United States)

L. E. Hislop; M. A. Ritter

The Connell Lake bridge was constructed in early 1991 on the Tongass National Forest, Alaska, as a demonstration bridge under the Timber Bridge Initiative. The bridge is a stress-laminated deck structure with an approximate 36-ft length and 18-ft width and is the first known stress-laminated timber bridge constructed in Alaska. Performance of the bridge was monitored...

Studies toward brevisulcenal F via convergent strategies for marine ladder polyether synthesis.

Science.gov (United States)

Katcher, Matthew; Jamison, Timothy F

2018-03-15

Shortly after the initial isolation of marine ladder polyether natural products, biomimetic epoxide-opening cascade reactions were proposed as an efficient strategy for the synthesis of these compounds. However, difficulties in assembling the cascade precursors have limited the realization of these cascades. In this report, we describe strategies that provide convergent access to cascade precursors via regioselective allylation and efficient fragment coupling. We then investigate epoxide-opening cascades promoted by strong bases for the formation of fused tetrahydropyrans. These strategies are evaluated in the context of the synthesis of rings CDEFG of brevisulcenal F.

Bridge Failure Due to Inadequate Design of Bed Protection

Science.gov (United States)

Gupta, Yogita; Kaur, Suneet; Dindorkar, Nitin

2017-12-01

The shallow foundation is generally provided on non-erodible strata or where scour depth is less. It is also preferable for low perennial flow or standing water condition. In the present case study shallow foundation is adopted for box type bridge. The total length of the bridge is 132.98 m, consisting of eight unit of RCC box. Each unit is composed of three cell box. The bottom slab of box unit is acted as raft foundation, founded 500 mm below ground level. River bed protection work is provided on both upstream and downstream side along the whole length of the bridge as it is founded above scour level. The bridge collapsed during the monsoon just after two years of service. The present paper explains the cause of failure. This study on failure of the bridge illustrates the importance of bridge inspection before and after monsoon period and importance of the timely maintenance. Standard specifications of Indian Road Congress for the river bed protection work are also included.

Imaging of DNA Ultrafine Bridges in Budding Yeast.

Science.gov (United States)

Quevedo, Oliver; Lisby, Michael

2018-01-01

DNA ultrafine bridges (UFBs) are a type of chromatin-free DNA bridges that connect sister chromatids in anaphase and pose a threat to genome stability. However, little is known about the origin of these structures, and how they are sensed and resolved by the cell. In this chapter, we review tools and methods for studying UFBs by fluorescence microscopy including chemical and genetic approaches to induce UFBs in the model organism Saccharomyces cerevisiae.

Imaging of DNA Ultrafine Bridges in Budding Yeast

DEFF Research Database (Denmark)

Quevedo Rodriguez, Oliver; Lisby, Michael

2018-01-01

DNA ultrafine bridges (UFBs) are a type of chromatin-free DNA bridges that connect sister chromatids in anaphase and pose a threat to genome stability. However, little is known about the origin of these structures, and how they are sensed and resolved by the cell. In this chapter, we review tools...... and methods for studying UFBs by fluorescence microscopy including chemical and genetic approaches to induce UFBs in the model organism Saccharomyces cerevisiae....

Design and construction of the Natorigawa Bridge; Natorigawa kyoryo no sekkei/seko

Energy Technology Data Exchange (ETDEWEB)

Murai, Y.; Oba, M.; Omurata, Y. [JR East Japan Railway Co., Tokyo (Japan); Miyauchi, M.; Iwasaki, I. [Taisei Corp., Tokyo (Japan)

1997-03-31

The Natorigawa Bridge is reconstructed. Out of the reconstruction work, a report is made mainly on the design of the superstructure work of the PC panel-stayed bridge and the details of the work. In selecting bridge type, PC simple through beam bridge, steel trussed bridge, PC cable-stayed bridge, and PC panel-stayed bridge are compared, and a 2-span continuous PC panel-stayed bridge is adopted. Its appearance resembles that of the cable-stayed bridge, but the structure resembles a girder bridge. The appropriate span length is the intermediate range between those of the girder bridge and the cable-stayed bridge. Its trafficability is excellent with little deformation by the running of trains because the main beam, diagonal panel, and the main tower are connected rigidly to provide high rigidity of the entire bridge. PRC structure is employed in consideration of the restriction to beam height and economical efficiency. Analyses by a FEM model using two dimensional plane elements and by a few plane frame models as well as comparison of sectional force are performed for this bridge, and a proper plane model is selected. Substructure work, superstructure work and measurement work are described. 3 refs., 16 figs., 6 tabs.

Unique Reversible Crystal-to-Crystal Phase Transition – Structural and Functional Properties of Fused Ladder Thienoarenes

KAUST Repository

Abe, Yuichiro

2017-08-15

Donor-acceptor type molecules based on fused ladder thienoarenes, indacenodithiophene (IDT) and dithienocyclopenta-thienothiophene (DTCTT), coupled with benzothiadiazole, are prepared and their solid-state structures are investigated. They display a rich variety of solid phases ranging from amorphous glass states to crystalline states, upon changes in the central aromatic core and side group structures. Most notably, the DTCTT-based derivatives showed reversible crystal-to-crystal phase transitions in heating and cooling cycles. Unlike what has been seen in π−conjugated molecules variable temperature XRD revealed that structural change occurs continuously during the transition. A columnar self-assembled structure with slip-stacked π−π interaction is proposed to be involved in the solid-state. This research provides the evidence of unique structural behavior of the DTCTT-based molecules through the detailed structural analysis. This unique structural transition paves the way for these materials to have self-healing of crystal defects, leading to improved optoelectronic properties.

Unique Reversible Crystal-to-Crystal Phase Transition – Structural and Functional Properties of Fused Ladder Thienoarenes

KAUST Repository

Abe, Yuichiro; Savikhin, Victoria; Yin, Jun; Grimsdale, Andrew C.; Soci, Cesare; Toney, Michael F.; Lam, Yeng Ming

2017-01-01

Donor-acceptor type molecules based on fused ladder thienoarenes, indacenodithiophene (IDT) and dithienocyclopenta-thienothiophene (DTCTT), coupled with benzothiadiazole, are prepared and their solid-state structures are investigated. They display a rich variety of solid phases ranging from amorphous glass states to crystalline states, upon changes in the central aromatic core and side group structures. Most notably, the DTCTT-based derivatives showed reversible crystal-to-crystal phase transitions in heating and cooling cycles. Unlike what has been seen in π−conjugated molecules variable temperature XRD revealed that structural change occurs continuously during the transition. A columnar self-assembled structure with slip-stacked π−π interaction is proposed to be involved in the solid-state. This research provides the evidence of unique structural behavior of the DTCTT-based molecules through the detailed structural analysis. This unique structural transition paves the way for these materials to have self-healing of crystal defects, leading to improved optoelectronic properties.

Controllable 5-sulfosalicylic acid assisted solvothermal synthesis of monodispersed superparamagnetic Fe{sub 3}O{sub 4} nanoclusters with tunable size

Energy Technology Data Exchange (ETDEWEB)

Wang, Wentao [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China); Tang, Bingtao, E-mail: tangbt@dlut.edu.cn [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China); Wu, Suli; Gao, Zhanming; Ju, Benzhi [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China); Teng, Xiaoxu [School of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing 408100 (China); Zhang, Shufen [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)

2017-02-01

Monodispersed Fe{sub 3}O{sub 4} nanoclusters were synthesized in a one-pot solvothermal route with 5-sulfosalicylic acid (SSA) as the functional ligand in a mixed-solvent system of diethylene glycol/ethylene glycol (DEG/EG). Nucleation and aggregation growth model was responsible for the formation of secondary structure of the clusters. In the process, the size of the clusters can be effectively controlled by varying the amounts of SSA and the volume ratio of DEG/EG. The nanoclusters exhibited superparamagnetic properties with high saturation magnetization value of about 68.7 emu g{sup −1} at room temperature. The water-soluble small-molecule SSA grafted on the surface of Fe{sub 3}O{sub 4} nanocrystals rendered the superparamagnetic clusters dispersible in water, which is crucial for potential applications in biomedical fields. - Graphical abstract: 5-sulfosalicylic acid assisted solvothermal synthesis of monodispersed superparamagnetic Fe{sub 3}O{sub 4} nanoclusters with tunable size by a mixed-solvent system of DEG/EG. - Highlights: • Monodispersed Fe{sub 3}O{sub 4} nanoclusters were synthesized in a one-pot 5-sulfosalicylic acid assisted solvothermal route. • The size of the clusters are tunable by varying the amounts of 5-sulfosalicylic acid and the volume ratio of DEG/EG. • The nanoclusters exhibited superparamagnetic properties with high saturation magnetization value. • The 5-sulfosalicylic acid grafted Fe{sub 3}O{sub 4} nanoclusters can be dispersed in water.

Monodisperse gold-palladium alloy nanoparticles and their composition-controlled catalysis in formic acid dehydrogenation under mild conditions.

Science.gov (United States)

Metin, Önder; Sun, Xiaolian; Sun, Shouheng

2013-02-07

Monodisperse 4 nm AuPd alloy nanoparticles with controlled composition were synthesized by co-reduction of hydrogen tetrachloroaurate(III) hydrate and palladium(II) acetylacetonate with a borane-morpholine complex in oleylamine. These NPs showed high activity (TOF = 230 h(-1)) and stability in catalyzing formic acid dehydrogenation and hydrogen production in water at 50 °C without any additives.

Standard plans for timber bridge superstructures

Science.gov (United States)

James P. Wacker; Matthew S. Smith

2001-01-01

These standardized bridge plans are for superstructures consisting of treated timber. Seven superstructure types are includes: five longitudinal and two transverse deck systems. Both HS520 and HS25 loadings are included, along with L/360 and L/500 deflection criteria.

High Performance Affinity Chromatography of Antithrombin III Based on Monodisperse Poly (glycidyl methacrylate) Beads

Institute of Scientific and Technical Information of China (English)

无

2001-01-01

A new approach for the separation of antithrombin III with high performance affinity chromatography (HPAC) was described. A novel monodisperse,non-porous,cross-linked poly (glycidyl methacrylate) beads (PGMA) were used as the affinity support. With the water-soluble carbodiimide,heparin was linked covalently to amino-PGMA-beads,which was prepared by amination of PGMA. The adsorbent obtained exhibits high binding activity to antithrombin III (ATIII),good resolution and excellent mechanical properties and can be used under high flow rate.

Generation of monodisperse cell-sized microdroplets using a centrifuge-based axisymmetric co-flowing microfluidic device.

Science.gov (United States)

Yamashita, Hitoyoshi; Morita, Masamune; Sugiura, Haruka; Fujiwara, Kei; Onoe, Hiroaki; Takinoue, Masahiro

2015-04-01

We report an easy-to-use generation method of biologically compatible monodisperse water-in-oil microdroplets using a glass-capillary-based microfluidic device in a tabletop mini-centrifuge. This device does not require complicated microfabrication; furthermore, only a small sample volume is required in experiments. Therefore, we believe that this method will assist biochemical and cell-biological experiments. Copyright © 2014 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

Evaluation of Summer Bridge Programs

Science.gov (United States)

Garcia, Lisa D.; Paz, Chiara C.

2009-01-01

Many colleges and universities in the United States offer summer programs for their incoming students. While programs are structured and administered in a variety of ways and target various student populations, the most common type of summer bridge program aims to serve historically underrepresented students and students of low socioeconomic…

Fault ride-through enhancement of fixed speed wind turbine using bridge-type fault current limiter

Directory of Open Access Journals (Sweden)

Mostafa I. Marei

2016-05-01

Full Text Available The interaction between wind energy turbines and the grid results in two main problems, increasing the short-circuit level and reducing the Fault Ride-Through (FRT capability during faults. The objective of this paper is to solve these problems, for fixed speed Wind Energy Systems (WECS, utilizing the bridge-type Fault Current Limiter (FCL with a discharging resistor. A simple cascaded control system is proposed for the FCL to regulate the terminal voltage of the generator and limit the current. The system is simulated on PSCAD/EMTDC software to evaluate the dynamic performance of the proposed WECS compensated by FCL. The simulation results show the potentials of the FCL as a simple and effective method for solving grid interconnection problems of WECS.

Communication: An exact bound on the bridge function in integral equation theories.

Science.gov (United States)

Kast, Stefan M; Tomazic, Daniel

2012-11-07

We show that the formal solution of the general closure relation occurring in Ornstein-Zernike-type integral equation theories in terms of the Lambert W function leads to an exact relation between the bridge function and correlation functions, most notably to an inequality that bounds possible bridge values. The analytical results are illustrated on the example of the Lennard-Jones fluid for which the exact bridge function is known from computer simulations under various conditions. The inequality has consequences for the development of bridge function models and rationalizes numerical convergence issues.

RESEARCH OF BRIDGE STRUCTURE VIBRATION CHARACTERISTICS

Directory of Open Access Journals (Sweden)

V.P. Babak

2005-02-01

Full Text Available  Bridge structure test results with using different types of dynamic force have been considered. It has been shown, that the developed technique of registering and processing vibration signals allows obtaining thin spectrum structure. The analysis of its change that is defined by the type of structure loading applied has been carried out. Key parameters of the vibration signals registered have been defined.

Biotemplate synthesis of monodispersed iron phosphate hollow microspheres

International Nuclear Information System (INIS)

Cao Feng; Li Dongxu

2010-01-01

Monodispersed iron phosphate hollow microspheres with a high degree of crystallization were prepared through a facile in situ deposition method using rape pollen grains as a biotemplate. The functional group on the surface of the pollen grains could adsorb Fe 3+ , which provided the nucleation sites for growth of iron phosphate nanoparticles. After being sintered at 600 deg. C for 10 h, the pollen grains were removed and iron phosphate hollow microspheres were obtained. A scanning electron microscope and x-ray diffraction were applied to characterize the morphology and crystalline structure of the pollen grains, iron phosphate-coated pollen grains and iron phosphate hollow microspheres. Differential scanning calorimetry and thermogravity analyses were performed to investigate the thermal behavior of the iron phosphate-coated pollen grains during the calcinations. Energy dispersive spectroscopy and Fourier transform infrared spectroscopy were utilized to investigate the interaction between the pollen grains and iron phosphate. The effect of the pollen wall on the surface morphology of these iron phosphate hollow microspheres was also proven in this work.