WorldWideScience

Sample records for liquid fuel sprays

  1. Autoignition of liquid-fuel sprays

    International Nuclear Information System (INIS)

    Mitzutani, Y.

    1991-01-01

    This paper reports on the published autoignition data of liquid fuel sprays that were extensively reviewed by classifying them into the following three categories; liquid fuels injected into a stagnant hot atmosphere, liquid fuels injected into a hot air stream (vitiated or unvitiated), and droplet cluster ignited behind an incident or reflected shock. Comparison of these data with the counterparts of gaseous fuels and single droplets revealed that it was the ignition process dominated by droplet evaporation whereas it was the one dominated by chemical kinetics. It consisted, depending on the experimental condition, of the data and of the ignition process dominated by the shattering of droplets by an incident shock. In addition, theoretical works on spray autoignition were reviewed, pointing out that they were still far from universally predicting the ignition delays of liquid fuel sprays

  2. Quantifying liquid boundary and vapor distributions in a fuel spray by rainbow schlieren deflectometry.

    Science.gov (United States)

    Taber Wanstall, C; Agrawal, Ajay K; Bittle, Joshua A

    2017-10-20

    The rainbow schlieren deflectometry (RSD) technique is used to determine the liquid boundary and the fuel volume fraction distributions in the vapor region of a high-pressure fuel spray. Experiments were conducted in a constant pressure flow vessel, whereby a customized single-hole common-rail diesel injector is used to introduce n-heptane fuel into a coflow of low-speed ambient air at two different test conditions. Only the quasi-steady period of the fuel spray is considered, and multiple injections are performed to acquire statistically significant data at an image acquisition rate of 20 kHz. An algorithm to identify the liquid boundary using intensity recorded by the RSD images is presented. The results are compared against measurements obtained by the Mie scattering technique. Results demonstrate that the RSD can be a powerful optical diagnostics technique to simultaneously quantify both the vapor and liquid regions in the high-pressure fuel sprays.

  3. Novel method for the measurement of liquid film thickness during fuel spray impingement on surfaces.

    Science.gov (United States)

    Henkel, S; Beyrau, F; Hardalupas, Y; Taylor, A M K P

    2016-02-08

    This paper describes the development and application of a novel optical technique for the measurement of liquid film thickness formed on surfaces during the impingement of automotive fuel sprays. The technique makes use of the change of the light scattering characteristics of a metal surface with known roughness, when liquid is deposited. Important advantages of the technique over previously established methods are the ability to measure the time-dependent spatial distribution of the liquid film without a need to add a fluorescent tracer to the liquid, while the measurement principle is not influenced by changes of the pressure and temperature of the liquid or the surrounding gas phase. Also, there is no need for non-fluorescing surrogate fuels. However, an in situ calibration of the dependence of signal intensity on liquid film thickness is required. The developed method can be applied to measure the time-dependent and two-dimensional distribution of the liquid fuel film thickness on the piston or the liner of gasoline direct injection (GDI) engines. The applicability of this technique was evaluated with impinging sprays of several linear alkanes and alcohols with different thermo-physical properties. The surface temperature of the impingement plate was controlled to simulate the range of piston surface temperatures inside a GDI engine. Two sets of liquid film thickness measurements were obtained. During the first set, the surface temperature of the plate was kept constant, while the spray of different fuels interacted with the surface. In the second set, the plate temperature was adjusted to match the boiling temperature of each fuel. In this way, the influence of the surface temperature on the liquid film created by the spray of different fuels and their evaporation characteristics could be demonstrated.

  4. Numerical modelling of fuel sprays

    Energy Technology Data Exchange (ETDEWEB)

    Bergstroem, C.

    1999-06-01

    The way the fuel is introduced into the combustion chamber is one of the most important parameters for the power output and the generation of emissions in the combustion of liquid fuels. The interaction between the turbulent gas flow field and the liquid fuel droplets, the vaporisation of them and the mixing of the gaseous fuel with the ambient air that are vital parameters in the combustion process. The use of numerical calculations is an important tool to better understand these complex interacting phenomena. This thesis reports on the numerical modelling of fuel sprays in non-reacting cases using an own developed spray module. The spray module uses the stochastic parcel method to represent the spray. The module was made in such manner that it could by coupled with different gas flow solver. Results obtained from four different gas flow solvers are presented in the thesis, including the use of two different kinds of turbulence models. In the first part the spray module is coupled with a k-{eta} based 2-D cylindrical gas flow solver. A thorough sensitivity analysis was performed on the spray and gas flow solver parameters, such as grid size dependence and sensitivity to initial values of k-{eta}. The results of the spray module were also compared to results from other spray codes, e.g. the well known KIVA code. In the second part of this thesis the spray was injected into a turbulent and fully developed crossflow studied. The spray module was attached to a LES (Large Eddy Simulation) based flow solvers enabling the study of the complex structures and time dependent phenomena involved in spray in crossflows. It was found that the spray performs an oscillatory motion and that the Strouhal number in the wake was about 0.1. Different spray breakup models were evaluated by comparing with experimental results 66 refs, 56 figs

  5. Investigation of Real-Time Two-Dimensional Visualization of Fuel Spray Liquid/Vapor Distribution via Exciplex Fluorescence.

    Science.gov (United States)

    1987-08-30

    EXCIPLEX FLUORESCENCE ~N 0FINAL REPORT 00 JAMES F. VERDIECK AND ARTHUR A. ROTUNNO UNITED TECHNOLOGIES RESEARCH CENTER 0 AND LYNN A. MELTON D I UNIVERSITY...DOCUMENTATION. "NWA 0. INVESTIGATION OF REAL-TINE TWO-DIMENSIONAL VISUALIZATION OF FUEL SPRAY LIQUID/VAPOR DISTRIBUTION VIA EXCIPLEX FLUORESCENCE FINAL...Spray Liquid/Vapor Distribution Via Exciplex Fluorescen , - 12. PERSONAL AUTHOR(S) J. F. Yeardierk. A- A. Rnriiunn-l L_ A. Millo - 13a TYPE OF REPORT

  6. Characterization of Liquid Fuel Evaporation of a Lifted Methanol Spray Flame in a Vitiated Coflow Burner

    Science.gov (United States)

    Cabra, Ricardo; Dibble, Robert W.; Chen, Jyh-Yuan

    2002-01-01

    An experimental investigation of lifted spray flames in a coflow of hot, vitiated gases is presented. The vitiated coflow burner is a spray flame that issues into a coaxial flow of hot combustion products from a lean, premixed H2/Air flame. The spray flame in a vitiated coflow emulates the combustion that occurs in many advanced combustors without the detailed fluid mechanics. Two commercially available laser diagnostic systems are used to characterize the spray flame and to demonstrate the vitiated coflow burner's amenability to optical investigation. The Ensemble Particle Concentration and Size (EPCS) system is used to measure the path-average droplet size distribution and liquid volume fraction at several axial locations while an extractive probe instrument named the Real-time Fuel-air Analyzer (RFA) is used to measure the air to fuel ratio downstream of the spray nozzle with high temporal and spatial resolution. The effect of coflow conditions (stoichiometry) and dilution of the fuel with water was studied with the EPCS optical system. As expected, results show that water retards the evaporation and combustion of fuels. Measurements obtained by the RFA extractive probe show that while the Delavan manufactured nozzle does distribute the fuel over the manufacturer specified spray angle, it unfortunately does not distribute the fuel uniformly, providing conditions that may result in the production of unwanted NOx. Despite some limitations due to the inherent nature of the experimental techniques, the two diagnostics can be readily applied to spray flames in the vitiated coflow environment.

  7. Linear Stability Analysis of Laminar Premixed Fuel-Rich Double-Spray Flames

    Directory of Open Access Journals (Sweden)

    Noam Weinberg

    2014-03-01

    Full Text Available This paper considers the stability of a double-spray premixed flame formed when both fuel and oxidizer are initially present in the form of sprays of evaporating liquid droplets. To simplify the inherent complexity that characterizes the analytic solution of multi-phase combustion processes, the analysis is restricted to fuel-rich laminar premixed double-spray flames, and assumes a single-step global chemical reaction mechanism. Steady-state solutions are obtained and the sensitivity of the flame temperature and the flame propagating velocity to the initial liquid fuel and/or oxidizer loads are established. The stability analysis revealed an increased proneness to cellular instability induced by the presence of the two sprays, and for the fuel-rich case considered here the influence of the liquid oxidizer was found to be more pronounced than that of the liquid fuel. Similar effects were noted for the neutral pulsating stability boundaries. The impact of unequal latent heats of vaporization is also investigated and found to be in keeping with the destabilizing influence of heat loss due to droplet evaporation. It should be noted that as far as the authors are aware no experimental evidence is available for (at least validation of the predictions. However, they do concur in a general and reasonable fashion with independent experimental evidence in the literature of the behavior of single fuel spray laminar premixed flames.

  8. Comparison of Global Sizing Velocimetry and Phase Doppler Anemometry measurements of alternative jet fuel sprays

    Science.gov (United States)

    Sadr, Reza; Kannaiyan, Kumaran

    2013-11-01

    Atomization plays a crucial precursor role in liquid fuel combustion that directly affects the evaporation, mixing, and emission levels. Laser diagnostic techniques are often used to study the spray characteristics of liquid fuels. The objective of this work is to compare the spray measurements of Gas-to Liquid (GTL) jet fuels obtained using Global Sizing Velocimetry (GSV) and Phase Doppler Anemometry (PDA) techniques at global and local levels, respectively. The chemical and physical properties of GTL fuels are different from conventional jet fuels, owing to the difference in their production methodology. In this work, the experimental facility, the measurement techniques, and spray characteristics of two different GTL fuels are discussed and compared with those of Jet A-1 fuel. Results clearly demonstrate that although the global measurement gives an overall picture of the spray, fine details are obtained only through local measurements and complement in gaining more inferences into the spray characteristics. The results also show a close similarity in spray characteristics between GTL and Jet A-1 fuels. Funded by Qatar Science and Technology Park.

  9. Experimental investigation of spray characteristics of alternative aviation fuels

    International Nuclear Information System (INIS)

    Kannaiyan, Kumaran; Sadr, Reza

    2014-01-01

    Highlights: • Physical properties of GTL fuel are different from those of conventional jet fuels. • Spray characteristics of GTL and Jet A-1 fuels are experimentally investigated using phase Doppler anemometry. • Regions near the nozzle are influenced by differences in fuel physical properties. • Spray characteristics of GTL can be predicted by empirical relations developed for conventional jet fuels. - Abstract: Synthetic fuels derived from non-oil feedstock are gaining importance due to their cleaner combustion characteristics. This work investigates spray characteristics of two Gas-to-Liquid (GTL) synthetic jet fuels from a pilot-scale pressure swirl nozzle and compares them with those of the conventional Jet A-1 fuel. The microscopic spray parameters are measured at 0.3 and 0.9 MPa injection pressures at several points in the spray using phase Doppler anemometry. The results show that the effect of fuel physical properties on the spray characteristics is predominantly evident in the regions close to the nozzle exit at the higher injection pressure. The lower viscosity and surface tension of GTL fuel seems to lead to faster disintegration and dispersion of the droplets when compared to those of Jet A-1 fuel under atmospheric conditions. Although the global characteristics of the fuels are similar, the effects of fuel properties are evident on the local spray characteristics at the higher injection pressure

  10. Study of ethanol and gasoline fuel sprays using mie-scatter and schlieren imaging

    Science.gov (United States)

    Bouchard, Lauren; Bittle, Joshua; Puzinauskas, Paul

    2016-11-01

    Many cars today are capable of running on both gasoline and ethanol, however it is not clear how well optimized the engines are for the multiple fuels. This experiment looks specifically at the fuel spray in a direct injection system. The length and angle of direct injection sprays were characterized and a comparison between ethanol and gasoline sprays was made. Fuels were tested using a modified diesel injector in a test chamber at variable ambient pressures and temperatures in order to simulate both high and low load combustion chamber conditions. Rainbow schlieren and mie-scatter imaging were both used to investigate the liquid and vapor portions of the sprays. The sprays behaved as expected with temperature and pressure changes. There was no noticeable fuel effect on the liquid portion of the spray (mie-scatter), though the gasoline vapor spray angles were wider than ethanol spray angles (possible a result of the distillation curves of the two fuels). Funding from NSF REU site Grant EEC 1358991 is greatly appreciated.

  11. Optical fuel spray measurements

    Energy Technology Data Exchange (ETDEWEB)

    Hillamo, H.

    2011-07-01

    Diesel fuel sprays, including fuel/air mixing and the physics of two-phase jet formation, are discussed in the thesis. The fuel/air mixing strongly affects emissions formation in spray combustion processes where the local combustion conditions dictate the emission formation. This study comprises optical measurements both in pressurized spray test rigs and in a running engine.The studied fuel injection was arranged with a common rail injection system and the injectors were operated with a solenoid-based injection valve. Both marine and heavy-duty diesel engine injectors were used in the study. Optical fuel spray measurements were carried out with a laser-based double-framing camera system. This kind of equipments is usually used for flow field measurements with Particle Image Velocimetry technique (PIV) as well as for backlight imaging. Fundamental fuel spray properties and spray formation were studied in spray test rigs. These measurements involved studies of mixing, atomization, and the flow field. Test rig measurements were used to study the effect of individual injection parameters and component designs. Measurements of the fuel spray flow field, spray penetration, spray tip velocity, spray angle, spray structure, droplet accumulation, and droplet size estimates are shown. Measurement campaign in a running optically accessible large-bore medium-speed engine was also carried out. The results from engine tests were compared with equivalent test rig measurements, as well as computational results, to evaluate the level of understanding of sprays. It was shown that transient spray has an acceleration and a deceleration phase. Successive flow field measurements (PIV) in optically dense diesel spray resulted in local and average velocity data of diesel sprays. Processing fuel spray generates a flow field to surrounding gas and entrainment of surrounding gas into fuel jet was also seen at the sides of the spray. Laser sheet imaging revealed the inner structure of diesel

  12. Quantitative liquid and vapor distribution measurements in evaporating fuel sprays using laser-induced exciplex fluorescence

    International Nuclear Information System (INIS)

    Fansler, Todd D; Drake, Michael C; Gajdeczko, Boguslaw; Düwel, Isabell; Koban, Wieland; Zimmermann, Frank P; Schulz, Christof

    2009-01-01

    Fully quantitative two-dimensional measurements of liquid- and vapor-phase fuel distributions (mass per unit volume) from high-pressure direct-injection gasoline injectors are reported for conditions of both slow and rapid vaporization in a heated, high-pressure spray chamber. The measurements employ the coevaporative gasoline-like fluorobenzene (FB)/diethylmethylamine (DEMA)/hexane exciplex tracer/fuel system. In contrast to most previous laser-induced exciplex-fluorescence (LIEF) experiments, the quantitative results here include regions in which liquid and vapor fuel coexist (e.g. near the injector exit). A unique aspect is evaluation of both vapor- and liquid-phase distributions at varying temperature and pressure using only in situ vapor-phase fluorescence calibration measurements at room temperature and atmospheric pressure. This approach draws on recent extensive measurements of the temperature-dependent spectroscopic properties of the FB–DEMA exciplex system, in particular on knowledge of the quantum efficiencies of the vapor-phase and liquid-phase (exciplex) fluorescence. In addition to procedures necessary for quantitative measurements, we discuss corrections for liquid–vapor crosstalk (liquid fluorescence that overlaps the vapor-fluorescence bandpass), the unknown local temperature due to vaporization-induced cooling, and laser-sheet attenuation by scattering and absorption

  13. Effect of Fuel Additives on Spray Performance of Alternative Jet Fuels

    Science.gov (United States)

    Kannaiyan, Kumaran; Sadr, Reza

    2015-11-01

    Role of alternative fuels on reducing the combustion pollutants is gaining momentum in both land and air transport. Recent studies have shown that addition of nanoscale metal particles as fuel additives to liquid fuels have a positive effect not only on their combustion performance but also in reducing the pollutant formation. However, most of those studies are still in the early stages of investigation with the addition of nanoparticles at low weight percentages. Such an addition can affect the hydrodynamic and thermo-physical properties of the fuel. In this study, the near nozzle spray performance of gas-to-liquid jet fuel with and without the addition of alumina nanoparticles are investigated at macro- and microscopic levels using optical diagnostic techniques. At macroscopic level, the addition of nanoparticles is seen to enhance the sheet breakup process when compared to that of the base fuel. Furthermore, the microscopic spray characteristics such as droplet size and velocity are also found to be affected. Although the addition of nanoscale metal particles at low weight percentages does not affect the bulk fluid properties, the atomization process is found to be affected in the near nozzle region. Funded by Qatar National Research Fund.

  14. Effect of aviation fuel type and fuel injection conditions on the spray characteristics of pressure swirl and hybrid air blast fuel injectors

    Science.gov (United States)

    Feddema, Rick

    Feddema, Rick T. M.S.M.E., Purdue University, December 2013. Effect of Aviation Fuel Type and Fuel Injection Conditions on the Spray Characteristics of Pressure Swirl and Hybrid Air Blast Fuel Injectors. Major Professor: Dr. Paul E. Sojka, School of Mechanical Engineering Spray performance of pressure swirl and hybrid air blast fuel injectors are central to combustion stability, combustor heat management, and pollutant formation in aviation gas turbine engines. Next generation aviation gas turbine engines will optimize spray atomization characteristics of the fuel injector in order to achieve engine efficiency and emissions requirements. Fuel injector spray atomization performance is affected by the type of fuel injector, fuel liquid properties, fuel injection pressure, fuel injection temperature, and ambient pressure. Performance of pressure swirl atomizer and hybrid air blast nozzle type fuel injectors are compared in this study. Aviation jet fuels, JP-8, Jet A, JP-5, and JP-10 and their effect on fuel injector performance is investigated. Fuel injector set conditions involving fuel injector pressure, fuel temperature and ambient pressure are varied in order to compare each fuel type. One objective of this thesis is to contribute spray patternation measurements to the body of existing drop size data in the literature. Fuel droplet size tends to increase with decreasing fuel injection pressure, decreasing fuel injection temperature and increasing ambient injection pressure. The differences between fuel types at particular set conditions occur due to differences in liquid properties between fuels. Liquid viscosity and surface tension are identified to be fuel-specific properties that affect the drop size of the fuel. An open aspect of current research that this paper addresses is how much the type of aviation jet fuel affects spray atomization characteristics. Conventional aviation fuel specifications are becoming more important with new interest in alternative

  15. Effect of W/O Emulsion Fuel Properties on Spray Combustion

    Science.gov (United States)

    Ida, Tamio; Fuchihata, Manabu; Takeda, Shuuco

    This study proposes a realizable technology for an emulsion combustion method that can reduce environmental loading. This paper discusses the effect on spray combustion for W/O emulsion fuel properties with an added agent, and the ratio between water and emulsifier added to a liquid fuel. The addition of water or emulsifier to a liquid fuel affected the spray combustion by causing micro-explosions in the flame due to geometric changes in the sprayed flame and changes to the temperature distribution. Experimental results revealed that the flame length shortened by almost 40% upon the addition of the water. Furthermore, it was found that water was effective in enhancing combustion due to its promoting micro-explosions. Results also showed that when the emulsifier was added to the spray flame, the additive burned in the flame's wake, producing a bright red flame. The flame length was observed to be long as a result. The micro-explosion phenomenon, caused by emulsifier dosage differences, was observed using time-dependent images at a generated frequency and an explosion scale with a high-speed photography method. Results indicated that the micro-explosion phenomenon in the W/O emulsion combustion method effectively promoted the combustion reaction and suppressed soot formation.

  16. Experimental characterisation of sprays resulting from impacts of liquid-containing projectiles

    Energy Technology Data Exchange (ETDEWEB)

    Hostikka, Simo, E-mail: simo.hostikka@aalto.fi [Aalto University, Espoo (Finland); Silde, Ari; Sikanen, Topi; Vepsä, Ari; Paajanen, Antti [VTT Technical Research Centre of Finland Ltd, Espoo (Finland); Honkanen, Markus [Pixact Oy, Tampere (Finland)

    2015-12-15

    Highlights: • Detailed characterisation of sprays resulting from the impacts of water-filled metal projectiles on a hard wall. • Experimental measurements of spray speed, direction and droplet size. • Detailed analysis of overall spray evolution. • The spray characterisation information can be used in CFD analyses of aircraft impact fires. - Abstract: Modelling and analysing fires following aircraft impacts requires information about the behaviour of liquid fuel. In this study, we investigated sprays resulting from the impacts of water-filled metal projectiles on a hard wall. The weights of the projectiles were in the range of 38–110 kg, with 8.6–68 kg water, and the impact speeds varied between 96 and 169 m/s. The overall spray behaviour was observed with high-speed video cameras. Ultra-high-speed cameras were used in backlight configuration for measuring the droplet size and velocity distributions. The results indicate that the liquid leaves the impact position as a thin sheet of spray in a direction perpendicular to the projectile velocity. The initial spray speeds were 1.5–2.5 times the impact speed, and the Sauter mean diameters were in the 147–344 μm range. This data can be used as boundary conditions in CFD fire analyses, considering the two-phase fuel flow. The overall spray observations, including the spray deceleration rate, can be used for validating the model.

  17. Numerical analysis of spray characteristics of dimethyl ether and diethyl ether fuel

    International Nuclear Information System (INIS)

    Mohan, Balaji; Yang, Wenming; Yu, Wenbin; Tay, Kun Lin

    2017-01-01

    Highlights: • Thermo-physical properties of liquid DME and DEE are reported. • Ether fuels tend to cavitate higher compared to that of diesel fuel. • Spray tip penetration and SMD are found to be lesser for ether fuels. • Ether fuels shows excellent atomization behavior. - Abstract: In this work, the spray characteristics of ether fuels such as dimethyl ether (DME) and diethyl ether (DEE) have been numerically investigated using KIVA-4 CFD code. A new hybrid spray model developed by coupling the standard KHRT model to cavitation sub model was used. The detailed thermo-physical properties of ether fuels have been predicted and validated with experimental results available from literature. The cavitation inception inside the injector nozzle hole has been studied for ether fuels in comparison with diesel fuel. It was found that ether fuels cavitates higher compared to that of conventional diesel fuel because of its low viscosity. The spray tip penetration of diesel fuel was longer than that of ether fuels due to high viscosity and density of diesel fuel. Ether fuels characterized by low Ohnesorge number and high Reynolds number showed better atomization behavior compared to that of the diesel fuel.

  18. Fuel temperature influence on diesel sprays in inert and reacting conditions

    International Nuclear Information System (INIS)

    Payri, Raul; García-Oliver, Jose M.; Bardi, Michele; Manin, Julien

    2012-01-01

    The detailed knowledge of the evaporation–combustion process of the Diesel spray is a key factor for the development of robust injection strategies able to reduce the pollutant emissions and keep or increase the combustion efficiency. In this work several typical measurement applied to the diesel spray diagnostic (liquid length, lift-off length and ignition delay) have been employed in a novel continuous flow test chamber that allows an accurate control on a wide range of thermodynamic test conditions (up to 1000 K and 15 MPa). A step forward in the control of the test boundary conditions has been done employing a special system to study the fuel temperature effect on the evaporation and combustion of the spray. The temperature of the injector body has been controlled with a thermostatic system and the relationship between injector body and fuel temperature has been observed experimentally. Imaging diagnostics have been employed to visualize the liquid phase penetration in evaporative/inert conditions and, lift-off length and ignition delay in reactive condition. The results underline a clear influence of the injector body temperature on both conditions, evaporative and, in a lesser degree, reactive; finally the physical models found in the literature have been compared with the results obtained experimentally. - Highlights: ► The effect of the fuel temperature is substantial on liquid length (up to 15%). ► Fuel temperature has low effect but still appreciable on LOL and ignition delay. ► Theoretical one dimensional spray models are able to reproduce the experimental results with good accuracy.

  19. Modelling of fuel spray and combustion in diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Huttunen, M T; Kaario, O T [VTT Energy, Espoo (Finland)

    1998-12-31

    Fuel spray and air motion characteristics and combustion in direct injection (DI) diesel engines was studied using computational models of the commercial CFD-code FIRE. Physical subprocesses modelled included Lagrangian spray droplet movement and behaviour (atomisation, evaporation and interaction of spray droplets) and combustion of evaporated liquid spray in the gas phase. Fuel vapour combustion rate was described by the model of Magnussen and Hjertager. The standard k,{epsilon}-model was used for turbulence. In order to be able to predict combustion accurately, the fuel spray penetration should be predicted with reasonable accuracy. In this study, the standard drag coefficient had to be reduced in order to match the computed penetration to the measured one. In addition, the constants in the submodel describing droplet breakup also needed to be adjusted for closer agreement with the measurements. The characteristic time scale of fuel consumption rate k/C{sub R} {epsilon} strongly influenced the heat release and in-cylinder pressure. With a value around 2.0 to 5.0 for C{sub R}, the computed in-cylinder pressure during the compression stroke agreed quite well with the measurements. On the other hand, the in-cylinder pressure was underpredicted during the expansion stroke. This is partly due to the fact that hydrocarbon fuel combustion was modelled as a one-step reaction reading to CO{sub 2} and H{sub 2}O and inadequate description of the mixing of reactants and combustion products. (author) 16 refs.

  20. Modelling of fuel spray and combustion in diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Huttunen, M.T.; Kaario, O.T. [VTT Energy, Espoo (Finland)

    1997-12-31

    Fuel spray and air motion characteristics and combustion in direct injection (DI) diesel engines was studied using computational models of the commercial CFD-code FIRE. Physical subprocesses modelled included Lagrangian spray droplet movement and behaviour (atomisation, evaporation and interaction of spray droplets) and combustion of evaporated liquid spray in the gas phase. Fuel vapour combustion rate was described by the model of Magnussen and Hjertager. The standard k,{epsilon}-model was used for turbulence. In order to be able to predict combustion accurately, the fuel spray penetration should be predicted with reasonable accuracy. In this study, the standard drag coefficient had to be reduced in order to match the computed penetration to the measured one. In addition, the constants in the submodel describing droplet breakup also needed to be adjusted for closer agreement with the measurements. The characteristic time scale of fuel consumption rate k/C{sub R} {epsilon} strongly influenced the heat release and in-cylinder pressure. With a value around 2.0 to 5.0 for C{sub R}, the computed in-cylinder pressure during the compression stroke agreed quite well with the measurements. On the other hand, the in-cylinder pressure was underpredicted during the expansion stroke. This is partly due to the fact that hydrocarbon fuel combustion was modelled as a one-step reaction reading to CO{sub 2} and H{sub 2}O and inadequate description of the mixing of reactants and combustion products. (author) 16 refs.

  1. Experimental study on spray characteristics of alternate jet fuels using Phase Doppler Anemometry

    Science.gov (United States)

    Kannaiyan, Kumaran; Sadr, Reza

    2013-11-01

    Gas-to-Liquid (GTL) fuels have gained global attention due to their cleaner combustion characteristics. The chemical and physical properties of GTL jet fuels are different from conventional jet fuels owing to the difference in their production methodology. It is important to study the spray characteristics of GTL jet fuels as the change of physical properties can affect atomization, mixing, evaporation and combustion process, ultimately affecting emission process. In this work, spray characteristics of two GTL synthetic jet fuels are studied using a pressure-swirl nozzle at different injection pressures and atmospheric ambient condition. Phase Doppler Anemometry (PDA) measurements of droplet size and velocity are compared with those of regular Jet A-1 fuel at several axial and radial locations downstream of the nozzle exit. Experimental results show that although the GTL fuels have different physical properties such as viscosity, density, and surface tension, among each other the resultant change in the spray characteristics is insignificant. Furthermore, the presented results show that GTL fuel spray characteristics exhibit close similarity to those of Jet A-1 fuel. Funded by Qatar Science and Technology Park.

  2. High Resolution Numerical Simulations of Primary Atomization in Diesel Sprays with Single Component Reference Fuels

    Science.gov (United States)

    2015-09-01

    NC. 14. ABSTRACT A high-resolution numerical simulation of jet breakup and spray formation from a complex diesel fuel injector at diesel engine... diesel fuel injector at diesel engine type conditions has been performed. A full understanding of the primary atomization process in diesel fuel... diesel liquid sprays the complexity is further compounded by the physical attributes present including nozzle turbulence, large density ratios

  3. Role of Oxides and Porosity on High-Temperature Oxidation of Liquid-Fueled HVOF Thermal-Sprayed Ni50Cr Coatings

    Science.gov (United States)

    Song, B.; Bai, M.; Voisey, K. T.; Hussain, T.

    2017-02-01

    High chromium content in Ni50Cr thermally sprayed coatings can generate a dense and protective scale at the surface of coating. Thus, the Ni50Cr coating is widely used in high-temperature oxidation and corrosion applications. A commercially available gas atomized Ni50Cr powder was sprayed onto a power plant steel (ASME P92) using a liquid-fueled high velocity oxy-fuel thermal spray with three processing parameters in this study. Microstructure of as-sprayed coatings was examined using oxygen content analysis, mercury intrusion porosimetry, scanning electron microscope (SEM), energy-dispersive x-ray spectroscopy (EDX) and x-ray diffraction (XRD). Short-term air oxidation tests (4 h) of freestanding coatings (without boiler steel substrate) in a thermogravimetric analyzer at 700 °C were performed to obtain the kinetics of oxidation of the as-sprayed coating. Long-term air oxidation tests (100 h) of the coated substrates were performed at same temperature to obtain the oxidation products for further characterization in detail using SEM/EDX and XRD. In all samples, oxides of various morphologies developed on top of the Ni50Cr coatings. Cr2O3 was the main oxidation product on the surface of all three coatings. The coating with medium porosity and medium oxygen content has the best high-temperature oxidation performance in this study.

  4. Spray characteristics and liquid distribution of multi-hole effervescent atomisers for industrial burners

    International Nuclear Information System (INIS)

    Jedelský, Jan; Jícha, Miroslav

    2016-01-01

    Highlights: • The multi-hole (mh) spray morphology is very similar to that of single-hole nozzles. • Unsteady spray was found at low pressure and low gas-to-liquid-ratio (GLR) values. • Cone angle variation in mh spray with pressure and GLR depends on the exit nozzles angle. • A liquid–gas gravitational separation in horizontal atomiser operation was observed. • It causes up to 70% fuel supply variance into exit holes depending on design and regime. - Graphical Abstract: - Abstract: The present paper provides an experimental study and optimisation of multi-hole effervescent atomisers for industrial burners using oil-based fossil, bio- or waste fuels with prospects of emission reduction. Several multi-hole nozzles were designed based on our previous work. We probed the spray quality by phase-Doppler anemometry. 3-D plots of Sauter mean diameter and mean droplet velocity demonstrate their spatial distribution within the spray. The effect of geometrical and operational factors on the spray is discussed. Droplet size–velocity correlations as well as the size and velocity distributions are presented, and differences are found against other investigations. A spray macrostructure is photographically observed and spray cone angles of the multi-hole nozzles are analysed. An internal two-phase flow is estimated using the Baker's map for horizontal two-phase flow. Our previous two-phase flow visualisations suggested a liquid–gas gravitational separation when the multi-hole atomiser operated horizontally. This issue is addressed here; the results of spray heterogeneity measurements document that fuel flow rates through individual exit holes differ significantly. This difference spans between 0 and 70% depending on the nozzle design and flow regime. Effervescent sprays are unsteady under some operating conditions; spray unsteadiness was detected at low pressure and low gas-to-liquid-ratios.

  5. Quantitative characterization of near-field fuel sprays by multi-orifice direct injection using ultrafast x-tomography technique

    International Nuclear Information System (INIS)

    Liu, X.; Im, K.S.; Wang, Y.; Wang, J.; Hung, D.L.S.; Winkelman, J.R.; Tate, M.W.; Ercan, A.; Koerner, L.J.; Caswell, T.; Chamberlain, D.; Schuette, D.R.; Philipp, H.; Smilgies, D.M.; Gruner, S.M.

    2006-01-01

    A low-pressure direct injection fuel system for spark ignition direct injection engines has been developed, in which a high-turbulence nozzle technology was employed to achieve fine fuel droplet size at a low injection pressure around 2 MPa. It is particularly important to study spray characteristics in the near-nozzle region due to the immediate liquid breakup at the nozzle exit. By using an ultrafast x-ray area detector and intense synchrotron x-ray beams, the interior structure and dynamics of the direct injection gasoline sprays from a multi-orifice turbulence-assisted nozzle were elucidated for the first time in a highly quantitative manner with μs-temporal resolution. Revealed by a newly developed, ultrafast computed x-microtomography technique, many detailed features associated with the transient liquid flows are readily observable in the reconstructed spray. Furthermore, an accurate 3-dimensional fuel density distribution, in the form of fuel volume fraction, was obtained by the time-resolved computed tomography. The time-dependent fuel density distribution revealed that the fuel jet is well broken up immediately at the nozzle exits. These results not only reveal the near-field characteristics of the partial atomized fuel sprays with unprecedented detail, but also facilitate the development of an advanced multi-orifice direct injector. This ultrafast tomography capability also will facilitate the realistic computational fluid dynamic simulations in highly transient and multiphase fuel spray systems.

  6. On the prediction of spray angle of liquid-liquid pintle injectors

    Science.gov (United States)

    Cheng, Peng; Li, Qinglian; Xu, Shun; Kang, Zhongtao

    2017-09-01

    The pintle injector is famous for its capability of deep throttling and low cost. However, the pintle injector has been seldom investigated. To get a good prediction of the spray angle of liquid-liquid pintle injectors, theoretical analysis, numerical simulations and experiments were conducted. Under the hypothesis of incompressible and inviscid flow, a spray angle formula was deduced from the continuity and momentum equations based on a control volume analysis. The formula was then validated by numerical and experimental data. The results indicates that both geometric and injection parameters affect the total momentum ratio (TMR) and then influence the spray angle formed by liquid-liquid pintle injectors. TMR is the pivotal non-dimensional number that dominates the spray angle. Compared with gas-gas pintle injectors, spray angle formed by liquid-liquid injectors is larger, which benefits from the local high pressure zone near the pintle wall caused by the impingement of radial and axial sheets.

  7. X-ray vision of fuel sprays

    International Nuclear Information System (INIS)

    Wang, J.

    2005-01-01

    With brilliant synchrotron X-ray sources, microsecond time-resolved synchrotron X-ray radiography and tomography have been used to elucidate the detailed three-dimensional structure and dynamics of high-pressure high-speed fuel sprays in the near-nozzle region. The measurement allows quantitative determination of the fuel distribution in the optically impenetrable region owing to the multiple scattering of visible light by small atomized fuel droplets surrounding the jet. X-radiographs of the jet-induced shock waves prove that the fuel jets become supersonic under appropriate injection conditions and that the quantitative analysis of the thermodynamic properties of the shock waves can also be derived from the most direct measurement. In other situations where extremely axial-asymmetric sprays are encountered, mass deconvolution and cross-sectional fuel distribution models can be computed based on the monochromatic and time-resolved X-radiographic images collected from various rotational orientations of the sprays. Such quantitative analysis reveals the never-before-reported characteristics and most detailed near-nozzle mass distribution of highly transient fuel sprays

  8. Imaging diagnostics of ethanol port fuel injection sprays for automobile engine applications

    International Nuclear Information System (INIS)

    Padala, Srinivas; Le, Minh Khoi; Kook, Sanghoon; Hawkes, Evatt R.

    2013-01-01

    This paper presents characteristics of ethanol sprays at port fuel injection (PFI) conditions with variations in injection and ambient parameters. Details of temporal and spatial development of ethanol PFI sprays are studied using Mie-scattering and high-speed shadowgraph imaging techniques. Momentum flux-based injection rate measurement is also performed. The influences of fuel flow-rate, injection duration, and ambient air cross-flow are of particular interest in an effort to understand ethanol PFI spray characteristics that are relevant to automobile engines. For comparison purposes, the results from gasoline fuel are also presented. Ethanol flow-rate effects are studied using two injectors with different nozzle-hole sizes at a fixed injection pressure. From the experiments, it was found that the actual injection duration was longer for the higher flow-rate injector although an electronic pulse width was fixed. This was due to an extended delay in the injector needle closing as the flow resistance against the needle was increased for the high flow-rate injector. For liquid droplets, the larger hole size of the higher flow-rate injector caused a higher mean droplet diameter and higher number of droplets. Injection duration was also varied to study transient spray behaviour: short-injection sprays with the end-of-injection transient dominating the overall spray development were compared to long, steady-injection sprays. From Mie-scattering images, the number of droplets and mean droplet diameter were found to be less for the short injection sprays. Detailed analysis using an axial profile of the number of droplets and mean droplet diameter suggested that the observed trends were a result of increased evaporation rate near the nozzle after the end of injection. This was consistent with shadowgraph images showing no liquid regions but only the vapour-phase fuel near the nozzle. Under the influence of ambient air cross-flow, both mean droplet diameter and number of

  9. Computational sensitivity study of spray dispersion and mixing on the fuel properties in a gas turbine combustor

    Energy Technology Data Exchange (ETDEWEB)

    Grosshans, Holger; Szász, Robert-Zoltán [Division of Fluid Mechanics, Lund University (Sweden); Cao, Le [Key Laboratory for Aerosol-Cloud-Precipitation of China Meteorological Administration, Nanjing University of Information Science and Technology, Nanjing (China); Fuchs, Laszlo, E-mail: holger.grosshans@uclouvain.be [Department of Mechanics, KTH, Stockholm (Sweden)

    2017-04-15

    A swirl stabilized gas turbine burner has been simulated in order to assess the effects of the fuel properties on spray dispersion and fuel–air mixing. The properties under consideration include fuel surface tension, viscosity and density. The turbulence of the gas phase is modeled applying the methodology of large eddy simulation whereas the dispersed liquid phase is described by Lagrangian particle tracking. The exchange of mass, momentum and energy between the two phases is accounted for by two-way coupling. Bag and stripping breakup regimes are considered for secondary droplet breakup, using the Reitz–Diwakar and the Taylor analogy breakup models. Moreover, a model for droplet evaporation is included. The results reveal a high sensitivity of the spray structure to variations of all investigated parameters. In particular, a decrease in the surface tension or the fuel viscosity, or an increase in the fuel density, lead to less stable liquid structures. As a consequence, smaller droplets are generated and the overall spray surface area increases, leading to faster evaporation and mixing. Furthermore, with the trajectories of the small droplets being strongly influenced by aerodynamic forces (and less by their own inertia), the spray is more affected by the turbulent structures of the gaseous phase and the spray dispersion is enhanced. (paper)

  10. Feasibility Demonstration of Exciplex Fluorescence Measurements in Evaporating Laminar Sprays of Diesel Fuel

    Science.gov (United States)

    2011-05-15

    code) 1 FEASIBILITY DEMONSTRATION OF EXCIPLEX FLUORESCENCE MEASUREMENTS IN EVAPORATING LAMINAR SPRAYS OF DIESEL FUEL Final Technical Report Grant...fluorescence is found to increase with temperature up to 538 K and then declines. Fluorescence from the liquid phase, i.e. the exciplex (Naphthalene+TMPD...to have as well characterized a description of the spray environment and assess conclusively the potential of the exciplex approach for more

  11. Experimental Study of Liquid Fuel Spray Combustion

    DEFF Research Database (Denmark)

    Westlye, Fredrik Ree

    the specific physical quantities needed in CFD validation of these types of flames. This work is a testament to that fact. The first part of this thesis is an extensive study of optical combustion diagnostics applied to complex transient sprayflames in a high temperature and pressure environment...... by the Danish Council for Strategic Research. Other supporters of the project have been MAN Diesel & Turbo A/S, DTU Mechanical Engineering, DTU Chemical Engineering, Sandia National Laboratories USA, Norwegian University of Science & Technology (NTNU) and University of Nottingham, Malaysia Campus.......The physiochemical properties and electromagnetic interactions in flames, of which various optical combustion diagnostics are based, have been reviewed. Key diagnostics have been presented with practical examples of their application which, together with a comprehensive review of fuel spray flames, form...

  12. Spray drying of liquid radioactive wastes

    International Nuclear Information System (INIS)

    Abrams, R.F.; Monat, J.P.

    1984-01-01

    Full scale performance tests of a Koch spray dryer were conducted on simulated liquid radioactive waste streams. The liquid feeds simulated the solutions that result from radwaste incineration of DAW an ion exchange resins, as well as evaporator bottoms. The integration of the spray dryer into a complete system is discussed

  13. Quantitative spray analysis of diesel fuel and its emulsions using digital image processing

    Directory of Open Access Journals (Sweden)

    Faik Ahmad Muneer El-Deen

    2015-01-01

    Full Text Available In the present work, an experimental investigation of spray atomization of different liquids has been carried out. An air-assist atomizer operating at low injection pressures valued (4 and 6 bar has been used to generate sprays of (diesel fuel, 5, 10, and 15% water-emulsified-diesel, respectively. A Photron-SA4 high speed camera has been used for spray imaging at 2000 fps. 20 time intervals (from 5 to 100 ms with 5 ms time difference are selected for analysis and comparison. Spray macroscopic characteristics (spray penetration, dispersion, cone angle, axial and dispersion velocities have been extracted by a proposed technique based on image processing using Matlab, where the maximum and minimum (horizontal and vertical boundaries of the spray are detected, from which the macroscopic spray characteristics are evaluated. The maximum error of this technique is (1.5% for diesel spray and a little bit higher for its emulsions.

  14. A spray flamelet/progress variable approach combined with a transported joint PDF model for turbulent spray flames

    Science.gov (United States)

    Hu, Yong; Olguin, Hernan; Gutheil, Eva

    2017-05-01

    A spray flamelet/progress variable approach is developed for use in spray combustion with partly pre-vaporised liquid fuel, where a laminar spray flamelet library accounts for evaporation within the laminar flame structures. For this purpose, the standard spray flamelet formulation for pure evaporating liquid fuel and oxidiser is extended by a chemical reaction progress variable in both the turbulent spray flame model and the laminar spray flame structures, in order to account for the effect of pre-vaporised liquid fuel for instance through use of a pilot flame. This new approach is combined with a transported joint probability density function (PDF) method for the simulation of a turbulent piloted ethanol/air spray flame, and the extension requires the formulation of a joint three-variate PDF depending on the gas phase mixture fraction, the chemical reaction progress variable, and gas enthalpy. The molecular mixing is modelled with the extended interaction-by-exchange-with-the-mean (IEM) model, where source terms account for spray evaporation and heat exchange due to evaporation as well as the chemical reaction rate for the chemical reaction progress variable. This is the first formulation using a spray flamelet model considering both evaporation and partly pre-vaporised liquid fuel within the laminar spray flamelets. Results with this new formulation show good agreement with the experimental data provided by A.R. Masri, Sydney, Australia. The analysis of the Lagrangian statistics of the gas temperature and the OH mass fraction indicates that partially premixed combustion prevails near the nozzle exit of the spray, whereas further downstream, the non-premixed flame is promoted towards the inner rich-side of the spray jet since the pilot flame heats up the premixed inner spray zone. In summary, the simulation with the new formulation considering the reaction progress variable shows good performance, greatly improving the standard formulation, and it provides new

  15. Fuel concentration in isothermal Diesel sprays through structured planar laser imaging measurements

    Energy Technology Data Exchange (ETDEWEB)

    Payri, R.; Gimeno, J.; Marti, P. [CMT Motores Termicos, Universidad Politecnica de Valencia, Camino de Vera s/n, 46022 Valencia (Spain); Manin, J., E-mail: jmanin@sandia.gov [Sandia National Laboratories, 7011 East Ave., 94551 Livermore, CA (United States)

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer Structured illumination has been implemented to quantify mixing in isothermal sprays. Black-Right-Pointing-Pointer Comparison to a gas-jet model conducted to Schmidt number below the unity (Sc = 0.8). Black-Right-Pointing-Pointer Results showed incomplete momentum transfer due to velocity slip between droplets and ambient. Black-Right-Pointing-Pointer Higher injection pressures enhance momentum transfer and lead to better global mixing. - Abstract: The mixing of isothermal liquid sprays in engine-like conditions has been investigated by applying the structured planar laser imaging technique to remove multiple light scattering. The intensity of the illumination plane has been recovered by removing multiply scattered light and mapping the spray three-dimensionally via discrete tomography. Based on the extinction of light within the illumination plane, the number density has been extracted. Coupled with 2-D maps of droplet diameters obtained through LIF/Mie ratio, the number density allowed to calculate the fuel concentration in the sprays. The mixture fraction of DI Diesel sprays injected into an inert environment held at room temperature has been evaluated and compared to a 2-D model based on gas-jet theory. The experimental results showed good agreement with the predictions when a Gaussian radial distribution is assumed and the Schmidt number is correctly tuned. Differences in the radial distribution has been observed and related to incomplete momentum transfer between the liquid spray and the surrounding gases. For different testing conditions, while the influence of ambient density on mixing was expected, the effect of injection pressure has been found to provide additional information concerning the global mixing of liquid sprays.

  16. The route of liquid precursor to ZnO nanoparticles in premixed combustion spray pyrolysis

    Science.gov (United States)

    Widiyastuti, W.; Machmudah, Siti; Nurtono, Tantular; Winardi, Sugeng

    2018-04-01

    Zinc oxide nanoparticles had been successfully synthesized by premixed combustion spray pyrolysis. Zinc acetate was dissolved in distilled water was selected as a liquid precursor. Zinc nitrate was also used for comparison the effect of precursor type on the generated particles morphology and the crystallinity. The premixed combustion reaction used liquefied petroleum gas (LPG) mainly consisting of butane and propane as a fuel and compressed air used as an oxidizer. The liquid precursor was atomized using a custom two fluid nozzle to generate droplets. Then, the droplets were sprayed by the flow of air as a carrier gas into the premixed combustion reactor. The zinc precursor was decomposed to zinc oxide due to the high temperature as a result of combustion reaction inside the reactor resulting in nanoparticles formation. The particle size decreased with the increase of the fuel flow rate. In addition, it can be found that at the same flow rate of fuel, the particle size of zinc oxide synthesized using zinc nitrate is larger than that of the use of zinc acetate as a precursor.

  17. Influence of fuel properties on fundamental spray characteristics and soot emissions using different tailor-made fuels from biomass

    International Nuclear Information System (INIS)

    García, Antonio; Monsalve-Serrano, Javier; Heuser, Benedikt; Jakob, Markus; Kremer, Florian; Pischinger, Stefan

    2016-01-01

    Highlights: • TMFB show clear potential to reduce soot emissions under mixing-controlled combustion. • The larger lift-off-length of 2-MTHF and 1-octanol promotes soot emissions reduction. • Oxidation process governs the improved soot emissions of DNBE. - Abstract: This work evaluates the potential of some new biomass-derived fuels as candidates for compression ignition operation. Thus, fundamental spray characteristics related to fuel vaporization and fuel/air mixing process for 2-Methyltetrahydrofuran, Di-n-butyl ether and 1-octanol has been studied and compared with conventional EN590 Diesel fuel. For this purpose, OH"∗ chemiluminescence and shadowgraphy measurements in a high pressure chamber as well as 1D simulations with a spray model have been carried out at different operating conditions representative of the NEDC driving cycle. Finally, measured soot emissions in the single-cylinder engine were presented and discussed. Results from the high pressure chamber presented very good agreement in terms of liquid length and vapor penetration with simulation results. Thus, some analytical expressions related to macroscopic spray characteristics have been proposed and validated experimentally for all four fuels. Finally, the single-cylinder engine results confirmed the relevant role of soot formation on final emissions for 1-octanol and 2-MTHF. In addition, DNBE showed greater soot oxidation potential than diesel and other TMFB candidates.

  18. Study on Spray Characteristics and Spray Droplets Dynamic Behavior of Diesel Engine Fueled by Rapeseed Oil

    Directory of Open Access Journals (Sweden)

    Sapit Azwan

    2014-07-01

    Full Text Available Fuel-air mixing is important process in diesel combustion. It directly affects the combustion and emission of diesel engine. Biomass fuel needs great help to atomize because the fuel has high viscosity and high distillation temperature. This study investigates the atomization characteristics and droplet dynamic behaviors of diesel engine spray fueled by rapeseed oil (RO. Optical observation of RO spray was carried out using shadowgraph photography technique. Single nano-spark photography technique was used to study the characteristics of the rapeseed oil spray while dual nano-spark shadowgraph technique was used to study the spray droplet behavior. The results show that RO has very poor atomization due to the high viscosity nature of the fuel. This is in agreement with the results from spray droplet dynamic behavior studies that shows due to the high viscosity, the droplets are large in size and travel downward, with very little influence of entrainment effect due to its large kinematic energy.

  19. Role of oxides and porosity on high temperature oxidation of liquid fuelled HVOF thermal sprayed Ni50Cr coatings

    OpenAIRE

    Song, B.; Bai, M.; Voisey, K.T.; Hussain, Tanvir

    2017-01-01

    High chromium content in Ni50Cr thermally sprayed coatings can generate a dense and protective scale at the surface of coating. Thus, the Ni50Cr coating is widely used in high temperature oxidation and corrosion applications. A commercially available gas atomized Ni50Cr powder was sprayed onto a power plant steel (ASME P92) using a liquid fuelled high velocity oxy-fuel (HVOF) thermal spray with three processing parameters in this study. Microstructure of as-sprayed coatings was examined using...

  20. Impact of alternative fuel rheology on spraying process of small pressure-swirl atomizer

    Energy Technology Data Exchange (ETDEWEB)

    Malý, Milan, E-mail: milan.maly@vutbr.cz; Janáčková, Lada; Jedelský, Jan, E-mail: jedelsky@vutbr.cz; Jícha, Miroslav [Brno University of Technology, Faculty of Mechanical Engineering, Energy Institute, Technická 2896/2, 61669 Brno (Czech Republic)

    2016-06-30

    A systematic investigation was made to analyse the atomizing performance of a small pressure-swirl atomizer with different crude-oil based fuels and water. The atomizer performance is characterized in terms of discharge coefficient, droplet Sauter mean diameter and nozzle efficiency. Phase-Doppler anemometry was used to measure droplets sizes and velocities and to determine the mean structure of the developed spray. A strong dependence of liquid viscosity on the mass flow rate through the atomizer as well as on the spray quality was found and discussed in comparison with relevant literature.

  1. Impact of alternative fuel rheology on spraying process of small pressure-swirl atomizer

    Science.gov (United States)

    Malý, Milan; Janáčková, Lada; Jedelský, Jan; Jícha, Miroslav

    2016-06-01

    A systematic investigation was made to analyse the atomizing performance of a small pressure-swirl atomizer with different crude-oil based fuels and water. The atomizer performance is characterized in terms of discharge coefficient, droplet Sauter mean diameter and nozzle efficiency. Phase-Doppler anemometry was used to measure droplets sizes and velocities and to determine the mean structure of the developed spray. A strong dependence of liquid viscosity on the mass flow rate through the atomizer as well as on the spray quality was found and discussed in comparison with relevant literature.

  2. Impact of alternative fuel rheology on spraying process of small pressure-swirl atomizer

    International Nuclear Information System (INIS)

    Malý, Milan; Janáčková, Lada; Jedelský, Jan; Jícha, Miroslav

    2016-01-01

    A systematic investigation was made to analyse the atomizing performance of a small pressure-swirl atomizer with different crude-oil based fuels and water. The atomizer performance is characterized in terms of discharge coefficient, droplet Sauter mean diameter and nozzle efficiency. Phase-Doppler anemometry was used to measure droplets sizes and velocities and to determine the mean structure of the developed spray. A strong dependence of liquid viscosity on the mass flow rate through the atomizer as well as on the spray quality was found and discussed in comparison with relevant literature.

  3. A multi-objective CFD optimization of liquid fuel spray injection in dry-low-emission gas-turbine combustors

    International Nuclear Information System (INIS)

    Asgari, Behrad; Amani, Ehsan

    2017-01-01

    Highlights: •An Eulerian-Lagrangian model for the fuel spray injection is evaluated. •The drop breakup, spray-vortex interaction, and wall-wetting play the key roles. •The injection location and direction are the most important parameters. •The best design candidates are proposed using multi-objective optimizations. •A large central perpendicular injection with high co-rotating swirls is optimal. -- Abstract: The main goal of this research is to investigate the effects of fuel injection strategy on the performance of the premixing chamber of modern Dry-Low-Emission (DLE) Gas-Turbine (GT) combustors. Here, an Eulerian-Lagrangian model for multi-phase multi-component flows is evaluated and used to investigate the effects of different fuel spray design parameters, including the injection location, direction, mass-flow-rate partitioning, and flow Swirl number, on the performance of the premixing chamber. The analysis is enriched by multi-objective optimizations accounting for several goals, including the evaporation efficiency, mixture stratification, entropy generation, and flow recirculation. It is observed that the droplet breakup, spray-vortex interactions, and wall-wetting have significant influences on the performance objectives while the droplet residence time effect is minor. Among the design parameters, the injection location and direction have a profound impact on the droplet breakup which predominately controls the evaporation efficiency. In addition, the interactions between the spray and the two swirling vertices inside the chamber strongly affect the mixture stratification (uniformity), e.g. the location and direction of the injection should not be chosen such that a large proportion of fuel droplets are trapped in the shear layer between the two vortices (otherwise the evaporation efficiency drops significantly) or trapped in the strong outer swirling vortex (if large mixture non-uniformity should be avoided). Finally, the best designs meeting

  4. Electrostatically atomised hydrocarbon sprays

    Energy Technology Data Exchange (ETDEWEB)

    Yule, A.J.; Shrimpton, J.S.; Watkins, A.P.; Balachandran, W.; Hu, D. [UMIST, Manchester (United Kingdom). Thermofluids Division, Dept. of Mechanical Engineering

    1995-07-01

    A burner using an electrostatic method to produce and control a fuel spray is investigated for non-burning sprays. The burner has a charge injection nozzle and the liquid flow rate and charge injection rate are varied using hydrocarbon liquids of differing viscosities, surface tensions and electrical conductivities (kerosene, white spirit and diesel oil). Droplet size distributions are measured and it is shown how the dropsize, spray pattern, breakup mechanism and breakup length depend on the above variables, and in particular on the specific charge achieved in the spray. The data are valuable for validating two computer models under development. One predicts the electric field and flow field inside the nozzle as a function of emitter potential, geometry and flow rate. The other predicts the effect of charge on spray dispersion, with a view to optimizing spray combustion. It is shown that electrostatic disruptive forces can be used to atomize oils at flow rates commensurate with practical combustion systems and that the charge injection technique is particularly suitable for highly resistive liquids. Possible limitations requiring further research include the need to control the wide spray angle, which may provide fuel-air mixtures too lean near the nozzle, and the need to design for maximum charge injection rate, which is thought to be limited by corona breakdown in the gas near the nozzle orifice. 30 refs., 15 figs., 1 tab.

  5. MODELING OF FUEL SPRAY CHARACTERISTICS AND DIESEL COMBUSTION CHAMBER PARAMETERS

    Directory of Open Access Journals (Sweden)

    G. M. Kukharonak

    2011-01-01

    Full Text Available The computer model for coordination of fuel spray characteristics with diesel combustion chamber parameters has been created in the paper.  The model allows to observe fuel sprays  develоpment in diesel cylinder at any moment of injection, to calculate characteristics of fuel sprays with due account of a shape and dimensions of a combustion chamber, timely to change fuel injection characteristics and supercharging parameters, shape and dimensions of a combustion chamber. Moreover the computer model permits to determine parameters of holes in an injector nozzle that provides the required fuel sprays characteristics at the stage of designing a diesel engine. Combustion chamber parameters for 4ЧН11/12.5 diesel engine have been determined in the paper.

  6. Numerical analysis of injector flow and spray characteristics from diesel injectors using fossil and biodiesel fuels

    International Nuclear Information System (INIS)

    Battistoni, Michele; Grimaldi, Carlo Nazareno

    2012-01-01

    Highlights: ► Fluid-dynamic simulation of injection process with biodiesel and diesel fuel. ► Coupling of Eulerian and Lagrangian spray CFD simulations. ► Effects of hole shaping: conical versus cylindrical and edge rounding effects. ► Prediction of spray characteristics improved using inner nozzle flow data. ► Explanation of mass flow differences depending on hole shape and fuel type. -- Abstract: The aim of the paper is the comparison of the injection process with two fuels, a standard diesel fuel and a pure biodiesel, methyl ester of soybean oil. Multiphase cavitating flows inside injector nozzles are calculated by means of unsteady CFD simulations on moving grids from needle opening to closure, using an Eulerian–Eulerian two-fluid approach which takes into account bubble dynamics. Afterward, spray evolutions are also evaluated in a Lagrangian framework using results of the first computing step, mapped onto the hole exit area, for the initialization of the primary breakup model. Two nozzles with cylindrical and conical holes are studied and their behaviors are discussed in relation to fuel properties. Nozzle flow simulations highlighted that the extent of cavitation regions is not much affected by the fuel type, whereas it is strongly dependent on the nozzle shape. Biodiesel provides a slightly higher mass flow in highly cavitating nozzles. On the contrary using hole shaped nozzles (to reduce cavitation) diesel provides similar or slightly higher mass flow. Comparing the two fuels, the effects of different viscosities and densities play main role which explains these behaviors. Simulations of the spray evolution are also discussed highlighting the differences between the use of fossil and biodiesel fuels in terms of spray penetration, atomization and cone-angle. Usage of diesel fuel in the conical convergent nozzle gives higher liquid penetration.

  7. On the modeling of fuel sprays

    Energy Technology Data Exchange (ETDEWEB)

    Bergstroem, Christer

    1997-12-01

    This report concerns on the modelling of fuel sprays in a non-combustible case using an own developed fuel spray code module. The spray code is made as an independent module to simplify the use of different gas flow solvers together with the spray module. This enables the possibility to use different turbulence models. In the report two turbulence models has been used, the standard k-{epsilon} and the LES (Large Eddy Simulation) model. The report presents results obtained from a sensitivity study of both numerical and physical parameters on an evaporating spray under diesel like conditions (light duty diesel engine) with the spray code module attached to a cylindrical gas phase flow solver. The results from the sensitivity analysis showed that these effects were not so pronounced as has been reported. It was suggested that this was due to the `easy` nature of the investigated case, where the flow field could be sufficiently resolved without violating the droplet void fraction criteria and break-up, collision and combustion that may increase the grid spacing sensitivity were not modelled. An investigation was performed to valuate the feasibility of using LES as turbulence model. Calculations of the initial phase of a developing jet were made and it was found that in the initial phase of the spray and the flow structure were similar to that of a spatially developing jet flow, which is in agreement with experimental observations. Results from LES calculations on a developing spray jet was also compared with k-{epsilon} based ones. This result showed that the spray-LES approach captured the transition from a laminar to a turbulent flow field with an increase in turbulent kinetic energy k along the injection direction 45 refs, 37 figs, 2 tabs

  8. Design Optimization of Liquid Fueled High Velocity Oxy- Fuel Thermal Spraying Technique for Durable Coating for Fossil Power Systems

    Energy Technology Data Exchange (ETDEWEB)

    Choudhuri, Ahsan [Univ. of Texas, El Paso, TX (United States); Love, Norman [Univ. of Texas, El Paso, TX (United States)

    2016-11-04

    High-velocity oxy–fuel (HVOF) thermal spraying was developed in 1930 and has been commercially available for twenty-five years. HVOF thermal spraying has several benefits over the more conventional plasma spray technique including a faster deposition rate which leads to quicker turn-around, with more durable coatings and higher bond strength, hardness and wear resistance due to a homogeneous distribution of the sprayed particles. HVOF thermal spraying is frequently used in engineering to deposit cermets, metallic alloys, composites and polymers, to enhance product life and performance. HVOF thermal spraying system is a highly promising technique for applying durable coatings on structural materials for corrosive and high temperature environments in advanced ultra-supercritical coal- fired (AUSC) boilers, steam turbines and gas turbines. HVOF thermal spraying is the preferred method for producing coatings with low porosity and high adhesion. HVOF thermal spray process has been shown to be one of the most efficient techniques to deposit high performance coatings at moderate cost. Variables affecting the deposit formation and coating properties include hardware characteristics such as nozzle geometry and spraying distance and process parameters such as equivalence ratio, gas flow density, and powder feedstock. In the spray process, the powder particles experience very high speeds combined with fast heating to the powder material melting point or above. This high temperature causes evaporation of the powder, dissolution, and phase transformations. Due to the complex nature of the HVOF technique, the control and optimization of the process is difficult. In general, good coating quality with suitable properties and required performance for specific applications is the goal in producing thermal spray coatings. In order to reach this goal, a deeper understanding of the spray process as a whole is needed. Although many researchers studied commercial HVOF thermal spray

  9. Characteristics of spray from a GDI fuel injector for naphtha and surrogate fuels

    KAUST Repository

    Wang, Libing

    2016-11-18

    Characterization of the spray angle, penetration, and droplet size distribution is important to analyze the spray and atomization quality. In this paper, the spray structure development and atomization characterization of two naphtha fuels, namely light naphtha (LN) and whole naphtha (WN) and two reference fuel surrogates, i.e. toluene primary reference fuel (TPRF) and primary reference fuel (PRF) were investigated using a gasoline direct injection (GDI) fuel injector. The experimental setup included a fuel injection system, a high-speed imaging system, and a droplet size measurement system. Spray images were taken by using a high-speed camera for spray angle and penetration analysis. Sauter mean diameter, Dv(10), Dv(50), Dv(90), and particle size distribution were measured using a laser diffraction technique. Results show that the injection process is very consistent for different runs and the time averaged spray angles during the measuring period are 103.45°, 102.84°, 102.46° and 107.61° for LN, WN, TPRF and PRF, respectively. The spray front remains relatively flat during the early stage of the fuel injection process. The peak penetration velocities are 80 m/s, 75 m/s, 75 m/s and 79 m/s for LN, WN, TPRF and PRF, respectively. Then velocities decrease until the end of the injection and stay relatively stable. The transient particle size and the time-averaged particle size were also analyzed and discussed. The concentration weighted average value generally shows higher values than the arithmetic average results. The average data for WN is usually the second smallest except for Dv90, of which WN is the biggest. Generally the arithmetic average particle sizes of PRF are usually the smallest, and the sizes does not change much with the measuring locations. For droplet size distribution results, LN and WN show bimodal distributions for all the locations while TPRF and PRF shows both bimodal and single peak distribution patterns. The results imply that droplet size

  10. A comparison of biological effect and spray liquid distribution and deposition for different spray application techniques in different crops

    OpenAIRE

    Larsolle, Anders; Wretblad, Per; Westberg, Carl

    2002-01-01

    The objective of this study was to compare a selection of spray application techniques with different application volumes, with respect to the spray liquid distribution on flat surfaces, the deposition in fully developed crops and the biological effect. The spray application techniques in this study were conventional spray technique with three different nozzles: Teelet XR, Lechler ID and Lurmark DriftBeta, and also AirTec, Danfoil, Hardi Twin, Kyndestoit and Släpduk. The dynamic spray liquid ...

  11. CONCHAS-SPRAY, Reactive Flows with Fuel Sprays

    International Nuclear Information System (INIS)

    Cloutman, L.D.; Dukowicz, J.K.; Ramshaw, J.D.; Amsden, A.A.

    2001-01-01

    Description of program or function: CONCHAS-SPRAY solves the equations of transient, multicomponent, chemically reactive fluid dynamics, together with those for the dynamics of an evaporating liquid spray. The program was developed with applications to internal combustion engines in mind. The formulation is spatially two-dimensional, and encompasses both planar and axisymmetric geometries. In the latter case, the flow is permitted to swirl about the axis of symmetry. CONCHAS-SPRAY is a time-marching, finite- difference program that uses a partially implicit numerical scheme. Spatial differences are formed with respect to a generalized two- dimensional mesh of arbitrary quadrilaterals whose corner locations are specified functions of time. This feature allows a Lagrangian, Eulerian, or mixed description, and is particularly useful for representing curved or moving boundary surfaces. Arbitrary numbers of species and chemical reactions are allowed. The latter are subdivided into kinetic and equilibrium reactions, which are treated by different algorithms. A turbulent law-of-the-wall boundary layer option is provided. CONCHAS-SPRAY calls a number of LANL system subroutines to display graphic or numerical information on microfiche. These routines are not included, but are described in the reference report. Several routines called from LINPACK and SLATEC1.0 are included

  12. Application of the FIRST Combustion model to Spray Combustion

    NARCIS (Netherlands)

    de Jager, B.; Kok, Jacobus B.W.

    2004-01-01

    Liquid fuel is of interest to apply to gas turbines. The large advantage is that liquids are easily storable as compared to gaseous fuels. Disadvantage is that liquid fuel has to be sprayed, vaporized and mixed with air. Combustion occurs at some stage of mixing and ignition. Depending on the

  13. Investigation of the spray characteristics for a secondary fuel injection nozzle using a digital image processing method

    Science.gov (United States)

    Jeong, Haeyoung; Lee, Kihyung; Ikeda, Yuji

    2007-05-01

    There are many ways to reduce diesel engine exhaust emissions. However, NOx emission is difficult to reduce because the hydrocarbon (HC) concentration in a diesel engine is not sufficient for NOx conversion. Therefore, in order to create stoichiometric conditions in the De-NOx catalyst, a secondary injection system is designed to inject liquid HC into the exhaust pipe. The atomization and distribution characteristics of the HC injected from a secondary injector are key technologies to obtain a high NOx conversion because inhomogeneous droplets of injected HC cause not only high fuel consumption but also deterioration of NOx emission. This paper describes the spray characteristics of a secondary injector including the spray angle, penetration length and breakup behaviour of the spray to optimize the reduction rate of the NOx catalyst. In this study, various optical diagnostics were applied to investigate these spray characteristics, the atomization mechanism and spray developing process. The visualization and image processing method for the spray pulsation were developed by high speed photography. The influence of the fuel supply pressure on the spray behaviour and a more detailed spray developing process have been analysed experimentally using image processing. Finally, the experimental results were used to correlate the spray structure to the injection system performance and to provide a design guide for a secondary injector nozzle.

  14. Modelling of spray evaporation and penetration for alternative fuels

    OpenAIRE

    Azami, M. H.; Savill, Mark A.

    2016-01-01

    The focus of this work is on the modelling of evaporation and spray penetration for alternative fuels. The extension model approach is presented and validated for alternative fuels, namely, Kerosene (KE), Ethanol (ETH), Methanol (MTH), Microalgae biofuel (MA), Jatropha biofuel (JA), and Camelina biofuel (CA). The results for atomization and spray penetration are shown in a time variant condition. Comparisons have been made to visualize the transient behaviour of these fuels. The vapour pressu...

  15. Influence of the spray characteristics of a piezo-A-nozzle on the inflammation at spray guided combustion processes; Einfluss der Spraycharakteristik einer Piezo-A-Duese auf die Entflammung beim strahlgefuehrten Brennverfahren

    Energy Technology Data Exchange (ETDEWEB)

    Breuninger, Tobias; Schmidt, Juergen [Magdeburg Univ. (DE). Inst. fuer Stroemungstechnik und Thermodynamik (ISUT); Hese, Martin; Tschoeke, Helmut [Magdeburg Univ. (DE). Inst. fuer Mobile Systeme (IMS); Kufferath, Andreas [Robert Bosch GmbH, Schwieberdingen (Germany); Altenschmidt, Frank [Daimler AG, Stuttgart (Germany)

    2011-07-01

    The spray-guided combustion process offers a significant potential for improvement on the fuel consumption in partial-load engine operation. Due to the very close positioning of the injector to the spark plug, there is only very little time for the fuel mixture generation which leads to the presence of still liquid fuel particles next to already evaporized one. Furthermore the fuel-mixture generation is primarily driven by the dynamics of the fuel spray. In this article the spray characteristics of a Piezo-A-injector under pressure-chamber conditions as well as the combustion behavior on a one-cylinder test motor are analyzed. The global spray dispersion is analyzed using high-speed visualization while laser-optical measurements are used to observe the ignition-area. The mean diameter as well as the velocity of fuel droplets are determined using the phase-doppler-anemometry (PDA). An extinction-measuring methodology is used to quantify the liquid fuel particles. Analyzing the evaluated misfire-rate as a function of the spray-attributes allows for rating the spray-sections according to their ignition behavior. (orig.)

  16. Digital image processing techniques for the analysis of fuel sprays global pattern

    Science.gov (United States)

    Zakaria, Rami; Bryanston-Cross, Peter; Timmerman, Brenda

    2017-12-01

    We studied the fuel atomization process of two fuel injectors to be fitted in a new small rotary engine design. The aim was to improve the efficiency of the engine by optimizing the fuel injection system. Fuel sprays were visualised by an optical diagnostic system. Images of fuel sprays were produced under various testing conditions, by changing the line pressure, nozzle size, injection frequency, etc. The atomisers were a high-frequency microfluidic dispensing system and a standard low flow-rate fuel injector. A series of image processing procedures were developed in order to acquire information from the laser-scattering images. This paper presents the macroscopic characterisation of Jet fuel (JP8) sprays. We observed the droplet density distribution, tip velocity, and spray-cone angle against line-pressure and nozzle-size. The analysis was performed for low line-pressure (up to 10 bar) and short injection period (1-2 ms). Local velocity components were measured by applying particle image velocimetry (PIV) on double-exposure images. The discharge velocity was lower in the micro dispensing nozzle sprays and the tip penetration slowed down at higher rates compared to the gasoline injector. The PIV test confirmed that the gasoline injector produced sprays with higher velocity elements at the centre and the tip regions.

  17. Ultrafast X-ray Imaging of Fuel Sprays

    Science.gov (United States)

    Wang, Jin

    2007-01-01

    Detailed analysis of fuel sprays has been well recognized as an important step for optimizing the operation of internal combustion engines to improve efficiency and reduce emissions. Ultrafast radiographic and tomographic techniques have been developed for probing the fuel distribution close to the nozzles of direct-injection diesel and gasoline injectors. The measurement was made using x-ray absorption of monochromatic synchrotron-generated radiation, allowing quantitative determination of the fuel distribution in this optically impenetrable region with a time resolution on the order of 1 μs. Furthermore, an accurate 3-dimensional fuel-density distribution, in the form of fuel volume fraction, was obtained by the time-resolved computed tomography. These quantitative measurements constitute the most detailed near-nozzle study of a fuel spray to date. With high-energy and high-brilliance x-ray beams available at the Advanced Photon Source, propagation-based phase-enhanced imaging was developed as a unique metrology technique to visualize the interior of an injection nozzle through a 3-mm-thick steel with a 10-μs temporal resolution, which is virtually impossible by any other means.

  18. Ultrafast X-ray Imaging of Fuel Sprays

    International Nuclear Information System (INIS)

    Wang Jin

    2007-01-01

    Detailed analysis of fuel sprays has been well recognized as an important step for optimizing the operation of internal combustion engines to improve efficiency and reduce emissions. Ultrafast radiographic and tomographic techniques have been developed for probing the fuel distribution close to the nozzles of direct-injection diesel and gasoline injectors. The measurement was made using x-ray absorption of monochromatic synchrotron-generated radiation, allowing quantitative determination of the fuel distribution in this optically impenetrable region with a time resolution on the order of 1 μs. Furthermore, an accurate 3-dimensional fuel-density distribution, in the form of fuel volume fraction, was obtained by the time-resolved computed tomography. These quantitative measurements constitute the most detailed near-nozzle study of a fuel spray to date. With high-energy and high-brilliance x-ray beams available at the Advanced Photon Source, propagation-based phase-enhanced imaging was developed as a unique metrology technique to visualize the interior of an injection nozzle through a 3-mm-thick steel with a 10-μs temporal resolution, which is virtually impossible by any other means

  19. Modeling of Diesel Fuel Spray Formation and Combustion in OpenFOAM

    Energy Technology Data Exchange (ETDEWEB)

    Koesters, Anne

    2012-07-01

    The formation, ignition, and combustion of fuel sprays are highly complex processes and the available models have various shortcomings. The development and application of multidimensional CFD models, that describe the different phenomena have rapidly increased through the use of commercial and public software (e.g. Star-CD, KIVA, FIRE and OpenFOAM). The general approach to spray modeling is given by the Eulerian-Lagrangian method, where the gas phase is modeled as a continuum and the droplets are tracked in a Lagrangian way. The accuracy and robustness of today's spray models vary substantially and spray penetration simulations and the levels of spray-generated turbulence are dependent on the discretization. The work presented here deals with the prediction of spray formation and combustion with improved models implemented in the free, open source software package OpenFOAM. The VSB2 spray model was implemented and tested under varying ambient conditions. The design criteria of the model were to be unconditionally robust, have a minimal number of tuning parameters, and be implementable in any CFD software package supporting particle tracking. The main difference between the VSB2 spray model and standard spray models is how the interaction between the liquid fuel and hot gas phase is modeled. In the VSB2 spray model, a 'blob' is defined, containing differently sized droplets; instead of a parcel containing equally sized droplets. Another feature is the definition of a bubble surrounding the blob. The blob just interacts with the gas phase in the bubble instead of with the gas phase in the whole grid cell. The idea is to reduce grid dependency. Furthermore, equilibrium between the blob and the bubble is ensured, which makes the model very robust. Results of spray penetration simulations are compared with data obtained from experiments done at Chalmers Univ. of Technology and with experimental data published by Siebers and Naber from Sandia National

  20. Fuel Evaporation in an Atmospheric Premixed Burner: Sensitivity Analysis and Spray Vaporization

    Directory of Open Access Journals (Sweden)

    Dávid Csemány

    2017-12-01

    Full Text Available Calculation of evaporation requires accurate thermophysical properties of the liquid. Such data are well-known for conventional fossil fuels. In contrast, e.g., thermal conductivity or dynamic viscosity of the fuel vapor are rarely available for modern liquid fuels. To overcome this problem, molecular models can be used. Currently, the measurement-based properties of n-heptane and diesel oil are compared with estimated values, using the state-of-the-art molecular models to derive the temperature-dependent material properties. Then their effect on droplet evaporation was evaluated. The critical parameters were liquid density, latent heat of vaporization, boiling temperature, and vapor thermal conductivity where the estimation affected the evaporation time notably. Besides a general sensitivity analysis, evaporation modeling in a practical burner ended up with similar results. By calculating droplet motion, the evaporation number, the evaporation-to-residence time ratio can be derived. An empirical cumulative distribution function is used for the spray of the analyzed burner to evaluate evaporation in the mixing tube. Evaporation number did not exceed 0.4, meaning a full evaporation prior to reaching the burner lip in all cases. As droplet inertia depends upon its size, the residence time has a minimum value due to the phenomenon of overshooting.

  1. Air/fuel ratio visualization in a diesel spray

    Science.gov (United States)

    Carabell, Kevin David

    1993-01-01

    To investigate some features of high pressure diesel spray ignition, we have applied a newly developed planar imaging system to a spray in an engine-fed combustion bomb. The bomb is designed to give flow characteristics similar to those in a direct injection diesel engine yet provide nearly unlimited optical access. A high pressure electronic unit injector system with on-line manually adjustable main and pilot injection features was used. The primary scalar of interest was the local air/fuel ratio, particularly near the spray plumes. To make this measurement quantitative, we have developed a calibration LIF technique. The development of this technique is the key contribution of this dissertation. The air/fuel ratio measurement was made using biacetyl as a seed in the air inlet to the engine. When probed by a tripled Nd:YAG laser the biacetyl fluoresces, with a signal proportional to the local biacetyl concentration. This feature of biacetyl enables the fluorescent signal to be used as as indicator of local fuel vapor concentration. The biacetyl partial pressure was carefully controlled, enabling estimates of the local concentration of air and the approximate local stoichiometry in the fuel spray. The results indicate that the image quality generated with this method is sufficient for generating air/fuel ratio contours. The processes during the ignition delay have a marked effect on ignition and the subsequent burn. These processes, vaporization and pre-flame kinetics, very much depend on the mixing of the air and fuel. This study has shown that poor mixing and over-mixing of the air and fuel will directly affect the type of ignition. An optimal mixing arrangement exists and depends on the swirl ratio in the engine, the number of holes in the fuel injector and the distribution of fuel into a pilot and main injection. If a short delay and a diffusion burn is desired, the best mixing parameters among those surveyed would be a high swirl ratio, a 4-hole nozzle and a

  2. Ignition of Liquid Fuel Spray and Simulated Solid Rocket Fuel by Photoignition of Carbon Nanotube Utilizing a Camera Flash

    Science.gov (United States)

    2011-12-01

    10,11 There has been a recent report on the photoignition of graphene oxide for fuel ignition applications.12 In this report, we will describe the...slide Aluminum foil Glass petri dish Xe flash Camera Sample Black spray paint Figure 2- Schematic and photographs of the experimental setup...Gilje, Sergey Dubin, Alireza Badakhshan, Jabari Farrar, Stephen. A. Danczyk, Richard B. Kaner, “Photothermal Deoxygenation of Graphene Oxide for

  3. Experimental analysis on the influence of nozzle geometry over the dispersion of liquid n-dodecane sprays

    Directory of Open Access Journals (Sweden)

    Raul ePayri

    2015-10-01

    Full Text Available Understanding and controlling mixing and combustion processes is fundamental in order to face the challenges set by the ever more demanding pollutant regulations and fuel consumption standards of direct injection diesel engines. The fundamentals of these processes haven been long studied by the diesel spray community from both experimental and numerical perspectives. However, certain topics such as the influence of nozzle geometry over the spray atomization, mixing and combustion process are still not completely well understood and predicted by numerical models. The present study seeks to contribute to the current understanding of this subject, by performing state-of-the-art optical diagnostics to liquid sprays injected through two singe-hole nozzles of different conicity. The experiments were carried out in a nitrogen-filled constant-pressure-flow facility. Back pressures were set to produce the desired engine-like density conditions in the chamber, at room temperature. The experimental setup consists in a diffused back illumination setup with a fast pulsed LED light source and a high-speed camera. The diagnostics focused on detecting the liquid spray contour and evaluating the influence of nozzle geometry over the time-resolved and quasi-steady response of the spray dispersion, at similar injection conditions. Results show a clear influence of nozzle geometry on spray contour fluctuations, where the cylindrical nozzle seems to produce larger dispersion in both time-resolved fluctuations and quasi-steady values, when compared to the conical nozzle. This evidences that the turbulence and radial velocity profiles originated at the cylindrical nozzle geometry are able to affect not only the microscopic scales inside the nozzle, but also macroscopic scales such as the steady spray. Observations from this study indicate that the effects of the flow characteristics within the nozzle are carried on to the first millimeters of the spray, in which the

  4. A Planar-Fluorescence Imaging Technique for Studying Droplet-Turbulence Interactions in Vaporizing Sprays

    Science.gov (United States)

    Santavicca, Dom A.; Coy, E.

    1990-01-01

    Droplet turbulence interactions directly affect the vaporization and dispersion of droplets in liquid sprays and therefore play a major role in fuel oxidizer mixing in liquid fueled combustion systems. Proper characterization of droplet turbulence interactions in vaporizing sprays require measurement of droplet size velocity and size temperature correlations. A planar, fluorescence imaging technique is described which is being developed for simultaneously measuring the size, velocity, and temperature of individual droplets in vaporizing sprays. Preliminary droplet size velocity correlation measurements made with this technique are presented. These measurements are also compared to and show very good agreement with measurements made in the same spray using a phase Doppler particle analyzer.

  5. A three-color absorption/scattering imaging technique for simultaneous measurements on distributions of temperature and fuel concentration in a spray

    Science.gov (United States)

    Qi, Wenyuan; Zhang, Yuyin

    2018-04-01

    A three-color imaging technique was proposed for simultaneous measurements on distributions of fuel/air mixture temperature and fuel vapor/liquid concentrations in evaporating sprays. The idea is based on that the vapor concentration is proportional to the absorption of vapor to UV light, the liquid-phase concentration is related to the light extinction due to scattering of droplet to visible light, and the mixture temperature can be correlated to the absorbance ratio at two absorbing wavelengths or narrow bands. For verifying the imaging system, the molar absorption coefficients of p-xylene at the three narrow bands, which were centered respectively at 265, 289, and 532 nm with FWHM of 10 nm, were measured in a specially designed calibration chamber at different temperatures (423-606 K) and pressure of 3.6 bar. It was found that the ratio of the molar absorption coefficients of p-xylene at the two narrow bands centered at the two UV wavelengths is sensitive to the mixture temperature. On the other hand, the distributions of fuel vapor/liquid concentrations can be obtained by use of absorbance due to ultraviolet absorption of vapor and visible light scattering of droplets. Combining these two methods, a simultaneous measurement on distributions of mixture temperature and fuel vapor/liquid concentrations can be realized. In addition, the temperature field obtained from the ratio of the two absorbing narrow bands can be further used to improve the measurement accuracy of vapor/liquid concentrations, because the absorption coefficients depend on temperature. This diagnostic was applied to an evaporating spray inside a high-temperature and high-pressure constant volume chamber.

  6. Numerical studies of spray combustion processes of palm oil biodiesel and diesel fuels using reduced chemical kinetic mechanisms

    KAUST Repository

    Kuti, Olawole

    2014-04-01

    Spray combustion processes of palm oil biodiesel (PO) and conventional diesel fuels were simulated using the CONVERGE CFD code. Thermochemical and reaction kinetic data (115 species and 460 reactions) by Luo et al. (2012) and Lu et al. (2009) (68 species and 283 reactions) were implemented in the CONVERGE CFD to simulate the spray and combustion processes of the two fuels. Tetradecane (C14H30) and n- heptane (C7H 16) were used as surrogates for diesel. For the palm biodiesel, the mixture of methyl decanoate (C11H20O2), methyl-9-decenoate (C11H19O2) and n-heptane was used as surrogate. The palm biodiesel surrogates were combined in proportions based on the previous GC-MS results for the five major biodiesel components namely methyl palmitate, methyl stearate, methyl oleate, methyl linoleate and methyl linolenate. The Favre-Averaged Navier Stokes based simulation using the renormalization group (RNG) k-ε turbulent model was implemented in the numerical calculations of the spray formation processes while the SAGE chemical kinetic solver is used for the detailed kinetic modeling. The SAGE chemical kinetic solver is directly coupled with the gas phase calculations by renormalization group (RNG) k-ε turbulent model using a well-stirred reactor model. Validations of the spray liquid length, ignition delay and flame lift-off length data were performed against previous experimental results. The simulated liquid length, ignition delay and flame lift-off length were validated at an ambient density of 15kg/m3, and injection pressure conditions of 100, 200 and 300 MPa were utilized. The predicted liquid length, ignition delay and flame lift-off length agree with the trends obtained in the experimental data at all injection conditions. Copyright © 2014 SAE International.

  7. Atomization and spray characteristics of bioethanol and bioethanol blended gasoline fuel injected through a direct injection gasoline injector

    International Nuclear Information System (INIS)

    Park, Su Han; Kim, Hyung Jun; Suh, Hyun Kyu; Lee, Chang Sik

    2009-01-01

    The focus of this study was to investigate the spray characteristics and atomization performance of gasoline fuel (G100), bioethanol fuel (E100), and bioethanol blended gasoline fuel (E85) in a direct injection gasoline injector in a gasoline engine. The overall spray and atomization characteristics such as an axial spray tip penetration, spray width, and overall SMD were measured experimentally and predicted by using KIVA-3V code. The development process and the appearance timing of the vortices in the test fuels were very similar. In addition, the numerical results accurately described the experimentally observed spray development pattern and shape, the beginning position of the vortex, and the spray breakup on the spray surface. Moreover, the increased injection pressure induced the occurrence of a clear circular shape in the downstream spray and a uniform mixture between the injected spray droplets and ambient air. The axial spray tip penetrations of the test fuels were similar, while the spray width and spray cone angle of E100 were slightly larger than the other fuels. In terms of atomization performance, the E100 fuel among the tested fuels had the largest droplet size because E100 has a high kinematic viscosity and surface tension.

  8. A review on laser diagnostics on atomization and evaporation of liquid fuel

    Science.gov (United States)

    Zhang, Yuyin; Li, Shiyan; Lin, Baiyang; Liu, Yang; Wu, Jian; Xu, Bin

    2014-08-01

    To evaluate the atomization and evaporation processes of liquid fuel, there are several laser diagnostics available in present. In this paper, the recent progress in laser diagnostics for atomization and evaporation will be introduced, as two categories: atomization and evaporation. The diagnostics for the former includes the primary breakup from liquid jet to ligaments or droplets and the secondary atomization from a bigger droplet to a smaller one, and the latter includes the droplet evaporation and the vapor distributions in a spray.

  9. GDI fuel sprays of light naphtha, PRF95 and gasoline using a piezoelectric injector under different ambient pressures

    KAUST Repository

    Wu, Zengyang; Wang, Libing; Badra, Jihad A.; Roberts, William L.; Fang, Tiegang

    2018-01-01

    This study investigates fuel sprays of light naphtha (LN), primary reference fuel (PRF) and gasoline under different ambient pressures with an outwardly opening piezo gasoline direct injection (GDI) fuel injector. The tested gasoline fuel (regular grade with up to 10% ethanol, E10) was obtained by mixing fuels with AKI (the average of the research octane number (RON) and the motor octane number (MON)) of 87 from three local gas stations. Primary reference fuel (PRF) is commonly used as gasoline surrogate fuel and is blended by iso-octane and n-heptane. PRF95 is the blend of 95% iso-octane and 5% n-heptane by volume. LN fuel was provided by Saudi Aramco Oil Company. Five different ambient pressure conditions varied from 1 bar to 10 bar were tested. The spray was visualized by applying a Mie-scattering technique and a high-speed camera was employed to capture the spray images. The spray structure, spray angle, spray penetration length and spray front fluctuation were analyzed and compared among three fuels. Spray images show that a clear filamentary hollow-cone spray structure is formed for all three fuels at atmospheric conditions, and toroidal recirculation vortexes are observed at the downstream spray edges. A higher ambient pressure leads to a stronger vortex located closer to the injector outlet. Generally speaking, larger spray angles are found under higher ambient pressure conditions for all three fuels. Gasoline fuel always has the largest spray angle for each ambient pressure, while PRF95 has the smallest at most time. For each fuel, the spray front penetration length and spray front penetration velocity decrease with increasing ambient pressure. LN, PRF95 and gasoline show similar penetration length and velocity under the tested conditions. A two-stage spray front fluctuation pattern is observed for all three fuels. Stage one begins from the start of the injection and ends at 450–500 μs after the start of the injection trigger (ASOIT) with a slow

  10. GDI fuel sprays of light naphtha, PRF95 and gasoline using a piezoelectric injector under different ambient pressures

    KAUST Repository

    Wu, Zengyang

    2018-03-20

    This study investigates fuel sprays of light naphtha (LN), primary reference fuel (PRF) and gasoline under different ambient pressures with an outwardly opening piezo gasoline direct injection (GDI) fuel injector. The tested gasoline fuel (regular grade with up to 10% ethanol, E10) was obtained by mixing fuels with AKI (the average of the research octane number (RON) and the motor octane number (MON)) of 87 from three local gas stations. Primary reference fuel (PRF) is commonly used as gasoline surrogate fuel and is blended by iso-octane and n-heptane. PRF95 is the blend of 95% iso-octane and 5% n-heptane by volume. LN fuel was provided by Saudi Aramco Oil Company. Five different ambient pressure conditions varied from 1 bar to 10 bar were tested. The spray was visualized by applying a Mie-scattering technique and a high-speed camera was employed to capture the spray images. The spray structure, spray angle, spray penetration length and spray front fluctuation were analyzed and compared among three fuels. Spray images show that a clear filamentary hollow-cone spray structure is formed for all three fuels at atmospheric conditions, and toroidal recirculation vortexes are observed at the downstream spray edges. A higher ambient pressure leads to a stronger vortex located closer to the injector outlet. Generally speaking, larger spray angles are found under higher ambient pressure conditions for all three fuels. Gasoline fuel always has the largest spray angle for each ambient pressure, while PRF95 has the smallest at most time. For each fuel, the spray front penetration length and spray front penetration velocity decrease with increasing ambient pressure. LN, PRF95 and gasoline show similar penetration length and velocity under the tested conditions. A two-stage spray front fluctuation pattern is observed for all three fuels. Stage one begins from the start of the injection and ends at 450–500 μs after the start of the injection trigger (ASOIT) with a slow

  11. The characteristic of spray using diesel water emulsified fuel in a diesel engine

    International Nuclear Information System (INIS)

    Park, Sangki; Woo, Seungchul; Kim, Hyungik; Lee, Kihyung

    2016-01-01

    Highlights: • Water in oil emulsion is produced using ceramic membrane. • Surfactant type affect stability performance and droplet size distribution. • Evaporation characteristic of DE is poor compared with neat diesel. • Coefficient of variation maintains below 2.0% both DE and neat diesel. - Abstract: In this study, it was applied to the diesel–water emulsified (DE) fuel that carried out the experiment for the characteristic of sprat using diesel water emulsified fuel in a diesel engine, and the possibility of its application to conventional diesel engines was evaluated from the fundamental characteristics of diesel–water emulsified fuel. According to the results of the spray characteristics such as spray penetration and spray distribution were measured in the experiment, and then analyzed through digital image processing. The DEs were applied to actual diesel engines and their combustion, emission, and fuel consumption characteristics were compared with those of diesel. The results showed that the experiments were confirmed as the spray atomization characteristics at the various emulsified fuels.

  12. PIV measurement of internal structure of diesel fuel spray

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Z M [Ecotechnology System Lab., Yokohama National Univ. (Japan); Nishino, K [Div. of Artificial Environment and Systems, Yokohama National Univ. (Japan); Mizuno, S [Yokohama National Univ. (Japan); Torii, K [Dept. of Mechanical Engineering and Materials Science, Yokohama National Univ. (Japan)

    2000-12-01

    This paper reports particle image velocimetry (PIV) measurements of diesel fuel spray injected from a single-hole nozzle at injection pressures ranging from 30 to 70 MPa, which are comparable to partial-load operating conditions of commercial diesel engines. The fuel is injected into a non-combusting environment pressurized up to 2.0 MPa. A laser-induced fluorescent (LIF) technique is utilized to visualize internal structures of fuel sprays formed by densely-distributing droplets. A specially designed synchronization system is developed to acquire double-frame spray images at an arbitrary time delay after injection. A direct cross-correlation PIV technique is applied to measure instantaneous droplet velocity distribution. Unique large-scale structures in droplet concentration, called 'branch-like structures' by Azetsu et al. (1990), are observed and shown to be associated with active vortical motions, which appear to be responsible for the mixing between droplets and the surrounding gas. It is found that the droplets tend to move out of the vortical structures and accumulate in the regions of low vorticity. Some other interesting features concerning droplet velocity fields are also presented. (orig.)

  13. Numerical modelling of diesel spray using the Eulerian multiphase approach

    International Nuclear Information System (INIS)

    Vujanović, Milan; Petranović, Zvonimir; Edelbauer, Wilfried; Baleta, Jakov; Duić, Neven

    2015-01-01

    Highlights: • Numerical model for fuel disintegration was presented. • Fuel liquid and vapour were calculated. • Good agreement with experimental data was shown for various combinations of injection and chamber pressure. - Abstract: This research investigates high pressure diesel fuel injection into the combustion chamber by performing computational simulations using the Euler–Eulerian multiphase approach. Six diesel-like conditions were simulated for which the liquid fuel jet was injected into a pressurised inert environment (100% N 2 ) through a 205 μm nozzle hole. The analysis was focused on the liquid jet and vapour penetration, describing spatial and temporal spray evolution. For this purpose, an Eulerian multiphase model was implemented, variations of the sub-model coefficients were performed, and their impact on the spray formation was investigated. The final set of sub-model coefficients was applied to all operating points. Several simulations of high pressure diesel injections (50, 80, and 120 MPa) combined with different chamber pressures (5.4 and 7.2 MPa) were carried out and results were compared to the experimental data. The predicted results share a similar spray cloud shape for all conditions with the different vapour and liquid penetration length. The liquid penetration is shortened with the increase in chamber pressure, whilst the vapour penetration is more pronounced by elevating the injection pressure. Finally, the results showed good agreement when compared to the measured data, and yielded the correct trends for both the liquid and vapour penetrations under different operating conditions

  14. Experimental and theoretical study on spray behaviors of modified bio-ethanol fuel employing direct injection system

    Directory of Open Access Journals (Sweden)

    Ghahremani Amirreza

    2017-01-01

    Full Text Available One of the key solutions to improve engine performance and reduce exhaust emissions of internal combustion engines is direct injection of bio-fuels. A new modified bio-ethanol is produced to be substituted by fossil fuels in gasoline direct injection engines. The key advantages of modified bio-ethanol fuel as an alternative fuel are higher octane number and oxygen content, a long-chain hydro-carbon fuel, and lower emissions compared to fossil fuels. In the present study spray properties of a modified bio-ethanol and its atomization behaviors have been studied experimentally and theoretically. Based on atomization physics of droplets dimensional analysis has been performed to develop a new non-dimensional number namely atomization index. This number determines the atomization level of the spray. Applying quasi-steady jet theory, air entrainment and fuel-air mixing studies have been performed. The spray atomization behaviors such as atomization index number, Ohnesorge number, and Sauter mean diameter have been investigated employing atomization model. The influences of injection and ambient conditions on spray properties of different blends of modified bio-ethanol and gasoline fuels have been investigated performing high-speed visualization technique. Results indicate that decreasing the difference of injection and ambient pressures increases spray cone angle and projected area, and decreases spray tip penetration length. As expected, increasing injection pressure improves atomization behaviors of the spray. Increasing percentage of modified bio-ethanol in the blend, increases spray tip penetration and decreases the projected area as well.

  15. Testing of a Spray-bar Thermodynamic Vent System in Liquid Nitrogen

    Science.gov (United States)

    Flachbart, R. H.; Hastings, L. J.; Hedayat, A.; Nelson, S. L.; Tucker, S. P.

    2005-01-01

    To support development of a microgravity pressure control capability for liquid oxygen, thermodynamic vent system (TVS) testing was conducted at Marshall Space Flight Center (MSFC) using liquid nitrogen (LN2) as a LOX simulant. The spray bar TVS hardware used was originally designed by the Boeing Company for testing in liquid hydrogen (LH2). With this concept, a small portion of the tank fluid is passed through a Joule-Thomson (J-T) device, and then through a longitudinal spray bar mixed-heat exchanger in order to cool the bulk fluid. To accommodate the larger mass flow rates associated with LN2, the TVS hardware was modified by replacing the recirculation pump with an LN2 compatible pump and replacing the J-T valve. The primary advantage of the spray-bar configuration is that tank pressure control can be achieved independent of liquid and vapor location, enhancing the applicability of ground test data to microgravity conditions. Performance testing revealed that the spray-bar TVS was effective in controlling tank pressure within a 6.89 kPa band for fill levels of 90%, 50%, and 25%. Tests were also conducted with gaseous helium (GHe) in the ullage. The TVS operated nominally with GHe in the ullage, with performance similar to the tests with gaseous nitrogen (GN2). Testing demonstrated that the spray-bar TVS design was flexible enough for use in two different propellants with minimal hardware modifications.

  16. Spray and atomization of diesel fuel and its alternatives from a single-hole injector using a common rail fuel injection system

    KAUST Repository

    Chen, PinChia

    2013-01-01

    Fuel spray and atomization characteristics play an important role in the performance of internal combustion engines. As the reserves of petroleum fuel are expected to be depleted within a few decades, finding alternative fuels that are economically viable and sustainable to replace the petroleum fuel has attracted much research attention. In this work, the spray and atomization characteristics were investigated for commercial No. 2 diesel fuel, biodiesel (FAME) derived from waste cooking oil (B100), 20% biodiesel blended diesel fuel (B20), renewable diesel fuel produced in house, and civil aircraft jet fuel (Jet-A). Droplet diameters and particle size distributions were measured by a laser diffraction particle analyzing system and the spray tip penetrations and cone angles were acquired using a high speed imaging technique. All experiments were conducted by employing a common-rail high-pressure fuel injection system with a single-hole nozzle under room temperature and pressure. The experimental results showed that biodiesel and jet fuel had different features compared with diesel. Longer spray tip penetration and larger droplet diameters were observed for B100. The smaller droplet size of the Jet-A were believed to be caused by its relatively lower viscosity and surface tension. B20 showed similar characteristics to diesel but with slightly larger droplet sizes and shorter tip penetration. Renewable diesel fuel showed closer droplet size and spray penetration to Jet-A with both smaller than diesel. As a result, optimizing the trade-off between spray volume and droplet size for different fuels remains a great challenge. However, high-pressure injection helps to optimize the trade-off of spray volume and droplet sizes. Furthermore, it was observed that the smallest droplets were within a region near the injector nozzle tip and grew larger along the axial and radial direction. The variation of droplet diameters became smaller with increasing injection pressure.

  17. Effects of self-pulsation on the spray characteristics of gas-liquid swirl coaxial injector

    Science.gov (United States)

    Kang, Zhongtao; Li, Qinglian; Cheng, Peng; Zhang, Xinqiao; Wang, Zhen-guo

    2016-10-01

    To understand the influence of self-pulsation on the spray characteristics of gas-liquid swirl coaxial injector, a back-lighting photography technique has been employed to capture the instantaneous self-pulsated spray and stable spray images with a high speed camera. The diameter and velocity of the droplets in the spray have been characterized with a Dantec Phase Doppler Anemometry (PDA) system. The effects of self-pulsation on the spray pattern, primary breakup, spray angle, diameter and velocity distribution and mass flow rate distribution are analyzed and discussed. The results show that the spray morphology is greatly influenced by self-pulsation. The stable spray has a cone shape, while the self-pulsated spray looks like a Christmas tree. The main difference of these two sprays is the primary breakup. The liquid film of stable spray keeps stable while that of self-pulsated spray oscillates periodically. The film width of self-pulsated spray varies in a large range with 'neck' and 'shoulder' features existing. The liquid film of self-pulsated spray breaks up at the second neck, and then the second shoulder begins to breakup into ligaments. The self-pulsated spray produces droplet clusters periodically, varies horizontal spray width and mass flux periodically. From the point of spatial distribution, self-pulsation is good for the spray, it uniformizes the mass flux along radius and increases the spray angle. However, when self-pulsation occurs, the SMD distribution varies from an inverted V shape to a hollow cone shape, and SMD increases at all the measuring points. Namely, from the point of atomization performance, self-pulsation has negative effects even when the breakup length is smaller. The effects of self-pulsation on the diameter and velocity distributions of the spray are mainly in the center part of the spray. The periphery of stable and self-pulsated spray has similar diameter and velocity distribution.

  18. Estimation of equivalence ratio distribution in diesel spray using a computational fluid dynamics

    Science.gov (United States)

    Suzuki, Yasumasa; Tsujimura, Taku; Kusaka, Jin

    2014-08-01

    It is important to understand the mechanism of mixing and atomization of the diesel spray. In addition, the computational prediction of mixing behavior and internal structure of a diesel spray is expected to promote the further understanding about a diesel spray and development of the diesel engine including devices for fuel injection. In this study, we predicted the formation of diesel fuel spray with 3D-CFD code and validated the application by comparing experimental results of the fuel spray behavior and the equivalence ratio visualized by Layleigh-scatter imaging under some ambient, injection and fuel conditions. Using the applicable constants of KH-RT model, we can predict the liquid length spray on a quantitative level. under various fuel injection, ambient and fuel conditions. On the other hand, the change of the vapor penetration and the fuel mass fraction and equivalence ratio distribution with change of fuel injection and ambient conditions quantitatively. The 3D-CFD code used in this study predicts the spray cone angle and entrainment of ambient gas are predicted excessively, therefore there is the possibility of the improvement in the prediction accuracy by the refinement of fuel droplets breakup and evaporation model and the quantitative prediction of spray cone angle.

  19. Study on fuel particle motion of a diesel spray; Diesel funmu ryushi no kyodo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Ishikawa, N. [Isuzu Motors Ltd., Tokyo (Japan); Tsujimura, K.

    1998-08-25

    This study was performed to clarify the mechanism of mixture formation at peripheral area of diesel spray with PIV technique. Two dimensional cross-sectional photographs of diesel spray were taken with double pulse laser sheet. Local fuel spray particles were analyzed with an auto-correlation method and velocity vector and vorticity of the fuel spray particle were obtained. The vortex number increased and vorticity scale became smaller and its value grew higher with both smaller injection nozzle diameter and higher fuel injection velocity. With this injection condition, the mixing of fuel spray with ambient gas seems to be improved and the turbulence is expected to increase in the regions of higher vortex number, higher vorticity and smaller vorticity scale. Based on above results, the branch-like structure of diesel fuel spray was considered to be caused by vortices which formed in the shear layer between the spray and the ambient gas. 14 refs., 18 figs., 1 tab.

  20. Macroscopic Properties of Hollow Cone Spray Using an Outwardly Opening Piezoelectric Injector in GCI Engine

    KAUST Repository

    Cheng, Penghui

    2016-07-01

    Fuel mixture formation and spray characteristics are crucial for the advancement of Gasoline Compression Ignition (GCI) engine. For investigations of spray characteristics, a high-pressure high-temperature spray chamber with constant volume has been designed, tested and commissioned at CCRC, KAUST. Back light illumination technique has been applied to investigate the macroscopic spray properties of an outwardly opening piezoelec- tric injector. Three parameters including injection pressure, ambient pressure, and ambient temperature have been involved. A total of 18 combinations of experimental conditions were tested under non-reactive conditions. Through qualitative analysis of spray morphology under different operating conditions, an apparent distinction of spray morphology has been noticed. Spray morphology and propagation have shown strong dependencies on ambient pressure and ambient tempera- ture while injection pressure has a negligible effect on spray shape. Increasingly compact and bushier spray patterns were observed in the cases of high ambient pressure due to in- creasing aerodynamic drag force on spray boundary. It should also be noted that ambient temperature plays a fairly important role in fuel evaporation rate. At 200 °C, oscillating and considerably short spray shape was produced. Also, circumferential ring-like vortices and distinctive string-like structures have been identified for the fuel spray exiting this hollow cone injector. It has been observed that high ambient pressure conditions (Pamb = 4 bar and 10.5 bar) are favorable to the vortices generation, which has also been reported in previous literature. The quantitative description of macroscopic spray properties reveals that ambient pres- sure and ambient temperature are found to be the most influential parameters on liquid penetration length. The rise of ambient pressure results in considerably shorter liquid pen- etration length. Ambient temperature also appears to be a very effective

  1. Multi-zone modeling of Diesel engine fuel spray development with vegetable oil, bio-diesel or Diesel fuels

    International Nuclear Information System (INIS)

    Rakopoulos, C.D.; Antonopoulos, K.A.; Rakopoulos, D.C.

    2006-01-01

    This work presents a model of fuel sprays development in the cylinders of Diesel engines that is two-dimensional, multi-zone, with the issuing jet (from the nozzle) divided into several discrete volumes, called 'zones', formed along the direction of the fuel injection as well as across it. The model follows each zone, with its own time history, as the spray penetrates into the swirling air environment of the combustion chamber before and after wall impingement. After the jet break up time, a group of droplets is generated in each zone, with the model following their motion during heating, evaporation and mixing with the in-cylinder air. The model is applied for the interesting case of using vegetable oils or their derived bio-diesels as fuels, which recently are considered as promising alternatives to petroleum distillates since they are derived from biological sources. Although there are numerous experimental studies that show curtailment of the emitted smoke with possible increase of the emitted NO x against the use of Diesel fuel, there is an apparent scarcity of theoretical models scrutinizing the formation mechanisms of combustion generated emissions when using these biologically derived fuels. Thus, in the present work, a theoretical detailed model of spray formation is developed that is limited to the related investigation of the physical processes by decoupling it from the chemical effects after combustion initiation. The analysis results show how the widely differing physical properties of these fuels, against the normal Diesel fuel, affect greatly the spray formation and consequently the combustion mechanism and the related emissions

  2. Advanced Research in Diesel Fuel Sprays Using X-rays From The Advanced Photon Source

    International Nuclear Information System (INIS)

    Powell, C.

    2003-01-01

    The fuel distribution and degree of atomization in the combustion chamber is a primary factor in the formation of emissions in diesel engines. A number of diagnostics to study sprays have been developed over the last twenty years; these are primarily based on visible light measurement techniques. However, visible light scatters strongly from fuel droplets surrounding the spray, which prevents penetration of the light. This has made quantitative measurements of the spray core very difficult, particularly in the relatively dense near- nozzle region [1-3]. For this reason we developed the x-ray technique to study the properties of fuel sprays in a quantitative way [4]. The x-ray technique is not limited by scattering, which allows it to be used to make quantitative measurements of the fuel distribution. These measurements are particularly effective in the region near the nozzle where other techniques fail. This technique has led to a number of new insights into the structure of fuel sprays, including the discovery and quantitative measurement of shock waves generated under some conditions by high-pressure diesel sprays [5]. We also performed the first-ever quantitative measurements of the time-resolved mass distribution in the near-nozzle region, which demonstrated that the spray is atomized only a few nozzle diameters from the orifice [6]. Our recent work has focused on efforts to make measurements under pressurized ambient conditions. We have recently completed a series of measurements at pressures up to 5 bar and are looking at the effect of ambient pressure on the structure of the spray. The enclosed figure shows the mass distributions measured for 1,2, and 5 bar ambient pressures. As expected, the penetration decreases as the pressure increases. This leads to changes in the measured mass distribution, including an increase in the density at the leading edge of the spray. We have also observed a narrowing in the cone angle of the spray core as the pressure

  3. The Effect of Fuel Injector Nozzle Configuration on JP-8 Sprays at Diesel Engine Conditions

    Science.gov (United States)

    2014-10-01

    The Effect of Fuel Injector Nozzle Configuration on JP-8 Sprays at Diesel Engine Conditions by Matthew Kurman, Luis Bravo, Chol-Bum Kweon...Fuel Injector Nozzle Configuration on JP-8 Sprays at Diesel Engine Conditions Matthew Kurman, Luis Bravo, and Chol-Bum Kweon Vehicle Technology...March 2014 4. TITLE AND SUBTITLE The Effect of Fuel Injector Nozzle Configuration on JP-8 Sprays at Diesel Engine Conditions 5a. CONTRACT NUMBER 5b

  4. Heat flux characteristics of spray wall impingement with ethanol, butanol, iso-octane, gasoline and E10 fuels

    International Nuclear Information System (INIS)

    Serras-Pereira, J.; Aleiferis, P.G.; Walmsley, H.L.; Davies, T.J.; Cracknell, R.F.

    2013-01-01

    Highlights: • Heat flux sensors used to characterise the locations of fuel spray wall impingement. • Droplet evaporation modelling used to study the effect of fuel properties. • Behaviour of ethanol and butanol distinctively different to hydrocarbons. -- Abstract: Future fuel stocks for spark-ignition engines are expected to include a significant portion of bio-derived components with quite different chemical and physical properties to those of liquid hydrocarbons. State-of-the-art high-pressure multi-hole injectors for latest design direct-injection spark-ignition engines offer some great benefits in terms of fuel atomisation, as well as flexibility in in-cylinder fuel targeting by selection of the exact number and angle of the nozzle’s holes. However, in order to maximise such benefits for future spark-ignition engines and minimise any deteriorating effects with regards to exhaust emissions, it is important to avoid liquid fuel impingement onto the cylinder walls and take into consideration various types of biofuels. This paper presents results from the use of heat flux sensors to characterise the locations and levels of liquid fuel impingement onto the engine’s liner walls when injected from a centrally located multi-hole injector with an asymmetric pattern of spray plumes. Ethanol, butanol, iso-octane, gasoline and a blend of 10% ethanol with 90% gasoline (E10) were tested and compared. The tests were performed in the cylinder of a direct-injection spark-ignition engine at static conditions (i.e. quiescent chamber at 1.0 bar) and motoring conditions (at full load with inlet plenum pressure of 1.0 bar) with different engine temperatures in order to decouple competing effects. The collected data were analysed to extract time-resolved signals, as well as mean and standard deviation levels of peak heat flux. The results were interpreted with reference to in-cylinder spray formation characteristics, as well as fuel evaporation rates obtained by modelling

  5. Study of Heterogeneous Structure in Diesel Fuel Spray by Using Micro-Probe L2F

    Science.gov (United States)

    Sakaguchi, Daisaku; Yamamoto, Shohei; Ueki, Hironobu; Ishdia, Masahiro

    A L2F (Laser 2-Focus velocimeter) was applied for the measurements of the velocity and size of droplets in diesel fuel sprays. The micro-scale probe of the L2F has an advantage in avoiding the multiple scattering from droplets in a dense region of fuel sprays. A data sampling rate of 15MHz has been achieved in the L2F system for detecting almost all of the droplets which passed through the measurement probe. Diesel fuel was injected into the atmosphere by using a common rail injector. Measurement positions were located along the spray axis at 10, 15, 20, 25, and 30 mm from the nozzle exit. Measurement result showed that the velocity and size of droplets decreased and the number density of droplets increased along the spray axis. It was clearly shown that the mass flow rate in the spray was highest near the spray tip and was lower inside the spray.

  6. Shock Tube Measurements for Liquid Fuels Combustion

    National Research Council Canada - National Science Library

    Hanson, Ronald K

    2006-01-01

    ...) fundamental studies of fuel spray evaporation rates and ignition times of low-vapor pressure fuels such as JP-8, diesel fuel and normal alkane surrogates in a new aerosol shock tube using state...

  7. Influence of fuel temperature on dispersion and decay of BDE sprays; Einfluss der Kraftstofftemperatur auf die Ausbreitung und den Zerfall von BDE-Sprays

    Energy Technology Data Exchange (ETDEWEB)

    Schmitz, I.; Beyrau, F.; Leipertz, A. [Erlangen-Nuernberg Univ., Erlangen (Germany). Lehrstuhl fuer Technische Thermodynamik

    2007-07-01

    As an example for a highly - developed technical spray system, the spray vaporization of a multi - hole injector used for the gasoline direct injection (GDI) has been investigated. Experiments were conducted in a heated injection chamber for different chamber pressures, fuels and fuel temperatures. In this investigation pure rotational coherent anti-Stokes Raman spectroscopy (RCARS) has been applied to the study of vaporizing sprays in combination with other laser techniques. Gas phase temperatures inside the sprays have been determined with high spatial and temporal resolution. A temperature drop of about 30 K was measured for all fuel temperatures studied. Droplet sizes and number densities have been measured using phase Doppler anemometry, and the correlation of these results with two - dimensional laser sheet Mie scattering images and laser-induced exciplex fluorescence allows an improved interpretation of the spray vaporization process. Furthermore under the influence of flash boiling a reduction of the mean drop size D10 up to 30% could be observed. (orig.)

  8. Droplets and sprays

    CERN Document Server

    Sazhin, Sergei

    2014-01-01

    Providing a clear and systematic description of droplets and spray dynamic models, this book maximises reader insight into the underlying physics of the processes involved, outlines the development of new physical and mathematical models, and broadens understanding of interactions between the complex physical processes which take place in sprays. Complementing approaches based on the direct application of computational fluid dynamics (CFD), Droplets and Sprays treats both theoretical and practical aspects of internal combustion engine process such as the direct injection of liquid fuel, subcritical heating and evaporation. Includes case studies that illustrate the approaches relevance to automotive applications,  it is also anticipated that the described models can find use in other areas such as in medicine and environmental science.

  9. Numerical Simulation and Analysis on Liquid Nitrogen Spray Heat Exchanger

    OpenAIRE

    Wenjing Ding; Weiwei Shan; Zijuan; Wang; Chao He

    2017-01-01

    Liquid spray heat exchanger is the critical equipment of temperature regulating system by gaseous nitrogen which realizes the environment temperature in the range of -180 ℃~+180 ℃. Liquid nitrogen is atomized into smaller liquid drops through liquid nitrogen sprayer and then contacts with gaseous nitrogen to be cooled. By adjusting the pressure of liquid nitrogen and gaseous nitrogen, the flowrate of liquid nitrogen is changed to realize the required outlet temperature of heat exchanger. The ...

  10. Laser-Based Spatio-Temporal Characterisation of Port Fuel Injection (PFI Sprays

    Directory of Open Access Journals (Sweden)

    C. T. N. Anand

    2010-06-01

    Full Text Available In the present work, detailed laser-based diagnostic experiments were conducted to characterise the spray from low pressure 2-hole and 4-hole Port Fuel Injection (PFI injectors. The main objective of the work included obtaining quantitative information of the spatio-temporal spray structure of such low-pressure gasoline sprays. A novel approach involving a combination of techniques such as Mie scattering, Granulometry, and Laser Sheet Dropsizing (LSD was used to study the spray structure. The droplet sizes, distributions with time, Sauter Mean Diameters (SMD, droplet velocities, cone angles and spray tip penetrations of the sprays from the injectors were determined. The spray from these injectors is found to be ‘pencil like’ and not dispersed as in high pressure sprays. The application of the above mentioned techniques provides two-dimensional SMD contours of the entire spray at different instants of time, with reasonable accuracy.

  11. Microstructure formation and corrosion behaviour in HVOF-sprayed Inconel 625 coatings

    International Nuclear Information System (INIS)

    Zhang, D.; Harris, S.J.; McCartney, D.G.

    2003-01-01

    The nickel-based alloy Inconel 625 was thermally sprayed by two different variants of the high velocity oxy-fuel process. In this study, coatings deposited by a liquid-fuelled gun were compared with those produced by a gas-fuelled system; in general, the former generates higher particle velocities but lower particle temperatures. Investigations into the microstructural evolution of the coatings, using scanning electron microscopy and X-ray diffraction, are presented along with results on their aqueous corrosion behaviour, obtained from salt spray and potentiodynamic tests. It is inferred from coating microstructures that, during spraying, powder particles generally comprised three separate zones as follows: fully melted regions; partially melted zones; and an unmelted core. However, the relative proportions formed in an individual powder particle depended on its size, trajectory through the gun, the gas dynamics (velocity/temperature) of the thermal spray gun and the type of gun employed. Cr 2 O 3 was the principal oxide phase formed during spraying and the quantity appeared to be directly related to the degree to which particles were melted. The salt spray test provides a sensitive means of determining the presence of interconnected porosity in coatings and those produced with the liquid-fuelled gun exhibited reduced interconnected porosity and increased corrosion resistance compared with deposits obtained from the gas-fuelled system. In addition, potentiodynamic tests revealed that passive current densities are 10-20 times lower in liquid-fuel coatings than in those sprayed with the gas-fuelled gun

  12. Computational Modeling of Turbulent Spray Combustion

    NARCIS (Netherlands)

    Ma, L.

    2016-01-01

    The objective of the research presented in this thesis is development and validation of predictive models or modeling approaches of liquid fuel combustion (spray combustion) in hot-diluted environments, known as flameless combustion or MILD combustion. The goal is to combine good physical insight,

  13. Hollow-Cone Spray Modeling for Outwardly Opening Piezoelectric Injector

    KAUST Repository

    Sim, Jaeheon

    2016-01-04

    Linear instability sheet atomization (LISA) breakup model has been widely used for modeling hollow-cone spray. However, the model was originally developed for inwardlyopening pressure-swirl injectors by assuming toroidal ligament breakups. Therefore, LISA model is not suitable for simulating outwardly opening injectors having string-like structures at wide spray angles. Furthermore, the varying area and shape of the annular nozzle exit makes the modeling difficult. In this study, a new spray modeling was proposed for outwardly opening hollow-cone injector. The injection velocities are computed from the given mas flow rate and injection pressure regardless of ambiguous nozzle exit geometries. The modified Kelvin-Helmholtz and Rayleigh-Taylor (KH-RT) breakup model is used with adjusted initial Sauter mean diameter (SMD) for modeling breakup of string-like liquid film spray. Liquid spray injection was modeled using Lagrangian discrete parcel method within the framework of commercial CFD software CONVERGE, and the detailed model was implemented by user defined functions. It was found that the new model predicted the liquid penetration length and local SMD accurately for various fuels and chamber conditions.

  14. Coupled Lagrangian impingement spray model for doublet impinging injectors under liquid rocket engine operating conditions

    Directory of Open Access Journals (Sweden)

    Qiang WEI

    2017-08-01

    Full Text Available To predict the effect of the liquid rocket engine combustion chamber conditions on the impingement spray, the conventional uncoupled spray model for impinging injectors is extended by considering the coupling of the jet impingement process and the ambient gas field. The new coupled model consists of the plain-orifice sub-model, the jet-jet impingement sub-model and the droplet collision sub-model. The parameters of the child droplet are determined with the jet-jet impingement sub-model using correlations about the liquid jet parameters and the chamber conditions. The overall model is benchmarked under various impingement angles, jet momentum and off-center ratios. Agreement with the published experimental data validates the ability of the model to predict the key spray characteristics, such as the mass flux and mixture ratio distributions in quiescent air. Besides, impinging sprays under changing ambient pressure and non-uniform gas flow are investigated to explore the effect of liquid rocket engine chamber conditions. First, a transient impingement spray during engine start-up phase is simulated with prescribed pressure profile. The minimum average droplet diameter is achieved when the orifices work in cavitation state, and is about 30% smaller than the steady single phase state. Second, the effect of non-uniform gas flow produces off-center impingement and the rotated spray fan by 38°. The proposed model suggests more reasonable impingement spray characteristics than the uncoupled one and can be used as the first step in the complex simulation of coupling impingement spray and combustion in liquid rocket engines.

  15. Coupled Lagrangian impingement spray model for doublet impinging injectors under liquid rocket engine operating conditions

    Institute of Scientific and Technical Information of China (English)

    Qiang WEI; Guozhu LIANG

    2017-01-01

    To predict the effect of the liquid rocket engine combustion chamber conditions on the impingement spray,the conventional uncoupled spray model for impinging injectors is extended by considering the couplingof the jet impingement process and the ambient gas field.The new coupled model consists of the plain-orifice sub-model,the jet-jet impingement sub-model and the droplet collision sub-model.The parameters of the child droplet are determined with the jet-jet impingement sub-model using correlations about the liquid jet parameters and the chamber conditions.The overall model is benchmarked under various impingement angles,jet momentum and offcenter ratios.Agreement with the published experimental data validates the ability of the model to predict the key spray characteristics,such as the mass flux and mixture ratio distributions in quiescent air.Besides,impinging sprays under changing ambient pressure and non-uniform gas flow are investigated to explore the effect of liquid rocket engine chamber conditions.First,a transient impingement spray during engine start-up phase is simulated with prescribed pressure profile.The minimum average droplet diameter is achieved when the orifices work in cavitation state,and is about 30% smaller than the steady single phase state.Second,the effect of non-uniform gas flow produces off-center impingement and the rotated spray fan by 38°.The proposed model suggests more reasonable impingement spray characteristics than the uncoupled one and can be used as the first step in the complex simulation of coupling impingement spray and combustion in liquid rocket engines.

  16. Development of Combustion Tube for Gaseous, Liquid, and Solid Fuels to Study Flame Acceleration and DDT

    Science.gov (United States)

    Graziano, Tyler J.

    An experimental combustion tube of 20 ft. in length and 10.25 in. in internal diameter was designed and fabricated in order to perform combustion tests to study deflagration rates, flame acceleration, and the possibility of DDT. The experiment was designed to allow gaseous, liquid, or solid fuels, or any combination of the three to produce a homogenous fuel/air mixture within the tube. Combustion tests were initiated with a hydrogen/oxygen torch igniter and the resulting flame behavior was measured with high frequency ion probes and pressure transducers. Tests were performed with a variety of gaseous and liquid fuels in an unobstructed tube with a closed ignition end and open muzzle. The flame performance with the gaseous fuels is loosely correlated with the expansion ratio, while there is a stronger correlation with the laminar flame speed. The strongest correlation to flame performance is the run-up distance scaling factor. This trend was not observed with the liquid fuels. The reason for this is likely due to incomplete evaporation of the liquid fuel droplets resulting in a partially unburned mixture, effectively altering the intended equivalence ratio. Results suggest that the simple theory for run-up distance and flame acceleration must be modified to more accurately predict the behavior of gaseous fuels. Also, it is likely that more complex spray combustion modeling is required to accurately predict the flame behavior for liquid fuels.

  17. Transported PDF Modeling of Ethanol Spray in Hot-Diluted Coflow Flame

    NARCIS (Netherlands)

    Ma, L.; Naud, B.; Roekaerts, D.J.E.M.

    2015-01-01

    This paper presents a numerical modeling study of one ethanol spray flame from the Delft Spray-in-Hot-Coflow (DSHC) database, which has been used to study Moderate or Intense Low-oxygen Dilution (MILD) combustion of liquid fuels (Correia Rodrigues et al. Combust. Flame 162(3), 759–773, 2015). A

  18. Real gas effects in mixing-limited diesel spray vaporization models

    NARCIS (Netherlands)

    Luijten, C.C.M.; Kurvers, C.

    2010-01-01

    The maximum penetration length of the liquid phase in diesel sprays is of paramount importance in reducing diesel engine emissions. Quasi-steady liquid length values have been successfully correlated in the literature, assuming that mixing of fuel and air is the limiting step in the evaporation

  19. Characterization of the liquid sodium spray generated by a pipework hole

    International Nuclear Information System (INIS)

    Torsello, G.; Parozzi, F.; Nericcio, L.; Araneo, L.; Cozzi, F.; Carcassi, M.; Mattei, N.

    2012-01-01

    Due to its advantageous thermodynamic characteristics at high temperature (550 deg. C), liquid sodium is the main candidate to be the cooling fluid for Generation TV nuclear reactors SFR (Sodium-cooled Fast Reactors). Now, sodium reacts very violently, both with the water and the oxygen of the air. Only few data were known about the liquid sodium behaviour when spread in the environment through micro defects. These are often present in a cooling circuit in welded or sealed joints and more rarely in the pipes. Micro defects, on the other hand, can be also generated in a cooling circuit because of the vibrations always present in a circuit into which a fluid runs. A new set-up, named LISOF, was built for testing high temperature liquid sodium when passing through micro defects and generating sprays or jets. Sprays and jets were generated by means of nozzles embedding sub milli-metric holes the diameter of which was: 0.2 mm, 0.4 mm, 0.5 mm. Tests were performed by pressurizing liquid sodium (550 deg. C) at: 3, 6 and 9 barg. Normal and high speed cinematography were used for the direct observation of the liquid sodium sprays while Phase Doppler Interferometry was used for the measurement of the droplets characteristics and velocity. Tests concerning the behaviour of the high temperature liquid sodium firing in air or in contact with the cement cover applied to a scaled down core catcher simulacrum were also performed. The paper presents the built set-up and the collected results. (authors)

  20. Characterization of the liquid sodium spray generated by a pipework hole

    Energy Technology Data Exchange (ETDEWEB)

    Torsello, G.; Parozzi, F.; Nericcio, L. [RSE - Nuclear and Industrial Plant Safety Team, Power Generation System Dept., via Rubattino 54, 20134 Milano (Italy); Araneo, L.; Cozzi, F. [Politecnico di Milano, Energy Dept., via Lambruschini 4, 20156 Milano (Italy); Carcassi, M.; Mattei, N. [Universita di Pisa-Facolta d' Ingegneria DIMNP-Mechanical, Nuclear and Production Dep., Largo L. Lazzarino 2, 56126 Pisa (Italy)

    2012-07-01

    Due to its advantageous thermodynamic characteristics at high temperature (550 deg. C), liquid sodium is the main candidate to be the cooling fluid for Generation TV nuclear reactors SFR (Sodium-cooled Fast Reactors). Now, sodium reacts very violently, both with the water and the oxygen of the air. Only few data were known about the liquid sodium behaviour when spread in the environment through micro defects. These are often present in a cooling circuit in welded or sealed joints and more rarely in the pipes. Micro defects, on the other hand, can be also generated in a cooling circuit because of the vibrations always present in a circuit into which a fluid runs. A new set-up, named LISOF, was built for testing high temperature liquid sodium when passing through micro defects and generating sprays or jets. Sprays and jets were generated by means of nozzles embedding sub milli-metric holes the diameter of which was: 0.2 mm, 0.4 mm, 0.5 mm. Tests were performed by pressurizing liquid sodium (550 deg. C) at: 3, 6 and 9 barg. Normal and high speed cinematography were used for the direct observation of the liquid sodium sprays while Phase Doppler Interferometry was used for the measurement of the droplets characteristics and velocity. Tests concerning the behaviour of the high temperature liquid sodium firing in air or in contact with the cement cover applied to a scaled down core catcher simulacrum were also performed. The paper presents the built set-up and the collected results. (authors)

  1. Applicability of fan spray nozzles to stripping insoluble gases from viscous liquids

    International Nuclear Information System (INIS)

    Tseng, H.H.; Johnson, E.F.

    1983-08-01

    Fan spray nozzle stripping appears to be a practical technique for separating dilute volatile solutes from nonvolatile solvents. In particular this technique can be used to strip molecular tritium and tritium fluoride at extremely small concentration (in the parts per million range) from molten salts used as blanket materials in a fusion reactor. Under adjusted operating conditions of the fan spray as it leaves the nozzle, a high percentage of the theoretically maximum achievable stripping would take place from the expanding sheet of the fan spray as it leaves the nozzle and before it breaks up. Although the only available experimental data are for aqueous solutions, a new theoretical analysis of the fan spray sheet demonstrates the applicability of this technique to nonaqueous liquids. The equation derived from this analysis relates the theoretically achievable mass transfer efficiency to the properties of the liquid flowing through the fan spray nozzle and to the operating conditions of the nozzle. Any fluid with viscosity higher than or equal to that of water would be expected to follow this equation as long as a fan-shaped sheet is formed under the operating conditions of the nozzle

  2. Limitations on the use of the planar laser induced exciplex fluorescence technique in diesel sprays

    Energy Technology Data Exchange (ETDEWEB)

    J.M. Desantes; J.V. Pastor; J.M. Pastor; J.E. Julia [Universidad Politecnica de Valencia, Valencia (Spain). CMT Motores Termicos

    2005-12-01

    The Planar Laser Induced Exciplex Fluorescence (PLIEF) technique is widely used to visualize and measure the fuel concentration fields in both liquid and vapor phases of DI Diesel sprays. However, the real limitations of the PLIEF technique in Diesel sprays and the accuracy of the results obtained are still a source of controversy. In this work, a complete methodology for maximum penetration and fuel concentration measurements in evaporating conditions in Diesel sprays has been developed and the reliability of the results obtained has been investigated. The methodology includes new procedures for measuring both liquid and vapor phases, adapting, when necessary, correlations available in the literature for calibration. An experimental matrix of nine test points with different injection pressures and combustion chamber densities has been performed. A critical analysis of the different error sources for proper quantification is made. Results have shown that macroscopic features can be accurately determined using the PLIEF technique, but for fuel concentration measurements special considerations have to be taken into account, particularly in the regions where liquid and vapor coexist. 37 refs., 15 figs., 2 tabs.

  3. Liquid sprays and flow studies in the direct-injection diesel engine under motored conditions

    Science.gov (United States)

    Nguyen, Hung Lee; Carpenter, Mark H.; Ramos, Juan I.; Schock, Harold J.; Stegeman, James D.

    1988-01-01

    A two dimensional, implicit finite difference method of the control volume variety, a two equation model of turbulence, and a discrete droplet model were used to study the flow field, turbulence levels, fuel penetration, vaporization, and mixing in diesel engine environments. The model was also used to study the effects of engine speed, injection angle, spray cone angle, droplet distribution, and intake swirl angle on the flow field, spray penetration and vaporization, and turbulence in motored two-stroke diesel engines. It is shown that there are optimum conditions for injection, which depend on droplet distribution, swirl, spray cone angle, and injection angle. The optimum conditions result in good spray penetration and vaporization and in good fuel mixing. The calculation presented clearly indicates that internal combustion engine models can be used to assess, at least qualitatively, the effects of injection characteristics and engine operating conditions on the flow field and on the spray penetration and vaporization in diesel engines.

  4. Sensitivity Analysis of Heavy Fuel Oil Spray and Combustion under Low-Speed Marine Engine-Like Conditions

    Directory of Open Access Journals (Sweden)

    Lei Zhou

    2017-08-01

    Full Text Available On account of their high power, thermal efficiency, good reliability, safety, and durability, low-speed two-stroke marine diesel engines are used as the main drive devices for large fuel and cargo ships. Most marine engines use heavy fuel oil (HFO as the primary fuel, however, the physical and chemical characteristics of HFO are not clear because of its complex thermophysical properties. The present study was conducted to investigate the effects of fuel properties on the spray and combustion characteristics under two-stroke marine engine-like conditions via a sensitivity analysis. The sensitivity analysis of fuel properties for non-reacting and reacting simulations are conducted by comparing two fuels having different physical properties, such as fuel density, dynamic viscosity, critical temperature, and surface tension. The performances of the fuels are comprehensively studied under different ambient pressures, ambient temperatures, fuel temperatures, and swirl flow conditions. From the results of non-reacting simulations of HFO and diesel fuel properties in a constant volume combustion chamber, it can be found that the increase of the ambient pressure promotes fuel evaporation, resulting in a reduction in the steady liquid penetration of both diesel and HFO; however, the difference in the vapor penetrations of HFO and diesel reduces. Increasing the swirl flow significantly influences the atomization of both HFO and diesel, especially the liquid distribution of diesel. It is also found that the ambient temperature and fuel temperature have the negative effects on Sauter mean diameter (SMD distribution. For low-speed marine engines, the combustion performance of HFO is not sensitive to activation energy in a certain range of activation energy. At higher engine speed, the difference in the effects of different activation energies on the in-cylinder pressure increases. The swirl flow in the cylinder can significantly promote fuel evaporation and

  5. A Review on Atomization and Sprays of Biofuels for IC Engine Applications

    Directory of Open Access Journals (Sweden)

    Prasad Boggavarapu

    2013-06-01

    Full Text Available Ever increasing energy requirements, environmental concerns and energy security needs are strongly influencing engine researchers to consider renewable biofuels as alternatives to fossil fuels. Spray process being important in IC engine combustion, existing literature on various biofuel sprays is reviewed and summarized. Both experimental and computational research findings are reviewed in a detailed manner for compression ignition (CI engine sprays and briefly for spark ignition (SI engine sprays. The physics of basic atomization process of sprays from various injectors is included to highlight the most recent research findings followed by discussion highlighting the effect of physico-chemical properties on spray atomization for both biofuels and fossil fuels. Biodiesel sprays are found to penetrate faster and have narrow spray plume angle and larger droplet sizes compared to diesel. Results of analytical and computational models are shown to be useful in shedding light on the actual process of atomization. However, further studies on understanding primary atomization and the effect of fuel properties on primary atomization are required. As far as secondary atomization is concerned, changes in regimes are observed to occur at higher air-jet velocities for biodiesel compared to those of diesel. Evaporating sprays revealed that the liquid length is longer for biodiesel. Pure plant oil sprays with potential use in CI engines may require alternative injector technology due to slower breakup as compared to diesel. Application of ethanol to gasoline engines may be feasible without any modifications to port fuel injection (PFI engines. More studies are required on the application of alternative fuels to high pressure sprays used in Gasoline Direct Injection (GDI engines.

  6. Governing parameters and dynamics of turbulent spray atomization from modern GDI injectors

    International Nuclear Information System (INIS)

    Moon, Seoksu; Li, Tianyun; Sato, Kiyotaka; Yokohata, Hideaki

    2017-01-01

    Understanding the governing parameters and dynamics of turbulent spray atomization is essential for the advancement of fuel injection technologies, but no concrete understandings have been derived previously. The current study investigates the governing parameters and dynamics of turbulent spray atomization by experimental observations of near-nozzle spray phenomena using an X-ray imaging technique. The effects of critical injection parameters such as fuel property, injection pressure and ambient density on near-nozzle liquid feature size and velocity distributions were extensively studied using three injection nozzles having different levels of initial flow turbulence and dispersion. Based on the results, the governing parameters and dynamics of turbulent spray atomization and the issues on the advanced fuel injection control of modern engines were thoroughly discussed. The results showed that fuel and injection pressure effects on spray atomization became insignificant from a critical Weber number which decreased upon the increase in initial flow turbulence and dispersion. The increase in ambient density increased the resultant droplet size at downstream due to the faster deceleration of spray which brought the atomization termination location closer to the nozzle exit. The spray atomization was terminated at the location of ca. 72% exit velocity regardless of the injection condition. - Highlights: • Governing parameters and dynamics of turbulent spray atomization are investigated. • Fuel and injection pressure effects on atomization are saturated from critical We. • High ambient density increases drop sizes due to faster termination of atomization. • Atomization terminates when the spray velocity decays to ca. 72% of exit velocity. • Strategies for improvement of current injection technologies are discussed.

  7. Effect of wall impingement on ambient gas entrainment, fuel evaporation and mixture formation of diesel spray

    Energy Technology Data Exchange (ETDEWEB)

    Nishida, Keiya [Department of Mechanical Physics Engineering, University of Hiroshima (Japan); Matsumoto, Yuhei; Zhang, Wu [Mazda Motor Corp. (Japan); Gao, Jian [University of Wisconsin (United States); Moon, Seoksu [Argonne National Laboratory (United States)

    2010-07-01

    In the energy sector, with the implementation of stringent regulations on combustion emissions and the depletion of conventional fuels, there is a pressing need to improve the performance of engines. The purpose of this paper is to determine the impact of wall impingement on several characteristics of diesel spray. Experiments were carried out with both a small and a large amount of diesel spray injected and ambient gas entrainment, fuel evaporation and mixture formation were evaluated using an LAS optical system. Results showed that wall impingement has the same effects for small or large amounts of diesel spray injected; these are: a larger volume spray after the impingement and a smaller volume after it, the suppression of ambient gas entrainment and fuel evaporation, and the shift of the PDF peak of the vapor equivalent ratio. This study provided useful information but further work is needed to address the remaining issues.

  8. Study on condensation of biomass pyrolysis gas by spray bio-oil droplets

    Energy Technology Data Exchange (ETDEWEB)

    Xie, Kun; Cheng, Wen-Long [University of Science and Technology of China (China)], email: wlcheng@ustc.edu.cn; Chen, Jing [Anhui Electric Power Design Institute (China); Shi, Wen-Jing [Anhui Heli Co., Ltd (China)

    2011-07-01

    This is a study of bio-oil generated by fast pyrolysis; a biomass feedstock is heated to pyrolyze at a rapid rate, the gas pyrolyzed is then condensed rapidly. The interesting result is a potential alternative fuel oil. An analysis was made of the effects of the initial pyrolysis gas temperatures, the initial bio-oil droplets temperatures and diameters, and the flow ratio of the gas and the liquid droplets on the heat and mass transfer between the gas and the liquid droplets. A few criterion equations were achieved with respect to the spray condenser. This paper established the gas-liquid phase equilibrium of an aqueous multi-composition system and the spray condensation model coupling heat and mass transfer. Model calculation and analysis showed that: spray condensation can effectively cool the high-temperature pyrolysis gas quickly; with gas liquid flowing, mass transfer rate reduces; and the relationship of gas and liquid flow ratio can achieve good accuracy.

  9. Flash radiographic technique applied to fuel injector sprays

    International Nuclear Information System (INIS)

    Vantine, H.C.

    1977-01-01

    A flash radiographic technique, using 50 ns exposure times, was used to study the pattern and density distribution of a fuel injector spray. The experimental apparatus and method are described. An 85 kVp flash x-ray generator, designed and fabricated at the Lawrence Livermore Laboratory, is utilized. Radiographic images, recorded on standard x-ray films, are digitized and computer processed

  10. Time-resolved measurements of supersonic fuel sprays using synchrotron X-rays.

    Science.gov (United States)

    Powell, C F; Yue, Y; Poola, R; Wang, J

    2000-11-01

    A time-resolved radiographic technique has been developed for probing the fuel distribution close to the nozzle of a high-pressure single-hole diesel injector. The measurement was made using X-ray absorption of monochromatic synchrotron-generated radiation, allowing quantitative determination of the fuel distribution in this optically impenetrable region with a time resolution of better than 1 micros. These quantitative measurements constitute the most detailed near-nozzle study of a fuel spray to date.

  11. Spray and atomization of diesel fuel and its alternatives from a single-hole injector using a common rail fuel injection system

    KAUST Repository

    Chen, PinChia; Wang, Weicheng; Roberts, William L.; Fang, Tiegang

    2013-01-01

    Fuel spray and atomization characteristics play an important role in the performance of internal combustion engines. As the reserves of petroleum fuel are expected to be depleted within a few decades, finding alternative fuels that are economically

  12. The spray characteristic of gas-liquid coaxial swirl injector by experiment

    OpenAIRE

    Chen Chen; Zhihui Yan; Yang Yang; Hongli Gao; Shunhua Yang; Lei Zhang

    2017-01-01

    Using the laser phase Doppler particle analyzer (PDPA), the spray characteristics of gas-liquid coaxial swirl injector were studied. The Sauter mean diameter (SMD), axial velocity and size data rate were measured under different gas injecting pressure drop and liquid injecting pressure drop. Comparing to a single liquid injection, SMD with gas presence is obviously improved. So the gas presence has a significant effect on the atomization of the swirl injector. What’s more, the atomization eff...

  13. A Numerical Comparison of Spray Combustion between Raw and Water-in-Oil Emulsified Fuel

    Directory of Open Access Journals (Sweden)

    D. Tarlet

    2010-03-01

    Full Text Available Heavy fuel-oils, used engine oils and animal fat can be used as dense, viscous combustibles within industrial boilers. Burning these combustibles in the form of an emulsion with water enables to decrease the flame length and the formation of carbonaceous residue, in comparison with raw combustibles. These effects are due to the secondary atomization among the spray, which is a consequence of the micro-explosion phenomenon. This phenomenon acts in a single emulsion droplet by the fast (< 0.1 ms vaporization of the inside water droplets, leading to complete disintegration of the whole emulsion droplet. First, the present work demonstrates a model of spray combustion of raw fuel. Secondly, the spray combustion of water-in-oil emulsified fuel is exposed to the same burning conditions, taking into account the micro-explosion phenomenon. Finally, the comparison between the results with and without second atomization shows some similar qualitative tendencies with experimental measurements from the literature.

  14. Time-resolved measurements of supersonic fuel sprays using synchrotron x-rays

    International Nuclear Information System (INIS)

    Powell, C.F.; Yue, Y.; Poola, R.; Wang, J.

    2000-11-01

    A time-resolved radiographic technique has been developed for probing the fuel distribution close to the nozzle of a high-pressure single-hole diesel injector. The measurement was made using X-ray absorption of monochromatic synchrotron-generated radiation, allowing quantitative determination of the fuel distribution in this optically impenetrable region with a time resolution of better than 1 μs. These quantitative measurements constitute the most detailed near-nozzle study of a fuel spray to date

  15. Modeling ethanol spray jet flame in hot-diluted coflow with transported PDF

    OpenAIRE

    Ma, L.; Naud, B.; Roekaerts, D.J.E.M.

    2014-01-01

    MILD Combustion, also known as flameless combustion, is attracting wide scientific interest due to its potential of high efficiency and low NOx emission. This paper focuses on the numerical modeling of one of the ethanol spray flame cases from the Delft Spray-in-Hot-Coflow (DSHC) burner, which has been used to study MILD oxidation of liquid fuels. The study has been carried out following the approach of dilute spray simulation. To properly account the turbulent two-phase flow system, a joint ...

  16. Low Emissions Burner Technology for Metal Processing Industry using Byproducts and Biomass Derived Liquid Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Agrawal, Ajay; Taylor, Robert

    2013-09-30

    This research and development efforts produced low-emission burner technology capable of operating on natural gas as well as crude glycerin and/or fatty acids generated in biodiesel plants. The research was conducted in three stages (1) Concept definition leading to the design and development of a small laboratory scale burner, (2) Scale-up to prototype burner design and development, and (3) Technology demonstration with field vefiication. The burner design relies upon the Flow Blurring (FB) fuel injection based on aerodynamically creating two-phase flow near the injector exit. The fuel tube and discharge orifice both of inside diameter D are separated by gap H. For H < 0.25D, the atomizing air bubbles into liquid fuel to create a two-phase flow near the tip of the fuel tube. Pressurized two-phase fuel-air mixture exits through the discharge orifice, which results in expansion and breakup of air bubbles yielding a spray with fine droplets. First, low-emission combustion of diesel, biodiesel and straight VO (soybean oil) was achieved by utilizing FB injector to yield fine sprays for these fuels with significantly different physical properties. Visual images for these baseline experiments conducted with heat release rate (HRR) of about 8 kW illustrate clean blue flames indicating premixed combustion for all three fuels. Radial profiles of the product gas temperature at the combustor exit overlap each other signifying that the combustion efficiency is independent of the fuel. At the combustor exit, the NOx emissions are within the measurement uncertainties, while CO emissions are slightly higher for straight VO as compared to diesel and biodiesel. Considering the large variations in physical and chemical properties of fuels considered, the small differences observed in CO and NOx emissions show promise for fuel-flexible, clean combustion systems. FB injector has proven to be very effective in atomizing fuels with very different physical properties, and it offers a

  17. The influence of cavitation on the flow characteristics of liquid nitrogen through spray nozzles: A CFD study

    Science.gov (United States)

    Xue, Rong; Ruan, Yixiao; Liu, Xiufang; Cao, Feng; Hou, Yu

    2017-09-01

    Spray cooling with cryogen could achieve lower temperature level than refrigerant spray. The internal flow conditions within spray nozzles have crucial impacts on the mass flow rate, particle size, spray angle and spray penetration, thereby influencing the cooling performance. In this paper, CFD simulations based on mixture model are performed to study the cavitating flow of liquid nitrogen in spray nozzles. The cavitation model is verified using the experimental results of liquid nitrogen flow over hydrofoil. The numerical models of spray nozzle are validated against the experimental data of the mass flow rate of liquid nitrogen flow through different types of nozzles including the pressure swirl nozzle and the simple convergent nozzle. The numerical studies are performed under a wide range of pressure difference and inflow temperature, and the vapor volume fraction distribution, outlet vapor quality, mass flow rate and discharge coefficient are obtained. The results show that the outlet diameter, the pressure difference, and the inflow temperature significantly influence the mass flow rate of spray nozzles. The increase of the inflow temperature leads to higher saturation pressure, higher cavitation intensity, and more vapor at nozzle outlet, which can significantly reduce mass flow rate. While the discharge coefficient is mainly determined by the inflow temperature and has little dependence on the pressure difference and outlet diameter. Based on the numerical results, correlations of discharge coefficient are proposed for pressure swirl nozzle and simple convergent nozzles, respectively, and the deviation is less than 20% for 93% of data.

  18. Characterization of metal-supported axial injection plasma sprayed solid oxide fuel cells with aqueous suspension plasma sprayed electrolyte layers

    Science.gov (United States)

    Waldbillig, D.; Kesler, O.

    A method for manufacturing metal-supported SOFCs with atmospheric plasma spraying (APS) is presented, making use of aqueous suspension feedstock for the electrolyte layer and dry powder feedstock for the anode and cathode layers. The cathode layer was deposited first directly onto a metal support, in order to minimize contact resistance, and to allow the introduction of added porosity. The electrolyte layers produced by suspension plasma spraying (SPS) were characterized in terms of thickness, permeability, and microstructure, and the impact of substrate morphology on electrolyte properties was investigated. Fuel cells produced by APS were electrochemically tested at temperatures ranging from 650 to 750 °C. The substrate morphology had little effect on open circuit voltage, but substrates with finer porosity resulted in lower kinetic losses in the fuel cell polarization.

  19. Characterization of metal-supported axial injection plasma sprayed solid oxide fuel cells with aqueous suspension plasma sprayed electrolyte layers

    Energy Technology Data Exchange (ETDEWEB)

    Waldbillig, D. [University of British Columbia, Department of Materials Engineering, 309-6350 Stores Road, Vancouver, BC (Canada); Kesler, O. [University of Toronto, Department of Mechanical and Industrial Engineering, 5 King' s College Road, Toronto, Ontario (Canada)

    2009-06-15

    A method for manufacturing metal-supported SOFCs with atmospheric plasma spraying (APS) is presented, making use of aqueous suspension feedstock for the electrolyte layer and dry powder feedstock for the anode and cathode layers. The cathode layer was deposited first directly onto a metal support, in order to minimize contact resistance, and to allow the introduction of added porosity. The electrolyte layers produced by suspension plasma spraying (SPS) were characterized in terms of thickness, permeability, and microstructure, and the impact of substrate morphology on electrolyte properties was investigated. Fuel cells produced by APS were electrochemically tested at temperatures ranging from 650 to 750 C. The substrate morphology had little effect on open circuit voltage, but substrates with finer porosity resulted in lower kinetic losses in the fuel cell polarization. (author)

  20. Measurements of non-reacting and reacting flow fields of a liquid swirl flame burner

    Science.gov (United States)

    Chong, Cheng Tung; Hochgreb, Simone

    2015-03-01

    The understanding of the liquid fuel spray and flow field characteristics inside a combustor is crucial for designing a fuel efficient and low emission device. Characterisation of the flow field of a model gas turbine liquid swirl burner is performed by using a 2-D particle imaging velocimetry(PIV) system. The flow field pattern of an axial flow burner with a fixed swirl intensity is compared under confined and unconfined conditions, i.e., with and without the combustor wall. The effect of temperature on the main swirling air flow is investigated under open and non-reacting conditions. The result shows that axial and radial velocities increase as a result of decreased flow density and increased flow volume. The flow field of the main swirling flow with liquid fuel spray injection is compared to non-spray swirling flow. Introduction of liquid fuel spray changes the swirl air flow field at the burner outlet, where the radial velocity components increase for both open and confined environment. Under reacting condition, the enclosure generates a corner recirculation zone that intensifies the strength of radial velocity. The reverse flow and corner recirculation zone assists in stabilizing the flame by preheating the reactants. The flow field data can be used as validation target for swirl combustion modelling.

  1. A Numerical Study of Spray Characteristics in Medium Speed Engine Fueled by Different HFO/n-Butanol Blends

    Directory of Open Access Journals (Sweden)

    Hashem Nowruzi

    2014-01-01

    Full Text Available In the present study, nonreacting and nonevaporating spray characteristics of heavy fuel oil (HFO/n-butanol blends are numerically investigated under two different high pressure injections in medium speed engines. An Eulerian-Lagrangian multiphase scheme is used to simulate blend of C14H30 as HFO and 0%, 10%, 15%, and 20% by volume of n-butanol. OpenFOAM CFD toolbox is modified and implemented to study the effect of different blends of HFO/n-butanol on the spray characteristics at 600 and 1000 bar. To validate the presented simulations, current numerical results are compared against existing experimental data and good compliance is achieved. Based on the numerical findings, addition of n-butanol to HFO increases the particles volume in parcels at 600 bar. It was also found that blend fuels increase the number of spray particles and the average velocity of spray compared to pure HFO. Moreover, under injection pressure of 1000 bar, HFO/n-butanol blends compared to pure HFO fuel decrease particles volume in parcels of spray. Another influence of HFO/n-butanol blends is the decrease in average of particles diameter in parcels. Meanwhile, the effect of HFO/n-butanol on spray length is proved to be negligible. Finally, it can be concluded that higher injection pressure improves the spray efficiency.

  2. Comparision on dynamic behavior of diesel spray and rapeseed oil spray in diesel engine

    Science.gov (United States)

    Sapit, Azwan; Azahari Razali, Mohd; Faisal Hushim, Mohd; Jaat, Norrizam; Nizam Mohammad, Akmal; Khalid, Amir

    2017-04-01

    Fuel-air mixing is important process in diesel combustion. It significantly affects the combustion and emission of diesel engine. Biomass fuel has high viscosity and high distillation temperature and may negatively affect the fuel-air mixing process. Thus, study on the spray development and atomization of this type of fuel is important. This study investigates the atomization characteristics and droplet dynamic behaviors of diesel engine spray fuelled by rapeseed oil (RO) and comparison to diesel fuel (GO). Optical observation of RO spray was carried out using shadowgraph photography technique. Single nano-spark photography technique was used to study the characteristics of the spray while dual nano-spark shadowgraph technique was used to study the spray droplet behavior. Using in-house image processing algorithm, the images were processed and the boundary condition of each spray was also studied. The results show that RO has very poor atomization due to the high viscosity nature of the fuel when compared to GO. This is in agreement with the results from spray droplet dynamic behavior studies that shows due to the high viscosity, the RO spray droplets are large in size and travel downward, with very little influence of entrainment effect due to its large kinematic energy.

  3. Nasal deposition and clearance in man: comparison of a bidirectional powder device and a traditional liquid spray pump.

    Science.gov (United States)

    Djupesland, Per Gisle; Skretting, Arne

    2012-10-01

    Delivery of powder formulations to the nose is an attractive alternative for many drugs and vaccines. This study compared the regional nasal deposition and clearance patterns of lactose powder delivered by the OptiNose powder device (Opt-Powder; OptiNose US Inc., Yardley, PA, USA) to that of liquid aerosol administered via a traditional hand-actuated liquid spray pump (Rexam SP270, Rexam Pharma, France). The study was an open-label, crossover design in seven healthy subjects (five females, two males). The regional nasal deposition and clearance patterns of the Opt-Powder device were compared to a traditional liquid spray pump by dynamic gamma camera imaging after administration of either (99m)Tc-labeled lactose powder or liquid (99m)Tc- diethelyne triamine pentaacetic acid-aerosol. The gamma camera images were scaled and aligned with sagittal magnetic resonance images to identify nasal regions. Possible deposition of radiolabeled material in the lungs following both methods of delivery was also evaluated. Both powder and spray were distributed to all of the nasal regions. The Opt-Powder device, however, achieved significantly larger initial deposition in the upper and middle posterior regions of the nose than spray (upper posterior region; Opt-Powder 18.3% ± 11.5 vs. Spray 2.4% ± 1.8, pSpray 15.7% ± 13.8, pdeposition to the lower anterior and posterior regions for spray was three times higher compared to Opt-Powder (Opt-Powder 17.4% ± 24.5 vs. Spray 59.4% ± 18.2, pdeposition was observed. The initial deposition following powder delivery was significantly larger in the ciliated mucosa of the upper and posterior nasal regions, whereas less was deposited in the lower regions. Overall nasal clearance of powder was slower initially, but due to retention in anterior nonciliated regions the overall nasal clearance after spray was slower.

  4. Developments in Spray Modeling in Diesel and Direct-Injection Gasoline Engines Progrès de la modélisation des sprays dans les moteurs Diesel et à essence

    Directory of Open Access Journals (Sweden)

    Kong S. C.

    2006-12-01

    Full Text Available In direct-injection engines, the fuel spray characteristics influence the combustion efficiency and exhaust emissions. The performance of available spray models for predicting liquid and vapor fuel distributions, and their influence on combustion is reviewed for both diesel and gasoline direct injection engines. A phenomenological nozzle flow model is described for simulating the effects of diesel injector nozzle internal geometry on the fuel injection and spray processes. The flow model provides initial conditions for the liquid jet breakup model that considers wave instabilities due to Kelvin-Helmholtz (KH and Rayleigh-Taylor (RT mechanisms. A linearized instability analysis has also been extended to consider the breakup of liquid sheets for modeling pressure-swirl gasoline injectors. Diesel engine predictions have been compared with extensive data from in-cylinder laser diagnostics carried out in optically accessible heavy-duty, DI Diesel engines over a wide range of operating conditions. The results show that the nozzle flow model used in combination with the KH and RT models gives realistic spray predictions. In particular, the limited liquid fuel penetration length observed experimentally and the flame shape details are captured accurately. The liquid sheet breakup model has also been compared favorably with experimental spray penetration and drop size data for gasoline hollow-cone sprays. This model is currently being applied to study stratified charge combustion in GDI engines. Dans les moteurs à injection directe, les caractéristiques du spray de carburant influent directement sur le rendement et les émissions. Les performances des modèles de spray existants et leur influence sur la combustion pour les moteurs Diesel et essence à injection directe sont analysées. Un modèle phénoménologique d'écoulement dans les injecteurs indiquant les effets de la géométrie sur les processus d'injection est présenté. Ce modèle donne les

  5. Spray structure as generated under homogeneous flash boiling nucleation regime

    International Nuclear Information System (INIS)

    Levy, M.; Levy, Y.; Sher, E.

    2014-01-01

    We show the effect of the initial pressure and temperature on the spatial distribution of droplets size and their velocity profile inside a spray cloud that is generated by a flash boiling mechanism under homogeneous nucleation regime. We used TSI's Phase Doppler Particle Analyzer (PDPA) to characterize the spray. We conclude that the homogeneous nucleation process is strongly affected by the initial liquid temperature while the initial pressure has only a minor effect. The spray shape is not affected by temperature or pressure under homogeneous nucleation regime. We noted that the only visible effect is in the spray opacity. Finally, homogeneous nucleation may be easily achieved by using a simple atomizer construction, and thus is potentially suitable for fuel injection systems in combustors and engines. - Highlights: • We study the characteristics of a spray that is generated by a flash boiling process. • In this study, the flash boiling process occurs under homogeneous nucleation regime. • We used Phase Doppler Particle Analyzer (PDPA) to characterize the spray. • The SMD has been found to be strongly affected by the initial liquid temperature. • Homogeneous nucleation may be easily achieved by using a simple atomizer unit

  6. Ceramic plasma-sprayed coating of melting crucibles for casting metal fuel slugs

    International Nuclear Information System (INIS)

    Kim, Ki Hwan; Lee, Chong Tak; Lee, Chan Bock; Fielding, R.S.; Kennedy, J.R.

    2013-01-01

    Thermal cycling and melt reaction studies of ceramic coatings plasma-sprayed on Nb substrates were carried out to evaluate the performance of barrier coatings for metallic fuel casting applications. Thermal cycling tests of the ceramic plasma-sprayed coatings to 1450 °C showed that HfN, TiC, ZrC, and Y 2 O 3 coating had good cycling characteristics with few interconnected cracks even after 20 cycles. Interaction studies by 1550 °C melt dipping tests of the plasma-sprayed coatings also indicated that HfN and Y 2 O 3 do not form significant reaction layer between U–20 wt.% Zr melt and the coating layer. Plasma-sprayed Y 2 O 3 coating exhibited the most promising characteristics among HfN, TiC, ZrC, and Y 2 O 3 coating

  7. Experimental studies on spray and gas entrainment characteristics of biodiesel fuel: Implications of gas entrained and fuel oxygen content on soot formation

    International Nuclear Information System (INIS)

    Kuti, Olawole Abiola; Nishida, Keiya; Zhu, Jingyu

    2013-01-01

    Experiments were performed inside the constant volume vessel to simulate the real diesel engine conditions. The LIF–PIV (Laser Induced Florescence – Particulate Image Velocimetry) technique was used to characterize the spray and gas entrainment characteristics of the fuels while the OH-chemiluminescence and two color pyrometry were applied to obtain information about the combustion processes. Biodiesel from palm oil (BDF (Biodiesel Fuel)) and the JIS #2 diesel fuel were utilized. It was observed that the SMD (Sauter mean diameter) obtained through an empirical equation decreased by increasing the injection pressure from 100 to 300 MPa and reducing the nozzle diameter from 0.16 to 0.08 mm. BDF has higher SMD values compared to diesel thus signifying inferior atomization. By increasing the injection pressure up to 300 MPa and reducing the nozzle diameter to 0.08 mm, the normal velocity and total mass flow rate of the entrained gas by the fuels increased. Due to higher viscosity and density properties, BDF possessed inferior atomization characteristics which made the normal velocity and total mass flow rate of the entrained gas lower compared to diesel. Due to inferior atomization which led to less gas being entrained upstream of the lift-off flame, the fuel oxygen content in BDF played a significant role in soot formation processes. - Highlights: • Spray and gas entrainment characteristics of biodiesel (BDF (Biodiesel Fuel)) and fuel were investigated. • Effect of injector parameters on BDF spray and gas entrainment characteristics was identified. • Higher viscosity and density of BDF yielded inferior spray atomization processes. • Gas entrainment velocity and mass flow rate of gas entrained by BDF lower. • Gas entrained had less effect on BDF's soot formation

  8. Thermal Radiation Effects on Thermal Explosion in Polydisperse Fuel Spray-Probabilistic Model

    Directory of Open Access Journals (Sweden)

    Ophir Navea

    2011-06-01

    Full Text Available We investigate the effect of thermal radiation on the dynamics of a thermal explosion of polydisperse fuel spray with a complete description of the chemistry via a single-step two-reactant model of general order. The polydisperse spray is modeled using a Probability Density Function (PDF. The thermal radiation energy exchange between the evaporation surface of the fuel droplets and the burning gas is described using the Marshak boundary conditions. An explicit expression of the critical condition for thermal explosion limit is derived analytically and represents a generalization of the critical parameter of the classical Semenov theory. Because we investigated the model in the range where the temperature is very high, the effect of the thermal radiation is significant.

  9. Production of Babbitt Coatings by High Velocity Oxygen Fuel (HVOF) Spraying

    Science.gov (United States)

    Nascimento, A. R. C.; Ettouil, F. B.; Moreau, C.; Savoie, S.; Schulz, R.

    2017-10-01

    This work presents HVOF as an alternative means to produce dense Babbitt coatings by thermal spray. A radial injection setup and low fuel flow rates were used to minimize heat transfer to the low melting point alloy. In-flight particle diagnostic systems were used to correlate spray parameters with the changes in particle velocity and thermal radiation intensity. The use of particles with larger diameters resulted in higher deposition efficiencies. It was shown that HVOF Babbitt coatings combine a dense structure and a fine distribution of intermetallic phases when compared to more traditional babbitting techniques.

  10. The spray characteristic of gas-liquid coaxial swirl injector by experiment

    Directory of Open Access Journals (Sweden)

    Chen Chen

    2017-01-01

    Full Text Available Using the laser phase Doppler particle analyzer (PDPA, the spray characteristics of gas-liquid coaxial swirl injector were studied. The Sauter mean diameter (SMD, axial velocity and size data rate were measured under different gas injecting pressure drop and liquid injecting pressure drop. Comparing to a single liquid injection, SMD with gas presence is obviously improved. So the gas presence has a significant effect on the atomization of the swirl injector. What’s more, the atomization effect of gas-liquid is enhanced with the increasing of the gas pressure drop. Under the constant gas pressure drop, the injector has an optimal liquid pressure drop under which the atomization performance is best.

  11. Formulation and analyses of vaporization and diffusion-controlled combustion of fuel sprays

    OpenAIRE

    Arrieta Sanagustín, Jorge

    2012-01-01

    This dissertation focuses on the modelling of vaporization and combustion of sprays. A general two-continua formulation is given for the numerical computation of spray flows, including the treatment of the droplets as homogenized sources. Group combustion is considered, with the reaction between the fuel coming from the vaporizing droplets and the oxygen of the air modeled in the Burke-Schumann limit of infinitely fast chemical reaction, with nonunity Lewis numbers allowed for the different r...

  12. KIVA3, Transient Multicomponent 2-D and 3-D Reactive Flows with Fuel Sprays

    International Nuclear Information System (INIS)

    Amsden, A.A.

    2001-01-01

    1 - Description of program or function: KIVA3VRELEASE2 is a computer program for the numerical calculation of transient, two and three-dimensional, chemically reactive flows with sprays. It is a newer version of the earlier KIVA3 (1993) that has now been extended to model vertical of canted valves in the cylinder head of a gasoline or diesel engine. KIVA3, in turn, was based on the earlier KIVA2 (1989) and uses the same numerical solution procedure and solves the same sort of equations. KIVA3VRELEASE2 uses a block-structured mesh with connectivity defined through indirect addressing. The departure from a single rectangular structure in logical space allows complex geometries to be modeled with significantly greater efficiency because large regions of deactivated cells are no longer necessary. Cell-face boundary conditions permit greater flexibility and simplification in the application of boundary conditions. KIVA3VRELEASE2 contains a number of significant changes. New features enhance the robustness, efficiency, and usefulness of the overall program for engine modeling. Automatic restart of the cycle with a reduced time-step in case of iteration limit or temperature overflow will reduce code crashes. A new option provides automatic deactivation of a port region when it is closed from the cylinder and reactivation when it communicates with the cylinder. Corrections in the code improve accuracy; extensions to the particle-based liquid wall film model makes the model more complete and a spli injection option has been added. A new subroutine monitors the liquid and gaseous fuel phases and energy balance data and emissions are monitored and printed. New features have been added to the grid generator K3PREP and the graphics post processor, K3POST. 2 - Method of solution: KIVA3VRELEASE2 solves the unsteady equations of motion of a turbulent, chemically reactive mixture of ideal gases, coupled to the equations for a single-component vaporizing fuel spray. The gas

  13. Retrofitting a spent fuel pool spray system for alternative cooling as a strategy for beyond design basis events

    Energy Technology Data Exchange (ETDEWEB)

    Hartmann, Christoph; Vujic, Zoran [Westinghouse Electric Germany GmbH, Mannheim (Germany)

    2017-06-15

    Due to requirements for nuclear power plants to withstand beyond design basis accidents, including events such as happened in 2011 in the Fukushima Daiichi Nuclear Power Plant in Japan, alternative cooling of spent fuel is needed. Alternative spent fuel cooling can be provided by a retrofitted spent fuel pool spray system based on the AP1000 plant design. As part of Krsko Nuclear Power Plant's Safety Upgrade Program, Krsko Nuclear Power Plant decided on, and Westinghouse successfully designed a retrofit of the AP1000 {sup registered} plant spent fuel pool spray system to provide alternative spent fuel cooling.

  14. Optimization and Characterization of High Velocity Oxy-fuel Sprayed Coatings: Techniques, Materials, and Applications

    Directory of Open Access Journals (Sweden)

    Maria Oksa

    2011-09-01

    Full Text Available In this work High Velocity Oxy-fuel (HVOF thermal spray techniques, spraying process optimization, and characterization of coatings are reviewed. Different variants of the technology are described and the main differences in spray conditions in terms of particle kinetics and thermal energy are rationalized. Methods and tools for controlling the spray process are presented as well as their use in optimizing the coating process. It will be shown how the differences from the starting powder to the final coating formation affect the coating microstructure and performance. Typical properties of HVOF sprayed coatings and coating performance is described. Also development of testing methods used for the evaluation of coating properties and current status of standardization is presented. Short discussion of typical applications is done.

  15. Multi-component vapor-liquid equilibrium model for LES of high-pressure fuel injection and application to ECN Spray A

    NARCIS (Netherlands)

    Matheis, Jan; Hickel, S.

    2018-01-01

    We present and evaluate a two-phase model for Eulerian large-eddy simulations (LES) of liquid-fuel injection and mixing at high pressure. The model is based on cubic equations of state and vapor-liquid equilibrium calculations and can represent the coexistence of supercritical states and

  16. Ecodesign of Liquid Fuel Tanks

    Science.gov (United States)

    Gicevska, Jana; Bazbauers, Gatis; Repele, Mara

    2011-01-01

    The subject of the study is a 10 litre liquid fuel tank made of metal and used for fuel storage and transportation. The study dealt with separate life cycle stages of this product, compared environmental impacts of similar fuel tanks made of metal and plastic, as well as analysed the product's end-of-life cycle stage, studying the waste treatment and disposal scenarios. The aim of this study was to find opportunities for improvement and to develop proposals for the ecodesign of 10 litre liquid fuel tank.

  17. Impinging jet spray formation using non-Newtonian liquids

    Science.gov (United States)

    Rodrigues, Neil S.

    Over the past two decades there has been a heightened interest in implementing gelled propellants for rocket propulsion, especially for hypergolic bi-propellants such as monomethylhydrazine (MMH) and nitrogen tetroxide oxidizer (NTO). Due to the very high level of toxicity of hypergolic liquid rocket propellants, increasing safety is an important area of need for continued space exploration and defense operations. Gelled propellants provide an attractive solution to meeting the requirements for safety, while also potentially improving performance. A gelling agent can be added to liquid propellants exhibiting Newtonian behavior to transform the liquid into a non-Newtonian fluid with some solid-like behavior, i.e. a gel. Non-Newtonian jet impingement is very different from its Newtonian counterpart in terms of fluid flow, atomization, and combustion. This is due to the added agents changing physical properties such as the bulk rheology (viscosity) and interfacial rheology (surface tension). Spray characterization of jet impingement with Newtonian liquids has been studied extensively in existing literature. However, there is a scarcity in literature of studies that consider the spray characterization of jet impingement with gelled propellants. This is a rather critical void since a major tradeoff of utilizing gelled propellants is the difficulty with atomization due to the increased effective viscosity. However, this difficulty can be overcome by using gels that exhibit shear-thinning behavior---viscosity decreases with increasing strain rate. Shear-thinning fluids are ideal because they have the distinct advantage of only flowing easily upon pressure. Thereby, greatly reducing the amount of propellant that could be accidentally leaked during both critical functions such as liftoff or engagement in the battlefield and regular tasks like refilling propellant tanks. This experimental work seeks to help resolve the scarcity in existing literature by providing drop size

  18. Image processing of vaporizing GDI sprays: a new curvature-based approach

    Science.gov (United States)

    Lazzaro, Maurizio; Ianniello, Roberto

    2018-01-01

    This article introduces an innovative method for the segmentation of Mie-scattering and schlieren images of GDI sprays. The contours of the liquid phase are obtained by segmenting the scattering images of the spray by means of optimal filtering of the image, relying on variational methods, and an original thresholding procedure based on an iterative application of Otsu’s method. The segmentation of schlieren images, to get the contours of the spray vapour phase, is obtained by exploiting the surface curvature of the image to strongly enhance the intensity texture due to the vapour density gradients. This approach allows one to unambiguously discern the whole vapour phase of the spray from the background. Additional information about the spray liquid phase can be obtained by thresholding filtered schlieren images. The potential of this method has been substantiated in the segmentation of schlieren and scattering images of a GDI spray of isooctane. The fuel, heated to 363 K, was injected into nitrogen at a density of 1.12 and 3.5 kg m-3 with temperatures of 333 K and 573 K.

  19. Simultaneous two-phase flow measurement of spray mixing process by means of high-speed two-color PIV

    International Nuclear Information System (INIS)

    Zhang, Ming; Xu, Min; Hung, David L S

    2014-01-01

    In this article, a novel high-speed two-color PIV optical diagnostic technique has been developed and applied to simultaneously measure the velocity flow-fields of a multi-hole spark-ignition direct injection (SIDI) fuel injector spray and its ambient gas in a high-pressure constant volume chamber. To allow for the phase discrimination between the fuel droplets and ambient gas, a special tracer-filter system was designed. Fluorescent seeding particles with Sauter mean diameter (SMD) of 4.8 µm were used to trace the gas inside the chamber. With a single high-speed Nd:YLF laser sheet (527 nm) as the incident light source, the Mie-scattering signal marked the phase of the fuel spray, while the fluorescent signal generated from the seeding particles tracked the phase of ambient gas. A high-speed camera, with an image-doubler (mounted in front of the camera lens) that divided the camera pixels into two parts focusing on the same field of view, was used to collect the Mie-scattering signal and LIF (laser induced fluorescence) signal simultaneously with two carefully selected optical filters. To accommodate the large dynamic range of velocities in the two phases (1–2 orders of magnitude difference), two separation times (dt) were introduced. This technique was successfully applied to the liquid spray and ambient gas two-phase flow measurement. The measurement accuracy was compared with those from LDV (laser Doppler velocimetry) measurement and good agreement was obtained. Ambient gas motion surrounding the fuel spray was investigated and characterized into three zones. The momentum transfer process between the fuel spray and ambient gas in each zone was analyzed. The two-phase flow interaction under various superheated conditions was investigated. A strengthened momentum transfer from the liquid spray to the ambient was observed with increased superheat degree. (paper)

  20. Verification on spray simulation of a pintle injector for liquid rocket engine

    Science.gov (United States)

    Son, Min; Yu, Kijeong; Radhakrishnan, Kanmaniraja; Shin, Bongchul; Koo, Jaye

    2016-02-01

    The pintle injector used for a liquid rocket engine is a newly re-attracted injection system famous for its wide throttle ability with high efficiency. The pintle injector has many variations with complex inner structures due to its moving parts. In order to study the rotating flow near the injector tip, which was observed from the cold flow experiment using water and air, a numerical simulation was adopted and a verification of the numerical model was later conducted. For the verification process, three types of experimental data including velocity distributions of gas flows, spray angles and liquid distribution were all compared using simulated results. The numerical simulation was performed using a commercial simulation program with the Eulerian multiphase model and axisymmetric two dimensional grids. The maximum and minimum velocities of gas were within the acceptable range of agreement, however, the spray angles experienced up to 25% error when the momentum ratios were increased. The spray density distributions were quantitatively measured and had good agreement. As a result of this study, it was concluded that the simulation method was properly constructed to study specific flow characteristics of the pintle injector despite having the limitations of two dimensional and coarse grids.

  1. Transported PDF Modeling of Ethanol Spray in Hot-Diluted Coflow Flame

    OpenAIRE

    Ma, L.; Naud, B.; Roekaerts, D.J.E.M.

    2015-01-01

    This paper presents a numerical modeling study of one ethanol spray flame from the Delft Spray-in-Hot-Coflow (DSHC) database, which has been used to study Moderate or Intense Low-oxygen Dilution (MILD) combustion of liquid fuels (Correia Rodrigues et al. Combust. Flame 162(3), 759–773, 2015). A “Lagrangian-Lagrangian” approach is adopted where both the joint velocity-scalar Probability Density Function (PDF) for the continuous phase and the joint PDF of droplet properties are modeled and solv...

  2. Liquid fuel cells

    Directory of Open Access Journals (Sweden)

    Grigorii L. Soloveichik

    2014-08-01

    Full Text Available The advantages of liquid fuel cells (LFCs over conventional hydrogen–oxygen fuel cells include a higher theoretical energy density and efficiency, a more convenient handling of the streams, and enhanced safety. This review focuses on the use of different types of organic fuels as an anode material for LFCs. An overview of the current state of the art and recent trends in the development of LFC and the challenges of their practical implementation are presented.

  3. Development of Cold Spray Coatings for Accident-Tolerant Fuel Cladding in Light Water Reactors

    Science.gov (United States)

    Maier, Benjamin; Yeom, Hwasung; Johnson, Greg; Dabney, Tyler; Walters, Jorie; Romero, Javier; Shah, Hemant; Xu, Peng; Sridharan, Kumar

    2018-02-01

    The cold spray coating process has been developed at the University of Wisconsin-Madison for the deposition of oxidation-resistant coatings on zirconium alloy light water reactor fuel cladding with the goal of improving accident tolerance during loss of coolant scenarios. Coatings of metallic (Cr), alloy (FeCrAl), and ceramic (Ti2AlC) materials were successfully deposited on zirconium alloy flats and cladding tube sections by optimizing the powder size, gas preheat temperature, pressure and composition, and other process parameters. The coatings were dense and exhibited excellent adhesion to the substrate. Evaluation of the samples after high-temperature oxidation tests at temperatures up to 1300°C showed that the cold spray coatings significantly mitigate oxidation kinetics because of the formation of thin passive oxide layers on the surface. The results of the study indicate that the cold spray coating process is a viable near-term option for developing accident-tolerant zirconium alloy fuel cladding.

  4. Injector spray characterization of methanol in reciprocating engines

    Science.gov (United States)

    Dodge, L.; Naegeli, D.

    1994-06-01

    This report covers a study that addressed cold-starting problems in alcohol-fueled, spark-ignition engines by using fine-spray port-fuel injectors to inject fuel directly into the cylinder. This task included development and characterization of some very fine-spray, port-fuel injectors for a methanol-fueled spark-ignition engine. After determining the spray characteristics, a computational study was performed to estimate the evaporation rate of the methanol fuel spray under cold-starting and steady-state conditions.

  5. Numerical Simulations of High Reactivity Gasoline Fuel Sprays under Vaporizing and Reactive Conditions

    KAUST Repository

    Mohan, Balaji; Jaasim, Mohammed; Ahmed, Ahfaz; Hernandez Perez, Francisco; Sim, Jaeheon; Roberts, William L.; Sarathy, Mani; Im, Hong G.

    2018-01-01

    Gasoline compression ignition (GCI) engines are becoming more popular alternative for conventional spark engines to harvest the advantage of high volatility. Recent experimental study demonstrated that high reactivity gasoline fuel can be operated in a conventional mixing controlled combustion mode producing lower soot emissions than that of diesel fuel under similar efficiency and NOx level [1]. Therefore, there is much interest in using gasoline-like fuels in compression ignition engines. In order to improve the fidelity of simulation-based GCI combustion system development, it is mandatory to enhance the prediction of spray combustion of gasoline-like fuels. The purpose of this study is to model the spray characteristics of high reactivity gasoline fuels and validate the models with experimental results obtained through an optically accessible constant volume vessel under vaporizing [2] and reactive conditions [3]. For reacting cases, a comparison of PRF and KAUST multi-component surrogate (KMCS) mechanism was done to obtain good agreement with the experimental ignition delay. From this study, some recommendations were proposed for GCI combustion modelling framework using gasoline like fuels.

  6. Numerical Simulations of High Reactivity Gasoline Fuel Sprays under Vaporizing and Reactive Conditions

    KAUST Repository

    Mohan, Balaji

    2018-04-03

    Gasoline compression ignition (GCI) engines are becoming more popular alternative for conventional spark engines to harvest the advantage of high volatility. Recent experimental study demonstrated that high reactivity gasoline fuel can be operated in a conventional mixing controlled combustion mode producing lower soot emissions than that of diesel fuel under similar efficiency and NOx level [1]. Therefore, there is much interest in using gasoline-like fuels in compression ignition engines. In order to improve the fidelity of simulation-based GCI combustion system development, it is mandatory to enhance the prediction of spray combustion of gasoline-like fuels. The purpose of this study is to model the spray characteristics of high reactivity gasoline fuels and validate the models with experimental results obtained through an optically accessible constant volume vessel under vaporizing [2] and reactive conditions [3]. For reacting cases, a comparison of PRF and KAUST multi-component surrogate (KMCS) mechanism was done to obtain good agreement with the experimental ignition delay. From this study, some recommendations were proposed for GCI combustion modelling framework using gasoline like fuels.

  7. Liquid fuel concept benefits

    International Nuclear Information System (INIS)

    Hron, M.

    1996-01-01

    There are principle drawbacks of any kind of solid nuclear fuel listed and analyzed in the first part of the paper. One of the primary results of the analyses performed shows that the solid fuel concept, which was to certain degree advantageous in the first periods of a nuclear reactor development and operation, has guided this branch of a utilization of atomic nucleus energy to a death end. On the background of this, the liquid fuel concept and its benefits are introduced and briefly described in the first part of the paper, too. As one of the first realistic attempts to utilize the advantages of liquid fuels, the reactor/blanket system with molten fluoride salts in the role of fuel and coolant simultaneously, as incorporated in the accelerator-driven transmutation technology (ADTT) being proposed and currently having been under development in the Los Alamos National Laboratory, will be studied both theoretically and experimentally. There is a preliminary design concept of an experimental assembly LA-O briefly introduced in the paper which is under preparation in the Czech Republic for such a project. Finally, there will be another very promising concept of a small low power ADTT system introduced which is characterized by a high level of safety and economical efficiency. In the conclusion, the overall survey of principal benefits which may be expected by introducing liquid nuclear fuel in nuclear power and research reactor systems is given and critically analyzed. 7 refs, 4 figs

  8. Study liquid length penetration results obtained with a direct acting piezo electric injector

    International Nuclear Information System (INIS)

    Payri, Raul; Gimeno, Jaime; Bardi, Michele; Plazas, Alejandro H.

    2013-01-01

    Highlights: ► A direct acting injector capable of controlling needle lift has been used to determine liquid phase penetration. ► The influence of injection pressure, chamber density and chamber temperature have been measured. ► When needle lift is reduced the stabilized liquid length is shortened. ► The relationship between needle lift and liquid length makes needle lift as a new way to control the injection event. - Abstract: A state of the art prototype common rail injector featuring direct control of the needle by means of a piezo stack (direct acting) has been tested. Liquid phase penetration of the sprays in diesel engine-like conditions has been studied via imaging technique in a novel continuous flow test chamber that allows an accurate control on a wide range of thermodynamic conditions (up to 1000 K and 15 MPa). This state of the art injector fitted with a 7-hole nozzle, allows a fully flexible control on the nozzle needle movement, enabling various fuel injection rate typologies. The temporal evolution of the seven sprays has been studied recording movies of the injection event in evaporative conditions via Mie scattering imaging technique and using a high speed camera. The results showed a strong influence of needle position on the stabilized liquid length while the effect of the injection pressure is negligible: the decrease of the needle lift causes a pressure drop in the needle seat and thus a reduction in the effective pressure upstream of the orifices (in the nozzle sac). According to known literature the stabilized liquid-length depends mainly on effective diameter, spray cone-angle and fuel/air properties and does not depend on fuel velocity at the orifice outlet. Therefore, due to small change in the spray cone-angle, higher injection pressures give slightly lower liquid length. However, partial needle lifts has an opposite effect: when needle is partially lifted a dramatic increase of the spray cone-angle and a consequent reduction of

  9. Electro-spray of high viscous liquids for producing mono-sized spherical alginate beads

    Institute of Scientific and Technical Information of China (English)

    Hamid Moghadam; Mohsen Samimi; Abdolreza Samimi; Mohamad Khorram

    2008-01-01

    Alginate beads, often used for controlled release of enzymes and drugs, are usually produced by spraying sodium alginate liquid into a gelling agent using mechanical vibration nozzle or air jet. In this work an alternative method of electro-spray was employed to form droplets with desired size from a highly viscous sodium alginate solution using constant DC voltage. The droplets were then cured in a calcium chloride solution. The main objective was to produce mono-sized beads from such a highly viscous and non-Newtonian liquid (1000-5000 mPa s). The effects of nozzle diameter, flow rate and concentration of liquid on the size of the beads were investigated. Among the parameters studied, voltage had a pronounced effect on the size of beads as compared to flow rate zzle diameter and concentration of alginate liquid. The size of beads was reduced to a minimum value with increasing the voltage in the range of 0-10 kV. At the early stages of voltage increase (I.e. Up to about 4 kV), the rate of size reduction was relatively low, while the dripping mode dominated. However, in the middle part of the range of applied voltage, where the rate of size reduction was high (I.e. About 4-7 kV), an unstable transition occurred between dripping and jetting. At the end part of the range (I.e. 7-10 kV) jet mode of spray was observed. Increasing the height of fall of the droplets was found to improve the sphericity of the beads, because of the increased time of flight for the droplets. This was especially identifiable at higher concentrations of the alginate liquid (I.e. 3 w/v%)

  10. Diesel spray characterization; Dieselmoottorin polttoainesuihkujen ominaisuudet

    Energy Technology Data Exchange (ETDEWEB)

    Pitkaenen, J.; Turunen, R.; Paloposki, T.; Rantanen, P.; Virolainen, T. [Helsinki Univ. of Technology, Otaniemi (Finland). Internal Combustion Engine Lab.

    1997-10-01

    Fuel injection of diesel engines will be studied using large-scale models of fuel injectors. The advantage of large-scale models is that the measurement of large-scale diesel sprays will be easier than the measurement of actual sprays. The objective is to study the break-up mechanism of diesel sprays and to measure drop size distributions in the inner part of the spray. The results will be used in the development of diesel engines and diesel fuels. (orig.)

  11. Ceramic Materials Selection of Fuel Crucibles based on Plasma Spray Coating for SFR

    Energy Technology Data Exchange (ETDEWEB)

    Song, Hoon; Kim, Jonghwan; Kim, Hyungtae; Ko, Youngmo; Woo, Yoonmyung; Oh, Seokjin; Kim, Kihwan; Lee, Chanbock [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2012-07-01

    The plasma-sprayed coating can provide the crucible with a denser, more friable coating layer, compared with the more friable coating layer formed by slurry-coating, which was used to prevent the interaction between melt and crucibles. Plasma-sprayed coatings are consolidated by mechanical interlocking of the molten particles impacting on the substrate and are dense by the heat applied by the plasma. The increased coating density is advantageous because it should not require frequent re coating and U-Zr melt penetration through the protective layer is more difficult in a dense coating than in a porous coating. In this study, we used Vacuum Plasma Spray method to investigate permanent coatings for re-usable crucibles for melting and casting of metallic fuel onto niobium substrates. Niobium was selected as a substrate because of its refractory nature and the coefficient of thermal expansion is similar to that of many of the candidate materials. After the HfC, ZrC, TiC, TaC, Y{sub 2}O{sub 3}, and 8% YSZ coatings were applied the resulting microstructure and chemical compositions was characterized to find the optimum process conditions for coating. Thermal plasma-sprayed coatings of refractory materials can be applied to develop a re-usable crucible coating for metallic fuel, such as the U-Zr alloy proposed for sodium cooled fast reactors.

  12. Spray calcination of nuclear wastes

    International Nuclear Information System (INIS)

    Bonner, W.F.; Blair, H.T.; Romero, L.S.

    1976-01-01

    The spray calciner is a relatively simple machine; operation is simple and is easily automated. Startup and shutdown can be performed in less than an hour. A wide variety of waste compositions and concentrations can be calcined under easily maintainable conditions. Spray calcination of all commercial fuel reprocessor high-level liquid wastes and mixed high and intermediate-level wastes have been demonstrated. Wastes have been calcined containing over 2M sodium. Thus waste generated during plant startup and shutdown can be blended with normal waste and calcined. Spray calcination of ILLW has also been demonstrated. A remotely replaceable atomizing nozzle has been developed for use in plant scale equipment. The 6 mm (0.25 inch) orifice and ceramic tip offer freedom from plugging and erosion thus nozzle replacement should be required only after several months operation. Calciner capacity of over 75 l/h (20 gal/h) has been demonstrated in pilot scale equipment. Sintered stainless steel filters are effective in deentraining over 99.9 percent of the solids that result from calcining the feedstock. Since such a small amount of radionuclides escape the calciner the volume of recycle required from the effluent treatment system is very small. The noncondensable off-gas volume is also low, less than 0.5 m 3 /min (15 scfm) for a liquid feedrate of 75 l/hr (20 gal/hr). Calcine holdup in the calciner is less than 1 kg, thus the liquid feedrate is directly relatable to calcine flowrate. The calcine produced is very fine and reactive. Successful remote operation and maintenance of a heated wall spray calciner has been demonstrated while processing actual high-level waste. During these operations radionuclide volatilization from the calciner was acceptably low. 8 figures

  13. Sensors Based Measurement Techniques of Fuel Injection and Ignition Characteristics of Diesel Sprays in DI Combustion System

    Directory of Open Access Journals (Sweden)

    S. Rehman

    2016-09-01

    Full Text Available Innovative sensor based measurement techniques like needle lift sensor, photo (optical sensor and piezoresistive pressure transmitter are introduced and used to measure the injection and combustion characteristics in direct injection combustion system. Present experimental study is carried out in the constant volume combustion chamber to study the ignition, combustion and injection characteristics of the solid cone diesel fuel sprays impinging on the hot surface. Hot surface ignition approach has been used to create variety of advanced combustion systems. In the present study, the hot surface temperatures were varied from 623 K to 723 K. The cylinder air pressures were 20, 30 and 40 bar and fuel injection pressures were 100, 200 and 300 bar. It is found that ignition delay of fuel sprays get reduced with the rise in injection pressure. The ignition characteristics of sprays much less affected at high fuel injection pressures and high surface temperatures. The fuel injection duration reduces with the increase in fuel injection pressures. The rate of heat release becomes high at high injection pressures and it decreases with the increase in injection duration. It is found that duration of burn/combustion decrease with the increase in injection pressure. The use of various sensors is quite effective, reliable and accurate in measuring the various fuel injection and combustion characteristics. The study simulates the effect of fuel injection system parameters on combustion performance in large heavy duty engines.

  14. Quantitative X-ray measurements of high-pressure fuel sprays from a production heavy duty diesel injector

    Energy Technology Data Exchange (ETDEWEB)

    Ramirez, A.I.; Som, S.; Aggarwal, Suresh K. [University of Illinois at Chicago, Department of Mechanical and Industrial Engineering, Chicago, IL (United States); Kastengren, A.L.; El-Hannouny, E.M.; Longman, D.E.; Powell, C.F. [Argonne National Laboratory, Energy Systems Division, Argonne, IL (United States)

    2009-07-15

    A quantitative and time-resolved X-ray radiography technique has been used for detailed measurements of high-pressure fuel sprays in the near-nozzle region of a diesel engine injector. The technique provides high spatial and temporal resolution, especially in the relatively dense core region. A single spray plume from a hydraulically actuated electronically controlled unit injector model 315B injector with a 6-hole nozzle was isolated and studied at engine-like densities for two different injection pressures. Optical spray imaging was also employed to evaluate the effectiveness of the shield used to isolate a single spray plume. The steady state fuel distributions for both injection pressures are similar and show a dense spray region along the axis of the spray, with the on-axis spray density decreasing as the spray progresses downstream. The higher injection pressure case exhibits a larger cone angle and spray broadening at the exit of the nozzle. For some time periods, the near-nozzle penetration speed is lower for the high injection pressure case than the low injection pressure case, which is unexpected, but can be attributed to the needle and flow dynamics inside the injector causing slower pressure build-up for the former case. Rate of injection testing was performed to further understand near-nozzle behavior. Mass distribution data were obtained and used to find mass-averaged velocity of the spray. Comparisons of the radiography data with that from a common rail single-hole light duty injectors under similar injection conditions show several significant differences. The current data show a larger cone angle and lower penetration speed than that from the light-duty injector. Moreover, these data display a Gaussian mass distribution across the spray near the injector, whereas in previous light-duty injector measurements, the mass distribution had steeper sides and a flatter peak. Measurements are also used to examine the spray models in the STAR-CD software

  15. Quantitative X-ray measurements of high-pressure fuel sprays from a production heavy duty diesel injector

    Science.gov (United States)

    Ramírez, A. I.; Som, S.; Aggarwal, Suresh K.; Kastengren, A. L.; El-Hannouny, E. M.; Longman, D. E.; Powell, C. F.

    2009-07-01

    A quantitative and time-resolved X-ray radiography technique has been used for detailed measurements of high-pressure fuel sprays in the near-nozzle region of a diesel engine injector. The technique provides high spatial and temporal resolution, especially in the relatively dense core region. A single spray plume from a hydraulically actuated electronically controlled unit injector model 315B injector with a 6-hole nozzle was isolated and studied at engine-like densities for two different injection pressures. Optical spray imaging was also employed to evaluate the effectiveness of the shield used to isolate a single spray plume. The steady state fuel distributions for both injection pressures are similar and show a dense spray region along the axis of the spray, with the on-axis spray density decreasing as the spray progresses downstream. The higher injection pressure case exhibits a larger cone angle and spray broadening at the exit of the nozzle. For some time periods, the near-nozzle penetration speed is lower for the high injection pressure case than the low injection pressure case, which is unexpected, but can be attributed to the needle and flow dynamics inside the injector causing slower pressure build-up for the former case. Rate of injection testing was performed to further understand near-nozzle behavior. Mass distribution data were obtained and used to find mass-averaged velocity of the spray. Comparisons of the radiography data with that from a common rail single-hole light duty injectors under similar injection conditions show several significant differences. The current data show a larger cone angle and lower penetration speed than that from the light-duty injector. Moreover, these data display a Gaussian mass distribution across the spray near the injector, whereas in previous light-duty injector measurements, the mass distribution had steeper sides and a flatter peak. Measurements are also used to examine the spray models in the STAR-CD software.

  16. Synchronized droplet size measurements for Coal-Water-Slurry (CWS) diesel sprays of an electronically-controlled fuel injection system

    Science.gov (United States)

    Kihm, K. D.; Terracina, D. P.; Payne, S. E.; Caton, J. A.

    Experiments were completed to study intermittent coal-water slurry (CWS) fuel sprays injected from an electronically-controlled accumulator injector system. A laser diffraction particle analyzing (LDPA) technique was used to measure the spray diameters (Sauter mean diameter, SMD) assuming the Rosin-Rammler two parameter model. In order to ensure an accurate synchronization of the measurement with the intermittent sprays, a new synchronization technique was developed using the light extinction signal as a triggering source for the data taking initiation. This technique allowed measurement of SMD's near the spray tip where the light extinction was low and the data were free from the multiscattering bias. Coal-water slurry fuel with 50% coal loading in mass containing 5 (mu)m mass median diameter coal particulates was considered. Injection pressures ranging from 28 to 110 MPa, two different nozzle orifice diameters, 0.2 ad 0.4 mm, and four axial measurement locations from 60 to 120 mm from the nozzle orifice were studied. Measurements were made for pressurized (2.0 MPa in gauge) and for ambient chamber conditions. The spray SMD showed an increase with the distance of the axial measurement location and with the ambient gas density, and showed a decrease with increasing injection pressure. A correlation of the Sauter mean diameter with the injection conditions was determined. The results were also compared with previous SMD correlations that were available only for diesel fuel sprays.

  17. Fuel spray and combustion characteristics of butanol blends in a constant volume combustion chamber

    International Nuclear Information System (INIS)

    Liu, Yu; Li, Jun; Jin, Chao

    2015-01-01

    Highlights: • A sudden drop is observed in spray penetration for B10S10D80 fuel at 800 and 900 K. • With increasing of temperature, auto-ignition timings of fuels become unperceivable. • Low n-butanol addition has little effect on autoignition timings from 800 to 1200 K. • n-Butanol additive can reduce soot emissions at the near-wall regions. • Larger soot reduction is seen at higher ambient temperatures for n-butanol addition. - Abstract: The processes of spray penetrations, flame propagation and soot formation and oxidation fueling n-butanol/biodiesel/diesel blends were experimentally investigated in a constant volume combustion chamber with an optical access. B0S20D80 (0% n-butanol, 20% soybean biodiesel, and 80% diesel in volume) was prepared as the base fuel. n-Butanol was added into the base fuel by volumetric percent of 5% and 10%, denoted as B5S15D80 (5% n-butanol/15% soybean biodiesel/80% diesel) and B10S10D80 (10% n-butanol/10% soybean biodiesel/80% diesel). The ambient temperatures at the time of fuel injection were set to 800 K, 900 K, 1000 K, and 1200 K. Results indicate that the penetration length reduces with the increase of n-butanol volumes in blending fuels and ambient temperatures. The spray penetration presents a sudden drop as fueling B10S10D80 at 800 K and 900 K, which might be caused by micro-explosion. A larger premixed combustion process is observed at low ambient temperatures, while the heat release rate of high ambient temperatures presents mixing controlled diffusion combustion. With a lower ambient temperature, the auto-ignition delay becomes longer with increasing of n-butanol volume in blends. However, with increasing of ambient temperatures, the auto-ignition timing between three fuels becomes unperceivable. Generally, low n-butanol addition has a limited or no effect on the auto-ignition timing in the current conditions. Compared with the base fuel of B0S20D80, n-butanol additive with 5% or 10% in volume can reduce soot

  18. Liquid nitrogen spray cryotherapy in Barrett's esophagus with high-grade dysplasia: long-term results.

    Science.gov (United States)

    Gosain, Sonia; Mercer, Kim; Twaddell, William S; Uradomo, Lance; Greenwald, Bruce D

    2013-08-01

    Liquid nitrogen endoscopic spray cryotherapy can safely and effectively eradicate high-grade dysplasia in Barrett's esophagus (BE-HGD). Long-term data on treatment success and safety are lacking. To assess the long-term safety and efficacy of spray cryotherapy in patients with BE-HGD. Single-center, retrospective study. Tertiary-care referral center. A total of 32 patients with BE-HGD of any length. Patients were treated with liquid nitrogen spray cryotherapy every 8 weeks until complete eradication of HGD (CE-HGD) and intestinal metaplasia (CE-IM) was found by endoscopic biopsy. Surveillance endoscopy with biopsies was performed for at least 2 years. CE-HGD, CE-IM, durability of response, disease progression, and adverse events. CE-HGD was 100% (32/32), and CE-IM was 84% (27/32) at 2-year follow-up. At last follow-up (range 24-57 months), CE-HGD was 31/32 (97%), and CE-IM was 26/32 (81%). Recurrent HGD was found in 6 (18%), with CE-HGD in 5 after repeat treatment. One patient progressed to adenocarcinoma, downgraded to HGD after repeat cryotherapy. BE segment length ≥3 cm was associated with a higher recurrence of IM (P = .004; odds ratio 22.6) but not HGD. No serious adverse events occurred. Stricture was seen in 3 patients (9%), all successfully dilated. Retrospective study design, small sample size. In patients with BE-HGD, liquid nitrogen spray cryotherapy has an acceptable safety profile and success rate for eliminating HGD and IM and is associated with a low rate of recurrence or progression to cancer with long-term follow-up. Copyright © 2013 American Society for Gastrointestinal Endoscopy. Published by Mosby, Inc. All rights reserved.

  19. DNS Study of the Ignition of n-Heptane Fuel Spray under HCCI Conditions

    Science.gov (United States)

    Wang, Yunliang; Rutland, Christopher J.

    2004-11-01

    Direct numerical simulations are carried out to investigate the mixing and auto-ignition processes of n-heptane fuel spray in a turbulent field using a skeletal chemistry mechanism with 44 species and 112 reactions. For the solution of the carrier gas fluid, we use the Eulerian method, while for the fuel spray, the Lagrangian method is used. We use an eighth-order finite difference scheme to calculate spacial derivatives and a fourth-order Runge-Kutta scheme for the time integration. The initial gas temperature is 926 K and the initial gas pressure is 30 atmospheres. The initial global equivalence ratio based on the fuel concentration is around 0.4. The initial droplet diameter is 60 macrons and the droplet temperature is 300 K. Evolutions of averaged temperature, species mass fraction, heat release and reaction rate are presented. Contours of temperature and species mass fractions are presented. The objective is to understand the mechanism of ignition under Homogeneous Charged Compression Ignition (HCCI) conditions, aiming at providing some useful information of HCCI combustion, which is one of the critical issues to be resolved.

  20. Producing liquid fuels from biomass

    Science.gov (United States)

    Solantausta, Yrjo; Gust, Steven

    The aim of this survey was to compare, on techno-economic criteria, alternatives of producing liquid fuels from indigenous raw materials in Finland. Another aim was to compare methods under development and prepare a proposal for steering research related to this field. Process concepts were prepared for a number of alternatives, as well as analogous balances and production and investment cost assessments for these balances. Carbon dioxide emissions of the alternatives and the price of CO2 reduction were also studied. All the alternatives for producing liquid fuels from indigenous raw materials are utmost unprofitable. There are great differences between the alternatives. While the production cost of ethanol is 6 to 9 times higher than the market value of the product, the equivalent ratio for substitute fuel oil produced from peat by pyrolysis is 3 to 4. However, it should be borne in mind that the technical uncertainties related to the alternatives are of different magnitude. Production of ethanol from barley is of commercial technology, while biomass pyrolysis is still under development. If the aim is to reach smaller carbon dioxide emissions by using liquid biofuels, the most favorable alternative is pyrolysis oil produced from wood. Fuels produced from cultivated biomass are more expensive ways of reducing CO2 emissions. Their potential of reducing CO2 emissions in Finland is insignificant. Integration of liquid fuel production to some other production line is more profitable.

  1. Cold spray deposition of Ti{sub 2}AlC coatings for improved nuclear fuel cladding

    Energy Technology Data Exchange (ETDEWEB)

    Maier, Benjamin R. [University of Wisconsin, Madison, WI (United States); Garcia-Diaz, Brenda L. [Savannah River National Laboratory, Aiken, SC (United States); Hauch, Benjamin [University of Wisconsin, Madison, WI (United States); Olson, Luke C.; Sindelar, Robert L. [Savannah River National Laboratory, Aiken, SC (United States); Sridharan, Kumar, E-mail: kumar@engr.wisc.edu [University of Wisconsin, Madison, WI (United States)

    2015-11-15

    Coatings of Ti{sub 2}AlC MAX phase compound have been successfully deposited on Zircaloy-4 (Zry-4) test flats, with the goal of enhancing the accident tolerance of LWR fuel cladding. Low temperature powder spray process, also known as cold spray, has been used to deposit coatings ∼90 μm in thickness using powder particles of <20 μm. X-ray diffraction analysis showed the phase-content of the deposited coatings to be identical to the powders indicating that no phase transformation or oxidation had occurred during the coating deposition process. The coating exhibited a high hardness of about 800 H{sub K} and pin-on-disk wear tests using abrasive ruby ball counter-surface showed the wear resistance of the coating to be significantly superior to the Zry-4 substrate. Scratch tests revealed the coatings to be well-adhered to the Zry-4 substrate. Such mechanical integrity is required for claddings from the standpoint of fretting wear resistance and resisting wear handling and insertion. Air oxidation tests at 700 °C and simulated LOCA tests at 1005 °C in steam environment showed the coatings to be significantly more oxidation resistant compared to Zry-4 suggesting that such coatings can potentially provide accident tolerance to nuclear fuel cladding. - Highlights: • Deposited Ti{sub 2}AlC coatings on Zircaloy-4 substrates with a low pressure powder spray process, also known as cold spray. • Coatings have high hardness and wear resistance for both damage resistance during rod insertion and fretting wear resistance. • The oxidation resistance of Ti{sub 2}AlC coated Zircaloy-4 at 700 °C and 1005 °C was significantly superior to uncoated Zircaloy. • Cold spray of Ti{sub 2}AlC demonstrates considerable promise as a near-term solution for accident tolerant Zr-alloy fuel claddings.

  2. Spray sealing: A breakthrough in integral fuel tank sealing technology

    Science.gov (United States)

    Richardson, Martin D.; Zadarnowski, J. H.

    1989-11-01

    In a continuing effort to increase readiness, a new approach to sealing integral fuel tanks is being developed. The technique seals potential leak sources by spraying elastomeric materials inside the tank cavity. Laboratory evaluations project an increase in aircraft supportability and reliability, an improved maintainability, decreasing acquisition and life cycle costs. Increased usable fuel volume and lower weight than conventional bladders improve performance. Concept feasibility was demonstrated on sub-scale aircraft fuel tanks. Materials were selected by testing sprayable elastomers in a fuel tank environment. Chemical stability, mechanical properties, and dynamic durability of the elastomer are being evaluated at the laboratory level and in sub-scale and full scale aircraft component fatigue tests. The self sealing capability of sprayable materials is also under development. Ballistic tests show an improved aircraft survivability, due in part to the elastomer's mechanical properties and its ability to damp vibrations. New application equipment, system removal, and repair methods are being investigated.

  3. Cold spray copper coatings for used fuel containers

    Energy Technology Data Exchange (ETDEWEB)

    Keech, P. [Nuclear Waste Management Organization, Toronto, ON (Canada); Vo, P.; Poirier, D.; Legoux, J-G [National Research Council, Boucherville QC, (Canada)

    2015-07-01

    Recently, the Nuclear Waste Management Organization has been developing copper coatings as a method of protecting steel used fuel containers (UFCs) from corrosion within a deep geological repository. The corrosion barrier design is based on the application of a copper coating bonded directly to the exterior surface of the UFC structural core. Copper coating technologies amendable to supply of pre-coated UFC vessel components and application to the weld zone following UFC closure within the radiological environment have been investigated. Copper cold spray has been assessed for both operations; this paper outlines the research and development to date of this technique. (author)

  4. Study of fuel spray characteristics for premixed lean diesel combustion; Kihaku yokongo diesel kikan ni okeru nenryo funmu keisei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, S.; Miyamoto, T.; Harada, A.; Akagawa, H.; Tsujimura, K. [New ACE Institute Co. Ltd., Tokyo (Japan)

    1998-05-01

    A study is being made on premixed lean diesel combustion (PREDIC) by means of early fuel injection in diesel engines. The PREDIC makes it possible to largely reduce NOx emission, but has such problems as ignition control and increase in THC and CO generation. In order to clarify the relationship between fuel spray characteristics in the PREDIC and properties of gas mixture and exhausts, the present study has investigated spread and internal structure of the spray by means of spray observation experiment using a pintle swirl nozzle. Based on the result therefrom, simulations were used to investigate effects of spatial dispersion characteristics of the spray on properties of the gas mixture and exhausts before ignition. The pintle swirl nozzle forms conical spray having an air layer inside the spray, where penetration is suppressed even under low atmospheric pressure. By forming hollow spray or solid spray in the conical spray, a possibility was indicated that equivalent ratio distribution of the gas mixture can be controlled and NO emission may be reduced. 8 refs., 12 figs., 1 tab.

  5. Characterization of an evaporating direct-injected gasoline spray using laser-induced exciplex fluorescence and particle image velocimetry techniques

    Energy Technology Data Exchange (ETDEWEB)

    Dong-Seok Choi; Choongsik Bae [Korea Advanced Institute of Science and Technology, Taejon (Korea). Dept. of Mechanical Engineering; Duck-Jool Kim [Pusan National University (Korea). School of Mechanical Engineering

    2004-07-01

    The purpose of this study is to characterize an evaporating direct-injected (DI) gasoline spray from a high-pressure swirl injector using the laser-induced exciplex fluorescence (LIEF) technique and particle image velocimetry (PIV). A fluorobenzene/diethylmethylamine (DEMA) system was used as the exciplex-forming dopants. The behaviour of the liquid and vapour phases was analysed by image processing. For the analysis of vorticity inside the spray, droplet velocity data obtained by PIV were used. The experiments were performed at two ambient temperatures (293 and 473 K) and three different ambient pressures (0.1, 0.5 and 1.0 MPa). It was found that ambient temperature had a significant effect on the axial and radial growth of the liquid phase of the evaporating spray at atmospheric pressure while it had little effect under elevated pressures. Radial growth of the vapour phase of the evaporating spray was more dominant than axial growth under high temperature and pressure conditions. As the ambient pressure was elevated, the liquid phase of the spray transformed from a hollow cone to a solid cone of bell shape, while the vapour phase varied from a widespread distribution to a compact shape with a locally richer mixture. The evaporating spray could be divided into two spray regions from the analysis of vorticity and the distributions of liquid and vapour phases. The cone region (penetrations of 0.3-0.5) was mainly liquid phase and disappeared rapidly at the end of injection. The mixing region contained the active interaction between entrained air and fuel vapour. (author)

  6. Measurement of Ambient Air Motion of D. I. Gasoline Spray by LIF-PIV

    Science.gov (United States)

    Yamakawa, Masahisa; Isshiki, Seiji; Yoshizaki, Takuo; Nishida, Keiya

    Ambient air velocity distributions in and around a D. I. gasoline spray were measured using a combination of LIF and PIV techniques. A rhodamine and water solution was injected into ambient air to disperse the fine fluorescent liquid particles used as tracers. A fuel spray was injected into the fluorescent tracer cloud and was illuminated by an Nd: YAG laser light sheet (532nm). The scattered light from the spray droplets and tracers was cut off by a high-pass filter (>560nm). As the fluorescence (>600nm) was transmitted through the high-pass filter, the tracer images were captured using a CCD camera and the ambient air velocity distribution could be obtained by PIV based on the images. This technique was applied to a D. I. gasoline spray. The ambient air flowed up around the spray and entered into the tail of the spray. Furthermore, the relative velocity between the spray and ambient air was investigated.

  7. Investigation of the temporal evolution and spatial variation of in-cylinder engine fuel spray characteristics

    International Nuclear Information System (INIS)

    Qin, Wenjin; Hung, David L.S.; Xu, Min

    2015-01-01

    Highlights: • POD quadruple decomposition can reconstruct spray structure into different parts. • Different quadruple POD parts reveal different levels of spay field intensity. • Large scale structure part dominates the CCV of the entire spray. • In-cylinder flow field has the strongest effect on CCV of spray structure. - Abstract: The proper orthogonal decomposition (POD) method is applied to analyze the pulsing spray characteristics of the fuel injection inside a four-valve optical spark-ignition direct-injection (SIDI) engine. The instantaneous spray structures are decomposed into four parts, namely the mean structure, large scale structure, transition structure and small scale structure, respectively, by using POD quadruple decomposition. The cycle-to-cycle variations (CCV) of the in-cylinder pulsing spray structure are examined separately based on the four parts. Analysis results indicate that the four parts have different characteristics, and each individual part represents a specific instantaneous spray structure. First, the mean part contains more than 90% of the total intensity of the spray field throughout the whole injection process. Moreover, the large scale structure part has the highest CCV level among all four parts, and it dominates the CCV of the entire spray field. The CCV of spray can be influenced by different engine operating conditions. In particular, the in-cylinder flow field has the strongest effect on the spray CCV. The varying motion of the in-cylinder flow field significantly influences the CCV of the large scale spray part, which in turn affects the CCV characteristics of the whole spray field

  8. Fuel flexible distributed combustion for efficient and clean gas turbine engines

    International Nuclear Information System (INIS)

    Khalil, Ahmed E.E.; Gupta, Ashwani K.

    2013-01-01

    Highlights: • Examined distributed combustion for gas turbines applications using HiTAC. • Gaseous, liquid, conventional and bio-fuels are examined with ultra-low emissions. • Novel design of fuel flexibility without any atomizer for liquid fuel sprays. • Demonstrated fuel flexibility with emissions x and CO, low noise, enhanced stability, higher efficiency and alleviation of combustion instability. Distributed reaction conditions were achieved using swirl for desirable controlled mixing between the injected air, fuel and hot reactive gases from within the combustor prior to mixture ignition. In this paper, distributed combustion is further investigated using a variety of fuels. Gaseous (methane, diluted methane, hydrogen enriched methane and propane) and liquid fuels, including both traditional (kerosene) and alternate fuels (ethanol) that cover a wide range of calorific values are investigated with emphasis on pollutants emission and combustor performance with each fuel. For liquid fuels, no atomization or spray device was used. Performance evaluation with the different fuels was established to outline the flexibility of the combustor using a wide range of fuels of different composition, phase and calorific value with specific focus on ultra-low pollutants emission. Results obtained on pollutants emission and OH * chemiluminescence for the specific fuels at various equivalence ratios are presented. Near distributed combustion conditions with less than 8 PPM of NO emission were demonstrated under novel premixed conditions for the various fuels tested at heat (energy) release intensity (HRI) of 27 MW/m 3 -atm. and a rather high equivalence ratio of 0.6. Higher equivalence ratios lacked favorable distributed combustion conditions. For the same conditions, CO emission varied for each fuel; less than 10 ppm were demonstrated for methane based fuels, while heavier liquid fuels provided less than 40 ppm CO emissions. Lower emissions of NO ( x can be possible by

  9. Investigation of spray characteristics from a low-pressure common rail injector for use in a homogeneous charge compression ignition engine

    Science.gov (United States)

    Lee, Kihyung; Reitz, Rolf D.

    2004-03-01

    Homogeneous charge compression ignition (HCCI) combustion provides extremely low levels of pollutant emissions, and thus is an attractive alternative for future IC engines. In order to achieve a uniform mixture distribution within the engine cylinder, the characteristics of the fuel spray play an important role in the HCCI engine concept. It is well known that high-pressure common rail injection systems, mainly used in diesel engines, achieve poor mixture formation because of the possibility of direct fuel impingement on the combustion chamber surfaces. This paper describes spray characteristics of a low-pressure common rail injector which is intended for use in an HCCI engine. Optical diagnostics including laser diffraction and phase Doppler methods, and high-speed camera photography, were applied to measure the spray drop diameter and to investigate the spray development process. The drop sizing results of the laser diffraction method were compared with those of a phase Doppler particle analyser (PDPA) to validate the accuracy of the experiments. In addition, the effect of fuel properties on the spray characteristics was investigated using n-heptane, Stoddard solvent (gasoline surrogate) and diesel fuel because HCCI combustion is sensitive to the fuel composition. The results show that the injector forms a hollow-cone sheet spray rather than a liquid jet, and the atomization efficiency is high (small droplets are produced). The droplet SMD ranged from 15 to 30 µm. The spray break-up characteristics were found to depend on the fuel properties. The break-up time for n-heptane is shorter and the drop SMD is smaller than that of Stoddard solvent and diesel fuel.

  10. Experimental study of the injection conditions influence over n-dodecane and diesel sprays with two ECN single-hole nozzles. Part I: Inert atmosphere

    International Nuclear Information System (INIS)

    Gimeno, Jaime; Bracho, Gabriela; Martí-Aldaraví, Pedro; Peraza, Jesús E.

    2016-01-01

    In this research, two Engine Combustion Network (ECN) mono-orifice nozzles, referred to as Spray C and Spray D respectively, were analyzed by performing visualization tests through Schlieren and Diffused Backlight Illumination (DBI) techniques under a wide range of ambient conditions in a non-reactive atmosphere. Spray C presents a straight nozzle designed with a sharp fillet in opposition to Spray D that has similar hydraulic properties, but with a convergent nozzle construction and a smoother corner. The experiments were carried out injecting two distinct fuels at different injection pressure ranges, from 50 MPa to 150 MPa with n-dodecane and to 200 MPa for diesel. The images were processed with Matlab home-built routines to calculate parameters as spray penetration, spreading angle, quasi-steady liquid length, as well as the spray penetration derivative respect to the square root of time, presented in this document as R-parameter. The results showed a clear influence of nozzle geometry in all measured parameters, due mainly to the nature of Spray C to cavitation, which increase the spreading angle and consequently a reduction in vapor penetration. On the other hand, fuel properties also affected spray penetration due to its dependency on viscous forces expressed in terms of the Reynolds number and its volatility in case of liquid length. This last parameter was calculated employing two processing methodologies, finding a good general agreement between them.

  11. Optical measurements in rocket engine liquid sprays

    Science.gov (United States)

    Feikema, Douglas A.

    1994-01-01

    The performance of liquid propellant rocket engines is dependent upon many elements of the entire system. One of the most fundamental and most critical is the performance of the injector elements. Their characterization is an important part of the development of combustion devices. Optical measurements within these environments have proven to be invaluable tools in quantifying the physical environment of two phase flows. The effort reported herein involves the measurement of drop velocity, drop size, and most importantly mass flux using Phase-Doppler Particle Anemometry within a spray generated by a single swirl injector element operating in atmospheric pressure conditions. The mass flux has been determined and validated by mechanical patternation methods and by profile integration of the mass flux.

  12. Development of nonintrusive, scatter-independent techniques for measurement of liquid density inside dense sprays

    Science.gov (United States)

    Hartfield, Roy

    1994-01-01

    A nonintrusive optical technique for measuring the liquid density in sprays used to simulate LOX injector flows is under development. This manuscript is a report on work toward that development which is currently in progress. The technique is a scatter-independent, absorption-based approach which depends on the numerical inversion of a collection of absorption profiles. For the case in which visible radiation passes through liquid-gas interfaces so numerous in sprays, substantial reductions and alterations in the signal result from scattering even in the absence of absorption. To avoid these problems, X-Rays will be used as the absorbed radiation. The experimental process is simulated by integrating the absorption spectrum for a known distribution, adding instrument noise to this 'measurement', creating a projection from the 'measurement', filtering the projection, inverting the projection, and comparing the results with the original prescribed distribution.

  13. Experimental study of spray characteristics of biodiesel derived from waste cooking oil

    International Nuclear Information System (INIS)

    Mohan, Balaji; Yang, Wenming; Tay, Kun Lin; Yu, Wenbin

    2014-01-01

    Highlights: • B20 and diesel exhibit similar spray tip penetration and angle. • Change in orientation of spray shapes observed with different fuels. • B100 shows poor air fuel mixing compared to B20 and diesel. • Diesel shows higher equivalence ratio compared to B20 and B100. - Abstract: In this study, the fuel spray characteristics and air-fuel mixing process of waste cooking oil biodiesel (B100) and its blend with diesel (B20) were investigated and compared with diesel fuel. Spray characteristics such as spray tip penetration, spray angle, spray velocity and spray morphology were investigated under high injection and ambient pressure conditions using a constant volume spray chamber. The air-fuel mixing process was analysed using empirical relations like fuel volume, mass of air entrained within the spray and equivalence ratio. The results shows that B100 has higher spray tip penetration and velocity but narrow spray angles due to high viscosity and large momentum possessed by B100 compared to B20 and diesel fuels. The deviation in spray tip penetration reduces under high ambient pressure. The spray angle shows no change under various injection pressures; however it increases significantly under high ambient pressure. The spray shape is affected by the cavitation inside the injector nozzle holes. The fuel volume and amount of air entrainment within the spray showed that B100 exhibits poor air-fuel mixing compared to B20 and diesel fuels. Nevertheless, the equivalence ratio along the axial direction of spray reveals that the B100 has lean equivalence ratio compared to B20 and diesel fuel due to the presence of inherent oxygen content in its structure. A numerical simulation was conducted using new hybrid spray model implemented in KIVA4 and found that the results obtained from the simulation were in good agreement with the empirical results calculated from the experiments

  14. Novel materials for fuel cells operating on liquid fuels

    Directory of Open Access Journals (Sweden)

    César A. C. Sequeira

    2017-05-01

    Full Text Available Towards commercialization of fuel cell products in the coming years, the fuel cell systems are being redefined by means of lowering costs of basic elements, such as electrolytes and membranes, electrode and catalyst materials, as well as of increasing power density and long-term stability. Among different kinds of fuel cells, low-temperature polymer electrolyte membrane fuel cells (PEMFCs are of major importance, but their problems related to hydrogen storage and distribution are forcing the development of liquid fuels such as methanol, ethanol, sodium borohydride and ammonia. In respect to hydrogen, methanol is cheaper, easier to handle, transport and store, and has a high theoretical energy density. The second most studied liquid fuel is ethanol, but it is necessary to note that the highest theoretically energy conversion efficiency should be reached in a cell operating on sodium borohydride alkaline solution. It is clear that proper solutions need to be developed, by using novel catalysts, namely nanostructured single phase and composite materials, oxidant enrichment technologies and catalytic activity increasing. In this paper these main directions will be considered.

  15. Atmospheric Plasma Spraying Low-Temperature Cathode Materials for Solid Oxide Fuel Cells

    Science.gov (United States)

    Harris, J.; Kesler, O.

    2010-01-01

    Atmospheric plasma spraying (APS) is attractive for manufacturing solid oxide fuel cells (SOFCs) because it allows functional layers to be built rapidly with controlled microstructures. The technique allows SOFCs that operate at low temperatures (500-700 °C) to be fabricated by spraying directly onto robust and inexpensive metallic supports. However, standard cathode materials used in commercial SOFCs exhibit high polarization resistances at low operating temperatures. Therefore, alternative cathode materials with high performance at low temperatures are essential to facilitate the use of metallic supports. Coatings of lanthanum strontium cobalt ferrite (LSCF) were fabricated on steel substrates using axial-injection APS. The thickness and microstructure of the coating layers were evaluated, and x-ray diffraction analysis was performed on the coatings to detect material decomposition and the formation of undesired phases in the plasma. These results determined the envelope of plasma spray parameters in which coatings of LSCF can be manufactured, and the range of conditions in which composite cathode coatings could potentially be manufactured.

  16. Adjustable wettability of paperboard by liquid flame spray nanoparticle deposition

    Science.gov (United States)

    Stepien, Milena; Saarinen, Jarkko J.; Teisala, Hannu; Tuominen, Mikko; Aromaa, Mikko; Kuusipalo, Jurkka; Mäkelä, Jyrki M.; Toivakka, Martti

    2011-01-01

    Liquid flame spray process (LFS) was used for depositing TiO x and SiO x nanoparticles on paperboard to control wetting properties of the surface. By the LFS process it is possible to create either superhydrophobic or superhydrophilic surfaces. Changes in the wettability are related to structural properties of the surface, which were characterized using scanning electron microscope (SEM) and atomic force microscope (AFM). The surface properties can be ascribed as a correlation between wetting properties of the paperboard and the surface texture created by nanoparticles. Surfaces can be produced inline in a one step roll-to-roll process without need for additional modifications. Furthermore, functional surfaces with adjustable hydrophilicity or hydrophobicity can be fabricated simply by choosing appropriate liquid precursors.

  17. A study on the macroscopic spray behavior and atomization characteristics of biodiesel and dimethyl ether sprays under increased ambient pressure

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hyung Jun; Park, Su Han [Graduate School of Hanyang University, 17 Haengdang-dong, Seoungdong-gu, Seoul 133-791 (Korea); Lee, Chang Sik [Department of Mechanical Engineering, Hanyang University, 17 Haengdang-dong, Seongdong-gu, Seoul 133-791 (Korea)

    2010-03-15

    The aim of this work is to investigate the spray behaviors of biodiesel and dimethyl ether (DME) fuels using image processing and atomization performance analysis of the two fuel sprays injected through a common-rail injection system under various ambient pressure conditions in a high pressure chamber. In order to observe the biodiesel and DME fuel spray behaviors under various ambient pressures, the spray images were analyzed at various times after the start of energization using a visualization system consisting of a high speed camera and two metal halide light sources. In addition, a high pressure chamber that can withstand a pressure of 4 MPa was used for adjusting the ambient pressure. From the spray images, spray characteristics such as the spray tip penetration, cone angle, area, and contour plot at various light intensity levels were analyzed using image conversion processing. Also, the local Sauter mean diameters (SMD) were measured at various axial/radial distances from the nozzle tip by a droplet measuring system to compare the atomization performances of the biodiesel and DME sprays. The results showed that the ambient pressure had a significant effect on the spray characteristics of the fuels at the various experimental conditions. The spray tip penetration and spray area decreased as the ambient pressure increased. The contour plot of the biodiesel and DME sprays showed a high light intensity level in the center regions of the sprays. In addition, it was revealed that the atomization performance of the biodiesel spray was inferior to that of the DME spray at the same injection and ambient conditions. (author)

  18. Spray combustion of Jet-A and diesel fuels in a constant volume combustion chamber

    KAUST Repository

    Jing, Wei; Roberts, William L.; Fang, Tiegang

    2015-01-01

    This work investigates the spray combustion of Jet-A fuel in an optical constant-volume combustion chamber under different ambient initial conditions. Ambient temperature was varied at 800 K, 1000 K, and 1200 K and five different ambient O2

  19. Spray characteristics of dimethyl ether (D.M.E.) as on alternative fuel for diesel engine; Daitai diesel nenryo to shite no dimethyl ether (D.M.E.) no funmu tokusei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Wakai, K; Nishida, K; Yoshizaki, T; Hiroyasu, H [Hiroshima University, Hiroshima (Japan)

    1997-10-01

    D.M.E. which was paid attention to as on alternative fuel for a diesel engine, was injected by using Bosch type injection pump and a hole nozzle into a high pressure and high temperature vessel. The spray was observed by using schlieren photography. Spray characteristics, such as, the tip penetration, the cone angle and the volume of the spray were and were compared with a diesel fuel spray. The following thing, and so on were found out as a results. The spray angle of the DME spray of atmosphere pressure Pa=0.1Mpa spreads out large in comparison with the diesel fuel spray, and the way of the change by the pressure is contrary to the case of the diesel fuel spray. 3 refs., 6 figs., 1 tab.

  20. Spray characteristics and spray cooling heat transfer in the non-boiling regime

    International Nuclear Information System (INIS)

    Cheng, Wen-Long; Han, Feng-Yun; Liu, Qi-Nie; Fan, Han-Lin

    2011-01-01

    Spray cooling is an effective method for dissipating high heat fluxes in the field of electronics thermal control. In this study, experiments were performed with distilled water as a test liquid to study the spray cooling heat transfer in non-boiling regime. A Phase Doppler Anemometry (PDA) was used to study the spray characteristics. The effects of spray flow rate, spray height, and inlet temperature on spray cooling heat transfer were investigated. It was found that the parameters affect heat transfer of spray cooling in non-boiling regime by the spray characteristics and working fluid thermophysical properties. Then the corresponding droplet axial velocity and Sauter mean diameter (SMD) were successfully correlated with mean absolute error of 15%, which were based upon the orifice diameter, the Weber and Reynolds numbers of the orifice flow prior to liquid breakup, dimensionless spray height and spray cross-section radius. The heat transfer in non-boiling regime was correlated with a mean absolute error of 7%, which was mainly associated with the working fluid thermophysical properties, the Weber and Reynolds numbers hitting the heating surface, dimensionless heating surface temperature and diameter. -- Highlights: → The spray flow rate, spray height, and inlet temperature affect heat transfer of spray cooling in non-boiling regime by the spray characteristics and the working fluid thermophysical properties. → Then the corresponding droplet axial velocity and Sauer mean diameter (SMD) were successfully correlated with mean absolute error of 15%. → The heat transfer in non-boiling regime was correlated with a mean absolute error of 7%.

  1. Structure of Non-evaporating diesel sprays

    International Nuclear Information System (INIS)

    Mirza, M.R.; Baluch, A.H.; Tahir, Z.R.

    2008-01-01

    Need is always felt of some rational experimental information on fuel spray jet formation, its development and dispersion in the combustion chamber of an internal combustion engine. The latest study uses computational fluid dynamics for the modeling of engine flows. The original experimental work of the present author on non-evaporating sprays produced by a single-hole orifice type nozzle using a distribution type commercial fuel injection pump forms the basis to derive correlations for penetration rates, break up times and lengths of non-evaporating diesel sprays. The correlations derived can be used to do CFD modeling of sprays under variable conditions of injector nozzle hole diameter, fuel injection pressure and combustion chamber pressure. (author)

  2. Nuclear Energy and Synthetic Liquid Transportation Fuels

    Science.gov (United States)

    McDonald, Richard

    2012-10-01

    This talk will propose a plan to combine nuclear reactors with the Fischer-Tropsch (F-T) process to produce synthetic carbon-neutral liquid transportation fuels from sea water. These fuels can be formed from the hydrogen and carbon dioxide in sea water and will burn to water and carbon dioxide in a cycle powered by nuclear reactors. The F-T process was developed nearly 100 years ago as a method of synthesizing liquid fuels from coal. This process presently provides commercial liquid fuels in South Africa, Malaysia, and Qatar, mainly using natural gas as a feedstock. Nuclear energy can be used to separate water into hydrogen and oxygen as well as to extract carbon dioxide from sea water using ion exchange technology. The carbon dioxide and hydrogen react to form synthesis gas, the mixture needed at the beginning of the F-T process. Following further refining, the products, typically diesel and Jet-A, can use existing infrastructure and can power conventional engines with little or no modification. We can then use these carbon-neutral liquid fuels conveniently long into the future with few adverse environmental impacts.

  3. Slurry spray distribution within a simulated laboratory scale spray dryer

    International Nuclear Information System (INIS)

    Bertone, P.C.

    1979-01-01

    It was found that the distribution of liquid striking the sides of a simulated room temperature spray dryer was not significantly altered by the choice of nozles, nor by a variation in nozzle operating conditions. Instead, it was found to be a function of the spray dryer's configuration. A cocurrent flow of air down the drying cylinder, not possible with PNL's closed top, favorably altered the spray distribution by both decreasing the amount of liquid striking the interior of the cylinder from 72 to 26% of the feed supplied, and by shifting the zone of maximum impact from 1.0 to 1.7 feet from the nozzle. These findings led to the redesign of the laboratory scale spray dryer to be tested at the Savannah River Plant. The diameter of the drying chamber was increased from 5 to 8 inches, and a cocurrent flow of air was established with a closed recycle. Finally, this investigation suggested a drying scheme which offers all the advantages of spray drying without many of its limitations

  4. Comparison of alternate fuels for aircraft. [liquid hydrogen, liquid methane, and synthetic aviation kerosene

    Science.gov (United States)

    Witcofski, R. D.

    1979-01-01

    Liquid hydrogen, liquid methane, and synthetic aviation kerosene were assessed as alternate fuels for aircraft in terms of cost, capital requirements, and energy resource utilization. Fuel transmission and airport storage and distribution facilities are considered. Environmental emissions and safety aspects of fuel selection are discussed and detailed descriptions of various fuel production and liquefaction processes are given. Technological deficiencies are identified.

  5. Characterization of Sodium Spray Aerosols

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, C. T.; Koontz, R. L.; Silberberg, M. [Atomics International, North American Rockwell Corporation, Canoga Park, CA (United States)

    1968-12-15

    The consequences of pool and spray fires require evaluation in the safety analysis of liquid metal-cooled fast breeder reactors. Sodium spray fires are characterized by high temperature and pressure, produced during the rapid combustion of sodium in air. Following the initial energy release, some fraction of the reaction products are available as aerosols which follow the normal laws of agglomeration, growth, settling, and plating. An experimental study is underway at Atomics International to study the characteristics of high concentration sprays of liquid sodium in reduced oxygen atmospheres and in air. The experiments are conducted in a 31.5 ft{sup 3} (2 ft diam. by 10 ft high) vessel, certified for a pressure of 100 lb/in{sup 2} (gauge). The spray injection apparatus consists of a heated sodium supply pot and a spray nozzle through which liquid sodium is driven by nitrogen pressure. Spray rate and droplet size can be varied by the injection velocity (nozzle size, nitrogen pressure, and sodium temperature). Aerosols produced in 0, 4, and 10 vol. % oxygen environments have been studied. The concentration and particle size distribution of the material remaining in the air after the spray injection and reaction period are measured. Fallout rates are found to be proportional to the concentration of aerosol which remains airborne following the spray period. (author)

  6. Spray solidification of nuclear waste

    International Nuclear Information System (INIS)

    Bonner, W.F.; Blair, H.T.; Romero, L.S.

    1976-08-01

    The spray calciner is a relatively simple machine. Operation is simple and is easily automated. Startup and shutdown can be performed in less than an hour. A wide variety of waste compositions and concentrations can be calcined under easily maintainable conditions. Spray calcination of high-level and mixed high- and intermediate-level liquid wastes has been demonstrated. Waste concentrations of from near infinite dilution to less than 225 liters per tonne of fuel are calcinable. Wastes have been calcined containing over 2M sodium. Feed concentration, composition, and flowrate can vary rapidly by over a factor of two without requiring operator action. Wastes containing mainly sodium cations can be spray calcined by addition of finely divided silica to the feedstock. A remotely replaceable atomizing nozzle has been developed for use in plant-scale equipment. Calciner capacity of over 75 l/h has been demonstrated in pilot-scale equipment. Sintered stainless steel filters are effective in deentraining over 99.9 percent of the solids that result from calcining the feedstock. The volume of recycle required from the effluent treatment system is very small. Vibrator action maintains the calcine holdup in the calciner at less than 1 kg. Successful remote operation and maintenance of a heated-wall spray calciner have been demonstrated while processing high-level waste. Radionuclide volatilization was acceptably low

  7. Quantification of sauter mean diameter in diesel sprays using scattering-absorption extinction measurements

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, Gabrielle L; Magnotti, Gina M; Knox, Benjamin W; Genzale, Caroline L; Matusik, Katarzyna E; Duke, Daniel J; Powell, Christopher F; Kastengren, Alan L

    2017-05-18

    Quantitative measurements of the primary breakup process in diesel sprays are lacking due to a range of experimental and diagnostic challenges, including: high droplet number density environments, very small characteristic drop size scales (~1-10 μm), and high characteristic velocities in the primary breakup region (~600 m/s). Due to these challenges, existing measurement techniques have failed to resolve a sufficient range of the temporal and spatial scales involved and much remains unknown about the primary atomization process in practical diesel sprays. To gain a better insight into this process, we have developed a joint visible and x-ray extinction measurement technique to quantify axial and radial distributions of the path-integrated Sauter Mean Diameter (SMD) and Liquid Volume Fraction (LVF) for diesel-like sprays. This technique enables measurement of the SMD in regions of moderate droplet number density, enabling construction of the temporal history of drop size development within practical diesel sprays. The experimental campaign was conducted jointly at the Georgia Institute of Technology and Argonne National Laboratory using the Engine Combustion Network “Spray D” injector. X-ray radiography liquid absorption measurements, conducted at the Advanced Photon Source at Argonne, quantify the liquid-fuel mass and volume distribution in the spray. Diffused back-illumination liquid scattering measurements were conducted at Georgia Tech to quantify the optical thickness throughout the spray. By application of Mie-scatter equations, the ratio of the absorption and scattering extinction measurements is demonstrated to yield solutions for the SMD. This work introduces the newly developed scattering-absorption measurement technique and highlights the important considerations that must be taken into account when jointly processing these measurements to extract the SMD. These considerations include co-alignment of measurements taken at different institutions

  8. Estimation of the diameter-charge distribution in polydisperse electrically charged sprays of electrically insulating liquids

    Energy Technology Data Exchange (ETDEWEB)

    Rigit, A.R.H. [University of Sarawak, Faculty of Engineering, Kota Samarahan, Sarawak (Malaysia); Shrimpton, John S. [University of Southampton, Energy Technology Research Group, School of Engineering Sciences, Southampton (United Kingdom)

    2009-06-15

    The majority of scientific and industrial electrical spray applications make use of sprays that contain a range of drop diameters. Indirect evidence suggests the mean drop diameter and the mean drop charge level are usually correlated. In addition, within each drop diameter class there is every reason to suspect a distribution of charge levels exist for a particular drop diameter class. This paper presents an experimental method that uses the joint PDF of drop velocity and diameter, obtained from phase Doppler anemometry measurements, and directly obtained spatially resolved distributions of the mass and charge flux to obtain a drop diameter and charge frequency distribution. The method is demonstrated using several data-sets obtained from experimental measurements of steady poly-disperse sprays of an electrically insulating liquid produced with the charge injection technique. The space charge repulsion in the spray plume produces a hollow cone spray structure. In addition an approximate self-similarity is observed, with the maximum radial mass and charge flow occurring at r/d{proportional_to}200. The charge flux profile is slightly offset from the mass flux profile, and this gives direct evidence that the spray specific charge increases from approximately 20% of the bulk mean spray specific charge on the spray axis to approximately 200% of the bulk mean specific charge in the periphery of the spray. The results from the drop charge estimation model suggest a complex picture of the correlation between drop charge and drop diameter, with spray specific charge, injection velocity and orifice diameter all contributing to the shape of the drop diameter-charge distribution. Mean drop charge as a function of the Rayleigh limit is approximately 0.2, and is invariant with drop diameter and also across the spray cases tested. (orig.)

  9. Estimation of the diameter-charge distribution in polydisperse electrically charged sprays of electrically insulating liquids

    Science.gov (United States)

    Rigit, A. R. H.; Shrimpton, John S.

    2009-06-01

    The majority of scientific and industrial electrical spray applications make use of sprays that contain a range of drop diameters. Indirect evidence suggests the mean drop diameter and the mean drop charge level are usually correlated. In addition, within each drop diameter class there is every reason to suspect a distribution of charge levels exist for a particular drop diameter class. This paper presents an experimental method that uses the joint PDF of drop velocity and diameter, obtained from phase Doppler anemometry measurements, and directly obtained spatially resolved distributions of the mass and charge flux to obtain a drop diameter and charge frequency distribution. The method is demonstrated using several data-sets obtained from experimental measurements of steady poly-disperse sprays of an electrically insulating liquid produced with the charge injection technique. The space charge repulsion in the spray plume produces a hollow cone spray structure. In addition an approximate self-similarity is observed, with the maximum radial mass and charge flow occurring at r/ d ~ 200. The charge flux profile is slightly offset from the mass flux profile, and this gives direct evidence that the spray specific charge increases from approximately 20% of the bulk mean spray specific charge on the spray axis to approximately 200% of the bulk mean specific charge in the periphery of the spray. The results from the drop charge estimation model suggest a complex picture of the correlation between drop charge and drop diameter, with spray specific charge, injection velocity and orifice diameter all contributing to the shape of the drop diameter-charge distribution. Mean drop charge as a function of the Rayleigh limit is approximately 0.2, and is invariant with drop diameter and also across the spray cases tested.

  10. Ultrafast high-repetition imaging of fuel sprays using picosecond fiber laser.

    Science.gov (United States)

    Purwar, Harsh; Wang, Hongjie; Tang, Mincheng; Idlahcen, Saïd; Rozé, Claude; Blaisot, Jean-Bernard; Godin, Thomas; Hideur, Ammar

    2015-12-28

    Modern diesel injectors operate at very high injection pressures of about 2000 bar resulting in injection velocities as high as 700 m/s near the nozzle outlet. In order to better predict the behavior of the atomization process at such high pressures, high-resolution spray images at high repetition rates must be recorded. However, due to extremely high velocity in the near-nozzle region, high-speed cameras fail to avoid blurring of the structures in the spray images due to their exposure time. Ultrafast imaging featuring ultra-short laser pulses to freeze the motion of the spray appears as an well suited solution to overcome this limitation. However, most commercial high-energy ultrafast sources are limited to a few kHz repetition rates. In the present work, we report the development of a custom-designed picosecond fiber laser generating ∼ 20 ps pulses with an average power of 2.5 W at a repetition rate of 8.2 MHz, suitable for high-speed imaging of high-pressure fuel jets. This fiber source has been proof tested by obtaining backlight images of diesel sprays issued from a single-orifice injector at an injection pressure of 300 bar. We observed a consequent improvement in terms of image resolution compared to standard white-light illumination. In addition, the compactness and stability against perturbations of our fiber laser system makes it particularly suitable for harsh experimental conditions.

  11. Experimental investigation concerning the influence of fuel type and properties on the injection and atomization of liquid biofuels in an optical combustion chamber

    International Nuclear Information System (INIS)

    Galle, J.; Defruyt, S.; Van de Maele, C.; Rodriguez, R. Piloto; Denon, Q.; Verliefde, A.; Verhelst, S.

    2013-01-01

    Due to the scarcity of fossil fuels and the future stringent emission limits, there is an increasing interest for the use of renewable biofuels in compression ignition engines. However, these fuels have different physical, chemical and thermodynamic properties affecting atomization, spray development and combustion processes. The results reported in this paper have been obtained by experimentation with a constant volume combustion chamber. The influences of physical fuel properties on injections under non-evaporating conditions are studied, using a pump-line-nozzle system from a medium speed diesel engine with injection pressures up to 1200 bar, by changing the fuel type and temperature. Experiments were conducted for diesel, biodiesel, straight vegetable oils and animal fats. Injection pressure and needle lift measurements were analyzed. A high speed camera was used to visualize the spray, which enabled us to study the spray penetration and spray angle. Our results show that the fuel temperature is an important parameter to control because it significantly affects the fuel properties. Both the injection timing and injection duration are affected by the fuel properties. The influences of these properties on the spray development were less pronounced. At low temperatures, a strongly deteriorated atomization of oils and fats was observed. -- Highlights: • Spray measurements in an optical combustion chamber. • Influence on the injections system is compared for different bio-fuels. •Temperature effects the fuel properties, with strong influence on the injection system. • Viscosity has significant influence on atomization, especially for viscous fuels. • No difference for spray penetration and angle unlike the mass distribution

  12. Spray combustion of biomass-based renewable diesel fuel using multiple injection strategy in a constant volume combustion chamber

    KAUST Repository

    Jing, Wei

    2016-05-26

    Effect of a two-injection strategy associated with a pilot injection on the spray combustion process was investigated under conventional diesel combustion conditions (1000 K and 21% O2 concentration) for a biomass-based renewable diesel fuel, i.e., biomass to liquid (BTL), and a regular No. 2 diesel in a constant volume combustion chamber using multiband flame measurement and two-color pyrometry. The spray combustion flame structure was visualized by using multiband flame measurement to show features of soot formation, high temperature and low temperature reactions, which can be characterized by the narrow-band emissions of radicals or intermediate species such as OH, HCHO, and CH. The objective of this study was to identify the details of multiple injection combustion, including a pilot and a main injection, and to provide further insights on how the two injections interact. For comparison, three injection strategies were considered for both fuels including a two-injection strategy (Case TI), single injection strategy A (Case SA), and single injection strategy B (Case SB). Multiband flame results show a strong interaction, indicated by OH emissions between the pilot injection and the main injection for Case TI while very weak connection is found for the narrow-band emissions acquired through filters with centerlines of 430 nm and 470 nm. A faster flame development is found for the main injection of Case TI compared to Cases SA and SB, which could be due to the high temperature environment and large air entrainment from the pilot injection. A lower soot level is observed for the BTL flame compared to the diesel flame for all three injection types. Case TI has a lower soot level compared to Cases SA and SB for the BTL fuel, while the diesel fuel maintains a similar soot level among all three injection strategies. Soot temperature of Case TI is lower for both fuels, especially for diesel. Based on these results, it is expected that the two-injection strategy could be

  13. MEASUREMENTS IN A LIQUID ATOMISER SPRAY USING THE PHASE-DOPPLER PARTICLE ANALYSER

    Directory of Open Access Journals (Sweden)

    R HADEF

    2000-12-01

    Full Text Available Experiments have been carried out at atmospheric conditions using a water atomiser spray. A phase Doppler anemometry was used to perform the measurements of the droplets size, their velocity and concentration, and photographs were taken.  The results showed that the small particles with low turbulence occupied the central core of the jet displaying a Gaussian profile for the axial velocity component.  The large particles were defected towards the outer edges of the jet, due to their higher initial momentum, and displayed relatively high levels of turbulence. The variables measured show that their spatial distributions were nearly symmetrical about the x-axis and although the number density of the droplets is very high in the centred region, most of the pulverised liquid was present in the edges of the spray.

  14. The Effect of Nozzle Design and Operating Conditions on the Atomization and Distribution of Fuel Sprays

    Science.gov (United States)

    Lee, Dana W

    1933-01-01

    The atomization and distribution characteristics of fuel sprays from automatic injection valves for compression-ignition engines were determined by catching the fuel drops on smoked-glass plates, and then measuring and counting the impressions made in the lampblack. The experiments were made in an air-tight chamber in which the air density was raised to values corresponding to engine conditions.

  15. Hydroxyapatite coatings deposited by liquid precursor plasma spraying: controlled dense and porous microstructures and osteoblastic cell responses

    International Nuclear Information System (INIS)

    Huang Yi; Song Lei; Liu Xiaoguang; Xiao Yanfeng; Wu Yao; Chen Jiyong; Wu Fang; Gu Zhongwei

    2010-01-01

    Hydroxyapatite coatings were deposited on Ti-6Al-4V substrates by a novel plasma spraying process, the liquid precursor plasma spraying (LPPS) process. X-ray diffraction results showed that the coatings obtained by the LPPS process were mainly composed of hydroxyapatite. The LPPS process also showed excellent control on the coating microstructure, and both nearly fully dense and highly porous hydroxyapatite coatings were obtained by simply adjusting the solid content of the hydroxyapatite liquid precursor. Scanning electron microscope observations indicated that the porous hydroxyapatite coatings had pore size in the range of 10-200 μm and an average porosity of 48.26 ± 0.10%. The osteoblastic cell responses to the dense and porous hydroxyapatite coatings were evaluated with human osteoblastic cell MG-63, in respect of the cell morphology, proliferation and differentiation, with the hydroxyapatite coatings deposited by the atmospheric plasma spraying (APS) process as control. The cell experiment results indicated that the heat-treated LPPS coatings with a porous structure showed the best cell proliferation and differentiation among all the hydroxyapatite coatings. Our results suggest that the LPPS process is a promising plasma spraying technique for fabricating hydroxyapatite coatings with a controllable microstructure, which has great potential in bone repair and replacement applications.

  16. Regimes of spray formation in gas-centered swirl coaxial atomizers

    Energy Technology Data Exchange (ETDEWEB)

    Sivakumar, D.; Kulkarni, V. [Indian Institute of Science, Department of Aerospace Engineering, Bangalore (India)

    2011-09-15

    Spray formation in ambient atmosphere from gas-centered swirl coaxial atomizers is described by carrying out experiments in a spray test facility. The atomizer discharges a circular air jet and an axisymmetric swirling water sheet from its coaxially arranged inner and outer orifices. A high-speed digital imaging system along with a backlight illumination arrangement is employed to record the details of liquid sheet breakup and spray development. Spray regimes exhibiting different sheet breakup mechanisms are identified and their characteristic features presented. The identified spray regimes are wave-assisted sheet breakup, perforated sheet breakup, segmented sheet breakup, and pulsation spray regime. In the regime of wave-assisted sheet breakup, the sheet breakup shows features similar to the breakup of two-dimensional planar air-blasted liquid sheets. At high air-to-liquid momentum ratios, the interaction process between the axisymmetric swirling liquid sheet and the circular air jet develops spray processes which are more specific to the atomizer studied here. The spray exhibits a periodic ejection of liquid masses whose features are dominantly controlled by the central air jet. (orig.)

  17. Low contaminant formic acid fuel for direct liquid fuel cell

    Science.gov (United States)

    Masel, Richard I [Champaign, IL; Zhu, Yimin [Urbana, IL; Kahn, Zakia [Palatine, IL; Man, Malcolm [Vancouver, CA

    2009-11-17

    A low contaminant formic acid fuel is especially suited toward use in a direct organic liquid fuel cell. A fuel of the invention provides high power output that is maintained for a substantial time and the fuel is substantially non-flammable. Specific contaminants and contaminant levels have been identified as being deleterious to the performance of a formic acid fuel in a fuel cell, and embodiments of the invention provide low contaminant fuels that have improved performance compared to known commercial bulk grade and commercial purified grade formic acid fuels. Preferred embodiment fuels (and fuel cells containing such fuels) including low levels of a combination of key contaminants, including acetic acid, methyl formate, and methanol.

  18. Coupled calculation of diesel injection, primary spray propagation and spray formation using a multifluid approach and comparison with experiments in transparent model nozzles; Gekoppelte Berechnung von Dieseleinspritzung, primaerem Strahlzerfall und Spraybildung mit dem Multifluid-Ansatz und Vergleich mit Experimenten in transparenten Modellduesen

    Energy Technology Data Exchange (ETDEWEB)

    Berg, E. von; Edelbauer, W.; Alajbegovic, A.; Tatschl, R. [AVL List GmbH, Graz (Austria)

    2004-07-01

    Based on the Eulerian multi-fluid approach cavitating nozzle flow in Diesel injectors as well as spray formation downstream of the nozzle orifice can be simulated in a single calculation. Fuel liquid, fuel vapor, spray droplets, and air are treated as interpenetrating phases. For each of the phases separate sets of conservation equations are solved. Different flow regimes such as cavitating nozzle flow and spray regions are described by using appropriate interfacial exchange terms between the phases. Besides a simplified calculation procedure the main advantage of this methodology is the direct coupling of the different flow regimes. Thus, effects of the cavitating nozzle flow can directly enter the primary break-up model, which is based on locally resolved nozzle flow turbulence. This new approach is applied for single- and multi-hole full scale Diesel injectors as well as for a large-scale model injector operated with water. The results obtained on the basis of the CFD code FIRE show good agreement compared to experimental data and yield the correct trends for both spray penetration and spray angle for increasing injection pressure. (orig.)

  19. Review of coal-water fuel pulverization technology and atomization quality registration methods

    Directory of Open Access Journals (Sweden)

    Zenkov Andrey

    2017-01-01

    Full Text Available Possibilities of coal-water fuel application in industrial power engineering are considered and described. Two main problems and disadvantages of this fuel type are suggested. The paper presents information about liquid fuel atomization technologies and provides data on nozzle type for coal-water fuel pulverization. This article also mentions some of the existing technologies for coal-water slurry spraying quality determination.

  20. NOx emissions from high swirl turbulent spray flames with highly oxygenated fuels

    KAUST Repository

    Bohon, Myles

    2013-01-01

    Combustion of fuels with fuel bound oxygen is of interest from both a practical and a fundamental viewpoint. While a great deal of work has been done studying the effect of oxygenated additives in diesel and gasoline engines, much less has been done examining combustion characteristics of fuels with extremely high mass fractions of fuel bound oxygen. This work presents an initial investigation into the very low NOx emissions resulting from the combustion of a model, high oxygen mass fraction fuel. Glycerol was chosen as a model fuel with a fuel bound oxygen mass fraction of 52%, and was compared with emissions measured from diesel combustion at similar conditions in a high swirl turbulent spray flame. This work has shown that high fuel bound oxygen mass fractions allow for combustion at low global equivalence ratios with comparable exhaust gas temperatures due to the significantly lower concentrations of diluting nitrogen. Despite similar exhaust gas temperatures, NOx emissions from glycerol combustion were up to an order of magnitude lower than those measured using diesel fuel. This is shown to be a result not of specific burner geometry, but rather is influenced by the presence of higher oxygen and lower nitrogen concentrations at the flame front inhibiting NOx production. © 2012 The Combustion Institute.

  1. Numerical study of the spray impingement onto a solid wall

    OpenAIRE

    Rodrigues, Christian Michel Gomes

    2011-01-01

    The modelling of turbulent multiphase flows has been gathering high interest in the last decades in the scientific community due to its relevance in several applications, such as in industrial and environmental processes or for chemical and biomedical purposes. In fact, regarding the industrial applications, the impingement of liquid fuel sprays onto engine surfaces has become a subject of interest due to its influence on the mixture preparation prior to combustion and, consequently, engine p...

  2. Spray pyrolysis of doped-ceria barrier layers for solid oxide fuel cells

    DEFF Research Database (Denmark)

    Szymczewska, Dagmara; Chrzan, Aleksander; Karczewski, Jakub

    2017-01-01

    Gadolinium doped ceria (Ce0.8Gd0.2O2 − x-CGO) layer fabricated by spray pyrolysis is investigated as the diffusion barrier for solid oxide fuel cell. It is deposited between the La0.6Sr0.4FeO3 − δ cathode and the yttria stabilized zirconia electrolyte to mitigate harmful interdiffusion...

  3. Thermal performance of a meso-scale liquid-fuel combustor

    International Nuclear Information System (INIS)

    Vijayan, V.; Gupta, A.K.

    2011-01-01

    Research highlights: → Demonstrated successful combustion of liquid fuel-air mixtures in a novel meso-scale combustor. → Flame quenching was eliminated using heat recirculation in a swiss roll type combustor that also extended the flammability limits. → Liquid fuel was rapidly vaporized with the use of hot narrow channel walls that eliminated the need of a fuel atomizer. → Maximum power density of the combustor was estimated to be about 8.5 GW/m3 and heat load in the range of 50-280W. → Overall efficiency of the combustor was estimated in the range of 12 to 20%. - Abstract: Combustion in small scale devices poses significant challenges due to the quenching of reactions from wall heat losses as well as the significantly reduced time available for mixing and combustion. In the case of liquid fuels there are additional challenges related to atomization, vaporization and mixing with the oxidant in the very short time-scale liquid-fuel combustor. The liquid fuel employed here is methanol with air as the oxidizer. The combustor was designed based on the heat recirculating concept wherein the incoming reactants are preheated by the combustion products through heat exchange occurring via combustor walls. The combustor was fabricated from Zirconium phosphate, a ceramic with very low thermal conductivity (0.8 W m -1 K -1 ). The combustor had rectangular shaped double spiral geometry with combustion chamber in the center of the spiral formed by inlet and exhaust channels. Methanol and air were introduced immediately upstream at inlet of the combustor. The preheated walls of the inlet channel also act as a pre-vaporizer for liquid fuel which vaporizes the liquid fuel and then mixes with air prior to the fuel-air mixture reaching the combustion chamber. Rapid pre-vaporization of the liquid fuel by the hot narrow channel walls eliminated the necessity for a fuel atomizer. Self-sustained combustion of methanol-air was achieved in a chamber volume as small as 32.6 mm 3

  4. No Heat Spray Drying Technology

    Energy Technology Data Exchange (ETDEWEB)

    Beetz, Charles [ZoomEssence, Inc., Hebron, KY (United States)

    2016-06-15

    No Heat Spray Drying Technology. ZoomEssence has developed our Zooming™ spray drying technology that atomizes liquids to powders at ambient temperature. The process of drying a liquid into a powder form has been traditionally achieved by mixing a heated gas with an atomized (sprayed) fluid within a vessel (drying chamber) causing the solvent to evaporate. The predominant spray drying process in use today employs air heated up to 400° Fahrenheit to dry an atomized liquid into a powder. Exposing sensitive, volatile liquid ingredients to high temperature causes molecular degradation that negatively impacts solubility, stability and profile of the powder. In short, heat is detrimental to many liquid ingredients. The completed award focused on several areas in order to advance the prototype dryer to a commercial scale integrated pilot system. Prior to the award, ZoomEssence had developed a prototype ‘no-heat’ dryer that firmly established the feasibility of the Zooming™ process. The award focused on three primary areas to improve the technology: (1) improved ability to formulate emulsions for specific flavor groups and improved understanding of the relationship of emulsion properties to final dry particle properties, (2) a new production atomizer, and (3) a dryer controls system.

  5. Comparison of the Viscous Liquids Spraying by the OIG and the Oil Configurations of an Effervescent Atomizer at Low Inlet Pressures

    Directory of Open Access Journals (Sweden)

    Mlkvik Marek

    2016-07-01

    Full Text Available In this work we studied the influence of the fluid injection configuration (OIG: outside-in-gas, OIL: outside-in-liquid on the internal flows and external sprays parameters. We sprayed the viscous aqueous maltodextrin solutions (μ = 60 mPa·s at a constant inlet pressure of the gas and the gas to the liquid mass flow ratio (GLR within the range 2.5 to 20%. We found that the fluids injection has a crucial influence on the internal flows. The internal flows patterns for the OIG atomizer were the slug flows, the internal flow of the OIL device was annular which led to the significant improvement of the spray quality: Smaller droplets, faster atomization, fewer pulsations.

  6. Spray Drift Reduction Evaluations of Spray Nozzles Using a Standardized Testing Protocol

    Science.gov (United States)

    2010-07-01

    Drop Size Characteristics in a Spray Using Optical Nonimaging Light-Scattering Instruments,” Annual Book of ASTM Standards, Vol. 14-02, ASTM...Test Method for Determining Liquid Drop Size Characteristics in a Spray Using Optical Non- imaging Light-Scattering Instruments 22. AGDISP Model

  7. Comparison of in vitro behavior of as-sprayed, alkaline-treated and collagen-treated bioceramic coatings obtained by high velocity oxy-fuel spray

    Energy Technology Data Exchange (ETDEWEB)

    Melero, H., E-mail: hortensia.melero.correas@gmail.com [Thermal Spray Centre, Universitat de Barcelona, Martí i Franqués, 1, 08028 Barcelona (Spain); Garcia-Giralt, N. [URFOA, IMIM (Institut Hospital del Mar d’Investigacions Mèdiques), RETICEF, Doctor Aiguader, 80, 08003 Barcelona (Spain); Fernández, J. [Thermal Spray Centre, Universitat de Barcelona, Martí i Franqués, 1, 08028 Barcelona (Spain); Díez-Pérez, A. [URFOA, IMIM (Institut Hospital del Mar d’Investigacions Mèdiques), RETICEF, Doctor Aiguader, 80, 08003 Barcelona (Spain); Servei de Medicina Interna, Hospital del Mar, Barcelona (Spain); Guilemany, J.M. [Thermal Spray Centre, Universitat de Barcelona, Martí i Franqués, 1, 08028 Barcelona (Spain)

    2014-07-01

    Hydroxyapatite (HAp)–TiO{sub 2} samples obtained using high velocity oxy-fuel spray (HVOF), that had previously shown excellent mechanical behaviour, were innovatively surface treated in order to improve their biological performance. The chosen treatments were an alkaline treatment to increase –OH radicals density on the surface (especially on TiO{sub 2} zones), and a collagen treatment to bond collagen fibrils to the –OH radicals present in hydroxyapatite. These coatings were analysed using scanning electron microscopy, energy-dispersive X-ray spectroscopy and infrared spectroscopy, and tested for human osteoblast biocompatibility and functionality. In the case of the alkaline treatment, although the –OH radicals density did not increase compared to the as-sprayed coatings, a nanostructured layer of sodium hydroxycarbonate precipitated on the surface, thus improving biological behaviour due to the nanoroughness effect. For the collagen-treated samples, collagen fibrils appeared well-adhered to the surface, and in vitro cell culture tests showed that these surfaces were much more conducive to cell adhesion and differentiation than the as-sprayed and alkaline-treated samples. These results pointed to collagen treatment as a very promising method to improve bioactivity of HAp–TiO{sub 2} thermal-sprayed coatings.

  8. An experimental study on atomizing formation process of diesel spray

    International Nuclear Information System (INIS)

    Kim, Ki Bong

    2000-02-01

    In this study, the experiment has, been conducted to investigate the spray characteristics under the parameter of an ambient pressure with a single hole nozzle having aspect ratio(L/D) of 5 and diameter of 0.45mm. Under the condition of the injection pressure of 14Mpa, the initial disintegrating process of a diesel spray is investigated and analysized according to change of the ambient pressures, 0.1, 1, 2 and 3Mpa. The double flash method has been employed to visualize the process of the diesel sprays. The results obtained in this study are as follows: 1) After spray starts, the spray is shown as non-disturbance liquid column within about 1∼2mm from the nozzle tip, whose diameter is similar to that of a nozzle. For the same injection pressure, the increase of the ambient pressure makes the length of the non-disturbance liquid column become short. 2) Due to the surface wave, ligaments of the shape thread appear at the boundary of liquid column right after spray. The more developed wave together the progress of spray transforms ligaments into droplets that have generally the uniformed size. 3) In case spraying into chambers having different ambient pressures, 1, 2, and 3Mpa, the spray tip velocities reach up to 1.5, 1.2, and 0.6ms, respectively, and decrease with lapse of time. The spray angle keeps increasing for 0.6, 1.2, and 1.4ms after spray under the various ambient pressures, 3, 2, and 1Mpa, respectively, and begins to decrease and maintains the constant value. Therefore, the transition points appear near the point where the velocity decreases and the spray angle increases, simultaneously. The higher ambient pressure leads to fast appearance of transition under the same spray pressure. 4) The disintegrating mechanism of the liquid spray is two combined effects: a) friction forces between the surface waves generated at the surface of the liquid column and the ambient gas, b) the collisions of liquid droplets and ligaments by spray were overtaking

  9. A system extinguishing a fire by insulating a liquid fuel

    International Nuclear Information System (INIS)

    Colome, Jacques; Duchene, Alain; Regnier, Jean.

    1975-01-01

    The invention refers to a system for quickly extinguishing a liquid fuel body on fire by insulating it completely from the ambient air. It applies particularly to the case of a high temperature liquid sodium sheet flowing accidentally from a circuit belonging to a fast neutron reactor. The system in question includes a lower receptacle for collecting the liquid fuel and a top cover shutting off the receptacle. This cover has inclined channels to take the liquid fuel flow and openings to allow this liquid through at the bottom end of the channels. These openings are closed by retractable shutters moving away under the pressure of the liquid in the channels and closing automatically after the liquid has flowed into the receptacle [fr

  10. NOx formation from the combustion of monodisperse n-heptane sprays doped with fuel-nitrogen additives

    Science.gov (United States)

    Sarv, Hamid; Cernansky, Nicholas P.

    1989-01-01

    A series of experiments with simulated synthetic fuels were conducted in order to investigate the effect of droplet size on the conversion of fuel-nitrogen to NOx. Pyridine and pyrrole were added to n-heptane as nitrogen-containing additives and burned as monodisperse fuel droplets under various operating conditions in a spray combustion facility. The experimental results indicate that under stoichiometric and fuel-rich conditions, reducing the droplet size increases the efficiency of fuel-N conversion to NOx. This observation is associated with improved oxidation of the pyrolysis fragments of the additive by better oxygen penetration through the droplet flame zone. The dominant reactions by which fuel-N is transformed to NOx were also considered analytically by a premixed laminar flame code. The calculations are compared to the small droplet size results.

  11. Simulation of oblique evaporating diesel sprays, and comparison with empirical correlations and simulated straight sprays

    International Nuclear Information System (INIS)

    Chaudhry, I.A.; Mirza, M.R.; Rashid, M.J.

    2010-01-01

    The innovation in software analysis and various available programming facilities have urged the designers at various levels to do indispensable calculations for engine flows. Presently, the 3-D analysis approach is under practice to do simulations for various parameters involving engine operations using various soft wares, 'Fluent' being the trendiest at the moment for CFD modeling. The present work involves CFD modeling of diesel fuel sprays at a specified angle with cylinder axis. Fuel spray modeling includes sub-models for aerodynamic drag, droplet oscillation and distortion, turbulence effects, droplet breakup, evaporation, and droplet collision and coalescence. The data available from existing published work is used to model the fuel spray and the subsequent simulation results are compared to experimental results to test validity of the proposed models. (author)

  12. Liquid chromatography-mass spectrometry coupling by the intermediary of a liquid micro chromatography-electro spray interface; Couplage chromatographie liquide-spectrometrie de masse par l`intermediaire d`une interface electrospray-microchromatographie liquide

    Energy Technology Data Exchange (ETDEWEB)

    Gillard Factor, C

    1996-12-06

    The objective of this work is to realize a liquid chromatography- mass spectrometry coupling by the intermediary of an electro spray interface and the evaluation of performances of tis analytical tool to study pollutants in water, and more particularly pesticides whom maximum admissible concentration in a table water is 0.1{mu}g/l. This study has allowed to bring to the fore the interest of the ionization mode by electro spray in a LC/MS coupling to identify and quantify pesticides in the state of traces without treating the sample. Then, it was demonstrated the usefulness of this analytical tool to detect high molecular masses molecules. (N.C.)

  13. Liquid fuels production from biomass. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Levy, P. F.; Sanderson, J. E.; Ashare, E.; Wise, D. L.; Molyneaux, M. S.

    1980-06-30

    The current program to convert biomass into liquid hydrocarbon fuels is an extension of a previous program to ferment marine algae to acetic acid. In that study it was found that marine algae could be converted to higher aliphatic organic acids and that these acids could be readily removed from the fermentation broth by membrane or liquid-liquid extraction. It was then proposed to convert these higher organic acids via Kolbe electrolysis to aliphatic hydrocarbons, which may be used as a diesel fuel. The specific goals for the current porgram are: (1) establish conditions under which substrates other than marine algae may be converted in good yield to organic acids, here the primary task is methane suppression; (2) modify the current 300-liter fixed packed bed batch fermenter to operate in a continuous mode; (3) change from membrane extraction of organic acids to liquid-liquid extraction; (4) optimize the energy balance of the electrolytic oxidation process, the primary task is to reduce the working potential required for the electrolysis while maintaining an adequate current density; (5) scale the entire process up to match the output of the 300 liter fermenter; and (6) design pilot plant and commercial size plant (1000 tons/day) processes for converting biomass to liquid hydrocarbon fuels and perform an economic analysis for the 1000 ton/day design.

  14. Combustion modelling of a fuel oil flame; Modelisation de la combustion d`une flamme de fuel

    Energy Technology Data Exchange (ETDEWEB)

    Flour, I.; Mechitouan, N.

    1996-10-01

    The combustion modelling of a fuel oil flame has been realised in the scope of the R and D `Combustion Turbines`. This report presents the results of the 2D simulation of a fuel oil flame (n-octane), at atmospherical pressure, without swirl, realised using the Eulerian two-phase flow software Melodif. This calculation has been defined in collaboration with IFP, using experimental data from the IFRP. The hollow cone spray of liquid fuel is injected in the middle of the combustion chamber, with a co-flowing annular air. The furnace diameter is 2 meter and its length is 6,25 meter. A large recirculation zone is induced by the air flow, and leads to take into account the whole furnace, in order to avoid some problems with the limit conditions at the outlet. This calculation deals with droplets evaporation, gaseous phase combustion and radiation heat transfer. Predictions concerning gaseous axial mean velocity and mean temperature gradient in the flame, are in good agreement with measurements. However the temperature is too low in the peripheral zone of the flow. This is probably due to the fact that heat exchanges at the wall furnace are not correctly represented, because of a lack of detailed limit conditions for the walls. The mean radial velocity is not so well predicted, but this measurement is also quite difficult in a strongly longitudinal flow. The results concerning the dispersed phase will not be compared, because no measurements on the liquid fuel were available. As it has been experimentally observed, the simulation shows that the fuel oil spray quickly evaporates as it enters the combustion chamber. This result allows to propose to use an homogeneous approach (hypothesis of no-slipping between the two phases) in an Eulerian one-phase flow code, in case of a 3D simulation of liquid fuel turbine. (authors)

  15. Aspects of industrial production of solid electrolyte fuel cells (SOFC) by thermal spraying technology; Aspekte industrieller Fertigung von Festelektrolyt-Brennstoffzellen (SOFC) mittels thermischer Beschichtungsverfahren

    Energy Technology Data Exchange (ETDEWEB)

    Weckmann, Hannes

    2010-07-01

    The present thesis deals with measures to optimize the large-volume production of Solid Oxide Fuel Cells (SOFC) based on thermal spraying technology. Based on the well-established Vacuum Plasma Spraying (VPS) at DLR the potential of alternative thermal spraying techniques as well as alternative base materials was investigated in order to deposit SOFC-anode, electrolyte and insulating layers. Production costs, reproducibility and long-term stability of the production process as well as the fuel cell performance were major target criteria. Depending on the parameter set applied when using the cost efficient Atmospheric Plasma Spraying (APS) in combination with Nickel-Graphite as base material a significant improvement of gas permeability and electrical conductivity was achieved in comparison to the VPS sprayed reference anode. The power density of a fuel cell with an APS-Nickel-Graphite anode (184 mW/cm{sup 2}) was slightly better than the performance with a VPS reference anode (159 mW/cm{sup 2}). In comparison to the VPS process, ceramic electrolyte layers of fully stabilized Zirconia (YSZ) with significantly higher gas tightness could be demonstrated when high energy processes such as Low Pressure Plasma Spraying (LPPS). Thin-film Low Pressure Plasma Spraying (LPPS-Thin-film) and High Velocity Oxy Fuel Spraying (HVOF) were applied. The power density of a fuel cell equipped with an HVOF electrolyte was significantly improved to 234 mW/cm{sup 2} as compared to 187 mW/cm{sup 2} with the VPS sprayed reference cell. Further improvement of the power density was achieved with an LPPS-electrolyte (273 mW/cm{sup 2}). HVOF and VPS sprayed layers of pure Spinel in composite with metallic active braze (equivalent to the sealing between individual layers in the fuel cell stack) could exceed the demanded charge transfer resistance of >1 k{omega}cm{sup 2} at 800 C operating temperature only in few cases. When blended base powder of Spinel and Magnesia in combination with the VPS

  16. Numerical investigation to the dual-fuel spray combustion process in an ethanol direct injection plus gasoline port injection (EDI + GPI) engine

    International Nuclear Information System (INIS)

    Huang, Yuhan; Hong, Guang; Huang, Ronghua

    2015-01-01

    Highlights: • A 5D PDF table was used to model the dual-fuel turbulence–chemistry interactions. • The cooling effect of ethanol direct injection (EDI) was examined. • The higher flame speed of ethanol in EDI + GPI increased the thermal efficiency. • The partially premixed combustion in EDI + GPI reduced the combustion temperature. • Ethanol’s low evaporation rate in low temperature led to incomplete combustion. - Abstract: Ethanol direct injection plus gasoline port injection (EDI + GPI) is a new technology to make the use of ethanol fuel more effective and efficient in spark ignition engines. Multi-dimensional computational fluid dynamics modelling was conducted on an EDI + GPI engine in both single and dual fuelled conditions. The in-cylinder flow field was solved in the realizable k−ε turbulence model with detailed engine geometry. The temporal and spatial distributions of the liquid and vapour fuels were simulated with the spray breakup and evaporation models. The combustion process was modelled with the partially premixed combustion concept in which both mixture fraction and progress variable were solved. The three-dimensional and five-dimensional presumed Probability Density Function (PDF) look-up tables were used to model the single-fraction-mixture and two-fraction-mixture turbulence–chemistry interactions respectively. The model was verified by comparing the numerical and experimental results of spray pattern and cylinder pressure. The simulation results showed that the combustion process of EDI + GPI dual-fuelled condition was partially premixed combustion because of the low evaporation rate of ethanol spray in low temperature environment before combustion. Compared with GPI only, the higher flame speed of ethanol fuel contributed to the greater pressure rise rate and maximum cylinder pressure in EDI + GPI condition, which consequently resulted in higher power output and thermal efficiency. The lower adiabatic flame temperature of

  17. Operating a locomotive on liquid methane fuel

    International Nuclear Information System (INIS)

    Stolz, J.L.

    1992-01-01

    This paper reports that several years ago, Burlington Northern Railroad looked into the feasibility of operating a diesel railroad locomotive to also run on compressed natural gas in a dual-fuel mode. Recognizing the large volume of on-board storage required and other limitations of CNG in the application, a program was begun to fuel a locomotive with liquefied natural gas. Because natural gas composition can vary with source and processing, it was considered desirable to use essentially pure liquid methane as the engine fuel. Initial testing results show the locomotive system achieved full diesel-rated power when operating on liquid methane and with equivalent fuel efficiency. Extended testing, including an American Association of Railroad 500-hour durability test, was undertaken to obtain information on engine life, wear rate and lubrication oil life

  18. In-nozzle flow and spray characteristics for mineral diesel, Karanja, and Jatropha biodiesels

    International Nuclear Information System (INIS)

    Agarwal, Avinash Kumar; Som, Sibendu; Shukla, Pravesh Chandra; Goyal, Harsh; Longman, Douglas

    2015-01-01

    Highlights: • In-nozzle flow characterization for biodiesel sprays. • Comparison of experimental spray parameters and nozzle hole simulations. • Effect of Karanja and Jatropha biodiesel on in-nozzle cavitation. • Cavitation formation investigation with diesel and biodiesels. • Nozzle hole outlet fuel velocity profile determination for test fuels. - Abstract: Superior spray behavior of fuels in internal combustion engines lead to improved combustion and emission characteristics therefore it is necessary to investigate fuel spray behavior of new alternative fuels. This study discusses the evolution of the in-nozzle orifice parameters of a numerical simulation and the evolution of spray parameters of fuel spray in a constant-volume spray chamber during an experiment. This study compares mineral diesel, biodiesels (Karanja-and Jatropha-based), and their blends with mineral diesel. The results show that mineral diesel provides superior atomization and evaporation behavior compared to the biodiesel test fuels. Karanja biodiesel provides superior atomization and evaporation characteristics compared to Jatropha biodiesel. The qualitative comparison of simulation and experimental results in tandem shows that nozzle-hole design is a critical parameter for obtaining optimum spray behavior in the engine combustion chamber

  19. Thermal bonding of light water reactor fuel using nonalkaline liquid-metal alloy

    International Nuclear Information System (INIS)

    Wright, R.F.; Tulenko, J.S.; Schoessow, G.J.; Connell, R.G. Jr.; Dubecky, M.A.; Adams, T.

    1996-01-01

    Light water reactor (LWR) fuel performance is limited by thermal and mechanical constraints associated with the design, fabrication, and operation of fuel in a nuclear reactor. A technique is explored that extends fuel performance by thermally bonding LWR fuel with a nonalkaline liquid-metal alloy. Current LWR fuel rod designs consist of enriched uranium oxide fuel pellets enclosed in a zirconium alloy cylindrical clad. The space between the pellets and the clad is filled by an inert gas. Because of the low thermal conductivity of the gas, the gas space thermally insulates the fuel pellets from the reactor coolant outside the fuel rod, elevating the fuel temperatures. Filling the gap between the fuel and clad with a high-conductivity liquid metal thermally bonds the fuel to the cladding and eliminates the large temperature change across the gap while preserving the expansion and pellet-loading capabilities. The application of liquid-bonding techniques to LWR fuel is explored to increase LWR fuel performance and safety. A modified version of the ESCORE fuel performance code (ESBOND) is developed to analyze the in-reactor performance of the liquid-metal-bonded fuel. An assessment of the technical feasibility of this concept for LWR fuel is presented, including the results of research into materials compatibility testing and the predicted lifetime performance of liquid-bonded LWR fuel. The results show that liquid-bonded boiling water reactor peak fuel temperatures are 400 F lower at beginning of life and 200 F lower at end of life compared with conventional fuel

  20. Reduction of spray pressure leads to less emission and better deposition of spray liquid at high-volume spraying in greenhouse tomato

    NARCIS (Netherlands)

    Os, van E.A.; Michielsen, J.M.G.P.; Corver, F.J.M.; Berg, van den J.V.; Bruins, M.A.; Porskamp, H.A.J.; Zande, van de J.C.

    2005-01-01

    In an experimental greenhouse, growing a tomato crop, it was investigated if a reduction in spray pressure could improve the spray result, while, simultaneously, emission to the ground could be reduced. Spray deposition on the leaves and the emission to the ground was evaluated at different spray

  1. High energy-density liquid rocket fuel performance

    Science.gov (United States)

    Rapp, Douglas C.

    1990-01-01

    A fuel performance database of liquid hydrocarbons and aluminum-hydrocarbon fuels was compiled using engine parametrics from the Space Transportation Engine Program as a baseline. Propellant performance parameters are introduced. General hydrocarbon fuel performance trends are discussed with respect to hydrogen-to-carbon ratio and heat of formation. Aluminum-hydrocarbon fuel performance is discussed with respect to aluminum metal loading. Hydrocarbon and aluminum-hydrocarbon fuel performance is presented with respect to fuel density, specific impulse and propellant density specific impulse.

  2. An experimental methodology to quantify the spray cooling event at intermittent spray impact

    International Nuclear Information System (INIS)

    Moreira, Antonio L.N.; Carvalho, Joao; Panao, Miguel R.O.

    2007-01-01

    The present paper describes an experimental methodology devised to study spray cooling with multiple-intermittent sprays as those found in fuel injection systems of spark-ignition and diesel engines, or in dermatologic surgery applications. The spray characteristics and the surface thermal behaviour are measured by combining a two-component phase-Doppler anemometer with fast response surface thermocouples. The hardware allows simultaneous acquisition of Doppler and thermocouple signals which are processed in Matlab to estimate the time-varying heat flux and fluid-dynamic characteristics of the spray during impact. The time resolution of the acquisition system is limited by the data rate of validation of the phase-Doppler anemometer, but it has been shown to be accurate for the characterization of spray-cooling processes with short spurt durations for which the transient period of spray injection plays an important role. The measurements are processed in terms of the instantaneous heat fluxes, from which phase-average values of the boiling curves are obtained. Two of the characteristic parameters used in the thermal analysis of stationary spray cooling events, the critical heat flux (CHF) and Leidenfrost phenomenon, are then inferred in terms of operating conditions of the multiple-intermittent injections, such as the frequency, duration and pressure of injection. An integral method is suggested to describe the overall process of heat transfer, which accounts for the fluid-dynamic heterogeneities induced by multiple and successive droplet interactions within the area of spray impact. The method considers overall boiling curves dependant on the injection conditions and provides an empirical tool to characterize the heat transfer processes on the impact of multiple-intermittent sprays. The methodology is tested in a preliminary study of the effect of injection conditions on the heat removed by a fuel spray striking the back surface of the intake valve as in spark

  3. Liquid-fueled SOFC power sources for transportation

    Science.gov (United States)

    Myles, K. M.; Doshi, R.; Kumar, R.; Krumpelt, M.

    Traditionally, fuel cells have been developed for space or stationary terrestrial applications. As the first commercial 200-kW systems were being introduced by ONSI and Fuji Electric, the potentially much larger, but also more challenging, application in transportation was beginning to be addressed. As a result, fuel cell-powered buses have been designed and built, and R&D programs for fuel cell-powered passenger cars have been initiated. The engineering challenge of eventually replacing the internal combustion engine in buses, trucks, and passenger cars with fuel cell systems is to achieve much higher power densities and much lower costs than obtainable in systems designed for stationary applications. At present, the leading fuel cell candidate for transportation applications is, without question, the polymer electrolyte fuel cell (PEFC). Offering ambient temperature start-up and the potential for a relatively high power density, the polymer technology has attracted the interest of automotive manufacturers worldwide. But the difficulties of fuel handling for the PEFC have led to a growing interest in exploring the prospects for solid oxide fuel cells (SOFCs) operating on liquid fuels for transportation applications. Solid oxide fuel cells are much more compatible with liquid fuels (methanol or other hydrocarbons) and are potentially capable of power densities high enough for vehicular use. Two SOFC options for such use are discussed in this report.

  4. Assessment of the candidate markets for liquid boiler fuels

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-12-01

    Liquid fuels can be produced from coal in a number of indirect and direct liquefaction processes. While indirect coal liquefaction has been proved commercially outside the United States, most attention in this country has focused on the direct liquefaction processes, which include the processes under examination in this report; namely, the Exxon Donor Solvent (EDS), the H-Coal, and the Solvent Refined Coal (SRC) II processes. The objectives of the study were to: compare the boiler fuels of direct coal liquefaction with residual fuel oil (No. 6 fuel oil) including physical characteristics and environmental hazards, such as carcinogenic characteristics and toxic hazard characteristics; determine whether a boiler fuel market would exist for the coal liquefaction products given their physical characteristics and potential environmental hazards; determine the advantages of utilizing methanol as a boiler fuel on a continuous basis in commercial boilers utilizing existing technology; identify the potential regional candidate markets for direct coal liquefaction products as liquid boiler fuels; determine the distributing and handling costs associated with marketing coal liquefaction products as liquid boiler fuels; determine the current regulatory issues associated with the marketing of coal liquefaction products as boiler fuels; and determine and evaluate other institutional issues associated with the marketing of direct coal liquefaction products as boiler fuels.

  5. Impact of buccal glucose spray, liquid sugars and dextrose tablets on the evolution of plasma glucose concentration in healthy persons.

    Science.gov (United States)

    Chlup, Rudolf; Zapletalova, Jana; Peterson, Karolina; Poljakova, Iveta; Lenhartova, Eva; Tancred, Adam; Perera, Russel; Smital, Jan

    2009-09-01

    The purpose of this prospective controlled trial was to assess the efficacy of three commercially available glucose products, (1) buccal glucose spray, (2) liquid sugars, and (3) dextrose tablet, on the evolution of plasma glucose concentration (PG). Sixteen healthy volunteers aged 21.8 +/- 0.78 y (mean +/- SE), BMI 23.5 +/- 0.84 kg/m(2), tested their PG over the course of 3 sets of 4 sessions (S) each: S(0)-control fasting, S(1)-buccal administration of 10 glucose spray-doses (0.84 g of glucose) without swallowing; S(2-) consumption of 1 sachet (13 ml) of liquid sugar (ca. 5.2 g glucose, 5.2 g fructose, 5.2 g sucrose); S(3-) consumption of one dextrose tablet (6 g). PG was tested in finger-prick capillary blood using a personal glucometer Linus at the start, and at 5, 10, 15, 20 and 30 min. The means of 3 respective sessions for each of the 16 subjects were analyzed. The Wilcoxon signed rank test revealed no significant differences between changes in the mean PG at the start vs. 5-minute interval either in control, or any intervention sessions. Analysis of regression coefficients after 30 min compared to the control session, demonstrated an increase in PG with the sachet of liquid sugars (0.068 mmol/l/min, p = 0.001) which was greater than a single dextrose tablet (0.052 mmol/l/min, p = 0.002), but no significant PG increase was found after buccal glucose spray. Liquid sugars or dextrose tablets, but not the buccal glucose spray, are effective means to increase PG within 10 minutes after ingestion.

  6. Iterative inversion of phase-Doppler-anemometry size distributions from sprays of optically inhomogeneous liquids.

    Science.gov (United States)

    Köser, O; Wriedt, T

    1996-05-20

    Using phase Doppler anemometry (PDA) to investigate sprays of optically inhomogeneous liquids leads to blurred measured size distributions. The blurring function is formed by performance of PDA measurements on single-size droplets generated by a piezoelectric droplet generator. To obtain the undistorted droplet-size distributions, a constrained iterative inversion algorithm is applied. The number of iteration steps to achieve the best possible restoration is determined by the use of synthetically generated data that has noise properties similar to the measured histograms. The obtained size distributions are checked by comparison with undistorted measurement results of an atomized optical homogeneous liquid.

  7. [The spectra of a laser-produced plasma source with CO2, O2 and CF4 liquid aerosol spray target].

    Science.gov (United States)

    Ni, Qi-Liang; Chen, Bo

    2008-11-01

    A laser-produced plasma (LPP) source with liquid aerosol spray target and nanosecond laser was developed, based on both soft X-ray radiation metrology and extreme ultraviolet projection lithography (EUVL). The LPP source is composed of a stainless steel solenoid valve whose temperature can be continuously controlled, a Nd : YAG laser with pulse width, working wavelength and pulse energy being 7 ns, 1.064 microm and 1J respectively, and a pulse generator which can synchronously control the valve and the laser. A standard General Valve Corporation series 99 stainless steel solenoid valve with copper gasket seals and a Kel-F poppet are used in order to minimize leakage and poppet deformation during high-pressure cryogenic operation. A close fitting copper cooling jacket surrounds the valve body. The jacket clamps a copper coolant carrying tube 3 mm in diameter, which is fed by an automatically pressurized liquid nitrogen-filled dewar. The valve temperature can be controlled between 77 and 473 K. For sufficiently high backing pressure and low temperature, the valve reservoir gas can undergo a gas-to-liquid phase transition. Upon valve pulsing, the liquid is ejected into a vacuum and breaks up into droplets, which is called liquid aerosol spray target. For the above-mentioned LPP source, firstly, by the use of Cowan program on the basis of non-relativistic quantum mechanics, the authors computed the radiative transition wavelengths and probabilities in soft X-ray region for O4+, O5+, O6+, O7+, F5+, F6+ and F7+ ions which were correspondingly produced from the interaction of the 10(11)-10(12) W x cm(-2) power laser with liquid O2, CO2 and CF4 aerosol spray targets. Secondly, the authors measured the spectra of liquid O2, CO2 and CF4 aerosol spray target LPP sources in the 6-20 nm band for the 8 x 10(11) W x cm(-2) laser irradiance. The measured results were compared with the Cowan calculated results ones, and the radiative transition wavelength and probability for the

  8. Simulating Impacts of Disruptions to Liquid Fuels Infrastructure

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Michael [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Resilience and Regulatory Effects; Corbet, Thomas F. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Policy and Decision Analytics; Baker, Arnold B. [ABB Consulting, Albuquerque, NM (United States); O' Rourke, Julia M. [Univ. of Texas, Austin, TX (United States). Dept. of Mechanical Engineering

    2015-04-01

    This report presents a methodology for estimating the impacts of events that damage or disrupt liquid fuels infrastructure. The impact of a disruption depends on which components of the infrastructure are damaged, the time required for repairs, and the position of the disrupted components in the fuels supply network. Impacts are estimated for seven stressing events in regions of the United States, which were selected to represent a range of disruption types. For most of these events the analysis is carried out using the National Transportation Fuels Model (NTFM) to simulate the system-level liquid fuels sector response. Results are presented for each event, and a brief cross comparison of event simulation results is provided.

  9. Liquid Bio fuels: Vegetable Oils and Bi oethanol

    International Nuclear Information System (INIS)

    Ballesteros, M.; Ballesteros, I.; Oliva, J. M.; Navarro, A. A.

    1998-01-01

    The European energy policy has defined clear objectives to reduce the high dependency on fossil petroleum imports, and to increase the security of sustainable energy supply for the transport sector. Moreover, the European environmental policy is requesting clean fuels that reduce environmental risks. Liquid Bio fuels (vegetable oils and bio ethanol) appear to be in a good position to contribute to achieve these goals expressed by the established objective of European Union to reach for bio fuels a market share of 5% of motor vehicle consumption. This work presents the current state and perspectives of the production and utilisation of liquid fuels from agricultural sources by reviewing agricultural feedstocks for energy sector, conversion technologies and different ways to use bio fuels. Environmental and economical aspects are also briefly analysed. (Author) 10 refs

  10. CHARACTERIZATION OF DIESEL SPRAY IMAGES USING A SHAPE PROCESSING METHODOLOGY

    Directory of Open Access Journals (Sweden)

    Cecile Petit

    2011-05-01

    Full Text Available In Diesel engines, a key element in achieving a clean and efficient combustion process is a proper fuel-air mixing, which is a consequence of the fuel spray development and fuel-air interaction inside the engine combustion chamber. The spray structure and behavior are classically described by the length (penetration and width (angle of the spray plume but these parameters do not give any clue on the geometrical injection center and on the spray symmetry. The purpose of this paper is to find out original tools to characterize the Diesel spray: the virtual spray origin is the geometrical injection center, which may (or may not coincide with the injector axis. Another interesting point is the description of the Diesel spray in terms of symmetry: the spray plume internal and external symmetry characterize the spray and the injector performance. Our approach is first to find out the virtual spray origin: after the image segmentation, the spray is coded with the Freeman code and with an original shape coding from which the moments are derived. The symmetry axes are then computed and the spray plumes are discarded (or not for the virtual spray origin computation, which is derived from a Voronoi diagram. The last step is the internal and external spray plume symmetry characterization thanks to correlation and mathematical distances.

  11. Intermediate Temperature Hybrid Fuel Cell System for the Conversion of Natural to Electricity and Liquid Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Krause, Theodore [Argonne National Lab. (ANL), Argonne, IL (United States)

    2017-11-22

    This goal of this project was to develop a new hybrid fuel cell technology that operates directly on natural gas or biogas to generate electrical energy and to produce ethane or ethylene from methane, the main component of natural gas or biogas, which can be converted to a liquid fuel or high-value chemical using existing process technologies. By taking advantage of the modularity and scalability of fuel cell technology, this combined fuel cell/chemical process technology targets the recovery of stranded natural gas available at the well pad or biogas produced at waste water treatment plants and municipal landfills by converting it to a liquid fuel or chemical. By converting the stranded gas to a liquid fuel or chemical, it can be cost-effectively transported to market thus allowing the stranded natural gas or biogas to be monetized instead of flared, producing CO2, a greenhouse gas, because the volumes produced at these locations are too small to be economically recovered using current gas-to-liquids process technologies.

  12. An Experimental Study on the Macroscopic Spray Characteristics of Biodiesel and Diesel in a Constant Volume Chamber

    Directory of Open Access Journals (Sweden)

    Hongzhan Xie

    2015-06-01

    Full Text Available The objective of this study was to investigate the macroscopic spray characteristics of different 0%–100% blends of biodiesel derived from drainage oil and diesel (BD0, BD20, BD50, BD80, BD100, such as spray tip penetration, average tip velocity at penetration, spray angle, average spray angle, spray evolution process, spray area and spray volume under different injection pressures (60, 70, 80, 90, 100 MPa and ambient pressures (0.1, 0.3, 0.5, 0.7, 0.9 MPa using a common rail system equipped with a constant volume chamber. The characteristic data was extracted from spray images grabbed by a high speed visualization system. The results showed that the ambient pressure and injection pressure had significant effects on the spray characteristics. As the ambient pressure increased, the spray angle increased, while the spray tip penetration and the peak of average tip velocity decreased. As the injection pressure increased, the spray tip penetration, spray angle, spray area and spray volume increased. The increasing blend ratio of biodiesel brought about a shorter spray tip penetration and a smaller spray angle compared with those of diesel. This is due to the comparatively higher viscosity and surface tension of biodiesel, which enhanced the friction effect between fuel and the injector nozzle surface and inhibited the breakup of the liquid jet.

  13. In vitro performance of ceramic coatings obtained by high velocity oxy-fuel spray.

    Science.gov (United States)

    Melero, H; Garcia-Giralt, N; Fernández, J; Díez-Pérez, A; Guilemany, J M

    2014-01-01

    Hydroxyapatite coatings obtained by plasma-spraying have been used for many years to improve biological performance of bone implants, but several studies have drawn attention to the problems arising from high temperatures and the lack of mechanical properties. In this study, plasma-spraying is substituted by high velocity oxy-fuel (HVOF) spray, with lower temperatures reached, and TiO2 is added in low amounts to hydroxyapatite in order to improve the mechanical properties. Four conditions have been tested to evaluate which are those with better biological properties. Viability and proliferation tests, as well as differentiation assays and morphology observation, are performed with human osteoblast cultures onto the studied coatings. The hydroxyapatite-TiO2 coatings maintain good cell viability and proliferation, especially the cases with higher amorphous phase amount and specific surface, and promote excellent differentiation, with a higher ALP amount for these cases than for polystyrene controls. Observation by SEM corroborates this excellent behaviour. In conclusion, these coatings are a good alternative to those used industrially, and an interesting issue would be improving biological behaviour of the worst cases, which in turn show the better mechanical properties.

  14. Electrochemical device for syngas and liquid fuels production

    Energy Technology Data Exchange (ETDEWEB)

    Braun, Robert J.; Becker, William L.; Penev, Michael

    2017-04-25

    The invention relates to methods for creating high value liquid fuels such as gasoline, diesel, jet and alcohols using carbon dioxide and water as the starting raw materials and a system for using the same. These methods combine a novel solid oxide electrolytic cell (SOEC) for the efficient and clean conversion of carbon dioxide and water to hydrogen and carbon monoxide, uniquely integrated with a gas-to-liquid fuels producing method.

  15. Economic Efficiency of Establishing Domestic Production of Synthetic Liquid Fuel

    Directory of Open Access Journals (Sweden)

    Kyzym Mykola O.

    2017-06-01

    Full Text Available The article notes a stable tendency to increasing the oil dependence of Ukraine, which creates a threat to the national economic security, and proves an expediency of establishing domestic production of synthetic liquid fuel. The technical, organizational and economic features of establishing synthetic liquid fuel production in Ukraine are presented. There proved a hypothesis on the expediency of organizing the production of synthetic liquid fuels based on steam-plasma coal gasification technology. The forecast resource cycle of the country until 2020 under conditions of developing this technology is modeled.

  16. Review of the direct thermochemical conversion of lignocellulosic biomass for liquid fuels

    Directory of Open Access Journals (Sweden)

    Jianchun JIANG,Junming XU,Zhanqian SONG

    2015-03-01

    Full Text Available Increased demand for liquid transportation fuels, environmental concerns and depletion of petroleum resources requires the development of efficient conversion technologies for production of second-generation biofuels from non-food resources. Thermochemical approaches hold great potential for conversion of lignocellulosic biomass into liquid fuels. Direct thermochemical processes convert biomass into liquid fuels in one step using heat and catalysts and have many advantages over indirect and biological processes, such as greater feedstock flexibility, integrated conversion of whole biomass, and lower operation costs. Several direct thermochemical processes are employed in the production of liquid biofuels depending on the nature of the feedstock properties: such as fast pyrolysis/liquefaction of lignocellulosic biomass for bio-oil, including upgrading methods, such as catalytic cracking and hydrogenation. Owing to the substantial amount of liquid fuels consumed by vehicular transport, converting biomass into drop-in liquid fuels may reduce the dependence of the fuel market on petroleum-based fuel products. In this review, we also summarize recent progress in technologies for large-scale equipment for direct thermochemical conversion. We focus on the technical aspects critical to commercialization of the technologies for production of liquid fuels from biomass, including feedstock type, cracking catalysts, catalytic cracking mechanisms, catalytic reactors, and biofuel properties. We also discuss future prospects for direct thermochemical conversion in biorefineries for the production of high grade biofuels.

  17. Production costs of liquid fuels from biomass

    International Nuclear Information System (INIS)

    Bridgwater, A.V.; Double, J.M.

    1994-01-01

    This project was undertaken to provide a consistent and thorough review of the full range of processes for producing liquid fuels from biomass to compare both alternative technologies and processes within those technologies in order to identify the most promising opportunities that deserve closer attention. Thermochemical conversion includes both indirect liquefaction through gasification, and direct liquefaction through pyrolysis and liquefaction in pressurized solvents. Biochemical conversion is based on a different set of feedstocks. Both acid and enzyme hydrolysis are included followed by fermentation. The liquid products considered include gasoline and diesel hydrocarbons and conventional alcohol fuels of methanol and ethanol. Results are given both as absolute fuel costs and as a comparison of estimated cost to market price. In terms of absolute fuel costs, thermochemical conversion offers the lowest cost products, with the least complex processes generally having an advantage. Biochemical routes are the least attractive. The most attractive processes from comparing production costs to product values are generally the alcohol fuels which enjoy a higher market value. (author)

  18. The JPL Direct Methanol Liquid-feed PEM Fuel Cell

    Science.gov (United States)

    Halpert, G.; Surampudi, S.

    1994-01-01

    Recently, there has been a breakthrough in fuel cell technology in the Energy Storage Systems Group at the Jet Propulsion Laboratory with the develpment of a direct methanol, liquid-feed, solid polymer electrolyte membrane (PEM) fuel cell... The methanol liquid-feed, solid polymer electrolyte (PEM) design has numerous system level advantages over the gas-feed design. These include:...

  19. Droplet size measurement of diesel fuel spray particles using a planar laser-induced fluorescence method; Nijigen laser yuki keikoho wo mochiita diesel funmu ryushi no ryukei keisoku ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Ishikawa, N. [Isuzu Motors Ltd., Tokyo (Japan); Niimura, K. [Nissan Diesel Motor Co. Ltd., Saitama (Japan); Tsujimura, K.

    1997-11-25

    In this study, the planar laser-induced fluorescence (PLIF) technique was used to measure the mean size and size distribution of diesel spray particles. The fuel used was n-tridecane mixed with 1 wt% N, N, Nprime, Nprime-tetramethylparaphenyenediamine (TMPD). The light source used to excite the TMPD in the fuel was a secondary harmonic of a ruby laser-light sheet. A highly magnified image of the fluorescence from TMPD was taken by a 35 mm still camera with magnified optics, and the mean particle size and particle size distribution of the fuel spray were determined by processing the images of fuel particles printed on paper. First, the accuracy of this method was confirmed by comparison with results of Phase Doppler Anemometry for fuel spray of an air-assisted gasoline injector. Then, for the diesel spray, the effects of injection velocity, ambient pressure, geometric configuration of nozzle hole (i.e., nozzle hole diameter and nozzle hole L/D) and of measurement points on the fuel particle mean size and size distribution in a high-pressure vessel at atmospheric temperature were investigated. The results showed that the small size particles increase in number with increasing injection velocity. At higher injection velocity, seem to atomize more actively. With increasing ambient pressure, the mean particle size increases. A reduction in nozzle diameter resulted in no improvement of atomization in this study. Also, the mean particle size in the downstream region of the spray is larger than that in the upstream region of the spray. 16 refs., 19 figs., 3 tabs.

  20. Large-Eddy Simulations of Reacting Liquid Spray

    Science.gov (United States)

    Lederlin, Thomas; Sanjose, Marlene; Gicquel, Laurent; Cuenot, Benedicte; Pitsch, Heinz; Poinsot, Thierry

    2008-11-01

    Numerical simulation, which is commonly used in many stages of aero-engine design, still has to demonstrate its predictive capability for two-phase reacting flows. This study is a collaboration between Stanford University and CERFACS to perform LES of a realistic spray combustor installed at ONERA, Toulouse. The experimental configuration is computed on the same unstructured mesh with two different solvers: Stanford's CDP code and CERFACS's AVBP code. CDP uses a low-Mach, variable-density solver with implicit time advancement. Droplets are tracked in a Lagrangian point-particle framework. The combustion model uses a flamelet approach, based on two transported scalars, mixture fraction and reaction progress variable. AVBP is a fully compressible solver with explicit time advancement. The liquid phase is described with an Eulerian method. The flame-turbulence interaction is modeled using a dynamically-thickened flame. Results are compared with experimental data for three regimes: purely gaseous non-reacting flow, non-reacting flow with evaporating droplets, reacting flow with droplets. Both simulations show a good agreement with experimental data and also stress the difference and relative advantages of the numerical methods.

  1. Drying grain using a hydrothermally treated liquid lignite fuel

    Energy Technology Data Exchange (ETDEWEB)

    Bukurov, Z.; Cvijanovic, P.; Bukurov, M. [Univ. of Novi Sad (Yugoslavia); Ljubicic, B.R. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-01

    A shortage of domestic oil and natural gas resources in Yugoslavia, particularly for agricultural and industrial purposes, has motivated the authors to explore the possibility of using liquid lignite as an alternate fuel for drying grain. This paper presents a technical and economic assessment of the possibility of retrofitting grain-drying plants currently fueled by oil or natural gas to liquid lignite fuel. All estimates are based on lignite taken from the Kovin deposit. Proposed technology includes underwater mining techniques, aqueous ash removal, hydrothermal processing, solids concentration, pipeline transport up to 120 km, and liquid lignite direct combustion. For the characterization of Kovin lignite, standard ASTM procedures were used: proximate, ultimate, ash, heating value, and Theological analyses were performed. Results from an extensive economic analysis indicate a delivered cost of US$20/ton for the liquid lignite. For the 70 of the grain-drying plants in the province of Vojvodina, this would mean a total yearly saving of about US $2,500,000. The advantages of this concept are obvious: easy to transport and store, nonflammable, nonexplosive, nontoxic, 30%-40% cheaper than imported oil and gas, domestic fuel is at hand. The authors believe that liquid lignite, rather than an alternative, is becoming more and more an imperative.

  2. Nontoxic Ionic Liquid Fuels for Exploration Applications

    Science.gov (United States)

    Coil, Millicent

    2015-01-01

    The toxicity of propellants used in conventional propulsion systems increases not only safety risks to personnel but also costs, due to special handling required during the entire lifetime of the propellants. Orbital Technologies Corporation (ORBITEC) has developed and tested novel nontoxic ionic liquid fuels for propulsion applications. In Phase I of the project, the company demonstrated the feasibility of several ionic liquid formulations that equaled the performance of conventional rocket propellant monomethylhydrazine (MMH) and also provided low volatility and low toxicity. In Phase II, ORBITEC refined the formulations, conducted material property tests, and investigated combustion behavior in droplet and microreactor experiments. The company also explored the effect of injector design on performance and demonstrated the fuels in a small-scale thruster. The ultimate goal is to replace propellants such as MMH with fuels that are simultaneously high-performance and nontoxic. The fuels will have uses in NASA's propulsion applications and also in a range of military and commercial functions.

  3. Predicting the Liquid Lengths of Heavy Hydrogen Fuels

    National Research Council Canada - National Science Library

    Hoogterp, Laura L

    2003-01-01

    .... Using models formulated by previous researchers as well as the thermodynamic properties for three fuel surrogates the liquid length can be determined for diesel fuel, JP8 as well as provide a model...

  4. Advancing liquid metal reactor technology with nitride fuels

    International Nuclear Information System (INIS)

    Lyon, W.F.; Baker, R.B.; Leggett, R.D.; Matthews, R.B.

    1991-08-01

    A review of the use of nitride fuels in liquid metal fast reactors is presented. Past studies indicate that both uranium nitride and uranium/plutonium nitride possess characteristics that may offer enhanced performance, particularly in the area of passive safety. To further quantify these effects, the analysis of a mixed-nitride fuel system utilizing the geometry and power level of the US Advanced Liquid Metal Reactor as a reference is described. 18 refs., 2 figs., 2 tabs

  5. Spray combustion of biomass-based renewable diesel fuel using multiple injection strategy in a constant volume combustion chamber

    KAUST Repository

    Jing, Wei; Wu, Zengyang; Roberts, William L.; Fang, Tiegang

    2016-01-01

    Effect of a two-injection strategy associated with a pilot injection on the spray combustion process was investigated under conventional diesel combustion conditions (1000 K and 21% O2 concentration) for a biomass-based renewable diesel fuel, i

  6. Inactivation of Burkholderia pseudomallei on environmental surfaces using spray-applied, common liquid disinfectants.

    Science.gov (United States)

    Calfee, M W; Wendling, M

    2015-11-01

    Five commercially available liquid antimicrobials were evaluated for their ability to decontaminate common environmental surface materials, contaminated with Burkholderia pseudomallei, using a spray-based disinfectant delivery procedure. Tests were conducted at both an ambient temperature (c. 20°C) and a lower temperature (c. 12°C) condition. Nonporous materials (glass and aluminium) were more easily decontaminated than porous materials (wood, concrete and carpet). Citric acid (1%) demonstrated poor efficacy in all test conditions. Bleach (pH-adjusted), ethanol (70%), quaternary ammonium and PineSol®, demonstrated high (>6 log10 reduction) efficacies on glass and aluminium at both temperatures, but achieved varying results for wood, carpet and concrete. Temperature had minimal effect on decontamination efficacy during these tests. Much of the antimicrobial efficacy data for pathogenic micro-organisms are generated with testing that utilizes hard nonporous surface materials. These data are not directly translatable for decontaminant selection following an incident whereby complex and porous environmental surfaces are contaminated. This study presents efficacy data for spray-applied antimicrobial liquids, when used to decontaminate common environmental surfaces contaminated with Burkholderia pseudomallei. These data can help responders develop effective remediation strategies following an environmental contamination incident involving B. pseudomallei. Published 2015. This article is a U.S. Government work and is in the public domain in the USA.

  7. Numerical studies of spray combustion processes of palm oil biodiesel and diesel fuels using reduced chemical kinetic mechanisms

    KAUST Repository

    Kuti, Olawole; Sarathy, Mani; Nishida, Keiya; Roberts, William L.

    2014-01-01

    Spray combustion processes of palm oil biodiesel (PO) and conventional diesel fuels were simulated using the CONVERGE CFD code. Thermochemical and reaction kinetic data (115 species and 460 reactions) by Luo et al. (2012) and Lu et al. (2009) (68

  8. Electrochemical performance of solid oxide fuel cells having electrolytes made by suspension and solution precursor plasma spraying

    Science.gov (United States)

    Marr, M.; Kuhn, J.; Metcalfe, C.; Harris, J.; Kesler, O.

    2014-01-01

    Yttria-stabilized zirconia (YSZ) electrolytes were deposited by suspension plasma spraying (SPS) and solution precursor plasma spraying (SPPS). The electrolytes were evaluated for permeability, microstructure, and electrochemical performance. With SPS, three different suspensions were tested to explore the influence of powder size distribution and liquid properties. Electrolytes made from suspensions of a powder with d50 = 2.6 μm were more gas-tight than those made from suspensions of a powder with d50 = 0.6 μm. A peak open circuit voltage of 1.00 V was measured at 750 °C with a cell with an electrolyte made from a suspension of d50 = 2.6 μm powder. The use of a flammable suspension liquid was beneficial for improving electrolyte conductivity when using lower energy plasmas, but the choice of liquid was less important when using higher energy plasmas. With SPPS, peak electrolyte conductivities were comparable to the peak conductivities of the SPS electrolytes. However, leak rates through the SPPS electrolytes were higher than those through the electrolytes made from suspensions of d50 = 2.6 μm powder. The electrochemical test data on SPPS electrolytes are the first reported in the literature.

  9. A new method for spray deposit assessment

    Science.gov (United States)

    Chester M. Himel; Leland Vaughn; Raymond P. Miskus; Arthur D. Moore

    1965-01-01

    Solid fluorescent particles suspended in a spray liquid are distributed in direct proportion to the size of the spray droplets. Use of solid fluorescent particles is the basis of a new method for visual recognition of the size and number of droplets impinging on target and nontarget portions of sprayed areas.

  10. A Review on Empirical Correlations for Jet/Spray Trajectory of Liquid Jet in Uniform Cross Flow

    Directory of Open Access Journals (Sweden)

    Soo-Young No

    2015-12-01

    Full Text Available The empirical correlations for the prediction of jet/spray penetration of liquid jet in subsonic uniform crossflow are reviewed in this study. Considerable number of empirical correlations had been proposed by many investigators. It has generally known that the jet/spray trajectory of a liquid jet in a cross-flow is a function of the liquid to air momentum flux ratio and the normalized distance in the airstream direction from the injector. However, several researchers incorporated the Weber number, liquid-to-water or air viscosity ratio, pressure ratio or Reynolds number, temperature ratio in the empirical correlations. Two different classification methods of correlations, i.e. classification based on mathematic functional form and classification based on flow regime, are introduced in this study. The one classification of existing correlations based on functional form includes correlations in a power-law, logarithmic, and exponential forms, respectively. The other classification of previous correlations based on flow regime includes one, two and three regime, correlations. Correlations in a power-law functional form can be further divided into three groups such as momentum flux ratio, Weber number and other parameters forms. Correlations in logarithmic functional form can be also grouped as momentum flux ratio and Weber number forms. Most of the evaluation studies reported the significant discrepancies of predicted values by the existing correlations. The possible reasons for discrepancies will be summarized as measurement technique, assumptions made in defining terms in the liquid to air momentum flux ratio, difficulties in defining the boundaries of the liquid jets, turbulence level in the core and boundary layer of incoming jet and gas flows, nozzle/injector geometry and its position in the crossflow. However, it can be found from the several evaluation studies that the power-law functional form with momentum flux ratio and two regimes

  11. Electrolyte creepage barrier for liquid electrolyte fuel cells

    Science.gov (United States)

    Li, Jian [Alberta, CA; Farooque, Mohammad [Danbury, CT; Yuh, Chao-Yi [New Milford, CT

    2008-01-22

    A dielectric assembly for electrically insulating a manifold or other component from a liquid electrolyte fuel cell stack wherein the dielectric assembly includes a substantially impermeable dielectric member over which electrolyte is able to flow and a barrier adjacent the dielectric member and having a porosity of less than 50% and greater than 10% so that the barrier is able to measurably absorb and chemically react with the liquid electrolyte flowing on the dielectric member to form solid products which are stable in the liquid electrolyte. In this way, the barrier inhibits flow or creepage of electrolyte from the dielectric member to the manifold or component to be electrically insulated from the fuel cell stack by the dielectric assembly.

  12. 26 CFR 48.4041-7 - Dual use of taxable liquid fuel.

    Science.gov (United States)

    2010-04-01

    ... taxable liquid fuel. Tax applies to all taxable liquid fuel sold for use or used as a fuel in the motor which is used to propel a diesel-powered vehicle or in the motor used to propel a motor vehicle... vehicle, motorboat, or aircraft. Thus, if the motor of a diesel-powered highway vehicle or a motorboat...

  13. Gas-to-liquids synthetic fuels for use in fuel cells : reformability, energy density, and infrastructure compatibility.

    Energy Technology Data Exchange (ETDEWEB)

    Ahmed, S.; Kopasz, J. P.; Russell, B. J.; Tomlinson, H. L.

    1999-09-08

    The fuel cell has many potential applications, from power sources for electric hybrid vehicles to small power plants for commercial buildings. The choice of fuel will be critical to the pace of its commercialization. This paper reviews the various liquid fuels being considered as an alternative to direct hydrogen gas for the fuel cell application, presents calculations of the hydrogen and carbon dioxide yields from autothermal reforming of candidate liquid fuels, and reports the product gas composition measured from the autothermal reforming of a synthetic fuel in a micro-reactor. The hydrogen yield for a synthetic paraffin fuel produced by a cobalt-based Fischer-Tropsch process was found to be similar to that of retail gasoline. The advantages of the synthetic fuel are that it contains no contaminants that would poison the fuel cell catalyst, is relatively benign to the environment, and could be transported in the existing fuel distribution system.

  14. Fuel gas production by microwave plasma in liquid

    International Nuclear Information System (INIS)

    Nomura, Shinfuku; Toyota, Hiromichi; Tawara, Michinaga; Yamashita, Hiroshi; Matsumoto, Kenya

    2006-01-01

    We propose to apply plasma in liquid to replace gas-phase plasma because we expect much higher reaction rates for the chemical deposition of plasma in liquid than for chemical vapor deposition. A reactor for producing microwave plasma in a liquid could produce plasma in hydrocarbon liquids and waste oils. Generated gases consist of up to 81% hydrogen by volume. We confirmed that fuel gases such as methane and ethylene can be produced by microwave plasma in liquid

  15. Sulphur in liquid fuels 2002

    Energy Technology Data Exchange (ETDEWEB)

    Guthrie, J. [Environment Canada, Gatineau, PQ (Canada). Fuels Div., Oil, Gas and Energy Branch ; Sabourin, R. [Carleton Univ., Ottawa, ON (Canada)

    2003-08-01

    Environment Canada has developed new regulations for sulphur content in fuels in an effort to align with requirements recently passed by the U.S. Environmental Protection Agency. This report summarizes data regarding sulphur content in liquid fuels for the year 2002. The requirements of the Sulphur in Gasoline Regulation came into effect in 2002, limiting the average sulphur content of gasoline to 150 mg/kg. In January 2005, a 30 mg/kg average limit will come into effect. Also, in July 2002, the Sulphur in Diesel Fuel Regulation stipulated a maximum limit of 500 mg/kg for on-road diesel fuel. The new regulation continues this limit until mid-2006 at which time a 15 mg/kg limit will come into effect for on-road diesel fuel. Nationally, the average sulphur content in gasoline in 2002 was 246 mg/kg, which was 14.3 per cent lower than in 2001. The data covers the period from January 1 to December 31, 2002 and was obtained from petroleum refineries and importing companies that are required to submit quarterly information to the regional office of Environment Canada. Failure to comply results in penalties. The report includes data for aviation turbo fuel, motor gasoline, aviation gasoline, kerosene oil, low-sulphur diesel fuel, diesel fuel, light fuel oil, and heavy fuel oil. 16 tabs., 17 figs., 7 appendices.

  16. Interior flow and near-nozzle spray development in a marine-engine diesel fuel injector

    Science.gov (United States)

    Hult, J.; Simmank, P.; Matlok, S.; Mayer, S.; Falgout, Z.; Linne, M.

    2016-04-01

    A consolidated effort at optically characterising flow patterns, in-nozzle cavitation, and near-nozzle jet structure of a marine diesel fuel injector is presented. A combination of several optical techniques was employed to fully transparent injector models, compound metal-glass and full metal injectors. They were all based on a common real-scale dual nozzle hole geometry for a marine two-stroke diesel engine. In a stationary flow rig, flow velocities in the sac-volume and nozzle holes were measured using PIV, and in-nozzle cavitation visualized using high-resolution shadowgraphs. The effect of varying cavitation number was studied and results compared to CFD predictions. In-nozzle cavitation and near-nozzle jet structure during transient operation were visualized simultaneously, using high-speed imaging in an atmospheric pressure spray rig. Near-nozzle spray formation was investigated using ballistic imaging. Finally, the injector geometry was tested on a full-scale marine diesel engine, where the dynamics of near-nozzle jet development was visualized using high-speed shadowgraphy. The range of studies focused on a single common geometry allows a comprehensive survey of phenomena ranging from first inception of cavitation under well-controlled flow conditions to fuel jet structure at real engine conditions.

  17. Liquid fuels from biomass in Europe

    Energy Technology Data Exchange (ETDEWEB)

    Coombs, J.

    1984-03-01

    The incorporation of solar energy into plant material through photosynthesis has the advantage that the energy is stored in a fixed form which is relatively stable, but the disadvantage is that plant biomass is not immediately compatible with the use in internal combustion engines to provide motive power. However, by choice of suitable crops, conversion technologies and engine modification it is possible to produce biomassderived liquid transport fuels; either substitutes for petroleum in the form of alcohols or replacements for diesel fuel in the form of vegetable oils or their esters. Using more complex conversion technologies it is also possible to produce hydrocarbon mixtures similar to petroleum. Some of these methodologies are available on a farm or commercial scale now; some are still at the research and development or demonstration stage, whereas others remain speculative. The purpose of this paper is to consider the present state of the art in respect of the production of liquid transport fuels from biomass and to indicate how the various possibilities might fit with present and future energy needs in the European Community.

  18. ROTARY SPRAY DUSTER

    Directory of Open Access Journals (Sweden)

    E. S. Nechaeva

    2013-01-01

    Full Text Available Results of researches of hydraulic resistance, ablation of splashes and efficiency of dedusting in the rotor spray dust collector are given. Influence of frequency of rotation of the spray, the specified speed of gas and diameter of spattering holes on hydraulic resistance, size ablation of splashes and efficiency of a dedusting the device by diameter 0,25 m is investigated. As model liquid water is used. Results of mathematical processing are presented.

  19. Parameters of electrostatic spraying and its influence on the application efficiency

    Directory of Open Access Journals (Sweden)

    Robson Shigueaki Sasaki

    2013-08-01

    Full Text Available When the electrostatic spraying is used correctly, it provides advantages over conventional systems, however many factors can affect the system efficiency. Therefore, the objective of this study was to evaluate the charge/mass ratio (Q/M at different spraying distances (0, 1, 2, 3, 4 and 5 m, and the liquid deposition efficiency on the target. Evaluating the Q/M ratio the Faraday cage method was used and to evaluate the liquid deposition efficiency the artificial targets were positioned longitudinally and transversely to the spray jet. It was found that the spraying distance affects the Q/M ratio, consequently, the liquid deposition efficiency. For the closest distance to the target the Q/M ratio was 4.11 mC kg-1, and at distances of 1, 2, 3, 4 and 5 m, the ratio decreased to 1.38, 0.64, 0.31, 0.17 and 0.005 mC kg-1, respectively. For the liquid deposition, the electrostatic system was affected by the target orientation and spraying distance. The target transversely to the jet of liquid did not improve the liquid deposition, but longitudinally increased the deposition up to 3 meters of distance.

  20. Effect of substrate and cathode parameters on the properties of suspension plasma sprayed solid oxide fuel cell electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Waldbillig, D.; Tang, Z.; Burgess, A. [British Columbia Univ., Vancouver, BC (Canada); Kesler, O. [Toronto Univ., ON (Canada)

    2008-07-01

    An axial injection suspension plasma spray system has been used to produce layers of fully stabilized yttriastabilized zirconia (YSZ) that could be used as solid oxide fuel cell (SOFC) electrolytes. Suspension plasma spraying is a promising technique for the rapid production of coatings with fine microstructures and controlled porosity without requiring a post-deposition heat treatment. This new manufacturing technique to produce SOFC active layers requires the build up of a number of different plasma sprayed SOFC functional layers (cathode, electrolyte and anode) sequentially on top of each other. To understand the influence of the substrate and previouslydeposited coating layers on subsequent coating layer properties, YSZ layers were deposited on top of plasma sprayed composite lanthanum strontium manganite (LSM)/YSZ cathode layers that were first deposited on porous ferritic stainless steel substrates. Three layer half cells consisting of the porous steel substrate, composite cathode, and suspension plasma sprayed electrolyte layer were then characterized. A systematic study was performed in order to investigate the effect of parameters such as substrate and cathode layer roughness, substrate surface pore size, and cathode microstructure and thickness on electrolyte deposition efficiency, cathode and electrolyte permeability, and layer microstructure. (orig.)

  1. Numerical simulation of the flow field and fuel sprays in an IC engine

    Science.gov (United States)

    Nguyen, H. L.; Schock, H. J.; Ramos, J. I.; Carpenter, M. H.; Stegeman, J. D.

    1987-01-01

    A two-dimensional model for axisymmetric piston-cylinder configurations is developed to study the flow field in two-stroke direct-injection Diesel engines under motored conditions. The model accounts for turbulence by a two-equation model for the turbulence kinetic energy and its rate of dissipation. A discrete droplet model is used to simulate the fuel spray, and the effects of the gas phase turbulence on the droplets is considered. It is shown that a fluctuating velocity can be added to the mean droplet velocity every time step if the step is small enough. Good agreement with experimental data is found for a range of ambient pressures in Diesel engine-type microenvironments. The effects of the intake swirl angle in the spray penetration, vaporization, and mixing in a uniflow-scavenged two-stroke Diesel engine are analyzed. It is found that the swirl increases the gas phase turbulence levels and the rates of vaporization.

  2. Modeling the Spray Forming of H13 Steel Tooling

    Science.gov (United States)

    Lin, Yaojun; McHugh, Kevin M.; Zhou, Yizhang; Lavernia, Enrique J.

    2007-07-01

    On the basis of a numerical model, the temperature and liquid fraction of spray-formed H13 tool steel are calculated as a function of time. Results show that a preheated substrate at the appropriate temperature can lead to very low porosity by increasing the liquid fraction in the deposited steel. The calculated cooling rate can lead to a microstructure consisting of martensite, lower bainite, retained austenite, and proeutectoid carbides in as-spray-formed material. In the temperature range between the solidus and liquidus temperatures, the calculated temperature of the spray-formed material increases with increasing substrate preheat temperature, resulting in a very low porosity by increasing the liquid fraction of the deposited steel. In the temperature region where austenite decomposition occurs, the substrate preheat temperature has a negligible influence on the cooling rate of the spray-formed material. On the basis of the calculated results, it is possible to generate sufficient liquid fraction during spray forming by using a high growth rate of the deposit without preheating the substrate, and the growth rate of the deposit has almost no influence on the cooling rate in the temperature region of austenite decomposition.

  3. Computational Analysis of Spray Jet Flames

    Science.gov (United States)

    Jain, Utsav

    There is a boost in the utilization of renewable sources of energy but because of high energy density applications, combustion will never be obsolete. Spray combustion is a type of multiphase combustion which has tremendous engineering applications in different fields, varying from energy conversion devices to rocket propulsion system. Developing accurate computational models for turbulent spray combustion is vital for improving the design of combustors and making them energy efficient. Flamelet models have been extensively used for gas phase combustion because of their relatively low computational cost to model the turbulence-chemistry interaction using a low dimensional manifold approach. This framework is designed for gas phase non-premixed combustion and its implementation is not very straight forward for multiphase and multi-regime combustion such as spray combustion. This is because of the use of a conserved scalar and various flamelet related assumptions. Mixture fraction has been popularly employed as a conserved scalar and hence used to parameterize the characteristics of gaseous flamelets. However, for spray combustion, the mixture fraction is not monotonic and does not give a unique mapping in order to parameterize the structure of spray flames. In order to develop a flamelet type model for spray flames, a new variable called the mixing variable is introduced which acts as an ideal conserved scalar and takes into account the convection and evaporation of fuel droplets. In addition to the conserved scalar, it has been observed that though gaseous flamelets can be characterized by the conserved scalar and its dissipation, this might not be true for spray flamelets. Droplet dynamics has a significant influence on the spray flamelet and because of effects such as flame penetration of droplets and oscillation of droplets across the stagnation plane, it becomes important to accommodate their influence in the flamelet formulation. In order to recognize the

  4. A technical review of liquid/liquid and solid/liquid separation equipment in the field of nuclear-fuel reprocessing

    International Nuclear Information System (INIS)

    Vassallo, G.

    1981-01-01

    Liquid/liquid extraction is generally accepted as the preferred method in nuclear-fuel reprocessing. However, although many types of liquid/liquid contactors are available, only a few meet the stringent specifications set by the nuclear industry. This report discusses the criteria for contactor selection and then reviews the most important types, namely packed columns, pulsed columns, mixer-setters and centrifugal contactors. Finally, a short section concerned with solid/liquid separations is included because of the possible deleterious effects caused by solids in liquid/liquid contactors

  5. Near infra-red chemical species tomography of sprays of volatile hydrocarbons

    Energy Technology Data Exchange (ETDEWEB)

    Hindle, F.P.; Carey, S.J.; Ozanyan, K.B.; McCann, H. [Dept. of Electrical Engineering and Electronics, UMIST, Manchester (United Kingdom); Winterbone, D.E.; Clough, E. [Dept. of Mechanical, Aerospace and Mfg. Engineering, UMIST, Manchester (United Kingdom)

    2002-08-01

    We report an All-Opto-Electronic tomography system that is sensitive to hydrocarbon vapour distribution, or liquid spray distribution, with temporal resolution of over 3000 frames per second. A tomography system comprising 32 channels has been built and tested. For chemical sensitivity to saturated hydrocarbons, we exploit the principle of Near Infra-Red (NIR) absorption at 1700 nm relative to a reference wavelength, using laser diode sources whose technology is based on that of the communications industry. Images are obtained from a laboratory set-up incorporating both gaseous injection and a liquid Gasoline Direct Injection (GDI) system. The performance of a prototype system on a running GDI engine is reported. The difficulty in performing concentration measurements of the gaseous fuel within the liquid spray region is shown, and means to improve this performance are discussed. However, it has been found possible to image the liquid spray cone using attenuation of the reference beam. These images correlate well with other techniques [1]. (orig.) [German] Wir berichten ueber ein optoelektronisches Tomographiesystem zur Bestimmung der Verteilung von Kohlenwasserstoffdaempfen oder von Spraypartikeln, das eine hohe zeitliche Aufloesung von 3000 Aufnahmen pro Sekunde liefert. Ein System mit 32 Kanaelen wurde gebaut und getestet. Um Empfindichkeit auf gesaettigte Kohlenwasserstoffdaempfe zu erzielen, wurde die Absorption im Nahen Infrarot (NIR) bei 1700 nm, bezogen auf die bei einer Referenzwellen-laenge, genutzt. Laserdioden, deren Technologien auch in der Kommunikationstechnik Verwendung finden, kamen zum Einsatz. Von einem Laboraufbau wurden Bilder aufgenommen sowohl bei Injektion von Gas als auch bei Direkteinspritzung fluessigen Brennstoffs (GDI). Wir berichten ueber die Ergebnisse mit dem Prototyp-Messsystem an einem GDI-Motor. Es werden die Schwierigkeiten gezeigt, Messungen der Gaskonzentration innerhalb eines Spraypartikelbereichs durchzufuehren, und

  6. Engineering a new class of thermal spray nano-based microstructures from agglomerated nanostructured particles, suspensions and solutions: an invited review

    Science.gov (United States)

    Fauchais, P.; Montavon, G.; Lima, R. S.; Marple, B. R.

    2011-03-01

    From the pioneering works of McPherson in 1973 who identified nanometre-sized features in thermal spray conventional alumina coatings (using sprayed particles in the tens of micrometres size range) to the most recent and most advanced work aimed at manufacturing nanostructured coatings from nanometre-sized feedstock particles, the thermal spray community has been involved with nanometre-sized features and feedstock for more than 30 years. Both the development of feedstock (especially through cryo-milling, and processes able to manufacture coatings structured at the sub-micrometre or nanometre sizes, such as micrometre-sized agglomerates made of nanometre-sized particles for feedstock) and the emergence of thermal spray processes such as suspension and liquid precursor thermal spray techniques have been driven by the need to manufacture coatings with enhanced properties. These techniques result in two different types of coatings: on the one hand, those with a so-called bimodal structure having nanometre-sized zones embedded within micrometre ones, for which the spray process is similar to that of conventional coatings and on the other hand, sub-micrometre or nanostructured coatings achieved by suspension or solution spraying. Compared with suspension spraying, solution precursor spraying uses molecularly mixed precursors as liquids, avoiding a separate processing route for the preparation of powders and enabling the synthesis of a wide range of oxide powders and coatings. Such coatings are intended for use in various applications ranging from improved thermal barrier layers and wear-resistant surfaces to thin solid electrolytes for solid oxide fuel cell systems, among other numerous applications. Meanwhile these processes are more complex to operate since they are more sensitive to parameter variations compared with conventional thermal spray processes. Progress in this area has resulted from the unique combination of modelling activities, the evolution of

  7. Environmental Life Cycle Assessment of Coal-Biomass to Liquid Jet Fuel Compared to Petroleum-Derived JP-8 Jet Fuel

    Science.gov (United States)

    2010-03-01

    is a Metal Deactivator Additive (MDA) to prevent fuel oxidation with trace metals such as copper or zinc that may be in the jet fuel (MIL- HDBK-510-1...react in the FT synthesis process). The gasifier is of the slagging type and a direct contact water quench spray system is used to cool the syngas...exiting the gasifier. The quench also removes particulate matter and contaminants not removed in the slag . However, because the ash from biomass is

  8. High liquid fuel yielding biofuel processes and a roadmap for the future transportation

    Science.gov (United States)

    Singh, Navneet R.

    In a fossil-fuel deprived world when crude oil will be scarce and transportation need cannot be met with electricity and transportation liquid fuel must be produced, biomass derived liquid fuels can be a natural replacement. However, the carbon efficiency of the currently known biomass to liquid fuel conversion processes ranges from 35-40%, yielding 90 ethanol gallon equivalents (ege) per ton of biomass. This coupled with the fact that the efficiency at which solar energy is captured by biomass (hydrodeoxygenation is proposed which can achieve liquid fuel yield of 215 ege/ton consuming 0.11 kg hydrogen per liter of oil. Due to the lower hydrogen consumption of the H2Bioil process, synergistically integrated transition pathways are feasible where hot syngas derived from coal gasification (H2Bioil-C) or a natural gas reformer (H 2Bioil-NG) is used to supply the hydrogen and process heat for the biomass fast-hydropyrolysis/hydrodeoxygenation. Another off-shoot of the H2Bioil process is the H2Bioil-B process, where hydrogen required for the hydropyrolysis is obtained from gasification of a fraction of the biomass. H2Bioil-B achieves the highest liquid fuel yield (126-146 ege/ton of biomass) reported in the literature for any self-contained conversion of biomass to biofuel. Finally, an integration of the H2Bioil process with the H2CAR process is suggested which can achieve 100% carbon efficiency (330 ege/ton of biomass) at the expense of 0.24 kg hydrogen/liter of oil. A sun-to-fuel efficiency analysis shows that extracting CO2 from air and converting it to liquid fuel is at least two times more efficient than growing dedicated fuel crops and converting them to liquid fuel even for the highest biomass growth rates feasible by algae. This implies that liquid fuel should preferably be produced from sustainably available waste (SAW) biomass first and if the SAW biomass is unable to meet the demand for liquid fuel, then, CO2 should be extracted from air and converted to

  9. Novel design for transparent high-pressure fuel injector nozzles

    Science.gov (United States)

    Falgout, Z.; Linne, M.

    2016-08-01

    The efficiency and emissions of internal combustion (IC) engines are closely tied to the formation of the combustible air-fuel mixture. Direct-injection engines have become more common due to their increased practical flexibility and efficiency, and sprays dominate mixture formation in these engines. Spray formation, or rather the transition from a cylindrical liquid jet to a field of isolated droplets, is not completely understood. However, it is known that nozzle orifice flow and cavitation have an important effect on the formation of fuel injector sprays, even if the exact details of this effect remain unknown. A number of studies in recent years have used injectors with optically transparent nozzles (OTN) to allow observation of the nozzle orifice flow. Our goal in this work is to design various OTN concepts that mimic the flow inside commercial injector nozzles, at realistic fuel pressures, and yet still allow access to the very near nozzle region of the spray so that interior flow structure can be correlated with primary breakup dynamics. This goal has not been achieved until now because interior structures can be very complex, and the most appropriate optical materials are brittle and easily fractured by realistic fuel pressures. An OTN design that achieves realistic injection pressures and grants visual access to the interior flow and spray formation will be explained in detail. The design uses an acrylic nozzle, which is ideal for imaging the interior flow. This nozzle is supported from the outside with sapphire clamps, which reduces tensile stresses in the nozzle and increases the nozzle's injection pressure capacity. An ensemble of nozzles were mechanically tested to prove this design concept.

  10. Fabrication of copper-based anodes via atmosphoric plasma spraying techniques

    Science.gov (United States)

    Lu, Chun [Monroeville, PA

    2012-04-24

    A fuel electrode anode (18) for a solid oxide fuel cell is made by presenting a solid oxide fuel cell having an electrolyte surface (15), mixing copper powder with solid oxide electrolyte in a mixing step (24, 44) to provide a spray feedstock (30,50) which is fed into a plasma jet (32, 52) of a plasma torch to melt the spray feed stock and propel it onto an electrolyte surface (34, 54) where the spray feed stock flattens into lamellae layer upon solidification, where the layer (38, 59) is an anode coating with greater than 35 vol. % based on solids volume.

  11. Spent fuel pool spray cooling system for the AP1000 {sup registered}

    Energy Technology Data Exchange (ETDEWEB)

    Vujic, Zoran; Sassen, Felix; Tietsch, Wolfgang [Westinghouse Electric Germany GmbH, Mannheim (Germany)

    2013-07-01

    The AP1000 {sup registered} plant design features multiple, diverse lines of defense to ensure spent fuel cooling can be maintained for Design Basis Events and Beyond Design Basis Accidents (BDBA). The AP1000 {sup registered} plant lines of defense with respect to Spent Fuel Pool (SFP) cooling are as follows: 1. During normal and abnormal conditions, defense-in-depth and duty systems provide highly reliable SFP cooling, supplied by offsite AC power or the onsite Standby Diesel Generators. 2. For unlikely events with extended loss of AC power (i.e. station black-out) and/or loss of heat sink, spent fuel cooling can be still provided indefinitely by: 2a. Passive systems, requiring minimal or no operator actions, sufficient for at least 72 hours under all possible loading conditions. 2b. After 3 days, several different means are provided to continue SFP cooling using installed plant equipment as well as off-site equipment with built-in connections. 3. Even for BDBA with postulated SFP damage and multiple failures in the passive safety-related systems and in the defense-in-depth active systems, the AP1000 {sup registered} SFP Spray System provides an additional line of defense to prevent spent fuel damage. (orig.)

  12. Research on electrostatic electrification during jet kerosene spraying

    International Nuclear Information System (INIS)

    Liu, Quanzhen; Li, Yipeng; Zhang, Wentian; Sun, Keping

    2013-01-01

    Multiple electrostatic electrifications during aircraft fuelling process may cause a fire disaster or explosion, so study on the protection measure for electrostatic electrification is very important for the security of aircraft fuelling. This paper investigated the electrostatic voltage and charge of the fuel nozzle and metal parts during the fuel spraying by self-designed jet kerosene spraying electrostatic electrification test system. The experimental results indicate that the voltage on the fuel nozzle and metal parts is very dangerous for electrostatic safety if they are not reliably grounded.

  13. An Overview of Spray Modeling With OpenNCC and its Application to Emissions Predictions of a LDI Combustor at High Pressure

    Science.gov (United States)

    Raju, M. S.

    2016-01-01

    The open national combustion code (Open- NCC) is developed with the aim of advancing the current multi-dimensional computational tools used in the design of advanced technology combustors. In this paper we provide an overview of the spray module, LSPRAY-V, developed as a part of this effort. The spray solver is mainly designed to predict the flow, thermal, and transport properties of a rapidly evaporating multi-component liquid spray. The modeling approach is applicable over a wide-range of evaporating conditions (normal, superheat, and supercritical). The modeling approach is based on several well-established atomization, vaporization, and wall/droplet impingement models. It facilitates large-scale combustor computations through the use of massively parallel computers with the ability to perform the computations on either structured & unstructured grids. The spray module has a multi-liquid and multi-injector capability, and can be used in the calculation of both steady and unsteady computations. We conclude the paper by providing the results for a reacting spray generated by a single injector element with 600 axially swept swirler vanes. It is a configuration based on the next-generation lean-direct injection (LDI) combustor concept. The results include comparisons for both combustor exit temperature and EINOX at three different fuel/air ratios.

  14. Failure analysis of thermally cycled columnar thermal barrier coatings produced by high-velocity-air fuel and axial-suspension-plasma spraying: A design perspective

    Czech Academy of Sciences Publication Activity Database

    Ganvir, A.; Vaidhyanathan, V.; Markocsan, N.; Gupta, M.; Pala, Zdeněk; Lukáč, František

    2018-01-01

    Roč. 44, č. 3 (2018), s. 3161-3172 ISSN 0272-8842 Institutional support: RVO:61389021 Keywords : Columnar Thermal Barrier Coatings * Axial Suspension Plasma spraying * Thermal Cyclic Fatigue * High Velocity Air Fuel Spraying Subject RIV: JK - Corrosion ; Surface Treatment of Materials OBOR OECD: Coating and films Impact factor: 2.986, year: 2016 https://www.sciencedirect.com/science/article/pii/S0272884217325403

  15. Sequential cryogen spraying for heat flux control at the skin surface

    Science.gov (United States)

    Majaron, Boris; Aguilar, Guillermo; Basinger, Brooke; Randeberg, Lise L.; Svaasand, Lars O.; Lavernia, Enrique J.; Nelson, J. Stuart

    2001-05-01

    Heat transfer rate at the skin-air interface is of critical importance for the benefits of cryogen spray cooling in combination with laser therapy of shallow subsurface skin lesions, such as port-wine stain birthmarks. With some cryogen spray devices, a layer of liquid cryogen builds up on the skin surface during the spurt, which may impair heat transfer across the skin surface due to relatively low thermal conductivity and potentially higher temperature of the liquid cryogen layer as compared to the spray droplets. While the mass flux of cryogen delivery can be adjusted by varying the atomizing nozzle geometry, this may strongly affect other spray properties, such as lateral spread (cone), droplet size, velocity, and temperature distribution. We present here first experiments with sequential cryogen spraying, which may enable accurate mass flux control through variation of spray duty cycle, while minimally affecting other spray characteristics. The observed increase of cooling rate and efficiency at moderate duty cycle levels supports the above described hypothesis of isolating liquid layer, and demonstrates a novel approach to optimization of cryogen spray devices for individual laser dermatological applications.

  16. Numerical simulation of fuel sprays and combustion in a premixed lean diesel engine; Kihaku yokongo diesel kikan ni okeru nenryo funmu to nensho no suchi simulation

    Energy Technology Data Exchange (ETDEWEB)

    Miyamoto, T; Harada, A; Sasaki, S; Shimazaki, N; Hashizume, T; Akagawa, H; Tsujimura, K

    1997-10-01

    Fuel sprays and combustion in a direct injection Premixed lean Diesel Combustion (PREDIC) engine, which can make smokeless combustion with little NOx emission, is studied numerically. Numerical simulation was carried out by means of KIVA II based computer code with a combustion submodel. The combustion submodel describes the formation of combustible fuel vapor by turbulent mixing and four-step chemical reaction which includes low temperature oxidation. Comparison between computation and experiment shows qualitatively good agreement in terms of heat release rate and NO emission. Computational results indicate that the combustion is significantly influenced by fuel spray characteristics and injection timing to vary NO emission. 10 refs., 8 figs., 1 tab.

  17. Liquid fuel from biomass

    International Nuclear Information System (INIS)

    Breinholt, T.; Gylling, M.; Parsby, M.; Meyer Henius, U.; Sander Nielsen, B.

    1992-09-01

    Various options for Danish production of liquid motor fuels from biomass have been studied in the context of the impact of EEC new common agricultural policy on prices and production quantities of crops, processes and production economy, restraints concerning present and future markets in Denmark, environmental aspects, in particular substitution of fossil fuels in the overall production and end-use, revenue loss required to assure competition with fossil fuels and national competence in business, industry and research. The options studied are rapeseed oil and derivates, ethanol, methanol and other thermo-chemical conversion products. The study shows that the combination of fuel production and co-generation of heat and electricity carried out with energy efficiency and utilization of surplus electricity is important for the economics under Danish conditions. Considering all aspects, ethanol production seems most favorable but in the long term, pyrolyses with catalytic cracking could be an interesting option. The cheapest source of biomass in Denmark is straw, where a considerable amount of the surplus could be used. Whole crop harvested wheat on land otherwise set aside to be fallow could also be an important source for ethanol production. Most of the options contribute favorably to reductions of fossil fuel consumption, but variations are large and the substitution factor is to a great extent dependent on the individual case. (AB) (32 refs.)

  18. Numerical Modeling of Diesel Spray Formation and Combustion

    NARCIS (Netherlands)

    Bekdemir, C.; Somers, L.M.T.; Goey, de L.P.H.

    2009-01-01

    A study is presented on the modeling of fuel sprays in diesel engines. The objective of this study is in the first place to accurately and efficiently model non-reacting diesel spray formation, and secondly to include ignition and combustion. For that an efficient 1D Euler-Euler spray model [21] is

  19. First results of the delayed fluorescence velocimetry as applied to diesel spray diagnostics

    Science.gov (United States)

    Megahed, M.; Roosen, P.

    1993-08-01

    One of the main parameters governing diesel spray formation is the fuel's velocity just beneath the nozzle. The high density of the injected liquid within the first few millimeters under the injector prohibits accurate measurements of this velocity. The liquid's velocity in this region has been mainly measured using intrusive methods and has been numerically calculated without considering the complex flow fields in the nozzle. A new optical method based on laser induced delayed fluorescence allowing the measurement of the fuel's velocity close to the nozzle is reported. The results are accurate to about 14% and represent the velocities of heavy oils within the first 2 - 5 mm beneath the nozzle. The development of the velocity over the injection period showed a drastic deceleration of the fuel within the first 3 mm beneath the nozzle. This is assumed to be due to the complex interaction of cavitation in the injection hole and pressure waves in the injection system which causes the start of atomization in the nozzle hole.

  20. Absorption/desorption in sprays

    International Nuclear Information System (INIS)

    Naimpally, A.

    1987-01-01

    This survey paper shall seek to present the present state of knowledge concerning absorption and desorption in spray chambers. The first part of the paper presents the theories and formulas for the atomization and break-up of sprays in nozzles. Formulas for the average (sauter-mean) diameters are then presented. For the case of absorption processes, the formulas for the dimensionless mass transfer coefficients is in drops. The total; mass transfer is the total of the transfer in individual drops. For the case of desorption of sparingly soluble gases from liquids in a spray chamber, the mass transfer occurs in the spray just at the point of break-up of the jet. Formulas for the desorption of gases are presented

  1. High pressure combustion of liquid fuels. [alcohol and n-paraffin fuels

    Science.gov (United States)

    Canada, G. S.

    1974-01-01

    Measurements were made of the burning rates and liquid surface temperatures for a number of alcohol and n-paraffin fuels under natural and forced convection conditions. Porous spheres ranging in size from 0.64-1.9 cm O.D. were emloyed to simulate the fuel droplets. The natural convection cold gas tests considered the combustion in air of methanol, ethanol, propanol-1, n-pentane, n-heptane, and n-decane droplets at pressures up to 78 atmospheres. The pressure levels of the natural convection tests were high enough so that near critical combustion was observed for methanol and ethanol vaporization rates and liquid surface temperature measurements were made of droplets burning in a simulated combustion chamber environment. Ambient oxygen molar concentrations included 13%, 9.5% and pure evaporation. Fuels used in the forced convection atmospheric tests included those listed above for the natural convection tests. The ambient gas temperature ranged from 600 to 1500 K and the Reynolds number varied from 30 to 300. The high pressure forced convection tests employed ethanol and n-heptane as fuels over a pressure range of one to 40 atmospheres. The ambient gas temperature was 1145 K for the two combustion cases and 1255 K for the evaporation case.

  2. Development and validation of spray models for investigating diesel engine combustion and emissions

    Science.gov (United States)

    Som, Sibendu

    Diesel engines intrinsically generate NOx and particulate matter which need to be reduced significantly in order to comply with the increasingly stringent regulations worldwide. This motivates the diesel engine manufacturers to gain fundamental understanding of the spray and combustion processes so as to optimize these processes and reduce engine emissions. Strategies being investigated to reduce engine's raw emissions include advancements in fuel injection systems, efficient nozzle orifice design, injection and combustion control strategies, exhaust gas recirculation, use of alternative fuels such as biodiesel etc. This thesis explores several of these approaches (such as nozzle orifice design, injection control strategy, and biodiesel use) by performing computer modeling of diesel engine processes. Fuel atomization characteristics are known to have a significant effect on the combustion and emission processes in diesel engines. Primary fuel atomization is induced by aerodynamics in the near nozzle region as well as cavitation and turbulence from the injector nozzle. The breakup models that are currently used in diesel engine simulations generally consider aerodynamically induced breakup using the Kelvin-Helmholtz (KH) instability model, but do not account for inner nozzle flow effects. An improved primary breakup (KH-ACT) model incorporating cavitation and turbulence effects along with aerodynamically induced breakup is developed and incorporated in the computational fluid dynamics code CONVERGE. The spray simulations using KH-ACT model are "quasi-dynamically" coupled with inner nozzle flow (using FLUENT) computations. This presents a novel tool to capture the influence of inner nozzle flow effects such as cavitation and turbulence on spray, combustion, and emission processes. Extensive validation is performed against the non-evaporating spray data from Argonne National Laboratory. Performance of the KH and KH-ACT models is compared against the evaporating and

  3. Spray and Combustion Characteristics of a Novel Multi-circular Jet Plate in Air-assisted Atomizer

    Directory of Open Access Journals (Sweden)

    Hisham Amirnordin Shahrin

    2017-01-01

    Full Text Available Atomization of liquid fuel in air-assisted atomizer is highly dependent on air mixing, which can be enhanced using turbulent generators, such as multi-circular jet (MCJ plates and swirler. This study aims to determine the effects of novel MCJ plates on the spray and combustion characteristics of an air-assisted atomizer by evaluating spray and flame parameters, such as penetration length, cone angle, and cone area. MCJ 30 and MCJ 45, with inclined jets at 30° and 45°, respectively, were used in the experiment. A swirler was also used for comparison. The spray and flame images were recorded at different equivalence ratios through direct photography and analyzed using image J software. Flame temperature was determined using a thermal infrared camera, and burning chamber and flue gas temperatures were measured using thermocouples. The spray and flame characteristics of MCJ 30 exhibited performance comparable with those of the MCJ 45 and swirler. The integration of turbulence and swirling motion concept into the novel MCJ plates can enhance the mixing formation and thus improve the performance of burner combustion.

  4. Wetted foam liquid fuel ICF target experiments

    International Nuclear Information System (INIS)

    Olson, R E; Leeper, R J; Yi, S A; Kline, J L; Zylstra, A B; Peterson, R R; Shah, R; Braun, T; Biener, J; Kozioziemski, B J; Sater, J D; Biener, M M; Hamza, A V; Nikroo, A; Hopkins, L Berzak; Ho, D; LePape, S; Meezan, N B

    2016-01-01

    We are developing a new NIF experimental platform that employs wetted foam liquid fuel layer ICF capsules. We will use the liquid fuel layer capsules in a NIF sub-scale experimental campaign to explore the relationship between hot spot convergence ratio (CR) and the predictability of hot spot formation. DT liquid layer ICF capsules allow for flexibility in hot spot CR via the adjustment of the initial cryogenic capsule temperature and, hence, DT vapor density. Our hypothesis is that the predictive capability of hot spot formation is robust and 1D-like for a relatively low CR hot spot (CR∼15), but will become less reliable as hot spot CR is increased to CR>20. Simulations indicate that backing off on hot spot CR is an excellent way to reduce capsule instability growth and to improve robustness to low-mode x-ray flux asymmetries. In the initial experiments, we will test our hypothesis by measuring hot spot size, neutron yield, ion temperature, and burn width to infer hot spot pressure and compare to predictions for implosions with hot spot CR's in the range of 12 to 25. Larger scale experiments are also being designed, and we will advance from sub-scale to full-scale NIF experiments to determine if 1D-like behavior at low CR is retained as the scale-size is increased. The long-term objective is to develop a liquid fuel layer ICF capsule platform with robust thermonuclear burn, modest CR, and significant α-heating with burn propagation. (paper)

  5. Conversion of Mixed Plastic Wastes (High Density Polyethylene and Polypropylene) into Liquid Fuel

    International Nuclear Information System (INIS)

    Chaw Su Su Hmwe; Tint Tint Kywe; Moe Moe Kyaw

    2010-12-01

    In this study, mixed plastic wastes were converted into liquid fuels. Mixed plastic wastes used were high density polyethylene (HDPE) and polypropylene (PP). The pyrolysis of mixed plastic waste to liquid fuel was carried out with and without prepared zeolite catalyst.The catalyst was characterized by X-ray Diffraction (XRD). This catalyst was pre-treated for activation. The experiments were carried out at temperature range of 350-410C.Physical properties (density, kinematic, viscosity,refractive index)of prepared liquid fuel samples were measured. From this study, yields of liquid fuel and gas fuel were found to be 41-64% and 15-35% respectively. As for by products, char was obtained as the yield percentages from 9 to 14% and wax (yield% - 1 to 14) was formed during pyrolysis.

  6. Effect of fuel temperature on the methanol spray and nozzle internal flow

    International Nuclear Information System (INIS)

    Chen, Zhifang; Yao, Anren; Yao, Chunde; Yin, Zenghui; Xu, Han; Geng, Peilin; Dou, Zhancheng; Hu, Jiangtao; Wu, Taoyang; Ma, Ming

    2017-01-01

    Highlights: • Cavitation region increases with the increasing of methanol temperature. • The nozzle exit velocity increases with the increasing of methanol temperature. • The discharge coefficient decreases with the increasing of methanol temperature. • Droplet SMD reduces when methanol temperature increases measured by PDPA system. • Droplet velocity has the maximum value when methanol temperature is 60 °C. - Abstract: The increasing of fuel temperature can reduce the droplet size and have an advantage of improving spray atomization, while investigations of the effect of temperature on the methanol injector internal flow and external spray is rare. Firstly, a detailed three dimensional numerical simulations of nozzle internal flow have been conducted to probe into the cavitation in methanol injector nozzles, and then an experimental study has been carried out to investigate the droplet size and velocity of methanol spray at various temperatures using the Phase Doppler Particle Analyzer (PDPA) detecting system. And results show that the region of cavitations in nozzle orifice enlarges as methanol temperature and injection pressure increases, and the temperature for 'super-cavitation' occurring decreases gradually with the increasing of injection pressure. Moreover, the nozzle exit velocity, discharge coefficient and cavitations number were also analyzed. However, the discharge coefficient reduces nearly equal under various pressure when the methanol temperature is higher than 60 °C. In addition, the Sauter Mean Diameter (SMD) and velocity of methanol droplet were also analyzed, and found that the droplet velocity reaches the maximum value when the methanol temperature is 60 °C.

  7. Two-stroke engine with gaseous and liquid fuel injection

    Energy Technology Data Exchange (ETDEWEB)

    Laursen, Rene Sejer [MAN Diesel and Turbo SE, Copenhagen (Denmark)

    2012-08-15

    The need to lower emissions of CO{sub 2}, NO{sub x}, SO{sub x} and particulates as well as rising oil prices have increased engine operators' interest in alternative fuels and fuel flexibility. The low speed two-stroke ME-GI and ME-LGI dual-fuel engines with diesel pilot injection from MAN Diesel and Turbo offer the opportunity of utilising fuels such as LNG, LPG, and methanol in a wide range of liquid to gaseous fuel ratios. (orig.)

  8. Metal-deactivating additives for liquid fuels

    Energy Technology Data Exchange (ETDEWEB)

    Boneva, M.I. [Institute of Organic Chemistry, Sofia (Bulgaria); Ivanov, S.K.; Kalitchin, Z.D. [SciBulCom, Ltd., Sofia (Bulgaria); Tanielyan, S.K. [Seton Hall Univ., South Orange, NJ (United States); Terebenina, A.; Todorova, O.I. [Institute of Inorganic Chemistry, Sofia (Bulgaria)

    1995-05-01

    The metal-deactivating and the antioxidant properties of 1-phenyl-3-methylpyrazolone-5 derivatives have been investigated both in the model reaction of low temperature oxidation of ethylbenzene and in gasoline oxidation. The study of the ability of these derivatives to reduce the catalytic effect of copper naphthenate demonstrates that they are promising as metal deactivating additives for light fuels. Some of the pyrazolone compounds appear to be of special interest for the long-term storage of liquid fuels due to their action as multifunctional inhibitors.

  9. Engineering a new class of thermal spray nano-based microstructures from agglomerated nanostructured particles, suspensions and solutions: an invited review

    International Nuclear Information System (INIS)

    Fauchais, P; Montavon, G; Lima, R S; Marple, B R

    2011-01-01

    From the pioneering works of McPherson in 1973 who identified nanometre-sized features in thermal spray conventional alumina coatings (using sprayed particles in the tens of micrometres size range) to the most recent and most advanced work aimed at manufacturing nanostructured coatings from nanometre-sized feedstock particles, the thermal spray community has been involved with nanometre-sized features and feedstock for more than 30 years. Both the development of feedstock (especially through cryo-milling, and processes able to manufacture coatings structured at the sub-micrometre or nanometre sizes, such as micrometre-sized agglomerates made of nanometre-sized particles for feedstock) and the emergence of thermal spray processes such as suspension and liquid precursor thermal spray techniques have been driven by the need to manufacture coatings with enhanced properties. These techniques result in two different types of coatings: on the one hand, those with a so-called bimodal structure having nanometre-sized zones embedded within micrometre ones, for which the spray process is similar to that of conventional coatings and on the other hand, sub-micrometre or nanostructured coatings achieved by suspension or solution spraying. Compared with suspension spraying, solution precursor spraying uses molecularly mixed precursors as liquids, avoiding a separate processing route for the preparation of powders and enabling the synthesis of a wide range of oxide powders and coatings. Such coatings are intended for use in various applications ranging from improved thermal barrier layers and wear-resistant surfaces to thin solid electrolytes for solid oxide fuel cell systems, among other numerous applications. Meanwhile these processes are more complex to operate since they are more sensitive to parameter variations compared with conventional thermal spray processes. Progress in this area has resulted from the unique combination of modelling activities, the evolution of

  10. Influence of narrow fuel spray angle and split injection strategies on combustion efficiency and engine performance in a common rail direct injection diesel engine

    Directory of Open Access Journals (Sweden)

    Raouf Mobasheri

    2017-03-01

    Full Text Available Direct injection diesel engines have been widely used in transportation and stationary power systems because of their inherent high thermal efficiency. On the other hand, emission regulations such as NOx and particulates have become more stringent from the standpoint of preserving the environment in recent years. In this study, previous results of multiple injection strategies have been further investigated to analyze the effects of narrow fuel spray angle on optimum multiple injection schemes in a heavy duty common rail direct injection diesel engine. An advanced computational fluid dynamics simulation has been carried out on a Caterpillar 3401 diesel engine for a conventional part load condition in 1600 r/min at two exhaust gas recirculation rates. A good agreement of calculated and measured in-cylinder pressure, heat release rate and pollutant formation trends was obtained under various operating points. Three different included spray angles have been studied in comparison with the traditional spray injection angle. The results show that spray targeting is very effective for controlling the in-cylinder mixture distributions especially when it accompanied with various injection strategies. It was found that the optimum engine performance for simultaneous reduction of soot and NOx emissions was achieved with 105° included spray angle along with an optimized split injection strategy. The results show, in this case, the fuel spray impinges at the edge of the piston bowl and a counterclockwise flow motion is generated that pushes mixture toward the center of the piston bowl.

  11. Mechanisms of spray formation and combustion from a multi-hole injector with E85 and gasoline

    Energy Technology Data Exchange (ETDEWEB)

    Aleiferis, P.G.; Serras-Pereira, J.; van Romunde, Z. [Department of Mechanical Engineering, University College London (United Kingdom); Caine, J. [Ford Motor Company, Dunton Engineering Centre (United Kingdom); Wirth, M. [Ford Werke GmbH, Merkenich, Cologne (Germany)

    2010-04-15

    The spray formation and combustion characteristics of gasoline and E85 (85% ethanol, 15% gasoline) have been investigated using a multi-hole injector with asymmetric nozzle-hole arrangement. Experiments were carried out in a quiescent optical chamber using high-speed shadowgraphy (9 kHz) to characterise the spray sensitivity to both injector temperature and ambient pressure in the range of 20-120 C and 0.5, 1.0 bar. Spray-tip penetrations and 'umbrella' spray cone angles were calculated for all conditions. Phase Doppler Anemometry was also used to measure droplet sizes in the core of one of the spray plumes, 25 mm below the injector tip. To study the effect of fuel properties on vaporisation and mixture preparation under realistic operating conditions, a separate set of experiments was carried out in a direct-injection spark-ignition optical engine. The engine was run at 1500 RPM under cold and fully warmed-up conditions (20 C and 90 C) at part load and full load (0.5 and 1.0 bar intake pressure). Floodlit laser Mie-scattering images of the sprays on two orthogonal planes corresponding to the swirl and tumble planes of in-cylinder flow motion were acquired to study the full injection event and post-injection mixing stage. These were used to make comparisons with the static chamber sprays and to quantify the liquid-to-vapour phase evaporation process for both fuels by calculating the projected 'footprint' of the sprays at different conditions. Analysis of the macroscopic structure and turbulent primary break-up properties of the sprays was undertaken in light of jet exit conditions described in terms of non-dimensional numbers. The effects on stoichiometric combustion were investigated by imaging the natural flame chemiluminescence through the engine's piston crown (swirl plane) and by post-processing to derive flame growth rates and trajectories of flame motion. (author)

  12. Solid oxide fuel cell electrolytes produced via very low pressure suspension plasma spray and electrophoretic deposition

    Science.gov (United States)

    Fleetwood, James D.

    Solid oxide fuel cells (SOFCs) are a promising element of comprehensive energy policies due to their direct mechanism for converting the oxidization of fuel, such as hydrogen, into electrical energy. Both very low pressure plasma spray and electrophoretic deposition allow working with high melting temperature SOFC suspension based feedstock on complex surfaces, such as in non-planar SOFC designs. Dense, thin electrolytes of ideal composition for SOFCs can be fabricated with each of these processes, while compositional control is achieved with dissolved dopant compounds that are incorporated into the coating during deposition. In the work reported, sub-micron 8 mole % Y2O3-ZrO2 (YSZ) and gadolinia-doped ceria (GDC), powders, including those in suspension with scandium-nitrate dopants, were deposited on NiO-YSZ anodes, via very low pressure suspension plasma spray (VLPSPS) at Sandia National Laboratories' Thermal Spray Research Laboratory and electrophoretic deposition (EPD) at Purdue University. Plasma spray was carried out in a chamber held at 320 - 1300 Pa, with the plasma composed of argon, hydrogen, and helium. EPD was characterized utilizing constant current deposition at 10 mm electrode separation, with deposits sintered from 1300 -- 1500 °C for 2 hours. The role of suspension constituents in EPD was analyzed based on a parametric study of powder loading, powder specific surface area, polyvinyl butyral (PVB) content, polyethyleneimine (PEI) content, and acetic acid content. Increasing PVB content and reduction of particle specific surface area were found to eliminate the formation of cracks when drying. PEI and acetic acid content were used to control suspension stability and the adhesion of deposits. Additionally, EPD was used to fabricate YSZ/GDC bilayer electrolyte systems. The resultant YSZ electrolytes were 2-27 microns thick and up to 97% dense. Electrolyte performance as part of a SOFC system with screen printed LSCF cathodes was evaluated with peak

  13. Current Status of Superheat Spray Modeling With NCC

    Science.gov (United States)

    Raju, M. S.; Bulzan, Dan L.

    2012-01-01

    An understanding of liquid fuel behavior at superheat conditions is identified to be a topic of importance in the design of modern supersonic engines. As a part of the NASA's supersonics project office initiative on high altitude emissions, we have undertaken an effort to assess the accuracy of various existing CFD models used in the modeling of superheated sprays. As a part of this investigation, we have completed the implementation of a modeling approach into the national combustion code (NCC), and then applied it to investigate the following three cases: (1) the validation of a flashing jet generated by the sudden release of pressurized R134A from a cylindrical nozzle, (2) the differences between two superheat vaporization models were studied based on both hot and cold flow calculations of a Parker-Hannifin pressure swirl atomizer, (3) the spray characteristics generated by a single-element LDI (Lean Direct Injector) experiment were studied to investigate the differences between superheat and non-superheat conditions. Further details can be found in the paper.

  14. Iron Oxide Doped Alumina-Zirconia Nanoparticle Synthesis by Liquid Flame Spray from Metal Organic Precursors

    OpenAIRE

    Juha-Pekka Nikkanen; Helmi Keskinen; Mikko Aromaa; Mikael Järn; Tomi Kanerva; Erkki Levänen; Jyrki M. Mäkelä; Tapio Mäntylä

    2008-01-01

    The liquid flame spray (LFS) method was used to make iron oxide doped alumina-zirconia nanoparticles. Nanoparticles were generated using a turbulent, high-temperature (Tmax⁡∼3000 K) H2-O2 flame. The precursors were aluminium-isopropoxide, zirconium-n-propoxide, and ferrocene in xylene solution. The solution was atomized into micron-sized droplets by high velocity H2 flow and introduced into the flame where nanoparticles were formed. The particle morphology, size, phase, and chemical compositi...

  15. Liquid-Feed Methanol Fuel Cell With Membrane Electrolyte

    Science.gov (United States)

    Surampudi, Subbarao; Narayanan, S. R.; Halpert, Gerald; Frank, Harvey; Vamos, Eugene

    1995-01-01

    Fuel cell generates electricity from direct liquid feed stream of methanol/water solution circulated in contact with anode, plus direct gaseous feed stream of air or oxygen in contact with cathode. Advantages include relative simplicity and elimination of corrosive electrolytic solutions. Offers potential for reductions in size, weight, and complexity, and for increases in safety of fuel-cell systems.

  16. A phenomenological model of two-phase (air/fuel droplet developing and breakup

    Directory of Open Access Journals (Sweden)

    Pavlović Radomir R.

    2013-01-01

    Full Text Available Effervescent atomization namely the air-filled liquid atomization comprehends certain complex two-phase phenomenon that are difficult to be modeled. Just a few researchers have found the mathematical expressions for description of the complex atomization model of the two-phase mixture air/diesel fuel. In the following review, developing model of twophase (air/fuel droplet of Cummins spray pump-injector is shown. The assumption of the same diameters of the droplet and the opening of the atomizer is made, while the air/fuel mass ratio inside the droplet varies.

  17. Rewetting of a hot metallic wall by liquid spray

    International Nuclear Information System (INIS)

    Castiglia, F.; Giardina, M.; Lombardo, C.

    2005-01-01

    Full text of publication follows: Rewetting is the re-establishment of liquid in contact with a hot dried surface, whose initial temperature is higher than the so-called 'rewetting temperature'. This phenomenology is of interest in many industrial processes, for example: in metallurgical quenching, in electronic equipments cooling, in cryogenic processes, in preserving the integrity of toxic and dangerous substances metallic containers endangered by a hypothetical fire. Moreover it is essential for the re-establishment of normal and safe temperature levels following rod cluster dryout or hypothesized loss of coolant accidents (LOCAs) in nuclear reactors. In spite of the large amount of experimental and theoretical work done in the past decades, the above depicted phenomenology still deserves further clarifications and deepening. For this reason, recently at the Institute of Energetic Thermal-Fluid Dynamics of ENEA (Ente per le Nuove Tecnologie, l'Energia e l'Ambiente, at Casaccia, Italy), experimental researches have been carried out on the rewetting of vertical surfaces, at ambient pressure and various water flow rates by spraying subcooled water at the top. Spraying devices of various configuration, able to supply water drops of uniform diameter, have been used [1]. As it is known when, following the drops impact in some region at the top of the surface the temperature is lowered below the rewetting temperature, a liquid falling film forms, the front of which advances with a velocity ( the so called 'rewetting velocity'), limited by the rapidity by which the heat is conducted into the solid (conduction controlled rewetting). In the past, about the rewetting the researchers of Department of Nuclear Engineering of the University of Palermo have carried out an extensive theoretical work and more recently, have proposed a semi-theoretical model which proved successful in correlating a lot of experimental data [2]. This model has been suitably modified in order to

  18. Concept of a subcritical transmutation system with fast neutron spectrum and liquid fuel

    International Nuclear Information System (INIS)

    Tittelbach, S.

    2002-11-01

    The annual amount of nearly 9500 t of spent fuel from worldwide industrial nuclear energy utilization has to be disposed as high level waste. The retention of nuclear waste from the biosphere has to be assured until the radiological risk decreases to tolerable levels. The long-term radiological risk of spent fuel is dominated by actinide elements, i.e. plutonium, americium and curium. It is intended to reduce this amount of high level waste by Partitioning and Transmutation, so that the radiotoxicity of the disposed waste falls short of the reference value of fresh fuel decaying naturally after about thousand years. For this time period the retention of high level waste can be assured by technical means. The scope of this work is the design of a subcritical fast transmutation system with liquid metal cooling and liquid metal fuel. The lead bismuth eutectic has been choosen as the liquid metal coolant and fuel carrier. To dissolve at least 3 at% of transuran elements, a minimum fuel temperature of 600 C is required. The calculations were carried out with a fuel composition, which results from two plutonium recycling steps in a thorium fuel cycle. Two homogeneous and two heterogeneous blankets have been designed and evaluated leading to one preferred heterogeneous blanket design, which has been investigated in more detail. This blanket design merges the positive properties of a solid fuel system (better control of fuel and reactivity because of smaller and closed fuel volumina) and a liquid fuel system (continous charge and discharge or extraction of fission products). The blanket design is based on the core design of fast breeder liquid metal reactors. It consists of hexagonal fuel elements housing up to six annular shaped fuel cylinders. The hexagonal shape of the fuel elements leads to three fuel zones positioned concentrically around the central spallation target. There is a strong heterogeneous distribution of power and heat flux in this blanket design. Besides

  19. Unsupervised Anomaly Detection for Liquid-Fueled Rocket Prop...

    Data.gov (United States)

    National Aeronautics and Space Administration — Title: Unsupervised Anomaly Detection for Liquid-Fueled Rocket Propulsion Health Monitoring. Abstract: This article describes the results of applying four...

  20. Experimental and numerical investigations on spray characteristics of fatty acid methyl esters.

    Science.gov (United States)

    Lanjekar, R D; Deshmukh, D

    2018-02-01

    A comparative experimental and numerical study is conducted to establish the significance of the use of single-component over multi-component representatives of biodiesel, diesel and their blend for predicting spray tip penetration. Methyl oleate and methyl laurate are used as single-component representative fuels for biodiesel. The pure components n -heptane, n -dodecane and n -tetradecane are used as single-component representative fuels for diesel. Methyl laurate is found to represent biodiesel of coconut, whereas methyl oleate is found to represent biodiesel having high percentage of long-chain fatty acid esters. The spray tip penetration of methyl oleate is found to be in good agreement with the measured spray tip penetration of karanja biodiesel. The spray tip penetration prediction of n -heptane fuel is closely following diesel spray tip penetration along with that of n -tetradecane and n -dodecane. The study suggests that the knowledge of the single-component representatives of biodiesel, diesel and their blend is sufficient to predict the spray tip penetration of the corresponding biodiesel, diesel and their blend under non-evaporating environment.

  1. Experimental and numerical investigations on spray characteristics of fatty acid methyl esters

    Science.gov (United States)

    Lanjekar, R. D.; Deshmukh, D.

    2018-02-01

    A comparative experimental and numerical study is conducted to establish the significance of the use of single-component over multi-component representatives of biodiesel, diesel and their blend for predicting spray tip penetration. Methyl oleate and methyl laurate are used as single-component representative fuels for biodiesel. The pure components n-heptane, n-dodecane and n-tetradecane are used as single-component representative fuels for diesel. Methyl laurate is found to represent biodiesel of coconut, whereas methyl oleate is found to represent biodiesel having high percentage of long-chain fatty acid esters. The spray tip penetration of methyl oleate is found to be in good agreement with the measured spray tip penetration of karanja biodiesel. The spray tip penetration prediction of n-heptane fuel is closely following diesel spray tip penetration along with that of n-tetradecane and n-dodecane. The study suggests that the knowledge of the single-component representatives of biodiesel, diesel and their blend is sufficient to predict the spray tip penetration of the corresponding biodiesel, diesel and their blend under non-evaporating environment.

  2. Cryogen spray cooling: Effects of droplet size and spray density on heat removal.

    Science.gov (United States)

    Pikkula, B M; Torres, J H; Tunnell, J W; Anvari, B

    2001-01-01

    Cryogen spray cooling (CSC) is an effective method to reduce or eliminate non-specific injury to the epidermis during laser treatment of various dermatological disorders. In previous CSC investigations, fuel injectors have been used to deliver the cryogen onto the skin surface. The objective of this study was to examine cryogen atomization and heat removal characteristics of various cryogen delivery devices. Various cryogen delivery device types including fuel injectors, atomizers, and a device currently used in clinical settings were investigated. Cryogen mass was measured at the delivery device output orifice. Cryogen droplet size profiling for various cryogen delivery devices was estimated by optically imaging the droplets in flight. Heat removal for various cryogen delivery devices was estimated over a range of spraying distances by temperature measurements in an skin phantom used in conjunction with an inverse heat conduction model. A substantial range of mass outputs were measured for the cryogen delivery devices while heat removal varied by less than a factor of two. Droplet profiling demonstrated differences in droplet size and spray density. Results of this study show that variation in heat removal by different cryogen delivery devices is modest despite the relatively large difference in cryogen mass output and droplet size. A non-linear relationship between heat removal by various devices and droplet size and spray density was observed. Copyright 2001 Wiley-Liss, Inc.

  3. An electrothermal chemical technology for thermal spray coatings

    International Nuclear Information System (INIS)

    Wald, S.; Appelbaum, G.; Alimi, R.; Rabani, L.; Zoler, D.; Zhitomirsky, V.; Factor, M.; Roman, I.

    1998-01-01

    A new spray technology for producing hard-coatings, has been developed at the SOREQ Nuclear Research Center. The concept is based on the extensive experience accumulated at SOREQ in the course of the development of Electrothermal (ET), Electrothermal-Chemical (ETC) and Solid-Propellant Electrothermal-Chemical (SPETC) guns(r). High quality coatings may be obtained by thermal spraying powder particles onto a variety of substrates. Mature state-of-the-art technologies such as plasma spray, high velocity oxy fuel (HVOF) and detonation gun (D-Gun) are widely used for many applications. As each method has its own drawbacks there is a need for a combination of several parameters which cannot be achieved by any existing individual commercial technology. The method presented is oriented toward a high-quality, multi-step, high-throughput, easily programmable continuous coating process and relatively inexpensive technology. The combustion products of a solid or liquid propellant accelerate the powder particles of the coating material. A pulsed-plasma jet, provided by a confined capillary discharge, ignites the propellant and controls the combustion process. The powder particles are accelerated to velocities over 1000 m/s. Due to the very high carrier gas density, high velocity, high throughput and high powder consumption efficiency are obtained. The plasma jet enables control of the gas temperature and consequently influences the powder temperature

  4. Spray Behavior and Atomization Characteristics of Biodiesel

    Science.gov (United States)

    Choi, Seung-Hun; Oh, Young-Taig

    Biodiesel has large amount of oxygen in itself, which make it very efficient in reducing exhaust emission by improving combustion inside an engine. But biodiesel has a low temperature flow problem because it has a high viscosity. In this study, the spray behavior and atomization characteristics were investigated to confirm of some effect for the combination of non-esterification biodiesel and fuel additive WDP and IPA. The process of spray was visualized through the visualization system composed of a halogen lamp and high speed camera, and atomization characteristics were investigated through LDPA. When blending WDP and IPA with biodiesel, atomization and spray characteristics were improved. Through this experimental result, SMD of blended fuel, WDP 25% and biodiesel 75%, was 33.9% reduced at distance 6cm from a nozzle tip under injection pressure 30MPa.

  5. 3D characterisation of the gaseous and liquid phase using laser-induced exciplex fluorescence (LIEF) tomography; Dreidimensionale Charakterisierung der Gas- und Fluessigphase mittels laserinduzierter Exciplexfluoreszenz (LIEF) Tomografie

    Energy Technology Data Exchange (ETDEWEB)

    Rogler, P.; Grzeszik, R.; Arndt, S. [Robert Bosch GmbH, Stuttgart (Germany); Waidmann, C. [Fachhochschule Aalen (Germany); Aigner, M. [DLR, Stuttgart (Germany). Inst. fuer Verbrennungstechnik

    2007-07-01

    The quality of mixture formation in gasoline engines has a significant influence on combustion, emissions and mileage. The measurement technique used for mixture formation analysis of both liquid and vapor phase is laser induced exciplex fluorescence (LIEF), where the aromatics TMPD and naphthalene are added to a non-fluorescing model fuel free of aromatic compounds. For spatially high-resolved measurements of liquid and vapor phase this technique was extended from planar to volume information via tomography. This new approach requires fundamental studies of tracer behavior and new evaluation algorithms for reliable signal interpretation of fluid dynamics in sprays. Using this measurement technique GDI sprays are investigated at a typical stratified engine operation point at part load. For the different injector types, e.g. multi hole and annular orifice injector, an optimal illumination is crucial. With the collected data the spray volume can be calculated, mixture homogeneity can be evaluated and, using a few assumptions, the air/fuel ratio {lambda} can be computed. (orig.)

  6. Comparison of atomization characteristics of drop-in and conventional jet fuels

    Science.gov (United States)

    Kannaiyan, Kumaran; Sadr, Reza; Micro Scale Thermo-Fluids Lab Team

    2016-11-01

    Surge in energy demand and stringent emission norms have been driving the interest on alternative drop-in fuels in aviation industry. The gas-to-liquid (GTL), synthetic paraffinic kerosene fuel derived from natural gas, has drawn significant attention as drop-in fuel due to its cleaner combustion characteristics when compared to other alternative fuels derived from various feedstocks. The fuel specifications such as chemical and physical properties of drop-in fuels are different from those of the conventional jet fuels, which can affect their atomization characteristics and in turn the combustion performance. The near nozzle liquid sheet dynamics of the drop-in fuel, GTL, is studied at different nozzle operating conditions and compared with that of the conventional Jet A-1 fuel. The statistical analysis of the near nozzle sheet dynamics shows that the drop-in fuel atomization characteristics are comparable to those of the conventional fuel. Furthermore, the microscopic spray characteristics measured using phase Doppler anemometry at downstream locations are slightly different between the fuels. Authors acknowledge the support by National Priorities Research Program (NPRP) of Qatar National Research Fund through the Grant NPRP-7-1449-2-523.

  7. The Advanced High-Temperature Reactor (AHTR) for Producing Hydrogen to Manufacture Liquid Fuels

    International Nuclear Information System (INIS)

    Forsberg, C.W.; Peterson, P.F.; Ott, L.

    2004-01-01

    Conventional world oil production is expected to peak within a decade. Shortfalls in production of liquid fuels (gasoline, diesel, and jet fuel) from conventional oil sources are expected to be offset by increased production of fuels from heavy oils and tar sands that are primarily located in the Western Hemisphere (Canada, Venezuela, the United States, and Mexico). Simultaneously, there is a renewed interest in liquid fuels from biomass, such as alcohol; but, biomass production requires fertilizer. Massive quantities of hydrogen (H2) are required (1) to convert heavy oils and tar sands to liquid fuels and (2) to produce fertilizer for production of biomass that can be converted to liquid fuels. If these liquid fuels are to be used while simultaneously minimizing greenhouse emissions, nonfossil methods for the production of H2 are required. Nuclear energy can be used to produce H2. The most efficient methods to produce H2 from nuclear energy involve thermochemical cycles in which high-temperature heat (700 to 850 C) and water are converted to H2 and oxygen. The peak nuclear reactor fuel and coolant temperatures must be significantly higher than the chemical process temperatures to transport heat from the reactor core to an intermediate heat transfer loop and from the intermediate heat transfer loop to the chemical plant. The reactor temperatures required for H2 production are at the limits of practical engineering materials. A new high-temperature reactor concept is being developed for H2 and electricity production: the Advanced High-Temperature Reactor (AHTR). The fuel is a graphite-matrix, coated-particle fuel, the same type that is used in modular high-temperature gas-cooled reactors (MHTGRs). The coolant is a clean molten fluoride salt with a boiling point near 1400 C. The use of a liquid coolant, rather than helium, reduces peak reactor fuel and coolant temperatures 100 to 200 C relative to those of a MHTGR. Liquids are better heat transfer fluids than gases

  8. Liquid Fuels from Lignins: Annual Report

    Energy Technology Data Exchange (ETDEWEB)

    Chum, H. L.; Johnson, D. K.

    1986-01-01

    This task was initiated to assess the conversion of lignins into liquid fuels, primarily of lignins relevant to biomass-to-ethanol conversion processes. The task was composed of a literature review of this area and an experimental part to obtain pertinent data on the conversion of lignins germane to biomass-to-ethanol conversion processes.

  9. Auto-Ignition and Spray Characteristics of n-Heptane and iso-Octane Fuels in Ignition Quality Tester

    KAUST Repository

    Jaasim, Mohammed

    2018-04-04

    Numerical simulations were conducted to systematically assess the effects of different spray models on the ignition delay predictions and compared with experimental measurements obtained at the KAUST ignition quality tester (IQT) facility. The influence of physical properties and chemical kinetics over the ignition delay time is also investigated. The IQT experiments provided the pressure traces as the main observables, which are not sufficient to obtain a detailed understanding of physical (breakup, evaporation) and chemical (reactivity) processes associated with auto-ignition. A three-dimensional computational fluid dynamics (CFD) code, CONVERGE™, was used to capture the detailed fluid/spray dynamics and chemical characteristics within the IQT configuration. The Reynolds-averaged Navier-Stokes (RANS) turbulence with multi-zone chemistry sub-models was adopted with a reduced chemical kinetic mechanism for n-heptane and iso-octane. The emphasis was on the assessment of two common spray breakup models, namely the Kelvin-Helmholtz/Rayleigh-Taylor (KH-RT) and linearized instability sheet atomization (LISA) models, in terms of their influence on auto-ignition predictions. Two spray models resulted in different local mixing, and their influence in the prediction of auto-ignition was investigated. The relative importance of physical ignition delay, characterized by spray evaporation and mixing processes, in the overall ignition behavior for the two different fuels were examined. The results provided an improved understanding of the essential contribution of physical and chemical processes that are critical in describing the IQT auto-ignition event at different pressure and temperature conditions, and allowed a systematic way to distinguish between the physical and chemical ignition delay times.

  10. Fuel transfer manipulator for liquid metal nuclear reactors

    International Nuclear Information System (INIS)

    Sturges, R.H.

    1983-01-01

    A manipulator for transferring fuel assemblies between inclined fuel chutes of a liquid metal nuclear reactor installation. Hoisting means are mounted on a mount supported by beams pivotably attached by pins to the mount and to the floor in such a manner that pivoting of the beams causes movement and tilting of a hoist tube between positions of alignment with the inclined chutes. (author)

  11. Spray and evaporation characteristics of ethanol and gasoline direct injection in non-evaporating, transition and flash-boiling conditions

    International Nuclear Information System (INIS)

    Huang, Yuhan; Huang, Sheng; Huang, Ronghua; Hong, Guang

    2016-01-01

    Highlights: • Sprays can be considered as non-evaporating when vapour pressure is lower than 30 kPa. • Ethanol direct injection should only be applied in high temperature engine environment. • Gasoline spray collapses at lower fuel temperature (350 K) than ethanol spray does (360 K). • Flash-boiling does not occur when fuel temperature reaches boiling point until ΔT is 14 K. • Not only spray evaporation mode but also breakup mechanism change with fuel temperature. - Abstract: Ethanol direct injection plus gasoline port injection (EDI + GPI) represents a more efficient and flexible way to utilize ethanol fuel in spark ignition engines. To exploit the potentials of EDI, the mixture formation characteristics need to be investigated. In this study, the spray and evaporation characteristics of ethanol and gasoline fuels injected from a multi-hole injector were investigated by high speed Shadowgraphy imaging technique in a constant volume chamber. The experiments covered a wide range of fuel temperature from 275 K (non-evaporating) to 400 K (flash-boiling) which corresponded to cold start and running conditions in an engine. The spray transition process from normal-evaporating to flash-boiling was investigated in greater details than the existed studies. Results showed that ethanol and gasoline sprays demonstrated the same patterns in non-evaporating conditions. The sprays could be considered as non-evaporating when vapour pressure was lower than 30 kPa. Ethanol evaporated more slowly than gasoline did in low temperature environment, but they reached the similar evaporation rates when temperature was higher than 375 K. This suggested that EDI should only be applied in high temperature engine environment. For both ethanol and gasoline sprays, when the excess temperature was smaller than 4 K, the sprays behaved the same as the subcooled sprays did. The sprays collapsed when the excess temperature was 9 K. Flash-boiling did not occur until the excess temperature

  12. Investigation of a piezoelectric droplet delivery method for fuel injection and physical property evaluation

    Science.gov (United States)

    Zhao, Wei; Menon, Shyam

    2017-11-01

    A piezoelectric droplet generator is investigated to deliver liquid hydrocarbon fuels to a micro-combustor application. Besides fuel delivery, the setup is intended to measure fuel physical properties such as viscosity and surface tension. These properties are highly relevant to spray generation in internal combustion engines. Accordingly, a drop-on-demand piezoelectric dispenser is used to generate fuel droplet trains, which are studied using imaging and Phase Doppler Particle Anemometry (PDPA). The diagnostics provide information regarding droplet size and velocity and their evolution over time. The measurements are correlated with results from one-dimensional (1D) models that incorporate sub-models for piezo-electric actuation and droplet vaporization. By validating the 1D models for fuels with known physical properties, a technique is developed that has the capability to meter low-vapor pressure liquid fuels to the microcombustor and use information from the droplet train to calculate physical properties of novel fuels.

  13. High-temperature reactors for underground liquid-fuels production with direct carbon sequestration

    International Nuclear Information System (INIS)

    Forsberg, C. W.

    2008-01-01

    The world faces two major challenges: (1) reducing dependence on oil from unstable parts of the world and (2) minimizing greenhouse gas emissions. Oil provides 39% of the energy needs of the United States, and oil refineries consume over 7% of the total energy. The world is running out of light crude oil and is increasingly using heavier fossil feedstocks such as heavy oils, tar sands, oil shale, and coal for the production of liquid fuels (gasoline, diesel, and jet fuel). With heavier feedstocks, more energy is needed to convert the feedstocks into liquid fuels. In the extreme case of coal liquefaction, the energy consumed in the liquefaction process is almost twice the energy value of the liquid fuel. This trend implies large increases in carbon dioxide releases per liter of liquid transport fuel that is produced. It is proposed that high-temperature nuclear heat be used to refine hydrocarbon feedstocks (heavy oil, tar sands, oil shale, and coal) 'in situ ', i.e., underground. Using these resources for liquid fuel production would potentially enable the United States to become an exporter of oil while sequestering carbon from the refining process underground as carbon. This option has become potentially viable because of three technical developments: precision drilling, underground isolation of geological formations with freeze walls, and the understanding that the slow heating of heavy hydrocarbons (versus fast heating) increases the yield of light oils while producing a high-carbon solid residue. Required peak reactor temperatures are near 700 deg. C-temperatures within the current capabilities of high-temperature reactors. (authors)

  14. Generation of 1:1 Carbamazepine:Nicotinamide cocrystals by spray drying.

    Science.gov (United States)

    Patil, Shashank P; Modi, Sameer R; Bansal, Arvind K

    2014-10-01

    The present study investigates the potential of spray drying as a technique for generation of pharmaceutical cocrystals. Carbamazepine-Nicotinamide cocrystal (CNC) was chosen as model cocrystal system for this study. Firstly, CNC was generated using liquid assisted grinding and used for generation of phase solubility diagram (PSD) and ternary phase diagram (TPD). Both PSD and TPD were carefully evaluated for phase behavior of CNC when equilibrated with solvent. The undersaturated region with respect to CNC, as depicted by TPD, was selected as target region to initiate cocrystallization experiments. Various points in this region, representative of different compositions of Carbamazepine, Nicotinamide and CNC, were selected and spray drying was carried out. The spray dried product was characterized for solid state properties and was compared with CNC generated by liquid assisted grinding. Spray drying successfully generated CNC of similar quality as those generated by liquid assisted grinding. Moreover, there was no significant impact of process variables on formation of CNC. Spray drying, owing to its simplicity and industrial scalability, can be a promising method for large scale cocrystal generation. Copyright © 2014 Elsevier B.V. All rights reserved.

  15. Numerical Investigation on Sensitivity of Liquid Jet Breakup to Physical Fuel Properties with Experimental Comparison

    Science.gov (United States)

    Kim, Dokyun; Bravo, Luis; Matusik, Katarzyna; Duke, Daniel; Kastengren, Alan; Swantek, Andy; Powell, Christopher; Ham, Frank

    2016-11-01

    One of the major concerns in modern direct injection engines is the sensitivity of engine performance to fuel characteristics. Recent works have shown that even slight differences in fuel properties can cause significant changes in efficiency and emission of an engine. Since the combustion process is very sensitive to the fuel/air mixture formation resulting from disintegration of liquid jet, the precise assessment of fuel sensitivity on liquid jet atomization process is required first to study the impact of different fuels on the combustion. In the present study, the breaking process of a liquid jet from a diesel injector injecting into a quiescent gas chamber is investigated numerically and experimentally for different liquid fuels (n-dodecane, iso-octane, CAT A2 and C3). The unsplit geometric Volume-of-Fluid method is employed to capture the phase interface in Large-eddy simulations and results are compared against the radiography measurement from Argonne National Lab including jet penetration, liquid mass distribution and volume fraction. The breakup characteristics will be shown for different fuels as well as droplet PDF statistics to demonstrate the influences of the physical properties on the primary atomization of liquid jet. Supported by HPCMP FRONTIER award, US DOD, Office of the Army.

  16. Liquid alternative diesel fuels with high hydrogen content

    Energy Technology Data Exchange (ETDEWEB)

    Hancsok, Jenoe; Varga, Zoltan; Eller, Zoltan; Poelczmann, Gyoergy [Pannonia Univ., Veszprem (Hungary). MOL Dept. of Hydrocarbon Processing; Kasza, Tamas [MOL Hungarian Oil and Gas Plc., Szazhalombatta (Hungary)

    2013-06-01

    Mobility is a keystone of the sustainable development. In the operation of the vehicles as the tools of mobility internal combustion engines, so thus Diesel engines will play a remarkable role in the next decades. Beside fossil fuels - used for power these engines - liquid alternative fuels have higher and higher importance, because of their known advantages. During the presentation the categorization possibilities based on the chronology of their development and application will be presented. The importance of fuels with high hydrogen content will be reviewed. Research and development activity in the field of such kind of fuels will be presented. During this developed catalytic systems and main performance properties of the product will be presented which were obtained in case of biogasoils produced by special hydrocracking of natural triglycerides and in case of necessity followed by isomerization; furthermore in case of synthetic biogasoils obtained by the isomerization hydrocracking of Fischer-Tropsch paraffins produced from biomass based synthesis gas. Excellent combustion properties (cetane number > 65-75), good cold flow properties and reduced harmful material emission due to the high hydrogen content (C{sub n}H{sub 2n+2}) are highlighted. Finally production possibilities of linear and branched paraffins based on lignocelluloses are briefly reviewed. Summarizing it was concluded that liquid hydrocarbons with high isoparaffin content are the most suitable fuels regarding availability, economical and environmental aspects, namely the sustainable development. (orig.)

  17. Reimagining liquid transportation fuels : sunshine to petrol.

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Terry Alan (Sandia National Laboratories, Livermore, CA); Hogan, Roy E., Jr.; McDaniel, Anthony H. (Sandia National Laboratories, Livermore, CA); Siegel, Nathan Phillip; Dedrick, Daniel E. (Sandia National Laboratories, Livermore, CA); Stechel, Ellen Beth; Diver, Richard B., Jr.; Miller, James Edward; Allendorf, Mark D. (Sandia National Laboratories, Livermore, CA); Ambrosini, Andrea; Coker, Eric Nicholas; Staiger, Chad Lynn; Chen, Ken Shuang; Ermanoski, Ivan; Kellog, Gary L.

    2012-01-01

    Two of the most daunting problems facing humankind in the twenty-first century are energy security and climate change. This report summarizes work accomplished towards addressing these problems through the execution of a Grand Challenge LDRD project (FY09-11). The vision of Sunshine to Petrol is captured in one deceptively simple chemical equation: Solar Energy + xCO{sub 2} + (x+1)H{sub 2}O {yields} C{sub x}H{sub 2x+2}(liquid fuel) + (1.5x+.5)O{sub 2} Practical implementation of this equation may seem far-fetched, since it effectively describes the use of solar energy to reverse combustion. However, it is also representative of the photosynthetic processes responsible for much of life on earth and, as such, summarizes the biomass approach to fuels production. It is our contention that an alternative approach, one that is not limited by efficiency of photosynthesis and more directly leads to a liquid fuel, is desirable. The development of a process that efficiently, cost effectively, and sustainably reenergizes thermodynamically spent feedstocks to create reactive fuel intermediates would be an unparalleled achievement and is the key challenge that must be surmounted to solve the intertwined problems of accelerating energy demand and climate change. We proposed that the direct thermochemical conversion of CO{sub 2} and H{sub 2}O to CO and H{sub 2}, which are the universal building blocks for synthetic fuels, serve as the basis for this revolutionary process. To realize this concept, we addressed complex chemical, materials science, and engineering problems associated with thermochemical heat engines and the crucial metal-oxide working-materials deployed therein. By project's end, we had demonstrated solar-driven conversion of CO{sub 2} to CO, a key energetic synthetic fuel intermediate, at 1.7% efficiency.

  18. Study on Calculation of Liquid Level And Storage of Tanks for LNG-fueled Vessels

    Science.gov (United States)

    Li, Kun; Wang, Guoqing; Liu, Chang

    2018-01-01

    As the ongoing development of the application of LNG as a clean energy in waterborne transport industry, the fleet scale of LNG-fueled vessels enlarged and the safety operation has attracted more attention in the industry. Especially the accurate detection of liquid level of LNG tanks is regarded as an important issue to ensure a safe and stable operation of LNG-fueled ships and a key parameter to keep the proper functioning of marine fuel storage system, supply system and safety control system. At present, detection of LNG tank liquid level mainly adopts differential pressure detection method. Liquid level condition could be found from the liquid level reference tables. However in practice, since LNG-fueled vessels are generally not in a stationary state, liquid state within the LNG tanks will constantly change, the detection of storage of tanks only by reference to the tables will cause deviation to some extent. By analyzing the temperature under different pressure, the effects of temperature change on density and volume integration calculation, a method of calculating the liquid level and storage of LNG tanks is put forward making the calculation of liquid level and actual storage of LNG tanks more accurately and providing a more reliable basis for the calculation of energy consumption level and operation economy for LNG-fueled vessels.

  19. Numerical Study on Fan Spray for Gasoline Direct Injection Engines

    OpenAIRE

    Shirabe, Naotaka; Sato, Takaaki; Murase, Eiichi

    2003-01-01

    In gasoline direct injection engines, it is important to optimize fuel spray characteristics, which strongly affect stratified combustion process. Spray simulation is expected as a tool for optimizing the nozzle design. Conventional simulation method, how

  20. LSPRAY-IV: A Lagrangian Spray Module

    Science.gov (United States)

    Raju, M. S.

    2012-01-01

    LSPRAY-IV is a Lagrangian spray solver developed for application with parallel computing and unstructured grids. It is designed to be massively parallel and could easily be coupled with any existing gas-phase flow and/or Monte Carlo Probability Density Function (PDF) solvers. The solver accommodates the use of an unstructured mesh with mixed elements of either triangular, quadrilateral, and/or tetrahedral type for the gas flow grid representation. It is mainly designed to predict the flow, thermal and transport properties of a rapidly vaporizing spray. Some important research areas covered as a part of the code development are: (1) the extension of combined CFD/scalar-Monte- Carlo-PDF method to spray modeling, (2) the multi-component liquid spray modeling, and (3) the assessment of various atomization models used in spray calculations. The current version contains the extension to the modeling of superheated sprays. The manual provides the user with an understanding of various models involved in the spray formulation, its code structure and solution algorithm, and various other issues related to parallelization and its coupling with other solvers.

  1. Spray combustion of Jet-A and diesel fuels in a constant volume combustion chamber

    KAUST Repository

    Jing, Wei

    2015-01-01

    This work investigates the spray combustion of Jet-A fuel in an optical constant-volume combustion chamber under different ambient initial conditions. Ambient temperature was varied at 800 K, 1000 K, and 1200 K and five different ambient O2 concentrations were used, spanning 10-21%. These ambient conditions can be used to mimic practical diesel engine working conditions under different fuel injection timings and exhaust gas recirculation (EGR) levels. Both transient and quasi-steady state analyses were conducted. The transient analysis focused on the flame development from the beginning to the end of the combustion process, illustrating how the flame structure evolves with time. The quasi-steady state analysis concentrated on the stable flame structure and compared the flame emissions in terms of spatially integrated intensity, flame effective area, and intensity per pixel. The transient analysis was based on measurements using high-speed imaging of both OH∗ chemiluminescence and broadband natural luminosity (NL). For the quasi-steady state analysis, three flame narrow-band emissions (OH∗ at 310 nm, Band A at 430 nm and Band B at 470 nm) were captured using an ICCD camera. Based on the current Jet-A data and diesel data obtained from previous experiments, a comparison between Jet-A and diesel was made in terms of flame development during the transient state and spatially integrated intensity, flame effective area, and intensity per pixel during the quasi-steady state. For the transient results, Jet-A shares a similar flame development trend to diesel, but featuring a narrower region of NL and a wider region of OH∗ with the increase of ambient temperature and O2 concentration. The soot cloud is oxidized more quickly for Jet-A than diesel at the end of combustion, evident by comparing the area of NL, especially under high O2 concentration. The quasi-steady state results suggest that soot is oxidized effectively under high O2 concentration conditions by the

  2. Rewetting of a hot metallic wall by liquid spray

    Energy Technology Data Exchange (ETDEWEB)

    Castiglia, F.; Giardina, M.; Lombardo, C. [University of Palermo, Department of Nuclear Engineering, V.le delle Scienze, 90128 Palermo (Italy)

    2005-07-01

    Full text of publication follows: Rewetting is the re-establishment of liquid in contact with a hot dried surface, whose initial temperature is higher than the so-called 'rewetting temperature'. This phenomenology is of interest in many industrial processes, for example: in metallurgical quenching, in electronic equipments cooling, in cryogenic processes, in preserving the integrity of toxic and dangerous substances metallic containers endangered by a hypothetical fire. Moreover it is essential for the re-establishment of normal and safe temperature levels following rod cluster dryout or hypothesized loss of coolant accidents (LOCAs) in nuclear reactors. In spite of the large amount of experimental and theoretical work done in the past decades, the above depicted phenomenology still deserves further clarifications and deepening. For this reason, recently at the Institute of Energetic Thermal-Fluid Dynamics of ENEA (Ente per le Nuove Tecnologie, l'Energia e l'Ambiente, at Casaccia, Italy), experimental researches have been carried out on the rewetting of vertical surfaces, at ambient pressure and various water flow rates by spraying subcooled water at the top. Spraying devices of various configuration, able to supply water drops of uniform diameter, have been used [1]. As it is known when, following the drops impact in some region at the top of the surface the temperature is lowered below the rewetting temperature, a liquid falling film forms, the front of which advances with a velocity ( the so called 'rewetting velocity'), limited by the rapidity by which the heat is conducted into the solid (conduction controlled rewetting). In the past, about the rewetting the researchers of Department of Nuclear Engineering of the University of Palermo have carried out an extensive theoretical work and more recently, have proposed a semi-theoretical model which proved successful in correlating a lot of experimental data [2]. This model has been

  3. High Fidelity Simulation of Primary Atomization in Diesel Engine Sprays

    Science.gov (United States)

    Ivey, Christopher; Bravo, Luis; Kim, Dokyun

    2014-11-01

    A high-fidelity numerical simulation of jet breakup and spray formation from a complex diesel fuel injector at ambient conditions has been performed. A full understanding of the primary atomization process in fuel injection of diesel has not been achieved for several reasons including the difficulties accessing the optically dense region. Due to the recent advances in numerical methods and computing resources, high fidelity simulations of atomizing flows are becoming available to provide new insights of the process. In the present study, an unstructured un-split Volume-of-Fluid (VoF) method coupled to a stochastic Lagrangian spray model is employed to simulate the atomization process. A common rail fuel injector is simulated by using a nozzle geometry available through the Engine Combustion Network. The working conditions correspond to a single orifice (90 μm) JP-8 fueled injector operating at an injection pressure of 90 bar, ambient condition at 29 bar, 300 K filled with 100% nitrogen with Rel = 16,071, Wel = 75,334 setting the spray in the full atomization mode. The experimental dataset from Army Research Lab is used for validation in terms of spray global parameters and local droplet distributions. The quantitative comparison will be presented and discussed. Supported by Oak Ridge Associated Universities and the Army Research Laboratory.

  4. Visualization research on spray atomization, evaporation and combustion processes of ethanol–diesel blend under LTC conditions

    International Nuclear Information System (INIS)

    Huang, Sheng; Deng, Peng; Huang, Ronghua; Wang, Zhaowen; Ma, Yinjie; Dai, Hui

    2015-01-01

    Highlights: • Spray combustion of E20 diesel in LTC condition shows a U-shape flame structure. • The chasing behavior of fuel spray exists near the spray axis. • Fuel ignition doesn’t initiate at the spray tip but in peripheral regions behind it. • An improper chamber structure may lead to a long post-combustion duration. - Abstract: Utilization of ethanol in diesel engines has been widely studied by means of engine experiments and emission detection. However, pertinent studies on the spray combustion process of ethanol–diesel blends are scarce. In order to verify the effect of ethanol in modern diesel engines, an experiment is conducted to visualize the spray combustion process of ethanol–diesel blend under LTC conditions. Stages including atomization, evaporation and combustion, are investigated individually to realize synergistic analysis. Meanwhile, considering the long time scale of combustion after fuel injection finishes, characteristics during and after injection period are both targeted in this paper. Moreover, measurement of macroscopic characteristics, such as spray tip penetration, spray spreading cone angle and flame lift off length, provides a quantitative profile of the spray structure. Results show that, evaporation, different from atomization, has little influence on spray penetration, but promotes the spray spreading angle and spray projected area. So does combustion, which enlarges the spray projected area further. Ignition takes place on the periphery behind the spray tip, then quickly extends to the whole head of the spray and forms a U-shape diffusion structure. After the injection period, the residual spray tail develops into wavelike structures due to absence of subsequent entrainment force. Also, the penetration speed falls greatly to an extent much slower than flame propagation, which frees the flame from the lift-off effect. Subsequently, the flame propagates upstream towards the nozzle orifice. After consumed all fuel in

  5. Coupled neutronics/thermal-hydraulics and safety characteristics of liquid-fueled molten salt reactors

    International Nuclear Information System (INIS)

    Qiu, Suizheng; Zhang, Dalin; Liu, Minghao; Liu, Limin; Xu, Rongshuan; Gong, Cheng; Su, Guanghui

    2016-01-01

    Molten salt reactor (MSR) as one candidate of the Generation IV advanced nuclear power systems is attracted more attention in China due to its top ranked fuel cycle and thorium utilization. The MSRs are characterized by using liquid-fuel, which offers complicated coupling problem of neutronics and thermal hydraulics. In this paper, the fundamental model and numerical method are established to calculate and analyze the safety characteristics for liquid-fuel MSRs. The theories and methodologies are applied to the MOSART concept. The liquid-fuel flow effects on neutronics, reactivity coefficients and three operation parameters' influences at steady state are obtained, which provide the basic information for safety analysis. The unprotected loss of flow transient is calculated, the results of which shows the inherent safety characteristics of MOSART due to its strong negative reactivity feedbacks.

  6. Coupled neutronics/thermal-hydraulics and safety characteristics of liquid-fueled molten salt reactors

    Energy Technology Data Exchange (ETDEWEB)

    Qiu, Suizheng; Zhang, Dalin; Liu, Minghao; Liu, Limin; Xu, Rongshuan; Gong, Cheng; Su, Guanghui [Xi' an Jiaotong Univ. (China). State Key Laboratory of Multiphase Flow in Power Engineering

    2016-05-15

    Molten salt reactor (MSR) as one candidate of the Generation IV advanced nuclear power systems is attracted more attention in China due to its top ranked fuel cycle and thorium utilization. The MSRs are characterized by using liquid-fuel, which offers complicated coupling problem of neutronics and thermal hydraulics. In this paper, the fundamental model and numerical method are established to calculate and analyze the safety characteristics for liquid-fuel MSRs. The theories and methodologies are applied to the MOSART concept. The liquid-fuel flow effects on neutronics, reactivity coefficients and three operation parameters' influences at steady state are obtained, which provide the basic information for safety analysis. The unprotected loss of flow transient is calculated, the results of which shows the inherent safety characteristics of MOSART due to its strong negative reactivity feedbacks.

  7. CFD Modeling of Fuel Injection and Combustion in an HDDI Engine

    Energy Technology Data Exchange (ETDEWEB)

    Rijk, E.

    2009-07-01

    In this study, the Star-CD CFD package is first used to model spray formation in a constant volume chamber and in a cycle of a heavy duty direct injection (HDDI) engine. Secondly, combustion is modeled using a standard Star-CD combustion model and a user-defined tabulated chemistry method (FGM). In modern diesel engines, fuel is injected into the combustion chamber by an injector, at a high pressure. As the fuel flows through this nozzle, phenomena like cavitation can occur influencing the injection velocity. When the liquid fuel jet exits the nozzle, it breaks up into droplets, which is called primary break-up. Due to the velocity difference between the in-cylinder air and these droplets, they break-up even further, called secondary break-up. The high temperature in the combustion chamber make the droplets evaporate until a point is reached where no liquid fuel is present anymore (liquid length). Hereafter, the evaporated fuel penetrates further (fuel penetration) and at some point in time, the spray auto-ignites. In Star-CD, different sub-models are present to simulate nozzle flow, primary and secondary break-up in a Eulerian-Lagrangian framework. The best performing sub-models are determined by comparing measured liquid length and fuel penetration with calculated values. To be able to do this objectively, a virtual Mie scattering method is developed and applied, together with a previously designed virtual Schlieren method. Using this optimal combination of sub-models, a sensitivity study is performed as previous research revealed that CFD calculations can be highly mesh and timestep dependent. When the optimal settings are known, the Star-CD spray results are validated with experimental data containing a wide range of nozzle diameters, ambient conditions, injection pressures and fuel types. Next to Star-CD, non-Lagrangian models are used to calculate liquid length and spray penetration. It appears that the accuracies of Star-CD and the non-Lagrangian model of

  8. Water storage of liquid-metal fast-breeder-reactor fuel

    International Nuclear Information System (INIS)

    Meacham, S.A.

    1982-01-01

    The purpose of this paper is to present a general overview of a concept proposed for receiving and storing liquid metal fast breeder reactor (LMFBR) spent fuel. This work was done as part of the Consolidated Fuel Reprocessing Program (CFRP) at the Oak Ridge National Laboratory (ORNL). The CFRP has as its major objective the development of technology for reprocessing advanced nuclear reactor fuels. The program plans that research and development will be carried through to a sufficient scale, using irradiated spent fuel under plant operating conditions, to establish a basis for confident projection of reprocessing capability to support a breeder industry

  9. Performance of metallic fuels in liquid-metal fast reactors

    International Nuclear Information System (INIS)

    Seidel, B.R.; Walters, L.C.; Kittel, J.H.

    1984-01-01

    Interest in metallic fuels for liquid-metal fast reactors has come full circle. Metallic fuels are once again a viable alternative for fast reactors because reactor outlet temperature of interest to industry are well within the range where metallic fuels have demonstrated high burnup and reliable performance. In addition, metallic fuel is very tolerant of off-normal events of its high thermal conductivity and fuel behavior. Futhermore, metallic fuels lend themselves to compact and simplified reprocessing and refabrication technologies, a key feature in a new concept for deployment of fast reactors called the Integral Fast Reactor (IFR). The IFR concept is a metallic-fueled pool reactor(s) coupled to an integral-remote reprocessing and fabrication facility. The purpose of this paper is to review recent metallic fuel performance, much of which was tested and proven during the twenty years of EBR-II operation

  10. New process of the preparation of catalyzed gas diffusion electrode for PEM fuel cells based on ultrasonic direct solution spray reaction method

    Energy Technology Data Exchange (ETDEWEB)

    Oishi, K.; Savadogo, O. [Ecole Polytechnique de Montreal, Montreal, PQ (Canada). Laboratoire de nouveaux materiaux pour l' energie et l' electrochimie

    2008-07-01

    This paper reported on a newly developed process for in-situ catalyst deposition on gas diffusion electrodes (GDE) for polymer electrolyte fuel cells. This process has the potential to reduce the number of steps for catalyzed GDE fabrication. In addition, the process offers economic advantages for the fuel cell commercialization. In this study, a home-made catalyst maker with ultrasonic spray method was used to prepare a solution of the carbon supported platinum catalyst on the GDL. The sprayed catalyst powder consisted of carbon support. The catalyst particles did not prevent gas flow channels on the GDL. The catalyst layer was shown to be located only on the top surface of the GDL and was not packed into its flow channel. Results of Cross-section SEM image, crystallization, micro structure and electro-catalytic activity for the oxygen reduction reaction were also discussed. 1 ref., 1 fig.

  11. Electrochemical applications of room temperature ionic liquids in nuclear fuel cycle

    International Nuclear Information System (INIS)

    Venkatesan, K.A.; Srinivasan, T.G.; Vasudeva Rao, P.R.

    2008-01-01

    Applications of room temperature ionic liquids (RTILs) have invaded all branches of science. They are also receiving an upsurge, in recent years, for possible applications in various stages of nuclear fuel cycle. Ionic liquids are compounds composed entirely of ions existing in liquid state and RTILs are ionic liquids molten at temperatures lower than 373 K. RTILs are generally made up of an organic cation and an inorganic or an organic anion. Room temperature ionic liquids have several fascinating properties, which are unique to a particular combination of cation and anion. The properties such as insignificant vapor pressure, amazing ability to dissolve organic and inorganic compounds, wide electrochemical window are the specific advantages when dealing with application of RTILs for reprocessing of spent nuclear fuel. The ionic liquids are regarded as designer or tailor-made solvents as their properties can be tuned for desired application by appropriate cation-anion combinations. An excellent review by Wilkes describes about the historical perspectives of room temperature ionic liquids, pioneers in that area, events and the products delivered till 2001. Furthermore, several comprehensive reviews have been made on room temperature ionic liquids by various authors

  12. Alternative Liquid Fuels Simulation Model (AltSim).

    Energy Technology Data Exchange (ETDEWEB)

    Williams, Ryan; Baker, Arnold Barry; Drennen, Thomas E.

    2009-12-01

    The Alternative Liquid Fuels Simulation Model (AltSim) is a high-level dynamic simulation model which calculates and compares the production and end use costs, greenhouse gas emissions, and energy balances of several alternative liquid transportation fuels. These fuels include: corn ethanol, cellulosic ethanol from various feedstocks (switchgrass, corn stover, forest residue, and farmed trees), biodiesel, and diesels derived from natural gas (gas to liquid, or GTL), coal (coal to liquid, or CTL), and coal with biomass (CBTL). AltSim allows for comprehensive sensitivity analyses on capital costs, operation and maintenance costs, renewable and fossil fuel feedstock costs, feedstock conversion ratio, financial assumptions, tax credits, CO{sub 2} taxes, and plant capacity factor. This paper summarizes the structure and methodology of AltSim, presents results, and provides a detailed sensitivity analysis. The Energy Independence and Security Act (EISA) of 2007 sets a goal for the increased use of biofuels in the U.S., ultimately reaching 36 billion gallons by 2022. AltSim's base case assumes EPA projected feedstock costs in 2022 (EPA, 2009). For the base case assumptions, AltSim estimates per gallon production costs for the five ethanol feedstocks (corn, switchgrass, corn stover, forest residue, and farmed trees) of $1.86, $2.32, $2.45, $1.52, and $1.91, respectively. The projected production cost of biodiesel is $1.81/gallon. The estimates for CTL without biomass range from $1.36 to $2.22. With biomass, the estimated costs increase, ranging from $2.19 per gallon for the CTL option with 8% biomass to $2.79 per gallon for the CTL option with 30% biomass and carbon capture and sequestration. AltSim compares the greenhouse gas emissions (GHG) associated with both the production and consumption of the various fuels. EISA allows fuels emitting 20% less greenhouse gases (GHG) than conventional gasoline and diesels to qualify as renewable fuels. This allows several of the

  13. Large eddy simulation of spray and combustion characteristics with realistic chemistry and high-order numerical scheme under diesel engine-like conditions

    International Nuclear Information System (INIS)

    Zhou, Lei; Luo, Kai Hong; Qin, Wenjin; Jia, Ming; Shuai, Shi Jin

    2015-01-01

    Highlights: • MUSCL differencing scheme in LES method is used to investigate liquid fuel spray and combustion process. • Using MUSCL can accurately capture the gas phase velocity distribution and liquid spray features. • Detailed chemistry mechanism with a parallel algorithm was used to calculate combustion process. • Increasing oxygen concentration can decrease ignition delay time and flame LOL. - Abstract: The accuracy of large eddy simulation (LES) for turbulent combustion depends on suitably implemented numerical schemes and chemical mechanisms. In the original KIVA3V code, finite difference schemes such as QSOU (Quasi-second-order upwind) and PDC (Partial Donor Cell Differencing) cannot achieve good results or even computational stability when using coarse grids due to large numerical diffusion. In this paper, the MUSCL (Monotone Upstream-centered Schemes for Conservation Laws) differencing scheme is implemented into KIVA3V-LES code to calculate the convective term. In the meantime, Lu’s n-heptane reduced 58-species mechanisms (Lu, 2011) is used to calculate chemistry with a parallel algorithm. Finally, improved models for spray injection are also employed. With these improvements, the KIVA3V-LES code is renamed as KIVALES-CP (Chemistry with Parallel algorithm) in this study. The resulting code was used to study the gas–liquid two phase jet and combustion under various diesel engine-like conditions in a constant volume vessel. The results show that using the MUSCL scheme can accurately capture the spray shape and fuel vapor penetration using even a coarse grid, in comparison with the Sandia experimental data. Similarly good results are obtained for three single-component fuels, i-Octane (C8H18), n-Dodecanese (C12H26), and n-Hexadecane (C16H34) with very different physical properties. Meanwhile the improved methodology is able to accurately predict ignition delay and flame lift-off length (LOL) under different oxygen concentrations from 10% to 21

  14. Tolerability and effectiveness of liquid nitrogen spray cryotherapy with very short freeze times in the treatment of xanthelasma palpebrarum.

    Science.gov (United States)

    Labandeira, Javier; Vázquez-Osorio, Igor; Figueroa-Silva, Olalla; Pereiro, Manuel; Toribio, Jaime

    2015-01-01

    Xanthelasma are cholesterol-filled, soft, yellow plaques that usually appear on the medial aspects of the eyelids bilaterally. They are always benign lesions so therapy is usually undertaken only for cosmetic reasons. Surgical excision, chemical peeling with tricholoroacetic acid, and laser ablation are commonly used treatments. Liquid nitrogen cryotherapy is a potentially effective but rarely used treatment due to the risk of intense eyelid swelling. We report on our experience with four of our patients, and propose an explanation for the effectiveness of gentle liquid nitrogen spray cryotherapy in xanthelasma. We consider that gentle liquid nitrogen cryotherapy should be used in the treatment of xanthelasma due to the ease of application and low risk of adverse effects. © 2015 Wiley Periodicals, Inc.

  15. Multiphysics modelling of the spray forming process

    International Nuclear Information System (INIS)

    Mi, J.; Grant, P.S.; Fritsching, U.; Belkessam, O.; Garmendia, I.; Landaberea, A.

    2008-01-01

    An integrated, multiphysics numerical model has been developed through the joint efforts of the University of Oxford (UK), University of Bremen (Germany) and Inasmet (Spain) to simulate the spray forming process. The integrated model consisted of four sub-models: (1) an atomization model simulating the fragmentation of a continuous liquid metal stream into droplet spray during gas atomization; (2) a droplet spray model simulating the droplet spray mass and enthalpy evolution in the gas flow field prior to deposition; (3) a droplet deposition model simulating droplet deposition, splashing and re-deposition behavior and the resulting preform shape and heat flow; and (4) a porosity model simulating the porosity distribution inside a spray formed ring preform. The model has been validated against experiments of the spray forming of large diameter IN718 Ni superalloy rings. The modelled preform shape, surface temperature and final porosity distribution showed good agreement with experimental measurements

  16. Spray-on polyvinyl alcohol separators and impact on power production in air-cathode microbial fuel cells with different solution conductivities

    KAUST Repository

    Hoskins, Daniel L.

    2014-11-01

    © 2014 Elsevier Ltd. Separators are used to protect cathodes from biofouling and to avoid electrode short-circuiting, but they can adversely affect microbial fuel cell (MFC) performance. A spray method was used to apply a polyvinyl alcohol (PVA) separator to the cathode. Power densities were unaffected by the PVA separator (339 ± 29 mW/m2), compared to a control lacking a separator in a low conductivity solution (1mS/cm) similar to wastewater. Power was reduced with separators in solutions typical of laboratory tests (7-13 mS/cm), compared to separatorless controls. The PVA separator produced more power in a separator assembly (SEA) configuration (444 ± 8 mW/m2) in the 1mS/cm solution, but power was reduced if a PVA or wipe separator was used in higher conductivity solutions with either Pt or activated carbon catalysts. Spray and cast PVA separators performed similarly, but the spray method is preferred as it was easier to apply and use.

  17. Reduced Gravity Studies of Soret Transport Effects in Liquid Fuel Combustion

    Science.gov (United States)

    Shaw, Benjamin D.

    2004-01-01

    Soret transport, which is mass transport driven by thermal gradients, can be important in practical flames as well as laboratory flames by influencing transport of low molecular weight species (e.g., monatomic and diatomic hydrogen). In addition, gas-phase Soret transport of high molecular weight fuel species that are present in practical liquid fuels (e.g., octane or methanol) can be significant in practical flames (Rosner et al., 2000; Dakhlia et al., 2002) and in high pressure droplet evaporation (Curtis and Farrell, 1992), and it has also been shown that Soret transport effects can be important in determining oxygen diffusion rates in certain classes of microgravity droplet combustion experiments (Aharon and Shaw, 1998). It is thus useful to obtain information on flames under conditions where Soret effects can be clearly observed. This research is concerned with investigating effects of Soret transport on combustion of liquid fuels, in particular liquid fuel droplets. Reduced-gravity is employed to provide an ideal (spherically-symmetrical) experimental model with which to investigate effects of Soret transport on combustion. The research will involve performing reduced-gravity experiments on combustion of liquid fuel droplets in environments where Soret effects significantly influence transport of fuel and oxygen to flame zones. Experiments will also be performed where Soret effects are not expected to be important. Droplets initially in the 0.5 to 1 mm size range will be burned. Data will be obtained on influences of Soret transport on combustion characteristics (e.g., droplet burning rates, droplet lifetimes, gas-phase extinction, and transient flame behaviors) under simplified geometrical conditions that are most amenable to theoretical modeling (i.e., spherical symmetry). The experiments will be compared with existing theoretical models as well as new models that will be developed. Normal gravity experiments will also be performed.

  18. Catalytic pyrolysis of microalgae to high-quality liquid bio-fuels

    NARCIS (Netherlands)

    Babych, Igor V.; van der Hulst, M.; Lefferts, Leonardus; Moulijn, J.A.; Seshan, Kulathuiyer; O'Connor, P.

    2011-01-01

    The pyrolytic conversion of chlorella algae to liquid fuel precursor in presence of a catalyst (Na2CO3) has been studied. Thermal decomposition studies of the algae samples were performed using TGA coupled with MS. Liquid oil samples were collected from pyrolysis experiments in a fixed-bed reactor

  19. Ignition capsules with aerogel-supported liquid DT fuel for the National Ignition Facility

    Directory of Open Access Journals (Sweden)

    Ho D.D.-M.

    2013-11-01

    Full Text Available For high repetition-rate fusion power plant applications, capsules with aerogel-supported liquid DT fuel can have much reduced fill time compared to β-layering a solid DT fuel layer. The melting point of liquid DT can be lowered once liquid DT is embedded in an aerogel matrix, and the DT vapor density is consequently closer to the desired density for optimal capsule design requirement. We present design for NIF-scale aerogel-filled capsules based on 1-D and 2-D simulations. An optimal configuration is obtained when the outer radius is increased until the clean fuel fraction is within 65 – 75% at peak velocity. A scan (in ablator and fuel thickness parameter space is used to optimize the capsule configurations. The optimized aerogel-filled capsule has good low-mode robustness and acceptable high-mode mix.

  20. Droplets Behavior of Hollow-Cone Spray in a Non-Condensable Environment

    International Nuclear Information System (INIS)

    Minoru Takahashi; Shin-ichi Kitagawa; Suizheng Qiu

    2002-01-01

    The characteristics of droplets in a water hollow-cone spray from nozzles 1.1 mm and 3.6 mm in diameter in an air environment have been investigated experimentally. The dual phase Doppler anemometry (PDA) system was used to measure the size and two velocity components of individual spherical particles. The liquid spray geometry, including spray breakup length and spray angle were also obtained experimentally. The mechanism and the influence of these parameters on a hollow cone spray flow were described. (authors)

  1. A Piston Geometry and Nozzle Spray Angle Investigation in a DI Diesel Engine by Quantifying the Air-Fuel Mixture

    Directory of Open Access Journals (Sweden)

    Pavlos Dimitriou

    2015-03-01

    Full Text Available Low temperature diesel combustion has been widely investigated over the last few years for reducing in-cylinder emissions of Direct Injection (DI diesel engines without sacrificing efficiency and fuel consumption. The spatial distribution of the fuel within the combustion chamber and the air-fuel mixing quality are the key factors affecting temperature generation within the cylinder. Avoiding fuel rich areas within the cylinder can significantly reduce the local high temperatures resulting in low NOx formation. This paper investigates the effects of the combustion chamber geometry and spray angle on the air-fuel mixing and emissions formation of a DI diesel engine. A new quantitative factor measuring the air-fuel mixing quality has been adopted in order to analyze and compare air-fuel mixing quality for different piston geometries. The results have shown that pistons with a narrow entrance and a deep combustion re-entrant chamber benefit from increased air-fuel mixtures due to the significantly higher swirl generated within the cylinder. However, the improved air-fuel mixing does not consequently lead to a reduced NOx generation, which is highly affected by the combustion efficiency of the engine.

  2. The effects of liquid-coating mulch spray on growth, yield and undersoil temperature in komatsuna greens (Brassica rapa L.)

    International Nuclear Information System (INIS)

    Sato, T.; Shiobara, Y.; Omori, A.; Yoshino, M.; Kuba, K.; Takada, K.; Ikeda, Y.; Motoki, S.; Ogura, S.; Kudo, M.

    2009-01-01

    This experiment was intended to examine the effects of a black liquid-coating mulch on the growth and yield of komatsuna greens. Four treatments (1, 0.5, 0.25 and 0 L/square m) of spray amount were tested in combination with seeding date (Sep. 21sup(st), Oct. 5sup(th), Oct. 20sup(th) in an open field and the Jan. 22sup(nd) in a plastic film house). As a result, we found this liquid-coating mulch increased yields of komatsuna greens, unrelated to the spray amount. Generally, the daily highest soil temperature (-5 cm) under the mulching exceeded the control in every treatment however the daily lowest temperature was less than control except in the case of seeding at Sep. 21sup(st). These phenomena were remarkable in the early stage of growing and the differences in temperature between the control and mulch treatments were reduced during the growth. There was no significant difference in the hourly-integrated temperature during the first 10 days between the 4 treatments on same seeding date. These findings suggest that the expansion of the daily soil temperature range contributed the increased yields of komatsuna greens

  3. Determination of proton conductivity of ionic liquids for fuel cell applications

    Energy Technology Data Exchange (ETDEWEB)

    Wallnofer, E.; Baumgartner, W.R.; Hacker, V. [Graz Univ. of Technology, Graz (Austria). Inst. for Chemistry and Technology of Inorganic Material

    2006-07-01

    Hydrogen fuel cells operating at temperatures of between 100 and 200 degrees C allow the catalyst to tolerate higher levels of carbon monoxide (CO) impurities. However, the number of possible materials for high temperature fuel cell electrolytes or membranes is limited. This study examined the relevant electrochemical properties of different ion liquids with specific reference to neutralized imidazole derivates with a dominant Grotthuss mechanism of proton conduction. The electrochemical stability of the ionic liquids was measured by cyclic voltammetry (CV) under nitrogen. Proton conductivity was measured under hydrogen by CV within the electrochemical limits. Hydrogen was dissolved at the anode, transported through the ionic liquid, and recombined at the cathode, so that the detected current could indicate the amount of transported hydrogen. Electrochemical impedance spectroscopy (EIS) was used to measure the frequency dependent behaviour of the ionic liquids. All measurements were conducted at 50, 100, and 150 degrees C. Results of the study showed that proton conductivity increased with higher temperatures. It was concluded that neutralized imidazole derivates with optimized side chains of the cation may prove to be a viable alternative to conventional fuel cell electrolytes. 4 refs., 2 figs.

  4. Multiplexed electrospray scaling for liquid fuel injection

    International Nuclear Information System (INIS)

    Waits, C Mike; Hanrahan, Brendan; Lee, Ivan

    2010-01-01

    Evaporation and space-charge requirements are evaluated to understand the effect of device scaling and fuel preheating for a liquid fuel injector using a multiplexed electrospray (MES) configuration in compact combustion applications. This work reveals the influence of the droplet diameter, droplet velocity and droplet surface temperature as well as the surrounding gas temperature on the size and performance of microfabricated MES. Measurements from MES devices are used in the model to accurately account for the droplet diameter versus flow rate relationship, the minimum droplet diameter and the relevant droplet velocities. A maximum extractor electrode to ground electrode distance of 3.1 mm required to overcome space-charge forces is found to be independent of voltage or droplet velocity for large levels of multiplexing. This maximum distance also becomes the required evaporation length scale which imposes minimum fuel pre-heating requirements for large flow densities. Required fuel preheating is therefore evaluated for both ethanol and 1-butanol with combustor parameters relevant to fuel reformation, thermoelectric conversion, thermophotovoltaic conversion and thermionic conversion

  5. Further Evaluation of Spray Characterization of Sprayers Typically Used in Vector Control

    Science.gov (United States)

    2012-01-01

    E1260. Standard test method for determining liquid drop size characteristics in a spray using optical nonimaging light-scattering instru- ments...The time that the spray cloud was directed through the optical path of the laser varied between sprayers depending on the width of the spray plume

  6. Effect of fuel injection pressure and injection timing of Karanja biodiesel blends on fuel spray, engine performance, emissions and combustion characteristics

    International Nuclear Information System (INIS)

    Agarwal, Avinash Kumar; Dhar, Atul; Gupta, Jai Gopal; Kim, Woong Il; Choi, Kibong; Lee, Chang Sik; Park, Sungwook

    2015-01-01

    Highlights: • Effect of FIP on microscopic spray characteristics. • Effect of FIP and SOI timing on CRDI engine performance, emissions and combustion. • Fuel injection duration shortened, peak injection rate increased with increasing FIP. • SMD (D 32 ) and AMD (D 10 ) of fuel droplets decreased for lower biodiesel blends. • Increase in biodiesel blend ratio and FIP, fuel injection duration decreased. - Abstract: In this investigation, effect of 10%, 20% and 50% Karanja biodiesel blends on injection rate, atomization, engine performance, emissions and combustion characteristics of common rail direct injection (CRDI) type fuel injection system were evaluated in a single cylinder research engine at 300, 500, 750 and 1000 bar fuel injection pressures at different start of injection timings and constant engine speed of 1500 rpm. The duration of fuel injection slightly decreased with increasing blend ratio of biodiesel (Karanja Oil Methyl Ester: KOME) and significantly decreased with increasing fuel injection pressure. The injection rate profile and Sauter mean diameter (D 32 ) of the fuel droplets are influenced by the injection pressure. Increasing fuel injection pressure generally improves the thermal efficiency of the test fuels. Sauter mean diameter (D 32 ) and arithmetic mean diameter (D 10 ) decreased with decreasing Karanja biodiesel content in the blend and significantly increased for higher blends due to relatively higher fuel density and viscosity. Maximum thermal efficiency was observed at the same injection timing for biodiesel blends and mineral diesel. Lower Karanja biodiesel blends (up to 20%) showed lower brake specific hydrocarbon (BSHC) and carbon monoxide (BSCO) emissions in comparison to mineral diesel. For lower Karanja biodiesel blends, combustion duration was shorter than mineral diesel however at higher fuel injection pressures, combustion duration of 50% blend was longer than mineral diesel. Up to 10% Karanja biodiesel blends in a CRDI

  7. The influence of droplet evaporation on fuel-air mixing rate in a burner

    Science.gov (United States)

    Komiyama, K.; Flagan, R. C.; Heywood, J. B.

    1977-01-01

    Experiments involving combustion of a variety of hydrocarbon fuels in a simple atmospheric pressure burner were used to evaluate the role of droplet evaporation in the fuel/air mixing process in liquid fuel spray flames. Both air-assist atomization and pressure atomization processes were studied; fuel/air mixing rates were determined on the basis of cross-section average oxygen concentrations for stoichiometric overall operation. In general, it is concluded that droplets act as point sources of fuel vapor until evaporation, when the fuel jet length scale may become important in determining nonuniformities of the fuel vapor concentration. In addition, air-assist atomizers are found to have short droplet evaporation times with respect to the duration of the fuel/air mixing process, while for the pressure jet atomizer the characteristic evaporation and mixing times are similar.

  8. Liquid films and droplet deposition in a BWR fuel element

    International Nuclear Information System (INIS)

    Damsohn, M.

    2011-01-01

    In the upper part of boiling water reactors (BWR) the flow regime is dominated by a steam-water droplet flow with liquid films on the nuclear fuel rod, the so called (wispy) annular flow regime. The film thickness and liquid flow rate distribution around the fuel rod play an important role especially in regard to so called dryout, which is the main phenomenon limiting the thermal power of a fuel assembly. The deposition of droplets in the liquid film is important, because this process sustains the liquid film and delays dryout. Functional spacers with different vane shapes have been used in recent decades to enhance droplet deposition and thus create more favorable conditions for heat removal. In this thesis the behavior of liquid films and droplet deposition in the annular flow regime in BWR bundles is addressed by experiments in an adiabatic flow at nearly ambient pressure. The experimental setup consists of a vertical channel with the cross-section resembling a pair of neighboring subchannels of a fuel rod bundle. Within this double subchannel an annular flow is established with a gas-water mixture. The impact of functional spacers on the annular flow behavior is studied closely. Parameter variations comprise gas and liquid flow rates, gas density and spacer shape. The setup is instrumented with a newly developed liquid film sensor that measures the electrical conductance between electrodes flush to the wall with high temporal and spatial resolution. Advanced post-processing methods are used to investigate the dynamic behavior of liquid films and droplet deposition. The topic is also assessed numerically by means of single-phase Reynolds-Averaged-Navier-Stokes CFD simulations of the flow in the gas core. For this the commercial code STAR-CCM+ is used coupled with additional models for the liquid film distribution and droplet motion. The results of the experiments show that the liquid film is quite evenly distributed around the circumference of the fuel rods. The

  9. Fabrication of gas diffusion layer based on x-y robotic spraying technique for proton exchange membrane fuel cell application

    International Nuclear Information System (INIS)

    Sitanggang, Ramli; Mohamad, Abu Bakar; Daud, Wan Ramli Wan; Kadhum, Abdul Amir H.; Iyuke, S.E.

    2009-01-01

    The x-y robotic spraying technique developed in the Universiti Kebangsaan Malaysia is capable of fabricating various sizes of thickness and porosity of gas diffusion layer (GDL) used in the proton exchange membrane fuel cell (PEMFC). These parameters are obtained by varying the characteristic spray numbers of the robotic spraying machine. This investigation results were adequately represented with mathematical equations for hydrogen gas distribution in GDL. Volumetric modulus (M) parameter is used to determine the value of current density produced on the electrode of a single cell PEMFC. Thus the M parameter can be employed as indicator for a successful GDL fabrication. GDL type 4 has three variables of layer design that can be optimized to function as gas distributor, gas storage, flooding preventer on GDL surface, to evacuate water from the electrode and to control the electrical conductivity. The gas distribution in GDL was mathematically represented with average error of 15.5%. The M value of GDL type 4 according to the model was 0.22 cm 3 /s and yielded a current density of 750 A/m 2 .

  10. Liquid Missile Fuels as Means of Chemical Terrorist Attack

    International Nuclear Information System (INIS)

    Superina, V.; Orehovec, Z.

    2007-01-01

    Modern world is faced with numerous terrorist attacks whose goals, methods and means of the conduct are various. It seems that we have entered the era when terrorism, one's own little terrorism, is the easiest and the most painless way of achieving a goal. That is why that such a situation has contributed to the necessity for strengthening individual and collective protection and safety, import and export control, control of the production and illegal sale of the potential means for delivering terrorist act. It has also contributed to the necessity for devising means of the delivery. For more than 10 years, a series of congresses on CB MTS Industry has pointed at chemicals and chemical industry as potential means and targets of terrorism. The specialization and experience of different authors in the field of the missile technology and missile fuels, especially those of Eastern origin, and the threat that was the reality of the war conflicts in 1990s was the reason for making a scientific and expert analysis of the liquid missile fuels as means of terrorism. There are not many experts in the field of NBC protection who are familiar with the toxicity and reaction of liquid missile fuels still lying discarded and unprotected in abandoned barracks all over Europe and Asia. The purpose of this paper is to draw public attention to possible different abuses of liquid missile fuels for a terrorist purpose, as well as to possible consequences and prevention measures against such abuses. (author)

  11. Transient analysis of intermittent multijet sprays

    Energy Technology Data Exchange (ETDEWEB)

    Panao, Miguel R.O.; Moreira, Antonio Luis N. [Universidade Tecnica de Lisboa, IN, Center for Innovation, Technology and Policy Research, Instituto Superior Tecnico, Lisboa (Portugal); Durao, Diamantino G. [Universidade Lusiada, Lisboa (Portugal)

    2012-07-15

    This paper analyzes the transient characteristics of intermittent sprays produced by the single-point impact of multiple cylindrical jets. The aim is to perform a transient analysis of the intermittent atomization process to study the effect of varying the number of impinging jets in the hydrodynamic mechanisms of droplet formation. The results evidence that hydrodynamic mechanisms underlying the physics of ligament fragmentation in 2-impinging jets sprays also apply to sprays produced with more than 2 jets during the main period of injection. Ligaments detaching from the liquid sheet, as well as from its bounding rim, have been identified and associated with distinct droplet clusters, which become more evident as the number of impinging jets increases. Droplets produced by detached ligaments constitute the main spray, and their axial velocity becomes more uniformly distributed with 4-impinging jets because of a delayed ligament fragmentation. Multijet spray dispersion patterns are geometric depending on the number of impinging jets. Finally, an analysis on the Weber number of droplets suggests that multijet sprays are more likely to deposit on interposed surfaces, thus becoming a promising and competitive atomization solution for improving spray cooling. (orig.)

  12. Status and future opportunities for conversion of synthesis gas to liquid energy fuels: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Mills, G. (Delaware Univ., Newark, DE (United States). Center for Catalytic Science and Technology)

    1993-05-01

    The manufacture of liquid energy fuels from syngas (a mixture of H[sub 2] and CO, usually containing CO[sub 2]) is of growing importance and enormous potential because: (1) Abundant US supplies of coal, gas, and biomass can be used to provide the needed syngas. (2) The liquid fuels produced, oxygenates or hydrocarbons, can help lessen environmental pollution. Indeed, oxygenates are required to a significant extent by the Clean Air Act Amendments (CAAA) of 1990. (3) Such liquid synfuels make possible high engine efficiencies because they have high octane or cetane ratings. (4) There is new, significantly improved technology for converting syngas to liquid fuels and promising opportunities for further improvements. This is the subject of this report. The purpose of this report is to provide an account and evaluative assessment of advances in the technology for producing liquid energy fuels from syngas and to suggest opportunities for future research deemed promising for practical processes. Much of the improved technology for selective synthesis of desired fuels from syngas has resulted from advances in catalytic chemistry. However, novel process engineering has been particularly important recently, utilizing known catalysts in new configurations to create new catalytic processes. This report is an update of the 1988 study Catalysts for Fuels from Syngas: New Directions for Research (Mills 1988), which is included as Appendix A. Technology for manufacture of syngas is not part of this study. The manufacture of liquid synfuels is capital intensive. Thus, in evaluating advances in fuels technology, focus is on the potential for improved economics, particularly on lowering plant investment costs. A second important criteria is the potential for environmental benefits. The discussion is concerned with two types of hydrocarbon fuels and three types of oxygenate fuels that can be synthesized from syngas. Seven alternative reaction pathways are involved.

  13. Power generation in fuel cells using liquid methanol and hydrogen peroxide

    Science.gov (United States)

    Narayanan, Sekharipuram R. (Inventor); Valdez, Thomas I. (Inventor); Chun, William (Inventor)

    2002-01-01

    The invention is directed to an encapsulated fuel cell including a methanol source that feeds liquid methanol (CH.sub.3 OH) to an anode. The anode is electrical communication with a load that provides electrical power. The fuel cell also includes a hydrogen peroxide source that feeds liquid hydrogen peroxide (H.sub.2 O.sub.2) to the cathode. The cathode is also in communication with the electrical load. The anode and cathode are in contact with and separated by a proton-conducting polymer electrolyte membrane.

  14. Numerical simulation of the gas-liquid interaction of a liquid jet in supersonic crossflow

    Science.gov (United States)

    Li, Peibo; Wang, Zhenguo; Sun, Mingbo; Wang, Hongbo

    2017-05-01

    The gas-liquid interaction process of a liquid jet in supersonic crossflow with a Mach number of 1.94 was investigated numerically using the Eulerian-Lagrangian method. The KH (Kelvin-Helmholtz) breakup model was used to calculate the droplet stripping process, and the secondary breakup process was simulated by the competition of RT (Rayleigh-Taylor) breakup model and TAB (Taylor Analogy Breakup) model. A correction of drag coefficient was proposed by considering the compressible effects and the deformation of droplets. The location and velocity models of child droplets after breakup were improved according to droplet deformation. It was found that the calculated spray features, including spray penetration, droplet size distribution and droplet velocity profile agree reasonably well with the experiment. Numerical results revealed that the streamlines of air flow could intersect with the trajectory of droplets and are deflected towards the near-wall region after they enter into spray zone around the central plane. The analysis of gas-liquid relative velocity and droplet deformation suggested that the breakup of droplets mainly occurs around the front region of the spray where gathered a large number of droplets with different sizes. The liquid trailing phenomenon of jet spray which has been discovered by the previous experiment was successfully captured, and a reasonable explanation was given based on the analysis of gas-liquid interaction process.

  15. Influence of geometric and hydro-dynamic parameters of injector on calculation of spray characteristics of diesel engines

    Directory of Open Access Journals (Sweden)

    Filipović Ivan

    2011-01-01

    Full Text Available The main role in air/fuel mixture formation at the IC diesel engines has the energy introduced by fuel into the IC engine that is the characteristics of spraying fuel into the combustion chamber. The characteristic can be defined by the spray length, the spray cone angle, the physical and the chemical structure of fuel spray by different sections. Having in mind very complex experimental setups for researching in this field, the mentioned characteristics are mostly analyzed by calculations. There are two methods in the literature, the first based on use of the semi-empirical expressions (correlations and the second, the calculations of spray characteristics by use of very complex mathematical methods. The second method is dominant in the modern literature. The main disadvantage of the calculation methods is a correct definition of real state at the end of the nozzle orifice (real boundary conditions. The majority of the researchers in this field use most frequently the coefficient of total losses inside the injector. This coefficient depends on injector design, as well as depends on the level of fuel energy and fuel energy transformation along the injector. Having in mind the importance of the real boundary conditions, the complex methods for calculation of the fuel spray characteristics should have the calculation of fuel flows inside the injector and the calculation of spray characteristics together. This approach is a very complex numerical problem and there are no existing computer programs with satisfactory calculation results. Analysis of spray characteristics by use of the semi-empirical expressions (correlations is presented in this paper. The special attention is dedicated to the analysis of the constant in the semi-empirical expressions and influence parameters on this constant. Also, the method for definition of realistic boundary condition at the end of the nozzle orifice is presented in the paper. By use of this method completely

  16. Structure of steam water mixture spray

    International Nuclear Information System (INIS)

    Mitsuhashi, Yuki; Mizutani, Hiroya; Sanada, Toshiyuki; Saito, Takayuki

    2008-01-01

    The flow structure of steam and water mixture spray is studied both numerically and experimentally. The velocity and pressure profiles of the single phase flow are calculated using numerical methods. Using calculated flow fields, the droplet behavior is predicted by the one-way interaction model. This numerical analysis clarifies that the droplets are still accelerated after they are sprayed from the nozzle. In the experiments, the spray of the mixture is observed by using ultra high-speed video camera, and the velocity field is measured by using PIV technique. Along with this PIV velocity field measurement, the velocities and diameters of droplets are measured by phase Doppler anemometry. Furthermore, mixing process of steam and water, and atomization process of liquid film are observed through the transparent nozzle. The high-speed photography observation reveals that the flow inside the nozzle forms the annular flow and the most of the liquid film is atomized at the nozzle outlet. Finally, the optimum method of processing mixture of steam and water is proposed. (author)

  17. The Influence Of Mass Fraction Of Dressed Coal On Ignition Conditions Of Composite Liquid Fuel Droplet

    Directory of Open Access Journals (Sweden)

    Shlegel Nikita E.

    2015-01-01

    Full Text Available The laws of condition modification of inert heat and ignition in an oxidant flow of composite liquid fuel droplet were studied by the developed experimental setup. Investigations were for composite liquid fuel composition based on the waste of bituminous and nonbaking coal processing, appropriate carbon dust, water, used motor oil. The characteristics of boundary layer inertia heat of composite liquid fuel droplet, thermal decomposition of coal organic part, the yield of volatiles and evaporation of liquid combustion component, ignition of the gas mixture and coke residue were defined.

  18. Application of TiC reinforced Fe-based coatings by means of High Velocity Air Fuel Spraying

    Science.gov (United States)

    Bobzin, K.; Öte, M.; Knoch, M. A.; Liao, X.; Sommer, J.

    2017-03-01

    In the field of hydraulic applications, different development trends can cause problems for coatings currently used as wear and corrosion protection for piston rods. Aqueous hydraulic fluids and rising raw material prices necessitate the search for alternatives to conventional coatings like galvanic hard chrome or High Velocity Oxygen Fuel (HVOF)-sprayed WC/Co coatings. In a previous study, Fe/TiC coatings sprayed by a HVOF-process, were identified to be promising coating systems for wear and corrosion protection in hydraulic systems. In this feasibility study, the novel High Velocity Air Fuel (HVAF)-process, a modification of the HVOF-process, is investigated using the same feedstock material, which means the powder is not optimized for the HVAF-process. The asserted benefits of the HVAF-process are higher particle velocities and lower process temperatures, which can result in a lower porosity and oxidation of the coating. Further benefits of the HVAF process are claimed to be lower process costs and higher deposition rates. In this study, the focus is set on to the applicability of Fe/TiC coatings by HVAF in general. The Fe/TiC HVAF coating could be produced, successfully. The HVAF- and HVOF-coatings, produced with the same powder, were investigated using micro-hardness, porosity, wear and corrosion tests. A similar wear coefficient and micro-hardness for both processes could be achieved. Furthermore the propane/hydrogen proportion of the HVAF process and its influence on the coating thickness and the porosity was investigated.

  19. Performance analysis of a mixed nitride fuel system for an advanced liquid metal reactor

    International Nuclear Information System (INIS)

    Lyon, W.F.; Baker, R.B.; Leggett, R.D.

    1991-01-01

    In this paper, the conceptual development and analysis of a proposed mixed nitride driver and blanket fuel system for a prototypic advanced liquid metal reactor design is performed. As a first step, an intensive literature survey is completed on the development and testing of nitride fuel systems. Based on the results of this survey, prototypic mixed nitride fuel and blanket pins is designed and analyzed using the SIEX computer code. The analysis predicts that the nitride fuel consistently operated at peak temperatures and cladding strain levels that compared quite favorably with competing fuel designs. These results, along with data available in the literature on nitride fuel performance, indicate that a nitride fuel system should offer enhanced capabilities for advanced liquid metal reactors

  20. Performance analysis of a mixed nitride fuel system for an advanced liquid metal reactor

    International Nuclear Information System (INIS)

    Lyon, W.F.; Baker, R.B.; Leggett, R.D.

    1990-11-01

    The conceptual development and analysis of a proposed mixed nitride driver and blanket fuel system for a prototypic advanced liquid metal reactor design has been performed. As a first step, an intensive literature survey was completed on the development and testing of nitride fuel systems. Based on the results of this survey, prototypic mixed nitride fuel and blanket pins were designed and analyzed using the SIEX computer code. The analysis predicted that the nitride fuel consistently operated at peak temperatures and cladding strain levels that compared quite favorably with competing fuel designs. These results, along with data available in the literature on nitride fuel performance, indicate that a nitride fuel system should offer enhanced capabilities for advanced liquid metal reactors. 13 refs., 10 figs., 2 tabs

  1. Characterization of microstructure and surface properties of hybrid coatings of WC-CoCr prepared by laser heat treatment and high velocity oxygen fuel spraying

    International Nuclear Information System (INIS)

    Zhang Shihong; Cho, Tong-Yul; Yoon, Jae-Hong; Fang, Wei; Song, Ki-O; Li Mingxi; Joo, Yun-Kon; Lee, Chan Gyu

    2008-01-01

    The microstructure and microhardness of high velocity oxygen fuel-sprayed WC-CoCr coatings were comparatively studied both before and after laser heat treatment of the coatings. Optical microscopy, scanning electron microscopy, X-ray diffraction and microhardness testing were applied to investigate the microstructure, phase composition, porosity and microhardness. The results indicate that WC is still present, and W 2 C has appeared, while neither cobalt nor σ-CrCo is detectable. Co 4 W 2 C has appeared in the high velocity oxygen fuel-sprayed coating after laser heat treatment as compared to the coating before laser treatment. The relative content of the W 2 C has not increased with laser treatment, but the laser treatment has essentially eliminated the porosity almost entirely, providing a more homogeneous and densified microstructure. The laser heat treatment has effected the formation of a denser compact coating on the substrate. After laser heat treatment, the thickness of the coating has decreased from 300 μm to 225 μm. This corresponds to an average porosity in the high velocity oxygen fuel-sprayed coating that is approximately five times greater than that in the subsequently laser heat-treated coating. The laser treatment has also resulted in an increased hardness of the coating near the surface, where the average value increased from Hv 0.2 = 1262.4 in the coating before laser heat treatment to Hv 0.2 = 1818.7 after laser heat treatment

  2. Characterization and Performance of a Liquid Hydrocarbon-Fueled Pulse Detonation Rocket Engine

    National Research Council Canada - National Science Library

    Damphousse, Paul

    2001-01-01

    .... The first time use of a new electro-hydraulic liquid fuel injector was demonstrated to produce consistent atomization properties while allowing for varying fuel injection durations at frequencies up to 50 Hz...

  3. Spray combustion of Jet-A and diesel fuels in a constant volume combustion chamber

    International Nuclear Information System (INIS)

    Jing, Wei; Roberts, William L.; Fang, Tiegang

    2015-01-01

    This work investigates the spray combustion of Jet-A fuel in an optical constant-volume combustion chamber under different ambient initial conditions. Ambient temperature was varied at 800 K, 1000 K, and 1200 K and five different ambient O 2 concentrations were used, spanning 10–21%. These ambient conditions can be used to mimic practical diesel engine working conditions under different fuel injection timings and exhaust gas recirculation (EGR) levels. Both transient and quasi-steady state analyses were conducted. The transient analysis focused on the flame development from the beginning to the end of the combustion process, illustrating how the flame structure evolves with time. The quasi-steady state analysis concentrated on the stable flame structure and compared the flame emissions in terms of spatially integrated intensity, flame effective area, and intensity per pixel. The transient analysis was based on measurements using high-speed imaging of both OH ∗ chemiluminescence and broadband natural luminosity (NL). For the quasi-steady state analysis, three flame narrow-band emissions (OH ∗ at 310 nm, Band A at 430 nm and Band B at 470 nm) were captured using an ICCD camera. Based on the current Jet-A data and diesel data obtained from previous experiments, a comparison between Jet-A and diesel was made in terms of flame development during the transient state and spatially integrated intensity, flame effective area, and intensity per pixel during the quasi-steady state. For the transient results, Jet-A shares a similar flame development trend to diesel, but featuring a narrower region of NL and a wider region of OH ∗ with the increase of ambient temperature and O 2 concentration. The soot cloud is oxidized more quickly for Jet-A than diesel at the end of combustion, evident by comparing the area of NL, especially under high O 2 concentration. The quasi-steady state results suggest that soot is oxidized effectively under high O 2 concentration conditions by

  4. Cold Spray for Repair of Magnesium Components

    Science.gov (United States)

    2011-11-01

    Readiness Center East GM General Motors He helium hex-Cr hexavalent chromium HP-Al High Purity Aluminum HVOF High Velocity Oxygen Fuel ID inner...process is the hexavalent chromium (hex-Cr) permissible exposure limit (PEL) as established by the Occupational Safety and Health Administration (OSHA...project related to replacement of hard chrome plating on helicopter dynamic components using HVOF thermal spray coatings. FRC-E has a thermal spray

  5. Renewable liquid transport fuels from microbes and waste resources

    OpenAIRE

    Jenkins, Rhodri

    2014-01-01

    In order to satisfy the global requirement for transport fuel sustainably, renewable liquid biofuels must be developed. Currently, two biofuels dominate the market; bioethanol for spark ignition and biodiesel for compression ignition engines. However, both fuels exhibit technical issues such as low energy density, poor low temperature performance and poor stability. In addition, bioethanol and biodiesel sourced from first generation feedstocks use arable land in competition with food producti...

  6. Method and system for purification of gas/liquid streams for fuel cells or electrolysis cells

    DEFF Research Database (Denmark)

    2013-01-01

    at least one scrubber in the gas/liquid stream at the inlet side of the first electrode of the fuel cell or electrolysis cell; and/or providing at least one scrubber in the gas/liquid stream at the inlet side of the second electrode of the fuel cell or electrolysis cell; and - purifying the gas....../liquid streams towards the first and second electrode; wherein the at least one scrubber in the gas/liquid stream at the inlet side of the first electrode and/or the at least one scrubber in the gas/liquid stream at the inlet side of the second electrode comprises a material suitable as an electrolyte material...... with the at least one scrubber, with the proviso that the fuel cell or electrolysis cell is not a solid oxide cell....

  7. Stationary liquid fuel fast reactor SLFFR – Part I: Core design

    Energy Technology Data Exchange (ETDEWEB)

    Jing, T.; Yang, G.; Jung, Y.S.; Yang, W.S., E-mail: yang494@purdue.edu

    2016-12-15

    Highlights: • An innovative fast reactor concept SLFFR based on liquid metal fuel is proposed for TRU burning. • A compact core design of 1000 MWt SLFFR is developed to achieve a zero conversion ratio and passive safety. • The core size and the control requirement are significantly reduced compared to the conventional solid fuel reactor with same conversion ratio. - Abstract: For effective burning of hazardous transuranic (TRU) elements of used nuclear fuel, a transformational advanced reactor concept named the stationary liquid fuel fast reactor (SLFFR) has been proposed based on a stationary molten metallic fuel. A compact core design of a 1000 MWt SLFFR has been developed using TRU-Ce-Co fuel, Ta-10W fuel container, and sodium coolant. Conservative design approaches have been adopted to stay within the current material performance database. Detailed neutronics and thermal-fluidic analyses have been performed to evaluate the steady-state performance characteristics. The analysis results indicate that the SLFFR of a zero TRU conversion ratio is feasible while satisfying the conservatively imposed thermal design constraints. A theoretical maximum TRU consumption rate of 1.01 kg/day is achieved with uranium-free fuel. Compared to the solid fuel reactors with the same TRU conversion ratio, the core size and the reactivity control requirement are reduced significantly. The primary and secondary control systems provide sufficient shutdown margins, and the calculated reactivity feedback coefficients show that the prompt fuel expansion coefficient is sufficiently negative.

  8. Consequences of metallic fuel-cladding liquid phase attack during over-temperature transient on fuel element lifetime

    International Nuclear Information System (INIS)

    Lahm, C.E.; Koenig, J.F.; Seidel, B.R.

    1990-01-01

    Metallic fuel elements irradiated in EBR-II at temperatures significantly higher than design, causing liquid phase attack of the cladding, were subsequently irradiated at normal operating temperatures to first breach. The fuel element lifetime was compared to that for elements not subjected to the over-temperature transient and found to be equivalent. 1 ref., 3 figs

  9. Universal electrode interface for electrocatalytic oxidation of liquid fuels.

    Science.gov (United States)

    Liao, Hualing; Qiu, Zhipeng; Wan, Qijin; Wang, Zhijie; Liu, Yi; Yang, Nianjun

    2014-10-22

    Electrocatalytic oxidations of liquid fuels from alcohols, carboxylic acids, and aldehydes were realized on a universal electrode interface. Such an interface was fabricated using carbon nanotubes (CNTs) as the catalyst support and palladium nanoparticles (Pd NPs) as the electrocatalysts. The Pd NPs/CNTs nanocomposite was synthesized using the ethylene glycol reduction method. It was characterized using transmission electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, voltammetry, and impedance. On the Pd NPs/CNTs nanocomposite coated electrode, the oxidations of those liquid fuels occur similarly in two steps: the oxidations of freshly chemisorbed species in the forward (positive-potential) scan and then, in the reverse scan (negative-potential), the oxidations of the incompletely oxidized carbonaceous species formed during the forward scan. The oxidation charges were adopted to study their oxidation mechanisms and oxidation efficiencies. The oxidation efficiency follows the order of aldehyde (formaldehyde) > carboxylic acid (formic acid) > alcohols (ethanol > methanol > glycol > propanol). Such a Pd NPs/CNTs nanocomposite coated electrode is thus promising to be applied as the anode for the facilitation of direct fuel cells.

  10. Large eddy simulation of the low temperature ignition and combustion processes on spray flame with the linear eddy model

    Science.gov (United States)

    Wei, Haiqiao; Zhao, Wanhui; Zhou, Lei; Chen, Ceyuan; Shu, Gequn

    2018-03-01

    Large eddy simulation coupled with the linear eddy model (LEM) is employed for the simulation of n-heptane spray flames to investigate the low temperature ignition and combustion process in a constant-volume combustion vessel under diesel-engine relevant conditions. Parametric studies are performed to give a comprehensive understanding of the ignition processes. The non-reacting case is firstly carried out to validate the present model by comparing the predicted results with the experimental data from the Engine Combustion Network (ECN). Good agreements are observed in terms of liquid and vapour penetration length, as well as the mixture fraction distributions at different times and different axial locations. For the reacting cases, the flame index was introduced to distinguish between the premixed and non-premixed combustion. A reaction region (RR) parameter is used to investigate the ignition and combustion characteristics, and to distinguish the different combustion stages. Results show that the two-stage combustion process can be identified in spray flames, and different ignition positions in the mixture fraction versus RR space are well described at low and high initial ambient temperatures. At an initial condition of 850 K, the first-stage ignition is initiated at the fuel-lean region, followed by the reactions in fuel-rich regions. Then high-temperature reaction occurs mainly at the places with mixture concentration around stoichiometric mixture fraction. While at an initial temperature of 1000 K, the first-stage ignition occurs at the fuel-rich region first, then it moves towards fuel-richer region. Afterwards, the high-temperature reactions move back to the stoichiometric mixture fraction region. For all of the initial temperatures considered, high-temperature ignition kernels are initiated at the regions richer than stoichiometric mixture fraction. By increasing the initial ambient temperature, the high-temperature ignition kernels move towards richer

  11. An experimental study of injection and spray characteristics of diesel and gasoline blends on a common rail injection system

    International Nuclear Information System (INIS)

    Han, Dong; Wang, Chunhai; Duan, Yaozong; Tian, Zhisong; Huang, Zhen

    2014-01-01

    The injection and spray characteristics of diesel and gasoline blends are investigated on a common rail injection system. The injection rate, fuel spray evolution process (tip penetration distance, spray cone angle, projected spray area and relative brightness intensity contour) and microscopic droplet features are analyzed. The results show that diesel and gasoline blends have higher volumetric injection rates, earlier starts of injection and shorter injection delays, but little variances are observed in the mass injection rates for different test fuels. Increased gasoline proportion in the test blends causes slightly decreased spray tip penetration distance but increased spray cone angle. Also, more smaller-size droplets are observed in the fuel jet of the diesel and gasoline blends, indicating that the spray breakup and atomization processes are promoted. - Highlights: • Injection rate and spray characteristics of diesel and gasoline blends are studied. • Diesel and gasoline blends have higher volumetric injection rates. • Earlier starts of injection are found when using diesel and gasoline blends. • Diesel and gasoline blends produce shorter spray penetration but higher cone angle. • The number of small droplets increases in the spray of diesel and gasoline blends

  12. Plant for producing an oxygen-containing additive as an ecologically beneficial component for liquid motor fuels

    Science.gov (United States)

    Siryk, Yury Paul; Balytski, Ivan Peter; Korolyov, Volodymyr George; Klishyn, Olexiy Nick; Lnianiy, Vitaly Nick; Lyakh, Yury Alex; Rogulin, Victor Valery

    2013-04-30

    A plant for producing an oxygen-containing additive for liquid motor fuels comprises an anaerobic fermentation vessel, a gasholder, a system for removal of sulphuretted hydrogen, and a hotwell. The plant further comprises an aerobic fermentation vessel, a device for liquid substance pumping, a device for liquid aeration with an oxygen-containing gas, a removal system of solid mass residue after fermentation, a gas distribution device; a device for heavy gases utilization; a device for ammonia adsorption by water; a liquid-gas mixer; a cavity mixer, a system that serves superficial active and dispersant matters and a cooler; all of these being connected to each other by pipelines. The technical result being the implementation of a process for producing an oxygen containing additive, which after being added to liquid motor fuels, provides an ecologically beneficial component for motor fuels by ensuring the stability of composition fuel properties during long-term storage.

  13. Effects of ambient pressure on dynamics of near-nozzle diesel sprays studied by ultrafast x-radiography

    International Nuclear Information System (INIS)

    Cheong, S. K.; Liu, J.; Shu, D.; Wang, J.; Powell, C. F.; Experimental Facilities Division

    2004-01-01

    A time-resolved x-radiographic technique has been employed for measuring the fuel distribution close to a single-hole nozzle fitted in a high-pressure diesel injector. Using a monochromatic synchrotron x-ray beam, it is possible to perform quantitative x-ray absorption measurements and obtain two-dimensional projections of the mass of the fuel spray. We have completed a series of spray measurements in the optically dense, near-nozzle region (ml 15 mm from the nozzle orifice) under ambient pressures of 1, 2, and 5.2 bar Nd2 and 1 bar SFd6 at room temperature with injection pressures of 500 and 1000 bar. The focus of the measurements is on the dynamical behaviors of the fuel jets with an emphasis on their penetration in the near-nozzle region. Careful analysis of the time-resolved, x-radiographic data revealed that the spray penetration in this near-nozzle region was not significantly affected by the limited change of the ambient pressure. In addition, well-defined features of the spray, such as the leading and trailing edges, and fluctuations of fuel mass density in the spray body, allowed us to calculate the leading, trailing, and internal speeds of the sprays

  14. Synergistic routes to liquid fuel for a petroleum-deprived future

    Energy Technology Data Exchange (ETDEWEB)

    Agrawal, R.; Singh, N.R. [Purdue University, West Lafayette, IN (United States). School of Chemical Engineering

    2009-07-15

    When compared with biomass gasification/Fischer-Tropsch synthesis, hydropyrolysis/hydrodeoxygenation (HDO)-based processes have a potential to achieve high biomass carbon conversion to liquid fuel with much lower amounts of supplementary H{sub 2}. On the basis of this observation, we suggest a Hydrogen Bio-oil (H{sub 2}Bioil) process using fast hydropyrolysis/HDO that has a potential to produce nearly double the amount of liquid fuel when compared with the existing biofuel processes while requiring only modest quantities of supplementary H{sub 2}. The optimal operating mode for the H{sub 2}Bioil process is suggested to be in an entrained bed mode in presence of H{sub 2} with gas phase HDO of hydropyrolyzed vapors. A remarkable result due to reduced need for the supplementary H{sub 2} is that it provides synergistic integration of the H(2)Bioil process with a coal gasification power plant or a small scale steam natural gas (NG) reformer leading to a dramatic increase in the liquid fuel production from biomass and coal or NG. Here, hot synthesis gas (T>500{sup o}C) from a coal gasifier or methane reformer supplies H{sub 2}/CO for hydropyrolysis and deoxygenation as well as heat for the process. This result is exciting, because it presents us with an option to build integrated H{sub 2}Bioil processes sooner rather than later when the cost effective H{sub 2}, becomes available from a carbon-free energy source such as solar or nuclear. The H{sub 2}Bioil process and its integrated version with a small scale NG reformer have strong potential to be attractive on a small scale while being more efficient than any current biomass to liquid fuel process in operation.

  15. Study on Electric field assisted low frequency (20 kHz) ultrasonic spray

    Science.gov (United States)

    Chae, Ilkyeong; Seong, Baekhoon; Marten, Darmawan; Byun, Doyoung

    2015-11-01

    Ultrasonic spray is one of the fabulous techniques to discharge small size of droplets because it utilizes ultrasonic vibration on nozzle. However, spray patterns and size of ejected droplet is hardly controlled in conventional ultrasonic spray method. Therefore, here we present electric field assisted ultrasonic spray, which combined conventional technique with electric field in order to control spray pattern and droplet size precisely. Six kinds of various liquid (D.I water, Ethanol, Acetone, Iso-propanol, Toluene, Hexane) with various dielectric constants were used to investigate the mechanism of this method. Also, PIV (Particle Image Velocimetry) was used and various variables were obtained including spray angle, amplitude of liquid vibration, current, and size distribution of ejected droplets. Our electric field assisted ultrasonic spray show that the standard deviation of atomized droplet was decreased up to 39.6%, and it shows the infinite possibility to be utilized in various applications which require precise control of high transfer efficiency. This work was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2014-023284).

  16. Fine Sprays for Disinfection within Healthcare

    Directory of Open Access Journals (Sweden)

    G Nasr

    2016-09-01

    Full Text Available Problems exist worldwide with Hospital Acquired Infections (HAI's. The Spray Research Group (SRG have been working with relevant industries in developing a product which can provide a delivery system for treatment chemicals for surfaces, including the design and testing of a novel Spill-Return Atomiser (SRA for this purpose. A comprehensive description of this atomiser has already been given. This paper reports on a new application of this atomiser and discusses the problem of spray coating for disinfection that has been considered very little in previous work. The related spray coating performance tests in developing the product are thus provided. The experimental work includes determining the required spray duration and the coverage area produced by different sprays, including the analysis of the effects of atomiser positions, configurations, and the required number of atomisers. Comparison is made with the efficacy of an ultrasonic gas atomiser that is currently used for this purpose. The investigation has found that the utilisation of fine sprays (10μm>D32>25μm at high liquid pressure (<12MPa and low flow rates (<0.3 l/min is suitable for surface disinfection in healthcare applications (i.e. MRSA, VRSA etc.

  17. Physical characterization of biomass-based pyrolysis liquids. Application of standard fuel oil analyses

    Energy Technology Data Exchange (ETDEWEB)

    Oasmaa, A; Leppaemaeki, E; Koponen, P; Levander, J; Tapola, E [VTT Energy, Espoo (Finland). Energy Production Technologies

    1998-12-31

    The main purpose of the study was to test the applicability of standard fuel oil methods developed for petroleum-based fuels to pyrolysis liquids. In addition, research on sampling, homogeneity, stability, miscibility and corrosivity was carried out. The standard methods have been tested for several different pyrolysis liquids. Recommendations on sampling, sample size and small modifications of standard methods are presented. In general, most of the methods can be used as such but the accuracy of the analysis can be improved by minor modifications. Fuel oil analyses not suitable for pyrolysis liquids have been identified. Homogeneity of the liquids is the most critical factor in accurate analysis. The presence of air bubbles may disturb in several analyses. Sample preheating and prefiltration should be avoided when possible. The former may cause changes in the composition and structure of the pyrolysis liquid. The latter may remove part of organic material with particles. The size of the sample should be determined on the basis of the homogeneity and the water content of the liquid. The basic analyses of the Technical Research Centre of Finland (VTT) include water, pH, solids, ash, Conradson carbon residue, heating value, CHN, density, viscosity, pourpoint, flash point, and stability. Additional analyses are carried out when needed. (orig.) 53 refs.

  18. 16 CFR 309.15 - Posting of non-liquid alternative vehicle fuel rating.

    Science.gov (United States)

    2010-01-01

    ... rating. (a) If you are a retailer who offers for sale or sells non-liquid alternative vehicle fuel (other... fuel. If you are a retailer who offers for sale or sells electricity to consumers through an electric... vehicle fuel dispensing system, either by letter or on the delivery ticket or other paper, or by a...

  19. Modeling the influence of nozzle-generated turbulence on diesel sprays

    Energy Technology Data Exchange (ETDEWEB)

    Magnotti, G M; Matusik, K E; Duke, D J; Knox, B W; Martinez, G L; Powell, C F; Kastengren, A L; Genzale, C L

    2017-05-18

    The physical mechanisms governing spray breakup in direct injection engines, such as aerodynamic induced instabilities and nozzle-generated cavitation and turbulence, are not well understood due to the experimental and computational limitations in resolving these processes. Recent x-ray and visible extinction measurements have been con-ducted with a targeted interest in the spray formation region in order to characterize the distribution of droplet sizes throughout the spray. Detailed analysis of these measurements shows promise of yielding insight into likely mechanisms governing atomization, which can inform the improvement of spray models for engine computational fluid dynamic (CFD) codes. In order to investigate potential atomization mechanisms, we employ a joint experimental and computational approach to characterize the structure of the spray formation region using the Engine Combustion Network Spray D injector. X-ray tomography, radiography and ultra-small angle x-ray scattering measurements conducted at the Advanced Photon Source at Argonne National Laboratory quantify the injector geometry, liquid fuel mass and Sauter mean diameter (SMD) distributions under non-vaporizing conditions. Diffused back-illumination imaging measurements, conducted at the Georgia Institute of Technology, characterize the asymmetry of the spray structure. The selected range of injection pressures (50 – 150 MPa) and ambient densities (1.2 – 22.8 kg/m3) allow for the influence of aerodynamic forces on the spray to be studied in a controlled and systematic manner, while isolating the atomization process from the effects of vaporization. In comparison to high ambient density conditions, the spray is observed to be more asymmetric at low ambient density conditions. Although several mechanisms may cause asymmetries in the nozzle exit flow conditions and ultimately the spray distribution, irregularities in the internal nozzle geometry were identified, suggesting an increased

  20. Polystyrene Plastic Waste Conversion into Liquid Fuel with Catalytic Cracking Process Using Al2O3 as Catalyst

    Directory of Open Access Journals (Sweden)

    Nurul Kholidah

    2018-01-01

    Full Text Available The increase in energy consumption and an increase in the plastic waste generation are two major problems that arise along with economic growth and the increase in population. Styrofoam is one type of polystyrene plastic waste that can be processed into liquid fuels by cracking process. In this study, the cracking process of polystyrene plastic waste into liquid fuel carried by the catalytic cracking process using Al2O3 as a catalyst. This study aimed to determine the effect of the catalyst weight, length of cracking time and range of temperature in the catalytic cracking process of polystyrene plastic waste into liquid fuel toward the mass and characteristics of liquid fuels produced and to determine the composition of liquid fuels produced. The catalytic cracking process of polystyrene plastic waste with catalyst was done in the fixed bed type reactor by heating the reactor with a heater, where the process took place at temperature of 150°C, 200°C, 250°C and 300°C and the length of the process was varied into 20, 40, and 60 minutes and the catalyst weight was also varied, which were 4%, 6% and 8%, while the styrofoam weight was 250 grams. From the research, the highest mass of liquid fuel derived from polystyrene catalytic cracking process was in the amount of 48.8 grams and liquid yield percentage of 19.5% at temperature of  250°C, cracking time of 60 minutes and weight of 8% catalyst, while the characteristics of liquid fuel that were approaching the characteristics of gasoline was at temperatures of 250°C, cracking time of 60 minutes and weight of 6% catalyst, in which each value of density of 0.763 g/ml, specific gravity of 0.778 and oAPI gravity of 50.2. While other liquid fuels obtained from the cracking of polystyrene were still within the tolerance range characteristic properties of gasoline. Liquid fuels produced from the catalytic cracking process was analyzed using a GC-MS, in which the analysis results indicated that liquid

  1. Plasma sprayed and electrospark deposited zirconium metal diffusion barrier coatings

    International Nuclear Information System (INIS)

    Hollis, Kendall J.; Pena, Maria I.

    2010-01-01

    Zirconium metal coatings applied by plasma spraying and electrospark deposition (ESD) have been investigated for use as diffusion barrier coatings on low enrichment uranium fuel for research nuclear reactors. The coatings have been applied to both stainless steel as a surrogate and to simulated nuclear fuel uranium-molybdenum alloy substrates. Deposition parameter development accompanied by coating characterization has been performed. The structure of the plasma sprayed coating was shown to vary with transferred arc current during deposition. The structure of ESD coatings was shown to vary with the capacitance of the deposition equipment.

  2. Fluctuations of a spray generated by an airblast atomizer

    Energy Technology Data Exchange (ETDEWEB)

    Batarseh, Feras Z.; Gnirss, Markus; Roisman, Ilia V.; Tropea, Cameron [Technische Universitaet Darmstadt (Germany). Chair of Fluid Mechanics and Aerodynamics

    2009-06-15

    This paper is devoted to the study of the aerodynamic instability of the spray generated by an airblast atomizer. As a result of this instability the spray shape and its velocity fluctuate with a certain frequency, which depends on the operational parameters of the atomizer. The effect of three parameters, namely; chamber pressure, liquid phase flow rate and the gas phase flow rate on the spray fluctuating frequency are investigated. The velocity vector of the drops in the spray and the arrival times to the detection volume are measured using the laser Doppler instrument. The slotting technique is applied to the data of axial velocity and arrival times of the drops in order to estimate the dominating spray frequencies. Additionally, the shape of the spray has been observed using the high-speed video system. The frequencies of the shape fluctuations are estimated using proper orthogonal decomposition of the time-resolved images of the spray. We show that the frequencies of the spray velocity and those exhibited by spray shape coincide over a wide range of spray parameters. Finally, a simple scaling for the spray frequency is proposed and validated by the experimental data. (orig.)

  3. Numerical study on heat transfer characteristics of liquid-fueled molten salt using OpenFOAM

    International Nuclear Information System (INIS)

    Jeong, Yeong Shin; Bang, In Cheol

    2017-01-01

    To pursue sustainability and safety enhancement of nuclear energy, molten salt reactor is regarded as a promising candidate among various types of gen-IV reactors. Besides, pyroprocessing, which treats molten salt containing fission products, should consider safety related to decay heat from fuel material. For design of molten salt-related nuclear system, it is required to consider both thermal-hydraulic characteristics and neutronic behaviors for demonstration. However, fundamental heat transfer study of molten salt in operation condition is not easy to be experimentally studied due to its large scale, high temperature condition as well as difficulties of treating fuel material. >From that reason, numerical study can have benefit to investigate behaviors of liquid-fueled molten salt in real condition. In this study, open source CFD package OpenFOAM was used to analyze liquid-fueled molten salt loop having internal heat source as a first step of research. Among various molten salts considered as a candidate of liquid fueled molten salt reactors, in this study, FLiBe was chosen as liquid salt. For simulating heat generation from fuel material within fluid flow, volumetric heat source was set for fluid domain and OpenFOAM solver was modified as fvOptions as customized. To investigate thermal-hydraulic behavior of molten salt, CFD model was developed and validated by comparing experimental results in terms of heat transfer and pressure drop. As preliminary stage, 2D cavity simulations were performed to validate the modeling capacity of modified solver of OpenFOAM by comparison with those of ANSYS-CFX. In addition, cases of external heat flux and internal heat source were compared to configure the effect of heat source setting in various operation condition. As a result, modified solver of OpenFOAM considering internal heat source have sufficient modeling capacity to simulate liquid-fueled molten salt systems including heat generation cases. (author)

  4. Identification of multiply charged proteins and amino acid clusters by liquid nitrogen assisted spray ionization mass spectrometry.

    Science.gov (United States)

    Kumar Kailasa, Suresh; Hasan, Nazim; Wu, Hui-Fen

    2012-08-15

    The development of liquid nitrogen assisted spray ionization mass spectrometry (LNASI MS) for the analysis of multiply charged proteins (insulin, ubiquitin, cytochrome c, α-lactalbumin, myoglobin and BSA), peptides (glutathione, HW6, angiotensin-II and valinomycin) and amino acid (arginine) clusters is described. The charged droplets are formed by liquid nitrogen assisted sample spray through a stainless steel nebulizer and transported into mass analyzer for the identification of multiply charged protein ions. The effects of acids and modifier volumes for the efficient ionization of the above analytes in LNASI MS were carefully investigated. Multiply charged proteins and amino acid clusters were effectively identified by LNASI MS. The present approach can effectively detect the multiply charged states of cytochrome c at 400 nM. A comparison between LNASI and ESI, CSI, SSI and V-EASI methods on instrumental conditions, applied temperature and observed charge states for the multiply charged proteins, shows that the LNASI method produces the good quality spectra of amino acid clusters at ambient conditions without applied any electric field and heat. To date, we believe that the LNASI method is the most simple, low cost and provided an alternative paradigm for production of multiply charged ions by LNASI MS, just as ESI-like ions yet no need for applying any electrical field and it could be operated at low temperature for generation of highly charged protein/peptide ions. Copyright © 2012 Elsevier B.V. All rights reserved.

  5. Developments in the formulation and delivery of spray dried vaccines

    NARCIS (Netherlands)

    Kanojia, Gaurav; Have, Rimko Ten; Soema, Peter C; Frijlink, Henderik; Amorij, Jean-Pierre; Kersten, Gideon

    2017-01-01

    Spray drying is a promising method for the stabilization of vaccines, which are usually formulated as liquids. Usually, vaccine stability is improved by spray drying in the presence of a range of excipients. Unlike freeze drying, there is no freezing step involved, thus the damage related to this

  6. Phase change predictions for liquid fuel in contact with steel structure using the heat conduction equation

    Energy Technology Data Exchange (ETDEWEB)

    Brear, D.J. [Power Reactor and Nuclear Fuel Development Corp., Oarai, Ibaraki (Japan). Oarai Engineering Center

    1998-01-01

    When liquid fuel makes contact with steel structure the liquid can freeze as a crust and the structure can melt at the surface. The melting and freezing processes that occur can influence the mode of fuel freezing and hence fuel relocation. Furthermore the temperature gradients established in the fuel and steel phases determine the rate at which heat is transferred from fuel to steel. In this memo the 1-D transient heat conduction equations are applied to the case of initially liquid UO{sub 2} brought into contact with solid steel using up-to-date materials properties. The solutions predict criteria for fuel crust formation and steel melting and provide a simple algorithm to determine the interface temperature when one or both of the materials is undergoing phase change. The predicted steel melting criterion is compared with available experimental results. (author)

  7. Phase change predictions for liquid fuel in contact with steel structure using the heat conduction equation

    International Nuclear Information System (INIS)

    Brear, D.J.

    1998-01-01

    When liquid fuel makes contact with steel structure the liquid can freeze as a crust and the structure can melt at the surface. The melting and freezing processes that occur can influence the mode of fuel freezing and hence fuel relocation. Furthermore the temperature gradients established in the fuel and steel phases determine the rate at which heat is transferred from fuel to steel. In this memo the 1-D transient heat conduction equations are applied to the case of initially liquid UO 2 brought into contact with solid steel using up-to-date materials properties. The solutions predict criteria for fuel crust formation and steel melting and provide a simple algorithm to determine the interface temperature when one or both of the materials is undergoing phase change. The predicted steel melting criterion is compared with available experimental results. (author)

  8. Spray drying of fruit and vegetable juices--a review.

    Science.gov (United States)

    Verma, Anjali; Singh, Satya Vir

    2015-01-01

    The main cause of spray drying is to increase the shelf life and easy handling of juices. In the present paper, the studies carried out so far on spray drying of various fruits and vegetables are reported. The major fruit juices dried are mango, banana, orange, guava, bayberry, watermelon, pineapple, etc. However, study on vegetable juices is limited. In spray drying, the major optimized parameters are inlet air temperature, relative humidity of air, outlet air temperature, and atomizer speed that are given for a particular study. The juices in spray drying require addition of drying agents that include matlodextrin, liquid glucose, etc. The drying agents are added to increase the glass transition temperature. Different approaches for spray dryer design have also been discussed in the present work.

  9. Experimental Assessment of the Mass of Ash Residue During the Burning of Droplets of a Composite Liquid Fuel

    Science.gov (United States)

    Glushkov, D. O.; Zakharevich, A. V.; Strizhak, P. A.; Syrodoi, S. V.

    2018-05-01

    An experimental study has been made of the regularities of burning of single droplets of typical compositions of a composite liquid fuel during the heating by an air flow with a varied temperature (600-900 K). As the basic components of the compositions of the composite liquid fuel, use was made of the: waste of processing (filter cakes) of bituminous coals of ranks K, C, and T, waste motor, turbine, and transformer oils, process mixture of mazut and oil, heavy crude, and plasticizer. The weight fraction of a liquid combustible component (petroleum) product) ranged within 0-15%. Consideration has been given to droplets of a composite liquid fuel with dimensions (radius) of 0.5 to 2 mm. Conditions of low-temperature initiation of combustion to ensure a minimum possible mass of solid incombustible residue have been determined. Petroleum products have been singled out whose addition to the composition of the composite liquid fuel tends to increase the ash mass (compared to the corresponding composition without a liquid combustible component). Approximation dependences have been obtained which permit predicting the influence of the concentration of the liquid petroleum product as part of the composite liquid fuel on the ash-residue mass.

  10. Characterizing Dissolved Gases in Cryogenic Liquid Fuels

    Science.gov (United States)

    Richardson, Ian A.

    Pressure-Density-Temperature-Composition (PrhoT-x) measurements of cryogenic fuel mixtures are a historical challenge due to the difficulties of maintaining cryogenic temperatures and precision isolation of a mixture sample. For decades NASA has used helium to pressurize liquid hydrogen propellant tanks to maintain tank pressure and reduce boil off. This process causes helium gas to dissolve into liquid hydrogen creating a cryogenic mixture with thermodynamic properties that vary from pure liquid hydrogen. This can lead to inefficiencies in fuel storage and instabilities in fluid flow. As NASA plans for longer missions to Mars and beyond, small inefficiencies such as dissolved helium in liquid propellant become significant. Traditional NASA models are unable to account for dissolved helium due to a lack of fundamental property measurements necessary for the development of a mixture Equation Of State (EOS). The first PrhoT-x measurements of helium-hydrogen mixtures using a retrofitted single-sinker densimeter, magnetic suspension microbalance, and calibrated gas chromatograph are presented in this research. These measurements were used to develop the first multi-phase EOS for helium-hydrogen mixtures which was implemented into NASA's Generalized Fluid System Simulation Program (GFSSP) to determine the significance of mixture non-idealities. It was revealed that having dissolved helium in the propellant does not have a significant effect on the tank pressurization rate but does affect the rate at which the propellant temperature rises. PrhoT-x measurements are conducted on methane-ethane mixtures with dissolved nitrogen gas to simulate the conditions of the hydrocarbon seas of Saturn's moon Titan. Titan is the only known celestial body in the solar system besides Earth with stable liquid seas accessible on the surface. The PrhoT-x measurements are used to develop solubility models to aid in the design of the Titan Submarine. NASA is currently designing the submarine

  11. Effects of gas liquid ratio on the atomization characteristics of gas-liquid swirl coaxial injectors

    Science.gov (United States)

    Kang, Zhongtao; Li, Qinglian; Zhang, Jiaqi; Cheng, Peng

    2018-05-01

    To understand the atomization characteristics and atomization mechanism of the gas-liquid swirl coaxial (GLSC) injector, a back-lighting photography technique has been employed to capture the instantaneous spray images with a high speed camera. The diameter and velocity of the droplets in the spray have been characterized with a Dantec Phase Doppler Anemometry (PDA) system. The effects of gas liquid ratio (GLR) on the spray pattern, Sauter mean diameter (SMD), diameter-velocity distribution and mass flow rate distribution were analyzed and discussed. The results show that the atomization of the GLSC injector is dominated by the film breakup when the GLR is small, and violent gas-liquid interaction when the GLR is large enough. The film breakup dominated spray can be divided into gas acceleration region and film breakup region while the violent gas-liquid interaction dominated spray can be divided into the gas acceleration region, violent gas-liquid interaction region and big droplets breakup region. The atomization characteristics of the GLSC injector is significantly influenced by the GLR. From the point of atomization performance, the increase of GLR has positive effects. It decreases the global Sauter mean diameter (GSMD) and varies the SMD distribution from a hollow cone shape (GLR = 0) to an inverted V shape, and finally slanted N shape. However, from the point of spatial distribution, the increase of GLR has negative effects, because the mass flow rate distribution becomes more nonuniform.

  12. Liquid waste treatment at plutonium fuels fabrication facility, 2

    International Nuclear Information System (INIS)

    Matsumoto, Ken-ichi; Itoh, Ichiroh; Ohuchi, Jin; Miyo, Hiroaki

    1974-01-01

    The economics in the management of the radioactive liquid waste from Plutonium Fuels Fabrication Facility with sludge-blanket type flocculators has been evaluated. (1) Cost calculation: The cost of chemicals and electricity to treat 1 cubic meter of liquid waste is about 876 yen, while the total operating cost is 250 thousand yen per cubic meter in the case of 140 m 3 /year treatment. These figures are much higher than those for ordinary wastes, due to the particular operation against plutonium. (2) Proposal of the closed system for liquid waste treatment at PFFF: In the case of a closed system using evaporator, ion exchange column and rotary-kiln calciner, the operating cost is estimated at 40 thousand yen per cubic meter of liquid waste. Final radioactivity of treated liquid is below 10 -8 micro curies/ml. (Mori, K.)

  13. Analysis of cyclic variations of liquid fuel-air mixing processes in a realistic DISI IC-engine using Large Eddy Simulation

    International Nuclear Information System (INIS)

    Goryntsev, D.; Sadiki, A.; Klein, M.; Janicka, J.

    2010-01-01

    Direct injection spark ignition (DISI) engines have a large potential to reduce emissions and specific fuel consumption. One of the most important problem in the design of DISI engines is the cycle-to-cycle variations of the flow, mixing and combustion processes. The Large Eddy Simulation (LES) based analysis is used to characterize the cycle-to-cycle fluctuations of the flow field as well as the mixture preparation in a realistic four-stroke internal combustion engine with variable charge motion system. Based on the analysis of cycle-to-cycle velocity fluctuations of in-cylinder flow, the impact of various fuel spray boundary conditions on injection processes and mixture preparation is pointed out. The joint effect of both cycle-to-cycle velocity fluctuations and variable spray boundary conditions is discussed in terms of mean and standard deviation of relative air-fuel ratio, velocity and mass fraction. Finally a qualitative analysis of the intensity of cyclic fluctuations below the spark plug is provided.

  14. Unreviewed safety question evaluation of 100 K West fuel canister gas and liquid sampling

    International Nuclear Information System (INIS)

    Alwardt, L.D.

    1995-01-01

    The purpose of this report is to provide the basis for answers to an Unreviewed Safety Question (USQ) safety evaluation for the gas and liquid sampling activities associated with the fuel characterization program at the 100 K West (KW) fuel storage basin. The scope of this safety evaluation is limited to the movement of canisters between the main storage basin, weasel pit, and south loadout pit transfer channel (also known as the decapping station); gas and liquid sampling of fuel canisters in the weasel pit; mobile laboratory preliminary sample analysis in or near the 105 KW basin building; and the placement of sample containers in an approved shipping container. It was concluded that the activities and potential accident consequences associated with the gas and liquid sampling of 100 KW fuel canisters are bounded by the current safety basis documents and do not constitute an Unreviewed Safety Question

  15. Experimental characterization of gasoline sprays under highly evaporating conditions

    Science.gov (United States)

    Khan, Muhammad Mahabat; Sheikh, Nadeem Ahmed; Khalid, Azfar; Lughmani, Waqas Akbar

    2018-05-01

    An experimental investigation of multistream gasoline sprays under highly evaporating conditions is carried out in this paper. Temperature increase of fuel and low engine pressure could lead to flash boiling. The spray shape is normally modified significantly under flash boiling conditions. The spray plumes expansion along with reduction in the axial momentum causes the jets to merge and creates a low-pressure area below the injector's nozzle. These effects initiate the collapse of spray cone and lead to the formation of a single jet plume or a big cluster like structure. The collapsing sprays reduces exposed surface and therefore they last longer and subsequently penetrate more. Spray plume momentum increase, jet plume reduction and spray target widening could delay or prevent the closure condition and limit the penetration (delayed formation of the cluster promotes evaporation). These spray characteristics are investigated experimentally using shadowgraphy, for five and six hole injectors, under various boundary conditions. Six hole injectors produce more collapsing sprays in comparison to five hole injector due to enhanced jet to jet interactions. The spray collapse tendency reduces with increase in injection pressure due high axial momentum of spray plumes. The spray evaporation rates of five hole injector are observed to be higher than six hole injectors. Larger spray cone angles of the six hole injectors promote less penetrating and less collapsing sprays.

  16. Flow structure of steam-water mixed spray

    International Nuclear Information System (INIS)

    Sanada, Toshiyuki; Mitsuhashi, Yuki; Mizutani, Hiroya; Saito, Takayuki

    2010-01-01

    In this study, the flow structure of a steam-water mixed spray is studied both numerically and experimentally. The velocity and pressure profiles of single-phase flow are calculated using numerical methods. On the basis of the calculated flow fields, the droplet behavior is predicted by a one-way interaction model. This numerical analysis reveals that the droplets are accelerated even after they are sprayed from the nozzle. Experimentally, the mixed spray is observed using an ultra-high-speed video camera, and the velocity field is measured by using the oarticle image velocimetry (PIV) technique. Along with this PIV velocity field measurement, the velocities and diameters of droplets are measured by phase Doppler anemometry. Furthermore, the mixing process of steam and water and the atomization process of a liquid film are observed using a transparent nozzle. High-speed photography observations reveal that the flow inside the nozzle is annular flow and that most of the liquid film is atomized at the nozzle throat and nozzle outlet. Finally, the optimum mixing method for steam and water is determined.

  17. Flow structure of steam-water mixed spray

    Energy Technology Data Exchange (ETDEWEB)

    Sanada, Toshiyuki, E-mail: ttsanad@ipc.shizuoka.ac.j [Department of Mechanical Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Shizuoka (Japan); Mitsuhashi, Yuki; Mizutani, Hiroya; Saito, Takayuki [Department of Mechanical Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Shizuoka (Japan)

    2010-12-15

    In this study, the flow structure of a steam-water mixed spray is studied both numerically and experimentally. The velocity and pressure profiles of single-phase flow are calculated using numerical methods. On the basis of the calculated flow fields, the droplet behavior is predicted by a one-way interaction model. This numerical analysis reveals that the droplets are accelerated even after they are sprayed from the nozzle. Experimentally, the mixed spray is observed using an ultra-high-speed video camera, and the velocity field is measured by using the oarticle image velocimetry (PIV) technique. Along with this PIV velocity field measurement, the velocities and diameters of droplets are measured by phase Doppler anemometry. Furthermore, the mixing process of steam and water and the atomization process of a liquid film are observed using a transparent nozzle. High-speed photography observations reveal that the flow inside the nozzle is annular flow and that most of the liquid film is atomized at the nozzle throat and nozzle outlet. Finally, the optimum mixing method for steam and water is determined.

  18. Soot and liquid-phase fuel distributions in a newly designed optically accessible DI diesel engine

    Science.gov (United States)

    Dec, J. E.; Espey, C.

    1993-10-01

    Two-dimensional (2-D) laser-sheet imaging has been used to examine the soot and liquid-phase fuel distributions in a newly designed, optically accessible, direct-injection diesel engine of the heavy-duty size class. The design of this engine preserves the intake port geometry and basic dimensions of a Cummins N-series production engine. It also includes several unique features to provide considerable optical access. Liquid-phase fuel and soot distribution studies were conducted at a medium speed (1,200 rpm) using a Cummins closed-nozzle fuel injector. The scattering was used to obtain planar images of the liquid-phase fuel distribution. These images show that the leading edge of the liquid-phase portion of the fuel jet reaches a maximum length of 24 mm, which is about half the combustion bowl radius for this engine. Beyond this point virtually all the fuel has vaporized. Soot distribution measurements were made at a high load condition using three imaging diagnostics: natural flame luminosity, 2-D laser-induced incandescence, and 2-D elastic scattering. This investigation showed that the soot distribution in the combusting fuel jet develops through three stages. First, just after the onset of luminous combustion, soot particles are small and nearly uniformly distributed throughout the luminous region of the fuel jet. Second, after about 2 crank angle degrees a pattern develops of a higher soot concentration of larger sized particles in the head vortex region of the jet and a lower soot concentration of smaller sized particles upstream toward the injector. Third, after fuel injection ends, both the soot concentration and soot particle size increase rapidly in the upstream portion of the fuel jet.

  19. Utility industry evaluation of the metal fuel facility and metal fuel performance for liquid metal reactors

    International Nuclear Information System (INIS)

    Burstein, S.; Gibbons, J.P.; High, M.D.; O'Boyle, D.R.; Pickens, T.A.; Pilmer, D.F.; Tomonto, J.R.; Weinberg, C.J.

    1990-02-01

    A team of utility industry representatives evaluated the liquid metal reactor metal fuel process and facility conceptual design being developed by Argonne National Laboratory (ANL) under Department of Energy sponsorship. The utility team concluded that a highly competent ANL team was making impressive progress in developing high performance advanced metal fuel and an economic processing and fabrication technology. The utility team concluded that the potential benefits of advanced metal fuel justified the development program, but that, at this early stage, there are considerable uncertainties in predicting the net overall economic benefit of metal fuel. Specific comments and recommendations are provided as a contribution towards enhancing the development program. 6 refs

  20. FY 2000 report on research and development of combustion technology utilizing microgravity conditions for fuel diversification; 2000 nendo bisho juryoku kankyo wo riyoshita nenryo tayoka nensho gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    This project is aimed at development of optimum combustion technology with diversified fuels, e.g., naphtha and LCO, for gas turbines and others as power sources for topographical energy supply. The combustion under the microgravity is also investigated using the underground facilities at Japan Microgravity Center. Described herein are the FY 2000 results. For construction of combustion model and simulation, the combustion reactions for various liquid fuels are simplified to calculate ignition delay, adiabatic flame temperature and laminar burning velocity with an error less than about 3%. The microgravity combustion experiments are conducted for spray dispersed into a cylinder, to find flame propagation velocities changing with the vaporization characteristics of liquid fuels, and also to construct the combustion models. The premixed turbulent combustion simulation program is developed using a probability density function and analyzed. Development of new combustion technologies includes the study themes of flame propagation and combustion of the air mixture of the multi-component fuel in which the spray exists, combustion characteristics of the droplets of diversified fuels, and combustion of gas turbines with diversified fuels. A propane/air mixture shows different flame propagation characteristics whether it contains kerosene or LCO droplets. The effects of electrical field intensity in the combustion zone on combustion of fuel droplets are elucidated. (NEDO)

  1. Flamelet Generated Manifold Strategies in Modeling of an Igniting Diesel Spray

    NARCIS (Netherlands)

    Bekdemir, C.; Somers, L.M.T.; Goey, de L.P.H.

    2009-01-01

    A study is presented on the modeling of fuel spray combustion in diesel engines. The objective is to model igniting diesel sprays with the detailed chemistry tabulation method FGM (Flamelet GeneratedManifold). The emphasis is on the accurate prediction of auto-ignition as well as the steady

  2. Superheated fuel injection for combustion of liquid-solid slurries

    Science.gov (United States)

    Robben, F.A.

    1984-10-19

    A method and device are claimed for obtaining, upon injection, flash evaporation of a liquid in a slurry fuel to aid in ignition and combustion. The device is particularly beneficial for use of coal-water slurry fuels in internal combustion engines such as diesel engines and gas turbines, and in external combustion devices such as boilers and furnaces. The slurry fuel is heated under pressure to near critical temperature in an injector accumulator, where the pressure is sufficiently high to prevent boiling. After injection into a combustion chamber, the water temperature will be well above boiling point at a reduced pressure in the combustion chamber, and flash boiling will preferentially take place at solid-liquid surfaces, resulting in the shattering of water droplets and the subsequent separation of the water from coal particles. This prevents the agglomeration of the coal particles during the subsequent ignition and combustion process, and reduces the energy required to evaporate the water and to heat the coal particles to ignition temperature. The overall effect will be to accelerate the ignition and combustion rates, and to reduce the size of the ash particles formed from the coal. 2 figs., 2 tabs.

  3. Application of room temperature ionic liquids in advanced fuel cycles RIAR research concept program users

    International Nuclear Information System (INIS)

    Bychkov, Alexander V.; Kormilitsyn, Michael V.; Savochkin, Yuri P.; Osipenko, Alexander G.; Smolensky, Valeri V.; Shadrin, Alexander Yu.; Babain, Vladimir A.

    2005-01-01

    The paper reviews briefly the research program on application of Room Temperature Ionic Liquids (RTILs) in some processes of the nuclear fuel reprocessing, particularly in the uranium-aluminum fuel reprocessing and separation of TPEs and REEs from the PUREX process liquid waste, and approaches to implementation of this program. (author)

  4. Performances and reliability of WC based thermal spray coatings

    International Nuclear Information System (INIS)

    Scrivani, A.; Rosso, M.; Salvarani, L.

    2001-01-01

    Thermal spray processes are used for a lot of traditional and innovative applications and their importance is becoming higher and higher. WC/CoCr based thermal spray coatings represent one of the most important class of coatings that find application in a wide range of industrial sectors. This paper will address a review of current applications and characteristics of this kind of coating. The most important spraying processes, namely HVOF (high velocity oxygen fuel) are examined, the characterization of the coatings from the point of view of corrosion and wear resistance is considered. (author)

  5. Ballistic Imaging and Scattering Measurements for Diesel Spray Combustion: Optical Development and Phenomenological Studies

    Science.gov (United States)

    2016-04-01

    3mm) of diesel sprays from a high-pressure single-hole fuel injector . Ballistic imaging of dodecane and methyl oleate sprays are reported...Porter, Sean P. Duran, Terence E. Parker. Picosecond Ballistic Imaging of Ligament Structures in the Near- Nozzle Region of Diesel Sprays, ILASS...Experiments in Fluids (12 2014) Sean Duran, Jason Porter, Terence Parker. Ballistic Imaging of a Diesel Injector Spray at High Temperature and

  6. Solidification Sequence of Spray-Formed Steels

    Science.gov (United States)

    Zepon, Guilherme; Ellendt, Nils; Uhlenwinkel, Volker; Bolfarini, Claudemiro

    2016-02-01

    Solidification in spray-forming is still an open discussion in the atomization and deposition area. This paper proposes a solidification model based on the equilibrium solidification path of alloys. The main assumptions of the model are that the deposition zone temperature must be above the alloy's solidus temperature and that the equilibrium liquid fraction at this temperature is reached, which involves partial remelting and/or redissolution of completely solidified droplets. When the deposition zone is cooled, solidification of the remaining liquid takes place under near equilibrium conditions. Scanning electron microscopy (SEM) and optical microscopy (OM) were used to analyze the microstructures of two different spray-formed steel grades: (1) boron modified supermartensitic stainless steel (SMSS) and (2) D2 tool steel. The microstructures were analyzed to determine the sequence of phase formation during solidification. In both cases, the solidification model proposed was validated.

  7. Liquid fuels from renewable resources in Canada: systems economics studies

    National Research Council Canada - National Science Library

    Osler, C. F

    1978-01-01

    This paper highlights the methodology and results of a six volume study completed for the Canadian government on alternatives for liquid fuel production from renewable resources after the mid-1980s...

  8. Improvement of the Oxidation Resistance of CoNiCrAlY Bond Coats Sprayed by High Velocity Oxygen-Fuel onto Nickel Superalloy Substrate

    Directory of Open Access Journals (Sweden)

    Alessio Fossati

    2010-11-01

    Full Text Available CoNiCrAlY powders with similar granulometry and chemical composition, but different starting reactivity toward oxygen, were sprayed onto superalloy substrates by High Velocity Oxygen-Fuel producing coatings of similar thicknesses. After spraying, samples were maintained at 1,273 K in air for different test periods of up to 5,000 hours. Morphological, microstructural, compositional and electrochemical analyses were performed on the coated samples in order to assess the high temperature oxidation resistance provided by the two different powders. The powder with higher starting reactivity towards oxygen improves the oxidation resistance of the coated samples by producing thinner and more adherent thermally grown oxide layers.

  9. Liquid fuels production from biomass. Final report, for period ending June 30, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Levy, P. F.; Sanderson, J. E.; Ashare, E.; Wise, D. L.; Molyneaux, M. S.

    1980-01-01

    The current program to convert biomass into liquid hydrocarbon fuels is an extension of a previous program to ferment marine algae to acetic acid. In that study it was found that marine algae could be converted to higher aliphatic organic acids and that these acids could be readily removed from the fermentation broth by membrane or liquid-liquid extraction. It was then proposed to convert these higher organic acids via Kolbe electrolysis to aliphatic hydrocarbons, which may be used as a diesel fuel. The specific goals for the current program are: (1) establish conditions under which substrates other than marine algae may be converted in good yield to organic acids, here the primary task is methane suppression; (2) modify the current 300-liter fixed packed bed batch fermenter to operate in a continuous mode; (3) change from membrane extraction of organic acids to liquid-liquid extraction; (4) optimize the energy balance of the electrolytic oxidation process, the primary task is to reduce the working potential required for the electrolysis while maintaining an adequate current density; (5) scale the entire process up to match the output of the 300 liter fermenter; and (6) design pilot plant and commercial size plant (1000 tons/day) processes for converting biomass to liquid hydrocarbon fuels and perform an economic analysis for the 1000 ton/day design.

  10. Structure of a swirl-stabilized spray flame by imaging, laser Doppler velocimetry, and phase Doppler anemometry

    Science.gov (United States)

    Edwards, C. F.; Rudoff, R. C.

    1991-01-01

    Data are presented which describe the mean structure of a steady, swirl-stabilized, kerosene spray flame in the near-injector region of a research furnace. The data presented include ensemble-averaged results of schlieren, luminosity, and extinction imaging, measurement of the gas phase velocity field by laser Doppler velocimetry, and characterization of the condensed phase velocity by phase Doppler anemometry. The results of these studies define six key regions in the flame: the dense spray region; the rich, two-phase, fuel jet; the main air jet; the internal product recirculation zone; the external product recirculation zone; and the gaseous diffusion flame zone. The first five of these regions form a conical mixing layer which prepares the air and fuel for combustion. The air and fuel jets comprise the central portion of this mixing layer and are bounded on either side by the hot product gases of the internal and external recirculation zones. Entrainment of these product gases into the air/fuel streams provides the energy required to evaporate the fuel spray and initiate combustion. Intermittency of the internal recirculation and spray jet flows accounts for unexpected behavior observed in the aerodynamics of the two phases. The data reported herein are part of the database being accumulated on this spray flame for the purpose of detailed comparison with numerical modeling.

  11. Cyanoborohydride-based ionic liquids as green aerospace bipropellant fuels.

    Science.gov (United States)

    Zhang, Qinghua; Yin, Ping; Zhang, Jiaheng; Shreeve, Jean'ne M

    2014-06-02

    In propellant systems, the most common bipropellants are composed of two chemicals, a fuel (or reducer) and an oxidizer. Currently, the choices for propellant fuels rely mainly on hydrazine and its methylated derivatives, even though they are extremely toxic, highly volatile, sensitive to adiabatic compression (risk of detonation), and, therefore, difficult to handle. With this background, the search for alternative green propellant fuels has been an urgent goal of space science. In this study, a new family of cyanoborohydride-based ionic liquids (ILs) with properties and performances comparable to hydrazine derivatives were designed and synthesized. These new ILs as bipropellant fuels, have some unique advantages including negligible vapor pressure, ultra-short ignition delay (ID) time, and reduced synthetic and storage costs, thereby showing great application potential as environmentally friendly fuels in bipropellant formulations. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Investigation of High Pressure, Multi-Hole Diesel Fuel Injection Using High Speed Imaging

    Science.gov (United States)

    Morris, Steven; Eagle, Ethan; Wooldridge, Margaret

    2012-10-01

    Research to experimentally capture and understand transient fuel spray behavior of modern fuel injection systems remains underdeveloped. To this end, a high-pressure diesel common-rail fuel injector was instrumented in a spherical, constant volume combustion chamber to image the early time history of injection of diesel fuel. The research-geometry fuel injector has four holes aligned on a radial plane of the nozzle with hole sizes of 90, 110, 130 and 150 μm in diameter. Fuel was injected into a non-reacting environment with ambient densities of 17.4, 24.0, and 31.8 kg/m3 at fuel rail pressures of 1000, 1500, and 2000 bar. High speed images of fuel injection were taken using backlighting at 100,000 frames per second (100 kfps) and an image processing algorithm. The experimental results are compared with a one-dimensional fuel-spray model that was historically developed and applied to fuel sprays from single-hole fuel injectors. Fuel spray penetration distance was evaluated as a function of time for the different injector hole diameters, fuel injection pressures and ambient densities. The results show the differences in model predictions and experimental data at early times in the spray development.

  13. Study on initial stage of diesel spray formation. Effects of the condition inside the nozzle sac; Diesel funmu no shoki keisei katei ni kansuru kenkyu. Sac nai nenryo no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Ishikawa, N.; Tsujimura, K. [Nissan Diesel Motor Co. Ltd., Saitama (Japan); Komori, M.

    1996-06-25

    To realize clean diesel exhaust, it is very important to clarify the atomization phenomena of the fuel spray. In this study, the initial stage of the atomization process of a diesel injection fuel spray was analyzed with a high-speed image converter camera under the conditions of atmospheric gas pressure and room temperature. As a result, it was found that the initial spray formation was greatly affected lay the condition inside the nozzle sac. In the case in which fuel existed in the sac, pin-like structure spray formation was observed at the initial injection stage. This phenomenon was not observed in the case in which no fuel was present in the sac, and a widely spread fuel spray formation was observed at the initial injection stage. The relatively low-speed fuel spray injected in the initial low-sac-pressure condition was pushed away by the subsequent fuel spray injected in the high-sac-pressure condition. 7 refs., 12 figs., 1 tab.

  14. Improved inherent safety in liquid fuel reactors

    International Nuclear Information System (INIS)

    Taube, M.

    1982-01-01

    The molten salt reactor system divided into core (thermal and fast) and breeding zone (fission breeder reactor, fusion hybrid system, accelerator-spallation system) has some unique inherent safety properties: a) reduced inventory of fission products during normal operation due to on-line chemical reprocessing and in-core gas purging; b) fast removal of freshly bred fissile nuclides and fission products from the breeding zone (the so called suppressed fission system); c) pressureless fuel and primary coolant system; d) elimination of the possibility of a violent exoenergetic chemical reaction with air, water or metals; e) elimination of the possibility of gaseous hydrogen production during an accident; f) provides a non-engineered feature of dumping of fuel from the core and heat exchanger to a safe drain tank; g) presence of a large heat sink in the form of an inactive diluent salt; h) possibility of natural convection heat removal during an accident and even normal operation (by means of gas lifting); i) dissipation of the remaining decayheat by spraying water on the containment from outside, which allows to manage the worst accident; i) Even in the case of the destruction in the war by conventional or nuclear weapon the contaminated land is significantly reduced. The world-wide present activity in the field of molten salt technology is reviewed. (orig.)

  15. [A microbiological investigation of the effectiveness of Micro Megas E-spray].

    Science.gov (United States)

    Kardel, K; Hegna, I K; Kardel, M

    1976-06-01

    The disinfecting effect of Micro Megas E-spray was tested using a microbiological technique which also included a practical test. Contra-angels and straight handpieces which were sprayed after being used for treatment on patients, and then dried and incubated in a liquid medium, showed a marked growth of microorganisms. The spray had a weak and barely significant growth inhibiting effect on contaminated, simulated instrument surfaces. using Pseudomonas aeruginosa, Escherichia coli and Staphylococcus aureus as test bacteria. It is concluded that the spray is not suitable for distinfection of contra-angels and straight handpieces.

  16. Droplet size effects on NO/x/ formation in a one-dimensional monodisperse spray combustion system

    Science.gov (United States)

    Sarv, H.; Nizami, A. A.; Cernansky, N. P.

    1982-01-01

    A one-dimensional monodisperse aerosol spray combustion facility is described and experimental results of post flame NO/NO(x) emissions are presented. Four different hydrocarbon fuels were studied: isopropanol, methanol, n-heptane, and n-octane. The results indicate an optimum droplet size in the range of 48-58 microns for minimizing NO/NO(x) production for all of the test fuels. This NO(x) behavior is associated with droplet interactions and the transition from diffusive type of spray burning to that of a prevaporized and premixed case. Decreasing the droplet size results in a trend of increasing droplet interactions, which suppresses temperatures and reduces NO(x). This trend continues until prevaporization effects begin to dominate and the system tends towards the premixed limit. The occurrence of the minimum NO(x) point at different droplet diameters for the different fuels appears to be governed by the extent of prevaporization of the fuel in the spray, and is consistent with theoretical calculations based on each fuel's physical properties.

  17. Stationary Liquid Fuel Fast Reactor

    International Nuclear Information System (INIS)

    Yang, Won Sik; Grandy, Andrew; Boroski, Andrew; Krajtl, Lubomir; Johnson, Terry

    2015-01-01

    For effective burning of hazardous transuranic (TRU) elements of used nuclear fuel, a transformational advanced reactor concept named SLFFR (Stationary Liquid Fuel Fast Reactor) was proposed based on stationary molten metallic fuel. The fuel enters the reactor vessel in a solid form, and then it is heated to molten temperature in a small melting heater. The fuel is contained within a closed, thick container with penetrating coolant channels, and thus it is not mixed with coolant nor flow through the primary heat transfer circuit. The makeup fuel is semi- continuously added to the system, and thus a very small excess reactivity is required. Gaseous fission products are also removed continuously, and a fraction of the fuel is periodically drawn off from the fuel container to a processing facility where non-gaseous mixed fission products and other impurities are removed and then the cleaned fuel is recycled into the fuel container. A reference core design and a preliminary plant system design of a 1000 MWt TRU- burning SLFFR concept were developed using TRU-Ce-Co fuel, Ta-10W fuel container, and sodium coolant. Conservative design approaches were adopted to stay within the current material performance database. Detailed neutronics and thermal-fluidic analyses were performed to develop a reference core design. Region-dependent 33-group cross sections were generated based on the ENDF/B-VII.0 data using the MC2-3 code. Core and fuel cycle analyses were performed in theta-r-z geometries using the DIF3D and REBUS-3 codes. Reactivity coefficients and kinetics parameters were calculated using the VARI3D perturbation theory code. Thermo-fluidic analyses were performed using the ANSYS FLUENT computational fluid dynamics (CFD) code. Figure 0.1 shows a schematic radial layout of the reference 1000 MWt SLFFR core, and Table 0.1 summarizes the main design parameters of SLFFR-1000 loop plant. The fuel container is a 2.5 cm thick cylinder with an inner radius of 87.5 cm. The fuel

  18. Stationary Liquid Fuel Fast Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Won Sik [Purdue Univ., West Lafayette, IN (United States); Grandy, Andrew [Argonne National Lab. (ANL), Argonne, IL (United States); Boroski, Andrew [Argonne National Lab. (ANL), Argonne, IL (United States); Krajtl, Lubomir [Argonne National Lab. (ANL), Argonne, IL (United States); Johnson, Terry [Argonne National Lab. (ANL), Argonne, IL (United States)

    2015-09-30

    For effective burning of hazardous transuranic (TRU) elements of used nuclear fuel, a transformational advanced reactor concept named SLFFR (Stationary Liquid Fuel Fast Reactor) was proposed based on stationary molten metallic fuel. The fuel enters the reactor vessel in a solid form, and then it is heated to molten temperature in a small melting heater. The fuel is contained within a closed, thick container with penetrating coolant channels, and thus it is not mixed with coolant nor flow through the primary heat transfer circuit. The makeup fuel is semi- continuously added to the system, and thus a very small excess reactivity is required. Gaseous fission products are also removed continuously, and a fraction of the fuel is periodically drawn off from the fuel container to a processing facility where non-gaseous mixed fission products and other impurities are removed and then the cleaned fuel is recycled into the fuel container. A reference core design and a preliminary plant system design of a 1000 MWt TRU- burning SLFFR concept were developed using TRU-Ce-Co fuel, Ta-10W fuel container, and sodium coolant. Conservative design approaches were adopted to stay within the current material performance database. Detailed neutronics and thermal-fluidic analyses were performed to develop a reference core design. Region-dependent 33-group cross sections were generated based on the ENDF/B-VII.0 data using the MC2-3 code. Core and fuel cycle analyses were performed in theta-r-z geometries using the DIF3D and REBUS-3 codes. Reactivity coefficients and kinetics parameters were calculated using the VARI3D perturbation theory code. Thermo-fluidic analyses were performed using the ANSYS FLUENT computational fluid dynamics (CFD) code. Figure 0.1 shows a schematic radial layout of the reference 1000 MWt SLFFR core, and Table 0.1 summarizes the main design parameters of SLFFR-1000 loop plant. The fuel container is a 2.5 cm thick cylinder with an inner radius of 87.5 cm. The fuel

  19. The thermodynamics of pyrochemical processes for liquid metal reactor fuel cycles

    International Nuclear Information System (INIS)

    Johnson, I.

    1987-01-01

    The thermodynamic basis for pyrochemical processes for the recovery and purification of fuel for the liquid metal reactor fuel cycle is described. These processes involve the transport of the uranium and plutonium from one liquid alloy to another through a molten salt. The processes discussed use liquid alloys of cadmium, zinc, and magnesium and molten chloride salts. The oxidation-reduction steps are done either chemically by the use of an auxiliary redox couple or electrochemically by the use of an external electrical supply. The same basic thermodynamics apply to both the salt transport and the electrotransport processes. Large deviations from ideal solution behavior of the actinides and lanthanides in the liquid alloys have a major influence on the solubilities and the performance of both the salt transport and electrotransport processes. Separation of plutonium and uranium from each other and decontamination from the more noble fission product elements can be achieved using both transport processes. The thermodynamic analysis is used to make process design computations for different process conditions

  20. Synthesis, characterization and application of 1-butyl-3-methylimidazolium tetrafluoroborate for extractive desulfurization of liquid fuel

    Directory of Open Access Journals (Sweden)

    Swapnil A. Dharaskar

    2016-07-01

    Full Text Available In the present paper the experimental data of extractive desulfurization of liquid fuel using 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM]BF4 have been presented. The data of FTIR, 1H NMR and 13C NMR have been discussed for the molecular confirmation of synthesized [BMIM]BF4. Further, the thermal properties, conductivity, solubility, and viscosity analysis of the [BMIM]BF4 were carried out. The effects of reaction time, reaction temperature, sulfur compounds, and recycling of ionic liquid without regeneration on dibenzothiophene removal of liquid fuel were presented. In extractive desulfurization process, the removal of dibenzothiophene in n-dodecane was 73.02% for mass ratio of 1:1 in 30 min at 30 °C under the mild reaction conditions. The ionic liquids could be reused four times without a significant decrease in activity. Also, the desulfurizations of real fuels, multistage extraction were presented. The data and results provided in the present paper explore the significant insights of imidazoled ILs for extractive desulfurization of liquid fuels.

  1. Application of a cold spray technique to the fabrication of a copper canister for the geological disposal of CANDU spent fuels

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Heui-Joo, E-mail: hjchoi@kaeri.re.k [Korea Atomic Energy Research Institute, Radioactive Waste Management Technology Development, 150 Dukjin-dong, Yuseong, Daejon, 305-353 (Korea, Republic of); Lee, Minsoo; Lee, Jong Youl [Korea Atomic Energy Research Institute, Radioactive Waste Management Technology Development, 150 Dukjin-dong, Yuseong, Daejon, 305-353 (Korea, Republic of)

    2010-10-15

    A new method was proposed for the manufacture of a copper-cast iron canister for the spent fuel disposal based on the cold spray coating technique. The thickness of a copper shell could be fabricated to be as thin as 10 mm with the new method. Around 6 tons of copper could be saved with a 10 mm thick canister compared with a 50 mm thick canister. The electrochemical properties of the cold sprayed copper layer and forged copper were measured through a polarization test. The two copper layers showed very similar electrochemical properties. The lifetime of a 10 mm copper canister was estimated with a mathematical model based on the mass transport of sulfide ions through the buffer. The results showed that the canister lifetime was more than 140,000 years under the Korean granite groundwater condition. The thermal analysis with a current pre-conceptual design of a CANDU spent fuel canister showed that the maximum temperature between the canister and the saturated buffer was below the thermal criteria, 100 {sup o}C. Finally, the mechanical stability of the copper canister was confirmed with a computer program, ABAQUS, under the rock movement scenario.

  2. Stationary liquid fuel fast reactor SLFFR — Part II: Safety analysis

    Energy Technology Data Exchange (ETDEWEB)

    Jing, T.; Jung, Y.S.; Yang, W.S., E-mail: yang494@purdue.edu

    2016-12-15

    Highlights: • A multi-channel safety analysis code named MUSA is developed for SLFFR transient analyses. • MUSA is verified against the SYS4A/SASSYS-1 code by simulating the ULOF accident for the advanced burner test reactor. • It is shown that SLFFR has a passive shutdown capability for double-fault, beyond-design-basis accidents UTOP, ULOHS and ULOF. - Abstract: Safety characteristics have been evaluated for the stationary liquid fuel fast reactor (SLFFR) proposed for effective burning of hazardous TRU elements of used nuclear fuel. In order to model the geometrical configuration and reactivity feedback mechanisms unique to SLFFR, a multi-channel safety analysis code named MUSA was developed. MUSA solves the time-dependent coupled neutronics and thermal-fluidic problems. The thermal-fluidic behavior of the core is described by representing the core with one-dimensional parallel channels. The primary heat transport system is modeled by connecting compressible volumes by liquid segments. A point kinetics model with six delayed neutron groups is used to represent the fission power transients. The reactivity feedback is estimated by combining the temperature and density variations of liquid fuel, structural material and sodium coolant with the corresponding axial distributions of reactivity worth in each individual thermal-fluidic channel. Preliminary verification tests with a conventional solid fuel reactor agreed well with the reference solutions obtained with the SAS4A/SASSYS-1 code. Transient analyses of SLFFR were performed for unprotected transient over-power (UTOP), unprotected loss of heat sink (ULOHS) and unprotected loss of flow (ULOF) accidents. The results showed that the thermal expansion of liquid fuel provides sufficiently large negative feedback reactivity for passive shutdown of UTOP and ULOHS. The ULOF transient is also terminated passively with the negative reactivity introduced by the gas expansion modules installed at the core periphery

  3. Chemical Looping Combustion with Different Types of Liquid Fuels Combustion en boucle chimique avec différentes charges liquides

    Directory of Open Access Journals (Sweden)

    Hoteit A.

    2011-02-01

    Full Text Available CLC is a new promising combustion process for CO2 capture with less or even no energy penalty compared to other processes. Up to now, most of the work performed on CLC was conducted with gaseous or solid fuels, using methane and coal and/or pet coke. Liquid fuels such as heavy fuels resulting from oil distillation or conversion may also be interesting feedstocks to consider. However, liquid fuels are challenging feedstock to deal with in fluidized beds. The objective of the present work is therefore to investigate the feasibility of liquid feed injection and contact with oxygen carrier in CLC conditions in order to conduct partial or complete combustion of hydrocarbons. A batch experimental fluidized bed set-up was developed to contact alternatively oxygen carrier with liquid fuels or air. The 20 mm i.d. fluidized bed reactor was filled up with 45 g of NiAl0.44O1.67 and pulses of 1-2 g of liquid were injected in the bed at high temperatures up to 950˚C. Different feedstocks have been injected, from dodecane to heavy fuel oils No.2. Results show that, during the reduction period, it is possible to convert all the fuel injected and there is no coke remaining on particles at the end of the reduction step. Depending upon oxygen available in the bed, either full combustion or partial combustion can be achieved. Similar results were found with different liquid feeds, despite their different composition and properties. Le CLC est un nouveau concept prometteur appliqué à la combustion qui permet le captage de CO en minimisant la pénalité énergétique liée au captage. Jusqu’à présent, l’essentiel des travaux de recherche dans le domaine du CLC concerne les charges gazeuses (méthane et solides (charbon et coke. Les charges liquides, et particulièrement les résidus pétroliers, sont des charges également intéressantes à considérer a priori. La mise en oeuvre de ces charges en lit fluidisé est cependant délicate. L’objet de ce

  4. Liquid Methane Testing With a Large-Scale Spray Bar Thermodynamic Vent System

    Science.gov (United States)

    Hastings, L. J.; Bolshinskiy, L. G.; Hedayat, A.; Flachbart, R. H.; Sisco, J. D.; Schnell. A. R.

    2014-01-01

    NASA's Marshall Space Flight Center conducted liquid methane testing in November 2006 using the multipurpose hydrogen test bed outfitted with a spray bar thermodynamic vent system (TVS). The basic objective was to identify any unusual or unique thermodynamic characteristics associated with densified methane that should be considered in the design of space-based TVSs. Thirteen days of testing were performed with total tank heat loads ranging from 720 to 420 W at a fill level of approximately 90%. It was noted that as the fluid passed through the Joule-Thompson expansion, thermodynamic conditions consistent with the pervasive presence of metastability were indicated. This Technical Publication describes conditions that correspond with metastability and its detrimental effects on TVS performance. The observed conditions were primarily functions of methane densification and helium pressurization; therefore, assurance must be provided that metastable conditions have been circumvented in future applications of thermodynamic venting to in-space methane storage.

  5. High-Performance Molybdenum Coating by Wire–HVOF Thermal Spray Process

    Science.gov (United States)

    Tailor, Satish; Modi, Ankur; Modi, S. C.

    2018-04-01

    Coating deposition on many industrial components with good microstructural, mechanical properties, and better wear resistance is always a challenge for the thermal spray community. A number of thermal spray methods are used to develop such promising coatings for many industrial applications, viz. arc spray, flame spray, plasma, and HVOF. All these processes have their own limitations to achieve porous free, very dense, high-performance wear-resistant coatings. In this work, an attempt has been made to overcome this limitation. Molybdenum coatings were deposited on low-carbon steel substrates using wire-high-velocity oxy-fuel (W-HVOF; WH) thermal spray system (trade name HIJET 9610®). For a comparison, Mo coatings were also fabricated by arc spray, flame spray, plasma spray, and powder-HVOF processes. As-sprayed coatings were analyzed using x-ray diffraction, scanning electron microscopy for phase, and microstructural analysis, respectively. Coating microhardness, surface roughness, and porosity were also measured. Adhesion strength and wear tests were conducted to determine the mechanical and wear properties of the as-sprayed coatings. Results show that the coatings deposited by W-HVOF have better performance in terms of microstructural, mechanical, and wear resistance properties, in comparison with available thermal spray process (flame spray and plasma spray).

  6. Experimental Study on Diesel Spray Characteristics and Autoignition Process

    Directory of Open Access Journals (Sweden)

    Özgür Oğuz Taşkiran

    2011-01-01

    Full Text Available The main goal of this study is to get the temporal and spatial spray evolution under diesel-like conditions and to investigate autoignition process of sprays which are injected from different nozzle geometries. A constant volume combustion chamber was manufactured and heated internally up to 825 K at 3.5 MPa for experiments. Macroscopic properties of diesel spray were recorded via a high-speed CCD camera by using shadowgraphy technique, and the images were analyzed by using a digital image processing program. To investigate the influence of nozzle geometry, 4 different types of divergent, straight, straight-rounded, convergent-rounded nozzles, were manufactured and used in both spray evolution and autoignition experiments. The internal geometry of the injector nozzles were obtained by using silicone mold method. The macroscopic properties of the nozzles are presented in the study. Ignition behaviour of different nozzle types was observed in terms of ignition delay time and ignition location. A commercial Diesel fuel, n-heptane, and a mixture of hexadecane-heptamethylnonane (CN65—cetane number 65 were used as fuels at ignition experiments. The similar macroscopic properties of different nozzles were searched for observing ignition time and ignition location differences. Though spray and ignition characteristics revealed very similar results, the dissimilarities are presented in the study.

  7. Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper

    Science.gov (United States)

    Li, Christina W.; Ciston, Jim; Kanan, Matthew W.

    2014-04-01

    The electrochemical conversion of CO2 and H2O into liquid fuel is ideal for high-density renewable energy storage and could provide an incentive for CO2 capture. However, efficient electrocatalysts for reducing CO2 and its derivatives into a desirable fuel are not available at present. Although many catalysts can reduce CO2 to carbon monoxide (CO), liquid fuel synthesis requires that CO is reduced further, using H2O as a H+ source. Copper (Cu) is the only known material with an appreciable CO electroreduction activity, but in bulk form its efficiency and selectivity for liquid fuel are far too low for practical use. In particular, H2O reduction to H2 outcompetes CO reduction on Cu electrodes unless extreme overpotentials are applied, at which point gaseous hydrocarbons are the major CO reduction products. Here we show that nanocrystalline Cu prepared from Cu2O (`oxide-derived Cu') produces multi-carbon oxygenates (ethanol, acetate and n-propanol) with up to 57% Faraday efficiency at modest potentials (-0.25 volts to -0.5 volts versus the reversible hydrogen electrode) in CO-saturated alkaline H2O. By comparison, when prepared by traditional vapour condensation, Cu nanoparticles with an average crystallite size similar to that of oxide-derived copper produce nearly exclusive H2 (96% Faraday efficiency) under identical conditions. Our results demonstrate the ability to change the intrinsic catalytic properties of Cu for this notoriously difficult reaction by growing interconnected nanocrystallites from the constrained environment of an oxide lattice. The selectivity for oxygenates, with ethanol as the major product, demonstrates the feasibility of a two-step conversion of CO2 to liquid fuel that could be powered by renewable electricity.

  8. Conventional OTSG development for heavy liquid fuel firing in thermal applications

    Energy Technology Data Exchange (ETDEWEB)

    Setchfield, W.P. [Mitchell Engineers Ltd., Glasgow, Scotland (United Kingdom); Roset, J.N. [Total S.A., Paris (France); Schaffer, M. [Total E and P Canada Ltd., Calgary, AB (Canada); O' Connor, D. [MEG Energy Inc., Calgary, AB (Canada); Kense, K. [TIW Western Inc., Calgary, AB (Canada)

    2008-10-15

    The demand for natural gas is expected to increase as a result of future expansion in Canadian extra heavy oil in-situ thermal production, such as steam assisted gravity drainage or SAGD projects. Natural gas is the current predominant fuel utilized for the associated steam generation. Potential natural gas shortages and related price volatility require that operators consider alternative fuels for the projected growth of in-situ thermal production in Alberta. This paper targeted the use of bitumen from upstream sites and derivative residues from upgrading activities as the most convenient alternative fuel sources for thermal operators of established horizontal type gas fired once through steam generators (OTSGs). The paper presented the methodology, the issues associated with bitumen or residue burning and the related technical solutions in developing a multi-fuel OTSG product. The paper provided background information on conventional OTSG design development, conventional OTSG existing deign, and general description of conventional OTSG. The paper also described the configuration of a radiant furnace, convection module, and theories and definitions such as heavy liquid fuels. A description and application of the equipment and processes as well as a presentation of the data and results was then offered. The multi fuel OTSG design is considered to be a practical and workable product capable of firing heavy liquid fuels. However, the design changes have had a significant impact when compared with conventional OTSG boilers. 11 figs.

  9. Application of High-Velocity Oxygen-Fuel (HVOF Spraying to the Fabrication of Yb-Silicate Environmental Barrier Coatings

    Directory of Open Access Journals (Sweden)

    Emine Bakan

    2017-04-01

    Full Text Available From the literature, it is known that due to their glass formation tendency, it is not possible to deposit fully-crystalline silicate coatings when the conventional atmospheric plasma spraying (APS process is employed. In APS, rapid quenching of the sprayed material on the substrate facilitates the amorphous deposit formation, which shrinks when exposed to heat and forms pores and/or cracks. This paper explores the feasibility of using a high-velocity oxygen-fuel (HVOF process for the cost-effective fabrication of dense, stoichiometric, and crystalline Yb2Si2O7 environmental barrier coatings. We report our findings on the HVOF process optimization and its resultant influence on the microstructure development and crystallinity of the Yb2Si2O7 coatings. The results reveal that partially crystalline, dense, and vertical crack-free EBCs can be produced by the HVOF technique. However, the furnace thermal cycling results revealed that the bonding of the Yb2Si2O7 layer to the Silicon bond coat needs to be improved.

  10. Intermittent cryogen spray cooling for optimal heat extraction during dermatologic laser treatment

    Science.gov (United States)

    Majaron, Boris; Svaasand, Lars O.; Aguilar, Guillermo; Nelson, J. Stuart

    2002-09-01

    Fast heat extraction is critically important to obtain the maximal benefit of cryogen spray cooling (CSC) during laser therapy of shallow skin lesions, such as port wine stain birthmarks. However, a film of liquid cryogen can build up on the skin surface, impairing heat transfer due to the relatively low thermal conductivity and higher temperature of the film as compared to the impinging spray droplets. In an attempt to optimize the cryogen mass flux, while minimally affecting other spray characteristics, we apply a series of 10 ms spurts with variable duty cycles. Heat extraction dynamics during such intermittent cryogen sprays were measured using a custom-made metal-disc detector. The highest cooling rates were observed at moderate duty cycle levels. This confirms the presence, and offers a practical way to eliminate the adverse effect of liquid cryogen build-up on the sprayed surface. On the other hand, lower duty cycles allow a substantial reduction in the average rate of heat extraction, enabling less aggressive and more efficient CSC for treatment of deeper targets, such as hair follicles.

  11. Electrochemical testing of suspension plasma sprayed solid oxide fuel cell electrolytes

    Science.gov (United States)

    Waldbillig, D.; Kesler, O.

    Electrochemical performance of metal-supported plasma sprayed (PS) solid oxide fuel cells (SOFCs) was tested for three nominal electrolyte thicknesses and three electrolyte fabrication conditions to determine the effects of electrolyte thickness and microstructure on open circuit voltage (OCV) and series resistance (R s). The measured OCV values were approximately 90% of the Nernst voltages, and electrolyte area specific resistances below 0.1 Ω cm 2 were obtained at 750 °C for electrolyte thicknesses below 20 μm. Least-squares fitting was used to estimate the contributions to R s of the YSZ bulk material, its microstructure, and the contact resistance between the current collectors and the cells. It was found that the 96% dense electrolyte layers produced from high plasma gas flow rate conditions had the lowest permeation rates, the highest OCV values, and the smallest electrolyte-related voltage losses. Optimal electrolyte thicknesses were determined for each electrolyte microstructure that would result in the lowest combination of OCV loss and voltage loss due to series resistance for operating voltages of 0.8 V and 0.7 V.

  12. Implications of electronic short circuiting in plasma sprayed solid oxide fuel cells on electrode performance evaluation by electrochemical impedance spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    White, B.D. [Department of Mechanical Engineering, The University of British Columbia, 2054-6250 Applied Sciences Lane, Vancouver, British Columbia (Canada); Kesler, O. [Department of Mechanical and Industrial Engineering, University of Toronto, 5 King' s College Road, Toronto, Ontario (Canada)

    2008-02-15

    Electronic short circuiting of the electrolyte in a solid oxide fuel cell (SOFC) arising from flaws in the plasma spray fabrication process has been found to have a significant effect on the perceived performance of the electrodes, as evaluated by electrochemical impedance spectroscopy (EIS). The presence of a short circuit has been found to lead to the underestimation of the electrode polarization resistance (R{sub p}) and hence an overestimation of electrode performance. The effect is particularly noticeable when electrolyte resistance is relatively high, for example during low to intermediate temperature operation, leading to an obvious deviation from the expected Arrhenius-type temperature dependence of R{sub p}. A method is developed for determining the real electrode performance from measurements of various cell properties, and strategies for eliminating the occurrence of short circuiting in plasma sprayed cells are identified. (author)

  13. Implications of electronic short circuiting in plasma sprayed solid oxide fuel cells on electrode performance evaluation by electrochemical impedance spectroscopy

    Science.gov (United States)

    White, B. D.; Kesler, O.

    Electronic short circuiting of the electrolyte in a solid oxide fuel cell (SOFC) arising from flaws in the plasma spray fabrication process has been found to have a significant effect on the perceived performance of the electrodes, as evaluated by electrochemical impedance spectroscopy (EIS). The presence of a short circuit has been found to lead to the underestimation of the electrode polarization resistance (R p) and hence an overestimation of electrode performance. The effect is particularly noticeable when electrolyte resistance is relatively high, for example during low to intermediate temperature operation, leading to an obvious deviation from the expected Arrhenius-type temperature dependence of R p. A method is developed for determining the real electrode performance from measurements of various cell properties, and strategies for eliminating the occurrence of short circuiting in plasma sprayed cells are identified.

  14. Platinum catalyst formed on carbon nanotube by the in-liquid plasma method for fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Show, Yoshiyuki; Hirai, Akira; Almowarai, Anas; Ueno, Yutaro

    2015-12-01

    In-liquid plasma was generated in the carbon nanotube (CNT) dispersion fluid using platinum electrodes. The generated plasma spattered the surface of the platinum electrodes and dispersed platinum particles into the CNT dispersion. Therefore, the platinum nanoparticles were successfully formed on the CNT surface in the dispersion. The platinum nanoparticles were applied to the proton exchange membrane fuel cell (PEMFC) as a catalyst. The electrical power of 108 mW/cm{sup 2} was observed from the fuel cell which was assembled with the platinum catalyst formed on the CNT by the in-liquid plasma method. - Highlights: • The platinum catalyst was successfully formed on the CNT surface in the dispersion by the in-liquid plasma method. • The electrical power of 108 mW/cm{sup 2} was observed from the fuel cell which was assembled with the platinum catalyst formed on the CNT by the in-liquid plasma method.

  15. Nanoparticles by spray drying using innovative new technology: the Büchi nano spray dryer B-90.

    Science.gov (United States)

    Li, Xiang; Anton, Nicolas; Arpagaus, Cordin; Belleteix, Fabrice; Vandamme, Thierry F

    2010-10-15

    Spray drying technology is widely known and used to transform liquids (solutions, emulsions, suspension, slurries, pastes or even melts) into solid powders. Its main applications are found in the food, chemical and materials industries to enhance ingredient conservation, particle properties, powder handling and storage etc. However, spray drying can also be used for specific applications in the formulation of pharmaceuticals for drug delivery (e.g. particles for pulmonary delivery). Büchi is a reference in the development of spray drying technology, notably for laboratory scale devices. This study presents the Nano Spray Dryer B-90, a revolutionary new sprayer developed by Büchi, use of which can lower the size of the produced dried particles by an order of magnitude attaining submicron sizes. In this paper, results are presented with a panel of five representative polymeric wall materials (arabic gum, whey protein, polyvinyl alcohol, modified starch, and maltodextrin) and the potentials to encapsulate nano-emulsions, or to formulate nano-crystals (e.g. from furosemide) are also shown. Copyright © 2010 Elsevier B.V. All rights reserved.

  16. Extension of the heat flux method to liquid (bio-)fuels

    Energy Technology Data Exchange (ETDEWEB)

    Meuwissen, R.

    2009-01-15

    The adiabatic burning velocity S{sub L} of a fuel/oxidizer mixture is a key parameter governing many properties of combustion, such as the shape and stabilization of the flame. It can be applied as an input parameter for many combustion models. Furthermore, kinetic schemes can be validated by the use of this parameter. A great extend of research has been performed on determining the adiabatic burning velocities of gaseous fuels. Liquid fuels however, have been examined far less extensive. Literature available shows eminent scatter amongst the data of independent groups and distinctive techniques. The methods used for measuring burning velocities need certain corrections for flame properties which cause additional uncertainties and make the scattering of data not completely unexpected. The heat flux burner used in this work, previously developed at the TU/e, creates a flat flame coherently no corrections for stretch are necessary. Instead, the heat exchange with the burner is considered; by measuring the temperature distribution over the burner plate, the net heat flux of the flame to the burner can be determined. By tuning the unburnt gas velocity until there is no net heat flux, the adiabatic burning velocity is found by interpolation. An extension to the original design, using a vaporized fluid in a carrier gas flow, enables to measure burning velocities of liquid fuels. In the present research, burning velocity measurements have been performed on vaporized ethanol/air flames in order to validate the setup. Similarities with the latest experimental research have been evaluated and good agreement has been found. Furthermore, temperature dependencies have been elucidated and compared to power law correlations stated by this external research. Again, good resemblance can be claimed, although the expanding of certain input parameters on mixture composition could give more solid confirmation. Subsequently, comparison with numerically performed calculations has been

  17. Thermodynamic consequences of sodium spray fires in closed containments. Pt. 1

    International Nuclear Information System (INIS)

    Cherdron, W.

    1985-06-01

    With respect to core disruptive accidents in LMFBR's liquid sodium might be sprayed with high pressure through the head of the tank into oxygen-containing atmosphere. A series of large spray fire experiments has been performed under accident conditions in the FAUNA facility of LAF I in the KfK. The experimental results showed that the overpressure did not exceed 1.8 bar at the experiment, spraying 60 kg Na in 1.5 seconds. (orig.) [de

  18. [Research about effect of spray drying conditions on hygroscopicity of spray dry powder of gubi compound's water extract and its mechanism].

    Science.gov (United States)

    Zong, Jie; Shao, Qi; Zhang, Hong-Qing; Pan, Yong-Lan; Zhu, Hua-Xu; Guo, Li-Wei

    2014-02-01

    To investigate moisture content and hygroscopicity of spray dry powder of Gubi compound's water extract obtained at different spray drying conditions and laying a foundation for spray drying process of Chinese herbal compound preparation. In the paper, on the basis of single-factor experiments, the author choose inlet temperature, liquid density, feed rate, air flow rate as investigated factors. The experimental absorption rate-time curve and scanning electron microscopy results showed that under different spray drying conditions the spray-dried powders have different morphology and different adsorption process. At different spray-dried conditions, the morphology and water content of the powder is different, these differences lead to differences in the adsorption process, at the appropriate inlet temperature and feed rate with a higher sample density and lower air flow rate, in the experimental system the optimum conditions is inlet temperature of 150 degrees C, feed density of 1.05 g x mL(-1), feed rate of 20 mL x min(-1) air flow rate of 30 m3 x h(-1).

  19. Direct Utilization of Liquid Fuels in SOFC for Portable Applications: Challenges for the Selection of Alternative Anodes

    Directory of Open Access Journals (Sweden)

    Massimiliano Cimenti

    2009-06-01

    Full Text Available Solid oxide fuel cells (SOFC have the advantage of being able to operate with fuels other than hydrogen. In particular, liquid fuels are especially attractive for powering portable applications such as small power generators or auxiliary power units, in which case the direct utilization of the fuel would be convenient. Although liquid fuels are easier to handle and transport than hydrogen, their direct use in SOFC can lead to anode deactivation due to carbon formation, especially on traditional nickel/yttria stabilized zirconia (Ni/YSZ anodes. Significant advances have been made in anodic materials that are resistant to carbon formation but often these materials are less electrochemically active than Ni/YSZ. In this review the challenges of using liquid fuels directly in SOFC, in terms of gas-phase and catalytic reactions within the anode chamber, will be discussed and the alternative anode materials so far investigated will be compared.

  20. Fuel production from biomass: generation of liquid biofuels

    Directory of Open Access Journals (Sweden)

    Carmen Ghergheleş

    2008-05-01

    Full Text Available Anaerobic fermentation processes mayalso be used to produce liquid fuels frombiological raw materials. An example is theethanol production from glucose, known asstandard yeast fermentation in the beer, wine andliquor industries. It has to take place in steps, suchthat the ethanol is removed (by distillation ordehydrator application whenever itsconcentration approaches a value (around 12%which would impede reproduction of the yeastculture.

  1. Modeling efficiency and water balance in PEM fuel cell systems with liquid fuel processing and hydrogen membranes

    Science.gov (United States)

    Pearlman, Joshua B.; Bhargav, Atul; Shields, Eric B.; Jackson, Gregory S.; Hearn, Patrick L.

    Integrating PEM fuel cells effectively with liquid hydrocarbon reforming requires careful system analysis to assess trade-offs associated with H 2 production, purification, and overall water balance. To this end, a model of a PEM fuel cell system integrated with an autothermal reformer for liquid hydrocarbon fuels (modeled as C 12H 23) and with H 2 purification in a water-gas-shift/membrane reactor is developed to do iterative calculations for mass, species, and energy balances at a component and system level. The model evaluates system efficiency with parasitic loads (from compressors, pumps, and cooling fans), system water balance, and component operating temperatures/pressures. Model results for a 5-kW fuel cell generator show that with state-of-the-art PEM fuel cell polarization curves, thermal efficiencies >30% can be achieved when power densities are low enough for operating voltages >0.72 V per cell. Efficiency can be increased by operating the reformer at steam-to-carbon ratios as high as constraints related to stable reactor temperatures allow. Decreasing ambient temperature improves system water balance and increases efficiency through parasitic load reduction. The baseline configuration studied herein sustained water balance for ambient temperatures ≤35 °C at full power and ≤44 °C at half power with efficiencies approaching ∼27 and ∼30%, respectively.

  2. Application of Constrained Linear MPC to a Spray Dryer

    DEFF Research Database (Denmark)

    Petersen, Lars Norbert; Poulsen, Niels Kjølstad; Niemann, Hans Henrik

    2014-01-01

    In this paper we develop a linear model predictive control (MPC) algorithm for control of a two stage spray dryer. The states are estimated by a stationary Kalman filter. A non-linear first-principle engineering model is developed to simulate the spray drying process. The model is validated against...... experimental data and able to precisely predict the temperatures, the air humidity and the residual moisture in the dryer. The MPC controls these variables to the target and reject disturbances. Spray drying is a cost-effective method to evaporate water from liquid foods and produces a free flowing powder...

  3. Some aspects of numerical analysis of turbulent gaseous and spray combustion

    International Nuclear Information System (INIS)

    Takagi, T.

    1991-01-01

    In this paper numerical calculations and analysis on turbulent non-premixed gaseous and spray combustion are reviewed. Attentions were paid to the turbulent flow and combustion modeling applicable to predicting the flow, mixing and combustion of gaseous fuels and sprays. Some of the computed results of turbulent gaseous non-premixed (diffusion) flames with and without swirl and transient spray combustion were compared with experimental ones to understand the processes in the flame and to assure how the computations predict the experiments

  4. Spray Characterization of Ultra-Low-Volume Sprayers Typically Used in Vector Control

    Science.gov (United States)

    2009-01-01

    Standard test method for determining liquid drop size characteristics in a spray using optical nonimaging light-scattering instruments. An- nual book of...cloud was directed through the optical path of the laser varied between sprayers, depending on the width of the spray 1 Mention of a trademark

  5. An investigation on effect of geometrical parameters on spray cone angle and droplet size distribution of a two-fluid atomizer

    Energy Technology Data Exchange (ETDEWEB)

    Shafaee, Maziar; Banitabaei, Sayed Abdolhossein; Esfahanian, Vahid; Ashjaee, Mehdi [Tehran University, Tehran (Iran, Islamic Republic of)

    2011-12-15

    A visual study is conducted to determine the effect of geometrical parameters of a two-fluid atomizer on its spray cone angle. The liquid (water) jets exit from six peripheral inclined orifices and are introduced to a high speed gas (air) stream in the gravitational direction. Using a high speed imaging system, the spray cone angle has been determined in constant operational conditions, i.e., Reynolds and Weber numbers for different nozzle geometries. Also, the droplet sizes (Sauter mean diameter) and their distributions have been determined using Malvern Master Sizer x. The investigated geometrical parameters are the liquid jet diameter, liquid port angle and the length of the gas-liquid mixing chamber. The results show that among these parameters, the liquid jet diameter has a significant effect on spray cone angle. In addition, an empirical correlation has been obtained to predict the spray cone angle of the present two-fluid atomizer in terms of nozzle geometries.

  6. Stochastic model of the near-to-injector spray formation assisted by a high-speed coaxial gas jet

    Energy Technology Data Exchange (ETDEWEB)

    Gorokhovski, M [Laboratoire de Mecanique des Fluides et d' Acoustique, CNRS-Ecole Centrale de Lyon-INSA Lyon-Universite Claude Bernard Lyon 1, 36 Avenue Guy de Collongue, 69131 Ecully Cedex (France); Jouanguy, J [Laboratoire de Mecanique de Lille, Ecole Centrale de Lille, Blvd Paul Langevin, 59655 Villeneuve d' Ascq Cedex (France); Chtab-Desportes, A [CD-adapco, 31 rue Delizy 93698 Pantin Cedex (France)], E-mail: mikhael.gorokhovski@ec-lyon.fr

    2009-06-01

    The stochastic model of spray formation in the vicinity of the air-blast atomizer has been described and assessed by comparison with measurements. In this model, the 3D configuration of a continuous liquid core is simulated by spatial trajectories of specifically introduced stochastic particles. The stochastic process is based on the assumption that due to a high Weber number, the exiting continuous liquid jet is depleted in the framework of statistical universalities of a cascade fragmentation under scaling symmetry. The parameters of the stochastic process have been determined according to observations from Lasheras's, Hopfinger's and Villermaux's scientific groups. The spray formation model, based on the computation of spatial distribution of the probability of finding the non-fragmented liquid jet in the near-to-injector region, is combined with the large-eddy simulation (LES) in the coaxial gas jet. Comparison with measurements reported in the literature for different values of the gas-to-liquid dynamic pressure ratio showed that the model predicts correctly the distribution of liquid in the close-to-injector region, the mean length of the liquid core, the spray angle and the typical size of droplets in the far field of spray.

  7. Investigation of the cooling film distribution in liquid rocket engine

    Directory of Open Access Journals (Sweden)

    Luís Antonio Silva

    2011-05-01

    Full Text Available This study presents the results of the investigation of a cooling method widely used in the combustion chambers, which is called cooling film, and it is applied to a liquid rocket engine that uses as propellants liquid oxygen and kerosene. Starting from an engine cooling, whose film is formed through the fuel spray guns positioned on the periphery of the injection system, the film was experimentally examined, it is formed by liquid that seeped through the inner wall of the combustion chamber. The parameter used for validation and refinement of the theoretical penetration of the film was cooling, as this parameter is of paramount importance to obtain an efficient thermal protection inside the combustion chamber. Cold tests confirmed a penetrating cold enough cooling of the film for the length of the combustion chamber of the studied engine.

  8. Study on the spray characteristics of methyl esters from waste cooking oil at elevated temperature

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Yung-Sung [Department of Mechanical and Automation Engineering, Da-Yeh University, 168 University Road, Dacun, Changhua 51591 (China); Department of Mechanical Engineering, Hsiuping Institute of Technology, No.11, Gongye Rd., Dali City, Taichung County 412-80 (China); Lin, Hai-Ping [Department of Mechanical and Automation Engineering, Da-Yeh University, 168 University Road, Dacun, Changhua 51591 (China)

    2010-09-15

    In Taiwan, millions of tons of waste cooking oil are produced each year, and less than 20% of it, about 150,000 ton/a, is reclaimed and reused. Most waste oil is flushed down the drain. Utilizing waste cooking oil to make biodiesel not only reduces engine exhaust gas pollution, but also replaces food-derived fuels, and reduces ecologic river pollution. This study employed two-stage transesterification to lower the high viscosity of waste oil, utilized emulsion to reduce the methyl ester NOx pollution, and used methanol to enhance the stability and viscosity of emulsified fuel. To further analyze spray characteristics of fuels, this experiment built a constant volume bomb under high temperature, used high speed photography to analyze spray tip penetration, spray angle, and the Sauter mean diameter (SMD) of fuel droplets, and compared the results with fossil diesel. The experimental results suggested that, two-stage transesterification can significantly lower waste oil viscosity to that which is close to fossil diesel viscosity. At a temperature above 300 C, waste cooking oil methyl esters had a water content of 20%, spray droplet characteristics were significantly improved, and NOx emission dropped significantly. The optimal fuel ratio suggested in this experiment was waste cooking oil methyl ester 74.5%, methanol 5%, water 20%, and composite surfactant Span-Tween 0.5%. (author)

  9. Design and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air or Liquid Heat Integration

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Kær, Søren Knudsen; Sahlin, Simon Lennart

    2013-01-01

    The present work describes the ongoing development of high temperature PEM fuel cell systems fuelled by steam reformed methanol. Various fuel cell system solutions exist, they mainly differ depending on the desired fuel used. High temperature PEM (HTPEM) fuel cells offer the possibility of using...... methanol is converted to a hydrogen rich gas with CO2 trace amounts of CO, the increased operating temperatures allow the fuel cell to tolerate much higher CO concentrations than Nafion-based membranes. The increased tolerance to CO also enables the use of reformer systems with less hydrogen cleaning steps...... liquid fuels such as methanol, due to the increased robustness of operating at higher temperatures (160-180oC). Using liquid fuels such as methanol removes the high volume demands of compressed hydrogen storages, simplifies refueling, and enables the use of existing fuel distribution systems. The liquid...

  10. High resolution visualization and analysis of nasal spray drug delivery.

    Science.gov (United States)

    Inthavong, Kiao; Fung, Man Chiu; Tong, Xuwen; Yang, William; Tu, Jiyuan

    2014-08-01

    Effective nasal drug delivery of new-generation systemic drugs requires efficient devices that can achieve targeted drug delivery. It has been established that droplet size, spray plume, and droplet velocity are major contributors to drug deposition. Continual effort is needed to better understand and characterise the physical mechanisms underpinning droplet formation from nasal spray devices. High speed laser photography combined with an in-house designed automated actuation system, and a highly precise traversing unit, measurements and images magnified in small field-of-view regions within the spray was performed. The qualitative results showed a swirling liquid sheet at the near-nozzle region as the liquid is discharged before ligaments of fluid are separated off the liquid sheet. Droplets are formed and continue to deform as they travel downstream at velocities of up to 20 m/s. Increase in actuation pressure produces more rapid atomization and discharge time where finer droplets are produced. The results suggest that device designs should consider reducing droplet inertia to penetrate the nasal valve region, but find a way to deposit in the main nasal passage and not escape through to the lungs.

  11. Collection Efficiencies of Various Airborne Spray Flux Samplers Used in Aerial Application Research

    Science.gov (United States)

    2008-01-01

    provided by ASTM Standard E1260: Standard Test Method for Determining Liquid Drop Size Characteristics in a Spray Using Optical Nonimaging Light...Size Characteristics in a Spray Using Optical Nonimaging Light-Scattering Instruments,” Annual Book of ASTM Stan- dards, ASTM International, West

  12. Investigation of the Extinguishing Features for Liquid Fuels and Organic Flammable Liquids Atomized by a Water Flow

    Directory of Open Access Journals (Sweden)

    Voytkov Ivan V.

    2016-01-01

    Full Text Available The processes of heat and mass transfer were investigated experimentally while moving and evaporating the atomized water flow in high-temperature combustion products of typical liquid fuels and organic flammable liquids: gasoline, kerosene, acetone, crude oil, industrial alcohol. We determined typical periods of liquid extinguishing by an atomized water flow of various dispersability. Data of the discharge of extinguishing medium corresponding to various parameters of atomization and duration of using the atomization devices was presented. It is shown that Um≈3.5 m/s is a minimal outflow velocity of droplets during moving while passing the distance of 1m in the high-temperature gas medium to stop the combustion of organic liquids.

  13. Catalytic pyrolysis of microalgae to high-quality liquid bio-fuels

    International Nuclear Information System (INIS)

    Babich, I.V.; Hulst, M. van der; Lefferts, L.; Moulijn, J.A.; O'Connor, P.; Seshan, K.

    2011-01-01

    The pyrolytic conversion of chlorella algae to liquid fuel precursor in presence of a catalyst (Na 2 CO 3 ) has been studied. Thermal decomposition studies of the algae samples were performed using TGA coupled with MS. Liquid oil samples were collected from pyrolysis experiments in a fixed-bed reactor and characterized for water content and heating value. The oil composition was analyzed by GC-MS. Pretreatment of chlorella with Na 2 CO 3 influences the primary conversion of chlorella by shifting the decomposition temperature to a lower value. In the presence of Na 2 CO 3 , gas yield increased and liquid yield decreased when compared with non-catalytic pyrolysis at the same temperatures. However, pyrolysis oil from catalytic runs carries higher heating value and lower acidity. Lower content of acids in the bio-oil, higher aromatics, combined with higher heating value show promise for production of high-quality bio-oil from algae via catalytic pyrolysis, resulting in energy recovery in bio-oil of 40%. -- Highlights: → The pyrolytic catalytic conversion of chlorella algae to liquid fuel precursor. → Na 2 CO 3 as a catalyst for the primary conversion of chlorella. → Pyrolysis oil from catalytic runs carries higher heating value and lower acidity. → High-quality bio-oil from algae via catalytic pyrolysis with energy recovery in bio-oil of 40%.

  14. Processing Adipose-Rich Mohs Samples: A Comparative Study of Effectiveness of Pretreatment With Liquid Nitrogen Versus Flash Freezing Spray.

    Science.gov (United States)

    Reserva, Jeave; Kozel, Zachary; Krol, Cindy; Speiser, Jodi; Adams, William; Tung, Rebecca

    2017-11-01

    Processing of adipose-rich Mohs micrographic surgery (MMS) specimens poses challenges that may preclude complete margin evaluation. In this setting, the value of additional freezing methods using various cooling agents has not been previously investigated. The aim of this study is to compare the frozen section quality of high-adipose Mohs specimens processed without additional cooling treatments versus those pretreated with 1,1,1,2-tetrafluoroethane (TFE) or liquid nitrogen (LN2). A set of 3 sections were each taken from 24 adipose-rich Mohs micrographic surgery specimens. A section from each set was subjected to either no additional cooling treatment (control), two 10-second pulse sprays of 1,1,1,2-tetrafluoroethane, or three 2-second pulse sprays of LN2. After staining, 2 blinded raters evaluated slide quality based on the presence or absence of the following features: margin completeness, nuclear clearing, epidermal or adipose folding, holes, or venetian blind-like artifacts. Pretreatment of the sample with LN2 produced a significantly (P < 0.001) greater number of high-quality slides (19/24) compared to pretreatment with 1,1,1,2-tetrafluoroethane (1/24) and no additional treatment (0/24). The adjunctive use of LN2 spray before tissue embedding circumvents the challenges of processing "thick" (high-adipose) specimens and facilitates the production of high-quality frozen section slides during Mohs micrographic surgery.

  15. High Fidelity Simulation of Atomization in Diesel Engine Sprays

    Science.gov (United States)

    2015-09-01

    state Figure 5. Q criterion isosurface colored by streamwise velocity in the diesel spray injector as viewed from the nozzle exit. Figure 6. U contour...fidelity simulation approach was adopted to study the atom- ization physics of a diesel injector with detailed nozzle internal geometry. The nozzle flow...26; Stanford, CA 14. ABSTRACT A high fidelity numerical simulation of jet breakup and spray formation from a complex diesel fuel injector has been

  16. Nano spray drying for encapsulation of pharmaceuticals.

    Science.gov (United States)

    Arpagaus, Cordin; Collenberg, Andreas; Rütti, David; Assadpour, Elham; Jafari, Seid Mahdi

    2018-05-17

    Many pharmaceuticals such as pills, capsules, or tablets are prepared in a dried and powdered form. In this field, spray drying plays a critical role to convert liquid pharmaceutical formulations into powders. In addition, in many cases it is necessary to encapsulate bioactive drugs into wall materials to protect them against harsh process and environmental conditions, as well as to deliver the drug to the right place and at the correct time within the body. Thus, spray drying is a common process used for encapsulation of pharmaceuticals. In view of the rapid progress of nanoencapsulation techniques in pharmaceutics, nano spray drying is used to improve drug formulation and delivery. The nano spray dryer developed in the recent years provides ultrafine powders at nanoscale and high product yields. In this paper, after explaining the concept of nano spray drying and understanding the key elements of the equipment, the influence of the process parameters on the final powders properties, like particle size, morphology, encapsulation efficiency, drug loading and release, will be discussed. Then, numerous application examples are reviewed for nano spray drying and encapsulation of various drugs in the early stages of product development along with a brief overview of the obtained results and characterization techniques. Copyright © 2018 Elsevier B.V. All rights reserved.

  17. Characterization of viscous biofuel sprays using digital imaging in the near field region

    International Nuclear Information System (INIS)

    Sallevelt, J.L.H.P.; Pozarlik, A.K.; Brem, G.

    2015-01-01

    Highlights: • Biodiesel, vegetable oil and glycerin sprays have been studied using PDIA. • The study is focused on the effect of fuel viscosity on the spray characteristics. • Viscosity has a strong effect on the breakup length in pressure-swirl atomization. • The results are compared to combustion experiments with a micro gas turbine. • The penetration depth of ligaments can be a critical factor in burning viscous fuel. - Abstract: The atomization of biodiesel, vegetable oil and glycerin has been studied in an atmospheric spray rig by using digital imaging (PDIA). Images of the spray were captured in the near field, just 18 mm downstream of the atomizer, and processed to automatically determine the size of both ligaments and droplets. The effect of the spray structure in this region is of major interest for the combustion of biofuels in gas turbines. The sprays were produced by a pressure-swirl atomizer that originates from the multifuel micro gas turbine (MMGT) setup. Various injection conditions have been tested to investigate the influence of viscosity on the spray characteristics and to assess the overall performance of the atomizer. The spray measurements have been compared to combustion experiments with biodiesel and vegetable oil in the micro gas turbine at similar injection conditions. The results show that the primary breakup process rapidly deteriorates when the viscosity is increased. A higher viscosity increases the breakup length, which becomes visible at the measurement location in the form of ligaments. This effect leads to an unacceptable spray quality once the viscosity slightly exceeds the typical range for conventional gas turbine fuels. The SMD in the investigated spray region was not significantly affected by viscosity, but mainly influenced by injection pressure. The data furthermore indicate an increase in SMD with surface tension. It was found that the penetration depth of ligaments can have major impact on the combustion process

  18. Application of sol gel spin coated yttria-stabilized zirconia layers for the improvement of solid oxide fuel cell electrolytes produced by atmospheric plasma spraying

    Energy Technology Data Exchange (ETDEWEB)

    Rose, Lars [University of British Columbia, Department of Materials Engineering, 309-6350 Stores Road, Vancouver, British Columbia, V6T 1Z4 (Canada); National Research Council, Institute for Fuel Cell Innovation, 4250 Wesbrook Mall, Vancouver, British Columbia, V6T 1W5 (Canada); Kesler, Olivera [National Research Council, Institute for Fuel Cell Innovation, 4250 Wesbrook Mall, Vancouver, British Columbia, V6T 1W5 (Canada); University of British Columbia, Department of Mechanical Engineering, 2054-6250 Applied Science Lane, Vancouver, British Columbia, V6T 1Z4 (Canada); Tang, Zhaolin; Burgess, Alan [Northwest Mettech Corp., 467 Mountain Hwy, North Vancouver, British Columbia, V7J 2L3 (Canada)

    2007-05-15

    Due to its high thermal stability and purely oxide ionic conductivity, yttria-stabilized zirconia (YSZ) is the most commonly used electrolyte material for solid oxide fuel cells (SOFCs). Standard electrolyte fabrication techniques for planar SOFCs involve wet ceramic techniques such as tape-casting or screen printing, requiring sintering steps at temperatures above 1300 C. Plasma spraying (PS) may provide a more rapid and cost efficient method to produce SOFCs without sintering. High-temperature sintering requires long processing times and can lead to oxidation of metal alloys used as mechanical supports, or to detrimental interreactions between the electrolyte and adjacent electrode layers. This study investigates the use of spin coated sol gel derived YSZ precursor solutions to fill the pores present in plasma sprayed YSZ layers, and to enhance the surface area for reaction at the electrolyte-cathode interface, without the use of high-temperature firing steps. The effects of different plasma conditions and sol concentrations and solid loadings on the gas permeability and fuel cell performance have been investigated. (author)

  19. Spray structure of a pressure-swirl atomizer for combustion applications

    Directory of Open Access Journals (Sweden)

    Jicha Miroslav

    2012-04-01

    Full Text Available In the present work, global as well as spatially resolved parameters of a spray produced by a pressure-swirl atomizer are obtained. Small pressure-swirl atomizer for aircraft combustion chambers was run on a newly designed test bench with Jet A-1 kerosene type aviation fuel. The atomizer was tested in four regimes based on typical operation conditions of the engine. Spray characteristics were studied using two optical measurement systems, Particle Image velocimetry (PIV and Phase-Doppler Particle Analyzer (P/DPA. The results obtained with P/DPA include information about Sauter Mean Diameter of droplets and spray velocity profiles in one plane perpendicular to the spray axis. Velocity magnitudes of droplets in an axial section of the spray were obtained using PIV. The experimental outputs also show a good confirmation of velocity profiles obtained with both instruments in the test plane. These data together will elucidate impact of the spray quality on the whole combustion process, its efficiency and exhaust gas emissions.

  20. Spray structure of a pressure-swirl atomizer for combustion applications

    Science.gov (United States)

    Durdina, Lukas; Jedelsky, Jan; Jicha, Miroslav

    2012-04-01

    In the present work, global as well as spatially resolved parameters of a spray produced by a pressure-swirl atomizer are obtained. Small pressure-swirl atomizer for aircraft combustion chambers was run on a newly designed test bench with Jet A-1 kerosene type aviation fuel. The atomizer was tested in four regimes based on typical operation conditions of the engine. Spray characteristics were studied using two optical measurement systems, Particle Image velocimetry (PIV) and Phase-Doppler Particle Analyzer (P/DPA). The results obtained with P/DPA include information about Sauter Mean Diameter of droplets and spray velocity profiles in one plane perpendicular to the spray axis. Velocity magnitudes of droplets in an axial section of the spray were obtained using PIV. The experimental outputs also show a good confirmation of velocity profiles obtained with both instruments in the test plane. These data together will elucidate impact of the spray quality on the whole combustion process, its efficiency and exhaust gas emissions.

  1. Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

    Science.gov (United States)

    Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

    2018-04-17

    The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

  2. Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

    Science.gov (United States)

    Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

    2017-05-23

    The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

  3. Heaters to simulate fuel pins for heat transfer tests in single-phase liquid-metal-flow

    International Nuclear Information System (INIS)

    Casal, V.; Graf, E.; Hartmann, W.

    1976-09-01

    The development of heaters for thermal simulation of the fuel elements of liquid metal cooled fast breeder reactors (SNR) is reported. Beginning with the experimental demands various heating methods are discussed for thermodynamic investigations of the heat transfer in liquid metals. Then a preferred heater rod is derived to simulate the fuel pins of a SNR. Finally it is reported on the fabrication and the operation practice. (orig.) [de

  4. Fabrication of Cr-doped UO2 Fuel Pellet using Liquid Phase Sintering

    International Nuclear Information System (INIS)

    Kim, Dong Joo; Yang, Jae Ho; Kim, Keon Sik; Rhee, Young Woo; Kim, Jong Hun; Oh, Jang Soo; Koo, Yang Hyun

    2013-01-01

    An enhancement of the thermal conductivity of a pellet can be obtained by the addition of a higher thermal conductive material in the pellet. In addition, the resistance to the PCI can be increased through a plasticity increase of the pellet. Thermal conductivity of ceramic materials is generally lower than that of metallic materials. The thermal conductivity of uranium oxide which is a typical ceramic material is low as well. The steep temperature gradient in the fuel pellet results from the low thermal conductivity. Therefore, the thermal conductivity improvement of a nuclear fuel pellet can enhance the fuel performance in various aspects. The lower centerline temperature of a fuel pellet affects the enhancement of fuel safety as well as fuel pellet integrity during nuclear reactor operation. Besides, the nuclear reactor power can be uprated due to the higher safety margin. So, many researches to enhance the thermal conductivity of nuclear fuel pellet have been performed in various ways. To improve the thermal conductivity of UO 2 pellet, an appropriate arrangement of the high thermal conductive material in UO 2 matrix is one of the various methods. We intended to control a placement of chromium as the high thermal conductive material. The metallic chromium and chromium oxide were arranged in a grain boundary of UO 2 using a liquid phase sintering method. The liquid phase sintering of Cr-doped UO 2 pellet could be adjusted using a control of an oxygen potential in sintering atmosphere

  5. Horizontal liquid film-mist two phase flow, (1)

    International Nuclear Information System (INIS)

    Akagawa, Koji; Sakaguchi, Tadashi; Fujii, Terushige; Nakatani, Yoji; Nakaseko, Kosaburo.

    1979-01-01

    The characteristics of liquid film in annular spray flow, the generation of droplets from liquid film and the transport of droplets to a wall are the important matters in the planning and design of nuclear reactor cooling system and the channels of steam generators. The study on the liquid film spray flow is scarce, and its characteristics are not yet elucidated. The purpose of this series of studies is to clarify the characteristics of liquid film, the generation, diffusion and distribution of droplets and pressure loss in the liquid film spray flow composed of the liquid film on the lower wall and spraying gas flow in a rectangular, horizontal channel. In this paper, the concentration distribution and the diffusion coefficient of droplets on a cross section in the region of flow completion are reported. The experimental apparatuses and the experimental method, the flow rate of droplets and the velocity distribution of gas phase, the concentration distribution and the diffusion coefficient of droplets, and the diameter of generated droplets are explained. The equation for the concentration distribution of droplets using dimensionless characteristic value was derived. The mean diffusion coefficient of droplets was constant on a cross section, and the effects of gravity and turbulent diffusion can be evaluated. (Kako, I.)

  6. Numerical Simulation of the Effect of 3D Needle Movement on Cavitation and Spray Formation in a Diesel Injector

    Science.gov (United States)

    Mandumpala Devassy, B.; Edelbauer, W.; Greif, D.

    2015-12-01

    Cavitation and its effect on spray formation and its dispersion play a crucial role in proper engine combustion and controlled emission. This study focuses on these effects in a typical common rail 6-hole diesel injector accounting for 3D needle movement and flow compressibility effects. Coupled numerical simulations using 1D and 3D CFD codes are used for this investigation. Previous studies in this direction have already presented a detailed structure of the adopted methodology. Compared to the previous analysis, the present study investigates the effect of 3D needle movement and cavitation on the spray formation for pilot and main injection events for a typical diesel engine operating point. The present setup performs a 3D compressible multiphase simulation coupled with a standalone 1D high pressure flow simulation. The simulation proceeds by the mutual communication between 1D and 3D solvers. In this work a typical common rail injector with a mini-sac nozzle is studied. The lateral and radial movement of the needle and its effect on the cavitation generation and the subsequent spray penetration are analyzed. The result indicates the effect of compressibility of the liquid on damping the needle forces, and also the difference in the spray penetration levels due to the asymmetrical flow field. Therefore, this work intends to provide an efficient and user-friendly engineering tool for simulating a complete fuel injector including spray propagation.

  7. Numerical Simulation of the Effect of 3D Needle Movement on Cavitation and Spray Formation in a Diesel Injector

    International Nuclear Information System (INIS)

    Devassy, B Mandumpala; Edelbauer, W; Greif, D

    2015-01-01

    Cavitation and its effect on spray formation and its dispersion play a crucial role in proper engine combustion and controlled emission. This study focuses on these effects in a typical common rail 6-hole diesel injector accounting for 3D needle movement and flow compressibility effects. Coupled numerical simulations using 1D and 3D CFD codes are used for this investigation. Previous studies in this direction have already presented a detailed structure of the adopted methodology. Compared to the previous analysis, the present study investigates the effect of 3D needle movement and cavitation on the spray formation for pilot and main injection events for a typical diesel engine operating point. The present setup performs a 3D compressible multiphase simulation coupled with a standalone 1D high pressure flow simulation. The simulation proceeds by the mutual communication between 1D and 3D solvers. In this work a typical common rail injector with a mini-sac nozzle is studied. The lateral and radial movement of the needle and its effect on the cavitation generation and the subsequent spray penetration are analyzed. The result indicates the effect of compressibility of the liquid on damping the needle forces, and also the difference in the spray penetration levels due to the asymmetrical flow field. Therefore, this work intends to provide an efficient and user-friendly engineering tool for simulating a complete fuel injector including spray propagation. (paper)

  8. Fabrication of ultrathin multilayered superomniphobic nanocoatings by liquid flame spray, atomic layer deposition, and silanization.

    Science.gov (United States)

    Sorvali, Miika; Vuori, Leena; Pudas, Marko; Haapanen, Janne; Mahlberg, Riitta; Ronkainen, Helena; Honkanen, Mari; Valden, Mika; Mäkelä, Jyrki M

    2018-05-04

    Superomniphobic, i.e. liquid-repellent, surfaces have been an interesting area of research during recent years due to their various potential applications. However, producing such surfaces, especially on hard and resilient substrates like stainless steel, still remains challenging. We present a stepwise fabrication process of a multilayered nanocoating on a stainless steel substrate, consisting of a nanoparticle layer, a nanofilm, and a layer of silane molecules. Liquid flame spray was used to deposit a TiO 2 nanoparticle layer as the bottom layer for producing a suitable surface structure. The interstitial Al 2 O 3 nanofilm, fabricated by atomic layer deposition (ALD), stabilized the nanoparticle layer, and the topmost fluorosilane layer lowered the surface energy of the coating for enhanced omniphobicity. The coating was characterized with field emission scanning electron microscopy, focused ion beam scanning electron microscopy, x-ray photoelectron spectroscopy, contact angle (CA) and sliding angle (SA) measurements, and microscratch testing. The widely recognized requirements for superrepellency, i.e. CA > 150° and SA layer at the expense of repellency. To our knowledge, this is the thinnest superomniphobic coating reported so far, with the average thickness of about 70 nm.

  9. Developments in the formulation and delivery of spray dried vaccines.

    Science.gov (United States)

    Kanojia, Gaurav; Have, Rimko Ten; Soema, Peter C; Frijlink, Henderik; Amorij, Jean-Pierre; Kersten, Gideon

    2017-10-03

    Spray drying is a promising method for the stabilization of vaccines, which are usually formulated as liquids. Usually, vaccine stability is improved by spray drying in the presence of a range of excipients. Unlike freeze drying, there is no freezing step involved, thus the damage related to this step is avoided. The edge of spray drying resides in its ability for particles to be engineered to desired requirements, which can be used in various vaccine delivery methods and routes. Although several spray dried vaccines have shown encouraging preclinical results, the number of vaccines that have been tested in clinical trials is limited, indicating a relatively new area of vaccine stabilization and delivery. This article reviews the current status of spray dried vaccine formulations and delivery methods. In particular it discusses the impact of process stresses on vaccine integrity, the application of excipients in spray drying of vaccines, process and formulation optimization strategies based on Design of Experiment approaches as well as opportunities for future application of spray dried vaccine powders for vaccine delivery.

  10. Developments in the formulation and delivery of spray dried vaccines

    Science.gov (United States)

    Kanojia, Gaurav; Have, Rimko ten; Soema, Peter C.; Frijlink, Henderik; Amorij, Jean-Pierre; Kersten, Gideon

    2017-01-01

    ABSTRACT Spray drying is a promising method for the stabilization of vaccines, which are usually formulated as liquids. Usually, vaccine stability is improved by spray drying in the presence of a range of excipients. Unlike freeze drying, there is no freezing step involved, thus the damage related to this step is avoided. The edge of spray drying resides in its ability for particles to be engineered to desired requirements, which can be used in various vaccine delivery methods and routes. Although several spray dried vaccines have shown encouraging preclinical results, the number of vaccines that have been tested in clinical trials is limited, indicating a relatively new area of vaccine stabilization and delivery. This article reviews the current status of spray dried vaccine formulations and delivery methods. In particular it discusses the impact of process stresses on vaccine integrity, the application of excipients in spray drying of vaccines, process and formulation optimization strategies based on Design of Experiment approaches as well as opportunities for future application of spray dried vaccine powders for vaccine delivery. PMID:28925794

  11. Characteristics of spray from a GDI fuel injector for naphtha and surrogate fuels

    KAUST Repository

    Wang, Libing; Badra, Jihad A.; Roberts, William L.; Fang, Tiegang

    2016-01-01

    size distribution were measured using a laser diffraction technique. Results show that the injection process is very consistent for different runs and the time averaged spray angles during the measuring period are 103.45°, 102.84°, 102.46° and 107

  12. Lignin depolymerization and upgrading via fast pyrolysis and electrocatalysis for the production of liquid fuels and value-added products

    Science.gov (United States)

    Garedew, Mahlet

    The production of liquid hydrocarbon fuels from biomass is needed to replace fossil fuels, which are decreasing in supply at an unsustainable rate. Renewable fuels also address the rising levels of greenhouse gases, an issue for which the Intergovernmental Panel on Climate Change implicated humanity in 2013. In response, the Energy Independence and Security Act (EISA) mandates the production of 21 billion gallons of advanced biofuels by 2022. Biomass fast pyrolysis (BFP) uses heat (400-600 °C) without oxygen to convert biomass to liquids fuel precursors offering an alternative to fossil fuels and a means to meet the EISA mandate. The major product, bio-oil, can be further upgraded to liquid hydrocarbon fuels, while biochar can serve as a solid fuel or soil amendment. The combustible gas co-product is typically burned for process heat. Though the most valuable of the pyrolysis products, the liquid bio-oil is highly oxygenated, corrosive, low in energy content and unstable during storage. As a means of improving bio-oil properties, electrocatalytic hydrogenation (ECH) is employed to reduce and deoxygenate reactive compounds. This work specifically focuses on lignin as a feed material for BFP. As lignin comprises up to 30% of the mass and 40% of the energy stored in biomass, it offers great potential for the production of liquid fuels and value-added products by utilizing fast pyrolysis as a conversion method coupled with electrocatalysis as an upgrading method.

  13. Optimization of the Automated Spray Layer-by-Layer Technique for Thin Film Deposition

    Science.gov (United States)

    2010-06-01

    air- pumped spray-paint cans 17,18 to fully automated systems using high pressure gas .7’ 19 This work uses the automated spray system previously...spray solutions were delivered by ultra high purity nitrogen gas (AirGas) regulated to 25psi, except when examining air pressure effects . The PAH solution...polyelectrolyte solution feed tube, the resulting Venturi effect causes the liquid solution to be drawn up into the airbrush nozzle, where it is

  14. Future developments and technological and economic assessment of methods for producing synthetic liquid fuel from coal

    Energy Technology Data Exchange (ETDEWEB)

    Shlikhter, E B; Khor' kov, A V; Zhorov, Yu M

    1980-11-01

    Promising methods for obtaining synthetic liquid fuel from coal are surveyed and described: thermal dissolution of coal by means of a hydrogen donor solution: hydrogenation; gasification with subsequent synthesis and pyrolysis. A technological and economic assessment of the above processes is given. Emphasis is placed on methods employing catalytic conversion of methanol into hydrocarbon fuels. On the basis of thermodynamic calculations of the process for obtaining high-calorific liquid fuel from methanol the possibility of obtaining diesel fractions as well as gasoline is demonstrated. (12 refs.) (In Russian)

  15. Investigation of an Alternative Fuel Form for the Liquid Salt Cooled Very High Temperature Reactor (LS-VHTR)

    International Nuclear Information System (INIS)

    Casino, William A. Jr.

    2006-01-01

    Much of the recent studies investigating the use of liquid salts as reactor coolants have utilized a core configuration of graphite prismatic fuel block assemblies with TRISO particles embedded into cylindrical fuel compacts arranged in a triangular pitch lattice. Although many calculations have been performed for this fuel form in gas cooled reactors, it would be instructive to investigate whether an alternative fuel form may yield improved performance for the liquid salt-cooled Very High Temperature Reactor (LS-VHTR). This study investigates how variations in the fuel form will impact the performance of the LS-VHTR during normal and accident conditions and compares the results with a similar analysis that was recently completed for a LS-VHTR core made up of prismatic block fuel. (author)

  16. Triaxial Swirl Injector Element for Liquid-Fueled Engines

    Science.gov (United States)

    Muss, Jeff

    2010-01-01

    A triaxial injector is a single bi-propellant injection element located at the center of the injector body. The injector element consists of three nested, hydraulic swirl injectors. A small portion of the total fuel is injected through the central hydraulic injector, all of the oxidizer is injected through the middle concentric hydraulic swirl injector, and the balance of the fuel is injected through an outer concentric injection system. The configuration has been shown to provide good flame stabilization and the desired fuel-rich wall boundary condition. The injector design is well suited for preburner applications. Preburner injectors operate at extreme oxygen-to-fuel mass ratios, either very rich or very lean. The goal of a preburner is to create a uniform drive gas for the turbomachinery, while carefully controlling the temperature so as not to stress or damage turbine blades. The triaxial injector concept permits the lean propellant to be sandwiched between two layers of the rich propellant, while the hydraulic atomization characteristics of the swirl injectors promote interpropellant mixing and, ultimately, good combustion efficiency. This innovation is suited to a wide range of liquid oxidizer and liquid fuels, including hydrogen, methane, and kerosene. Prototype testing with the triaxial swirl injector demonstrated excellent injector and combustion chamber thermal compatibility and good combustion performance, both at levels far superior to a pintle injector. Initial testing with the prototype injector demonstrated over 96-percent combustion efficiency. The design showed excellent high -frequency combustion stability characteristics with oxygen and kerosene propellants. Unlike the more conventional pintle injector, there is not a large bluff body that must be cooled. The absence of a protruding center body enhances the thermal durability of the triaxial swirl injector. The hydraulic atomization characteristics of the innovation allow the design to be

  17. Spraying mode effect on droplet formation and ion chemistry in electrosprays.

    Science.gov (United States)

    Nemes, Peter; Marginean, Ioan; Vertes, Akos

    2007-04-15

    Depending on the spraying conditions and fluid properties, a variety of electrospray regimes exists. Here we explore the changes in ion production that accompany the transitions among the three axial spraying modes, the burst mode, the pulsating Taylor cone mode, and the cone-jet mode. Spray current oscillation and phase Doppler anemometry measurements, fast imaging of the electrified meniscus, and mass spectrometry are utilized to study the formation, size, velocity, and chemical composition of droplets produced in the three modes. High-speed images indicate that the primary droplets are produced by varicose waves and lateral kink instabilities on the liquid jet emerging from the Taylor cone, whereas secondary droplets are formed by fission. Dramatic changes in the droplet size distributions result from the various production and breakup mechanisms observed at different emitter voltages and liquid flow rates. We demonstrate that droplet fission can be facilitated by space charge effects along the liquid jet and in the plume. Compared to the other two regimes, a significantly enhanced signal-to-noise ratio, a lower degree of analyte oxidation, and milder fragmentation are observed for the cone-jet mode.

  18. Organic-resistant screen-printed graphitic electrodes: Application to on-site monitoring of liquid fuels

    International Nuclear Information System (INIS)

    Almeida, Eduardo S.; Silva, Luiz A.J.; Sousa, Raquel M.F.; Richter, Eduardo M.; Foster, Christopher W.; Banks, Craig E.; Munoz, Rodrigo A.A.

    2016-01-01

    This work presents the potential application of organic-resistant screen-printed graphitic electrodes (SPGEs) for fuel analysis. The required analysis of the antioxidant 2,6-di-tert-butylphenol (2,6-DTBP) in biodiesel and jet fuel is demonstrated as a proof-of-concept. The screen-printing of graphite, Ag/AgCl and insulator inks on a polyester substrate (250 μm thickness) resulted in SPGEs highly compatible with liquid fuels. SPGEs were placed on a batch-injection analysis (BIA) cell, which was filled with a hydroethanolic solution containing 99% v/v ethanol and 0.1 mol L −1 HClO 4 (electrolyte). An electronic micropipette was connected to the cell to perform injections (100 μL) of sample or standard solutions. Over 200 injections can be injected continuously without replacing electrolyte and SPGE strip. Amperometric detection (+1.1 V vs. Ag/AgCl) of 2,6-DTBP provided fast (around 8 s) and precise (RSD = 0.7%, n = 12) determinations using an external calibration curve. The method was applied for the analysis of biodiesel and aviation jet fuel samples and comparable results with liquid and gas chromatographic analyses, typically required for biodiesel and jet fuel samples, were obtained. Hence, these SPGE strips are completely compatible with organic samples and their combination with the BIA cell shows great promise for routine and portable analysis of fuels and other organic liquid samples without requiring sophisticated sample treatments. - Highlights: • Organic-resistant screen-printed graphitic electrodes (SPGE) for (bio)fuels. • Screen-printing of conductive and insulator inks on thin polyester substrate. • Continuous detection of antioxidants in electrolyte with 99% v/v ethanol. • SPGE coupled with batch-injection analysis allows over 200 injections (100 μL). • Similar results to GC and HPLC analyses of biodiesel and aviation jet fuels.

  19. Energy harvesting from organic liquids in micro-sized microbial fuel cells

    KAUST Repository

    Mink, J.E.; Qaisi, R.M.; Logan, B.E.; Hussain, Muhammad Mustafa

    2014-01-01

    Micro-sized microbial fuel cells (MFCs) are miniature energy harvesters that use bacteria to convert biomass from liquids into usable power. The key challenge is transitioning laboratory test beds into devices capable of producing high power using

  20. Recent Advances in the Characterization of Gaseous and Liquid Fuels by Vibrational Spectroscopy

    Directory of Open Access Journals (Sweden)

    Johannes Kiefer

    2015-04-01

    Full Text Available Most commercial gaseous and liquid fuels are mixtures of multiple chemical compounds. In recent years, these mixtures became even more complicated when the suppliers started to admix biofuels into the petrochemical basic fuels. As the properties of such mixtures can vary with composition, there is a need for reliable analytical technologies in order to ensure stable operation of devices such as internal combustion engines and gas turbines. Vibrational spectroscopic methods have proved their suitability for fuel characterization. Moreover, they have the potential to overcome existing limitations of established technologies, because they are fast and accurate, and they do not require sampling; hence they can be deployed as inline sensors. This article reviews the recent advances of vibrational spectroscopy in terms of infrared absorption (IR and Raman spectroscopy in the context of fuel characterization. The focus of the paper lies on gaseous and liquid fuels, which are dominant in the transportation sector and in the distributed generation of power. On top of an introduction to the physical principles and review of the literature, the techniques are critically discussed and compared with each other.

  1. In situ liquid water visualization in polymer electrolyte membrane fuel cells with high resolution synchrotron x-ray radiography

    Energy Technology Data Exchange (ETDEWEB)

    Chevalier, S.; Banerjee, R.; Lee, J.; Ge, N.; Lee, C.; Bazylak, A., E-mail: abazylak@mie.utoronto.ca [Dept. of Mechanical & Industrial Engineering, Faculty of Applied Science & Engineering, University of Toronto, Toronto, Ontario (Canada); Wysokinski, T. W.; Belev, G.; Webb, A.; Miller, D.; Zhu, N. [Canadian Light Source, Saskatoon, Saskatchewan (Canada); Tabuchi, Y.; Kotaka, T. [EV System Laboratory, Research Division 2, Nissan Motor Co., Ltd., Yokosuka, Kanagawa (Japan)

    2016-07-27

    In this work, we investigated the dominating properties of the porous materials that impact water dynamics in a polymer electrolyte membrane fuel cell (PEMFC). Visualizations of liquid water in an operating PEMFC were performed at the Canadian Light Source. A miniature fuel cell was specifically designed for X-ray imaging investigations, and an in-house image processing algorithm based on the Beer-Lambert law was developed to extract quantities of liquid water thicknesses (cm) from raw X-ray radiographs. The X-ray attenuation coefficient of water at 24 keV was measured with a calibration device to ensure accurate measurements of the liquid water thicknesses. From this experiment, the through plane distribution of the liquid water in the fuel cell was obtained.

  2. In situ liquid water visualization in polymer electrolyte membrane fuel cells with high resolution synchrotron x-ray radiography

    International Nuclear Information System (INIS)

    Chevalier, S.; Banerjee, R.; Lee, J.; Ge, N.; Lee, C.; Bazylak, A.; Wysokinski, T. W.; Belev, G.; Webb, A.; Miller, D.; Zhu, N.; Tabuchi, Y.; Kotaka, T.

    2016-01-01

    In this work, we investigated the dominating properties of the porous materials that impact water dynamics in a polymer electrolyte membrane fuel cell (PEMFC). Visualizations of liquid water in an operating PEMFC were performed at the Canadian Light Source. A miniature fuel cell was specifically designed for X-ray imaging investigations, and an in-house image processing algorithm based on the Beer-Lambert law was developed to extract quantities of liquid water thicknesses (cm) from raw X-ray radiographs. The X-ray attenuation coefficient of water at 24 keV was measured with a calibration device to ensure accurate measurements of the liquid water thicknesses. From this experiment, the through plane distribution of the liquid water in the fuel cell was obtained.

  3. LES of n-Dodecane Spray Combustion Using a Multiple Representative Interactive Flamelets Model

    Directory of Open Access Journals (Sweden)

    Davidovic Marco

    2017-09-01

    Full Text Available A single-hole n-dodecane spray flame is studied in a Large-Eddy Simulation (LES framework under Diesel-relevant conditions using a Multiple Representative Interactive Flamelets (MRIF combustion model. Diesel spray combustion is strongly affected by the mixture formation process, which is dominated by several physical processes such as the flow within the injector, break-up of the liquid fuel jet, evaporation and turbulent mixing with the surrounding gas. While the effects of nozzle-internal flow and primary breakup are captured within tuned model parameters in traditional Lagrangian spray models, an alternative approach is applied in this study, where the initial droplet conditions and primary fuel jet breakup are modeled based on results from highly resolved multiphase simulations with resolved interface. A highly reduced chemical mechanism consisting of 57 species and 217 reactions has been developed for n-dodecane achiving a good computational performance at solving the chemical reactions. The MRIF model, which has demonstrated its capability of capturing combustion and pollutant formation under typical Diesel conditions in Reynolds-Averaged Navier-Stokes (RANS simulations is extended for the application in LES. In the standard RIF combustion model, representative chemistry conditioned on mixture fraction is solved interactively with the flow. Subfilter-scale mixing is modeled by the scalar dissipation rate. While the standard RIF model only includes temporal changes of the scalar dissipation rate, the spatial distribution can be accounted for by extending the model to multiple flamelets, which also enables the possibility of capturing different fuel residence times. Overall, the model shows good agreement with experimental data regarding both, low and high temperature combustion characteristics. It is shown that the ignition process and pollutant formation are affected by turbulent mixing. First, a cool flame is initiated at approximately

  4. Technical and economic modelling of processes for liquid fuel production in Europe

    International Nuclear Information System (INIS)

    Bridgwater, A.V.; Double, J.M.

    1991-01-01

    The project which is described had the objective of examining the full range of technologies for liquid fuel production from renewable feedstocks in a technical and economic evaluation in order to identify the most promising technologies. The technologies considered are indirect thermochemical liquefaction (i.e. via gasification) to produce methanol, fuel alcohol or hydrocarbon fuels, direct thermochemical liquefaction or pyrolysis to produce hydrocarbon fuels and fermentation to produce ethanol. Feedstocks considered were wood, refuse derived fuel, straw, wheat and sugar beet. In order to carry out the evaluation, a computer model was developed, based on a unit process approach. Each unit operation is modelled as a process step, the model calculating the mass balance, energy balance and operating cost of the unit process. The results from the process step models are then combined to generate the mass balance, energy balance, capital cost and operating cost for the total process. The results show that the lowest production cost (L7/GJ) is obtained for methanol generated from a straw feedstock, but there is a moderate level of technical uncertainty associated with this result. The lowest production cost for hydrocarbon fuel (L8.6/GJ) is given by the pyrolysis process using a wood feedstock. This process has a high level of uncertainty. Fermentation processes showed the highest production costs, ranging from L14.4/GJ for a simple wood feedstock process to L25.2/GJ for a process based on sugar beet. The important conclusions are as follows: - In every case, the product cost is above current liquid fuel prices; - In most cases the feedstock cost dominates the production cost; -The most attractive products are thermochemically produced alcohol fuels

  5. Technical and economic modelling of processes for liquid fuel production in Europe

    Energy Technology Data Exchange (ETDEWEB)

    Bridgwater, A V; Double, J M [Aston Univ. Birmingham (GB). Dept of Chemical Engineering

    1992-12-31

    The project which is described had the objective of examining the full range of technologies for liquid fuel production from renewable feedstocks in a technical and economic evaluation in order to identify the most promising technologies. The technologies considered are indirect thermochemical liquefaction (i.e. via gasification) to produce methanol, fuel alcohol or hydrocarbon fuels, direct thermochemical liquefaction or pyrolysis to produce hydrocarbon fuels and fermentation to produce ethanol. Feedstocks considered were wood, refuse derived fuel, straw, wheat and sugar beet. In order to carry out the evaluation, a computer model was developed, based on a unit process approach. Each unit operation is modelled as a process step, the model calculating the mass balance, energy balance and operating cost of the unit process. The results from the process step models are then combined to generate the mass balance, energy balance, capital cost and operating cost for the total process. The results show that the lowest production cost (L7/GJ) is obtained for methanol generated from a straw feedstock, but there is a moderate level of technical uncertainty associated with this result. The lowest production cost for hydrocarbon fuel (L8.6/GJ) is given by the pyrolysis process using a wood feedstock. This process has a high level of uncertainty. Fermentation processes showed the highest production costs, ranging from L14.4/GJ for a simple wood feedstock process to L25.2/GJ for a process based on sugar beet. The important conclusions are as follows: - In every case, the product cost is above current liquid fuel prices; - In most cases the feedstock cost dominates the production cost; -The most attractive products are thermochemically produced alcohol fuels.

  6. Spray Modeling for Outwardly-Opening Hollow-Cone Injector

    KAUST Repository

    Sim, Jaeheon

    2016-04-05

    The outwardly-opening piezoelectric injector is gaining popularity as a high efficient spray injector due to its precise control of the spray. However, few modeling studies have been reported on these promising injectors. Furthermore, traditional linear instability sheet atomization (LISA) model was originally developed for pressure swirl hollow-cone injectors with moderate spray angle and toroidal ligament breakups. Therefore, it is not appropriate for the outwardly-opening injectors having wide spray angles and string-like film structures. In this study, a new spray injection modeling was proposed for outwardly-opening hollow-cone injector. The injection velocities are computed from the given mass flow rate and injection pressure instead of ambiguous annular nozzle geometry. The modified Kelvin-Helmholtz and Rayleigh-Taylor (KH-RT) breakup model is used with adjusted initial Sauter mean diameter (SMD) for modeling breakup of string-like structure. Spray injection was modeled using a Lagrangian discrete parcel method within the framework of commercial CFD software CONVERGE, and the new model was implemented through the user-defined functions. A Siemens outwardly-opening hollow-cone spray injector was characterized and validated with existing experimental data at the injection pressure of 100 bar. It was found that the collision modeling becomes important in the current injector because of dense spray near nozzle. The injection distribution model showed insignificant effects on spray due to small initial droplets. It was demonstrated that the new model can predict the liquid penetration length and local SMD with improved accuracy for the injector under study.

  7. Development of thermohydraulic codes for modeling liquid metal boiling in LMR fuel subassemblies

    International Nuclear Information System (INIS)

    Sorokin, G.A.; Avdeev, E.F.; Zhukov, A.V.; Bogoslovskaya, G.P.; Sorokin, A.P.

    2000-01-01

    An investigation into the reactor core accident cooling, which are associated with the power grow up or switch off circulation pumps in the event of the protective equipment comes into action, results in the problem of liquid metal boiling heat transfer. Considerable study has been given over the last 30 years to alkaline metal boiling including researches of heat transfer, boiling patterns, hydraulic resistance, crisis of heat transfer, initial heating up, boiling onset and instability of boiling. The results of these investigations have shown that the process of liquid metal boiling has substantial features in comparison with water boiling. Mathematical modeling of two phase flows in fast reactor fuel subassemblies have been developed intensively. Significant success has been achieved in formulation of two phase flow through the pin bundle and in their numerical realization. Currently a set of codes for thermohydraulic analysis of two phase flows in fast reactor subassembly have been developed with 3D macrotransfer governing equations. These codes are used for analysis of boiling onset and liquid metals boiling in fuel subassemblies during loss-of-coolant accidents, of warming up of reactor core, of blockage of some part of flow cross section in fuel subassembly. (author)

  8. New Technique Of Determination Of Biogenic Fraction In Liquid Fuels By The 14C Method

    International Nuclear Information System (INIS)

    Krajcar Bronic, I.; Baresic, J.; Horvatincic, N.; Kristof, R.; Kozar Logar, J.

    2015-01-01

    According to the EU Directive 2009/28/EC all (liquid) fuels have to contain at least 10 percent of bio-fuel, i.e., blend of biogenic origin, by 2020. 14C method is the most reliable method of determination of the biogenic fraction in fuels and various measurement techniques can be applied. A technique of direct measurement of the 14C content in liquid fuel is simple and fast but has main disadvantage: different liquid colours cause different quenching and changes in the measurement efficiency. Here we have described a new technique that uses liquids of different colours to construct modern and background calibration curves, MCC and BCC, respectively, by measuring count rates and SQP values of various modern and fossil liquids. Several types of fossil fuel, pure benzine and benzene (used as 14C-free background for 14C dating) were used for BCC, and various brands of domestic oil (vegetable, sunflower, olive, pumpkin), bioethanol and benzene prepared from modern samples were used MCC construction. The procedure for the unknown sample consists of: 1) measurement of the count rate and the SQP value, 2) calculation of background and modern count rates corresponding to the measured SQP value based on the BCC and MCC curves, respectively, and 3) the ratio of net count rates of the unknown sample and the modern net count rate at the same SQP represents the fraction of the biogenic component in the liquid. All samples should be measured under the same conditions. In our case these are: UltimaGold F scintillator, the ratio sample:scintillator (10 mL:10 mL), low-potassium glass vials of 20 mL volume, spectra recorded by LSC Quantulus and evaluated in the window 124 - 570. Lowest detectable biogenic fraction is 0.5 %. The technique depends neither on the fossil matrix or the biogenic additive types. The results are in good agreement with those obtained by different evaluation technique. (author).

  9. Calculations for reproducible autologous skin cell-spray grafting.

    Science.gov (United States)

    Esteban-Vives, Roger; Young, Matthew T; Zhu, Toby; Beiriger, Justin; Pekor, Chris; Ziembicki, Jenny; Corcos, Alain; Rubin, Peter; Gerlach, Jörg C

    2016-12-01

    Non-cultured, autologous cell-spray grafting is an alternative to mesh grafting for larger partial- and deep partial-thickness burn wounds. The treatment uses a suspension of isolated cells, from a patient's donor site skin tissue, and cell-spray deposition onto the wound that facilitates re-epithelialization. Existing protocols for therapeutic autologous skin cell isolation and cell-spray grafting have defined the donor site area to treatment area ratio of 1:80, substantially exceeding the coverage of conventional mesh grafting. However, ratios of 1:100 are possible by maximizing the wound treatment area with harvested cells from a given donor site skin tissue according to a given burn area. Although cell isolation methods are very well described in the literature, a rational approach addressing critical aspects of these techniques are of interest in planning clinical study protocols. We considered in an experimental study the cell yield as a function of the donor site skin tissue, the cell density for spray grafting, the liquid spray volume, the sprayed distribution area, and the percentage of surface coverage. The experimental data was then used for the development of constants and mathematical equations to give a rationale for the cell isolation and cell-spray grafting processes and in planning for clinical studies. Copyright © 2016 Elsevier Ltd and ISBI. All rights reserved.

  10. Organic-resistant screen-printed graphitic electrodes: Application to on-site monitoring of liquid fuels.

    Science.gov (United States)

    Almeida, Eduardo S; Silva, Luiz A J; Sousa, Raquel M F; Richter, Eduardo M; Foster, Christopher W; Banks, Craig E; Munoz, Rodrigo A A

    2016-08-31

    This work presents the potential application of organic-resistant screen-printed graphitic electrodes (SPGEs) for fuel analysis. The required analysis of the antioxidant 2,6-di-tert-butylphenol (2,6-DTBP) in biodiesel and jet fuel is demonstrated as a proof-of-concept. The screen-printing of graphite, Ag/AgCl and insulator inks on a polyester substrate (250 μm thickness) resulted in SPGEs highly compatible with liquid fuels. SPGEs were placed on a batch-injection analysis (BIA) cell, which was filled with a hydroethanolic solution containing 99% v/v ethanol and 0.1 mol L(-1) HClO4 (electrolyte). An electronic micropipette was connected to the cell to perform injections (100 μL) of sample or standard solutions. Over 200 injections can be injected continuously without replacing electrolyte and SPGE strip. Amperometric detection (+1.1 V vs. Ag/AgCl) of 2,6-DTBP provided fast (around 8 s) and precise (RSD = 0.7%, n = 12) determinations using an external calibration curve. The method was applied for the analysis of biodiesel and aviation jet fuel samples and comparable results with liquid and gas chromatographic analyses, typically required for biodiesel and jet fuel samples, were obtained. Hence, these SPGE strips are completely compatible with organic samples and their combination with the BIA cell shows great promise for routine and portable analysis of fuels and other organic liquid samples without requiring sophisticated sample treatments. Copyright © 2016 Elsevier B.V. All rights reserved.

  11. Motor fuels by hydrogenation of liquid hydrocarbons

    Energy Technology Data Exchange (ETDEWEB)

    1938-05-07

    A process is disclosed for the production of knock-stable low-boiling motor fuels by conversion of liquid hydrocarbons which are vaporizable under the reaction conditions, which comprises passing the initial material at a temperature above 380/sup 0/C in a true vapor phase under pressure of more than 40 atmospheres together with hydrogen and gaseous hydrocarbons containing more than 1 carbon atom in the molecule in an amount by volume larger than that of the hydrogen over catalysts stable to poisoning stationarily confined in the reaction vessel.

  12. PERFORMANCE, EMISSION, AND COMBUSTION CHARACTERISTICS OF A CI ENGINE USING LIQUID PETROLEUM GAS AND NEEM OIL IN DUAL FUEL MODE

    Directory of Open Access Journals (Sweden)

    Palanimuthu Vijayabalan

    2010-01-01

    Full Text Available Increased environmental awareness and depletion of resources are driving the industries to develop viable alternative fuels like vegetable oils, compresed natural gas, liquid petroleum gas, producer gas, and biogas in order to provide suitable substitute to diesel for compression ignition engine. In this investigation, a single cylinder, vertical, air-cooled diesel engine was modified to use liquid petroleum gas in dual fuel mode. The liquefied petroleum gas, was mixed with air and supplied through intake manifold. The liquid fuel neem oil or diesel was injected into the combustion chamber. The performance, emission, and combustion characteristics were studied and compared for neat fuel and dual fuel mode. The experimental results on dual fuel engine show a reduction in oxides of nitrogen up to 70% of the rated power and smoke in the entire power range. However the brake thermal efficiency was found decreased in low power range due to lower calorific value of liquid petroleum gas, and increase in higher power range due to the complete burning of liquid petroleum gas. Hydrocarbon and carbon monoxide emissions were increased significantly at lower power range and marginal variation in higher power range.

  13. Metallic coating deposited by Cold Gas Spray onto Light alhoys

    OpenAIRE

    Villa Vidaller, Maria

    2013-01-01

    This thesis focuses on the use of Cold Gas Spray technology (CGS) to spray different nature powders onto light alloys with the aim of increasing their wear resistance. The growing industrial interest for costs reduction (fuel consumption, machinery lifetime, or personal security) has emphasized the necessity to investigate the potential applications that light alloys can offer. Weight reduction is a reason why light metals and its alloys have been associated with strong industries a...

  14. Catalysts for synthetic liquid fuels

    Energy Technology Data Exchange (ETDEWEB)

    Bruce, L.A.; Turney, T.W.

    1987-12-01

    Fischer-Tropsch catalysts have been designed, characterized and tested for the selective production of hydrocarbons suitable as synthetic liquid transport fuels from synthesis gas (i.e., by the reduction of carbon monoxide with hydrogen). It was found that hydrocarbons in the middle distillate range, or suitable for conversion to that range, could be produced over several of the new catalyst systems. The various catalysts examined included: (1) synthetic cobalt clays, mainly cobalt chlorites; (2) cobalt hydrotalcites; (3) ruthenium metal supported on rare earth oxides of high surface area; and (4) a novel promoted cobalt catalyst. Active and selective catalysts have been obtained, in each category. With the exception of the clays, reproducibility of catalyst performance has been good. Catalysts in groups 2 and 4 have exhibited very high activity, with long lifetimes and easy regeneration.

  15. Air plasma spray processing and electrochemical characterization of Cu-SDC coatings for use in solid oxide fuel cell anodes

    Energy Technology Data Exchange (ETDEWEB)

    Benoved, Nir [Department of Mechanical Engineering, The University of British Columbia, 2054-6250 Applied Sciences Lane, Vancouver, British Columbia (Canada); Kesler, O. [Department of Mechanical and Industrial Engineering, University of Toronto, 5 King' s College Road, Toronto, Ontario (Canada)

    2009-09-05

    Air plasma spraying has been used to produce porous composite anodes based on Ce{sub 0.8}Sm{sub 0.2}O{sub 1.9} (SDC) and Cu for use in solid oxide fuel cells (SOFCs). Preliminarily, a range of plasma conditions has been examined for the production of composite coatings from pre-mixed SDC and CuO powders. Plasma gas compositions were varied to obtain a range of plasma temperatures. After reduction in H{sub 2}, coatings were characterized for composition and microstructure using EDX and SEM. As a result of these tests, symmetrical sintered electrolyte-supported anode-anode cells were fabricated by air plasma spraying of the anodes, followed by in situ reduction of the CuO to Cu. Full cells deposited on SS430 porous substrates were then produced in one integrated process. Fine CuO and SDC powders have been used to produce homogeneously mixed anode coatings with higher surface area microstructures, resulting in area-specific polarization resistances of 4.8 {omega} cm{sup 2} in impedance tests in hydrogen at 712 C. (author)

  16. Air plasma spray processing and electrochemical characterization of Cu-SDC coatings for use in solid oxide fuel cell anodes

    Science.gov (United States)

    Benoved, Nir; Kesler, O.

    Air plasma spraying has been used to produce porous composite anodes based on Ce 0.8Sm 0.2O 1.9 (SDC) and Cu for use in solid oxide fuel cells (SOFCs). Preliminarily, a range of plasma conditions has been examined for the production of composite coatings from pre-mixed SDC and CuO powders. Plasma gas compositions were varied to obtain a range of plasma temperatures. After reduction in H 2, coatings were characterized for composition and microstructure using EDX and SEM. As a result of these tests, symmetrical sintered electrolyte-supported anode-anode cells were fabricated by air plasma spraying of the anodes, followed by in situ reduction of the CuO to Cu. Full cells deposited on SS430 porous substrates were then produced in one integrated process. Fine CuO and SDC powders have been used to produce homogeneously mixed anode coatings with higher surface area microstructures, resulting in area-specific polarization resistances of 4.8 Ω cm 2 in impedance tests in hydrogen at 712 °C.

  17. Characterization of Ni-YSZ anodes for solid oxide fuel cells fabricated by suspension plasma spraying with axial feedstock injection

    Science.gov (United States)

    Metcalfe, Craig; Kuhn, Joel; Kesler, Olivera

    2013-12-01

    Composite Ni-Y0.15Zr0.85O1.925 anodes were fabricated by axial-injection suspension plasma spraying in open atmosphere conditions. The composition of the anode is controllable by adjustment of the plasma gas composition, stand-off distance, and suspension feed rate. The total porosity is controllable through the addition of carbon black to the suspension as a sacrificial pore-forming material as well as by adjustment of the suspension feed rate. The size of the NiO particles in suspension affects both the composition and total porosity, with larger NiO particles leading to increased Ni content and porosity in the deposited coatings. The surface roughness increases with a decrease of the in-flight droplet momentum, which results from both smaller NiO particles in suspension and the addition of low density pore-forming materials. A solid oxide fuel cell was fabricated with both electrodes and electrolyte fabricated by axial-injection plasma spraying. Peak power densities of 0.718 W cm-2 and 1.13 W cm-2 at 750 °C and 850 °C, respectively, were achieved.

  18. Advanced Vacuum Plasma Spray (VPS) for a Robust, Longlife and Safe Space Shuttle Main Engine (SSME)

    Science.gov (United States)

    Holmes, Richard R.; Elam, Sandra K.; McKechnie, Timothy N.; Power, Christopher A.

    2010-01-01

    In 1984, the Vacuum Plasma Spray Lab was built at NASA/Marshall Space Flight Center for applying durable, protective coatings to turbine blades for the space shuttle main engine (SSME) high pressure fuel turbopump. Existing turbine blades were cracking and breaking off after five hot fire tests while VPS coated turbine blades showed no wear or cracking after 40 hot fire tests. Following that, a major manufacturing problem of copper coatings peeling off the SSME Titanium Main Fuel Valve Housing was corrected with a tenacious VPS copper coating. A patented VPS process utilizing Functional Gradient Material (FGM) application was developed to build ceramic lined metallic cartridges for space furnace experiments, safely containing gallium arsenide at 1260 degrees centigrade. The VPS/FGM process was then translated to build robust, long life, liquid rocket combustion chambers for the space shuttle main engine. A 5K (5,000 Lb. thrust) thruster with the VPS/FGM protective coating experienced 220 hot firing tests in pristine condition with no wear compared to the SSME which showed blanching (surface pulverization) and cooling channel cracks in less than 30 of the same hot firing tests. After 35 of the hot firing tests, the injector face plates disintegrated. The VPS/FGM process was then applied to spraying protective thermal barrier coatings on the face plates which showed 50% cooler operating temperature, with no wear after 50 hot fire tests. Cooling channels were closed out in two weeks, compared to one year for the SSME. Working up the TRL (Technology Readiness Level) to establish the VPS/FGM process as viable technology, a 40K thruster was built and is currently being tested. Proposed is to build a J-2X size liquid rocket engine as the final step in establishing the VPS/FGM process TRL for space flight.

  19. Prospects for production of synthetic liquid fuel from low-grade coal

    Directory of Open Access Journals (Sweden)

    Shevyrev Sergei

    2015-01-01

    Full Text Available In the paper, we compare the energy costs of steam and steam-oxygen gasification technologies for production of synthetic liquid fuel. Results of mathematic simulation and experimental studies on gasification of low-grade coal are presented.

  20. Identifying Indicators of Progress in Thermal Spray Research Using Bibliometrics Analysis

    Science.gov (United States)

    Li, R.-T.; Khor, K. A.; Yu, L.-G.

    2016-12-01

    We investigated the research publications on thermal spray in the period of 1985-2015 using the data from Web of Science, Scopus and SciVal®. Bibliometrics analysis was employed to elucidate the country and institution distribution in various thermal spray research areas and to characterize the trends of topic change and technology progress. Results show that China, USA, Japan, Germany, India and France were the top countries in thermal spray research, and Xi'an Jiaotong University, Universite de Technologie Belfort-Montbeliard, Shanghai Institute of Ceramics, ETH Zurich, National Research Council of Canada, University of Limoges were among the top institutions that had high scholarly research output during 2005-2015. The terms of the titles, keywords and abstracts of the publications were analyzed by the Latent Dirichlet Allocation model and visually mapped using the VOSviewer software to reveal the progress of thermal spray technology. It is found that thermal barrier coating was consistently the main research area in thermal spray, and high-velocity oxy-fuel spray and cold spray developed rapidly in the last 10 years.