Selected soil thermal conductivity models
Directory of Open Access Journals (Sweden)
Rerak Monika
2017-01-01
Full Text Available The paper presents collected from the literature models of soil thermal conductivity. This is a very important parameter, which allows one to assess how much heat can be transferred from the underground power cables through the soil. The models are presented in table form, thus when the properties of the soil are given, it is possible to select the most accurate method of calculating its thermal conductivity. Precise determination of this parameter results in designing the cable line in such a way that it does not occur the process of cable overheating.
Conductive thermal modeling of Wyoming geothermal systems
Energy Technology Data Exchange (ETDEWEB)
Heasler, H.P.; Ruscetta, C.A.; Foley, D. (eds.)
1981-05-01
A summary of techniques used by the Wyoming Geothermal Resource Assessment Group in defining low-temperature hydrothermal resource areas is presented. Emphasis is placed on thermal modeling techniques appropriate to Wyoming's geologic setting. Thermal parameters discussed include oil-well bottom hole temperatures, heat flow, thermal conductivity, and measured temperature-depth profiles. Examples of the use of these techniques are from the regional study of the Bighorn Basin and two site specific studies within the Basin.
Homogenized thermal conduction model for particulate foods
Energy Technology Data Exchange (ETDEWEB)
Chinesta, Francisco [Laboratoire de mecanique des systemes et des procedes, Ecole nationale superieure d' arts et metiers, 151 boulevard de l' Hopital, 75013, Paris (France); Torres, Rafael [Departamento de Ingenieria Mecanica, Universidad Politecnica de Valencia, Camino de Vera s/n. 46071, Valencia (Spain); Ramon, Antonio [AIMPLAS, Gustave Eiffel 4, 46980 Paterna, Valencia (Spain); Rodrigo, Mari Carmen; Rodrigo, Miguel [Instituto de Agroquimica y Tecnologia de Alimentos, Consejo Superior de Investigaciones Cientificas, Apartado de correos 73, 46100, Burjasot (Spain)
2002-12-01
This paper deals with the definition of an equivalent thermal conductivity for particulate foods. An homogenized thermal model is used to asses the effect of particulate spatial distribution and differences in thermal conductivities. We prove that the spatial average of the conductivity can be used in an homogenized heat transfer model if the conductivity differences among the food components are not very large, usually the highest conductivity ratio between the foods components is lower than 5. In the general case we propose to use a standard spatial homogenization procedure. Although the heterogeneity give rise to an anisotropic heat transfer behaviour, this effect is negligible when the food particles are randomly distributed. When we use pre-mixed particulate foods a statistical average can be defined from a small number of possible particle arrangements. (authors)
Thermal Conductivity Coefficient from Microscopic Models
Nemakhavhani, T E
2016-01-01
Thermal conductivity of hadron matter is studied using a microscopic transport model, which will be used to simulate ultra-relativistic heavy ion collisions at different energy densities, namely the Ultra-relativistic Quantum Molecular Dynamics (UrQMD). The molecular dynamics simulation is performed for a system of light mesons species (pion, rho, kaon) in a box with periodic boundary conditions. The equilibrium state is investigated by studying chemical equilibrium and thermal equilibrium of the system. Particle multiplicity equilibrates with time, and the energy spectra of different light mesons species have the same slopes and common temperatures when thermal equilibrium is reached. Thermal conductivity transport coefficient is calculated from the heat current - current correlations using the Green-Kubo relations.
Model calculation of thermal conductivity in antiferromagnets
Energy Technology Data Exchange (ETDEWEB)
Mikhail, I.F.I., E-mail: ifi_mikhail@hotmail.com; Ismail, I.M.M.; Ameen, M.
2015-11-01
A theoretical study is given of thermal conductivity in antiferromagnetic materials. The study has the advantage that the three-phonon interactions as well as the magnon phonon interactions have been represented by model operators that preserve the important properties of the exact collision operators. A new expression for thermal conductivity has been derived that involves the same terms obtained in our previous work in addition to two new terms. These two terms represent the conservation and quasi-conservation of wavevector that occur in the three-phonon Normal and Umklapp processes respectively. They gave appreciable contributions to the thermal conductivity and have led to an excellent quantitative agreement with the experimental measurements of the antiferromagnet FeCl{sub 2}. - Highlights: • The Boltzmann equations of phonons and magnons in antiferromagnets have been studied. • Model operators have been used to represent the magnon–phonon and three-phonon interactions. • The models possess the same important properties as the exact operators. • A new expression for the thermal conductivity has been derived. • The results showed a good quantitative agreement with the experimental data of FeCl{sub 2}.
Multiscale Modeling of UHTC: Thermal Conductivity
Lawson, John W.; Murry, Daw; Squire, Thomas; Bauschlicher, Charles W.
2012-01-01
We are developing a multiscale framework in computational modeling for the ultra high temperature ceramics (UHTC) ZrB2 and HfB2. These materials are characterized by high melting point, good strength, and reasonable oxidation resistance. They are candidate materials for a number of applications in extreme environments including sharp leading edges of hypersonic aircraft. In particular, we used a combination of ab initio methods, atomistic simulations and continuum computations to obtain insights into fundamental properties of these materials. Ab initio methods were used to compute basic structural, mechanical and thermal properties. From these results, a database was constructed to fit a Tersoff style interatomic potential suitable for atomistic simulations. These potentials were used to evaluate the lattice thermal conductivity of single crystals and the thermal resistance of simple grain boundaries. Finite element method (FEM) computations using atomistic results as inputs were performed with meshes constructed on SEM images thereby modeling the realistic microstructure. These continuum computations showed the reduction in thermal conductivity due to the grain boundary network.
Model for thermal conductivity of CNT-nanofluids
Indian Academy of Sciences (India)
H E Patel; K B Anoop; T Sundararajan; Sarit K Das
2008-06-01
This work presents a simple model for predicting the thermal conductivity of carbon nanotube (CNT) nanofluids. Effects due to the high thermal conductivity of CNTs and the percolation of heat through it are considered to be the most important reasons for their anomalously high thermal conductivity enhancement. A new approach is taken for the modeling, the novelty of which lies in the prediction of the thermal behaviour of oil based as well as water based CNT nanofluids, which are quite different from each other in thermal characteristics. The model is found to correctly predict the trends observed in experimental data for different combinations of CNT nanofluids with varying concentrations.
Multiscale modeling of thermal conductivity of polycrystalline graphene sheets.
Mortazavi, Bohayra; Pötschke, Markus; Cuniberti, Gianaurelio
2014-03-21
We developed a multiscale approach to explore the effective thermal conductivity of polycrystalline graphene sheets. By performing equilibrium molecular dynamics (EMD) simulations, the grain size effect on the thermal conductivity of ultra-fine grained polycrystalline graphene sheets is investigated. Our results reveal that the ultra-fine grained graphene structures have thermal conductivity one order of magnitude smaller than that of pristine graphene. Based on the information provided by the EMD simulations, we constructed finite element models of polycrystalline graphene sheets to probe the thermal conductivity of samples with larger grain sizes. Using the developed multiscale approach, we also investigated the effects of grain size distribution and thermal conductivity of grains on the effective thermal conductivity of polycrystalline graphene. The proposed multiscale approach on the basis of molecular dynamics and finite element methods could be used to evaluate the effective thermal conductivity of polycrystalline graphene and other 2D structures.
Thermal conductivity modeling of water containing metal oxide nanoparticles
Institute of Scientific and Technical Information of China (English)
Ahmad Azari
2015-01-01
The nano particles have demonstrated great potential to improve the heat transfer characteristics of heat transfer fluids. Possible parameters responsible for this increase were studied. The heat transfer profile in the nanolayer region was combined with other parameters such as volume fraction, particle radius thermal conductivity of the fluid, particle and nanolayer, to formulate a thermal conductivity model. Results predicting the thermal conductivity of nanofluids using the model were compared with experimental results as well as studies by other researchers. The comparison of the results obtained for the CuO/water and TiO2/water nanofluids studied shows that the correlation proposed is in closest proximity in predicting the experimental results for the thermal conductivity of a nanofluid. Also, a parametric study was performed to understand how a number of factors affect the thermal conductivity of nanofluids using the developed correlation.
Thermal scale modeling of radiation-conduction-convection systems.
Shannon, R. L.
1972-01-01
Investigation of thermal scale modeling applied to radiation-conduction-convection systems with particular emphasis on the spacecraft cabin atmosphere/cabin wall thermal interface. The 'modified material preservation,' 'temperature preservation,' 'scaling compromises,' and 'Nusselt number preservation' scale modeling techniques and their inherent limitations and problem areas are described. The compromised scaling techniques of mass flux preservation and heat transfer coefficient preservation show promise of giving adequate thermal similitude while preserving both gas and temperature in the scale model. The use of these compromised scaling techniques was experimentally demonstrated in tests of full scale and 1/4 scale models. Correlation of test results for free and forced convection under various test conditions shows the effectiveness of these scaling techniques. It is concluded that either mass flux or heat transfer coefficient preservation may result in adequate thermal similitude depending on the system to be modeled. Heat transfer coefficient preservation should give good thermal similitude for manned spacecraft scale modeling applications.
Modeling of Thermal Conductivity of Graphite Nanosheet Composites
Lin, Wei; Zhang, Rongwei; Wong, C. P.
2010-03-01
Recent experiments demonstrated a very high thermal conductivity in graphite nanosheet (GNS)/epoxy nanocomposites; however, theoretical analysis is lacking. In this letter, an effective medium model has been used to analyze the effective thermal conductivity of the GNS/polymer nanocomposites and has shown good validity. Strong influences of the aspect ratio and the orientation of the GNS are evident. As expected, interfacial thermal resistance still plays a role in determining the overall thermal transport in the GNS/polymer nanocomposites. In comparison with the interfacial thermal resistance between carbon nanotubes and polymers, the interfacial thermal resistance between GNS and polymers is about one order of magnitude lower, the reason for which is discussed.
Multiscale Modeling of Thermal Conductivity of Polymer/Carbon Nanocomposites
Clancy, Thomas C.; Frankland, Sarah-Jane V.; Hinkley, Jeffrey A.; Gates, Thomas S.
2010-01-01
Molecular dynamics simulation was used to estimate the interfacial thermal (Kapitza) resistance between nanoparticles and amorphous and crystalline polymer matrices. Bulk thermal conductivities of the nanocomposites were then estimated using an established effective medium approach. To study functionalization, oligomeric ethylene-vinyl alcohol copolymers were chemically bonded to a single wall carbon nanotube. The results, in a poly(ethylene-vinyl acetate) matrix, are similar to those obtained previously for grafted linear hydrocarbon chains. To study the effect of noncovalent functionalization, two types of polyethylene matrices. -- aligned (extended-chain crystalline) vs. amorphous (random coils) were modeled. Both matrices produced the same interfacial thermal resistance values. Finally, functionalization of edges and faces of plate-like graphite nanoparticles was found to be only modestly effective in reducing the interfacial thermal resistance and improving the composite thermal conductivity
Rock thermal conductivity as key parameter for geothermal numerical models
Di Sipio, Eloisa; Chiesa, Sergio; Destro, Elisa; Galgaro, Antonio; Giaretta, Aurelio; Gola, Gianluca; Manzella, Adele
2013-04-01
The geothermal energy applications are undergoing a rapid development. However, there are still several challenges in the successful exploitation of geothermal energy resources. In particular, a special effort is required to characterize the thermal properties of the ground along with the implementation of efficient thermal energy transfer technologies. This paper focuses on understanding the quantitative contribution that geosciences can receive from the characterization of rock thermal conductivity. The thermal conductivity of materials is one of the main input parameters in geothermal modeling since it directly controls the steady state temperature field. An evaluation of this thermal property is required in several fields, such as Thermo-Hydro-Mechanical multiphysics analysis of frozen soils, designing ground source heat pumps plant, modeling the deep geothermal reservoirs structure, assessing the geothermal potential of subsoil. Aim of this study is to provide original rock thermal conductivity values useful for the evaluation of both low and high enthalpy resources at regional or local scale. To overcome the existing lack of thermal conductivity data of sedimentary, igneous and metamorphic rocks, a series of laboratory measurements has been performed on several samples, collected in outcrop, representative of the main lithologies of the regions included in the VIGOR Project (southern Italy). Thermal properties tests were carried out both in dry and wet conditions, using a C-Therm TCi device, operating following the Modified Transient Plane Source method.Measurements were made at standard laboratory conditions on samples both water saturated and dehydrated with a fan-forced drying oven at 70 ° C for 24 hr, for preserving the mineral assemblage and preventing the change of effective porosity. Subsequently, the samples have been stored in an air-conditioned room while bulk density, solid volume and porosity were detected. The measured thermal conductivity
A thermal conductivity model for U-Si compounds
Energy Technology Data Exchange (ETDEWEB)
Zhang, Yongfeng [Idaho National Lab. (INL), Idaho Falls, ID (United States); Andersson, Anders David Ragnar [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
2017-02-02
U_{3}Si_{2} is a candidate for accident tolerant nuclear fuel being developed as an alternative to UO_{2} in commercial light water reactors (LWRs). One of its main benefits compared to UO_{2} is higher thermal conductivity that increases with temperature. This increase is contrary to UO_{2}, for which the thermal conductivity decreases with temperature. The reason for the difference is the electronic origin of thermal conductivity in U_{3}Si_{2}, as compared to the phonon mechanism responsible for thermal transport in UO_{2}. The phonon thermal conductivity in UO_{2} is unusually low for a fluorite oxide due to the strong interaction with the spins in the paramagnetic phase. The thermal conductivity of U_{3}Si_{2} as well as other U-Si compounds has been measured experimentally [1-4]. However, for fuel performance simulations it is also critical to model the degradation of the thermal conductivity due to damage and microstructure evolution caused by the reactor environment (irradiation and high temperature). For UO_{2} this reduction is substantial and it has been the topic of extensive NEAMS research resulting in several publications [5, 6]. There are no data or models for the evolution of the U_{3}Si_{2} thermal conductivity under irradiation. We know that the intrinsic thermal conductivities of UO_{2} (semi-conductor) and U_{3}Si_{2} (metal) are very different, and we do not necessarily expect the dependence on damage to be the same either, which could present another advantage for the silicide fuel. In this report we summarize the first step in developing a model for the thermal conductivity of U-Si compounds with the goal of capturing the effect of damage in U_{3}Si_{2}. Next year, we will focus on lattice damage. We will also attempt to assess the impact of fission gas bubbles.
Physical-Statistical Model of Thermal Conductivity of Nanofluids
Directory of Open Access Journals (Sweden)
B. Usowicz
2014-01-01
Full Text Available A physical-statistical model for predicting the effective thermal conductivity of nanofluids is proposed. The volumetric unit of nanofluids in the model consists of solid, liquid, and gas particles and is treated as a system made up of regular geometric figures, spheres, filling the volumetric unit by layers. The model assumes that connections between layers of the spheres and between neighbouring spheres in the layer are represented by serial and parallel connections of thermal resistors, respectively. This model is expressed in terms of thermal resistance of nanoparticles and fluids and the multinomial distribution of particles in the nanofluids. The results for predicted and measured effective thermal conductivity of several nanofluids (Al2O3/ethylene glycol-based and Al2O3/water-based; CuO/ethylene glycol-based and CuO/water-based; and TiO2/ethylene glycol-based are presented. The physical-statistical model shows a reasonably good agreement with the experimental results and gives more accurate predictions for the effective thermal conductivity of nanofluids compared to existing classical models.
Atomistic Modeling of Thermal Conductivity of Epoxy Nanotube Composites
Fasanella, Nicholas A.; Sundararaghavan, Veera
2016-05-01
The Green-Kubo method was used to investigate the thermal conductivity as a function of temperature for epoxy/single wall carbon nanotube (SWNT) nanocomposites. An epoxy network of DGEBA-DDS was built using the `dendrimer' growth approach, and conductivity was computed by taking into account long-range Coulombic forces via a k-space approach. Thermal conductivity was calculated in the direction perpendicular to, and along the SWNT axis for functionalized and pristine SWNT/epoxy nanocomposites. Inefficient phonon transport at the ends of nanotubes is an important factor in the thermal conductivity of the nanocomposites, and for this reason discontinuous nanotubes were modeled in addition to long nanotubes. The thermal conductivity of the long, pristine SWNT/epoxy system is equivalent to that of an isolated SWNT along its axis, but there was a 27% reduction perpendicular to the nanotube axis. The functionalized, long SWNT/epoxy system had a very large increase in thermal conductivity along the nanotube axis (~700%), as well as the directions perpendicular to the nanotube (64%). The discontinuous nanotubes displayed an increased thermal conductivity along the SWNT axis compared to neat epoxy (103-115% for the pristine SWNT/epoxy, and 91-103% for functionalized SWNT/epoxy system). The functionalized system also showed a 42% improvement perpendicular to the nanotube, while the pristine SWNT/epoxy system had no improvement over epoxy. The thermal conductivity tensor is averaged over all possible orientations to see the effects of randomly orientated nanotubes, and allow for experimental comparison. Excellent agreement is seen for the discontinuous, pristine SWNT/epoxy nanocomposite. These simulations demonstrate there exists a threshold of the SWNT length where the best improvement for a composite system with randomly oriented nanotubes would transition from pristine SWNTs to functionalized SWNTs.
Fractional Heat Conduction Models and Thermal Diffusivity Determination
Directory of Open Access Journals (Sweden)
Monika Žecová
2015-01-01
Full Text Available The contribution deals with the fractional heat conduction models and their use for determining thermal diffusivity. A brief historical overview of the authors who have dealt with the heat conduction equation is described in the introduction of the paper. The one-dimensional heat conduction models with using integer- and fractional-order derivatives are listed. Analytical and numerical methods of solution of the heat conduction models with using integer- and fractional-order derivatives are described. Individual methods have been implemented in MATLAB and the examples of simulations are listed. The proposal and experimental verification of the methods for determining thermal diffusivity using half-order derivative of temperature by time are listed at the conclusion of the paper.
A micro-convection model for thermal conductivity of nanofluids
Indian Academy of Sciences (India)
Hrishikesh E Patel; T Sundararajan; T Pradeep; A Dasgupta; N Dasgupta; Sarit K Das
2005-11-01
Increase in the specific surface area as well as Brownian motion are supposed to be the most significant reasons for the anomalous enhancement in thermal conductivity of nanofluids. This work presents a semi-empirical approach for the same by emphasizing the above two effects through micro-convection. A new way of modeling thermal conductivity of nanofluids has been explored which is found to agree excellently with a wide range of experimental data obtained by the present authors as well as the data published in literature.
Modeling Interfacial Thermal Boundary Conductance of Engineered Interfaces
2014-08-31
involving carbon materials. Determined scaling laws for conductivity of carbon nanotube networks [11]. Modified the DMM to predict hBD at metal–graphite...111, 084310 (2012). 11A. N. Volkov and L. V. Zhigilei, “Scaling laws and mesoscopic modeling of thermal conductivity in carbon nanotube materials...instead from an algebraic expression that accurately reproduces the MD results but with negligible computational expense. This permitted a large
Thermal Conductivity in Suspension Sprayed Thermal Barrier Coatings: Modeling and Experiments
Ganvir, Ashish; Kumara, Chamara; Gupta, Mohit; Nylen, Per
2016-12-01
Axial suspension plasma spraying (ASPS) can generate microstructures with higher porosity and pores in the size range from submicron to nanometer. ASPS thermal barrier coatings (TBC) have already shown a great potential to produce low thermal conductivity coatings for gas turbine applications. It is important to understand the fundamental relationships between microstructural defects in ASPS coatings such as crystallite boundaries, porosity etc. and thermal conductivity. Object-oriented finite element (OOF) analysis has been shown as an effective tool for evaluating thermal conductivity of conventional TBCs as this method is capable of incorporating the inherent microstructure in the model. The objective of this work was to analyze the thermal conductivity of ASPS TBCs using experimental techniques and also to evaluate a procedure where OOF can be used to predict and analyze the thermal conductivity for these coatings. Verification of the model was done by comparing modeling results with the experimental thermal conductivity. The results showed that the varied scaled porosity has a significant influence on the thermal conductivity. Smaller crystallites and higher overall porosity content resulted in lower thermal conductivity. It was shown that OOF could be a powerful tool to predict and rank thermal conductivity of ASPS TBCs.
Thermal Conductivity in Suspension Sprayed Thermal Barrier Coatings: Modeling and Experiments
Ganvir, Ashish; Kumara, Chamara; Gupta, Mohit; Nylen, Per
2017-01-01
Axial suspension plasma spraying (ASPS) can generate microstructures with higher porosity and pores in the size range from submicron to nanometer. ASPS thermal barrier coatings (TBC) have already shown a great potential to produce low thermal conductivity coatings for gas turbine applications. It is important to understand the fundamental relationships between microstructural defects in ASPS coatings such as crystallite boundaries, porosity etc. and thermal conductivity. Object-oriented finite element (OOF) analysis has been shown as an effective tool for evaluating thermal conductivity of conventional TBCs as this method is capable of incorporating the inherent microstructure in the model. The objective of this work was to analyze the thermal conductivity of ASPS TBCs using experimental techniques and also to evaluate a procedure where OOF can be used to predict and analyze the thermal conductivity for these coatings. Verification of the model was done by comparing modeling results with the experimental thermal conductivity. The results showed that the varied scaled porosity has a significant influence on the thermal conductivity. Smaller crystallites and higher overall porosity content resulted in lower thermal conductivity. It was shown that OOF could be a powerful tool to predict and rank thermal conductivity of ASPS TBCs.
Effective Thermal Conductivity Modeling of Sandstones: SVM Framework Analysis
Rostami, Alireza; Masoudi, Mohammad; Ghaderi-Ardakani, Alireza; Arabloo, Milad; Amani, Mahmood
2016-06-01
Among the most significant physical characteristics of porous media, the effective thermal conductivity (ETC) is used for estimating the thermal enhanced oil recovery process efficiency, hydrocarbon reservoir thermal design, and numerical simulation. This paper reports the implementation of an innovative least square support vector machine (LS-SVM) algorithm for the development of enhanced model capable of predicting the ETCs of dry sandstones. By means of several statistical parameters, the validity of the presented model was evaluated. The prediction of the developed model for determining the ETCs of dry sandstones was in excellent agreement with the reported data with a coefficient of determination value ({R}2) of 0.983 and an average absolute relative deviation of 0.35 %. Results from present research show that the proposed LS-SVM model is robust, reliable, and efficient in calculating the ETCs of sandstones.
Modeling of thermal conductivity of stainless-steelmaking dust pellets
Institute of Scientific and Technical Information of China (English)
彭兵; 彭及; 余笛
2004-01-01
The thermal conductivity of stainless-steelmaking dust pellets, an important parameter for the direct recycling of the dust, is naturally of interest to metallurgists. The measurement of central temperature and surface temperature was taken in a furnace. The physical model and calculation model for the heating process were set up to check the thermal conductivity of the dust pellets. The physical structure parameters δ and λ of the basic unit are 0.92 and 0.45 based on the calculation. The temperature in the pellet can be expressed in a linear equation a5 Tp =a1 TN +a2 TM +a4. This is convenient to determine the central temperature of a pellet in the direct recycling process.
Thermal Conductivity of the Potential Repository Horizon Model Report
Energy Technology Data Exchange (ETDEWEB)
J. Ramsey
2002-08-29
The purpose of this report is to assess the spatial variability and uncertainty of thermal conductivity in the host horizon for the proposed repository at Yucca Mountain. More specifically, the lithostratigraphic units studied are located within the Topopah Spring Tuff (Tpt) and consist of the upper lithophysal zone (Tptpul), the middle nonlithophysal zone (Tptpmn), the lower lithophysal zone (Tptpll), and the lower nonlithophysal zone (Tptpln). The Tptpul is the layer directly above the repository host layers, which consist of the Tptpmn, Tptpll, and the Tptpln. Current design plans indicate that the largest portion of the repository will be excavated in the Tptpll (Board et al. 2002 [157756]). The main distinguishing characteristic among the lithophysal and nonlithophysal units is the percentage of large scale (cm-m) voids within the rock. The Tptpul and Tptpll, as their names suggest, have a higher percentage of lithophysae than the Tptpmn and the Tptpln. Understanding the influence of the lithophysae is of great importance to understanding bulk thermal conductivity and perhaps repository system performance as well. To assess the spatial variability and uncertainty of thermal conductivity, a model is proposed that is functionally dependent on the volume fraction of lithophysae and the thermal conductivity of the matrix portion of the rock. In this model, void space characterized as lithophysae is assumed to be air-saturated under all conditions, while void space characterized as matrix may be either water- or air-saturated. Lithophysae are assumed to be air-saturated under all conditions since the units being studied are all located above the water table in the region of interest, and the relatively strong capillary forces of the matrix will, under most conditions, preferentially retain any moisture present in the rock.
Model for predicting thermal conductivity using transient hot wire method
Kumar, Sublania Harish; Singh K., J.; Somani A., K.
2016-05-01
The use of the hot wire method for estimating the thermal conductivity measurement has recently known a significant increase. However, this method is theoretically not applicable to materials. Thermal conductivity values are necessary whenever a heat transfer problem is to be evaluated.
The Lattice and Thermal Radiation Conductivity of Thermal Barrier Coatings: Models and Experiments
Zhu, Dongming; Spuckler, Charles M.
2010-01-01
The lattice and radiation conductivity of ZrO2-Y2O3 thermal barrier coatings was evaluated using a laser heat flux approach. A diffusion model has been established to correlate the coating apparent thermal conductivity to the lattice and radiation conductivity. The radiation conductivity component can be expressed as a function of temperature, coating material scattering, and absorption properties. High temperature scattering and absorption of the coating systems can be also derived based on the testing results using the modeling approach. A comparison has been made for the gray and nongray coating models in the plasma-sprayed thermal barrier coatings. The model prediction is found to have a good agreement with experimental observations.
Thermal conductivity modeling of circular-wire nanocomposites
Hsieh, Tse-Yang; Yang, Jaw-Yen
2010-08-01
A phonon Boltzmann equation solver using multiblock-structured grid system is developed and applied to study transverse thermal transport in silicon-germanium circular-wire nanocomposite (silicon nanowires embedded in germanium host matrix). Past studies usually assume geometric simplification for the circular-wire nanocomposite, so the heat transfer is actually modeled in a square-wire nanocomposite. To demonstrate geometry effect, phonon transport in both the circular-wire and square-wire nanocomposites are investigated with various wire spacings, volume fractions, and dimensions. In ballistic phonon transport, due to the smoothness of circular shape, the circular wire imposes less thermal resistance than the square wire. Nevertheless, in the geometric simplification, the wire spacing of the square-wire nanocomposite is larger than that of the circular-wire nanocomposite. The usual geometric simplification can overestimate the thermal conductivity of the circular-wire nanocomposite. The obtained results can provide essential information for the development of bulk-nanostructured thermoelectric devices.
Decomposition model for phonon thermal conductivity of a monatomic lattice
Evteev, Alexander V.; Momenzadeh, Leila; Levchenko, Elena V.; Belova, Irina V.; Murch, Graeme E.
2014-12-01
An analytical treatment of decomposition of the phonon thermal conductivity of a crystal with a monatomic unit cell is developed on the basis of a two-stage decay of the heat current autocorrelation function observed in molecular dynamics simulations. It is demonstrated that the contributions from the acoustic short- and long-range phonon modes to the total phonon thermal conductivity can be presented in the form of simple kinetic formulas, consisting of products of the heat capacity and the average relaxation time of the considered phonon modes as well as the square of the average phonon velocity. On the basis of molecular dynamics calculations of the heat current autocorrelation function, this treatment allows for a self-consistent numerical evaluation of the aforementioned variables. In addition, the presented analysis allows, within the Debye approximation, for the identification of the temperature range where classical molecular dynamics simulations can be employed for the prediction of phonon thermal transport properties. As a case example, Cu is considered.
Normal thermal conduction in lattice models with asymmetric harmonic interparticle interactions
Institute of Scientific and Technical Information of China (English)
Zhong Yi; Zhang Yong; Wang Jiao; Zhao Hong
2013-01-01
We study the thermal conduction behaviors of one-dimensional lattice models with asymmetric harmonic interparticle interactions.Normal thermal conductivity that is independent of system size is observed when the lattice chains are long enough.Because only the harmonic interactions are involved,the result confirms,without ambiguity,that asymmetry plays a key role in normal thermal conduction in one-dimensional momentum conserving lattices.Both equilibrium and nonequilibrium simulations are performed to support the conclusion.
A Fractal Model for the Effective Thermal Conductivity of Granular Flow with Non-uniform Particles
Institute of Scientific and Technical Information of China (English)
ZHANG Duan-Ming; LEI Ya-Jie; YU Bo-Ming; ZHANG Mei-Jun; HUANG Ming-Tao; LI Zhi-Hua; GUAN Li
2002-01-01
The equipartition of energy applied in binary mixture of granular flow is extended to granular flow withnon-uniform particles. Based on the fractal characteristic of granular flow with non-uniform particles as well as energyequipartition, a fractal velocity distribution function and a fractal model of effective thermal conductivity are derived.Thermal conduction resulted from motions of particles in the granular flow, as well as the effect of fractal dimension oneffective thermal conductivity, is discussed.
A Network Model for the Effective Thermal Conductivity of Rigid Fibrous Refractory Insulations
Marschall, Jochen; Cooper, D. M. (Technical Monitor)
1995-01-01
A procedure is described for computing the effective thermal conductivity of a rigid fibrous refractory insulation. The insulation is modeled as a 3-dimensional Cartesian network of thermal conductance. The values and volume distributions of the conductance are assigned to reflect the physical properties of the insulation, its constituent fibers, and any permeating gas. The effective thermal conductivity is computed by considering the simultaneous energy transport by solid conduction, gas conduction and radiation through a cubic volume of model insulation; thus the coupling between heat transfer modes is retained (within the simplifications inherent to the model), rather than suppressed by treating these heat transfer modes as independent. The model takes into account insulation composition, density and fiber anisotropy, as well as the geometric and material properties of the constituent fibers. A relatively good agreement, between calculated and experimentally derived thermal conductivity values, is obtained for a variety of rigid fibrous insulations.
A fractal model for the effective thermal conductivity of nanoparticle suspensions
Institute of Scientific and Technical Information of China (English)
WANG Buxuan; ZHOU Leping; PENG Xiaofeng
2004-01-01
Extending the effective medium approximation with the fractal theory for describing nanoparticle clusters and their radius distribution, a predictive model is proposed for the effective thermal conductivity of nanoparticle suspension, combined with the consideration of size effect and surface adsorption effect of nanoparticles.The predicted effective thermal conductivity of nanoparticle suspension is consistent with experimental data in the dilute limit.
Thermal conductivity of granular porous media: A pore scale modeling approach
Directory of Open Access Journals (Sweden)
R. Askari
2015-09-01
Full Text Available Pore scale modeling method has been widely used in the petrophysical studies to estimate macroscopic properties (e.g. porosity, permeability, and electrical resistivity of porous media with respect to their micro structures. Although there is a sumptuous literature about the application of the method to study flow in porous media, there are fewer studies regarding its application to thermal conduction characterization, and the estimation of effective thermal conductivity, which is a salient parameter in many engineering surveys (e.g. geothermal resources and heavy oil recovery. By considering thermal contact resistance, we demonstrate the robustness of the method for predicting the effective thermal conductivity. According to our results obtained from Utah oil sand samples simulations, the simulation of thermal contact resistance is pivotal to grant reliable estimates of effective thermal conductivity. Our estimated effective thermal conductivities exhibit a better compatibility with the experimental data in companion with some famous experimental and analytical equations for the calculation of the effective thermal conductivity. In addition, we reconstruct a porous medium for an Alberta oil sand sample. By increasing roughness, we observe the effect of thermal contact resistance in the decrease of the effective thermal conductivity. However, the roughness effect becomes more noticeable when there is a higher thermal conductivity of solid to fluid ratio. Moreover, by considering the thermal resistance in porous media with different grains sizes, we find that the effective thermal conductivity augments with increased grain size. Our observation is in a reasonable accordance with experimental results. This demonstrates the usefulness of our modeling approach for further computational studies of heat transfer in porous media.
Modeling of Thermal Conductivity of CVI-Densified Composites at Fiber and Bundle Level
Directory of Open Access Journals (Sweden)
Kang Guan
2016-12-01
Full Text Available The evolution of the thermal conductivities of the unidirectional, 2D woven and 3D braided composites during the CVI (chemical vapor infiltration process have been numerically studied by the finite element method. The results show that the dual-scale pores play an important role in the thermal conduction of the CVI-densified composites. According to our results, two thermal conductivity models applicable for CVI process have been developed. The sensitivity analysis demonstrates the parameter with the most influence on the CVI-densified composites’ thermal conductivity is matrix cracking’s density, followed by volume fraction of the bundle and thermal conductance of the matrix cracks, finally by micro-porosity inside the bundles and macro-porosity between the bundles. The obtained results are well consistent with the reported data, thus our models could be useful for designing the processing and performance of the CVI-densified composites.
A Model of Thermal Conductivity for Planetary Soils: 1. Theory for Unconsolidated Soils
Piqueux, S.; Christensen, P. R.
2009-01-01
We present a model of heat conduction for mono-sized spherical particulate media under stagnant gases based on the kinetic theory of gases, numerical modeling of Fourier s law of heat conduction, theoretical constraints on the gas thermal conductivity at various Knudsen regimes, and laboratory measurements. Incorporating the effect of the temperature allows for the derivation of the pore-filling gas conductivity and bulk thermal conductivity of samples using additional parameters (pressure, gas composition, grain size, and porosity). The radiative and solid-to-solid conductivities are also accounted for. Our thermal model reproduces the well-established bulk thermal conductivity dependency of a sample with the grain size and pressure and also confirms laboratory measurements finding that higher porosities generally lead to lower conductivities. It predicts the existence of the plateau conductivity at high pressure, where the bulk conductivity does not depend on the grain size. The good agreement between the model predictions and published laboratory measurements under a variety of pressures, temperatures, gas compositions, and grain sizes provides additional confidence in our results. On Venus, Earth, and Titan, the pressure and temperature combinations are too high to observe a soil thermal conductivity dependency on the grain size, but each planet has a unique thermal inertia due to their different surface temperatures. On Mars, the temperature and pressure combination is ideal to observe the soil thermal conductivity dependency on the average grain size. Thermal conductivity models that do not take the temperature and the pore-filling gas composition into account may yield significant errors.
Thermal conductivity model for powdered materials under vacuum based on experimental studies
Directory of Open Access Journals (Sweden)
N. Sakatani
2017-01-01
Full Text Available The thermal conductivity of powdered media is characteristically very low in vacuum, and is effectively dependent on many parameters of their constituent particles and packing structure. Understanding of the heat transfer mechanism within powder layers in vacuum and theoretical modeling of their thermal conductivity are of great importance for several scientific and engineering problems. In this paper, we report the results of systematic thermal conductivity measurements of powdered media of varied particle size, porosity, and temperature under vacuum using glass beads as a model material. Based on the obtained experimental data, we investigated the heat transfer mechanism in powdered media in detail, and constructed a new theoretical thermal conductivity model for the vacuum condition. This model enables an absolute thermal conductivity to be calculated for a powder with the input of a set of powder parameters including particle size, porosity, temperature, and compressional stress or gravity, and vice versa. Our model is expected to be a competent tool for several scientific and engineering fields of study related to powders, such as the thermal infrared observation of air-less planetary bodies, thermal evolution of planetesimals, and performance of thermal insulators and heat storage powders.
Study on Unit Cell Models and the Effective Thermal Conductivities of Silica Aerogel.
Liu, He; Li, Zeng-Yao; Zhao, Xin-Peng; Tao, Wen-Quan
2015-04-01
In this paper, two modified unit cell models, truncated octahedron and cubic array of intersecting square rods with 45-degree rotation, are developed in consideration of the tortuous path of heat conduction in solid skeleton of silica aerogel. The heat conduction is analyzed for each model and the expressions of effective thermal conductivity of the modified unit cell models are derived. Considering the random microstructure of silica aerogel, the probability model is presented. We also discuss the effect of the thermal conductivity of aerogel backbone. The effective thermal conductivities calculated by the proposed probability model are in good agreement with available experimental data when the density of the aerogel is 110 kg/m3.
Network model for thermal conductivities of unidirectional fiber-reinforced composites
Wang, Yang; Peng, Chaoyi; Zhang, Weihua
2014-12-01
An empirical network model has been developed to predict the in-plane thermal conductivities along arbitrary directions for unidirectional fiber-reinforced composites lamina. Measurements of thermal conductivities along different orientations were carried out. Good agreement was observed between values predicted by the network model and the experimental data; compared with the established analytical models, the newly proposed network model could give values with higher precision. Therefore, this network model is helpful to get a wider and more comprehensive understanding of heat transmission characteristics of fiber-reinforced composites and can be utilized as guidance to design and fabricate laminated composites with specific directional or specific locational thermal conductivities for structures that simultaneously perform mechanical and thermal functions, i.e. multifunctional structures (MFS).
A Model of Thermal Conductivity for Planetary Soils. 2; Theory for Cemented Soils
Piqueux, S.; Christensen, P. R.
2009-01-01
A numerical model of heat conduction through particulate media made of spherical grains cemented by various bonding agents is presented. The pore-filling gas conductivity, volume fraction, and thermal conductivity of the cementing phase are tunable parameters. Cement fractions thermal conductivity. A significant conductivity increase (factor 3-8) is observed for bond fractions of 0.01 to 1% in volume. In the 1 to 15% bond fraction domain, the conductivity increases continuously but less intensely (25-100% conductivity increase compared to a 1% bond system). Beyond 15% of cements, the conductivity increases vigorously and the bulk conductivity rapidly approaches that of bedrock. The composition of the cements (i.e. conductivity) has little influence on the bulk thermal inertia of the soil, especially if the volume of bond thermal inertia (200-600 J s(0.5)/sq m/K) has long been hypothesized to be associated with a duricrust. The fraction of cement required to fit the thermal data is less than approx.1-5% by volume. This small amount of material is consistent with orbital observations, confirming that soil cementation is an important factor controlling the thermal inertia of the Martian surface
Energy Technology Data Exchange (ETDEWEB)
Al-Nimr, Moh' d A.; Naji, Malak; Al-Wardat, Salem A. [Mechanical Engineering Department, Jordan University of Science and Technology, Irbid 22110, P.O. Box 3030 (Jordan)
2004-02-01
The thermal behavior of thin slab as described by the parabolic microscopic heat conduction model with variable thermal properties is investigated under two types of heating sources. These types are the unit step and the fluctuating harmonic heating sources. The considered thermal properties are the electron gas C{sub e} and the solid lattice C{sub L} total thermal capacities. It is found that the slab thermal behavior is more sensitive to the variation in C{sub e} as compared to the variation in C{sub L}. Assuming C{sub e} constant may cause an error of magnitude 19% while assuming C{sub L} constant causes an error of magnitude 5%. The sensitivity of the parabolic microscopic heat conduction model to the variation in C{sub e} is higher under the effect of a fluctuating heating source as compared to a unit step heating source. (authors)
Thermal conductivity of boron carbides
Wood, C.; Emin, D.; Gray, P. E.
1985-01-01
Knowledge of the thermal conductivity of boron carbide is necessary to evaluate its potential for high-temperature thermoelectric energy conversion applications. Measurements have been conducted of the thermal diffusivity of hot-pressed boron carbide BxC samples as a function of composition (x in the range from 4 to 9), temperature (300-1700 K), and temperature cycling. These data, in concert with density and specific-heat data, yield the thermal conductivities of these materials. The results are discussed in terms of a structural model that has been previously advanced to explain the electronic transport data. Some novel mechanisms for thermal conduction are briefly discussed.
Resistors Network Model of Bcc Cell for Investigating Thermal Conductivity of Nanofluids
Masturi, Masturi; Sustini, Euis; Khairurrijal, Khairurrijal; Abdullah, Mikrajuddin
2011-12-01
A model was developed to investigate thermal conductivity of nanofluids. It was based on resistors circuit network in bcc cell as alternative form of simple cubic cell has been successfully developed. The present model has involved the Brownian motion of nanoparticles in the fluid with an assumption that the nanoparticles are in low volume fraction so the diameter size of nanoparticle can be neglected in comparison to particles distance. Generally, this model was very fit to experimental results has been obtained from some authors. As an example, for alumina-water nanofluid, that is alumina (Al2O3) dispersed in water, it was found that the enhancement of its thermal conductivity calculated using this model was in good agreement with experimental results that it tended to increase as nanoparticle fraction increases. As in alumina-water, the agreement was also shown in titania (TiO2)-water and cuprum oxide (CuO)-water. This model also showed the dependence of thermal conductivity enhancement to diameter size of nanoparticle and temperature of the nanofluid. In relation to diameter size, thermal conductivity enhancement decreases as diameter size increases. Otherwise, thermal conductivity enhancement increases as temperature increases. However, even though this model was very close to experimental results, the problem of this model was in dimensionless constant that varied for different nanofluids.
Summary report on UO_{2} thermal conductivity model refinement and assessment studies
Energy Technology Data Exchange (ETDEWEB)
Liu, Xiang-Yang [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Cooper, Michael William Donald [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mcclellan, Kenneth James [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Lashley, Jason Charles [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Byler, Darrin David [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Bell, B. D.C. [Imperial College, London (United Kingdom); Grimes, R. W. [Imperial College, London (United Kingdom); Stanek, Christopher Richard [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Andersson, David Ragnar [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
2017-02-03
Uranium dioxide (UO_{2}) is the most commonly used fuel in light water nuclear reactors and thermal conductivity controls the removal of heat produced by fission, therefore, governing fuel temperature during normal and accident conditions. The use of fuel performance codes by the industry to predict operational behavior is widespread. A primary source of uncertainty in these codes is thermal conductivity, and optimized fuel utilization may be possible if existing empirical models were replaced with models that incorporate explicit thermal conductivity degradation mechanisms during fuel burn-up. This approach is able to represent the degradation of thermal conductivity due to each individual defect type, rather than the overall burn-up measure typically used which is not an accurate representation of the chemical or microstructure state of the fuel that actually governs thermal conductivity and other properties. To generate a mechanistic thermal conductivity model, molecular dynamics (MD) simulations of UO_{2} thermal conductivity including representative uranium and oxygen defects and fission products are carried out. These calculations employ a standard Buckingham type interatomic potential and a potential that combines the many-body embedded atom method potential with Morse-Buckingham pair potentials. Potential parameters for UO_{2+x} and ZrO_{2} are developed for the latter potential. Physical insights from the resonant phonon-spin scattering mechanism due to spins on the magnetic uranium ions have been introduced into the treatment of the MD results, with the corresponding relaxation time derived from existing experimental data. High defect scattering is predicted for Xe atoms compared to that of La and Zr ions. Uranium defects reduce the thermal conductivity more than oxygen defects. For each defect and fission product, scattering parameters are derived for application in both a Callaway model and the corresponding high
A Fractal Model for the Transverse Thermal Dispersion Conductivity in Porous Media
Institute of Scientific and Technical Information of China (English)
郁伯铭; 李建华
2004-01-01
A quasi-analytical model, i.e. the fractal model, for the transverse thermal dispersion conductivity in porous media is presented based on the fractal characteristics of tortuous flow paths/streamlines in porous media. The fractal dimension of tortuous flow paths, the spatial deviation velocity and the transverse thermal dispersion conductivity are derived. The proposed model is expressed as functions of the fractal dimension of tortuous flow paths/streamlines, Peclet number, porosity and structural parameters. The present results are compared with those from the existing correlation, and good agreement is found between the present model predictions and those from the existing correlation.
Thermal conductivity of supercooled water.
Biddle, John W; Holten, Vincent; Sengers, Jan V; Anisimov, Mikhail A
2013-04-01
The heat capacity of supercooled water, measured down to -37°C, shows an anomalous increase as temperature decreases. The thermal diffusivity, i.e., the ratio of the thermal conductivity and the heat capacity per unit volume, shows a decrease. These anomalies may be associated with a hypothesized liquid-liquid critical point in supercooled water below the line of homogeneous nucleation. However, while the thermal conductivity is known to diverge at the vapor-liquid critical point due to critical density fluctuations, the thermal conductivity of supercooled water, calculated as the product of thermal diffusivity and heat capacity, does not show any sign of such an anomaly. We have used mode-coupling theory to investigate the possible effect of critical fluctuations on the thermal conductivity of supercooled water and found that indeed any critical thermal-conductivity enhancement would be too small to be measurable at experimentally accessible temperatures. Moreover, the behavior of thermal conductivity can be explained by the observed anomalies of the thermodynamic properties. In particular, we show that thermal conductivity should go through a minimum when temperature is decreased, as Kumar and Stanley observed in the TIP5P model of water. We discuss physical reasons for the striking difference between the behavior of thermal conductivity in water near the vapor-liquid and liquid-liquid critical points.
Low thermal conductivity oxides
Energy Technology Data Exchange (ETDEWEB)
Pan, Wei; Phillpot, Simon R.; Wan, Chunlei; Chernatynskiy, Aleksandr; Qu, Zhixue
2012-10-09
Oxides hold great promise as new and improved materials for thermal-barrier coating applications. The rich variety of structures and compositions of the materials in this class, and the ease with which they can be doped, allow the exploration of various mechanisms for lowering thermal conductivity. In this article, we review recent progress in identifying specific oxides with low thermal conductivity from both theoretical and experimental perspectives. We explore the mechanisms of lowering thermal conductivity, such as introducing structural/chemical disorder, increasing material density, increasing the number of atoms in the primitive cell, and exploiting the structural anisotropy. We conclude that further systematic exploration of oxide crystal structures and chemistries are likely to result in even further improved thermal-barrier coatings.
Salerno, Louis J.; Kittel, Peter
1997-01-01
The performance of cryogenic instruments is often a function of their operating temperature. Thus, designers of cryogenic instruments often are required to predict the operating temperature of each instrument they design. This requires accurate thermal models of cryogenic components which include the properties of the materials and assembly techniques used. When components are bolted or otherwise pressed together, a knowledge of the thermal performance of such joints are also needed. In some cases, the temperature drop across these joints represents a significant fraction of the total temperature difference between the instrument and its cooler. While extensive databases exist on the thermal properties of bulk materials, similar databases for pressed contacts do not. This has often lead to instrument designs that avoid pressed contacts or to the over-design of such joints at unnecessary expense. Although many people have made measurements of contact conductances at cryogenic temperatures, this data is often very narrow in scope and even more often it has not been published in an easily retrievable fashion, if published at all. This paper presents a summary of the limited pressed contact data available in the literature.
High Thermal Conductivity Materials
Shinde, Subhash L
2006-01-01
Thermal management has become a ‘hot’ field in recent years due to a need to obtain high performance levels in many devices used in such diverse areas as space science, mainframe and desktop computers, optoelectronics and even Formula One racing cars! Thermal solutions require not just taking care of very high thermal flux, but also ‘hot spots’, where the flux densities can exceed 200 W/cm2. High thermal conductivity materials play an important role in addressing thermal management issues. This volume provides readers a basic understanding of the thermal conduction mechanisms in these materials and discusses how the thermal conductivity may be related to their crystal structures as well as microstructures developed as a result of their processing history. The techniques for accurate measurement of these properties on large as well as small scales have been reviewed. Detailed information on the thermal conductivity of diverse materials including aluminum nitride (AlN), silicon carbide (SiC), diamond, a...
In vitro burn model illustrating heat conduction patterns using compressed thermal papers.
Lee, Jun Yong; Jung, Sung-No; Kwon, Ho
2015-01-01
To date, heat conduction from heat sources to tissue has been estimated by complex mathematical modeling. In the present study, we developed an intuitive in vitro skin burn model that illustrates heat conduction patterns inside the skin. This was composed of tightly compressed thermal papers with compression frames. Heat flow through the model left a trace by changing the color of thermal papers. These were digitized and three-dimensionally reconstituted to reproduce the heat conduction patterns in the skin. For standardization, we validated K91HG-CE thermal paper using a printout test and bivariate correlation analysis. We measured the papers' physical properties and calculated the estimated depth of heat conduction using Fourier's equation. Through contact burns of 5, 10, 15, 20, and 30 seconds on porcine skin and our burn model using a heated brass comb, and comparing the burn wound and heat conduction trace, we validated our model. The heat conduction pattern correlation analysis (intraclass correlation coefficient: 0.846, p < 0.001) and the heat conduction depth correlation analysis (intraclass correlation coefficient: 0.93, p < 0.001) showed statistically significant high correlations between the porcine burn wound and our model. Our model showed good correlation with porcine skin burn injury and replicated its heat conduction patterns.
Energy Technology Data Exchange (ETDEWEB)
Folsom, Charles [Utah State Univ., Logan, UT (United States). Mechanical and Aerospace Engineering Dept.; Xing, Changhu [Utah State Univ., Logan, UT (United States). Mechanical and Aerospace Engineering Dept.; Jensen, Colby [Utah State Univ., Logan, UT (United States). Mechanical and Aerospace Engineering Dept.; Ban, Heng [Utah State Univ., Logan, UT (United States). Mechanical and Aerospace Engineering Dept.; Marshall, Douglas W. [Idaho National Lab. (INL), Idaho Falls, ID (United States)
2015-03-01
Accurate modeling capability of thermal conductivity of tristructural-isotropic (TRISO) fuel compacts is important to fuel performance modeling and safety of Generation IV reactors. To date, the effective thermal conductivity (ETC) of tristructural-isotropic (TRISO) fuel compacts has not been measured directly. The composite fuel is a complicated structure comprised of layered particles in a graphite matrix. In this work, finite element modeling is used to validate an analytic ETC model for application to the composite fuel material for particle-volume fractions up to 40%. The effect of each individual layer of a TRISO particle is analyzed showing that the overall ETC of the compact is most sensitive to the outer layer constituent. In conjunction with the modeling results, the thermal conductivity of matrix-graphite compacts and the ETC of surrogate TRISO fuel compacts have been successfully measured using a previously developed measurement system. The ETC of the surrogate fuel compacts varies between 50 and 30 W m^{-1} K^{-1} over a temperature range of 50-600°C. As a result of the numerical modeling and experimental measurements of the fuel compacts, a new model and approach for analyzing the effect of compact constituent materials on ETC is proposed that can estimate the fuel compact ETC with approximately 15-20% more accuracy than the old method. Using the ETC model with measured thermal conductivity of the graphite matrix-only material indicate that, in the composite form, the matrix material has a much greater thermal conductivity, which is attributed to the high anisotropy of graphite thermal conductivity. Therefore, simpler measurements of individual TRISO compact constituents combined with an analytic ETC model, will not provide accurate predictions of overall ETC of the compacts emphasizing the need for measurements of composite, surrogate compacts.
Optimizing the transverse thermal conductivity of 2D-SiCf/SiC composites, I. Modeling
Energy Technology Data Exchange (ETDEWEB)
Youngblood, Gerald E.; Senor, David J.; Jones, Russell H.
2002-12-31
For potential fusion applications, considerable fabrication efforts have been directed to obtaining transverse thermal conductivity (Keff) values in excess of 30 W/mK (unirradiated) in the 800-1000°C temperature range for 2D-SiCf/SiC composites. To gain insight into the factors affecting Keff, at PNNL we have tested three different analytic models for predicting Keff in terms of constituent (fiber, matrix and interphase) properties. The tested models were: the Hasselman-Johnson (H-J) “2-Cylinder” model, which examines the effects of fiber-matrix (f/m) thermal barriers; the Markworth “3-Cylinder” model, which specifically examines the effects of interphase thickness and thermal conductivity; and a newly-developed Anisotropic “3-Square” model, which examines the potential effect of introducing a fiber coating with anisotropic properties to enhance (or diminish) f/m thermal coupling. The first two models are effective medium models, while the third model is a simple combination of parallel and series conductances. Model predictions suggest specific designs and/or development efforts directed to optimize the overall thermal transport performance of 2D-SiCf/SiC.
Kumar, Prashant; Topin, Frédéric
2017-08-01
It is often desirable to predict the effective thermal conductivity (ETC) of a homogenous material like open-cell foams based on its composition, particularly when variations in composition are expected. A combination of five fundamental simplified thermal conductivity bounds and models (series, parallel, Hashin-Shtrikman, effective medium theory, and reciprocity models) is proposed to predict ETC of open-cell foams. Usually, these models use a parameter as the weighted mean to account the proportion of each bound arranged in arithmetic and geometric schemes. Based on ETC data obtained on numerous virtual Kelvin-like foam samples, the dependence of this parameter has been deduced as a function of morphology and phase thermal conductivity ratio. Various effective thermal conductivity correlations are derived based on material properties and foam structure. This is valid for open-cell foams filled with any arbitrary working fluid over a solid conductivity of materials range (λs /λf = 10-30,000) and over a wide range of porosity (0.60 < ɛo < 0.95). Arrangement of series and parallel models together using the simplest models for both, arithmetic and geometric schemes, is found to predict excellent results among all the generic combinations.
Kumar, Prashant; Topin, Frédéric
2017-02-01
It is often desirable to predict the effective thermal conductivity (ETC) of a homogenous material like open-cell foams based on its composition, particularly when variations in composition are expected. A combination of five fundamental simplified thermal conductivity bounds and models (series, parallel, Hashin-Shtrikman, effective medium theory, and reciprocity models) is proposed to predict ETC of open-cell foams. Usually, these models use a parameter as the weighted mean to account the proportion of each bound arranged in arithmetic and geometric schemes. Based on ETC data obtained on numerous virtual Kelvin-like foam samples, the dependence of this parameter has been deduced as a function of morphology and phase thermal conductivity ratio. Various effective thermal conductivity correlations are derived based on material properties and foam structure. This is valid for open-cell foams filled with any arbitrary working fluid over a solid conductivity of materials range (λs /λf = 10-30,000) and over a wide range of porosity (0.60 < &epsilono < 0.95). Arrangement of series and parallel models together using the simplest models for both, arithmetic and geometric schemes, is found to predict excellent results among all the generic combinations.
Low Conductivity Thermal Barrier Coatings
Zhu, Dong-Ming
2005-01-01
Thermal barrier coatings will be more aggressively designed to protect gas turbine engine hot-section components in order to meet future engine higher fuel efficiency and lower emission goals. In this presentation, thermal barrier coating development considerations and requirements will be discussed. An experimental approach is established to monitor in real time the thermal conductivity of the coating systems subjected to high-heat-flux, steady-state and cyclic temperature gradients. Advanced low conductivity thermal barrier coatings have also been developed using a multi-component defect clustering approach, and shown to have improved thermal stability. The durability and erosion resistance of low conductivity thermal barrier coatings have been improved utilizing advanced coating architecture design, composition optimization, in conjunction with more sophisticated modeling and design tools.
Thermal conductivity of local moment models with strong spin-orbit coupling
Stamokostas, Georgios L.; Lapas, Panteleimon E.; Fiete, Gregory A.
2017-02-01
We study the magnetic and lattice contributions to the thermal conductivity of electrically insulating strongly spin-orbit coupled magnetically ordered phases on a two-dimensional honeycomb lattice using the Kitaev-Heisenberg model. Depending on model parameters, such as the relative strength of the spin-orbit induced anisotropic coupling, a number of magnetically ordered phases are possible. In this work, we study two distinct regimes of thermal transport depending on whether the characteristic energy of the phonons or the magnons dominates, and focus on two different relaxation mechanisms, boundary scattering and magnon-phonon scattering. For spatially anisotropic magnetic phases, the thermal conductivity tensor can be highly anisotropic when the magnetic energy scale dominates, since the magnetic degrees of freedom dominate the thermal transport for temperatures well below the magnetic transition temperature. In the opposite limit in which the phonon energy scale dominates, the thermal conductivity will be nearly isotropic, reflecting the isotropic (at low temperatures) phonon dispersion assumed for the honeycomb lattice. We further discuss the extent to which thermal transport properties are influenced by strong spin-orbit induced anisotropic coupling in the local moment regime of insulating magnetic phases. The developed methodology can be applied to any 2D magnon-phonon system, and more importantly to systems where an analytical Bogoliubov transformation cannot be found and magnon bands are not necessarily isotropic.
A Model to Predict Thermal Conductivity of Irradiated U-Mo Dispersion Fuel
Energy Technology Data Exchange (ETDEWEB)
Burkes, Douglas; Huber, Tanja K.; Casella, Andrew M.
2016-05-01
The Office of Materials Management and Minimization Reactor Conversion Program continues to develop existing and new research and test reactor fuels to achieve maximum attainable uranium loadings to support the conversion of a number of the world’s remaining high-enriched uranium fueled reactors to low-enriched uranium fuel. The program is focused on assisting with the development and qualification of a fuel design that consists of a uranium-molybdenum (U-Mo) alloy dispersed in an aluminum matrix as one option for reactor conversion. Thermal conductivity is an important consideration in determining the operational temperature of the fuel and can be influenced by interaction layer formation between the dispersed phase and matrix and upon the concentration of the dispersed phase within the matrix. This paper extends the use of a simple model developed previously to study the influence of interaction layer formation as well as the size and volume fraction of fuel particles dispersed in the matrix, Si additions to the matrix, and Mo concentration in the fuel particles on the effective thermal conductivity of the U-Mo/Al composite during irradiation. The model has been compared to experimental measurements recently conducted on U-Mo/Al dispersion fuels at two different fission densities with acceptable agreement. Observations of the modeled results indicate that formation of an interaction layer and subsequent consumption of the matrix reveals a rather significant effect on effective thermal conductivity. The modeled interaction layer formation and subsequent consumption of the high thermal conductivity matrix was sensitive to the average dispersed fuel particle size, suggesting this parameter as one of the most effective in minimizing thermal conductivity degradation of the composite, while the influence of Si additions to the matrix in the model was highly dependent upon irradiation conditions.
A model to predict thermal conductivity of irradiated U-Mo dispersion fuel
Burkes, Douglas E.; Huber, Tanja K.; Casella, Andrew M.
2016-05-01
Numerous global programs are focused on the continued development of existing and new research and test reactor fuels to achieve maximum attainable uranium loadings to support the conversion of a number of the world's remaining high-enriched uranium fueled reactors to low-enriched uranium fuel. Some of these programs are focused on assisting with the development and qualification of a fuel design that consists of a uranium-molybdenum (U-Mo) alloy dispersed in an aluminum matrix as one option for reactor conversion. Thermal conductivity is an important consideration in determining the operational temperature of the fuel and can be influenced by interaction layer formation between the dispersed phase and matrix and upon the concentration of the dispersed phase within the matrix. This paper extends the use of a simple model developed previously to study the influence of interaction layer formation as well as the size and volume fraction of fuel particles dispersed in the matrix, Si additions to the matrix, and Mo concentration in the fuel particles on the effective thermal conductivity of the U-Mo/Al composite during irradiation. The model has been compared to experimental measurements recently conducted on U-Mo/Al dispersion fuels at two different fission densities with acceptable agreement. Observations of the modeled results indicate that formation of an interaction layer and subsequent consumption of the matrix reveals a rather significant effect on effective thermal conductivity. The modeled interaction layer formation and subsequent consumption of the high thermal conductivity matrix was sensitive to the average dispersed fuel particle size, suggesting this parameter as one of the most effective in minimizing thermal conductivity degradation of the composite, while the influence of Si additions to the matrix in the model was highly dependent upon irradiation conditions.
A Model of Thermal Conductivity for Planetary Soils. 2; Theory for Cemented Soils
Piqueux, S.; Christensen, P. R.
2009-01-01
A numerical model of heat conduction through particulate media made of spherical grains cemented by various bonding agents is presented. The pore-filling gas conductivity, volume fraction, and thermal conductivity of the cementing phase are tunable parameters. Cement fractions conductivity. A significant conductivity increase (factor 3-8) is observed for bond fractions of 0.01 to 1% in volume. In the 1 to 15% bond fraction domain, the conductivity increases continuously but less intensely (25-100% conductivity increase compared to a 1% bond system). Beyond 15% of cements, the conductivity increases vigorously and the bulk conductivity rapidly approaches that of bedrock. The composition of the cements (i.e. conductivity) has little influence on the bulk thermal inertia of the soil, especially if the volume of bond <10%. These results indicate that temperature measurements are sufficient to detect cemented soils and quantify the amount of cementing phase, but the mineralogical nature of the bonds and the typical grain size are unlikely to be determined from orbit. On Mars, a widespread surface unit characterized by a medium albedo (0.19-0.26) and medium/high thermal inertia (200-600 J s(0.5)/sq m/K) has long been hypothesized to be associated with a duricrust. The fraction of cement required to fit the thermal data is less than approx.1-5% by volume. This small amount of material is consistent with orbital observations, confirming that soil cementation is an important factor controlling the thermal inertia of the Martian surface
Effective Thermal Conductivity For Drift-Scale Models Used In TSPA-SR
Energy Technology Data Exchange (ETDEWEB)
N.D. Francis
2001-01-25
The objective of this calculation is to develop a time dependent in-drift effective thermal conductivity parameter that will approximate heat conduction, thermal radiation, and natural convection heat transfer using a single mode of heat transfer (heat conduction). In order to reduce the physical and numerical complexity of the heat transfer processes that occur (and must be modeled) as a result of the emplacement of heat generating wastes, a single parameter will be developed that approximates all forms of heat transfer from the waste package surface to the drift wall (or from one surface exchanging heat with another). Subsequently, with this single parameter, one heat transfer mechanism (e.g., conduction heat transfer) can be used in the models. The resulting parameter is to be used as input in the drift-scale process-level models applied in total system performance assessments for the site recommendation (TSPA-SR). The format of this parameter will be a time-dependent table for direct input into the thermal-hydrologic (TH) and the thermal-hydrologic-chemical (THC) models.
Highly Thermal Conductive Nanocomposites
Sun, Ya-Ping (Inventor); Connell, John W. (Inventor); Veca, Lucia Monica (Inventor)
2015-01-01
Disclosed are methods for forming carbon-based fillers as may be utilized in forming highly thermal conductive nanocomposite materials. Formation methods include treatment of an expanded graphite with an alcohol/water mixture followed by further exfoliation of the graphite to form extremely thin carbon nanosheets that are on the order of between about 2 and about 10 nanometers in thickness. Disclosed carbon nanosheets can be functionalized and/or can be incorporated in nanocomposites with extremely high thermal conductivities. Disclosed methods and materials can prove highly valuable in many technological applications including, for instance, in formation of heat management materials for protective clothing and as may be useful in space exploration or in others that require efficient yet light-weight and flexible thermal management solutions.
Gheribi, Aïmen E.; Poncsák, Sándor; Guérard, Sébastien; Bilodeau, Jean-François; Kiss, László; Chartrand, Patrice
2017-03-01
During aluminium electrolysis, a ledge of frozen electrolytes is generally formed, attached to the sides of the cells. This ledge acts as a protective layer, preventing erosion and chemical attacks of both the electrolyte melt and the liquid aluminium on the side wall materials. The control of the sideledge thickness is thus essential in ensuring a reasonable lifetime for the cells. The key property for modelling and predicting the sideledge thickness as a function of temperature and electrolyte composition is the thermal conductivity. Unfortunately, almost no data is available on the thermal conductivity of the sideledge. The aim of this work is to alleviate this lack of data. For seven different samples of sideledge microstructures, recovered from post-mortem industrial electrolysis cells, the thermal diffusivity, the density, and the phase compositions were measured in the temperature range of 423 K to 873 K. The thermal diffusivity was measured with a laser flash technique and the average phase compositions by X-ray diffraction analysis. The thermal conductivity of the sideledge is deduced from the present experimental thermal diffusivity and density, and the thermodynamically assessed heat capacity. In addition to the present experimental work, a theoretical model for the prediction of the effective thermal transport properties of the sideledge microstructure is also proposed. The proposed model considers an equivalent microstructure and depends on phase fractions, porosity, and temperature. The strength of the model lies in the fact that only a few key physical properties are required for its parametrization and they can be predicted with a good accuracy via first principles calculations. It is shown that the theoretical predictions are in a good agreement with the present experimental measurements.
Volkov, Alexey N.; Salaway, Richard N.; Zhigilei, Leonid V.
2013-09-01
The propensity of carbon nanotubes (CNTs) to self-organize into continuous networks of bundles has direct implications for thermal transport properties of CNT network materials and defines the importance of clear understanding of the mechanisms and scaling laws governing the heat transfer within the primary building blocks of the network structures—close-packed bundles of CNTs. A comprehensive study of the thermal conductivity of CNT bundles is performed with a combination of non-equilibrium molecular dynamics (MD) simulations of heat transfer between adjacent CNTs and the intrinsic conductivity of CNTs in a bundle with a theoretical analysis that reveals the connections between the structure and thermal transport properties of CNT bundles. The results of MD simulations of heat transfer in CNT bundles consisting of up to 7 CNTs suggest that, contrary to the widespread notion of strongly reduced conductivity of CNTs in bundles, van der Waals interactions between defect-free well-aligned CNTs in a bundle have negligible effect on the intrinsic conductivity of the CNTs. The simulations of inter-tube heat conduction performed for partially overlapping parallel CNTs indicate that the conductance through the overlap region is proportional to the length of the overlap for CNTs and CNT-CNT overlaps longer than several tens of nm. Based on the predictions of the MD simulations, a mesoscopic-level model is developed and applied for theoretical analysis and numerical modeling of heat transfer in bundles consisting of CNTs with infinitely large and finite intrinsic thermal conductivities. The general scaling laws predicting the quadratic dependence of the bundle conductivity on the length of individual CNTs in the case when the thermal transport is controlled by the inter-tube conductance and the independence of the CNT length in another limiting case when the intrinsic conductivity of CNTs plays the dominant role are derived. An application of the scaling laws to bundles of
Mathematical model for solar drying of potato cylinders with thermal conductivity radially modulated
Trujillo Arredondo, Mariana
2014-05-01
A mathematical model for drying potato cylinders using solar radiation is proposed and solved analytically. The model incorporates the energy balance for the heat capacity of the potato, the radiation heat transfer from the potato toward the drying chamber and the solar radiation absorbed by the potato during the drying process. Potato cylinders are assumed to exhibit a thermal conductivity which is radially modulated. The method of the Laplace transform, with integral Bromwich and residue theorem will be applied and the analytic solutions for the temperature profiles in the potato cylinder will be derived in the form of an infinite series of Bessel functions, when the thermal conductivity is constant; and in the form of an infinite series of Heun functions, when the thermal conductivity has a linear radial modulation. All computations are performed using computer algebra, specifically Maple. It is expected that the analytical results obtained will be useful in food engineering and industry. Our results suggest some lines for future investigations such as the adoption of more general forms of radial modulation for the thermal conductivity of potato cylinders; and possible applications of other computer algebra software such as Maxima and Mathematica.
Two-phase numerical model for thermal conductivity and convective heat transfer in nanofluids.
Kondaraju, Sasidhar; Lee, Joon Sang
2011-03-21
Due to the numerous applications of nanofluids, investigating and understanding of thermophysical properties of nanofluids has currently become one of the core issues. Although numerous theoretical and numerical models have been developed by previous researchers to understand the mechanism of enhanced heat transfer in nanofluids; to the best of our knowledge these models were limited to the study of either thermal conductivity or convective heat transfer of nanofluids. We have developed a numerical model which can estimate the enhancement in both the thermal conductivity and convective heat transfer in nanofluids. It also aids in understanding the mechanism of heat transfer enhancement. The study reveals that the nanoparticle dispersion in fluid medium and nanoparticle heat transport phenomenon are equally important in enhancement of thermal conductivity. However, the enhancement in convective heat transfer was caused mainly due to the nanoparticle heat transport mechanism. Ability of this model to be able to understand the mechanism of convective heat transfer enhancement distinguishes the model from rest of the available numerical models.
Byrd, N. R.; Jenkins, R. K.; Lister, J. L. (Inventor)
1971-01-01
A thermally conductive polymer is provided having physical and chemical properties suited to use as a medium for potting electrical components. The polymer is prepared from hydroquinone, phenol, and formaldehyde, by conventional procedures employed for the preparation of phenol-formaldehyde resins. While the proportions of the monomers can be varied, a preferred polymer is formed from the monomers in a 1:1:2.4 molar or ratio of hydroquinone:phenol:formaldehyde.
Energy Technology Data Exchange (ETDEWEB)
Dhuley, R. C. [Fermilab; Hollister, M. I. [Fermilab; Ruschman, M. K. [Fermilab; Martin, L. D. [Fermilab; Schmitt, R. L. [Fermilab; Tatkowski, Tatkowski,G.L. [Fermilab; Bauer, D. a. [Fermilab; Lukens, P. T. [Fermilab
2017-09-13
The detectors of the Super Cryogenic Dark Matter Search experiment at SNOLAB (SuperCDMS SNOLAB) will operate in a seven-layered cryostat with thermal stages between room temperature and the base temperature of 15 mK. The inner three layers of the cryostat, which are to be nominally maintained at 1 K, 250 mK, and 15 mK, will be cooled by a dilution refrigerator via conduction through long copper stems. Bolted and mechanically pressed contacts, at and cylindrical, as well as exible straps are the essential stem components that will facilitate assembly/dismantling of the cryostat. These will also allow for thermal contractions/movements during cooldown of the sub-Kelvin system. To ensure that these components and their contacts meet their design thermal conductance, prototypes were fabricated and cryogenically tested. The present paper gives an overview of the SuperCDMS SNOLAB sub-Kelvin architecture and its conductance requirements. Results from the conductance measurements tests and from sub-Kelvin thermal modeling are discussed.
Lattice Thermal Conductivity of Superlattices from an Adiabatic Bond Charge Model
Ward, Alistair; Broido, David
2007-03-01
The adiabatic bond charge model (ABCM) has successfully rendered phonon dispersions of a host of bulk semiconductors [1,2] and has also been used to calculate the phonon dispersions in quantum well superlattices [3]. We have developed an ABCM for superlattices and combined it with a symmetry-based representation of the anharmonic interatomic forces to calculate the lattice thermal conductivity of short-period superlattices, using an iterative solution to the Boltzmann-Peierls equation [4]. We compare our ABCM results with those obtained from some commonly used models for the interatomic forces in semiconductors to assess the importance of accurate descriptions of the phonon dispersions in thermal conductivity calculations. [1] W. Weber, Physical Review B 15, 4789 (1977). [2] K. C. Rustagi and W. Weber, Solid State Communications 18, 673 (1976). [3] S. K. Yip and Y. C. Chang, Physical Review B 30 7037 (1984). [4] D. A. Broido, A. Ward, and N. Mingo, Physical Review B 72, 014308 (2005).
Madhusudana, Chakravarti V
2013-01-01
The work covers bothÂ theoretical and practical aspects of thermal contact conductance. The theoretical discussionÂ focuses onÂ heat transfer through spots, joints, and surfaces, as well as the role of interstitial materials (both planned and inadvertent). The practical discussion includes formulae and data that can be used in designing heat-transfer equipment for a variety of joints, including special geometries and configurations. All of the material has been updated to reflect the latest advances in the field.
Ji, Pengfei
2016-01-01
By combining ab initio quantum mechanics calculation and Drude model, electron temperature and lattice temperature dependent electron thermal conductivity is calculated and implemented into a multiscale model of laser material interaction, which couples the classical molecular dynamics and two-temperature model. The results indicated that the electron thermal conductivity obtained from ab initio calculation leads to faster thermal diffusion than that using the electron thermal conductivity from empirical determination, which further induces deeper melting region, larger number of density waves travelling inside the copper film and more various speeds of atomic clusters ablated from the irradiated film surface.
Variable Temperature Blackbodies via Variable Conductance: Thermal Design, Modelling and Testing
Melzack, N.; Jones, E.; Peters, D. M.; Hurley, J. G.; Watkins, R. E. J.; Fok, S.; Sawyer, C.; Marchetaux, G.; Acreman, A.; Winkler, R.; Lowe, D.; Theocharous, T.; Montag, V.; Gibbs, D.; Pearce, A. B.; Bishop, G.; Newman, E.; Keen, S.; Stokes, J.; Pearce, A.; Stamper, R.; Cantell-Hynes, A.
2017-02-01
This paper presents the overall design for large (˜ 400 mm aperture) reference blackbody cavities currently under development at the Science and Technology Facilities Council Rutherford Appleton Laboratory Space Department (STFC RAL Space), in collaboration with the National Physical Laboratory (NPL). These blackbodies are designed to operate in vacuum over a temperature range from 160 K to 370 K, with an additional capability to operate at ˜ 100 K as a point of near-zero radiance. This is a challenging problem for a single blackbody. The novel thermal design presented in this paper enables one target that can physically achieve and operate successfully at both thermal extremes, whilst also meeting stringent temperature gradient requirements. The overall blackbody design is based upon a helium gas-gap heat switch and modified to allow for variable thermal conductance. The blackbody design consists of three main concentric cylinder components—an inner cavity (aluminium alloy), a radiation shield (aluminium) and an outer liquid nitrogen (LN2) jacket (stainless steel). The internal surface of the cavity is the effective radiating surface. There is a helium gas interspace surrounding the radiation shield and enclosed by the LN2 jacket and the inner cavity. The blackbodies are now at a mature stage of development. In this paper, the overall design, focusing upon the thermal design solution, is detailed. This paper will also concern the full-scale prototype breadboard model, for which results on thermal stability, spatial gradients and other sensitivities will be presented.
Thermal conductivity of thermal-battery insulations
Energy Technology Data Exchange (ETDEWEB)
Guidotti, R.A.; Moss, M.
1995-08-01
The thermal conductivities of a variety of insulating materials used in thermal batteries were measured in atmospheres of argon and helium using several techniques. (Helium was used to simulate the hydrogen atmosphere that results when a Li(Si)/FeS{sub 2} thermal battery ages.) The guarded-hot-plate method was used with the Min-K insulation because of its extremely low thermal conductivity. For comparison purposes, the thermal conductivity of the Min-K insulating board was also measured using the hot-probe method. The thermal-comparator method was used for the rigid Fiberfrax board and Fiberfrax paper. The thermal conductivity of the paper was measured under several levels of compression to simulate the conditions of the insulating wrap used on the stack in a thermal battery. The results of preliminary thermal-characterization tests with several silica aerogel materials are also presented.
Energy Technology Data Exchange (ETDEWEB)
Kukkonen, I.; Suppala, I. [Geological Survey of Finland, Espoo (Finland)
1999-01-01
In situ measurements of thermal conductivity and diffusivity of bedrock were investigated with the aid of a literature survey and theoretical simulations of a measurement system. According to the surveyed literature, in situ methods can be divided into `active` drill hole methods, and `passive` indirect methods utilizing other drill hole measurements together with cutting samples and petrophysical relationships. The most common active drill hole method is a cylindrical heat producing probe whose temperature is registered as a function of time. The temperature response can be calculated and interpreted with the aid of analytical solutions of the cylindrical heat conduction equation, particularly the solution for an infinite perfectly conducting cylindrical probe in a homogeneous medium, and the solution for a line source of heat in a medium. Using both forward and inverse modellings, a theoretical measurement system was analysed with an aim at finding the basic parameters for construction of a practical measurement system. The results indicate that thermal conductivity can be relatively well estimated with borehole measurements, whereas thermal diffusivity is much more sensitive to various disturbing factors, such as thermal contact resistance and variations in probe parameters. In addition, the three-dimensional conduction effects were investigated to find out the magnitude of axial `leak` of heat in long-duration experiments. The radius of influence of a drill hole measurement is mainly dependent on the duration of the experiment. Assuming typical conductivity and diffusivity values of crystalline rocks, the measurement yields information within less than a metre from the drill hole, when the experiment lasts about 24 hours. We propose the following factors to be taken as basic parameters in the construction of a practical measurement system: the probe length 1.5-2 m, heating power 5-20 Wm{sup -1}, temperature recording with 5-7 sensors placed along the probe, and
Indian Academy of Sciences (India)
Jagjiwanram; Ramvir Singh
2004-08-01
A theoretical model has been developed for real two-phase system assuming linear flow of heat flux lines having ellipsoidal particles arranged in a three-dimensional cubic array. The arrangement has been divided into unit cells, each of which contains an ellipsoid. The resistor model has been applied to determine the effective thermal conductivity (ETC) of the unit cell. To take account of random packing of the phases, non-uniform shape of the particles and non-linear flow of heat flux lines in real systems, incorporating an empirical correction factor in place of physical porosity modifies an expression for ETC. An effort is made to correlate it in terms of the ratio of thermal conductivities of the constituents and the physical porosity. Theoretical expression so obtained has been tested on a large number of samples cited in the literature and found that the values predicted are quite close to the experimental results. Comparison of our model with different models cited in the literature has also been made.
Kochetov, R.; Korobko, A.V.; Andritsch, T.; Morshuis, P.H.F.; Picken, S.J.; Smit, J.J.
2011-01-01
In this paper the thermal conductivity of epoxy-based composite materials is analysed. Two and three-phase Lewis–Nielsen models are proposed for fitting the experimental values of the thermal conductivity of epoxy-based polymer composites. Various inorganic nano- and microparticles were used, namely
The prediction model of thermal conductivity of sand-bentonite based buffer material
Energy Technology Data Exchange (ETDEWEB)
Tien, Y.M.; Chu, C.A. [National Central University, Dpt. of Civil Engineering, Taiwan (China); Chuangz, W.S. [Institute of Nuclear Energy Research, Atomic Energy Council, Taiwan (China)
2005-07-01
The thermal conductivity of sand-bentonite based buffer materials is a key factor for the design of HLW depository. In the Thermal-Hydraulic-Mechanical environment, the thermal conductivity varies due to the change in clay density, the water content, and the volumetric fraction of sand or crushed granite. In this article, an improved thermal probe method for the measurement of thermal conductivity is proposed. The probe is placed within the sand-bentonite powder inside the specially designed mold which the volume can be controlled by the position of the compacting piston. While the clay density reaches to a designated level, the measurement is executed to evaluate the thermal conductivity. With repeating the procedure, the relationship of clay dry density and the thermal conductivity can be established in one specimen. The weight water content of the bentonite is adjusted by placing in a humid chamber or in an oven for different periods. The relationship of thermal conductivity with clay dry density, water content, and sand or crushed granite is well established in this article. (authors)
A Model for Hydrogen Thermal Conductivity and Viscosity Including the Critical Point
Wagner, Howard A.; Tunc, Gokturk; Bayazitoglu, Yildiz
2001-01-01
In order to conduct a thermal analysis of heat transfer to liquid hydrogen near the critical point, an accurate understanding of the thermal transport properties is required. A review of the available literature on hydrogen transport properties identified a lack of useful equations to predict the thermal conductivity and viscosity of liquid hydrogen. The tables published by the National Bureau of Standards were used to perform a series of curve fits to generate the needed correlation equations. These equations give the thermal conductivity and viscosity of hydrogen below 100 K. They agree with the published NBS tables, with less than a 1.5 percent error for temperatures below 100 K and pressures from the triple point to 1000 KPa. These equations also capture the divergence in the thermal conductivity at the critical point
Bui, Khoa; Papavassiliou, Dimitrios
2012-02-01
The effective thermal conductivity (Keff) of carbon nanotube (CNT) composites is affected by the thermal boundary resistance (TBR) and by the dispersion pattern and geometry of the CNTs. We have previously modeled CNTs as straight cylinders and found that the TBR between CNTs (TBRCNT-CNT) can suppress Keff at high volume fractions of CNTs [1]. Effective medium theory results assume that the CNTs are in a perfect dispersion state and exclude the TBRCNT-CNT [2]. In this work, we report on the development of an algorithm for generating CNTs with worm-like geometry in 3D, and with different persistence lengths. These worm-like CNTs are then randomly placed in a periodic box representing a realistic state, since the persistence length of a CNT can be obtained from microscopic images. The use of these CNT geometries in conjunction with off-lattice Monte Carlo simulations [1] in order to study the effective thermal properties of nanocomposites will be discussed, as well as the effects of the persistence length on Keff and comparisons to straight cylinder models. References [1] K. Bui, B.P. Grady, D.V. Papavassiliou, Chem. Phys. Let., 508(4-6), 248-251, 2011 [2] C.W. Nan, G. Liu, Y. Lin, M. Li, App. Phys. Let., 85(16), 3549-3551, 2006
Shape memory thermal conduction switch
Vaidyanathan, Rajan (Inventor); Krishnan, Vinu (Inventor); Notardonato, William U. (Inventor)
2010-01-01
A thermal conduction switch includes a thermally-conductive first member having a first thermal contacting structure for securing the first member as a stationary member to a thermally regulated body or a body requiring thermal regulation. A movable thermally-conductive second member has a second thermal contacting surface. A thermally conductive coupler is interposed between the first member and the second member for thermally coupling the first member to the second member. At least one control spring is coupled between the first member and the second member. The control spring includes a NiTiFe comprising shape memory (SM) material that provides a phase change temperature <273 K, a transformation range <40 K, and a hysteresis of <10 K. A bias spring is between the first member and the second member. At the phase change the switch provides a distance change (displacement) between first and second member by at least 1 mm, such as 2 to 4 mm.
Radiative thermal conduction fronts
Borkowski, Kazimierz J.; Balbus, Steven A.; Fristrom, Carl C.
1990-01-01
The discovery of the O VI interstellar absorption lines in our Galaxy by the Copernicus observatory was a turning point in our understanding of the Interstellar Medium (ISM). It implied the presence of widespread hot (approx. 10 to the 6th power K) gas in disk galaxies. The detection of highly ionized species in quasi-stellar objects' absorption spectra may be the first indirect observation of this hot phase in external disk galaxies. Previous efforts to understand extensive O VI absorption line data from our Galaxy were not very successful in locating the regions where this absorption originates. The location at interfaces between evaporating ISM clouds and hot gas was favored, but recent studies of steady-state conduction fronts in spherical clouds by Ballet, Arnaud, and Rothenflug (1986) and Bohringer and Hartquist (1987) rejected evaporative fronts as the absorption sites. Researchers report here on time-dependent nonequilibrium calculations of planar conductive fronts whose properties match well with observations, and suggest reasons for the difference between the researchers' results and the above. They included magnetic fields in additional models, not reported here, and the conclusions are not affected by their presence.
High-Thermal-Conductivity Fabrics
Chibante, L. P. Felipe
2012-01-01
Heat management with common textiles such as nylon and spandex is hindered by the poor thermal conductivity from the skin surface to cooling surfaces. This innovation showed marked improvement in thermal conductivity of the individual fibers and tubing, as well as components assembled from them. The problem is centered on improving the heat removal of the liquid-cooled ventilation garments (LCVGs) used by astronauts. The current design uses an extensive network of water-cooling tubes that introduces bulkiness and discomfort, and increases fatigue. Range of motion and ease of movement are affected as well. The current technology is the same as developed during the Apollo program of the 1960s. Tubing material is hand-threaded through a spandex/nylon mesh layer, in a series of loops throughout the torso and limbs such that there is close, form-fitting contact with the user. Usually, there is a nylon liner layer to improve comfort. Circulating water is chilled by an external heat exchanger (sublimator). The purpose of this innovation is to produce new LCVG components with improved thermal conductivity. This was addressed using nanocomposite engineering incorporating high-thermalconductivity nanoscale fillers in the fabric and tubing components. Specifically, carbon nanotubes were added using normal processing methods such as thermoplastic melt mixing (compounding twin screw extruder) and downstream processing (fiber spinning, tubing extrusion). Fibers were produced as yarns and woven into fabric cloths. The application of isotropic nanofillers can be modeled using a modified Nielsen Model for conductive fillers in a matrix based on Einstein s viscosity model. This is a drop-in technology with no additional equipment needed. The loading is limited by the ability to maintain adequate dispersion. Undispersed materials will plug filtering screens in processing equipment. Generally, the viscosity increases were acceptable, and allowed the filled polymers to still be
Brannon, Sean
2014-01-01
Magnetic reconnection in the corona results in contracting flare loops, releasing energy into plasma heating and shocks. The hydrodynamic shocks so produced drive thermal conduction fronts (TCFs) which transport energy into the chromosphere and drive upflows (evaporation) and downflows (condensation) in the cooler, denser footpoint plasma. Observations have revealed that certain properties of the transition point between evaporation and condensation (the "flow reversal point" or FRP), such as temperature and velocity-temperature derivative at the FRP, vary between different flares. These properties may provide a diagnostic tool to determine parameters of the coronal energy release mechanism and the loop atmosphere. In this study, we develop a 1-D hydrodynamical flare loop model with a simplified three-region atmosphere (chromosphere/transition region/corona), with TCFs initiated by shocks introduced in the corona. We investigate the effect of two different flare loop parameters (post-shock temperature and tra...
Energy Technology Data Exchange (ETDEWEB)
Liu, Yan-Gai; Peng, Peng; Fang, Minghao; Huang, Zhaohui [School of Materials Science and Technology, China University of Geosciences, Beijing (China)
2012-03-15
Rare-earth aluminate ceramics for thermal-barrier coatings (TBCs) are synthesized. The Young's modulus and thermal properties decrease with erbium additive increasing. The Y{sub 3-x}Er{sub x}Al{sub 5}O{sub 12} ceramics (x=1,3) possess a much-lower thermal conductivity compared with 8YSZ. The lower Young's modulus and thermal-expansion coefficient are due to the larger atomic weight of the Er substitutional atom. Additional phonon-scattering effects also contribute to the lower thermal conductivity. The results indicate that Y{sub 3-x}Er{sub x}Al{sub 5}O{sub 12} can be explored as a candidate material for TBC systems. A theoretical model that describes the influence of point defects on the thermal conductivity is discussed. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Mahdavi, Seyed Mohamad; Neyshabouri, Mohammad Reza; Fujimaki, Haruyuki
2016-08-01
Simulation of heat transfer in soil under steady and unsteady situations requires reliable estimate of soil thermal conductivity (λ) at varying environmental conditions. In the current work several soil thermal conductivity predicting models including I) de Vries, II) Campbell, III) combined de Vries and Campbell and IV) de Vries-Nobre were evaluated for the four soils of coarse sand, sandy loam, loam and clay loam textured at varying in temperature and bulk density at low moisture range. Thermal conductivities measured by the cylindrical probe method served as the reference for models assessment. Results showed that approximately same thermal conductivities obtained by the five methods at low moisture range (θ ≤ 0.05 m3/m3). Also the de Vries and de Vries-Campbell models produced accurate than Campbell and de vries-Nobre models. The accuracy of the two models increased with soil compaction but decreased with temperature rise. Campbell model showed more reliability at higher (311.16 and 321.16 K) temperatures; but its accuracy declined with soil compaction in current work. It seems that assuming needle shape for the soil particles is far away from the reality whereas assuming spherical shapes may be more realistic and produced more satisfactory prediction of thermal conductivity. The compaction would alter particle arrangement and may increase the contact area of particles; and then make them behave more or less spherical shape.it seems thermal conductivity in solid particles increase via increasing in temperature. Since a modified mineral shape factor, g m , was developed as a combination between sphere and needle according to geometric mean particle diameter as well as bulk density and temperature as modifying factors. This factor increased the accuracy of de Vries-Nobre model up to 10.37%. Regarding nonlinear regression model, moisture content, bulk density, temperature and quartz content demonstrated significant effect on soil thermal conductivity in our
Effective Thermal Conductivity of Corrugated Insulating Materials
Yamada, Etsuro; Kato, Masayasu; Tomikawa, Takayuki; Takahashi, Kaneko
The effective thermal conductivity of corrugated insulating materials which are made by polypropylene or polycarbonate have been measured by employing steady state comparison method for several specimen having various thickness and specific weight. The thermal conductivity of them evaluated are also by using the thermal resistance models, and are compared with above measured values and raw materials' conductivity. The main results obtained in this paper are as follows: (1) In regard to the specimen in this paper, the effective thermal conductivity increases with increasing temperature, but the increasing rate of them is small. (2) There are considerable differences between the measured values and the predicted ones that are estimated by using the thermal resistance model in which heat flow by conduction only. This differences increase with increasing specimens' thickness. This difference become extinct by considering the coexistence heat flow of conduction and radiation in the air phase of specimen. (3) The thermal resistance of specimen increases linearly with increasing specimens' thickness.
THERMAL CONDUCTIVITY OF METALLIC WIRES
Institute of Scientific and Technical Information of China (English)
LU XIANG; GU JI-HUA; CHU JUN-HAO
2001-01-01
The effect of radial thickness on the thermal conductivity of a free standing wire is investigated. The thermal conductivity is evaluated using the Boltzmann equation. A simple expression for the reduction in conductivity due to the increase of boundary scattering is presented. A comparison is made between the experimental results of indium wires and the theoretical calculations. It is shown that this decrease of conductivity in wires is smaller than that in film where heat flux is perpendicular to the surface.
Brannon, Sean; Longcope, D.
2013-07-01
Magnetic reconnection in the corona results in contracting flare loops, releasing energy into plasma heating and shocks. These hydrodynamic shocks drive thermal conduction fronts (TCFs), which deposit energy into the chromosphere, driving upflows (evaporation) and downflows (condensation) across a range of temperatures. Observations have revealed that the transition between evaporation and condensation, the "velocity reversal point" (VRP), occurs at a characteristic temperature and with a characteristic slope, which vary between different flares. In this study, we develop a 1-D hydrodynamical flare loop model with a simplified three-region atmosphere (chromosphere / transition region (TR) / corona), with TCFs initiated by piston shocks introduced in the corona. We investigate the effect of three different flare loop parameters (post-shock temperature, TR temperature ratio, and TR thickness) on the temperature and slope of the VRP. We find that both of the evaporation characteristics have power-law relationships to the varied flare parameters, and we report the scaling exponents for our model. Finally, we develop a method to determine the best-fit post-shock temperature and TR temperature ratio based on the observed quantities, and discuss the results for two sets of published data.
Edrisi, Siroos; Bidhendi, Norollah Kasiri; Haghighi, Maryam
2017-01-01
Effective thermal conductivity of the porous media was modeled based on a self-consistent method. This model estimates the heat transfer between insulator surface and air cavities accurately. In this method, the pore size and shape, the temperature gradient and other thermodynamic properties of the fluid was taken into consideration. The results are validated by experimental data for fire bricks used in cracking furnaces at the olefin plant of Maroon petrochemical complexes well as data published for polyurethane foam (synthetic polymers) IPTM and IPM. The model predictions present a good agreement against experimental data with thermal conductivity deviating <1 %.
Effective Thermal Conductivity of Adsorbent Packed Beds
Mori, Hideo; Hamamoto, Yoshinori; Yoshida, Suguru
The effective thermal conductivity of adsorbent packed beds of granular zeolite 13X and granular silica gel A in the presence of stagnant steam or air was measured under different conditions of the adsorbent bed temperature, particle size and filler-gas pressure. The measured effective thermal conductivity showed to become smaller with decreasing particle size or decreasing pressure, but it was nearly independent of the bed temperature. When steam was the filler-gas, the rise in the thermal conductivity of the adsorbent particles due to steam adsorption led to the increase in the effective thermal conductivity of the bed, and this effect was not negligible at high steam pressure for the bed of large particle size. It was found that both the predictions of the effective thermal conductivity by the Hayashi et al.'s model and the Bauer-Schlünder model generally agreed well with the measurements, by considering the particle thermal conductivity rise due to steam adsorption. The thermal conductivity of a consolidated bed of granular zeolite 13X was also measured, and it was found to be much larger than that of the packed bed especially at lower pressure. The above prediction models underestimated the effective thermal conductivity of the consolidated bed.
Thermally conducting electron transfer polymers
Byrd, N. R.; Jenkins, R. K.; Lister, J. L.
1969-01-01
New polymeric material exhibits excellent physical shock protection, high electrical resistance, and thermal conductivity. It is especially useful for electronic circuitry, such as subminiaturization of components and modular construction of circuits.
Thermal conductivity of graphene laminate.
Malekpour, H; Chang, K-H; Chen, J-C; Lu, C-Y; Nika, D L; Novoselov, K S; Balandin, A A
2014-09-10
We have investigated thermal conductivity of graphene laminate films deposited on polyethylene terephthalate substrates. Two types of graphene laminate were studied, as deposited and compressed, in order to determine the physical parameters affecting the heat conduction the most. The measurements were performed using the optothermal Raman technique and a set of suspended samples with the graphene laminate thickness from 9 to 44 μm. The thermal conductivity of graphene laminate was found to be in the range from 40 to 90 W/mK at room temperature. It was found unexpectedly that the average size and the alignment of graphene flakes are more important parameters defining the heat conduction than the mass density of the graphene laminate. The thermal conductivity scales up linearly with the average graphene flake size in both uncompressed and compressed laminates. The compressed laminates have higher thermal conductivity for the same average flake size owing to better flake alignment. Coating plastic materials with thin graphene laminate films that have up to 600× higher thermal conductivity than plastics may have important practical implications.
Thermal Conductivity of Foam Glass
DEFF Research Database (Denmark)
Petersen, Rasmus Rosenlund; König, Jakob; Yue, Yuanzheng
Due to the increased focus on energy savings and waste recycling foam glass materials have gained increased attention. The production process of foam glass is a potential low-cost recycle option for challenging waste, e.g. CRT glass and industrial waste (fly ash and slags). Foam glass is used...... as thermal insulating material in building and chemical industry. The large volume of gas (porosity 90 – 95%) is the main reason of the low thermal conductivity of the foam glass. If gases with lower thermal conductivity compared to air are entrapped in the glass melt, the derived foam glass will contain...... only closed pores and its overall thermal conductivity will be much lower than that of the foam glass with open pores. In this work we have prepared foam glass using different types of recycled glasses and different kinds of foaming agents. This enabled the formation of foam glasses having gas cells...
Thermal conductivity of unsaturated clay-rocks
Directory of Open Access Journals (Sweden)
D. Jougnot
2010-01-01
Full Text Available The parameters used to describe the electrical conductivity of a porous material can be used to describe also its thermal conductivity. A new relationship is developed to connect the thermal conductivity of an unsaturated porous material to the thermal conductivity of the different phases of the composite, and two electrical parameters called the first and second Archie's exponents. A good agreement is obtained between the new model and thermal conductivity measurements performed using packs of glass beads and core samples of the Callovo-Oxfordian clay-rocks at different saturations of the water phase. We showed that the three model parameters optimised to fit the new model against experimental data (namely the thermal conductivity of the solid phase and the two Archie's exponents are consistent with independent estimates. We also observed that the anisotropy of the effective thermal conductivity of the Callovo-Oxfordian clay-rock was mainly due to the anisotropy of the thermal conductivity of the solid phase.
Minimum Thermal Conductivity of Superlattices
Energy Technology Data Exchange (ETDEWEB)
Simkin, M. V.; Mahan, G. D.
2000-01-31
The phonon thermal conductivity of a multilayer is calculated for transport perpendicular to the layers. There is a crossover between particle transport for thick layers to wave transport for thin layers. The calculations show that the conductivity has a minimum value for a layer thickness somewhat smaller then the mean free path of the phonons. (c) 2000 The American Physical Society.
Degueldre, C.; Arima, T.; Lee, Y. W.
2003-06-01
An inert matrix fuel material based on yttria-stabilized cubic zirconia: Er xY yPu zZr 1- x- y- zO 2-( x + y)/2 ( x+ y=0.15, z: [0.05-0.15]) was proposed for burning excess plutonium in light water reactors. The studied inert matrix fuel is made of cubic stabilized zirconia. The limited number of experimental thermal conductivity data justifies this formal and intensive study. Approaches derived from Klemens theory were revisited and the derived conductivity model applied for zirconia, accounting the effects of phononic scattering centers. The hyperbolic thermal conductivity trend with temperature known for pure zirconia, is reduced by isotopes, impurities, dopants and oxygen vacancies, which act as scattering centers and contribute to conductivity reduction to a flat plot with temperature for stabilized zirconia. It is experimentally observed that the thermal conductivity derived from laser flash measurements for Er xY yM zZr 1- x- y- zO 2-( x + y)/2 (with M=Ce or Pu, z=0 or ˜0.1 and x+ y=0.15) is rather constant as a function of temperature in the range 300-1000 K. The thermal conductivity was observed to depend on the concentration of dopants such as YO 1.5 and/or ErO 1.5, CeO 2 (analogous of PuO 2) or PuO 2. The bulk material conductivity of Er 0.05Y 0.10Pu 0.10Zr 0.75O 1.925 is about 2 W m -1 K -1. In this study, the thermal conductivity data of both monoclinic and stabilized cubic zirconia based IMF are tested with the model approach in order to understand the experimental data in a semi-quantitative way.
Equivalent thermal conductivity of heat pipes
Institute of Scientific and Technical Information of China (English)
Zesheng LU; Binghui MA
2008-01-01
In precision machining, the machining error from thermal distortion carries a high proportion of the total errors. If a precision machining tool can transfer heat fast, the thermal distortion will be reduced and the machining precision will be improved. A heat pipe working based on phase transitions of the inner working liquid transfers heat with high efficiency and is widely applied in spaceflight and chemical industries. In mechanics, applications of heat pipes are correspondingly less. When a heat pipe is applied to a hydrostatic motor-ized spindle, the thermal distortion cannot be solved dur-ing the heat transfer process because thermal conductivity or equivalent thermal conductivity should be provided first for special application in mechanics. An equivalent thermal conductivity model based on equivalent thermal resistances is established. Performance tests for a screen wick pipe, gravity pipe, and rotation heat pipe are done to validate the efficiency of the equivalent thermal conduc-tivity model. The proposed model provides a calculation method for the thermal distortion analysis of heat pipes applied in the motorized spindle.
Ahmed, Muneeb; Liu, Zhengjun; Humphries, Stanley; Goldberg, S Nahum
2008-11-01
To use an established computer simulation model of radiofrequency (RF) ablation to characterize the combined effects of varying perfusion, and electrical and thermal conductivity on RF heating. Two-compartment computer simulation of RF heating using 2-D and 3-D finite element analysis (ETherm) was performed in three phases (n = 88 matrices, 144 data points each). In each phase, RF application was systematically modeled on a clinically relevant template of application parameters (i.e., varying tumor and surrounding tissue perfusion: 0-5 kg/m(3)-s) for internally cooled 3 cm single and 2.5 cm cluster electrodes for tumor diameters ranging from 2-5 cm, and RF application times (6-20 min). In the first phase, outer thermal conductivity was changed to reflect three common clinical scenarios: soft tissue, fat, and ascites (0.5, 0.23, and 0.7 W/m- degrees C, respectively). In the second phase, electrical conductivity was changed to reflect different tumor electrical conductivities (0.5 and 4.0 S/m, representing soft tissue and adjuvant saline injection, respectively) and background electrical conductivity representing soft tissue, lung, and kidney (0.5, 0.1, and 3.3 S/m, respectively). In the third phase, the best and worst combinations of electrical and thermal conductivity characteristics were modeled in combination. Tissue heating patterns and the time required to heat the entire tumor +/-a 5 mm margin to >50 degrees C were assessed. Increasing background tissue thermal conductivity increases the time required to achieve a 50 degrees C isotherm for all tumor sizes and electrode types, but enabled ablation of a given tumor size at higher tissue perfusions. An inner thermal conductivity equivalent to soft tissue (0.5 W/m- degrees C) surrounded by fat (0.23 W/m- degrees C) permitted the greatest degree of tumor heating in the shortest time, while soft tissue surrounded by ascites (0.7 W/m- degrees C) took longer to achieve the 50 degrees C isotherm, and complete ablation
Thermal Conductivity of Diamond Composites
Directory of Open Access Journals (Sweden)
Fedor M. Shakhov
2009-12-01
Full Text Available A major problem challenging specialists in present-day materials sciences is the development of compact, cheap to fabricate heat sinks for electronic devices, primarily for computer processors, semiconductor lasers, high-power microchips, and electronics components. The materials currently used for heat sinks of such devices are aluminum and copper, with thermal conductivities of about 250 W/(m·K and 400 W/(m·K, respectively. Significantly, the thermal expansion coefficient of metals differs markedly from those of the materials employed in semiconductor electronics (mostly silicon; one should add here the low electrical resistivity metals possess. By contrast, natural single-crystal diamond is known to feature the highest thermal conductivity of all the bulk materials studied thus far, as high as 2,200 W/(m·K. Needless to say, it cannot be applied in heat removal technology because of high cost. Recently, SiC- and AlN-based ceramics have started enjoying wide use as heat sink materials; the thermal conductivity of such composites, however, is inferior to that of metals by nearly a factor two. This prompts a challenging scientific problem to develop diamond-based composites with thermal characteristics superior to those of aluminum and copper, adjustable thermal expansion coefficient, low electrical conductivity and a moderate cost, below that of the natural single-crystal diamond. The present review addresses this problem and appraises the results reached by now in studying the possibility of developing composites in diamond-containing systems with a view of obtaining materials with a high thermal conductivity.
Thermal conductivity of nanoscale thin nickel films
Institute of Scientific and Technical Information of China (English)
YUAN Shiping; JIANG Peixue
2005-01-01
The inhomogeneous non-equilibrium molecular dynamics (NEMD) scheme is applied to model phonon heat conduction in thin nickel films. The electronic contribution to the thermal conductivity of the film is deduced from the electrical conductivity through the use of the Wiedemann-Franz law. At the average temperature of T = 300 K, which is lower than the Debye temperature ()D = 450 K,the results show that in a film thickness range of about 1-11 nm, the calculated cross-plane thermal conductivity decreases almost linearly with the decreasing film thickness, exhibiting a remarkable reduction compared with the bulk value. The electrical and thermal conductivities are anisotropic in thin nickel films for the thickness under about 10 nm. The phonon mean free path is estimated and the size effect on the thermal conductivity is attributed to the reduction of the phonon mean free path according to the kinetic theory.
Thermal conductance through molecular wires
Segal, D; Nitzan, A; Segal, Dvira; Nitzan, Abraham; Hanggi, Peter
2003-01-01
We consider phononic heat transport through molecular chains connecting two thermal reservoirs. For relatively short molecules at normal temperatures heat conduction is dominated by the harmonic part of the molecular force-field. We develop a general theory for the heat conduction through harmonic chains in 3-dimensions. A Landauer-type expression for the heat conduction is obtained, in agreement with other recent studies. We use this formalism to study the heat conduction properties of alkanes. For relatively short (1-30 carbon atoms) chains the length and temperature dependence of the molecular heat conduction result from the balance of three factors: (i) The molecular frequency spectrum in relation to the frequency cutoff of the thermal reservoirs, (ii) the degree of localization of the molecular normal modes and (iii) the molecule-heat reservoirs coupling. The fact that molecular modes at different frequency regimes have different localization properties gives rise to intricate dependence of the heat cond...
INTERACTION MODELS FOR EFFECTIVE THERMAL AND ELECTRIC CONDUCTIVITIES OF CARBON NANOTUBE COMPOSITES
Institute of Scientific and Technical Information of China (English)
Fei Deng; Quanshui Zheng
2009-01-01
The present article provides supplementary information of previous works of ana-lytic models for predicting conductivity enhancements of carbon nanotube composites. The mod-els, though fairly simple, are able to take account of the effects of conductivity anisotropy, non-straightness, and aspect ratio of the CNT additives on the conductivity enhancement of the com-posite and to give predictions agreeing well with existing experimental data. The omitted detailed derivation of this model is demonstrated in the present article with a more systematical analysis, which may help with further development in this direction. Furthermore, the effects of various orientation distributions of CNTs are reported here for the first time. The information may be useful in design or fabrication technology of CNT composites for better or specified conductivities.
The Lattice and Thermal Radiation Conductivity of Thermal Barrier Coatings
Zhu, Dongming; Spuckler, Charles M.
2008-01-01
The lattice and radiation conductivity of thermal barrier coatings was evaluated using a laser heat flux approach. A diffusion model has been established to correlate the apparent thermal conductivity of the coating to the lattice and radiation conductivity. The radiation conductivity component can be expressed as a function of temperature and the scattering and absorption properties of the coating material. High temperature scattering and absorption of the coating systems can also be derived based on the testing results using the modeling approach. The model prediction is found to have good agreement with experimental observations.
Tawfik, Abdel Nasser; Hussein, M T
2016-01-01
In mean field approximation, the grand canonical potential of SU(3) Polyakov linear-$\\sigma$ model (PLSM) is analysed for chiral phase-transition, $\\sigma_l$ and $\\sigma_s$ and for deconfinement order-parameters, $\\phi$ and $\\phi^*$ of light- and strange-quarks, respectively. Various PLSM parameters are determined from the assumption of global minimization of the real part of the potential. Then, we have calculated the subtracted condensates ($\\Delta_{l,s}$). All these results are compared with recent lattice QCD simulations. Accordingly, essential PLSM parameters are determined. The modelling of the relaxation time is utilized in estimating the conductivity properties of the QCD matter in thermal medium, namely electric [$\\sigma_{el}(T)$] and heat [$\\kappa(T)$] conductivities. We found that the PLSM results on the electric conductivity and on the specific heat agree well with the available lattice QCD calculations. Also, we have calculated bulk and shear viscosities normalized to the thermal entropy, $\\xi/s$...
Colbert, Keegan; Naraghi, Mohammad; Boyd, James G.
2017-02-01
This paper presents a model and computational method to predict the steady-state performance of thermal flexure microactuators at high input powers and various levels of partial vacuum. The model accounts for nonlinear temperature dependence of material properties, heat loss due to radiation, and intra-device heat transfer by conduction across an air gap. The model is validated by comparing the model predictions with the experimentally measured voltage, current, and displacement at standard conditions, prior to adjusting for partial vacuum. In order to understand the effect of nonlinearities on model reliability, the predictions of six additional hypothetical models are considered where (1) intra-device heat transfer is neglected, (2) radiation is neglected, (3) the thermal conductivity of silicon is assumed to be temperature-independent, (4) the thermal conductivity of air is assumed to be temperature-independent, (5) the electrical resistivity of silicon is assumed to be linear in temperature, and (6) the thermal expansion coefficient of silicon is assumed to be temperature-independent. All factors except radiation were shown to have a significant influence on the device performance especially at high input powers. The experimentally validated full model is then employed to predict the effect of reduced air pressure on the displacement and heat transfer properties of the actuator. This aspect of the study targets applications of thermal actuators in controlled environments such as space applications, actuators used for in situ micropositioning and tensile testing inside electron microscopy chambers, or actuators incorporated into the design of MEMS resonators. It was demonstrated that the maximum actuator displacement is not a linear function of reduced pressure and that it reaches a maximum at a certain partial vacuum level.
Thermal conductivity of thermal barrier coatings
Energy Technology Data Exchange (ETDEWEB)
Klemens, P.G.; Gell, M. [Connecticut Univ., Storrs, CT (United States). Inst. of Materials Science
1998-05-01
In thermal barrier coatings and other ceramic oxides, heat is conducted by lattice waves, and also by a radiative component which becomes significant at high temperatures. The theory of heat conduction by lattice waves is reviewed in the equipartition limit (above room temperature). The conductivity is composed of contributions from a spectrum of waves, determined by the frequency dependent attenuation length. Interaction between lattice waves (intrinsic processes), scattering by atomic scale point defects and scattering by extended imperfections such as grain boundaries, each limit the attenuation length in different parts of the spectrum. Intrinsic processes yield a spectral conductivity which is independent of frequency. Point defects reduce the contribution of the high frequency spectrum, grain boundaries and other extended defects that of the low frequencies. These reductions are usually independent of each other. Estimates will be given for zirconia containing 7wt% Y{sub 2}O{sub 3}, and for yttrium aluminum garnet. They will be compared to measurements. The effects of grain size, cracks and porosity will be discussed both for the lattice and the radiative components. While the lattice component of the thermal conductivity is reduced substantially by decreasing the grain size to nanometers, the radiative component requires pores or other inclusions of micrometer scale. (orig.) 9 refs.
Thermal radiation of conducting nanoparticles
Martynenko, Y V; Martynenko, Yu. V.
2005-01-01
A simple and universal criterion was obtained for the thermal radiation energy loss efficiency by small conductive particles which include along with metals and graphite also most practically important metal carbides like tungsten carbide, titanium carbide and the number of others.
Henke, Stephan; Trieloff, Mario
2016-01-01
The construction of models for the internal constitution and the temporal evolution of large planetesimals, the parent bodies of chondrites, requires information on the heat conductivity of the complex mixture of minerals and iron metal found in chondrites. It is attempted to evaluate the heat conductivity of a multi-component mineral mixture and granular medium from the heat conductivities of its mixture components. Random mixtures of solids with chondritic composition and packings of spheres are numerically generated. The heat conduction equation is solved in high spatial resolution for a test cube filled with such matter. From the heat flux through the cube the heat conductivity of the mixture is derived. The model results for porous material are consistent with data for compacted sandstone, but are at odds with measurements for H and L chondrites. The discrepancy is traced back to shock modification of the currently available meteoritic material by impacts on the parent body over the last 4.5 Ga. This cau...
Energy Technology Data Exchange (ETDEWEB)
Huang, Hai; Plummer, Mitchell; Podgorney, Robert
2013-02-01
Advancement of EGS requires improved prediction of fracture development and growth during reservoir stimulation and long-term operation. This, in turn, requires better understanding of the dynamics of the strongly coupled thermo-hydro-mechanical (THM) processes within fractured rocks. We have developed a physically based rock deformation and fracture propagation simulator by using a quasi-static discrete element model (DEM) to model mechanical rock deformation and fracture propagation induced by thermal stress and fluid pressure changes. We also developed a network model to simulate fluid flow and heat transport in both fractures and porous rock. In this paper, we describe results of simulations in which the DEM model and network flow & heat transport model are coupled together to provide realistic simulation of the changes of apertures and permeability of fractures and fracture networks induced by thermal cooling and fluid pressure changes within fractures. Various processes, such as Stokes flow in low velocity pores, convection-dominated heat transport in fractures, heat exchange between fluid-filled fractures and solid rock, heat conduction through low-permeability matrices and associated mechanical deformations are all incorporated into the coupled model. The effects of confining stresses, developing thermal stress and injection pressure on the permeability evolution of fracture and fracture networks are systematically investigated. Results are summarized in terms of implications for the development and evolution of fracture distribution during hydrofracturing and thermal stimulation for EGS.
Specific heat and thermal conductivity of nanomaterials
Bhatt, Sandhya; Kumar, Raghuvesh; Kumar, Munish
2017-01-01
A model is proposed to study the size and shape effects on specific heat and thermal conductivity of nanomaterials. The formulation developed for specific heat is based on the basic concept of cohesive energy and melting temperature. The specific heat of Ag and Au nanoparticles is reported and the effect of size and shape has been studied. We observed that specific heat increases with the reduction of particle size having maximum shape effect for spherical nanoparticle. To provide a more critical test, we extended our model to study the thermal conductivity and used it for the study of Si, diamond, Cu, Ni, Ar, ZrO2, BaTiO3 and SrTiO3 nanomaterials. A significant reduction is found in the thermal conductivity for nanomaterials by decreasing the size. The model predictions are consistent with the available experimental and simulation results. This demonstrates the suitability of the model proposed in this paper.
Brisson, Elodie; Desplats, Henri; Carre, Patrick; Keryvin, Vincent; Rogeon, Philippe; Feulvarch, Eric; Bonhomme, Alexandre
2016-12-01
During resistance sintering (RS) of a conductive porous material, effective electrical and thermal conductivities have a great influence on the thermal gradients inside the matter, which could induce heterogeneous microstructures. Part I of this investigation focused on the characterization of the effective conductivities of AgSnO2 during sintering conditions, with the understanding of the relations between their evolutions and the microstructure. In Part II, the emphasis is on the development of appropriate constitutive equations able to describe the evolutions of the effective conductivities of AgSnO2 during RS. This work proposes constitutive equations taking into account the two main mechanisms, identified in Part I, which modify the contact conditions between the particles. The first mechanism corresponds to viscoplastic deformations of particles. A creep behavior law is used to calculate the macroscopic deformation and the densification kinetics. The second one deals with bonding diffusion under the effect of temperature, which decreases the contact resistance between the particles. As no specific effect of current has been highlighted in the case of AgSnO2, the effective conductivities' behavior laws are available for RS and for hot pressing (HP). Relationships for effective conductivities are included in the numerical HP model and combined with governing laws. Finite element analyses are compared to experimental results obtained from HP tests to validate and discuss the model.
Thermal Conductivity of Humid Air
Beirão, S. G. S.; Ribeiro, A. P. C.; Lourenço, M. J. V.; Santos, F. J. V.; Nieto de Castro, C. A.
2012-09-01
In this article, measurements of the thermal conductivity of humid air as a function of pressure, temperature, and mole fraction of water, for pressures up to 5 MPa and temperatures up to 430 K, for different water contents (up to 10 % vapor mole fraction) are reported. Measurements were performed using a transient hot-wire apparatus capable of obtaining data with an uncertainty of 0.8 % for gases. However, as moist air becomes corrosive above 373 K and at pressures >5 MPa, the apparatus, namely, the pressure vessel and the cells had to be modified, by coating all stainless-steel parts with a titanium nitride thin film coating, about 4 μm thick, obtained by physical vapor deposition. The expanded uncertainty (coverage factor k = 2) of the present experimental thermal conductivity data is 1.7 %, while the uncertainty in the mole fraction is estimated to be better than 0.0006. Experimental details regarding the preparation of the samples, the precautions taken to avoid condensation in the tubes connected to the measuring cell, and the method developed for obtaining reliable values of the water content for the gas mixtures are discussed. A preliminary analysis of the application of the kinetic theory of transport properties in reacting mixtures to interpret the complex dependence of the thermal conductivity of humid air on water composition is addressed.
Thickness dependent thermal conductivity of gallium nitride
Ziade, Elbara; Yang, Jia; Brummer, Gordie; Nothern, Denis; Moustakas, Theodore; Schmidt, Aaron J.
2017-01-01
As the size of gallium nitride (GaN) transistors is reduced in order to reach higher operating frequencies, heat dissipation becomes the critical bottleneck in device performance and longevity. Despite the importance of characterizing the physics governing the thermal transport in thin GaN films, the literature is far from conclusive. In this letter, we report measurements of thermal conductivity in a GaN film with thickness ranging from 15-1000 nm grown on 4H-SiC without a transition layer. Additionally, we measure the thermal conductivity in the GaN film when it is 1 μm-thick in the temperature range of 300 < T < 600 K and use a phonon transport model to explain the thermal conductivity in this film.
Thermal Conductance of Andreev Interferometers
Jiang, Z.; Chandrasekhar, V.
2005-04-01
We calculate the thermal conductance GT of diffusive Andreev interferometers, which are hybrid loops with one superconducting arm and one normal-metal arm. The presence of the superconductor suppresses GT; however, unlike a conventional superconductor, GT/GTN does not vanish as the temperature T→0, but saturates at a finite value that depends on the resistance of the normal-superconducting interfaces, and their distance from the path of the temperature gradient. The reduction of GT is determined primarily by the suppression of the density of states in the proximity-coupled normal metal along the path of the temperature gradient. GT is also a strongly nonlinear function of the thermal current, as found in recent experiments.
Thermal Conductivity Of Rubble Piles
Luan, Jing
2015-01-01
Rubble piles are a common feature of solar system bodies. They are composed of monolithic elements of ice or rock bound by gravity. Voids occupy a significant fraction of the volume of a rubble pile. They can exist up to pressure $P\\approx \\epsy\\mu$, where $\\epsy$ is the monolithic material's yield strain and $\\mu$ its rigidity. At low $P$, contacts between neighboring elements are confined to a small fraction of their surface areas. As a result, the effective thermal conductivity of a rubble pile, $\\kcon\\approx k(P/(\\epsy\\mu))^{1/2}$, can be orders of magnitude smaller than, $k$, the thermal conductivity of its monolithic elements. In a fluid-free environment, only radiation can transfer energy across voids. It contributes an additional component, $\\krad=16\\ell\\sigma T^3/3$, to the total effective conductivity, $\\keff=\\kcon +\\krad$. Here $\\ell$, the inverse of the opacity per unit volume, is of order the size of the elements and voids. An important distinction between $\\kcon$ and $\\krad$ is that the former i...
DEFF Research Database (Denmark)
Gharagheizi, Farhad; Ilani‐Kashkouli, Poorandokht; Sattari, Mehdi
2013-01-01
In this communication, a general model for representation/presentation of the liquid thermal conductivity of chemical compounds (mostly organic) at 1 atm pressure for temperatures below normal boiling point and at saturation pressure for temperatures above the normal boiling point is developed...... of the model comprise temperature, acentric factor, critical pressure, normal boiling temperature, and molecular weight. Nearly 80% of the data set (15,221 data) is randomly assigned to develop the model equation, 10% of the data set (1902 data) is used to validate the model, and the remaining data (1902 data......) were implemented to evaluate its predictive power. The average absolute relative deviation of the model results from the DIPPR 801 data is less than 9%. In terms of simplicity and wide range of applicability, this empirical model shows acceptable accuracy. © 2012 American Institute of Chemical...
Energy Technology Data Exchange (ETDEWEB)
Ho, T.T.Y.; Sahai, S.K. [Conoco Inc., Ponca City, OK (United States); Leadholm, R.H. [Conoco Inc., Houston, TX (United States); Senneseth, O. [Conoco Norway Inc., Stavanger (Norway); Jensen, R.P.
1998-12-31
The primary objective of this paper is to demonstrate the successful application of maturation modelling using velocity-based thermal conductivity in the whole cycle of hydrocarbon exploration (frontier, developing and mature) on the Halten Terrace, Offshore Norway. This seismic geochemical method, used as a critical technique for selecting a favourable block in the early stages of exploration in the early 80s, enabled Conoco and its partners to make the first oil discovery and the subsequent discovery of the giant Heidrun Field in the area north of the 62nd parallel. Additional data (modelling and measured) on the thermal conductivity and Ro values are now available, and provide an excellent opportunity to compare the original (pre-drilling) basin models and related modelling results of the early 80s with 1990s (post-drilling) state-of-the-art data and models. The results of the comparative study indicate that the velocity-based conductivity compares very well with measured data, particularly in an overpressured area where conventional porosity (modelled) based thermal conductivities were inadequate. The pre-drilling predicted values of heat flow, geothermal gradient and vitrinite reflectance (based on Arrhenius equation) and oil window limits also compared favourably with post-drilling measured results. Thus, the method of calculating thermal conductivity from seismic data provides a useful tool to integrate geochemistry and geophysical (seismic) data, to calibrate maturation models, and to enhance the value of geochemistry and basin modelling in hydrocarbon exploration. (Author)
A 1-D radiative conductive model to study the SOIR/VEx thermal profiles
Mahieux, Arnaud; Erwin, Justin T.; Chamberlain, Sarah; Robert, Séverine; Carine Vandaele, Ann; Wilquet, Valérie; Thomas, Ian; Yelle, Roger V.; Bertaux, Jean-Loup
2015-04-01
SOIR is an infrared spectrometer on board Venus Express that probes the Venus terminator region since 2006. The measurements are taken on the morning and evening sides of the terminator, covering all latitudes from the North Pole to the South Pole. Its wavelength range - 2.2 to 4.3 μm - allows a detailed chemical inventory of the Venus atmosphere [1-5], such as CO2, CO, H2O, HCl, HF, SO2 and aerosols. CO2 is detected from 70 km up to 165 km, CO from 70 km to 140 km, and the minor species typically below 110 km down to 70 km. Number density profiles of these species are computed from the measured spectra. Temperature profiles are obtained while computing the spectral inversion of the CO2 spectra combined with the hydrostatic law [6]. These temperature measurements show a striking permanent temperature minimum (at 125 km) and a weaker temperature maximum (over 100-115 km). The time variability of the CO2 density profiles spans over two orders of magnitude, and a clear trend is seen with latitude. The temperature variations are also important, of the order of 35 K for a given pressure level, but the latitude variation are small. Miss-RT, a 1D radiative transfer model has been developed to reproduce the SOIR terminator profiles, derived from the Mars thermosphere code presented in [7]. This model has been expanded to better account for the CO2, CO, and O non-LTE radiative heating and cooling processes which have to be considered in the dense atmosphere of Venus. Radiative cooling by minor species detected by SOIR (e.g. HCl, SO2, and H2O) are found to be small in comparison to the 15 μm CO2 cooling. Aerosol cooling in the 60-90km altitude range may be important to the thermal balance. There is a good agreement between the 1D model temperature profile and the mean SOIR temperature profile. Further we can suggest parameters that can be adjusted to improve the agreement between the model and measurements. The remaining differences can be attributed to the atmosphere
Mean free path dependent phonon contributions to interfacial thermal conductance
Tao, Yi; Liu, Chenhan; Chen, Weiyu; Cai, Shuang; Chen, Chen; Wei, Zhiyong; Bi, Kedong; Yang, Juekuan; Chen, Yunfei
2017-06-01
Interfacial thermal conductance as an accumulation function of the phonon mean free path is rigorously derived from the thermal conductivity accumulation function. Based on our theoretical model, the interfacial thermal conductance accumulation function between Si/Ge is calculated. The results show that the range of mean free paths (MFPs) for phonons contributing to the interfacial thermal conductance is far narrower than that for phonons contributing to the thermal conductivity. The interfacial thermal conductance is mainly contributed by phonons with shorter MFPs, and the size effects can be observed only for an interface constructed by nanostructures with film thicknesses smaller than the MFPs of those phonons mainly contributing to the interfacial thermal conductance. This is why most experimental measurements cannot detect size effects on interfacial thermal conductance. A molecular dynamics simulation is employed to verify our proposed model.
Thermal conductivity of molten metals
Energy Technology Data Exchange (ETDEWEB)
Peralta-Martinez, Maria Vita
2000-02-01
A new instrument for the measurement of the thermal conductivity of molten metals has been designed, built and commissioned. The apparatus is based on the transient hot-wire technique and it is intended for operation over a wide range of temperatures, from ambient up to 1200 K, with an accuracy approaching 2%. In its present form the instrument operates up to 750 K. The construction of the apparatus involved four different stages, first, the design and construction of the sensor and second, the construction of an electronic system for the measurement and storage of data. The third stage was the design and instrumentation of the high temperature furnace for the melting and temperature control of the sample, and finally, an algorithm was developed for the extraction of the thermal conductivity from the raw measurement data. The sensor consists of a cylindrical platinum-wire symmetrically sandwiched between two rectangular plane sheets of alumina. The rectangular sensor is immersed in the molten metal of interest and a voltage step is applied to the ends of the platinum wire to induce heat dissipation and a consequent temperature rise which, is in part, determined by the thermal conductivity of the molten metal. The process is described by a set of partial differential equations and appropriate boundary conditions rather than an approximate analytical solution. An electronic bridge configuration was designed and constructed to perform the measurement of the resistance change of the platinum wire in the time range 20 {mu}s to 1 s. The resistance change is converted to temperature change by a suitable calibration. From these temperature measurements as a function of time the thermal conductivity of the molten metals has been deduced using the Finite Element Method for the solution of the working equations. This work has achieved its objective of improving the accuracy of the measurement of the thermal conductivity of molten metals from {+-}20% to {+-}2%. Measurements
Garmendia, Iñaki; Anglada, Eva
2016-05-01
Genetic algorithms have been used for matching temperature values generated using thermal mathematical models against actual temperatures measured in thermal testing of spacecrafts and space instruments. Up to now, results for small models have been very encouraging. This work will examine the correlation of a small-medium size model, whose thermal test results were available, by means of genetic algorithms. The thermal mathematical model reviewed herein corresponds to Tribolab, a materials experiment deployed on board the International Space Station and subjected to preflight thermal testing. This paper will also discuss in great detail the influence of both the number of reference temperatures available and the number of thermal parameters included in the correlation, taking into account the presence of heat sources and the maximum range of temperature mismatch. Conclusions and recommendations for the thermal test design will be provided, as well as some indications for future improvements.
Radiative magnetized thermal conduction fronts
Borkowski, Kazimierz J.; Balbus, Steven A.; Fristrom, Carl C.
1990-01-01
The evolution of plane-parallel magnetized thermal conduction fronts in the interstellar medium (ISM) was studied. Separating the coronal ISM phase and interstellar clouds, these fronts have been thought to be the site of the intermediate-temperature regions whose presence was inferred from O VI absorption-line studies. The front evolution was followed numerically, starting from the initial discontinuous temperature distribution between the hot and cold medium, and ending in the final cooling stage of the hot medium. It was found that, for the typical ISM pressure of 4000 K/cu cm and the hot medium temperature of 10 to the 6th K, the transition from evaporation to condensation in a nonmagnetized front occurs when the front thickness is 15 pc. This thickness is a factor of 5 smaller than previously estimated. The O VI column densities in both evaporative and condensation stages agree with observations if the initial hot medium temperature Th exceeds 750,000 K. Condensing conduction fronts give better agreement with observed O VI line profiles because of lower gas temperatures.
Thermal Conductivity of Al-Salt Composites
Li, Peng; Zhang, Mei; Wang, Lijun; Seetharaman, Seshadri
2015-11-01
With a view to examine the possibility of estimating the content of entrapped metallic aluminium in the salt cake from aluminium remelting, the thermal diffusivity of reference composites of KCl-NaCl-Al was measured as a function of aluminium metal content at room temperature. The thermal conductivity of the reference composites was found to increase with the metallic Al content. The lumped parameter model approach was carried out to discuss the influence of different geometry arrangements of each phase, viz. air, salts and metallic aluminium on the thermal conductivity. Application of the present results to industrial samples indicates that factors such as the interfacial condition of metallic Al particles have to be considered in order to estimate the amount of entrapped Al in the salt cake.
Development of Soft-Sphere Contact Models for Thermal Heat Conduction in Granular Flows
Energy Technology Data Exchange (ETDEWEB)
Morris, A. B.; Pannala, S.; Ma, Zhiwen; Hrenya, C. M.
2016-12-01
Conductive heat transfer to flowing particles occurs when two particles (or a particle and wall) come into contact. The direct conduction between the two bodies depends on the collision dynamics, namely the size of the contact area and the duration of contact. For soft-sphere discrete-particle simulations, it is computationally expensive to resolve the true collision time because doing so would require a restrictively small numerical time step. To improve the computational speed, it is common to increase the 'softness' of the material to artificially increase the collision time, but doing so affects the heat transfer. In this work, two physically-based correction terms are derived to compensate for the increased contact area and time stemming from artificial particle softening. By including both correction terms, the impact that artificial softening has on the conductive heat transfer is removed, thus enabling simulations at greatly reduced computational times without sacrificing physical accuracy.
Local measurement of thermal conductivity and diffusivity
Energy Technology Data Exchange (ETDEWEB)
Hurley, David H.; Schley, Robert S. [Materials Science and Engineering Department, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, Idaho 83415-2209 (United States); Khafizov, Marat [Mechanical and Aerospace Engineering Department, The Ohio State University, 201 W. 19th Ave., Columbus, Ohio 43210 (United States); Wendt, Brycen L. [Nuclear Science and Engineering, Idaho State University, 921 S. 8th Ave., Pocatello, Idaho 83209-8060 (United States)
2015-12-15
Simultaneous measurement of local thermal diffusivity and conductivity is demonstrated on a range of ceramic samples. This was accomplished by measuring the temperature field spatial profile of samples excited by an amplitude modulated continuous wave laser beam. A thin gold film is applied to the samples to ensure strong optical absorption and to establish a second boundary condition that introduces an expression containing the substrate thermal conductivity. The diffusivity and conductivity are obtained by comparing the measured phase profile of the temperature field to a continuum based model. A sensitivity analysis is used to identify the optimal film thickness for extracting the both substrate conductivity and diffusivity. Proof of principle studies were conducted on a range of samples having thermal properties that are representatives of current and advanced accident tolerant nuclear fuels. It is shown that by including the Kapitza resistance as an additional fitting parameter, the measured conductivity and diffusivity of all the samples considered agreed closely with the literature values. A distinguishing feature of this technique is that it does not require a priori knowledge of the optical spot size which greatly increases measurement reliability and reproducibility.
Local measurement of thermal conductivity and diffusivity
Hurley, David H.; Schley, Robert S.; Khafizov, Marat; Wendt, Brycen L.
2015-12-01
Simultaneous measurement of local thermal diffusivity and conductivity is demonstrated on a range of ceramic samples. This was accomplished by measuring the temperature field spatial profile of samples excited by an amplitude modulated continuous wave laser beam. A thin gold film is applied to the samples to ensure strong optical absorption and to establish a second boundary condition that introduces an expression containing the substrate thermal conductivity. The diffusivity and conductivity are obtained by comparing the measured phase profile of the temperature field to a continuum based model. A sensitivity analysis is used to identify the optimal film thickness for extracting the both substrate conductivity and diffusivity. Proof of principle studies were conducted on a range of samples having thermal properties that are representatives of current and advanced accident tolerant nuclear fuels. It is shown that by including the Kapitza resistance as an additional fitting parameter, the measured conductivity and diffusivity of all the samples considered agreed closely with the literature values. A distinguishing feature of this technique is that it does not require a priori knowledge of the optical spot size which greatly increases measurement reliability and reproducibility.
Thermal Conductivity Measurements on consolidated Soil Analogs
Seiferlin, K.; Heimberg, M.; Thomas, N.
2007-08-01
Heat transport in porous media such as soils and regolith is significantly reduced compared to the properties of compact samples of the same material. The bottle neck for solid state heat transport is the contact area between adjacent grains. For "dry" and unconsolidated materials the contact areas and thus the thermal conductivity are extremely small. Sintering and cementation are two processes that can increase the cross section of interstitial bonds signifcantly. On Mars, cementation can be caused by condensation of water or carbon dioxide ice from the vapor phase, or from salts and minerals that fall out from aqueous solutions. We produced several artificially cemented samples, using small glass beads of uniform size as soil analog. The cementation is achieved by initially molten wax that is mixed with the glass beads while liqiud. The wax freezes preferably at the contact points between grains, thus minimizing surface energy, and consolidates the samples. The thermal conductivity of these samples is then measured in vacuum. We present the results of these measurements and compare them with theoretical models. The observed range of thermal conductivity values can explain some, but not all of the variations in thermal intertia that can be seen in TES remote sensing data.
DEFF Research Database (Denmark)
Fuchs, Sven; Balling, Niels
2016-01-01
The subsurface temperature field and the geothermal conditions in sedimentary basins are frequently examined by using numerical thermal models. For those models, detailed knowledge of rock thermal properties are paramount for a reliable parameterization of layer properties and boundary conditions...... against known observed temperatures of good quality. Results clearly show that the use of location-specific well-log derived rock thermal properties and the integration of laterally varying input data (reflecting changes of lithofacies) significantly improves the temperature prediction...
Thermal Conductivity Measurement of Synthesized Mantle Minerals
Asimow, P. D.; Luo, S.; Mosenfelder, J. L.; Liu, W.; Staneff, G. D.; Ahrens, T. J.; Chen, G.
2002-12-01
Direct thermal conductivity (k) measurement of mantle minerals is crucial to constrain the thermal profile of the Earth as well as geodynamic studies of the mantle (e.g., to determine the Rayleigh number). We have embarked on systematic multi-anvil syntheses of dense polycrystalline specimens of mantle phases of adequate size and zero porosity for precise thermal conductivity measurements by the 3ω method (\\textit{Cahill and Pohl, Phys. Rev. B, 1987}) under elevated temperatures (T). Coesite and stishovite (see \\textit{Luo et al., GRL, 2002}) as well as majorite and wadsleyite have been synthesized; ringwoodite and perovskite are scheduled. Preliminary thermal conductivity measurements at ambient pressure on coesite (120 - 300 K, 9.53 Wm-1K-1 at 300 K) are consistent with prior room temperature data (\\textit{Yukutake & Shimada, PEPI, 1978}), while our stishovite data at 300 K appear to be low (1.96 Wm-1K-1). Efforts are being made to extend the measurement to higher temperatures (e.g., above Debye temperature Θ D), thus allowing determination of k(T) relationship (say, k~ T-n); success will depend on the decomposition kinetics of these metastable phases. The pressure dependence of k of these synthesized samples can also be measured (\\textit{e.g., Osako et al., HPMPS-6, 2002; Xu et al., EOS, 2001}). Recent thermal conductivity measurement on LiF and Al2O_3 from shock wave loading (\\textit{Holland & Ahrens, 1998}) is consistent with the modeling on MgO and Al2O_3 (\\textit{Manga & Jeanloz, JGR, 1997}) with classical theories. Thus, k values at modest pressures and T (say, above Θ D) would allow extrapolation of k to appropriate mantle conditions.
Thermal conduction in cosmological SPH simulations
Jubelgas, M; Dolag, K
2004-01-01
Thermal conduction in the intracluster medium has been proposed as a possible heating mechanism for offsetting central cooling losses in rich clusters of galaxies. In this study, we introduce a new formalism to model conduction in a diffuse ionised plasma using smoothed particle hydrodynamics (SPH), and we implement it in the parallel TreePM/SPH-code GADGET-2. We consider only isotropic conduction and assume that magnetic suppression can be described in terms of an effective conductivity, taken as a fixed fraction of the temperature-dependent Spitzer rate. We also account for saturation effects in low-density gas. Our formulation manifestly conserves thermal energy even for individual and adaptive timesteps, and is stable in the presence of small-scale temperature noise. This allows us to evolve the thermal diffusion equation with an explicit time integration scheme along with the ordinary hydrodynamics. We use a series of simple test problems to demonstrate the robustness and accuracy of our method. We then ...
Thermal Boundary Conductance: A Materials Science Perspective
Monachon, Christian; Weber, Ludger; Dames, Chris
2016-07-01
The thermal boundary conductance (TBC) of materials pairs in atomically intimate contact is reviewed as a practical guide for materials scientists. First, analytical and computational models of TBC are reviewed. Five measurement methods are then compared in terms of their sensitivity to TBC: the 3ω method, frequency- and time-domain thermoreflectance, the cut-bar method, and a composite effective thermal conductivity method. The heart of the review surveys 30 years of TBC measurements around room temperature, highlighting the materials science factors experimentally proven to influence TBC. These factors include the bulk dispersion relations, acoustic contrast, and interfacial chemistry and bonding. The measured TBCs are compared across a wide range of materials systems by using the maximum transmission limit, which with an attenuated transmission coefficient proves to be a good guideline for most clean, strongly bonded interfaces. Finally, opportunities for future research are discussed.
Römer, Frank; Lervik, Anders; Bresme, Fernando
2012-08-21
We report an extensive nonequilibrium molecular dynamics investigation of the thermal conductivity of water using two of the most accurate rigid nonpolarizable empirical models available, SPC/E and TIP4P/2005. Our study covers liquid and supercritical states. Both models predict the anomalous increase of the thermal conductivity with temperature and the thermal conductivity maximum, hence confirming their ability to reproduce the complex anomalous behaviour of water. The performance of the models strongly depends on the thermodynamic state investigated, and best agreement with experiment is obtained for states close to the liquid coexistence line and at high densities and temperatures. Considering the simplicity of these two models the overall agreement with experiments is remarkable. Our results show that explicit polarizability and molecular flexibility are not needed to reproduce the anomalous heat conduction of water.
Anisotropic Thermal Conductivity of Exfoliated Black Phosphorus.
Jang, Hyejin; Wood, Joshua D; Ryder, Christopher R; Hersam, Mark C; Cahill, David G
2015-12-22
The anisotropic thermal conductivity of passivated black phosphorus (BP), a reactive two-dimensional material with strong in-plane anisotropy, is ascertained. The room-temperature thermal conductivity for three crystalline axes of exfoliated BP is measured by time-domain thermo-reflectance. The thermal conductivity along the zigzag direction is ≈2.5 times higher than that of the armchair direction.
The thermal conductivity of clustered nanocolloids
Directory of Open Access Journals (Sweden)
Saba Lotfizadeh
2014-06-01
Full Text Available We quantify the effect of clustering on the thermal conductivity of colloidal dispersions using silane-treated silica, a system engineered to exhibit reversible clustering under well-controlled conditions. We show that the thermal conductivity increases monotonically with cluster size and spans the entire range between the two limits of Maxwell's theory. The results, corroborated by numerical simulation, demonstrate that large increases of the thermal conductivity of colloidal dispersions are possible, yet fully within the predictions of classical theory.
Thermal conductivity analysis of lanthanum doped manganites
Energy Technology Data Exchange (ETDEWEB)
Mansuri, Irfan, E-mail: dr.irfan.mansuri@gmail.com [Indore Institute of Science and Technology, Pithampur Road Rau, Indore-453331 India and School of Physics, Devi Ahilya University, Khandwa Road Campus, Indore-452001 (India); Shaikh, M. W. [School of Physics, Devi Ahilya University, Khandwa Road Campus, Indore-452001, India and Acropolis Technical Campus, Village Tillore, Indore-453331 (India); Khan, E.; Varshney, Dinesh [School of Physics, Devi Ahilya University, Khandwa Road Campus, Indore-452001 (India)
2014-04-24
The temperature-dependent thermal conductivity of the doped manganites La{sub 0.7}Ca{sub 0.3}MnO{sub 3} is theoretically analyzed within the framework of Kubo formulae. The Hamiltonian consists of phonon, electron and magnon thermal conductivity contribution term. In this process we took defects, carrier, grain boundary, scattering process term and then calculate phonon, electron and magnon thermal conductivity.
Low lattice thermal conductivity of stanene.
Peng, Bo; Zhang, Hao; Shao, Hezhu; Xu, Yuchen; Zhang, Xiangchao; Zhu, Heyuan
2016-02-03
A fundamental understanding of phonon transport in stanene is crucial to predict the thermal performance in potential stanene-based devices. By combining first-principle calculation and phonon Boltzmann transport equation, we obtain the lattice thermal conductivity of stanene. A much lower thermal conductivity (11.6 W/mK) is observed in stanene, which indicates higher thermoelectric efficiency over other 2D materials. The contributions of acoustic and optical phonons to the lattice thermal conductivity are evaluated. Detailed analysis of phase space for three-phonon processes shows that phonon scattering channels LA + LA/TA/ZA ↔ TA/ZA are restricted, leading to the dominant contributions of high-group-velocity LA phonons to the thermal conductivity. The size dependence of thermal conductivity is investigated as well for the purpose of the design of thermoelectric nanostructures.
Directory of Open Access Journals (Sweden)
Tamara Kujawska
Full Text Available A tissue thermal conductivity (Ks is an important parameter which knowledge is essential whenever thermal fields induced in selected organs are predicted. The main objective of this study was to develop an alternative ultrasonic method for determining Ks of tissues in vitro suitable for living tissues. First, the method involves measuring of temperature-time T(t rises induced in a tested tissue sample by a pulsed focused ultrasound with measured acoustic properties using thermocouples located on the acoustic beam axis. Measurements were performed for 20-cycle tone bursts with a 2 MHz frequency, 0.2 duty-cycle and 3 different initial pressures corresponding to average acoustic powers equal to 0.7 W, 1.4 W and 2.1 W generated from a circular focused transducer with a diameter of 15 mm and f-number of 1.7 in a two-layer system of media: water/beef liver. Measurement results allowed to determine position of maximum heating located inside the beef liver. It was found that this position is at the same axial distance from the source as the maximum peak-peak pressure calculated for each nonlinear beam produced in the two-layer system of media. Then, the method involves modeling of T(t at the point of maximum heating and fitting it to the experimental data by adjusting Ks. The averaged value of Ks determined by the proposed method was found to be 0.5±0.02 W/(m·°C being in good agreement with values determined by other methods. The proposed method is suitable for determining Ks of some animal tissues in vivo (for example a rat liver.
Thermal conductivity of heterogeneous LWR MOX fuels
Staicu, D.; Barker, M.
2013-11-01
It is generally observed that the thermal conductivity of LWR MOX fuel is lower than that of pure UO2. For MOX, the degradation is usually only interpreted as an effect of the substitution of U atoms by Pu. This hypothesis is however in contradiction with the observations of Duriez and Philiponneau showing that the thermal conductivity of MOX is independent of the Pu content in the ranges 3-15 and 15-30 wt.% PuO2 respectively. Attributing this degradation to Pu only implies that stoichiometric heterogeneous MOX can be obtained, while we show that any heterogeneity in the plutonium distribution in the sample introduces a variation in the local stoichiometry which in turn has a strong impact on the thermal conductivity. A model quantifying this effect is obtained and a new set of experimental results for homogeneous and heterogeneous MOX fuels is presented and used to validate the proposed model. In irradiated fuels, this effect is predicted to disappear early during irradiation. The 3, 6 and 10 wt.% Pu samples have a similar thermal conductivity. Comparison of the results for this homogeneous microstructure with MIMAS (heterogeneous) fuel of the same composition showed no difference for the Pu contents of 3, 5.9, 6, 7.87 and 10 wt.%. A small increase of the thermal conductivity was obtained for 15 wt.% Pu. This increase is of about 6% when compared to the average of the values obtained for 3, 6 and 10 wt.% Pu. For comparison purposes, Duriez also measured the thermal conductivity of FBR MOX with 21.4 wt.% Pu with O/M = 1.982 and a density close to 95% TD and found a value in good agreement with the estimation obtained using the formula of Philipponneau [8] for FBR MOX, and significantly lower than his results corresponding to the range 3-15 wt.% Pu. This difference in thermal conductivity is of about 20%, i.e. higher than the measurement uncertainties.Thus, a significant difference was observed between FBR and PWR MOX fuels, but was not explained. This difference
The Electronic Thermal Conductivity of Graphene.
Kim, Tae Yun; Park, Cheol-Hwan; Marzari, Nicola
2016-04-13
Graphene, as a semimetal with the largest known thermal conductivity, is an ideal system to study the interplay between electronic and lattice contributions to thermal transport. While the total electrical and thermal conductivity have been extensively investigated, a detailed first-principles study of its electronic thermal conductivity is still missing. Here, we first characterize the electron-phonon intrinsic contribution to the electronic thermal resistivity of graphene as a function of doping using electronic and phonon dispersions and electron-phonon couplings calculated from first-principles at the level of density-functional theory and many-body perturbation theory (GW). Then, we include extrinsic electron-impurity scattering using low-temperature experimental estimates. Under these conditions, we find that the in-plane electronic thermal conductivity κe of doped graphene is ∼300 W/mK at room temperature, independently of doping. This result is much larger than expected and comparable to the total thermal conductivity of typical metals, contributing ∼10% to the total thermal conductivity of bulk graphene. Notably, in samples whose physical or domain sizes are of the order of few micrometers or smaller, the relative contribution coming from the electronic thermal conductivity is more important than in the bulk limit, because lattice thermal conductivity is much more sensitive to sample or grain size at these scales. Last, when electron-impurity scattering effects are included we find that the electronic thermal conductivity is reduced by 30 to 70%. We also find that the Wiedemann-Franz law is broadly satisfied at low and high temperatures but with the largest deviations of 20-50% around room temperature.
Anisotropic thermal conductivity in uranium dioxide.
Gofryk, K; Du, S; Stanek, C R; Lashley, J C; Liu, X-Y; Schulze, R K; Smith, J L; Safarik, D J; Byler, D D; McClellan, K J; Uberuaga, B P; Scott, B L; Andersson, D A
2014-08-01
The thermal conductivity of uranium dioxide has been studied for over half a century, as uranium dioxide is the fuel used in a majority of operating nuclear reactors and thermal conductivity controls the conversion of heat produced by fission events to electricity. Because uranium dioxide is a cubic compound and thermal conductivity is a second-rank tensor, it has always been assumed to be isotropic. We report thermal conductivity measurements on oriented uranium dioxide single crystals that show anisotropy from 4 K to above 300 K. Our results indicate that phonon-spin scattering is important for understanding the general thermal conductivity behaviour, and also explains the anisotropy by coupling to the applied temperature gradient and breaking cubic symmetry.
Thermal conductivity of silicon nanocrystals and polystyrene nanocomposite thin films
Bagja Juangsa, Firman; Muroya, Yoshiki; Ryu, Meguya; Morikawa, Junko; Nozaki, Tomohiro
2016-09-01
Silicon nanocrystals (SiNCs) are well known for their size-dependent optical and electronic properties; they also have the potential for low yet controllable thermal properties. As a silicon-based low-thermal conductivity material is required in microdevice applications, SiNCs can be utilized for thermal insulation. In this paper, SiNCs and polymer nanocomposites were produced, and their thermal conductivity, including the density and specific heat, was measured. Measurement results were compared with thermal conductivity models for composite materials, and the comparison shows a decreasing value of the thermal conductivity, indicating the effect of the size and presence of the nanostructure on the thermal conductivity. Moreover, employing silicon inks at room temperature during the fabrication process enables a low cost of fabrication and preserves the unique properties of SiNCs.
Thermal conductance of pressed contacts at liquid helium temperatures
Salerno, L. J.; Kittel, P.; Spivak, A. L.
1983-01-01
It is pointed out that the optimum design of cryogenic instruments requires accurate thermal models. The present models are limited by a lack of knowledge of the low temperature thermal conductance of the bolted joints which are typically used in the instrument-to-system interface. In connection with studies of pressed contacts, it has been found that the thermal conductance does not obey the Wiedemann-Franz law. The present investigation is concerned with the characterization of the thermal conductance of pressed contacts at liquid helium-4 temperatures, taking into account the dependence of thermal contact conductance on applied force and temperature. It is shown that for the 0.4 micron OFHC copper pressed contact pair, the thermal conductance varies roughly as the second power of the temperature, and increases with increasing applied force.
Electrically conductive and thermally conductive materials for electronic packaging
Liu, Zongrong
The aim of this dissertation is to develop electrically or thermally conductive materials that are needed for electronic packaging and microelectronic cooling. These materials are in the form of coatings and are made from pastes. The research work encompasses paste formulation, studying the process of converting a paste to a conductive material, relating the processing conditions to the structure and performance, and evaluating performance attributes that are relevant to the application of these conductive materials. The research has resulted in new information that is valuable to the microelectronic industry. Work on electrically conductive materials emphasizes the development of electrical interconnection materials in the form of air-firable glass-free silver-based electrically conductive thick films, which use the Ti-Al alloy as the binder and are in contrast to conventional films that use glass as the binder. The air-firability, as enabled by minor additions of tin and zinc to the paste, is in contrast to previous glass-free films that are not firable. The recommended firing condition is 930°C in air. The organic vehicle in the paste comprises ethyl cellulose, which undergoes thermal decomposition during burnout of the paste. The ethyl cellulose is dissolved in ether, which facilitates the burnout. Excessive ethyl cellulose hinders the burnout. A higher heating rate results in more residue after burnout. The presence of silver particles facilitates drying and burnout. Firing in air gives lower resistivity than firing in oxygen. Firing in argon gives poor films. Compared to conventional films that use glass as the binder, these films, when appropriately fired, exhibit lower electrical resistivity (2.5 x 10-6 O.cm) and higher scratch resistance. Work on thermally conductive materials addresses thermal interface materials, which are materials placed at the interface between a heat sink and a heat source for the purpose of improving the thermal contact. Heat
Thermal Conductivity and Sintering Behavior of Advanced Thermal Barrier Coatings
Zhu, Dongming; Miller, Robert A.
2002-01-01
Advanced thermal barrier coatings, having significantly reduced long-term thermal conductivities, are being developed using an approach that emphasizes real-time monitoring of thermal conductivity under conditions that are engine-like in terms of temperatures and heat fluxes. This is in contrast to the traditional approach where coatings are initially optimized in terms of furnace and burner rig durability with subsequent measurement in the as-processed or furnace-sintered condition. The present work establishes a laser high-heat-flux test as the basis for evaluating advanced plasma-sprayed and physical vapor-deposited thermal barrier coatings under the NASA Ultra Efficient Engine Technology (UEET) Program. The candidate coating materials for this program are novel thermal barrier coatings that are found to have significantly reduced thermal conductivities due to an oxide-defect-cluster design. Critical issues for designing advanced low conductivity coatings with improved coating durability are also discussed.
Thermal Conductance through Sapphire-Sapphire Bonding
Suzuki, T.; Tomaru, T.; Haruyama, T.; Shintomi, T.; Uchinyama, T.; Miyoki, S.; Ohashi, M.; Kuroda, K.
2003-07-01
Thermal conductance on sapphire-sapphire bonded interface has been investigated. Two pieces of single crystal sapphire bar with square cross section were bonded together by adhesion free bonding. In two sections of the bar, thermal conductivity was measured between 5 K to 300K. One section contains a bonded interface and the other section measured a thermal conductivity of the sapphire as a reference. No significant thermal resistance due to bonded interface was found from this measurement. Obtained thermal conductivity reaches κ 1 × 104 [W/m·K] in temperature range of T = 20 ˜ 30 K which is a planned operating temperature of a cryogenic mirror of the Large scale Cryogenic Gravitational wave telescope. It looks promising for sapphire bonding technique to improve a heat transfer from a large cryogenic mirror to susp ension wires.
Thermal conductivity of sintered lithium orthosilicate compacts
Löbbecke, Birgit; Knitter, Regina; Rohde, Magnus; Reimann, Jörg
2009-04-01
The design of solid breeder blankets is strongly affected by the low values of thermal conductivity and density of ceramic breeder pebble beds. A significant rise of both quantities would enhance the thermal performance and lead to an increased tritium breeding ratio. In order to improve these quantities pretreated lithium orthosilicate pebble material was dry pressed and subsequently sintered. The thermal conductivity of cylindrical pellets was determined by the heat pulse method using a laser flash device. A pebble bed characteristic sample was also investigated in order to check the measurement accuracy in comparison with previous results. Furthermore, two samples of low density cellular ceramics were also prepared by infiltration of polymer foams with a ceramic slurry. The thermal conductivity results show that the values are affected both by the particle size and the sample density. Thermal conductivity values of higher than 2 W/m K were obtained using large particles and sintering at 1000 °C.
THERMAL CONDUCTIVITY OF RUBBERIZED GYPSUM BOARD
Directory of Open Access Journals (Sweden)
Taher Abu-Lebdeh
2014-01-01
Full Text Available The disposal of scrap tires is a challenging task and hence an innovative solution to meet these challenges is needed. Extensive work has been done on the utilization of waste tires in a variety of applications in asphalt pavements and concrete. However, previous investigations focus only on the mechanical properties of the rubberized materials, but few on the thermal performance. This is especially true for rubberized gypsum. Limited or no experimental data on the thermal performance of rubberized gypsum board are available. In this study, an experimental program is established to investigate the effect of amount and size of crumb rubber on the thermal properties of gypsum materials. Gypsum is replaced by four different percentage of crumb rubber: 10, 20, 30 and 40% by weight of gypsum and two sizes of crumb rubber (#30, #10_20 to make eight rubberized gypsum specimens. The prepared specimens were tested for thermal conductivity using an apparatus specially designed and constructed for this purpose. The experimental program was concluded by proposing an empirical equation to predict the thermal conductivity of rubberized gypsum board. Results indicated better thermal performance of the gypsum board due to the addition of crumb rubber. Thermal conductivity of the rubberized gypsum was 18-38% lower than the ordinary gypsum. It is concluded that thermal conductivity of rubberized gypsum decreases with the increase of crumb rubber regardless the size of the rubber and that thermal conductivity of mixtures contained 40% of rubber was about 38% lower than conventional mixture when crumb rubber #10_20 was added, while the thermal conductivity reduced by 22% when crumb rubber #30 was added. The study suggested for future work to investigate the effect of air voids size and ratio on the thermal conductivity of rubberized gypsum.
Thermal conductivity measurements of Summit polycrystalline silicon.
Energy Technology Data Exchange (ETDEWEB)
Clemens, Rebecca; Kuppers, Jaron D.; Phinney, Leslie Mary
2006-11-01
A capability for measuring the thermal conductivity of microelectromechanical systems (MEMS) materials using a steady state resistance technique was developed and used to measure the thermal conductivities of SUMMiT{trademark} V layers. Thermal conductivities were measured over two temperature ranges: 100K to 350K and 293K to 575K in order to generate two data sets. The steady state resistance technique uses surface micromachined bridge structures fabricated using the standard SUMMiT fabrication process. Electrical resistance and resistivity data are reported for poly1-poly2 laminate, poly2, poly3, and poly4 polysilicon structural layers in the SUMMiT process from 83K to 575K. Thermal conductivity measurements for these polysilicon layers demonstrate for the first time that the thermal conductivity is a function of the particular SUMMiT layer. Also, the poly2 layer has a different variation in thermal conductivity as the temperature is decreased than the poly1-poly2 laminate, poly3, and poly4 layers. As the temperature increases above room temperature, the difference in thermal conductivity between the layers decreases.
Tailoring thermal conductivity via three-dimensional porous alumina
Abad, Begoña; Maiz, Jon; Ruiz-Clavijo, Alejandra; Caballero-Calero, Olga; Martin-Gonzalez, Marisol
2016-12-01
Three-dimensional anodic alumina templates (3D-AAO) are an astonishing framework with open highly ordered three-dimensional skeleton structures. Since these templates are architecturally different from conventional solids or porous templates, they teem with opportunities for engineering thermal properties. By establishing the mechanisms of heat transfer in these frameworks, we aim to create materials with tailored thermal properties. The effective thermal conductivity of an empty 3D-AAO membrane was measured. As the effective medium theory was not valid to extract the skeletal thermal conductivity of 3D-AAO, a simple 3D thermal conduction model was developed, based on a mixed series and parallel thermal resistor circuit, giving a skeletal thermal conductivity value of approximately 1.25 W·m-1·K-1, which matches the value of the ordinary AAO membranes prepared from the same acid solution. The effect of different filler materials as well as the variation of the number of transversal nanochannels and the length of the 3D-AAO membrane in the effective thermal conductivity of the composite was studied. Finally, the thermal conductivity of two 3D-AAO membranes filled with cobalt and bismuth telluride was also measured, which was in good agreement with the thermal model predictions. Therefore, this work proved this structure as a powerful approach to tailor thermal properties.
Tailoring thermal conductivity via three-dimensional porous alumina.
Abad, Begoña; Maiz, Jon; Ruiz-Clavijo, Alejandra; Caballero-Calero, Olga; Martin-Gonzalez, Marisol
2016-12-09
Three-dimensional anodic alumina templates (3D-AAO) are an astonishing framework with open highly ordered three-dimensional skeleton structures. Since these templates are architecturally different from conventional solids or porous templates, they teem with opportunities for engineering thermal properties. By establishing the mechanisms of heat transfer in these frameworks, we aim to create materials with tailored thermal properties. The effective thermal conductivity of an empty 3D-AAO membrane was measured. As the effective medium theory was not valid to extract the skeletal thermal conductivity of 3D-AAO, a simple 3D thermal conduction model was developed, based on a mixed series and parallel thermal resistor circuit, giving a skeletal thermal conductivity value of approximately 1.25 W·m(-1)·K(-1), which matches the value of the ordinary AAO membranes prepared from the same acid solution. The effect of different filler materials as well as the variation of the number of transversal nanochannels and the length of the 3D-AAO membrane in the effective thermal conductivity of the composite was studied. Finally, the thermal conductivity of two 3D-AAO membranes filled with cobalt and bismuth telluride was also measured, which was in good agreement with the thermal model predictions. Therefore, this work proved this structure as a powerful approach to tailor thermal properties.
Molecular dynamics simulation of thermal conductivities of superlattice nanowires
Institute of Scientific and Technical Information of China (English)
杨决宽; 陈云飞; 颜景平
2003-01-01
Nonequilibrium molecular dynamics simulations were carried out to investigate heat transfer in superlattice nanowires. Results show that for fixed period length superlattice nanowires, the ratio of the total interfacial thermal resistance to the total thermal resistance and the effective thermal conductivities are invariant with the changes in interface numbers. Increasing the period length leads to an increase in the average interfacial thermal resistance, which indicates that the interfacial thermal resistance depends not only on the materials that constitute the alternating segments of superlattice nanowires, but also on the lattice strain throughout the segments. The modification of the lattice structure due to the lattice mismatch should be taken into account in the acoustic mismatch model. Simulation results also demonstrated the size confinement effect on the thermal conductivities for low dimensional structures, i.e. the thermal conductivities and the interfacial thermal resistance increase as the nanowire cross-sectional area increases.
Thermal Conductivity of Carbon Nanoreinforced Epoxy Composites
Directory of Open Access Journals (Sweden)
C. Kostagiannakopoulou
2016-01-01
Full Text Available The present study attempts to investigate the influence of multiwalled carbon nanotubes (MWCNTs and graphite nanoplatelets (GNPs on thermal conductivity (TC of nanoreinforced polymers and nanomodified carbon fiber epoxy composites (CFRPs. Loading levels from 1 to 3% wt. of MWCNTs and from 1 to 15% wt. of GNPs were used. The results indicate that TC of nanofilled epoxy composites increased with the increase of GNP content. Quantitatively, 176% and 48% increase of TC were achieved in nanoreinforced polymers and nanomodified CFRPs, respectively, with the addition of 15% wt. GNPs into the epoxy matrix. Finally, micromechanical models were applied in order to predict analytically the TC of polymers and CFRPs. Lewis-Nielsen model with optimized parameters provides results very close to the experimental ones in the case of polymers. As far as the composites are concerned, the Hashin and Clayton models proved to be sufficiently accurate for the prediction at lower filler contents.
Thermal conductivity of reinforced soils：A literature review
Institute of Scientific and Technical Information of China (English)
Muge Elif Orakoglu; JianKun Liu
2014-01-01
This-paper-aims-a-review-of-the-literature-related-to-soil-reinforcements-to-achieve-lower-soil-thermal-conductivity-(λ).-The-use-of-various-natural-and-synthetic-fibers,-polymers,-geosynthetics,-agricultural-waste/materials,-and-nanoclays-is-dis-cussed-and-existing-prediction-models-that-have-been-thought-to-affect-low-thermal-conductivity-are-presented.
Increased thermal conductivity monolithic zeolite structures
Klett, James; Klett, Lynn; Kaufman, Jonathan
2008-11-25
A monolith comprises a zeolite, a thermally conductive carbon, and a binder. The zeolite is included in the form of beads, pellets, powders and mixtures thereof. The thermally conductive carbon can be carbon nano-fibers, diamond or graphite which provide thermal conductivities in excess of about 100 W/mK to more than 1,000 W/mK. A method of preparing a zeolite monolith includes the steps of mixing a zeolite dispersion in an aqueous colloidal silica binder with a dispersion of carbon nano-fibers in water followed by dehydration and curing of the binder is given.
New method for measuring the thermal conductivity.
Goldratt, E; Greenfield, A J
1978-11-01
A new experimental method is presented for measuring the thermal conductivity as a function of temperature. The basic innovation lies in extracting from the measured temperature profile of a sample in vacuo, the thermal conductivity of each individual cross-sectional sample element. The estimated experimental error is +/-1%. Not only is high accuracy achieved, but also a self-checking procedure offers the possibility of avoiding systematic errors. Measurements on two samples of type 304 stainless steel are presented. Three independent sets of measurements give consistent values for the thermal conductivity to well within the estimated error of +/-1%.
Method for Measuring Thermal Conductivity of Small Samples Having Very Low Thermal Conductivity
Miller, Robert A.; Kuczmarski, Maria a.
2009-01-01
This paper describes the development of a hot plate method capable of using air as a standard reference material for the steady-state measurement of the thermal conductivity of very small test samples having thermal conductivity on the order of air. As with other approaches, care is taken to ensure that the heat flow through the test sample is essentially one-dimensional. However, unlike other approaches, no attempt is made to use heated guards to block the flow of heat from the hot plate to the surroundings. It is argued that since large correction factors must be applied to account for guard imperfections when sample dimensions are small, it may be preferable to simply measure and correct for the heat that flows from the heater disc to directions other than into the sample. Experimental measurements taken in a prototype apparatus, combined with extensive computational modeling of the heat transfer in the apparatus, show that sufficiently accurate measurements can be obtained to allow determination of the thermal conductivity of low thermal conductivity materials. Suggestions are made for further improvements in the method based on results from regression analyses of the generated data.
Thermal Conduction and Insulation Modification in Asphalt-Based Composites
Institute of Scientific and Technical Information of China (English)
Xiaofeng Zhou; Shengyue Wang; Chao Zhou
2012-01-01
The relationship between thermal conductivity and properties of mixing particles is required for quantitative study of heat transfer processes in asphalt-based materials. In this paper, we measured the e？ective ther- mal conductivity of asphalt-based materials with thermal conduction （graphite） and insulation （cenosphere） powders modification. By taking account of the particle shape, volume fraction, the thermal conductivity of filling particles and base asphalt, we present a new differential effective medium formula to predict the thermal conductivity modification in asphalt-based composite. Our theoretical predications are in good agreement with the experiment data. The new model can be applied for predicting the thermal properties of asphalt-based mixture, which is available for most of thermal modification in two-phase composites.
Thermal Conductivity Measurement of Anisotropic Biological Tissue In Vitro
Yue, Kai; Cheng, Liang; Yang, Lina; Jin, Bitao; Zhang, Xinxin
2017-06-01
The accurate determination of the thermal conductivity of biological tissues has implications on the success of cryosurgical/hyperthermia treatments. In light of the evident anisotropy in some biological tissues, a new modified stepwise transient method was proposed to simultaneously measure the transverse and longitudinal thermal conductivities of anisotropic biological tissues. The physical and mathematical models were established, and the analytical solution was derived. Sensitivity analysis and experimental simulation were performed to determine the feasibility and measurement accuracy of simultaneously measuring the transverse and longitudinal thermal conductivities. The experimental system was set up, and its measurement accuracy was verified by measuring the thermal conductivity of a reference standard material. The thermal conductivities of the pork tenderloin and bovine muscles were measured using the traditional 1D and proposed methods, respectively, at different temperatures. Results indicate that the thermal conductivities of the bovine muscle are lower than those of the pork tenderloin muscle, whereas the bovine muscle was determined to exhibit stronger anisotropy than the pork tenderloin muscle. Moreover, the longitudinal thermal conductivity is larger than the transverse thermal conductivity for the two tissues and all thermal conductivities increase with the increase in temperature. Compared with the traditional 1D method, results obtained by the proposed method are slightly higher although the relative deviation is below 5 %.
Lattice thermal conductivity evaluated using elastic properties
Jia, Tiantian; Chen, Gang; Zhang, Yongsheng
2017-04-01
Lattice thermal conductivity is one of the most important thermoelectric parameters in determining the energy conversion efficiency of thermoelectric materials. However, the lattice thermal conductivity evaluation requires time-consuming first-principles (quasi)phonon calculations, which limits seeking high-performance thermoelectric materials through high-throughput computations. Here, we establish a methodology to determine the Debye temperature Θ , Grüneisen parameter γ , and lattice thermal conductivity κ using computationally feasible elastic properties (the bulk and shear moduli). For 39 compounds with three different prototypes (the cubic isotropic rocksalt and zinc blende, and the noncubic anisotropic wurtzite), the theoretically calculated Θ ,γ , and κ are in reasonable agreement with those determined using (quasi)harmonic phonon calculations or experimental measurements. Our results show that the methodology is an efficient tool to predict the anharmonicity and the lattice thermal conductivity.
Measurement of the anisotropic thermal conductivity of the porcine cornea.
Barton, Michael D; Trembly, B Stuart
2013-10-01
Accurate thermal models for the cornea of the eye support the development of thermal techniques for reshaping the cornea and other scientific purposes. Heat transfer in the cornea must be quantified accurately so that a thermal treatment does not destroy the endothelial layer, which cannot regenerate, and yet is responsible for maintaining corneal transparency. We developed a custom apparatus to measure the thermal conductivity of ex vivo porcine corneas perpendicular to the surface and applied a commercial apparatus to measure thermal conductivity parallel to the surface. We found that corneal thermal conductivity is 14% anisotropic at the normal state of corneal hydration. Small numbers of ex vivo feline and human corneas had a thermal conductivity perpendicular to the surface that was indistinguishable from the porcine corneas. Aqueous humor from ex vivo porcine, feline, and human eyes had a thermal conductivity nearly equal to that of water. Including the anisotropy of corneal thermal conductivity will improve the predictive power of thermal models of the eye. Copyright © 2013 Elsevier Ltd. All rights reserved.
Engineering thermal conductivity in polymer blends
Rashidi, Vahid; Coyle, Eleanor; Kieffer, John; Pipe, Kevin
Weak inter-chain bonding in polymers is believed to be a bottleneck for both thermal conductivity and mechanical strength. Most polymers have low thermal conductivity (~0.1 W/mK), hindering their performance in applications for which thermal management is critical (e.g., electronics packaging). In this work, we use computational methods to study how hydrogen bonding between polymer chains as well as water content can be used to engineer thermal transport in bulk polymers. We examine how changes in the number of hydrogen bonds, chain elongation, density, and vibrational density of states correlate with changes in thermal conductivity for polymer blends composed of different relative constituent fractions. We also consider the effects of bond strength, tacticity, and polymer chain mass. For certain blend fractions, we observe large increases in thermal conductivity, and we analyze these increases in terms of modifications to chain chemistry (e.g., inter-chain bonding) and chain morphology (e.g., chain alignment and radius of gyration). We observe that increasing the number of hydrogen bonds in the system results in better packing as well as better chain alignment and elongation that contribute to enhanced thermal conductivity. The Air Force Office of Scientific Research, Grant No. FA9550-14-1-0010.
DEFF Research Database (Denmark)
Hemmat esfe, Mohammad; Wongwises, Somchai; Naderi, Ali
2015-01-01
In the present paper, the thermal conductivity of hybrid nanofluids is experimentally investigated. The studied nanofluid was produced using a two-step method by dispersing Cu and TiO2 nanoparticles with average diameter of 70 and 40 nm in a binary mixture of water/EG (60:40). The properties of t...... an artificial neural network (ANN) and are based on experimental data. The results indicate that these two new models have great ability to predict thermal conductivity and show excellent agreement with the experimental results....
Thermal Conductivity of Ordered Molecular Water
Energy Technology Data Exchange (ETDEWEB)
W Evans; J Fish; P Keblinski
2006-02-16
We use molecular dynamics simulation to investigate thermal transport characteristics of water with various degree of orientational and translational order induced by the application of an electric field. We observe that orientational ordering of the water dipole moments has a minor effect on the thermal conductivity. However, electric-field induced crystallization and associated translational order results in approximately a 3-fold increase of thermal conductivity with respect to the base water, i.e., to values comparable with those characterizing ice crystal structures.
Thermal Conductivity of Carbon Nanotube Composite Films
Ngo, Quoc; Cruden, Brett A.; Cassell, Alan M.; Walker, Megan D.; Koehne, Jessica E.; Meyyappan, M.; Li, Jun; Yang, Cary Y.
2004-01-01
State-of-the-art ICs for microprocessors routinely dissipate power densities on the order of 50 W/sq cm. This large power is due to the localized heating of ICs operating at high frequencies, and must be managed for future high-frequency microelectronic applications. Our approach involves finding new and efficient thermally conductive materials. Exploiting carbon nanotube (CNT) films and composites for their superior axial thermal conductance properties has the potential for such an application requiring efficient heat transfer. In this work, we present thermal contact resistance measurement results for CNT and CNT-Cu composite films. It is shown that Cu-filled CNT arrays enhance thermal conductance when compared to as-grown CNT arrays. Furthermore, the CNT-Cu composite material provides a mechanically robust alternative to current IC packaging technology.
THERMAL CONDUCTIVITY OF NON-REPOSITORY LITHOSTRATIGRAPHIC LAYERS
Energy Technology Data Exchange (ETDEWEB)
R. JONES
2004-10-22
This model report addresses activities described in ''Technical Work Plan for: Near-Field Environment and Transport Thermal Properties and Analysis Reports Integration'' (BSC 2004 [DIRS 171708]). The model develops values for thermal conductivity, and its uncertainty, for the nonrepository layers of Yucca Mountain; in addition, the model provides estimates for matrix porosity and dry bulk density for the nonrepository layers. The studied lithostratigraphic units, as identified in the ''Geologic Framework Model'' (GFM 2000) (BSC 2004 [DIRS 170029]), are the Timber Mountain Group, the Tiva Canyon Tuff, the Yucca Mountain Tuff, the Pah Canyon Tuff, the Topopah Spring Tuff (excluding the repository layers), the Calico Hills Formation, the Prow Pass Tuff, the Bullfrog Tuff, and the Tram Tuff. The deepest model units of the GFM (Tund and Paleozoic) are excluded from this study because no data suitable for model input are available. The parameter estimates developed in this report are used as input to various models and calculations that simulate heat transport through the rock mass. Specifically, analysis model reports that use product output from this report are: (1) Drift-scale coupled processes (DST and TH seepage) models; (2) Drift degradation analysis; (3) Multiscale thermohydrologic model; and (4) Ventilation model and analysis report. In keeping with the methodology of the thermal conductivity model for the repository layers in ''Thermal Conductivity of the Potential Repository Horizon'' (BSC 2004 [DIRS 169854]), the Hsu et al. (1995 [DIRS 158073]) three-dimensional (3-D) cubic model (referred to herein as ''the Hsu model'') was used to represent the matrix thermal conductivity as a function of the four parameters (matrix porosity, thermal conductivity of the saturating fluid, thermal conductivity of the solid, and geometric connectivity of the solid). The Hsu model requires input data
A universal thermal conductance of charge carriers
Energy Technology Data Exchange (ETDEWEB)
Greiner, A.; Reggiani, L. [Lecce, Univ. (Italy). Ist. Nazionale di Fisica della Materia. Dipt. di Scienza dei Materiali; Kuhn, T. [Munster, Westfalische Wilhelms-Univ. (Germany). Inst. fur Theoretische Physik II; Varani, L. [Montpellier, Univ. Montpellier II (France). Centre d`Electronique et de Micro-optoelectronique
1996-12-01
A universal thermal conductance of charge carriers K = 2{pi}{sup 2}k{sub B}{sup 2}T / (3h) is rigorously derived within a correlation-function formalism. Similar to the case of the universal electrical conductance G = 2e{sup 2} / h this result pertains to one-dimensional, ballistic, and degenerate conditions for non-interacting particles.
Undergraduate Study of Thermal Conductivity of Metals
Directory of Open Access Journals (Sweden)
Ferrari T. B.
2002-01-01
Full Text Available In this work we analyze an undergraduate experiment used to determine the thermal conductivity of metals (K. We introduce few modifications in order to offer the student the chance to explore dierent models, learning the basic scientiffic method of developing appropriate and improved explanations for each experiment in order to better link theory and empirical results. Semi-empirical corrections are introduced in the system in order to check the experimental results according to previously reported K values. As specific cases we use copper [K = 0.92 cal /(°C s cm], aluminum [K = 0.49 cal /(°C s cm] and brass [K = 0.26 cal /(°C s cm] cylinders.
Thermal Conductivity of Alumina-reinforced Zirconia Composites
Bansal, Narottam P.
2005-01-01
10-mol% yttria-stabilized zirconia (10SZ) - alumina composites containing 0-30 mol% alumina were fabricated by hot pressing at 1500 C in vacuum. Thermal conductivity was determined at various temperatures using a steady-state laser heat flux technique. Thermal conductivity of the composites increased with increase in alumina content. Composites containing 0, 5, and 10-mol% alumina did not show any change in thermal conductivity with temperature. However, those containing 20 and 30-mol% alumina showed a decrease in thermal conductivity with increase in temperature. The measured values of thermal conductivity were in good agreement with those calculated from the Maxwell-Eucken model where one phase is uniformly dispersed within a second major continuous phase.
Thermal Conductivity of Ce Doped Bi-2212 Superconductors
Institute of Scientific and Technical Information of China (English)
LI Bo; WU Bai-Mei; M.Ausloos
2004-01-01
The temperature dependence of the thermal conductivity in Bi2Sr2 Ca1-x Cex Cu2Oy x = 0.1, 0.2, 0.3, 0.4 is presented. With increasing Ce-doping level, the thermal conductivity peak under TC is suppressed then disappears,while another peak appears at low temperatures for the non-superconducting compounds. The numerical analysis shows that the thermal conductivity peak under TC can be well described by the normal electron relaxation-time contribution model, and the phonon-induced thermal conductivity peak could be well described within the Debye approximation of the phonon spectrum. The existence and variation of these two thermal conductivity peaks indicate the adjustability between the superconducting and insulating components in the samples with different Ce-doping levels.
Thermal conductivity of hydrate-bearing sediments
Cortes, Douglas D.; Martin, Ana I.; Yun, Tae Sup; Francisca, Franco M.; Santamarina, J. Carlos; Ruppel, Carolyn
2009-11-01
A thorough understanding of the thermal conductivity of hydrate-bearing sediments is necessary for evaluating phase transformation processes that would accompany energy production from gas hydrate deposits and for estimating regional heat flow based on the observed depth to the base of the gas hydrate stability zone. The coexistence of multiple phases (gas hydrate, liquid and gas pore fill, and solid sediment grains) and their complex spatial arrangement hinder the a priori prediction of the thermal conductivity of hydrate-bearing sediments. Previous studies have been unable to capture the full parameter space covered by variations in grain size, specific surface, degree of saturation, nature of pore filling material, and effective stress for hydrate-bearing samples. Here we report on systematic measurements of the thermal conductivity of air dry, water- and tetrohydrofuran (THF)-saturated, and THF hydrate-saturated sand and clay samples at vertical effective stress of 0.05 to 1 MPa (corresponding to depths as great as 100 m below seafloor). Results reveal that the bulk thermal conductivity of the samples in every case reflects a complex interplay among particle size, effective stress, porosity, and fluid-versus-hydrate filled pore spaces. The thermal conductivity of THF hydrate-bearing soils increases upon hydrate formation although the thermal conductivities of THF solution and THF hydrate are almost the same. Several mechanisms can contribute to this effect including cryogenic suction during hydrate crystal growth and the ensuing porosity reduction in the surrounding sediment, increased mean effective stress due to hydrate formation under zero lateral strain conditions, and decreased interface thermal impedance as grain-liquid interfaces are transformed into grain-hydrate interfaces.
Thermal conductivity of hydrate-bearing sediments
Cortes, D.D.; Martin, A.I.; Yun, T.S.; Francisca, F.M.; Santamarina, J.C.; Ruppel, C.
2009-01-01
A thorough understanding of the thermal conductivity of hydrate-bearing sediments is necessary for evaluating phase transformation processes that would accompany energy production from gas hydrate deposits and for estimating regional heat flow based on the observed depth to the base of the gas hydrate stability zone. The coexistence of multiple phases (gas hydrate, liquid and gas pore fill, and solid sediment grains) and their complex spatial arrangement hinder the a priori prediction of the thermal conductivity of hydrate-bearing sediments. Previous studies have been unable to capture the full parameter space covered by variations in grain size, specific surface, degree of saturation, nature of pore filling material, and effective stress for hydrate-bearing samples. Here we report on systematic measurements of the thermal conductivity of air dry, water- and tetrohydrofuran (THF)-saturated, and THF hydrate-saturated sand and clay samples at vertical effective stress of 0.05 to 1 MPa (corresponding to depths as great as 100 m below seafloor). Results reveal that the bulk thermal conductivity of the samples in every case reflects a complex interplay among particle size, effective stress, porosity, and fluid-versus-hydrate filled pore spaces. The thermal conductivity of THF hydrate-bearing soils increases upon hydrate formation although the thermal conductivities of THF solution and THF hydrate are almost the same. Several mechanisms can contribute to this effect including cryogenic suction during hydrate crystal growth and the ensuing porosity reduction in the surrounding sediment, increased mean effective stress due to hydrate formation under zero lateral strain conditions, and decreased interface thermal impedance as grain-liquid interfaces are transformed into grain-hydrate interfaces. Copyright 2009 by the American Geophysical Union.
Thermal conductivity of different colored compomers.
Guler, Cigdem; Keles, Ali; Guler, Mehmet S; Karagoz, Sendogan; Cora, Ömer N; Keskin, Gul
2017-06-15
Compomers are mostly used in primary dentition. The thermal conductivity properties of traditional or colored compomers have not been investigated in detail so far. The aim of this in vitro study was to assess and compare the thermal conductivities of traditional and colored compomers. Two sets of compomers - namely, Twinky Star (available in berry, lemon, green, silver, blue, pink, gold and orange shades) and Dyract Extra (available in B1, A3 and A2 shades) - were included in this study. All of the traditional and colored compomers were applied to standard molds and polymerized according to the manufacturers' instructions. Three samples were prepared from each compomer. Measurements were conducted using a heat conduction test setup, and the coefficient of heat conductivity was calculated for each material. The heat conductivity coefficients were statistically analyzed using Kruskal-Wallis and Duncan tests. Uncertainty analysis was also performed on the calculated coefficients of heat conductivity. Statistically significant differences were found (p<0.05) between the thermal conductivity properties of the traditional and colored compomers examined. Among all of the tested compomers, the silver shade compomer exhibited the highest coefficient of heat conductivity (p<0.05), while the berry shade exhibited the lowest coefficient (p<0.05). Uncertainty analyses revealed that 6 out of 11 samples showed significant differences. The silver shade compomer should be avoided in deep cavities. The material properties could be improved for colored compomers.
Pandey, Hari Datt; Leitner, David M.
2017-08-01
Thermalization in molecular junctions and the extent to which it mediates thermal transport through the junction are explored and illustrated with computational modeling of polyethylene glycol (PEG) oligomer junctions. We calculate rates of thermalization in the PEG oligomers from 100 K to 600 K and thermal conduction through PEG oligomer interfaces between gold and other materials, including water, motivated in part by photothermal applications of gold nanoparticles capped by PEG oligomers in aqueous and cellular environments. Variation of thermalization rates over a range of oligomer lengths and temperatures reveals striking effects of thermalization on thermal conduction through the junction. The calculated thermalization rates help clarify the scope of applicability of approaches that can be used to predict thermal conduction, e.g., where Fourier's law breaks down and where a Landauer approach is suitable. The rates and nature of vibrational energy transport computed for PEG oligomers are compared with available experimental results.
Anisotropic Thermal Conduction in Polymers and its Molecular Origins
Nieto Simavilla, David; Venerus, David; Schieber, Jay; uCoSm Team
2014-03-01
Anisotropy in thermal conductivity has a significant impact on both processing and final properties of materials. Simple molecular arguments suggest that Fourier?s law must be generalized to allow for anisotropic thermal conductivity. We present two complementary experimental methods to obtain quantitative measurements of the thermal diffusivity (conductivity) tensor. We report anisotropic thermal diffusivity and stress in molten, cross-linked and solid polymers under several types of flows. Our results support the validity of a linear relationship between stress and anisotropy in thermal conductivity. When the proportionality constant, the stress-thermal coefficient, is made dimensionless by the plateau modulus of the polymer melt, a universal value of approximately 0.03 is observed for all chemistries. Such a universality is surprising, since phonon transport mechanisms are sensitive to chemical structure. For instance, the analogous stress-optic coefficient depends strongly on chemistry, and can even change sign. Connecting these measurements with current theories for thermal transport in amorphous materials, such as Minimum Thermal Conductivity (MTC) model, is crucial to understand the molecular origins of anisotropic thermal conduction in polymers.
Determining Effective Thermal Conductivity of Fabrics by Using Fractal Method
Zhu, Fanglong; Li, Kejing
2010-03-01
In this article, a fractal effective thermal conductivity model for woven fabrics with multiple layers is developed. Structural models of yarn and plain woven fabric are derived based on the fractal characteristics of macro-pores (gap or channel) between the yarns and micro-pores inside the yarns. The fractal effective thermal conductivity model can be expressed as a function of the pore structure (fractal dimension) and architectural parameters of the woven fabric. Good agreement is found between the fractal model and the thermal conductivity measurements in the general porosity ranges. It is expected that the model will be helpful in the evaluation of thermal comfort for woven fabric in the whole range of porosity.
Study on the Thermal Conductivity Model of Hollow Beads Insulating Mortar%玻化微珠保温砂浆导热系数模型研究
Institute of Scientific and Technical Information of China (English)
龚建清; 张婵韬
2014-01-01
Based on the minimum thermal resistance theory and homogenization method,the effective thermal conductivity of hollow beads insulating mortar was estimated.With ANSYS imitating the heat transmission of the 2D unit model of hollow beads insulating mortar,we can find it will bring about calcu-lation errors by considering the extreme cases of the transverse thermal resistance of resistance network. Compared with the effective thermal conductivity of 3D unit cell model calculated by ANSYS with three kinds of theoretical calculating value,it is more accurate than the effective thermal conductivity of unit cal-culated by the model of effective thermal resistance average.A model was built by assuming transverse thermal resistance infinitesimal and infinite.Final laboratory finding also confirms this conclusion.With only 0.2% deviation between the experiment values and the calculation of theoretical model,it is feasible to estimate the effective thermal conductivity of hollow bead insulating mortar.%基于最小热阻力法则和均匀化方法估算了玻化微珠保温砂浆的等效导热系数.用ANSYS模拟玻化微珠保温砂浆二维单元胞体的热传导，发现对热阻网络的横向热阻的极端考虑会给计算结果带来误差.用 ANSYS 计算的三维单元体模型的等效导热系数值与3种理论计算值进行比较，发现用假设横向热阻无穷小与假设横向热阻无穷大求得的单元体等效热阻的平均值作为单元体的等效热阻来求单元体等效导热系数更精确，最后实验也验证了这一结论.实验值与本文提出的理论模型计算值偏差仅为0.2%，证明用该方法来估算玻化微珠保温砂浆的导热系数是可行的.
Thermal conductivity and interface thermal conductance of thin films in Li ion batteries
Jagannadham, K.
2016-09-01
Laser physical vapor deposition is used to deposit thin films of lithium phosphorous oxynitride in nitrogen and lithium nickel manganese oxide in oxygen ambient on Si substrate. LIPON film is also deposited on LiNiMnO film that is deposited on Si. Graphene films consisting of graphene platelets are deposited on Si substrate from a suspension in isopropyl alcohol. Li-graphene films are obtained after Li adsorption by immersion in LiCl solution and further drying. Transient thermo reflectance signal is used to determine the cross-plane thermal conductivity of different layers and interface thermal conductance of the interfaces. The results show that LIPON film with lower thermal conductivity is a thermal barrier. The interface thermal conductance between LIPON and Au or Si is found to be very low. Thermal conductivity of LiNiMnO is found to be reasonably high so that it is not a barrier to thermal transport. Film with graphene platelets shows a higher value and Li adsorbed graphene film shows a much higher value of cross-plane thermal conductivity. The value of interface thermal conductance between graphene and Au or Si (100) substrate is also much lower. The implications of the results for the thermal transport in thin film Li batteries are discussed.
Modulating thermal conduction by the axial strain
Jiang, Jianjun; Zhao, Hong
2016-09-01
Recent studies have revealed that the symmetry of interparticle potential plays an important role in the one-dimensional thermal conduction problem. Here we demonstrate that, by introducing strain into the Fermi-Pasta-Ulam-β lattice, the interparticle potential can be converted from symmetric to asymmetric, which leads to a change of the asymptotic decaying behavior of the heat current autocorrelation function. More specifically, such a change in the symmetry of the potential induces a fast decaying stage, in which the heat current autocorrelation function decays faster than power-law manners or in a power-law manner but faster than ~t -1, in the transient stage. The duration of the fast decaying stage increases with increasing strain ratio and decreasing of the temperature. As a result, the thermal conductivity calculated following the Green-Kubo formula may show a truncation-time independent behavior, suggesting a system-size independent thermal conductivity.
Thermal Conductivity Measurements of Caged Structural Superconductors
Matsuzaki, H.; Hida, K.; Kase, N.; Nakano, T.; Takeda, N.
Thermal conductivity of Ca3Rh4Sn13 and Sr3Ir4Sn13 were measured in magnetic fields to reveal superconducting state. From magnetic susceptibility χ(T) and electrical resistivity ρ(T) measurements, superconducting transition temperature Tc of Ca3Rh4Sn13 and Sr3Ir4Sn13 is determined to be 8 and 5 K, respectively. Thermal conductivity κ(T) of Ca3Rh4Sn13 indicates that superconducting state is nodeless s-wave, because residual thermal conductivity κ0/T in zero magnetic field is very small. On the other hand, κ(T) of Sr3Ir4Sn13 in zero magnetic field suggests that superconductivity possesses nodal gap rather than full gap. Whether nodal superconducting gap exists or not still remains to be clarified, because there is a possibility that the achieving temperature is insufficient to discuss superconducting state.
New Density-based Thermal Conductivity Equation for Snow
Directory of Open Access Journals (Sweden)
R.K. Aggarwal
2009-03-01
Full Text Available More than two hundred thermal conductivity measurements for different snow densities and snow types were carried out in-situ at a field research station located in greater Himalayan range of India. These measurements were carried out using a commercially available portable thermal conductivity meter. Thermal conductivity measurements were carried out on the fresh snow, equi-temperature snow, and surface hoar and temperaturegradient snow. Average thermal conductivity of snow varied from 0.08 W/mK (Fresh snow of 120 kg/m3 density to 0.32 W/m K (Equi-temperature snow of 420 kg/m3 density. Based on these measurements, a new density-based thermal conductivity equation is proposed. Using this proposed equation, modeled snowpack temperatures showed closer agreement with the observed data as compared to the predictions based on other well-known empirical and theoretical thermal conductivity equations for snow. This study highlights the advantages and limitations of empirical based thermal conductivity equations over the complex models based on snow microstructure.Defence Science Journal, 2009, 59(2, pp.126-130, DOI:http://dx.doi.org/10.14429/dsj.59.1499
Temperature Dependence of Thermal Conductivity of Nanofluids
Institute of Scientific and Technical Information of China (English)
LI Yu-Hua; QU Wei; FENG Jian-Chao
2008-01-01
Mechanism of thermal conductivity of nanofluids is analysed and calculated, including Brownian motion effects, particle agglomeration and viscosity, together influenced by temperature. The results show that only Brownian motion as reported is not enough to describe the temperature dependence of the thermal conductivity of nanofluids. The change of particle agglomeration and viscosity with temperature are also important factors. As temperature increases, the reduction of the particle surface energy would decrease the agglomeration of nanopartides, and the reduction of viscosity would improve the Brownian motion. The results agree well with the experimental data reported.
Anisotropic thermal conductivity of magnetic fluids
Institute of Scientific and Technical Information of China (English)
Xiaopeng Fang; Yimin Xuan; Qiang Li
2009-01-01
Considering the forces acting on the particles and the motion of the particles, this study uses a numerical simulation to investigate the three-dimensional microstructure of the magnetic fluids in the presence of an external magnetic field. A method is proposed for predicting the anisotropic thermal conductivity of magnetic fluids. By introducing an anisotropic structure parameter which characterizes the non-uniform distribution of particles suspended in the magnetic fluids, the traditional Maxwell formula is modified and extended to calculate anisotropic thermal conductivity of the magnetic fluids. The results show that in the presence of an external magnetic field the magnetic nanoparticles form chainlike clusters along the direction of the external magnetic field, which leads to the fact that the thermal conduc-tivity of the magnetic fluid along the chain direction is bigger than that along other directions. The thermal conductivity of the magnetic fluids presents an anisotropic feature. With the increase of the magnetic field strength the chainlike clusters in the magnetic fluid appear to be more obvious, so that the anisotropic feature of heat conduction in the fluids becomes more evident.
Thermal Conductivity from Core and Well log Data
Hartmann, Andreas; Clauser, Christoph
2008-01-01
The relationships between thermal conductivity and other petrophysical properties have been analysed for a borehole drilled in a Tertiary Flysch sequence. We establish equations that permit us to predict rock thermal conductivity from logging data. A regression analysis of thermal conductivity, bulk density, and sonic velocity yields thermal conductivity with an average accuracy of better than 0.2 W/(m K). As a second step, logging data is used to compute a lithological depth profile, which in turn is used to calculate a thermal conductivity profile. From a comparison of the conductivity-depth profile and the laboratory data it can be concluded that thermal conductivity can be computed with an accuracy of less than 0.3 W/(m K)from conventional wireline data. The comparison of two different models shows that this approach can be practical even if old and incomplete logging data is used. The results can be used to infer thermal conductivity for boreholes without appropriate core data that are drilled in a simil...
An Innovative High Thermal Conductivity Fuel Design
Energy Technology Data Exchange (ETDEWEB)
PI: James S. Tulenko; Co-PI: Ronald H. Baney,
2007-10-14
Uranium dioxide (UO2) is the most common fuel material in commercial nuclear power reactors. UO2 has the advantages of a high melting point, good high-temperature stability, good chemical compatibility with cladding and coolant, and resistance to radiation. The main disadvantage of UO2 is its low thermal conductivity. During a reactor’s operation, because the thermal conductivity of UO2 is very low, for example, about 2.8 W/m-K at 1000 oC [1], there is a large temperature gradient in the UO2 fuel pellet, causing a very high centerline temperature, and introducing thermal stresses, which lead to extensive fuel pellet cracking. These cracks will add to the release of fission product gases after high burnup. The high fuel operating temperature also increases the rate of fission gas release and the fuel pellet swelling caused by fission gases bubbles. The amount of fission gas release and fuel swelling limits the life time of UO2 fuel in reactor. In addition, the high centerline temperature and large temperature gradient in the fuel pellet, leading to a large amount of stored heat, increase the Zircaloy cladding temperature in a lost of coolant accident (LOCA). The rate of Zircaloy-water reaction becomes significant at the temperature above 1200 oC [2]. The ZrO2 layer generated on the surface of the Zircaloy cladding will affect the heat conduction, and will cause a Zircaloy cladding rupture. The objective of this research is to increase the thermal conductivity of UO2, while not affecting the neutronic property of UO2 significantly. The concept to accomplish this goal is to incorporate another material with high thermal conductivity into the UO2 pellet. Silicon carbide (SiC) is a good candidate, because the thermal conductivity of single crystal SiC is 60 times higher than that of UO2 at room temperature and 30 times higher at 800 oC [3]. Silicon carbide also has the properties of low thermal neutron absorption cross section, high melting point, good chemical
Determination of Radiative Thermal Conductivity in Needlepunched Nonwovens
Directory of Open Access Journals (Sweden)
Rahul Vallabh
2008-12-01
Full Text Available Radiation heat transfer is found to be the dominant mode of heat transfer at temperatures higher than 400-500K [11]. Convection heat transfer being negligible in nonwovens, effective thermal conductivity is given by the sum of its conduction and radiation components. In this research two methods were identified to determine radiative thermal conductivity of needlepunched samples made from Nomex fibers. The first method involved the determination of radiative thermal conductivity using effective (total thermal conductivity determined using a Guarded Hot Plate (GHP instrument. In the second method radiative thermal conductivity was estimated using the extinction coefficient of samples. The extinction coefficient was determined by using direct transmission measurements made using a Fourier Transform InfraRed (FTIR spectrometer. Results confirmed that radiation was the dominant mode of heat transfer at temperatures higher than 535 K. The conduction component of effective thermal conductivity did not change much in the range of densities tested. Empirical models for predicting the temperature difference across thickness of the fabric and the radiative thermal conductivity with R-square values of 0.94 and 0.88 respectively showed that fabric density, fabric thickness, fiber fineness, fiber length, mean pore size and applied temperature were found to have significant effect on the effective thermal conductivity and its radiation component. Though a high correlation between the results of Method 1 (Guarded Hot Plate and Method 2 (FTIR was not seen, the absorbance measurements made using the FTIR spectrometer were found to have significant effect on the radiative thermal conductivity.
Investigations Regarding the Thermal Conductivity of Straw
Directory of Open Access Journals (Sweden)
Marian Pruteanu
2010-01-01
Full Text Available The reduction of buildings heat losses and pollutants emissions is a worldwide priority. It’s intending to reduce the specific final energy consumption under limit of 120...150 kWh/m2.yr and even under 15...45 kWh/m2.yr, foreseen in 2020 for the passive houses, which is necessary for a sustainable development and for allowing to became profitable the use of unconventional energies [1]. These values can be achieved through the use of thermal insulations, for protecting the constructions fund and through making envelope elements, as much as possible, from materials with a high thermal resistance, for new buildings. With intention to substitute the conventional thermal insulations: mineral wool, expanded polystyrene, which are both great energy consumers, it’s proposed, among others unconventional technologies and materials, the use of vegetable wastes both as a thermal insulation material and as a material used for building load-bearing and in-fill straw-bale construction. In speciality literature there are presented experimental determinations of this material’s thermal conductivity. The paper proposes a simple method, adequate for the measurement of thermal conductivity for bulk’s materials as straw bales.
Ghafouri, A.; Salari, M.; Jozaei, A. F.
2017-01-01
In this numerical study, the effects of variable thermal conductivity models on the combined convection heat transfer in a two-dimensional lid-driven square enclosure are investigated. The fluid in the square enclosure is a water-based nanofluid containing alumina nanoparticles. The top and bottom horizontal walls are insulated, while the vertical walls are kept at different constant temperatures. Five different thermal conductivity models are used to evaluate the effects of various parameters, such as the nanofluid bulk temperature, nanoparticle size, nanoparticle volume fraction, Brownian motion, interfacial layer thickness, etc. The governing stream-vorticity equations are solved by using a second-order central finite difference scheme coupled with the conservation of mass and energy. It is found that higher heat transfer is predicted when the effects of the nanoparticle size and bulk temperature of the nanofluid are taken into account.
Predicting the effective thermal conductivity of carbon nanotube based nanofluids
Energy Technology Data Exchange (ETDEWEB)
Sastry, N N Venkata; Bhunia, Avijit; Sundararajan, T; Das, Sarit K [Department of Mechanical Engineering, Indian Institute of Technology, Madras, Chennai 600 036 (India)
2008-02-06
Adding a small volume fraction of carbon nanotubes (CNTs) to a liquid enhances the thermal conductivity significantly. Recent experimental findings report an anomalously wide range of enhancement values that continue to perplex the research community and remain unexplained. In this paper we present a theoretical model based on three-dimensional CNT chain formation (percolation) in the base liquid and the corresponding thermal resistance network. The model considers random CNT orientation and CNT-CNT interaction forming the percolating chain. Predictions are in good agreement with almost all available experimental data. Results show that the enhancement critically depends on the CNT geometry (length), volume fraction, thermal conductivity of the base liquid and the nanofluid (CNT-liquid suspension) preparation technique. Based on the physical mechanism of heat conduction in the nanofluid, we introduce a new dimensionless parameter that alone characterizes the nanofluid thermal conductivity with reasonable accuracy ({approx} {+-} 5%)
Predicting the effective thermal conductivity of carbon nanotube based nanofluids.
Venkata Sastry, N N; Bhunia, Avijit; Sundararajan, T; Das, Sarit K
2008-02-06
Adding a small volume fraction of carbon nanotubes (CNTs) to a liquid enhances the thermal conductivity significantly. Recent experimental findings report an anomalously wide range of enhancement values that continue to perplex the research community and remain unexplained. In this paper we present a theoretical model based on three-dimensional CNT chain formation (percolation) in the base liquid and the corresponding thermal resistance network. The model considers random CNT orientation and CNT-CNT interaction forming the percolating chain. Predictions are in good agreement with almost all available experimental data. Results show that the enhancement critically depends on the CNT geometry (length), volume fraction, thermal conductivity of the base liquid and the nanofluid (CNT-liquid suspension) preparation technique. Based on the physical mechanism of heat conduction in the nanofluid, we introduce a new dimensionless parameter that alone characterizes the nanofluid thermal conductivity with reasonable accuracy (∼ ± 5%).
Neural Network for Predicting Thermal Conductivity of Knit Materials
Directory of Open Access Journals (Sweden)
Faten Fayala, Ph.D.
2008-12-01
Full Text Available The major aim of comfort research is to find the comfort temperature for an individual or group. This subjective property can be evaluated by means of thermal conductivity as a physical characteristic of fabric. This phenomenon depends on many fabric parameters and it is difficult to study the effect of ones without changing the others. In addition, the non-linear relationship of fabric parameters and thermal conductivity handicap mathematical modelling. So a neural network approach was used to predict the thermal conductivity of knitting structure as a function of porosity, air permeability, weight and fiber conductivity. Data on thermal conductivity are measured by experiments carried out on jersey knitted structure.
Thermal Conductivity of Polyimide/Nanofiller Blends
Ghose, S.; Watson, K. A.; Delozier, D. M.; Working, D. c.; Connell, J. W.; Smith, J. G.; Sun, Y. P.; Lin, Y.
2006-01-01
In efforts to improve the thermal conductivity of Ultem(TM) 1000, it was compounded with three carbon based nano-fillers. Multiwalled carbon nanotubes (MWCNT), vapor grown carbon nanofibers (CNF) and expanded graphite (EG) were investigated. Ribbons were extruded to form samples in which the nano-fillers were aligned. Samples were also fabricated by compression molding in which the nano-fillers were randomly oriented. The thermal properties were evaluated by DSC and TGA, and the mechanical properties of the aligned samples were determined by tensile testing. The degree of dispersion and alignment of the nanoparticles were investigated with high-resolution scanning electron microscopy. The thermal conductivity of the samples was measured in both the direction of alignment as well as perpendicular to that direction using the Nanoflash technique. The results of this study will be presented.
Juszczyk, J; Kaźmierczak-Bałata, A; Firek, P; Bodzenta, J
2017-01-27
While measuring the thermal properties of a thin film, one of the most often encountered problems is the influence of the substrate thermal properties on measured signal and the need for its separation. In this work an approach for determining the thermal conductivity κ of a thin layer is presented. It bases on Scanning Thermal Microscopy (SThM) measurement combined with thermal spreading resistance analysis for a system consisting of a single layer on a substrate. Presented approach allows to take into account the influence of the substrate thermal properties on SThM signal and to estimate the true value of a thin film κ. It is based on analytical solution of the problem being a function of dimensionless parameters and requires numerical solution of relatively simple integral equation. As the analysis utilizes a solution in dimensionless parameters it can be used for any substrate-layer system. As an example, the method was applied for determination of the thermal conductivities of 4 different thin layers of thicknesses from 12 to 100nm. The impact of model parameters on the uncertainty of the estimated final κ value was analyzed.
Thermal conductivity of a new insulator
Energy Technology Data Exchange (ETDEWEB)
Payamara, Jahangir [Physics Department, Shahed University (Iran, Islamic Republic of)], E-mail: jahangirpayamara@yahoo.com
2011-07-01
With the depletion of energy resources it becomes increasingly important to save energy. Significant amounts of energy are consumed in residential and commercial buildings, mainly for space heating. The aim of this paper is to assess the thermal conductivity of gunny, a new insulator produced in the Middle East and Far East from plant fiber. An insulation chamber of 0.75x0.6x1m3 was built in the physics department of Shahed University and measurements of the thermal conductivity of gunny were carried out. The thermal conductivity of gunny was found to be 0.80 joules per second meter degree celsius which is good in comparison to wood's thermal conductivity. In addition, results showed that the rate of heat energy hitting the cooler end is lower than that reaching the hot end and that gunny leads to energy savings in buildings. This study demonstrated that gunny can be considered a desirable insulator for buildings.
Dependence of thermal conductivity of snow on microstructure
Indian Academy of Sciences (India)
P K Satyawali; A K Singh
2008-08-01
A geometrical model,including different geometrical shapes in ﬂuencing thermal conductivity of snow is proposed.The geometrical model has been assumed to comprise of unit cells having solid (ice)inclusion as an aggregation of spherical,cylindrical or cubical shapes with vertical connection, arranged in a cubic packing.From the geometrical model and one-dimensional heat transfer theory, the effective thermal conductivity has been computed.For this purpose,coupled one-dimensional heat transfer equations have been solved for steady-state condition to account for conduction in ice, conduction in air and latent heat transfer due to water vapour sublimation through air.The model demonstrates the dependency of thermal conductivity on density,grain-spacing,grain contact ratio and temperature.Spherical inclusions give highest conductivity while cubical inclusion estimates lowest value for the same density.Thermal conductivity has been found increasing sharply near to the packing density for all three shapes.Empirical model results and results obtained from existing microstructure based models have also been compared with the present model.
Thermal conductivity of polymer composites with oriented boron nitride
Energy Technology Data Exchange (ETDEWEB)
Ahn, Hong Jun; Eoh, Young Jun [Department of Materials Engineering, Kyonggi University, Suwon (Korea, Republic of); Park, Sung Dae [Electronic Materials and Device Research Center, Korea Electronics Technology Institute, Seongnam (Korea, Republic of); Kim, Eung Soo, E-mail: eskim@kyonggi.ac.kr [Department of Materials Engineering, Kyonggi University, Suwon (Korea, Republic of)
2014-08-20
Highlights: • Thermal conductivity depended on the orientation of BN in the polymer matrices. • Hexagonal boron nitride (BN) particles were treated by C{sub 27}H{sub 27}N{sub 3}O{sub 2} and C{sub 14}H{sub 6}O{sub 8}. • Amphiphilic-agent-treated BN particles are more easily oriented in the composite. • BN/PVA composites with C{sub 14}H{sub 6}O{sub 8}-treated BN showed the highest thermal conductivity. • Thermal conductivity of the composites was compared with several theoretical models. - Abstract: Thermal conductivity of boron nitride (BN) with polyvinyl alcohol (PVA) and/or polyvinyl butyral (PVB) was investigated as a function of the degree of BN orientation, the numbers of hydroxyl groups in the polymer matrices and the amphiphilic agents used. The composites with in-plane orientation of BN showed a higher thermal conductivity than the composites with out-of-plane orientation of BN due to the increase of thermal pathway. For a given BN content, the composites with in-plane orientation of BN/PVA showed higher thermal conductivity than the composites with in-plane orientation of BN/PVB. This result could be attributed to the improved degree of orientation of BN, caused by a larger number of hydroxyl groups being present. Those treated with C{sub 14}H{sub 6}O{sub 8} amphiphilic agent demonstrated a higher thermal conductivity than those treated by C{sub 27}H{sub 27}N{sub 3}O{sub 2}. The measured thermal conductivity of the composites was compared with that predicted by the several theoretical models.
Impulse propagation in a conducting medium with arbitrary thermal conductivity
Energy Technology Data Exchange (ETDEWEB)
Myasnikov, S.P.
1977-07-01
An examination is made of impulse propagation in a conducting medium that accounts for its thermal conductivity. Such a medium, even with an infinitely large electric conductivity, will have a weak dispersion. Following dispersion through a sufficiently large time interval, out of the entire set of planar waves comprising a wave packet, only the low-frequency components were shown to remain (these are the components that are propagated at a velocity of c/sub s/) along with the high-frequency components that are propagated at the speed of c/sub T/. Consequently, the initial derangement is converted into two separate waves of a bell-shaped form that run to various sides at a phase velocity equal to the adiabatic speed of sound c/sub s/. 6 references.
Lawson, John W.; Daw, Murray S.; Squire, Thomas H.; Bauschlicher, Charles W.
2012-01-01
We are developing a multiscale framework in computational modeling for the ultra high temperature ceramics (UHTC) ZrB2 and HfB2. These materials are characterized by high melting point, good strength, and reasonable oxidation resistance. They are candidate materials for a number of applications in extreme environments including sharp leading edges of hypersonic aircraft. In particular, we used a combination of ab initio methods, atomistic simulations and continuum computations to obtain insights into fundamental properties of these materials. Ab initio methods were used to compute basic structural, mechanical and thermal properties. From these results, a database was constructed to fit a Tersoff style interatomic potential suitable for atomistic simulations. These potentials were used to evaluate the lattice thermal conductivity of single crystals and the thermal resistance of simple grain boundaries. Finite element method (FEM) computations using atomistic results as inputs were performed with meshes constructed on SEM images thereby modeling the realistic microstructure. These continuum computations showed the reduction in thermal conductivity due to the grain boundary network.
Advanced Testing Method for Ground Thermal Conductivity
Energy Technology Data Exchange (ETDEWEB)
Liu, Xiaobing [ORNL; Clemenzi, Rick [Geothermal Design Center Inc.; Liu, Su [University of Tennessee (UT)
2017-04-01
A new method is developed that can quickly and more accurately determine the effective ground thermal conductivity (GTC) based on thermal response test (TRT) results. Ground thermal conductivity is an important parameter for sizing ground heat exchangers (GHEXs) used by geothermal heat pump systems. The conventional GTC test method usually requires a TRT for 48 hours with a very stable electric power supply throughout the entire test. In contrast, the new method reduces the required test time by 40%–60% or more, and it can determine GTC even with an unstable or intermittent power supply. Consequently, it can significantly reduce the cost of GTC testing and increase its use, which will enable optimal design of geothermal heat pump systems. Further, this new method provides more information about the thermal properties of the GHEX and the ground than previous techniques. It can verify the installation quality of GHEXs and has the potential, if developed, to characterize the heterogeneous thermal properties of the ground formation surrounding the GHEXs.
Anisotropic thermal conductivity in epoxy-bonded magnetocaloric composites
Weise, Bruno; Sellschopp, Kai; Bierdel, Marius; Funk, Alexander; Bobeth, Manfred; Krautz, Maria; Waske, Anja
2016-09-01
Thermal management is one of the crucial issues in the development of magnetocaloric refrigeration technology for application. In order to ensure optimal exploitation of the materials "primary" properties, such as entropy change and temperature lift, thermal properties (and other "secondary" properties) play an important role. In magnetocaloric composites, which show an increased cycling stability in comparison to their bulk counterparts, thermal properties are strongly determined by the geometric arrangement of the corresponding components. In the first part of this paper, the inner structure of a polymer-bonded La(Fe, Co, Si)13-composite was studied by X-ray computed tomography. Based on this 3D data, a numerical study along all three spatial directions revealed anisotropic thermal conductivity of the composite: Due to the preparation process, the long-axis of the magnetocaloric particles is aligned along the xy plane which is why the in-plane thermal conductivity is larger than the thermal conductivity along the z-axis. Further, the study is expanded to a second aspect devoted to the influence of particle distribution and alignment within the polymer matrix. Based on an equivalent ellipsoids model to describe the inner structure of the composite, numerical simulation of the thermal conductivity in different particle arrangements and orientation distributions were performed. This paper evaluates the possibilities of microstructural design for inducing and adjusting anisotropic thermal conductivity in magnetocaloric composites.
Thermal Conductivity Measurement and Analysis of Fully Ceramic Microencapsulated fuel
Energy Technology Data Exchange (ETDEWEB)
Lee, H. G.; Kim, D. J.; Park, J. Y.; Kim, W. J. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Lee, S. J. [KEPCO Nuclear Fuel, Daejeon (Korea, Republic of)
2015-10-15
FCM nuclear fuel is composed of tristructural isotropic(TRISO) fuel particle and SiC ceramic matrix. SiC ceramic matrix play an essential part in protecting fission product. In the FCM fuel concept, fission product is doubly protected by TRISO coating layer and SiC ceramic matrix in comparison with the current commercial UO2 fuel system of LWR. In addition to a safety enhancement of FCM fuel, thermal conductivity of SiC ceramic matrix is better than that of UO2 fuel. Because the centerline temperature of FCM fuel is lower than that of the current UO2 fuel due to the difference of thermal conductivity of fuel, an operational release of fission products from the fuel can be reduced. SiC ceramic has attracted for nuclear fuel application due to its high thermal conductivity properties with good radiation tolerant properties, a low neutron absorption cross-section and a high corrosion resistance. Thermal conductivity of ceramic matrix composite depends on the thermal conductivity of each component and the morphology of reinforcement materials such as fibers and particles. There are many results about thermal conductivity of fiber-reinforced composite like as SiCf/SiC composite. Thermal conductivity of SiC ceramics and FCM pellets with the volume fraction of TRISO particles were measured and analyzed by analytical models. Polycrystalline SiC ceramics and FCM pellets with TRISO particles were fabricated by hot press sintering with sintering additives. Thermal conductivity of the FCM pellets with TRISO particles of 0 vol.%, 10 vol.%, 20 vol.%, 30 vol.% and 40 vol.% show 68.4, 52.3, 46.8, 43.0 and 34.5 W/mK, respectively. As the volume fraction of TRISO particles increased, the measured thermal conductivity values closely followed the prediction of Maxwell's equation.
Thermal conductivity enhancement in thermal grease containing different CuO structures.
Yu, Wei; Zhao, Junchang; Wang, Mingzhu; Hu, Yiheng; Chen, Lifei; Xie, Huaqing
2015-01-01
Different cupric oxide (CuO) structures have attracted intensive interest because of their promising applications in various fields. In this study, three kinds of CuO structures, namely, CuO microdisks, CuO nanoblocks, and CuO microspheres, are synthesized by solution-based synthetic methods. The morphologies and crystal structures of these CuO structures are characterized by field-emission scanning electron microscope and X-ray diffractometer, respectively. They are used as thermal conductive fillers to prepare silicone-based thermal greases, giving rise to great enhancement in thermal conductivity. Compared with pure silicone base, the thermal conductivities of thermal greases with CuO microdisks, CuO nanoblocks, and CuO microspheres are 0.283, 0256, and 0.239 W/mK, respectively, at filler loading of 9 vol.%, which increases 139%, 116%, and 99%, respectively. These thermal greases present a slight descendent tendency in thermal conductivity at elevated temperatures. These experimental data are compared with Nan's model prediction, indicating that the shape factor has a great influence on thermal conductivity improvement of thermal greases with different CuO structures. Meanwhile, due to large aspect ratio of CuO microdisks, they can form thermal networks more effectively than the other two structures, resulting in higher thermal conductivity enhancement.
Thermal conductivity enhancement of nanofluids containing graphene nanosheets
Sen Gupta, Soujit; Manoj Siva, V.; Krishnan, Sreenath; Sreeprasad, T. S.; Singh, Pawan K.; Pradeep, T.; Das, Sarit K.
2011-10-01
This paper envisages a mechanism of heat conduction behind the thermal conductivity enhancement observed in graphene nanofluids. Graphene nanofluids have been prepared, characterized, and their thermal conductivity was measured using the transient hot wire method. The enhancements in thermal conductivity are substantial even at lower concentrations and are not predicted by the classical Maxwell model. The enhancement also shows strong temperature dependence which is unlike its carbon predecessors, carbon nanotube (CNT) and graphene oxide nanofluids. It is also seen that the magnitude of enhancement is in-between CNT and metallic/metal oxide nanofluids. This could be an indication that the mechanism of heat conduction is a combination of percolation in CNT and Brownian motion and micro convection effects in metallic/metal oxide nanofluids, leading to a strong proposition of a hybrid model.
Energy Technology Data Exchange (ETDEWEB)
Ha, K.P. [Seoul National University Graduate School, Seoul (Korea); Kauh, S.K. [Seoul National University, Seoul (Korea)
1999-04-01
Stator winding and endwinding are hot spots of a induction motor, and their temperature are heavily affected by the thermal conductivity of stator winding, endwinding and iron core. Hence, thermal conductivity evaluation of those materials is very important and the present study proposed prediction schemes for directional thermal conductivity of stator winding, endwinding, and iron core of a small induction motor. Longitudinal thermal conductivity of stator winding is evaluated by serial model, and transversal thermal conductivity is by Lewis and Nielson's model. Thermal conductivity of endwinding can be obtained by rotational transform of thermal conductivity tensor. And thermal conductivity of iron core is evaluated by serial model and parallel model. In the evaluation of the thermal conductivity of iron core, it was assumed that the contact resistance between the core plates plays 80% role in total resistance. This requires more detailed analysis. (author). 11 refs., 5 figs., 3 tabs.
Fabrication and Characterization of a Conduction Cooled Thermal Neutron Filter
Energy Technology Data Exchange (ETDEWEB)
Heather Wampler; Adam Gerth; Heng Ban; Donna Post Guillen; Douglas Porter; Cynthia Papesch
2010-06-01
Installation of a conduction cooled thermal (low-energy) neutron filter in an existing domestic test reactor would provide the U.S. the capability to test new reactor fuels and materials for advanced fast (high-energy) reactor concepts. A composite consisting of Al3Hf-Al has been proposed for the neutron filter due to both the neutron filtering properties of hafnium and the conducting capabilities of aluminum. Knowledge of the thermal conductivity of the Al3Hf-Al composite is essential for the design of the filtering system. The present objectives are to identify a suitable fabrication technique and to measure the thermophysical properties of the Al3Hf intermetallic, which has not been done previous to this study. A centrifugal casting method was used to prepare samples of Al3Hf. X-ray diffraction and Rietveld analysis were conducted to determine the structural make-up of each of the samples. Thermophysical properties were measured as follows: specific heat by a differential scanning calorimeter (DSC), thermal diffusivity by a laser flash thermal diffusivity measuring system, thermal expansion by a dilatometer, and thermal conductivity was calculated based on the previous measurements. All measurements were acquired over a temperature range of 90°C - 375°C with some measurements outside these bounds. The average thermal conductivity of the intermetallic Al3Hf (~7 at.% Hf) was found to be ~ 41 W/m-K for the given temperature range. This information fills a knowledge gap in the thermophysical properties of the intermetallic Al3Hf with the specified percentage of hafnium. A model designed to predict composite properties was used to calculate a thermal conductivity of ~177 W/m-K for an Al3Hf-Al composite with 23 vol% Al3Hf. This calculation was based upon the average thermal conductivity of Al3Hf over the specified temperature range.
Thermal conductivity at different humidity conditions
DEFF Research Database (Denmark)
Kristiansen, Finn Harken; Rode, Carsten
1999-01-01
The thermal conductivity (the l-value) of several alternative insulation products and a traditional product is determined under different humidity conditions in a specially constructed hot plate apparatus.The hot plate apparatus is constructed with an air gap on each side of the test specimen where...... humidified air can pass. Thus, it is possible to build up different degrees of moisture on each side of the test specimen.The thermal conductivity is determined for the following types of alternative insulation: sheep's wool, flax, paper insulation, perlite and mineral wool. The insulation products were...... by an accumulation of moisture as condensation in the parts of the insulation that lie immediately close to the cold side of the apparatus. The high l-values found are therefore of no practical importance in structures where no condensation occurs. Disregarding these condensation situations, the maximum increase...
Thermal conductivity at different humidity conditions
DEFF Research Database (Denmark)
Kristiansen, Finn Harken; Rode, Carsten
1999-01-01
humidified air can pass. Thus, it is possible to build up different degrees of moisture on each side of the test specimen.The thermal conductivity is determined for the following types of alternative insulation: sheep's wool, flax, paper insulation, perlite and mineral wool. The insulation products were......The thermal conductivity (the l-value) of several alternative insulation products and a traditional product is determined under different humidity conditions in a specially constructed hot plate apparatus.The hot plate apparatus is constructed with an air gap on each side of the test specimen where...... Ekofiber Vind, Herawool (without support fibres), Heraflax, Isodan with and without salts, Miljø Isolering with and without salts, Perlite (water-repellent), and Rockwool A-batts for comparison.All measurements of the materials started with no affection of moisture. Nevertheless, results were achieved...
Ultralow Thermal Conductivity in Full Heusler Semiconductors
He, Jiangang; Amsler, Maximilian; Xia, Yi; Naghavi, S. Shahab; Hegde, Vinay I.; Hao, Shiqiang; Goedecker, Stefan; OzoliĆš, Vidvuds; Wolverton, Chris
2016-07-01
Semiconducting half and, to a lesser extent, full Heusler compounds are promising thermoelectric materials due to their compelling electronic properties with large power factors. However, intrinsically high thermal conductivity resulting in a limited thermoelectric efficiency has so far impeded their widespread use in practical applications. Here, we report the computational discovery of a class of hitherto unknown stable semiconducting full Heusler compounds with ten valence electrons (X2Y Z , X =Ca , Sr, and Ba; Y =Au and Hg; Z =Sn , Pb, As, Sb, and Bi) through high-throughput ab initio screening. These new compounds exhibit ultralow lattice thermal conductivity κL close to the theoretical minimum due to strong anharmonic rattling of the heavy noble metals, while preserving high power factors, thus resulting in excellent phonon-glass electron-crystal materials.
Workshop on thin film thermal conductivity measurements
Feldman, Albert; Balzaretti, Naira M.; Guenther, Arthur H.
1998-04-01
On a subject of considerable import to the laser-induced damage community, a two day workshop on the topic, Thin Film Thermal Conductivity Measurement was held as part of the 13th Symposium on Thermophysical Properties at the University of Colorado in Boulder CO, June 25 and 26, 1997. The Workshop consisted of 4 sessions of 17 oral presentations and two discussion sessions. Two related subjects of interest were covered; 1) methods and problems associated with measuring thermal conductivity ((kappa) ) of thin films, and 2) measuring and (kappa) of chemical vapor deposited (CVD) diamond. On the subject of thin film (kappa) measurement, several recently developed imaginative techniques were reviewed. However, several authors disagreed on how much (kappa) in a film differs from (kappa) in a bulk material of the same nominal composition. A subject of controversy was the definition of an interface. In the first discussion session, several questions were addressed, a principal one being, how do we know that the values of (kappa) we obtain are correct and is there a role for standards in thin film (kappa) measurement. The second discussion session was devoted to a round-robin interlaboratory comparison of (kappa) measurements on a set of CVD diamond specimens and several other specimens of lower thermal conductivity. Large interlaboratory differences obtained in an earlier round robin had been attributed to specimen inhomogeneity. Unfortunately, large differences were also observed in the second round robin even though the specimens were more homogenous. There was good consistency among the DC measurements, however, the AC measurements showed much greater variability. There was positive feedback from most of the attenders regarding the Workshop with nearly all respondents recommending another Workshop in three or fewer years. There was general recognition that thin film thermal conductivity measurements are important for predicting the resistance of optical coating
Evaluation of New Thermally Conductive Geopolymer in Thermal Energy Storage
Černý, Matěj; Uhlík, Jan; Nosek, Jaroslav; Lachman, Vladimír; Hladký, Radim; Franěk, Jan; Brož, Milan
This paper describes an evaluation of a newly developed thermally conductive geopolymer (TCG), consisting of a mixture of sodium silicate and carbon micro-particles. The TCG is intended to be used as a component of high temperature energy storage (HTTES) to improve its thermal diffusivity. Energy storage is crucial for both ecological and economical sustainability. HTTES plays a vital role in solar energy technologies and in waste heat recovery. The most advanced HTTES technologies are based on phase change materials or molten salts, but suffer with economic and technological limitations. Rock or concrete HTTES are cheaper, but they have low thermal conductivity without incorporation of TCG. It was observed that TCG is stable up to 400 °C. The thermal conductivity was measured in range of 20-23 W m-1 K-1. The effect of TCG was tested by heating a granite block with an artificial fissure. One half of the fissure was filled with TCG and the other with ballotini. 28 thermometers, 5 dilatometers and strain sensors were installed on the block. The heat transport experiment was evaluated with COMSOL Multiphysics software.
Thermal Expansion and Thermal Conductivity of Rare Earth Silicates
Zhu, Dongming; Lee, Kang N.; Bansal, Narottam P.
2006-01-01
Rare earth silicates are considered promising candidate materials for environmental barrier coatings applications at elevated temperature for ceramic matrix composites. High temperature thermophysical properties are of great importance for coating system design and development. In this study, the thermal expansion and thermal conductivity of hot-pressed rare earth silicate materials were characterized at temperatures up to 1400 C. The effects of specimen porosity, composition and microstructure on the properties were also investigated. The materials processing and testing issues affecting the measurements will also be discussed.
Measurements of Thermal Conductivity and Thermal Diffusivity of Molten Carbonates
Wicaksono, Hendro; Zhang, Xing; Fujiwara, Seiji; Fujii, Motoo
2001-01-01
The thermal conductivity and thermal diffusivity of molten carbonates (Li_2CO_3/K_2CO_3 and Li_2CO_3/Na_2CO_3) were measured using the transient short-hot-wire method in the temperature range from 530 to 670℃. Two types of probes were examined. One was a platinum short-hot-wire probe coated with alumina (Al_2O_3) thin film to prevent current leakage and corrosion. The other was a bare gold short-hot-wire probe. For the platinum probe, the quality of coating reduces gradually during the measur...
Review of interfacial layer's effect on thermal conductivity in nanofluid
Kotia, Ankit; Borkakoti, Sheeba; Deval, Piyush; Ghosh, Subrata Kumar
2017-01-01
An ordered liquid layer around the particle-liquid interface is called as interfacial layer. It has been observed that interfacial layer is an essential parameter for determining the effective thermal conductivity of nanofluids. The review attempts to summarize the prominent articles related to interfacial layer effect on the thermal conductivity of nanofluids. First section of the paper discusses about various experimental approaches used to describe the effect of interfacial layer. Second section deals with about the mathematical models and assumed values regarding the thickness of interfacial layer by several authors. A review of previous works featuring mathematical investigations and experimental approaches seem to be suggesting that, interfacial layer have dominating effect on the effective thermal conductivity of the nanofluids. Third section of the paper deals with various mathematical models available in open literature for interfacial layer thermal conductivity. In the last section, models for effective thermal conductivity of the nanofluids considering the interfacial layer and percentage deviations in the predictions of mathematical models have been discussed.
Institute of Scientific and Technical Information of China (English)
Wenjing Du; Peili Wang; Lipeng Song; Lin Cheng
2015-01-01
A conduction heat transfer process is enhanced by filling prescribed quantity and optimized-shaped high thermal conductivity materials to the substrate. Numerical simulations and analyses are performed on a volume to point conduction problem based on the principle of minimum entropy generation. In the optimization, the arrange-ment of high thermal conductivity materials is variable, the quantity of high thermal-conductivity material is constrained, and the objective is to obtain the maximum heat conduction rate as the entropy is the minimum. A novel algorithm of thermal conductivity discretization is proposed based on large quantity of calculations. Compared with other algorithms in literature, the average temperature in the substrate by the new algorithm is lower, while the highest temperature in the substrate is in a reasonable range. Thus the new algorithm is fea-sible. The optimization of volume to point heat conduction is carried out in a rectangular model with radiation boundary condition and constant surface temperature boundary condition. The results demonstrate that the al-gorithm of thermal conductivity discretization is applicable for volume to point heat conduction problems.
Henon, J.; Alzina, A.; Absi, J.; Smith, D. S.; Rossignol, S.
2015-07-01
The geopolymers are alumino-silicate binders. The addition of a high pores volume fraction, gives them a thermal insulation character desired in the building industry. In this work, potassium geopolymer foams were prepared at room temperature (< 70 ∘C) by a process of in situ gas release. The porosity distribution shows a multiscale character. However, the thermal conductivity measurements gave values from 0.35 to 0.12 Wm-1.K-1 for a pore volume fraction values between 65 and 85%. In the aim to predict the thermal properties of these foams and focus on the relationship "thermal-conductivity/microstructure", knowledge of the thermal conductivity of their solid skeleton (λ s ) is paramount. However, there is rare work on the determination of this value depending on the initial composition. By the formulation used, the foaming agent contributes to the final network, and it is not possible to obtain a dense material designate to make a direct measurement of λ s . The objective of this work is to use inverse analytical methods to identify the value of λ s . Measurements of thermal conductivity by the fluxmetre technique were performed. The obtained value of the solid skeleton thermal conductivity by the inverse numerical technique is situated in a framework between 0.95 and 1.35 Wm-1.K-1 and is in agreement with one issue from the literature.
Thermal computations for electronics conductive, radiative, and convective air cooling
Ellison, Gordon
2010-01-01
IntroductionPrimary mechanisms of heat flowConductionApplication example: Silicon chip resistance calculationConvectionApplication example: Chassis panel cooled by natural convectionRadiationApplication example: Chassis panel cooled only by radiation 7Illustrative example: Simple thermal network model for a heat sinked power transistorIllustrative example: Thermal network circuit for a printed circuit boardCompact component modelsIllustrative example: Pressure and thermal circuits for a forced air cooled enclosureIllustrative example: A single chip package on a printed circuit board-the proble
Treating Fibrous Insulation to Reduce Thermal Conductivity
Zinn, Alfred; Tarkanian, Ryan
2009-01-01
A chemical treatment reduces the convective and radiative contributions to the effective thermal conductivity of porous fibrous thermal-insulation tile. The net effect of the treatment is to coat the surfaces of fibers with a mixture of transition-metal oxides (TMOs) without filling the pores. The TMO coats reduce the cross-sectional areas available for convection while absorbing and scattering thermal radiation in the pores, thereby rendering the tile largely opaque to thermal radiation. The treatment involves a sol-gel process: A solution containing a mixture of transition-metal-oxide-precursor salts plus a gelling agent (e.g., tetraethylorthosilicate) is partially cured, then, before it visibly gels, is used to impregnate the tile. The solution in the tile is gelled, then dried, and then the tile is fired to convert the precursor salts to the desired mixed TMO phases. The amounts of the various TMOs ultimately incorporated into the tile can be tailored via the concentrations of salts in the solution, and the impregnation depth can be tailored via the viscosity of the solution and/or the volume of the solution relative to that of the tile. The amounts of the TMOs determine the absorption and scattering spectra.
Quasi-ballistic Electronic Thermal Conduction in Metal Inverse Opals.
Barako, Michael T; Sood, Aditya; Zhang, Chi; Wang, Junjie; Kodama, Takashi; Asheghi, Mehdi; Zheng, Xiaolin; Braun, Paul V; Goodson, Kenneth E
2016-04-13
Porous metals are used in interfacial transport applications that leverage the combination of electrical and/or thermal conductivity and the large available surface area. As nanomaterials push toward smaller pore sizes to increase the total surface area and reduce diffusion length scales, electron conduction within the metal scaffold becomes suppressed due to increased surface scattering. Here we observe the transition from diffusive to quasi-ballistic thermal conduction using metal inverse opals (IOs), which are metal films that contain a periodic arrangement of interconnected spherical pores. As the material dimensions are reduced from ∼230 nm to ∼23 nm, the thermal conductivity of copper IOs is reduced by more than 57% due to the increase in surface scattering. In contrast, nickel IOs exhibit diffusive-like conduction and have a constant thermal conductivity over this size regime. The quasi-ballistic nature of electron transport at these length scales is modeled considering the inverse opal geometry, surface scattering, and grain boundaries. Understanding the characteristics of electron conduction at the nanoscale is essential to minimizing the total resistance of porous metals for interfacial transport applications, such as the total electrical resistance of battery electrodes and the total thermal resistance of microscale heat exchangers.
DEFF Research Database (Denmark)
Bording, Thue Sylvester; Nielsen, Søren Bom; Balling, Niels
2016-01-01
Accurate information on thermal conductivity and thermal diffusivity of materials is of central importance in relation to geoscience and engineering problems involving the transfer of heat. Within the geosciences, this applies to all aspects regarding the determination of terrestrial heat flow...... and volumetric heat capacity, and thereby also thermal diffusivity, are measured simultaneously. As the density of samples is easily determined independently, specific heat capacity may also be determined. Finite element formulation provides a flexible forward solution for heat transfer across the bar...... and subsurface temperature modelling. Several methods, including the classical divided-bar technique, are available for laboratory measurements of thermal conductivity, and much fewer for thermal diffusivity. We have generalized the divided-bar technique to the transient case, in which thermal conductivity...
DEFF Research Database (Denmark)
Bording, Thue Sylvester; Nielsen, Søren Bom; Balling, Niels
2016-01-01
Accurate information on thermal conductivity and thermal diffusivity of materials is of central importance in relation to geoscience and engineering problems involving the transfer of heat. Within the geosciences, this applies to all aspects regarding the determination of terrestrial heat flow...... and subsurface temperature modelling. Several methods, including the classical divided-bar technique, are available for laboratory measurements of thermal conductivity, and much fewer for thermal diffusivity. We have generalized the divided-bar technique to the transient case, in which thermal conductivity...... and volumetric heat capacity, and thereby also thermal diffusivity, are measured simultaneously. As the density of samples is easily determined independently, specific heat capacity may also be determined. Finite element formulation provides a flexible forward solution for heat transfer across the bar...
Thermal Conductivity and Heat Transfer Coefficient of Concrete
Institute of Scientific and Technical Information of China (English)
GUO Lixia; GUO Lei; ZHONG Ling; ZHU Yueming
2011-01-01
A very simple model for predicting thermal conductivity based on its definiensis was presented.The thermal conductivity obtained using the model provided a good coincidence to the investigations performed by other authors.The heat transfer coefficient was determined by inverse analysis using the temperature measurements.From experimental results,it is noted that heat transfer coefficient increases with the increase of wind velocity and relative humidity,a prediction equation on heat transfer coefficient about wind velocity and relative humidity is given.
Honda, S.; Yuen, D. A.
The sensitivity of pressure- and temperature-dependent thermal conductivity (k: W/m/K) and the thermal expansivity (α:1/K) on the thermal structure of the oceanic plate is investigated parametrically by comparing the ocean floor depth and heat flux calculated by one-dimensional conduction model with those of GDH1, a theoretical thermal model of the oceanic lithosphere. We find that an optimum fit is obtained, when the value of thermal expansivity is ˜ 3 × 10-5, while those associated with the thermal conductivity have many possibilities. The estimates, which give an equally good fit to the GDH1 model, of the plate thickness D (km) and the temperature at the base of the plate Tm (°C) may be given by Tm ˜ 1450-(k0-4.5) × 100-(α-3.0 × 10-5) × 105×100, D ˜ 90 + (k0-4.5) × 20 - (α-3.0 × 10-5) × 105 × 20 where k0 (W/m/K) is the lattice thermal conductivity at the ocean floor. A similar relation is obtained for constant thermal conductivity.
Inhomogeneous thermal conductivity enhances thermoelectric cooling
Directory of Open Access Journals (Sweden)
Tingyu Lu
2014-12-01
Full Text Available We theoretically investigate the enhancement of thermoelectric cooling performance in thermoelectric refrigerators made of materials with inhomogeneous thermal conductivity, beyond the usual practice of enhancing thermoelectric figure of merit (ZT of materials. The dissipation of the Joule heat in such thermoelectric refrigerators is asymmetric which can give rise to better thermoelectric cooling performance. Although the thermoelectric figure of merit and the coefficient-of-performance are slightly enhanced, both the maximum cooling power and the maximum cooling temperature difference can be enhanced significantly. This finding can be used to increase the heat absorption at the cold end. We further find that the asymmetric dissipation of Joule heat leads to thermal rectification.
Energy Technology Data Exchange (ETDEWEB)
Dinwiddie, R.B.; Beecher, S.C.; Porter, W.D. [Oak Ridge National Lab., TN (United States); Nagaraj, B.A. [General Electric Co., Cincinnati, OH (United States). Aircraft Engine Group
1996-05-01
Thermal barrier coatings (TBCs) applied to the hot gas components of turbine engines lead to enhanced fuel efficiency and component reliability. Understanding the mechanisms which control the thermal transport behavior of the TBCs is of primary importance. Electron beam-physical vapor deposition (EV-PVD) and air plasma spraying (APS) are the two most commonly used coating techniques. These techniques produce coatings with unique microstructures which control their performance and stability. The density of the APS coatings was controlled by varying the spray parameters. The low density APS yttria-partially stabilized zirconia (yttria-PSZ) coatings yielded a thermal conductivity that is lower than both the high density APS coatings and the EB-PVD coatings. The thermal aging of both fully and partially stabilized zirconia are compared. The thermal conductivity of the coatings permanently increases upon exposure to high temperatures. These increases are attributed to microstructural changes within the coatings. This increase in thermal conductivity can be modeled using a relationship which depends on both the temperature and time of exposure. Although the EB-PVD coatings are less susceptible to thermal aging effects, results suggest that they typically have a higher thermal conductivity than APS coatings before thermal aging. The increases in thermal conductivity due to thermal aging for plasma sprayed partially stabilized zirconia have been found to be less than for plasma sprayed fully stabilized zirconia coatings.
Energy Technology Data Exchange (ETDEWEB)
Midttoemme, Kirsti
1997-12-31
The thermal conductivity of sedimentary rocks is an important parameter in basin modelling as the main parameter controlling the temperature within a sedimentary basin. This thesis presents measured thermal conductivities, mainly on clay- and mudstone. The measured values are compared with values obtained by using thermal conductivity models. Some new thermal conductivity models are developed based on the measured values. The values obtained are less than most previously published values. In a study of unconsolidated sediments a constant deviation was found between thermal conductivities measured with a needle probe and a divided bas apparatus. Accepted thermal conductivity models based on the geometric mean model fail to predict the thermal conductivity of clay- and mudstone. Despite this, models based on the geometric mean model, where the effect of porosity is taken account of by the geometric mean equation, seem to be the best. Existing models underestimate the textural influence on the thermal conductivity of clay- and mudstone. The grain size was found to influence the thermal conductivity of artificial quartz samples. The clay mineral content seems to be a point of uncertainty in both measuring and modelling thermal conductivity. A good universal thermal conductivity model must include many mineralogical and textural factors. Since this is difficult, different models restricted to specific sediment types and textures are suggested to be the best solution to obtain realistic estimates applicable in basin modelling. 243 refs., 64 figs., 31 tabs.
Rybakov, I. M.; Goryachev, N. V.; Kochegarov, I. I.; Grishko, A. K.; Brostilov, S. A.; Yurkov, N. K.
2017-01-01
The paper proves the necessity of taking into account external conductive layers of the printed circuit board with the thermal physical designing radio-electronic means. For example, a single printed circuit board shows the level of influence of the external conductive layer on the thermal conditions of the printed circuit board. It proved the influence of Joule heat in the thermal conditions of a single conductor. Developed geometrical and thermal printed circuit board models take into account the topological layer and can improve the accuracy of determining the thermal conditions of the printed circuit board.
Anisotropic thermal conduction with magnetic fields in galaxy clusters
Arth, Alexander; Dolag, Klaus; Beck, Alexander; Petkova, Margarita; Lesch, Harald
2015-08-01
Magnetic fields play an important role for the propagation and diffusion of charged particles, which are responsible for thermal conduction. In this poster, we present an implementation of thermal conduction including the anisotropic effects of magnetic fields for smoothed particle hydrodynamics (SPH). The anisotropic thermal conduction is mainly proceeding parallel to magnetic fields and suppressed perpendicular to the fields. We derive the SPH formalism for the anisotropic heat transport and solve the corresponding equation with an implicit conjugate gradient scheme. We discuss several issues of unphysical heat transport in the cases of extreme ansiotropies or unmagnetized regions and present possible numerical workarounds. We implement our algorithm into the cosmological simulation code GADGET and study its behaviour in several test cases. In general, we reproduce the analytical solutions of our idealised test problems, and obtain good results in cosmological simulations of galaxy cluster formations. Within galaxy clusters, the anisotropic conduction produces a net heat transport similar to an isotropic Spitzer conduction model with low efficiency. In contrast to isotropic conduction our new formalism allows small-scale structure in the temperature distribution to remain stable, because of their decoupling caused by magnetic field lines. Compared to observations, strong isotropic conduction leads to an oversmoothed temperature distribution within clusters, while the results obtained with anisotropic thermal conduction reproduce the observed temperature fluctuations well. A proper treatment of heat transport is crucial especially in the outskirts of clusters and also in high density regions. It's connection to the local dynamical state of the cluster also might contribute to the observed bimodal distribution of cool core and non cool core clusters. Our new scheme significantly advances the modelling of thermal conduction in numerical simulations and overall gives
15th International Conference on Thermal Conductivity
1978-01-01
Once again, it gives me a great pleasure to pen the Foreword to the Proceedings of the 15th International Conference on Thermal Conductivity. As in the past, these now biannual conferences pro vide a broadly based forum for those researchers actively working on this important property of matter to convene on a regular basis to exchange their experiences and report their findings. As it is apparent from the Table of Contents, the 15th Conference represents perhaps the broadest coverage of subject areas to date. This is indicative of the times as the boundaries between disciplines be come increasingly diffused. I am sure the time has come when Con ference Chairmen in coming years will be soliciting contributions not only in the physical sciences and engineering', but will actively seek contributions from the earth sciences and life sciences as well. Indeed, the thermal conductivity and related properties of geological and biological materials are becoming of increasing im portance to our way of life. As...
Paloma, Cynthia S.
The plasma electron temperature (Te) plays a critical role in a tokamak nu- clear fusion reactor since temperatures on the order of 108K are required to achieve fusion conditions. Many plasma properties in a tokamak nuclear fusion reactor are modeled by partial differential equations (PDE's) because they depend not only on time but also on space. In particular, the dynamics of the electron temperature is governed by a PDE referred to as the Electron Heat Transport Equation (EHTE). In this work, a numerical method is developed to solve the EHTE based on a custom finite-difference technique. The solution of the EHTE is compared to temperature profiles obtained by using TRANSP, a sophisticated plasma transport code, for specific discharges from the DIII-D tokamak, located at the DIII-D National Fusion Facility in San Diego, CA. The thermal conductivity (also called thermal diffusivity) of the electrons (Xe) is a plasma parameter that plays a critical role in the EHTE since it indicates how the electron temperature diffusion varies across the minor effective radius of the tokamak. TRANSP approximates Xe through a curve-fitting technique to match experimentally measured electron temperature profiles. While complex physics-based model have been proposed for Xe, there is a lack of a simple mathematical model for the thermal diffusivity that could be used for control design. In this work, a model for Xe is proposed based on a scaling law involving key plasma variables such as the electron temperature (Te), the electron density (ne), and the safety factor (q). An optimization algorithm is developed based on the Sequential Quadratic Programming (SQP) technique to optimize the scaling factors appearing in the proposed model so that the predicted electron temperature and magnetic flux profiles match predefined target profiles in the best possible way. A simulation study summarizing the outcomes of the optimization procedure is presented to illustrate the potential of the
Surface functionalization on the thermal conductivity of graphene–polymer nanocomposites
Directory of Open Access Journals (Sweden)
Mingchao Wang
2014-04-01
Full Text Available Exploring thermal transport in graphene–polymer nanocomposite is significant to its applications with better thermal properties. Interfacial thermal conductance between graphene and polymer matrix plays a critical role in the improvement of thermal conductivity of graphene–polymer nanocomposite. Unfortunately, it is still challenging to understand the interfacial thermal transport between graphene nanofiller and polymer matrix at small material length scale. To this end, using nonequilibrium molecular dynamics (NEMD simulations, we investigate the interfacial thermal conductance of graphene–polyethylene (PE nanocomposite. The influence of functionalization with hydrocarbon chains on the interfacial thermal conductance of graphene–polymer nanocomposites was studied, taking into account the effects of model size and thermal conductivity of graphene. An analytical model is also used to calculate the thermal conductivity of nanocomposite. The results are considered to contribute to the development of new graphene–polymer nanocomposites with tailored thermal properties.
Firkowska, Izabela; Boden, André; Boerner, Benji; Reich, Stephanie
2015-07-08
We developed a nanocomposite with highly aligned graphite platelets in a copper matrix. Spark plasma sintering ensured an excellent copper-graphite interface for transmitting heat and stress. The resulting composite has superior thermal conductivity (500 W m(-1) K(-1), 140% of copper), which is in excellent agreement with modeling based on the effective medium approximation. The thermal expansion perpendicular to the graphite platelets drops dramatically from ∼20 ppm K(-1) for graphite and copper separately to 2 ppm K(-1) for the combined structure. We show that this originates from the layered, highly anisotropic structure of graphite combined with residual stress under ambient conditions, that is, strain-engineering of the thermal expansion. Combining excellent thermal conductivity with ultralow thermal expansion results in ideal materials for heat sinks and other devices for thermal management.
On thermal conductivity of gas mixtures containing hydrogen
Zhukov, Victor P.; Pätz, Markus
2016-12-01
A brief review of formulas used for the thermal conductivity of gas mixtures in CFD simulations of rocket combustion chambers is carried out in the present work. In most cases, the transport properties of mixtures are calculated from the properties of individual components using special mixing rules. The analysis of different mixing rules starts from basic equations and ends by very complex semi-empirical expressions. The formulas for the thermal conductivity are taken for the analysis from the works on modelling of rocket combustion chambers. H_2- O_2 mixtures are chosen for the evaluation of the accuracy of the considered mixing rules. The analysis shows that two of them, of Mathur et al. (Mol Phys 12(6):569-579, 1967), and of Mason and Saxena (Phys Fluids 1(5):361-369, 1958), have better agreement with the experimental data than other equations for the thermal conductivity of multicomponent gas mixtures.
Cosmological MHD simulations of cluster formation with anisotropic thermal conduction
Ruszkowski, M; Bruggen, M; Parrish, I; Oh, S Peng
2010-01-01
(abridged) The ICM has been suggested to be buoyantly unstable in the presence of magnetic field and anisotropic thermal conduction. We perform first cosmological simulations of galaxy cluster formation that simultaneously include magnetic fields, radiative cooling and anisotropic thermal conduction. In isolated and idealized cluster models, the magnetothermal instability (MTI) tends to reorient the magnetic fields radially. Using cosmological simulations of the Santa Barbara cluster we detect radial bias in the velocity and magnetic fields. Such radial bias is consistent with either the inhomogeneous radial gas flows due to substructures or residual MTI-driven field rearangements that are expected even in the presence of turbulence. Although disentangling the two scenarios is challenging, we do not detect excess bias in the runs that include anisotropic thermal conduction. The anisotropy effect is potentially detectable via radio polarization measurements with LOFAR and SKA and future X-ray spectroscopic stu...
Increased Thermal Conductivity in Metal-Organic Heat Carrier Nanofluids
Nandasiri, Manjula I.; Liu, Jian; McGrail, B. Peter; Jenks, Jeromy; Schaef, Herbert T.; Shutthanandan, Vaithiyalingam; Nie, Zimin; Martin, Paul F.; Nune, Satish K.
2016-06-01
Metal-organic heat carriers (MOHCs) are recently developed nanofluids containing metal-organic framework (MOF) nanoparticles dispersed in various base fluids including refrigerants (R245Fa) and methanol. Here, we report the synthesis and characterization of MOHCs containing nanoMIL-101(Cr) and graphene oxide (GO) in an effort to improve the thermo-physical properties of various base fluids. MOHC/GO nanocomposites showed enhanced surface area, porosity, and nitrogen adsorption compared with the intrinsic nanoMIL-101(Cr) and the properties depended on the amount of GO added. MIL-101(Cr)/GO in methanol exhibited a significant increase in the thermal conductivity (by approximately 50%) relative to that of the intrinsic nanoMIL-101(Cr) in methanol. The thermal conductivity of the base fluid (methanol) was increased by about 20%. The increase in the thermal conductivity of nanoMIL-101(Cr) MOHCs due to GO functionalization is explained using a classical Maxwell model.
Increased Thermal Conductivity in Metal-Organic Heat Carrier Nanofluids.
Nandasiri, Manjula I; Liu, Jian; McGrail, B Peter; Jenks, Jeromy; Schaef, Herbert T; Shutthanandan, Vaithiyalingam; Nie, Zimin; Martin, Paul F; Nune, Satish K
2016-06-15
Metal-organic heat carriers (MOHCs) are recently developed nanofluids containing metal-organic framework (MOF) nanoparticles dispersed in various base fluids including refrigerants (R245Fa) and methanol. Here, we report the synthesis and characterization of MOHCs containing nanoMIL-101(Cr) and graphene oxide (GO) in an effort to improve the thermo-physical properties of various base fluids. MOHC/GO nanocomposites showed enhanced surface area, porosity, and nitrogen adsorption compared with the intrinsic nanoMIL-101(Cr) and the properties depended on the amount of GO added. MIL-101(Cr)/GO in methanol exhibited a significant increase in the thermal conductivity (by approximately 50%) relative to that of the intrinsic nanoMIL-101(Cr) in methanol. The thermal conductivity of the base fluid (methanol) was increased by about 20%. The increase in the thermal conductivity of nanoMIL-101(Cr) MOHCs due to GO functionalization is explained using a classical Maxwell model.
On thermal conductivity of gas mixtures containing hydrogen
Zhukov, Victor P.; Pätz, Markus
2017-06-01
A brief review of formulas used for the thermal conductivity of gas mixtures in CFD simulations of rocket combustion chambers is carried out in the present work. In most cases, the transport properties of mixtures are calculated from the properties of individual components using special mixing rules. The analysis of different mixing rules starts from basic equations and ends by very complex semi-empirical expressions. The formulas for the thermal conductivity are taken for the analysis from the works on modelling of rocket combustion chambers. \\hbox {H}_2{-}\\hbox {O}_2 mixtures are chosen for the evaluation of the accuracy of the considered mixing rules. The analysis shows that two of them, of Mathur et al. (Mol Phys 12(6):569-579, 1967), and of Mason and Saxena (Phys Fluids 1(5):361-369, 1958), have better agreement with the experimental data than other equations for the thermal conductivity of multicomponent gas mixtures.
Anisotropic thermal conduction in galaxy clusters with MHD in Gadget
Arth, Alexander; Beck, Alexander M; Petkova, Margarita; Lesch, Harald
2014-01-01
We present an implementation of thermal conduction including the anisotropic effects of magnetic fields for SPH. The anisotropic thermal conduction is mainly proceeding parallel to magnetic fields and suppressed perpendicular to the fields. We derive the SPH formalism for the anisotropic heat transport and solve the corresponding equation with an implicit conjugate gradient scheme. We discuss several issues of unphysical heat transport in the cases of extreme ansiotropies or unmagnetized regions and present possible numerical workarounds. We implement our algorithm into the GADGET code and study its behaviour in several test cases. In general, we reproduce the analytical solutions of our idealised test problems, and obtain good results in cosmological simulations of galaxy cluster formations. Within galaxy clusters, the anisotropic conduction produces a net heat transport similar to an isotropic Spitzer conduction model with an efficiency of one per cent. In contrast to isotropic conduction our new formalism ...
Thermal Conductivity of Nanotubes: Effects of Chirality and Isotope Impurity
Gang, Zhang; Li, Baowen
2005-01-01
We study the dependence of thermal conductivity of single walled nanotubes (SWNT) on chirality and isotope impurity by nonequilibrium molecular dynamics method with accurate potentials. It is found that, contrary to electronic conductivity, the thermal conductivity is insensitive to the chirality. The isotope impurity, however, can reduce the thermal conductivity up to 60% and change the temperature dependence behavior. We also study the dependence of thermal conductivity on tube length for t...
Xie, Huaqing; Gu, Hua; Fujii, Motoo; Zhang, Xing
2006-01-01
A transient short hot wire technique (SHWT) is developed for simultaneous determination of the thermal conductivity and thermal diffusivity of various materials such as liquids, gases or powders. A metal wire with (or without) insulation coating serves both as a heating unit and as an electrical resistance thermometer and the wire is calibrated using water and toluene with known thermophysical properties. This SHWT includes correlation of the experimental data with numerically simulated values based on a two-dimensional heat-conduction model. For the measurements with proportional relation between temperature rise and logarithmic heating time interval, the thermal conductivity and thermal diffusivity are obtained from the slope and the intercept of the measured temperature rise and those of calculated non-dimensional temperature rise by including the heat flux and the properties of the wire. For the measurements with nonlinear relation between temperature rise and logarithmic heating time interval, the thermal conductivity and thermal diffusivity are extracted from a curve fitting method by using the downhill simplex method to match the experimental data and the numerical values. This technique is applied here using air as a testing sample. The effect of natural convection is investigated and the accuracy of this measurement is estimated to be 2% for thermal conductivity and 7% for thermal diffusivity.
Effect of Sintering on Thermal Conductivity and Thermal Barrier Effects of Thermal Barrier Coatings
Institute of Scientific and Technical Information of China (English)
WANG Kai; PENG Hui; GUO Hongbo; GONG Shengkai
2012-01-01
Thermal barrier coatings (TBCs) are mostly applied to hot components of advanced turbine engines to insulate the components from hot gas.The effect of sintering on thermal conductivity and thermal barrier effects of conventional plasma sprayed and nanostructured yttria stabilized zirconia (YSZ) thermal barrier coatings (TBCs) are investigated.Remarkable increase in thermal conductivity occurs to both typical coatings after heat treatment.The change of porosity is just the opposite.The grain size of the nanostructured zirconia coating increases more drastically with annealing time compared to that of the conventional plasma sprayed coating,which indicates that coating sintering makes more contributions to the thermal conductivity of the nanostructured coating than that of the conventional coating.Thermal barrier effect tests using temperature difference technique are performed on both coatings.The thermal barrier effects decrease with the increase of thermal conductivity after heat treatment and the decline seems more drastic in low thermal conductivity range.The decline in thermal barrier effects is about 80 ℃for nanostructured coating after 100 h heat treatment,while the conventional coating reduces by less than 60 ℃ compared to the as-sprayed coating.
Theoretical and experimental study of the thermal conductivity of nanoporous media
Institute of Scientific and Technical Information of China (English)
JIANG PeiXue; XIANG Heng; XU RuiNa
2012-01-01
The nanoparticle thermal conductivity and nanoscale thermal contact resistance were investigated by molecular dynamics (MD) simulations to further understand nanoscale porous media thermal conductivity.Macroscale porous media thermal conductivity models were then revised for nanoporous media.The effective thermal conductivities of two packed beds with nanoscale nickel particles and a packed bed with microscale nickel particles were then measured using the Hot Disk.The measured results show that the nano/microscale porous media thermal conductivities were much less than the thermal conductivities of the solid particles.Comparison of the measured and calculated results shows that the revised combined parallel-series model and the revised Hsu-Cheng model can accurately predict the effective thermal conductivities of micro-and nanoparticle packed beds.
Lattice thermal conductivity of LaSe
Energy Technology Data Exchange (ETDEWEB)
Li, Wei, E-mail: tolwwt@163.com [School of Physics and Telecommunication Engineering, South China Normal University, 510006 Guangzhou (China); Pan, Zhong-liang; Chen, Jun-fang; He, Qin-yu [School of Physics and Telecommunication Engineering, South China Normal University, 510006 Guangzhou (China); Wang, Teng [School of Computer, South China Normal University, 510631 Guangzhou (China)
2015-07-15
The phonon dispersions and phonon density of states of LaSe are obtained, based on density functional perturbation theory and the norm-conserving pseudo-potential method. An anomaly in calculated phonon dispersion curves is presented and interpreted as a Kohn anomaly. The heat capacity of LaSe is calculated then. For the three-phonon process scattering, the lowest non-harmonic cubic terms of the interatomic potential are considered to obtain single-phonon relaxation rate by applying the Fermi's golden rule. For the boundary scattering, the average phonon relaxation time was obtained. Considering two kinds of phonon scattering mechanisms, we obtain the lattice thermal conductivity of LaSe.
Comparative study of thermal conductivity in crystalline and amorphous nanocomposite
Juangsa, Firman Bagja; Muroya, Yoshiki; Ryu, Meguya; Morikawa, Junko; Nozaki, Tomohiro
2017-06-01
Silicon nanocrystals (SiNCs)/polystyrene (PS) nanocomposite has been observed to have a significant decrease in thermal conductivity in terms of the SiNC fraction with unspecified factors remained unclear. In this paper, amorphous silicon nanoparticles (a-SiNPs) with a mean diameter of 6 nm and PS nanocomposites were synthesized, and their thermal conductivity, including the density and specific heat, was compared with our previous work which investigated well-crystalized SiNPs (6 nm) and PS nanocomposite. The difference between amorphous and crystalline structure is insignificant, but phonon scattering at SiNPs and PS boundary is the key influencing factor of thermal conductivity reduction. The effective thermal conductivity models for nanocomposite revealed that the thermal boundary resistance, explained by Kapitza principle, is estimated to be 4 × 10-7 m2K/W, showing the significant effect of nanostructured heterogenic surface resistance on overall heat transfer behavior. Preservation of unique properties nanoscale materials and low-cost fabrication by silicon inks process at room temperature give the promising potential of SiNPs based heat transfer management.
On non-extensive nature of thermal conductivity
Indian Academy of Sciences (India)
Ashok Razdan
2007-01-01
In this paper we study non-extensive nature of thermal conductivity. It is observed that there is similarity between non-extensive entropic index and fractal dimension obtained for the silica aerogel thermal conductivity data at low temperature.
High-Thermal Conductive Coating Used on Metal Heat Exchanger
Institute of Scientific and Technical Information of China (English)
李静; 梁剧; 刘业明
2014-01-01
Based on modified silicon polyester resin in addition to several functional fillers such as corro-sion-resistant fillers, heat-resistant fillers and thermal conductive fillers, a high thermal conductive coating can be made. On the basis of boronnitride (BN) and aluminum nitride (AIN) used as thermal conductive fillers and by means of the testing system of hot disk and heat transfer experiment, researches on the varieties of thermal conduc-tive fillers and the effects of the contents of high-thermal conductive coating have been done, which shows that the thermal conductivity of coating increases with the increase of the quality fraction and the coefficient of thermal conductivity of the thermal conductive fillers of coating. With guaranteeing better heat resistance, stronger corro-sion resistance and adhesive force, the coefficient of coating can reach a level as high as 3 W·m-1·K-1.
Prediction of the effective thermal conductivity of microsphere insulation
Energy Technology Data Exchange (ETDEWEB)
Jin, Ling Xue; Park, Ji Ho; Lee, Cheon Kyu; Seo, Man Su; Jeong, Sang Kwon [Cryogenic Engineering Laboratory, Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of)
2014-03-15
Since glass microsphere has high crush strength, low density and small particle size, it becomes alternative thermal insulation material for cryogenic systems, such as storage and transportation tank for cryogenic fluids. Although many experiments have been performed to verify the effective thermal conductivity of microsphere, prediction by calculation is still inaccurate due to the complicated geometries, including wide range of powder diameter distribution and different pore sizes. The accurate effective thermal conductivity model for microsphere is discussed in this paper. There are four mechanisms which contribute to the heat transfer of the evacuated powder: gaseous conduction (k{sub g}), solid conduction (k{sub s}), radiation (k{sub r}) and thermal contact (k{sub c}). Among these components, k{sub g} and k{sub s} were calculated by Zehner and Schlunder model (1970). Other component values for k{sub c} and k{sub r}, which were obtained from experimental data under high vacuum conditions were added. In this research paper, the geometry of microsphere was simplified as a homogeneous solid sphere. The calculation results were compared with previous experimental data by R. Wawryk (1988), H. S. Kim (2010) and the experiment of this paper to show good agreement within error of 46%, 4.6% and 17 % for each result.
Measurement of in-plane thermal conductivity in polymer films
National Research Council Canada - National Science Library
Wei, Qingshuo; Uehara, Chinatsu; Mukaida, Masakazu; Kirihara, Kazuhiro; Ishida, Takao
2016-01-01
.... We evaluated thermal conductivities and anisotropic ratios for various types of samples including insulating polymers, undoped semiconducting polymers, doped conducting polymers, and one-dimensional...
Thermal conductance in a two-slit quantum waveguide
Institute of Scientific and Technical Information of China (English)
Nie Liu-Ying; Li Chun-Xian; Zhou Xiao-Ping; Wang Cheng-Zhi; Cheng Fang
2012-01-01
Using the scattering-matrix method,we investigate the thermal conductance in a two-slit quantum waveguide at low temperature.The results show that the total thermal conductance decreases monotonically with temperature increasing. Moreover,we find that the behaviours of the thermal conductance versus temperature are different for different types of slits.
DEFF Research Database (Denmark)
Christensen, René
2011-01-01
cylindrical tube the characteristic length is the radius. A triangular cross-section does not have a characteristic length, but as will be shown in this paper the model can in fact be used as long as 1) the cross-sectional pressure is constant and 2) a characteristic impedance and propagation wavenumber can...
Pure-oxygen radiative shocks with electron thermal conduction
Borkowski, Kazimierz J.; Shull, J. Michael
1990-01-01
Steady state radiative shock models in gas composed entirely of oxygen are calculated with the purpose of explaining observations of fast-moving knots in Cas A and other oxygen-rich SNRs. Models with electron thermal conduction differ significantly from models in which conduction is neglected. Conduction reduces postshock electron temperatures by a factor of 7-10 and flattens temperature gradients. The O III ion, whose forbidden emission usually dominates the observed spectra, is present over a wide range of shock velocities, from 100 to 170 km/s. The electron temperature in the O III forbidden line formation region is 30,000 K, in agreement with the 20,000 K derived from observations. All models with conduction have extensive warm (T above 4000 K) photoionization zones, which provides better agreement with observed optical O I line strengths.
Boosting Magnetic Reconnection by Viscosity and Thermal Conduction
Minoshima, Takashi; Imada, Shinsuke
2016-01-01
Nonlinear evolution of magnetic reconnection is investigated by means of magnetohydrodynamic simulations including uniform resistivity, uniform viscosity, and anisotropic thermal conduction. When viscosity exceeds resistivity (the magnetic Prandtl number Prm > 1), the viscous dissipation dominates outflow dynamics and leads to the decrease in the plasma density inside a current sheet. The low-density current sheet supports the excitation of the vortex. The thickness of the vortex is broader than that of the current for Prm > 1. The broader vortex flow more efficiently carries the upstream magnetic flux toward the reconnection region, and consequently boosts the reconnection. The reconnection rate increases with viscosity provided that thermal conduction is fast enough to take away the thermal energy increased by the viscous dissipation (the fluid Prandtl number Pr < 1). The result suggests the need to control the Prandtl numbers for the reconnection against the conventional resistive model.
Ming, Yi; Li, Hui-Min; Ding, Ze-Jun
2016-03-01
Thermal rectification and negative differential thermal conductance were realized in harmonic chains in this work. We used the generalized Caldeira-Leggett model to study the heat flow. In contrast to most previous studies considering only the linear system-bath coupling, we considered the nonlinear system-bath coupling based on recent experiment [Eichler et al., Nat. Nanotech. 6, 339 (2011)]. When the linear coupling constant is weak, the multiphonon processes induced by the nonlinear coupling allow more phonons transport across the system-bath interface and hence the heat current is enhanced. Consequently, thermal rectification and negative differential thermal conductance are achieved when the nonlinear couplings are asymmetric. However, when the linear coupling constant is strong, the umklapp processes dominate the multiphonon processes. Nonlinear coupling suppresses the heat current. Thermal rectification is also achieved. But the direction of rectification is reversed compared to the results of weak linear coupling constant.
Ming, Yi; Li, Hui-Min; Ding, Ze-Jun
2016-03-01
Thermal rectification and negative differential thermal conductance were realized in harmonic chains in this work. We used the generalized Caldeira-Leggett model to study the heat flow. In contrast to most previous studies considering only the linear system-bath coupling, we considered the nonlinear system-bath coupling based on recent experiment [Eichler et al., Nat. Nanotech. 6, 339 (2011), 10.1038/nnano.2011.71]. When the linear coupling constant is weak, the multiphonon processes induced by the nonlinear coupling allow more phonons transport across the system-bath interface and hence the heat current is enhanced. Consequently, thermal rectification and negative differential thermal conductance are achieved when the nonlinear couplings are asymmetric. However, when the linear coupling constant is strong, the umklapp processes dominate the multiphonon processes. Nonlinear coupling suppresses the heat current. Thermal rectification is also achieved. But the direction of rectification is reversed compared to the results of weak linear coupling constant.
Directory of Open Access Journals (Sweden)
Cieśliński Janusz T.
2015-12-01
Full Text Available In this study the results of simultaneous measurements of dynamic viscosity, thermal conductivity, electrical conductivity and pH of two nanofluids, i.e., thermal oil/Al2O3 and thermal oil/TiO2 are presented. Thermal oil is selected as a base liquid because of possible application in ORC systems as an intermediate heating agent. Nanoparticles were tested at the concentration of 0.1%, 1%, and 5% by weight within temperature range from 20 °C to 60 °C. Measurement devices were carefully calibrated by comparison obtained results for pure base liquid (thermal oil with manufacturer’s data. The results obtained for tested nanofluids were compared with predictions made by use of existing models for liquid/solid particles mixtures.
Cieśliński, Janusz T.; Ronewicz, Katarzyna; Smoleń, Sławomir
2015-12-01
In this study the results of simultaneous measurements of dynamic viscosity, thermal conductivity, electrical conductivity and pH of two nanofluids, i.e., thermal oil/Al2O3 and thermal oil/TiO2 are presented. Thermal oil is selected as a base liquid because of possible application in ORC systems as an intermediate heating agent. Nanoparticles were tested at the concentration of 0.1%, 1%, and 5% by weight within temperature range from 20 °C to 60 °C. Measurement devices were carefully calibrated by comparison obtained results for pure base liquid (thermal oil) with manufacturer's data. The results obtained for tested nanofluids were compared with predictions made by use of existing models for liquid/solid particles mixtures.
Simulations of thermal conductance across tilt grain boundaries in graphene
Institute of Scientific and Technical Information of China (English)
Peng Wang; Bo Gong; Qiong Feng; Hong-Tao Wang
2012-01-01
Non-equilibrium molecular dynamics (MD) method was performed to simulate the thermal transportation process in graphene nanoribbons (GNRs).A convenient way was conceived to introduce tilt grain boundaries (GBs) into the graphene lattice by repetitive removing C atom rows along certain directions.Comprehensive MD simulations reveal that larger-angle GBs are effective thermal barriers and substantially reduce the average thermal conductivity of GNRs.The GB thermal conductivity is ～ 10 W.m-1·K-1 for a bicrystal GNR with a misorientation of 21.8°,which is ～97％ less than that of a prefect GNR with the same size.The total thermal resistance has a monotonic dependence on the density of the 5-7 defects along the GBs.A theoretical model is proposed to capture this relation and resolve the contributions by both the reduction in the phonon mean free path and the defect-induced thermal resistance.
Strain-controlled thermal conductivity in ferroic twinned films
Li, Suzhi; Ding, Xiangdong; Ren, Jie; Moya, Xavier; Li, Ju; Sun, Jun; Salje, Ekhard K. H.
2014-09-01
Large reversible changes of thermal conductivity are induced by mechanical stress, and the corresponding device is a key element for phononics applications. We show that the thermal conductivity κ of ferroic twinned thin films can be reversibly controlled by strain. Nonequilibrium molecular dynamics simulations reveal that thermal conductivity decreases linearly with the number of twin boundaries perpendicular to the direction of heat flow. Our demonstration of large and reversible changes in thermal conductivity driven by strain may inspire the design of controllable thermal switches for thermal logic gates and all-solid-state cooling devices.
Thermal conductivity and contact resistance of metal foams
Sadeghi, E.; Hsieh, S.; Bahrami, M.
2011-03-01
Accurate information on heat transfer and temperature distribution in metal foams is necessary for design and modelling of thermal-hydraulic systems incorporating metal foams. The analysis of heat transfer requires determination of the effective thermal conductivity as well as the thermal contact resistance (TCR) associated with the interface between the metal foam and the adjacent surfaces/layers. In this study, a test bed that allows the separation of effective thermal conductivity and TCR in metal foams is described. Measurements are performed in a vacuum under varying compressive loads using ERG Duocel aluminium foam samples with different porosities and pore densities. Also, a graphical method associated with a computer code is developed to demonstrate the distribution of contact spots and estimate the real contact area at the interface. Our results show that the porosity and the effective thermal conductivity remain unchanged with the variation of compression in the range 0-2 MPa; but TCR decreases significantly with pressure due to an increase in the real contact area at the interface. Moreover, the ratio of real to nominal contact area varies between 0 and 0.013, depending upon the compressive force, porosity, pore density and surface characteristics.
Energy Technology Data Exchange (ETDEWEB)
Kang, Hyung-sun; Koh, Young Ha; Jin, Jae Sik [Chosun College of Science and Technology, Gwangju (Korea, Republic of)
2017-06-15
The aim of this study is to understand the phonon transfer characteristics of a silicon thin film transistor. For this purpose, the Joule heating mechanism was considered through the electron-phonon interaction model whose validation has been done. The phonon transport characteristics were investigated in terms of phonon mean free path for the variations in the device power and silicon layer thickness from 41 nm to 177 nm. The results may be used for developing the thermal design strategy for achieving reliability and efficiency of the silicon-on-insulator (SOI) transistor, further, they will increase the understanding of heat conduction in SOI systems, which are very important in the semiconductor industry and the nano-fabrication technology.
Feng, Changping; Ni, Haiying; Chen, Jun; Yang, Wei
2016-08-03
Thermally conductive polymer composites have aroused significant academic and industrial interest for several decades. Herein, we report a novel fabrication method of graphite/polypropylene (PP) composites with high thermal conductivity in which graphite flakes construct a continuous thermally conductive network. The thermal conductivity coefficient of the graphite/PP composites is markedly improved to be 5.4 W/mK at a graphite loading of 21.2 vol %. Such a great improvement of the thermal conductivity is ascribed to the occurrence of orientations of crystalline graphite flakes with large particles around PP resin particles and the formation of a perfect thermally conductive network. The model of Hashin-Shtrikman (HS) is adopted to interpret the outstanding thermally conductive property of the graphite/PP composites. This work provides a guideline for the easy fabrication of thermally conductive composites with network structures.
Thermal Crosslinking of Organic Semiconducting Polythiophene Improves Transverse Hole Conductivity
Energy Technology Data Exchange (ETDEWEB)
Gearba, I.R.; Nam, C.-Y.; Pindak, R.; Black, C.T.
2009-10-26
Thermal crosslinking using a suitable radical initiator simultaneously improves electrical conductivity in the semiconducting polymer poly(3-hexylthiophene) and makes the material insoluble. Crosslinked polythiophene shows as much as a fivefold increase in hole conductivity across the film thickness without any shift in spectral light absorption. Grazing incidence x-ray diffraction reveals more in-plane polymer lamellae stacking with only a small decrease in film crystallinity. Improved transverse conductivity increases the performance of model planar solar cells by threefold, from 0.07% to 0.2%. The ability to render polythiophene insoluble without disrupting film structural order enables fabrication pathways to more complex device architectures.
Thermal crosslinking of organic semiconducting polythiophene improves transverse hole conductivity
Gearba, Ioana R.; Nam, Chang-Yong; Pindak, Ron; Black, C. T.
2009-10-01
Thermal crosslinking using a suitable radical initiator simultaneously improves electrical conductivity in the semiconducting polymer poly(3-hexylthiophene) and makes the material insoluble. Crosslinked polythiophene shows as much as a fivefold increase in hole conductivity across the film thickness without any shift in spectral light absorption. Grazing incidence x-ray diffraction reveals more in-plane polymer lamellae stacking with only a small decrease in film crystallinity. Improved transverse conductivity increases the performance of model planar solar cells by threefold, from 0.07% to 0.2%. The ability to render polythiophene insoluble without disrupting film structural order enables fabrication pathways to more complex device architectures.
Thermal conductivity of Cu–4.5 Ti alloy
Indian Academy of Sciences (India)
S Nagarjuna
2004-02-01
The thermal conductivity (TC) of peak aged Cu–4.5 wt% Ti alloy was measured at different temperatures and studied its variation with temperature. It was found that TC increased with increasing temperature. Phonon and electronic components of thermal conductivity were computed from the results. The alloy exhibits an electronic thermal conductivity of 46.45 W/m.K at room temperature. The phonon thermal conductivity decreased with increasing temperature from 17.6 at 0 K to 1.75 W/m.K at 298 K, which agrees with literature that the phonon component of thermal conductivity is insignificant at room temperature.
Four-terminal thermal conductance of mesoscopic dielectric systems.
Sun, Qing-Feng; Yang, Ping; Guo, Hong
2002-10-21
A four-terminal thermal conductance formula for a mesoscopic dielectric system with arbitrary central scattering region is derived. Similar to four-terminal electric conductance, the four-terminal thermal conductance also has a set of Onsager relations. In the temperature T-->0 limit, in contrast to the two-terminal thermal conductance which is a monotonic function of T and tends to zero, the four-terminal thermal conductance is nonmonotonic and tends to infinity. We also find that temperatures of the two terminals without thermal flux become very close to each other at low temperatures. Rather different behaviors are found for systems satisfying fractional exclusion statistics.
Decreasing the Effective Thermal Conductivity in Glass Supported Thermoelectric Layers.
Bethke, Kevin; Andrei, Virgil; Rademann, Klaus
2016-01-01
As thermoelectric devices begin to make their way into commercial applications, the emphasis is put on decreasing the thermal conductivity. In this purely theoretical study, finite element analysis is used to determine the effect of a supporting material on the thermal conductivity of a thermoelectric module. The simulations illustrate the heat transfer along a sample, consisting from Cu, Cu2O and PbTe thermoelectric layers on a 1 mm thick Pyrex glass substrate. The influence of two different types of heating, at a constant temperature and at a constant heat flux, is also investigated. It is revealed that the presence of a supporting material plays an important role on lowering the effective thermal conductivity of the layer-substrate ensemble. By using thinner thermoelectric layers the effective thermal conductivity is further reduced, almost down to the value of the glass substrate. As a result, the temperature gradient becomes steeper for a fixed heating temperature, which allows the production of devices with improved performance under certain conditions. Based on the simulation results, we also propose a model for a robust thin film thermoelectric device. With this suggestion, we invite the thermoelectric community to prove the applicability of the presented concept for practical purposes.
2015-11-09
2014, 95, 16−20. (10) Zhang, P.; Li, Q.; Xuan, Y. Thermal Contact Resistance of Epoxy Composites Incorporated with Nano- Copper Particles and the Multi...Patnaik, S. S.; Roy, A. K.; Froudakis, G.; Farmer, B. L. Modeling of Thermal Transport in Pillared -Graphene Architectures. ACS Nano 2010, 4, 1153−1161
Jamilpanah, Pouya; Pahlavanzadeh, Hassan; Kheradmand, Amanj
2016-09-01
In the present study, nanoscale iron oxide was synthesized using a hydrothermal method; XRD analysis revealed that all the produced crystals are iron oxide. FESEM microscopic imaging showed that particles are on the scale of nano and their morphology is cloud fractal. To study the laboratory properties of thermal conductivity, viscosity, and electrical conductivity of the nanoparticles, they were dispersed in ethylene glycol-based fluid and the nanofluid was in a two-step synthesis during this process. The experiments were carried out with a weight fraction between 0 and 2 % at temperatures between 25 and 45 °C. According to the results of the experiments, increasing the density of nanoparticles in the fluid increases thermal conductivity, as it was predicted in all theoretical models. On the other hand, nano viscosity increases as the weight fraction increases while it decreases as temperature goes up. Electrical conductivity also increases with raising the temperature and weight fraction. Theoretical models were studied to predict Thermal conductivity, viscosity, and electrical conductivity of the nanofluid.
Jamilpanah, Pouya; Pahlavanzadeh, Hassan; Kheradmand, Amanj
2017-04-01
In the present study, nanoscale iron oxide was synthesized using a hydrothermal method; XRD analysis revealed that all the produced crystals are iron oxide. FESEM microscopic imaging showed that particles are on the scale of nano and their morphology is cloud fractal. To study the laboratory properties of thermal conductivity, viscosity, and electrical conductivity of the nanoparticles, they were dispersed in ethylene glycol-based fluid and the nanofluid was in a two-step synthesis during this process. The experiments were carried out with a weight fraction between 0 and 2 % at temperatures between 25 and 45 °C. According to the results of the experiments, increasing the density of nanoparticles in the fluid increases thermal conductivity, as it was predicted in all theoretical models. On the other hand, nano viscosity increases as the weight fraction increases while it decreases as temperature goes up. Electrical conductivity also increases with raising the temperature and weight fraction. Theoretical models were studied to predict Thermal conductivity, viscosity, and electrical conductivity of the nanofluid.
Aguirre-Ramirez, G.; Oden, J. T.
1969-01-01
Finite element method applied to heat conduction in solids with temperature dependent thermal conductivity, using nonlinear constitutive equation for heat ABCDEFGHIABCDEFGHIABCDEFGHIABCDEFGHIABCDEFGHIABCDEFGHIABCDEFGHIABCDEFGHIABCDEFGHIABCDEFGHIABCDEFGHIABCDEFGH
Bording, Thue S.; Nielsen, Søren B.; Balling, Niels
2016-04-01
Accurate information on thermal conductivity and thermal diffusivity of materials is of central importance in relation to geoscience and engineering problems involving the transfer of heat. Within the geosciences, this applies to all aspects regarding the determination of terrestrial heat flow and subsurface temperature modelling. Several methods, including the classical divided-bar technique, are available for laboratory measurements of thermal conductivity, and much fewer for thermal diffusivity. We have generalized the divided-bar technique to the transient case, in which thermal conductivity and volumetric heat capacity, and thereby also thermal diffusivity, are measured simultaneously. As the density of samples is easily determined independently, specific heat capacity may also be determined. Finite element formulation provides a flexible forward solution for heat transfer across the bar and thermal properties are estimated by inverse Monte Carlo modelling. This methodology enables a proper quantification of experimental uncertainties on measured thermal properties. The developed methodology was applied to laboratory measurements of various materials, including a standard ceramic material and different rock samples, and measuring results were compared with results applying traditional steady-state divided-bar and an independent line-source method. All measurements show highly consistent results and with excellent reproducibility and high accuracy. For conductivity, uncertainty is typically 1-3 %, and for diffusivity uncertainty may be reduced to about 3-5 %. The main uncertainty originates from the presence of thermal contact resistance associated with the internal interfaces of the bar. They are not resolved during inversion, and it is highly important that they are minimized by careful sample preparation.
Plane waves in a thermally conducting viscous liquid
Indian Academy of Sciences (India)
Baljeet Singh
2004-02-01
The aim of this paper is to investigate plane waves in a thermally conducting viscous liquid half-space with thermal relaxation times. There exist three basic waves, namely; thermal wave, longitudinal wave and transverse wave in a thermally conducting viscous liquid half-space. Reﬂection of plane waves from the free surface of a thermally conducting viscous liquid half-space is studied. The results are obtained in terms of amplitude ratios and are compared with those without viscosity and thermal disturbances.
Determination of thermal conductivity of magnesium-alloys
Institute of Scientific and Technical Information of China (English)
无
2001-01-01
An indirect method, Angstroms method was adopted and an instrument was designed to determine the thermal conductivity of magnesium metal and alloys. Angstroms method is an axial periodic heat flow technique by which the thermal diffusivity can be measured directly. Then thermal conductivity can be obtained with relation to thermal diffusivity. Compared with the recommended data from the literature the fitted values of the thermal diffiusivity correspond with 3%, and the credible probability of the thermal conductivity in the range of 0-450 ℃ is about 95%. The method is applicable in the given temperature range.
Thermal Properties of Asphalt Mixtures Modified with Conductive Fillers
Directory of Open Access Journals (Sweden)
Byong Chol Bai
2015-01-01
Full Text Available This paper investigates the thermal properties of asphalt mixtures modified with conductive fillers used for snow melting and solar harvesting pavements. Two different mixing processes were adopted to mold asphalt mixtures, dry- and wet-mixing, and two conductive fillers were used in this study, graphite and carbon black. The thermal conductivity was compared to investigate the effects of asphalt mixture preparing methods, the quantity, and the distribution of conductive filler on thermal properties. The combination of conductive filler with carbon fiber in asphalt mixture was evaluated. Also, rheological properties of modified asphalt binders with conductive fillers were measured using dynamic shear rheometer and bending beam rheometer at grade-specific temperatures. Based on rheological testing, the conductive fillers improve rutting resistance and decrease thermal cracking resistance. Thermal testing indicated that graphite and carbon black improve the thermal properties of asphalt mixes and the combined conductive fillers are more effective than the single filler.
Thermal signature and thermal conductivities of PEM fuel cells; PEM = Proton Exchange Membrane
Energy Technology Data Exchange (ETDEWEB)
Burheim, Odne Stokke
2009-11-15
The work gives estimates on thermal gradients within the PEM fuel cell, an experimental route to measure the through-plane thermal conductivity of the materials used in the PEM fuel cell and also suggestions of which material characteristics should be aimed for with respect to thermal management of fuel cells. The work reports for the first time how the thermal conductivity of Nafion changes with water content. An effect residual water has on the thermal conductivity of the PTL is also reported for the first time. In addition to this a calorimeter for the PEMFC was constructed to measure the thermal signature. This is also reported for the first time in the literature. To elucidate the heat gradients possible within a PEM fuel cell and to better understand the calorimetric measurements, a 2D thermal model was created and applied at different conditions. The model was made by the use of the finite element method software COMSOL 3.3. This model was used to evaluate temperature elevations in the single cell mainly imposed by water transport, component thermal conductivity modifications and gas flow channel design. The 2D model was compared to a 1 D model to demonstrate the importance of taking the gas flow channel design into account. Parallel gas flow channels tend to impose an increased current density under the gas channel while serpentine flow channel pattern does the opposite, according to several studies. Thus a simple 2D model can, as very good approximation, be used to study effects rising from 3D cell designs. It was demonstrated that parallel flow fields give a higher maximum temperature than serpentine gas flow channels. Changes in the porous transport layer, such as compression, residual water and increased through-plane thermal conductivity were also discussed. In general, the maximum temperatures predicted for the PEM fuel cell were between 4.5 and 15 K above the control temperature in the polarization plate, depending on the conditions in the model. One
Experimental Investigations on Thermal Conductivity of Fenugreek and Banana Composites
Pujari, Satish; Venkatesh, Talari; Seeli, Hepsiba
2017-06-01
The use of composite materials in manufacturing has significantly increased in the past decade. Research is being done to identify natural fibers that can be used as composites. Several natural fibers are already being used in the industry as composites. The appealing advantages of using natural fibers are reflected in lower density when compared to synthetic fibers and also in saving costs. This research paper highlights the experiment that analyses the use of biodegradable fenugreek composite as natural fiber and concludes that fenugreek natural fibers are an excellent substitute to the synthetic fibers in terms of reinforcement properties for the polymers. These fenugreek fibers are naturally sourced, renewable, cost effective and bio-friendly. In thermal energy storage systems as well as in air conditioning systems, thermal insulators are predominantly used to enhance the storage properties. An experiment was created to investigate the thermal properties of fenugreek banana composites for different fiber concentrations. The experimental results showed that the thermal conductivity of the composites decrease with an increase in the fiber content. The experimental results were compared with the theoretical models to describe the variation of thermal conductivity with the volume fraction of the fiber. Good agreement between theoretical and experimental results was observed.
Institute of Scientific and Technical Information of China (English)
Zun Peng; Yan-ping Bao; Ya-nan Chen; Li-kang Yang; Cao Xie; Feng Zhang
2014-01-01
An unsteady, two-dimensional, explicitly solved finite difference heat transfer model of a billet caster was presented to clarify the influence of the thermal conductivity of steel on model accuracy. Different approaches were utilized for calculating the thermal conductivity of solid, mushy and liquid steels. Model results predicted by these approaches were compared, and the advantages of advocated approaches were discussed. It is found that the approach for calculating the thermal conductivity of solid steel notably influences model predictions. Convection effects of liquid steel should be considered properly while calculating the thermal conductivity of mushy steel. Different values of the effective thermal conductivity of liquid steel adopted could partly be explained by the fact that different models adopted dissimilar ap-proaches for calculating the thermal conductivity of solid and mushy steels.
Mean-field versus microconvection effects in nanofluid thermal conduction.
Eapen, Jacob; Williams, Wesley C; Buongiorno, Jacopo; Hu, Lin-Wen; Yip, Sidney; Rusconi, Roberto; Piazza, Roberto
2007-08-31
Transient hot-wire data on thermal conductivity of suspensions of silica and perfluorinated particles show agreement with the mean-field theory of Maxwell but not with the recently postulated microconvection mechanism. The influence of interfacial thermal resistance, convective effects at microscales, and the possibility of thermal conductivity enhancements beyond the Maxwell limit are discussed.
Mean-Field Versus Microconvection Effects in Nanofluid Thermal Conduction
Eapen, Jacob; Williams, Wesley C.; Buongiorno, Jacopo; Hu, Lin-Wen; Yip, Sidney; Rusconi, Roberto; Piazza, Roberto
2007-08-01
Transient hot-wire data on thermal conductivity of suspensions of silica and perfluorinated particles show agreement with the mean-field theory of Maxwell but not with the recently postulated microconvection mechanism. The influence of interfacial thermal resistance, convective effects at microscales, and the possibility of thermal conductivity enhancements beyond the Maxwell limit are discussed.
Thermal Conductivity of Carbon Nanotubes Embedded in Solids
Institute of Scientific and Technical Information of China (English)
CAO Bing-Yang; HOU Quan-Wen
2008-01-01
@@ A carbon-nanotube-atom fixed and activated scheme of non-equilibrium molecular dynamics simulations is put forward to extract the thermal conductivity of carbon nanotubes (CNTs) embedded in solid argon. Though a 6.5% volume fraction of CNTs increases the composite thermal conductivity to about twice as much as that of the pure basal material, the thermal conductivity of CNTs embedded in solids is found to be decreased by 1/8-1/5with reference to that of pure ones. The decrease of the intrinsic thermal conductivity of the solid-embedded CNTs and the thermal interface resistance are demonstrated to be responsible for the results.
Micromachined hot-wire thermal conductivity probe for biomedical applications.
Yi, Ming; Panchawagh, Hrishikesh V; Podhajsky, Ronald J; Mahajan, Roop L
2009-10-01
This paper presents the design, fabrication, numerical simulation, and experimental validation of a micromachined probe that measures thermal conductivity of biological tissues. The probe consists of a pair of resistive line heating elements and resistance temperature detector sensors, which were fabricated by using planar photolithography on a glass substrate. The numerical analysis revealed that the thermal conductivity and diffusivity can be determined by the temperature response induced by the uniform heat flux in the heating elements. After calibrating the probe using a material (agar gel) of known thermal conductivity, the probe was deployed to calculate the thermal conductivity of Crisco. The measured value is in agreement with that determined by the macro-hot-wire probe method to within 3%. Finally, the micro thermal probe was used to investigate the change of thermal conductivity of pig liver before and after RF ablation treatment. The results show an increase in thermal conductivity of liver after the RF ablation.
Institute of Scientific and Technical Information of China (English)
陈春; 钱春香; 许燕波
2012-01-01
The traditional calculation model of thermal conductivity of concrete that mechanically compartmentalizes the transfer path of heat flow in concrete material according to its compositions can seldom meet the minimum thermal resistance theory and may lead to large simulation results. Based on the minimum thermal resistance theory, an improved model considering the role of pore in concrete is presented. By introducing the heat transfer area proportion coefficient method, the comp-artmentalization of heat flow in concrete can meet not only the requirements of the concrete compositions , but also the minimum thermal resistance theory. The thermal conductivity of eight kinds of concrete is calculated by using the model. The deviation between the calculated results and experimental results ranges from - 14. 0% to +5. 1% , while the corresponding deviation scope by the Harmathy model and the Campbell-Allen and Throne model are 4.9%-29. 3% and 11.0%-32.1 % , respectively. It can be found that the presented model is more accurate than the traditional calculation models of thermal conductivity.%针对传统混凝土导热系数计算模型机械地按照混凝土组成来划分热流途径而导致计算结果偏大的问题,基于最小热阻理论,并考虑到混凝土中孔隙作用,对传统混凝土导热系数计算模型进行了改进.通过引入传热面积比例系数的方法,使混凝土中热流途径的划分不仅满足了混凝土组成的要求,而且满足了最小热阻理论.采用该模型分别计算了8种混凝土的导热系数,其计算结果与实测结果的误差率在-14.0％ ～ +5.1％范围内,而Harmathy模型和Campbell-Allen and Throne模型的计算结果与实测结果误差率分别在4.9％ ～29.3％和11.0％～32.1％范围内.相比于传统的混凝土导热系数计算模型,基于最小热阻理论建立的混凝土导热系数计算模型精度有了较大的提高.
Institute of Scientific and Technical Information of China (English)
X.G.Liang; X.S.Ge; 等
1992-01-01
This investigation was done to study the gas filled powder insulation and thermal conductivity probe for the measurent of thermal conductivity of powders.The mathematical analysis showed that the heat capacity of the probe itself and the thermal rsistance between the probe and powder must be considered .The authors developed a slender probe and measured the effective thermal conductivity of sillca and carbon black powders under a variety of conditions.
Honda, S.; Yuen, D. A.
2004-04-01
We have extended our previous analysis of the effects of constant vs. variable, i.e., pressure and temperature dependent thermal conductivity (k) and constant thermal expansivity (a) on the thermal structure of the oceanic lithosphere. We apply our analysis to the actual data set including information on the geoid slope. The heat flow and ocean floor depth data constrain the thermal expansivity (a ≍ 3 × 10-5 1/°C). Including geoid slope data may loosely constrain both the thermal expansivity and the thermal conductivity. The probable value of thermal conductivity is ≍ 3 W/m/°C for the constant k case and ≍ 4 W/m/°C (at ambient conditions) for the variable k case. These a and k are generally consistent with laboratory data of appropriate lithospheric materials. Our analysis supports the plate model with thin lithosphere and high bottom temperature, such as GDH1 (95 km; 1450°C). Variable k case requires slightly thinner and higher temperature lithosphere (≍ 85 km and ≍ 1500°C) and gives a slightly better fit to the geoid slope data.
Modeling Thermal Contact Resistance
Kittel, Peter; Sperans, Joel (Technical Monitor)
1994-01-01
One difficulty in using cryocoolers is making good thermal contact between the cooler and the instrument being cooled. The connection is often made through a bolted joint. The temperature drop associated with this joint has been the subject of many experimental and theoretical studies. The low temperature behavior of dry joints have shown some anomalous dependence on the surface condition of the mating parts. There is also some doubts on how well one can extrapolate from the test samples to predicting the performance of a real system. Both finite element and analytic models of a simple contact system have been developed. The model assumes (a) the contact is dry (contact limited to a small portion of the total available area and the spaces in-between the actual contact patches are perfect insulators), (b) contacts are clean (conductivity of the actual contact is the same as the bulk), (c) small temperature gradients (the bulk conductance may be assumed to be temperature independent), (d) the absolute temperature is low (thermal radiation effects are ignored), and (e) the dimensions of the nominal contact area are small compared to the thickness of the bulk material (the contact effects are localized near the contact). The models show that in the limit of actual contact area much less than the nominal area (a much less than A), that the excess temperature drop due to a single point of contact scales as a(exp -1/2). This disturbance only extends a distance approx. A(exp 1/2) into the bulk material. A group of identical contacts will result in an excess temperature drop that scales as n(exp -1/2), where n is the number of contacts and n dot a is constant. This implies that flat rough surfaces will have a lower excess temperature drop than flat polished surfaces.
Salaway, Richard N.; Zhigilei, Leonid V.
2016-07-01
The contact conductance of carbon nanotube (CNT) junctions is the key factor that controls the collective heat transfer through CNT networks or CNT-based materials. An improved understanding of the dependence of the intertube conductance on the contact structure and local environment is needed for predictive computational modeling or theoretical description of the effective thermal conductivity of CNT materials. To investigate the effect of local structure on the thermal conductance across CNT-CNT contact regions, nonequilibrium molecular dynamics (MD) simulations are performed for different intertube contact configurations (parallel fully or partially overlapping CNTs and CNTs crossing each other at different angles) and local structural environments characteristic of CNT network materials. The results of MD simulations predict a stronger CNT length dependence present over a broader range of lengths than has been previously reported and suggest that the effect of neighboring junctions on the conductance of CNT-CNT junctions is weak and only present when the CNTs that make up the junctions are within the range of direct van der Waals interaction with each other. A detailed analysis of the results obtained for a diverse range of intertube contact configurations reveals a nonlinear dependence of the conductance on the contact area (or number of interatomic intertube interactions) and suggests larger contributions to the conductance from areas of the contact where the density of interatomic intertube interactions is smaller. An empirical relation accounting for these observations and expressing the conductance of an arbitrary contact configuration through the total number of interatomic intertube interactions and the average number of interatomic intertube interactions per atom in the contact region is proposed. The empirical relation is found to provide a good quantitative description of the contact conductance for various CNT configurations investigated in the MD
Measuring the Thermal Conductivities of Low Heat Conducting Disk Samples by Monitoring the Heat Flow
Directory of Open Access Journals (Sweden)
José A. Ibáñez-Mengual
2017-02-01
Full Text Available This article aims to establish an experimental procedure to measure heat transmission coefficients in low heat conductive materials. The newly developed model takes as starting point the application of Fourier’s law to a disk sample when a temperature gradient is established between its faces. The power of a heating element is determined as the heat transfer coefficient of the problem disk. Initially, a glass vessel containing water is placed in direct contact with the heating element; then, a problem plastic disk is placed between this element and the glass vessel, treating the set as a composite wall. Prior to the above the water equivalent of a calorimetric set (vessel + water + accessories and the thermal conductivity of the vessel must be determined. The thermal conductivity of the problem plastic disk sample is obtained for temperatures ranging from 30 to 70° C. The results reveal the existence of some type of structural transition for the problem material.
Thermal conductivity and multiferroics of electroactive polymers and polymer composites
Jin, Jiezhu
Electronically conducting polymers and electromechanical polymers are the two important branches of the cutting-edge electroactive polymers. They have shown significant impact on many modern technologies such as flat panel display, energy transport, energy conversion, sensors and actuators. To utilize conducting polymers in microelectronics, optoelectronics and thermoelectrics, it is necessary to have a comprehensive study of their thermal conductivity since thermal conductivity is a fundamental materials property that is particularly important and sometimes a determining factor of the device performance. For electromechanical polymers, larger piezoelectric effect will contribute to the improvement of magnetoelectric (ME) coupling efficiency in their multiferroic composites. This dissertation is devoted to characterizing electronically conducting polymers for their electrical and thermal conductivity, and developing new classes of electromechanical polymers and strain-mediated electromechanical polymer-based multiferroic ME composites. Conducting polymers opened up new possibilities for devices combining novel electrical and thermal properties, but there has been limited understanding of the length-scale effect of the electrical and thermal conductivity, and the mechanism underlying the electricity and heat transport behavior. In this dissertation, the analytical model and experimental technique are presented to measure the in-plane thermal conductivity of polyaniline thin films. For camphorsulfonic acid doped polyaniline patterned on silicon oxide/silicon substrate using photolithography and reactive ion etching, the thermal conductivity of the film with thickness of 20 nm is measured to be 0.0406 W/m˙K, which significantly deviates from their bulk (> 0.26 W/m˙K). The size effect on thermal conductivity at this scale is attributed to the significant phonon boundary scattering. When the film goes up to 130 nm thick, the thermal conductivity increases to 0.166 W
THERMAL CONDUCTIVITY OF RUBBERIZED GYPSUM BOARD
Taher Abu-Lebdeh; Ellie Fini; Ashraf Fadiel
2014-01-01
The disposal of scrap tires is a challenging task and hence an innovative solution to meet these challenges is needed. Extensive work has been done on the utilization of waste tires in a variety of applications in asphalt pavements and concrete. However, previous investigations focus only on the mechanical properties of the rubberized materials, but few on the thermal performance. This is especially true for rubberized gypsum. Limited or no experimental data on the thermal performance of rubb...
Shocks and Thermal Conduction Fronts in Retracting Reconnected Flux Tubes
Guidoni, Silvina
2010-01-01
We present a model for plasma heating produced by time-dependent, spatially localized reconnection within a flare current sheet separating skewed magnetic fields. The reconnection creates flux tubes of new connectivity which subsequently retract at Alfv\\'enic speeds from the reconnection site. Heating occurs in gas-dynamic shocks which develop inside these tubes. Here we present generalized thin flux tube equations for the dynamics of reconnected flux tubes, including pressure-driven parallel dynamics as well as temperature dependent, anisotropic viscosity and thermal conductivity. The evolution of tubes embedded in a uniform, skewed magnetic field, following reconnection in a patch, is studied through numerical solutions of these equations, for solar coronal conditions. Even though viscosity and thermal conductivity are negligible in the quiet solar corona, the strong gas-dynamic shocks generated by compressing plasma inside reconnected flux tubes generate large velocity and temperature gradients along the t...
Tuning thermal conductivity in molybdenum disulfide by electrochemical intercalation
Zhu, Gaohua; Liu, Jun; Zheng, Qiye; Zhang, Ruigang; Li, Dongyao; Banerjee, Debasish; Cahill, David G.
2016-10-01
Thermal conductivity of two-dimensional (2D) materials is of interest for energy storage, nanoelectronics and optoelectronics. Here, we report that the thermal conductivity of molybdenum disulfide can be modified by electrochemical intercalation. We observe distinct behaviour for thin films with vertically aligned basal planes and natural bulk crystals with basal planes aligned parallel to the surface. The thermal conductivity is measured as a function of the degree of lithiation, using time-domain thermoreflectance. The change of thermal conductivity correlates with the lithiation-induced structural and compositional disorder. We further show that the ratio of the in-plane to through-plane thermal conductivity of bulk crystal is enhanced by the disorder. These results suggest that stacking disorder and mixture of phases is an effective mechanism to modify the anisotropic thermal conductivity of 2D materials.
Rapid thermal conductivity measurements for combinatorial thin films.
McDowell, Matthew G; Hill, Ian G
2013-05-01
A simple and inexpensive automated method for determining the thermal conductivity of a combinatorial library of thin films is demonstrated by measuring the thermal conductivity of a sputtered silicon dioxide film of varying thickness deposited on single crystal silicon. Using 3ω measurements, two methods for calculating the substrate thermal conductivity and two methods for determining the film thermal conductivity are demonstrated and compared. The substrate thermal conductivity was found to be 139 ± 3 W/m·K. Using the measured variation in film thickness, the film thermal conductivity was found to be 1.11 ± 0.05 W/m·K, in excellent agreement with published values for sputtered SiO2, demonstrating the accuracy of the method.
Tuning thermal conductivity in molybdenum disulfide by electrochemical intercalation.
Zhu, Gaohua; Liu, Jun; Zheng, Qiye; Zhang, Ruigang; Li, Dongyao; Banerjee, Debasish; Cahill, David G
2016-10-21
Thermal conductivity of two-dimensional (2D) materials is of interest for energy storage, nanoelectronics and optoelectronics. Here, we report that the thermal conductivity of molybdenum disulfide can be modified by electrochemical intercalation. We observe distinct behaviour for thin films with vertically aligned basal planes and natural bulk crystals with basal planes aligned parallel to the surface. The thermal conductivity is measured as a function of the degree of lithiation, using time-domain thermoreflectance. The change of thermal conductivity correlates with the lithiation-induced structural and compositional disorder. We further show that the ratio of the in-plane to through-plane thermal conductivity of bulk crystal is enhanced by the disorder. These results suggest that stacking disorder and mixture of phases is an effective mechanism to modify the anisotropic thermal conductivity of 2D materials.
Thermal conductivity degradation of graphites irradiated at low temperature
Energy Technology Data Exchange (ETDEWEB)
Snead, L.L.; Burchell, T.D. [Oak Ridge National Lab., TN (United States)
1995-04-01
The objective of this work is to study the thermal conductivity degradation of new, high thermal conductivity graphites and to compare these results to more standard graphites irradiated at low temperatures. Several graphites and graphite composites (C/C`s) have been irradiated near 150{degree}C and at fluences up to a displacement level of 0.24 dpa. The materials ranged in unirradiated room temperature thermal conductivity of these materials varied from 114 W/m-K for H-451 isotropic graphite, to 670 W/m-K for unidirectional FMI-1D C/C composite. At the irradiation temperature a saturation reduction in thermal conductivity was seen to occur at displacement levels of approximately 0.1 dpa. All materials were seen to degrade to approximately 10 to 14 % of their original thermal conductivity after irradiation. The effect of post irradiation annealing on the thermal conductivity was also studied.
Tuning thermal conductivity in molybdenum disulfide by electrochemical intercalation
Zhu, Gaohua; Liu, Jun; Zheng, Qiye; Zhang, Ruigang; Li, Dongyao; Banerjee, Debasish; Cahill, David G.
2016-01-01
Thermal conductivity of two-dimensional (2D) materials is of interest for energy storage, nanoelectronics and optoelectronics. Here, we report that the thermal conductivity of molybdenum disulfide can be modified by electrochemical intercalation. We observe distinct behaviour for thin films with vertically aligned basal planes and natural bulk crystals with basal planes aligned parallel to the surface. The thermal conductivity is measured as a function of the degree of lithiation, using time-domain thermoreflectance. The change of thermal conductivity correlates with the lithiation-induced structural and compositional disorder. We further show that the ratio of the in-plane to through-plane thermal conductivity of bulk crystal is enhanced by the disorder. These results suggest that stacking disorder and mixture of phases is an effective mechanism to modify the anisotropic thermal conductivity of 2D materials. PMID:27767030
Universal Features of Quantized Thermal Conductance of Carbon Nanotubes
Yamamoto, Takahiro; Watanabe, Satoshi; Watanabe, Kazuyuki
2003-01-01
The universal features of quantized thermal conductance of carbon nanotubes (CNTs) are revealed through theoretical analysis based on the Landauer theory of heat transport. The phonon-derived thermal conductance of semiconducting CNTs exhibits a universal quantization in the low temperature limit, independent of the radius or atomic geometry. The temperature dependence follows a single curve given in terms of temperature scaled by the phonon energy gap. The thermal conductance of metallic CNT...
Thermal conductivity of nickel superalloy MAR-M247
P. Jonšta; Koštial, P.; Jonšta, Z.; Vlčková, I.; T. Kulová
2016-01-01
The paper presents the narrow connection between γ’ phase dissolving and values of thermal conductivity. In annealing process the free space among γ’ particles (blocks) changes in certain cycle from fine to rough and back to fine. This is accompanied by decrease and subsequent increase of thermal conductivity as well as the sample density. The results of thermal conductivity coarse are supported by image analysis. Web of Science 55 3 422 420
Energy Technology Data Exchange (ETDEWEB)
Mesalhy, O.; Lafdi, K.; Elgafy, A.; Bowman, K. [Dayton University Research Inst., OH (United States)
2005-04-01
In this paper, the melting process inside an irregular geometry filled with high thermal conductivity porous matrix saturated with phase change material PCM is investigated numerically. The numerical model is resting on solving the volume averaged conservation equations for mass, momentum and energy with phase change (melting) in the porous medium. The convection motion of the liquid phase inside the porous matrix is solved considering the Darcy, Brinkman and Forchiemer effects. A local thermal non-equilibrium assumption is considered due to the large difference in thermal properties between the solid matrix and PCM by applying a two energy equation model. The numerical code shows good agreement for pure PCM melting with another published numerical work. Through this study it is found that the presence of the porous matrix has a great effect on the heat transfer and melting rate of the PCM energy storage. Decreasing the porosity of the matrix increases the melting rate, but it also damps the convection motion. It is also found that the best technique to enhance the response of the PCM storage is to use a solid matrix with high porosity and high thermal conductivity. (author)
Institute of Scientific and Technical Information of China (English)
李海; 黄晨; 杜爱兵; 徐宝玉
2014-01-01
The thermal conductivity is one of the most important parameters in the computer code for performance prediction for fuel rods.Several fuel thermal conductivity models used in foreign computer code,including thermal conductivity models for MOX fuel and UO2 fuel were introduced in this paper. Thermal conductivities were calculated by using these models, and the results were compared and analyzed.Finally, the thermal conductivity model for the native computer code for performance prediction for fuel rods in fast reactor was recommended.%热导率是燃料元件性能分析程序最重要的参数之一，本文介绍了各国部分性能分析程序的燃料热导率模型，按照 MOX和 UO2燃料分类，给出了这些性能分析程序热导率模型的计算结果，并进行分析对比，给出了国产快堆性能分析程序的热导率推荐模型。
Thermal conductivity of isotopically modified graphene.
Chen, Shanshan; Wu, Qingzhi; Mishra, Columbia; Kang, Junyong; Zhang, Hengji; Cho, Kyeongjae; Cai, Weiwei; Balandin, Alexander A; Ruoff, Rodney S
2012-01-10
In addition to its exotic electronic properties graphene exhibits unusually high intrinsic thermal conductivity. The physics of phonons--the main heat carriers in graphene--has been shown to be substantially different in two-dimensional (2D) crystals, such as graphene, from in three-dimensional (3D) graphite. Here, we report our experimental study of the isotope effects on the thermal properties of graphene. Isotopically modified graphene containing various percentages of 13C were synthesized by chemical vapour deposition (CVD). The regions of different isotopic compositions were parts of the same graphene sheet to ensure uniformity in material parameters. The thermal conductivity, K, of isotopically pure 12C (0.01% 13C) graphene determined by the optothermal Raman technique, was higher than 4,000 W mK(-1) at the measured temperature T(m)~320 K, and more than a factor of two higher than the value of K in graphene sheets composed of a 50:50 mixture of 12C and 13C. The experimental data agree well with our molecular dynamics (MD) simulations, corrected for the long-wavelength phonon contributions by means of the Klemens model. The experimental results are expected to stimulate further studies aimed at a better understanding of thermal phenomena in 2D crystals.
Thermal conductivity determination of cometary and asteroid material analogues
Banaszkiewicz, M.; Seweryn, K.; Wawrzaszek, R.
Measurements of physical properties of surface and subsurface layers of planetary bodies often provide important information about the structure of the medium and processes that occur there Thermal properties of cometary nuclues subsurface material are crucial in determining the heat and gas transport Similarly asteroid s regolith is a buffering zone in heat transfer from to surface to from interior of a body There are space experiments planned to perform temperature and thermal conductivity measurements on a comet ROSETTA and one can easily foresee such measurements carried out by future robotic missions on Mars planetary satellites and asteroids In the paper we present the results of measurements carried out with a new type of thermal sensors The elementary cylindrical sensor is made of platinum wire resistance thermometer and isotan wire heating element that can operate independently By choosing these materials the problems of temperature measurement calibration and constant heating power are resolved We confront the results of measurements made for a number of sensors combined into a long cylinder in delrin basalt ice-dust mixture comet analogue and regolith-like material with models and show that agreement is very good Therefore we can recommend both the sensors and the method of data interpretation for the thermal conductivity determination as very useful tools in future space missions and in laboratory experiments on cometary and asteroid material analogues
Prediction of the Effective Thermal Conductivity of Powder Insulation
Jin, Lingxue; Park, Jiho; Lee, Cheonkyu; Jeong, Sangkwon
The powder insulation method is widely used in structural and cryogenic systems such as transportation and storage tanks of cryogenic fluids. The powder insulation layer is constructed by small particle powder with light weight and some residual gas with high porosity. So far, many experiments have been carried out to test the thermal performance of various kinds of powder, including expanded perlite, glass microspheres, expanded polystyrene (EPS). However, it is still difficult to predict the thermal performance of powder insulation by calculation due to the complicated geometries, including various particle shapes, wide powder diameter distribution, and various pore sizes. In this paper, the effective thermal conductivity of powder insulation has been predicted based on an effective thermal conductivity calculationmodel of porous packed beds. The calculation methodology was applied to the insulation system with expanded perlite, glass microspheres and EPS beads at cryogenic temperature and various vacuum pressures. The calculation results were compared with previous experimental data. Moreover, additional tests were carried out at cryogenic temperature in this research. The fitting equations of the deformation factor of the area-contact model are presented for various powders. The calculation results show agood agreement with the experimental results.
Enhanced thermal conductance of polymer composites through embeddingaligned carbon nanofibers
Directory of Open Access Journals (Sweden)
Dale K. Hensley
2016-07-01
Full Text Available The focus of this work is to find a more efficient method of enhancing the thermal conductance of polymer thin films. This work compares polymer thin films embedded with randomly oriented carbon nanotubes to those with vertically aligned carbon nanofibers. Thin films embedded with carbon nanofibers demonstrated a similar thermal conductance between 40–60 μm and a higher thermal conductance between 25–40 μm than films embedded with carbon nanotubes with similar volume fractions even though carbon nanotubes have a higher thermal conductivity than carbon nanofibers.
Reduced thermal conductivity of isotopically modulated silicon multilayer structures
DEFF Research Database (Denmark)
Bracht, H.; Wehmeier, N.; Eon, S.;
2012-01-01
We report measurements of the thermal conductivity of isotopically modulated silicon that consists of alternating layers of highly enriched silicon-28 and silicon-29. A reduced thermal conductivity of the isotopically modulated silicon compared to natural silicon was measured by means of time......-resolved x-ray scattering. Comparison of the experimental results to numerical solutions of the corresponding heat diffusion equations reveals a factor of three lower thermal conductivity of the isotope structure compared to natural Si. Our results demonstrate that the thermal conductivity of silicon can...
Thermal Conductivity of Alumina-Toughened Zirconia Composites
Bansal, Narottam P.; Zhu, Dong-Ming
2003-01-01
10-mol% yttria-stabilized zirconia (10YSZ)-alumina composites containing 0 to 30 mol% alumina were fabricated by hot pressing at 1500 C in vacuum. Thermal conductivity of the composites, determined at various temperatures using a steady-state laser heat flux technique, increased with increase in alumina content. Composites containing 0, 5, and 10-mol% alumina did not show any change in thermal conductivity with temperature. However, those containing 20 and 30-mol% alumina showed a decrease in thermal conductivity with increase in temperature. The measured values of thermal conductivity were in good agreement with those calculated from simple rule of mixtures.
Dependence of thermal conductivity in micro to nano silica
Indian Academy of Sciences (India)
Vangala Dhanunjana Chari; Deepala V S G K Sharma; Pinnelli S R Prasad; S Ramana Murthy
2013-08-01
This work presents the measurement of thermal conductivity of nano-silica particles using needle probe method. The validation test of thermal probe was conducted on ice and THF hydrates using our experimental set up and the results are satisfactory when compared with the literature data. The nano silica used in this study is with particle sizes in the range 50–1000 nm. The sand powders sieved in different sizes <75 and 75 m > > 250 m were also studied to probe the particle size dependence on thermal conductivity. Thermal conductivity decreased by about 70% in silica nano powders.
Thermal conductivity of penta-graphene from molecular dynamics study.
Xu, Wen; Zhang, Gang; Li, Baowen
2015-10-21
Using classical equilibrium molecular dynamics simulations and applying the original Tersoff interatomic potential, we study the thermal transport property of the latest two dimensional carbon allotrope, penta-graphene. It is predicted that its room-temperature thermal conductivity is about 167 W/mK, which is much lower than that of graphene. With normal mode decomposition, the accumulated thermal conductivity with respect to phonon frequency and mean free path is analyzed. It is found that the acoustic phonons make a contribution of about 90% to the thermal conductivity, and phonons with mean free paths larger than 100 nm make a contribution over 50%. We demonstrate that the remarkably lower thermal conductivity of penta-graphene compared with graphene results from the lower phonon group velocities and fewer collective phonon excitations. Our study highlights the importance of structure-property relationship and provides better understanding of thermal transport property and valuable insight into thermal management of penta-graphene.
Controlling thermal chaos in the mantle by positive feedback from radiative thermal conductivity
Directory of Open Access Journals (Sweden)
F. Dubuffet
2002-01-01
Full Text Available The thermal conductivity of mantle materials has two components, the lattice component klat from phonons and the radiative component krad due to photons. These two contributions of variable thermal conductivity have a nonlinear dependence in the temperature, thus endowing the temperature equation in mantle convection with a strongly nonlinear character. The temperature derivatives of these two mechanisms have different signs, with ∂klat /∂T negative and dkrad /dT positive. This offers the possibility for the radiative conductivity to control the chaotic boundary layer instabilities developed in the deep mantle. We have parameterized the weight factor between krad and klat with a dimensionless parameter f , where f = 1 corresponds to the reference conductivity model. We have carried out two-dimensional, time-dependent calculations for variable thermal conductivity but constant viscosity in an aspect-ratio 6 box for surface Rayleigh numbers between 106 and 5 × 106. The averaged Péclet numbers of these flows lie between 200 and 2000. Along the boundary in f separating the chaotic and steady-state solutions, the number decreases and the Nusselt number increases with internal heating, illustrating the feedback between internal heating and radiative thermal conductivity. For purely basal heating situation, the time-dependent chaotic flows become stabilized for values of f of between 1.5 and 2. The bottom thermal boundary layer thickens and the surface heat flow increases with larger amounts of radiative conductivity. For magnitudes of internal heating characteristic of a chondritic mantle, much larger values of f , exceeding 10, are required to quench the bottom boundary layer instabilities. By isolating the individual conductive mechanisms, we have ascertained that the lattice conductivity is partly responsible for inducing boundary layer instabilities, while the radiative conductivity and purely depth-dependent conductivity exert a stabilizing
Anisotropic thermal conductivity of thin polycrystalline oxide samples
Directory of Open Access Journals (Sweden)
A. Tiwari
2013-11-01
Full Text Available This paper reports about the development of a modified laser-flash technique and relation to measure the in-plane thermal diffusivity of thin polycrystalline oxide samples. Thermal conductivity is then calculated with the product of diffusivity, specific heat and density. Design and operating features for evaluating in-plane thermal conductivities are described. The technique is advantageous as thin samples are not glued together to measure in-plane thermal conductivities like earlier methods reported in literature. The approach was employed to study anisotropic thermal conductivity in alumina sheet, textured kaolin ceramics and montmorillonite. Since it is rare to find in-plane thermal conductivity values for such anisotropic thin samples in literature, this technique offers a useful variant to existing techniques.
Anisotropic thermal conductivity of thin polycrystalline oxide samples
Energy Technology Data Exchange (ETDEWEB)
Tiwari, A., E-mail: abhishektiwariiitr@gmail.com [Groupe d’Etudes des Matériaux Hétérogènes (GEMH, EA 3178), Ecole Nationale Supérieure de Céramique Industrielle, 12, Rue Atlantis, 87068 Limoges Cedex (France); Department of Mechanical and Aerospace Engineering, Monash University, Melbourne, VIC 3800 (Australia); Boussois, K.; Nait-Ali, B.; Smith, D. S.; Blanchart, P. [Groupe d’Etudes des Matériaux Hétérogènes (GEMH, EA 3178), Ecole Nationale Supérieure de Céramique Industrielle, 12, Rue Atlantis, 87068 Limoges Cedex (France)
2013-11-15
This paper reports about the development of a modified laser-flash technique and relation to measure the in-plane thermal diffusivity of thin polycrystalline oxide samples. Thermal conductivity is then calculated with the product of diffusivity, specific heat and density. Design and operating features for evaluating in-plane thermal conductivities are described. The technique is advantageous as thin samples are not glued together to measure in-plane thermal conductivities like earlier methods reported in literature. The approach was employed to study anisotropic thermal conductivity in alumina sheet, textured kaolin ceramics and montmorillonite. Since it is rare to find in-plane thermal conductivity values for such anisotropic thin samples in literature, this technique offers a useful variant to existing techniques.
Thermal conductivity of disordered two-dimensional binary alloys.
Zhou, Yang; Guo, Zhi-Xin; Cao, Hai-Yuan; Chen, Shi-You; Xiang, Hong-Jun; Gong, Xin-Gao
2016-10-20
Using non-equilibrium molecular dynamics simulations, we have studied the effect of disorder on the thermal conductivity of two-dimensional (2D) C1-xNx alloys. We find that the thermal conductivity not only depends on the substitution concentration of nitrogen, but also strongly depends on the disorder distribution. A general linear relationship is revealed between the thermal conductivity and the participation ratio of phonons in 2D alloys. Localization mode analysis further indicates that the thermal conductivity variation in the ordered alloys can be attributed to the number of inequivalent atoms. As for the disordered alloys, we find that the thermal conductivity variation can be described by a simple linear formula with the disorder degree and the substitution concentration. The present study suggests some general guidance for phonon manipulation and thermal engineering in low dimensional alloys.
A study on the thermal conductivity of compacted bentonites
Tang, Anh-Minh; Le, Trung Tinh; 10.1016/j.clay.2007.11.001
2008-01-01
Thermal conductivity of compacted bentonite is one of the most important properties in the design of high-level radioactive waste repositories where this material is proposed for use as a buffer. In the work described here, a thermal probe based on the hot wire method was used to measure the thermal conductivity of compacted bentonite specimens. The experimental results were analyzed to observe the effects of various factors (i.e. dry density, water content, hysteresis, degree of saturation and volumetric fraction of soil constituents) on the thermal conductivity. A linear correlation was proposed to predict the thermal conductivity of compacted bentonite based on experimentally observed relationship between the volumetric fraction of air and the thermal conductivity. The relevance of this correlation was finally analyzed together with others existing methods using experimental data on several compacted bentonites.
Nanofluids Thermal Conductivity Measurement in a Bénard Cell
Directory of Open Access Journals (Sweden)
Mohamed Mojahed
2013-01-01
Full Text Available Thermal conductivity measurements of nanofluids were the subject of a considerable amount of published research works. Up to now, the experimental results reported in the current literature are still scarce and show many discrepancies. In this paper we propose measurements of this parameter using another experimental set-up. Because of very good thermal controls and big aspect ratio, the Bénard set-up is particularly well suited to determine the thermal conductivity. The aim of this paper is to detail the experimental measurement protocol. The investigated liquid is composed of single walled carbon nanotubes dispersed in water. The effect of liquid temperature on thermal conductivity was investigated. Obtained results confirm the potential of nanofluids in enhancing thermal conductivity and also show that the thermal conductivity temperature dependence is nonlinear, which is different from the results for metal/metal oxide nanofluids.
Increased Thermal Conductivity in Metal-Organic Heat Carrier Nanofluids
Energy Technology Data Exchange (ETDEWEB)
Nandasiri, Manjula I.; Liu, Jian; McGrail, B. Peter; Jenks, Jeromy WJ; Schaef, Herbert T.; Shutthanandan, V.; Nie, Zimin; Martin, Paul F.; Nune, Satish K.
2016-06-15
Metal organic heat carriers (MOHCs) are recently developed nanofluids containing metal organic framework (MOF) nanoparticles dispersed in various base fluids including refrigerants (R245Fa) and methanol. MOHCs utilize the MOF properties to improve the thermo-physical properties of base fluids. Here, we report the synthesis and characterization of MOHCs containing nanoMIL-101(Cr) and graphene oxide (GO) in an effort to improve the thermo-physical properties of various base fluids. MOHC containing MIL-101(Cr)/GO nanocomposites showed enhanced surface area, porosity, and nitrogen adsorption compared with the intrinsic nano MIL-101(Cr) and the properties depend on the amount of GO added. Powder X-ray diffraction (PXRD) confirmed the preserved crystallinity of MIL-101(Cr) in all nanocomposites with the absence of any unreacted GO. Scanning electron microscopy images confirmed the presence of near spherical MIL-101(Cr) nanoparticles in the range of 40-80 nm in diameter. MOHC nanofluids containing MIL-101(Cr)/GO in methanol exhibited significant enhancement in the thermal conductivity (by approxi-mately 50%) relative to that of the intrinsic nano MIL-101(Cr) in methanol. The thermal conductivity of base fluid (methanol) was enhanced by about 20 %. The enhancement in the thermal conductivity of nanoMIL-101(Cr) MOHCs due to graphene oxide functionalization is explained using a classical Maxwell model.
Measurement of Thermal Conductivity of Liquids at High Temperature
Schick, V.; Remy, B.; Degiovanni, A.; Demeurie, F.; Meulemans, J.; Lombard, P.
2012-11-01
The goal purchased in this paper is to implement a pulse method to measure the thermal conductivity of liquid silica glass above 1200°C until 1600°C. A heat flux stimulation controlled in energy and in time is generated on the front face of an experimental cell. The temperature rise is measured on the rear face of this cell face by using a fast cooled infrared camera. The choice of the measurement cell geometry is fundamental to be able to estimate at the same time the thermal diffusivity and the specific heat of the liquid by an inverse technique. The parameters estimation problem takes into account the optimization of the cell wall thickness. The theoretical model used for the inversion takes into account the coupled heat transfer modes (conduction, convection and radiation) that can occur during the experiment, particularly the thermal conductive short-cut through metallic lateral walls of the cell and radiative transfer within the semi-transparent and participating medium. First measurements are performed on a cell filled with water at ambient temperature in order to validate the parameters estimation procedure.
The Thermal Electrical Conductivity Probe (TECP) for Phoenix
Zent, Aaron P.; Hecht, Michael H.; Cobos, Doug R.; Campbell, Gaylon S.; Campbell, Colin S.; Cardell, Greg; Foote, Marc C.; Wood, Stephen E.; Mehta, Manish
2009-01-01
The Thermal and Electrical Conductivity Probe (TECP) is a component of the Microscopy, Electrochemistry, and Conductivity Analyzer (MECA) payload on the Phoenix Lander. TECP will measure the temperature, thermal conductivity and volumetric heat capacity of the regolith. It will also detect and quantify the population of mobile H2O molecules in the regolith, if any, throughout the polar summer, by measuring the electrical conductivity of the regolith, as well as the dielectric permittivity. In the vapor phase, TECP is capable of measuring the atmospheric H2O vapor abundance, as well as augment the wind velocity measurements from the meteorology instrumentation. TECP is mounted near the end of the 2.3 m Robotic Arm, and can be placed either in the regolith material or held aloft in the atmosphere. This paper describes the development and calibration of the TECP. In addition, substantial characterization of the instrument has been conducted to identify behavioral characteristics that might affect landed surface operations. The greatest potential issue identified in characterization tests is the extraordinary sensitivity of the TECP to placement. Small gaps alter the contact between the TECP and regolith, complicating data interpretation. Testing with the Phoenix Robotic Arm identified mitigation techniques that will be implemented during flight. A flight model of the instrument was also field tested in the Antarctic Dry Valleys during the 2007-2008 International Polar year. 2
Effective Thermal Conductivity of MOF-5 Powder under a Hydrogen Atmosphere
Directory of Open Access Journals (Sweden)
Hui Wang
2015-11-01
Full Text Available Effective thermal conductivity is an important thermophysical property in the design of metal-organic framework-5 (MOF-5-based hydrogen storage tanks. A modified thermal conductivity model is built by coupling a theoretical model with the grand canonical Monte Carlo simulation (GCMC to predict the effect of the H2 adsorption process on the effective thermal conductivity of a MOF-5 powder bed at pressures ranging from 0.01 MPa to 50 MPa and temperatures ranging from 273.15 K to 368.15 K. Results show that the mean pore diameter of the MOF-5 crystal decreases with an increase in pressure and increases with an increase in temperature. The thermal conductivity of the adsorbed H2 increases with an increased amount of H2 adsorption. The effective thermal conductivity of the MOF-5 crystal is significantly enhanced by the H2 adsorption at high pressure and low temperature. The effective thermal conductivity of the MOF-5 powder bed increases with an increase in pressure and remains nearly unchanged with an increase in temperature. The thermal conductivity of the MOF-5 powder bed increases linearly with the decreased porosity and increased thermal conductivity of the skeleton of the MOF-5 crystal. The variation in the effective thermal conductivities of the MOF-5 crystals and bed mainly results from the thermal conductivities of the gaseous and adsorption phases.
Tunable thermal conductivity in mesoporous silicon by slight porosity change
Seol, Jae Hun; Barth, David S.; Zhu, Jia; Ćoso, Dušan; Hippalgaonkar, Kedar; Lim, Jongwoo; Han, Junkyu; Zhang, Xiang; Majumdar, Arun
2017-08-01
We report the thermal conductivity of photoelectrochemically synthesized mesoporous silicon (MPS), with ˜20-nm diameter pores and 52%-58% porosity. The thermal conductivity of MPS samples with a thickness of a few microns was measured using the three omega (3 ω ) differential technique. We experimentally demonstrated that the thermal conductivity of MPS varies between 3 and 7 W/m K at room temperature and is dependent on the photoelectrochemical etching times used during the MPS synthesis, which induces a slight change in the MPS porosity. Calculations were conducted using the Boltzmann transport equation in the relaxation time approximation, with the results suggesting that the large thermal conductivity reduction in the MPSs was not entirely explained by the pore boundary scattering. Our findings indicate that elastic softening in the mesoporous structure may be responsible for the reduction in the thermal conductivity.
Demystifying umklapp vs normal scattering in lattice thermal conductivity
Maznev, A. A.; Wright, O. B.
2014-11-01
We discuss the textbook presentation of the concept of umklapp vs normal phonon-phonon scattering processes in the context of lattice thermal conductivity. A simplistic picture, in which the "momentum conservation" in a normal process leads to the conservation of the heat flux, is only valid within the single-velocity Debye model of phonon dispersion. Outside this model, the simple "momentum conservation" argument is demonstrably inaccurate and leads to conceptual confusion. Whether or not an individual scattering event changes the direction of the energy flow is determined by the phonon group velocity, which, unlike the quasimomentum, is a uniquely defined quantity independent of the choice of the primitive cell in reciprocal space. Furthermore, the statement that normal processes do not lead to a finite thermal conductivity when umklapp processes are absent is a statistical statement that applies to a phonon distribution rather than to individual scattering events. It is also important to understand that once umklapp processes are present, both normal and umklapp processes contribute to thermal resistance. A nuanced explanation of the subject would help avoid confusion of the student and establish a connection with cutting edge research.
Thermal conductivity calibration for hot wire based dc scanning thermal microscopy
Lefèvre, Stéphane; Volz, Sebastian; Saulnier, Jean-Bernard; Fuentes, Catherine; Trannoy, Nathalie
2003-04-01
Thermal conductivity characterization with nanoscale spatial resolution can be performed by contact probe techniques only. The technique based on a hot anemometer wire probe mounted in an atomic force microscope is now a standard setup. However, no rigorous calibration procedure is provided so far in basic dc mode. While in contact with the sample surface, the electrical current I injected into the probe is controlled so that electrical resistance or the wire temperature is maintained by the Joule effect. The variation in current is assumed to be linearly related to the heat flux lost towards the sample and traditional calibration is carried out by relating the thermal conductivity of a set of samples to the measured current I. We provide analytical and numerical thermal modeling of the tip and sample to estimate the key heat transfer in a conductivity calibration procedure. A simple calibration expression is established that provides thermal conductivity as a function of the probe current or voltage measured. Finally, experimental data allow us to determine the unknown quantities of the parametric form obtained, i.e., the mean tip-sample contact radius and conductance.
Investigation of the Effective Thermal Conductivity in Containment Wall of OPR1000
Energy Technology Data Exchange (ETDEWEB)
Noh, Hyung Gyun [Pohang University, Pohang (Korea, Republic of); Lee, Jong Hwi; Kang, Hie Chan [Kunsan National University, Gunsan (Korea, Republic of)
2016-05-15
Many computational codes used for analyzing pressure of containment was developed such as CAP (Containment Analysis Package). These computational codes consider concrete conductivity instead of thermal conductivity of containment wall which have special geometry as heat sink. For precise analysis, effective thermal conductivity of containment wall has to be measured in individual NPPs. Thermal properties of concrete such as thermal conductivity have been investigated as function of chemical composition and temperature. Generally, containment of OPR1000 is constructed by Prestressed (PS) concrete-a composite material. Containment wall of OPR1000 is made up of steel liner, tendon, rebar and concrete as shown in Figure 1. Role of steel liner protects release of radioactive materials so called leak tightness. The effective thermal conductivity of containment wall in OPR1000 is analyzed by numerical tool (CFD) and compared with thermal conductivity models in composite solids. The effective thermal conductivity of containment wall of OPR1000 is investigated by numerical analysis (CFD). The thermal conductivity of reinforced concrete is 18.6% higher than that of concrete only. Several models were compared with CFD results. Rayleigh-Parallel liner model agrees well with CFD results. Experiment results will be compared with CFD result and models. CFD result was calculated in low steel volume fraction (0.0809) than that of OPR1000 (0.1043). The effective thermal conductivity in OPR1000 has slightly higher than CFD result because of different volume fraction.
3 omega method for specific heat and thermal conductivity measurements
Lü, L; Zhang, D L
2001-01-01
We present a 3 omega method for simultaneously measuring the specific heat and thermal conductivity of a rod- or filament-like specimen using a way similar to a four-probe resistance measurement. The specimen in this method needs to be electrically conductive and with a temperature-dependent resistance, for acting both as a heater to create a temperature fluctuation and as a sensor to measure its thermal response. With this method we have successfully measured the specific heat and thermal conductivity of platinum wire specimens at cryogenic temperatures, and measured those thermal quantities of tiny carbon nanotube bundles some of which are only 10^-9 g in mass.
Polyaniline Conducting Electroactive Polymers Thermal and Environmental Stability Studies
Directory of Open Access Journals (Sweden)
Reza Ansari
2006-01-01
Full Text Available In the current studies, polyaniline (PANi was prepared both chemical and electrochemically in the presence of different bronsted acids from aqueous solutions. The effect of thermal treatment on electrical conductivity, and thermal stability of the PANi conducting polymers were investigated using 4-point probe and TGA techniques respectively. It was found that polymer prepared by CV method is more thermally stable than those prepared by the other electrochemical techniques. In this paper we have also reviewed some fundamental information about synthesis, general properties, diverse applications, thermal and environmental stability of polyaniline conducting polymers.
Lattice thermal conductivity in layered BiCuSeO
Kumar, S.
2016-06-30
We quantify the low lattice thermal conductivity in layered BiCuSeO (the oxide with the highest known figure of merit). It turns out that the scattering of acoustical into optical phonons is strongly enhanced in the material because of the special structure of the phonon dispersion. For example, at room temperature the optical phonons account for an enormous 42% of the lattice thermal conductivity. We also quantify the anisotropy of the lattice thermal conductivity and determine the distribution of the mean free path of the phonons at different temperatures to provide a guide for tuning the thermal properties. © the Owner Societies 2016.
Development of high-thermal-conductivity silicon nitride ceramics
Directory of Open Access Journals (Sweden)
You Zhou
2015-09-01
Full Text Available Silicon nitride (Si3N4 with high thermal conductivity has emerged as one of the most promising substrate materials for the next-generation power devices. This paper gives an overview on recent developments in preparing high-thermal-conductivity Si3N4 by a sintering of reaction-bonded silicon nitride (SRBSN method. Due to the reduction of lattice oxygen content, the SRBSN ceramics could attain substantially higher thermal conductivities than the Si3N4 ceramics prepared by the conventional gas-pressure sintering of silicon nitride (SSN method. Thermal conductivity could further be improved through increasing the β/α phase ratio during nitridation and enhancing grain growth during post-sintering. Studies on fracture resistance behaviors of the SRBSN ceramics revealed that they possessed high fracture toughness and exhibited obvious R-curve behaviors. Using the SRBSN method, a Si3N4 with a record-high thermal conductivity of 177 Wm−1K−1 and a fracture toughness of 11.2 MPa m1/2 was developed. Studies on the influences of two typical metallic impurity elements, Fe and Al, on thermal conductivities of the SRBSN ceramics revealed that the tolerable content limits for the two impurities were different. While 1 wt% of impurity Fe hardly degraded thermal conductivity, only 0.01 wt% of Al caused large decrease in thermal conductivity.
Role of Chain Morphology and Stiffness in Thermal Conductivity of Amorphous Polymers.
Zhang, Teng; Luo, Tengfei
2016-02-04
Designing thermally conductive polymer is of scientific interest and practical importance for applications like thermal interface materials, electronics packing, and plastic heat exchangers. In this work, we study the fundamental relationship between the molecular morphology and thermal conductivity in bulk amorphous polymers. We use polyethylene as a model system and performed systematic parametric study in molecular dynamics simulations. We find that the thermal conductivity is a strong function of the radius of gyration of the molecular chains, which is further correlated to persistence length, an intrinsic property of the molecule that characterizes molecular stiffness. Larger persistence length can lead to more extended chain morphology and thus higher thermal conductivity. Further thermal conductivity decomposition analysis shows that thermal transport through covalent bonds dominates the effective thermal conductivity over other contributions from nonbonded interactions (van der Waals) and translation of molecules disregarding the morphology. As a result, the more extended chains due to larger persistence length provide longer spatial paths for heat to transfer efficiently and thus lead to higher thermal conductivity. In addition, rigid rod-like polymers with very large persistence length tend to spontaneously crystallize and form orientated chains, leading to a thermal conductivity increase by more than 1 order of magnitude. Our results will provide important insights into the design of thermally conductive amorphous polymers.
Thermal conductivities of minor actinide oxides for advanced fuel
Energy Technology Data Exchange (ETDEWEB)
Tsuyoshi Nishi; Akinori Itoh; Masahide Takano; Mitsuo Akabori; Yasuo Arai; Kazuo Minato [Nuclear Science and Engineering Directorate, Japan Atomic Energy Agency, Tokai-mura, Ibaraki 319-1195 (Japan)
2008-07-01
The thermal diffusivities of americium oxide and neptunium dioxide were determined by a laser flash method. It was found that the thermal diffusivities of AmO{sub 2-x} and NpO{sub 2} decreased with increasing temperature. It was also found that the decrease in O/Am ratio during the thermal diffusivity measurements under vacuum resulted in a slight decrease in thermal diffusivity of AmO{sub 2-x}. The thermal conductivities of AmO{sub 2-x} and NpO{sub 2} were evaluated from the measured thermal diffusivities, heat capacities and bulk densities. The thermal conductivity of AmO{sub 2-x} was smaller than those of the literature values of UO{sub 2} and PuO{sub 2}. On the other hand, the thermal conductivity of NpO{sub 2} from 873 to 1473 K lay between those of UO{sub 2} and PuO{sub 2}. The thermal conductivities of AmO{sub 2-x} and NpO{sub 2} decreased with increasing temperature in the temperature range investigated. This temperature dependence of thermal conductivities showed a similar tendency as those of UO{sub 2}, PuO{sub 2} and (U{sub 0.8}Pu{sub 0.2})O{sub 2-x}. (authors)
Therma1 Conductivity and Durability of Advanced Thermal Barrier Coatings
Zhu, Dong-Ming; Miller, Robert A.
2003-01-01
Thermal barrier coatings (TBCs) will play a crucial role in advanced gas turbine engines because of their ability to further increase engine operating temperature and reduce cooling, thus helping to achieve engine emission and efficiency goals. Future TBCs must be designed with increased phase stability, lower thermal conductivity, and improved sintering and thermal stress resistance in order to effectively protect engine hot-section components. Advanced low conductivity TBCs are being developed at NASA by incorporating multi-component oxide dopants into zirconia-yttria or hafnia-yttria to promote the formation of thermodynamically stable defect clusters within the coating structures. This presentation will primarily focus on thermal conductivity and durability of the novel defect cluster thermal barrier coatings for turbine airfoil and combustor applications, determined by a unique CO2 laser heat-flux approach. The laser heat-flux testing approach emphasizes the real-time monitoring and assessment of the coating thermal conductivity under simulated engine temperature and thermal gradient conditions. The conductivity increase due to coating sintering (and/or phase change) and the conductivity decrease due to coating delamination have been determined under steady-state, cyclic, uniform or non-uniform heat-flux conditions. The coating radiation flux resistance has been evaluated by varying coating thermal gradients, and also by using a laser-heated radiative-flux source. Advanced multi-component TBC systems have been shown to have significantly reduced thermal conductivity and improved high temperature stability due to the nano-sized, low mobility defect clusters associated with the paired rare earth dopant additions. The effect of oxide defect cluster dopants on coating thermal conductivity, thermal stability and furnace cyclic durability will also be discussed. The current low conductivity TBC systems have demonstrated long-term cyclic durability at very high
A multi-scale micromechanical investigation on thermal conductivity of cement-based composites
Liu, Jiahan; Xu, Shilang; Zeng, Qiang
2017-01-01
Cement-based composites (CBCs) are one of the most widely used materials in construction. An appealing characterization of thermal conductivity of CBCs plays an essential role to evaluate the energy consumption in buildings and to facilitate the development of novel thermal insulation materials. Based on Eshelby equivalent inclusion principle and multi-scale methodology, this paper attempted to present a generalized multi-scale micromechanical model in terms of thermal performance of the CBCs, which covers some classic models for thermal conductivity estimation. A Mori-Tanaka homogenization method was applied to investigate the thermal conductivity of the CBCs of different compounds, water-to-cement ratios and curing ages. In addition, saturation degree factor was considered. The results of this model are in good agreement with the experimental value, showing that the multi-scale model developed in this paper is able to evaluate the thermal conductivity of the CBCs in different conditions.
Thermal conductivity of silicon nanowires embedded on thermoelectric platforms
Choi, JinYong; Cho, Kyoungah; Yoon, Dae Sung; Kim, Sangsig
2016-10-01
In this study, we propose a simple method for obtaining the thermal conductivity of silicon nanowires (SiNWs) embedded on a thermoelectric platform. The approximation of the heat flux in SiNWs with temperature differences enables the determination of thermal conductivity. Using this method, the thermal conductivities of our n- and p-type SiNWs are found to be 18.06 ± 0.12 and 20.29 ± 0.77 W m-1 · K-1, respectively. The atomic weight of arsenic ions in the n-type SiNWs is responsible for a lower thermal conductivity than that of boron ions in the p-type SiNWs. Our results demonstrate that this simple method is capable of measuring the thermal conductivity of thermoelectric nanomaterials embedded on thermoelectric devices.
Thermal conductance of graphene/hexagonal boron nitride heterostructures
Lu, Simon; McGaughey, Alan J. H.
2017-03-01
The lattice-based scattering boundary method is applied to compute the phonon mode-resolved transmission coefficients and thermal conductances of in-plane heterostructures built from graphene and hexagonal boron nitride (hBN). The thermal conductance of all structures is dominated by acoustic phonon modes near the Brillouin zone center that have high group velocity, population, and transmission coefficient. Out-of-plane modes make their most significant contributions at low frequencies, whereas in-plane modes contribute across the frequency spectrum. Finite-length superlattice junctions between graphene and hBN leads have a lower thermal conductance than comparable junctions between two graphene leads due to lack of transmission in the hBN phonon bandgap. The thermal conductances of bilayer systems differ by less than 10% from their single-layer counterparts on a per area basis, in contrast to the strong thermal conductivity reduction when moving from single- to multi-layer graphene.
Manipulating Steady Heat Conduction by Sensu-shaped Thermal Metamaterials
Han, Tiancheng; Liu, Dan; Gao, Dongliang; Li, Baowen; Thong, John T L; Qiu, Cheng-Wei
2014-01-01
The ability to design the control of heat flow has innumerable benefits in the design of electronic systems such as thermoelectric energy harvesters, solid-state lighting, and thermal imagers, where the thermal design plays a key role in performance and device reliability. However, to realize one advanced control function of thermal flux, one needs to design one sophisticated, multilayered and inhomogeneous thermal structure with different composition/shape at different regions of one device. In this work, we employ one identical sensu-unit with facile natural composition to experimentally realize a new class of thermal metamaterials for controlling thermal conduction (e.g., thermal concentrator, focusing/resolving, uniform heating), only resorting to positioning and locating the same unit element of sensu-shape structure. The thermal metamaterial unit and the proper arrangement of multiple identical units are capable of transferring, redistributing and managing thermal energy in a versatile fashion. It is al...
Low thermal conductivity of graphyne nanotubes from molecular dynamics study
Hu, Ming; Jing, Yuhang; Zhang, Xiaoliang
2015-04-01
It is well known that carbon nanotubes (CNTs) possess ultrahigh thermal conductivity that is comparable to bulk diamond. However, no research has studied the possible low thermal conductivity of different CNTs so far. By performing nonequilibrium molecular dynamic simulations, we reveal that the perfect graphyne nanotube (GNT) exhibits an unprecedentedly low thermal conductivity (below 10 W/mK at room temperature), which is generally two orders of magnitude lower than that of ordinary CNTs and even lower than the values reported for defected, doped, and chemically functionalized CNTs. By performing phonon polarization and spectral energy density analysis, we observe that the ultralow thermal conductivity stems from the unique atomic structure of the GNT, consisting of the weak acetylenic linkage (s p C-C bonds) and the strong hexagonal ring (s p2 C-C bonds), which results in a large vibrational mismatch between these two components, and thus induces significantly inefficient heat transfer. Moreover, the thermal transport in GNT with a large number of acetylenic linkages is dominated by the low frequency longitudinal modes in the linkage. Such strong confinement of the low frequency thermal energy results in the extremely low thermal conductivity due to the flattened phonon dispersion curves (low phonon group velocities). The exploration of the abnormal thermal transport of GNTs paves the way for design and application of the relevant devices that could benefit from the ultralow thermal conductivity, such as thermoelectrics for energy conversion.
Thermal and electrical conductivity of iron at Earth's core conditions.
Pozzo, Monica; Davies, Chris; Gubbins, David; Alfè, Dario
2012-04-11
The Earth acts as a gigantic heat engine driven by the decay of radiogenic isotopes and slow cooling, which gives rise to plate tectonics, volcanoes and mountain building. Another key product is the geomagnetic field, generated in the liquid iron core by a dynamo running on heat released by cooling and freezing (as the solid inner core grows), and on chemical convection (due to light elements expelled from the liquid on freezing). The power supplied to the geodynamo, measured by the heat flux across the core-mantle boundary (CMB), places constraints on Earth's evolution. Estimates of CMB heat flux depend on properties of iron mixtures under the extreme pressure and temperature conditions in the core, most critically on the thermal and electrical conductivities. These quantities remain poorly known because of inherent experimental and theoretical difficulties. Here we use density functional theory to compute these conductivities in liquid iron mixtures at core conditions from first principles--unlike previous estimates, which relied on extrapolations. The mixtures of iron, oxygen, sulphur and silicon are taken from earlier work and fit the seismologically determined core density and inner-core boundary density jump. We find both conductivities to be two to three times higher than estimates in current use. The changes are so large that core thermal histories and power requirements need to be reassessed. New estimates indicate that the adiabatic heat flux is 15 to 16 terawatts at the CMB, higher than present estimates of CMB heat flux based on mantle convection; the top of the core must be thermally stratified and any convection in the upper core must be driven by chemical convection against the adverse thermal buoyancy or lateral variations in CMB heat flow. Power for the geodynamo is greatly restricted, and future models of mantle evolution will need to incorporate a high CMB heat flux and explain the recent formation of the inner core.
Investigations Regarding the Thermal Conductivity of Straw
2010-01-01
The reduction of buildings heat losses and pollutants emissions is a worldwide priority. It’s intending to reduce the specific final energy consumption under limit of 120...150 kWh/m2.yr and even under 15...45 kWh/m2.yr, foreseen in 2020 for the passive houses, which is necessary for a sustainable development and for allowing to became profitable the use of unconventional energies [1]. These values can be achieved through the use of thermal insulations, for protecting the constructions fund a...
Thermal conductivity of silica nanoparticle powder: Measurement and theoretical analysis
Huang, Congliang; Lin, Zizhen; Feng, Yanhui; Zhang, Xinxin; Wang, Ge
2015-12-01
The hot-wire method was applied to experimentally determine the thermal conductivity (TC) of a silica nanoparticle powder. A fitting model was further employed to analyze the experimental results and to predict the TC over a wider porosity scale. Results show that the effective TC of the silica-nanoparticle powder can be less than that of free air because of the low TC of both the silica nanoparticles and the air confined in the pore spaces; the relative contribution of the nanoparticle TC, the confined air TC, and the radiation heat transfer coefficient to the effective TC will significantly affect at which porosity the extreme value of the effective TC occurs; the porosity obtained when the contribution to the effective TC of the confined air equals that of the nanoparticles is the most favorable for constructing thermal insulation materials.
Khadem, Masoud H; Wemhoff, Aaron P
2013-02-28
Non-equilibrium molecular dynamics (NEMD) simulations are used to investigate the thermal conductivity of herringbone graphite nanofibers (GNFs) at room temperature by breaking down the axial and transverse conductivity values into intralayer and interlayer components. The optimized Tersoff potential is used to account for intralayer carbon-carbon interactions while the Lennard-Jones potential is used to model the interlayer carbon-carbon interactions. The intralayer thermal conductivity of the graphene layers near room temperature is calculated for different crease angles and number of layers using NEMD with a constant applied heat flux. The edge effect on a layer's thermal conductivity is investigated by computing the thermal conductivity values in both zigzag and armchair directions of the heat flow. The interlayer thermal conductivity is also predicted by imposing hot and cold Nosé-Hoover thermostats on two layers. The limiting case of a 90° crease angle is used to compare the results with those of single-layer graphene and few-layer graphene. The axial and transverse thermal conductivities are then calculated using standard trigonometric conversions of the calculated intralayer and interlayer thermal conductivities, along with calculations of few-layer graphene without a crease. The results show a large influence of the crease angle on the intralayer thermal conductivity, and the saturation of thermal conductivity occurs when number of layers is more than three. The axial thermal conductivity, transverse thermal conductivity in the crease direction, and transverse thermal conductivity normal to the crease for the case of a five-layer herringbone GNF with a 45° crease angle are calculated to be 27 W∕m K, 263 W∕m K, and 1500 W∕m K, respectively, where the axial thermal conductivity is in good agreement with experimental measurements.
Nanostructure-thermal conductivity relationships in protic ionic liquids.
Murphy, Thomas; Varela, Luis M; Webber, Grant B; Warr, Gregory G; Atkin, Rob
2014-10-16
The thermal conductivities of nine protic ionic liquids (ILs) have been investigated between 293 and 340 K. Within this range, the thermal conductivities are between 0.18 and 0.30 W · m(-1) · K(-1). These values are higher than those typically associated with oils and aprotic ILs, but lower than those of strongly hydrogen bonding solvents like water. Weak linear decreases in thermal conductivity with temperature are noted, with the exception of ethanolammonium nitrate (EtAN) where the thermal conductivity increases with temperature. The dependence of thermal conductivity on IL type is analyzed with use of the Bahe-Varela pseudolattice theory. This theory treats the bulk IL as an array of ordered domains with intervening domains of uncorrelated structure which enable and provide barriers to heat propagation (respectively) via allowed vibrational modes. For the protic ILs investigated, thermal conductivity depends strongly on the IL cation alkyl chain length. This is because the cation alkyl chain controls the dimensions of the IL bulk nanostructure, which consists of charged (ordered domains) and uncharged regions (disordered domains). As the cation alkyl chain controls the dimensions of the disordered domains, it thus limits the thermal conductivity. To test the generality of this interpretation, the thermal conductivities of propylammonium nitrate (PAN) and PAN-octanol mixtures were examined; water selectively swells the PAN charged domain, while octanol swells the uncharged regions. Up to a certain concentration, adding water increases thermal conduction and octanol decreases it, as expected. However, at high solute concentrations the IL nanostructure is broken. When additional solvent is added above this concentration the rate of change in thermal conductivity is greatly reduced. This is because, in the absence of nanostructure, the added solvent only serves to dilute the salt solution.
Effects of carbon content and solidification rate on thermal conductivity of grey cast iron
Institute of Scientific and Technical Information of China (English)
无
2007-01-01
The thermal conductivity or diffusivity of pearlitic grey irons with various carbon contents is investigated by the laser flash method. The materials are cast in controlled thermal environments and produced in three dissimilar cooling rates. The cooling rate together with the carbon content largely influence the thermal conductivity of grey iron. Linear relationships exist between the thermal conductivity and the carbon content, the carbon equivalent and the fraction of former primary solidified austenite transformed into pearlite. The work shows that optimal thermal transport properties are obtained at medium cooling rates. Equations describing the thermal conductivity of pearlite,solidified as pre-eutectic austenite, and the eutectic of grey iron are derived. The thermal conductivity of pearlitic grey iron is modeled at both room temperature and elevated temperature with good accuracy.
Effects of Carbon Content and Solidification Rate on the Thermal Conductivity of Grey Cast Iron
Institute of Scientific and Technical Information of China (English)
Daniel Holmgren; Attila Diószegi; Ingvar L.Svensson
2008-01-01
The thermal conductivity/diffusivity of pearlitic grey irons with various carbon contents was investi- gated by the laser flash method. The materials were cast in controlled thermal environments producing three dissimilar cooling rates. The cooling rates together with the carbon content largely influence the thermal conductivity of grey iron. Linear relationships exist between the thermal conductivity and the carbon content, the carbon equivalent, and the fraction of the former primary solidified austenite transformed into pearlite. The results show that the optimal thermal transport properties are obtained at medium cooling rates. Equa- tions are given for the thermal conductivity of pearlite, solidified as pre-eutectic austenite, and the eutectic of grey iron. The thermal conductivity of pearlitic grey iron is modelled at both room temperature and elevated temperatures with good accuracy.
Effects of carbon content and solidification rate on thermal conductivity of grey cast iron
Directory of Open Access Journals (Sweden)
Daniel Holmgren
2007-08-01
Full Text Available The thermal conductivity or diffusivity of pearlitic grey irons with various carbon contents is investigated by the laser flash method. The materials are cast in controlled thermal environments and produced in three dissimilar cooling rates. The cooling rate together with the carbon content largely influence the thermal conductivity of grey iron. Linear relationships exist between the thermal conductivity and the carbon content, the carbon equivalent and the fraction of former primary solidified austenite transformed into pearlite. The work shows that optimal thermal transport properties are obtained at medium cooling rates. Equations describing the thermal conductivity of pearlite,solidified as pre-eutectic austenite, and the eutectic of grey iron are derived. The thermal conductivity of pearlitic grey iron is modeled at both room temperature and elevated temperature with good accuracy.
First-principles study of lattice thermal conductivity of Td-WTe2
Liu, Gang; Sun, Hong Yi; Zhou, Jian; Li, Qing Fang; Wan, Xian-Gang
2016-03-01
The structural and thermal properties of bulk Td-WTe2 have been studied by using first-principles calculations based on the simple Klemens model and an iterative self-consistent method. Both methods show that lattice thermal conductivity is anisotropic, with the highest value in the (001) plane, and lowest one along the c-axis at 300 K. The calculated average thermal conductivity of WTe2 is in agreement with the experimental measurement. The size dependent thermal conductivity shows that nanostructuring of WTe2 can possibly further decrease the lattice thermal conductivity, which can improve the thermoelectric efficiency. Such extremely low thermal conductivity, even much lower than WSe2, makes WTe2 having many potential applications in thermal insulation and thermoelectric materials.
Role of Brownian Motion Hydrodynamics on Nanofluid Thermal Conductivity
Energy Technology Data Exchange (ETDEWEB)
W Evans, J Fish, P Keblinski
2005-11-14
We use a simple kinetic theory based analysis of heat flow in fluid suspensions of solid nanoparticles (nanofluids) to demonstrate that the hydrodynamics effects associated with Brownian motion have a minor effect on the thermal conductivity of the nanofluid. Our conjecture is supported by the results of molecular dynamics simulations of heat flow in a model nanofluid with well-dispersed particles. Our findings are consistent with the predictions of the effective medium theory as well as with recent experimental results on well dispersed metal nanoparticle suspensions.
Analysis of thermal conductivity in tree-like branched networks
Institute of Scientific and Technical Information of China (English)
Kou Jian-Long; Lu Hang-Jun; Wu Feng-Min; Xu You-Sheng
2009-01-01
Asymmetric tree-like branched networks are explored by geometric algorithms.Based on the network,an analysis of the thermal conductivity is presented.The relationship between effective thermal conductivity and geometric structures is obtained by using the thermal-electrical analogy technique.In all studied cases,a clear behaviour is observed,where angle(δ,θ)among parent branching extended lines,branches and parameter of the geometric structures have stronger effects on the effective thermal conductivity.When the angle δ is fixed,the optical diameter ratio β* is dependent on angle θ.Moreover,γ and m are not related to β*.The longer the branch is,the smaller the effective thermal conductivity will be.It is also found that when the angle θ＜δ/2,the higher the iteration m is,the lower the thermal conductivity will be and it tends to zero,otherwise,it is bigger than zero.When the diameter ratio β1＜0.707 and angle δ is bigger,the optimal k of the perfect ratio increases with the increase of the angle δ;when β1＞0.707,the optimal k decreases.In addition,the effective thermal conductivity is always less than that of single channel material.The present results also show that the effective thermal conductivity of the asymmetric tree-like branched networks does not obey Murray's law.
Nanoscale Electromechanics To Measure Thermal Conductivity, Expansion, and Interfacial Losses.
Mathew, John P; Patel, Raj; Borah, Abhinandan; Maliakkal, Carina B; Abhilash, T S; Deshmukh, Mandar M
2015-11-11
We study the effect of localized Joule heating on the mechanical properties of doubly clamped nanowires under tensile stress. Local heating results in systematic variation of the resonant frequency; these frequency changes result from thermal stresses that depend on temperature dependent thermal conductivity and expansion coefficient. The change in sign of the linear expansion coefficient of InAs is reflected in the resonant response of the system near a bath temperature of 20 K. Using finite element simulations to model the experimentally observed frequency shifts, we show that the thermal conductivity of a nanowire can be approximated in the 10-60 K temperature range by the empirical form κ = bT W/mK, where the value of b for a nanowire was found to be b = 0.035 W/mK(2), significantly lower than bulk values. Also, local heating allows us to independently vary the temperature of the nanowire relative to the clamping points pinned to the bath temperature. We suggest a loss mechanism (dissipation ~10(-4)-10(-5)) originating from the interfacial clamping losses between the metal and the semiconductor nanostructure.
Thermal conductivity of halite using a pulsed laser
Energy Technology Data Exchange (ETDEWEB)
Smith, D.D.
1976-12-13
A feasibility study of the experimental determination of thermal conductivities of salts (NaCl) and a steel casing material using a pulsed laser technique are presented. Optically transparent materials such as salt were effectively coated with an opaque layer of aluminum or silver to satisfy test boundary conditions. Thermal conductivities for the three specimens were obtained from the thermal diffusivity, heat capacity and density relationship. Based on measurements from room temperature to 923/sup 0/K, single crystal halite yielded values ranging from 6.5 to 1.5 W/m-K versus 5.5 to 1.2 W/m-K for Avery Island Bed Salt. AISI 106-Grade B steel gave values of 46 to 29 W/m-K. While these measurements may be no better than +- 10 percent, it is possible with appropriate equipment and technique to generate data of engineering quality, +- 5 percent error, provided adequate test specimens can be fabricated. Attributes of this technique include the generation of data very quickly which is more applicable to testing large numbers of specimens relative to steady-state methods. The use of penny-sized specimens can be a problem from the fabrication requirement, especially for friable and anisotropic geological materials. The quality of the data rests on the adherence of the experimental design to the mathematical model.
Method for estimating the lattice thermal conductivity of metallic alloys
Energy Technology Data Exchange (ETDEWEB)
Yarbrough, D.W.; Williams, R.K.
1978-08-01
A method is described for calculating the lattice thermal conductivity of alloys as a function of temperature and composition for temperatures above theta/sub D//2 using readily available information about the atomic species present in the alloy. The calculation takes into account phonon interactions with point defects, electrons and other phonons. Comparisons between experimental thermal conductivities (resistivities) and calculated values are discussed for binary alloys of semiconductors, alkali halides and metals. A discussion of the theoretical background is followed by sufficient numerical work to facilitate the calculation of lattice thermal conductivity of an alloy for which no conductivity data exist.
Thermally Conductive Tape Based on Carbon Nanotube Arrays
Kashani, Ali
2011-01-01
To increase contact conductance between two mating surfaces, a conductive tape has been developed by growing dense arrays of carbon nanotubes (CNTs, graphite layers folded into cylinders) on both sides of a thermally conductive metallic foil. When the two mating surfaces are brought into contact with the conductive tape in between, the CNT arrays will adhere to the mating surface. The van der Waals force between the contacting tubes and the mating surface provides adhesion between the two mating surfaces. Even though the thermal contact conductance of a single tube-to-tube contact is small, the tremendous amount of CNTs on the surface leads to a very large overall contact conductance. Interface contact thermal resistance rises from the microroughness and the macroscopic non-planar quality of mating surfaces. When two surfaces come into contact with each other, the actual contact area may be much less than the total area of the surfaces. The real area of contact depends on the load, the surface roughness, and the elastic and inelastic properties of the surface. This issue is even more important at cryogenic temperatures, where materials become hard and brittle and vacuum is used, which prevents any gas conduction through the interstitial region. A typical approach to increase thermal contact conductance is to use thermally conducting epoxies or greases, which are not always compatible with vacuum conditions. In addition, the thermal conductivities of these compounds are often relatively low. The CNTs used in this approach can be metallic or semiconducting, depending on the folding angle and diameter. The electrical resistivity of multiwalled carbon nanotubes (MWCNTs) has been reported. MWCNTs can pass a current density and remain stable at high temperatures in air. The thermal conductivity of a MWCNT at room temperature is measured to be approximately 3,000 W/m-K, which is much larger than that of diamond. At room temperature, the thermal conductance of a 0.3 sq cm
Thermal conductivity and interfacial conductance of AlN particle reinforced metal matrix composites
Kida, M.; Weber, L.; Monachon, C.; Mortensen, A.
2011-03-01
Aluminum nitride (AlN) particle reinforced metal-matrix-composites produced by pressure infiltration are characterized in terms of their thermal conductivity. The composites are designed to cover a wide range of phase contrast between the dispersed particles and the matrix; this is achieved by changing the matrix conductivity using Cu, Al, Sn, and Pb as the matrix. The interface thermal conductance (hc) between AlN and the matrix metals is determined by varying the size of the AlN particles using the Hasselman-Johnson approach and the differential effective medium (DEM) model to calculate hc from measured composite conductivity values. In addition, hc is measured directly at the AlN/Al interface using the transient thermoreflectance (TTR) method on thin aluminum layers deposited on flat AlN substrates to find good agreement with the value derived directly from Al/AlN composites of variable particle size and thus confirm the approach used here to measure hc. Data from the study show that hc at AlN-metal interfaces increases with the metal/AlN Debye temperature ratio; however, the increase is much less than predicted by currently accepted models.
Thermal and tensile strength testing of thermally-conductive adhesives and carbon foam
Chertok, M.; Fu, M.; Irving, M.; Neher, C.; Shi, M.; Tolfa, K.; Tripathi, M.; Vinson, Y.; Wang, R.; Zheng, G.
2017-01-01
Future collider detectors, including silicon tracking detectors planned for the High Luminosity LHC, will require components and mechanical structures providing unprecedented strength-to-mass ratios, thermal conductivity, and radiation tolerance. This paper studies carbon foam used in conjunction with thermally conductive epoxy and thermally conductive tape for such applications. Thermal performance and tensile strength measurements of aluminum-carbon foam-adhesive stacks are reported, along with initial radiation damage test results.
Sen Lu; Tusheng Ren; Yili Lu; Ping Meng; Jinsong Zhang
2017-01-01
The thermal conductivity of dry soils is related closely to air pressure and the contact areas between solid particles. In this study, the thermal conductivity of two-phase soil systems was determined under reduced and increased air pressures. The thermal separation of soil particles, i.e., the characteristic dimension of the pore space (d), was then estimated based on the relationship between soil thermal conductivity and air pressure. Results showed that under both reduced and increased air...
Liang, Xin M; Sekar, Praveen K; Zhao, Gang; Zhou, Xiaoming; Shu, Zhiquan; Huang, Zhongping; Ding, Weiping; Zhang, Qingchuan; Gao, Dayong
2015-05-20
An improved thermal-needle approach for accurate and fast measurement of thermal conductivity of aqueous and soft biomaterials was developed using microfabricated thermal conductivity sensors. This microscopic measuring device was comprehensively characterized at temperatures from 0 °C to 40 °C. Despite the previous belief, system calibration constant was observed to be highly temperature-dependent. Dynamic thermal conductivity response during cooling (40 °C to -40 °C) was observed using the miniaturized single tip sensor for various concentrations of CPAs, i.e., glycerol, ethylene glycol and dimethyl sulfoxide. Chicken breast, chicken skin, porcine limb, and bovine liver were assayed to investigate the effect of anatomical heterogeneity on thermal conductivity using the arrayed multi-tip sensor at 20 °C. Experimental results revealed distinctive differences in localized thermal conductivity, which suggests the use of approximated or constant property values is expected to bring about results with largely inflated uncertainties when investigating bio-heat transfer mechanisms and/or performing sophisticated thermal modeling with complex biological tissues. Overall, the presented micro thermal sensor with automated data analysis algorithm is a promising approach for direct thermal conductivity measurement of aqueous solutions and soft biomaterials and is of great value to cryopreservation of tissues, hyperthermia or cryogenic, and other thermal-based clinical diagnostics and treatments.
Effective Thermal Conductivity Analysis of Xonotlite-aerogel Composite Insulation Material
Institute of Scientific and Technical Information of China (English)
Gaosheng WEI; Xinxin ZHANG; Fan YU
2009-01-01
A 3-dimensional unit cell model is developed for analyzing effective thermal conductivity of xonotlite-aerogel composite insulation material based on its microstructure features. Effective thermal conductivity comparisons between xonotlite-type calcium silicate and aerogel as well as xonotlite-aerogei composite insulation material are presented. It is shown that the density of xonotlite-type calcium silicate is the key factor affecting the effective thermal conductivity of xonotlite-aerogel composite insulation material, and the density of aerogel has tittle in-fluence. The effective thermal conductivity can be lowered greatly by composite of the two materials at an ele-vated temperature.
Choi, David; Poudel, Nirakar; Cronin, Stephen B.; Shi, Li
2017-02-01
Electrostatic force microscopy and scanning thermal microscopy are employed to investigate the electric transport and localized heating around defects introduced during transfer of graphene grown by chemical vapor deposition to an oxidized Si substrate. Numerical and analytical models are developed to explain the results based on the reported basal-plane thermal conductivity, κ, and interfacial thermal conductance, G, of graphene and to investigate their effects on the peak temperature. Irrespective of the κ values, increasing G beyond 4 × 107 W m-2 K-1 can reduce the peak temperature effectively for graphene devices made on sub-10 nm thick gate dielectric, but not for the measured device made on 300-nm-thick oxide dielectric, which yields a cross-plane thermal conductance (Gox) much smaller than the typical G of graphene. In contrast, for typical G values reported for graphene, increasing κ from 300 W m-1 K-1 toward 3000 W m-1 K-1 is effective in reducing the hot spot temperature for the 300-nm-thick oxide devices but not for the sub-10 nm gate dielectric case, because the heat spreading length (l) can be appreciably increased relative to the micron-scale localized heat generation spot size (r0) only when the oxide layer is sufficiently thick. As such, enhancement of κ increases the vertical heat transfer area above the gate dielectric only for the thick oxide case. In all cases considered, the hot spot temperature is sensitive to varying G and κ only when the G/Gox ratio and r0/l ratio are below about 5, respectively.
Investigation of the Thermal Conductance of Selected Opal Structures
Lamberton, , Jr.; Tritt, Terry M.; Zakhidov, A.; Baughmann, R.; Khayrullin, I.
1999-11-01
In relation to thermoelectrics, recently some attention has come to opal structures.^1 The structure of the SiO2 opals is hoped to be useful in lowering thermal conductivity when this structure is infiltrated with traditional thermoelectric materials, such as Bi or Bi_2Te_3. Preliminary measurements show that, by infiltration, it may be possible to increase the thermoelectric figure of merit by improving the ratio of electrical conductivity to thermal conductivity.^2 We have built a new steady state thermal conductivity apparatus for measuring thermal conductivity of samples between 10K and 350K. With this new system the thermal properties of the opal systems and the effects of infiltration will be investigated. Data from the thermal conductivity and heat capacity measurements will be presented and discussed, along with a comparison of thermal conductivity obtained with the laser flash method. 1.) A. Zakhidov et al., Science , 282, 897 (1998) 2.) R. Baughman, A. Zakhidov, et.al, Proc. of ICT '98, IEEE Press, p 288 (1998)
High and low thermal conductivity of amorphous macromolecules
Xie, Xu; Yang, Kexin; Li, Dongyao; Tsai, Tsung-Han; Shin, Jungwoo; Braun, Paul V.; Cahill, David G.
2017-01-01
We measure the thermal conductivity, heat capacity and sound velocity of thin films of five polymers, nine polymer salts, and four caged molecules to advance the fundamental understanding of the lower and upper limits to heat conduction in amorphous macromolecules. The thermal conductivities vary by more than one order of magnitude, from 0.06 W m-1K-1 for [6,6]-phenyl-C71-butyric acid methyl ester to 0.67 W m-1K-1 for poly(vinylphosphonic acid calcium salt). Minimum thermal conductivity calculated from the measured sound velocity and effective atomic density is in good agreement with the thermal conductivity of macromolecules with various molecular structures and intermolecular bonding strength.
Measurement of in-plane thermal conductivity in polymer films
Wei, Qingshuo; Uehara, Chinatsu; Mukaida, Masakazu; Kirihara, Kazuhiro; Ishida, Takao
2016-04-01
Measuring the in-plane thermal conductivity of organic thermoelectric materials is challenging but is critically important. Here, a method to study the in-plane thermal conductivity of free-standing films (via the use of commercial equipment) based on temperature wave analysis is explored in depth. This subject method required a free-standing thin film with a thickness larger than 10 μm and an area larger than 1 cm2, which are not difficult to obtain for most solution-processable organic thermoelectric materials. We evaluated thermal conductivities and anisotropic ratios for various types of samples including insulating polymers, undoped semiconducting polymers, doped conducting polymers, and one-dimensional carbon fiber bulky papers. This approach facilitated a rapid screening of in-plane thermal conductivities for various organic thermoelectric materials.
Measurement of in-plane thermal conductivity in polymer films
Directory of Open Access Journals (Sweden)
Qingshuo Wei
2016-04-01
Full Text Available Measuring the in-plane thermal conductivity of organic thermoelectric materials is challenging but is critically important. Here, a method to study the in-plane thermal conductivity of free-standing films (via the use of commercial equipment based on temperature wave analysis is explored in depth. This subject method required a free-standing thin film with a thickness larger than 10 μm and an area larger than 1 cm2, which are not difficult to obtain for most solution-processable organic thermoelectric materials. We evaluated thermal conductivities and anisotropic ratios for various types of samples including insulating polymers, undoped semiconducting polymers, doped conducting polymers, and one-dimensional carbon fiber bulky papers. This approach facilitated a rapid screening of in-plane thermal conductivities for various organic thermoelectric materials.
Energy Technology Data Exchange (ETDEWEB)
Li, Dongsheng; Sun, Xin; Khaleel, Mohammad A.
2011-09-28
This study evaluated different upscaling methods to predict thermal conductivity in loaded nuclear waste form, a heterogeneous material system. The efficiency and accuracy of these methods were compared. Thermal conductivity in loaded nuclear waste form is an important property specific to scientific researchers, in waste form Integrated performance and safety code (IPSC). The effective thermal conductivity obtained from microstructure information and local thermal conductivity of different components is critical in predicting the life and performance of waste form during storage. How the heat generated during storage is directly related to thermal conductivity, which in turn determining the mechanical deformation behavior, corrosion resistance and aging performance. Several methods, including the Taylor model, Sachs model, self-consistent model, and statistical upscaling models were developed and implemented. Due to the absence of experimental data, prediction results from finite element method (FEM) were used as reference to determine the accuracy of different upscaling models. Micrographs from different loading of nuclear waste were used in the prediction of thermal conductivity. Prediction results demonstrated that in term of efficiency, boundary models (Taylor and Sachs model) are better than self consistent model, statistical upscaling method and FEM. Balancing the computation resource and accuracy, statistical upscaling is a computational efficient method in predicting effective thermal conductivity for nuclear waste form.
Manipulating Steady Heat Conduction by Sensu-shaped Thermal Metamaterials
Han, Tiancheng; Bai, Xue; Liu, Dan; Gao, Dongliang; Li, Baowen; Thong, John T. L.; Qiu, Cheng-Wei
2015-01-01
The ability to design the control of heat flow has innumerable benefits in the design of electronic systems such as thermoelectric energy harvesters, solid-state lighting, and thermal imagers, where the thermal design plays a key role in performance and device reliability. In this work, we employ one identical sensu-unit with facile natural composition to experimentally realize a new class of thermal metamaterials for controlling thermal conduction (e.g., thermal concentrator, focusing/resolving, uniform heating), only resorting to positioning and locating the same unit element of sensu-shape structure. The thermal metamaterial unit and the proper arrangement of multiple identical units are capable of transferring, redistributing and managing thermal energy in a versatile fashion. It is also shown that our sensu-shape unit elements can be used in manipulating dc currents without any change in the layout for the thermal counterpart. These could markedly enhance the capabilities in thermal sensing, thermal imaging, thermal-energy storage, thermal packaging, thermal therapy, and more domains beyond. PMID:25974383
Manipulating Steady Heat Conduction by Sensu-shaped Thermal Metamaterials.
Han, Tiancheng; Bai, Xue; Liu, Dan; Gao, Dongliang; Li, Baowen; Thong, John T L; Qiu, Cheng-Wei
2015-05-14
The ability to design the control of heat flow has innumerable benefits in the design of electronic systems such as thermoelectric energy harvesters, solid-state lighting, and thermal imagers, where the thermal design plays a key role in performance and device reliability. In this work, we employ one identical sensu-unit with facile natural composition to experimentally realize a new class of thermal metamaterials for controlling thermal conduction (e.g., thermal concentrator, focusing/resolving, uniform heating), only resorting to positioning and locating the same unit element of sensu-shape structure. The thermal metamaterial unit and the proper arrangement of multiple identical units are capable of transferring, redistributing and managing thermal energy in a versatile fashion. It is also shown that our sensu-shape unit elements can be used in manipulating dc currents without any change in the layout for the thermal counterpart. These could markedly enhance the capabilities in thermal sensing, thermal imaging, thermal-energy storage, thermal packaging, thermal therapy, and more domains beyond.
Tong, H.; Lan, F.; Liu, Y. J.; Zhou, L. J.; Wang, X. J.; He, Q.; Wang, K. Z.; Miao, X. S.
2017-09-01
Temperature-dependent thermal conductivity of phase-change material, GeTe/Bi2Te3 superlattices, has been investigated in the temperature range of 40-300 K. We have found that thermal conductivity increases with increasing temperature, which is contrary to the common results indicated by other works. In this paper, two possible mechanisms are suggested for this result. One is that the thermal conductivity is affected by the thermal boundary resistance at the interfaces between layers, and the other considers the factor of electronic thermal conductivity in the partially coherent regime which is based on the very wave-particle duality of phonons. Finally, the periodic thickness dependence of the thermal conductivity in GeTe/Bi2Te3 superlattices have been measured at room temperature, and the results indicate the main contribution of electron in the total thermal conductivity and the partially coherent regime of phonon. Thus we believe that the second explanation is more reasonable. The work here deepens the understanding of basic mechanisms of thermal transport in phase-change superlattices, and is instructive in modeling and simulation of phase change memories.
Thermal conductivity evaluation of initial stage sintering phenomena
Schlaefer, Constance Elaine
The onset of sinter bonding and concomitant handling strength is a critical period in the processing of powder metallurgy materials. Mechanical characterization of this evolution during predensification sintering is difficult, due to the fragile nature of the materials. Thermal properties such as thermal diffusivity and thermal conductivity also evolve during the onset of sinter bonding. This research investigates the potential for assessing mechanical strength through thermal diffusivity evaluation, using the non-contact technique of laser flash analysis. Thermal conductivity and transverse rupture strength were evaluated for a nickel powder system in three different formats: injection-molded, low-density die-compacted, and high-density die-compacted. Measurements focused on post-sintering strength and thermal conductivity evolution from 20 to 700°C for the first two formats. In situ strength was evaluated for the high-density die-compacted material. Thermal conductivity was demonstrated to be a linear function of neck diameter, versus a function of the neck area as anticipated. Strength evaluation confirmed previous research that strength is a function of the neck area. Based on both properties' dependence on neck size, an integrated relationship was constructed, allowing mechanical strength to be directly predicted from thermal conductivity measurement for the given system.
A Device to Emulate Diffusion and Thermal Conductivity Using Water Flow
Blanck, Harvey F.
2005-01-01
A device designed to emulate diffusion and thermal conductivity using flowing water is reviewed. Water flowing through a series of cells connected by a small tube in each partition in this plastic model is capable of emulating diffusion and thermal conductivity that occurs in variety of systems described by several mathematical equations.
Thermal conduction effects in spin-lattice relaxation experiments on ytterbium chloride hexahydrate
Flokstra, Jakob; Gerritsma, G.J.; Blokhuis, A.C.
1979-01-01
The anomalous behaviour of the spin-lattice relaxation observed for single crystals of ytterbium chloride hexahydrate at fields stronger than 5 kOe is due to the poor heat transfer in the liquid-helium bath. The thermal conduction effects can be explained by means of a thermal conduction model for
Monte Carlo analysis: error of extrapolated thermal conductivity from molecular dynamics simulations
Energy Technology Data Exchange (ETDEWEB)
Liu, Xiang-Yang [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Andersson, Anders David [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
2016-11-07
In this short report, we give an analysis of the extrapolated thermal conductivity of UO2 from earlier molecular dynamics (MD) simulations [1]. Because almost all material properties are functions of temperature, e.g. fission gas release, the fuel thermal conductivity is the most important parameter from a model sensitivity perspective [2]. Thus, it is useful to perform such analysis.
Laser X-ray Conversion and Electron Thermal Conductivity*
Institute of Scientific and Technical Information of China (English)
无
2001-01-01
The influence of electron thermal conductivity on the laser x-ray conversion in the coupling of 3ωo laser with Au plane target has been investigated by using a non-LTE radiation hydrodynamic code. The non-local electron thermal conductivity is introduced and compared with the other two kinds of the flux-limited Spitzer-Harm description. The results show that the non-local thermal conductivity causes the increase of the laser x-ray conversion efficiency andimportant changes of the plasma state and coupling feature
Phonon Transport and Thermal Conductivity in an Acoustic Filter
Institute of Scientific and Technical Information of China (English)
LU Jian-Duo; SHAO Liang; HOU Yang-Lai; YI Lin
2007-01-01
We investigate the phonon ballistic transmission and the thermal conductivity in a dielectric quantum structure.It is found that these observable quantities sensitively depend on geometric parameters, and are of quantum character. The total transmission coefficient as a function of the reduced waveguide-length exhibits periodical belaviour and the reduced thermal conductance decreases below the ideal universal value for the low temperature.Our results show that one can control the thermal conductivity of the structure and make all kinds of acoustic filters to match practical requirements in devices by adjustingthe geometric parameters.
In-Pile Thermal Conductivity Measurement Method for Nuclear Fuels
Energy Technology Data Exchange (ETDEWEB)
Joy L. Rempe; Brandon Fox; Heng Ban; Joshua E. Daw; Darrell L. Knudson; Keith G. Condie
2009-08-01
Thermophysical properties of advanced nuclear fuels and materials during irradiation must be known prior to their use in existing, advanced, or next generation reactors. Thermal conductivity is one of the most important properties for predicting fuel and material performance. A joint Utah State University (USU) / Idaho National Laboratory (INL) project, which is being conducted with assistance from the Institute for Energy Technology at the Norway Halden Reactor Project, is investigating in-pile fuel thermal conductivity measurement methods. This paper focuses on one of these methods – a multiple thermocouple method. This two-thermocouple method uses a surrogate fuel rod with Joule heating to simulate volumetric heat generation to gain insights about in-pile detection of thermal conductivity. Preliminary results indicated that this method can measure thermal conductivity over a specific temperature range. This paper reports the thermal conductivity values obtained by this technique and compares these values with thermal property data obtained from standard thermal property measurement techniques available at INL’s High Test Temperature Laboratory. Experimental results and material properties data are also compared to finite element analysis results.
Remarkable reduction of thermal conductivity in phosphorene phononic crystal.
Xu, Wen; Zhang, Gang
2016-05-05
Phosphorene has received much attention due to its interesting physical and chemical properties, and its potential applications such as thermoelectricity. In thermoelectric applications, low thermal conductivity is essential for achieving a high figure of merit. In this work, we propose to reduce the thermal conductivity of phosphorene by adopting the phononic crystal structure, phosphorene nanomesh. With equilibrium molecular dynamics simulations, we find that the thermal conductivity is remarkably reduced in the phononic crystal. Our analysis shows that the reduction is due to the depressed phonon group velocities induced by Brillouin zone folding, and the reduced phonon lifetimes in the phononic crystal. Interestingly, it is found that the anisotropy ratio of thermal conductivity could be tuned by the 'non-square' pores in the phononic crystal, as the phonon group velocities in the direction with larger projection of pores is more severely suppressed, leading to greater reduction of thermal conductivity in this direction. Our work provides deep insight into thermal transport in phononic crystals and proposes a new strategy to reduce the thermal conductivity of monolayer phosphorene.
Lattice thermal conductivity of minerals in the deep mantle condition
Dekura, H.; Tsuchiya, T.; Tsuchiya, J.
2011-12-01
Thermal transport property of materials under pressure and temperature is of importance for understanding the dynamics of the solid Earth and the thermal history. Both experimental and theoretical determinations of the thermal conductivity, however, still remain technically challenging particularly at the deep mantle condition. Recent progress in ab initio computational method based on the density-functional theory is now makes it possible to examine the transport phenomena including the lattice thermal conduction. The intrinsic bulk thermal conduction of insulator is caused by lattice anharmonicity owing to phonon-phonon interaction. The key parameter to predict lattice thermal conductivity is thus the anharmonic coupling constant. Earlier theoretical works calculated the lattice thermal conductivity of MgO with ab initio molecular dynamics simulation or finite difference lattice dynamics simulation (Nico de Koker, Phys. Rev. Lett. 103, 125902, 2009; X. Tang and J. Dong, Proc. Natl. Acad. Sci. U.S.A. 107, 4539, 2010). However, in these approaches, the simulation cell size could often be insufficient for accurate description of the long wavelength phonon scattering. This leads to a lack of the decay channels for the phonons. As an alternative approach, the anharmonic coupling strength between phonon modes can be evaluated within the density-functional perturbation theory. In this approach, the higher-order force tensors are calculated through a number of phonon decay channels obtained within the perturbative scheme taking care only of the primitive cell. We have been developing a technique for calculation of the phonon linewidth necessary to obtain the phonon lifetime. Then the lattice thermal conductivity is evaluated combining with additional harmonic-level of propeties. In this presentation, we show the behavior of lattice thermal conductivity in lower mantle minerals, and discuss the effects of pressure and temperature on their conductivities up to the deep
Origins of ultralow thermal conductivity in bulk [6,6]-phenyl-C61-butyric acid methyl ester (PCBM).
Pöhls, Jan-Hendrik; Johnson, Michel B; White, Mary Anne
2016-01-14
Bulk PCBM has exceptionally low thermal conductivity, 0.07 W m(-1) K(-1) at room temperature. We show that its ultralow thermal conductivity is an intrinsic property. Based on results for thermal conductivity and heat capacity measurements down to thermal conductivity was developed. In the model the thermal energy is transferred between entities of phonons oscillating in a range of frequencies, and limited by the atomic density and the phonon mean speed. The model accurately represents the low thermal conductivity for both PCBM and C60/C70.
Charge-transport model for conducting polymers
Dongmin Kang, Stephen; Jeffrey Snyder, G.
2016-11-01
The growing technological importance of conducting polymers makes the fundamental understanding of their charge transport extremely important for materials and process design. Various hopping and mobility edge transport mechanisms have been proposed, but their experimental verification is limited to poor conductors. Now that advanced organic and polymer semiconductors have shown high conductivity approaching that of metals, the transport mechanism should be discernible by modelling the transport like a semiconductor with a transport edge and a transport parameter s. Here we analyse the electrical conductivity and Seebeck coefficient together and determine that most polymers (except possibly PEDOT:tosylate) have s = 3 and thermally activated conductivity, whereas s = 1 and itinerant conductivity is typically found in crystalline semiconductors and metals. The different transport in polymers may result from the percolation of charge carriers from conducting ordered regions through poorly conducting disordered regions, consistent with what has been expected from structural studies.
How intermixing and anharmonicity enhances interfacial thermal conductance?
Polanco, Carlos; Zhang, Jingjie; Le, Nam; Rastgarkafshgarkolaei, Rouzbeh; Norris, Pamela; Ghosh, Avik
2015-03-01
The thermal conductance at an interface, whether ballistic or diffusive, can be expressed as a product of the number of conducting channels (M) and their average transmission (T). The common expectation is that interfacial defects reduce T and thus hurt the conductance. This is however at odds with recent simulations showing that a thin intermixing layer can in fact enhance the conductance. We argue that such an enhancement occurs when the increase in number of modes outweighs the reduction in their average transmission. The new channels open as a result of (a) the random interfacial structure that relaxes the conservation rules for the transverse momentum and promotes transitions between formerly symmetry disallowed channels; and (b) inelastic scattering through phonon-phonon interactions that allow modes beyond the contact cut-off frequency to contribute to transport. We use these results to build a back of the envelope model for interfacial conductance that depends on the mixing distribution, the anharmonic strength, the phonon polarization and wavelength. Non-Equilibrium Green's Function (NEGF) as well as Molecular Dynamics (MD) simulations on Si/mixed layer/Ge, as well as simpler FCC crystals support our results. NSF-CAREER (QMHP 1028883), NSF-IDR (CBET 1134311), XSEDE (TG-DMR130123).
Thermal conductivity of microPCMs-filled epoxy matrix composites
Su, J.F.; Wang, X.Y; Huang, Z.; Zhao, Y.H.; Yuan, X.Y.
2011-01-01
Microencapsulated phase change materials (microPCMs) have been widely applied in solid matrix as thermal-storage or temperature-controlling functional composites. The thermal conductivity of these microPCMs/matrix composites is an important property need to be considered. In this study, a series of
Thermal Conduction in Systems out of Hydrostatic Equilibrium
Herrera, L; Hernández-Pastora, J L; Martín, J; Martínez, J
1997-01-01
We analyse the effects of thermal conduction in a relativistic fluid, just after its departure from hydrostatic equilibrium, on a time scale of the order of thermal relaxation time. It is obtained that the resulting evolution will critically depend on a parameter defined in terms of thermodynamic variables, which is constrained by causality requirements.
Anisotropic Tuning of Graphite Thermal Conductivity by Lithium Intercalation.
Qian, Xin; Gu, Xiaokun; Dresselhaus, Mildred S; Yang, Ronggui
2016-11-17
Understanding thermal transport in lithium intercalated layered materials is not only important for managing heat generation and dissipation in lithium ion batteries but also the understanding potentially provides a novel way to design materials with reversibly tunable thermal conductivity. In this work, the thermal conductivity of lithium-graphite intercalation compounds (LixC6) is calculated using molecular dynamics simulations as a function of the amount of lithium intercalated. We found that intercalation of lithium has an anisotropic effect on tuning the thermal conductivity: the thermal conductivity in the basal plane decreases monotonically from 1232 W/m·K of pristine graphite to 444 W/m·K of the fully lithiated LiC6, while the thermal conductivity along the c-axis decreases first from 6.5 W/m·K for graphite to 1.3 W/m·K for LiC18 and then increases to 5.0 W/m·K for LiC6 as the lithium composition increases. More importantly, we provide the very first atomic-scale insight into the effect of lithium intercalation on the spectral phonon properties of graphite. The intercalated lithium ions are found to suppress the phonon lifetime and to reduce the group velocity of phonons parallel to the basal plane but significantly to increase the phonon group velocity along the c-axis, which anisotropically tunes the thermal conductivity of lithiated graphite compounds. This work could shed some light on the search for tunable thermal conductivity materials and might have strong impacts on the thermal management of lithium ion batteries.
Enhanced thermal conductivity through the development of nanofluids
Energy Technology Data Exchange (ETDEWEB)
Eastman, J.A.; Choi, U.S.; Li, S.; Thompson, L.J.; Lee, S.
1996-11-01
Low thermal conductivity is a primary limitation in the development of energy-efficient heat transfer fluids required in many industrial applications. To overcome this limitation, a new class of heat transfer fluids is being developed by suspending nanocrystalline particles in liquids such as water or oil. The resulting nanofluids possess extremely high thermal conductivities compared to the liquids without dispersed nanocrystalline particles. For example, 5 volume % of nanocrystalline copper oxide particles suspended in water results in an improvement in thermal conductivity of almost 60% compared to water without nanoparticles. Excellent suspension properties are also observed, with no significant settling of nanocrystalline oxide particles occurring in stationary fluids over time periods longer than several days. Direct evaporation of Cu nanoparticles into pump oil results in similar improvements in thermal conductivity compared to oxide-in-water systems, but importantly, requires far smaller concentrations of dispersed nanocrystalline powder.
Evidence for enhanced thermal conduction through percolating structures in nanofluids
Energy Technology Data Exchange (ETDEWEB)
Philip, John; Shima, P D; Raj, Baldev [Metallurgy and Materials Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102, Tamilnadu (India)], E-mail: philip@igcar.gov.in
2008-07-30
The unusually large enhancement of thermal conductivity (k/k{sub f}{approx}4.0, where k and k{sub f} are the thermal conductivities of the nanofluid and the base fluid, respectively) observed in a nanofluid containing linear chain-like aggregates provides direct evidence for efficient transport of heat through percolating paths. The nanofluid used was a stable colloidal suspension of magnetite (Fe{sub 3}O{sub 4}) nanoparticles of average diameter 6.7 nm, coated with oleic acid and dispersed in kerosene. The maximum enhancement under magnetic field was about 48{phi} (where {phi} is the volume fraction). The maximum enhancement is observed when chain-like aggregates are uniformly dispersed without clumping. These results also suggest that nanofluids containing well-dispersed nanoparticles (without aggregates) do not exhibit significant enhancement of thermal conductivity. Our findings offer promising applications for developing a new generation of nanofluids with tunable thermal conductivity.
Evidence for enhanced thermal conduction through percolating structures in nanofluids.
Philip, John; Shima, P D; Raj, Baldev
2008-07-30
The unusually large enhancement of thermal conductivity (k/k(f)∼4.0, where k and k(f) are the thermal conductivities of the nanofluid and the base fluid, respectively) observed in a nanofluid containing linear chain-like aggregates provides direct evidence for efficient transport of heat through percolating paths. The nanofluid used was a stable colloidal suspension of magnetite (Fe(3)O(4)) nanoparticles of average diameter 6.7 nm, coated with oleic acid and dispersed in kerosene. The maximum enhancement under magnetic field was about 48φ (where φ is the volume fraction). The maximum enhancement is observed when chain-like aggregates are uniformly dispersed without clumping. These results also suggest that nanofluids containing well-dispersed nanoparticles (without aggregates) do not exhibit significant enhancement of thermal conductivity. Our findings offer promising applications for developing a new generation of nanofluids with tunable thermal conductivity.
Cryogenic Thermal Conductivity Measurements on Candidate Materials for Space Missions
Tuttle, JIm; Canavan, Ed; Jahromi, Amir
2017-01-01
Spacecraft and instruments on space missions are built using a wide variety of carefully-chosen materials. In addition to having mechanical properties appropriate for surviving the launch environment, these materials generally must have thermal conductivity values which meet specific requirements in their operating temperature ranges. Space missions commonly propose to include materials for which the thermal conductivity is not well known at cryogenic temperatures. We developed a test facility in 2004 at NASAs Goddard Space Flight Center to measure material thermal conductivity at temperatures between 4 and 300 Kelvin, and we have characterized many candidate materials since then. The measurement technique is not extremely complex, but proper care to details of the setup, data acquisition and data reduction is necessary for high precision and accuracy. We describe the thermal conductivity measurement process and present results for several materials.
Thermal conductivity of newspaper sandwiched aerated lightweight concrete panel
Energy Technology Data Exchange (ETDEWEB)
Ng, Soon-Ching; Low, Kaw-Sai [Faculty of Engineering and Science, Universiti Tunku Abdul Rahman, Jalan Genting Kelang, Setapak, 53300 Kuala Lumpur, Wilayah Persekutuan (Malaysia)
2010-12-15
Investigation on the thermal conductivity of newspaper sandwiched aerated lightweight concrete (ALC) panels is the main purpose of this study. Various densities of ALC panels ranging from 1700, 1400 and 1100 kg/m{sup 3} with three different aerial intensities of newspaper sandwiched were produced. Investigation was limited to the effect of aerial intensity of newspaper sandwiched and the effect of density of ALC on thermal conductivity. It is found that the thermal conductivity of newspaper sandwiched ALC panels reduced remarkably compared to control ALC panels. The reduction was recorded at 18.0%, 21.8% and 20.7% correspond to densities of 1700, 1400 and 1100 kg/m{sup 3} with just a mere 0.05 g/cm{sup 2} aerial intensity of newspaper sandwiched. Newspaper sandwiched has a significant impact on the performance of thermal conductivity of ALC panels based on regression analysis. (author)
Thermal conductance of pressed brass contacts at liquid helium temperatures
Salerno, L. J.; Kittel, P.; Brooks, W. F.; Spivak, A. L.; Marks, W. G., Jr.
1986-01-01
An apparatus has been designed and fabricated which will measure the thermal conductance of pressed contacts at liquid helium temperatures as a function of applied force, with surface finish as a parameter. The apparatus is automated and was used to measure thermal conductance at temperatures from 1.5 to 6.5 K at applied forces up to 700 N for brass sample pairs having surface finishes from 0.1 to 1.6 micron rms. The experimental data were found to fit a simple power law where the thermal conductance is given by k = alpha T exp n, where k is the thermal conductance, T is the absolute temperature, and alpha and n are empirically determined constants.
Thermal conductivity measurements at cryogenic temperatures at LASA
Energy Technology Data Exchange (ETDEWEB)
Broggi, F.; Pedrini, D.; Rossi, L. [INFN, Milan (Italy)]|[Laboratorio LASA, Segrate, Milan (Italy)
1995-08-01
Here the improvement realised to have better control of the reference junction temperature and measurements carried out on Nb{sub 3}Sn cut out from 2 different coils (named LASA3 and LASA5), showing the difference between the longitudinal and the transverse thermal conductivity, is described. Two different methods of data analysis are presented, the DAM (derivative approximated method) and the TCI (thermal conductivity integral). The data analysis for the tungsten and the LASA5 coil has been done according to the two methods showing that the TCI method with polynomial functions is not adequate to describe the thermal conductivity. Only a polynomial fit based on the TCI method but limited at a lower order than the nominal, when the data are well distributed along the range of measurements, can describe reasonably the thermal conductivity dependence with the temperature. Finally the measurements on a rod of BSCCO 2212 high T{sub c} superconductor are presented.
Taheri, H.; Schmidt, F. P.; Gabi, M.
2015-01-01
This paper presents a numerical case study of heat transfer mechanisms during the charging process of a stratified thermal storage tank applied in a specific adsorption heat pump cycle. The effective thermal conductivity of the heat transfer fluid during the charging process is analyzed through CFD simulations using Unsteady Reynolds-averaged Navier-Stokes equations (URANS). The aim of the study is to provide an equivalent thermal conductivity for a one-dimensional storage tank model to be us...
Estimation of thermal conductivity of short pastry biscuit at different baking stages
Directory of Open Access Journals (Sweden)
Chiara Cevoli
2014-10-01
Full Text Available Thermal conductivity of a food material is an essential physical property in mathematical modelling and computer simulation of thermal processing. Effective thermal conductivity of non-homogeneous materials, such as food matrices, can be determined experimentally or mathematically. The aim of the following research was to compare the thermal conductivity of short pastry biscuits, at different baking stages (60-160 min, measured by a line heat source thermal conductivity probe and estimated through the use of thermo-physical models. The measures were carried out on whole biscuits and on powdered biscuits compressed into cylindrical cases. Thermal conductivity of the compacted material, at different baking times (and, consequently at different moisture content, was then used to feed parallel, series, Krischer and Maxwell-Eucken models. The results showed that the application of the hot wire method for the determination of thermal conductivity is not fully feasible if applied directly to whole materials due to mechanical changes applied to the structure and the high presence of fats. The method works best if applied to the biscuit component phases separately. The best model is the Krischer one for its adaptability. In this case the value of biscuit thermal conductivity, for high baking time, varies from 0.15 to 0.19 Wm–1 K–1, while the minimum, for low baking time, varies from 0.11 to 0.12 Wm–1 K–1. These values are close to that reported in literature for similar products.
On the Effective Thermal Conductivity of Frost Considering Mass Diffusion and Eddy Convection
Kandula, Max
2010-01-01
A physical model for the effective thermal conductivity of water frost is proposed for application to the full range of frost density. The proposed model builds on the Zehner-Schlunder one-dimensional formulation for porous media appropriate for solid-to-fluid thermal conductivity ratios less than about 1000. By superposing the effects of mass diffusion and eddy convection on stagnant conduction in the fluid, the total effective thermal conductivity of frost is shown to be satisfactorily described. It is shown that the effects of vapor diffusion and eddy convection on the frost conductivity are of the same order. The results also point out that idealization of the frost structure by cylindrical inclusions offers a better representation of the effective conductivity of frost as compared to spherical inclusions. Satisfactory agreement between the theory and the measurements for the effective thermal conductivity of frost is demonstrated for a wide range of frost density and frost temperature.
Advanced Low Conductivity Thermal Barrier Coatings: Performance and Future Directions
Zhu, Dongming; Miller, Robert A.
2008-01-01
Thermal barrier coatings will be more aggressively designed to protect gas turbine engine hot-section components in order to meet future engine higher fuel efficiency and lower emission goals. In this presentation, thermal barrier coating development considerations and performance will be emphasized. Advanced thermal barrier coatings have been developed using a multi-component defect clustering approach, and shown to have improved thermal stability and lower conductivity. The coating systems have been demonstrated for high temperature combustor applications. For thermal barrier coatings designed for turbine airfoil applications, further improved erosion and impact resistance are crucial for engine performance and durability. Erosion resistant thermal barrier coatings are being developed, with a current emphasis on the toughness improvements using a combined rare earth- and transition metal-oxide doping approach. The performance of the toughened thermal barrier coatings has been evaluated in burner rig and laser heat-flux rig simulated engine erosion and thermal gradient environments. The results have shown that the coating composition optimizations can effectively improve the erosion and impact resistance of the coating systems, while maintaining low thermal conductivity and cyclic durability. The erosion, impact and high heat-flux damage mechanisms of the thermal barrier coatings will also be described.
A novel method to determine effective thermal conductivity of porous materials
Institute of Scientific and Technical Information of China (English)
QIAN Jiyu; LI Qiang; YU Kai; XUAN Yimin
2004-01-01
A 2D Lattice-Boltzmann (LB) model is proposed for analyzing the heat conduction process in the porous media. The effective thermal conductivities of several porous materials are calculated by means of this model. The calculated results are found to be in excellent agreement with the experimental data of the existing references. The factors affecting the effective thermal conductivity of porous materials are discussed. The results show that the effective thermal conductivity is strongly dependent upon the porosity and the pore structure and only has imperceptible dependence on the pore density. Then the correlation for estimating the effective thermal conductivity of the porous material is established. This LB model can be used conveniently to calculate and analyze the heat conduction problems of porous media or other materials with complex geometry boundary in pore scale.
Allan, J.; Pinder, H.; Dehouche, Z.
2016-03-01
Samples of Ethylene-Vinyl Acetate (EVA) were doped with particles of Boron Nitride (BN) in concentrations ranging from 0-60% w/w. Thermal conductivity was measured using a Differential Scanning Calorimetery (DSC) technique. The thermal conductivity of parent EVA was increased from 0.24W/m ṡ K to 0.80W/m ṡ K for the 60% w/w sample. Two PV laminates were made; one using the parent EVA the other using EVA doped with 50% BN. When exposed to a one directional heat flux the doped laminate was, on average, 6% cooler than the standard laminate. A finite difference model had good agreement with experimental results and showed that the use of 60% BN composite achieved a PV performance increase of 0.3% compared to the standard laminate.
Directory of Open Access Journals (Sweden)
J. Allan
2016-03-01
Full Text Available Samples of Ethylene-Vinyl Acetate (EVA were doped with particles of Boron Nitride (BN in concentrations ranging from 0-60% w/w. Thermal conductivity was measured using a Differential Scanning Calorimetery (DSC technique. The thermal conductivity of parent EVA was increased from 0.24W/m ⋅ K to 0.80W/m ⋅ K for the 60% w/w sample. Two PV laminates were made; one using the parent EVA the other using EVA doped with 50% BN. When exposed to a one directional heat flux the doped laminate was, on average, 6% cooler than the standard laminate. A finite difference model had good agreement with experimental results and showed that the use of 60% BN composite achieved a PV performance increase of 0.3% compared to the standard laminate.
Prediction of thermal conductivity of sedimentary rocks from well logs
DEFF Research Database (Denmark)
Fuchs, Sven; Förster, Andrea
2014-01-01
. A common procedure in the latter approach is the use of empirical relations between TC and different petrophysical properties. Although numerous prediction equations were developed in the past five decades, none of these seem to be universally applicable for all major types of sedimentary rocks (clastics...... combinations of standard geophysical well-logs. In combination with a feasible mixing-model (i.e. geometric mean model) bulk TC is computed along borehole profiles. The underlying approach was proposed by Fuchs & Förster (2014) and rests upon the detailed analysis of the interrelations between major physical...... parameters (i.e. thermal conductivity, density, hydrogen index, sonic interval transit time, gamma-ray response, photoelectric factor) of artificial mineral assemblages consisting 15 rock-forming minerals that are used in different combinations to typify sedimentary rocks. The predictive capacity of the new...
High thermal conductivity of a hydrogenated amorphous silicon film.
Liu, Xiao; Feldman, J L; Cahill, D G; Crandall, R S; Bernstein, N; Photiadis, D M; Mehl, M J; Papaconstantopoulos, D A
2009-01-23
We measured the thermal conductivity kappa of an 80 microm thick hydrogenated amorphous silicon film prepared by hot-wire chemical-vapor deposition with the 3omega (80-300 K) and the time-domain thermo-reflectance (300 K) methods. The kappa is higher than any of the previous temperature dependent measurements and shows a strong phonon mean free path dependence. We also applied a Kubo based theory using a tight-binding method on three 1000 atom continuous random network models. The theory gives higher kappa for more ordered models, but not high enough to explain our results, even after extrapolating to lower frequencies with a Boltzmann approach. Our results show that this material is more ordered than any amorphous silicon previously studied.
Thermal conductivity, electrical conductivity and specific heat of copper-carbon fiber composite
Kuniya, Keiichi; Arakawa, Hideo; Kanai, Tsuneyuki; Chiba, Akio
1988-01-01
A new material of copper/carbon fiber composite is developed which retains the properties of copper, i.e., its excellent electrical and thermal conductivity, and the property of carbon, i.e., a small thermal expansion coefficient. These properties of the composite are adjustable within a certain range by changing the volume and/or the orientation of the carbon fibers. The effects of carbon fiber volume and arrangement changes on the thermal and electrical conductivity, and specific heat of the composite are studied. Results obtained are as follows: the thermal and electrical conductivity of the composite decrease as the volume of the carbon fiber increases, and were influenced by the fiber orientation. The results are predictable from a careful application of the rule of mixtures for composites. The specific heat of the composite was dependent, not on fiber orientation, but on fiber volume. In the thermal fatigue tests, no degradation in the electrical conductivity of this composite was observed.
Identification of temperature-dependent thermal conductivity and experimental verification
Pan, Weizhen; Yi, Fajun; Zhu, Yanwei; Meng, Songhe
2016-07-01
A modified Levenberg-Marquardt method (LMM) for the identification of temperature-dependent thermal conductivity is proposed; the experiment and structure of the specimen for identification are also designed. The temperature-dependent thermal conductivities of copper C10200 and brass C28000 are identified to verify the effectiveness of the proposed identification method. The comparison between identified results and the measured data of laser flash diffusivity apparatus indicates the fine consistency and potential usage of the proposed method.
APPLICATION OF NUMERICAL SIMULATION TO STUDY ON THERMAL CONDUCTION
Institute of Scientific and Technical Information of China (English)
C. Zhu; Z. Xu; D.E. Wu
2004-01-01
In this paper, using computer simulation and mathematic experiment method to solve the simplified one dimensional thermal conduction equation and to obtain the temperature distribution in a metal bar when its one end was heated. According to principle of hot expansion, a holograph of temperature distribution in the bar by laser holotechnique was taken. The results of numerical simulation and experiments are in good agreement and a new method for study on thermal conduction by laser holo-technique was found.
Studies and Properties of Ceramics with High Thermal Conductivity
Institute of Scientific and Technical Information of China (English)
无
2006-01-01
The sintering technology of the AlN ceramics power were discussed. It is discussed that the compound sintering aids is consistent with the enhancement of the the thermal conductivity of AlN ceramics, and sintering technics is helped to the improvement of density. It is analyzed how to sinter machinable AlN ceramics with high thermal conductivity. And the microstructure of compound ceramics based on AlN was studied.
Thermal conductivities of some lead and bismuth glasses
Velden, P.F. van
1965-01-01
Thermal conductivities have been measured, mainly at 40°C, of glasses within the systems PbO-Bi2O3-SiO2, PbO-Bi2O3-Al2O3-SiO2, and BaO- (Bi2O3 or PbO) -SiO2. Aiming at lowest thermal conductivity, preference was given to glasses of low silica and low alumina contents. Glass formation persists at rat
Dependence of thermal conductivity on structural parameters in porous samples
L. Miettinen; Kekäläinen, P; T. Turpeinen; Hyväluoma, J; Merikoski, J.; J. Timonen
2012-01-01
The in-plane thermal conductivity of porous sintered bronze plates was studied both experimentally and numerically. We developed and validated an experimental setup, where the sample was placed in vacuum and heated while its time-dependent temperature field was measured with an infrared camera. The porosity and detailed three-dimensional structure of the samples were determined by X-ray microtomography. Lattice-Boltzmann simulations of thermal conductivity in the tomographic reconstructions o...
Thermal Conductivity Measurements on Icy Satellite Analogs
Javeed, Aurya; Barmatz, Martin; Zhong, Fang; Choukroun, Mathieu
2012-01-01
With regard to planetary science, NASA aspires to: "Advance scientific knowledge of the origin and history of the solar system, the potential for life elsewhere, and the hazards and resources present as humans explore space". In pursuit of such an end, the Galileo and Cassini missions garnered spectral data of icy satellite surfaces implicative of the satellites' structure and material composition. The potential for geophysical modeling afforded by this information, coupled with the plausibility of life on icy satellites, has pushed Jupiter's Europa along with Saturn's Enceladus and Titan toward the fore of NASA's planetary focus. Understanding the evolution of, and the present processes at work on, the aforementioned satellites falls squarely in-line with NASA's cited goal.
Graphene nanoplatelets: Thermal diffusivity and thermal conductivity by the flash method
Potenza, M.; Cataldo, A.; Bovesecchi, G.; Corasaniti, S.; Coppa, P.; Bellucci, S.
2017-07-01
The present work deals with the measurement of thermo-physical properties of a freestanding sheet of graphene (thermal diffusivity and thermal conductivity), and their dependence on sample density as result of uniform mechanical compression. Thermal diffusivity of graphene nano-platelets (thin slabs) was measured by the pulse flash method. Obtained response data were processed with a specifically developed least square data processing algorithm. GNP specific heat was assumed from literature and thermal conductivity derived from thermal diffusivity, specific heat and density. Obtained results show a significant difference with respect to other porous media: the thermal diffusivity decreases as the density increases, while thermal conductivity increases for low and high densities, and remain fairly constant for the intermediate range. This can be explained by the very high thermal conductivity values reached by the nano-layers of graphene and the peculiar arrangement of platelets during the compression applied to the samples to get the desired density. Due to very high thermal conductivity of graphene layers, the obtained results show that thermal conductivity of conglomerates increases when there is an air reduction due to compression, and consequent density increases, with the number of contact points between platelets also increased. In the intermediate range (250 ≤ ρ ≤ 700 kg.m-3) the folding of platelets reduces density, without increasing the contact points of platelets, so thermal conductivity can slightly decrease.
Dong, Huicong; Wen, Bin; Melnik, Roderick
2014-11-13
A theoretical model for describing effective thermal conductivity (ETC) of nanocrystalline materials has been proposed, so that the ETC can be easily obtained from its grain size, single crystal thermal conductivity, single crystal phonon mean free path (PMFP), and the Kaptiza thermal resistance. In addition, the relative importance between grain boundaries (GBs) and size effects on the ETC of nanocrystalline diamond at 300 K has been studied. It has been demonstrated that with increasing grain size, both GBs and size effects become weaker, while size effects become stronger on thermal conductivity than GBs effects.
Metallic coatings for enhancement of thermal contact conductance
Lambert, M. A.; Fletcher, L. S.
1994-04-01
The reliability of standard electronic modules may be improved by decreasing overall module temperature. This may be accomplished by enhancing the thermal contact conductance at the interface between the module frame guide rib and the card rail to which the module is clamped. Some metallic coatings, when applied to the card rail, would deform under load, increasing the contact area and associated conductance. This investigation evaluates the enhancements in thermal conductance afforded by vapor deposited silver and gold coatings. Experimental thermal conductance measurements were made for anodized aluminum 6101-T6 and electroless nickel-plated copper C11000-H03 card materials to the aluminum A356-T61 rail material. Conductance values for the electroless nickel-plated copper junction ranged from 600 to 2800 W/m(exp 2)K and those for the anodized aluminum junction ranged from 25 to 91 W/m(exp 2)K for contact pressures of 0.172-0.862 MPa and mean junction temperatures of 20-100 C. Experimental thermal conductance values of vapor deposited silver- and gold-coated aluminum A356-T61 rail surfaces indicate thermal enhancements of 1.25-2.19 for the electroless nickel-plated copper junctions and 1.79-3.41 for the anodized aluminum junctions. The silver and gold coatings provide significant thermal enhancement; however, these coating-substrate combinations are susceptible to galvanic corrosion under some conditions.
Toward nanofluids of ultra-high thermal conductivity.
Wang, Liqiu; Fan, Jing
2011-02-18
The assessment of proposed origins for thermal conductivity enhancement in nanofluids signifies the importance of particle morphology and coupled transport in determining nanofluid heat conduction and thermal conductivity. The success of developing nanofluids of superior conductivity depends thus very much on our understanding and manipulation of the morphology and the coupled transport. Nanofluids with conductivity of upper Hashin-Shtrikman (H-S) bound can be obtained by manipulating particles into an interconnected configuration that disperses the base fluid and thus significantly enhancing the particle-fluid interfacial energy transport. Nanofluids with conductivity higher than the upper H-S bound could also be developed by manipulating the coupled transport among various transport processes, and thus the nature of heat conduction in nanofluids. While the direct contributions of ordered liquid layer and particle Brownian motion to the nanofluid conductivity are negligible, their indirect effects can be significant via their influence on the particle morphology and/or the coupled transport.
Remote cooling by a novel thermal lens with anisotropic positive thermal conductivity
Sun, Fei; He, Sailing
2017-01-01
A novel thermal lens that can achieve a remote cooling effect is designed by transformation thermodynamics. The effective distance between the separate hot source and cold source is shortened by our shelled thermal lens without any negative thermal conductivity. Numerical simulations verify the performance of our thermal lens. Based on the effective medium theory, we also propose a practical way to realize our lens using two-layered isotropic thermal media that are both found in nature. The proposed thermal lens will have potential applications in remote temperature control and in creating other thermal illusions.
Voltage tunability of thermal conductivity in ferroelectric materials
Ihlefeld, Jon; Hopkins, Patrick Edward
2016-02-09
A method to control thermal energy transport uses mobile coherent interfaces in nanoscale ferroelectric films to scatter phonons. The thermal conductivity can be actively tuned, simply by applying an electrical potential across the ferroelectric material and thereby altering the density of these coherent boundaries to directly impact thermal transport at room temperature and above. The invention eliminates the necessity of using moving components or poor efficiency methods to control heat transfer, enabling a means of thermal energy control at the micro- and nano-scales.
Thermal conductivity measurements of particulate materials under Martian conditions
Presley, M. A.; Christensen, P. R.
1993-01-01
The mean particle diameter of surficial units on Mars has been approximated by applying thermal inertia determinations from the Mariner 9 Infrared Radiometer and the Viking Infrared Thermal Mapper data together with thermal conductivity measurement. Several studies have used this approximation to characterize surficial units and infer their nature and possible origin. Such interpretations are possible because previous measurements of the thermal conductivity of particulate materials have shown that particle size significantly affects thermal conductivity under martian atmospheric pressures. The transfer of thermal energy due to collisions of gas molecules is the predominant mechanism of thermal conductivity in porous systems for gas pressures above about 0.01 torr. At martian atmospheric pressures the mean free path of the gas molecules becomes greater than the effective distance over which conduction takes place between the particles. Gas particles are then more likely to collide with the solid particles than they are with each other. The average heat transfer distance between particles, which is related to particle size, shape and packing, thus determines how fast heat will flow through a particulate material.The derived one-to-one correspondence of thermal inertia to mean particle diameter implies a certain homogeneity in the materials analyzed. Yet the samples used were often characterized by fairly wide ranges of particle sizes with little information about the possible distribution of sizes within those ranges. Interpretation of thermal inertia data is further limited by the lack of data on other effects on the interparticle spacing relative to particle size, such as particle shape, bimodal or polymodal mixtures of grain sizes and formation of salt cements between grains. To address these limitations and to provide a more comprehensive set of thermal conductivities vs. particle size a linear heat source apparatus, similar to that of Cremers, was assembled to
Shocks and Thermal Conduction Fronts in Retracting Reconnected Flux Tubes
Guidoni, S. E.; Longcope, D. W.
2010-08-01
We present a model for plasma heating produced by time-dependent, spatially localized reconnection within a flare current sheet separating skewed magnetic fields. The reconnection creates flux tubes of new connectivity which subsequently retract at Alfvénic speeds from the reconnection site. Heating occurs in gas-dynamic shocks (GDSs) which develop inside these tubes. Here we present generalized thin flux tube equations for the dynamics of reconnected flux tubes, including pressure-driven parallel dynamics as well as temperature-dependent, anisotropic viscosity and thermal conductivity. The evolution of tubes embedded in a uniform, skewed magnetic field, following reconnection in a patch, is studied through numerical solutions of these equations, for solar coronal conditions. Even though viscosity and thermal conductivity are negligible in the quiet solar corona, the strong GDSs generated by compressing plasma inside reconnected flux tubes generate large velocity and temperature gradients along the tube, rendering the diffusive processes dominant. They determine the thickness of the shock that evolves up to a steady state value, although this condition may not be reached in the short times involved in a flare. For realistic solar coronal parameters, this steady state shock thickness might be as long as the entire flux tube. For strong shocks at low Prandtl numbers, typical of the solar corona, the GDS consists of an isothermal sub-shock where all the compression and cooling occur, preceded by a thermal front where the temperature increases and most of the heating occurs. We estimate the length of each of these sub-regions and the speed of their propagation.
Thermal and Electrical Conductivity Measurements of CDA 510 Phosphor Bronze
Tuttle, James E.; Canavan, Edgar; DiPirro, Michael
2009-01-01
Many cryogenic systems use electrical cables containing phosphor bronze wire. While phosphor bronze's electrical and thermal conductivity values have been published, there is significant variation among different phosphor bronze formulations. The James Webb Space Telescope (JWST) will use several phosphor bronze wire harnesses containing a specific formulation (CDA 510, annealed temper). The heat conducted into the JWST instrument stage is dominated by these harnesses, and approximately half of the harness conductance is due to the phosphor bronze wires. Since the JWST radiators are expected to just keep the instruments at their operating temperature with limited cooling margin, it is important to know the thermal conductivity of the actual alloy being used. We describe an experiment which measured the electrical and thermal conductivity of this material between 4 and 295 Kelvin.
Ultralow thermal conductivity in Electrolessly Etched (EE) Silicon Nanowires
Hippalgaonkar, Kedar; Chen, Renkun; Budaev, Bair; Tang, Jinyao; Andrews, Sean; Murphy, Padraig; Mukerjee, Subroto; Moore, Joel; Yang, Peidong; Majumdar, Arun
2009-03-01
EE process produces single-crystalline Silicon nanowires with rough walls. We use suspended structures to directly compute the heat transfer through single nanowires. Nanowires with diameters less than the mean free path of phonons impede transport by boundary scattering. The roughness acts as a secondary scattering mechanism to further reduce phonon transport. By controlling the amount of roughness it is possible to push limits to the extent that nanowire conductance close to quanta of thermal conductance,πkB^2 T / πkB^2 T 6 . - 6 is observed. Traditionally, the lower limit of conductivity is amorphous Silicon at 1 W/mK at room temperature. The measured conductivity of our nanostructures challenges even this amorphous limit pointing towards previously unstudied mechanisms of thermal resistance. We measure thermal conductivity of ˜150nm diameter EE wires to be ˜1 W/mK.
Thermal and tensile strength testing of thermally-conductive adhesives and carbon foam
Chertok, Maxwell; Irving, Michael; Neher, Christian; Shi, Mengyao; Tolfa, Kirk; Tripathi, Mani; Vinson, Yasmeen; Wang, Ruby; Zheng, Gayle
2016-01-01
Future collider detectors, including silicon tracking detectors planned for the High Luminosity LHC, will require components and mechanical structures providing unprecedented strength-to-mass ratios, thermal conductivity, and radiation tolerance. This paper studies carbon foam used in conjunction with thermally conductive epoxy and thermally conductive tape for such applications. Thermal conductivity and tensile strength measurements of aluminum-carbon foam-adhesive stacks are reported. Initial radiation damage tests are also presented. These results can inform bonding method choices for future tracking detectors.
Thermal Conductivity Based on Modified Laser Flash Measurement
Lin, Bochuan; Ban, Heng; Li, Chao; Scripa, Rosalia N.; Su, Ching-Hua; Lehoczky, Sandor L.
2005-01-01
The laser flash method is a standard method for thermal diffusivity measurement. It employs single-pulse heating of one side of a thin specimen and measures the temperature response of the other side. The thermal diffusivity of the specimen can be obtained based on a one-dimensional transient heat transfer analysis. This paper reports the development of a theory that includes a transparent reference layer with known thermal property attached to the back of sample. With the inclusion of heat conduction from the sample to the reference layer in the theoretical analysis, the thermal conductivity and thermal diffusivity of sample can be extracted from the temperature response data. Furthermore, a procedure is established to select two points from the data to calculate these properties. The uncertainty analysis indicates that this method can be used with acceptable levels of uncertainty.
Thermal conductivity characteristics of dewatered sewage sludge by thermal hydrolysis reaction.
Song, Hyoung Woon; Park, Keum Joo; Han, Seong Kuk; Jung, Hee Suk
2014-12-01
The purpose of this study is to quantify the thermal conductivity of sewage sludge related to reaction temperature for the optimal design of a thermal hydrolysis reactor. We continuously quantified the thermal conductivity of dewatered sludge related to the reaction temperature. As the reaction temperature increased, the dewatered sludge is thermally liquefied under high temperature and pressure by the thermal hydrolysis reaction. Therefore, the bound water in the sludge cells comes out as free water, which changes the dewatered sludge from a solid phase to slurry in a liquid phase. As a result, the thermal conductivity of the sludge was more than 2.64 times lower than that of the water at 20. However, above 200, it became 0.704 W/m* degrees C, which is about 4% higher than that of water. As a result, the change in physical properties due to thermal hydrolysis appears to be an important factor for heat transfer efficiency. Implications: The thermal conductivity of dewatered sludge is an important factor the optimal design of a thermal hydrolysis reactor. The dewatered sludge is thermally liquefied under high temperature and pressure by the thermal hydrolysis reaction. The liquid phase slurry has a higher thermal conductivity than pure water.
Temperature dependence of thermal conductivity of biological tissues.
Bhattacharya, A; Mahajan, R L
2003-08-01
In this paper, we present our experimental results on the determination of the thermal conductivity of biological tissues using a transient technique based on the principles of the cylindrical hot-wire method. A novel, 1.45 mm diameter, 50 mm long hot-wire probe was deployed. Initial measurements were made on sponge, gelatin and Styrofoam insulation to test the accuracy of the probe. Subsequent experiments conducted on sheep collagen in the range of 25 degrees C temperature. Further, these changes in the thermal conductivity were found to be reversible. However, when the tissue was heated beyond 55 degrees C, irreversible changes in thermal conductivity were observed. Similar experiments were also conducted for determining the thermal conductivity of cow liver. In this case, the irreversible effects were found to set in much later at around 90 degrees C. Below this temperature, in the range of 25 degrees C temperature. In the second part of our study, in vivo measurements were taken on the different organs of a living pig. Comparison with reported values for dead tissues shows the thermal conductivities of living organs to be higher, indicating thereby the dominant role played by blood perfusion in enhancing the net heat transfer in living tissues. The degree of enhancement is different in different organs and shows a direct dependence on the blood flow rate.
Modified graphite filled natural rubber composites with good thermal conductivity
Institute of Scientific and Technical Information of China (English)
Junping Song; Lianxiang Ma; Yan He; Haiquan Yan; Zan Wu; Wei Li
2015-01-01
The rubber composites with good thermal conductivity contribute to heat dissipation of tires. Graphite filled natural rubber composites were developed in this study to provide good thermal conductivity. Graphite was coated with polyacrylate polymerized by monomers including methyl methacrylate, n-butyl acrylate and acrylic acid. The ratios between a filler and acrylate polymerization emulsion and those between monomers were varied. Eight types of surface modification formulas were experimentally investigated. Modification formula can affect coating results and composite properties greatly. The best coating type was achieved by a ratio of 1:1 between methyl methacrylate and n-butyl acrylate. The coating of graphite was thermal y stable in a running tire. Filled with modified graphite, the tire thermal conductivity reached up to 0.517–0.569 W·m-1·K-1. In addition, the mechanical performance was improved with increased crosslink density, extended scorch time and short vulcanization time.
Coherent thermal conductance of 1-D photonic crystals
Energy Technology Data Exchange (ETDEWEB)
Tschikin, Maria [Institut für Physik, Carl von Ossietzky Universität, D-26111 Oldenburg (Germany); Ben-Abdallah, Philippe [Laboratoire Charles Fabry, UMR 8501, Institut d' Optique, CNRS, Université Paris-Sud, 2, Avenue Augustin Fresnel, RD128, 91127 Palaiseau Cedex (France); Biehs, Svend-Age, E-mail: biehs@theorie.physik.uni-oldenburg.de [Institut für Physik, Carl von Ossietzky Universität, D-26111 Oldenburg (Germany)
2012-10-01
We present an exact calculation of coherent thermal conductance in 1-D multilayer photonic crystals using the S-matrix method. In particular, we study the thermal conductance in a bilayer structure of Si/vacuum or Al{sub 2}O{sub 3}/vacuum slabs by means of the exact radiative heat flux expression. Based on the results obtained for the Al{sub 2}O{sub 3}/vacuum structure we show by comparison with previous works that the material losses and (localized) surface modes supported by the inner layers play a fundamental role and cannot be omitted in the definition of thermal conductance. Our results could have significant implications in the conception of efficient thermal barriers.
Size effects in molecular dynamics thermal conductivity predictions
Sellan, D. P.; Landry, E. S.; Turney, J. E.; McGaughey, A. J. H.; Amon, C. H.
2010-06-01
We predict the bulk thermal conductivity of Lennard-Jones argon and Stillinger-Weber silicon using the Green-Kubo (GK) and direct methods in classical molecular dynamics simulations. While system-size-independent thermal conductivities can be obtained with less than 1000 atoms for both materials using the GK method, the linear extrapolation procedure [Schelling , Phys. Rev. B 65, 144306 (2002)] must be applied to direct method results for multiple system sizes. We find that applying the linear extrapolation procedure in a manner consistent with previous researchers can lead to an underprediction of the GK thermal conductivity (e.g., by a factor of 2.5 for Stillinger-Weber silicon at a temperature of 500 K). To understand this discrepancy, we perform lattice dynamics calculations to predict phonon properties and from these, length-dependent thermal conductivities. From these results, we find that the linear extrapolation procedure is only accurate when the minimum system size used in the direct method simulations is comparable to the largest mean-free paths of the phonons that dominate the thermal transport. This condition has not typically been satisfied in previous works. To aid in future studies, we present a simple metric for determining if the system sizes used in direct method simulations are sufficiently large so that the linear extrapolation procedure can accurately predict the bulk thermal conductivity.
Beating the amorphous limit in thermal conductivity by superlattices design.
Mizuno, Hideyuki; Mossa, Stefano; Barrat, Jean-Louis
2015-09-16
The value measured in the amorphous structure with the same chemical composition is often considered as a lower bound for the thermal conductivity of any material: the heat carriers are strongly scattered by disorder, and their lifetimes reach the minimum time scale of thermal vibrations. An appropriate design at the nano-scale, however, may allow one to reduce the thermal conductivity even below the amorphous limit. In the present contribution, using molecular-dynamics simulation and the Green-Kubo formulation, we study systematically the thermal conductivity of layered phononic materials (superlattices), by tuning different parameters that can characterize such structures. We have discovered that the key to reach a lower-than-amorphous thermal conductivity is to block almost completely the propagation of the heat carriers, the superlattice phonons. We demonstrate that a large mass difference in the two intercalated layers, or weakened interactions across the interface between layers result in materials with very low thermal conductivity, below the values of the corresponding amorphous counterparts.
Robustly Engineering Thermal Conductivity of Bilayer Graphene by Interlayer Bonding.
Zhang, Xiaoliang; Gao, Yufei; Chen, Yuli; Hu, Ming
2016-02-25
Graphene and its bilayer structure are the two-dimensional crystalline form of carbon, whose extraordinary electron mobility and other unique features hold great promise for nanoscale electronics and photonics. Their realistic applications in emerging nanoelectronics usually call for thermal transport manipulation in a controllable and precise manner. In this paper we systematically studied the effect of interlayer covalent bonding, in particular different interlay bonding arrangement, on the thermal conductivity of bilayer graphene using equilibrium molecular dynamics simulations. It is revealed that, the thermal conductivity of randomly bonded bilayer graphene decreases monotonically with the increase of interlayer bonding density, however, for the regularly bonded bilayer graphene structure the thermal conductivity possesses unexpectedly non-monotonic dependence on the interlayer bonding density. The results suggest that the thermal conductivity of bilayer graphene depends not only on the interlayer bonding density, but also on the detailed topological configuration of the interlayer bonding. The underlying mechanism for this abnormal phenomenon is identified by means of phonon spectral energy density, participation ratio and mode weight factor analysis. The large tunability of thermal conductivity of bilayer graphene through rational interlayer bonding arrangement paves the way to achieve other desired properties for potential nanoelectronics applications involving graphene layers.
Discussion on the thermal conductivity enhancement of nanofluids.
Xie, Huaqing; Yu, Wei; Li, Yang; Chen, Lifei
2011-02-09
Increasing interests have been paid to nanofluids because of the intriguing heat transfer enhancement performances presented by this kind of promising heat transfer media. We produced a series of nanofluids and measured their thermal conductivities. In this article, we discussed the measurements and the enhancements of the thermal conductivity of a variety of nanofluids. The base fluids used included those that are most employed heat transfer fluids, such as deionized water (DW), ethylene glycol (EG), glycerol, silicone oil, and the binary mixture of DW and EG. Various nanoparticles (NPs) involving Al2O3 NPs with different sizes, SiC NPs with different shapes, MgO NPs, ZnO NPs, SiO2 NPs, Fe3O4 NPs, TiO2 NPs, diamond NPs, and carbon nanotubes with different pretreatments were used as additives. Our findings demonstrated that the thermal conductivity enhancements of nanofluids could be influenced by multi-faceted factors including the volume fraction of the dispersed NPs, the tested temperature, the thermal conductivity of the base fluid, the size of the dispersed NPs, the pretreatment process, and the additives of the fluids. The thermal transport mechanisms in nanofluids were further discussed, and the promising approaches for optimizing the thermal conductivity of nanofluids have been proposed.
Energy Technology Data Exchange (ETDEWEB)
Wang, Hsin [ORNL; Porter, Wallace D [ORNL; Bottner, Harold [Fraunhofer-Institute, Freiburg, Germany; Konig, Jan [Fraunhofer-Institute, Freiburg, Germany; Chen, Lidong [Chinese Academy of Sciences; Bai, Shengqiang [Chinese Academy of Sciences; Tritt, Terry M. [Clemson University; Mayolett, Alex [Corning, Inc; Senawiratne, Jayantha [Corning, Inc; Smith, Charlene [Corning, Inc; Harris, Fred [ZT-Plus; Gilbert, Partricia [Marlow Industries, Inc; Sharp, J [Marlow Industries, Inc; Lo, Jason [CANMET - Materials Technology Laboratory, Natural Resources of Canada; Keinke, Holger [University of Waterloo, Canada; Kiss, Laszlo I. [University of Quebec at Chicoutimi
2013-01-01
For bulk thermoelectrics, figure-of-merit, ZT, still needs to improve from the current value of 1.0 - 1.5 to above 2 to be competitive to other alternative technologies. In recent years, the most significant improvements in ZT were mainly due to successful reduction of thermal conductivity. However, thermal conductivity cannot be measured directly at high temperatures. The combined measurements of thermal diffusivity and specific heat and density are required. It has been shown that thermal conductivity is the property with the greatest uncertainty and has a direct influence on the accuracy of the figure of merit. The International Energy Agency (IEA) group under the implementing agreement for Advanced Materials for Transportation (AMT) has conducted two international round-robins since 2009. This paper is Part II of the international round-robin testing of transport properties of bulk bismuth telluride. The main focuses in Part II are on thermal diffusivity, specific heat and thermal conductivity.
Thermal conductivity enhancement of laser induced graphene foam upon P3HT infiltration
Smith, M. K.; Luong, D. X.; Bougher, T. L.; Kalaitzidou, K.; Tour, J. M.; Cola, B. A.
2016-12-01
Significant research has been dedicated to the exploration of high thermal conductivity polymer composite materials with conductive filler particles for use in heat transfer applications. However, poor particle dispersibility and interfacial phonon scattering have limited the effective composite thermal conductivity. Three-dimensional foams with high ligament thermal conductivity offer a potential solution to the two aforementioned problems but are traditionally fabricated through expensive and/or complex manufacturing methods. Here, laser induced graphene foams, fabricated through a simple and cost effective laser ablation method, are infiltrated with poly(3-hexylthiophene) in a step-wise fashion to demonstrate the impact of polymer on the thermal conductivity of the composite system. Surprisingly, the addition of polymer results in a drastic (250%) improvement in material thermal conductivity, enhancing the graphene foam's thermal conductivity from 0.68 W/m-K to 1.72 W/m-K for the fully infiltrated composite material. Graphene foam density measurements and theoretical models are utilized to estimate the effective ribbon thermal conductivity as a function of polymer filling. Here, it is proposed that the polymer solution acts as a binding material, which draws graphene ligaments together through elastocapillary coalescence and bonds these ligaments upon drying, resulting in greatly reduced contact resistance within the foam and an effective thermal conductivity improvement greater than what would be expected from the addition of polymer alone.
Directory of Open Access Journals (Sweden)
C. Mahesh
2013-01-01
Full Text Available Finite element method is effectively used to homogenize the thermal conductivity of FRP composites consisting of hybrid materials and fibre-matrix debonds at some of the fibres. The homogenized result at microlevel is used to determine the property of the layer using macromechanics principles; thereby, it is possible to minimize the computational efforts required to solve the problem as in state through only micromechanics approach. The working of the proposed procedure is verified for three different problems: (i hybrid composite having two different fibres in alternate layers, (ii fibre-matrix interface debond in alternate layers, and (iii fibre-matrix interface debond at one fibre in a group of four fibres in one unit cell. It is observed that the results are in good agreement with those obtained through pure micro-mechanics approach.
A MICROMECHANICAL MODEL FOR DAMAGE AND THERMAL CONDUCTIVITY OF BRITTLE ROCKS%脆性岩石损伤与热传导特性的细观力学模型
Institute of Scientific and Technical Information of China (English)
陈益峰; 李典庆; 荣冠; 姜清辉; 周创兵
2011-01-01
基于均匀化方法给出低孔隙率脆性岩石在热-力耦合荷载作用条件下的各向异性损伤模型和有效热传导特性模型.其中,损伤模型可考虑非等温条件下裂纹的法向压缩变形、刚度恢复以及裂纹的滑动剪胀特性,热传导特性模型可反映损伤过程中细观结构的演化以及裂纹形态、孔隙率和饱和度变化对岩石有效热传导特性的影响.讨论低孔隙率结晶岩裂纹形态和饱和度对其有效热传导特性的影响；采用瑞典(A)sp(o)闪长岩在三轴压缩条件下的应力-应变曲线验证损伤模型的有效性,并分析岩石在损伤演化过程中裂纹体积率、密度、形态、饱和度和有效热传导特性的演化规律.研究成果对于深部岩体的热-力耦合特性研究具有一定参考意义.%An anisotropic damage model and an effective thermal conductivity model were presented based on homogenization techniques for low-porosity brittle rocks subjected to mechanical and thermal loadings. The thermal effect, the recovery of normal stiffness and the mobilized dilatancy behavior were incorporated in the damage model. The thermal conductivity model took into account the effects of damage-induced microstructure evolution, crack shape, porosity and saturation degree on the effective thermal conductivity of brittle rocks. The influences of crack shape and saturation degree on the effective thermal conductivity of low-porosity crystallized rocks were particularly discussed. The damage model was validated by the triaxial test data on an intact Aspo diorite; and the evolutions of porosity, crack density, crack shape, saturation degree and the effective thermal conductivity during the mechanical loading were demonstrated. The results may provide a helpful reference for better understanding the coupled thermo-mechanical behaviors of deep rocks.
Performance of thermal conductivity probes for planetary applications
Directory of Open Access Journals (Sweden)
E. S. Hütter
2012-01-01
Full Text Available This work aims to contribute to the development of in situ instruments feasible for space application. Commercial as well as custom made thermal sensors, based on the transient hot wire technique and suitable for direct measurement of the effective thermal conductivity of granular media, were tested for application under airless conditions. The investigated media range from compact specimen of well known thermal conductivity used for calibration of the sensors to various granular planetary analogue materials of different shape and grain size. Measurements were performed under gas pressures ranging from 103 hPa down to about 10−5 hPa. It was found that for the inspected granular materials the given pressure decrease results in a decrease of the thermal conductivity by about two orders of magnitude. In order to check the ability of custom-made sensors to measure the thermal conductivity of planetary surface layers, detailed numerical simulations predicting the response of the different sensors have also been performed. Both, measurements and simulations, revealed that for investigations under high vacuum conditions (as they prevail e.g. on the lunar surface the derived thermal conductivity values can significantly depend on the sensor geometry, the axial heat flow and the thermal contact between probe and surrounding material. Therefore in these cases a careful calibration of each particular sensor is necessary in order to obtain reliable thermal conductivity measurements. The custom-made sensors presented in this work can serve as prototypes for payload to be flown on future planetary lander missions, in particular for airless bodies like the Moon, asteroids and comets, but also for Mars.
Measurements of interfacial thermal contact conductance between pressed alloys at low temperatures
Zheng, Jiang; Li, Yanzhong; Chen, Pengwei; Yin, Geyuan; Luo, Huaihua
2016-12-01
Interfacial thermal contact conductance is the primary factor limiting the heat transfer in many cryogenic engineering applications. This paper presents an experimental apparatus to measure interfacial thermal contact conductance between pressed alloys in a vacuum environment at low temperatures. The measurements of thermal contact conductance between pressed alloys are conducted by using the developed apparatus. The results show that the contact conductance increases with the decrease of surface roughness, the increase of interface temperature and contact pressure. The temperature dependence of thermal conductivity and mechanical properties is analyzed to explain the results. Thermal contact conductance of a pair of stainless steel specimens is obtained in the interface temperature range of 135-245 K and in the contact pressure range of 1-9 MPa. The results are regressed as a power function of temperature and load. Thermal conductance is also obtained between aluminums as well as between stainless steel and aluminum. The load exponents of the regressed relations for different contacts are compared. Existing theoretical models (the Cooper-Mikic-Yovanovich plastic model, the Mikic elastic model and the improved Kimura model) are reviewed and compared with the experimental results. The Cooper-Mikic-Yovanovich model predictions are found to be in good agreement with experimental results, especially with measurements between aluminums.
Experimental Preparation and Numerical Simulation of High Thermal Conductive Cu/CNTs Nanocomposites
Directory of Open Access Journals (Sweden)
Muhsan Ali Samer
2014-07-01
Full Text Available Due to the rapid growth of high performance electronics devices accompanied by overheating problem, heat dissipater nanocomposites material having ultra-high thermal conductivity and low coefficient of thermal expansion was proposed. In this work, a nanocomposite material made of copper (Cu reinforced by multi-walled carbon nanotubes (CNTs up to 10 vol. % was prepared and their thermal behaviour was measured experimentally and evaluated using numerical simulation. In order to numerically predict the thermal behaviour of Cu/CNTs composites, three different prediction methods were performed. The results showed that rules of mixture method records the highest thermal conductivity for all predicted composites. In contrast, the prediction model which takes into account the influence of the interface thermal resistance between CNTs and copper particles, has shown the lowest thermal conductivity which considered as the closest results to the experimental measurement. The experimentally measured thermal conductivities showed remarkable increase after adding 5 vol.% CNTs and higher than the thermal conductivities predicted via Nan models, indicating that the improved fabrication technique of powder injection molding that has been used to produced Cu/CNTs nanocomposites has overcome the challenges assumed in the mathematical models.
Calibration of non-ideal thermal conductivity sensors
Directory of Open Access Journals (Sweden)
N. I. Kömle
2012-09-01
Full Text Available A popular method for measuring the thermal conductivity of solid materials is the transient heated needle method. It allows to evaluate the thermal conductivity of a solid or granular material to be evaluated simply by combining a temperature measurement with a well-defined electrical current flowing through a resistance wire enclosed in a long and thin needle. Standard laboratory sensors that are typically used in laboratory work consist of very thin steel needles with a large length-to-diameter ratio. This type of needles is convenient since it is mathematically easy to derive the thermal conductivity of a soft granular material from a simple temperature measurement. However, such a geometry often results in a mechanically weak sensor, which can bend or fail when inserted into a material that is harder than expected. For deploying such a sensor on a planetary surface, with often unknown soil properties, it is necessary to construct more rugged sensors. These requirements can lead to a design which differs substantially from the ideal geometry, and additional care must be taken in the calibration and data analysis. In this paper we present the performance of a prototype thermal conductivity sensor designed for planetary missions. The thermal conductivity of a suite of solid and granular materials was measured both by a standard needle sensor and by several customized sensors with non-ideal geometry. We thus obtained a calibration curve for the non-ideal sensors. The theory describing the temperature response of a sensor with such unfavorable length-to-diameter ratio is complicated and highly nonlinear. However, our measurements reveal that over a wide range of thermal conductivities there is an almost linear relationship between the result obtained by the standard sensor and the result derived from the customized, non-ideal sensors. This allows to measure thermal conductivity values for harder soils, which are not easily accessible when using
Calibration of non-ideal thermal conductivity sensors
Directory of Open Access Journals (Sweden)
N. I. Kömle
2013-04-01
Full Text Available A popular method for measuring the thermal conductivity of solid materials is the transient hot needle method. It allows the thermal conductivity of a solid or granular material to be evaluated simply by combining a temperature measurement with a well-defined electrical current flowing through a resistance wire enclosed in a long and thin needle. Standard laboratory sensors that are typically used in laboratory work consist of very thin steel needles with a large length-to-diameter ratio. This type of needle is convenient since it is mathematically easy to derive the thermal conductivity of a soft granular material from a simple temperature measurement. However, such a geometry often results in a mechanically weak sensor, which can bend or fail when inserted into a material that is harder than expected. For deploying such a sensor on a planetary surface, with often unknown soil properties, it is necessary to construct more rugged sensors. These requirements can lead to a design which differs substantially from the ideal geometry, and additional care must be taken in the calibration and data analysis. In this paper we present the performance of a prototype thermal conductivity sensor designed for planetary missions. The thermal conductivity of a suite of solid and granular materials was measured both by a standard needle sensor and by several customized sensors with non-ideal geometry. We thus obtained a calibration curve for the non-ideal sensors. The theory describing the temperature response of a sensor with such unfavorable length-to-diameter ratio is complicated and highly nonlinear. However, our measurements reveal that over a wide range of thermal conductivities there is an almost linear relationship between the result obtained by the standard sensor and the result derived from the customized, non-ideal sensors. This allows for the measurement of thermal conductivity values for harder soils, which are not easily accessible when using
Effect of functional groups on thermal conductivity of graphene/paraffin nanocomposite
Energy Technology Data Exchange (ETDEWEB)
Zabihi, Zabiholah; Araghi, Houshang, E-mail: araghi@aut.ac.ir
2016-11-25
In this paper, thermal conductivity of graphene/paraffin nanocomposite using micromechanical model has been studied. The behavior of thermal conductivity of nanocomposite as a function of volume fraction of graphene is studied. Then is shown that as the interfacial thermal resistance at the graphene–paraffin interface decreases, the thermal conductivity of nanocomposite increases. In order to reduce the interfacial thermal resistance, functional groups in the interface between graphene and paraffin are used. It can be observed that using functional groups of hydrogen, methyl and phenyl in the interface of nanocomposite, contributes to the improvement of the thermal conductivity. Moreover, as the rate of coverage of the surface of graphene with functional groups of H, CH{sub 3} and C{sub 6}H{sub 5} increases, the thermal conductivity of nanocomposite improves. - Highlights: • Thermal conductivity nanocomposite exhibit nonlinear behavior with volume faction. • Phenyl is better to form the thermal conductivity network in paraffin. • The thickness of interfacial layer can be obtained 12.75 nm.
Thermal Conductivity of Suspension of Aggregating Nanometric Rods
Directory of Open Access Journals (Sweden)
Amine Ammar
2016-12-01
Full Text Available Enhancing thermal conductivity of simple fluids is of major interest in numerous applicative systems. One possibility of enhancing thermal properties consists of dispersing small conductive particles inside. However, in general, aggregation effects occur and then one must address systems composed of dispersed clusters composed of particles as well as the ones related to percolated networks. This papers analyzes the conductivity enhancement of different microstructures scaling from clusters dispersed into a simple matrix to the ones related to percolated networks exhibiting a fractal morphology.
Effective Thermal Conductivity of MOF-5 Powder under a Hydrogen Atmosphere
Hui Wang; Zhiguo Qu; Wen Zhang; Wenquan Tao
2015-01-01
Effective thermal conductivity is an important thermophysical property in the design of metal-organic framework-5 (MOF-5)-based hydrogen storage tanks. A modified thermal conductivity model is built by coupling a theoretical model with the grand canonical Monte Carlo simulation (GCMC) to predict the effect of the H2 adsorption process on the effective thermal conductivity of a MOF-5 powder bed at pressures ranging from 0.01 MPa to 50 MPa and temperatures ranging from 273.15 K to 368.15 K. Re...
Interfacial Thermal Conductance of Thiolate-Protected Gold Nanospheres
Stocker, Kelsey M; Gezelter, J Daniel
2016-01-01
Molecular dynamics simulations of thiolate-protected and solvated gold nanoparticles were carried out in the presence of a non-equilibrium heat flux between the solvent and the core of the particle. The interfacial thermal conductance ($G$) was computed for these interfaces, and the behavior of the thermal conductance was studied as a function of particle size, ligand flexibility, and ligand chain length. In all cases, thermal conductance of the ligand-protected particles was higher than the bare metal-solvent interface. A number of mechanisms for the enhanced conductance were investigated, including thiolate-driven corrugation of the metal surface, solvent ordering at the interface, solvent-ligand interpenetration, and ligand ordering relative to the particle surface. Only the smallest particles exhibited significant corrugation. All ligands permitted substantial solvent-ligand interpenetration, and ligand chain length has a significant influence on the orientational ordering of interfacial solvent. Solvent-...
Bulk thermal conductivity of composites with spherical inclusions
Sangani, A. S.; Yao, C.
1988-03-01
The problem of determining the bulk or effective thermal conductivity of a two-phase composite material whose unit cells contain N(N>1) spherical particles of thermal conductivity αk suspended in a medium of thermal conductivity k has been treated by extending an earlier analysis of McPhedran and Milton [Appl. Phys. A 26, 207 (1981)] who considered the case N=1. The technique is applied to computer-generated two-phase composites with N=16 whose radial distribution functions approximately satisfy the Percus-Yevick equation. The results, which are presented for a wide range of α and φ (the volume fraction of the spheres), are shown to be in good agreement with the experimental values of conductivity of fluidized beds reported by Turner [Chem. Eng. Sci. 31, 487 (1976)].
Anisotropy of thermal conductivity in YBaCuO single crystals
Gusakov, V.; Jezowski, A.; Barilo, S.; Kalanda, N.; Saiko, A.
2000-11-01
The anisotropy of thermal conductivity (k) in single crystals YBa 2Cu 3O 7 have been studied. The temperature dependence of k in c-direction is well described by the lattice thermal conductivity ( Tmax = 60K; k max = 4W/mK; T D = 140K). The precise measurements reveal the hysteretic behavior of out-of-plane thermal conductivity. In ab-direction the upturn in k for temperatures below T c is observed and temperatures of thermal conductivity peaks in ab- and c-direction are coincided. Theoretical analysis suggests a model in which an observed peak below T c in thermal conductivity for ab-direction is ascribed to a quasiparticle contribution.
Anisotropy of thermal conductivity in single crystals YBa 2Cu 3O 7
Gusakov, Vasilii; Jezowski, Andrzej; Barilo, Sergey; Kalanda, Nikolay; Saiko, Alexandr
2000-07-01
The anisotropy of thermal conductivity k in single crystals YBa 2Cu 3O 7 has been studied. The temperature dependence of k in c-direction is well described by the lattice thermal conductivity ( T max=60 K; k max=4 W/ mK; T D=140 K) . The precise measurements reveal the hysteretic behavior of out-of-plane thermal conductivity. In ab-direction the upturn in k for temperatures below Tc is observed and temperatures of thermal conductivity peaks in ab- and c-direction coincide. Theoretical analysis suggests a model in which an observed peak below Tc in thermal conductivity for ab-direction is ascribed to a quasiparticle contribution.
A Novel Approach for the Effective Thermal Conductivity of Porous Ceramics
Institute of Scientific and Technical Information of China (English)
ZHU Qiang; ZHANG Fan-wei; ZHANG Yue; ZHANG Da-hai; LI Zhong-ping
2006-01-01
A new approach in combination of the effective medium theory with the equivalent unit in numerical simulation was developed to study the effective thermal conductivity of porous ceramics. The finite element method was used to simulate the heat transfer process which enables to acquire accurate results through highly complicated modeling and intensive computation. An alternative approach to mesh the material into small cells was also presented. The effective medium theory accounts for the effective thermal conductivity of cells while the equivalent unit is subsequently applied in numerical simulation to analyze the effective thermal conductivity of the porous ceramics. A new expression for the effective thermal conductivity, allowing for some structure factors such as volume fraction of pores and thermal conductivity, was put forward, and the results of its application was proved to be close to those of the mathematical simulation.
Energy Technology Data Exchange (ETDEWEB)
Oh, Sun Ryung; Park, Hyun Sun [POSTECH, Pohang (Korea, Republic of); Kim, Moo Hwan [KAERI, Daejeon (Korea, Republic of)
2016-05-15
The sodium-cooled fast reactor (SFR) is one of generation IV type reactors and has been extensively researched since 1950s. A strong advantage of the SFR is its liquid sodium coolant which is well-known for its superior thermal properties. However, in terms of possible pipe leakage or rupture, a liquid sodium coolant possesses a critical issue due to its high chemical reactivity which leads to fire or explosion. Due to its safety concerns, dispersion of nanoparticles in liquid sodium has been proposed to reduce the chemical reactivity of sodium. In case of sodium based titanium nanofluid (NaTiNF), the chemical reactivity suppression effect when interacting with water has been proved both experimentally and theoretically [1,2]. Suppression of chemical reactivity is critical without much loss of high heat transfer characteristic of sodium. As there is no research conducted for applying 3-omega sensor in liquid metal as well as high temperature liquid, the sensor development is performed for using in NaTiNF as well as effective thermal conductivity model validation. Based on the acquired effective thermal conductivity of NaTiNF, existing effective thermal conductivity models are evaluated. Thermal conductivity measurement is performed for liquid sodium based titanium nanofluid (NaTiNF) through 3-Omega method. The experiment is conducted at three temperature points of 120, 150, and 180 .deg. C for both pure liquid sodium and NaTiNF. By using 3- omega sensor, thermal conductivity measurement of liquid metal can be more conveniently conducted in labscale. Also, its possibility to measure the thermal conductivity of high temperature liquid metal with metallic nanoparticles being dispersed is shown. Unlike other water or oil-based nanofluids, NaTiNF exhibits reduction of thermal conductivity compare with liquid sodium. Various nanofluid models are plotted, and it is concluded that the MSBM which considers interfacial resistance and Brownian motion can be used in predicting
Development of Advanced Low Conductivity Thermal Barrier Coatings
Zhu, Dong-Ming; Miller, Robert A.
2004-01-01
Advanced multi-component, low conductivity oxide thermal barrier coatings have been developed using an approach that emphasizes real-time monitoring of thermal conductivity under conditions that are engine-like in terms of temperatures and heat fluxes. This is in contrast to the traditional approach where coatings are initially optimized in terms of furnace and burner rig durability with subsequent measurement in the as-processed or furnace-sintered condition. The present work establishes a laser high-heat-flux test as the basis for evaluating advanced plasma-sprayed and electron beam-physical vapor deposited (EB-PVD) thermal barrier coatings under the NASA Ultra-Efficient Engine Technology (UEET) Program. The candidate coating materials for this program are novel thermal barrier coatings that are found to have significantly reduced thermal conductivities and improved thermal stability due to an oxide-defect-cluster design. Critical issues for designing advanced low conductivity coatings with improved coating durability are also discussed.
Performance of thermal conductivity probes for planetary applications
Directory of Open Access Journals (Sweden)
E. S. Hütter
2012-05-01
Full Text Available This work aims to contribute to the development of in situ instruments feasible for space application. Commercial as well as custom-made thermal sensors, based on the transient hot wire technique and suitable for direct measurement of the effective thermal conductivity of granular media, were tested for application under airless conditions. In order to check the ability of custom-made sensors to measure the thermal conductivity of planetary surface layers, detailed numerical simulations predicting the response of the different sensors have been performed. These simulations reveal that for investigations under high vacuum conditions (as they prevail, e.g. on the lunar surface, the derived thermal conductivity values can significantly depend on sensor geometry, axial heat flow, and the thermal contact between probe and surrounding material. Therefore, a careful calibration of each particular sensor is necessary in order to obtain reliable thermal conductivity measurements. The custom-made sensors presented in this work can serve as prototypes for payload to be flown on future planetary lander missions, in particular for airless bodies like the Moon, asteroids and comets, but also for Mars.
Fuel Cell Thermal Management Through Conductive Cooling Plates
Colozza, Anthony J.; Burke, Kenneth A.
2008-01-01
An analysis was performed to evaluate the concept of utilizing conductive cooling plates to remove heat from a fuel cell stack, as opposed to a conventional internal cooling loop. The potential advantages of this type of cooling system are reduced stack complexity and weight and increased reliability through the reduction of the number of internal fluid seals. The conductive cooling plates would extract heat from the stack transferring it to an external coolant loop. The analysis was performed to determine the required thickness of these plates. The analysis was based on an energy balance between the thermal energy produced within the stack and the heat removal from the cooling plates. To accomplish the energy balance, the heat flow into and along the plates to the cooling fluid was modeled. Results were generated for various numbers of cells being cooled by a single cooling plate. The results provided cooling plate thickness, mass, and operating temperature of the plates. It was determined that utilizing high-conductivity pyrolitic graphite cooling plates can provide a specific cooling capacity (W/kg) equivalent to or potentially greater than a conventional internal cooling loop system.
Thermal conductivity of major rock types in western and central Anatolia regions, Turkey
Balkan, Elif; Erkan, Kamil; Şalk, Müjgan
2017-08-01
Thermal conductivity is a key parameter in heat flow and geothermal investigations as it controls the temperature distribution within the Earth. Turkey has a significant geothermal potential yet rock thermal conductivity studies have been very limited. Here, we report new thermal conductivity values collected from 240 rock samples in western and central Anatolia regions. The data were initially classified according to lithologic descriptions; then mean thermal conductivities were determined after applying corrections from dry to saturated conditions, if necessary. The major rock types encountered in these regions are igneous metamorphic, and sedimentary rocks. Limestone is the most common lithological unit encountered both in western and central Anatolia regions. The limestones in western Anatolia show a higher mean thermal conductivity than the limestones in central Anatolia. Dolomitization has a significant effect on the thermal conductivity of limestones. Neritic limestones show a higher mean thermal conductivity compared to lacustrine limestones. The results of this study reveal large contrasts in thermal conductivity values among different rock types that can have major implications for future heat flow and geothermal modeling studies in these regions.
Thermal signal propagation in soils in Romania: conductive and non-conductive processes
Directory of Open Access Journals (Sweden)
C. Demetrescu
2007-11-01
Full Text Available Temperature data recorded in 2002 and 2003 at 10 stations out of the 70 available in the Romanian automatic weather stations network are presented and analyzed in terms of the heat transfer from air to underground. The air temperature at 2 m, the soil temperatures at 0, 5, 10, 20, 50 and 100 cm below the surface as well as rain fall and snow cover thickness have been monitored. The selected locations sample various climate environments in Romania. Preliminary analytical modelling shows that soil temperatures track air temperature variations at certain locations and, consequently, the heat transfer is by conduction, while at other stations processes such as soil freezing and/or solar radiation heating play an important part in the heat flux balance at the air/soil interface. However, the propagation of the annual thermal signal in the uppermost one meter of soil is mainly by conduction; the inferred thermal diffusivity for 8 stations with continuous time series at all depth levels ranges from 3 to 10×10^{−7} m^{2} s^{−1}.
Reduction of thermal conductivity in phononic nanomesh structures
Yu, Jen-Kan
2010-07-25
Controlling the thermal conductivity of a material independently of its electrical conductivity continues to be a goal for researchers working on thermoelectric materials for use in energy applications1,2 and in the cooling of integrated circuits3. In principle, the thermal conductivity κ and the electrical conductivity σ may be independently optimized in semiconducting nanostructures because different length scales are associated with phonons (which carry heat) and electric charges (which carry current). Phonons are scattered at surfaces and interfaces, so κ generally decreases as the surface-to-volume ratio increases. In contrast, σ is less sensitive to a decrease in nanostructure size, although at sufficiently small sizes it will degrade through the scattering of charge carriers at interfaces. Here, we demonstrate an approach to independently controlling κ based on altering the phonon band structure of a semiconductor thin film through the formation of a phononic nanomesh film. These films are patterned with periodic spacings that are comparable to, or shorter than, the phonon mean free path. The nanomesh structure exhibits a substantially lower thermal conductivity than an equivalently prepared array of silicon nanowires, even though this array has a significantly higher surface-to-volume ratio. Bulk-like electrical conductivity is preserved. We suggest that this development is a step towards a coherent mechanism for lowering thermal conductivity. © 2010 Macmillan Publishers Limited. All rights reserved.
Divergent and Ultrahigh Thermal Conductivity in Millimeter-Long Nanotubes
Lee, Victor; Wu, Chi-Hsun; Lou, Zong-Xing; Lee, Wei-Li; Chang, Chih-Wei
2017-03-01
Low-dimensional materials could display anomalous thermal conduction that the thermal conductivity (κ ) diverges with increasing lengths, in ways inconceivable in any bulk materials. However, previous theoretical or experimental investigations were plagued with many finite-size effects, rendering the results either indirect or inconclusive. Indeed, investigations on the anomalous thermal conduction must demand the sample length to be sufficiently long so that the phenomena could emerge from unwanted finite-size effects. Here we report experimental observations that the κ 's of single-wall carbon nanotubes continuously increase with their lengths over 1 mm, reaching at least 8640 W /mK at room temperature. Remarkably, the anomalous thermal conduction persists even with the presence of defects, isotopic disorders, impurities, and surface absorbates. Thus, we demonstrate that the anomalous thermal conduction in real materials can persist over much longer distances than previously thought. The finding would open new regimes for wave engineering of heat as well as manipulating phonons at macroscopic scales.
On the thermal conductivity of gold nanoparticle colloids.
Shalkevich, Natallia; Escher, Werner; Bürgi, Thomas; Michel, Bruno; Si-Ahmed, Lynda; Poulikakos, Dimos
2010-01-19
Nanofluids (colloidal suspensions of nanoparticles) have been reported to display significantly enhanced thermal conductivities relative to those of conventional heat transfer fluids, also at low concentrations well below 1% per volume (Putnam, S. A., et at. J. Appl. Phys. 2006, 99, 084308; Liu, M.-S. L., et al. Int. J. Heat Mass Transfer. 2006, 49; Patel, H. E., et al. Appl. Phys. Lett. 2003, 83, 2931-2933). The purpose of this paper is to evaluate the effect of the particle size, concentration, stabilization method and particle clustering on the thermal conductivity of gold nanofluids. We synthesized spherical gold nanoparticles of different size (from 2 to 45 nm) and prepared stable gold colloids in the range of volume fraction of 0.00025-1%. The colloids were inspected by UV-visible spectroscopy, transmission electron microscope (TEM) and dynamic light scattering (DLS). The thermal conductivity has been measured by the transient hot-wire method (THW) and the steady state parallel plate method (GAP method). Despite a significant search in parameter space no significant anomalous enhancement of thermal conductivity was observed. The highest enhancement in thermal conductivity is 1.4% for 40 nm sized gold particles stabilized by EGMUDE (triethyleneglycolmono-11-mercaptoundecylether) and suspended in water with a particle-concentration of 0.11 vol%.
Lv, Wei; Henry, Asegun
2016-10-01
Thermal conductivity is important for almost all applications involving heat transfer. The theory and modeling of crystalline materials is in some sense a solved problem, where one can now calculate their thermal conductivity from first principles using expressions based on the phonon gas model (PGM). However, modeling of amorphous materials still has many open questions, because the PGM itself becomes questionable when one cannot rigorously define the phonon velocities. In this report, we used our recently developed Green-Kubo modal analysis (GKMA) method to study amorphous silicon dioxide (a-SiO2). The predicted thermal conductivities exhibit excellent agreement with experiments and anharmonic effects are included in the thermal conductivity calculation for all the modes in a-SiO2 for the first time. Previously, localized modes (locons) have been thought to have a negligible contribution to thermal conductivity, due to their highly localized nature. However, in a-SiO2 our results indicate that locons contribute more than 10% to the total thermal conductivity from 400 K to 800 K and they are largely responsible for the increase in thermal conductivity of a-SiO2 above room temperature. This is an effect that cannot be explained by previous methods and therefore offers new insight into the nature of phonon transport in amorphous/glassy materials.
Lv, Wei; Henry, Asegun
2016-10-21
Thermal conductivity is important for almost all applications involving heat transfer. The theory and modeling of crystalline materials is in some sense a solved problem, where one can now calculate their thermal conductivity from first principles using expressions based on the phonon gas model (PGM). However, modeling of amorphous materials still has many open questions, because the PGM itself becomes questionable when one cannot rigorously define the phonon velocities. In this report, we used our recently developed Green-Kubo modal analysis (GKMA) method to study amorphous silicon dioxide (a-SiO2). The predicted thermal conductivities exhibit excellent agreement with experiments and anharmonic effects are included in the thermal conductivity calculation for all the modes in a-SiO2 for the first time. Previously, localized modes (locons) have been thought to have a negligible contribution to thermal conductivity, due to their highly localized nature. However, in a-SiO2 our results indicate that locons contribute more than 10% to the total thermal conductivity from 400 K to 800 K and they are largely responsible for the increase in thermal conductivity of a-SiO2 above room temperature. This is an effect that cannot be explained by previous methods and therefore offers new insight into the nature of phonon transport in amorphous/glassy materials.
Validation of thermal models for a prototypical MEMS thermal actuator.
Energy Technology Data Exchange (ETDEWEB)
Gallis, Michail A.; Torczynski, John Robert; Piekos, Edward Stanley; Serrano, Justin Raymond; Gorby, Allen D.; Phinney, Leslie Mary
2008-09-01
This report documents technical work performed to complete the ASC Level 2 Milestone 2841: validation of thermal models for a prototypical MEMS thermal actuator. This effort requires completion of the following task: the comparison between calculated and measured temperature profiles of a heated stationary microbeam in air. Such heated microbeams are prototypical structures in virtually all electrically driven microscale thermal actuators. This task is divided into four major subtasks. (1) Perform validation experiments on prototypical heated stationary microbeams in which material properties such as thermal conductivity and electrical resistivity are measured if not known and temperature profiles along the beams are measured as a function of electrical power and gas pressure. (2) Develop a noncontinuum gas-phase heat-transfer model for typical MEMS situations including effects such as temperature discontinuities at gas-solid interfaces across which heat is flowing, and incorporate this model into the ASC FEM heat-conduction code Calore to enable it to simulate these effects with good accuracy. (3) Develop a noncontinuum solid-phase heat transfer model for typical MEMS situations including an effective thermal conductivity that depends on device geometry and grain size, and incorporate this model into the FEM heat-conduction code Calore to enable it to simulate these effects with good accuracy. (4) Perform combined gas-solid heat-transfer simulations using Calore with these models for the experimentally investigated devices, and compare simulation and experimental temperature profiles to assess model accuracy. These subtasks have been completed successfully, thereby completing the milestone task. Model and experimental temperature profiles are found to be in reasonable agreement for all cases examined. Modest systematic differences appear to be related to uncertainties in the geometric dimensions of the test structures and in the thermal conductivity of the
Thermal conductivity as influenced by the temperature and apparent viscosity of dairy products.
Gonçalves, B J; Pereira, C G; Lago, A M T; Gonçalves, C S; Giarola, T M O; Abreu, L R; Resende, J V
2017-03-02
This study aimed to evaluate the rheological behavior and thermal conductivity of dairy products, composed of the same chemical components but with different formulations, as a function of temperature. Subsequently, thermal conductivity was related to the apparent viscosity of yogurt, fermented dairy beverage, and fermented milk. Thermal conductivity measures and rheological tests were performed at 5, 10, 15, 20, and 25°C using linear probe heating and an oscillatory rheometer with concentric cylinder geometry, respectively. The results were compared with those calculated using the parallel, series, and Maxwell-Eucken models as a function of temperature, and the discrepancies in the results are discussed. Linear equations were fitted to evaluate the influence of temperature on the thermal conductivity of the dairy products. The rheological behavior, specifically apparent viscosity versus shear rate, was influenced by temperature. Herschel-Bulkley, power law, and Newton's law models were used to fit the experimental data. The Herschel-Bulkley model best described the adjustments for yogurt, the power law model did so for fermented dairy beverages, and Newton's law model did so for fermented milk and was then used to determine the rheological parameters. Fermented milk showed a Newtonian trend, whereas yogurt and fermented dairy beverage were shear thinning. Apparent viscosity was correlated with temperature by the Arrhenius equation. The formulation influenced the effective thermal conductivity. The relationship between the 2 properties was established by fixing the temperature and expressing conductivity as a function of apparent viscosity. Thermal conductivity increased with viscosity and decreased with increasing temperature.
Spectral mapping of thermal conductivity through nanoscale ballistic transport.
Hu, Yongjie; Zeng, Lingping; Minnich, Austin J; Dresselhaus, Mildred S; Chen, Gang
2015-08-01
Controlling thermal properties is central to many applications, such as thermoelectric energy conversion and the thermal management of integrated circuits. Progress has been made over the past decade by structuring materials at different length scales, but a clear relationship between structure size and thermal properties remains to be established. The main challenge comes from the unknown intrinsic spectral distribution of energy among heat carriers. Here, we experimentally measure this spectral distribution by probing quasi-ballistic transport near nanostructured heaters down to 30 nm using ultrafast optical spectroscopy. Our approach allows us to quantify up to 95% of the total spectral contribution to thermal conductivity from all phonon modes. The measurement agrees well with multiscale and first-principles-based simulations. We further demonstrate the direct construction of mean free path distributions. Our results provide a new fundamental understanding of thermal transport and will enable materials design in a rational way to achieve high performance.
Zhang, Teng; Luo, Tengfei
2014-01-01
Polymer nanofibers with high thermal conductivities and outstanding thermal stabilities are highly desirable in heat transfer-critical applications such as thermal management, heat exchangers and energy storage. In this work, we unlock the fundamental relations between the thermal conductivity and thermal stability of polymer nanofibers and their molecular characteristics by studying the temperature-induced phase transitions and thermal transport of a series of polymer nanofibers. Ten different polymer nanofibers with systematically chosen molecular structures are studied using large scale molecular dynamics simulations. We found that high thermal conductivity and good thermal stability can be achieved in polymers with rigid backbones, exemplified by {\\pi}-conjugated polymers, due to suppressed segmental rotations and large phonon group velocities. The low probability of segmental rotation does not only prevent temperature-induced phase transition but also enables long phonon mean free paths due to reduced di...
The influence of the solid thermal conductivity on active magnetic regenerators
DEFF Research Database (Denmark)
Nielsen, Kaspar Kirstein; Engelbrecht, Kurt
2012-01-01
for a range of thermal conductivities, operating frequencies, a long and short regenerator, and finally a regenerator with a low and a high number of transfer units (NTU) regenerator. In this way the performance is mapped out and the impact of the thermal conductivity of the solid is probed. Modeling shows......The influence of the thermal conductivity of the regenerator solid on the performance of a flat plate active magnetic regenerator (AMR) is investigated using an established numerical AMR model. The cooling power at different (fixed) temperature spans is used as a measure of the performance...... that under certain operating conditions, the AMR cycle is sensitive to the solid conductivity. It is found that as the operating frequency is increased it is not only sufficient to have a high NTU regenerator but the regenerator performance will also benefit from increased thermal conductivity in the solid...
A PC- Based Transient Method for Thermal Conductivity Measurement.
Directory of Open Access Journals (Sweden)
A.K. Singh
2000-10-01
Full Text Available In this paper, an indigenously developed thermal probe has been interfaced with a PC for automated measurement of thermal conductivity (K . The developed system has been calibrated and standardised by measuring K of glycerol. The maximum percentage error, for repeated sets of observations, was within 7.29 per cent of standard value reported for glycerol. This methodology has been successfully employed for measuring K of propellant oxidisers, additives, binders, etc.
Determination of thermal conductivity in foundry mould mixtures
Directory of Open Access Journals (Sweden)
G. Solenički
2010-01-01
Full Text Available For a thorough understanding of the behaviour of foundry mould mixtures, a good knowledge of thermal properties of mould materials is needed. Laboratory determination of thermal conductivity of mould mixtures enables a better control over scabbing defects which are a major problem in green sand mould mixtures. A special instrument has been designed for that purpose and it is described in this work.
Inverse transient heat conduction problems and identification of thermal parameters
Atchonouglo, K.; Banna, M.; Vallée, C.; Dupré, J.-C.
2008-04-01
This work deals with the estimation of polymers properties. An inverse analysis based on finite element method is applied to identify simultaneously the constants thermal conductivity and heat capacity per unit volume. The inverse method algorithm constructed is validated from simulated transient temperature recording taken at several locations on the surface of the solid. Transient temperature measures taped with infrared camera on polymers were used for identifying the thermal properties. The results show an excellent agreement between manufacturer and identified values.
Investigation on the Thermal Conductivity of 3-Dimensional and 4-Directional Braided Composites
Institute of Scientific and Technical Information of China (English)
Liu Zhenguo; Zhang Haiguo; Lu Zixing; Li Diansen
2007-01-01
It is vital to choose a factual and reasonable micro-structural model of braided composites for improving the calculating precision of thermal property of 3-D braided composites by finite element method (FEM). On the basis of new microstructure model of braided composites proposed recently, the model of FEM calculation for thermal conductivity of 3-dimennsional and 4-directional braided composites is set up in this paper. The curves of coefficient of effective thermal conductivity versus fiber volume ratio and interior braiding angle are obtained. Furthermore, comparing the results of FEM with the available experimental data, the reasonability and veracity of calculation are confirmed at the same time.
Dynamic Measurements of the Thermal Conductivity of Insulators
Bezjak, Mladen; Zvizdić, Davor
2011-08-01
Measurements of the thermal conductivity of insulators that are commonly used in civil engineering are as a rule performed using Pönsgen's guarded hot-plate method under steady-state conditions. Achieving these steady-state conditions is a time consuming and relatively expensive procedure. Therefore, the application of a method that is less time consuming and less costly to common building insulating materials is of interest. The method should also have the accuracy and repeatability comparable to that of presently used methods. One such method is the transient hot-wire method (predominantly used for liquids, non-Newtonian fluids, plastics, semi-plastics, and similar materials), a dynamic method that uses a very thin pure platinum wire that functions as a thermal source in combination with a temperature sensor that detects temperature transients. This article describes the application of the transient hot-wire method to most commonly used building thermal insulating materials. The transient hot-wire measurements of the thermal conductivity were performed on many building material samples. For the sake of comparison, the thermal conductivity of samples made from the same materials was also tested using the stationary Pönsgen's guarded hot-plate method. This article describes the comparison and evaluation of the measurement results obtained from both methods as well as the estimation of pertinent measurement uncertainties. The results are presented in graphical and numerical form in tables and diagrams for each type of thermal insulator.
Toward lithium ion batteries with enhanced thermal conductivity.
Koo, Bonil; Goli, Pradyumna; Sumant, Anirudha V; dos Santos Claro, Paula Cecilia; Rajh, Tijana; Johnson, Christopher S; Balandin, Alexander A; Shevchenko, Elena V
2014-07-22
As batteries become more powerful and utilized in diverse applications, thermal management becomes one of the central problems in their application. We report the results on thermal properties of a set of different Li-ion battery electrodes enhanced with multiwalled carbon nanotubes. Our measurements reveal that the highest in-plane and cross-plane thermal conductivities achieved in the carbon-nanotube-enhanced electrodes reached up to 141 and 3.6 W/mK, respectively. The values for in-plane thermal conductivity are up to 2 orders of magnitude higher than those for conventional electrodes based on carbon black. The electrodes were synthesized via an inexpensive scalable filtration method, and we demonstrate that our approach can be extended to commercial electrode-active materials. The best performing electrodes contained a layer of γ-Fe2O3 nanoparticles on carbon nanotubes sandwiched between two layers of carbon nanotubes and had in-plane and cross-plane thermal conductivities of ∼50 and 3 W/mK, respectively, at room temperature. The obtained results are important for thermal management in Li-ion and other high-power-density batteries.
Schmidt, Aaron J; Chen, Xiaoyuan; Chen, Gang
2008-11-01
The relationship between pulse accumulation and radial heat conduction in pump-probe transient thermoreflectance (TTR) is explored. The results illustrate how pulse accumulation allows TTR to probe two thermal length scales simultaneously. In addition, the conditions under which radial transport effects are important are described. An analytical solution for anisotropic heat flow in layered structures is given, and a method for measuring both cross-plane and in-plane thermal conductivities of thermally anisotropic thin films is described. As verification, the technique is used to extract the cross-plane and in-plane thermal conductivities of highly ordered pyrolytic graphite. Results are found to be in good agreement with literature values.
Effective Thermal Conductivity of Insulating Material made from Recycled Newspapers
Yamada, Etsuro; Takahashi, Kaneko; Sato, Mitsuo; Ishii, Yukihiro
In this paper, the experimental results are represented on the effective thermal conductivity of cellulose insulation powder which is made from recycled newspapers. This insulating material is useful for energy and resources saving. The steady state cylindrical absolute method is employed by considering the accuracy of measurement. The experimental results are compared with the ones measured previously by other methods. The main results obtained are as follows (1) The effective thermal conductivity of this insulating material increases with increasing temperature and effective specific density, respectively. But, these increasing rate is not so large. (2) The effective thermal conductivity is about 0.04-0.06[W/mK] at the range of the effective specific density less than 100 [kg/m3]. This value is comparable with other industrial insulating materials.
Thermal conductivity measurement of thin films by a dc method.
Yang, Junyou; Zhang, Jiansheng; Zhang, Hui; Zhu, Yunfeng
2010-11-01
A dc method, which needs no complex numerical calculation and expensive hardware configuration, was developed to measure the cross-plane thermal conductivity of thin films in this paper. Two parallel metallic heaters, which were deposited on different parts of the sample, serve simultaneously as the heaters and temperature sensors during the measurement. A direct current was flowed through the same two metallic strips to heat the thin-film sample. The heating power and the heater's temperature were obtained by a data acquisition device, and the thermal conductivity of thin film was calculated. To verify the validity of the dc method, several SiO(2) films with different thicknesses were deposited on Si wafers, respectively, and their thermal conductivities were measured by both the dc method and 3ω method. The results of two methods are in good agreement within an acceptable error, and they are also inconsistent with some of previously published data.
Thermal conductivity of bulk and monolayer MoS 2
Gandi, Appala
2016-02-26
© Copyright EPLA, 2016. We show that the lattice contribution to the thermal conductivity of MoS2 strongly dominates the carrier contribution in a broad temperature range from 300 to 800 K. Since theoretical insight into the lattice contribution is largely missing, though it would be essential for materials design, we solve the Boltzmann transport equation for the phonons self-consistently in order to evaluate the phonon lifetimes. In addition, the length scale for transition between diffusive and ballistic transport is determined. The low out-of-plane thermal conductivity of bulk MoS2 (2.3 Wm-1K-1 at 300 K) is useful for thermoelectric applications. On the other hand, the thermal conductivity of monolayer MoS2 (131 Wm-1K-1 at 300 K) is comparable to that of Si.
Thermal conductivities of some novel nonlinear optical materials.
Beasley, J D
1994-02-20
Results of thermal conductivity measurements are reported for several of the more recently developed nonlinear optical crystals. New or substantially revised values of thermal conductivity were obtained in six materials. Notable thermal conductivities measured were those for AgGaS(2) [0.014 W/(cm K) and 0.015 W/(cm K)], AgGaSe(2) [0.010 W/(cm K) and 0.011 W/(cm K)], beta barium borate [0.016 W/(cm K) and 0.012 W/(cm K)], and ZnGeP(2) [0.36 W/(cm K) and 0.35 W/(cm K)], with values quoted for directions respectively parallel and perpendicular to the optic axis for each material. These new data provide necessary input for the design of high-power optical frequency converters.
Dynamical thermal conductivity of the spin Lieb lattice
Yarmohammadi, Mohsen
2016-05-01
In the ferromagnetic insulator with the Dzyaloshinskii-Moriya interaction (DMI), we have theoretically investigated the dynamical thermal conductivity (DTC). In other words, we have investigated the frequency dependence of thermal conductivity, κ, of the Lieb lattice, a face-centered square lattice, subjected to a time dependence temperature gradient. Using linear response theory and Green's function approach, DTC has been obtained in the context of Heisenberg Hamiltonian. At low frequencies, DTC is found to be monotonically increasing with DMI strength (DMIS), temperature and next-nearest-neighbor (NNN) coupling. Also we have found that DTC includes a peak for different values of temperature, DMIS and NNN coupling. Furthermore we study the temperature dependence of thermal conductivity of Lieb lattice for different values of DMIS, NNN coupling and external magnetic filed. We witness a decrease in DTC with temperature due to the quantum effects in the system.
Thermal conductivity at a disordered quantum critical point
Hartnoll, Sean A; Santos, Jorge E
2015-01-01
Strongly disordered and strongly interacting quantum critical points are difficult to access with conventional field theoretic methods. They are, however, both experimentally important and theoretically interesting. In particular, they are expected to realize universal incoherent transport. Such disordered quantum critical theories have recently been constructed holographically by deforming a CFT by marginally relevant disorder. In this paper we find additional disordered fixed points via relevant disordered deformations of a holographic CFT. Using recently developed methods in holographic transport, we characterize the thermal conductivity in both sets of theories in 1+1 dimensions. The thermal conductivity is found to tend to a constant at low temperatures in one class of fixed points, and to scale as $T^{0.3}$ in the other. Furthermore, in all cases the thermal conductivity exhibits discrete scale invariance, with logarithmic in temperature oscillations superimposed on the low temperature scaling behavior....
Reduction of thermal conductivity by nanoscale 3D phononic crystal.
Yang, Lina; Yang, Nuo; Li, Baowen
2013-01-01
We studied how the period length and the mass ratio affect the thermal conductivity of isotopic nanoscale three-dimensional (3D) phononic crystal of Si. Simulation results by equilibrium molecular dynamics show isotopic nanoscale 3D phononic crystals can significantly reduce the thermal conductivity of bulk Si at high temperature (1000 K), which leads to a larger ZT than unity. The thermal conductivity decreases as the period length and mass ratio increases. The phonon dispersion curves show an obvious decrease of group velocities in 3D phononic crystals. The phonon's localization and band gap is also clearly observed in spectra of normalized inverse participation ratio in nanoscale 3D phononic crystal.
Aqueous Solution Thermal Conductivity of Beryllium-Subgroup Metal Chlorides
Directory of Open Access Journals (Sweden)
K. Abdullayev
2013-01-01
Full Text Available The paper presents experimental data on thermal conductivity of BeCl2 and SrCl2 salt aqueous solutions in the temperature range from 20 to 300 °С and at various electrolyte concentrations in mass percent. For the first time thermal conductivity of the system Н2О + BeCl2 has been investigated at high temperatures.The experimental results are described with the help of an empirical equation in the form of: λs = λo (1+ Am + Bm3/2 + Cm2,where λs and λo – thermal conductivity coefficients of solution and water; A, B and C – coefficients depending on electrolyte nature; m – molality in units mol/kg.The formula error is less than ±1 %.
Energy Technology Data Exchange (ETDEWEB)
Wei, Wei, E-mail: weiw2015@gmail.com [Hubei Subsurface Multi-scale Imaging Key Laboratory, Institute of Geophysics and Geomatics, China University of Geosciences, Wuhan 430074 (China); Cai, Jianchao, E-mail: caijc@cug.edu.cn [Hubei Subsurface Multi-scale Imaging Key Laboratory, Institute of Geophysics and Geomatics, China University of Geosciences, Wuhan 430074 (China); Hu, Xiangyun, E-mail: xyhu@cug.edu.cn [Hubei Subsurface Multi-scale Imaging Key Laboratory, Institute of Geophysics and Geomatics, China University of Geosciences, Wuhan 430074 (China); Han, Qi, E-mail: hanqi426@gmail.com [Hubei Subsurface Multi-scale Imaging Key Laboratory, Institute of Geophysics and Geomatics, China University of Geosciences, Wuhan 430074 (China); Liu, Shuang, E-mail: lius@cug.edu.cn [Hubei Subsurface Multi-scale Imaging Key Laboratory, Institute of Geophysics and Geomatics, China University of Geosciences, Wuhan 430074 (China); Zhou, Yingfang, E-mail: yingfang.zhou@abdn.ac.uk [School of Engineering, University of Aberdeen, FN 264, King' s College, Aberdeen, AB24 3UE (United Kingdom)
2016-08-26
A theoretical effective thermal conductivity model for nanofluids is derived based on fractal distribution characteristics of nanoparticle aggregation. Considering two different mechanisms of heat conduction including particle aggregation and convention, the model is expressed as a function of the fractal dimension and concentration. In the model, the change of fractal dimension is related to the variation of aggregation shape. The theoretical computations of the developed model provide a good agreement with the experimental results, which may serve as an effective approach for quantitatively estimating the effective thermal conductivity of nanofluids. - Highlights: • A thermal conductivity model is derived based on fractal aggregation distribution. • The relationship between aggregation shape and fractal dimension is analyzed. • Predictions of the proposed model show good agreement with experimental data.
Wei, Wei; Cai, Jianchao; Hu, Xiangyun; Han, Qi; Liu, Shuang; Zhou, Yingfang
2016-08-01
A theoretical effective thermal conductivity model for nanofluids is derived based on fractal distribution characteristics of nanoparticle aggregation. Considering two different mechanisms of heat conduction including particle aggregation and convention, the model is expressed as a function of the fractal dimension and concentration. In the model, the change of fractal dimension is related to the variation of aggregation shape. The theoretical computations of the developed model provide a good agreement with the experimental results, which may serve as an effective approach for quantitatively estimating the effective thermal conductivity of nanofluids.
Study of thermal conductivity enhancement of aqueous suspensions containing silver nanoparticles
Iyahraja, S.; Rajadurai, J. Selwin
2015-05-01
Nanofluids are prepared by dispersing polyvinylpyrrolidone coated silver nanoparticles in distilled water. The thermal conductivity of nanofluids is measured by KD2 Pro thermal analyzer which is based on transient hot wire method. The influence of size and concentration of nanoparticles, surfactant and temperature of suspensions on the enhancement of the thermal conductivity is analyzed. The experimental results show that the thermal conductivity of nanofluids increases with the decrease in the size and increase in the concentration of the nanoparticles. Even with low volume fraction of 0.1 % and 20 nm size of silver nanoparticles, a high thermal conductivity enhancement of 54 % has been achieved. The surfactant and the temperature have a significant effect on the thermal conductivity enhancement of the nanofluids. The increase in temperature of the nanofluid from 30oC to 60oC increases its thermal conductivity up to 69 % whereas the addition of surfactant lessens the thermal conductivity enhancement to 34.2% with polyvinylpyrrolidone and 31.5 % with sodium dodecyl sulfate. The experimental results are compared with the existing theoretical models.
Wang, Fangfang; Zeng, Xiaoliang; Yao, Yimin; Sun, Rong; Xu, Jianbin; Wong, Ching-Ping
2016-01-19
Polymer composites with high thermal conductivity have recently attracted much attention, along with the rapid development of the electronic devices toward higher speed and performance. However, a common method to enhance polymer thermal conductivity through an addition of high thermally conductive fillers usually cannot provide an expected value, especially for composites requiring electrical insulation. Here, we show that polymeric composites with silver nanoparticle-deposited boron nitride nanosheets as fillers could effectively enhance the thermal conductivity of polymer, thanks to the bridging connections of silver nanoparticles among boron nitride nanosheets. The thermal conductivity of the composite is significantly increased from 1.63 W/m-K for the composite filled with the silver nanoparticle-deposited boron nitride nanosheets to 3.06 W/m-K at the boron nitride nanosheets loading of 25.1 vol %. In addition, the electrically insulating properties of the composite are well preserved. Fitting the measured thermal conductivity of epoxy composite with one physical model indicates that the composite with silver nanoparticle-deposited boron nitride nanosheets outperforms the one with boron nitride nanosheets, owning to the lower thermal contact resistance among boron nitride nanosheets' interfaces. The finding sheds new light on enhancement of thermal conductivity of the polymeric composites which concurrently require the electrical insulation.
Study of thermal conductivity enhancement of aqueous suspensions containing silver nanoparticles
Directory of Open Access Journals (Sweden)
S. Iyahraja
2015-05-01
Full Text Available Nanofluids are prepared by dispersing polyvinylpyrrolidone coated silver nanoparticles in distilled water. The thermal conductivity of nanofluids is measured by KD2 Pro thermal analyzer which is based on transient hot wire method. The influence of size and concentration of nanoparticles, surfactant and temperature of suspensions on the enhancement of the thermal conductivity is analyzed. The experimental results show that the thermal conductivity of nanofluids increases with the decrease in the size and increase in the concentration of the nanoparticles. Even with low volume fraction of 0.1 % and 20 nm size of silver nanoparticles, a high thermal conductivity enhancement of 54 % has been achieved. The surfactant and the temperature have a significant effect on the thermal conductivity enhancement of the nanofluids. The increase in temperature of the nanofluid from 30oC to 60oC increases its thermal conductivity up to 69 % whereas the addition of surfactant lessens the thermal conductivity enhancement to 34.2% with polyvinylpyrrolidone and 31.5 % with sodium dodecyl sulfate. The experimental results are compared with the existing theoretical models.
High thermal conductivity of chain-oriented amorphous polythiophene.
Singh, Virendra; Bougher, Thomas L; Weathers, Annie; Cai, Ye; Bi, Kedong; Pettes, Michael T; McMenamin, Sally A; Lv, Wei; Resler, Daniel P; Gattuso, Todd R; Altman, David H; Sandhage, Kenneth H; Shi, Li; Henry, Asegun; Cola, Baratunde A
2014-05-01
Polymers are usually considered thermal insulators, because the amorphous arrangement of the molecular chains reduces the mean free path of heat-conducting phonons. The most common method to increase thermal conductivity is to draw polymeric fibres, which increases chain alignment and crystallinity, but creates a material that currently has limited thermal applications. Here we show that pure polythiophene nanofibres can have a thermal conductivity up to ∼ 4.4 W m(-1) K(-1) (more than 20 times higher than the bulk polymer value) while remaining amorphous. This enhancement results from significant molecular chain orientation along the fibre axis that is obtained during electropolymerization using nanoscale templates. Thermal conductivity data suggest that, unlike in drawn crystalline fibres, in our fibres the dominant phonon-scattering process at room temperature is still related to structural disorder. Using vertically aligned arrays of nanofibres, we demonstrate effective heat transfer at critical contacts in electronic devices operating under high-power conditions at 200 °C over numerous cycles.
IR thermography applied to the assessment of thermal conductivity of building materials
Bison, P.; Grinzato, E.
2010-05-01
A device to measure thermal conductivity of small specimens is presented. The specimen is sandwiched between two thermoelectric cells, one sources heat the other sink it. An infrared camera looks at the device and specimen on its side, determining both the heat flux flowing through it and the temperature gradient due to the unknown thermal resistance. The thermal conductivity is quickly recovered, as soon as the steady thermal regime is reached. The heat flux toward the environment is evaluated and minimized working at zero mean temperature difference. A couple of specimens made of materials used to prepare radiant heating floor screeds are measured. The Maxwell model to determine the thermal conductivity of mixture, based on the knowledge of the conductivity of the different phases and their volume fraction, is used to interpret the results.
Kim, Si-Hyung; Joung, Chang-Young; Kim, Han-Soo; Lee, Young-Woo; Ryu, Ho-Jin; Sohn, Dong-Seong; Kim, Dong-Joo
2006-06-01
UO2 pellets containing molybdenum networks were fabricated when UO2 pellets mixed with 3 or 5 wt% MoO3 powder were sintered in the CO2/CO ratio of 19/1 and then annealed in an H2 atmosphere. The thermal diffusivities of UO2 and Mo-precipitated UO2 pellets were measured in the range of 298-1673 K by a laser flash method and their thermal conductivities were calculated from the thermal diffusivity, the sample density and the published specific heat capacity data. The temperature dependency of the thermal conductivity up to 1673 K in UO2 and Mo-precipitated UO2 was found to be modeled well using the conductivity equation, κ = (A + BT)-1. The thermal conductivity of the Mo-precipitated UO2 was higher than that of the pure UO2.
Experimental Investigation of Thermal Conductivity of Meat During Freezing
Shinbayeva, A.; Arkharov, I.; Aldiyarov, A.; Drobyshev, A.; Zhubaniyazova, M.; Kurnosov, V.
2017-04-01
The cryogenic technologies of processing and storage of agricultural products are becoming increasingly indispensable in the food industry as an important factor of ensuring food safety. One of such technologies is the shock freezing of meat, which provides a higher degree of preservation of the quality of frozen products in comparison with traditional technologies. The thermal conductivity of meat is an important parameter influencing the energy consumption in the freezing process. This paper presents the results of an experimental investigation of the temperature dependence of the thermal conductivity of beef. The measurements were taken by using a specially designed measurement cell, which allows covering the temperature range from 80 to 300 K.
Measurement of in-plane thermal conductivity in polymer films
Qingshuo Wei; Chinatsu Uehara; Masakazu Mukaida; Kazuhiro Kirihara; Takao Ishida
2016-01-01
Measuring the in-plane thermal conductivity of organic thermoelectric materials is challenging but is critically important. Here, a method to study the in-plane thermal conductivity of free-standing films (via the use of commercial equipment) based on temperature wave analysis is explored in depth. This subject method required a free-standing thin film with a thickness larger than 10 μm and an area larger than 1 cm2, which are not difficult to obtain for most solution-processable organic ther...
Low-temperature thermal conductivity of Nylon-6/Cu nanoparticles
Energy Technology Data Exchange (ETDEWEB)
Martelli, V., E-mail: martelliv@fi.infn.i [INFN, Section of Florence, Via G. Sansone 1, 50019 Sesto Fiorentino, Florence (Italy); LENS, University of Florence, Via Nello Carrara 1, 50019 Sesto Fiorentino (Italy); Toccafondi, N. [Department of Chemistry - CSGI, University of Florence, Via Lastruccia 3, 50019 Sesto Fiorentino, Florence (Italy); Ventura, G. [INFN, Section of Florence, Via G. Sansone 1, 50019 Sesto Fiorentino, Florence (Italy); Department of Physics, University of Florence, Via G. Sansone 1, 50019 Sesto Fiorentino, Florence (Italy)
2010-10-15
We have produced a new nanocomposite material made up of a Nylon-6 matrix in which metallic copper nanoparticle (5% in weight) are uniformly dispersed. Here we report about the measurement of the thermal conductivity of such material between 0.1 and 30 K. Thermal conductivity of the nanocomposite does not substantially differ from that of Nylon. Nevertheless data show interesting features, in particular a sharp dip at 1.4 K which can be interpreted as a resonant scattering of phonons by copper nanoparticles.
Effect of fibre shape on transverse thermal conductivity of unidirectional composites
Indian Academy of Sciences (India)
B Raghava Rao; V Ramachandra Raju; K Mohana Rao
2015-04-01
The determination of thermal conductivities of a composite lamina is of paramount importance in the effective design and application of composite materials. The thermal conductivity of a lamina along the fibre direction can be easily estimated from the Rule of Mixtures but, the thermal conductivity in the transverse direction which depends on many factors need to be determined effectively. The transverse thermal conductivities of continuous fibre reinforced composite lamina are computed by numerical method using finite element analysis. Different fibre concentrations, fibre shapes and different fibre-matrix combinations are examined. A Regular array of square pattern of fibres is considered. The finite element model is validated with the available experimental results and theoretical models for a circular fibre and then extended to other shapes of fibres. Two-dimensional finite element model is adopted for the analysis, due to the restriction of heat flow only in transverse direction and the fibres are assumed to be continuous and perfectly bonded to the matrix. Analysis is carried out for a wide range of fibre-matrix combinations and up to the maximum fibre concentration in the composite. The analysis is extended for circular, square, elliptical and rhombus shaped fibres. From the results it is observed that there is a significant variation in the transverse thermal conductivity due to the shape of fibre, concentration ratios and fibre matrix combinations. This variation in thermal conductivity of a composite lamina results into a broader choice for the selection of composite materials in thermal applications.
Effect of point defects on the thermal conductivity of UO2: molecular dynamics simulations
Energy Technology Data Exchange (ETDEWEB)
Liu, Xiang-Yang [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Stanek, Christopher Richard [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Andersson, Anders David Ragnar [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
2015-07-21
The thermal conductivity of uranium dioxide (UO_{2}) fuel is an important materials property that affects fuel performance since it is a key parameter determining the temperature distribution in the fuel, thus governing, e.g., dimensional changes due to thermal expansion, fission gas release rates, etc. [1] The thermal conductivity of UO_{2} nuclear fuel is also affected by fission gas, fission products, defects, and microstructural features such as grain boundaries. Here, molecular dynamics (MD) simulations are carried out to determine quantitatively, the effect of irradiation induced point defects on the thermal conductivity of UO_{2}, as a function of defect concentrations, for a range of temperatures, 300 – 1500 K. The results will be used to develop enhanced continuum thermal conductivity models for MARMOT and BISON by INL. These models express the thermal conductivity as a function of microstructure state-variables, thus enabling thermal conductivity models with closer connection to the physical state of the fuel [2].
Estimating thermal diffusivity and specific heat from needle probe thermal conductivity data
Waite, W.F.; Gilbert, L.Y.; Winters, W.J.; Mason, D.H.
2006-01-01
Thermal diffusivity and specific heat can be estimated from thermal conductivity measurements made using a standard needle probe and a suitably high data acquisition rate. Thermal properties are calculated from the measured temperature change in a sample subjected to heating by a needle probe. Accurate thermal conductivity measurements are obtained from a linear fit to many tens or hundreds of temperature change data points. In contrast, thermal diffusivity calculations require a nonlinear fit to the measured temperature change occurring in the first few tenths of a second of the measurement, resulting in a lower accuracy than that obtained for thermal conductivity. Specific heat is calculated from the ratio of thermal conductivity to diffusivity, and thus can have an uncertainty no better than that of the diffusivity estimate. Our thermal conductivity measurements of ice Ih and of tetrahydrofuran (THF) hydrate, made using a 1.6 mm outer diameter needle probe and a data acquisition rate of 18.2 pointss, agree with published results. Our thermal diffusivity and specific heat results reproduce published results within 25% for ice Ih and 3% for THF hydrate. ?? 2006 American Institute of Physics.
Xu, Hong-Fei; He, Shao-Jian; Du, Yi-Hang; Yu, Nan-Jie; Du, Xiao-Ze; Lin, Jun; Nazarenko, Sergei
2017-01-01
Mussel-inspired approach was attempted to non-covalently functionalize the surfaces of boron nitride (BN) with self-polymerized dopamine coatings in order to reduce the interfacial thermal barrier and enhance the thermal conductivity of BN-containing composites. Compared to the polypropylene (PP) composites filled with pristine BN at the same filler content, thermal conductivity was much higher for those filled with both functionalized BN (f-BN) and maleic anhydride grafted PP (PP-g-ma) due to the improved filler dispersion and better interfacial filler-matrix compatibility, which facilitated the development of more thermal paths. Theoretical models were also applied to predict the composite thermal conductivity in which the Nielsen model was found to fit well with the experimental results, and the estimated effective aspect ratio of fillers well corresponded to the degree of filler aggregation as observed in the morphological study. PMID:28107466
Chen, Lin; Xu, Hong-Fei; He, Shao-Jian; Du, Yi-Hang; Yu, Nan-Jie; Du, Xiao-Ze; Lin, Jun; Nazarenko, Sergei
2017-01-01
Mussel-inspired approach was attempted to non-covalently functionalize the surfaces of boron nitride (BN) with self-polymerized dopamine coatings in order to reduce the interfacial thermal barrier and enhance the thermal conductivity of BN-containing composites. Compared to the polypropylene (PP) composites filled with pristine BN at the same filler content, thermal conductivity was much higher for those filled with both functionalized BN (f-BN) and maleic anhydride grafted PP (PP-g-ma) due to the improved filler dispersion and better interfacial filler-matrix compatibility, which facilitated the development of more thermal paths. Theoretical models were also applied to predict the composite thermal conductivity in which the Nielsen model was found to fit well with the experimental results, and the estimated effective aspect ratio of fillers well corresponded to the degree of filler aggregation as observed in the morphological study.
Thermal conduction in a mirror-unstable plasma
Komarov, S. V.; Churazov, E. M.; Kunz, M. W.; Schekochihin, A. A.
2016-07-01
The plasma of galaxy clusters is subject to firehose and mirror instabilities at scales of order the ion Larmor radius. The mirror instability generates fluctuations of magnetic-field strength δB/B ˜ 1. These fluctuations act as magnetic traps for the heat-conducting electrons, suppressing their transport. We calculate the effective parallel thermal conductivity in the ICM in the presence of the mirror fluctuations for different stages of the evolution of the instability. The mirror fluctuations are limited in amplitude by the maximum and minimum values of the field strength, with no large deviations from the mean value. This key property leads to a finite suppression of thermal conduction at large scales. We find suppression down to ≈0.2 of the Spitzer value for the secular phase of the perturbations' growth, and ≈0.3 for their saturated phase. The effect operates in addition to other suppression mechanisms and independently of them. Globally, fluctuations δB/B ˜ 1 can be present on much larger scales, of the order of the scale of turbulent motions. However, we do not expect large suppression of thermal conduction by these, because their scale is considerably larger than the collisional mean free path of the ICM electrons. The obtained suppression of thermal conduction by a factor of ˜5 appears to be characteristic and potentially universal for a weakly collisional mirror-unstable plasma.
Reduction in thermal conductivity of BiSbTe lump
Ahmad, Kaleem; Wan, C.; Al-Eshaikh, M. A.; Kadachi, A. N.
2017-03-01
In this work, systematic investigations on the thermal conductivities of BiSbTe lump, microstructured pristine BiSbTe bulk and single wall carbon nanotubes (SWCNTs)/BiSbTe bulk nanocomposites were performed. BiSbTe lumps were crushed to form a coarse powder (200 µm) and effect of particle size reduction on the effective thermal conductivity of BiSbTe (200 µm) bulk were analyzed. For further reduction in the conductivity, a two pronged strategy has been employed. First, additional refinement of BiSbTe (200 µm) were performed through ball milling in an inert environment. Second, SWCNTs in 0.75, and 1.0 vol% were distributed uniformly in the fine BiSbTe ball milled powder. The results showed that the effective thermal conductivities decrease with the reduction in the particle size from lump to BiSbTe (200 µm) bulk as well as with the addition of SWCNTs accompanied by further refinement of BiSbTe particles. The significant reduction in thermal conductivities of the lump was achieved for pure BiSbTe (200 µm) bulk and 0.75 vol% of SWCNTs/BiSbTe composite. This can be ascribed to the enhanced phonon scattering by the grain boundaries between the nanostructured BiSbTe particles as well as the interfaces between BiSbTe and the low dimensional carbon nanotubes.
Effect of cryogenic treatment on thermal conductivity properties of copper
Nadig, D. S.; Ramakrishnan, V.; Sampathkumaran, P.; Prashanth, C. S.
2012-06-01
Copper exhibits high thermal conductivity properties and hence it is extensively used in cryogenic applications like cold fingers, heat exchangers, etc. During the realization of such components, copper undergoes various machining operations from the raw material stage to the final component. During these machining processes, stresses are induced within the metal resulting in internal stresses, strains and dislocations. These effects build up resistance paths for the heat carriers which transfer heat from one location to the other. This in turn, results in reduction of thermal conductivity of the conducting metal and as a result the developed component will not perform as per expectations. In the process of cryogenic treatment, the metal samples are exposed to cryogenic temperature for extended duration of time for 24 hours and later tempered. During this process, the internal stresses and strains are reduced with refinement of the atomic structure. These effects are expected to favourably improve thermal conductivity properties of the metal. In this experimental work, OFHC copper samples were cryotreated for 24 hours at 98 K and part of them were tempered at 423K for one hour. Significant enhancement of thermal conductivity values were observed after cryotreating and tempering the copper samples.
Reduction in thermal conductivity of BiSbTe lump
Energy Technology Data Exchange (ETDEWEB)
Ahmad, Kaleem [King Saud University, Sustainable Energy Technologies Center, College of Engineering, PO Box 800, Riyadh (Saudi Arabia); Wan, C. [Tsinghua University, State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Beijing (China); Al-Eshaikh, M.A.; Kadachi, A.N. [King Saud University, Research Center, College of Engineering, PO Box 800, Riyadh (Saudi Arabia)
2017-03-15
In this work, systematic investigations on the thermal conductivities of BiSbTe lump, microstructured pristine BiSbTe bulk and single wall carbon nanotubes (SWCNTs)/BiSbTe bulk nanocomposites were performed. BiSbTe lumps were crushed to form a coarse powder (200 μm) and effect of particle size reduction on the effective thermal conductivity of BiSbTe (200 μm) bulk were analyzed. For further reduction in the conductivity, a two pronged strategy has been employed. First, additional refinement of BiSbTe (200 μm) were performed through ball milling in an inert environment. Second, SWCNTs in 0.75, and 1.0 vol% were distributed uniformly in the fine BiSbTe ball milled powder. The results showed that the effective thermal conductivities decrease with the reduction in the particle size from lump to BiSbTe (200 μm) bulk as well as with the addition of SWCNTs accompanied by further refinement of BiSbTe particles. The significant reduction in thermal conductivities of the lump was achieved for pure BiSbTe (200 μm) bulk and 0.75 vol% of SWCNTs/BiSbTe composite. This can be ascribed to the enhanced phonon scattering by the grain boundaries between the nanostructured BiSbTe particles as well as the interfaces between BiSbTe and the low dimensional carbon nanotubes. (orig.)
Developing a High Thermal Conductivity Fuel with Silicon Carbide Additives
Energy Technology Data Exchange (ETDEWEB)
baney, Ronald; Tulenko, James
2012-11-20
The objective of this research is to increase the thermal conductivity of uranium oxide (UO{sub 2}) without significantly impacting its neutronic properties. The concept is to incorporate another high thermal conductivity material, silicon carbide (SiC), in the form of whiskers or from nanoparticles of SiC and a SiC polymeric precursor into UO{sub 2}. This is expected to form a percolation pathway lattice for conductive heat transfer out of the fuel pellet. The thermal conductivity of SiC would control the overall fuel pellet thermal conductivity. The challenge is to show the effectiveness of a low temperature sintering process, because of a UO{sub 2}-SiC reaction at 1,377°C, a temperature far below the normal sintering temperature. Researchers will study three strategies to overcome the processing difficulties associated with pore clogging and the chemical reaction of SiC and UO{sub 2} at temperatures above 1,300°C:
Thermally Conductive-Silicone Composites with Thermally Reversible Cross-links.
Wertz, J T; Kuczynski, J P; Boday, D J
2016-06-08
Thermally conductive-silicone composites that contain thermally reversible cross-links were prepared by blending diene- and dienophile-functionalized polydimethylsiloxane (PDMS) with an aluminum oxide conductive filler. This class of thermally conductive-silicones are useful as thermal interface materials (TIMs) within Information Technology (IT) hardware applications to allow rework of valuable components. The composites were rendered reworkable via retro Diels-Alder cross-links when temperatures were elevated above 130 °C and required little mechanical force to remove, making them advantageous over other TIM materials. Results show high thermal conductivity (0.4 W/m·K) at low filler loadings (45 wt %) compared to other TIM solutions (>45 wt %). Additionally, the adhesion of the material was found to be ∼7 times greater at lower temperatures (25 °C) and ∼2 times greater at higher temperatures (120 °C) than commercially available TIMs.
Designing low thermal conductivity of RuO2 for thermoelectric applications
Music, Denis; Kremer, Oliver; Pernot, Gilles; Schneider, Jochen M.
2015-02-01
We have applied Umklapp phonon-phonon and phonon-defect scattering to calculate the thermal conductivity of unalloyed as well as Fe- and La-alloyed RuO2 (P42/mnm). These models are computationally efficient and parameter free as they are supported by density functional theory. We predict an order of magnitude drop in the thermal conductivity upon alloying, which is beneficial for thermoelectric applications as it increases the figure of merit. Thermal conductivity data obtained by thermoreflectance on magnetron sputtered thin films are consistent with the calculations. The here employed research strategy may also be beneficial for designing phases that require manipulation of entangled properties.
Phonon Transmission and Thermal Conductance in Fibonacci Wire at Low Temperature
Institute of Scientific and Technical Information of China (English)
ZHANG Yong-Mei; XU Chen-Hua; XIONG Shi-Jie
2007-01-01
We investigate the phonon transmission and thermal conductance in a general Fibonacci quasicrystal by the model of lattice dynamics and the technique of transfer matrix.It is found that quasiperiodic distribution of masses may greatly destroy the phonon transport at both low and high frequencies and thus may affect the thermal conductance.The thermal conductance increases with temperature at low temperatures and displays saturation with further increase of the temperature.Such saturation behaviour is preserved even when the mass ratio of atoms in the Fibonacci chain is changed.
Institute of Scientific and Technical Information of China (English)
FENG Xiao-Li; LI Zhi-Xin; GUO Zeng-Yuan
2001-01-01
Thermal conductivity in the normal direction of ultra-thin dielectric films is predicted by molecular dynamics calculations for argon crystal. For film thicknesses of about 2-10nm within which real measurements cannot yet be implemented, the size dependence of lattice thermal conductivity is captured and a remarkable thermal conductivity drop is found as compared with bulk experimental data. This size effect demonstrates that phonon-boundary scattering in thin films may also be very significant at high temperatures even above the Debye temperature. The influence of different potential models is examined according to the comparison between results from the Lennard-Jones potential and a soft-sphere potential.