Identification of low-lying proton-based intruder states in 189-193Pb

International Nuclear Information System (INIS)

Vel, K. van de; Andreyev, A.N.; Huyse, M.; Duppen, P. van; Cocks, J.F.C.; Dorvaux, O.; Greenlees, P.T.; Helariutta, K.; Jones, P.; Julin, R.; Juutinen, S.; Kettunen, H.; Kuusiniemi, P.; Leino, M.; Muikku, M.; Nieminen, P.; Eskola, K.; Wyss, R.

2002-01-01

Low-lying proton-based intruder states have been observed in the odd-mass isotopes 189,191,193 Pb in experiments at the RITU gas-filled recoil separator. The identification has been performed by observing the fine structure in the α decay of the parent 193,195,197 Po nuclei in prompt coincidence with conversion electrons and γ rays in the daughter lead isotopes. Along with the literature data these results establish a systematics of intruder states in the odd-mass lead isotopes from 197 Pb down to 185 Pb. Interpretation of these states involves the coupling of the 1i 13/2 or 3p 3/2 odd neutron to the 0 + state in the oblate minimum in the even-mass lead core. Conversion coefficients have been determined for some of the transitions, revealing mixing between the coexisting states. The experimental results are compared to potential energy surface calculations

Spectroscopic features of the low-lying electronic states of some sodium-helium and potassium-helium van der Waals systems

Science.gov (United States)

Chattopadhyay, Anjan

2011-08-01

Configuration interaction studies on MHe and MHe2 (where M = Na, K) systems have revealed several interesting characteristics in the properties of their low-lying electronic states. Binding energy values of the 12Π1/2, 3/2 states in MHe systems are found to be lower than the values of 12Πu (1/2, 3/2) states in the He-M-He systems by a margin of more than 200 cm-1, indicating better exciplex stabilities of the latter systems. Excited states of the other variety of the linear MHe2 (M-He-He) systems are almost repulsive. The characteristic energy barrier of the first excited spin-orbit state of alkali metal-helium systems is found to be only 15 cm-1 in KHe and 19 cm-1 in He-K-He. For the Na*He and K*He exciplexes, predicted radiative lifetime values of 18.5 ns and 29.8 ns, respectively, are in excellent agreement with the experimental values. The red-tail portions of their emission bands are contributed by M*He2 exciplexes with relatively high radiative lifetimes. The repulsive excited state of 2Σ+1/2 (or 2Σ+g,1/2) symmetry in these van der Waals systems is likely to play an important role in the pumping of the blue side of the ns2S1/2 → np2P3/2 transition, which eventually may give rise to the np2P1/2 → ns2S1/2 lasing transition.

Spectroscopic features of the low-lying electronic states of some sodium-helium and potassium-helium van der Waals systems

International Nuclear Information System (INIS)

Chattopadhyay, Anjan

2011-01-01

Configuration interaction studies on MHe and MHe 2 (where M = Na, K) systems have revealed several interesting characteristics in the properties of their low-lying electronic states. Binding energy values of the 1 2 Π 1/2,3/2 states in MHe systems are found to be lower than the values of 1 2 Π u(1/2,3/2) states in the He-M-He systems by a margin of more than 200 cm -1 , indicating better exciplex stabilities of the latter systems. Excited states of the other variety of the linear MHe 2 (M-He-He) systems are almost repulsive. The characteristic energy barrier of the first excited spin-orbit state of alkali metal-helium systems is found to be only 15 cm -1 in KHe and 19 cm -1 in He-K-He. For the Na*He and K*He exciplexes, predicted radiative lifetime values of 18.5 ns and 29.8 ns, respectively, are in excellent agreement with the experimental values. The red-tail portions of their emission bands are contributed by M*He 2 exciplexes with relatively high radiative lifetimes. The repulsive excited state of 2 Σ + 1/2 (or 2 Σ + g,1/2 ) symmetry in these van der Waals systems is likely to play an important role in the pumping of the blue side of the ns 2 S 1/2 → np 2 P 3/2 transition, which eventually may give rise to the np 2 P 1/2 → ns 2 S 1/2 lasing transition.

The Electro-Excitation Form Factors for Low-Lying States of 7Li Nucleus

International Nuclear Information System (INIS)

Dakhl, Z.A.; Salih, L.; Al-Qazaz, B.S.

2010-01-01

The transverse electron scattering form factors have been studied for low -lying excited states of 7 L i nucleus. These states are specified by JπT= (0.478MeV),(4.63MeV) and(6.68MeV). The transitions to these states are taking place by both isoscalar and isovector components. These form factors have been analyzed in the framework of the multi-nucleon configuration mixing of harmonic oscillator shell model with size parameter b r ms=1.74fm. The universal two-body of Cohen-Kurath is used to generate the 1p-shell wave functions. The core polarization effects are included in the calculations through effective g-factors and resolved many discrepancies with experiments. A higher configuration effect outside the 1p-shell model space, such as the 2p-shell, enhances the form factors for q-values and reproduces the data. The present results are compared with other theoretical models. PACS: 25.30.Bf Elastic electron scattering - 25.30.Dh Inelastic electron scattering to specific states - 21.60.Cs Shell model - 27.20. +n 5≤ A ≥19

Low-lying isomeric levels in Cu75

Science.gov (United States)

Daugas, J. M.; Faul, T.; Grawe, H.; Pfützner, M.; Grzywacz, R.; Lewitowicz, M.; Achouri, N. L.; Angélique, J. C.; Baiborodin, D.; Bentida, R.; Béraud, R.; Borcea, C.; Bingham, C. R.; Catford, W. N.; Emsallem, A.; de France, G.; Grzywacz, K. L.; Lemmon, R. C.; Lopez Jimenez, M. J.; de Oliveira Santos, F.; Regan, P. H.; Rykaczewski, K.; Sauvestre, J. E.; Sawicka, M.; Stanoiu, M.; Sieja, K.; Nowacki, F.

2010-03-01

Isomeric low-lying states were identified and investigated in the Cu75 nucleus. Two states at 61.8(5)- and 128.3(7)-keV excitation energies with half-lives of 370(40)- and 170(15)-ns were assigned as Cu75m1 and Cu75m2, respectively. The measured half-lives combined with the recent spin assignment of the ground state allow one to deduce tentatively spin and parity of the two isomers and the dominant multipolarities of the isomeric transitions with respect to the systematics of the Cu isotopes. Shell-model calculations using an up-to-date effective interaction reproduce the evolution of the 1/2-, 3/2-, and 5/2- states for the neutron-rich odd-mass Cu isotopes when filling the νg9/2. The results indicate a significant change in the nuclear structure in this region, where a single-particle 5/2- state coexists with more and more collective 3/2- and 1/2- levels at low excitation energies.

Low-lying levels of 129Xe and 131Xe

International Nuclear Information System (INIS)

Palmer, D.C.; Irving, A.D.; Forsyth, P.D.; Hall, I.; Martin, D.G.E.; Maynard, M.J.

1978-01-01

The nuclei 129 Xe and 131 Xe have been studied by Coulomb excitation and by (α, n) reactions on 126 Te and 128 Te. Eleven new levels for 129 Xe and six for 131 Xe and B(E2) transition values for some of the low-lying states are reported. The present Coulomb excitation experiments together with published β-decay work enable some spin-parity assignments and restrictions to be made. The data are broadly consistent with the predictions of the particle-vibrator coupling model, although a thorough comparison requires further spectroscopic measurements and more detailed theoretical calculation. (author)

Spectroscopic features of the low-lying electronic states of some sodium-helium and potassium-helium van der Waals systems

Energy Technology Data Exchange (ETDEWEB)

Chattopadhyay, Anjan, E-mail: anjan@bits-goa.ac.in, E-mail: anjan_chattopadhyay@yahoo.com [Department of Chemistry, Birla Institute of Technology and Science (BITS), Pilani -K.K. Birla Goa Campus, Goa, 403 726 (India)

2011-08-28

Configuration interaction studies on MHe and MHe{sub 2} (where M = Na, K) systems have revealed several interesting characteristics in the properties of their low-lying electronic states. Binding energy values of the 1{sup 2}{Pi}{sub 1/2,3/2} states in MHe systems are found to be lower than the values of 1{sup 2}{Pi}{sub u(1/2,3/2)} states in the He-M-He systems by a margin of more than 200 cm{sup -1}, indicating better exciplex stabilities of the latter systems. Excited states of the other variety of the linear MHe{sub 2} (M-He-He) systems are almost repulsive. The characteristic energy barrier of the first excited spin-orbit state of alkali metal-helium systems is found to be only 15 cm{sup -1} in KHe and 19 cm{sup -1} in He-K-He. For the Na*He and K*He exciplexes, predicted radiative lifetime values of 18.5 ns and 29.8 ns, respectively, are in excellent agreement with the experimental values. The red-tail portions of their emission bands are contributed by M*He{sub 2} exciplexes with relatively high radiative lifetimes. The repulsive excited state of {sup 2}{Sigma}{sup +}{sub 1/2} (or {sup 2}{Sigma}{sup +}{sub g,1/2}) symmetry in these van der Waals systems is likely to play an important role in the pumping of the blue side of the ns{sup 2}S{sub 1/2} {yields} np{sup 2}P{sub 3/2} transition, which eventually may give rise to the np{sup 2}P{sub 1/2} {yields} ns{sup 2}S{sub 1/2} lasing transition.

Lie algebra symmetries and quantum phase transitions in nuclei

Indian Academy of Sciences (India)

2014-04-05

Apr 5, 2014 ... 743–755. Lie algebra symmetries and quantum phase transitions in nuclei .... Applications of this CS to QPT in sdgIBM model will be briefly ..... as a linear combination of ˆC2, ˆC3 and ˆC4 of SUsdg(5) and similarly also for the.

Ferromagnetic semiconductor-metal transition in heterostructures of electron doped europium monoxide

Energy Technology Data Exchange (ETDEWEB)

Stollenwerk, Tobias

2013-09-15

In the present work, we develop and solve a self-consistent theory for the description of the simultaneous ferromagnetic semiconductor-metal transition in electron doped Europium monoxide. We investigate two different types of electron doping, Gadolinium impurities and Oxygen vacancies. Besides the conduction band occupation, we can identify low lying spin fluctuations on magnetic impurities as the driving force behind the doping induced enhancement of the Curie temperature. Moreover, we predict the signatures of these magnetic impurities in the spectra of scanning tunneling microscope experiments. By extending the theory to allow for inhomogeneities in one spatial direction, we are able to investigate thin films and heterostructures of Gadolinium doped Europium monoxide. Here, we are able to reproduce the experimentally observed decrease of the Curie temperature with the film thickness. This behavior is attributed to missing coupling partners of the localized 4f moments as well as to an electron depletion at the surface which leads to a reduction of the number of itinerant electrons. By investigating the influence of a metallic substrate onto the phase transition in Gadolinium doped Europium monoxide, we find that the Curie temperature can be increased up to 20%. However, as we show, the underlying mechanism of metal-interface induced charge carrier accumulation is inextricably connected to a suppression of the semiconductor-metal transition.

Ferromagnetic semiconductor-metal transition in heterostructures of electron doped europium monoxide

International Nuclear Information System (INIS)

Stollenwerk, Tobias

2013-09-01

In the present work, we develop and solve a self-consistent theory for the description of the simultaneous ferromagnetic semiconductor-metal transition in electron doped Europium monoxide. We investigate two different types of electron doping, Gadolinium impurities and Oxygen vacancies. Besides the conduction band occupation, we can identify low lying spin fluctuations on magnetic impurities as the driving force behind the doping induced enhancement of the Curie temperature. Moreover, we predict the signatures of these magnetic impurities in the spectra of scanning tunneling microscope experiments. By extending the theory to allow for inhomogeneities in one spatial direction, we are able to investigate thin films and heterostructures of Gadolinium doped Europium monoxide. Here, we are able to reproduce the experimentally observed decrease of the Curie temperature with the film thickness. This behavior is attributed to missing coupling partners of the localized 4f moments as well as to an electron depletion at the surface which leads to a reduction of the number of itinerant electrons. By investigating the influence of a metallic substrate onto the phase transition in Gadolinium doped Europium monoxide, we find that the Curie temperature can be increased up to 20%. However, as we show, the underlying mechanism of metal-interface induced charge carrier accumulation is inextricably connected to a suppression of the semiconductor-metal transition.

Low-energy magnetic dipole response in 56Fe from high-resolution electron scattering

International Nuclear Information System (INIS)

Fearick, R.W.; Hartung, G.; Langanke, K.; Martinez-Pinedo, G.; Neumann-Cosel, P. von; Richter, A.

2003-01-01

The 56 Fe(e, e') reaction has been studied for excitation energies up to about 8 MeV and momentum transfers q≅0.4-0.55 fm -1 at the Darmstadt electron linear accelerator (DALINAC) with kinematics emphasizing M1 transitions. Additional data have been taken for q≅0.8-1.7 fm -1 at the electron accelerator NIKHEF, Amsterdam. A PWBA analysis allows spin and parity determination of the excited states. For M1 excitations, transition strengths are derived with a DWBA analysis using shell-model form factors. The resulting B(M1) strength distribution is compared to shell-model calculations employing different effective interactions. The form factor of the prominent low-lying M1 transition at 3.449 MeV demonstrates its dominant orbital nature. It represents a major part of the scissors mode in 56 Fe

Experimental study of the low-lying structure of 94Zr with the (n,n'γ) reaction

International Nuclear Information System (INIS)

Elhami, E.; Orce, J. N.; Scheck, M.; Mukhopadhyay, S.; Choudry, S. N.; McEllistrem, M. T.; Yates, S. W.; Angell, C.; Boswell, M.; Karwowski, H. J.; Fallin, B.; Howell, C. R.; Hutcheson, A.; Parpottas, Y.; Tonchev, A. P.; Tornow, W.; Kelley, J. H.

2008-01-01

The low-lying structure of 40 94 Zr was studied with the (n,n ' γ) reaction, and a level scheme was established based on excitation function and γγ coincidence measurements. Branching ratios, multipole mixing ratios, and spin assignments were determined from angular distribution measurements. Lifetimes of levels up to 3.4 MeV were measured by the Doppler-shift attenuation method, and for many transitions the reduced transition probabilities were determined. In addition to the anomalous 2 2 + state, which has a larger B(E2;2 2 + →0 1 + ) value than the B(E2;2 1 + →0 1 + ), the experimental results revealed interesting and unusual properties of the low-lying states in 94 Zr. In a simple interpretation, the excited states are classified in two distinct categories, i.e., those populating the 2 2 + state and those decaying to the 2 1 + state

On the low-lying states of TiC

Science.gov (United States)

Bauschlicher, C. W., Jr.; Siegbahn, P. E. M.

1984-01-01

The ground and low-lying excited states of TiC are investigated using a CASSCF-externally contracted CI approach. The calculations yield a 3Sigma(+) ground state, but the 1Sigma(+) state is only 780/cm higher and cannot be ruled out. The low-lying states have some triple bond character. The nature of the bonding and origin of the states are discussed.

Spectroscopic properties of the low-lying electronic states of RbHen (n = 1, 2) and their comparison with lighter alkali metal-helium systems

International Nuclear Information System (INIS)

Chattopadhyay, Anjan

2012-01-01

Ab initio-based configuration interaction studies on RbHe and He–Rb–He have explored some key features of the low-lying electronic states of these van der Waals systems. The radiative lifetime of the Rb*He exciplex has been calculated to be around 24.5 ns, which is slightly higher than the HeRb*He lifetime (∼20 ns) and lower than the atomic fluorescence lifetime of Rb, by roughly 3.5 ns. Better exciplex stability of the symmetric triatomic system is evidenced by its higher binding energy value in comparison to the diatomic system by a substantial margin. BSSE-corrected spin–orbit calculations of RbHe have predicted a potential barrier of the 1 2 Π 1/2 state with a height of 15 cm −1 and width of 2.57 Å. The 2 Π u state of the triatomic molecule shows a conical intersection of its Renner–Teller components (1 2 A 1 and 1 2 B 2 ) near a 99° bond angle along the bending path. Their unstable higher excited states (1 2 Σ + 1/2 or 1 2 Σ + g, 1/2 ) can trigger the pumping of the blue side of the ns 2 S 1/2 → np 2 P 3/2 transition, and this may eventually lead to the np 2 P 1/2 →ns 2 S 1/2 lasing transition. The broad fluorescence band with a peak near 11 900 cm −1 is found to arise from the 1 2 Π 3/2 –X 2 Σ + 1/2 transition of RbHe. (paper)

Low-dimensional filiform Lie algebras over finite fields

OpenAIRE

Falcón Ganfornina, Óscar Jesús; Núñez Valdés, Juan; Pacheco Martínez, Ana María; Villar Liñán, María Trinidad; Vasek, Vladimir (Coordinador); Shmaliy, Yuriy S. (Coordinador); Trcek, Denis (Coordinador); Kobayashi, Nobuhiko P. (Coordinador); Choras, Ryszard S. (Coordinador); Klos, Zbigniew (Coordinador)

2011-01-01

In this paper we use some objects of Graph Theory to classify low-dimensional filiform Lie algebras over finite fields. The idea lies in the representation of each Lie algebra by a certain type of graphs. Then, some properties on Graph Theory make easier to classify the algebras. As results, which can be applied in several branches of Physics or Engineering, for instance, we find out that there exist, up to isomorphism, six 6-dimensional filiform Lie algebras over Z/pZ, for p = 2, 3, 5. Pl...

Calculations of energy levels and lifetimes of low-lying states of barium and radium

International Nuclear Information System (INIS)

Dzuba, V. A.; Ginges, J. S. M.

2006-01-01

We use the configuration-interaction method and many-body perturbation theory to perform accurate calculations of energy levels, transition amplitudes, and lifetimes of low-lying states of barium and radium. Calculations for radium are needed for the planning of measurements of parity- and time-invariance-violating effects which are strongly enhanced in this atom. Calculations for barium are used to control the accuracy of the calculations

Theory of emission spectra from metal films irradiated by low energy electrons near normal incidence

International Nuclear Information System (INIS)

Kretschmann, E.; Callcott, T.A.; Arakawa, E.T.

1980-01-01

The emission spectrum produced by low energy electrons incident on a rough metal surface has been calculated for a roughness auto-correlation function containing a prominent peak at a high wave vector. For low energy electrons near normal incidence, the high wavevector peak dominates the roughness coupled surface plasmon radiation (RCSPR) process. The calculation yields estimates of the ratio of RCSPR to transition radiation, the dependence of emission intensity on electron energy and the shape and position of the RCSPR peak. The most interesting result is that the high-wavevector roughness can split the RCSPR radiation into peaks lying above and below the asymptotic surface plasma frequency. The results are compared with data from Ag in the following paper. (orig.)

An ab initio study on four low-lying electronic potential energy curves for atomic cesium and rare gas pairs

International Nuclear Information System (INIS)

Kobayashi, Takanori; Yuki, Kenta; Matsuoka, Leo

2016-01-01

Using multireference configuration interaction (MRCI) calculations with single and double excitation levels, Davidson correction, and a spin-orbit (SO) effective core potential, we have developed a series of four low-lying electronic potential energy curves (PECs) for the pairs formed between a cesium atom (Cs) and a rare gas (Rg = He, Ne, Ar, Kr, and Xe). The results obtained at the MRCI level were compared with those generated at the SOCI level, which were recently reported by Blank et al. The shapes of the PECs were essentially the same when the same basis set was used. Based on this agreement, more precise PECs for Cs-Rg pairs were calculated using a larger basis set for Rg. (author)

Characterization of the low-lying 0$^{+}$ and 2$^{+}$ states of $^{68}$ Ni

CERN Multimedia

Recently, a number of low-lying low-spin states have been firmly identified in $^{68}$Ni; the position of the first excited state (which is a 0$^{+}$ state), the spin and parity of the second excited 0$^{+}$ state and the spin and parity of the second and third 2$^+$ states have been fixed. The identification of these three pairs of 0$^+$ and 2$^+$ states in $^{68}$Ni (Z=28 and N=40) forms ideal tests to validate shell-model calculations and the effective interactions developed for the nickel region but also hints to triple shape coexistence including even strongly deformed structures. The aim of this proposal is to collect detailed spectroscopic data of the low-spin states of $^{68}$Ni (Z=28, N=40) in order to characterize these triple pairs of 0$^+$ and 2$^+$ states. $\\gamma$-branching ratios of the 0$^+$ and 2$^+$ states and the E0 transition strengths as well as the E2 transition rate of the 0$_3^+$ will be obtained using the new ISOLDE decay station that is constructed from an efficient array of germaniu...

Comprehensive ab initio calculation and simulation on the low-lying electronic states of TlX (X = F, Cl, Br, I, and At).

Science.gov (United States)

Zou, Wenli; Liu, Wenjian

2009-03-01

The low-lying electronic states of TlX (X=F, Cl, Br, I, and At) are investigated using the configuration interaction based complete active space third-order perturbation theory [CASPT3(CI)] with spin-orbit coupling accounted for. The potential energy curves and the corresponding spectroscopic constants are reported. The results are grossly in good agreement with the available experimental data. The absorption spectra are simulated as well to reassign the experimental bands. The present results are also useful for guiding future experimental measurements.

All Electron ab initio Investigations of the Three Lowest Lying Electronic States of the RuC Molecule

DEFF Research Database (Denmark)

Shim, Irene; Gingerich, K. A.

2000-01-01

The three lowest-lying electronic states of RuC, (1)Sigma(+), (3)Delta, and (1)Delta, have been investigated by performing all-electron ab initio multi-configuration self-consistent-field (CASSCF) and multi-reference configuration interaction (MRCI) calculations including relativistic corrections....... The electronic ground state is derived as (1)Sigma(+) with the spectroscopic constants r(e) = 1.616 Angstrom and omega(e) = 1085 cm(-1). The lowest-lying excited state, (3)Delta, has r(e) = 1.632 Angstrom, omega(e) = 1063 cm(-1), and T-e = 912 cm(-1). These results are consistent with recent spectroscopic values....... The chemical bonds in all three lowest-lying states are triple bonds composed of one sigma and two pi bonds. (C) 2000 Elsevier Science B.V. All rights reserved....

Short communication: Association of lying behavior and subclinical ketosis in transition dairy cows.

Science.gov (United States)

Kaufman, E I; LeBlanc, S J; McBride, B W; Duffield, T F; DeVries, T J

2016-09-01

The objective of this study was to characterize the association of lying behavior and subclinical ketosis (SCK) in transition dairy cows. A total of 339 dairy cows (107 primiparous and 232 multiparous) on 4 commercial dairy farms were monitored for lying behavior and SCK from 14d before calving until 28 d after calving. Lying time, frequency of lying bouts, and average lying bout length were measured using automated data loggers 24h/d. Cows were tested for SCK 1×/wk by taking a blood sample and analyzing for β-hydroxybutyrate; cows with β-hydroxybutyrate ≥1.2mmol/L postpartum were considered to have SCK. Cases of retained placenta, metritis, milk fever, or mastitis during the study period were recorded and cows were categorized into 1 of 4 groups: healthy (HLT) cows had no SCK or any other health problem (n=139); cows treated for at least 1 health issue other than SCK (n=50); SCK (HYK) cows with no other health problems during transition (n=97); or subclinically ketotic plus (HYK+) cows that had SCK and 1 or more other health problems (n=53). Daily lying time was summarized by week and comparisons were made between HLT, HYK, and HYK+, respectively. We found no difference among health categories in lying time, bout frequency, or bout length fromwk -2 towk +4 relative to calving for first-lactation cows. Differences in lying time for multiparous cows were seen inwk +1, when HYK+ cows spent 92±24.0 min/d more time lying down than HLT cows, and duringwk +3 and +4 when HYK cows spent 44±16.7 and 41±18.9 min/d, respectively, more time lying down than HLT cows. Increased odds of HYK+ were found to be associated with higher parity, longer dry period, and greater stall stocking density inwk -1 and longer lying time duringwk +1. When comparing HYK to HLT cows, the same variables were associated with odds of SCK; however, lying time was not retained in the final model. These results suggest that monitoring lying time may contribute to identifying multiparous cows

Low-lying dipole strength of the open-shell nucleus 94Mo

Science.gov (United States)

Romig, C.; Beller, J.; Glorius, J.; Isaak, J.; Kelley, J. H.; Kwan, E.; Pietralla, N.; Ponomarev, V. Yu.; Sauerwein, A.; Savran, D.; Scheck, M.; Schnorrenberger, L.; Sonnabend, K.; Tonchev, A. P.; Tornow, W.; Weller, H. R.; Zilges, A.; Zweidinger, M.

2013-10-01

The low-lying dipole strength of the open-shell nucleus 94Mo was studied via the nuclear resonance fluorescence technique up to 8.7 MeV excitation energy at the bremsstrahlung facility at the Superconducting Darmstadt Electron Linear Accelerator (S-DALINAC), and with Compton backscattered photons at the High Intensity γ-ray Source (HIγS) facility. In total, 83 excited states were identified. Exploiting polarized quasi-monoenergetic photons at HIγS, parity quantum numbers were assigned to 41 states excited by dipole transitions. The electric dipole-strength distribution was determined up to 8.7 MeV and compared to microscopic calculations within the quasiparticle phonon model. Calculations and experimental data are in good agreement for the fragmentation, as well as for the integrated strength. The average decay pattern of the excited states was investigated exploiting the HIγS measurements at five energy settings. Mean branching ratios to the ground state and first excited 21+ state were extracted from the measurements with quasi-monoenergetic photons and compared to γ-cascade simulations within the statistical model. The experimentally deduced mean branching ratios exhibit a resonance-like maximum at 6.4 MeV which cannot be reproduced within the statistical model. This indicates a nonstatistical structure in the energy range between 5.5 and 7.5 MeV.

Study of lifetimes of low-lying levels in {sup 53}Mn

Energy Technology Data Exchange (ETDEWEB)

Singh, K.P.; Oswal, Mumtaz; Behera, B.R.; Kumar, Ashok; Singh, Gulzar [Panjab University, Cyclotron Laboratory, Department of Physics, Centre of Advance Study in Physics, Chandigarh (India)

2015-05-15

The properties of low-lying states of {sup 53}Mn were investigated via the {sup 53}Cr(p, n γ){sup 53}Mn reaction using 4.3 MeV proton beam energy. The lifetimes of the levels at 1289.5, 1440.8, 1620.0 and 2273.8 keV excitation energies were measured using the Doppler Shift Attenuation Method (DSAM). The reduced transition probabilities B(M1) and B(E2) were extracted using the measured values of lifetimes for these levels and the mixing ratios from the literature. These values are compared with already known experimental values as well as the shell model calculations using an effective interaction. (orig.)

Ab initio study of vibronic transitions between x2π and 12Σ+ electronic states of HCP+ ion

Directory of Open Access Journals (Sweden)

Stojanović Ljiljana

2013-01-01

Full Text Available The ground and low-lying excited doublet electronic states of the HCP+ ion were studied by means of multireference configuration interaction method. Vibronic energy levels of the X2Π state of Σ, Π, Δ, and Φ symmetry, up to the 2500 cm-1, have been calculated variationally, employing previously developed ab initio methods which take into account vibronic and spin-orbit interactions. Obtained vibronic wave functions were used to estimate transition moments between vibronic energy levels of the X2Π and 12Σ+ electronic states. Results were compared to available experimental and theoretical data. [Projekat Ministarstva nauke Republike Srbije, br. 172040

The low-lying collective multipole response of atomic nuclei

Energy Technology Data Exchange (ETDEWEB)

Spieker, Mark; Derya, Vera; Hennig, Andreas; Pickstone, Simon G.; Prill, Sarah; Vielmetter, Vera; Weinert, Michael; Wilhelmy, Julius; Zilges, Andreas [Institute for Nuclear Physics, University of Cologne, Cologne (Germany); Petkov, Pavel [Institute for Nuclear Physics, University of Cologne, Cologne (Germany); INRNE, Bulgarian Academy of Sciences, Sofia (Bulgaria); National Institute for Physics and Nuclear Engineering, Bucharest (Romania)

2016-07-01

We present experimental results on the low-lying multipole response, which were obtained with the recently established DSA-method in Cologne. Nuclear level lifetimes in the sub-ps regime are extracted by means of centroid-shifts utilizing the (p,p{sup '}γ) reaction at the 10 MV FN-Tandem accelerator in Cologne. The scattered protons are coincidently detected with the deexciting γ rays using the SONIC rate at HORUS detector array, which allows for a precise determination of the reaction kinematics. In addition to the pioneering results on octupole and hexadecapole mixed-symmetry states of {sup 96}Ru, this contribution will feature new results on low-lying quadrupole-octupole coupled states and on the low-lying E2 strength of {sup 112,114}Sn, which was recently discussed to be generated due to a quadrupole-type oscillation of the neutron skin against the isospin-saturated core.

Transitions to improved core electron heat confinement triggered by low order rational magnetic surfaces in the stellarator TJ-II

International Nuclear Information System (INIS)

Estrada, T.; Medina, F.; Lopez-Bruna, D.; AscasIbar, E.; BalbIn, R.; Cappa, A.; Castejon, F.; Eguilior, S.; Fernandez, A.; Guasp, J.; Hidalgo, C.; Petrov, S.

2007-01-01

Transitions to improved core electron heat confinement are triggered by low order rational magnetic surfaces in TJ-II electron cyclotron heated (ECH) plasmas. Experiments are performed changing the magnetic shear around the rational surface n = 3/m = 2 to study its influence on the transition; ECH power modulation is used to look at transport properties. The improvement in the electron heat confinement shows no obvious dependence on the magnetic shear. Transitions triggered by the rational surface n = 4/m = 2 show, in addition, an increase in the ion temperature synchronized with the increase in the electron temperature. Ion temperature changes had not been previously observed either in TJ-II or in any other helical device. SXR measurements demonstrate that, under certain circumstances, the rational surface positioned inside the plasma core region precedes and provides a trigger for the transition

Calculations of the Low-Lying Structures in the Even-Even Nd/Sm/Gd/Dy Isotopes

Science.gov (United States)

Lee, Su Youn; Lee, J. H.; Lee, Young Jun

2018-05-01

The nuclear structure of deformed nuclei has been studied using the interacting boson model (IBM). In this study, energy levels and E2 transition probabilities were determined for even nuclei in the Nd/Sm/Gd/Dy chains which have a transition characteristic between the rotational, SU(3) and vibrational, U(5) limits. The structure of the nuclei exhibits a slight breaking of the SU(3) symmetry in the direction of U(5), and therefore, we add the d-boson number operator n d , which is the main term of the U(5) symmetric Hamiltonian, to the SU(3) Hamiltonian of the IBM. The calculated results for low-lying energy levels and E2 transition rates in Nd/Sm/Gd/Dy isotopes are in reasonably good agreement with known experimental results.

Oscillator strengths and lifetimes for low-lying terms in the Al isoelectronic sequence

International Nuclear Information System (INIS)

Hjort-Jensen, M.; Aashamar, K.

1988-11-01

Using the Multiconfiguration Optimized Potential Model, calculations of oscillator strengths in the length, and velocity formulation for a large number of transitions in the Aluminium isoelectronic sequence from Si II through K VII, have been performed. The results have been used to determine the lifetimes of 14 low-lying excited terms along the sequence. Comparison is made with experiment and with other theory where results are available. The agreement between the obtained values and other theoretical results is generally good, although deviations do occur near level crossings. Some significant discrepancies between theory and experiment persist concerning lifetimes for S IV

Low-lying level structure of the neutron-rich nucleus {sup 109}Nb: A possible oblate-shape isomer

Energy Technology Data Exchange (ETDEWEB)

Watanabe, H., E-mail: hiroshi@ribf.riken.j [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Sumikama, T. [Department of Physics, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba (Japan); Nishimura, S. [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Yoshinaga, K. [Department of Physics, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba (Japan); Li, Z. [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Miyashita, Y. [Department of Physics, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba (Japan); Yamaguchi, K. [Department of Physics, Osaka University, Machikaneyama-machi 1-1, Osaka 560-0043 Toyonaka (Japan); Baba, H. [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Berryman, J.S. [Nuclear Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Blasi, N. [INFN, Sezione di Milano, via Celoria 16, I-20133 Milano (Italy); Bracco, A.; Camera, F. [INFN, Sezione di Milano, via Celoria 16, I-20133 Milano (Italy); Dipartimento di Fisica, Universita di Milano, via Celoria 16, I-20133 Milano (Italy); Chiba, J. [Department of Physics, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba (Japan); Doornenbal, P. [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Go, S.; Hashimoto, T.; Hayakawa, S. [Center for Nuclear Study, University of Tokyo, Hirosawa 2-1, Wako, Saitama 351-0198 (Japan); Hinke, C. [Physik Department, Technische Universitaet Muenchen, D-85748 Garching (Germany); Ideguchi, E. [Center for Nuclear Study, University of Tokyo, Hirosawa 2-1, Wako, Saitama 351-0198 (Japan); Isobe, T. [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan)

2011-01-31

The neutron-rich nuclei {sup 109}Nb and {sup 109}Zr have been populated using in-flight fission of a {sup 238}U beam at 345 MeV/nucleon at the RIBF facility. A T{sub 1/2}=150(30) ns isomer at 313 keV has been identified in {sup 109}Nb for the first time. The low-lying levels in {sup 109}Nb have been also populated following the {beta}-decay of {sup 109}Zr. Based on the difference in feeding pattern between the isomeric and {beta} decays, the decay scheme from the isomeric state in {sup 109}Nb was established. The observed hindrances of the electromagnetic transitions deexciting the isomeric state are discussed in terms of possible shape coexistence. Potential energy surface calculations for single-proton configurations predict the presence of low-lying oblate-deformed states in {sup 109}Nb.

Low-lying electric-dipole strengths of Ca, Ni, and Sn isotopes imprinted on total reaction cross sections

Science.gov (United States)

Horiuchi, W.; Hatakeyama, S.; Ebata, S.; Suzuki, Y.

2017-08-01

Low-lying electric-dipole (E 1 ) strength of a neutron-rich nucleus contains information on neutron-skin thickness, deformation, and shell evolution. We discuss the possibility of making use of total reaction cross sections on 40Ca, 120Sn, and 208Pb targets to probe the E 1 strength of neutron-rich Ca, Ni, and Sn isotopes. They exhibit large enhancement of the E 1 strength at neutron number N >28 , 50, and 82, respectively, due to a change of the single-particle orbits near the Fermi surface participating in the transitions. The density distributions and the electric-multipole strength functions of those isotopes are calculated by the Hartree-Fock+BCS and the canonical-basis-time-dependent-Hartree-Fock-Bogoliubov methods, respectively, using three kinds of Skyrme-type effective interaction. The nuclear and Coulomb breakup processes are respectively described with the Glauber model and the equivalent photon method in which the effect of finite-charge distribution is taken into account. The three Skyrme interactions give different results for the total reaction cross sections because of different Coulomb breakup contributions. The contribution of the low-lying E 1 strength is amplified when the low-incident energy is chosen. With an appropriate choice of the incident energy and target nucleus, the total reaction cross section can be complementary to the Coulomb excitation for analyzing the low-lying E 1 strength of unstable nuclei.

Free-Free Transitions in the Presence of Laser Fields and Debye Potential at Very Low Incident Electron Energies

Science.gov (United States)

Bhatia, Anand

2012-01-01

We study the free-free transition in electron-helium ion in the ground state and embedded in a Debye potential in the presence of an external laser field at very low incident electron energies. The laser field is treated classically while the collision dynamics is treated quantum mechanically. The laser field is chosen as monochromatic, linearly polarized and homogeneous. The incident electron is considered to be dressed by the laser field in a nonperturbative manner by choosing Volkov wave function for it. The scattering wave function for the incident electron on the target embedded in a Debye potential is solved numerically by taking into account the effect of electron exchange. We calculate the laser-assisted differential and total cross sections for free-free transition for absorption/emission of a single photon or no photon exchange. The results will be presented at the conference.

Role of quasiparticle x phonon components in gamma-decay of hogh-lying states

International Nuclear Information System (INIS)

Ponomarev, V.Yu.; Solov'ev, V.G.; Vdovin, A.I.; Stoyanov, Ch.

1986-01-01

In the framework of quasiparticle-phonon model of a nucleus the probabilities of gamma-transitions (E1, M1, E2) from a high-lying resonance-similar structure to the excitation of neutron hole state (lg 9/2 ) -1 of 111 Sn nucleus to the main and low-excited one-quasiparticle states have been calculated. Wave function of a highly excited state comprised the components ''quasiparticle x phonon'' and ''quasiparticle x two phonons''. For E1-transitions 9/2 + → 11/2 1 - the main contribution to the transition is made by one-quasiparticle components of wave functions of the initial and final states. E2-transition 9/2 + → 7/2 g,s + takes place at the expense of impurities in ''quasiparticle x phonon'' states. For M1-transition from the states 9/2 + to the main one a strong destructive interference of contributions of one-quasiparticle and ''quasiparticle x phonon'' components is observed. Thus it is shown that components ''quasiparticle x phonon'' may play the major role in correct description of gamma-transitions from high-lying one-particle or low-lying hole states

Longitudinal Electron Bunch Diagnostics Using Coherent Transition Radiation

CERN Document Server

Mihalcea, Daniel; Happek, Uwe; Regis-Guy Piot, Philippe

2005-01-01

The longitudinal charge distribution of electron bunches in the Fermilab A0 photo-injector was determined by using the coherent transition radiation produced by electrons passing through a thin metallic foil. The auto-correlation of the transition radiation signal was measured with a Michelson type interferometer. The response function of the interferometer was determined from measured and simulated power spectra for low electron bunch charge and maximum longitudinal compression. Kramers-Kroning technique was used to determine longitudinal charge distribution. Measurements were performed for electron bunch lengths in the range from 0.3 to 2 ps (rms).

Electron crystallization in two dimensions

Energy Technology Data Exchange (ETDEWEB)

Glattli, D.C.; Deville, G.; Probst, O.; Williams, F.I.B. (Lab. de Physique du Solide et de Resonance Magnetique, C.E.N. Saclay, 91 - Gif-sur-Yvette (France)); Andrei, E.Y. (Dept. of Physics, Rutgers Univ., Piscataway, NJ (USA)); Clark, R.G.; Wright, P.A. (Clarendon Lab., Oxford (UK)); Dorin, C.; Etienne, B.; Paris, E. (Lab. de Microstructures et Microelectronique, 92 - Bagneux (France)); Foxon, C.T.; Harris, J.J. (Phillips Research Lab., Redhill (UK))

1991-02-01

Electrons confined at the interface of a GaAs/GaAlAs heterojunction form a 2D quantum electron liquid. Under a strong magnetic field a phase transition to an electron (Wigner) solid takes place in the low filling factor regime of the Fractional Quantum Hall Effect (FQHE). We describe experimental evidence for such electron solid formation obtained both by radiofrequency (RF) study of the low-frequency collective excitations and by conductivity measurements. A finite-threshold electric field for DC conduction reflecting the electron crystallite pinning in the sample random potential is found associated to a small gap in the solid phase low-lying collective excitation branch. The {nu}=1/5 FQHE liquid reenters the solid domain at low temperature. (orig.).

Low lying states of Th229

DEFF Research Database (Denmark)

Andersen, Torkild; Maack Bisgård, K.; Hansen, P.Gregers

1961-01-01

The decay of 1.6 × 105y U233 has been studied by means of a six gap beta-ray spectrometer, a xenon filled proportional counter and scintillation spectrometers. Internal conversion electrons having energies below 100 keV were measured. The mixing ratios for the 42 keV and the 55 keV transitions ag...... agree with the assumed rotational character of the 42 keV and 97 keV states. Results concerning the 163 keV state indicate that this state is also a member of the ground state rotational band.......The decay of 1.6 × 105y U233 has been studied by means of a six gap beta-ray spectrometer, a xenon filled proportional counter and scintillation spectrometers. Internal conversion electrons having energies below 100 keV were measured. The mixing ratios for the 42 keV and the 55 keV transitions...

Free-Free Transitions in the Presence of Laser Fields at Very Low Incident Electron Energy

Science.gov (United States)

Bhatia, A. K.; Sinha, Chandana

2010-01-01

We study the free-free transition in electron-hydrogenic systems in ground state in presence of an external laser field at very loud incident energies. The laser field is treated classically while the collision dynamics is treated quantum mechanically. The laser field is chosen to be monochromatic, linearly polarized and homogeneous. The incident electron is considered to be dressed by the laser in a nonperturbative manner by choosing a Volkov wave function for it. The scattering weave function for the electron is solved numerically by taking into account the effect of the electron exchange, short-range as well as of the long-range interactions to get the S and P wave phase shifts while for the higher angular momentum phase shifts the exchange approximation has only been considered. We calculate the laser assisted differential cross sections (LADCS) for the aforesaid free-free transition process for single photon absorption/emission. The laser intensity is chosen to be much less than the atomic field intensity. A strong suppression is noted in the LADCS as compared to the field free (FF) cross sections. Unlike the FF ones, the LADCS exhibit some oscillations having a distinct maximum at a low value of the scattering angle depending on the laser parameters as well as on the incident energies.

Coulomb excitations of low lying levels in 127I and 197Au

International Nuclear Information System (INIS)

Singh, K.P.; Tayal, D.C.; Hans, H.S.

1988-01-01

The low-lying levels of 127 I and 197 Au were Coulomb excited with 3.54 to 4.2 MeV protons. The reduced quadrupole transition probabilities of the 203, 374.9, 418, 618.4, 628.7, 651.1 and 745.5 keV states of 127 I, and the 268.8, 278.9, 502, and 547.5 keV states of 197 Au was measured from Coulomb excitation by observing the de-excitation gamma rays with a high resolution Ge(Li) detector. The low-energy protons were used for the first time to Coulomb-excite the two levels at 618.4 and 651.1 keV of 127 I and one level at 502 keV of 197 Au. The present experimental results are found in agreement with the existing experimental data except the B(E2) value of the level at 268.8 keV of 197 Au. (author). 4 figs., 4 tabs., 32 refs

Survey of experimental and theoretical electron-impact ionization cross sections for transition metal ions in low stages of ionization

International Nuclear Information System (INIS)

Pindzola, M.S.; Griffin, D.C.; Bottcher, C.

1985-03-01

Electron-ion crossed beams measurements and distorted-wave theory have been employed to make a study of electron-impact ionization for transition metal ions in low stages of ionization. The atomic ions Ti+, Ti 2 +, Ti 3 +, Fe+, Fe 2 +, Fe 3 +, Fe 4 +, Ni+, Ni 2 +, Ni 3 +, Cu+, Cu 2 +, and Cu 3 + are examined

The low-lying electronic states of pentacene and their roles in singlet fission.

Science.gov (United States)

Zeng, Tao; Hoffmann, Roald; Ananth, Nandini

2014-04-16

We present a detailed study of pentacene monomer and dimer that serves to reconcile extant views of its singlet fission. We obtain the correct ordering of singlet excited-state energy levels in a pentacene molecule (E (S1) pentacene, we use a well-developed diabatization scheme to characterize the six low-lying singlet states of a pentacene dimer that approximates the unit cell structure of crystalline pentacene. The local, single-excitonic diabats are not directly coupled with the important multiexcitonic state but rather mix through their mutual couplings with one of the charge-transfer configurations. We analyze the mixing of diabats as a function of monomer separation and pentacene rotation. By defining an oscillator strength measure of the coherent population of the multiexcitonic diabat, essential to singlet fission, we find this population can, in principle, be increased by small compression along a specific crystal direction.

Hierarchy of the low-lying excitations for the (2+1-dimensional q=3 Potts model in the ordered phase

Directory of Open Access Journals (Sweden)

Yoshihiro Nishiyama

2017-03-01

Full Text Available The (2+1-dimensional q=3 Potts model was simulated with the exact diagonalization method. In the ordered phase, the elementary excitations (magnons are attractive, forming a series of bound states in the low-energy spectrum. We investigate the low-lying spectrum through a dynamical susceptibility, which is readily tractable with the exact diagonalization method via the continued-fraction expansion. As a result, we estimate the series of (scaled mass gaps, m2,3,4/m1 (m1: single-magnon mass, in proximity to the transition point.

Low lying magnetic dipole strength distribution in 176Hf

International Nuclear Information System (INIS)

Kuliev, A. A.; Ertugral, F.; Yakut, H.; Bektasoglu, M.; Guliyev, E.

2006-01-01

In this study the scissors mode 1 + states are systematically investigated within the rotational invariant Quasiparticle Random Phase Approximation (QRPA) for 1 76Hf isotopes. We consider the 1 + vibrations generated by the isovector spin-spin interactions and the isoscalar (h 0 ) and isovector (h 1 ) quadrupole type separable forces restoring the broken symmetry by a deformed mean field. It has been shown that restoration of the broken rotational symmetry of the Hamiltonian essentially decreases the B(M1) value of the low lying 1 + states and increases the collectivization of the scissors mode excitations in the spectroscopic energy region. Agreement between the calculated mean excitation energies as well as the summed B(M1) value of the scissors mode excitations and the available experimental data of 1 76Hf is rather good. For instance, distributions of the calculated B(M1) transition strengths in the 1 76 Hf isotopes with respect to K π =1 + excitations is represented in Figure. Thus, we see that the models which use the Hamiltonian with broken rotational symmetry strongly overestimate the M1 strength at low energy. These results indicate an importance of the models which are free from the low-energy spurious states. The marked differences between the results for 1 + states, calculated in rotational invariant (RI) and non-rotational invariant (NRI) model indicate the importance of the approaches which are free from spurious low-energy solutions. A separation of the rotational state from the 1 + states changes somewhat the distribution of the B(M1) strength in the spectroscopic energy region and increases the fragmentation of the scissors mode 1 + excitations in agreement with the experimental data

Laser photoelectron spectroscopy of MnH - and FeH - : Electronic structures of the metal hydrides, identification of a low-spin excited state of MnH, and evidence for a low-spin ground state of FeH

Science.gov (United States)

Stevens, Amy E.; Feigerle, C. S.; Lineberger, W. C.

1983-05-01

The laser photoelectron spectra of MnH- and MnD-, and FeH- and FeD- are reported. A qualitative description of the electronic structure of the low-spin and high-spin states of the metal hydrides is developed, and used to interpret the spectra. A diagonal transition in the photodetachment to the known high-spin, 7Σ+, ground state of MnH is observed. An intense off-diagonal transition to a state of MnH, at 1725±50 cm-1 excitation energy, is attributed to loss of an antibonding electron from MnH-, to yield a low-spin quintet state of MnH. For FeH- the photodetachment to the ground state is an off-diagonal transition, attributed to loss of the antibonding electron from FeH-, to yield a low-spin quartet ground state of FeH. A diagonal transition results in an FeH state at 1945±55 cm-1; this state of FeH is assigned as the lowest-lying high-spin sextet state of FeH. An additional excited state of MnH and two other excited states of FeH are observed. Excitation energies for all the states are reported; vibrational frequencies and bond lengths for the ions and several states of the neutrals are also determined from the spectra. The electron affinity of MnH is found to be 0.869±0.010 eV; and the electron affinity of FeH is determined to be 0.934±0.011 eV. Spectroscopic constants for the various deuterides are also reported.

Transitions to improved core electron heat confinement in JT-II plasmas

International Nuclear Information System (INIS)

Estrada, T.; Medina, F.; Ascasibar, E.; Balbin, R.; Castejon, F.; Hidalgo, C.; Lopez-Bruna, D.; Petrov, S.

2008-01-01

Transitions to improved core electron heat confinement are triggered by low order rational magnetic surfaces in TJ-II ECH plasmas. Transitions triggered by the rational surface n=4/m=2 show an increase in the ion temperature synchronized with the increase in the electron temperature. SXR measurements demonstrate that, under certain circumstances, the rational surface positioned inside the plasma core region precedes and provides a trigger for the transition. (author)

Low-lying magnetic dipole strength distribution in the γ-soft even-even 130-136Ba

International Nuclear Information System (INIS)

Guliyev, E.; Ertugral, F.; Kuliev, A.A.

2006-01-01

In this study the scissors mode 1 + states are systematically investigated within the rotational invariant Quasiparticle Random Phase Approximation (QRPA) for 130-136 Ba isotopes. We consider the 1 + vibrations generated by the isovector spin-spin interactions and the isoscalar and isovector quadrupole-type separable forces restoring the broken symmetry by a deformed mean field according to A.A. Kuliev et al. (Int. J. Mod. Phys. E 9, 249 (2000)). It has been shown that the restoration of the broken rotational symmetry of the Hamiltonian essentially decreases the B(M1) value of the low-lying 1 + states and increases the collectivization of the scissors mode excitations in the spectroscopic energy region. The agreement between the calculated mean excitation energies as well as the summed B(M1) value of the scissors mode excitations and the available experimental data of 134 Ba and 136 Ba is rather good. A destructive interference between the orbit and spin part of the M1 strength has been found for barium isotopes near the shell closer. For all the nuclei under investigation, the low-lying M1 transitions have ΔK=1 character as it is the case for the well-deformed nuclei. (orig.)

Interaction effects in liquids with low electron densities

International Nuclear Information System (INIS)

Warren, W.W. Jr.

1987-01-01

The author discusses two complementary classes of systems in which strong electron-electron or electron-ion interactions appear at low electron densities. The first are the expanded liquid alkali metals (cesium) in which electron correlation effects have a profound effect on the magnetic properties on the metallic side of the metal-nonmetal transition. The second group are molten alkali halides containing low densities of localized electrons introduced, say, by dissolution of small amounts of excess metal. (Auth.)

Shape transition in the Nd-isotopes

International Nuclear Information System (INIS)

Sandor, Robert Karl Josef.

1991-01-01

In this thesis the results of an electron scattering experiment on 142 Nd, 146 Nd and 150 Nd, designed to study the influence of this shape transition an the low-lying excited states, have been presented and discussed. The spectra have been obtained at the high-resolution electron scattering facility of NIKHEF-K and cover a momentum transfer range from 0.5 up to 2.8 fm -1 . The experimental form factors and transition charge densities have been compared to two microscopic models, i.e. the Quasiparticle-Phonon Model for 142 Nd and 146 Nd and the Density-Dependent Hartree-Fock-Boguliubov model with a dynamical approach to calculate transition charge densities for 146 Nd and 150 Nd. The data obtained for the latter nuclei have also been compared to the macroscopic Rotation-Vibration Model. (author). 127 refs.; 49 figs.; 26 tabs

The electronic structure of vanadium monochloride cation (VCl+): Tackling the complexities of transition metal species

Science.gov (United States)

DeYonker, Nathan J.; Halfen, DeWayne T.; Allen, Wesley D.; Ziurys, Lucy M.

2014-11-01

Six electronic states (X 4Σ-, A 4Π, B 4Δ, 2Φ, 2Δ, 2Σ+) of the vanadium monochloride cation (VCl+) are described using large basis set coupled cluster theory. For the two lowest quartet states (X 4Σ- and A 4Π), a focal point analysis (FPA) approach was used that conjoined a correlation-consistent family of basis sets up to aug-cc-pwCV5Z-DK with high-order coupled cluster theory through pentuple (CCSDTQP) excitations. FPA adiabatic excitation energies (T0) and spectroscopic constants (re, r0, Be, B0, bar De, He, ωe, v0, αe, ωexe) were extrapolated to the valence complete basis set Douglas-Kroll (DK) aug-cc-pV∞Z-DK CCSDT level of theory, and additional treatments accounted for higher-order valence electron correlation, core correlation, and spin-orbit coupling. Due to the delicate interplay between dynamical and static electronic correlation, single reference coupled cluster theory is able to provide the correct ground electronic state (X 4Σ-), while multireference configuration interaction theory cannot. Perturbations from the first- and second-order spin orbit coupling of low-lying states with quartet spin multiplicity reveal an immensely complex rotational spectrum relative to the isovalent species VO, VS, and TiCl. Computational data on the doublet manifold suggest that the lowest-lying doublet state (2Γ) has a Te of ˜11 200 cm-1. Overall, this study shows that laboratory and theoretical rotational spectroscopists must work more closely in tandem to better understand the bonding and structure of molecules containing transition metals.

Low-lying excited states by constrained DFT

Science.gov (United States)

Ramos, Pablo; Pavanello, Michele

2018-04-01

Exploiting the machinery of Constrained Density Functional Theory (CDFT), we propose a variational method for calculating low-lying excited states of molecular systems. We dub this method eXcited CDFT (XCDFT). Excited states are obtained by self-consistently constraining a user-defined population of electrons, Nc, in the virtual space of a reference set of occupied orbitals. By imposing this population to be Nc = 1.0, we computed the first excited state of 15 molecules from a test set. Our results show that XCDFT achieves an accuracy in the predicted excitation energy only slightly worse than linear-response time-dependent DFT (TDDFT), but without incurring into problems of variational collapse typical of the more commonly adopted ΔSCF method. In addition, we selected a few challenging processes to test the limits of applicability of XCDFT. We find that in contrast to TDDFT, XCDFT is capable of reproducing energy surfaces featuring conical intersections (azobenzene and H3) with correct topology and correct overall energetics also away from the intersection. Venturing to condensed-phase systems, XCDFT reproduces the TDDFT solvatochromic shift of benzaldehyde when it is embedded by a cluster of water molecules. Thus, we find XCDFT to be a competitive method among single-reference methods for computations of excited states in terms of time to solution, rate of convergence, and accuracy of the result.

E0 and E2 decay of low-lying 0+ states in the even-even nuclei 206Pb, 208Po, 112-120 Sn and 112114Cd

International Nuclear Information System (INIS)

Julin, Rauno.

1979-04-01

Several new methods of in-beam conversion-electron and γ-ray spectrometry, applicable in the determination of E0 and E2 decay properties of low-lying 0 + states in even-mass nuclei, have been developed. The main attention has been paid to direct lifetime-measurement and coincidence methods based on the use of the natural pulsing of a cyclotron beam. With the aid of these methods, the similarity of the absolute decay rates of the two-neutron-hole 0 + 2 states in the N = 124 nuclei 206 Pb and 208 Po has been shown. A systematic investigation of the de-excitation of the 0 + 2 and 0 + 3 states in 112 , 11 4 , 116 , 118 , 120 Sn has been carried out. Twelve E0 transitions connecting the 0 + states have been observed, including very strong low-energy E0 transitions between the excited 0 + states, and several absolute transition probabilities have been determined. Furthermore, the new techniques have been applied successfully in determining the absolute E0 and E2 transition rates from the 0 + 2 and 0 + 3 states in 112 Cd and 114 Cd. The use of isotope-shift data in the calculation of the monopole strengths in 206 Pb and 208 Po is discussed. The results on even Sn and Cd nuclei are discussed within the framework of the coexistence of different shapes and of configuration mixing. (author)

Evolution of low-temperature phases in a low-temperature structural transition of a La cuprate

International Nuclear Information System (INIS)

Inoue, Y.; Horibe, Y.; Koyama, Y.

1997-01-01

The microstructure produced by a low-temperature structural phase transition in La 1.5 Nd 0.4 Sr 0.1 CuO 4 has been examined by transmission electron microscopy with the help of imaging plates. The low-temperature transition was found to be proceeded not only by the growth of the Pccn/low-temperature-tetragonal phases nucleated along the twin boundary but also by the nucleation and growth of the phases in the interior of the low-temperature-orthorhombic domain. In addition, because the map of the octahedron tilt as an order parameter is not identical to that of the spontaneous strain accompanied by the transition, the microstructure below the transition is understood to be a very complex mixture of the low-temperature phases. copyright 1997 The American Physical Society

Transition densities with electron scattering

International Nuclear Information System (INIS)

Heisenberg, J.

1985-01-01

This paper reviews the ground state and transition charge densities in nuclei via electron scattering. Using electrons as a spectroscopic tool in nuclear physics, these transition densities can be determined with high precision, also in the nuclear interior. These densities generally ask for a microscopic interpretation in terms of contributions from individual nucleons. The results for single particle transitions confirm the picture of particle-phonon coupling. (Auth.)

Properties of low-lying intruder states in $^{34}$Al and $^{34}$Si sequentially populated in $\\beta$-decay of $^{34}$Mg

CERN Multimedia

A low-lying long-lived (26±1 ms) isomer in $^{34}$Al has been observed recently and assigned as 1$^{+}$ state of intruder character. It was populated in $^{36}$S fragmentation and feeds, in $\\beta$-decay, the 0$_{2}^{+}$ state in $^{34}$Si whose excitation energy and lifetime were determined in an electron-positron pairs spectroscopy experiment. In the present experiment we intend to measure for the first time the $\\gamma$-rays following the $\\beta$-decay of $^{34}$Mg. Despite the interest for $^{34}$Mg, the up-right corner of the “N$\\thicksim$20 island of inversion”, the only information on its $\\beta$-decay is the lifetime of 20±10 ms, determined from $\\beta$-neutron coincidences. As a result of the proposed experiment, we expect to place the first transitions in the level scheme of $^{34}$Al and to strongly populate the newly observed isomer, measuring its excitation energy, if the branching ratio to 4$^{−}$ ground state is significant. Theoretical estimations for the $\\beta$-decay of the new isome...

Transitive Lie algebras of vector fields: an overview

NARCIS (Netherlands)

Draisma, J.

2011-01-01

This overview paper is intended as a quick introduction to Lie algebras of vector fields. Originally introduced in the late 19th century by Sophus Lie to capture symmetries of ordinary differential equations, these algebras, or infinitesimal groups, are a recurring theme in 20th-century research on

On the electron density localization in elemental cubic ceramic and FCC transition metals by means of a localized electrons detector.

Science.gov (United States)

Aray, Yosslen; Paredes, Ricardo; Álvarez, Luis Javier; Martiz, Alejandro

2017-06-14

The electron density localization in insulator and semiconductor elemental cubic materials with diamond structure, carbon, silicon, germanium, and tin, and good metallic conductors with face centered cubic structure such as α-Co, Ni, Cu, Rh, Pd, Ag, Ir, Pt, and Au, was studied using a localized electrons detector defined in the local moment representation. Our results clearly show an opposite pattern of the electron density localization for the cubic ceramic and transition metal materials. It was found that, for the elemental ceramic materials, the zone of low electron localization is very small and is mainly localized on the atomic basin edges. On the contrary, for the transition metals, there are low-valued localized electrons detector isocontours defining a zone of highly delocalized electrons that extends throughout the material. We have found that the best conductors are those in which the electron density at this low-value zone is the lowest.

Saturated bonds and anomalous electronic transport in transition-metal aluminides

Energy Technology Data Exchange (ETDEWEB)

Schmidt, T.

2006-05-22

This thesis deals with the special electronic properties of the transition-metal aluminides. Following quasicrystals and their approximants it is shown that even materials with small elementary cells exhibit the same surprising effects. So among the transition-metal aluminides also semi-metallic and semiconducting compounds exist, although if they consist of classic-metallic components like Fe, Al, or Cr. These properties are furthermore coupled with a deep pseusogap respectively gap in the density of states and strongly covalent bonds. Bonds are described in this thesis by two eseential properties. First by the bond charge and second by the energetic effect of the bond. It results that in the caes of semiconducting transition-metal aluminides both a saturation of certain bonds and a bond-antibond alteration in the Fermi level is present. By the analysis of the near-order in form of the so-calles coordination polyeders it has been succeeded to establish a simple rule for semiconductors, the five-fold coordination for Al. This rule states that aluminium atoms with their three valence electrons are not able to build more than five saturated bonds to their nearest transition-metal neighbours. In excellent agreement with the bond angles predicted theoretically under assumption of equal-type bonds it results that all binary transition-element aluminide semiconductors exhibit for the Al atoms the same near order. Typical values for specific resistances of the studied materials at room temperature lie in the range of some 100 {mu}{omega}cm, which is farly larger than some 10 {mu}{omega}cm as in the case of the unalloyed metals. SUrprising is furthermore a high transport anisotropy with a ratio of the specific resistances up to 3.0. An essential result of this thesis can be seen in the coupling of the properties of the electronic transport and the bond properties. The small conducitivities could be explained by small values in the density of states and a bond

The scaling dimension of low lying Dirac eigenmodes and of the topological charge density

CERN Document Server

Aubin, C.; Gottlieb, Steven; Gregory, E.B.; Heller, Urs M.; Hetrick, J.E.; Osborn, J.; Sugar, R.; Toussaint, D.; de Forcrand, Ph.; Jahn, Oliver

2005-01-01

As a quantitative measure of localization, the inverse participation ratio of low lying Dirac eigenmodes and topological charge density is calculated on quenched lattices over a wide range of lattice spacings and volumes. Since different topological objects (instantons, vortices, monopoles, and artifacts) have different co-dimension, scaling analysis provides information on the amount of each present and their correlation with the localization of low lying eigenmodes.

Electron heating mode transition induced by mixing radio frequency and ultrahigh frequency dual frequency powers in capacitive discharges

International Nuclear Information System (INIS)

Sahu, B. B.; Han, Jeon G.

2016-01-01

Electron heating mode transitions induced by mixing the low- and high-frequency power in dual-frequency nitrogen discharges at 400 mTorr pressure are presented. As the low-frequency (13.56 MHz) power decreases and high-frequency (320 MHz) power increases for the fixed power of 200 W, there is a transition of electron energy distribution function (EEDF) from Druyvesteyn to bi-Maxwellian type characterized by a distinguished warm electron population. It is shown that this EEDF evolution is attributed to the transition from collisional to collisionless stochastic heating of the low-energy electrons.

Electronic transport and dielectric properties of low-dimensional structures of layered transition metal dichalcogenides

Energy Technology Data Exchange (ETDEWEB)

Kumar, Ashok, E-mail: ashok.1777@yahoo.com; Ahluwalia, P.K., E-mail: pk_ahluwalia7@yahoo.com

2014-02-25

Graphical abstract: We present electronic transport and dielectric response of layered transition metal dichalcogenides nanowires and nanoribbons. Illustration 1: Conductance (G) and corresponding local density of states(LDOS) for LTMDs wires at applied bias. I–V characterstics are shown in lowermost panels. Highlights: • The studied configurations show metallic/semiconducting nature. • States around the Fermi energy are mainly contributed by the d orbitals of metal atoms. • The studied configurations show non-linear current–voltage (I–V) characteristics. • Additional plasmonic features at low energy have been observed for both wires and ribbons. • Dielectric functions for both wires and ribbons are anisotropic (isotropic) at low (high) energy range. -- Abstract: We present first principle study of the electronic transport and dielectric properties of nanowires and nanoribbons of layered transition metal dichalcogenides (LTMDs), MX{sub 2} (M = Mo, W; X = S, Se, Te). The studied configuration shows metallic/semiconducting nature and the states around the Fermi energy are mainly contributed by the d orbitals of metal atoms. Zero-bias transmission show 1G{sub 0} conductance for the ribbons of MoS{sub 2} and WS{sub 2}; 2G{sub 0} conductance for MoS{sub 2}, WS{sub 2}, WSe{sub 2} wires, and ribbons of MoTe{sub 2} and WTe{sub 2}; and 3G{sub 0} conductance for WSe{sub 2} ribbon. The studied configurations show non-linear current–voltage (I–V) characteristics. Negative differential conductance (NDC) has also been observed for the nanoribbons of the selenides and tellurides of both Mo and W. Furthermore, additional plasmonic features below 5 eV energy have been observed for both wires and ribbons as compared to the corresponding monolayers, which is found to be red-shifted on going from nanowires to nanoribbons.

Elastic scattering of low-energy electrons with Sr atoms

International Nuclear Information System (INIS)

Yuan, J.; Zhang, Z.; Wan, H.

1990-01-01

Static-exchange, plus correlation-polarization-potential calculations are performed for elastic low-energy electron scattering from Sr atoms while paying attention to the low-lying shape resonances. The correlation potential is calculated both with and without a scaling factor. A 2 D-shape resonance is produced at 1.0 eV with a parameter-free, and at 1.25 eV with a scaled, correlation potential. No 2 P-shape resonances are predicted, but evidence to support the existence of a stable negative ion Sr - in the 5s 2 5p electron configuration is given from the viewpoint of electron scattering. The bound energy of the extra electron in the negative ion is estimated by transforming the phase shift of the corresponding partial wave into the polarization quantum-defect number and extrapolating the number from positive to negative energies

Electronic Structure Evolution across the Peierls Metal-Insulator Transition in a Correlated Ferromagnet

Directory of Open Access Journals (Sweden)

P. A. Bhobe

2015-10-01

Full Text Available Transition metal compounds often undergo spin-charge-orbital ordering due to strong electron-electron correlations. In contrast, low-dimensional materials can exhibit a Peierls transition arising from low-energy electron-phonon-coupling-induced structural instabilities. We study the electronic structure of the tunnel framework compound K_{2}Cr_{8}O_{16}, which exhibits a temperature-dependent (T-dependent paramagnetic-to-ferromagnetic-metal transition at T_{C}=180  K and transforms into a ferromagnetic insulator below T_{MI}=95  K. We observe clear T-dependent dynamic valence (charge fluctuations from above T_{C} to T_{MI}, which effectively get pinned to an average nominal valence of Cr^{+3.75} (Cr^{4+}∶Cr^{3+} states in a 3∶1 ratio in the ferromagnetic-insulating phase. High-resolution laser photoemission shows a T-dependent BCS-type energy gap, with 2G(0∼3.5(k_{B}T_{MI}∼35  meV. First-principles band-structure calculations, using the experimentally estimated on-site Coulomb energy of U∼4  eV, establish the necessity of strong correlations and finite structural distortions for driving the metal-insulator transition. In spite of the strong correlations, the nonintegral occupancy (2.25 d-electrons/Cr and the half-metallic ferromagnetism in the t_{2g} up-spin band favor a low-energy Peierls metal-insulator transition.

Core excitations to the low lying states of thallium isotopes

International Nuclear Information System (INIS)

Gruenbaum, L.; Tomaselli, M.; Herold, D.

1977-08-01

The admixture of core excitations to the low lying states of A = 203 and A = 205 thallium isotopes has been calculated. The wave functions obtained reproduce the electromagnetic properties as well as the hyperfine splittings and the isomershifts of both thallium isotopes. (orig.) [de

Lie algebraic approach to valence bond theory of π-electron systems: a preliminary study of excited states

Science.gov (United States)

Paldus, J.; Li, X.

1992-10-01

Following a brief outline of various developments and exploitations of the unitary group approach (UGA), and its extension referred to as Clifford algebra UGA (CAUGA), in molecular electronic structure calculations, we present a summary of a recently introduced implementation of CAUGA for the valence bond (VB) method based on the Pariser-Parr-Pople (PPP)-type Hamiltonian. The existing applications of this PPP-VB approach have been limited to groundstates of various π-electron systems or, at any rate, to the lowest states of a given multiplicity. In this paper the method is applied to the low-lying excited states of several archetypal models, namely cyclobutadiene and benzene, representing antiaromatic and aromatic systems, hexatriene, representing linear polyenic systems and, finally, naphthalene, representing polyacenes.

Low-lying dipole response in the stable 40,48Ca nuclei within the second random-phase approximation

International Nuclear Information System (INIS)

Gambacurta, D.; Grasso, M.; Catara, F.

2012-01-01

The low-lying dipole strength distributions of 40 CaCa and 48 Ca, in the energy region between 5 and 10 MeV, are studied within the second random phase approximation (RPA) with Skyrme interaction. Standard RPA models do not usually predict any presence of strength in this energy region, while experimentally a significant amount of strength is found. The inclusion of the 2 particle −2 hole configurations allows to obtain a description in a rather good agreement with the experimental data. The properties of the most collective state are analyzed in terms of its 1 particle −1 hole nature and its transition densities.

Low-lying dipole response in the stable 40,48Ca nuclei within the second random-phase approximation

Science.gov (United States)

Gambacurta, D.; Grasso, M.; Catara, F.

2012-10-01

The low-lying dipole strength distributions of 40CaCa and 48Ca, in the energy region between 5 and 10 MeV, are studied within the second random phase approximation (RPA) with Skyrme interaction. Standard RPA models do not usually predict any presence of strength in this energy region, while experimentally a significant amount of strength is found. The inclusion of the 2 particle -2 hole configurations allows to obtain a description in a rather good agreement with the experimental data. The properties of the most collective state are analyzed in terms of its 1 particle -1 hole nature and its transition densities.

Microscopic study of low-lying yrast spectra and deformation ...

Indian Academy of Sciences (India)

73, No. 4. — journal of. October 2009 physics pp. 657–668. Microscopic study of low-lying yrast spectra and deformation systematics in neutron-rich. 98−106Sr isotopes ... with a large and rigid moment of inertia. 98Sr is predicted to have a ... 2 energy as neutron number N changes from 58 to 60. The onset of deformation in ...

The electronic structure of vanadium monochloride cation (VCl{sup +}): Tackling the complexities of transition metal species

Energy Technology Data Exchange (ETDEWEB)

DeYonker, Nathan J., E-mail: ndyonker@memphis.edu [Department of Chemistry, The University of Memphis, Memphis, Tennessee 38152 (United States); Halfen, DeWayne T.; Ziurys, Lucy M. [Department of Chemistry, Department of Astronomy, Arizona Radio Observatory, and Steward Observatory, University of Arizona, Tucson, Arizona 85721 (United States); Allen, Wesley D. [Department of Chemistry and Center for Computational Chemistry, University of Georgia, Athens, Georgia 30602 (United States)

2014-11-28

Six electronic states (X {sup 4}Σ{sup −}, A {sup 4}Π, B {sup 4}Δ, {sup 2}Φ, {sup 2}Δ, {sup 2}Σ{sup +}) of the vanadium monochloride cation (VCl{sup +}) are described using large basis set coupled cluster theory. For the two lowest quartet states (X {sup 4}Σ{sup −} and A {sup 4}Π), a focal point analysis (FPA) approach was used that conjoined a correlation-consistent family of basis sets up to aug-cc-pwCV5Z-DK with high-order coupled cluster theory through pentuple (CCSDTQP) excitations. FPA adiabatic excitation energies (T{sub 0}) and spectroscopic constants (r{sub e}, r{sub 0}, B{sub e}, B{sub 0}, D{sup ¯}{sub e}, H{sub e}, ω{sub e}, v{sub 0}, α{sub e}, ω{sub e}x{sub e}) were extrapolated to the valence complete basis set Douglas-Kroll (DK) aug-cc-pV∞Z-DK CCSDT level of theory, and additional treatments accounted for higher-order valence electron correlation, core correlation, and spin-orbit coupling. Due to the delicate interplay between dynamical and static electronic correlation, single reference coupled cluster theory is able to provide the correct ground electronic state (X {sup 4}Σ{sup −}), while multireference configuration interaction theory cannot. Perturbations from the first- and second-order spin orbit coupling of low-lying states with quartet spin multiplicity reveal an immensely complex rotational spectrum relative to the isovalent species VO, VS, and TiCl. Computational data on the doublet manifold suggest that the lowest-lying doublet state ({sup 2}Γ) has a T{sub e} of ∼11 200 cm{sup −1}. Overall, this study shows that laboratory and theoretical rotational spectroscopists must work more closely in tandem to better understand the bonding and structure of molecules containing transition metals.

More evidence of localization in the low-lying Dirac spectrum

CERN Document Server

Bernard, C; Gottlieb, Steven; Levkova, L.; Heller, U.M.; Hetrick, J.E.; Jahn, O.; Maresca, F.; Renner, Dru Bryant; Toussaint, D.; Sugar, R.; Forcrand, Ph. de; Gottlieb, Steven

2006-01-01

We have extended our computation of the inverse participation ratio of low-lying (asqtad) Dirac eigenvectors in quenched SU(3). The scaling dimension of the confining manifold is clearer and very near 3. We have also computed the 2-point correlator which further characterizes the localization.

Dielectronic recombination into excited levels of Ne-like titanium from F-like low-lying states

International Nuclear Information System (INIS)

Qiu Yanghui; Li Shichang; Sun Yongsheng

1993-01-01

The energy levels, wavelengths, oscillator strengths, Auger rates and level-to-level dielectronic recombination rate coefficients describing dielectronic recombination into excited levels of Ne-like titanium from F-like low-lying states are calculated. Our calculations are based on Dr. R.D. Cowan's semi-relativistic mass-velocity and Darwin corrections are included in the Hamiltonian, and the distorted-wave model is used for the calculation of free electron wavefunctions. In order to set the recombination rate coefficients on a level by level basis, in a manner compatible with detailed level population kinetics modelling of highly-stripped ions in plasma, the dielectronic recombination rate coefficients as a function of free electron temperatures are given in an analytical form, which is not only very convenient in practice, but also hopefully accurate compared with the exactly calculated numerical results. (orig.)

An investigation of the reflection of low energy electrons from the surfaces of layered transition metal dichalcogenides

International Nuclear Information System (INIS)

Smith, A.E.; Mohamed, M.H.; Wohlenberg, T.; Johnson, E.; Chadderton, L.T.; Moeller, P.J.

1980-01-01

Experimental measurements, using the total current spectroscopy (TCS) technique, on the energy dependence of the reflection of low energy electrons from clean surfaces of layered transition metal dichalcogenides are reported for the molybdenum semiconductor compounds 2H-MoS 2 and 2H-MoSe 2 . A simple model calculation involving both elastic and inelastic scattering is presented and correspondence established with the experimental spectra. In this picture information on the electronic band structure of the materials can then be extracted from the single particle component of the inelastic scattering. The model is extended to show that a feature in the 2H-MoS 2 experimental spectrum may be attributed to the excitation of an intermediate plasmon. (Auth.)

Magnetic and Structural Phase Transitions in Thulium under High Pressures and Low Temperatures

Energy Technology Data Exchange (ETDEWEB)

Vohra, Yogesh K.; Tsoi, Georgiy M.; Samudrala, Gopi K. [UAB

2017-10-01

The nature of 4f electrons in many rare earth metals and compounds may be broadly characterized as being either "localized" or "itinerant", and is held responsible for a wide range of physical and chemical properties. The pressure variable has a very dramatic effect on the electronic structure of rare earth metals which in turn drives a sequence of structural and magnetic transitions. We have carried out four-probe electrical resistance measurements on rare earth metal Thulium (Tm) under high pressures to 33 GPa and low temperatures to 10 K to monitor the magnetic ordering transition. These studies are complemented by angle dispersive x-ray diffraction studies to monitor crystallographic phase transitions at high pressures and low temperatures. We observe an abrupt increase in magnetic ordering temperature in Tm at a pressure of 17 GPa on phase transition from ambient pressure hcp-phase to α-Sm phase transition. In addition, measured equation of state (EOS) at low temperatures show anomalously low thermal expansion coefficients likely linked to magnetic transitions.

A density matrix renormalization group study of low-lying excitations ...

Indian Academy of Sciences (India)

Symmetrized density-matrix-renormalization-group calculations have been carried out, within Pariser-Parr-Pople Hamiltonian, to explore the nature of the ground and low-lying excited states of long polythiophene oligomers. We have exploited 2 symmetry and spin parity of the system to obtain excited states of ...

Electron collisions with Fe-peak elements: Forbidden transitions between the low lying valence states 3d6, 3d54s, and 3d54p of Fe III

International Nuclear Information System (INIS)

McLaughlin, B.M.; Scott, M.P.; Sunderland, A.G.; Noble, C.J.; Burke, V.M.; Ramsbottom, C.A.; Reid, R.H.G.; Hibbert, A.; Bell, K.L.; Burke, P.G.

2007-01-01

Effective collision strengths are presented for the Fe-peak element Fe III at electron temperatures (T e in degrees Kelvin) in the range 2 x 10 3 to 1 x 10 6 . Forbidden transitions results are given between the 3d 6 , 3d 5 4s, and the 3d 5 4p manifolds applicable to the modeling of laboratory and astrophysical plasmas

Elementary and advanced Lie algebraic methods with applications to accelerator design, electron microscopes, and light optics

International Nuclear Information System (INIS)

Dragt, A.J.

1987-01-01

A review is given of elementary Lie algebraic methods for treating Hamiltonian systems. This review is followed by a brief exposition of advanced Lie algebraic methods including resonance bases and conjugacy theorems. Finally, applications are made to the design of third-order achromats for use in accelerators, to the design of subangstroem resolution electron microscopes, and to the classification and study of high order aberrations in light optics. (orig.)

Shape mixing dynamics in the low-lying states of proton-rich Kr isotopes

International Nuclear Information System (INIS)

Sato, Koichi; Hinohara, Nobuo

2011-01-01

We study the oblate-prolate shape mixing in the low-lying states of proton-rich Kr isotopes using the five-dimensional quadrupole collective Hamiltonian. The collective Hamiltonian is derived microscopically by means of the CHFB (constrained Hartree-Fock-Bogoliubov) + Local QRPA (quasiparticle random phase approximation) method, which we have developed recently on the basis of the adiabatic self-consistent collective coordinate method. The results of the numerical calculation show the importance of large-amplitude collective vibrations in the triaxial shape degree of freedom and rotational effects on the oblate-prolate shape mixing dynamics in the low-lying states of these isotopes.

Electronic structure of the [MNH2]+ (M = Sc-Cu) complexes.

Science.gov (United States)

Hendrickx, Marc F A; Clima, Sergiu

2006-11-23

B3LYP geometry optimizations for the [MNH2]+ complexes of the first-row transition metal cations (Sc+-Cu+) were performed. Without any exception the ground states of these unsaturated amide complexes were calculated to possess planar geometries. CASPT2 binding energies that were corrected for zero-point energies and including relativistic effects show a qualitative trend across the series that closely resembles the experimental observations. The electronic structures for the complexes of the early and middle transition metal cations (Sc+-Co+) differ from the electronic structures derived for the complexes of the late transition metal cations (Ni+ and Cu+). For the former complexes the relative higher position of the 3d orbitals above the singly occupied 2p(pi) HOMO of the uncoordinated NH2 induces an electron transfer from the 3d shell to 2p(pi). The stabilization of the 3d orbitals from the left to the right along the first-row transition metal series causes these orbitals to become situated below the HOMO of the NH2 ligand for Ni+ and Cu+, preventing a transfer from occurring in the [MNH2]+ complexes of these metal cations. Analysis of the low-lying states of the amide complexes revealed a rather unique characteristic of their electronic structures that was found across the entire series. Rather exceptionally for the whole of chemistry, pi-type interactions were calculated to be stronger than the corresponding sigma-type interactions. The origin of this extraordinary behavior can be ascribed to the low-lying sp2 lone pair orbital of the NH2 ligand with respect to the 3d level.

Low-lying dipole response in the stable {sup 40,48}Ca nuclei within the second random-phase approximation

Energy Technology Data Exchange (ETDEWEB)

Gambacurta, D.; Grasso, M.; Catara, F. [GANIL,CEA/DSM-CNRS/IN2P3, Caen (France); Institut de Physique Nucleaire, Universite Paris-Sud, IN2P3-CNRS, F-91406 Orsay Cedex (France); Dipartimento di Fisica e Astronomia dell' Universita di and INFN Catania (Italy)

2012-10-20

The low-lying dipole strength distributions of {sup 40}CaCa and {sup 48}Ca, in the energy region between 5 and 10 MeV, are studied within the second random phase approximation (RPA) with Skyrme interaction. Standard RPA models do not usually predict any presence of strength in this energy region, while experimentally a significant amount of strength is found. The inclusion of the 2 particle -2 hole configurations allows to obtain a description in a rather good agreement with the experimental data. The properties of the most collective state are analyzed in terms of its 1 particle -1 hole nature and its transition densities.

Low energy E0 transitions in odd-mass nuclei of the neutron deficient 180 < A < 200 region

International Nuclear Information System (INIS)

Zganjar, E.F.; Kortelahti, M.O.; Wood, J.L.; Papanicolopulos, C.D.

1987-01-01

The region of neutron-deficient nuclei near Z = 82 and N = 104 provides the most extensive example of low-energy shape coexistence anywhere on the mass surface. It is shown that E0 and E0 admixed transitions may be used as a fingerprint to identify shape coexistence in odd-mass nuclei. It is also shown that all the known cases of low energy E0 and E0 admixed transitions in odd-mass nuclei occur where equally low-lying O + states occur in neighboring even-even nuclei. A discussion of these and other relevant data as well as suggestions for new studies which may help to clarify and, more importantly, quantify the connection between E0 transitions and shape coexistence are presented. 60 refs., 7 figs., 4 tabs

Spectroscopic study of low-lying 16N levels

International Nuclear Information System (INIS)

Bardayan, Daniel W.; O'Malley, Patrick; Blackmon, Jeff C.; Chae, K.Y.; Chipps, K.; Cizewski, J.A.; Hatarik, Robert; Jones, K.L.; Kozub, R. L.; Matei, Catalin; Moazen, Brian; Nesaraja, Caroline D.; Pain, Steven D.; Paulauskas, Stanley; Peters, W.A.; Pittman, S.T.; Schmitt, Kyle; Shriner, J.F. Jr.; Smith, Michael Scott

2008-01-01

The magnitude of the 15N(n,gamma)16N reaction rate in asymptotic giant branch stars depends directly on the neutron spectroscopic factors of low-lying 16N levels. A new study of the 15N(d,p)16N reaction is reported populating the ground and first three excited states in 16N. The measured spectroscopic factors are near unity as expected from shell model calculations, resolving a long-standing discrepancy with earlier measurements that had never been confirmed or understood. Updated 15N(n,gamma)16N reaction rates are presented

Factors associated with low-lying intrauterine devices: a cross-sectional ultrasound study in a cohort of African-American women.

Science.gov (United States)

Moshesh, Malana; Saldana, Tina; Deans, Elizabeth; Cooper, Tracy; Baird, Donna

2018-03-14

The object of this study is to examine factors and symptoms associated with low-lying IUDs as defined by ultrasound. This is a cross-sectional sub-study of participants in the Study of Environment, Life-style, and Fibroids (SELF). SELF participants had screening ultrasounds for fibroids at study enrollment; those with an IUD in place are included in this sub-study. Low-lying IUDs were identified and localized. Logistic regression was used to identify factors and symptoms associated with low-lying IUDs. Among 168 women with IUDs at ultrasound, 28 (17%) had a low-lying IUD. Having a low-lying IUD was associated with low education level (≤high school: aOR 3.1 95% CI 1.14-8.55) and with increased BMI (p=.002). Women with a low-lying IUD were more likely to report a "big problem" with dysmenorrhea (the highest option of the Likert scale) as compared to women with a normally-positioned IUD (OR 3.2 95% CI 1.07-9.54). Our study found that women with a low-lying IUD are more likely to be of lower education and higher BMI, and to report more dysmenorrhea. Women who are obese may benefit from additional counseling and closer follow-up after IUD placement. Future research is warranted to investigate IUD placement and possible IUD migration among women who are obese. Copyright © 2018 Elsevier Inc. All rights reserved.

E3-transitions in sup(105, 107, 109, 111)Ag

International Nuclear Information System (INIS)

Shevelev, G.A.; Troitskaya, A.G.; Kartashov, V.M.

1978-01-01

Electron radiation of the isomeric transitions of the sup(105-111)Ag odd nuclei was studied using an iron magnetic πsup(√2) beta spectrometer. For most isomeric transitions, relative intensities of the K, L, M, and N lines have been measured; for sup(105-111)Ag and 111 Cd they were measured for the first time. Energy of gamma transitions, relative intensities of internal conversion electrons (ICE) compared with the theoretical ICE values for the E3 transitions are presented. The observations for all the shells are in a fairly gool agreement with the calculations. Systematics of low-lying excited states of the silver nuclei involved is proposed. It has been established that spins and parities of the first excited states of the sup(105-111)Ag odd nuclei are 7/2 + . Multipolarities of isomeric transitions from these staes are pure E3. Spin and parity 9/2 + of the second excited states may be uniquely determined unly for 109 Ag from direct measurements of the ICE transition at 45.8 keV

Theoretical description of high-lying two-electrons states

International Nuclear Information System (INIS)

Greene, C.H.; Cavagnero, M.; Sadeghpour, H.R.

1993-01-01

Within the past two years, experiments on high-lying doubly-excited states in He and H- have shown spectra at energies near excited hydrogenic thresholds having principal quantum numbers in the range N=5--9. While they display some nontrivial complexities, the spectra are tremendously simpler than might be anticipated on the basis of independent electron models, in that only a small fraction of the total number of anticipated resonances are observed experimentally. Moreover, for principal quantum number N that are not too high, specifically N - , the resonance positions are described accurately by adiabatic calculations using hyperspherical coordinates and can be parametrized by a remarkably simple two-electron Rydberg formula. The observed propensity for excitation of only a small subset of the possible resonance states has been codified by several groups into approximate selection rules based on alternative (but apparently equivalent) classification schemes. Comparatively few attempts have been made at quantitative tests of the validity of these rules. The present review describes recent efforts to quantify their accuracy and limitations using R-matrix and quantum defect techniques, and Smith's delay-time matrix. Prospensity rules for exciting different degrees of freedom are found to differ greatly in their degree of validity

Size-dependent single electron transfer and semi-metal-to-insulator transitions in molecular metal oxide electronics

Science.gov (United States)

Balliou, Angelika; Bouroushian, Mirtat; Douvas, Antonios M.; Skoulatakis, George; Kennou, Stella; Glezos, Nikos

2018-07-01

All-inorganic self-arranged molecular transition metal oxide hyperstructures based on polyoxometalate molecules (POMs) are fabricated and tested as electronically tunable components in emerging electronic devices. POM hyperstructures reveal great potential as charging nodes of tunable charging level for molecular memories and as enhancers of interfacial electron/hole injection for photovoltaic stacks. STM, UPS, UV–vis spectroscopy and AFM measurements show that this functionality stems from the films’ ability to structurally tune their HOMO–LUMO levels and electron localization length at room temperature. By adapting POM nanocluster size in solution, self-doping and current modulation of four orders of magnitude is monitored on a single nanocluster on SiO2 at voltages as low as 3 Volt. Structurally driven insulator-to-semi-metal transitions and size-dependent current regulation through single electron tunneling are demonstrated and examined with respect to the stereochemical and electronic structure of the molecular entities. This extends the value of self-assembly as a tool for correlation length and electronic properties tuning and demonstrate POM hyperstructures’ plausibility for on-chip molecular electronics operative at room temperature.

Size-dependent single electron transfer and semi-metal-to-insulator transitions in molecular metal oxide electronics.

Science.gov (United States)

Balliou, Angelika; Bouroushian, Mirtat; Douvas, Antonios M; Skoulatakis, George; Kennou, Stella; Glezos, Nikos

2018-07-06

All-inorganic self-arranged molecular transition metal oxide hyperstructures based on polyoxometalate molecules (POMs) are fabricated and tested as electronically tunable components in emerging electronic devices. POM hyperstructures reveal great potential as charging nodes of tunable charging level for molecular memories and as enhancers of interfacial electron/hole injection for photovoltaic stacks. STM, UPS, UV-vis spectroscopy and AFM measurements show that this functionality stems from the films' ability to structurally tune their HOMO-LUMO levels and electron localization length at room temperature. By adapting POM nanocluster size in solution, self-doping and current modulation of four orders of magnitude is monitored on a single nanocluster on SiO 2 at voltages as low as 3 Volt. Structurally driven insulator-to-semi-metal transitions and size-dependent current regulation through single electron tunneling are demonstrated and examined with respect to the stereochemical and electronic structure of the molecular entities. This extends the value of self-assembly as a tool for correlation length and electronic properties tuning and demonstrate POM hyperstructures' plausibility for on-chip molecular electronics operative at room temperature.

Computations in finite-dimensional Lie algebras

Directory of Open Access Journals (Sweden)

A. M. Cohen

1997-12-01

Full Text Available This paper describes progress made in context with the construction of a general library of Lie algebra algorithms, called ELIAS (Eindhoven Lie Algebra System, within the computer algebra package GAP. A first sketch of the package can be found in Cohen and de Graaf[1]. Since then, in a collaborative effort with G. Ivanyos, the authors have continued to develop algorithms which were implemented in ELIAS by the second author. These activities are part of a bigger project, called ACELA and financed by STW, the Dutch Technology Foundation, which aims at an interactive book on Lie algebras (cf. Cohen and Meertens [2]. This paper gives a global description of the main ways in which to present Lie algebras on a computer. We focus on the transition from a Lie algebra abstractly given by an array of structure constants to a Lie algebra presented as a subalgebra of the Lie algebra of n×n matrices. We describe an algorithm typical of the structure analysis of a finite-dimensional Lie algebra: finding a Levi subalgebra of a Lie algebra.

Ab initio effective core potentials for molecular calculations. Potentials for the transition metal atoms Sc to Hg

International Nuclear Information System (INIS)

Hay, P.J.; Wadt, W.R.

1985-01-01

Ab initio effective core potentials (ECP's) have been generated to replace the Coulomb, exchange, and core-orthogonality effects of the chemically inert core electron in the transition metal atoms Sc to Hg. For the second and third transition series relative ECP's have been generated which also incorporate the mass--velocity and Darwin relativistic effects into the potential. The ab initio ECP's should facilitate valence electron calculations on molecules containing transition-metal atoms with accuracies approaching all-electron calculations at a fraction of the computational cost. Analytic fits to the potentials are presented for use in multicenter integral evaluation. Gaussian orbital valence basis sets are developed for the (3d,4s,4p), (4d,5s,5p), and (5d,6s,6p) orbitals of the first, second, and third transition series atoms, respectively. All-electron and valence-electron atomic excitation energies are also compared for the low-lying states of Sc--Hg, and the valence-electron calculations are found to reproduce the all-electron excitation energies (typically within a few tenths of an eV)

Rigid muffin-tin approximation for the electron-phonon interaction in transition metals

International Nuclear Information System (INIS)

Butler, W.H.

1980-01-01

Progress in calculating the electron-phonon parameters of transition metals has been based on either the rigid muffin-tin approximation (RMTA) or the fitted modified tight-binding approximation (FMTBA). The RMTA has been shown to be remarkably accurate for average electron-phonon properties, but there are indications that RMTA matrix elements may be too small at low momentum transfer. An attempt is made to demonstrate these assertions concerning the accuracy of RMTA and the numerous electron-phonon calculations are placed in a broader perspective by a demonstration of how they can be used to explain the trends in the strength of the electron-phonon coupling among the transition metals and the A-15 compounds

Rigid muffin-tin approximation for the electron-phonon interaction in transition metals

Energy Technology Data Exchange (ETDEWEB)

Butler, W.H.

1980-01-01

Progress in calculating the electron-phonon parameters of transition metals has been based on either the rigid muffin-tin approximation (RMTA) or the fitted modified tight-binding approximation (FMTBA). The RMTA has been shown to be remarkably accurate for average electron-phonon properties, but there are indications that RMTA matrix elements may be too small at low momentum transfer. An attempt is made to demonstrate these assertions concerning the accuracy of RMTA and the numerous electron-phonon calculations are placed in a broader perspective by a demonstration of how they can be used to explain the trends in the strength of the electron-phonon coupling among the transition metals and the A-15 compounds. (GHT)

Properties of a new magnetic dipole mode discovered in low energy electron scattering

International Nuclear Information System (INIS)

Bohle, D.; Guhr, T.; Hartmann, U.; Hummel, K.D.; Kilgus, G.; Milkau, U.; Richter, A.

1986-01-01

In a large range of nuclei low lying J π =1 + states have been found that are excited predominantly by a new M1 mode. Four properties of the new mode will be discussed in detail. Firstly, from the excitation energy systematics observed the strength of the Majorana force of the interacting boson model (IBA) is deduced. Secondly, through the comparison of electron scattering and proton scattering experiments it is shown that the new mode is largely due to the orbital motion of protons with respect to neutrons. Thirdly, taking the nucleus 164 Dy as an example, g-factors and effective boson charges of the M1-, E2- and M3 IBA transition operators, respectively, are studied. The F-scalar magnetic octupol g-factor Ω S is derived for the first time. Finally, the distribution of M1 strength in 156 Gd will be discussed in the light of recent theoretical calculations. (orig.)

M1 transitions between low-lying states in the sdg-IBM-2

Science.gov (United States)

Casperson, Robert; Werner, Volker

2006-10-01

The interplay between collective and single-particle degrees of freedom for nuclei in the A=90 region have recently been under investigation. In Molybdenum and Ruthenium nuclei, collective symmetric and mixed-symmetric structures have been identified, while in Zirconium, underlying shell-structure plays an enhanced role. Collective symmetric structures appear when protons and neutrons are in phase, whereas mixed-symmetric structures occur when they are not. The one-phonon 2^+ mixed-symmetric state was identified from strong M1 transitions to the 2^+1 state. Similar transitions were observed between higher-spin states, and are predicted by the shell model. These phenomena will be investigated within the sdg Interacting Boson Model 2 in order to obtain a better understanding about the structure of the states involved, and results from first model calculations will be presented. Work supported by US DOE under grant number DE-FG02-91ER-40609.

Effects of pairing correlation on low-lying quasi-particle resonance in neutron drip-line nuclei

OpenAIRE

Kobayashi, Yoshihiko; Matsuo, Masayuki

2015-01-01

We discuss effects of pairing correlation on quasi-particle resonance. We analyze in detail how the width of low-lying quasi-particle resonance is governed by the pairing correlation in the neutron drip-line nuclei. We consider the 46Si + n system to discuss low-lying p wave quasi-particle resonance. Solving the Hartree-Fock-Bogoliubov equation in the coordinate space with scattering boundary condition, we calculate the phase shift, the elastic cross section, the resonance width and the reson...

Solubility of hydrogen in transition metals

International Nuclear Information System (INIS)

Lee, H.M.

1976-01-01

Correlations exist between the heat of solution of hydrogen and the difference in energy between the lowest lying energy levels of the trivalent d/sup n-1/s electronic configuration and the divalent d/sup n-2/s 2 (or the tetravalent d/sup n/) configuration of the neutral gaseous atoms. The trends observed in the transition metal series are discussed in relation to the number of valence electrons per atom in the transition elements in their metallic and neutral states

Electronic structure of some adenosine receptor antagonists. III. Quantitative investigation of the electronic absorption spectra of alkyl xanthines

Science.gov (United States)

Moustafa, H.; Shalaby, Samia H.; El-sawy, K. M.; Hilal, Rifaat

2002-07-01

Quantitative and comparative investigation of the electronic absorption spectra of theophylline, caffeine and their derivatives is reported. The spectra of theophylline, caffeine and theobromine were compared to establish the predominant tautomeric species in solution. This comparison, analysis of solvent effects and assignments of the observed transitions via MO computations indicate the exits of only one tautomeric species in solution that is the N7 form. A low-lying triplet state was identified which corresponds to a HOMO-LUMO transition. This relatively long-lived T 1 state is always less polar than the ground state and may very well underlie the photochemical reactivity of alkyl xanthines. Substituents of different electron donating or withdrawing strengths and solvent effects are investigated and analyzed. The present analysis is facilitated via computer deconvolution of the observed spectra and MO computation.

Electronic phase transitions

CERN Document Server

Kopaev, YuV

1992-01-01

Electronic Phase Transitions deals with topics, which are presently at the forefront of scientific research in modern solid-state theory. Anderson localization, which has fundamental implications in many areas of solid-state physics as well as spin glasses, with its influence on quite different research activities such as neural networks, are two examples that are reviewed in this book. The ab initio statistical mechanics of structural phase transitions is another prime example, where the interplay and connection of two unrelated disciplines of solid-state theory - first principle ele

Low-lying nuclear levels and radiative transitions in hadronic atoms

International Nuclear Information System (INIS)

Popov, V.S.; Kudryavtsev, A.E.; Lisin, V.I.; Mur, V.D.

1985-01-01

The analytic theory of nuclear level shifts permit the position of the nuclear level perturbing the Coulomb spectrum to be calculated on the basis of the magnitude of the level shift of a hadron atom. As an example the K -4 He atom is discussed. The experimental data on the 2p-level shift indicate that a weakly bound p-state with a binding energy and width epsilon approximately γ approximately 0.5 MeV may exist in the system. The probabilities for radiative transitions to this level and the cross section for its creation in a nuclear reaction with 6 Li are calculated. The possible existence of weakly coupled K - and anti p states for other light nuclei is discussed. An exact solution of the model Coulomb problem with short range interaction is obtained and this permits the limits of validity of the initial approximations to be determined

Localized versus collective behaviour of d-electrons in transition metal oxide systems of perovskite systems

Energy Technology Data Exchange (ETDEWEB)

Rao, C N.R. [Indian Inst. of Tech., Kanpur

1974-12-01

The behavior of d-electrons in perovskites of the type LnZO/sub 3/ (Z = trivalent transition metal ion and Ln = rare earth or yttrium) depends on the spin configuration of the transition metal ion. LaTiO/sub 3/ and LaNiO/sub 3/ with low-spin transition metal ions (S = 1/2) are metallic while LaCrO/sub 3/, LnMnO/sub 3/ and LnFeO/sub 3/ with high-spin ions are poor semiconductors exhibiting localized behavior of d-electrons. In rare earth cobaltites, the cobalt ions are present mainly in the diamagnetic low-spin Co /sup III/ state at low temperatures. The Co/sup III/ ions transform to high-spin Co/sup 3 +/ ions with increase in temperature. At higher temperatures, there is electron-transfer from Co/sup 3 +/ to Co/sup III/ions producing intermetallic states. Spin-state transitions are seen in these cobaltites in the range 150-870/sup 0/K. At high temperatures, the cobaltites show evidence for localized-itinerant electron transitions. In La/sub 1-x/ Sr/sub x/CoO/sub 3/ there is onset of ferromagnetism at x > 0.125, at which point there is a structural dicontinuity and electrons become itinerant. The composition with x = 0.5 is metallic and T/sub c/ = 230/sup 0/K. The ferromagnetic component in La/sub 1-x/Sr/sub x/ CoO/sub 3/ increases with x in the range 0.125-0.50. Catalytic properties of rare earth cobaltites appear to be related to the spin state equilibria. (auth)

Transition radiation electron beam diagnostic study at ATF

International Nuclear Information System (INIS)

Qiu, X.Z.; Wang, X.J.; Batchelor, K.; Ben-Zvi, I.

1995-01-01

Recently we have started a program to develop transition radiation based electron beam diagnostics at the Accelerator Test Facility at Brookhaven National Laboratory. In this paper, we will discuss a technique to estimate the lower limit in electron beam divergence measurement with single foil transition radiation and two-foil transition radiation interferometer. Preliminary experimental data from 4.5 MeV electron beam will be presented

Explaining the MoVO4- photoelectron spectrum: Rationalization of geometric and electronic structure.

Science.gov (United States)

Thompson, Lee M; Jarrold, Caroline C; Hratchian, Hrant P

2017-03-14

Attempts to reconcile simulated photoelectron spectra of MoVO 4 - clusters are complicated by the presence of very low energy barriers in the potential energy surfaces (PESs) of the lowest energy spin states and isomers. Transition state structures associated with the inversion of terminal oxygen ligands are found to lie below, or close to, the zero point energy of associated modes, which themselves are found to be of low frequency and thus likely to be significantly populated in the experimental characterization. Our simulations make use of Boltzmann averaging over low-energy coordinates and full mapping of the PES to obtain simulations in good agreement with experimental spectra. Furthermore, molecular orbital analysis of accessible final spin states reveals the existence of low energy two-electron transitions in which the final state is obtained from a finite excitation of an electron along with the main photodetachment event. Two-electron transitions are then used to justify the large difference in intensity between different bands present in the photoelectron spectrum. Owing to the general presence of terminal ligands in metal oxide clusters, this study identifies and proposes a solution to issues that are generally encountered when attempting to simulate transition metal cluster photoelectron spectroscopy.

Theoretical study on the low-lying excited states of the phosphorus monoiodide (PI) including the spin-orbit coupling

Science.gov (United States)

Zhang, Xiaomei; Liu, Xiaoting; Liang, Guiying; Li, Rui; Xu, Haifeng; Yan, Bing

2016-01-01

The potential energy curves (PECs) of the 22 Λ-S states of the phosphorus monoiodide (PI) molecule have been calculated at the level of MRCI+Q method with correlation-consistent quadruple-ζ quality basis set. The spectroscopic constants of the bound states are determined, which well reproduce the available measurements. The metastable a1Δ state has been reported for the first time, which lies between the X3Σ- and b1Σ+ states and have much deeper well than the ground state. The R-dependent spin-orbit (SO) matrix elements are calculated with the full-electron Breit-Pauli operator. Based on the SO matrix elements, the perturbations that the 23Π state may suffer from are analyzed in detail. The SOC effect makes the original Λ-S states split into 51 Ω states. In the zero-field splitting of the ground state X3Σ-, the spin-spin coupling contribution (2.23 cm-1) is found to be much smaller compared to the spin-orbit coupling contribution (50 cm-1). The avoided crossings between the Ω states lead to much shallower potential wells and the change of dissociation relationships of the states. The Ω-state wavefunctions are analyzed depending on their Λ-S compositions, showing the strong interactions among several quasidegenerate Λ-S states of the same total SO symmetry. The transition properties including electric dipole (E1), magnetic dipole (M1), and electric quadrupole (E2) transition moments (TMs), the Franck-Condon factors, the transition probabilities and the radiative lifetimes are computed for the transitions between Ω components of a1Δ and b1Σ+ states and ground state. The transition probabilities induced by the E1, E2, and M1 transitions are evaluated. The E2 makes little effect on transition probabilities. In contrast, the E1 transition makes the main contribution to the transition probability and the M1 transition also brings the influence that cannot be neglected. Finally, the radiative lifetimes are determined with the transition moments including E

Shake-off processes at the electron transitions in atoms

International Nuclear Information System (INIS)

Matveev, V.I.; Parilis, Eh.S.

1982-01-01

Elementary processes in multielectron atoms - radiative and Auger transitions, photoionization and ionization by an electron impact etc. are usually followed by the relaxation of electron shells. The conditions under which such multielectron problem could be solved in the shake-off approximation are considered. The shake-off processes occurring. as a result of the electron transitions are described from the general point of view. The common characteristics and peculiar features of this type of excitation in comparison with the electron shake-off under nuclear transformations are pointed out. Several electron shake-off processes are considered, namely: radiative Auger effect, the transition ''two electrons-one photon'', dipole ionization, spectral line broadening, post collision interaction, Auger decay stimulated by collision with fast electrons, three-electron Auger transitions: double and half Auger effect. Their classification is given according to the type of the electron transition causing the shake-off process. The experimental data are presented and the methods of theoretical description are reviewed. Other similar effects, which could follow the transitions in electron shells are pointed out. The deduction of shake-off approximation is presented, and it is pointed out that this approach is analogous to the distorted waves approximation in the theory of scattering. It was shown that in atoms the shake-off approximation is a very effective method, which allows to obtain the probability of different electronic effects

Study of the β- decay of 116m1In: A new interpretation of low-lying 0+ states in 116Sn

Science.gov (United States)

Pore, J. L.; Cross, D. S.; Andreoiu, C.; Ashley, R.; Ball, G. C.; Bender, P. C.; Chester, A. S.; Diaz Varela, A.; Demand, G. A.; Dunlop, R.; Garnsworthy, A. B.; Garrett, P. E.; Hackman, G.; Hadinia, B.; Jigmeddorj, B.; Laffoley, A. T.; Liblong, A.; Kanungo, R.; Noakes, B.; Petrache, C. M.; Rajabali, M. M.; Starosta, K.; Svensson, C. E.; Voss, P. J.; Wang, Z. M.; Wood, J. L.; Yates, S. W.

2017-02-01

The 116Sn nucleus contains a collective rotational band originating from proton π 2 p-2 h excitations across the proton Z=50 shell gap. Even though this nucleus has been extensively investigated in the past, there was still missing information on the low-energy interband transitions connecting the intruder and normal structures. The low-lying structure of 116Sn was investigated through a high-statistics study of the β- decay of 116m1In with the 8π spectrometer and its ancillary detectors at TRIUMF. These measurements are critical in order to properly characterize the π 2 p-2 h rotational band. Weak γ-decay branches are observed utilizing γ-γ coincidence spectroscopy methods, leading to the first direct observation of the 85 keV 22+→ 03+ γ ray with a transition strength of B(E2) = 99.7(84) W.u. The analysis of these results strongly suggests that the 2027 keV 03+ state should replace the previously assigned 1757 keV 02+ state as the band-head of the π 2 p-2 h rotational band.

Superconductivity and the magnetic electron bond

International Nuclear Information System (INIS)

Szurek, P.

1989-01-01

The concept of the magnetic electron bond as the fundamental characteristic of superconductivity was first introduced during a presentation at the 1988 Winter Annual Meeting of the American Society of Mechanical Engineers. Postulates describing the role of the electron and the magnetic bond were suggested to explain in a consistent manner known observations. What may becoming clear is that a boundary set of conditions may exist above and below the transition temperature at which a material superconducts. Prior to recent history, scientists have concentrated on postulating, experimenting, and learning about the set of conditions that exist above the transition temperature, which has set the standard for todays quantum theory. Above the transition temperature they have learned about the interrelationships that exist between the electron, a small magnetic and negatively charged body, and the nucleus, a large positively charged body. By grouping common general characteristics due to the interaction between the outer shell electrons and the nucleus of different elements, three bond types have been established, covalent, ionic, and metallic. They may now be in the process of determining those conditions that lie below the transition temperature, a realm where charge effects may no longer dominate magnetic effects. This may involve updating the quantum theory to reflect those conditions that exist above and below the transition temperature. The following discussion reviews, updates, and attempts to answer some preliminary questions regarding postulates that may define some of the conditions that lie below the transition temperature. As an introduction, figure 1 depicts what may occur to loosely held outer shell electrons below the transition temperature due to increased inner electron shielding. 7 refs., 9 figs

MRCI study on the spectroscopic parameters, transition dipole moments and transition probabilities of 16 low-lying states of the BeB radical

Science.gov (United States)

Zhou, Dan; Shi, Deheng; Sun, Jinfeng; Zhu, Zunlue

2018-03-01

In this work, we calculate the potential energy curves of 16 Λ-S and 36 Ω states of beryllium boride (BeB) radical using the complete active space self-consistent field method, followed by the valence internally contracted multireference configuration interaction approach with Davidson correction. The 16 Λ-S states are the X2Π, A2Σ+, B2Π, C2Δ, D2Ʃ-, E2Σ+, G2Π, I2Σ+, a4Σ-, b4Π, c4Σ-, d4Δ, e4Σ+, g4Π, h4Π, and 24Σ+, which are obtained from the first three dissociation channels of the BeB radical. The Ω states are obtained from the Λ-S states. Of the Λ-S states, the G2Π, I2Σ+, and h4Π states exhibit double well curves. The G2Π, b4Π, and g4Π states are inverted with the spin-orbit coupling effect included. The d4Δ, e4Σ+, and g4Π states as well as the second well of the h4Π state are very weakly bound. Avoided crossings exist between the G2Π and H2Π states, the A2Σ+ and E2Σ+ states, the c4Σ- and f4Σ- states, the g4Π and h4Π states, the I2Σ+ and 42Σ+ states, as well as the 24Σ+ and 34Σ+ states. To improve the quality of the potential energy curves, core-valence correlation and scalar relativistic corrections, as well as the extrapolation of the potential energies to the complete basis set limit, are included. The transition dipole moments are computed. Spectroscopic parameters and vibrational levels are determined along with Franck-Condon factors, Einstein coefficients, and radiative lifetimes of many electronic transitions. The transition probabilities are evaluated. The spin-orbit coupling effect on the spectroscopic parameters and vibrational levels is discussed. The spectroscopic parameters, vibrational levels, and transition probabilities reported in this paper can be considered very reliable and can be employed to predict these states in an appropriate spectroscopy experiment.

Calculation of nuclear excitation in an electron transition

Energy Technology Data Exchange (ETDEWEB)

Pisk, K. (Institut Rudjer Boskovic, Zagreb (Yugoslavia)); Kaliman, Z. (Rijeka Univ. (Yugoslavia). Faculty of Pedagogics); Logan, B.A. (Ottawa Univ., ON (Canada). Ottawa-Carleton Centre for Physics)

1989-11-06

We have made a theoretical investigation of nuclear excitation during an electron transition (NEET). Our approach allows us to express the NEET probabilities in terms of the excited nuclear level width, the energy difference between the nuclear and electron transition, the Coulomb interaction between the initial electron states, and the electron level width. A comparison is made with the available experimental results. (orig.).

Excitation of lowest electronic states of thymine by slow electrons

Science.gov (United States)

Chernyshova, I. V.; Kontros, E. J.; Markush, P. P.; Shpenik, O. B.

2013-11-01

Excitation of lowest electronic states of the thymine molecules in the gas phase is studied by elec- tron energy loss spectroscopy. In addition to dipole-allowed transitions to singlet states, transitions to the lowest triplet states were observed. The low-energy features of the spectrum at 3.66 and 4.61 eV are identified with the excitation of the first triplet states 13 A' (π → π*) and 13 A″ ( n → π*). The higher-lying features at 4.96, 5.75, 6.17, and 7.35 eV are assigned mainly to the excitation of the π → π* transitions to the singlet states of the molecule. The excitation dynamics of the lowest states is studied. It is found that the first triplet state 13 A'(π → π*) is most efficiently excited at a residual energy close to zero, while the singlet 21 A'(π → π*) state is excited with almost identical efficiency at different residual energies.

Going, Going, Gone: The Fate of Low-Lying Islands and Estuaries

OpenAIRE

Cairns, John

2009-01-01

Garrett Hardin s lifeboat metaphor is used to illustrate the problems of overpopulation and finite resources. Sea levels are rising due to excess atmospheric greenhouse gases that melt glaciers and warm the oceans. With anthropogenic greenhouse gas emissions continuing to increase, humankind has placed human culture and individuals at serious risk. Rising sea levels will soon make some low-lying islands uninhabitable.

Low-spin electromagnetic transition probabilities in {sup 102,104}Cd

Energy Technology Data Exchange (ETDEWEB)

Jolie, J.; Dewald, A.; Fransen, C.; Linnemann, A.; Melon, B.; Moeller, O. [Inst. fuer Kernphysik, Univ. zu Koeln (Germany); Boelaert, N. [Inst. fuer Kernphysik, Univ. zu Koeln (Germany); Dept. of Subatomic and Radiation Physics, Gent Univ. (Belgium); Smirnova, N.; Heyde, K. [Dept. of Subatomic and Radiation Physics, Gent Univ. (Belgium)

2007-07-01

Lifetimes of low-lying states in {sup 102,104}Cd were determined by using the recoil distance Doppler shift technique with a plunger device and a Ge array consisting of five HP Ge detectors and one Euroball cluster detector. The experiments were carried out at the Cologne FN Tandem accelerator using the {sup 92,94}Mo({sup 12}C,2n){sup 102,104}Cd reactions. The differential decay curve method in coincidence mode was employed to derive the lifetime of the first excited 2{sup +} state in both nuclei and the first excited 4{sup +} state in {sup 104}Cd. The corresponding E2 transition probabilities agree well with large scale shell-model calculations. (orig.)

Electron spectroscopic investigation of metal–insulator transition in ...

Indian Academy of Sciences (India)

Unknown

Electronic structure of transition metal (TM) oxides has been under detailed investi- ..... Scientific and Industrial Research, New Delhi for a fellowship. ... Maiti K 1998 Novel electronic structures in transition metal oxides, Ph D thesis, Solid.

Effect of high lying states on the ground and few low lying excited O+ energy levels of some closed-shell nuclei

International Nuclear Information System (INIS)

Ayoub, N.Y.

1980-02-01

The ground and some excited O + (J=O, T=O positive parity) energy levels of closed-shell nuclei are examined, in an oscillator basis, using matrix techniques. The effect of states outside the mixed (O+2(h/2π)ω). model space in 4 He (namely configurations at 4(h/2π)ω excitation) are taken into account by renormalization using the generalized Rayleigh-Schroedinger perturbation expressions for a mixed multi-configurational model space, where the resultant non-symmetric energy matrices are diagonalized. It is shown that the second-order renormalized O + energy spectrum is close to the corresponding energy spectrum obtained by diagonalizing the O+2+4(h/2π)ω 4 He energy matrix. The effect, on the ground state and the first few low-lying excited O + energy levels, of renormalizing certain parts of the model space energy matrix up to second order in various approximations is also studied in 4 He and 16 O. It is found that the low-lying O + energy levels in these various approximations behave similarly in both 4 He and 16 O. (author)

Low-lying 1/2-hidden strange pentaquark states in the constituent quark model

Institute of Scientific and Technical Information of China (English)

Hui Li; Zong-Xiu Wu; Chun-Sheng An; Hong Chen

2017-01-01

We investigate the spectrum of the low-lying 1/2-hidden strange pentaquark states,employing the constituent quark model,and looking at two ways within that model of mediating the hyperfine interaction between quarks-Goldstone boson exchange and one gluon exchange.Numerical results show that the lowest 1/2-hidden strange pentaquark state in the Goldstone boson exchange model lies at ～ 1570 MeV,so this pentaquark configuration may form a notable component in S11(1535) if the Goldstone boson exchange model is applied.This is consistent with the prediction that S11 (1535) couples very strongly to strangeness channels.

The low-lying electronic states of BeP: a reliable and accurate quantum mechanical prediction

International Nuclear Information System (INIS)

Ornellas, Fernando R

2009-01-01

A very high level of theoretical treatment (complete active space self-consistent field CASSCF/MRCI/aug-cc-pV5Z) was used to characterize the spectroscopic properties of a manifold of quartet and doublet states of the species BeP, as yet experimentally unknown. Potential energy curves for 11 electronic states were obtained, as well as the associated vibrational energy levels, and a whole set of spectroscopic constants. Dipole moment functions and vibrationally averaged dipole moments were also evaluated. Similarities and differences between BeN and BeP were analysed along with the isovalent SiB species. The molecule BeP has a X 4 Σ - ground state, with an equilibrium bond distance of 2.073 A, and a harmonic frequency of 516.2 cm -1 ; it is followed closely by the states 2 Π (R e = 2.081 A, ω e = 639.6 cm -1 ) and 2 Σ - (R e = 2.074 A, ω e = 536.5 cm -1 ), at 502 and 1976 cm -1 , respectively. The other quartets investigated, A 4 Π (R e = 1.991 A, ω e = 555.3 cm -1 ) and B 4 Σ - (R e = 2.758 A, ω e = 292.2 cm -1 ) lie at 13 291 and 24 394 cm -1 , respectively. The remaining doublets ( 2 Δ, 2 Σ + (2) and 2 Π(3)) all fall below 28 000 cm -1 . Avoided crossings between the 2 Σ + states and between the 2 Π states add an extra complexity to this manifold of states.

Mechanical and electronic properties of Janus monolayer transition metal dichalcogenides

Science.gov (United States)

Shi, Wenwu; Wang, Zhiguo

2018-05-01

The mechanical and electronic properties of Janus monolayer transition metal dichalcogenides MXY (M  =  Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W; X/Y  =  S, Se, Te) were investigated using density functional theory. Results show that breaking the out-of-plane structural symmetry can be used to tune the electronic and mechanical behavior of monolayer transition metal dichalcogenides. The band gaps of monolayer WXY and MoXY are in the ranges of 0.16–1.91 and 0.94–1.69 eV, respectively. A semiconductor to metallic phase transition occurred in Janus monolayer MXY (M  =  Ti, Zr and Hf). The monolayers MXY (M  =  V, Nb, Ta and Cr) show metallic characteristics, which show no dependence on the structural symmetry breaking. The mechanical properties of MXY depended on the composition. Monolayer MXY (M  =  Mo, Ti, Zr, Hf and W) showed brittle characteristic, whereas monolayer CrXY and VXY are with ductile characteristic. The in-plane stiffness of pristine and Janus monolayer MXY are in the range between 22 and 158 N m‑1. The tunable electronic and mechanical properties of these 2D materials would advance the development of ultra-sensitive detectors, nanogenerators, low-power electronics, and energy harvesting and electromechanical systems.

Electron spin transition causing structure transformations of earth's interiors under high pressure

Science.gov (United States)

Yamanaka, T.; Kyono, A.; Kharlamova, S.; Alp, E.; Bi, W.; Mao, H.

2012-12-01

To elucidate the correlation between structure transitions and spin state is one of the crucial problems for understanding the geophysical properties of earth interiors under high pressure. High-pressure studies of iron bearing spinels attract extensive attention in order to understand strong electronic correlation such as the charge transfer, electron hopping, electron high-low spin transition, Jahn-Teller distortion and charge disproponation in the lower mantle or subduction zone [1]. Experiment Structure transitions of Fe3-xSixO4, Fe3-xTixO4 Fe3-xCrxO4 spinel solid solution have been investigated at high pressure up to 60 GPa by single crystal and powder diffraction studies using synchrotron radiation with diamond anvil cell. X-ray emission experiment (XES) at high pressure proved the spin transition of Fe-Kβ from high spin (HS) to intermediate spin state (IS) or low spin state (LS). Mössbauer experiment and Raman spectra study have been also conducted for deformation analysis of Fe site and confirmation of the configuration change of Fe atoms. Jahn-Teller effect A cubic-to-tetragonal transition under pressure was induced by Jahn-Teller effect of IVFe2+ (3d6) in the tetrahedral site of Fe2TiO4 and FeCr2O4, providing the transformation from 43m (Td) to 42m (D2d). Tetragonal phase is formed by the degeneracy of e orbital of Fe2+ ion. Their c/a ratios are c/adisordered in the M2 site. At pressures above 53 GPa, Fe2TiO4 structure further transforms to Pmma. This structure change results in the order-disorder transition [2]. New structure of Fe2SiO4 The spin transition exerts an influence to Fe2SiO4 spinel structure and triggers two distinct curves of the lattice constant in the spinel phase. The reversible structure transition from cubic to pseudo-rhombohedral phase was observed at about 45 GPa. This transition is induced by the 20% shrinkage of ionic radius of VIFe2+at the low sin state. Laser heating experiment at 1500 K has confirmed the decomposition from the

Quantum phase transitions of strongly correlated electron systems

International Nuclear Information System (INIS)

Imada, Masatoshi

1998-01-01

Interacting electrons in solids undergo various quantum phase transitions driven by quantum fluctuations. The quantum transitions take place at zero temperature by changing a parameter to control quantum fluctuations rather than thermal fluctuations. In contrast to classical phase transitions driven by thermal fluctuations, the quantum transitions have many different features where quantum dynamics introduces a source of intrinsic fluctuations tightly connected with spatial correlations and they have been a subject of recent intensive studies as we see below. Interacting electron systems cannot be fully understood without deep analyses of the quantum phase transitions themselves, because they are widely seen and play essential roles in many phenomena. Typical and important examples of the quantum phase transitions include metal-insulator transitions, (2, 3, 4, 5, 6, 7, 8, 9) metal-superconductor transitions, superconductor-insulator transitions, magnetic transitions to antiferromagnetic or ferromagnetic phases in metals as well as in Mott insulators, and charge ordering transitions. Here, we focus on three different types of transitions

Electron transfer by excited benzoquinone anions: slow rates for two-electron transitions.

Science.gov (United States)

Zamadar, Matibur; Cook, Andrew R; Lewandowska-Andralojc, Anna; Holroyd, Richard; Jiang, Yan; Bikalis, Jin; Miller, John R

2013-09-05

Electron transfer (ET) rate constants from the lowest excited state of the radical anion of benzoquinone, BQ(-•)*, were measured in THF solution. Rate constants for bimolecular electron transfer reactions typically reach the diffusion-controlled limit when the free-energy change, ΔG°, reaches -0.3 eV. The rate constants for ET from BQ(-•)* are one-to-two decades smaller at this energy and do not reach the diffusion-controlled limit until -ΔG° is 1.5-2.0 eV. The rates are so slow probably because a second electron must also undergo a transition to make use of the energy of the excited state. Similarly, ET, from solvated electrons to neutral BQ to form the lowest excited state, is slow, while fast ET is observed at a higher excited state, which can be populated in a transition involving only one electron. A simple picture based on perturbation theory can roughly account for the control of electron transfer by the need for transition of a second electron. The picture also explains how extra driving force (-ΔG°) can restore fast rates of electron transfer.

Topological Phase Transitions in Zinc-Blende Semimetals Driven Exclusively by Electronic Temperature

Science.gov (United States)

Trushin, Egor; Görling, Andreas

2018-04-01

We show that electronic phase transitions in zinc-blende semimetals with quadratic band touching (QBT) at the center of the Brillouin zone, like GaBi, InBi, or HgTe, can occur exclusively due to a change of the electronic temperature without the need to involve structural transformations or electron-phonon coupling. The commonly used Kohn-Sham density-functional methods based on local and semilocal density functionals employing the local density approximation (LDA) or generalized gradient approximations (GGAs), however, are not capable of describing such phenomena because they lack an intrinsic temperature dependence and account for temperature only via the occupation of bands, which essentially leads only to a shift of the Fermi level without changing the shape or topology of bands. Kohn-Sham methods using the exact temperature-dependent exchange potential, not to be confused with the Hartree-Fock exchange potential, on the other hand, describe such phase transitions. A simple modeling of correlation effects can be achieved by screening of the exchange. In the considered zinc-blende compounds the QBT is unstable at low temperatures and a transition to electronic states without QBT takes place. In the case of HgTe and GaBi Weyl points of type I and type II, respectively, emerge during the transitions. This demonstrates that Kohn-Sham methods can describe such topological phase transitions provided they are based on functionals more accurate than those within the LDA or GGA. Moreover, the electronic temperature is identified as a handle to tune topological materials.

Universal Quantum Criticality in the Metal-Insulator Transition of Two-Dimensional Interacting Dirac Electrons

Directory of Open Access Journals (Sweden)

Yuichi Otsuka

2016-03-01

Full Text Available The metal-insulator transition has been a subject of intense research since Mott first proposed that the metallic behavior of interacting electrons could turn to an insulating one as electron correlations increase. Here, we consider electrons with massless Dirac-like dispersion in two spatial dimensions, described by the Hubbard models on two geometrically different lattices, and perform numerically exact calculations on unprecedentedly large systems that, combined with a careful finite-size scaling analysis, allow us to explore the quantum critical behavior in the vicinity of the interaction-driven metal-insulator transition. Thereby, we find that the transition is continuous, and we determine the quantum criticality for the corresponding universality class, which is described in the continuous limit by the Gross-Neveu model, a model extensively studied in quantum field theory. Furthermore, we discuss a fluctuation-driven scenario for the metal-insulator transition in the interacting Dirac electrons: The metal-insulator transition is triggered only by the vanishing of the quasiparticle weight, not by the Dirac Fermi velocity, which instead remains finite near the transition. This important feature cannot be captured by a simple mean-field or Gutzwiller-type approximate picture but is rather consistent with the low-energy behavior of the Gross-Neveu model.

Lie-superalgebraical aspects of quantum statistics

International Nuclear Information System (INIS)

Palev, T.D.

1978-01-01

The Lie-superalgebraical properties of the ordinary quantum statistics are discussed with the aim of possible generalization in quantum theory and in theoretical physics. It is indicated that the algebra generated by n pairs of Fermi or paraFermi operators is isomorphic to the classical simple Lie algebra Bsub(n) of the SO(2n+1) orthogonal group, whereas n pairs of Bose or paraBose operators generate the simple orthosympletic superalgebra B(O,n). The transition to infinite number of creation and annihilation operators (n → infinity) does not change a superalgebraic structure. Hence, ordinary Bose and Fermi quantization can be considered as quantization over definite irreducible representations of two simple Lie superalgebras. The idea is given of how one can introduce creation and annihilation operators that satisfy the second quantization postulates and generate other simple Lie superalgebras

The RF voltage dependence of the electron sheath heating in low pressure capacitively coupled rf discharges

International Nuclear Information System (INIS)

Buddemeier, U.; Kortshagen, U.; Pukropski, I.

1995-01-01

In low pressure capacitively coupled RF discharges two competitive electron heating mechanisms have been discussed for some time now. At low pressures the stochastic sheath heating and for somewhat higher pressures the Joule heating in the bulk plasma have been proposed. When the pressure is increased at constant RF current density a transition from concave electron distribution functions (EDF) with a pronounced cold electron group to convex EDFs with a missing strong population of cold electrons is found. This transition was interpreted as the transition from dominant stochastic to dominant Joule heating. However, a different interpretation has been given by Kaganovich and Tsendin, who attributed the concave shaped EDFs to the spatially inhomogeneous RF field in combination with the nonlocality of the EDF

Semirelativistic potential model for low-lying three-gluon glueballs

International Nuclear Information System (INIS)

Mathieu, Vincent; Semay, Claude; Silvestre-Brac, Bernard

2006-01-01

The three-gluon glueball states are studied with the generalization of a semirelativistic potential model giving good results for two-gluon glueballs. The Hamiltonian depends only on 3 parameters fixed on two-gluon glueball spectra: the strong coupling constant, the string tension, and a gluon size which removes singularities in the potential. The Casimir scaling determines the structure of the confinement. Low-lying J PC states are computed and compared with recent lattice calculations. A good agreement is found for 1 -- and 3 -- states, but our model predicts a 2 -- state much higher in energy than the lattice result. The 0 -+ mass is also computed

Transition to H-mode by energetic electrons

International Nuclear Information System (INIS)

Itoh, Kimitaka; Itoh, Sanae.

1992-07-01

Effect of the electron loss due to the toroidal ripple on an H-mode transition is studied. When energetic electrons exist in tokamaks, e.g., in the case of the current drive by lower hybrid (LH) waves, the edge electric field can show the bifurcation to the more positive value. In this state, both the electron loss and ion loss (such as loss cone loss) are reduced. The criterion for the transition is derived. Comparison with H-mode in JT-60 LH plasma shows a qualitative agreement. (author)

E-H mode transition in low-pressure inductively coupled nitrogen-argon and oxygen-argon plasmas

International Nuclear Information System (INIS)

Lee, Young Wook; Lee, Hye Lan; Chung, T. H.

2011-01-01

This work investigates the characteristics of the E-H mode transition in low-pressure inductively coupled N 2 -Ar and O 2 -Ar discharges using rf-compensated Langmuir probe measurements and optical emission spectroscopy (OES). As the ICP power increases, the emission intensities from plasma species, the electron density, the electron temperature, and the plasma potential exhibit sudden changes. The Ar content in the gas mixture and total gas pressure have been varied in an attempt to fully characterize the plasma parameters. With these control parameters varying, the changes of the transition threshold power and the electron energy distribution function (EEDF) are explored. In N 2 -Ar and O 2 -Ar discharges at low-pressures of several millitorr, the transition thresholds are observed to decrease with Ar content and pressure. It is observed that in N 2 -Ar plasmas during the transition, the shape of the EEDF changes from an unusual distribution with a flat hole near the electron energy of 3 eV in the E mode to a Maxwellian distribution in the H mode. However, in O 2 -Ar plasmas, the EEDFs in the E mode at low Ar contents show roughly bi-Maxwellian distributions, while the EEDFs in the H mode are observed to be nearly Maxwellian. In the E and H modes of O 2 -Ar discharges, the dissociation fraction of O 2 molecules is estimated using optical emission actinometry. During the E-H mode transition, the dissociation fraction of molecules is also enhanced.

Transition to electronic publishing

Science.gov (United States)

Bowning, Sam

Previous communications have described some of the many changes that will occur in the next few months as AGU makes the transition to fully electronic publishing. With the advent of the new AGU electronic publishing system, manuscripts will be submitted, edited, reviewed, and published in electronic formats. This piece discusses how the electronic journals will differ from the print journals. Electronic publishing will require some adjustments to the ways we currently think about journals from our perspective of standard print versions. Visiting the Web site of AGU's Geochemistry, Geophysics, Geosystems (G-Cubed) is a great way to get familiar with the look and feel of electronic publishing. However, protocols, especially for citations of articles, are still evolving. Some of the biggest changes for users of AGU publications may be the lack of page numbers, the use of a unique identifier (DOI),and changes in citation style.

Conversion-electron experiment to characterize the decay of the 237Np shape isomer

International Nuclear Information System (INIS)

Henry, E.A.; Becker, J.A.; Bauer, R.W.; Gardner, D.G.; Decman, D.J.; Meyer, R.A.; Roy, N.; Sale, K.E.

1987-01-01

Conversion electrons from the decay of low-lying levels of 237 Np have been measured to detect the population of these levels by gamma-ray decay of the 237 Np shape isomer. Analysis of the 208-keV transition L conversion-electron peak gives an upper limit of about 17 μb for the population of the 3/2 - 267-keV level in 237 Np from the shape isomer decay. Model calculations are compared with the measured limit. Improvements are suggested for this experiment. 9 refs., 4 figs

Study on infrared multiphoton excitation of the linear triatomic molecule by the Lie-algebra approach

International Nuclear Information System (INIS)

Feng, H.; Zheng, Y.; Ding, S.

2007-01-01

Infrared multiphoton vibrational excitation of the linear triatomic molecule has been studied using the quadratic anharmonic Lie-algebra model, unitary transformations, and Magnus approximation. An explicit Lie-algebra expression for the vibrational transition probability is obtained by using a Lie-algebra approach. This explicit Lie-algebra expressions for time-evolution operator and vibrational transition probabilities make the computation clearer and easier. The infrared multiphoton vibrational excitation of the DCN linear tri-atomic molecule is discussed as an example

On the structure of graded transitive Lie algebras

NARCIS (Netherlands)

Post, Gerhard F.

2000-01-01

We study finite-dimensional Lie algebras ${\\mathfrak L}$ of polynomial vector fields in $n$ variables that contain the vector fields $\\dfrac{\\partial}{\\partial x_i} \\; (i=1,\\ldots, n)$ and $x_1\\dfrac{\\partial}{\\partial x_1}+ \\dots + x_n\\dfrac{\\partial}{\\partial x_n}$. We show that the maximal ones

Search for low-lying opposite parity states from a simple perspective

International Nuclear Information System (INIS)

Hernandez de la Pena, L.; Hess, P.O.; Levai, G.

2003-01-01

The low-lying spectrum of many light nuclei can be described reasonably well by assigning SU(3) quantum numbers to the states. When one focuses on basic properties of nuclei in a wide mass range, however, simplified models with fewer parameters (and thus with less arbitrary nature) can be useful. The agreement to available experimental data was found to be reasonable, expect when the nucleus is near a shell closure and has small deformation. (R.P.)

Extracting Low-Lying Lambda Resonances Using Correlation Matrix Techniques

International Nuclear Information System (INIS)

Menadue, Benjamin J.; Kamleh, Waseem; Leinweber, Derek B.; Mahbub, M. S.

2011-01-01

The lowest-lying negative-parity state of the Lambda is investigated in (2+1)-flavour full-QCD on the PACS-CS configurations made available through the ILDG. We show that a variational analysis using multiple source and sink smearings can extract a state lying lower than that obtained by using a standard fixed smeared source and sink operator alone.

Inelastic electron scattering at low momentum transfer

International Nuclear Information System (INIS)

Richter, A.

1979-01-01

Recent advances of high energy resolution (ΔE approx. 30 keV FWHM) inelastic electron scattering at low momentum transfer (q -1 ) using selected experimental data from the Darmstadt electron linear accelerator are discussed. Strong emphasis is given to a comparison of the data with theoretical nuclear model predictions. Of the low multipolarity electric transitions investigated, as examples only E1 transitions to unnatural parity states in 11 B and E2 transitions of the very fragmented isoscalar quadrupole giant resonance in 208 Pb are considered. In 11 B the role of the Os hole in the configuration of the 1/2 + , 3/2 + and 5/2 + states is quantitatively determined via an interference mechanism in the transition probability. By comparison of the high resolution data with RPA calculations the E2 EWSR in 208 Pb is found to be much less exhausted than anticipated from previous medium energy resolution (e,e) and hadron scattering experiments. In the case of M1 transitions it is shown that the simplest idealized independent particle shell-model prediction breaks down badly. In 28 Si, ground-state correlations influence largely the detected M1 strength and such ground-state correlations are also responsible for the occurence of a strong M1 transition to a state at Ex = 10.319 MeV in 40 Ca. In 90 Zr only about 10% of the theoretically expected M1 strength is seen in (e,e) and in 140 Ce and 208 Pb none (detection limit 1-2 μ 2 K). In the case of 208 Pb high resolution spectra exist now up to an excitation energy of Ex = approx. 12MeV. The continuous decrease of the M1 strength with mass number is corroborated by the behaviour of strong but very fragmented M2 transitions which are detected in 28 Si, 90 Zr, 140 Ce and 208 Pb concentrated at an excitation energy E x approx. 44A -1 / 3 MeV. In 90 Zr, the distribution of spacings and widths of the many Jπ = 2 states are consistent with a Wigner and Porter-Thomas distribution, respectively. (orig.) 891 KBE/orig. 892 ARA

Laser Assisted Free-Free Transition in Electron - Atom Collision

Science.gov (United States)

Sinha, C.; Bhatia, A. K.

2011-01-01

Free-free transition is studied for electron-Hydrogen atom system in ground state at very low incident energies in presence of an external homogeneous, monochromatic and linearly polarized laser field. The incident electron is considered to be dressed by the laser in a non perturbative manner by choosing the Volkov solutions in both the channels. The space part of the scattering wave function for the electron is solved numerically by taking into account the effect of electron exchange, short range as well as of the long range interactions. Laser assisted differential as well as elastic total cross sections are calculated for single photon absorption/emission in the soft photon limit, the laser intensity being much less than the atomic field intensity. A strong suppression is noted in the laser assisted cross sections as compared to the field free situations. Significant difference is noted in the singlet and the triplet cross sections.

Quasi-Lie algebras and Lie groups

International Nuclear Information System (INIS)

Momo Bangoura

2006-07-01

In this work, we define the quasi-Poisson Lie quasigroups, dual objects to the quasi-Poisson Lie groups and we establish the correspondence between the local quasi-Poisson Lie quasigoups and quasi-Lie bialgebras (up to isomorphism). (author) [fr

Hyperfine structure of six low-lying fine structure levels of 191Ir and 193Ir and the 191Δs193 hyperfine anomaly

International Nuclear Information System (INIS)

Buettgenbach, S.; Dicke, R.; Gebauer, H.; Kuhnen, R.; Traeber, F.

1978-01-01

The hyperfine interaction constants A and B of six low-lying metastable fine structure states of the two iridium isotopes 191 Ir and 193 Ir and the electronic g-factors of these levels have been measured using the atomic-beam magnetic-resonance method. From the values of the magnetic-dipole interaction constants A, corrected for off-diagonal perturbations, we extracted the hyperfine anomaly of a pure 6s-electron state: 191 Δs 193 = 0.64(7)%. Using nonrelativistic approximations for the effective radial parameters the nuclear electric-quadrupole moments were obtained: Q( 191 Ir) = 0.81(21)b, Q( 193 Ir) = 0.73(19)b (corrected for Sternheimer shielding effects). (orig.) [de

Electronic topological transitions in Zn under compression

Science.gov (United States)

Kechin, Vladimir V.

2001-01-01

The electronic structure of hcp Zn under pressure up to 10 GPa has been calculated self-consistently by means of the scalar relativistic tight-binding linear muffin-tin orbital method. The calculations show that three electronic topological transitions (ETT's) occur in Zn when the c/a axial ratio diminishes under compression. One transition occurs at c/a~=1.82 when the ``needles'' appear around the symmetry point K of the Brillouin zone. The other two transitions occur at c/a~=3, when the ``butterfly'' and ``cigar'' appear simultaneously both around the L point. It has been shown that these ETT's are responsible for a number of anomalies observed in Zn at compression.

Spectroscopic parameters, vibrational levels, transition dipole moments and transition probabilities of the 9 low-lying states of the NCl+ cation

Science.gov (United States)

Yin, Yuan; Shi, Deheng; Sun, Jinfeng; Zhu, Zunlue

2018-03-01

This work calculates the potential energy curves of 9 Λ-S and 28 Ω states of the NCl+ cation. The technique employed is the complete active space self-consistent field method, which is followed by the internally contracted multireference configuration interaction approach with the Davidson correction. The Λ-S states are X2Π, 12Σ+, 14Π, 14Σ+, 14Σ-, 24Π, 14Δ, 16Σ+, and 16Π, which are yielded from the first two dissociation channels of NCl+ cation. The Ω states are generated from these Λ-S states. The 14Π, 14Δ, 16Σ+, and 16Π states are inverted with the spin-orbit coupling effect included. The 14Σ+, 16Σ+, and 16Π states are very weakly bound, whose well depths are only several-hundred cm- 1. One avoided crossing of PECs occurs between the 12Σ+ and 22Σ+ states. To improve the quality of potential energy curves, core-valence correlation and scalar relativistic corrections are included. The potential energies are extrapolated to the complete basis set limit. The spectroscopic parameters and vibrational levels are calculated. The transition dipole moments are computed. The Franck-Condon factors, Einstein coefficients, and radiative lifetimes of many transitions are determined. The spectroscopic approaches are proposed for observing these states according to the transition probabilities. The spin-orbit coupling effect on the spectroscopic and vibrational properties is evaluated. The spectroscopic parameters, vibrational levels, transition dipole moments, as well as transition probabilities reported in this paper could be considered to be very reliable.

Theoretical study of the lowest-lying electronic states of Aluminium monoiodide

International Nuclear Information System (INIS)

Taher, F.; Kabbani, A.; Ani-El Houte, W.

2004-01-01

Full text.The spectroscopic study of Aluminium monohalides, especially the Aluminium monoiodide, is important for monitoring such species in high temperature fast-flow reactors. Theoretical calculations of AlI are not available, whereas several studies have been done for the other aluminium monohalides. In this work, CAS-SCF/MRCI calculations are performed for the lowest-lying electronic states of AlI in a range of internuclear distance between 2.30 A and 2.80 A. Ab-initio calculations have been effectuated by using the computational chemistry program Molpro. The basis set used in this study for aluminium atom is that used by Langhoff for aluminium monohalides, of contractions using atomic natural orbitals and a pseudopotential is used for iode. Accurate theoretical spectroscopic constants and potential curves are obtained for the ground state X 1 Σ + and the first excited states a 3 Π and A 1 Π. The calculated values of Te, ωe, ωexe and re of these states are compatible with the experimental results. An ordering of states is represented for the lowest five predicted singlet and lowest five predicted triplet states. These results provide a big support to determine the analogy in the ordering of the electronic states in AlF, AlBr and AlI respectively at lower energies. These theoretical results identify a set of electronic singlet and triplet states unobserved experimentally

On the gyro resonance electron-whistler interaction in transition layers of near-earth plasma

International Nuclear Information System (INIS)

Erokhin, N.S.; Zol'nikova, N.N.; Mikhajlovskaya, L.A.

1996-01-01

Gyro resonance interaction of electrons with low amplitude triggered whistler in the transition layers of the ionospheric and magnetospheric plasma that correspond to the blurred jumps of the magnetic field and plasma concentration was studied

Analytical calculation of the vibrator-rotor transition in the sdg interacting boson model

International Nuclear Information System (INIS)

Wang Baolin

1992-01-01

Analytical calculation of the vibrator-rotor transition is given by utilizing the 1/N expansion technique in the sdg IBM. The phase transition of low-lying energy spectrum and E2 transition for Sm isotopes are calculated

Observation of strongly forbidden solid effect dynamic nuclear polarization transitions via electron-electron double resonance detected NMR

Energy Technology Data Exchange (ETDEWEB)

Smith, Albert A.; Corzilius, Björn; Haze, Olesya; Swager, Timothy M.; Griffin, Robert G., E-mail: rgg@mit.edu [Department of Chemistry and Francis Bitter Magnet Laboratory, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

2013-12-07

We present electron paramagnetic resonance experiments for which solid effect dynamic nuclear polarization transitions were observed indirectly via polarization loss on the electron. This use of indirect observation allows characterization of the dynamic nuclear polarization (DNP) process close to the electron. Frequency profiles of the electron-detected solid effect obtained using trityl radical showed intense saturation of the electron at the usual solid effect condition, which involves a single electron and nucleus. However, higher order solid effect transitions involving two, three, or four nuclei were also observed with surprising intensity, although these transitions did not lead to bulk nuclear polarization—suggesting that higher order transitions are important primarily in the transfer of polarization to nuclei nearby the electron. Similar results were obtained for the SA-BDPA radical where strong electron-nuclear couplings produced splittings in the spectrum of the indirectly observed solid effect conditions. Observation of high order solid effect transitions supports recent studies of the solid effect, and suggests that a multi-spin solid effect mechanism may play a major role in polarization transfer via DNP.

Quantum theory of the electronic and optical properties of low-dimensional semiconductor systems

Science.gov (United States)

Lau, Wayne Heung

This thesis examines the electronic and optical properties of low-dimensional semiconductor systems. A theory is developed to study the electron-hole generation-recombination process of type-II semimetallic semiconductor heterojunctions based on a 3 x 3 k·p matrix Hamiltonian (three-band model) and an 8 x 8 k·p matrix Hamiltonian (eight-band model). A novel electron-hole generation and recombination process, which is called activationless generation-recombination process, is predicted. It is demonstrated that the current through the type-II semimetallic semiconductor heterojunctions is governed by the activationless electron-hole generation-recombination process at the heterointerfaces, and that the current-voltage characteristics are essentially linear. A qualitative agreement between theory and experiments is observed. The numerical results of the eight-band model are compared with those of the threeband model. Based on a lattice gas model, a theory is developed to study the influence of a random potential on the ionization equilibrium conditions for bound electron-hole pairs (excitons) in III--V semiconductor heterostructures. It is demonstrated that ionization equilibrium conditions for bound electron-hole pairs change drastically in the presence of strong disorder. It is predicted that strong disorder promotes dissociation of excitons in III--V semiconductor heterostructures. A theory of polariton (photon dressed by phonon) spontaneous emission in a III--V semiconductor doped with semiconductor quantum dots (QDs) or quantum wells (QWs) is developed. For the first time, superradiant and subradiant polariton spontaneous emission phenomena in a polariton-QD (QW) coupled system are predicted when the resonance energies of the two identical QDs (QWs) lie outside the polaritonic energy gap. It is also predicted that when the resonance energies of the two identical QDs (QWs) lie inside the polaritonic energy gap, spontaneous emission of polariton in the polariton

A collective model description of the low lying and giant dipole resonant properties of 40424446Ca

International Nuclear Information System (INIS)

Weise, J.I.

1982-01-01

The low-lying and giant dipole resonant properties of the even-even calcium isotopes are calculated within the framework of the Gneuss-Greiner model and compared with the experimental data. In the low energy region, comparison is also made with the predictions of a coexistence model

Study of the radioactive disintegration of /sup 187/Au existence of E0 transitions in /sup 187/Pt?

CERN Document Server

Braham, A B; Bourgeois, C; Desthuilliers-Porquet, M G; Höglund, A; Huck, A; Kilcher, P; Knipper, A; Letessier, J; Serre, Claude; Schuck, C

1979-01-01

The decay /sup 187/Au to /sup 187/Pt has been studied using on-line mass-separated sources produced at ISOCELE (ORSAY) and ISOLDE (CERN). Lifetime measurements are performed with a Gerholm spectrometer and precise conversion electron determination with a 180 degrees spectrograph. A decay scheme is proposed. Low-lying low-spin states in /sup 187/Pt are discussed. Special attention is given to four highly converted transitions (260.3, 262.5, 498.2 and 498.8 keV) which are tentatively considered to have large E0 components. (41 refs).

Low-lying 1/2- hidden strange pentaquark states in the constituent quark model

Science.gov (United States)

Li, Hui; Wu, Zong-Xiu; An, Chun-Sheng; Chen, Hong

2017-12-01

We investigate the spectrum of the low-lying 1/2- hidden strange pentaquark states, employing the constituent quark model, and looking at two ways within that model of mediating the hyperfine interaction between quarks - Goldstone boson exchange and one gluon exchange. Numerical results show that the lowest 1/2- hidden strange pentaquark state in the Goldstone boson exchange model lies at ˜1570 MeV, so this pentaquark configuration may form a notable component in S 11(1535) if the Goldstone boson exchange model is applied. This is consistent with the prediction that S 11(1535) couples very strongly to strangeness channels. Supported by National Natural Science Foundation of China (11675131, 11645002), Chongqing Natural Science Foundation (cstc2015jcyjA00032) and Fundamental Research Funds for the Central Universities (SWU115020)

Calculated and experimental low-loss electron energy loss spectra of dislocations in diamond and GaN

CERN Document Server

Jones, R; Gutiérrez-Sosa, A; Bangert, U; Heggie, M I; Blumenau, A T; Frauenheim, T; Briddon, P R

2002-01-01

First-principles calculations of electron energy loss (EEL) spectra for bulk GaN and diamond are compared with experimental spectra acquired with a scanning tunnelling electron microscope offering ultra-high-energy resolution in low-loss energy spectroscopy. The theoretical bulk low-loss EEL spectra, in the E sub g to 10 eV range, are in good agreement with experimental data. Spatially resolved spectra from dislocated regions in both materials are distinct from bulk spectra. The main effects are, however, confined to energy losses lying above the band edge. The calculated spectra for low-energy dislocations in diamond are consistent with the experimental observations, but difficulties remain in understanding the spectra of threading dislocations in GaN.

Combination of activity and lying/standing data for detection of oestrus in cows

DEFF Research Database (Denmark)

Jónsson, Ragnar Ingi; Blanke, Mogens; Poulsen, Niels Kjølstad

2009-01-01

is measured by a sensor attached to the hind leg of the cow. Activity and lying/standing behaviour are modelled as a discrete event system, constructed using automata theory. In an attempt to estimate a biologically relevant lying balance, a lying balance indicator is constructed and is influencing transition...

Electronic transitions and intermolecular forces

International Nuclear Information System (INIS)

Hemert, M.C. van.

1981-01-01

This thesis describes two different subjects - electronic transitions and intermolecular forces - that are related mainly by the following observation: The wavenumber at which an electronic transition in an atom or molecule occurs, depends on the environment of that atom or molecule. This implies, for instance, that when a molecule becomes solvated its absorption spectrum may be shifted either to the blue or to the red side of the original gasphase spectrum. In part I attention is paid to the experimental aspects of VUV spectroscopy, both in the gasphase and in the condensed phase. In part II a series of papers are presented, dealing with the calculation of intermolecular forces (and some related topics) both for the ground state and for the excited state interactions, using different non-empirical methods. The calculations provide, among other results, a semiquantitative interpretation of the spectral blue shifts encountered in our experiments. (Auth.)

Lifetimes of low-lying states in 132Nd and 134Nd

International Nuclear Information System (INIS)

Kruecken, R.; Mullins, S.M.; Thornley, D.J.; Kirwan, A.J.; Nolan, P.J.; Regan, P.H.; Wadsworth, R.

1995-01-01

Lifetimes of low-lying states have been measured in 132 Nd and 134 Nd using the coincidence-plunger technique. The reaction 32 S+ 105 Pd was used at a bombarding energy of 152 MeV. The measurement has been performed at the NSF Daresbury using the ESSA 30 array. The differential decay-curve method (DDCM) was used to analyze the recoil-distance Doppler-shift (RDDS) data. The experimental B(E2) values in 132 Nd are well described by the predictions of the rotational model and the IBM in the O(6) limit. ((orig.))

Accurate potential energy curves, spectroscopic parameters, transition dipole moments, and transition probabilities of 21 low-lying states of the CO+ cation

Science.gov (United States)

Xing, Wei; Shi, Deheng; Zhang, Jicai; Sun, Jinfeng; Zhu, Zunlue

2018-05-01

This paper calculates the potential energy curves of 21 Λ-S and 42 Ω states, which arise from the first two dissociation asymptotes of the CO+ cation. The calculations are conducted using the complete active space self-consistent field method, which is followed by the valence internally contracted multireference configuration interaction approach with the Davidson correction. To improve the reliability and accuracy of the potential energy curves, core-valence correlation and scalar relativistic corrections, as well as the extrapolation of potential energies to the complete basis set limit are taken into account. The spectroscopic parameters and vibrational levels are determined. The spin-orbit coupling effect on the spectroscopic parameters and vibrational levels is evaluated. To better study the transition probabilities, the transition dipole moments are computed. The Franck-Condon factors and Einstein coefficients of some emissions are calculated. The radiative lifetimes are determined for a number of vibrational levels of several states. The transitions between different Λ-S states are evaluated. Spectroscopic routines for observing these states are proposed. The spectroscopic parameters, vibrational levels, transition dipole moments, and transition probabilities reported in this paper can be considered to be very reliable and can be used as guidelines for detecting these states in an appropriate spectroscopy experiment, especially for the states that were very difficult to observe or were not detected in previous experiments.

To the theory of spin-charge separation in one-dimensional correlated electron systems

International Nuclear Information System (INIS)

Zvyagin, A.A.

2004-01-01

Spin-charge separation is considered to be one of the key properties that distinguish low-dimensional electron systems from others. Three-dimensional correlated electron systems are described by the Fermi liquid theory. There, low-energy excitations (quasiparticles) are reminiscent of noninteracting electrons: They carry charges -e and spins 1/2 . It is believed that for any one-dimensional correlated electron system, low-lying electron excitations carry either only spin and no charge, or only charge without spin. That is why recent experiments looked for such low-lying collective electron excitations, one of which carries only spin, and the other carries only charge. Here we show that despite the fact that for exactly solvable one-dimensional correlated electron models there exist excitations which carry only spin and only charge, in all these models with short-range interactions the low-energy physics is described by low-lying collective excitations, one of which carries both spin and charge

Electronic specific heat of transition metal carbides

International Nuclear Information System (INIS)

Conte, R.

1964-07-01

The experimental results that make it possible to define the band structure of transition metal carbides having an NaCI structure are still very few. We have measured the electronic specific heat of some of these carbides of varying electronic concentration (TiC, either stoichiometric or non-stoichiometric, TaC and mixed (Ti, Ta) - C). We give the main characteristics (metallography, resistivity, X-rays) of our samples and we describe the low temperature specific heat apparatus which has been built. In one of these we use helium as the exchange gas. The other is set up with a mechanical contact. The two use a germanium probe for thermometer. The measurement of the temperature using this probe is described, as well as the various measurement devices. The results are presented in the form of a rigid band model and show that the density of the states at the Fermi level has a minimum in the neighbourhood of the group IV carbides. (author) [fr

Application of the Moessbauer effect to the study of the structure of transition metal complexes; Applications de l'effet Mossbauer a l'etude de la structure des complexes des metaux de transition

Energy Technology Data Exchange (ETDEWEB)

Tsymbal, C [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

1968-07-01

In this survey, the structural investigations of transition metal complexes by the hyperfine interactions in the Moessbauer effect are described. The isomer shift provides a unique tool for estimating s electrons covalency in high spin complexes and one of the best pieces of evidence for the importance of bacle donation in low spin complexes. The electric field gradient deriving from quadrupole coupling measurements is correlated with the energy levels distribution of d orbitals in high spin complexes, whereas in low spin complexes it originates from the unbalanced d electrons. (authors) [French] Dans cette etude, nous decrivons les applications des interactions hyperfines dans l' effet Mossbauer a l'etude de la structure des complexes des metaux de transition. Le deplacement isomerique donne des informations tres utiles sur la covalence des electrons s dans les complexes a spin eleve et met en evidence d'une maniere nette l'importance du phenomene de 'bacle donation' dans les complexes a spin faible. Le gradient de champ electrique qui provient des mesures d'interaction quadripolaire est lie a la distribution des niveaux d'energie des orbitales d dans les complexes a spin eleve alors que dans les complexes a spin faible, il est provoque par des electrons d non apparies. (auteurs)

Structure and bonding of ScCN and ScNC: Ground and low-lying states

International Nuclear Information System (INIS)

Kalemos, Apostolos; Metropoulos, Aristophanes; Mavridis, Aristides

2012-01-01

Graphical abstract: The experimentally unknown systems ScCN and ScNC have been studied through single reference CISD and CCSD(T) methods. A total of 20 = 10 (ScCN) + 10 (ScNC) states were examined. All states are quite ionic whereas ScNC(X ∼3 Δ) is stabler than ScCN(X ∼3 Δ) by ∼5 kcal/mol. Display Omitted Highlights: ► We have studied through ab initio methods the polytopic system Sc[CN]. ► A series of low lying states for both isomeric forms have been examined. ► Around equilibrium the system displays a pronounced Sc + [CN] − ionic character. - Abstract: We have studied the experimentally unknown Sc[CN] molecular system in both its isomeric forms, scandium cyanide (ScCN) and isocyanide (ScNC), through ab initio computations. We report energetics, geometries, harmonic frequencies, and dipole moments for the first 20 Sc[CN] states correlating diabatically to Sc + ( 3 D, 1 D, 3 F) + CN − (X 1 Σ + ). Both isomers have a pronounced ionic character around equilibrium due to the high electron affinity of the CN group and the low ionization energy of the Sc atom. According to our calculations the ScNC isomer (X ∼3 Δ) is stabler than the ScCN(X ∼3 Δ) by ∼5 kcal/mol.

Velocity fields and transition densities in nuclear collective modes

Energy Technology Data Exchange (ETDEWEB)

Stringari, S [Dipartimento di Matematica e Fisica, Libera Universita di Trento, Italy

1979-08-13

The shape of the deformations occurring in nuclear collective modes is investigated by means of a microscopic approach. Analytical solutions of the equations of motion are obtained by using simplified nuclear potentials. It is found that the structure of the velocity field and of the transition density of low-lying modes is considerably different from the predictions of irrotational hydrodynamic models. The low-lying octupole state is studied in particular detail by using the Skyrme force.

Boson forbidden transitions and their manifestation in spherical nuclei

International Nuclear Information System (INIS)

Stoyanov, Ch.

2002-01-01

For the correct description of the 'boson forbidden' transitions it is necessary to go beyond the quasi-boson approximation and to take into account the fermion structure of the phonons. Once it done it is quantitative description of the transitions is possible within the simplest model based on the separable residual interactions. Calculations of the forbidden E1-transitions in 120 Sn, 144 Sm and 144 Nd are presented. Analysis of some low-energy M1-transitions is made using IBM-2. The discussed examples reveal the complex properties of the low-lying excited states

Influence of axial and peripheral ligands on the electronic structure of titanium phthalocyanines

DEFF Research Database (Denmark)

Pickup, David F.; García Lastra, Juan Maria; Rogero, Celia

2013-01-01

core-level binding energy was observed in the bidentate complex and compared to a calculated core-level stabilization. DFT predicts a change of the LUMO from the inner phthalocyanine ring to the Ti dxy orbital and a reversal of the high-lying dx2-y2 and d z2 orbitals. The N 1s edge was calculated using......-ray absorption spectroscopy and photoelectron spectroscopy were combined with density functional theory (DFT) and crystal-field multiplet calculations to characterize the Ti 3d and N 2p valence electrons that form the frontier orbitals. When a monodentate oxo axial ligand was replaced by a bidentate catechol...... ligand, the multiplet structure of the Ti 2p-to-3d transitions was found to change systematically. The most noticeable change was an additional transition into the low-lying 3dxy level, which is attributed to a reduction in local symmetry from 4-fold to 2-fold at the Ti center. An increase of the Ti 2p...

Understanding electron magnetic circular dichroism in a transition potential approach

Science.gov (United States)

Barthel, J.; Mayer, J.; Rusz, J.; Ho, P.-L.; Zhong, X. Y.; Lentzen, M.; Dunin-Borkowski, R. E.; Urban, K. W.; Brown, H. G.; Findlay, S. D.; Allen, L. J.

2018-04-01

This paper introduces an approach based on transition potentials for inelastic scattering to understand the underlying physics of electron magnetic circular dichroism (EMCD). The transition potentials are sufficiently localized to permit atomic-scale EMCD. Two-beam and three-beam systematic row cases are discussed in detail in terms of transition potentials for conventional transmission electron microscopy, and the basic symmetries which arise in the three-beam case are confirmed experimentally. Atomic-scale EMCD in scanning transmission electron microscopy (STEM), using both a standard STEM probe and vortex beams, is discussed.

Classification and identification of Lie algebras

CERN Document Server

Snobl, Libor

2014-01-01

The purpose of this book is to serve as a tool for researchers and practitioners who apply Lie algebras and Lie groups to solve problems arising in science and engineering. The authors address the problem of expressing a Lie algebra obtained in some arbitrary basis in a more suitable basis in which all essential features of the Lie algebra are directly visible. This includes algorithms accomplishing decomposition into a direct sum, identification of the radical and the Levi decomposition, and the computation of the nilradical and of the Casimir invariants. Examples are given for each algorithm. For low-dimensional Lie algebras this makes it possible to identify the given Lie algebra completely. The authors provide a representative list of all Lie algebras of dimension less or equal to 6 together with their important properties, including their Casimir invariants. The list is ordered in a way to make identification easy, using only basis independent properties of the Lie algebras. They also describe certain cl...

Electron spin relaxation in a transition-metal dichalcogenide quantum dot

Science.gov (United States)

Pearce, Alexander J.; Burkard, Guido

2017-06-01

We study the relaxation of a single electron spin in a circular quantum dot in a transition-metal dichalcogenide monolayer defined by electrostatic gating. Transition-metal dichalcogenides provide an interesting and promising arena for quantum dot nano-structures due to the combination of a band gap, spin-valley physics and strong spin-orbit coupling. First we will discuss which bound state solutions in different B-field regimes can be used as the basis for qubits states. We find that at low B-fields combined spin-valley Kramers qubits to be suitable, while at large magnetic fields pure spin or valley qubits can be envisioned. Then we present a discussion of the relaxation of a single electron spin mediated by electron-phonon interaction via various different relaxation channels. In the low B-field regime we consider the spin-valley Kramers qubits and include impurity mediated valley mixing which will arise in disordered quantum dots. Rashba spin-orbit admixture mechanisms allow for relaxation by in-plane phonons either via the deformation potential or by piezoelectric coupling, additionally direct spin-phonon mechanisms involving out-of-plane phonons give rise to relaxation. We find that the relaxation rates scale as \\propto B 6 for both in-plane phonons coupling via deformation potential and the piezoelectric effect, while relaxation due to the direct spin-phonon coupling scales independant to B-field to lowest order but depends strongly on device mechanical tension. We will also discuss the relaxation mechanisms for pure spin or valley qubits formed in the large B-field regime.

Electron-vibrational transitions under molecular ions collisions with slow electrons

International Nuclear Information System (INIS)

Andreev, E.A.

1993-01-01

A concept of a multichannel quantum defect is considered and basic theoretic ratios of inelastic collisional processes with the participation of molecular positive ions and slow electrons playing an important role both in atmospheric and laboratory plasma, are presented. The problem of scattering channel number limitation with the provision of S-matrix unique character is considered. Different models of electron rotation-vibrational connection under collision of two-atom molecular ions with slow electrons are analysed. Taking N 2 + as an example, a high efficiency of transitions between different electron states of a molecular ion is shown. 73 refs., 9 figs., 1 tab

Novel Solution for Low-Lying Land Areas Safe from Natural Hazards—Toward Reconstruction of Lost Coastal Areas in Northeast Japan

Directory of Open Access Journals (Sweden)

Toshio Nakajima

2015-07-01

Full Text Available The imminent fear of water-related hazards such as flooding hangs over low-lying areas, in particular now because climate changes have led to increased hazards, like storm surges, that could result in serious harm. This paper aims to provide a novel solution—namely “the floating platform”—that can transform dangerous low-lying areas into those safeguarded against potential hazards. Additionally, by utilizing this solution as a secure base for society to build atop this new artificial reservoir, we offer a better future role for such areas. Meanwhile, we propose adoption of our concept soon at two low-lying areas in northeast Japan hard-hit by the huge 11 March 2011 tsunami: Sendai’s Arahama coastal district and the still-devastated residential harbor area of Kesennuma, both cities in need of a fresh perspective.

Low-temperature thermal transport and thermopower of monolayer transition metal dichalcogenide semiconductors

Science.gov (United States)

Sengupta, Parijat; Tan, Yaohua; Klimeck, Gerhard; Shi, Junxia

2017-10-01

We study the low temperature thermal conductivity of single-layer transition metal dichalcogenides (TMDCs). In the low temperature regime where heat is carried primarily through transport of electrons, thermal conductivity is linked to electrical conductivity through the Wiedemann-Franz law (WFL). Using a k.p Hamiltonian that describes the K and K{\\prime} valley edges, we compute the zero-frequency electric (Drude) conductivity using the Kubo formula to obtain a numerical estimate for the thermal conductivity. The impurity scattering determined transit time of electrons which enters the Drude expression is evaluated within the self-consistent Born approximation. The analytic expressions derived show that low temperature thermal conductivity (1) is determined by the band gap at the valley edges in monolayer TMDCs and (2) in presence of disorder which can give rise to the variable range hopping regime, there is a distinct reduction. Additionally, we compute the Mott thermopower and demonstrate that under a high frequency light beam, a valley-resolved thermopower can be obtained. A closing summary reviews the implications of results followed by a brief discussion on applicability of the WFL and its breakdown in context of the presented calculations.

All-electron ab initio investigations of the electronic states of the NiC molecule

DEFF Research Database (Denmark)

Shim, Irene; Gingerich, Karl. A.

1999-01-01

The low-lying electronic states of NiC are investigated by all-electron ab initio multi-configuration self-consistent-field (CASSCF) calculations including relativistic corrections. The electronic structure of NiC is interpreted as perturbed antiferromagnetic couplings of the localized angular...

Growth and electronic structure of single-layered transition metal dichalcogenides

DEFF Research Database (Denmark)

Dendzik, Maciej

2016-01-01

only a weak interaction between SL MoS2 and graphene, which leads to a quasi-freestanding band structure, but also to the coexistence of multiple rotational domains. Measurements of SL WS2 on Ag(111), on the other hand, reveals formation of interesting in-gap states which make WS2 metallic. Low...... different from graphene’s. For example, semiconducting TMDCs undergo an indirectdirect band gap transition when thinned to a single layer (SL); this results in greatly enhanced photoluminescence, making those materials attractive for applications in optoelectronics. Furthermore, metallic TMDCs can host......-quality SL TMDCs. We demonstrate the synthesis of SL MoS2, WS2 and TaS2 on Au(111), Ag(111) and graphene on SiC. The morphology and crystal structure of the synthesized materials is characterized by scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED). The electronic structure of SL...

Lie groups and Lie algebras for physicists

CERN Document Server

Das, Ashok

2015-01-01

The book is intended for graduate students of theoretical physics (with a background in quantum mechanics) as well as researchers interested in applications of Lie group theory and Lie algebras in physics. The emphasis is on the inter-relations of representation theories of Lie groups and the corresponding Lie algebras.

Sheath structure transition controlled by secondary electron emission

Science.gov (United States)

Schweigert, I. V.; Langendorf, S. J.; Walker, M. L. R.; Keidar, M.

2015-04-01

In particle-in-cell Monte Carlo collision (PIC MCC) simulations and in an experiment we study sheath formation over an emissive floating Al2O3 plate in a direct current discharge plasma at argon gas pressure 10-4 Torr. The discharge glow is maintained by the beam electrons emitted from a negatively biased hot cathode. We observe three types of sheaths near the floating emissive plate and the transition between them is driven by changing the negative bias. The Debye sheath appears at lower voltages, when secondary electron emission is negligible. With increasing applied voltage, secondary electron emission switches on and a first transition to a new sheath type, beam electron emission (BEE), takes place. For the first time we find this specific regime of sheath operation near the floating emissive surface. In this regime, the potential drop over the plate sheath is about four times larger than the temperature of plasma electrons. The virtual cathode appears near the emissive plate and its modification helps to maintain the BEE regime within some voltage range. Further increase of the applied voltage U initiates the second smooth transition to the plasma electron emission sheath regime and the ratio Δφs/Te tends to unity with increasing U. The oscillatory behavior of the emissive sheath is analyzed in PIC MCC simulations. A plasmoid of slow electrons is formed near the plate and transported to the bulk plasma periodically with a frequency of about 25 kHz.

Instantaneous nonvertical electronic transitions with shaped femtosecond laser pulses: Is it possible?

DEFF Research Database (Denmark)

Henriksen, Niels Engholm; Møller, Klaus Braagaard

2003-01-01

In molecular electronic transitions, a vertical transition can be induced by an ultrashort laser pulse. That is, a replica of the initial nuclear state-times the transition dipole moment of the electronic transition-can be created instantaneously (on the time scale of nuclear motion) in the excited...

Electric Monopole Transition Strengths in 62Ni

Directory of Open Access Journals (Sweden)

Evitts L. J.

2016-01-01

Full Text Available Excited states in 62Ni were populated with a (p, p’ reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0, were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77−34+23 × 10−3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0 value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0 values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0 value for the 22+ to 21+ transition.

Electric Monopole Transition Strengths in 62Ni

Science.gov (United States)

Evitts, L. J.; Garnsworthy, A. B.; Kibédi, T.; Moukaddam, M.; Alshahrani, B.; Eriksen, T. K.; Holt, J. D.; Hota, S. S.; Lane, G. J.; Lee, B. Q.; McCormick, B. P.; Palalani, N.; Reed, M. W.; Stroberg, S. R.; Stuchbery, A. E.

2016-09-01

Excited states in 62Ni were populated with a (p, p') reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0), were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77-34+23 × 10-3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0) value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0) values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0) value for the 22+ to 21+ transition.

Low-lying qq(qq)-bar states in a relativistic model based on the Bethe-Salpeter equation

International Nuclear Information System (INIS)

Ram, B.; Kriss, V.

1985-01-01

Low-lying qq(qq)-bar states are analysed in a previously given relativistic model based on the Bethe-Salpeter equation. It is not got M-diquonia, P-mesonia, or meson molecules, but it is got T-diquonia

Dynamical mean-field theory and path integral renormalisation group calculations of strongly correlated electronic states

Energy Technology Data Exchange (ETDEWEB)

Heilmann, D.B.

2007-02-15

The two-plane HUBBARD model, which is a model for some electronic properties of undoped YBCO superconductors as well as displays a MOTT metal-to-insulator transition and a metal-to-band insulator transition, is studied within Dynamical Mean-Field Theory using HIRSCH-FYE Monte Carlo. In order to find the different transitions and distinguish the types of insulator, we calculate the single-particle spectral densities, the self-energies and the optical conductivities. We conclude that there is a continuous transition from MOTT to band insulator. In the second part, ground state properties of a diagonally disordered HUBBARD model is studied using a generalisation of Path Integral Renormalisation Group, a variational method which can also determine low-lying excitations. In particular, the distribution of antiferromagnetic properties is investigated. We conclude that antiferromagnetism breaks down in a percolation-type transition at a critical disorder, which is not changed appreciably by the inclusion of correlation effects, when compared to earlier studies. Electronic and excitation properties at the system sizes considered turn out to primarily depend on the geometry. (orig.)

Dynamical mean-field theory and path integral renormalisation group calculations of strongly correlated electronic states

International Nuclear Information System (INIS)

Heilmann, D.B.

2007-02-01

The two-plane HUBBARD model, which is a model for some electronic properties of undoped YBCO superconductors as well as displays a MOTT metal-to-insulator transition and a metal-to-band insulator transition, is studied within Dynamical Mean-Field Theory using HIRSCH-FYE Monte Carlo. In order to find the different transitions and distinguish the types of insulator, we calculate the single-particle spectral densities, the self-energies and the optical conductivities. We conclude that there is a continuous transition from MOTT to band insulator. In the second part, ground state properties of a diagonally disordered HUBBARD model is studied using a generalisation of Path Integral Renormalisation Group, a variational method which can also determine low-lying excitations. In particular, the distribution of antiferromagnetic properties is investigated. We conclude that antiferromagnetism breaks down in a percolation-type transition at a critical disorder, which is not changed appreciably by the inclusion of correlation effects, when compared to earlier studies. Electronic and excitation properties at the system sizes considered turn out to primarily depend on the geometry. (orig.)

All electron ab initio investigations of the electronic states of the FeC molecule

DEFF Research Database (Denmark)

Shim, Irene; Gingerich, Karl A.

1999-01-01

The low lying electronic states of the molecule FeC have been investigated by performing all electron ab initio multi-configuration self-consistent-field (CASSCF) and multi reference configuration interaction (MRCI) calculations. The relativistic corrections for the one electron Darwin contact term...

All Electron ab initio Investigations of the Electronic States of the MoN Molecule

DEFF Research Database (Denmark)

Shim, Irene; Gingerich, Karl A.

1999-01-01

The low lying electronic states of the molecule MoN have been investigated by performing all electron ab initio multi-configuration self-consistent-field (CASSCF) calculations. The relativistic corrections for the one electron Darwin contact term and the relativistic mass-velocity correction have...

Low-energy electron scattering from pyrimidine: Similarities and differences with benzene

Science.gov (United States)

Jones, D. B.; Bellm, S. M.; Limão-Vieira, P.; Brunger, M. J.

2012-05-01

Differential cross sections for low-energy electron-impact excitation of the unresolved combinations of 23B2 + 21A1 and 31A1 + 21B2 electronic states of pyrimidine are reported. Comparisons are made with recent differential cross section measurements for the electron-impact excitation of the 1E1u and unresolved 1B1u + 3E2g electronic states of benzene [H. Kato, M. Hoshino, H. Tanaka, P. Limão-Vieira, O. Ingolfsson, L. Campbell, M.J. Brunger, J. Chem. Phys. 134 (2011) 134308.], in order to evaluate the nature of electron impact π-π∗ transitions in aromatic species.

Ferromagnetic semiconductor-metal transition in heterostructures of europium monoxide

Energy Technology Data Exchange (ETDEWEB)

Stollenwerk, Tobias; Kroha, Johann [Physikalisches Institut der Universitaet Bonn (Germany)

2012-07-01

Experiments on thin films of electron doped europium monoxide show a simultaneous ferromagnetic semiconductor-metal transition which goes along with a huge drop in resistivity over several orders of magnitude. Therefore, this material is a very promising candidate for spintronics applications. We have developed a theory which correctly predicts the simultaneous phase transition in thin films of electron doped EuO and the increase of the Curie temperature T{sub C} with doping concentration. The origin of the increased T{sub C} lies in the enhanced RKKY interaction between the localized 4f moments of the Eu atoms. Therefore, the phase transition is controlled by the population of the conduction band. We investigate the influence of film thickness and interface effects on the population of the conduction band and on the magnetic and electronic properties of the EuO film.

Microscopic study of low-lying yrast spectra and deformation systematics of even-even barium isotopes

International Nuclear Information System (INIS)

Sarswat, S.P.; Bharti, Arun; Khosa, S.K.

1996-01-01

The yrast spectra has been obtained in the variation-after-projection framework using pairing-plus-quadrupole- quadrupole model for the two body interaction. Besides the low-lying yrast spectra, the calculated values of intrinsic quadrupole moments of some of the barium isotopes i.e. 124-134 Ba are presented

Identification of dynamical Lie algebras for finite-level quantum control systems

Energy Technology Data Exchange (ETDEWEB)

Schirmer, S.G.; Pullen, I.C.H.; Solomon, A.I. [Quantum Processes Group and Department of Applied Maths, Open University, Milton Keynes (United Kingdom)]. E-mails: S.G.Schirmer@open.ac.uk; I.C.H.Pullen@open.ac.uk; A.I.Solomon@open.ac.uk

2002-03-08

The problem of identifying the dynamical Lie algebras of finite-level quantum systems subject to external control is considered, with special emphasis on systems that are not completely controllable. In particular, it is shown that the dynamical Lie algebra for an N-level system with symmetrically coupled transitions, such as a system with equally spaced energy levels and uniform transition dipole moments, is a subalgebra of so(N) if N=2l+1, and a subalgebra of sp(l) if N=2l. General criteria for obtaining either so(2l+1) or sp(l) are established. (author)

Characteristics of the Mott transition and electronic states of high-temperature cuprate superconductors from the perspective of the Hubbard model

Science.gov (United States)

Kohno, Masanori

2018-04-01

A fundamental issue of the Mott transition is how electrons behaving as single particles carrying spin and charge in a metal change into those exhibiting separated spin and charge excitations (low-energy spin excitation and high-energy charge excitation) in a Mott insulator. This issue has attracted considerable attention particularly in relation to high-temperature cuprate superconductors, which exhibit electronic states near the Mott transition that are difficult to explain in conventional pictures. Here, from a new viewpoint of the Mott transition based on analyses of the Hubbard model, we review anomalous features observed in high-temperature cuprate superconductors near the Mott transition.

Intra- and inter-atomic optical transitions of Fe, Co, and Ni ferrocyanides studied using first-principles many-electron calculations

Energy Technology Data Exchange (ETDEWEB)

Watanabe, Shinta, E-mail: s-watanabe@nucl.nagoya-u.ac.jp, E-mail: j-onoe@nucl.nagoya-u.ac.jp; Sawada, Yuki; Nakaya, Masato; Yoshino, Masahito; Nagasaki, Takanori; Onoe, Jun, E-mail: s-watanabe@nucl.nagoya-u.ac.jp, E-mail: j-onoe@nucl.nagoya-u.ac.jp [Department of Materials, Physics and Energy Engineering, Graduated School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603 (Japan); Kameyama, Tatsuya; Torimoto, Tsukasa [Department of Crystalline Materials Science, Graduated School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603 (Japan); Inaba, Yusuke; Takahashi, Hideharu; Takeshita, Kenji [Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, 2-12-1-N1-16 O-okayama, Meguro-ku, Tokyo 152-8550 (Japan)

2016-06-21

We have investigated the electronic structures and optical properties of Fe, Co, and Ni ferrocyanide nanoparticles using first-principles relativistic many-electron calculations. The overall features of the theoretical absorption spectra for Fe, Ni, and Co ferrocyanides calculated using a first-principles many-electron method well reproduced the experimental one. The origins of the experimental absorption spectra were clarified by performing a configuration analysis based on the many-electron wave functions. For Fe ferrocyanide, the experimental absorption peaks originated from not only the charge-transfer transitions from Fe{sup 2+} to Fe{sup 3+} but also the 3d-3d intra-transitions of Fe{sup 3+} ions. In addition, the spin crossover transition of Fe{sup 3+} predicted by the many-electron calculations was about 0.24 eV. For Co ferrocyanide, the experimental absorption peaks were mainly attributed to the 3d-3d intra-transitions of Fe{sup 2+} ions. In contrast to the Fe and Co ferrocyanides, Ni ferrocyanide showed that the absorption peaks originated from the 3d-3d intra-transitions of Ni{sup 3+} ions in a low-energy region, while from both the 3d-3d intra-transitions of Fe{sup 2+} ions and the charge-transfer transitions from Fe{sup 2+} to Ni{sup 3+} in a high-energy region. These results were quite different from those of density-functional theory (DFT) calculations. The discrepancy between the results of DFT calculations and those of many-electron calculations suggested that the intra- and inter-atomic transitions of transition metal ions are significantly affected by the many-body effects of strongly correlated 3d electrons.

Communication: Electronic flux induced by crossing the transition state

Science.gov (United States)

Jia, Dongming; Manz, Jörn; Yang, Yonggang

2018-01-01

We present a new effect of chemical reactions, e.g., isomerizations, that occurs when the reactants pass along the transition state, on the way to products. It is based on the well-known fact that at the transition state, the electronic structure of one isomer changes to the other. We discover that this switch of electronic structure causes a strong electronic flux that is well distinguishable from the usual flux of electrons that travel with the nuclei. As a simple but clear example, the effect is demonstrated here for bond length isomerization of Na2 (21Σu+), with adiabatic crossing the barrier between the inner and outer wells of the double minimum potential that support different "Rydberg" and "ionic" type electronic structures, respectively.

Low-energy electron transmission and secondary-electron emission experiments on crystalline and molten long-chain alkanes

International Nuclear Information System (INIS)

Ueno, N.; Sugita, K.; Seki, K.; Inokuchi, H.

1986-01-01

This paper describes the results of low-energy electron transmission and secondary-electron emission experiments on thin films of long-chain alkanes deposited on metal substrates. The spectral changes due to crystal-melt phase transition were measured in situ in both experiments. The ground-state energy V 0 of the quasifree electron in crystalline state was determined to be 0.5 +- 0.1 eV. The value of V 0 for the molten state was found to be negative. Further, in the crystalline state evidence is found for a direct correspondence between the transmission maxima and the high value of the density of states in the conduction bands

Electronic transitions of fluorene, dibenzofuran, carbazole, and dibenzothiophene

DEFF Research Database (Denmark)

Nguyen, Duy Duc; Trunk, John; Nakhimovsky, Lina

2010-01-01

A comparative study of the electronic transitions of fluorene and its hetero-analogues dibenzofuran, carbazole, and dibenzothiophene was performed in a wide energy range. Gas phase, crystal phase, and linear dichroism electronic transmittance spectra were measured with synchrotron radiation...

Comparison of a low- to high-confinement transition theory with experimental data from DIII-D.

Science.gov (United States)

Guzdar, P N; Kleva, R G; Groebner, R J; Gohil, P

2002-12-23

From our recent theory based on the generation of shear flow and field in finite beta plasmas, the criterion for bifurcation from low to high confinement mode yields a critical parameter proportional to T(e)/square root (L(n)), where T(e) is the electron temperature and L(n) is the density scale length. The predicted threshold shows very good agreement with edge measurements on discharges undergoing low-to-high transitions in DIII-D. The observed differences in the transitions with the reversal of the toroidal magnetic field are reconciled in terms of this critical parameter. The theory also provides an explanation for pellet injection H modes in DIII-D, thereby unifying unconnected methods for accomplishing the transition.

Effective Hamiltonian and low-lying eigenenergy clustering patterns of four-sublattice antiferromagnets

DEFF Research Database (Denmark)

Zhang, N.G.; Henley, C.L.; Rischel, C.

2002-01-01

We study the low-lying eigenenergy clustering patterns of quantum antiferromagnets with p sublattices (in particular p = 4). We treat each sublattice as a large spin, and using second-order degenerate perturbation theory, we derive the effective (biquadratic) Hamiltonian coupling the p large spins....... In order to compare with exact diagonalizations, the Hamiltonian is explicitly written for a finite-size lattice, and it contains information on energies of excited states as well as the ground state. The result is applied to the face-centered-cubic Type-I antiferromagnet of spin 1/2, including second...

Electronic spectra from TDDFT and machine learning in chemical space

International Nuclear Information System (INIS)

Ramakrishnan, Raghunathan; Hartmann, Mia; Tapavicza, Enrico; Lilienfeld, O. Anatole von

2015-01-01

Due to its favorable computational efficiency, time-dependent (TD) density functional theory (DFT) enables the prediction of electronic spectra in a high-throughput manner across chemical space. Its predictions, however, can be quite inaccurate. We resolve this issue with machine learning models trained on deviations of reference second-order approximate coupled-cluster (CC2) singles and doubles spectra from TDDFT counterparts, or even from DFT gap. We applied this approach to low-lying singlet-singlet vertical electronic spectra of over 20 000 synthetically feasible small organic molecules with up to eight CONF atoms. The prediction errors decay monotonously as a function of training set size. For a training set of 10 000 molecules, CC2 excitation energies can be reproduced to within ±0.1 eV for the remaining molecules. Analysis of our spectral database via chromophore counting suggests that even higher accuracies can be achieved. Based on the evidence collected, we discuss open challenges associated with data-driven modeling of high-lying spectra and transition intensities

Electronic spectra from TDDFT and machine learning in chemical space

Energy Technology Data Exchange (ETDEWEB)

Ramakrishnan, Raghunathan [Institute of Physical Chemistry and National Center for Computational Design and Discovery of Novel Materials, Department of Chemistry, University of Basel, Klingelbergstrasse 80, CH-4056 Basel (Switzerland); Hartmann, Mia; Tapavicza, Enrico, E-mail: Enrico.Tapavicza@csulb.edu [Department of Chemistry and Biochemistry, California State University, 1250 Bellflower Boulevard, Long Beach, California 90840 (United States); Lilienfeld, O. Anatole von, E-mail: anatole.vonlilienfeld@unibas.ch [Institute of Physical Chemistry and National Center for Computational Design and Discovery of Novel Materials, Department of Chemistry, University of Basel, Klingelbergstrasse 80, CH-4056 Basel (Switzerland); Argonne Leadership Computing Facility, Argonne National Laboratory, 9700 S. Cass Avenue, Lemont, Illinois 60439 (United States)

2015-08-28

Due to its favorable computational efficiency, time-dependent (TD) density functional theory (DFT) enables the prediction of electronic spectra in a high-throughput manner across chemical space. Its predictions, however, can be quite inaccurate. We resolve this issue with machine learning models trained on deviations of reference second-order approximate coupled-cluster (CC2) singles and doubles spectra from TDDFT counterparts, or even from DFT gap. We applied this approach to low-lying singlet-singlet vertical electronic spectra of over 20 000 synthetically feasible small organic molecules with up to eight CONF atoms. The prediction errors decay monotonously as a function of training set size. For a training set of 10 000 molecules, CC2 excitation energies can be reproduced to within ±0.1 eV for the remaining molecules. Analysis of our spectral database via chromophore counting suggests that even higher accuracies can be achieved. Based on the evidence collected, we discuss open challenges associated with data-driven modeling of high-lying spectra and transition intensities.

Study of the β{sup -} decay of {sup 116m1}In: A new interpretation of low-lying 0{sup +} states in {sup 116}Sn

Energy Technology Data Exchange (ETDEWEB)

Pore, J.L.; Cross, D.S.; Andreoiu, C.; Ashley, R.; Chester, A.S.; Noakes, B.; Starosta, K.; Voss, P.J. [Simon Fraser University, Department of Chemistry, Burnaby BC (Canada); Ball, G.C.; Bender, P.C.; Garnsworthy, A.B.; Hackman, G.; Rajabali, M.M. [TRIUMF, Vancouver BC (Canada); Diaz Varela, A.; Demand, G.A.; Dunlop, R.; Garrett, P.E.; Hadinia, B.; Jigmeddorj, B.; Laffoley, A.T.; Liblong, A.; Svensson, C.E. [University of Guelph, Department of Physics, Guelph ON (Canada); Kanungo, R. [Saint Mary' s University, Department of Astronomy and Physics, Halifax NS (Canada); Petrache, C.M. [Universite Paris-Saclay, CSNSM, CNRS-IN2P3, Orsay Cedex (France); Wang, Z.M. [Simon Fraser University, Department of Chemistry, Burnaby BC (Canada); TRIUMF, Vancouver BC (Canada); Wood, J.L. [Georgia Institute of Technology, School of Physics, Atlanta, GA (United States); Yates, S.W. [University of Kentucky, Departments of Chemistry and Physics and Astronomy, Lexington, KY (United States)

2017-02-15

The {sup 116}Sn nucleus contains a collective rotational band originating from proton π 2p-2h excitations across the proton Z = 50 shell gap. Even though this nucleus has been extensively investigated in the past, there was still missing information on the low-energy interband transitions connecting the intruder and normal structures. The low-lying structure of {sup 116}Sn was investigated through a high-statistics study of the β{sup -} decay of {sup 116m1}In with the 8π spectrometer and its ancillary detectors at TRIUMF. These measurements are critical in order to properly characterize the π 2p-2h rotational band. Weak γ-decay branches are observed utilizing γ-γ coincidence spectroscopy methods, leading to the first direct observation of the 85 keV 2{sub 2}{sup +} → 0{sub 3}{sup +} γ ray with a transition strength of B(E2) = 99.7(84) W.u. The analysis of these results strongly suggests that the 2027 keV 0{sub 3}{sup +} state should replace the previously assigned 1757 keV 0{sub 2}{sup +} state as the band-head of the π 2p-2h rotational band. (orig.)

On Deformations and Contractions of Lie Algebras

Directory of Open Access Journals (Sweden)

Marc de Montigny

2006-05-01

Full Text Available In this contributed presentation, we discuss and compare the mutually opposite procedures of deformations and contractions of Lie algebras. We suggest that with appropriate combinations of both procedures one may construct new Lie algebras. We first discuss low-dimensional Lie algebras and illustrate thereby that whereas for every contraction there exists a reverse deformation, the converse is not true in general. Also we note that some Lie algebras belonging to parameterized families are singled out by the irreversibility of deformations and contractions. After reminding that global deformations of the Witt, Virasoro, and affine Kac-Moody algebras allow one to retrieve Lie algebras of Krichever-Novikov type, we contract the latter to find new infinite dimensional Lie algebras.

Optical transition probabilities in electron-vibration-rotation spectra of diatomic molecules

International Nuclear Information System (INIS)

Kuznetsova, L.A.; Kuz'menko, N.E.; Kuzyakov, Yu.Ya.; Plastinin, Yu.A.

1974-01-01

The present review systematizes the data on the absolute probabilities of electron transitions in diatomic molecules, which have been published since the beginning of 1961 and up to the end of 1973, and those on the relative transition probabilities, which have been published since the beginning of 1966 till the end of 1973. The review discussed the theoretical relationships underlying the experimental techniques of determining the absolute transition probabilities. Modifications of the techniques under discussion are not specially examined; the details of interest can be found, however, in the references cited. The factual material-, such as the values of the absolute probabilities of electron transitions, the dependences of the electron transition moments on the internuclear distance and the values of the Franck-Condon factors,- is presented in tables 1, 2 and 4, respectively, embracing all the relevant works known to the present authors. Along with a complete systematization of the transition probability data, the authors have attempted a critical analysis of the available data in order to select the most reliable results. The recommended values of the squared matrix elements of the electron transition dipole moments are given in table 3. The last chaper of the work compares the results of calculations of the Franck-Condon factors obtained with the different milecular potentials [ru

Electronic and thermodynamic properties of transition metal elements and compounds

International Nuclear Information System (INIS)

Haeglund, J.

1993-01-01

This thesis focuses on the use of band-structure calculations for studying thermodynamic properties of solids. We discuss 3d-, 4d- and 5d-transition metal carbides and nitrides. Through a detailed comparison between theoretical and experimental results, we draw conclusions on the character of the atomic bonds in these materials. We show how electronic structure calculations can be used to give accurate predictions for bonding energies. Part of the thesis is devoted to the application of the generalized gradient approximation in electronic structure calculations on transition metals. For structures with vibrational disorder, we present a method for calculating averaged phonon frequencies without using empirical information. For magnetic excitations, we show how a combined use of theoretical results and experimental data can yield information on magnetic fluctuations at high temperatures. The main results in the thesis are: Apart for an almost constant shift, theoretically calculated bonding energies for transition metal carbides and nitrides agree with experimental data or with values from analysis of thermochemical information. The electronic spectrum of transition metal carbides and nitrides can be separated into bonding, antibonding and nonbonding electronic states. The lowest enthalpy of formation for substoichiometric vanadium carbide VC 1-X at zero temperature and pressure occurs for a structure containing vacancies (x not equal to 0). The generalized gradient approximation improves theoretical calculated cohesive energies for 3d-transition metals. Magnetic phase transitions are sensitive to the description of exchange-correlation effects in electronic structure calculations. Trends in Debye temperatures can be successfully analysed in electronic structure calculations on disordered lattices. For the elements, there is a clear dependence on the crystal structure (e.g., bcc, fcc or hcp). Chromium has fluctuating local magnetic moments at temperatures well above

Lifetime measurements in transitional nuclei by fast electronic scintillation timing

Science.gov (United States)

Caprio, M. A.; Zamfir, N. V.; Casten, R. F.; Amro, H.; Barton, C. J.; Beausang, C. W.; Cooper, J. R.; Gürdal, G.; Hecht, A. A.; Hutter, C.; Krücken, R.; McCutchan, E. A.; Meyer, D. A.; Novak, J. R.; Pietralla, N.; Ressler, J. J.; Berant, Z.; Brenner, D. S.; Gill, R. L.; Regan, P. H.

2002-10-01

A new generation of experiments studying nuclei in spherical-deformed transition regions has been motivated by the introduction of innovative theoretical approaches to the treatment of these nuclei. The important structural signatures in the transition regions, beyond the basic yrast level properties, involve γ-ray transitions between low-spin, non-yrast levels, and so information on γ-ray branching ratios and absolute matrix elements (or level lifetimes) for these transitions is crucial. A fast electronic scintillation timing (FEST) system [H. Mach, R. L. Gill, and M. Moszyński, Nucl. Instrum. Methods A 280, 49 (1989)], making use of BaF2 and plastic scintillation detectors, has been implemented at the Yale Moving Tape Collector for the measurement of lifetimes of states populated in β^ decay. Experiments in the A100 (Pd, Ru) and A150 (Dy, Yb) regions have been carried out, and a few examples will be presented. Supported by the US DOE under grants and contracts DE-FG02-91ER-40609, DE-FG02-88ER-40417, and DE-AC02-98CH10886 and by the German DFG under grant Pi 393/1.

Ab initio calculation on the low-lying excited states of Si2+ cation including spin–orbit coupling

International Nuclear Information System (INIS)

Liu, Yanlei; Zhai, Hongsheng; Zhang, Xiaomei; Liu, Yufang

2013-01-01

Highlights: • 24 Λ–S states are correlated to the dissociation limit of Si( 3 P g ) + Si + ( 2 P u ) are first reported. • The dissociation energies of the calculated electronic states are predicted in our work. • It is first time that the entire 54 Ω states generated from the 24 Λ–S states have been studied. • PECs of Λ–S and Ω states are depicted with the aid of avoided crossing rule between the same symmetry. - Abstract: Ab initio all-electron relativistic calculations of the low-lying excited states of Si 2 + have been performed at MRCI+Q/AVQZ level. The calculated electronic states, including 12 doublet and 12 quartet Λ–S states, are correlated to the dissociation limit of Si( 3 P g ) + Si + ( 2 P u ). Spin–orbit interaction is taken into account via the state interaction approach with the full Breit-Pauli Hamiltonian, which causes the entire 24 Λ–S states to split into 54 Ω states. This is the first time that spin–orbit coupling (SOC) calculation has been performed on Si 2 + . The obtained potential energy curves (PECs) of Λ–S and Ω states are respectively depicted with the aid of the avoided crossing rule between the same symmetry. The spectroscopic constants of the bound Λ–S and Ω states are determined, and excellent agreements with the latest theoretical results are achieved

Electron scattering by nuclei and transition charge densities

International Nuclear Information System (INIS)

Gul'karov, I.S.

1988-01-01

Transition charge densities for states of electric type, for nuclei with A≤40--50 as obtained from data on inelastic electron scattering, are studied. The formalism of electroexcitation of nuclei is considered, together with various models (macroscopic and microscopic) used to calculate form factors, transition charge densities, and the moments of these densities: B(Eλ) and R/sub λ/ . The macroscopic models are derived microscopically, and it is shown that the model-independent sum rules lead to the same transition densities as calculations based on various hydrodynamic models. The sum rules with and without allowance for the Skyrme exchange interaction are discussed. The results of the calculations are compared with the experimental form factors of electron scattering by nuclei from 12 C to 48 Ca with excitation in them of normal-parity states with I/sup π/ = 0 + , 1 - , 2 + , 3 - , 4 + , 5 - and T = 0. The model-independent transition charge densities for the weakly collectivized excitations differ strongly from the model-dependent densities. The influence of neutrons on the transition charge densities of the nuclear isotopes 16 /sup ,/ 18 O, 32 /sup ,/ 34 S, and 40 /sup ,/ 48 Ca is considered

High-Resolution Measurements of Low-Energy Conversion Electrons

CERN Multimedia

Gizon, A; Putaux, J

2002-01-01

Measurements of low-energy internal conversion electrons have been performed with high energy resolution in some N = 105 odd and odd-odd nuclei using a semi-circular spectrograph associated to a specific tape transport system. These experiments aimed to answer the following questions~: \\begin{itemize} \\item Do M3 isomeric transitions exist in $^{183}$Pt and $^{181}$Os, isotones of $^{184}$Au~? \\item Are the neutron configurations proposed to describe the isomeric and ground states of $^{184}$Au right or wrong~? \\item Does it exist an isomeric state in $^{182}$Ir, isotone of $^{181}$Os, $^{183}$Pt and $^{184}$Au~? \\item What are the spin and parity values of the excited states of $^{182}$Ir~? \\end{itemize} In $^{183}$Pt, the 35.0 keV M3 isomeric transition has been clearly observed and the reduced transition probability has been determined. The deduced hindrance factor is close to that observed in the neighbouring odd-odd $^{184}$Au nucleus. This confirms the neutron configurations previously proposed for the ...

Lie Quasi-Bialgebras and Cohomology of Lie algebra

International Nuclear Information System (INIS)

Bangoura, Momo

2010-05-01

Lie quasi-bialgebras are natural generalisations of Lie bialgebras introduced by Drinfeld. To any Lie quasi-bialgebra structure of finite-dimensional (G, μ, γ, φ), corresponds one Lie algebra structure on D = G + G*, called the double of the given Lie quasi-bialgebra. We show that there exist on ΛG, the exterior algebra of G, a D-module structure and we establish an isomorphism of D-modules between ΛD and End(ΛG), D acting on ΛD by the adjoint action. (author) [fr

Seniority four admixures in the low-lying 0+ states of even-mass tin and lead nuclei

International Nuclear Information System (INIS)

Quesne, C.; Salmon, Y.; Spitz, S.

1977-01-01

New statistical measures of symmetry breaking are used to evaluate the total seniority four admixtures in the low-lying 0 + states of even-mass tin and lead nuclei. This approach is based on the centroid energies and partial widths of fixed total seniority and parity spectral distributions. Some seniority four states are found to be surprisingly low. However, the ground state is always a very pure seniority zero state

Meta-orbital transition in heavy-fermion systems. Analysis by dynamical mean field theory and self-consistent renormalization theory of orbital fluctuations

International Nuclear Information System (INIS)

Hattori, Kazumasa

2010-01-01

We investigate a two-orbital Anderson lattice model with Ising orbital intersite exchange interactions on the basis of a dynamical mean field theory combined with the static mean field approximation of intersite orbital interactions. Focusing on Ce-based heavy-fermion compounds, we examine the orbital crossover between two orbital states, when the total f-electron number per site n f is ∼1. We show that a 'meta-orbital' transition, at which the occupancy of two orbitals changes steeply, occurs when the hybridization between the ground-state f-electron orbital and conduction electrons is smaller than that between the excited f-electron orbital and conduction electrons at low pressures. Near the meta-orbital critical end point, orbital fluctuations are enhanced and couple with charge fluctuations. A critical theory of meta-orbital fluctuations is also developed by applying the self-consistent renormalization theory of itinerant electron magnetism to orbital fluctuations. The critical end point, first-order transition, and crossover are described within Gaussian approximations of orbital fluctuations. We discuss the relevance of our results to CeAl 2 , CeCu 2 Si 2 , CeCu 2 Ge 2 , and related compounds, which all have low-lying crystalline-electric-field excited states. (author)

Imaging ultrafast excited state pathways in transition metal complexes by X-ray transient absorption and scattering using X-ray free electron laser source

DEFF Research Database (Denmark)

Chen, Lin X; Shelby, Megan L; Lestrange, Patrick J

2016-01-01

This report will describe our recent studies of transition metal complex structural dynamics on the fs and ps time scales using an X-ray free electron laser source, Linac Coherent Light Source (LCLS). Ultrafast XANES spectra at the Ni K-edge of nickel(ii) tetramesitylporphyrin (NiTMP) were measured...... on the low-energy shoulder of the edge, which is aided by the computation of X-ray transitions for postulated excited electronic states. The observed and computed inner shell to valence orbital transition energies demonstrate and quantify the influence of the electronic configuration on specific metal...

Compatible Lie Bialgebras

International Nuclear Information System (INIS)

Wu Ming-Zhong; Bai Cheng-Ming

2015-01-01

A compatible Lie algebra is a pair of Lie algebras such that any linear combination of the two Lie brackets is a Lie bracket. We construct a bialgebra theory of compatible Lie algebras as an analogue of a Lie bialgebra. They can also be regarded as a “compatible version” of Lie bialgebras, that is, a pair of Lie bialgebras such that any linear combination of the two Lie bialgebras is still a Lie bialgebra. Many properties of compatible Lie bialgebras as the “compatible version” of the corresponding properties of Lie bialgebras are presented. In particular, there is a coboundary compatible Lie bialgebra theory with a construction from the classical Yang–Baxter equation in compatible Lie algebras as a combination of two classical Yang–Baxter equations in Lie algebras. Furthermore, a notion of compatible pre-Lie algebra is introduced with an interpretation of its close relation with the classical Yang–Baxter equation in compatible Lie algebras which leads to a construction of the solutions of the latter. As a byproduct, the compatible Lie bialgebras fit into the framework to construct non-constant solutions of the classical Yang–Baxter equation given by Golubchik and Sokolov. (paper)

Lie groups, lie algebras, and representations an elementary introduction

CERN Document Server

Hall, Brian

2015-01-01

This textbook treats Lie groups, Lie algebras and their representations in an elementary but fully rigorous fashion requiring minimal prerequisites. In particular, the theory of matrix Lie groups and their Lie algebras is developed using only linear algebra, and more motivation and intuition for proofs is provided than in most classic texts on the subject. In addition to its accessible treatment of the basic theory of Lie groups and Lie algebras, the book is also noteworthy for including: a treatment of the Baker–Campbell–Hausdorff formula and its use in place of the Frobenius theorem to establish deeper results about the relationship between Lie groups and Lie algebras motivation for the machinery of roots, weights and the Weyl group via a concrete and detailed exposition of the representation theory of sl(3;C) an unconventional definition of semisimplicity that allows for a rapid development of the structure theory of semisimple Lie algebras a self-contained construction of the representations of compac...

Experimental efforts at NIST towards one-electron ions in circular Rydberg states

International Nuclear Information System (INIS)

Tan, Joseph N; Guise, Nicholas D; Brewer, Samuel M

2011-01-01

Experimental effort is underway at NIST to enable tests of theory with one-electron ions synthesized in circular Rydberg states from captured bare nuclei. Problematic effects that limit the accuracy of predicted energy levels for low-lying states are vanishingly small for high-angular-momentum (high-L) states; in particular, the nuclear size correction for high-L states is completely negligible for any foreseeable improvement of measurement precision. As an initial step towards realizing such states, highly charged ions are extracted from the NIST electron beam ion trap (EBIT) and steered through the electrodes of a Penning trap. The goal is to capture bare nuclei in the Penning trap for experiments to make one-electron atoms in circular Rydberg states with dipole (E1) transitions in the optical domain accessible to a frequency comb.

High current density ion beam obtained by a transition to a highly focused state in extremely low-energy region

Energy Technology Data Exchange (ETDEWEB)

Hirano, Y., E-mail: y.hirano@aist.go.jp, E-mail: hirano.yoichi@phys.cst.nihon-u.ac.jp [Innovative Plasma Processing Group, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8568 (Japan); College of Science and Technologies, Nihon University, Chiyodaku, Tokyo 101-0897 (Japan); Kiyama, S.; Koguchi, H. [Innovative Plasma Processing Group, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8568 (Japan); Fujiwara, Y.; Sakakita, H. [Innovative Plasma Processing Group, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8568 (Japan); Department of Engineering Mechanics and Energy, University of Tsukuba, Ibaraki 305-8577 (Japan)

2015-11-15

A high current density (≈3 mA/cm{sup 2}) hydrogen ion beam source operating in an extremely low-energy region (E{sub ib} ≈ 150–200 eV) has been realized by using a transition to a highly focused state, where the beam is extracted from the ion source chamber through three concave electrodes with nominal focal lengths of ≈350 mm. The transition occurs when the beam energy exceeds a threshold value between 145 and 170 eV. Low-level hysteresis is observed in the transition when E{sub ib} is being reduced. The radial profiles of the ion beam current density and the low temperature ion current density can be obtained separately using a Faraday cup with a grid in front. The measured profiles confirm that more than a half of the extracted beam ions reaches the target plate with a good focusing profile with a full width at half maximum of ≈3 cm. Estimation of the particle balances in beam ions, the slow ions, and the electrons indicates the possibility that the secondary electron emission from the target plate and electron impact ionization of hydrogen may play roles as particle sources in this extremely low-energy beam after the compensation of beam ion space charge.

Low-energy electron emitters for targeted radiotherapy of small tumours

International Nuclear Information System (INIS)

Bernhardt, Peter; Forssell-Aronsson, Eva; Jacobsson, Lars; Skarnemark, Gunnar

2001-01-01

The possibility of using electron emitters to cure a cancer with metastatic spread depends on the energy of the emitted electrons. Electrons with high energy will give a high, absorbed dose to large tumours, but the absorbed dose to small tumours or single tumour cells will be low, because the range of the electrons is too long. The fraction of energy absorbed within the tumour decreases with increasing electron energy and decreasing tumour size. For tumours smaller than 1 g, the tumour-to-normal-tissue mean absorbed dose-rate ratio, TND, will be low, e.g. for 131 I and 90 Y, because of the high energy of the emitted electrons. For radiotherapy of small tumours, radionuclides emitting charged particles with short ranges (a few m u m ) are required. A mathematical model was constructed to evaluate the relation between TND and electron energy, photon-to-electron energy ratio, p/e, and tumour size. Criteria for the selection of suitable radionuclides for the treatment of small tumours were defined based on the results of the TND model. In addition, the possibility of producing such radionuclides and their physical and chemical properties were evaluated. Based on the mathematical model, the energy of the emitted electrons should be = 40 keV for small tumours ( 58m Co, 103m Rh, 119 Sb, 161 Ho, and 189m Os. All of these nuclides by internal transition or electron capture, which yields conversion and Auger electrons, and it should be possible to produce most of them in therapeutic amounts. The five low-energy electron-emitting radionuclides identified may be relevant in the radiation treatment of small tumours, especially if bound to internalizing radiopharmaceuticals

Interplay of structural transition and superconductivity in cuprates

International Nuclear Information System (INIS)

Ghosh, Haranath; Mitra, Manidipa; Behera, S.N.; Ghatak, S.K.

1997-01-01

The presence of lattice distortion is known to suppress the superconducting (SC) transition in the cuprates. It is now accepted that electron correlation plays a dominant role in shaping the properties of these undoped and doped systems. Furthermore, since the Fermi level in these systems lies in a degenerate band of Cu : d and O : p orbitals the structural transition can be modeled as a band Jahn-Teller effect. We study the coexistence of superconductivity and band Jahn-Teller (J-T) distortion, taking into account the electron correlation within the slave boson formalism. It is shown that with increasing dopant concentration (δ), the structural transition temperature (T s ) remains constant up to a certain value and then vanishes, while the SC transition temperature (T c ) increases to a maximum value. The highest value of T c corresponds to that value of δ where T s vanishes. Besides with increasing lattice distortion superconductivity is suppressed. These findings are in qualitative agreement with the experimental results. (author)

Strongly Coupled Magnetic and Electronic Transitions in Multivalent Strontium Cobaltites.

Science.gov (United States)

Lee, J H; Choi, Woo Seok; Jeen, H; Lee, H-J; Seo, J H; Nam, J; Yeom, M S; Lee, H N

2017-11-22

The topotactic phase transition in SrCoO x (x = 2.5-3.0) makes it possible to reversibly transit between the two distinct phases, i.e. the brownmillerite SrCoO 2.5 that is a room-temperature antiferromagnetic insulator (AFM-I) and the perovskite SrCoO 3 that is a ferromagnetic metal (FM-M), owing to their multiple valence states. For the intermediate x values, the two distinct phases are expected to strongly compete with each other. With oxidation of SrCoO 2.5 , however, it has been conjectured that the magnetic transition is decoupled to the electronic phase transition, i.e., the AFM-to-FM transition occurs before the insulator-to-metal transition (IMT), which is still controversial. Here, we bridge the gap between the two-phase transitions by density-functional theory calculations combined with optical spectroscopy. We confirm that the IMT actually occurs concomitantly with the FM transition near the oxygen content x = 2.75. Strong charge-spin coupling drives the concurrent IMT and AFM-to-FM transition, which fosters the near room-T magnetic transition characteristic. Ultimately, our study demonstrates that SrCoO x is an intriguingly rare candidate for inducing coupled magnetic and electronic transition via fast and reversible redox reactions.

Nuclear structure and order-to-chaos transition

International Nuclear Information System (INIS)

Solov'ev, V.G.

1995-01-01

A general scheme of the nuclear many-body problem is presented. Different models for description of low-lying states and giant resonances are discussed. The wave functions of the low-lying states have a single dominating one-quasiparticle or quasiparticle O+ phonon or one-phonon component. They demonstrate the regularity in nuclei. Giant resonances are determined by strongly fragmented one-phonon components of the wave functions. The wave functions at higher excitation energies have two-, three-and many-phonon components. Based on the statement that there is order in the large and chaos in the small components of the nuclear wave functions, the order-to-chaos transition is treated as a transition from the large to the small components of the wave functions. A quasiparticle-phonon interaction is responsible for the fragmentation of one- and many-quasiparticle and phonon states and for the mixing of closely spaced states. Therefore, experimental investigation of the fragmentation of many-quasiparticle and phonon states plays a decisive role. 30 refs

Low-lying eigenmodes of the Wilson-Dirac operator and correlations with topological objects

International Nuclear Information System (INIS)

Kusterer, Daniel-Jens; Hedditch, John; Kamleh, Waseem; Leinweber, D.B.; Williams, Anthony G.

2002-01-01

The probability density of low-lying eigenvectors of the hermitian Wilson-Dirac operator H(κ)=γ 5 D W (κ) is examined. Comparisons in position and size between eigenvectors, topological charge and action density are made. We do this for standard Monte-Carlo generated SU(3) background fields and for single instanton background fields. Both hot and cooled SU(3) background fields are considered. An instanton model is fitted to eigenmodes and topological charge density and the sizes and positions of these are compared

Seniority structure of the cranked shell model wave function and the pairing phase transition

International Nuclear Information System (INIS)

Wu, C.S.; Zeng, J.Y.; Center of Theoretical Physics, China Center of Advanced Science and Technology

1989-01-01

The accurate solutions to the low-lying eigenstates of the cranked shell model Hamiltonian are obtained by the particle-number-conserving treatment, in which a many-particle configuration truncation is adopted instead of the conventional single-particle level truncation. The variation of the seniority structures of low-lying eigenstates with rotational frequency ω is analyzed. The gap parameter of the yrast band decreases with ω very slowly, though the seniority structure has undergone a great change. It is suggested to use the seniority structure to indicate the possible pairing phase transition from a superconducting state to a normal state. The important blocking effects on the low-lying eigenstates are discussed

Electron correlation influenced magnetic phase transitions in f-electron systems

International Nuclear Information System (INIS)

Frauenheim, T.; Ropke, G.

1980-01-01

The temperature-induced phase transition (on lowering the temperature) antiferromagnet-ferromagnet in the heavy rare earth and some of actinide compounds is qualitatively explained in the scope of a two-band Hubbard model and the more complex RKKY model as the result of electron correlation effects in the conduction bands. (orig.)

Ab initio CASSCF study of the electronic structure of the transition-metal alkylidene-like complexes Mo-M[prime]H[sub 2] (M[prime] = C, Si, Ge, and Sn)

Energy Technology Data Exchange (ETDEWEB)

Marquez, A.; Sanz, J.F. (Universidad de Sevilla (Spain))

1992-12-02

Experimental and theoretical research on the electronic and geometric structure of transition-metal-carbenes and -alkylidenes is an active area in chemistry nowadays due to their potential activity in catalysis and in organic and organometallic synthesis. A theoretical investigation of the electronic structure of the high-valent, transition-metal, alkylidene-like complexes MoM[prime]H[sub 2] (M[prime] = C, Si, Ge, and Sn) is reported. Based on ab initio calculations carried out at the complete active space multiconfiguration self-consistent field (CASSCF) level, the molecular structure of the ground state and some low-lying excited states have been determined. For M[prime] = C, Si, and Ge, the ground state has C[sub 2v] symmetry (state [sup 5]B[sub 1]) and corresponds to pairing each electron of the M[prime]H[sub 2] triplet [sup 3]B[sub 1] with an electron of Mo ([sup 7]S). In the case of MoSnH[sub 2], the lowest state is bent (C[sub s] symmetry, state [sup 7]A[prime]), the out-of-plane angle being 68[degrees], and dissociates into SnH[sub 2] ([sup 1]A[sub 1]) + Mo ([sup 7]S). Dissociation energies, potential energy profiles for the dissociation, harmonic force constants in terms of internal symmetry coordinates, and vibrational frequencies are reported. The comparison of these properties with those of their pentacarbonylated homologous (CO)[sub 5]M[double bond]M[prime]H[sub 2] shows that the carbene-like (Fischer) type of complexation is stronger than the alkylidene-like one (Schrock). 28 refs., 4 figs., 6 tabs.

Treatment of Electronic Energy Level Transition and Ionization Following the Particle-Based Chemistry Model

Science.gov (United States)

Liechty, Derek S.; Lewis, Mark

2010-01-01

A new method of treating electronic energy level transitions as well as linking ionization to electronic energy levels is proposed following the particle-based chemistry model of Bird. Although the use of electronic energy levels and ionization reactions in DSMC are not new ideas, the current method of selecting what level to transition to, how to reproduce transition rates, and the linking of the electronic energy levels to ionization are, to the author s knowledge, novel concepts. The resulting equilibrium temperatures are shown to remain constant, and the electronic energy level distributions are shown to reproduce the Boltzmann distribution. The electronic energy level transition rates and ionization rates due to electron impacts are shown to reproduce theoretical and measured rates. The rates due to heavy particle impacts, while not as favorable as the electron impact rates, compare favorably to values from the literature. Thus, these new extensions to the particle-based chemistry model of Bird provide an accurate method for predicting electronic energy level transition and ionization rates in gases.

Efficient photocarrier injection in a transition metal oxide heterostructure

CERN Document Server

Muraoka, Y; Ueda, Y; Hiroi, Z

2002-01-01

An efficient method for doping a transition metal oxide (TMO) with hole carriers is presented: photocarrier injection (PCI) in an oxide heterostructure. It is shown that an insulating vanadium dioxide (VO sub 2) film is rendered metallic under light irradiation by PCI from an n-type titanium dioxide (TiO sub 2) substrate doped with Nb. Consequently, a large photoconductivity, which is exceptional for TMOs, is found in the VO sub 2 /TiO sub 2 :Nb heterostructure. We propose an electronic band structure where photoinduced holes created in TiO sub 2 :Nb can be transferred into the filled V 3d band via the low-lying O 2p band of VO sub 2. (letter to the editor)

Relaxation dynamics following transition of solvated electrons

International Nuclear Information System (INIS)

Barnett, R.B.; Landman, U.; Nitzan, A.

1989-01-01

Relaxation dynamics following an electronic transition of an excess solvated electron in clusters and in bulk water is studied using an adiabatic simulation method. In this method the solvent evolves classically and the electron is constrained to a specified state. The coupling between the solvent and the excess electron is evaluated via the quantum expectation value of the electron--water molecule interaction potential. The relaxation following excitation (or deexcitation) is characterized by two time scales: (i) a very fast (/similar to/20--30 fs) one associated with molecular rotations in the first solvation shell about the electron, and (ii) a slower stage (/similar to/200 fs), which is of the order of the longitudinal dielectric relaxation time. The fast relaxation stage exhibits an isotope effect. The spectroscopical consequences of the relaxation dynamics are discussed

Lie algebras

CERN Document Server

Jacobson, Nathan

1979-01-01

Lie group theory, developed by M. Sophus Lie in the 19th century, ranks among the more important developments in modern mathematics. Lie algebras comprise a significant part of Lie group theory and are being actively studied today. This book, by Professor Nathan Jacobson of Yale, is the definitive treatment of the subject and can be used as a textbook for graduate courses.Chapter I introduces basic concepts that are necessary for an understanding of structure theory, while the following three chapters present the theory itself: solvable and nilpotent Lie algebras, Carlan's criterion and its

Free-Free Transitions of e-H System Inside a Dense Plasma Irradiated by a Laser Field at Very Low Incident Electron Energies

Science.gov (United States)

Bhatia, A. K.; Sinha, C.

2012-01-01

The free-free transition is studied for an electron-hydrogen in the ground state at low incident energies in the presence of an external homogenous, monochromatic, and linearly polarized laser-field inside a hot dense plasma.The effect of plasma screening is considered in the Debye-Huckel approximation. The calculations are performed in the soft photon limit, assuming that the plasma frequency is much higher than the laser frequency. The incident electron is considered to be dressed by the laser field in a nonperturbative manner by choosing the Volkov solutions in both the initial and final channels. The space part of the scattering wave function for the electron is solved numerically by taking into account the electron exchange. The laser-assisted differential and total cross sections are calculated for single-photon absorption /emission and no photon exchange in the soft photon limit, the laser intensity being much less than the atomic field intensity. The calculations have been carried out for various values of Debye parameter, ranging from 0.005 to 0.12. A strong suppression is noted in the laser-assisted cross sections as compared to the field-free situation. A significant difference is noted for the singlet and triplet cross sections. The suppression is much more in the triplet states.

Free-Free Transitions of the e-H System Inside a Dense Plasma Irradiated by a Laser Field at Very Low Incident-Electron Energies

Science.gov (United States)

Bhatia, A. K.; Sinha, C.

2012-01-01

The free-free transition is studied for an electron-hydrogen atom in ground state when a low-energy electron (external) is injected into hydrogenic plasma in the presence of an external homogenous, monochromatic, and linearly polarized laser field. The effect of plasma screening is considered in the Debye-Huckel approximation. The calculations are performed in the soft photon limit. The incident electron is considered to be dressed by the laser field in a nonperturbative manner by choosing the Volkov solutions in both the initial and final channels. The space part of the scattering wave function for the electron is solved numerically by taking into account the electron exchange. The laser-assisted differential and total cross sections are calculated for single-photon absorption or emission and no-photon exchange in the soft photon limit, the laser intensity being much less than the atomic field intensity. The calculations have been carried out for various values of Debye parameter, ranging from 0.005 to 0.12. A strong suppression is noted in the laser-assisted cross sections as compared to the field-free situation. A significant difference is noted for the singlet and triplet cross sections. The suppression is much more in the triplet states.

Is there a low-lying 1{sup −} state in {sup 10}He?

Energy Technology Data Exchange (ETDEWEB)

Chulkov, L.V. [GSI Helmholtzzentrum für Schwerionenforschung GmbH/ExtreMe Matter Institute, EMMI, D-64291 Darmstadt (Germany); Kurchatov Institute, RU-123182 Moscow (Russian Federation); Aumann, T. [Institut für Kernphysik, Technische Universität, D-64289 Darmstadt (Germany); GSI Helmholtzzentrum für Schwerionenforschung GmbH/ExtreMe Matter Institute, EMMI, D-64291 Darmstadt (Germany); Jonson, B., E-mail: Bjorn.Jonson@chalmers.se [Fundamental Fysik, Chalmers Tekniska Högskola, S-412 96 Göteborg (Sweden); Nilsson, T. [Fundamental Fysik, Chalmers Tekniska Högskola, S-412 96 Göteborg (Sweden); Simon, H. [GSI Helmholtzzentrum für Schwerionenforschung GmbH/ExtreMe Matter Institute, EMMI, D-64291 Darmstadt (Germany)

2013-03-26

In a recent paper by S.I. Sidorchuk et al., Phys. Rev. Lett. 108 (2012) 202502, angular correlations in the decay of {sup 10}He were interpreted as a coherent superposition of a 0{sup +}, 1{sup −} and 2{sup +} states. It was concluded that it is the 1{sup −} state that dominates in the energy region 4.5–6 MeV. It is here demonstrated here that the experimental data might be understood without assuming the presence of a low-lying 1{sup −} state.

The numerical evaluation on non-radiative multiphonon transition rate from different electronic bases

International Nuclear Information System (INIS)

Zhu Bangfen.

1985-10-01

A numerical calculation on the non-radiative multiphonon transition probability based on the adiabatic approximation (AA) and the static approximation (SA) has been accomplished in a model of two electronic levels coupled to one phonon mode. The numerical results indicate that the spectra based on different approximations are generally different apart from those vibrational levels which are far below the classical crossing point. For large electron-phonon coupling constant, the calculated transition rates based on AA are more reliable; on the other hand, for small transition coupling the transition rates near or beyond the cross region are quite different for two approximations. In addition to the diagonal non-adiabatic potential, the mixing and splitting of the original static potential sheets are responsible for the deviation of the transition rates based on different approximations. The relationship between the transition matrix element and the vibrational level shift, the Huang-Rhys factor, the separation of the electronic levels and the electron-phonon coupling is analysed and discussed. (author)

Electron-nuclear. gamma. transition spectrum of a nucleus in a multicharged atomic ion

Energy Technology Data Exchange (ETDEWEB)

Ivanov, L N; Letokhov, V S

1987-08-01

The nuclear emission of absorption spectrum of an atom possesses a set of electron satelites which are due to an alternation of the state of the electron shell. It is shown that the mechanism of formation of the satellites might be different for neutral atoms and high-charge ions. In the first case (loose electron shell) a ''shaking'' of the shell resulting from the interaction between the nucleus and ..gamma.. quantum is predominant. In the second case (rigid electron shell) the mechanism involves a direct interaction between the ..gamma.. quantum and electrons. The second mechanism is important in the case of dipole nuclear transitions and dominates at ..gamma.. quantum energies electron transition multiplicity do not pertain to the second mechanism. Consequently, the satellite spectrum is much enriched and transitions between the fine and hyperfine structure components, transitions and transitions which do not involve a change in the electron configuration can be considered. The relative intensities of the satellites are determined by the smallest parameter ..mu../sub p//sup 2lambda/ (lambda is the nuclear transition multipole order, ..mu../sub p/ approx. 12 ..pi.. is the relative proton mass and z the core mass). In the spectrum of the plasma source the electron satellites corresponding to the ..gamma.. quantum emission and absorption lines are not overlapped by the Doppler contour of the ..gamma.. line.

Effect of electron-electron collisions on the phase transition and kinetics of nonequilibrium superconductors

International Nuclear Information System (INIS)

Elesin, V.F.; Kashurnikov, V.A.; Kondrashov, V.E.; Shamraev, B.N.

1983-01-01

An explicit expression is obtained for the distribution function of excess quasiparticles, taking into account electron-electron collisions in nonequilibrium superconductors. It is shown that the character of the phase transition may change at a definite ratio of the electron-electron and electron-phonon interaction constants: the dependence of the order parameter on the power of the source becomes single-valued. In addition, diffusion instability and paramagnetism of the superconductors arise. The multiplication factor of the excess quasiparticles due to electron-electron collisions and to reabsorption of phonons is calculated

Role of Sn impurity on electronic topological transitions in 122 Fe-based superconductors

Energy Technology Data Exchange (ETDEWEB)

Ghosh, Haranath, E-mail: hng@rrcat.gov.in [Homi Bhabha National Institute, Anushaktinagar, Mumbai 400 094 (India); Indus Synchrotrons Utilization Division, Raja Ramanna Centre for Advanced Technology, Indore 452013 (India); Sen, Smritijit [Homi Bhabha National Institute, Anushaktinagar, Mumbai 400 094 (India); Indus Synchrotrons Utilization Division, Raja Ramanna Centre for Advanced Technology, Indore 452013 (India)

2016-08-25

We show that only a few percentage of Sn doping at the Ba site on BaFe{sub 2}As{sub 2}, can cause electronic topological transition, namely, the Lifshitz transition. A hole like d{sub xy} band of Fe undergoes electron like transition due to 4% Sn doping. Lifshitz transition is found in BaFe{sub 2}As{sub 2} system around all the high symmetry points. Our detailed first principles simulation predicts absence of any Lifshitz transition in other 122 family compounds like SrFe{sub 2}As{sub 2}, CaFe{sub 2}As{sub 2} in agreement with experimental observations. This work bears practical significance due to the facts that a few percentage of Sn impurity is in-built in tin-flux grown single crystals method of synthesizing 122 materials and inter-relationship among the Lifshitz transition, magnetism and superconductivity. - Highlights: • Electronic topological transition due to Sn contamination in BaFe{sub 2}As{sub 2}. • Hole like Fe-d{sub xy} band converts into electron like in 3% Sn contaminated BaFe{sub 2}As{sub 2}. • Electron like Fe-d{sub xz}, d{sub yz} bands moves above Fermi Level at X,Y points. • No Lifshitz transition found in Sn-contaminated Sr-122, Ca-122 systems.

Electron impact spectra of methane, ethane, and neopentane

International Nuclear Information System (INIS)

Johnson, K.E.; Kim, K.; Johnston, D.B.; Lipsky, S.

1979-01-01

Electron impact spectra of methane, ethane, and neopentane have been obtained at scattering angles of 0 0 and 90 0 and at impact energies from approx. =30 to 250 eV. The data are consistent with the lowest excitation in all of these systems to involve promotion of an electron to a 3s Rydberg-like orbital. Differences between 0 0 and 90 0 onsets are attributed to large-angle intensity enhancements of transitions to the 3s Rydberg triplets. At 90 0 all of the spectra exhibit very similar intensity redistributions with strong enhancement of transitions in the 12 and 15 eV region as compared to lower-lying transitions. Assignments of the spectra and possible origins of the angular dependence are discussed

Lie Algebraic Treatment of Linear and Nonlinear Beam Dynamics

Energy Technology Data Exchange (ETDEWEB)

Alex J. Dragt; Filippo Neri; Govindan Rangarajan; David Douglas; Liam M. Healy; Robert D. Ryne

1988-12-01

The purpose of this paper is to present a summary of new methods, employing Lie algebraic tools, for characterizing beam dynamics in charged-particle optical systems. These methods are applicable to accelerator design, charged-particle beam transport, electron microscopes, and also light optics. The new methods represent the action of each separate element of a compound optical system, including all departures from paraxial optics, by a certain operator. The operators for the various elements can then be concatenated, following well-defined rules, to obtain a resultant operator that characterizes the entire system. This paper deals mostly with accelerator design and charged-particle beam transport. The application of Lie algebraic methods to light optics and electron microscopes is described elsewhere (1, see also 44). To keep its scope within reasonable bounds, they restrict their treatment of accelerator design and charged-particle beam transport primarily to the use of Lie algebraic methods for the description of particle orbits in terms of transfer maps. There are other Lie algebraic or related approaches to accelerator problems that the reader may find of interest (2). For a general discussion of linear and nonlinear problems in accelerator physics see (3).

Equation of motion approach for describing allowed transitions in Ne and Al3+ under classical and quantum plasmas

Science.gov (United States)

Chaudhuri, Supriya K.; Mukherjee, Prasanta K.; Chaudhuri, Rajat K.; Chattopadhyay, Sudip

2018-04-01

The equation of motion coupled cluster methodology within relativistic framework has been applied to analyze the electron correlation effects on the low lying dipole allowed excited states of Ne and Al3+ under classical and quantum plasma environments. The effect of confinement due to classical plasma has been incorporated through screened Coulomb potential, while that of quantum plasma has been treated by exponential cosine screened Coulomb potential. The confined structural properties investigated are the depression of ionization potential, low lying excitation energies (dipole allowed), oscillator strengths, transition probabilities, and frequency dependent polarizabilities under systematic variation of the plasma-atom coupling strength determined through the screening parameter. Specific atomic systems are chosen for their astrophysical importance and availability of experimental data related to laboratory plasma with special reference to Al3+ ion. Here, we consider 1 s22 s22 p6(1S0)→1 s22 s22 p5 n s /n d (1P1) (n =3 ,4 ) dipole allowed transitions of Ne and Al3+. Results for the free (isolated) atomic systems agree well with those available in the literature. Spectroscopic properties under confinement show systematic and interesting pattern with respect to plasma screening parameter.

Low Dimensional Vessiot-Guldberg-Lie Algebras of Second-Order Ordinary Differential Equations

Directory of Open Access Journals (Sweden)

Rutwig Campoamor-Stursberg

2016-03-01

Full Text Available A direct approach to non-linear second-order ordinary differential equations admitting a superposition principle is developed by means of Vessiot-Guldberg-Lie algebras of a dimension not exceeding three. This procedure allows us to describe generic types of second-order ordinary differential equations subjected to some constraints and admitting a given Lie algebra as Vessiot-Guldberg-Lie algebra. In particular, well-known types, such as the Milne-Pinney or Kummer-Schwarz equations, are recovered as special cases of this classification. The analogous problem for systems of second-order differential equations in the real plane is considered for a special case that enlarges the generalized Ermakov systems.

Hot Electron Photoemission from Plasmonic Nanostructures: The Role of Surface Photoemission and Transition Absorption

DEFF Research Database (Denmark)

Babicheva, Viktoriia; Zhukovsky, Sergei; Ikhsanov, Renat Sh

2015-01-01

We study mechanisms of photoemission of hot electrons from plasmonic nanoparticles. We analyze the contribution of "transition absorption", i.e., loss of energy of electrons passing through the boundary between different materials, to the surface mechanism of photoemission. We calculate photoemis......We study mechanisms of photoemission of hot electrons from plasmonic nanoparticles. We analyze the contribution of "transition absorption", i.e., loss of energy of electrons passing through the boundary between different materials, to the surface mechanism of photoemission. We calculate...... photoemission rate and transition absorption for nanoparticles surrounded by various media with a broad range of permittivities and show that photoemission rate and transition absorption follow the same dependence on the permittivity. Thus, we conclude that transition absorption is responsible...

Energy-level scheme and transition probabilities of Si-like ions

International Nuclear Information System (INIS)

Huang, K.N.

1984-01-01

Theoretical energy levels and transition probabilities are presented for 27 low-lying levels of silicon-like ions from Z = 15 to Z = 106. The multiconfiguration Dirac-Fock technique is used to calculate energy levels and wave functions. The Breit interaction and Lamb shift contributions are calculated perturbatively as corrections to the Dirac-Fock energy. The M1 and E2 transitions between the first nine levels and the E1 transitions between excited and the ground levels are presented

The Prevalence and Role of Low Lying Peroneus Brevis Muscle Belly in Patients with Peroneal Tendon Pathologies: A Potential Source for Tendon Subluxation

OpenAIRE

Mirmiran, Roya; Squire, Chad; Wassell, Daniel

2015-01-01

A low lying peroneus brevis muscle belly is a rare anomaly. There are few published studies that support presence of this anomaly as an etiology for peroneal tendon tear. However, the association between a low lying peroneus muscle belly (LLMB) and tendon subluxation is not well explored. In this retrospective study, the magnetic resonance imaging (MRI) and intraoperative findings of 50 consecutive patients undergoing a primary peroneal tendon surgery, in a five year period, were assessed. Th...

Determination of the production rate of low intensity isomeric transitions

International Nuclear Information System (INIS)

Lakosi, L.; Veres, A.; Tam, N.C.; Pavlicsek, I.

1992-01-01

Flat 2π and cylindrical 4π multiwire proportional counters were built for counting for low energy internal conversion electrons from the nuclear isomers 83m Kr, 103m Rh and 189m Os, induced by irradiation with high intensity 60 Co and 4 MeV bremsstrahlung sources. The β-decay of 176m Lu was recorded by a plastic scintillator. In this way higher sensitivities were attained than by detecting γ-rays or characteristic X-rays associated with the isomeric transitions, and the excitation of 189m Os by low energy 137 Cs and 300 kV X-ray sources also became detectable. Comparatively large isomeric activities produced by linac irradiation were standardizing by a Ge spectrometer for calibrating proportional and scintillation counting. (orig.)

Driving spin transition at interface: Role of adsorption configurations

Science.gov (United States)

Zhang, Yachao

2018-01-01

A clear insight into the electrical manipulation of molecular spins at interface is crucial to the design of molecule-based spintronic devices. Here we report on the electrically driven spin transition in manganocene physisorbed on a metallic surface in two different adsorption configurations predicted by ab initio techniques, including a Hubbard-U correction at the manganese site and accounting for the long-range van der Waals interactions. We show that the application of an electric field at the interface induces a high-spin to low-spin transition in the flat-lying manganocene, while it could hardly alter the high-spin ground state of the standing-up molecule. This phenomenon cannot be explained by either the molecule-metal charge transfer or the local electron correlation effects. We demonstrate a linear dependence of the intra-molecular spin-state splitting on the energy difference between crystal-field splitting and on-site Coulomb repulsion. After considering the molecule-surface binding energy shifts upon spin transition, we reproduce the obtained spin-state energetics. We find that the configuration-dependent responses of the spin-transition originate from the binding energy shifts instead of the variation of the local ligand field. Through these analyses, we obtain an intuitive understanding of the effects of molecule-surface contact on spin-crossover under electrical bias.

Low-lying S-wave and P-wave dibaryons in a nodal structure analysis

International Nuclear Information System (INIS)

Liu Yuxin; Li Jingsheng; Bao Chengguang

2003-01-01

The inherent nodal surface structure analysis approach is proposed for six-quark clusters with u, d, and s quarks. The wave functions of the six-quark clusters are classified, and the contribution of the hidden-color channels are discussed. The quantum numbers and configurations of the wave functions of the low-lying dibaryons are obtained. The states [ΩΩ] (0,0 + ) , [ΩΩ] (0,2 - ) , [Ξ * Ω] (1/2,0 + ) , and [Σ * Σ * ] (0,4 - ) and the hidden-color channel states with the same quantum numbers are proposed to be the candidates of experimentally observable dibaryons

Grupos de Lie

OpenAIRE

Rubio Martí, Vicente

2016-01-01

En el presente proyecto definimos lo que es un grupo de Lie, así como su respectiva álgebra de Lie canónica como aproximación lineal a dicho grupo de Lie. El proceso de linealización, que es hallar el algebra de Lie de un grupo de Lie dado, tiene su

Correlated electron pseudopotentials for 3d-transition metals

International Nuclear Information System (INIS)

Trail, J. R.; Needs, R. J.

2015-01-01

A recently published correlated electron pseudopotentials (CEPPs) method has been adapted for application to the 3d-transition metals, and to include relativistic effects. New CEPPs are reported for the atoms Sc − Fe, constructed from atomic quantum chemical calculations that include an accurate description of correlated electrons. Dissociation energies, molecular geometries, and zero-point vibrational energies of small molecules are compared with all electron results, with all quantities evaluated using coupled cluster singles doubles and triples calculations. The CEPPs give better results in the correlated-electron calculations than Hartree-Fock-based pseudopotentials available in the literature

Effects of electron transitions on the susceptibility of Cd3Mg

International Nuclear Information System (INIS)

Sereda, Yu.P.

1988-01-01

The monotone susceptibility component has been examined at 4.2-420 K for Cd 1-x Mg x ordering single crystals for 0.18 < x < 0.33. The temperature and concentration curves for the susceptibility components show features related to structural and electronic topological transitions. The susceptibility anomalies at the electron-transition points are correlated with the boundaries to the existence of the allotropic forms

High-Pressure Thermodynamic Properties of f-electron Metals, Transition Metal Oxides, and Half-Metallic Magnets

International Nuclear Information System (INIS)

Richard T. Scalettar; Warren E. Pickett

2005-01-01

This project involves research into the thermodynamic properties of f-electron metals, transition metal oxides, and half-metallic magnets at high pressure. These materials are ones in which the changing importance of electron-electron interactions as the distance between atoms is varied can tune the system through phase transitions from localized to delocalized electrons, from screened to unscreened magnetic moments, and from normal metal to one in which only a single spin specie can conduct. Three main thrusts are being pursued: (1) Mott transitions in transition metal oxides, (2) magnetism in half-metallic compounds, and (3) large volume-collapse transitions in f-band metals

High-Pressure Thermodynamic Properties of f-electron Metals, Transition Metal Oxides, and Half-Metallic Magnets

Energy Technology Data Exchange (ETDEWEB)

Scalettar, Richard T.; Pickett, Warren E.

2004-07-01

This project involves research into the thermodynamic properties of f-electron metals, transition metal oxides, and half-metallic magnets at high pressure. These materials are ones in which the changing importance of electron-electron interactions as the distance between atoms is varied can tune the system through phase transitions from localized to delocalized electrons, from screened to unscreened magnetic moments, and from normal metal to one in which only a single spin specie can conduct. Three main thrusts are being pursued: (1) Mott transitions in transition metal oxides, (2) magnetism in half-metallic compounds, and (3) large volume-collapse transitions in f-band metals.

High-Pressure Thermodynamic Properties of f-electron Metals, Transition Metal Oxides, and Half-Metallic Magnets

Energy Technology Data Exchange (ETDEWEB)

Richard T. Scalettar; Warren E. Pickett

2005-08-02

This project involves research into the thermodynamic properties of f-electron metals, transition metal oxides, and half-metallic magnets at high pressure. These materials are ones in which the changing importance of electron-electron interactions as the distance between atoms is varied can tune the system through phase transitions from localized to delocalized electrons, from screened to unscreened magnetic moments, and from normal metal to one in which only a single spin specie can conduct. Three main thrusts are being pursued: (i) Mott transitions in transition metal oxides, (ii) magnetism in half-metallic compounds, and (iii) large volume-collapse transitions in f-band metals.

Electronic energy states of HfSe/sub 2/ and NbSe/sub 2/ by low energy electron loss spectroscopy study

Energy Technology Data Exchange (ETDEWEB)

Ito, T; Iwami, M; Hiraki, A [Osaka Univ., Suita (Japan). Faculty of Engineering

1981-06-01

Low energy electron loss spectroscopy (ELS) study was performed on 1T-HfSe/sub 2/ (group IVB metal compound) and 2H-NbSe/sub 2/ (group VB metal compound) by using incident electron energies of 30-250 eV. From the loss data in the second derivative form, maxima in density-of-states in the conduction band of the compounds were deduced through the information on the filled core states by X-ray photoelectron spectroscopy. The conduction band of the transition-metal dichalcogenides could be divided into two parts. The results are discussed in relation to the previous work on WS/sub 2/ (group VIB metal compound), and also to proposals based on band calculations and experimental studies on the transition-metal dichalcogenides with constituent metals of group IVB, VB and VIB.

Coherent transition radiation from a laser wakefield accelerator as an electron bunch diagnostic

International Nuclear Information System (INIS)

Tilborg, J. van; Geddes, C.G.R.; Toth, C.; Esarey, E.; Schroeder, C.B.; Martin, M.C.; Hao, Z.; Leemans, W.P.

2004-01-01

The observation and modeling of coherent transition radiation from femtosecond laser accelerated electron bunches is discussed. The coherent transition radiation, scaling quadratically with bunch charge, is generated as the electrons transit the plasma-vacuum boundary. Due to the limited transverse radius of the plasma boundary, diffraction effects will strongly modify the angular distribution and the total energy radiated is reduced compared to an infinite transverse boundary. The multi-nC electron bunches, concentrated in a length of a few plasma periods (several tens of microns), experience partial charge neutralization while propagating inside the plasma towards the boundary. This reduces the space-charge blowout of the beam, allowing for coherent radiation at relatively high frequencies (several THz). The charge distribution of the electron bunch at the plasma-vacuum boundary can be derived from Fourier analysis of the coherent part of the transition radiation spectrum. A Michelson interferometer was used to measure the coherent spectrum, and electron bunches with duration on the order of 50 fs (rms) were observed

Transition from isentropic to isothermal expansion in laser produced plasmas

Energy Technology Data Exchange (ETDEWEB)

Barrero, A; Santartin, J R

1980-07-01

The transition that the expansion flow of laser-produced plasmas experiences when ones moves from long, low intensity pulses (temperature vanishing at the Isentropic plasma-vacuum front, lying at finite distance) to short, intense ones (non-zero, uni- form temperature at the plasma-vacuum front, lying at infinity) is studied. For planar geometry and large Ion number Z{sub j} the transition occurs for d {phi} / d t {approx_equal} 0.14(27/8)k{sup 7}/2 Z{sub j}{sup 3}/2/m{sub j}{sup 3}/2 K; {phi}, k, m{sub j}, and K are laser intensity, Boltzmann s constant, ion mass, and Spitzer s heat conduction coefficient. This result remains valid for finite Z{sub j} though the numerical factor in d{phi} / d t is different. In spherical geometry a similar transition occurs even in steady conditions. Shorter wavelength lasers and higher Z{sub j} plasmas allow faster rising pulses below transition. (Author) 13 refs.

Right Inferior Frontal Gyrus Activation as a Neural Marker of Successful Lying

Directory of Open Access Journals (Sweden)

Oshin eVartanian

2013-10-01

Full Text Available There is evidence to suggest that successful lying necessitates cognitive effort. We tested this hypothesis by instructing participants to lie or tell the truth under conditions of high and low working memory (WM load. The task required participants to register a response on 80 trials of identical structure within a 2 (WM Load: high, low × 2 (Instruction: truth or lie repeated-measures design. Participants were less accurate and responded more slowly when WM load was high, and also when they lied. High WM load activated the fronto-parietal WM network including dorsolateral prefrontal cortex (PFC, middle frontal gyrus, precuneus, and intraparietal cortex. Lying activated areas previously shown to underlie deception, including middle and superior frontal gyrus and precuneus. Critically, successful lying in the high vs. low WM load condition was associated with longer response latency, and it activated the right inferior frontal gyrus—a key brain region regulating inhibition. The same pattern of activation in the inferior frontal gyrus was absent when participants told the truth. These findings demonstrate that lying under high cognitive load places a burden on inhibition, and that the right inferior frontal gyrus may provide a neural marker for successful lying.

Right inferior frontal gyrus activation as a neural marker of successful lying.

Science.gov (United States)

Vartanian, Oshin; Kwantes, Peter J; Mandel, David R; Bouak, Fethi; Nakashima, Ann; Smith, Ingrid; Lam, Quan

2013-01-01

There is evidence to suggest that successful lying necessitates cognitive effort. We tested this hypothesis by instructing participants to lie or tell the truth under conditions of high and low working memory (WM) load. The task required participants to register a response on 80 trials of identical structure within a 2 (WM Load: high, low) × 2 (Instruction: truth or lie) repeated-measures design. Participants were less accurate and responded more slowly when WM load was high, and also when they lied. High WM load activated the fronto-parietal WM network including dorsolateral prefrontal cortex (PFC), middle frontal gyrus, precuneus, and intraparietal cortex. Lying activated areas previously shown to underlie deception, including middle and superior frontal gyrus and precuneus. Critically, successful lying in the high vs. low WM load condition was associated with longer response latency, and it activated the right inferior frontal gyrus-a key brain region regulating inhibition. The same pattern of activation in the inferior frontal gyrus was absent when participants told the truth. These findings demonstrate that lying under high cognitive load places a burden on inhibition, and that the right inferior frontal gyrus may provide a neural marker for successful lying.

Low-lying intruder state of the unbound nucleus {sup 13}Be

Energy Technology Data Exchange (ETDEWEB)

Kondo, Y., E-mail: kondo@phys.titech.ac.j [Department of Physics, Tokyo Institute of Technology, 2-12-1 Oh-Okayama, Meguro, Tokyo 152-8551 (Japan); Nakamura, T.; Satou, Y. [Department of Physics, Tokyo Institute of Technology, 2-12-1 Oh-Okayama, Meguro, Tokyo 152-8551 (Japan); Matsumoto, T.; Aoi, N. [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Endo, N. [Department of Physics, Tohoku University, 2-1-1 Katahira, Aoba, Sendai, Miyagi 980-8577 (Japan); Fukuda, N.; Gomi, T. [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Hashimoto, Y. [Department of Physics, Tokyo Institute of Technology, 2-12-1 Oh-Okayama, Meguro, Tokyo 152-8551 (Japan); Ishihara, M. [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Kawai, S. [Department of Physics, Rikkyo University, 3-34-1 Nishi-Ikebukuro, Toshima, Tokyo 171-8501 (Japan); Kitayama, M.; Kobayashi, T.; Matsuda, Y. [Department of Physics, Tohoku University, 2-1-1 Katahira, Aoba, Sendai, Miyagi 980-8577 (Japan); Matsui, N. [Department of Physics, Tokyo Institute of Technology, 2-12-1 Oh-Okayama, Meguro, Tokyo 152-8551 (Japan); Motobayashi, T. [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Nakabayashi, T.; Okumura, T. [Department of Physics, Tokyo Institute of Technology, 2-12-1 Oh-Okayama, Meguro, Tokyo 152-8551 (Japan); Ong, H.J.; Onishi, T.K. [Department of Physics, University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-0033 (Japan)

2010-06-21

An experimental study for the unbound nucleus {sup 13}Be has been performed by means of the invariant mass method via the one-neutron removal reaction {sup 1}H({sup 14}Be,{sup 12}Be+n). A resonance has been observed at 0.51(1) MeV in the relative energy (E{sub rel}) spectrum of the {sup 12}Be+n system. The transverse momentum distribution of the {sup 12}Be+n system as well as the resonance width of 0.45(3) MeV gives evidence for the p-wave nature of the resonance. A d-wave resonance has also been observed at 2.39(5) MeV in the E{sub rel} spectrum. The observation of the low-lying p-wave resonance indicates the disappearance of the N=8 magicity in the vicinity of the neutron drip line region.

Electronic computer prediction of properties of binary refractory transition metal compounds on the base of their simplificated electronic structure

International Nuclear Information System (INIS)

Kutolin, S.A.; Kotyukov, V.I.

1979-01-01

An attempt is made to obtain calculation equations of macroscopic physico-chemical properties of transition metal refractory compounds (density, melting temperature, Debye characteristic temperature, microhardness, standard formation enthalpy, thermo-emf) using the method of the regression analysis. Apart from the compound composition the argument of the regression equation is the distribution of electron bands of d-transition metals, created by the energy electron distribution in the simplified zone structure of transition metals and approximated by Chebishev polynoms, by the position of Fermi energy on the map of distribution of electron band energy depending upon the value of quasi-impulse, multiple to the first, second and third Brillouin zone for transition metals. The maximum relative error of the regressions obtained as compared with the literary data is 15-20 rel.%

Precision electron-gamma spectroscopic studies in 111Cd

International Nuclear Information System (INIS)

Sai Vignesh, T.; Chhetri, Premaditya; Vijay Sai, K.; Gowrishankar, R.; Venkataramaniah, K.; Deepa, S.; Rao, Dwarakarani; Kailas, S.

2011-01-01

The energy levels of 111 Cd has formerly been considered in terms of the states available to the 63rd neutron which is in the 3s 1/2 sub-shell. Kisslinger and Sorensen have used the pairing plus-quadrupole model to predict the energy levels. In the Coulomb excitation experiment only five levels have been excited. The decay of 111 Ag has been investigated only by few workers, Burmistov and Didorenko, Shevlev et al and Goswamy et al. The previous data on level energies, gamma energies and intensities differ considerably even for intense gamma transitions. There has been no detailed study of the internal conversion spectrum. There have been no multipolarity assignments for some of the transitions. An extensive experimental investigation of the gamma and conversion electron spectra has been undertaken to provide precision spectroscopic information on the low lying levels of 111 Cd from the beta decay of 111 Ag

Low temperature nuclear orientation studies of nuclei far from stability

International Nuclear Information System (INIS)

Brown, D.E.

1990-01-01

One of the major current interests in nuclear physics is to study transitional nuclei which lie between well known regions of spherical and deformed nuclei. The neutron deficient Tellurium and Iodine isotopes are examples of such nuclei. In both cases, the influence of a πg 9/2 intruder orbital is expected to be strong at low excitation energies and at A ∼120. The 120 Te decay scheme has been investigated in detail by LTNO supported by γ-γ coincidences and conversion electron spectroscopy. An interaction of the level scheme using an IBM-2 calculation which allows for mixing between the ground state and a (4p-2h) intruder state is made. The success of this calculation provides strong evidence for the existence of the intruder configuration in 120 Te. In addition, the relative electric quadrupole moments of the ground states in 120-123 I have been measured. The light Platinum isotopes are also transitional nuclei. The ground state magnetic dipole and electric quadrupole moments have been measured for 185,187 Pt which lie inside the region in which the shape transition is known to occur. An interpretation of nuclear moments and level structures in the range 179≤A≤193 using a particle plus triaxial core shows that the shape change takes place gradually via a broad region in which the nuclear shape is triaxial. (author)

Determination of electron bunch shape using transition radiation and phase-energy measurements

International Nuclear Information System (INIS)

Crosson, E.R.; Berryman, K.W.; Richman, B.A.

1995-01-01

We present data comparing microbunch temporal information obtained from electron beam phase-energy measurements with that obtained from transition radiation auto-correlation measurements. The data was taken to resolve some of the ambiguities in previous transition radiation results. By measuring the energy spectrum of the electron beam as a function of its phase relative to the accelerating field, phase-energy information was extracted. This data was analyzed using tomographic techniques to reconstruct the phase-space distribution assuming an electron energy dependence of E(var-phi) = E o + E acc cos(var-phi), where E o is the energy of an electron entering the field, E acc is the peak energy gain, and var-phi is the phase between the crest of the RF wave and an electron. Temporal information about the beam was obtained from the phase space distribution by taking the one dimensional projection along the time axis. We discuss the use of this technique to verify other transition radiation analysis methods

Determination of electron bunch shape using transition radiation and phase-energy measurements

Energy Technology Data Exchange (ETDEWEB)

Crosson, E.R.; Berryman, K.W.; Richman, B.A. [Stanford Univ., CA (United States)] [and others

1995-12-31

We present data comparing microbunch temporal information obtained from electron beam phase-energy measurements with that obtained from transition radiation auto-correlation measurements. The data was taken to resolve some of the ambiguities in previous transition radiation results. By measuring the energy spectrum of the electron beam as a function of its phase relative to the accelerating field, phase-energy information was extracted. This data was analyzed using tomographic techniques to reconstruct the phase-space distribution assuming an electron energy dependence of E({var_phi}) = E{sub o} + E{sub acc}cos({var_phi}), where E{sub o} is the energy of an electron entering the field, E{sub acc} is the peak energy gain, and {var_phi} is the phase between the crest of the RF wave and an electron. Temporal information about the beam was obtained from the phase space distribution by taking the one dimensional projection along the time axis. We discuss the use of this technique to verify other transition radiation analysis methods.

Determining partial differential cross sections for low-energy electron photodetachment involving conical intersections using the solution of a Lippmann-Schwinger equation constructed with standard electronic structure techniques.

Science.gov (United States)

Han, Seungsuk; Yarkony, David R

2011-05-07

A method for obtaining partial differential cross sections for low energy electron photodetachment in which the electronic states of the residual molecule are strongly coupled by conical intersections is reported. The method is based on the iterative solution to a Lippmann-Schwinger equation, using a zeroth order Hamiltonian consisting of the bound nonadiabatically coupled residual molecule and a free electron. The solution to the Lippmann-Schwinger equation involves only standard electronic structure techniques and a standard three-dimensional free particle Green's function quadrature for which fast techniques exist. The transition dipole moment for electron photodetachment, is a sum of matrix elements each involving one nonorthogonal orbital obtained from the solution to the Lippmann-Schwinger equation. An expression for the electron photodetachment transition dipole matrix element in terms of Dyson orbitals, which does not make the usual orthogonality assumptions, is derived.

High-resolution electron microscopy study of electron-irradiation-induced crystalline-to-amorphous transition in α-SiC single crystals

International Nuclear Information System (INIS)

Inui, H.; Mori, H.; Sakata, T.

1992-01-01

An electron-irradiation-induced crystalline-to-amorphous (CA) transition in α-SiC has been studied by high-resolution electron microscopy (HREM). The irradiation-produced damage structure was examined as a function of dose of electrons by taking high-resolution maps extending from the unirradiated crystalline region to the completely amorphized region. In the intermediate region between those two regions, that is in the CA transition region, the damage structure was essentially a mixture of crystalline and amorphous phases. The volume fraction of the amorphous phase was found to increase with increasing dose of electrons and no discrete crystalline-amorphous interface was observed in the CA transition region. These facts indicate the heterogeneous and gradual nature of the CA transition. In the transition region close to the unirradiated crystalline region, a sort of fragmentation of the crystal lattice was observed to occur, crystallites with slightly different orientations with respect to the parent crystal were formed owing to the strain around the dispersed local amorphous regions. In the transition region close to the amorphized region, these crystallites were reduced in size and were embedded in an amorphous matrix. This damage structure is the result of the increased volume fraction of the amorphous phase. In the completely amorphized region, no lattice fringes were recognized in the HREM images. The atomistic process of the CA transition is discussed on the basis of the present results and those from previous studies. (Author)

Quantum-classical transition in the electron dynamics of thin metal films

International Nuclear Information System (INIS)

Jasiak, R; Manfredi, G; Hervieux, P-A; Haefele, M

2009-01-01

The quantum electrons dynamics in a thin metal film is studied numerically using the self-consistent Wigner-Poisson equations. The initial equilibrium is computed from the Kohn-Sham equations at finite temperature, and then mapped into the phase-space Wigner function. The time-dependent results are compared systematically with those obtained previously with a classical approach (Vlasov-Poisson equations). It is found that, for large excitations, the quantum and classical dynamics display the same low-frequency oscillations due to ballistic electrons bouncing back and forth on the film surfaces. However, below a certain excitation energy (roughly corresponding to one quantum of plasmon energy ℎω p ), the quantum and classical results diverge, and the ballistic oscillations are no longer observed. These results provide an example of a quantum-classical transition that may be observed with current pump-probe experiments on thin metal films.

Theory of coherent transition radiation generated by ellipsoidal electron bunches

NARCIS (Netherlands)

Root, op 't W.P.E.M.; Smorenburg, P.W.; Oudheusden, van T.; Wiel, van der M.J.; Luiten, O.J.

2007-01-01

We present the theory of coherent transition radiation (CTR) generated by ellipsoidal electron bunches. We calculate analytical expressions for the electric field spectrum, the power spectrum, and the temporal electric field of CTR, generated by cylindrically symmetric ellipsoidal electron bunches

c -Axis Dimer and Its Electronic Breakup: The Insulator-to-Metal Transition in Ti2 O3

Science.gov (United States)

Chang, C. F.; Koethe, T. C.; Hu, Z.; Weinen, J.; Agrestini, S.; Zhao, L.; Gegner, J.; Ott, H.; Panaccione, G.; Wu, Hua; Haverkort, M. W.; Roth, H.; Komarek, A. C.; Offi, F.; Monaco, G.; Liao, Y.-F.; Tsuei, K.-D.; Lin, H.-J.; Chen, C. T.; Tanaka, A.; Tjeng, L. H.

2018-04-01

We report on our investigation of the electronic structure of Ti2 O3 using (hard) x-ray photoelectron and soft x-ray absorption spectroscopy. From the distinct satellite structures in the spectra, we have been able to establish unambiguously that the Ti-Ti c -axis dimer in the corundum crystal structure is electronically present and forms an a1 ga1 g molecular singlet in the low-temperature insulating phase. Upon heating, we observe a considerable spectral weight transfer to lower energies with orbital reconstruction. The insulator-metal transition may be viewed as a transition from a solid of isolated Ti-Ti molecules into a solid of electronically partially broken dimers, where the Ti ions acquire additional hopping in the a -b plane via the egπ channel, the opening of which requires consideration of the multiplet structure of the on-site Coulomb interaction.

Symmetrized density matrix renormalization group algorithm for low-lying excited states of conjugated carbon systems: Application to 1,12-benzoperylene and polychrysene

Science.gov (United States)

Prodhan, Suryoday; Ramasesha, S.

2018-05-01

The symmetry adapted density matrix renormalization group (SDMRG) technique has been an efficient method for studying low-lying eigenstates in one- and quasi-one-dimensional electronic systems. However, the SDMRG method had bottlenecks involving the construction of linearly independent symmetry adapted basis states as the symmetry matrices in the DMRG basis were not sparse. We have developed a modified algorithm to overcome this bottleneck. The new method incorporates end-to-end interchange symmetry (C2) , electron-hole symmetry (J ) , and parity or spin-flip symmetry (P ) in these calculations. The one-to-one correspondence between direct-product basis states in the DMRG Hilbert space for these symmetry operations renders the symmetry matrices in the new basis with maximum sparseness, just one nonzero matrix element per row. Using methods similar to those employed in the exact diagonalization technique for Pariser-Parr-Pople (PPP) models, developed in the 1980s, it is possible to construct orthogonal SDMRG basis states while bypassing the slow step of the Gram-Schmidt orthonormalization procedure. The method together with the PPP model which incorporates long-range electronic correlations is employed to study the correlated excited-state spectra of 1,12-benzoperylene and a narrow mixed graphene nanoribbon with a chrysene molecule as the building unit, comprising both zigzag and cove-edge structures.

A fresh look at the photoelectron spectrum of bromobenzene: A third-order non-Dyson electron propagator study

International Nuclear Information System (INIS)

Schneider, M.; Wormit, M.; Dreuw, A.; Soshnikov, D. Yu.; Trofimov, A. B.; Holland, D. M. P.; Powis, I.; Antonsson, E.; Patanen, M.; Nicolas, C.; Miron, C.

2015-01-01

The valence-shell ionization spectrum of bromobenzene, as a representative halogen substituted aromatic, was studied using the non-Dyson third-order algebraic-diagrammatic construction [nD-ADC(3)] approximation for the electron propagator. This method, also referred to as IP-ADC(3), was implemented as a part of the Q-Chem program and enables large-scale calculations of the ionization spectra, where the computational effort scales as n 5 with respect to the number of molecular orbitals n. The IP-ADC(3) scheme is ideally suited for investigating low-lying ionization transitions, so fresh insight could be gained into the cationic state manifold of bromobenzene. In particular, the present IP-ADC(3) calculations with the cc-pVTZ basis reveal a whole class of low-lying low-intensity two-hole-one-particle (2h-1p) doublet and quartet states, which are relevant to various photoionization processes. The good qualitative agreement between the theoretical spectral profile for the valence-shell ionization transitions generated with the smaller cc-pVDZ basis set and the experimental photoelectron spectrum measured at a photon energy of 80 eV on the PLÉIADES beamline at the Soleil synchrotron radiation source allowed all the main features to be assigned. Some theoretical aspects of the ionization energy calculations concerning the use of various approximation schemes and basis sets are discussed

Matrix elements of the relativistic electron-transition operators

International Nuclear Information System (INIS)

Rudzikas, Z.B.; Slepcov, A.A.; Kickin, I.S.

1976-01-01

The formulas, which enable us to calculate the electric and magnetic multipole transition probabilities in relativistic approximation under various gauge conditions of the electromagnetic potential, are presented. The numerical values of the coefficients of the one-electron reduced matrix elements of the relativistic operators of the electric and magnetic dipole transitions between the configurations K 0 n 2 l 2 j 2 α 0 J 0 j 2 J--K 0 n 1 l 1 j 1 α 0 'J 0 'j 1 J', where K 0 represents any electronic configuration, having the quantum number of the total angular momentum 0 less than or equal to J 0 less than or equal to 8 (the step is 1 / 2 ), and 1 / 2 less than or equal to j 2 , j 1 less than or equal to 7 / 2 , are given

Low-lying collective quadrupole and octupole strengths in even-even nuclei

International Nuclear Information System (INIS)

Raman, S.; Nestor, C.W. Jr.; Kahane, S.; Bhatt, K.H.

1991-01-01

The B(E2)↑ values for the first 2 + state of even-even nuclei in the Z≥50 region are compared with the predictions of several theoretical models. Comparative estimates of the overall agreement with the data are provided. Gaps and discrepancies in the data and examples that show interesting features such as shape changes are discussed. The B(E2)↑ values are examined critically to search for the dynamical Pauli effects predicted by the fermion dynamic symmetry model. The empirical B(E2)↑ and B(E3)↑ systematics are employed to obtain a measure of the harmonicity of the quadrupole and octupole vibrations. The fraction of the energy-weighted sum-rule strength exhausted by the sum of all known low-lying 2 + states below 2.3 MeV is found to be surprisingly constant in the 60< A<250 region except near closed shells

Electronic topological transition in zinc under pressure: An x-ray absorption spectroscopy study

International Nuclear Information System (INIS)

Aquilanti, G.; Trapananti, A.; Pascarelli, S.; Minicucci, M.; Principi, E.; Liscio, F.; Twarog, A.

2007-01-01

Zinc metal has been studied at high pressure using x-ray absorption spectroscopy. In order to investigate the role of the different degrees of hydrostaticity on the occurrence of structural anomalies following the electronic topological transition, two pressure transmitting media have been used. Results show that the electronic topological transition, if it exists, does not induce an anomaly in the local environment of compressed Zn as a function of hydrostatic pressure and any anomaly must be related to a loss of hydrostaticity of the pressure transmitting medium. The near-edge structures of the spectra, sensitive to variations in the electronic density of states above the Fermi level, do not show any evidence of electronic transition whatever pressure transmitting medium is used

Quantum spin-glass transition in the two-dimensional electron gas

Indian Academy of Sciences (India)

Home; Journals; Pramana – Journal of Physics; Volume 58; Issue 2 ... Spin glasses; quantum phase transition; ferromagnetism; electron gas. ... We argue that a quantum transition involving the destruction of the spin-glass order in an applied in-plane magnetic field offers a natural explanation of some features of recent ...

Electronic traffic signs: Reflecting upon its transition

Energy Technology Data Exchange (ETDEWEB)

Arbaiza Martin, A.E.; Alba, A.L.; Hernando Mazon, A.; Blanch Mico, M.T.

2016-07-01

In our days we face a fundamental issue concerning road signs. We may display contents in vertical and horizontal format (static signs, variable message signs, road markings), either on a post, a gantry or a dashboard. And we foresee a coming age where the excellent matrix resolution of painted signs will be truly approached by the resolution of full matrix displays. But we also risk a babel context threatening the universal approach encouraged by international catalogues as the 1968 Convention (ECE/TRANS/196, 2007). And the fundamental risk comes from our decisions regarding how the transition from the contents and formats displayed on static message signs to the ones displayed on electronic signs (in gantries or dashboards) should be. Our work explores this issue specifically, considering the transition from Advance Direction Signs (static message signs, class G, 1 in the 1968 Convention) to what could be termed Advance Location Signs (signs concerning the location of variable events with regards to certain landmarks) developed as an adaptation of the G, 1 class to electronic traffic signs.(Author)

Predictors of children's prosocial lie-telling: Motivation, socialization variables, and moral understanding.

Science.gov (United States)

Popliger, Mina; Talwar, Victoria; Crossman, Angela

2011-11-01

Children tell prosocial lies for self- and other-oriented reasons. However, it is unclear how motivational and socialization factors affect their lying. Furthermore, it is unclear whether children's moral understanding and evaluations of prosocial lie scenarios (including perceptions of vignette characters' feelings) predict their actual prosocial behaviors. These were explored in two studies. In Study 1, 72 children (36 second graders and 36 fourth graders) participated in a disappointing gift paradigm in either a high-cost condition (lost a good gift for a disappointing one) or a low-cost condition (received a disappointing gift). More children lied in the low-cost condition (94%) than in the high-cost condition (72%), with no age difference. In Study 2, 117 children (42 preschoolers, 41 early elementary school age, and 34 late elementary school age) participated in either a high- or low-cost disappointing gift paradigm and responded to prosocial vignette scenarios. Parents reported on their parenting practices and family emotional expressivity. Again, more children lied in the low-cost condition (68%) than in the high-cost condition (40%); however, there was an age effect among children in the high-cost condition. Preschoolers were less likely than older children to lie when there was a high personal cost. In addition, compared with truth-tellers, prosocial liars had parents who were more authoritative but expressed less positive emotion within the family. Finally, there was an interaction between children's prosocial lie-telling behavior and their evaluations of the protagonist's and recipient's feelings. Findings contribute to understanding the trajectory of children's prosocial lie-telling, their reasons for telling such lies, and their knowledge about interpersonal communication. Copyright © 2011 Elsevier Inc. All rights reserved.

Transition of radial electric field by electron cyclotron heating in stellarator plasmas

International Nuclear Information System (INIS)

Idei, H.; Ida, K.; Sanuki, H.

1993-06-01

The transition of a radial electric field from a negative to a positive value is observed in Compact Helical System when the electron loss is sufficiently enhanced by the superposition of the off-axis second harmonic electron cyclotron heating on the neutral beam heated plasmas. The observed threshold for the enhanced particle flux required to cause the transition is compared with a theoretical prediction. (author)

Lie superalgebras

International Nuclear Information System (INIS)

Berezin, F.A.

1977-01-01

Generalization of the Laplace-Casimir operator theory on the Lie supergroups is considered. The main result is the formula for radial parts of the Laplace operators under some general assumptions about the Lie supergroup. In particular these assumptions are valid for the Lie suppergroups U(p,g) and C (m,n). The first one is the analogue of the unitary group, the second one is the analogue of the linear group of canonical transformations

"Lie to me"-Oxytocin impairs lie detection between sexes.

Science.gov (United States)

Pfundmair, Michaela; Erk, Wiebke; Reinelt, Annika

2017-10-01

The hormone oxytocin modulates various aspects of social behaviors and even seems to lead to a tendency for gullibility. The aim of the current study was to investigate the effect of oxytocin on lie detection. We hypothesized that people under oxytocin would be particularly susceptible to lies told by people of the opposite sex. After administration of oxytocin or a placebo, male and female participants were asked to judge the veracity of statements from same- vs. other-sex actors who either lied or told the truth. Results showed that oxytocin decreased the ability of both male and female participants to correctly classify other-sex statements as truths or lies compared to placebo. This effect was based on a lower ability to detect lies and not a stronger bias to regard truth statements as false. Revealing a new effect of oxytocin, the findings may support assumptions about the hormone working as a catalyst for social adaption. Copyright © 2017. Published by Elsevier Ltd.

Quantum-classical transition in the electron dynamics of thin metal films

Energy Technology Data Exchange (ETDEWEB)

Jasiak, R; Manfredi, G; Hervieux, P-A [Institut de Physique et Chimie des Materiaux, CNRS and Universite de Strasbourg, BP 43, F-67034 Strasbourg (France); Haefele, M [INRIA Nancy Grand-Est and Institut de Recherche en Mathematiques Avancees, 7 rue Rene Descartes, F-67084 Strasbourg (France)], E-mail: Giovanni.Manfredi@ipcms.u-strasbg.fr

2009-06-15

The quantum electrons dynamics in a thin metal film is studied numerically using the self-consistent Wigner-Poisson equations. The initial equilibrium is computed from the Kohn-Sham equations at finite temperature, and then mapped into the phase-space Wigner function. The time-dependent results are compared systematically with those obtained previously with a classical approach (Vlasov-Poisson equations). It is found that, for large excitations, the quantum and classical dynamics display the same low-frequency oscillations due to ballistic electrons bouncing back and forth on the film surfaces. However, below a certain excitation energy (roughly corresponding to one quantum of plasmon energy {Dirac_h}{omega}{sub p}), the quantum and classical results diverge, and the ballistic oscillations are no longer observed. These results provide an example of a quantum-classical transition that may be observed with current pump-probe experiments on thin metal films.

Three-body hadronic structure of low-lying 1/2+ Σ and Λ resonances

International Nuclear Information System (INIS)

Martinez Torres, A.; Khemchandani, K.P.; Oset, E.

2008-01-01

We discuss the dynamical generation of some low-lying 1/2 + Σ's and Λ's in two-meson one-baryon systems. These systems have been constructed by adding a pion in the S-wave to the anti KN pair and its coupled channels, where the 1/2 - Λ(1405)-resonance gets dynamically generated. We solve Faddeev equations in the coupled-channel approach to calculate the T-matrix for these systems as a function of the total energy and the invariant mass of one of the meson-baryon pairs. This squared T-matrix shows peaks at the energies very close to the masses of the strangeness -1,1/2 + resonances listed in the particle data book. (orig.)

Lie construction affects information storage under high memory load condition.

Directory of Open Access Journals (Sweden)

Yuqiu Liu

Full Text Available Previous studies indicate that lying consumes cognitive resources, especially working memory (WM resources. Considering the dual functions that WM might play in lying: holding the truth-related information and turning the truth into lies, the present study examined the relationship between the information storage and processing in the lie construction. To achieve that goal, a deception task based on the old/new recognition paradigm was designed, which could manipulate two levels of WM load (low-load task using 4 items and high-load task using 6 items during the deception process. The analyses based on the amplitude of the contralateral delay activity (CDA, a proved index of the number of representations being held in WM, showed that the CDA amplitude was lower in the deception process than that in the truth telling process under the high-load condition. In contrast, under the low-load condition, no CDA difference was found between the deception and truth telling processes. Therefore, we deduced that the lie construction and information storage compete for WM resources; when the available WM resources cannot meet this cognitive demand, the WM resources occupied by the information storage would be consumed by the lie construction.

Lie construction affects information storage under high memory load condition.

Science.gov (United States)

Liu, Yuqiu; Wang, Chunjie; Jiang, Haibo; He, Hongjian; Chen, Feiyan

2017-01-01

Previous studies indicate that lying consumes cognitive resources, especially working memory (WM) resources. Considering the dual functions that WM might play in lying: holding the truth-related information and turning the truth into lies, the present study examined the relationship between the information storage and processing in the lie construction. To achieve that goal, a deception task based on the old/new recognition paradigm was designed, which could manipulate two levels of WM load (low-load task using 4 items and high-load task using 6 items) during the deception process. The analyses based on the amplitude of the contralateral delay activity (CDA), a proved index of the number of representations being held in WM, showed that the CDA amplitude was lower in the deception process than that in the truth telling process under the high-load condition. In contrast, under the low-load condition, no CDA difference was found between the deception and truth telling processes. Therefore, we deduced that the lie construction and information storage compete for WM resources; when the available WM resources cannot meet this cognitive demand, the WM resources occupied by the information storage would be consumed by the lie construction.

M1-transitions in the MIT bag model

International Nuclear Information System (INIS)

Hackman, R.H.; Deshpande, N.G.; Dicus, D.A.; Teplitz, V.L.

1977-03-01

In the MIT bag model, the M1-transitions of low lying hadrons are investigated. The following calculations are performed: 32 hadron masses are recomputed with a choice of bag parameters designed to give the correct values for the proton magnetic moment, μ/sub p/, and several masses, M/sub rho/ M/sub ω/ M/sub Δ/ M/sub Ω/, and M/sub D/; (2) eta, eta', eta/sub c/ mixing is computed in an untrustworthy approximation; and the widths for 38 M1-transitions are computed

Hot-electron effect in spin relaxation of electrically injected electrons in intrinsic Germanium.

Science.gov (United States)

Yu, T; Wu, M W

2015-07-01

The hot-electron effect in the spin relaxation of electrically injected electrons in intrinsic germanium is investigated by the kinetic spin Bloch equations both analytically and numerically. It is shown that in the weak-electric-field regime with E ≲ 0.5 kV cm(-1), our calculations have reasonable agreement with the recent transport experiment in the hot-electron spin-injection configuration (2013 Phys. Rev. Lett. 111 257204). We reveal that the spin relaxation is significantly enhanced at low temperature in the presence of weak electric field E ≲ 50 V cm(-1), which originates from the obvious center-of-mass drift effect due to the weak electron-phonon interaction, whereas the hot-electron effect is demonstrated to be less important. This can explain the discrepancy between the experimental observation and the previous theoretical calculation (2012 Phys. Rev. B 86 085202), which deviates from the experimental results by about two orders of magnitude at low temperature. It is further shown that in the strong-electric-field regime with 0.5 ≲ E ≲ 2 kV cm(-1), the spin relaxation is enhanced due to the hot-electron effect, whereas the drift effect is demonstrated to be marginal. Finally, we find that when 1.4 ≲ E ≲ 2 kV cm(-1) which lies in the strong-electric-field regime, a small fraction of electrons (≲5%) can be driven from the L to Γ valley, and the spin relaxation rates are the same for the Γ and L valleys in the intrinsic sample without impurity. With the negligible influence of the spin dynamics in the Γ valley to the whole system, the spin dynamics in the L valley can be measured from the Γ valley by the standard direct optical transition method.

The drift velocity of electrons in water vapour at low values of E/N

International Nuclear Information System (INIS)

Cheung, B.; Elford, M.T.

1990-01-01

The drift velocity of electrons in water vapour at 294 K has been measured over the E/N range 1.4 to 40 Td with an error estimated to be 35 Td. The present data show that μN decreases monotonically with decreasing E/N at low E/N values as observed by Wilson et al. (1975) and does not become independent of E/N as indicated by Lowke and Rees (1963). The present values although lower than those of Lowke and Rees, lie within the combined error limits, except for values below 2 Td. The present data suggested that the momentum transfer cross section at low energies is approximately 10% larger than that obtained by Pack et al. (1962) from their drift velocity measurements. 13 refs., 2 tabs., 5 figs

DFT and two-dimensional correlation analysis methods for evaluating the Pu3+–Pu4+ electronic transition of plutonium-doped zircon

International Nuclear Information System (INIS)

Bian, Liang; Dong, Fa-qin; Song, Mian-xin; Dong, Hai-liang; Li, Wei-Min; Duan, Tao; Xu, Jin-bao; Zhang, Xiao-yan

2015-01-01

Highlights: • Effect of Pu f-shell electron on the electronic property of zircon is calculated via DFT and 2D-CA techniques. • Reasons of Pu f-shell electron influencing on electronic properties are systematically discussed. • Phase transitions are found at two point 2.8 mol% and 7.5 mol%. - Abstract: Understanding how plutonium (Pu) doping affects the crystalline zircon structure is very important for risk management. However, so far, there have been only a very limited number of reports of the quantitative simulation of the effects of the Pu charge and concentration on the phase transition. In this study, we used density functional theory (DFT), virtual crystal approximation (VCA), and two-dimensional correlation analysis (2D-CA) techniques to calculate the origins of the structural and electronic transitions of Zr 1−c Pu c SiO 4 over a wide range of Pu doping concentrations (c = 0–10 mol%). The calculations indicated that the low-angular-momentum Pu-f xy -shell electron excites an inner-shell O-2s 2 orbital to create an oxygen defect (V O-s ) below c = 2.8 mol%. This oxygen defect then captures a low-angular-momentum Zr-5p 6 5s 2 electron to form an sp hybrid orbital, which exhibits a stable phase structure. When c > 2.8 mol%, each accumulated V O-p defect captures a high-angular-momentum Zr-4d z electron and two Si-p z electrons to create delocalized Si 4+ → Si 2+ charge disproportionation. Therefore, we suggest that the optimal amount of Pu cannot exceed 7.5 mol% because of the formation of a mixture of ZrO 8 polyhedral and SiO 4 tetrahedral phases with the orientation (10-1). This study offers new perspective on the development of highly stable zircon-based solid solution materials

Substrate effects on photoluminescence and low temperature phase transition of methylammonium lead iodide hybrid perovskite thin films

Science.gov (United States)

Shojaee, S. A.; Harriman, T. A.; Han, G. S.; Lee, J.-K.; Lucca, D. A.

2017-07-01

We examine the effects of substrates on the low temperature photoluminescence (PL) spectra and phase transition in methylammonium lead iodide hybrid perovskite (CH3NH3PbI3) thin films. Structural characterization at room temperature with X-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman spectroscopy indicated that while the chemical structure of films deposited on glass and quartz was similar, the glass substrate induced strain in the perovskite films and suppressed the grain growth. The luminescence response and phase transition of the perovskite thin films were studied by PL spectroscopy. The induced strain was found to affect both the room temperature and low temperature PL spectra of the hybrid perovskite films. In addition, it was found that the effects of the glass substrate inhibited a tetragonal to orthorhombic phase transition such that it occurred at lower temperatures.

Changing electronic density in sites of crystalline lattice under superconducting of phase transition

International Nuclear Information System (INIS)

Turaev, N.Yu.; Turaev, E.Yu.; Khuzhakulov, E.S.; Seregin, P.P.

2006-01-01

Results of electron density change calculations for sites of the one-dimensional Kronig-Penny lattice at the superconducting phase transition have been presented. The transition from normal state to super conducting one is accompanied by the rise of the electron density at the unit cell centre. It is agreement with Moessbauer spectroscopy data. (author)

Lie Superalgebras

CERN Document Server

Papi, Paolo; Advances in Lie Superalgebras

2014-01-01

The volume is the outcome of the conference "Lie superalgebras," which was held at the Istituto Nazionale di Alta Matematica, in 2012. The conference gathered many specialists in the subject, and the talks held provided comprehensive insights into the newest trends in research on Lie superalgebras (and related topics like vertex algebras, representation theory and supergeometry). The book contains contributions of many leading esperts in the field and provides a complete account of the newest trends in research on Lie Superalgebras.

Upper ocean stratification and sea ice growth rates during the summer-fall transition, as revealed by Elephant seal foraging in the Adélie Depression, East Antarctica

Science.gov (United States)

Williams, G. D.; Hindell, M.; Houssais, M.-N.; Tamura, T.; Field, I. C.

2011-03-01

Southern elephant seals (Mirounga leonina), fitted with Conductivity-Temperature-Depth sensors at Macquarie Island in January 2005 and 2010, collected unique oceanographic observations of the Adélie and George V Land continental shelf (140-148° E) during the summer-fall transition (late February through April). This is a key region of dense shelf water formation from enhanced sea ice growth/brine rejection in the local coastal polynyas. In 2005, two seals occupied the continental shelf break near the grounded icebergs at the northern end of the Mertz Glacier Tongue for several weeks from the end of February. One of the seals migrated west to the Dibble Ice Tongue, apparently utilising the Antarctic Slope Front current near the continental shelf break. In 2010, immediately after that year's calving of the Mertz Glacier Tongue, two seals migrated to the same region but penetrated much further southwest across the Adélie Depression and sampled the Commonwealth Bay polynya from March through April. Here we present observations of the regional oceanography during the summer-fall transition, in particular (i) the zonal distribution of modified Circumpolar Deep Water exchange across the shelf break, (ii) the upper ocean stratification across the Adélie Depression, including alongside iceberg C-28 that calved from the Mertz Glacier and (iii) the convective overturning of the deep remnant seasonal mixed layer in Commonwealth Bay from sea ice growth. Heat and freshwater budgets to 200-300 m are used to estimate the ocean heat content (400→50 MJ m-2), flux (50-200 W m-2 loss) and sea ice growth rates (maximum of 7.5-12.5 cm day-1). Mean seal-derived sea ice growth rates were within the range of satellite-derived estimates from 1992-2007 using ERA-Interim data. We speculate that the continuous foraging by the seals within Commonwealth Bay during the summer/fall transition was due to favorable feeding conditions resulting from the convective overturning of the deep

Study of radicals, clusters and transition state species by anion photoelectron spectroscopy

International Nuclear Information System (INIS)

Arnold, D.W.

1994-08-01

Free radicals, elemental and van der Waals clusters and transition state species for bimolecular chemical reactions are investigated using anion photoelectron spectroscopy. Several low-lying electronic states of ozone have been identified via photoelectron spectroscopy of O 3 - . A characterization of these states is important to models for atmospheric ozone reaction kinetics. The fluoroformyloxyl radical, FCO 2 , has been investigated, providing vibrational frequencies and energies for two electronic states. The technique has also been employed to make the first direct observation and characterization of the NNO 2 molecule. Several electronic states are observed for this species which is believed to play a role as a reactive intermediate in the N + NO 2 reaction. The experimental results for all three of these radicals are supplemented by ab initio investigations of their molecular properties. The clusters investigations include studies of elemental carbon clusters (C 2 - - C 11 - ), and van der Waals clusters (X - (CO 2 ) n , X = I, Br, Cl; n ≤ 13 and I - (N 2 O) n=1--11 ). Primarily linear clusters are observed for the smaller carbon clusters, while the spectra of the larger clusters contain contribution from cyclic anion photodetachment. Very interesting ion-solvent interactions are observed in the X - (CO 2 )n clusters. The transition state regions for several bimolecular chemical reactions have also been investigated by photodetachment of a negative ion precursor possessing a geometry similar to that of the transition state species. These spectra show features which are assigned to motions of the unstable neutral complex existing between reactants and products

Cyclic electron flow is redox-controlled but independent of state transition.

Science.gov (United States)

Takahashi, Hiroko; Clowez, Sophie; Wollman, Francis-André; Vallon, Olivier; Rappaport, Fabrice

2013-01-01

Photosynthesis is the biological process that feeds the biosphere with reduced carbon. The assimilation of CO2 requires the fine tuning of two co-existing functional modes: linear electron flow, which provides NADPH and ATP, and cyclic electron flow, which only sustains ATP synthesis. Although the importance of this fine tuning is appreciated, its mechanism remains equivocal. Here we show that cyclic electron flow as well as formation of supercomplexes, thought to contribute to the enhancement of cyclic electron flow, are promoted in reducing conditions with no correlation with the reorganization of the thylakoid membranes associated with the migration of antenna proteins towards Photosystems I or II, a process known as state transition. We show that cyclic electron flow is tuned by the redox power and this provides a mechanistic model applying to the entire green lineage including the vast majority of the cases in which state transition only involves a moderate fraction of the antenna.

Motivation and Consequences of Lying. A Qualitative Analysis of Everyday Lying

Directory of Open Access Journals (Sweden)

Beata Arcimowicz

2015-09-01

Full Text Available This article presents findings of qualitative analysis of semi-structured interviews with a group of "frequent liars" and another of "rare liars" who provided their subjective perspectives on the phenomenon of lying. Participants in this study previously had maintained a diary of their social interactions and lies over the course of one week, which allowed to assign them to one of the two groups: frequent or rare liars. Thematic analysis of the material followed by elements of theory formulation resulted in an extended lying typology that includes not only the target of the lie (the liar vs. other but also the motivation (protection vs. bringing benefits. We offer an analysis of what prevents from telling the truth, i.e. penalties, relationship losses, distress of the lied-to, and anticipated lack of criticism for telling the truth. We also focus on understanding moderatorsof consequences of lying (significance of the area of life, the type of lie and capacity to understand the liar that can be useful in future studies. URN: http://nbn-resolving.de/urn:nbn:de:0114-fqs1503318

Electronic transport and conduction mechanism transition in La1∕3Sr2∕3FeO3 thin films

International Nuclear Information System (INIS)

Devlin, R. C.; Krick, A. L.; Sichel-Tissot, R. J.; Xie, Y. J.; May, S. J.

2014-01-01

We report on the electronic transport properties of epitaxial La 1∕3 Sr 2∕3 FeO 3 films using temperature dependent resistivity, Hall effect, and magnetoresistance measurements. We show that the electronic phase transition, which occurs near 190 K, results in a change in conduction mechanism from nonadiabatic polaron transport at high temperatures to resistivity behavior following a power law temperature dependence at low temperatures. The phase transition is also accompanied by an abrupt increase in apparent mobility and Hall coefficient below the critical temperature (T*). We argue that the exotic low temperature transport properties are a consequence of the unusually long-range periodicity of the antiferromagnetic ordering, which also couples to the electronic transport in the form of a negative magnetoresistance below T* and a sign reversal of the Hall coefficient at T*. By comparing films of differing thicknesses, stoichiometry, and strain states, we demonstrate that the observed conduction behavior is a robust feature of La 1∕3 Sr 2∕3 FeO 3 .

Electric dipole excitation of {sup 208}Pb by polarized electron impact

Energy Technology Data Exchange (ETDEWEB)

Jakubassa-Amundsen, D.H. [University of Munich, Mathematics Institute, Munich (Germany); Ponomarev, V.Yu. [Technische Universitaet Darmstadt, Institut fuer Kernphysik, Darmstadt (Germany)

2016-03-15

The cross sections and spin asymmetries for the excitation of 1{sup -} states in {sup 208}Pb by transversely polarized electrons with collision energy of 30-180MeV have been examined within the DWBA scattering formalism. As examples, we have considered a low-lying 1{sup -} state and also states belonging to the pygmy dipole and giant dipole resonances. The structure of these states and their corresponding transition charge and current densities have been taken from an RPA calculation within the quasiparticle phonon model. The complex-plane rotation method has been applied to achieve the convergence of the radial DWBA integrals for backward scattering. We have studied the behaviour of the cross sections and spin asymmetries as a function of electron energy and scattering angle. The role of the longitudinal and transversal contributions to the excitation has been thoroughly studied. We conclude that the spin asymmetry S, related to unpolarized outgoing electrons, is mostly well below 1% even at the backward scattering angles and its measurement provides a challenge for future experiments with polarized electrons. (orig.)

Low-energy electron-helium scattering in a Nd–YAG laser field

International Nuclear Information System (INIS)

Ajana, I.; Makhoute, A.; Khalil, D.

2014-01-01

Highlights: • Laser assisted electron helium excitation is studied at low incident energies. • The inclusion of the second-order Born contributions is significant at low incident energies. • The target distortion induced by the laser field should be taken into account. • The effect of the second term of the Born series is reduced as the energy increases. - Abstract: We study the electron-impact excitation of atomic helium, in the presence of a linearly polarized Nd–YAG laser field, accompanied by the transfer of ℓ photons, for low collision energy of 25 eV and laser intensity of 5.3 × 10 11 W cm −2 . The second-order Born approximation has been used to calculate the differential cross sections. Detailed calculations of the scattering amplitudes are performed by using the Sturmian basis expansion. A detailed analysis is made of the excitation of the 1 1 S → 2 1 S and 1 1 S → 2 1 P transitions. We discuss the behavior and the variation of the cross sections corresponding to the excitation process for various geometrical configurations

Spin crossover and Mott—Hubbard transition under high pressure and high temperature in the low mantle of the Earth

Science.gov (United States)

Ovchinnikov, S. G.; Ovchinnikova, T. M.; Plotkin, V. V.; Dyad'kov, P. G.

2015-11-01

Effect of high pressure induced spin crossover on the magnetic, electronic and structural properties of the minerals forming the Earth's low mantle is discussed. The low temperature P, T phase diagram of ferropericlase has the quantum phase transition point Pc = 56 GPa at T = 0 confirmed recently by the synchrotron Mössbauer spectroscopy. The LDA+GTB calculated phase diagram describes the experimental data. Its extension to the high temperature resulted earlier in prediction of the metallic properties of the Earth's mantle at the depth 1400 km insulator transition and compare them with the experimental seismic and geomagnetic field data.

Effects of hydrogen-like impurity and electromagnetic field on quantum transition of an electron in a Gaussian potential with QD thickness

Science.gov (United States)

Xin, Wei; Zhao, Yu-Wei; Sudu; Eerdunchaolu

2018-05-01

Considering Hydrogen-like impurity and the thickness effect, the eigenvalues and eigenfunctions of the electronic ground and first exited states in a quantum dot (QD) are derived by using the Lee-Low-Pins-Pekar variational method with the harmonic and Gaussian potentials as the transverse and longitudinal confinement potentials, respectively. A two-level system is constructed on the basis of those two states, and the electronic quantum transition affected by an electromagnetic field is discussed in terms of the two-level system theory. The results indicate the Gaussian potential reflects the real confinement potential more accurately than the parabolic one; the influence of the thickness of the QD on the electronic transition probability is interesting and significant, and cannot be ignored; the electronic transition probability Γ is influenced significantly by some physical quantities, such as the strength of the electron-phonon coupling α, the electric-field strength F, the magnetic-field cyclotron frequency ωc , the barrier height V0 and confinement range L of the asymmetric Gaussian potential, suggesting the transport and optical properties of the QD can be manipulated further though those physical quantities.

Gas phase structure of transition metal dihydrides

International Nuclear Information System (INIS)

Demuynck, J.; Schaefer, H.F. III

1980-01-01

ESR and infrared spectroscopic measurements on matrix isolated MnH 2 and CrH 2 have recently suggested that these simple molecules may be bent. This result would be the opposite of that found experimentally for the transition metal dihalides MX 2 , known to be linear. Here the geometrical structure of MnH 2 has been investigated by molecular electronic structure theory. A large contracted Gaussian basis set [Mn(14s11p6p/9s8p3d), H(5s1p/3s1p)] was used in conjunction with self-consistent field and configuration interaction methods. These suggest that the 6 A 1 ground state of MnH 2 is linear. Further studies of the 3 A 1 state (one of several low-lying states) of TiH 2 also favor linearity, although this potential energy surface is extremely flat with respect to bending. Thus it appears probable that most MH 2 molecules, like the related MX 2 family, are linear

RPC Calculations for K-forbidden Transitions in {sup 183}W, Evidence for Large Inertial Parameter Connected with High-lying Rotational Bands

Energy Technology Data Exchange (ETDEWEB)

Malmskog, S G [AB Atomenergi, Nykoeping (Sweden); Wahlborn, S [Div. of Theore tical Physics, Royal Inst. of Technology Stockholm (Sweden)

1967-09-15

Recent measurements have shown that the transitions deexciting the 453 keV 7/2{sup -} level in {sup 183}W to the K = 1/2{sup -} and 3/2{sup -} bands are strongly retarded. The data for B(M1) and B(E2) are analyzed in terms of the RPC model (rotation + particle motion + coupling). With the {delta}K = 1 (Coriolis) coupling, the K-forbidden M1-transitions proceed via admixtures of high-lying 5/2{sup -} bands. A reasonable and unambiguous fit to the data is obtained by varying the strength of the coupling. Allowing for various uncertainties and corrections, one finds that the inertial parameter (the inverse of the coupling constant, i. e. 2J(2{pi}){sup 2}/({Dirac_h}){sup 2} may have values between roughly 1 and 3 times the rigid rotator value of 2J(2{pi}){sup 2}/({Dirac_h}){sup 2}, thus being unexpectedly large. Calculations with the {delta}K=2 coupling were also performed and turn out not to give better agreement with experiment.

Lie-Nambu and Lie-Poisson structures in linear and nonlinear quantum mechanics

International Nuclear Information System (INIS)

Czachor, M.

1996-01-01

Space of density matrices in quantum mechanics can be regarded as a Poisson manifold with the dynamics given by certain Lie-Poisson bracket corresponding to an infinite dimensional Lie algebra. The metric structure associated with this Lie algebra is given by a metric tensor which is not equivalent to the Cartan-Killing metric. The Lie-Poisson bracket can be written in a form involving a generalized (Lie-)Nambu bracket. This bracket can be used to generate a generalized, nonlinear and completely integrable dynamics of density matrices. (author)

Spin-orbit coupling induced two-electron relaxation in silicon donor pairs

Science.gov (United States)

Song, Yang; Das Sarma, S.

2017-09-01

We unravel theoretically a key intrinsic relaxation mechanism among the low-lying singlet and triplet donor-pair states in silicon, an important element in the fast-developing field of spintronics and quantum computation. Despite the perceived weak spin-orbit coupling (SOC) in Si, we find that our discovered relaxation mechanism, combined with the electron-phonon and interdonor interactions, drives the transitions in the two-electron states over a large range of donor coupling regimes. The scaling of the relaxation rate with interdonor exchange interaction J goes from J5 to J4 at the low to high temperature limits. Our analytical study draws on the symmetry analysis over combined band, donor envelope, and valley configurations. It uncovers naturally the dependence on the donor-alignment direction and triplet spin orientation, and especially on the dominant SOC source from donor impurities. While a magnetic field is not necessary for this relaxation, unlike in the single-donor spin relaxation, we discuss the crossover behavior with increasing Zeeman energy in order to facilitate comparison with experiments.

The influence of anharmonic vibrations of the core to M2-transition between low-lying states in 115Sn

International Nuclear Information System (INIS)

Sy Savane, Y.

1995-12-01

The influence of the anharmonicity of the core vibration, on the magnetic transition 11/2 - 1 → 7/2 + 1 in 115 Sn have been investigated in the frame of the quasiparticle-phonon nuclear model. The model wave function includes a ''quasiparticle + two phonons'' component. The performed numerical calculations show that those effects cannot explain the strong reduction of the M2-transition observed in the experiment. A full agreement with the experimental value is obtained with g eff s = 0.42g free s . (author). 10 refs, 2 figs, 1 tab

Radiation from silver films bombarded by low-energy electrons

International Nuclear Information System (INIS)

Chung, M.S.; Callcott, T.A.; Kretschmann, E.; Arakawa, E.T.

1980-01-01

Emission spectra from Ag films irradiated by low energy electrons (20-1500 eV) have been measured, and the results compared with theory. For relatively smooth films, two peaks in the spectra are resolved. One at 3.73 eV, the volume plasmon energy, is attributed to transition radiation and/or bremsstrahlung. The second, at about 3.60 eV, is very sensitive to surface roughness in both position and magnitude and is produced by roughness-coupled radiation from surface plasmons. For rough films, the roughness-coupled radiation dominates the emission. In addition to spectral shapes, the polarization of the radiation and its intensity as a function of electron energy were measured. The experimental results are compared with new calculations of roughness-coupled emission which account for most of our observations. They indicate that high wavevector roughness components play the dominant role in the emission process. (orig.)

Lie groups, Lie algebras, and some of their applications

CERN Document Server

Gilmore, Robert

1974-01-01

Lie group theory plays an increasingly important role in modern physical theories. Many of its calculations remain fundamentally unchanged from one field of physics to another, altering only in terms of symbols and the language. Using the theory of Lie groups as a unifying vehicle, concepts and results from several fields of physics can be expressed in an extremely economical way. With rigor and clarity, this text introduces upper-level undergraduate students to Lie group theory and its physical applications.An opening discussion of introductory concepts leads to explorations of the classical

Transition and Electron Impact Excitation Collision Rates for O III

Science.gov (United States)

Tayal, S. S.; Zatsarinny, O.

2017-12-01

Transition probabilities, electron excitation collision strengths, and rate coefficients for a large number of O III lines over a broad wavelength range, from the infrared to ultraviolet, have been reported. The collision strengths have been calculated in the close-coupling approximation using the B-spline Breit-Pauli R-matrix method. The multiconfiguration Hartree-Fock method in combination with B-spline expansions is employed for an accurate representation of the target wave functions. The close-coupling expansion contains 202 O2+ fine-structure levels of the 2{s}22{p}2,2s2{p}3, 2{p}4,2{s}22p3s,3p,3d, 4s,4p,4d,4f,5s, and 2s2{p}33s,3p,3d configurations. The effective collision strengths are obtained by averaging electron excitation collision strengths over a Maxwellian distribution of velocities at electron temperatures ranging from 100 to 100,000 K. The calculated effective collision strengths have been reported for the 20,302 transitions between all 202 fine-structure levels. There is an overall good agreement with the recent R-matrix calculations by Storey et al. for the transitions between all levels of the ground 2{s}22{p}2 configuration, but significant discrepancies have been found with Palay et al. for transitions to the 2{s}22{p}2 1 S 0 level. Line intensity ratios between the optical lines arising from the 2{s}22{p}2{}3{P}{0,1,2} - 1 D 2 transitions have been compared with other calculations and observations from the photoionized gaseous nebulae, and good agreement is found. The present calculations provide the most complete and accurate data sets, which should allow a more detailed treatment of the available measured spectra from different ground and space observatories.

Probing a molecular electronic transition by two-colour sum-frequency generation spectroscopy

International Nuclear Information System (INIS)

Humbert, C.; Dreesen, L.; Nihonyanagi, S.; Masuda, T.; Kondo, T.; Mani, A.A.; Uosaki, K.; Thiry, P.A.; Peremans, A.

2003-01-01

We demonstrate that a new emerging technique, two-colour sum-frequency generation (SFG) spectroscopy, can be used to probe the molecular electronic properties of self-assembled monolayers (SAMs). In the CH spectral range (2800-3200 cm -1 ), we show that the sum-frequency generation signal of a porphyrin alkanethiol derivative adsorbed on Pt(1 1 1) reaches a maximum intensity at ∼435 nm SFG wavelength. This wavelength corresponds to the porphyrin moiety specific π-π* molecular electronic transition which is called the Soret or B band. This resonant behaviour is not observed for 1-dodecanethiol SAMs, which are devoid of molecular electronic transition in the investigated visible spectral range

Brief introduction to Lie-admissible formulations in statistical mechanics

International Nuclear Information System (INIS)

Fronteau, J.

1981-01-01

The present article is a summary of the essential ideas and results published in previous articles, the aim here being to describe the situation in a schematic way for the benefit of non-specialists. The non-truncated Liouville theorem and equation, natural introduction of Lie-admissible formulations into statistical mechanics, the notion of a statistical quasi-particle, and transition towards the notion of fine thermodynamics are discussed

Strongly correlated electron systems and neutron scattering. Magnetism, superconductivity, structural phase transition

Energy Technology Data Exchange (ETDEWEB)

Katano, Susumu [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

1998-03-01

Neutron scattering experiments in our group on strongly correlated electron systems are reviewed Metal-insulator transitions caused by structural phase transitions in (La{sub 1-x}Sr{sub x}) MnO{sub 3}, a novel magnetic transition in the CeP compound, correlations between antiferromagnetism and superconductivity in UPd{sub 2}Al{sub 3} and so forth are discussed. Here, in this note, the phase transition of Mn-oxides was mainly described. (author)

Ab initio study of small He cluster ions Hen+, n=2, 3, 4, 5, and low-lying Rydberg states of He4

International Nuclear Information System (INIS)

Staemmler, V.

1990-01-01

SCF and CEPA calculations are applied to study the structure of small He cluster ions, He n 3 , n=2, 3, 4, 5 and some low-lying Rydberg states of He 4 . The effect of electron correlation upon the equilibrium structures and binding energies is discussed. He 3 + has a linear symmetric equilibrium geometry with a bond length of 2.35 a 0 and a binding energy D e =0.165 eV with respect to He 2 + +He (experimentally: D 0 =0.17 eV which corresponds to D e ≅0.20 eV). He 4 + is a very floppy molecular ion with several energetically very similar geometrical configurations. Our CEPA calculations yield a T-shaped form with a He 3 + centre (R e =2.35 a 0 ) and one inductively bound He atom (4.39 a 0 from the central He atom of He 3 + ) as equilibrium structure. Its binding energy with respect to He 3 + +He is 0.031 eV. A linear symmetric configuration consisting of a He 2 + centre with a bond length of 2.10 a 0 and two inductively bound He atoms (4.20 a 0 from the centre of He 2 + ) is only 0.02-0.03 eV higher in energy. We expect that in larger He cluster ions structures with He 2 + and He 3 + centres and n-2 or n-3 inductively bound He atoms have nearly the same energies. In He 4 a low-lying metastable Rydberg state ( 3 π symmetry for linear He 4 * , 3 B 1 for the T-shaped form) exists which is slightly stronger bound with respect to He 3 * +He than the corresponding ion. (orig.)

Multireference configuration interaction study on spectroscopic properties of low-lying electronic states of As2 molecule

International Nuclear Information System (INIS)

Wang Jie-Min; Liu Qiang

2013-01-01

The potential energy curves (PECs) of four electronic states (X 1 Σ g + , e 3 Δ u , a 3 Σ u − , and d 3 Π g ) of an As 2 molecule are investigated employing the complete active space self-consistent field (CASSCF) method followed by the valence internally contracted multireference configuration interaction (MRCI) approach in conjunction with the correlation-consistent aug-cc-pV5Z basis set. The effect on PECs by the relativistic correction is taken into account. The way to consider the relativistic correction is to employ the second-order Douglas-Kroll Hamiltonian approximation. The correction is made at the level of a cc-pV5Z basis set. The PECs of the electronic states involved are extrapolated to the complete basis set limit. With the PECs, the spectroscopic parameters (T e , R e , ω e , ω e x e , ω e y e , α e , β e , γ e , and B e ) of these electronic states are determined and compared in detail with those reported in the literature. Excellent agreement is found between the present results and the experimental data. The first 40 vibrational states are studied for each electronic state when the rotational quantum number J equals zero. In addition, the vibrational levels, inertial rotation and centrifugal distortion constants of d 3 Π g electronic state are reported which are in excellent agreement with the available measurements. Comparison with the experimental data shows that the present results are both reliable and accurate. (atomic and molecular physics)

Novel Structures for the Excess Electron State of the Water Hexamer and the Interaction Forces Governing the Structures

International Nuclear Information System (INIS)

Lee, S.; Kim, J.; Lee, S.J.; Kim, K.S.

1997-01-01

The geometrical and electronic structures of partially hydrated electron systems, in particular, the water hexamer, which have been controversial for decades, have been clarified by an exhaustive search for possible low-lying energy structures. Several competing interaction forces governing the conformation have been examined for the first time. The low-lying energy structures are hybrid (or partially internal and partially surface) excess electron states. Our prediction is evidenced from excellent agreements with available experimental data. The vertical electron-detachment energies are mainly determined by the number of dangling H atoms (H d ) . copyright 1997 The American Physical Society

Geographies of energy transition: Space, place and the low-carbon economy

International Nuclear Information System (INIS)

Bridge, Gavin; Bouzarovski, Stefan; Bradshaw, Michael; Eyre, Nick

2013-01-01

This paper makes a case for examining energy transition as a geographical process, involving the reconfiguration of current patterns and scales of economic and social activity. The paper draws on a seminar series on the ‘Geographies of Energy Transition: security, climate, governance' hosted by the authors between 2009 and 2011, which initiated a dialogue between energy studies and the discipline of human geography. Focussing on the UK Government's policy for a low carbon transition, the paper provides a conceptual language with which to describe and assess the geographical implications of a transition towards low carbon energy. Six concepts are introduced and explained: location, landscape, territoriality, spatial differentiation, scaling, and spatial embeddedness. Examples illustrate how the geographies of a future low-carbon economy are not yet determined and that a range of divergent – and contending – potential geographical futures are in play. More attention to the spaces and places that transition to a low-carbon economy will produce can help better understand what living in a low-carbon economy will be like. It also provides a way to help evaluate the choices and pathways available. - Highlights: ► Examines transition as a geographical process, reconfiguring patterns and scales of activity. ► Provides concepts for assessing geographical implications of transition to a low-carbon economy. ► Outlines location, landscape, territoriality, uneven development, scaling, and embeddedness.

Field-Lines-Threaded Model for: (1) the Low Solar Corona; (2) Electrons in the Transition Region; and (3) Solar Energetic Particle Acceleration and Transport

Science.gov (United States)

Sokolov, I.; van der Holst, B.; Jin, M.; Gombosi, T. I.; Taktakishvili, A.; Khazanov, G. V.

2013-12-01

In numerical simulations of the solar corona, both for the ambient state and especially for dynamical processes the most computational resources are spent for maintaining the numerical solution in the Low Solar Corona and in the transition region, where the temperature gradients are very sharp and the magnetic field has a complicated topology. The degraded computational efficiency is caused by the need in a highest resolution as well as the use of the fully three-dimensional implicit solver for electron heat conduction. On the other hand, the physical nature of the processes involved is rather simple (which still does not facilitate the numerical methods) as long as the heat fluxes as well as slow plasma motional velocities are aligned with the magnetic field. The Alfven wave turbulence, which is often believed to be the main driver of the solar wind and the main source of the coronal heating, is characterized by the Poynting flux of the waves, which is also aligned with the magnetic field. Therefore, the plasma state in any point of the three-dimensional grid in the Low Solar Corona can be found by solving a set of one-dimensional equations for the magnetic field line ('thread'), which passes through this point and connects it to the chromosphere and to the global Solar Corona. In the present paper we describe an innovative computational technology based upon the use of the magnetic-field-line-threads to find the local solution. We present the development of the AWSoM code of the University of Michigan with the field-lines-threaded Low Solar Corona. In the transition region, where the essentially kinetic description of the electron energy fluxes is required, we solve the Fokker-Plank equation on the system of threads, to achieve the physically consistent description of chromosphere evaporation. The third application for the field-lines-treaded model is the Solar Energetic Particle (SEP) acceleration and transport. Being the natural extension of the Field

Spin delocalization phase transition in a correlated electrons model

International Nuclear Information System (INIS)

Huerta, L.

1990-11-01

In a simplified one-site model for correlated electrons systems we show the existence of a phase transition corresponding to spin delocalization. The system becomes a solvable model and zero-dimensional functional techniques are used. (author). 7 refs, 3 figs

E0 transitions in {sup 106}Pd: Implications for shape coexistence

Energy Technology Data Exchange (ETDEWEB)

Peters, E.E.; Mynk, M.G. [University of Kentucky, Department of Chemistry, Lexington, KY (United States); Prados-Estevez, F.M.; Chakraborty, A.; Yates, S.W. [University of Kentucky, Department of Chemistry, Lexington, KY (United States); University of Kentucky, Department of Physics and Astronomy, Lexington, KY (United States); Bandyopadhyay, D.; Choudry, S.N.; Crider, B.P.; Kumar, A.; Lesher, S.R.; McKay, C.J.; Orce, J.N.; Scheck, M. [University of Kentucky, Department of Physics and Astronomy, Lexington, KY (United States); Garrett, P.E. [University of Guelph, Department of Physics, Guelph, Ontario (Canada); Hicks, S.F. [University of Dallas, Department of Physics, Irving, TX (United States); Vanhoy, J.R. [United States Naval Academy, Department of Physics, Annapolis, MD (United States); Wood, J.L. [Georgia Institute of Technology, School of Physics, Atlanta, GA (United States)

2016-04-15

Level lifetimes in {sup 106}Pd were measured with the Doppler-shift attenuation method following inelastic neutron scattering, and electric monopole transition strengths between low-lying 2{sup +} states were deduced. The large ρ{sup 2} (E0) values obtained provide evidence for shape coexistence, extending observation of such structures in the N = 60 isotones. Included in these results is the first determination of the E0 transition strength in the Pd nuclei between levels with K = 2. (orig.)

Three-particle recombination at low temperature: QED approach

International Nuclear Information System (INIS)

Bhattacharyya, S.; Roy, A.

2001-01-01

A theoretical study of three-body recombination of proton in presence of a spectator electron with electronic beam at near-zero temperature is presented using field theory and invariant Lorentz gauge. Contributions from the Feynman diagrams of different orders give an insight into the physics of the phenomena. Recombination rate coefficient is obtained for low lying principal quantum number n = 1 to 10. At a fixed ion beam temperature (300 K) recombination rate coefficient is found to increase in general with n, having a flat and a sharp peak at quantum states 3 to 5, respectively. In absence of any theoretical and experimental results for low temperature formation of H-atom by three-body recombination at low lying quantum states, we have presented the theoretical results of Stevefelt and group for three-body recombination of deuteron with electron along with the present results. Three-body recombination of antihydrogen in antiproton-positron plasma is expected to yield similar result as that for three-body recombination of hydrogen formation in proton-electron plasma. The necessity for experimental investigation of low temperature three-body recombination at low quantum states is stressed. (author)

Model of electron capture in low-temperature glasses

International Nuclear Information System (INIS)

Bartczak, W.M.; Swiatla, D.; Kroh, J.

1983-01-01

The new model of electron capture by a statistical variety of traps in glassy matrices is proposed. The electron capture is interpreted as the radiationless transition (assisted by multiphonon emission) of the mobile electron to the localized state in the trap. The conception of 'unfair' and 'fair' traps is introduced. The 'unfair' trap captures the mobile electron by the shallow excited state. In contrast, the 'fair' trap captures the electron by the ground state. The model calculations of the statistical distributions of the occupied electron traps are presented and discussed with respect to experimental results. (author)

Measurement of peripheral electron temperature by electron cyclotron emission during the H-mode transition in JFT-2M tokamak

International Nuclear Information System (INIS)

Hoshino, Katsumichi; Yamamoto, Takumi; Kawashima, Hisato

1987-01-01

Time evolution and profile of peripheral electron temperature during the H-mode like transition in a tokamak plasma is measured using the second and third harmonic of electron cyclotron emission (ECE). The so called ''H-mode'' state which has good particle/energy confinement is characterized by sudden decrease in the spectral line intensity of deuterium molecule. Such a sudden decrease in the line intensity of D α with good energy confinement is found not only in divertor discharges, but also in limiter dischargs in JFT-2M tokamak. It is found by the measurement of ECE that the peripheral electron temperature suddenly increases in both of such phases. The relation between H-transition and the peripheral electron temperature or its profile is investigated. (author)

Far infrared spectroscopy of solids. I. Impurity states in Al2O3. II. Electron-hole droplets in Ge

International Nuclear Information System (INIS)

Aurbauch, R.L.

1975-01-01

Far infrared Fourier transform spectroscopy was used to study the low lying vibronic states of Mn 3+ in Al 2 O 3 and the plasma absorption of electron-hole droplets in Ge. The transmission of Mn-doped samples of Al 2 O 3 was measured in the frequency range from 3 to 30 cm -1 in applied magnetic fields up to 50 kG. Absorption lines were observed due to both ground and excited state transitions. Polarization measurements established that these absorption lines were due to electric dipole transitions. Temperature dependence measurements were used to derive a level diagram for the low lying states of Mn 3+ . A phenomenological model based on an electronic Hamiltonian was developed which successfully describes the data. The empirically determined trigonal field and spin-orbit quenching parameters of this model are 0.7 and 0.1 respectively. This quenching is attributed to the dynamic Jahn--Teller interaction. The plasma absorption of small (α) electron-hole drops in Ge was measured in the frequency range from 30 to 300 cm -1 . The observed absorption is in good agreement with measurements by Vavilov and other workers. A theoretical model which includes both intraband and interband contributions to the dielectric constant in the Rayleigh limit of Mie theory is used to describe the observed lineshape. Measurements of plasma absorption of large (γ) drops in inhomogeneously stressed Ge were made in magnetic fields up to 50 kG. The lineshape at zero applied field was calculated in the large sphere limit of Mie theory including intraband terms and a zero-strain interband term. Qualitative agreement with experiment was obtained. The peak absorption shifted quadratically with applied magnetic field and the total plasma absorption increased. No oscillatory structure was observed in the field-dependence of the total absorption

Low lying electric dipole excitations in nuclei of the rare earth region

International Nuclear Information System (INIS)

von Brentano, P.; Zilges, A.; Herzberg, R.D.; Kneissl, U.; Heil, R.D.; Pitz, H.H.; Wesselborg, C.

1992-01-01

From many experiments with low energy photon scattering on deformed rare earth nuclei we have obtained detailed information about the distribution of electric dipole strength below 4 MeV. Apart from some weaker transitions between 2 and 4 MeV we observed one, and sometimes two, very strong El-groundstate transitions around 1.5 MeV in all examined nuclei. They arise from the de-excitation of the bandheads of the (J π ,K)=(l - ,0) and (J π ,K)=(l - ,1) octupole vibrational bands. It is shown that the decay branching ratios and the absolute transition strengths of these states can be reproduced rather well with an improved T(El)-operator in the sdf-Interacting Boson Model. Another class of octupole states has been investigated in the region of the semimagic nucleus 142 Nd. Here a quintuplet of collective excitations around 3.5 MeV is expected due to the coupling of the 3--octupole vibration with the 2+-quadrupole vibration. We performed photon scattering experiments on the odd A neighboring nucleus 141 Pr and found first evidence for the existence of 3 - times 2+circle-times particle-states

Electron paramagnetic resonance of transition ions

CERN Document Server

Abragam, Anatole

1970-01-01

This book is a reissue of a classic Oxford text, and provides a comprehensive treatment of electron paramagnetic resonance of ions of the transition groups. The emphasis is on basic principles, with numerous references to publications containing further experimental results and more detailed developments of the theory. An introductory survey gives a general understanding, and a general survey presents such topics as the classical and quantum resonance equations, thespin-Hamiltonian, Endor, spin-spin and spin-lattice interactions, together with an outline of the known behaviour of ions of each

Electronic states and nature of bonding of the molecule PdGe by all electron ab initio HF–CI calculations and mass spectrometric equilibrium experiments

DEFF Research Database (Denmark)

Shim, Irene; Kingcade, Joseph E. , Jr.; Gingerich, Karl A.

1986-01-01

In the present work we present all-electron ab initio Hartree–Fock (HF) and configuration interaction (CI) calculations of six electronic states of the PdGe molecule. The molecule is predicted to have a 3Pi ground state and two low-lying excited states 3Sigma− and 1Sigma+. The electronic structure...

Lectures on Lie groups

CERN Document Server

Hsiang, Wu-Yi

2017-01-01

This volume consists of nine lectures on selected topics of Lie group theory. We provide the readers a concise introduction as well as a comprehensive 'tour of revisiting' the remarkable achievements of S Lie, W Killing, É Cartan and H Weyl on structural and classification theory of semi-simple Lie groups, Lie algebras and their representations; and also the wonderful duet of Cartans' theory on Lie groups and symmetric spaces.With the benefit of retrospective hindsight, mainly inspired by the outstanding contribution of H Weyl in the special case of compact connected Lie groups, we develop the above theory via a route quite different from the original methods engaged by most other books.We begin our revisiting with the compact theory which is much simpler than that of the general semi-simple Lie theory; mainly due to the well fittings between the Frobenius-Schur character theory and the maximal tori theorem of É Cartan together with Weyl's reduction (cf. Lectures 1-4). It is a wonderful reality of the Lie t...

MgH Rydberg series: Transition energies from electron propagator theory and oscillator strengths from the molecular quantum defect orbital method

Science.gov (United States)

Corzo, H. H.; Velasco, A. M.; Lavín, C.; Ortiz, J. V.

2018-02-01

Vertical excitation energies belonging to several Rydberg series of MgH have been inferred from 3+ electron-propagator calculations of the electron affinities of MgH+ and are in close agreement with experiment. Many electronically excited states with n > 3 are reported for the first time and new insight is given on the assignment of several Rydberg series. Valence and Rydberg excited states of MgH are distinguished respectively by high and low pole strengths corresponding to Dyson orbitals of electron attachment to the cation. By applying the Molecular Quantum Defect Orbital method, oscillator strengths for electronic transitions involving Rydberg states also have been determined.

Positron annihilation and pressure-induced electronic s-d transition

International Nuclear Information System (INIS)

McMahan, A.K.; Skriver, H.L.

1985-06-01

The polycrystalline, partial annihilation rates for positrons in compressed cesium have been calculated using the linear muffin-tin orbitals method. These results suggest that the pressure-induced electronic s-d transition in Cs should be directly observable by momentum sensitive positron annihilation experiments

Low-temperature transitions in cod and tuna determined by differential scanning calorimetry

DEFF Research Database (Denmark)

Jensen, Kristina Nedenskov; Jørgensen, Bo; Nielsen, Jette

2003-01-01

Differential scanning calorimetry measurements have revealed different thermal transitions in cod and tuna samples. Transition temperatures detected Lit -11degreesC, -15degreesC and -21degreesC were highly dependent on the annealing temperature. In tuna muscle an additional transition was observed...... at -72degreesC. This transition appeared differently than the thermal events observed at higher temperatures, as it spanned a broad temperature interval of 25degreesC. The transition was comparable to low-temperature glass transitions reported in protein-rich systems. No transition at this low...... temperature was detected in cod samples. The transitions observed at higher temperatures (-11degreesC to -21degreesC) may possibly stein from a glassy matrix containing muscle proteins. However, the presence of a glass transition at - 11degreesC was in disagreement with the low storage stability at -18degrees...

Transitions and transition management. The case of an emission-low energy supply

International Nuclear Information System (INIS)

Rotmans, J.; Van Asselt, M.; Molendijk, K.; Kemp, R.; Geels, F.; Verbong, G.

2000-12-01

Transitions are societal transformation processes that occur in at least one generation (i.e. 25 years). Transitions are structural changes of the society or a complex part of that society. Transitions show technological, economical, ecological, socio-cultural and institutional developments on different levels. A transition is the result of slow changes (developments in supplies) and fast dynamics (flows). In general, four transition phases can be distinguished: (1) a pre-development phase of dynamic equilibrium in which the status quo does not change much; (2) a take-off phase in which the process of change is started; (3) an acceleration phase in which structural changes occur, resulting in collective learning processes, diffusion and processes of implementation; (4) a stabilization phase in which the speed of societal changes decreases and a new dynamic equilibrium exists. Within the framework of the preparatory process of the Fourth Dutch National Environmental Plan (NMP4) a study has been carried out to explore the transition concept, focusing on an emission-low energy supply in the Netherlands. 49 refs

Low-lying baryon spectrum with two dynamical twisted mass fermions

Energy Technology Data Exchange (ETDEWEB)

Alexandrou, C. [Cyprus Univ., Nicosia (Cyprus). Dept. of Physics; Computation-based Science and Technology Research Center, Cyprus Institute, Nicosia (Cyprus); Baron, R.; Guichon, P. [CEA-Saclay, IRFU/Service de Physique Nucleaire, Gif-sur-Yvette (France); Carbonell, J.; Drach, V. [UJF/CNRS/IN2P3, Grenoble (France). Lab. de Physique Subatomique et Cosmologie; Jansen, K. [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany). John von Neumann-Inst. fuer Computing NIC; Korzec, T. [Cyprus Univ., Nicosia (Cyprus). Dept. of Physics; Pene, O. [Paris-11 Univ., 91 - Orsay (France). Lab. de Physique Theorique

2009-10-15

The masses of the low lying baryons are evaluated using two degenerate flavors of twisted mass sea quarks corresponding to pseudo scalar masses in the range of about 270 MeV to 500 MeV. The strange valence quark mass is tuned to reproduce the mass of the kaon in the physical limit. The tree-level Symanzik improved gauge action is employed. We use lattices of spatial size 2.1 fm and 2.7 fm at two values of the lattice spacing with r{sub 0}/a=5.22(2) and r{sub 0}/a=6.61(3). We check for both finite volume and cut-off effects on the baryon masses. We performed a detailed study of the chiral extrapolation of the octet and decuplet masses using SU(2) {chi}PT. The lattice spacings determined using the nucleon mass at the physical point are consistent with the values extracted using the pion decay constant. We examine the issue of isospin symmetry breaking for the octet and decuplet baryons and its dependence on the lattice spacing. We show that in the continuum limit isospin breaking is consistent with zero, as expected. The baryon masses that we find after taking the continuum limit and extrapolating to the physical limit are in good agreement with experiment. (orig.)

Nanolines of transition metals ruled by grain boundaries in graphene: An ab initio study

Energy Technology Data Exchange (ETDEWEB)

Lima, F.D.C. de, E-mail: felipe.lima@ufu.br; Miwa, R.H., E-mail: hiroki@infis.ufu.br

2017-06-15

We have performed an ab initio investigation of the energetic stability, and the electronic properties of transition metals (TMs = Mn, Fe, Co, and Ru) adsorbed on graphene, upon the presence of grain boundaries (GBs); where we found an energetic preference for the TMs lying on the GB sites (TM/GB). Further energy barrier calculations, of the transition metals in TM/GB, reveal that the GBs promote the formation of energetically favorable diffusion channels on graphene. By increasing the concentration of the TM adatoms, the energetic stability of the TM/GB systems has been strengthened; giving rise to TM nanolines (TM-NLs). The electronic properties of those TM-NLs were characterized through extensive electronic band structure calculations, where the energy bands of the TM/GB systems indicate the appearance of an anisotropic spin-polarized electronic current along the TM-NLs on graphene. - Highlights: • Formation of transition metal (TM) nanolines on graphene ruled by extended defects. • Those extended defects give rise to diffusion pipes of TMs on graphene. • The electronic band structure calculations indicate the formation of spin-polarized current upon the presence of TM nanolines. • The formation of those TM nanolines support the recent experimental findings.

Electron scattering from 36Ar and 40Ar

International Nuclear Information System (INIS)

Finn, J.M.

1975-01-01

The argon isotopes, 36 Ar and 40 Ar, have been investigated using electron scattering at the high-resolution Linac facilities of the National Bureau of Standards. Both elastic scattering and scattering to low-lying states have been observed. A high-pressure, low-volume gas target cell was designed and developed for this experiment. The cell features a transmission geometry and has resolution comparable to solid targets. Spectra were obtained at incident beam energies ranging from 65 to 115 MeV at scattering angles of 92.5 0 and 110 0 . Values obtained for the rms charge radii are 3.327 +- 0.015 and 3.393 +- 0.015 fm for 36 Ar and 40 Ar respectively. A sensitive measurement was made of the difference in the two radii yielding a value of Δ r = 0.079 +- 0.006 fm. The inelastic levels observed are the 1.97 (2 + ) and 4.18 MeV (3 - ) levels in 36 Ar, and the 1.46 (2 + ), 2.52 (2 + ), 3.21 (2 + ), and 3.68 MeV (3 - ) levels in 40 Ar. A Tassie model analysis was made of the inelastic transitions in the DWBA approximation and transition strengths of these levels were extracted

Electron-doping by hydrogen in transition-metal dichalcogenides

Science.gov (United States)

Oh, Sehoon; Im, Seongil; Choi, Hyoung Joon

Using first-principles calculations, we investigate the atomic and electronic structures of 2H-phase transition-metal dichalcogenides (TMDC), 2H-MX2, with and without defects, where M is Mo or W and X is S, Se or Te. We find that doping of atomic hydrogen on 2H-MX2 induces electron doping in the conduction band. To understand the mechanism of this electron doping, we analyze the electronic structures with and without impurities. We also calculate the diffusion energy barrier to discuss the spatial stability of the doping. Based on these results, we suggest a possible way to fabricate elaborately-patterned circuits by modulating the carrier type of 2H-MoTe2. We also discuss possible applications of this doping in designing nano-devices. This work was supported by NRF of Korea (Grant No. 2011-0018306) and KISTI supercomputing center (Project No. KSC-2016-C3-0052).

Suppression of the Transit -Time Instability in Large-Area Electron Beam Diodes

Science.gov (United States)

Myers, Matthew C.; Friedman, Moshe; Swanekamp, Stephen B.; Chan, Lop-Yung; Ludeking, Larry; Sethian, John D.

2002-12-01

Experiment, theory, and simulation have shown that large-area electron-beam diodes are susceptible to the transit-time instability. The instability modulates the electron beam spatially and temporally, producing a wide spread in electron energy and momentum distributions. The result is gross inefficiency in beam generation and propagation. Simulations indicate that a periodic, slotted cathode structure that is loaded with resistive elements may be used to eliminate the instability. Such a cathode has been fielded on one of the two opposing 60 cm × 200 cm diodes on the NIKE KrF laser at the Naval Research Laboratory. These diodes typically deliver 600 kV, 500 kA, 250 ns electron beams to the laser cell in an external magnetic field of 0.2 T. We conclude that the slotted cathode suppressed the transit-time instability such that the RF power was reduced by a factor of 9 and that electron transmission efficiency into the laser gas was improved by more than 50%.

Suppression of the transit-time instability in large-area electron beam diodes

International Nuclear Information System (INIS)

Myers, Matthew C.; Friedman, Moshe; Sethian, John D.; Swanekamp, Stephen B.; Chan, L.-Y.; Ludeking, Larry

2002-01-01

Experiment, theory, and simulation have shown that large-area electron-beam diodes are susceptible to the transit-time instability. The instability modulates the electron beam spatially and temporally, producing a wide spread in electron energy and momentum distributions. The result is gross inefficiency in beam generation and propagation. Simulations indicate that a periodic, slotted cathode structure that is loaded with resistive elements may be used to eliminate the instability. Such a cathode has been fielded on one of the two opposing 60 cm x 200 cm diodes on the NIKE KrF laser at the Naval Research Laboratory. These diodes typically deliver 600 kV, 500 kA, 250 ns electron beams to the laser cell in an external magnetic field of 0.2 T. We conclude that the slotted cathode suppressed the transit-time instability such that the RF power was reduced by a factor of 9 and that electron transmission efficiency into the laser gas was improved by more than 50%

Blackbody radiation shift of the Ga+ clock transition

International Nuclear Information System (INIS)

Cheng, Yongjun; Mitroy, J

2013-01-01

The blackbody radiation shift of the Ga + clock transition is computed to be −0.0140 ± 0.0062 Hz at 300 K. The small shift is consistent with the blackbody radiation shifts of the clock transitions of other group III ions which are of a similar size. The polarizabilities of the Ga + states were computed using the configuration interaction method with an underlying semi-empirical core potential. Quadrupole and non-adiabatic dipole polarizabilities were also computed. A byproduct of the analysis involved calculations of the low-lying spectrum and oscillator strengths, including polarizabilities, of the Ga 2+ ion. (paper)

Upper ocean stratification and sea ice growth rates during the summer-fall transition, as revealed by Elephant seal foraging in the Adélie Depression, East Antarctica

Directory of Open Access Journals (Sweden)

G. D. Williams

2011-03-01

Full Text Available Southern elephant seals (Mirounga leonina, fitted with Conductivity-Temperature-Depth sensors at Macquarie Island in January 2005 and 2010, collected unique oceanographic observations of the Adélie and George V Land continental shelf (140–148° E during the summer-fall transition (late February through April. This is a key region of dense shelf water formation from enhanced sea ice growth/brine rejection in the local coastal polynyas. In 2005, two seals occupied the continental shelf break near the grounded icebergs at the northern end of the Mertz Glacier Tongue for several weeks from the end of February. One of the seals migrated west to the Dibble Ice Tongue, apparently utilising the Antarctic Slope Front current near the continental shelf break. In 2010, immediately after that year's calving of the Mertz Glacier Tongue, two seals migrated to the same region but penetrated much further southwest across the Adélie Depression and sampled the Commonwealth Bay polynya from March through April. Here we present observations of the regional oceanography during the summer-fall transition, in particular (i the zonal distribution of modified Circumpolar Deep Water exchange across the shelf break, (ii the upper ocean stratification across the Adélie Depression, including alongside iceberg C-28 that calved from the Mertz Glacier and (iii the convective overturning of the deep remnant seasonal mixed layer in Commonwealth Bay from sea ice growth. Heat and freshwater budgets to 200–300 m are used to estimate the ocean heat content (400→50 MJ m⁻², flux (50–200 W m⁻² loss and sea ice growth rates (maximum of 7.5–12.5 cm day⁻¹. Mean seal-derived sea ice growth rates were within the range of satellite-derived estimates from 1992–2007 using ERA-Interim data. We speculate that the continuous foraging by the seals within Commonwealth Bay during the summer/fall transition was due to favorable feeding

77 FR 47692 - Notice of Transportation Services' Transition From Paper to Electronic Fare Media Comments...

Science.gov (United States)

2012-08-09

... and effective electronic fare media transition to its participating transit benefit agencies... New Program Distribution Methodology for Transit Benefits This section presents a summary of the..., 2012 on TRANServe's adoption of a new program distribution methodology for transit benefits and...

The low-lying πσ* state and its role in the intramolecular charge transfer of aminobenzonitriles and aminobenzethyne

International Nuclear Information System (INIS)

Lee, Jae-Kwang; Fujiwara, Takashige; Kofron, William G.; Zgierski, Marek Z.; Lim, Edward C.

2008-01-01

Electronic absorption spectra of the low-lying ππ* and πσ* states of several aminobenzonitriles and 4-dimethylaminobenzethyne have been studied by time-resolved transient absorption and time-dependent density functional theory calculation. In acetonitrile, the lifetime of the πσ*-state absorption is very short (picoseconds or subpicosecond) for molecules that exhibit intramolecular charge transfer (ICT), and very long (nanoseconds) for those that do not. Where direct comparison of the temporal characteristics of the πσ*-state and the ICT-state transients could be made, the formation rate of the ICT state is identical to the decay rate of the πσ* state within the experimental uncertainty. These results are consistent with the πσ*-mediated ICT mechanism, L a (ππ*)→πσ*→ICT, in which the decay rate of the πσ* state is determined by the rate of the solvent-controlled πσ*→ICT charge-shift reaction. The ππ*→πσ* state crossing does not occur in 3-dimethylaminobenzonitrile or 2-dimethylaminobenzonitrile, as predicted by the calculation, and 4-aminobenzonitrile and 4-dimethylaminobenzethyne does not exhibit the ICT reaction, consistent with the higher energy of the ICT state relative to the πσ* state

Ultrafast Hot Electron Induced Phase Transitions in Vanadium Dioxide

Directory of Open Access Journals (Sweden)

Haglund R. F.

2013-03-01

Full Text Available The Au/Cr/VO2/Si system was investigated in pump–probe experiments. Hot-electrons generated in the Au were found to penetrate into the underlying VO2 and couple with its lattice inducing a semiconductor-to-metal phase transition in ~2 picoseconds.

Triggering of 178Hfm2 by photoinduced electron transition

Directory of Open Access Journals (Sweden)

A. Ya. Dzyublik

2013-03-01

Full Text Available We considered the NEET (nuclear excitation by electron transition as a possible triggering mechanism of the isomer 178Hfm2 during ionization of the L3 atomic shell by x-rays. This isomer is assumed to be excited into an intermediate state by E1 electronic transition between M5 and L3 shells. Simple nonrelativistic formulas are derived for the NEET probability. The estimations show the probability to be less than the experimental data of [1] by one order of magnitude. The intermediate level is found to decay bypassing the isomeric level 16+, if the nucleus attributes a triaxial shape in the state and, besides, there exists a level 13- shifted with respect to 15- by 400 keV. We have shown also that the NEET cross section as a function of the energy of x-ray photons , has to accept constant value above the L photoionization threshold in contrast to narrow peak observed by [1].

Electron beam bunch length characterizations using incoherent and coherent transition radiation on the APS SASE FEL project

CERN Document Server

Lumpkin, Alex H; Berg, W J; Lewellen, J W; Sereno, N S; Happek, U

2000-01-01

The Advanced Photon Source (APS) injector linac has been reconfigured with a low-emittance RF thermionic gun and a photocathode (PC) RF gun to support self-amplified spontaneous emission (SASE) free-electron laser (FEL) experiments. One of the most critical parameters for optimizing SASE performance (gain length) is the electron beam peak current, which requires a charge measurement and a bunch length measurement capability. We report here initial measurements of the latter using both incoherent optical transition radiation (OTR) and coherent transition radiation (CTR). A visible light Hamamatsu C5680 synchroscan streak camera was used to measure the thermionic RF gun beam's bunch length (sigma approx 2-3 ps) via OTR generated by the beam at 220 MeV and 200 mA macropulse average current. In addition, a CTR monitor (Michelson Interferometer) based on a Golay cell as the far-infrared (FIR) detector has been installed at the 40-MeV station in the beamline. Initial observations of CTR signal strength variation wi...

Tracing the transition of a macro electron shuttle into nonlinear response

Energy Technology Data Exchange (ETDEWEB)

Kim, Chulki [Sensor System Research Center, Korea Institute of Science and Technology, Seoul 136791 (Korea, Republic of); Prada, Marta [I. Institut für Theoretische Physik, Universität Hamburg, Jungiusstr. 9, Hamburg 20355 (Germany); Qin, Hua [Key Laboratory of Nanodevices, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, 398 Ruoshui Road, Industrial Park, Suzhou City, Jiangsu 215123 (China); Kim, Hyun-Seok [Division of Electronics and Electrical Engineering, Dongguk University-Seoul, 100715 Seoul (Korea, Republic of); Blick, Robert H., E-mail: rblick@physnet.uni-hamburg.de [Department of Physics, University of Wisconsin-Madison, 1150 University Avenue, Madison, Wisconsin-53706 (United States); Center for Hybrid Nanostructures, Universität Hamburg, Jungiusstr. 11c, Hamburg 20355 (Germany); Department of Electrical and Computer Engineering, University of Wisconsin-Madison, 1415 Engineering Dr. Madison, Wisconsin-53706 (United States)

2015-02-09

We present a study on a macroscopic electron shuttle in the transition from linear to nonlinear response. The shuttle consists of a classical mechanical pendulum situated between two capacitor plates. The metallic pendulum enables mechanical transfer of electrons between the plates, hence allowing to directly trace electron shuttling in the time domain. By applying a high voltage to the plates, we drive the system into a controlled nonlinear response, where we observe period doubling.

Lying in business : Insights from Hanna Arendt's 'Lying in Politics'

NARCIS (Netherlands)

Eenkhoorn, P.; Graafland, J.J.

2011-01-01

The political philosopher Hannah Arendt develops several arguments regarding why truthfulness cannot be counted among the political virtues. This article shows that similar arguments apply to lying in business. Based on Hannah Arendt's theory, we distinguish five reasons why lying is a structural

Electron-nuclear γ transition spectrum of a nucleus in a multicharged atomic ion

International Nuclear Information System (INIS)

Ivanov, L.N.; Letokhov, V.S.

1987-01-01

The nuclear emission of absorption spectrum of an atom possesses a set of electron satelites which are due to an alternation of the state of the electron shell. It is shown that the mechanism of formation of the satellites might be different for neutral atoms and high-charge ions. In the first case (loose electron shell) a ''shaking'' of the shell resulting from the interaction between the nucleus and γ quantum is predominant. In the second case (rigid electron shell) the mechanism involves a direct interaction between the γ quantum and electrons. The second mechanism is important in the case of dipole nuclear transitions and dominates at γ quantum energies p 2λ (λ is the nuclear transition multipole order, μ p ∼ 1/2 π is the relative proton mass and z the core mass). In the spectrum of the plasma source the electron satellites corresponding to the γ quantum emission and absorption lines are not overlapped by the Doppler contour of the γ line

Systematics on the low-lying spectra in N = 78 ~ 80 isotones

International Nuclear Information System (INIS)

Cheng, Y.Y.; Zhang, S.Q.; Li, X.Q.

2014-01-01

Combining the new spectroscopy results of 144 Tb and previous spectroscopy studies of neighboring nuclei, a systematic investigation on the low-lying spectra in N = 78 ~ 80 isotones is performed. Good systematics have been found for the coupling patterns which couple the odd nucleon(s), such as πh 11/2 , νh 11/2 —1 , νh 11/2 2 , νh 11/2 —2 , νh 11/2 —1 , to the 2 + , 4 + , 6 + and 3 - core excitations. It is found that the relative excitation energies of the states formed by coupling h 11/2 proton(s) to the 2 + , 4 + core excitations are pushed up, in contrast with those formed by coupling h 11/2 neutron hole(s) to the 2 + , 4 + core excitations, which are pulled down. According to the systematics, the interpretation that the 17/2 + states observed in 141 Sm and 143 Gd are the fully aligned member of coupling the odd h 11/2 neutron hole to the octupole 3 - core excitation, is explored to the isotones 145 Dy, 142 Eu, and 144 Tb. (author)

Politicians lie, so do I.

Science.gov (United States)

Celse, Jérémy; Chang, Kirk

2017-11-30

This research analyzed whether political leaders make people lie via priming experiments. Priming is a non-conscious and implicit memory effect in which exposure to one stimulus affects the response to another. Following priming theories, we proposed an innovative concept that people who perceive leaders to be dishonest (such as liars) are likely to lie themselves. We designed three experiments to analyze and critically discussed the potential influence of prime effect on lying behavior, through the prime effect of French political leaders (including general politicians, presidents and parties). Experiment 1 discovered that participants with non-politician-prime were less likely to lie (compared to politician-prime). Experiment 2A discovered that, compared to Hollande-prime, Sarkozy-prime led to lying behavior both in gravity (i.e., bigger lies) and frequency (i.e., lying more frequently). Experiment 2B discovered that Republicans-prime yielded an impact on more lying behavior, and Sarkozy-prime made such impact even stronger. Overall, the research findings suggest that lying can be triggered by external influencers such as leaders, presidents and politicians in the organizations. Our findings have provided valuable insights into organizational leaders and managers in their personnel management practice, especially in the intervention of lying behavior. Our findings also have offered new insights to explain non-conscious lying behavior.

Structure of ground status in magic nuclei and description of their electric transition probabilities

International Nuclear Information System (INIS)

Savane, Y.Sy.

1996-11-01

The structure of the low-lying states in the even-even semi-magic nuclei ( 106-114 50 Sn) and the reduced transition probabilities B(E2, 6 + 1 → 4 = 1 ) for E2-transition have been investigated in the frame of the quasiparticle-phonon nuclear model. The model wave function includes a quasiparticle + two phonons components. It is shown that the small values of the transitions are connected with the non collective structure of the states. The calculated values are in agreement with the observed property of decreasing of the transition with increasing of mass number. (author). 16 refs, 6 tabs

Variation of kinetic energy release with temperature and electron energy for unimolecular ionic transitions

International Nuclear Information System (INIS)

Rabia, M.A.; Fahmy, M.A.

1992-01-01

The kinetic energy released during seven unimolecular ionic transitions, generated from benzyl alcohol and benzyl amine have been studied as a function of ion source temperature and ionizing electron energy. Only, the kinetic energy released during H CN elimination from fragment [C 7 H 8 N]+ ion of benzyl amine displays a temperature dependence. For only two transitions, generated from benzyl alcohol, the kinetic energy released show a significant ionizing electron energy dependence. These results may reveal the role of the internal energy of reacting ions in producing the kinetic energy released some transitions produced from benzyl alcohol

Recombinational laser employing electron transitions of diatomic molecules

Energy Technology Data Exchange (ETDEWEB)

Biriukov, A S; Prokhorov, A M; Shelepin, L A; Shirokov, N N

1974-12-01

Conditions are established for obtaining laser action in the visible and uv regions of the spectrum, using transitions between electronic states of diatomic molecules during recombination of a dissociated gas. The mechanism of population inversion was studied for the oxygen molecule, and gain estimates were obtained for laser action at a wavelength of 4881 A. The feasibility of laser action at other wavelengths was examined.

Decay modes of high-lying single-particle states in [sup 209]Pb

Energy Technology Data Exchange (ETDEWEB)

Beaumel, D.; Fortier, S.; Gales, S.; Guillot, J.; Langevin-Joliot, H.; Laurent, H.; Maison, J.M.; Vernotte, J.; Bordewijk, J.A.; Brandenburg, S.; Krasznahorkay, A.; Crawley, G.M.; Massolo, C.P.; Renteria, M. (Institut de Physique Nucleaire, Institut National de Physique Nucleaire et de Physique des Particules Centre National de la Recherche Scientifique, 91406 Orsay Cedex (France) Kernfysisch Versneller Instituut, 9747AA Groningen (Netherlands) National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States) Departamento de Fisica, Fac. Cs. Exactas, Universidad Nacional de La Plata, CC No. 67, 1900 La Plata (Argentina))

1994-05-01

The neutron decay of high-lying single-particle states in [sup 209]Pb excited by means of the ([alpha],[sup 3]He) reaction has been investigated at 122 MeV incident energy using a multidetector array. The high spin values of these states, inferred from previous inclusive experiments, are confirmed by the present data involving angular correlation measurements and the determination of branching ratios to low lying levels in [sup 208]Pb. The structure located between 8.5 and 12 MeV excitation energy in [sup 209]Pb displays large departures from a pure statistical decay with significant direct feeding of the low-lying collective states (3[sup [minus

Soft-mode transition in the ferroelastic crystal K2Hg(CN)4

International Nuclear Information System (INIS)

Powell, B.M.; Gerlach, P.N.

1989-01-01

Inelastic neutron scattering techniques have been used to investigate the structural transition from the paraelastic to the ferroelastic phase in K 2 Hg(CN) 4 . Several low-frequency phonon branches were measured along the high-symmetry directions and found to be almost independent of temperature. However, a particular low-lying branch along [111] was found to show a strong temperature dependence. The structure factor for this mode shows it to be a longitudinal, librational mode whose eigenvector specifies antiphase rotation of adjacent rigid cyanotetrahedra. This is in agreement with the change in the crystal structure observed at the transition by diffraction measurements. The frequency of this branch at the zone- boundary L point tended to zero at ∼101 K, thus showing the paraelastic to ferroelastic transition in this cyanospinel is a soft-mode transition. (author)

Electronic and thermodynamic properties of the transition between metallic and nonmetallic states in dense media

International Nuclear Information System (INIS)

Fortin, Xavier

1971-01-01

The effects of thermal excitation are introduced in the study of a simple electronic structure model for condensed media. The choice of a particle-interaction potential leads to a self-consistent calculation performed on a computer. This calculation gives a metal - nonmetal transition similar to the MOTT transition. We consider the effects of temperature and density variations upon this transition. It is possible to make use of this electronic structure to obtain the thermodynamic properties near the transition: pressure, free energy, sound velocity. The numerical results of this simple model are satisfactory. Particularly, if a dielectric constant is taken into account, the transition temperature and density are of the same order of magnitude as those observed experimentally in semiconductors. (author) [fr

A Solvable Model for Nuclear Shape Phase Transitions

International Nuclear Information System (INIS)

Levai, G.; Arias, J. M.

2009-01-01

There has been considerable interest recently in phase transitions that occur between some well-defined nuclear shapes, e.g. the spherical vibrator, the axially deformed rotor and the γ-unstable rotor, which are assigned to the U(5), SU(3) and 0(6) symmetries. These shape phase transitions occur through critical points of the IBM phase diagram and correspond to rapid structural changes. The first transition of this type describes transition form the spherical to the γ-unstable phase and has been associated with an E(5) symmetry. Later further critical point symmetries e.g. X(5) and Y(5) have also been proposed for transitions between other nuclear shape phases. In another application the chain of even Ru isotopes was considered from A 98 to 112 [2]. The parameters were extracted from a fit to the low-lying energy spectrum of each nucleus and were used to plot the corresponding potential. It was found that up to A =102 the potential is essentially an harmonic oscillator, while at A =104 a rather flat potential was seen, in accordance with the expected phase transition and E(5) symmetry there. With increasing A then the minimum got increasingly deeper and moved away from β = 0. We discuss the possibility of generalizing the formalism in two ways: first by including dependence on the 7 variable allowing for the approximate description of nuclei close to the X(5) symmetry, and second, including higher-lying energy levels in the quasi-exactly solvable formalism

High-resolution electron collision spectroscopy with multicharged ions in merged beams

Energy Technology Data Exchange (ETDEWEB)

Lestinsky, M.

2007-04-18

The Heidelberg ion storage ring Tsr is currently the only ring equipped with two independent devices for the collinear merging of a cold electron beam with stored ions. This greatly improves the potential of electron-ion collision experiments, as the ion beam can be cooled with one electron beam, while the other one is used as a dedicated target for energy-resolved electron collision processes, such as recombination. The work describes the implementation of this system for rst electron collision spectroscopy experiments. A detection system has been realized including an ion detector and specroscopic beam-control software and instrumentation. Moreover, in order to improve the spectroscopic resolution systematical studies of intrinsic relaxation processes in the electron beam have been carried out. These include the dependence on the electron beam density, the magnetic guiding eld strength, and the acceleration geometry. The recombination measurements on low-lying resonances in lithiumlike Sc{sup 18+} yield a high-precision measurement of the 2s-2p{sub 3/2} transition energy in this system. Operation of the two-electron-beam setup at high collision energy ({approx}1000 eV) is established using resonances of hydrogenlike Mg{sup 11+}, while the unique possibility of modifying the beam-merging geometry con rms its importance for the electron-ion recombination rate at lowest relative energy, as demonstrated on F{sup 6+}. (orig.)

High-resolution electron collision spectroscopy with multicharged ions in merged beams

International Nuclear Information System (INIS)

Lestinsky, M.

2007-01-01

The Heidelberg ion storage ring Tsr is currently the only ring equipped with two independent devices for the collinear merging of a cold electron beam with stored ions. This greatly improves the potential of electron-ion collision experiments, as the ion beam can be cooled with one electron beam, while the other one is used as a dedicated target for energy-resolved electron collision processes, such as recombination. The work describes the implementation of this system for rst electron collision spectroscopy experiments. A detection system has been realized including an ion detector and specroscopic beam-control software and instrumentation. Moreover, in order to improve the spectroscopic resolution systematical studies of intrinsic relaxation processes in the electron beam have been carried out. These include the dependence on the electron beam density, the magnetic guiding eld strength, and the acceleration geometry. The recombination measurements on low-lying resonances in lithiumlike Sc 18+ yield a high-precision measurement of the 2s-2p 3/2 transition energy in this system. Operation of the two-electron-beam setup at high collision energy (∼1000 eV) is established using resonances of hydrogenlike Mg 11+ , while the unique possibility of modifying the beam-merging geometry con rms its importance for the electron-ion recombination rate at lowest relative energy, as demonstrated on F 6+ . (orig.)

Ultrafast Phase Transition in Vanadium Dioxide Driven by Hot-Electron Injection

Directory of Open Access Journals (Sweden)

Prasankumar R. P.

2013-03-01

Full Text Available We present a novel all-optical method of triggering the phase transition in vanadium dioxide by means of ballistic electrons injected across the interface between a mesh of Au nanoparticles coveringd VO2 nanoislands. By performing non-degenerate pump-probe transmission spectroscopy on this hybrid plasmonic/phase-changing nanostructure, structural and electronic dynamics can be retrieved and compared.

Electronic transport and conduction mechanism transition in La{sub 1∕3}Sr{sub 2∕3}FeO{sub 3} thin films

Energy Technology Data Exchange (ETDEWEB)

Devlin, R. C.; Krick, A. L.; Sichel-Tissot, R. J.; Xie, Y. J.; May, S. J., E-mail: smay@coe.drexel.edu [Department of Materials Science and Engineering, Drexel University, Philadelphia, Pennsylvania 19104 (United States)

2014-06-21

We report on the electronic transport properties of epitaxial La{sub 1∕3}Sr{sub 2∕3}FeO{sub 3} films using temperature dependent resistivity, Hall effect, and magnetoresistance measurements. We show that the electronic phase transition, which occurs near 190 K, results in a change in conduction mechanism from nonadiabatic polaron transport at high temperatures to resistivity behavior following a power law temperature dependence at low temperatures. The phase transition is also accompanied by an abrupt increase in apparent mobility and Hall coefficient below the critical temperature (T*). We argue that the exotic low temperature transport properties are a consequence of the unusually long-range periodicity of the antiferromagnetic ordering, which also couples to the electronic transport in the form of a negative magnetoresistance below T* and a sign reversal of the Hall coefficient at T*. By comparing films of differing thicknesses, stoichiometry, and strain states, we demonstrate that the observed conduction behavior is a robust feature of La{sub 1∕3}Sr{sub 2∕3}FeO{sub 3}.

Electronic structure of xenon implanted with low energy in amorphous silicon

International Nuclear Information System (INIS)

Barbieri, P.F.; Landers, R.; Oliveira, M.H. de; Alvarez, F.; Marques, F.C.

2007-01-01

Electronic structure of Xe implanted in amorphous silicon (a-Si) films are investigated. Xe atoms were implanted with low energy by ion beam assisted deposition (IBAD) technique during growth of the a-Si films. The Xe implantation energy varied in the 0-300 eV energy range. X-ray photoelectron spectroscopy (XPS), X-ray Auger excited spectroscopy (XAES) and X-ray absorption spectroscopy (XAS) were used for investigating the Xe electronic structure. The Xe M 4 N 45 N 45 transitions were measured to extract the Auger parameter and to analyze the initial state and relaxation contributions. It was found that the binding energy variation is mainly due to initial state contribution. The relaxation energy variation also shows that the Xe trapped environment depends on the implantation energy. XAS measurements reveals that Xe atoms are dispersed in the a-Si matrix

Nb3Al thin film deposition for low-noise terahertz electronics

International Nuclear Information System (INIS)

Dochev, D; Pavolotsky, A B; Belitsky, V; Olofsson, H

2008-01-01

Higher energy gap superconducting materials were always interesting for low-noise mixer applications such as superconductor-insulator-superconductor tunnel junctions (SIS) and hot-electron bolometer (HEB) used in sub-millimeter and terahertz parts of electro-magnetic spectrum. Here, we report a novel approach for producing Nb 3 Al thin film by co-sputtering from two confocally arranged Nb and Al dc-magnetrons onto substrate heated up to 830 deg. C. Characterization of the deposited films revealed presence of the A15 phase and measured critical temperature was up to 15.7 K with the transition width 0.2-0.3 K for a 300 nm thick film. We measured the film critical magnetic field and studied influence of annealing on the film properties. We have investigated compositional depth profile of the deposited films by spectroscopy of reflected electrons

Phase engineering of monolayer transition-metal dichalcogenide through coupled electron doping and lattice deformation

International Nuclear Information System (INIS)

Ouyang, Bin; Lan, Guoqiang; Song, Jun; Guo, Yinsheng; Mi, Zetian

2015-01-01

First-principles calculations were performed to investigate the phase stability and transition within four monolayer transition-metal dichalcogenide (TMD) systems, i.e., MX 2 (M = Mo or W and X = S or Se) under coupled electron doping and lattice deformation. With the lattice distortion and electron doping density treated as state variables, the energy surfaces of different phases were computed, and the diagrams of energetically preferred phases were constructed. These diagrams assess the competition between different phases and predict conditions of phase transitions for the TMDs considered. The interplay between lattice deformation and electron doping was identified as originating from the deformation induced band shifting and band bending. Based on our findings, a potential design strategy combining an efficient electrolytic gating and a lattice straining to achieve controllable phase engineering in TMD monolayers was demonstrated

The electronic origin of shear-induced direct to indirect gap transition and anisotropy diminution in phosphorene.

Science.gov (United States)

Sa, Baisheng; Li, Yan-Ling; Sun, Zhimei; Qi, Jingshan; Wen, Cuilian; Wu, Bo

2015-05-29

Artificial monolayer black phosphorus, so-called phosphorene, has attracted global interest with its distinguished anisotropic, optoelectronic, and electronic properties. Here, we unraveled the shear-induced direct-to-indirect gap transition and anisotropy diminution in phosphorene based on first-principles calculations. Lattice dynamic analysis demonstrates that phosphorene can sustain up to 10% applied shear strain. The bandgap of phosphorene experiences a direct-to- indirect transition when 5% shear strain is applied. The electronic origin of the direct-to-indirect gap transition from 1.54 eV at ambient conditions to 1.22 eV at 10% shear strain for phosphorene is explored. In addition, the anisotropy diminution in phosphorene is discussed by calculating the maximum sound velocities, effective mass, and decomposed charge density, which signals the undesired shear-induced direct-to-indirect gap transition in applications of phosphorene for electronics and optoelectronics. On the other hand, the shear-induced electronic anisotropy properties suggest that phosphorene can be applied as the switcher in nanoelectronic applications.

Electronic self-organization in layered transition metal dichalcogenides

Energy Technology Data Exchange (ETDEWEB)

Ritschel, Tobias

2015-10-30

The interplay between different self-organized electronically ordered states and their relation to unconventional electronic properties like superconductivity constitutes one of the most exciting challenges of modern condensed matter physics. In the present thesis this issue is thoroughly investigated for the prototypical layered material 1T-TaS{sub 2} both experimentally and theoretically. At first the static charge density wave order in 1T-TaS{sub 2} is investigated as a function of pressure and temperature by means of X-ray diffraction. These data indeed reveal that the superconductivity in this material coexists with an inhomogeneous charge density wave on a macroscopic scale in real space. This result is fundamentally different from a previously proposed separation of superconducting and insulating regions in real space. Furthermore, the X-ray diffraction data uncover the important role of interlayer correlations in 1T-TaS{sub 2}. Based on the detailed insights into the charge density wave structure obtained by the X-ray diffraction experiments, density functional theory models are deduced in order to describe the electronic structure of 1T-TaS{sub 2} in the second part of this thesis. As opposed to most previous studies, these calculations take the three-dimensional character of the charge density wave into account. Indeed the electronic structure calculations uncover complex orbital textures, which are interwoven with the charge density wave order and cause dramatic differences in the electronic structure depending on the alignment of the orbitals between neighboring layers. Furthermore, it is demonstrated that these orbital-mediated effects provide a route to drive semiconductor-to-metal transitions with technologically pertinent gaps and on ultrafast timescales. These results are particularly relevant for the ongoing development of novel, miniaturized and ultrafast devices based on layered transition metal dichalcogenides. The discovery of orbital textures

The electronic structure and metal-insulator transitions in vanadium oxides

International Nuclear Information System (INIS)

Mossanek, Rodrigo Jose Ochekoski

2010-01-01

The electronic structure and metal-insulator transitions in vanadium oxides (SrVO_3, CaVO_3, LaVO_3 and YVO_3) are studied here. The purpose is to show a new interpretation to the spectra which is coherent with the changes across the metal-insulator transition. The main experimental techniques are the X-ray photoemission (PES) and X-ray absorption (XAS) spectroscopies. The spectra are interpreted with cluster model, band structure and atomic multiplet calculations. The presence of charge-transfer satellites in the core-level PES spectra showed that these vanadium oxides cannot be classified in the Mott-Hubbard regime. Further, the valence band and core-level spectra presented a similar behavior across the metal insulator transition. In fact, the structures in the spectra and their changes are determined by the different screening channels present in the metallic or insulating phases. The calculated spectral weight showed that the coherent fluctuations dominate the spectra at the Fermi level and give the metallic character to the SrVO_3 and CaVO_3 compounds. The vanishing of this charge fluctuation and the replacement by the Mott-Hubbard screening in the LaVO_3 and YVO_3 systems is ultimately responsible for the opening of a band gap and the insulating character. Further, the correlation effects are, indeed, important to the occupied electronic structure (coherent and incoherent peaks). On the other hand, the unoccupied electronic structure is dominated by exchange and crystal field effects (t2g and eg sub-bands of majority and minority spins). The optical conductivity spectrum was obtained by convoluting the removal and addition states. It showed that the oxygen states, as well as the crystal field and exchange effects are necessary to correctly compare and interpret the experimental results. Further, a correlation at the charge-transfer region of the core-level and valence band optical spectra was observed, which could be extended to other transition metal oxides

Medicine, lies and deceptions.

Science.gov (United States)

Benn, P

2001-04-01

This article offers a qualified defence of the view that there is a moral difference between telling lies to one's patients, and deceiving them without lying. However, I take issue with certain arguments offered by Jennifer Jackson in support of the same conclusion. In particular, I challenge her claim that to deny that there is such a moral difference makes sense only within a utilitarian framework, and I cast doubt on the aptness of some of her examples of non-lying deception. But I argue that lies have a greater tendency to damage trust than does non-lying deception, and suggest that since many doctors do believe there is a moral boundary between the two types of deception, encouraging them to violate that boundary may have adverse general effects on their moral sensibilities.

Electric Monopole Transition Strengths in the Stable Nickel Isotopes

Science.gov (United States)

Evitts, Lee John

A series of measurements of stable nickel isotopes were performed at the Australian National University in Canberra. Excited states in 58,60,62Ni were populated via inelastic scattering of proton beams delivered by the 14UD Pelletron accelerator. Multiple setups were used in order to determine the structure of low-lying states. The CAESAR array of Compton-suppressed HPGe detectors was used to measure the (E2/M1) mixing ratio of transitions from angular distributions of gamma rays. The Super-e spectrometer was used to measure conversion coefficients for a number of J to J transitions. The data obtained from both devices was combined with previously measured parent lifetimes and branching ratios to determine E0 transition strengths between J-pi transitions. The E0 transition strength for the second 0+ to first 0+ transitions in 60,62Ni have been measured for the first time through internal conversion electron detection. The experimental value of 132(+59,-70) for 62Ni agrees within 2 sigma of the previous result obtained from internal pair formation. However it is likely that the previous experimental results used an outdated theoretical model for internal pair formation emission. This work also represents the first measurements of E0 transition strengths between 2+ states in Ni isotopes. There is generally large E0 strength between the 2+ states, particularly in the second 2+ to first 2+ transition, however there is also a large uncertainty in the measurements owing to the difficulties involved in measuring conversion coefficients. In 62Ni, the E0 transition strength of 172(+62,-77) for the second 2+ to first 2+ transition gives further weight to the argument against the spherical vibrator model, as an E0 transition is forbidden if there is a change of only one phonon. The large measurement also indicates the presence of shape coexistence, complementing the recent experimental work carried out in the neutron-rich Ni isotopes.

Overscreening-underscreening transition in the two-channel Kondo model induced by electron-electron repulsion

International Nuclear Information System (INIS)

Zhang Yumei; Chen Hong.

1995-09-01

The effects of the repulsion between the electrons on the two-channel Kondo problem are studied by use of the bosonization technique. Following Emery and Kivelson, we define a special case in the spin density wave sector, in which the impurity spin is actually detached from the dynamics of the electrons. The model is thus mapped to a local Sine-Gordon system. For weak repulsion, the basic features of the overscreening picture are maintained. However, at sufficient strong repulsion the system is driven into the weak coupling regime, hence an overscreening-underscreening transition emerges. (author). 22 refs

Particle-like structure of Lie algebras

Science.gov (United States)

Vinogradov, A. M.

2017-07-01

If a Lie algebra structure 𝔤 on a vector space is the sum of a family of mutually compatible Lie algebra structures 𝔤i's, we say that 𝔤 is simply assembled from the 𝔤i's. Repeating this procedure with a number of Lie algebras, themselves simply assembled from the 𝔤i's, one obtains a Lie algebra assembled in two steps from 𝔤i's, and so on. We describe the process of modular disassembling of a Lie algebra into a unimodular and a non-unimodular part. We then study two inverse questions: which Lie algebras can be assembled from a given family of Lie algebras, and from which Lie algebras can a given Lie algebra be assembled. We develop some basic assembling and disassembling techniques that constitute the elements of a new approach to the general theory of Lie algebras. The main result of our theory is that any finite-dimensional Lie algebra over an algebraically closed field of characteristic zero or over R can be assembled in a finite number of steps from two elementary constituents, which we call dyons and triadons. Up to an abelian summand, a dyon is a Lie algebra structure isomorphic to the non-abelian 2-dimensional Lie algebra, while a triadon is isomorphic to the 3-dimensional Heisenberg Lie algebra. As an example, we describe constructions of classical Lie algebras from triadons.

DFT and two-dimensional correlation analysis methods for evaluating the Pu{sup 3+}–Pu{sup 4+} electronic transition of plutonium-doped zircon

Energy Technology Data Exchange (ETDEWEB)

Bian, Liang, E-mail: bianliang@ms.xjb.ac.cn [Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011, Xinjiang (China); Laboratory for Extreme Conditions Matter Properties, South West University of Science and Technology, Mianyang 621010, Sichuan (China); Dong, Fa-qin; Song, Mian-xin [Laboratory for Extreme Conditions Matter Properties, South West University of Science and Technology, Mianyang 621010, Sichuan (China); Dong, Hai-liang [Department of Geology and Environmental Earth Science, Miami University, Oxford, OH 45056 (United States); Li, Wei-Min [Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011, Xinjiang (China); Duan, Tao; Xu, Jin-bao [Laboratory for Extreme Conditions Matter Properties, South West University of Science and Technology, Mianyang 621010, Sichuan (China); Zhang, Xiao-yan [Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011, Xinjiang (China); Laboratory for Extreme Conditions Matter Properties, South West University of Science and Technology, Mianyang 621010, Sichuan (China)

2015-08-30

Highlights: • Effect of Pu f-shell electron on the electronic property of zircon is calculated via DFT and 2D-CA techniques. • Reasons of Pu f-shell electron influencing on electronic properties are systematically discussed. • Phase transitions are found at two point 2.8 mol% and 7.5 mol%. - Abstract: Understanding how plutonium (Pu) doping affects the crystalline zircon structure is very important for risk management. However, so far, there have been only a very limited number of reports of the quantitative simulation of the effects of the Pu charge and concentration on the phase transition. In this study, we used density functional theory (DFT), virtual crystal approximation (VCA), and two-dimensional correlation analysis (2D-CA) techniques to calculate the origins of the structural and electronic transitions of Zr{sub 1−c}Pu{sub c}SiO{sub 4} over a wide range of Pu doping concentrations (c = 0–10 mol%). The calculations indicated that the low-angular-momentum Pu-f{sub xy}-shell electron excites an inner-shell O-2s{sup 2} orbital to create an oxygen defect (V{sub O-s}) below c = 2.8 mol%. This oxygen defect then captures a low-angular-momentum Zr-5p{sup 6}5s{sup 2} electron to form an sp hybrid orbital, which exhibits a stable phase structure. When c > 2.8 mol%, each accumulated V{sub O-p} defect captures a high-angular-momentum Zr-4d{sub z} electron and two Si-p{sub z} electrons to create delocalized Si{sup 4+} → Si{sup 2+} charge disproportionation. Therefore, we suggest that the optimal amount of Pu cannot exceed 7.5 mol% because of the formation of a mixture of ZrO{sub 8} polyhedral and SiO{sub 4} tetrahedral phases with the orientation (10-1). This study offers new perspective on the development of highly stable zircon-based solid solution materials.

Binding lies

Directory of Open Access Journals (Sweden)

Avraham eMerzel

2015-10-01

Full Text Available Do we feel bound by our own misrepresentations? Does one act of cheating compel the cheater to make subsequent choices that maintain the false image even at a cost? To answer these questions we employed a two-task paradigm such that in the first task the participants could benefit from false reporting of private observations whereas in the second they could benefit from making a prediction in line with their actual, rather than their previously reported observations. Thus, for those participants who inflated their report during the first task, sticking with that report for the second task was likely to lead to a loss, whereas deviating from it would imply that they had lied. Data from three experiments (total N=116 indicate that, having lied, participants were ready to suffer future loss rather than admit, even if implicitly, that they had lied.

The use of Rich and Suter diagrams to explain the electron configurations of transition elements

Energy Technology Data Exchange (ETDEWEB)

Orofino, Hugo; Machado, Sergio P.; Faria, Roberto B., E-mail: faria@iq.ufrj.br [Instituto de Quimica, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ (Brazil)

2013-09-01

Rich and Suter diagrams are a very useful tool to explain the electron configurations of all transition elements, and in particular, the s{sup 1} and s{sup 0} configurations of the elements Cr, Cu, Nb, Mo, Ru, Rh, Pd, Ag, and Pt. The application of these diagrams to the inner transition elements also explains the electron configurations of lanthanoids and actinoids, except for Ce, Pa, U, Np, and Cm, whose electron configurations are indeed very special because they are a mixture of several configurations. (author)

The use of Rich and Suter diagrams to explain the electron configurations of transition elements

Directory of Open Access Journals (Sweden)

Hugo Orofino

2013-01-01

Full Text Available Rich and Suter diagrams are a very useful tool to explain the electron configurations of all transition elements, and in particular, the s¹ and s0 configurations of the elements Cr, Cu, Nb, Mo, Ru, Rh, Pd, Ag, and Pt. The application of these diagrams to the inner transition elements also explains the electron configurations of lanthanoids and actinoids, except for Ce, Pa, U, Np, and Cm, whose electron configurations are indeed very special because they are a mixture of several configurations.

When is a lie acceptable? Work and private life lying acceptance depends on its beneficiary.

Science.gov (United States)

Cantarero, Katarzyna; Szarota, Piotr; Stamkou, Eftychia; Navas, Marisol; Dominguez Espinosa, Alejandra Del Carmen

2018-01-01

In this article we show that when analyzing attitude towards lying in a cross-cultural setting, both the beneficiary of the lie (self vs other) and the context (private life vs. professional domain) should be considered. In a study conducted in Estonia, Ireland, Mexico, The Netherlands, Poland, Spain, and Sweden (N = 1345), in which participants evaluated stories presenting various types of lies, we found usefulness of relying on the dimensions. Results showed that in the joint sample the most acceptable were other-oriented lies concerning private life, then other-oriented lies in the professional domain, followed by egoistic lies in the professional domain; and the least acceptance was shown for egoistic lies regarding one's private life. We found a negative correlation between acceptance of a behavior and the evaluation of its deceitfulness.

Changes to Workflow and Process Measures in the PICU During Transition From Semi to Full Electronic Health Record.

Science.gov (United States)

Salib, Mina; Hoffmann, Raymond G; Dasgupta, Mahua; Zimmerman, Haydee; Hanson, Sheila

2015-10-01

Studies showing the changes in workflow during transition from semi to full electronic medical records are lacking. This objective study is to identify the changes in workflow in the PICU during transition from semi to full electronic health record. Prospective observational study. Children's Hospital of Wisconsin Institutional Review Board waived the need for approval so this study was institutional review board exempt. This study measured clinical workflow variables at a 72-bed PICU during different phases of transition to a full electronic health record, which occurred on November 4, 2012. Phases of electronic health record transition were defined as follows: pre-electronic health record (baseline data prior to transition to full electronic health record), transition phase (3 wk after electronic health record), and stabilization (6 mo after electronic health record). Data were analyzed for the three phases using Mann-Whitney U test with a two-sided p value of less than 0.05 considered significant. Seventy-two bed PICU. All patients in the PICU were included during the study periods. Five hundred and sixty-four patients with 2,355 patient days were evaluated in the three phases. Duration of rounds decreased from a median of 9 minutes per patient pre--electronic health record to 7 minutes per patient post electronic health record. Time to final note decreased from 2.06 days pre--electronic health record to 0.5 days post electronic health record. Time to first medication administration after admission also decreased from 33 minutes pre--electronic health record and 7 minutes post electronic health record. Time to Time to medication reconciliation was significantly higher pre-electronic health record than post electronic health record and percent of medication reconciliation completion was significantly lower pre--electronic health record than post electronic health record and percent of medication reconciliation completion was significantly higher pre--electronic

Ultrafast optical snapshots of hybrid perovskites reveal the origin of multiband electronic transitions

Science.gov (United States)

Appavoo, Kannatassen; Nie, Wanyi; Blancon, Jean-Christophe; Even, Jacky; Mohite, Aditya D.; Sfeir, Matthew Y.

2017-11-01

Connecting the complex electronic excitations of hybrid perovskites to their intricate organic-inorganic lattice structure has critical implications for energy conversion and optoelectronic technologies. Here we detail the multiband, multivalley electronic structure of a halide hybrid perovskite by measuring the absorption transients of a millimeter-scale-grain thin film as it undergoes a thermally controlled reversible tetragonal-to-orthogonal phase transition. Probing nearly single grains of this hybrid perovskite, we observe an unreported energy splitting (degeneracy lifting) of the high-energy 2.6 eV band in the tetragonal phase that further splits as the rotational degrees of freedom of the disordered C H3N H3 + molecules are reduced when the sample is cooled. This energy splitting drastically increases during an extended phase-transition coexistence region that persists from 160 to 120 K, becoming more pronounced in the orthorhombic phase. By tracking the temperature-dependent optical transition energies and using symmetry analysis that describes the evolution of electronic states from the tetragonal phase to the orthorhombic phase, we assign this energy splitting to the nearly degenerate transitions in the tetragonal phase from both the R - and M -point-derived states. Importantly, these assignments explain how momentum conservation effects lead to long hot-carrier lifetimes in the room-temperature tetragonal phase, with faster hot-carrier relaxation when the hybrid perovskite structurally transitions to the orthorhombic phase due to enhanced scattering at the Γ point.

An Ultrasensitive Hot-Electron Bolometer for Low-Background SMM Applications

Science.gov (United States)

Olayaa, David; Wei, Jian; Pereverzev, Sergei; Karasik, Boris S.; Kawamura, Jonathan H.; McGrath, William R.; Sergeev, Andrei V.; Gershenson, Michael E.

2006-01-01

We are developing a hot-electron superconducting transition-edge sensor (TES) that is capable of counting THz photons and operates at T = 0.3K. The main driver for this work is moderate resolution spectroscopy (R approx. 1000) on the future space telescopes with cryogenically cooled (approx. 4 K) mirrors. The detectors for these telescopes must be background-limited with a noise equivalent power (NEP) approx. 10(exp -19)-10(exp -20) W/Hz(sup 1/2) over the range v = 0.3-10 THz. Above about 1 THz, the background photon arrival rate is expected to be approx. 10-100/s), and photon counting detectors may be preferable to an integrating type. We fabricated superconducting Ti nanosensors with a volume of approx. 3x10(exp -3) cubic microns on planar substrate and have measured the thermal conductance G to the thermal bath. A very low G = 4x10(exp -14) W/K, measured at 0.3 K, is due to the weak electron-phonon coupling in the material and the thermal isolation provided by superconducting Nb contacts. This low G corresponds to NEP(0.3K) = 3x10(exp -19) W/Hz(sup 1/2). This Hot-Electron Direct Detector (HEDD) is expected to have a sufficient energy resolution for detecting individual photons with v > 0.3 THz at 0.3 K. With the sensor time constant of a few microseconds, the dynamic range is approx. 50 dB.

Titanium oxidation-reduction at low oxygen pressure under electron bombardment

International Nuclear Information System (INIS)

Brasca, R.; Passeggi, M.C.G.; Ferron, J.

2006-01-01

The effect of the electron bombardment on the first stages of the titanium oxidation process has been studied by means of Auger Electron Spectroscopy. Using Factor Analysis and the valence electron dependence behaviour of the titanium LMV Auger transition, we found that the process is strongly dependent on the oxygen pressure and electron current density. Depending on the irradiation conditions, films of different thickness and Ti oxidized states are obtained

Study of radicals, clusters and transition state species by anion photoelectron spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Arnold, Don Wesley [Univ. of California, Berkeley, CA (United States)

1994-08-01

Free radicals, elemental and van der Waals clusters and transition state species for bimolecular chemical reactions are investigated using anion photoelectron spectroscopy. Several low-lying electronic states of ozone have been identified via photoelectron spectroscopy of O₃^-. A characterization of these states is important to models for atmospheric ozone reaction kinetics. The fluoroformyloxyl radical, FCO₂, has been investigated, providing vibrational frequencies and energies for two electronic states. The technique has also been employed to make the first direct observation and characterization of the NNO₂ molecule. Several electronic states are observed for this species which is believed to play a role as a reactive intermediate in the N + NO₂ reaction. The experimental results for all three of these radicals are supplemented by ab initio investigations of their molecular properties. The clusters investigations include studies of elemental carbon clusters (C₂^- - C₁₁^-), and van der Waals clusters (X^-(CO₂)_n, X = I, Br, Cl; n {le} 13 and I^- (N₂O)_n=1--11). Primarily linear clusters are observed for the smaller carbon clusters, while the spectra of the larger clusters contain contribution from cyclic anion photodetachment. Very interesting ion-solvent interactions are observed in the X^-(CO₂)n clusters. The transition state regions for several bimolecular chemical reactions have also been investigated by photodetachment of a negative ion precursor possessing a geometry similar to that of the transition state species. These spectra show features which are assigned to motions of the unstable neutral complex existing between reactants and products.

Mott transition: Low-energy excitations and superconductivity

International Nuclear Information System (INIS)

Ioffe, L.B.; Larkin, A.I.

1988-09-01

It is possible that metal-dielectric transition does not result in changes of magnetic or crystallographic symmetry. In this case a fermionic spectrum is not changed at the transition, but additional low-energy excitations appear which can be described as a gauge field that has the same symmetry as an electromagnetic one. In the case of a non half-filled band gapless scalar Bose excitations also appear. Due to the presence of additional gauge field the physical conductivity is determined by the lowest conductivity of the Fermi or Bose subsystems. (author). 11 refs

Positron annihilation induced Auger electron spectroscopy and its implementation at accelerator based low energy positron factories

International Nuclear Information System (INIS)

Weiss, A.; Koeymen, A.R.; Mehl, D.; Lee, K.H.; Yang Gimo; Jensen, K.

1991-01-01

Positron annihilation induced auger electron spectroscopy (PAES) makes use of a beam of low energy positrons to excite Auger transitions by annihilating core electrons. The large secondary electron background usually present in Auger spectra can be eliminated by setting the positron beam energy well below the Auger electron energy. This allows true Auger lineshapes to be obtained. Further, because the positron is localized just outside the surface before it annihilates, PAES is extremely sensitive to the topmost atomic layer. Recent PAES results obtained at the University of Texas at Arlington will be presented. In addition, the use of high resolution energy analyzers with multichannel particle detection schemes to prevent problems due to the high data rates associated with accelerator based positron beams will be discussed. (orig.)

Investigations of the valence-shell excitations of molecular ethane by high-energy electron scattering

Science.gov (United States)

Xu, Wei-Qing; Xu, Long-Quan; Qi, De-Guang; Chen, Tao; Liu, Ya-Wei; Zhu, Lin-Fan

2018-04-01

The differential cross sections and generalized oscillator strengths for the low-lying excitations of the valence-shell 1eg orbital electron in ethane have been measured for the first time at a high incident electron energy of 1500 eV and a scattering angular range of 1.5°-10°. A weak feature, termed X here, with a band center of about 7.5 eV has been observed, which was also announced by the previous experimental and theoretical studies. The dynamic behaviors of the generalized oscillator strengths for the 3s (8.7 eV), 3s+3p (9.31 eV, 9.41 eV), and X (˜7.5 eV) transitions on the momentum transfer squared have been obtained. The integral cross sections of these transitions from their thresholds to 5000 eV have been obtained with the aid of the BE-scaling (B is the binding energy and E is the excitation energy) method. The optical oscillator strengths of the above transitions determined by extrapolating their generalized oscillator strengths to the limit of the squared momentum transfer K2 → 0 are in good agreement with the ones from the photoabsorption spectrum [J. W. Au et al., Chem. Phys. 173, 209 (1993)], which indicates that the present differential cross sections, generalized oscillator strengths, and integral cross sections can serve as benchmark data.

Lie bialgebras with triangular decomposition

International Nuclear Information System (INIS)

Andruskiewitsch, N.; Levstein, F.

1992-06-01

Lie bialgebras originated in a triangular decomposition of the underlying Lie algebra are discussed. The explicit formulas for the quantization of the Heisenberg Lie algebra and some motion Lie algebras are given, as well as the algebra of rational functions on the quantum Heisenberg group and the formula for the universal R-matrix. (author). 17 refs

Secondary electron emission yield in the limit of low electron energy

CERN Document Server

Andronov, A.N.; Kaganovich, I.D.; Startsev, E.A.; Raitses, Y.; Demidov, V.I.

2013-04-22

Secondary electron emission (SEE) from solids plays an important role in many areas of science and technology.1 In recent years, there has been renewed interest in the experimental and theoretical studies of SEE. A recent study proposed that the reflectivity of very low energy electrons from solid surface approaches unity in the limit of zero electron energy2,3,4, If this was indeed the case, this effect would have profound implications on the formation of electron clouds in particle accelerators,2-4 plasma measurements with electrostatic Langmuir probes, and operation of Hall plasma thrusters for spacecraft propulsion5,6. It appears that, the proposed high electron reflectivity at low electron energies contradicts to numerous previous experimental studies of the secondary electron emission7. The goal of this note is to discuss possible causes of these contradictions.

Pulse shape and spectrum of coherent diffraction-limited transition radiation from electron beams

Energy Technology Data Exchange (ETDEWEB)

van Tilborg, J.; Schroeder, C.B.; Esarey, E.; Leemans, W.P.

2003-12-20

The electric field in the temporal and spectral domain of coherent diffraction-limited transition radiation is studied. An electron bunch, with arbitrary longitudinal momentum distribution, propagating at normal incidence to a sharp metal-vacuum boundary with finite transverse dimension is considered. A general expression for the spatiotemporal electric field of the transition radiation is derived, and closed-form solutions for several special cases are given. The influence of parameters such as radial boundary size, electron momentum distribution, and angle of observation on the waveform (e.g., radiation pulse length and amplitude) are discussed. For a Gaussian electron bunch, the coherent radiation waveform is shown to have a single-cycle profile. Application to a novel THz source based on a laser-driven accelerator is discussed.

Exotic Quantum Phases and Phase Transitions of Strongly Interacting Electrons in Low-Dimensional Systems

Science.gov (United States)

Mishmash, Ryan V.

Experiments on strongly correlated quasi-two-dimensional electronic materials---for example, the high-temperature cuprate superconductors and the putative quantum spin liquids kappa-(BEDT-TTF)2Cu2(CN)3 and EtMe3Sb[Pd(dmit)2]2---routinely reveal highly mysterious quantum behavior which cannot be explained in terms of weakly interacting degrees of freedom. Theoretical progress thus requires the introduction of completely new concepts and machinery beyond the traditional framework of the band theory of solids and its interacting counterpart, Landau's Fermi liquid theory. In full two dimensions, controlled and reliable analytical approaches to such problems are severely lacking, as are numerical simulations of even the simplest of model Hamiltonians due to the infamous fermionic sign problem. Here, we attempt to circumvent some of these difficulties by studying analogous problems in quasi-one dimension. In this lower dimensional setting, theoretical and numerical tractability are on much stronger footing due to the methods of bosonization and the density matrix renormalization group, respectively. Using these techniques, we attack two problems: (1) the Mott transition between a Fermi liquid metal and a quantum spin liquid as potentially directly relevant to the organic compounds kappa-(BEDT-TTF)2Cu 2(CN)3 and EtMe3Sb[Pd(dmit)2] 2 and (2) non-Fermi liquid metals as strongly motivated by the strange metal phase observed in the cuprates. In both cases, we are able to realize highly exotic quantum phases as ground states of reasonable microscopic models. This lends strong credence to respective underlying slave-particle descriptions of the low-energy physics, which are inherently strongly interacting and also unconventional in comparison to weakly interacting alternatives. Finally, working in two dimensions directly, we propose a new slave-particle theory which explains in a universal way many of the intriguing experimental results of the triangular lattice organic spin

Verbal lie detection

NARCIS (Netherlands)

Vrij, Aldert; Taylor, Paul J.; Picornell, Isabel; Oxburgh, Gavin; Myklebust, Trond; Grant, Tim; Milne, Rebecca

2015-01-01

In this chapter, we discuss verbal lie detection and will argue that speech content can be revealing about deception. Starting with a section discussing the, in our view, myth that non-verbal behaviour would be more revealing about deception than speech, we then provide an overview of verbal lie

Importance of correlation effects in hcp iron revealed by a pressure-induced electronic topological transition.

Science.gov (United States)

Glazyrin, K; Pourovskii, L V; Dubrovinsky, L; Narygina, O; McCammon, C; Hewener, B; Schünemann, V; Wolny, J; Muffler, K; Chumakov, A I; Crichton, W; Hanfland, M; Prakapenka, V B; Tasnádi, F; Ekholm, M; Aichhorn, M; Vildosola, V; Ruban, A V; Katsnelson, M I; Abrikosov, I A

2013-03-15

We discover that hcp phases of Fe and Fe(0.9)Ni(0.1) undergo an electronic topological transition at pressures of about 40 GPa. This topological change of the Fermi surface manifests itself through anomalous behavior of the Debye sound velocity, c/a lattice parameter ratio, and Mössbauer center shift observed in our experiments. First-principles simulations within the dynamic mean field approach demonstrate that the transition is induced by many-electron effects. It is absent in one-electron calculations and represents a clear signature of correlation effects in hcp Fe.

Ultra-low-energy wide electron exposure unit

International Nuclear Information System (INIS)

Yonago, Akinobu; Oono, Yukihiko; Tokunaga, Kazutoshi; Kishimoto, Junichi; Wakamoto, Ikuo

2001-01-01

Heat and ultraviolet ray processes are used in surface dryness of paint, surface treatment of construction materials and surface sterilization of food containers. A process using a low-energy wide-area electron beam (EB) has been developed that features high speed and low drive cost. EB processing is not widespread in general industry, however, due to high equipment cost and difficult maintenance. We developed an ultra-low-energy wide-area electron beam exposure unit, the Mitsubishi Wide Electron Exposure Unit (MIWEL) to solve these problems. (author)

Lying to patients with dementia: Attitudes versus behaviours in nurses.

Science.gov (United States)

Cantone, Daniela; Attena, Francesco; Cerrone, Sabrina; Fabozzi, Antonio; Rossiello, Riccardo; Spagnoli, Laura; Pelullo, Concetta Paola

2017-01-01

Using lies, in dementia care, reveals a common practice far beyond the diagnosis and prognosis, extending to the entire care process. In this article, we report results about the attitude and the behaviour of nurses towards the use of lies to patients with dementia. An epidemiological cross-sectional study was conducted between September 2016 and February 2017 in 12 elderly residential facilities and in the geriatric, psychiatric and neurological wards of six specialised hospitals of Italy's Campania Region. In all, 106 nurses compiled an attitude questionnaire (A) where the main question was 'Do you think it is ethically acceptable to use lies to patients with dementia?', instead 106 nurses compiled a behaviour questionnaire (B), where the main question was 'Have you ever used lies to patients with dementia?' Ethical considerations: Using lies in dementia care, although topic ethically still controversial, reveals a common practice far beyond the diagnosis and prognosis, extending to the entire care process. Only a small percentage of the interviewed nurses stated that they never used lies/that it is never acceptable to use lies (behaviour 10.4% and attitude 12.3%; p = 0.66). The situation in which nurses were more oriented to use lies was 'to prevent or reduce aggressive behaviors'. Indeed, only the 6.7% in the attitude group and 3.8% in the behaviour group were against using lies. On the contrary, the case in which the nurses were less oriented to use lies was 'to avoid wasting time giving explanations', in this situation were against using lies the 51.0% of the behaviour group and the 44.6% of the attitude group. Our results, according to other studies, support the hypothesis of a low propensity of nurses to ethical reflection about use of lies. In our country, the implementation of guidelines about a correct use of lie in the relationship between health operators and patients would be desirable.

LIE n-RACKS

OpenAIRE

Biyogmam, Guy Roger

2011-01-01

In this paper, we introduce the category of Lie $n$-racks and generalize several results known on racks. In particular, we show that the tangent space of a Lie $n$-Rack at the neutral element has a Leibniz $n$-algebra structure. We also define a cohomology theory of $n$-racks..

Thermoelectric power and topological transitions in quasi-two-dimensional electronic systems

International Nuclear Information System (INIS)

Blanter, Ya.M.; Pantsulaya, A.V.; Varlamov, A.A.

1991-05-01

Electron-impurity relaxation time and the thermoelectric power (TEP) of quasi-two-dimensional electron gas are calculated. Two cases are discussed: the isotropic spectrum and the electronic topological transition (ETT) of the ''neck-breaking'' type. Methods of thermal diagramatic technique are used for the calculation. It is found that the TEP in the vicinity of the ETT greatly exceeds its background value. The results of experimental investigations of the TEP in the metal-oxide-semiconductor structures are compared with the predictions of the proposed theory. (author). 17 refs, 5 figs

High-effective position time spectrometer in actual measurements of low intensity region of electron spectra

International Nuclear Information System (INIS)

Babenkov, M.I.; Zhdanov, V.S.

2002-01-01

Magnetic position-time spectrometer was proposed in previous work, where not only electron coordinates in focal plane are measured by position sensitive detector (PSD) but places of their birth in beta source plane of a large area are fixed using another PSD, situated behind it, by quick effects, accompanying radioactive decay. PSD on the basis of macro-channel plates are used. It is succeeded in position-time spectrometer to combine beta sources of a large area with multichannel registration for a wide energy interval, that efficiency of measurements was two orders of magnitude increase d in comparison magnetic apparatus having PSD only in focal plane. Owing to two detectors' switching on coincidence the relation effect/background in increased minimum on two orders of magnitude in comparison with the same apparatus. At some complication of mathematical analysis it was obtained, that high characteristics of position-time spectrometer are kept during the use the magnetic field, providing double focusing. Owning to this focusing the gain the efficiency of measurements will make one more order of magnitude. Presented high-effective position-time spectrometer is supposed to use in the measurements of low-intensity region of electron spectra, which are important for development of fundamental physics. This is the first of all estimation of electron anti-neutrino mass by the form of beta spectrum of tritium in the region of boundary energy. Recently here there was problem of non physical negative values. This problem can be solved by using in measurement of different in principle high-effective spectrometers, which possess improved background properties. A position-time spectrometers belongs to these apparatus, which provides the best background conditions at very large effectiveness of the measurements of tritium beta spectrum in the region of boundary energy with acceptable high resolution. An important advantage of position-time spectrometer is the possibility of

Surface sterilization by low energy electron beams

International Nuclear Information System (INIS)

Sekiguchi, Masayuki; Tabei, Masae

1989-01-01

The germicidal effectiveness of low energy electron beams (175 KV) against bacterial cells was investigated. The dry spores of Bacillus pumilus ATCC 27142 and Bacillus globigii ATCC 9372 inoculated on carrier materials and irradiated by gamma rays showed the exponential type of survival curves whereas they showed sigmoidal ones when exposed to low energy electron beams. When similarly irradiated, the wet spores inoculated on membrane filter showed the same survival curves as the dry spores inoculated on carrier materials. The wet vegetative cells of Escherichia coli ATCC 25922 showed exponential curves when exposed to gamma and electron beam irradiation. Low energy electron beams in air showed little differences from nitrogen stream in their germicidal effectiveness against dry spores of B. pumilus. The D values of B. pumilus spores inoculated on metal plates decreased as the amounts of backscattering electrons from the plates increased. There was adequate correlation between the D value (linear region of survival curve), average D value (6D/6) and 1% survival dose and backscattering factor. Depth dose profile and backscatterig dose of low energy electron beams were measured by radiochromic dye film dosimeter (RCD). These figures were not always in accord with the observed germicidal effectiveness against B. pumilus spores because of varying thickness of RCD and spores inoculated on carrier material. The dry spores were very thin and this thinness was useful in evaluating the behavior of low energy electrons. (author)

Transition radiation detectors for electron identification beyond 1 GeV/c

International Nuclear Information System (INIS)

Appuhn, R.D.; Heinloth, K.; Lange, E.; Oedingen, R.; Schloesser, A.

1987-07-01

Transition radiation detectors (TRDs) have been tested for the separation of electrons from pions in the momentum range between 1 GeV/c and 6 GeV/c. Foams as well as fibres and foils served as radiator materials while two types of chambers, a longitudinal drift chamber (DC) and a multiwire proportional chamber (MWPC), both of 16 mm depth and dominantly filled with xenon, were used for detecting the transition radiation photons with a setup of four chambers. Analyzing the data we compared the methods of mean, truncated mean and of maximum likelihood of the total charge measurements and several methods of cluster analysis. As a result of the total charge measurements performed at test beams at CERN and DESY we obtained about 1% pion contamination at 90% electron efficiency for the polypropylene materials in the configuration of four modules with a total length of 40 cm. An improvement by a factor of about two for the electron/pion discrimination can be obtained in case of a detailed analysis of the clusters. (orig.)

Decay modes of high-lying single-particle states in 209Pb

International Nuclear Information System (INIS)

Beaumel, D.; Fortier, S.; Gales, S.; Guillot, J.; Crawley, G.M.; Massolo, C.P.; Renteria, M.

1993-01-01

The neutron decay of high-lying single-particle states in 209 Pb excited by means of the (α, 3 He) reaction has been investigated at 122 MeV incident energy using the multidetector array EDEN. The high spin values of these states, inferred from previous inclusive experiments, are confirmed by the present data involving angular correlation measurements and the determination of branching ratios to low lying levels in 208 Pb. The structure located between 8.5 and 12 MeV excitation energy in 209 Pb displays large departures from a pure statistical decay with significant direct feeding of the low-lying collective states (3 - ,5 - ) of 208 Pb. At higher excitation energy up to 20 MeV, the measured neutron decay is in agreement with the predictions of the statistical model. (authors). 24 refs., 16 figs., 2 tabs

From simplicial Lie algebras and hypercrossed complexes to differential graded Lie algebras via 1-jets

OpenAIRE

Jurco, Branislav

2011-01-01

Let g be a simplicial Lie algebra with Moore complex Ng of length k. Let G be the simplicial Lie group integrating g, which is simply connected in each simplicial level. We use the 1-jet of the classifying space of G to construct, starting from g, a Lie k-algebra L. The so constructed Lie k-algebra L is actually a differential graded Lie algebra. The differential and the brackets are explicitly described in terms (of a part) of the corresponding k-hypercrossed complex structure of Ng. The res...

Inelastic electron scattering, fine structure of M1 giant resonances and Gamow-Teller states

International Nuclear Information System (INIS)

Richter, A.

1983-01-01

Recent progress in obtaining detailed fine structure distributions of magnetic giant resonances in nuclei using high resolution inelastic electron scattering at low energy is discussed. Specific examples chosen are the medium heavy nuclei 40 42 44 48 Ca in which M1 excitations are due to neutron spin-flip transitions and the N=28 isotones 50 Ti, 52 Cr and 54 Fe where in addition also proton excitations contribute to the measured M1 strength. It is found that the M1 strength is very fragmented and considerably quenched in comparison to predictions of shell model calculations in a model space that includes up to 2p-2h excitations. Finally, the old problem of M1 strength in 208 Pb is revisited and the results of a form factor measurement of a recently discovered low lying Jsup(π)=1 + state by nuclear resonance fluorescence are presented. (Auth.)

Electron scattering off palladium isotopes

International Nuclear Information System (INIS)

Laan, J.B. van der.

1986-01-01

The low-lying states of the even Pd isotopes are characterized by vibrator-like properties. In this thesis the results of an electron scattering experiment on the Pd isotopes, designed to study the description of such nuclei in the Anharmonic Vibrator Model (AVM) and the Interacting Boson Approximation (IBA), are presented and discussed. Data have been taken at the high-resolution electron scattering facility of NIKHEF-K and covered a momentum-transfer range of 0.4 to 2.5 fm -1 . (Auth.)

Evidence for a new class of many-electron Auger transitions in atoms

International Nuclear Information System (INIS)

Lee, I.; Wehlitz, R.; Becker, U.; Amusia, M.Ya.; Academy of Sciences, Saint Petersburg

1993-01-01

The possibility of the joint decay of two holes and one excited electron is discussed as one way many-electron Auger transitions can take place. It is shown that existing experimental decay spectra of resonantly excited states in krypton and xenon exhibit weak lines which may be associated with this new type of Auger process. (Author)

Nonflexible Lie-admissible algebras

International Nuclear Information System (INIS)

Myung, H.C.

1978-01-01

We discuss the structure of Lie-admissible algebras which are defined by nonflexible identities. These algebras largely arise from the antiflexible algebras, 2-varieties and associator dependent algebras. The nonflexible Lie-admissible algebras in our discussion are in essence byproducts of the study of nonassociative algebras defined by identities of degree 3. The main purpose is to discuss the classification of simple Lie-admissible algebras of nonflexible type

Stranski–Krastanov transition and self-organized structures in low-strained AlInN/GaN multilayer structures

International Nuclear Information System (INIS)

Krost, A; Berger, C; Moser, P; Bläsing, J; Dadgar, A; Hums, C; Hempel, T; Bastek, B; Veit, P; Christen, J

2011-01-01

Low-strained AlInN/GaN multilayers aimed as Bragg mirrors were grown by metal organic vapour phase epitaxy on GaN/Si(1 1 1). In such structures the upper AlInN/GaN interfaces show a considerable roughening on a nanometre scale whereas the lower ones appear flat as evaluated by cross-sectional electron and transmission electron microscopy. The roughening is attributed to a Stranski–Krastanov transition from two-dimensional layer-by-layer to three-dimensional island growth. In addition, a self-organized wavy-like surface morphology on a micrometre scale is observed in such structures which we discuss in terms of Grinfeld instability

Low energy intense electron beams with extra-low energy spread

International Nuclear Information System (INIS)

Aleksandrov, A.V.; Calabrese, R.; Ciullo, G.; Dikansky, N.S.; Guidi, V.; Kot, N.C.; Kudelainen, V.I.; Lamanna, G.; Lebedev, V.A.; Logachov, P.V.; Tecchio, L.; Yang, B.

1994-01-01

Maximum achievable intensity for low energy electron beams is a feature that is not very often compatible with low energy spread. We show that a proper choice of the source and the acceleration optics allows one to match them together. In this scheme, a GaAs photocathode excited by a single-mode infrared laser and adiabatic acceleration in fully magnetised optics enables the production of a low-energy-spread electron beam with relatively high intensity. The technological problems associated with the method are discussed together with its limitations. (orig.)

New development of the projected shell model and description of low-lying collective states in transitional nuclei

International Nuclear Information System (INIS)

Chen, F. Q.; Sun, Y.

2013-01-01

Description of the interplay between different nuclear shapes is an interesting but challenging problem. The original projected shell model (PSM) is applicable to nuclei with fixed shapes. We extend the PSM by superimposing (angular-momentum- and particle-number-) projected product wave functions in the spirit of the generate coordinate method. With this development, the Gd isotopes across the N = 90 region are studied, and the results indicate spectroscopic features of shape phase transition with varying neutron number. In order to illustrate the shape distribution in microscopic wave functions, we introduce a deformation representation and show that the collectively excited K π = 0 + states in the Gd isotopes have characters of shape vibration. (authors)

Isomorphism of Intransitive Linear Lie Equations

Directory of Open Access Journals (Sweden)

Jose Miguel Martins Veloso

2009-11-01

Full Text Available We show that formal isomorphism of intransitive linear Lie equations along transversal to the orbits can be extended to neighborhoods of these transversal. In analytic cases, the word formal is dropped from theorems. Also, we associate an intransitive Lie algebra with each intransitive linear Lie equation, and from the intransitive Lie algebra we recover the linear Lie equation, unless of formal isomorphism. The intransitive Lie algebra gives the structure functions introduced by É. Cartan.

Filiform Lie algebras of order 3

Science.gov (United States)

Navarro, R. M.

2014-04-01

The aim of this work is to generalize a very important type of Lie algebras and superalgebras, i.e., filiform Lie (super)algebras, into the theory of Lie algebras of order F. Thus, the concept of filiform Lie algebras of order F is obtained. In particular, for F = 3 it has been proved that by using infinitesimal deformations of the associated model elementary Lie algebra it can be obtained families of filiform elementary lie algebras of order 3, analogously as that occurs into the theory of Lie algebras [M. Vergne, "Cohomologie des algèbres de Lie nilpotentes. Application à l'étude de la variété des algèbres de Lie nilpotentes," Bull. Soc. Math. France 98, 81-116 (1970)]. Also we give the dimension, using an adaptation of the {sl}(2,{C})-module Method, and a basis of such infinitesimal deformations in some generic cases.

When is a lie more of a lie? Moral judgment mediates the relationship between perceived benefits of others and lie-labeling

Directory of Open Access Journals (Sweden)

Cantarero Katarzyna

2017-06-01

Full Text Available Lay perceptions of lying are argued to consist of a lie prototype. The latter was found to entail the intention to deceive, belief in falsity and falsity (Coleman & Kay, 1981. We proposed and found that the perceptions of the benefits of others are also an important factor that influences the extent, to which an act of intentional misleading someone to foster a false belief is labeled as a lie. Drawing from the intuitionist model of moral judgments (Haidt, 2001 we assumed that moral judgment of the behaviour would mediate the relationship. In Study 1 we analyzed data coming from a crosscultural project and found that perceived intention to benefit others was negatively related to lie labeling and that this relationship was mediated by the moral judgment of that act. In Study 2 we found that manipulating the benefits of others influenced the extent, to which an act of intentional misleading in order to foster a false belief is labeled as a lie and that, again, this relationship is mediated by the moral judgment of that act.

Microscopic description of the three major bands in transitional nuclei

International Nuclear Information System (INIS)

Pineda S, R.L.

1986-01-01

The author has extended the Coherent Phonon Model to the description of the three major bands in medium heavy transitional nuclei. The model assumes an axially symmetric deformed ground intrinsic state for the description of the low lying yrast levels of the ground band, while the excited bands are generated by intrinsic excitations of the ground band. Good angular momentum states are generated by the Peierls-Yoccoz angular momentum projection method

Electronic structure of Ge-2 and Ge-2 and thermodynamic properties of Ge-2 from all electron ab initio investigations and Knudsen effusion mass spectroscopic measurements

DEFF Research Database (Denmark)

Shim, Irene; Baba, M. Sai; Gingerich, K.A.

2002-01-01

The low-lying states of the molecule Ge-2 and of the ion Ge-2(-) have been investigated by all electron ab initio multiconfiguration self-consistent field (CASSCF) and multi-reference configuration interaction (MRCI) calculations. The relativistic corrections for the Darwin contact term and for t......The low-lying states of the molecule Ge-2 and of the ion Ge-2(-) have been investigated by all electron ab initio multiconfiguration self-consistent field (CASSCF) and multi-reference configuration interaction (MRCI) calculations. The relativistic corrections for the Darwin contact term...... excited states are presented. Thermal functions based on the theoretically determined molecular parameters were used to derive the thermodynamic properties of the Ge-2 molecule from new mass spectrometric equilibrium data. The literature value for the dissociation energy of Ge-2 has been re...

How to quantify the transition phase during golf swing performance: Torsional load affects low back complaints during the transition phase.

Science.gov (United States)

Sim, Taeyong; Choi, Ahnryul; Lee, Soeun; Mun, Joung Hwan

2017-10-01

The transition phase of a golf swing is considered to be a decisive instant required for a powerful swing. However, at the same time, the low back torsional loads during this phase can have a considerable effect on golf-related low back pain (LBP). Previous efforts to quantify the transition phase were hampered by problems with accuracy due to methodological limitations. In this study, vector-coding technique (VCT) method was proposed as a comprehensive methodology to quantify the precise transition phase and examine low back torsional load. Towards this end, transition phases were assessed using three different methods (VCT, lead hand speed and X-factor stretch) and compared; then, low back torsional load during the transition phase was examined. As a result, the importance of accurate transition phase quantification has been documented. The largest torsional loads were observed in healthy professional golfers (10.23 ± 1.69 N · kg -1 ), followed by professional golfers with a history of LBP (7.93 ± 1.79 N · kg -1 ), healthy amateur golfers (1.79 ± 1.05 N · kg -1 ) and amateur golfers with a history of LBP (0.99 ± 0.87 N · kg -1 ), which order was equal to that of the transition phase magnitudes of each group. These results indicate the relationship between the transition phase and LBP history and the dependency of the torsional load magnitude on the transition phase.

Lie Algebras and Integrable Systems

International Nuclear Information System (INIS)

Zhang Yufeng; Mei Jianqin

2012-01-01

A 3 × 3 matrix Lie algebra is first introduced, its subalgebras and the generated Lie algebras are obtained, respectively. Applications of a few Lie subalgebras give rise to two integrable nonlinear hierarchies of evolution equations from their reductions we obtain the nonlinear Schrödinger equations, the mKdV equations, the Broer-Kaup (BK) equation and its generalized equation, etc. The linear and nonlinear integrable couplings of one integrable hierarchy presented in the paper are worked out by casting a 3 × 3 Lie subalgebra into a 2 × 2 matrix Lie algebra. Finally, we discuss the elliptic variable solutions of a generalized BK equation. (general)

New trends in the optical and electronic applications of polymers containing transition-metal complexes.

Science.gov (United States)

Liu, Shu-Juan; Chen, Yang; Xu, Wen-Juan; Zhao, Qiang; Huang, Wei

2012-04-13

Polymers containing transition-metal complexes exhibit excellent optical and electronic properties, which are different from those of polymers with a pure organic skeleton and combine the advantages of both polymers and metal complexes. Hence, research about this class of polymers has attracted more and more interest in recent years. Up to now, a number of novel polymers containing transition-metal complexes have been exploited, and significant advances in their optical and electronic applications have been achieved. In this article, we summarize some new research trends in the applications of this important class of optoelectronic polymers, such as chemo/biosensors, electronic memory devices and photovoltaic devices. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Investigation of electronic transport properties of some liquid transition metals

Science.gov (United States)

Patel, H. P.; Sonvane, Y. A.; Thakor, P. B.

2018-04-01

We investigated electronic transport properties of some liquid transition metals (V, Cr, Mn, Fe, Co and Pt) using Ziman formalism. Our parameter free model potential which is realized on ionic and atomic radius has been incorporated with the Hard Sphere Yukawa (HSY) reference system to study the electronic transport properties like electrical resistivity (ρ), thermal conductivity (σ) and thermo electrical power (Q). The screening effect on aforesaid properties has been studied by using different screening functions. The correlations of our results and others data with in addition experimental values are profoundly promising to the researchers working in this field. Also, we conclude that our newly constructed parameter free model potential is capable to explain the aforesaid electronic transport properties.

Electron Emission by N6+ Ions Scattered at a Magnetized Iron Surface

International Nuclear Information System (INIS)

Solleder, B.; Lemell, C.; Burgdoerfer, J.; Tokesi, K.

2006-01-01

Complete text of publication follows. Magnetized materials are of considerable interest in the electronics industry (hard discs, spintronics, etc.). A detailed understanding of the properties of magnetized surfaces is therefore important to optimize technical applications. In the last decades, different experimental techniques have been developed to probe spin effects in magnetized materials. In this work the spin polarization of electrons emitted during the impact of N 6+ ions on a magnetized Fe surface is investigated. We study potential emission (PE) of electrons as well as secondary electron (SE) production and transport in the target with the help of Monte Carlo (MC) simulations. Spin dependence of electron transfer processes and of transport in the solid are included. Fig. 1 shows the results of our simulation for the energy distribution and spin polarization of emitted electrons in comparison with experimental data of Pfandzelter et al. [1] for the interaction of N 6+ ions with magnetized Fe. Electrons with energies higher than 200 eV are predominantly PE electrons, emitted close to the surface via autoionization (AI), Auger capture (AC) and Auger deexcitation (AD) channels. Low energy electrons are dominated by promoted, autoionized, and secondary electrons. The polarization of above surface electrons is determined by the high of the potential barrier separating projectile and target. At large distances, the barrier drops only slightly below the Fermi edge and enables transitions of electrons from this part of the band structure which has about 50% polarization. These electrons are transferred to high n states feeding promotion and AI processes between high lying states. Electrons emitted by these processes therefore reflect the polarization near the Fermi edge. Close to the surface, the barrier is low enough to allow for electron capture from the entire conduction band. K-Auger electrons are emitted in immediate vicinity of the surface and therefore mirror

Electron impact excitation of 1'S-2'S transition in helium

International Nuclear Information System (INIS)

Mohanty, J.P.; Singh, C.S.

1989-01-01

The modified variable-charge Coulomb-projected Born approximation is applied to electron impact excitation of 1 1 S-2 1 S transition in helium. The results are compared with other theoretical and experimental results. (author). 30 refs., 4 figs

Electron collisions with biomolecules

International Nuclear Information System (INIS)

McKoy, V; Winstead, C

2008-01-01

We report on results of recent studies of collisions of low-energy electrons with nucleobases and other DNA constituents. A particular focus of these studies has been the identification and characterization of resonances that play a role in electron attachment leading to strand breaks in DNA. Comparison of the calculated resonance positions with results of electron transmission measurements is quite encouraging. However, the higher-lying π* resonances of the nucleobases appear to be of mixed elastic and core-excited character. Such resonant channel coupling raises the interesting possibility that the higher π*resonances in the nucleobases may promote dissociation of DNA by providing doorway states to triplet excited states.

Electronic specific heat of transition metal carbides; Chaleur specifique electronique de carbures de metaux de transition

Energy Technology Data Exchange (ETDEWEB)

Conte, R [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

1964-07-15

The experimental results that make it possible to define the band structure of transition metal carbides having an NaCI structure are still very few. We have measured the electronic specific heat of some of these carbides of varying electronic concentration (TiC, either stoichiometric or non-stoichiometric, TaC and mixed (Ti, Ta) - C). We give the main characteristics (metallography, resistivity, X-rays) of our samples and we describe the low temperature specific heat apparatus which has been built. In one of these we use helium as the exchange gas. The other is set up with a mechanical contact. The two use a germanium probe for thermometer. The measurement of the temperature using this probe is described, as well as the various measurement devices. The results are presented in the form of a rigid band model and show that the density of the states at the Fermi level has a minimum in the neighbourhood of the group IV carbides. (author) [French] Les donnees experimentales permettant de preciser la structure de bandes des carbures de metaux de transition de structure NaCI sont encore peu.nombreuses. Nous avons mesure la chaleur specifique electronique de certains de ces carbures, de differentes concentrations electroniques (TiC stoechiometrique ou non, TaC et mixtes (Ti, Ta) - C). Nous donnons les principales caracteristiques (metallographie, resistivite, rayon X), de nos echantillons, et nous decrivons l'appareillage de chaleur specifique a basse temperature realise. Dans l'un nous utilisons l'helium comme gaz d'echange. L'autre est monte avec un contact mecanique. Les deux utilisent une sonde au germanium comme thermometre. La mesure de la resistance de cette sonde est decrite, ainsi que les differents montages de mesure. Les resultats, presentes dans un modele de bande rigide, font apparaitre que la densite des etats au niveau de Fermi presente un minimum au voisinage des carbures du groupe IV. (auteur)

Filiform Lie algebras of order 3

International Nuclear Information System (INIS)

Navarro, R. M.

2014-01-01

The aim of this work is to generalize a very important type of Lie algebras and superalgebras, i.e., filiform Lie (super)algebras, into the theory of Lie algebras of order F. Thus, the concept of filiform Lie algebras of order F is obtained. In particular, for F = 3 it has been proved that by using infinitesimal deformations of the associated model elementary Lie algebra it can be obtained families of filiform elementary lie algebras of order 3, analogously as that occurs into the theory of Lie algebras [M. Vergne, “Cohomologie des algèbres de Lie nilpotentes. Application à l’étude de la variété des algèbres de Lie nilpotentes,” Bull. Soc. Math. France 98, 81–116 (1970)]. Also we give the dimension, using an adaptation of the sl(2,C)-module Method, and a basis of such infinitesimal deformations in some generic cases

Plasma phase transition in dense hydrogen and electron-hole plasmas

CERN Document Server

Filinov, V S; Levashov, P R; Fortov, V E; Ebeling, W; Schlanges, M; Koch, S W

2003-01-01

Plasma phase transitions in dense hydrogen and electron-hole plasmas are investigated by direct path integral Monte Carlo methods. The phase boundary of the electron-hole liquid in germanium is calculated and is found to agree reasonably well with the known experimental results. Analogous behaviour is found for high-density hydrogen. For a temperature of T = 10 000 K it is shown that the internal energy is lowered due to droplet formation for densities between 10 sup 2 sup 3 cm sup - sup 3 and 10 sup 2 sup 4 cm sup - sup 3.

Nb{sub 3}Al thin film deposition for low-noise terahertz electronics

Energy Technology Data Exchange (ETDEWEB)

Dochev, D; Pavolotsky, A B; Belitsky, V; Olofsson, H [Group for Advanced Receiver Development and Onsala Space Observatory, Department of Radio- and Space Science, Chalmers University of Technology, SE 412 96 Gothenburg (Sweden)], E-mail: dimitar.dochev@chalmers.se

2008-02-01

Higher energy gap superconducting materials were always interesting for low-noise mixer applications such as superconductor-insulator-superconductor tunnel junctions (SIS) and hot-electron bolometer (HEB) used in sub-millimeter and terahertz parts of electro-magnetic spectrum. Here, we report a novel approach for producing Nb{sub 3}Al thin film by co-sputtering from two confocally arranged Nb and Al dc-magnetrons onto substrate heated up to 830 deg. C. Characterization of the deposited films revealed presence of the A15 phase and measured critical temperature was up to 15.7 K with the transition width 0.2-0.3 K for a 300 nm thick film. We measured the film critical magnetic field and studied influence of annealing on the film properties. We have investigated compositional depth profile of the deposited films by spectroscopy of reflected electrons.

Control over the magnetism and transition between high- and low-spin states of an adatom on trilayer graphene.

Science.gov (United States)

Zheng, Anmin; Gao, Guoying; Huang, Hai; Gao, Jinhua; Yao, Kailun

2017-05-31

Using density-functional theory, we investigate the electronic and magnetic properties of an adatom (Na, Cu and Fe) on ABA- and ABC-stacked (Bernal and rhombohedral) trilayer graphenes. In particular, we study the influence of an applied gate voltage on magnetism, as it modifies the electronic states of the trilayer graphene (TLG) as well as changes the adatom spin states. Our study performed for a choice of three different adatoms (Na, Cu, and Fe) shows that the nature of adatom-graphene bonding evolves from ionic to covalent in moving from an alkali metal (Na) to a transition metal (Cu or Fe). Applying an external electric field (EEF) to TLG systems with different stacking orders results in the transition between high- and low-spin states in the latter case (Cu, Fe) and induces a little of magnetism in the former (Na) without magnetism in the absence of an external electric field. Our study would be useful for controlled adatom magnetism and (organic) spintronic applications in nanotechnology.

Wigner-like crystallization of Anderson-localized electron systems with low electron densities

CERN Document Server

Slutskin, A A; Pepper, M

2002-01-01

We consider an electron system under conditions of strong Anderson localization, taking into account interelectron long-range Coulomb repulsion. We establish that at sufficiently low electron densities and sufficiently low temperatures the Coulomb electron interaction brings about ordering of the Anderson-localized electrons into a structure that is close to an ideal (Wigner) crystal lattice, provided the dimension of the system is > 1. This Anderson-Wigner glass (AWG) is a new macroscopic electron state that, on the one hand, is beyond the conventional Fermi glass concept, and on the other hand, qualitatively differs from the known 'plain' Wigner glass (inherent in self-localized electron systems) in that the random slight electron displacements from the ideal crystal sites essentially depend on the electron density. With increasing electron density the AWG is found to turn into the plain Wigner glass or Fermi glass, depending on the width of the random spread of the electron levels. It is shown that the res...

Recent measurements concerning uranium hexafluoride-electron collision processes

International Nuclear Information System (INIS)

Trajmar, S.; Chutjian, A.; Srivastava, S.; Williams, W.; Cartwright, D.C.

1976-01-01

Scattering of electrons by UF 6 molecule was studied at impact energies ranging from 5 to 100 eV and momentum transfer, elastic and inelastic scattering cross sections were determined. The measurements also yielded spectroscopic information which made possible to extend the optical absorption cross sections from 2000 to 435A. It was found that UF 6 is a very strong absorber in the vacuum UV region. No transitions were found to lie below the onset of the optically detected 3.0 eV feature

On lying and deceiving.

OpenAIRE

Bakhurst, D

1992-01-01

This article challenges Jennifer Jackson's recent defence of doctors' rights to deceive patients. Jackson maintains there is a general moral difference between lying and intentional deception: while doctors have a prima facie duty not to lie, there is no such obligation to avoid deception. This paper argues 1) that an examination of cases shows that lying and deception are often morally equivalent, and 2) that Jackson's position is premised on a species of moral functionalism that misconstrue...

Phase stability and electronic structure of transition-metal aluminides

International Nuclear Information System (INIS)

Carlsson, A.E.

1992-01-01

This paper will describe the interplay between die electronic structure and structural energetics in simple, complex, and quasicrystalline Al-transition metal (T) intermetallics. The first example is the Ll 2 -DO 22 competition in Al 3 T compounds. Ab-initio electronic total-energy calculations reveal surprisingly large structural-energy differences, and show that the phase stability of both stoichiometric and ternary-substituted compounds correlates closely with a quasigap in the electronic density of states (DOS). Secondly, ab-initio calculations for the structural stability of the icosahedrally based Al 12 W structure reveal similar quasigap effects, and provide a simple physical explanation for the stability of the complex aluminide structures. Finally, parametrized tight-binding model calculations for the Al-Mn quasicrystal reveal a large spread in the local Mn DOS behavior, and support a two-site model for the quasicrystal's magnetic behavior

Microscopic mean-field boson approach to the shape transition in Sm isotopes

International Nuclear Information System (INIS)

Kuchta, R.

1988-01-01

The phase transition from spherical to deformed shape in Sm 146-156 nuclei is analyzed within the mean-field approximation applied to the Dyson image of the shell-model Hamiltonian. No quasiparticle transformation is involved in the present approach and the Pauli principle in the physical boson subspace is properly taken into account. The low-lying spectra, B(E2; O 1 + →2 + ) probabilities and the corresponding densities of electromagnetic transitions are calculated. The results provide a reasonable explanation of the phase transition in the Sm isotopes. The role of bosons with different multipolarity is investigated and it is found that g-bosons (J=4) cannot be neglected in the transition region. Comparison of the present results with those of other approaches is given as well

Low carbon transition and sustainable development path of tourism industry

Science.gov (United States)

Zhu, Hongbing; Zhang, Jing; Zhao, Lei; Jin, Shenglang

2017-05-01

The low carbon transition is as much a transformative technology shift as it represents a response to global environment challenges. The low carbon paradigm presents a new direction of change for tourism industry. However, the lack of theoretical frameworks on low carbon transformation in tourism industry context provides a significant knowledge gap. This paper firstly investigates the relationships between low carbon and sustainable development, followed by exploring the existing challenges of tourism sustainable development. At last, this paper presents a sustainable development path framework for low carbon transition of tourism industry, which include accelerating deployment of renewable energy, energy-saving green building construction, improving green growth investment, and adopting a sustainable consumption and production system, in order to promote energy and water efficiency, waste management, GHG emissions mitigation and eventually enhance its sustainability.

Electron form factors of deformable nuclei

International Nuclear Information System (INIS)

Tartakovskii, V.K.; Isupov, V.Yu.

1988-01-01

Using the smallness of the deformation parameter of the nucleus, we obtain simple explicit expressions for the form factors of electroexcitation of the low-lying rotation-vibration states of light, deformable, even-even nuclei. The expressions satisfactorily describe the experimental data on the excitation of collective nuclear states by the inelastic scattering of fast electrons

Low-temperature structural phase transition in deuterated and protonated lithium acetate dihydrate

Energy Technology Data Exchange (ETDEWEB)