Mida õppida vanalt healt Inglismaalt? / Margit Sutrop

Index Scriptorium Estoniae

Sutrop, Margit, 1963-

2002-01-01

Filosoofiaprofessor Margit Sutrop kirjutab teenindajate lojaalsusest. Autorit hämmastab fakt, et presidendi kantselei peakokk räägib leheveergudel sellest, kuidas presidendi perekond mingit sööki omavahel "möksiks" nimetab

Riigikontroll kahtlustab Tiit Laja korruptiivsetes tehingutes / Gert D. Hankewitz

Index Scriptorium Estoniae

Hankewitz, Gert D.

2007-01-01

Riigikontrolli auditist selgub, et endine riigikantselei peadirektor Tiit Laja kantis Kaitseliidu Kinnisvara SA juhatuse liikmena sadu tuhandeid kroone enda ja oma pereliikmetega seotud ettevõtetesse. Vt. ka Tiit Laja ja Mario Sootna vastust Äripäev 29. märts lk. 18

Tiskre-Hansu elamud = Tiskre-Hansu Homes / Tiit Sild

Index Scriptorium Estoniae

Sild, Tiit, 1977-

2005-01-01

Projekteerija: KPME Engineering & Design. Planeeringu eskiisi autorid Maarja Kask, Tiit Sild, kaasa töötas Kalle Rannula. Detailplaneering: Andres Volens, Kalle Rannula. I etapi kortermajade autor Tiit Sild, kaasa töötasid Maret Volens, Andres Volens, Kristo Tihvand. Valmis 2004-2005. Ill.: I, II ja III korruse plaan, 4 värv. välisvaadet

Kirjanduse periodiseerimisest / Tiit Hennoste

Index Scriptorium Estoniae

Hennoste, Tiit, 1953-

2003-01-01

Järg: Akadeemia, 2003, nr. 6, lk. 1146-1172. Bibliograafia lk. 1170-1172. Ilmunud ka kogumikus: Hennoste, Tiit. Eurooplaseks saamine : kõrvalkäija altkulmupilk. Tartu : Tartu Ülikooli Kirjastus, 2003, lk. 57-107

Mõtteid Eesti Kultuurkapitali arhitektuuripreemiatest = Thoughts about the Cultural Endowment of Estonia's prizes for architecture / Epp Lankots

Index Scriptorium Estoniae

Lankots, Epp, 1976-

2012-01-01

Arhitektuuriaastast 2011. Eesti Kultuurkapitali aastapreemia - Juta Lember (Peterburi Jaani kirik). Arhitektuuri sihtkapitali maastikuarhitektuuri preemia - Kersti Lootus, Kiur Lootus, Siim Lootus, Katri Soonberg, Heidi Viilop (Pärnu Vallikääru park), restaureerimispreemia - Nele Rohtla (Kiltsi mõis), arhitektuuripreemia - Maarja Kask, Ralf Lõoke, Karli Luik, Ene-Liis Semper, Pelle-Sten Viiburg (NO99 Põhuteater), tegevuspreemia - Margit Argus, Margit Aule, Maarin Ektermann, Ingrid Ruudi (festivali "LIFT11" kuraatorid)

Thoughts on a road about roads / Margit Mutso

Index Scriptorium Estoniae

Mutso, Margit, 1966-

2013-01-01

Arhitekt Margit Mutso teede rekonstrueerimise ja planeerimise problemaatikast: autoteed, liiklussõlmed, liiklusmärgid, müratõkked, teeäärne arhitektuur, liiklusohutus, avalik kunst, linna sissesõidud, tänavad, inseneride haridus

Tiskre-Hansu korterelamud / Maarja Kask, Tiit Sild, Kalle Rannula...[jt.

Index Scriptorium Estoniae

2005-01-01

I, II ja III korruse plaan, 4 värv. välisvaadet; projekteerija: KPME Engineering & Design, planeeringu eskiisi autorid Maarja Kask, Tiit Sild, kaasa töötas Kalle Rannula, detailplaneering: Andres Volens, Kalle Rannula, I etapi kortermajade autor Tiit Sild, kaasa töötasid Maret Volens, Andres Volens, Kristo Tihvand

Eesti kooliõpilaste väärtushinnanguist ja huvialadest / Ingrid Rüütel, Ene-Margit Tiit

Index Scriptorium Estoniae

Rüütel, Ingrid, 1935-

2005-01-01

Artiklis analüüsitakse 2004. a. Eesti koolides läbi viidud ankeetküsitlusi teemal "Kooliõpilaste väärtushinnangud ja huvialad". Küsitleti 12-19-aastasi eestikeelsete koolide õpilasi kogu Eestist. Kokku vastas küsitlusele 345 õpilast

Tallinna sadamaala linnaruumiline arengukava : ettepanek = Urban Development Plan for the Tallinn Port Area : Proposal

Index Scriptorium Estoniae

2006-01-01

Tellija: Tallinna Linnaplaneerimise Amet. Korraldaja: Eesti Arhitektide Liit. Aeg: 2006. a. veebruar. Osalejad: linnageograaf Hardo Aasmäe, arhitektid Andres Alver, Rein Hansberg, Veljo Kaasik, Ott Kadarik, Erik Konze, Margit Mutso, Tiit Sild, Villem Tomiste, TLPA juht, Tallinna peaarhitekt Igor Volkov, Tallinna Sadama esindaja Hannes Kuhlbach, TLPA projektijuht Jaan Kurm, TLPA üldplaneeringute osakonna juhataja Endrik Mänd, Logi Projekti esindaja Taimi Lokotar, Heldur Meerits

Tiit Linnamägi - metsaga peab olema sina peal / Merle Rips

Index Scriptorium Estoniae

Rips, Merle, 1950-

2015-01-01

Raplamaal Märjamaa vallas Purga külas Orava talus elab tänavu metsakultuuri kandja austava nimetuse pälvinud loodusemees Tiit Linnamägi. Kodumetsi majandab ta poeg Märdiga nii, et sealsed looduslikud ja kultuurilised rikkused säiliksid. Vestlusest Tiit ja Märt Linnamägiga

Microbial synthesis of alka(enes

Directory of Open Access Journals (Sweden)

Weihua eWang

2013-10-01

Full Text Available Alka(enes are the predominant constituents of gasoline, diesel, and jet fuels. They can be produced naturally by a wide range of microorganisms. Bio- alka(enes can be used as drop-in biofuels. To date, five microbial pathways that convert free fatty acids or fatty acid derivatives into alka(enes have been identified or reconstituted. The discoveries open a door to achieve microbial production of alka(enes with high efficiency. The modules derived from these alka(ene biosynthetic pathways can be assembled as biological parts and synthetic biology strategies can be employed to optimize the metabolic pathways and improve alka(ene production.

Muuseumisõbra tiitli sai Rein Veidemann

Index Scriptorium Estoniae

2017-01-01

Muuseumiühing andis tänavuse muuseumisõbra tiitli ajakirjanikule ja kirjandusteadlasele Rein Veidemannile kirjanike muuseumide kaitseks meedias välja astumise ning Vilde ja Tammsaare Sõprade Seltsi loomisele kaasa aitamise eest

Tiit Land: kui saaks Tallinnast Võrru kolme tunni asemel kahega / intervjueerinud Andres Kalvik

Index Scriptorium Estoniae

Land, Tiit, 1964-

2016-01-01

Intervjuu Tallinna ülikooli rektori valimised võitnud Tiit Landiga. Ülikoolis algatatud reformidest, välistudengitest ülikoolis, väljalangevusest, ülikoolide koostööst ühiste õppekavade osas. Ka Tiit Landi erialast biokeemiast

Päästes euroopa naaritsat / Tiit Maran ; vahendas Jaanus Vaiksoo

Index Scriptorium Estoniae

Maran, Tiit, 1959-

2007-01-01

16. jaanuaril 2007 kaitses Tallinna Loomaaia teadussekretär ja liigikaitse labori juhataja Tiit Maran Tallinna Ülikoolis doktoritööd "Euroopa naarits, Mustela lutreola, (Linnaeus 1761) looduskaitsebioloogia : liigi väljasuremine ja selle põhjused". Doktoritöö kajastab aastatepikkuse uurimise tulemusi, kuid veelgi tähtsam on Tiit Marani igapäevane praktiline töö euroopa naaritsa päästmise nimel. Euroopa naaritsa asurkonna loomisest Hiiumaal

Juugendit armastav 21. sajandi kodu / Ene Vool

Index Scriptorium Estoniae

Vool, Ene, 1948-

2006-01-01

Kaunisse ümbrusse ehitatud stiilne maja, mille projekteeris Margit Kõrts. Sisustus, valgustid ja mööbel on juugendstiilis ja Kadri Tarbe-Pärtelpoeg projekteeris sobiva trepivõre ning trafarettmaalingu tegi Ruth Tuvike, kopeerides Alphonse Maria Mucha seinamaalingut. Mirjam Peili kommentaar

Tiit Kuusmik : "Linnajuhil peab olema julgust võtta otsuseid üksi vastu" / Tiit Kuusmik ; interv. Gerli Romanovitsh

Index Scriptorium Estoniae

Kuusmik, Tiit, 1950-

2005-01-01

Ilmunud ka: Severnaja Poberezhje : Subbota 22. oktoober lk. 3. 12 aastat Kiviõli linna juhtinud Tiit Kuusmik on otsustanud asuda Riigikogus asendama Mihhail Stalnuhhinit, kes jätkab Narva volikogus. Kommenteerivad Teet Kuusmik ja Vladimir Kruzman

Kommunikatsioonijuhtide professionaalsed praktikad / Triin Vihalemm, Margit Keller, Maie Kiisel ; intervjueerinud Inga Kald

Index Scriptorium Estoniae

Vihalemm, Triin, 1968-

2015-01-01

Tartu Ülikooli ühiskonnateaduste instituudi õppejõudude Triin Vihalemma, Margit Kelleri ja Maie Kiiseli kommunikatsiooniõpikust "From intervention to social change : a guide to reshaping everyday practices"

ENES the European Network for Earth System modelling and its infrastructure projects IS-ENES

Science.gov (United States)

Guglielmo, Francesca; Joussaume, Sylvie; Parinet, Marie

2016-04-01

The scientific community working on climate modelling is organized within the European Network for Earth System modelling (ENES). In the past decade, several European university departments, research centres, meteorological services, computer centres, and industrial partners engaged in the creation of ENES with the purpose of working together and cooperating towards the further development of the network, by signing a Memorandum of Understanding. As of 2015, the consortium counts 47 partners. The climate modelling community, and thus ENES, faces challenges which are both science-driven, i.e. analysing of the full complexity of the Earth System to improve our understanding and prediction of climate changes, and have multi-faceted societal implications, as a better representation of climate change on regional scales leads to improved understanding and prediction of impacts and to the development and provision of climate services. ENES, promoting and endorsing projects and initiatives, helps in developing and evaluating of state-of-the-art climate and Earth system models, facilitates model inter-comparison studies, encourages exchanges of software and model results, and fosters the use of high performance computing facilities dedicated to high-resolution multi-model experiments. ENES brings together public and private partners, integrates countries underrepresented in climate modelling studies, and reaches out to different user communities, thus enhancing European expertise and competitiveness. In this need of sophisticated models, world-class, high-performance computers, and state-of-the-art software solutions to make efficient use of models, data and hardware, a key role is played by the constitution and maintenance of a solid infrastructure, developing and providing services to the different user communities. ENES has investigated the infrastructural needs and has received funding from the EU FP7 program for the IS-ENES (InfraStructure for ENES) phase I and II

Kontserdisari kutsub "Klavessiinisalongi"

Index Scriptorium Estoniae

2008-01-01

Rakvere Kaurikooli saalis toimuvatest kontsertidest: 7. dets."iViva Espagna!" (esinevad klavessiiniduo Ene Nael - Kristiina Are ja näitleja Tarmo Song), 15. veebr. "Häälemeelne" (laulja Kelli Pärnaste ja kitarrist Tiit Korsar, klavessinist Ene Nael) ja 26. apr. "Fiori musicali" (Tallinna Vanalinna Hariduskolleegiumi, Tallinna Muusikakeskkooli ja Rakvere Kaurikooli klavessiiniõpilased)

Tiit Tammsaar GMO-toidu vastu / Sigrid Laev

Index Scriptorium Estoniae

Laev, Sigrid

2003-01-01

Põllumajandusminister Tiit Tammsaare sõnul ei suuda Eesti geneetiliselt muundatud toidule (GMO) tõenäoliselt vastu seista. EL-i riikide esindajad ei leidnud üksmeelt, kas lubada liitu uut tüüpi maisi Bt-11

Vilistlastest kutseõpetajad Tartu kutsekoolidest / Jaan Sakson, Toomas Lepik, Margit Tennosaar, Kairi Partsioja

Index Scriptorium Estoniae

2007-01-01

Küsimustele vastavad metalliala kutseõpetaja Jaan Sakson, CISCO labori instruktor Toomas Lepik, veebidisaini ja e-kaubanduse kutseõpetaja Margit Tennosaar ja kelneri eriala õpilane Kairi Partsioja

Eesti noorim metsavend / Tiit Vahemets

Index Scriptorium Estoniae

Vahemets, Tiit

2007-01-01

Katkendid Tiit Vahemetsa raamatust "Lapsena metsas". Järgneb: 6. dets., 13.dets., 20.dets. lk. 7, 2008: 4. jaan., 10. jaan., 17. jaan., 24. jaan., 31. jaan., 7. veebr., 14. veebr., 21. veebr., 28. veebr., 6. märts, 13. märts, 20. märts, 27. märts, 3. apr., 10. apr., 17. apr., 24. apr., 8. mai, 15. mai

Teatrinukkude muuseum = Museum of Puppet Arts / Liis Lindvere, Raili Paling ; intervjueerinud Margit Mutso

Index Scriptorium Estoniae

Lindvere, Liis

2011-01-01

Tallinnas Lai 1/Nunne 8 asuva muuseumi sisekujundusest. Sisearhitektid: Margit Argus, Raili Paling, Liis Lindvere (KOKO Arhitektid). Ekspositsiooni autor Kalju Kivi. Siltide ja viitade kujunduse autor Andrus Kõresaar

Teatriankeet 2007/2008

Index Scriptorium Estoniae

2008-01-01

Teatrihooaega 2007/2008 hindavad teatrikriitikud, -loolased, -uurijad. Nimetatud ka parimad lavastused 2007/2008 - A. H. Tammsaare / Urmas Lennuk "Wargamäe Wabariik" (Tallinna Linnateater, lav. Elmo Nüganen), Tiit Ojasoo ja Ene-Liis Semper "Ruja" (Vanemuine, lav. Tiit Ojasoo), Veljo Tormis "Eesti meeste laulud" (Von Krahli Teater ja Nargen Opera, lav. Peeter Jalaks, muusikaline juht Tõnu Kaljuste), Anton Tshehhov "Kajakas" (Endla, lav. Andres Noormets)

Elusloodus õpetab teadlasi / Tiit Kändler

Index Scriptorium Estoniae

Kändler, Tiit, 1948-

2007-01-01

Korduvalt on juhtunud, et füüsikud, insenerid ja keemikud on midagi leiutanud ning siis on bioloogid avastanud, et loodus on sarnase asja leiutanud juba sadu miljoneid aastaid varem. Tiit Kändler räägib bioinspiratsioonist, võttes aluseks Peter Forbesi raamatu The geckoѫs foot : 2006

Sõmeru keskushoone = Sõmeru centre building / Ralf Lõoke ; intervjueerinud Margit Mutso

Index Scriptorium Estoniae

Lõoke, Ralf, 1978-

2011-01-01

Sõmeru keskushoone (Kooli 2, Sõmeru alevik) arhitektuursest lahendusest. Arhitektid Maarja Kask, Karli Luik ja Ralf Lõoke pälvisid Eesti Kultuurkapitali aastapreemia (2010) kõrgetasemelise panuse eest Eesti maa-arhitektuuri: Sõmeru keskushoone (kaasautorid Kristiina Arusoo ja Margit Argus) ja Eesti Maanteemuuseumi välialad (kaasautor Pelle-Sten Viiburg)

Romantikutest, armastusega ja ja halastuseta / Margit Tõnson

Index Scriptorium Estoniae

Tõnson, Margit, 1978-

2010-01-01

Kolmest suvelavastusest: Tiit Palu dramatiseering Gustave Flaubert'i teosest "Madame Bovary" Endla teatris, Marcel Pagnoli "Tuulesaared", lavastaja Maria Peterson - Theatrum ja MTÜ Arhipelaag Hiiumaal Tahkuna tuletorni all ja Eugene O'Neilli "Iha jalakate all", lavastaja Roman Baskin, MTÜ Kell Kümme Kurgjal Jakobsoni talumuuseumis

Tilda Swintoni uskumatu elu / Tilda Swinton ; intervjueerinud Peter Cowie, refereerinud Margit Tõnson

Index Scriptorium Estoniae

Swinton, Tilda, 1960-

2009-01-01

Berliini 59. rahvusvahelise filmifestivali poolt ellu kutsutud ja noortele talentidele mõeldud "Berlinale Talent Campus" vestluste sari nimega "Rambivalgus". Vestlust Berlinale võistlusprogrammi žürii esinaise Tilda Swintoniga modereeris filmiajaloolane Peter Cowie, vahendas Margit Tõnson

Uus õpik julgustab maailma parandama / Triin Vihalemm, Margit Keller, Maie Kiisel ; intervjueerinud Annela Laaneots

Index Scriptorium Estoniae

Vihalemm, Triin, 1968-

2013-01-01

Intervjuu Tartu Ülikooli ajakirjanduse ja kommunikatsiooni instituudi õppejõudude Triin Vihalemma, Margit Kelleri ja Maie Kiiseliga nende e-õpikust "Kuidas parandada maailma? Kommunikatsioon sotsiaalsete muutuste kujundamisel"

Uus Tartu Loodusmaja = The new Tartu Nature Building / Tiit Sild

Index Scriptorium Estoniae

Sild, Tiit, 1977-

2010-01-01

Tartu Loodusmaja avalikust arhitektuurivõistlusest, kvalifitseerimistingimustest, energiatõhususest ja žürii tööst. 1. preemia sai töö "Känd", autorid Diana Taalfeld, Kai Süda, Margit Valma, Martin Kinks (Urmas Lõokese AB / Karisma Arhitektid). Nimetatud 2. ja 3. koha saanud tööd, autorid

Why do dismissed employees need art? / Margit Säde

Index Scriptorium Estoniae

Säde, Margit, 1984-

2009-01-01

"Koondatute kunsti keskus" Tallinna Postimajas 23.-30. aprillini 2009. Eesti Kunstiakadeemia üliõpilaste sotsiaalse kunstiprojekti eesmärgist, sellest osavõtust, dokumentaalfilmi õpikojast, mida viisid läbi Anna Škodenko, Anne-Liis Kogan ja Margit Säde. Valminud tööd ja projekti dokumentatsioon olid väljas detsembris 2009 avatud Anders Härmi kureeritud näitusel "Blue-Collar Blues" Tallinna Kunstihoones

Estraadi comeback. Ojasoo - Semperi "Nafta!" kui XXI sajandi estraadilavastus / Ott Karulin

Index Scriptorium Estoniae

Karulin, Ott, 1980-

2006-01-01

Estraadi sugemetega etendustest ja estraaditeatrist Eestis. Pikemalt peatutakse Ene-Liis Semperi ja Tiit Ojasoo lavastustel "Nafta", "No More Tears", "Julia" (aut. W. Shakespeare - T. Ojasoo) ja "Kuningas Ubu" (aut. A. Jarry)

Tiit Pääsuke - maalija par excellence / Ants Juske

Index Scriptorium Estoniae

Juske, Ants, 1956-2016

2006-01-01

Tiit Pääsukese loomingust, kes peab ennast inimeste maalijaks, kuid nad on talle värviga modelleerimisel vaid vahendiks põneva pildimaailma loomisel. Illustratsiooniks "Punase kleidiga naine". Õli, lõuend, 1974. Eesti Kunstimuuseum

Süütust näpates

Index Scriptorium Estoniae

2007-01-01

Tanel Veenre fotoseeria teatrikostüümidest Draamateatri laval. Stilist: Hanna Tiidus. Naine: Merle Palmiste. Poiss: Joonas (MJ-Models). Jumestus: Margit Soosaar. Juuksed: Jelena Radtsenkova. Kostüümid etendustest "Rohuvoodi" (Aime Unt), "Rehepapp", "Tõeline inspektor koer" (Ene-Liis Semper), "Liilia" (Lilja Blumenfeld), "Mort" (Kersti Varrak), "Potilaadale" (Reet Aus), "Amadeus" (Krista Tool)

5 küsimust Ene Läkile / Ene Läkk ; interv. Ell-Maaja Randküla

Index Scriptorium Estoniae

Läkk, Ene, 1957-

2006-01-01

Ene Läkist, kes on alates 2005. aastast interjööri-, disaini- ja arhitektuuriajakirja "Ruum" peatoimetaja. Ene Läkk, Eesti Sisearhitektide Liidu 2005. a. aastapreemia nominent ajakirjandusliku tegevuse eest, ajakirjast "Ruum". Ill.: 6 värv. vaadet, foto ajakirjanikust

Kunstnike moraalsed valikud kultuurikonfliktides = The moral choices of artists in cultural conflicts

Index Scriptorium Estoniae

2006-01-01

Kaasaegse Kunsti Eesti Keskuse 4. ettekannete päev "Kunstnike moraalsed valikud kultuurikonfliktides" sarjast "Lisandusi eesti kunstiloole" Tallinna Kunstihoones 27.04.2006. Kava, esinevad Margit Sutrop, Johannes Saar, Andres Tali, Marek Järvik, Ene-Liis Semper ja Eero Epner, Marco Laimre. Soome filmirežissööri Pirjo Honkasalo dokumentaalfilmi "Melanhoolia kolm tuba" presentatsioon

Rakvere uus bussijaam = New Bus Terminal in Rakvere / Margit Mutso, Madis Eek

Index Scriptorium Estoniae

Mutso, Margit, 1966-

2000-01-01

Ühekorruseline bussijaamahoone, ooteruum paikneb klaasmahus. Projekteerija, istemööbli disain: Arhitektuuribüroo Eek & Mutso. Arhitektid Margit Mutso, Madis Eek, kaasa töötas Reio Avaste. Konstruktiivne osa, eriosad: Projektbüroo Talone. Projekt 1999, ehitus 1999-2000. 12 ill. Asendiplaan, I korruse plaan, lõiked, välis- ja sisevaated

Ajatu Ita Ever pühendab end jäägitult teatrile / Rein Veidemann

Index Scriptorium Estoniae

Veidemann, Rein, 1946-

2006-01-01

Näitleja Ita Everi 75. sünnipäeva puhul. Arvamust tema kohta avaldavad ka näitlejad Aleksander Eelmaa, Rasmus Kaljujärv, Tiit Sukk, teatrikunstnikud Ene-Liis Semper ja Aime Unt, teatrinõunik Tõnu Lensment

Eesti pensionisüsteem Euroopa Liidu ühiste pensionimärkide valguses / Lauri Leppik, Ene-Margit Tiit, Andres Võrk

Index Scriptorium Estoniae

Leppik, Lauri, 1964-

2004-01-01

Eesti pensionisüsteemi probleemid on senistest liikmesriikidest erinevad: pensionisüsteemi jätkusuutlikkus on hea ja pensionäride vaesusrisk ei ole kõrge, kuid asendusmäär on suhteliselt madal. See tähendab, et ei suudeta tagada EL-i pensionieesmärki, mis taotleb, et inimesel oleks pensionile jäädes võimalk säilitada oma varasem elatustase. Diagramm. Tabelid. Graafikud

Hydroxylative activity of Aspergillus niger towards androst-4-ene and androst-5-ene steroids.

Science.gov (United States)

Świzdor, Alina; Panek, Anna; Milecka-Tronina, Natalia

2017-10-01

Aspergillus niger, one of fungal species most frequently used for experimental and industrial-scale biotransformations of various organic compounds, is generally known to transform steroids at 16β position. In this work, application of the strain A. niger KCH910 to bioconversion of dehydroepiandrosterone (DHEA), androstenediol and testosterone is described, with emphasis on the metabolic steps leading to the products. Evidence from this study indicated that incubated 5-ene steroids underwent bioconversion within two metabolic pathways: oxidation by the action of 3β-HSD (3β-hydroxysteroid dehydrogenase) to 4-ene steroids, and minor allylic hydroxylation to epimeric 7-alcohols. Further transformation of the 3-oxo-4-ene metabolites resulted in non-selective 16-hydroxylation. It is the first report on an A. niger strain able to introduce not only 16β- but also 16α-hydroxyl function into steroids. Copyright © 2017. Published by Elsevier Inc.

Mõeldes arhitektuuri välkloengutele = Considering flash lectures on architecture / Margit Mutso

Index Scriptorium Estoniae

Mutso, Margit, 1966-

2010-01-01

7. veebruaril 2008 Von Krahli Teatris alanud arhitektuuri välkloengutest, mille eesmärk oli haarata avalikkust kaasa mõtlema, rääkima meid ümbritsevast keskkonnast ning viia ühiskonda arusaamist, et arhitektuur on meie kõigi asi. Arhitektuurist kutsuti rääkima tuntud äri- ja kultuuriinimesi. Välkloenguid modereerisid Ülar Mark, Margit Mutso ja Mattias Agabus

Hybrid Organic/Inorganic Thiol-ene-Based Photopolymerized Networks

OpenAIRE

Schreck, Kathleen M.; Leung, Diana; Bowman, Christopher N.

2011-01-01

The thiol-ene reaction serves as a more oxygen tolerant alternative to traditional (meth)acrylate chemistry for forming photopolymerized networks with numerous desirable attributes including energy absorption, optical clarity, and reduced shrinkage stress. However, when utilizing commercially available monomers, many thiol-ene networks also exhibit decreases in properties such as glass transition temperature (Tg) and crosslink density. In this study, hybrid organic/inorganic thiol-ene resins ...

Märkmeid ja viiteid Ojasoo-Semperi teatri kohta / Aare Pilv

Index Scriptorium Estoniae

Pilv, Aare, 1976-

2006-01-01

Tiit Ojasoo ja Ene-Liis Semperi NO99 teater Eesti teatripildis kui uudne nähtus. Peatutakse pikemalt lavastustel "Vahel on tunne, et elu saab otsa ja armastust polnudki", "Seitse samuraid", aga ka "Verevennad" ja Draamateatris tehtud lavastusel "Julia". Kommentaarid, lk. 20

Majanduse struktuur kujuneb isevoolu / Tiit Made, Rein Kask ; interv. Ester Shank

Index Scriptorium Estoniae

Made, Tiit, 1940-

1999-01-01

Riigikogu majanduskomisjoni esimees Tiit Made ja tema asetäitja Rein Kask nentisid Maailmakaubanduskeskuse klubi kokkutulekul, et kaheksa aasta jooksul ei ole Eesti valitsused suutnud ette näha, millise struktuuriga majandus peaks meie riigis kujunema

"Tere! Head teatripäeva!" : Rakveres jagati auhindu mulluste teatriteenete eest / Verni Leivak

Index Scriptorium Estoniae

Leivak, Verni, 1966-

2009-01-01

Rakvere Teatris toimunud teatriauhindade jagamisest. Lisatud aastaauhindade laureaadid - Tiit Ojasoo ja Ene-Liis Semper parim lavastus ("Ruja"), Lembit Peterson - lavastaja auhind ("Maarja kuulutamine" ja "Linn"), Maria Peterson ja Laura Peterson - naisnäitleja auhind, Marius Peterson - meesnäitleja auhind, Piret Laurimaa - naiskõrvalosa auhind, Rain Simmul - meeskõrvalosa auhind, Liisi Eelmaa - kunstniku auhind, Ain Saviauk - žürii eriauhind, Valle-Sten Maiste - Reet Neimari kriitikaauhind, Arvo Volmer - muusikalavastuse auhind, Eve Andre - balletilavastuse auhind, Jaan Undusk - algupärase dramaturgia auhind, Marius Peterson - sõnalavastuse muusikalise kujunduse auhind, Tiina Tauraite ja Margus Prangel - Ants Lauteri auhind, Lembit Peterson - Priit Põldroosi auhind, Mart Madiste - Georg Otsa auhind, Sigrid Orusaar - Otto Hermanni auhind, Tiit Härm - Rahel Olbrei auhind, Ene-Liis Semper - Natalie Mei auhind, Jevgeni Ibragimov - Salme Reegi auhind, Margus Alver - Aleksander Kurtna auhind, Toomas Suuman - Karl Adra auhind, Sten Karpov ja Uku Uusberg - Kristallkingakese auhind

Ene Sepp esitles esikteost "Medaljon" / Heli Talinurm

Index Scriptorium Estoniae

Talinurm, Heli

2009-01-01

Ene Sepp esitles 19. veebruaril Rapla Keskraamatukogus oma raamatut, mis pälvis kolmanda koha Eesti Lastekirjanduse Teabekeskuse ja kirjastuse Tänapäev 2008. aasta noorsooromaani võistlusel. Ly Ehini mõtteid, mida Ene Sepa raamat temas tekitas

Teater post-perspektiivis / Luule Epner

Index Scriptorium Estoniae

Epner, Luule, 1953-

2006-01-01

Post-mõistetest - poststrukturalistlikud teooriad, postdramaatiline teater - ja uuest teatrist. Näiteina Tiit Palu lavastus "Mis värvi on vabadus" Mati Undi romaani "Mõrv hotellis" põhjal Endlas, Sasha Pepeljajevi "Kirsiaed" Anton Tshehhovi näidendi ainetel, EMA Kõrgema Lavakunstikooli XXII lennu üliõpilaste ja NO99 näitlejatega, Tiit Ojasoo ja Ene-Liis Semperi "Vahel on tunne, et elu saab otsa ja armastust polnudki" ja "Seitse samuraid" NO99 teatris ja Kristian Smedsi lavastus "Jänese aasta" Von Krahli Teatris, Aare Toikka lavastus "Klammi sõda" VAT Teatris

Arhitektuurikonkursid 2004

Index Scriptorium Estoniae

2004-01-01

Tulemused: Pärnu kergejõustikumaneezh: I preemia - Ralf Lõoke ja Karli Luik; Tartus Raatuse, Pika, Fortuuna ja Põigu tänava vahelise ala hoonestuskava: I - Kai Kuusik ja Taavi Kuri; Aasta betoonehitis 2003: peapreemia - Emil Urbel; Veneetsia IX rahvusvahelise arhitektuuribiennaali "Metamorfoosid" raames eksponeeritava eesti kaasaegse arhitektuuri näituse ideekonkurss: I - Kristjan Holm; äri- ja elumaja Pärnus Aida t. 5: I - Andres Lember; Eesti parim puitehitis 2003-2004: I - Aivo Schults; Eesti parim tellishoone 2003-2004: I- Tiit Trummal; Sõmeru keskusehoone: I - Ralf Lõoke ja Maarja Kask; Eesti Maanteemuuseumi välialade maastikuarhitektuurne ideekonkurss: I - Margit Kärner

Maia Laul / Maia Laul ; interv. Ene Ammer

Index Scriptorium Estoniae

Laul, Maia, 1921-2009

1998-01-01

Maia Laul eriala omandamisest, õppejõududest. Lõpetas 1949. a. Tallinna Riikliku Tarbekunsti Instituudi. Alar Kotli käealusena "Estonia" teatri taastamisprojekti juures. Peeter Tarvase ja August Volbergiga ENSV paviljponi kujundamas Moskvas VDNHs. Töötamisest ARSis. Sisearhitektuur ja monumentaalkunst (koostöö Eva Jänesega). Esinemistest näitustel "Ruum ja vorm". Ühiskondlike hoonete sisekujundustest. Vanaturu apteek (klaasigraafika Tiit Jürna)

Kas majanduskuritegusid uuritakse vähe? / Ken-Marti Vaher, Tiit Vähi

Index Scriptorium Estoniae

Vaher, Ken-Marti, 1974-

2010-01-01

Küsimusele vastavad riigikogu õiguskomisjoni esimees Ken-Marti Vaher ja Silmet Grupi juhatuse esimees Tiit Vähi. Vastukaja artiklile: Krjutškova, Katariina. Majanduskuriteod vaeslaste osas // Äripäev (2010) 19.-22. aug., lk. 10-11

Eesti Ajaloomuuseumi Suurgildi hoone. Püsinäitus "Visa hing. 11 000 aastat Eesti ajalugu" = Restoration of the Estonian History Museum Great Guild Hall building, permanent exhibition "Spirit of survival. 11,000 years of Estonian history" / Margit A

Index Scriptorium Estoniae

Argus, Margit, 1981-

2012-01-01

Suurgildi hoone renoveerimisest, sisekujundusest, ekspositsioonist. Sisearhitektid Margit Aule, Liis Lindvere, Margit Argus (Koko Arhitektid). Restaureerimisarhitekt: Mart Keskküla (Restor). Graafilise disaini autorid Jan Tomson, Indrek Sirkel, Mikk Heinsoo, Kaarel Nõmmik, Andrus Kõresaar (Produktsioonigrupp). Ekspositsiooni multimeedia ja interaktsioon: Produktsioonigrupp

Teatri aastaauhindade nominendid

Index Scriptorium Estoniae

2006-01-01

Lavastajaauhind : Merle Karusoo, Elmo Nüganen, Tiit Ojasoo, Ene-Liis Semper, Kristian Smeds, Hendrik Toompere jun, Ingomar Vihmar ; kunstnikuauhind : Iir Hermeliin, Liina Keevallik, Ene-Liis Semper, Aime Unt, Ervin Õunapuu ; naisnäitleja auhind : Ülle Kaljuste, Kaie Mihkelson, Harriet Toompere, Marika Vaarik, Liina Vahtrik ; meesnäitleja auhind : Ain Lutsepp, Rein Oja, Rain Simmul, Tarvo Sõmer, Tambet Tuisk, Aarne Üksküla ; Balleti- ja tantsuteater : Marina Tshirkova, Seki Hirotaka, Mari Savitski, Oksana Titova, Taavet Jansen, Sasha Pepeljajev, Katrin Essenson ja Tantsuteater Fine 5

Teatri aastaauhindadele kandideerijad selgunud

Index Scriptorium Estoniae

2006-01-01

Lavastajaauhind : Merle Karusoo, Elmo Nüganen, Tiit Ojasoo, Ene-Liis Semper, Kristian Smeds, Hendrik Toompere jun, Ingomar Vihmar ; kunstnikuauhind : Iir Hermeliin, Liina Keevallik, Ene-Liis Semper, Aime Unt, Ervin Õunapuu ; naisnäitleja auhind : Ülle Kaljuste, Kaie Mihkelson, Harriet Toompere, Marika Vaarik, Liina Vahtrik ; meesnäitleja auhind : Ain Lutsepp, Rein Oja, Rain Simmul, Tarvo Sõmer, Tambet Tuisk, Aarne Üksküla ; Balleti- ja tantsuteater : Marina Tshirkova, Seki Hirotaka, Mari Savitski, Oksana Titova, Taavet Jansen, Sasha Pepeljajev, Katrin Essenson ja Tantsuteater Fine 5

Üks suund, kaks vaadet / Tiit Land, Argo Ralja ; intervjueerinud Katrin Reimann

Index Scriptorium Estoniae

Land, Tiit, 1964-

2012-01-01

Intervjuu Tallinna Ülikooli rektori Tiit Landi ja Üliõpilaskonna juhatuse esimehe Argo Raljaga Tallinna Ülikooli iseloomustavatest märksõnadest möödunud aastal, positsioonist Eesti hariduses, ülikooli koostööst instituutide ja kolledžitega

Hybrid Organic/Inorganic Thiol-ene-Based Photopolymerized Networks.

Science.gov (United States)

Schreck, Kathleen M; Leung, Diana; Bowman, Christopher N

2011-09-15

The thiol-ene reaction serves as a more oxygen tolerant alternative to traditional (meth)acrylate chemistry for forming photopolymerized networks with numerous desirable attributes including energy absorption, optical clarity, and reduced shrinkage stress. However, when utilizing commercially available monomers, many thiol-ene networks also exhibit decreases in properties such as glass transition temperature (T(g)) and crosslink density. In this study, hybrid organic/inorganic thiol-ene resins incorporating silsesquioxane (SSQ) species into the photopolymerized networks were investigated as a route to improve these properties. Thiol- and ene-functionalized SSQs (SH-SSQ and allyl-SSQ, respectively) were synthesized via alkoxysilane hydrolysis/condensation chemistry, using a photopolymerizable monomer [either pentaerythriol tetrakis(3-mercaptopropionate) (PETMP) or 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione (TATATO)] as the reaction solvent. The resulting SSQ-containing solutions (SSQ-PETMP and SSQ-TATATO) were characterized, and their incorporation into photopolymerized networks was evaluated.

Autentsuse ihalus ja strateegiad tänases Eesti teatris / Anneli Saro

Index Scriptorium Estoniae

Saro, Anneli, 1968-

2007-01-01

Aluseks võetud lavastused "Rätsep" (lav. Mart Koldits) ja "Nii see on kui teile nii näib" (lav. Adolf Shapiro) Tallinna Linnateatris, "Hamletid" (lav. Sasha Pepeljajev) ja "Faust" (lav. Taavi Eelmaa) Von Krahli Teatris, Tiit Ojasoo ja Ene-Liis Semperi lavastus "Nafta!" NO99 teatris. Kasut. kirjandus lk. 126

Me suudame ajaga kaasas käia / interv. Ene Riet

Index Scriptorium Estoniae

2003-01-01

Eesti raamatukoguhoidjate VIII kongressi (9.-10. juuni 2002) delegaatitelt küsiti arvamust Eesti raamatukogunduse kohta, vastasid: Kalli Kuhi, Sirje Okapuu, Toomas Liivamägi, Sirje Lauring-Vaska, Helve Sreiberg, Irina Kruusla, Ädu Neemre, Tiit Margna, Valentina Brovina, Asko Tamme, Meeli Veskus

Synthesis of some 16,17-secoandrost-5-ene derivatives

Directory of Open Access Journals (Sweden)

Gaković Andrea R.

2010-01-01

Full Text Available Starting from 3β-acetoxy-17-oxo-16,17-secoandrost-5-ene-16-nitrile (1, 3β-acetoxy-16,17-secoandrost-5-ene-16-nitrile (4 was synthesized by a three-stage procedure. First, the formyl group of compound 1 was reduced, to yield the alcohol 2. Compound 2 was further transformed to the mesyloxy derivative 3, whose reduction with NaBH3CN gave compound 4. Apart from compound 4 as the main reaction product, two additional products were obtained, for which the GC/MS analysis suggested that they are 8(14 and 14 derivatives of compound 4. Compound 4 was transformed into 3β-hydroxy-16,17-sesoandrost-5-ene-16-nitrile (7, the Oppenauer oxidation of which afforded 3-oxo-16,17-secoandrost-4-ene-16-nitrile (8.

Ene Käpp ali optimizem

Directory of Open Access Journals (Sweden)

Dušana Findeisen

1998-12-01

Full Text Available Na »Konferenci o vlogi in organizaciji izobraževanja odraslih v času prehoda«, ki je bila novembra lani v Tallinnu, glavnem mestu Estonije, smo srečevali nekaj razsvetljenih obrazov organizatorjev. Med njimi je bila Ene Kapp, kratko pristriženih las, živahnega videza in prodornega glasu. Ene Kapp je neprestano bedela nad nami. Tisti, ki so povezani z estonskim izobraževanjem odraslih, jo poznajo že dolgo. Srečujejo se z njo na ANDRAS-u, estonskem združenju za izobraževanje odraslih.

Thiol-ene/methacrylate systems for mechanical damping

Science.gov (United States)

McNair, Olivia; Senyurt, Askim; Wei, Huanyu; Gould, Trent; Piland, Scott; Hoyle, Charles; Savin, Daniel

2010-03-01

Ternary thiol-ene-methacrylate (TEMA) networks as materials for mechanical energy damping are unique to the sports world. Using a photoinitiation process, TEMA systems are formed via an initial thiol-ene step-growth mechanism along with traditional radical polymerization of acrylate and ene monomers. Final networks have two-part morphologies: acrylate homopolymer sectors imbedded in a multi-component mesh. Several (TEMA) systems have been synthesized and analyzed via thermal and mechanical probing. Initial studies on these ternary systems have shown excellent properties compared to traditional ethylene vinyl alcohol (EVA) copolymers. For example, PEMA networks exhibit glass transition temperatures 33 K higher than EVA, resulting in improved damping at room temperature. This research will help develop relationships between tan delta, glass transition and their effects on mechanical energy damping for ternary (TEMA) systems.

Narva Jõesuu võib Tiit Vähilt erastatud hoone tagasi nõuda / Tanel Mazur

Index Scriptorium Estoniae

Mazur, Tanel, 1971-

2009-01-01

Narva-Jõesuu kuursaali erastanud firma Navesco, mille enamusosanik on Tiit Vähi kontrollitav Silmet Grupp, on linna väitel oma investeerimiskohustusi täitnud vaid 2006. aastal. Firma vastuväidetest

5-Ene-4-thiazolidinones - An efficient tool in medicinal chemistry.

Science.gov (United States)

Kaminskyy, Danylo; Kryshchyshyn, Anna; Lesyk, Roman

2017-11-10

The presented review is an attempt to summarize a huge volume of data on 5-ene-4-thiazolidinones being a widely studied class of small molecules used in modern organic and medicinal chemistry. The manuscript covers approaches to the synthesis of 5-ene-4-thiazolidinone derivatives: modification of the C5 position of the basic core; synthesis of the target compounds in the one-pot or multistage reactions or transformation of other related heterocycles. The most prominent pharmacological profiles of 5-ene derivatives of different 4-thiazolidinone subtypes belonging to hit-, lead-compounds, drug-candidates and drugs as well as the most studied targets have been discussed. Currently target compounds (especially 5-en-rhodanines) are assigned as frequent hitters or pan-assay interference compounds (PAINS) within high-throughput screening campaigns. Nevertheless, the crucial impact of the presence/nature of C5 substituent (namely 5-ene) on the pharmacological effects of 5-ene-4-thiazolidinones was confirmed by the numerous listed findings from the original articles. The main directions for active 5-ene-4-thiazolidinones optimization have been shown: i) complication of the fragment in the C5 position; ii) introduction of the substituents in the N3 position (especially fragments with carboxylic group or its derivatives); iii) annealing in complex heterocyclic systems; iv) combination with other pharmacologically attractive fragments within hybrid pharmacophore approach. Moreover, the utilization of 5-ene-4-thiazolidinones in the synthesis of complex compounds with potent pharmacological application is described. The chemical transformations cover mainly the reactions which involve the exocyclic double bond in C5 position of the main core and correspond to the abovementioned direction of the 5-ene-4-thiazolidinone modification. Copyright © 2017 Elsevier Masson SAS. All rights reserved.

Letni sezon : ot avangardista do "Sjurrealistov" / Boris Tuch

Index Scriptorium Estoniae

Tuch, Boris, 1946-

2006-01-01

Suvelavastustest: Andrus Kivirähk "Sürrealistid" Viinistus (lavastaja Hendrik Toompere jun), Mart Kivastik "Kits viiuli ja õngega" Viinistus (lavastaja Raimo Pass), Alfred Jarry "Kuningas Ubu" Teater NO99 Haapsalu Kiltsi lennuvälja angaarides (lavastajad Ene-Liis Semper ja Tiit Ojasoo), Jaan Tätte "Kaev" Tallinna Linnateatri siseõues (lavastaja Indrek Sammul)

IS-ENES project management - lessons learnt

Science.gov (United States)

Parinet, Marie; Guglielmo, Francesca; Joussaume, Sylvie

2017-04-01

IS-ENES is the distributed e-infrastructure of models, model data and metadata of the European Network for Earth System Modelling (ENES). It has benefitted from two EC FP7 grants and aims towards further European and national funding to achieve sustainability. We highlight here several challenges related to project management that have risen in the course of these two project-phases spanning 8 years. Some challenges are related to the heterogeneity of the activities within IS-ENES, with different groups working on very diverse activities, not necessarily strictly interdependent. An immediate consequence is the need of implementing and setting up in early phases of the project efficient collection and circulation of information to preserve and reinforce the systemic view of the infrastructure as a whole and the pursuit of common goals, including coordinated provision of services. Toward and beyond such common goals, managing IS-ENES, covering both scientific and more strictly management-related aspects, implies a double-paced approach: besides setting up efficient project workflow, there is the need of setting up longer term objectives. This implies, within the project lifetime, to elaborate and implement a coherent organizational (consistent with scientific goals, funding schemes, research and technology landscape) strategy to pursue these goals beyond the project itself. Furthermore, a series of more generic project management challenges will also be listed and can be gathered around 3 main objectives: ease the internal processes in order to optimize the work, anticipate delays and budget issues, and motivate the project teams by ensuring an efficient internal and external communication.

Multi-chamber and multi-layer thiol-ene microchip for cell culture

DEFF Research Database (Denmark)

Tan, H. Y.; Hemmingsen, Mette; Lafleur, Josiane P.

2014-01-01

We present a multi-layer and multi-chamber microfluidic chip fabricated using two different thiol-ene mixtures. Sandwiched between the thiol-ene chip layers is a commercially available membrane whose morphology has been altered with coatings of thiol-ene mixtures. Experiments have been conducted ...... with the microchip and shown that the fabricated microchip is suitable for long term cell culture....

Kas transatlantilised liitlassuhted on tõesti madalseisus? / Tiit Meren

Index Scriptorium Estoniae

Meren, Tiit

2005-01-01

NATO Reservohvitseride Konföderatsiooni (CIOR) ja Konrad Adenaueri Fondi koostöös 30. jaanuarist kuni 3. veebruarini 2005 Saksamaal Wesselingis korraldatud rahvusvahelisest seminarist "NATO, the European Union and the Global war on terrorism. No go? - Routine? - New beginning?" (NATO, Euroopa Liit ja ülemaailmne sõda terrorismi vastu. Loobumine? - Rutiin? - Uus algus?). Eesti delegatsiooni kuulusid EROK president leitnant Heino Piirsalu ja EROK välistoimkonna esimees Tiit Meren. CIOR-i konverentsist Brüsselis

Tiit Land: Anname panuse Alzheimeri tõve võimalikuks raviks / Kristel Toom

Index Scriptorium Estoniae

Toom, Kristel

2008-01-01

Tallinna Ülikooli Matemaatika ja Loodusteaduste Instituudis töötab uurimisrühm, kelle huvi on seotud organismis toimuva raua ainevahetuse ning selle häirete tagajärjel ilmnevate haiguslike protsessidega, mille hulka kuulub ka Alzheimeri tõbi. Teadusprojekte juhivad Tiit Land ja Sandra Zetterström Fernaeus

Vaba Läti ehitab / Margit Mutso

Index Scriptorium Estoniae

Mutso, Margit, 1966-

2007-01-01

13.-17.04. 2007 hindas rahvusvaheline žürii Läti parimaid arhitektuuriteoseid. Parim rekonstrueeritud ehitis oli büroohoone Riias Dzirnavu tn. 68 (arhitektid Aleksejs Birjukovs, Andis Silis). Parim tööstushoone oli Ventspilsis asuv mahlakontsentraatide käitlus- ja laohoone (arhitektid Aija Kokina, Andris Kokins, Krista Strelita-Strele). Bürookategooria võiduprojektiks valiti Liepajas Zivju tn. 11/13 paiknev kontorihoone (arhitektid Diana Zalane, Artis Rokis). Parima elamu tiitli pälvis Jurmalas Jura tn. 32 asuv maja (arhitektid Janis Alksnis, Nora Saulespurena, Andris Rubenis). Eramajadest oli parim suvemaja Pavilostas (arhitekt Janis Sauka). Parima maastikuarhitektuur-väikevormi preemia said Gvido Rekis, Anita Neilande, Andris Kausenieks, Didzis Oshenieks Ventspilsi dzhungliraja eest. Sisekujunduspreemia sai originaaldisainiga ekspositsioonikapslitega Grindeksi farmaatsiatoodete näidisteruum Riias

Preparation and Preliminary Dielectric Characterization of Structured C60-Thiol-Ene Polymer Nanocomposites Assembled Using the Thiol-Ene Click Reaction

Directory of Open Access Journals (Sweden)

Hanaa M. Ahmed

2015-11-01

Full Text Available Fullerene-containing materials have the ability to store and release electrical energy. Therefore, fullerenes may ultimately find use in high-voltage equipment devices or as super capacitors for high electric energy storage due to this ease of manipulating their excellent dielectric properties and their high volume resistivity. A series of structured fullerene (C60 polymer nanocomposites were assembled using the thiol-ene click reaction, between alkyl thiols and allyl functionalized C60 derivatives. The resulting high-density C60-urethane-thiol-ene (C60-Thiol-Ene networks possessed excellent mechanical properties. These novel networks were characterized using standard techniques, including infrared spectroscopy (FTIR, differential scanning calorimetry (DSC, dynamic mechanical analysis (DMA, and thermal gravimetric analysis (TGA. The dielectric spectra for the prepared samples were determined over a broad frequency range at room temperature using a broadband dielectric spectrometer and a semiconductor characterization system. The changes in thermo-mechanical and electrical properties of these novel fullerene-thiol-ene composite films were measured as a function of the C60 content, and samples characterized by high dielectric permittivity and low dielectric loss were produced. In this process, variations in chemical composition of the networks were correlated to performance characteristics.

Kelle nimel NO99 seekord kõneleb ja kelle poole pöördub? / Valle-Sten Maiste, Gerda Kordemets, Madli Pesti...[jt.

Index Scriptorium Estoniae

2011-01-01

23. märtsil esietendub Nokia kontserdimajas NO99 lavastus"The Rise and Fall of Estonia", mis saab olema Eesti-teemaliste lavastuste tsükli lõpp. Lavastajad Ene-Liis Semper ja Tiit Ojasoo. Eesti teatrikriitikute ühendus tegi eksperimendi ja otsustas oma teatrimuljed kohe jäädvustada: esietendusjärgsel hilisõhtul vestlesid lavastusest erinevad eesti teatrikriitikud

Highly tailorable thiol-ene based emulsion-templated monoliths

DEFF Research Database (Denmark)

Lafleur, J. P.; Kutter, J. P.

2014-01-01

The attractive surface properties of thiol-ene polymers combined with their ease of processing make them ideal substrates in many bioanalytical applications. We report the synthesis of highly tailorable emulsion-templated porous polymers and beads in microfluidic devices based on off-stoichiometr......The attractive surface properties of thiol-ene polymers combined with their ease of processing make them ideal substrates in many bioanalytical applications. We report the synthesis of highly tailorable emulsion-templated porous polymers and beads in microfluidic devices based on off......-stoichiometry thiolene chemistry. The method allows monolith synthesis and anchoring inside thiol-ene microchannels in a single step. Variations in the monomer stoichiometric ratios and/or amount of porogen used allow for the creation of extremely varied polymer morphologies, from foam-like materials to dense networks...

Tiit Ojasoo: mida igatseb tänapäeva eestlane? / intervjueerinud Kaarel Kressa

Index Scriptorium Estoniae

Ojasoo, Tiit, 1977-

2011-01-01

23. märtsil esietendub Nokia kontserdimajas NO99 lavastus"The Rise and Fall of Estonia", mis saab olema Eesti-teemaliste lavastuste tsükli lõpp. Teatri kunstiline juht Tiit Ojasoo uuest lavastusest, sellele eelnenud lavastusest "Ühtne Eesti suurkogu", NO99 teatrist, teatri tulevikuplaanidest

Tallinna Ülikool / Leif Kalev, Anneli Leinpere, Tiit Land, Alessandro Centonze, Hannes Palang, Liis Kelberg

Index Scriptorium Estoniae

2008-01-01

Ülikooli ja seal õpetatavaid erialasid tutvustavad dotsent Leif Kalev, kunstimagistrant Anneli Leinpere, professor Tiit Land, välisüliõpilane Milanost Alessandro Centonze, vanemteadur Hannes Palang ning kirjaliku tõlke magistrant Liis Kelberg

Otsustava teo päev / Tiit Maksim

Index Scriptorium Estoniae

Maksim, Tiit, 1941-

2005-01-01

Tallinnas Harjumäe nõlval avati Vabaduse monumendi alge - Võrumaalt Urvaste vallast toodud põllukivi, millesse on raiutud "Siia rajatakse vabaduse monument. 29. X 2005", osales ka parlamendiliige, spiiker Ene Ergma

Surface functionalized thiol-ene waveguides for fluorescence biosensing in microfluidic devices

DEFF Research Database (Denmark)

Feidenhans'l, Nikolaj Agentoft; Lafleur, Josiane P.; Jensen, Thomas Glasdam

2013-01-01

-ene waveguides were fabricated from 40% excess thiol thiol-ene to ensure the presence of thiol functional groups at the surface of the waveguide. Biotin alkyne was photografted at specific locations using a photomask, directly at the interface between the microfluidic channel and the thiol-ene waveguide prior...

Suur Miller ja Väike Killer / Tiit Palu, Andrus Allikvee ; intervjueerinud Anu Tonts ja Sven Karja

Index Scriptorium Estoniae

Palu, Tiit, 1970-

1997-01-01

Vanemuises esietenduvad 19. mail Arthur Milleri 'Sööst kuristikku' (lavastaja Andrus Allikvee) ja 20. mail Tracy Lettsi 'Killer Joe' (lavastaja Tiit Palu). Postimehe küsitlus lavastajatele (vastavad samadele küsimustele)

Dream Poetics as a Method of Performance Analysis / Anneli Saro

Index Scriptorium Estoniae

Saro, Anneli, 1968-

2007-01-01

Vaadeldakse draamaklassika näidetele toetudes - Shakespeare'i "Suveöö unenägu", Calder̤ni "Elu on unenägu", Strindbergi "Unenäomäng", "Teel Damascusesse" ja "Kummitussonaat" - unenäo ja teatri poeetilist sarnasust ja selle kaudu analüüsitakse Tiit Ojasoo ja Ene-Liis Semperi Shakespeare'i ainelist "Julia" lavastust Eesti Draamateatris 2004

Joonistus läheb moodi! II / Tiit Pääsuke, Anu Juurak

Index Scriptorium Estoniae

Pääsuke, Tiit, 1941-

2006-01-01

Eesti Kunstiakadeemia joonistuse õppetooli juhatatajad Tiit Pääsuke ja Anu Juurak joonistuse tähendusest ja rollist teiste kunstiliikide seas, suundumustest ja stiilidest ajalises mõttes, kuni 10. IX Tallinna Kunstihoones avatud rahvusvahelisest joonistuste näitusest "Improvisatsioon". 3. IX tantsib näitusel Helena Ehrenbusch, joonistavad Angelika Schneider ja Flo Kasearu, 3.-10. IX improviseerivad kooliõpilased Loit Jõekalda juhendamisel

Fabrication and bonding of thiol-ene-based microfluidic devices

DEFF Research Database (Denmark)

Sikanen, Tiina M; Lafleur, Josiane P.; Moilanen, Maria-Elisa

2013-01-01

In this work, the bonding strength of microchips fabricated by thiol-ene free-radical polymerization was characterized in detail by varying the monomeric thiol/allyl composition from the stoichiometric ratio (1:1) up to 100% excess of thiol (2:1) or allyl (1:2) functional groups. Four different...... properties for each application. Here, a capillary electrophoresis separation is performed to demonstrate the attractive properties of stoichiometric thiol-ene microchips....

Evaluation and Control of Thiol-ene/Thiol-epoxy Hybrid Networks.

Science.gov (United States)

Carioscia, Jacquelyn A; Stansbury, Jeffrey W; Bowman, Christopher N

2007-03-08

The development of thiol-ene/thiol-epoxy hybrid networks offers the advantage of tailorable polymerization kinetics while producing a highly crosslinked, high T(g) polymer that has significantly reduced shrinkage stress. Stoichiometric mixtures of pentaerythritol tetra(3-mercaptopropionate) (PETMP)/triallyl-1,3,5-triazine-2,4,6-trione (TATATO) (thiol-ene, mixture 1) and PETMP/bisphenol a diglycidyl ether (BADGE) (thiol-epoxy, mixture 2) were prepared and hybrid mixtures of 75/25, 50/50, 25/75, and 10/90 w/w of mixtures 1 and 2 were polymerized using a combination of both radical and anionic initiation. The light exposure timing and the relative initiation conditions of the two types were used to control the order and relative rates of the radical and anionic polymerizations. The 50/50 w/w thiol-ene/thiol-epoxy hybrid material exhibited a final stress of only 0.2 MPa, which is 90 % lower than the stress developed in a control dimethacrylate resin. Kinetic analysis indicates composition affects network development in thiol-ene/thiol-epoxy hybrid networks and produces materials with robust mechanical properties.

Rahvusvaheliselt pärjatud õpivara eesti keeles ja kirjanduses / Helin Puksand, Reet Bobõlski, Margit Ross ; intervjueeris Krista Kerge

Index Scriptorium Estoniae

Puksand, Helin, 1970-

2015-01-01

Eesti õpivarale antud rahvusvahelised auhinnad: Best European Learning Material Silver Award 2014 Helin Puksandi, Reet Bobõlski ja Margit Rossi eesti keele õpikule "Punkt" (2013) ja Best European Schoolbook Silver Award 2012 samade autorite eesti keele õpikule "Peegel 3" (2011). Best European Schoolbook Bronze Award 2006 Jaanus Vaiksoo, Sirje Toomla ja Kadri Liivese aabitsale "Ilus emakeel" (2005).

Fabrication and bonding of thiol-ene-based microfluidic devices

International Nuclear Information System (INIS)

Sikanen, Tiina M; Moilanen, Maria-Elisa; Lafleur, Josiane P; Zhuang, Guisheng; Jensen, Thomas G; Kutter, Jörg P

2013-01-01

In this work, the bonding strength of microchips fabricated by thiol-ene free-radical polymerization was characterized in detail by varying the monomeric thiol/allyl composition from the stoichiometric ratio (1:1) up to 100% excess of thiol (2:1) or allyl (1:2) functional groups. Four different thiol-ene to thiol-ene bonding combinations were tested by bonding: (i) two stoichiometric layers, (ii) two layers bearing complementary excess of thiols and allyls, (iii) two layers both bearing excess of thiols, or (iv) two layers both bearing excess of allyls. The results showed that the stiffness of the cross-linked polymer plays the most crucial role regarding the bonding strength. The most rigid polymer layers were obtained by using the stoichiometric composition or an excess of allyls, and thus, the bonding combinations (i) and (iv) withstood the highest pressures (up to the cut-off value of 6 bar). On the other hand, excess of thiol monomers yielded more elastic polymer layers and thus decreased the pressure tolerance for bonding combinations (ii) and (iii). By using monomers with more thiol groups (e.g. tetrathiol versus trithiol), a higher cross-linking ratio, and thus, greater stiffness was obtained. Surface characterization by infrared spectroscopy confirmed that the changes in the monomeric thiol/allyl composition were also reflected in the surface chemistry. The flexibility of being able to bond different types of thiol-enes together allows for tuning of the surface chemistry to yield the desired properties for each application. Here, a capillary electrophoresis separation is performed to demonstrate the attractive properties of stoichiometric thiol-ene microchips. (technical note)

Vabaduse väljak = The first design stage of Freedom Square / Margit Mutso

Index Scriptorium Estoniae

Mutso, Margit, 1966-

2010-01-01

Tallinna Vabaduse väljakust, mis pälvis Eesti Kultuurkapitali 2009. aasta aastapreemia uue kvaliteedi eest Eesti linnaehituses ja avaliku ruumi loomisel. Arhitektid: Andres Alver, Veljo Kaasik, Tiit Trummal, kaasautorid Indrek Rünkla, Tarmo Laht, Sven Koppel, Ulla Saar, Toomas Tammis (Alver Arhitektid OÜ). Ajaloolane Rein Zobel. Žürii liikmete Kalle Komissarovi ja Mait Summataveti hinnang väljakule

Piimandus: laenukarid, ikaldused ja hinnaralli tõid kriisi / Ain Alvela ; kommenteerinud Tiit Tuuleveski, Urmas Põlluaas ja Tõnu Post

Index Scriptorium Estoniae

Alvela, Ain, 1967-

2009-01-01

Kuigi piimatootmisega tegelevad ettevõtted vajaksid tegevuse arendamiseks hädasti investeeringuid, jäävad enamiku rahastamisplaanid paremaid aegu ootama. Diagramm. Kommenteerivad Tiit Tuuleveski, Urmas Põlluaas ja Tõnu Post

Investigations of thiol-modified phenol derivatives for the use in thiol-ene photopolymerizations.

Science.gov (United States)

Reinelt, Sebastian; Tabatabai, Monir; Fischer, Urs Karl; Moszner, Norbert; Utterodt, Andreas; Ritter, Helmut

2014-01-01

Thiol-ene photopolymerizations gain a growing interest in academic research. Coatings and dental restoratives are interesting applications for thiol-ene photopolymerizations due to their unique features. In most studies the relative flexible and hydrophilic ester derivative, namely pentaerythritoltetra(3-mercaptopropionate) (PETMP), is investigated as the thiol component. Thus, in the present study we are encouraged to investigate the performance of more hydrophobic ester-free thiol-modified bis- and trisphenol derivatives in thiol-ene photopolymerizations. For this, six different thiol-modified bis- and trisphenol derivatives exhibiting four to six thiol groups are synthesized via the radical addition of thioacetic acid to suitable allyl-modified precursors and subsequent hydrolysis. Compared to PETMP better flexural strength and modulus of elasticity are achievable in thiol-ene photopolymerizations employing 1,3,5-triallyl-1,3,5-triazine-2,4,6-trione (TATATO) as the ene derivative. Especially, after storage in water, the flexural strength and modulus of elasticity is twice as high compared to the PETMP reference system.

Investigations of thiol-modified phenol derivatives for the use in thiol–ene photopolymerizations

Science.gov (United States)

Reinelt, Sebastian; Tabatabai, Monir; Fischer, Urs Karl; Moszner, Norbert; Utterodt, Andreas

2014-01-01

Summary Thiol–ene photopolymerizations gain a growing interest in academic research. Coatings and dental restoratives are interesting applications for thiol–ene photopolymerizations due to their unique features. In most studies the relative flexible and hydrophilic ester derivative, namely pentaerythritoltetra(3-mercaptopropionate) (PETMP), is investigated as the thiol component. Thus, in the present study we are encouraged to investigate the performance of more hydrophobic ester-free thiol-modified bis- and trisphenol derivatives in thiol–ene photopolymerizations. For this, six different thiol-modified bis- and trisphenol derivatives exhibiting four to six thiol groups are synthesized via the radical addition of thioacetic acid to suitable allyl-modified precursors and subsequent hydrolysis. Compared to PETMP better flexural strength and modulus of elasticity are achievable in thiol–ene photopolymerizations employing 1,3,5-triallyl-1,3,5-triazine-2,4,6-trione (TATATO) as the ene derivative. Especially, after storage in water, the flexural strength and modulus of elasticity is twice as high compared to the PETMP reference system. PMID:25161731

Investigations of thiol-modified phenol derivatives for the use in thiol–ene photopolymerizations

Directory of Open Access Journals (Sweden)

Sebastian Reinelt

2014-07-01

Full Text Available Thiol–ene photopolymerizations gain a growing interest in academic research. Coatings and dental restoratives are interesting applications for thiol–ene photopolymerizations due to their unique features. In most studies the relative flexible and hydrophilic ester derivative, namely pentaerythritoltetra(3-mercaptopropionate (PETMP, is investigated as the thiol component. Thus, in the present study we are encouraged to investigate the performance of more hydrophobic ester-free thiol-modified bis- and trisphenol derivatives in thiol–ene photopolymerizations. For this, six different thiol-modified bis- and trisphenol derivatives exhibiting four to six thiol groups are synthesized via the radical addition of thioacetic acid to suitable allyl-modified precursors and subsequent hydrolysis. Compared to PETMP better flexural strength and modulus of elasticity are achievable in thiol–ene photopolymerizations employing 1,3,5-triallyl-1,3,5-triazine-2,4,6-trione (TATATO as the ene derivative. Especially, after storage in water, the flexural strength and modulus of elasticity is twice as high compared to the PETMP reference system.

Vägivald ja propaganda

Index Scriptorium Estoniae

2006-01-01

8. IV-28. V Tallinna Kunstihoones Elin Kardi, Marco Laimre, Marko Mäetamme ja Andres Tali näitus "Vägivald ja propaganda". 26. IV-7. V näituse raames emergency biennale, rahvusvaheline rändnäitus Tšetšeenia toetuseks. 27. IV Kaasaegse Kunsti Eesti Keskuse IV ettekannete päev "Kunstniku moraalsed valikud liberaalse demokraatia ja islami kokkupõrgetes". Esinevad Margit Sutrop, Johannes Saar, Marek Järvik, Ene-Liis Semper & Eero Epner ning näitusel "Vägivald ja propaganda" osalevad kunstnikud

Eesti Maanteemuuseumi välialad = Estonian Road Museum, outdoor areas / Ralf Lõoke, Karli Luik, Maarja Kask ; intervjueerinud Margit Mutso

Index Scriptorium Estoniae

Lõoke, Ralf, 1978-

2011-01-01

Arhitektid: Maarja Kask, Karli Luik, Ralf Lõoke, Pelle-Sten Viiburg (Salto AB). Näituse kujundajad: Malle Jürgenson, Tea Tammelaan, Krista Lepland (Laika, Belka & Strelka). Maarja Kask, Karli Luik ja Ralf Lõoke pälvisid Eesti Kultuurkapitali aastapreemia (2010) kõrgetasemelise panuse eest Eesti maa-arhitektuuri: Eesti Maanteemuuseumi välialad (kaasautor Pelle-Sten Viiburg), Sõmeru keskushoone (kaasautorid Kristiina Arusoo ja Margit Argus)

Uudised : Veljo Tormise aasta on alanud. Eesti laul Tiit Kuusiku mälestuseks. Claude Delangle Eestis / Arne Mikk

Index Scriptorium Estoniae

Mikk, Arne, 1934-

2000-01-01

V. Tormise juubeliaasta üritustest. 19. ja 20. veebr. toimuvast neljandast eesti autorite vokaalmuusika esitamise võistlusest Tiit Kuusiku mälestuseks. 15. veebr. Estonia kammerlaval toimunud kontserdist ئ esinesid C. ja O. Delangle

Evaluation and Control of Thiol-ene/Thiol-epoxy Hybrid Networks

OpenAIRE

Carioscia, Jacquelyn A.; Stansbury, Jeffrey W.; Bowman, Christopher N.

2007-01-01

The development of thiol-ene/thiol-epoxy hybrid networks offers the advantage of tailorable polymerization kinetics while producing a highly crosslinked, high Tg polymer that has significantly reduced shrinkage stress. Stoichiometric mixtures of pentaerythritol tetra(3-mercaptopropionate) (PETMP)/triallyl-1,3,5-triazine-2,4,6-trione (TATATO) (thiol-ene, mixture 1) and PETMP/bisphenol a diglycidyl ether (BADGE) (thiol-epoxy, mixture 2) were prepared and hybrid mixtures of 75/25, 50/50, 25/75, ...

Rapid and simple preparation of thiol-ene emulsion-templated monoliths and their application as enzymatic microreactors

DEFF Research Database (Denmark)

Lafleur, Josiane P; Senkbeil, Silja; Novotny, Jakub

2015-01-01

A novel, rapid and simple method for the preparation of emulsion-templated monoliths in microfluidic channels based on thiol-ene chemistry is presented. The method allows monolith synthesis and anchoring inside thiol-ene microchannels in a single photoinitiated step. Characterization by scanning...... electron microscopy showed that the methanol-based emulsion templating process resulted in a network of highly interconnected and regular thiol-ene beads anchored solidly inside thiol-ene microchannels. Surface area measurements indicate that the monoliths are macroporous, with no or little micro...

Teoretiska perspektiv på kön, klass och gränsöverskridanden i akademin. Margit Abenius som forskare och litteraturkritiker

Directory of Open Access Journals (Sweden)

Marta Ronne

2006-01-01

Full Text Available THEORETICAL APPROACHES TO GENDER AND IDENTITY IN STUDIES OF THE INTELLECTUAL.MARGIT ABENIUS AND THE MAKING OF A FEMALE CRITIC. The aim of this article is todiscuss some of the most important feminist approaches to Pierre Bourdieu’ssociology of culture and the way in which they make possible new interpre-tations of gender and identity. Feminist readings of Bourdieu, from Toril Moi1991 to very recent contributions, have developed a new concept of gender asa part of the general social field and of a ”gender habitus”. These theoretical,non-essentialist standpoints can be combined both with intersectional analy-sis and with quite recent feminist concepts of ”women” as ”social class”(Lovell and ”women” as ”seriality” (Young. Here I use my own study ofthe Swedish literary critic Margit Abenius (1899–1970 to exemplify howthese different theoretical approaches can be brought together. A possibilityof combining feminist readings of Bourdieu with Zygmunt Bauman’s theoryof identity is also discussed in relation to contemporary debate on the con-cepts of subjectivity and identity.

Ene-Liis Semper : hindan päeva, kui teen ühte asja / Ene-Liis Semper ; interv. Jaanus Kulli

Index Scriptorium Estoniae

Semper, Ene-Liis, 1969-

2008-01-01

Teatri- ja videokunstnik Ene-Liis Semper oma elust ja tööst. Lisaks repliik "Parim päev on tööst prii päev" ja peagi Teater NO99s esietenduvast William Shakespeare'i lavastusest "Muinasjutuline "Perikles"

Teel taevatundmise poole / Pille-Riin Purje

Index Scriptorium Estoniae

Purje, Pille-Riin, 1963-

2009-01-01

Neljast rollist teatriaastast 2008: Rein Oja - akadeemik Gustav Naan (Erki Aule - Enn Vetemaa - Merle Karusoo "Sigma Tau-C705", Eesti Draamateater), Priit Võigemast - Rannap (Tiit Ojasoo - Ene-Liis Semper "Ruja", Vanemuine), Ülle Kaljuste - Salme (Andrus Kivirähk "Üks udune päev" (kuuldemäng), režissöör Astrid Relve. Raadioteater), Piret Laurimaa - Eleonore ja Esme (vanem) Tom Stoppard "Rock'n'roll", lavastaja Heiti Pakk, Endla)

On the reaction of the nitroso group with olefins. Mechanisms of ene reactions

International Nuclear Information System (INIS)

Seymour, C.A.; Greene, F.D.

1982-01-01

Intra- and intermolecular isotope effects point to a two-step process for the reaction of pentafluoronitrosobenzene with tetramethylethylene to afford the ene product, rate-determining formation of an intermediate (for which the arizidine N-oxide is suggested) followed by C-H (or C-D) cleavage to the ene product

Antibiofouling hybrid dendritic Boltorn/star PEG thiol-ene cross-linked networks.

Science.gov (United States)

Bartels, Jeremy W; Imbesi, Philip M; Finlay, John A; Fidge, Christopher; Ma, Jun; Seppala, Jonathan E; Nystrom, Andreas M; Mackay, Michael E; Callow, James A; Callow, Maureen E; Wooley, Karen L

2011-06-01

A series of thiol-ene generated amphiphilic cross-linked networks was prepared by reaction of alkene-modified Boltorn polyesters (Boltorn-ene) with varying weight percent of 4-armed poly(ethylene glycol) (PEG) tetrathiol (0-25 wt%) and varying equivalents of pentaerythritol tetrakis(3-mercaptopropionate) (PETMP) (0-64 wt%). These materials were designed to present complex surface topographies and morphologies, with heterogeneity of surface composition and properties and robust mechanical properties, to serve as nontoxic antibiofouling coatings that are amenable to large-scale production for application in the marine environment. Therefore, a two-dimensional matrix of materials compositions was prepared to study the physical and mechanical properties, over which the compositions spanned from 0 to 25 wt% PEG tetrathiol and 0-64 wt% PETMP (the overall thiol/alkene (SH/ene) ratios ranged from 0.00 to 1.00 equiv), with both cross-linker weight percentages calculated with respect to the weight of Boltorn-ene. The Boltorn-ene components were prepared through the esterification of commercially available Boltorn H30 with 3-butenoic acid. The subsequent cross-linking of the Boltorn-PEG-PETMP films was monitored using IR spectroscopy, where it was found that near-complete consumption of both thiol and alkene groups occurred when the stoichiometry was ca. 48 wt% PETMP (0.75 equiv SH/ene, independent of PEG amount). The thermal properties of the films showed an increase in T(g) with an increase in 4-armed PEG-tetrathiol wt%, regardless of the PETMP concentration. Investigation of the bulk mechanical properties in dry and wet states found that the Young's modulus was the greatest at 48 wt% PETMP (0.75 equiv of SH/ene). The ultimate tensile strength increased when PETMP was constant and the PEG concentration was increased. The Young's modulus was slightly lower for wet films at constant PEG or constant PETMP amounts, than for the dry samples. The nanoscopic surface features were

A Study of Functional Polymer Colloids Prepared Using Thiol-Ene/Yne Click Chemistry

Science.gov (United States)

Durham, Olivia Z.

This project demonstrates the first instance of thiol-ene chemistry as the polymerization method for the production of polymer colloids in two-phase heterogeneous suspensions, miniemulsions, and emulsions. This work was also expanded to thiol-yne chemistry for the production of polymer particles containing increased crosslinking density. The utility of thiol-ene and thiol-yne chemistries for polymerization and polymer modification is well established in bulk systems. These reactions are considered 'click' reactions, which can be defined as processes that are both facile and simple, offering high yields with nearly 100% conversion, no side products, easy product separation, compatibility with a diverse variety of commercially available starting materials, and orthogonality with other chemistries. In addition, thiol-ene and thiol-yne chemistry follow a step-growth mechanism for the development of highly uniform polymer networks, where polymer growth is dependent on the coupling of functional groups. These step-growth polymerization systems are in stark contrast to the chain-growth mechanisms of acrylic and styrenic monomers that have dominated the field of conventional heterogeneous polymerizations. Preliminary studies evaluated the mechanism of particle production in suspension and miniemulsion systems. Monomer droplets were compared to the final polymer particles to confirm that particle growth occurred through the polymerization of monomer droplets. Additional parameters examined include homogenization energy (mechanical mixing), diluent species and concentration, and monomer content. These reactions were conducted using photoinitiation to yield particles in a matter of minutes with diameters in the size range of several microns to hundreds of microns in suspensions or submicron particles in miniemulsions. Improved control over the particle size and size distribution was examined through variation of reaction parameters. In addition, a method of seeded suspension

Surface modification of cyclomatrix polyphosphazene microsphere by thiol-ene chemistry and lectin recognition

International Nuclear Information System (INIS)

Chen, Chen; Zhu, Xue-yan; Gao, Qiao-ling; Fang, Fei; Huang, Xiao-jun

2016-01-01

Graphical abstract: A new synthetic route leading to polyphosphazene cyclomatrix microsphere with various functional groups has achieved via thiol-ene click modification. Herein, hexacholorocyclophosphazene (HCCP) crosslinked with bisphenol-S and 4,4′-diallyl bisphenol-S to generate broadly dispersed microspheres. Thiol-ene modification under UV irradiation not only presented high efficiency and flexibility for post-functionalization, but also imposed no harm on global morphology and crosslinked skeleton of such microspheres. - Highlights: • Functional polyphosphazene microspheres with high chemical flexibility were synthesized by thiol-ene modification. • Polyphosphazene microspheres possessed high thermal stability. • Glycosylated polyphosphazene microspheres showed affinity to lectin Con-A, which inferred potential application in biomedicine. - Abstract: A new synthetic route leading to functional polyphosphazene cyclomatrix microsphere has been developed via thiol-ene click modification. Hexacholorocyclophosphazene (HCCP) was crosslinked with both bisphenol-S and 4,4′-diallyl bisphenol-S to obtain vinyl polyphosphazene microspheres (VPZM) in order to ensure high crosslinking degree and introduce vinyl moieties. Compared to the microspheres obtained by HCCP and bisphenol-S, the size of VPZM was broadly dispersed from 400 nm to 1.40 μm. Thiol-ene click reactions were carried out to attach functional groups, such as glucosyl, carboxyl, ester and dodecyl groups onto polyphosphazene microspheres, which demonstrated no change in morphology and size after modification. Solid state NMR (SSNMR) and Fourier transform infrared spectoscopy (FT-IR) results showed that the vinyl moieties were introduced in the period of crosslinking and functionalization was also successful via click reactions. Moreover, the microspheres presented a little difference in thermal properties after modification. Concanavalin A (Con-A) fluorescent adsorption was also observed for

Surface modification of cyclomatrix polyphosphazene microsphere by thiol-ene chemistry and lectin recognition

Energy Technology Data Exchange (ETDEWEB)

Chen, Chen; Zhu, Xue-yan; Gao, Qiao-ling; Fang, Fei; Huang, Xiao-jun, E-mail: hxjzxh@zju.edu.cn

2016-11-30

Graphical abstract: A new synthetic route leading to polyphosphazene cyclomatrix microsphere with various functional groups has achieved via thiol-ene click modification. Herein, hexacholorocyclophosphazene (HCCP) crosslinked with bisphenol-S and 4,4′-diallyl bisphenol-S to generate broadly dispersed microspheres. Thiol-ene modification under UV irradiation not only presented high efficiency and flexibility for post-functionalization, but also imposed no harm on global morphology and crosslinked skeleton of such microspheres. - Highlights: • Functional polyphosphazene microspheres with high chemical flexibility were synthesized by thiol-ene modification. • Polyphosphazene microspheres possessed high thermal stability. • Glycosylated polyphosphazene microspheres showed affinity to lectin Con-A, which inferred potential application in biomedicine. - Abstract: A new synthetic route leading to functional polyphosphazene cyclomatrix microsphere has been developed via thiol-ene click modification. Hexacholorocyclophosphazene (HCCP) was crosslinked with both bisphenol-S and 4,4′-diallyl bisphenol-S to obtain vinyl polyphosphazene microspheres (VPZM) in order to ensure high crosslinking degree and introduce vinyl moieties. Compared to the microspheres obtained by HCCP and bisphenol-S, the size of VPZM was broadly dispersed from 400 nm to 1.40 μm. Thiol-ene click reactions were carried out to attach functional groups, such as glucosyl, carboxyl, ester and dodecyl groups onto polyphosphazene microspheres, which demonstrated no change in morphology and size after modification. Solid state NMR (SSNMR) and Fourier transform infrared spectoscopy (FT-IR) results showed that the vinyl moieties were introduced in the period of crosslinking and functionalization was also successful via click reactions. Moreover, the microspheres presented a little difference in thermal properties after modification. Concanavalin A (Con-A) fluorescent adsorption was also observed for

Episodic nature of the delta 4-ene and delta 5-ene steroidogenic pathways and their relationship to the adreno-gonadal axis in stallions.

Science.gov (United States)

Ganjam, V K

1979-01-01

Changes in the daily secretory patterns of testosterone and other 17 beta-hydroxyandrogen, total oestrogens and total corticoids were investigated in 7 stallions. Pulsatile fluctuations in plasma hormone levels were found in the serial blood samples collected hourly for 24 h in all animals. The plasma profiles indicated that corticoids, oestrogens and androgens were secreted episodically at all times in stallions. A significant correlation was observed between the precursor and products of delta 4-ene and delta 5-ene pathways and in inverse correlation (r = -0.68; P less than 0.01) was observed between total androgens and total corticoids. The significance of these episodic fluctuations of the major steroid hormones are discussed.

Kandidaadid : Ene Ergma versus Toomas Hendrik Ilves

Index Scriptorium Estoniae

2006-01-01

Artiklis vastatakse küsimustele, kes oleksid Kadriorus Ene Ergma ja Toomas Hendrik Ilvese nõunikud, millist sõnumit kannaks nende esimene iseseisvuspäeva kõne, kuidas nad tähistaksid oma võitu presidendivalimistel, kellele nad annaksid Maarjamaa Risti, kuhu nad teeksid oma esimese välisvisiidi

Tandem Wittig-ene reaction approach to kainic acid

Digital Repository Service at National Institute of Oceanography (India)

Majik, M.S.; Parameswaran, P.S.; Tilve, S.G.

The first example of a tandem Wittig-intramolecular ene reaction approach and its application toward the synthesis of kainic acid is reported. The synthetic pathway involves conversion of prenyl bromide into phosphorane 3, followed by one-pot Wittig...

Functionalization of embedded thiol-ene waveguides for evanescent wave induced fluorescence detection in a microfluidic device

DEFF Research Database (Denmark)

Feidenhans'l, Nikolaj Agentoft; Jensen, Thomas Glasdam; Lafleur, Josiane P.

2013-01-01

We demonstrate the use of functional surface groups inherently present on off-stoichiometric thiol−ene polymers, for site-specific immobilization of biomolecules and detection by evanescent wave-induced fluorescence. An optofluidic chip featuring an embedded thiol−ene waveguide was selectively...... functionalized with biotin using photografting. The biotin was used for immobilization of fluorescently labelled streptavidin, and experiments revealed a linear correlation between streptavidin concentration and fluorescent intensity. To further demonstrate the attractiveness of using thiol−ene for optofluidic...

Investigations of thiol-modified phenol derivatives for the use in thiol–ene photopolymerizations

OpenAIRE

Sebastian Reinelt; Monir Tabatabai; Urs Karl Fischer; Norbert Moszner; Andreas Utterodt; Helmut Ritter

2014-01-01

Summary Thiol–ene photopolymerizations gain a growing interest in academic research. Coatings and dental restoratives are interesting applications for thiol–ene photopolymerizations due to their unique features. In most studies the relative flexible and hydrophilic ester derivative, namely pentaerythritoltetra(3-mercaptopropionate) (PETMP), is investigated as the thiol component. Thus, in the present study we are encouraged to investigate the performance of more hydrophobic ester-free thiol-m...

Europan 7 Eestis : Lasnamäe. Pärnu / Tiit Trummal, Andres Kurg

Index Scriptorium Estoniae

Trummal, Tiit, 1954-

2004-01-01

Võistluse "Äärelinna võimalus, linnalik intensiivsus ja elamise mitmekesisus" Eesti-Rootsi ühisžüriis Eestist Urmas Muru, Tiit Trummal, Andres Kurg. Tallinna Lasnamäe (14 tööd) ja Pärnu (47 tööd) võistlusalast, võitnud tööde arhitektide loetelu ja võitnud töödest. Lasnamäe: I preemia - autor hispaanlane Andres Fernandes Atela, kaasautorid prantslased Mathieu Andrieu ja Iman Morshedi. Pärnu: I preemia - autorid rumeenlane Oana-Maria Bogdan, ameeriklane Susan Kelly Shannon, argentiinlane Laura Vescina, hispaanlased Juny Llach ja Parra Colacios

An academic with ambition / Ene Ergma ; interv. Kadri Kukk

Index Scriptorium Estoniae

Ergma, Ene, 1944-

2006-01-01

Intervjuus Riigikogu asespiikriga käsitletakse kõrghariduse korraldust, professorite rohkust kõrgkoolides, võimalikku kandideerimist Tartu ülikooli rektori kohale, omandatud poliitilisi kogemusi ning ajude äravoolu Eestist. Ene Ergma CV

Poska 28 elamust : kortermaja Tallinnas Kadriorus = About the Multi-Family Dwelling at Poska 28 : Apartment House in KadriorgTallinn / Tiit Trummal

Index Scriptorium Estoniae

Trummal, Tiit, 1954-

2002-01-01

Projekteerija: Alver Trummal Arhitektid. Autorid Tiit Trummal, Tarmo Laht, Ulla Mets. Konstruktsioonid: Aivar Lukk, Indrek Einloo. Üheksa korteriga elamul on avarad terrassid, rõdudele avanevad vannitoad jm. Projekt 2001, valmis 2002. 7 ill.: vaated, tüüpkorruse plaan

Rändeandmete kvaliteet ja rändesuundumused Eestis aastatel 2000-2005 = The quality of migration data and the trends of migration in Estonia in 2000-2005 / Alis Tammur, Tiit Tammaru, Ene- Margit Tiit

Index Scriptorium Estoniae

Tammur, Alis

2006-01-01

Eesti statistilise rahvastikuarvestuse alus on olnud viimase rahvaloenduse rahvaarv, millele lisatakse omavalitsusüksuste kaupa registripõhiselt kogutavad sünnid, surmad ning sisse- ja väljaränne. Rahvaloenduse ja rahvastikuregistri andmete põhimõtteline erinevus. Sise- ja välisrände arvestamise probleemid, rändesuundumuste analüüs. Diagramm. Tabelid

Vähem formaalsust, rohkem julgust ja enesekriitikat! / Marko Mäetamm, Anneli Porri, Tiit Pääsuke ... [jt.] ; intervjueerinud Reet Varblane

Index Scriptorium Estoniae

2009-01-01

Kunstiõpetamise võimalikkuse ja vajalikkuse üle vestlesid Eesti Kunstiakadeemia vabade kunstide teaduskonna dekaan Marko Mäetamm, fotokunsti osakonna õppejõud Anneli Porri, emeriitprofessor Tiit Pääsuke, prorektor Liina Siib, graafilise disaini osakonna õppejõud Indrek Sirkel ja ehtekunsti osakonna õppejõud Tanel Veenre

Sa uurisid ekspressionismi 1960ndatel ja 70ndatel... / Ene Lamp

Index Scriptorium Estoniae

Lamp, Ene

2005-01-01

2004. a. ilmunud raamatu "Ekspressionism" eest Eesti Kultuurkapitali suure kunstipreemia (100000 kr.) saanud Ene Lamp ekspressionismi tähenduse muutumiset, ekspressionismi rollist eesti kunstis, oma tulevikuplaanidest

Ene-Liiz Semper. Anton Litvin. Bogdan Mamonov

Index Scriptorium Estoniae

2005-01-01

Veebruaris Madridis toimunud Euroopa kunstilaada ARCO jaoks Vene saatkonna galerii poolt koostatud kunstinäitus TRINITY toimub nüüd Tallinnas Vene saatkonna galeriis. Kuraatorid Masha ja Andrei Melnikovid. Osalevad Ene-Liis Semper videoga ArtVideo, vene kunstnik Bogdan Mamonov maaliseeriaga "Ma kanoniseerisin oma sõpru" ja vene kunstnik Anton Litvin fotoprojektiga "Punktuatsioon". Madridis näitas Semper videot "Nimetu"

Proof of a conjecture of Colliot-Th\\'el\\`ene

OpenAIRE

Denef, Jan

2011-01-01

We prove a conjecture of Colliot-Th\\'el\\`ene that implies the Ax-Kochen Theorem on p-adic forms. We obtain it as an easy consequence of a diophantine excision theorem whose proof forms the body of the present paper.

preparation of bicyclic lactones using lewis acids catalyzed ene

African Journals Online (AJOL)

Administrator

The synthesis of the cis-fused bicyclic lactones relies extensively on the Lewis acid ... having an allylic hydrogen (an"ene") and a compound containing an electron .... observed that the lithium enolate obtained from 3-methyl-2(5H)- furanone ...

Preparation and Characterization of Fluorinated Hydrophobic UV-Crosslinkable Thiol-Ene Polyurethane Coatings

Directory of Open Access Journals (Sweden)

Wenjing Xia

2017-08-01

Full Text Available The polyurethane prepolymer terminated with a double bond was synthesized using isophorone diisocyanate (IPDI, hydroxyl terminated polybutadiene (HTPB, 1,4-butanediol (BDO, and 2-hydroxyethyl acrylate (HEA. Then, a series of innovative UV-curable polyurethane coatings were prepared by blending ene-terminated polyurethane, fluoroacrylate monomer, and multifunctional thiol crosslinker upon UV exposure. The incorporation of fluoroacrylate monomer and multifunctional thiols into polyurethane coatings significantly enhanced the hydrophobic property, mechanical property, pencil hardness, and glossiness of the polyurethane coatings. This method of preparing UV crosslinkable, hydrophobic polyurethane coatings based on thiol-ene chemistry exhibited numerous advantages over other UV photocuring systems.

ENE-Mates - A public information program for women

International Nuclear Information System (INIS)

Nagashima, Kyoko

1995-01-01

Japan depends on import for more than 80 percent of its total energy supply. Nuclear energy is one of the most promising alternatives to oil. It plays a significant role for energy supply in terms of reliability, economic viability and reduction of CO 2 emissions. In order to secure needed capacity, the Government concentrates its efforts on acquiring public acceptance of nuclear power as well as ensuring the safety of plants and improving plant capability and reliability. An opinion poll, done by the Japanese Government in Sep. of 1990, showed that 73.3 percent of man and 57.4 percent of women think that nuclear power is necessary to secure energy supply. Nuclear Power Engineering Corporation (NUPEC) employs various methods for information services arid, in particular, electric power generation including nuclear with an assignment from the Japanese Government. Public information activities by the Nuclear Power Engineering Corporation (NUPEC) are as follows: a) Telephone QA service to respond to public inquiries; b) Publishing the 'Nuclear Newsletter' monthly and various brochures; c) Information service by personal computer network Atomnet concerning energy in general, and operation/trouble informations of nuclear plants; d) Distribution and service of personal computers to local governments offices/museums, etc., for users ranging from children to adults to gather nuclear related information; e) Organization of female monitors 'ENE-MATES' to have lecture meetings and site tours. ENE-MATES - A Public Information Program For Women. As a 1990 opinion poll shows, women's feelings about nuclear energy differ from that of men. Women are more sensitive and anxious than men on nuclear energy issues. To improve this situation several programs for women have been planned and implemented.'ENE-MATES' program is one of these cases. It's purpose is to encourage women, centering around house wives, to have unbiased understanding of energy-related issues

Novel Thiol-Ene Hybrid Coating for Metal Protection

Directory of Open Access Journals (Sweden)

Mona Taghavikish

2016-04-01

Full Text Available A novel hybrid anticorrosion coating with dual network of inorganic (Si–O–Si and organic bonds (C–S–C was prepared on metal through an in situ sol-gel and thiol-ene click reaction. This novel interfacial thin film coating incorporates (3-mercaptopropyl trimethoxysilane (MPTS and 1,4-di(vinylimidazolium butane bisbromide based polymerizable ionic liquid (PIL to form a thiol-ene based photo-polymerized film, which on subsequent sol-gel reaction forms a thin hybrid interfacial layer on metal surface. On top of this PIL hybrid film, a self-assembled nanophase particle (SNAP coating was employed to prepare a multilayer thin film coating for better corrosion protection and barrier performance. The novel PIL hybrid film was characterised for structure and properties using Fourier transform infrared spectroscopy (FTIR, differential scanning calorimetry (DSC, and thermogravimetric analysis (TGA. The corrosion protection performance of the multilayer coating was examined using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS. The results reveal that this novel double layer coating on metal offers excellent protection against corrosion and has remarkably improved the barrier effect of the coating.

DFT Investigation of the Palladium-Catalyzed Ene-Yne Coupling

DEFF Research Database (Denmark)

Henriksen, Signe Teuber; Tanner, David Ackland; Skrydstrup, T.

2010-01-01

). Concerning chemoselectivity, the calculations also clarify why the ene-yne coupling is able to dominate over plausible alternative reaction pathways such as alkene homocoupiing and alkyne polymerization. The role of the phosphine ligand at various stages of the catalytic cycle has also been delineated....

Teoretiska perspektiv på kön, klass och gränsöverskridanden i akademin. Margit Abenius som forskare och litteraturkritiker

OpenAIRE

Marta Ronne

2006-01-01

THEORETICAL APPROACHES TO GENDER AND IDENTITY IN STUDIES OF THE INTELLECTUAL.MARGIT ABENIUS AND THE MAKING OF A FEMALE CRITIC. The aim of this article is todiscuss some of the most important feminist approaches to Pierre Bourdieu’ssociology of culture and the way in which they make possible new interpre-tations of gender and identity. Feminist readings of Bourdieu, from Toril Moi1991 to very recent contributions, have developed a new concept of gender asa part of the general social field and ...

Synthesis and characterization of thiol-ene functionalized siloxanes and evaluation of their polymerization kinetics, network properties, and dental applications

Science.gov (United States)

Cole, Megan A.

We explored formation-structure-property relationships in thiol-ene functionalized oligosiloxanes to create crosslinked networks. Specifically, nine oligomers were synthesized, three with thiol-functional silane repeats and three with allyl-functional silane repeats. Structural variations in each oligomer were systematically induced through the incorporation of non-reactive repeats bearing either diphenyl or di-n-octyl moieties, and the oligomer molecular weight was limited by the presence of monofunctional silane condensation species. The molecular weights and chain compositions of all oligomers were ascertained and subsequently used in the evaluation of network properties formed upon photopolymerization of thiol- and ene-functional reactants. Polymerization kinetics of the thiol-ene functionalized siloxanes were also investigated using photoinitiation owing to the spatial and temporal control afforded by this technique. In particular, the effects of the viscosity of the ene-functionalized oligomer and the degree of thiol functionalization on the observed polymerization rate were determined. Results showed that the speed of polymerization varied with changes to the rate-limiting step, which was heavily influenced by neighboring non-reactive functionalities. Moreover, the thiol-ene reaction was found to exhibity unimolecular termination exclusively in siloxane-based systems. Proposed use of the thiol-ene functionalized siloxane system as a dental impression material necessitated the development of a redox initiation scheme. Evaluation of the benzoylperoxide/dimethyl-p-toluidine redox pair in traditional systems showed bulk thiol-ene polymerizations comparable to photoinitiation with the added advantage of uninhibited depth control, as also demonstrated in small molecule thiol-ene coupling reactions initiated by this same redox system. Application of the redox pair to the siloxane system allowed for the viscoelastic properties as well as the feature replication

Preparation of Biomolecule Microstructures and Microarrays by Thiol–ene Photoimmobilization

NARCIS (Netherlands)

Weinrich, Dirk; Köhn, Maja; Jonkheijm, Pascal; Westerlind, Ulrika; Dehmelt, Leif; Engelkamp, Hans; Christianen, Peter C.M.; Kuhlmann, Jürgen; Maan, Jan C.; Nüsse, Dirk; Schröder, Hendrik; Wacker, Ron; Voges, Edgar; Breinbauer, Rolf; Kunz, Horst; Niemeyer, Christof M.; Waldmann, Herbert

2010-01-01

A mild, fast and flexible method for photoimmobilization of biomolecules based on the light-initiated thiol–ene reaction has been developed. After investigation and optimization of various surface materials, surface chemistries and reaction parameters, microstructures and microarrays of biotin,

Thiol-ene reaction as tool for crosslinking of polynorbornene micelles in the nanoscale

Science.gov (United States)

Rupp, Barbara; Bauer, Thomas; Slugovc, Christian

2009-08-01

The thiol-ene reaction is a established photoreaction of multifunctional thiols and enes. Virtually any type of ene will participate in a free radical polymerisation process with a thiol. An advantage over many other photochemical reactions is that the reaction proceeds almost as rapidly in ambient conditions as in inert atmosphere. In this work we introduce the UV-crosslinking of polynorbornenes made by ring opening metathesis polymerization making use of the residual double bond in the polymer backbone. The crosslinking experiments were done in thin films and were followed by FTIR measurements, to proof the accessibility of double-bonds in the polymers for the addition of the thiols. As a result of these pre-experiments we created flexible and light transmitting films. To further increase the scope of this reaction, amphiphilic block copolymers were prepared and used to form block copolymer micelles in a selective solvent, which were subsequently crosslinked with pentaerythritol tetra(3-mercaptopropionate) (PETMP). FT-IR, DLS and SEM-measurements were used to prove the successful crosslinking and thus nanoparticle formation.

Orented immobilization of farnesylated proteins by the thiol-ene reaction

NARCIS (Netherlands)

Weinrich, Dirk; Lin, Po-Chiao; Jonkheijm, Pascal; Nguyen, Uyen T.T.; Schröder, Hendrik; Niemeyer, Christof M.; Alexandrov, Kirill; Goody, Roger; Waldmann, Herbert

2010-01-01

Anchoring the protein: Proteins were immobilized rapidly under mild conditions by thiol-ene photocoupling between S-farnesyl groups attached to a genetically encodable “CAAX-box” tetrapeptide sequence (A is aliphatic) at the C terminus of the protein and surface-exposed thiols (see scheme). This

Simple preparation of thiol-ene particles in glycerol and surface functionalization by thiol-ene chemistry (TEC) and surface chain transfer free radical polymerization (SCT-FRP)

DEFF Research Database (Denmark)

Hoffmann, Christian; Chiaula, Valeria; Yu, Liyun

2018-01-01

functionalization of excess thiol groups via photochemical thiol-ene chemistry (TEC) resulting in a functional monolayer. In addition, surface chain transfer free radical polymerization (SCT-FRP) was used for the first time to introduce a thicker polymer layer on the particle surface. The application potential...

Spray-deposition and photopolymerization of organic-inorganic thiol-ene resins for fabrication of superamphiphobic surfaces.

Science.gov (United States)

Xiong, Li; Kendrick, Laken L; Heusser, Hannele; Webb, Jamie C; Sparks, Bradley J; Goetz, James T; Guo, Wei; Stafford, Christopher M; Blanton, Michael D; Nazarenko, Sergei; Patton, Derek L

2014-07-09

Superamphiphobic surfaces, exhibiting high contact angles and low contact angle hysteresis to both water and low surface tension liquids, have attracted a great deal attention in recent years because of the potential of these materials in practical applications such as liquid-resistant textiles, self-cleaning surfaces, and antifouling/anticorrosion coatings. In this work, we present a simple strategy for fabricating of superamphiphobic coatings based on photopolymerization of hybrid thiol-ene resins. Spray-deposition and UV photopolymerization of thiol-ene resins containing hydrophobic silica nanoparticles and perfluorinated thiols provide a multiscale topography and low-energy surface that endows the surface with superamphiphobicity. The wettability and chemical composition of the surfaces were characterized by contact-angle goniometry and X-ray photoelectron spectroscopy, respectively. The hierarchical roughness features of the thiol-ene surfaces were investigated with field-emission scanning electron microscopy. Droplet impact and sandpaper abrasion tests indicate the coatings respectively possess a robust antiwetting behavior and good mechanical durability.

Fabrication of Biomolecule Microarrays Using Rapid Photochemical Surface Patterning in Thiol-Ene-Based Microfluidic Devices.

Science.gov (United States)

Jönsson, Alexander; Lafleur, Josiane P

2018-01-01

In many biochip applications, it is advantageous to be able to immobilize biomolecules at specific locations on the surface of solid supports. In this protocol, we describe a photochemical surface patterning procedure based on thiol-ene/yne photochemistry which allows for the simple and rapid selective patterning of biomolecules on thiol-ene solid supports. We describe the preparation of solid supports which are required for the immobilization, including porous monoliths, as well as two different immobilization schemes based on biotin-streptavidin interactions and covalent linkage via free amino groups respectively.

Ene-yne Cross-Metathesis for the Preparation of 2,3-Diaryl-1,3-dienes

Directory of Open Access Journals (Sweden)

Meriem K. Abderrezak

2017-11-01

Full Text Available Ene-yne cross-metathesis from alkynes and ethylene is a useful method to produce substituted conjugated butadiene derivatives. If this method has been used with aliphatic alkynes, it has however never been used starting from diarylacetylenes as internal alkynes. We show that the ene-yne cross-metathesis catalyzed by the second generation Hoveyda ruthenium catalyst provides the 2,3-diarylbuta-1,3-dienes under 3 atm of ethylene at 100 °C. The scope and limitations of the reaction have been evaluated starting from unsymmetrical functionalized diarylacetylene derivatives hence leading to unsymmetrical 2,3-diarylbuta-1,3-dienes in a straightforward and environmentally acceptable manner.

Evaluation of fracture toughness and mechanical properties of ternary thiol-ene-methacrylate systems as resin matrix for dental restorative composites.

Science.gov (United States)

Beigi, Saeed; Yeganeh, Hamid; Atai, Mohammad

2013-07-01

Study and evaluation of fracture toughness, flexural and dynamic mechanical properties, and crosslink density of ternary thiol-ene-methacrylate systems and comparison with corresponding conventional methacrylate system were considered in the present study. Urethane tetra allyl ether monomer (UTAE) was synthesized as ene monomer. Different formulations were prepared based on combination of UTAE, BisGMA/TEGDMA and a tetrathiol monomer (PETMP). The photocuring reaction was conducted under visible light using BD/CQ combination as photoinitiator system. Mechanical properties were evaluated via measuring flexural strength, flexural modulus and fracture toughness. Scanning electron microscopy (SEM) was utilized to study the morphology of the fractured specimen's cross section. Viscoelastic properties of the samples were also determined by dynamic mechanical thermal analysis (DMTA). The same study was performed on a conventional methacrylate system. The data were analyzed and compared by ANOVA and Tukey HSD tests (significance level=0.05). The results showed improvement in fracture toughness of the specimens containing thiol-ene moieties. DMTA revealed a lower glass transition temperature and more homogenous structure for thiol-ene containing specimens in comparison to the system containing merely methacrylate monomer. The flexural modulus and flexural strength of the specimens with higher thiol-ene content were lower than the neat methacrylate system. The SEM micrographs of the fractured surface of specimens with higher methacrylate content were smooth and mirror-like (shiny) which represent brittle fracture. The thiol-ene-methacrylate system can be used as resin matrix of dental composites with enhanced fracture toughness in comparison to the methacrylate analogous. Copyright © 2013 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Chalcogenidobis(ene-1,2-dithiolate)molybdenum(IV) complexes (chalcogenide E = O, S, Se): probing Mo≡E and ene-1,2-dithiolate substituent effects on geometric and electronic structure.

Science.gov (United States)

Sugimoto, Hideki; Tano, Hiroyuki; Suyama, Koichiro; Kobayashi, Tomoya; Miyake, Hiroyuki; Itoh, Shinobu; Mtei, Regina P; Kirk, Martin L

2011-02-07

New square-pyramidal bis(ene-1,2-dithiolate)MoSe complexes, [Mo(IV)Se(L)(2)](2-), have been synthesised along with their terminal sulfido analogues, [Mo(IV)S(L)(2)](2-), using alkyl (L(C(4)H(8))), phenyl (L(Ph)) and methyl carboxylate (L(COOMe)) substituted dithiolene ligands (L). These complexes now complete three sets of Mo(IV)O, Mo(IV)S and Mo(IV)Se species that are coordinated with identical ene-1,2-dithiolate ligands. The [alkyl substituted Mo(S/Se)(L(C(4)H(8)))(2)](2-) complexes were reported in prior investigations (H. Sugimoto, T. Sakurai, H. Miyake, K. Tanaka and H. Tsukube, Inorg. Chem. 2005, 44, 6927, H. Tano, R. Tajima, H. Miyake, S. Itoh and H. Sugimoto, Inorg. Chem. 2008, 47, 7465). The new series of complexes enable a systematic investigation of terminal chalcogenido and supporting ene-1,2-dithiolate ligand effects on geometric structure, electronic structure, and spectroscopic properties. X-ray crystallographic analysis of these (Et(4)N)(2)[MoEL(2)] (E = terminal chalocogenide) complexes reveals an isostructural Mo centre that adopts a distorted square pyramidal geometry. The M≡E bond distances observed in the crystal structures and the ν(M≡E) vibrational frequencies indicate that these bonds are weakened with an increase in L→Mo electron donation (L(COOMe) < L(Ph) < L(C(4)H(8))), and this order is confirmed by an electrochemical study of the complexes. The (77)Se NMR resonances in MoSeL complexes appear at lower magnetic fields as the selenido ion became less basic from MoSeL(C(4)H(8)), MoSeL(Ph) and MoSeL(COOMe). Electronic absorption and resonance Raman spectroscopies have been used to assign key ligand-field, MLCT, LMCT and intraligand CT bands in complexes that possess the L(COOMe) ligand. The presence of low-energy intraligand CT transition in these MoEL(COOMe) compounds directly probes the electron withdrawing nature of the -COOMe substituents, and this underscores the complex electronic structure of square pyramidal bis(ene-1

NO99 Põhuteater = NO99 Straw Theatre / Ralf Lõoke, Maarja Kask ; intervjueerinud Margit Mutso

Index Scriptorium Estoniae

Lõoke, Ralf, 1978-

2012-01-01

Põhuteatri arhitektid Maarja Kask, Karli Luik, Ralf Lõoke, Pelle-Sten Viiburg (Salto Arhitektid) ja Ene-Liis Semper pälvisid EK arhitektuuri sihtkapitali 2011. a. arhitektuuripreemia vormitähendustes edasi liikunud ning arhitektuurile kui sündmusele ja kohaloomele keskendunud aktsiooni eest. Konstruktor Tõnu Peipmann

Rapid photochemical surface patterning of proteins in thiol-ene based microfluidic devices

DEFF Research Database (Denmark)

Lafleur, Josiane P.; Kwapiszewski, Radoslaw; Jensen, Thomas Glasdam

2013-01-01

! 17 SH nm"2. Biotin alkyne was patterned directly inside thiol–ene microchannels prior to conjugation with fluorescently labelled streptavidin. The surface bound conjugates were detected by evanescent waveinduced fluorescence (EWIF), demonstrating the success of the grafting procedure and its...

Investigations of step-growth thiol-ene polymerizations for novel dental restoratives.

Science.gov (United States)

Lu, Hui; Carioscia, Jacquelyn A; Stansbury, Jeffery W; Bowman, Christopher N

2005-12-01

The goal of this work was to investigate the feasibility of formulating novel dental restorative materials that utilize a step-growth thiol-ene photopolymerization. Particularly, we are aiming to significantly reduce the polymerization shrinkage and shrinkage stress while retaining adequate physical properties as compared to current dimethacrylatre-based systems. The thiol-ene system is composed of a 4:3 molar mixture of triallyl-1,3,5-triazine-2,4,6-trione (TATATO) and pentaerythritol tetramercaptopropionate (PETMP). The simultaneous measurement of shrinkage stress and functional group conversion was performed. Solvent extraction of unreacted monomers and dynamic mechanical analysis on the polymer networks that were formed were also studied. Flexural strength was measured for both filled and unfilled PETMP/TATATO and Bis-GMA/TEGDMA systems. Photopolymerization of PETMP/TATATO occurs at a much higher rate, with the maximum polymerization rate six times faster, than Bis-GMA/TEGDMA cured under the identical conditions. The results from the simultaneous measurement of shrinkage stress and conversion showed that the onset of shrinkage stress coincides with the delayed gel point conversion, which is predicted to be 41% for the 3:4 stoichiometric PETMP/TATATO resin composition. The maximum shrinkage stress developed for PETMP/TATATO was about 0.4 MPa, which was only approximately 14% of the maximum shrinkage stress of the Bis-GMA/TEGDMA system. Adequate flexural strength and flexural modulus values were obtained for both filled and unfilled PETMP/TATATO systems. The dramatically reduced shrinkage stress, increased polymerization rate, significance increased functional group conversion, and decreased leachable species are all benefits for the use-of thiol-ene systems as potential dental restorative materials.

Heat- and light-induced thiol-ene oligomerization of soybean oil-based polymercaptan

Science.gov (United States)

Polymercaptanized soybean oil (PMSO), the product of a thiol-ene reaction between soybean oil and hydrogen sulfide, is a material of interest as a lubricant additive and polymer precursor. We investigated with gel permeation chromatography, nuclear magnetic resonance (one-dimensional and two-dimensi...

Patterned Hydrophilization of Nanoporous 1,2‐PB by Thiol‐ene Photochemistry

DEFF Research Database (Denmark)

Berthold, Anton; Sagar, Kaushal Shashikant; Ndoni, Sokol

2011-01-01

is monitored by FT‐IR, UV–Vis, contact angle, and gravimetry. Overall quantum yields are calculated for the two thiol‐ene “click” reactions in nano‐confinement, neatly revealing their chain‐like nature. Top–down photolithographic patterning is demonstrated, realizing hydrophilic nanoporous “corridors...

Photocured thiol-ene based optical fluorescence sensor for determination of gold(III)

Energy Technology Data Exchange (ETDEWEB)

Çubuk, Soner, E-mail: sonercubuk@marmara.edu.tr; Kahraman, Memet Vezir; Yetimoğlu, Ece Kök; Kenan, Sibel

2014-02-17

Graphical abstract: -- Highlights: •Photopolymerized fluorescence sensor for Au(III) analysis has been developed. •Preparation of polymeric sensor is simple and quick. •Fluorescence sensor used for analysis of Au(III) in real samples. -- Abstract: This study describes the preparation and the characterization of a new thiol-ene based polymeric fluorescence sensor by photo initiated polymerization of trimethylolpropane tris(3-mercaptopropionate), 2-hydroxyethylacrylate, and 2,4,6-triallyloxy-1,3,5-triazine which are used as monomers and also a photo initiator (2,2-dimethoxy-2-phenylacetophenone) for its usage as optical sensor for gold ions. The thiol-ene based polymeric membrane sensor was characterized by using attenuated total reflectance-fourier transform infrared spectroscopy (ATR-FTIR) and scanning electron microscopy (SEM). The response characteristics of the sensors including dynamic range, pH effect, response time, and the effect of foreign ions were investigated. Fluorescence spectra showed that the excitation/emission maxima of the membrane were at 379/425 nm, respectively.

Photocured thiol-ene based optical fluorescence sensor for determination of gold(III)

International Nuclear Information System (INIS)

Çubuk, Soner; Kahraman, Memet Vezir; Yetimoğlu, Ece Kök; Kenan, Sibel

2014-01-01

Graphical abstract: -- Highlights: •Photopolymerized fluorescence sensor for Au(III) analysis has been developed. •Preparation of polymeric sensor is simple and quick. •Fluorescence sensor used for analysis of Au(III) in real samples. -- Abstract: This study describes the preparation and the characterization of a new thiol-ene based polymeric fluorescence sensor by photo initiated polymerization of trimethylolpropane tris(3-mercaptopropionate), 2-hydroxyethylacrylate, and 2,4,6-triallyloxy-1,3,5-triazine which are used as monomers and also a photo initiator (2,2-dimethoxy-2-phenylacetophenone) for its usage as optical sensor for gold ions. The thiol-ene based polymeric membrane sensor was characterized by using attenuated total reflectance-fourier transform infrared spectroscopy (ATR-FTIR) and scanning electron microscopy (SEM). The response characteristics of the sensors including dynamic range, pH effect, response time, and the effect of foreign ions were investigated. Fluorescence spectra showed that the excitation/emission maxima of the membrane were at 379/425 nm, respectively

Rapid photochemical surface patterning of proteins in thiol-ene based microfluidic devices

DEFF Research Database (Denmark)

Lafleur, Josiane P.; Kwapiszewski, Radoslaw; Jensen, Thomas Glasdam

2012-01-01

” and “ene” monomers present in the microfluidic chip bulk material provides a simple and efficient way of tuning the chip’s surface chemistry. Here, thiol-ene chips displaying an excess of functional thiol groups at their surfaces are functionalized with biotin and streptavidin in a controlled fashion using...

Superhydrophobic hybrid inorganic-organic thiol-ene surfaces fabricated via spray-deposition and photopolymerization.

Science.gov (United States)

Sparks, Bradley J; Hoff, Ethan F T; Xiong, Li; Goetz, James T; Patton, Derek L

2013-03-13

We report a simple and versatile method for the fabrication of superhydrophobic inorganic-organic thiol-ene coatings via sequential spray-deposition and photopolymerization under ambient conditions. The coatings are obtained by spray-deposition of UV-curable hybrid inorganic-organic thiol-ene resins consisting of pentaerythritol tetra(3-mercaptopropionate) (PETMP), triallyl isocyanurate (TTT), 2,4,6,8-tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane (TMTVSi), and hydrophobic fumed silica nanoparticles. The spray-deposition process and nanoparticle agglomeration/dispersion provide surfaces with hierarchical morphologies exhibiting both micro- and nanoscale roughness. The wetting behavior, dependent on the concentration of TMTVSi and hydrophobic silica nanoparticles, can be varied over a broad range to ultimately provide coatings with high static water contact angles (>150°), low contact angle hysteresis, and low roll off angles (spray-deposition and UV-cure process on a variety of substrate surfaces including glass, paper, stone, and cotton fabric.

Preliminary Engineering Report contaminated groundwater seeps 317/319/ENE area

International Nuclear Information System (INIS)

1996-01-01

When the Resource Conservation and Recovery Act Facility Investigation (RFI) in the 317/319/ENE Area of Argonne National Laboratory-East (ANL-E) was being completed, groundwater was discovered moving to the surface through a series of seeps. The seeps are located approximately 600 ft south of the ANL fence line in Waterfall Glen Forest Preserve. Samples of this water were collected and analyzed for selected parameters. Two of five seeps sampled were found to contain detectable levels of organic contaminants. Three chemical species were identified: chloroform (14-25 μg/L), carbon tetrachloride (56-340 μg/L), and tetrachloroethylene (3-6 μg/L). The other seeps did not contain detectable levels of volatile organic compounds (VOCs). The water issuing from these two contaminated seeps flows into a narrow ravine, where it is visible as a trickle of water flowing through sand and gravel deposits on the floor of the ravine. Approximately 100-ft downstream of the seep area, the contaminated water is no longer visible, having drained back into the soil in the bed of the ravine. Figure 1 shows the location of the 317/319/ENE Area in relation to the ANL-E site and the Waterfall Glen Forest Preserve

Stereoselectivity in ene reactions with 1O2: matrix effects in polymer supports, photo-oxygenation of organic salts and asymmetric synthesis.

Science.gov (United States)

Griesbeck, Axel G; Bartoschek, Anna; Neudörfl, Jörg; Miara, Claus

2006-01-01

The ene reaction of chiral allylic alcohols is applied as a tool for the investigation of intrapolymer effects by means of the stereoselectivity of the singlet-oxygen addition. The diastereo selectivity strongly depends on the structure of the polymer, the substrate loading degree and also on the degree of conversion demonstrating additional supramolecular effects evolving during the reaction. The efficiency and the stability of polymer-bound sensitizers were evaluated by the ene reaction of singlet oxygen with citronellol. The ene reaction with chiral ammonium salts of tiglic acid was conducted under solution phase conditions or in polystyrene beads under chiral contact ion-pair conditions. The products thus obtained precipitate during the photoreaction as ammonium salts. Moderate asymmetric induction was observed for this procedure for the first time.

Synergistic Diazo-OH Insertion/Conia-Ene Cascade Catalysis for the Stereoselective Synthesis of γ-Butyrolactones and Tetrahydrofurans.

Science.gov (United States)

Hunter, Arianne C; Schlitzer, Steven C; Sharma, Indrajeet

2016-11-02

A novel and highly efficient diazo-OH insertion/Conia-ene cascade reaction of readily available homopropargylic acids and alcohols with diazo carbonyl compounds is described. The cascade reaction involves a synergistic Rh/Ag/Au catalyst cocktail and proceeds instantly with a variety of substituted diazo compounds and acids/alcohols to provide functionalized γ-butyrolactones and tetrahydrofurans with complete regio- and stereoselectivity. The unprecedented rate-enhancement, complete stereoselectivity, and the enabling of new Conia-ene cyclizations suggest a concerted [4+1]-cycloaddition reaction pathway under synergistic (Rh/Ag/Au)-catalysis conditions. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

One-step fabrication of PEGylated fluorescent nanodiamonds through the thiol-ene click reaction and their potential for biological imaging

Science.gov (United States)

Huang, Hongye; Liu, Meiying; Tuo, Xun; Chen, Junyu; Mao, Liucheng; Wen, Yuanqing; Tian, Jianwen; Zhou, Naigen; Zhang, Xiaoyong; Wei, Yen

2018-05-01

Over the past years, fluorescent carbon nanoparticles have got growing interest for biological imaging. Fluorescent nanodiamonds (FNDs) are novel fluorescent carbon nanoparticles with multitudinous useful properties, including remarkable fluorescence properties, extremely low toxicity and high refractive index. However, facile preparation of FNDs with designable properties and functions from non-fluorescent detonation nanodiamonds (DNDs) has demonstrated to be challengeable. In this work, we reported for the first time that preparation of Polyethylene glycol (PEG) functionalized FNDs through a one-step thiol-ene click reaction using thiol containing PEG (PEG-SH) as the coating agent. Based on the characterization results, we demonstrated that PEG-SH could be efficiently introduced on DNDs to obtain FNDs through the thiol-ene click chemistry. The resultant FND-PEG composites showed high water dispersibility, strong fluorescence and low cytotoxicity. Moreover, FND-PEG composites could be internalized by cells and displayed good cell dyeing performance. All of these features implied that FND-PEG composites are of great potential for biological imaging. Taken together, a facile one-step strategy based on the one-step thiol-ene click reaction has been developed for efficient preparation of FND-PEG composites from non-fluorescent DNDs. The strategy should be also useful for fabrication of many other functional FNDs via using different thiol containing compounds for the universality of thiol-ene click reaction.

Stavovi medicinskih sestara u Hrvatskoj o primarnom oživljavanju prijevremeno rođene novorođenčadi

OpenAIRE

Bilić, Iva; Prpić, Igor; Radić, Jelena; Vukelić, Petar; Petrović, Ana; Juretić, Emilija; Furlan, Ivanka

2008-01-01

CILJ: Cilj istraživanja bilo je ispitati stavove medicinskih sestara u Hrvatskoj o primarnom oživljavanju prijevremeno rođene djece. METODE: Pisanom anketom ispitivana je dob, roditeljstvo, radno iskustvo i mjesto rada te stavovi medicinskih sestara iz Hrvatske o primarnom oživljavanju prijevremeno rođene djece. Anketirano je 174 medicinskih sestara; 49 zaposlenih u rađaonici ili na mjestima rada sa trudnicama (Rađ/Tr), 79 u pedijatrijskim/ neonatološkim jedinicama intenzivnog liječenja (...

Advantages and drawbacks of Thiol-ene based resins for 3D-printing

Science.gov (United States)

Leonards, Holger; Engelhardt, Sascha; Hoffmann, Andreas; Pongratz, Ludwig; Schriever, Sascha; Bläsius, Jana; Wehner, Martin; Gillner, Arnold

2015-03-01

The technology of 3D printing is conquering the world and awakens the interest of many users in the most varying of applications. New formulation approaches for photo-sensitive thiol-ene resins in combination with various printing technologies, like stereolithography (SLA), projection based printing/digital light processing (DLP) or two-photon polymerization (TPP) are presented. Thiol-ene polymerizations are known for its fast and quantitative reaction and to form highly homogeneous polymer networks. As the resins are locally and temporally photo-curable the polymerization type is very promising for 3D-printing. By using suitable wavelengths, photoinitiator-free fabrication is feasible for single- and two photon induced polymerization. In this paper divinyl ethers of polyethylene glycols in combination with star-shaped tetrathiols were used to design a simple test-system for photo-curable thiol-ene resins. In order to control and improve curing depth and lateral resolution in 3D-polymerization processes, either additives in chemical formulation or process parameters can be changed. The achieved curing depth and resolution limits depend on the applied fabrication method. While two-/multiphoton induced lithography offers the possibility of micron- to sub-micron resolution it lacks in built-up speed. Hence single-photon polymerization is a fast alternative with optimization potential in sub-10-micron resolution. Absorber- and initiator free compositions were developed in order to avoid aging, yellowing and toxicity of resulting products. They can be cured with UV-laser radiation below 300 nm. The development at Fraunhofer ILT is focusing on new applications in the field of medical products and implants, technical products with respect to mechanical properties or optical properties of 3D-printed objects. Recent process results with model system (polyethylene glycol divinylether/ Pentaerithrytol tetrakis (3-mercaptopropionat), Raman measurements of polymer conversion

Heterofunctional Glycopolypeptides by Combination of Thiol-Ene Chemistry and NCA Polymerization.

Science.gov (United States)

Krannig, Kai-Steffen; Schlaad, Helmut

2016-01-01

Glycopolypeptides are prepared either by the polymerization of glycosylated amino acid N-carboxyanhydrides (NCAs) or by the post-polymerization functionalization of polypeptides with suitable functional groups. Here we present a method for the in-situ functionalization and (co-) polymerization of allylglycine N-carboxyanhydride in a facile one-pot procedure, combining radical thiol-ene photochemistry and nucleophilic ring-opening polymerization techniques, to yield well-defined heterofunctional glycopolypeptides.

Continuous Flow Science in an Undergraduate Teaching Laboratory: Photocatalytic Thiol-Ene Reaction Using Visible Light

Science.gov (United States)

Santandrea, Jeffrey; Kairouz, Vanessa; Collins, Shawn K.

2018-01-01

An undergraduate teaching laboratory experiment involving a continuous flow, photocatalytic thiol-ene reaction using visible-light irradiation is described that allows students to explore concepts of green chemistry, photochemistry, photocatalysis, and continuous flow chemistry.

Emplazamiento hacia el ENE del manto de Los Reales (Alpujarrides occidentales: criterios estructurales y de petrofábrica

Directory of Open Access Journals (Sweden)

Tubía, J. M.

1984-08-01

Full Text Available Los Reales nappe rests over Ojén nappe to the North of Sierra Alpujata. The nappe contact zone shows a intense plastic deformation with mylonitic rocks, The deformation decreases progressively going away from the contacto The structural study of footwall and hangingwall roen permits to attribute this deformation to the Los Reales nappe emplacement over that of Ojén. The foliation and stretching lineation distributions show a WSW-ENE shear direction. The mylonite microstructural characteristics and the enstatite crystalline preferred orientations in the basal peridotites give a mear sense in according that, Los Reales nappe is displaced, in their present position, from the WSW towards the ENE.

El manto de Los Reales descansa sobre el manto de Ojén, al norte de Sierra Alpujata. La zona de contacto entre mantos exhibe una intensa deformación plástica con rocas miloníticas; la deformación disminuye progresivamente al alejarse del contacto. El estudio estructural de las rocas infra y suprayacentes al contacto permite atribuir esta deformación al emplazamiento del manto de Los Reales sobre el de Ojén. , Las distribuciones de la foliación y de la lineación, de estiramiento indican una dirección de cizallamiento WSW-ENE. Las características microestructurales de las milonitas y las orientaciones preferentes cristalinas de la enstatita en las peridotitas basales proporcionan un sentido de cizallamiento tal que el manto de Los Reales se ha desplazado, en su posición actual, desde el WSW hacia el ENE.

Efforts toward rapid construction of the cortistatin A carbocyclic core via enyne-ene metathesis

KAUST Repository

Baumgartner, Corinne; Ma, Sandy; Liu, Qi; Stoltz, Brian M.

2010-01-01

Our efforts toward the construction of the carbocylic core of cortistatin A via an enyne-ene metathesis are disclosed. Interestingly, an attempted S N2 inversion of a secondary mesylate in our five-membered D-ring piece gave a product with retention

Eesti teatri aastaauhinnad 2006. aasta loomingu eest

Index Scriptorium Estoniae

2007-01-01

Elmo Nüganen - lavastajaauhind, Ene-Liis Semper - kunstniku auhind, Hele Kõre - naisnäitleja auhind, Lembit Ulfsak - meesnäitleja auhind, Evelin Pang - naiskõrvalosa auhind, Margus Prangel - meeskõrvalosa auhind, Oleg Titov - draamalavastuse eriauhind, Helen Lokuta ja Lauri Sirp - muusikalavastuse auhind, Michiel Dijkema - muusikalavastuse eriauhind, Mare Tommingas - balletilavastuse auhind, ZUGA ühendatud tantsijad - tantsulavastuse auhind, Margus Mikomägi - kriitikaauhind, Tiit Sukk - Ants Lauteri näitlejaauhind, Ingomar Vihmar - Ants Lauteri lavastajaauhind, Rauno Elp - Georg Otsa auhind, Aare Toikka - Salme Reegi auhind, Reet Aus - Natalie Mei auhind, Anu Lamp - Priit Põldroosi auhind, Peeter Sauter - Aleksander Kurtna auhind, Artjom Maksakov ja Natalja Popenko - Kristallkingakese auhind, Enar Tarmo, Hendrik Kiisler ja Marika Tint - tehnilise töötaja auhind

Eesti teatri aastaauhinnad 2006

Index Scriptorium Estoniae

2007-01-01

Elmo Nüganen - lavastajaauhind, Ene-Liis Semper - kunstniku auhind, Hele Kõre - naisnäitleja auhind, Lembit Ulfsak - meesnäitleja auhind, Evelin Pang - naiskõrvalosa auhind, Margus Prangel - meeskõrvalosa auhind, Oleg Titov - draamalavastuse eriauhind, Helen Lokuta ja Lauri Sirp - muusikalavastuse auhind, Michiel Dijkema - muusikalavastuse eriauhind, Mare Tommingas - balletilavastuse auhind, ZUGA ühendatud tantsijad - tantsulavastuse auhind, Margus Mikomägi - kriitikaauhind, Tiit Sukk - Ants Lauteri näitlejaauhind, Ingomar Vihmar - Ants Lauteri lavastajaauhind, Rauno Elp - Georg Otsa auhind, Aare Toikka - Salme Reegi auhind, Reet Aus - Natalie Mei auhind, Anu Lamp - Priit Põldroosi auhind, Peeter Sauter - Aleksander Kurtna auhind, Artjom Maksakov ja Natalja Popenko - Kristallkingakese auhind, Enar Tarmo, Hendrik Kiisler ja Marika Tint - tehnilise töötaja auhind

Preparation and Characterization of Fluorinated Hydrophobic UV-Crosslinkable Thiol-Ene Polyurethane Coatings

OpenAIRE

Wenjing Xia; Nianqing Zhu; Rongjie Hou; Wengui Zhong; Mingqing Chen

2017-01-01

The polyurethane prepolymer terminated with a double bond was synthesized using isophorone diisocyanate (IPDI), hydroxyl terminated polybutadiene (HTPB), 1,4-butanediol (BDO), and 2-hydroxyethyl acrylate (HEA). Then, a series of innovative UV-curable polyurethane coatings were prepared by blending ene-terminated polyurethane, fluoroacrylate monomer, and multifunctional thiol crosslinker upon UV exposure. The incorporation of fluoroacrylate monomer and multifunctional thiols into polyurethane ...

High performance thiol-ene thermosets based on fully bio-based poly(limonene carbonate)s

NARCIS (Netherlands)

Li, C.; Johansson, M.; Sablong, R.J.; Koning, C.E.

2017-01-01

High glass transition temperature (Tg) thiol-ene networks (TENs) based on poly(limonene carbonate)s (PLCs), derived from orange oils and of potential degradability are described here. PLCs with moderate molecular weight were prepared by copolymerization of limonene oxide with CO2 and subsequent

ENED-GEM: A Conceptual Framework Model for Psychological Enjoyment Factors and Learning Mechanisms in Educational Games about the Environment

Science.gov (United States)

Fjællingsdal, Kristoffer S.; Klöckner, Christian A.

2017-01-01

Based on a thorough review of psychological literature, this article seeks to develop a model of game enjoyment and environmental learning (ENvironmental EDucational Game Enjoyment Model, ENED-GEM) and delineate psychological processes that might facilitate learning and inspire behavioral change from educational games about the environment. A critically acclaimed digital educational game about environmental issues (Fate of the World by Red Redemption/Soothsayer Games) was used as a case study. Two hundred forty-nine reviews of the game from the popular gaming and reviewing platform known as Steam were analyzed by means of a thematic content analysis in order to identify key player enjoyment factors believed to be relevant to the process of learning from games, as well as to gain an understanding of positive and negative impressions about the game’s general content. The end results of the thematic analysis were measured up to the suggested ENED-GEM framework. Initial results generally support the main elements of the ENED-GEM, and future research into the importance of these individual core factors is outlined. PMID:28701988

ENED-GEM: A Conceptual Framework Model for Psychological Enjoyment Factors and Learning Mechanisms in Educational Games about the Environment

Directory of Open Access Journals (Sweden)

Kristoffer S. Fjællingsdal

2017-06-01

Full Text Available Based on a thorough review of psychological literature, this article seeks to develop a model of game enjoyment and environmental learning (ENvironmental EDucational Game Enjoyment Model, ENED-GEM and delineate psychological processes that might facilitate learning and inspire behavioral change from educational games about the environment. A critically acclaimed digital educational game about environmental issues (Fate of the World by Red Redemption/Soothsayer Games was used as a case study. Two hundred forty-nine reviews of the game from the popular gaming and reviewing platform known as Steam were analyzed by means of a thematic content analysis in order to identify key player enjoyment factors believed to be relevant to the process of learning from games, as well as to gain an understanding of positive and negative impressions about the game’s general content. The end results of the thematic analysis were measured up to the suggested ENED-GEM framework. Initial results generally support the main elements of the ENED-GEM, and future research into the importance of these individual core factors is outlined.

ENED-GEM: A Conceptual Framework Model for Psychological Enjoyment Factors and Learning Mechanisms in Educational Games about the Environment.

Science.gov (United States)

Fjællingsdal, Kristoffer S; Klöckner, Christian A

2017-01-01

Based on a thorough review of psychological literature, this article seeks to develop a model of game enjoyment and environmental learning (ENvironmental EDucational Game Enjoyment Model, ENED-GEM) and delineate psychological processes that might facilitate learning and inspire behavioral change from educational games about the environment. A critically acclaimed digital educational game about environmental issues (Fate of the World by Red Redemption/Soothsayer Games) was used as a case study. Two hundred forty-nine reviews of the game from the popular gaming and reviewing platform known as Steam were analyzed by means of a thematic content analysis in order to identify key player enjoyment factors believed to be relevant to the process of learning from games, as well as to gain an understanding of positive and negative impressions about the game's general content. The end results of the thematic analysis were measured up to the suggested ENED-GEM framework. Initial results generally support the main elements of the ENED-GEM, and future research into the importance of these individual core factors is outlined.

Lift 11 paneb arhitektid ja kunstnikud linna arendama / Oliver Õunmaa

Index Scriptorium Estoniae

Õunmaa, Oliver

2011-01-01

Kultuuripealinna programmi raames maist septembrini Tallinna avalikus ruumis toimuvast linnainstallatsioonide festivalist "Lift11". Kuraatorid Margit Aule, Margit Argus, Maarin Mürk, Ingrid Ruudi. Ideekonkursile esitatud 129 teosest valiti teostamiseks 17 installatsiooni. Tutvustab Margit Aule

[Tiit-Rein Viitso. Līvõkīel-estikīel-leţkīel sõnārōntõz] / Eberhard Winkler

Index Scriptorium Estoniae

Winkler, Eberhard, 1955-

2013-01-01

Arvustus: Līvõkīel-estikīel-leţkīel sõnārōntõz = Liivi-eesti-läti sõnaraamat = Lībiešu-igauņu-latviešu vārdnīca / [koostamine:] Tiit-Rein Viitso, [toimetamine ja läti vasted:] Valts Ernštreits. Riga : Latviešu valodas aģentūra ; Tartu : Tartu Ülikool, 2012

Efforts toward rapid construction of the cortistatin A carbocyclic core via enyne-ene metathesis

KAUST Repository

Baumgartner, Corinne

2010-01-01

Our efforts toward the construction of the carbocylic core of cortistatin A via an enyne-ene metathesis are disclosed. Interestingly, an attempted S N2 inversion of a secondary mesylate in our five-membered D-ring piece gave a product with retention of stereochemistry. © 2010 The Royal Society of Chemistry.

Amino acid-incorporated polymer network by thiol-ene polymerization

Directory of Open Access Journals (Sweden)

R. Yokose

2015-08-01

Full Text Available Triallyl L-alanine (A3A and triallyl L-phenylalanine (A3F were synthesized by reactions of L-alanine and L-phenylalanine with allyl bromide in the presence of sodium hydroxide, respectively. Thiol-ene thermal polymerization of A3A or A3F with pentaerythritol-based primary tetrathiol (pS4P or pentaerythritol-based secondary tetrathiol (S4P at allyl/SH 1/1 in the presence of 2,2'-azobis(isobutyronitrile produced an amino acid-incorporated polymer network (A3ApS4P, A3A-S4P or A3F-S4P. Although the thermally cured resins were homogeneous and flat films, the corresponding thiol-ene photopolymerization did not give a successful result. Degree of swelling for each thermally cured film in N,Ndimethylformamide was much higher than that in water. The glass transition and 5% weight loss temperatures (Tg and T5 of A3F-pS4P and A3F-S4P were higher than those of A3A-pS4P and A3A-S4P, respectively. Also, A3F-pS4P and A3F-S4P exhibited much higher tensile strengths and moduli than A3A-pS4P and A3A-S4P did, respectively. Consequently, A3FpS4P displayed the highest Tg (38.7°C, T5 (282.0°C, tensile strength (9.5 MPa and modulus (406 MPa among all the thermally cured resins.

Ene-Liis Semper : Kohalolu piiritsoonis = Presence in the border zone / Anu Allas

Index Scriptorium Estoniae

Allas, Anu, 1977-

2007-01-01

Teatri- ja videokunstnik Ene-Liis Semperi peamiselt 1990-ndate aastate videotest, mis on valdavalt rõhutatult lavastuslikud, paisutatult sümbolistlikud või kus on esitatud piirsituatsioone, ahistust ning selle teadlikku eksponeerimist väljakutsena publikule. Iseennast paljastades, alandades ja ohtu seades jääb kunstnik enamasti jahedalt distantseerituks, publikule jääb aga arusaamatuks, kas tegemist on ohvri, kangelanna või osava mänguriga

Teater

Index Scriptorium Estoniae

2006-01-01

Vanemuise teatri draamanäitlejad tunnistasid möödunud aasta parimaks lavastuseks augustis Setumaal Obinitsas etendunud "Taarka", mille lavastas Ain Mäeots. Parimaks naispeaosatäitjaks valiti Merle Jääger, parimaks meespeaosatäitjaks Indrek Taalmaa, parimaks naiskõrvalosatäitjaks Karin Tammaru, parimaks meeskõrvalosatäitjaks Tanel Jonas. Eesti Draamateatri 2005. aasta Antsud ehk kolleegipreemiate laureaadid : Ingomar Vihmar (parim lavastaja), Ervin Õunapuu (parim kunstnik), Ülle Kaljuste (parim naisnäitleja), Ain Lutsepp (parim meesnäitleja), Väikesed Antsud pälvisid Elina Reinold ja Taavi Teplenkov, Abi-Antsuks kuulutati teatri kirjandusala juhataja Ene Paaver. Endla 2005. aasta kolleegipreemiad said Lii Tedre (parim naisnäitleja), Tambet Seling (parim meesnäitleja), Tiit Palu (parim lavastaja) ja Silver Vahtre (parim kunstnik)

Teatri aastaauhindade laureaadid 2007

Index Scriptorium Estoniae

2007-01-01

Elmo Nüganen - lavastajaauhind, Ene-Liis Semper - kunstniku auhind, Hele Kõre - naisnäitleja auhind, Lembit Ulfsak - meesnäitleja auhind, Evelin Pang - naiskõrvalosa auhind, Margus Prangel - meeskõrvalosa auhind, Oleg Titov - draamalavastuse eriauhind, Helen Lokuta ja Lauri Sirp - muusikalavastuse auhind, Michiel Dijkema - muusikalavastuse eriauhind, Mare Tommingas - balletilavastuse auhind, ZUGA ühendatud tantsijad - tantsulavastuse auhind, Margus Mikomägi - kriitikaauhind, Tiit Sukk - Ants Lauteri näitlejaauhind, Ingomar Vihmar - Ants Lauteri lavastajaauhind, Rauno Elp - Georg Otsa auhind, Aare Toikka - Salme Reegi auhind, Reet Aus - Natalie Mei auhind, Anu Lamp - Priit Põldroosi auhind, Peeter Sauter - Aleksander Kurtna auhind, Artjom Maksakov ja Natalja Popenko - Kristallkingakese auhind, Enar Tarmo, Hendrik Kiisler ja Marika Tint - tehnilise töötaja auhind. Ka Kuressaares toimunud teatripeost

Teatri aastaauhindade laureaadid 2007

Index Scriptorium Estoniae

2007-01-01

Nimekiri teatri aastaauhinna laureaatidest sõna-, muusika-, balleti-, tantsulavastuste, teatri tehnilise töötaja auhinna kategoorias ja aasta kriitikaauhind. Elmo Nüganen - lavastajaauhind, Ene-Liis Semper - kunstniku auhind, Hele Kõre - naisnäitleja auhind, Lembit Ulfsak - meesnäitleja auhind, Evelin Pang - naiskõrvalosa auhind, Margus Prangel - meeskõrvalosa auhind, Oleg Titov - draamalavastuse eriauhind, Helen Lokuta ja Lauri Sirp - muusikalavastuse auhind, Michiel Dijkema - muusikalavastuse eriauhind, Mare Tommingas - balletilavastuse auhind, ZUGA ühendatud tantsijad - tantsulavastuse auhind, Margus Mikomägi - kriitikaauhind, Tiit Sukk - Ants Lauteri näitlejaauhind, Ingomar Vihmar - Ants Lauteri lavastajaauhind, Rauno Elp - Georg Otsa auhind, Aare Toikka - Salme Reegi auhind, Reet Aus - Natalie Mei auhind, Anu Lamp - Priit Põldroosi auhind, Peeter Sauter - Aleksander Kurtna auhind, Artjom Maksakov ja Natalja Popenko - Kristallkingakese auhind

1-Methoxy-3-o-tolylbicyclo[2.2.2]oct-5-ene-2,2-dicarbonitrile

Directory of Open Access Journals (Sweden)

Orhan Büyükgüngör

2009-09-01

Full Text Available In the title compound, C18H18N2O, the cyclohexene and cyclohexane rings of the bicyclo[2.2.2]oct-5-ene unit adopt distorted boat conformations. In the crystal, molecules exist as C—H...N hydrogen-bonded centrosymmetric R22(14 dimers, which are further linked by C—H...π interactions.

Thiol-Ene Photo-Click Collagen-PEG Hydrogels: Impact of Water-Soluble Photoinitiators on Cell Viability, Gelation Kinetics and Rheological Properties

Directory of Open Access Journals (Sweden)

Róisín Holmes

2017-06-01

Full Text Available Thiol-ene photo-click hydrogels were prepared via step-growth polymerisation using thiol-functionalised type-I collagen and 8-arm poly(ethylene glycol norbornene-terminated (PEG-NB, as a potential injectable regenerative device. Type-I collagen was thiol-functionalised by a ring opening reaction with 2-iminothiolane (2IT, whereby up to 80 Abs.% functionalisation and 90 RPN% triple helical preservation were recorded via 2,4,6-Trinitrobenzenesulfonic acid (TNBS colorimetric assay and circular dichroism (CD. Type, i.e., either 2-Hydroxy-1-[4-(2-hydroxyethoxy phenyl]-2-methyl-1-propanone (I2959 or lithium phenyl-2,4,6-trimethylbenzoylphosphinate (LAP, and concentration of photoinitiator were varied to ensure minimal photoinitiator-induced cytotoxicity and to enable thiol-ene network formation of collagen-PEG mixtures. The viability of G292 cells following 24 h culture in photoinitiator-supplemented media was largely affected by the photoinitiator concentration, with I2959-supplemented media observed to induce higher toxic response (0.1 → 0.5% (w/v I2959, cell survival: 62 → 2 Abs.% compared to LAP-supplemented media (cell survival: 86 → 8 Abs.%. In line with the in vitro study, selected photoinitiator concentrations were used to prepare thiol-ene photo-click hydrogels. Gelation kinetics proved to be largely affected by the specific photoinitiator, with LAP-containing thiol-ene mixtures leading to significantly reduced complete gelation time (τ: 187 s with respect to I2959-containing mixtures (τ: 1683 s. Other than the specific photoinitiator, the photoinitiator concentration was key to adjusting the hydrogel storage modulus (G’, whereby 15-fold G’ increase (232 → 3360 Pa was observed in samples prepared with 0.5% (w/v compared to 0.1% (w/v LAP. Further thiol-ene formulations with 0.5% (w/v LAP and varied content of PEG-NB were tested to prepare photo-click hydrogels with porous architecture, as well as tunable storage modulus (G�

Koolirõõmuta kool on lapsele kui sunnitöö / Ene-Silvia Sarv ; intervjueerinud Karin Klaus

Index Scriptorium Estoniae

Sarv, Ene-Silvia, 1945-

2013-01-01

Intervjuu Pärnus hariduskonverentsil "Õnnelik õpilane, õnnelik õpetaja" esinenud Tallinna ülikooli lektori Ene-Silvia Sarvega, kes rääkis oma ettekandes, milline paistab tänapäeva kool õpilaste silme läbi ja mis mõjutab koolikliimat kõige enam

Rapid and simple preparation of thiol–ene emulsion-templated monoliths and their application as enzymatic microreactors

Czech Academy of Sciences Publication Activity Database

Lafleur, J. P.; Senkbeil, S.; Novotný, Jakub; Nys, G.; Bøgelund, N.; Rand, K. D.; Foret, František; Kutter, J. P.

2015-01-01

Roč. 15, č. 10 (2015), s. 2162-2172 ISSN 1473-0197 R&D Projects: GA ČR(CZ) GBP206/12/G014 Institutional support: RVO:68081715 Keywords : thiol-enes * mictoreactor * monolith * fabrication * proteins Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 5.586, year: 2015

Kas erivajadustega lapsed saavad õigel ajal abi? / Ene Mägi, Urve Raudsepp-Alt, Ale Sprenk, Peeter Aas

Index Scriptorium Estoniae

2009-01-01

Küsimusele vastavad: Tallinna Ülikooli Kasvatusteaduste Instituudi eri- ja sotsiaalpedagoogika osakonna juhataja Ene Mägi, Tallinna Haridusameti üldhariduse osakonna peaspetsialist Urve Raudsepp-Alt, Krabi põhikooli direktor Ale Sprenk, Põlva Maavalitsuse haridus-, kultuuri- ja sotsiaalosakonna juhataja Peeter Aas

Poly(ethylene glycol)-based thiol-ene hydrogel coatings: curing chemistry, aqueous stability, and potential marine antifouling applications

NARCIS (Netherlands)

Lundberg, P.; Bruin, A.; Klijnstra, J.W.; Nyström, A.M.; Johansson, M.; Malkoch, M.; Hult, A.

2010-01-01

Photocured thiol-ene hydrogel coatings based on poly(ethylene glycol) (PEG) were investigated for marine antifouling purposes. By varying the PEG length, vinylic end-group, and thiol cross-linker, a library of hydrogel coatings with different structural composition was efficiently accomplished, with

Limitations of the Neurological Evolutional Exam (ENE as a motor assessment for first graders Limitações do Exame Neurológico Evolutivo (ENE como um instrumento de avaliação motora para crianças da primeira série

Directory of Open Access Journals (Sweden)

Priscila M. Caçola

2010-10-01

Full Text Available BACKGROUND: Many clinicians and researchers in Brazil consider the Neurological Developmental Exam (NDE, a valid and reliable assessment for Brazilian school-aged children. However, since its inception, several tests have emerged that, according to some researchers, provide more in-depth evaluation of motor ability and go beyond the detection of general motor status (soft neurological signs. OBJECTIVES: To highlight the limitations of the NDE as a motor skill assessment for first graders. METHODS: Thirty-five children were compared on seven selected items of the NDE, seven of the Bruininks-Oseretsky Test (BOT, and seven of the Visual-Motor Integration test (VMI. Participants received a "pass" or "fail" score for each item, as prescribed by the respective test manual. RESULTS: Chi-square and ANOVA results indicated that the vast majority of children (74% passed the NDE items, whereas values for the other tests were 29% (BOT and 20% (VMI. Analysis of specific categories (e.g. visual, fine, and gross motor coordination revealed a similar outcome. CONCLUSIONS: Our data suggest that while the NDE may be a valid and reliable test for the detection of general motor status, its use as a diagnostic/remedial tool for identifying motor ability is questionable. One of our recommendations is the consideration of a revised NDE in light of the current needs of clinicians and researchers.CONTEXTUALIZAÇÃO: Muitos clínicos e pesquisadores brasileiros consideram o Exame Neurológico Evolutivo (ENE, um instrumento válido e confiável para crianças brasileiras em idade escolar. Entretanto, desde a sua criação, surgiram outros testes para uma avaliação mais profunda de habilidade motora, os quais vão além de detectar status motor geral em forma de sinais neurológicos leves. OBJETIVOS: Demonstrar os pontos fracos do ENE como teste de avaliação de habilidade motora para crianças de primeira série. MÉTODOS: Trinta e cinco crianças realizaram 7 itens

A Convergent Enantioselective Total Synthesis of (-)-Perhydrohistrionicotoxin with an Intramolecular Imino Ene-type Reaction as a Key Step

DEFF Research Database (Denmark)

Tanner, David Ackland; Hagberg, Lars

1998-01-01

A convergent enantioselective total synthesis of the neurotoxic spirocyclic alkaloid (-)-perhydrohistrionicotoxin (2) is described. A Lewis acid-mediated intramolecular imine ene-type reaction was used for the key spirocyclisation step (14 to 3, with 3 being obtained as a single diastereoisomer...

Süütust näpates : Tanel Veenre fotoseeria teatrikostüümidest Draamateatri laval / Tanel Veenre, Hanna Tiidus, Margit Soosaar...[jt.

Index Scriptorium Estoniae

2007-01-01

Stilist: Hanna Tiidus. Naine: Merle Palmiste. Poiss: Joonas (MJ-Models). Kostüümid etendustest "Rohuvoodi" (Aime Unt), "Rehepapp", "Tõeline inspektor koer" (Ene-Liis Semper), "Liilia" (Lilja Blumenfeld), "Mort" (Kersti Varrak), "Potilaadale" (Reet Aus), "Amadeus" (Krista Tool)

Investigation of curing rates of bio-based thiol-ene films from diallyl 2,5-furandicaboxylate

DEFF Research Database (Denmark)

Larsen, Daniel Bo; Sønderbæk-Jørgensen, Rene; Duus, Jens Ø.

2018-01-01

The bio-based monomer, 2,5-furandicarboxylic acid, has been adapted to classic thiol-ene chemistry by derivatization of the acid with allyl alcohol. This new monomer has allowed for the synthesis of new thermoset systems, capable of forming green, sustainable materials through UV-crosslinking. In......The bio-based monomer, 2,5-furandicarboxylic acid, has been adapted to classic thiol-ene chemistry by derivatization of the acid with allyl alcohol. This new monomer has allowed for the synthesis of new thermoset systems, capable of forming green, sustainable materials through UV......-crosslinking. In this study, the synthesis of the new monomer along with thorough kinetic studies of the new thermoset systems are presented. In order to determine kinetic values for the systems, all reactions have been followed by real-time FT-IR. Initially, a study of three different photoinitiators is performed...... on a classic TEMPIC-TATATO system, in order to determine the superior initiator for the new systems. The new monomer is crosslinked with five different thiol compounds in both stoichiometric and off-stoichiometric ratios, yielding an array of bio-based thermosets. The properties of these systems are determined...

Assessment of the role of in situ generated (E)-2,4-diene-valproic acid in the toxicity of valproic acid and (E)-2-ene-valproic acid in sandwich-cultured rat hepatocytes

Energy Technology Data Exchange (ETDEWEB)

Surendradoss, Jayakumar; Chang, Thomas K.H.; Abbott, Frank S., E-mail: frank.abbott@ubc.ca

2012-11-01

Valproic acid (VPA) undergoes cytochrome P450-mediated desaturation to form 4-ene-VPA, which subsequently yields (E)-2,4-diene-VPA by β-oxidation. Another biotransformation pathway involves β-oxidation of VPA to form (E)-2-ene-VPA, which also generates (E)-2,4-diene-VPA by cytochrome P450-mediated desaturation. Although the synthetic form of (E)-2,4-diene-VPA is more hepatotoxic than VPA as shown in various experimental models, there is no conclusive evidence to implicate the in situ generated (E)-2,4-diene-VPA in VPA hepatotoxicity. The present study investigated the effects of modulating the in situ formation of (E)-2,4-diene-VPA on markers of oxidative stress (formation of 2′,7′-dichlorofluorescein; DCF), steatosis (accumulation of BODIPY 558/568 C{sub 12}), necrosis (release of lactate dehydrogenase; LDH), and on cellular total glutathione (GSH) levels in sandwich-cultured rat hepatocytes treated with VPA or (E)-2-ene-VPA. Treatment with either of these chemicals alone increased each of the toxicity endpoints. In VPA-treated hepatocytes, (E)-2,4-diene-VPA was detected only at trace levels, even after phenobarbital (PB) pretreatment and there was no effect on the toxicity of VPA. Furthermore, pretreatment with a cytochrome P450 enzyme inhibitor, 1-aminobenzotriazole (1-ABT), did not influence the extent of VPA toxicity in both PB-pretreated and vehicle-pretreated hepatocytes. However, in (E)-2-ene-VPA-treated hepatocytes, PB pretreatment greatly enhanced the levels of (E)-2,4-diene-VPA and this was accompanied by a further enhancement of the effects of (E)-2-ene-VPA on DCF formation, BODIPY accumulation, LDH release, and GSH depletion. Pretreatment with 1-ABT reduced the concentrations of (E)-2,4-diene-VPA and the extent of (E)-2-ene-VPA toxicity; however, this occurred in PB-pretreated hepatocytes, but not in control hepatocytes. In conclusion, in situ generated (E)-2,4-diene-VPA is not responsible for the hepatocyte toxicity of VPA, whereas it

Ene-Liis Semper: selle aasta puhkepäevad võib ühe käe sõrmedel kokku lugeda

Index Scriptorium Estoniae

Semper, Ene-Liis, 1969-

2011-01-01

Tallinna kultuuripealinna projekti panustanud Ene-Liis Semper võtab 2011. aasta sündmused kokku ja selgitab, kuidas jõudsid publiku ette suurlavastused "The Rise and Fall of Estonia", "Three Kingdoms", Põhuteater ning isikunäitus Kumus

Hydrophobic thiol-ene surfaces fabricated via plasma activation and photo polymerization

Science.gov (United States)

Champathet, P.; Ervithayasuporn, V.; Osotchan, T.; Dangtip, S.

2017-09-01

Alumina, such as glazed alumina for electrical insulator, operated in an open field subjects to a very harsh condition; resulting in lifetime shortening. Coating hydrophobic layer on alumina surface can help prolonging its lifetime. In this study, 25 ×25 mm alumina sheets were used as substrates. The hydrophobic composite polymers were prepared from (3-mercaptopropyl)trimethoxysilane(MPTMS), 2,4,6,8-tetramethyl-2,4,6,8tetravinylcyclotetra siloxane(TMTVSi), pentaerythritoltetra(3-mercaptopropionate)(PETMP), 2,2-dimethoxy-2-phe nylaceto phenone(photoinitiator) and heptadecafluorodecylmethacrylate(HEFDMA) via the thiol-ene reaction. The alumina sheets were first activated by dielectric-barrier discharge plasma to improve its adhesion. All the polymers were found to optimize at the ratio of (MPTMS:TMTVSi:PETMP:HDFDMA) to 4:2:1:2 for coating on the alumina substrate. To enhance polymerization, 2,2-dimethoxy-2-phenylaceto phenome was also used as a photoinitiator A proper mixing sequence in the thiol-ene reaction results in film with excellent surface retention after prolong soaking in solvent such as acetone. FTIR shows that S-H and C=C functional groups have significantly changed after photopolymerization and thermally cured. The static contact angle increase from mere 53.0°±1.5° of the uncoated substrate to 120.0°±1.2° after coating. SEM shows the film with clear appearance of a few-micron thick. Under AFM, the coated surface roughness was about 9.3 nm with evenly distributed spikes of a few nanometer in height. The cross-cut test also confirmed the film was very smooth and none of the square of the films detached.

Mida teie oma tervise heaks teete? / Ly Jagor, Ülle Mihhailova, Ene Pill, Katrin Käbin...[jt.

Index Scriptorium Estoniae

2008-01-01

Küsimusele vastavad Pärnu Õppenõustamiskeskuse psühholoog Ly Jagor, Maasika lasteaia juhataja asetäitja Ülle Mihhailova, Tallinna Perekeskuse ja Tähetorni lastekeskuse psühholoog Ene Pill, Tallinna Nõmme Noortemaja väikelaste ringijuht Katrin Käbin, Tääksi Põhikooli õpetaja Silva Kolk

Ülikooli varakamber = The University Treasury / Mariann Raisma

Index Scriptorium Estoniae

Raisma, Mariann, 1974-

2012-01-01

Tartu Ülikooli Ajaloo muuseumi varakambri sisearhitektuursest lahendusest ja ekspositsiooni kujundusest. Autorid Margit Argus ja Margit Aule. Projekteerija: KAOS Arhitektid. Valmis: 2012. Varakambri museoloogilisest kontseptsioonist

Inorganic-Organic Thiol-ene Coated Mesh for Oil/Water Separation.

Science.gov (United States)

Chen, Qiyi; de Leon, Al; Advincula, Rigoberto C

2015-08-26

A highly efficient mesh for oil/water separation was fabricated by using a superhydrophobic and superoleophilic coating of thiol-ene hybrid, consisting of pentaerythritol tetra(3-mercaptopropionate) (PETMP), 2,4,6,8-tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane (TMTVSi), and hydrophobic fumed silica nanoparticles, via a simple two-step fabrication process. Spray deposition and UV curing photopolymerization were sequentially performed, during which solvent evaporation provides microscale roughness while nanoparticle aggregation forms nanoscale roughness. The hierarchical morphologies were stabilized after UV curing photopolymerization. High contact angle (>150°) and low roll-off angle (<5°) were achieved due to the multiscale roughness structure of the hierarchical morphologies. These coatings also have excellent chemical resistance, as well as temperature and pH stability, after curing.

Thiol-ene thermosets exploiting surface reactivity for layer-by-layer structures and control of penetration depth for selective surface reactivity

DEFF Research Database (Denmark)

Daugaard, Anders Egede; Westh, Andreas; Pereira Rosinha Grundtvig, Ines

Thiol-ene thermosets have been shown to be an efficient platform for preparation of functional polymer surfaces. Especially the effectiveness and versatility of the system has enabled a large variety of network properties to be obtained in a simple and straight-forward way. Due to its selectivity......, various thiols and allyl or other vinyl reactants can be used to obtain either soft and flexible1 or more rigid functional thermosets 2. The methodology permits use of etiher thermal or photochemical conditions both for matrix preparation as well as for surface functionalization. Due to excess reactive...... groups in thµe surface of thiol-ene thermosets, it is possible to prepare surface functional thermosets or to exploit the reactive groups for modular construction and subsequent chemical bonding. Here a different approach preparing monolithic layer-by-layer structures with controlled mechanical...

3-(2-Benzofuranyl)quinuclidin-2-ene derivatives: novel muscarinic antagonists.

Science.gov (United States)

Nordvall, G; Sundquist, S; Johansson, G; Glas, G; Nilvebrant, L; Hacksell, U

1996-08-16

A series of 26 derivatives of the novel muscarinic antagonist 3-(2-benzofuranyl)quinuclidin-2-ene (1) has been synthesized and evaluated for muscarinic and antimuscarinic properties. The affinity of the compounds was determined by competition experiments in homogenates of cerebral cortex, heart, parotid gland, and urinary bladder from guinea pigs using (-)-[3H]-3-quinuclidinyl benzilate as the radioligand, and the antimuscarinic-potency was determined in a functional assay on isolated guinea pig urinary bladder using carbachol as the agonist. The 5-fluorobenzofuranyl derivative was slightly more potent than 1. The 7-bromo-substituted 8 displayed a 14-fold tissue selectivity ratio for muscarinic receptors in the cortex versus the parotid gland. Comparative molecular field analysis and quantitative structure-activity relationship models were developed for this series of substituted benzofuranyl derivatives.

Tartu Ülikooli Muuseumi varakamber = Treasury of the University of Tartu Museum

Index Scriptorium Estoniae

2015-01-01

Tartu Ülikooli Muuseumi varakamber Lossi tänav 25, valminud 2012. Arhitektuuri sihtkapitali sisearhitektuuripreemia 2012 minevikust tulevikku vaatava efektse ja noorusliku ekspositsiooniruumi kujundamise eest. Sisearhitektid Margit Argus, Margit Aule (KAOS Arhitektid)

Kohtla "majamasin" = Kohtla's Mining-Machine / Kaisa Kaer

Index Scriptorium Estoniae

Kaer, Kaisa

2013-01-01

Kohtla kaevanduspark Ida-Virumaal. Projekteerijad: Arden Arroval, Joonas Sarapuu / Innopolis Insenerid OÜ. Ekspositsiooni kujundus, sisekujundus ja asendiplaan: Margit Argus, Margit Aule / KAOS Arhitektid. 2014. a. valmib endise rikastusvabriku hoones maapealne külastuskeskus

Sõmeru keskusehoone = Sõmeru community centre

Index Scriptorium Estoniae

2011-01-01

Sõmeru alevikus Kooli 2 asuva Sõmeru keskusehoone arhitektuursest lahendusest ja sisekujundusest. Autorid Kristiina Arusoo, Karli Luik, Ralf Lõoke, Maarja Kask (Salto AB), Margit Argus. Loetletud AB Salto ja Margit Arguse tehtud töid

Biocatalysis with thermostable enzymes: structure and properties of a thermophilic 'ene'-reductase related to old yellow enzyme.

Science.gov (United States)

Adalbjörnsson, Björn V; Toogood, Helen S; Fryszkowska, Anna; Pudney, Christopher R; Jowitt, Thomas A; Leys, David; Scrutton, Nigel S

2010-01-25

We report the crystal structure of a thermophilic "ene" reductase (TOYE) isolated from Thermoanaerobacter pseudethanolicus E39. The crystal structure reveals a tetrameric enzyme and an active site that is relatively large compared to most other structurally determined and related Old Yellow Enzymes. The enzyme adopts higher order oligomeric states (octamers and dodecamers) in solution, as revealed by sedimentation velocity and multiangle laser light scattering. Bead modelling indicates that the solution structure is consistent with the basic tetrameric structure observed in crystallographic studies and electron microscopy. TOYE is stable at high temperatures (T(m)>70 degrees C) and shows increased resistance to denaturation in water-miscible organic solvents compared to the mesophilic Old Yellow Enzyme family member, pentaerythritol tetranitrate reductase. TOYE has typical ene-reductase properties of the Old Yellow Enzyme family. There is currently major interest in using Old Yellow Enzyme family members in the preparative biocatalysis of a number of activated alkenes. The increased stability of TOYE in organic solvents is advantageous for biotransformations in which water-miscible organic solvents and biphasic reaction conditions are required to both deliver novel substrates and minimize product racemisation.

Hydrophobic Coatings by Thiol-Ene Click Functionalization of Silsesquioxanes with Tunable Architecture.

Science.gov (United States)

Dirè, Sandra; Bottone, Davide; Callone, Emanuela; Maniglio, Devid; Génois, Isabelle; Ribot, François

2017-08-08

The hydrolysis-condensation of trialkoxysilanes under strictly controlled conditions allows the production of silsesquioxanes (SSQs) with tunable size and architecture ranging from ladder to cage-like structures. These nano-objects can serve as building blocks for the preparation of hybrid organic/inorganic materials with selected properties. The SSQs growth can be tuned by simply controlling the reaction duration in the in situ water production route (ISWP), where the kinetics of the esterification reaction between carboxylic acids and alcohols rules out the extent of organosilane hydrolysis-condensation. Tunable SSQs with thiol functionalities (SH-NBBs) are suitable for further modification by exploiting the simple thiol-ene click reaction, thus allowing for modifying the wettability properties of derived coatings. In this paper, coatings were prepared from SH-NBBs with different architecture onto cotton fabrics and paper, and further functionalized with long alkyl chains by means of initiator-free UV-induced thiol-ene coupling with 1-decene (C10) and 1-tetradecene (C14). The coatings appeared to homogeneously cover the natural fibers and imparted a multi-scale roughness that was not affected by the click functionalization step. The two-step functionalization of cotton and paper warrants a stable highly hydrophobic character to the surface of natural materials that, in perspective, suggests a possible application in filtration devices for oil-water separation. Furthermore, the purification of SH-NBBs from ISWP by-products was possible during the coating process, and this step allowed for the fast, initiator-free, click-coupling of purified NBBs with C10 and C14 in solution with a nearly quantitative yield. Therefore, this approach is an alternative route to get sol-gel-derived, ladder-like, and cage-like SSQs functionalized with long alkyl chains.

Fabrication of antibody-loaded microgels using microfluidics and thiol-ene photoclick chemistry.

Science.gov (United States)

Gregoritza, Manuel; Abstiens, Kathrin; Graf, Moritz; Goepferich, Achim M

2018-06-01

Reducing burst effects, providing controlled release, and safeguarding biologics against degradation are a few of several highly attractive applications for microgels in the field of controlled release. However, the incorporation of proteins into microgels without impairing stability is highly challenging. In this proof of concept study, the combination of microfluidics and thiol-ene photoclick chemistry was evaluated for the fabrication of antibody-loaded microgels with narrow size distribution. Norbornene-modified eight-armed poly(ethylene glycol) with an average molecular mass of 10,000 Da, 20,000 Da, or 40,000 Da were prepared as macromonomers for microgel formation. For functionalization, either hydrolytically cleavable ester or stable amide bonds were used. A microfluidic system was employed to generate precursor solution droplets containing macromonomers, the cross-linker dithiothreitol and the initiator Eosin-Y. Irradiation with visible light was used to trigger thiol-ene reactions which covalently cross-linked the droplets. For all bond-types, molecular masses, and concentrations gelation was very rapid (<20 s) and a plateau for the complex shear modulus was reached after only 5 min. The generated microgels had a rod-like shape and did not show considerable cellular toxicity. Stress conditions during the fabrication process were simulated and it could be shown that fabrication did not impair the activity of the model proteins lysozyme and bevacizumab. It was confirmed that the average hydrogel network mesh size was similar or smaller than the hydrodynamic diameter of bevacizumab which is a crucial factor for restricting diffusion and delaying release. Finally, microgels were loaded with bevacizumab and a sustained release over a period of 30 ± 4 and 47 ± 7 days could be achieved in vitro. Copyright © 2018 Elsevier B.V. All rights reserved.

Katkenud õpingute teise kõrgkooli "kolimine" nõuab visadust / Agne Narusk, Ene Küüner, Heli Mattisen, Kadri Osula

Index Scriptorium Estoniae

Narusk, Agne

2007-01-01

Pooleli jäänud ülikooliõpingute lõpetamisest. Varasemate õpingute ja töökogemuse arvestamise tingimusi õpingute jätkamisel selgitavad Tartu Ülikooli avatud ülikooli tasemeõppe koordinaator Ene Küüner, Tallinna Ülikooli akadeemiline prorektor Heli Mattisen ja Estonian Business Schoolì õppeosakonna juhataja Kadri Osula

Eesti Ajaloomuuseum = Estonian History Museum

Index Scriptorium Estoniae

2012-01-01

Renoveeritud Eesti Ajaloomuuseumi Suurgildi hoone sisekujundusest ja ekspositsioonist. Sisekujundusprojekti autorid: Margit Aule (KAOS Arhitektid), Liis Lindvere (KOKO Arhitektid) ja Margit Argus (KAOS Arhitektid), loetletud nende töid. Suure saali metallpõranda autorid: Risto Tali, Rait Siska

A neutral polyacrylate copolymer coating for surface modification of thiol-ene microchannels for improved performance of protein separation by microchip electrophoresis

DEFF Research Database (Denmark)

Mesbah, Kiarach; Mai, T.D.; Jensen, Thomas Glasdam

2016-01-01

We have investigated the behavior of thiol-ene substrates that is a class of promising materials for lab-on-a-chip electrophoresis applications. Two polymeric materials were prepared by copolymerization of N, N-dimethylacrylamide (DMA), (3-(methacryloyl-oxy)propyl)trimethoxysilane (PMA) and 3-tri...

Selective fluorescence quenching of 2,3-diazabicyclo[2.2.2]oct-2-ene by nucleotides.

Science.gov (United States)

Marquez, Cesar; Pischel, Uwe; Nau, Werner M

2003-10-16

[reaction: see text] The fluorescence quenching of 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) by nucleotides has been studied. The quenching mechanism was analyzed on the basis of deuterium isotope effects, tendencies for exciplex formation, and the quenching efficiency in the presence of a molecular container (cucurbit[7]uril). Exciplex-induced quenching appears to prevail for adenosine, cytidine, and uridine, while hydrogen abstraction becomes competitive for thymidine and guanosine. Compared to other fluorescent probes, DBO responds very selectively to the type of nucleotide.

Lift11 / Ingrid Ruudi

Index Scriptorium Estoniae

Ruudi, Ingrid, 1978-

2010-01-01

23. augustist 11. oktoobrini 2010 toimuvast konkursist, mille eesmärk on leida kultuuripealinna üritusena toimuva linnainstallatsioonide festivali "Lift11" tarvis installatsioonide ideekavandeid. Festivali kuraatorid on kunstiteadlased Maarin Mürk ja Ingrid Ruudi ning arhitektid Margit Aule ja Margit Argus

Thiol-ene click chemistry derived cationic cyclodextrin chiral stationary phase and its enhanced separation performance in liquid chromatography.

Science.gov (United States)

Yao, Xiaobin; Tan, Timothy Thatt Yang; Wang, Yong

2014-01-24

This work is the first demonstration of a simple thiol-ene click chemistry to anchor vinyl imidazolium β-CD onto thiol silica to form a novel cationic native cyclodextrin (CD) chiral stationary phase (CSP). The CSP afforded high enantioseparation ability towards dansyl (Dns) amino acids, carboxylic aryl compounds and flavonoids in chiral HPLC. The current CSP demonstrates the highest resolving ability (selectivity >1.1, resolution >1.5) towards Dns amino acids in a mobile phase buffered at pH=6.5, with the resolution of Dns-dl-leucine as high as 6.97. 2,4-dichloride propionic acid (2,4-ClPOPA) was well resolved with the selectivity and resolution of 1.37 and 4.88, respectively. Compared to a previously reported native CD-CSP based on a triazole linkage, the current cationic CD-CSP shows a stronger retention and higher resolution towards acidic chiral compounds, ascribed to the propitious strong electrostatic attraction. Stability evaluation results indicated that thiol-ene reaction can provide a facile and robust approach for the preparation of positively charged CD CSPs. Copyright © 2013 Elsevier B.V. All rights reserved.

Functional characterization and stability improvement of a ‘thermophilic-like’ ene-reductase from Rhodococcus opacus 1CP

Directory of Open Access Journals (Sweden)

Anika eRiedel

2015-10-01

Full Text Available Ene-reductases are widely applied for the asymmetric synthesis of relevant industrial chemicals. A novel ene-reductase OYERo2 was found within a set of 14 putative Old Yellow Enzymes (OYEs obtained by genome mining of the actinobacterium Rhodococcus opacus 1CP. Multiple sequence alignment suggested that the enzyme belongs to the group of ‘thermophilic-like’ OYEs. OYERo2 was produced in Escherichia coli and biochemically characterized. The enzyme is strongly NADPH dependent and uses non-covalently bound FMNH2 for the reduction of activated α,β-unsaturated alkenes. In the active form OYERo2 is a dimer. Optimal catalysis occurs at pH 7.3 and 37 °C. OYERo2 showed highest specific activities (4550 U mg-1 on maleimides, which are efficiently converted to the corresponding succinimides. The OYERo2-mediated reduction of prochiral alkenes afforded the (R-products with excellent optical purity (ee > 99%. OYERo2 is not as thermo-resistant as related OYEs. Introduction of a characteristic intermolecular salt bridge by site-specific mutagenesis raised the half-life of enzyme inactivation at 32 °C from 28 min to 87 min and improved the tolerance towards organic co-solvents. The suitability of OYERo2 for application in industrial biocatalysis is discussed.

NO 99 näitlejatel ei ole veel aega sõrmega mööda aialippe vedada / Tiit Ojasoo ; interv. Margus Mikomägi

Index Scriptorium Estoniae

Ojasoo, Tiit, 1977-

2007-01-01

Lavastajaga teist suve Haapsalu lennuvälja angaarides mängitavast lavastusest "Kuningas Ubu" (peaosatäitjaks Jarek Kasar). Lisaks Ene-Liis Semperi vastus näitlejate kostüüme puudutavale küsimusele. Artikkel ilmub Teatrikülgedel rubriigis "Teater & küljed" 7/19

Polysiloxane-based luminescent elastomers prepared by thiol-ene "click" chemistry.

Science.gov (United States)

Zuo, Yujing; Lu, Haifeng; Xue, Lei; Wang, Xianming; Wu, Lianfeng; Feng, Shengyu

2014-09-26

Side-chain vinyl poly(dimethylsiloxane) has been modified with mercaptopropionic acid, methyl 3-mercaptopropionate, and mercaptosuccinic acid. Coordinative bonding of Eu(III) to the functionalized polysiloxanes was then carried out and crosslinked silicone elastomers were prepared by thiol-ene curing reactions of these composites. All these europium complexes could be cast to form transparent, uniform, thin elastomers with good flexibility and thermal stability. The networks were characterized by FTIR, NMR, UV/Vis, and luminescence spectroscopy as well as by scanning electron microscopy, thermogravimetric analysis, and X-ray photoelectron spectroscopy. The europium elastomer luminophores exhibited intense red light at 617 nm under UV excitation at room temperature due to the (5)D0 →(7)F2 transition in Eu(III) ions. The newly synthesized luminescent materials offer many advantages, including the desired mechanical flexibility. They cannot be dissolved or fused, and so they have potential for use in optical and electronic applications. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Synthesis of Upconverting Hydrogel Nanocomposites Using Thiol-Ene Click Chemistry: Template for the Formation of Dendrimer-Like Gold Nanoparticle Assemblies.

Science.gov (United States)

Meesaragandla, Brahmaiah; Mahalingam, Venkataramanan

2015-11-16

The synthesis of upconverting hydrogel nanocomposites by base-catalyzed thiol-ene click reaction between 10-undecenoic acid capped Yb(3+)/Er(3+)-doped NaYF4 nanoparticles and pentaerythritol tetrakis(3-mercaptopropionate) (PETMP) as tetrathiol monomer is reported. This synthetic strategy for nanocomposite gels is quite different from works where usually the preformed gels are mixed with the nanoparticles. Developing nanocomposites by surface modification of capping ligands would allow tuning and controlling of the separation of the nanoparticles inside the gel network. The hydrogel nanocomposites prepared by thiol-ene click reaction show strong enhancement in luminescence intensity compared to 10-undecenoic acid-capped Yb(3+)/Er(3+)-doped NaYF4 nanoparticles through the upconversion process (under 980 nm laser excitation). The hydrogel nanocomposites display strong swelling characteristics in water resulting in porous structures. Interestingly, the resulting nanocomposite gels act as templates for the synthesis of dendrimer-like Au nanostructures when HAuCl4 is reduced in the presence of the nanocomposite gels. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Lennusadam = Seaplane Harbour / Andrus Kõresaar

Index Scriptorium Estoniae

Kõresaar, Andrus, 1975-

2013-01-01

Tallinna Lennusadama vesilennukite angaaride rekonstrueerimisest, Eesti Meremuuseumi uue ekspositsiooni kujundusest. Autorid: Andrus Kõresaar, Olga Batuhtina, Raivo Kotov, Margit Argus, Margit Aule, Indrek Mikk (KOKO Arhitektid). Insener Karl Õiger. Arhitektuuriajaloolase Mart Kalmu ning arhitektuurikriitiku ja ESLi aastapreemiate žürii liikme Triin Ojari arvamused

Kui oluliseks isikuandmete kaitsmist kooli oludes peate ja millest seda tehes lähtute? / Harri Kõo, Ene Tannberg, Kalle Niinas, Maria Tiro...[jt.

Index Scriptorium Estoniae

2008-01-01

Küsimusele vastavad Tabasalu Ühisgümnaasiumi direktor Harri Kõo, Tartu Miina Härma Gümnaasiumi direktor Ene Tannberg, Jakob Westholmi Gümnaasiumi direktor Kalle Niinas, Jüri Gümnaasiumi direktor Maria Tiro ja Viimsi Keskkooli direktor Leelo Tiisvelt

Tallinna Teletorn = Tallinn Television Tower

Index Scriptorium Estoniae

2015-01-01

Rekonstrueeritud Tallinna Teletorn Kloostrimetsa tee 58a, valminud 2012. Eesti kultuurkapitali aastapreemia 2012. Arhitekt David Basiladze. Rekonstrueerimise projekti arhitektid Raivo Kotov, Andrus Kõresaar, Indrek Mikk, Margit Aule, Jaanus Männik, Lea Laidra, Karis Kahr (KOKO Arhitektid). Sisearhitektid Liis Lindvere, Raili Paling, Margit Argus (KOKO Arhitektid). Konstruktor Neoprojekt

(E-2-((4R,5R-5-((Benzyloxymethyl-2,2-dimethyl-1,3-dioxolan-4-ylbut-2-ene-1,4-diol

Directory of Open Access Journals (Sweden)

Carlos R. Carreras

2010-04-01

Full Text Available The synthesis of (E-2-((4R,5R-5-((benzyloxymethyl-2,2-dimethyl-1,3-dioxolan-4-ylbut-2-ene-1,4-diol by a one-step reduction of the appropriate 2-substituted butenolide is reported. Product characterization was carried out by IR, 1H NMR, 13C NMR, MS, elemental analysis and optical rotation.

Novel Anti-Biofouling Soft Contact Lens: l-Cysteine Conjugated Amphiphilic Conetworks via RAFT and Thiol-Ene Click Chemistry.

Science.gov (United States)

Zhang, Chengfeng; Liu, Ziyuan; Wang, Haiye; Feng, Xiaofeng; He, Chunju

2017-07-01

A unique l-cysteine conjugated antifouling amphiphilic conetwork (APCN) is synthesized through end-crosslinking of well-defined triblock copolymers poly(allyl methacrylate)-b-poly(ethylene glycol)-b-poly(allyl methacrylate) via a combination of reversible addition-fragmentation chain transfer (RAFT) polymerization and thiol-ene "click" chemistry. The synthesized poly(ethylene glycol) macro-RAFT agent initiates the polymerization of allyl methacrylate in a controlled manner. The vinyl pendant groups of the precursor partially conjugate with l-cysteine and the rest fully crosslink with mercaptopropyl-containing siloxane via thiol-ene click chemistry under UV irradiation into APCNs, which show distinguished properties, that is, excellent biocompatibility, more than 39.6% water content, 101 barrers oxygen permeability, optimized mechanical properties, and more than 93% visible light transmittance. What's more, the resultant APCNs exhibit eminent resistance to protein adsorption, where the bovine serum albumin and lysozyme adsorption are decreased to 12 and 21 µg cm -2 , respectively. The outstanding properties of APCNs depend on the RAFT controlled method, which precisely designs the hydrophilic/hydrophobic segments and eventually greatly improves the crosslinking efficiency and homogeneity. Meantime, the l-cysteine monolayer can effectively reduce the surface hydrophobicity and prevent protein adsorption, which exhibits the viability for antifouling surface over and under ophthalmic devices, suggesting a promising soft contact lens. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Muusika : Tiit Kuusik 90. Wagneri ooperid EMA-le. Eva Märtsoni laulukonkurss Tallinnas. USA tantsijad tõlgendavad Pärti. Sumera luigelaul salves. WGT Baltimaade kultuurifestivalil. Paul Mägi tagasi Malmös. / Martti Raide

Index Scriptorium Estoniae

Raide, Martti

2001-01-01

11.IX möödus 90 aastat Tiit Kuusiku sünnist. Eesti Richard Wagneri Ühingu vahendusel anti EMA raamatukogule üle Wagneri ooperite 32 CD-le salvestatud kogumik. 25.IX ئ 2.X toimus EMA-s saksa lauluprofessori Eva Märtsoni meistrikursus. 1.ئ10.X külastab Eestit Ohio osariigist pärit moderntantsutrupp Antaeus Dance. ERSO ja Paavo Järvi salvestavad Lepo Sumera viimaseid heliteoseid. Weekend Guitar Trio on ringreisil Soomes. Paul Mägi kutsuti Malmo Sümfooniaorkestrit juhatama. Põltsamaa linnavalitsuses arutati 2002. a. oktoobris toimuva Põhja- ja Baltimaade puhkpillilaagri korraldamisega seonduvat.

Joint statement of the President, Speaker of the Riigikogu and Prime Minister of the Republic of Estonia / Toomas Hendrik Ilves, Ene Ergma, Andrus Ansip

Index Scriptorium Estoniae

Ilves, Toomas Hendrik, 1953-

2008-01-01

President Toomas Hendrik Ilvese, Riigikogu spiikri Ene Ergma ja peaminister Andrus Ansipi ühisavaldus Teise maailmasõja lõpu 62. aastapäeva puhul 8. mail 2007, milles kinnitatakse, et hoolimata Teise maailmasõja ajaloolistest tõlgendustest on kõik Eestis elavad inimesed vabad ning jagavad ühist tulevikku

Eesti Meremuuseumi hoone Lennusadamas = Estonian Maritime Museum in the Tallinn Seaplane Harbour

Index Scriptorium Estoniae

2015-01-01

Eesti Meremuuseumi rekonstrueeritud vesilennukite angaarid Tallinnas Vesilennuki 6, valminud 2012. Eesti kultuurkapitali aastapreemia 2012. Arhitektid Raivo Kotov, Andrus Kõresaar, Indrek Mikk, Margit Aule, Tõnis Savi, Lea Laidra, Karis Kahr, Jelena Altmäe, Jaanus Männik (KOKO Arhitektid). Sisearhitektid Margit Argus, Andrus Kõresaar, Olga Batuhtina (KOKO Arhitektid). Raudbetoonkonstruktsioonide renoveerimisprojekt Karl Õiger, Heiki Onton (Tallinna Tehnikaülikool). Uued konstruktsioonid Neoprojekt

Facile preparation of organic-silica hybrid monolith for capillary hydrophilic liquid chromatography based on "thiol-ene" click chemistry.

Science.gov (United States)

Chen, Ming-Luan; Zhang, Jun; Zhang, Zheng; Yuan, Bi-Feng; Yu, Qiong-Wei; Feng, Yu-Qi

2013-04-05

In this work, a one-step approach to facile preparation of organic-inorganic hybrid monoliths was successfully developed. After vinyl-end organic monomers and azobisisobutyronitrile (AIBN) were mixed with hydrolyzed tetramethoxysilane (TMOS) and 3-mercaptopropyltrimethoxysilane (MPTMS), the homogeneous mixture was introduced into a fused-silica capillary for simultaneous polycondensation and "thiol-ene" click reaction to form the organic-silica hybrid monoliths. By employing this strategy, two types of organic-silica hybrid monoliths with positively charged quaternary ammonium and amide groups were prepared, respectively. The functional groups were successfully introduced onto the monoliths during the sol-gel process with "thiol-ene" click reaction, which was demonstrated by ζ-potential assessment, energy dispersive X-ray spectroscopy (EDX), and Fourier transform infrared (FT-IR) spectroscopy. The porous structure of the prepared monolithic columns was examined by scanning electron microscopy (SEM), nitrogen adsorption-desorption measurement, and mercury intrusion porosimetry. These results indicate the prepared organic-silica hybrid monoliths possess homogeneous column bed, large specific surface area, good mechanical stability, and excellent permeability. The prepared monolithic columns were then applied for anion-exchange/hydrophilic interaction liquid chromatography. Different types of analytes, including benzoic acids, inorganic ions, nucleosides, and nucleotides, were well separated with high column efficiency around 80,000-130,000 plates/m. Taken together, we present a facile and universal strategy to prepare organic-silica hybrid monoliths with a variety of organic monomers using one-step approach. Copyright © 2013 Elsevier B.V. All rights reserved.

Crystal and Molecular Structure Studies of Ethyl 4-(4-Hydroxyphenyl-6-(6-methoxy-2-naphthyl-2-oxocyclohex-3-ene-1-carboxylate and Ethyl 4-(3-Bromophenyl-6-(6-methoxy-2-naphthyl-2-oxocyclohex-3-ene-1-carboxylate

Directory of Open Access Journals (Sweden)

Badiadka Narayana

2012-08-01

Full Text Available The crystal and molecular structures of the title compounds, ethyl 4-(4-hydroxyphenyl-6-(6-methoxy-2-naphthyl-2-oxocyclohex-3-ene-1-carboxylate (I and ethyl 4-(3-bromophenyl-6-(6-methoxy-2-naphthyl-2-oxocyclohex-3-ene-1-carboxylate (II, are reported and confirmed by single crystal X-ray diffraction data. Compound (I, C26H24O5, crystallizes from a methanol solution in the monoclinic C2/c space group with eight molecules in the unit cell. The unit cell parameters are: a = 25.4114(5 Å, b = 8.47440(10 Å, c = 20.6921(4 Å, β = 108.328(2° and V = 4229.92(13 Å3. Disorder is observed throughout the entire molecule with an occupancy ratio 0.690(2:0.310(2. Compound (II, C26H23O4Br, crystallizes from an ethyl acetate solution in the monoclinic P21/c spacegroup with four molecules in the unit cell. The unit cell parameters are a = 17.8991(9 Å, b = 11.4369(6 Å, c = 10.8507(5 Å, β = 92.428(4° and V = 2219.25(19 Å3. Disorder is observed in the cyclohexenone ring and the carboxylate group with an occupancy ratio 0.830(6:0.170(6. Weak O–H...O (I or C–H...O (II intermolecular interactions are observed which influence crystal packing stability. These chalcone derivative types of molecules are important in their ability to act as activated unsaturated systems in conjugated addition reactions of carbanions in the presence of basic catalysts which exhibit a multitude of biological activities.

Synthesis and Transformations of di-endo-3-Aminobicyclo-[2.2.2]oct-5-ene-2-carboxylic Acid Derivatives

Directory of Open Access Journals (Sweden)

Márta Palkó

2011-09-01

Full Text Available all-endo-3-amino-5-hydroxybicyclo[2.2.2]octane-2-carboxylic acid (13 and all-endo-5-amino-6-(hydroxymethylbicyclo[2.2.2]octan-2-ol (10 were prepared via dihydro-1,3-oxazine or g-lactone intermediates by the stereoselective functionalization of an N-protected derivative of endo-3-aminobicyclo[2.2.2]oct-5-ene-2-carboxylic acid (2. Ring closure of b-amino ester 4 resulted in tricyclic pyrimidinones 15 and 16. The structures, stereochemistry and relative configurations of the synthesized compounds were determined by IR and NMR.

Vabariigi presidendi, riigikogu esimehe ja peaministri ühisavaldus 8. mail 2007 / Toomas Hendrik Ilves, Ene Ergma, Andrus Ansip

Index Scriptorium Estoniae

Ilves, Toomas Hendrik, 1953-

2007-01-01

President Toomas Hendrik Ilvese, Riigikogu spiikri Ene Ergma ja peaminister Andrus Ansipi avaldus Teise maailmasõja lõpu 62. aastapäeva puhul. Ilmunud ka: Severnoje Poberežje 9. mai 2007, lk. 2; Eesti Elu 11. mai 2007, lk. 2, pealk.: Riigijuhtide ühisavaldus Teise maailmasõja mälestuspäeval, ingl. k. lk. 11, pealk.: Joint statement May 8, 2007; ingl. k. Vaba Eesti Sõna 10. mai 2007, lk. 12, pealk.: Joint statement of the President, Speaker of the Parliament and Prime Minister of the Republic of Estonia

Iron complexes of tetramine ligands catalyse allylic hydroxyamination via a nitroso–ene mechanism

Directory of Open Access Journals (Sweden)

David Porter

2015-12-01

Full Text Available Iron(II complexes of the tetradentate amines tris(2-pyridylmethylamine (TPA and N,N′-bis(2-pyridylmethyl-N,N′-dimethylethane-1,2-diamine (BPMEN are established catalysts of C–O bond formation, oxidising hydrocarbon substrates via hydroxylation, epoxidation and dihydroxylation pathways. Herein we report the capacity of these catalysts to promote C–N bond formation, via allylic amination of alkenes. The combination of N-Boc-hydroxylamine with either FeTPA (1 mol % or FeBPMEN (10 mol % converts cyclohexene to the allylic hydroxylamine (tert-butyl cyclohex-2-en-1-yl(hydroxycarbamate in moderate yields. Spectroscopic studies and trapping experiments suggest the reaction proceeds via a nitroso–ene mechanism, with involvement of a free N-Boc-nitroso intermediate. Asymmetric induction is not observed using the chiral tetramine ligand (+-(2R,2′R-1,1′-bis(2-pyridylmethyl-2,2′-bipyrrolidine ((R,R′-PDP.

Development of a thiol-ene based screening platform for enzyme immobilization demonstrated using horseradish peroxidase

DEFF Research Database (Denmark)

Hoffmann, Christian; Pinelo, Manuel; Woodley, John

2017-01-01

Efficient immobilization of enzymes on support surfaces requires an exact match between the surface chemistry and the specific enzyme. A successful match would normally be identified through time consuming screening of conventional resins in multiple experiments testing individual immobilization...... strategies. In this study we present a versatile strategy that largely expands the number of possible surface functionalities for enzyme immobilization in a single, generic platform. The combination of many individual surface chemistries and thus immobilization methods in one modular system permits faster...... functionalization by thiol-ene chemistry (TEC) resulted in the formation of a functional monolayer in each well, whereas, polymer surface grafts were introduced through surface chain transfer free radical polymerization (SCT-FRP). Enzyme immobilization on the modified surfaces was evaluated by using a rhodamine...

Facile synthesis of linear-dendritic cholesteryl-poly(epsilon-caprolactone)-b-(L-lysine)(G2) by thiol-ene and azide-alkyne "click" reactions

DEFF Research Database (Denmark)

Javakhishvili, Irakli; Binder, W.H.; Tanner, S.

2010-01-01

The construction of a linear-dendritic block copolymer consisting of terminal cholesteryl moiety, poly(epsilon-caprolactone), and a second generation L-lysine dendron has been accomplished by the combination of copper(I) catalyzed azide-alkyne and UV-triggered thiol-ene "click" reactions. Ring-op...... and thiocholesterol. Near to quantitative functionalization of the intermediate and final products has been attained as confirmed by NMR spectroscopy and MALDI-TOF spectrometry....

Photolithographic fabrication of solid–liquid core waveguides by thiol-ene chemistry

International Nuclear Information System (INIS)

Sagar, Kaushal; Gopalakrishnan, Nimi; Christiansen, Mads Brøkner; Kristensen, Anders; Ndoni, Sokol

2011-01-01

In this work we demonstrate an efficient and cleanroom compatible method for the fabrication of solid–liquid core waveguides based on nanoporous polymers. We have used thiol-ene photo-grafting to tune and pattern the hydrophilicity of an originally hydrophobic nanoporous 1, 2-polybutadiene. The generated refractive index contrast between the patterned water-filled volume and the surrounding empty hydrophobic porous polymer allows for light confinement within the water-filled volume—the solid–liquid core. The presented fabrication process is simple and fast. It allows a high degree of flexibility on the type and grade of surface chemistry imparted to the large nanoporous area depending upon the application. The fabrication does not need demanding chemical reaction conditions. Thus, it can be readily used on a standard silicon lithography bench. The propagation loss values reported in this work are comparable with literature values for state-of-the-art liquid-core waveguide devices. The demonstrated waveguide function added to the nanoporous polymer with a very high internal surface area makes the system interesting for many applications in different areas, such as diagnostics and bio-chemical sensing

Thermal decomposition of lanthanides (III) and yttrium (III) solid complexes from ethyl ene diamine tetraacetic acid

International Nuclear Information System (INIS)

Mercadante, A.

1991-01-01

Solid state compounds of lanthanides (III) and yttrium derived from ethyl ene diamine tetraacetic acid were prepared from respective basic carbonates, that were neutralized with EDTA stoichiometry quantities. Complexometry with EDTA, thermogravimetry (TG), differential thermal analysis (DTA) and X-ray diffraction have been used in the study of these compounds. The results of complexometry with EDTA as well as TG and DTA curves bed to the stoichiometry of these compounds the following general formula is obeyed: H[Ln(EDTA]. n H 2 O. X-ray powder patterns of these compounds permitted to establish two isomorphous series. The DTA ant TG curves allowed us to study the dehydration process, the thermal stability and thermal decomposition of these compounds. (C.G.C.)

Modifying surface resistivity and liquid moisture management property of keratin fibers through thiol-ene click reactions.

Science.gov (United States)

Yu, Dan; Cai, Jackie Y; Church, Jeffrey S; Wang, Lijing

2014-01-22

This paper reports on a new method for improving the antistatic and liquid moisture management properties of keratinous materials. The method involves the generation of thiols by controlled reduction of cystine disulfide bonds in keratin with tris(2-carboxyethyl) phosphine hydrochloride and subsequent grafting of hydrophilic groups onto the reduced keratin by reaction with an acrylate sulfonate or acrylamide sulfonate through thiol-ene click chemistry. The modified substrates were characterized with Raman spectroscopy and scanning electron microscopy and evaluated for their performance changes in liquid moisture management, surface resistivity, and wet burst strength. The results have revealed that the thiol-acrylate reaction is more efficient than the thiol-acrylamide reaction, and the keratinous substrate modified with an acrylate sulfonate salt exhibits significantly improved antistatic and liquid moisture management properties.

Raamatututvustus

Index Scriptorium Estoniae

2007-01-01

2006. a. Tallinnas Eesti Kunstimuuseumilt ilmunud Heini Paasi koostatud album-kataloogist "Amandus Adamson 1855-1929" (kujundaja Tiit Jürna, toimetajad: Mai Levin, Anu Allas). 2007. a. Tallinnas ilmunud näitusekataloogist "Ado Lill" (koostaja ja essee autor Harry Liivrand, kujundaja Tiit Jürna, fotod: Liina Siib, Jaan Künnap, Peeter Sirge, Stanislav Stepashko). Ajakirja kunst.ee (peatoimetaja Heie Treier) 2007. a. numbrist 2, ajakirja Cheese (peatoimetaja Tiit Lepp) 2007. a. numbrist 23.

14. VII avati Rael Arteli galerii fotoruumis...

Index Scriptorium Estoniae

2004-01-01

Anu Allase kureeritud näitus "Juhitud reisid/Guided Tours". Näitusel osalevad Liisi Peets, Katrin Tees, Piret Räni, Anu Vahtra, Daisy Lappard, Tiit Sokk (Ulvi Tiit & Marili Sokk), Raivo Hool ja Rataplan

Investors ponder private bridge for Narva-Ivangorod / Gary Peach, Joel Alas

Index Scriptorium Estoniae

Peach, Gary

2007-01-01

Tiit Vähi ja Andrei Katkovi lubadusest ehitada Narva jõele uus sild, kuna valitsused silla ehitamises niipea kokkuleppele ei jõua. Tiit Vähi, Edgar Savisaare, Raivo Vare ja Igor Gräzini arvamused

Linnar Viik kaotas lahingu IKEA omanikule / Airi Ilisson

Index Scriptorium Estoniae

Ilisson, Airi, 1980-

2005-01-01

Linnar Viik valiti 50 kõige mõjukama eurooplase hulka ning kandideeris Euroopa aasta ärijuhi tiitlile, tiitli pälvis IKEA asutaja Ingvar Kamprad. Kõige edukama eurooplase tiitli sai Türgi peaminister Recep Tayyip Erdogan

Suveteater kui bränd ja trend. Teatrisuvi 2006 / Jaak Allik

Index Scriptorium Estoniae

Allik, Jaak, 1946-

2006-01-01

Suvelavastustest: "Vargamäe kuningriik" A. H. Tammsaare "Tõe ja õiguse" I ja V osa ainetel Endla teatri ja Rakvere Teatri ühisprojekt Vargamäel (lavastaja Jaanus Rohumaa), Urmas Lennuk "Koidula" Emajõe Suveteatris (lavastaja Andres Dvinjaninov), "Romeo & Julia" Eesti Nuku- ja Noorsooteatris (lavastaja Andres Dvinjaninov), Andrus Kivirähk "Sürrealistid" Viinistus (lavastaja Hendrik Toompere jun), Mart Kivastik "Kits viiuli ja õngega" Viinistus (lavastaja Raimo Pass), Jaan Kross "Vastutuulelaev" Naissaarel (lavastaja Aleksander Eelmaa), Alfred Jarry "Kuningas Ubu" Teater NO99 Haapsalu Kiltsi lennuvälja angaarides (lavastajad Ene-Liis Semper ja Tiit Ojasoo), Mart Laar ja Lauri Vahtre "Minust jäävad ainult laulud" Munamäe nõlval (lavastaja Tõnu Lensment), A. H. Tammsaare - H. Rekkor "Tõde:ei:õigus" Vargamäe aidas (lavastaja Helen Rekkor), Rudolf Reiman "Painaja" Leigo Järveteatris (lavastajad Jaan Tooming ja Anne Türnpu), Brian Friel "Kodukoht" Eesti Draamateater Keila-Joa mõisas (lavastaja Priit Pedajas), A. Tshehhov - P. Tammearu "Kolm klaasikest kirsiviina" Ugala tiigi kaldal (lavastaja Peeter Tammearu), Jaan Tätte "Kaev" Tallinna Linnateatri siseõues (lavastaja Indrek Sammul), Jim Ashilev "Nagu poisid vihma käes" Endla teater Muuseumiaidas (lavastaja Andres Noormets)

Postsotsialismist vaatemängulinna = From Post-Socialism to the City of the Spectacle / Andres Kurg

Index Scriptorium Estoniae

Kurg, Andres, 1975-

2007-01-01

Büroo Alver Trummal Arhitektid töödest, Andres Alverist ja Tiit Trummalist. Ärihoonest Tallinnas Rävala pst. 4. Autorid: Andres Alver, Tiit Trummal, Tarmo Laht, Indrek Rünkla, Ulla Mets, Sven Koppel. Konstruktor Eido Uustalu (Eesti Projekt). Projekt 2001, valmis 2006. City Plazast Tallinnas Tartu mnt. 2. Autorid: A. Alver, T. Trummal, T. Laht, I. Rünkla, Martin Melioranski, U. Mets. Konstruktor: Tiit Masso, Pike Projekt. Sisekujundus (fuajeed, restoran): Pille Lausmäe. Projekt 2001, valmis 2004. Lõige, põhiplaan, 3 värv. välis- ja 5 sisevaadet

Pyriculins A and B, two monosubstituted hex-4-ene-2,3-diols and other phytotoxic metabolites produced by Pyricularia grisea isolated from buffelgrass (Cenchrus ciliaris).

Science.gov (United States)

Masi, Marco; Meyer, Susan; Górecki, Marcin; Mandoli, Alessandro; Di Bari, Lorenzo; Pescitelli, Gennaro; Cimmino, Alessio; Cristofaro, Massimo; Clement, Suzette; Evidente, Antonio

2017-11-01

Pyricularia grisea has been identified as a foliar pathogen on buffelgrass (Cenchrus ciliaris) in North America and was studied as a potential source of phytotoxins for buffelgrass control. Two monosubstituted hex-4-ene-2,3-diols, named pyriculins A and B, were isolated from its culture filtrate organic extract together with (10S,11S)-(-)-epipyriculol, trans-3,4-dihydro-3,4,8-trihydroxy-1(2H)-napthalenone, and (4S)-(+)-isosclerone. Pyriculins A and B were characterized by spectroscopic (essentially nuclear magnetic resonance [NMR], High-resolution electrospray ionization mass spectrometry [HRESIMS]) and chemical methods such as (4E)-1-(4-hydroxy-1,3-dihydroisobenzofuran-1-yl)hex-4-ene-2,3-diols. The relative and absolute configuration of these compounds was determined by a combination of spectroscopic (NMR, electronic circular dichroism [ECD]) and computational tools. When bioassayed in a buffelgrass coleoptile and radicle elongation test, (10S,11S)-(-)-epipyriculol proved to be the most toxic compound. Seed germination was much reduced and slowed with respect to the control and radicles failed to elongate. All five compounds delayed germination, but only (10S,11S)-(-)-epipyriculol was able to prevent radicle development of buffelgrass seedlings. It had no effect on coleoptile elongation, while the other four compounds caused significantly increased coleoptile development relative to the control. © 2017 Wiley Periodicals, Inc.

Alternativa nomer 99 / Boris Tuch

Index Scriptorium Estoniae

Tuch, Boris, 1946-

2008-01-01

Teatri NO99 ajaloost ja lavastustest - Tiit Ojasoo "Nafta", "Kuningas Ubu", "GEP", "Seitse samuraid","Perikles"ja Sebastian Hartmani lavastus "Stalker" Andrei Tarkovski filmi põhjal ning Hendrik Toompere "Kommunisti surm". Ka Tiit Ojasoo lavastusest "Julia" Shakespeare'i ainetel Eesti Draamateatris

Альтернатива номер 99 / Борис Тух

Index Scriptorium Estoniae

Тух, Борис, 1946-

2008-01-01

Teatri NO99 ajaloost ja lavastustest - Tiit Ojasoo "Nafta", "Kuningas Ubu", "GEP", "Seitse samuraid","Perikles" ja Sebastian Hartmani lavastus "Stalker" Andrei Tarkovski filmi põhjal ning Hendrik Toompere "Kommunisti surm". Ka Tiit Ojasoo lavastusest "Julia" Shakespeare'i ainetel Eesti Draamateatris

The IS-ENES climate4impact portal: bridging the CMIP5 and CORDEX data to impact users

Science.gov (United States)

Som de Cerff, Wim; Plieger, Maarten; Page, Christian; Tatarinova, Natalia; Hutjes, Ronald; de Jong, Fokke; Bärring, Lars; Sjökvist, Elin; Vega Saldarriaga, Manuel; Santiago Cofiño Gonzalez, Antonio

2015-04-01

The aim of climate4impact (climate4impact.eu) is to enhance the use of Climate Research Data and to enhance the interaction with climate effect/impact communities. The portal is based on 17 impact use cases from 5 different European countries, and is evaluated by a user panel consisting of use case owners. It has been developed within the IS-ENES European project and is currently operated and further developed in the IS ENES2 project. As the climate impact community is very broad, the focus is mainly on the scientific impact community. Climate4impact is connected to the Earth System Grid Federation (ESGF) nodes containing global climate model data (GCM data) from the fifth phase of the Coupled Model Intercomparison Project (CMIP5) and regional climate model data (RCM) data from the Coordinated Regional Climate Downscaling Experiment (CORDEX). This global network of climate model data centers offers services for data description, discovery and download. The climate4impact portal connects to these services using OpenID, and offers a user interface for searching, visualizing and downloading global climate model data and more. A challenging task is to describe the available model data and how it can be used. The portal informs users about possible caveats when using climate model data. All impact use cases are described in the documentation section, using highlighted keywords pointing to detailed information in the glossary. Climate4impact currently has two main objectives. The first one is to work on a web interface which automatically generates a graphical user interface on WPS endpoints. The WPS calculates climate indices and subset data using OpenClimateGIS/icclim on data stored in ESGF data nodes. Data is then transmitted from ESGF nodes over secured OpenDAP and becomes available in a new, per user, secured OpenDAP server. The results can then be visualized again using ADAGUC WMS. Dedicated wizards for processing of climate indices will be developed in close

Politseinik seotud koolitüdruku tapmisega / Janar Filippov, Tarmo Vahter

Index Scriptorium Estoniae

Filippov, Janar, 1976-

2006-01-01

16-aastase koolitüdruku Veronika Dari tapmise ja Riigi Kinnisvara juhi Tiit Ottise ründamise uurimises on toimunud pööre - kurjategijate kaasosaliseks osutus Põhja politseiprefektuuri mõrvarühma juhtivinspektor. Lisa: Kes tellis Tiit Ottise ründamise?

Uurijad : arvatavalt tappis Veronika Dari alaealine narkosõltlasest palgamõrvar / Ulvar Käärt

Index Scriptorium Estoniae

Käärt, Ulvar, 1982-

2006-01-01

Arreteeriti kolm Viktoria Dari mõrvas kahtlustatavat. Mõrv võis olla tellimustöö, kuid väidetavalt oli tegelik sihtmärk Riigi Kinnisvara AS-i juht Tiit Ottis. Vt. samas lühiintervjuud Tiit Ottisega. Lisa: Tütarlaps hukkus kooliteel

Crystal structures of three anhydrous salts of the Lewis base 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU with the ring-substituted benzoic acid analogues 4-aminobenzoic acid, 3,5-dinitrobenzoic acid and 3,5-dinitrosalicylic acid

Directory of Open Access Journals (Sweden)

Graham Smith

2016-03-01

Full Text Available The anhydrous salts of the Lewis base 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU with 4-aminobenzoic acid [1-aza-8-azoniabicyclo[5.4.0]undec-7-ene 4-aminobenzoate, C9H17N2+·C7H6NO2− (I], 3,5-dinitrobenzoic acid [1-aza-8-azoniabicyclo[5.4.0]undec-7-ene 3,5-dinitrobenzoate, C9H17N2+·C7H3N2O6−, (II] and 3,5-dinitrosalicylic acid (DNSA [1-aza-8-azoniabicyclo[5.4.0]undec-7-ene 2-hydroxy-3,5-dinitrobenzoate, C9H17N2+·C7H3N2O7−, (III] have been determined and their hydrogen-bonded structures are described. In both (II and (III, the DBU cations have a common disorder in three of the C atoms of the six-membered ring moieties [site-occupancy factors (SOF = 0.735 (3/0.265 (3 and 0.686 (4/0.314 (4, respectively], while in (III, there is additional rotational disorder in the DNSA anion, giving two sites (SOF = 0.72/0.28, values fixed for the phenol group. In the crystals of (I and (III, the cation–anion pairs are linked through a primary N—H...Ocarboxyl hydrogen bond [2.665 (2 and 2.869 (3 Å, respectively]. In (II, the ion pairs are linked through an asymmetric three-centre R12(4, N—H...O,O′ chelate association. In (I, structure extension is through amine N—H...Ocarboxyl hydrogen bonds between the PABA anions, giving a three-dimensional structure. The crystal structures of (II and (III are very similar, the cation–anion pairs being associated only through weak C—H...O hydrogen bonds, giving in both overall two-dimensional layered structures lying parallel to (001. No π–π ring associations are present in any of the structures.

Enantioselective synthesis of possible diastereomers of heptadeca-1-ene-4,6-diyne-3,8,9,10-tetrol; putative structure of a conjugated diyne natural product isolated from Hydrocotyle leucocephala.

Science.gov (United States)

Prasad, Kavirayani R; Swain, Bandita

2011-04-01

Enantioselective synthesis of possible diastereomers of heptadeca-1-ene-4,6-diyne-3,8,9,10-tetrol, a structure proposed for the natural product isolated from Hydrocotyle leucocephala is accomplished. The reported spectral data of the natural product did not match those of any of the isomers that were synthesized and established that the structure proposed for the natural product is not correct and requires revision.

Kõrge majandusauhind Mart Laarile / Martin Hanson

Index Scriptorium Estoniae

Hanson, Martin, 1984-

2006-01-01

Cato instituut premeeris Mart Laari majandusteadlase Milton Friedmani nimelise auhinnaga ja üle 6 miljoni krooniga. Vt. samas: Mart Laari varasemad autasud; Milton Friedmani auhind anti kätte kolmandat korda. Kommenteerivad: Ivari Padar, Tiit Vähi, Tiit Tammsaar, Linnar Viik ja Andres Lipstok

Tallinn ostab vaestemaja hoone endistelt riigifirmade juhtidelt / Villy Paimets

Index Scriptorium Estoniae

Paimets, Villy, 1972-

2004-01-01

Tallinna linnavalitsus ostab toimetulekuraskustes linlastele üürieluasemete rajamiseks OÜ-lt Rustikal Tuulemaa 6 asuva ühiselamu. OÜ Rustikal omanikud on endised riigi kinnisvara haldajad Tiit Griffel ja Urmas Kivisalu. Vt. samas intervjuud OÜ Rustikal juhatuse liikme Tiit Griffeliga. Lisa: Endiste riigifirmajuhtidega seotud hulk firmasid

Kolme ekspeaministri talk-show Ida-Viru ärieliidi ees / Erik Gamzejev

Index Scriptorium Estoniae

Gamzejev, Erik, 1967-

2008-01-01

Ilmunud ka: Severnoje Poberezhje : Subbota 16. veebr., lk. 1. Majandusminister Juhan Parts, IRL esimees ja parlamendiliige Mart Laar ja Sillamäe sadama ning Silmeti suuraktsionär Tiit Vähi kohtusid Ida-Virumaa suurettevõtete juhtidega. Lisa: Mart Laar; Tiit Vähi; Juhan Parts

Stereochemistry of 16a-Hydroxyfriedelin and 3-Oxo-16-methylfriedel-16-ene Established by 2D NMR Spectroscopy

Directory of Open Access Journals (Sweden)

Vagner Fernandes Knupp

2009-02-01

Full Text Available Friedelin (1, 3b-friedelinol (2, 28-hydroxyfriedelin (3, 16a-hydroxyfriedelin (4, 30-hydroxyfriedelin (5 and 16a,28-dihydroxyfriedelin (6 were isolated through fractionation of the hexane extract obtained from branches of Salacia elliptica. After a week in CDCl3 solution, 16a-hydroxyfriedelin (4 reacted turning into 3-oxo-16-methylfriedel-16-ene (7. This is the first report of a dehydration followed by a Nametkin rearrangement of a pentacyclic triterpene in CDCl3 solution occurring in the NMR tube. These seven pentacyclic triterpenes was identified through NMR spectroscopy and the stereochemistry of compound 4 and 7 was established by 2D NMR (NOESY spectroscopy and mass spectrometry (GC-MS. It is also the first time that all the 13C-NMR and 2D NMR spectral data are reported for compounds 4 and 7.

Copy & paste / Andreas Trossek

Index Scriptorium Estoniae

Trossek, Andreas, 1980-

2007-01-01

Rühmituse Tiit Sokk (Marili Sokk, Ulvi Tiit) ruumiinstallatsioon "Alter Egode Agentuur" Tallinna Linnagaleriis 27. I-4. III ja Kristin Kalamehe näitus "Intensiivravi", mis oli 24. I-4. II vaadatav läbi Hobusepea galerii akende ja 5. II ka galeriis. Väljavõtteid pressitekstidest

Cyclohex-1-ene carboxylic acids: synthesis and biological evaluation of novel inhibitors of human 5 alpha reductase.

Science.gov (United States)

Baston, Eckhard; Salem, Ola I A; Hartmann, Rolf W

2003-03-01

In search of novel nonsteroidal mimics of steroidal inhibitors of 5 alpha reductase, 4-(2-phenylethyl)cyclohex-1-ene carboxylic acids 1-5 were synthesized with different substituents in para position of the phenyl ring (1: N, N-diisopropylcarbamoyl, 2: phenyl, 3: phenoxy, 4: benzoyl, and 5: benzyl). The principal synthetic approach for the desired compounds consisted of a Wittig olefination between 1, 4-dioxaspiro [4.5]-decane-8-carbaldehyde (4g and the appropriate phosphonium salts. The compounds were tested for inhibition of human 5 alpha reductase isozymes 1 and 2 using DU 145 cells and preparations from prostatic tissue, respectively. They turned out to be good inhibitors of the prostatic isozyme 2 with compound 1 being the most potent one (IC(50) = 760 nM). Isozyme 1 was only slightly inhibited. It is concluded that the novel structures are appropriate for being further optimized, aiming at the development of a novel drug for the treatment of benign prostatic hyperplasia.

Endla teater 2006 : aasta omadramaturgiat / Luule Epner

Index Scriptorium Estoniae

Epner, Luule, 1953-

2007-01-01

Andrus Kivirähki "Rehepapp" (lav. Priit Pedajas), Liisu Krassi/ Sandra Sillaotsa "Sõbrapäev" (juh. Enn Keerd), August Kitzbergi "Kauka jumal" (lav. Andres Noormets), Silvi Väljali/Kiti Põllu "Jussikese seitse sõpra" (lav. Piret Rauk), A. H. Tammsaare /Urmas Lennuki "Vargamäe kuningriik" (lav. Jaanus Rohumaa), Jim Ashilevi "Nagu poisid vihma käes" (lav. Andres Noormets), Jaan Kruusvalli "Võikõllane üü" (lav. Enn Keerd), Friedebert Tuglase/Tiit Palu "Väike Illimar" (lav. Tiit Palu), Asrtid Reinla "Koduabiline" (lav. Tiit Palu), Jaan Kaplinski "Liblikas ja peegel" (lav. Madis Kalmet), Eva Koffi "Sabaga täht" (lav. Andres Noormets). Kasut. kirjandus lk. 39

Na vosmom jezhegodnom konkurse titula "lutshsheje betonnoje strojenije" udostoilsja most Puurmani / Eva Kiisler

Index Scriptorium Estoniae

Kiisler, Eva

2008-01-01

Konkursi "Aasta betoonehitis 2007" võitis Puurmani kaarsild Tallinn-Tartu-Luhamaa maanteel, konstruktorid Siim ja Juhan Idnurm, ehitaja AS Merko Ehitus, projektijuht Tiit Joosti, betooni tarnija AS Rudus Eesti. AS Merko Ehitus kvaliteedijuht Enno Põder ja Tiit Joosti ehituse käigust. Puurmani liiklussõlmest. Aadu Kana ja Toomas Vainola konkursist

"ArtGenda" erobert Hamburg / Anders Härm

Index Scriptorium Estoniae

Härm, Anders, 1977-

2002-01-01

7.-23. VI Hamburgis Läänemere-äärsete linnade noorte kunstnike biennaal "ArtGenda". Eestist osalevad projektides rühmitus Valie Export Society (Killu Sukmit, Mari Laanemets, Kadi Estland), rühmitus Tiit Sokk (Ulvi Tiit, Marili Sokk), ESTO TV (Ken & Tolk, Andres Maimik), Elin Kard, Aivar Tõnso, Kiwa

Haapsalu Piiskopilinnuse uuendamine / Lilian Hansar

Index Scriptorium Estoniae

Hansar, Lilian, 1949-

2015-01-01

Sihtasutus Haapsalu ja Läänemaa Muuseumid koostöös Eesti Arhitektide Liiduga korraldasid arhitektuurivõistluse, et valida välja parim arhitektuurne ja kasutusfunktsioonile sobiv lahendus Haapsalu piiskopilinnuse pealinnuse rekonstrueerimiseks kaasaegseks muuseumikompleksiks. Esimese koha sai töö märgusõnaga "Salaaed" (Margit Aule, Margit Argus, Siim Karro ja Mart Kadarik arhitektuuribüroost KAOS Arhitektid). Teise koha sai töö märgusõnaga "Helevalge" (Mari Hunt, Kalle Komissorov, Silver Liiberg, Kadri Klementi, Aet Ader ja Karin Tõugu arhitektuuribüroost b210). Kolmanda koha sai töö märgusõnaga "Ristvõlv" (Indrek Laos ja Andreas Kivi arhitektuuribüroost Flux projekt)

Superhydrophobic and Slippery Lubricant-Infused Flexible Transparent Nanocellulose Films by Photoinduced Thiol-Ene Functionalization.

Science.gov (United States)

Guo, Jiaqi; Fang, Wenwen; Welle, Alexander; Feng, Wenqian; Filpponen, Ilari; Rojas, Orlando J; Levkin, Pavel A

2016-12-14

Films comprising nanofibrillated cellulose (NFC) are suitable substrates for flexible devices in analytical, sensor, diagnostic, and display technologies. However, some major challenges in such developments include their high moisture sensitivity and the complexity of current methods available for functionalization and patterning. In this work, we present a facile process for tailoring the surface wettability and functionality of NFC films by a fast and versatile approach. First, the NFC films were coated with a layer of reactive nanoporous silicone nanofilament by polycondensation of trichlorovinylsilane (TCVS). The TCVS afforded reactive vinyl groups, thereby enabling simple UV-induced functionalization of NFC films with various thiol-containing molecules via the photo "click" thiol-ene reaction. Modification with perfluoroalkyl thiols resulted in robust superhydrophobic surfaces, which could then be further transformed into transparent slippery lubricant-infused NFC films that displayed repellency against both aqueous and organic liquids with surface tensions as low as 18 mN·m -1 . Finally, transparent and flexible NFC films incorporated hydrophilic micropatterns by modification with OH, NH 2 , or COOH surface groups, enabling space-resolved superhydrophobic-hydrophilic domains. Flexibility, transparency, patternability, and perfect superhydrophobicity of the produced nanocellulose substrates warrants their application in biosensing, display protection, and biomedical and diagnostics devices.

Kultuurajakirjanduslik initsiatiiv Tartust / Rael Artel

Index Scriptorium Estoniae

Artel, Rael, 1980-

2006-01-01

Ajakirjast "Cheese", 2006. a. uue kujundusega ilmunud ajakirja 15. numbrist (peatoimetaja Tiit Lepp, toimetajad Ahto Külvet ja Jaan Sokk, kujundaja Tiit Lepp) ning Tartu Linnavalitsuse kultuuriosakonna poolt Tartus 2005. ja 2006. aastal väljaantud artiklikogumikust "Ideeturg : esseid ja artikleid kultuuriturundusest. 1-3" (toimetajad Esta Tatrik ja Andreas W, kujundaja Vägev Vähk)

Inspection and monitoring plan, contaminated groundwater seeps 317/319/ENE Area, Argonne National Laboratory

International Nuclear Information System (INIS)

1996-01-01

During the course of completing the Resource Conservation and Recovery Act (RCRA) Facility Investigation (RFI) in the 317/319/East-Northeast (ENE) Area of Argonne National Laboratory-East (ANL-E), groundwater was discovered moving to the surface through a series of groundwater seeps. The seeps are located in a ravine approximately 600 ft south of the ANL-E fence line in Waterfall Glen Forest Preserve. Samples of the seep water were collected and analyzed for selected parameters. Two of the five seeps sampled were found to contain detectable levels of organic contaminants. Three chemical species were identified: chloroform (14--25 microg/L), carbon tetrachloride (56--340 microg/L), and tetrachloroethylene (3--6 microg/L). The other seeps did not contain detectable levels of volatile organics. The nature of the contaminants in the seeps will also be monitored on a regular basis. Samples of surface water flowing through the bottom of the ravine and groundwater emanating from the seeps will be collected and analyzed for chemical and radioactive constituents. The results of the routine sampling will be compared with the concentrations used in the risk assessment. If the concentrations exceed those used in the risk assessment, the risk calculations will be revised by using the higher numbers. This revised analysis will determine if additional actions are warranted

Kuni 20. VIII on Tallinnas vastavatud kultuuritehases Polymer ennast sisse seadnud...Rael Artel Gallery

Index Scriptorium Estoniae

2004-01-01

Näha saab G-Labi (Arturas Bumsteinas, Laura Garbstiene, Leedu) heliinstallatsiooni "Mirrors and Copulations", Kiwa heliteost "Hlör U Fang Axaxaxas mlö", Anu Allase kureeritud väljapanekut "Juhitud reisid/Guided Tours" (osalevad Liisi Peets, Katrin Tees, Piret Räni, Anu Vahtra, Daisy Lappard, rühmitus Tiit Sokk: Ulvi Tiit & Marili Sokk, Raivo Hool, Rataplan), Grace Schwindti (London) videot "Desire"

Afgaane ei saa aidata vaid läbi soomuki akna / Toomas Sildam

Index Scriptorium Estoniae

Sildam, Toomas, 1961-

2005-01-01

Põhja-Afganistani Mazar-e-Sharifi linnas brittide juhtimisel tegutseva provintsi ülesehitusmeeskonna koosseisu kuulub kaks Eesti üksust - vaatlusmeeskond ja Eesti kaitseväe demineerijate rühm. Kaitseministeeriumi plaani kohaselt saadetakse 2006. aastal Lõuna-Afganistani ligi 120 Eesti sõdurit. Kaart. Vt. samas lühiintervjuud kapten Tiit Paljakuga: Kapten Tiit Paljak: me ei tee afgaanide eest kõike ära

15 aastat ehitamist Eestis / Ado Eigi

Index Scriptorium Estoniae

Eigi, Ado, 1938-2008

2006-01-01

Eesti arhitektuur viimase 15 aasta jooksul. Loetletud parimad arhitektuuriteosed: Mardi talu Saaremaal (Jüri Okas, 2002); Transgroup Investi büroohoone Tallinnas (Urmas Lõoke, 2005); Ferrumi kaubanduskeskuse hoone Kuressaares (Andres Alver, Tiit Trummal, Tarmo Laht, Indrek Rünkla, Ulla Mets, 2002); KUMU kunstimuuseum (Pekka Vapaavuori, 2005); Lootsi 3a korterelamu Tallinnas (Hanno Grossschmidt, 2005); City Plaza Tallinnas (Andres Alver, Tiit Trummal, Martin Melioranski, Indrek Rünkla, 2005); Okupatsioonide muuseum (Indrek Peil, Siiri Vallner, 2003); Pärnu kesklinna koolide võimla (Katrin Koov, Kaire Nõmm, Heidi Urb, Siiri Vallner, 2005); De la Gardie kaubamaja Tallinnas (Andres Alver, Tiit Trummal, Tarmo Laht, 2000); Lasnamäe spordihoone Tallinnas (Siiri Vallner, Hanno Grossschmidt, Tomomi Hayashi, 2003); TTP büroohoone Tallinnas (Meelis Press, 2005)

Cinamon kui uus nähtus kinomaastikul / Dagmar Reinolt

Index Scriptorium Estoniae

Reinolt, Dagmar

2009-01-01

Cinamoni kinoketi perspektiividest Eestis. Cinamoni nõukogu esimees Peeter Rebane, Tallinnfilmi juht Margit Vremmert ja kinoketi Forum Cinemas levijuht Lauri Kaare esitavad oma vaateid kinode ja filmilevi kohta Eestis

Krokodill sõi karu mett / Eero Kangor

Index Scriptorium Estoniae

Kangor, Eero, 1982-

2007-01-01

Tartu Ülikooli, Tartu Kõrgema Kunstikooli ja Tartu Kunstikooli õpilaste näitusest Tartu Kunstimuuseumis, kuraator Liisa Kaljula. Pikemalt Ronald Baumanni, Helen Kikkase, Margit Lõhmuse maalidest, Jana Huuli skulptuurist

Moeteater ühendab mitmest rahvusest Tallinna lapsi / Merike Teder

Index Scriptorium Estoniae

Teder, Merike

2005-01-01

Tallinnas Suur-Ameerika noortekeskuses avatud moeteatri Max Moda tegevusest. Rajaja ja tegevjuht Maksim Hlebnikov, kunstiline juht Margit Leerimaa. Moeteatri esimene etendus toimub 11. märtsil Rahvusraamatukogu suures konverentsisaalis

Teise korruse filmid Kanuti Gildi saalis : Zoova, Säde ja Piibemann

Index Scriptorium Estoniae

2008-01-01

Kanuti Gildi saali teisel korrusel filmiprogrammi "Teise korruse filmid" linastuvad täna Jasper Zoova filmid "Parallel Euro" ja "Armastuse barrikaadidel", Margit Säde "Failing Files", Taavi Piibemanni "Peategelased"

Estimación del impacto económico de los museos a través de las nuevas tecnologías de la información: el caso del museo Ene.Térmica

Directory of Open Access Journals (Sweden)

Vicente COLL-SERRANO

Full Text Available Cada vez es más necesario poner de relieve el potencial de la cultura como motor del desarrollo económico y su capacidad para generar ingresos y crear empleo. Por este motivo, en este trabajo se evalúa el impacto económico del museo Ene.Térmica sobre el territorio en el que se ubica, Ponferrada (Comunidad de Castilla y León, España. Para lograr este objetivo, la estimación de los distintos tipos de efectos necesarios para determinar el impacto de las actividades económicas vinculas a la existencia de Ene.Térmica se realiza, en base a la metodología de las Tablas Input-Output, mediante la herramienta Impactrimonio, una aplicación implementada sobre una plataforma web. Los resultados obtenidos indican que entre las actividades del museo y los flujos de demanda desplegados por el efecto arrastre de los visitantes se generó, entre los años 2011 y 2012, un incremento de la producción de más de 15 millones de euros, un incremento de las rentas de la población de casi 10 millones de euros y un aumento de la ocupación de 327 empleos.

Tallinna Teletorn = Tallinn's Television Tower / Andrus Kõresaar

Index Scriptorium Estoniae

Kõresaar, Andrus, 1975-

2013-01-01

Renoveeritud Teletornist. Ekspositsiooni autorid: Andrus Kõresaar, Liis Lindvere, Raili Paling, sisearhitektid: Liis Lindvere, Raili Paling, Margit Argus (KOKO Arhitektid). Arhitekti ja ESLi aastapreemiate žürii liikme Raivo Puusepa arvamus

Geeniandmepankade eetilised, juriidilised ja sotsiaalsed aspektid / Kristi Lõuk

Index Scriptorium Estoniae

Lõuk, Kristi

2004-01-01

Geeniandmepankadest ja ajakirja Trames erinumbrist "Human Genetic databases: ethical, legal and social issues" (vol. 8, no 1-2, 2004), mille külalistoimetajaks on TÜ eetikakeskuse juhataja prof Margit Sutrop

MTÜ Setomaa Turism eestvedaja Ülle Pärnoja: kõige olulisem on suure pildi nägemise oskus / intervjueerinud Annela Laaneots

Index Scriptorium Estoniae

Pärnoja, Ülle

2015-01-01

Intervjuu Ülle Pärnojaga, kelle juhitav MTÜ Setomaa Turism sai Seto Külävüü kostipäeva ehk kodukohvikute päeva eest Setomaal Põlvamaa aasta turismi-/turundusteo 2014 tiitli, Ülle Pärnoja sai tiitli Põlvamaa 2014. aasta turismitöötaja. Kostipäeva korraldamisest ja turunduskommunikatsioonist, Setomaa turismikommunikatsioonist. Obinitsa Setomaal on soome-ugri kultuuripealinn 2015, toimuvatest üritustest

Väikestest ja suurtest võitjatest : 62. Cannes'i rahvusvahelise filmifestivali auhindadest / Jaak Lõhmus

Index Scriptorium Estoniae

Lõhmus, Jaak, 1955-

2009-01-01

62. Cannes'i festivali peaauhinna võitis Michael Haneke filmiga "Valge pael" ("Das weiße Band"), grand prix' sai prantslase Jacques Audiard'i "Prohvet" ("Un prophete"), parima meestäitja tiitli võitis Christoph Waltz rolli eest Quentin Tarantino filmis "Vääritud tõprad", parima naisosatäitja tiitli võitis Charlotte Gainsbourg rolli eest Lars von Trieri filmis "Antikristus". Lisatud auhinnasaajate nimekiri

Libavaida sugrusida uherles ja vurles kehus* / Maria Ulfsak-Šeripova

Index Scriptorium Estoniae

Ulfsak-Šeripova, Maria, 1981-

2010-01-01

Tim Burtoni filmist "Alice Imedemaal" (USA 2010), stsenarist Linda Woolverton, peaosades Mia Wasikowska, Johnny Depp. Lisaks kaks arvamust "3D poolt", autor Mann Jõgeda ja "3D vastu", autor Margit Tõnson

Elamuslik arhitektuur : Salto AB Sõmeru keskusehoone = Salto AB experiential architecture and the Sõmeru Community Centre / Carl-Dag Lige

Index Scriptorium Estoniae

Lige, Carl-Dag

2011-01-01

Arhitektuuribüroo Salto loomingust, mille fookus on kasutaja teenimisel ning meeleheal. 2010. a. valminud Sõmeru keskusehoonest. Arhitektid Maarja Kask, Ralf Lõoke, Karli Luik, kaasautorid Kristiina Arusoo, Margit Argus. Projekt: 2004

Villa Pirital : turvaliselt lõppenud arhitektuurieksperiment / Alvin Järving

Index Scriptorium Estoniae

Järving, Alvin, 1986-

2013-01-01

Masinlikuna detailitäpsest ja tehnoloogilisest eramust Pirital. Arhitekt Raul Vaiksoo (Raul Vaiksoo Arhitektuuribüroo). Sisearhitektid Raul Vaiksoo ja Margit Teikari (Stuudio TEMA). Ehitusaeg: 2011-2013. Elamispind: 374 m²

Tallinna Sakala keskuse projekt kütab kirgi / Aivo Vahemets

Index Scriptorium Estoniae

Vahemets, Aivo

2004-01-01

Raine Karbi projekteeritud hoone ümberehituse projekt telliti Inglismaalt büroost Burrow&Cave, OÜ Arhitektuuriagentuuri projektist loobuti. Eesti Arhitektide Liidu esinaise Margit Mutso ja arhitektuurinõukogu esimehe Peep Aaviksoo kommentaar

Theoretical study on the photolysis mechanism of 2,3-diazabicyclo[2.2.2]oct-2-ene.

Science.gov (United States)

Chen, Hui; Li, Shuhua

2005-09-28

A CASPT2/CASSCF study has been carried out to investigate the mechanism of the photolysis of 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) under direct and triplet-sensitized irradiation. By exploring the detailed potential energy surfaces including intermediates, transition states, conical intersections, and singlet/triplet crossing points, for the first excited singlet (S(1)) and the low-lying triplet states (T(1), T(2), and T(3)), we provide satisfactory explanations of many experimental findings associated with the photophysical and photochemical processes of DBO. A key finding of this work is the existence of a significantly twisted S(1) minimum, which can satisfactorily explain the envelope of the broad emission band of DBO. It is demonstrated that the S(1) (n-pi*) intermediate can decay to the T(1) (n-pi*) state by undergoing intersystem crossing (rather inefficient) to the T(2) (pi-pi*) state followed by internal conversion to the T(1) state. The high fluorescence yield and the extraordinarily long lifetime of the singlet excited DBO are due to the presence of relatively high barriers, both for intersystem crossing and for C-N cleavage. The short lifetime of the triplet DBO is caused by fast radiationless decay to the ground state.

Kohtumine 8645 kolleegiga / Siiri Vallner, Indrek Peil

Index Scriptorium Estoniae

Vallner, Siiri, 1972-

2008-01-01

29. 06-3. 07 2008 Torinos toimunud Maailma Arhitektide Liidu (UIA) 23. kongressist teemal edastatav arhitektuur (Transmitting Architecture). Eesti osa balti ühisekspositsioonis koosnes Maja aastafilmide (autor Margit Mutso) näitamisest

Thiol-ene immobilisation of carbohydrates onto glass slides as a simple alternative to gold-thiol monolayers, amines or lipid binding.

Science.gov (United States)

Biggs, Caroline I; Edmondson, Steve; Gibson, Matthew I

2015-01-01

Carbohydrate arrays are a vital tool in studying infection, probing the mechanisms of bacterial, viral and toxin adhesion and the development of new treatments, by mimicking the structure of the glycocalyx. Current methods rely on the formation of monolayers of carbohydrates that have been chemically modified with a linker to enable interaction with a functionalised surface. This includes amines, biotin, lipids or thiols. Thiol-addition to gold to form self-assembled monolayers is perhaps the simplest method for immobilisation as thiolated glycans are readily accessible from reducing carbohydrates in a single step, but are limited to gold surfaces. Here we have developed a quick and versatile methodology which enables the use of thiolated carbohydrates to be immobilised as monolayers directly onto acrylate-functional glass slides via a 'thiol-ene'/Michael-type reaction. By combining the ease of thiol chemistry with glass slides, which are compatible with microarray scanners this offers a cost effective, but also useful method to assemble arrays.

Investigation of the fluorescence quenching of 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) by certain substituted uracils

Energy Technology Data Exchange (ETDEWEB)

Anbazhagan, V. [School of Chemistry, Bharathidasan University, Tiruchirappalli 620024, Tamil Nadu (India); Renganathan, R. [School of Chemistry, Bharathidasan University, Tiruchirappalli 620024, Tamil Nadu (India)], E-mail: rrengas@yahoo.com

2009-04-15

The fluorescence quenching of 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) by a series of uracils has been studied in water and acetonitrile solvents using steady-state and time-resolved fluorescence techniques. The steady-state fluorescence quenching technique has been performed in three different pHs (i.e. 4, 8 and 12). The bimolecular quenching rate constant (k{sub q}) increases with increase in pH of uracils. In acidic pH, a pure hydrogen atom abstraction is proposed as the quenching mechanism. This is supported by a pronounced solvent deuterium isotope effect. Electron transfer from the anionic form of uracil to the excited state of DBO is proposed as a mechanism for quenching in basic pH on the basis of highly exergonic thermodynamics obtained from the Rehm-Weller equation. The variation of k{sub q} is explained on the basis of the electronic effect of substitution in uracils as well.

Investigation of the fluorescence quenching of 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) by certain substituted uracils

International Nuclear Information System (INIS)

Anbazhagan, V.; Renganathan, R.

2009-01-01

The fluorescence quenching of 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) by a series of uracils has been studied in water and acetonitrile solvents using steady-state and time-resolved fluorescence techniques. The steady-state fluorescence quenching technique has been performed in three different pHs (i.e. 4, 8 and 12). The bimolecular quenching rate constant (k q ) increases with increase in pH of uracils. In acidic pH, a pure hydrogen atom abstraction is proposed as the quenching mechanism. This is supported by a pronounced solvent deuterium isotope effect. Electron transfer from the anionic form of uracil to the excited state of DBO is proposed as a mechanism for quenching in basic pH on the basis of highly exergonic thermodynamics obtained from the Rehm-Weller equation. The variation of k q is explained on the basis of the electronic effect of substitution in uracils as well

The photochemical reaction of 1,1-dicyano-3-phenylbut-1-ene. Simultaneous occurrence of p-methane and di-p-methane rearrangements

Directory of Open Access Journals (Sweden)

Silva Francisco A. da

1999-01-01

Full Text Available The direct photolysis of 1,1-dicyano-3-phenylbut-1-ene (3-MDCN was investigated at room temperature in solvents of different polarities (hexane, dichloromethane and acetonitrile. Cyclopropanes arising from both the di-pi-methane and pi-methane (1,2-H migration processes were obtained as photoproducts. The structures of the products were elucidated by ¹H-NMR, GC/MS, IR and chromatography. Relative quantum yield determination and GC analysis of sequential irradiations gave evidence that: i no secondary reactions occur, even at high conversions; ii the di-pi-methane rearrangement is significantly more affected by the solvent variation than the pi-methane reaction. Photosensitization with acetophenone or acetone did not yield any observable products. The existence of the simultaneous mechanisms and the observed effects were considered as evidence of a possible differentiation between localized and delocalized excitation on the excited state surface.

Tartu Keskkonnahariduse Keskuse Loodusmaja = Nature School of Tartu Environmental Education Centre

Index Scriptorium Estoniae

2015-01-01

Tartu Keskkonnahariduse Keskuse Loodusmaja Lille tänav 10, valminud 2013. Arhitektuurivõistlus 2010. Arhitektid Martin Kinks, Risto Parve, Kai Süda, Margit Valma (Karisma Arhitktid), Diana Taalfeld (NU Arhitektuur). Sisearhitekt Tõnis Kalve

Olean-18-ene triterpenoids from Celastraceae species inhibit HIV replication targeting NF-kB and Sp1 dependent transcription.

Science.gov (United States)

Osorio, Alex A; Muñóz, Alejandro; Torres-Romero, David; Bedoya, Luis M; Perestelo, Nayra R; Jiménez, Ignacio A; Alcamí, José; Bazzocchi, Isabel L

2012-06-01

In the present study we report the isolation of nine new olean-18-ene triterpenes (1-9), along with three known ones (10-12), from Cassine xylocarpa and Maytenus jelskii. Their stereostructures have been elucidated on the basis of spectroscopic analysis, including 1D and 2D NMR techniques (COSY, ROESY, HSQC and HMBC), and spectrometric methods. The natural compounds and derivatives 13-15 have been tested for their potential as inhibitors of human immunodeficiency virus type 1 replication. Five compounds from this series displayed potent antiviral activity with IC(50)s in the micromolar range (1, 3, 4, 7 and 8) being 1 and 8 the most active compounds. The target of these compounds was different from antiretroviral drugs currently licensed as they act as inhibitors of enhancer-dependent transcription. The structure-activity relationships were established based on the regiosubstitution and oxidation degree of the triterpene scaffold, revealing that these aspects were able to modulate the selectivity and intensity of HIV inhibition. Copyright © 2012 Elsevier Masson SAS. All rights reserved.

[Miks uurib politsei Ottise ja ehitusfirma Facio vahelist tüli?] / Tarmo Vahter

Index Scriptorium Estoniae

Vahter, Tarmo, 1970-

2006-01-01

Seoses koolitüdruku Veronika Dari tapmisega, kus tegelikuks sihtmärgiks oli Riigi Kinnisvara juht Tiit Ottis, tunneb politsei huvi kolme riigi poolt tellitud ehitustöö vastu. Need on keskkriminaalpolitsei peakorteri ning Tallinna Pae ja Mustamäe gümnaasiumi renoveerimine. Uurimise käigust. Vt. samas: Katkeid Riigi Kinnisvara ja Facio Ehituse juhtide kirjavahetusest Pae ja Mustamäe gümnaasiumide remondi teemal. Tiit Ottis: "Mehed, te rikastute alusetult!"

Allen Ginsberg kirjutab Ameerikast

Index Scriptorium Estoniae

2003-01-01

Arvustus: Ginsberg, Allen. Ameerika : valik luuletusi 1947-1996 / koostanud ja toimetanud Hasso Krull ; inglise keelest tõlkinud Contra, Lauri Kitsnik, Hasso Krull, Andres Langemets, Margit Langemets, Jürgen Rooste, Tõnu Õnnepalu. Tallinn : Perioodika, 2003

Informeeritud nõusolek ja muutuvad eetilised raamistikud bioeetikas / Kristi Lõuk

Index Scriptorium Estoniae

Lõuk, Kristi

2011-01-01

Ülevaade 4.-6. novembril 2010 toimunud informeeritud nõusoleku teemalisel konverentsil kõneldust. Esinejad: Tom L. Beauchamp, Margit Sutrop, Ruth Faden, Theda Rehbock, Kjetil Rommetveit, Toivo Maimets, Ruth Chadwick, Ants Nõmper, Jan Helge Solbakk

1,4a-Dimethyl-6-methyl-ene-5-(5,5,6,6-tetra-cyano-2-methyl-cyclo-hex-2-enylmeth-yl)deca-hydro-naphthalene-1-carboxylic acid: a trans-communic acid derivative.

Science.gov (United States)

Rejouani, Nezha; Auhmani, Aziz; Ait Itto, My Youssef; Benharref, Ahmed; Daran, Jean-Claude

2008-01-18

In the search for cancer chemopreventive agents, we have studied the Diels-Alder reaction of trans-communic acid with tetra-cyano-ethyl-ene in the presence of SiO(2) as catalyst. The title cycloadduct, C(26)H(30)N(4)O(2), was obtained in 75% yield. The mol-ecules are arranged in pairs through O-H⋯O hydrogen bonds, forming an R(2) (2)(8) ring motif. Both the fused cyclohexyl rings adopt a chair conformation, whereas the nonfused ring adopts a half-chair conformation.

Erivajadustega laste koolitee toob erilisi takistusi / Anu Mõistlik

Index Scriptorium Estoniae

Mõistlik, Anu

2003-01-01

Puudega laste vanemate probleemidest oma laste koolitamisel-kasvatamisel. Lisa: Arvamus [Tartu Descartes℗þi Lütseumi direktori Jaan Reinsoni ja Noorteklubi Händikäpp juhatuse esimehe Margit Rosentali seisukohad liikumispuudega laste kooli valiku võimalustest

Meie nominendid

Index Scriptorium Estoniae

2005-01-01

Areeni kultuuripreemia žürii tutvustab nominente: kunstikoguja Jaan Manitski, fotograaf Peeter Laurits, lavastaja Ain Mäeots, maalikunstnik Peeter Mudist, fotograaf Tiit Lepp, graafik Kristjan Mändmaa, metallikunstnik Ivar Kaasik, arhitekt Arne Maasik, PÖFFi korraldaja Tiina Lokk, tantsumanager Priit Raud, teatrijuht, lavastaja Peeter Jalakas, režissöör Mark Soosaar, lavastaja Tiit Ojasoo, kirjanikud Jaan Kaplinski, Hando Runnel, ajaloolane Magnus Ilmjärv, muusik Aivar Tõnso, disainer Lazer, helilooja Rein Fuks, hip hop ansambel Toe Tag

Eesti filmid tõid Lätist auhindu

Index Scriptorium Estoniae

2004-01-01

Arsenalsi festivali Balti võistlusprogrammis osalenud Sulev Keeduse "Somnambuul" võitis parima Balti mängufilmi tiitli ja 2000 USA dollarit. Jaak Kilmi-Rene Reinumäe "Sigade revolutsioon" sai Vienna Laboratory eripreemia. Laila Pakalnina kolme Balti riigi ja Soome ühistööna valminud "Buss" võitis nii parima Balti filmi kui ka parima Balti dokumentaalfilmi tiitli. Festivali grand prix' sai Kanada režissööri Guy Maddini film "The Saddest Music in the World"

Kinolevi filme tutvustab Tiit Tuumalu / Tiit Tuumalu

Index Scriptorium Estoniae

Tuumalu, Tiit, 1971-

2008-01-01

Põnevusfilm "Eela orus" ("In the Valley of Elah") : režissöör Paul Haggis : Ameerika Ühendriigid 2007 ja Wong Kar-Wai mängufilm "Minu mustikakarva ööd" ("My Blueberry Nights") : Hiina - Hongkong - Prantsusmaa 2007

Eesti laste suvi

Index Scriptorium Estoniae

2010-01-01

Laste suvisest koolivaheajast räägivad Eesti omavalitsuse ametnikud ja sotsiaaltöötajad: Kaasi Almers, Inna Kask, Aasa Saarna, Ülle Rajasalu, Merle Leopard, Aime Koger, Margit Pajo, Pilleriin Aalde, Andres Julle ja Tiiu Kuus

Uusi maalijaid Tartust

Index Scriptorium Estoniae

2007-01-01

Tartu Ülikooli maalikunsti eriala lõpetajate Veiko Klemmeri, Helen Kikkase ja Margit Lõhmuse tööde näitus Tartu Kunstimuuseumis ning Ronald Baumanni, Nadezhda Tshernobai ja Jäppe Johansoni näitus Tartu Kunstimajas

The synthesis of weak acidic type hybrid monolith via thiol-ene click chemistry and its application in hydrophilic interaction chromatography.

Science.gov (United States)

Zeng, Jiao; Liu, Shengquan; Wang, Menglin; Yao, Shouzhuo; Chen, Yingzhuang

2017-05-01

In this work, a porous structure and good permeability monolithic column was polymerized in UV transparent fused-silica capillaries via photo-initiated thiol-ene click polymerization of 2,4,6,8-tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane (TMTVS), pentaerythritol tetra(3-mercaptopropionate)(PETMP), itaconic acid, respectively, in the presence of porogenic solvents (tetrahydrofuranand methanol) and an initiator (2,2-dimethoxy-2-phenylacetophenone) (DMPA) within 30 min. The physical properties of this monolith were characterized by scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and nitrogen adsorption/desorption measurements. For an overall evaluation of the monolith in chromatographic application, separations of polycyclic aromatic hydrocarbons (PAHs), phenols, amides and bases were carried out. The column efficiency of this monolith could be as high as 112 560 N/m. It also possesses a potential application in fabrication of monoliths with high efficiency for c-LC. In addition, the resulting monolithic column demonstrated the potential use in analysis of environment waters. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Mustjõe asumi planeerimiskonkurss = The Competition for Planning the Mustjõe Community / Veljo Kaasik

Index Scriptorium Estoniae

Kaasik, Veljo

2002-01-01

Tallinna Mustjõe asumi korterelamu ja puhkeala ruumilise planeerimise võistluse eeltingimustest, premeeritud töödest. I preemia - Villem Tomiste, Mihkel Tüür, Ott Kadarik, II - Margit Mutso (koos kaastöölistega), III - Veronika Valk

Mis oli ja mida ei olnud : lisandusi kahele kirjutisele / Tiiu Erelt

Index Scriptorium Estoniae

Erelt, Tiiu, 1942-

2008-01-01

Lisandusi artiklitele: Koppel, Margit-Mariann. Mahalaskmine pärast surma //Eesti Ekspress, 23. aug. 2007, mis käsitleb Elmar Muugi saatust, ning: Raag, Raimo. Valter Tauli elust ja keelelisest tegevusest // Keel ja Kirjandus, (2007/Nov), nr. 11

LIFT 11 kutsub kogemist väärt kohtadesse / Silvia Pärmann

Index Scriptorium Estoniae

Pärmann, Silvia

2011-01-01

Installatsioonide festivalist LIFT 11 Tallinnas, kuraator Margit Aule. Margus Tamme ja Argo Peeveri installatsioonist "Face It", Raul Kalvo skulptuurist "Uurijad", Raul Kelleri installatsioonist "Tütarlaps kloaagis", Aet Aderi, Kaarel Künnapi, Grete Soosalu, Flo Kasearu, Andra Aaloe kunstiprojektist "O"

Hotell Arensburg : Lossi 15, Kuressaare / Liina Jänes

Index Scriptorium Estoniae

Jänes, Liina, 1977-

2008-01-01

Arensburg Boutique Hotel & Spa. Arhitektid: Margit Kärner, Raivo Kotov, Lea Laidra. Sisearhitektid: Liisi Murula, Raivo Kotov, Raili Paling. Peatöövõtja: EBC Ehitus AS. I korruse plaan, 2 värv. välisvaadet, 3 sisevaadet

Pärnu uue kunsti muuseumis on näitus "Kümme aastat moodsat kunsti Pärnus varakapitalistliku Eesti tingimustes"

Index Scriptorium Estoniae

2003-01-01

Osalevad Peeter Allik, Mila Balti, Chintis, Margit Joonas, Toomas Kuusing, Hannes Paldrok, Meeland Sepp, Inge Ting, Taje Tross, Andrus Joonas, Bille Tuul, Mariliis Beilmann, Olle Meyer, Sorge, rühmitus Non Grata, Asta Isak, Marianne Männi, Ville-Karel Viirelaid

Comment on "An unexpected formation of the novel 7-oxa-2-azabicyclo[2.2.1]hept-5-ene skeleton during the reaction of furfurylamine with maleimides and their bioprospection using a zebrafish embryo model" by C. E. Puerto Galvis and V. V. Kouznetsov, Org. Biomol. Chem., 2013, 11, 407.

Science.gov (United States)

Zubkov, F I; Kvyatkovskaya, E A; Nikitina, E V; Amoyaw, P N-A; Kouznetsov, V V; Lazarenko, V A; Khrustalev, V N

2017-08-02

It has been proved that the reaction between furfuryl amines and N-R-maleimides leads to the formation of aza-Michael addition products - 3-(furylmethylamino)-N-R-pyrrolidine-2,5-diones, instead of 7-oxa-2-azabicyclo[2.2.1]hept-5-enes, as this journal reported previously.

DVD. Margit Tõnson soovitab : "Libahundi needus" / Margit Tõnson

Index Scriptorium Estoniae

Tõnson, Margit, 1978-

2006-01-01

ETV levitab DVD-l mängufilmi "Libahundi needus" : stsenaristid Margus Kasterpalu, Ilmar Raag ja Rainer Sarnet : režissöör Rainer Sarnet : osades Katariina Lauk, Rene Reinumägi : Shop of Dreams - Eesti Televisioon 2005

Pärnu mudaravila restaureerimine ja juurdeehitus = Restoration and extension of the Pärnu mud baths / Tarmo Teedumäe, Paco Ulman, Tüüne-Kristin Vaikla

Index Scriptorium Estoniae

Teedumäe, Tarmo, 1970-

2015-01-01

Restaureeritud ja uue juurdeehitusega Pärnu mudaravila Ranna puiestee 1, valminud 2014. Arhitektid Tarmo Teedumäe, Paco Ulman, Inga Raukas, Arhitektuuriagentuur, Allianss Arhitektid. Sisearhitektid Tüüne-Kristin Vaikla, Urmo Vaikla, Tuuli Trei, Margit Teikari (Vaikla Stuudio). 2014. aasta Kultuurkapitali Arhitektuuripreemia kandidaat

Eduka ettevõtte aluseks saab olla vaid looming / Ave Schmidt

Index Scriptorium Estoniae

Schmidt, Ave

2010-01-01

Tänapäeva ettevõttele tagavad konkurentsieelise inspiratsioon ja originaalsed ideed. Arvamust avaldavad Tallinna kohviku Nop asutaja Margit Aasmäe, Estonian Airi arendusdirektor Gunnar Mägi, Tallinna Kaubamaja müügi- ja turundusdirektor Enn Parel ja Balteco disainijuht Aivar Habakukk

Eesti interjöörileiud

Index Scriptorium Estoniae

2007-01-01

Tutvustatakse Ameerika moodi Mack-restorani Tartu maanteel - sisearhitekt Hillar Mänd koostöös restorani juhi Paul Lepikuga ja Arensburgi hotelli Kuressaares - arhitekt Margit Kärner koostöös Raivo Kotovi ja Lea Laidraga, sisearhitektid Liis Murula ja Raili Paling

"Klass : elu pärast" võitis peaauhinna

Index Scriptorium Estoniae

2009-01-01

Genfis toimunud rahvusvahelisel festivalil Cinema Tous Ecrans sai telesarjade võistlusprogrammis peaauhinna ETV sari "Klass : elu pärast", produtsent Gerda Kordemets, stsenarist Margit Keerdo, režissöörid Ilmar Raag, Gerda Kordemets, Liina Paakspuu, Priit Valkna ja Marek Miil

"Klass : elu pärast" võitis rahvusvahelisel festivalil peaauhinna

Index Scriptorium Estoniae

2009-01-01

Genfis toimunud rahvusvahelisel festivalil Cinema Tous Ecrans sai telesarjade võistlusprogrammis peaauhinna ETV sari "Klass : elu pärast", produtsent Gerda Kordemets, stsenarist Margit Keerdo, režissöörid Ilmar Raag, Gerda Kordemets, Liina Paakspuu, Priit Valkna ja Marek Miil

Kas Mustjõe kasvab linnaks? / Tõnu Laigu

Index Scriptorium Estoniae

Laigu, Tõnu

2002-01-01

Tallinna Mustjõe asumi korterelamu ja puhkeala ruumilise planeerimise ideevõistlusest. Preemiad: I - Ott Kadarik, Villem Tomiste, Mihkel Tüür (büroo Kosmos), II - Margit Mutso (büroo Eek & Mutso), III - Veronika Valk, ostupreemia - Sverre Laanjärv, Ivar Lubjak

Arutlus autorist ja ruumist / Meelis Oidsalu

Index Scriptorium Estoniae

Oidsalu, Meelis, 1978-

2010-01-01

Dokumentaalfilmi sarjas "Eesti lood" linastunud filmidest: "Beebilõust" - Saaremaa poeedist ja hiphop-muusikust Andrus Elbingust, režissöör ja stsenarist Margit Lillak ning "Pastacas" - Soomes elavast Eesti kunstnikust ja muusikust Ramo Tedrest, režissöör Rein Kotov

Poly(allyl methacrylate) functionalized hydroxyapatite nanocrystals via the combination of surface-initiated RAFT polymerization and thiol-ene protocol: a potential anticancer drug nanocarrier.

Science.gov (United States)

Bach, Long Giang; Islam, Md Rafiqul; Vo, Thanh-Sang; Kim, Se-Kwon; Lim, Kwon Taek

2013-03-15

Hydroxyapatite nanocrystals (HAP NCs) were encapsulated by poly(allyl methacrylate) (PolyAMA) employing controlled surface-initiated reversible addition-fragmentation chain transfer (SI-RAFT) polymerization of allyl methacrylate to afford HAP-PolyAMA nanohybrids. The subsequent thiol-ene coupling of nanohybrids with 2-mercaptosuccinic acid resulted HAP-Poly(AMA-COOH) possessing multicarboxyl group. The formation of the nanohybrids was confirmed by FT-IR and EDS analyses. The TGA and FE-SEM investigation were further suggested the grafting of PolyAMA onto HAP NCs. The utility of the HAP-PolyAMA nanohybrid as drug carrier was also explored. The pendant carboxyl groups on the external layers of nanohybrids were conjugated with anticancer drug cisplatin to afford HAP-Poly(AMA-COOH)/Pt complex. The formation of the complex was confirmed by FT-IR, XPS, and FE-SEM. In vitro evaluation of the synthesized complex as nanomedicine revealed its potential chemotherapeutic efficacy against cancer cell lines. Copyright © 2012 Elsevier Inc. All rights reserved.

Uusi kinolevi filme tutvustab Tiit Tuumalu / Tiit Tuumalu

Index Scriptorium Estoniae

Tuumalu, Tiit, 1971-

2008-01-01

Mängufilmid "Lubadused idast" ("Eastern Promises") : režissöör David Cronenberg : Suurbritannia - Kanada - Ameerika Ühendriigid 2007 ja "Ma olen legend" ("I Am Legend") : režissöör Francis Lawrence : Ameerika Ühendriigid 2007

Parimad Eesti modellid / Mari-Liis Helvik

Index Scriptorium Estoniae

Helvik, Mari-Liis

2008-01-01

Kersti Pedanik, Martin Merimaa agentuurist Living Models Agency; Olga Serova, Anett Griffel agentuurist EMA Model Management; Triin Villemsaar, Kertu-Maria Nurk agentuurist Beatrice MASS Modelnet; Karmen Pedaru, Carolina Bergstein agentuurist MJ-Models. Kommenteerivad Evelyn Mikomägi, Katrin Rannaväli, Beatrice, Margit Jõgger

Rene Valner ja Mikk Suursild - lihtsa elu tegelased / Susan Lahesalu

Index Scriptorium Estoniae

Lahesalu, Susan

2007-01-01

Arhitekt Rene Valner ja Mikk Suursild - tandem nimega UNITe - ehitavad ökonoomseid ja ökoloogilisi looduslikest materjalidest maju. Nende koostöös on valminud ka Peipsi ääres Nina külas 3 põhumaja. Ott Kadariku, Margit Mutso ja Kuido Kartau kommentaarid

Sherlock Holmes - esteedist härrasmees või kokaiinisõltlasest rusikakangelane? / Martin Saar

Index Scriptorium Estoniae

Saar, Martin

2010-01-01

Autor poleemiseerib Margit Adorfi kriitilise artikli "Härrast rusikakangelaseks" (Eesti Ekspress: TV Ekspress, 2010, 15.-21. jaan., lk. 3 ) teemadel. Võrdluses on Arthur Conan Doyle' poolt loodud tegelaskuju ja tema tõepärane kujutamine Guy Ritchie filmis "Sherlock Holmes" (Inglise-Austraalia-USA 2009)

Pärnus tähistatakse moodsa kunsti 10. aastapäeva

Index Scriptorium Estoniae

2003-01-01

Ülevaatenäitus Pärnu Uue Kunsti Muuseumis. Näitusel osalevad Peeter Mudist, Mila Balti, Chintis, Margit Joonas, Toomas Kuusing, Hannes Paldrok, Meeland Sepp, Inge Ting, Taje Tross, Andrus Joonas, Bille Tuul, Marliis Beilmann, Olle Meyes, Sorge, Non Grata, Asta Isak, Marianne Männi

Design and fabrication of uniquely shaped thiol-ene microfibers using a two-stage hydrodynamic focusing design.

Science.gov (United States)

Boyd, Darryl A; Shields, Adam R; Howell, Peter B; Ligler, Frances S

2013-08-07

Microfluidic systems have advantages that are just starting to be realized for materials fabrication. In addition to the more common use for fabrication of particles, hydrodynamic focusing has been used to fabricate continuous polymer fibers. We have previously described such a microfluidics system which has the ability to generate fibers with controlled cross-sectional shapes locked in place by in situ photopolymerization. The previous fiber fabrication studies produced relatively simple round or ribbon shapes, demonstrated the use of a variety of polymers, and described the interaction between sheath-core flow-rate ratios used to control the fiber diameter and the impact on possible shapes. These papers documented the fact that no matter what the intended shape, higher flow-rate ratios produced rounder fibers, even in the absence of interfacial tension between the core and sheath fluids. This work describes how to fabricate the next generation of fibers predesigned to have a much more complex geometry, as exemplified by the "double anchor" shape. Critical to production of the pre-specified fibers with complex features was independent control over both the shape and the size of the fabricated microfibers using a two-stage hydrodynamic focusing system. Design and optimization of the channels was performed using finite element simulations and confocal imaging to characterize each of the two stages theoretically and experimentally. The resulting device design was then used to generate thiol-ene fibers with a unique double anchor shape. Finally, proof-of-principle functional experiments demonstrated the ability of the fibers to transport fluids and to interlock laterally.

If It's Part Broke Half Fix It / Virginija Januskeviciute

Index Scriptorium Estoniae

Januskeviciute, Virginija, 1979-

2011-01-01

Kaasaegse Kunsti Eesti Keskuse ja Vilniuse Kaasaegse Kunsti Keskuse korraldatud näitus "If It's Part Broke, Half Fix It" Kaasaegse Kunsti Keskuses Vilniuses 28.01.-13.03.2011, kuraator Margit Säde Lehni. Osalesid kunstnikud Eestist, Leedust, Saksamaalt, Rootsist, Soomest, Inglismaalt ja Hollandist, osalejad loetletud

Janneli Kurvits, Eeva Masso : omanäoline apartmenthotell Marokos

Index Scriptorium Estoniae

2006-01-01

Janneli Kurvitsast (sünd. 1975) ja Eeva Massost (sünd. 1975), nende olulisemad teostatud objektid. J. Kurvitsa ja E. Masso kujundatud hotell (19. saj. lõpp, omanik Margit Naptal) Marokos Fezis. Sisearhitektide kommentaarid. Ill.: joonised, 19 värv. vaadet, värv. foto arhitektidest

Tartu ja Tallinna boheemkond ning lotovõitjad : Valitud palu dokumentaalfilmide sarjast "Eesti lood" / Olev Remsu

Index Scriptorium Estoniae

Remsu, Olev, 1947-

2009-01-01

ETVs näidatud dokumentaalfilmidest sarjas "Eesti lood" - Indrek Kangro film Jaan-Jürgen Klausist "Professionaalne amatöör" (eetris 3. XII 2008), Margit Lillaku film kunstnik Sandra Jõgevast "Ars longa" (eetris 29. X 2008), Eva-Katariina Taimre "Jackpot" lotovõitjatest (eetris 19. XI 2008)

Clinical efficacy of implementing Bio Immune(G)ene MEDicine in the treatment of chronic asthma with the objective of reducing or removing effectively corticosteroid therapy: A novel approach and promising results.

Science.gov (United States)

Glady, Gilbert

2018-06-01

Asthma is one of the diseases that demonstrates a wide range of variation in its clinical expression, in addition to an important heterogeneity in the pathophysiological mechanisms present in each case. The ever-increasing knowledge of the molecular signalling routes and the development of the Bio Immune(G)ene Medicine [BI(G)MED] therapy in line with this knowledge has revealed a whole novel potential set of self-regulation biological molecules, that may be used to promote the physiological immunogenic self-regulation mechanisms and re-establish the homeostatic balance at a genomic, proteomic and cellular level. The aim of the present study is to demonstrate that the sublingual use of a therapeutic protocol based on BI(G)MED regulatory BIMUREGs in the treatment of chronic asthma may reduce or suppress corticosteroid therapy and avoid its harmful side effects which some patients suffer when using this treatment on a long-term basis. The clinical efficacy of BI(G)MED for chronic asthma was evaluated through a multi-centre study carried out in 2016 implementing a 6-month BI(G)MED treatment protocol for Bronchial Asthma. A total of 61 patients from private medical centres and of European countries including Germany, Austria, France, Belgium and Spain participated. The manuscript describes in detail the clinical efficacy of Bio Immune(G)ene regulatory BI(G)MED treatment protocol that allows the reduction or total removal of the corticosteroid dose in patients with chronic asthma. No adverse reactions were observed. The BI(G)MED regulatory therapy brings novel therapeutic possibilities as an effective and safe treatment of chronic asthma. BI(G)MED was demonstrated to significantly reduce asthma severity when parameter compositions were all analysed by categorical outcomes. Therefore, it is considered a good therapeutic alternative for patients who respond poorly to steroids.

Reaction of singlet-excited 2,3-diazabicyclo[2.2.2]oct-2-ene and tert-butoxyl radicals with aryl-substituted benzofuranones.

Science.gov (United States)

Lundgren, Cecilia Vannesjö; Koner, Apurba L; Tinkl, Michael; Pischel, Uwe; Nau, Werner M

2006-03-03

5,7-Di-tert-butyl-3-aryl-3H-benzofuran-2-ones are lactones with potential antioxidant activity, owing to their abstractable benzylic C-H hydrogens. The fluorescence quenching of the azoalkane 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO), an established probe for the hydrogen-donor propensity of chain-breaking antioxidants, was investigated for 16 aryl-substituted benzofuranone derivatives [m,m-(CF3)2, p-CN, m-CN, p-CF3, p-COOCH3, m-CF3, p-Cl, p-F, H, m-CH3, p-CH3, m,p-(CH3)2, p-OCH3, o-CH3, o-CF3, o,m-(CH3)2]. Analysis of the rate data in terms of a linear free energy relationship yielded a reaction constant of rho = +0.35. This implies that n,pi*-excited DBO acts as nucleophilic species. In contrast, hydrogen abstraction of tert-butoxyl radicals from the benzofuranones was accelerated by electron-donating substituents (rho = -0.23), in conformity with the electrophilic character of oxygen-centered alkoxyl radicals. Possible implications for the optimization of the hydrogen-donor propensity of antioxidants through structural variation are discussed.

Eesti rootslased Göteborgi raamatumessil "Bok & Bibliotek" / Aino Siebert, Georg von Stackelberg

Index Scriptorium Estoniae

Siebert, Aino

2007-01-01

rets. rmt.: "Runö" historien om svenskön i Rigabukten" / koostaja Jörgen Hedman. "Estlandsvenskarna som kom till Roslagen" / koostaja Kristina Rosen. "Berättelser från Nargö" - "Naisaare Lood" / koostaja Margit Rosen Norlin. "Kärslätt min by" / koostaja Sven Svärd

Investigations on the fluorescence quenching of 2,3-diazabicyclo[2.2.2]oct-2-ene by certain flavonoids.

Science.gov (United States)

Anbazhagan, V; Kalaiselvan, A; Jaccob, M; Venuvanalingam, P; Renganathan, R

2008-05-29

The fluorescence quenching of 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) by seven flavonoids namely flavone, flavanone, quercetin, rutin, genistein, diadzein and chrysin has been investigated in acetonitrile and dichloromethane solvents. The bimolecular quenching rate constants lie in the range of 0.09-5.75 x 10(9)M(-1)s(-1) and are explained in terms of structure of the flavonoids studied. The reactivity of flavonoids are in the order: quercetin>rutin>genistein>diadzein>chrysin>flavone>flavanone. The quenching rate constants (k(q)) increase with increase in the number of -OH groups. The endergonic thermodynamic values of DeltaG(et) reveal that electron transfer quenching mechanism can be ruled out. Bond dissociation enthalpy calculations reveal that the position of -OH is important. Further in vitro-antioxidant activities of flavonoids were evaluated with rat liver catalase by gel electrophoresis. The deuterium isotope effect thus observed in this work provides evidence for hydrogen abstraction involved in the quenching process of singlet excited DBO by flavonoids. The data suggest the involvement of direct hydrogen atom transfer (radical scavenging) in the fluorescence quenching of DBO. Bond dissociation enthalpy calculation performed at B3LYP/6-31G(p')//B3LYP/3-21G level are in excellent agreement with the above observations and further reveal that the number OH groups and position of them decide the quenching ability of the flavonoids.

Milline on ilus maja? / Sulev Oll

Index Scriptorium Estoniae

Oll, Sulev, 1964-

2008-01-01

Ilusatest majadest ja arhitektuurikonkursside võiduprojektidest. Konkursist "Brick Award". Tallinna sünagoog valiti rahvusvahelise tellisarhitektuuri aastaraamatusse "brick'08" (arhitektid Lembit-Kaur Stöör, Andrus Kõresaar, Tõnis Kimmel arhitektuuribüroost KOKO Arhitektid). Loetletud konkursi "Aasta betoonehitis" võitjad läbi aegade. Kommenteerivad Margit Mutso, Emil Urbel

Thiol-ene and photo-cleavage chemistry for controlled presentation of biomolecules in hydrogels.

Science.gov (United States)

Grim, Joseph C; Marozas, Ian A; Anseth, Kristi S

2015-12-10

photochemical methods have led to important advances in the tissue regeneration community, namely the thiol-ene photo-click reaction for bioconjugation and photocleavage reactions that allow for the removal of protecting groups. Specific examples will be highlighted where these methodologies have been used to engineer hydrogels that control and direct cell function with the aim of inspiring their use in regenerative medicine. Copyright © 2015 Elsevier B.V. All rights reserved.

Festival "Lift 11" toob pealinna pööraseid installatsioone / Kristjan Pihl

Index Scriptorium Estoniae

Pihl, Kristjan

2011-01-01

Linnainstallatsioonide festivali "LIFT11" algselt väljakuulutatud 17 võidutööst teostub 11. 17. augustil avatakse Lasnamäe kanali ääres skulptuur "Uurijad", 23. augustil Russalka juures Margus Tamme ja Argo Peeveri installatsioon "Face it". Ärajäävatest töödest. Tutvustab kuraator Margit Aule

Properties of solid electrolyte interphase formed by prop-1-ene-1,3-sultone on graphite anode of Li-ion batteries

International Nuclear Information System (INIS)

Li, Bin; Xu, Mengqing; Li, Benzhen; Liu, Yanlin; Yang, Liang; Li, Weishan; Hu, Shejun

2013-01-01

Highlights: • SEI formed by PES on NG was characterized with charge/discharge test, SEM, FTIR, and XPS. • NG in PC-based electrolyte can be well protected using PES. • Sulfur-containing species is the main component of the SEI formed by PES. • Preferable reduction of PES results in the formation of protective SEI on NG. -- Abstract: The physical and chemical properties of the solid electrolyte interphase (SEI) formed by prop-1-ene-1,3-sultone (PES) on graphite anode in propylene carbonate (PC) based electrolyte for lithium ion battery were investigated by charge–discharge test, scanning electron spectroscopy with energy dispersive X-ray spectroscopy (SEM–EDS), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). It is found that the charge–discharge performance of the cell LiCoO 2 /natural graphite (NG) using PC-based electrolyte containing 3 wt% PES is superior to that containing 6 wt% propane sultone (PS), an SEI formation additive that has the similar molecular structure to PES but is reduced not as easily as PES. The results from SEM–EDS, FTIR and XPS show that the structure of graphite has been protected and some S-containing species are proven to be components of the SEI, suggesting that the preferable reduction of PES plays an important role in the formation of a protective SEI on NG

Ekspert pakub autotunnelit Mustamäe nõlva sisse / Urmas Seaver

Index Scriptorium Estoniae

Seaver, Urmas, 1973-

2007-01-01

Tallinnasse planeeritavatest eritasandilistest ristmikest ja tunnelitest. Teemaplaneering "Tallinna tänavavõrk ja kergliiklusteed" valmis Tallinna Tehnikaülikooli teedeinstituudis. Kommenteerib liiklusekspert Tiit Metsavahi

Euroopa parlamenti kandideerijad lubavad kaitsta väikese Eesti huve / Matis Song

Index Scriptorium Estoniae

Song, Matis, 1978-

2004-01-01

11. mail 2004 Rapla maavalitsuse haldushoones toimunud kohtumisest Euroopa Parlamendi saadikukandidaatide Tunne Kelami, Tiit Tammsaare, Toomas Savi, Vilja Savisaare, Mart Viisitamme ja Urmas Reinsaluga

Coplas de la tierra en la chilena, lírica tradicional de la Mixteca

Directory of Open Access Journals (Sweden)

Grissel Gómez Estrada

2015-04-01

Full Text Available ABSTRACT: This paper seeks to highlight the traditional lyrical genre known as Chilean, who will sing and dance mostly in the Mexican’s Mixteca region. I will focus on the analysis of the ‘verses of the Earth’, as he calls them Margit Frenk, as I feel that these characterize the genre, based on a corpus of more than a hundred chilean. In addition, these verses will give an account of the culture of the inhabitants of the region. RESUMEN: El presente trabajo pretende dar a conocer el género lírico tradicional conocido como chilena, que se canta y baila sobre todo en la región mexicana de la Mixteca. Me centraré en el análisis de las ‘coplas de la tierra’, como las llama Margit Frenk, pues considero que éstas caracterizan al género, a partir de un corpus de más de cien chilenas. Asimismo, dichas coplas van a dar cuenta de la cultura de los habitantes de la región.

Proshtshalnõi privet Zhaku Derrida / Boris Tuch

Index Scriptorium Estoniae

Tuch, Boris, 1946-

2004-01-01

Postmodernistlikud uuslavastused : F. Kafka "Metamorfoos" Tallinna Linnateatris, lavastaja M. Koldits ja W. Shakespeare'i "Romeo ja Julia" moderniseeritud versioon "Julia", lavastaja Tiit Ojasoo, Eesti Draamateatris

IN0523 (Urs-12-ene-3α,24β-diol) a plant based derivative of boswellic acid protect Cisplatin induced urogenital toxicity.

Science.gov (United States)

Singh, Amarinder; Arvinda, S; Singh, Surjeet; Suri, Jyotsna; Koul, Surinder; Mondhe, Dilip M; Singh, Gurdarshan; Vishwakarma, Ram

2017-03-01

The limiting factor for the use of Cisplatin in the treatment of different type of cancers is its toxicity and more specifically urogenital toxicity. Oxidative stress is a well-known phenomenon associated with Cisplatin toxicity. However, in Cisplatin treated group, abnormal animal behavior, decreased body weight, cellular and sub-cellular changes in the kidney and sperm abnormality were observed. Our investigation revealed that Cisplatin when administered in combination with a natural product derivative (Urs-12-ene-3α,24β-diol, labeled as IN0523) resulted in significant restoration of body weight and protection against the pathological alteration caused by Cisplatin to kidney and testis. Sperm count and motility were significantly restored near to normal. Cisplatin caused depletion of defense system i.e. glutathione peroxidase, catalase and superoxide dismutase, which were restored close to normal by treatment of IN0523. Reduction in excessive lipid peroxidation induced by Cisplatin was also found by treatment with IN0523. The result suggests that IN0523 is a potential candidate for ameliorating Cisplatin induced toxicity in the kidney and testes at a dose of 100mg/kg p.o. via inhibiting the oxidative stress/redox status imbalance and may be improving the efflux mechanism. Copyright © 2017 Elsevier Inc. All rights reserved.

Eesti Maanteemuuseumi välialad : avalik maastikuarhitektuuri ideekonkurss = Public Landscape Architectural Idea Competition "Outdoor Spaces of the Estonian Highway Museum" / Toomas Muru

Index Scriptorium Estoniae

Muru, Toomas, 1970-

2004-01-01

Põlvamaal, endises Varbuse hobupostijaamas avatava Eesti Maanteemuuseumi välialade konkursi eesmärgist, tingimustest, žürii koosseisust, premeeritud töödest. Preemiad: I - Margit Kärner, II - Karli Luik, Ralf Lõoke ja Maarja Kask, III - Taavi Kuningas, Andrus Padu ja Martin Prommik, ergutuspreemiad - Piret Looveer ja Remi Kübar ning Maria Pukk ja Ivar Lubjak

"Kunstisuvi" Pärnus / Sirje Eelma

Index Scriptorium Estoniae

Eelma, Sirje, 1950-

2002-01-01

VIII "Kunstisuve" väikeformaadilise maali näitus "Minima(a)l - tsiteeri(ta)v maalikunst" Pärnu Linnagaleriis. Kuraator Kreg A-Kristring, 36 osalejat. Galerii fassaadil Margit Joonase ülisuur maal. Endla Teatrigaleriis eesti noortekunsti näitus "Autoportree". Kuraator Margaret Tali. Osalejad loetletud. Avamisel Krõõt Juuraku ja Merle Saarva häppening "Green house"

Mis tähendus on sündmusel "Kunstisuvi" teile, korraldajatele? / Sirje Eelma

Index Scriptorium Estoniae

Eelma, Sirje, 1950-

2002-01-01

"Kunstisuve 2002" näitused: Pärnu Linnagaleriis Kreg A-Kristringi kureeritav "Tsiteeri(ta)v maalikunst", Margit Joonase maal galerii välisseinal, Terje Ojaveri installatsioon, Endla Teatrigaleriis Margaret Tali kureeritav noortenäitus, Vallikäärus Rait Pärja korraldatav skulptuuri-workshop, Roma Kungsgardis Gotlandi saarel eesti-rootsi kunsti ühisnäitus (nimetatud osalejad Eestist)

Kuldala elamurajoon Rae vallas Harjumaal / Lembit-Kaur Stöör, Margus Maiste, Raivo Kotov...[jt.

Index Scriptorium Estoniae

2008-01-01

joonised: vaade, I-IV korruse plaan (2), planeeringu makett, 5 värv. fotot: 3 välis- ja 2 sisevaadet; fotod: Kaido Haagen; arhitektuurne projekt: KOKO Arhitektid.; autorid: L.-K. Stöör, M. Maiste, R. Kotov, T. Kimmel, hoonete projekteerimine: L.-K. Stöör, M. Maiste, Olga Batuhtina, maastikuarhitektuur: Margit Kärner

Kuressaare kursiivis on Arensburg / Urmas Oja

Index Scriptorium Estoniae

Oja, Urmas, 1981-2012

2007-01-01

Arensburg Boutique Hotel & Spa lisahoone Kuressaares Lossi t. 15. Arhitektid: Raivo Kotov, Margit Kärner ja Lea Laidra, KOKO Arhitektid OÜ. Sisekujundus: Liisi Murula Maridisain OÜ-st ja Raili Paling KOKO Arhitektid OÜ-st. Ehitustööde peatöövõtja: AS EBC Ehitus. Ehitusaeg: 2005-2007. 7 värv. välisvaadet

Noorte eesti režissööride uued filmid Sõpruses / Mari Peegel

Index Scriptorium Estoniae

Peegel, Mari, 1978-

2005-01-01

Sõpruse kinos esilinastub homme kaks eesti lühimängufilmi - "Vanameeste paradiis" : stsenaristid Ove Musting, Urmas Lennuk : režissöör Ove Musting : mängivad Tõnu Aav, Aleksander Eelmaa jt ning "Ukse taga" : stsenarist Margit Keerdo : režissöör Andrus Tuisk : osades Hele Kõre, Karin Lätsim, Kirill Käro, Igor Gavrilov

Esilinastuseni jõuab kaks uut Eesti lühimängufilmi

Index Scriptorium Estoniae

2005-01-01

Sõpruse kinos esilinastub homme kaks eesti lühimängufilmi - "Vanameeste paradiis" : stsenaristid Ove Musting, Urmas Lennuk : režissöör Ove Musting : mängivad Tõnu Aav, Aleksander Eelmaa jt ning "Ukse taga" : stsenarist Margit Keerdo : režissöör Andrus Tuisk : osades Hele Kõre, Karin Lätsim, Kirill Käro, Igor Gavrilov

Ära tee, tee! = Do not do it, do it! / Rebeka Põldsam

Index Scriptorium Estoniae

Põldsam, Rebeka, 1989-

2016-01-01

Margit Säde-Lehni kuraatorinäitus "DOings & kNOTs. Kunst ja/või instruktsioon" Tallinna Kunstihoones. Lähtepunktiks on Hans Ulrich Obristi 1993. a. algatatud projekt „Do it”. Kunstihoonesse on kutsutud 20 kunstnikku/rühmitust üle Euroopa, et tõlgendada kellegi teise jäetud instruktsioone ja teha nende järgi uusi teoseid

Mikko Fritze : kultuuripealinna ei tehta vaid turistide ja ametnike lõbustamiseks / Mikko Fritze ; interv. Liina Ristoja

Index Scriptorium Estoniae

Fritze, Mikko, 1963-

2008-01-01

Sihtasutuse Tallinn Euroopa Kultuuripealinnaks 2011 juht Mikko Fritze vastab küsimustele, mis puudutavad kultuuripealinna tiitli mõjusid Tallinna linnale ning Eesti kultuurielule. Kommenteerib Peeter Jalakas

Mõista mitte hukka mõista / Mario Sootna

Index Scriptorium Estoniae

Sootna, Mario, 1962-

2004-01-01

Rahvaliidu põllumajandusministri Tiit Tammsaare tagasiastumisest seoses teraviljavarude vargusega ning rünnakutest siseminister Margus Leivo vastu julgeolekuvarude varguse avastamise ning tema poja narkoprobleemide tõttu

Reisirongiliiklus Võrumaal võib alata kõige varem nelja aasta pärast / Mari-Anne Leht

Index Scriptorium Estoniae

Leht, Mari-Anne, 1950-

2004-01-01

Reisirongiliikluse tulevikuvõimalusi Võrumaal analüüsivad Antsla vallavanem Tiit Tõnts, Võru maavalitsuse transpordi ja infrastruktuuri peaspetsialist Ahti Siimon ja Edelaraudtee juhatuse liige Henn Ruubel

Üle 21 aasta eraettevõtluses vastu pidanud / Väinu Rozental

Index Scriptorium Estoniae

Rozental, Väinu, 1957-

2008-01-01

Üle 21 aasta tagasi registreeritud teenindus-tootmiskooperatiividest, mis toimivad edukalt tänaseni. Vt. samas: Audio-Video firma väntab edasi; Giga omanik ja eestööline Tiit Veeber: mul ei ole kuskil mujal olla kui kraavis - see on mu elu; Helko asutaja tegutseb endiselt helide ja võimendamise maailmas; Ilves-Extra orienteerub rõivaste tootmise ja müügi maailmas hästi. Lisad: OÜ Audio-Video; AS Giga; FIE Mart Jallai Helko Helivõimendustehnika; AS Ilves-Extra. Küsimusele, mis on aidanud vastu pidada ja mis saab edasi, vastavad OÜ Audio-Video ainuomanik Jaan Kalmus, ASi Giga omanik Tiit Veeber, OÜ Helimees omanik Mart Jallai ning ASi Ilves-Extra põhiomanik Arvo Kivikas

Milline on sel nädalal 15. tegevusaastat tähistava Võrumaa omavalitsusliidu positsioon viie aasta pärast? / interv. Arved Breidaks

Index Scriptorium Estoniae

2008-01-01

Küsimusele vastavad regionaalminister Siim-Valmar Kiisler, parlamendiliige Kalvi Kõva, ettevõtja Tiit Niilo, Võru linnavolikogu esimees Tõnu Anton ja maaomavalitsuste liidu esimees Kurmet Müürsepp

Ekspert predlagajet avtotunnel v Mustamjae / Urmas Seaver

Index Scriptorium Estoniae

Seaver, Urmas, 1973-

2007-01-01

Tallinna Tehnikaülikooli teedeinstituudis valminud teemaplaneeringus "Tallinna tänavavõrk ja kergliiklusteed" ettenähtud eritasandilistest ristmikest ja tunnelitest. Kommenteerib liiklusekspert Tiit Metsavahi. Lisatud skeem

Hingekeeled ajaloo kuumas tolmus / Jan Kaus

Index Scriptorium Estoniae

Kaus, Jan, 1971-

2011-01-01

Arvustus: Hargla, Indrek. Apteeker Melchior ja timuka tütar : kriminaalromaan vanast Tallinnast. Tallinn : Varrak, 2011 ja Aleksejev, Tiit. Kindel linn : lugu Esimesest ristisõjast. Tallinn : Varrak, 2011

Kalle Norberg õpetab eestlasi kasutama Luksemburgi pangasaladuste kaitset / Airi Ilisson

Index Scriptorium Estoniae

Ilisson, Airi, 1980-

2004-01-01

Firma Luxembourg Financial Service filiaal Eestis hakkab pakkuma privaatpanganduse teenust. Vt. samas intervjuud Kalle Norbergiga. Kommenteerib Tiit Vähi. Lisad: Luxembourg Financial Services; Luksemburgi ärikeskkond; Info lekib

Eesti kokakunsti kõrghetk / Kristiina Viiron

Index Scriptorium Estoniae

Viiron, Kristiina, 1971-

2008-01-01

Restorani Egoist peakokk Vladislav Djatshuk osales Stavangeris toimunud ülemaailmsel kokandusvõistluse Bocuse DþOr Euroopa eelvoorus. Vladislav Djatshuki abikokk Viktor Leshevitsh võitis Stavangeris parima abikoka tiitli

Vann, see on funktsionaalsus, puhtus ja ilu

Index Scriptorium Estoniae

2006-01-01

AS Balteco vannimudelite valikust. Firma vanne on kujundanud Toomas Kelder, Aivar Habakukk, Matti Õunapuu ja Tiit Liiv. Erineva disainiga vannid on grupeeritud kolme tooteseeriasse: Basic, Forma, Relax

Pro Kapitali ärikeskuse taha kerkivad ärid ja korterid / Piret Peensoo

Index Scriptorium Estoniae

Peensoo, Piret

2007-01-01

Tallinnas Pro Kapitali ärikvartalisse Jõe ja Aedvilja tänaval kavandatakse seitsmekorruselist kortermaja ja kuuekorruselist ärihoonet. Arhitekt Tiit Trummal, detailplaneeringu koostas EA Rengi arhitekt Reino Rass

Mehed, kes ei ole kunagi käega löönud / Rain Pikand, Urmas Lilleorg ; interv. Krista Dudarenko

Index Scriptorium Estoniae

Pikand, Rain

2008-01-01

Reklaamiagentuur Division pälvis konkursil "Kuldmuna" Grand Prix' ja Aasta Agentuuri tiitli. Agentuuri loomisest, tähtsamatest töödest, edu tagamaadest, kaasaegses reklaamimaailmas valitsevatest suundadest

Regulation of a putative corticosteroid, 17, 21-dihydroxypregn-4-ene, 3, 20-one, in sea lamprey, Petromyzon marinus.

Science.gov (United States)

Roberts, Brent W.; Didier, Wes; Satbir, Rai; Johnson, Nicholas S.; Libants, Scot V.; Sang-Seon, Yun; Close, David

2013-01-01

In higher vertebrates, in response to stress, the hypothalamus produces corticotropin-releasing hormone (CRH), which stimulates cells in the anterior pituitary to produce adrenocorticotropic hormone (ACTH), which in turn stimulates production of either cortisol (F) or corticosterone (B) by the adrenal tissues. In lampreys, however, neither of these steroids is present. Instead, it has been proposed that the stress steroid is actually 17,21-dihydroxypregn-4-ene-3,20-dione (11-deoxycortisol; S). However, there have been no studies yet to determine its mechanism of regulation or site of production. Here we demonstrate that (1) intraperitoneal injections of lamprey-CRH increase plasma S in a dose dependent manner, (2) intraperitoneal injections of four lamprey-specific ACTH peptides at 100 lg/kg, did not induce changes in plasma S concentrations in either males or females; (3) two lamprey-specific gonadotropin-releasing hormones (GnRH I and III) and arginine-vasotocin (AVT), all at single doses, stimulated S production as well as, or to an even greater extent than CRH; (4) sea lamprey mesonephric kidneys, in vitro, converted tritiated 17a-hydroxyprogesterone (17a-P) into a steroid that had the same chromatographic properties (on HPLC and TLC) as S; (5) kidney tissues released significantly more immunoassayable S into the incubation medium than gill, liver or gonad tissues. One interpretation of these results is that the corticosteroid production of the sea lamprey, one of the oldest extant vertebrates, is regulated through multiple pathways rather than the classical HPI-axis. However, the responsiveness of this steroid to the GnRH peptides means that a reproductive rather than a stress role for this steroid cannot yet be ruled out.

Plaadid / Margit Tõnson

Index Scriptorium Estoniae

Tõnson, Margit, 1978-

2005-01-01

Uute heliplaatide Gorillaz "Demon Days", Nine Inch Nails "With Teeth", Weezer "Make Believe", CDOASS "Extra Fingers", System Of A Down "Mezmerize", Crosby Stills & Nash "Createst Hits 2005", "The Others"

Plaadid / Margit Tõnson

Index Scriptorium Estoniae

Tõnson, Margit, 1978-

2005-01-01

Uutest heliplaatidest Saint Etienne "Tales From Turnpike House", "Team Sleep", Jamiroquai "Dynamite", Life Of Agony "Broken Valley", The Wallflowers "Rebel, Sweetheart", morcheeba "The Antidote", Amerie "Touch"

Plaadid / Margit Tõnson

Index Scriptorium Estoniae

Tõnson, Margit, 1978-

2005-01-01

Uutest heliplaatidest Metro Luminal "Reboot", Rannap, Rein "Tantsib klaveril", Hüpnosaurus "Lint nr 33", Eminem "Encore", Marianne Faithfull "Before the Poision", Aerosmith "You Gotta move", Evanescence "Anywhwre but Home"

Pop / Margit Tõnson

Index Scriptorium Estoniae

Tõnson, Margit, 1978-

2006-01-01

Heliplaatidest: Massive Attack "Collected: the Best of Massive Attack", Daft Punk "Musique Vol.1 - 1993-2005", Psychoterror "Anarhia ja dekadents", The Bluetones "A Rough Outline: The Singles & B-Sides 95-03", Pretty Girls Make Graves "⁹lan Vital", DFA "The DFA Remixes: Chapter One"

Plaadid / Margit Tõnson

Index Scriptorium Estoniae

Tõnson, Margit, 1978-

2004-01-01

Uutest heliplaatidest Travis "Singles", Talking Heads "The Best Of", The Hidden Cameras "Mississauga Goddam", Aberfeldy "Young Forever", The Music "Welcome To The North", Bitch Alert "Kill Your Darlings", Manic Street Preachers "Lifeblood", Depeche Mode "Remixes81-04"

Plaadid / Margit Tõnson

Index Scriptorium Estoniae

Tõnson, Margit, 1978-

2004-01-01

Uutest heliplaatidest Embrace "Out of Nothing", Arrested Development "Among The Trees", Kalm, Kristjan "Generalissimus", Bossacucanova "Uma batida diferente", Adams, Bryan "Room Service", "Kasabian", Korn "Greatest Hits. Vol 1", Papa Roach "Getting Away With Murder"

Plaadid / Margit Tõnson

Index Scriptorium Estoniae

Tõnson, Margit, 1978-

2004-01-01

Uutest heliplaatidest "Maria Rita", "Between Heaven and Earth", Marilyn Manson "Lest We Forget. The Best Of", Phil Collins "Love Songs", Dizzee Rascal "Showtime", Bruce Hornsby "Halcyon Days", Bill Frisell "Unspeakable"

Cheese / Eero Epner

Index Scriptorium Estoniae

Epner, Eero, 1978-

2004-01-01

Fotoajakirjast "Cheese". Fotograafia uurimisest, fotoajaloo läbikirjutatusest Eestis. Samas "Cheese'i" toimetaja Tiit Lepp ajakirja erainitsiatiivil väljaandmisest, Eesti Kultuurkapitali ebapiisavast ja määramatust toetusest

Kakaja mogla bõ bõt alternativa povõsheniju NSO?

Index Scriptorium Estoniae

2008-01-01

Rahandusministeeriumi plaanist tõsta seni 5protsendise käibemaksuga maksustatud kaupade ja teenuste maksu 9 protsendini. Küsimusele vastavad Heido Vitsur, Vello Vallaste, Rain Lõhmus ja Tiit Kuusmik

Kroonika esitleb : Justin Timberlake ja Rod Stewart / Justin Timberlake ; interv. Katrin Lust-Buchanan

Index Scriptorium Estoniae

Timberlake, Justin

2006-01-01

Meesteajakirja GQ auhindade jagamise tseremoonial Londonis sai ajakirja Kroonika reporter jutule aasta rahvusvahelisima mehe tiitli pälvinud Justin Timberlake'i ja elutööpreemia saanud Rod Stewartiga

Majad kohanesid kameeleonina ajaga : millised oleksid võinud Tartu hooned olla / Mari-Liis Pintson

Index Scriptorium Estoniae

Pintson, Mari-Liis

2008-01-01

Tartusse ehitatud hoonete esialgsest ning lõplikust väliskujust. Tasku (Koma), Plasku, GMP Plaza hoonetest, Tartu Kaubamajast, Vabaduse sillast. Kommenteerivad arhitektid Andres Lunge, Kalle Rõõmus, Tiit Sild

Tänavu sünnib ligi 300 last rohkem kui mullu / Mirko Ojakivi

Index Scriptorium Estoniae

Ojakivi, Mirko

2005-01-01

Demograafilistest protsessidest Eestis lõppeval aastal. TÜ inimgeograafia õppetooli vanemteaduri Tiit Tammaru prognoose lähitulevikuks. Lisa: Rummo rõõmustab edasimineku üle. Graafik: Ligi 300 last enam

Draamateatri direktor selgub kolme väljavalitu seast / Tambet Kaugema

Index Scriptorium Estoniae

Kaugema, Tambet

1999-01-01

Eesti Draamateatri direktori ametikoha täitmiseks moodustatud komisjonile esitas personaliotsingufirma Fontes kolm kandidaati - Estonia turundusjuhi Tiit Lauri, ENA tegevdirektori Külli Holstingi ja eraettevõtluses tegutseva Rein Kirsi

Selgusi selle aasta parimad sportlased / Ketlin Bejaev

Index Scriptorium Estoniae

Bejaev, Ketlin

2006-01-01

Tartu tänavune parim meessportlane on karate maailmameister Marko Luhamaa, tema treener Jüri Post pälvis aasta treeneri tiitli. Parimaks naissportlaseks tunnistati laskeorienteerumise maailmameister Eveli Saue

Moes on lopsakad taimed ja geomeetrilised vormid / Tiina Kolk

Index Scriptorium Estoniae

Kolk, Tiina

2010-01-01

Aiadisainer Merilen Mentaali muljeid Briti Kuningliku Aiandusseltisi 2010. aasta Chelsea Flower Show'lt. Peapreemia ehk parima show-aia tiitli võitis disainer Andy Sturgeon The Daily Telegraphi aia eest

Voldemar ehk Portreed temas ja tema ümber / Kristi Eberhart

Index Scriptorium Estoniae

Eberhart, Kristi

2007-01-01

Andrus Kivirähki "Voldemar", mis kirjutatud toetudes Voldemar Panso kirjutatud lugudele, päevikule, kirjadele. Lavastaja Merle Karusoo, peaosas Tiit Sukk. Esietendus 25. märtsil Eesti Draamateatris

Ühendatud inimeste üksindus / Martin Ehala

Index Scriptorium Estoniae

Ehala, Martin, 1963-

2007-01-01

Vastukaja art.: Sutrop, Margit. Vabadus ja vastutus // Postimees : AK : Arvamus. Kultuur (2007) 20. jaan. Artikli autor Martin Ehala selgitab, miks laguneb lääne ühiskondades sotsiaalne kapital ja kaob ühiskonda liitev meie-tunne. Kolmest olulisest sotsiaalsest nähtusest : individualismist, kollektivismist ja sotsiaalsest kapitalist. Üks olulisemaid tingimusi meie-tunde arenemiseks on ühiste väärtuste olemasolu

Kodu osa isiklikus ja ühiskondlikus elus

Index Scriptorium Estoniae

2008-01-01

15. II avatakse Eesti Tarbekunsti-ja Disainimuuseumis Eesti Vabariigi 90. aastapäevale pühendatud näitus "Varamu. Esindusruum ja moodne kodu 1918-1940", mille on koostanud Merike Alber, kujundanud Margit Lillak ning graafiliselt kujundanud Denes Farkas. Eksponaadid on pärit riigikogust, presidendi kantseleist, Eesti muuseumidest ning erakogudest. Lõik Hanno Kompuse artiklist ajakirjas "Kaunis Kodu", 1935, nr. 3

Kodu osa isiklikus ja ühiskondlikus elus

Index Scriptorium Estoniae

2008-01-01

15. veebruaril 2008. a. avatakse Eesti Tarbekunsti-ja Disainimuuseumis Eesti Vabariigi 90. aastapäevale pühendatud näitus "Varamu. Esindusruum ja moodne kodu 1918-1940", mille on koostanud Merike Alber, kujundanud Margit Lillak ning graafiliselt kujundanud Denes Farkas. Eksponaadid on pärit riigikogust, presidendi kantseleist, Eesti muuseumidest ning erakogudest. Lõik Hanno Kompuse artiklist ajakirjas "Kaunis Kodu", 1935, nr. 3

Tervisliku liikumise tähendusest - on see sport või midagi muud? / Marko Uibu

Index Scriptorium Estoniae

Uibu, Marko, 1983-

2016-01-01

Terviseedenduse jaoks kommunikatiivsetest, liikumise tähendustega seotud väljakutsetest. Liikumise spordikesksest käsitlusest. Tartu Ülikooli veetavast liikumisprojektist, mis püüab kaasa aidata laste aktiivsemale liikumisele nii vahetundides kui ka ainetundides. Artikkel põhineb projekti "Laste ja noorte tõenduspõhise liikumisprogrammi arendamine" käigus Margit Kelleri, Marko Uibu ja Triin Vihalemma koostatud uuringuraportil

Elamu Kalamaja piiril : Noole 4, Tallinn = Residential Building on the Edge of the Kalamaja District : Noole 4, Tallinn / Triin Ojari

Index Scriptorium Estoniae

Ojari, Triin, 1974-

2008-01-01

42 korteriga elamu, mille alumine korrus on endise tööstushoone paemüür, II korrus on puidust, III korrus on kaetud Cortenterasega. Projekteerija: Arhitektuuribüroo Eek & Mutso. Autorid: Margit Mutso, Kristi Põldme. Konstruktor: OÜ Kuup Ehitus. Ehitaja: YIT. Projekt: 2006, valmis: 2007. M. Mutso hoone kavandamisest ja valmimisest. I-IV korruse plaan, 6 värv. välisvaadet

Kuni 13. III saab Y-galeriis vaadata EKA avatud akadeemia näitust "Lavastused ja interpretatsioonid"

Index Scriptorium Estoniae

2005-01-01

Stseenid modellidega on lavastanud Tiina Tammetalu, maalinud-interpreteerinud üliõpilased Ulvi Kuldkepp, Margit Maksing, Liis-Theresia Ulman, (Margus) Soho Fond, Ian Oja, Alissa Didõk-Riikjärv ja Monika Sorokina. Väljapaneku on kujundanud T. Tammetalu ja U. Kuldkepp. Projekt "Happy" on T. Tammetalu kureeritav näitusesari, mis tutvustab tema juhendamisel tehtud üliõpilaste töid

Hoiugrupp vajus nagu Titanic / Sulev Vedler

Index Scriptorium Estoniae

Vedler, Sulev, 1970-

1998-01-01

Hoiupanga grupi kahjum ja segased tehingud, mis selle põhjustasid. Hoiupanga liitumine Hansapangaga ei olnud võrdsete partnerite ühinemine. Olari Taali, Lembit Kaljuvee, Tiit Vähi jt. kahtlased tehingud

Taastatud Pilistvere pastoraat / Dolores Hoffmann, Helmi Seil, Vello Rajangu

Index Scriptorium Estoniae

Hoffmann, Dolores, 1937-

2006-01-01

7 ill.; fotod: Tiit Koha; kontoriruumi akent ehib Dagmar ?(Dolores) Hoffmanni vitraaž, seinal on Helmi Seili ristpistes tikitud Eesti kaart, talvekirikus Vello Rajangu Pallase päevil loodud inglikuju

Maailma parim ehitis 2011 / Jarmo Kauge

Index Scriptorium Estoniae

Kauge, Jarmo

2011-01-01

Barcelonas 2.-4. nov. 2011 toimunud 4. Maailma arhitektuurifestivalil (WAF) aasta parima ehitise tiitli pälvinud Media-ICT kontorihoonest Barcelonas. Autor: Enric Ruiz-Geli arhitektuuribüroost Cloud 9

Vastuolud annavad märku muutuste vajadusest / Marit Pukk

Index Scriptorium Estoniae

Pukk, Marit

2002-01-01

Kiiresti areneva firma struktuur vajab muutmist. Kommenteerivad gasellettevõtete juhid Argo Schneider (OÜ Albion Reisid), Peep Nork (AS Euro Truck Trade Center), Riinu Värk (AS Meditsiinigrupp) ja Tiit Elenurm

Ring opening of 2-aza-3-borabicyclo[2.2.0]hex-5-ene, the Dewar form of 1,2-dihydro-1,2-azaborine: stepwise versus concerted mechanisms

Directory of Open Access Journals (Sweden)

Holger F. Bettinger

2013-04-01

Full Text Available The ring opening of the Dewar form of 1,2-dihydro-1,2-azaborine, 2-aza-3-borabicyclo[2.2.0]hex-5-ene (3 is investigated by theoretical methods by using multiconfiguration SCF (CASSCF and coupled cluster theory [CCSD(T] with basis sets up to polarised quadruple-zeta quality. The title compound was previously reported to form photochemically in cryogenic noble gas matrices from 1,2-dihydro-1,2-azaborine (4. Four reaction paths for the thermal ring opening of 3 to 4 could be identified. These are the conventional disrotatory and conrotatory electrocyclic ring-opening pathways where the BN unit is only a bystander. Two more favourable paths are stepwise and involve 1,3-boron–carbon interactions. The lowest energy barrier for the isomerisation reaction, 22 kcal mol−1, should be high enough for an experimental observation in solution. However, in solution the dimerisation of 3 is computed to have a very low barrier (3 kcal mol−1, and thus 3 is expected to be a short-lived reactive intermediate.

IN0523 (Urs-12-ene-3α,24β-diol) a plant based derivative of boswellic acid protect Cisplatin induced urogenital toxicity

International Nuclear Information System (INIS)

Singh, Amarinder; Arvinda, S; Singh, Surjeet; Suri, Jyotsna; Koul, Surinder; Mondhe, Dilip M.; Singh, Gurdarshan; Vishwakarma, Ram

2017-01-01

The limiting factor for the use of Cisplatin in the treatment of different type of cancers is its toxicity and more specifically urogenital toxicity. Oxidative stress is a well-known phenomenon associated with Cisplatin toxicity. However, in Cisplatin treated group, abnormal animal behavior, decreased body weight, cellular and sub-cellular changes in the kidney and sperm abnormality were observed. Our investigation revealed that Cisplatin when administered in combination with a natural product derivative (Urs-12-ene-3α,24β-diol, labeled as IN0523) resulted in significant restoration of body weight and protection against the pathological alteration caused by Cisplatin to kidney and testis. Sperm count and motility were significantly restored near to normal. Cisplatin caused depletion of defense system i.e. glutathione peroxidase, catalase and superoxide dismutase, which were restored close to normal by treatment of IN0523. Reduction in excessive lipid peroxidation induced by Cisplatin was also found by treatment with IN0523. The result suggests that IN0523 is a potential candidate for ameliorating Cisplatin induced toxicity in the kidney and testes at a dose of 100 mg/kg p.o. via inhibiting the oxidative stress/redox status imbalance and may be improving the efflux mechanism. - Highlights: • Synthesis of a novel boswellic acid derivative (IN0523) • Counter oxidative stress induced due to Cisplatin • Protect against urogenital toxicity induced by Cisplatin

IN0523 (Urs-12-ene-3α,24β-diol) a plant based derivative of boswellic acid protect Cisplatin induced urogenital toxicity

Energy Technology Data Exchange (ETDEWEB)

Singh, Amarinder [Academy of Scientific & Innovative Research (AcSIR), New Delhi (India); PK-PD-Toxicology and Formulation Division, CSIR-Indian Institute of Integrative Medicine, Canal Road, Jammu 180001, J& K (India); Arvinda, S [Deptt. of Pathology, Govt. Medical College, Jammu 180001, J& K (India); Singh, Surjeet [PK-PD-Toxicology and Formulation Division, CSIR-Indian Institute of Integrative Medicine, Canal Road, Jammu 180001, J& K (India); Suri, Jyotsna [Deptt. of Pathology, Govt. Medical College, Jammu 180001, J& K (India); Koul, Surinder [Bio-Organic Chemistry Division, CSIR-Indian Institute of Integrative Medicine, Canal Road, Jammu 180001, J& K (India); Mondhe, Dilip M. [Cancer Pharmacology Division, CSIR-Indian Institute of Integrative Medicine, Canal Road, Jammu 180001, J& K (India); Singh, Gurdarshan, E-mail: singh_gd@iiim.ac.in [PK-PD-Toxicology and Formulation Division, CSIR-Indian Institute of Integrative Medicine, Canal Road, Jammu 180001, J& K (India); Vishwakarma, Ram [Bio-Organic Chemistry Division, CSIR-Indian Institute of Integrative Medicine, Canal Road, Jammu 180001, J& K (India)

2017-03-01

The limiting factor for the use of Cisplatin in the treatment of different type of cancers is its toxicity and more specifically urogenital toxicity. Oxidative stress is a well-known phenomenon associated with Cisplatin toxicity. However, in Cisplatin treated group, abnormal animal behavior, decreased body weight, cellular and sub-cellular changes in the kidney and sperm abnormality were observed. Our investigation revealed that Cisplatin when administered in combination with a natural product derivative (Urs-12-ene-3α,24β-diol, labeled as IN0523) resulted in significant restoration of body weight and protection against the pathological alteration caused by Cisplatin to kidney and testis. Sperm count and motility were significantly restored near to normal. Cisplatin caused depletion of defense system i.e. glutathione peroxidase, catalase and superoxide dismutase, which were restored close to normal by treatment of IN0523. Reduction in excessive lipid peroxidation induced by Cisplatin was also found by treatment with IN0523. The result suggests that IN0523 is a potential candidate for ameliorating Cisplatin induced toxicity in the kidney and testes at a dose of 100 mg/kg p.o. via inhibiting the oxidative stress/redox status imbalance and may be improving the efflux mechanism. - Highlights: • Synthesis of a novel boswellic acid derivative (IN0523) • Counter oxidative stress induced due to Cisplatin • Protect against urogenital toxicity induced by Cisplatin.

Critical Parameters and Critical-Region (p,ρ ,T) Data of trans-1,1,1,3-Tetrafluorobut-2-ene [HFO-1354mzy(E)

Science.gov (United States)

Kimura, Takeru; Kayukawa, Yohei; Miyamoto, Hiroyuki; Saito, Kiyoshi

2017-08-01

This study presents the experimental measurement of the pρ T properties and critical parameters of a low GWP type refrigerant, trans-1,1,1,3-Tetrafluorobut-2-ene (HFO-1354mzy(E)). The sample purity of the substance was 99 area %. p ρ T property measurements and visual observations of the meniscus of HFO-1354mzy(E) were carried out using a metal-bellows volumometer with an optical cell. The critical temperature was determined by observation of the critical opalescence. The critical pressure and critical density were determined as the inflection point of the isothermal p ρ T property data at the critical temperature. For more precise clarification of the thermodynamic surface in the vicinity of the critical point, additional p ρ T property measurements were carried out on three isotherms in the supercritical region. The expanded uncertainties (k = 2) in the temperature, pressure, and density measurements were estimated to be less than 3 mK, 1.2 kPa, and 0.32 \\hbox {kg} \\cdot \\hbox {m}^{-3}, respectively. The expanded uncertainties of the critical parameters were estimated to be less than 13 mK, 1.4 kPa, and 2.3 \\hbox {kg} \\cdot \\hbox {m}^{-3}, respectively. These values are the first reported for HFO-1354mzy(E) and are necessary for the development of its equation of state in the near future.

Endla teater kavandab põnevaid lavastusi / Silja Joon

Index Scriptorium Estoniae

Joon, Silja, 1966-

2008-01-01

Endla teatri suvelavastustest - kolmandat suve etenduvast "Vargamäe kuningriigist" ja ameerika kirjaniku Doug Wrighti monotükist "Ma olen iseenda naine" Tiit Palu lavastuses, ka sügisel etenduvatest uuslavastustest

Valitsus peaks noortebändi Bedwetters autasustama

Index Scriptorium Estoniae

2007-01-01

Rahvaliidu noored peavad vajalikuks, et valitsus autasustaks esimese Eesti bändina MTV Europe Music Awards 2007 galal Saksamaal Münchenis auhinnakategoorias "Euroopa uue heli" tiitli võitnud pop-punkansamblit Bedwetters

Aasta film - joonisfilm "Mont Blanc" / Verni Leivak

Index Scriptorium Estoniae

Leivak, Verni, 1966-

2002-01-01

Eesti Filmiajakirjanike Ühing andis aasta 2001 parima filmi tiitli Priit Tenderi joonisfilmile "Mont Blanc" : Eesti Joonisfilm 2001.Ka filmikriitikute eelistused kinodes ja televisioonis 2001. aastal näidatud filmide osas

Raplamaa kutsehariduse saatus pani poliitikud stressipalle mudima / Matis Song

Index Scriptorium Estoniae

Song, Matis, 1978-

2004-01-01

Põllumajandusminister Tiit Tammsaar, rahandusminister Taavi Veskimägi, Riigikogu liikmed Tunne Kelam, Leino Mägi ja Harri Õunapuu külastasid Raplamaad ning tutvusid kutse- ja täiendhariduse probleemidega

Veronika Dari mõrvarid mõisteti vangi / Madis Taras

Index Scriptorium Estoniae

Taras, Madis

2008-01-01

Harju maakohtu otsusest Tallinnas 2005. aasta 7. oktoobri hommikul Riigi Kinnisvara AS-i endise esimehe Tiit Ottise mõrvakatse käigus koolitüdruku Veronika Dari tapnud kurjategijate karistamise kohta

Mõrvarid jahtisid Riigi Kinnisvara juhti / Andris Tammela

Index Scriptorium Estoniae

Tammela, Andris

2006-01-01

Politsei pidas kinni kolm meest, keda kahtlustatakse oktoobri alguses Tallinna koolitüdruku Veronika Dari tapmises, väidetavalt oli meeste tegelik sihtmärk Riigi Kinnisvara aktsiaseltsi juht Tiit Ottis

Osavalt peidetud / Silvia Pärmann

Index Scriptorium Estoniae

Pärmann, Silvia

2015-01-01

Arhitekt Tiit Silla projekteeritud avara katuseterrassiga hotell "Konrad" Tartus Küütri tänav 8. Hoone kaasautorid Martin McLean ja Keiti Kaasik (Arhitektuuribüroo Sport), sisearhitekt Kristiina Kuustuba

Sirje ja Harald. Sült ja sõleke / Pille-Riin Purje

Index Scriptorium Estoniae

Purje, Pille-Riin, 1963-

2009-01-01

Kahest Endla teatri lavastusest: Raimonds Paulsi muusikal põhinevast muusikalavastustusest "Raimonds", lavastaja Tiit Palu, esietendus 7. märtsil. Urmas Vadi pseudoajaloolisest põnevusloost "Ballettmeister", lavastaja Andres Noormets, esietendus 30. aprillil

Plaadid / Tiit Kusnets

Index Scriptorium Estoniae

Kusnets, Tiit

2004-01-01

Uutest heliplaatidest Van Halen "The Best Of Both Worlds", Lars Danielsson "Libera Me", The Verve "This Is Music", Massive Attack "Danny The Dog", Duran Duran "Astronaut", Macy Gray "The Very Best Of"

Popmuusika / Tiit Kusnets

Index Scriptorium Estoniae

Kusnets, Tiit

2005-01-01

Uutest heliplaatidest Les Paul & Friends "American Made World Played", "So Amazing", Kolumbus Kris "See on voodoo", Abstrait Presents "Al-pha-x & Ma Faiza", Kjetil Björnstad "Floating", S.U.M.O. "Rebounces", Queen ? Paul Rodgers "Return Of The Champions"

Plaadid / Tiit Kusnets

Index Scriptorium Estoniae

Kusnets, Tiit

2005-01-01

Uutest heliplaatidest Sõpruse Puiestee "XX sajandi lapsed", Joel Tammik "Eemal", Har Mar Superstar "The Handler", "Brazilian Girls", "The New Sound Of Regage", Eric Clapton "Sessions For Robert J", Freeform Five "Strangest Things"

Plaadid / Tiit Kusnets

Index Scriptorium Estoniae

Kusnets, Tiit

2004-01-01

Uutest plaatidest Luavrik Luavrik "Passioon & Fuuga", Arve Henriksen "Chiaroscuro", Bullfrog Brown "Mudhole Stories", "Scoonby-Doo 2", Bela fleck & Edgar Mayer "Music For Two", Christiana Milian "It's About Time"

Kirev moepillerkaar / Britt Rosen

Index Scriptorium Estoniae

Rosen, Britt, 1968-

2008-01-01

FIBITi moepäevad ja Kuldnõela gala Viru keskuses. Eesti parima moekunstniku tiitli pälvis Riina Põldroos. Kommentaarid Riina Põldroosilt, Aldo Järvsoolt, Urmas Väljaotsalt, Kirill Safonovilt. 17 ill

Vikergallup: eesti kirjandus 2003 : [vastused Vikerkaare küsimustele] / Vahur Afanasjev, Indrek Hargla, Peeter Helme ... [jt.

Index Scriptorium Estoniae

2004-01-01

2003. a. parima uudisraamatu tiitli pälvis Kivisildniku "Päike, mida sa õhtul teed"; parima esikraamatu tiitlit jagasid Asko Künnapi "Ja sisalikud vastasid (kolmes kirjas)" ning Erkki Luugi "Ornitoloogi meelespea"

Ellen Aitsam - õpetaja kõige paremas mõttes / Tiia Truu

Index Scriptorium Estoniae

Truu, Tiia

2007-01-01

Persoonilugu 33 aastat Vigalas keemia-, biloogia- ja geograafiaõpetajana töötanud Ellen Aitsamist. Mare Mursak-Ülemaante; Jaan Moor; Evi Tikerpalu-Andrejev; Elme Tiits-Moor: Mis meenub õpetaja Ellen Aitsamist?

Täna kell 20.30 avatakse Tartu ööklubis "Tallinn"...

Index Scriptorium Estoniae

2002-01-01

Avatakse 58 mø digitaalpannoo"Tallinna taastamine" I faas "Subtroopilised tellingud". Pannoo teiseneb regulaarselt. Autorid Peeter Laurits, Madis Palm, Ulvi Tiit. Kasutatud ka Georg Johannes Parikase, Rain Tamme, Arne Aderi jt. fotosid

Godovshtshina bez eiforii / Aleksei Klepikov

Index Scriptorium Estoniae

Klepikov, Aleksei

2005-01-01

EL-i ja NATO-ga liitumise mõjudest Baltimaade elanike turvatundele ning majandusele. Arvamust avaldavad Tiit Matsulevitsh, Ivar Sikk, Toivo Kuldkepp jt. Toimetuse kommentaar. Diagramm: Inflatsioonimäärad Ida-Euroopa riikides

Korpusepoistest / Toomas Hiio

Index Scriptorium Estoniae

Hiio, Toomas, 1965-

2008-01-01

Rets. rmt.: Tiit Noormets, Toe Nõmm, Hanno Ojalo, Olev Raidla, Eigo Rosenthal, Tõnis Taavet, Mati Õun. Korpusepoisid. Tallinn : Eesti Akadeemiline Sõjaajaloo Selts : Sentinel, 2007. Punaarmee eesti üksustest aastatel 1940-1956.

Merkel - Euroopa mõjukaim poliitik / Aadu Hiietamm

Index Scriptorium Estoniae

Hiietamm, Aadu, 1954-

2008-01-01

Harris Interactive'i korraldatud küsitluste tulemuste põhjal peavad Euroopa Liidu viie liikmesriigi kodanikud ühenduse liidriks Saksamaad. Saksamaa liidukantsler Angela Merkel pälvis Euroopa mõjukaima poliitiku tiitli

Inimesed ja mesilased / Rein Tootmaa

Index Scriptorium Estoniae

Tootmaa, Rein

2005-01-01

Nukufilm "Gene+ratio" : stsenarist, kunstnik ja režissöör Mait Laas : konsultant Paavo Matsin : operaatorid Ragnar Neljandi, Raivo Möllits : helilooja Tiit Kikas : Nukufilm OÜ - Icon Film (Saksamaa) 2005

Minimalism, sooja südamega / Malle Pajula, Eva Toome ; kommenteerinud Riina Harik

Index Scriptorium Estoniae

Pajula, Malle, 1971-

2009-01-01

Perekond Kremmi napi ja läbimõeldud kujunduse ning tervikliku valguslahenduse ja välibasseiniga eramust Tiskres, mis pälvis konkursil "Kaunis Kodu 2008" sisekujundaja kaasabil loodud kauneima kodu tiitli

Bekkerist võib saada sõjalaevastiku baas / Nils Niitra

Index Scriptorium Estoniae

Niitra, Nils, 1975-

2000-01-01

Teede- ja sideministeeriumis ja siseministeeriumis arutatakse Tallinna miinisadama müüki ja Eesti sõjalavastiku koondamist Bekkeri sadamasse. Vastuseks vt. Äripäev Feb/1 lk. 27 Tiit Maidre artiklit

Raamatukogu esisele kerkib kevadel Marie Underi kuju / Andres Eilart

Index Scriptorium Estoniae

Eilart, Andres

2009-01-01

Skulptor Mati Karminil ja arhitekt Tiit Trummalil valmib valgest marmorist mälestusmärk Marie Underile. Kuju püstitatakse 2010. a. kevadel Eesti Rahvusraamatukogu ette. Alale on kavandatud ka veekaskaadid

7-{[2-(4-Hydroxyphenylmethylidene]amino}-1,3-thiazol-4-yl-2-(methoxyiminoacetyl]amino}-3-{[(2-methyl-5,6-dioxo-1,2,5,6-tetrahydro-1,2,4-triazin-3-ylsulfanyl]methyl}-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylic Acid

Directory of Open Access Journals (Sweden)

Ghulam Fareed

2012-05-01

Full Text Available Novel 7-{[2-(4-hydroxyphenylmethylidene]amino}-1,3-thiazol-4-yl-2-(methoxyiminoacetyl]amino}-3-{[(2-methyl-5,6-dioxo-1,2,5,6-tetrahydro-1,2,4-triazin-3-ylsulfanyl]methyl}-8-oxo-5-thia-1azabicyclo [4.2.0]oct-2-ene-2-carboxylic acid was prepared by condensation of ceftriaxone disodium (1 with 4-hydroxybenzaldehyde (2 in ethanol under reflux conditions for 3–4 h. The structure of synthesized compound was elucidated using LCMS, ¹H-NMR, and CHN techniques.

Экслибрисы Юрия Орлова получили признание в Польше

Index Scriptorium Estoniae

2009-01-01

Graafik Juri Orlov sai Poolas toimunud Rahvusvahelisel graafiliste väikevormide ja eksliibriste biennaalil (XIII Międzyanrodowe Biennale Małej Formy Graficznej i Ekslibrisu, Ostrów Wielkopolski 2009) laureaadi tiitli

Vabariigi President õnnitles maailmameister Gerd Kanterit

Index Scriptorium Estoniae

2007-01-01

President Toomas Hendrik Ilves helistas Gerd Kanterile, kes võitis Osakas kergejõustiku maailmameistrivõistlustel kettaheites kuldmedali. Riigipea õnnitles G. Kanterit maailmameistri tiitli puhul ja kutsus ta Eestisse saabumise järel Kadriorgu

Plaadid / Maris Meiesaar, Tui Hirv, Veiko Pesur...[jt.

Index Scriptorium Estoniae

2008-01-01

Uutest heliplaatidest Elbow "The Seldom Seen Kid", Bonzo "Ei saa mitte vaiki olla", Cavalera Conspiracy "Inflikted", Tiit Kaluste Jump Band "Prantsuse spetsaliteet", Gnarls Barkley "The Odd Couple", Counting Crows "Saturday Nights & Sunday Mornings"

Avastamata aare - Soomaa / Merle Adams, Rait Parts

Index Scriptorium Estoniae

Adams, Merle

2009-01-01

Euroopa Komisjoni algatatud rahvusvahelisest projektist EDEN "European Tourist Destinations of Exellence" ning selle raames toimunud Euroopa kontekstis loodusturismi sihtkohtade konkursi "European Destinations of Exellence" Eesti 2009. aasta sihtkoha tiitli võitnud Soomaa rahvuspargist

Tatiana Detlofson: "Mandariinide" film on nagu väike kalliskivi üüratus meres / intervjueerinud Annela Laaneots

Index Scriptorium Estoniae

Detlofson, Tatiana

2016-01-01

Intervjuu Oscari nominatsiooni jõudnud Eesti filmi "Mandariinid" PR-tegija Tatiana Detlofsoniga filmi PR-i eduteguritest. Filmi meeskond pälvis Aasta Suhtekorraldaja 2015 tiitli professionaalse ja tulemusliku PR-töö eest

Kadunud vili ja Eesti haldussuutlikkus / Kaul Nurm

Index Scriptorium Estoniae

Nurm, Kaul

2004-01-01

Teravilja julgeolekuvaru kadumise tagajärjed ja õppetunnid Euroopa Liidu poolt vaadatuna. Autori arvates oleks olnud vili alles, kui põllumajandusminister Tiit Tammsaar oleks kasutanud oma aega enda valitsemisalas riigi haldussuutlikkuse tõstmisele

Ilves receives honorary degree / Ella Karapetyan

Index Scriptorium Estoniae

Karapetyan, Ella

2010-01-01

President Toomas Hendrik Ilves nimetati Johannes Paulus II nimelise Lublini Katoliikliku Ülikooli audoktoriks. President T. H. Ilvese kõnest tiitli üleandmise tseremoonial. Töövisiit Poola Vabariiki 19.-20.05.2010

Linn ostis 135 000 krooni eest kunsti

Index Scriptorium Estoniae

2000-01-01

Tallinna linnavalitsus ostis Tiit Pääsukese "Osaliselt varjatud IV, V, VI" (60000 kr.), Sirje Runge "Vaikus III" (25000 kr.), Jüri Arraku "Purunenud kuju II" (30000 kr.), Enno Halleku "Objekt" (20000 kr.)

Areen küsib : mis oli aasta kultuurishokk?

Index Scriptorium Estoniae

2005-01-01

Positiivne ja negatiivne kultuurisündmus 2005. aastal. Küsimusele vastavad Juhan Maiste, Karin Hallas-Murula, Jaan Toomik, Toivo Raidmets, Maile Grünberg, Leo Lapin, Märt Väljataga, Berk Vaher, Sergei Stadnikov, Veljo Kaasik, Margit Mutso, Erkki-Sven Tüür, Mihkel Mutt, Kaarel Tarand, Priidu Beier, Hasso Krull, Jaan Pehk, Hendrik Luuk, Karlo Funk, Kristo Rajasaare, Andres Maimik, Priit Raud, Marianne Kõrver

Lahe viisnurkne maja / Urmas Oja

Index Scriptorium Estoniae

Oja, Urmas, 1981-2012

2005-01-01

Eramu (257 m2) Tabasalus. Valge kahekorruselise osaga liitub ühekordne must, oranzhikate triipudega garaazhi ja vannitoaga maht. Terves majas on kasutatud võimalikult palju puitu. Arhitekt Margit Mutso. Sisearhitekt Kätlin Ölluk, kes on kavandanud ka enamiku mööbliesemetest. Projekt 2003, valminud 2005. Ill.: 3 värv. välis- ja 6 sisevaadet, I ja II korruse ning asendiplaan

Nähtamatu naise nähtav panus / Eerik Purje ; fotod: V. Sarapuu

Index Scriptorium Estoniae

Purje, Eerik, 1927-

2006-01-01

17. oktoobri õhtul Tartu College´i saalis toimunud pidulikust õhtust, mis oli pühendatud Vaiki Toile, esitades Roman Toi loomingut ja tähistades Romani 90. sünnipäeva. Õhtut juhtis Avo Kittask, esinesid Estonia Koor, Toronto Eesti Meeskoor, lauluansambel Helin, klaveril saatis Asta Ballstadt, koore juhatasid Margit Viia-Maiste, Ingrid Silm, Charles Kipper. Avati kunstnik Josef Milczarski portree juubilarist

N-O chemistry for antibiotics: discovery of N-alkyl-N-(pyridin-2-yl)hydroxylamine scaffolds as selective antibacterial agents using nitroso Diels-Alder and ene chemistry.

Science.gov (United States)

Wencewicz, Timothy A; Yang, Baiyuan; Rudloff, James R; Oliver, Allen G; Miller, Marvin J

2011-10-13

The discovery, syntheses, and structure-activity relationships (SAR) of a new family of heterocyclic antibacterial compounds based on N-alkyl-N-(pyridin-2-yl)hydroxylamine scaffolds are described. A structurally diverse library of ∼100 heterocyclic molecules generated from Lewis acid-mediated nucleophilic ring-opening reactions with nitroso Diels-Alder cycloadducts and nitroso ene reactions with substituted alkenes was evaluated in whole cell antibacterial assays. Compounds containing the N-alkyl-N-(pyridin-2-yl)hydroxylamine structure demonstrated selective and potent antibacterial activity against the Gram-positive bacterium Micrococcus luteus ATCC 10240 (MIC(90) = 2.0 μM or 0.41 μg/mL) and moderate activity against other Gram-positive strains including antibiotic resistant strains of Staphylococcus aureus (MRSA) and Enterococcus faecalis (VRE). A new synthetic route to the active core was developed using palladium-catalyzed Buchwald-Hartwig amination reactions of N-alkyl-O-(4-methoxybenzyl)hydroxylamines with 2-halo-pyridines that facilitated SAR studies and revealed the simplest active structural fragment. This work shows the value of using a combination of diversity-oriented synthesis (DOS) and parallel synthesis for identifying new antibacterial scaffolds.

Potshemu ne goditsja nõheshnjaja sistema nalogooblazhenija?

Index Scriptorium Estoniae

2003-01-01

Oma arvamuse Eesti maksusüsteemi kohta ütlevad: Siim Kallas - Reformierakond, Tõnis Palts - Res Publica, Nikolai Maspanov - VEE, Eiki Nestor - Rahvaerakond Mõõdukad, Tiit Toomsalu - ESDTP, Küllo Arjakas - Keskerakond, Mart Opmann - ERL

Ristikultuuri äratajad / Heinz Valk, Eerik Kõuts, Sirje Endre

Index Scriptorium Estoniae

Valk, Heinz, 1936-

1998-01-01

Intervjuu raamatu "Rist ja raud" autorite Heinz Valgu ja Eerik Kõutsiga meie kalmistukultuurist ja vanadest sepistest ning raamatu väljaandja Sirje Endrega; raamatu fotode autor on Tiit Veermäe, kujundaja Andres Tali

Loomisel elujõudu sümboliseeriv linnaskulptuur

Index Scriptorium Estoniae

1998-01-01

Hoiupanga korraldatud linnaskulptuuride konkursi Angela Orgusaare võidutööst "Urban Egg" on valminud makett. Kommentaarid Krista Kodreselt, Angela Orgusaarelt. Skulptuuri keskne sepis valmib koostöös Tiit Masso inseneribürooga

Rabapistriku juhtum / Kristel Ader

Index Scriptorium Estoniae

Ader, Kristel

2003-01-01

Loomadega kaubitsemise konventsiooni CITES Eesti teadusnõuniku Tiit Marani sõnul liigub Eestis küll väiteid lindudega kaubitsemise kohta, kuid kindlat infot pole CITES-i kaudu teistest riikidest Eestisse jõudnud

Kaire Kemp-Tishler : harmoonia moodsa ja vana vahel / Gitte Hint

Index Scriptorium Estoniae

Hint, Gitte

2003-01-01

Eramu sisekujundus. Sisearhitekt Kaire Kemp-Tishler, tema kommentaarid. Arhitekt Vahur Sova. Kamina sepised tegi Heigo Jelle. Trepihallis Tiit Pääsukese maal "Orasnzh". Ill.: I ja II korruse plaan, 14 värv. vaadet

Põlvamaa ettevõtluse Mastimänd on Põlva Agro / Mati Määrits

Index Scriptorium Estoniae

Määrits, Mati, 1958-

2006-01-01

Põlvamaa Mastimänd 2005 tiitli sai piimatootmisega tegelev Põlva Agro parimate toodangunäitajate, innovaatilisuse ning investeeringute eest. Põlvamaa ettevõtluse Tõusev Täht 2005 on AS Nordic Foods ja parim õpilasfirma Pitseto

Eesti meister peresõbralikkuses : Eesti Post / Sulev Oll

Index Scriptorium Estoniae

Oll, Sulev, 1964-

2001-01-01

Äripäeva ning ajakirja Pere ja Kodu konkursil pälvis Eesti kõige peresõbralikuma firma tiitli Eesti Post. Tabel: 30 peresõbralikumat firmat. Tabel: Eesti Post toetuste jagamisel keskmisest heldem

Bols Grand Prix 2014 selgitas parima baarmenite võistkonna ja parima Bols kokteili

Index Scriptorium Estoniae

2014-01-01

12. veebruaril ööklubis Venus Club toimunud 17. Bols Grand Prix võistkondliku võistluse võitis Butterfly Lounge'i võistkond Tallinnast ja parima Bols kokteili tiitli sai Getter Laur Tartust Kivi baarist

Kumu Kunstimuuseum. Felicien Ropsi loomingu näituse "Eros ja Surm" kujundus / Mari Kaljuste, Mari Kurismaa

Index Scriptorium Estoniae

Kaljuste, Mari, 1957-

2007-01-01

plaan, 7 värv. vaadet; fotod: Priit Põldme, Tiit Sermann. M. Kurismaa (näituse kujundus) ja M. Kaljuste (graafiline kujundus) pälvisid Eesti Sisearhitektide Liidu 2006. a. näituse kujunduse preemia

Harvardi tudengid saavad seksiteemalise ajakirja / Kristel Kossar

Index Scriptorium Estoniae

Kossar, Kristel

2004-01-01

Harvardi ülikooli tudengid plaanivad hakata välja andma ajakirja H-Bomb, mis kajastaks seksiteemat Harvardi vaatevinklist. Kommenteerivad TÜ teabejuht Illari Lään, TTÜ teabejuht Tiit Sinissaar ja Riigikogu kultuurikomisjoni esimees Olav Aarna

What has happened to previous Estonian marketing acts? / Ingrid Nielsen

Index Scriptorium Estoniae

Nielsen, Ingrid

2004-01-01

Ülevaade eelnevatel aastatel Eesti turundusteo tiitli pälvinud kampaaniatega seotud ettevõtete, teenuste ja ürituste - EGO järelmaksukaart, EMT ja Eurovisiooni lauluvõistlus - käekäigust, korraldatud reklaamikampaaniate tulemuslikkusest

Ametiühingute arenguteedest / Kadi Pärnits, Margarita Tuch, Harri Taliga

Index Scriptorium Estoniae

Pärnits, Kadi, 1965-

2003-01-01

Ilmunud ka: EAKL Teataja : Narodnaja Gazeta mai lk. 2,4. Järg juuni lk. 2-3. EAKLi juhatuse liikmed ning liitude esindajad arutasid Vihterpalus sotsiaaldialoogi probleeme. Sotsiaalministeeriumi tööosakonna juhataja Tiit Kaadu ettekandest

Romaaniedetabelis troonib "Tappa laulurästast"

Index Scriptorium Estoniae

2008-01-01

Briti internetikaubamaja play.comm korraldatud lugejaküsitlusel võitis kõigi aegade parima romaani tiitli Lee Harperi romaan "Tappa laulurästast", mida on müüdud maailmas üle 30 miljoni ekemplari

Kunstigaleriist pART on võimalik tellida näitust tutvustavaid loenguid / Ülle Lätte

Index Scriptorium Estoniae

Lätte, Ülle, 1955-

2008-01-01

Kunstigalerii pART näitusel "Nad rõõmustavad meid" eksponeeritakse Põltsamaalt pärit kunstnike Tiit Pääsukese, Peeter Alliku, Toivo Raidmetsa, Viive Väljaotsa, Mare Tralla, Ave Nahkuri, Peep Pedmansoni loomingut

Synthesis of Pyridine and Spiropyridine Derivatives Derived from 2-aminoprop- 1-ene-1,1,3-tricarbonitrile Together with their c-Met Kinase and Antiproliferative Evaluations.

Science.gov (United States)

Mohareb, Rafat M; Abouzied, Amr S; Abbas, Nermeen S

2018-02-07

Among a wide range of pyridines, 3-cyanopyridines acquired a special attention due to their wide range of pharmacological activities especially the therapeutic activities. Many pharmacological drugs containing the pyridine nucleus were known in the market. The aim of this work was to synthesize target molecules not only possess anti-tumor activities but also kinase inhibitors. To achieve this goal, our strategy was to synthesize a series of 3-cyanopyridine derivatives using 2-aminoprop-1-ene-1,1,3-tricarbonitrile (1) as the key starting material for many heterocyclization reactions. Muticoponent reactions were adopted using compound 1 to get different pyridine derivatives that were capable for different heterocyclization reactions. Antiproliferative evaluations and c-Met kinase, Pim-1 kinse inhibitions were perform where some compounds gave high activities. Compounds that showed high antiprolifeative activity were tested gor c-Met-independent and the results showed that compounds 5c, 5e, 5f, 7c, 7f and 16d were more active than foretinib. The Pim-1 kinase inhibition activity of some selected compounds showed that compounds 5e and 16c were high potent to inhibit Pim-1 activity. Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.org.

Refractive index effects on the oscillator strength and radiative decay rate of 2,3-diazabicyclo[2.2.2]oct-2-ene.

Science.gov (United States)

Mohanty, Jyotirmayee; Nau, Werner M

2004-01-01

The photophysical properties of 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) were determined in 15 solvents, two supramolecular hosts (cucurbit[7]uril and beta-cyclodextrin) as well as in the gas phase. The oscillator strength and radiative decay rate of DBO as a function of refractive index i.e. polarizability have been analyzed. The oscillator strength increases by a factor of 10 upon going from the gas phase to the most polarizable carbon disulfide, while the corresponding radiative decay rates increase by a factor of 40. There is a good empirical correlation between the oscillator strength of the weakly allowed n,pi* transition of DBO and the reciprocal bulk polarizability, which can be employed to assess the polarizability of unknown microheterogeneous environments. A satisfactory correlation between the radiative decay rate and the square of the refractive index is also found, as previously documented for chromophores with allowed transitions. However, the correlation improves significantly when the oscillator strength is included in the correlation, which demonstrates the importance of this factor in the Strickler-Berg equation for chromophores with forbidden or weakly allowed transitions, for which the oscillator strength may be strongly solvent dependent. The radiative decay rate of DBO in two supramolecular assemblies has been determined, confirming the very low polarizability inside the cucurbituril cavity, in between perfluorohexane and the gas phase. The fluorescence quantum yield of DBO in the gas phase has been remeasured (5.1 +/- 0.5%) and was found to fall one full order of magnitude below a previously reported value.

Tallinna lennujaam - rehielamusse kätketud vene ja prantsuse modernsus / Signe Kalberg

Index Scriptorium Estoniae

Kalberg, Signe, 1959-

2009-01-01

Konkursil "Aasta Betoonehitis 2008" Eesti aasta betoonehitise tiitli pälvinud Tallinna lennujaama reisiterminali laiendusest. Arhitekt: Jean-Marie Bonnard, Sofreavia SA, Prantsusmaa. Projekteerija: AS EA Reng. Konstruktsioonid: OÜ Inseneribüroo Pike. Ehitaja: AS Skanska EMV

Kes peaks katma õpilasekskursiooni kulud? / Sirje Tobreluts, Riho Kutsar, Aire Orula ... [jt.

Index Scriptorium Estoniae

2012-01-01

Küsimusele vastavad: Laheda vallavanem Sirje Tobreluts, Aseri keskkooli direktor Riho Kutsar, lapsevanem ja loodusgiid Aire Orula, Lähte ühisgümnaasiumi meediaõpetaja ja lapsevanem Tiit Helm ja Haridus- ja Teadusministeeriumi konsultant Asso Ladva

David James O'Brock-Kaljuvee : Viru Liimid oli omaniku kallis hobi / David James O'Brock-Kaljuvee ; interv. Gerli Romanovitsh

Index Scriptorium Estoniae

O'Brock-Kaljuvee, David James, 1970-

2005-01-01

Ilmunud ka: Severnoje Poberezhje : Subbota. AS-i Viru Liimid juhatuse esimees oma ettevõttest, mille välismüük on kasvanud 20% ning esimest korda ollakse kasumis. Arvamust avaldavad Lembit Kaljuvee ja Tiit Vau

Sure ära ehk Ka kriitiku käes on ligimese saatus / Silver Vahtre

Index Scriptorium Estoniae

Vahtre, Silver

2006-01-01

Vastuseks 2005. aasta sõnalavastuste žürii otsusele Tiit Palu lavastusele "Mis värvi on vabadus" Endlas. Oma mõtteid avaldab lavastuse kunstnik Silver Vahtre. (7. apr. "Sirbi" intervjuu Reet Neimari ja Madis Kolgiga)

Saalomon ja Raul / Jaak Jõerüüt

Index Scriptorium Estoniae

Jõerüüt, Jaak, 1947-

2010-01-01

Raul Meele näitus Genti ülikooli raamatukogus 20.04.- 28.05.2010. Kunstniku kunstnikuraamat üheteistkümnes keeles: Meel, Raul. Salomon's Song of Songs = Saalomoni Ülemlaul / kujundanud Tiit Jürna. Tallinn, 2010

Eramu ja vaatetorn = Residential building and a viewing tower

Index Scriptorium Estoniae

2015-01-01

Tähevälja eramu ja vaatetorn Kiiu-Aabla külas Kuusalu vallas, valminud 2013. Arhitektuurivõistlus 2009. Maja arhitekt Martin Aunin, sisearhitekt Tiit Jürna. Vaatetorni arhitektid Martin Aunin, Martin Melioranski. Konstruktor Urmas Rasina

Short outlines of books by Estonian authors / Rutt Hinrikus, Janika Kronberg

Index Scriptorium Estoniae

Hinrikus, Rutt, 1946-

2002-01-01

Ehlvest, Jüri. Taevatrepp ; Suuman, Aleksander. Tondihobu tõugud vetikatega ; Õunapuu, Ervin. Mõõk. Nagu jõgi ; Nigov, Anton. Harjutused ; Hainsalu, Lehte. Kellakuuljad ; Heinsaar, Mehis. Härra Pauli kroonikad ; Bristol, Piret. Sajandi öömajad ; Kas kuulete...? : [kuuldemängud] / koost. Tamur Tohver; Rummo, Paul-Eerik. Kohvikumuusikat ; Käsper, Kalle. Vennad Luiged ; Põldroos, Enn. Mees narrimütsiga ; Remsu, Olev. Margit Puusaag ja tema mehed ; Sauter, Peeter. Pori

Euroopa filmieliit kohtub 2010. aastal Tallinnas / Kristiina Davidjants

Index Scriptorium Estoniae

Davidjants, Kristiina, 1974-

2007-01-01

Euroopa Filmiakadeemia auhinnatseremoonia toimub 2010.a. Eestis. Selle aasta parima Euroopa filmi tiitli sai rumeenlase Cristiam Mungiu film "4 kuud, 3 nädalat ja 2 päeva". Lisatud nimekiri "Euroopa Filmiakadeemia tänavused laureaadid"

Spordipreemiad leidsid omaniku / Anne Põder

Index Scriptorium Estoniae

Põder, Anne, 1973-

2007-01-01

Järvamaa omavalitsuste liit ja spordiliit tunnustasid maakonna parimaid sportlasi, kelleks osutusid Ain-Alar Juhanson, Mikko Vanaisak, Viktoria Leks ja Grit Shadeiko. Spordiedendaja preemia sai Tiit Kavak, spordi elutöö preemia pälvis Enn Sõmeri

Kuldgloobuse auhinnad leidsid omanikud / Marko Lillemägi

Index Scriptorium Estoniae

Lillemägi, Marko

2007-01-01

Kuldse Gloobuse auhinna galast. Draamakategoorias võitis mängufilm "Paabel" ("Babel"), režissöör Alejandro Gonzalez Inarritu. Ka teised Golden Globe filmiauhinna saajad; lisad : Tiit Tuumalu kommentaar "Segane seis" ja võitjate nimekiri

Kas president peaks Asso Kommerile armu andma? : kuueks ja pooleks aastaks vangi mõistetud endine jäägripealik Asso Kommer esitas veebruari lõpul armuandmispalve

Index Scriptorium Estoniae

1998-01-01

Eesti Päevalehe küsitlusele vastavad EELK Põlva Maarja koguduse kirikuõpetaja Üllar Kask, Medica Arstikeskuse perearst Ahti Virkus, AS Ius Dicere tegevdirektor Reigo Kala, Tallinna volikogu liige Arved Liivrand, Riigikogu majanduskomisjoni esimees Tiit Made

57. Baltisches Historikertreffen : vom 5. bis 6. Juni 2004 in Göttingen

Index Scriptorium Estoniae

2004-01-01

57. balti ajaloolaste kohtumisel 5.-6. juunini 2004 esinesid ettekannetega Erki Tammiksaar, Tiit Rosenberg, Olaf Mertelsmann, Klaus Neitmann, Matthias Thumsen, Ilgvars Misans, Henrik Bolte, Thomas Brück, Juhan Kreem, Dieter Heckmann, Stefan Hartmann. Ettekannete kokkuvõtted

Kurortnõi roman : energetika i tranzit / Jevgeni Ashihmin

Index Scriptorium Estoniae

Ashihmin, Jevgeni

2008-01-01

Majandus- ja kommunikatsiooniminister Juhan Parts, IRL-i juht ja parlamendiliige Mart Laar ning kontserni Silmet Grupp juht Tiit Vähi kohtusid Ida-Virumaa suurettevõtete juhtidega. Arutati põlevkivienergeetika tulevikku, transiidiküsimusi ja Vene-Eesti suhteid

LHV teenindusbüroo = LHV Service Bureau

Index Scriptorium Estoniae

2012-01-01

LHV Panga teenindusbüroo (Tallinn, Tartu mnt. 2) sisekujundusest. Sisearhitektid Kerli Lepp ja Pille Lausmäe (Pille Lausmäe SAB), loetletud nende ühiselt tehtud töid. Arhitektid Andres Alver ja Tiit Trummal

Leo Burnett wins agency of the year title in Estonia and Lithuania

Index Scriptorium Estoniae

2004-01-01

Eesti Kuldmuna reklaamikonkursil, Leedu reklaamifestivalil Adrenalinas aasta reklaamiagentuuri tiitli pälvinud ettevõttest Kontuur Leo Burnett. Madis Laas, Tomas Ramanauskas ja Marius Petrukaitis vastavad küsimustele firma edu võimalike põhjuste ja tulevikuplaanide kohta

Rhodium-catalyzed [5 + 2 + 1] cycloaddition of ene-vinylcyclopropanes and CO: reaction design, development, application in natural product synthesis, and inspiration for developing new reactions for synthesis of eight-membered carbocycles.

Science.gov (United States)

Wang, Yi; Yu, Zhi-Xiang

2015-08-18

Practical syntheses of natural products and their analogues with eight-membered carbocyclic skeletons are important for medicinal and biological investigations. However, methods and strategies to construct the eight-membered carbocycles are limited. Therefore, developing new methods to synthesize the eight-membered carbocycles is highly desired. In this Account, we describe our development of three rhodium-catalyzed cycloadditions for the construction of the eight-membered carbocycles, which have great potential in addressing the challenges in the synthesis of medium-sized ring systems. The first reaction described in this Account is our computationally designed rhodium-catalyzed two-component [5 + 2 + 1] cycloaddition of ene-vinylcyclopropanes (ene-VCPs) and CO for the diastereoselective construction of bi- and tricyclic cyclooctenones. The design of this reaction is based on the hypothesis that the C(sp(3))-C(sp(3)) reductive elimination of the eight-membered rhodacycle intermediate generated from the rhodium-catalyzed cyclopropane cleavage and alkene insertion, giving Wender's [5 + 2] cycloadduct, is not easy. Under CO atmosphere, CO insertion may occur rapidly, converting the eight-membered rhodacycle into a nine-membered rhodacycle, which then undergoes an easy C(sp(2))-C(sp(3)) reductive elimination process and furnishes the [5 + 2 + 1] product. This hypothesis was supported by our preliminary DFT studies and also served as inspiration for the development of two [7 + 1] cycloadditions: the [7 + 1] cycloaddition of buta-1,3-dienylcyclopropanes (BDCPs) and CO for the construction of cyclooctadienones, and the benzo/[7 + 1] cycloaddition of cyclopropyl-benzocyclobutenes (CP-BCBs) and CO to synthesize the benzocyclooctenones. The efficiency of these rhodium-catalyzed cycloadditions can be revealed by the application in natural product synthesis. Two eight-membered ring-containing natural products, (±)-asterisca-3(15),6-diene and (+)-asteriscanolide, have been

Eesti paviljon Hannoveri maailmanäitusel EXPO 2000 = Estonian Pavilion at Hannover World Exposition EXPO 2000 / Andrus Kõresaar

Index Scriptorium Estoniae

Kõresaar, Andrus

2000-01-01

Eesti paviljoni arhitektuurist. Autorid Andrus Kõresaar, Raivo Kotov. Sisekujundajad A. Kõresaar, R. Kotov, Tiit Tael, Hannes Praks. Konstruktsioonid: Neoprojekt. Saksamaa-poolne kontaktarhitektuuribüroo: KSP Engel & Zimmermann. 15 ill.: korruste plaanid, lõiked, välis- ja sisevaated

Pala kooli direktor Malle Weinrauch muretseb maakoolide tuleviku pärast / Eva Klaas

Index Scriptorium Estoniae

Klaas, Eva

2003-01-01

Konkursi "Eestimaa kauneim kool" tiitli võitnud Anna Haava nimelisest Pala koolist. Kooli direktor Malle Weinrauch'i sõnul oli president Arnold Rüütli külaskäik suursündmus nii kooli õpetajatele kui õpilastele

11. I avati rahvusraamatukogu peanäitusesaalis...

Index Scriptorium Estoniae

2006-01-01

Eesti Rahva Muuseumi fotonäitus "Inimnäoline islam". Väljas on paarikümne eesti harrastusfotograafi tehtud pildid. Näituse koostasid Leida Lepik, Jaanus Plaat ja Tiit Pruuli. Näitusega kaasneb raamat "Inimnäoline islam"

Kalli ajaloosarja esikfilm jõuab ETVsse / Kiur Aarma ; interv. Andri Maimets

Index Scriptorium Estoniae

Aarma, Kiur, 1975-

2005-01-01

6-osalise ajaloodokumentaalide sarja "Kuum külm sõda" esimesena valminud, sisuliselt kolmas film "Haukka grupp" : stsenaristid Kiur Aarma, Tiit Pruuli : režissöör Rene Vilbre : Ruut Pictures 2005. Esilinastus 08.05. kinos "Sõprus"

Ametnikud naudivad piiramatuid lisatasusid / Kaire Uusen

Index Scriptorium Estoniae

Uusen, Kaire

2004-01-01

Eestis lubab valitsuse määrus maksta riigiteenistujatele piiramatus ulatuses lisatasu, Euroopa Liidu maades saavad ametnikud tulemustasu 10-15% palgast. Lisa: Lisatasud võivad tuua suurema osa palgast. Kommenteerivad: Christoph Demmke, Hans Peter Larsen ja Tiit Randla

City Plaza büroohoone : Tartu mnt. 2, Tallinn = City Plaza office building : Tartu maantee 2, Tallinn

Index Scriptorium Estoniae

2006-01-01

Arhitektid: Tiit Trummal, Andres Alver, Martin Melioranski, Indrek Rünkla, AB Alver Trummal Arhitektid. Eesti Kultuurkapitali arhitektuuri sihtkapitali 2005. a. objektipreemia. Žürii liikme Ado Eigi arvamus. 5 värv. välis- ja 4 sisevaadet

Mart Laar - visionäärina kuulsam välismaal / Kertu Ruus

Index Scriptorium Estoniae

Ruus, Kertu, 1977-

2005-01-01

Maailmas on kümneid riike, kes imetlevad meie endise peaministri Mart Laari reforme Eestis. Kommenteerivad Margaret Thatcher, Alfredo Arias-King ja Tiit Vähi. Vt. samas: Väljavõtteid Mart Laari kohta ajakirjandusest; Laia haardega tegutseja: Liikmelisus

Mine vaatama!

Index Scriptorium Estoniae

2005-01-01

Eesti Loodusmuuseumis 23. II-14. IV Kaupo Klooreni puust amulettide näitus, 16.-30. IV Tiit Leito fotonäitus "Metsamaastikud". Eesti Põllumajandusmuuseumis 7. III-15. IX Tan Silliksaare ja Tõnu Lingi fotonäitus "Maameeste maastikud"

Trebujutsja Minin i Pozharski / Anna Hrustaljova

Index Scriptorium Estoniae

Hrustaljova, Anna

2004-01-01

Vene filmifestival "Moskovskaja premjera" ja seal esile tõstetud filmid : "Shiza" ( režissöör Gulshad Omarova), "Pikk hüvastijätt" ("Dolgoje proshtshanije"), parima režissööri tiitli saanud Sergei Ursuljak)

Galerii tahab endale kesklinna villa osta / Mehis Pärnamets

Index Scriptorium Estoniae

Pärnamets, Mehis

2007-01-01

Kaitseliidule kuuluv villa Doll Viljandis läheb augustis korraldataval oksjonil enampakkumisele. Majas näitusi korraldanud Noore Linna galerii soovib hoonet osta. Kommenteerivad major Ülar Vomm ja ärimees Tiit Maisa. Mõlemad pooldavad maja kasutamist kultuuriobjektina

Occurrence of (Z)-3,4-Dideoxyglucoson-3-ene in Different Types of Beer and Malt Beer as a Result of 3-Deoxyhexosone Interconversion.

Science.gov (United States)

Hellwig, Michael; Nobis, Arndt; Witte, Sophia; Henle, Thomas

2016-04-06

In beer, 3-deoxyglucosone (3-DG) and 3-deoxygalactosone (3-DGal) are important sugar degradation products, but little is known about the relevance of the interconversion reaction between these compounds in different types of beer. In the present study, 3-DG was quantitated at concentrations of 12.9-52.7 mg/L and 3-DGal at concentrations of 6.0-26.4 mg/L in different types of beer (pilsner, wheat, bock, dark, and alcohol-free beers). The concentrations in malt beer tended to be higher. Largely overlapping concentration ranges precluded a classification of beers by their 3-deoxyglycosone contents. 3,4-Dideoxyglucoson-3-ene (3,4-DGE) was identified as an important intermediate and quantitated in beer and malt beer for the first time. The E and Z isomers of the corresponding quinoxaline were synthesized by a new synthetic approach and isolated by semipreparative HPLC. An assay was developed for quantitation of (E)- and (Z)-3,4-DGE by HPLC-MS/MS, and the Z isomer was determined at concentrations of 0.3-1.7 mg/L in beer and 0.5-4.8 mg/L in malt beer samples. The E isomer was shown to be of little importance. Concentrations of 5-hydroxymethylfurfural (HMF) were twice as high as those of (Z)-3,4-DGE in beer samples (0.4-3.7 mg/L) but much higher in malt beer samples (1.6-336 mg/L).

Photo-initiated polymerisation of 1,8-octanedithiol and styrene

International Nuclear Information System (INIS)

Ang, J.B.; Hill, D.J.T.; Pomery, P.J.; Whittaker, A.K.

1998-01-01

Full text: Photo-initiated polymerisation of the thiol-ene system has been well investigated. Its applications include adhesives, coatings and opthalmic lenses. It is unlike the usual UV curable polymeric systems which are predominantly based on acrylates. Typically, acrylate systems are not strictly stoichiometric reactions. The thiol-ene process is a reactive composition based on the stoichiometric reaction of olefins (enes, acrylates) and thiols (mercaptans), which polymerise on exposure to UV light. A unique feature of the thiol-ene system is that the reaction is not inhibited by dissolved or ambient oxygen within the system, thereby eliminating the termination reaction which occurs in acrylate systems. The mechanism of the thiol-ene reaction is a step growth addition process which propagates by a free radical chain mechanism to yield the anti-Markovnikov product scheme. The majority of thiol-ene systems investigated focus on multifunctional moieties of thiol and olefin to produce highly cross-linked networks. This discussion will focus on kinetic information obtained from a linear system comprised of a disfunctional thiol (1,8-octanedithiol) and styrene initiated by a UV light source

ADrenalinas 2005

Index Scriptorium Estoniae

2005-01-01

3. juunil Leedus toimunud 3. reklaamifestivalil ADrenalina jagas rahvusvaheline žürii välja auhinnad 29 kategoorias, millest 18 läksid Leo Burnett Vilniusele, mis võitis sellega teistkordselt "Aasta agentuuri" tiitli. Lisa: Advertising festival "ADrenalinas" 2005

Pärast teatrikuudki tuleb Eesti lavadele esietendusi lademes / Andres Laasik

Index Scriptorium Estoniae

Laasik, Andres, 1960-2016

2008-01-01

Tutvustatakse hooaja lõpu lavastusi Vene Teatris ja Nukuteatris ning arvustatakse NO99 teatris esietendunud Shakespeare'i "Periklest" Tiit Ojasoo lavastuses ja "Pommimängu" Endlas Joseph Helleri näidendi "Me pommitasime New Havenit" ainetel Madis Kalmeti lavastuses

Balteco esitleb : loodusest inspireeritud - puhas ja kordumatu vorm

Index Scriptorium Estoniae

2010-01-01

Parima Disaini rakrendaja tiitli 2010. aastal pälvinid Balteco (disainijuht Aivar Habakukk) Onyx kivivannide sarjast, vannidest Rego (Sven Sõrmus, 2010), Senzo (Harri Ehrlich, 2010), Pao (Matti Õunapuu, 2008), dušialustest Visio ja Vibe, massaaživannidest

President kritiseeris koolide kinnisvara arendamise kava

Index Scriptorium Estoniae

2004-01-01

Ilmunud ka ajalehes Koit (2004/Sep/18) lk. 2. President Arnold Rüütli ja haridus- ja teadusminister Toivo Maimetsa ettekannetest üleriigilisel konverentsil "21. sajandi haridus". Üldhariduskoolide kinnisvara arendamise programmi tutvustas Riigi Kinnisvara ASi projektidirektor Tiit Kerem

Väikeste sammudega saab jõudsamalt edasi liikuda / Liisi Seil

Index Scriptorium Estoniae

Seil, Liisi, 1971-

2009-01-01

Täiskasvanud õppija nädala raames tunnustati Viljandimaa aasta parimaid. Aasta õppija tiitli pälvis OÜ Sveba-Dahlen tootmistehnik Raul Järve, aasta koolitaja on vabakutseline õpetaja Enn Onni ning aasta koolitussõbralikemaks omavalitsuseks tunnistati Tarvastu Vallavalitsus

Siidii / Kreete Reval

Index Scriptorium Estoniae

Reval, Kreete

2003-01-01

Heliplaatidest: Johnny Cash "American IV: The Man Comes Around", Monumentum "Ad Nauseam", Oakenfold "Bunkka", Sibul, Riho "Estonian Dream Big Band", Eesti Filharmoonia Kammerkoor "Baltic Voices 1", Villu Veski & Tiit Kalluste "Põhjala saarte hääled", Meredith Monk "Mercy"

Tapa firma tituleeriti halvimaks tööandjaks / Marina Loštšina

Index Scriptorium Estoniae

Loštšina, Marina

2006-01-01

Ilmunud ka: Pärnu Postimees 21. märts lk. 9. Eesti Transpordi- ja Teetöötajate Ametiühing andis aasta halvima tööandja tiitli OÜ-le Tapa Autobussipark üleriigilise palgaleppe pideva eiramise eest

Filmikunst saab igamehe bisniseks / Priit Pullerits

Index Scriptorium Estoniae

Pullerits, Priit, 1965-

2000-01-01

Eesti Aasta Film '99 tiitli saanud 26-aastase Marko Raadi "Esteetilistel põhjustel" näitab suundumust, et väga väikeste rahadega võivad andekad inimesed teha häid filme, mis konkureerivad suure eelarvega linateostega

Helen Mirren võitis Elizabeth II rolliga brittide Oscari / Triin Tael

Index Scriptorium Estoniae

Tael, Triin

2007-01-01

Stephen Frearsi mängufilmis "Kuninganna" ("The Queen") kuninganna Elizabeth II kehastav Helen Mirren sai oma rolli eest parima naisnäitleja Bafta (Briti filmiakadeemia auhind). Linateos pälvis ka aasta parima filmi tiitli. Ka teistest võitjatest

Aasta põllumeheks 2003 sai Johannes Valk / Mati Jakson

Index Scriptorium Estoniae

Jakson, Mati

2003-01-01

Aasta põllumehe tiitli kätteandmisest Rahvusraamatukogus, kus esines tervitussõnavõtuga ka president Arnold Rüütel. 2003. aasta põllumeheks valitud Harjumaa suurtalunik Johannes Valk andis lühiülevaate Laheotsa talu tegevusest 2003. aastal

Eramu Nõmmel = House in Nõmme / Piret Lindpere

Index Scriptorium Estoniae

Lindpere, Piret, 1963-

2002-01-01

Vabaduse puiesteel 2000. a. valminud eramu projekteeris arhitekt Jaan Ollik. Kujunduskonsultant Tiit Jürna kavandas CD-riiulid, lauad jm. Lihtsa musta maja väljapaistvaim osa on läbi kahe korruse ulatuv klaasist raamatukogu. 7 ill.: plaanid, vaated

Nunnufaktor korda kaks / Karri Kaas

Index Scriptorium Estoniae

Kaas, Karri, 1982-

2009-01-01

Betty Thomase animafilmist "Alvin ja koopaoravad 2", USA 2009. Järg 2007. a. menukomöödiale. Tegelastele annavad eesti keeles oma hääled Anatoli Tafitšuk, Maarius Pärn, Veiko Anvelt, Tiit Sukk ja teised

Kasv tuleb europrojektidest / Madli Kents

Index Scriptorium Estoniae

Kents, Madli

2003-01-01

Audiitorfirmade TOP 50 3. koht. Deloitte & Touche Eesti AS-i nõukogu esimehe Tiit Järve sõnul saavutas ettevõte konkurentsieelise europrojektide ja rahvusvahelise emafirma toetuse tõttu. Diagramm: Tänavu ootab ees parem tulemus. Kommenteerib Mati Nõmmiste

Rafineeritud naudingud : kuumaveeallikad Valsis (Šveits)

Index Scriptorium Estoniae

1998-01-01

Peter Zumthori (sünd. 1943) projekteeritud, 1997. a. valminud supelasutusest Alpides Valsi kuurordis. Kalju sisse uuristatud veekompleksi ehitusmaterjaliks on kivim gneiss. 1997. a. Euroopa parima ehitise tiitli sai napilt Valsi supelasutuse ees Pariisi uus rahvusraamatukogu (arhitekt D. Perrault).

Oma kool - parim kool! / Maris Kütt, Mirli Isak

Index Scriptorium Estoniae

Kütt, Maris

2012-01-01

Võru 1. Põhikool tähistab 220 aastapäeva. Artiklisse on kogutud praeguste õpilaste vastused küsimusele, mida nad arvavad oma auväärsesse ikka jõudnud koolist. Ka TLÜ rektori Tiit Landi meenutused oma kooliajast

2 ühe hoobiga. Uusi kinolevi filme tutvustab Tiit Tuumalu / Tiit Tuumalu

Index Scriptorium Estoniae

Tuumalu, Tiit, 1971-

2008-01-01

Õudusmuusikal "Sweeney Todd : Fleet Streeti deemonlik habemeajaja" Stephen Sondheimi muusikali alusel : režissöör Tim Burton : peaosas Johnny Depp : Ameerika Ühendriigid - Suurbritannia 2007 ja muusikaline draama "Ükskord" ("Once") : režissöör John Carey : Iirimaa 2006

The traditional medicine Spilanthes acmella, and the alkylamides spilanthol and undeca-2E-ene-8,10-diynoic acid isobutylamide, demonstrate in vitro and in vivo anti-malarial activity

Science.gov (United States)

Spelman, Kevin; Depoix, Delphine; McCray, Megan; Mouray, Elisabeth; Grellier, Philippe

2010-01-01

Spilanthes spp. are used as traditional herbal medicines in Africa and India to treat malaria. Yet, to date, there is no data on active constituents or most effective extraction methods for this indication. The isolated alkylamides, spilanthol and undeca-2E-ene-8,10-diynoic acid isobutylamide, found in S. acmella Murr., were shown to have IC50s of 16.5 μg/mL and 41.4 μg/mL on Plasmodium falciparum strain PFB and IC50s of 5.8 μg/mL and 16.3 μg/mL for the chloroquine resistant P. falciparum K1 strain, respectively. Further investigations revealed that at relatively low concentrations, spilanthol and the water extract of S. acmella reduced the parasitemia 59% and 53% in mice infected with P. yoelii yoelii 17XNL at 5 mg/kg and 50 mg/kg, respectively. Unexpectedly, the 95% ethanol extract of S. acmella was less effective (36% reduction in parasitemia) at 50 mg/kg. These results provide the first evidence supporting S. acmella against malaria and demonstrating active constituents in S. acmella against P. falciparum. PMID:22692989

Olemise ja unustamise vahel : World Press Photo '98 / Ants Juske

Index Scriptorium Estoniae

Juske, Ants, 1956-2016

1998-01-01

Parimate pressifotode rändnäitusest. Konkursil osales 3627 fotograafi, Eestist Tiit Räis ja Viktor Vesterinen. Aasta parimaks tunnistati alžeeria fotograafi Hocine pilt naisest massimõrva ohvrite haigla juures. Paremini müüvad fotod katastroofidest

Kange prooviga Eesti kuld / Kristel Kossar

Index Scriptorium Estoniae

Kossar, Kristel

2008-01-01

Marina Kaljurannal täitub juulis kolm aastat suursaadikuna Venemaal, see aeg tõi talle mullu Eesti aasta inimese lugupidava tiitli. Marie Claire veetis temaga Moskvas ühe päeva, et tuua tükike suursaadiku elust miljonilinnas oma lugejateni

ABB honoured in Estonia

Index Scriptorium Estoniae

2008-01-01

Energeetikafirma ABB pälvis Ettevõtluse Arendamise Sihtasutuse poolt Eesti parimale ettevõttele antava "Ettevõtluse Auhinna 2008" ja Aasta Välisinvestori tiitli. 18. septembril 2008 toimunud pidulikul tseremoonial autasustas president Toomas Hendrik Ilves ABB Balti riikide juhti Bo Henrikssoni

IBBY kongressist Londonis / Piret Raud

Index Scriptorium Estoniae

Raud, Piret, 1971-

2012-01-01

Rahvusvahelisest Noorsookirjanduse Nõukogu kongressist Londonis, mis kandis pealkirja "Ületades piire: tõlked ja ränded". Kongressil anti üle ka Hans Christian Anderseni auhinnad. Kirjanikupreemia sai María Teresa Andruetto ja parima illustraatori tiitli Peter Sís.

Eesti film - needusega? / Margot Visnap

Index Scriptorium Estoniae

Visnap, Margot, 1959-

2006-01-01

Mängufilm "Libahundi needus" : stsenaristid Margus Kasterpalu, Ilmar Raag ja Rainer Sarnet : režissöör Rainer Sarnet : osades Katariina Lauk, Rene Reinumägi, Raine Loo, Kersti Kreismann, Marje Metsur, Tiit Lilleorg : Shop of Dreams - Eesti Televisioon 2005

Lugu mehest, kes oli iseenda naine / Kaja Roomets

Index Scriptorium Estoniae

Roomets, Kaja

2008-01-01

Doug Wrighti "Ma olen iseenda naine" Endla teatris, lavastaja Tiit Palu. Esietendus 27. juunil. Lisaks saksa päritolu transvestiidist Charlotte von Mahlsdofist (1928-2002) : "Charlotte oli fenomen" ja Kati Murutari ning Raivo Järvi arvamus : "Mis tunde esietenduselt kaasa saite?"

"Dozhd" Jurija Lotmana / Anastasia Semjonova

Index Scriptorium Estoniae

Semjonova, Anastasia

2006-01-01

Juri Lotmani mälestusmärgi konkursi võidutöödest. Võitnud kavandist "Vihm". Võidutööde autorid avalikustatakse 10. juulil Raatuse tänava ühiselamus avataval kavandite näitusel. Kommenteerib Tartu linnakunstnik Tiit Kaunissaare

The lacuna, an empty space in urban construction. Cesare Brandi's restoration theory in the integral preservation of old town areas / Lilian Hansar

Index Scriptorium Estoniae

Hansar, Lilian, 1949-

2008-01-01

Cesare Brandi (1906-1988) restaureerimisteooriast ja vanalinna kui kunstiteose terviklikust säilitamisest, uute hoonete sulandamisest ning renoveerimisest. Ka Ferrumi Kaubamaja uue hoone heast sobivusest Kuressaare vanalinna - arhitektid Andres Alver, Tarmo Laht, Indrek Rünkla, Ulla Mets ja Tiit Trummal

Avati Deco Galerii Boutique

Index Scriptorium Estoniae

2000-01-01

Eragalerii Deco asutajad Epp ja Tiit Rebane avasid Vana-Posti 2 Deco Galerii Boutique, kus pakutakse vaadata ja müüa minimaali, -graafikat ja vitraaže (loetletud kunstnikke). Kadriorus asunud Deco lõpetas tegevuse rendilepingu lõppemise tõttu

Tammsaar muutis kohtus tunnistusi / Hindrek Riikoja

Index Scriptorium Estoniae

Riikoja, Hindrek

2008-01-01

Ilmunud ka: Postimees : na russkom jazõke 15. mai lk. 4. Jõgeval toimunud Tartu maakohtu istungist, kus Werolist väidetavalt väljakanditud rahast 600 000 krooni saanud endine põllumajandusminister Tiit Tammsaar tunnistusi andes muutis varasemaid ütlusi

Kas võidab teater või sihikindel needus ? / Matis Song

Index Scriptorium Estoniae

Song, Matis, 1978-

2006-01-01

Mängufilm "Libahundi needus" : stsenaristid Margus Kasterpalu, Ilmar Raag ja Rainer Sarnet : režissöör Rainer Sarnet : osades Katariina Lauk, Rene Reinumägi, Raine Loo, Kersti Kreismann, Marje Metsur, Tiit Lilleorg : Shop of Dreams - Eesti Televisioon 2005

C60 and Sc3N@C80(TMB-PPO derivatives as constituents of singlet oxygen generating, thiol-ene polymer nanocomposites

Directory of Open Access Journals (Sweden)

Ashli R. Toles

2016-07-01

Full Text Available Numerous functionalization methods have been employed to increase the solubility, and therefore, the processability of fullerenes in composite structures, and of these radical addition reactions continue to be an important methodology. C60 and Sc3N@C80 derivatives were prepared via radical addition of the photodecomposition products from the commercial photoinitiator TMB-PPO, yielding C60(TMB-PPO5 and Sc3N@C80(TMB-PPO3 as preferred soluble derivatives obtained in high yields. Characterization of the mixture of isomers using standard techniques suggests an overall 1PPO:6TMB ratio of addends, reflecting the increased reactivity of the carbon radical. Although, a higher percentage of PPO is observed in the Sc3N@C80(TMB-PPO3 population, perhaps due to reverse electronic requirements of the substrate. Visually dispersed thiol-ene nanocomposites with low extractables were prepared using two monomer compositions (PETMP:TTT and TMPMP:TMPDE with increasing fullerene derivative loading to probe network structure-property relationships. Thermal stability of the derivatives and the resulting networks decreased with increased functionality and at high fullerene loadings, respectively. TMPMP:TMPDE composite networks show well-dispersed derivatives via TEM imaging, and increasing Tg’s with fullerene loading, as expected for the incorporation of a more rigid network component. PETMP:TTT composites show phase separation in TEM, which is supported by the observed Tg’s. Singlet oxygen generation of the derivatives decreases with increased functionality; however, this is compensated for by the tremendous increase in solubility in organic solvents and miscibility with monomers. Most importantly, singlet oxygen generation from the composites increased with fullerene derivative loading, with good photostability of the networks.

Mustamäe Maarja Magdaleena kiriku arhitektuurivõistlus = Architecture competition for Mustamäe`s Church of Mary Magdalene / Pille Epner

Index Scriptorium Estoniae

Epner, Pille

2013-01-01

Arhitektuurikonkursist, võidutööst "Fiat Lux" (arhitektid Risto Parve, Kai Süda, Martin Kinks, Margit Valma, arhitektuuriteadlane Mait Väljas, Karisma Arhitektid), 2. koha pälvinud tööst "Õhuke Koht" (Pille Noole, Üllar Ambos, Kaisa Lasner, Kerttu Karjust, Jiannis Lykouras, Arhitektuurinurk), 3. koha pälvinud tööst "Tee" (Villem Tomiste, Stuudio Tallinn). Loetletud ostupreemia ja kolm tunnustuse pälvinud võistlustööd

Kuldala elamurajoon : Rae vald, Harjumaa = Kuldala Residential Community : Rae municipality, Harju County / Triin Ojari

Index Scriptorium Estoniae

Ojari, Triin, 1974-

2008-01-01

Arhitektuurne projekt: KOKO Arhitektid. Kutsutud konkurss 2004, autorid: Lembit-Kaur Stöör, Margus Maiste, Raivo Kotov, Tõnis Kimmel. Hoonete projekteerimine: Lembit-Kaur Stöör, Margus Maiste, Olga Batuhtina. Maastikuarhitektuur: Margit Kärner. Projekt: 2005-2006. Lembit-Kaur Stöör arhitektuurikonkursist, planeeringust, elamute arhitektuurist, fassaadidest, ehitusest, sisehoovist. Joonised: vaade, I-IV korruse plaan (2), planeeringu makett, 5 värv. fotot: 3 välis- ja 2 sisevaadet

Simpsonite isa / Margit Tõnson

Index Scriptorium Estoniae

Tõnson, Margit, 1978-

2007-01-01

Joonisfilmi "Simpsonite film" ("The Simpsons Movie") maailmaesilinastuste puhul seriaali looja, Kanada päritolu Matt Groeningist ja tema loodud seriaali populaarsuse fenomenist. Lisaks filmi süzheest "Mees peab oma naist kuulama!" (režissöör David Silverman)

Margit Ellinor: forgotten images

Directory of Open Access Journals (Sweden)

Bente Geving

2014-10-01

Full Text Available I began photographing my mother’s room in 2002. Around that time she began changing the arrangements of pictures and ornaments, fetching things out that had been stored in cupboards and drawers, and putting away other things that had previously been features of the room. She assembled various objects on tables, shelves and in cupboards. She tidied and sorted. I became fascinated by the colours of her compositions, and wanted to enter her world.

"Piinakambri" perenaine / Margit Tõnson

Index Scriptorium Estoniae

Tõnson, Margit, 1978-

2010-01-01

2009. a. filmiloomingu kuus Oscarit sai Kathryn Bigelow mängufilm "Piinakamber". Selle võiduga on ta esimene naisrežissöör, kes võitnud parima lavastaja auhinna. Sõjafilmist, mille tegevus toimub Iraagis ja mis räägib pommirühma igapäevasest elust

Olla ise / Margit Tõnson

Index Scriptorium Estoniae

Tõnson, Margit, 1978-

2008-01-01

Filmisarjas "Ainult friikidele" linastub Tallinnas Sõpruse kinos ja Tartus Athena Keskuses John Cassavetese mängufilm "Naise parimad aastad" ("A Woman Under the Influence") : Ameerika Ühendriigid 1974