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Sample records for la-icp-ms u-pb zircon

  1. Simultaneous in-situ determination of U-Pb age and trace elements in zircon by LA-ICP-MS in 20 μm spot size

    Institute of Scientific and Technical Information of China (English)

    LIU XiaoMing; GAO Shan; DIWU ChunRong; YUAN HongLin; HU ZhaoChu

    2007-01-01

    Simultaneous in-situ determination of U-Pb agea and 20 trace elements of three international zircon standards (91500, GJ1 and TEMORA 1) and one laboratory zircon standard (SK10-2) separated from Cenozoic fine-grained gabbro was carried out on quadrupole ICP-MS equipped with 193 nm excimer laser in 20 μm spot size. The weighted mean 208Pb/238U ages of g1500, GJ1 and TEMORA 1 are 1064.4±4.8 Ma (2σ), 603.2±2.4 Ma (2σ) and 418.2±2.4 Ma (2σ), respectively. The relative standard deviations (RSDs) of 206Pb/238U ages (2σ) are less than 2.2% for single measurements and 0.6% for weighted means. The obtained weighted mean 206Pb/238U ages of three atandard zircons agree with the recommended values within 2σσerror. The weighted mean 206Pb/238U age of SK10-2 is 31.42±0.25 Ma (2σ)and the RSDs of 206Pb/238U ages (2σ) are between 2.4% and 5.7% for single measurements and less than 0.8% for weighted mean. The obtained weighted mean 206Pb/238U age is in good agreement with the age obtained by Yuan (2004). Trace element concentrations of NIST612 and NIST614 obtained under the same LA-ICP-MS operating conditions agree with the recommended values within analytical error. The results indicate that it is possible to measure U-Pb age and trace elements aimultaneously by LA-ICP-MS in a small spot size of 20 μm.

  2. Primera edad U-Pb en circón usando LA-ICP-MS de un dique traquiandesítico emplazado en el granito tipo-A Los Árboles, Sierras Pampeanas Orientales First age U-Pb zircon LA-ICP-MS from trachyandesitic dyke emplaced in the A-type Los Árboles pluton, Eastern Sierras Pampeanas

    Directory of Open Access Journals (Sweden)

    Juan A Dahlquist

    2012-06-01

    Full Text Available La edad de cristalización de diques subvolcánicos emplazados en plutones graníticos carboníferos, Sierras Pampeanas Orientales, permanece incierta. La primera edad U-Pb en circón usando LA-ICP-MS obtenida en un dique que intruye al plutón Los Árboles (sierra de Fiambalá, revela una edad de cristalización de 311 ± 3 Ma.The crystallization age of subvolcanic dykes emplaced in Carboniferous granitic plutons of the Sierras Pampeanas Orientales remains uncertain. The first age precise U-Pb zircon LA-ICP-MS obtained from a dyke emplaced in the Los Árboles pluton (Sierra de Fiambalá yield a crystallization age of 311 ± 3 Ma.

  3. Geochemistry and LA-ICP-MS zircon U-Pb dating of the Dongjiahe ophiolite complex from the western Bikou terrane

    Institute of Scientific and Technical Information of China (English)

    LAI; ShaoCong; LI; YongFei; QIN; JiangFeng

    2007-01-01

    The Dongjiahe ophiolite complex occurring in the western Bikou terrane that is composed chiefly of serpentinite, listwanitizational peridotite, gabbro, cumulus gabbro, and sub-alkaline meta-basalt, possesses a rock association of typical ophiolite sequence. The metaperidotite is depleted in light rare earth element (LREE), whereas the gabbro and meta-basalt from the studied ophiolite sequence, generated by the same parental magmas those have close affinity to the MORB (Mid-ocean ridge basalt), their REE and immobile elements patterns imply an ocean in the northern margin of the Yangtze plate during the Neoproterozoic period. The zircon LA-ICP-MS U-Pb dating for the gabbro yields a weighted mean age of 839.2±8.2Ma, suggesting that the basin occurred during the Neoproterozoic period.

  4. Uplift of Northwest Margin of Tibetan Plateau: Indicated by Zircon LA ICP-MS U-Pb Dating of Conglomerate from Mazartagh, Tarim Basin

    Institute of Scientific and Technical Information of China (English)

    Si Jialiang; Li Haibing; Pei Junling; Pan Jiawei

    2009-01-01

    Radiometric age dating of detrital zircons is highly advantageous for analysis of the depositional environment and to identify source areas. Aiming at the uplift and denudation of the surrounding ranges, LA ICP-MS U-Pb analysis has been performed on zircon grains from a conglomerate collected at the Lower Pilocene of Mazartagh, which is in the center of the Tarim basin, Xinjinng (新疆), China. A wide range of ages mainly failing into three groups was yielded: 200-500, 800-1 100, and 1 800-2 000 Ma. Zircon features principally indicate magmatic origin. According to the comparison between the analyzed zircons with those from surrounding orogenic belts, the younger grains are mainly related to the west while the older ones are to the regions more eastward. The variations might imply the W-E propagation tectonic activation and uplift of the surrounding orogenic belts. The west segment uplifted and was denuded firstly, driven by the approximate W-E height difference, upon the denudation, transportation and deposition, acting as the source of young zircons analyzed. With the eastward spreading of tectonic movement, the segment more to the east rose, the meridional relief in creased rapidly and began to control the flow direction, then more zircons joined in the Pliocene in Mazartagh. It is difficult to definitely explain the source of grains with similar values to that from the Altyn Mountain region, more detailed data and chronological ages with higher precision will be helpful for making more credible conclusion.

  5. Single Zircon LA-ICP-MS U-Pb Dating of the Guandimiao and Wawutang Granitic Plutons in Hunan, South China and Its Petrogenetic Significance

    Institute of Scientific and Technical Information of China (English)

    CHEN Weifeng; CHEN Peirong; ZHOU Xinmin; HUANG Hongye; DING Xing; SUN Tao

    2007-01-01

    The Guandimao and Wawutang plutons are located at the center of Hunan, South China.The former is mainly composed of biotite monzonitic granites/granodiorites and two-mica monzonitic granites, but the latter only consists of biotite monzonitic granites. The zircon ages of 203.0±1.6 Ma (biotite monzonitic granites) and 208.0±3.2 Ma (two-mica monzonitic granites) for the Guandimao pluton and 204±3 Ma for the Wawutang pluton obtained with the LA-ICP-MS U-Pb dating indicate that they were formed during the late Indosinian. In consideration of other geochronological data from Indosinlan rocks of South China and adjacent regions, it is inferred that the two plutons were derived from crustal materials by decompressional melting in a post-collisional tectonic setting during spontaneous thinning of the thickened curst. Moreover, the inherited zircon age of 1273±k57 Ma from the Wawutang pluton indicates that the source of the two plutons is related to the early Proterozoic crustal basement.

  6. LA-ICP-MS zircon U-Pb dating and phenocryst EPMA of dikes, Guocheng, Jiaodong Peninsula: Implications for North China Craton lithosphere evolution

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Widespread dike swarm, including diorite-, monzonite-porphyry and lamprophyre, intruded in the al- tered breccia gold deposits along basin marginal faults, Guocheng, Jiaodong Peninsula. Petrography exhibits biotite enclaves in amphibole phenocrysts and the presence of acicular apatites in these dikes. Electron probe microanalyses (EPMA) show that the amphibole and clinopyroxene phenocryst’s mantle in diorite porphyry and lamprophyre respectively has sharply higher MgO (Mg#) and Cr2O3 contents in contrast to their cores. The plagioclase phenocryst in monzonite porphyry has reverse zoning. These results indicate that the magma mixing between mantle-derived mafic and crust-derived felsic magmas occurred in the original process of the dikes. Zircon cathodoluminescence (CL) images show well-developed magmatic oscillatory zones and the acquired LA-ICP-MS zircon U-Pb weighted mean 206Pb/238U ages are 114±2 Ma (MSDW=1.5) for monzonite porphyry (GS1) and 116±1 Ma (MSDW=0.8) for diorite porphyry (GS2), respectively. Earlier magmatic events in the northwest Jiaodong Peninsula represented by some inherited or captured zircons also occur in these dikes. Magmatic zircons from GS1 and GS2 display consistent chondrite-normalized REE patterns and Nb/Ta values, implying that they may share a similar or same source. HREE enrichment and obvious negative Eu anomalies of these zircons preclude garnet presented in their source. Our results, combined with preciously pub- lished data, indicate that dike intrusion and gold mineralization among quartz vein, altered tectonite and altered breccia gold deposits are broadly contemporaneous throughout the Jiaodong Peninsula. These also imply that the intensive crust-mantle interaction and asthenospheric underplating had oc- curred in the Early Cretaceous in the Peninsula, together with foundering of lower crust in the early Mesozoic, representing the different stages of lithosphere thinning in the North China Craton (NNC).

  7. LA-ICP-MS zircon U-Pb dating and phenocryst of dikes, Guocheng, Jiaodong Peninsula: Implications for North China Craton lithosphere evolution

    Institute of Scientific and Technical Information of China (English)

    TAN Jun; WEI JunHao; GUO LingLi; ZHANG KeQing; YAO ChunLiang; LU JianPei; LI HongMei

    2008-01-01

    Widespread dike swarm, including diorite-, monzonite-porphyry and lamprophyre, intruded in the altered breccia gold deposits along basin marginal faults, Guocheng, Jiaodong Peninsula. Petrography exhibits biotite enclaves in amphibole phenocrysts and the presence of acicular apatites in these dikes.Electron probe microanalyses (EPMA) show that the amphibole and clinopyroxene phenocryst's mantle in diorite porphyry and lamprophyre respectively has sharply higher MgO (Mg#) and Cr203 contents in contrast to their cores. The plagioclase phenocryst in monzonite porphyry has reverse zoning. These results indicate that the magma mixing between mantle-derived mafic and crust-derived felsic magmas occurred in the original process of the dikes. Zircon cathodoluminescence (CL) images show well-developed magmatic oscillatory zones and the acquired LA-ICP-MS zircon U-Pb weighted mean 206pb/238U ages are 114±2 Ma (MSDW=1.5) for monzonite porphyry (GS1) and 116±1 Ma (MSDW=0.8) for diorite porphyry (GS2), respectively. Earlier magmatic events in the northwest Jiaodong Peninsula represented by some inherited or captured zircons also occur in these dikes. Magmatic zircons from GSl and GS2 display consistent chondrite-normalized REE patterns and Nb/Ta values, implying that they may share a similar or same source. HREE enrichment and obvious negative Eu anomalies of these zircons preclude garnet presented in their source. Our results, combined with preciously published data, indicate that dike intrusion and gold mineralization among quartz vein, altered tectonite and altered breccia gold deposits are broadly contemporaneous throughout the Jiaodong Peninsula.These also imply that the intensive crust-mantle interaction and asthenospheric underplating had occurred in the Early Cretaceous in the Peninsula, together with foundering of lower crust in the early Mesozoic, representing the different stages of lithosphere thinning in the North China Craton (NNC).

  8. The LA-ICP-MS zircons U-Pb ages and geochemistry of the Baihua basic igneous complexes in Tianshui area of West Qinling

    Institute of Scientific and Technical Information of China (English)

    PEI; XianZhi; DING; SaPing; ZHANG; GuoWei; LIU; HuiBin; LI; ZuoChen; LI; GaoYang; LIU; ZhanQing; MENG; Yong

    2007-01-01

    Baihua meta-igneous complex consists mainly of pyroxenite-gabbro(diorite)-diorite-quartz diorite. They form a complete comagmatic evolutionary series. The geochemical characteristics of basic-interme- diate basic igneous rocks indicate that they belong to a tholeiite suite. The REE distribution pattern is nearly flat type and LREE is slightly enriched type, and their primitive mantle-normalized and MORB-normalized trace element spider diagrams are generally similar; the LIL elements (LILE) Cs, Ba, Sr, Th and U are enriched, but Rb, K and the HFSEs Nb, P, Zr, Sm, Ti and Y are relatively depleted. All these show comagmatic evolution and origin characteristics. The tectonics environment discrimination of trace element reveals that these igneous complexes formed in an island-arc setting. The LA-ICP-MS single-zircons U-Pb age of Baihua basic igneous complex is 434.6±1.5 Ma (MSWD = 1.3), which proves that the formation time of the island-arc type magmatite in the northern zone of West Qinling is Late Ordovician or Early Silurian, also reveals that the timing of subduction of paleo-ocean basin represented by the Guanzizhen ophiolite and resulting island-arc-type magmatic activities is probably Middle-Late Ordovician to Early Silurian.

  9. LA-ICP-MS U-Pb Zircon Geochronology of Basic Dikes within Maxianshan Rock Group in the Central Qilian Orogenic Belt and Its Tectonic Implications

    Institute of Scientific and Technical Information of China (English)

    He Shiping; Wang Hongliang; Chen Junlu; Xu Xueyi; Zhang Hongfei; Ren Guangming; Yu Jiyuan

    2007-01-01

    A large number of basic dikes, which indicate an important tectonic-magmatic event in the eastern part of the Central Qilian (祁连) orogenic belt, were found from Maxianshan (马衔山) rock group, Yongjing (永靖) county, Gansu (甘肃) Province, China. According to the research on the characteristics of geology and petrology, the basic dike swarms, widely intruded in Maxianshan rock group,are divided into two phases by the authors. U-Pb isotope of zircons from the basic dikes above two phases is separately determined by LA-ICP-MS in the Key Laboratory of Continental Dynamics of Northwest University, China and the causes of formation of the zircons are studied using CL images.The formation age of the earlier phase of metagabbro dikes is (441.1±1.4) Ma (corresponding to the early stage of Early Silurian), and the age of the main metamorphic period is (414.3±1.2) Ma (corresponding to the early stage of Early Devonian). The formation age of the later phase of diabase dike swarms is (434±1.0) Ma (corresponding to the late stage of Early Silurian). The cap- tured-zircons from diabase dike swarms saved some information of material interfusion by Maxianshan rock group (207pb/206Pb apparent ages are (2325±3)-(2573±6) Ma), and some zircons from diabase dike swarms also saved impacted information by tectonic thermal event during the late period of Caledonian movement (206pb/238U apparent ages are (400±2)-(429±2) Ma). By combining the results of the related studies, the basic dikes within Maxianshan rock group were considered to be formed in the transfer period, from subductional orogeny towards collisional orogeny, which represents geological records of NW-SE extension during regional NE-SW towards intense compression in the Central Qilian block.

  10. Zircon LA-ICP-MS U-Pb dating and Sr-Nd isotope study of the Guposhan granite complex, Guangxi, China

    Institute of Scientific and Technical Information of China (English)

    GU Shengyan; HUA Renmin; QI Huawen

    2007-01-01

    Zircon U-Pb dating by the LA-ICP-MS method was applied to determining the ages of different units of the Guposhan granite complex, among which the East Guposhan unit is 160.8±1.6 Ma, the West Guposhan unit is 165.0±1.9 Ma, and the Lisong unit is 163.0±1.3 Ma in age. Much similarity in ages of the three units has thus proved that the whole Guposhan granite complex was formed in the same period of time. They were the products of large-scale granitic magmatism through crust-remelting in the first stage of the Middle Yanshanian in South China. However, the three units have differences both in petrology and in geochemistry. Besides the differences in major, trace and rare-earth elements, they are distinct in their Rb-Sr and Sm-Nd isotopic compositions. The East Guposhan unit and Lisong unit and its enclaves have a similar (87Sr/86Sr)i value of 0.7064 with an average of εNd(t)=-3.03, indicating that more mantle material was evolved in the magma derivation; whereas the West Guposhan unit has a higher (87Sr/86Sr)i value of 0.7173 but a lower εNd(t) value of -5.00, and is characterized by strong negative Eu anomalies and higher Rb/Sr ratios, suggesting that its source materials were composed of relatively old crust components and new mantle-derived components. In addition, an inherited zircon grain in the East Guposhan unit (GP-1) yielded a 206Pb/238U age of 806.4 Ma, which is similar to the ages of the Jiulin cordierite granite in northern Jiangxi and of the Yinqiao migmatic granite in Guangxi in the HZH granite zone. All this may provide new evidence for Late Proterozoic magmatism in the HZH granite zone.

  11. Geochemical Characteristics and LA-ICP-MS Zircon U-Pb Dating of Amphibolites in the Songshugou Ophiolite in the Eastern Qinling

    Institute of Scientific and Technical Information of China (English)

    LIU Liang; CHEN Danling; ZHANG Anda; ZHANG Chengli; YUAN Honglin; LUO Jinhai

    2004-01-01

    in basalts from other regions of the world. The LA-ICP-MS trace element and U-Pb isotopic analyses show that the zircon grains from the amphibolites are similar to the typical magmatic zircon in terms of their very low U and Th contents (62.36-0.10 μg/g and 78.47-0.003 μtg/g, respectively). Seven pits from the core and core-mantle parts of the zircon grains yielded an average weighted 206Pb/238U age of 973+35 (2σ) Ma with the Th/U ratios range from 0.01 to 8.38 and mostly greater than 0.23. This age is consistent within the error range with the whole-rock Sm-Nd isochron age of 1030±46 Ma for the same kind of rocks reported by Dong et al. (1997a). In a combined analysis with the zircon positions on the CL images and the corresponding Th/U ratios, the age of 973±35 Ma is probably the formation age of tholeiite, the protolith of the Songshugou amphibolite. The geochronological determination gives further evidence that the Songshugou ophiolite was formed during the Neoproterozoic. In addition, there is one pit from the rim of a zircon grain giving a 206pb/238U age of 572+ 199 (1 σ) Ma with a Th/U ratio of 0.08. It may represent the age of the accretionary zircon in the amphibolite-facies metamorphism.

  12. LA--ICP--MS zircon U--Pb age of Dongliang pluton in Balinyouqi,Inner Mongolia and its geochemical characteristics%内蒙古巴林右旗东梁岩体 LA--ICP--MS 锆石 U--Pb 定年及地球化学特征

    Institute of Scientific and Technical Information of China (English)

    王璐; 赵庆英; 李鹏川; 李子昊; 邱士龙; 田子龙

    2016-01-01

    The study of the petrologic,chronological and geochemical characteristics of Dongliang pluton in Balinyouqi,Inner Mongolia shows that the lithology of Dongliang pluton is of quartz diorite,while the LA--ICP--MS zircon U --Pb dating shows the weighted average age as (251.9 ±4.4) Ma,representing the Dongliang pluton formed in the Early Triassic.The geochemical characteristics indicate that the rocks are enriched in Si,Al,Na, and depleted in Mg,K.The A /CNK is 0.98 ~1.11,showing the pluton is of calc-alkalic metaluminous-weakly peraluminous rocks.The quartz diorite is rich in LREE,depleted in HREE and without Eu,Ce anomaly,which shows the characteristics of high Sr,low Y and Yb,belonging to adakite rocks.Combined with previous resear-ches,the authors believe that the magma of Dongliang pluton may be originated from the partial melting of juvenile crust caused by the collision and suturing of Siberian Plate and North China Plate.%本文对内蒙古巴林右旗东梁岩体进行的岩石学、年代学和地球化学研究显示,东梁岩体岩性为石英闪长岩,LA-ICP-MS 锆石 U-Pb 定年加权平均年龄为(251.9±4.4)Ma,指示东梁岩体形成于早三叠世。地球化学特征表明岩石富硅、铝、钠,贫镁、钾,A /CNK =0.98~1.11,属于钙碱性准铝质-弱过铝质岩石,轻稀土富集,重稀土亏损,不具 Eu 和 Ce 异常,具有高 Sr、低 Y、低 Yb 的特征,属于埃达克岩。结合区域已有研究成果,认为东梁岩体的岩浆可能来源于西伯利亚板块和华北板块碰撞拼合所导致的新生地壳部分熔融。

  13. A Modern Analog to the Depositional Age Problem: Zircon and Apatite Fission Track and U-Pb Age Distributions by LA-ICP-MS

    Science.gov (United States)

    Donelick, H. M.; Donelick, M. B.; Donelick, R. A.

    2012-12-01

    Sand from three river systems in North Idaho (Snake River near Lewiston, Clearwater River near Lewiston and the Salmon River near White Bird) and two regional ash fall events (Mt. Mazama and Mt. St. Helens) were collected for zircon U-Pb detrital age analysis. Up to 120 grains of zircon per sample were ablated using a Resonetics M-50 193 nm ArF Excimer laser ablation (LA) system and the Pb, Th, and U isotopic signals were quantified using an Agilent 7700x quadrupole inductively coupled plasma-mass spectrometer (ICP-MS). Isotopic signals for major, minor, and trace elements, including all REEs, were also monitored. The youngest zircon U-Pb ages from the river samples were approximately 44 Ma; Cenozoic Idaho Batholith and Precambrian Belt Supergroup ages were well represented. Significant common Pb contamination of the Clearwater River sample (e.g., placer native Cu was observed in the sample) precluded detailed analysis of the zircon U-Pb ages but no interpretable ages <44 Ma were observed. Interestingly, not one of the river samples yielded zircon U-Pb ages near 0 Ma, despite all three catchment areas having received significant ash from Mt. St. Helens in 1980, and Mount Mazama 7,700 years ago, and no doubt other events during the Quaternary. Work currently in progress seeks to address bias against near 0 Ma ages in the catchment areas due to: a) small, local ash fall grain sizes and b) overwhelming number of older grains relative to the ash fall grains. Data from Mt. St. Helens ash from several localities near the mountain (Toutle River and Maple Flats, WA) and several far from the mountain (Spokane, WA; Princeton, ID; Kalispell, MT) and Mt. Mazama ash fall deposits near Lewiston, ID and Spokane, WA will be presented to address these possibilities. Additionally, fission track and U-Pb ages from apatites collected from these river and ash fall samples will also be shown to help constrain the problem.

  14. 滇东南建水火山岩 LA-ICP-MS 锆石 U-Pb 测年、地球化学特征及地质意义%LA-ICP-MS Zircon U-Pb Dating, Geochemical Characteristics of Volcanic Rocks in Jianshui, Southeast Yunnan and Their Geological Implications

    Institute of Scientific and Technical Information of China (English)

    陈超; 周涛; 胡维云; 陈桂凡; 李华亮; 张林友; 李德威

    2016-01-01

    滇东南建水地区位于师宗‒弥勒构造带的南段,区内出露一套玄武岩–安山岩–英安岩–流纹岩组合。研究这套火山岩的形成时间和形成环境对认识滇东南构造格局有着重要意义。本文首次对建水火山岩进行 LA-ICP-MS 锆石 U-Pb 测年,获得两个样品的年龄分别为261.9±2.2 Ma (MSWD=0.80)、264.8±1.7 Ma (MSWD=1.12),属中二叠世晚期,代表建水火山岩的形成时间。建水玄武岩与安山岩具有低 TiO2含量(0.50%~0.88%)、高 Mg#(52.0~64.5)、弱富集 LREE((La/Yb)N=1.42~3.44)、富集 LILE(Rb, Th, U, Pb)、轻微亏损 HFSE(Nb, Ta, Ti)的特点,具典型岛弧玄武岩的特征;英安岩和流纹岩高ΣREE 含量(139.5×10–6~313.6×10–6)、富集 LREE((La/Yb)N=4.16~9.78)和 LILE(Rb, Ba, Th, U)、亏损 HFSE(Nb, Ta)、强亏损 Sr、Ti、Y 等元素的特点与典型的岛弧流纹岩相似,但高钾(K2O 含量平均7.73%)、钙碱性(δ=0.93~2.94)、强过铝质(A/CNK=1.13~2.10)的特点使之区别于一般岛弧酸性火山岩,而具有一些上地壳部分熔融形成的 S 型花岗岩的特点。综合建水火山岩岩石组合、地球化学和区域地质背景,认为建水火山岩形成于活动大陆边缘的弧后盆地伸展环境,是地幔部分熔融形成的玄武质岩浆结晶分异与上地壳混染作用的共同结果,与滇桂交界处岛弧火山岩、两广交界处岛弧玄武岩等同为哀牢山洋向北俯冲的产物。%The age and tectonic setting of a set of basalt-andesite-dacite-rhyolite in Jianshui, Southeast Yunnan, south of the Shizong-Mile structural belt is studied in this paper. LA-ICP-MS zircon U-Pb dating of two samples yield 261.9±2.2 Ma (MSWD=0.80) and 264.8±1.7 Ma (MSWD=1.12) respectively. The basalts and andesites are characterized by low TiO2 (0.50%–0.88%), high Mg# (52.0–64.5), slightly enriched LREE ((La/Yb)N=1.42–3.44), enriched LILE (Rb, Th, U, Pb) and slightly depleted HFSE (Nb, Ta, Ti), which are typical of

  15. LA-ICP-MS U-Pb Zircon Dating for Felsic Granulite,Huangtuling Area, North Dabieshan: Constraints on Timing of Its Protolith and Granulite-Facies Metamorphism, and Thermal Events in Its Provenance

    Institute of Scientific and Technical Information of China (English)

    Chen Nengsong; Liu Rong; Sun Min; Li Huimin; He Lei; Wang Qinyan; Zhang Hongfei

    2005-01-01

    Information about the protolith of the Huangtuling granulite in North Dabieshan has been unavailable. The complex evolution history of the rock and its host basement must be further discussed. LA-ICP-MS U-Pb dating was conducted on three textural domains in zircon from a high-temperature, high-pressure felsic granulite in the Huangtuling area, North Dabieshan, Central China. The metamorphic growth-derived detrital zircon domain yields a 207Pb/206Pb age in the range of (2 493±54) -(2 500±180) Ma. The magmatic genesis-derived detrital zircon domain gives a 207Pb/206Pb age ranging from 2 628 Ma to 2 690 Ma, with an oldest 206Pb/238U age of (2 790±150) Ma. The metamorphic overgrowth or metamorphic recrystallization zircon domain yields a dicsordia with an upper intercept age of (2 044.7±29.3) Ma. Compositions of the mineral assemblage, major element geochemistry, and especially the complex interior texture of the zircon suggest that the prololith of the felsic granulite is of sedimentary origin. Results show that the protolith material of the granulite came from a provenance with a complex thermal history, i.e. ~2.8 Ga magmatism and ~2.5 Ga metamorphism, and was deposited in a basin not earlier than 2.5 Ga. The high-temperature and high-pressure granulite-facies metamorphic age was precisely constrained at (2.04±0.03) Ga, which indicates the granulite in Huangtuling area should be a relict of a Paleoproterozoic UHT (ultrahigh temperature) metamorphosed slab.

  16. Possible early Neoproterozoic magmatism associated with slab window in the Pingshui segment of the Jiangshan-Shaoxing suture zone: Evidence from zircon LA-ICP-MS U-Pb geochronology and geochemistry

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    We report here geochemical data, U-Pb zircon ages, and Hf isotopes for the high-Mg diorites (HMDs), Nb-enriched basaltic porphyrys (NEBPs) and plagiogranites (PLAGs) in the Pingshui segment of the Jiangshan-Shaoxing suture zone. The HMDs are characterized by high Mg# (>60), high Na and LREE contents, depletion of HREE and HFSE, and pronounced positive εNd(t) values of 7.0 to 7.7, similar to some adakitic high-Mg andesites. The NEBPs are relatively Na-rich (Na2O/K2O>6) and display high abundances of P2O5 (~1.00%), TiO2 (~3.08%) and HFSE (e.g., Nb=9.53-10.27 ppm). Their Nd isotopic compositions (εNd(t)=6.8-8.0) are comparable to those of the HMDs. The PLAGs are metaluminous (A/CNK=0.84-0.89) and sodic (Na2O/K2O>10). Their depletion in HFSE (e.g., Nb, Ta) is consistent with "SSZ-type" plagiogranite. Zircon LA-ICP-MS U-Pb dating yields an age of 932±7 Ma for the HMD, 916±6 Ma for the NEBP, and 902±5 Ma for the PLAG, respectively, indicating that they were products of early Neoproterozoic magmatism. The PLAGs exhibit relatively high zircon Hf isotopes and positive εHf(t) values of 11.0 to 16.2, consistent with their Nd isotopic data (εNd(t)=7.5-8.4). Such features are similar to those of oceanic plagiogranites in ophiolites and distinct from those of crust-derived granites. The PLAGs were most likely derived from partial melting of subducted oceanic crust in an active continental margin. Considering these results in the context of the regional geology, we suggest that a slab window in the subducting oceanic crust between the Yangtze Block and Cathaysia Block was possibly the principal cause for the unique arc magmatism in the area. The upwelling asthenosphere below the slab window may have provided significant thermodynamic conditions.

  17. Possible early Neoproterozoic magmatism associated with slab window in the Pingshui segment of the Jiangshan-Shaoxing suture zone: Evidence from zircon LA-ICP-MS U-Pb geochronology and geochemistry

    Institute of Scientific and Technical Information of China (English)

    CHEN ZhiHong; GUO KunYi; DONG YongGuan; CHEN Rong; LI LongMing; LIANG YiHong; LI ChunHai; YU XiMing; ZHAO Ling; XING GuangFui

    2009-01-01

    We report here geochemical data, U-Pb zircon ages, and Hf Isotopes for the high-Mg diorites (HMDs), Nb-enriched basaltic porphyrys (NEBPs) and plagiogranitee (PLAGs) in the Pingshui segment of the Jiangshan-Shaoxing suture zone. The HMDs are characterized by high Mg# (>60), high Na and LREE contents, depletion of HREE and HFSE, and pronounced positive εNd(t) values of 7.0 to 7.7, similar to some adakitic high-Mg andesites. The NEBPs are relatively Na-rich (Na2O/K2O>6) and display high abundances of P2Os5(~1.00%), TiO2(~3.08%) and HFSE (e.g., Nb=9.53-10.27 ppm). Their Nd isotopic compositions (εNd(t)=6.8-8.0) are comparable to those of the HMDs. The PLAGs are metaluminous (AJCNK=0.84-0.89) and sodic (Na2O/K2O>10). Their depletion in HFSE (e.g., Nb, Ta) Is consistent with "SSZ-type" plagiogrenite. Zircon LA-ICP-MS U-Pb dating yields an age of 932±7 Ma for the HMD, 916±6 Ma for the NEBP, and 902±5 Ma for the PLAG, respectively, indicating that they were products of early Neoproterozoic magmatism. The PLAGs exhibit relatively high zircon Hf isotopes and positive εHf(t) values of 11.0 to 16.2, consistent with their Nd isotopic data (trod(f)=7.5-8.4). Such features are similar to those of oceanic plagiogranites in ophiolites and distinct from those of crust-derived granites. The PLAGs were most likely derived from partial melting of subducted oceanic crust in an active conUnen- tal margin. Considering these results in the context of the regional geology, we suggest that a slab window in the subducting oceanic crust between the Yangtze Block and Cathaysia Block was possibly the principal cause for the unique arc magmatism in the area. The upwelling aathenosphere below the slab window may have provided significant thermodynamic conditions.

  18. Relationship between Precambrian North Korean Peninsula and the North China Craton: Evidence from LA-ICP-MS U-Pb ages of detrital zircons from Neoproterozoic tillites of North Korea and Southern North China Craton

    Science.gov (United States)

    Hu, B.; Zhai, M.; Peng, P.; Zhang, Y.; Wu, J.; Jia, X.; Zhang, H.; Lei, W.; Zhuang, G.

    2016-12-01

    Relationship between Precambrian Korean Peninsula and the North China Craton (NCC) is focus of attention. There are Neoproterozoic tillites in Phyongnam Basin, Nangrim massif, North Korea (NK) and Southern NCC. Nangrim massif was regarded as a part of the NCC according to similar Precambrian basements between Nangrim massif and Longgang massif in the Northeast NCC. But the comparation of Neoproterozoic rocks is lacked between NK and NCC. Detrital zircon LA-ICP-MS U-Pb ages of 2 pebbly phyllite samples of Pirangdong Series in Phyongnam Basin and 2 argillaceous cemented mix-conglomeate samples of Luoquan Series in Southern NCC was analyzed in this research. Detrital zircon ages of pebbly phyllites of Pirangdong Series distribute mainly at 1.85 Ga, 1.8 Ga, 1.6 Ga, 1.4 Ga and 1.2 Ga. A small number of them are at 3.2 Ga, 2.6 - 2.5 Ga, 2.3 Ga, 2.1 Ga and 900 - 860 Ma. Detrital zircon ages of mix-conglomeates of Luoquan Series mainly focus on 2.5 Ga, 2.2 Ga, 2.0 Ga, 1.8 Ga and 1.6 Ga. Minor of them distribute at 1.12 Ga. The similar age distribution of Pirangdong and Luoquan Series of 2.6 - 2.5 Ga, 2.1 - 2.0 Ga, 1.85 - 1.8 Ga and 1.6 Ga corresponds to Precambrian significant tectonic- magmatic- thermal events of the NCC, which indicates that the Precambrian basement rocks of the NCC are main provenances of both Pirangdong and Luoquan Series. This also confirm that the Phyongnam Basin is a part of Neoproterozoic sedimentary covers of the NCC. It is worth to mention that 1.2 - 1.0 Ga and 900 - 850 Ma magmatic rocks in the NCC are seldom reported which relate to the assemblage and breakup of Rodinia Supercontinent. whereas they crop out widely in the South China Craton (SCC) and was always regarded as a mark distingusing the two craton. 1.2 - 1.0 Ga and 900 - 850 Ma zircon ages preserved in sedimentary rocks not only in North Korea and Southern NCC but also in Northeast NCC and East NCC provide data to compare Neoproterozoic strata between NCC and SCC and important clues to

  19. Zircon LA-ICP-MS U-Pb dating of amphibolite in the southern margin of Altyn Tagh,China and its geological implication%阿尔金山南缘清水泉地区斜长角闪岩锆石LA-ICP-MS U-Pb测年及其地质意义

    Institute of Scientific and Technical Information of China (English)

    唐卓; 马中平; 李向民; 孙吉明

    2011-01-01

    Altyn Tagh Group is the oldest metamorphosed strata in the Altyn Tagh area. Because of lack of precise isotopic dating,some researchers porposed that this Group formed in Neoproterozoic and there were not existence of Neoarchean to Paleoproterozoic metamorphosed basement in Altyn Tagh area. This paper provides the zircon LA-ICP-MS U-Pb isotopic dating result of the amphibolite from Altyn Tagh Group in the southern margin of Altyn Tagh and discusses its geological significance. The CL images of zircons from the amphibolite show that most of the zircons present the typical characteristics of metamorphic zircons with multi-faceted shape structure and without girdle structure and core-rim structure of magmatic zircons and with lower Th/U ratios. Zircon LAICP-MS U-Pb isotopic dating give a weighted mean 207Pb/206Pb age of 1827±13Ma(MSWD=4.4), with 207Pb/206Pb ages ranging from (1786±10) Ma to (1877±12) Ma of 19 analysing plots and suggest that the epoch of metamorphism of the amphibolite is Later Paleoproterozoic. The new data of isotopic chronology indicated that there existed a tectothermal event which corresponds to Ltiliang orogenic movement in China and maybe related to the converging or breakup event of global Columbia suppercontinent in Paleoproterozoic. The result also indicate that there are Neoarchean-Paleoproterozoic metamorphosed basement in the Altyn Tagh area and provide a new data for research Precambrian teotothermal events and the evolution of Altyn Tagh belt.%阿尔金群为阿尔金构造带的古老变质基底,由于缺乏精确的同位素测年数据,对其形成时代尚存争议.运用LA-ICP-MS锆石U-Pb定年分析方法,对阿尔金山南缘清水泉地区阿尔金群中的斜长角闪岩进行了年代学测定.并初步探讨其地质意义.锆石CL图像具有多晶面面状结构,无岩浆锆石具有的震荡环带和核边结构.Th/U比值大多都较低(<0.1),显示变质锆石的特点.18个锆石颗粒的19个测点给出的207Pb

  20. 广西大瑶山古罗碱性辉长岩体 LA-ICP-MS 锆石 U-Pb 年龄、岩石学、地球化学及其构造意义%Zircon LA-ICP-MS U-Pb age, petrog-raphy, geochemistry and tectonic implications of the Guluo alkaline gabbroic rock in the Dayaoshan, Guangxi

    Institute of Scientific and Technical Information of China (English)

    许华; 黄炳诚; 倪战旭; 韩淑朋; 黄英; 龚云

    2014-01-01

    古罗碱性辉长岩体包括古罗、黄羌冲两个侵入体,主要由辉长岩、石英辉长岩(或石英闪长岩)组成。岩石以富碱、富集大离子亲石元素(LILE)、轻稀土元素(LREE)和高场强元素(HFSE),无 Nb、Ta 异常,是典型的板内钾玄岩。对古罗辉长岩体进行了高精度的 LA-ICP-MS 锆石 U-Pb 定年,获得石英辉长岩的206Pb/238U 加权平均年龄为165.63±0.95 Ma。研究认为古罗碱性辉长岩体形成于中侏罗世,属典型的板内钾玄岩,形成于大陆地壳伸展拉张减薄的构造背景,为燕山期早期华南后造山阶段的地质记录。%Guluo alkaline gabbroic magmatic rocks including Guluo and Huangqiangchong intrusive rocks are comprising of gabbro, quartz-gabbro (or quartz-diorite). These rocks are enriched in alkalies, LILE, LREE and HFSE, characteristed by no Nb and Ta anomalies, which indicates belongs to typical intrapate-shoshonite series. Zircon LA-ICP-MS U-Pb dating of Guluo alkaline gabbroic rocks yields the 206Pb/238U age of 165.63±0.95 Ma. The geochronology data suggests that Guluo alkaline gabbroic rocks as typical intrapate-shoshonite series was formed in the Middle Jurassic Period, and indicated that the magma was generated in the tectonic settings of con-tinental crust extension and thinning, which records post-orogenesis event of South China in the Early Yanshan-nian period.

  1. LA-ICP-MS Zircon U-Pb Ages and Implications for Tectonic Setting of the Mangling Granitoid Plutons in Qinling Orogen Belt%秦岭造山带蟒岭花岗岩锆石LA-ICP-MS U-Pb年龄及其地质意义

    Institute of Scientific and Technical Information of China (English)

    秦海鹏; 吴才来; 武秀萍; 雷敏; 侯振辉

    2012-01-01

    蟒岭花岗岩位于东秦岭地区商南-丹凤断裂带北侧的北秦岭构造带上,呈北西西走向,与区域构造线方向基本一致.本文报道了该岩体的锆石LA-ICP-MS U-Pb定年数据和地球化学数据,并结合前人的资料初步总结了该岩体的年代学特征.结果显示,蟒岭花岗岩的岩浆演化可以分为两个阶段:晚侏罗世-早白垩世的二长花岗岩(158.4±1.8Ma~160.5±1.3Ma)和早白垩世中期的钾长花岗岩(124.1±2.0Ma).此外,样品09CL264获得锆石继承核部年龄为1883±36Ma、1860±35Ma,可能代表了源岩年龄.地球化学特征上,早期的二长花岗岩具有高硅、碱,K2O/Na2O>1,以及高Sr、低Yb、Y的特征,而晚期的钾长花岗岩具有高硅、碱,K2O/Na2O<1,低Sr、低Y、Yb的特征.其中,晚侏罗世-早白垩世的二长花岗岩(09CL260)的εHf(t)值变化于-9.4~-3.1,暗示其可能具有多源特征,源岩主要为下地壳元古宙物质.%The Mangling granite is located on the north side of the Shannan-Danfeng foult, eastern sector of the north Qinling Orogen. The granite is in North-West-West strech and in agreement with structural lineament. The paper reports the results of Zircon LA-ICP-MS U-Pb age and geochemical data. The results show that the Mangling granite includs two granite emplacements. Early Monzogranite whose ages ranging from 158.4 ± 1. 8Ma to 160.5 ± 1.3 Ma belongs to Late Jurassic Early Cretaceous period and the late alkali granite has an age of 124. 1 ± 2.0 Ma belonging to Middle Cretaceous. In addition, sample 09CL264 give inherited core age of 1883 ±36Ma and 1860 ±35 Ma belonging to proterozoic and may represent its protolith age. In geochemistry, monzogranite with the characteristics of high SiO2, K2O + Na2O , K2O/Na2O > 1 and high Sr low Yb, Y. The alkali granite has the characteristic ofhighSiO2, K2O + Na2O, K2O/Na2O

  2. Zircon LA-ICP MS U-Pb Age, Sr-Nd-Pb Isotopic Compositions and Geochemistry of the Triassic Post-collisional Wulong Adakitic Granodiorite in the South Qinling, Central China, and Its Petrogenesis

    Institute of Scientific and Technical Information of China (English)

    QIN Jiangfeng; LAI Shaocong; WANG Juan; LI Yongfei

    2008-01-01

    The Indosinian post-collisional Wulong pluton intruded into the Mesoproterozoic Fuping Group, South Qinling, central China. In the southern part of the pluton, some mafic enclaves have sharp or gradational contact relationships with the host biotite granodiorite. Geochemistry, zircon LA-ICP MS (laser ablation inductively-coupled plasma mass spectrometry) U-Pb chronology and Sr- Nd-Pb isotope geochemistry of the pluton are reported in this paper. The biotite granodiorite shows close compositional similarities to high-silica adakite. Its chondrite-normalized REE patterns are characterized by strong HREE depletion (Yb = 0.33-0.96 10-6 and Y = 4.77-11.19×10-6), enrichment of Ba (775-1386×10-6) and Sr (643-1115×10-6) and high Sr/Y (57.83-159.99) and Y/Yb (10.99-14.32) ratios, as well as insignificant Eu anomalies (δEu = 0.70-0.83), suggesting a feldspar-poor, garnet±amphibole-rich residual mineral assemblage. The mafic enclaves have higher MgO (4.15- 8.13%), Cr (14.79-371.31×10-6), Ni (20.00-224.24×10-6) and Nb/Ta (15.42-21.91) than the host granodiorite, implying that they are mantle-derived and might represent underplated mafic magma. Zircon LA-ICP MS dating of the granodiorite yields a 20.6Pb/238U weighted mean age of 208±2 Ma (MSWD=0.50, 1σ), which is the age of emplacement of the host biotite granodiorite. This age indicates that the Wulong pluton formed during the late-orogenic or post-collisional stage (≤242±21 Ma) of the South Qinling belt. The host biotite granodiorite displays 87Sr/86Sr = 0.7059-0.7062, Isr = 0.7044-0.7050,143Nd/144Nd = 0.51236-0.51238, εNd(t)=-2.26 to-2.66,2.6Pb/2.4pb=18.099-18.209,207Pb/2.4pb=15.873-15.979 and 2.8Pb/204pb=38.973-39.430. Those ratios are similar to those of the Mesoproterozoic Yaolinghe Group in the South Qinling. Furthermore, its Nd isotopic model age(~1.02 Ga) is consistent with the age (~1.1 Ga) of the Yaolinghe Group. Based on the integrated geological and geochemical studies, coupled with previous

  3. The Cadomian Orogeny and the opening of the Rheic Ocean: The diacrony of geotectonic processes constrained by LA-ICP-MS U Pb zircon dating (Ossa-Morena and Saxo-Thuringian Zones, Iberian and Bohemian Massifs)

    Science.gov (United States)

    Linnemann, Ulf; Pereira, Francisco; Jeffries, Teresa E.; Drost, Kerstin; Gerdes, Axel

    2008-12-01

    Cadomian orogenic processes and their continuum to the opening of the Rheic Ocean were modeled by making use of new LA-ICP-MS U-Pb ages from detrital zircons of sedimentary rocks of Late Neoproterozoic (Ediacaran) and Cambro-Ordovician sediments of the Ossa-Morena Zone (Iberian Massif) compared with those from the Saxo-Thuringian Zones (Bohemian Massif). Presented data constrain a diachrony of Cadomian and related geotectonic processes along the northern realm of the Gondwana Supercontinent. Early stage of Cadomian evolution is characterized by a continental magmatic arc at the periphery of the West African Craton and a related back-arc basin opened at c. 590 to 570 Ma. Diacronic arc-continent collision was caused by oblique vector of subduction and started first in the East of Peri-Gondwana at c. 560-570 Ma and resulted at c. 543 Ma in the formation of a short-lived Cadomian retro-arc basin in the Saxo-Thuringian Zone. In contrast, more to the West in the Ossa-Morena Zone, the Cadomian back-arc basin was longer active, at least until c. 545 Ma. In that region, final magmatic pulse of the Cadomian magmatic arc at c. 550 Ma is documented by new zircon data. Closure of the Cadomian back-arc basin and arc-continent collision in the Ossa-Morena Zone occurred between c. 545 Ma and the overall onset of Cambrian plutonism at c. 540 Ma. A mid-oceanic ridge was subducted underneath the Cadomian orogen accompanied by slab break-off of the subducted oceanic plate. Oblique incision of the oceanic ridge into the continent caused the formation of rift basins during the Lower to Middle Cambrian (c. 530-500 Ma). This process continued and finally caused the opening of the Rheic Ocean documented by thick Lower Ordovician siliciclastic sediments and a final magmatic event at c. 490-485 Ma. Opening of the Cambrian rift basin and of the Rheic Ocean again was diachronic and started from the West of Peri-Gondwana and expanded eastward.

  4. 大兴安岭北部红水泉组碎屑锆石LA-ICP-MS U-Pb年代学及其地质意义%LA-ICP-MS U-Pb Geochronology of Detrital Zircon from the Hongshuiquan Formation in the Northern Da Hinggan Area and Its Tectonic Significance

    Institute of Scientific and Technical Information of China (English)

    赵芝; 迟效国; 赵秀羽; 孙巍; 潘世语; 胡兆初

    2012-01-01

    红水泉组广泛出露于大兴安岭北部地区,主要由杂砂岩、砂板岩、碳酸盐岩和凝灰岩组成,含腕足、珊瑚和苔藓虫化石,时代为早石炭世.对额尔古纳右旗和扎兰屯地区的红水泉组砂岩样品进行了LA-ICP-MS锆石U-Pb测年.结果显示,87个谐和-近谐和年龄主要分布在4个年龄区间:353~379 Ma,峰值年龄约为366Ma;428~473Ma,峰值年龄约为441Ma和464Ma;487~521Ma,峰值年龄约为502Ma;1 790~1943Ma,峰值年龄约为1 848Ma.其中:约366、441、464和502Ma的峰值年龄与额尔古纳、兴安地块的岩浆事件基本吻合,1 848 Ma的峰值年龄普遍存在于2个地块,说明红水泉组的沉积物主要来自额尔古纳—兴安地块;约366Ma的峰值年龄反映沉积物部分来自大兴安岭北部晚泥盆世火山弧,物源区具有双向性(古老陆壳和火山弧).结合区域早石炭世沉积特征认为红水泉组为一套弧后盆地沉积.%The Hongshuiquan Formation, widely exposed in the northern Da Hinggan area, consists mainly of greywacke, sand-slate, carbonate rocks and tuffs, in which brachiopods, corals and bryozoans flourished in Early Carboniferous. LA - ICP - MS zircon U - Pb dating of the sandstones from the Hongshuiquan Formation in Ergun and Zhalantun area is carried out in order to discuss the Early Carboniferous basin type. Results show that 87 zircon concordant ages give four age groups: 353 - 379 Ma with peak age at 366 Ma, 428 - 473 Ma with peak age at 441 Ma and 464 Ma, 487 - 521 Ma with peak age at 502 Ma and 1 790 -1 943 Ma with peak age at 1 848 Ma. In this frame, the peak ages of 366 Ma, 441 Ma, 464 Ma and 502 Ma are consistent with the magmatic events in Ergun and Xing'an blocks, and the peak age of 1 848 Ma is widely existed in the two blocks, suggesting that sediments of the Hongshuiquan Formation mainly derive from Ergun-Xing'an blocks. The youngest peak age of 366 Ma indicates that the sediments come partly from the Late

  5. Petrology and LA-ICP-MS Zircon U-Pb Geochronology of the Qianjinchang Pluton, Southeastern Inner Mongolia%内蒙古前进场岩体岩石学与锆石U-Pb年代学研究

    Institute of Scientific and Technical Information of China (English)

    徐佳佳; 赖勇; 崔栋; 鲁彬

    2012-01-01

    The Qianjinchang biotite granite from southeastern Inner Mongolia is located in the suture zone between the Siberian and North China Cratons. The Daolundaba Cu-W-Sn polymetallic deposit formed at the contact zone between the north-west margin of the pluton and the Lower Permian Linxi Formation. The biotite granite is high-K calc-alkaline and peraluminous, with Na2O+K2O: 6.12% to 9.31%, Al2O3: 14.42% to 15.59%, A/CNK: 1.09 to 1.22, and a mean 5value of 2.41. The rock samples lie within the S-type granite region in the ACF plot. They are depleted in Sr (89.91 to 192.80 μg/g), Ba, Eu (δEu: 0.46 to 0.81) and δREE (102.65 to 237.92 μg/g), but slightly enriched in Yb (2.17 to 3.46 μg/g) and La, consistent with the characteristics of S-type granites. The rocks further fall in the region of post-collisional granite in the Rb vs. Y+Nb diagram. LA-ICP-MS zircon U-Pb geochronology shows that the pluton emplaced at (273±7.7) to (278 ±4.3) Ma. These Permian granite rocks probably formed in an extensional setting that postdated the collision between the Siberian and North China Cratons.%前进场黑云母花岗岩岩体位于内蒙古东南部,华北板块与西伯利亚板块碰撞的缝合部位。岩体北西边缘与林西组地层的接触带发育道伦达坝中型铜-钨-锡多金属岩浆热液矿床。岩石地球化学研究表明,黑云母花岗岩为高钾钙碱性系列的过铝质花岗岩,Na2O+K2O含量为6.12%-9.31%,Al2O3含量为14.42%-15.59%,A/CNK值为1.09-1.22,万均值为2.41,在花岗岩ACF图解中落人s型花岗岩区。全岩总稀土含量为102.65~237.92μg/g,低Sr(89.91-192.80μg/g)高Yb(2.17~3.46μg/g),δEu值为0.46~0.81,亏损Ba,Sr,Eu,富集La,显示S型花岗岩特征,在Rb-(Y+Nb)图解中显示后碰撞岩浆地球化学性质。利用LA-ICP-MS锆石U-Pb年代学方法,确定岩体形成年代为(273±7.7)-(278±4.3)Ma,在早

  6. LA-ICP-MS U-Pb Ages and Its Significance of Detrital Zircon Come from Gravel of Sedimentary Rock in Moraine nearby Vestfold Hills, East Antarctica%来自东南极西福尔丘陵附近冰碛物中沉积岩砾石的碎屑锆石LA-ICP-MS U-Pb年龄及其意义

    Institute of Scientific and Technical Information of China (English)

    刘健; 赵越; 刘晓春; 崔建军

    2011-01-01

    There are bands of moraine extending for 20 km which comprises of complex composition, including a few kinds of gravels of sedimentary rocks which were markedly different from the basement rocks of high-grade gneiss on the southeast side of the Vestfold Hills, East Antarctica. Based on the direction of glacier movement the source of the gravel is inferred to be under the glacier in the southeast of Vestfold Hills. LA-ICP-MS detrital zircon U-Pb age analyses of eight representative sedimentary gravel samples demonstrate that the U-Pb ages of the fdetrital zircons are predominantly in between 2410 Ma and 2600 Ma, and 3340 Ma and 3500 Ma, without the metamorphic ages of 1000 Ma and 500 Ma. This not only indicates that in the southeast of Vestfold Hills exists an Early-Archaean continental massif but also means that the source rocks of the clastic rocks are simple and relatively uniform in age.%东南极西福尔丘陵东南侧分布着长约20 km带状冰碛物,这些冰碛物成分复杂,其中含有少量与该地区高级片麻岩的基岩显著不同的沉积岩砾石.根据冰川流动方向可以推测它们来自西福尔丘陵的东南侧的冰盖之下.对其中8个具有代表性的沉积岩砾石样品进行碎屑锆石LA-ICP-MS U-Pb年龄测试,其U-Pb表面年龄主要集中在2410~2600Ma和3340~3500Ma之间,缺乏1000Ma和500Ma变质年龄,这些信息不仅暗示在西福尔丘陵东南侧存在一个古太古代陆块,而且说明该碎屑岩的物源区的岩石组成相对较为单一.

  7. 西藏冈底斯厅宫铜矿侵入岩成因:LA-ICP-MS 锆石U-Pb 年龄、地球化学及 Sr-Nd-Pb 同位素证据%Petrogenesis of Intrusions in Tinggong Copper Deposit,Gangdese, Xizang(Tibet):Evidence from LA-ICP-MS Zircon U-Pb Dating, Petrogeochemical,and Sr-Nd-Pb Isotopic Composition

    Institute of Scientific and Technical Information of China (English)

    黄勇; 丁俊; 李光明; 董随亮; 黄瀚霄; 崔晓亮; 戴婕; 闫国强

    2015-01-01

    studies of above major granites are benefited for future exploration.LA-ICP-MS zircon U-Pb dating,major and trace elements,Rb-Sr,Sm-Nd,Pb isotope composition were test by this study.The results show that the age of above granites are 50.32 Ma,48.34 Ma,and 49.41 Ma,respectively,which are apparently older than that of mineralization.Above stocks belong to high-K calc-alkaline,weakly peraluminous,I-type granites.The REE patterns indicate a LREE rich,with weak /no HREE fractionation V-type model and strong depleted δEu,which are reverse with SiO2 content.All granites are rich in Th,U,K,Cs,and Rb,depleted in Ba,Nb,Sr,Ti.Whole rock Pb isotopic compositions show that calculated n(206 Pb)/n(204 Pb)n(207 Pb)/n(204 Pb),n(208 Pb)/n(204 Pb) are 18.414 ~18.5137,15.616 ~15.7039,38.6394 ~39.0029,respectively,indicating a high radio-Pb isotope composition.Calculated n(87 Sr)/n(86 Sr)and n(143 Nd)/n(144 Nd)restrict in narrow range:0.70320 ~0.70477, 0.51260 ~0.51265,respectively,with calculated positive εNd (t)(0.51 ~1.44).The above results indicate that spread magna are not related to the mineralization and derived from new lower crust/depleted mantle during the roll-back and break-off of northward subducted ocean crust,undergoing AFC process during emplace.

  8. 广东连平大顶铁矿区石背岩体 LA-ICP-MS锆石 U-Pb 年龄及地质意义%LA-ICP-MS zircon U-Pb dating of Shibei pluton at Dading iron mine area in Lianping,Guangdong and its geological significance

    Institute of Scientific and Technical Information of China (English)

    林小明; 李宏卫; 黄建桦; 娄峰

    2016-01-01

    Dading iron mine in Lianping,Guangdong province is well known as the largest iron ore de-posit,and is also the most typical skarn type deposit in South China.The LA-ICP-MS zircon U-Pb age of coarse-grain porphyritic biotite granite and medium-grain porphyritic biotite granite from Dading pluton, closely related to mineralization in Dading mining area,are (174.3 ±3.6)Ma (MSWD =1.6)and (176.9 ±4.3)Ma (MSWD =2.6),respectively,and it shows the emplacement age of Shibei pluton belonged to the early Jurassic-middle Jurassic,and it was the product of the first magma activity of yans-hanian period.The Shibei pluton was formed in extrusion tectonic setting,in the process of subduction of the Pacific plate under Eurasian plate in the early Mesozoic.Its source mainly from crust,formed by crustal material melting and magma consolidation,similar to the Fogang pluton,is crustal transformation type (S-type)granite.%广东连平大顶铁矿被誉为华南第一大铁矿床,为华南地区最为典型的矽卡岩型矿床。对大顶铁矿区与成矿作用有关的石背岩体粗粒斑状黑云母花岗岩和中粒斑状黑云母花岗岩进行 LA-ICP-MS 锆石 U-Pb 定年,获得的同位素年龄分别为(174.3±3.6)Ma (MSWD =1.6)和(176.9±4.3)Ma (MSWD =2.6),表明石背岩体侵位时代为早侏罗世晚期-中侏罗世早期,是燕山第一幕岩浆活动之产物。石背岩体形成于早中生代古太平洋板块向欧亚板块俯冲过程中的挤压构造背景,其物源主要来自于地壳,为壳内物质熔融-岩浆固结而成,与佛冈岩体相似,均为陆壳改造型(S -型)花岗岩。

  9. 新疆大黑山东部姜巴斯套组下段的凝灰岩锆石LA-ICP-MS U-Pb年龄及其地质意义%Crystal Tuff Zircon LA-ICP-MS U-Pb Ages from the Lower Jiangbasitao Formation in the East Daheishan Area, Xinjiang and Their Geological Implications

    Institute of Scientific and Technical Information of China (English)

    樊婷婷; 周小虎; 柳益群; 李玮; 郑朝阳; 胡亭; 梁浩

    2011-01-01

    准噶尔东部大黑山地区出露的姜巴斯套组为一套厚层海相火山-沉积地层,其形成时代及地层层序存在争议.对姜巴斯套组下段2个具有地层意义的晶屑凝灰岩开展的锆石LA-ICP-MS测年,获得的加权平均年龄分别为339.4±1.9 Ma(MSWD = 0.39)和336.3±2.6 Ma(MSWD=0.58),结合古生物新的研究成果,确定了该套地层时代为早石炭世.其中,最老的继承性单颗粒碎屑锆石谐和年龄为2999±51 Ma,推测该区应存在前寒武纪古老地块,因此准噶尔盆地东北缘古生代山系由两条蛇绿岩、蛇绿混杂岩带围限的区带,应是由蛇绿岩、蛇绿混杂岩地体、岛弧岩浆杂岩和微古陆块共同组成的古生代增生带.%The Daheishan area is located in the south of the Santanghu Basin, north to the Balikun-Kaedikeshan,and is adjacent to the Tu-ha Basin, which is located in the Paleozoic Orogenic Belt of eastern edge of Junggar basin.A suite of thick-bedded marine volcanic-sedimentary rocks consist mainly of tuffaceous sandstones and siltstones,tuffs, muddy siltstones, silty mudstones, mudstones, and conglomerates are distributed in the Daheishan region in east Junggar, of which the ages and stratigraphy are highly controversial. More importantly, as the study area is sand-wicbed between the Zhaheba-Aermantai and the Kelamaili-Takezhale ophiolitic melange belts, it is of importance to investigate the stratigraphy. Two crystal tuff horizons (Nos. DHS04N and DHS07N) are sampled from the Jiangbasitao Formation of Lower Carboniferous and are dated using zircon LA-ICP-MS method. The analysis shows that the zircons are of typical magmatic origin with oscillatory zoning. Samples of DHS04N have a uranium content of 63 ~ 642 μg/g, thorium of 19 ~ 1037 μg/g, and a Th/U value range between 0.29 and 1.89. Whereas those of DHS07N have a uranium content of 40 ~476 μg/g, thorium of 25 ~466 μg/g, and Th/U of 0.48 ~1.14. The dating results yield two weighted mean 206

  10. LA-ICP-MS zircon U-Pb dating of the gold-bearing quartz veins in the Bainaimiao Au deposit of Inner Mongolia and its geological significance%内蒙古白乃庙金矿含金石英脉LA-ICP-MS锆石U-Pb测年及其地质意义

    Institute of Scientific and Technical Information of China (English)

    冯晓曦; 姚书振; 段明; 王佳营; 曲凯; 魏佳林; 李光耀; 朱强

    2014-01-01

    Cathodoluminescence image (CL) and zircon LA-ICP-MS U-Pb dating techniques were used to study the metallogenic age of the Bainaimiao gold deposit.According to the results obtained, all zircons from the gold-bearing quartz veins show clear core-mantle-rim texture, the core-mantles are of magmatic and metamorphic characteristics,the rims of zircons show the features of hydro-thermal zircon with clear core-mantle-rim texture, non-luminescent rim, and euhedral and subhedral crystals, Th/U ratios vary in the range of 0.2~0.5,and the results of the rim dating are 421.4~447.6Ma, suggesting that the Bainaimiao gold deposit formed in Si-lurian. The ages are accordant to ages of granodiorite porphyry, which has similar zircon core-mantle CL features. It is thus held that the gold deposit was closely related to tectonic-magmatism, post-magmatic hydrothermal activities and durative orogenesis resulting from the intense subduction of Early Paleozoic paleo-Asian oceanic plate towards the northern margin of North China craton.%为了厘定内蒙古白乃庙金矿床的成矿时代,对矿区主要含金石英脉中热液蚀变锆石进行了LA-ICP-MS U-Pb测年。结果表明,锆石热液蚀变特征明显,具有清晰的核-幔-边结构,锆石核、幔均为岩浆锆石或变质锆石,热液蚀变增生边呈自形-半自形结构,Th/U值集中于0.2~0.5之间,测年数据为421.4~447.6Ma,认为金矿形成时代为志留纪。从区域成矿规律分析,初步认为白乃庙金矿床的形成与早古生代古亚洲板块向华北地块强烈俯冲引起的构造-岩浆活动密切相关。

  11. Coupling of Uranium and Thorium Series Isotope Systematics for Age Determination of Late Pleistocene Zircons using LA-ICP-MS

    Science.gov (United States)

    Sakata, S.; Hirakawa, S.; Iwano, H.; Danhara, T.; Hirata, T.

    2014-12-01

    Zircon U-Th-Pb dating method is one of the most important tools for estimating the duration of magmatism by means of coupling of uranium, actinium and thorium decay series. Using U-Pb dating method, its reliability is principally guaranteed by the concordance between 238U-206Pb and 235U-207Pb ages. In case of dating Quaternary zircons, however, the initial disequilibrium effect on 230Th and 231Pa should be considered. On the other hands, 232Th-208Pb dating method can be a simple but powerful approach for investigating the age of crystallization because of negligible influence from initial disequilibrium effect. We have developed a new correction model for accurate U-Pb dating of the young zircon samples by taking into consideration of initial disequilibrium and a U-Pb vs Th-Pb concordia diagram for reliable age calibration was successfully established. Hence, the U-Th-Pb dating method can be applied to various zircons ranging from Hadean (4,600 Ma) to Quaternary (~50 ka) ages, and this suggests that further detailed information concerning the thermal history of the geological sequences can be made by the coupling of U-Th-Pb, fission track and Ar-Ar ages. In this presentation, we will show an example of U-Th-Pb dating for zircon samples from Sambe Volcano (3 to 100 ka), southwest Japan and the present dating technique using LA-ICP-MS.

  12. Datacion U-PB por LA-ICP-MS de diques graniticos del ciclo pampeano, sierra de Mojotoro, Cordillera Oriental LA-ICP-MS U-Pb age from granitic dikes fr om the Pampean cycle, Sierra de Mo/otoro, Cordillera Oriental

    Directory of Open Access Journals (Sweden)

    Pamela A Aparicio González

    2011-03-01

    Full Text Available El objetivo del presente trabajo es dar a conocer los resultados de dataciones U-Pb por el método LA-ICP-MS sobre circones procedentes de diques de pórfido granítico que intruyen a la Formación Chachapoyas (nom. nov. en la sierra de Mojotoro, en el noroeste de Argentina. Para ello, se analizaron 20 circones euhedrales de morfologías prismáticas aciculares y transparentes. Los resultados obtenidos son concordantes en ocho granos de circones permitiendo definir una edad de cristalización para el dique de 533 ± 2 Ma. Si se asocian los nuevos datos con otros de rocas ígneas de edades similares localizadas en otros sectores de la Cordillera Oriental, se confirma un evento magmàtico ácido ocurrido en el Cámbrico inferior.A zircon U-Pb age obtained with the LA-ICP-MS method is presented for a granite porphyry from Chachapoyas Formation (nom. nop., sierra de Mojotoro, NW Argentina. 20 euhedral zircons with acicular prismatic and transparent morphology were analyzed. The data obtained is concordant in eight zircons grains and show a crystallization age of 533 ± 2 Ma. The new data could be associated with igneous rocks of similar ages located in the Eastern Cordillera, and suggest an acid magmatic event during the Lower Cambrian. This outcrop represents the southern expression of the Pampean magmatic arc in the NW of Argentina.

  13. Chemical Abrasion Applied to LA-ICP-MS U–Pb Zircon Geochronology

    Directory of Open Access Journals (Sweden)

    Quentin G. Crowley

    2014-06-01

    Full Text Available Zircon (ZrSiO4 is the most commonly used mineral in U–Pb geochronology. Although it has proven to be a robust chronometer, it can suffer from Pb-loss or elevated common Pb, both of which impede precision and accuracy of age determinations. Chemical abrasion of zircon involves thermal annealing followed by relatively low temperature partial dissolution in HF acid. It was specifically developed to minimize or eliminate the effects of Pb-loss prior to analysis using Thermal Ionization Mass Spectrometry (TIMS. Here we test the application of chemical abrasion to Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS by analyzing zircons from both untreated and chemically abraded samples. Rates of ablation for high alpha-dose non-treated zircons are up to 25% faster than chemically abraded equivalents. Ablation of 91500 zircon reference material demonstrates a ca. 3% greater down-hole fractionation of 206Pb/238U for non-treated zircons. These disparities necessitate using chemical abrasion for both primary reference material and unknowns to avoid applying an incorrect laser induced fractionation correction. All treated samples display a marked increase in the degree of concordance and/or lowering of common Pb, thereby illustrating the effectiveness of chemical abrasion to LA-ICP-MS U–Pb zircon geochronology.

  14. 黑龙江完达山地区358高地岩金矿床花岗斑岩LA-ICP-MS锆石U-Pb定年及其地质意义%LA-ICP-MS zircon U-Pb dating of granite-porphyry from 358 Upland rock gold deposit in Wanda Mountain area, Heilongjiang Province and its geological significance

    Institute of Scientific and Technical Information of China (English)

    王庆磊; 杨言辰; 李骞; 马晓阳; 谈艳; 张国宾

    2015-01-01

    The 358 Upland rock gold deposit is located at the east edge of the Wanda orogenic belt, being part of the Circum-Pacif-ic metallogenic belt. The authors selected the granite porphyry closely associated with mineralization in the study area to conduct a systematic study of geology, petrography, element geochemistry and LA-ICP-MS zircon U-Pb dating results. According to the re-sults obtained, the granite porphyry is rich in silicon, sodium, potassium, aluminum and poor in magnesium and calcium, the Rittman index (σ) is 1.12 to 2.00(σ1.1). The granite-porphyry is enriched in LILE, relatively depleted in Ba, Nb and Ta, severely depleted in Sr, P and Ti; enriched in LREE, and depleted in HREE, with Eu anomalies. These characteristics reveal that the granite-porphyry is peraluminous, and the S type granite and magma might have been of shell source. LA-ICP-MS zircon dating methods were used to determine the age of the granite-porphyry. It is thus concluded that the gold metallogenic epoch should be late Early Cretaceous. Combined with the tectonic discrimination diagrams, the porphy-ry-granite shows the characteristics of post-collisional granite, and the formation of the porphyry might have been closely related to the post-collisional extension of the Pacific plate.%选取黑龙江省完达山地区358高地与成矿关系密切的花岗斑岩,进行系统的地质、岩相学、元素地球化学及LA-ICP-MS锆石U-Pb定年研究.结果显示:花岗斑岩具有富硅、钠、钾、铝,贫镁、钙的特征,里特曼指数(σ)为1.12~2.00(σ1.1);富集大离子亲石元素,亏损Nb、Ta,严重亏损Sr、P、Ti;轻稀土元素富集,重稀土元素亏损,具有负Eu异常.这些特征揭示,花岗斑岩是过铝质的S型花岗岩,岩浆来源可能为壳源.LA-ICP-MS锆石定年获得花岗斑岩的成岩年龄为128±1Ma,推断金矿成矿时代应为早白垩世晚期.构造判别图解显示,花岗斑岩具有碰撞后花岗岩的特征,斑岩体的形成很可能

  15. LA-ICP-MS zircon U-Pb ages of tectonic-thermal events in the Yalaxiangbo dome of ;Tethys Himalayan belt%特提斯喜马拉雅构造带雅拉香波穹隆构造热事件LA-ICP-MS锆石U-Pb年龄证据

    Institute of Scientific and Technical Information of China (English)

    吴珍汉; 叶培盛; 吴中海; 赵珍

    2014-01-01

    Paleozoic-Cenozoic rocks and strata together with intense ductile shearing and magmatic thermal events occurred in the Yalaxiangbo (Yardoi) dome of eastern Tethys Himalayan belt, which well recorded the structural deformation and thermal history caused by northward subduction of the Indian Continental Plate. LA-ICP-MS U-Pb isotopic dating of zircons with clear growth zonation selected from granitic rocks sampled in different structural zones reveals high-resolution ages of four periods of tectonic-magmatic events that took place in the Yalaxiangbo dome. The U-Pb isotopic ages of zircons, 520.4 ± 6.3Ma and 536 ± 12.3Ma, are indicative of magmatic emplacement of the Pan-African orogeny in the crystalline basement of the Himalayan block. The other U-Pb isotopic ages of zircons reveal geological epochs of tectonic-thermal events during Cenozoic collisional orogeny, e.g., ages 45.6± 1.2~44.16±0.88Ma are indicative of the initial time of the northward subduction of the Indian Continental Plate, 35.00±0.48Ma is a representative age for Late Eocene tectonic-thermal event that occurred in the depth of the thickened crust, and 15.67±0.50Ma indi-cates the epoch of the emplacement of the core granite and the formation of the Yalaxiangbo dome.%雅拉香波穹隆位于特提斯喜马拉雅构造带东部,出露显生宙不同时期的岩石地层,发育强烈韧性剪切变形和多期岩浆热事件,良好地记录了印度大陆俯冲导致的构造变形和岩浆热历史。对雅拉香波穹隆不同构造部位的花岗质岩石进行LA-ICP-MS锆石U-Pb同位素测年,获得4期构造岩浆事件的高精度测年数据。早期锆石年龄520.4±6.3Ma与536±12Ma指示喜马拉雅地块结晶基底泛非期岩浆侵位时代,晚期锆石年龄揭示新生代碰撞造山不同阶段构造热事件的发生时代。其中,45.6±1.2~44.16±0.88Ma反映印度大陆向北俯冲的起始时代,35.00±0.48Ma对应于始新世晚期增厚地壳

  16. 浙江临安夏色岭钨矿含矿岩体特征及LA-ICP-MS锆石铀-铅年代学研究%Characteristics and LA-ICP-MS Zircon U-Pb Geochronology Study of Metallogenic Intrusion in the Xiaseling Tungsten Deposit in Lin'an,Zhejiang Province

    Institute of Scientific and Technical Information of China (English)

    黄国成; 王登红; 吴小勇

    2012-01-01

    夏色岭钨矿是浙江省内已知规模最大的石英脉型钨矿,其形成与夏色岭花岗岩体关系密切,前人对该岩体的年代学研究方法比较局限.本研究采集了夏色岭钨矿区的新鲜花岗岩样品,从岩石的矿物学特征及地球化学特征出发,讨论了岩体与成矿作用之间的关系.通过分析精度更高、结果更可靠的激光剥蚀-电感耦合等离子体质谱( LA - ICP - MS)锆石U- Pb测年技术,获得206Pb/238 U加权平均年龄为( 126.9±1.7)Ma,表明为燕山晚期早阶段(早白垩世)的产物,结合区域上的找矿成果,对本地区的地质找矿具有一定指导意义.%The Xiaseling tungsten deposit is the largest discovered quartz-veined tungsten deposit in Zhejiang Province, which is closely related to Xiaseling Granite. The geochronological study on this granite has been very limited in previous studies. Fresh granite samples were collected from the Xiaseling tungsten deposit. The relationship between Xiaseling Granite and mineralization is discussed by mineralogy and geochemical characteristics of the rocks. The in-situ zircon U-Pb dating was performed with Laser Ablation-Multicollector Inductively Coupled Plasma-Mass Spectrometry ( LA-MC-ICPMS) with higher accuracy and greater reliability than previously achieved. Our result indicates that the weighted average 206Pb/238U ages for zircons from the Xiaseling granite is ( 126. 9 ?.7) Ma, suggesting the granite was intruded in the early stage of the late Yenshanian Period of the early Cretaceous era. Together with regional prospecting findings, it is also important for ore exploration work in this area.

  17. 陕西柞水地区小茅岭复式岩体东段LA-ICP-MS锆石U-Pb定年%LA-ICP-MS zircon U-Pb geochronology of the eastern pan of the Xiaomaoling composite intrusives in Zhashui area,Shaanxi,China

    Institute of Scientific and Technical Information of China (English)

    刘仁燕; 牛宝贵; 和政军; 任纪舜

    2011-01-01

    小茅岭复式岩体东段主要由早期宋家屋场蚀变角闪辉绿(辉长)岩体和晚期迷魂阵蚀变闪长岩体、磨沟峡蚀变石英闪长岩体、叶家湾蚀变二长闪长岩体组成.经LA-ICp-MS锆石U-Pb同位素测年,分别获得宋家屋场岩体侵位年龄864.4Ma±1.7Ma,迷魂阵岩体846.7Ma±2.7Ma,磨沟峡岩体为859.4Ma±1.7Ma,叶家湾岩体861.1Ma+1.8Ma,确证该复式岩体形成于新元古代.鉴于在小茅岭-陡岭隆起带的早前寒武系变质岩中曾获得与北秦岭造山事件(1000-848Ma)相一致的变质年龄,结合该复式岩体自身的特征,认为小茅岭复式岩体东段形成于后造山应力松弛的构造环境.%The eastern part of the Xiaomaoling composite intrusives in the Qinling Mountains is considered to consist mainly of the early Songjiawuchang altered proterobase or bojite, the late Mihunzhen altered diorite, Mogouxia altered quartz diorite and Yejiawan altered monzodiorite.The LA-ICP-MS U-Pb isotope dating for zircons from the rock masses above yields four ages: 864.4Ma±1.7Ma from Songjiawuchang, 846.7Ma±2.7Ma from Mihunzhen, 859.4Ma±1.7Ma from Mogouxia and 861.1Ma±1.8Ma from Yejiawan.All the data suggest that the eastern part of the Xiaomaoling composite intrusives belongs to the Neoprotozoic in age.The metamorphic age obtained from the early Precambrian metamorphic rocks of the Xiaomaoling-Douling uplift belt is close to the age of the North Qinling orogenic event (1000Ma~848Ma) based on the previous materials and combining with the intrusives' own character, the authors infer that the eastern part of the Xiaomaoling composite intrusives forms in the post-collisional stress relaxation environment.

  18. 滇东北东川下田坝A型花岗岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其构造意义%LA-ICP-MS zircon U-Pb age and geochemistry of Xiatianba A-type granites in Dongchuan, Northeast Yunnan, and their tectonic significance

    Institute of Scientific and Technical Information of China (English)

    武昱东; 王宗起; 罗金海; 程家孝; 闫全人; 张英利; 王师迪

    2014-01-01

    通过对滇东北东川下田坝地区黑云母二长花岗岩和似斑状钾长花岗岩2种岩体的地球化学分析及对黑云母二长花岗岩的U-Pb同位素测试,得到如下认识:黑云母二长花岗岩和似斑状钾长花岗岩总体地球化学特征相似,主量元素表现出高SiO2(平均71.7%)、过铝质(A/CNK指数在1.03~1.52)的特征,过碱指数在0.95~1.37之间,总体属于钙碱系列;稀土元素总量较高(ΣREE平均313×10-6),(Ce/Yb)N均值为8.85,(La/Yb)N均值为9.54,呈现轻稀土元素(LREE)富集,仅Eu亏损(δEu均值0.31)的海鸥型右倾模式;大离子亲石元素Rb、Th、U、K等相对富集,高场强元素Nb、Ta、Sr、Ti等呈明显负异常,说明岩浆源岩以陆壳成分为主;Ga/Al均值为2.69,(Zr+Nb+Ce+Y)均值为383;微量元素Sr、Eu低,富集Nb、Zr等元素,反映其源区存在斜长石的残留;锆石饱和温度为724~786℃,表明初始岩浆温度较高。上述特征说明,下田坝花岗岩为典型的A型花岗岩,形成于中上地壳的板内伸展背景。黑云母二长花岗岩LA-ICP-MS锆石U-Pb年龄为801.1±6.6Ma,同时受到762.1±6.2Ma热事件的影响,与新元古代Rodinia超大陆裂解事件在时间上一致,亦与东川铜矿成矿时代相符,说明新元古代裂谷环境的岩浆事件范围可扩大至滇东北东川,并可能引发热液成矿作用。%Geochemical analysis and LA-ICP-MS zircon U-Pb dating of Xiatianba granites of two granitic bodies in Dongchuan of northeast Yuannan were conducted in this study. The general geochemical characteristics of biotite adamellite and porphyraceous moy-ite are similar to each other, characterized by high SiO2(71.7% on average)and belonging to the peraluminous (A/CNK value be-tween 1.03~1.52) and alkaline series (AI value between 0.95~1.37). They have highΣREE content with an averageΣREE value of 313 × 10-6, an average(Ce/Yb)N value of 8

  19. 新疆库鲁克塔格阿訇开里得南石炭纪花岗岩LA-ICP-MS锆石U-Pb定年及其地质意义%Zircon LA-ICP-MS U-Pb dating of South Ahongkailide Carbonifereous granite in Kuruktag of Xinjiang and its geological implications

    Institute of Scientific and Technical Information of China (English)

    尼加提·阿布都逊; 郭瑞清; 帕拉提·阿布都卡迪尔; 贾晓亮; 秦切; 朱志新; 王克卓

    2013-01-01

    对出露于新疆库鲁克塔格地块西段的阿訇开里得南花岗岩进行了详细的岩石学、地球化学及锆石U-Pb定年研究,并探讨了其构造背景及地质意义.岩体LA-ICP-MS锆石U-Pb原位定年获得年龄为340.6Ma±5.7Ma,属于石炭纪花岗岩.地球化学分析显示岩体具高硅、高铝、高钾,贫钠、低钙、低磷、低钛和贫镁的特征,铝饱和指数(A/CNK)为1.14~2.31,CIPW标准刚玉分子大于1%,属高钾钙碱性过铝质花岗岩.在稀土元素球粒陨石标准化配分模式图上,轻稀土元素(LREE)富集、重稀土元素(HREE)亏损,轻重稀土元素分馏明显,Eu出现中等负异常(δEu=0.52~0.62);在微量元素原始地幔标准化蛛网图上,明显富集大离子亲石元素Rb、Ba、Th和K,亏损高场强元素Nb、Ta、Ti.综合分析研究认为,岩体的形成与加厚地壳引起的地壳重熔有关,反映了塔里木板块与伊犁-中天山板块陆-陆碰撞的岩浆活动.%The South Ahongkailide Carboniferous granite is exposed in the west segment of Kuruktag block in Xinjiang. This paper has studied petrographical, geochemical and zircon U-Pb chronolgical characteristics of this granite as well as its petrogenesis and geological significance. Zircon LA-ICP-MS dating yielded the age of 340.6Ma±5.7Ma, implying that the magmatic crystallization epoch of the granite is Carboniferous. Geochemical analyses show that the granite has high SiO2, A12O3, K2O but relatively low CaO, P2O5, TiO2 and MgO. The ratios of A/CNK vary from 1.14 to 2.31, suggesting high-K calc- alkaline peraluminous syn-collision granite. The chondrite-normalized REE patterns show that the granite is enriched in LREE but depleted in HREE, with high fractionations between LREE and HREE and moderate negative Eu anomalies ((δEu=0.52~0.62). In addition, the granite is relatively rich in such LILEs as Rb,Ba.Th and K, but poor in such HFSEs as Nb, Ta and Ti, with relative enrichment of Ce in the primitive mantle

  20. Petrotectonic assemblages and LA-ICP-MS zircon U-Pb age of Early Paleozoic volcanic rocks in Qimantag area, Tibetan Plateau%青藏高原祁漫塔格地区早古生代火山岩岩石构造组合和LA-ICP-MS锆石U-Pb年龄

    Institute of Scientific and Technical Information of China (English)

    王秉璋; 罗照华; 潘彤; 宋泰忠; 校培喜; 张志青

    2012-01-01

    A study of the Early Paleozoic volcanic rocks in Qimantag area reveals that they were formed in the Middle-Late Ordovi-cian period. The volcanic rocks can be assigned to four volcanic rock belts, i.e., Gonglugou - luanshigou belt, Kuangou - Xi-aolangyashan belt, Bayan Gol-Suhait belt and Naling Gol belt. The first volcanic rock belt belongs to a combination of Nb-enriched basalts characterized by high content of Nb (7.38×10-6-10.1×10-6), TiO2 (1.56%-2.24%) and P2O5 (0.24%-0.34%). The combinations of the volcanic rocks in the second belt are complicated, the SiO2 mass fractions of these rocks are concentrated on two end members, and these rocks can be further divided into two sub-combinations of basalt+basatic andesite and dacite+lithoidite. U-Pb LA-ICP-MS analyses of zircons in basalt and lithoidite yielded the data of 440.2±2.4Ma and 450.3±1.2Ma, respectively. The content of TiO2 (1.1%) and K2O(0.14%) is low while that of Na2O(2.17%) is high for the rocks of the tholeiite combinations in the third belt. Although the content of TiO2 (1.64%) is relatively high, the tholeiite combinations in the fourth belt are very similar to those in the third belt.%祁漫塔格地区早古生代海相火山岩发育,初步确定该地区早古生代海相火山岩的形成时代为中晚奥陶世,可划分出4个火山岩带,分别为公路沟-乱石沟带、宽沟-小狼牙山带、巴音郭勒-苏海图带和那陵格勒河带.公路沟-乱石沟带火山岩为富铌玄武岩组合,具有相对高的Nb(7.4×10-6~10.1×10-6)、TiO2( 1.56%~2.24%)和P2Os(0.24%~0.34%)含量.宽沟-小狼牙山带火山岩岩石类型复杂,SiO2质量分数集中分布于2个端元,可进一步分为玄武岩+玄武安山岩组合和英安岩+流纹岩组合,玄武岩中获得了440.2Ma±2.4Ma的LA-ICP-MS锆石U-Pb年龄值,流纹岩中获得了450.3Ma±1.2Ma的年龄值.巴音郭勒-苏海图带为拉斑玄武岩组合,具低钛(1.1%)、富钠(2.17%,)、低钾(0.14%)的特

  1. LA-ICP-MS Zircon U-Pb Dating of the Dacite Porphyry from Zijinshan Cu-Au Deposit and its Metallogenetic Implications%福建紫金山矿田晚中生代英安玢岩形成时代及其成矿意义

    Institute of Scientific and Technical Information of China (English)

    胡春杰; 黄文婷; 包志伟; 梁华英; 王春龙

    2012-01-01

    The dacite porphyry occurs in the volcanic caldera of Zijinshan ore field and closely associates with the Cu-Au mineralization.The LA-ICP-MS zircon U-Pb dating of two dacite porphyry samples yields weighted mean ages of ( 105.0 ±0.7) Ma and ( 105.0 ±2.2) Ma,respectively.These results suggest that the dacite porphyry was formed proximately contemporarily with the other two Mo and Cu mineralized granite porphyries,i.e.,the Sifang and Luoboling granite porphyries.The dacite and granite intrusives are characterized by high Ce4+/Ce3+ ratios,which indicates that the magmatic system was of oxidative and therefore consistent with the huge Cu-Mo-Au ore-forming potential of the dacite and granite porphyries.Moreover,the similarities of age,geochemical characteristics and mineralization demonstrate that the Cu-Mo-Au mineralization in the Zijinshan ore field is most likely a unified porphyry ore-forming system.%福建紫金山Cu-Mo-Au-Ag多金属矿田是一个完整的斑岩-浅成低温热液矿床成矿体系.英安玢岩主要分布在紫金山Au-Cu矿床内火山机构及其附近,与高品位Au-Cu矿体空间上联系密切,是矿田内火山-侵入岩浆过程的一个重要环节.采自矿区的两个英安玢岩样品LA-ICP-MS锫石U-Pb定年结果分别为(105.0±0.7) Ma(MSWD =0.83)和(105.0±2.2) Ma (MSWD=1.70),其形成时代与区内Mo-Cu矿化的萝卜岭和四方岩体形成时代相近.三个岩体形成时代及地球化学特征的相似性表明它们应为同源岩浆演化的产物,它们均具有较高的锆石Ce4+/Ce3+值,即岩浆体系具有较高的氧逸度,与区内斑岩成矿体系巨量金属堆积的地质事实相一致.英安玢岩的精确定年表明,紫金山Cu-Au矿与萝卜岭Mo-Cu矿及四方岩体有关的Mo矿床为同一斑岩成矿体系的产物.

  2. 藏北羌塘中部果干加年山石炭纪蛇绿岩地球化学特征及LA-ICP-MS锆石U-Pb年龄%Geochemical characteristics and LA-ICP-MS zircon U-Pb geochronology of Guogangjianan Carboniferous ophiolite in central Qiangtang, the Tibetan Plateau

    Institute of Scientific and Technical Information of China (English)

    吴彦旺; 李才; 徐梦婧; 解超明; 王明; 熊盛青; 范正国

    2014-01-01

    In order to investigate the evolution of the Lungmu Co-Shuanghu plate suture zone and the tectonic history of central Qiangtang, the authors studied Guoganjianian ophiolite in the aspects of petrology, geochemistry and geochronology. The cumulate in Guoganjianian ophiolite was recently discovered during 1∶50000 regional geological survey of the Gemuri area. Geochemical studies show that the cumulate gabbro has low REE content and flatten REE patterns with slight enrichment of LREE, and the degree of differentiation between LREE and HREE is low. These samples are enriched in large ion lithophile elements (LILE) such as Rb and Ba, and depleted in Nb, Ta and Ti, suggesting that they were probably formed in a subduction zone. LA-ICP-MS technique was applied to U-Pb zircon dating of the cumulate gabbro from Guoganjianian ophiolite. The result shows that the ages of cumulate gabbro is 354.8Ma±2.4Ma, suggesting that Lungmu Co-Shuanghu Ocean already began its subduction in Early Carboniferous. The study of Guoganjianian cumulate gabbro provides important basic data for investigating the evolution of Lungmu Co-Shuanghu plate suture zone and the tectonic history of central Qiangtang.%在羌塘地区开展1∶5万戈木日区域地质调查的过程中,为研究龙木错-双湖板块缝合带的演化历史,探讨青藏高原羌塘中部地区的构造演化,对果干加年山地区的蛇绿岩进行了详细研究。石炭纪蛇绿岩变质堆晶辉长岩是填图过程中的新发现。全岩地球化学研究结果显示,岩石ΣREE较低,LREE弱富集,轻、重稀土元素分异程度不高;富集Rb、Bb等大离子亲石元素,明显亏损Nb、Ta、Ti等元素,具有典型的SSZ型蛇绿岩特征,表明其形成于俯冲带之上。蛇绿岩中变质堆晶辉长岩的LA-ICP-MS锆石U-Pb年龄为354.8Ma±2.4Ma,属于早石炭世。最终研究表明,龙木错-双湖板块缝合带所代表的古大洋至少在早石炭世就已经存在俯冲

  3. Zircons LA ICP MS U Pb Ages of the Lower Triassic Lujiatun Group and Its Geological Significance in Jilin Province%吉林省下三叠统卢家屯组 LA-ICP-MS锆石 U-Pb 定年及其地质意义

    Institute of Scientific and Technical Information of China (English)

    聂立军; 于宏斌; 张建泽; 王聪; 李栋; 李阳

    2015-01-01

    According to the associated lithologic feature,the Lujiatun Formation is divided into Yingbeishan conglomerate section,Loudoushan variegated rock section,and Yangshuhezi black rock section.Based on the fossil assemblages,such as Palaeanodonta-Palaeomutela fauna,P leuroneia ? sp. and the conchostracan,it was formed in Permian.A systematic U Pb isotopic chronology of the detrital zircon is studied for the Bottom,Middle,and Upper Section of the construction profiles of Lujiatun Formation in Yingbeishan Shuangdingshan in Jiutai.The results show three minimum zircon age peaks at (283.4±7.9)Ma,(262.4±3.9)Ma,and (255.5 ±5.8)Ma from the bottom to the top.It can be confirmed that the top section of the formation belonged to the Late Permian.The detrital zircon ages of 1 800 Ma and 2 500 Ma in the Lujiantun Group are typical for the base plate age of North China Plate.In conclusion,the plate closure happened probably during P3 T1 between the northern margin of North China Plate and the group of plates to its north.%卢家屯组按岩性组合自下而上分为影背山砾岩段、漏斗山杂色岩段、杨树河子黑色岩段,前人采集到的 Palaeanodonta-Palaeomutela 动物群、P leuroneia? sp.和叶肢介等生物化石组合指示时代为二叠纪。本次对九台市影背山双顶山卢家屯组建组剖面下、中、上段进行了系统的碎屑锆石 U Pb 同位素年代学研究,证实卢家屯组由下至上存在3个最小锆石年龄峰值,分别为(283.4±7.9)、(262.4±3.9)、(255.5±5.8)Ma,确定了卢家屯组的上限为晚二叠世。根据卢家屯组中碎屑锆石存在1800 Ma 和2500 Ma 左右的典型华北板块基底年龄,认为华北板块北缘与其北侧地块群最终闭合时间应为 P3 T1。

  4. 内蒙古赤峰地区蒙古营子花岗闪长岩LA-ICP-MS锆石U-Pb年龄及成因%LA-ICP-MS zircon U-Pb ages and petrogenesis of granodi-orite in Mengguyingzi, Chifeng, Inner Mongolia

    Institute of Scientific and Technical Information of China (English)

    刘珏; 郗爱华; 葛玉辉; 唐向阳; 徐博文; 王明智; 马艳军

    2015-01-01

    Located in the south of the Xing'an-Mongolian orogenic belt in northern North China plate, the Mengguyingzi granites are mainly composed of granodiorite. All samples show chemical signatures of high-K calc-alkaline I-type granites and have the fol⁃lowing characteristics:SiO2 is about 56.88%~68.82%, Na2O is about 4.32%~4.54%, K2O is about 2.3%~3.86%, Na2O>K2O, Rittmann indexσ=2.08~2.33, Al2O3 is about 15.1%~16.8%, and A/CNK=0.81~0.92. The granodiorite is enriched in light rare earth (LREE) and relatively depleted in heavy rare earth (HREE) and high field strength elements. The content of Sr is about 782×10-6~1230×10-6, and the average values of Y and Yb are 20.1×10-6 and 1.77×10-6 respectively.δEu=0.81~1.04, and Eu anomaly is not obvious. The granodiorite shows C adakitic rock geochemical properties, implying that its magma might have been derived from partial melting of the thickened lower continental crust. The zircon 206Pb/238U age of granodiorite measured by LA-ICP-MS zircon U-Pb dating is 252.8 ± 2.4Ma, implying that the Mengguyingzi granodiorite were formed in the late Paleozoic-Early Mesozoic. Combined with the tectonic evolution of the Xing'an-Mongolian orogenic belt, the authors hold that the Mengguyingzi granodiorite resulted from post-collision between Siberia plate and North China plate and suggested that the underplating of mantle-derived magma induced crustal growth.%赤峰蒙古营子岩体位于华北板块以北的兴蒙造山带南端,岩性主要为花岗闪长岩。其SiO2含量介于56.88%~68.82%之间,Na2O含量为4.32%~4.54%,K2O含量为2.3%~3.86%,且Na2O>K2O。里特曼指数σ=2.4~3.29,Al2O3含量介于15.1%~16.8%之间,A/CNK=0.81~0.92,属于高钾钙碱性I型花岗岩。富集轻稀土元素(LREE)、亏损重稀土元素(HREE)和高场强元素(HFSE)。Sr含量为782×10-6~1230×10-6,Y和Yb平均值分别为20.1×10-6和1.77×10-6,(La/Yb)N值为19.84~22.03,δEu=0.81~1.04,Eu异常不明显。岩

  5. Las rocas monzoníticas del sector oriental del plutón de Cachauta, Precordillera mendocina: características geoquímicas y edad U/Pb (LA-ICP-MS The monzonitic rocks of the eastern sector of the Cacheuta Pluton, Precordillera of Mendoza: geochemical signature and U/Pb age (LA-ICP-MS

    Directory of Open Access Journals (Sweden)

    Carlos A Cingolani

    2012-06-01

    Full Text Available En el sur de la Precordillera mendocina, afora el plutón de Cacheuta formado por un borde de tipo monzonítico a granodiorítico (Boca del Río gris-verdoso y otro posterior de mayor superficie aforante de composición granítica y tonos rosados-rojizos. Se ofrecen en este trabajo nuevos datos geoquímicos sobre las rocas monzoníticas y el análisis geocronológico por el método U/Pb (LA-ICP-MS sobre 25 cristales de circones extraídos de tres muestras. Las rocas monzoníticas analizadas son de características subalcalinas, metaaluminosas y presentan enriquecimiento en LREE, diseño plano o ligeramente inclinado de HREE y leve anomalía negativa de Eu. La signatura geoquímica es de rocas calco-alcalinas de arco magmático. El análisis geocronológico por U/Pb permitió definir un histograma con una moda principal de edades entre 253 - 258 Ma correspondiente al Pérmico Tardío. Luego los datos isotópicos se extienden entre el Carbonífero Tardío con 302 Ma para un circón de una de las muestras como registro más antiguo y otra que presenta la edad de 249 Ma correspondiendo ya al Triásico más bajo. Con estos datos se confirma que el magmatismo del plutón de Cacheuta pertenece al ciclo gondwánico, resultando coetáneo con parte de la actividad volcánica del Grupo Choiyoi.In the south of the Precordillera of Mendoza crops out the Cacheuta Pluton formed with an eastern belt of gray-green monzonite to granodiorite type rocks (Boca del Rio and a subsequent larger surface outcrop of pink granitic rocks. In this work are offered new whole rock geochemical and geochronological U/Pb (LA-ICP-MS data on 25 zircon crystals extracted from three monzonitic rock samples. These rocks have subalkaline and metaaluminous signature, with enrichment in light REE with less negative Eu anomaly. The analyses of zircon crystals by U/Pb geochronology show that a main mode of ages is 253 -258 Ma that represent the Late Permian. Then the isotopic data span

  6. LA-ICP-MS U-Pb dating of rutile inclusions within corundum (ruby and sapphire): new constraints on the formation of corundum deposits along the Mozambique belt

    Science.gov (United States)

    Sorokina, Elena S.; Rösel, Delia; Häger, Tobias; Mertz-Kraus, Regina; Saul, John M.

    2017-06-01

    Direct dating of corundum and the establishment of age constraints for corundum crystal growth are restricted due to the absence of a geochronometer. Syngenetic mineral inclusions may help define minimum ages for corundum growth. Here, we present results of in situ LA-ICP-MS U-Pb dating applied to rutile inclusions in corundum from localities along the Mozambique belt. U-Pb dating of rutile inclusions gave ages of 533 ± 11 Ma (2 σ) for the Gitonga pit (John Saul ruby mine) and 526 ± 13 Ma for the Aqua Ruby mine, both in the Mangari area of Kenya, and an age of 499 ± 12 Ma for ruby from the Morogoro area, Tanzania. These ages are interpreted as cooling ages that set a minimum age for corundum growth following metamorphism along the East-African Antarctic Orogen, and might be used for petrogenetic tracing of corundum in placer deposits.

  7. LA-ICP-MS zircon U-Pb geochronology to constrain the age of post-Neocomian continental deposits of the Cerrillos Formation, Atacama Region , northern Chile: tectonic and metallogenic implications Geocronología U-Pb en circón por LA-ICP-MS para circunscribir la edad de depósitos continentales post-neocomianos de la Formacion Cerrillos, Región de Atacama, norte de Chile: implicancias tectónicas y metalogénicas

    Directory of Open Access Journals (Sweden)

    Víctor Maksaev

    2009-07-01

    Full Text Available New U-Pb zircon dating of volcamc intercalations in the lower conglomeratic part of the Cerrillos Formation shows that its deposition extended in time at least from 110.7±1.7 to 99.7±1.6 Ma. The significantly younger U-Pb zircon age of 69.5±1.0 Ma obtained for the upper volcamc part of the Cerrillos Formation suggests recurrence of volcanism in the Late Cretaceous instead of continual volcanic activity. A minimum late Maastrichtian age for the Cerrillos Formation and its initial deformation was determined by the U-Pb zircon age range from 66.9±1.0 to 65.2±1.0 Ma for the lower part of the unconformably overlying Hornitos Formation. The new U-Pb data for the Cerrillos and Hornitos formations poses questions about the Campanian-Maastrichtian age range currently ascribed to the latter. The lower part of the Cerrillos Formation represents a major change in the sedimentary regime from previous marine carbonate sedimentation in a back-arc basin until the late Aptian to subsequent coarse alluvial sedimentation and volcanism since the early Albian. The lower part of the Cerrillos Formation is interpreted as the development of coalescent alluvial fans thinning inland, accompanied by volcanism. These developed as the result of transpressive deformation and uplift of the area of the current Coastal Cordillera by late Aptian, leading to subsequent active erosion and sedimentation inland, along with the eastward shift of the magmatic foci in the Región . Amineralizing period of Cu-Au porphyries overlaps in time with the deposition of the Cerrillos Formation in northern Chile; marking also a significant change in the metallogeny of the Andes of northern Chile.Nuevas dataciones U-Pb obtenidas para intercalaciones volcánicas en la parte inferior conglomerádica de la Formacion Cerrillos muestran que su depositacion se extendió en el tiempo al menos desde 110,7±1,7 hasta 99,7±1,6 Ma. La edad U-Pb significativamente más joven de 69,5±1,0 Ma obtenida

  8. U-Pb (LA-ICP-MS of detrital zircon and whole rock Nd and geochemical constraints on the provenance, depositional age and tectonic setting of the metasedimentary Piriá Basin, northern Brazil: implications for the evolution of the Gurupi Belt

    Directory of Open Access Journals (Sweden)

    Elem Cristina dos Santos Lopes

    Full Text Available ABSTRACT: The Piriá Basin (Piriá Formation is a hemi-graben shaped basin that developed over Precambrian rocks of the Gurupi Belt. The lithological content comprises four interfingered lithofacies: (1 arkose and greywacke with pelite layers, (2 laminated siltstones and pelites, (3 arkose with hummocky stratification, and (4 oligomictic conglomerate. This sequence was formed in alluvial fans (conglomerate, and fluvial systems (arkose, greywacke, siltstones and pelites that were established and evolved during the migration of the subsidence. The sedimentary sequence underwent anquimetamorphism and very weak tectonic deformation. U-Pb analyses of detrital zircon set the maximum depositional age at 591 Ma and indicate several sediment sources, that range in age from the Neoproterozoic to the Archean. The main sources are from the Rhyacian, which is the main period of continental crust formation in the São Luís cratonic fragment and the basement of the Gurupi Belt. Neoproterozoic sources were important in the eastern segment of the basin. Ages from unknown sources in the region so far have also been recorded. Combined, the U-Pb zircon data, the whole-rock geochemical and Sm-Nd results, and the petrographic information revealed proximal felsic to intermediate provenance, in addition to recycled sedimentary sources. As a whole, our data suggest that the Piriá Formation was deposited in a post-orogenic basin related to the final stage of evolution of the Brasiliano cycle of orogenies, which built up the Gurupi Belt.

  9. 西藏嘎拉勒夕卡岩型金(铜)矿床地球化学特征与锆石的LA-ICP-MS定年及意义%Geochemical characteristics and zircon LA-ICP-MS U-Pb dating of Galale skarn gold(copper) deposit,Tibet and its significance

    Institute of Scientific and Technical Information of China (English)

    吕立娜; 崔玉斌; 宋亮; 赵元艺; 曲晓明; 王江朋

    2011-01-01

    嘎拉勒金(铜)矿床位于西藏班公湖—怒江缝合带的西段,为夕卡岩型金(大型)铜(小型)矿床。矿区主要岩石为巨斑状石英闪长岩、中细粒花岗闪长岩与闪长玢岩。该矿床岩石样品的REE分异程度较高,Eu呈弱负异常,w(Al2O3)为14.45%~15.84%,铝过饱和指数A/CNK为1.33~1.46,均大于1,表明为S型花岗岩。经微量元素的相关分析,该矿岩体为板内花岗岩,形成期接近于同碰撞期。锆石的LA-ICP-MS定年结果表明巨斑状石英闪长岩的年龄为(131±17)Ma,中细粒花岗闪长岩为(86.52±0.41)Ma,两个闪长玢岩的年龄分别为(88.59±0.45)和(88.09±0.41)Ma,其中巨斑状石英闪长岩为非成矿岩体,其测年数据代表了成岩时代下限;矿体只产在中细粒花岗闪长岩和闪长玢岩岩体与灰岩和粉砂岩夹硅质岩的接触带,为燕山期成矿。由测年结果可将该矿床的岩浆演化过程大致分为两个阶段,早白垩世非成矿岩体巨斑状石英闪长岩岩体的侵入和晚白垩世成矿岩体的形成,发生在白垩纪班公湖—怒江中特提斯洋构造演化的第4个阶段弧-陆碰撞造山阶段。%The Galale gold(copper) deposit is located in the west section of Bangong lake-Nujiang suture zone in Tibet.It is a gold(of large scale) and copper(of small scale) skarn deposit.There are mainly huge porphyritic quartz diorite,middle-fine grain granodiorite and diorite porphyrite in the mine area.The REE differential degree of rock sample in this ore deposit has a relatively higher value,and Eu negative anomaly is weak.The content of Al2O3 is 14.45%-15.84%.The aluminum supersaturation index(A/CNK) ranges between 1.33 and 1.46,which is greater than 1,indicating its being S-type granite.According to the analysis of trace elements,the magmatic body belongs to MPG.The forming stage is close to the collision stage.The result of zircon LA-ICP-MS dating indicates that the age of

  10. LA-ICP-MS U-Pb apatite dating of Lower Cretaceous rocks from teschenite-picrite association in the Silesian Unit (southern Poland

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    Szopa Krzysztof

    2014-08-01

    Full Text Available The main products of volcanic activity in the teschenite-picrite association (TPA are shallow, sub-volcanic intrusions, which predominate over extrusive volcanic rocks. They comprise a wide range of intrusive rocks which fall into two main groups: alkaline (teschenite, picrite, syenite, lamprophyre and subalkaline (dolerite. Previous 40Ar/39Ar and 40K/40Ar dating of these rocks in the Polish Outer Western Carpathians, performed on kaersutite, sub-silicic diopside, phlogopite/biotite as well as on whole rock samples has yielded Early Cretaceous ages. Fluorapatite crystals were dated by the U-Pb LA-ICP-MS method to obtain the age of selected magmatic rocks (teschenite, lamprophyre from the Cieszyn igneous province. Apatite-bearing samples from Boguszowice, Puńców and Lipowa yield U-Pb ages of 103± 20 Ma, 119.6 ± 3.2 Ma and 126.5 ± 8.8 Ma, respectively. The weighted average age for all three samples is 117.8 ± 7.3 Ma (MSWD = 2.7. The considerably smaller dispersion in the apatite ages compared to the published amphibole and biotite ages is probably caused by the U-Pb system in apatite being less susceptible to the effects of hydrothermal alternation than the 40Ar/39Ar or 40K/40Ar system in amphibole and/or biotite. Available data suggest that volcanic activity in the Silesian Basin took place from 128 to 103 Ma with the the main magmatic phase constrained to 128-120 Ma.

  11. 西准噶尔巴尔雷克-带石炭系黑山头组火山岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及构造环境%LA-ICP-MS Zircon U-Pb Age, Geochemistry and Tectonic Setting of the Volcanic Rocks in the Heishantou Formation from the Area of Barleik, West Junggar

    Institute of Scientific and Technical Information of China (English)

    田陟贤; 阎军; 李永军; 杨高学; 田猛; 佟丽莉; 严镜

    2013-01-01

    西准噶尔巴尔雷克山南部的石炭系黑山头组火山岩主要由灰-灰紫色(气孔)杏仁状安山岩、杏仁状玄武安山岩组成,属亚碱性系列.LA-ICP-MS锆石U Pb年龄为349±8 Ma,MSWD=0.14(95%置信度),时代属早石炭世.Mg#介于23.82~50.45,全碱含量(Na2O+K2O=3.74%~8.02%)较高且相对富钠,轻稀土(LREE)相对富集[(La/Yb)N=2.87~13.41]且分馏较好[(La/Sm)N值均大于1(1.46~3.41)],重稀土分馏较差[(Gd/Yb)N=1.46~3.48].仅部分样品有微弱的负铕异常(δEu=0.82~1.47).大离子亲石元素(LILE) Ba、Th、K、Sr相对富集,其中Ba、K的富集尤为明显,高场强元素(HFSE) Nb、Ta相对亏损,Ti轻微亏损,Zr、Hf略富集.地球化学特征表明其为俯冲带流体交代岩石圈地幔的产物,综合分析认为其形成于活动大陆边缘环境.黑山头组火山岩时代的确定及构造环境信息为进一步认识西准噶尔巴尔雷克一带的构造演化提供了新的证据.%The volcanic rocks of the Heishantou Formation in the area of Barleik, West Junggar, consist of gray purple (vesicular) almond andesite and almond shaped basaltic andesite, belonging to sub-alkaline series. High-precision LA-ICP-MS zircon U-Pb dating shows that the rocks formed at the age of 349 8Ma, with MSWD=0. 14 (95% conf.), suggesting an age of Early Carboniferous. These rocks are characterized by moderate Mg* (23. 82—50. 4) , relatively high alkali (Na2O+K2O=3. 74% ~8. 02%), and relative enrichment in Na, enrichment in LREE [(La/Yb)N = 2. 87~13. 41] and well fractionated [(La/Sm)N = 1. 46 ~ 3. 41], and weak HREE fractionation [(Gd/Yb)N = l. 46~3. 48]. Only part of the samples shows weak negative Eu anomalies (δEu = 0. 82 — 1. 47). Large ion lithophile elements (LILEs, eg. , Ba, Th, K and Sr) are relatively enriched, especially Ba and K, and high field-strength elements (HFSEs, eg. , Nb, Ta , and Ti) are depleted, but Zr and Hf slightly enriched. Geochemical features indicate that the volcanic

  12. Formation Age of the Marble in the Khondalite Series in Jining, Inner Mongolia: Evidence of the LA-ICP-MS Zircon U-Pb Dating of Felsic Gneiss%内蒙集宁地区孔兹岩系中大理岩的形成时代——长英质片麻岩中LA-ICP-MS锆石U-Pb测年的证据

    Institute of Scientific and Technical Information of China (English)

    徐仲元; 范志伟; 刘正宏; 李世超; 王挽琼; 张超; 马越; 王英男

    2013-01-01

    Our research area is located in Jining,the eastern section of the Khondalite belt in the western block of the North China craton,where the khondalite series is composed of garnet-biotite gneiss in the lower part and marble in the upper part.Several layers of felsic gneiss interbedded with thin marble layers are found,and the parental rock of the felsic gneiss is defined as feldsparthic sandstone by petrographical study,zircon characteristics and restoring the protolithic types.After LA-ICP-MS zircon U-Pb dating of the felsic gneiss,72 zircon data are obtained from 70 zircon grains,among which the youngest detrital zircon data is (2 091±20) Ma that can represent the lower limit of felsic gneiss formation age; And the weighted average 207Pb/206 Pb apparent age of the 19 metamorphic zircon concentrated between 1.8-1.9 Ga is (1 852±15) Ma(MSWD=0.7),can represent the upper limit of deposition age of the original rock of the felsic gneiss.Based on the previous research results,we could conclude that in Jining area,marbles in the khondalite series were formed in the Paleoproterozoic Era between (1 852±15) Ma and (2 091±20) Ma,and underwent the regional metamorphism in (1 852±15) Ma.This suggests that marbles are the import.ant component of the khondalite series; In the Khondalite belt across the western block of the North China craton,a large scale of granitic intrusion had existed in the source region of protolith of the khondalite series.However,there are different material Source regions in every part of the belt; the protoliths of the khondalite series is not the in-situ deposition of fragmentary materials provided by the nearby Archean rocks,but alien tectonic rock sheet mingled with the nearby Archean rocks by Late Paleoproterozoic tectonic processes.%研究区位于华北克拉通西部孔兹岩带东段的集宁一带,区内的孔兹岩系由下部的榴云片麻岩组合和上部的大理岩组合组成.在大理岩组合的底部发现了数层与薄层大

  13. Las rocas monzoníticas del sector oriental del plutón de Cachauta, Precordillera mendocina: características geoquímicas y edad U/Pb (LA-ICP-MS) The monzonitic rocks of the eastern sector of the Cacheuta Pluton, Precordillera of Mendoza: geochemical signature and U/Pb age (LA-ICP-MS)

    OpenAIRE

    Carlos A. Cingolani; Norberto Uriz; Farid Chemale Jr; Ricardo Varela

    2012-01-01

    En el sur de la Precordillera mendocina, afora el plutón de Cacheuta formado por un borde de tipo monzonítico a granodiorítico (Boca del Río) gris-verdoso y otro posterior de mayor superficie aforante de composición granítica y tonos rosados-rojizos. Se ofrecen en este trabajo nuevos datos geoquímicos sobre las rocas monzoníticas y el análisis geocronológico por el método U/Pb (LA-ICP-MS) sobre 25 cristales de circones extraídos de tres muestras. Las rocas monzoníticas analizadas son de carac...

  14. Primera edad U-Pb en circón usando LA-ICP-MS de un dique traquiandesítico emplazado en el granito tipo-A Los Árboles, Sierras Pampeanas Orientales

    Directory of Open Access Journals (Sweden)

    Juan A Dahlquist

    2012-06-01

    Full Text Available La edad de cristalización de diques subvolcánicos emplazados en plutones graníticos carboníferos, Sierras Pampeanas Orientales, permanece incierta. La primera edad U-Pb en circón usando LA-ICP-MS obtenida en un dique que intruye al plutón Los Árboles (sierra de Fiambalá, revela una edad de cristalización de 311 ± 3 Ma.

  15. REE distribution in zircon from reference rocks of the Arctic region: Evidence from study by the LA-ICP-MS method

    Science.gov (United States)

    Nikolaev, A. I.; Drogobuzhskaya, S. V.; Bayanova, T. B.; Kaulina, T. V.; Lyalina, L. M.; Novikov, A. I.; Steshenko, E. N.

    2016-10-01

    The results of the LA-ICP-MS analysis of the concentrations of REEs, U, Th, and Hf in zircon from Paleo- and Neoarchean reference rocks of the Kola region (garnet-amphibole gneiss, basic and acid granulites, and granite pegmatite) are reported. A new methodology of the study of accessory zircons has been validated and modified. The accuracy of the results is confirmed by analysis of standard zircons Temora 1 and 91 500 and by comparison with the data obtained in other laboratories.

  16. 西准噶尔马拉苏早泥盆世火山岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其大地构造意义%LA-ICP-MS zircon U-Pb geochronology, geochemical characteristics and tec-tonic significance of Early Devonian volcanic rocks in Malasu area, western Juggar Basin

    Institute of Scientific and Technical Information of China (English)

    翁凯; 徐学义; 马中平; 孙吉明; 张涛

    2015-01-01

    The early Devonian strata in Malasu area is a set of littoral-neritic facies volcanic sedimentary rocks. This paper reports the zircon age and geochemical characteristics of the volcanic rocks. A lot of Neo-Archean and middle Neo-Proterozoic zircons indicate that this area contains ancient continental crust material. According to the values of major elements (SiO 2 52.38%~69.6%, Na2O 2.80%~4.85%, K2O 0.16%~0.96%, TiO2 0.5%~1.96%, Al2O3 14.62%~18.18%, MgO 1.08%~5.75%) and the values of Mg# (22.92~38), the volcanic rocks of Malasu area are characterized by high content of sodium and low content of potassium, and thus belong to low-po⁃tassium tholeiite series and calc-alkaline series. The volcanic rocks have significant negative Eu anomalies ( 0.83~0.83), total rare earth element values of 73×10-6~115×10-6, and LREE/HREE values of 2.66~3.25. The geochemical characteristics of basaltic andesite sam⁃ples are similar to those of typical volcanic arc basalts, being rich in large ion lithophile elements K, Rb, Ba, Sr and depleted in the high field strength elements Nb, Ta, Zr, Hf. The same characteristics of enrichment of LILE and depletion of HFSE for dacite por⁃ phyry samples reflect the addition of lots of crust-derived materials. The chondrite-normalized REE and primitive mantle-normal⁃ized alteration-resistant trace element patterns for the dacite porphyry are similar to the patterns of basaltic andesite, which suggests that they belong to the comagmatic evolutionary series. Comprehensive research shows that the volcanic rocks have the characteristics of island arc volcanic rocks, and were formed in the volcanic island arc environment in the process of plate subduction.%马拉苏地区早泥盆世地层为一套滨海—浅海相火山—沉积岩系,对其中的火山岩夹层进行锆石U-Pb同位素定年和岩石地球化学研究,定年结果显示有大量的新太古代和中新元古代锆石,表明该区存在古老的大陆地壳

  17. LA-ICP-MS Pb-U Dating of Young Zircons from the Kos-Nisyros Volcanic Centre, SE Aegean Arc (Greece)

    Science.gov (United States)

    Guillong, M.; Von Quadt, A.; Peytcheva, I.; Bachmann, O.

    2014-12-01

    Zircon Pb-U dating has become a key technique for answering many important questions in geosciences. This paper describes a new LA-ICP-MS approach. We show, using previously dated samples of a large quaternary rhyolitic eruption in the Kos-Nisyros volcanic centre (the 161 ka Kos Plateau Tuff), that the precision of our LA-ICP-MS method is as good as via SHRIMP, while ID-TIMS measurements confirm the accuracy. Gradational age distribution over >140 ka of the Kos zircons and the near-absence of inherited cores indicate near-continuous crystallisation in a growing magma reservoir with little input from wall rocks. Previously undated silicic eruptions from Nisyros volcano (Lower Pumice, Nikia Flow, Upper Pumice), which are stratigraphically constrained to have happened after the Kos Plateau Tuff, are dated to be younger than respectively 124 ± 35 ka, 111 ± 42 ka and 70 ± 24 ka. Samples younger than 1 Ma were corrected for initial thorium disequilibrium using a new formula that also accounts for disequilibrium in 230Th decay. Guillong, M. et al., 2014, JAAS, 29, p. 963-967; doi: 10.1039/c4ja00009a.

  18. Electron microprobe chemical U-Th-Pb and La-ICP-MS U-Pb dating of multiple hydrothermal and metamorphic events recorded in minerals of the Lagoa Real uraniferous albitites (Brazil)

    Energy Technology Data Exchange (ETDEWEB)

    Chaves, Alexandre de Oliveira, E-mail: alochaves@yahoo.com.b [Universidade Federal do Espirito Santo (UFES), Vitoria (Brazil); Tubrett, Michael [Memorial University of Newfoundland (Canada); Avelar, Simone Cristina Pires; Rios, Francisco Javier; Neves, Jose Marques Correia; Alves, James Vieira; Fuzikawa, Kazuo; Prates, Sonia Pinto [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil); Sgarbi, Geraldo Norberto Chaves [Universidade Federal de Minas Gerais (IG/UFMG), Belo Horizonte (Brazil). Inst. de Geociencias; Matos, Evando Carele de [Industrias Nucleares do Brasil, Caetite, BA (Brazil)

    2009-05-15

    Lagoa Real uraniferous albitites are rocks which went through multiple modifications after formation. Electron microprobe chemical U-Th-Pb and LA-ICP-MS U-Pb dating of minerals of albitites reveal protolith (U-bearing sodic syenites) crystallization and isochemical metamorphism at ca. 2.0-1.9 Ga during the final stages of the Orosirian orogenic event, when the first generation of uraninites was formed. Multiple uranium and lead mobilization promoted by at least five hydrothermal events (ca. 1.7 Ga, ca. 1.5 Ga, ca. 1.3 Ga, ca. 1.1 Ga, and ca. 1.0 Ga) was detected in the albitites. A probable formation of a second uraninite group and/or resetting of UPb clock of older uraninites during the Brasiliano orogenic event at ca. 0.5 Ga also took place.(author)

  19. LA-ICP-MS zircon U-Pb geochronology of the tuffs on the uppermost of the Emeishan basalt succession in Panxian County, Guizhou Province: Constraints on genetic link between Emeishan large igneous province and the mass extinction%贵州盘县峨眉山玄武岩系顶部凝灰岩LA-ICP-MS锆石U-Pb年龄:对峨眉山大火成岩省与生物大规模灭绝关系的约束

    Institute of Scientific and Technical Information of China (English)

    朱江; 张招崇; 侯通; 康健丽

    2011-01-01

    voluminous gases and volcanic ash production. Recently, we have found a - 100m thick tuff layer in the uppermost of Emeishan basalt succession in the Panxian County, Guizhou Province, the eastern ELIP. Our new LA-ICP-MS zircon U-Pb dating on tuff from the uppermost of the Emeishan basalt succession yields an average age of 251. 0 ± 1.0Ma, coeval to those from ash or clay beds in the P-TB of the Meishan section in Zhejiang Province. Consequently, the end of the Emeishan flood volcanism is consistent with the main pulse of the P-TB Siberian large igneous province. Thus, our new dating result provides us a clue of a cause-and-e£fect relationship between the Emeishan large igneous province and the largest mass extinction in the earth's history (P-TB).

  20. In situ isotopic analyses of U and Pb in zircon by remotely operated SHRIMP II, and Hf by LA-ICP-MS: an example of dating and genetic evolution of zircon by {sup 176}Hf/{sup 177}Hf from the Ita Quarry in the Atuba Complex, SE, Brazil; Analises in situ de U e Pb em zircao por SRIMP II por controle remoto e de Hf por LA-ICP-MS: um exemplo de datacao e da evolucao genetica de zircao atraves da razao {sup 176}Hf/{sup 177} em amostra da Pedreira Ita no Complexo Atuba, SE, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Sato, K.; Siga Junior, Oswaldo; McReath, Ian; Sproesser, Walter; Basei, Miguel Angelo Stipp [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Geociencias. Centro de Pesquisas Geocronologicas], e-mail: keisato@usp.br, e-mail: osigajr@usp.br, e-mail: ianmcr@usp.br, e-mail: wmspres@usp.br, e-mail: baseimas@usp.br; Silva, Josiane Aline da [Universidade de Sao Paulo (USP), SP (Brazil). Programa de Pos-graduacao em Geoquimica e Geotectonica; Dunyi, Liu [Institute of Geology, Beijing (China); Iizuka, Takafumi; Rino, Shuji; Hirata, Takafumi [Tokyo Institute of Technology, Tokyo (Japan)

    2009-10-15

    Remotely-operated SHRIMP dating of zircon is an interesting alternative for dating of zircon crystals. Although it does not represent any technical progress of the geochronological method using the U-Pb system in zircon it is a very useful and cheap facility. The procedure was first used for mass spectrometric analyses involving two international laboratories in Sao Paulo, Brazil and Beijing, China. It was applied to samples of three gneiss-migmatitic rocks from the Ita quarry in the Atuba Complex (located between the Luis Alves and the Apiai Domain) to test previous controversial hypotheses about its evolution. The presence of important archaean and paleo proterozoic components in the complex is confirmed by analyses of zircon found in probably neo proterozoic leucosomes. Diorite intrusion also occurred during the neo proterozoic, associated with the 0.6Ga continental collisions involved in the assembly of Gondwana. The determination of Hf isotope ratios by LA-ICP/MS represents a new option for checking the relative importance of mantle ({epsilon}{sub Hf} > 0) and crustal contributions (({epsilon}{sub Hf} < 0) during the growth of the zircon crystals. While the archaean component in the complex was derived from the mantle ({epsilon}{sub Hf} + 1.5 to + 8.7) the paleo proterozoic component had a crustal contribution ({epsilon}{sub Hf} - 9.1 to -10.1). (author)

  1. Chronological record of the Early Mesozoic underplating in the northern margin of North China-U-Pb chronometry of zircons in the Late Mesozoic andesite from Western Liaoning

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Cathodoluminescence spectroscopic analysis of zircons in the uppermost sanukites of the early Cretaceous Yixian Formation in Western Liaoning reveals zoning structures of the zircons in the volcanic rocks. LA-ICP-MS chronometry shows that the central part of the zircons is remnant zircon with a U-Pb dating of 254 Ma, which is consistent with the age of the Early Mesozoic underplating granulites, and that the periphery is zircon crystallizing out of the host magma with a U-Pb dating of 116 Ma, which is highly consistent with the Ar-Ar dating of the host volcanic rocks. Compositions of the clinopyroxenes xenocrystals in the sanukites are similar to those of the clinopyroxenes in the underplating granulites, indicating that the granulites accreted to the lower crust in the Early Mesozoic have been reformed and disrupted by the upwelling diapers of the asthenosphere and taken part in formation of the sanukites in the Late Mesozoic.

  2. U-Pb geochronology by La-CIP-MS and petrography of Sao Carlos massif - stanniferous province of Rondonia; Geocronologia U-Pb por La-ICP-MS e petrografia do macico Sao Carlos - Provincia Estanifera de Rondonia

    Energy Technology Data Exchange (ETDEWEB)

    Debowski, Beatriz P.; Geraldes, Mauro Cesar; Nogueira, Camila; Almeida, Bruna Saar de [Universidade do Estado do Rio de Janeiro, (UERJ), RJ (Brazil)

    2015-07-01

    U-Pb dating by ICP-MS-LA were performed in four samples of the Massif Sao Carlos massif, representative of the younger Granites of Rondonia belonging to the stanniferous province of the same State. Dated samples are granites of pink in colour and coarse-grained to porphyry with main mineralogy consisting of feldspar pertitic to mesopertitic, quartz, plagioclase in lower proportion, biotite and amphibole in some cases. Ages obtained were 986 ± 14 Ma, 974 ± 10 Ma, ± 8 Ma 992.7 and 996 ± 8 Ma and represent the age of crystallization of the Massif. Such ages are concordant with others reported on the bibliography ratifying the inclusion of the massif in the younger Granites of Rondonia, which are directly associated with the most significant mineralization of cassiterite in the State.

  3. QEMSCAN+LA-ICP-MS: a 'big data' generator for sedimentary provenance analysis

    Science.gov (United States)

    Vermeesch, Pieter; Rittner, Martin; Garzanti, Eduardo

    2017-04-01

    Sedimentary provenance may be traced by 'fingerprinting' sediments with chemical, mineralogical or isotopic means. Normally, each of these provenance proxies is characterised on a separate aliquot of the same sample. For example, the chemical composition of the bulk sample may be analysed by X-ray fluorescence (XRF) on one aliquot, framework petrography on another, heavy mineral analysis on a density separate of a third split, and zircon U-Pb dating on a further density separate of the heavy mineral fraction. The labour intensity of this procedure holds back the widespread application of multi-method provenance studies. We here present a new method to solve this problem and avoid mineral separation by coupling a QEMSCAN electron microscope to an LA-ICP-MS instrument and thereby generate all four aforementioned provenance datasets as part of the same workflow. Given a polished hand specimen, a petrographic thin section, or a grain mount, the QEMSCAN+LA-ICP-MS method produces chemical and mineralogical maps from which the X-Y coordinates of the datable mineral are extracted. These coordinates are subsequently passed on to the laser ablation system for isotopic and, hence, geochronological analysis. In the process of finding all the zircons in a sediment grain mount, the QEMSCAN yields the compositional and mineralogical compositions as byproducts. We have applied the new QEMSCAN+LA-ICP-MS instrument suite to over 100 samples from three large sediment routing systems: (1) the Tigris-Euphrates river catchments and Rub' Al Khali desert in Arabia; (2) the Nile catchment in northeast Africa and (3) desert and beach sands between the Orange and Congo rivers in southwest Africa. These studies reveal (1) that Rub' Al Khali sand is predominantly derived from the Arabian Shield and not from Mesopotamia; (2) that the Blue Nile is the principal source of Nile sand; and (3) that Orange River sand is carried northward by longshore drift nearly 1,800km from South Africa to southern

  4. Cenozoic foreland basins of Central Andes: a preliminary provenance U-Pb zircon analysis of sedimentary sequences of Calchaqui Valley

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Alisson Lopes; Hauser, Natalia; Pimentel, Marcio Martins; Matteini, Massimo, E-mail: alisson_oliveira@hotmail.com [Universidade de Brasilia (UnB), DF (Brazil). Laboratorio de Geocronologia; Galli, Claudia Ines [Faculdad de Ingenieria, Universidad Nacional de Jujuy (Argentina); Coira, Beatriz [CIT Jujuy, CONICET. Instituto de Geologia y Mineria (Argentina); Alonso, Ricardo; Barrientos, Andrea [Instituto CEGA, CONICET. Universidad Nacional de Salta (Argentina)

    2015-07-01

    The Eocene of northwestern Argentina records complex basin and structural evolution, including continental sedimentation of the post-rift Salta Basin and the beginning of the Andean uplift and foreland system evolution. This illuminates a significant period of evolutionary history of this and surrounding basins in northwestern Argentina. U-Pb zircon analyses by LA-ICP-MS for three formations representing post-rift to foreland stages allowed interpretation about provenance terrains. The Lumbrera Formation, representing the post-rift stage, shows bimodal sources with a main zircon population around 462 Ma, and a second population around 1023 Ma. The Los Colorados and Angastaco Formations representing the sedimentation in a foreland basin, show a unimodal source around 490 Ma, and 517 Ma respectively. Zircons younger than 50 Ma were not identified during this study. (author)

  5. Crustal melting and recycling: geochronology and sources of Variscan syn-kinematic anatectic granitoids of the Tormes Dome (Central Iberian Zone). A U-Pb LA-ICP-MS study

    Science.gov (United States)

    López-Moro, F. J.; López-Plaza, M.; Gutiérrez-Alonso, G.; Fernández-Suárez, J.; López-Carmona, A.; Hofmann, M.; Romer, R. L.

    2017-04-01

    In this study, we report U-Pb Laser Ablation ICP-MS zircon and ID-TIMS monazite ages for peraluminous granitoid plutons (biotite ± muscovite ± cordierite ± sillimanite) in the Tormes Dome, one of the gneiss-cored domes located in the Central Iberian Zone of the Variscan belt of northern Spain. Textural domains in zircon, interpreted to represent the magmatic crystallization of the granitoids (and one monazite fraction in the Ledesma pluton) yielded ages around 320 Ma, in agreement with other geochronological studies in the region. This age is interpreted to date the timing of decompression crustal melting driven by the extensional collapse of the orogenic belt in this domain of the Variscan chain of western Europe. In addition, there are several populations of inherited (xenocrystic) zircon: (1) Carboniferous zircon crystals (ca. 345 Ma) as well as one of the monazite fractions in the coarse-grained facies of the Ledesma pluton that also yielded an age of ca. 343 Ma. (2) Devonian-Silurian zircon xenocrysts with scattered ages between ca. 390 and 432 Ma. (3) Middle Cambrian-Ordovician (ca. 450-511 Ma). (4) Ediacaran-Cryogenian zircon ages (ca. 540-840 Ma). (5) Mesoproterozoic to Archaean zircon (900-2700 Ma). The abundance of Carboniferous-inherited zircon shows that crustal recycling/cannibalization may often happen at a fast pace in orogenic scenarios with only short lapses of quiescence. In our case study, it seems plausible that a "crustal layer" of ca. 340 Ma granitoids/migmatites was recycled, partially or totally, only 15-20 My after its emplacement.

  6. New U-Pb zircon and 40Ar/39Ar muscovite age constraints on the emplacement of the Lizio syn-tectonic granite (Armorican Massif, France)

    OpenAIRE

    Tartese, Romain; Poujol, Marc; Ruffet, Gilles; Boulvais, Philippe; Yamato, Philippe; Kosler, Jan

    2011-01-01

    International audience; LA-ICP-MS U-Pb analyses performed on zircon grains from the Lizio granite yielded an emplacement age of 316 6 Ma. Typical S-C structures show that the Lizio granite was emplaced contemporaneously with dextral shearing along the northern branch of the South Armorican Shear Zone and that it was therefore active at that time. 40Ar/39Ar analyses performed on muscovite grains yielded plateau dates ranging between 311.5 and 308.2 Ma. Muscovite chemistry is typical of primary...

  7. Allanite age-dating: Non-matrix-matched standardization in quadrupole LA-ICP-MS

    Science.gov (United States)

    Burn, M.; Lanari, P.; Pettke, T.; Engi, M.

    2014-12-01

    Allanite Th-U-Pb age-dating has recently been found to be powerful in unraveling the timing of geological processes such as the metamorphic dynamics in subduction zones and crystallization velocity of magmas. However, inconsistencies among analytical techniques have raised doubts about the accuracy of allanite age data. Spot analysis techniques such as LA-ICP-MS are claimed to be crucially dependent on matrix-matched standards, the quality of which is variable. We present a new approach in LA-ICP-MS data reduction that allows non-matrix-matched standardization via well constrained zircon reference materials as primary standards. Our data were obtained using a GeoLas Pro 193 nm ArF excimer laser ablation system coupled to an ELAN DRC-e quadrupole ICP-MS. We use 32 μm and 24 μm spot sizes; laser operating conditions of 9 Hz repetition rate and 2.5 J/cm2 fluence have proven advantageous. Matrix dependent downhole fractionation evolution is empirically determined by analyzing 208Pb/232Th and 206Pb/238U and applied prior to standardization. The new data reduction technique was tested on three magmatic allanite reference materials (SISSb, CAPb, TARA); within error these show the same downhole fractionation evolution for all allanite types and in different analytical sessions, provided measurement conditions remain the same. Although the downhole evolution of allanite and zircon differs significantly, a link between zircon and allanite matrix is established by assuming CAPb and TARA to be fixed at the corresponding reference ages. Our weighted mean 208Pb/232Th ages are 30.06 ± 0.22 (2σ) for SISSb, 275.4 ± 1.3 (2σ) for CAPb, and 409.9 ± 1.8 (2σ) for TARA. Precision of single spot age data varies between 1.5 and 8 % (2σ), dependent on spot size and common lead concentrations. Quadrupole LA-ICP-MS allanite age-dating has thus similar uncertainties as do other spot analysis techniques. The new data reduction technique is much less dependent on quality and homogeneity

  8. First U-Pb isotopic data on zircon from andesite of the Saf'yanovka Cu-bearing massive sulfide deposit (Middle Urals)

    Science.gov (United States)

    Ronkin, Yu. L.; Pritchin, M. E.; Soroka, E. I.; Gerdes, A.; Puchkov, V. N.; Busharina, S. V.

    2016-07-01

    New results of U-Pb LA ICP-MS dating of zircon from andesite samples cropping out on the western wall of the Saf'yanovka quarry (57°22'58.88″ N, 61°31'50.85″ E) in the synonymous Cu-Zn-bearing massive sulfide deposit of the Urals type are considered. The position of data points of the U-Pb systematics in the 207Pb/235U-206Pb/238U plot determines a cluster practically corresponding to the concordant U-Pb age: 422.8 ± 2.0 Ma. This date indicates for the first time the presence of Pridolian volcanogenic rocks in the East Urals megazone of the Middle Urals.

  9. Petrogenetic setting of andsites in Rongna ore block, Tiegelong Cu (Au-Ag) deposit, Duolong ore concentration area, Tibet:Evidence from zircon U-Pb LA-ICP-MS dating and petrogeochemistry of andsites%西藏多龙矿集区铁格隆南铜(金银)矿床荣那矿段安山岩成岩背景:来自锆石U-Pb年代学、岩石地球化学的证据

    Institute of Scientific and Technical Information of China (English)

    王勤; 卫鲁杰; 冯军; 李力; 唐菊兴; 方向; 林彬; 宋扬; 王艺云; 杨欢欢; 杨超; 李彦波

    2015-01-01

    In this paper, the authors studied the andsites in Rongna ore block, Tiegelong Cu (Au-Ag) deposit, Duolong ore concentration area, Tibet, and used the zircon U-Pb data and petrogeochemistry of andsites to identify the petrogenetic age and tectonic setting of the andsites. The weighted average age of zircon U-Pb is 110.1 ± 0.7 Ma (MSWD=2.3) , which represents the petrogenesis age. An analysis of the whole rock sample shows that SiO2 values are 59.5%-61.48%, Al2O3 values are 16.14%-17.11%and Na2O+K2O values are 6.02%-6.63%;Mg# is of intermediate value. LILE such as Ba, Rb, Th, K are rich, HFSE such as Ta, Nb, P, Ti are relatively poor and characterized by Rb positive anomaly and obvious Zr, Hf negative anomalies. Petrological and geochemical studies show that the andesites are high potassium calc-alkaline rocks exhibiting the characteristics of Andean-type active continental margin volcanic rocks. They resulted probably from partial melting of subducted oceanic slab as well as miscibility with crustal material during the upward migration of the magma in the case that subducted oceanic slab didn’t interact with the mantle. They were the magma products of the northward subduction of Bangong Co-Nujiang Ocean and Lhasa and the collision collage process of Qiangtang terrane. In combination with other dating data and drilling core catalog data, the authors hold that the formation of andesites was later than the rock-forming and ore-forming stage of the Tiegelongnan high sulfur epithermal Cu (Au-Ag) deposits, which seems to have been the important condition for the preservation of the ore deposit.%本文主要对出露与西藏多龙矿集区铁格隆南矿区荣那矿段的安山岩开展了锆石U−Pb定年、岩石地球化学测试,旨在确定该套火山岩的成岩年龄及其形成的构造背景。安山岩的LA−ICP−MS锆石U−Pb加权平均年龄为(110.1±0.7) Ma (MSWD=2.3),代表了其成岩年龄。岩石SiO2为59.5%~61.48%;Al2O3为16.14%~17.11%

  10. Recent applications on isotope ratio measurements by ICP-MS and LA-ICP-MS on biological samples and single particles

    Science.gov (United States)

    Becker, J. Sabine; Sela, Hagit; Dobrowolska, Justina; Zoriy, Miroslav; Becker, J. Susanne

    2008-02-01

    Inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation ICP-MS (LA-ICP-MS) have proved themselves to be powerful and sensitive inorganic mass spectrometric techniques for analysing stable and radioactive isotopes in different application fields because of their high sensitivity, low detection limits, good accuracy and precision. New applications of ICP-MS focus on tracer experiments and the development of isotope dilution techniques together with nanoflow injections for the analysis of small volumes of biological samples. Today, LA-ICP-MS is the method of choice for direct determination of metals, e.g., on protein bands in gels after the gel electrophoresis of protein mixtures. Tracer experiments using highly enriched 65Cu were utilized in order to study the formation of metal-binding bovine serum proteins. A challenging task for LA-ICP-MS is its application as an imaging mass spectrometric technique for the production of isotope images (e.gE, from thin sections of brain tissues stained with neodymium). In this paper, we demonstrate the application of imaging mass spectrometry on single particles (zircon and uranium oxide). Single Precambrian zircon crystals from the Baltic Shield were investigated with respect to isotope ratios using LA-ICP-MS for age dating. The U-Pb age was determined from the isochrone with (1.48 ± 0.14) × 109 a. Using isotope ratio measurements on 10 nuclear uranium oxide single particles the 235U/238U isotope ratio was determined to be 0.032 ± 0.004. This paper describes recent developments and applications of isotope ratio measurements by ICP-MS and LA-ICP-MS on biological samples and single particles.

  11. Zircon U-Pb geochronology of basement metamorphic rocks in the Songliao Basin

    Institute of Scientific and Technical Information of China (English)

    PEI FuPing; XU WenLiang; YANG DeBin; ZHAO QuanGuo; LIU XiaoMing; HU ZhaoChu

    2007-01-01

    Zircon LA-ICP MS U-Pb dating of six metamorphic rocks and a metagranite (breccia) from southern basement of the Songliao Basin are reported in order to constrain the formation ages of basement. The basement metamorphic rocks in the Songliao Basin mainly consist of metagabbro (L45-1), amphibolite (SN117), metarhyolitical tuff (G190), sericite (Ser) schist (N103), chlorite (Chi) schist (T5-1), biotite (Bi)-actinolite (Act)-quartz (Q) schist (Y205), and metagranite (L44-1). The cathodoluminesence (CL)images of the zircons from metagabbro (L45-1) and metagranite (L44-1) indicate that they have cores of magmatic origin and rims of metamorphic overgrowths. Their U-Pb isotopic ages are 1808±21 Ma and 1873±13 Ma, respectively. The zircons with oscillatory zoning from amphibolite (SN117) and Chi schist (T5-1), being similar to those of mafic igneous rocks, yield ages of 274 ± 3.4 Ma and 264 ± 3.2 Ma, respectively. The zircons from metarhyolitical tuff (G190) and Ser schist (N103) display typical magmatic growth zoning and yield ages of 424 ± 4.5 Ma and 287 ± 5.1Ma, respectively. Most of zircons from Bi-Act-Q schist (Y2O5) are round in shape and different in absorption degree in the CL images, implying their sedimentary detritals. U-Pb dating yield concordant ages of 427 ± 3.1Ma, 455 ± 12 Ma, 696 ± 13 Ma,1384±62 Ma, 1649±36 Ma, 1778±18 Ma, 2450±9 Ma, 2579±10 Ma, 2793±4 Ma and 2953±14 Ma. The above-mentioned results indicate that the Precambrian crystalline basement (1808-1873 Ma) exists in the southern Songliao Basin and could be related to tectonic thrust, and that the Early Paleozoic (424-490 Ma) and Late Paleozoic magmatisms (264-292 Ma) also occur in the basin basement, which are consistent with the ages of the detrital zircons from Bi-Act-Q schist in the basement.

  12. Provenance and sediment dynamics within river basins in Western Peru through detrital zircons U-Pb ages

    Science.gov (United States)

    Camille, Litty; Pierre, Lanari; Marco, Burn; Fritz, Schlunegger

    2016-04-01

    U-Pb dating of detrital zircons from clastic sediments by LA-ICPMS has become a popular method in sedimentary correlation and provenance studies. Because of remarkable durability, detrital zircons may be reworked through multiple sedimentary cycles and provide an ideal material to study the sedimentary provenance in rivers and the erosional characteristics. The Western side of the Peruvian Andes has experienced multiple pluvial periods induced phases of erosion and the formation of subsequent cut-and-fill terrace sequences since the Pleistocene. The aim of the study is to estimate the source areas of the terrace and modern deposits to infer changes in sediment dynamics through time and correlate them with the climatic change and especially precipitation patterns. To this extent, we determined the provenance of 4 dated terrace deposits along with modern sediments from the same streams by matching detrital-zircon ages with crystallization ages of source rocks. Age populations of detrital zircons are derived using U-Pb LA-ICP-MS analysis of about 50 zircons. Results show changes in the sediment provenance through time. Nowadays, sediment source areas are mainly located on the uppermost reach of the rivers whereas during the Pleistocene, sediment source areas were both located in the headwaters and along the middle reach of the rivers. These differences in terms of provenance could correlate with a change in precipitation locations and rates. Indeed a scenario where the locus of precipitation occurrence shifted from the middle reaches including the Altiplano during the past, to the Altiplano only as observed today, along with higher precipitation rates during the periods of terraces formation, offers an explanation to explain the erosional patterns recorded by detrital zircons.

  13. Significance of zircon U-Pb ages from the Pescadero felsite, west-central California coast ranges

    Science.gov (United States)

    McLaughlin, Robert J.; Moore, Diane E.; ,; Martens, UWE C.; Clark, J.C.

    2011-01-01

    Weathered felsite is associated with the late Campanian–Maastrichtian Pigeon Point Formation near Pescadero, California. Poorly exposed, its age and correlation are uncertain. Is it part of the Pigeon Point section west of the San Gregorio–Hosgri fault? Does it rest on Nacimiento block basement? Is it dextrally offset from the Oligocene Cambria Felsite, ∼185 km to the southeast? Why is a calc-alkaline hypabyssal igneous rock intrusive into the outboard accretionary prism? To address these questions, we analyzed 43 oscillatory-zoned zircon crystals from three incipiently recrystallized pumpellyite ± prehnite ± laumontite-bearing Pescadero felsite samples by sensitive high-resolution ion microprobe–reverse geometry (SHRIMP-RG) and laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) techniques. Thirty-three zircons gave late Mesozoic U-Pb ages, with single-grain values ranging from 81 to 167 Ma; ten have pre-Mesozoic, chiefly Proterozoic ages. A group of the four youngest Pescadero zircons yielded an apparent maximum igneous age of ca. 86–90 Ma. Reflecting broad age scatter and presence of partly digested sandstone inclusions, we interpret the rest of the zircons (perhaps all) as xenocrysts. Twenty-three zircons were separated and analyzed from two samples of the similar Cambria Felsite, yielding a unimodal 27 Ma U-Pb age. Clearly, the origin of the Upper Oligocene Cambria Felsite is different from that of the Upper Cretaceous Pescadero felsite; these rocks are not correlated, and do not constrain displacement along the San Gregorio–Hosgri fault. Peak ages differ slightly, but relative probability curves for Mesozoic and pre-Mesozoic Pescadero zircons compare well, for example, with abundant U-Pb age data for detrital zircons from Franciscan metaclastic strata ∼100 km to the east in the Diablo Range–San Francisco Bay area, San Joaquin Great Valley Group turbidites, Upper Cretaceous Nacimiento block Franciscan strata, and Upper

  14. LA-ICP-MS U-Pb ages of pillow lava basalts in southwestern Langshan, Inner Mongolia and their implication%内蒙古狼山西南地区枕状玄武岩LA-ICP-MS锆石U-Pb年龄及意义

    Institute of Scientific and Technical Information of China (English)

    张进; 李锦轶; 刘建峰; 李岩峰; 曲军峰; 张义平

    2013-01-01

    报道了新近在华北北缘西段狼山地区发现的枕状玄武岩的初步定年工作.前人将其时代定为早古生代.对选自玄武岩的32颗锆石进行了LA-ICP-MS U-Pb定年结果表明,玄武岩的锆石大量为捕获基底的锆石,其年龄和锆石内部结构复杂多样.根据锆石内部特征将其划分为4类,其中的板状锆石被定为玄武岩的自生锆石,年龄为晚古生代末期—早三叠世早期.其余均为来自阿拉善地块基底的锆石,主要为古元古代—新大古代和古生代锆石.狼山晚古生代末期的玄武岩可能产自古亚洲洋封闭后由于岩石圈拆沉导致的伸展环境,该期伸展贯穿华北北缘直至阿拉善地块,暗示华北板块与阿拉善地块至少在晚古生代之前就已经拼合在一起了.%Recent found pillow lava basalts in the southwestern Langshan and its preliminary dating has been reported here. Previous survey had assigned its age at the Early Paleozoic. 32 zircons from pillow lava basalts have been dated using LA-ICP-MS. Most zircons from basalts are captured from the basement, the distribution of ages and internal structures of which are complicated. Four groups of zircons have been distinguished by their internal structures. Among them the tabular zircons have been believed as the autogenetic zircons of pillow lava basalts, the ages of these zircons range from the end of Permian to the Early Triassic. The rest zircons in the samples are all from the Alashan basement, among which Paleoproterozoic and Newarchaeozoic zircons and Paleozoic zircons are most. The latest Late Permian Langshan basalts may developed in the extensional tectonics resulting from the delamination of the lithosphere after the closure of the Paleoasian Ocean, the extension of this period occurred along the whole north margin of the North China Plate including the Alashan block, which means that the Alashan block jointed with the North China Plate at least before the Late Paleozoic.

  15. Provenance from zircon U-Pb age distributions in crustally contaminated granitoids

    Science.gov (United States)

    Bahlburg, Heinrich; Berndt, Jasper

    2016-05-01

    The basement of sedimentary basins is often entirely covered by a potentially multi-stage basin fill and therefore removed from direct observation and sampling. Melts intruding through the basin stratigraphy at a subsequent stage in the geological evolution of a region may assimilate significant volumes of country rocks. This component may be preserved in the intrusive body either as xenoliths or it may be reflected only by the age spectrum of incorporated zircons. Here we present the case of an Ordovician calc-alkaline intrusive belt in NW Argentina named the "Faja Eruptiva de la Puna Oriental" (Faja Eruptiva), which in the course of intrusion sampled the unexposed and unknown basement of the Ordovician basin in this region, and parts of the basin stratigraphy. We present new LA-ICP-MS U-Pb ages on zircons from 9 granodiorites and granites of the Faja Eruptiva. The main part of the Faja Eruptiva intruded c. 445 Ma in the Late Ordovician. The zircon ages obtained from the intrusive rocks have a large spread between 2683.5 ± 21.6 and 440.0 ± 4.9 Ma and reflect the underlying crust and may be interpreted in several ways. The inherited zircons may have been derived from the oldest known unit in the region, the thick siliciclastic turbidite successions of the upper Neoproterozoic-lower Cambrian Puncoviscana Formation, which is inferred to represent the basement of the NW Argentina. The basement to the Puncoviscana Formation is not known. Alternatively, the inherited zircons may reflect the geochronological structure of the entire unexposed Early Paleozoic crust underlying this region of which the Puncoviscana Formation was only one component. This crust likely contained rocks pertaining to and detritus derived from earlier orogenic cycles of the southwestern Amazonia craton, including sources of Early Meso- and Paleoproterozoic age. Detritus derived, in turn, from the Faja Eruptiva intrusive belt reflects the origin of the granitoids as well as the inherited

  16. First U-Pb detrital zircon ages from Numidian sandstones in Southern Apennines (Italy): Evidences of African provenance

    Science.gov (United States)

    Fornelli, Annamaria; Micheletti, Francesca; Langone, Antonio; Perrone, Vincenzo

    2015-05-01

    Two samples of quartz-rich sandstones collected in the Numidian Flysch of Southern Apennines (Italy) have been studied to highlight the provenance of detritus using radiometric dating by LA-ICP-MS of detrital zircons and to compare the obtained ages with those of the Betic and Maghrebian Chains. The provenance of quartzose detritus from European or African Plates is still debated in these Chains, accordingly the ages of the detrital zircons can contribute significantly to discriminate the origin of the quartzose supply. The U-Pb zircon ages (n = 47) vary from 3047 ± 13 Ma (Mesoarchean) to 516 ± 19 Ma (Cambrian). The predominance of Paleo-Proteozoic ages (2500-1600 Ma) and the lack of Hercynian and Alpine ones suggest a provenance of the Numidian supply from North-African cratonic areas during the early-middle Langhian, when the Numidian successions of Southern Apennines were deposited. In addition, a cluster of ages at 773 ± 24 Ma and 668 ± 12 Ma in one sample and at 664 ± 17 Ma in the other sample, calculated on zircon domains with magmatic zoning, testify to an important contribution from Neo-proterozoic "granitic" rocks widely outcropping in the North-African Craton. The age data on detrital zircons from Numidian sandstones in Southern Apennines overlap those found in the Numidian sandstones widespread in the Betic Cordillera and in the Maghrebian Chain from south Spain to Sicily. This suggests that the entire depositional zone in which Numidian Flysch deposited, was fed from a southerly source represented by the African Craton where Archean, Proterozoic and Cambrian rocks widely crop out from the Atlantic coast to the Hoggar and Tibesti Massifs. Finally, it must be outlined that a Meso-Archean zircon age (3047 Ma) has been found in the Numidian Flysch of the Southern Apennines whereas in the Numidian Flysch of the Maghrebian Chain, zircons older than Paleo-proterozoic (1840 Ma) have not yet been found.

  17. Detrital zircon U-Pb and Hf isotopic data from the Liuling Group in the South Qinling belt: Provenance and tectonic implications

    Science.gov (United States)

    Liao, Xiao-ying; Wang, Ya-wei; Liu, Liang; Wang, Chao; Santosh, M.

    2017-02-01

    The Liuling Group is exposed in the Northern part of the South Qinling orogenic belt. LA-ICP-MS U-Pb analysis of detrital zircons from the meta-sandstones in this Group yields ages ranging between 400 Ma and 3200 Ma, with three prominent age clusters at 500-400 Ma, 850-700 Ma and 1000-900 Ma. A few older zircon populations with U-Pb ages of 1750-1450 Ma, 2000 Ma and 2600-2400 Ma are also present. Age data integrated with cathodoluminescence, trace element data and εHf(t) values of zircon grains show that the Liuling sediments have a complex source. Source rocks mainly include Early Neoproterozoic and Early Paleozoic granitoids, together with minor ultra-high pressure/high pressure (HP-UHP) metamorphic rocks, and paragneiss in the North Qinling belt, and Middle-Late Neoproterozoic magmatic rocks in the South Qinling belt. The dominant population of detrital zircon grains with ages between 500 Ma and 400 Ma show the characteristics of both magmatic and metamorphic zircons. They show three age clusters at 497 Ma, 451 Ma, and ca. 420 Ma and show marked correlation with the three stages of Palaeozoic magmatism, as well as with the peak and retrograde HP-UHP metamorphic stages in the North Qinling belt. This correlation demonstrates that these Early Palaeozoic granitoids and HP-UHP metamorphic rocks in the North Qinling belt were already exhumed to the surface, underwent erosion prior to Middle Devonian time and were then deposited in an extensional basin. Based on the results from detrital zircon U-Pb dating, combined with geochemical data and the regional geology, the deposition of Liuling sediments is inferred to have occurred in a post-orogenic extensional basin, rather than a subduction-related fore-arc basin or a foreland basin formed during or after continental collision.

  18. Petrogenesis of keratophyes in the Pingshui Group,Zhejiang: Constraints from zircon U-Pb ages and Hf isotopes

    Institute of Scientific and Technical Information of China (English)

    CHEN ZhiHong; XING GuangFu; GUO KungaYi; DONG YongGuan; CHEN Rong; ZENG Yong; LI LongMing; HE ZhengYu; ZHAO Ling

    2009-01-01

    Zircon LA-ICP-MS U-Pb ages and Hf isotopic as well as whole-rock geochemical data are reported for keratophyes in the Pingshui Group, Zhejiang. The results are used to discuss their petrogenesis and geological significance. The keratophyes were dated at 904±8 to 906±10 Ma. These intermediate-felsic rocks are characterized by high LREE contents end depletion of HREE and HFSE (e.g., Nb, Ta, Ti, P), resembling arc-derived rocks. The keratophyes exhibit positive εHf(t) values of 8.6 to 15.4, consistent with their εNd(t) values of 6.4 to 7.9 but far away from those of crust-derived rocks. Such features indicate that they were likely originated from prompt reworking of juvenile crust by arc-continent collision during the early-Neoproterozoic assembly between the Cathaysia and Yangtze Blocks. Combining with their Hf model ages, we suggest that there may exist not only remarkable growth of juvenile crust at ca.1.3-1.1 Ga but also production of juvenile arc-derived crust along the southeastern margin of the Yangtze Block (e.g., the Pingshui area) at ca.1.0-0.9 Ga.

  19. Analysis of U-Pb, O, Hf, and trace elements of horizontally oriented outer and inner zones of zircons from the Boulder batholith, Montana

    Science.gov (United States)

    Aleinikoff, J. N.; Lund, K.; Du Bray, E. A.; Wooden, J. L.; Kozdon, R.; Kita, N.; Valley, J. W.; Kamenov, G. D.; Mueller, P. A.

    2010-12-01

    The Late Cretaceous Boulder batholith, southwestern MT, is composed of the Butte Granite and at least a dozen smaller granodiorite to syenogranite plutons. These plutons (81-73 Ma) were dated by zircon U-Pb geochronology using the SHRIMP. Typically for SIMS analysis of igneous zircon, the analytical spot is located midway between core and rim on an area that displays fine oscillatory zoning, thus sampling a ~25-30 µm area of vertically oriented zones to a depth of 1-2 µm. For this study, preliminary LA-ICP-MS analysis of Hf isotopes in zircons from several plutons suggested that some grains show significant variation (>5 ɛHf units) between inner and outer zones. This finding instigated a detailed investigation in which data for multiple isotopic systems (U-Pb, trace elements, O, and Hf ) were collected from horizontally oriented zones. Zircons were mounted in epoxy but not ground or polished. Reflected light, profilometer, and CL images were used to select homogeneous crystal faces. The outermost parts of 12-15 grains each from 12 plutons were analyzed consecutively for O and U-Pb isotope ratios, and trace element concentrations using an ion microprobe. The grains were then ground to half-thickness and O, U-Pb, and trace elements were measured at the centers of previously analyzed grains. The final step was Hf isotopic analysis by LA-ICP-MS which ablated a hole completely through the remaining half-grains. Although measurements of these isotopes from the outsides and insides of selected zircons is a limited form of depth-profiling, it enables acquisition of a very large, more precise data set than typical depth profiling. For all samples, U-Pb ages of zircon from interior and exterior zones are not resolvably different at ± 1% (2-sigma). However, in several samples a few outliers were identified, suggesting that interior parts in some grains formed later, during or after growth of the exterior parts of other grains. Thus, zircon growth was not an episodic

  20. Geochemistry and U-Pb zircon geochronology of Late-Mesozoic lavas from Xishan, Beijing

    Institute of Scientific and Technical Information of China (English)

    YUAN; Honglin; LIU; Xiaoming; LIU; Yongsheng; GAO; Shan; LING; Wenli

    2006-01-01

    Zircon U-Pb dating by both SHRIMP and LA-ICP-MS and geochemical study of the Tiaojishan Formation and the Donglintai Formation from Xishan, Beijing, reveal that ages of upper lavas of Tiaojishan Formation and Middle of Donglintai Formation are 137.1±4.5 Ma(2σ) and 130-134 Ma, respectively. The fomer is slightly older than the latter and the age difference between these two formations is less than 5 Ma. These lines of evidence prove that the two volcanoes erupted within a short time. The age of the Tiaojishan Formation from Xishan, Beijing is distinctively different from that of the Chende Basin. This indicated that the ages of Tiaojishan lavas varied in different regions. The Tiaojishan Formation consists of typical adakite (SiO2=56%, Na2O = 3.99-6.17, Na2O/K2O = 2.2-3.1, Sr = 680-1074×10-6, Y = 13.2-16.3×10-6, Yb = 1.13-1.52×10-6, Sr/Y = 43-66), high-Mg adakite and high-Mg andesite (Mg# = 54-55). Features of continental crust of adakite from the Tiaojishan Formation and its syngeneric middle silicic vocanic rocks, such as typical Nd-Ta negative abnormality and Pb possive abnormality, indicate that these lavas are originated from partial melts of continental crust. These results suggest that the adakite from the Tiaojishan Formation of Xishan, Beijing derived from thickened eclogitic lower crust and lithosphere beneath the North China craton at mesozoic that was foundered into the aesthenosphere, and subsequenctly partially melted and interacted with mantle olivine during melts upward migration. The age of lavas from the Tiaojishan Formation restrained the foundation which should last at least until 137 Ma. Lavas of the Donglintai Formation are rhyolith and andesite with normal Mg# and thus they did not interact with the mantle. These lavas represent remobilized melts of lower crust material caused by mantle aesthenosphere upwelling migration induced by foundation.

  1. U-Pb dating of zircon from the Central Zone of the East Kunlun Orogen and its implications for tectonic evolution

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    LA-ICP-MS and SHRIMP U-Pb dating of zircons from orthogneisses and amphibolite from the Central Zone of the Kunlun Orogen is reported in this paper. One orthogneiss sample has metamorphic zircons yielding weighted average 206Pb/238U age of 517.0 +5.0/-6.0 Ma, and the other orthogneiss sample con- tains zircons with inherited magmatic cores giving three population 207Pb/206Pb ages of 955 Ma, 895 Ma and 657 Ma for the magmatic protolith, and metamorphic recrystallized rims with peak 206Pb/238U ages of 559 +12/?17 Ma and 516 ± 13 Ma. The amphibolite yielded three populations of weighted average 206Pb/238U age of 482.0 +10/?8.0 Ma, 516.2 ± 5.8 Ma and 549 ± 10 Ma for the metamorphic zircons. These dating results recorded the tectonothermal events that occurred in the early Paleozoic and the Pre- cambrian time. The records of the Cambrian magmatic-metamorphic event in the Qinling Orogen, the Altyn Tagh belt, north margin of the Qaidam Block and the Kunlun Orogen suggest that continental assembly probably occurred in the early evolutionary history of the Proto-Tethys.

  2. U-Pb dating of zircon from the Central Zone of the East Kunlun Orogen and its implications for tectonic evolution

    Institute of Scientific and Technical Information of China (English)

    CHEN NengSong; SUN Min; WANG QinYan; ZHANG KeXin; WAN YuSheng; CHEN HaiHong

    2008-01-01

    LA-ICP-MS and SHRIMP U-Pb dating of zircons from orthogneisses and amphibolite from the Central Zone of the Kunlun Orogen is reported in this paper. One orthogneiss sample has metamorphic zircons yielding weighted average 206Pb/238U age of 517.0 +5.0/-6.0 Ma,and the other orthogneiss sample contains zircons with inherited magmatic cores giving three population 207Pb/206Pb ages of 955 Ma,895 Ma and 657 Ma for the magmatic protolith,and metamorphic recrystallized rims with peak 206pb/238U ages of 559 +12/-17 Ma and 516 + 13 Ma. The amphibolite yielded three populations of weighted average 206Pb/238U age of 482.0 +10/-8.0 Ma,516.2 ± 5.8 Ma and 549 ± 10 Ma for the metamorphic zircons. These dating results recorded the tectonothermal events that occurred in the early Paleozoic and the Precambrian time. The records of the Cambrian magmatic-metamorphic event in the Qinling Orogen,the Altyn Tagh belt,north margin of the Qaidam Block and the Kunlun Orogen suggest that continental assembly probably occurred in the early evolutionary history of the Proto-Tethys.

  3. U-Pb zircon and CHIME monazite dating of granitoids and high-grade metamorphic rocks from the Eastern and Peninsular Thailand - A new report of Early Paleozoic granite

    Science.gov (United States)

    Kawakami, T.; Nakano, N.; Higashino, F.; Hokada, T.; Osanai, Y.; Yuhara, M.; Charusiri, P.; Kamikubo, H.; Yonemura, K.; Hirata, T.

    2014-07-01

    In order to understand the age and tectonic framework of Eastern to Peninsular Thailand from the viewpoint of basement (metamorphic and plutonic) geology, the LA-ICP-MS U-Pb zircon dating and the chemical Th-U-total Pb isochron method (CHIME) monazite dating were performed in the Khao Chao, Hub-Kapong to Pran Buri, and Khanom areas in Eastern to Peninsular Thailand. The LA-ICP-MS U-Pb zircon dating of the garnet-hornblende gneiss from the Khao Chao area gave 229 ± 3 Ma representing the crystallization age of the gabbro, and that of the garnet-biotite gneisses gave 193 ± 4 Ma representing the timing of an upper amphibolite facies metamorphism. The CHIME monazite dating of pelitic gneiss from the Khao Chao gneiss gave scattered result of 68 ± 22 Ma, due to low PbO content and rejuvenation of older monazite grains during another metamorphism in the Late Cretaceous to Tertiary time. The U-Pb ages of zircon from the Hua Hin gneissic granite in the Hub-Kapong to Pran Buri area scatter from 250 Ma to 170 Ma on the concordia. Granite crystallization was at 219 ± 2 Ma, followed by the sillimanite-grade regional metamorphism at 185 ± 2 Ma. Monazite in the pelitic gneiss from this area also preserves Early to Middle Jurassic metamorphism and rejuvenation by later contact metamorphism by non-foliated granite or by another fluid infiltration event in the Late Cretaceous to Tertiary time. The Khao Dat Fa granite from the Khanom area of Peninsular Thailand gave a U-Pb zircon age of 477 ± 7 Ma. This is the second oldest granite pluton ever reported from Thailand, and is a clear evidence for the Sibumasu block having a crystalline basement that was formed during the Pan-African Orogeny. The Khao Pret granite gives U-Pb zircon concordia age of 67.5 ± 1.3 Ma, which represents the timing of zircon crystallization from the granitic melt and accompanied sillimanite-grade contact metamorphism against surrounding metapelites and gneisses. Metamorphic rocks in the Doi Inthanon area

  4. Zircon U-Pb age of the Pescadero felsite: A late Cretaceous igneous event in the forearc, west-central California Coast Ranges

    Science.gov (United States)

    Ernst, W.G.; Martens, U.C.; McLaughlin, R.J.; Clark, J.C.; Moore, Diane E.

    2011-01-01

    Weathered felsite is associated with the late Campanian-Maastrichtian Pigeon Point Formation near Pescadero, California. Poorly exposed, its age and correlation are uncertain. Is it part of the Pigeon Point section west of the San Gregorio-Hosgri fault? Does it rest on Nacimiento block basement? Is it dextrally offset from the Oligocene Cambria Felsite, ~185 km to the southeast? Why is a calc-alkaline hypabyssal igneous rock intrusive into the outboard accretionary prism? To address these questions, we analyzed 43 oscillatory-zoned zircon crystals from three incipiently recrystallized pumpellyite ?? prehnite ?? laumontite-bearing Pescadero felsite samples by sensitive high-resolution ion microprobe-reverse geometry (SHRIMPRG) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) techniques. Thirty-three zircons gave late Mesozoic U-Pb ages, with single-grain values ranging from 81 to 167 Ma; ten have pre-Mesozoic, chiefl y Proterozoic ages. A group of the four youngest Pescadero zircons yielded an apparent maximum igneous age of ca. 86-90 Ma. Refl ecting broad age scatter and presence of partly digested sandstone inclusions, we interpret the rest of the zircons (perhaps all) as xenocrysts. Twenty-three zircons were separated and analyzed from two samples of the similar Cambria Felsite, yielding a unimodal 27 Ma U-Pb age. Clearly, the origin of the Upper Oligocene Cambria Felsite is different from that of the Upper Cretaceous Pescadero felsite; these rocks are not correlated, and do not constrain displacement along the San Gregorio-Hosgri fault. Peak ages differ slightly, but relative probability curves for Mesozoic and pre-Mesozoic Pescadero zircons compare well, for example, with abundant U-Pb age data for detrital zircons from Franciscan metaclastic strata ~100 km to the east in the Diablo Range- San Francisco Bay area, San Joaquin Great Valley Group turbidites, Upper Cretaceous Nacimiento block Franciscan strata, and Upper Cretaceous

  5. Comparison of SHRIMP U-Pb dating of monazite and zircon

    Institute of Scientific and Technical Information of China (English)

    WAN Yusheng; LIU Dunyi; JIAN Ping

    2004-01-01

    Monazite dating is an important technique in geochronological studies. However, monazite U-Pb dating by SHRIMP is much less popular than zircon in geochronological applications. This paper compares the results of SHRIMP U-Pb dating of monazites and zircons separated from two granite samples, indicating that monazite SHRIMP U-Pb dating at the Beijing SHRIMP Centre is feasible and provides identical results within error.

  6. Source and mode of the Permian Panjal Trap magmatism: Evidence from zircon U-Pb and Hf isotopes and trace element data from the Himalayan ultrahigh-pressure rocks

    Science.gov (United States)

    Rehman, Hafiz Ur; Lee, Hao-Yang; Chung, Sun-Lin; Khan, Tahseenullah; O'Brien, Patrick J.; Yamamoto, Hiroshi

    2016-09-01

    We present an integrated study of LA-ICP-MS U-Pb age, Hf isotopes, and trace element geochemistry of zircons from the Himalayan eclogites (mafic rocks) and their host gneisses (felsic rocks) from the Kaghan Valley in Pakistan in order to understand the source and mode of their magmatic protoliths and the effect of metamorphism. Zircons from the so-called Group I (high-pressure) eclogites yielded U-Pb mean ages of 259 ± 10 Ma (MSWD = 0.74), whereas those of Group II (ultrahigh-pressure) eclogites yielded 48 ± 3 Ma (MSWD = 0.71). In felsic gneisses the central or core domains of zircons yielded ages similar to those from Group I eclogites but zircon overgrowth domains yielded 47 ± 1 Ma (MSWD = 1.9). Trace element data suggest a magmatic origin for Group I-derived (having Th/U ratios: > 0.5) and metamorphic origin for Group II-derived (Th/U rocks (Panjal Traps) with almost no contribution from the ancient crustal material. The similar ƐHf(t) values, identical protolith ages and trace element compositions of zircons in felsic (granites or rhyolites) and mafic (basalt and dolerite) rocks attest to a bimodal magmatism accounting for the Panjal Traps during the Permian. Later, during India-Asia collision in Eocene times, both the felsic and mafic lithologies were subducted to mantle-depths (> 90 km: coesite-stable) and experienced ultrahigh-pressure metamorphism before their final exhumation.

  7. U-Pb detrital zircon age patterns of Cenozoic clastic sedimentary rocks in Trinidad and its implications

    Science.gov (United States)

    Xie, Xiangyang; Mann, Paul

    2014-06-01

    The Cenozoic evolution of northern South America can be simplified as a diachronous, west-to-east change from north-facing passive margin, to active convergence and transcurrent plate margin. As the current eastern end of the Caribbean-South America plate boundary, the Trinidad area records the most recent tectonic regime transition. Documenting the provenance of Cenozoic clastic rocks in Trinidad provides insights into the spatial and temporal relationships between mountain range uplifting, sediment dispersal, and drainage system development along the eastern end of the Caribbean-South American plate boundary. Four Eocene to Pliocene age outcropping sandstone samples were collected from Trinidad and 545 detrital zircon grains were analyzed using the U-Pb LA-ICP-MS method. A total of 404 analyses with less than 10% discordance were used for the final interpretation. Results show that the age distribution of the Eocene to the Early Oligocene samples is very restricted and dominated by Precambrian age grains with age peaks at ~ 1400 Ma, ~ 1800 Ma, and ~ 2000 Ma, typically derived from the Guyana Shield. In contrast, the Late Oligocene and younger samples show much broader and mixed age distribution that includes Mesozoic, Paleozoic, and Precambrian peaks. This age shift was interpreted as arriving of the Great Caribbean Arc and oblique collision between the South America and Caribbean plates. Continuing collision uplifted the Andes belts to the west. The Eastern Cordillera of Colombia, the Merida Andes, and the northern Venezuela coastal ranges then became the second primary sources. Offshore sedimentation switched from the passive margin with multiple small drainage systems to the active convergent and transcurrent plate margin with a single large river-dominated delivery system.

  8. Middle Permian Seamount from Xiahe Area, Gansu Province, Northwest China: Zircon U-Pb Age, Biostratigraphy and Tectonic Implications

    Institute of Scientific and Technical Information of China (English)

    Kou Xiaohu; Zhang Kexin; Zhu Yunhai; Chen Zhongqiang; Lin Qixiang; Chen Fenning; Huang Jinyuan

    2009-01-01

    The well-preserved seamount buildups are documented from the northwestern Qinling (秦岭) orogenic belts, Northwest China. The study sections are located in the Ganjia (甘加) area of the Xiahe (夏河) County, Gansu (甘肃) Province. The dark basalt and overlying massive reef carbonate characterize the Xiahe seamount buildup. Basalts are dominated by the olivine type of rocks and bear distinct porphyritic textures, and fumarole and amygdaloidal structures. The basaits are dominated by SiO2(up to 48.49 wt.%-52.29 wt.%) followed by (Na2O+ K2O) (3.80 wt.%-4.96 wt.%) and TiO2 (2.04 wt.%-2.52 wt.%). They are featured by considerably high content of Ti. The tholeilteseries rocks dominate the basalts, while calc-alkali-series rocks are also present. The REE of the basalts shows the LREE-enrichment type with distinct positive Eu abnormal. The trace elements of the basalts are characterized by the lack of P and high content of Ti. These geochemical signals suggest that the Xiahe basalts were formed in an ocean-island setting. The LA ICP-MS zircon U-Pb age of the basalts is 267.6±5 Ma, which is reinforced by the presnce of the fusuHnid Neoschwagerina Zone of the Wordian (Middle Permian) in the limestone interbeds of the basalts. Integration of petrological and geochemical studies of seamount basaits and lateral correlation of seamount buildups reveals that the Qinling-qilian-Kunlun orogenic belts were probably the archipelagtc oceans during the Permian.

  9. Zircon U-Pb ages of olivine pyroxenite xenolith from Hannuoba:Links between the 97-158 Ma basaltic under-plating and granulite-facies metamorphism

    Institute of Scientific and Technical Information of China (English)

    LIU Yongsheng; YUAN Honglin; GAO Shan; HU Zhaochu; WANG Xuance; LIU Xiaoming; LIN Wenli

    2004-01-01

    U-Pb zircon dating by LA-ICP-MS and SHRIMP for one olivine pyroxenite yields complex age populations including Mesozoic ages of 97-158 Ma and 228 ±8.7 Ma, Early Paleozoic ages of 418-427 Ma, Paleoproterozoic age of 1844±13 Ma, Neoarchean age of 2541 ± 54 Ma and middle Archean age of 3123 ± 4.4 Ma. The 97-158 Ma and 228 ± 8.7 Ma zircons show typical igneous oscillatory zonation in CL images, suggesting two episodes of magmatic events. Overlapping of the 97-158 Ma ages with that of granulite xenoliths indicates that the Mesozoic granulite-facies metamorphism was induced by heating from the basaltic underplating at the base of the lower crust. Both processes lasted at least from about 158 to 97 Ma. Ages of 418-427 Ma could be records of the subduction of Mongolia oceanic crust under the North China craton. Ages of 1.84 Ga,2.54 Ga and 3.12 Ga correspond to the three important crust-mantle evolutionary events in the North China craton,and imply preservation of Precambrian lower crust in the present-day lower crust.

  10. U-Pb ages related to uranium mineralization of Lagoa Real, Bahia - Brazil: tectonic implications

    Energy Technology Data Exchange (ETDEWEB)

    Chaves, Alexandre O.; Rios, Francisco J.; Oliveira, Lucilia A.R.; Alves, James V.; Fuzikawa, Kazuo; Neves, Jose M.C.; Chaves, Adriana M.D.V.; Prates, Sonia P. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)]. E-mail: aoc@cdtn.br; Tubrett, Michael [Memorial University of Newfoundland, NL (Canada). Inco Innovation Centre. MicroAnalysis Facility; Matos, Evando C. [Industrias Nucleares do Brasil S.A. (INB), Rio de Janeiro, RJ (Brazil)

    2007-07-01

    The uranium from Lagoa Real (Bahia/Brazil) is associated with syenitic magmatism (1904 {+-}44 Ma minimum age from upper intercept of zircon U-Pb discordia by LA-ICP-MS) belonging to a mafic/ felsic lithologic association linked to the final stages of 2.05-1.80 Ga Orosirian Orogeny, which acted in the Paramirim Block. These syenitic rocks are rich not only in albite, but also in U-rich titanite (source of uranium). In association with the development of the Orosirian ductile shear zones, the syenites were crystallized and deformed. The metamorphic reactions, which include intense recrystallization of magmatic minerals, led uraninite to precipitate (1868 {+-} 69 Ma; U-Pb by LA-ICP MS) under Redox control. A second population of uraninites was also generated by shear zones reactivation during 0.6-0.5 Ga Brasiliano Orogeny (605 {+-} 170 Ma; U-Pb by LA-ICP-MS). The geotectonic implications are: a) the importance of the Orosirian event in the Paramirim Block during paleoproterozoic Sao Francisco/Congo Craton edification and b) the influence of the Brasiliano event in the Paramirim Block during the West-Gondwana assembly processes, indicated by the 605 {+-} 170 Ma uraninite (second population) age and by the 483 {+-} 100 Ma lower intercept of the metamorphosed syenite U-Pb discordia. (author)

  11. LA-ICP-MS of magnetite: Methods and reference materials

    Science.gov (United States)

    Nadoll, P.; Koenig, A.E.

    2011-01-01

    Magnetite (Fe3O4) is a common accessory mineral in many geologic settings. Its variable geochemistry makes it a powerful petrogenetic indicator. Electron microprobe (EMPA) analyses are commonly used to examine major and minor element contents in magnetite. Laser ablation ICP-MS (LA-ICP-MS) is applicable to trace element analyses of magnetite but has not been widely employed to examine compositional variations. We tested the applicability of the NIST SRM 610, the USGS GSE-1G, and the NIST SRM 2782 reference materials (RMs) as external standards and developed a reliable method for LA-ICP-MS analysis of magnetite. LA-ICP-MS analyses were carried out on well characterized magnetite samples with a 193 nm, Excimer, ArF LA system. Although matrix-matched RMs are sometimes important for calibration and normalization of LA-ICP-MS data, we demonstrate that glass RMs can produce accurate results for LA-ICP-MS analyses of magnetite. Cross-comparison between the NIST SRM 610 and USGS GSE-1G indicates good agreement for magnetite minor and trace element data calibrated with either of these RMs. Many elements show a sufficiently good match between the LA-ICP-MS and the EMPA data; for example, Ti and V show a close to linear relationship with correlation coefficients, R2 of 0.79 and 0.85 respectively. ?? 2011 The Royal Society of Chemistry.

  12. Mesoproterozoic island arc magmatism along the south-eastern margin of the Indian Plate: Evidence from geochemistry and zircon U-Pb ages of mafic plutonic complexes

    Science.gov (United States)

    Subramanyam, K. S. V.; Santosh, M.; Yang, Qiong-Yan; Zhang, Ze-ming; Balaram, V.; Reddy, U. V. B.

    2016-11-01

    The Prakasam Igneous Province within the Nellore Schist Belt (NSB) preserves important imprints of mafic magmatism along the south-eastern margin of the Indian plate. Here we report petrology, geochemistry and zircon U-Pb age data from three gabbro plutons namely Purimetla, Kanigiri and P C Palle which intruded into the high grade rocks of the region. LA-ICP-MS U-Pb data on zircons from the three plutons reveal prominent late Mesoproterozoic ages of 1334 ± 15 Ma, 1338 ± 27 Ma and 1251.2 ± 9.4 Ma. The cumulative 207Pb/206Pb mean age of 1315 ± 11 Ma is interpreted to represent the timing of mafic magmatism in the Prakasam Igneous Province. These rocks show adcumulus to mesocumulus and poikilitic textures indicating fractional crystallization of plagioclase and clinopyroxenes in the Purimetla pluton whereas the Kanigiri and P C Palle intrusions possess hornblende and biotite suggesting the role of water during partial melting. The rocks show LREE enrichment (∑LREE/∑HREE = 2.2-15.0), marked Eu-anomalies (Eu/Eu∗ = 0.8-2.2) and fractionated patterns (LaN/YbN = 3-79). Primitive mantle normalised trace element spider diagrams indicate subduction modified arc signatures with LILE enrichment and depletion of Nb, Ti and Zr relative to Th and La. Tectonic discrimination diagrams show arc magmatic affinities for the three gabbro plutons consistent with subduction zone setting. We propose a tectonic model involving intra oceanic island arc accretion during late Mesoproterozoic along the eastern margin of the Indian continent.

  13. Tectono-magmatic evolution of the Chihuahua-Sinaloa border region in northern Mexico: Insights from zircon-apatite U-Pb geochronology, zircon Hf isotope composition and geochemistry of granodiorite intrusions

    Science.gov (United States)

    Mahar, Munazzam Ali; Goodell, Philip C.; Feinstein, Michael Nicholas

    2016-11-01

    We present the whole-rock geochemistry, LA-ICP-MS zircon-apatite U-Pb ages and zircon Hf isotope composition of the granodioritic plutons at the southwestern boundary of Chihuahua with the states of Sinaloa and Sonora. These granodiorites are exposed in the north and south of the Rio El Fuerte in southwest Chihuahua and northern Sinaloa. The magmatism spans over a time period of 37 Ma from 90 to 53 Ma. Zircons are exclusively magmatic with strong oscillatory zoning. No inheritance of any age has been observed. Our new U-Pb dating ( 250 analyses) does not support the involvement of older basement lithologies in the generation of the granitic magmas. The U-Pb apatite ages from granodiorites in southwest Chihuahua vary from 52 to 70 Ma. These apatite ages are 1 to 20 Ma younger than the corresponding zircon U-Pb crystallization ages, suggesting variable cooling rates from very fast to 15 °C/Ma ( 800 °C to 500 °C) and shallow to moderate emplacement depths. In contrast, U-Pb apatite ages from the Sinaloa batholith are restricted from 64 to 61 Ma and are indistinguishable from the zircon U-Pb ages range from 67 to 60 Ma within the error, indicating rapid cooling and very shallow emplacement. However, one sample from El Realito showed a larger difference of 20 Ma in zircon-apatite age pair: zircon 80 ± 0.8 Ma and apatite 60.6 ± 4 Ma, suggesting a slower cooling rate of 15 °C/Ma. The weighted mean initial εHf (t) isotope composition (2σ) of granodiorites varies from + 1.8 to + 5.2. The radiogenic Hf isotope composition coupled with previous Sr-Nd isotope data demonstrates a significant shift from multiple crustal sources in the Sonoran batholithic belt to the predominant contribution of the mantle-derived magmas in the southwest Chihuahua and northern Sinaloa. Based on U-Pb ages, the absence of inheritance, typical high Th/U ratio and radiogenic Hf isotope composition, we suggest that the Late Cretaceous-Paleogene magmatic rocks in this region are not derived from

  14. U-Pb Dating of Zircons and Phosphates in Lunar Meteorites, Acapulcoites and Angrites

    Science.gov (United States)

    Zhou, Q.; Zeigler, R. A.; Yin, Q. Z.; Korotev, R. L.; Joliff, B. L.; Amelin, Y.; Marti, K.; Wu, F. Y.; Li, X. H.; Li, Q. L.; Lin, Y. T.; Liu, Y.; Tang, G. Q.

    2012-01-01

    Zircon U-Pb geochronology has made a great contribution to the timing of magmatism in the early Solar System [1-3]. Ca phosphates are another group of common accessory minerals in meteorites with great potential for U-Pb geochronology. Compared to zircons, the lower closure temperatures of the U-Pb system for apatite and merrillite (the most common phosphates in achondrites) makes them susceptible to resetting during thermal metamorphism. The different closure temperatures of the U-Pb system for zircon and apatite provide us an opportunity to discover the evolutionary history of meteoritic parent bodies, such as the crystallization ages of magmatism, as well as later impact events and thermal metamorphism. We have developed techniques using the Cameca IMS-1280 ion microprobe to date both zircon and phosphate grains in meteorites. Here we report U-Pb dating results for zircons and phosphates from lunar meteorites Dhofar 1442 and SaU 169. To test and verify the reliability of the newly developed phosphate dating technique, two additional meteorites, Acapulco, obtained from Acapulco consortium, and angrite NWA 4590 were also selected for this study as both have precisely known phosphate U-Pb ages by TIMS [4,5]. Both meteorites are from very fast cooled parent bodies with no sign of resetting [4,5], satisfying a necessity for precise dating.

  15. Genesis of zircon and its constraints on interpretation of U-Pb age

    Institute of Scientific and Technical Information of China (English)

    WU Yuanbao; ZHENG Yongfei

    2004-01-01

    Zircon U-Pb dating is the most commonly used method for isotopic geochronology. However, it has been a difficult issue when relating zircon U-Pb ages to metamorphic conditions in complex metamorphic rocks. Much progress has been made in the past decade with respect to the genesis of zircon and its constraints on interpretation of U-Pb age. Three methods have been proposed to link zircon U-Ph age to metamorphic conditions: ( I ) internal structure; (ii)trace element feature; (iii) mineral inclusion composition.Magmatic zircon shows typical oscillatory zoning and/or sector zoning, whereas metamorphic zircon has internal structures such as no zoned, weakly zoned, cloudy zoned,sector zoned, planar zoned, and patched zoned ones. Zircons formed in different geological environments generally have characteristic internal structures. Magmatic zircons from different rock types have variable trace element abundances,with a general trend of increasing trace element abundances in zircons from ultramafic through mafic to granitic rocks.Zircons formed under different metamorphic conditions have different trace element characteristics that can be used to relate their formation to metamorphic conditions. It is an effective way to relate zircon growth to certain P-T conditions by studying the trace element partitioning between coexisting metamorphic zircon and garnet in high-grade metamorphic rocks containing both zircon and garnet. Primary mineral inclusions in zircon can also provide unambiguous constraints on its formation conditions. Therefore,interpretation of zircon U-Pb ages can be constrained by its internal structure, trace element composition, mineral inclusion and so on.

  16. Neoproterozoic granitic magmatism along the Ailao Shan-Red River belt: U-Pb zircon geochronology, Lu-Hf isotopes and tectonic implications

    Science.gov (United States)

    Chen, Xiaoyu; Liu, Junlai; Qi, Yinchuan; Fan, Wenkui; Burg, Jean-Pierre

    2017-04-01

    The Neoproterozoic tectonic characteristics of the high grade metamorphic massifs along the Ailao Shan-Red River belt are debated. Controversies are on 1) whether the massifs were parts of the Yangtze block to the northeast or 2) parts of the Indochina block to the southwest and 3) the magmatic rocks represent arc magmatism or rifting linked to break-up of the Rodinia supercontinent. This study presents new and precise LA-ICP-MS U-Pb age dating and geochemical and Hf isotopic analyses of granitic intrusions along the Ailao Shan-Red River belt in an attempt to elucidate the Neoproterozoic magmatic evolution of this belt. In general, zircon U-Pb ages of the studied granitic rocks are between 804 and 724Ma, with a weighted mean of ca. 770 Ma, thus confirming Neoproterozoic magmatism. All samples plot into the peraluminous domain, indicating a major crustal resource. In consistency with these conclusions, most of the Neoproterozoic granitoids show negative ɛHf (t) values near the chondrite line. A few samples possess low positiveɛ Hf (t) values, being signatures of mantle sources. It is therefore concluded that the Neoproterozoic magmatism along the ASRR belt originated from mantle sources with important contributions through anatexis of ancient lower crust. Discrimination diagrams of tectonic settings suggest continental arc magmatism. Neoproterozoic magmatism is widely reported along the margins of the Yangtze block, especially in the northern margin. However, there are fewer reports about Neoproterozoic magmatic activity along the southern and southwestern margins. The geochronology spectrum and geochemisty of the studied Neoproterozoic granitic rocks are similar to those along the western margin of the Yangtze block. The present study, combined with previous results, suggests that oceanic subduction contributed to the generation of the arc magmatisms along the western and southwestern margin of the Yangtze plate and along the ASRR belt (as part of the

  17. Brittle-ductile deformation effects on zircon crystal-chemistry and U-Pb ages: an example from the Finero Mafic Complex (Ivrea-Verbano Zone, western Alps)

    Science.gov (United States)

    Langone, Antonio; José Alberto, Padrón-Navarta; Zanetti, Alberto; Mazzucchelli, Maurizio; Tiepolo, Massimo; Giovanardi, Tommaso; Bonazzi, Mattia

    2016-04-01

    A detailed structural, geochemical and geochronological survey was performed on zircon grains from a leucocratic dioritic dyke discordantly intruded within meta-diorites/gabbros forming the External Gabbro unit of the Finero Mafic Complex. This latter is nowadays exposed as part of a near complete crustal section spanning from mantle rocks to upper crustal metasediments (Val Cannobina, Ivrea-Verbano Zone, Italy). The leucocratic dyke consists mainly of plagioclase (An18-24Ab79-82Or0.3-0.7) with subordinate amounts of biotite, spinel, zircon and corundum. Both the leucocratic dyke and the surrounding meta-diorites show evidence of ductile deformation occurred under amphibolite-facies conditions. Zircon grains (up to 2 mm in length) occur mainly as euhedral grains surrounded by fine grained plagioclase-dominated matrix and pressure shadows, typically filled by oxides. Fractures and cracks within zircon are common and can be associated with grain displacement or they can be filled by secondary minerals (oxides and chlorite). Cathodoluminescence (CL) images show that zircon grains have internal features typical of magmatic growth, but with local disturbances. However EBSD maps on two selected zircon grains revealed a profuse mosaic texture resulting in an internal misorientation of ca. 10o. The majority of the domains of the mosaic texture are related to parting and fractures, but some domains show no clear relation with brittle features. Rotation angles related to the mosaic texture are not crystallographically controlled. In addition, one of the analysed zircons shows clear evidence of plastic deformation at one of its corners due to indentation. Plastic deformation results in gradual misorientations of up to 12o, which are crystallographically controlled. Trace elements and U-Pb analyses were carried out by LA-ICP-MS directly on petrographic thin sections and designed to cover the entire exposed surface of selected grains. Such investigations revealed a strong

  18. Geochemistry, zircon U-Pb dating and Hf isotopies composition of Paleozoic granitoids in Jinchuan, NW China: Constraints on their petrogenesis, source characteristics and tectonic implication

    Science.gov (United States)

    Zeng, Renyu; Lai, Jianqing; Mao, Xiancheng; Li, Bin; Ju, Peijiao; Tao, Shilong

    2016-05-01

    Granitoids are widely distributed in Jinchuan at the southwestern margin of the North China plate, which is also an important area of mineral deposits. The research subject of this article are two Paleozoic granitoids, a cataclastic syenogranite and a granodiorite porphyry. This study presents whole rock geochemistry and zircon U-Pb-Hf isotope data for the two granitoids to determine their petrogenesis, source characteristics and tectonic significance. The cataclastic syenogranite is characterized by metaluminous composition with high potassium, and LaN/YbN from 39 to 48. The composition with strong negative Eu anomalies and Zircon saturation temperatures (TZr) from 947 to 1072 °C classify this intrusion as an A-type granite. The granodiorite porphyry is metaluminous with high sodium, sub-alkaline, LaN/YbN ratios from 27 to 32. These I-type intrusions have no Eu anomalies and TZr ranges from 818 to 845 °C. Both the cataclastic syenogranite and granodiorite porphyry show enrichment of LREE and LILE and depletion of HREE and HFSE, except Hf and Zr. Using single zircon LA-ICP-MS U-Pb dating, the emplacement age of the cataclastic syenogranite and granodiorite porphyry are determined at 433.4 ± 3.7 Ma and 361.7 ± 4.6 Ma, respectively. Zircons from the cataclastic syenogranits have uniform negative εHf(t) values (-11 ± 0.5 to -9 ± 0.5), implying the involvement of an old Palaeoproterozoic crustal source in magma genesis. The zircons from the granodiorite porphyry have εHf(t) values that range from -8 ± 1.0 to +10 ± 0.6, suggesting heterogeneous source materials involving both juvenile and ancient crust reworked crustal components. Based on the geological significance of granites at the southwestern margin of the North China plate, the closure of the North Qilian Ocean occurred at ∼444 Ma. Geochemical features suggest that the cataclastic syenogranite and granodiorite porphyry formed in an intraplate extensional and compressional setting, respectively. Hence

  19. Geochemistry and U-Pb zircon geochronology of the pegmatites in Ede area, southwestern Nigeria: A newly discovered oldest Pan African rock in southwestern Nigeria

    Science.gov (United States)

    Adetunji, A.; Olarewaju, V. O.; Ocan, O. O.; Ganev, V. Y.; Macheva, L.

    2016-03-01

    Field and petrographic studies, whole rock geochemistry and in-situ LA-ICP-MS geochemical and isotopic U-Pb measurements on zircons have been performed on granitic pegmatites of Ede area, southwestern Nigeria with a view to characterize them, determining their mineralization potentials, petrogenetic attributes and emplacement age. The pegmatites are hosted by migmatite gneiss complex, biotite-muscovite schist and associated quartzite. The textural and mineralogical characteristics of these pegmatites indicate the occurrence of two main varieties, namely, muscovite pegmatite and garnet pegmatite. Of less importance are inclusions and pods of graphic granite, quartz-microcline aplitic and pegmatitic bodies. At the present level of erosion, the parent igneous rocks of the pegmatites are not exposed. The two dominant pegmatite varieties show slightly different chemical peculiarities but similar peraluminous character. The average K/Rb ratios of 165 and 163, respectively, for muscovite and garnet pegmatites combined with other trace element compositions are indicative of affinity to muscovite class of pegmatite which are generally not promising for rare elements mineralization. However, the unusually high concentration of bismuth in the zircons indicates Bi mineralization in the area which can either be in the pegmatites or host rocks. The Nb/Ta ratios for both muscovite and garnet pegmatites range from 0.7 to 15.2 and 1.0 to 14.8, respectively. These Nb/Ta ratios and Eu anomalies are statistically similar for both pegmatites. These probably indicate the pegmatites crystallized from a common source but separated into crystallization paths that produced different pegmatite varieties through liquid-liquid immiscibity mechanism. In-situ measurements of REE, P, Y, Nb, Hf, Ta, Bi, Th and U of individual zircon grains show the existence of two chemically and texturally different domains which are indicative of alteration that may be due to interface-coupled dissolution

  20. Combined U Pb and Hf isotope LA-(MC-)ICP-MS analyses of detrital zircons: Comparison with SHRIMP and new constraints for the provenance and age of an Armorican metasediment in Central Germany

    Science.gov (United States)

    Gerdes, Axel; Zeh, Armin

    2006-09-01

    Uranium-lead ages obtained by LA-ICP-MS analyses of zircon cores from a high-grade Armorican metasediment from the Mid-German Crystalline Rise, Central Germany, yield results which are identical to, but more precise than those previously obtained by SHRIMP dating. This is mainly due to the fact that SHRIMP analyses are more sensitive than LA-ICP-MS analyses to common Pb contamination on the surface of the grain mount. The new U-Pb ages, in combination with in-situ Hf isotope analyses of zircon, provide the first evidence that detrital zircons within Armorican sediments crystallized in both juvenile and evolved magmatic rocks during the Archaean at 2.7-2.9 Ga, the Palaeoproterozoic at 1.8-2.1 Ga, and the Neoproterozoic/Early Palaeozoic at 500-720 Ma. In addition, zircons were formed at ca. 1.0 Ga by remelting of Palaeoproterozoic crust during the Grenville orogeny. The U-Pb dataset shows an age gap between 1.8 and 1.0 Ga, which is characteristic of Armorican sediments, and indicates that the metasediment protolith is younger than Late Cambrian. In addition, the data support previous conclusions that sediments constituting the Armorican terrane assemblage were derived from three crustal sources. Dominant sources were the Avalonian-Cadomian belt (ca. 45%), situated at the northern margin of Gondwana during the Neoproterozoic, and the West-African and/or eastern Amazonian cratons (ca. 50%). The Grenville belt was a minor source (< 5%). Variation of ɛHf( t) values of the Neoproterozoic/Early Paleozoic zircons indicates two periods of increased juvenile magma formation, one at 595-575 Ma and a second at 515-500 Ma. The older event is coeval with the formation of the Avalonian-Cadomian magmatic arc, whereas the younger event can be related to the break-up of the northern Gondwana margin in Cambrian/Ordovician times. In between, at around 545 Ma, only recycling of older crustal material took place.

  1. Permian volcanisms in eastern and southeastern margins of the Jiamusi Massif, northeastern China: zircon U-Pb chronology, geochemistry and its tectonic implications

    Institute of Scientific and Technical Information of China (English)

    MENG En; XU WenLiang; YANG DeBin; PEI FuPing; Yu Yang; Zhang XingZhou

    2008-01-01

    LA-ICP-MS zircon U-Pb dating and geochemical data for the Late Paleozoic volcanic rocks from eastern and southeastern margins of the Jiamusi Massif are presented to understand the regional tectonic evolution. Zircons from eight representative volcanic rocks are euhedral-subhedral in shape and dis-play striped absorption and fine-scale oscillatory growth zoning as well as high Th/U ratios (0.33-2.37), implying a magmatic origin. The dating results show that the Late Paleozoic volcanic rocks in the study area can be divided into two stages, I.e., the Early Permian (a weighted mean 206pb/238U age of 288 Ma) and the Middle Permian volcanisms (a weighted mean 206Pb/238U age of 268 Ma). The former is com-posed mainly of basalt, basaltic-andesite, andesite and minor dacite. They are characterized by low SiO2 contents, high Mg# (0.40-0.59), enrichment in Na (Na2O/K2O = 1.26-4.25) and light rare earth elements (LREEs), relative depletion in heavy rare earth elements (HREEs) and high field strength ele-ments (HFSEs), indicating that an active continental margin setting could exist in the eastern margin of the Jiamusi Massif in the Early Permian. The latter consists mainly of rhyolite and minor dacite with high SiO2 (77.23%-77.52%), low MgO (0.11%-0.14%), enrichment in K2O (Na2O/K2O ratios <0.80) and Rb, Th, U and depletion in Eu, Sr, P and Ti, implying a crust-derived origin. Therefore, it is proposed that the Middle Permian volcanic rocks could have formed under the collision of the Jiamusi and the Khanka Massifs.

  2. Disturbed Sr and Nd Isotope Systematics in Zircons With Concordant SHRIMP U-Pb Ages

    Science.gov (United States)

    Weaver, K. L.; Bennett, V. C.; Depaolo, D. J.; Mundil, R.

    2004-12-01

    Little is known about the Sr- and Nd-isotopic systematics of zircon. With slow diffusion rates and a high resistance to weathering, zircon should preserve accurate age information and initial Sr and Nd isotopic ratios. As a common accessory mineral, it could provide petrogenetic information for rocks that have been altered, weathered, or metamorphosed. We have investigated the Sm-Nd and Rb-Sr systematics of zircons from unmetamorphosed granitic rocks that have yielded concordant U-Pb SHRIMP (Sensitive High Resolution Ion Microprobe) ages and have depleted mantle signatures for Nd and Sr isotopes. Zircon populations from mantle-derived igneous rocks with ages of 0.1, 1.7, and 3.8 Ga were chosen for Sr and Nd isotopic analysis. Low concentrations (Sr, 4 to 8 ppm and Nd, 6 to 12 ppm) and small grain size necessitate the use of multigrain aliquots. Meaningful results can be obtained only if all of the zircons in the rock are a coherent population with homogeneous ages throughout and among grains. Zircon U-Pb ages were characterized using the SHRIMP RG, and trace element concentrations were measured by LA-ICPMS. The populations are homogeneous and the material ablated by the ion beam ( ˜~20 μ m spot size) shows little evidence of lead loss. Results on zircons of 100 Ma and 1700 Ma indicate that both the Rb-Sr and Sm-Nd systems have been severely disturbed. For the 1700 Ma granitic rocks from the Yavapai sequence of Arizona, zircon Sm-Nd apparent ages are ca. 1000 Ma! Leaching was used to remove contributions from adhering or included minerals, but leached residues that presumably most closely approximate the composition of the pure zircon (e.g. have high Sm/Nd) are no less disturbed than unleached samples. Despite the U-Pb SHRIMP ages indicating a closed system, the zircons have failed to preserve a reasonable age or initial isotopic composition for Sr and Nd, indicating that parts of the crystal might be severely affected by radiation damage resulting in disturbed

  3. Zircon U-Pb Age for the Tuff before the Luoping Biota and Its Geological Implication%罗平生物群下部凝灰岩锆石年龄及其地质意义

    Institute of Scientific and Technical Information of China (English)

    谢韬; 周长勇; 张启跃; 胡世学; 黄金元; 文芠; 丛峰

    2013-01-01

    二叠纪大灭绝之后到生物复苏经历了漫长的6Ma,大灭绝对生态环境的摧毁和之后环境动荡是使复苏时间推迟的根本原因.在罗平生物群(安尼期)下部发现的火山活动证据——凝灰岩(华南地区广泛分布的绿豆岩),其锆石LA-ICP-MS U-Pb年龄为246.6±1.4Ma,新的年龄数据对罗平生物群年龄下限提供了约束,为生物复苏与辐射提供了精确时间点,且为区域地层对比和划分提供了时间框架.%The full recovery from the end-Permian extinction event had a duration of about 6 Ma delayed Early Triassic recovery was longer than could be accounted for merely by the magnitude of the extinction and was best explained by continuing environmental stress. Crucial to models for the extinction and subsequent recovery is a precise chronology. A volcanic-ash horizon was found under the Luoping biota ( Anisian) layer. It is widely distributed in southern China and named the green-bean rock. Zircon LA-ICP-MS U-Pb age of 246. 6 ±1. 4Ma provides limit to the age of Luoping biota. It provides a precise point time for recovery and radiation, and provides a time frame for regional stratigraphic correlation.

  4. HFSE (High Field Strength Elements)-transport and U-Pb-Hf isotope homogenization mediated by Ca-bearing aqueous fluids at 2.04 Ga: Constraints from zircon, monazite, and garnet of the Venetia Klippe, Limpopo Belt, South Africa

    Science.gov (United States)

    Zeh, A.; Gerdes, A.

    2014-08-01

    Results from laser-ablation inductively-coupled-plasma mass spectrometry (LA-ICP-MS) and isotope dilution (ID) analyses of minerals and rocks from a single outcrop of the Venetia Klippe of the Limpopo Belt indicate that the U-Pb and Hf isotope system homogenized on the decimetre scale under amphibolite-facies conditions of ⩽645 ± 25 °C and ⩽7.0 ± 1.1 kbar, i.e. in the presence of an aqueous fluid phase. For a metabasite sample, homogenization is supported by isotope analyses of metamorphic zircon, garnet, and whole rock, which yield a six-point Lu-Hf isochron age of 2039.7 ± 3.4 Ma, with initial 176Hf/177Hf of 0.28126 ± 0.00001, and a U-Pb zircon age of 2042 ± 10 Ma. The occurrence of a few inherited magmatic zircon cores with ages up to 2705 Ma, and with significantly lower initial 176Hf/177Hf of 0.28112, however, indicate that homogenization was incomplete. For a chlorite-biotite-garnet schist isotope homogenization is reflected by within error identical zircon and monazite U-Pb ages of 2045 ± 10 Ma and 2041 ± 8 Ma, respectively, and by a zircon-garnet-whole rock Lu-Hf isochron age of 2083 ± 63 Ma, with an initial 176Hf/177Hf of 0.28140 ± 0.00003. Contemporaneous formation of metamorphic zircon, monazite and garnet in the chlorite schist is not only supported by the isotope data, but also by chlorite inclusions in all three minerals, and by inclusions of metamorphic zircon in garnet. The inclusion textures and the identical initial 176Hf/177Hf support the conclusion that metamorphic zircon grains precipitated from an aqueous fluid phase, after dissolution of zirconium-bearing phases elsewhere, followed by a major HFSE transport, and Hf isotope homogenization. This fluid perhaps was Ca-bearing, as is suggested by the fact that garnet in the schist sample is the only Ca-bearing phase, and that metamorphic monazite, dating the metamorphic peak, is partially replacement by apatite. The fact that the metamorphic zircon rims in the metabasite sample have

  5. Zircon U-Pb ages, Hf isotope data, and tectonic implications of Early-Middle Triassic granitoids in the Ailaoshan high-grade metamorphic belt of Southeast Tibet

    Science.gov (United States)

    Wu, Wenbin; Liu, Junlai; Chen, Xiaoyu; Zhang, Lisheng

    2017-04-01

    The Ailaoshan tectonic belt, where the effects of the Paleo-Tethyan ocean evolution and Indian-Eurasian plate collision are superimposed, is one of the most significant geological discontinuities in western Yunnan province of southeast Tibet. An Ailaoshan micro-block within the belt is bounded by the Ailaoshan suture zone to the west and the Red River Fault to the east, and consists of low- and high-grade metamorphic belts. Late Permian-Middle Triassic granitoids that are widely distributed to the west of the Ailaoshan suture zone and within the Ailaoshan micro-block may yield significant information on the Tethyan tectonic evolution of the Ailaoshan tectonic belt. This study reports new LA-ICP-MS zircon U-Pb geochronology and Hf isotope data of four granitoids from the Ailaoshan high-grade metamorphic belt. Zircon grains from the Yinjie granitoid do not have inherited cores and yield a weighted mean U-Pb age of 247.1 ± 2.0 Ma. The zircon ɛ Hf( t) values range from 7.8 to 12.1, and Hf model ages from 775 to 546 Ma, indicating that the granitoid was derived from juvenile crust. The rims of zircons from the Majie and Yuanjiang granitoids yield weighted mean U-Pb ages of 239.5 ± 1.8 and 237.9 ± 2.6 Ma, respectively, whereas the cores yield ages of 1608-352 Ma. The ɛ Hf( t) values of zircon rims range from -20.4 to -5.3, yielding Hf model ages from 2557 to 1606 Ma and suggesting that the source magma of the Majie and Yuanjiang granitoids was derived from ancient crust. An additional granitoid located near the Majie Village yields a zircon U-Pb age of 241.2 ± 1.0 Ma. Based on our geochronological and geochemical data, combined with geological observations, we propose that the Ailaoshan micro-block was derived from the western margin of the Yangtze block, and is comparable to the Zhongzan and Nam Co micro-blocks. The presence of late Permian mafic rocks with rift-related geochemical characteristics within the Ailaoshan micro-block, together with granitoids derived

  6. Zircon U-Pb ages, Hf isotope data, and tectonic implications of Early-Middle Triassic granitoids in the Ailaoshan high-grade metamorphic belt of Southeast Tibet

    Science.gov (United States)

    Wu, Wenbin; Liu, Junlai; Chen, Xiaoyu; Zhang, Lisheng

    2016-05-01

    The Ailaoshan tectonic belt, where the effects of the Paleo-Tethyan ocean evolution and Indian-Eurasian plate collision are superimposed, is one of the most significant geological discontinuities in western Yunnan province of southeast Tibet. An Ailaoshan micro-block within the belt is bounded by the Ailaoshan suture zone to the west and the Red River Fault to the east, and consists of low- and high-grade metamorphic belts. Late Permian-Middle Triassic granitoids that are widely distributed to the west of the Ailaoshan suture zone and within the Ailaoshan micro-block may yield significant information on the Tethyan tectonic evolution of the Ailaoshan tectonic belt. This study reports new LA-ICP-MS zircon U-Pb geochronology and Hf isotope data of four granitoids from the Ailaoshan high-grade metamorphic belt. Zircon grains from the Yinjie granitoid do not have inherited cores and yield a weighted mean U-Pb age of 247.1 ± 2.0 Ma. The zircon ɛ Hf(t) values range from 7.8 to 12.1, and Hf model ages from 775 to 546 Ma, indicating that the granitoid was derived from juvenile crust. The rims of zircons from the Majie and Yuanjiang granitoids yield weighted mean U-Pb ages of 239.5 ± 1.8 and 237.9 ± 2.6 Ma, respectively, whereas the cores yield ages of 1608-352 Ma. The ɛ Hf(t) values of zircon rims range from -20.4 to -5.3, yielding Hf model ages from 2557 to 1606 Ma and suggesting that the source magma of the Majie and Yuanjiang granitoids was derived from ancient crust. An additional granitoid located near the Majie Village yields a zircon U-Pb age of 241.2 ± 1.0 Ma. Based on our geochronological and geochemical data, combined with geological observations, we propose that the Ailaoshan micro-block was derived from the western margin of the Yangtze block, and is comparable to the Zhongzan and Nam Co micro-blocks. The presence of late Permian mafic rocks with rift-related geochemical characteristics within the Ailaoshan micro-block, together with granitoids derived

  7. U/Pb Dating of Zircon from the Suvasvesi Impact Structures, Finland

    Science.gov (United States)

    Schwarz, W. H.; Breutmann, G.; Schmitt, A. K.; Trieloff, M.; Ludwig, T.; Hanel, M.; Buchner, E.; Schmieder, M.; Pesonen, L. J.; Moilanen, J.

    2016-08-01

    The two Suvasvesi impact structures (Finland), both covered by lakes, forming an apparent crater doublet, were analysed by in-situ U/Pb dating of zircon grains, concluding that the two craters were formed in separate events, ~600 Ma apart.

  8. Middle Neoproterozoic (ca. 705-716 Ma) arc to rift transitional magmatism in the northern margin of the Yangtze Block: Constraints from geochemistry, zircon U-Pb geochronology and Hf isotopes

    Science.gov (United States)

    Wang, Ruirui; Xu, Zhiqin; Santosh, M.; Xu, Xianbing; Deng, Qi; Fu, Xuehai

    2017-09-01

    The South Qinling Belt in Central China is an important window to investigate the Neoproterozoic tectono-magmatic processes along the northern margin of the Yangtze Block. Here we present whole-rock geochemistry, zircon U-Pb geochronology and Lu-Hf isotopes of a suite of Middle Neoproterozoic intrusion from the Wudang Uplift in South Qinling. Zircon LA-ICP-MS U-Pb ages reveal that these rocks were formed at ca. 705-716 Ma. Geochemical features indicate that the felsic magmatic rocks are I-type granitoids, belong to calcic- to calc-alkaline series, and display marked negative Nb, Ta and Ti anomalies. Moreover, the enrichment of light rare earth elements (LREEs) and large ion lithophile elements (LILEs), combined with depletion of heavy rare earth elements (HREEs) support that these rocks have affinity to typical arc magmatic rocks formed in Andean-type active continental margins. The REE patterns are highly to moderately fractionated, with (La/Yb)N = 5.13-8.10 in meta-granites, and 2.32-2.35 in granodiorite. The granitoids have a wide range of zircon εHf(t) values (-29.91 to 14.76) and zircon Hf two-stage model ages (696-3482 Ma). We suggest that the ca. 705-716 Ma granitoids were sourced from different degrees of magma mixing between partial melting of the overlying mantle wedge triggered by hydrous fluids released from subducted materials and crustal melting. The hybrid magmas were emplaced in the shallow crust accompanied by assimilation and fractional crystallization (AFC). Both isotopic and geochemical data suggest that the ca. 705-716 Ma felsic magmatic rocks were formed along a continental arc. These rocks as well as the contemporary A-type granite may mark a transitional tectonic regime from continental arc to rifting, probably related to slab rollback during the oceanic subduction beneath the northern margin of Yangtze Block.

  9. Allanite from the El Muerto Pegmatite, Oaxaca, Mexico: A Potential New Standard for 232Th-208Pb Dating by LA-ICP-MS

    Science.gov (United States)

    Price, J.; Crowley, J. L.; Solari, L.; Prol-Ledesma, R.

    2012-12-01

    Allanite dating may be important to studies addressing tectonomagmatic evolution, provenance of monocyclic sediment, and mineral weathering. Obtaining accurate allanite ages by SIMS has been challenging and time-consuming due to the mineral's extreme chemical variability which often prevents finding adequately matrix-matched standards. Isotopic measurements by LA-ICP-MS minimize the need for standards of nearly identical composition to the unknown allanite being analyzed, and it is done relatively rapidly. Dating by LA-ICP-MS requires high quality standards for isotopic fractionation corrections. However, readily accessible and well characterized allanite standards are scarce. We investigated gemstone allanite from the El Muerto pegmatite, Oaxaca, Mexico, as a potential new geochronology standard for 232Th-208Pb allanite dating by LA-ICP-MS. Compositional homogeneity was thoroughly investigated by scanning and backscatter electron microscopy, cathodoluminescence, quantitative and qualitative energy dispersive x-ray spectroscopy, electron microprobe, and LA-ICP-MS. The possibility of metamictization was investigated by extensive X-ray diffraction analyses. The El Muerto allanite was U-Pb dated by ID-TIMS, with common Pb ratios determined from cogenetic K-feldspar by ID-TIMS and LA-MC-ICP-MS. Future work includes Th-Pb dating by ID-TIMS. The samples investigated are homogeneous with respect to major and trace elements. Major element compositional results are generally in agreement with published values, and no metamictization was identified despite the allanite being nearly 1 Ga. The only limitation of the El Muerto allanite is that it contains small, generally <100 μm, scarce inclusions of quartz, calciothorite, albite, calcite, and biotite. However, these grains are easily recognized and avoided during LA-ICP-MS analyses. Based on these results, the El Muerto allanite has the potential to serve as a standard for LA-ICP-MS dating.

  10. Large-scale displacement along the Altyn Tagh Fault (North Tibet) since its Eocene initiation: Insight from detrital zircon U-Pb geochronology and subsurface data

    Science.gov (United States)

    Cheng, Feng; Jolivet, Marc; Fu, Suotang; Zhang, Changhao; Zhang, Qiquan; Guo, Zhaojie

    2016-05-01

    Marking the northern boundary of the Tibetan plateau, the Altyn Tagh fault plays a crucial role in accommodating the Cenozoic crustal deformation affecting the plateau. However, its initiation time and amount of offset are still controversial despite being key information for the understanding of Tibet evolution. In this study, we present 1122 single LA-ICP-MS detrital zircon U-Pb ages obtained from 11 Mesozoic to Cenozoic sandstone samples, collected along two sections in the northwestern Qaidam basin (Eboliang and Huatugou). These data are combined with new 3D seismic reflection profiles to demonstrate that: (1) from the Paleocene to early Eocene, the Eboliang section was approximately located near the present position of Anxi, 360 ± 40 km southwest from its current location along the Altyn Tagh fault, and sediments were mainly derived from the Altyn Tagh Range. At the same period, the Huatugou section was approximately located near the present position of Tula, ca. 360 km southwest from its current location along the Altyn Tagh fault, and the Eastern Kunlun Range represented a significant sediment source. (2) Left-lateral strike-slip movement along the Altyn Tagh fault initiated during the early-middle Eocene, resulting in northeastward displacement of the two sections. (3) By early Miocene, the intensive deformation within the Altyn Tagh Range and northwestern Qaidam basin strongly modified the drainage system, preventing the materials derived from the Altyn Tagh Range to reach the Eboliang and the Huatugou sections. The post-Oligocene clastic material in the western Qaidam basin is generally derived from local sources and recycling of the deformed Paleocene to Oligocene strata. From these data, we suggest enhanced tectonic activity within the Altyn Tagh Range and northwestern Qaidam basin since Miocene time, and propose an early-middle Eocene initiation of left-lateral strike-slip faulting leading to a 360 ± 40 km offset along the Altyn Tagh fault.

  11. Petrogenesis of subvolcanic rocks from the Khunik prospecting area, south of Birjand, Iran: Geochemical, Sr-Nd isotopic and U-Pb zircon constraints

    Science.gov (United States)

    Samiee, Somayeh; Karimpour, Mohammad Hassan; Ghaderi, Majid; Haidarian Shahri, Mohammad Reza; Klöetzli, Urs; Santos, José Francisco

    2016-01-01

    The Khunik prospecting area is located 106 km south of Birjand in eastern Iran, and is considered as an epithermal gold prospecting area. The mineralization is related to subvolcanic rocks. There are several outcrops of subvolcanic intrusions in the area which intruded into Paleocene-Eocene volcanic rocks (andesite, trachy-andesite and pyroclastic rocks). Petrographic studies indicate that subvolcanic rocks consist mainly of diorite, monzonite, quartz-monzonite, monzodiorite and quartz-monzodiorite. Mineralogically, these rocks contain plagioclase, K-feldspar, amphibole, pyroxene, biotite and quartz. Geochemically, they have features typical of high-K calk-alkaline to shoshonitic and are metaluminous, and also belong to magnetite granitoid series (I-type). Primitive mantle normalized trace element spider diagrams display enrichment in LILE, such as Rb, Ba, and Cs, compared to HFSE. Chondrite-normalized REE plots show moderately LREE enriched patterns (7.45 < LaN/YbN < 10.54), and no significant Eu anomalies. Tectonic discrimination diagrams also show affinities with modern convergent margin magmas, suggesting that magmas of Khunik area formed in volcanic arc setting related to subduction of the oceanic crust under the Lut Block plate. The initial 87Sr/86Sr ratios (0.704196-0.704772) and εNdi values (+1.3 to +3.3) are compatible with an origin of the parental melts in a supra-subduction mantle wedge. Zircon U-Pb dating by LA-ICP-MS indicates the age of 38 ± 1 Ma (late Eocene) for subvolcanic units that are related to mineralization. A biotite granodiorite porphyry is the testimony of the youngest magmatic activity in the area, with an age of 31 ± 1 Ma (early Oligocene). The represented dates are interpreted as magmatic crystallization ages of subvolcanic intrusions.

  12. Early Paleozoic intracontinental orogeny in the Yunkai domain, South China Block: New insights from field observations, zircon U-Pb geochronological and geochemical investigations

    Science.gov (United States)

    Yan, Chaolei; Shu, Liangshu; Michel, Faure; Chen, Yan; Li, Cheng

    2017-01-01

    Debate on whether the Early Paleozoic tectono-magmatic event in South China is related to a subduction-collision or an intracontinental orogen has been lasted for decades within the geoscience community. This study deals with LA-ICP-MS zircon U-Pb ages, whole-rock chemistry, rare earth elements, trace elements and Hf isotopes from granitoid samples collected in the Yunkai domain in order to better constrain the Early Paleozoic tectonic evolution of the South China Block. The weighted mean 206Pb/238U ages for eight samples range from 426 Ma to 443 Ma, representing the crystallization ages of the magma. Fourteen samples were analyzed for geochemistry, all of which are characterized by a peraluminous signature with A/CNK values greater than 1.0. The REE geochemistry reveals enrichment in light rare earth element. LREE/HREE values range from 2.81 to 30.36 and (La/Yb)N vary from 1.23 to 55.14 (mean of 14 analyses is 14.69). All the samples exhibit distinct negative Ba, Sr and Nb anomalies and enrichment in Rb, Th, U and Pb. Hf isotopic analyses indicate negative εHf (t) values mainly ranging from - 3 to - 12, corresponding to two model age distributing from 1637 Ma to 2208 Ma. The geochemical analyses indicate that the Silurian granitic magmas in the Yunkai domain were derived from partial melting of crustal materials with little or no input of mantle source. These new data support the intracontinental subduction model already proposed to account for the Early Paleozoic tectonic, metamorphic and magmatic event of South China.

  13. U-Pb dating by zircon dissolution method using chemical abrasion

    Energy Technology Data Exchange (ETDEWEB)

    Takehara, Lucy, E-mail: lucytakehara@gmail.com.br [Servico Geologico do Brasil (CPRM), Brasilia, DF (Brazil); Chemale Junior, Farid [Universidade de Brasilia (UnB), Brasilia, DF (Brazil). Inst. de Geociencias. Lab. de Geocronologia; Hartmann, Leo A. [Universidade Federal do Rio Grande do Sul (UFRS), Porto Alegre, RS (Brazil). Inst. de Geociencias; Dussin, Ivo A.; Kawashita, Koji [Universidade de Sao Paulo (USP), SP, (Brazil). Centro de Pesquisa Geocronologicas

    2012-06-15

    Chemical abrasion was carried out on zircons grains of the Temora II standard for U-Pb dating prior to analyses using in situ Laser Ablation-Multi Collector Ion Coupled Plasma Mass Spectrometer (LA-ICPMS) followed by the Isotope Dissolution Thermal Ionization Mass Spectrometer (ID-TIMS) method. The proposed methodology was herein applied in order to reduce primarily the effects of secondary Pb loss, the presence of common lead and/or silicate impurities. Nine Temora II zircon grains were analyzed by the laser ablation method yielding an age of 418.3 +- 4.3 Ma. Zircon grains of a same population were separated for chemical abrasion before dissolution and mass spectrometry analyses. Six fractions of them were separated for isotope dissolution using {sup 235}U-{sup 205}Pb mixed spike after we have checked and assured the laboratory conditions of low blank values for total Pb of less than 2 pg/g. The obtained U-Pb zircon age by the ID-TIMS method was 415.7 +- 1.8 Ma (error 0.43 %) based on four successful determinations. The results are consistent with the published ages for the Temora diorite (Temora I - 416.75 +- 1.3 Ma; Temora II - 416.78 +- 0.33 Ma) and established as 416 +- 0.33 Ma. The technique is thus recommended for high precision U-Pb zircon analyses (error < 1 %), mainly for high resolution stratigraphic studies of Phanerozoic sequences. (author)

  14. Zircon U-Pb ages of the basement rocks beneath the Songliao Basin, NE China

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The basement of the Songliao Basin is mainly composed of slightly-metamorphosed or unmetamorphosed Paleozoic strata, granites and gneiss. Petrographical studies indicate that the gneiss was originally the granitic intrusions which were deformed in the later stage. One undeformed granitic rock sample gives a U-Pb age of (305±2) Ma, and the mylonitic granite yields a U-Pb age of (165±3) Ma. Both of the two samples contain no inherited zircon, which suggests that there is no large-scale Precambrian crystalline basement beneath the Songliao Basin.

  15. Petrography and U-Pb Zircon Geochronology of Geological Units of the Mesa de Cocodite, Península de Paraguaná, Venezuela

    Science.gov (United States)

    Mendi, D.; Baquero, M. L.; Oliveira, E. P.; Urbani, F.; Pinto, J.; Grande, S.; Valencia, V.

    2013-05-01

    Several continental crust units crop out in The Mesa de Cocodite, central Paraguaná Peninsula, Northwestern Venezuela, including a newly mapped quartz-feldspar gneiss that intruded the El Amparo Pluton, a major low-graded metamorphic unit of Permian age. It is unconformably overlying by Late Jurassic phyllites of the Pueblo Nuevo Formation. All these units are cross-cut by narrow dykes. This contribution focuses on the petrography and LA-ICP-MS U-Pb zircon dating of the igneous units, with the aim of constraining magmatism and its tectonic significance in the area. The quartz-feldspar gneiss consists of albite, bluish-smoked quartz, muscovite-chlorite, epidote and zircon. The enclosing El Amparo Pluton is typically a coarse-grained and thick-banded metagranodiorite, containing andesine, quartz, hornblende, epidote, K-feldspar, biotite, chlorite, titanite and zircon. The younger dykes consist of fine-grained, porphyritic hornblende diorites that contain numerous hornblende phenocrysts. The main minerals are andesine, hornblende, quartz, and chlorite. Accessory minerals include zircon, epidote and opaques. A felsic gneiss xenolith collected from the dykes contain quartz, K-feldspar, chlorite, epidote, albite and zircon. Zircon population in the quartz-feldspar gneiss displays a discordia trend, ranging in age from 1050-750 Ma but mostly around 950-900 Ma, which may represent a peak high-grade metamorphism in the area. The El Amparo Pluton provides a concordant Permian age (271.3±6.5 Ma), which is comparable with previous reported U-Pb ages in titanite. Because the porphyry dykes cross-cut all the units in the area, they should be post-Late Jurassic in Age; however, all dated zircons from the dykes are in the range of 1200-750 Ma. The absence of younger ages can be attributed to either formation during a relatively low temperature magmatic event, which generated very narrow younger zircon rims only and thus undetectable with the technique used, or a completely lack

  16. Precise U-Pb Zircon Dating of the Syenite Phase from the Ditrau Alkaline Igneous Complex

    Directory of Open Access Journals (Sweden)

    Pană Dinu

    2000-04-01

    Full Text Available The Ditrău igneous complex represents the largest alkaline intrusion in the Carpathian-Pannonian region consisting of a plethora of rock types formed by complicated magmatic and metasomatic processes. A detailed U-Pb zircon age study is currently underway and the results for the syenite intrusion phase is reported herein. The U-Pb zircon emplacement age of the syenite of 229.6 +1.7/-1.2 Ma documents the quasi-contemporaneous production and emplacement of the gabbro and syenite magmas. We suggest that the syenite and associated granite formed by crustal melting during the emplacement of the mantle derived gabbroic magma around 230 Ma. The thermal contact aureole produced by the Ditrău alkaline igneous complex constrains the main tectonism recorded by surrounding metamorphic lithotectonic assemblages to be pre-Ladinian.

  17. High-Precision U-Pb Zircon Dates as Benchmarks in Absolute Time

    Science.gov (United States)

    Schmitz, M. D.; Bowring, S. A.; Schoene, B.

    2003-12-01

    High-precision IDTIMS U-Pb zircon dates provide the most precise and accurate isotopic benchmarks in absolute time, due to the concordancy check of the paired U-Pb decay schemes, the precisely measured 235U and 238U decay constants, very high initial parent/daughter ratios, and the robust nature of zircon to loss or gain of U and Pb over geologic time. However, caveats to the use of such zircon dates include the accurate assessment and minimization of random and systematic errors in the analytical methods, and decay constant uncertainties. Unfortunately, there exists little consensus within the U-Pb geochronological community regarding an international zircon standard for the external assessment of interlaboratory reproducibility, while residual questions remain regarding the potential for systematic error in the single available high-precision counting experiment of the U decay constants1. Stringent criteria are imposed on candidates for zircon geochronology standards including the absence of inheritance and Pb-loss at both the single grain scale and the resolution of microbeam techniques. We present an example of the potential and limitations of a possible zircon standard, AS3, from the Duluth Complex, North American Midcontinent Rift2. New data for 27 single zircons are indistinguishable from prior results, with 207Pb/206Pb and upper intercept dates identical within error to a U-Pb concordia date of 1099.1+/-0.2 Ma (+/-1.2 Ma with systematic errors) based on 12 concordant and equivalent analyses. However, we must reiterate that a zircon population exhibiting consistent concordancy remains elusive, as AS3 and all Paleozoic and older standard candidates so far examined contain grains exhibiting Pb-loss, although rigorous selection and preparation of zircons through diamagnetic separation and aggressive abrasion can mitigate this phenomenon. The continued screening of candidate standards by both IDTIMS and SHRIMP techniques should be an organized, international

  18. A comparison of zircon U-Pb age results of the Red Clay sequence on the central Chinese Loess Plateau

    Science.gov (United States)

    Gong, Hujun; Nie, Junsheng; Wang, Zhao; Peng, Wenbin; Zhang, Rui; Zhang, Yunxiang

    2016-08-01

    Single grain zircon U-Pb geochronology has demonstrated great potentials in extracting tectonic and atmospheric circulation signal carried by aeolian, fluvial, and fluviolacustrine sediments. A routine in this sort of studies is analyzing 100-150 grains and then compares zircon U-Pb age spectra between the measured sample and the potential sources. Here we compared the zircon U-Pb age results of the late Miocene-Pliocene Red Clay sequence of two neighboring sites from the Chinese Loess Plateau where similar provenance signal is expected. Although the results from the 5.5 Ma sediment support this prediction, the results from the 3 Ma sediment at these two sites differ from each other significantly. These results emphasize the importance of increasing analysis number per sample and combining the zircon U-Pb geochronology with other provenance tools in order to get reliable provenance information.

  19. Sequence of Late Jurassic-Early Cretaceous magmatic-hydrothermal events in the Xiong'ershan region, Central China: An overview with new zircon U-Pb geochronology data on quartz porphyries

    Science.gov (United States)

    Deng, Jun; Gong, Qingjie; Wang, Changming; Carranza, Emmanuel John M.; Santosh, M.

    2014-01-01

    Recent investigations have revealed several large Au and Mo deposits in the Xiong'ershan region, Central China. Most quartz porphyries associated with the mineralization occur as dikes and apophyses, or as rubbles cemented in mineralized breccia pipes. Three types of quartz porphyries were sampled from the Leimengou Mo deposit, the Qiyugou Au deposit, and the Niutougou Au deposit. LA-ICP-MS zircon U-Pb analysis was performed in zircons from two quartz porphyries; the results yielded ages of 125.4 ± 0.77 Ma for Leimengou Mo deposit and 150.1 ± 1.1 Ma for Qiyugou Au deposit. The magma source of Leimengou quartz porphyry is similar to that of the mineralized cementing material in breccia pipes of the Qiyugou Au deposit, whereas the magma source of Qiyugou quartz porphyry is the same as that of quartz porphyries in Niutougou Au deposit. Based on the new U-Pb isotopic ages of granitic plutons reported in this study, together with the age data in the literature, we identify distinct magmatic pulses in the Xiong'ershan region at ca.160, 150, 143, 133, 125, and 115 Ma during the Late Jurassic-Early Cretaceous. The ages of Au and Mo mineralization coincide with the thermal events at about 115, 125, 133, and 143 Ma are considered to be co-eval with granitic magmatism. No mineralization ages of 150 and 160 Ma thermal events have been previously reported. Our study demonstrates Late Jurassic-Early Cretaceous multiple magmatic pulses and mineralization in the Xiong'ershan region.

  20. Ductile-brittle deformation effects on crystal-chemistry and U-Pb ages of magmatic and metasomatic zircons from a dyke of the Finero Mafic Complex (Ivrea-Verbano Zone, Italian Alps)

    Science.gov (United States)

    Langone, Antonio; Padrón-Navarta José, Alberto; Ji, Wei-Qiang; Zanetti, Alberto; Mazzucchelli, Maurizio; Tiepolo, Massimo; Giovanardi, Tommaso; Bonazzi, Mattia

    2017-07-01

    A detailed microstructural, geochemical and geochronological study was performed on zircon grains from plagioclase-rich dioritic dykes discordantly intruded within meta-diorites/gabbros forming the External Gabbro unit of the Finero Mafic Complex (Italian Alps). This unit is exposed as part of a near complete crustal section spanning from mantle rocks to upper crustal metasediments (Val Cannobina, Ivrea-Verbano Zone, Italy). The leucocratic dykes consist mainly of plagioclase (An18-24Ab79-82Or0.3-0.7) with subordinate amounts of biotite and spinel defining melanocratic layers. Zircon and corundum are common accessory phases. Both the dykes and the surrounding meta-diorites/gabbros show evidence of ductile deformation under amphibolite-facies conditions. Zircon grains/fragments (up to 2 mm in length) occur as porphyroclasts surrounded by fine-grained plagioclase within the leucocratic domains and may occur within the melanocratic layers completely or partially surrounded by biotite and spinels. Fractures are common within zircon, define networks and have associated displacements occasionally and/or they can be filled by secondary minerals. Cathodoluminescence (CL) images reveal that zircon grains from the leucocratic layers show relicts of primary magmatic (i.e. oscillatory and or sector) zoning generally related with the crystal shapes or crystallographic orientation, whereas those from the melanocratic domains do not. In both cases, zircon shows secondary CL features, i.e. mosaic-like textures, due to deformation. EBSD maps confirmed a profuse mosaic texture, resulting in an internal misorientation of ca. 10°, generally associated with fractures. Locally, zircon shows clear evidence of crystal-plastic deformation at the edges, with a gradual misorientations of up to 12°, suggesting an origin prior fragmentation. Trace elements and U-Pb analyses were carried out by LA-ICP-MS directly on petrographic thin sections. Such in situ investigations revealed a strong

  1. Zircon U-Pb age, Hf isotope and geochemistry of Carboniferous intrusions from the Langshan area, Inner Mongolia: Petrogenesis and tectonic implications

    Science.gov (United States)

    Liu, Min; Zhang, Da; Xiong, Guangqiang; Zhao, Hongtao; Di, Yongjun; Wang, Zhong; Zhou, Zhiguang

    2016-04-01

    Late Paleozoic was a critical period for the tectonic evolution of the northern margin of the Alxa-North China craton, but the evolutionary history is not well constrained. The Carboniferous intrusions in the Langshan area in the western part of the northern margin of the Alxa-North China craton are mainly composed of tonalite, quartz diorite, olivine gabbro and pyroxene peridotite. Zircon LA-ICP-MS U-Pb dating indicates that the Langshan Carboniferous intrusions were emplaced at ca. 338-324 Ma. The quartz diorites are characterized by high amounts of compatible trace elements (Cr, Ni and V) and high Mg# values, which may suggest a significant mantle source. The positive Pb and negative Nb-Ta-Ti anomalies, the variable εHf(t) (-6.9 to 2.0) values and the old Hf model ages (1218-1783 Ma) imply some involvement of ancient continental materials in its petrogenesis. The tonalite has relatively high Sr/Y ratios, low Mg#, Yb and Y contents, features of adakite-like rocks, negative εHf(t) values (-9.8 to -0.1) and older Hf model ages (1344-1953 Ma), which suggest significant involvement of ancient crust materials and mantle-derived basaltic component in its petrogenesis. The high Mg# values, high Cr and Ni contents, and low Zr and Hf contents of the mafic-ultramafic rocks show evidence of a mantle source, and the relatively low zircon εHf(t) values (-5.9 to 3.2) might point to an enriched mantle. The trace element characteristics indicate the influence of subducted sediments and slab-derived fluids. In the tectonic discrimination diagrams, all the rocks plot in subduction-related environment, such as volcanic arc and continental arc. Considering the regional geology, we suggest that the Carboniferous intrusions in the Langshan area were likely emplaced during the late stage of the southward subduction of the Paleo-Asian Ocean plate, which formed a continental arc along the northern margin of the Alxa-North China craton.

  2. New structural and U-Pb zircon data from Anafi crystalline basement (Cyclades, Greece): constraints on the evolution of a Late Cretaceous magmatic arc in the Internal Hellenides

    Science.gov (United States)

    Martha, Silviu O.; Dörr, Wolfgang; Gerdes, Axel; Petschick, Rainer; Schastok, Janina; Xypolias, Paraskevas; Zulauf, Gernold

    2016-10-01

    The Asterousia Crystalline Complex consists of Late Cretaceous amphibolite facies metamorphic rocks and associated granitoids, which can be found in exposures on Crete and the Cyclades (Greece). It is attributed to the Uppermost Unit and therefore to the Pelagonian domain of the Internal Hellenides. The tectonometamorphic evolution of this unit is still a matter of debate. We present new structural and petrological data of Asterousia-type rocks and greenschist facies metamorphic rocks from the island of Anafi in the southern Aegean Sea as well as U-Pb zircon ages of granitoids from Anafi. The crystalline sequence of Anafi rests on top of Eocene flysch and comprises from bottom to top: (a) Anafi Greenschist; (b) Anafi Amphibolite Group (orthoamphibolite with intercalations of metasedimentary rocks at the base); and (c) Chalepa Group (amphibolite facies metasediments with slices of serpentinite and granitoids). LA-ICP-MS and ID-TIMS 206Pb/238U zircon ages of granodiorite from the Chalepa Group reveal several similar zircon populations suggesting continuous emplacement of granitoids inside a magmatic arc from ca. 72.5 to 79 Ma. The minimum emplacement age of granodioritic magma, deduced from the 206Pb/238U median age of the youngest zircon population, is 72.6 +0.1/-0.2 Ma. Deformation (micro)fabrics of granodiorite result from low strain obtained at T > 600 °C. This along with the U-Pb ages and published K-Ar ages indicates intrusion of the plutonic rocks at deep structural levels followed by very slow cooling. Monzogranitic dykes cutting through granodiorite in north-eastern Anafi are undeformed and yielded a 206Pb/238U median age of 69.9 +0.7/-0.7 Ma. Based on the new and published data, the following implications for the tectonometamorphic evolution on Anafi can be made: (1) obduction and accretion of mantle slices (serpentinite) to the Asterousia-type rocks were prior to amphibolite facies metamorphism; (2) intrusion of granitoids during the middle to late

  3. Genesis of the Bangbule Pb-Zn-Cu polymetallic deposit in Tibet, western China: Evidence from zircon U-Pb geochronology and S-Pb isotopes

    Science.gov (United States)

    Kan, Tian; Zheng, Youye; Gao, Shunbao

    2016-04-01

    The Banbule Pb-Zn-Cu skarn deposit is located in the Longger-Gongbujiangda volcanic magma arc in the Gangdese-Nyainqentanglha Plate. It is the only lead-zinc polymetallic deposit discovered in the westernmost Nyainqentanglha metallogenic belt. The measured and indicated resources include 0.9 Mt of Pb+Zn (4.77% Pb and 4.74% Zn, respectively), 6499 t of Cu, and 178 t of Ag (18.75g/t Ag). The orebodies mainly occur as lenses, veins and irregular shapes in the contact zone between the quartz-porphyry and limestone of the Upper Permian Xiala Formation, or in the boundaries between limestone and sandstone. Pb-Zn-Cu mineralization in the Banbule deposit is closely associated with skarns. The ore minerals are dominated by galena, sphalerite, chalcopyrite, bornite, and magnetite, with subordinate pyrite, malachite, and azurite. The gangue minerals are mainly garnet, actinolite, diopside, quartz, and calcite. The ore-related quartz-porphyry displays LA-ICP-MS zircon U-Pb age of 77.31±0.74 Ma. The δ34S values of sulfides define a narrow range of -0.8 to 4.7‰ indicating a magmatic source for the ore-forming materials. Lead isotopic systematics yield 206Pb/204Pb of 18.698 to 18.752, 207Pb/204Pb of 15.696 to 15.760, and 208Pb/204Pb of 39.097 to 39.320. The data points are constrained around the growth curves of upper crust and orogenic belt according to the tectonic discrimination diagrams. The calculated Δβ - Δγ values plot within the magmatic field according to the discrimination diagram of Zhu et al. (1995). The S-Pb isotopic data suggest that Bangbule is a typical skarn deposit, and the Pb-Zn-Cu mineralization is genetically related to the quartz-porphyry in the mining district. The discovery of the Bangbule deposit indicates that there is metallogenic potential in the westernmost Nyainqentanglha belt, which is of great importance for the exploration work in this area.

  4. Zircon U-Pb Dating of Dayishan and Tashan Plutons in Hunan Province and Its Tectonic Implications%湖南大义山、塔山岩体锆石U-Pb年龄及其构造意义

    Institute of Scientific and Technical Information of China (English)

    李勇; 张岳桥; 苏金宝; 李建华; 董树文

    2015-01-01

    The distribution and intrusion of Early Mesozoic granites in central South China such as Dayishan pluton and Tashan pluton are closely related to folded structure in this region. Precise chronologic studies can constrain the age of the tectonic deformation. This paper report zircon U-Pb LA-ICP-MS ages of the southern part of Dayishan pluton based on dating of 3 samples:the age of the eastern margin is (171.8±1.9) Ma, that of the western margin is (169.9±1.8) Ma and that of the central part is (164.2±2.6) Ma. The zircon U-Pb LA-ICP-MS age of the eastern part of Tashan pluton is (247±5.9) Ma. Dayishan pluton experienced two phases of intrusion between 164.2 and 171.8 Ma and formed a composite pluton;after that, it experienced rapid uplift prior to 125 Ma, and then it was rapidly raised to the surface at the cooling rate of 1°C/Ma. Dayishan pluton and Tashan pluton recorded Indosinian and Yanshanian magmatic activities. The EW-trending structural zone controlled Indosinian granites, such as Yangmingshan and Tashan; the ages of Dayishan and Qitianling plutons constrain the Yanshanian tectonic deformation, and the formation of the NNE-trending folds in South China should be earlier than (171.8±1.9) Ma.%华南中部地区大义山、塔山等早中生代花岗岩的展布和侵入特征与这一时期褶皱构造之间存在着非常密切的关系,对这些岩体进行精确年代学研究,可以为构造变形时代提供年代学约束。大义山岩体南部地区锆石U-Pb LA-ICP-MS年龄为东缘(171.8±1.9) Ma、西缘(169.9±1.8) Ma、中部(164.2±2.6) Ma,塔山岩体东段为(247±5.9) Ma。大义山岩体在164.2—171.8 Ma之间经历两个期次的侵入,形成了一个复式岩体,岩体形成后至125 Ma经历了快速隆升,之后以接近1°C/Ma的冷却速率抬升到地表。大义山和塔山岩体记录了华南早中生代印支和燕山两期重要的岩浆活动。阳明山、塔山岩体等E—W向展布岩体受

  5. Subduction-related Late Carboniferous to Early Permian Magmatism in the Eastern Pontides, the Camlik and Casurluk plutons: Insights from geochemistry, whole-rock Sr-Nd and in situ zircon Lu-Hf isotopes, and U-Pb geochronology

    Science.gov (United States)

    Karsli, Orhan; Dokuz, Abdurrahman; Kandemir, Raif

    2016-12-01

    Late Carboniferous to early Permian granitoid rocks represent a volumetrically minor component of the Eastern Pontide lithosphere, but they preserve useful information about the region's tectonomagmatic history. The Casurluk and Camlik plutons primarily consist of gabbro, gabbroic diorite, diorite, monzogabbro, monzodiorite and monzonite, which intrude early to middle Carboniferous granitic basement rocks in the region. In this study, we use in situ zircon U-Pb ages and Lu-Hf isotopic values, whole-rock Sr-Nd isotopic values, and mineral chemistry and geochemistry of these plutons to determine petrogenesis and crustal evolution; we also discuss geodynamic implications. LA-ICP-MS zircon U-Pb dating of magmatic zircons from the rocks suggests that the plutons were emplaced during the late Carboniferous to early Permian (302 Ma). The metaluminous and I-type intrusive rocks belong to the high-K calc-alkaline series. In addition, they are relatively enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs); they are depleted in heavy rare earth elements (HREEs) and high field strength elements (HFSEs), such as Nb and Ti. All of the samples have homogeneous initial ISr values (0.70675 to 0.70792) and low εNd (t) values (- 5.1 to - 3.3). Zircons from the rocks of both plutons have uniform negative to slightly positive εHf (t) values (- 3.5 to 1.4) and old Hf two-stage model ages (1323 to 1548 Ma), implying that they have the same source, as well as suggesting the involvement of old enriched lithospheric mantle materials during their magma genesis. These results, combined with the εHf (t) values and two-stage model ages, demonstrate that the primary magmas were derived from partial melting of old lithospheric mantle material metasomatized by subduction-related fluids. Considering other regional geological data from the Sakarya Zone where these plutons formed, we conclude that late Carboniferous to early Permian magmatism in the area

  6. Detrital zircon U-Pb and (U-Th)/He double-dating of Upper Cretaceous-Cenozoic Zagros foreland basin strata in the Kurdistan Region of northern Iraq

    Science.gov (United States)

    Barber, D. E.; Stockli, D. F.; Koshnaw, R. I.; Horton, B. K.; Tamar-Agha, M. Y.; Kendall, J. J.

    2014-12-01

    The NW Zagros orogen is the result of the multistage collisional history associated with Late Cretaceous-Cenozoic convergence of the Arabian and Eurasian continents and final closure of Neotethys. Siliciclastic strata preserved within a ~400 km segment of the NW Zagros fold-thrust belt and foreland basin in the Iraqi Kurdistan Region (IKR) provide a widespread record of exhumation and sedimentation. As a means of assessing NW Zagros foreland basin evolution and chronostratigraphy, we present coupled detrital zircon (DZ) U-Pb and (U-Th)/He geo-thermochronometric data of Upper Cretaceous to Pliocene siliciclastic strata from the Duhok, Erbil, and Suleimaniyah provinces of IKR. LA-ICP-MS U-Pb age analyses reveal that the foreland basin fill in IKR in general was dominantly derived from Pan-African/Arabian-Nubian, Peri-Gondwandan, Eurasian, and Cretaceous volcanic arc terrenes. However, the provenance of these strata varies systematically along strike and through time, with an overall increase in complexity upsection. DZ age distribution of Paleocene-Eocene strata is dominated by a ~95 Ma grain age population, likely sourced from the Late Cretaceous Hassanbag-Bitlis volcanic arc complex along the northern margin of Arabia. In contrast, DZ U-Pb age distributions of Neogene strata show a major contribution derived from various Eurasian (e.g., Iranian, Tauride, Pontide; ~45, 150, 300 Ma) and Pan-African (~550, 950 Ma) sources. The introduction of Eurasian DZ ages at the Paleogene-Neogene transition likely records the onset of Arabian-Eurasian collision. Along strike to the southeast, the DZ U-Pb spectra of Neogene strata show a decreased percentage of Pan-African, Peri-Gondwandan, Tauride, and Ordovician ages, coupled with a dramatic increase in 40-50 Ma DZ ages that correspond to Urumieh-Dokhtar magmatic rocks in Iran. Combined with paleocurrent data, this suggests that Neogene sediments were transported longitudinally southeastward through an unbroken foreland basin

  7. U-Pb zircon dating, geochemical and Sr-Nd-Hf isotopic compositions of mafic intrusive rocks in the Motuo, SE Tibet constrain on their petrogenesis and tectonic implication

    Science.gov (United States)

    Pan, Fa-Bin; Zhang, Hong-Fei; Xu, Wang-Chun; Guo, Liang; Luo, Bi-Ji; Wang, Shuai

    2016-02-01

    Mafic intrusive rocks are widely exposed in the Motuo tectono-magmatic belt, southeast Lhasa terrane. LA-ICP-MS U-Pb zircon dating shows that they have magma crystallization ages of 69 and ca. 50 Ma. These mafic intrusive rocks are characterized by variable SiO2 (44.60-57.60 wt.%), high Al2O3 (17.19-20.86 wt.%), and low MgO (1.85-5.38 wt.%) with Mg# of 31-55. Their chemical composition is comparable with low-MgO high-Al basalts to basaltic andesites. They are enriched in LILEs (Rb, Ba, K) and LREE and depleted in HFSEs (Nb, Ta, Zr, Hf, Ti), with weakly evolved Sr-Nd-Hf compositions (whole-rock (87Sr/86Sr)0 = 0.7064 to 0.7086, εNd(t) = - 3.41 to + 1.22, and zircon εHf(t) = - 3.8 to + 6.4). The mafic rocks were derived from partial melting of metasomatized lithospheric mantle. Geochemical and Sr-Nd-Hf isotopic data show that they were insignificantly modified during magma emplacement. We provide a different secular evolution of the lithospheric mantle beneath the eastern part relative to the central part of the southern Lhasa terrane. Sr-Nd isotopic composition of the Motuo Late Cretaceous-Eocene mafic rocks argues that they were derived from partial melting of a relatively homogeneous and depleted lithospheric mantle. We propose that the Late Cretaceous delamination resulted in the replacement of ancient lithospheric mantle by the juvenile homogeneous lithospheric mantle in the eastern Lhasa terrane. The foundered ancient materials may subsequently re-fertilize the lithospheric mantle not only in the eastern Lhasa terrane but also in the surrounding areas.

  8. Resolving high precision U-Pb ages from Tertiary plutons with complex zircon systematics

    Science.gov (United States)

    Mcclelland, William C.; Mattinson, James M.

    1996-10-01

    Success in establishing high precision crystallization ages with the U/Pb zircon method is highly dependent on the ability to isolate or remove the effects of inherited xenocrystic components or secondary lead-loss, or the combined effects of both. Current "conventional" single crystal and ion probe (SHRIMP) methods are successfully applied to Paleozoic and older samples but typically suffer from imprecision when applied to younger (Mesozoic-Cenozoic) samples due to generally reduced radiogenic lead concentrations. Here we apply a series of intense partial dissolution steps to multigrain zircon fractions from a series of Paleocene tonalitic to granodioritic intrusive rocks from southeastern Alaska. The zircon systematics are complicated by both minor inheritance and postcrystallization lead-loss. Physical and isotopic evidence demonstrate that the partial dissolution steps preferentially remove outer layers susceptible to lead loss, as well as core regions containing inherited components. The final residues are often hollow shells of low-U primary igneous zircon that yield highly precise, reproducible, and concordant ages. The resulting age determinations commonly statistically differ at the 95% confidence level from ages based on apparently concordant, but less precise conventional isotope dilution analyses, the uncertainties of which masked minor, subtle isotopic complexities. This observation strongly cautions against basing age assignments of samples yielding slightly discordant data on (1) single "concordant" analyses accompanied by an array of discordant data or (2) the mean of several 206Pb/ 238U or 207Pb/ 206Pb ages. The step-wise dissolution technique allows age determinations on young, relatively low U and Pb zircons at a resolution not currently possible with techniques such as single-grain conventional or spot ion probe analyses. Widespread application of the technique will likely prove instrumental in resolving detailed magmatic histories of igneous

  9. Tubular textures in pillow lavas from a Caledonian west Norwegian ophiolite: A combined TEM, LA-ICP-MS, and STXM study

    Science.gov (United States)

    Fliegel, Daniel; Wirth, Richard; Simonetti, Antonio; Schreiber, Anja; Furnes, Harald; Muehlenbachs, Karlis

    2011-02-01

    Tubular alteration textures, mineralized by titanite, in glassy rims of pillow lavas from a Norwegian ophiolite (Solund-Stavfjord ophiolite complex (SSOC)) are described and characterized by a multimethod approach. Tubular alteration textures, mineralized by titanite, have been previously proposed to result from bioalteration. The microstructure of the titanite and the tubes is investigated using focused ion beam milling in combination with transmission electron microscopy (TEM) and scanning transmission X-ray microscopy (STXM). These indicate an assemblage of submicrometer-sized (about 500 nm) titanite single crystals with no organic film or residue in between the grains. In situ U-Pb radiometric dating of the titanite, using laser ablation-multicollector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS), yielded a metamorphic age of 442 ± 13 Ma. An isotope dilution-thermal ionization mass spectrometric age obtained previously for zircons from the SSOC plutonic rocks yielded a magmatic age of 443 ± 3 Ma. The overlap in ages indicates that subseafloor metamorphism, responsible for titanite formation, occurred during seafloor or subseafloor formation of the tubular alteration textures. The rare earth element contents of the titanite were determined using LA-ICP-MS and chondrite-normalized patterns are similar to those of the SSOC volcanics; hence these do not reflect hydrothermal or seawater influence. The Y/Ho ratio of ˜20-30 in the titanite is also consistent with an upper mantle-derived origin. The sum of all of the spatial resolved data reported here neither supports nor refutes a biogenic origin for the tubular textures.

  10. Age and timing of the Permian mass extinctions: U/Pb dating of closed-system zircons.

    Science.gov (United States)

    Mundil, Roland; Ludwig, Kenneth R; Metcalfe, Ian; Renne, Paul R

    2004-09-17

    The age and timing of the Permian-Triassic mass extinction have been difficult to determine because zircon populations from the type sections are typically affected by pervasive lead loss and contamination by indistinguishable older xenocrysts. Zircons from nine ash beds within the Shangsi and Meishan sections (China), pretreated by annealing followed by partial attack with hydrofluoric acid, result in suites of consistent and concordant uranium/lead (U/Pb) ages, eliminating the effects of lead loss. The U/Pb age of the main pulse of the extinction is 252.6 +/- 0.2 million years, synchronous with the Siberian flood volcanism, and it occurred within the quoted uncertainty.

  11. Hf isotopic compositions of the standard zircons for U-Pb dating

    Institute of Scientific and Technical Information of China (English)

    XU Ping; WU Fuyuan; XIE Liewen; YANG Yueheng

    2004-01-01

    Using the newly published Yb isotopic abundances and the mass bias relationship between Yb and Hf, we carried out an analysis of Hf isotopes in the standard zircon 91500 by means of 193 nm laser attached to Neptune multi-collector ICP-MS (LA-MC-ICPMS). The obtained Hf isotopic data, in either in situ or line scan modes, are not only identical for different spot sizes, but also are consistent with previously published results obtained on TIMS or other MC-ICPMS machines within errors. This indicates that it is possible to obtain reliable 176Hf/177Hf isotopic ratios for zircon in either in situ or line scan conditions on LA-MC-ICPMS machine, and the applied procedures in our study for elemental interfering correction are appropriate for the purpose of acquiring satisfactory accuracy for Hf isotope analyses. The Hf isotopic compositions of four zircon standards in high spatial resolution U-Pb dating, 91500, CZ3,CN92-1 and TEMORA, are measured, respectively. The obtained 176Hf/177Hf ratios are 0.282316+4 (n = 34, 2σ) for 91500, 0.281704±6 (n = 16, 2σ) for CZ3, 0.282200±6 (n = 20,2σ-) for CN92-1 and 0.282684±14 (n = 24, 2σ) for TEMORA,respectively, with 176Lu/177Hf ratios of ~0.00031, 0.000036,0.00083 and 0.00127. Zircons 91500 and CZ3 show narrower variations in 176Hf/177Hf and 176Lu/177Hf ratios than those of zircons CN92-1 and TEMORA, and thus are appropriate standards for the Hf isotope analysis.

  12. U-Pb (Zircon Ages of Metavolcanic Rocks From the Itaiacoca Group: Tectonic Implications

    Directory of Open Access Journals (Sweden)

    Oswaldo Siga Jr.

    2003-08-01

    Full Text Available The main aim of this work is to present and discuss the U-Pb ages obtained for zircon grains from metavolcanic rocks of theItaiacoca Group. The Itaiacoca Group is a metavolcano-sedimentary sequence, which occurs as a narrow belt between theCunhaporanga granitic batholith to the northwest and the Itapirapuã shear zone to the south and southwest, which separates thesequence from the Três Córregos granite batholith and metasedimentary rocks of the Açungui Group. Geological studies of thesouthern part of the Itaiacoca belt led to the recognition of three units, represented (from base to top by metawackes with animportant volcanic component, metacarbonate, and metapelitic and metapsammitic rocks. The U-Pb geochronological analyses ofzircon grains from two outcrops of metavolcanic rocks yield ages of 628 ± 18 Ma (SHRIMP and 636 ± 30 Ma (conventional multigrainanalyses. These ages are quite close to the metamorphic event recorded in the Itaiacoca Group (628 – 610 Ma, suggesting ashort interval between the formation of these rocks and closure of the basin. Furthermore, this volcanism is very close to the age offormation of the Três Córregos (630 Ma and Cunhaporanga (590 Ma granitic batholiths, admitted as associated with a probablemagmatic arc. Such an isotopic pattern characterizes a Neoproterozoic tectonic scenario involving volcanism, metamorphism andgranitic plutonism, interpreted here as the final stages in the evolution of the Itaiacoca Basin.

  13. Petrology and U-Pb zircon geochronology of bimodal volcanic rocks from the Maierze Group, northern Tibet: Constraints on the timing of closure of the Banggong-Nujiang Ocean

    Science.gov (United States)

    Fan, Jian-Jun; Li, Cai; Xie, Chao-Ming; Wang, Ming; Chen, Jing-Wen

    2015-06-01

    We present new zircon U-Pb dates, major and trace element chemistry, and Hf isotopic compositions for bimodal volcanic rocks of the Maierze Group (MG) in the Maierze area of the Southern Qiangtang-Baoshan block, northern Tibet. We discuss the implications of these data for the evolution of this region. The MG bimodal volcanic rocks consist of basalts and dacites that yield LA-ICP-MS zircon U-Pb ages of 122 and 120 Ma, respectively. The MG basalts have light rare earth element (LREE)-enriched chondrite-normalized REE patterns (LaN/YbN = 13-14), high Ti/V ratios (45-64), high Zr (190-270 ppm) and Nb (22-41 ppm) concentrations, and Zr/Y ratios (7-9) that are similar to those of within-plate basalts. The MG basalts also have low MgO and total Fe2O3 (TFe2O3) concentrations, significant enrichments in the LREE and the light ion lithophile elements (LILEs; Rb, Ba, Th, U and Pb), and weak depletions in the high field strength elements (HFSE; Nb, Ta, and Ti), all of which are clearly evident in primitive-mantle-normalized multi-element variation diagrams. The MG dacites are more enriched in the LILE (e.g., Rb, Ba, Th, U, K, and Pb) and more depleted in the HFSE (e.g., Nb, Ta, and Ti) than the MG basalts. Moreover, the dacites have variable zircon εHf(t) values (- 6.3 to + 6.3). These features indicate that the parental magma for the MG basalts was likely derived from an enriched lithospheric mantle source that was contaminated by subduction-related fluids or melts. In contrast, the MG dacites were derived from mixing of the MG basaltic magma with a second magma derived from partial melting of the continental crust. The geochemical and Hf isotopic characteristics of the MG bimodal volcanic rocks suggest that they formed during the initial stages of development of a back-arc basin. From south to north, the Bangong-Nujiang suture zone, the Duolong gold-rich porphyry copper deposit, and the Maierze bimodal rocks are interpreted to represent a remnant of a complete volcanic arc

  14. SHRIMP U-Pb zircon age of the youngest exposed pluton in eastern China

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Analysis using the Sensitive High Resolution Ion Microprobe (SHRIMP) shows that the Yongsheng pluton, located to the south of Huadian County, Jilin Province, in the North China Craton, has a zircon U-Pb isotopic emplacement age of (31.6±13) Ma. It is therefore the youngest exposed pluton so far recognized in eastern China. Although geochemical data indicate intensive crystal fractionation, the Sr-Nd isotopic features suggest that the magmatic source region of the lithospheric mantle was weakly depleted. This implies that the previous enriched lithospheric mantle had been replaced by juvenile asthenospheric mantle before or during the Palaeogene. This recognition has great significance for future work on the Mesozoic-Cenozoic geological evolution and deep geological processes in eastern China.

  15. Zircon U-Pb ages for Wulian granites in northwest Sulu and their tectonic implications

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The Wulian complex occurring in the north-western part of the Sulu orogen consists of metaigneous and metasedimentary rocks at greenschist-facies. Zircon U-Pb dating for three granite intrusions within it yields concordant ages of (672±4), (742±9) and (747±14) Ma, respectively. These ages indicate that the granites are the Neoproterozoic intrusions in the northern margin of the Yangtze plate, and correspond to the magmatic complex at Luzhenguan in the eastern part of the Beihuaiyang belt in the Dabie orogen. They were tectonic slices scraped off from the Yangtze plate during Triassic subduction and thus belong to a part of the accretionary wedge of the Yangtze plate subduction. The discovery of extensive Neoproterozoic magmatic rocks in the Wulian area suggests that the suture location between the North China and the Yangtze plates lies north of the Wulian complex.

  16. SHRIMP U-Pb zircon dating of Pedras Grandes Suite, southern Santa Catarina State, Brazil

    Directory of Open Access Journals (Sweden)

    Andréa R. Jelinek

    2005-03-01

    Full Text Available Two major magmatic pulses of the granitic Florianópolis Batholith in Santa Catarina State, southern Brazil, occurred between 613±5Ma and 595±5 Ma, during the Neoproterozoic Brasiliano Cycle. These ages were obtained by U-Pb isotopic determinations with the sensitive high mass-resolution ion microprobe on igneous zircons from Pedras Grandes Suite in Santa Catarina State. Euhedral zircons remained unaltered close to a fluorite vein deposited at 180?C or more. These ages suggest a northern limit for the Pedras Grandes Suite, explaining the spatial relationship between the fluorite veins and the source rock.Dois dos principais pulsos da atividade granítica no Batólito Florianópolis em Santa Catarina ocorreram entre 613 ±5 Ma e 595 ±5 Ma, durante o Neoproterozóico do Ciclo Brasiliano. Estas idades foram obtidas a partir dedeterminações isotópicas U-Pb em cristais de zircão da Suite Pedras Grandes por "Sensitive high-resolution íon microprobe" - SHRIMP II. Os cristais de zircão permaneceram inalterados mesmo mediante condições hidrotermais com temperaturas iguais e, até mesmo, superiores a 180ºC. Estas idades sugerem a delimitação norte do Maciço Pedras Grandes, explicando a relação espacial existente entre os filões de fluorita e a rocha fonte destas mineralizações.

  17. U-Pb Ages and Hf Isotope Compositions of Detrital Zircons from the Sandstone in the Early Cretaceous Wawukuang Formation in the Jiaolai Basin, Shandong Province and its Tectonic Implications%胶莱盆地早白垩世瓦屋夼组砂岩中碎屑锆石U-Pb-Hf同位素组成及其构造意义

    Institute of Scientific and Technical Information of China (English)

    霍腾飞; 杨德彬; 许文良; 王枫; 刘海彬; 师江朋

    2015-01-01

    LA-ICP-MS U-Pb dating and in situ Hf isotope analysis were carried out for the detrital zircons to constrain the depositional age and provenance of the Wawukuang Formation, which is believed as the earliest unit of the Laiyang Group in the Jiaolai Basin, and its implications. Most of these detrital zircons from the feldspar quartz sandstone in the Wawukuang Formation are magmatic in origin, which are euhedral-subhedral and display oscillatory zoning in CL images; whereas few Late Triassic detrital zircons are metamorphic in origin and structureless in CL images. U-Pb isotopic dating of 82 zircon grains yields age populations at ca. 129 Ma, 158 Ma, 224 Ma, 253 Ma, 461 Ma, 724 Ma, 1851 Ma and 2456 Ma. U-Pb dating and Hf isotopic results indicate that:1) the Wawukuang Formation deposited during the Early Cretaceous (129–106 Ma);2) the detrital zircons with the ages of 1851 Ma and 2456 Ma mainly sourced from the Precambrian basement rocks of the North China Craton;the Neoproterozoic (729–721 Ma) magmatic zircons and the Late Triassic (226–216 Ma) metamorphic zircons sourced from the Su-Lu terrane; The Late Paleozoic detrital zircons could source from the Late Paleozoic igneous rocks in the northern margin of the North China Craton;the Late Triassic (231–223 Ma) magmatic zircons and the 158–129 Ma zircons sourced from the coeval igneous rocks in the Jiaobei and Jiaodong;3) the deposition age and provenance of the Jiaolai Basin are different from those of the Hefei Basin; 4) the recognition of clastic sediments from the Su-Lu terrane in the Wawukuang Formation suggests that the Su-Lu terrane was under denudation in the Early Cretaceous.%本文报道了胶莱盆地莱阳群最底部瓦屋夼组长石石英砂岩中碎屑锆石的LA-ICP-MS U-Pb年代学和原位Hf同位素分析结果,进而约束了瓦屋夼组砂岩的沉积时代和物源及其构造意义。碎屑锆石多数呈自形–半自形晶,发育岩浆生长环带,暗示它们为岩浆成因

  18. U-Pb dating by zircon dissolution method using chemical abrasion

    Directory of Open Access Journals (Sweden)

    Lucy Takehara

    2012-06-01

    Full Text Available Chemical abrasion was carried out on zircons grains of the Temora II standard for U-Pb dating prior to analyses using in situ Laser Ablation-MultiCollector Ion Coupled Plasma Mass Spectrometer (LA-ICPMS followed by the Isotope Dissolution Thermal Ionization Mass Spectrometer (ID-TIMS method. The proposed methodology was herein applied in order to reduce primarily the effects of secondary Pb loss, the presence of common lead and/or silicate impurities. Nine Temora II zircon grains were analyzed by the laser ablation method yielding an age of 418.3±4.3 Ma. Zircon grains of a same population were separated for chemical abrasion before dissolution and mass spectrometry analyses. Six fractions of them were separated for isotope dissolution using 235U-205Pb mixed spike after we have checked and assured the laboratory conditions of low blank values for total Pb of less than 2 pg/g. The obtained U-Pb zircon age by the ID-TIMS method was 415.7±1.8 Ma (error 0.43 % based on four successful determinations. The results are consistent with the published ages for the Temora diorite (Temora I – 416.75±1.3 Ma; Temora II – 416.78±0.33 Ma and established as 416±0.33 Ma. The technique is thus recommended for high precision U-Pb zircon analyses (error Este trabalho apresenta a técnica de abrasão química em zircões do padrão Temora II aplicada em datação de U-Pb por Dissolução Isotópica e Espectrometria de Massa por Ionização Térmica, método DI-ESIT. O emprego deste método tem como princípio diminuir os efeitos da perda secundária de Pb radiogênico antes da dissolução. Em primeira instância, os zircões foram analisados pelo método in situ com uso de Microssonda Laser acoplada a um Espectrômetro de Massa Multicoletor com Plasma Acoplado Indutivamente (MC-ICP-MS, cujo objetivo foi identificar os grãos de zircão de fase de cristalização simples sem sobrecrescimento. Nove cristais de zircão analisados com microssonda a

  19. Zircon-apatite U-Pb geochronology, zircon Hf isotope composition and geochemistry of granite batholith in the northern Mexico: Implications for Tectonomagmatic evolution of southern Cordillera.

    Science.gov (United States)

    Mahar, M. A.; Goodell, P.

    2015-12-01

    We present the zircon-apatite U-Pb ages and zircon Hf isotope composition of the granite batholith exposed at the western boundary of Chihuahua. Granidiorite samples were analyzed from both, north and south of the Rio El Fuerte and Sinforosa Lineament. Based on previous studies, the WWN-EES trending Sinforosa Lineament is proposed as the manifestation of a terrane boundary between Seri in the north and Tahue terrane in the south. Zircon U-Pb data indicate that the magmatism spans a time period of 36 Ma from 89 to 53 Ma to the north of the Sinforosa Lineament while granodiorites in the south of the Sinforosa Lineament are dated at 59 Ma. The U-Pb apatite ages are variable in the north of the Sinforosa Lineament and range from 86-51 Ma. These apatite dates are 1-28 Ma younger than the corresponding zircon U-Pb crystallization ages. This indicates variable cooling rates and moderate to shallow emplacement. In contrast, in the south of the Sinforosa Lineament, the U-Pb apatite ages (64-59 Ma) are indistinguishable from the zircon U-Pb age (59 Ma), indicating rapid cooling and shallow emplacement. Zircon morphology and U-Pb dating revealed the absence of inherited component in the zircon ages, as no inheritance of any age has been observed. Most of the northwestern Mexico is underlain by Precambrian-Paleozoic-Jurassic basement. However, in the study area, U-Pb dating does not support the involvement of the older basement in generating the granite magmas. The weighted mean initial ɛHf (t) isotope composition of granodiorites on both sides of the Sinforosa Lineament varies from +2 to +5. However, Hf isotope composition in the south of the Sinforosa Lineament is more heterogeneous and relatively evolved with weighted Mean ɛHf (t) = +1.45. The Hf isotope composition is consistent with the previously reported near bulk silicate Sr-Nd isotope values. We suggest that the magmatic rocks in this region are not derived from melting of a felsic older crust beneath the batholith

  20. Zircon U-Pb geochronology,Hf isotopic composition and geological implications of the rhyodacite and rhyodacitic porphyry in the Xiangshan uranium ore field,Jiangxi Province,China

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The Xiangshan uranium ore field is the largest volcanic rock hosted uranium deposit in China.The host rock is a volcanic intrusive complex,including rhyodacite,porphyroclastic lava and late stage sub-volcanic rocks.In this study,zircons from an early stage rhyodacite and a late stage rhyodacite porphyry were dated by SHRIMP and LA-ICP-MS U-Pb methods,and their Hf isotopic compositions were measured by LA-MC-ICP-MS.206Pb/238U ages of 135.1±1.7 and 134.8±1.1 Ma were obtained for the rhyodacite and rhyodacitic porphyry,respectively.These accurate ages indicate that the Xiangshan volcanic-intrusive complex formed in the Early Cretaceous rather than in the Late Jurassic,as concluded in some previous studies.By the Early Cretaceous,the tectonic setting of the area has evolved into a back-arc extensional setting,possibly related to subduction of the paleo-Pacific plate.The close ages of the(early) eruptive rhyodacite and the(late) hypabyssal rhyodacitic porphyry shows that the Xiangshan volcanism was intensive and concentrated in a short time.Zircons from the rhyodacite show negative εHf(t) values of-5.7 to-8.5,with Hf depleted mantle model ages between 1550 and 1720 Ma,whereas zircons from the rhyodacitic porphyry yield εHf(t) values of-6.9 to-10.1 and Hf model ages between 1621 and 1823 Ma.These zircon Hf model ages are similar to the whole rock Nd model ages(1486 to 1911 Ma).Combined with other geochemical characteristics,the Xiangshan rhyodacite and rhyodacitic porphyry may have been derived from partial melting of the Paleo-Mesoproterozoic metamorphic rocks from the Xiangshan basement,without any significant addition of mantle-derived magma.Contribution of basement of this age is also supported by finding a Paleoproterozoic xenocrystic zircon core in the rhyodacite sample.

  1. Zircon U-Pb Ages of Bottom and Top Parts of the Zhangjiakou Formation in Lingyuan Area (West Liaoning Province) and Luanping Area (North Hebei Province) and Their Significance

    Institute of Scientific and Technical Information of China (English)

    Zhang Hong; Liu Xiaoming; Zhang Yeqing; Yuan Honglin; Hu Zhaochu; Diwu Chunrong

    2005-01-01

    In Lingyuan region of West Liaoning Province, the Zhangjiakou Formation (J3z) and the Yixian Formation (K1y) display an angular unconformity. That is, the Lower Mesozoic strata of the Zhangjiakou Formation are ENE (near E-W) oriented, while the overlying strata of the Yixian Formation exhibit an NNE orientation. The results of LA-ICP-MS zircon U-Pb ages show the Zhangjiakou Formation formed from about 130 Ma to 132 Ma in Lingyuan and 135 Ma to 136 Ma in Luanping (North Hebei Province), respectively. Three conclusions can be drawn: (1) The Zhangjiakou Formation in Lingyuan is comparable to that in Luanping, with the volcanic rocks of the Zhangjiakou Formation from Lingyuan being younger than those from Luanping. (2) 5-6 Ma difference between the top of the Zhangjiakou Formation and the bottom of the Yixian Formation in Lingyuan proves the angular unconformity between the two formations; and it reflects that the 5-6 Ma interval period is the main period of the transition of tectonic framework in Mesozoic in North Hebei and West Liaoning. In the interval period, the magmatic action went up to high tide in Mesozoic in the northeast of China. Moreover, after the interval period, the "Rehe fauna" developed into "erupted" period. This reflects that the interval period is also an important biological interface in Northern Hebei and Western Liaoning. (3) The Dabeigou Formation in Luanping should correspond to the upper part of the Zhangjiakou Formation, but not to the lower part of the Yixian Formation.

  2. Neoproterozoic transpression and granite magmatism in the Gavilgarh-Tan Shear Zone, central India: Tectonic significance of U-Pb zircon and U-Th-total Pb monazite ages

    Science.gov (United States)

    Chattopadhyay, Anupam; Chatterjee, Amitava; Das, Kaushik; Sarkar, Arindam

    2017-10-01

    The Gavilgarh-Tan Shear Zone (GTSZ) is a crustal-scale shear/fault zone that dissects the unclassified basement gneisses separating two major supracrustal belts, viz. the Paleo- to Mesoproterozoic (≥1.5 Ga) Betul Belt and the Neoproterozoic (∼1.0 Ga) Sausar Belt, of the Central Indian Tectonic Zone (CITZ). The GTSZ extends for more than 300 km strike length, partly covered by the Deccan Trap flows. Granitoid rocks ranging from syenogranite to granodiorite in composition, sheared at temperatures corresponding to the amphibolite facies metamorphic condition, define the GTSZ in the Kanhan River Valley. Earlier geological studies have suggested that the GTSZ underwent a sinistral-sense partitioned transpression in response to an oblique collision between two continental fragments, possibly related to crustal thickening and high-pressure granulite metamorphism (the Ramakona-Katangi granulite: RKG) in the northern part of the Sausar Belt. LA-ICP-MS U-Pb dating of zircon and EPMA U-Th-total Pb dating of monazite grains from four different types of syn-tectonic granitoids of the GTSZ carried out in the present study show that granitoids intruded the basement gneisses between 1.2 Ga and 0.95 Ga, given the error limit of the calculated ages. The age of transpression and mylonitization is more definitely bracketed between 1.0 Ga and 0.95 Ga, which correlates well with the published ages of deformation and metamorphism in the Sausar Belt. This age data strongly supports the suggested collisional tectonic model involving the GTSZ and the RKG granulites of the Sausar Belt and underlines a Grenvillian-age tectonic history for the southern part of the Central Indian Tectonic Zone (CITZ), which possibly culminated in the crustal assembly of the Neoproterozoic supercontinent Rodinia.

  3. SHRIMP zircon U-Pb geochronology of Indosinian granites in Hunan Province and its petrogenetic implications

    Institute of Scientific and Technical Information of China (English)

    WANG Yuejun; FAN Weiming; LIANG Xinquan; PENG Touping; SHI Yuruo

    2005-01-01

    The SHRIMP zircon U-Pb geochronology of three typically Indosinian granitic plutons with peraluminous and potassium-rich affinities (Tangshi ultraunit for Weishan and Baimashan, and Longtan ultraunit for Guandimiao) is presented in Hunan Province, South China. The analyses of zircons from biotite monozonite granites for Weishan, Baimashan and Guandimiao plutons show the single and tight clusters on the concordia, and yield the weighted mean 206Pb/238U ages of 244±4, 243±3 and 239±3 Ma, respectively, representing the crystallized ages of these Indosinian granites. These data suggest that the Indosinian granitic plutons as previously thought formed at a narrow age span. In combination with other data, it is inferred that the Indosinian granites within the South China Block probably distributed in Hunan, Jiangxi, Guangxi and Guangdong provinces as planar shape, and were the derivation of the crustal materials in the intracontinental thickening setting. These precisely geochronological data provide important constraints for better understanding the spatiotemporal pattern of the Indosinian peraluminous granites and early Mesozoic tectonic evolution of the South China Block.

  4. Geochemistry and U-Pb geochronology of detrital zircons in the Brujas beach sands, Campeche, Southwestern Gulf of Mexico, Mexico

    Science.gov (United States)

    Tapia-Fernandez, Hector J.; Armstrong-Altrin, John S.; Selvaraj, Kandasamy

    2017-07-01

    This study investigated the bulk sediment geochemistry, U-Pb ages and rare earth element (REE) geochemistry of one hundred detrital zircons recovered from the Brujas beach sands in southwestern Gulf of Mexico to understand the provenance and age spectra. The bulk sediments are high in Zr and Hf contents (∼1400-3773 ppm and ∼33-90 ppm, respectively) suggested the abundance of resistant mineral zircon. The chondrite normalized REE patterns of the bulk sediments are less fractionated with enriched low REE (LREE; LaCN/SmCN = ∼491-693), depleted heavy REE (HREE; GdCN/YbCN = ∼44-69) and a negative Eu anomaly (Eu/Eu∗ = ∼0.44-0.67) suggested that the source rock is felsic type. The results of this study revealed highly varied contents of Th (∼4.2-321 ppm), U (∼20.7-1680 ppm), and Hf (∼6970-14,200 ppm) in detrital zircons compared to bulk sands. The total REE content (∼75 and 1600 ppm) and its chondrite-normalized pattern with positive Ce and negative Eu anomalies as well as low Th/U ratio of zircon grains indicated that they were dominantly of magmatic origin. U-Pb data of zircons indicated two age populations, with predominance of Permian-Triassic (∼216-286 Ma) and Neoproterozoic (∼551-996 Ma). The Permian-Triassic zircons were contributed by the granitoids and recycled metasedimentary rocks of the Chiapas Massif Complex. The major contribution of Neoproterozoic zircons was from the Chaucus, Oaxacan, and Chiapas Massif Complexes in Grenville Province, southern Mexico. U-Pb ages of zircons from the Brujas beach are consistent to the reported zircon ages from the drainage basins of Usumacinta, Coatzacoalcos, and Grijalva Rivers in southern Mexico, suggesting that the sediments delivered by the rivers to the beach area are vital in defining the provenance of placers.

  5. U-Pb provenance ages of shocked zircons from the K-T boundary, Raton Basin, Colorado

    Science.gov (United States)

    Premo, W. R.; Izett, G. A.

    1993-01-01

    U-Pb isotopic systematics from analyses of single zircons identify at least two provenance ages, approximately 575 Ma and approximately 330 Ma, for zircons from the impact layer of the K-T boundary, Raton Basin, Colorado. These data are a preliminary confirmation of results reported from the same layer. The zircon provenance ages provide a unique signature for identification of the source crater since igneous rocks of these ages (or sedimentary rocks derived from them) must characterize part of the impact stratigraphy.

  6. In situ simultaneous determination of trace elements,U-Pb and Lu-Hf isotopes in zircon and baddeleyite

    Institute of Scientific and Technical Information of China (English)

    XIE LieWen; ZHANG YanBin; ZHANG HuiHuang; SUN JingFeng; WU FuYuan

    2008-01-01

    This paper describes a combined method of simultaneously measuring U-Pb and Lu-Hf isotopes as well as trace elements in Phalaborwa baddeleyite and 91500, GJ-1, TEMORA-1 and SK10-2 zircons by means of Neptune MC-ICPMS and Agilent Q-ICPMS connected to a 193 nm excimer laser ablation system. Material ablated by laser was carried in different proportions into Q-ICPMS for U-Pb isotopic and trace elemental and MC-ICPMS for Lu-Hf isotopic compositions. Experiments indicate that different propor-tions of ablated material for the Q-ICPMS and MC-ICPMS (6∶4, 5∶5 and 4∶6 respectively) do not show any bias for the zircon/baddeleyite U-Pb age, Lu-Hf isotope and trace elemental compositions within ana-lytical errors. Using 40-60 μm spot size, the obtained U-Pb ages of Phalaborwa baddeleyite, 91500, GJ-1, TEMORA and SK10-2 zircons are 2065~15 (2σ, n=20), 1063±6 (2σ, n=19), 613±6 (2σ,=20), 416±5 (2σ, n=20) and 32.6±0.5 (2σ, n=20) Ma, respectively. The 176Hf/177Hf ratios are 0.281231±24 (2SD, n=20), 0.282310±35 (2SD, n=19), 0.282028±34 (2SD, n=20), 0.282687±34 (2SD, n=20) and 0.282752±53 (2SD, n=20), respectively. The obtained trace elemental compositions are identical to the reference values. Therefore, this kind of technique makes it possible to simultaneously obtain the U-Pb age, Lu-Hf iso-topes and trace elemental compositions of zircon and baddeleyite, which could be an important tool in solving problems in earth sciences.

  7. Chemical abrasion-SIMS (CA-SIMS) U-Pb dating of zircon from the late Eocene Caetano caldera, Nevada

    Science.gov (United States)

    Watts, Kathryn E.; Coble, Matthew A.; Vazquez, Jorge A.; Henry, Christopher D.; Colgan, Joseph P.; John, David A.

    2016-01-01

    Zircon geochronology is a critical tool for establishing geologic ages and time scales of processes in the Earth's crust. However, for zircons compromised by open system behavior, achieving robust dates can be difficult. Chemical abrasion (CA) is a routine step prior to thermal ionization mass spectrometry (TIMS) dating of zircon to remove radiation-damaged parts of grains that may have experienced open system behavior and loss of radiogenic Pb. While this technique has been shown to improve the accuracy and precision of TIMS dating, its application to high-spatial resolution dating methods, such as secondary ion mass spectrometry (SIMS), is relatively uncommon. In our efforts to U-Pb date zircons from the late Eocene Caetano caldera by SIMS (SHRIMP-RG: sensitive high resolution ion microprobe, reverse geometry), some grains yielded anomalously young U-Pb ages that implicated Pb-loss and motivated us to investigate with a comparative CA and non-CA dating study. We present CA and non-CA 206Pb/238U ages and trace elements determined by SHRIMP-RG for zircons from three Caetano samples (Caetano Tuff, Redrock Canyon porphyry, and a silicic ring-fracture intrusion) and for R33 and TEMORA-2 reference zircons. We find that non-CA Caetano zircons have weighted mean or bimodal U-Pb ages that are 2–4% younger than CA zircons for the same samples. CA Caetano zircons have mean U-Pb ages that are 0.4–0.6 Myr older than the 40Ar/39Ar sanidine eruption age (34.00 ± 0.03 Ma; error-weighted mean, 2σ), whereas non-CA zircons have ages that are 0.7–1.3 Myr younger. U-Pb ages do not correlate with U (~ 100–800 ppm), Th (~ 50–300 ppm) or any other measured zircon trace elements (Y, Hf, REE), and CA and non-CA Caetano zircons define identical trace element ranges. No statistically significant difference in U-Pb age is observed for CA versus non-CA R33 or TEMORA-2 zircons. Optical profiler measurements of ion microprobe pits demonstrate consistent depths of ~ 1.6

  8. The Dabie Orogen as the early Jurassic sedimentary provenance: Constraints from the detrital zircon SHRIMP U-Pb dating

    Institute of Scientific and Technical Information of China (English)

    LI Renwei; WAN Yusheng; CHENG Zhenyu; ZHOU Jianxiong; XU Yunhua; LI Zhong; JIANG Maosheng

    2005-01-01

    The SHRIMP U-Pb ages of detrital zircon from the oldest Mesozoic strata, the Fanghushan Fomation, in the Hefei Basin range from 200 Ma to ca. 2500 Ma, which indicates that the Dabie Orogen as the early Jurassic sedimentary provenance was complex. The composition of the Dabie Orogen includes: the Triassic high pressure-ultrahigh pressure metamorphic rocks, of which the detrital zircon ages are from 234 Ma to 200 Ma; the rocks possibly related to the Qinling and Erlangping Groups representing the southern margin of the Sino-Korean craton in the Qinling and Dabie area, of which the detrital zircon has an age of 481-378 Ma; the Neoproterozoic rocks originated from the Yangtze croton, of which the detrital zircon ages are 799-721 Ma old; and the rocks with the detrital zircon ages of ca. 2000 Ma and ca. 2500 Ma, which could be the old basement of the Yangtze craton.

  9. U-Pb zircon geochronology of Caledonian age orthogneisses dredged from the Chukchi Borderland, Arctic Ocean.

    Science.gov (United States)

    Brumley, K.; Miller, E. L.; Mayer, L. A.; Wooden, J.; Grove, M.

    2012-04-01

    Over 500 kilos of metamorphic rock was dredged from outcrops along a steep normal fault scarp in the central Chukchi Borderland in 2009 (HLY0905) from water depths of between about 2500-1400m. The rocks in the dredge included broken angular cobbles and boulder-sized samples of amphibolites, orthogneisses, and granitoids of the same amphibolite facies metamorphic grade, as well as gravel to small cobble-sized ice rafted debris of various rock types. Zircons were separated from two of the orthogneiss samples, and single grain zircon U-Pb ages were determined by SHRIMP analysis to be 428 Ma ± 3.4 for both samples (N=60). Several zircon grains had distinct igneous cores that ranged in age from about 928-1200 Ma (n=7) with two older grains (1700, 1760 Ma). The Caledonian orogenic belt developed in the Ordovician to Devonian affecting northern Europe, Greenland and Arctic Canada. Caledonian deformational trends continue into the Arctic and disappear at the rifted margin of the Arctic Ocean. Syn-orogenic magmatism in the Barents region date deformation in this region during the Caledonian event to have occurred between about 450-410 Ma (Johansson et al., 2005; Gee et al., 2006; Gee and Tebenkov, 2004). Grenville age plutons (900-1250Ma) that were later involved in Caledonian deformation and intruded by 410-450 Ma aged plutons are found on western and eastern Svalbard (Johansson et al., 2005), eastern Greenland, and the Pearya Terrane of northern Ellesmere Island (Trettin,1986, 1992). The Franklinian basement of Arctic Alaska and Canada do not share these Grenvillian ages (Trentin et al, 1987). This suggests that the inherited zircon cores in the Chukchi Borderland orthogneisses were derived, at least in part, from an older Grenvillian basement like that of Pearya, Svalbard and parts of Greenland, or through sediments eroded from these sources, and later intruded by Caledonian aged granites. This constrains the pre-rift location of the Chukchi Borderland to be within the

  10. Imaging mass spectrometry of elements in forensic cases by LA-ICP-MS.

    Science.gov (United States)

    Lauer, Estelle; Villa, Max; Jotterand, Morgane; Vilarino, Raquel; Bollmann, Marc; Michaud, Katarzyna; Grabherr, Silke; Augsburger, Marc; Thomas, Aurélien

    2017-03-01

    Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) was performed to map elements in thin formalin-fixed paraffin-embedded tissue sections of two forensic cases with firearm and electrocution injuries, respectively. In both cases, histological examination of the wounded tissue regions revealed the presence of exogenous aggregates that may be interpreted as metallic depositions. The use of imaging LA-ICP-MS allowed us to unambiguously determine the elemental composition of the observed aggregates assisting the pathologist in case assessments. To the best of our knowledge, we demonstrate for the first time the use of imaging LA-ICP-MS as a complementary tool for forensic pathologists and toxicologists in order to map the presence of metals and other elements in thin tissue sections of post-mortem cases.

  11. Quantitative characterization of single cells by use of immunocytochemistry combined with multiplex LA-ICP-MS.

    Science.gov (United States)

    Mueller, Larissa; Herrmann, Antje J; Techritz, Sandra; Panne, Ulrich; Jakubowski, Norbert

    2017-05-01

    Actual research demonstrates that LA-ICP-MS is capable of being used as an imaging tool with cellular resolution. The aim of this investigation was the method development for LA-ICP-MS to extend the versatility to quantitative and multiplexing imaging of single eukaryotic cells. For visualization of individual cells selected, lanthanide-labeled antibodies were optimized for immuno-imaging of single cells with LA-ICP-MS. The molar content of the artificial introduced labels per cell was quantified using self-made nitrocellulose-coated slides for matrix-matched calibration and calculated amounts were in the range of 3.1 to 17.8 atmol per cell. Furthermore, the quantification strategy allows a conversion of 2D intensity profiles based on counts per second (cps) to quantitative 2D profiles representing the molar amount of the artificial introduced elemental probes per pixel for each individual cell. Graphical abstract ᅟ.

  12. Cretaceous Volcanic Events in Southeastern Jilin Province, China: Evidence from Single Zircon U-Pb Ages

    Institute of Scientific and Technical Information of China (English)

    CHEN Yuejun; SUN Chunlin; SUN Yuewu; SUN Wei

    2008-01-01

    Mesozoic volcanic rocks in southeastern Jilin Province are an important component of the huge Mesozoic volcanic belt in the northeastern area. Study of the age of their formation is of great significance to recognize Mesozoic volcanic rule in northeastern China. Along with the research of rare Mesozoic biota and extensive Mesozoic mineralization in western Liaoning, a number of researchers have focused on Mesozoic volcanic events. The authors studied the ages of the Cretaceous volcanic rocks in southeastern Jilin Province using single Zircon U-Pb. The result shows that the Sankeyushu Formation volcanic rocks in the Tonghua area are 119.2 Ma in age, the Yingcheng Formation in the Jiutai area 113.4±3.1 Ma, the Jinjiatun Formation in Pinggang Town of Liaoyuan City and the Wufeng volcanic rocks in the Yanji area 103.2±4.7 Ma and 103.6±1 Ma, respectively. Combined with the data of recent publication on volcanic rocks ages; the Cretaceous volcanic events in southeastern Jilin Province can be tentatively subdivided into three eruption periods: 119 Ma, 113 Ma and 103 Ma. The result not only provides important chronology data for subdividing Mesozoic strata in southeastern Jilin Province, establishing Mesozoic volcanic event sequence, discussing geological tectonic background, and surveying the relation between noble metals to the Cretaceous volcanic rocks, but also otters important information of Mesozoic volcanism in northeastern China.

  13. Zircon U-Pb age of the Shacun gabbro body,Yuexi,Dabie orogen and its geological implications

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The single grain zircon U-Pb age of the Shacun mafic-ultramafic intrusion,Yuexi,North Dabie is (128.1±2.0) Ma.This date indicates that the intrusion was implaced at Yanshanian when most Mesozoic granitoids were intruded.It was not the syn-collisional intrusion related to the subduction of the Yangtze Block and ultrahigh-pressure metamorphism at Indosinian.

  14. Age and genesis of the Myanmar jadeite: Constraints from U-Pb ages and Hf isotopes of zircon inclusions

    Institute of Scientific and Technical Information of China (English)

    QIU ZhiLi; WU FuYuan; YANG ShuFeng; ZHU Min; SUN JinFeng; YANG Ping

    2009-01-01

    Myanmar jadeite (jadeitite) is well known for its economical value and distinctive tectonic locality within the collisional belt between India and Eurasian plates. However, it is less studied for its genesis and geodynamic implications due to precipitous topography, adverse weather and local military conflicts in the area. By means of combined ICP-MS and LA-MC-ICPMS techniques, we have carried out in-situ trace elements, U-Pb and Lu-Hf isotopes for zircon inclusions in a piece of jadeite gem sample. CL imaging suggests that the zircons are metasomatic in origin, and contain mineral inclusions of jadeite and omphacite. Seventy-five analyses on 16 grains of the zircons yield a U-Pb age of 158±2 Ma. The Myanmar zircons differ from other types in that they have no significant Eu anomalies despite high HREE concentrations. Measured 176Hf/177Hf ratios range from 0.282976 to 0.283122, with an average value of 0.283066±7;εHf(t) value of 13.8±0.3 (n=75). These results indicate that the Myanmar jadeite was formed in the Late Jurassic, probably by interaction of fluid released from subducted oceanic slab with mantle wedge. Therefore, its formation has no genetic relationship to the continental collision between Indian and Euroasian plates.

  15. Investigating sources of ignimbrites in the Altiplano-Puna Volcanic Complex using U-Pb dating of zircons

    Science.gov (United States)

    Kern, J. M.; de Silva, S. L.; Schmitt, A. K.

    2011-12-01

    Large silicic volcanic fields (LSVFs) are thought to represent the surface expression of upper crustal batholith emplacement, with the spatiotemporal distribution of the vents and eruptions representing the development of the system. The Altiplano-Puna Volcanic Complex (APVC) in the Central Andes is a LSVF active from 11-1 Ma that erupted over 13,000 km3 of magma from large, multicyclic caldera centers and smaller ignimbrite shields during 3 distinct pulses of volcanism at 8.4, 5.5, and 4.0 Ma. Links to the magmatic system beneath are being pursued through U-Pb zircon dating of APVC ignimbrites. Initial results comprise 61 238U/206Pb zircon ages of mostly marginal crystal domains from five APVC ignimbrites-the 0.98 ± 0.03 Ma Purico, 3.96 ± 0.08 Ma Atana, 4.0 ± 0.9 Ma Toconao, 4.09 ± 0.02 Ma Puripicar, and 8.33 ± 0.06 Ma Sifon ignimbrites-dated by high-resolution secondary ionization mass spectrometry (SIMS). Each zircon analyzed was less than 350 μm in length and cathodoluminescence images reveal zonations within individual zircons, though significant core-rim age differences are rare. The ~1 Ma Purico ignimbrite displays multiple zircon age populations significantly predating the 40Ar/39Ar eruption age, but younger than ages from the nearby large-volume Atana ignimbrite erupted from La Pacana caldera. Some peaks do, however, coincide with later resurgent activity within La Pacana as expressed by the 2.7 Ma Cerro Bola dome. Zircon ages in the Atana ignimbrite are indistinguishable from its eruption, while those from the 4.0 Ma Toconao ignimbrite-the volatile-rich cap of the Atana magma chamber-contains three populations of xenocrystic zircons from the Proterozoic-Ordivician, ~13 Ma, and ~9 Ma. The ~9 Ma zircons correlate with K-Ar ages from an underlying ignimbrite, whereas the 13 Ma xenocrysts likely have a plutonic source. The Purico ignimbrite thus provides direct evidence of zircon inheritance from previous eruption cycles, while the Toconao records a

  16. Zircon U-Pb Dating of the Lamprophyre in the Xikuangshan Mining District, Central Hunan and its Geological Implications%湘中锡矿山矿区煌斑岩中捕获锆石U-Pb定年及其地质意义

    Institute of Scientific and Technical Information of China (English)

    彭建堂; 胡阿香; 张龙升; 雷文艳; 阳杰华; 林芳梅

    2014-01-01

    The giant Xikuangshan deposit, located in the Xiangzhong Basin, Central Hunan, is the largest antimony deposit in the world. In spite of numerous detailed geological investigations and geochemical researches have been carried out, the sources and tectonic background of the giant ore deposit is unclear. The lamprophyre dyke occurring in the eastern part of the mining district probably can shed light on these issues. LA-ICP-MS U-Pb isotopic dating has been conducted on zircon grains collected from the lamprophyre dyke in the Xikuangshan mining district. The zircon grains are usually subhedral or sub-rounded, and exhibit typical oscillatory or sector zoning under cathodoluminescence. Both its the morphology and geochemical signatures (Th/U ratio and REE chondrite-normalized distribution pattern) of these zircon grains reveals that they are predominately of magmatic origin, and were probably captured from the wall rocks during magma ascending. The zircon U-Pb ages mainly vary in the range of 830 Ma to 800 Ma, which coincide well with the ages of the Neoproterozoic Lengjiaxi Group and Banxi Group occurred in the adjacent Xufeng Range, implying the possible existence of underlying Precambrian clastic basement in the Xiangzhong Basin. The inferred Precambrian basement lays foundation for the further understanding for tracing the ore-forming metal of the giant Xikuangshan deposit and determining the tectonic nature of the Xiangzhong Basin. The Neoproterozoic basement underlying in the Xiangzhong Basin might have provided Sb for the giant ore accumulation in the Xikuangshan mining district. Tectonically, the Xiangzhong Basin should belong to the Yangtze Block rather than the Cathaysian Block as was previously considered. The lamprophyre in the Xikuangshan mining district formed under the geodynamic setting of crustal extension, and emplaced at a depth of at least 5 kilometers.%利用 LA-ICP-MS 技术,对湘中锡矿山煌斑岩中的锆石进行 U-Pb 同位素定年。研

  17. Petrogenesis and zircon U-Pb dating of skarnified pyroxene-bearing dioritic rocks in Bisheh area, south of Birjand, eastern Iran

    Directory of Open Access Journals (Sweden)

    Malihe Nakhaei

    2014-10-01

    Full Text Available Introduction The study area is located 196 km south of Birjand in eastern border of the Lut block Berberian and King, 1981 in eastern Iran between 59°05′35" and 59°09′12" E longitude and 31°42′29" and 31°44′13" N latitude. The magmatic activity in the Lut block began in the middle Jurassic such as Kalateh Ahani, Shah Kuh and Surkh Kuh granitoids that are among the oldest rocks exposed within the Lut block (Esmaeily et al., 2005; Tarkian et al., 1983; Moradi Noghondar et al., 2011-2012. Eastern Iran, and particularly the Lut block, has great potential for different types of mineralization as skarnification in Bisheh area which has been studied in this paper. The goal of this study is to highlight the geochronology, geochemistry of major and trace elements, Rb-Sr, Sm-Nd isotopes for skarnified pyroxene-bearing diorites. Materials and methods Major element compositions of thirteen samples were determined by wavelength-dispersive X-ray fluorescence (XRF spectrometry, using fused discs and the Phillips PW 1410 XRF spectrometer at Ferdowsi University, Mashhad, Iran. These samples were analysed for trace elements using inductively coupled plasma-mass spectrometry (ICP-MS in the Acme Analytical Laboratories, Vancouver, British Columbia, Canada. Zircon grains were separated from pyroxene diorite porphyrys using heavy liquid and magnetic techniques at the Institute of Earth Sciences, Academia Sinica, Taipei, Taiwan. Zircon U-Pb dating was performed by laser ablation-inductively-coupled plasma-mass spectrometry (LA-ICP-MS, using an Agilent 7500 s machine and a New Wave UP213 laser ablation system, equipped at the Dr Shen-Su Sun memorial laboratory in the Department of Geosciences, National Taiwan University, Taiwan. Strontium and Nd isotopic analyses were performed on a six-collector Finnigan MAT 261 thermal-ionization mass spectrometer at the University of Colorado, Boulder, Colorado, United States. 87Sr/86Sr ratios were determined using four

  18. Sm-Nd and zircon SHRIMP U-Pb dating of Huilanshan mafic granulite in the Dabie Mountains and its zircon trace element geochemistry

    Institute of Scientific and Technical Information of China (English)

    HOU; Zhenhui; LI; Shuguang; CHEN; Nengsong; LI; Qiuli; LIU

    2005-01-01

    The mafic granulites from Huilanshan are outcropped on the center of the Luotian dome in the northern Dabie Mountains. The Sm-Nd isochron defined by granulite-facies metamorphic minerals (garnet + clinopyroxene + hypersthene) yields an age of 136(±)18 Ma indicating the early Cretaceous granulite-facies metamorphism. The cathodoluminescence (CL) images of zircons from the granulite show clearly core-mantle-rim structures. The zircon cores are characterized by typical oscillatory zoning and highly HREE enriched patterns, which suggests their magma origin. Some zircon cores among them with little Pb loss give SHRIMP U-Pb ages ranging from 753 to 780 Ma, which suggests that the protolith of Huilanshan granulite is Neoproterozoic mafic rocks. The zircon mantles usually cut across the oscillatory zone of the zircon cores have 3―10 times lower REE, Th, U, Y, Nb and Ta contents than the igneous zircon cores but have high common Pb contents. These characteristics suggest that they were formed by hydrothermal alteration of the igneous zircons. The part of zircon mantles with little Pb loss give a similar SHRIMP U-Pb age (716―780 Ma) to the igneous zircon cores, which implies that the hydrothermal events occurred closely to the magmatic emplacement. In view of the strong early Cretaceous magmatism in the Luotian dome, consequently, the Huilanshan mafic granulite was formed by heating of the Neoproterozoic mafic rocks in mid-low crust, which caused the granulite-facies metamorphism underneath the Dabie Mountains. The similarity between the granulite metamorphic age (136±18 Ma) defined by Sm-Nd isochron and K-Ar age of 123―127 Ma given by amphible from the gneiss in Luotian dome suggests a rapid uplifting of the Luotian dome, which may result in further exhumation of the ultrahigh pressure metamorphic rocks in the Dabie Mountains.

  19. Zircon SHRIMP U-Pb age of garnet olivine pyroxenite at Hujialin in the Sulu terrane and its geological significance

    Institute of Scientific and Technical Information of China (English)

    GAO Tianshan; CHEN Jiangfeng; XIE Zhi; YANG Shenghong; YU Gang

    2004-01-01

    Garnet olivine pyroxenite at Hujialin is situated in the Sulu ultrahigh pressure (UHP) metamorphic belt, Shandong Province. Most of the zircon separated from the rock is well crystallized, prismatic and granular with a length to width ratio of 1︰1.3-1︰2.5. CL and BSE images show the magmatic oscillatory zoning in the zircon. Th/U ratio ranges from 0.99 to 2.81. These suggest a magmatic origin for the zircon studied. SHRIMP dating yields 206Pb/238U ages of 207-223 Ma, with a weighted average of 216±3 Ma. This age corresponds to zircon growth during exhumation of UHP slab and thus the timing of amphibolite-facies retrogression. The garnet olivine pyroxenite was wrapped and brought to the crust by the UHP slab during exhumation, and then suffered from metasomatism by fluid from the UHP slab itself. The zircon U-Pb age records the timing of the crystallization of metasomatic melt. Therefore, fluid that was released during exhumation of deeply subducted continental slab may be the important source for zircon growth.

  20. Zircon U-Pb dating and geochemical study of the Xianggou granite in the Ma’anqiao gold deposit and its relationship with gold mineralization

    Institute of Scientific and Technical Information of China (English)

    LEE; Ben

    2010-01-01

    Single zircon LA-ICP-MS U-Pb dating and lithogeochemical studies have been performed on the Xianggou monzonitic granitic porphyry outcropped in the Ma’anqiao gold deposit.A weighted average U-Pb age of 242.0±0.8 Ma for Xianggou monzonitic porphyry has been obtained.This corresponds with the conclusions of previous studies indicating a syn-orogenic age (242±21 Ma) of the Qinling Orogenic Belt,suggesting that the formation of the Xianggou granite should be associated with the collisional event of the North China Plate and the Yangtze Plate in the Indosinian period.The Xianggou granite is characterized by the high silicon and alkali of high K calc-alkaline series granites.It is rich in Al (Al2O3=14.49%-15.61%) and Sr (457.10-630.82 ppm),poor in Y (<16 ppm) and HREE (Yb<0.45 ppm),and exhibits high ratios of Sr/Y (76.24-97.34) and (La/Yb)N (29.65-46.10),as well as strongly fractionated REE patterns.These geochemical characteristics suggest the Xianggou granite can be classified as C-type adakitic rock.The initial Sr isotope ratios for the Xianggou granite vary from 0.70642 to 0.70668,εNd(t) values from -4.54 to -3.98,and TDM values from 1152 Ma to 1220 Ma.The low εNd(t) and ISr and high TDM values,as well as Na2O/K2O ratios of the Xianggou granite are close to 1 (Na2O/K2O=0.95-1.10),indicating that it is not an I-type adakite formed by partial melting of the subducting oceanic crust,nor adakitic rock formed by melting of the underplated basaltic lower crust,but the product of partial melting of the nonunderplated basaltic thickened lower crust.Zircons from the Xianggou pluton have a homogeneous Hf isotopic composition with negative εHf(t) values (between -9.7 and -5.9,with an average of -6.9),indicating that the rock-forming materials were mostly extracted from the ancient crust,not from the depleted mantle.The Xianggou monzonitic granitic porphyry is rich in LILE and LREE and depleted in HSFE,HREE and Y;the composition of trace element and REE are similar to

  1. The Triassic reworking of the Yunkai massif (South China): EMP monazite and U-Pb zircon geochronologic evidence

    Science.gov (United States)

    Chen, Cheng-Hong; Liu, Yung-Hsin; Lee, Chi-Yu; Sano, Yuji; Zhou, Han-Wen; Xiang, Hua; Takahata, Naoto

    2017-01-01

    Geohistory of the Yunkai massif in South China Block is important in understanding the geodynamics for the build-up of this block during the Phanerozoic orogenies. To investigate this massif, we conduct EMP monazite and U-Pb zircon geochronological determinations on mineral inclusions and separate for seventeen samples in four groups, representing metamorphic rocks from core domain, the Gaozhou Complex (amphibolite facies, NE-striking) and the Yunkai Group (greenschist facies, NW-striking) of this massif and adjacent undeformed granites. Some EMP monazite ages are consistent with the NanoSIMS results. Monazite inclusions, mostly with long axis parallel to the cleavage of platy and elongated hosts, give distinguishable age results for NW- and NE-trending deformations at 244-236 Ma and 236-233 Ma, respectively. They also yield ages of 233-230 Ma for core domain gneissic granites and 232-229 Ma for undefomed granites. Combining U-Pb zircon ages of the same group, 245 Ma and 230 Ma are suggested to constrain the time of two phases of deformation. Aside from ubiquity of Triassic ages in studied rocks, ages of detrital monazite in the meta-sandstone match the major U-Pb zircon age clusters of the metamorphic rock that are largely concentrated at Neoproterozoic (1.0-0.9 Ga) and Early Paleozoic (444-431 Ma). Based on these geochronological data, Triassic is interpreted as representing the time for recrystallization of these host minerals on the Early Paleozoic protolith, and the also popular Neoproterozoic age is probably inherited. With this context, Yunkai massif is regarded as a strongly reactivated Triassic metamorphic terrain on an Early Paleozoic basement which had incorporated sediments with Neoproterozoic provenances. Triassic tectonic evolution of the Yunkai massif is suggested to have been controlled by converging geodynamics of the South China and Indochina Blocks as well as mafic magma emplacement related to the Emeishan large igneous province (E-LIP).

  2. Elemental Analysis and Comparison of Bulk Soil Using LA-ICP-MS and LIBS methods

    Science.gov (United States)

    Almirall, J.

    2012-04-01

    Elemental analysis methods utilizing Laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) and laser-induced breakdown spectroscopy (LIBS) were developed and used in the characterization of soil samples from the US and Canada as part of a comprehensive forensic evaluation of soils. A LA-ICP-MS method was recently optimized for analysis and comparison between different soil samples in an environmental forensic application [1,2] and LIBS has recently attracted the interest of analytical chemists and forensic laboratories as a simpler, lower cost alternative to the more established analytical methods. In developing a LIBS method, there are many parameters to consider, including laser wavelength, spectral resolution, sensitivity, and matrix effects. The first LIBS method using a 266 nm laser for forensic soil analysis has also been recently reported by our group [3]. The results of an inter-laboratory comparison involving thirteen (13) laboratories conducting bulk elemental analysis by various methods are also reported. The aims of the inter-laboratory tests were: a) to evaluate the inter-laboratory performance of three methods (LA-ICP-MS, µXRF and LIBS) in terms of accuracy (bias), precision (relative standard deviation, RSD) and sensitivity using standard reference materials (SRMs); b) to evaluate the newly released NIST SRM 2710a, which supersedes 2710; and c) to evaluate the utility of LIBS as an alternative technique to LA-ICP-MS and µXRF for bulk analysis of soils. Each sample and standard was homogenized in a high-speed ball mill and pressed into pellets. Participants were instructed to measure the following elements: 7Li, 25Mg, 27Al, 42Ca, 45Sc, 47,49Ti, 51V, 55Mn, 88Sr, 137Ba, 206,207,208 Pb (LA-ICP-MS); Ti, Cr, Mn, Fe, Cu, Sr, Zr, Pb (µXRF); Ba, Cr, Cu, Fe, Li, Mg, Mn, Pb, Sr, Ti, Zr (LIBS). For both LIBS and µXRF, the choice of appropriate spectral lines was determined by the user, optimizing for linearity, sensitivity and precision

  3. Trace element signature and U-Pb geochronology of eclogite-facies zircon, Bergen Arcs, Caledonides of W Norway

    Science.gov (United States)

    Bingen, Bernard; Austrheim, Håkon; Whitehouse, Martin J.; Davis, William J.

    Secondary-ion mass spectrometry (SIMS) U-Pb and trace element data are reported for zircon to address the controversial geochronology of eclogite-facies metamorphism in the Lindås nappe, Bergen Arcs, Caledonides of W Norway. Caledonian eclogite-facies overprint in the nappe was controlled by fracturing and introduction of fluid in the Proterozoic-Sveconorwegian-granulite-facies meta-anorthosite-norite protolith. Zircon grains in one massive eclogite display a core-rim structure. Sveconorwegian cores have trace element signatures identical with those of zircon in the granulite protolith, i.e. 0.31<=Th/U<=0.89, heavy rare earth element (HREE) enrichment, and negative Eu anomaly. Weakly-zoned to euhedral oscillatory-zoned Caledonian rims are characterized by Th/U<=0.13, low LREE content (minimum normalized abundance for Pr or Nd), variable enrichment in HREE, and no Eu anomaly. A decrease of REE towards the outermost rim, especially HREE, is documented. This signature reflects co-precipitation of zircon with garnet and clinozoisite in a feldspar-absent assemblage, and consequently links zircon to the eclogite-facies overprint. The rims provide a mean 206Pb/238U crystallization age of 423+/-4 Ma. This age reflects eclogite-forming reactions and fluid-rock interaction. This age indicates that eclogite-facies overprint in the Lindås nappe took place at the onset of the Scandian (Silurian) collision between Laurentia and Baltica.

  4. U-Pb zircon dating constraints on formation time of Qilian high-grade metamorphic rock and its tectonic implications

    Institute of Scientific and Technical Information of China (English)

    XU WangChun; ZHANG HongFei; LIU XiaoMing

    2007-01-01

    In order to constrain the formation time of high-grade metamorphic rocks in the Qilian Mountains, U-Pb zircon dating was carried out by using LA-ICPMS technique for a paragneiss of the Hualong Group in the Qilian Mountains basement series and a weakly foliated granite that intruds into the Hualong Group. Zircons from the paragneiss consist dominantly of detrital magma zircons with round or sub-round shape. They have 207Pb/206Pb ages mostly ranging from 880 to 900 Ma, with a weighted mean age of 891±9 Ma, which is interpreted as the magma crystallization age of its igneous provenance and can be taken as a lower age limit for the Hualong Group. Magma crystallization age for the weak-foliated granite is 875±8 Ma, which can be taken as an upper age limit for the Hualong Group. Accordingly, the formation time of the Hualong Group is constrained at sometime between 875 and 891 Ma. A few zircons from both paragneiss and weak-foliated granite display old inherited ages of 1000 to 1700 Ma and young metamorphic ages of Early Paleozoic. The zircon age distribution pattern confirms that the Qilian Mountains and the northern margin of Qaidam Basin had a united basement, with geotectonic affinity to the Yangtze Block. The results also reveal that sediments of the Hualong Group formed by rapid accumulation due to rapid crustal uplift-erosion. This process may result from intensive Neoproterozoic orogenesis due to assembly of the suppercontinent Rodinia.

  5. Palaeoproterozoic U Pb SHRIMP zircon age from basement rocks in Bangladesh: A possible remnant of the Columbia supercontinent

    Science.gov (United States)

    Hossain, Ismail; Tsunogae, Toshiaki; Rajesh, Hariharan M.; Chen, Bin; Arakawa, Yoji

    2007-12-01

    We present new U-Pb SHRIMP zircon geochronological data for basement rocks in Bangladesh, and discuss the relationship with the formation of the Columbia supercontinent. Euhedral zircons from a diorite sample yield a concordia age of 1730 ± 11 Ma, which is interpreted as the crystallization age. The Palaeoproterozoic age of the examined basement rock and the common occurrences of similar ˜1.7-Ga geologic units in the Central Indian Tectonic Zone and Meghalaya-Shillong Plateau in Indian Shield suggest their apparent continuation. This, together with the occurrence of similar ˜1.7-Ga geologic units in the Albany-Fraser belt in Australia and East Antarctica, are used to suggest that the basement rocks in Bangladesh formed towards the final stages of the assembly of the Columbia supercontinent.

  6. Timing of the granulite facies metamorphism in the Sanggan area, North China craton: zircon U-Pb geochronology

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Zircon U-Pb ages are reported for three samples of intrusive rocks in Khondalite series in the Sanggan area, North China craton. The age of meta-granite is dated as 2005±9 Ma, implying that the sedimentary sequences in Khondalites series formed before 2.0Ga. The age of 1921 ±1Ma for the meta-diorite constrain the age of granulite facies metamorphism younger than this date. The age of 1892±10 Ma for garnet granite is obtained, but the granite crystallization age seems a little younger than the date considering the morphology of zircons. On the basis of these dates and of a concise review of previous age data, it is inferred that the Khondalite series was subjected to granulite facies metamorphism at about 1.87Ga together with tonalitic granulites and HP basic granulites in the Sanggan area.

  7. Bioimaging of metals by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS).

    Science.gov (United States)

    Becker, J Sabine; Zoriy, Miroslav; Matusch, Andreas; Wu, Bei; Salber, Dagmar; Palm, Christoph; Becker, J Susanne

    2010-01-01

    The distribution analysis of (essential, beneficial, or toxic) metals (e.g., Cu, Fe, Zn, Pb, and others), metalloids, and non-metals in biological tissues is of key interest in life science. Over the past few years, the development and application of several imaging mass spectrometric techniques has been rapidly growing in biology and medicine. Especially, in brain research metalloproteins are in the focus of targeted therapy approaches of neurodegenerative diseases such as Alzheimer's and Parkinson's disease, or stroke, or tumor growth. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) using double-focusing sector field (LA-ICP-SFMS) or quadrupole-based mass spectrometers (LA-ICP-QMS) has been successfully applied as a powerful imaging (mapping) technique to produce quantitative images of detailed regionally specific element distributions in thin tissue sections of human or rodent brain. Imaging LA-ICP-QMS was also applied to investigate metal distributions in plant and animal sections to study, for example, the uptake and transport of nutrient and toxic elements or environmental contamination. The combination of imaging LA-ICP-MS of metals with proteomic studies using biomolecular mass spectrometry identifies metal-containing proteins and also phosphoproteins. Metal-containing proteins were imaged in a two-dimensional gel after electrophoretic separation of proteins (SDS or Blue Native PAGE). Recent progress in LA-ICP-MS imaging as a stand-alone technique and in combination with MALDI/ESI-MS for selected life science applications is summarized.

  8. U-Pb zircon constraints on the age and provenance of the Rocas Verdes basin fill, Tierra del Fuego, Argentina

    Science.gov (United States)

    Barbeau, David L.; Gombosi, David J.; Zahid, Khandaker M.; Bizimis, Michael; Swanson-Hysell, Nicholas; Valencia, Victor; Gehrels, George E.

    2009-12-01

    The Late Jurassic to Early Cretaceous Rocas Verdes basin constitutes one of the most poorly understood components of the southernmost Andes. As a result, accurate reconstructions and interpretations of deformation associated with the Andean orogeny and the kinematics of Scotia arc development also remain poorly constrained. In this data brief, we report U-Pb zircon ages from sandstones of the Rocas Verdes basin fill and from a crosscutting pluton in the southernmost Andes of Argentine Tierra del Fuego. Detrital samples contain predominant Early to early Middle Cretaceous (circa 130-105 Ma) U-Pb zircon age populations, with very small or single-grain middle Mesozoic and Proterozoic subpopulations. A very small subpopulation of Late Cretaceous ages in one sample raises the unlikely possibility that parts of the Rocas Verdes basin are younger than perceived. A sample from a crosscutting syenitic pegmatite yields a crystallization age of 74.7 +2.2/-2.0 Ma. The data presented herein encourage further geochronologic evaluation of the Rocas Verdes basin in order to better constrain the depositional ages and provenance of its contents.

  9. U-Pb ages of detrital zircon and provenances of Red Clay in the Chinese Loess Plateau

    Science.gov (United States)

    Gong, Hujun; Xie, Wenbin; Zhang, Rui; Zhang, Yunxiang

    2017-05-01

    The Chinese Loess Plateau (CLP), which is located in the central part of China, mainly contains two sequences: the Quaternary loess-paleosol sequence and the late Miocene-Pliocene Red Clay sequence. U-Pb ages of detrital zircon from the Quaternary loess-paleosol sequences indicate that the current spatial pattern of central Asian aridification was largely established during the early Quaternary. U-Pb ages of detrital zircon from the underlying Red Clay sequences demonstrate that the northern source regions were important contributors for the dust since the late Miocene, except for the periods of ∼8 Ma and ∼5.5 to ∼4 Ma. These two periods correspond to increased and decreased dust deposition in the North Pacific, respectively, ascribed to the late Miocene aridification of the Qaidam Basin (in the west of the CLP) and the early Pliocene aridification of the Tarim Basin (in the west of the CLP). We attribute the increase of the Qaidam Basin-derived North Pacific dust fluxes to the uplift of the NE Tibetan Plateau. Such uplift also controlled the climatic and environmental changes in central Asian during the late Miocene. This study highlights the dynamical process of the central Asian aridification during the late Miocene-Pliocene.

  10. Zircon U-Pb Age Determination of Volcanic Eruptions in Lutao and Lanyu in the Northern Luzon Magmatic Arc

    Directory of Open Access Journals (Sweden)

    Wen-Yu Shao

    2014-01-01

    Full Text Available This paper reports for the first time zircon U-Pb ages of volcanic rocks and sands from Lutao and Lanyu, two islets off SE Taiwan in the north Luzon arc. The samples include (1 seven andesites from four volcanic units and three river/beach sands from Lutao and (2 five basaltic andesites from four volcanic units and two river/beach sands from Lanyu. The Lutao andesites contain abundant magmatic zircons, aging from ~1.54 to ~1.24 Ma for individual sample, which yielded an overall mean 206Pb/238U age of 1.31 ±± 0.03 Ma (n = 190, MSWD = 2.6. This is slightly older than, or broadly coincident with, a mean 206Pb/238U age of 1.23 ±± 0.03 Ma (n = 103, MSWD = 1.9 given by detrital zircons from the three sands. The Lanyu volcanics appear to have less abundant magmatic zircons, aging from ~2.72 to ~2.35 Ma for individual sample, which yielded an overall mean 206Pb/238U age of 2.61 ±± 0.13 Ma (n = 11, MSWD = 1.8. This accords with a mean 206Pb/238U age of 2.69 ±± 0.11 Ma (n = 34, MSWD = 4.7 obtained by detrital zircons from the two sands. The age data suggest that in Lutao and Lanyu the major volcanic eruptions occurred at ~1.3 and ~2.6 Ma, respectively. Moreover, volcanic samples from both islets contain various amounts of older inherited zircons, ~11% in Lutao and up to ~82% in Lanyu, which together with detrital zircons from the sands show main age peaks at ~150 Ma and ~1.9 and ~2.5 Ga, consistent with the notion for a _ continental crust involved in the genesis of the northern Luzon magmatic arc.

  11. Sediment provenance, reworking and transport processes in the Indus River by U-Pb dating of detrital zircon grains

    Science.gov (United States)

    Alizai, Anwar; Carter, Andrew; Clift, Peter D.; VanLaningham, Sam; Williams, Jeremy C.; Kumar, Ravindra

    2011-03-01

    We present new major and trace element data, together with U-Pb ages for zircon sand grains from the major tributaries of the Indus River, as well as the adjacent Ghaggar and Yamuna Rivers and from bedrocks within the Sutlej Valley, in order to constrain the origin of the sediment reaching the Arabian Sea. Zircon grains from the upper Indus are generally younger than 200 Ma and contrast with those from the eastern tributaries eroded from Himalayan sources. Grains younger than 15 Ma, which typify the Nanga Parbat Massif, comprise no more than 1-2% of the total, even in the upper Indus, showing that this terrain is not a major sediment producer, in contrast with the Namche Barwe Massif in the eastern Himalayan syntaxis. The Sutlej and Yamuna Rivers in particular are very rich in Lesser Himalayan-derived 1500-2300 Ma zircons, while the Chenab is dominated by 750-1250 Ma zircons, mostly eroded from the Greater Himalaya. The upper Indus, Chenab and Ravi yield zircon populations broadly consistent with the outcrop areas, but the Jhelum and the Sutlej contain many more 1500-2300 Ma zircons than would be predicted from the area of Lesser Himalayan rock within their drainages. A significant population of grains younger than 200 Ma in the sands of the Thar Desert indicates preferential eolian, monsoon-related transport from the Indus lower reaches, rather than reworking from the local rivers. Modelling of observed zircon ages close to the delta contrasts with modern water discharge. The delta is rich in zircons dating 1500-2300 Ma, while discharge from modern rivers carrying such grains is low. The modest size of the Sutlej, the richest source of these materials in the modern system, raises the possibility that the compositionally similar Yamuna used to flow westwards in the recent past. Our data indicate a non-steady state river with zircon transport times of 5-10 k.y. inferred from earlier zircon dating of delta sands. The modern delta zircons image an earlier, likely

  12. Detrital zircon U-Pb geochronology and provenance of the Carboniferous-Permian glaciomarine pebbly slates in the Tibetan Plateau

    Science.gov (United States)

    Wang, Q.; Zhu, D.; Zhao, Z.; Chung, S.; Li, C.; Sui, Q.; Fu, X.; Mo, X.

    2011-12-01

    Glaciomarine diamictites (including pebbly slate, pebbly siltstone, and pebbly sandstone) in the Tibetan Plateau are widely interpreted to have been associated with the deglaciation of the Indian continent. Guiding by zircon cathodoluminescence images, we determined U-Pb ages for detrital zircons from five typical Carboniferous-Permian pebbly slate samples from the Qiangtang, Lhasa, and Tethyan Himalaya of the Tibetan Plateau. The age distributions of detrital zircons from two samples (180 analyses) from Qiwu and Gangma Tso of the Qiangtang Terrane are similar, with two main age peaks ca. 579 and ca. 816 Ma and one minor age peak ca. 2490 Ma. Two samples (177 analyses) from Jiangrang and Damxung of the Lhasa Terrane define similar age distributions with two main age peaks ca. 539 and ca. 1175 Ma. Ages of detrital zircons from one sample (110 analyses) from Kangmar of the Tethyan Himalaya display main age peaks ca. 535, ca. 949, and ca. 2490 Ma. The ca. 816-Ma detrital zircons from the Qiangtang Terrane were most likely derived from the Lesser Himalaya, and the ca. 950-Ma detrital zircons from the Tethyan Himalaya might have been sourced from the High Himalaya, Eastern Ghats Province of the Indian plate and the Rayner Province of East Antarctica. The distinctive ca. 1175-Ma age population characteristic of zircons in the pebbly slates from the Lhasa Terrane is identical to the detrital zircons from the late Paleozoic sandstones (Zhu et al., 2011a) and the inherited zircons from the Mesozoic peraluminous granites (Zhu et al., 2011b) in this terrane, but significantly absent in the pebbly slates from both the Qiangtang and the Tethyan Himalayan terranes. The ca. 1175-Ma detrital zircons in the Lhasa Terrane were most likely sourced from the Albany-Fraser-Wilkes in southwestern Australia and East Antarctica. These new data obtained in this study reveal a distinct difference of detrital zircon provenance for the coeval Carboniferous-Permian glaciomarine pebbly slates

  13. Geochemical (LA-ICP-MS) investigations of baddeleyite from the Palaeoproterozoic mafic and Palaeozoic alkaline intrusions in the Arctic part of the Baltic shield

    Science.gov (United States)

    Drogobuzhskaya, Svetlana; Bayanova, Tamara; Novikov, Andrey

    2017-04-01

    Baddeleyite is a zirconium dioxide mineral, which is very important, but less common as zircon. While the zircon microelementary composition study is widely applicable, the baddeleyite geochemical features are poorly known. The first data on REE concentrations and distribution in baddeleyite were published in the past century. Baddeleyite is used as a geochronometer for dating mafic and alkaline rocks. It may be noted that the data on its geochemical composition are quite contradictory with a strongly varying Ce anomaly value and absent Eu anomaly in some samples. The new data on the elementary composition of baddeleyite (REE, Hf, U, Th, Y, and Ti) from the Monchegorsk pluton mafic rocks (2.5 Ga) and Kovdor and Vuoriyarvi deposits (380 Ma) was obtained. The sample morphology was studied using an electronic spectroscopy method (Hitachi S-430), and the position of local analysis on baddeleyite crystals was chosen based on analyzed optic images of minerals. The content of REE and other elements was measured using LA-ICP-MS technique on quadrupole mass-spectrometer ELAN 9000 DRC-e (Perkin Elmer) with laser evaporator UP-266 MACRO (New Wave Research) with a wave length of 266 nm for sampling. The laser ablation was made in argon atmosphere in a 35 and 70 μm diameter spot or when scanning to a line with a pulse repetition rate of 10 Hz and pulse energy of 14-15 J/cm2. The device was calibrated using the NIST SRM 612 standard with a REE, U, and Th concentration of about 40 ppm. The baddeleyite from reference rocks of mafic intrusions are characterized by medium concentrations of Hf (0.69-1.9 %), Th (7.6-21.1), REE (50.3-162), U (164-357), Y (5.0-149) ppm for the sample M-2 from Monchegorsk. Another rocks of alkaline intrusions are depleted in Th (0.25-5.9), REE (9.2-103), U (1.8-48.1), Y(2.9-65.9) ppm and Hf (0.20-1.9%) for the sample Bd-400 from Vuoriyarvi and Hf (0.18-1.3 %), Th (0.4-5.2), REE (2.1-17.7), U (4.2-32.6), Y(2.2-68.4) ppm for the samples Bd-300 and Bd-300

  14. U-Pb zircon in situ dating with LA-MC-ICP-MS using a mixed detector configuration

    Energy Technology Data Exchange (ETDEWEB)

    Chemale Junior, Farid, E-mail: fchemale@unb.br [Universidade de Brasilia (UnB), DF (Brazil). Inst. de Geociencias; Kawashita, Koji; Dussin, Ivo A. [Universidade de Sao Paulo (USP), SP (Brazil). Centro de Pesquisas Geocronologicas; Avila, Janaina N. [Australian National University, Canberra, (Australia). Research School of Earth Sciences; Justino, Dayvisson; Bertotti, Anelise [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Curso de Pos-Graduacao em Geociencias

    2012-06-15

    The LA-MC-ICP-MS method applied to U-Pb in situ dating is still rapidly evolving due to improvements in both lasers and ICP-MS. To test the validity and reproducibility of the method, 5 different zircon samples, including the standard Temora-2, ranging in age between 2.2 Ga and 246 Ma, were dated using both LA-MC-ICP-MS and SHRIMP. The selected zircons were dated by SHRIMP and, after gentle polishing, the laser spot was driven to the same site or on the same zircon phase with a 213 nm laser microprobe coupled to a multi-collector mixed system. The data were collected with a routine spot size of 25 {mu}m and, in some cases, of 15 and 40 {mu}m. A careful cross-calibration using a diluted U-Th-Pb solution to calculate the Faraday reading to counting rate conversion factors and the highly suitable GJ-1 standard zircon for external calibrations were of paramount importance for obtaining reliable results. All age results were concordant within the experimental errors. The assigned age errors using the LA-MC-ICP-MS technique were, in most cases, higher than those obtained by SHRIMP, but if we are not faced with a high resolution stratigraphy, the laser technique has certain advantages. (author)

  15. The existing time of Sihetun vertebrate in western Liaon-ing, China--Evidence from U-Pb dating of zircon

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In different opinions, the stratigraphic time of the feathered dinosaurs and early birds in Sihetun and its neighboring areas in Beipiao, western Liaoning is appointed to different epoches of eras, such as Late Jurassic, Early Cretaceous and Late Jurassic-Early Cretaceous. Even the recently dating data are still very different. This note first reported the U-Pb age of (125.2±0.9) Ma of zircon separated from tuff of Sihetun vertebrates horizon. The age reveals that Sihetun vertebrate belongs to Early Cretaceous. The method is more objective, because of the strong ability of disturbance resistance and high U-Pb blocking temperature of zircons.

  16. Zircon U-Pb age and geological significance of the diabase porphyrite from the Yumuchuan area in the Songnen-Zhangguangcailing Block,Jilin,China%吉林省松嫩-张广才岭地块榆木川辉绿玢岩年代学及其地质意义

    Institute of Scientific and Technical Information of China (English)

    冯光英; 刘遷; 杨经绥; 牛晓露

    2016-01-01

    In order to comprehensively discuss the petrogenic age,tectonic setting and geological significance of the Yumu-chuan diabase porphyrites in the southern part of the Songnen-Zhangguangcailingblock of the Xingmeng orogenic belt,the zircon LA-ICP-MS U-Pbdating and Sr-Nd isotope measurement of the diabase porphyrites have been carried out in this paper. Results show that thezircon LA-ICP-MS U-Pb age of 399±1.8Ma for the Yumuchuan diabase porphyrites is different from the previously reported K-Ar age(Permian).In addition,these diabase porphyrites have relatively low(87Sr/86Sr)i ratios (0.704439-0.70551 8)and positive εNd(t)values(6.8-7.9).With the combination of results of previous studies,we have suggested that the timing of the extension of the Songnan-Zhangguangcailing and Jiamusi blocks is furtherly constrain-ed to the early Devonian.In addition,as there was significant crustal growth in the NE China in phanerozoic,the forma-tion of the Yumuchuandiabase porphyrites,which was the direct product of the crustal growth,means that there could be an important event of the vertical crustal growth in the Songnan-Zhangguangcailingblock in early stage of the LatePaleozoic.%为探讨位于兴蒙造山带松嫩-张广才岭地块南部的榆木川辉绿玢岩的成岩时代、构造背景及地质意义,对其进行了LA-ICP-MS 锆石U-Pb定年和Sr-Nd同位素测试。结果显示,榆木川辉绿玢岩的成岩时代为399±1.8Ma,而非前人所指的二叠纪。Sr-Nd同位素测试结果显示,该套辉绿玢岩具有相对较低的(87Sr/86Sr)i 值(0.704439~0.705518)和正的εNd(t)值(6.8~7.9)。结合前人对该区构造背景的认识,进一步将松嫩-张广才岭地块与佳木斯地块伸展拉张环境的时间限定为早泥盆世。另外,东北地区显生宙地壳增生显著,榆木川辉绿玢岩本身就为地壳增生的产物,其形成暗示晚古生代早期松嫩-张广才岭地块可能存在一期重要的地壳垂向增生事件。

  17. Zircon LA ICPMS U Pb Geochronology of the Beryl-Bearing Pegmatite and Its Geological Significance,Western Yunnan,Southwest China%滇西含绿柱石伟晶岩锆石UPb年代学及其地质意义

    Institute of Scientific and Technical Information of China (English)

    李再会; 唐发伟; 林仕良; 丛峰; 谢韬; 邹光富

    2014-01-01

    Zircon LA ICP MS U Pb dating and geochemical analyses were carried out for the beryl-bearing pegmatite of Tengchong Lianghe area,western Yunnan.Dating results revealed that the beryl-bearing pegmatite were formed at (48.1±0.8)Ma (MSWD=4.0).Zircon morphology and trace element feature indicate that the zircons suffered from hydrothermal alteration.The beryl-bearing pegmatite shows similar characteristics with respect to major elements,trace elements and rare elements with muscovite granite which formed during 55 52 Ma.They are sub-alkaline series,peraluminous granite with strongly Eu depletion,relatively enriched HREE with (La/Yb)N=1.61 1.92 and showing typical M-type of REE tetrad effect.The genesis of beryl-bearing pegmatite is related to the evolution of muscovite granitoids and the crystallization temperature of beryl-bearing pegmatite is 581 ℃.It indicates the overthickened crust tectonic setting caused by India-Asia continental collision.%对腾冲梁河地区含绿柱石伟晶岩进行了锆石 LA ICP MS U Pb 定年和地球化学分析。结果表明:含绿柱石伟晶岩的形成时代为(48.1±0.8)Ma(MSWD=4.0),锆石形态特征和微量元素特征显示,伟晶岩锆石受到热液的改造。含绿柱石伟晶岩与55~52 Ma 的白云母花岗岩在主量元素、微量元素及稀土元素方面表现出极其相似的特征,为钙碱性系列,过铝质花岗岩,表现出强烈的 Eu 亏损,δEu 为0.074~0.083,相对富集 HREE,(La/Yb)N =1.61~1.92,总体表现出典型的“M”型稀土元素四分组效应。含绿柱石伟晶岩是白云母花岗岩浆高度演化的结果,伟晶岩结晶温度为581℃,代表了印度欧亚板块碰撞导致地壳加厚的构造背景。

  18. Multi-stage evolution of gneiss from North Dabie:evidence from zircon U-Pb chronology

    Institute of Scientific and Technical Information of China (English)

    XIE Zhi; GAO Tianshan; CHEN Jiangfeng

    2004-01-01

    TTG gneiss is a common rock to outcrop in the northern part of the Dabie orogen, a few of which are closely associated with eclogites that experienced the Triassic ultrahigh pressure metamorphism. Although they were thermally metamorphosed by a large-scale magma activity in this region at the Early Cretaceous, it is unclear whether or not they are also affected by the Triassic metamorphism during continental subduction and exhumation. In order to resolve this issue, SHRIMP zircon U-Pb dating was carried out for the host gneiss of eclogites in North Dabie. The results show that cores from the gneiss have an age of 746±31 Ma, consistent with the protolith ages of granitic gneisses in the Dabie orogen. Zircon overgrowing with different U and Th concentrations give concordant ages of 212±21 and 120±11 Ma, respectively. Th/U ratios of overgrown zircons are both lower than 0.1, suggesting a metamorphic genesis. The present results suggest that the gneiss in North Dabie has the similar protolith ages of Neoproterozoic to those granitic gneisses elsewhere in the Dabie orogen, and experienced not only the Triassic metamorphism but also the thermal metamorphism due to the Early Cretaceous magmatism. This provides an important insight into the geodynamic evolution of gneissic rocks in the Dabie orogen.

  19. SHRIMP U-Pb geochronology of the detrital zircons from the Longshoushan Group and its tectonic significance

    Institute of Scientific and Technical Information of China (English)

    KuoAn TUNG; HoungYi YANG; LIU DunYi; ZHANG JianXin; ChienYuan TSENG; WAN YuSheng

    2007-01-01

    Sixty-two geologically meaningful U-Pb dates were obtained by using SHRIMP technique for the detrital zircons in three mettasedimentary rocks from stratigraphically uppermost parts of the Longshoushan Group in the present study.Eighty percents of these dates range from 1.7 Ga to 2.2 Ga with a peak at 1.8-2.0 Ga and twenty percents from 2.3 Ga to 2.7 Ga.The youngest detrital zircon is dated at 1724±19Ma which is interpreted as the maximum depositional age of the metasedimentary rocks.Therefore,the age for the diagenesis and lithification of the original sedimentary rocks of the Longshoushan Group before the metamorphism must be younger than 1724±19 Ma.Comparison of the age histograms of these detrital zircons with the ages of the igneous rocks on the surrounding older massifs suggests that the sediments of the Longshoushan Group were most likely derived from the Alaxa Block and Tarim Craton.This implies that the affinity between Alaxa Block and Tarim Craton was strong and that they might have been a unified craton during middle-early Proterozoic time

  20. Zircon SHRIMP U-Pb dating for olivine gabbro at Wangmuguan in the Beihuaiyang zone and its geological significance

    Institute of Scientific and Technical Information of China (English)

    LIU Yican; LI Shuguang; GU Xiaofeng; HOU Zhenhui

    2006-01-01

    Zircon SHRIMP U-Pb dating was performed for olivine gabbro at Wangmuguan in the Beihuaiyang zone of the Dabie orogen and its country rock (garnet-bearing epidote-mica-quartz schist).The results show that the gabbro was crystallized at 635±5 Ma, in the late Neoproterozoic rather than in the late Paleozoic as previously suggested; its country rocks formed at 464±7 Ma, younger than the enclosed gabbro. The U-Pb age for the gabbro is in good agreement with ages for tuff interbedded with sediments from the Doushantuo Formation in the South China Block and late-Neoproterozoic basic dyke swarms distributed on a large scale over areas of Suizhou to Zaoyang of Hubei Province in the northern margin of the South China Block. This suggests a large-scale magmatic activity occurred at the late Neoproterozoic in the South China Block, so that the gabbro at Wangmuguan in the western segment of the Beihuaiyang zone is geotectonic affinity to the northern margin of the South China Block. Since the olivine gabbro occurs within the schist of Ordovician protolith with tectonic contact between them but forming in different tectonic settings, it is concluded that the late-Neoproterozoic gabbro was detached from the Precambrian basement of the South China Block during the Triassic subduction of the South China Block, and tectonically thrusted over the metamorphosed rocks in the southern margin of the North China Block.

  1. SHRIMP zircon U-Pb dating for subduction-related granitic rocks in the northern part of east Junggar, Xinjiang

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    SHRIMP U-Pb zircon dating on the Xileketehalasu granodiorite porphyry and Kalasayi monodiorite porphyry that intrude middle Devonian Beitashan Formation at the north part of east Junggar region shows that they were formed at 381±6 Ma and 376±10 Ma respectively. They are interpreted as subduction-related granitic rocks, which is the first report that the isotopic ages for the granitic rocks range from 350 to 390 Ma. Another determined age for the Kalasayi monodiorite porphyry is 408±9 Ma, representing the age of underlain Lower Devonian volcanic rocks. Thus, the U-Pb dates suggest that the northeastward subduction of Junggar ocean from southwest occurred at 408 to 376 Ma (the real interval may be larger). Because the ore-bearing porphyry intruded following the formation of the volcanic rocks of middle Devonian Beitashan Formation, their tectonic setting is similar to the Andes Mountains that hosts world-class porphyry copper deposits, and the researched area could be regarded as a potential area for prospecting large porphyry copper deposits.

  2. U-Pb zircon age of the foliated garnet-bearing granites in western Dabie Mountains,Central China

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    U-Pb zircon dating on two foliated gar net-bearing granite samples in the western Dabie ultra high-pressure (UHP) metamorphic unit yields concordant ages of (234±4) Ma and (227±5) Ma, respectively. These ages, following the UHP peak metamorphism, represent the magma emplacement ages for the foliated garnet-bearing granites. This, for the first time, shows that there are the Triassic granites in the Dabie Mountains. The foliated gar net-bearing granites resemble A-type granite in geochemical characteristics, indicating that they were formed in exten sional geodynamic setting. The magma formation reflects a reheating event in the Dabie orogenic belt and it enhances the transfer of tectonic regime from collision into extension and promotes the rapid exhumation into lower crust for the UHP metamorphic rocks.

  3. Zircon U?Pb ages in Myanmar: Magmatic?metamorphic events and the closure of a neo-Tethys ocean?

    Science.gov (United States)

    Mitchell, Andrew; Chung, Sun-Lin; Oo, Thura; Lin, Te-Hsien; Hung, Chien-Hui

    2012-08-01

    Previous isotopic age studies have concluded that the main metamorphism in the Mogok Metamorphic belt (MMB) in Myanmar was Tertiary and caused by collision with or underthrusting by India. We present here results of zircon U-Pb age determinations on 18 samples from Myanmar, largely on intrusive rocks from the north-trending 550 km long Shan Scarps segment of the sickle-shaped MMB. The oldest determination is 491 Ma on orthogneiss north of Mandalay, interpreted as a protolith age and similar to the stratigraphic age of the Bawdwin Volcanics. Augen gneiss at Kyaukse has a 114 Ma protolith age. Our zircon U-Pb ages on undeformed intrusive rocks in the MMB range from Cretaceous to Miocene; the oldest (128 Ma), on a diorite near Yebokson, implies an earliest Cretaceous minimum age for regional metamorphism here. Younger ages on undeformed intrusions include 91 Ma on diorite at Mokpalin, 72 Ma on the weakly foliated garnet-bearing Nattaung granite, 44 and 48 Ma respectively on the MEC and Sedo granites, and 17-20 Ma on granite dykes. For the 128 Ma diorite, Sr and Nd isotopes indicative of a continental crust component, and mapped continuity of metamorphic host rocks, suggest correlation with mid early Cretaceous plutons in the eastern Transhimalayas. Zircon U-Pb ages for the MEC, Sedo and other granites within the MMB and Slate belt help to define a late Cretaceous to early Eocene age range for mostly ilmenite series peraluminous granites within the Western Granite belt and more restricted Western tin belt of Myanmar and southern Thailand. In the Wuntho-Popa arc west of the dextral Sagaing Fault, our new U-Pb zircon age of 105 Ma on diorite at Salingyi supports previous K-Ar ages (106-93 Ma) for pre-Tertiary intrusions. In the Cretaceous this arc may have occupied the Andaman Sea and continued northwards through the Mokpalin diorites and west of the MMB to the 103-80 Ma I-type plutons in the Gandise batholith of southern Tibet. We interpret the MMB and Slate belt as

  4. Mesoproterozoic Continental Arc Type Granite in the Central Tianshan Mountains: Zircon SHRIMP U-Pb Dating and Geochemical Analyses

    Institute of Scientific and Technical Information of China (English)

    YANG Tiannan; LI Jinyi; SUN Guihua; WANG Yanbin

    2008-01-01

    The Central Tianshan belt in northwestern China is a small Precambrian block located in the southern part of the Central Asia Orogenic Belt (CAOB), which is considered as "the most voluminous block of young continental crust in the world" that comprises numerous small continental blocks separated by Paleozoic magmatic arcs. The Precambrian basement of the central Tianshan Mountains is composed of volcanic rocks and associated volcano-sedimentary rocks that were intruded by granitic plutons. Geochemical analyses demonstrate that the granitic plutons and volcanic rocks were generated in the Andean-type active continental arc environment like today's Chile, and the zircon U-Pb SHRIMP dating indicates that they were developed at about 956 Ma, possibly corresponding to the subduction of the inferred Mozambique Ocean under the Baltic-African super-continent.

  5. Zircon U-Pb age and geochemical constraints on the origin of the Birjand ophiolite, Sistan suture zone, eastern Iran

    Science.gov (United States)

    Zarrinkoub, Mohammad Hossein; Pang, Kwan-Nang; Chung, Sun-Lin; Khatib, Mohammad Mahdi; Mohammadi, Seyyed Saeid; Chiu, Han-Yi; Lee, Hao-Yang

    2012-12-01

    The Birjand ophiolite is one of the ophiolitic complexes in the northern Sistan suture zone, eastern Iran, which marks the closure of an enigmatic branch of the Neotethys Ocean (called the Sistan Ocean) associated with the collision between the Lut and Afghan continental blocks. Ophiolitic rocks in the suture zone occur as collisional block-to-block geological terranes, or as blocks within tectonic mélange. We present zircon U-Pb age, and whole-rock geochemical and Sr-Nd isotopic data of the Birjand ophiolite to understand its formation age and magma genesis in this poorly constrained part of the Alpine-Himalayan orogenic belt. Varieties of the ophiolitic rocks include clinopyroxene-bearing harzburgites, harzburgites, dunites, massive and pillow basalts, dolerites, gabbros and leucogabbros. Using laser ablation inductively coupled plasma-mass spectrometry, zircon separates from two leucogabbros yield U-Pb ages of 113 ± 1 and 107 ± 1 Ma, which are interpreted to represent the formation ages of the ophiolite. The clinopyroxene-bearing harzburgites can be explained as melting residues after low to moderate extraction of MORB-type melts, whereas the harzburgites require more than one melting event to explain their trace element depletion. Most mafic rocks of the ophiolite display MORB-like trace element patterns and high ɛNd(t) (+ 3.4 to + 8.4), features consistent with derivation from MORB-source mantle. Magma genesis can be explained by low to moderate degrees of melting of moderately depleted spinel peridotite and variable interaction with enriched mantle melts. The Birjand ophiolite represents a MORB-type ophiolite and part of the Middle Cretaceous oceanic lithosphere of the Sistan Ocean that closed during the destruction of a narrow arm of the Neotethys Ocean.

  6. Zircon SHRIMP U-Pb Dating, Geochemical Characteristics and Tectonic Significance of Granitic Gneisses in Amdo, Tibet

    Institute of Scientific and Technical Information of China (English)

    Lu Lu; Zhenhan Wu; Zhen Zhao; Daogong Hu; Peisheng Ye

    2014-01-01

    The Amdo microcontinent is located within the middle of Bangong-Nujiang suture (BNS) zone in the shape of lens. The basic geological research restricts geologists from understand-ing the histories of tectonic evolution of BNS and regional geology more deeply. This paper system-atically studies the geochronology and geochemistry of granitic gneisses from Amdo basement. These data provide constraints on formation age, source characteristics and tectonic setting of their protolith. The SHRIMP zircon U-Pb dating is operated for granitic gneisses. Samples AGS-2 and AGS-3 (granitic gneiss) yield average zircon U-Pb ages of 485±14 and 487±6 Ma, respectively. These ages should represent the formation age of protolith and indicate that they are formed in the Early Ordovician. Granitic gneisses are characterized by high SiO2, Na2O, K2O and Al2O3, low Fe and Mg, enrichment in light rare earth elements (LREEs) and large ion lithophile elements (LILEs), deple-tion in heavy rare earth elements (HREEs) and high field strength elements (HFSEs), with negative Eu anomaly. The Rittmann index (σ) is 1.77 to 2.60, less than 3.3. The aluminum saturation index (A/CNK) values range from 0.88 to 1.26. These features suggest that protolith of granitic gneisses from Amdo basement show characteristics of calc-alkaline and S-type granite, and they could be de-rived from partial melting of metamorphic greywackes in the upper crust of low maturity. The tec-tonic setting is syn-collision. These all suggest that the formation of protolith of granitic gneisses from Amdo are caused by the Early Paleozoic orogeny, which could be related to proto-Tethyan oceanic subduction along Gondwana continental margins, and does not result from the production of Pan-African orogenesis.

  7. Constraining a SHRIMP U-Pb age: micro-scale characterization of zircons from Saxonian Rotliegend rhyolites

    Science.gov (United States)

    Nasdala, Lutz; Götze, Jens; Pidgeon, Robert T.; Kempe, Ulf; Seifert, Thomas

    We present results of a detailed investigation of zircons from two rhyolites from St. Egidien and Chemnitz, Saxony, using a combination of microprobe techniques (SHRIMP ion probe, Raman microprobe, SEM: SE, BSE, and CL imaging). These rhyolites belong to the so-called ``lower volcanics'', which is the older of two series of Late Variscan volcanic rocks occurring in the Saxonian Sub-Erzgebirge basin (Germany). The purpose of the present contribution is to demonstrate that detailed characterization of zircons, as provided by the different micro-techniques, facilitates soundest interpretation of geochronological data. The zircons (at most 40 to 80 m in size) show oscillatory growth zoning, with reversely correlated CL and BSE signal intensities. These zircons are interpreted to have grown during crystallization of the rhyolite because, apart from some cracking, they do not appear to have experienced any alteration since the time of their growth: The shapes of the zircons and their internal structures revealed by CL and BSE imaging appear to be magmatic, and neither annealing of the accumulated alpha-decay damage nor disturbance of the U-Pb system is observed. The SHRIMP ion probe measurements on the zircons gave a Permian 206Pb/238U age of 278 +/- 5 Ma (95% confidence). The concordance of this age is supported by the correlation between the low degrees of metamictization (estimated from Raman parameters) and the accumulated alpha fluxes (calculated from SHRIMP data). The 278 Ma zircon age is interpreted to represent the age of the ``lower rhyolites'' series and, with that, the age of postkinematic Late Variscan volcanism in the Sub-Erzgebirge basin, which has been related to anorogenic extension and uplift as a result of intracontinental rifting. Because of genetic association of rhyolites in the Sub-Erzgebirge basin and Li-F granites and lamprophyres in the neighbouring Erzgebirge, the rhyolite age also indirectly contributes to the understanding of the geological

  8. SHRIMP zircon U-Pb dating in Jingshan "migmatitic granite", Bengbu and its geological significance

    Institute of Scientific and Technical Information of China (English)

    XU Wenliang; WANG Qinghai; YANG Debin; LIU Xiaochun; GUO Jinghui

    2005-01-01

    The petrographic characteristics of Jingshan "migmatitic granite" and the occurrence of the magmatic zircons indicate that the granite was formed by normal crystallization of felsic melts. All zircons in the granite have inherited cores and fine-scale oscillatory zoning rims of magmatic origin. It is realized that the granite was formed at 160.2±1.3 Ma through dating magmatic zircons. The generation of the granitic magma could be related to the lithospheric mantle and/or lower crust delamination after the ultrahigh pressure metamorphism (UHPM) in Triassic. Most inherited zircons yield the ages of 217.1±6.6 Ma, which is consistent with the peak UHPM in the Dabie-Sulu orogenic belt. Some of the inherited zircons (433-722 Ma) constitute a discordia line with the upper intercept age of 850+85/-68 Ma and a lower intercept age of 261+100/-140 Ma. These ages imply that the granite could be derived from the partial melting of the crustal materials of the South China Block that was intensively superimposed by the UHPM. The UHPM could be the reason for the major Pb loss at ±220 Ma.

  9. Petrography and U-Pb zircon geochronology of Caledonian age orthogneisses dredged from the Chukchi Borderland, Arctic Ocean

    Science.gov (United States)

    Brumley, K.; Miller, E. L.; Mayer, L. A.; Wooden, J. L.; Dumitru, T. A.

    2011-12-01

    The Caledonian orogenic belt developed in the Ordovician to Devonian affecting northern Europe, Greenland and Arctic Canada. Caledonian deformational trends continue into the Arctic region disappearing at the rifted margin of the Arctic Ocean. Syn-orogenic magmatism in the Barents region date deformation of Grenvillian basement during the Caledonian event to be between about 450-410 Ma (Johansson et al., 2005; Gee et al., 2006; Gee and Tebenkov, 2004). Over 500 kilos of metamorphic rock was dredged from outcrops in the central Chukchi Borderland in 2009 (HLY0905) that included amphibolites and orthogneisses metamorphosed to amphibolite facies continuing to deform under greenschist conditions. Zircons were separated from two orthogneiss samples from this dredge, and single grain zircon U-Pb ages were determined by SHRIMP analysis be 428 Ma ± 3.4 for both samples (N=60). One sample had several zircon grains with distinct igneous cores that ranged in age from about 850-1000 Ma. Grenville age plutons (1000-910 Ma) that were later involved in Caledonian deformation and intruded by 450-410 Ma aged plutons are found on western and eastern Svalbard (Johansson et al., 2005), eastern Greenland, and the Pearya Terrane of northern Ellesmere Island (Trettin,1986, 1992). The Franklinian basement of Arctic Alaska and Canada do not share these Grenvillian ages (Trentin et al, 1987). This suggests that the inherited zircon cores in the Chukchi Borderland orthogneisses were derived, at least in part, from an older Grenvillian basement like that of Pearya, Svalbard and parts of Greenland and later intruded by Caledonian aged granites.

  10. Isotope U-Pb age on single zircon and REE distribution in rocks and zircon from paleoproterozoic Kandalaksha-Kolvitsa complex Baltic shield

    Science.gov (United States)

    Steshenko, Ekaterina; Bayanova, Tamara; Drogobuzhskaya, Svetlana; Lyalina, Ludmila; Serov, Pavel; Chashchin, Viktor; Elizarov, Dmitriy

    2017-04-01

    Kandalaksha-Kolvitsa paleoproterozoic complex located in the N-E part of Baltic shield and consists of three zones. Marginal zone (mesocratic metanorite) lies at the base of the massif. Main zone is composed of leucocratic metagabbro. The upper zone is alteration of mataanorthosite and leucocratic metagabbro. All rocks were subjected to granulate and anorthositic metamorphism. Age of magmatic crystallization of the massif was determined for the first time, using the U-Pb isotope method for single zircon grains. Three fractions of single zircons from anorthosite of the Kandalaksha massif gave precise U-Pb age of 2435.5 ± 4.8 Ma. For the first time REE concentration (WR) was determined using a quadrupole mass spectrometer (Agilent 7500 ce ICP-MS) in the main varieties of rocks of the Kandalaksha-Kolvitsa paleoproterozoic complex. Anorthosite and leucocratic metagabbros (main zone) are characterized by a flat spectrum distribution of HREE, which were normalized by [1]. The REE pattern is characterized by significant positive anomalies of Eu ((Eu / Eu *)n = 3.72-3.91) in anorthosite and leucogabbros and 7.26 - in ortoamfibolitah. General content of individual elements that are common for this type of rocks: Cen = 5.82-8.54, Ybn = 1.54-1.58, which indicates that the process of crystallization of the rock occurred with predominant accumulation of plagioclase. According to geochemical and Nd-Sr isotopic data (ISr=0.702 - 0.706, ɛNd(T) = +1 - (-3)) Kandalaksha Kolvitsa complex, appear to have a general plume source with Paleoproterozoic layered intrusions of the Baltic Shield [2] Distribution of REE (ELAN-9000 ICP-MS) in zircon have a typical magmatic species: a positive Ce, negative Eu anomaly and HREE flat spectrum. Titanium content in zircons were measured for the calculation of their crystallization temperature with 8350C. These data are evidence of magmatic origin of zircon [3]. The scientific researches are supported by RFBR (projects № 15-35-20501, № 16

  11. Laser ablation - inductively coupled plasma mass spectrometry (LA-ICP-MS): Novel applications for coal research

    Energy Technology Data Exchange (ETDEWEB)

    Booth, C.A.; Spears, D.A.

    1999-07-01

    Laser Ablation - Inductively Coupled Plasma - Mass Spectrometry (LA-ICP-MS) has enormous potential in coal research. Element concentrations are determined with limits of detection currently in the parts per billion range, whilst spatial resolution as low as 10 microns can be achieved using the CETAC Technologies LSX-100 laser ablation system. Calibration of the LA-ICP-MS systems is notoriously difficult but in this paper the authors review two different techniques used in Sheffield, which allow trace element concentrations of whole coals (bituminous) and minerals and macerals within the coal to be determined. The first technique involves calibrating the system with PF grade coal samples in order that trace element concentrations can directly be determined after ablation of a solid coal or pressed coal sample. Using this technique, potentially hazardous trace elements such as As, Cd, Pb and Hg can be detected and measured even in the low parts per billion concentration (mg/Kg) range. The second application utilizes the spatial resolution of the laser to measure element concentrations in individual coal components. In this paper the results from ablating pyrite framboids in polished sections of the coal are discussed. Elemental information is obtained throughout the ablation procedure and this is then calibrated against the Fe content in order to establish the concentration of an element per 1% pyritic iron.

  12. Evidence for multi-cycle sedimentation and provenance constraints from detrital zircon U-Pb ages: Triassic strata of the Lusitanian basin (western Iberia)

    Science.gov (United States)

    Pereira, M. F.; Gama, C.; Chichorro, M.; Silva, J. B.; Gutiérrez-Alonso, G.; Hofmann, M.; Linnemann, U.; Gärtner, A.

    2016-06-01

    Laser ablation ICP-MS U-Pb analyses were conducted on detrital zircons of Triassic sandstone and conglomerate from the Lusitanian basin in order to: i) document the age spectra of detrital zircon; ii) compare U-Pb detrital zircon ages with previous published data obtained from Upper Carboniferous, Ordovician, Cambrian and Ediacaran sedimentary rocks of the pre-Mesozoic basement of western Iberia; iii) discuss potential sources; and iv) test the hypothesis of sedimentary recycling. U-Pb dating of zircons established a maximum depositional age for this deposit as Permian (ca. 296 Ma), which is about sixty million years older compared to the fossil content recognized in previous studies (Upper Triassic). The distribution of detrital zircon ages obtained points to common source areas: the Ossa-Morena and Central Iberian zones that outcrop in and close to the Porto-Tomar fault zone. The high degree of immaturity and evidence of little transport of the Triassic sediment suggests that granite may constitute primary crystalline sources. The Carboniferous age of ca. 330 Ma for the best estimate of crystallization for a granite pebble in a Triassic conglomerate and the Permian-Carboniferous ages (< ca. 315 Ma) found in detrital zircons provide evidence of the denudation of Variscan and Cimmerian granites during the infilling of continental rift basins in western Iberia. The zircon age spectra found in Triassic strata are also the result of recycling from the Upper Carboniferous Buçaco basin, which probably acted as an intermediate sediment repository. U-Pb data in this study suggest that the detritus from the Triassic sandstone and conglomerate of the Lusitanian basin is derived from local source areas with features typical of Gondwana, with no sediment from external sources from Laurussia or southwestern Iberia.

  13. U-Pb ages and morphology of zircons from different granites within the Saxonian Granulite Massif

    Energy Technology Data Exchange (ETDEWEB)

    Sagawe, Anja [Senckenberg Naturhistorische Sammlungen Dresden (Germany). Oeffentlichkeitsarbeit; Gaertner, Andreas; Hofmann, Mandy; Linnemann, Ulf [Senckenberg Naturhistorische Sammlungen Dresden (Germany). Sektion Geochronologie

    2013-07-01

    The Saxonian Granulite Massif comprises various granitoid intrusions with different stages of deformation but of similar ages. However, there is only little knowledge about the magmatic source of these rocks. Combining the external and internal morphology of zircons and taking into consideration their Th-U values allows the differentiation of the granitoids into at least two groups of distinct evolution.

  14. SHRIMP zircon U-Pb ages and tectonic implications of igneous events in the Ereendavaa metamorphic terrane in NE Mongolia

    Science.gov (United States)

    Miao, Laicheng; Zhang, Fochin; Baatar, Munkhtsengel; Zhu, Mingshuai; Anaad, Chimedtseren

    2017-08-01

    The Ereendavaa metamorphic terrane in NE Mongolia has long been considered as a Pre-Altaid block or a Precambrian cratonic terrane with a Paleoproterozoic basement overlain by Neoproterozoic-Cambrian rocks, but the idea has not been supported by any isotopic dating. Sensitive high resolution ion microprobe (SHRIMP) zircon U-Pb dating on gneisses, amphibolite and schists (mylonites) of the Ereendavaa terrane suggests that the terrane mainly formed during Early Paleozoic (495-464 Ma) and Late Paleozoic-Early Mesozoic (295-172 Ma). A minor amount of Precambrian rocks might have been involved in the formation of the protoliths of these rocks, as shown by Precambrian inherited zircons (1796-794 Ma). The new age data also suggest that the Ereendavaa terrane experienced at least two periods of magmatism: (1) Early Paleozoic (495-464 Ma) and (2) Late Paleozoic-Early Mesozoic (295-172 Ma), which are probably produced by the subduction of the Paleo Asian Ocean in the south and the subduction of the Mongol-Okhotsk Ocean in the north, respectively. The mylonitized granite (172 Ma) and undeformed pegmatite (163 Ma) are interpreted to be syn- and post-kinematic products. The new age data constrain the closure of the Mongol-Okhotsk Ocean at mid-Jurassic.

  15. Metamorphic evolution and U-Pb zircon SHRIMP geochronology of the Belizario ultramafic amphibolite, Encantadas Complex, southernmost Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Hartmann, Leo A.; Porcher, Carla C. [Rio Grande do Sul Univ., Porto Alegre (Brazil). Inst. de Geociencias]. E-mail: leo.hartmann@ufrgs.br; Santos, Joao O.S. [Centro de Pesquisas de Recursos Minerais (CPRM), Porto Alegre, RS (Brazil). Brazilian Geological Survey; Leite, Jayme A.D. [Mato Grosso Univ., Cuiaba (Brazil). Dept. de Recursos Minerais; McNaughton, Neal J. [Western Australia Univ., Nedlands, WA (Australia). Centre for Global Metallogeny

    2003-09-15

    The integrated investigation of metamorphism and zircon U-Pb SHRIMP geochronology of the Belizario ultramafic amphibolite from southernmost Brazil leads to a better understanding of the processes involved in the generation of the Encantadas Complex. Magmatic evidence of the magnesian basalt or pyroxenite protolith is only preserved in cores of zircon crystals, which are dated at 2257 {+-} 12 Ma. Amphibolite facies metamorphism M{sub 1} formed voluminous hornblende in the investigated rock possibly at 1989 {+-} 21 Ma. This ultramafic rock was re-metamorphosed at 702+- 21 Ma during a greenschist facies event M{sub 2}; the assemblage actinolite + oligoclase + microcline + epidote + titanite + monazite formed by alteration of hornblende. The metamorphic events are probably related to the Encantadas Orogeny (2257 {+-} 12 Ma) and Camboriu Orogeny ({approx}1989 Ma) of the Trans-Amazonian Cycle, followed by an orogenic event (702 {+-} 21 Ma) of the Brasiliano Cycle. The intervening cratonic period (2000-700 Ma) corresponds to the existence of the Supercontinent Atlantica, known regionally as the Rio de la Plata Craton. (author)

  16. SHRIMP Zircon U-Pb Dating of the Tongshi Magmatic Complex in Western Shandong and Its Geological Implications

    Institute of Scientific and Technical Information of China (English)

    HU Huabin; MAO Jingwen; LIU Dunyi; NIU Shuyin; WANG Yanbin; LI Yongfeng; SHI Ruruo

    2005-01-01

    The SHRIMP U-Pb zircon dating result of the Tongshi magmatic complex in western Shandong is presented in this paper.The Tongshi magmatic complex comprises fine-grained porphyritic diorite and syenitic porphyry.Eighteen analyses for fine-grained porphyritic diorite gave two concordia ages,in which ten analyses constitute the young age group,giving 206Pb/238U ages ranging from 167.9 Ma to 183 Ma with a weighted mean age of 175.7±3.8 Ma,and the other eight yielded 207Pb/206Pb ages of 2502 Ma to 2554 Ma with a weighted mean 2518±11 Ma.Two analyses for syenitic porphyry gave ages of 2485 Ma and 2512 Ma,respectively.The age of 175.7±3.8 Ma indicates that the crystallization of the Tongshi magmatic complex occurred in the Middle Jurassic,whereas that of 2518±11 Ma is interpreted as the age of inherited magmatic zircons in the Neoarchean Wutai period.

  17. Provenance records of the North Jiangsu Basin,East China:Zircon U-Pb geochronology and geochemistry from the Paleogene Dainan Formation in the Gaoyou Sag

    Institute of Scientific and Technical Information of China (English)

    Chun-Ming; Lin; Xia; Zhang; Ni; Zhang; Shun-Yong; Chen; Jian; Zhou; Yu-Rui; Liu

    2014-01-01

    Detailed zircon U-Pb dating and whole-rock geochemical analyses were carried out on the sedimentary rocks of the Paleogene Dainan Formation from Gaoyou Sag in the North Jiangsu Basin,East China.Whole-rock rare earth element characteristics suggest that the provenance was mainly from the Late Proterozoic low-grade metamorphic felsic rocks in the Dabie-Sulu orogenic belt,with the parent rocks probably being the I-type high-potassium granite gneiss.Cathodoluminescence images indicate that most of the detrital zircons are originally magmatic.A few zircons show overgrowths,indicating multiple-episode tectonic events.The U-Pb age distribution patterns of the detrital zircons suggest four main magmatic episodes in the provenance:Late Archean-Early Proterozoic(2450-2600 Ma),Early Proterozoic(1700-1900 Ma),Late Proterozoic(700-850 Ma),and Late Paleozoic-Mesozoic(100-300 Ma).These zircon U-Pb age and whole-rock geochemical results suggest that the sediments of the Dainan Formation were mainly sourced from the recycled orogenic belts within and/or around the North Jiangsu Basin,including the basement of the Yangtze Block,the Neoproterozoic rocks in the Dabie-Sulu orogenic belt,and the Mesozoic igneous rocks in the south part of Zhangbaling Uplift.

  18. Determination of U-Pb age and rare earth element concentrations of zircons from Cenozoic intrusions in northeastern China by laser ablation ICP-MS

    Institute of Scientific and Technical Information of China (English)

    YUAN Honglin; WU Fuyuan; GAO Shan; LIU Xiaoming; XU Ping; SUN Deyou

    2003-01-01

    Using the in situ zircon U-Pb dating method of LA-ICPMS, we analyzed the 31 Ma old SHRIMP U-Pb age of the Yongsheng nepheline syenite from southern Jilin Province under different spot sizes. The obtained ages are comparable with that of SHRIMP in both accuracy and precision. The age is also identical to that of the Yinmawanshan gabbro from the Liaodong Peninsula within error. Both the Yongsheng nepheline syenite and the Yinmawanshan gabbro represent the youngest known exposed intrusions in northeastern and even eastern China. The results indicate the Eocene mantle-derived magmatic underplating, and the rapid crustal uplifting of this region since 30 Ma. The analyses also document extremely high LREE concentrations and relatively flat REE patterns for the zircons from the Yongsheng nepheline syenite, which represent a new type of zircon REE pattern.

  19. U-Pb zircon age from the base of the Ediacaran Doushantuo Formation in the Yangtze Gorges,South China: constraint on the age of Marinoan glaciation

    Institute of Scientific and Technical Information of China (English)

    ChongyuYin; FengTang; YongqingLiu; LinzhiGao; PengjuLiu; YushengXing; ZhiqingYang; YushengWan; ZiqiangWang

    2005-01-01

    The reported new U-Pb age by sensitive high-resolution ion microprobe (SHRIMP Ⅱ) on zircon was obtained from a tuff sample at the basal Doushantuo Formation in the Jiuqunao section, which situated at the western limb of the Huangling anticline in the Yangtze Gorges in Zigui, Hubei, South China. Eighteen spots of zircons were analyzed and they form two clusters: one includes three spots, with an inherited age of 784+ 15 Ma (MSWD=0.05); the other consists of 15 spots and gives a weighted mean 206pb/238U age of 628.3±5.8 Ma (MSWD=0.86). It is the first SHRIMP U-Pb zircon age obtained nearly the base of the Doushantuo Formation of Ediacaran and represents a maximum age of the Doushantuo Formation It also forms an age constraint on the upper limit age of the Nantuo (Marinoantype) glaciation.

  20. Small-Volume U-Pb Zircon Geochronology by Laser Ablation-Multicollector-ICP-MS

    Science.gov (United States)

    2008-11-03

    detrital and metamorphic history of a granulite -facies paragneiss — demonstrate the utility of this technique to a variety of geologic problems and confirm... granulite -facies pelitic gneiss collected inn geochronology by laser ablation-multicollector-ICP-MS, Chemical Fig. 11. A) Concordia plot of all...zircons to unravel the detrital–metamorphic history of a granulite -facies paragneiss from east Greenland. In addition to the small spot diameter, the

  1. Paleozoic accretionary orogenesis in the eastern Beishan orogen: constraints from zircon U-Pb and 40Ar/39Ar geochronology

    Science.gov (United States)

    Ao, Songjian; Xiao, Wenjiao; Windley, Brian; Mao, Qigui

    2016-04-01

    The continental growth mechanism of the Altaids in Central Asia is still in controversy between models of continuous subduction-accretion versus punctuated accretion by closure of multiple oceanic basins. The Beishan orogenic belt, located in the southern Altaids, is a natural laboratory to address this controversy. Key questions that are heavily debated are: the closure time and subduction polarity of former oceans, the emplacement time of ophiolites, and the styles of accretion and collision. This paper reports new structural data, zircon ages and Ar-Ar dates from the eastern Beishan Orogen that provide information on the accretion process and tectonic affiliation of various terranes. Our geochronological and structural results show that the younging direction of accretion was northwards and the subduction zone dipped southwards under the northern margin of the Shuangyingshan micro-continent. This long-lived and continuous accretion process formed the Hanshan accretionary prism. Our field investigations show that the emplacement of the Xiaohuangshan ophiolite was controlled by oceanic crust subduction beneath the forearc accretionary prism of the Shuangyingshan-Mazongshan composite arc to the south. Moreover, we address the age and terrane affiliation of lithologies in the eastern Beishan orogen through detrital zircon geochronology of meta-sedimentary rocks. We provide new information on the ages, subduction polarities, and affiliation of constituent structural units, as well as a new model of tectonic evolution of the eastern Beishan orogen. The accretionary processes and crustal growth of Central Asia were the result of multiple sequences of accretion and collision of manifold terranes. Reference: Ao, S.J., Xiao, W., Windley, B.F., Mao, Q., Han, C., Zhang, J.e., Yang, L., Geng, J., Paleozoic accretionary orogenesis in the eastern Beishan orogen: Constraints from zircon U-Pb and 40Ar/39Ar geochronology. Gondwana Research, doi: http://dx.doi.org/10.1016/j

  2. SHRIMP U-Pb zircon geochronology and its implications on the Xilin Gol Complex, Inner Mongolia, China

    Institute of Scientific and Technical Information of China (English)

    SHI Guanghai; LIU Dunyi; ZHANG Fuqin; JIAN Ping; MIAO Laicheng; SHI Yuruo; TAO Hua

    2003-01-01

    The Xilin Gol Complex, consisting of deformed and metamorphosed rocks, was exposed as a large geological unit within the Central Asian Orogenic Belt, but its forming and subsequent deformed and metamorphic time has been an issue of little consensus. Petrographic analyses and SHRIMP dating on biotite-plagioclase gneiss, one of the major rocks within the Xilin Gol Complex, in southeast Xilinhot City, Inner Mongolia, China, where the Xilin Gol Complex was identified and named, yield its lower limit age of 437 ( 3 Ma (2--) by its magmatic zircon SHRIMP U-Pb dating, and an upper limit age of 316 ( 3Ma (2--), which was constrained by SHRIMP dating of magmatic zircons from adjacent undeformed garnet-bearing granite which intruded the Complex. The Complex was thus determined to be formed and subsequently deformed/metamorphosed from the late Ordovician-early Silurian to the mid-Carboniferous. Consequently, it is not the Precambrian terrane as previously considered by most geologists. More or less, the major rock--biotite- plagioclase gneiss within the Complex is more likely to be Paleozoic fore-arc turbidite formation before metamorphism and intensive deformation, in which the detrital zircons gave sporadic Precambrian ages as old as up to 3.1 Ga. The source of the turbidite formation is multiple, which may be derived either from the North China Craton, or from the South- Mongolia Micro-continent, or probably came from a potential and undiscovered in situ terranes aged 600-800 Ma or even up to ca 3.1 Ga near the Complex.

  3. Identification of 3.5 Ga detrital zircons from Yangtze craton in south China and the implication for Archean crust evolution

    Institute of Scientific and Technical Information of China (English)

    LIU Xiaoming; GAO Shan; LING Wenli; YUAN Honglin; HU Zhaochu

    2006-01-01

    The LA-ICP-MS U-Pb dating of hundreds of detrital zircon grains from the Sinian sandstones of Liantuo formation and tillites of Nantuo formation at Sanxia area in Yichang identified 3319-3508 Ma zircon grains. Their 207pb/206pb and 206pb/238U ages show excellent agreement (concordia degree 99 %-100 % ). Their CL images exhibit well-developed oscillatory zoning and the Th/U ratios are within 0. 46-0. 76, implying that they are igneous zircons which formed during middle-early Archean. These zircons are the oldest ones discovered in Yangtze craton until now. However, the detrital zircons with ages older than 3.3 Ga in the metamorphic rocks of Kongling group were not found by further investigation, which suggests the presence of crust older than high-grade metamorphic Kongling terrain in Yangtze craton.

  4. Impact of hydrothermal alteration on the U-Pb isotopic system of zircons from the Fangcheng syenites in the Qinling orogen, Henan Province, China

    Institute of Scientific and Technical Information of China (English)

    BAO Zhiwei; WANG Qiang; BAI Guodian; ZHAO Zhenhua

    2009-01-01

    Disturbance of the zircon U-Pb isotopic system has been investigated extensively, but mostly in lab, in the last decades. Here, we reported a field-based study on intensive sericitization, K-feldsparthization and the impacts of mylonitization on zircons from the Fangcheng syenites.The Fangcheng syenites occur in the eastern part of the Qinling orogen and consist mainly of aegirine-augite syenite, aegirine nepheline syenite, biotite syenite and hornblende nepheline syenite. Zircons from the slightly sericitized aegirine augite syenite are colorless, transparent crystals and exhibit well-developed oscillatory and sector zoning on the cathodoluminescence (CL) images which are typical of magmatic zircons from alkaline rocks. Zircon U-Pb determinations by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) showed that the syenite was formed in Neoproterozoic time, the weighted average of 206Pb/238U ages is 844.3±1.6 Ma (MSWD=0.86). In contrast, the hydrothermally altered zircons (hydrothermal zircon) from the intensively sericitized, K-feldsparthized, and weakly mylonitized aegirine augite syenite are conglomerates, yellowish to brown in color, generally translucent and internally textureless. The CL and backscatter electron (BSE) images of hydrothermal zircons exhibit fractured, textureless or mosaic textures, and occasionally show "sponge texture" with the veinlets and inclusions of K-feldspar; however, relicts of magmatic oscillatory zoning can still be discerned locally in individual grains. LA-ICPMS analyses of the hydrothermal zircons demonstrated that the zircons are chemically inhomogeneous, with enhanced and widely varied Pb, U, and Th contents. The U and Th contents of the hydrothermal zircons are estimated to be 32×10-6-1550×10-6 and 188×10-6-4059×10-6, respectively, with Th/U ratios within the range of 0.7-44.9. 206Pb/238U apparent ages of the hydrothermal zircons are negatively correlated with the contents of U, and radiogenic and

  5. The India-Asia collision in north Pakistan: Insight from the U-Pb detrital zircon provenance of Cenozoic foreland basin

    Science.gov (United States)

    Ding, Lin; Qasim, Muhammad; Jadoon, Ishtiaq A. K.; Khan, Muhammad Asif; Xu, Qiang; Cai, Fulong; Wang, Houqi; Baral, Upendra; Yue, Yahui

    2016-12-01

    The northernmost exposures of sub-Himalayan Cenozoic strata in the Hazara-Kashmir syntaxial region of north Pakistan comprises the Paleocene-Eocene marine strata in the lower part and Oligocene-Miocene nonmarine strata in the upper part. This study provides the detrital zircon U-Pb geochronology of the Cenozoic strata in this area. The strong resemblance of U-Pb age spectra of Paleocene Hangu, Lockhart and Patala formations with those of Himalayan strata indicate an Indian plate provenance. The first appearance of Pakistan at ca. 56-55 Ma.

  6. Temporal evolution of the giant Salobo IOCG deposit, Carajás Province (Brazil): constraints from paragenesis of hydrothermal alteration and U-Pb geochronology

    Science.gov (United States)

    deMelo, Gustavo H. C.; Monteiro, Lena V. S.; Xavier, Roberto P.; Moreto, Carolina P. N.; Santiago, Erika S. B.; Dufrane, S. Andrew; Aires, Benevides; Santos, Antonio F. F.

    2017-06-01

    The giant Salobo copper-gold deposit is located in the Carajás Province, Amazon Craton. Detailed drill core description, petrographical studies, and U-Pb SHRIMP IIe and LA-ICP-MS geochronology unravel its evolution regarding the host rocks, hydrothermal alteration and mineralization. Within the Cinzento Shear Zone, the deposit is hosted by orthogneisses of the Mesoarchean Xingu Complex (2950 ± 25 and 2857 ± 6.7 Ma) and of the Neoarchean Igarapé Gelado suite (2763 ± 4.4 Ma), which are crosscut by the Old Salobo granite. Remnants of the Igarapé Salobo metavolcanic-sedimentary sequence are represented by a quartz mylonite with detrital zircon populations (ca. 3.1-3.0, 2.95, 2.86, and 2.74 Ga). High-temperature calcic-sodic hydrothermal alteration (hastingsite-actinolite) was followed by silicification, iron-enrichment (almandine-grunerite-magnetite), tourmaline formation, potassic alteration with biotite, copper-gold ore formation, and later Fe-rich hydrated silicate alteration. Myrmekitic bornite-chalcocite and magnetite comprise the bulk of copper-gold ore. All these alteration assemblages have been overprinted by post-ore hematite-bearing potassic and propylitic alteration, which is also recognized in the Old Salobo granite. In the central zone of the deposit the mylonitized Igarapé Gelado suite rocks yield an age of 2701 ± 30 Ma. Zircon ages of 2547 ± 5.3 and 2535 ± 8.4 Ma were obtained for the Old Salobo granite and for the high-grade copper ore, respectively. A U-Pb LA-ICP-MS monazite age (2452 ± 14 Ma) from the copper-gold ore indicates hydrothermal activity and overprinting in the Siderian. Therefore, a protracted tectono-thermal event due to the reactivation of the Cinzento Shear Zone is proposed for the evolution of the Salobo deposit.

  7. Timing of the granulite facies metamorphism in the Sanggan area, North China craton: zircon U-Pb geochronology

    Institute of Scientific and Technical Information of China (English)

    GUO; Jinghui

    2001-01-01

    on the Early Precambrian grey gneiss and Khondalitein Nei Mongol-Shanxi-Hebei junction region, north China, Acta Petrologica Sinica (in Chinese with English abstract), 1996, 12(2): 329-342.[19]Guo, J. H., Shi, X., Bian, A. G. et al., Pb isotopic composition of feldspar and U-Pb age of zircon from early Proterozoic granite in Sanggan area, North China craton: Metamorphism, crustal melting and tectono-thermal event, Acta Petrologica Sinica (in Chinese with English abstract), 1999, 15(2): 199-207.[20]Krogh, T. E., A low contamination method for the hydrothermal decomposition of zircon and extraction of U and Pb for isotopic age determinations, Geochim. Cosmochim. Acta, 1973, 37: 485-494,[21]Xu, R. H., The single zircon U-Pb dating method, Acta Petrologica Sinica (in Chinese with English abstract), 1989, 5(2):88-93.[22]Stacey, J. S., Kramers, J. D., Approximation of terrestrial lead isotopes evolution by a two-stage model, Earth Planet. Sci.Lett., 1975, 26: 207-221.[23]Wiedenbeck, M., An example of reverse discordance during ion microprobe zircon dating: an artifact of enhanced ion yields from a radiogenic labile Pb, Chem. Geol., 1995, 125: 197-218.[24]Williams, I. S., Compston, W., Black, L. P. et al., Unsupported radiogenic Pb in zircon: a cause of anomalously high Pb-Pb, U-Pb and Th-Pb ages, Contrib. Mineral. Petrol., 1984, 88: 322-327.[25]Chen, F., Siebel, W., Satir, M., Zircon and zircons; unveiled by the stepwise leach experiment (abstr.), EUG-I 1 (European Union of Geosciences), Strasbourg, France, 2001, 37.[26]Pidgeon, R. T., Aftalion, M., Cogenetic and inherited zircon U-Pb systems in granites: Paleozoic granites of Scotland and England, in Crustal Evolution of Northwestern Britain and Adjacent Regions (eds. Bowes, R. D., Leake, B. E.), Geological Journal (special issue), 1978, 10: 183-220.[27]Schenk, V., U-Pb and Rb-Sr radiometric dates and their correlation with metamorphic events in the granulite facies basement of the

  8. SHRIMP U-Pb in zircon geochronology of granitoids from Myanmar: temporal constraints on the tectonic evolution of Southeast Asia

    Science.gov (United States)

    Barley, M. E.; Zaw, Khin

    2009-04-01

    The Mesozoic to Tertiary tectonic evolution of Southeast Asia is the result of the convergence and collision of fragments of Gondwanaland with Eurasia culminating in the collision of India. A rapidly growing geochronological database is placing tight constraints on the timing and duration of magmatic episodes, metallogenic and tectonic events in the Himalayas, Tibet and eastern Indochina. However, there is little comparable geochronology for Myanmar. This SHRIMP U-Pb in zircon geochronology focuses on granitoids from the Mogok Metamorphic Belt (MMB, a belt of high grade metamorphic rocks at the edge of the Shan-Thai Terrane), the Myeik Archipelago (Shan-Thai Terrane) and the west Myanmar Terrane. Strongly deformed granitic orthogneisses in the MMB near Mandalay contain Jurassic (~170 Ma) zircons that have partly recrystallised during ~43 Ma high-grade metamorphism. A hornblende syenite from Mandalay also contains Jurassic zircons with evidence of Eocene metamorphism rimmed by thin zones of 30.9 ±0.7 Ma magmatic zircon. The relative abundance of Jurassic zircons in these rocks is consistent with suggestions that southern Eurasia had an Andean-type margin at that time. Mid-Cretaceous to earliest Eocene (120 to 50 Ma). I-type granitoids in the MMB, Myeik Archipelago and west Myanmar confirm that prior to the collision of India, an up to 200km wide magmatic belt extended along the Eurasian margin. The primitive I-type Khanza Chaung granodiorite in the Wuntho batholith in the west Myanmar terrane hosts porphyry-style mineralisation and has a magmatic age of 94  1 Ma. Triassic (~240 Ma), Jurassic (~170 Ma) and Early Cretaceous xenocryst zircons in this granitoid correspond with peaks of granitoid magmatism in the Shan-Thai terrane and establish that west Myanmar was part of the margin of Eurasia during the Mesozoic. A suite of highly fractionated metaluminous to peraluminous I-type granitoids with associated Sn-W-Ta mineralisation emplaced in the Myeik Archipelago of

  9. Scanning ion imaging - a potent tool in SIMS U -Pb zircon geochronology

    Science.gov (United States)

    Whitehouse, M. J.; Fedo, C.; Kusiak, M.; Nemchin, A.

    2012-12-01

    The application of high spatial resolution (BSE) characterisation, has revolutionised geochronology over the past 25 years, re-vealing complexities of crustal evolution from zoned zircons. In addition to ge-ochronology, such studies now commonly form the basis of broader investigations using O- and Hf- isotopes and trace elements obtained from the same growth zone as age, circumventing ambiguities commonly present in bulk-rock isotope studies. The choice of analytical beam diameter is often made to maximise the precision of data obtained from a given area of analysis within an identifiable growth zone. In cases where zircons yield poorly constrained internal structures in SEM, high spatial resolution spot analyses may yield uninterpretable and/or meaningless mixed ages by inadvertent sampling across regions with real age differences. Scanning ion imaging (SII) has the potential to generate accurate and precise geochrono-logical data with a spatial resolution down to ca. 2 μm, much higher than that of a normal spot analysis. SII acquisition utilises a rastered primary beam to image an area of the sample with a spatial resolution dependent on the selected primary beam diameter. On the Cameca ims1270/80 instruments, the primary beam scanning is coupled with the dynamic transfer optical system (DTOS) which deflects the secondary ions back on to the ion optical axis of the instrument regardless of where in the raster illuminated area the ions originated. This feature allows retention of a high field magnification (= high transmission) mode and the ability to operate the mass spectrometer at high mass resolution without any compromise in the quality of the peak shape. Secondary ions may be detected either in a sequential (peak hopping) mono-collection mode or simultaneous multicollection mode using low-noise pulse counting electron multipliers. Regardless of the detection mode, data are acquired over sufficient cycles to generate usable counting statistics from selected

  10. The Approach to Reducing the Detection Limit for LA-ICP-MS

    Science.gov (United States)

    Poteshin, S. S.; Sysoev, Alexey A.; Torbotryas, R.

    This work is a part of the RED-100 big project. The aim of the RED-100 experiment is to detect the presently undiscovered coherent neutrino scattering off xenon atomic nuclei. The manufacture of such detectors requires ultrapure materials with very low content of natural radioactive elements. So the pure titanium was selected to assay the uranium and thorium contaminations on 1 ng/g level. In this paper we investigate the possibility of reducing the LOD for LA-ICP-MS analysis by increasing the pulse repetition rate of solid-state laser irradiation up to 4,000 Hz and appropriate adjusting the irradiation power. LODs for U and Th in titanium matrix estimation fell in the sub 10-10 g g- 1 level.

  11. New analytical strategies for quantitative and spatially resolved direct solid analysis by LA-ICP-MS

    OpenAIRE

    Konz Gherghel, Ioana

    2014-01-01

    La ablación láser acoplada a un plasma de acoplamiento inductivo con espectrometría de masas (LA-ICP-MS) se está convirtiendo en una tecnología dominante para el muestreo directo de sólidos en química analítica. La ablación láser se refiere al proceso en el cual una intensa energía suministrada por un pulso láser se utiliza para arrancar una pequeña cantidad de material. Los beneficios del empleo de la ablación láser para la introducción de la muestra en el ICP-MS son múltiples e incluyen la ...

  12. Chemical evolution of Himalayan leucogranites based on an O, U-Pb and Hf study of zircon

    Science.gov (United States)

    Hopkinson, Thomas N.; Warren, Clare J.; Harris, Nigel B. W.; Hammond, Samantha J.; Parrish, Randall R.

    2015-04-01

    Crustal melting is a characteristic process at convergent plate margins, where crustal rocks are heated and deformed. Miocene leucogranite sheets and plutons are found intruded into the high-grade metasedimentary core (the Greater Himalayan Sequence, GHS) across the Himalayan orogen. Previously-published Himalayan whole-rock data suggest that these leucogranites formed from a purely meta-sedimentary source, isotopically similar to those into which they now intrude. Bulk rock analyses carry inherent uncertainties, however: they may hide contributions from different contributing sources, and post-crystallization processes such as fluid interaction may significantly alter the original chemistry. In contrast, zircon is more able to retain precise information of the contributing sources of the melt from which it crystallises whilst its resistant nature is impervious to post-magmatic processes. This multi-isotope study of Oligocene-Miocene leucogranite zircons from the Bhutan Himalaya, seeks to differentiate between various geochemical processes that contribute to granite formation. Hf and O isotopes are used to detect discrete changes in melt source while U-Pb isotopes provide the timing of zircon crystallisation. Our data show that zircon rims of Himalayan age yield Hf-O signatures that lie within the previously reported whole-rock GHS field, confirming the absence of a discernible mantle contribution to the leucogranite source. Importantly, we document a decrease in the minimum ɛHf values during Himalayan orogenesis through time, correlating to a change in Hf model age from 1.4 Ga to 2.4 Ga. Nd model ages for the older Lesser Himalayan metasediments (LHS) that underthrust the GHS are significantly older than those for the GHS (2.4-2.9 Ga compared with 1.4-2.2 Ga), and as such even minor contributions of LHS material incorporated into a melt would significantly increase the resulting Hf model age. Hence our leucogranite data suggest either a change of source within

  13. 海拉尔盆地火山岩的锆石 U-Pb 年龄及其地质意义%Zircon U-Pb Chronology of Volcanic Rocks in the Hailaer Basin, NE China and Its Geological Implications

    Institute of Scientific and Technical Information of China (English)

    陈崇阳; 高有峰; 吴海波; 瞿雪姣; 刘志文; 白雪峰; 王璞臖

    2016-01-01

    The Hailaer basin is located in the west of the Great Xing'an Range,and there are many sets of volcanic sedimentary rocks in the basin.Determining the age of the formation of volcanic rocks can provide reliable evidence for the stratigraphic cor-relation of the basin and the Great Xing'an Range,and the tectonic evolution in Northeast China as well.LA-ICP-MS zircon U-Pb dating for 4 volcanic rock samples from coring well in the Hailaer basin (HB)is presented in this paper.Their formation time and tectonic setting focusing on the intra-/inter-basinal stratigraphic correlation are discussed.The dating results show that volcanic rocks with ages of Late Triassic-early Early Jurassic (214.4±4.3 Ma)do exist in the HB.And the whole volcanic succession in the region can be subdivided into 4 stages of eruption including Middle-Late Carboniferous (320-290 Ma),Late Triassic-early Early Jurassic (224-197 Ma),Late Jurassic-early Early Cretaceous (152-138 Ma),and late Early Cretaceous (128-117 Ma).Combined with geochemical characteristics,temporal and spatial distribution characteristics of the magma in the Great Xing'an Range area,as well as the characteristics of the seismic profile of the basin,it is suggested that the Middle-Late Carboniferous magmatic rocks (320-290 Ma)were probably formed in a post-collision extensional setting related to the collision and merging of the Songnen and Ergun-Xing'an blocks.The Late Triassic-early Early Jurassic volcanic rocks (224-197 Ma)were probably formed in a post-collision extensional setting related to the closure of Paleo-Asian Ocean,which indi-cates Paleo-Asian Ocean tectonic domain affects the Great Xing'an Range area extended to the early Early Jurassic at least and the collision of the Mongolia Okhotsk Ocean possibly started in the early Jurassic at the earliest.The Late Jurassic-early Early Cretaceous (152-138 Ma)and the Late Early Cretaceous (128 -117 Ma)volcanic rocks were probably formed in a post-collision extensional setting

  14. U/Pb zircon geochronology and tempo of the end-permian mass extinction

    Science.gov (United States)

    Bowring; Erwin; Jin M W Martin YG; Davidek; Wang

    1998-05-15

    The mass extinction at the end of the Permian was the most profound in the history of life. Fundamental to understanding its cause is determining the tempo and duration of the extinction. Uranium/lead zircon data from Late Permian and Early Triassic rocks from south China place the Permian-Triassic boundary at 251.4 +/- 0.3 million years ago. Biostratigraphic controls from strata intercalated with ash beds below the boundary indicate that the Changhsingian pulse of the end-Permian extinction, corresponding to the disappearance of about 85 percent of marine species, lasted less than 1 million years. At Meishan, a negative excursion in delta13C at the boundary had a duration of 165,000 years or less, suggesting a catastrophic addition of light carbon.

  15. Zircon U-Pb SHRIMP Ages from the Late Paleozoic Turpan-Hami Basin, NW China

    Institute of Scientific and Technical Information of China (English)

    Xiang Mao; Jianghai Li; Huatian Zhang

    2014-01-01

    Permian volcanic rocks are widely distributed in the Turpan-Hami Basin, which is part of the Central Asian orogenic belt. Here we present SHRIMP zircon data for the rhyolite in Well Baocan 1, one of the deepest wells in the basin. The 283.9±2.7 Ma reported in our study provides the best precise age determination for the Yierxitu Formation, the oldest Permian layer of Hami Depression, one of the three substructural units of the Turpan-Hami Basin, and a potential hydrocarbon reservoir in this ba-sin. Our data refines earlier imprecise39Ar-40Ar ages and shows that the volcanic rocks both inside the Turpan-Hami Basin and along its margin are almost coeval. We delineate a collisional orogenesis, and the new age of 283.9±2.7 Ma may limit the latest time of the collision orogenesis.

  16. Tectonic implications of U-Pb zircon ages of the himalayan orogenic belt in nepal

    Science.gov (United States)

    DeCelles; Gehrels; Quade; LaReau; Spurlin

    2000-04-21

    Metasedimentary rocks of the Greater Himalaya are traditionally viewed as Indian shield basement that has been thrust southward onto Lesser Himalayan sedimentary rocks during the Cenozoic collision of India and Eurasia. Ages determined from radioactive decay of uranium to lead in zircon grains from Nepal suggest that Greater Himalayan protoliths were shed from the northern end of the East African orogen during the late Proterozoic pan-African orogenic event. These rocks were accreted onto northern Gondwana and intruded by crustal melts during Cambrian-Ordovician time. Our data suggest that the Main Central thrust may have a large amount of pre-Tertiary displacement, that structural restorations placing Greater Himalayan rocks below Lesser Himalayan rocks at the onset of Cenozoic orogenesis are flawed, and that some metamorphism of Greater Himalayan rocks may have occurred during early Paleozoic time.

  17. Online Standard Additions Technique for La-ICP-MS Using a Desolvating Nebulizer System

    Science.gov (United States)

    Roy, J.; Asogan, D.; Moody, S.; Clarke, D.

    2014-12-01

    Historically, quantification with laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has been limited to the ability to matrix match both standards and samples. This can prove problematic when a particular matrix matched standard is not readily available. Liquid standard addition has been shown1-4 as an alternative technique for quantification that does not require matrix matching; however, further fundamental study is needed especially considering the different mass flow rates delivered to the plasma from traditional pneumatic nebulizers and laser ablation itself. In this work, the authors combine a specialized low-flow desolvating nebulizer system with LA-ICP-MS. This nebulizer system efficiently removes water vapour, thereby significantly reducing oxide based mass spectral interferences. For the instrument setup, the output from the laser is combined with the dried aerosol from the nebulizer system prior to entering the ICP-MS source. By using two sources of dry aerosol, mixing efficiency is improved whilst minimising plasma power lost to solvent (water vapour) processing. The method was applied to both USGS Green River Shale and an Arkansas Womble Shale. The results showed a number of elements that were correctly quantified using the technique as compared to reference values. References Gunther, D., Cousin, H., Magyar, B., Leopold, I., J. Anal. Atom. Spectrom., 1997, 12, 165 - 170. Leach, J.J., Allen, L. A., Aeschliman, D.B., Houk, R.S., Anal. Chem., 1999, 71, 440 - 445. O'Conner, C.J.P., Sharp, B.L, Evans, P.J., Anal. Atom. Spectrom., 2006, 21, 556. Yang, C.K., Chi, P.H., Lin, Y.C., Sun, Y.C., Yang, M.H., Talanta, 2010, 80, 1222 - 1227.

  18. SHRIMP Zircon U-Pb Chronology and Geochemistry of the Henglingguan and Beiyu Granitoids in the Zhongtiao Mountains, Shanxi Province

    Institute of Scientific and Technical Information of China (English)

    YU Shengqiang; LIU Shuwen; TIAN Wei; LI Qiugen; FENG Yonggang

    2006-01-01

    Henglingguan and Beiyu metamorphic granitoids, distributed in the northwest of the Zhongtiaoshan Precambrian complex, comprise trondhjemites and calc-alkaline monzogranites,displaying intrusive contacts with the Archean Zhaizi TTG gneisses. And the Beiyu metamorphic granitoids consist mainly of trondhjemites, distributed at the core of the Hujiayu anticline fold. New SHRIMP zircon U-Pb dating data show that the weighted mean 207Pb/206Pb ages are 2435.9 Ma and 2477 Ma for the Henglingguan metamorphic calc-alkaline monzogranites and Beiyu metamorphic trondhjemites, respectively, and reveal ~2600 Ma inherited core in magmatic zircons. Whole-rock geochemical data indicate that all the Henglingguan and Beiyu metamorphic trondhjemites and calcalkaline monzogranites belong to the metaluminous medium- and high-potassium calc-alkaline series.These rocks are characterized by relatively high total alkali contents (Na2O+K2O, up to 9.08%),depleted Nb, Ta, P and Ti, and right-declined REE patterns with moderate to high LREEs/HREEs fractionation (the mean ratio of (La/Yb)n = 25). The Henglingguan and Beiyu metamorphic trondhjemites display negative Rb, Th and K anomalies in the multi-element spider diagrams normalized by primitive mantle. Sm-Nd isotopic data reveal that these granitoids have initial εNd(t)=-1.2 to +2.4 and Nd depleted mantle model ages of TMD = 2622 Ma-2939 Ma. All these geochemical features indicate that these granitoids were formed in an continent-marginal arc, and the trondhjemites mainly originated from partial melting of juvenile basaltic materials and, howbeit, the Henglingguan metamorphic calc-alkaline monzogranites derived from recycling of materials in the ancient crust under a continent-marginal arc. The granitic magma underwent contamination and fractional crystallization during their formation.

  19. Detrital zircon U-Pb geochronology, Lu-Hf isotopes and REE geochemistry constrains on the provenance and tectonic setting of Indochina Block in the Paleozoic

    Science.gov (United States)

    Wang, Ce; Liang, Xinquan; Foster, David A.; Fu, Jiangang; Jiang, Ying; Dong, Chaoge; Zhou, Yun; Wen, Shunv; Van Quynh, Phan

    2016-05-01

    In situ U-Pb geochronology, Lu-Hf isotopes and REE geochemical analyses of detrital zircons from Cambrian-Devonian sandstones in the Truong Son Belt, central Vietnam, are used to provide the information of provenance and tectonic evolution of the Indochina Block. The combined detrital zircon age spectra of all of the samples ranges from 3699 Ma to 443 Ma and shows with dominant age peaks at ca. 445 Ma and 964 Ma, along with a number of age populations at 618-532 Ma, 1160-1076 Ma, 1454 Ma, 1728 Ma and 2516 Ma. The zircon age populations are similar to those from time equivalent sedimentary sequences in continental blocks disintegrated from the East Gondwana during the Phanerozoic. The younger zircon grains with age peaks at ca. 445 Ma were apparently derived from middle Ordovician-Silurian igneous and metamorphic rocks in Indochina. Zircons with ages older than about 600 Ma were derived from other Gondwana terrains or recycled from the Precambrian basement of the Indochina Block. Similarities in the detrital zircon U-Pb ages suggest that Paleozoic strata in the Indochina, Yangtze, Cathaysia and Tethyan Himalayas has similar provenance. This is consistent with other geological constrains indicating that the Indochina Block was located close to Tethyan Himalaya, northern margin of the India, and northwestern Australia in Gondwana.

  20. Late Cretaceous volcanic arc system in Southwest Korea: Occurrence, lithological characteristics, SHRIMP zircon U-Pb age, and tectonic implications

    Science.gov (United States)

    Koh, Hee Jae; Kwon, Chang Woo

    2017-04-01

    In the southwest region of the Korean Peninsula, four large volcanoes, the Buan, Seonunsan, Wido, and Beopseongpo, with a maximum diameter of ca 20 km, form a distinct topographic undulation along the NE-SW-trending Hamyeol Fault. These volcanics comprise various types of pyroclastic, sedimentary, and lava/intrusive rocks, and are interpreted as remnants of calderas resulting from various volcanic eruptions, indicating that Hamyeol Fault, together with crustal extension, played an important role in volcano formation in this region. SHRIMP U-Pb ages of zircon isolated from each volcanics are as follows. For Buan Volcanics, Cheonmasan Tuff 87.23 ±0.92 Ma, Udongje Tuff 86.79 ±0.71 Ma, Seokpo Tuff 87.30 ±0.99 Ma and Yujeongje Tuff 86.66 ±0.93 Ma. For Seonunsan Volcanics, Gyeongsusan Tuff 84.9 ±1.1 Ma and Yeongije Tuff 86.61 ±0.67 Ma. These ages indicate that the four volcanics were formed in the Late Cretaceous. The ages are comparable to those of the volcanic rocks of the Aioi and Arima groups in Southwestern Japan, suggesting that the Late Cretaceous volcanic arc systems developed in a NE-SW direction from the Japanese Islands to the southwestern part of the Korean Peninsula caused by regional magmatism together with crustal deformation as reflected by occurrence of the volcanic rocks along the Hamyeol Fault.

  1. U-Pb zircon age for the Daohugou Biota at Ningcheng of Inner Mongolia and comments on related issues

    Institute of Scientific and Technical Information of China (English)

    LIU Yongqing; LIU Yanxue; JI Shu'an; YANG Zhiqing

    2006-01-01

    SHRIMP U-Pb zircon dating was carried out for the Daohugou Biota near Ningcheng of Inner Mongolia and for lavas overlying or underlying salamander-bearing strata at Reshuitang in Lingyuan of West Liaoning. The results suggest that the Daohugou Biota occurred at an interval from 168 Ma to 164-152 Ma. Both the Daohugou Biota and the salamander-bearing fossil assemblage are the same biota and thus developed from 168 to 152 Ma, i.e.from late Middle Jurassic to the early Late Jurassic.The Daohugou Biota-bearing rocks, resting on the Jiulongshan Formation in disconformity and being overlain in unconformity by Late Jurassic Tuchengzi Formation and Early Cretaceous rocks containing the Jehol Biota, are mainly composed of volcanic-sedimentary rocks in a normal sequence. It is recommended that the Daohugou Biota and the related stratigraphy should be correlated with the Tiaojishan Formation (Lanqi Formation in West Liaoning) or its synchronous rocks. It is suggested that the Daohugou Biota and the Jehol Biota would be neither taken into one biota nor considered as the earliest elements of the Jehol Biota. The Daohugou Biota and the related rocks and the Yixian Formation were respectively formed in different periods of volcanic-sedimentary tectonics.

  2. U Pb zircon and monazite geochronology of Variscan magmatism related to syn-convergence extension in Central Northern Portugal

    Science.gov (United States)

    Valle Aguado, B.; Azevedo, M. R.; Schaltegger, U.; Martínez Catalán, J. R.; Nolan, J.

    2005-05-01

    The Viseu area is located in the Central Iberian Zone of the Iberian Variscan Belt and hosts numerous post-thickening, collision-related granitoids intruded into upper and middle crustal levels. The present paper reports high precision U-Pb zircon and monazite ages for four plutons of the Viseu area: the syn-kinematic granitoids of Maceira (314±5 Ma), Casal Vasco (311±1 Ma) and Junqueira (307.8±0.7 Ma) and the late-kinematic biotite monzogranites of Cota (306±9 Ma). This points to a synchronous emplacement of the different syn-kinematic plutons shortly followed by the intrusion of the late-kinematic granites and shows that the Upper Carboniferous plutonism occurred within a short time span of ca. 10 million years. The ascent of granite magmas took place after an extensional tectonic event (D 2) and is coeval with dextral and sinistral crustal-scale transcurrent shearing (D 3). Field and petrographical evidence suggest a narrow time-span between peak T metamorphic conditions and the intrusion of granitic melts which implies very fast uplift rates accommodated through active tectonic exhumation. Magma compositions evolve through time, reflecting an increasing involvement of mid-crustal sources and the underplating effect of an upwelling asthenospheric mantle at the base of a thinning and stretching continental crust.

  3. Timing of the terrestrial Permian-Triassic boundary biotic crisis: Implications from U-Pb dating of authigenic zircons

    Institute of Scientific and Technical Information of China (English)

    YU JianXin; LI HuiMin; ZHANG SuXin; YANG FengQing; FENG QingLai

    2008-01-01

    The Late Permian to Early Triassic transition represents one of the most important Phanerozoic mass extinction episodes.The cause of this event is still in debate between catastrophic and gradual mechanisms.This study uses the U-Pb method on zircons from the uppermost Permian/lowermost Triassic clay deposits at Chahe (Guizhou Province,SW China) to examine time constraints for this event.The results of both this and previous studies show that the ages of Bed 68a and 68c (the upper clay bed of the terrestrial Permian-Triassic boundary (PTB)) respectively are 252.6~2.8 and 247.5±2.8 Ma.This age (within the margin of error) almost accords with the upper clay bed (Bed 28) age of Meishan and the eruption age of Tunguss Basalt,and is so far the most accurate age obtained from terrestrial PTB.The claystone of Bed 68 was formed in the earliest Triassic.The biotic crisis occurred at nearly the same time in terrestrial and marine environments during Permian-Triassic interval; however the extinction patterns and processes are different.The extinction pattern of the terrestrial plants shows a major decline at the PTB after long-term evolution,followed by a retarded extinction of the relicts in the earliest Triassic.

  4. Timing of the terrestrial Permian-Triassic boundary biotic crisis:Implications from U-Pb dating of authigenic zircons

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The Late Permian to Early Triassic transition represents one of the most important Phanerozoic mass extinction episodes. The cause of this event is still in debate between catastrophic and gradual mechanisms. This study uses the U-Pb method on zircons from the uppermost Permian/lowermost Triassic clay deposits at Chahe (Guizhou Province, SW China) to examine time constraints for this event. The results of both this and previous studies show that the ages of Bed 68a and 68c (the upper clay bed of the terrestrial Permian-Triassic boundary (PTB)) respectively are 252.6±2.8 and 247.5±2.8 Ma. This age (within the margin of error) almost accords with the upper clay bed (Bed 28) age of Meishan and the eruption age of Tunguss Basalt, and is so far the most accurate age obtained from terrestrial PTB. The claystone of Bed 68 was formed in the earliest Triassic. The biotic crisis occurred at nearly the same time in terrestrial and marine environments during Permian-Triassic interval; however the extinction patterns and processes are different. The extinction pattern of the terrestrial plants shows a major decline at the PTB after long-term evolution, followed by a retarded extinction of the relicts in the earliest Triassic.

  5. The Paleogene California River: Evidence of Mojave-Uinta paleodrainage from U-Pb ages of detrital zircons

    Science.gov (United States)

    Davis, S.J.; Dickinson, W.R.; Gehrels, G.E.; Spencer, J.E.; Lawton, T.F.; Carroll, A.R.

    2010-01-01

    U-Pb age spectra of detrital zircons in samples from the Paleogene Colton Formation in the Uinta Basin of northeastern Utah and the Late Cretaceous McCoy Mountains Formation of southwestern Arizona (United States) are statistically indistinguishable. This finding refutes previous inferences that arkosic detritus of the Colton was derived from cratonic basement exposed by Laramide tectonism, and instead establishes the Cordilleran magmatic arc (which also provided sediment to the McCoy Mountains Formation) as the primary source. Given the existence of a north-south-trending drainage divide in eastern Nevada and the north-northeast direction of Laramide paleoflow throughout Arizona and southern Utah, we infer that a large river system headed in the arc of the Mojave region flowed northeast ~700 km to the Uinta Basin. Named after its source area, this Paleogene California River would have been equal in scale but opposite in direction to the modern Green River-Colorado River system, and the timing and causes of the subsequent drainage reversal are important constraints on the tectonic evolution of the Cordillera and the Colorado Plateau. ?? 2010 Geological Society of America.

  6. External calibration strategy for trace element quantification in botanical samples by LA-ICP-MS using filter paper

    Energy Technology Data Exchange (ETDEWEB)

    Nunes, Matheus A.G.; Voss, Mônica; Corazza, Gabriela; Flores, Erico M.M.; Dressler, Valderi L., E-mail: vdressler@gmail.com

    2016-01-28

    The use of reference solutions dispersed on filter paper discs is proposed for the first time as an external calibration strategy for matrix matching and determination of As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Sr, V and Zn in plants by laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS). The procedure is based on the use of filter paper discs as support for aqueous reference solutions, which are further evaporated, resulting in solid standards with concentrations up to 250 μg g{sup −1} of each element. The use of filter paper for calibration is proposed as matrix matched standards due to the similarities of this material with botanical samples, regarding to carbon concentration and its distribution through both matrices. These characteristics allowed the use of {sup 13}C as internal standard (IS) during the analysis by LA-ICP-MS. In this way, parameters as analyte signal normalization with {sup 13}C, carrier gas flow rate, laser energy, spot size, and calibration range were monitored. The calibration procedure using solution deposition on filter paper discs resulted in precision improvement when {sup 13}C was used as IS. The method precision was calculated by the analysis of a certified reference material (CRM) of botanical matrix, considering the RSD obtained for 5 line scans and was lower than 20%. Accuracy of LA-ICP-MS determinations were evaluated by analysis of four CRM pellets of botanical composition, as well as by comparison with results obtained by ICP-MS using solution nebulization after microwave assisted digestion. Plant samples of unknown elemental composition were analyzed by the proposed LA method and good agreement were obtained with results of solution analysis. Limits of detection (LOD) established for LA-ICP-MS were obtained by the ablation of 10 lines on the filter paper disc containing 40 μL of 5% HNO{sub 3} (v v{sup −1}) as calibration blank. Values ranged from 0.05 to 0.81  μg g{sup −1}. Overall, the use of filter

  7. Petrography and U-Pb detrital zircon geochronology of metasedimentary strata dredged from the Chukchi Borderland, Amerasia Basin, Arctic Ocean

    Science.gov (United States)

    Brumley, K.; Miller, E. L.; Mayer, L. A.; Andronikov, A.; Wooden, J. L.; Dumitru, T. A.; Elliott, B.; Gehrels, G. E.; Mukasa, S. B.

    2010-12-01

    In 2008-2009, twelve dredges were taken aboard the USCGC Healy from outcrops along the Alpha Ridge, Northern Chukchi Borderland, Northwind Ridge and the Chukchi Plateau in the Arctic Ocean as part of the U.S. Extended Continental Shelf Project. To ensure sampling of outcrop, steep bathymetric slopes (>40°) with little mud cover were identified with multibeam sonar and targeted for dredging. The first dredge from Alpha Ridge yielded volcaniclastic sedimentary rocks deposited from a phreatomagmatic eruption in shallow water (<200m). This is inconsistent with tectonic reconstructions suggesting that the Alpha Ridge was created as an oceanic plateau on deep oceanic crust of the Canada Basin. Another dredge, taken from the northern tip of Northwind Ridge, yielded metasedimentary rocks deformed under greenschist facies conditions (chlorite+white mica). These rocks are intruded and/or overlain by mid-Cretaceous alkalic basalts, also taken in this dredge, and dated by 40Ar/39Ar (plagioclase separate) to be 112±1 Ma. The metasedimentary rocks, from this single dredge, range in grain size from mud to coarse sandstone and grit which all contain grains and sub-angular clasts of volcanic, plutonic, metamorphic and fine grained sedimentary rocks as well as monocrystalline quartz, potassium feldspar, and plagioclase. All of these samples display the same bedding to foliation angle and lithology, which further indicates that they were dredged from in situ outcrop and are not random samples of ice rafted debris. Based on grain size variations and graded beds, they are interpreted as Silurian gravity flow deposits fed by proximal syn-orogenic and/or magmatic arc sources. Detrital zircons were separated from four sandstone samples of the Northwind Ridge dredge, and their U-Pb single grain ages determined by LA-MC-ICPMS and SHRIMP, (N= 393). Their detrital zircon populations are dominated by euhedral first-cycle zircon ca. 430 and 980 Ma with lesser older recycled zircons between

  8. Large southward motion and clockwise rotation of Indochina throughout the Mesozoic: Paleomagnetic and detrital zircon U-Pb geochronological constraints

    Science.gov (United States)

    Yan, Yonggang; Huang, Baochun; Zhao, Jie; Zhang, Donghai; Liu, Xiaohui; Charusiri, Punya; Veeravinantanakul, Apivut

    2017-02-01

    We report a combined paleomagnetic and U-Pb geochronologic study of sedimentary rocks from the Huai Hin Lat and Nam Phong formations of Mesozoic age in NE Thailand in order to provide independent constraints on the tectonic movement of the Indochina Block during convergence of the major blocks now comprising East Asia. The maximum allowable depositional age of the two formations is estimated to be 227 Ma and 215 Ma, respectively, from detrital zircon U-Pb geochronologic analysis which also indicates a sediment source transition in the Khorat Plateau Basin during the Middle-Late Jurassic. A formation mean paleomagnetic direction of Dg /Ig = 21.4 ° / 38.1 ° (kg = 19.5, α95 = 9.6 °) before and Ds /Is = 43.0 ° / 48.0 ° (ks = 47.4, α95 = 6.1 °, N = 13) after tilt correction is derived from samples with different lithologies, bedding attitudes, magnetic carriers and polarities and yields a positive fold test. Hence, the magnetization is likely primary. The revised Mesozoic APWP of the Indochina Block yields paleolatitudes (for a reference site of 22°N, 102°E) of 33.4 ± 7.2°N during the Norian Late Triassic, 25.9 ± 5.9°N during the Late Triassic to Early Jurassic, 23.9 ± 8°N during the Late Jurassic to Early Cretaceous, 27.5 ± 3.2°N during the Early Cretaceous and 24.5 ± 4.9°N by the Late Cretaceous; corresponding declinations are 45.2 ± 8.6°, 38.0 ± 6.6°, 36.3 ± 8.8°, 29.6 ± 3.6° and 24.9 ± 5.4° respectively. These data indicate a significantly southward displacement accompanied by clockwise rotation during the Mesozoic. A reconstruction of the Indochina Block within the now well-studied merging process of South China and North China indicates that the Indochina Block was located at a higher latitude than the South China Block during the Norian stage of Late Triassic times whilst no significant relative poleward displacement apparently occurred during the Early Jurassic to Early Cretaceous interval. Our study supports a post

  9. 浙江石浦下白垩统灰岩微相分析与锆石U-Pb年代学研究%Microfacies and Zircon U-Pb Dating of the Lower Cretaceous Shipu Limestone in Xiangshan, Eastern Zhejiang

    Institute of Scientific and Technical Information of China (English)

    王学寅; 胡文瑄; 胡广; 姚素平; 曹剑; 王小林; 谢小敏

    2012-01-01

    Through the synthetic lithofacies studies for the Shipu limestone section located in Xiangshan, Zhejiang Province, four types microfacies can be recognized, i. e. bioclasts micrite, oolite micritic limestone, stromatolite marlite, and thin lamina-banded limestone, and they formed in tidal flat, oolitic beach and shallow environments, accordingly. Based on the researches of the cyclostratigrapy, the Shipu limestone can be divided into four sedimentary cycles which record three major transgressions. Furthermore, zircon LA-ICP-MS U-Pb dating has been conduced for the tuff beds from the base and top of the section for the first time. The new radiometric age data indicated that the Shipu limestones deposited in the Early Cretaceous age from 114. 2 Ma to 96. 3Ma. We believe that these results should stir up a new thought on the depositional environment and tectonic background of Early Cretaceous in southeast of China%通过对浙江象山石浦灰岩剖面系统的岩相学研究,总结出4种基本灰岩微相类型,即生物碎屑泥晶灰岩、泥晶鲕粒灰岩或鲕粒泥晶灰岩、叠层石泥灰岩、薄层一条带状泥灰岩,其形成于潮坪、鲕粒滩和浅海等三种沉积环境.结合整个剖面岩性变化规律,划分出4个沉积旋回,反映了3次主要海侵过程.并利用LA-ICP-MS锆石U-Pb 同位素定年技术,首次获得了该剖面下部凝灰岩夹层中锆石U-Pb年龄为114±2Ma,确定了该剖面形成时代为早白垩世.这一成果对于深化我国东南沿海早白垩世构造—沉积环境的研究具有重要意义.

  10. U-Pb zircon and biostratigraphic data of high-pressure/low-temperature metamorphic rocks of the Talea Ori: tracking the Paleotethys suture in central Crete, Greece

    Science.gov (United States)

    Zulauf, G.; Dörr, W.; Krahl, J.; Lahaye, Y.; Chatzaras, V.; Xypolias, P.

    2016-10-01

    Inherited deformation microfabrics of detrital quartz grains and U-Pb (Laser ablation (LA)-ICPMS and ID TIMS) ages of detrital zircons separated from the Phyllite-Quartzite Unit s.l. of the Talea Ori, central Crete, suggest strikingly different source rocks. Albite gneiss of the lower Rogdia Beds includes Cambrian and Neoproterozoic rounded zircons with main U-Pb age peaks at 628 and 988 Ma. These and minor Paleoproterozoic and Archean peaks, together with the lack of Variscan-aged and Mesoproterozoic zircons, are similar to the age spectra obtained from the Phyllite-Quartzite Unit s.str. of the Peloponnesus and eastern Crete and from the Taurides. All of these zircons should be derived from the northeastern passive margin of Gondwana (Cimmeria). Metatuffites of the uppermost Rogdia Beds and metasandstone of Bali beach, on the other hand, include euhedral detrital zircons displaying a Variscan U-Pb age spectra at ca. 300 Ma with concordia ages at 291 ± 3, 300 ± 1 Ma (Rogdia) and 286 ± 3, 300 ± 3, 313 ± 2 Ma (Bali). Both types of metasediments and their zircons are similar to those of the pre-Alpine basement and overlying Tyros Beds of eastern Crete, revealing a provenance at the southern active margin of Laurasia. Thus, in central Crete the Paleotethys suture should be situated inside the Rogdia Beds. Magmatic zircons separated from a rhyolite boulder of the lower Achlada Beds yielded a concordant U-Pb zircon age at 242 ± 2 Ma placing a maximum age for the deposition of the (meta)conglomerate from which the boulder was collected. This age is compatible with an Olenekian-early Anisian age of the underlying Vasilikon marble suggested by new findings of the foraminifera Meandrospira aff. pusilla. Both the Achlada Beds and the Vasilikon marble can be attributed to the lower Tyros Beds of eastern Crete. The Alpine deformation led to a pervasive mylonitic foliation, which is affecting most of the studied rocks. This foliation results from D2 top

  11. Chronology and Sources of Mesozoic Intrusive Complexes in the Xuzhou-Huainan Region, Central China:Constraints from SHRIMP Zircon U-Pb Dating

    Institute of Scientific and Technical Information of China (English)

    XU Wenliang; WANG Qinghai; LIU Xiaochun; WANG Dongyan; GUO Jinghui

    2004-01-01

    SHRIMP zircon U-Pb dating in the Liguo and Jiagou intmsives indicates that they were formed at ~130 Ma in the Early Cretaceous. Most inherited zircons in the Liguo intrusive were formed at 2509±43 Ma. Most inherited and detrital zircons in the Jiagou intrusive were formed at ~2500 Ma, ~2000 Ma and ~1800 Ma. The SHRIMP zircon U-Pb dating in two gneiss xenoliths from the Jiagou intrusive yields the ages of 2461+22 Ma and 2508±15 Ma, respectively. The dating results from inherited and detrital zircons in the intmsives and the gneiss xenoliths imply that the magmas could be derived from the partial melting of the basement of the North China Block (NCB). The magmatism is strong and extensive in the periods from 115 to 132 Ma, which is of typical bimodal characteristics. It is suggested that the lithospheric thinning in the eastern North China Block reached its peak in 115-132 Ma.

  12. Temporal-spatial Distribution and Tectonic Implications of the Batholiths in the Gaoligong-Tengliang-Yingjiang Area, Eastern Tibet: Constraints from Zircon U-Pb Ages and Hf Isotopes

    Institute of Scientific and Technical Information of China (English)

    XU Yi-gang; YANG Qi-jun; LAN Jiang-bo; HUANG Xiao-long; LUO Zhen-yu; SHI Yu-ruo; XIE Lie-wen

    2008-01-01

    @@ Zircon U-Pb dating reveals three episodes of plutonism, and more importantly a southwestward magmatic migration in the Gaoligong-Tengliang-Yingjiang area (west Yunnan), east of the eastern Himalayan Syntaxis.

  13. Age of the emerald mineralization from the Itabira-Nova Era District, Minas Gerais, Brazil, based on LA-ICP-MS geochronology of cogenetic titanite

    Directory of Open Access Journals (Sweden)

    Hanna Jordt-Evangelista

    Full Text Available ABSTRACT: In the Itabira-Nova Era Emerald District, southeast Brazil, gemological emerald is extracted from underground mines found in schist-type deposits at the contact zone of the Archean Metavolcanosedimentary Sequence of the Guanhães Complex and Paleoproterozoic anorogenic granites of the Borrachudos Suite. Schist-type deposits are commonly generated by reactions enhanced by deformation and heat during regional metamorphism. The age of the mineralization in the region has been a matter of debate for decades: Ages ranging from the Archean to the Neoproterozoic are mentioned in the literature. In the mineralized zone from the Piteiras mine fluorine-aluminum-bearing titanite is found in metamafic rocks. The fluorine content was probably derived from the Borrachudos granites and pegmatites like the beryllium for emerald, thus both minerals could have been generated during the same event. U-Pb titanite geochronology via laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS was performed on a thin section of a phlogopite-plagioclase-hornblende schist from the Piteiras mine. The determined age of 576 ± 7 Ma is also the probable age for emerald generation during the Brasiliano cycle, which was the only tectonometamorphic event postdating the intrusion of the granites. This event provided heat and fluids necessary for reactions between the Be- and the Cr-bearing rocks, thus enabling the formation of emeralds.

  14. Paleoproterozoic basement beneath the southern Jiangxi Province: Evidence from U-Pb ages and Lu-Hf isotopes in zircons from the Doushui Iamprophyre

    Institute of Scientific and Technical Information of China (English)

    YU JinHai; WANG LiJuan; O'REILLY S Y; SHU LiangShu; UN Tao

    2009-01-01

    This paper presents geochemical analyses of a lamprophyre intruding the Caledonian Doushui granite body in Shangyou County, southern Jiangxi Province. U-Pb dating and Hf-isotope analyses are especially carried out for zircons from it. Petrological and geochemical features show that the lamprophyre belongs to a high-K, weakly alkaline pyroxene-biotite iamprophyre. It is characterized by high Mg# (0.74),Ni (253 μg/g) and Cr (893 μg/g) contents, and also enriched in incompatible elements, such as REE, Rb, Sr, Ba and K. It is suggested that its primitive melt probably derived from enriched mantle metasomatized by non-crust-derived agent. Morphology and LAM-ICPMS dating results of zircons in the lam prophyre indicate that they are xenocrysts captured from deep crustal rocks. Most xenocrystic zircons formed at -1.86 Ga, and a few in different Phanerozoic periods. The Paleoproterozoic zircons are of magmatic origin and have similar 176Hf/177Hf and 176Lu/177Hf ratios, indicating that they probably are from the same igneous basement rock. The ages and Hf-isotope compositions of zircons from this basement rock are similar to those of Paleoproterozoic Danzhu granite in the southern Zhejiang Province, but extremely distinguished from the Nanling basement, suggesting that the study area probably is a westward extension part of Paleoproterozoic Wuyishan terrane in the eastern Cathaysia Block. These Paleoproterozoic zircons have low Hf-isotope compositions, characteristic of crustal source. Hf model ages of these zircons and the presence of older inherited cores within them, coupled with available other data reported by previous studies, suggest that the source of Paleoproterozoic magma is Neoarchaean crust, implying the existence of older basement in the Wuyishan terrane. U-Pb ages and Hf isotopes of five Phanerozoic zircons indicate that Paleoproterozoic basement underwent multi-reworking occurring in Caledonian, Indosinian and early Yanshanian, respectively. The Caledonian

  15. Sun Lixin, Ren Bangfang, Zhao Fengqing, et al. Zircon U-Pb ages and Hf isotope characteristics of Taipingchuan large porphy-ritic granite pluton of Erguna Massif in the Great Xing'an Range.%额尔古纳地块太平川巨斑状花岗岩的锆石U-Pb年龄和Hf同位素特征

    Institute of Scientific and Technical Information of China (English)

    孙立新; 任邦方; 赵凤清; 彭丽娜

    2012-01-01

    大兴安岭北段额尔古纳地块莫尔道嘎—太平川一带分布有大量的新元古代巨斑状花岗岩,该岩体形成的确切时代及成因尚不清楚。笔者等运用LA-ICP-MS技术进行了锆石U-Pb定年和锆石Hf同位素组成测定。锆石U-Pb年龄结果揭示太平川巨斑状花岗岩形成时代为791.4Ma。锆石Hf同位素研究显示εHf(t)为1.4~6.4,均〉0,反映亏损地幔来源新生地壳物质在花岗岩的形成中起主导作用,锆石Hf单阶段的模式年龄tDM为1.09~1.28Ga,与岩石的形成时间791.4Ma有较长的时间间隔,表明该区花岗岩的母岩来自具有较长地壳滞留时间的地壳物质的部分熔融。结合额尔古纳已有的花岗岩锆石Hf同位素资料,认为额尔古纳地块在中、新元古代曾发生过地壳增生事件,存在1.09~1.28Ga的中元古代晚期增生地壳。%Taipingchuan large porphyritic granite pluton was developed in the Erguna Massif in the northern Great Xing'an Range, NE China. The precise age of the formation and genesis of this pluton are unclear. The authors have carried out zircon U-Pb dating and Hf isotope studies by means of LA-ICP-MS. Zircon U-Pb dating results revealed that the age of Taipingchuan granite is 791.4 Ma. Zircon Hf isotope characteristics indicate that the zircon enf (t)values of the granite range from 1.4 to 6. 4, implying that the depleted-mantle- derived juvenile crustal material played an important role in the formation of the granite magma. The 2-stage model ages t~,~of 1.09 - 1.28 Ca, as revealed by Hf composition in zircon, showed rather large interval with the formation age 791.4 Ma of the granite. It indicates that the parental magma of the granitic rock in this region was derived from the partial melting of the crustal material which had a long resident time within the crust. Combined with the previous zircon Hf isotope data obtained from Erguna Massif, the authors hold that there had been crustal accretion event in

  16. U-Pb zircon geochronology, Sr-Nd isotope geochemistry, and petrogenesis of oxidant granitoids at Keybarkuh, southwest of Khaf

    Directory of Open Access Journals (Sweden)

    Ehsan Salati

    2012-10-01

    Full Text Available Keybarkuh area is located 70 km southwest of Khaf, Khorasan Razavi province. The study area is situated in northeastern Lut block. The rock units in the area are Paleozoic metamorphic rocks and Cretaceous to Tertiary subvolcanic intrusions intruded as dike, stock and batholith; their composition varies from granite to diorite. Based on magnetic susceptibility, the intrusive rocks are divided into oxidant and reduced series. In this study, the oxidant intrusions are discussed. These intrusions are mostly high-K to shoshonitic and also meta-aluminous type. Their magma formed in subduction magmatic arc and they belong to I-type granitoid series. Enrichment of Large Ion Lithophile Elements (LILE such as Rb, Cs, K, Ba, and Th relative to High Field Stength Elements (HFSE such as Nb, Zr, and Ti supported the idea. Enrichment of Light Rare Earth Elements (LREE and depletion of Heavy Rare Earth Elements (HREE are also typical of subduction magmatism. Negative anomalies of Eu/Eu* can be attributed to the presence of residual plagioclase in a mantle source and contamination of magma by reduced continental crust. The amount of Nb > 11 ppm, lower ratio of Zr/Nb 0.706, initial 143Nd/144Nd (> 0.512 and εNd (< -3.5 indicate that magma contaminated by reduced continental crust. Hornblende biotite granodiorite porphyry dated using U-Pb zircon geochronology at 43.44 Ma (Middle Eocene. Based on calculated TDM, magma derived from ancient slab with 820 Ma age in the Keybarkuh area, was affected by the highest continental crust contamination during its ascent.

  17. Zircon Geochronology (U-Pb, Petrography, Geochemistry and Radioisotopes of Bornaward Metarhyolites (Central Taknar Zone-Northwest of Bardaskan

    Directory of Open Access Journals (Sweden)

    Reza Monazzami Bagherzadeh

    2016-07-01

    Full Text Available Introduction The Bornaward area is located in the Northeastern Iran (in the Khorasan Razavi province 28 km northwest of the city of Bardaskan at 57˚ 46΄ to 57˚ 52΄ N latitude and 35˚ 21΄ to 35˚ 24΄E longitude. The Taknar structural zone, situated in the North central Iranian micro continent, is part of the Lut block (Forster, 1978. The Taknar zone is an allochthonous block bounded by the Darouneh and Taknar major faults. Much of this zone consists of metarhyolite-rhyodacite volcanic rocks, and rhyolitic tuff with interlayers of sandstone and dolomite (Taknar Formation. Analytical Results ICP-MS analysis of REE and minor elements of samples of the Bornaward metarhyolites was carried out at the ACME Laboratory in Vancouver, Canada. U-Pb dating of the metarhyolites was performed on isolated zircons in Crohn's Laser Lab, in Arizona (Gehrels et al., 2008. Measurement of Rb, Sr, Sm and Nd isotopes and (143Nd/144Ndi and (87Sr/86Sri ratios took place in the radioisotope laboratory of the University of Aveiro in Portugal. Petrography The volcanic rocks are porphyritic, commonly containing phenocrysts of orthoclase and rarely sanidine, quartz and intermediate plagioclase in a groundmass of fine-grained quartz and feldspar. An alteration has produced oriented needles of sericite and clay minerals, clusters of fine-grained green biotite and clots of epidote and chlorite. Geochemistry The compositions of the volcanic rocks are calc alkaline and high K- calc alkaline. The obtained Shand index (Al2O3/( CaO+Na2O+K2O is above 1.1, in the peraluminous S-type granite field (Chappell and White, 2001. Plotted on the TAS diagram (Middlemost, 1994, all the metarhyolite-rhyodacite samples are located in the sub-alkaline field and the majority fall into the rhyolite group. The metarhyolite-rhyodacites show enrichment of LREE with a moderately ascending pattern ((La/YbN=2.51-10.11 and La=46.45-145.48. Europium shows a negative anomaly (Eu/Eu*=0.23-0.71. U-Pb

  18. U-Pb Zircon geochronology of the Cambro-Ordovician metagranites and metavolcanic rocks of central and NW Iberia

    Science.gov (United States)

    Talavera, C.; Montero, P.; Bea, F.; González Lodeiro, F.; Whitehouse, M.

    2013-01-01

    New U-Pb zircon data from metagranites and metavolcanic rocks of the Schist-Graywacke Complex Domain and the Schistose Domain of Galicia Tras-os-Montes Zone from central and NW Iberia contribute to constrain the timing of the Cambro-Ordovician magmatism from Central Iberian and Galicia Tras-os-Montes Zones which occurred between 498 and 462 Ma. The crystallization ages of the metagranites and metavolcanic rocks from the northern Schist-Graywacke Complex Domain are as follows: (a) in west Salamanca, 489 ± 5 Ma for Vitigudino, 486 ± 6 Ma for Fermoselle and 471 ± 7 Ma for Ledesma; (b) in northern Gredos, 498 ± 4 Ma for Castellanos, 492 ± 4 Ma for San Pelayo and 488 ± 3 Ma for Bercimuelle; (c) in Guadarrama, 490 ± 5 Ma for La Estación I, 489 ± 9 Ma for La Cañada, 484 ± 6 Ma for Vegas de Matute (leucocratic), 483 ± 6 Ma for El Cardoso, 482 ± 8 Ma for La Morcuera, 481 ± 9 Ma for Buitrago de Lozoya, 478 ± 7 Ma for La Hoya, 476 ± 5 Ma for Vegas de Matute (melanocratic), 475 ± 5 Ma for Riaza, 473 ± 8 Ma for La Estación II and 462 ± 11 Ma for La Berzosa; and (d) in Toledo, 489 ± 7 Ma for Mohares and 480 ± 8 Ma for Polán. The crystallization ages of the metagranites from the Schistose Domain of Galicia Tras-os-Montes Zone are 497 ± 6 Ma for Laxe, 486 ± 8 Ma for San Mamede, 482 ± 7 Ma for Bangueses, 481 ± 5 Ma for Noia, 480 ± 10 for Rial de Sabucedo, 476 ± 9 Ma for Vilanova, 475 ± 6 Ma for Pontevedra, 470 ± 6 Ma for Cherpa and 462 ± 8 Ma for Bande. This magmatism is characterized by an average isotopic composition of (87Sr/86Sr)485Ma ≈ 0.712, (ɛNd)485Ma ≈ -4.1 and (TDM) ≈ 1.62 Ga, and a high zircon inheritance, composed of Ediacaran-Early Cambrian (65 %) and, to a lesser extent, Cryogenian, Tonian, Mesoproterozoic, Orosirian and Archean pre-magmatic cores. Combining our geochronological and isotopic data with others of similar rocks from the European Variscan Belt, it may be deduced that Cambro-Ordovician magmas from this belt were mainly

  19. A combined study of SHRIMP U-Pb dating, trace element and mineral inclusions on high-pressure metamorphic overgrowth zircon in eclogite from Qinglongshan in the Sulu terrane

    Institute of Scientific and Technical Information of China (English)

    LI Qiuli; LI Shuguang; HOU Zhenhui1; HONG Jian; YANG Wei1

    2005-01-01

    Methods recently advanced for discrimination on the genesis of metamorphic zircon, such as analysis of mineral inclusions and trace elements, provide us powerful means to distinguish zircon overgrowth during high-pressure metamorphism. Zircons in ultrahigh-pressure eclogite from Qinglongshan in the Sulu terrane were studied by the SHRIMP U-Pb method in combining with trace element and mineral inclusion analyses. No inherited core was identified in the analyzed zircons by means of cathodoluminescence images. The occurrence of high-pressure metamorphic mineral inclusions in zircon, such as garnet, omphacite, rutile, and the flat HREE pattern in zircon indicate that the zircon formed at high-pressure metamorphic conditions. Therefore, a weighted average U-Pb age of 227.4 ± 3.5 Ma obtained from such a kind of zircon is interpreted to represent the timing of peak metamorphism for the Qinglongshan eclogite.

  20. Elemental bioimaging of Cisplatin in Caenorhabditis elegans by LA-ICP-MS

    Science.gov (United States)

    Crone, Barbara; Aschner, Michael; Schwerdtle, Tanja; Karst, Uwe; Bornhorst, Julia

    2015-01-01

    Cis-diamminedichloroplatinum(II) (Cisplatin) is one of the most important and frequently used cytostatic drugs for the treatment of various solid tumors. Herein, a laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) method incorporating a fast and simple sample preparation protocol was developed for the elemental mapping of Cisplatin in the model organism Caenorhabditis elegans (C. elegans). The method allows imaging of the spatially-resolved elemental distribution of platinum in the whole organism with respect to the anatomic structure in L4 stage worms at a lateral resolution of 5 µm. In addition, a dose- and time-dependent Cisplatin uptake was corroborated quantitatively by a total reflection X-ray fluorescence spectroscopy (TXRF) method, and the elemental mapping indicated that Cisplatin is located in the intestine and in the head of the worms. Better understanding of the distribution of Cisplatin in this well-established model organism will be instrumental in deciphering Cisplatin toxicity and pharmacokinetics. Since the cytostatic effect of Cisplatin is based on binding the DNA by forming intra- and interstrand crosslinks, the response of poly(ADP-ribose)metabolism enzyme 1 (pme-1) deletion mutants to Cisplatin was also examined. Loss of pme-1, which is the C. elegans ortholog of human poly(ADP-ribose) polymerase 1 (PARP-1) led to disturbed DNA damage response. With respect to survival and brood size, pme-1 deletion mutants were more sensitive to Cisplatin as compared to wildtype worms, while Cisplatin uptake was indistinguishable. PMID:25996669

  1. Zircon U-Pb Age, Trace Element, and Hf Isotope Evidence for Paleoproterozoic Granulite-Facies Metamorphism and Archean Crustal Remnant in the Dabie Orogen

    Institute of Scientific and Technical Information of China (English)

    Lei Nengzhong; Wu Yuanbao

    2008-01-01

    Zircon U-Pb age, trace elements, and Hf isotopes were determined for granulite and gneiss at Huaugtuling (黄土岭), which is hosted by ultrahigh-pressure metamorphic rocks in the Dabie(大别) orogen, east-central China. Cathodolumineseence (CL) images reveal core-rim structure for most zircons in the granulite. The cores show oscillatory zoning, relatively high Th/U and 176 Lu/177 Hf ratios, and high rare earth element (HREE)-enriched pattern, consistent with magmatic origin. They gave a weighted mean 207 Pb/206 Pb age of (2 766±9) Ma, dating magma emplacement of protolith. The rims are characterized by sector ur planar zoning, low Th/U and 176 Lu/177 Hf ratios, negative Euanomalies and flat HREE patterns, consistent with their formation under granulite-facies metamorphicconditions. Zircon U-Pb dating yields an age of (2 029±13) Ma, which is interpreted as a record ofmetamorphic event during the assembly of the supercontinent Columbia. The gneiss has a protolith ageof (1982±14) Ma, which is similar to the zircon U-Pb age for the granulite-facies metamorphism,suggesting complementary processes to granulite-facies metamorphism and partial melting. A fewinherited cores with igneous characteristics have 207 pb/206 Pb ages of approximately 3.53, 3.24, and 2.90Ga, respectively, suggesting the presence of Mesoarchean to Paleoarchean crustal remnants. A fewTriassic and Cretaceous metamorphic ages were obtained, suggesting the influences by the Triassiccontinental collision and postcollisional collapse in response to the Cretaceous extension. Comparingwith abundant occurrence of Triassic metamorphic zircons in ultrahigh-pressure eclogite and granitehydrous melt is evident for zircon growth in theHuangtuling granulite and gneiss during thecontinental collision. The magmatic protolithzircons from the granulite show a large variationin 176 Hf/177 Hf ratios from 0.280 809 to 0.281 289,corresponding to era(t) values of-7.3 to 6.3 andHf model ages of 2.74 to 3.34 Ga. The 2

  2. Petrogenesis and tectonic setting of Mingnandong pluton in Yanbian area:Constraints from petro-geochemistry and zircon U-Pb ages%延边地区明南洞岩体的成因及构造背景:岩石地球化学、锆石U-Pb年龄的制约

    Institute of Scientific and Technical Information of China (English)

    雷聪聪; 李世超; 刘正宏; 徐仲元; 张超; 白新会

    2014-01-01

    In this paper Mingnandong pluton was studied throughly by such means as field observation, LA-ICP-MS zircon U-Pb isotopic measurement and petro-geochemistry. The results show that Mingnandong pluton was formed in the Early Jurassic (180.47± 0.71Ma). Chemical analyses yielded the following data for Mingnandong pluton: SiO2=60.71%-67.72%, Al2O3=15.60%-17.44%, Na2O+K2O=6.79%-7.63%, K2O/Na2O=0.61-1.01 and A/CNK=0.94-1.01, implying high-potassium calc-alkaline I-type granites. Besides, Mingnandong pluton is enriched in light rare earth elements and large ion lithophile elements, and depleted in heavy rare earth elements and high field strength elements. These features suggest that Mingnandong pluton has obvious characteristics of active continental margin and volcanic arc granites. The ingredient zonation parallel to the orientation of the subduction of oceanic crust made up of cale-alkaine, high-K calc-alkaline granites and the bimodal volcanic rock association from Yanbian and Taiping Mountain to Xiao Hinggan Mountains and Zhangguangcai Mountain indicate the orientation of the subduction of ancient Pacific plate. In a word, the emplacement of Mingnandong pluton was influenced by the subduction of ancient Pacific plate in the Early Jurassic.%通过野外观测、锆石LA-ICP-MS U-Pb同位素测定及岩石地球化学等手段,详细地对延边地区明南洞岩体进行了研究。研究表明,延边地区明南洞岩体的成岩年龄为(180.5±0.7) Ma,为早侏罗世岩浆事件的产物。明南洞岩体中SiO2含量为60.71%~67.72%,Al2O3含量为15.60%~17.44%,全碱(Na2O+K2O)值为6.79%~7.63%,K2O/Na2O值为0.61~1.01,A/CNK=0.94~1.01,属高钾钙碱性I型花岗岩,并具有富集轻稀土元素和大离子亲石元素,亏损重稀土元素和高场强元素的特征。以上特征表明,明南洞岩体具有显著的活动大陆边缘及火山弧花岗岩的特点。延边-太平岭地区的陆缘钙碱性、高钾钙碱性花岗岩到张

  3. Paleoproterozoic mojaveprovince in northwestern Mexico? Isotopic and U-Pb zircon geochronologic studies of precambrian and Cambrian crystalline and sedimentary rocks, Caborca, Sonora

    Science.gov (United States)

    Lang, Farmer G.; Bowring, S.A.; Matzel, J.; Maldonado, G.E.; Fedo, C.; Wooden, J.

    2005-01-01

    Whole-rock Nd isotopic data and U-Pb zircon geochronology from Precambrian crystalline rocks in the Caborca area, northern Sonora, reveal that these rocks are most likely a segment of the Paleoproterozoic Mojave province. Supporting this conclusion are the observations that paragneiss from the ??? 1.75 Ga Bamori Complex has a 2.4 Ga Nd model age and contains detrital zircons ranging in age from Paleo- proterozoic (1.75 Ga) to Archean (3.2 Ga). Paragneisses with similar age and isotopic characteristics occur in the Mojave province in southern California. In addition, "A-type" granite exposed at the southern end of Cerro Rajon has ca 2.0 Ga Nd model age and a U-Pb zircon age of 1.71 Ga, which are similar to those of Paleoproterozoic granites in the Mojave province. Unlike the U.S. Mojave province, the Caborcan crust contains ca. 1.1 Ga granite (Aibo Granite), which our new Nd isotopic data suggest is largely the product of anatexis of the local Precambrian basement. Detrital zircons from Neoproterozoic to early Cambrian miogeoclinal arenites at Caborca show dominant populations ca. 1.7 Ga, ca. 1.4 Ga, and ca. 1.1 Ga, with subordinate Early Cambrian and Archean zircons. These zircons were likely derived predominately from North American crust to the east and northeast, and not from the underlying Caborcan basement. The general age and isotopic similarities between Mojave province basement and overlying miogeoclinal sedimentary rocks in Sonora and southern California is necessary, but not sufficient, proof of the hypothesis that Sonoran crust is allochthonous and was transported to its current position during the Mesozoic along the proposed Mojave-Sonora megashear. One viable alternative model is that the Caborcan Precambrian crust is an isolated, autochthonous segment of Mojave province crust that shares a similar, but not identical, Proterozoic geological history with Mojave province crust found in the southwest United States ?? 2005 Geological Society of America.

  4. U-Pb zircon geochronology and Nd-Hf-O isotopic systematics of the Neoproterozoic Hadb adh Dayheen ring complex, Central Arabian Shield, Saudi Arabia

    Science.gov (United States)

    Ali, Kamal A.; Jeon, Heejin; Andresen, Arild; Li, Shuang-Qing; Harbi, Hesham M.; Hegner, Ernst

    2014-10-01

    A combined study of single zircon U-Pb dating, Hf-O zircon isotopic analyses and whole-rock Nd isotopic compositions was carried out to infer the magma sources of Neoproterozoic post-collisional A-type granitoids in Saudi Arabia. U-Pb zircon dating of magmatic zircons of two samples from the Hadb adh Dayheen ring complex yielded ages of 625 ± 11 Ma for a hornblende-biotite granite sample, and 613 ± 4 Ma for a monzogranite sample. The granitic rocks show initial εNd values of + 4.1 to + 5.3 and εHf of + 4.5 to + 8.4 that are lower than those of a model depleted mantle (εHf ~+ 14 and εNd ~+ 6.5) and consistent with melting of subduction-related crustal protoliths that were formed during the Neoproterozoic assembly of the Arabian-Nubian Shield (ANS). Crustal-model ages (Hf-tNC) of 0.81 to 1.1 Ga are inconsistent with depleted-mantle Nd model ages of 0.71 to 0.81 Ga and indicate that the post-collisional Hadb adh Dayheen granites were derived mostly from juvenile crust formed in Neoproterozoic time. Single zircons data show a wide range in δ18O values from + 3.2‰ to + 6.4‰, possibly indicating crystallization of zircon from magma derived from magmatic rocks altered by meteoric water in a magma chamber-caldera system.

  5. Fingerprinting the K/T impact site and determining the time of impact by U-Pb dating of single shocked zircons from distal ejecta

    Science.gov (United States)

    Krogh, T. E.; Kamo, S. L.; Bohor, B. F.

    1993-01-01

    U-Pb isotopic dating of single 1 - 3 micrograms zircons from K/T distal ejecta from a site in the Raton Basin, Colorado provides a powerful new tool with which to determine both the time of the impact event and the age of the basement at the impact site. Data for the least shocked zircons are slightly displaced from the 544 +/- 5 Ma primary age for a component of the target site, while those for highly shocked and granular grains are strongly displaced towards the time of impact at 65.5 +/- 3.0 Ma. Such shocked and granular zircons have never been reported from any source, including explosive volcanic rocks. Zircon is refractory and has one of the highest thermal blocking temperatures; hence, it can record both shock features and primary and secondary ages without modification by post-crystallization processes. Unlike shocked quartz, which can come from almost anywhere on the Earth's crust, shocked zircons can be shown to come from a specific site because basement ages vary on the scale of meters to kilometers. With U-Pb zircon dating, it is now possible to correlate ejecta layers derived from the same target site, test the single versus multiple impact hypothesis, and identify the target source of impact ejecta. The ages obtained in this study indicate that the Manson impact site, Iowa, which has basement rocks that are mid-Proterozoic in age, cannot be the source of K/T distal ejecta. The K/T distal ejecta probably originated from a single impact site because most grains have the same primary age.

  6. A simple metal staining procedure for identification and visualization of single cells by LA-ICP-MS.

    Science.gov (United States)

    Herrmann, A J; Techritz, S; Jakubowski, N; Haase, A; Luch, A; Panne, U; Mueller, L

    2017-05-21

    High lateral resolution of metal detection in single cells by use of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) demands powerful staining methods. In this work different staining procedures for the single cell analysis with LA-ICP-MS were optimized. An iridium intercalator was utilized to stain the cell nuclei whereas the whole cell was stained by the use of maleimido-mono-amide-DOTA (mDOTA) complexing lanthanide(iii) ions. The content of the artificially introduced metals per cell was quantified using a matrix matched calibration approach based on cellulose membranes onto which standards were spotted by a microarray spotter. Absolute metal stain amounts in the range of 2.34 to 9.81 femtomole per cell were determined. The metal staining procedures allow direct identification and visualization of single cells and their cell compartments by element microscopy without the use of bright field images of the sample.

  7. Analysis of Rare Earth Elements in Rock and Mineral Samples by ICP-MS and LA-ICP-MS

    Science.gov (United States)

    Sindern, Sven

    2017-02-01

    The group of the rare earth elements (REEs) serves as valuable indicator of numerous geological processes such as magma formation or fluid-rock interaction. The decay systems of the radioactive REE isotopes 138La, 147Sm and 176Lu are used for geochronometric dating of a range of events, starting from first steps of planetary formation to younger steps of geodynamic development. Thus, the abundance of all REEs occurring in a large range of concentrations as well as precise isotope ratios must be analysed in different geomaterials. The inductively coupled plasma (ICP) ion source and various types of mass spectrometers (MS) represent the basis to fulfil the analytical requirements of geoscientific studies. Today, ICP-quadrupole MS and ICP-sector field MS (SFMS) with a single detector or multiple ion collection (MC-ICP-MS) are standard instruments for REE analyses in the geosciences. Due to the need for in situ analysis, laser ablation (LA)-ICP-MS has become an important trace element microprobe technique, which is widely applied for determination of REE concentrations and isotope compositions in geoscientific laboratories. The quality of concentration analysis or isotope ratio determination of REEs by ICP-MS and LA-ICP-MS is affected by many parameters. Most significant are interferences caused by polyatomic oxide and hydroxide ion species formed in the plasma as well as fractionation effects leading to non-stoichiometric behaviour during element determination or to biased isotope ratio measurements. Laser-induced fractionation and isobaric interferences have to be considered as additional effects for LA-ICP-MS. As analyte elements and matrix are unseparated, mineral standards matching the matrix of samples are a prerequisite for accurate and precise REE concentration and isotope ratio determination. Application of fs lasers instead of the more common ns lasers in LA-ICP-MS systems turns out to be a significant step to reduce laser-induced fractionation and to

  8. Detecting art forgeries using LA-ICP-MS incorporating the in situ application of laser-based collection technology.

    Science.gov (United States)

    Smith, Kari; Horton, Kristin; Watling, R John; Scoullar, Natalie

    2005-08-15

    The nature of art lends itself to forgery as a skilled and determined forger can mimic the techniques and styles of an artist to a level where even an expert can be duped. The authentication of paintings is a subjective process, but modern techniques may provide the means to provenance artist pigments based on elemental composition. This study applies laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) to the analysis of artist paints from different manufacturers to identify variation between the elemental association patterns of these materials. The technique facilitates comparison of the paints used by an artist with produced works of art to assist provenancing initiatives of questioned materials. The effects of the trace element profiles of the backing substrate and binder on analytical data were also identified. By applying the technique to paint scraped from real paintings, a limited database was created to allow comparison to be made with some of Australian artist, Kathleen O'Connor's artworks and assist in determining production chronology. Data from this study were able to facilitate comparison of blue paints from two different paintings and confirm their co-provenance consequently determining the relative production date of a separate painting of previously unknown age. Preliminary trials of a prototype collection device designed to reduce damage and allow for in situ sampling of artworks were also undertaken. The device, which allows direct laser-based sampling of a complete painting, was tested using a Francis Ryan painting. The prototype allows for the collection of debris directly generated by LA-ICP-MS of a predefined area of a painting prior to subsequent analysis using direct LA-ICP-MS. This collection method significantly minimizes the amount of damage produced by conventional sampling methods. Analyses of the debris collected, using the prototype, were found to be comparable to the scrapings of equivalent paint analysed using

  9. LA-iMageS: a software for elemental distribution bioimaging using LA-ICP-MS data.

    Science.gov (United States)

    López-Fernández, Hugo; de S Pessôa, Gustavo; Arruda, Marco A Z; Capelo-Martínez, José L; Fdez-Riverola, Florentino; Glez-Peña, Daniel; Reboiro-Jato, Miguel

    2016-01-01

    The spatial distribution of chemical elements in different types of samples is an important field in several research areas such as biology, paleontology or biomedicine, among others. Elemental distribution imaging by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is an effective technique for qualitative and quantitative imaging due to its high spatial resolution and sensitivity. By applying this technique, vast amounts of raw data are generated to obtain high-quality images, essentially making the use of specific LA-ICP-MS imaging software that can process such data absolutely mandatory. Since existing solutions are usually commercial or hard-to-use for average users, this work introduces LA-iMageS, an open-source, free-to-use multiplatform application for fast and automatic generation of high-quality elemental distribution bioimages from LA-ICP-MS data in the PerkinElmer Elan XL format, whose results can be directly exported to external applications for further analysis. A key strength of LA-iMageS is its substantial added value for users, with particular regard to the customization of the elemental distribution bioimages, which allows, among other features, the ability to change color maps, increase image resolution or toggle between 2D and 3D visualizations.

  10. Zircon U-Pb geochronological framework of Qitianling granite batholith, middle part of Nanling Range, South China

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The Qitianling granite batholith (QGB) is located in the southern Hunan Province, middle part of the Nanling Range, South China. Its total exposure area is about 520 km2. Based on our 25 single grain zircon U-Pb age data and 7 published data as well as the geological, petrological, and space distribution characteristics, we conclude that QGB is an Early Yanshanian (Jurassic) multi-staged composite pluton. Its formation process can be subdivided into three major stages. The first stage, emplaced at 163―160 Ma with a peak at about 161 Ma, is mainly composed of hornblende-biotite monzonitic granites and locally biotite granites, and distributed in the eastern, northern, and western peripheral parts of the pluton. The second stage, emplaced at 157―153 Ma with a peak at 157―156 Ma, is mainly composed of biotite granites and locally containing hornblende, and distributed in the middle and southeastern parts of the pluton. The third stage, emplaced at 150―146 Ma with a peak at about 149 Ma, is mainly composed of fine-grained (locally porphyritic) biotite granites, and distributed in the middle-southern part of the pluton. Each stage can be further disintegrated into several granite bodies. The first two intrusive stages comprise the major phase of QGB, and the third intrusive stage comprises the additional phase. Many second stage fine-grained granite bosses and dykes intruded into the first stage host granites with clear chilling margin-baking phenomena at their intrusive contacts. They were emplaced in the open fracture space of the earlier stage consolidated rocks. Their isotopic ages are mostly 2―6 Ma younger than their hosts. Conceivably, the time interval from magma emplacement, through cooling, crystallization, solidification, up to fracturing of the earlier stage granites cannot exceed 2―6 Ma. During the Middle-Late Jurassic in the Qitianling area and neighboring Nanling Range, the coeval granitic and basic-intermediate magmatic activities were widely

  11. Application of gold thin-films for internal standardization in LA-ICP-MS imaging experiments.

    Science.gov (United States)

    Bonta, Maximilian; Lohninger, Hans; Marchetti-Deschmann, Martina; Limbeck, Andreas

    2014-03-21

    LA-ICP-MS imaging experiments are of growing interest within the field of biosciences. Revealing the distributions of major components as well as trace elements in biological samples can help to understand fundamental biological processes. However, highly variable sample conditions and changing instrumental parameters during measurement time aggravate reliable quantification especially in biological tissues. Normally matrix matched standards used for calibration are scarcely available and the manufacturing process thereof is rather complicated. Thus most experiments reported in the literature only delivered qualitative information on the analyte distributions. The use of appropriate internal standards facilitates the preparation of calibrations even without the utilization of matrix-matched standards. In the presented work an approach for providing reliable quantitative bio-images is proposed using gold thin-layers as an internal standard and patterns printed with commercially available inkjet printers as standards. The method development is based on copper from blue ink as the element of interest. It could be shown that gold standardization compensates instrumental drifts, matrix related ablation differences and day-to-day signal changes. Not only was the quality of the obtained images improved by gold standardization; while the relative standard deviation of the measurements was around 15% before standardization it could be decreased to less than 5% by gold standardization. Also quantitative information could be obtained for samples with unknown analyte concentrations. Depending on the used beam diameter limits of detection in the range of some hundreds ng g(-1) were achieved. The presented method is a promising and easy-to-handle alternative to matrix matched standards for signal quantification.

  12. LA-ICP-MS for Pu source identification at Mayak PA, the Urals, Russia.

    Science.gov (United States)

    Cagno, S; Hellemans, K; Lind, O C; Skipperud, L; Janssens, K; Salbu, B

    2014-02-01

    Information on Pu in environmental samples is traditionally based on the determination of the (240+239)Pu activity via Alpha Spectrometry (AS). A large number of alpha spectrometry sources (planchettes) containing radiochemically separated Pu are therefore stored worldwide and are available for further analyses. These archive samples represent a resource from which valuable information on isotopic composition of alpha emitters including Pu can be obtained. The relative abundances of Pu isotopes can be used to trace specific Pu sources and characterize the relative contributions of different Pu sources in a sample. Thus, in addition to the total (239+240)Pu activity, determination of the (240)Pu/(239)Pu ratio can provide valuable information on the nature of the Pu emitting sources. The Pu isotopic ratios can be determined by mass spectrometry techniques such as Sector Field Inductively Coupled Plasma Mass Spectrometry (SF-ICPMS) or Accelerator Mass Spectrometry (AMS) that require dissolution and complete destruction of the material deposited on the planchettes. In this study Laser Ablation (LA)-quadrupole-ICP-MS has been employed for the analysis of (239)Pu/(240)Pu ratios from alpha-planchettes prepared from samples originating from the Mayak PA nuclear facility, Russia. The results are compared with data from AMS and show that the (240)Pu/(239)Pu ratios obtained by LA-ICP-MS can be utilized to distinguish weapons-grade Pu from civil reprocessing sources. Moreover, isotope ratio mapping can also be performed across the planchettes, allowing e.g. the visualization of possible inhomogeneities in the Pu-isotope distribution on their surface. Thus, this solid sample technique can be applied to extract additional information from existing archives of samples.

  13. Paleo-Pacific subduction-accretion: Evidence from Geochemical and U-Pb zircon dating of the Nadanhada accretionary complex, NE China

    Science.gov (United States)

    Zhou, Jian-Bo; Cao, Jia-Lin; Wilde, Simon A.; Zhao, Guo-Chun; Zhang, Jin-Jiang; Wang, Bin

    2014-12-01

    The Nadanhada Terrane, located along the eastern margin of Eurasia, contains a typical accretionary complex related to paleo-Pacific plate subduction-accretion. The Yuejinshan Complex is the first stage accretion complex that consists of meta-clastic rocks and metamafic-ultramafic rocks, whereas the Raohe Complex forms the main parts of the terrane and consists of limestone, bedded chert, and mafic-ultramafic rocks embedded as olistolith blocks in a weakly sheared matrix of clastic meta-sedimentary rocks. Geochemical data indicate that the Yuejinshan metabasalts have normal mid-ocean ridge basalt (N-MORB) affinity, whereas the Raohe basaltic pillow lavas have an affinity to ocean island basalts (OIB). Sensitive high-resolution ion microprobe (SHRIMP) U-Pb zircon analyses of gabbro in the Raohe Complex yield a weighted mean 206Pb/238U zircon age of 216 ± 5 Ma, whereas two samples of granite intruded into the complex yield weighted mean 206Pb/238U zircon ages of 128 ± 2 and 129 ± 2 Ma. Laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) U-Pb zircon analyses of basaltic pillow lava in the Raohe Complex define a weighted mean age of 167 ± 1 Ma. Two sandstone samples in the Raohe Complex record younger concordant zircon weighted mean ages of 167 ± 17 and 137 ± 3 Ma. These new data support the view that accretion of the Raohe Complex was between 170 and 137 Ma, and that final emplacement of the Raohe Complex took place at 137-130 Ma. The accretion of the Yuejinshan Complex probably occurred between the 210 and 180 Ma, suggesting that paleo-Pacific plate subduction was initiated in the Late Triassic to Early Jurassic.

  14. U-Pb (LA-PIMMS) Ages of Inherited Zircons from Early Palaeozoic Granitoids of the W Sudetes, N Bohemian Massif, Central Europe: Implications for Neoproterozoic Continental Reconstructions

    Science.gov (United States)

    Crowley, Q. G.; Patocka, F.; Kachlík, V.

    2003-04-01

    A U-Pb laser ablation plasma ionisation multi-collector mass spectrometry (LA-PIMMS) geochronological study of zircons from early Palaeozoic (meta)granitoids of the Czech W Sudetes (E Saxothuringian Zone), NW Bohemian Massif, was carried out in order to determine the range of inherited age spectra preserved in these lithologies. Backscattered SEM images indicate that many zircons have distinct cores and rims. The majority of inherited zircon components yield concordant U-Pb ages that fall into the following age ranges: (1) 520-770 Ma, (2) 1.9-2.2 Ga and (3) ca. 3.0 Ga. These three age populations are typical of the W African Craton and the Armorican Terrane Assemblage of Europe. The age spectra correspond to Cadomian, Birimian / Icartian / Eburnean / Burkinian and Leonian events respectively. Some previous Pb-Pb zircon and whole rock Nd studies of similar lithologies from the W Sudetes (e.g. Hegner &Kröner, 2000) have attributed the presence of Mesoproterozoic 207Pb/206Pb ages to a peri-Amazonian provenance. Although some zircons from this study have yielded apparent Mesoproterozoic ages, they are discordant and can be resolved into early Palaeozoic to Neoproterozoic lower intercept and Palaeoproterozoic to Archaean upper intercept components. This unequivocally proves that an inherited Grenvillian component does not exist in these lithologies. We therefore favour derivation of the Saxothuringian zone and associated members of the Armorican Terrane Assemblage from a W African Craton Gondwanan setting. References: Hegner, E, &Kröner, A. 2000. Review of Nd data and xenocrystic and detrital ages from the pre-Variscan basement in the Eastern Bohemian Massif: speculations on palinspastic reconstructions. In: Franke, W., Altherr, R., Haak, V. &Oncken, O. (eds.), Orogenic Processes: Quantification and Modelling in the Variscan Belt of Central Europe Geological Society of London Special Publication, 179, 113-129.

  15. SHRIMP U-Pb zircon age of tuff from the Kunyang Group in central Yunnan: Evidence for Grenvillian orogeny in South China

    Institute of Scientific and Technical Information of China (English)

    ZHANG ChuanHeng; GAO LinZhi; WU ZhenJie; SHI XiaoYing; YAN QuanRen; LI DaJian

    2007-01-01

    Whether or not Grenvillian orogeny occurred in South China still remains highly controversial because high-quality, discriminating data are lacking, and therefore, the key to resolve this matter is to find datable volcanic and/or sedimentary rocks related to Grenvillian orogeny. Such rocks are apparently present in the Fuliangpeng Member from the lower-middle part of Kunyang Group in central Yunnan;here the unit is more than 100 m thick and consists of andesitic ignimbrite, tuffite, terrigeous clastic rocks and carbonates. These volcanic rocks, developed south of the Sibao fold-thrust belts, represent the earliest calc-alkaline volcanic activity in late Precambrian time from central Yunnan and are coeval with both a change in sedimentary facies from detritus to carbonates and the beginning of seismite development elsewhere. Two samples for SHRIMP analysis were collected from this volcanic unit.Sample G3-29-2, from the bottom of Fuliangpeng Member, is an ignimbrite, and about 100 zircon crystals recovered from it have euhedral shapes and display relatively simple sector zonation under cathodoluminescent (CL) imaging, suggesting a magmatogenic origin. Twenty-five of the zircons were analyzed and a weighed-mean U-Pb age of 1032±9 Ma was obtained. Sample G3-29-3 from uppermost part of Fuliangpeng Member is a tuffite, and many rounded, evidently detrital zircons were recovered.Nine of these zircons were analyzed, and the oldest single-grain U-Pb zircon age is 1938±26 Ma, implying that Paleoproterozoic basement developed in Cathaysia. The dating result, combined with the geotectonic research on the Fuliangpeng Member, leads us to conclude that late Mesoproterozoic orogenic volcanic activity occurred in the western part of South China, and that the related collision of Yangtze and Cathaysian cratons was an integral part of the assembly of Rodinia.

  16. Laser Ablation Split Stream (LASS) U-Pb & Lu-Hf Isotope Analysis of Detrital Zircons from the Old Red Sandstone, NW Svalbard: Implications for Northern Caledonian Paleogeography

    Science.gov (United States)

    Beranek, L. P.; Gee, D. G.; Fisher, C. M.

    2015-12-01

    The Svalbard archipelago consists of three Caledonian provinces that were assembled by thrusting and transcurrent faulting during the Silurian and Devonian in a location directly northeast of the Greenland Caledonides. Syn- to post-orogenic alluvial strata, referred to as the Old Red Sandstones, filled pull-apart basins adjacent to the transcurrent faults and comprise cover assemblages that help constrain the timing of the Caledonian orogeny. To further investigate the tectonic history and paleogeography of the Raudfjorden-Liefdefjorden-Woodfjorden area of Spitsbergen, NW Svalbard, we analyzed rock samples of the Old Red Sandstones and underlying Precambrian basement complexes for detrital zircon analysis. Laboratory studies of the Old Red Sandstones include the novel Laser Ablation Split Stream (LASS) technique, which allows for simultaneous U-Pb & Lu-Hf isotope analysis of zircon crystals. Lower Devonian Red Bay Group strata contain a range of early Neoproterozoic to Neoarchean detrital zircons with prominent age peaks c. 960, 1050, 1370, 1450, 1650, and 2700 Ma; subordinate Ordovician (c. 460-490 Ma) and Cryogenian (c. 650 Ma) detrital zircons occur in a subset of the samples. Underlying Precambrian metasedimentary rocks are composed of similar earliest Neoproterozoic to Neoarchean age populations, which argues for much of the Red Bay Group to be derived from local basement rocks during thrusting and other faulting. The U-Pb ages and Hf isotope compositions of Paleozoic to Neoarchean detrital zircons are consistent with Arctic crustal evolution, and support the hypothesis that northwestern and northeastern provinces of the Svalbard Caledonides are extruded fragments of the northeast Greenland allochthons. The new Hf isotope results further allow paleogeographic and stratigraphic comparisons with rock assemblages proximal to the North Atlantic Caledonides during the Silurian-Devonian, including the Pearya terrane of Ellesmere Island, Alexander terrane of NW

  17. SHRIMP U-Pb zircon age, geochemistry and Nd isotope of the Guandaoshan pluton in SW Sichuan: Petrogenesis and tectonic significance

    Institute of Scientific and Technical Information of China (English)

    LI; Xianhua(李献华); LI; Zhengxiang(李正祥); ZHOU; Hanwen(周汉文); LIU; Ying(刘颖); LIANG; Xirong(梁细荣); LI; Wuxian(李武显)

    2003-01-01

    SHRIMP U-Pb zircon age, geochemical and Nd isotopic data are reported for the Neoproterozoic Guandaoshan pluton in the Yanbian region, SW Sichuan. This pluton is of typical I-type granite and emplaced at (857±13) Ma. Geochemical and Nd isotopic characters suggest that the pluton was generated by partial melting of pre-existing, young (late Mesoproterozoic to early Neoproterozoic) low-K tholeiitic protolith within an intraplate anorogenic setting. The Guandaoshan pluton probably records the earliest magmatism induced by the proposed ca. 860-750 Ma mantle superplume beneath the supercontinent Rodinia.

  18. Zircon U-Pb and Lu-Hf isotope study of the Neoproterozoic Haizhou Group in the Sulu orogen: Provenance and tectonic implications

    Science.gov (United States)

    Zhou, Jian-Bo; Wilde, Simon A.; Liu, Fu-Lai; Han, Jie

    2012-04-01

    The Neoproterozoic Haizhou Group crops out sporadically in the Sulu orogen in east-central China. It is divided into the Jinping and Yuntai formations and consists of quartzite, quartz schist, marble and graphite- and apatite-bearing sequences. Major and trace element data for quartz schist from the two formations indicate that these rocks have a greywacke protolith and have been deposited during strong tectonic activity. LA-ICPMS U-Pb dating of detrital zircon yields ages of 635 to 1074 Ma for three samples from the Jinping Formation and 611 to 943 Ma for two samples from the Yuntai Formation. More than 78% of the detrital zircons from the two formations have U-Pb ages grouped between 700 and 890 Ma, with two clusters peaking at 758 Ma and 828 Ma, respectively. This indicates that their provenance is magmatic rocks of Neoproterozoic age that have a tectonic affinity to the South China Block (SCB). A few older zircon populations with peak U-Pb ages at 943 and 1074 Ma are also present. A younger population shows peaks at 661 and 611 Ma. This suggests that deposition of the Haizhou Group was later than ~ 611 Ma rather than during the Mesoproterozoic as previously thought. Zircon Lu-Hf isotope data collected from the same U-Pb sites show negative ɛHf(t) values of - 22.8 to - 7.4 and Hf model ages of 2341 to 3100 Ma. This indicates that the Neoproterozoic magmatic rocks were derived from reworking of ancient Paleoproterozoic to Archean crust. The results support the contention that the Haizhou Group is similar to the Wulian Group at the northwestern edge of the Sulu orogen, both having a SCB affinity, but that the Penglai Group does not belong to the SCB because of the absence of Neoproterozoic ages. This lends support to the conclusion that the Triassic suture between the North China and South China blocks is located along the Baichihe-Yantai Fault, which lies north of the Wulian Complex and south of the Jiaobei Terrane; thus the Wulian-Yantai Fault is not the suture

  19. Laser Ablation in situ (U-Th-Sm)/He and U-Pb Double-Dating of Apatite and Zircon: Techniques and Applications

    Science.gov (United States)

    McInnes, B.; Danišík, M.; Evans, N.; McDonald, B.; Becker, T.; Vermeesch, P.

    2015-12-01

    We present a new laser-based technique for rapid, quantitative and automated in situ microanalysis of U, Th, Sm, Pb and He for applications in geochronology, thermochronometry and geochemistry (Evans et al., 2015). This novel capability permits a detailed interrogation of the time-temperature history of rocks containing apatite, zircon and other accessory phases by providing both (U-Th-Sm)/He and U-Pb ages (+trace element analysis) on single crystals. In situ laser microanalysis offers several advantages over conventional bulk crystal methods in terms of safety, cost, productivity and spatial resolution. We developed and integrated a suite of analytical instruments including a 193 nm ArF excimer laser system (RESOlution M-50A-LR), a quadrupole ICP-MS (Agilent 7700s), an Alphachron helium mass spectrometry system and swappable flow-through and ultra-high vacuum analytical chambers. The analytical protocols include the following steps: mounting/polishing in PFA Teflon using methods similar to those adopted for fission track etching; laser He extraction and analysis using a 2 s ablation at 5 Hz and 2-3 J/cm2fluence; He pit volume measurement using atomic force microscopy, and U-Th-Sm-Pb (plus optional trace element) analysis using traditional laser ablation methods. The major analytical challenges for apatite include the low U, Th and He contents relative to zircon and the elevated common Pb content. On the other hand, apatite typically has less extreme and less complex zoning of parent isotopes (primarily U and Th). A freeware application has been developed for determining (U-Th-Sm)/He ages from the raw analytical data and Iolite software was used for U-Pb age and trace element determination. In situ double-dating has successfully replicated conventional U-Pb and (U-Th)/He age variations in xenocrystic zircon from the diamondiferous Ellendale lamproite pipe, Western Australia and increased zircon analytical throughput by a factor of 50 over conventional methods

  20. SHRIMP Zircon U-Pb Dating of Gabbro and Granite from the Huashan Ophiolite, Qinling Orogenic Belt, China: Neoproterozoic Suture on the Northern Margin of the Yangtze Craton

    Institute of Scientific and Technical Information of China (English)

    SHI Yuruo; LIU Dunyi; ZHANG Zongqing; MIAO Laicheng; ZHANG Fuqin; XUE Hongmei

    2007-01-01

    The recently identified Huashan ophiolitic mélange was considered as the eastern part of the Mianliie suture in the Qinling orogenic belt. SHRIMP zircon U-Pb geochronology on gabbro from the Huashan ophiolite and granite intruding basic volcanic rocks indicates crystallization ages of 947±14Ma and 876±17 Ma respectively. These ages do not support a recently proposed Hercynian Huashan Ocean, but rather favor that a Neoproterozoic suture assemblage (ophiolite) is incorporated into the younger (Phanerozoic) Qinling orogenic belt.

  1. Cryogenian U-Pb (SHRIMP I) zircon ages of anorthosites from the upper sequences of Niquelandia and Barro Alto Complexes, Central Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Correia, Ciro Teixeira Vicente; Girardi, Antonio Vitorio; Basei, Miguel Angelo Stipp, E-mail: ccorrei@usp.b, E-mail: girardi@usp.b, E-mail: baseimas@usp.b [Universidade de Sao Paulo (IG/USP), SP (Brazil). Inst. de Geociencias. Dept. de Mineralogia e Geotectonica; Nutman, Allen, E-mail: allen.nutman@anu.edu.a [Australian National University, Camberra (Canada). Research School of Earth Science

    2007-12-15

    The Niquelandia Complex comprises two main superposed sequences dipping westward: the lower (LS), at the eastern, and the upper (US), at the western part of the body. The Complex is either interpreted as a single body, or as two distinct unrelated layered massifs. New SHRIMP U-Pb determinations on igneous zircon grains of anorthosites from Niquelandia US and from the upper portion of the Barro Alto Complex indicate crystallization ages of 833 {+-} 21 Ma and 733 {+-} 25 Ma, respectively, thus supporting Cryogenian Neoproterozoic ages for the igneous crystallization of the US unit of Niquelandia and for the Barro Alto anorthosites. (author)

  2. External calibration strategy for trace element quantification in botanical samples by LA-ICP-MS using filter paper.

    Science.gov (United States)

    Nunes, Matheus A G; Voss, Mônica; Corazza, Gabriela; Flores, Erico M M; Dressler, Valderi L

    2016-01-28

    The use of reference solutions dispersed on filter paper discs is proposed for the first time as an external calibration strategy for matrix matching and determination of As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Sr, V and Zn in plants by laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS). The procedure is based on the use of filter paper discs as support for aqueous reference solutions, which are further evaporated, resulting in solid standards with concentrations up to 250 μg g(-1) of each element. The use of filter paper for calibration is proposed as matrix matched standards due to the similarities of this material with botanical samples, regarding to carbon concentration and its distribution through both matrices. These characteristics allowed the use of (13)C as internal standard (IS) during the analysis by LA-ICP-MS. In this way, parameters as analyte signal normalization with (13)C, carrier gas flow rate, laser energy, spot size, and calibration range were monitored. The calibration procedure using solution deposition on filter paper discs resulted in precision improvement when (13)C was used as IS. The method precision was calculated by the analysis of a certified reference material (CRM) of botanical matrix, considering the RSD obtained for 5 line scans and was lower than 20%. Accuracy of LA-ICP-MS determinations were evaluated by analysis of four CRM pellets of botanical composition, as well as by comparison with results obtained by ICP-MS using solution nebulization after microwave assisted digestion. Plant samples of unknown elemental composition were analyzed by the proposed LA method and good agreement were obtained with results of solution analysis. Limits of detection (LOD) established for LA-ICP-MS were obtained by the ablation of 10 lines on the filter paper disc containing 40 μL of 5% HNO3 (v v(-1)) as calibration blank. Values ranged from 0.05 to 0.81  μg g(-1). Overall, the use of filter paper as support for dried aqueous

  3. SHRIMP zircon U-Pb ages for the Paleoproterozoic metamorphic-magmatic events in the southeast margin of the North China Craton

    Institute of Scientific and Technical Information of China (English)

    GUO SuShu; LI ShuGuang

    2009-01-01

    A garnet-pyroxene bearing amphibolite as a xenolith hosted by the Mesozoic igneous rocks from Xuzhou-Suzhou area was dated by zircon SHRIMP U-Pb method, which yields a metamorphic age of Archean metamorphic complex named Wuhe group in the Bengbu uplift give a metamorphic U-Pb age Bengbu uplift give a magma crystallization U-Pb age of 2054 ± 22 Ma. Both the Xuzhou-Suzhou area and Bengbu uplift are located in the southeastern margin of the North China Craton. Therefore, these ages indicate that there is a Paleoproterozoic tectonic zone in the southeastern margin of the North China Craton, and its metamorphic and magmatic ages are consistent with those of the other three Paleoproterozoic tectonic zones in the North China Craton. In view of the large scale sinistral strike-slip movement occurred at the Mesozoic along the Tan-Lu fault zone, the position of the eastern Shandong area, which is a south section of the Paleoproterozoic Jiao-Liao-Ji Belt, was correlated to Xuzhou-Suzhou-Bengbu area prior to movement of the Tan-Lu fault zone. This suggests that the Xuzhou-Suzhou-Bengbu Paleoproterozoic tectonic zone might be a southwest extension of the Paleoproterozoic Jiao-Liao-Ji Belt.

  4. Grenvillian orogeny in the Southern Cathaysia Block: Constraints from U-Pb ages and Lu-Hf isotopes in zircon from metamorphic basement

    Institute of Scientific and Technical Information of China (English)

    WANG LiJuan; YU JinHai; S.Y. O'REILLY; W.L. GRIFFIN; SUN Tao; WEI ZhenYang; JIANG ShaoYong; SHU LiangShu

    2008-01-01

    Metamorphic basement rocks in the Cathaysia Block are composed mainly of meta-sediments with different ages. New zircon U-Pb geochronological results from the meta-sedimentary rocks exposed in the Zengcheng and Hezi areas, southern Cathaysia Block, show that they consist dominantly of early Neoproterozoic (1.0-0.9 Ga) materials with minor Paleo- to Mesoproterozoic and late Neoproterozoic (0.8-0.6 Ga) components, suggesting that the detritus mostly come from a Grenvillian orogen. The youngest detrital zircon ages place a constraint on the deposition time of these sediments in Late Neoproterozoic. Zircon Hf isotopic compositions indicate that the Grenvillian zircons were derived from the reworking of Mesoproterozoic arc magmatic rocks and Paleoproterozoic continental crust, implying an arc-continent collisional setting. Single-peak age spectra and the presence of abundant euhedral Grenvillian zircons suggest that the sedimentary provenance is not far away from the sample location. Thus, the Grenvillian orogen probably preexisted along the southern margin of the Cathaysia Block, or very close to the south. Similarity in the ages of Grenvillian orogeny and the influence of the assembly of Gondwana in South China with India and East Antarctic are discussed, with suggestion that South China was more likely linked with the India-East Antarctica continents in Early Neoproterozoic rather than between western Laurentia and eastern Australia.

  5. Amplifying Earth history: Zircon U-Pb geochronology by ID-TIMS at the 0.1 ‰ level using new 1013 ohm resistors

    Science.gov (United States)

    Wotzlaw, Jörn-Frederik; von Quadt, Albrecht

    2016-04-01

    Precise and accurate radiometric dating of volcanic ash beds in sedimentary successions is the backbone of the numerical calibration of Earth history. Uranium-lead geochronology by isotope dilution thermal ionization mass spectrometry (ID-TIMS) is the most precise and accurate dating technique and is applicable to most of Earth history from the Hadean to the Pleistocene. The accessory mineral zircon is the prime target material due to its commonly high U concentration, virtually no initial Pb and high daughter-product retentivity. However, complex crystallization histories as well as magmatic and sedimentary recycling of zircons require the analysis of single crystals resulting in small amounts of radiogenic Pb (Pb* usually dates with uncertainties <0.2 ‰ for high-Pb* zircons and weighted mean ages for populations of closed system zircons with uncertainties <0.1 ‰ . This level of temporal resolution will allow to better quantify the timing and durations of critical intervals in Earth history, evaluate causalities between different events such as flood basalt eruptions and mass extinctions, quantify rates of changes in biodiversity and assess the origin of cyclic patterns in the sedimentary records. [1] von Quadt, A., Wotzlaw, J.F., Buret, Y., Large, S., Peytcheva, I., Trinquier, A., 2016, High-precision zircon U/Pb geochronology by ID-TIMS using new 1013 ohm resistors. J. Anal. At. Spectrom., DOI: 10.1039/C5JA00457H

  6. The influence of laser pulse duration and energy on ICP-MS signal intensity, elemental fractionation, and particle size distribution in NIR fs-LA-ICP-MS

    Science.gov (United States)

    Diwakar, Prasoon K.; Harilal, Sivanandan S.; LaHaye, Nicole L.; Hassanein, Ahmed; Kulkarni, Pramod

    2015-01-01

    Laser parameters, typically wavelength, pulse width, irradiance, repetition rate, and pulse energy, are critical parameters which influence the laser ablation process and thereby influence the LA-ICP-MS signal. In recent times, femtosecond laser ablation has gained popularity owing to the reduction in fractionation related issues and improved analytical performance which can provide matrix-independent sampling. The advantage offered by fs-LA is due to shorter pulse duration of the laser as compared to the phonon relaxation time and heat diffusion time. Hence the thermal effects are minimized in fs-LA. Recently, fs-LA-ICP-MS demonstrated improved analytical performance as compared to ns-LA-ICP-MS, but detailed mechanisms and processes are still not clearly understood. Improvement of fs-LA-ICP-MS over ns-LA-ICP-MS elucidates the importance of laser pulse duration and related effects on the ablation process. In this study, we have investigated the influence of laser pulse width (40 fs to 0.3 ns) and energy on LA-ICP-MS signal intensity and repeatability using a brass sample. Experiments were performed in single spot ablation mode as well as rastering ablation mode to monitor the Cu/Zn ratio. The recorded ICP-MS signal was correlated with total particle counts generated during laser ablation as well as particle size distribution. Our results show the importance of pulse width effects in the fs regime that becomes more pronounced when moving from femtosecond to picosecond and nanosecond regimes. PMID:26664120

  7. Dating sub-20 micron zircons in granulite-facies mafic dikes from SW Montana: a new approach using automated mineralogy and SIMS U-Pb geochronology

    Science.gov (United States)

    Ault, A. K.; Mahan, K. H.; Flowers, R. M.; Chamberlain, K.; Appleby, S. K.; Schmitt, A. K.

    2010-12-01

    Geochronological data is fundamental to all tectonic studies, but a major limitation for many lithologies is a paucity of sizeable zircons suitable for conventional U-Pb techniques. In particular, mafic dike swarms provide important time markers for tectonometamorphic activity in Precambrian terranes, but commonly yield little or no zircon or baddeleyite sufficient for TIMS or standard ion-probe analysis of crystal separates. We apply a new approach involving in-situ automated mineralogy and high spatial resolution Secondary Ion Mass Spectrometry (SIMS) geochronology to a mafic dike swarm exposed in the Northern Madison Range of SW Montana. The dikes cross-cut early fabrics but are also variably deformed and metamorphosed to P-T conditions as high as 1.2 GPa and 850 C. The swarm emplacement age is inferred to be ca. 2.1 Ga based on similarities to dated dikes in the adjacent Tobacco Root Mountains. Resolving the timing of dike emplacement and high-grade metamorphism in the study area is important for understanding the extent of post-Archean modification to the northwest margin of the Wyoming craton. Identification and textural characterization of zircons were facilitated by in-situ automated mineralogical analysis, in contrast to a standard elemental X-ray mapping approach. Our technique uses an SEM-based platform coupling calibrated BSE data with X-ray data collected by multiple energy dispersive spectrometers to rapidly identify target accessory phases at high spatial resolution. Whole thin section search maps were generated in ~30 minutes at 4 µm pixel resolution. Our dike thin sections commonly contained >300 zircons in a variety of textural settings, with 80% having a short dimension 95% for 206Pb. SIMS data for 22 zircons from a granulite-facies mafic dike thin section define a chord with upper and lower intercepts of 1753.1 ± 9.5 Ma and 63.2 ± 7.9 Ma, respectively (2 sigma error, MSWD = 1.6). A positive correlation between U concentration and degree of

  8. Paleoproterozoic lower crust beneath Nushan in Anhui Province: Evidence from zircon SHRIMP U-Pb dating on granulite xenoliths in Cenozoic alkali basalt

    Institute of Scientific and Technical Information of China (English)

    HUANG Xiaolong; XU Yigang; LIU Dunyi; JIAN Ping

    2003-01-01

    Zircon SHRIMP U-Pb dating was carried out for an intermediate granulite xenolith in Cenozoic alkali basalt from Nushan. The results suggest that the lower crust beneath Nushan may have formed at about 2400-2200 Ma, and have been subjected to granulite-facies metamorphism at 1915±27 Ma. The old age of the Nushan lower crust is consistent with the geochemical similarities between Nushan granulite xenoliths and Archean-Paleoproterozoic granulite terrains in the NorthChina craton, but it is not distinguishable from high-grade metamorphic rocks in the Yangtze craton where such old ages were also reported. Significant Pb-lossoccurs in the Nushan zircons, implying important influence of widespread Mesozoic to Cenozoic underplating in East China on the lower crust beneath Nushan.

  9. SHRIMP zircon U-Pb age and significance of Early Paleozoic volcanic rocks in East Kunlun orogenic belt, Qinghai Province, China

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Early Paleozoic volcanic rocks in Nuomuhong area occurred as basalt slice and meta-volcanic slice. SHRIMP zircon U-Pb dating of the basalt slice and the meta-volcanic slice show that the age of the basalt slice is 419±5 Ma, and that of the meta-volcanic slice is 401± 6 Ma. These ages directly testify that there existed Early Paleozoic ocean-continent transform in East Kunlun, the basalt slice was formed in an extensional mid-ocean ridge setting and the meta-volcanic rock slice was formed in an extrusion subduction and collision setting. The inherited zircon age of 1734 Ma in volcanic rocks reflects that the base of East Kunlun may be Middle Proterozoic.

  10. Monazite trumps zircon: applying SHRIMP U-Pb geochronology to systematically evaluate emplacement ages of leucocratic, low-temperature granites in a complex Precambrian orogen

    Science.gov (United States)

    Piechocka, Agnieszka M.; Gregory, Courtney J.; Zi, Jian-Wei; Sheppard, Stephen; Wingate, Michael T. D.; Rasmussen, Birger

    2017-08-01

    Although zircon is the most widely used geochronometer to determine the crystallisation ages of granites, it can be unreliable for low-temperature melts because they may not crystallise new zircon. For leucocratic granites U-Pb zircon dates, therefore, may reflect the ages of the source rocks rather than the igneous crystallisation age. In the Proterozoic Capricorn Orogen of Western Australia, leucocratic granites are associated with several pulses of intracontinental magmatism spanning 800 million years. In several instances, SHRIMP U-Pb zircon dating of these leucocratic granites either yielded ages that were inconclusive (e.g., multiple concordant ages) or incompatible with other geochronological data. To overcome this we used SHRIMP U-Th-Pb monazite geochronology to obtain igneous crystallisation ages that are consistent with the geological and geochronological framework of the orogen. The U-Th-Pb monazite geochronology has resolved the time interval over which two granitic supersuites were emplaced; a Paleoproterozoic supersuite thought to span 80 million years was emplaced in less than half that time (1688-1659 Ma) and a small Meso- to Neoproterozoic supersuite considered to have been intruded over 70 million years was instead assembled over 130 million years and outlasted associated regional metamorphism by 100 million years. Both findings have consequences for the duration of associated orogenic events and any estimates for magma generation rates. The monazite geochronology has contributed to a more reliable tectonic history for a complex, long-lived orogen. Our results emphasise the benefit of monazite as a geochronometer for leucocratic granites derived by low-temperature crustal melting and are relevant to other orogens worldwide.

  11. Determinations of rare earth element abundance and U-Pb age of zircons using multispot laser ablation-inductively coupled plasma mass spectrometry.

    Science.gov (United States)

    Yokoyama, Takaomi D; Suzuki, Toshihiro; Kon, Yoshiaki; Hirata, Takafumi

    2011-12-01

    We have developed a new calibration technique for multielement determination and U-Pb dating of zircon samples using laser ablation-inductively coupled plasma mass spectrometry (ICPMS) coupled with galvanometric optics. With the galvanometric optics, laser ablation of two or more sample materials could be achieved in very short time intervals (~10 ms). The resulting sample aerosols released from different ablation pits or different solid samples were mixed and homogenized within the sample cell and then transported into the ICP ion source. Multiple spot laser ablation enables spiking of analytes or internal standard elements directly into the solid samples, and therefore the standard addition calibration method can be applied for the determination of trace elements in solid samples. In this study, we have measured the rare earth element (REE) abundances of two zircon samples (Nancy 91500 and Prešovice) based on the standard addition technique, using a direct spiking of analytes through a multispot laser ablation of the glass standard material (NIST SRM612). The resulting REE abundance data show good agreement with previously reported values within analytical uncertainties achieved in this study (10% for most elements). Our experiments demonstrated that nonspectroscopic interferences on 14 REEs could be significantly reduced by the standard addition technique employed here. Another advantage of galvanometric devices is the accumulation of sample aerosol released from multiple spots. In this study we have measured the U-Pb age of a zircon sample (LMR) using an accumulation of sample aerosols released from 10 separate ablation pits of low diameters (~8 μm). The resulting (238)U-(206)Pb age data for the LMR zircons was 369 ± 64 Ma, which is in good agreement with previously reported age data (367.6 ± 1.5 Ma). (1) The data obtained here clearly demonstrate that the multiple spot laser ablation-ICPMS technique can become a powerful approach for elemental and isotopic

  12. Age and origin of post collision Baltoro granites, south Karakoram, North Pakistan: Insights from in-situ U-Pb, Hf and oxygen isotopic record of zircons

    Science.gov (United States)

    Mahar, Munazzam Ali; Mahéo, Gweltaz; Goodell, Philip C.; Pavlis, Terry L.

    2014-09-01

    Origin of post collision plutonism is critical to understand the tectonothermal evolution of the over thickened continental crust in collision zones. This has proven difficult to reconcile with the conventional whole rock geochemical and field based studies alone. We report in-situ study of zircon U-Pb, Hf and O isotopes from five samples of the Baltoro Plutonic Unit (BPU) in south Karakoram. The plutonic unit is the western part of the southern Asian margin of the India-Asia convergent zone. Baltoro granites and a biotite-rich enclave yielded similar and overlapping U-Pb ages ranging from 26 to 15 Ma. Hafnium isotopic composition (εHf (0)) is very heterogeneous ranging from - 17.1 to + 4.4 while the oxygen isotopic composition of the granites is homogeneous with mean δ18O ranging from 7.2 to 9.4‰. Based on U-Pb geochronology and Hf-O isotopic composition, the involvement of two main sources is suggested (1) Cretaceous calc-alkaline Karakoram crust and (2) Karakoram gneisses. Moreover, possible involvement of metasomatized Asian lithospheric mantle is supported by elevated oxygen composition of granites and identical Hf composition of biotite-rich enclave to the mantle derived Baltoro lamprophyre. However, direct contribution from juvenile pristine mantle is unlikely as no juvenile mantle type Hf and oxygen values were obtained. This also precludes the involvement of southward juvenile arc related component of Kohistan-Ladakh batholith. Our new U-Pb and Hf data are comparable to the Mesozoic Karakoram batholith, Miocene two-mica leucogranites in the Pangong Range and magmatism from the Lhasa terrane in south Tibet, suggesting a genetic link between the Karakoram and the rocks to the east. This magmatic event is best explained by lower crust partial melting promoted by both thermal equilibration following crustal thickening and heat advection by ultrapotassic magmas associated with the breakoff of the Indian continental margin.

  13. Coupling thermodynamic modeling and high-resolution in situ LA-ICP-MS monazite geochronology: evidence for Barrovian metamorphism late in the Grenvillian history of southeastern Ontario

    Science.gov (United States)

    McCarron, Travis; Gaidies, Fred; McFarlane, Christopher R. M.; Easton, R. Michael; Jones, Peter

    2014-12-01

    The Flinton Group is a greenschist to upper amphibolite facies package of metasediments in southeastern Ontario that was metamorphosed during the Ottawan Orogeny. Thermodynamic modeling of metapelitic mineral assemblages suggests an increase in peak conditions of metamorphism across the 40 km wide study area from 3.5 to 7.9 kbar and 540 to 715 °C. Garnet isopleth thermobarometry applied to the cores of compositionally zoned porphyroblasts reveals remarkably similar P-T conditions of initial crystallization at approximately 3.7-4.0 kbar and 512-520 °C, corresponding to a relatively high geothermal gradient of ca. 34-45 °C km-1. It is inferred from modeling and reaction textures that metamorphism was along Barrovian P-T paths. Major and trace element zoning in garnet from one sample records a complex growth history as evidenced by major and trace element zoning and the distribution of xenotime, allanite and monazite inclusions. High-resolution (6 μm) LA-ICP-MS U-Pb geochronology performed on monazite in the rock matrix and included in the outer 150 μm of garnet rim-ward of a Y annulus revealed an age of 976 ± 4 Ma. The age is interpreted to reflect monazite growth at the expense of allanite and apatite late in garnet's growth history over the P-T interval 4.5-6.8 kbar and 540-640 °C. This new age estimate for near peak metamorphism fits well into the regional framework but is significantly younger than previously reported ages for Ottawan metamorphism. Based on microstructures this new age suggests that compressional tectonics were operating much later in the history of the Grenville of southeastern Ontario than previously thought.

  14. Geochemistry and zircon U-Pb ages of granulite xenolith from Tuoyun basalts, Xinjiang: Implications for the petrogenesis and the lower crustal nature beneath the southwestern Tianshan

    Institute of Scientific and Technical Information of China (English)

    ZHENG Jianping; LUO Zhaohua; YU Chunmei; YU Xiaolu; ZHANG Ruisheng; LU Fengxiang; LI Huimin

    2005-01-01

    The granulitic xenoliths discovered in the late Cretaceous basaltic rocks from Tuoyun basin, western Xinjiang Province contain the assemblage of Opx + Cpx + Pl ± Grt ± Qtz ± Kfs. Mineral chemistry, petrochemistry and zircon U-Pb ages from the xenoliths have been reported in the paper. Petrogenesis, the lower crustal nature and the mantle-crust interaction reflected by the granulites are discussed as well. Tuoyun granulites are mainly mafic with few intermediate components, and represent the magmatic products underwent granulite-facies metamorphism in lower crustal condition. Equilibrium temperature and the maximum pressure estimates of the granulites are 910 ± 35℃ and 13.5 × 108 Pa respectively, indicating that the crust beneath southwestern Tianshan had the thickness of less than 44 km and high geotherm (e.g. > 80 mW/m2) when the host magma erupted. During their formation, the fractional crystallization of olivine, pyroxene, plagioclase and ilmenite, plagioclase accumulation and the contamination of felsic components or fluid metasomatism processes had happened. Metamorphic zircon U-Pb age of 253 Ma may record the crust-mantle interaction caused by the orogenic root delamination beneath the southwestern Tianshan.

  15. Tectonic evolution of the southern margin of the Amazonian craton in the late Mesoproterozoic based on field relationships and zircon U-Pb geochronology

    Directory of Open Access Journals (Sweden)

    GILMAR J. RIZZOTTO

    2014-03-01

    Full Text Available New U-Pb zircon geochronological data integrated with field relationships and an airborne geophysical survey suggest that the Nova Brasilândia and Aguapeí belts are part of the same monocyclic, metaigneous and metasedimentary belt formed in the late Mesoproterozoic (1150 Ma-1110 Ma. This geological history is very similar to the within-plate origin of the Sunsás belt, in eastern Bolivia. Thus, we propose that the Nova Brasilândia, Aguapeí and Sunsás belts represent a unique geotectonic unit (here termed the Western Amazon belt that became amalgamated at the end of the Mesoproterozoic and originated through the reactivation of a paleo-suture (Guaporé suture zone in an intracontinental rift environment. Therefore, its geological history involves a short, complete Wilson cycle of ca. 40 Ma. Globally, this tectonic evolution may be related with the final breakup of the supercontinent Columbia. Mafic rocks and trondhjemites in the northernmost portion of the belt yielded U-Pb zircon ages ca. 1110 Ma, which dates the high-grade metamorphism and the closure of the rift. This indicates that the breakup of supercontinent Columbia was followed in short sequence by the assembly of supercontinent Rodinia at ca. 1.1-1.0 Ga and that the Western Amazon belt was formed during the accretion of the Arequipa-Antofalla basement to the Amazonian craton.

  16. U-Pb zircon SHRIMP data from the Cana Brava layered complex: new constraints for the mafic-ultramafic intrusions of Northern Goiás, Brazil

    Science.gov (United States)

    Giovanardi, T.; Girardi, V. A. V.; Correia, C. T.; Sinigoi, S.; Tassinari, C. C. G.; Mazzucchelli, M.

    2015-08-01

    The Cana Brava Complex is the northernmost and least well known layered intrusion of a discontinuous belt of mafic-ultramafic massifs within the Brasilia Belt, which also comprises theNiquelândia and Barro Alto complexes. Available geochronological data from a range of techniques (K/Ar, Ar/Ar, Rb/Sr, Sm/Nd and U/Pb) provide a range of possible ages (time span from 3.9 Ga to 450 Ma), hence a precise and reliable age for the Cana Brava Complex is still lacking. Also, preliminary isotopic and geochemical data of the Cana Brava Complex suggest a significant crustal contamination, which could have affected bulk-rock Sr and Nd systematics resulting in meaningless age determinations. In this paper, we present new U-Pb SHRIMP zircon analyses from four samples of different units of the Cana Brava Complexwhich suggest that the intrusion occurred during the Neoproterozoic, between 800 and 780 Ma, i.e. at the same age ofNiquelândia. Discordant older 206Pb/238U ages are provided by inherited zircons, and match the age of the metamorphism of the embedding Palmeirópolis Sequence.

  17. SIMS U-Pb zircon age of a tuff layer in the Meishucun section, Yunnan, southwest China: Constraint on the age of the Precambrian-Cambrian boundary

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Determination of the age of the Precambrian-Cambrian boundary is critical in understanding early evolution of life on Earth. SIMS U-Pb zircon analyses of the Bed 5 tuff layer of the Meishucun section were carried out closely following the guidance of cathodoluminescence images, and the majority of analyses were conducted on the oscillatory zircon grains. Thirteen measurements yield a highly reliable Concordia U-Pb age of 536.7 ± 3.9 Ma for the Bed 5 horizon. A grand mean of 206Pb/238U age of 535.2± 1.7 Ma (MSWD = 0.53) is calculated based on 13 concordant SIMS measurements of this study and 4 nano-SIMS measurements of Sawaki et al., which is the best estimate of the deposition age of the tuff layer within Bed 5 in the Meishucun section. This age has provided a robust age constraint on the significant Precambrian-Cambrian boundary strata in southern China, which independently suggested the placement of the Precambrian-Cambrian boundary at the bottom of the Xiaowaitoushan Member (Marker A).

  18. U-Pb zircon geochronology and Sr-Nd isotopic composition of the Inchope orthogneiss in Mozambique: Age constraints and petrogenetic implications

    Science.gov (United States)

    Manjate, Vicente Albino

    2017-07-01

    The Inchope orthogneiss comprises a mesoproterozoic group of variously deformed and migmatised orthogneisses in the Chimoio group. This area is well known for its numerous, small pegmatite deposits with cassiterite and columbite. Zircon U-Pb geochronological and whole rock Sr-Nd isotope data are reported for five Inchope orthogneiss samples. The zircon U-Pb data exhibit one period of crystallization between 1065 and 1053 Ma and two metamorphic ages of 956 Ma and 484 Ma. The Inchope orthogneiss displays evolved Nd isotopic compositions with ɛNdi between -11.7 and -13.3, 87Sr/86Sri between 0.7117 and 0.7209 and TDM values of between 2.3 and 2.4 Ga. Therefore, the Inchope orthogneiss crystallized in Mesoproterozoic from the paleoproterozoic metapelites along the eastern margin of the archaen Zimbabwean craton. This was followed by pegmatite veins intrusions and Pan-African tectonometamorphic reworking. These features are typical of S-type and calc-alkaline granites in continental margin arcs.

  19. U-Pb zircon geochronology of rocks in the Salinas Valley region of California: A reevaluation of the crustal structure and origin of the Salinian block

    Science.gov (United States)

    Barth, A.P.; Wooden, J.L.; Grove, M.; Jacobson, C.E.; Pedrick, J.N.

    2003-01-01

    The Salinian block in the Salinas Valley region of central California consists of arc granitic and metasedimentary rocks (schist of Sierra de Salinas) sandwiched between coeval high-pressure, low-temperature me??lange belts. U-Pb zircon ages of three granitic plutons from this region range from 88 to 82 Ma, and coexisting biotite yielded 40Ar/39Ar cooling ages of 76-75 Ma. The U-Pb ages from detrital zircons indicate derivation of the protolith of the schist from a 117-81 Ma igneous provenance. Muscovite and biotite 40Ar/ 39Ar cooling ages of 72-68 Ma from the nearby schist are distinctly younger than those from the granitic plutons. These data indicate that deposition and metamorphism of the schist occurred after emplacement of adjacent granitic rocks, contradicting the prevailing view that the schist comprises the local framework for the Salinian arc. We propose that the schist of Sierra de Salinas was thrust beneath the Salinian magmatic arc along a Campanian thrust fault that has not been recognized. This hypothesis implies that the Salinian arc originated as a klippe of basement rocks derived from the vicinity of the western Mojave Desert. Thrusting initiated southeastward-migrating Laramide tectonism of a style similar to that which formed the Vincent thrust and the latest Cretaceous and Paleocene Pelona and Orocopia Schists of southern California and southwestern Arizona.

  20. U-Pb isotopic ages and Hf isotope composition of zircons in Variscan gabbros from central Spain: evidence of variable crustal contamination

    Science.gov (United States)

    Villaseca, Carlos; Orejana, David; Belousova, Elena; Armstrong, Richard A.; Pérez-Soba, Cecilia; Jeffries, Teresa E.

    2011-03-01

    Ion microprobe U-Pb analyses of zircons from three gabbroic intrusions from the Spanish Central System (SCS) (Talavera, La Solanilla and Navahermosa) yield Variscan ages (300 to 305 Ma) in agreement with recent studies. Only two zircon crystals from La Solanilla massif gave slightly discordant Paleoproterozoic ages (1,848 and 2,010 Ma). Hf isotope data show a relatively large variation with the juvenile end-members showing ɛHfi values as high as +3.6 to +6.9 and +1.5 to +2.9 in the Navahermosa and Talavera gabbros, respectively. These positive ɛHfi values up to +6.9 might represent the composition of the subcontinental mantle which generates these SCS gabbros. This ɛHfi range is clearly below depleted mantle values suggesting the involvement of enriched mantle components on the origin of these Variscan gabbros, and is consistent with previous whole-rock studies. The presence of zircons with negative ɛHfi values suggest variable, but significant, crustal contamination of the gabbros, mainly by mixing with coeval granite magmas. Inherited Paleoproterozoic zircons of La Solanilla gabbros have similar trace element composition (e.g. Th/U ratios), but more evolved Hf-isotope signatures than associated Variscan zircons. Similar inherited ages have been recorded in zircons from coeval Variscan granitoids from the Central Iberian Zone. Granitic rocks have Nd model ages (TDM) predominantly in the range of 1.4 to 1.6 Ga, suggesting a juvenile addition during the Proterozoic. However, Hf crustal model ages of xenocrystic Proterozoic zircons in La Solanilla gabbro indicate the presence of reworked Archean protoliths (TDM2 model ages of 3.0 to 3.2 Ga) incorporated into the hybridized mafic magma.

  1. SHRIMP single zircon U-Pb dating of the Kongling high-grade metamorphic terrain: Evidence for >3.2 Ga old continental crust in the Yangtze craton

    Institute of Scientific and Technical Information of China (English)

    GAO; Shan; (

    2001-01-01

    [1]Liu, G. L., New progress in the geochronology of the Kongling terrain, Regional Geology of China, 1987, 1: 95.[2]Zheng, W. Z., Liu, G. L., Wang, X. W., Geochronology of the Archean Kongling terrain, Bull. Yichang Inst. Geol. Miner. Resour. (in Chinese), 1991, 16: 97-105.[3]Yuan, H. H., Zhang, Z. L., Liu, W. et al., Dating of zircons by evaporation method and its application, Mineral. Petrol. (in Chinese), 1991, 11: 72.-79[4]Ling, W. L., Gao, S., Zheng, H. F. et al., Sm-Nd isotopic dating of Kongling terrain, Chinese. Sci. Bull., 1998, 43(1): 86-89.[5]Gao, S., Ling, W. L., Qiu, Y. et al., Contrasting geochemical and Sm-Nd isotopic compositions of Archean metasediments from the Kongling high-grade terrain of the Yangtze craton: evidence for cratonic evolution and redistribution of REE during crustal anatexis, Geochim. Cosmochim. Acta, 1999, 63: 2071-2088.[6]Gao, S., Zhang, B. R., The discovery of Archean TTG gneisses in northern Yangtze craton and their implications, Earth Sci. (in Chinese, with English abstract), 1990, 15: 675-679.[7]Dong, S. B., Metamorphism and Its Relation to the Crustal Evolution in China (in Chinese), Beijing: Geological Publishing House, 1986. [8]Composton, W., Williams, I. S., Meyer, C., U-Pb geochronology of zircons from lunar breccia 73217 using sensitive high mass-resolution ion microprobe, J. Geophys. Res., 1984, 89(B): 252-534.[9]Williams, I. S., Composton, W., Black, L. P et al., Unsupported radiogenic Pb in zircon: a case of anomalously high Pb-Pb, U-Pb and Th-Pb ages, Contrib. Mineral. Petrol., 1984, 88: 322-327.[10] Nelson, D. R., Evolution of the Archean granite-greenstone terrains of the Eastern Goldfileds, Western Australia: SHRIMP U-Pb zircon constraints, Precambrian Res., 1997, 83: 57-81.[11] Ling, W. L., Geochronology and crustal growth of the Paleoproterozoic basements along the northern margin of the Yangzte craton, Earth Sci., 1996, 21(5): 491—493.

  2. Zircon U-Pb Geochronology, Hf Isotopic Composition and Geological Implications of the Neoproterozoic Huashan Group in the Jingshan Area, Northern Yangtze Block, China

    Science.gov (United States)

    Yang, Z.; Yang, K.

    2015-12-01

    In the northern Yangtze Block, a clear angular unconformity between the Mesoproterozoic sequences (e.g. Dagushi Group) and the overlying Neoproterozoic strata (e.g. Huashan Group) marks the the Jinning orogeny. A combined study of Lu-Hf isotopes and U-Pb ages for detrital zircons from Huashan Group can provide information on the crustal evolution of sedimentary provenances and the timing of the Jinning orogeny. Detrital zircons from Huashan Group have two major U-Pb age populations of about 2.0Ga, 2.65Ga, and three subordinate age groups of about 0.82Ga, 2.5Ga, 2.9Ga with minor >3.0Ga ages. The youngest five analyses yield a weighted average age of 816±9Ma, which is consistent with that of interlayered basalt (824±9Ma, Deng et al., 2013) and roughly defines the minimum depositional age of Huashan Group. Detrital zircons of Huashan Group mostly have two stage Hf isotope model ages (TDM2) between 3.0 to 3.3Ga, indicating that the northern Yangtze Block experienced significant continental crustal growth during the Paleo- to Meso-archean. Similar U-Pb ages of detrital zircons have been obtained from Precambrian sedimentary rocks in the northern Yangtze Block from previous studies (Liu et al., 2008; Guo et al., 2014 and references therein). Recently, ca. 2.65Ga A-type granites had been reported from the Kongling and Huji area, which likely record the thermally stable lithosphere (Chen et al., 2013; Zhou et al., 2015). In combination with this study, it documents the widespread 2.6-2.7Ga magmatic rocks in the northern Yangtze Block. Zhao et al. (2013) demonstrated both the ca. 850Ma tonalite and trondhjemite of the Huangling igneous complex were formed in a continental arc setting. This suggests the Miaowan-Huashan oceanic basin proposed by Bader et al. (2013) has not been closed at ca. 850Ma. This evidence, together with the depositional age of the Huashan Group, indicates the Jinning orogeny took place at 850-820 Ma. [1] Bader et al., 2013 Tectonics [2] Deng et al

  3. Zircon SHRIMP U-Pb ages of the "Xinghuadukou Group" in Hanjiayuanzi and Xinlin areas and the "Zhalantun Group" in Inner Mongolia, Da Hinggan Mountains

    Institute of Scientific and Technical Information of China (English)

    MIAO LaiCheng; LIU DunYi; ZHANG FuQin; FAN WeiMing; SHI YuRuo; XIE HangQiang

    2007-01-01

    A report is presented of SHRIMP zircon U-Pb dating data of meta-igneous and meta-sedimentary rocks of the Xinghuadukou Group (Xinlin-Hanjiayuanzi area, Heilongjiang Province) and meta-volcanic rocks of the Zhalantun Group (Zhalantun district, Inner Mongolia). The SHRIMP analyses show that the meta-igneous rocks from the Xinghuadukou Group formed at 506±10-547±46 Ma, belonging to Early-Middle Precambrian, whereas the meta-sedimentary rocks yielded detrital zircons, with ages of 1.0-1.2, 1.6-1.8 and 2.5-2.6 Ga, indicative of deposition age at least <1.0 Ga.Meta-basic volcanic rocks from the Zhalantun Group have a formation age of 506±3 Ma. These data suggest that both the Xinghuadukou and Zhalantun Groups formed during Cambrian and/or Neoproterozoic time, rather than Paleoproterozoic time as previously thought. Early Precambrian inherited zircons in the meta-igneous rocks and numerous Precambrian detrital zircons in the meta-sedimentary rocks imply that these rocks were formed proximal to older crust. It is inferred that the Xinghuadukou and Zhalantun Groups represent Cambrian and/or Neoproterozoic volcano-sedimentary sequences formed in an active continental margin setting.

  4. Zircon U-Pb Ages from an Ultra-High Temperature Metapelite, Rauer Group, East Antarctica: Implications for Overprints by Grenvillian and Pan-African Events

    Science.gov (United States)

    Wang, Yanbin; Tong, Laixi; Liu, Dunyi

    2007-01-01

    SHRIMP U-Pb dating of zircon from an ultra-high temperature (UHT, ~1000 °C) granulite-facies metapelite from the Rauer Group, Mather Peninsula, east Antarctica, has yielded evidence for two episodes of metamorphic zircon growth, at ~1.00 Ga and ~530 Ma, and two episodes of magmatism in the source region for the protolith sediment, at ~2.53 and ~2.65 Ga, were identified from the zircon cores. Successive zircon growth at ~1.00 Ga and ~530 Ma records a sequence of distinct, widely spaced high-temperature metamorphic and/or anatectic events related to Grenvillian and Pan-African orogenesis. This study presents the first robust geochronological evidence for the timing of UHT metamorphism of the Rauer Group, supporting arguments that the peak UHT metamorphic event occurred at ~1.00 Ga and was overprinted by a separate high-grade event at ~530 Ma. The new age data indicate that the UHT granulites of the Rauer Group experienced a complex, multi-stage tectonothermal history, which cannot simply be explained via a single Pan-African (~500 Ma) high-grade tectonic event. This is critical in understanding the role of the eastern Prydz Bay region during the assembly of the east Gondwana supercontinent, and the newly recognized inherited Archaean ages (~2.53 and ~2.65 Ga) suggest a close tectonic relationship between the Rauer Group and the adjacent Archaean of the Vestfold Hills

  5. Developing a Methodology to Connect the Siberian Flood Basalts and the Permian-Triassic Extinction Through LA-ICP-MS

    Science.gov (United States)

    Baransky, E.; Rodriguez, S.; Rampino, M. R.

    2016-12-01

    The Siberian flood basalts have been implicated as a major contributor to the End-Permian extinction (252 Mya), the largest mass extinction known to date. Their relation is still unclear and more information about Meishan, China, the Global Stratotype Section and Point for the Upper Permian stage, is needed to better understand their link. Due to the slow sedimentation rate, 0.36 - 0.17 cm/ka, of this time and region, a centimeter by centimeter sampling using a Laser Ablation Inductively Coupled Plasma Mass Spectrometer (LA-ICP-MS) will attain a comprehensive, detailed elemental analysis. In this study, we established a method for preparation of powdered Meishan, China samples to use with the LA-ICP-MS. Powdered samples remove cost prohibitive thin section sample preparation, create homogenous samples and provide a process which can be mimicked for standard calibration preparation. We performed more than 80 trials to develop sample preparation procedures of beds 24 - 28 and polyvinyl alcohol 8-88 (PVA) standards for analyses of the Meishan samples. Pellet preparation varied in mass, amount of PVA solution, drying time and pressure. For comparison, limestone sample, like Bed 24, requires 10 μL of 5% PVA solution and can be immediately pressed, while clay enriched sample, like Bed 25, requires no solution and is dried at 40 ° before being compacted with a pre-dried hydraulic press. The differing ideal procedures indicate that sample preparation should be developed on a sample-by-sample basis, but these methods can be used for future studies with similar sample composition. This procedure will be used for our continuing research with the LA-ICP-MS which will more accurately analyze for a broad scope of elements. We will focus on Os, Re, Ir, and Hg to search for further evidence of the relationship between flood-basalt volcanism and extinctions.

  6. Better U-Pb Zircon Standards for SIMS and LA-ICPMS? Preliminary Results of Detailed Characterization and Pre-treatment using CA-TIMS

    Science.gov (United States)

    Mattinson, J. M.; Hourigan, J.; Wooden, J. L.

    2006-12-01

    U-Pb zircon dating using SIMS and LA-ICPMS requires calibrations against natural zircons of known age. Ideally, such zircons should be perfectly concordant -- free from Pb-loss, inheritance, or any other complications, and also accurately dated. In practice this can be problematic. Complexities can be difficult to detect by SIMS and LA-ICPMS analysis if they are at or below the level of precision of an individual analysis. In addition, conventional TIMS dating, used to date the standards, can be limited by residual minor Pb loss that has not been removed by conventional "pretreatments" such as air abrasion. CA-TIMS (Mattinson, 2005, Chem Geol 220, 47-66) utilizes high-T annealing of natural radiation damage, followed by partial dissolution in HF, and has proven highly successful at complete removal of zircon domains that have experienced Pb loss, both from the outer rims and also from the deep interiors of zircon grains. Thus, it is useful for detailed characterization of existing and potential zircon standards. Here, we also investigate the potential of CA-TIMS for pre-treating zircon standards prior to SIMS and LA-ICPMS analysis. Multi-step CA-TIMS analyses of Temora-2, R-33, and a possible new standard from the Klamath Mountains reveal minor Pb loss in the first few partial dissolution steps, then yield excellent 206Pb*/238 plateau ages, and concordant 207Pb*/206Pb* ages for the remaining steps. Additional aliquots of these zircons were then "pretreated" by CA-TIMS, with sufficient partial dissolution to remove all vestiges of Pb loss, based on the earlier experiments. A sample of AS-57 was pre-treated "blind" because it was received just prior to a scheduled SHRIMP session. All samples were then prepared in a single mount for SHRIMP analysis. Our preliminary results from a round-robin Stanford SHRIMP-RG session using Temora-2, R-33, AS-57, and the Klamath sample are very promising. The Temora-2 and Klamath zircons in particular yielded excellent reproducibility

  7. U-Pb ases and Hf isotopes for detrital zircons from quartzite in the Paleoproterozoic Songshan Group on the southwestern margin of the North China Craton

    Institute of Scientific and Technical Information of China (English)

    DIWU ChunRong; SUN Yong; YUAN HongLin; WANG HongLiang; ZHONG XingPing; LIU XiaoMing

    2008-01-01

    In situ U-Pb dating and Lu-Hf isotopic analysis were carried out for detrital zircons from quartzite in the Paleoproterozoic Songshan Group on the southern margin of the North China Craton (NCC). The re-sults provide further constraints on the crustal formation and evolution history of NCC. Four 207Pb/206Pb age populations were obtained from 99 analyses, with clusters at ~3.40 Ga, 2.77-2.80 Ga, ~2.50 Ga and 2.34 Ga, respectively. The 3.40 Ga old zircons have similar Hf isotopic compositions to those from Ar-chean rocks in the Jidong and Anshan areas of NCC. However, crustal remnants older than 3.6 Ga have been identified in the southern margin of NCC, the South China Craton, the northwestern part of the Qinling Orogen and its adjacent area. Thus, it is not easy to trace the source rock from which the 3.40 Ga detrital zircons were derived. It can be inferred that the crustal remnants older than 3.40 Ga might have been widely distributed in the North China Craton. The 2.77-2.80 Ga zircons make up a relatively small proportion and have the highest ε (t) values (up to 6.1±1.6), consistent with the Hf isotopic composition of the depleted mantle at 2.83 Ga. Their single-stage Hf model age of 2.83 Ga is close to their crystallized age, suggesting that their source rocks were extracted from the contemporaneous depleted mantle. The ~2.50 Ga zircon grains constitute about 85% of the total grain population and their Hf isotopic compositions indicate major growth of juvenile crust at ~2.50 Ga but minor reworking of ancient crust. The youngest zircon dated in this study gave an U-Pb age of 2337±23 Ma, which can be considered the maximum depositional age of the formation of the Songshan Group.

  8. Orogenesis and Basin Development: U-Pb Detrital Zircon Age Constraints on Evolution of the Late Paleozoic St. Marys Basin, Central Mainland Nova Scotia.

    Science.gov (United States)

    Murphy; Hamilton

    2000-01-01

    The St. Marys Basin, along the southern flank of the composite Late Paleozoic Magdalen Basin in the Canadian Appalachians and along the Avalon-Meguma terrane boundary, contains Late Devonian-Early Carboniferous continental clastic rocks of the Horton Group that were deposited in fluvial and lacustrine environments after the peak of the Acadian orogeny. SHRIMP II (Geological Survey of Canada) data on approximately 100 detrital zircons from three samples of Horton Group rocks from the St. Marys Basin show that most of the zircons have been involved in a multistage history, recycled from clastic rocks in the adjacent Meguma and Avalonian terranes. Although there is a minor contribution from Early Silurian (411 Ma) and Late Devonian suites (ca. 380-370 Ma), Neoproterozoic (ca. 700-550 Ma) and Paleoproterozoic (ca. 2.0-2.2 Ga) zircon populations predominate, with a minor contribution from ca. 1.0-, 1.2-, and 1.8-Ga zircons. Published U-Pb single-zircon analyses on clastic sedimentary rocks indicate that the Meguma and Avalon terranes have different populations of detrital zircons, sourced from discrete portions (Amazonian and West African cratons) of the ancient Gondwanan margin. Both terranes contain Neoproterozoic and Late Archean populations. The SHRIMP data, in conjunction with published sedimentological and geochemical data, indicate that the Horton Group basin-fill sediments are largely the result of rapid uplift and erosion of Meguma terrane metasedimentary and granitoid rocks immediately to the south of the St. Marys Basin during the waning stages of the Acadian orogeny. Regional syntheses indicate that this uplift occurred before and during deposition and was a consequence of dextral ramping of the Meguma terrane over the Avalon terrane along the southern flank of the Magdalen Basin.

  9. 华北板块北缘东段二叠纪的构造属性:来自火山岩锆石U-Pb年代学与地球化学的制约%Permian tectonic evolution of the eastern section of the northern margin of the North China Plate: Constraints from zircon U-Pb geochronology and geochemistry of the volcanic rocks

    Institute of Scientific and Technical Information of China (English)

    曹花花; 许文良; 裴福萍; 郭鹏远; 王枫

    2012-01-01

    本文对华北板块北缘东段大河深组、关门咀子组火山岩进行了锆石LA-ICP-MS U-Pb定年和岩石地球化学研究以便制约该区的区域构造演化.大河深组和关门咀子组火山岩中的锆石均呈自形-半自形晶,具有清晰的岩浆振荡生长环带和条痕状吸收(玄武安山岩)的特点,其Th/U比值高达0.31 ~1.56,表明其岩浆成因.测年结果表明,桦甸大河深组流纹岩形成于早二叠世( 279±3Ma ~ 293±2Ma),珲春和图们关门咀子组玄武安山岩和玄武岩分别形成于早二叠世(275±7Ma)和晚二叠世(250 ±5Ma).大河深组火山岩SiO2含量介于64.9% ~ 75.4%,Mg#值介于0.21 ~0.57,属于中钾-高钾钙碱性系列,明显富集轻稀土元素(LREEs)和大离子亲石元素(LILEs)、亏损高场强元素(HFSEs,如Nb、Ta、Ti)以及P元素,类似活动大陆边缘火山岩;其锆石的εHf(t)值为+0.9 ~+ 10.37,Hf同位素二阶段模式年龄值为785 ~1240Ma,表明它们均起源于中-新元古代新增生玄武质下地壳的部分熔融.珲春早二叠世关门咀子组属于中钾钙碱性系列;贫硅(53.4% ~53.7%)和HFSEs,富铝(16.4% ~ 16.8%)和LILEs,具有较低的稀土元素总量,以及较平坦的稀土配分型式,显示出岛弧火山岩的地球化学属性;该组火山岩的原始岩浆应起源于受俯冲板片脱水熔融交代的亏损地幔楔.图们晚二叠世关门咀子组玄武岩SiO2含量为48.7%~49.6%,Mg#值高达0.64~0.72,相对富集LREEs和LILEs,亏损HREEs和HFSEs,具有火山弧玄武岩的地球化学属性,同时其εNd(t)=+6.01,暗示其原始岩浆起源于亏损的岩石圈地幔.综上所述,我们认为早二叠世至晚二叠世期间,华北板块北缘东段(吉林中部地区)和兴凯地块西南缘均处于古亚洲洋的俯冲作用下.%LA-ICP-MS zircon U-Pb dating and geochemical data have been obtained for the volcanic rocks from the Daheshen and Guanmenzuizi formations in the middle

  10. Tracing long term tectonic evolution of accretionary orogens by U-Pb zircon geochronology: Proterozoic to Jurassic tectonics of the Santander Massif, northern Colombia

    Science.gov (United States)

    Valencia, V. A.; Cardona, A.; Gehrels, G. E.; Ruiz, J.; Ibañez, M.

    2009-12-01

    Accurate orogenic models are nedded to reconstruct complex tectonic histories of long lived convergent margins. Integrated zircon U-Pb geochronology on igneous, sedimentary and metasedimentry rocks within single crustal domains is a powerful tool, as it can be used to trace the timing of rock forming events, magmatic style and episodity, and identify crustal recycling. U-Pb detrital zircon and magmatic geochronology was carried on multiple litostratigraphic units of the Santander Massif in the northeastern Andes, in order to reconstruct its long term Late Proterozoic to Early Mesozoic tectonic evolution. Major zircon forming events includ well defined Grenvillian, Late Neoproterozoic to Ordovician, Silurian, Early Permian and Jurassic events. Major peaks of activity at ca. 197 Ma, 440-410 Ma and 470-490 Ma and 950-1052 Ma, support the existence of continental scale tectonic cycles. Older Mesoproterozoic (1.3-1.5 Ga) crustal input in metasediments and magmatic rocks link these units to crustal recycling on the margins of the Amazon Craton, whereas the older 950-1052 Ma peak indicates the link of this crustal segment with other Andean Grenvillian remnant. Previous interpretations of the Paleozoic Silgara Formation seem incorrect, as acquired dates from this study includ different metamorphic units, deposited and formed after the Silurian and Permian during final stages of Pangea's assemblage, probably as Laurentia migrated to its final Alleghanian position. Finally the presence of the NW South America Jurassic arc is also present in the region by granitoid ages. The limited input of this arc signature within the contemporaneous and overlapping Early Cretaceous sedimentary rocks suggest that this arc was developed in a back arc setting.

  11. Characterization and zircon SHRIMP U-Pb geochronology of the subvolcanic rocks from Yarumalito Porphyry System, Marmato District, Colombia; Caracterizacao e geocronologia SHRIMP U-Pb em zircao das rochas subvulcanicas do sistema porfiro Yarumalito, Distrito de Marmato, Colombia

    Energy Technology Data Exchange (ETDEWEB)

    Henrichs, Isadora A.; Frantz, Jose Carlos; Marques, Juliana C.; Castoldi, Marco S., E-mail: isahenrichs@gmail.com, E-mail: jose.frantz@ufrgs.br, E-mail: juliana.marques@ufrgs.br [Universidade Federal do Rio Grande do Sul (UFRS), Porto Alegre, RS (Brazil). Instituto de Geociencias; Ordonez-Carmona, Oswaldo, E-mail: oswaldo.geologo@gmail.com [Universidad Nacional de Colombia, Medellin (Colombia). Facultad de Minas; Sato, Kei, E-mail: keisato@usp.br [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Centro de Pesquisas Geocronologicas

    2014-09-15

    The mining District of Marmato, located in the Central Cordillera, is considered one of the oldest gold districts in Colombia and its exploration dates back to the Inca’s times, being exploited regularly for more than a thousand years. Inserted in this context lies the Yarumalito porphyry system (YPS), characterized to concentrate ore in structure related veins and stockworks. The YPS is related to the Miocene magmatism of the Combia Formation. In this paper, the subvolcanic rocks directly associated with the mineralized zones were described in order to obtain U-Pb ages in zircon to the intrusions. Selected samples from two fertile intrusions, one andesitic (more abundant in the area) and other dioritic (more restricted), were carefully described and dated by SHRIMP. The results points to a very restricted interval for the ages, with weighted average {sup 206}Pb/{sup 238}U varying from 7,00 ± 0,15 Ma for the andesitic porphyry and 6.95 ± 0.16 Ma for the dioritic porphyry. These results constrain the Yarumalito system to the final stages of the Combia magmatism and suggest a brief period for the crystallization of the mineralized subvolcanic rocks in the area and in the Marmato District. (author)

  12. Methodology for determination of trace elements in mineral phases of iron banded formation by LA-ICP-MS; Metodologia de determinacao de elementos-traco em fases minerais de formacoes ferriferas bandadas por LA-ICP-MS

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, Denise V.M. de; Nalini Junior, Herminio A.; Sampaio, Geraldo M.S.; Abreu, Adriana T. de; Lana, Cristiano de C., E-mail: deniseversiane2@yahoo.com.br, E-mail: nalini@degeo.ufop.br, E-mail: geraldomssampaio@gmail.com, E-mail: adrianatropia@gmail.com, E-mail: cristianodeclana@gmail.com [Universidade Federal de Ouro Preto (DEGEO/UFOP), Ouro Preto, MG (Brazil). Departamento de Geologia

    2015-07-01

    The study of the chemical composition of mineral phases of iron formation (FF), especially of trace elements, is an important tool in the understanding of the genesis of these rocks and the contribution of the phases in the composition of whole rock. Low mass fraction of such elements in the mineral phases present in this rock type requires a suitable analytical procedure. The laser ablation technique coupled with ICP-MS (LA-ICP-MS) has been widely used for determination of trace elements in geological samples. Thus, the aim of this study is to develop calibration curves for determination of trace elements (Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) in mineral phases of banded iron formations by LA-ICP-MS. Several certified reference materials (CRM) were used for calibrate the equipment. The analytical conditions were checked by CRM NIST SRM 614. The results were satisfactory, since the curves showed good linearity coefficients, good accuracy and precision of results. (author)

  13. Jurassic cooling ages in Paleozoic to early Mesozoic granitoids of northeastern Patagonia: 40Ar/39Ar, 40K-40Ar mica and U-Pb zircon evidence

    Science.gov (United States)

    Martínez Dopico, Carmen I.; Tohver, Eric; López de Luchi, Mónica G.; Wemmer, Klaus; Rapalini, Augusto E.; Cawood, Peter A.

    2016-12-01

    U-Pb SHRIMP zircon crystallization ages and Ar-Ar and K-Ar mica cooling ages for basement rocks of the Yaminué and Nahuel Niyeu areas in northeastern Patagonia are presented. Granitoids that cover the time span from Ordovician to Early Triassic constitute the main outcrops of the western sector of the Yaminué block. The southern Yaminué Metaigneous Complex comprises highly deformed Ordovician and Permian granitoids crosscut by undeformed leucogranite dikes (U-Pb SHRIMP zircon age of 254 ± 2 Ma). Mica separates from highly deformed granitoids from the southern sector yielded an Ar-Ar muscovite age of 182 ± 3 Ma and a K-Ar biotite age of 186 ± 2 Ma. Moderately to highly deformed Permian to Early Triassic granitoids made up the northern Yaminué Complex. The Late Permian to Early Triassic (U-Pb SHRIMP zircon age of 252 ± 6 Ma) Cabeza de Vaca Granite of the Yaminué block yielded Jurassic mica K-Ar cooling ages (198 ± 2, 191 ± 1, and 190 ± 2 Ma). At the boundary between the Yaminué and Nahuel Niyeu blocks, K-Ar muscovite ages of 188 ± 3 and 193 ± 5 Ma were calculated for the Flores Granite, whereas the Early Permian Navarrete granodiorite, located in the Nahuel Niyeu block, yielded a K-Ar biotite age of 274 ± 4 Ma. The Jurassic thermal history is not regionally uniform. In the supracrustal exposures of the Nahuel Niyeu block, the Early Permian granitoids of its western sector as well as other Permian plutons and Ordovician leucogranites located further east show no evidence of cooling age reset since mica ages suggest cooling in the wake of crystallization of these intrusive rocks. In contrast, deeper crustal levels are inferred for Permian-Early Triassic granitoids in the Yaminué block since cooling ages for these rocks are of Jurassic age (198-182 Ma). Jurassic resetting is contemporaneous with the massive Lower Jurassic Flores Granite, and the Marifil and Chon Aike volcanic provinces. This intraplate deformational pulse that affected northeastern

  14. U-Pb SHRIMP zircon dating of high-grade rocks from the Upper Allochthonous Terrane of Bragança and Morais Massifs (NE Portugal); geodynamic consequences

    Science.gov (United States)

    Mateus, A.; Munhá, J.; Ribeiro, A.; Tassinari, C. C. G.; Sato, K.; Pereira, E.; Santos, J. F.

    2016-04-01

    Bragança and Morais Massifs are part of the mega-klippen ensemble of NW Iberia, comprising a tectonic pile of four allochthonous units stacked above the Central-Iberian Zone autochthon. On top of this pile, the Upper Allochthonous Terrane (UAT) includes different high-grade metamorphic series whose age and geodynamic meaning are controversial. Mafic granulites provided U-Pb zircon ages at 399 ± 7 Ma, dating the Variscan emplacement of UAT. In contrast, U-Pb zircon ages of ky- and hb-eclogites, felsic/intermediate HP/HT-granulites and orthogneisses (ca. 500-480 Ma) are identical to those of gabbros (488 ± 10 Ma) and Grt-pyroxenites (495 ± 8 Ma) belonging to a mafic/ultramafic igneous suite that records upper mantle melting and mafic magma crustal underplating at these times. Gabbros intrude the high-grade units of UAT and did not underwent the HP metamorphic event experienced by eclogites and granulites. These features and the zircon dates resemblance among different lithologies, suggest that extensive age resetting of older events may have been correlative with the igneous suite emplacement/crystallisation. Accordingly, reconciliation of structural, petrological and geochronological evidence implies that the development and early deformation of UAT high-grade rocks should be ascribed to an orogenic cycle prior to ≈ 500 Ma. Undisputable dating of this cycle is impossible, but the sporadic vestiges of Cadomian ages cannot be disregarded. The ca. 500-480 Ma time-window harmonises well with the Lower Palaeozoic continental rifting that trace the Variscan Wilson Cycle onset and the Rheic Ocean opening. Subsequent preservation of the high heat-flow regime, possibly related to the Palaeotethys back-arc basin development (ca. 450-420 Ma), would explain the 461 ± 10 Ma age yielded by some zircon domains in felsic granulites, conceivably reflecting zircon dissolution/recrystallisation till Ordovician times, long before the Variscan paroxysm (ca. 400-390 Ma). This

  15. U-Pb LA-SF-ICP-MS zircon geochronology of the Serbo-Macedonian Massif, Greece: palaeotectonic constraints for Gondwana-derived terranes in the Eastern Mediterranean

    Science.gov (United States)

    Meinhold, Guido; Kostopoulos, Dimitrios; Frei, Dirk; Himmerkus, Felix; Reischmann, Thomas

    2010-06-01

    The Pirgadikia Terrane in northern Greece forms tectonic inliers within the Vardar suture zone bordering the Serbo-Macedonian Massif to the southwest. It comprises Cadomian basement rocks of volcanic-arc origin and very mature quartz-rich metasedimentary rocks. U-Pb laser ablation sector-field inductively-coupled plasma mass spectrometry analyses of detrital zircons from the latter reveal a marked input from a Cadomian-Pan-African source with minor contribution from Mesoproterozoic, Palaeoproterozoic and Archaean sources. The metasedimentary rocks are correlated with Ordovician overlap sequences at the northern margin of Gondwana on the basis of their maturity and zircon age spectra. The Pirgadikia Terrane can be best interpreted as a peri-Gondwana terrane of Avalonian origin, which was situated close to the Cadomian terranes in the Late Neoproterozoic-Early Palaeozoic, very much like the Istanbul Terrane. The second unit investigated is the Vertiskos Terrane, which constitutes the major part of the Serbo-Macedonian Massif in Greece. It comprises predominantly igneous rocks of Silurian age and minor metasedimentary rocks of unknown age and provenance. U-Pb analyses of detrital zircons from a garnetiferous mica schist of the Vertiskos Terrane indicate derivation from 550 to 1,150 Ma-old source rocks with a major Cadomian peak. This, combined with minor input of >1,950 Ma-old zircons and the absence of ages between ca. 1.2 and 1.7 Ga suggests a NW Africa source. The protolith age of the garnetiferous mica schist is presumably Early Ordovician. One sample of garnet-bearing biotite gneiss, interpreted as meta-igneous rock, comprises predominantly subhedral zircons of igneous origin with late Middle Ordovician to Silurian ages. We suggest that the rock association of the Vertiskos Terrane is part of an ancient active-margin succession of the Hun superterrane, comparable to successions of the Austro- and Intra-Alpine Terranes. The new data of this study provide evidence

  16. U-Pb ages and Hf isotope compositions of zircons in plutonic rocks from the central Famatinian arc, Argentina

    Science.gov (United States)

    Otamendi, Juan E.; Ducea, Mihai N.; Cristofolini, Eber A.; Tibaldi, Alina M.; Camilletti, Giuliano C.; Bergantz, George W.

    2017-07-01

    The Famatinian arc formed around the South Iapetus rim during the Ordovician, when oceanic lithosphere subducted beneath the West Gondwana margin. We present combined in situ U-Th-Pb and Lu-Hf isotope analyses for zircon to gain insights into the origin and evolution of Famatinian magmatism. Zircon crystals sampled from four intermediate and silicic plutonic rocks confirm previous observations showing that voluminous magmatism took place during a relatively short pulse between the Early and Middle Ordovician (472-465 Ma). The entire zircon population for the four plutonic rocks yields coherent εHf negative values and spreads over several ranges of initial εHf(t) units (-0.3 to -8.0). The range of εHf units in detrital zircons of Famatinian metasedimentary rocks reflects a prolonged history of the cratonic sources during the Proterozoic to the earliest Phanerozoic. Typical tonalites and granodiorites that contain zircons with evolved Hf isotopic compositions formed upon incorporating (meta)sedimentary materials into calc-alkaline metaluminous magmas. The evolved Hf isotope ratios of zircons in the subduction related plutonic rocks strongly reflect the Hf isotopic character of the metasedimentary contaminant, even though the linked differentiation and growth of the Famatinian arc crust was driven by ascending and evolving mantle magmas. Geochronology and Hf isotope systematics in plutonic zircons allow us understanding the petrogenesis of igneous series and the provenance of magma sources. However, these data could be inadequate for computing model ages and supporting models of crustal evolution.

  17. Mesozoic Bimodal Volcanic Suite in Zhalantun of the Da Hinggan Range and Its Geological Significance:Zircon U-Pb Age and Hf Isotopic Constraints

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Mesozoic bimodal volcanic rocks of basaltic andesite and rhyolite are widely distributed in the Da Hinggan Range, but their petrogenetic relationships and geodynamic implications are rarely constrained. Detailed studies on doleritic and porphyry dikes in the Zhalantun area indicate that they display features of magma mixing, suggesting their coeval formation. In situ zircon U-Pb dating shows that the porphyry was emplaced in the Early Cretaceous with a 206Pb/238U age of 130±1 Ma. Zircons from the dolerite also yield an Early Cretaceous emplacement age of 124±2 Ma although some inherited zircons have been identified. These age results indicate that the Early Cretaceous was an important period of magmatism in the Da Hinggan Range. Zircons from porphyry are characterized by positive value of εHf(t) as high as 10.3±0.5 with Hf depleted mantle model age of 349-568 Ma, whereas magmatic zircons from the dolerite have εHf(t) value of 11.0±1.4 with Hf depleted mantel model age of 342-657 Ma,consistent with those from the porphyry. Considering other data on the geological evolution of this area,it is concluded that the mafic magma originated from the partial melting of Paleozoic enriched lithospheric mantle, whereas the felsic magma came from recycling of juvenile crust formed during the Paleozoic. Both of the protoliths are closely related to the subduction of the Paleo-Asian Ocean during the Paleozoic, indicating that the Paleozoic is an important period of large-scale crustal growth in the area.

  18. Using zircon U-Pb ages to constrain the provenance and transport of heavy minerals within the northwestern shelf of the South China Sea

    Science.gov (United States)

    Zhong, Lifeng; Li, Gang; Yan, Wen; Xia, Bin; Feng, Yuexing; Miao, Li; Zhao, Jianxin

    2017-02-01

    Numerous ore-grade heavy mineral placer deposits occur in the northern South China Sea region. Previous studies on these deposits have focused on the heavy-mineral ore resources themselves, but the provenance and transport pathways of these heavy minerals are poorly constrained. This paper presents U-Pb ages of detrital zircons from sediments within the northwestern shelf of the South China Sea, and uses this new dataset to determine the provenance and transport pathway of the sediments. Zircons in sediments from ten areas of the northwestern shelf exhibit distinct age populations, suggesting that they have multiple provenances. Zircons in sediments from the Pearl River Mouth, Shangchuan Island, and Moyang River Mouth areas all have an obvious peak of Mesozoic ages, indicating that they have similar sediment provenances; i.e., mainly from the Pearl River, and to a lesser degree from the Moyang River. Zircons in sediments from the areas around the Jian River Mouth and Leizhou Bay, and off Hainan Island have an early Paleozoic age, suggesting that the sediments predominantly originate from the Yunkai massif. Zircons of the sediments from the remaining four areas, the Leiqiong Strait, Wanquan River Mouth, Qiongdongnan, and the Outer Shelf, have Yanshannian and Indosinian age peaks in addition to an obvious early Paleozoic population, implying mixed provenances, including the Yunkai massif and Hainan Island. The sediment transport may have involved two hydrodynamic conditions in two distinct stages. First, the Guangdong Longshore Current carried the river sediments to where they dispersed in the inner shelf; subsequently, wave-induced strong currents further transported sandy sediments southeastward to the outer shelf. In addition to explaining the provenance and transport pathways of heavy minerals within the northwestern shelf of the South China Sea, these results provide new information relevant to exploration for heavy-mineral placer deposits.

  19. Zircon U-Pb age and Hf isotope of Quanyishang A-type granite in Yichang: Signification for the Yangtze continental cratonization in Paleoproterozoic

    Institute of Scientific and Technical Information of China (English)

    XIONG Qing; ZHENG JianPing; YU ChunMei; SU YuPing; TANG HuaYun; ZHANG ZhiHai

    2009-01-01

    Zircon U-Pb age and Hf isotope, and major and trace element compositions were reported for granite at Quanyishang, which intruded into the Kongling complex in Yichang, Hubei Province. The results show that the Quanyishang granite is rich in silicon and alkalis but poor in calcium and magnesium, and displays enrichment in Ga, Y, Zr, Nb but depletion in Sr and Ba, exhibiting the post-orogenic A-type affinity. 90% zircons from the granite are concordant, and give a middle Paleoproterozoic magmatic crystallization age (mean 1854 Ma). Initial Hf isotope ratios (176Hf/177Hf)1 of the middle Paleoproterozoic zircons range from 0.280863 to 0.281134 and they have negative εHf(t) values with a minimum of -26.3. These zircons give the depleted mantle model ages (TDM) of 2.9-3.3 Ga (mean 3.0 Ga), and the average crustal model ages (Tcrust) of 3.6-4.2 Ga (mean 3.8 Ga)., A Mesoarchean grain with 207pb/206Pb age of 2859 Ma has a slightly high TDM (3.4 Ga) but similar Tcrust (3.8 Ga) to the Paleoproterozoic zircons. All these data suggest that the source materials of the Quanyishang A-type granite are unusually old, at least ≥2.9 Ga (even Eoarchean). The event of crustal remelting, which resulted in the formation of the Quanyishang granite in the middle Paleoproterozoic, recorded the cratonization of the Yangtze conti-nent. The process may have relation to the extension and collapse of the deep crust with Archean ages, in response to the transition stage of the assembly and breakup of the Columbia supercontinent.

  20. Age of the Lava Creek supereruption and magma chamber assembly at Yellowstone based on 40Ar/39Ar and U-Pb dating of sanidine and zircon crystals

    Science.gov (United States)

    Matthews, Naomi E.; Vazquez, Jorge A.; Calvert, Andrew T.

    2015-01-01

    The last supereruption from the Yellowstone Plateau formed Yellowstone caldera and ejected the >1000 km3 of rhyolite that composes the Lava Creek Tuff. Tephra from the Lava Creek eruption is a key Quaternary chronostratigraphic marker, in particular for dating the deposition of mid Pleistocene glacial and pluvial deposits in western North America. To resolve the timing of eruption and crystallization history for the Lava Creek magma, we performed (1) 40Ar/39Ar dating of single sanidine crystals to delimit eruption age and (2) ion microprobe U-Pb and trace-element analyses of the crystal faces and interiors of single zircons to date the interval of zircon crystallization and characterize magmatic evolution. Sanidines from the two informal members composing Lava Creek Tuff yield a preferred 40Ar/39Ar isochron date of 631.3 ± 4.3 ka. Crystal faces on zircons from both members yield a weighted mean 206Pb/238U date of 626.5 ± 5.8 ka, and have trace element concentrations that vary with the eruptive stratigraphy. Zircon interiors yield a mean 206Pb/238U date of 659.8 ± 5.5 ka, and reveal reverse and/or oscillatory zoning of trace element concentrations, with many crystals containing high U concentration cores that likely grew from highly evolved melt. The occurrence of distal Lava Creek tephra in stratigraphic sequences marking the Marine Isotope Stage 16–15 transition supports the apparent eruption age of ∼631 ka. The combined results reveal that Lava Creek zircons record episodic heating, renewed crystallization, and an overall up-temperature evolution for Yellowstone's subvolcanic reservoir in the 103−104 year interval before eruption.

  1. Bioimaging of metals in brain tissue by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and metallomics.

    Science.gov (United States)

    Becker, J Sabine; Matusch, Andreas; Palm, Christoph; Salber, Dagmar; Morton, Kathryn A; Becker, J Susanne

    2010-02-01

    Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has been developed and established as an emerging technique in the generation of quantitative images of metal distributions in thin tissue sections of brain samples (such as human, rat and mouse brain), with applications in research related to neurodegenerative disorders. A new analytical protocol is described which includes sample preparation by cryo-cutting of thin tissue sections and matrix-matched laboratory standards, mass spectrometric measurements, data acquisition, and quantitative analysis. Specific examples of the bioimaging of metal distributions in normal rodent brains are provided. Differences to the normal were assessed in a Parkinson's disease and a stroke brain model. Furthermore, changes during normal aging were studied. Powerful analytical techniques are also required for the determination and characterization of metal-containing proteins within a large pool of proteins, e.g., after denaturing or non-denaturing electrophoretic separation of proteins in one-dimensional and two-dimensional gels. LA-ICP-MS can be employed to detect metalloproteins in protein bands or spots separated after gel electrophoresis. MALDI-MS can then be used to identify specific metal-containing proteins in these bands or spots. The combination of these techniques is described in the second section.

  2. SHRIMP zircon U-Pb dating for volcanic rocks of the Dasi Formation in southeast Hubei Province, middle-lower reaches of the Yangtze River and its implications

    Institute of Scientific and Technical Information of China (English)

    XIE Guiqing; MAO Jingwen; LI Ruiling; ZHOU Shaodong; YE Huishou; YAN Quanren; ZHANG Zusong

    2006-01-01

    The Jinniu Basin in southeast Hubei,located at the westernmost part of middle-lower valley of the Yangtze River, is one of the important volcanic basins in East China. Volcanic rocks in the Jinniu Basin are distributed mainly in the Majiashan Formation, the Lingxiang Formation and the Dasi Formation, consisting of rhyolite, basalt and basaltic andesite, (trachy)-basalt and basaltic trachy-andesite and (trachy)-andesite and (trachy)-dacite and rhyolite respectively, in which the Dasi volcanism is volumetrically dominant and widespread. The Dasi volcanic rocks were selected for SHRIMP zircon U-Pb dating to confirm the timing of volcanism. The results indicate that there exist a large amount of magmatic zircons characterized by high U and Th contents in the volcanic rocks. The concordia ages for 13 points are 128±1Ma (MSWD = 3.0). On account of the shape of zircons and Th/U ratios, this age is considered to represent the crystallization time of the Dasi volcanism. The volcanic rocks in the Dasi, Majiashan and Lingxiang Formations share similar trace element and REE partition patterns as well as Sr-Nd isotopic compositions. In combination with the regional geology, it is proposed that the southeast Hubei volcanic rocks were formed mainly during the Early Cretaceous, just like other volcanic basins in middle-lower Yangtze valley. A lithospheric extension is also suggested for tectonic regime in this region in the Cretaceous Period.

  3. Magmatism as a response to exhumation of the Priest River complex, northern Idaho: Constraints from zircon U-Pb geochronology and Hf isotopes

    Science.gov (United States)

    Stevens, L. M.; Baldwin, J. A.; Crowley, J. L.; Fisher, C. M.; Vervoort, J. D.

    2016-10-01

    Zircon and monazite U-Pb geochronology and zircon Hf isotopes place constraints on the temporal and source relationships between crustal anatexis, magmatism, and exhumation of the Priest River metamorphic core complex, northern Idaho. Granitoids that intruded the migmatitic, pelitic Hauser Lake gneiss include the pluton emplacement in the Priest River complex indicates that it was primarily a response to decompression rather than a cause. The mylonitized Silver Point and undeformed Wrencoe plutons bracket the end of a rapid phase of exhumation to c. 50-48 Ma. Zircon εHf(i) values and Lu-Hf isotope evolution indicate that the Silver Point and Wrencoe plutons crystallized from homogeneous magmas sourced from Archean-Proterozoic basement orthogneisses, whereas the Spokane granite and two leucocratic units appear to have been produced by partial melting of the Hauser Lake gneiss. Comparison of the Priest River complex with other deeply exhumed northern Cordilleran complexes indicates variability in the timing and, therefore, relative influences of partial melting and magmatism on the initiation of exhumation, which must be accounted for in numerical models of metamorphic core complex formation and evolution.

  4. High-pressure granulite from Western Kunlun,northwestern China:Its metamorphic evolution,zircon SHRIMP U-Pb ages and tectonic implication

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    High-pressure mafic granulites occurring as lenticular bodies within garnet-amphibolites in Kangxiwar Fault have been first reported in this paper. The P-T conditions of two metamorphic stages were ob-tained using calibrated geothermal barometers and ThermoCalc Program. The peak metamorphic con-dition of these high-pressure granulites is about 760―820℃,1.0―1.2 GPa and the retrograde meta-morphic condition is about 620―720℃,0.7―0.8 GPa. The petrological studies show that they have a near-isobaric cooling P-T path which suggests that the Western Kunlun underwent initial crustal thickening,subsequent exhumation and cooling. The SHRIMP zircon U-Pb dating gives two groups of ages for high-pressure granulites. One is 177±6 Ma which is obtained from the rim of the zircon. We consider this age should be the metamorphic age. And the other is 456±30 Ma which is obtained from the core of the zircon and should be the protolith age. The formation of these high-pressure granulites in western Kunlun is closely correlated with the evolution of the Paleo-Tethys and has important im-plications for the research on Tethys and Paleo-Asian tectonic zone.

  5. High-pressure granulite from Western Kunlun, northwestern China: Its metamorphic evolution, zircon SHRIMP U-Pb ages and tectonic implication

    Institute of Scientific and Technical Information of China (English)

    QU JunFeng; ZHANG LiFei; AI YongLiang; L(U) Zeng; WANG JianPing; ZHOU Hui; WANG ShiYan

    2007-01-01

    High-pressure mafic granulites occurring as lenticular bodies within garnet-amphibolites in Kangxiwar Fault have been first reported in this paper. The P-T conditions of two metamorphic stages were obtained using calibrated geothermal barometers and ThermoCalc Program. The peak metamorphic condition of these high-pressure granulites is about 760-820℃, 1.0-1.2 GPa and the retrograde metamorphic condition is about 620-720℃, 0.7-0.8 GPa. The petrological studies show that they have a near-isobaric cooling P-T path which suggests that the Western Kunlun underwent initial crustal thickening, subsequent exhumation and cooling. The SHRIMP zircon U-Pb dating gives two groups of ages for high-pressure granulites. One is 177±6 Ma which is obtained from the rim of the zircon. We consider this age should be the metamorphic age. And the other is 456±30 Ma which is obtained from the core of the zircon and should be the protolith age. The formation of these high-pressure granulites in western Kunlun is closely correlated with the evolution of the Paleo-Tethys and has important implications for the research on Tethys and Paleo-Asian tectonic zone.

  6. U-Pb SHRIMP Dating of Zircon from Quartz Veins of the Yangshan Gold Deposit in Gansu Province and Its Geological Significance

    Institute of Scientific and Technical Information of China (English)

    QI Jinzhong; YUAN Shisong; LIU Zhijie; LIU Dunyi; WANG Yanbin; LI Zhihong; GUO Junhua; SUN Bin3

    2004-01-01

    The Yangshan gold deposit is a super-large fine-grained disseminated gold deposit located in southern Gansu Province. Its metallogenic age has been determined by using the cathodoluminescence image and ion probe U-Pb dating techniques. It is found that zircons from quartz veinlet of the fine-grained disseminated gold ore show characters of magmatic origin with prism idiomorphism, oscillatory zoning and dominant Th/U ratios of 0.5-1.5. Three main populations of zircons are obtained, giving average 206pb/238U ages of 197.6±1.7 Ma, 126.9±3.2 Ma and 51.2±l.3 Ma respectively. The first age corresponds to the K-Ar age of the plagiogranite dike, while the latter two ages indicate that buried Cretaceous and Tertiary intrusives exist in the orefield, suggesting that the Yangshan gold deposit was genetically related to the three magmatic hydrothermal activities. By contrast, zircons from coarse gold-bearing quartz vein in the mining area are much older than the host rock, indicating that the vein was formed earlier and was not contaminated by later magmatic fluids. It is concluded that the coupling of multiperiodic hydrothermal activities in the mining area has contributed a lot to mineralization of the Yangshan gold deposit.

  7. LA-ICPMS zircon U-Pb geochronological constraints on the tectonothermal evolution of the Early Paleoproterozoic Dakendaban Group in the Quanji Block, NW China

    Institute of Scientific and Technical Information of China (English)

    WANG QinYan; CHEN NengSong; LI XiaoYan; HAO Shuang; CHEN HaiHong

    2008-01-01

    The Ouanji Block, situated between the northern margin of the Oaidam Block and the South Qilian orogenic belt in the NE Qinghai-Tibet Plateau, China, is thought to represent a remnant continental crust. In this study, LA-ICPMS U-Pb analyses of detrital zircon grains from two mesosomes in the migmatitic Dakendaban Group yield ages of 2467+281-26 Ma and 2474+66/-52 Ms, respectively. Zircon grains from a leucosome give two distinct ages of 2471+18/-16 Ma and 1924+14/-15 Ms. Zircon from a granitic pegmatite that intruded into the Dakendaban Group yields an age of 2427+44/-38 Ms. These data suggest that the Early Paleoproterozoic Dakendaban Group deposited between ~2.43 to ~2.47 Ga and has been subject to an intrusive event at 2.43 Ga, and regional metamorphism-anatexis at 1.92 Ga. The common lower intercept age of ~0.9 Ga probably records a significant Early Neoproterozoic event in the Quanji Block.

  8. U-Pb (SHRIMP-II) isotope dating of zircons from alkali rocks of Vitim province, West Transbaikalia

    Science.gov (United States)

    Doroshkevich, A. G.; Ripp, G. S.; Sergeev, S. A.

    2012-03-01

    A U-Pb (SHRIMP-II) geochronological study of rocks from the Sayzhenski, Snezhny and Nizhne-Burulzayski massifs, incorporated into the Vitim alkali province (Sayzhenski Complex) has been made. The acquired data indicate that the rocks formed in the interval of 520-486 Ma. The proximity of their age to accretionary-collision processes in the Central Asian fold belt, accompanied by intràplate magmatism, has been noted. Two independent stages in the evolution of Vitim Province magmatism are suggested: Early Paleozoic (520-485 Ma) and Late Paleozoic (350-290 Ma).

  9. The onset of flood basalt volcanism, Northern Paraná Basin, Brazil: A precise U-Pb baddeleyite/zircon age for a Chapecó-type dacite

    Science.gov (United States)

    Janasi, Valdecir de Assis; de Freitas, Vivian Azor; Heaman, Larry H.

    2011-02-01

    We report the first U-Pb baddeleyite/zircon date for a felsic volcanic rock from the Paraná Large Igneous Province in south Brazil. The new date of 134.3 ± 0.8 Ma for a hypocrystalline Chapecó-type dacite from Ourinhos (northern Paraná basin) is an important regional time marker for the onset of flood basalt volcanism in the northern and western portion of the province. The dated dacite was erupted onto basement rocks and is overlain by a high-Ti basalt sequence, interpreted to be correlative with Pitanga basalts elsewhere. This new U-Pb date for the Ourinhos dacite is consistent with the local stratigraphy being slightly older than the few reliable step-heating 40Ar/39Ar dates currently available for overlying high-Ti basalts (133.6-131.5 Ma). This indicates an ~ 3 Ma time span for the building of the voluminous high-Ti lava sequence of the Paraná basin. On the other hand, it overlaps the 40Ar/39Ar dates (134.8-134.1 Ma) available for the stratigraphically older low-Ti basalt (Gramado + Esmeralda types) and dacite-rhyolite (Palmas type) sequences from South Brazil, which is consistent with the short-lived character of this volcanism and its rapid succession by the high-Ti sequence.

  10. SHRIMP U-Pb dating of detrital zircons in paragneiss from Oki-Dogo Island, western Japan

    National Research Council Canada - National Science Library

    TSUTSUMI, Yukiyasu; YOKOYAMA, Kazumi; HORIE, Kenji; TERADA, Kentaro; HIDAKA, Hiroshi

    2006-01-01

    We obtained the radiometric ages of detrital zircons from two samples of paragneiss from Oki-Dogo Island, Japan, from the 238U/206Pb ratio and isotopic composition of Pb determined using a Sensitive...

  11. SHRIMP U-Pb dating of detrital zircons in paragneiss from Oki-Dogo Island, western Japan

    National Research Council Canada - National Science Library

    TSUTSUMI, Yukiyasu; YOKOYAMA, Kazumi; HORIE, Kenji; TERADA, Kentaro; HIDAKA, Hiroshi

    2006-01-01

      We obtained the radiometric ages of detrital zircons from two samples of paragneiss from Oki-Dogo Island, Japan, from the 238U/206Pb ratio and isotopic composition of Pb determined using a Sensitive...

  12. U-Pb dating on zircons for the la Borie eclogite (Haut-Allier, France) and consequences for the pre-Variscan evolution of the Western Europe

    Energy Technology Data Exchange (ETDEWEB)

    Ducrot, J.; Lancelot, J.R. (Montpellier-2 Univ., 44 (France). Lab. de Geochimie-Isotopique); Marchand, J. (Nantes Univ., 34 (France). Lab. de Petrologie et Minerologie)

    1983-03-01

    A crystallization age of 432sub(-10)/sup +20/Ma has been determined for the 'La Borie' eclogite (Haut-Allier, France), by U-Pb dating on zircons. This age is yielded by the upper intercept with the Concordia curve. In agreement with recent dates obtained in the southern part of the Massif Central, in Brittany and in Vendee, these data indicate that the high-pressure/high-temperature-metamorphic phase representative of the pre-Variscan evolution of the western Europe, took place at the Silurian/Ordovician boundary. This high-pressure/high-temperature metamorphism could be significant of subduction processes more or less synchronous, preceeding the main continental collision responsible of the Variscan belt.

  13. New U-Pb SHRIMP zircon ages for pre-variscan orthogneisses from Portugal and their bearing on the evolution of the Ossa-Morena tectonic zone

    Directory of Open Access Journals (Sweden)

    Cordani Umberto G.

    2006-01-01

    Full Text Available New SHRIMP U-Pb zircon ages for the Portalegre and Alcáçovas orthogneisses document a complex pre- Variscan history for the Iberian basement in Portugal. The available geochemical and geochronological data for the Alcáçovas orthogneiss (ca. 540 Ma tend to favor its involvement in a Cadomian orogenic event. This is consistent with the development of an active continental margin setting at the end of the Proterozoic and supports a Gondwanan provenance for the Iberian crust. On the other hand, the Ordovician emplacement age obtained for the magmatic precursors of the Portalegre orthogneisses (497?10 Ma provides additional evidence for the occurrence of rift-related magmatic activity during the Lower Paleozoic.

  14. New U-Pb SHRIMP zircon ages for pre-variscan orthogneisses from Portugal and their bearing on the evolution of the Ossa-Morena tectonic zone.

    Science.gov (United States)

    Cordani, Umberto G; Nutman, Allen P; Andrade, Antonio S; Santos, José F; Azevedo, Maria do Rosário; Mendes, Maria Helena; Pinto, Manuel S

    2006-03-01

    New SHRIMP U-Pb zircon ages for the Portalegre and Alcáçovas orthogneisses document a complex pre- Variscan history for the Iberian basement in Portugal. The available geochemical and geochronological data for the Alcáçovas orthogneiss (ca. 540 Ma) tend to favor its involvement in a Cadomian orogenic event. This is consistent with the development of an active continental margin setting at the end of the Proterozoic and supports a Gondwanan provenance for the Iberian crust. On the other hand, the Ordovician emplacement age obtained for the magmatic precursors of the Portalegre orthogneisses (497 +/- 10 Ma) provides additional evidence for the occurrence of rift-related magmatic activity during the Lower Paleozoic.

  15. Zircon SHRIMP U-Pb dating of meta-diorite from the basement of the Songliao Basin and its geological significance

    Institute of Scientific and Technical Information of China (English)

    WANG Ying; ZHANG Fuqin; ZHANG Dawei; MIAO Laicheng; LI Tiesheng; XIE Hangqiang; MENG Qingren; LIU Dunyi

    2006-01-01

    The basement of the Songliao Basin mainly contains low-grade metamorphic rocks and granites. It has been long disputed whether the basin has Precambrian metamorphic basement. This is a report of zircon SHRIMP U-Pb dating results of a meta-diorite sample, which was taken from the Si-5 drilling hole in the southern portion of the Songliao Basin. The SHRIMP analyses indicate that the meta-diorite with a weighted mean 207Pb/206Pb age of 1839±7 Ma (2σ, n = 8) was emplaced during Paleo-Proterozoic time. Additionally, the meta-diorite has old Nd model ages (TDM1:2999Ma; TDM2:2849Ma). These data suggest that the southern part of the Songliao Basin do possess Precambrian basement.

  16. Geochemistry and SHRIMP Zircon U-Pb Age of Post-Collisional Granites in the Southwest Tianshan Orogenic Belt of China: Examples from the Heiyingshan and Laohutai Plutons

    Institute of Scientific and Technical Information of China (English)

    LONG Lingli; GAO Jun; WANG Jingbin; QIAN Qing; XIONG Xianming; WANG Yuwang; WANG Lijuan; GAO Liming

    2008-01-01

    The Heiyingshan granite and the Laohutai granite plutons exposed in the Southwest Tianshan resemble A-type granites geochemically. Analysis shows that the both are ferron calc-alkalic peraluminous or ferron aikali-calcic peraluminous with a relatively high concentration of SiO2 (>70%), high alkali contents (Na2O + K2O = 7.14%-8.56%; K2O>N2O; A/CNK = 0.99-1.20), and pronounced negative anomales in Eu, Ba, Sr, P and Ti. A SHRIMP zircon U-Pb age of 285±4 Ma was obtained for the Heiyingshan hornblende biotite granite intrusion. The geochemical and age dating data reported in this paper indicate that these granites were formed during the post-collisional crustal extension of the Southwest Tianshan orogenic belt, in agreement with the published data for the granites in the South Tianshan.

  17. SHRIMP U-Pb Zircon Dating of the Tula Granite Pluton on the South Side of the Altun Fault and Its Geological Implications

    Institute of Scientific and Technical Information of China (English)

    WU Suoping; WU Cailai; WANG Meiying; CHEN Qilong; Joseph L. WOODEN

    2008-01-01

    The Tula A2-subtype granite pluton is located between the Altun fault and its branching fault.According to the geological, geochemical, REE and trace elements characteristics, it belongs to the A2 (PA) subtype granite. The SHRIMP U-Pb zircon dating gives a result of 385.2+8.1 Ma, which is located between the Middle and Late Devonian in the international stratigraphic chart, and can be regarded as the crystallization age of the Tula granite. The study indicates that the Tula area was in a local extensional environment in the end of the Middle Devonian, and that environment was probably related to the synchronized strike-slip activity of the Altun fault.

  18. Stages of late Paleozoic to early Mesozoic magmatism in the Song Ma belt, NW Vietnam: evidence from zircon U-Pb geochronology and Hf isotope composition

    Science.gov (United States)

    Hieu, Pham Trung; Li, Shuang-Qing; Yu, Yang; Thanh, Ngo Xuan; Dung, Le Tien; Tu, Vu Le; Siebel, Wolfgang; Chen, Fukun

    2016-05-01

    The Song Ma zone in NW Vietnam bears important tectonic implications as a potential subduction corridor between the Indochina and South China blocks. On the basis of U-Pb ages, the Hf isotopic characteristics of zircons and the geochemical composition of granitoids, a two-stage magmatic evolution process of the Song Ma zone at ~290-260 and ~245-230 Ma can be proposed. Isotopic analyses indicate magmatic contributions from Neoproterozoic oceanic island basalt, Proterozoic continental crust, and depleted mantle or juvenile lithosphere. By combining geochronological and geochemical data from the granitoid rocks, we suggest that the staged magmatic processes of Song Ma zone may be related to a long-lasting period of ocean subduction (ca. 290-260 Ma) and subsequent syn-/post-collisional evolution (ca. 245-230 Ma).

  19. U-Pb dating of zircon from the bed parallel anatectic granitic intrusion in the Baoban group in Hainan Island and the tectonic implication

    Institute of Scientific and Technical Information of China (English)

    DING; Shijiang; HU; Jianmin; SONG; Biao; CHEN; Mulun; XIE

    2005-01-01

    The petrological and geochemical features of the bed parallel granitic intrusion in the Pre-Cambrian Baoban group in Hainan Island attest to the anatexis origin of the granites. U-Pb dating analyses of zircons from the anatectic granite and the biotite two-feldspar gneiss in the Baoban group, using SHRIMP II in the Beijing Ion-probe Center, acquire 206Pb/238U ages of 368±3.5 Ma (of granite, 95% confidence level, MSDW=1.23) and 362.9±6.1 Ma (of gneiss, 95% confidence level, MSDW = 2.04) respectively. The two late Devonian ages indicate consistently a tectonic- thermal event experienced in Hainan Island, and are the first discovered record of the Devonian geological process in the district. This event possibly resulted from the deep thermal-dynamic process when the Gondwana continent began to break up in the Devonian period.

  20. Zircon U-Pb geochronology of the volcanic rocks from Fanchang-Ningwu volcanic basins in the Lower Yangtze region and its geological implications

    Institute of Scientific and Technical Information of China (English)

    YAN Jun; LIU HaiQuan; SONG ChuanZhong; XU XiSheng; AN YaJun; LIU Jia; DAI LiQun

    2009-01-01

    The latest eruptions in two important Mesozoic volcanic basins of Fanchang and Ningwu located in the middle-lower reaches of the Yangtze River formed the bimodal volcanic rocks of the Kedoushan Formation and ultrapotassic volcanic rocks of the Niangniangshan Formation,respectively.The representative volcanic rocks of the two Formations were selected for LA-ICPMS zircon U-Pb dating.The results indicate that there exist a large amount of magmatic zircons as indicated by high Th/U ratios in these volcanic rocks.The weighted mean age of 21 analyses is 130.7±1.1 Ma for the Kedoushan Formation,and that of 20 analyses is 130.6±1.1 Ma for the Niangniangshan Formation.These U-Pb ages are interpreted to represent the formation times of the volcanic rocks.In combination with other known geochronological data for Mesozoic volcanic rocks from the Lower Yangtze region,it is proposed that the latest volcanic activations in the Jinniu,Luzong,Fanchang and Ningwu volcanic basins probably came to end prior to ca.128 Me.There is no significant time interval between the early and later volcanic activities in the Luzong and Ningwu basins,suggesting e short duration of volcanic activities and thus implying the onset of an extensional tectonic setting at about 130 Ma in the Lower Yangtze region.Integrated studies reveal that the Early Cretaceous magmatic activities and their geochronological framework in the Lower Yangtze region are a response to progressively dynamic deep processes that started with the transformation of tectonic setting from compression to extension,followed by delaminating of the lower part of the thickened lithosphere,lithospheric thinning,asthenosphere upwelling,and crust-mantle interaction.

  1. Baddeleyite and zircon U Pb ages from the Kærven area, Kangerlussuaq: Implications for the timing of Paleogene continental breakup in the North Atlantic

    Science.gov (United States)

    Holm, Paul Martin; Heaman, Larry M.; Pedersen, Lise E.

    2006-11-01

    We report U-Pb zircon and baddeleyite age results for two mafic units in the Kangerlussuaq area which are part of the Paleogene East Greenland igneous province; the Kangerlussuaq macrodyke, which represents a feeder to some flood basalts, and the nearby Kærven Gabbro. Baddeleyite from the macrodyke yielded a concordant age of 54.7 ± 0.4 (2 σ) Ma and this is among the most precise age determinations from the province. This age is interpreted to reflect the time of emplacement. The macrodyke belongs to a swarm of dykes emplaced perhaps in a failed arm during continental rifting, and the age predates the completion of continental breakup at the end of emplacement of the Plateau Basalts of the East Greenland eruption sequence. Geochemically the macrodyke is correlated with the Milne Land Formation lavas. The magma experienced slight crustal contamination. Based on the age and geochemistry of the macrodyke, the age of the Skaergaard intrusion and Skrænterne Formation lavas, an age span of 1-2 Ma is confirmed for the extrusion of the entire Plateau Basalts. U-Pb analysis of zircon from the Kærven Gabbro yields an age of 53.0 ± 0.3 (2 σ) Ma. The Kærven Gabbro was intruded after extension had ceased in the area and we suggest that the post plateau basalt magmatism did not take place at a distinct later time, but instead that igneous activity continued for some time at a lower rate. Slightly fractionated HREEs indicate that the Kærven Gabbro magma was extracted at relatively shallow levels in the mantle.

  2. U-Pb zircon geochronology, petrochemical and Sr-Nd isotopic characteristic of Late Neoproterozoic granitoid of the Bornaward Complex (Bardaskan-NE Iran)

    Science.gov (United States)

    Bagherzadeh, R. Monazzami; Karimpour, M. H.; Farmer, G. Lang; Stern, C. R.; Santos, J. F.; Rahimi, B.; Heidarian Shahri, M. R.

    2015-11-01

    The Bornaward Granitoid Complex (BGC) in the Taknar Zone is located in the northeast of Central Iranian Block. The BGC consists of granite, alkaligranite, syenogranite, leucogranite, granophyre, monzogranite, granodiorite, tonalite and diorite that have intruded into the center of Taknar Zone. These intrusive rocks affected by low grade metamorphism. Because of there are no reliable isotope dating data, for the Bornaward Granitoid Complex rocks have been proposed discordant ages (Jurassic, Cretaceous or even younger ages) by many studies. In the present study, new isotopic information based on zircon U-Pb dating has revealed the origin and time of the formation of the BGC. These new results do not confirm previously proposed ages. The results obtained from zircon U-Pb dating of the BGC rocks suggest late-Neoproterozoic (Precambrian) age (540-550 Ma). The Bornaward Granitoid Complex is middle-high metaluminous to lower-middle peraluminous and belongs to tholeiite, calc-alkaline to high-K calc-alkaline rock series with enrichment in LIL (Cs, Rb and Ba, U, K, Zr, Y, Th) and depletion in HIL (Sr and Nb, Ta, Ti) elements. Chondrite-normalized Rare Earth Elements (REE) plots indicate minor enrichment of LREE compared to HREE, and strong negative anomaly of Eu compared to other Rare Earth Elements. Furthermore, initial 87Sr/86Sr and 143Nd/144Nd range from 0.70351 to 0.71689 and 0.511585 to 0.512061, respectively, and initial εNd isotope values for granite, granodiorite and diorite range from -6.73 to 2.52. These all indicate that the BGC has derived from partial melting of distinct basement source regions with very high initial 87Sr/86Sr and undergoing extensive crustal contamination (S-type granite).

  3. Coupled zircon Lu-Hf and U-Pb isotopic analyses of the oldest terrestrial crust, the >4.03 Ga Acasta Gneiss Complex

    Science.gov (United States)

    Bauer, Ann M.; Fisher, Christopher M.; Vervoort, Jeffrey D.; Bowring, Samuel A.

    2017-01-01

    The Acasta Gneiss Complex of the Northwest Territories, Canada, contains some of the earliest terrestrial continental crust and thus provides a critical sample set for characterization of crust-forming processes on the early Earth. Here we report the results of a combined Lu-Hf and U-Pb isotopic study of zircons from predominantly felsic orthogneisses from the Acasta Gneiss Complex that crystallized between ∼4.0 and 2.9 Ga, many of which contain complex zoning and therefore require an analytical treatment suited to distinguish amongst compositionally distinct age and Hf isotopic domains. To ensure the reliability of the analyses and of subsequent geologic interpretations, we employed the laser ablation split-stream (LASS) technique to concurrently measure the Lu-Hf and U-Pb isotopic systems in zircon. Our results confirm prior findings of precursor Hadean crust (>4.0 Ga) in the source of these rocks and the continued involvement of this reservoir until ∼3.6 Ga. We present evidence for the input of relatively more juvenile material at ∼3.6 Ga, which we suggest corresponds to a fundamental change in the source of the magmas. This study extends the lower bound of the published Acasta Hf isotopic record from 3.6 Ga to 2.9 Ga and demonstrates that the ∼3.6 Ga-2.9 Ga interval is largely represented by reworking of relatively juvenile ∼3.6 Ga crust and the diminution of the >4.0 Ga crustal signal. Significantly, there is no evidence that rocks within the Acasta Gneiss Complex were derived from a strongly depleted mantle.

  4. U-Pb zircon geochronology of ''brasiliano'' granitoids from the Serido orogenic belt (Borborema Province, NE Brazil). Ages U-Pb sur zircon de granitoides ''brasilianos'' de la ceinture du Serido (Province Borborema, NE Bresil)

    Energy Technology Data Exchange (ETDEWEB)

    Leterrier, J.; Bertrand, J.M. (Centre National de la Recherche Scientifique (CNRS), 54 - Nancy (France). Centre de Recherches Petrographiques et Geochimiques); Pin, C. (Clermont-Ferrand-2 Univ., 63 - Aubiere (France)); Jardim de Sa, E.

    1994-06-01

    Diorites previously attributed to an early stage of the 'brasiliano' plutonic evolution of the Serido belt yielded U-Pb zircon age of 579 [+-]7 Ma. The age of associated granites is slightly younger although a synchronous emplacement of granites and diorites is suggested by field relationships. Such an age difference may result from difficulties to distinguish 'crystallization age' from 'emplacement age', which is still to be determined precisely. (authors). 16 refs., 3 figs., 1 tab.

  5. Timing and origin of migmatitic gneisses in south Karakoram: Insights from U-Pb, Hf and O isotopic record of zircons

    Science.gov (United States)

    Mahar, Munazzam Ali; Mahéo, Gweltaz; Goodell, Philip C.; Pavlis, Terry L.

    2016-04-01

    The timing and origin of partial melting in collision belts is crucial to understand the thermotectonic evolution and the relationship between HT metamorphism and magmatism in over-thickened crust. In the present study, we used the in-situ isotopic (Hf, O and U-Pb) record of zircons to investigate the timing and origin of migmatitic gneisses exposed in the core of the Dassu dome in south Karakoram. The new U-Pb zircon dating identified the Proterozoic inherited cores (1.8-1.9 Ga and 2.3-2.5 Ga) surrounded by a Neogene overgrowth with ages ranging from ∼6 to ∼20 Ma. These ages imply that the partial melting in the Karakoram Metamorphic Complex lasted from >20 Ma to ∼6 Ma and can be correlated with the Miocene magmatism in the adjacent Baltoro region. Oxygen isotopic data from Proterozoic inherited cores (1.8-1.9 Ga) and Neogene overgrowths are indistinguishable and generally vary from 8‰ to 9.5‰. These values are slightly higher than the most igneous zircons (6.5-8‰, Valley et al., 2005) indicating an igneous precursor with heavy initial O composition that later might have equilibrated with low temperature environment or some involvement of supracrustal material is likely. However, a few low U/Th, relatively old inherited cores (2.3-2.5 Ga) showed mantle-like (δ18O = 5.3 ± 0.6‰, Valley et al., 2005) values of δ18O = 5.5 ± 2.7‰. The present-day weighted mean εHf (0) of the Proterozoic inherited cores ranges from -50 ± 1.0 to -44.3 ± 1.2. In contrast, the Neogene rims are 15-20 ε-units higher than the inherited core with present-day εHf (0) = -30.6 ± 0.9. This implies that the Hf composition of the Neogene overgrowth is not controlled exclusively by the dissolution of the inherited cores and that contamination by external melts is likely. We suggest a contribution from the Neogene, less-evolved magmatism in the Baltoro region (εHf (0) = ∼-4 to -10). The elevated oxygen composition is not consistent with the contribution from pristine

  6. LA-ICPMS U-Pb Ages of Zircon from Metaleucosomes, Olongbuluke Microcontinent,North Qaidam, and Implications on the Response to the Global Rodinia Supercontinent Assembly Event in NW China

    Institute of Scientific and Technical Information of China (English)

    Wang Shuqing; Li Xiaoyan; Chen Nengsong; Wang Xinyu; Wang Qinyan; Liu Xiaoming

    2006-01-01

    U-Pb dating was conducted on different domains of zircons from metamorphosed leucosomes in Delingha (德令哈) complex, the lower basement rocks of the Olongbuluke (欧龙布鲁克) microcontinent, North Qaidam, in order to review its complex tectonothermal history. The zircon core is comprised of highly-modified magmatic zircon relicts, the zircon mantle was produced in response to anatexis of a Late Protoproterozoic thermal event; age and isotopic composition of both the zircon core and the zircon mantle have been seriously disturbed due to the thermal event related with growth of the zircon overgrowth rim. The 207 Pb/206 Pb apparent age of the overgrowth rim was estimated to be ~ 1 030 Ma. This Late Mesoproterozoic thermal event has been interpreted as a response to the global Rodinia supercontinent assembly event in the Olongbuluke microcontinent,Northwest China.

  7. U-Pb geochronology of zircon and monazite from Mesoproterozoic granitic gneisses of the northern Blue Ridge, Virginia and Maryland, USA

    Science.gov (United States)

    Aleinikoff, J.N.; Burton, W.C.; Lyttle, P.T.; Nelson, A.E.; Southworth, C.S.

    2000-01-01

    Mesoproterozoic granitic gneisses comprise most of the basement of the northern Blue Ridge geologic province in Virginia and Maryland. Lithology, structure, and U-Pb geochronology have been used to subdivide the gneisses into three groups. The oldest rocks, Group 1, are layered granitic gneiss (1153 ?? 6 Ma), hornblende monzonite gneiss (1149 ?? 19 Ma), porphyroblastic granite gneiss (1144 ?? 2 Ma), coarse-grained metagranite (about 1140 Ma), and charnockite (>1145 Ma?). These gneisses contain three Proterozoic deformational fabrics. Because of complex U-Pb systematics due to extensive overgrowths on magmatic cores, zircons from hornblende monzonite gneiss were dated using the sensitive high-resolution ion microprobe (SHRIMP), whereas all other ages are based on conventional U-Pb geochronology. Group 2 rocks are leucocratic and biotic varieties of Marshall Metagranite, dated at 1112??3 Ma and 1111 ?? 2 Ma respectively. Group 3 rocks are subdivided into two age groups: (1) garnetiferous metagranite (1077 ?? 4 Ma) and quartz-plagioclase gneiss (1077 ?? 4 Ma); (2) white leucocratic metagranite (1060 ?? 2 Ma), pink leucocratic metagranite (1059 ?? 2), biotite granite gneiss (1055 ?? 4 Ma), and megacrystic metagranite (1055 ?? 2 Ma). Groups 2 and 3 gneisses contain only the two younger Proterozoic deformational fabrics. Ages of monazite, seprated from seven samples, indicate growth during both igneous and metamorphic (thermal) events. However, ages obtained from individual grains may be mixtures of different age components, as suggested by backscatter electron (BSE) imaging of complexly zoned grains. Analyses of unzoned monazite (imaged by BSE and thought to contain only one age component) from porphyroblastic granite gneiss yield ages of 1070, 1060, and 1050 Ma. The range of ages of monazite (not reset to a uniform date) indicates that the Grenville granulite event at about 1035 Ma did not exceed about 750??C. Lack of evidence for 1110 Ma growth of monazite in

  8. Biomonitoring of metal contamination in a marine prosobranch snail (Nassarius reticulatus) by imaging laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS).

    Science.gov (United States)

    Santos, Mirian C; Wagner, Martin; Wu, Bei; Scheider, Jessica; Oehlmann, Jörg; Cadore, Solange; Becker, J Sabine

    2009-12-15

    An imaging mass spectrometric method using laser ablation inductively coupled plasma spectrometry (LA-ICP-MS) was developed to determine Cu, Zn, Cd, Hg and Pb and metal distribution in longitudinal tissue sections of the marine snail Nassarius reticulatus (Gastropoda, Prosobranchia). Snails were sampled in northern Brittany (France) at three stations with different contamination levels. The quantification of metal distribution (imaging or mapping) in a thin slice of the snail tissue was carried out using different strategies: by one-point calibration and via matrix-matched laboratory standards using different biological materials (BCR 278, snail tissue, and rat brain). Together with the imaging of metals the distribution of two non-metals (carbon and sulfur) was analyzed. The imaging LA-ICP-MS analysis yielded an inhomogeneous distribution for all elements investigated. The detection limits for the distribution analysis of Cu, Zn, Cd, Hg and Pb measured by LA-ICP-MS were in the low microg g(-1) range.

  9. The stages and duration of the Kieveiskoe and Fedorovskoe Pt-Pd deposits formation: U-Pb zircon data (Kola Peninsula)

    Science.gov (United States)

    Nitkina, Elena

    2010-05-01

    The Kola Peninsula is one of the unique geological provinces both in Russia and in the world, where Pt-Pd Kieveiskoe and Fedorovskoe deposits have been discovered (Mitrofanov, 2005). Several deposits within the Northern and Southern belts contain first hundreds of tons of estimated platinum metal resources, allowing us to ascribe the intrusions of the belts to the class of large igneous province (Schissel et al., 2002; Mitrofanov, 2005). The Kieveiskoe and Fedorovskoe deposits belong to the Pt-bearing Fedorovo-Pansky layered intrusion which is situated in the central part of the Kola Peninsula and is one of 14 major Early Proterozoic layered massifs of the Northern belt occurring at the border between Early Proterozoic volcano-sedimentary rift sequences and Archaean basement gneisses (Zagorodny, Radchenko, 1983; Bayanova, 2004). The aim of this report is to summarize all U-Pb data for Kieveiskoe and Fedorovskoe deposits including single grain dating with Pb205 tracer. At present, the following ages have been defined for the different stages of the massif evolution: 2526 - 2516 Ma - pyroxenite and gabbro of the Fedorovskoe deposit magma chamber (Nitkina, 2006), 2515 - 2518 Ma - Pt-bearing gabbro of Federovskoe stratiforme deposit; 2505 - 2496- 2485 Ma (Bayanova, 2004; Nitkina, 2006) - gabbro-norite and gabbro of the main phase of the Kieveiskoe deposit magma chamber and disseminated platinum-metal mineralization and relatively rich Cu-Ni sulphide mineralization in the basal part of the Kieveiskoe and Fedorovskoe non-stratiforme deposits; ca. 2470 Ma (Bayanova, 2004) - pegmatoid gabbro-anothosite and, probably, fluid-associated rich platinum-metal ores of the Lower Layered Horizon (Kieveiskoe deposit); ca. 2447+/-12 Ma (U-Pb zircon and baddeleyte (Bayanova, 2004)) - anorthositic injections and, probably, local lens-like rich Pt-Pd accumulations of the Upper layered Horizon (Kieveiskoe deposit). The U-Pb zircon ages of the massif evolution stages corroborate the

  10. Provenance variability along the Early Ordovician north Gondwana margin: Paleogeographic and tectonic implications of U-Pb detrital zircon ages from the Armorican Quartzite of the Iberian Variscan belt

    NARCIS (Netherlands)

    Shaw, J.; Gutiérrez-Alonso, G.; Johnston, S.T.; Pastor-Galán, D.

    2014-01-01

    Detrital zircon laser ablation–inductively coupled plasma–mass spectrometry U-Pb age data from the Lower Ordovician Armorican Quartzite (deformed passive margin strata of Gondwanan affinity) of the Iberian Massif are presented herein. The S-shaped coupled Iberian oroclines defined within these zones

  11. African/Amazonian Proterozoic correlations of Iberia: A detrital zircon U-Pb study of early Cambrian conglomerates from the Sierra de la Demanda (northern Spain)

    Science.gov (United States)

    ÁBalos, B.; Gil Ibarguchi, J. I.; SáNchez-Lorda, M. E.; Paquette, J. L.

    2012-06-01

    Unfoliated conglomerates define the base of an Early Cambrian transgressive system tract in the Sierra de la Demanda. Correlations allow us to bracket the corresponding sechron between 532 Ma and 520-521 Ma. These conglomerates contain sandstone and metamorphic quartzite pebbles carrying detrital tourmaline, rutile and zircon grains of plutonic or medium- to high-grade metamorphic derivation. Zircon detrital grains exhibit concordant or sub-concordant U/Pb ages clustered in various groups, including Neoarchean (2.52-2.56 Ga), Paleoproterozoic (1.71-2.02 Ga), and Mesoproterozoic (1.47 and ca. 1.1-1.0 Ga), the latter representative of orogenic magmatism related to Rodinia supercontinental assembly. The Neoproterozoic is represented by concordant ages in the range 750-880 Ma and by Cryogenian discordant ages. Ediacaran zircons cluster in two subsets ranging between 590 and 680 Ma and 560-585 Ma, both including several concordant ages. They reflect formation of juvenile crust in magmatic arc and back-arc basin settings. Zircon ages younger than 520-525 Ma postdate the depositional age of the conglomerate and may represent Hercynian overprinting. Bibliographic data overlooked in other provenance studies indicate that Mesoproterozoic relics as those presented here should no longer be considered of exotic origin with respect to a Gondwanan (West African) affinity of the Neoproterozoic to early Paleozoic of Iberia. The proposed source area, the "Ebro Massif" of central-north Iberia, currently is concealed under a kilometer-thick Paleozoic or younger cover. Its tectonic organization would compare to that of the North African or Amazonian cratons (including Mesoproterozoic components), rather than to the Neoproterozoic arc settings described in northwest and southwest Iberia.

  12. Complexity of In-situ zircon U-Pb-Hf isotope systematics during arc magma genesis at the roots of a Cretaceous arc, Fiordland, New Zealand

    Science.gov (United States)

    Milan, L. A.; Daczko, N. R.; Clarke, G. L.; Allibone, A. H.

    2016-11-01

    Zircons from seventeen samples of Western Fiordland Orthogneiss (WFO) diorites and three samples of country rock (two schists and one Darran Suite diorite) from the lowermost exposed sections of the Median Batholith, Fiordland, New Zealand, were analysed for in-situ U-Pb and Hf-isotopes. The WFO represents the deeper levels of Early Cretaceous continental arc magmatism on the Pacific margin of Gondwana, marking the final stage of long-lived arc magmatism on the margin spanning the Palaeozoic. The WFO plutons were emplaced at high-P (mid to deep crust at c. 8-12 kbar) between 124 and 114 Ma. Minor very high-P (c. 18 kbar) WFO eclogite and omphacite granulite facies orthogneiss (Breaksea Orthogneiss) are inferred to have crystallised in the base of thickened crust at c. 124 Ma. Zircons from the Breaksea Orthogneiss are considered to be variably affected by Pb-loss due to emplacement of the adjacent (Malaspina) Pluton at c. 114 Ma. By identifying Pb-loss, magmatic ages were able to be inferred in respect to apparent Pb-loss ages. Hf isotope data for the WFO define an excursion to less radiogenic Hf isotope ratios with time, reflecting increased recycling of an old source component. Peaks at c. 555, 770 and 2480 Ma, determine the age spectra of inherited populations of zircons within the WFO. This contrasts with detrital zircon patterns in country rocks of the Takaka terrane, which include peaks at c. 465 Ma, and 1250-900 Ma that are absent in the WFO inheritance pattern. These results indicate a previously unrecognised Precambrian lower crustal component of New Zealand. Recycling of this lower crust became increasingly important as a source for the final stage or Mesozoic arc magmatism along this segment of the palaeo-Pacific margin of Gondwana.

  13. Heavy mineral compositions and zircon U-Pb ages of Cenozoic sandstones in the SW Qaidam basin, northern Tibetan Plateau: Implications for provenance and tectonic setting

    Science.gov (United States)

    Zhu, Wen; Wu, Chaodong; Wang, Jialin; Zhou, Tianqi; Li, Jijun; Zhang, Changhao; Li, Linlin

    2017-09-01

    The Qaidam basin is the largest intermountain basin within the Tibetan Plateau. The spatio-temporal evolution of the basin and the provenances of the deposits in the SW Qaidam basin were greatly influenced by the boundary ranges. Comprehensive research is needed to identify the relationships between the basin and the surrounding ranges. Therefore, 4682 heavy mineral data from 70 wells and 720 detrital zircon ages from 8 samples were used to investigate the provenances of the deposits in the SW Qaidam basin and to further constrain the tectonic evolution of the boundary ranges. The heavy mineral data, zircon U-Pb ages, and paleocurrent data indicate that the Qimen Tagh Range and the Altyn Tagh Range were two provenances of the sediments deposited in the SW Qaidam basin during the Cenozoic. The variations of heavy mineral assemblages and ZTR index (100 ∗ (zircon + tourmaline + rutile)/total transparent heavy minerals) on the northern flank of the Qimen Tagh Range suggest that the Qimen Tagh Range experienced rapid uplift in the Early to Middle Miocene. Furthermore, according to the greatly increased quantities of epidote and hornblende sourced from the Altyn Tagh Range and the obvious decrease in the ZTR index values, the Altyn Tagh Range underwent fast uplift in the Late Oligocene to Early Miocene. In addition, based on the ages of the granitic plutons in the Altyn Tagh Range and the zircon ages in the Ganchaigou and Qigequan sections, the strike-slip movement of the Altyn Tagh Fault (ATF) initiated during or no later than the Middle Eocene, resulting in the ATF offsets of ca. 200 km between the Middle Eocene and the Miocene and of ca. 345 km between the Middle Eocene and the present.

  14. U-Pb geochronology of zircon and polygenetic titanite from the Glastonbury Complex, Connecticut, USA: An integrated SEM, EMPA, TIMS, and SHRIMP study

    Science.gov (United States)

    Aleinikoff, J.N.; Wintsch, R.P.; Fanning, C.M.; Dorais, M.J.

    2002-01-01

    U-Pb ages for zircon and titanite from a granodioritic gneiss in the Glastonbury Complex, Connecticut, have been determined using both isotope dilution thermal ionization mass spectrometry (TIMS) and the sensitive high resolution ion microprobe (SHRIMP). Zircons occur in three morphologic populations: (1) equant to stubby, multifaceted, colorless, (2) prismatic, dark brown, with numerous cracks, and (3) elongate, prismatic, light tan to colorless. Cathodoluminescence (CL) imaging of the three populations shows simple concentric oscillatory zoning. The zircon TIMS age [weighted average of 207Pb/206Pb ages from Group 3 grains-450.5 ?? 1.6 Ma (MSWD=1.11)] and SHRIMP age [composite of 206Pb/238 U age data from all three groups-448.2 ?? 2.7 Ma (MSWD = 1.3)], are interpreted to suggest a relatively simple crystallization history. Titanite from the granodioritic gneiss occurs as both brown and colorless varieties. Scanning electron microscope backscatter (BSE) images of brown grains show multiple cross-cutting oscillatory zones of variable brightness and dark overgrowths. Colorless grains are unzoned or contain subtle wispy or very faint oscillatory zoning. Electron microprobe analysis (EMPA) clearly distinguishes the two populations. Brown grains contain relatively high concentrations of Fe2O3, Ce2O3 (up to ~ 1.5 wt.%), Nb2O5, and Zr. Cerium concentration is positively correlated with total REE + Y concentration, which together can exceed 3.5 wt.%. Oscillatory zoning in brown titanite is correlated with variations in REE concentrations. In contrast, colorless titanite (both as discrete grains and overgrowths on brown titanite) contains lower concentrations of Y, REE, Fe2O3, and Zr, but somewhat higher Al2O3 and Nb2O5. Uranium concentrations and Th/U discriminate between brown grains (typically 200-400 ppm U; all analyses but one have Th/U between about 0.8 and 2) and colorless grains (10-60 ppm U; Th/U of 0-0.17). In contrast to the zircon U-Pb age results, SHRIMP U-Pb

  15. In situ quantification of Br and Cl in minerals and fluid inclusions by LA-ICP-MS: a powerful tool to identify fluid sources

    Science.gov (United States)

    Hammerli, Johannes; Rusk, Brian; Spandler, Carl; Emsbo, Poul; Oliver, Nicholas H.S.

    2013-01-01

    Bromine and chlorine are important halogens for fluid source identification in the Earth's crust, but until recently we lacked routine analytical techniques to determine the concentration of these elements in situ on a micrometer scale in minerals and fluid inclusions. In this study, we evaluate the potential of in situ Cl and Br measurements by LA-ICP-MS through analysis of a range of scapolite grains with known Cl and Br concentrations. We assess the effects of varying spot sizes, variable plasma energy and resolve the contribution of polyatomic interferences on Br measurements. Using well-characterised natural scapolite standards, we show that LA-ICP-MS analysis allows measurement of Br and Cl concentrations in scapolite, and fluid inclusions as small as 16 μm in diameter and potentially in sodalite and a variety of other minerals, such as apatite, biotite, and amphibole. As a demonstration of the accuracy and potential of Cl and Br analyses by LA-ICP-MS, we analysed natural fluid inclusions hosted in sphalerite and compared them to crush and leach ion chromatography Cl/Br analyses. Limit of detection for Br is ~8 μg g−1, whereas relatively high Cl concentrations (> 500 μg g−1) are required for quantification by LA-ICP-MS. In general, our LA-ICP-MS fluid inclusion results agree well with ion chromatography (IC) data. Additionally, combined cathodoluminescence and LA-ICP-MS analyses on natural scapolites within a well-studied regional metamorphic suite in South Australia demonstrate that Cl and Br can be quantified with a ~25 μm resolution in natural minerals. This technique can be applied to resolve a range of hydrothermal geology problems, including determining the origins of ore forming brines and ore deposition processes, mapping metamorphic and hydrothermal fluid provinces and pathways, and constraining the effects of fluid–rock reactions and fluid mixing.

  16. LA-ICPMS U-Pb Dating of Zircons from Tuffs of the Upper Permian-Middle Triassic in Youjiang Basin,Guangxi Province and Its Geological Significance%右江盆地上二叠统—中三叠统凝灰岩年龄及其地质意义

    Institute of Scientific and Technical Information of China (English)

    黄虎; 杨江海; 杜远生; 黄宏伟; 黄志强; 谢春霞; 胡丽沙

    2012-01-01

    Upper Permian-Middle Triassic sections in Youjiang basin contain many volcanic tuff horizons. Zircon LA-ICP-MS U-Pb dating of 4 volcanic tuff samples from the bottom of the Luolou and Baifeng formations in the Jiuxu and Lizhou areas, Guangxi Province, yield the depositional ages of 252. 8 + 1. 8, 253. 0 + 2. 4, 247. 2+1. 5 and 239. 3±2. 7 Ma, respectively, which, together with the inherited or xenocrystal zircon ages (with peak values of 264 and 267 Ma), indicate that episodical volcanism occurred during Middle Permian Gudalupian and Middle Triassic Bithynian in southwestern China The appearance of the inherited zircon ages (260-270 Ma) from the volcanic tuffs around the Permian-Triassic boundary (PTB) indicate the volcanic events in South China may have caused the End-Permian extinction. The depositional age of 247. 2 + 1. 5 Ma from the volcanic tuff at the bottom of the Middle Triassic Baifeng Formation indicates it is more appropriate to place the Early to Middle Trissic boundary at 247. 2 Ma. The petrographical study of the volcanic tuffs indicates the Youjiang basin expierenced the tectonic transition from extension to compression after Middle Triassic, and especially after Bithynian, which resulted in the great tectonic subsidence of the basin.%右江盆地上二叠统—中三叠统地层中常含有多层凝灰岩,对采自广西河池九圩及田林利周罗楼组和百逢组底部的4件凝灰岩样品进行锆石原位LA-ICPMS方法U-Pb同位素定年,结果显示凝灰岩的形成年龄分别为252.8±1.8Ma、253.0±2.4 Ma、247.2±1.5Ma和239.3±2.7Ma,指示晚二叠世末期到中三叠世Bithynian期华南地块西南缘存在多期火山活动,其可能与华南西南缘陆块的裂解与汇聚有关.凝灰岩中继承或捕虏锆石年龄(260~270Ma)记录了中晚二叠世峨眉山大火成岩省岩浆活动或华南西南缘岛弧火山活动事件.凝灰岩的岩相学研究表明,中三叠世特别是Bithynian期之后右江盆地由伸展

  17. U-Pb zircon geochronology and phase equilibria modelling of a mafic eclogite from the Sumdo complex of south-east Tibet: Insights into prograde zircon growth and the assembly of the Tibetan plateau

    Science.gov (United States)

    Weller, O. M.; St-Onge, M. R.; Rayner, N.; Waters, D. J.; Searle, M. P.; Palin, R. M.

    2016-10-01

    The Sumdo complex is a Permian-Triassic eclogitic metamorphic belt in south-east Tibet, which marks the location of a suture zone that separates the northern and southern Lhasa terranes. An integrated geochronological and petrological study of a mafic eclogite from the complex has constrained its tectonometamorphic history and provides a case study of zircon growth in eclogite as a product of prograde dissolution-precipitation. In situ U-Pb geochronology indicates that the eclogite contains a single population of zircon with a crystallisation age of 273.6 ± 2.8 Ma. The morphology and chemistry of the zircon grains are consistent with growth by dissolution-precipitation of protolith magmatic zircon. The presence of zircon grains as inclusions in the cores of peak phases indicates that zircon dissolution-precipitation occurred during prograde metamorphism, and calculated pressure and temperature conditions over which mineral inclusions in zircon are stable suggest that the zircon most likely precipitated at 15.5-16.5 kbar and 500-560 °C. Subsequent peak metamorphism is calculated to have reached pressure-temperature conditions of 27 ± 1 kbar and 670 ± 50 °C. Previous studies, which have documented a range of peak metamorphic conditions from high- to ultrahigh-pressure at c. 266-230 Ma, indicate that the Sumdo complex is a composite belt that experienced protracted eclogite exhumation. The results of this study are consistent with this interpretation, and extend the age range of high-pressure metamorphism in the complex to over 40 Myr. Analysis of published pressure-temperature-time data indicates two systematic behaviours within this spread. First, peak metamorphic temperatures declined over time. Second, eclogite exhumation occurred in two discrete intervals: soon after formation, and during the demise of the subduction zone. The latter behaviour serves as a reminder that eclogite exhumation is the exception rather than the rule.

  18. Imaging of Selenium by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) in 2-D Electrophoresis Gels and Biological Tissues.

    Science.gov (United States)

    Cruz, Elisa Castañeda Santa; Susanne Becker, J; Sabine Becker, J; Sussulini, Alessandra

    2018-01-01

    Selenium and selenoproteins are important components of living organisms that play a role in different biological processes. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is a powerful analytical technique that has been employed to obtain distribution maps of selenium in biological tissues in a direct manner, as well as in selenoproteins, previously separated by their molecular masses and isoelectric points using two-dimensional polyacrylamide gel electrophoresis (2-D PAGE). In this chapter, we present the protocols to perform LA-ICP-MS imaging experiments, allowing the distribution visualization and determination of selenium and/or selenoproteins in biological systems.

  19. SHRIMP U-Pb zircon ages of granite gneiss and paragneiss from Oki-Dogo island, southwest Japan, and their tectonic implications

    Science.gov (United States)

    Cho, D.-L.; Takahashi, Y.; Yi, K.; Lee, S. R.

    2012-04-01

    The Hida belt, located in the northern part of southwest Japan, is considered to be a rarely preserved cratonic remnant originated from the easternmost continental margin of the Eurasian continent before the major build-up of the Japanese Islands. It is thus one of the key tectonic elements to unravel the continental accretion processes of the East Asia that have been almost accomplished at the end of the Permo-Triassic time. The gneiss in the Oki-Dogo Island is considered as a western extension of the Hida gneiss on the basis of similarities in both lithofacies and metamorphic ages. However, recent geochronologic investigations on these gneisses raised a question against the simple tectonic correlation between the Hida belt and Oki-Dogo Island (e.g., Tsutsumi et al., 2006). In this work we report new SHRIMP U-Pb zircon ages obtained from two granite gneiss and a paragneiss (Oki gneiss) from Oki-Dogo island. Samples include garnet-bearing granite gneiss (OKI8), granite gneiss (OKI14) and garnet-biotite gneiss (OKI13). Most of zircon grains in OKI8 and OKI14 show oscillatory zoning patterns. They give almost equivalent Late Paleoprotrozoic ages of 1867±16 Ma (n=20, MSWD=2.0) and 1881±17 Ma (n= 20, MSWD=4.4) which are interpreted to date the emplacement ages of the granite protoliths. A few of zircon grains from sample OKI8 show recrystallized rims yielding Triassic metamorphic age of 235.0±6.1 Ma (n=9, MSWD=1.8). Zircon grains from OKI13 have overgrowth rims with low Th/U ratio, and gave a Late Paleoprotrozoic metamorphic age of 1867±16 Ma (n=18, MSWD=3.3) marking the timing of the paragneiss. Most of inherited cores of OKI13 zircons showing magmatic zoning patterns with high Th/U ratio gave a spectrum ranging in ages from Late Archean (up to 2693 Ma) to Early Paleotroterozoic. The Permo-Triassic metamorphic age (~235 Ma) obtained here is well corroborated with those reported from the Hida belt. However, formation ages (~1.9 Ga) of the Oki Gneisses are clearly

  20. U-Pb Detrital Zircon Geochronologic Constraints on Depositional Age and Sediment Source Terrains of the Late Paleozoic Tepuel-Genoa Basin

    Science.gov (United States)

    Griffis, N. P.; Montanez, I. P.; Isbell, J.; Gulbranson, E. L.; Wimpenny, J.; Yin, Q. Z.; Cúneo, N. R.; Pagani, M. A.; Taboada, A. C.

    2014-12-01

    The late Paleozoic Ice Age (LPIA) is the longest-lived icehouse of the Phanerozoic and the only time a metazoan dominated and vegetated world transitioned from an icehouse climate into a greenhouse. Despite several decades of research, the timing, extent of glaciation and the location of ice centers remain unresolved, which prohibits reconstruction of ice volume. The Permo-Carboniferous sediments in the Tepuel-Genoa Basin, Patagonia contains a near complete record of sedimentation from the lower Carboniferous through lower Permian. Outsized clasts, thin pebble-rich diamictites and slumps represent the last of the late Paleozoic glacially influenced deep-water marine sediments in the Mojón de Hierro Fm. and the Paleozoic of Patagonia. U-Pb analysis of detrital zircons separated from slope sediments reveal groupings (20 myr bins, n≥5 zircons) with peak depositional ages of 420, 540 to 660 and 1040 Ma. Zircon age populations recovered from the Mojón de Hierro Fm. compare well with bedrock ages of the Deseado Massif of SE Patagonia, suggesting this may be a potential source of sediments. The maximum depositional age of the sediments is 306.05 ± 3.7 Ma (2σ) as determined by the median age of the two youngest concordant zircons that overlap in error. The youngest zircon from the analysis yields a 238U/206Pb age of 301.3 ± 4.5 Ma (2σ; MSWD = 2.3). Younger zircons from the analysis compare well with the age of granite bedrock exposed along the basin margin to the E-NE suggesting they may reflect a more proximal source. These data, which indicate a maximum age of late Carboniferous for the Mojón de Hierro Fm, provide the first geochemical constraints for the timing of final deposition of glaciomarine sediments in the Tepuel-Genoa Basin, and contributes to the biostratigraphic correlation of the late Paleozoic succession in Patagonia with other key LPIA basins that has thus far been hindered by faunal provincialism.

  1. Formation history and protolith characteristics of granulite facies metamorphic rock in Central Cathaysia deduced from U-Pb and Lu-Hf isotopic studies of single zircon grains

    Institute of Scientific and Technical Information of China (English)

    YU Jinhai; ZHOU Xinmin; Y. S. O'Reilly; ZHAO Lei; W. L. Griffin; WANG Rucheng; WANG Lijuan; CHEN Xiaomin

    2005-01-01

    The petrochemical as well as zircon U-Pb and Lu-Hf isotopic studies of granulite facies metamorphic rock from the Taoxi Group in eastern Nanling Range, Central Cathaysia indicate that its protolith is the sedimentary rock with low maturation index. The clastic materials are mostly from middle Neoproterozoic (~736 Ma) granitoid rocks with minor Neoarchaean and Paleoproterozoic rocks. The timing of this Neoproterozoic magmatism is in agreement with the second period of magmatism widespread surrounding the Yangtze Block. Hf isotopic data indicate that the Neoproterozoic granitoids resulted from the recycled Paleoproterozoic mantle-derived crustal materials. The sedimentary rock was deposited in Late Neoproterozoic Era, and carried into low crust in Early Paleozoic. The partial melting of the meta-sedimentary rock took place at about 480 Ma and subsequently granulite facies metamorphism occurred at ca. 443 Ma. The zircons forming during this time interval (Early Paleozoic) show large Hf isotope variations, and their -Hf(t) values increase from -13.2 to +2.36 with decreasing age, suggesting the injection of mantle-derived materials during partial melting and metamorphism processes in the Early Paleozoic. Calculation results show that this metamorphic rock, if evolved to Mesozoic, has similar isotopic composition to the nearby Mesozoic high Si peraluminous granites, implying that this kind of granulite facies metamorphic rock is probably the source material of some Mesozoic peraluminous granitoids in eastern Nanling Range.

  2. U/Pb ages on detrital zircons in the southern central Andes Neogene foreland (36°-37°S): Constraints on Andean exhumation

    Science.gov (United States)

    Sagripanti, Lucía; Bottesi, Germán; Naipauer, Maximiliano; Folguera, Andrés; Ramos, Victor A.

    2011-12-01

    U/Pb dating on detrital zircons was performed in the Pampa de Carrizalito depocenter of the Late Miocene foreland basin associated with the Southern Central Andes orogenic front. This reveals Andean and pre-Andean components in magmatic derived zircons inhomogeneously distributed through the sequence. Andean, Grenville, Pampean, Famatinian and Gondwanic components reveal a complex source distribution from either the Main Andes, Coastal Cordillera and basement foreland areas. These are discussed showing different patterns in the context of the Andean orogenic cycle. Cretaceous and Jurassic components that are partly related to Mesozoic batholiths, developed at the western slope of the Andes at these latitudes, have a very contrasting behavior through the sequence: While Jurassic grains are represented from base to top, Cretaceous ones dilute upwardly. This is explained through the progressive uplift of the Southern Central Andes that could have created a barrier to Cretaceous and Jurassic detritus, while the older ones could have had either an alternative source area represented by the inverted rift system of the Huincul Ridge in the foreland area and the Cordillera del Viento in the hinterland area or the reworking of Jurassic sedimentary sequences of the Neuquén basin. Finally, a progressive enrichment in pre-Andean components to the top of the sequence is interpreted as related to the development of a broken foreland and the consequent rapid expansion of the orogenic front at the time of development of a slab shallowing setting in the region as shown by previous works.

  3. U Pb zircon (TIMS and SIMS) and Sm Nd whole-rock geochronology of the Gour Oumelalen granulitic basement, Hoggar massif, Tuareg shield, Algeria

    Science.gov (United States)

    Peucat, Jean Jacques; Drareni, Amar; Latouche, Louis; Deloule, Etienne; Vidal, Philippe

    2003-11-01

    Two major granulitic units are recognized in the Gour Oumelalen area. One of the units is composed partially of Archean gneisses (Red Gneiss complex) with U-Pb zircon SIMS and TIMS ages of approximately 2.7 Ga. Although they were formed from 3.0- to 3.2-Ga-old precursors, as indicated by Nd model ages, we find no evidence of any older history (≈3.5 Ga) as suggested by previous Pb-Pb ages. The other formation (Gour Oumelalen supergroup) is a metasedimentary sequence at least partly of Paleoproterozoic age, as indicated by zircon dates of a metavolcanic rock at approximately 2.2 Ga. A later magmatic event is recorded at approximately 1.9 Ga in both units and related to coeval granulite-facies metamorphism that affected both units. Nd model ages at approximately 2.0 Ga suggest an accretion of juvenile crust formation at that time. The existence of T DM Nd model ages intermediate between 2.5 and 2.9 Ga could result from the mixing of 3.2 and 2.0-Ga-old material or may reflect separate events.

  4. Paleoproterozoic crustal evolution in the East Sarmatian Orogen: Petrology, geochemistry, Sr-Nd isotopes and zircon U-Pb geochronology of andesites from the Voronezh massif, Western Russia

    Science.gov (United States)

    Terentiev, R. A.; Savko, K. A.; Santosh, M.

    2016-03-01

    Andesites and related plutonic rocks are major contributors to continental growth and provide insights into the interaction between the mantle and crust. Paleoproterozoic volcanic rocks are important components of the East Sarmatian Orogen (ESO) belonging to the East European Craton, although their petrogenesis and tectonic setting remain controversial. Here we present petrology, mineral chemistry, bulk chemistry, Sr-Nd isotopes, and zircon U-Pb geochronological data from andesites and related rocks in the Losevo and Vorontsovka blocks of the ESO. Clinopyroxene phenocrysts in the andesites are depleted in LREE, and enriched in HFSE (Th, Nb, Zr, Hf, Ti) and LILE (Ba, Sr). Based on the chemistry of pyroxenes and whole rocks, as well as Fe-Ti oxides, we estimate a temperature range of 1179 to 1262 °C, pressures of 11.3 to 13.0 kbar, H2O content of 1-5 wt.%, and oxygen fu gacity close to the MH buffer for the melts of the Kalach graben (KG) and the Baygora area (BA) andesites. Our zircon U-Pb geochronological data indicate new zircon growth during the middle Paleoproterozoic as displayed by weighted mean 207Pb/206Pb ages of 2047 ± 17 Ma and 2040 ± 16 Ma for andesite and dacite-porphyry of the BA, and 2050 ± 16 Ma from high-Mg basaltic andesite of the KG. The andesites and related rocks of the KG and BA are characterized by high magnesium contents (Mg # up to 0.68). All these volcanic rocks are depleted in LREE and HFSE, and display negative Nb and Ti anomalies relative to primitive mantle. The high-Mg bulk composition, and the presence of clinopyroxene phenocrysts suggests that the parent melts of the KG and BA suite were in equilibrium with the mantle rocks. The rocks show positive εNd(T) values and low initial 87Sr/86Sr, suggesting that the magmas were mostly derived from metasomatized mantle source. The geochemical differences between the two andesite types are attributed to: the predominance of fractional crystallization, and minor role of contamination in the

  5. SHRIMP U-Pb zircon geochronology of Mesozoic granitoids from the Bariloche region (Argentina): Implications for the Middle-Late Jurassic evolution of the North Patagonian batholith.

    Science.gov (United States)

    Castro, Antonio; Vujovich, Graciela; Fernández, Carlos; Moreno-Ventas, Iñaki; Martino, Roberto; Corretgé, Guillermo; Díaz-Alvarado, Juan; Heredia, Nemesio; Gallastegui, Gloria

    2010-05-01

    A detailed U-Pb geochronological study has been carried out on granitoids of the North Patagonian batholith in the region of Bariloche (Argentina), between 40°30' S and 41°45' S. In this region, the calc-alkaline, subduction-related, granitic bodies of the North Patagonian batholith intruded an Early Jurassic volcano-sedimentary sequence contemporary with the intrusion of the Subcordilleran Patagonian batholith (J1 magmatism), and unconformably overlying a metamorphic Gondwanan basement. All these rocks were affected by the Andean compressional phases during the Cenozoic. U-Pb SHRIMP dating of zircon crystals from 11 samples (109 spots) of diorites, tonalites, granodiorites and granites yielded dates ranging from 173 ± 3 Ma to 150 ± 2 Ma (Aalenian to Tithonian). No significant age differences have been identified among the distinct lithological types. Also no spatial trend emerges from these results, although ages tend to be younger westward in the traverse of the Manso River (≈ 41° 35' S). Two peaks appear in the probability density plot of zircon ages. Most of the dated zircons are Bajocian-Bathonian (Middle Jurassic, ≈169 Ma, J2 magmatism), while a secondary peak is observed at the boundary Oxfordian-Kimmeridgian (Late Jurassic, ≈ 156 Ma, J3 magmatism). The J2 magmatic period is coeval to the main stage of effusive activity (V2) in the huge volcanic Chon Aike Province, while J3 coincides with the lesser V3 period of volcanism in Chon Aike. These new geochronological data strongly contribute to the knowledge of the first stages of tectonic evolution of the Andean subduction margin in southern South America. Contrary to previous models, it can be proposed that the subduction-related Mesozoic magmatism started well before the Late Jurassic, and that a continuous supply of calc-alkaline magmas dominated the active margin of South America during at least 190 Ma, from the Early Jurassic to nowadays. Therefore, no dramatic time gap can be observed between

  6. The timing of final closure along the Changchun-Yanji suture zone: Constraints from detrital zircon U-Pb dating of the Triassic Dajianggang Formation, NE China

    Science.gov (United States)

    Wang, Bin; Zhou, Jian-Bo; Wilde, Simon A.; Zhang, Xing-Zhou; Ren, Shou-Mai

    2016-09-01

    The Dajianggang Formation is located in the Changchun-Yanji suture zone of central Jilin Province and unconformably overlies the Changchun-Yanji Accretionary Complex (CYAC), which is a mélange resulting from subduction of the Jiamusi-Khanka Block (JKB) beneath the North China Craton (NCC). LA-MC-ICP-MS U-Pb dating of detrital zircon from four samples of the formation yields ages of 2516 to 216 Ma. Zircons with U-Pb ages at 2516-2501 Ma and 1897-1832 Ma indicate a provenance from Precambrian basement rocks of the NCC. The 525-482 Ma ages indicate a provenance from metamorphic rocks of Late Pan-African age in the JKB that have a tectonic affinity to the Central Asian Orogenic Belt (CAOB). Zircon grains with ages of 383-314 Ma and 275-250 Ma were likely derived from the underlying CYAC. The youngest population has a peak age of ca. 225 Ma, which together with Late Triassic fossils, suggests that deposition of the Dajianggang Formation was Late Triassic or younger. This result supports the view that the final collision of the JKB and NCC along the Changchun-Yanji suture took place before the Late Triassic. Furthermore, this closure time is at least 10-20 Ma later than closure along the Solonker-Xar Moron-Changchun suture in the Late Permian. We thus establish that the Changchun-Yanji suture is not related to the collision between the Siberia Craton (SC) and the NCC but was instead related to the Paleo-Pacific plate subduction. Consequently, the Changchun-Yanji suture is not the eastward extension of the Solonker-Xar Moron-Changchun suture as previously considered, but the southern margin of the Jilin-Heilongjiang high-pressure metamorphic belt (Ji-Hei HP belt), and resulted from westward subduction of the Paleo-Pacific Ocean. Thus, the Late Triassic marked the switch in subduction from the Paleo-Asian Ocean to the Paleo-Pacific Ocean in NE China.

  7. Zircon U-Pb Ages Chronicle 3 Myr of Episodic Crystallization in the Composite Miocene Tatoosh Pluton, Mount Rainier National Park, Washington Cascades

    Science.gov (United States)

    Bacon, C. R.; Du Bray, E. A.; Wooden, J. L.; Mazdab, F. K.

    2007-12-01

    Zircon geochronology of upper crustal plutons can constrain longevities of intermediate to silicic magmatic systems. As part of a larger study of the geochemistry and metallogeny of Tertiary Cascades magmatic arc rocks, we used the USGS-Stanford SHRIMP RG to determine 20 to 28 238U-206Pb ages for zircons from each of 6 quartz monzodiorite (qmd), quartz monzonite (qm), or granodiorite (grd) samples representative of the Tatoosh pluton, and one grd from the nearby Carbon River stock. The 7x12 km composite Tatoosh pluton, discontinuously exposed on the south flank of Mount Rainier, consists of at least 4 petrographic/compositional phases, here termed Pyramid Peak, Nisqually, Reflection Lake, and Tatoosh. These collectively intrude gently folded and weakly metamorphosed basaltic andesite flows and volcaniclastic rocks of the Eocene Ohanapecosh Formation, silicic ignimbrites and sedimentary rocks of the Oligocene Stevens Ridge Formation, and basaltic to intermediate volcanic rocks of the Miocene Fifes Peak Formation. Histograms and relative probability plots of U- Pb ages indicate 2 to 4 age populations within each sample. The weighted mean age of each of the youngest populations (all ±2σ) is interpreted as the time of final solidification: Pyramid Peak qmd (58.5% SiO2) 17.4±0.2 Ma, Nisqually grd (in Paradise Valley; 65.4% SiO2) 16.7±0.2 Ma, Nisqually grd (at Christine Falls; 66.4% SiO2) 17.3±0.2 Ma, Reflection Lake qm (along Pinnacle Peak trail; 66.6% SiO2) 17.1±0.2 Ma, Tatoosh grd (in Stevens Canyon; 67.8% SiO2) 18.2±0.2 Ma, Tatoosh grd (south of Louise Lake; 69.3% SiO2) 19.3±0.1 Ma, and Carbon River grd (68.0% SiO2) 17.4±0.3 Ma. The older Nisqually grd age is indistinguishable from a TIMS zircon age of 17.5±0.1 Ma reported by Mattinson (GSA Bulletin 88:1509-1514, 1977) for grd from a nearby locality. None of the 164 SHRIMP-RG U-Pb ages, including cores, is older than 21 Ma. The relatively small, high-level pluton likely was emplaced and solidified in pulses

  8. Determination of Trace and Volatile Element Abundance Systematics of Lunar Pyroclastic Glasses 74220 and 15426 Using LA-ICP-MS

    Science.gov (United States)

    McIntosh, E. Carrie; Porrachia, Magali; McCubbin, Francis M.; Day, James M. D.

    2017-01-01

    Since their recognition as pyroclastic glasses generated by volcanic fire fountaining on the Moon, 74220 and 15426 have garnered significant scientific interest. Early studies recognized that the glasses were particularly enriched in volatile elements on their surfaces. More recently, detailed analyses of the interiors of the glasses, as well as of melt inclusions within olivine grains associated with the 74220 glass beads, have determined high H2O, F, Cl and S contents. Such elevated volatile contents seem at odds with evidence from moderately volatile elements (MVE), such as Zn and K, for a volatile- depleted Moon. In this study, we present initial results from an analytical campaign to study trace element abundances within the pyroclastic glass beads. We report trace element data determined by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) for 15426 and 74220.

  9. Bioimaging mass spectrometry of trace elements – recent advance and applications of LA-ICP-MS: A review

    Energy Technology Data Exchange (ETDEWEB)

    Becker, J.Sabine, E-mail: s.becker@fz-juelich.de [Central Institute for Engineering, Electronics and Analytics (ZEA-3), Forschungszentrum Jülich, Jülich D-52425 (Germany); Matusch, Andreas, E-mail: a.matusch@fz-juelich.de [Institute for Neuroscience and Medicine (INM-2), Forschungszentrum Jülich, Jülich D-52425 (Germany); Wu, Bei, E-mail: b.wu@fz-juelich.de [Central Institute for Engineering, Electronics and Analytics (ZEA-3), Forschungszentrum Jülich, Jülich D-52425 (Germany)

    2014-07-04

    Highlights: • Bioimaging LA-ICP-MS is established for trace metals within biomedical specimens. • Trace metal imaging allows to study brain function and neurodegenerative diseases. • Laser microdissection ICP-MS was applied to mouse brain hippocampus and wheat root. - Abstract: Bioimaging using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) offers the capability to quantify trace elements and isotopes within tissue sections with a spatial resolution ranging about 10–100 μm. Distribution analysis adds to clarifying basic questions of biomedical research and enables bioaccumulation and bioavailability studies for ecological and toxicological risk assessment in humans, animals and plants. Major application fields of mass spectrometry imaging (MSI) and metallomics have been in brain and cancer research, animal model validation, drug development and plant science. Here we give an overview of latest achievements in methods and applications. Recent improvements in ablation systems, operation and cell design enabled progressively better spatial resolutions down to 1 μm. Meanwhile, a body of research has accumulated covering basic principles of the element architecture in animals and plants that could consistently be reproduced by several laboratories such as the distribution of Fe, Cu, Zn in rodent brain. Several studies investigated the distribution and delivery of metallo-drugs in animals. Hyper-accumulating plants and pollution indicator organisms have been the key topics in environmental science. Increasingly, larger series of samples are analyzed, may it be in the frame of comparisons between intervention and control groups, of time kinetics or of three-dimensional atlas approaches.

  10. A comparison of sample preparation strategies for biological tissues and subsequent trace element analysis using LA-ICP-MS.

    Science.gov (United States)

    Bonta, Maximilian; Török, Szilvia; Hegedus, Balazs; Döme, Balazs; Limbeck, Andreas

    2017-03-01

    Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is one of the most commonly applied methods for lateral trace element distribution analysis in medical studies. Many improvements of the technique regarding quantification and achievable lateral resolution have been achieved in the last years. Nevertheless, sample preparation is also of major importance and the optimal sample preparation strategy still has not been defined. While conventional histology knows a number of sample pre-treatment strategies, little is known about the effect of these approaches on the lateral distributions of elements and/or their quantities in tissues. The technique of formalin fixation and paraffin embedding (FFPE) has emerged as the gold standard in tissue preparation. However, the potential use for elemental distribution studies is questionable due to a large number of sample preparation steps. In this work, LA-ICP-MS was used to examine the applicability of the FFPE sample preparation approach for elemental distribution studies. Qualitative elemental distributions as well as quantitative concentrations in cryo-cut tissues as well as FFPE samples were compared. Results showed that some metals (especially Na and K) are severely affected by the FFPE process, whereas others (e.g., Mn, Ni) are less influenced. Based on these results, a general recommendation can be given: FFPE samples are completely unsuitable for the analysis of alkaline metals. When analyzing transition metals, FFPE samples can give comparable results to snap-frozen tissues. Graphical abstract Sample preparation strategies for biological tissues are compared with regard to the elemental distributions and average trace element concentrations.

  11. Structural evolution and U-Pb SHRIMP zircon ages of the Neoproterozoic Maria da Fé shear zone, central Ribeira Belt - SE Brazil

    Science.gov (United States)

    Zuquim, M. P. S.; Trouw, R. A. J.; Trouw, C. C.; Tohver, E.

    2011-03-01

    The Maria da Fé Shear Zone (MFSZ) is a sinistral strike-slip kilometric-scale structure developed in the late Neoproterozoic during the assembly of Gondwana. The MFSZ development is related to the NW-SE collision between the São Francisco Paleocontinent and the Rio Negro Magmatic Arc, which formed the Ribeira Belt. This paper describes the shear zone in detail, concluding that the orientation and age are consistent with NW-SE shortening during the afore mentioned collision. A U-Pb SHRIMP Concordia age of 586.9 ± 8.7 Ma is reported from zircon grains of a granitic dyke that crystallised synkinematically to the main tectonic activity of the shear zone. Another group of zircon grains from the same sample generated an upper intercept age of 2083 ± 43 Ma anchored in the younger Concordia age. These zircon grains are interpreted as relict grains of the basement from which the granite dyke was generated by partial melting. The temperature during mylonitization in the MFSZ was estimated in the range from 450 to 600 °C, based on microstructures in quartz and feldspar. An earlier collision in the same region, between 640 and 610 Ma, led to an extensive nappe-stack with tectonic transport to ENE, integrating the southern Brasilia Belt. One of the thrust zones between these nappes in the studied area is the Cristina Shear Zone with mylonites that were generated under upper amphibolite to granulite facies conditions. Brittle-ductile E-W metric-scale shear zones are superimposed on the MFSZ, which were active in similar, but probably slightly cooler, metamorphic conditions (≈500 °C).

  12. Timing and tectonic implications of the Pan-African Bangangte syenomonzonite, West Cameroon: Constraints from in-situ zircon U-Pb age and Hf-O isotopes

    Science.gov (United States)

    Tchouankoue, Jean Pierre; Li, Xian-Hua; Belnoun, Rose Noel Ngo; Mouafo, Lucas; Ferreira, Valderez Pinto

    2016-12-01

    The Bangangte pluton is a SW-NE elongated (5 × 20 km) massif located in the southeastern part of the Pan-African North Equatorial Fold Belt in Cameroon, consisting of two units with dominant monzonites in the south and syenites in the north. SIMS U-Pb zircon dating yields consistent emplacement ages of 585 ± 4 Ma and 583 ± 4 Ma for the southern unit and the northern unit, respectively. The Bangangte rocks display typical shoshonitic compositions characterized by Na2O + K2O > 5 wt%, K2O/Na2O ∼2, enrichment in LILE and LREE, but depletion in HFSE. Rocks from both units have similar O-Hf isotopes, with the monzonite zircons from the southern unit showing slightly higher δ18O (7.0 ± 0.4‰) but lower εHf(t) (-15.3 ± 1.4) value than the syenite zircons from southern unit (δ18O = 6.0 ± 0.4‰; εHf(t) = -14.0 ± 2.0). They were generated by partial melting of an enriched mantle source metasomatized by previous subduction processes, accompanied by crystal fractionation of pyroxene, Ti-Fe oxides and apatite, as well as crustal contamination to varying degrees. These rocks display a transitional geochemical feature of the subduction-related and within-plate shoshonites, suggesting that they were most likely emplaced in a post-collisional setting at the waning stage of the Pan-African orogeny.

  13. Zircon U-Pb ages and O-Nd isotopic composition of basement rocks in the North Qinling Terrain, central China: evidence for provenance and evolution

    Science.gov (United States)

    Liu, Bing-Xiang; Qi, Yue; Wang, Wei; Siebel, Wolfgang; Zhu, Xi-Yan; Nie, Hu; He, Jian-Feng; Chen, Fukun

    2013-11-01

    The Qinling Group was previously interpreted as the oldest Precambrian basement unit of the North Qinling Terrain, recording its formation and early crustal evolution. The Qinling Group consists predominantly of gneisses, amphibolites, and marbles, which underwent multi-phase deformation and metamorphism. In order to better constrain the provenance and tectonic setting of this group and the evolution of the North Qinling orogenic belt, in situ U-Pb dating and oxygen isotopic analysis of zircons in combination with whole-rock geochemistry and Sr-Nd isotope analysis was performed on the two dominant rock types, amphibolite and felsic gneiss. Felsic gneisses exhibit enrichment of LREEs and LILEs (Rb, Ba, Th, K, Pb), negative Eu anomalies and depletion of HFSEs (Nb, Ta, P, Ti). The rocks have slightly elevated δ18O values (6.5-9.3 ‰) and initial ɛ Nd values of -4.6 corresponding to two-stage Nd model age of 1.99 Ga. Amphibolites are also enriched in LILEs and LREEs and depleted in Nb and Ta and have homogeneous δ18O values (5.0-6.0 ‰), but higher initial ɛ Nd values (2.8-3.3) and younger two-stage Nd model ages (1.29-1.24 Ga) compared to the gneisses. The zircon age record indicates that the gneisses and amphibolites were formed in a ~960 Ma volcanic arc environment rather than in a rift setting as previously suggested. A major metamorphic event took place during the Early Paleozoic. Based on the age spectrum of detrital zircons, the Qinling Group is interpreted as an autonomous geological unit, which was mainly derived mostly from 1,000 to 900 Ma old granitoid rocks. The North Qinling Terrain can be regarded as a remnant of the Grenville orogenic belt with an early Neoproterozoic evolution different from that of the North and South China blocks.

  14. Timing of the Wudangshan, Yaolinghe volcanic sequences and mafic sills in South Qinling: U-Pb zircon geochronology and tectonic implication

    Institute of Scientific and Technical Information of China (English)

    LING WenLi; REN BangFang; DUAN RuiChun; LIU XiaoMing; MAO XinWu; PENG LianHong; LIU ZaoXue; CHENG JianPing; YANG HongMei

    2008-01-01

    The Wudangshan, Yaolinghe volcanic-sedimentary sequences and doleritic-gabbroic sills comprise the largest exposed Precambrian basement in South Qinling. Zircons separated from 5 volcanic-pyroclas-tic samples of the Wudangshan Group, 2 volcanic samples of the Yaolinghe Group and one sample for the mafic sills were used for U-Pb dating by laser ablation-inductively coupled plasma mass spec-trometry (LA-ICPMS). The results reveal that the Wudangshan volcanic sequence was formed at (755±3) Ma (a weighted mean from the 5 samples, MSWD=0.47), whereas the Yaolinghe volcanic suite and the mafic sill were crystallized at (685:L±5) (2 samples, MSWD=0.36) and (679±J:3) Ma (MSWD=1.6), respectively, which are equal to each other within analysis errors. These ages are markedly younger than those previously documented for the rocks. The newly obtained ages for the Wudangshan and Yaolinghe Groups are identical to those of the bottom Liantuo and slightly older than those of the Nantuo Forms-tions, respectively, lower strata of the Nanhua (middle to late Neoproterozoic) stratotype section in eastern Three Gorges, Yangtze craton. A range of inherited magmatic zircons was recognized with ages of 830 to 780 Ma, which are typical of Neoprotzrozoic magmatisms recorded along the margins and interior of the Yangtze craton. Thus, there is Neoproterozoic basement comprising 830-780 Ma igne-ous suites in South Qinling; the inherited zircons were detrital sediments derived from the northern margin of the Yangtze craton. Accordingly, it is suggested that the South Qinling is a segment of the Yangtze craton before the Qinling Orogeny.

  15. SHRIMP U-Pb zircon geochronology of granulites at Rimana (Southern Tibet) in the central segment of Himalayan Orogen

    Institute of Scientific and Technical Information of China (English)

    LI Dewei; LIAO Qunan; YUAN Yanming; WAN Yusheng; LIU Demin; ZHANG Xionghua; YI Shunhua; CAO Shuzhao; XIE Defan

    2003-01-01

    High-pressure mafic granulites, occurring as lenses within gneisses and quartzite in the central segment of the Himalayan orogen, were dated using SHRIMP U-Pb technique. 13 analyses out of a total of 15 are plotted along a concordia line and yield a mean 206Pb/238U age of 17.6 ± 0.3 Ma. This age indicates adiabatic decompression and a metamorphic event associated with rapid uplift of granulites in a tectonic environment resulted from the collision between India and Eurasia, synchronous with large-scale thrusting, extension, detachment as well as emplacement of leucogranite. One analysis gives a 206Pb/238U age of 29.5 ± 0.4 Ma that is interpreted to represent the timing of the final closure of the Neo-Tethys. Another age is 1991 ± 26 Ma that represents the age of the protolith of the granulites. In summary, dating results show that granulites in this area underwent multiphase metamorphism and complex geological evolution.

  16. Tracing source terranes using U-Pb-Hf isotopic analysis of detrital zircons: provenance of the Orhanlar Unit of the Palaeotethyan Karakaya subduction-accretion complex, NW Turkey

    Science.gov (United States)

    Ustaömer, Timur; Ayda Ustaömer, Petek; Robertson, Alastair; Gerdes, Axel

    2016-04-01

    Sandstones of the Late Palaeozoic-Early Mesozoic Karakaya Complex are interpreted to have accumulated along an active continental margin related to northward subduction of Palaeotethys. The age of deposition and provenance of the sandstones are currently being determined using radiometric dating of detrital zircons, coupled with dating of potential source terranes. Our previous work shows that the U-Pb-Hf isotopic characteristics of the sandstones of all but one of the main tectonostratigraphic units of the Karakaya Complex are compatible with a provenance that was dominated by Triassic and Permo-Carboniferous magmatic arc-type rocks, together with a minor contribution from Lower to Mid-Devonian igneous rocks (Ustaömer et al. 2015). However, one of the tectono-stratigraphic units, the Orhanlar Unit, which occurs in a structurally high position, differs in sedimentary facies and composition from the other units of the Karakaya Complex. Here, we report new isotopic age data for the sandstones of the Orhanlar Unit and also from an extensive, associated tectonic slice of continental metamorphic rocks (part of the regional Sakarya Terrane). Our main aim is to assess the provenance of the Orhanlar Unit sandstones in relation to the tectonic development of the Karakaya Complex as a whole. The Orhanlar Unit is composed of shales, sandstone turbidites and debris-flow deposits, which include blocks of Devonian radiolarian chert and Carboniferous and Permian neritic limestones. The sandstones are dominated by rock fragments, principally volcanic and plutonic rocks of basic-to-intermediate composition, metamorphic rocks and chert, together with common quartz, feldspar and mica. This modal composition contrasts significantly with the dominantly arkosic composition of the other Karakaya Complex sandstones. The detrital zircons were dated by the U-Pb method, coupled with determination of Lu-Hf isotopic compositions using a laser ablation microprobe attached to a multicollector

  17. U-Pb SHRIMP-RG zircon ages and Nd signature of lower Paleozoic rifting-related magmatism in the Variscan basement of the Eastern Pyrenees

    Science.gov (United States)

    Martinez, F.J.; Iriondo, A.; Dietsch, C.; Aleinikoff, J.N.; Peucat, J.J.; Cires, J.; Reche, J.; Capdevila, R.

    2011-01-01

    The ages of orthogneisses exposed in massifs of the Variscan chain can determine whether they are part of a pre-Neoproterozoic basement, a Neoproterozoic, Panafrican arc, or are, in fact, lower Paleozoic, and their isotopic compositions can be used to probe the nature of their source rocks, adding to the understanding of the types, distribution, and tectonic evolution of peri-Gondwanan crystalline basement. Using SHRIMP U-Pb zircon geochronology and Nd isotopic analysis, pre-Variscan metaigneous rocks from the N??ria massif in the Eastern Pyrenean axial zone and the Guilleries massif, 70km to the south, have been dated and their Nd signatures characterized. All dated orthogneisses from the N??ria massif have the same age within error, ~457Ma, including the Ribes granophyre, interpreted as a subvolcanic unit within Caradocian sediments contemporaneous with granitic magmas intruded into Cambro-Ordovician sediments at deeper levels. Orthogneisses in the Guilleries massif record essentially continuous magmatic activity during the Ordovician, beginning at the Cambro-Ordovician boundary (488??3Ma) and reaching a peak in the volume of magma in the early Late Ordovician (~460Ma). Metavolcanic rocks in the Guilleries massif were extruded at 452??4Ma and appear to have their intrusive equivalent in thin, deformed veins of granitic gneiss (451??7Ma) within metasedimentary rocks. In orthogneisses from both massifs, the cores of some zircons yield Neoproterozoic ages between ~520 and 900Ma. The age of deposition of a pre-Late Ordovician metapelite in the Guilleries massif is bracketed by the weighted average age of the youngest detrital zircon population, 582??11Ma, and the age of cross-cutting granitic veins, 451??7Ma. Older detrital zircons populations in this metapelite include Neoproterozoic (749-610Ma; n=10), Neo- to Mesoproterozoic (1.04-0.86Ga; n=7), Paleoproterozoic (2.02-1.59Ga; n=5), and Neoarchean (2.74-2.58Ga; n=3). Nd isotopic analyses of the N??ria and Guilleries

  18. Depositional Age of the Pake Formation of Ximeng Group and Its Tectonic Implications:Constraints from Zircon U-Pb Geochronology and Lu-Hf Isotopes%滇西南西盟群帕可组沉积时代厘定及构造意义:锆石U-P b年代学及Lu-Hf同位素证据

    Institute of Scientific and Technical Information of China (English)

    邢晓婉; 张玉芝

    2016-01-01

    研究滇西南地区出露的西盟群碎屑岩沉积时限及其古地理属性对了解冈瓦纳大陆东缘的构造演化及其古地理重建具有重要意义。本文对西盟群帕可组3个变质砂岩样品中的碎屑锆石进行了 LA-ICP-MS U-Pb测年和原位 Lu-Hf同位素组成分析,获得样品的最小年龄峰值分别为568Ma、541Ma和560Ma,εHf(t)值为-24.0~26.3。结合前人对帕可组内片麻状花岗岩的研究成果,推测西盟群帕可组沉积于早寒武世—中奥陶世(541~460Ma),而非以往所认为的前寒武纪地层。Lu-Hf同位素组成则表明西盟群帕可组物源为古老地壳物质的再循环并混入新生地壳组分,结合其他区域地质资料推断西盟群物源类似东印度板块,与东冈瓦纳大陆具有亲缘性。%Depositional age,provenance and paleogeography characteristics of the Ximeng metasedimentary sequence is key for better understanding the tectonic evolution and paleogeographic reconstruction of East Gondwana Continent.This paper presented the zircon U-Pb geochronology and Lu-Hf isotope for three metamorphic sandstone samples from the Pake Formation of Ximeng Group in SW Yunnan.The group has been traditionally considered as the Precambrian metamorphic basement of the Shan-Thai Block.The detrital zircons from three samples yielded the youngest age peaks at 568Ma, 541Ma and 560Ma,respectively,and the εHf(t)values change from -24.0 to +26.3.In combination with other data,it is inferred that the Pake Formation deposited at 541-460Ma,equivalent to Late Cambrian to early-middle Ordovician pe-riod,different from previous proposed Precambrian strata.Their εHf(t)values indicate that their source rocks might origi-nate from the mixing of recycled ancient continental material with juvenile crustal component.Our results,along with other geological data,suggest that the source rocks of the Ximeng Group have an affinity of Tethys-Himalaya and from

  19. U-Pb ages of detrital zircon grains from the Donghe Group in the Southern Qinling Microcontinent: Implications for tectonic evolution%南秦岭东河群碎屑锆石U-Pb年龄及其板块构造意义

    Institute of Scientific and Technical Information of China (English)

    毛世东; 陈衍景; 周振菊; 鲁颖淮

    2013-01-01

    南秦岭微陆块是秦岭造山带的重要构造单元,其早白垩世沉积物是研究物源区及南秦岭微陆块构造演化的理想对象.南秦岭微陆块南缘观音坝盆地早白垩世砂砾岩中的碎屑锆石LA-ICP-MS U-Pb年龄给出了5个年龄峰,范围分别是2600~2300Ma、2050~1800Ma、1200~750Ma、650~400Ma和350~200Ma,对应于Kenor、Columbia、Rodinia、Gondwana和Pangaea等5次超大陆事件.碎屑锆石源区复杂,但主要源自华北克拉通和北秦岭增生带,表明晚古生代南秦岭微陆块是秦岭-华北联合大陆板块的一部分,而非独立的微陆块.最年轻的锆石年龄峰给出了勉略洋向秦岭-华北大陆俯冲的时限,即350~ 200Ma;扬子与秦岭-华北联合大陆板块的碰撞造山作用始于三叠纪-侏罗纪之交,强烈的挤压造山作用发生在侏罗纪,而非三叠纪或更早.%The Southern Qinling Microcontinent is an important tectonic unit of the Qinling orogenic belt. The Early Cretaceous sedimentary sequence is useful to trace the tectonic evolution of the Southern Qinling Microcontinent and sedimentary provenances. Detrital zircon grains from the Early Cretaceous sediments in Southern Qinling Microcontinent yield five U-Pb age clusters of 2600 -2300Ma, 2050 ~ 1800Ma, 1200 ~750Ma, 650 ~400Ma and 350 ~200Ma, corresponding five supercontinental events, namely Kenor, Columbia, Rodinia, Gondwana and Pangaea, respectively. The zircon grains have very complicated sources, but mainly from the Northern Qinling Accretionary Belt and North China Craton, implying that the Southern Qinling Microcontinent was a part of the Qinling-North China united continent, never being an isolated continent, during Late Paleozoic. The youngest age peak constrained that the subduction duration of the Mian-Lue ocean plate northwardly beneath the Qinling-North China united continent was 350 ~ 200Ma; and that the continental collision between the Yangtze Craton and the Qinling-North China

  20. Trace Elements in Ivory Coast Tektites, Microtektites, and Fallback Particles of the Lake Bosumtwi Impact Crater, Ghana: A LA-ICP-MS Study

    Science.gov (United States)

    Luetke, S.; Deutsch, A.; Berndt, J.; Langenhorst, F.

    2008-03-01

    LA-ICP-MS trace element data of Ivory Coast tektites, microtektites, and glassy fallback particles indicate a soil contribution to the precursor materials of the tektites. A variable Ni/Co ratio seems to be characteristic of the fallback particles.

  1. High-resolution line-scan analysis of resin-embedded sediments using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS)

    NARCIS (Netherlands)

    Hennekam, Rick|info:eu-repo/dai/nl/357286081; Jilbert, Tom|info:eu-repo/dai/nl/304835714; Mason, Paul R D|info:eu-repo/dai/nl/304829331; de Lange, Gert J.|info:eu-repo/dai/nl/073930962; Reichart, Gert Jan|info:eu-repo/dai/nl/165599081

    2015-01-01

    Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) line-scanning is a promising technique for producing high-resolution (μm-scale) geochemical records on resin-embedded sediments. However, this approach has not yet been thoroughly tested on sediment samples of known elemental

  2. High-resolution line-scan analysis of resin-embedded sediments using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS)

    NARCIS (Netherlands)

    Hennekam, R.; Jilbert, T.; de Lange, G.J.; Reichart, G.J.

    2015-01-01

    Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) line-scanning is a promising technique for producing high-resolution (µm-scale) geochemical records on resin-embedded sediments. However, this approach has not yet been thoroughly tested on sediment samples of known elemental

  3. The influence of ns- and fs-LA plume local conditions on the performance of a combined LIBS/LA-ICP-MS sensor

    Energy Technology Data Exchange (ETDEWEB)

    LaHaye, Nicole L.; Phillips, Mark C.; Duffin, Andrew M.; Eiden, Gregory C.; Harilal, Sivanandan S.

    2016-01-01

    Both laser-induced breakdown spectroscopy (LIBS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) are well-established analytical techniques with their own unique advantages and disadvantages. The combination of the two analytical methods is a very promising way to overcome the challenges faced by each method individually. We made a comprehensive comparison of local plasma conditions between nanosecond (ns) and femtosecond (fs) laser ablation (LA) sources in a combined LIBS and LA-ICP-MS system. The optical emission spectra and ICP-MS signal were recorded simultaneously for both ns- and fs-LA and figures of merit of the system were analyzed. Characterization of the plasma was conducted by evaluating temperature and density of the plume under various irradiation conditions using optical emission spectroscopy, and correlations to ns- and fs-LIBS and LA-ICP-MS signal were made. The present study is very useful for providing conditions for a multimodal system as well as giving insight into how laser ablation plume parameters are related to LA-ICP-MS and LIBS results for both ns- and fs-LA.

  4. The tectonic evolution of the Irtysh tectonic belt: New zircon U-Pb ages of arc-related and collisional granitoids in the Kalaxiangar tectonic belt, NW China

    Science.gov (United States)

    Hong, Tao; Klemd, Reiner; Gao, Jun; Xiang, Peng; Xu, Xing-Wang; You, Jun; Wang, Xin-Shui; Wu, Chu; Li, Hao; Ke, Qiang

    2017-02-01

    Precise geochronological constraints of the Irtysh tectonic belt situated between the Saur Island Arc and the Altay Terrane are crucial to a better understanding of the tectonic evolution of the Central Asian Orogenic Belt (CAOB). Recently, we discovered repeatedly deformed arc-related and collisional granitoids in the Kalaxiangar tectonic belt (KTB), which is located in the eastern part of the Irtysh tectonic belt. In this study, we report new whole-rock geochemical, zircon U-Pb and Hf isotopic data of the arc-related and collisional granitoids. Our data reveal that 1) arc-related granodioritic porphyries formed at ca. 382-374 Ma. Recrystallized zircon grains from a (ultra-)mylonitic granodiorite of the Laoshankou zone in the southern KTB display a U-Pb age of ca. 360 Ma; 2) syn-collisional granodioritic porphyries, which distribute along faults and parallel to the cleavage, were emplaced at ca. 367-356 Ma, with εHf(t) values varying from + 7.8 to + 14.2 and Hf model ages from 873 to 459 Ma; 3) a post-collisional A-type granodioritic porphyry, which crosscuts the NW-NNW trending schistosity of the metasedimentary country rocks at a low angle, has an age of ca. 324-320 Ma, while the εHf(t) values range from + 7.6 to + 14.4 with Hf model ages from 850 to 416 Ma; 4) post-collisional strike-slip A-type granite dykes, exposed along strike-slip faults, gave ages between 287 and 279 Ma, whereas the εHf(t) values range from + 4.9 to + 12.7 and the Hf model ages from 995 to 500 Ma; and 5) A-type biotite granite dykes, which intruded along conjugate tension joints, have ages of 274-271 Ma, and εHf(t) values from + 1.5 to + 13.2 with Hf model ages from 1196 to 454 Ma. Consequently, we propose that the collision between the Saur Island Arc and the Altay Terrane occurred in the Early Carboniferous (ca. 367-356 Ma) and the subsequent post-collisional tectonic process continued to the Late Carboniferous (ca. 324-320 Ma). It is further suggested that the Irtysh tectonic belt

  5. Metamorphic evolution and U-Pb zircon SHRIMP geochronology of the Belizário ultramafic amphibolite, Encantadas Complex, southernmost Brazil

    Directory of Open Access Journals (Sweden)

    Léo A. Hartmann

    2003-09-01

    Full Text Available The integrated investigation of metamorphism and zircon U-Pb SHRIMP geochronology of the Belizário ultramafic amphibolite from southernmost Brazil leads to a better understanding of the processes involved in the generation of the Encantadas Complex. Magmatic evidence of the magnesian basalt or pyroxenite protolith is only preserved in cores of zircon crystals, which are dated at 2257 ± 12 Ma. Amphibolite facies metamorphism M1 formed voluminous hornblende in the investigated rock possibly at 1989 ± 21 Ma. This ultramafic rock was re-metamorphosed at 702±21 Ma during a greenschist facies eventM2; the assemblage actinolite + oligoclase + microcline + epidote + titanite + monazite formed by alteration of hornblende. The metamorphic events are probably related to the Encantadas Orogeny (2257±12 Ma and Camboriú Orogeny (~ 1989 Ma of the Trans-Amazonian Cycle, followed by an orogenic event (702±21 Ma of the Brasiliano Cycle. The intervening cratonic period (2000-700 Ma corresponds to the existence of the Supercontinent Atlantica, known regionally as the Rio de la Plata Craton.O entendimento dos processos evolutivos do Complexo Encantadas no sul do Brasil foi aperfeiçoado através do estudo integrado do metamorfismo de um anfibolito ultramáfico e da geocronologia U-Pb SHRIMP de zircão. Os núcleos herdados de alguns cristais de zircão tem idades em torno de 2257 ±12 Ma e constituem a única evidência preservada do protólito ígneo, que pode ter sido um basalto magnesiano ou um piroxenito. O metamorfismo M de fácies anfibolito formou abundante hornblenda na amostra investigada, possivelmente há 1989 ±21 Ma. Esta rocha ultramáfica foi re-metamorfizada talvez há cerca de 702 ±21 Ma durante um evento M de fácies xistos verdes do metamorfismo regional. Durante o evento M, a hornblenda foi recristalizada e formou a assembléia actinolita + oligoclásio + microclínio + epidoto + titanita + monazita. Estes eventos foram a manifesta

  6. Timing of K-alkaline magmatism in the Balkan segment of southeast European Variscan edifice: ID-TIMS and LA-ICP-MS study

    Science.gov (United States)

    Dyulgerov, Momchil; Ovtcharova-Schaltegger, Maria; Ulianov, Alexey; Schaltegger, Urs

    2017-08-01

    The Variscan orogen in southeast Europe is exposed in isolated remnants, affected by a subsequent Alpine tectono-magmatic overprint. Unlike the central European Variscides, in SE Europe the juxtaposition and correlation of the events and products are impeded by the scarcity of Variscan domains with preserved magmatic, metamorphic, sedimentological and structural characteristics. To reveal the particular evolution of the Variscan orogen in Balkan Mts, we present the results of ID-TIMS and LA-ICP-MS dating of three potassic-alkaline intrusions: Svidnya, Buhovo-Seslavtsi and Shipka. The age determinations from the plutons do not permit to establish their unequivocal ages, but they bracket the time interval of emplacements. Based on geochronological, tectonic and stratigraphic evidence the emplacement interval for plutons could be: 317-310 Ma for Svidnya, 330-310 Ma for Buhovo-Seslavtsi and 320-303 Ma for Shipka. These results show that the generation of potassic-alkaline magmas was post-Visean and is contemporaneous with the adjacent numerous calc-alkaline granitoid plutons. Thus, the Variscan orogen in the Balkan Mts is not characterized by a time-dependent geochemical evolution of magma generation. Hence, the observed differences in the rocks' compositions can be interpreted solely by distinction between the magma sources. The available data for both potassic-alkaline and calc-alkaline rocks indicate that the major episodes of crustal stacking and shearing in the Balkan part of the Variscan edifice are pre-Visean ( 330 Ma). The present study reveals that the potassic-alkaline rocks from the Balkan Mts are younger than the central European potassic granitoids (durbachites). It suggests that melting of enriched mantle source took place at different times throughout the Variscan orogen. In spite of the alkaline character of the magmas, the studied zircons show a complex nature, with inherited cores and magmatic overgrowths. The observed heterogeneities in the zircons

  7. Zircon Trace Element Contents and Refined U-Pb Crystallization Ages for the Tatoosh Pluton, Mount Rainier National Park, Washington Cascades

    Science.gov (United States)

    Bacon, C. R.; Du Bray, E. A.; John, D. A.; Mazdab, F. K.; Wooden, J. L.

    2008-12-01

    The 7x12 km Tatoosh pluton south of Mount Rainier consists of 4 petrographic/compositional phases, here termed Nisqually, Reflection, Pyramid, and Stevens, that intrude Tertiary volcanic and sedimentary wall and roof rocks; contacts between the 4 intrusive units are rarely exposed. We used the USGS-Stanford SHRIMP- RG to analyze, in a continuous session, zircons from each of 6 quartz monzodiorite (qmd), quartz monzonite (qm), or granodiorite (grd) samples for 206Pb/238U ages and, concurrently, U, Th, Hf, and REE concentrations. A round-robin procedure yielded statistically robust geochronological results. Ages that we reported previously (FM07) were compromised by instrument instability and by calibration differences between analytical sessions. Between 11 and 31 new analyses of zircons from each sample were evaluated using the TuffZirc and Umix Ages routines of Isoplot 3.41 (Ludwig, 2003). TuffZirc solidification ages for the intrusions are: Nisqually grd (Paradise Valley; 65.4% SiO2) 17.29 +0.37/-0.24 Ma, Nisqually grd (Christine Falls; 66.4%) 17.70 +0.30/-0.16 Ma, Reflection qm (Pinnacle Peak trail; 66.6%) 18.38 +0.45/-0.28 Ma, Pyramid qmd (58.5%) 18.58 +0.20/-0.15 Ma, Stevens grd (Stevens Canyon; 67.8%) 19.15 +0.15/-0.12 Ma, and Stevens grd (south of Louise Lake; 69.3%) 19.20 +0.31/-0.26 Ma (U-Th initial-disequilibrium corrected, ±2σ). Precision of the U-Pb data limits rigorous identification of antecrysts to those with ages ~1 Myr > solidification ages. Antecryst ages that produce subsidiary modes in relative probability diagrams for the two Stevens samples give weighted mean values of 20.18 ±0.26 Ma and 20.07 ±0.18 Ma. Wide ranges in trace element concentrations and ratios indicate that many analyzed zircons grew in highly fractionated residual liquids in high-crystallinity environments. Concentrations of Th and U in Tatoosh zircons vary by two orders of magnitude, cores tend to have higher Th, U, and Th/U than rims, and overgrowths that fill reentrants

  8. Mineral inclusions and SHRIMP U-Pb dating of zircons from the Alamas nephrite and granodiorite: Implications for the genesis of a magnesian skarn deposit

    Science.gov (United States)

    Liu, Yan; Zhang, Rongqing; Zhang, Zhiyu; Shi, Guanghai; Zhang, Qichao; Abuduwayiti, Maituohuti; Liu, Jianhui

    2015-01-01

    Extending approximately 1300 km and located in the Western Kunlun Mountains, the Hetian nephrite belt is the largest nephrite belt in the world and contains approximately 11 major deposits and more than 20 orebodies including the Alamas deposit. Hetian nephrite deposits can be classified as Mg-skarn deposits with Precambrian dolomitic marble host rock and green, green-white and white nephrite zones are distributed gradually in the zone of a granodiorite pluton. The green nephrite is mainly predominately composed of tremolite with generally minor to trace constituents of diopside, grossularitic garnet, actinolite and other minerals. Also green nephrite has higher content of TFe2O3, than green-white and white nephrites have. We subdivided the zircons from the green nephrites into four types, depending on their internal textures, mineral inclusions, and SHRIMP U-Pb ages. Type I zircons are round instead of idiomorphic in shape and lack obvious zoning. Type II and IV zircons have broad, clear oscillatory zoning and are hypidiomorphic or idiomorphic in shape; they contain inclusions of diopside, tremolite, chlorite and calcite. Most Type III zircons are narrow rims (nephrite deposit. The partially recrystallization of zircons during skarn formation possibly lead to some younger individual ages (406.5 to 308 Ma). In the Western Kunlun Mountain, both Buya granite and Alamas grandiorite are high Ba-Sr granites and crystallized in Western Kunlun Orogen. The Buya granite formed at about 430 Ma in a post-orogenic tectonic environment. Considering Alamas granodiorite formed at about 12 Ma younger than that of Buya granite and it is convincible that Alamas granodiorite also formed at a post-orogenic tectonic environment. Together with the evolution of Western Kunlun Mountain, it is also possible that high Ba-Sr Alamas granodiorite and the nephrite deposit formed in the post-orogenic stage. Most zircons in the Alamas granodiorite and green nephrite have high Th/U ratios (> 0

  9. Imaging of metals, metalloids, and non-metals by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) in biological tissues.

    Science.gov (United States)

    Becker, J Sabine; Becker, J Susanne

    2010-01-01

    The determination of the localization and distribution of essential and beneficial metals (e.g., Cu, Fe, Zn, Mn, Co, Ti, Al, Ca, K, Na, Cr and others), toxic metals (like Cd, Pb, Hg, U), metalloids (e.g., As, Se, Sb), and non-metals (such as C, S, P, Cl, I) in biological tissues is a challenging task for life science studies. Over the past few years, the development and application of mass spectrometric imaging (MSI) techniques for elements has been rapidly growing in the life sciences in order to investigate the uptake and the transport of both essential and toxic metals in plant and animal sections. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is a very sensitive and efficient trace, surface, and isotopic analytical technique for biological samples. LA-ICP-MS is increasingly utilized as an elemental mass spectrometric technique using double-focusing sector field (LA-ICP-SFMS) or quadrupole mass spectrometers (LA-ICP-QMS) to produce images of detailed regionally specific element distributions in thin biological tissue sections. Nowadays, MSI studies focus on brain research for studying neurodegenerative diseases such as Alzheimer's or Parkinson's, stroke, or tumor growth, or for the imaging of cancer biomarkers in tissue sections.The combination of the mass spectrometry imaging of metals by LA-ICP-MS with proteomics using biomolecular mass spectrometry (such as MALDI-MS or ESI-MS) to identify metal-containing proteins has become an important strategy in the life sciences. Besides the quantitative imaging of metals, non-metals and metalloids in biological tissues, LA-ICP-MS has been utilized for imaging metal-containing proteins in a 2D gel after electrophoretic separation of proteins. Recent progress in applying LA-ICP-MS in life science studies will be reviewed including the imaging of thin slices of biological tissue and applications in proteome analysis in combination with MALDI/ESI-MS to analyze metal-containing proteins.

  10. SHRIMP-RG U-Pb zircon geochronology of mesoproterozoic metamorphism and plutonism in the southwesternmost United States

    Science.gov (United States)

    Barth, Andrew P.; Wooden, Joseph L.; Coleman, Drew S.

    2001-01-01

    Mesoproterozoic intrusive and granulite‐grade metamorphic rocks in southern California have been inferred to be exotic to North America on the basis of perceived chronologic incompatibility with autochthonous cratonal rocks. Ion microprobe geochronology indicates that zircons in granulite‐grade gneisses, dated at 1.4 Ga using conventional methods, are composed of 1.68–1.80‐Ga cores and 1.19‐Ga rims. These Early Proterozoic gneisses were metamorphosed at extremely high temperatures and moderate pressures during emplacement of the 1.19‐Ga San Gabriel anorthosite complex. The lack of a 1.4‐Ga metamorphic event suggests that Proterozoic rocks in this region, rather than being exotic to North America, may in fact be a midcrustal window into Mesoproterozoic crustal evolutionary processes in southwestern North America.

  11. Petrogenesis of Jurassic fractionated I-type granites in Southeast China: Constraints from whole-rock geochemical and zircon U-Pb and Hf-O isotopes

    Science.gov (United States)

    Zhang, Yang; Yang, Jin-Hui; Sun, Jin-Feng; Zhang, Ji-Heng; Chen, Jing-Yuan; Li, Xian-Hua

    2015-11-01

    Whole-rock geochemical and Sr-Nd-Hf isotopic data and zircon in situ U-Pb ages and Hf-O isotopes are reported for twelve granitic intrusions from inland to coastal areas of the Cathaysia Block, Southeast (SE) China, in order to constrain their magma sources and petrogenesis. They are mainly composed of biotite granites with minor granodiorites. Zircon U-Pb dating by LA-ICPMS and SIMS methods gave emplacement ages of 165-154 Ma for these rocks, which are metaluminous to weakly peraluminous (A/CNK = 0.95-1.10), with variable SiO2 contents and high K2O contents. They are all depleted in high field strength elements (HFSEs) and enriched in light rare earth elements (LREEs) and large ion lithophile elements (LILEs), and show negative Sr, Ba and Eu anomalies in the spidergrams. Petrographic and geochemical features suggest the granodiorites that contain hornblende to be typical of I-type, while the biotite granites without hornblende are fractionated I-type granites. Their variable major and trace element concentrations are due to fractional crystallization of feldspar, biotite, hornblende, and accessory minerals, including apatite, allanite and monazite. Moreover, our data indicate significant variations in isotopic compositions of these granitoids from inland to coastal areas. The inland granites, from the Lapu, Fogang, Xinfengjiang and Baishigang plutons, have relatively high initial 87Sr/86Sr ratios (0.7105-0.7155) and low εNd(t) (-11.2 to -7.3) and εHf(t) (-10.9 to -6.3) values for whole rocks, and variable δ18O values of 7.69-9.25‰ and εHf(t) values of -13.5 to -6.7 for zircons. In contrast, the coastal granites, from the Longwo, Wushikeng, Lianhuashan, Shigushan, Chiliao, Hulutian, Mantoushan and Fenghuang plutons, show relatively low initial 87Sr/86Sr ratios (0.7056-0.7110) and high εNd(t) (-7.6 to -6.2) and εHf(t) (-6.5 to -2.8) values for whole-rocks, together with εHf(t) values of -7.2 to 3.9 and δ18O values of 6.69-8.38‰ for zircons. The spatial

  12. Zircon U-Pb geochronology, Sr-Nd-Hf isotopic composition and geological significance of the Late Triassic Baijiazhuang and Lvjing granitic plutons in West Qinling Orogen

    Science.gov (United States)

    Duan, Meng; Niu, Yaoling; Kong, Juanjuan; Sun, Pu; Hu, Yan; Zhang, Yu; Chen, Shuo; Li, Jiyong

    2016-09-01

    The Qinling Orogen was a consequence of continental collision of the South China Craton with the North China Craton in the Triassic and caused widespread granitoid magmatism. However, the petrogenesis of these granitoids remains controversial. In this paper, we choose the Baijiazhuang (BJZ) and Lvjing (LJ) plutons in the West Qinling Orogen for a combined study of the zircon U-Pb geochronology, whole-rock major and trace element compositions and Sr-Nd-Hf isotopic characteristics. We obtained zircon crystallization ages of 216 Ma and 212 Ma for the BJZ and the LJ plutons, respectively. The granitoid samples from both plutons have high K2O metaluminous to peraluminous compositions. They are enriched in large ion lithophile elements (LILEs), light rare earth elements (LREEs) and depleted in high field-strength elements (HFSEs) with significant negative Eu anomalies. The BJZ samples have initial Sr isotopic ratios of 0.7032 to 0.7078, εNd(t) of - 10.99 to - 8.54 and εHf (t) of - 10.22 to - 6.41. The LJ granitoids have initial Sr isotopic ratios of 0.7070 to 0.7080, εNd(t) of - 5.37 to - 4.58 and εHf(t) of - 3.64 to - 1.78. The enriched isotopic characteristics of the two plutons are consistent with their source being dominated by ancient continental crust. However, two BJZ samples show depleted Sr isotope compositions, which may infer possible involvement of mantle materials. Mantle-derived melt, which formed from partial melting of mantle wedge peridotite facilitated by dehydration of the subducted/subducting Mianlue ocean crust, provide the required heat for the crustal melting while also contributing to the compositions of these granitoids. That is, the two granitic plutons are magmatic responses to the closure of the Mianlue ocean basin and the continental collision between the Yangtze and South Qinling crustal terranes.

  13. New material of microfossils from the Ediacaran Doushantuo Formation in the Zhangcunping area,Yichang, Hubei Province and its zircon SHRIMP U-Pb age

    Institute of Scientific and Technical Information of China (English)

    LIU PengJu; YIN ChongYu; GAO LinZhi; TANG Feng; CHEN ShouMing

    2009-01-01

    The Zhangcunping area is located at the north limb of the Huangling anticline in Yichang, Hubei Province. Here, the sedimentary succession of the Ediacaran Doushantuo Formation is similar with that in the Weng'an area, Guizhou Province. A large number of new microfossils (mainly acanthoacritarchs) from the Doushantuo Formation in this area are reported in this paper. The fossil assemblage shows similarity as the phosphatized biota of the Doushantuo Formation at Wang'an, Guizhou Province and the silicified biota of the Doushantuo Formation at the Yangtze Gorges, which suggests that the Zhangcunping area is a key for correlation of the Doushantuo Formation between the Weng'an area,Guizhou Province and the Yangtze Gorges. Besides, a new zircon SHRIMP U-Pb age (614.0±7.6 Ma) is first obtained from a horizon underneath the exposed surface in the middle of the Doushantuo Formation in the Zhangcunping area. This age not only provides a new datum for subdivision of the Ediacaran Doushantuo Formation, but also indicates that the age of the exposed surface in the middle of the Doushantuo Formation in the Yangtze Platform should be posterior to 614.0±7.6 Ma. Due to the horizon of the Weng'an biota situated above the exposed surface, the age of the Wang'an biota should be posterior to 614.0±7.6 Ma as well.

  14. LA-ICPMS Zircon U-Pb Dating in the Jurassic Daohugou Beds and Correlative Strata in Ningcheng of Inner Mongolia

    Institute of Scientific and Technical Information of China (English)

    LIU Yanxue; LIU Yongqing; ZHANG Hong

    2006-01-01

    LA-ICPMS Zircon U-Pb dating is applied to volcanic rocks overlying and underlying the Salamander-bearing bed in the Daohugou beds of Ningcheng in Inner Mongola and Reshuichang of Lingyuan and Mazhangzi of Jianping in western Liaoning. The results indicate that the youngest age of the rocks in Daohugou of Ningcheng is 158 Ma, and the oldest one is 164 Ma. Synthesized researches indicate that the salamander-bearing beds in Daohugou of Ningcheng, Reshuichang of Lingyuan and Mazhangzi of Jianping were developed in the same period. The Daohugou beds were formed in the geological age of 164-158 Ma of the middle-late Jurassic. Whilst, the Daohugou beds and its correlative strata should correspond to the Tiaojishan Formation (or Lanqi Formation) of the middle Jurassic in northern Hebei Province and western Liaoning Province, based on the disconformity between the Daohugou beds and its overlaying beds of the Tuchengzi Formation of Late Jurassic and the Jehol Beds of early Cretaceous, and the disconformity between the Daohugou Beds and its underlying Jiulongshan Formation, which is composed of conglomerate, sandstone, shale with coal and thin coal beds.

  15. SHRIMP zircon U-Pb dating from K-bentonite in the top of Ordovician of Wangjiawan Section, Yichang, Hubei,China

    Institute of Scientific and Technical Information of China (English)

    HU YanHua; ZHOU JiBin; SONG Biao; LI Wei; SUN WeiDong

    2008-01-01

    The Global boundary Stratotype Section and Point (GSSP) for the base of the Hirnantian Stage (the latest stage of the Ordovician System) is defined at a point 0.39m below the base of the Kuanyinchiao Bed in the Wangjiawan North Section, which is the upper most "golden spike" of the Ordovician.However, this "golden spike" is lack of reliable geochronology data. This article gives a sensitive high resolution ion microprobe (SHRIMPII) zircon U-Pb dating for a K-bentonite sample from the Kuanyinchiao Bed in the Wangjiawan North Section. The age of the K-bentonite sample is 443.2+1.6 Ma, that is to say, the isotopic age of the uppermost of Hirnantian Stage, the point of Ordovician-Silurian boundary,should be near to, but slightly younger than 443.2±1.6 Ma. This age is identical to the Ordovician-Silurian boundary age 443.7±1.5 Ma as declared by International Commission on Stratigraphy (ICS). So, this research provides some good geochronlogical data for the Hirnantian Stage and the Ordovician-Silurian boundary as well as the global correlation.

  16. Zircon SHRIMP U-Pb dating for the Cangshuipu volcanic rocks and its implications for the lower boundary age of the Nanhua strata in South China

    Institute of Scientific and Technical Information of China (English)

    WANG Jian; LI Xianhua; DUAN Taizhong; LIU Dunyi; SONG Biao; LI Zhongxiong; GAO Yonghua

    2003-01-01

    The continental volcanic rocks and volcaniclastic sedimentary conglomerates of the Cangshuipu Formation occur well in Yiyang of Hunan Province, consisting of a wedge-shaped succession of Neoproterozoic strata that overlie with high-angle unconformity the flysch turbidites of the Lengjiaxi Group in the Upper Mesoproterozoic Eonothem. SHRIMP zircon U-Pb dating gives a weighted mean age of 814 ( 12 Ma for the dacitic volcanic agglomerates from the lowest part of the volcanic rocks in the Cangshuipu Formation. This age is younger than previously reported values of 921-933 Ma for the volcanic rocks from the Cangshuipu Formation. Our new dating represents the lower boundary age of the Neoproterozoic System in the studied area. The younger age for the Cangshuipu volcanic rocks is supported by the following observations: (1) Lower Neoproterozoic strata (814-1000 Ma) are missing in the studied area; (2) the Nanhua rift system was initiated at about 820 Ma; and (3) an age of ~820 Ma may be taken as the lower boundary timing of the Nanhua System (even Neoproterozoic) in South China.

  17. Emplacement age for the mafic-ultramafic plutons in the northern Dabie Mts. (Hubei): Zircon U-Pb, Sm-Nd and 40Ar/39Ar dating

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The protoliths of mafic-ultramafic plutons in the northern Dabie Mts. (NDM) (Hubei) include pyroxenite and gabbro. The zircon U-Pb dating for a gabbro suggests that emplacement of mafic magma took place in the post-collisional setting at the age of 122.9(0.6 Ma. It is difficult to obtain a reliable Sm-Nd isochron age, due to disequilibrium of the Sm-Nd isotopic system. Two hornblende 40Ar/39Ar ages of 116.1(1.1 Ma and 106.6(0.8 Ma may record cooling of metamorphism in the mafic-ultramafic plutons in Hubei below 500(C. The hornblende 40Ar/39Ar ages for the mafic-ultramafic rocks in Hubei are evidently 15-25 Ma younger than those for the same rocks in Anhui, indicating that there is a diversity of the cooling rates for the mafic-ultramafic rocks in Hubei and Anhui. The difference in their cooling rates may be controlled by the north-dipping normal faults in the NDM. The intense metamorphism occurring in the mafic-ultramafic rocks in Hubei may result from the Yanshanian magmatic reheating and thermal fluid action induced by the Cretaceous migmatization. The geochemical similarity of these mafic-ultramafic rocks wherever in Hubei and Anhui may be attributed to the same tectonic setting via an identical genetic mechanism.

  18. Devonian alkaline magmatism in the northern North China Craton: Geochemistry, SHRIMP zircon U-Pb geochronology and Sr-Nd-Hf isotopes

    Directory of Open Access Journals (Sweden)

    Dingling Huang

    2017-01-01

    Full Text Available The Wulanhada pluton is among the rare suite of Devonian alkaline plutons occurring along the northern margin of the North China Craton (NCC. The intrusion is mainly composed of quartz-monzonite. Here we report zircon SHRIMP U-Pb data from this intrusion which shows emplacement age of ca. 381.5 Ma. The rock is metaluminous with high (Na2O + K2O values ranging from 8.46 to 9.66 wt.%. The REE patterns of the rocks do not show any Eu anomaly whereas the primitive-mantle-normalized spider diagram shows strong positive Sr and Ba anomalies. The Wulanhada rocks exhibit high initial values of (87Sr/86Srt = 0.70762–0.70809, low ɛNd(t = −12.76 to −12.15 values and negative values of ɛHf(t = −23.49 to −17.02 with small variations in (176Hf/177Hft (0.281873–0.282049. These geochemical features and quantitative isotopic modeling results suggest that the rocks might have been formed through the partial melting of Neoarchean basic rocks in the lower crust of the NCC. The Wulanhada rocks, together with the Devonian alkaline rocks and mafic-ultramafic complex from neighboring regions, constitute a post-collisional magmatic belt along the northern NCC.

  19. Petrogenesis and significance of the Hongshan syenitic pluton,South Taihang: zircon SHRIMP U-Pb age, chemical compositions and Sr-Nd isotopes

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The Hongshan syenitic pluton (South Taihang) is mainly made up of hornblende syenite and minor granite. SHRIMP zircon dating yields a U-Pb age of 135 ± 2.7 Ma for the emplacement of the pluton, while biotite Rb-Sr isotopic data give an isochron of 120.3 ± 2.4 Ma. Hongshan syenites show low silica, high alkalis and LILE such as Sr, and exhibit negligible Eu anomalies or slightly positive anomalies in the REE patterns. The syenites show quite enriched isotopic compositions with Isr from 0. 7052 to 0. 7102 and εNd( t ) from - 7.5 to - 11. 1. Petrogenesis of the pluton can be that partial melting of an enriched lithospheric mantle gave birth to an alkali basaltic magma, which subsequently underplated in the lower crust and experienced a coupled fractionation of ferromagnesian phases like pyroxene and hornblende and minor ( < 10 % ) contamination of lower continental crust, producing the Hongshan syenites that partially evolved into granite through combined fractionation of hornblende and feldspar. Our data are not in agreement with a previous model that the syenites originated from melting of lower crust in a thickened crust circumstance, and thus do not support the speculation of "East China Plateau" in the Mesozoic.

  20. LA-ICPMS Zircon U-Pb Dating for Three Indosinian Granitic Plutons from Central Hunan and Western Guangdong Provinces and Its Petrogenetic Implications

    Institute of Scientific and Technical Information of China (English)

    PENG Bingxia; WANG Yuejun; FAN Weiming; PENG Touping; LIANG Xinquan

    2006-01-01

    The LA-ICPMS zircon U-Pb geochronology of three typically Indosinian granitic plutons yielded weighted mean 206Pb/238U ages of 214.1±5.9 Ma and 210.3±4.7 Ma for the biotite monzonitic granites from the Xiema and Xiangzikou plutons in Hunan Province, and 205.3±1.6 Ma for biotite granite from the Napeng pluton, western Guandong Province, respectively, showing a similar late Indosinian age of crystallization. In combination with other geochronological data from Indosinian granites within the South China Block (SCB), it is proposed that those late Indosinian granites with an age of ~210 Ma and the early Indosinian granites (230-245 Ma) have the similar petrogenesis in identical tectonic setting. The Indosinian granites within the SCB might be the products of anatexis of the thickening crust in a compressive regime. These data provide a further understanding for the temporal and spatial distribution of the Indosinian granites and the dynamic evolution of the SCB.

  1. SHRIMP U-Pb zircon dating for lamprophyre from Liaodong Peninsula: Constraints on the initial time of Mesozoic lithosphere thinning beneath eastern China

    Institute of Scientific and Technical Information of China (English)

    JIANG Yaohui; JIANG Shaoyong; ZHAO Kuidong; NI Pei; LING Hongfei; LIU Dunyi

    2005-01-01

    It is undebated fact that the lithospheric mantle beneath eastern China was considerably thinned during the Mesozoic time. However, it has no adequate evidence for the exact timing when the lithosphere thinning started. The Liaodong Peninsula is located in the eastern segment of the North China Craton and is one of the important domains to explore the event of lithosphere thinning. SHRIMP U-Pb zircon dating and geochemical study were carried out for the lamprophyre dike swarm that intruded into the magnesite ore-beds in the Dashiqiao Formation of Paleoproterozoic Liaohe Group at the Huaziyu magnesite ore district, Liaodong Peninsula. The results indicate that these lamprophyre dikes were intruded in late Jurassic (155±4 Ma) and show some geochemical characteristics of potassic magmas. It is now accepted that the lithosphere thinning took place in the late Mesozoic, and the peak thinning stage occurred in early Cretaceous (130―120 Ma). Considering the potassic mafic magmatism marking the onset of the lithospheric thinning, we therefore suggest that the studied late Jurassic potassic lamprophyre dike swarm could imply that the late Jurassic is the time that lithosphere thinning started.

  2. High-precision U-Pb zircon age from the Anfiteatro de Ticó Formation: Implications for the timing of the early angiosperm diversification in Patagonia

    Science.gov (United States)

    Perez Loinaze, Valeria S.; Vera, Ezequiel I.; Passalia, Mauro G.; Llorens, Magdalena; Friedman, Richard; Limarino, Carlos O.; Césari, Silvia N.

    2013-12-01

    The Baqueró Group is one of the most relevant units regarding the study of the early diversification of angiosperms in South America. Whereas the age of the upper part of the Group, namely the Punta del Barco Formation, has been recently dated at 114.67 ± 0.18 Ma, the rest of the unit still lacks precise dating. In this contribution a CA-TIMS U-Pb zircon age of 118.23 ± 0.09 Ma for a tuff interlayered with fossiliferous rocks of the Anfiteatro de Ticó Formation (lower part of the Baqueró Group) is reported. This age constrains the duration of deposition of the Baqueró Group to approximately 4 Ma and provides new evidence for the age interpretation of the previously described angiosperm flora and associated pollen assemblages from this unit, until now interpreted as early Aptian or possibly Barremian in age. The Aptian age of the Baqueró Group allows a better comparison between the paleofloras from this southernmost region.

  3. Triassic U-Pb age for zircon from granites in the Tonghua area and its response to the Dabie-Sulu ultrahigh-pressure collisional orogenesis

    Institute of Scientific and Technical Information of China (English)

    LU Xiaoping; WU Fuyuan; ZHAO Chengbi; ZHANG Yanbin

    2003-01-01

    Single-grain zircon U-Pb dating was carried out to constrain the emplacement timing of granitic plutons at Chaxinzi, Xiaoweishahe and Longtou in the Tonghua area, south of Jilin Province. The results show that these plutons formed in the Triassic with ages of 203-217 Ma. Geological and geochemical characteristics indicate that the plutons are composed of quartz diorite and granite. The former was derived from partial melting of mafic lower crust, whereas the latter originated from thickened crust with garnet as the residue in the source. It appears that protoliths of these two types of granitits are different although they have the same emplacement age. Considering that these plutons are petrologically different from the coeval granites in the Xingmeng (Xing'an-Mongolian) to Jihei (Jilin-Heilongjiang) orogenic belt in the north, it is suggested that their formation was related to the Dabie-Sulu ultrahigh-pressure collisional orogenesis since their ages are only 10-20 Ma younger than timing of the ultrahigh-pressure metamorphism, but comparable to that of the first rapid exhumation of the ultrahigh-pressure metamorphic rocks and the emplacement of the post-collisional granites.

  4. Geochemical characteristics and zircon U-Pb isotopic ages of island-arc basic igneous complexes from the Tianshui area in West Qinling

    Institute of Scientific and Technical Information of China (English)

    PEI Xianzhi; LI Zuochen; LIU Huibin; LI Gaoyang; DING Saping; LI Yong; HU Bo; GUO Junfeng

    2007-01-01

    The Liushuigou intermediate-basic meta-igneous complex at Guanzizhen, Tianshui area, is mainly composed of metagabbro, metagabbro diorite and metadiorite, while the Baihua basic meta-igneous complex consists mainly of pyroxenite, gabbro (gabbro diorite), diorite and quartz diorite.They form a relatively complete comagmatic evolutionary series. The geochemical characteristics of intermediate-basic igneous rocks indicate that they belong to a tholeiite suite.Their chondrite-normalized REE patterns are nearly flat and are LREE-slightly enriched type, and their primitive mantle-normalized and MORB-normalized trace element spider-grams are generally similar; the LILEs Cs, Ba, Sr, Th and U are enriched, while Rb and K and the HFSEs Nb, P, Zr,Sm, Ti and Y are depleted. All these show comagmatic evolu-tionary and genetic characteristics. The tectonic environment discrimination by trace element reveals that these igneous complexes formed in an island-arc setting. The Thermal Ionization Mass Spectrometry (TIMS) single-grain zircon U-Pb age for the Liushuigou intermediate-basic meta-igneous rocks in the Guanzizhen area is (507.5 ± 3.0) Ma, represent-ing the age of these igneous complexes, which indicates that island-arc-type magmatite rocks in the northern zone of West Qinling are Late Cambrian and also reveals that the timing of subduction of the paleo-ocean basin represented by the Guanzizhen ophiolite and resulting island-arc-type magrnaticactivity are probably Late Cambrian to Early Ordovician.

  5. Geochemistry and zircon U-Pb geochronology of the rhyolitic tuff on Port Island, Hong Kong: Implications for early Cretaceous tectonic setting

    Directory of Open Access Journals (Sweden)

    Longlong Zhao

    2017-05-01

    Full Text Available Early Cretaceous rhyolitic tuffs, widely distributed on Port Island, provide insights into the volcanism and tectonic setting of Hong Kong. In this paper we present petrological, geochronological and geochemical data of the rhyolitic tuff to constrain the diagenesis age and petrogenesis of the rocks, tectonic setting and early Cretaceous volcanism of Hong Kong. The first geochronological data show that the zircons in the volcanic rocks have U-Pb age of 141.1–139.5 Ma, which reveals that the rhyolitic tuff on Port Island was formed in the early Cretaceous (K1. Geochemically, these acid rocks, which are enriched in large ion lithophile elements (LILEs and light rare earth elements (LREEs, and depleted in high field strength elements (HFSEs, belong to the high K calc-alkaline to shoshonite series with strongly-peraluminous characteristic. The geochemical analyses suggest that the volcanic rocks were derived from deep melting in the continental crust caused by basaltic magma underplating. Based on the geochemical analysis and previous studies, we concluded that the rhyolitic tuffs on Port Island were formed in a back-arc extension setting in response to the subduction of the Paleo-Pacific Plate beneath the Eurasian Plate.

  6. LA-ICP-MS trace element mapping: insights into the crystallisation history of a metamorphic garnet population

    Science.gov (United States)

    George, Freya; Gaidies, Fred

    2017-04-01

    In comparison to our understanding of major element zoning, relatively little is known about the incorporation of trace elements into metamorphic garnet. Given their extremely slow diffusivities and sensitivity to changing mineral assemblages, the analysis of the distribution of trace elements in garnet has the potential to yield a wealth of information pertaining to interfacial attachment mechanisms during garnet crystallisation, the mobility of trace elements in both garnet and the matrix, and trace element geochronology. Due to advances in the spatial resolution and analytical precision of modern microbeam techniques, small-scale trace element variations can increasingly be documented and used to inform models of metamorphic crystallisation. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) in particular, can be used to rapidly quantify a wide range of elemental masses as a series of laser rasters, producing large volumes of spatially constrained trace element data. In this study, we present LA-ICP-MS maps of trace element concentrations from numerous centrally-sectioned garnets representative of the crystal size-distribution of a single sample's population. The study sample originates from the garnet-grade Barrovian zone of the Lesser Himalayan Sequence in Sikkim, northeast India, and has been shown to have crystallised garnet within a single assemblage between 515 ˚C and 565˚C, with no evidence for accessory phase reaction over the duration of garnet growth. Previous models have indicated that the duration of garnet crystallisation was extremely rapid (documents the primary zonation generated during garnet growth. In spite of straightforward (i.e. concentrically-zoned) major element garnet zonation, trace elements maps are characterised by significant complexity and variability. Y and the heavy rare earth elements are strongly enriched in crystal cores, where there is overprinting of the observed internal fabric, and exhibit numerous

  7. U-Pb zircon and monazite geochronology of the Hercynian two-mica granite composite pluton of Cabeceiras de Basto (Northern Portugal); Geochronologie U-Pb sur zircon et monazite du massif composite de granite a deux micas hercynien de Cabeceiras de Basto (Nord-Portugal)

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, A.; Noronha, F. [Universidade do Porto (Portugal). Centro de Geologia; Leterrier, J. [Centre de Recherches Petrographiques et Geochimiques, 54 - Vandoeuvre-les-Nancy (France); Bertrand, J.M. [Universite de Savoie, 73 - Le-Bourget-du-Lac (France). Laboratoire de geodynamique des Chaines alpines

    1998-06-01

    The zircon and monazite U-Pb minimum age of the Hercynian peraluminous two-mica composite granite pluton of Cabeceiras de Basto (Northern Portugal) is 311 {+-} 1 Ma (2 {sigma}). This age, well constrained by a concordant monazite of 311{+-}4 Ma (2{sigma}), is in good agreement with the age suggested for the syn-kinematic, syn-D3, Iberian granites of the Hercynian orogeny (315-305; Pinto et al., 1987). The ({sup 87}Sr/{sup 86}Sr){sub i} and {xi}{sub Nd} isotopic ratios, calculated for 311 Ma, suggest that the three granite units which constitute the massif may derive from an heterogeneous crustal source dated (upper intercept of the discordance) around 1200 Ma. (authors) 21 refs.

  8. Zircon U/Pb Dating of Cretaceous Adakitic Volcanic Rocks in the Eastern Part of North Dabie Mountains

    Institute of Scientific and Technical Information of China (English)

    薛怀民; 董树文; 刘晓春

    2003-01-01

    Mesozoic volcanic rocks in the eastern part of the North Dabie Mountains are rich inNa ( Na2O=4.03%, Na2O/K2O = 1.31 ), Sr (865μg/g) and Ba ( 1361μg/g) , and high inSr/Y ratio (66.1) but low in Nb, Y and HREE. They have experienced strong fractionation ofREE [ (La/Yb)N = 26.6 ], and are similar to adakite in geochemical characteristics. The U-Pbdating of zircon from the volcanic rocks is ( 129.2 + 2.6) Ma, belonging to Early Cretaceous.These rocks are similar to the volcanic rocks of North Huaiyang not only in age and rare-earth el-ement and trace element geochemistry, but also in the formation temperature and pressure of theminerals. The results indicated that the delamination of mountain root and underplating of mafic-ultramafic magma had happened in the Dabie orogen before Early Cretaceous. Mesozoic mag-matism was intense in the North Dabie Mountains, including the intrusion of mafic-ultramaficmagma, uplifting of gneiss dome, explosion of volcanic rocks and intrusion of granitic magma.The Mesozoic volcanic rocks in the eastern part of the North Dabie Mountains may be one part ofthe Mesozoic volcano-intrusive complex belt of North Huaiyang. The existence of Mesozoic vol-canic remnant cap means the denudation of the Dabie orogenic belt was not very strong sinceEarly Cretaceous.

  9. Integrated U-Pb zircon and palynological/palaeofloristic age determinations of a Bashkirian palaeofjord fill, Quebrada Grande (Western Argentina)

    Science.gov (United States)

    Valdez Buso, Victoria; di Pasquo, Mercedes; Milana, Juan Pablo; Kneller, Benjamin; Fallgatter, Claus; Junior, Farid Chemale; Gomes Paim, Paulo Sérgio

    2017-01-01

    This work presents a new age framework for the main Bashkirian glacio-eustatic transgression in Argentina, including the first absolute age for the Jejenes Formation, San Juan Province, based on radiometric dating of a crystal-rich tuff, supported by palynological and palaeofloristic studies, and presented within a revised palaeogeographic setting. The Jejenes Formation represents the glacial to postglacial fill of the Quebrada Grande palaeofjord carved in the Eastern Precordillera. The succession has been subdivided into five stages, the youngest of which suggests a previously unrecognised glacial event for this locality. Six productive levels for palynology were found within proglacial strata, and in the base and top of the succeeding interglacial stage. Palynoassemblages are characterized by poorly preserved trilete spores and monosaccate pollen grains along with a large amount of terrestrial phytoclasts. Main species indicating the Raistrickia densa-Convolutispora muriornata SubZone (DMa SZ) are Vallatisporites ciliaris, Cristatisporites rollerii, C. stellatus, C. chacoparanensis, C. inconstans and monosaccates such as Circumplicatipollis plicatus. This DMa SZ is estimated as Serpukhovian/Bashkirian and characterizes the glacial-related Guandacol Formation and equivalents units of the western Paganzo Basin. A tuffaceous level in the proglacial unit, bearing platyspermic seeds, plant remains and palynomorphs, yielded first-cycle volcanic zircons that were analysed by SHRIMP. An absolute age of 321.3 ± 5.3 Ma confirms a Bashkirian age for the main postglacial transgression in the Paganzo Basin, and offers a novel calibration for the palynoassemblages of DMa SZ that occurs elsewhere in Western Argentina.

  10. LA-ICP-MS analysis of isolated phosphatic grains indicates selective rare earth element enrichment during reworking and transport processes

    Science.gov (United States)

    Auer, Gerald; Reuter, Markus; Hauzenberger, Christoph A.; Piller, Werner E.

    2016-04-01

    Rare earth elements (REE) are a commonly used proxy to reconstruct water chemistry and oxygen saturation during the formation history of authigenic and biogenic phosphates in marine environments. In the modern ocean REE exhibit a distinct pattern with enrichment of heavy REE and strong depletion in Cerium. Studies of ancient phosphates and carbonates, however, showed that this 'modern' pattern is only rarely present in the geological past. Consequently, the wide range of REE enrichment patterns found in ancient marine phosphates lead to the proposition that water chemistry had to have been radically different in the earth's past. A wealth of studies has already shown that both early and late diagenesis can strongly affect REE signatures in phosphates and severely alter primary marine signals. However, no previous research was conducted on how alteration processes occurring prior to final deposition affect marine phosphates. Herein we present a dataset of multiple LA-ICP-MS measurements of REE signatures in isolated phosphate and carbonate grains deposited in a carbonate ramp setting in the central Mediterranean Sea during the middle Miocene "Monterey event". The phosphates are represented by authigenic, biogenic and detrital grains emplaced in bioclastic grain- to packstones dominated by bryozoan and echinoderm fragments, as well as abundant benthic and planktic foraminifers. The results of 39 grain specific LA-ICP-MS measurements in three discrete rock samples reveals four markedly different REE patterns (normalized to the Post Archean Australian Shale standard) in terms of total enrichment and pattern shape. Analyses of REE diagenesis proxies show that diagenetic alteration affected the samples only to a minor degree. Considering grain shape and REE patterns together indicate that authigenic, detrital and biogenic phosphates have distinct REE patterns irrespective of the sample. Our results show that the observed REE patterns in phosphates only broadly reflect

  11. Opening of the Tethys in southwest China and its significance to the breakup of East Gondwanaland in late Paleozoic: Evidence from SHRIMP U-Pb zircon analyses for the Garzê ophiolite block

    Institute of Scientific and Technical Information of China (English)

    YAN Quanren; WANG Jianguo; ZHANG Dehui; ZHAO Jian; WANG Zongqi; LIU Shuwen; LI Qiugen; ZHANG Hongyuan; WANG Tao; LIU Dunyi; SHI Yuruo; JIAN Ping

    2005-01-01

    SHRIMP U-Pb zircon analyses for a gabbro sample from the Garzê ophiolite block yielded a mean 206Pb/238U age of 292±4 Ma, which indicated that the spreading time of the Garzê-Litang Tethys was most likely at the earliest Permian. Combined with previous studies, we suggest that the opening of the Tethys in southwest China was derived from breakup of the East Gondwanaland in the late Paleozoic.

  12. Multiple provenance of rift sediments in the composite basin-mountain system: Constraints from detrital zircon U-Pb geochronology and heavy minerals of the early Eocene Jianghan Basin, central China

    Science.gov (United States)

    Wu, Lulu; Mei, Lianfu; Liu, Yunsheng; Luo, Jin; Min, Caizheng; Lu, Shengli; Li, Minghua; Guo, Libin

    2017-03-01

    Zircon U-Pb geochronology and heavy minerals are used in combination to provide valuable insights into the provenance of the early Eocene Jianghan Basin, central China. Five samples for zircon U-Pb dating and eighty-five samples for heavy mineral analysis were collected from drill cores or cuttings of the Xingouzui Formation. Most analyzed zircons are of magmatic origin, with oscillatory zoning. Detrital zircons from sample M96 located on eastern basin have two dominant age groups of 113-158 Ma and 400-500 Ma, and the other samples located on southern basin have three prominent age populations at 113-158 Ma, 400-500 Ma and 700-1000 Ma. Samples on different parts of the basin show distinct differences in heavy mineral compositions and they apparently divide into two groups according to the content of rutile (higher or lower than 4%). The spatial variations of zircon-tourmaline-rutile (ZTR) indices are marked by some noticeable increasing trends from basin margins to the inner part of the basin. Compared with the potential source areas, this study clarifies the multiple source characteristics of the Jianghan basin in the composite basin-mountain system. The majority of clastic material was supplied from the north source area through rift-trough sediment-transport pathways, and the eastern, southern and northwestern source areas also contributed detritus to the basin. This clastic material is broadly dispersed in the basin. The early Eocene paleogeography implies that rift architecture and rifting process had an important influence on sediment dispersal. This study shows that integrated zircon U-Pb geochronology and heavy mineral analysis is a useful and powerful method to identify sediment provenance.

  13. Mid-Neoproterozoic intraplate magmatism in the northern margin of the Southern Granulite Terrane, India: Constraints from geochemistry, zircon U-Pb geochronology and Lu-Hf isotopes

    Science.gov (United States)

    Deeju, T. R.; Santosh, M.; Yang, Qiong-Yan; Pradeepkumar, A. P.; Shaji, E.

    2016-11-01

    The northern margin of the Southern Granulite Terrane in India hosts a number of mafic, felsic and alkaline magmatic suites proximal to major shear/paleo-suture zones and mostly represents magmatism in rift-settings. Here we investigate a suite of gabbros and granite together with intermediate (dioritic) units generated through mixing and mingling of a bimodal magmatic suite. The massive gabbro exposures represent the cumulate fraction of a basic magma whereas the granitoids represent the product of crystallization in felsic magma chambers generated through crustal melting. Diorites and dioritic gabbros mostly occur as enclaves and lenses within host granitoids resembling mafic magmatic enclaves. Geochemistry of the felsic units shows volcanic arc granite and syn-collisional granite affinity. The gabbro samples show mixed E-MORB signature and the magma might have been generated in a rift setting. The trace and REE features of the rocks show variable features of subduction zone enrichment, crustal contamination and within plate enrichment, typical of intraplate magmatism involving the melting of source components derived from both depleted mantle sources and crustal components derived from older subduction events. The zircons in all the rock types show magmatic crystallization features and high Th/U values. Their U-Pb data are concordant with no major Pb loss. The gabbroic suite yields 206Pb/238U weighted mean ages in the range of 715 ± 4-832.5 ± 5 Ma marking a major phase of mid Neoproterozoic magmatism. The diorites crystallized during 206Pb/238U weighted mean age of 724 ± 6-830 ± 2 Ma. Zircons in the granite yield 206Pb/238U weighted mean age of 823 ± 4 Ma. The age data show broadly similar age ranges for the mafic, intermediate and felsic rocks and indicate a major phase of bi-modal magmatism during mid Neoproterozoic. The zircons studied show both positive and negative εHf(t) values for the gabbros (-6.4 to 12.4), and negative values for the diorites (-7

  14. Zircon U-Pb geochronology and geochemistry of low-grade metamorphosed volcanic rocks from the Dantazi Complex: Implications for the evolution of the North China Craton

    Science.gov (United States)

    Ge, Songsheng; Zhai, Mingguo; Li, Tiesheng; Peng, Peng; Santosh, M.; Shan, Houxiang; Zuo, Pengfei

    2015-11-01

    The late Neoarchean witnessed the cratonization of the North China Craton (NCC) through amalgamation of several micro-blocks to form a coherent basement. The Archean orthogneisses and supracrustal rocks in this craton have experienced various grades of metamorphism ranging up to upper amphibolite and granulite facies at ∼2500 Ma. Recently, a suite of low-grade metamorphosed (greenschist to lower amphibolite facies) volcanic rocks was discovered in the late Neoarchean Dantazi Complex in northern Hebei province. These meta-volcanic rocks consist of bimodal basalt-andesite and trachyte-dacite with a SiO2 gap between 54.4 wt.% and 60.7 wt.%. Here we report SHRIMP zircon U-Pb ages of 2490 ± 19 Ma (MSWD = 2.0) and 2502 ± 8 Ma (MSWD = 0.83) from the meta-mafic and meta-felsic volcanics, respectively, representing the timing of igneous activity. All the meta-mafic volcanic rocks display coherent trace element and REE patterns which are characterized by enriched LILE and LREE but depleted HFSE and HREE ((La/Yb)N = 6.29-15.10). Combining these trace element features with the positive zircon εHf(t) values (+1.3 to +6.6), we propose that the mafic rocks were likely derived from partial melting of a previously metasomatized lithospheric mantle. In the primitive mantle-normalized diagram, the felsic rocks display uniform patterns enriched in LILE but depleted in Nb and Ta, similar to those of lower crust. Furthermore, their strongly fractionated REE ((La/Yb)N = 15.24-61.20), lower HREE concentrations (Yb = 0.47-1.65 ppm) and positive zircon εHf(t) values (+1.6 to +5.3) suggest that they were derived from partial melting of the lower crust with garnet in the residue. This coeval occurrence of metasomatized mantle-derived mafic magmas and potassic felsic magmas from different source regions reflects an intracontinental extensional setting during the late Neoarchean to earliest Paleoproterozoic following the cratonization of the NCC. Our new data, combined with previous

  15. Geochemistry, mineralogy, and zircon U-Pb-Hf isotopes in peraluminous A-type granite xenoliths in Pliocene-Pleistocene basalts of northern Pannonian Basin (Slovakia)

    Science.gov (United States)

    Huraiová, Monika; Paquette, Jean-Louis; Konečný, Patrik; Gannoun, Abdel-Mouhcine; Hurai, Vratislav

    2017-08-01

    Anorogenic granite xenoliths occur in alkali basalts coeval with the Pliocene-Pleistocene continental rifting of the Pannonian Basin. Observed granite varieties include peraluminous, calcic to peralkalic, magnesian to ferroan types. Quartz and feldspars are dominant rock-forming minerals, accompanied by minor early ilmenite and late magnetite-ulvöspinel. Zircon and Nb-U-REE minerals (oxycalciopyrochlore, fergusonite, columbite) are locally abundant accessory phases in calc-alkalic types. Absence of OH-bearing Fe, Mg-silicates and presence of single homogeneous feldspars (plagioclase in calcic types, anorthoclase in calc-alkalic types, ferrian Na-sanidine to anorthoclase in alkalic types) indicate water-deficient, hypersolvus crystallization conditions. Variable volumes of interstitial glass, absence of exsolutions, and lacking deuteric hydrothermal alteration and/or metamorphic/metasomatic overprint are diagnostic of rapid quenching from hypersolidus temperatures. U-Pb zircon ages determined in calcic and calc-alkalic granite xenoliths correspond to a time interval between 5.7 and 5.2 Ma. Positive ɛHf values (14.2 ± 3.9) in zircons from a 5.2-Ma-old calc-alkalic granite xenolith indicate mantle-derived magmas largely unaffected by the assimilation of crustal material. This is in accordance with abundances of diagnostic trace elements (Rb, Y, Nb, Ta), indicating A1-type, OIB-like source magmas. Increased accumulations of Nb-U-REE minerals in these granites indicate higher degree of the magmatic differentiation reflected in Rb-enrichment, contrasting with Ba-enrichment in barren xenoliths. Incipient charnockitization, i.e. orthopyroxene and ilmenite crystallization from interstitial silicate melt, was observed in many granite xenoliths. Thermodynamic modeling using pseudosections showed that the orthopyroxene growth may have been triggered by water exsolution from the melt during ascent of xenoliths in basaltic magma. Euhedral-to-skeletal orthopyroxene growth

  16. High-precision U-Pb zircon geochronological constraints on the End-Triassic Mass Extinction, the late Triassic Astronomical Time Scale and geochemical evolution of CAMP magmatism

    Science.gov (United States)

    Blackburn, T. J.; Olsen, P. E.; Bowring, S. A.; McLean, N. M.; Kent, D. V.; Puffer, J. H.; McHone, G.; Rasbury, T.

    2012-12-01

    Mass extinction events that punctuate Earth's history have had a large influence on the evolution, diversity and composition of our planet's biosphere. The approximate temporal coincidence between the five major extinction events over the last 542 million years and the eruption of Large Igneous Provinces (LIPs) has led to the speculation that climate and environmental perturbations generated by the emplacement of a large volume of magma in a short period of time triggered each global biologic crisis. Establishing a causal link between extinction and the onset and tempo of LIP eruption has proved difficult because of the geographic separation between LIP volcanic deposits and stratigraphic sequences preserving evidence of the extinction. In most cases, the uncertainties on available radioisotopic dates used to correlate between geographically separated study areas often exceed the duration of both the extinction interval and LIP volcanism by an order of magnitude. The "end-Triassic extinction" (ETE) is one of the "big five" and is characterized by the disappearance of several terrestrial and marine species and dominance of Dinosaurs for the next 134 million years. Speculation on the cause has centered on massive climate perturbations thought to accompany the eruption of flood basalts related to the Central Atlantic Magmatic Province (CAMP), the most aerially extensive and volumetrically one of the largest LIPs on Earth. Despite an approximate temporal coincidence between extinction and volcanism, there lacks evidence placing the eruption of CAMP prior to or at the initiation of the extinction. Estimates of the timing and/or duration of CAMP volcanism provided by astrochronology and Ar-Ar geochronology differ by an order of magnitude, precluding high-precision tests of the relationship between LIP volcanism and the mass extinction, the causes of which are dependent upon the rate of magma eruption. Here we present high precision zircon U-Pb ID-TIMS geochronologic data

  17. U-Pb zircon and geochemical evidence for bimodal mid-Paleozoic magmatism and syngenetic base-metal mineralization in the Yukon-Tanana terrane, Alaska

    Science.gov (United States)

    Dusel-Bacon, C.; Wooden, J.L.; Hopkins, M.J.

    2004-01-01

    New SHRIMP (sensitive, high-resolution ion microprobe) U-Pb zircon ages and trace element geochemical data for mafic and felsic metaigneous rocks of the pericratonic Yukon-Tanana terrane in east-central Alaska help define the tectonic setting of mid-Paleozoic magmatism and syngenetic hydrothermal Zn-Pb-Ag mineralization along the ancient Pacific margin of North America. We compare data from similar greenschist-facies sequences of bimodal volcanic and subvolcanic rocks associated with carbonaceous and siliciclastic marine sedimentary rocks, in the Wood River area of the Alaska Range and the Salcha River area of the Yukon-Tanana Upland, and from amphibolite-facies augen gneiss and mafic gneiss (amphibolite) in the Goodpaster River area of the upland. Allowing for analytical uncertainties, igneous crystallization age ranges of 376-353 Ma, 378-346 Ma, and 374-358 Ma are indicated by 13 new SHRIMP U-Pb dates for the Wood River, Salcha River, and Goodpaster River areas, respectively. Bimodal magmatism is indicated by Late Devonian crystallization ages for both augen gneiss (371 ?? 3 and 362 ?? 4 Ma) and associated orthoamphibolite (369 ?? 3 Ma) in the upland and by stratigraphic interleaving of mafic and felsic rocks in the Alaska Range. Metabasites in all three study areas have elevated HFSE (high field strength element) and REE (rare earth element) contents indicative of generation in a within-plate (extensional) tectonic setting. Within-plate trace element signatures also are indicated for peralkaline metarhyolites that host the largest volcanogenic massive sulfide deposits of the Bonnifield district in the Wood River area and for metarhyolite tuff interlayered with the carbonaceous Nasina assemblage, which hosts sedimentary exhalative sulfide occurrences in the Salcha River area. Most of the other felsic metaigneous samples from the Alaska Range and the Yukon-Tanana Upland have geochemical signatures that are similar to those of both average upper continental crust

  18. U-Pb (LA-ICPMS) zircon ages and Nd isotopes for granitoids of the Tamboril-Santa Quiteria Complex, Ceara Central Domain: implication for neoproterozoic syncollisional magmatism in north Borborema Province, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Felipe Grandjean da; Araujo, Carlos Eduardo Ganade de; Vasconcelos, Antonio Maurilio, E-mail: felipe.costa@cprm.gov.br, E-mail: caegeo@gmail.com, E-mail: maurilio.vasconcelos@cprm.gov.br [Servico Geologico do Brasil (CPRM), Fortaleza, CE (Brazil); Amaral, Wagner da Silva, E-mail: wamaral@ufc.br [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Departamento de Geologia; Rodrigues, Joseneusa Brilhante, E-mail: joseneusa.rodrigues@cprm.gov.br [Servico Geologico do Brasil (CPRM), Brasilia, DF (Brazil)

    2013-06-15

    The Tamboril-Santa Quiteria Complex (TSQC) is one of the largest Neoproterozoic plutonic manifestations in the north Borborema Province (NE Brazil). It represents an anatectic/igneous association characterized by a number of magmatic pulses that occurred in the 650-610 Ma interval. In this paper, we present U-Pb (LA-MC-ICP-MS) zircon ages and Nd isotopes for quartz monzonite and quartz diorites of the southern part of TSQC. The quartz monzonite belong to a hybrid granitoid association, including monzonite, syenites and quartz syenites, all with abundant mafic magmatic enclaves. A quartz monzonite sample yielded a U-Pb zircon age of 634 {+-} 10 Ma and a TDM age of 2.69 Ga. The quartz diorites are much more homogeneous in composition and yielded a U-Pb zircon age of 618 {+-} 23 Ma and a TDM age of 2.19 Ga. The presence of coeval mantle-derived magmatism and diatexites (crustal anatexis) post-dating high-pressure metamorphism (ca. 650 Ma), and together with high-temperature metamorphism (ca. 630-610 Ma), suggests that this large magmatic manifestation evolved in a collisional setting, probably related to slab break off during the Western Gondwana amalgamation. (author)

  19. Parent zonation in thermochronometers - resolving complexity revealed by ID-TIMS U-Pb dates and implications for the application of decay-based thermochronometers

    Science.gov (United States)

    Navin Paul, Andre; Spikings, Richard; Chew, David; Daly, J. Stephen; Ulyanov, Alexey

    2017-04-01

    High temperature (>350℃) U-Pb thermochronometers primarily use accessory minerals such as apatite, titanite and rutile, and assume that daughter isotopes are lost by thermally activated volume diffusion while the parent remains immobile. Studies exploiting such behaviour have been successfully used to reconstruct thermal histories spanning several hundred million years (e.g. Cochrane et al., 2014). However, outliers in date (ID-TIMS) vs diffusion length space are frequently observed, and grains are frequently found to be either too young or too old for expected thermal history solutions using the diffusion data of Cherniak et al. (2010). These deviations of single grain apatite U-Pb dates from expected behaviour could be caused by a combination of i) metamorphic (over-)growth, ii) fluid-aided Pb mobilisation during alteration/recrystallization, iii) parent isotope zonation, iv) metamictisation, and v) changes in diffusion length with time (e.g. fracturing). We present a large data set from the northern Andes of South America, where we compare apatite U-Pb ID-TIMS-(TEA) data with LA-ICP-MS element maps and in-situ apatite U-Pb LA-(MC)-ICP-MS dates. These are combined with U-Pb zircon and 40Ar/39Ar (muscovite) data to attempt to distinguish between thermally activated volume diffusion and secondary overgrowth/recrystallization. We demonstrate that in young (e.g. Phanerozoic) apatites that have not recrystallized or experienced metasomatic overgrowths, U-Pb dates are dominantly controlled by volume diffusion and intra-crystal uranium zonation. This implies that ID-TIMS analyses of apatites with zoned parent isotope distributions will not usually recover accurate thermal history solutions, and an in-situ dating method is required. Recovering the uranium distribution during in-situ analysis provides a means to account for parent zonation, substantially increasing the accuracy of the modelled t-T-paths. We present in-situ data from apatites where scatter in date v

  20. Genesis of Augite-Bearing Ureilites: Evidence From LA-ICP-MS Analyses of Pyroxenes and Olivine

    Science.gov (United States)

    Herrin, J. S.; Lee, C-T. A.; Mittlefehldt, D. W.

    2008-01-01

    Ureilites are ultramafic achondrites composed primarily of coarse-grained low-Ca pyroxene and olivine with interstitial carbonaceous material, but a number of them contain augite [1]. Ureilites are considered to be restites after partial melting of a chondritic precursor, although at least some augite-bearing ureilites may be partially cumulate [1, 2]. In this scenario, the augite is a cumulus phase derived from a melt that infiltrated a restite composed of typical ureilite material (olivine+low-Ca pyroxene) [2]. To test this hypothesis, we examined the major and trace element compositions of silicate minerals in select augite-bearing ureilites with differing mg#. Polished thick sections of the augite-bearing ureilites ALH 84136 , EET 87511, EET 96293, LEW 88201, and META78008 and augite-free typical ureilite EET 90019 were examined by EPMA for major and minor elements and laser ablation ICP-MS (LA-ICP-MS) for trace elements, REE in particular. Although EET 87511 is reported to contain augite, the polished section that we obtained did not.

  1. Imaging Metals in Brain Tissue by Laser Ablation - Inductively Coupled Plasma - Mass Spectrometry (LA-ICP-MS).

    Science.gov (United States)

    Hare, Dominic J; Kysenius, Kai; Paul, Bence; Knauer, Beate; Hutchinson, Robert W; O'Connor, Ciaran; Fryer, Fred; Hennessey, Tom P; Bush, Ashley I; Crouch, Peter J; Doble, Philip A

    2017-01-22

    Metals are found ubiquitously throughout an organism, with their biological role dictated by both their chemical reactivity and abundance within a specific anatomical region. Within the brain, metals have a highly compartmentalized distribution, depending on the primary function they play within the central nervous system. Imaging the spatial distribution of metals has provided unique insight into the biochemical architecture of the brain, allowing direct correlation between neuroanatomical regions and their known function with regard to metal-dependent processes. In addition, several age-related neurological disorders feature disrupted metal homeostasis, which is often confined to small regions of the brain that are otherwise difficult to analyze. Here, we describe a comprehensive method for quantitatively imaging metals in the mouse brain, using laser ablation - inductively coupled plasma - mass spectrometry (LA-ICP-MS) and specially designed image processing software. Focusing on iron, copper and zinc, which are three of the most abundant and disease-relevant metals within the brain, we describe the essential steps in sample preparation, analysis, quantitative measurements and image processing to produce maps of metal distribution within the low micrometer resolution range. This technique, applicable to any cut tissue section, is capable of demonstrating the highly variable distribution of metals within an organ or system, and can be used to identify changes in metal homeostasis and absolute levels within fine anatomical structures.

  2. Diffusivities of Redox-Sensitive Elements in Basalt vs. Oxygen Fugacity Determined by LA-ICP-MS

    Science.gov (United States)

    Szumila, Ian; Danielson, Lisa; Trail, Dustin

    2017-01-01

    Several diffusion experiments were conducted in a piston cylinder device across a range of oxygen fugacities (FMQ-3 FMQ-1.2, FMQ+6) at 1 GPa and 1300 C. This was done to explore the effects of oxygen fugacity (fO2) on diffusivity of redox sensitive trace elements. This allows investigation of how these elements diffuse across the fO2 range encountered in different reservoirs on planets and moons in our solar system. The University of Rochester LA-ICP-MS system was used for analysis of samples. Analyses were conducted using an Agilent 7900 quadrupole mass spectrometer connected to a Photon Machines 193 nm G2 laser ablation (LA) system equipped with a HelEx 2-volume sample chamber. Spots used were 35 micrometers circles spaced at 65 micrometers intervals. Laser fluence was 7.81 J/cm^2 with a rep rate of 10 Hz. The iolite software package was used to reduce data collected from laser ablation analysis of experiments with Si-29 used as the internal standard isotope. Iolite's global fit module was used to simultaneously fit elements' diffusivities in each experiment while keeping the Matano interface constant. Elements analysed include V, Nb, W, Mo, La, Ce, Pr, Sm, Eu, Gd, Ta, and W. Figures

  3. An autochthonous Avalonian basement source for the latest Ordovician Brenton Pluton in the Meguma terrane of Nova Scotia: U-Pb-Hf isotopic constraints and paleogeographic implications

    Science.gov (United States)

    Duncan Keppie, J.; Gregory Shellnutt, J.; Dostal, Jaroslav; Fraser Keppie, D.

    2017-06-01

    The Ediacaran-Ordovician Meguma Supergroup was thrust over Avalonia basement prior to the intrusion of post-Acadian, ca. 370 Ma, S-type granitic batholiths. This has led to two main hypotheses regarding the original location of the Meguma terrane, a continental rise prism bordering either NW Africa or Avalonia. On the other hand, the pre-Acadian, ca. 440 Ma Brenton pluton has yielded the following U/Pb LA-ICP-MS zircon data: (1) 448 ± 3 Ma population peak inferred to be the intrusive age and (2) ca. 550 and 700 Ma inherited ages common to both Avalonia and NW Africa. In contrast, Hf isotopic analyses of zircon yielded model ages ranging from 814 to 1127 Ma with most between 940 and 1040 Ma: such ages are typical of Avalonia and not NW Africa. The ages of the inherited zircons found within the Brenton pluton suggest that it was probably derived by partial melting of sub-Meguma, mid-crustal Avalonian rocks, upon which the Meguma Supergroup was deposited. Although Avalonia is commonly included in the peri-Gondwanan terranes off NW Africa or Amazonia, paleomagnetic data, faunal provinciality, and Hf data suggest that, during the Ediacaran-Early Cambrian, it was an island chain lying near the tropics (ca. 20-30 °S) and was possibly a continuation of the Bolshezemel volcanic arc accreted to northern Baltica during the Ediacaran Timanide orogenesis. This is consistent with the similar derital zircon population in the Ediacaran-Cambrian Meguma Supergroup and the Dividal Group in northeastern Baltica.

  4. Initial subduction of the Paleo-Pacific Oceanic plate in NE China: Constraints from whole-rock geochemistry and zircon U-Pb and Lu-Hf isotopes of the Khanka Lake granitoids

    Science.gov (United States)

    Liu, Kai; Zhang, Jinjiang; Wilde, Simon A.; Zhou, Jianbo; Wang, Meng; Ge, Maohui; Wang, Jiamin; Ling, Yiyun

    2017-03-01

    Northeast China is located in the eastern part of the Central Asian Orogenic Belt (CAOB) and was influenced by Paleo-Pacific subduction during the Mesozoic. Abundant granitoids from the late Paleozoic to early Mesozoic in NE China record this process, including the Khanka Lake granitoids, which resulted in extensive growth of continental crust in the area. However, the question of how and when the Paleo-Pacific tectonic system began to affect NE China is still highly controversial. The Khanka Lake granitoids can be subdivided into two main components based on their geochemical characteristics, namely granodiorite and syenogranite. The granodiorite has a U-Pb age of 249 Ma and is adakite-like (enriched in LREE and LILEs with high Mg#, Sr, La/Yb, Sr/Y and Na2O/K2O), with zircon εHf(t) values of - 0.65 to 1.61, produced by the magma mixing between melting of the lower continental crust and juvenile basaltic magma. The syenogranite has zircon U-Pb ages of 209 to 199 Ma and geochemical features of highly fractionated I-type granites, with high SiO2, total alkalis and low Mg (and Mg#), Fe, Cr and Ni, and positive zircon εHf(t) of 1.72 to 5.12, indicating an origin from remelting of juvenile crust. The granitoids were intruded by felsic veins between 195 and 184 Ma with positive zircon εHf(t) from 0.57 to 5.32. The εHf(t) values of the granitoids become more positive as the zircon U-Pb ages become younger, suggesting continuous melting of juvenile crust during subduction. It is concluded that the Khanka Lake granitoids record the early stage of subduction of the Paleo-Pacific Oceanic plate, which commenced at least ca. 250 Ma ago.

  5. Age revision of the Neotethyan arc migration into the southeast Urumieh-Dokhtar belt of Iran: Geochemistry and U-Pb zircon geochronology

    Science.gov (United States)

    Hosseini, Mohammad Reza; Hassanzadeh, Jamshid; Alirezaei, Saeed; Sun, Weidong; Li, Cong-Ying

    2017-07-01

    The Urumieh-Dokhtar magmatic belt of Central Iran runs parallel to the Zagros orogenic belt and has been resulted from Neotethys ocean subduction underneath Eurasia. The Bahr Aseman volcanic-plutonic complex (BAC), covering an area 2000 km2 in the Kerman magmatic belt (KMB) in the southern section of the Urumieh-Dokhtar belt, has long been considered as the earliest manifestation of extensive Cenozoic arc magmatism in KMB. The nature and timing of the magmatism, however, is poorly constrained. An area 1000 km2, in BAC and adjacent Razak volcaniclastic complex and Jebal Barez-type granitoids, was mapped and sampled for geochemistry and geochronology. Andesite and basaltic andesite are the main volcanic components in the study area; plutonic bodies vary from tonalite to quartz diorite, granodiorite and biotite-granite. The rocks in BAC display dominantly normal calc-alkaline character. On spider diagrams, the rocks are characterized by enrichments in LILE relative to HFSE and enrichments in LREE relative to HREE. These features suggest a subduction related setting for the BAC. LaN/YbN ratios for the intrusive and volcanic rocks range from 1.41 to 5.16 and 1.01 to 6.42, respectively. These values are lower than those for other known granitoids in KMB, namely the abyssal, dominantly Oligocene Jebal Barez-type (LaN/YbN = 1.66-9.98), and the shallow, dominantly late Miocene Kuh Panj-type (LaN/YbN = 12.97-36.04) granitoids. This suggests a less evolved magma source for the BAC igneous rocks. In Y vs. Nb and Th/Yb vs. La/Yb discrimination diagrams, an island-arc setting is defined for the BAC rocks. The rocks further plot in primitive island-arc domain in Nb vs. Rb/Zr and Y/Nb vs. TiO2 diagrams. The BAC volcanic and plutonic rocks yielded zircon U-Pb ages of 78.1 to 82.7 Ma and 77.5 to 80.8 Ma, respectively. Zircon U-Pb dating of volcanic rocks and granitoids from the adjacent Razak complex and the Jebal Barez-type granitoids indicated 48.2 Ma and 26.1 Ma ages

  6. Tectonic evolution of the Irtysh collision belt: New zircon U-Pb ages of deformed and collisional granitoids in the Kalaxiangar area, NW China

    Science.gov (United States)

    Tao, Hong; Jun, Gao; Xingwang, Xu; Klemd, Reiner

    2016-04-01

    The CAOB is thought to have formed by multiple accretion and collision of various microcontinents, island arcs, oceanic plateaus and accretionary wedges due to the closure of the Paleo-Asia Ocean [1, 2, 3]. The Irtysh collision belt is located at the middle-western part of the CAOB and generally thought to be the result of the collision of the Sawuer Island arc and the Altay Terrane, subsequent to the consumption of the Early Paleozoic Junggar Ocean, a branch of Paleo-Asia Ocean. Therefore, the exact timing of the Irtysh collision belt is crucial for a better understanding of the tectonic evolution of this collision belt and will provide constraints on the evolution of the CAOB. Recently, we discovered various collisional granitoids in the Kalaxiangar tectonic belt (KTB), which is located in the eastern part of the Irtysh collision belt. In this contribution, we report new geochemical whole-rock, zircon U-Pb and Hf isotopic data of the arc-related and collisional granitoids. Our new results reveal that 1) the arc-related granodioritic porphyries formed at ca. 374 Ma. Furthermore, recrystallized zircons from the granodioritic mylonite and ultramylonite of the Laoshankou ductile deformation zone have a similar U-Pb age of ca. 360 Ma; 2) the syn-collisional granodioritic porphyries, which distribute along cleavege, were emplaced at ca. 355 Ma; 3) the post-collisional A-type granodioritic porphyry, which cuts the NW-NNW trending schistosity at a low angle, has an age of ca. 323 Ma, ɛHf(t) values from + 7.5 to + 14.4, and young Hf model ages between 387 and 658 Ma; 4) the post-collisional A-type granite dykes, which are exposed along strike-slip faults, have ages between 282.5 and 279.2Ma, ɛHf(t) values from + 4.8 to + 12.6, and Hf model ages between 436 and 729 Ma; 5) the A-type biotite granite dykes that intruded along conjugate tension joints have ages between 273.9 and 271.4 Ma, ɛHf(t) values from + 1.1 to + 12.8, and Hf model ages between 393 and 979 Ma. In

  7. Petrology and U-Pb zircon dating of intrusive rocks from A, C-south, and Dardvay districts, Sangan iron stone mine, Khaf

    Directory of Open Access Journals (Sweden)

    Abbas Golmohammadi

    2013-10-01

    Full Text Available Sangan magnetite skarn mine is located 300 km southeast of Mashhad, along the eastern part of Khaf-Drouneh volcanic-plutonic belt. Granitoids from three areas within the Sangan mine A, C-North and Dardvay were studied. Within the study area, three intrusive rocks including biotite-hornblende monzonite porphyry, biotite syenite and syenogranite were recognized. Based on field cross cutting, absence of garnet-magnetite skarn around the contact, and alteration by younger hydrothermal fluids, these granitoids are older than the magnetite skarn. U-Pb zircon age of the granitoid is 42 Ma (Middle Eocene. Magnetic susceptibility of the granitoids are 310-900 × 10-5 (SI units and therefore, they are classified as belonging to the magnetite-series (oxidant type I-type. Chemically, these granitoids are metaluminous, alkali-calcic to alkali and shoshonite to ultrapotassic. Enrichment of LREE, relative to HREE and enrichment of LILE (Sr, Cs, Rb, K and Ba relative to HFSE (Nb, Ta, Ti, Hf and Zr indicate that the magma formed in island arc setting. This magma originated from low partial melting (<1% of garnet-spinel lherzolite (low garnet and was contaminated in the continental crust. Based on the ratio of (La/YbN 6.23-34.73, indicate that small amount of garnet was left in the source rock. High ration of Rb/Sr, LILE/HFSE and high content of K2O, Th and Nb indicative of continental crust contamination. Petrognesis and geochronology of Sangan granitoid will help to know more about tectonomagmatic of Khaf-Kashmar-Drouneh volcanic-plutonic belt and their mineralization.

  8. Early Cretaceous U-Pb zircon ages for the Copiapó plutonic complex and implications for the IOCG mineralization at Candelaria, Atacama Region, Chile

    Science.gov (United States)

    Marschik, Robert; Söllner, Frank

    2006-12-01

    Four of the major plutons in the vicinity of the Candelaria mine (470 Mt at 0.95% Cu, 0.22 g/t Au, 3.1 g/t Ag) and a dike-sill system exposed in the Candelaria open pit have been dated with the U-Pb zircon method. The new geochronological data indicate that dacite magmatism around 123 Ma preceded the crystallization of hornblende diorite (Khd) at 118 ± 1 Ma, quartz-monzonite porphyry (Kqm) at 116.3 ± 0.4 Ma, monzodiorite (Kmd) at 115.5 ± 0.4 Ma, and tonalite (Kt) at 110.7 ± 0.4 Ma. The new ages of the plutons are consistent with field relationships regarding the relative timing of emplacement. Plutonism temporally overlaps with the iron oxide Cu-Au mineralization (Re-Os molybdenite ages at ˜115 Ma) and silicate alteration (ages mainly from 114 to 116 and 110 to 112 Ma) in the Candelaria-Punta del Cobre district. The dated dacite porphyry and hornblende diorite intrusions preceded the ore formation. A genetic link of the metallic mineralization with the quartz-monzonite porphyry and/or the monzodiorite is likely. Both of these metaluminous, shoshonitic (high-K) intrusions could have provided energy and contributed fluids, metals, and sulfur to the hydrothermal system that caused the iron oxide Cu-Au mineralization. The age of the tonalite at 110.7 Ma falls in the same range as the late alteration at 110 to 112 Ma. Tonalite emplacement may have sustained existing or driven newly developed hydrothermal cells that caused this late alteration or modified 40Ar/39Ar and K/Ar systematic in some areas.

  9. Zircon U-Pb dating of Maherabad porphyry copper-gold prospect area: evidence for a late Eocene porphyry-related metallogenic epoch in east of Iran

    Directory of Open Access Journals (Sweden)

    Azadeh Malekzadeh Shafaroudi

    2011-04-01

    Full Text Available Eastern Iran has great potential for porphyry copper deposits, as a result of its past subduction zone tectonic setting that lead to extensive alkaline to calc-alkaline magmatic activity in Tertiary time. Maherabad is the first porphyry Cu-Au prospecting area which is discovered in eastern Iran. This is related to a succession o f monzonitic to dioritic porphyries stocks that were emplaced within volcanic rocks. Monzonitic porphyries have basic role in mineralization. Hydrothermal alteration zones are well developed including potassic, sericitic-potassic, quartz-sericite-carbonate-pyrite, quartz-carbonate-pyrite, silicified-propylitic, propylitic, carbonate and silicified zones. Mineralization occurs as Disseminated, stockwork and hydrothermal breccia. Based on early stage of exploration, Cu is between 179- 6830 ppm (ave. 3200 ppm and Au is up to 1000 ppb (ave. 570 ppb. This prospect is gold- rich porphyry copper deposit. Laser-ablation U-Pb dating of two samples from ore-related intrusive rocks indicate that these two monzonitic porphyries crystallized at 39.0 ± 0.8 Ma to 38.2 ± 0.8 Ma, within a short time span of less than ca. 1 Ma during the middle Eocene. This provides the first precise ages for metallogenic episode of porphyry-type mineralization. Also, the initial 87Sr/86Sr and (143Nd/144Ndi was recalculated to an age of 39 Ma. Initial 87Sr/86Sr ratios for monzonitic rocks are 0.7047-0.7048. The (143Nd/144Ndi isotope composition are 0