WorldWideScience

Sample records for isotopically engineered si

  1. Si Isotopes of Brownleeite

    Science.gov (United States)

    Nakamura-Messenger, K.; Messenger, Scott R.; Ito, M.; Keller, L. P.; Clemett, S. J.; Jones, J. H.; Tatsuoka, H.; Zolensky, M. E.; Tatsuoka, H.

    2010-01-01

    Brownleeite is a manganese silicide, ideally stoichiometric MnSi, not previously observed in nature until its discovery within an interplanetary dust particle (IDP) that likely originated from a comet [1]. Three discrete brownleeite grains in the IDP L2055 I3 (4 microns in size, hereafter IDP I3) were identified with maximum dimensions of 100, 250 and 600 nm and fully analyzed using scanning-transmission electron microscopy (STEM) [1]. One of the grains (100 nm in size) was poikilitically enclosed by low-Fe, Mn-enriched (LIME) olivine. LIME olivine is epitaxial to the brownleeite with the brownleeite (200) parallel to the olivine c* [1]. LIME olivine is an enigmatic phase first reported from chondritic porous IDPs and some unequilibrated ordinary chondrites [ 2], that is commonly observed in chondritic-porous IDPs. Recently, LIME olivine has been also found in comet Wild-2 (Stardust) samples [3], indicating that LIME olivine is a common mineral component of comets. LIME olivine has been proposed to form as a high temperature condensate in the protosolar nebula [2]. Brownleeite grains also likely formed as high-temperature condensates either in the early Solar System or in the outflow of an evolved star or supernova explosion [1]. The isotopic composition of the brownleeite grains may strongly constrain their ultimate source. To test this hypothesis, we performed isotopic analyses of the brownleeite and the associated LIME olivine, using the NASA/JSC NanoSIMS 50L ion microprobe.

  2. Si isotope homogeneity of the solar nebula

    Energy Technology Data Exchange (ETDEWEB)

    Pringle, Emily A.; Savage, Paul S.; Moynier, Frédéric [Department of Earth and Planetary Sciences and McDonnell Center for the Space Sciences, Washington University in St. Louis, One Brookings Drive, St. Louis, MO 63130 (United States); Jackson, Matthew G. [Department of Earth Science, University of California, Santa Barbara, CA 93109 (United States); Barrat, Jean-Alix, E-mail: eapringle@wustl.edu, E-mail: savage@levee.wustl.edu, E-mail: pringle@ipgp.fr, E-mail: moynier@ipgp.fr, E-mail: jackson@geol.ucsb.edu, E-mail: Jean-Alix.Barrat@univ-brest.fr [Université Européenne de Bretagne, Université de Brest, CNRS UMR 6538 (Domaines Océaniques), I.U.E.M., Place Nicolas Copernic, F-29280 Plouzané Cedex (France)

    2013-12-20

    The presence or absence of variations in the mass-independent abundances of Si isotopes in bulk meteorites provides important clues concerning the evolution of the early solar system. No Si isotopic anomalies have been found within the level of analytical precision of 15 ppm in {sup 29}Si/{sup 28}Si across a wide range of inner solar system materials, including terrestrial basalts, chondrites, and achondrites. A possible exception is the angrites, which may exhibit small excesses of {sup 29}Si. However, the general absence of anomalies suggests that primitive meteorites and differentiated planetesimals formed in a reservoir that was isotopically homogenous with respect to Si. Furthermore, the lack of resolvable anomalies in the calcium-aluminum-rich inclusion measured here suggests that any nucleosynthetic anomalies in Si isotopes were erased through mixing in the solar nebula prior to the formation of refractory solids. The homogeneity exhibited by Si isotopes may have implications for the distribution of Mg isotopes in the solar nebula. Based on supernova nucleosynthetic yield calculations, the expected magnitude of heavy-isotope overabundance is larger for Si than for Mg, suggesting that any potential Mg heterogeneity, if present, exists below the 15 ppm level.

  3. Equilibrium and kinetic Si isotope fractionation factors and their implications on Si isotope distributions in the Earth's surface environments

    Science.gov (United States)

    Tang, M.; Zhang, S.; Liu, Y.

    2015-12-01

    Several important equilibrium Si isotope fractionation factors among minerals, organic molecules and the H4SiO4 solution are complemented to facilitate explanation of distributions of Si isotope in the Earth's surface environments. The results reveal that heavy Si isotopes will be significantly enriched in the secondary silicate minerals in comparison to aqueous H4SiO4. On the contrary, quadra-coordinated organosilicon complexes are enriched in light silicon isotope relative to the solution. The extent of 28Si-enrichment in hyper-coordinated organosilicon complexes is found the largest. In addition, the large kinetic isotope effect associated with the polymerization of monosilicic acid and dimer is calculated and the result supports previous statement that highly 28Si-enrichment in the formation of amorphous quartz precursor contributes to the discrepancy between theoretical calculations and field observations. With equilibrium Si isotope fractionation factors provided here, Si isotope distributions in many surface systems of the Earth can be explained. For example, the change of bulk soil δ30Si can be predicted as a concave pattern with respect to weathering degree, with the minimum value where allophane completely dissolves and the total amount of sesqui-oxides and poorly crystalline minerals reaches its maximum. When well-crystallized clays start to precipitate from pore solutions under equilibrium conditions, the bulk soil δ30Si will increase again and reach a constant value. Similarly, the precipitation of crystalline smectite and the dissolution of poorly crystalline kaolinite may explain δ30Si variations in the ground water profile. Equilibrium Si isotope fractionations among quadra-coordinated organosilicon complexes and the H4SiO4 solution may also shed the light on the Si isotope distributions in Si-accumulating plants.

  4. Abiologic silicon isotope fractionation between aqueous Si and Fe(III)-Si gel in simulated Archean seawater: Implications for Si isotope records in Precambrian sedimentary rocks

    Science.gov (United States)

    Zheng, Xin-Yuan; Beard, Brian L.; Reddy, Thiruchelvi R.; Roden, Eric E.; Johnson, Clark M.

    2016-08-01

    Precambrian Si-rich sedimentary rocks, including cherts and banded iron formations (BIFs), record a >7‰ spread in 30Si/28Si ratios (δ30Si values), yet interpretation of this large variability has been hindered by the paucity of data on Si isotope exchange kinetics and equilibrium fractionation factors in systems that are pertinent to Precambrian marine conditions. Using the three-isotope method and an enriched 29Si tracer, a series of experiments were conducted to constrain Si isotope exchange kinetics and fractionation factors between amorphous Fe(III)-Si gel, a likely precursor to Precambrian jaspers and BIFs, and aqueous Si in artificial Archean seawater under anoxic conditions. Experiments were conducted at room temperature, and in the presence and absence of aqueous Fe(II) (Fe(II)aq). Results of this study demonstrate that Si solubility is significantly lower for Fe-Si gel than that of amorphous Si, indicating that seawater Si concentrations in the Precambrian may have been lower than previous estimates. The experiments reached ˜70-90% Si isotope exchange after a period of 53-126 days, and the highest extents of exchange were obtained where Fe(II)aq was present, suggesting that Fe(II)-Fe(III) electron-transfer and atom-exchange reactions catalyze Si isotope exchange through breakage of Fe-Si bonds. All experiments except one showed little change in the instantaneous solid-aqueous Si isotope fractionation factor with time, allowing extraction of equilibrium Si isotope fractionation factors through extrapolation to 100% isotope exchange. The equilibrium 30Si/28Si fractionation between Fe(III)-Si gel and aqueous Si (Δ30Sigel-aqueous) is -2.30 ± 0.25‰ (2σ) in the absence of Fe(II)aq. In the case where Fe(II)aq was present, which resulted in addition of ˜10% Fe(II) in the final solid, creating a mixed Fe(II)-Fe(III) Si gel, the equilibrium fractionation between Fe(II)-Fe(III)-Si gel and aqueous Si (Δ30Sigel-aqueous) is -3.23 ± 0.37‰ (2σ). Equilibrium

  5. Isotope engineering of carbon nanotube systems.

    Science.gov (United States)

    Simon, F; Kramberger, Ch; Pfeiffer, R; Kuzmany, H; Zólyomi, V; Kürti, J; Singer, P M; Alloul, H

    2005-07-01

    The synthesis of a unique isotope engineered system, double-wall carbon nanotubes with natural carbon outer and highly 13C enriched inner walls, is reported from isotope enriched fullerenes encapsulated in single-wall carbon nanotubes (SWCNTs). The material allows the observation of the D line of the highly defect-free inner tubes that can be related to a curvature induced enhancement of the electron-phonon coupling. Ab initio calculations explain the inhomogeneous broadening of inner tube Raman modes due to the distribution of different isotopes. Nuclear magnetic resonance shows a significant contrast of the isotope enriched inner SWCNTs compared to other carbon phases and provides a macroscopic measure of the inner tube mass content. The high curvature of the small diameter inner tubes manifests in an increased distribution of the chemical shift tensor components.

  6. Shallow dopants in nanostructered and in isotopically engineered silicon

    Energy Technology Data Exchange (ETDEWEB)

    Stegner, Andre Rainer

    2011-01-15

    isotopically engineered {sup 28}Si samples, we have found that the broad inter-subband EPR line of B acceptors shows an inhomogeneous Lorentzian broadening proportional to the concentration of carbon, oxygen and boron point defects down to approximately 5 x 10{sup 15} cm{sup -3} caused by local strain fields. For samples with less than 5 x 10{sup 15} cm{sup -3} point defects, we have found a linewidth threshold of {approx}2.2 mT for which we have discussed different possible explanations. (orig.)

  7. Wideband SI Engine Lambda Control

    DEFF Research Database (Denmark)

    Jensen, Per Buchbjerg; Olsen, Mads Bruun; Poulsen, Jannik

    1998-01-01

    Long term control of the AFR (Air/Fuel Ratio) of spark ignition engines is currently accomplished with a self-oscialling PI control loop. Because of the intake/exhaust time delay, the oscillation frequency and hence bandwidth of this loop is small. This paper describes a new approach to the desig...

  8. Flex Fuel Optimized SI and HCCI Engine

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Guoming; Schock, Harold; Yang, Xiaojian; Huisjen, Andrew; Stuecken, Tom; Moran, Kevin; Zhen, Ron; Zhang, Shupeng

    2013-09-30

    The central objective of the proposed work is to demonstrate an HCCI (homogeneous charge compression ignition) capable SI (spark ignited) engine that is capable of fast and smooth mode transition between SI and HCCI combustion modes. The model-based control technique was used to develop and validate the proposed control strategy for the fast and smooth combustion mode transition based upon the developed control-oriented engine; and an HCCI capable SI engine was designed and constructed using production ready two-step valve-train with electrical variable valve timing actuating system. Finally, smooth combustion mode transition was demonstrated on a metal engine within eight engine cycles. The Chrysler turbocharged 2.0L I4 direct injection engine was selected as the base engine for the project and the engine was modified to fit the two-step valve with electrical variable valve timing actuating system. To develop the model-based control strategy for stable HCCI combustion and smooth combustion mode transition between SI and HCCI combustion, a control-oriented real-time engine model was developed and implemented into the MSU HIL (hardware-in-the-loop) simulation environment. The developed model was used to study the engine actuating system requirement for the smooth and fast combustion mode transition and to develop the proposed mode transition control strategy. Finally, a single cylinder optical engine was designed and fabricated for studying the HCCI combustion characteristics. Optical engine combustion tests were conducted in both SI and HCCI combustion modes and the test results were used to calibrate the developed control-oriented engine model. Intensive GT-Power simulations were conducted to determine the optimal valve lift (high and low) and the cam phasing range. Delphi was selected to be the supplier for the two-step valve-train and Denso to be the electrical variable valve timing system supplier. A test bench was constructed to develop control strategies for

  9. Light and heavy element isotopic compositions of mainstream SiC grains.

    Energy Technology Data Exchange (ETDEWEB)

    Amari, S.; Clayton, R. N.; Davis, A. M.; Lewis, R. S.; Pellin, M. J.

    1999-02-03

    Although a variety of types of pre-solar SiC grains have been classified by their C, N, and Si isotopic composition, the majority of such grains are so-called mainstream grains and are believed to have come from asymptotic giant branch stars [1]. We have previously reported the Mo isotopic compositions of presolar SiC grains whose C, N, and Si isotopic compositions were not known [2]. Since most presolar SiC grains fall in the mainstream group, we assumed that these grains were mainstream. The excellent match of the Mo isotopic data with expectations for nucleosynthesis in AGB stars was consistent with this identification. In order to better understand the distribution of isotopic compositions in presolar grains, we have begun to measure heavy element isotopic compositions of presolar SiC grains of known C, N and Si isotopic composition.

  10. Flex Fuel Optimized SI and HCCI Engine

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Guoming; Schock, Harold; Yang, Xiaojian; Huisjen, Andrew; Stuecken, Tom; Moran, Kevin; Zhen, Ron; Zhang, Shupeng

    2013-09-30

    The central objective of the proposed work is to demonstrate an HCCI (homogeneous charge compression ignition) capable SI (spark ignited) engine that is capable of fast and smooth mode transition between SI and HCCI combustion modes. The model-based control technique was used to develop and validate the proposed control strategy for the fast and smooth combustion mode transition based upon the developed control-oriented engine; and an HCCI capable SI engine was designed and constructed using production ready two-step valve-train with electrical variable valve timing actuating system. Finally, smooth combustion mode transition was demonstrated on a metal engine within eight engine cycles. The Chrysler turbocharged 2.0L I4 direct injection engine was selected as the base engine for the project and the engine was modified to fit the two-step valve with electrical variable valve timing actuating system. To develop the model-based control strategy for stable HCCI combustion and smooth combustion mode transition between SI and HCCI combustion, a control-oriented real-time engine model was developed and implemented into the MSU HIL (hardware-in-the-loop) simulation environment. The developed model was used to study the engine actuating system requirement for the smooth and fast combustion mode transition and to develop the proposed mode transition control strategy. Finally, a single cylinder optical engine was designed and fabricated for studying the HCCI combustion characteristics. Optical engine combustion tests were conducted in both SI and HCCI combustion modes and the test results were used to calibrate the developed control-oriented engine model. Intensive GT-Power simulations were conducted to determine the optimal valve lift (high and low) and the cam phasing range. Delphi was selected to be the supplier for the two-step valve-train and Denso to be the electrical variable valve timing system supplier. A test bench was constructed to develop control strategies for

  11. Mean Value Modelling of a Turbocharged SI Engine

    DEFF Research Database (Denmark)

    Müller, Martin; Hendricks, Elbert; Sorenson, Spencer C.

    1998-01-01

    An important paradigm for the modelling of naturallly aspirated (NA) spark ignition (SI) engines for control purposes is the Mean Value Engine Model (MVEM). Such models have a time resolution which is just sufficient to capture the main details of the dynamic performance of NA SI engines but not ...

  12. Interstellar SiC: Extended Studies of C, N, and SI Isotopes in Small Single Grains

    Science.gov (United States)

    Hoppe, P.; Strebel, R.; Eberhardt, P.; Amari, S.; Lewis, R. S.

    1993-07-01

    In search of grain-size dependent characteristics of interstellar SiC, we have measured the C, N, and Si isotopes in 596 single grains from Murchison separate KJE (average size 1.14 micrometers) [1]. So far, extended studies of single SiC grains from the Murchison K-series were made on separates KJG (average size 3.02 micrometers) and KJH (average size 4.57 micrometers) [2] and a limited dataset was also obtained for separate KJF (average size 1.86 micrometers) [2,3]. As it is the case for the larger grains, most grains from KJE have heavy carbon and light nitrogen. ^12C/^13C ratios vary between 2.3 and 270. The distribution of ^12C/^13C ratios is almost identical to those observed for the larger-grain separates, with most grains having ^12C/^13C ~40-100 (Fig. 1a-c). ^14N/^15N ratios vary between 48 and >10,000. The distribution of ^14N/^15N ratios clearly differs from those observed for the larger-grain separates (Fig. 1d-f). Grains from separate KJE, on the average, have much higher ^14N/^15N ratios. The median value is 2800 compared to 1250 for KJG and 550 for KJH [2]. As is evident from these numbers, there is a clear trend with the typical ^14N/^15N ratio increasing with decreasing grain size. In close agreement with the larger grains, most grains from KJE have delta^29Si ~ -50 to 200 per mil and delta^30Si ~ 0 to 160 per mil, in a three-isotope-plot lying along a line with slope ~1.1. However, there are 12 grains clearly off this line with 10 of them being depleted in ^29Si and enriched in ^30Si. Nine grains were identified as grains X [4], being charaterized by light C, heavy N, and light Si. Five of them, in addition, show a very high nitrogen content, ~5x higher than that of a typical grain from KJE. Furthermore, one grain has the Si-isotopic signature of grains X, but heavy C. While the observed C-isotopic ratios for the majority of the grains can be explained by standard stellar evolution models for AGB-stars [5], the ^14N/^15N ratios > ~2000, as it is

  13. 40 CFR 90.913 - Exemption for engines certified to standards for large SI engines.

    Science.gov (United States)

    2010-07-01

    ... standards for large SI engines. 90.913 Section 90.913 Protection of Environment ENVIRONMENTAL PROTECTION... for engines certified to standards for large SI engines. (a) An engine is exempt from the requirements... meets emission standards and other requirements under 40 CFR part 1048 for the appropriate model...

  14. NanoSIMS isotopic analysis of small presolar grains : search for Si3N4 grains from AGB stars and Al and Ti isotopic compositions of rare presolar SiC grains

    NARCIS (Netherlands)

    Zinner, E.; Sachiko, A.; Guinness, R.; Jennings, C.; Mertz, A.F.; Nguyen, A.N.; Gallino, R.; Hoppe, P.; Lugaro, M.A.; Nittler, L.R.; Lewis, R.S.

    2007-01-01

    We report isotopic ratio measurements of small SiC and Si3N4grains, with special emphasis on presolar SiC grains of type Z, and new nucleosynthesis models for 26Al/27Al and the Ti isotopic ratios in asymptotic giant branch (AGB) stars. With the NanoSIMS we analyzed 310 SiC grains from Murchison (car

  15. NanoSIMS isotopic analysis of small presolar grains : search for Si3N4 grains from AGB stars and Al and Ti isotopic compositions of rare presolar SiC grains

    NARCIS (Netherlands)

    Zinner, E.; Sachiko, A.; Guinness, R.; Jennings, C.; Mertz, A.F.; Nguyen, A.N.; Gallino, R.; Hoppe, P.; Lugaro, M.A.; Nittler, L.R.; Lewis, R.S.

    2007-01-01

    We report isotopic ratio measurements of small SiC and Si3N4grains, with special emphasis on presolar SiC grains of type Z, and new nucleosynthesis models for 26Al/27Al and the Ti isotopic ratios in asymptotic giant branch (AGB) stars. With the NanoSIMS we analyzed 310 SiC grains from Murchison

  16. Sulfur Isotopic Compositions of Submicrometer SiC Grains from the Murchison Meteorite

    Science.gov (United States)

    Xu, Yuchen; Zinner, Ernst; Gallino, Roberto; Heger, Alexander; Pignatari, Marco; Lin, Yangting

    2015-02-01

    We report C, Si, N, S, Mg-Al, and Ca-Ti isotopic compositions of presolar silicon carbide (SiC) grains from the SiC-rich KJE size fraction (0.5-0.8 μm) of the Murchison meteorite. One thousand one hundred thirteen SiC grains were identified based on their C and Si isotopic ratios. Mainstream, AB, C, X, Y, and Z subtypes of SiC, and X-type silicon nitride (Si3N4) account for 81.4%, 5.7%, 0.1%, 1.5%, 5.8%, 4.9%, and 0.4%, respectively. Twenty-five grains with unusual Si isotopic ratios, including one C grain, 16 X grains, 1 Y grain, 5 Z grains, and 2 X-type Si3N4 grains were selected for N, S, Mg-Al, and Ca-Ti isotopic analysis. The C grain is highly enriched in 29Si and 30Si (δ29Si = 1345‰ ± 19‰, δ30Si = 1272‰ ± 19‰). It has a huge 32S excess, larger than any seen before, and larger than that predicted for the Si/S supernova (SN) zone, providing evidence against the elemental fractionation model by Hoppe et al. Two SN models investigated here present a more satisfying explanation in terms of a radiogenic origin of 32S from the decay of short-lived 32Si (τ1/2 = 153 yr). Silicon-32 as well as 29Si and 30Si can be produced in SNe by short neutron bursts; evidence for initial 44Ti (τ1/2 = 60 yr) in the C grain is additional evidence for an SN origin. The X grains have marginal 32S excesses, much smaller than expected from their large 28Si excesses. Similarly, the Y and Z grains do not show the S-isotopic anomalies expected from their large Si isotopic anomalies. Low intrinsic S contents and contamination with isotopically normal S are the most likely explanations.

  17. SULFUR ISOTOPIC COMPOSITIONS OF SUBMICROMETER SiC GRAINS FROM THE MURCHISON METEORITE

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Yuchen [Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002 (China); Zinner, Ernst [Laboratory for Space Sciences and Physics Department, Washington University, St. Louis, MO 63130 (United States); Gallino, Roberto [Dipartimento di Fisica, Università di Torino, I-10125 Torino (Italy); Heger, Alexander [Monash Centre for Astrophysics, School of Mathematical Sciences, Monash University, Vic 3800 (Australia); Pignatari, Marco [Department of Physics, University of Basel, CH-4056 Basel (Switzerland); Lin, Yangting, E-mail: xuyuchen@mail.iggcas.ac.cn [Key Laboratory of Earth' s Deep Interior, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029 (China)

    2015-02-01

    We report C, Si, N, S, Mg-Al, and Ca-Ti isotopic compositions of presolar silicon carbide (SiC) grains from the SiC-rich KJE size fraction (0.5-0.8 μm) of the Murchison meteorite. One thousand one hundred thirteen SiC grains were identified based on their C and Si isotopic ratios. Mainstream, AB, C, X, Y, and Z subtypes of SiC, and X-type silicon nitride (Si{sub 3}N{sub 4}) account for 81.4%, 5.7%, 0.1%, 1.5%, 5.8%, 4.9%, and 0.4%, respectively. Twenty-five grains with unusual Si isotopic ratios, including one C grain, 16 X grains, 1 Y grain, 5 Z grains, and 2 X-type Si{sub 3}N{sub 4} grains were selected for N, S, Mg-Al, and Ca-Ti isotopic analysis. The C grain is highly enriched in {sup 29}Si and {sup 30}Si (δ{sup 29}Si = 1345‰ ± 19‰, δ{sup 30}Si = 1272‰ ± 19‰). It has a huge {sup 32}S excess, larger than any seen before, and larger than that predicted for the Si/S supernova (SN) zone, providing evidence against the elemental fractionation model by Hoppe et al. Two SN models investigated here present a more satisfying explanation in terms of a radiogenic origin of {sup 32}S from the decay of short-lived {sup 32}Si (τ{sub 1/2} = 153 yr). Silicon-32 as well as {sup 29}Si and {sup 30}Si can be produced in SNe by short neutron bursts; evidence for initial {sup 44}Ti (τ{sub 1/2} = 60 yr) in the C grain is additional evidence for an SN origin. The X grains have marginal {sup 32}S excesses, much smaller than expected from their large {sup 28}Si excesses. Similarly, the Y and Z grains do not show the S-isotopic anomalies expected from their large Si isotopic anomalies. Low intrinsic S contents and contamination with isotopically normal S are the most likely explanations.

  18. Silicon stable isotope distribution traces Southern Ocean export of Si to the eastern South Pacific thermocline

    Science.gov (United States)

    de Souza, G. F.; Reynolds, B. C.; Johnson, G. C.; Bullister, J. L.; Bourdon, B.

    2012-11-01

    The cycling and transport of dissolved silicon (Si) in the ocean may be traced by its stable isotope composition, δ30Si. We present a dataset of δ30Si values along 103° W in the eastern South Pacific Ocean, ranging from the Antarctic Zone of the Southern Ocean (62° S) to the equatorial Pacific (12° S). At high southern latitudes, the uptake and associated isotope fractionation of Si by diatoms results in highly elevated δ30Si values (up to +3.2‰) in the summer mixed layer. High δ30Si values (+2‰) are also preserved in the high-latitude fossil winter mixed layer, documenting the efficient export of diatom opal beyond the maximum depth of winter convection. This elevated winter mixed layer δ30Si signature is introduced into the ocean interior by the subduction of Subantarctic Mode Water (SAMW) and Antarctic Intermediate Water (AAIW), whose northward spreading results in a strong isopycnal control on lower-thermocline and intermediate δ30Si values in the well-ventilated eastern South Pacific. Values of δ30Si are strongly conserved along SAMW and AAIW density levels as far north as 26° S, documenting the importance of the export of preformed Si from the surface Southern Ocean to lower latitudes. In contrast, in the equatorial Pacific, depressed δ30Si values in the mesopelagic ocean are observed, most likely documenting the combined influence of a North Pacific Si source as well as the accumulation of remineralized Si within the eastern equatorial Pacific shadow zone. At depth, δ30Si values in the South Pacific remain indistinguishable from deep Southern Ocean values of +1.25‰, even within Si-rich and oxygen-poor deep waters returning from the North Pacific. This homogeneity implies that the dissolution of opal plays a negligible role in altering the δ30Si value of deep waters as they traverse the deep Pacific Ocean.

  19. Mean Value Engine Modelling of an SI Engine with EGR

    DEFF Research Database (Denmark)

    Føns, Michael; Müller, Martin; Chevalier, Alain

    1999-01-01

    Mean Value Engine Models (MVEMs) are simplified, dynamic engine models what are physically based. Such models are useful for control studies, for engine control system analysis and for model based engine control systems. Very few published MVEMs have included the effects of Exhaust Gas...... Recirculation (EGR). The purpose of this paper is to present a modified MVEM which includes EGR in a physical way. It has been tested using newly developed, very fast manifold pressure, manifold temperature, port and EGR mass flow sensors. Reasonable agreement has been obtained on an experimental engine...

  20. Mechanical engineering science in SI units

    CERN Document Server

    Gwyther, J L; Williams, G

    1970-01-01

    0.1 Mechanical Engineering Science covers various fundamental concepts that are essential in the practice of mechanical engineering. The title is comprised of 19 chapters that detail various topics, including chemical and physical laws. The coverage of the book includes Newtonian laws, mechanical energy, friction, stress, and gravity. The text also discusses the chemical aspects of mechanical engineering, which include gas laws, states of matter, and fuel combustion. The last chapter tackles concerns in laboratory experiments. The book will be of great use to students of mechanical eng

  1. Higher Order Continuous SI Engine Observers

    DEFF Research Database (Denmark)

    Vesterholm, Thomas; Hendricks, Elbert; Houbak, Niels

    1992-01-01

    A nonlinear compensator for the fuel film dynamics and a second order nonlinear observer for a spark ignition engine are presented in this paper. The compensator and observer are realized as continuous differential equations and an especially designed integration algorithm is used to integrate them...... in real time. Using these means, accurate steady state and transient air/fuel control can be obtained with excellent robustness properties. Some useful condition monitoring facilities are also available in the observer. The compensator and observer are based on a Mean Value Engine Model (MVEM) presented...... earlier. A MVEM is one which predicts the mean value of the engine states and internal variables over time scales which are large compared to the cyclic engine process....

  2. Mean Value Modelling of Turbocharged SI Engines

    DEFF Research Database (Denmark)

    Müller, Martin; Hendricks, Elbert; Sorenson, Spencer C.

    1998-01-01

    The development of a computer simulation to predict the performance of a turbocharged spark ignition engine during transient operation. New models have been developed for the turbocharged and the intercooling system. An adiabatic model for the intake manifold is presented....

  3. Continuous Identification of a Four-Stroke SI Engine

    DEFF Research Database (Denmark)

    Melgaard, Henrik; Hendricks, Elbert; Madsen, Henrik

    1990-01-01

    Compact engine models often consist of a set of nonlinear differential equations which predict the time development of the mean value of the engine state variables (and perhaps some internal variables): such models are sometimes called mean value engine models. Currently a great deal of attention...... is focused on constructing such continuous time models and on finding their parameters. This paper shows, that it is possible to identify an engine model from a linearized version of a mean value model for a CFI four-cycle spark ignition (SI) engine. Such an approach is useful because it preserves a physical...... understanding of the engine throughout the identification stage. Afterwards the identification results are available for general dynamic engine studies. The identfication techniques discussed in this paper include classical methods (step response) as well as modern statistical methods (Kalman filtering...

  4. Mean Value SI Engine Model for Control Studies

    DEFF Research Database (Denmark)

    Hendricks, Elbert; Sorenson, Spencer C

    1990-01-01

    This paper presents a mathematically simple nonlinear three state (three differential equation) dynamic model of an SI engine which has the same steady state accuracy as a typical dynamometer measurement of the engine over its entire speed/load operating range (± 2.0%). The model's accuracy for l....... The model can easily be run on a Personal Computer (PC) using a ordinary differential equation (ODE) integrating routine or package. This makes the model is useful for control system design and evaluation....

  5. High resolution optical spectroscopy in isotopically-pure Si using radioactive isotopes: towards a re-evaluation of deep centres

    CERN Multimedia

    2008-01-01

    Deep centres in silicon have been studied in great detail over the last 50 years and much progress has been made in the understanding and control of impurities in this material. Much of this effort has been focussed on the problems of metallic impurities such as Fe, Ag, Cu and Au. These are impurities that diffuse quickly into the crystal and hamper device performance. Although the understanding of these impurity centres in Si is widely thought to be "solved" recent experiments with isotopically-pure Si are disproving long-held results and are opening up new perspectives on the constitutent nature of deep centres in Si. In particular, there is new evidence to show that the family of Cu, Ag and Au may all show essentially the same behaviour by forming a cluster of $\\textbf{any four atoms}$ of these elements. This has been established for Cu and Ag through the use of different stable isotopes in the preparation of samples, but the case of Au remains unproven since there is only one stable Au isotope. In this pr...

  6. Quadrupole collectivity in Si isotopes around N=20

    CERN Document Server

    Rodríguez-Guzman, R R; Robledo, L M

    2001-01-01

    The angular momentum projected Generator Coordinate Method using the quadrupole moment as collective coordinate and the Gogny force as the effective interaction is used to describe the properties of the ground state and low-lying excited states of the neutron rich light nuclei 32,34,36Si. It is found that the ground state of the nucleus 34Si is spherical. However, this is not only due to the N=20 shell closure as the ground state of 34Si contains a significant amount of the intruder f7/2 neutron orbital. On the other hand, rather good agreement with experimental data for many observables is obtained.

  7. SI Engine with repetitive NS spark plug

    Science.gov (United States)

    Pancheshniy, Sergey; Nikipelov, Andrey; Anokhin, Eugeny; Starikovskiy, Andrey; Laplase Team; Mipt Team; Pu Team

    2013-09-01

    Now de-facto the only technology for fuel-air mixtures ignition in IC engines exists. It is a spark discharge of millisecond duration in a short discharge gap. The reason for such a small variety of methods of ignition initiation is very specific conditions of the engine operation. First, it is very high-pressure of fuel-air mixture - from 5-7 atmospheres in old-type engines and up to 40-50 atmospheres on the operating mode of HCCI. Second, it is a very wide range of variation of the oxidizer/fuel ratio in the mixture - from almost stoichiometric (0.8-0.9) at full load to very lean (φ = 0.3-0.5) mixtures at idle and/or economical cruising mode. Third, the high velocity of the gas in the combustion chamber (up to 30-50 m/s) resulting in a rapid compression of swirling inlet flow. The paper presents the results of tests of distributed spark ignition system powered by repetitive pulse nanosecond discharge. Dynamic pressure measurements show the increased pressure and frequency stability for nanosecond excitation in comparison with the standard spark plug. Excitation by single nanosecond high-voltage pulse and short train of pulses was examined. In all regimes the nanosecond pulsed excitation demonstrate a better performance.

  8. 640 x 480 PtSi infrared engine

    Science.gov (United States)

    Lang, Frank B.; Coyle, Peter J.; Stabile, Paul J.; Tower, John R.; Zubalsky, I.; Ornstein, Itzhak

    1996-06-01

    The design and performance of a compact, light-weight, low power infrared engine is presented. The 3 - 5 micron MWIR imaging subsystem consists of a Stirling-cooled, 640 (H) by 480 (V) staring PtSi infrared focal plane array (IRFPA) with associated drive and analog video processing electronics. The IR engine provides user-selectable integration time control. This infrared imaging subsystem is designed to be gimbal-mounted, and has been qualified to be operated in minus 10 Celsius to plus 50 Celsius environments. The infrared engine is also designed to meet the requirements of demanding shock and vibration environments.

  9. Silicon pool dynamics and biogenic silica export in the Southern Ocean, inferred from Si-isotopes

    Directory of Open Access Journals (Sweden)

    F. Fripiat

    2011-03-01

    Full Text Available Water column silicon isotopic signatures (δ30Si of silicic acid (Si(OH4 in the Southern Ocean were measured along a meridional transect from South Africa (Subtropical Zone down to 57° S (northern Weddell Gyre. These data are the first reported for a summer transect across the whole Antarctic Circumpolar Current (ACC. δ30Si variations are large in the upper 1000 m, reflecting the effect of the silica pump superimposed upon meridional transfer across the ACC: the transport of Antarctic surface waters northward by a net Ekman drift and their convergence and mixing with warmer upper-ocean Si-depleted waters to the north. Using Si isotopic signatures, we determined different mixing interfaces between ACC water masses: the Antarctic Surface Water (AASW, the Antarctic Intermediate Water (AAIW, and the thermoclines in the low latitude areas. The residual silicic acid concentrations of end-members control the δ30Si alteration of the mixing products. With the exception of AASW, all mixing interfaces have a highly Si-depleted mixed layer end-member. These processes deplete the silicic acid AASW concentration across the different interfaces northward without significantly changing the AASW δ30Si. By comparing our new results with a previous study in the Australian sector we show that during the circumpolar transport of the ACC eastward, there is a slight but significant Si-isotopic lightening of the silicic acid pools from the Atlantic to the Australian sectors. This results either from the dissolution of biogenic silica in the deeper layers and/or from an isopycnal mixing with the deep water masses in the different oceanic basins: North Atlantic Deep Water in the Atlantic, and Indian Ocean deep water in the Indo-Australian sector. This eastward lightening is further transmitted to the subsurface waters, representing mixing interfaces between the surface and deeper layers.

    Using the Si-isotopic

  10. MoSi2-Base Hybrid Composite Passed Engine Test

    Science.gov (United States)

    Keith, Theo G., Jr.; Hebsur, Mohan

    1998-01-01

    The intermetallics compound molybdenum disilicide (MoSi2) is an attractive high-temperature structural material for advanced engine applications. It has excellent oxidation resistance, a high melting point, relatively low density, and high thermal conductivity, and it is easily machined. Past research'at the NASA Lewis Research Center has resulted in the development of a hybrid composite consisting of a MoSi2 matrix reinforced with silicon nitride (Si3N4) Particulate and silicon carbide (SiC) fibers. This composite has demonstrated attractive strength, toughness, thermal fatigue, and oxidation resistance, including resistance to "pest" oxidation. These properties attracted the interest of the Office of Naval Research and Pratt & Whitney, and a joint NASA/Navy/Pratt & Whitney effort was developed to continue to mature the MoSi2 Composite technology. A turbine blade outer air seal, which was part of the Integrated High Performance Turbine Engine Technology (IHPTET) program, was chosen as a first component on which to focus. The first tasks of the materials development effort were to develop improved processing methods to reduce costs and to use fine-diameter fibers that enable the manufacturing of complex shapes. Tape-casting methods were developed to fully infiltrate the fine SiC fibers with matrix powders. The resulting composites were hot pressed to 100-percent density. Composites with cross-plied fiber architectures with 30 vol. % hi-nicalon SiC fibers and 30 vol. % nitride particles are now made routinely and demonstrate a good balance of properties. The next task entailed the measurement of a wide variety of mechanical properties to confirm the suitability of this composite in engines. In particular, participants in this effort demonstrated that composites made with Hi-Nicalon fibers had strength and toughness properties equal to or better than those of the composites made with the large-diameter fibers that had been used previously. Another critically

  11. Experimental investigation of ethanol blends with gasoline on SI engine

    Directory of Open Access Journals (Sweden)

    Gaurav tiwari

    2014-10-01

    Full Text Available Automobile have become a very important part of our modern life style. But the future of automobile based on internal combustion engines has been badly affected by two major problems. That is less availability of fuel and environmental degradation. So it is very important to found some new renewable non polluting alternative fuels to ensure the proper and safe survival of internal combustion engines. In present study we evaluate the performance of two stroke single cylinder spark ignition engine with ratio of 10% 20% and 30% of ethanol and gasoline by volume. Performance parameters (brake thermal efficiency, brake specific energy consumption and brake specific fuel consumption were determined at various loads on engine with ethanol blended gasoline. The comparison was made on performance of conventional SI engine with pure gasoline operation. As a result, brake thermal efficiency, brake specific fuel consumption and brake specific fuel consumption showed comparable performance when compared with pure gasoline performances.

  12. Nuclear Structure and Reaction Properties of Ne, Mg and Si Isotopes with RMF Densities

    CERN Document Server

    Panda, R N; Patra, S K

    2013-01-01

    We have studied nuclear structure and reaction properties of Ne, Mg and Si isotopes, using relativistic mean field densities, in the frame work of Glauber model. Total reaction cross section $\\sigma_R$ for Ne isotopes on 12C target have been calculated at incident energy 240 MeV. The results are compared with the experimental data and with the recent theoretical study [W. Horiuchi et al., Phys. Rev. C, 86, 024614 (2012)]. Study of $\\sigma_R$ using deformed densities have shown a good agreement with the data. We have also predicted total reaction cross section $\\sigma_R$ for Ne, Mg and Si isotopes as projectiles and 12C as target at different incident energies.

  13. 40 CFR 91.1013 - Exemption for certified Small SI engines.

    Science.gov (United States)

    2010-07-01

    ... Marine SI Engines § 91.1013 Exemption for certified Small SI engines. The provisions of 40 CFR 1045.605... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Exemption for certified Small SI engines. 91.1013 Section 91.1013 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED)...

  14. Silicon stable isotope distribution traces Southern Ocean export of Si to the eastern South Pacific thermocline

    Directory of Open Access Journals (Sweden)

    G. F. de Souza

    2012-06-01

    Full Text Available The cycling and transport of dissolved silicon (Si in the ocean may be traced by its stable isotope composition, δ30Si. We present a dataset of δ30Si values along 103° W in the eastern South Pacific Ocean, ranging from the Antarctic Zone of the Southern Ocean (62° S to the equatorial Pacific (12° S. At high southern latitudes, the uptake and associated isotope fractionation of Si by diatoms results in highly elevated δ30Si values (up to +3.2 ‰ in the summer mixed layer. The efficient export of diatom opal to depths inaccessible to annual winter convection is reflected by high δ30Si values (+2 ‰ preserved in high-latitude winter mixed layers. These elevated δ30Si values are introduced into the ocean interior by the subduction of Subantarctic Mode Water (SAMW and Antarctic Intermediate Water (AAIW, whose northward spreading results in a strong isopycnal control on lower-thermocline and intermediate δ30Si values in the well-ventilated eastern South Pacific. Values of δ30Si are strongly conserved along SAMW and AAIW density levels as far north as 26° S, documenting the importance of the export of preformed Si from the surface Southern Ocean to lower latitudes. In contrast, in the equatorial Pacific, depressed δ30Si values in the mesopelagic ocean are observed, most likely documenting the combined influence of a North Pacific Si source as well as the accumulation of remineralized Si within the eastern equatorial Pacific shadow zone. At depth, δ30Si values in the South Pacific remain indistinguishable from deep Southern Ocean values of +1.25 ‰, even within Si-rich and oxygen-poor deep waters returning from the North Pacific. This homogeneity implies that the dissolution of opal plays a negligible role in altering the δ30Si value of deep waters as they traverse the deep Pacific Ocean.

  15. Silicon pool dynamics and biogenic silica export in the Southern Ocean inferred from Si-isotopes

    Directory of Open Access Journals (Sweden)

    F. Fripiat

    2011-09-01

    Full Text Available Silicon isotopic signatures (δ30Si of water column silicic acid (Si(OH4 were measured in the Southern Ocean, along a meridional transect from South Africa (Subtropical Zone down to 57° S (northern Weddell Gyre. This provides the first reported data of a summer transect across the whole Antarctic Circumpolar Current (ACC. δ30Si variations are large in the upper 1000 m, reflecting the effect of the silica pump superimposed upon meridional water transfer across the ACC: the transport of Antarctic surface waters northward by a net Ekman drift and their convergence and mixing with warmer upper-ocean Si-depleted waters to the north. Using Si isotopic signatures, we determine different mixing interfaces: the Antarctic Surface Water (AASW, the Antarctic Intermediate Water (AAIW, and thermoclines in the low latitude areas. The residual silicic acid concentrations of end-members control the δ30Si alteration of the mixing products and with the exception of AASW, all mixing interfaces have a highly Si-depleted mixed layer end-member. These processes deplete the silicic acid AASW concentration northward, across the different interfaces, without significantly changing the AASW δ30Si composition. By comparing our new results with a previous study in the Australian sector we show that during the circumpolar transport of the ACC eastward, the δ30Si composition of the silicic acid pools is getting slightly, but significantly lighter from the Atlantic to the Australian sectors. This results either from the dissolution of biogenic silica in the deeper layers and/or from an isopycnal mixing with the deep water masses in the different oceanic basins: North Atlantic Deep Water in the Atlantic, and Indian Ocean deep water in the Indo-Australian sector. This isotopic trend is further transmitted to the subsurface waters, representing mixing interfaces between the surface and deeper layers.

  16. First-principles investigation of equilibrium isotopic fractionation of Si and O isotopes among quartz, albite, anthorite, orthoenstatite, clinoenstatite, olivine, and zircon

    Science.gov (United States)

    Qin, T.; Wu, F.; Huang, F.; Wu, Z.

    2013-12-01

    Silicon is one of the most abundant elements in the crust and mantle. Because of advance of high precision analytical technique, Si isotope geochemistry has been widely applied into studies of a variety of important processes including planetary formation, core-mantle segregation, magmatism, and weathering of the crust. In order to better understanding Si isotope data in high temperature rock and mineral samples, it is critical to obtain equilibrium fractionation factors of Si isotopes among silicate minerals. However, experimental studies on calibrating Si isotope fractionation factors are still no available in literature. Here we used first-principles calculation based on density functional theory to investigate Si isotope fractionation factors among silicate minerals commonly occurring in magmatism in crustal level. These minerals include quartz, albite, anthorite, orthoenstatite, clinoenstatite, olivine, and zircon. We also calculated oxygen isotope fractionation factors among these minerals. Our results indicate the 18O-enrichment order among these minerals follows sequence of quartz > albite > anorthite > enstatite> zircon > olivine, showing good agreement with the data from previous experiments or natural sample measurement. For Si isotopes, our work shows that the 30Si-enrichment order in these minerals follows sequence of quartz > albite > anorthite > olivine ~ zircon > enstatite > diopside. These results are consistent with previous calculation [1] and observation from natural minerals. For example, Δ30Sianorthite-olivine = 0.2‰ at 1000oC based on our calculation, well consistent with value from the study of Skaergaard Intrusion (Δ30Siplagioclase-olivine = 0.24-27‰) [2] at same temperature. Our calculation indicates that Si isotopes can be significantly fractionated among silicate minerals during high temperature geochemical processes. References: [1] M. Méheut et al (2007), GCA 71:3170-3180. [2] P. S. Savage et al (2011), GCA 75:6124-6139.

  17. Processes controlling the Si-isotopic composition in the Southern Ocean and application for paleoceanography

    Directory of Open Access Journals (Sweden)

    F. Fripiat

    2012-07-01

    Full Text Available Southern Ocean biogeochemical processes have an impact on global marine primary production and global elemental cycling, e.g. by likely controlling glacial-interglacial pCO2 variation. In this context, the natural silicon isotopic composition (δ30Si of sedimentary biogenic silica has been used to reconstruct past Si-consumption:supply ratios in the surface waters. We present a new dataset in the Southern Ocean from a IPY-GEOTRACES transect (Bonus-GoodHope which includes for the first time summer δ30Si signatures of suspended biogenic silica (i for the whole water column at three stations and (ii in the mixed layer at seven stations from the subtropical zone up to the Weddell Gyre. In general, the isotopic composition of biogenic opal exported to depth was comparable to the opal leaving the mixed layer and did not seem to be affected by any diagenetic processes during settling, even if an effect of biogenic silica dissolution cannot be ruled out in the northern part of the Weddell Gyre. We develop a mechanistic understanding of the processes involved in the modern Si-isotopic balance, by implementing a mixed layer model. We observe that the accumulated biogenic silica (sensu Rayleigh distillation should satisfactorily describe the δ30Si composition of biogenic silica exported out of the mixed layer, within the limit of the current analytical precision on the δ30Si. The failures of previous models (Rayleigh and steady state become apparent especially at the end of the productive period in the mixed layer, when biogenic silica production and export are low. This results from (1 a higher biogenic silica dissolution:production ratio imposing a lower net fractionation factor and (2 a higher Si-supply:Si-uptake ratio supplying light Si-isotopes into the mixed layer. The latter effect is especially expressed when the summer mixed layer becomes strongly Si-depleted, together with a large

  18. Processes controlling the Si-isotopic composition in the Southern Ocean and application for paleoceanography

    Directory of Open Access Journals (Sweden)

    F. Fripiat

    2011-10-01

    Full Text Available Southern Ocean biogeochemical processes have an impact on global marine primary production and global elemental cycling, e.g. by likely controlling glacial-interglacial pCO2 variation. The natural silicon isotopic composition (δ30Si of sedimentary biogenic silica has been used to reconstruct past Si-consumption:supply ratio in the surface waters. We present a new dataset in the Southern Ocean which includes for the first time summer δ30Si signatures of suspended biogenic silica (i for the whole water column at three stations and (ii in the mixed layer at seven stations from the sub-tropical zone up to the Weddell Gyre.

    In general, the biogenic silica isotopic composition at depth reflected a mixed layer origin and seemed not affected by any diagenetic effect in the water column, even if in the northern part of the Weddell Gyre an effect of biogenic silica dissolution cannot be ruled out.

    We develop a mechanistic understanding of the processes involved in the modern Si-isotopic balance, by implementing a mixed layer model. We observe that the accumulated biogenic silica (sensu Rayleigh should satisfactorily describe the δ30Si composition of biogenic silica exported out of the mixed layer, within the limit of the current analytical precision on the δ30Si. The failures of previous models (Rayleigh and steady state become apparent especially at the end of the productive period in the mixed layer, when biogenic silica production is low. This results from: (1 a higher biogenic silica dissolution:production ratio imposing a lower net fractionation factor and (2 a higher Si-supply:Si-uptake ratio supplying light Si-isotopes into the mixed layer. The latter effect is especially expressed when the summer mixed layer becomes strongly Si-depleted together with a large vertical silicic acid gradient.

  19. An Isotope Study of Hydrogenation of poly-Si/SiOx Passivated Contacts for Si Solar Cells: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Schnabel, Manuel; Nemeth, William; van de Loo, Bas, W.H.; Macco, Bart; Kessels, Wilhelmus, M.M.; Stradins, Paul; Young, David, L.

    2017-06-26

    For many years, the record Si solar cell efficiency stood at 25.0%. Only recently have several companies and institutes managed to produce more efficient cells, using passivated contacts of made doped poly-Si or a-Si:H and a passivating intrinsic interlayer in all cases. Common to these designs is the need to passivate the layer stack with hydrogen. In this contribution, we perform a systematic study of passivated contact passivation by hydrogen, using poly-Si/SiOx passivated contacts on n-Cz-Si, and ALD Al2O3 followed by a forming gas anneal (FGA) as the hydrogen source. We study p-type and n-type passivated contacts with implied Voc exceeding 690 and 720 mV, respectively, and perform either the ALD step or the FGA with deuterium instead of hydrogen in order to separate the two processes via SIMS. By examining the deuterium concentration at the SiOx in both types of samples, we demonstrate that the FGA supplies negligible hydrogen species to the SiOx, regardless of whether the FGA is hydrogenated or deuterated. Instead, it supplies the thermal energy needed for hydrogen species in the Al2O3 to diffuse there. Furthermore, the concentration of hydrogen species at the SiOx can saturate while implied Voc continues to increase, showing that the energy from the FGA is also required for hydrogen species already at the SiOx to find recombination-active defects to passivate.

  20. Stable iron isotope fractionation between aqueous Fe(II) and model Archean ocean Fe-Si coprecipitates and implications for iron isotope variations in the ancient rock record

    Science.gov (United States)

    Wu, Lingling; Percak-Dennett, Elizabeth M.; Beard, Brian L.; Roden, Eric E.; Johnson, Clark M.

    2012-05-01

    Iron isotope fractionation between aqueous Fe(II) (Fe(II)aq) and two amorphous Fe(III) oxide-Si coprecipitates was investigated in an aqueous medium that simulated Archean marine conditions, including saturated amorphous silica, low sulfate, and zero dissolved oxygen. The equilibrium isotope fractionation (in 56Fe/54Fe) between Fe(II)aq and Fe(III)-Si coprecipitates at circum-neutral pH, as inferred by the three-isotope method, was -3.51 ± 0.20 (2σ)‰ and -3.99 ± 0.17 (2σ)‰ for coprecipitates that had Fe:Si molar ratios of 1:2 and 1:3, respectively. These results, when combined with earlier work, indicate that the equilibrium isotope fractionation factor between Fe(II)aq and Fe(III)-Si coprecipitates changes as a function of Fe:Si ratio of the solid. Isotopic fractionation was least negative when Fe:Si = 1:1 and most negative when Fe:Si = 1:3. This change corresponds with changes in the local structure of iron, as revealed by prior spectroscopic studies. The kinetics of isotopic exchange was controlled by movement of Fe(II) and Si, where sorption of Fe(II) from aqueous to solid phase facilitated atom exchange, but sorption of Si hindered isotopic exchange through blockage of reactive surface sites. Although Fe(II)-Fe(III) isotopic exchange rates were a function of solid and solution compositions in the current study, in all cases they were much higher than that determined in previous studies of aqueous Fe(III) and ferrihydrite interaction, highlighting the importance of electron exchange in promoting Fe atom exchange. When compared to analogous microbial reduction experiments of overlapping Fe(II) to Fe(III) ratios, isotopic exchange rates were faster in the biological experiments, likely due to promotion of atom exchange by the solid-phase Fe(II) produced in the biological experiments. These results provide constraints for interpreting the relatively large range of Fe isotope compositions in Precambrian marine sedimentary rocks, and highlight important

  1. Production of Rare Earth Isotope Beams for Radiotracer-DLTS on SiC

    CERN Multimedia

    2002-01-01

    Electrical properties of semiconductors are extremely sensitive to minor traces of impurities and defects. This fact allows to intentionally modify material properties and is thus the very basis of semiconductor electronics and optoelectronics. In the present project, electronic properties and doping effects of rare-earth elements in the technologically important semiconductor SiC are to be investigated using optical and electrical characterization techniques like Photoluminescence, Deep Level Transient Spectroscopy and Thermal Admittance Spectroscopy. By using the elemental transmutation of radioactive isotopes as a tracer, it will be guaranteed that the impurity-related band gap states can definitively be distinguished from intrinsic or process-induced defects. For SiC up to now only detailed investigation of Er- related deep levels have been reported, preliminary data exist for Sm- and Gd- impurities. In this project we propose the implantation of Pr and Eu isotopes for detailed level studies.

  2. Engine Torque Control of SI Engine using Linear Quadratic Integral Tracking (LQIT Optimal Control

    Directory of Open Access Journals (Sweden)

    Aris Triwiyatno

    2011-11-01

    Full Text Available Due to the needs of improving fuel economy and reducing emissions, it is increasingly important to achieve control over robustness behavior and meet performance objectives over the life of the vehicle. This requires the development of high performance and optimal power train controllers. The performance objectives are often conflicting, or at least interrelated. One way to potentially meet these performance requirements is to introduce a method of controlling engine torque of Spark Ignition (SI engine using Linear Quadratic Integral Tracking (LQIT optimal control. The goal is to develop simple algorithms which can control engine torque well, thus providing fuel control more efficient and simultaneously improving engine performance due to the needs of the driver based on throttle opening information. In this case, spark ignition engine with automatic transmission simulation model is used to meet a good performance under this controller design.

  3. Experimental investigation of Methanol blends with gasoline on SI engine

    Directory of Open Access Journals (Sweden)

    Gaurav tiwari

    2014-10-01

    Full Text Available Automobile have become a very important part of our modern life style. And it runs on fossil fuel. But the excessive use of fossil fuels will very soon leads to the energy crises so the future of automobile based on fossil fuels has been badly affected by two major problems. That is less availability of fuel and environmental degradation. So it is very important to found some new renewable non polluting alternative fuels to ensure the proper and safe survival of internal combustion engines. In present study we evaluate the performance of two stroke single cylinder spark ignition engine with ratio of 10%, 20% and 30% of methanol and gasoline by volume. Performance parameters (brake thermal efficiency, brake specific energy consumption and brake specific fuel consumption were determined at various loads on engine with methanol blended gasoline. The comparison was made on performance of conventional SI engine with pure gasoline operation. As a result, brake thermal efficiency and brake specific fuel consumption showed improved performance when compared with pure gasoline performances.

  4. The use of gaseous fuels mixtures for SI engines propulsion

    Science.gov (United States)

    Flekiewicz, M.; Kubica, G.

    2016-09-01

    Paper presents results of SI engine tests, carried on for different gaseous fuels. Carried out analysis made it possible to define correlation between fuel composition and engine operating parameters. Tests covered various gaseous mixtures: of methane and hydrogen and LPG with DME featuring different shares. The first group, considered as low carbon content fuels can be characterized by low CO2 emissions. Flammability of hydrogen added in those mixtures realizes the function of combustion process activator. That is why hydrogen addition improves the energy conversion by about 3%. The second group of fuels is constituted by LPG and DME mixtures. DME mixes perfectly with LPG, and differently than in case of other hydrocarbon fuels consists also of oxygen makes the stoichiometric mixture less oxygen demanding. In case of this fuel an improvement in engine volumetric and overall engine efficiency has been noticed, when compared to LPG. For the 11% DME share in the mixture an improvement of 2% in the efficiency has been noticed. During the tests standard CNG/LPG feeding systems have been used, what underlines utility value of the research. The stand tests results have been followed by combustion process simulation including exhaust forming and charge exchange.

  5. Understanding the mechanisms of Si-K-Ca glass alteration using silicon isotopes

    Science.gov (United States)

    Verney-Carron, Aurélie; Sessegolo, Loryelle; Saheb, Mandana; Valle, Nathalie; Ausset, Patrick; Losno, Rémi; Mangin, Denis; Lombardo, Tiziana; Chabas, Anne; Loisel, Claudine

    2017-04-01

    It is important to understand glass alteration mechanisms and to determine their associated kinetics in order to develop models able to predict the alteration of nuclear, basaltic or archaeological glasses. Recent studies revealed that the respective contributions of diffusion, dissolution, condensation and precipitation processes in alteration are still a matter for debate. In this work, the alteration of a medieval-type glass (Si-K-Ca) was investigated as it presents a specific composition (without B and with low Al). Experiments were performed using a dynamic device, at 30 °C, at pH 8 and 9 and during 1 month in order to simulate alteration in contact with water (rainfall or condensation). The solution was doped in 29Si to discriminate between the silicon from glass (mainly 28Si) and from solution. The results showed that the external region of the alteration layer is devoid of modifier cations (K, Ca) and presents a 29Si/28Si ratio close to the solution one. This excludes that the alteration layer is a glass skeleton and highlights a progressive hydrolysis/condensation process, even if non-hydrolyzed silica tetrahedra could remain when the Si isotopic equilibrium is not reached. The internal zone appears to be gradually depleted in modifier cations and partly enriched in 29Si, but the thickness of this zone is overestimated using SEM-EDS and SIMS techniques. Even if in these experiments the dissolution mechanism is favored, the contribution of interdiffusion cannot be neglected to explain the weathering of ancient stained glassed windows in the atmosphere. The respective contribution of diffusion and dissolution are also discussed as a function of glass composition and surface texture, as well as of experimental conditions (alkaline pH, renewal of the solution).

  6. Tensor-force-driven Jahn-Teller effect and shape transitions in exotic Si isotopes

    CERN Document Server

    Utsuno, Yutaka; Brown, B Alex; Honma, Michio; Mizusaki, Takahiro; Shimizu, Noritaka

    2012-01-01

    We show how the shape evolution of the neutron-rich exotic Si and S isotopes can be understood as a Jahn-Teller effect that comes in part from the tensor-driven evolution of single-particle energies. The detailed calculations we present are in excellent agreement with known experimental data, and we point out of new features that should be explored in new experiments. Potential energy surfaces are used to understand the shape evolutions. The sub-shell closed nucleus, $^{42}$Si, is shown to be a perfect example of a strongly oblate shape instead of a sphere through a robust Jahn-Teller mechanism. The distribution of spectroscopic factors measured by $^{48}$Ca(e,e'p) experiment is shown to be well described, providing a unique test on the tensor-driven shell evolution.

  7. Spatially controlled Fe and Si isotope variations: an alternative view on the formation of the Torres del Paine pluton

    Science.gov (United States)

    Gajos, Norbert A.; Lundstrom, Craig C.; Taylor, Alexander H.

    2016-11-01

    We present new Fe and Si isotope ratio data for the Torres del Paine igneous complex in southern Chile. The multi-composition pluton consists of an approximately 1 km vertical exposure of homogenous granite overlying a contemporaneous 250-m-thick mafic gabbro suite. This first-of-its-kind spatially dependent Fe and Si isotope investigation of a convergent margin-related pluton aims to understand the nature of granite and silicic igneous rock formation. Results collected by MC-ICP-MS show a trend of increasing δ56Fe and δ30Si with increasing silica content as well as a systematic increase in δ56Fe away from the mafic base of the pluton. The marginal Torres del Paine granites have heavier Fe isotope signatures (δ56Fe = +0.25 ± 0.02 2se) compared to granites found in the interior pluton (δ56Fe = +0.17 ± 0.02 2se). Cerro Toro country rock values are isotopically light in both Fe and Si isotopic systems (δ56Fe = +0.05 ± 0.02 ‰; δ30Si = -0.38 ± 0.07 ‰). The variations in the Fe and Si isotopic data cannot be accounted for by local assimilation of the wall rocks, in situ fractional crystallization, late-stage fluid exsolution or some combination of these processes. Instead, we conclude that thermal diffusion or source magma variation is the most likely process producing Fe isotope ratio variations in the Torres del Paine pluton.

  8. Si isotope fractionation between Si-poor metal and silicate melt at pressure-temperature conditions relevant to metal segregation in small planetary bodies

    Science.gov (United States)

    Kempl, J.; Vroon, P. Z.; Zinngrebe, E.; van Westrenen, W.

    2013-04-01

    Experimental investigations of Si isotope fractionation between Si-bearing metal alloy and silicate phases have to date been limited to high pressure (1-7 GPa) and high temperature (1800-2200 °C) conditions at highly reducing conditions, to optimize applicability of results to early core formation processes in the Earth. Here, we assess the extent and mechanism of Si isotopic fractionation at conditions relevant to metal segregation in small (km-scale) planetary bodies, using samples obtained from an industrial-scale blast furnace of Tata Steel (IJmuiden, the Netherlands). During the low-pressure, high-temperature process of steelmaking inhomogeneous blast furnace burden consisting of pre- and untreated iron ore, iron silicates and coke is reduced to oxygen fugacities near the C-CO buffer, resulting in the segregation of a metal phase containing only ∼0.3 wt% Si. Seven sample sets, each comprising a metal alloy and a silicate slag, were taken during tapping of the blast furnace at tapping temperatures between 1400 °C and 1600 °C. We find large isotopic mass fractionation between metal and silicate, with Δ30Sisilicate-metal varying between 0.7‰ and 1.6‰, values that are as high as previously obtained in high-pressure, highly reduced experiments. A model for metal-silicate Si isotope fractionation in blast furnaces can explain both the sense and magnitude of fractionation, if the presence of SiO-bearing vapour is explicitly taken into account. Our data indicate that significant Si isotope fractionation can occur between metal and silicate at low-pressure, high-temperature and only mildly reducing conditions for which Si solubility in molten Fe-rich metal is low. This suggests an important role for SiO at low confining pressures. Our data can be applied to models of aubrite meteorite formation through high-temperature differentiation of an enstatite chondrite parent body. Our calculations suggest a far larger degree of rehomogenisation during differentiation

  9. Fe stable isotope fractionation in modern and ancient hydrothermal Fe-Si deposits

    Science.gov (United States)

    Moeller, K.; Schoenberg, R.; Thorseth, I. H.; Øvreås, L.; Pedersen, R.

    2010-12-01

    Modern iron-silica deposits of small yellow to rust coloured mounds and chimney-like structures were found in a low-temperature venting area distal to a white smoker type hydrothermal vent site at the south-western part of the Mohns Ridge, North Atlantic. Individual stratified mm to cm thick laminated layers within these structures are largely composed of branching, twisted filaments resembling encrusted stalks of Fe-oxidising bacteria. DNA analyses have confirmed the presence of both Fe-oxidising (Mariprofundus ferrooxidans and other ζ-Proteobacteria) and Fe-reducing bacteria (Shewanellaceae). Similar morphologic features, such as several mm thick red hematite-rich laminae and micron-scale filamentous structures concentrated in discrete laminae, have also been found in Early Ordovician volcanogenic massive sulphide (VMS) hosted jasper deposits in the Løkken-Høydal area, Norway [1]. These filamentous structures are believed to be formed by Fe-oxidising bacteria similar to Mariprofundus ferrooxidans [2]. Here, we compare the Fe isotope composition of these two different types of Fe-Si deposits with the aim to gain further information about deposition mechanisms and the role of microorganisms in Fe redox cycling of deep-sea hydrothermal systems. Fe isotope compositions of the modern biogenic Fe-Si deposit vary between -2.09 and -0.66 ‰ in δ56Fe values, a range that is comparable to late Archaean to early Proterozoic banded iron formations. The ~490 Ma old Løkken jaspers show a similar variation, but with significantly higher δ56Fe values ranging from -0.39 to +0.89 ‰. The Fe isotopic composition of the Løkken jaspers clearly correlates with morphological features with the lowest δ56Fe values in layered and the highest ones in brecciform jaspers. Our data demonstrate that variations in Fe isotope compositions of the modern Fe-Si deposit cannot be explained by a single process, but rather reflect the full complexity of Fe redox cycling within deep

  10. Isotopic fingerprints of gold-containing luminescence centers in 28Si

    CERN Document Server

    Steger, M; Sekiguchi, T; Saeedi, K; Thewalt, M L W; Henry, M O; Johnston, K; Riemann, H; Abrosimov, N V; Churbanov,; Gusev, A V; Bulanov, A D; Kaliteevski, I D; Godisov, O N; Becker, P; Pohl, H J

    2009-01-01

    We have recently shown that the dramatic reduction in linewidth of many deep luminescence centers in highly enriched 28Si can lead to the observation of isotopic fingerprints, revealing not only that a specific element is involved in the defect complex, but also the number of atoms of that element. This has led to many surprises regarding the actual constituents of supposedly well known luminescence centers, as well as the discovery of new members of a family of four-atom centers where the constituents can be chosen from Cu, Ag, Au and Li. Obtaining the isotopic fingerprint of Au is problematic, since only 197Au is stable, but we have now used the relatively long-lived 195Au to reveal the presence, and the number, of Au atoms in several of these centers. We find a series of four-atom centers containing one Au plus Cu and/or Li. Surprisingly, the Au isotopic fingerprint also reveals a series of five-atom centers containing a single Au plus Cu and/or Li. Further evidence for the ubiquity of these four- and five...

  11. Silicon carbide grains of type C provide evidence for the production of the unstable isotope $^{32}$Si in supernovae

    CERN Document Server

    Pignatari, M; Bertolli, M G; Trappitsch, R; Hoppe, P; Rauscher, T; Fryer, C; Herwig, F; Hirschi, R; Timmes, F X; Thielemann, F -K

    2013-01-01

    Carbon-rich grains are observed to condense in the ejecta of recent core-collapse supernovae, within a year after the explosion. Silicon carbide grains of type X are C-rich grains with isotpic signatures of explosive supernova nucleosynthesis have been found in primitive meteorites. Much rarer silicon carbide grains of type C are a special sub-group of SiC grains from supernovae. They show peculiar abundance signatures for Si and S, isotopically heavy Si and isotopically light S, which appear to to be in disagreement with model predictions. We propose that C grains are formed mostly from C-rich stellar material exposed to lower SN shock temperatures than the more common type X grains. In this scenario, extreme $^{32}$S enrichments observed in C grains may be explained by the presence of short-lived $^{32}$Si ($\\tau$$_{1/2}$ = 153 years) in the ejecta, produced by neutron capture processes starting from the stable Si isotopes. No mixing from deeper Si-rich material and/or fractionation of Si from S due to mole...

  12. Silicon isotope fractionation during microbial reduction of Fe(III)-Si gels under Archean seawater conditions and implications for iron formation genesis

    Science.gov (United States)

    Reddy, Thiruchelvi R.; Zheng, Xin-Yuan; Roden, Eric E.; Beard, Brian L.; Johnson, Clark M.

    2016-10-01

    Microbial dissimilatory iron reduction (DIR) is a deeply rooted metabolism in the Bacteria and Archaea. In the Archean and Proterozoic, the most likely electron acceptor for DIR in marine environments was Fe(III)-Si gels. It has been recently suggested that the Fe and Si cycles were coupled through sorption of aqueous Si to iron oxides/hydroxides, and through release of Si during DIR. Evidence for the close association of the Fe and Si cycles comes from banded iron formations (BIFs), which consist of alternating bands of Fe-bearing minerals and quartz (chert). Although there has been extensive study of the stable Fe isotope fractionations produced by DIR of Fe(III)-Si gels, as well as studies of stable Fe isotope fractionations in analogous abiologic systems, no studies to date have investigated stable Si isotope fractionations produced by DIR. In this study, the stable Si isotope fractionations produced by microbial reduction of Fe(III)-Si gels were investigated in simulated artificial Archean seawater (AAS), using the marine iron-reducing bacterium Desulfuromonas acetoxidans. Microbial reduction produced very large 30Si/28Si isotope fractionations between the solid and aqueous phase at ˜23 °C, where Δ30Sisolid-aqueous isotope fractionations of -3.35 ± 0.16‰ and -3.46 ± 0.09‰ were produced in two replicate experiments at 32% Fe(III) reduction (solid-phase Fe(II)/FeTotal = 0.32). This isotopic fractionation was substantially greater than that observed in two abiologic controls that had solid-phase Fe(II)/FeTotal = 0.02-0.03, which produced Δ30Sisolid-aqueous isotope fractionations of -2.83 ± 0.24‰ and -2.65 ± 0.28‰. In a companion study, the equilibrium Δ30Sisolid-aqueous isotope fractionation was determined to be -2.3‰ for solid-phase Fe(II)/FeTotal = 0. Collectively, these results highlight the importance of Fe(II) in Fe-Si gels in producing large changes in Si isotope fractionations. These results suggest that DIR should produce highly

  13. Usage of burnt fuel isotopic compositions from engineering codes in Monte-Carlo code calculations

    Energy Technology Data Exchange (ETDEWEB)

    Aleshin, Sergey S.; Gorodkov, Sergey S.; Shcherenko, Anna I. [Nuclear Research Centre ' ' Kurchatov Institute' ' , Moscow (Russian Federation)

    2015-09-15

    A burn-up calculation of VVER's cores by Monte-Carlo code is complex process and requires large computational costs. This fact makes Monte-Carlo codes usage complicated for project and operating calculations. Previously prepared isotopic compositions are proposed to use for the Monte-Carlo code (MCU) calculations of different states of VVER's core with burnt fuel. Isotopic compositions are proposed to calculate by an approximation method. The approximation method is based on usage of a spectral functionality and reference isotopic compositions, that are calculated by engineering codes (TVS-M, PERMAK-A). The multiplication factors and power distributions of FA and VVER with infinite height are calculated in this work by the Monte-Carlo code MCU using earlier prepared isotopic compositions. The MCU calculation data were compared with the data which were obtained by engineering codes.

  14. Towards H-infinity Control of an SI Engine's A/F Ratio

    DEFF Research Database (Denmark)

    Vigild, Christian; Struwe, Michael; Andersen, Karsten

    1999-01-01

    Long term stoichiometric Air/Fuel Ratio (AFR) control of an SI engine is at the present mainly maintained by table mapping of the engine's fresh air intake as a function of the engine operating point. In order to reduce a stationary error in the AFR to zero the table based control normally works ...

  15. Isotopic fingerprints of Pt-containing luminescence centers in highly enriched Si-28

    CERN Document Server

    Steger, M; Godisov, O N; Alves, E; Kaliteevskii, A K; Saeedi, K; Abrosimov, N V; Churbanov, M F; Gusev, A V; Johnston, K; Thewalt, M L W; Sekiguchi, T; Yang, A; Riemann, H; Henry, M O; Pohl, H -J; Wahl, U

    2010-01-01

    Recently we have shown that the reduction in the photoluminescence linewidth of many deep luminescence centers in highly enriched Si-28 results in well-resolved isotopic fingerprints. This allows for a better characterization of a defect center, as not only the involvement of a specific element but also the number of atoms of that element within the complex can be determined. Surprisingly, we have found that many well-known luminescence centers have a different composition than originally supposed. In addition, we have found a large number of four- and five-atom luminescence centers involving the elements Cu, Au, and Li. Here we introduce series of four- and five-atom deep luminescence centers involving a single Pt atom together with Cu and Li, similar to what has been seen previously for Au-containing luminescence centers.

  16. Characterizing SI Engine Transient Fuel Consumption in ALPHA

    Science.gov (United States)

    Examine typical transient engine operation encountered over the EPA's vehicle and engine testing drive cycles to characterize that transient fuel usage, and then describe the changes made to ALPHA to better model transient engine operation.

  17. Characterizing SI Engine Transient Fuel Consumption in ALPHA

    Science.gov (United States)

    Examine typical transient engine operation encountered over the EPA's vehicle and engine testing drive cycles to characterize that transient fuel usage, and then describe the changes made to ALPHA to better model transient engine operation.

  18. Surface engineering of SiC via sublimation etching

    Science.gov (United States)

    Jokubavicius, Valdas; Yazdi, Gholam R.; Ivanov, Ivan G.; Niu, Yuran; Zakharov, Alexei; Iakimov, Tihomir; Syväjärvi, Mikael; Yakimova, Rositsa

    2016-12-01

    We present a technique for etching of SiC which is based on sublimation and can be used to modify the morphology and reconstruction of silicon carbide surface for subsequent epitaxial growth of various materials, for example graphene. The sublimation etching of 6H-, 4H- and 3C-SiC was explored in vacuum (10-5 mbar) and Ar (700 mbar) ambient using two different etching arrangements which can be considered as Si-C and Si-C-Ta chemical systems exhibiting different vapor phase stoichiometry at a given temperature. The surfaces of different polytypes etched under similar conditions are compared and the etching mechanism is discussed with an emphasis on the role of tantalum as a carbon getter. To demonstrate applicability of such etching process graphene nanoribbons were grown on a 4H-SiC surface that was pre-patterned using the thermal etching technique presented in this study.

  19. Shape transitions in exotic Si and S isotopes and tensor-force-driven Jahn-Teller effect

    CERN Document Server

    Utsuno, Yutaka; Brown, B Alex; Honma, Michio; Mizusaki, Takahiro; Shimizu, Noritaka

    2012-01-01

    We show how shape transitions in the neutron-rich exotic Si and S isotopes occur in terms of shell-model calculations with a newly constructed Hamiltonian based on V_MU interaction. We first compare the calculated spectroscopic-strength distributions for the proton 0d_5/2,3/2 and 1s_1/2 orbitals with results extracted from a 48Ca(e,e'p) experiment to show the importance of the tensor-force component of the Hamiltonian. Detailed calculations for the excitation energies, B(E2) and two-neutron separation energies for the Si and S isotopes show excellent agreement with experimental data. The potential energy surface exhibits rapid shape transitions along the isotopic chains towards N=28 that are different for Si and S. We explain the results in terms of an intuitive picture involving a Jahn-Teller-type effect that is sensitive to the tensor-force-driven shell evolution. The closed sub-shell nucleus 42Si is a particularly good example of how the tensor-force-driven Jahn-Teller mechanism leads to a strong oblate ra...

  20. The effect of permafrost, vegetation, and lithology on Mg and Si isotope composition of the Yenisey River and its tributaries at the end of the spring flood

    Science.gov (United States)

    Mavromatis, Vasileios; Rinder, Thomas; Prokushkin, Anatoly S.; Pokrovsky, Oleg S.; Korets, Mikhail A.; Chmeleff, Jérôme; Oelkers, Eric H.

    2016-10-01

    This work focuses on the behavior of the stable Mg and Si isotope compositions of the largest Arctic river, the Yenisey River and 28 of its major and minor tributaries during the spring flood period. Samples were collected along a 1500 km latitudinal profile covering a wide range of permafrost, lithology, and vegetation. Despite significant contrasts in the main physico-geographical, climate, and lithological parameters of the watersheds, the isotope composition of both dissolved Mg and Si was found to be only weakly influenced by the degree of the permafrost coverage, type of vegetation (forest vs. tundra), and lithology (granites, basalts, carbonates or terrigenous rocks). This observation is generally consistent with the lack of chemical uptake of Mg and Si by soil mineral formation and vegetation during the early spring. The radiogenic Sr isotope composition of the Yenisey and its tributaries varied within a narrow range (0.708 ⩽ 87Sr/86Sr ⩽ 0.711) reflecting the dominance of Phanerozoic rock weathering and/or atmospheric deposition on these compositions. The Mg and Si isotopic compositions of riverine samples reflect two main processes with distinct isotopic signatures. First, isotopically heavier Mg (δ26Mg = -1.0 ± 0.2‰) and isotopically lighter Si (δ30Si = 1.0 ± 0.25‰) are added to the waters by river suspended matter dissolution and leaching from vegetation biomass/topsoil litter. Second, isotopically lighter Mg (δ26Mg = -1.5 to -1.75‰) and isotopically heavier Si (δ30Si = 1.75-2.0‰) are delivered to the Yenisey's tributaries from deep underground water feeding the rivers via taliks. This lighter Mg and heavier Si isotopic composition is interpreted to originate from Precambrian dolomite dissolution and aluminosilicate dissolution coupled with authigenic mineral precipitation, respectively, in deep underground water reservoirs. Taking account of the isotopic composition evolution over the course of the year established earlier on mono

  1. Mean Value Modelling of an SI Engine with EGR

    DEFF Research Database (Denmark)

    Føns, Michael; Muller, Martin; Chevalier, Alain

    1999-01-01

    Mean Value Engine Models (MVEMs) are simplified, dynamic engine models which are physically based. Such models are useful for control studies, for engine control system analysis and for model based control systems. Very few published MVEMs have included the effects of Exhaust Gas Recirculation (E...

  2. Large isotopic anomalies of Si, C, N and noble gases in interstellar silicon carbide from the Murray meteorite

    Science.gov (United States)

    Zinner, E.; Ming, T.; Anders, E.

    1987-12-01

    Primitive meteorites contain several noble gas components with anomalous isotopic compositions which imply that they - and their solid 'carrier' phases - are of exotic, pre-solar origin. The authors found that minor fractions of the Murray meteorite contain two minerals not previously seen in meteorites: silicon carbide and an amorphous Si-O phase. They report ion microprobe analyses of these phases which reveal very large isotopic anomalies in silicon, nitrogen and carbon, exceeding the highest anomalies previously measured by factors of up to ≡50. It is concluded that these phases are circumstellar grains from carbon-rich stars, whose chemical inertness allowed them to survive in exceptionally well-preserved form.

  3. Laser photochemical lead isotopes separation for harmless nuclear power engineering

    Science.gov (United States)

    Bokhan, P. A.; Fateev, N. V.; Kim, V. A.; Zakrevsky, D. E.

    2016-09-01

    The collisional quenching of the metastable 3 P 1,2 and 1 D 2 lead atoms is studied experimentally in the gas flow of the lead atoms, reagent-molecules and a carrier gas Ar. The experimental parameters were similar to the conditions that are required in the operation of the experimental setup for photochemical isotope separation. Excited atoms are generated under electron impact conditions created by a gas glow discharge through the mixture of gases and monitored photoelectrically by attenuation of atomic resonance radiation from hollow cathode 208Pb lamp. The decay of the excited atoms has been studied in the presence various molecules and total cross section data are reported. The flow tube measurements has allowed to separate the physical and chemical quenching channels and measure the rates of the chemical reaction excited lead with N2O, CH2Cl2, SF6 and CuBr molecules. These results are discussed in the prospects of the obtaining isotopically modified lead as a promising coolant in the reactors on the fast-neutron.

  4. Improvement of hydrogen isotope exchange reactions on Li4SiO4 ceramic pebble by catalytic metals

    Institute of Scientific and Technical Information of China (English)

    Cheng Jian Xiao; Chun Mei Kang; Xiao Jun Chen; Xiao Ling Gao; Yang Ming Luo; Sheng Hu; Xiao Lin Wang

    2012-01-01

    Li4SiO4 ceramic pebble is considered as a candidate tritium breeding material of Chinese Helium Cooled Solid Breeder Test Blanket Module (CH HCSB TBM) for the International Thermonuclear Experimental Reactor (ITER).In this paper,Li4SiO4 ceramic pebbles deposited with catalytic metals,including Pt,Pd,Ru and Ir,were prepared by wet impregnation method.The metal particles on Li4SiO4 pebble exhibit a good promotion of hydrogen isotope exchange reactions in H2-DzO gas system,with conversion equilibrium temperature reduction of 200-300 ℃.The out-of-pile tritium release experiments were performed using 1.0 wt% Pt/Li4SiO4 and Li4SiO4 pebbles irradiated in a thermal neutron reactor.The thermal desorption spectroscopy shows that Pt was effective to increase the tritium release rate at lower temperatures,and the ratio of tritium molecule (HT) to tritiated water (HTO) of 1.0 wt% Pt/Li4SiO4 was much more than that of Li4SiO4,which released mainly as HTO.Thus,catalytic metals deposited on Li4SiO4 pebble may help to accelerate the recovery of bred tritium particularly in low temperature region,and increase the tritium molecule form released from the tritium breeding materials.

  5. Carrier Mobility Enhancement of Tensile Strained Si and SiGe Nanowires via Surface Defect Engineering.

    Science.gov (United States)

    Ma, J W; Lee, W J; Bae, J M; Jeong, K S; Oh, S H; Kim, J H; Kim, S-H; Seo, J-H; Ahn, J-P; Kim, H; Cho, M-H

    2015-11-11

    Changes in the carrier mobility of tensile strained Si and SiGe nanowires (NWs) were examined using an electrical push-to-pull device (E-PTP, Hysitron). The changes were found to be closely related to the chemical structure at the surface, likely defect states. As tensile strain is increased, the resistivity of SiGe NWs deceases in a linear manner. However, the corresponding values for Si NWs increased with increasing tensile strain, which is closely related to broken bonds induced by defects at the NW surface. Broken bonds at the surface, which communicate with the defect state of Si are critically altered when Ge is incorporated in Si NW. In addition, the number of defects could be significantly decreased in Si NWs by incorporating a surface passivated Al2O3 layer, which removes broken bonds, resulting in a proportional decrease in the resistivity of Si NWs with increasing strain. Moreover, the presence of a passivation layer dramatically increases the extent of fracture strain in NWs, and a significant enhancement in mobility of about 2.6 times was observed for a tensile strain of 5.7%.

  6. Emission and Combustion Characteristics of Si Engine Working Under Gasoline Blended with Ethanol Oxygenated Organic Compounds

    Directory of Open Access Journals (Sweden)

    Dhanapal Balaji

    2010-01-01

    Full Text Available Problem statement: The objective of this study is to investigate the effect of using unleaded gasoline and additives blends on Spark Ignition engine (SI engine combustion and exhaust emission. Approach: A four stroke, single cylinder SI engine was used for conducting this study. Exhaust emissions were analysed for Carbon Monoxide (CO, Hydrocarbon (HC and Oxides of Nitrogen (NOx and carbon dioxide (CO2 using unleaded gasoline and additives blends with different percentages of fuel at varying engine torque condition and constant engine speed. Results: The result showed that the blending of unleaded gasoline increases the octane number and power output this may leads to increase the brake thermal efficiency. The CO, HC and NOx emissions concentrations in the engine exhaust decreases while the CO2 concentration increases. Conclusion: Using ethanol as a fuel additive to unleaded gasoline causes an improvement in combustion characteristics and significant reduction in exhaust emissions.

  7. Performance and Emission Studies of a SI Engine using Distilled Plastic Pyrolysis Oil-Petrol Blends

    OpenAIRE

    Kumar Kareddula Vijaya; Puli Ravi Kumar; Swarna Kumari A.; Shailesh P.

    2016-01-01

    In the present work, an experimental investigation is carried out to evaluate the use of plastic oil derived from waste plastic which used in a Spark Ignition engine. Experiments are conducted, the measured performance and emissions of plastic oil blends at different proportions are compared with the baseline operation of the SI engine running with gasoline fuel. Engine performance and exhaust gas emissions such as carbon monoxide, total unburned hydrocarbons, carbon dioxide and oxides of nit...

  8. 40 CFR 1045.610 - What provisions apply to using engines already certified to Small SI emission standards?

    Science.gov (United States)

    2010-07-01

    ... already certified to Small SI emission standards? 1045.610 Section 1045.610 Protection of Environment... engines already certified to Small SI emission standards? This section applies to marine engines that are identical to land-based engines certified under 40 CFR part 90 or 1054. See § 1045.605 for provisions...

  9. Alternative Observers for SI Engine Air/Fuel Ratio Control

    DEFF Research Database (Denmark)

    Hendricks, Elbert; Poulsen, Jannik; Olsen, Mads Bruun

    1996-01-01

    sensors other than a MAP sensor. In this paper it is shown that it is possible to construct a family of alternative nonlinear observers which “naturally” allow the use of any given air mass flow related sensor or a combination of them for A/F ratio control. This new family of observers provides the SI...

  10. Engineering helimagnetism in MnSi thin films

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, S. L.; Hesjedal, T., E-mail: Thorsten.Hesjedal@physics.ox.ac.uk [Department of Physics, Clarendon Laboratory, University of Oxford, Oxford, OX1 3PU (United Kingdom); Chalasani, R.; Kohn, A. [Department of Materials Science and Engineering, Tel Aviv University, Ramat Aviv 6997801, Tel Aviv (Israel); Baker, A. A. [Department of Physics, Clarendon Laboratory, University of Oxford, Oxford, OX1 3PU (United Kingdom); Magnetic Spectroscopy Group, Diamond Light Source, Didcot, OX11 0DE (United Kingdom); Steinke, N.-J. [ISIS, Harwell Science and Innovation Campus, Didcot, Oxfordshire, OX11 0QX (United Kingdom); Figueroa, A. I.; Laan, G. van der [Magnetic Spectroscopy Group, Diamond Light Source, Didcot, OX11 0DE (United Kingdom)

    2016-01-15

    Magnetic skyrmion materials have the great advantage of a robust topological magnetic structure, which makes them stable against the superparamagnetic effect and therefore a candidate for the next-generation of spintronic memory devices. Bulk MnSi, with an ordering temperature of 29.5 K, is a typical skyrmion system with a propagation vector periodicity of ∼18 nm. One crucial prerequisite for any kind of application, however, is the observation and precise control of skyrmions in thin films at room-temperature. Strain in epitaxial MnSi thin films is known to raise the transition temperature to 43 K. Here we show, using magnetometry and x-ray spectroscopy, that the transition temperature can be raised further through proximity coupling to a ferromagnetic layer. Similarly, the external field required to stabilize the helimagnetic phase is lowered. Transmission electron microscopy with element-sensitive detection is used to explore the structural origin of ferromagnetism in these Mn-doped substrates. Our work suggests that an artificial pinning layer, not limited to the MnSi/Si system, may enable room temperature, zero-field skyrmion thin-film systems, thereby opening the door to device applications.

  11. Engineering helimagnetism in MnSi thin films

    Directory of Open Access Journals (Sweden)

    S. L. Zhang

    2016-01-01

    Full Text Available Magnetic skyrmion materials have the great advantage of a robust topological magnetic structure, which makes them stable against the superparamagnetic effect and therefore a candidate for the next-generation of spintronic memory devices. Bulk MnSi, with an ordering temperature of 29.5 K, is a typical skyrmion system with a propagation vector periodicity of ∼18 nm. One crucial prerequisite for any kind of application, however, is the observation and precise control of skyrmions in thin films at room-temperature. Strain in epitaxial MnSi thin films is known to raise the transition temperature to 43 K. Here we show, using magnetometry and x-ray spectroscopy, that the transition temperature can be raised further through proximity coupling to a ferromagnetic layer. Similarly, the external field required to stabilize the helimagnetic phase is lowered. Transmission electron microscopy with element-sensitive detection is used to explore the structural origin of ferromagnetism in these Mn-doped substrates. Our work suggests that an artificial pinning layer, not limited to the MnSi/Si system, may enable room temperature, zero-field skyrmion thin-film systems, thereby opening the door to device applications.

  12. Fe isotope fractionation during Fe(II) oxidation by the marine photoferrotroph Rhodovulum iodosum in the presence of Si - Implications for Precambrian iron formation deposition

    Science.gov (United States)

    Wu, Wenfang; Swanner, Elizabeth D.; Kleinhanns, Ilka C.; Schoenberg, Ronny; Pan, Yongxin; Kappler, Andreas

    2017-08-01

    The iron (Fe) isotopic composition of Precambrian iron formations (IFs), besides providing geological context through its mineralogical properties, was suggested to function as a biosignature that can be used to infer a potential microbial role in the formation of the deposited Fe minerals. Anoxygenic phototrophic Fe(II)-oxidizing bacteria (photoferrotrophs), capable of oxidizing Fe(II) anoxically using light energy, were potentially involved in Fe(II) oxidation in anoxic or suboxic Precambrian oceans. The effect of Si on Fe isotopic fractionation between aqueous Fe(II) and Fe-Si-co-precipitates has been investigated before. However, it is currently unknown how stable Fe isotopes are fractionated during enzymatic Fe(II) oxidation under marine hydrogeochemical conditions, and particularly how the presence of Si affects the Fe isotope composition and the isotopic exchange among different Fe phases. We therefore studied Fe isotope fractionation during Fe(II) oxidation by the marine photoferrotroph Rhodovulum iodosum in simulated Precambrian seawater amended with 1 mM dissolved Si. Our results show that the change in the Fe isotope compositions over time for both the initial aqueous Fe(II) (Feaq) and the Fe(III) precipitates (Feppt) follow a Rayleigh distillation model. Moreover, the fractionation (ε56Feppt-aq) determined independently from either δ56Feaq or δ56Feppt data resulted in a value of 2.3 ± 0.3 (2SD, N = 6). This value differs from the fractionation factor determined previously for Fe(II) oxidation by R. iodosum in the absence of Si, where the fractionation calculated from δ56Feaq (i.e. 0.96-1.18) was different from that calculated from δ56Feppt (1.96-1.98). This difference was attributed to isotopic exchange processes with soluble and sorbed Fe species. The present study suggests that Si present in Precambrian oceans retards Fe isotopic exchange, likely through combined effects of complexation of dissolved Fe species by Si and sorption of Si to Fe

  13. Electrical assistance for S.I. engine idle speed control

    Energy Technology Data Exchange (ETDEWEB)

    Bidan, P.; Kouadio, I.K.; Valentin, M.; Montseny, G.

    1997-07-01

    An original method for improving spark-ignition engine idling conditions, is presented. The proposed solution has the distinctive feature of simultaneously combining the traditional airflow rate control and the usual automobile alternator operating as a synchronous motor in order to provide a fast supplementary torque. Experimental validation of the electric assistance system is carried out on a production engine, and the new method is compared with the standard one in terms of idle stability, fuel consumption and pollution emissions

  14. Experimental investigation of ethanol blends with gasoline on SI engine

    OpenAIRE

    2014-01-01

    Automobile have become a very important part of our modern life style. But the future of automobile based on internal combustion engines has been badly affected by two major problems. That is less availability of fuel and environmental degradation. So it is very important to found some new renewable non polluting alternative fuels to ensure the proper and safe survival of internal combustion engines. In present study we evaluate the performance of two stroke single cylinder sp...

  15. [Solid state isotope hydrogen exchange for deuterium and tritium in human gene-engineered insulin].

    Science.gov (United States)

    Zolotarev, Yu A; Dadayan, A K; Kozik, V S; Gasanov, E V; Nazimov, I V; Ziganshin, R Kh; Vaskovsky, B V; Murashov, A N; Ksenofontov, A L; Haribin, O N; Nikolaev, E N; Myasoedov, N F

    2014-01-01

    The reaction of high temperature solid state catalytic isotope exchange in peptides and proteins under the action of catalyst-activated spillover hydrogen was studied. The reaction of human gene-engineered insulin with deuterium and tritium was conducted at 120-140° C to produce insulin samples containing 2-6 hydrogen isotope atoms. To determine the distribution of the isotope label over tritium-labeled insulin's amino acid residues, oxidation of the S-S bonds of insulin by performic acid was performed and polypeptide chains isolated; then their acid hydrolysis, amino acid analysis and liquid scintillation counts of tritium in the amino acids were conducted. The isotope label was shown to be incorporated in all amino acids of the protein, with the peptide fragment FVNQHLCGSHLVE of the insulin β-chain showing the largest incorporation. About 45% of the total protein isotope label was incorporated in His5 and His10 of this fragment. For the analysis of isotope label distribution in labeled insulin's peptide fragments, the recovery of the S-S bonds by mercaptoethanol, the enzymatic hydrolysis by glutamyl endopeptidase from Bacillus intermedius and HPLC division of the resulting peptides were carried out. Attribution of the peptide fragments formed due to hydrolysis at the Glu-X bond in the β-chain was accomplished by mass spectrometry. Mass spectrometry analysis data of the deuterium-labeled insulin samples' isotopomeric composition showed that the studied solid state isotope exchange reaction equally involved all the protein molecules. Biological studying of tritium-labeled insulin showed its physiological activity to be completely retained.

  16. Interface orbital engineering of large-gap topological states: Decorating gold on a Si(111) surface

    Science.gov (United States)

    Huang, Bing; Jin, Kyung-Hwan; Zhuang, Houlong L.; Zhang, Lizhi; Liu, Feng

    2016-03-01

    Intensive effort has recently been made in search of topological insulators (TIs) that have great potential in spintronics applications. In this paper, a novel concept of overlayer induced interfacial TI phase in conventional semiconductor surface is proposed. The first-principles calculations demonstrate that a p -band-element X (X =In , Bi, and Pb) decorated d -band surface, such as Au/Si(111) surface [X /Au/Si(111)] of an existing experimental system, offers a promising prototype for TIs. Specifically, Bi/Au/Si(111) and Pb/Au/Si(111) are identified to be large-gap TIs. A p -d band inversion mechanism induced by growth of X in the Au/Si(111) surface is revealed to function at different coverage of X with different lattice symmetries, suggesting a general approach of interface orbital engineering of large-gap TIs via tuning the interfacial atomic orbital position of X relative to Au.

  17. Characteristics of Knock in Hydrogen-Oxygen-Argon SI Engine

    Energy Technology Data Exchange (ETDEWEB)

    Killingsworth, N; Rapp, V; Flowers, D; Aceves, S; Chen, J; Dibble, R

    2010-02-23

    A promising approach for improving the efficiency of internal combustion engines is to employ a working fluid with a high specific heat ratio such as the noble gas argon. Moreover, all harmful emissions are eliminated when the intake charge is composed of oxygen, nonreactive argon, and hydrogen fuel. Previous research demonstrated indicated thermal efficiencies greater than 45% at 5.5 compression ratio in engines operating with hydrogen, oxygen, and argon. However, knock limits spark advance and increasing the efficiency further. Conditions under which knock occurs in such engines differs from typical gasoline fueled engines. In-cylinder temperatures using hydrogen-oxygen-argon are higher due to the high specific heat ratio and pressures are lower because of the low compression ratio. Better understanding of knock under these conditions can lead to operating strategies that inhibit knock and allow operation closer to the knock limit. In this work we compare knock with a hydrogen, oxygen, and argon mixture to that of air-gasoline mixtures in a variable compression ratio cooperative fuels research (CFR) engine. The focus is on stability of knocking phenomena, as well as, amplitude and frequency of the resulting pressure waves.

  18. Combustion characteristics of an SI engine fueled with biogas fuel

    Science.gov (United States)

    Chen, Lei; Long, Wuqiang; Song, Peng

    2017-04-01

    An experimental research of the effect of H2 substitution and CO2 dilution on CH4 combustion has been carried out on a spark ignition engine. The results show that H2 addition could improve BMEP, thermal efficiency, CO and THC emissions. NOX emissions increased for higher low heating value (LHV) of H2 than CH4. CO2 dilution could effective reduce NOX emission of H2-CH4 combustion. Although engine performance, thermal efficiency and exhaust get unacceptable under high fuel dilution ratio (F.D.R.) conditions, it could be solved by decreasing F.D.R. and/or increasing hydrogen substitution ratio (H.S.R.).

  19. Performance and Emission Studies of a SI Engine using Distilled Plastic Pyrolysis Oil-Petrol Blends

    Directory of Open Access Journals (Sweden)

    Kumar Kareddula Vijaya

    2016-01-01

    Full Text Available In the present work, an experimental investigation is carried out to evaluate the use of plastic oil derived from waste plastic which used in a Spark Ignition engine. Experiments are conducted, the measured performance and emissions of plastic oil blends at different proportions are compared with the baseline operation of the SI engine running with gasoline fuel. Engine performance and exhaust gas emissions such as carbon monoxide, total unburned hydrocarbons, carbon dioxide and oxides of nitrogen are measured. From the experiments it is observed that 50% Distilled Plastic Pyrolysis Oil (50%DPPO exhibits the substantial enhancement in brake power, brake thermal efficiency and reduction in brake specific fuel consumption running at full load conditions among different blends and pure petrol. There is also noticed decrement of carbon dioxide and unburned hydrocarbons emissions at the same blend. The experimental result shows that plastic oil shall conveniently be used as a substitute to gasoline in the existing SI engines without any modifications.

  20. Zr and Mo isotopic constraints on the origins of unusual types of presolar SiC grains.

    Energy Technology Data Exchange (ETDEWEB)

    Pellin, M. J.; Davis, A. M.; Calaway, W. F.; Lewis, R. S.; Clayton, R. N.; Amari, S.

    2000-03-01

    Although most presolar silicon carbide grains form in asymptotic giant branch red giant stars (the so-called mainstream grains) or supernovae (the X-grains), there are a number of other minor types of grains whose origin is less clear. The dominant mechanisms of heavy element nucleosynthesis, the s-process and r-process, are thought to occur mainly in AGB stars and supernovae, respectively [1], and the isotopic patterns in heavy elements in presolar grains can be used to constrain their origins. We have previously reported that mainstream SiC grains have strong enrichments in the s-process isotopes of Sr, Zr and Mo [2-5] and that X-grains have an unusual Mo isotopic composition that differs from s- and r-process expectations [6,7]. We report here the first measurements of Zr and Mo isotopes in several grains of other rare types that were found in the same mount as the mainstream and X-grains reported previously.

  1. Combustion Chamber Deposits and PAH Formation in SI Engines Fueled by Producer Gas from Biomass Gasification

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper; Henriksen, Ulrik Birk; Schramm, Jesper

    2003-01-01

    Investigations were made concerning the formation of combustion chamber deposits (CCD) in SI gas engines fueled by producer gas. The main objective was to determine and characterise CCD and PAH formation caused by the presence of the light tar compounds phenol and guaiacol in producer gas from an...

  2. Molecular isotopic engineering (MIE): industrial manufacture of naproxen of predetermined stable carbon-isotopic compositions for authenticity and security protection and intellectual property considerations

    Science.gov (United States)

    Jasper, J. P.; Farina, P.; Pearson, A.; Mezes, P. S.; Sabatelli, A. D.

    2016-05-01

    Molecular Isotopic Engineering (MIE) is the directed stable-isotopic synthesis of chemical products for reasons of product identification and of product security, and also for intellectual property considerations. We report here a generally excellent correspondence between the observed and predicted stable carbon-isotopic (δ13C) results for a successful directed synthesis of racemic mixture from its immediate precursors. The observed results are readily explained by the laws of mass balance and isotope mass balance. Oxygen- and hydrogen isotopic results which require an additional assessment of the effects of O and H exchange, presumably due to interaction with water in the reaction solution, are addressed elsewhere. A previous, cooperative study with the US FDA-DPA showed that individual manufacturers of naproxen could readily be differentiated by their stable-isotopic provenance (δ13C, δ18O, and δD ref. 1). We suggest that MIE can be readily employed in the bio/pharmaceutical industry without alteration of present manufacturing processes other than isotopically selecting and/or monitoring reactants and products.

  3. Assessment of The Performance of a Small Capacity SI Engine Fuelled with Model Lean Mixture of Biogas

    OpenAIRE

    Przybyla, Grzegorz Kazimierz; Andrzej SZLEK; Ziolkowski, Lukasz

    2013-01-01

    In this paper the results of the experimental study on the SI engine using biogas will be presented. The experiments were carried out on a petrol engine with a low engine displacement. Typical SI engine was selected in order to evaluate the potential application of gaseous fuel (i.e. biogas). These types of engines are available on a wide scale and commonly used in automotive sector because of the low purchase price and operating costs. It is expected that after minor modifications, the engin...

  4. Circuit-quantum electrodynamics with direct magnetic coupling to single-atom spin qubits in isotopically enriched {sup 28}Si

    Energy Technology Data Exchange (ETDEWEB)

    Tosi, Guilherme, E-mail: g.tosi@unsw.edu.au; Mohiyaddin, Fahd A.; Morello, Andrea, E-mail: a.morello@unsw.edu.au [Centre for Quantum Computation and Communication Technology, School of Electrical Engineering and Telecommunications, UNSW Australia, Sydney, New South Wales 2052, Australia. (Australia); Huebl, Hans [Walther-Meissner-Institut, Bayerische Akademie der Wissenschaften, D-85748 Garching (Germany); Nanosystems Initiative Munich (NIM), Schellingstr. 4, D-80799 Munich, Germany. (Germany)

    2014-08-15

    Recent advances in silicon nanofabrication have allowed the manipulation of spin qubits that are extremely isolated from noise sources, being therefore the semiconductor equivalent of single atoms in vacuum. We investigate the possibility of directly coupling an electron spin qubit to a superconducting resonator magnetic vacuum field. By using resonators modified to increase the vacuum magnetic field at the qubit location, and isotopically purified {sup 28}Si substrates, it is possible to achieve coupling rates faster than the single spin dephasing. This opens up new avenues for circuit-quantum electrodynamics with spins, and provides a pathway for dispersive read-out of spin qubits via superconducting resonators.

  5. Circuit-quantum electrodynamics with direct magnetic coupling to single-atom spin qubits in isotopically enriched 28Si

    Directory of Open Access Journals (Sweden)

    Guilherme Tosi

    2014-08-01

    Full Text Available Recent advances in silicon nanofabrication have allowed the manipulation of spin qubits that are extremely isolated from noise sources, being therefore the semiconductor equivalent of single atoms in vacuum. We investigate the possibility of directly coupling an electron spin qubit to a superconducting resonator magnetic vacuum field. By using resonators modified to increase the vacuum magnetic field at the qubit location, and isotopically purified 28Si substrates, it is possible to achieve coupling rates faster than the single spin dephasing. This opens up new avenues for circuit-quantum electrodynamics with spins, and provides a pathway for dispersive read-out of spin qubits via superconducting resonators.

  6. SiGe-based re-engineering of electronic warfare subsystems

    CERN Document Server

    Lambrechts, Wynand

    2017-01-01

    This book equips readers with a thorough understanding of the applicability of new-generation silicon-germanium (SiGe) electronic subsystems for the military purposes of electronic warfare and defensive countermeasures. The theoretical and technical background is extensively explained and all aspects of the integration of SiGe as an enabling technology for maritime, land, and airborne (including space) electronic warfare are addressed, including research, design, development, and implementation. The coverage is supported by mathematical derivations, informative illustrations, practical examples, and case studies. While SiGe technology provides speed, performance, and price advantages in many markets, sharing of information on its use in electronic warfare systems has to date been limited, especially in developing nations. This book will therefore be warmly welcomed as an engineering guideline that focuses especially on the speed and reliability of current-generation SiGe circuits and highlights emerging innov...

  7. Engineering empty space between Si nanoparticles for lithium-ion battery anodes.

    Science.gov (United States)

    Wu, Hui; Zheng, Guangyuan; Liu, Nian; Carney, Thomas J; Yang, Yuan; Cui, Yi

    2012-02-01

    Silicon is a promising high-capacity anode material for lithium-ion batteries yet attaining long cycle life remains a significant challenge due to pulverization of the silicon and unstable solid-electrolyte interphase (SEI) formation during the electrochemical cycles. Despite significant advances in nanostructured Si electrodes, challenges including short cycle life and scalability hinder its widespread implementation. To address these challenges, we engineered an empty space between Si nanoparticles by encapsulating them in hollow carbon tubes. The synthesis process used low-cost Si nanoparticles and electrospinning methods, both of which can be easily scaled. The empty space around the Si nanoparticles allowed the electrode to successfully overcome these problems Our anode demonstrated a high gravimetric capacity (~1000 mAh/g based on the total mass) and long cycle life (200 cycles with 90% capacity retention).

  8. REAL TIME FUEL INJECTION IN SI ENGINE USING ELECTRONIC INSTRUMENTATION

    Directory of Open Access Journals (Sweden)

    V. VINOTH KUMAR, M.E

    2012-05-01

    Full Text Available To meet the present stringent emission norms. These systems are enerally termed as Electronic Fuel Injection (EFI systems. The fuel is injected into the throttle body or into the inlet manifold through an electronic fuel injector, which is controlled by an Electronic Control Unit (ECU. The quantity of fuel injected by the injector plays a vital role as far as performance and emission characteristics of spark ignition engines are concerned. This paper deals with the static and dynamic fuel injection characteristics of two gasoline fuelinjectors. The effect of different injection parameters like fuel injection pressure, injection duration, supply voltage to injector and engine speed on the quantity of fuel injected have been studied for two injectors. The injection dead time and its variation with respect to fuel pressure and supply voltage to injector have beenanalyzed. Based on the analysis of results, an empirical formula has been obtained to determine the dynamic fuel injection quantity from the static fuel injection characteristics and it was compared with the measured values. It is found that the empirical formula developed in this work gives reasonably good results and therefore, it can be used with confidence for predicting the dynamic characteristics of any given injector from its static injection characteristics.

  9. A statistical combustion phase control approach of SI engines

    Science.gov (United States)

    Gao, Jinwu; Wu, Yuhu; Shen, Tielong

    2017-02-01

    In order to maximize the performance of internal combustion engine, combustion phase is usually controlled to track its desired reference. However, suffering from the cyclic variability of combustion, it is difficulty but meaningful to control mean of combustion phase and constrain its variance. As a combustion phase indicator, the location of peak pressure (LPP) is utilized for real-time combustion phase control in this research. The purpose of the proposed method is to ensure the mean of LPP statistically tracks its reference and constrains the standard deviation of LPP distribution. To achieve this, LPP is first calculated based on the cylinder pressure sensor, and its characteristics are analyzed at the steady-state operating condition, then the distribution of LPP is examined online using hypothesis test criterion. On the basis of the presented statistical algorithm, current mean of LPP is applied in the feedback channel for designing spark advance adjustment law, and the stability of closed-loop system is theoretically ensured according to a steady statistical model. Finally, the proposed strategy is verified on a spark ignition gasoline engine.

  10. Structure of molten CaSiO3: neutron diffraction isotope substitution with aerodynamic levitation and molecular dynamics study.

    Science.gov (United States)

    Skinner, L B; Benmore, C J; Weber, J K R; Tumber, S; Lazareva, L; Neuefeind, J; Santodonato, L; Du, J; Parise, J B

    2012-11-15

    We have performed neutron diffraction isotopic substitution experiments on aerodynamically levitated droplets of CaSiO(3), to directly extract intermediate and local structural information on the Ca environment. The results show a substantial broadening of the first Ca-O peak in the pair distribution function of the melt compared to the glass, which comprises primarily of 6- and 7-fold coordinated Ca-polyhedra. The broadening can be explained by a redistribution of Ca-O bond lengths, especially toward longer distances in the liquid. The first order neutron difference function provides a test of recent molecular dynamics simulations and supports the MD model which contains short chains or channels of edge shared Ca-octahedra in the liquid state. It is suggested that the polymerization of Ca-polyhedra is responsible for the fragile viscosity behavior of the melt and the glass forming ability in CaSiO(3).

  11. The structure of molten CaSiO3: A neutron diffraction isotope substitution and aerodynamic levitation study.

    Energy Technology Data Exchange (ETDEWEB)

    Skinner, Lawrie [State University of New York, Stony Brook; Benmore, Chris J [Argonne National Laboratory (ANL); Weber, Richard [Argonne National Laboratory (ANL); Santodonato, Louis J [ORNL; Tumber, Sonia [Materials Development, Inc., Evanston, IL; Neuefeind, Joerg C [ORNL; Lazareva, Lena [State University of New York, Stony Brook; Du, Jincheng [University of North Texas; Parise, John B [Stony Brook University (SUNY)

    2012-01-01

    We have performed neutron diffraction isotopic substitution experiments on aerodynamically levitated droplets of CaSiO3, to directly extract intermediate and local structural information on the Ca environment. The results show a substantial broadening of the Ca-O peak in the pair distribution function of the melt compared to the glass, which comprises primarily of 6- and 7-fold coordinated Ca-polyhedra. The broadening can be explained by a re-distribution of Ca-O bond lengths, especially towards longer distances in the liquid. The first order neutron difference function provides a rigorous test of recent molecular dynamics simulations and supports the model of the presence of short chains or channels of edge shared Ca-octahedra in the liquid state. It is suggested that the polymerization of Ca-polyhedra is responsible for the fragile viscosity behavior of the melt and the glass forming ability in CaSiO3.

  12. Design and Analysis of Cylinder and Cylinder head of 4-stroke SI Engine for weight reduction

    Directory of Open Access Journals (Sweden)

    Ravindra R. Navthar

    2012-03-01

    Full Text Available The present paper deals with design of cylinder & cylinder head with air cooling system for 4 strokes 4 cylinder SI engine. The main objective of design is to reduce weight to power ratio & will result in producing high specific power. The authors have proposed preliminary design cylinder & cylinder head of a horizontallyopposed SI engine, which develops 120 BHP and posses the maximum rotational speed of 6000rpm. Four stroke opposed engine is inherently well balanced due to opposite location of moving masses and also it provides efficient air cooling. For the requirement of weight reduction the material selected for design of cylinder and cylinder head is Aluminum alloy that is LM-13. The cylinder bore coating using NIKASIL coating was done to improve strength of cylinder with minimum weight..

  13. Work Function Adjustment by Using Dipole Engineering for TaN-Al2O3-Si3N4-HfSiOx-Silicon Nonvolatile Memory

    Directory of Open Access Journals (Sweden)

    Yu-Hsien Lin

    2015-08-01

    Full Text Available This paper presents a novel TaN-Al2O3-HfSiOx-SiO2-silicon (TAHOS nonvolatile memory (NVM design with dipole engineering at the HfSiOx/SiO2 interface. The threshold voltage shift achieved by using dipole engineering could enable work function adjustment for NVM devices. The dipole layer at the tunnel oxide–charge storage layer interface increases the programming speed and provides satisfactory retention. This NVM device has a high program/erase (P/E speed; a 2-V memory window can be achieved by applying 16 V for 10 μs. Regarding high-temperature retention characteristics, 62% of the initial memory window was maintained after 103 P/E-cycle stress in a 10-year simulation. This paper discusses the performance improvement enabled by using dipole layer engineering in the TAHOS NVM.

  14. 40 CFR Table 1 to Subpart Jjjj of... - NOX, CO, and VOC Emission Standards for Stationary Non-Emergency SI Engines ≥100 HP (Except...

    Science.gov (United States)

    2010-07-01

    ... Stationary Non-Emergency SI Engines â¥100 HP (Except Gasoline and Rich Burn LPG), Stationary SI Landfill... Standards for Stationary Non-Emergency SI Engines ≥100 HP (Except Gasoline and Rich Burn LPG), Stationary SI...-Emergency SI Natural Gas b and Non-Emergency SI Lean Burn LPG b 100≤HP HP<130 1/1/2009 c 102.0 3874.0...

  15. Toward complete isotopic analysis of individual presolar silicon carbide grains : C, N, Si, Sr, Zr, Mo, and Ba in single grains of type X.

    Energy Technology Data Exchange (ETDEWEB)

    Pellin, M. J.; Calaway, W. F.; Davis, A. M.; Lewis, R. S.; Amari, S.; Clayton, R. N.

    2000-03-01

    Presolar silicon carbide grains form in a variety of types of stars, including asymptotic giant branch red giant stars and supernovae. The dominant mechanisms of heavy element nucleosynthesis, the s-process and r-process, are thought to occur mainly in AGB stars and supernovae, respectively [1]. We have previously reported that mainstream SiC grains have strong enrichments in the s-process isotopes of Sr, Zr and Mo [2-4] and initial results for X-type SiC grains showing enrichments in the r-process isotopes of Mo[5]. We report here the first measurements of Zr, Sr, and Ba isotopes along with expanded studies of Mo in individual X-type SiC grains, which have previously been identified as having formed from supernova ejects.

  16. Tungsten isotopic compositions in stardust SiC grains from the Murchison meteorite: Constraints on the s-process in the Hf-Ta-W-Re-Os region

    CERN Document Server

    Ávila, J N; Ireland, T R; Gyngard, F; Zinner, E; Cristallo, S; Holden, P; Buntain, J; Amari, S; Karakas, A

    2011-01-01

    We report the first tungsten isotopic measurements in stardust silicon carbide (SiC) grains recovered from the Murchison carbonaceous chondrite. The isotopes 182W, 183W, 184W, 186W and 179Hf, 180Hf were measured on both an aggregate (KJB fraction) and single stardust SiC grains (LS+LU fraction) believed to have condensed in the outflows of low-mass carbon-rich asymptotic giant branch (AGB) stars with close-to-solar metallicity. The SiC aggregate shows small deviations from terrestrial (=solar) composition in the 182W/184W and 183W/184W ratios, with deficits in 182W and 183W with respect to 184W. The 186W/184W ratio, however, shows no apparent deviation from the solar value. Tungsten isotopic measurements in single mainstream stardust SiC grains revealed lower than solar 182W/184W, 183W/184W, and 186W/184W ratios. We have compared the SiC data with theoretical predictions of the evolution of W isotopic ratios in the envelopes of AGB stars. These ratios are affected by the slow neutron-capture process and match...

  17. Unveiling the Si cycle using isotopes in an iron fertilized zone of the Southern Ocean: from mixed layer supply to export

    OpenAIRE

    Closset, Ivia; Cardinal, Damien; Rembauville, Mathieu; Thil, François; Blain, Stéphane

    2016-01-01

    A massive diatom-bloom is observed annually in the surface waters of the naturally Fe-fertilized Kerguelen Plateau (Southern Ocean). In this study, silicon isotopic signatures (δ30Si) of silicic acid (DSi) and suspended biogenic silica (BSi) were investigated in the whole water column with an unprecedented spatial resolution in this region, during the KEOPS-2 experiment (spring 2011). We use δ30Si measurements to track the silicon sources that fuel the bloom, and investigate the seasonal evol...

  18. Ga self-diffusion in isotopically enriched GaAs heterostructures doped with Si and Zn

    Energy Technology Data Exchange (ETDEWEB)

    Norseng, Marshall Stephen [Univ. of California, Berkeley, CA (United States)

    1999-12-01

    This study attempts to advance the modeling of AlGaAs/GaAs/AlAs diffusion by experimental investigation of Ga self-diffusion in undoped, as-grown doped and Zinc diffused structures. We utilize novel, isotopically enriched superlattice and heterostructure samples to provide direct observation and accurate measurement of diffusion with a precision not possible using conventional techniques.

  19. Modelling cycle to cycle variations in an SI engine with detailed chemical kinetics

    Energy Technology Data Exchange (ETDEWEB)

    Etheridge, Jonathan; Mosbach, Sebastian; Kraft, Markus [Department of Chemical Engineering and Biotechnology, University of Cambridge (United Kingdom); Wu, Hao; Collings, Nick [Department of Engineering, University of Cambridge (United Kingdom)

    2011-01-15

    This paper presents experimental results and a new computational model that investigate cycle to cycle variations (CCV) in a spark ignition (SI) engine. An established stochastic reactor model (SRM) previously used to examine homogeneous charge compression ignition (HCCI) combustion has been extended by spark initiation, flame propagation and flame termination sub-models in order to simulate combustion in SI engines. The model contains a detailed chemical mechanism but relatively short computation times are achieved. The flame front is assumed to be spherical and centred at the spark location, and a pent roof and piston bowl geometry are accounted for. The model is validated by simulating the pressure profile and emissions from an iso-octane fuelled single cylinder research engine that showed low CCV. The effects of key parameters are investigated. Experimental results that show cycle to cycle fluctuations in a four-cylinder naturally aspirated gasoline fuelled SI engine are presented. The model is then coupled with GT-Power, a one-dimensional engine simulation tool, which is used to simulate the breathing events during a multi-cycle simulation. This allows an investigation of the cyclic fluctuations in peak pressure. The source and magnitude of nitric oxide (NO) emissions produced by different cycles are then investigated. It was found that faster burning cycles result in increased NO emissions compared with cycles that have a slower rate of combustion and that more is produced in the early stages of combustion compared with later in the cycle. The majority of NO was produced via the thermal mechanism just after combustion begins. (author)

  20. Towards multi-tracer data-assimilation: biomass burning and carbon isotope exchange in SiBCASA

    Directory of Open Access Journals (Sweden)

    I. R. van der Velde

    2014-01-01

    Full Text Available We present an enhanced version of the SiBCASA photosynthetic/biogeochemical model for a future integration with a multi-tracer data-assimilation system. We extended the model with (a biomass burning emissions from the SiBCASA carbon pools using remotely sensed burned area from Global Fire Emissions Database (GFED version 3.1, (b a new set of 13C pools that cycle consistently through the biosphere, and (c, a modified isotopic discrimination scheme to estimate variations in 13C exchange as a~response to stomatal conductance. Previous studies suggest that the observed variations of atmospheric 13C/12C are driven by processes specifically in the terrestrial biosphere rather than in the oceans. Therefore, we quantify in this study the terrestrial exchange of CO2 and 13CO2 as a function of environmental changes in humidity and biomass burning. Based on an assessment of observed respiration signatures we conclude that SiBCASA does well in simulating global to regional plant discrimination. The global mean discrimination value is 15.2‰, and ranges between 4 and 20‰ depending on the regional plant phenology. The biomass burning emissions (annually and seasonally compare favorably to other published values. However, the observed short-term changes in discrimination and the respiration 13C signature are more difficult to capture. We see a too weak drought response in SiBCASA and too slow return of anomalies in respiration. We demonstrate possible ways to improve this, and discuss the implications for our current capacity to interpret atmospheric 13C observations.

  1. Reduction of the linewidths of deep luminescence centers in 28Si reveals fingerprints of the isotope constituents.

    Science.gov (United States)

    Steger, M; Yang, A; Stavrias, N; Thewalt, M L W; Riemann, H; Abrosimov, N V; Churbanov, M F; Gusev, A V; Bulanov, A D; Kovalev, I D; Kaliteevskii, A K; Godisov, O N; Becker, P; Pohl, H-J

    2008-05-02

    Dramatic reductions of the linewidths of well-known deep centers in 28Si reveal "isotopic fingerprints" of the constituents. The approximately 1014 meV Cu center, thought to be either a Cu pair or an isolated Cu, is shown to contain four Cu atoms, and the approximately 780 meV Ag center is shown to contain four Ag. The approximately 944 meV ;{*}Cu center, thought to be a different configuration of a Cu pair, in fact contains three Cu and one Ag, and a new two-Cu two-Ag center is found. The approximately 735 meV center, previously assigned to Fe, actually contains Au and three Cu. This suggests a family of four-atom (Cu, Ag, Au) centers.

  2. Neural control of fast nonlinear systems--application to a turbocharged SI engine with VCT.

    Science.gov (United States)

    Colin, Guillaume; Chamaillard, Yann; Bloch, Gérard; Corde, Gilles

    2007-07-01

    Today, (engine) downsizing using turbocharging appears as a major way in reducing fuel consumption and pollutant emissions of spark ignition (SI) engines. In this context, an efficient control of the air actuators [throttle, turbo wastegate, and variable camshaft timing (VCT)] is needed for engine torque control. This paper proposes a nonlinear model-based control scheme which combines separate, but coordinated, control modules. Theses modules are based on different control strategies: internal model control (IMC), model predictive control (MPC), and optimal control. It is shown how neural models can be used at different levels and included in the control modules to replace physical models, which are too complex to be online embedded, or to estimate nonmeasured variables. The results obtained from two different test benches show the real-time applicability and good control performance of the proposed methods.

  3. Unveiling the Si cycle using isotopes in an iron-fertilized zone of the Southern Ocean: from mixed-layer supply to export

    Science.gov (United States)

    Closset, Ivia; Cardinal, Damien; Rembauville, Mathieu; Thil, François; Blain, Stéphane

    2016-11-01

    A massive diatom bloom forms annually in the surface waters of the naturally iron-fertilized Kerguelen Plateau (Southern Ocean). In this study, silicon isotopic signatures (δ30Si) of silicic acid (DSi) and suspended biogenic silica (BSi) were investigated through the whole water column with unprecedented spatial resolution, during the KEOPS-2 experiment (spring 2011). We used δ30Si measurements to track the sources of silicon that fuelled the bloom, and investigated the seasonal evolution of the Si biogeochemical cycle in the iron-fertilized area. We compared the results from stations with various degrees of iron enrichment and bloom conditions to an HNLC reference station. Dissolved and particulate δ30Si signatures were highly variable in the upper 500 m, reflecting the effect of intense silicon utilization in spring, while they were quite homogeneous in deeper waters. The Si isotopic and mass balance identified a unique Winter Water (WW) Si source for the iron-fertilized area that originated from southeast of the Kerguelen Plateau and spread northward. When the WW reached a retroflection of the Polar Front (PF), the δ30Si composition of the silicic acid pool became progressively heavier. This would result from sequential diapycnal and isopycnal mixings between the initial WW and ML water masses, highlighting the strong circulation of surface waters that defined this zone. When comparing the results from the two KEOPS expeditions, the relationship between DSi depletion, BSi production, and their isotopic composition appears decoupled in the iron-fertilized area. This seasonal decoupling could help to explain the low apparent fractionation factor observed in the ML at the end of summer. Taking into account these considerations, we refined the seasonal net BSi production in the ML of the iron-fertilized area to 3.0 ± 0.3 mol Si m-2 yr-1, which was exclusively sustained by surface water phytoplankton populations. These insights confirm that the isotopic

  4. The 13C-Pocket Structure in AGB Models: Constraints from Zirconium Isotope Abundances in Single Mainstream SiC Grains

    CERN Document Server

    Liu, Nan; Bisterzo, Sara; Davis, Andrew M; Savina, Michael R; Pellin, Michael J

    2014-01-01

    We present postprocess AGB nucleosynthesis models with different $^{13}$C-pocket internal structures to better explain zirconium isotope measurements in mainstream presolar SiC grains by Nicolussi et al. (1997) and Barzyk et al. (2007). We show that higher-than-solar $^{92}$Zr/$^{94}$Zr ratios can be predicted by adopting a $^{13}$C-pocket with a flat $^{13}$C profile, instead of the previous decreasing-with-depth $^{13}$C profile. The improved agreement between grain data for zirconium isotopes and AGB models provides additional support for a recent proposal of a flat $^{13}$C profile based on barium isotopes in mainstream SiC grains by Liu et al. (2014).

  5. The {sup 13}C-pocket structure in AGB models: constraints from zirconium isotope abundances in single mainstream SiC grains

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Nan; Davis, Andrew M.; Pellin, Michael J. [Department of the Geophysical Sciences, The University of Chicago, Chicago, IL 60637 (United States); Gallino, Roberto; Bisterzo, Sara [Dipartimento di Fisica, Università di Torino, Torino I-10125 (Italy); Savina, Michael R., E-mail: lnsmile@uchicago.edu [Chicago Center for Cosmochemistry, Chicago, IL 60637 (United States)

    2014-06-20

    We present postprocess asymptotic giant branch (AGB) nucleosynthesis models with different {sup 13}C-pocket internal structures to better explain zirconium isotope measurements in mainstream presolar SiC grains by Nicolussi et al. and Barzyk et al. We show that higher-than-solar {sup 92}Zr/{sup 94}Zr ratios can be predicted by adopting a {sup 13}C-pocket with a flat {sup 13}C profile, instead of the previous decreasing-with-depth {sup 13}C profile. The improved agreement between grain data for zirconium isotopes and AGB models provides additional support for a recent proposal of a flat {sup 13}C profile based on barium isotopes in mainstream SiC grains by Liu et al.

  6. Strain-engineered band parameters of graphene-like SiC monolayer

    Science.gov (United States)

    Behera, Harihar; Mukhopadhyay, Gautam

    2014-10-01

    Using full-potential density functional theory (DFT) calculations we show that the band gap and effective masses of charge carriers in SiC monolayer (ML-SiC) in graphene-like two-dimensional honeycomb structure are tunable by strain engineering. ML-SiC was found to preserve its flat 2D graphene-like structure under compressive strain up to 7%. A transition from indirect-to-direct gap-phase is predicted to occur for a strain value lying within the interval (1.11 %, 1.76%). In both gap-phases band gap decreases with increasing strain, although the rate of decrease is different in the two gap-phases. Effective mass of electrons show a non-linearly decreasing trend with increasing tensile strain in the direct gap-phase. The strain-sensitive properties of ML-SiC, may find applications in future strain-sensors, nanoelectromechanical systems (NEMS) and nano-optomechanical systems (NOMS) and other nano-devices.

  7. High-Performance Si/SiOx Nanosphere Anode Material by Multipurpose Interfacial Engineering with Black TiO(2-x).

    Science.gov (United States)

    Bae, Juhye; Kim, Dae Sik; Yoo, Hyundong; Park, Eunjun; Lim, Young-Geun; Park, Min-Sik; Kim, Young-Jun; Kim, Hansu

    2016-02-01

    Silicon oxides (SiOx) have attracted recent attention for their great potential as promising anode materials for lithium ion batteries as a result of their high energy density and excellent cycle performance. Despite these advantages, the commercial use of these materials is still impeded by low initial Coulombic efficiency and high production cost associated with a complicated synthesis process. Here, we demonstrate that Si/SiOx nanosphere anode materials show much improved performance enabled by electroconductive black TiO(2-x) coating in terms of reversible capacity, Coulombic efficiency, and thermal reliability. The resulting anode material exhibits a high reversible capacity of 1200 mAh g(-1) with an excellent cycle performance of up to 100 cycles. The introduction of a TiO(2-x) layer induces further reduction of the Si species in the SiOx matrix phase, thereby increasing the reversible capacity and initial Coulombic efficiency. Besides the improved electrochemical performance, the TiO(2-x) coating layer plays a key role in improving the thermal reliability of the Si/SiOx nanosphere anode material at the same time. We believe that this multipurpose interfacial engineering approach provides another route toward high-performance Si-based anode materials on a commercial scale.

  8. Emission reduction in SI engine using ethanol – gasoline blends on thermal barrier coated pistons

    Directory of Open Access Journals (Sweden)

    C.Ananda Srinivasan and C.G.Saravanan

    2010-07-01

    Full Text Available In this study, the effects of ethanol and unleaded gasoline with Isoheptanol blends on multi- cylinder SI engine were investigated. The test fuels were prepared using 99.9% pure ethanol and unleaded gasoline with Isoheptanol blend, in the ratio of E 60 + 2.0 Isoheptanol, E 50 + 1.0 Isoheptanol. In this work the performance, emission and combustion tests were conducted in multi-cylinder petrol engine. The experimental results reveal an increase in brake thermal efficiency on the use of test fuel. In the emission test, CO is found slightly decreased, while HC increased moderately and CO2 and NOx are appreciably reduced, when compared to the sole fuel. The second part of the investigation is carried out in the same engine with Alumina Titania coated crown of the pistons, to gain more inside improvement of engine performance and in-cylinder pressure for coated pistons. The experiment is repeated along with fuel additives and ethanol blends in the same blended ratio to analyse the performance and combustion characteristics of the engine. The results show marginal increase in brake thermal efficiency and reduction in CO, NOx, HC and CO2 emissions. In this study, combustion analyses are made with the help of AVL combustion analyzer, in which cylinder pressure, heat release rate and cumulative heat release are performed.

  9. Nano-engineering approach to destabilization of magnesium hydride (MgH2) by solid-state reaction with Si.

    Science.gov (United States)

    Bystrzycki, J; Polanski, M; Plocinski, T

    2009-06-01

    We studied a possibility of destabilization of MgH2 by chemical reaction with Si by using a nano-engineering method for reducing diffusion distances and increasing surface area. The structure, morphology, chemical composition and dehydriding properties were investigated by XRD, SEM, EDS, DTA-TG and the volumetric Sievert method. The commercial MgH2 and Si powder mixture corresponded to the stoichiometry of the ideal Mg2Si intermetallic compound was ball-milled under argon atmosphere to reach a nanocrystalline composite structure (MgH2-Si mixture leads to the formation only a small amount of the Mg2Si compound. Microstructural studies showed that Si after ball-milling is heterogeneously distributed on the surface of MgH2 particles and incorporated in the nanocrystalline MgH2 matrix, forming a nanocomposite structure. The sluggish destabilization of MgH2 by solid-state reaction with Si forming the Mg2Si intermetallic compound was observed at 250 degrees C. The XRD and EDS analysis confirmed that the Mg2Si compound is formed after the dehydrogenation of the synthesized MgH2-Si composite. The activation energy of the destabilization reaction for the investigated composite significantly decreased (162 kJ/mol) as compared with unmilled MgH2-Si powder mixture (213 kJ/mol).

  10. A novel bioactive porous CaSiO3 scaffold for bone tissue engineering.

    Science.gov (United States)

    Ni, Siyu; Chang, Jiang; Chou, Lee

    2006-01-01

    The aim of this study was to fabricate bioactive porous CaSiO3 scaffolds and examine their effects on proliferation and differentiation of osteoblast-like cells. In this study, porous CaSiO3 scaffolds were obtained by sintering a ceramic slip-coated polymer foam at 1350 degrees C. X-ray diffraction (XRD) of the scaffolds indicated that the products were essentially pure alpha-CaSiO3. The obtained scaffolds had a well-interconnected porous structure with pore sizes ranging from several micrometers to more than 100 microm and porosities of 88.5 +/- 2.8%. The in vitro bioactivity of the scaffolds was investigated by soaking them in simulated body fluid (SBF) for 7 days and then characterizing them by scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) analysis. The results indicated that hydroxyapatite (HAp) was formed on the surface of the scaffolds. In addition, the scaffolds were incubated in Ringer's solution at 37 degrees C to study the in vitro degradation by measurement of weight loss after incubation, which showed that the CaSiO3 scaffolds were degradable. The cellular responses to the scaffolds were assessed in terms of cell proliferation and differentiation. Osteoblast-like cells were seeded into the CaSiO3 scaffolds. SEM observations showed that there was significant cell adhesion, as the cells spread and grew in the scaffolds. In addition, the proliferation rate and alkaline phosphatase (ALP) activity of the cells in the scaffolds were improved as compared to the controls. These studies demonstrate initial in vitro cell compatibility and their potential application to bone tissue engineering. (c) 2005 Wiley Periodicals, Inc

  11. TUNGSTEN ISOTOPIC COMPOSITIONS IN STARDUST SiC GRAINS FROM THE MURCHISON METEORITE: CONSTRAINTS ON THE s-PROCESS IN THE Hf-Ta-W-Re-Os REGION

    Energy Technology Data Exchange (ETDEWEB)

    Avila, Janaina N.; Ireland, Trevor R.; Holden, Peter [Research School of Earth Sciences, Australian National University, Canberra, ACT 0200 (Australia); Lugaro, Maria; Buntain, Joelene [Centre for Stellar and Planetary Astrophysics, Monash University, Clayton, VIC 3800 (Australia); Gyngard, Frank; Zinner, Ernst; Amari, Sachiko [Laboratory for Space Sciences and the Department of Physics, Washington University, One Brookings Drive, St. Louis, MO 63130 (United States); Cristallo, Sergio [Departamento de Fisica Teorica y del Cosmos, Universidad de Granada, Granada 18071 (Spain); Karakas, Amanda, E-mail: janaina.avila@anu.edu.au [Mount Stromlo Observatory, Australian National University, Weston Creek, ACT 2611 (Australia)

    2012-01-01

    We report the first tungsten isotopic measurements in stardust silicon carbide (SiC) grains recovered from the Murchison carbonaceous chondrite. The isotopes {sup 182,183,184,186}W and {sup 179,180}Hf were measured on both an aggregate (KJB fraction) and single stardust SiC grains (LS+LU fraction) believed to have condensed in the outflows of low-mass carbon-rich asymptotic giant branch (AGB) stars with close-to-solar metallicity. The SiC aggregate shows small deviations from terrestrial (= solar) composition in the {sup 182}W/{sup 184}W and {sup 183}W/{sup 184}W ratios, with deficits in {sup 182}W and {sup 183}W with respect to {sup 184}W. The {sup 186}W/{sup 184}W ratio, however, shows no apparent deviation from the solar value. Tungsten isotopic measurements in single mainstream stardust SiC grains revealed lower than solar {sup 182}W/{sup 184}W, {sup 183}W/{sup 184}W, and {sup 186}W/{sup 184}W ratios. We have compared the SiC data with theoretical predictions of the evolution of W isotopic ratios in the envelopes of AGB stars. These ratios are affected by the slow neutron-capture process and match the SiC data regarding their {sup 182}W/{sup 184}W, {sup 183}W/{sup 184}W, and {sup 179}Hf/{sup 180}Hf isotopic compositions, although a small adjustment in the s-process production of {sup 183}W is needed in order to have a better agreement between the SiC data and model predictions. The models cannot explain the {sup 186}W/{sup 184}W ratios observed in the SiC grains, even when the current {sup 185}W neutron-capture cross section is increased by a factor of two. Further study is required to better assess how model uncertainties (e.g., the formation of the {sup 13}C neutron source, the mass-loss law, the modeling of the third dredge-up, and the efficiency of the {sup 22}Ne neutron source) may affect current s-process predictions.

  12. Testing the limits of micro-scale analyses of Si stable isotopes by femtosecond laser ablation multicollector inductively coupled plasma mass spectrometry with application to rock weathering

    Energy Technology Data Exchange (ETDEWEB)

    Schuessler, Jan A., E-mail: jan.schuessler@gfz-potsdam.de; Blanckenburg, Friedhelm von

    2014-08-01

    An analytical protocol for accurate in-situ Si stable isotope analysis has been established on a new second-generation custom-built femtosecond laser ablation system. The laser was coupled to a multicollector inductively coupled plasma mass spectrometer (fsLA-MC-ICP-MS). We investigated the influence of laser parameters such as spot size, laser focussing, energy density and repetition rate, and ICP-MS operating conditions such as ICP mass load, spectral and non-spectral matrix effects, signal intensities, and data processing on precision and accuracy of Si isotope ratios. We found that stable and reproducible ICP conditions were obtained by using He as aerosol carrier gas mixed with Ar/H{sub 2}O before entering the plasma. Precise δ{sup 29}Si and δ{sup 30}Si values (better than ± 0.23‰, 2SD) can be obtained if the area ablated is at least 50 × 50 μm; or, alternatively, for the analysis of geometric features down to the width of the laser spot (about 20 μm) if an equivalent area is covered. Larger areas can be analysed by rastering the laser beam, whereas small single spot analyses reduce the attainable precision of δ{sup 30}Si to ca. ± 0.6‰, 2SD, for < 30 μm diameter spots. It was found that focussing the laser beam beneath the sample surface with energy densities between 1 and 3.8 J/cm{sup 2} yields optimal analytical conditions for all materials investigated here. Using pure quartz (NIST 8546 aka. NBS-28) as measurement standard for calibration (standard-sample-bracketing) did result in accurate and precise data of international reference materials and samples covering a wide range in chemical compositions (Si single crystal IRMM-017, basaltic glasses KL2-G, BHVO-2G and BHVO-2, andesitic glass ML3B-G, rhyolitic glass ATHO-G, diopside glass JER, soda-lime glasses NIST SRM 612 and 610, San Carlos olivine). No composition-dependent matrix effect was discernible within uncertainties of the method. The method was applied to investigate the Si isotope

  13. Engineering of Sub-Nanometer SiOx Thickness in Si Photocathodes for Optimized Open Circuit Potential.

    Science.gov (United States)

    Das, Chittaranjan; Kot, Malgorzata; Henkel, Karsten; Schmeisser, Dieter

    2016-09-01

    Silicon is one of the most promising materials to be used for tandem-cell water-splitting devices. However, the electrochemical instability of bare Si makes it difficult to be used for stable devices. Besides that, the photovoltage loss in Si, caused by several factors (e.g., metal oxide protection layer and/or SiO2 /Si or catalyst/Si interface), limits its use in these devices. In this work, we present that an optimized open circuit potential (OCP) of Si can be obtained by controlling the SiOx thickness in sub-nanometer range. It can be done by means of a simple and cost-effective way using the combination of a wet chemical etching and the low temperature atomic layer deposition (ALD) of TiO2 . We have found that a certain thickness of the native SiOx is necessary to prevent further oxidation of the Si photocathode during the ALD growth of TiO2 . Moreover, covering the Si photocathode with an ALD TiO2 layer enhances its stability.

  14. Direct fabrication of graphene on SiO2 enabled by thin film stress engineering.

    Science.gov (United States)

    McNerny, Daniel Q; Viswanath, B; Copic, Davor; Laye, Fabrice R; Prohoda, Christophor; Brieland-Shoultz, Anna C; Polsen, Erik S; Dee, Nicholas T; Veerasamy, Vijayen S; Hart, A John

    2014-05-23

    We demonstrate direct production of graphene on SiO2 by CVD growth of graphene at the interface between a Ni film and the SiO2 substrate, followed by dry mechanical delamination of the Ni using adhesive tape. This result is enabled by understanding of the competition between stress evolution and microstructure development upon annealing of the Ni prior to the graphene growth step. When the Ni film remains adherent after graphene growth, the balance between residual stress and adhesion governs the ability to mechanically remove the Ni after the CVD process. In this study the graphene on SiO2 comprises micron-scale domains, ranging from monolayer to multilayer. The graphene has >90% coverage across centimeter-scale dimensions, limited by the size of our CVD chamber. Further engineering of the Ni film microstructure and stress state could enable manufacturing of highly uniform interfacial graphene followed by clean mechanical delamination over practically indefinite dimensions. Moreover, our findings suggest that preferential adhesion can enable production of 2-D materials directly on application-relevant substrates. This is attractive compared to transfer methods, which can cause mechanical damage and leave residues behind.

  15. Silicon isotope separation utilizing infrared multiphoton dissociation of Si{sub 2}F{sub 6} irradiated with two-color CO{sub 2} laser light

    Energy Technology Data Exchange (ETDEWEB)

    Yokoyama, Atsushi; Ohba, Hironori; Hashimoto, Masashi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Ishii, Takeshi; Ohya, Akio [Nuclear Development Corp., Tokai, Ibaraki (Japan); Arai, Shigeyoshi [Hill Research Co. Ltd., Tokyo (Japan)

    2002-08-01

    Silicon isotope separation has been done by utilizing the Infrared Multiphoton Dissociation (IRMPD) of Si{sub 2}F{sub 6} irradiated with two-color CO{sub 2} laser lights. The two-color excitation method improved the separation efficiency keeping the high enrichment factors. For example, 99.74% of {sup 28}Si was obtained at 49.63% dissociation of Si{sub 2}F{sub 6} after the simultaneous irradiation of 200 pulses with 966.23 cm{sup -1} photons (0.084 J/cm{sup 2}) and 954.55 cm{sup -1} photons (0.658 J/cm{sup 2}), while 2000 pulses were needed to obtain 99.35% of {sup 28}Si at 35.6% dissociation in the case of only one-color irradiation at 954.55 cm{sup -1} (0.97 J/cm{sup 2}). (author)

  16. Stress engineering in GaN structures grown on Si(111) substrates by SiN masking layer application

    Energy Technology Data Exchange (ETDEWEB)

    Szymański, Tomasz, E-mail: tomasz.szymanski@pwr.edu.pl; Wośko, Mateusz; Paszkiewicz, Bogdan; Paszkiewicz, Regina [The Faculty of Microsystem Electronics and Photonics, Wrocaw University of Technology, Janiszewskiego 11/17, 50-372 Wroclaw (Poland); Drzik, Milan [International Laser Center, Ilkovicova 3, 841-04 Bratislava 4 (Slovakia)

    2015-07-15

    GaN layers without and with an in-situ SiN mask were grown by using metal organic vapor phase epitaxy for three different approaches used in GaN on silicon(111) growth, and the physical and optical properties of the GaN layers were studied. For each approach applied, GaN layers of 1.4 μm total thickness were grown, using silan SiH{sub 4} as Si source in order to grow Si{sub x}N{sub x} masking layer. The optical micrographs, scanning electron microscope images, and atomic force microscope images of the grown samples revealed cracks for samples without SiN mask, and micropits, which were characteristic for the samples grown with SiN mask. In situ reflectance signal traces were studied showing a decrease of layer coalescence time and higher degree of 3D growth mode for samples with SiN masking layer. Stress measurements were conducted by two methods—by recording micro-Raman spectra and ex-situ curvature radius measurement—additionally PLs spectra were obtained revealing blueshift of PL peak positions with increasing stress. The authors have shown that a SiN mask significantly improves physical and optical properties of GaN multilayer systems reducing stress in comparison to samples grown applying the same approaches but without SiN masking layer.

  17. Combustion, Performance and Emission Analysis of an Oxygen-Controlling Downsized SI Engine

    Directory of Open Access Journals (Sweden)

    Zhou J.X.

    2016-07-01

    Full Text Available In the present study, experiments were carried out in a single-cylinder downsized SI engine with different rates of oxygen (15% to 27% by volume in the total mixture of intake gases except fuel and equivalence ratios (from 0.45 to 1. Therefore, the oxygen volume fraction is due to oxygen enrichment or nitrogen dilution. The study of the impact of controlling the oxygen concentration on the combustion characteristics and emissions was performed at 1 400 rpm, at several loads (Indicated Mean Effective Pressure (IMEP from 400 to 1 000 kPa. For each operation point, the spark advance and the intake pressure were adjusted simultaneously in order to maintain the load and obtain a minimum value of the indicated Specific Fuel Consumption (SFC. The effect of the oxygen concentration on the engine combustion characteristics was simulated by using the commercial software AMESim, with the combustion model developed by IFP Energies nouvelles, and an adapted algorithm was used to avoid residual gas calibration. By implementing a correlation for the laminar burning velocity, the in-cylinder pressures were perfectly predicted with a maximum pressure relative error of less than 2% for almost all the operating points. The classification of engine combustion according to the Peters-Borghi diagram, gives a deeper insight into the interaction between turbulence and the flame front.

  18. Wet chemical preparation and isotope exchange process of H/D-terminated Si(111) and Si(110) studied by adsorbate vibrational analysis

    Science.gov (United States)

    Kawamoto, Erina; Kang, Jungmin; Matsuda, Takuya; Yamada, Taro; Suto, Shozo

    2017-02-01

    A convenient procedure for preparing D-terminated Si(111)-(1×1) and Si(110)-(1×1) by wet chemical etching was developed and applied to the vibrational analysis of these surfaces by high-resolution electron-energy loss spectroscopy (HREELS). Fully H-terminated Si(111)/(110) was first prepared in regular 40% NH4F/H2O solution, followed by immersion in saturated KF/D2O solution. HREELS revealed partially D-terminated H:Si(111)/(110) with the amount of deuterium termination depending on the immersion time. A series of various immersion times revealed the H/D exchange reaction kinetics, which are associated with the Si substrate etching processes on Si(111) (step-flow etching) and Si(110) (zipper reaction). The H-Si and D-Si stretching vibration frequencies as functions of the surface D fraction did not appear to change on Si(111), but on Si(110) the H-Si signal red shifted at a high D fraction. This is due to the adsorbate-adsorbate interaction, which is more intense on Si(110) because of the short nearest-neighbor distance of the adsorbates.

  19. Synthesis and properties of MoSi2 based engineering ceramics

    Indian Academy of Sciences (India)

    P Srikari Tantri; Anup K Bhattacharya; Sheela K Ramasesha

    2001-10-01

    Molybdenum disilicide is a high temperature structural ceramic with many attractive properties for engineering applications. Foremost amongst these is its stability in corrosive atmospheres up to about 1600°C. However, there are a few undesirable properties that need to be addressed before it can become a viable material in high temperature applications. Since MoSi2 forms thermodynamically stable composites with both metals and ceramics, many reinforcing materials are incorporated into the matrix to improve the fracture toughness and creep properties. The low temperature oxidation can be controlled by making high density (> 95% of theoretical density) compacts. This article summarizes the important attempts that are made in improving the properties of molybdenum disilicide-based ceramics by the reinforcement with other materials.

  20. Experimental investigation of nitrogen based emissions from an ammonia fueled SI-engine

    DEFF Research Database (Denmark)

    Westlye, Fredrik Ree; Ivarsson, Anders; Schramm, Jesper

    2013-01-01

    This study concerns nitrogen based emissions from a hydrogen enriched ammonia fueled SI engine. These emissions deserve special attention as their formation may differ from conventional HC combustion due to the nitrogen content in the fuel. A range of experiments are conducted with a single...... with gasoline, but has a relatively low share of the total NOx emissions (3-4%). Nitrous oxide is a product of NH2 reacting with NO 2 and NH reacting with NO. The magnitude is largely affected by ignition timing due to the temperature development during expansion and the amount of excess air, as increased...... oxygen availability stimulates the formation of the NH2 radical and the levels of NO2 are higher. Under ideal operating conditions (MBT ignition timing) N2O levels are very low. The dominating contributors to unburned ammonia are chamber crevices as the magnitude of these emissions is greatly affected...

  1. LPG gaseous phase electronic port injection on performance, emission and combustion characteristics of Lean Burn SI Engine

    Science.gov (United States)

    Bhasker J, Pradeep; E, Porpatham

    2016-08-01

    Gaseous fuels have always been established as an assuring way to lessen emissions in Spark Ignition engines. In particular, LPG resolved to be an affirmative fuel for SI engines because of their efficient combustion properties, lower emissions and higher knock resistance. This paper investigates performance, emission and combustion characteristics of a microcontroller based electronic LPG gaseous phase port injection system. Experiments were carried out in a single cylinder diesel engine altered to behave as SI engine with LPG as fuel at a compression ratio of 10.5:1. The engine was regulated at 1500 rpm at a throttle position of 20% at diverse equivalence ratios. The test results were compared with that of the carburetion system. The results showed that there was an increase in brake power output and brake thermal efficiency with LPG gas phase injection. There was an appreciable extension in the lean limit of operation and maximum brake power output under lean conditions. LPG injection technique significantly reduces hydrocarbon and carbon monoxide emissions. Also, it extremely enhances the rate of combustion and helps in extending the lean limit of LPG. There was a minimal increase of NOx emissions over the lean operating range due to higher temperature. On the whole it is concluded that port injection of LPG is best suitable in terms of performance and emission for LPG fuelled lean burn SI engine.

  2. Study of performance and emission characteristics of a partially coated LHR SI engine blended with n-butanol and gasoline

    Directory of Open Access Journals (Sweden)

    Nitesh Mittal

    2013-09-01

    Full Text Available To meet the present requirements of the automotive industry, there is continuous search to improve the performance, exhaust emission, and life of the IC engines. The meet the first two challenges, researchers are working both on newer engine technologies and fuels. Some of the published work indicates that coating on the combustion surface of the engine with ceramic material results in improved performance and reduced emission levels when fueled with alternate fuel blended fuels, and this serves as a base for this work. Normal-Butanol has molecular structure that is adaptable to gasoline, and it is considered as one of the alternative fuels for SI engines. Blending butanol with gasoline changes the properties of the fuel and alters the engine performance and emission characteristics. This is because heat which is released at a rate as a result of combustion of the compressed air–fuel mixture in the combustion chamber gets changed with respect to change fuel properties, air fuel ratio, and engine speed. An experimental investigation is carried out on a partially insulated single cylinder SI engine to study the performance and emission characteristics when fueled with two different blends of butanol and gasoline. The cylinder head surface and valves are coated with a ceramic material consisting of Zirconium dioxide (ZrO2 with 8% by weight of Yttrium Oxide (Y2O3 to a thickness of 0.3 mm by plasma spray method. Two different fuel blends containing 10% and 15% by volume of butanol in Gasoline are tested on an engine dynamometer using the uncoated and ceramic coated engines. The results strongly indicate that combination of ceramic coated engine and butanol gasoline blended fuel has potential to improve the engine performance.

  3. Performance and emission characteristics of the thermal barrier coated SI engine by adding argon inert gas to intake mixture

    Directory of Open Access Journals (Sweden)

    T. Karthikeya Sharma

    2015-11-01

    Full Text Available Dilution of the intake air of the SI engine with the inert gases is one of the emission control techniques like exhaust gas recirculation, water injection into combustion chamber and cyclic variability, without scarifying power output and/or thermal efficiency (TE. This paper investigates the effects of using argon (Ar gas to mitigate the spark ignition engine intake air to enhance the performance and cut down the emissions mainly nitrogen oxides. The input variables of this study include the compression ratio, stroke length, and engine speed and argon concentration. Output parameters like TE, volumetric efficiency, heat release rates, brake power, exhaust gas temperature and emissions of NOx, CO2 and CO were studied in a thermal barrier coated SI engine, under variable argon concentrations. Results of this study showed that the inclusion of Argon to the input air of the thermal barrier coated SI engine has significantly improved the emission characteristics and engine’s performance within the range studied.

  4. Micrometer-scale chemical and isotopic criteria (O and Si) on the origin and history of Precambrian cherts: Implications for paleo-temperature reconstructions

    Science.gov (United States)

    Marin-Carbonne, Johanna; Chaussidon, Marc; Robert, François

    2012-09-01

    Oxygen and silicon isotopes in cherts have been extensively used for the reconstruction of seawater temperature during the Precambrian. These reconstructions have been challenged because cherts can have various origins (hydrothermal, sedimentary, volcanic silicification) and their isotopic compositions might have been reset by metamorphic fluid circulation. Existing criteria used to assess the pristine sedimentary origin of a chert are based on petrography (criterion #1: chert is composed mostly of microquartz); on the bulk oxygen isotopic composition (criterion #2: bulk δ18O has to be close enough to the maximum δ18O value previously measured in other cherts of the same age); and on the presence of a large δ18O range at the micrometer scale (criterion #3: δ18O range of ˜10‰ at ˜2 μm). However, these criteria remain incomplete in determining precisely the origin and degree of preservation of ancient cherts. We report in situ Si and O isotope compositions and trace element concentrations in seven chert samples ranging from 1.88 to 3.5 Ga in age. Correlations between δ30Si and Al2O3 (and K2O, TiO2) reveal that microquartz is of three different origins, i.e. diagenetic, hydrothermal or silicification. Moreover, chert samples composed mostly of diagenetic microquartz show a large range of δ30Si at the micrometer scale (1.7-4.5‰), consistent with the large range of δ18O previously found in the Gunflint diagenetic cherts. We propose two further quantitative criteria to assess the origin, state of preservation and diagenetic history of cherts. Criterion #4 uses trace element concentrations coupled with δ30Si to ascribe the origin of cherts among three possible end-members (diagenetic, hydrothermal, and silicified). Criterion #5 is the presence of a large range of δ30Si in pure diagenetic microquartz. In the seven samples analyzed in this study, only one (from the Gunflint Iron formation at 1.88 Ga) passes all the criteria assessed here and can be used for

  5. The impact of air-fuel mixture composition on SI engine performance during natural gas and producer gas combustion

    Science.gov (United States)

    Przybyła, G.; Postrzednik, S.; Żmudka, Z.

    2016-09-01

    The paper summarizers results of experimental tests of SI engine fuelled with gaseous fuels such as, natural gas and three mixtures of producer gas substitute that simulated real producer gas composition. The engine was operated under full open throttle and charged with different air-fuel mixture composition (changed value of air excess ratio). The spark timing was adjusted to obtain maximum brake torque (MBT) for each fuel and air-fuel mixture. This paper reports engine indicated performance based on in-cylinder, cycle resolved pressure measurements. The engine performance utilizing producer gas in terms of indicated efficiency is increased by about 2 percentage points when compared to fuelling with natural gas. The engine power de-rating when producer gas is utilized instead the natural gas, varies from 24% to 28,6% under stoichiometric combustion conditions. For lean burn (λ=1.5) the difference are lower and varies from 22% to 24.5%.

  6. Raman spectroscopy and in situ Raman spectroelectrochemistry of isotopically engineered graphene systems.

    Science.gov (United States)

    Frank, Otakar; Dresselhaus, Mildred S; Kalbac, Martin

    2015-01-20

    CONSPECTUS: The special properties of graphene offer immense opportunities for applications to many scientific fields, as well as societal needs, beyond our present imagination. One of the important features of graphene is the relatively simple tunability of its electronic structure, an asset that extends the usability of graphene even further beyond present experience. A direct injection of charge carriers into the conduction or valence bands, that is, doping, represents a viable way of shifting the Fermi level. In particular, electrochemical doping should be the method of choice, when higher doping levels are desired and when a firm control of experimental conditions is needed. In this Account, we focus on the electrochemistry of graphene in combination with in situ Raman spectroscopy, that is, in situ Raman spectroelectrochemistry. Such a combination of methods is indeed very powerful, since Raman spectroscopy not only can readily monitor the changes in the doping level but also can give information on eventual stress or disorder in the material. However, when Raman spectroscopy is employed, one of its main strengths lies in the utilization of isotope engineering during the chemical vapor deposition (CVD) growth of the graphene samples. The in situ Raman spectroelectrochemical study of multilayered systems with smartly designed isotope compositions in individual layers can provide a plethora of knowledge about the mutual interactions (i) between the graphene layers themselves, (ii) between graphene layers and their directly adjacent environment (e.g., substrate or electrolyte), and (iii) between graphene layers and their extended environment, which is separated from the layer by a certain number of additional graphene layers. In this Account, we show a few examples of such studies, from monolayer to two-layer and three-layer specimens and considering both turbostratic and AB interlayer ordering. Furthermore, the concept and the method can be extended further

  7. Coincident high-velocity DSA lifetime measurements on excited states of Si isotopes and stopping power investigations

    NARCIS (Netherlands)

    Scherpenzeel, D.E.C.; Engelbertink, G.A.P.; Aarts, H.J.M.; Poel, C.J. van der; Arciszewski, H.F.R.

    1980-01-01

    Mean lives of low-lying states of 28Si, 29Si and 30Si have been measured with the coincident high-velocity DSA method by 28Si bombardment of 2H, 3H and 4He targets. The recoils with an initial velocity of about 0.048c are slowed down in Mg, Cu, Ag and Au. The emitted γ-ray Doppler patterns are obser

  8. Band gap tuning of epitaxial SrTiO{sub 3-δ}/Si(001) thin films through strain engineering

    Energy Technology Data Exchange (ETDEWEB)

    Cottier, Ryan J.; Steinle, Nathan A.; Currie, Daniel A.; Theodoropoulou, Nikoleta, E-mail: ntheo@txstate.edu [Physics Department, Texas State University, San Marcos, Texas 78666 (United States)

    2015-11-30

    We investigate the effect of strain and oxygen vacancies (V{sub O}) on the crystal and optical properties of oxygen deficient, ultra-thin (4–30 nm) films of SrTiO{sub 3-δ} (STO) grown heteroepitaxially on p-Si(001) substrates by molecular beam epitaxy. We demonstrate that STO band gap tuning can be achieved through strain engineering and show that the energy shift of the direct energy gap transition of SrTiO{sub 3-δ}/Si films has a quantifiable dimensional and doping dependence that correlates well with the changes in crystal structure.

  9. Etats intrus dans les noyaux de la couche sd : de 1p-1t à np-nt dans les isotopes de Si

    OpenAIRE

    Goasduff, Alain

    2012-01-01

    New large-scale shell-model calculations with full 1¯hω valence space for the sd-nuclei has been used for the first time to predict lifetimes of positive and negative parity states in neutron rich Si isotopes. The predicted lifetimes (1 - 100 ps) fall in the range of the differential Doppler shift method. Using the demonstrator of the European next generation γ-ray array, AGATA, in coincidence with the large acceptance PRISMA magnetic spectrometer from LNL (Legnaro) and the differential plung...

  10. Engineering

    National Research Council Canada - National Science Library

    Includes papers in the following fields: Aerospace Engineering, Agricultural Engineering, Chemical Engineering, Civil Engineering, Electrical Engineering, Environmental Engineering, Industrial Engineering, Materials Engineering, Mechanical...

  11. Monte-Carlo code calculation of 3D reactor core model with usage of burnt fuel isotopic compositions, obtained by engineering codes

    Energy Technology Data Exchange (ETDEWEB)

    Aleshin, Sergey S.; Gorodkov, Sergey S.; Shcherenko, Anna I. [National Research Centre ' Kurchatov Institute' , Moscow (Russian Federation)

    2016-09-15

    A burn-up calculation of large systems by Monte-Carlo code (MCU) is complex process and it requires large computational costs. Previously prepared isotopic compositions are proposed to be used for the Monte-Carlo code calculations of different system states with burnt fuel. Isotopic compositions are calculated by an approximation method. The approximation method is based on usage of a spectral functionality and reference isotopic compositions, that are calculated by the engineering codes (TVS-M, BIPR-7A and PERMAK-A). The multiplication factors and power distributions of FAs from a 3-D reactor core are calculated in this work by the Monte-Carlo code MCU using earlier prepared isotopic compositions. The separate conditions of the burnt core are observed. The results of MCU calculations were compared with those that were obtained by engineering codes.

  12. Impact of methanol-gasoline fuel blend on the fuel consumption and exhaust emission of a SI engine

    Science.gov (United States)

    Rifal, Mohamad; Sinaga, Nazaruddin

    2016-04-01

    In this study, the effect of methanol-gasoline fuel blend (M15, M30 and M50) on the fuel consumption and exhaust emission of a spark ignition engine (SI) were investigated. In the experiment, an engine four-cylinder, four stroke injection system (engine of Toyota Kijang Innova 1TR-FE) was used. Test were did to know the relation of fuel consumption and exhaust emission (CO, CO2, HC) were analyzed under the idle throttle operating condition and variable engine speed ranging from 1000 to 4000 rpm. The experimental result showed that the fuel consumption decrease with the use of methanol. It was also shown that the CO and HC emission were reduced with the increase methanol content while CO2 were increased.

  13. AlSi17Cu5Mg alloy as future material for castings of pistons for internal combustion engines

    Directory of Open Access Journals (Sweden)

    J. Piątkowski

    2015-07-01

    Full Text Available The paper presents chosen properties and microstructure of AlSi17Cu5Mg alloy as future material for casting pistons in automotive industry. Tests were conducted to elaborate technology of preparation, assessment of crystallisation parameters and shaping the primary structure of the silumin with the aim to improve the working parameters and the functioning efficiency in cylinder-piston system. Refinement of Si crystals, achieved due to overheating above the temperature Tliq. causes that the alloy reaches satisfactory properties in working chamber of the engine are optimised. Such condition of material characteristics causes that hypereutectic silumins, for chosen applications in transport, may serve as an alternative to Al - Si alloys of hypoeutectic and near - eutectic type.

  14. Environmental and Mechanical Stability of Environmental Barrier Coated SA Tyrannohex SiC Composites Under Simulated Turbine Engine Environments

    Science.gov (United States)

    Zhu, Dongming; Halbig, Michael Charles; Sing, Mrityunjay

    2014-01-01

    The environmental stability and thermal gradient cyclic durability performance of SA Tyrannohex composites were investigated for turbine engine component applications. The work has been focused on investigating the combustion rig recession, cyclic thermal stress resistance and thermomechanical low cycle fatigue of uncoated and environmental barrier coated Tyrannohex SiC SA composites in simulated turbine engine combustion water vapor, thermal gradients, and mechanical loading conditions. Flexural strength degradations have been evaluated, and the upper limits of operating temperature conditions for the SA composite material systems are discussed based on the experimental results.

  15. Numerical simulation and validation of SI-CAI hybrid combustion in a CAI/HCCI gasoline engine

    Science.gov (United States)

    Wang, Xinyan; Xie, Hui; Xie, Liyan; Zhang, Lianfang; Li, Le; Chen, Tao; Zhao, Hua

    2013-02-01

    SI-CAI hybrid combustion, also known as spark-assisted compression ignition (SACI), is a promising concept to extend the operating range of CAI (Controlled Auto-Ignition) and achieve the smooth transition between spark ignition (SI) and CAI in the gasoline engine. In this study, a SI-CAI hybrid combustion model (HCM) has been constructed on the basis of the 3-Zones Extended Coherent Flame Model (ECFM3Z). An ignition model is included to initiate the ECFM3Z calculation and induce the flame propagation. In order to precisely depict the subsequent auto-ignition process of the unburned fuel and air mixture independently after the initiation of flame propagation, the tabulated chemistry concept is adopted to describe the auto-ignition chemistry. The methodology for extracting tabulated parameters from the chemical kinetics calculations is developed so that both cool flame reactions and main auto-ignition combustion can be well captured under a wider range of thermodynamic conditions. The SI-CAI hybrid combustion model (HCM) is then applied in the three-dimensional computational fluid dynamics (3-D CFD) engine simulation. The simulation results are compared with the experimental data obtained from a single cylinder VVA engine. The detailed analysis of the simulations demonstrates that the SI-CAI hybrid combustion process is characterised with the early flame propagation and subsequent multi-site auto-ignition around the main flame front, which is consistent with the optical results reported by other researchers. Besides, the systematic study of the in-cylinder condition reveals the influence mechanism of the early flame propagation on the subsequent auto-ignition.

  16. Identification of volatile and semivolatile compounds in chemical ionization GC-MS using a mass-to-structure (MTS) Search Engine with integral isotope pattern ranking.

    Science.gov (United States)

    Liao, Wenta; Draper, William M

    2013-02-21

    The mass-to-structure or MTS Search Engine is an Access 2010 database containing theoretical molecular mass information for 19,438 compounds assembled from common sources such as the Merck Index, pesticide and pharmaceutical compilations, and chemical catalogues. This database, which contains no experimental mass spectral data, was developed as an aid to identification of compounds in atmospheric pressure ionization (API)-LC-MS. This paper describes a powerful upgrade to this database, a fully integrated utility for filtering or ranking candidates based on isotope ratios and patterns. The new MTS Search Engine is applied here to the identification of volatile and semivolatile compounds including pesticides, nitrosoamines and other pollutants. Methane and isobutane chemical ionization (CI) GC-MS spectra were obtained from unit mass resolution mass spectrometers to determine MH(+) masses and isotope ratios. Isotopes were measured accurately with errors of Search Engine and details performance testing with over 50 model compounds.

  17. Raw data for 'Tensile Strain Engineering of Germanium Micro-Disks on Free-Standing SiO2 Beams'.

    OpenAIRE

    Al-Attili, Abdelrahman

    2016-01-01

    This dataset contains the raw data for 'Tensile Strain Engineering of Germanium Micro-Disks on Free-Standing SiO2 Beams'. Summary of this dataset in the form of figures were published by the Japanese Journal of Applied Physics (JJAP), Special Issues of the International Conference on Solid-State Devices and Materials (SSDM) 2015, Sapporo, Japan.\\ud Copyright 2016 The Japan Society of Applied Physics.\\ud \\ud

  18. Physical and electrical properties of band-engineered SiO2/(TiO2) x (SiO2)1- x stacks for nonvolatile memory applications

    Science.gov (United States)

    Oh, Jinho; Na, Heedo; Mok, In-Su; Kim, Jonggi; Lee, Kyumin; Sohn, Hyunchul

    2012-09-01

    In our study, the physical properties of (TiO2) x (SiO2)1- x , including band-gap, band-offset, and thermal stability and the electrical properties of band-engineered SiO2/(TiO2) x (SiO2)1- x tunnel barrier stacks, including the tunneling current and charge-trapping characteristics for applications to nonvolatile memory devices were investigated. It was observed that the band-gap and band-offset of (TiO2) x (SiO2)1- x can be controlled by adjustment in the composition of the (TiO2) x (SiO2)1- x films. Ti-silicate film with TiO2:SiO2 cycle ratio of 1:5 was maintained in an amorphous phase, even after annealing at 950 °C. The tunneling current of the band-engineered SiO2/(TiO2) x (SiO2)1- x stacked tunnel barrier was larger than that of a single SiO2 barrier under a higher external bias, while the tunneling current of a SiO2/(TiO2) x (SiO2)1- x stacked tunnel barrier under a lower external bias was smaller. Charge-trapping tests showed that the voltage shift for SiO2/(TiO2) x (SiO2)1- x is slightly larger than that for single SiO2.

  19. Characteristics of Sr, Nd and Pb isotopic compositions of hydrothermal Si-Fe-Mn-oxyhydroxides at the PACMANUS hydrothermal field, Eastern Manus Basin

    Institute of Scientific and Technical Information of China (English)

    YANG Baoju; ZENG Zhigang; WANG Xiaoyuan

    2015-01-01

    Si-Fe-Mn-oxyhydroxides dredged at the PACMANUS (Papua New Guinea–Australia–Canada–Manus) hydrothermal field, Eastern Manus Basin, have87Sr/86Sr=0.708 079–0.708 581;εNd=5.149 833–6.534 826;208Pb/204Pb=38.245–38.440;207Pb/204Pb=15.503–15.560;206Pb/204Pb=18.682–18.783.87Sr/86Sr isotope ratios are relatively homogeneous and close to the value of the surrounding seawater (0.709 16). The content of Sr in the samples contributed by seawater was estimated to be 76.7%–83.1% of total amount. The mixing temperature of hydrothermal fluids and seawater were ranging from 53.2°C to 72.2°C and the hydrothermal activities were unstable when the samples precipitated. TheεNd values of all the samples are positive, which differ from the values of ferromanganese nodules (crusts) with hydrogenic origin. Nd was mainly derived from substrate rocks leached by hydrothermal circulation and preserved the hydrothermal signature. Pb isotopic compositions of most samples show minor variability except Sample #9–2 that has relatively high values of Pb isotopes. The Pb may be derived from the Eastern Manus Basin rocks leached by the hydrothermal fluid. The slightly lower208Pb/204Pb and 207Pb/204Pb values of the samples indicated that the hydrothermal circulation in PACMANUS was not entire and sufficient, or that hydrothermal circulation had transient changes in the past. Si-Fe-Mn-oxyhydroxides in the samples preserved the heterogeneities of local rocks.

  20. Engineering Studies of a Pilot Plant for Laser Isotope Separation of CARBON-13 by Multiphoton Dissociation of Chlorodifluoromethane

    Science.gov (United States)

    Mehmetli, Bulent Ahmet

    Recent research in laser isotope separation by multiphoton dissociation (LISMPD) of ^{13 }C suggests that an LISMPD commercial process is more economical than the cryogenic CO distillation technology currently used to meet most of the world's ^ {13}C demand. In this dissertation, experimental studies of an engineering process for LISMPD of polyatomic molecules is examined. The experimental results have been obtained by MPD of chlorodifluoromethane (CF_2 HCl) to yield ^{13}C -enriched tetrafluoroethylene rm(C_2F _4). Emphasis is on research leading to the development of a practical chemical plant for the preparation of stable isotopes by this method. The experimental program has achieved the design, construction, and operation of a laboratory-scale ^{13}C separation apparatus and parametric dependences of enrichment factors and dissociated fractions. In this experiment, the reactant gas, industrial grade CF_2HCl, flows continuously along the axis of a stainless steel reaction cell. The beam of a commercial CO_2 TEA laser, delivering up to 3 J/pulse at a single wavelength, is focused into the cell to induce isotope-selective multiphoton dissociation. The ^{13}C-enriched reaction product, rm C_2F_4, is analyzed by mass spectroscopy for its isotopic content. Typical production rates of the setup are about 10 g/year ^{13}C at an enrichment of 15% or 1 g/year at an enrichment of 65%. The results of a detailed cost analysis, which takes into account different reaction conditions and laser types, showed that at production rates of 7,000 kg per year, the cost of ^{13}C can be as low as 4/g. This figure is about an order of magnitude less than the cost of ^13 C obtained by cryogenic distillation of CO. The design, construction, and operation of a CO _2 MOPA (Master Oscillator/ Power Amplifier) laser is proposed because a MOPA combines the advantages of favorable isotope separation reaction conditions of TEA lasers and the cheaper photons of cw discharges. Analytical

  1. EFFECT OF GASOLINE - ETHANOL BLENDS ON PERFORMANCE AND EMISSION CHARACTERISTICS OF A SINGLE CYLINDER AIR COOLED MOTOR BIKE SI ENGINE

    Directory of Open Access Journals (Sweden)

    A. SAMUEL RAJA

    2015-12-01

    Full Text Available This paper investigates the effect of using gasoline-ethanol (GE blends on performance and exhaust emission of a four stroke 150 cc single cylinder air cooled spark ignition (SI engine, without any modifications. Experiments were conducted at part load and different engine speeds ranging from 3000 to 5000 rpm, without and with catalytic converter. Ethanol content was varied from 5 percentage to 20 percentage by volume and four different blends (E5, E10, E15 and E20 were tested. Fuel consumption, engine speed, air fuel ratio, exhaust gas temperature and exhaust emissions were measured during each experiment. Brake thermal efficiency (ηb,th, volumetric efficiency (ηvol, brake specific fuel consumption (BSFC and excess air factor were calculated for each test run. Brake specific fuel consumption, volumetric efficiency and excess air factor increased with ethanol percentage in the blend. Carbon monoxide (CO, hydrocarbon (HC and oxides of nitrogen (NOx emissions decreased with blends.

  2. Source/drain eSiGe engineering for FinFET technology

    Science.gov (United States)

    Peng, Jianwei; Qi, Yi; Lo, Hsien-Ching; Zhao, Pei; Yong, Chloe; Yan, Jianghu; Dou, Xinyuan; Zhan, Hui; Shen, Yanping; Regonda, Suresh; Hu, Owen; Yu, Hong; Joshi, Manoj; Adams, Charlotte; Carter, Rick; Samavedam, Srikanth

    2017-09-01

    Epitaxy growth loading effect—the growth rate difference between device macros due to their local open ratio difference—is an important consideration for device design and thus process optimization. A poor loading process leads to device performance delta across macros. For eSiGe on FinFETs, we found that optimized eSiGe on FinFETs saturates as the eSiGe diamond pins at fin top surface and the fin-sidewall-spacer (FSS). The eSiGe diamond size measured by lateral CD does not increase with deposition time, but it linearly correlates to cavity depth and FSS pushdown. In principle, the eSiGe loading effect can be addressed with an extended growth time until every device macros saturates. However, it is found that, the epitaxy growth related defects, measured by abnormal eSiGe and unwanted growth, can also be elevated to an unacceptable level for a longer deposition time. Thus, the eSiGe loading process still needs to be optimized for an improved process window. In this work, an optimized eSiGe process achieves reduced loading between 2-fin and 40-fin macros and thus a smaller pFET performance gap between the two device macros.

  3. 20,22Ne-E(H) and 4He Measured in Single Interstellar SiC Grains of Known C-Isotopic Composition

    Science.gov (United States)

    Nichols, R. H., Jr.; Amari, S.; Hohenberg, C. M.; Hoppe, P.; Lewis, R. S.

    1993-07-01

    We have analyzed 61 individual interstellar SiC grains (Murchison KJH, ~4.6- micrometer nominal diameter) first by ion microprobe to determine C- and N- isotopic compositions and then by laser-gasas-extraction to determine He and Ne compositions. This work complements our initial investigation of the ^4He, ^22Ne, and C compositions in a suite of 92 individual SiC grains from the Murchison KJG SiC fraction (~3 micrometers) [1,2]. Three grains in the present suite carried ^4He and ^22Ne-E(H) above detection limits (Table 1). The results presented here support our initial conclusions [1,2]: (1) only a small fraction (~5%) of the SiC grains is gas-rich and contains essentially all the Ne-E measured in the bulk residues and (2) ^4He accompanies ^22Ne-E(H) in each gas-rich grain and vice versa. The gas-poor grains were either degassed or were not exposed to the stellar source(s) that produced Ne-E(H). One extremely gas-rich grain in the present suite (7611, estimated ^4He and ^22Ne concentrations of 2.0 and 0.02 ccSTP/g respectively) contained sufficient 20Ne to establish a precise value for the (^20Ne/^22Ne)E(H) ratio (0.09 +/- 0.02). This ratio is consistent both with the bulk KJH measurements [3,4] and those expected from AGB (asymptotic giant branch) star He-burning shells [5], leaving little or no room in the grain for an additional complement of envelope-derived gases. The ^4He/^22Ne ratio in grain 7611 is also consistent with an AGB star He-shell composition [5]. The elevated ^4He/^22Ne ratios in the other two gas-rich grains indicate that these grains contain a larger complement of envelope-derived gases. Spallation-derived gases are not detectable in the individual grains; however, the upper limit to the (^21Ne/^22Ne)E(H) ratio (90%) of the spallation-derived gases measured in the bulk residues. This would imply that the 3.4-Ga interstellar cosmic ray exposure age of the gas-rich SiC grains, calculated by assuming that the Ne-E-rich grains carry all the

  4. A New Family of Nonlinear Observers for SI Engine Air/Fuel Ratio Control

    DEFF Research Database (Denmark)

    Jensen, P. B.; Olsen, M. B.; Poulsen, J.;

    1997-01-01

    The paper treats a newly developed set of nonlinear observers for advanced spark ignition engine control.......The paper treats a newly developed set of nonlinear observers for advanced spark ignition engine control....

  5. Development of Innovative Radioactive Isotope Production Techniques at the Pennsylvania State University Radiation Science and Engineering Center

    Energy Technology Data Exchange (ETDEWEB)

    Johnsen, Amanda M. [Pennsylvania State Univ., State College, PA (United States). Radiation Science and Engineering Center; Heidrich, Brenden [Pennsylvania State Univ., State College, PA (United States). Radiation Science and Engineering Center; Durrant, Chad [Pennsylvania State Univ., State College, PA (United States). Department of mechanical and Nuclear Engineering Center; Bascom, Andrew [Pennsylvania State Univ., State College, PA (United States). Department of mechanical and Nuclear Engineering Center; Unlu, Kenan [Pennsylvania State Univ., State College, PA (United States). Radiation Science and Engineering Center

    2013-08-15

    The Penn State Breazeale Nuclear Reactor (PSBR) at the Radiation Science and Engineering Center (RSEC) has produced radioisotopes for research and commercial purposes since 1956. With the rebirth of the radiochemistry education and research program at the RSEC, the Center stands poised to produce a variety of radioisotopes for research and industrial work that is in line with the mission of the DOE Office of Science, Office of Nuclear Physics, Isotope Development and Production Research and Application Program. The RSEC received funding from the Office of Science in 2010 to improve production techniques and develop new capabilities. Under this program, we improved our existing techniques to provide four radioisotopes (Mn-56, Br-82, Na-24, and Ar-41) to researchers and industry in a safe and efficient manner. The RSEC is also working to develop new innovative techniques to provide isotopes in short supply to researchers and others in the scientific community, specifically Cu-64 and Cu-67. Improving our existing radioisotopes production techniques and investigating new and innovative methods are two of the main initiatives of the radiochemistry research program at the RSEC.

  6. Selective growth and ordering of SiGe nanowires for band gap engineering.

    Science.gov (United States)

    Benkouider, A; Ronda, A; Gouyé, A; Herrier, C; Favre, L; Lockwood, D J; Rowell, N L; Delobbe, A; Sudraud, P; Berbezier, I

    2014-08-22

    Selective growth and self-organization of silicon-germanium (SiGe) nanowires (NWs) on focused ion beam (FIB) patterned Si(111) substrates is reported. In its first step, the process involves the selective synthesis of Au catalysts in SiO₂-free areas; its second step involves the preferential nucleation and growth of SiGe NWs on the catalysts. The selective synthesis process is based on a simple, room-temperature reduction of gold salts (Au³⁺Cl₄⁻) in aqueous solution, which provides well-organized Au catalysts. By optimizing the reduction process, we are able to generate a bidimensional regular array of Au catalysts with self-limited sizes positioned in SiO₂-free windows opened in a SiO₂/Si(111) substrate by FIB patterning. Such Au catalysts subsequently serve as preferential nucleation and growth sites of well-organized NWs. Furthermore, these NWs with tunable position and size exhibit the relevant features and bright luminescence that would find several applications in optoelectronic nanodevices.

  7. 40 CFR 60.4232 - How long must my engines meet the emission standards if I am a manufacturer of stationary SI...

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false How long must my engines meet the emission standards if I am a manufacturer of stationary SI internal combustion engines? 60.4232 Section 60.4232 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW...

  8. GaAs epitaxy on Si substrates: modern status of research and engineering

    Energy Technology Data Exchange (ETDEWEB)

    Bolkhovityanov, Yu B; Pchelyakov, O P [Institute of Semiconductor Physics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk (Russian Federation)

    2008-05-31

    While silicon and gallium arsenide are dominant materials in modern micro- and nanoelectronics, devices fabricated from them still use Si and GaAs substrates only separately. Integrating these materials on the (highest effeciency) substrate of Si has been the subject of much research effort for more than twenty years. This review systematizes and generalizes the current understanding of the fundamental physical mechanisms governing the epitaxial growth of GaAs and its related III-V compounds on Si substrates. Basic techniques avilable for improving the quality of such heterostructures are described, and recent advances in fabricating device-quality A{sup III}B{sup V}/Si heterostructures and devices on their bases are also presented. (reviews of topical problems)

  9. Extreme Environment SiC Wireless Sensor Suite for Nuclear Thermal Propulsion Engines Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In this program, APEI, Inc. will build on successful demonstrations of SiC-based wireless transmitter designs in high temperature and high mechanical load...

  10. Coupled Ge/Si and Ge isotope ratios as geochemical tracers of seafloor hydrothermal systems: Case studies at Loihi Seamount and East Pacific Rise 9°50‧N

    Science.gov (United States)

    Escoube, Raphaelle; Rouxel, Olivier J.; Edwards, Katrina; Glazer, Brian; Donard, Olivier F. X.

    2015-10-01

    Germanium (Ge) and Silicon (Si) exhibit similar geochemical behavior in marine environments but are variably enriched in seafloor hydrothermal fluids relative to seawater. In this study, Ge isotope and Ge/Si ratio systematics were investigated in low temperature hydrothermal vents from Loihi Seamount (Pacific Ocean, 18°54‧N, 155°15‧W) and results were compared to high-temperature vents from the East Pacific Rise (EPR) at 9°50‧N. Loihi offers the opportunity to understand contrasting Ge and Si behavior in low temperature seafloor hydrothermal systems characterized by abundant Fe oxyhydroxide deposition at the seafloor. The results show that both Ge/Si and δ74/70Ge in hydrothermal fluids are fractionated relative to the basaltic host rocks. The enrichment in Ge vs. Si relative to fresh basalts, together with Ge isotope fractionation (Δ74/70Gefluid-basalt up to 1.15‰ at EPR 9°50‧N and 1.64‰ at Loihi) are best explained by the precipitation of minerals (e.g. quartz and Fe-sulfides) during higher temperature seawater-rock reactions in the subsurface. The study of Fe-rich hydrothermal deposits at Loihi, largely composed of Fe-oxyhydroxides, shows that Ge isotopes are also fractionated upon mineral precipitation at the seafloor. We obtained an average Ge isotope fractionation factor between Fe-oxyhydroxide (ferrihydrite) and dissolved Ge in the fluid of -2.0 ± 0.6‰ (2sd), and a maximum value of -3.6 ± 0.6‰ (2sd), which is consistent with recent theoretical and experimental studies. The study of a hydrothermal chimney at Bio 9 vent at EPR 9°50‧N also demonstrates that Ge isotopes are fractionated by approximately -5.6 ± 0.6‰ (2sd) during precipitation of metal sulfides under hydrothermal conditions. Using combined Ge/Si and estimated Ge isotope signatures of Ge sinks and sources in seawater, we propose a preliminary oceanic budget of Ge which reveals that an important sink, referred as the "missing Ge sink", may correspond to Ge sequestration

  11. Methods of Si based ceramic components volatilization control in a gas turbine engine

    Science.gov (United States)

    Garcia-Crespo, Andres Jose; Delvaux, John; Dion Ouellet, Noemie

    2016-09-06

    A method of controlling volatilization of silicon based components in a gas turbine engine includes measuring, estimating and/or predicting a variable related to operation of the gas turbine engine; correlating the variable to determine an amount of silicon to control volatilization of the silicon based components in the gas turbine engine; and injecting silicon into the gas turbine engine to control volatilization of the silicon based components. A gas turbine with a compressor, combustion system, turbine section and silicon injection system may be controlled by a controller that implements the control method.

  12. Chapter 17 - Engineering cationic liposome siRNA complexes for in vitro and in vivo delivery.

    Science.gov (United States)

    Podesta, Jennifer E; Kostarelos, Kostas

    2009-01-01

    RNA interference, the sequence-specific silencing of gene expression by introduction of short interfering RNA (siRNA) is a powerful tool that that the potential to act as a therapeutic agent and the advantage of decreasing toxic effects on normal tissue sometimes seen with conventional treatments i.e. small molecule inhibitors. Naked, unmodified siRNA is poorly taken up by cells and is subject to degradation when exposed to blood proteins during systemic administration. It has also been shown to produce non-specific immune response as well as having the potential to generate 'off-target' effects. Therefore there is a requirement for a delivery system to not only protect the siRNA and facilitate its uptake, but additionally to offer the potential for targeted delivery with an aim of exploiting the high specificity afforded by RNA interference. Cationic liposomes are the most studied, non-viral delivery system used for nucleic acid delivery. As such, the use of cationic liposomes is promising for siRNA for delivery. Furthermore, polyethylene glycol (PEG) can be incorporated into the liposome formulation to create sterically stabilized or 'stealth' liposomes. Addition of PEG can reduce recognition by the reticuloendothelial system (RES) thereby prolonging circulation time. Here we describe a methodology for the complexation of siRNA with cationic liposomes and PEGylated liposomes using two protocols: mixing and encapsulation. Moreover, the different formulations are compared head to head to demonstrate their efficacy for gene silencing.

  13. Tuning the electrical properties of Si nanowire field-effect transistors by molecular engineering.

    Science.gov (United States)

    Bashouti, Muhammad Y; Tung, Raymond T; Haick, Hossam

    2009-12-01

    Exposed facets of n-type silicon nanowires (Si NWs) fabricated by a top-down approach are successfully terminated with different organic functionalities, including 1,3-dioxan-2-ethyl, butyl, allyl, and propyl-alcohol, using a two-step chlorination/alkylation method. X-ray photoemission spectroscopy and spectroscopic ellipsometry establish the bonding and the coverage of these molecular layers. Field-effect transistors fabricated from these Si NWs displayed characteristics that depended critically on the type of molecular termination. Without molecules the source-drain conduction is unable to be turned off by negative gate voltages as large as -20 V. Upon adsorption of organic molecules there is an observed increase in the "on" current at large positive gate voltages and also a reduction, by several orders of magnitude, of the "off" current at large negative gate voltages. The zero-gate voltage transconductance of molecule-terminated Si NW correlates with the type of organic molecule. Adsorption of butyl and 1,3-dioxan-2-ethyl molecules improves the channel conductance over that of the original SiO(2)-Si NW, while adsorption of molecules with propyl-alcohol leads to a reduction. It is shown that a simple assumption based on the possible creation of surface states alongside the attachment of molecules may lead to a qualitative explanation of these electrical characteristics. The possibility and potential implications of modifying semiconductor devices by tuning the distribution of surface states via the functionality of attached molecules are discussed.

  14. Strain engineering effects on electrical properties of lead-free piezoelectric thin films on Si wafers.

    Science.gov (United States)

    Ohno, Tomoya; Kamai, Yuto; Oda, Yuutaro; Sakamoto, Naonori; Matsuda, Takeshi; Wakiya, Naoki; Suzuki, Hisao

    2014-01-01

    Using radio frequency - magnetron sputtering, calcium-doped barium zirconate titanate ((Ba(0.85)Ca(0.15))(Zr(0.1)Ti(0.9))O(3), BCZT) thin films were deposited on Si wafers with different bottom electrodes. The obtained BCZT thin film on a lanthanum nickel oxide (LNO) electrode had a highly c-axis preferred orientation, while the BCZT thin film on a Pt bottom electrode had (111) preferred orientation. Furthermore, the out-of-plane lattice constant of the BCZT on LNO/Si was 3.4% larger than that of the reported bulk material because of the compressive thermal stress from LNO with a large thermal expansion coefficient. This compressive thermal stress engenders an increase of the Curie temperature. The local piezoelectric response of the BCZT thin film on a LNO/Si structure was measured by piezoresponse force microscope.

  15. Optical investigations of combustion process in SI and CI engines fuelled with butanol blends

    Energy Technology Data Exchange (ETDEWEB)

    Marchitto, L.; Mazzei, A.; Merola, S.S.; Tornatore, C. [CNR Napoli, Naples (Italy). Istituto Motori; Valentino, G.

    2013-06-01

    The use of alternative fuels, as biodiesel and ethanol, for light duty engines to approach the target of low exhaust emissions without fuel economy and performance penalty has been widely investigated. Recently it is growing the interest in the butanol and bio-butanol as viable alternatives either single or blended with conventional based fuels. In this paper, butanol effects on combustion processes were investigated through conventional methods and optical diagnostics applied in the combustion chamber of a compression ignition engine and of a spark ignition engine. Blends of diesel and n-butanol were used in a common rail DI diesel engine running at different operating conditions. Fuel injection timing and oxygen at the intake were changed in a single cylinder compression ignition engine equipped with common rail multi-jets injection system. Spray combustion and pollutant formation were investigated though UV-visible digital imaging and natural emission spectroscopy. Flame emissions and spectroscopy were applied in an optically accessible cylinder of a port fuel-injection, spark-ignition engine with an external boosting device. The engine worked with a stoichiometric mixture at medium speed and boosting in wide open throttle condition. Normal and knocking combustion was tested. Experiments in both the engines demonstrated that butanol allowed to reduce carbonaceous compounds formation and soot emission and to decrease unpleasant effects related to the combustion process such as the fuel deposition burning. Moreover some emission bands of OH radicals could be used as feature of different phenomena related to the combustion process. (orig.)

  16. Surface engineering of gold nanoparticles for in vitro siRNA delivery

    Science.gov (United States)

    Zhao, Enyu; Zhao, Zhixia; Wang, Jiancheng; Yang, Chunhui; Chen, Chengjun; Gao, Lingyan; Feng, Qiang; Hou, Wenjie; Gao, Mingyuan; Zhang, Qiang

    2012-07-01

    Cellular uptake, endosomal/lysosomal escape, and the effective dissociation from the carrier are a series of hurdles for specific genes to be delivered both in vitro and in vivo. To construct siRNA delivery systems, poly(allylamine hydrochloride) (PAH) and siRNA were alternately assembled on the surface of 11.8 +/- 0.9 nm Au nanoparticles (GNP), stabilized by denatured bovine serum albumin, by the ionic layer-by-layer (LbL) self-assembly method. By manipulating the outmost PAH layer, GNP-PAH vectors with different surface electric potentials were prepared. Then, the surface potential-dependent cytotoxicity of the resultant GNP-PAH particles was evaluated via sulforhodamine B (SRB) assay, while the surface potential-dependent cellular uptake efficiency was quantitatively analyzed by using the flow cytometry method based on carboxyfluorescein (FAM)-labeled siRNA. It was revealed that the GNP-PAH particles with surface potential of +25 mV exhibited the optimal cellular uptake efficiency and cytotoxicity for human breast cancer MCF-7 cells. Following these results, two more positively charged polyelectrolytes with different protonating abilities in comparison with PAH, i.e., polyethylenimine (PEI), and poly(diallyl dimethyl ammonium chloride) (PDDA), were chosen to fabricate similarly structured vectors. Confocal fluorescence microscopy studies indicated that siRNA delivered by GNP-PAH and GNP-PEI systems was better released than that delivered by the GNP-PDDA system. Further flow cytometric assays based on immunofluorescence staining of the epidermal growth factor receptor (EGFR) revealed that EGFR siRNA delivered by GNP-PAH and GNP-PEI exhibited similar down-regulation effects on EGFR expression in MCF-7 cells. The following dual fluorescence flow cytometry assays by co-staining phosphatidylserine and DNA suggested the EGFR siRNA delivered by GNP-PAH exhibited an improved silencing effect in comparison with that delivered by the commercial transfection reagent

  17. Investigation of work parameters of SI engine dedicated to energetics aggregates with pneumatic injection system

    Science.gov (United States)

    Marek, W.; Śliwiński, K.

    2016-09-01

    The article presents the possibilities of alternative fuel combustion in the engine four- stroke spark ignition engines. Power of the motor was carried out pneumatic fuel injection system using a hot gas developed by Prof. Stanislaw Jarnuszkiewicz. Presented made the position of the measuring system with the power and results. The engine experimental at the time of the study was powered by a blend of alcohol and gasoline. The main aim of the study was the question of control fuel dosage, taking into account the energy needs of forcing the engine load. During the tests carried load characteristics control the motor using the power control quality. Another issue was the elimination of penetration of fuel to the engine lubrication system, a problem occurred in the initial study on the issue of the pneumatic fuel injection using the hot exhaust gases. In summary we present the findings of this phase of the study.

  18. A calibration of the triple oxygen isotope fractionation in the SiO2-H2O system and applications to natural samples

    Science.gov (United States)

    Sharp, Z. D.; Gibbons, J. A.; Maltsev, O.; Atudorei, V.; Pack, A.; Sengupta, S.; Shock, E. L.; Knauth, L. P.

    2016-08-01

    It is now recognized that variations in the Δ17O of terrestrial materials resulting from purely mass dependent fractionations, though small, have geological significance. In this study, the δ18O and δ17O values of selected low temperature quartz and silica samples were measured in order to derive the quartz-water fractionation-temperature relationship for the three oxygen isotope system. A 18O/16O quartz-water fractionation equation valid for all temperatures was generated from published high temperature exchange experiments and low temperature empirical estimates and is given by 1000ln αqz-H2O 18O /16O =4.20 (0.11) ×106/T2 - 3.3 (0.2) × 1000/T (T in Kelvins). The equilibrium δ17O-δ18O relationship is given by the equation lnα17O/16O = θlnα18O/16O . The variation of θ with temperature for the quartz-water system was determined empirically using low temperature marine diatoms, microcrystalline quartz and a modern sinter sample. A best fit to the data give the equation θSiO2-H2O = -(1.85 ± 0.04)/T + 0.5305 , indistinguishable from an earlier theoretical estimate. Application of the quartz-water triple isotope system to low temperature samples provides constraints on both temperature and composition of the water with which the silica last equilibrated. Authigenic quartz crystallization temperatures cluster around 50 °C, which are lower than many previous estimates. The combined δ18O and δ17O values of samples considered to be in equilibrium with ocean or meteoric waters can be used to estimate both formation temperatures and the δ18O value of the meteoric water. Unlike other multiple isotopes systems, such as combined H and O isotopes in cherts, the oxygen source and diagenetic potential for both 17O/16O and 18O/16O ratios are identical, simplifying interpretations from ancient samples.

  19. Performance and combustion characteristics of a direct injection SI hydrogen engine

    Energy Technology Data Exchange (ETDEWEB)

    Mohammadi, Ali [Engine Technology, Powertrain, Toyota Motor Europe, Technical centre Hoge Wei 33 Zaventem 1930 (Belgium); Shioji, Masahiro; Nakai, Yasuyuki; Ishikura, Wataru [Graduate School of Energy Science, Kyoto University, Yoshida-honmachi Sakyo-ku Kyoto 605-8501 (Japan); Tabo, Eizo [Environmental and Technical Affairs Department, Mitsubishi Motors Co., 5-33-8 Shiba Minatoku Tokyo 108-8401 (Japan)

    2007-02-15

    Hydrogen with low spark-energy requirement, wide flammability range and high burning velocity is an important candidate for being used as fuel in spark-ignition engines. It also offers CO{sub 2} and HC free combustion and lean operation resulting in lower NO{sub x} emissions. However, well examined external mixing of hydrogen with intake air causes backfire and knock especially at higher engine loads. In addition, low heating value per unit of volume of hydrogen limits the maximum output power. In this study, attention was paid to full usage of hydrogen advantage employing internal mixing method. Hydrogen was directly injected into cylinder of a single-cylinder test engine using a high-pressure gas injector and effects of injection timing and spark timing on engine performance and NO{sub x} emission were investigated under wide engine loads. The results indicate that direct injection of hydrogen prevents backfire, and that high thermal efficiency and output power can be achieved by hydrogen injection during late compression stroke. Moreover, by further optimization of the injection timing for each engine load, NO{sub x} emission can be reduced under the high engine output conditions. (author)

  20. Mathematical optimization of variable valve timing for reducing fuel consumption of A SI engine

    OpenAIRE

    Kakaee, Amir-Hasan; Keshavarz, Mehdi; Paykani, Amin; Keshavarz, Mohaamad

    2016-01-01

    In this study, the sensitivity analysis and Quasi-Newton algorithms are used to optimize valve timing XU7/L3 engine in order to reduce fuel consumption and increase engine performance. At first, all components of engine are modeled in GT-POWER and a comparison with experimental results is performed to confirm the accuracy of the model. Then, GT-POWER model is coupled with MATLAB-SIMULINK to control inputs and outputs with sensitivity analysis and Quasi-Newton algorithms. The results obtained ...

  1. The Effects of Fuels and Lubricants on Low- Speed Pre- Ignition in Gasoline SI Engines

    Institute of Scientific and Technical Information of China (English)

    Eric LIU

    2012-01-01

    With the onset of downsized and highly- boosted engines, engine designers are encountering a new combustion phenomenon, called low - speed pre - ignition (LSPI) or superknock, which occurs when the engine operates under a low - speed, high - load conditions. LSPI events cause large spikes in cylinder pressure that can easily exceed the design limits of the engine. Therefore, it is important for the automotive industry to understand how LSPI events occur and develop a so- lution that can either eliminate it or detect and mitigate its effects. This paper summarizes the existing work that has been conducted on the subject of LSPI. Much of presented hypothesizes that physical and chemical interactions and accumulation of fuels and lubricants in crevice volume affect the frequency of LPSl events. Therefore, it may be possible to formulate fuels and mitigate or eliminate the occurrence of LPSI. the research work the piston top land lubricants that can

  2. S.I. engine idle control improvement by using automobile reversible alternator

    Energy Technology Data Exchange (ETDEWEB)

    Kouadio, L.; Bidan, P.; Valentin, M.; Berry, J.P.

    1995-12-31

    This paper describes the improvements which can be made to spark ignition engine by extensive use of automatic control. Particular emphasis is placed on fast transient phases produced by simultaneous action on the throttle and the electronic fuel injection device. The aim is to achieve better performance for the fuel/air ratio regulation system, thereby improving engine efficiency and exhaust emission during these transient phases. The authors begin by presenting an average dynamic model of the intake manifold validated on an engine test bench and goes on to develop a closed-loop system controlling average pressure in the intake manifold using the reference tracking model method. The air supply control system is combined with a predictor to compensate for delays in the injection procedure. The paper concludes with a comparison between the results obtained using simulation and those obtained experimentally from the engine. (authors) 15 refs.

  3. Substrate engineering by hexagonal boron nitride/SiO2 for hysteresis-free graphene FETs and large-scale graphene p-n junctions.

    Science.gov (United States)

    Xu, Hua; Wu, Juanxia; Chen, Yabin; Zhang, Haoli; Zhang, Jin

    2013-10-01

    We have explored an approach for the fabrication of intrinsic and hysteresis-free graphene field-effect transistors (FETs) and for the construction of graphene p-n junctions based on substrate engineering by hexagonal boron nitride (h-BN)/SiO2. The effect of various interfaces on the performance of the graphene FETs was systematically studied by constructing four types of graphene devices (graphene/SiO2 FETs, graphene/h-BN FETs, h-BN/graphene/SiO2 FETs, and h-BN/graphene/h-BN FETs). Graphene/SiO2 FETs and h-BN/graphene/SiO2 FETs always exhibit large hysteresis before and after annealing, whereas graphene/h-BN FETs and h-BN/graphene/h-BN FETs show intrinsic properties after annealing. Raman measurements also indicate that graphene on a SiO2 substrate contains large amounts of p-doping, whereas that on a h-BN substrate is intrinsic. Thus, the graphene/h-BN interface gives intrinsic and hysteresis-free graphene FETs, whilst the graphene/SiO2 interface affords p-doping and a hysteresis effect in the graphene FETs. This result is because h-BN serves as an insulation layer, which prevents charge trapping between the graphene and the charge traps at the graphene/SiO2 interface, which cause the hysteresis. In addition, the negligible electrostatic doping of h-BN into graphene also ensures the intrinsic and hysteresis-free properties of graphene/BN/SiO2 FETs. Moreover, benefitting from the p-doped and intrinsic features of graphene on SiO2 and h-BN substrates, respectively, large-scale graphene p-n junction superlattices with great potential difference are constructed and integrated into photodetector arrays by substrate engineering with h-BN/SiO2. Efficient hot carrier-assisted photocurrent was generated by laser excitation at the junction under ambient conditions.

  4. Turbulence, combustion, efficiency and emission measurements on a supercharged natural gas SI engine

    Energy Technology Data Exchange (ETDEWEB)

    Einewall, P.; Olsson, Magnus

    1996-08-01

    LDV was used to measure turbulence in six different combustion chambers for a natural gas operated TD102 Volvo truck engine. The efficiency and emissions were measured during supercharged lean operation. The combustion chambers were altered by using pistons with different crown geometries. Some of the load cases require supercharged operation of the engine. The cooling of the cylinder-head was therefore improved. Turbulence, combustion rate, emissions and efficiency was measured for four different piston design. 8 refs, figs

  5. Photoluminescence enhancement through vertical stacking of defect-engineered Ge on Si quantum dots

    Science.gov (United States)

    Groiss, Heiko; Spindlberger, Lukas; Oberhumer, Peter; Schäffler, Friedrich; Fromherz, Thomas; Grydlik, Martyna; Brehm, Moritz

    2017-02-01

    In this work, we show that the room-temperature photoluminescence intensity from Ge ion-bombarded (GIB) epitaxial Ge on Si quantum dots (QD) can be improved by their vertical stacking. We stress that the growth of GIB-QD multilayers is more demanding compared to all-crystalline epitaxial QDs, as a consequence of local amorphous regions within the GIB-QDs required during their genesis. We show that in spite of those amorphous regions, for accurately chosen growth temperatures of the Si spacer layers separating the GIB-QD layers, multiple GIB-QD layers can be stacked without detrimental break-down of epitaxial growth. Compared to a single GIB-QD layer, we observe a 650% increase in PL intensity for an eleven-layer GIB-QD stack, indicating that such multilayers are promising candidates as gain material for all-group-IV nano-photonic lasers.

  6. Increased Efficiency in SI Engine with Air Replaced by Oxygen in Argon Mixture

    Energy Technology Data Exchange (ETDEWEB)

    Killingsworth, N J; Rapp, V H; Flowers, D L; Aceves, S M; Chen, J; Dibble, R

    2010-01-13

    Basic engine thermodynamics predicts that spark ignited engine efficiency is a function of both the compression ratio of the engine and the specific heat ratio of the working fluid. In practice the compression ratio of the engine is often limited due to knock. Both higher specific heat ratio and higher compression ratio lead to higher end gas temperatures and increase the likelihood of knock. In actual engine cycles, heat transfer losses increase at higher compression ratios and limit efficiency even when the knock limit is not reached. In this paper we investigate the role of both the compression ratio and the specific heat ratio on engine efficiency by conducting experiments comparing operation of a single-cylinder variable-compression-ratio engine with both hydrogen-air and hydrogen-oxygen-argon mixtures. For low load operation it is found that the hydrogen-oxygen-argon mixtures result in higher indicated thermal efficiencies. Peak efficiency for the hydrogen-oxygen-argon mixtures is found at compression ratio 5.5 whereas for the hydrogen-air mixture with an equivalence ratio of 0.24 the peak efficiency is found at compression ratio 13. We apply a three-zone model to help explain the effects of specific heat ratio and compression ratio on efficiency. Operation with hydrogen-oxygen-argon mixtures at low loads is more efficient because the lower compression ratio results in a substantially larger portion of the gas to reside in the adiabatic core rather than in the boundary layer and in the crevices, leading to less heat transfer and more complete combustion.

  7. Study on waste heat recovery from exhaust gas spark ignition (S.I. engine using steam turbine mechanism

    Directory of Open Access Journals (Sweden)

    Talib Kamarulhelmy

    2017-01-01

    Full Text Available The issue of global warming has pushed the effort of researchers not only to find alternative renewable energy, but also to improve the machine’s energy efficiency. This includes the utilization of waste energy into ‘useful energy’. For a vehicle using internal combustion engine (ICE, the waste energy produce by exhaust gas can be utilize to ‘useful energy’ up to 34%. The energy from the automotive exhaust can be harness by implementing heat pipe heat exchanger in the automotive system. In order to maximize the amount of waste energy that can be turned to ‘useful energy’, the used of appropriate fluid in the heat exchanger is important. In this study, the fluid used is water, thus converting the fluid into steam and thus drive the turbine that coupling with generator. The paper will explore the performance of a naturally aspirated spark ignition (S.I. engine equipped with waste heat recovery mechanism (WHRM that used water as the heat absorption medium. The experimental and simulation test suggest that the concept is thermodynamically feasible and could significantly enhance the system performance depending on the load applied to the engine.

  8. Mixture Dilution on a Natural Gas SI Engine Operating at Low Load

    Directory of Open Access Journals (Sweden)

    Vávra JiŘí

    2015-01-01

    Full Text Available V článku je prezentován výsledek experimentálního průzkumu spalování zředěné směsi zemního plynu se vzduchem při nízkém zatížení zážehového motoru. Zředění směsi vzduchem a recirkulujícími spalinami bylo porovnáno s provozem na stechiometrickou směs. Byla provedená detailní termodynamická analýza záznamu průběhu tlaku ve válci a byl vyhodnocen a analyzován průběh hoření. Výsledky naznačují potenciál ke zlepšení účinnosti motoru a současně možnost významného snížení emise NOX v surových spalinách v porovnání se spalováním homogenní stechiometrické směsi.

  9. Analytical study to minimize the engine exhaust emissions and safe knock limit of CNG powered four-stroke SI engine

    Directory of Open Access Journals (Sweden)

    Jeewan V. Tirkey, H.N. Gupta, S.K. Shukla

    2010-01-01

    Full Text Available In this paper, theoretical analysis has been done to minimise engine emissions and safe knock limit by changing some operational and design parameters such as equivalence ratio, spark plug location, compression ratio, and cylinder diameter by using computer simulation model. For this purpose a zero dimensional knock model, two zone combustion model(one in front and one behind the flame front, and gas dynamic model have been incorporated. Subsequently, the Nitric Oxide exhaust emission concentrations have been predicted by using the rate kinetic model in the power cycle and along the exhaust pipes. Furthermore, Carbon Monoxide is computed under chemical equilibrium condition and then empirical adjustment is made for kinetic behaviours based upon experimental results. It is inferred that the value of cylinder pressure data, BMEP, BSFC obtained by using computer simulation model based on theoretical analysis are in closer agreement with those which are obtained by previous studies.

  10. Investigation of ecological parameters of four-stroke SI engine, with pneumatic fuel injection system

    Science.gov (United States)

    Marek, W.; Śliwiński, K.

    2016-09-01

    The publication presents the results of tests to determine the impact of using waste fuels, alcohol, to power the engine, on the ecological parameters of the combustion engine. Alternatively fuelled with a mixture of iso- and n-butanol, indicated with "X" and "END, and gasoline and a mixture of fuel and alcohol. The object of the study was a four-stroke engine with spark ignition designed to work with a generator. Motor power was held by the modified system of pneumatic injection using hot exhaust gases developed by Prof. Stanislaw Jarnuszkiewicz, controlled by modern mechatronic systems. Tests were conducted at a constant speed for the intended use of the engine. The subject of the research was to determine the control parameters such as ignition timing, mixture composition and the degree of exhaust gas recirculation on the ecological parameters of the engine. Tests were carried out using partially quality power control. In summary we present the findings of this phase of the study.

  11. Evaluating the effect of methanol-unleaded gasoline blends on SI engine performance

    Directory of Open Access Journals (Sweden)

    B Sabahi

    2015-09-01

    Full Text Available Introduction: Today, all kinds of vehicle engines work with fossil fuels. The limited fossil fuel resources and the negative effects of their consumption on the environment have led researchers to focus on clean, renewable and sustainable energy systems. In all of the fuels being considered as an alternativefor gasoline, methanol is one of the more promising ones and it has experienced major research and development. Methanol can be obtained from many sources, both fossil and renewable; these include coal, natural gas, food industry and municipal waste, wood and agricultural waste. In this study, the effect of using methanol–unleaded gasoline blends on engine performance characteristics has been experimentally investigated. The main objective of the study was to determine engine performance parameters using unleaded gasoline and methanol-unleaded gasoline blends at various engine speeds and loads, and finally achieving an optimal blend of unleaded gasoline and methanol. Materials and Methods: The experimental apparatus consists of an engine test bed with a hydraulic dynamometer which is coupled with a four cylinder, four-stroke, spark ignition engine that is equipped with the carbureted fuel system. The engine has a cylinder bore of 81.5 mm, a stroke of 82.5 mm, and a compression ratio of 7.5:1 with maximum power output of 41.8 kW. The engine speed was monitored continuously by a tachometer, and the engine torque was measured with a hydraulic dynamometer. Fuel consumption was measured by using a calibrated burette (50cc and a stopwatch with an accuracy of 0.01s. In all tests, the cooling water temperature was kept at 82±3˚C. The test room temperature was kept at 29±3˚C during performing the tests. The experiments were performed with three replications. The factors in the experiments were four methanol- unleaded gasoline blends (M0, M10, M20 and M30 and six engine speeds (2000, 2500. 3000, 3500, 4000 and 4500 rpm. Methanol with a purity of

  12. Computation of air and fuel droplet flows in S.I. engine manifolds

    Science.gov (United States)

    Chen, P. Y. P.; Behnia, M.; Milton, B. E.

    The flow of air and fuel mixture similar to that in the induction systems of an Sl engine has been studied. A standard, general purpose single phase CFD code was used with some modifications to account for momentum, mass and heat transfers between the air stream and fuel droplets. Based on a Lagrangian approach, the movement from an assumed spray distribution model of fuel droplets were individually tracked. Models using different assumed coupling between the two phases have been investigated. Under typical engine operating conditions, it was found that a fully coupled treatment for momentum is not required. For estimation of fuel evaporation, a computing time saving one-dimensional treatment was found to be adequate. Fuel film formation on various surfaces of a duct and butterfly valve simulating an engine manifold is reported.

  13. Combustion characteristics of SI engine fueled with methanol-gasoline blends during cold start

    Institute of Scientific and Technical Information of China (English)

    Ruizhi SONG; Tiegang HU; Shenghua LIU; Xiaoqiang LIANG

    2008-01-01

    A 3-cylinder port fuel injection (PFI) engine fueled with methanol-gasoline blends was used to study combustion and emission characteristics. Cylinder pres-sure analysis indicates that engine combustion is improved when methanol is added to gasoline. With the increase of methanol, the flame developing period and the rapid combustion period are shortened, and the indicated mean effective pressure increases during the first 50 cycles. Meanwhile, a novel quasi-instantaneous sampling system was designed to measure engine emissions during cold start and warm-up. The results at 5℃ show that unburned hydrocarbon (UHC) and carbon monoxide (CO) decrease remarkably. Hydrocarbon (HC) reduces by 40% and CO by 70% when fueled with M30 (30% methanol in volume). The exhaust gas temperature is about 140℃ higher at 200 s after operation compared with that of gasoline.

  14. EFFECT OF IGNITION TIMING ON THE PERFORMANCE OF LPG FUELLED SI ENGINE

    Directory of Open Access Journals (Sweden)

    R.M.Dabhadkar

    2013-05-01

    Full Text Available Fast depletion of fossil fuels and their detrimental effect on the environment is demanding an urgent need of alternative fuels for meeting sustainable energy demand with minimum environmental impact.A lot of research is being carried out throughout the world to evaluate the performance, exhaust emission and combustion characteristics of the existing engines using several alternative fuels such as hydrogen, compressed natural gas, alcohols, liquefied petroleum gas (LPG, biogas, producer gas, bio-diesels developed from vegetable oils, and others (Roy et. al, 2010. LPG and CNG are the alternative fuels to be widely adopted for use in the world. Gaseous fuel mix uniformly with air which burns precisely during combustion than liquid fuels. It has minimum carbon deposition & negligible physical delay. Internal combustion engines running on liquid petroleum gas (LPG are well-proven technologies and work much likegasoline-powered spark-ignition engines. They are normally used as spark-ignition engines for bi-fuelled (gasoline/CH4 cars, but have also been used, for example, in compression-ignition engines for heavy-duty vehicles. Both LPG and NG are not used alone, but always in bi-fuel vehicles, in combination with gasoline. In bi-fuel vehicles two fuels are stored in separate tanks and the engine runs on one fuel at a time. Bi-fuel vehicles have the capability to switch back and forth from gasoline to the other fuel, manually or automatically. As a fuel for spark-ignition engines LPG have some advantages over gasoline, such as a better anti-knock characteristic and reduced CO and unburned HC emissions (Hsieh et al., 2002. Environmental point of view is that there is an increasing interest among the suppliers to investigate LPG as a transportation fuel.It was found that the liquid petroleum gas, roughly a mixture of propane and butane, which gives a benefit in terms of toxic hydrocarbons emissions and ozone formation due to its composition and CO2

  15. Plasmonic effect of Ag nanoparticles in a SiON antireflective coating: engineering rules and physical barrier

    Science.gov (United States)

    Lecler, S.; Bastide, S.; Tan, J.; Qu, M.; Slaoui, A.; Fix, T.

    2016-10-01

    Surface plasmon polaritons have been proposed in the architectures of several solar cells as a way to enhance light collection and thus to increase their efficiency. Here, Ag nanoparticles (NPs) are embedded in a SiON antireflective layer using an electroless technique. The plasmonic effects are modeled and observed experimentally for NPs 5 to 200 nm in size. The systematic comparison of scattering and extinction efficiencies computed as a function of the NPs and surrounding medium properties allows establishing engineering rules, validated by the experimental measurements. The fact that Ag NPs larger than 30 nm mainly contribute to light scattering and therefore to optical path enlargement (green-red light), whereas those smaller than 15 nm absorb light by light trapping (blue-green), is demonstrated and physically explained. A physical barrier making it impossible to shift the dominant resonance beyond 650 nm is pointed out.

  16. Numerical simulation of charge stratifications to improve combustion and NO formation of lean-burn SI engines

    Institute of Scientific and Technical Information of China (English)

    Zhijun PENG

    2009-01-01

    The influences of charge stratification on spark ignition (SI) engine combustion and NO emission were analyzed using a phenomenological model. The mixture in the cylinder was divided spherically into three parts: a central core with a stoichiometric air-fuel charge, a dilution region without any combustible charge, and a mixing region lying between the core and the dilution region.Three mixture stratification parameters such as the extent of dilution in the mixing region, the extent of combustible charge in the mixing region, and the gradient of stratification in the mixing region were investigated. The results indicate that the extent of combustible charge in the mixing region could reduce in-cylinder NO formation significantly, compared with the extent of dilution in the mixing region. As long as the degree of dilution in the mixing region is within the dilution limit of the combustible charge, the gradient of dilution has little effect on combustion and NO formation.

  17. Investigation on heat transfer evaluation for a more efficient two-zone combustion model in the case of natural gas SI engines

    OpenAIRE

    Lounici, Mohand Said; Loubar, Khaled; Balistrou, Mourad; Tazerout, Mohand

    2010-01-01

    Abstract Two-zone model is one of the most interesting engine simulation tools, especially for SI engines. However, the pertinence of the simulation depends on the accuracy of the heat transfer model. In fact, an important part of the fuel energy is transformed to heat loss from the chamber walls. Also, knock appearance is closely related to heat exchange. However, in the previous studies using two-zone models, many choices are made for heat transfer evaluation and no choice influe...

  18. Evolution and Engineering of Precisely Controlled Ge Nanostructures on Scalable Array of Ordered Si Nano-pillars

    Science.gov (United States)

    Wang, Shuguang; Zhou, Tong; Li, Dehui; Zhong, Zhenyang

    2016-06-01

    The scalable array of ordered nano-pillars with precisely controllable quantum nanostructures (QNs) are ideal candidates for the exploration of the fundamental features of cavity quantum electrodynamics. It also has a great potential in the applications of innovative nano-optoelectronic devices for the future quantum communication and integrated photon circuits. Here, we present a synthesis of such hybrid system in combination of the nanosphere lithography and the self-assembly during heteroepitaxy. The precise positioning and controllable evolution of self-assembled Ge QNs, including quantum dot necklace(QDN), QD molecule(QDM) and quantum ring(QR), on Si nano-pillars are readily achieved. Considering the strain relaxation and the non-uniform Ge growth due to the thickness-dependent and anisotropic surface diffusion of adatoms on the pillars, the comprehensive scenario of the Ge growth on Si pillars is discovered. It clarifies the inherent mechanism underlying the controllable growth of the QNs on the pillar. Moreover, it inspires a deliberate two-step growth procedure to engineer the controllable QNs on the pillar. Our results pave a promising avenue to the achievement of desired nano-pillar-QNs system that facilitates the strong light-matter interaction due to both spectra and spatial coupling between the QNs and the cavity modes of a single pillar and the periodic pillars.

  19. Energy Efficient Heat Treatment for Linerless Hypereutectic Al-Si Engine Blocks Made Using Vacuum HPDC Process

    Science.gov (United States)

    Kasprzak, W.; Sokolowski, J. H.; Yamagata, H.; Aniolek, M.; Kurita, H.

    2011-02-01

    Heat treatment standards developed by the aluminum industry over the last several decades are often not well optimized when applied to components cast by high cooling rate processes such as High Pressure Die Casting (HPDC), Low Pressure Permanent Mold (LPPM), Squeeze Casting, etc. The inherently finer as-cast structures should not require long solution times for the effective dissolution of intermetallic phases and the adequate thermal modification of structural constituents. Hence, long and expensive T6 and T7 treatments should not be required. Heat treatment studies involving as-cast laboratory samples with SDAS = 13.6 μm (equivalent to a thick-section HPDC casting) were conducted. Traditional and modified solution and aging treatments were compared. These studies suggest that a reduction of up to 92% in thermal processing time is possible while maintaining and/or improving the cast component's metallurgical characteristics including hardness (≥75 HRB), dissolution of secondary phases, and spheroidization of the eutectic Si as well as overall homogeneity. Vacuum HPDC of an actual hypereutectic Al-20%Si motorcycle engine block confirmed the potential for significantly reduced heat treatment times, energy consumption, and overall costs.

  20. Stress engineering with silicon nitride stressors for Ge-on-Si lasers

    CERN Document Server

    Ke, Jiaxin; Guangrui,; Xia,

    2016-01-01

    Side and top silicon nitride stressors were proposed and shown to be effective ways to reduce the threshold current Ith and improve the wall-plug efficiency {\\eta}wp of Ge-on-Si lasers. Side stressors only turned out to be a more efficient way to increase {\\eta}wp than using top and side stressors together. With the side stressors only and geometry optimizations, a {\\eta}wp of 30.5% and an Ith of 50 mA (Jth of 37 kA/cm2) can be achieved with the defect limited carrier lifetime of 1 nsec. With the defect limited carrier lifetime of 10 nsec, an Ith of 7.8 mA (Jth of 5.8 kA/cm2) and a wall-plug efficiency of 38.7% can be achieved. These are tremendous improvements from the case without any stressors. These results give strong support to the Ge-on-Si laser technology and provide an effective way to improve the Ge laser performance.

  1. β decay of Si,4038 (Tz=+5 ,+6 ) to low-lying core excited states in odd-odd P,4038 isotopes

    Science.gov (United States)

    Tripathi, Vandana; Lubna, R. S.; Abromeit, B.; Crawford, H. L.; Liddick, S. N.; Utsuno, Y.; Bender, P. C.; Crider, B. P.; Dungan, R.; Fallon, P.; Kravvaris, K.; Larson, N.; Macchiavelli, A. O.; Otsuka, T.; Prokop, C. J.; Richard, A. L.; Shimizu, N.; Tabor, S. L.; Volya, A.; Yoshida, S.

    2017-02-01

    Low-lying excited states in P,4038 have been identified in the β decay of Tz=+5 ,+6 , Si,4038. Based on the allowed nature of the Gamow-Teller (GT) decay observed, these states are assigned spin and parity of 1+ and are core-excited 1p1h intruder states with a parity opposite to the ground state. The occurrence of intruder states at low energies highlights the importance of pairing and quadrupole correlation energies in lowering the intruder states despite the N =20 shell gap. Configuration interaction shell model calculations with the state-of-art SDPF-MU effective interaction were performed to understand the structure of these 1p1h states in the even-A phosphorus isotopes. States in 40P with N =25 were found to have very complex configurations involving all the f p orbitals leading to deformed states as seen in neutron-rich nuclei with N ≈28 . The calculated GT matrix elements for the β decay highlight the dominance of the decay of the core neutrons rather than the valence neutrons.

  2. Evaluating the effect of methanol-unleaded gasoline blends on SI engine performance

    OpenAIRE

    B Sabahi; M.J Sheikhdavoodi; Bahrami, H.; D Baveli Bahmaei

    2015-01-01

    Introduction: Today, all kinds of vehicle engines work with fossil fuels. The limited fossil fuel resources and the negative effects of their consumption on the environment have led researchers to focus on clean, renewable and sustainable energy systems. In all of the fuels being considered as an alternativefor gasoline, methanol is one of the more promising ones and it has experienced major research and development. Methanol can be obtained from many sources, both fossil and renewable; these...

  3. Shape engineering for electronic and optoelectronic properties of Si nanostructure solar cells

    Science.gov (United States)

    He, Yan; Zhao, Yipeng; Quan, Jun; Ouyang, Gang

    2016-10-01

    An analytical model is developed to explore the shape-dependent electronic and optoelectronic properties of silicon nanostructure solar cells, including nanocones (NCs), nanowires (NWs), and truncated-nanocones (TNCs), on the basis of atomic-bond-relaxation consideration and detailed balance principle. It is found that the inhomogeneous NCs can not only make the band gap shrink gradually from the top to the bottom, but also suppress the surface recombination and enhance light absorption. Moreover, the optimal performance of silicon nanostructures can be achieved through modulating the geometrical parameters. Strikingly, the SiNCs show the highest solar conversion efficiency compared with that of NWs and TNCs under identical conditions, which suggest that this kind of nanostructures could be expected to be applicable for the new-typed and friendly alternative solar cell unit.

  4. Interfacial engineering of solution-processed Ni nanochain-SiOx (x < 2) cermets towards thermodynamically stable, anti-oxidation solar selective absorbers

    Science.gov (United States)

    Yu, Xiaobai; Wang, Xiaoxin; Zhang, Qinglin; Liu, Jifeng

    2016-04-01

    Cermet solar thermal selective absorber coatings are an important component of high-efficiency concentrated solar power (CSP) receivers. The oxidation of the metal nanoparticles in cermet solar absorbers is a great challenge for vacuum-free operation. Recently, we have demonstrated that oxidation is kinetically retarded in solution processed, high-optical-performance Ni nanochain-SiOx cermet system compared to conventional Ni-Al2O3 system when annealed in air at 450-600 °C for several hours. However, for long-term, high-temperature applications in CSP systems, thermodynamically stable antioxidation behavior is highly desirable, which requires new mechanisms beyond kinetically reducing the oxidation rate. Towards this goal, in this paper, we demonstrate that pre-operation annealing of Ni nanochain-SiOx cermets at 900 °C in N2 forms the thermodynamically stable orthorhombic phase of NiSi at the Ni/SiOx interfaces, leading to self-terminated oxidation at 550 °C in air due to this interfacial engineering. In contrast, pre-operation annealing at a lower temperature of 750 °C in N2 (as conducted in our previous work) cannot achieve interfacial NiSi formation directly, and further annealing in air at 450-600 °C for >4 h only leads to the formation of the less stable (metastable) hexagonal phase of NiSi. Therefore, the high-temperature pre-operation annealing is critical to form the desirable orthorhombic phase of NiSi at Ni/SiOx interfaces towards thermodynamically stable antioxidation behavior. Remarkably, with this improved interfacial engineering, the oxidation of 80-nm-diameter Ni nanochain-SiOx saturates after annealing at 550 °C in air for 12 h. Additional annealing at 550 °C in air for as long as 20 h (i.e., 32 h air annealing at >550 °C in total) has almost no further impact on the structural or optical properties of the coatings, the latter being very sensitive to any interfacial changes due to the localized surface plasmon resonances of the metal

  5. Lattice-engineered Si{sub 1-x}Ge{sub x}-buffer on Si(001) for GaP integration

    Energy Technology Data Exchange (ETDEWEB)

    Skibitzki, Oliver, E-mail: skibitzki@ihp-microelectronics.com; Zaumseil, Peter; Yamamoto, Yuji; Andreas Schubert, Markus [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Paszuk, Agnieszka; Hannappel, Thomas [Technische Universität Ilmenau, Gustav-Kirchhoff-Str. 5, 98693 Ilmenau (Germany); Hatami, Fariba; Ted Masselink, W. [Institut für Physik, Humboldt Universität zu Berlin, Newtonstrasse 15, 12489 Berlin (Germany); Trampert, Achim [Paul Drude Institut für Festkörperelektronik, Hausvogteiplatz 5-7, 10117 Berlin (Germany); Tillack, Bernd [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Technische Universität Berlin, HFT4, Einsteinufer 25, 10587 Berlin (Germany); Schroeder, Thomas [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Brandenburgische Technische Universität, Konrad-Zuse Str. 1, 03046 Cottbus (Germany)

    2014-03-14

    We report a detailed structure and defect characterization study on gallium phosphide (GaP) layers integrated on silicon (Si) (001) via silicon-germanium (SiGe) buffer layers. The presented approach uses an almost fully relaxed SiGe buffer heterostructure of only 400 nm thickness whose in-plane lattice constant is matched to GaP—not at room but at GaP deposition temperature. Single crystalline, pseudomorphic 270 nm thick GaP is successfully grown by metalorganic chemical vapour deposition on a 400 nm Si{sub 0.85}Ge{sub 0.15}/Si(001) heterosystem, but carries a 0.08% tensile strain after cooling down to room temperature due to the bigger thermal expansion coefficient of GaP with respect to Si. Transmission electron microscopy (TEM) studies confirm the absence of misfit dislocations in the pseudomorphic GaP film but growth defects (e.g., stacking faults, microtwins, etc.) especially at the GaP/SiGe interface region are detected. We interpret these growth defects as a residue of the initial 3D island coalescence phase of the GaP film on the SiGe buffer. TEM-energy-dispersive x-ray spectroscopy studies reveal that these defects are often correlated with stoichiometric inhomogeneities in the GaP film. Time-of-flight Secondary ion mass spectrometry detects sharp heterointerfaces between GaP and SiGe films with a minor level of Ga diffusion into the SiGe buffer.

  6. Material gain engineering in GeSn/Ge quantum wells integrated with an Si platform

    Science.gov (United States)

    Mączko, H. S.; Kudrawiec, R.; Gladysiewicz, M.

    2016-09-01

    It is shown that compressively strained Ge1‑xSnx/Ge quantum wells (QWs) grown on a Ge substrate with 0.1 ≤ x ≤ 0.2 and width of 8 nm ≤ d ≤ 14 nm are a very promising gain medium for lasers integrated with an Si platform. Such QWs are type-I QWs with a direct bandgap and positive transverse electric mode of material gain, i.e. the modal gain. The electronic band structure near the center of Brillouin zone has been calculated for various Ge1‑xSnx/Ge QWs with use of the 8-band kp Hamiltonian. To calculate the material gain for these QWs, occupation of the L valley in Ge barriers has been taken into account. It is clearly shown that this occupation has a lot of influence on the material gain in the QWs with low Sn concentrations (Sn  15%). However, for QWs with Sn > 20% the critical thickness of a GeSn layer deposited on a Ge substrate starts to play an important role. Reduction in the QW width shifts up the ground electron subband in the QW and increases occupation of the L valley in the barriers instead of the Γ valley in the QW region.

  7. COLD START CHARACTERISTICS STUDY BASED ON REAL TIME NO EMISSIONS IN AN LPG SI ENGINE

    Directory of Open Access Journals (Sweden)

    Yingli Zu

    2010-01-01

    Full Text Available Normally, cylinder pressure was used as a criterion of combustion occurrence, while in some conditions, it may be unreliable when identifying lean mixture combustion. This is particularly important for fuels like liquefied petroleum gas, which has good capacity for lean combustion. In this study, a fast response NO detector, based on the chemiluminescence method, was used to measure real time NO emissions in order to evaluate the technique as a criterion for establishing combustion occurrence. Test results show that real time NO emissions can be used to identify the cylinder combustion and misfire occurrence during engine cranking, and real time NO emissions can be used to understand the combustion and misfire occurrence. Real time NO emissions mostly happened in first several cycles during cold start, and NO emissions increased with the spark timing advancing.

  8. Chemical, physical and isotopic characterization of U{sub 3}Si{sub 2}, for nuclear forensics purposes; Caracterizacao quimica, fisica e isotopica de U{sub 3}Si{sub 2} para fins forenses nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Rosa, Daniele Scarpim

    2011-07-01

    In the early 1990's, the first illicit trafficking of nuclear and radioactive materials was observed mainly in Europe. A decade marked by numerous cases of seizures of these materials. As a result, these events have become the subject of criminal forensic investigations and develop from there, nuclear forensics. In Brazil there are no illicit trafficking official records of nuclear material, however, is widely known the extraction and illegal transportation of radioactive geological materials, and the materials pieces attachment used as shielding for radioactive sources. One of the main tools used in nuclear forensics is the nuclear materials databases establishment. These documents must contain the most information as possible about the physical, chemical and nuclear material seized, allowing the identification of their origin, manufacturing process or age. Thus, it sets characteristic composition standards of each material, called 'chemical signatures' (chemical finger print). In this work nuclear forensic protocol was adopted as well as the three stages of assessment suggested by International Atomic Energy Agency (IAEA) in identifying the origin of uranium silicide (U{sub 3}Si{sub 2}). Assays were performed in order to make physical, chemical and isotopic characterization of the studied materials and compared the data with those obtained for other uranium compounds (Uranium tetrafluoride, UF{sub 4}; uranium oxide, UO{sub 2} and U{sub 3}O{sub 8}; Yellow cake) by establishing a characteristic signature for each one. Through the assays the uranium compounds were classify by origin groups, as far as they are from different manufactured process and/ or origin. It was also possible to show the importance of a nuclear forensic database during an investigation of a nuclear forensic event. (author)

  9. Using Carbon-14 Isotope Tracing to Investigate Molecular Structure Effects of the Oxygenate Dibutyl Maleate on Soot Emissions from a DI Diesel Engine

    Energy Technology Data Exchange (ETDEWEB)

    Buchholz, B A; Mueller, C J; Upatnieks, A; Martin, G C; Pitz, W J; Westbrook, C K

    2004-01-07

    The effect of oxygenate molecular structure on soot emissions from a DI diesel engine was examined using carbon-14 ({sup 14}C) isotope tracing. Carbon atoms in three distinct chemical structures within the diesel oxygenate dibutyl maleate (DBM) were labeled with {sup 14}C. The {sup 14}C from the labeled DBM was then detected in engine-out particulate matter (PM), in-cylinder deposits, and CO{sub 2} emissions using accelerator mass spectrometry (AMS). The results indicate that molecular structure plays an important role in determining whether a specific carbon atom either does or does not form soot. Chemical-kinetic modeling results indicate that structures that produce CO{sub 2} directly from the fuel are less effective at reducing soot than structures that produce CO before producing CO{sub 2}. Because they can follow individual carbon atoms through a real combustion process, {sup 14}C isotope tracing studies help strengthen the connection between actual engine emissions and chemical-kinetic models of combustion and soot formation/oxidation processes.

  10. Research on Control-Oriented Modeling for Turbocharged SI and DI Gasoline Engines

    Directory of Open Access Journals (Sweden)

    Feitie Zhang

    2015-01-01

    Full Text Available In order to analyze system performance and develop model-based control algorithms for turbocharged spark ignition and direct injection (SIDI gasoline engines, a control oriented mean value model is developed and validated. The model is constructed based on theoretical analysis for the different components, including the compressor, turbine, air filter, intercooler, throttle, manifold, and combustion chamber. Compressor mass flow and efficiency are modeled as parameterized functions. A standard nozzle model is used to approximate the mass flow through the turbine, and the turbine efficiency is modeled as a function of blade speed ratio (BSR. The air filter is modeled as a tube for capturing its pressure drop feature. The effectiveness number of transfer units (NTU modeling method is utilized for the intercooler. The throttle model consists of the standard nozzle model with an effective area regressed to throttle position. Manifolds are modeled for their dynamically varying pressure state. For the cylinder, the air mass flow into cylinders, fuel mass, torque, and exhaust temperature are modeled. Compared to the conventional lookup table approach, transient dynamics error can be improved significantly through using the model from this work.

  11. Effective work function engineering for a TiN/XO(X = La, Zr, Al)/SiO{sub 2} stack structures

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Dongjin, E-mail: dongjin0710.lee@samsung.com; Lee, Jieun; Jung, Kyoungho; Jeong, Moonyoung; Yamada, Satoru; Hong, Hyeongsun; Lee, Kyupil [DRAM Technology Development Team, Semiconductor R& D Center, 1, Samsungjeonja-ro, Hwaseong-si, Gyeonggi-do 18448 (Korea, Republic of); Cho, Eunae; Heo, Sung, E-mail: prestine@hanmail.net; Ko, Dongsu; Kim, Yong Su; Kyoung, Yong Koo; Lee, Hyung-Ik; Lee, Hyo Sug; Park, Gyeong-Su; Shin, Jai Kwang [Platform Technology Lab, Samsung Advanced Institute of Technology, 130, Samsung-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do 16678 (Korea, Republic of)

    2016-05-23

    In this study, we demonstrated that work function engineering is possible over a wide range (+200 mV to −430 mV) in a TiN/XO (X = La, Zr, or Al)/SiO{sub 2} stack structures. From ab initio simulations, we selected the optimal material for the work function engineering. The work function engineering mechanism was described by metal diffusion into the TiN film and silicate formation in the TiN/SiO{sub 2} interface. The metal doping and the silicate formation were confirmed by transmission electron microscopy and energy dispersive spectroscopy line profiling, respectively. In addition, the amount of doped metal in the TiN film depended on the thickness of the insertion layer XO. From the work function engineering technique, which can control a variety of threshold voltages (Vth), an improvement in transistors with different V{sub th} values in the TiN/XO/SiO{sub 2} stack structures is expected.

  12. Silicon isotopes: from cosmos to benthos

    OpenAIRE

    Chakrabarti, Ramananda

    2015-01-01

    Silicon is the second most abundant element on the Earth and one of the more abundant elements in our Solar System. Variations in the relative abundance of the stable isotopes of Si (Si isotope fractionation) in different natural reservoirs, both terrestrial (surface and deep Earth) as well as extra-terrestrial (e.g. meteorites, lunar samples), are a powerful tracer of present and past processes involving abiotic as well as biotic systems. The versatility of the Si isotope tracer is reflected...

  13. Experimental Investigation of 2nd Generation Bioethanol Derived from Empty-fruit-bunch (EFB of Oil-palm on Performance and Exhaust Emission of SI Engine

    Directory of Open Access Journals (Sweden)

    Yanuandri Putrasari

    2014-07-01

    Full Text Available The experimental investigation of 2nd generation bioethanol derived from EFB of oil-palm blended with gasoline for 10, 20, 25% by volume and pure gasoline were conducted on performance and exhaust emission tests of SI engine. A four stroke, four cylinders, programmed fuel injection (PGMFI, 16 valves variable valve timing and electronic lift control (VTEC, single overhead camshaft (SOHC, and 1,497 cm3 SI engine (Honda/L15A was used in this investigation. Engine performance test was carried out for brake torque, power, and fuel consumption. The exhaust emission was analyzed for carbon monoxide (CO and hydrocarbon (HC. The engine was operated on speed range from1,500 until 4,500 rev/min with 85% throttle opening position. The results showed that the highest brake torque of bioethanol blends achieved by 10% bioethanol content at 3,000 to 4,500 rpm, the brake power was greater than pure gasoline at 3,500 to 4,500 rpm for 10% bioethanol, and bioethanol-gasoline blends of 10 and 20% resulted greater bsfc than pure gasoline at low speed from 1,500 to 3,500 rpm. The trend of CO and HC emissions tended to decrease when the engine speed increased.

  14. Silicon isotope fractionation during magmatic differentiation

    Science.gov (United States)

    Savage, Paul S.; Georg, R. Bastian; Williams, Helen M.; Burton, Kevin W.; Halliday, Alex N.

    2011-10-01

    The Si isotopic composition of Earth's mantle is thought to be homogeneous (δ 30Si = -0.29 ± 0.08‰, 2 s.d.) and not greatly affected by partial melting and recycling. Previous analyses of evolved igneous material indicate that such rocks are isotopically heavy relative to the mantle. To understand this variation, it is necessary to investigate the degree of Si isotopic fractionation that takes place during magmatic differentiation. Here we report Si isotopic compositions of lavas from Hekla volcano, Iceland, which has formed in a region devoid of old, geochemically diverse crust. We show that Si isotopic composition varies linearly as a function of silica content, with more differentiated rocks possessing heavier isotopic compositions. Data for samples from the Afar Rift Zone, as well as various igneous USGS standards are collinear with the Hekla trend, providing evidence of a fundamental relationship between magmatic differentiation and Si isotopes. The effect of fractionation has been tested by studying cumulates from the Skaergaard Complex, which show that olivine and pyroxene are isotopically light, and plagioclase heavy, relative to the Si isotopic composition of the Earth's mantle. Therefore, Si isotopes can be utilised to model the competing effects of mafic and felsic mineral fractionation in evolving silicate liquids and cumulates. At an average SiO 2 content of ˜60 wt.%, the predicted δ 30Si value of the continental crust that should result from magmatic fractionation alone is -0.23 ± 0.05‰ (2 s.e.), barely heavier than the mantle. This is, at most, a maximum estimate, as this does not take into account weathered material whose formation drives the products toward lighter δ 30Si values. Mass balance calculations suggest that removal of continental crust of this composition from the upper mantle will not affect the Si isotopic composition of the mantle.

  15. Ternary GeSiSn alloys: New opportunities for strain and band gap engineering using group-IV semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    D' Costa, V.R. [Department of Physics, Arizona State University, Tempe, AZ 85287-1504 (United States); Fang, Y.-Y.; Tolle, J.; Kouvetakis, J. [Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287-1604 (United States); Menendez, J. [Department of Physics, Arizona State University, Tempe, AZ 85287-1504 (United States)

    2010-02-26

    Ternary GeSiSn alloys have been recently demonstrated on Ge- and GeSn-buffered Si substrates. These alloys, with a two-dimensional compositional space, make it possible to decouple lattice constant and electronic structure for the first time in a group-IV system. This paper reviews the basic properties of the GeSiSn alloy, presents some new results on its optical properties, and discusses the approach that has been followed to model heterostructures containing GeSiSn layers for applications in modulators, quantum cascade lasers, and photovoltaics.

  16. Experimental evaluation of the effect of compression ratio on performance and emission of SI engine fuelled with gasoline and n-butanol blend at different loads

    Directory of Open Access Journals (Sweden)

    Rinu Thomas

    2016-09-01

    Full Text Available Never ending demand for efficient and less polluting engines have always inspired newer technologies. Extensive study has been done on variable compression ratio, a promising in-cylinder technology, in the recent past. The present work is an experimental investigation to examine the variation of different parameters such as brake thermal efficiency, exhaust gas temperature and emissions with respect to change in compression ratio in a single-cylinder carbureted SI engine at different loads with two different fuels. Experiments were conducted at three different compression ratios (CR = 7:1, 8.5:1 and 10:1. The fuels used in this study are pure gasoline and 20% n-butanol blend (B20 in gasoline. The results showed that brake thermal efficiency increases with CR at all loads. Further, the experimental results showed the scope of improving the part-load efficiency of SI engine by adopting the concept of variable compression ratio (VCR technology, especially when fuels with better anti-knock characteristics are used. The uncertainty analysis of the experiments based on the specifications of the equipment used is also tabulated.

  17. Isotope tracing ({sup 29}Si and {sup 18}O) of the alteration mechanisms of the French glass 'SON68' used for the storage of nuclear waste; Tracage isotopique ({sup 29}Si and {sup 18}O) des mecanismes de l'alteration du verre de confinement des dechets nucleaires: 'SON68'

    Energy Technology Data Exchange (ETDEWEB)

    Valle, N

    2001-07-01

    This study aims to enhance our understanding of the mechanisms of aqueous corrosion of the glasses used for the storage of nuclear waste. Glass samples 'SON68', doped with a different rare earth element (La, Ce or Nd), were altered simultaneously with water enriched in {sup 29}Si and {sup 18}O, throughout a period of 20 months. The aim of such isotope tracing was (i) to follow the 'real' exchanges between glass and solution and (ii) to understand the reactions involving Si-O bonds in the leached layer during alteration. Leachates were analyzed by ICP-MS and -AES, and elemental and isotopic variations in the altered glass layer were measured by ion-probe, using a depth profiling technique. Elemental analyses enabled the distribution of the elements in the two layers of altered glass (phyllosilicates and gel) to be established, and the results reveal a selective partitioning of elements between the two layers. Isotopic analyses of altered layers and leachates allowed phyllosilicates to be distinguished from gel, and suggest two different mechanisms of formation. Whilst phyllosilicates grow on the surface of the glass by a mechanism of precipitation, gel is formed by a succession of hydrolysis / condensation reactions taking place mainly at the gel / pristine glass interface. This gel is formed by the in situ rearrangement of hydrated species, without reaching equilibrium with the solution. Moreover, an experimental technique has been developed enabling one to trace the transport of silicon from the solution into the altered glasses, under an isotopic gradient. Diffusion profiles, obtained by ion-probe, have been modeled and have allowed the determination of the apparent silicon diffusion coefficient (DSi) in gels. Therefore, our experiments have permitted the quantification of the influence of both the alteration conditions (dynamic or static tests) and the solution composition on the value of DSi. (author)

  18. The influence of high-octane fuel blends on the performance of a two-stroke SI engine with knock-limited-compression ratio

    Science.gov (United States)

    Poola, Ramesh B.; Bhasker, T.; Nagalingam, B.; Gopalakrishnan, K. V.

    The use of alcohol-gasoline blends enables the favorable features of alcohols to be utilized in spark ignition (SI) engines while avoiding the shortcomings of their application as straight fuels. Eucalyptus and orange oils possess high octane values and are also good potential alternative fuels for SI engines. The high octane value of these fuels can enhance the octane value of the fuel when it is blended with low-octane gasoline. In the present work, 20 percent by volume of orange oil, eucalyptus oil, methanol and ethanol were blended separately with gasoline, and the performance, combustion and exhaust emission characteristics were evaluated at two different compression ratios. The phase separation problems arising from the alcohol-gasoline blends were minimized by adding eucalyptus oil as a cosolvent. Test results indicate that the compression ratio can be raised from 7.4 to 9 without any detrimental effect, due to the higher octane rating of the fuel blends. Knock-limited maximum brake output also increases due to extension of the knock limit. The knock limit is extended by methanol-eucalyptus-ethanol-orange oil blends, in descending order.

  19. Uniform Silicon Isotope Ratios Across the Milky Way Galaxy

    Science.gov (United States)

    Monson, Nathaniel N.; Morris, Mark R.; Young, Edward D.

    2017-04-01

    We report the relative abundances of the three stable isotopes of silicon, 28Si, 29Si, and 30Si, across the Galaxy using the v=0,J=1\\to 0 transition of silicon monoxide. The chosen sources represent a range in Galactocentric radii ({R}{GC}) from 0 to 9.8 kpc. The high spectral resolution and sensitivity afforded by the Green Bank Telescope permit isotope ratios to be corrected for optical depths. The optical-depth-corrected data indicate that the secondary-to-primary silicon isotope ratios {}29{Si}{/}28{Si} and {}30{Si}{/}28{Si} vary much less than predicted on the basis of other stable isotope ratio gradients across the Galaxy. Indeed, there is no detectable variation in Si isotope ratios with {R}{GC}. This lack of an isotope ratio gradient stands in stark contrast to the monotonically decreasing trend with {R}{GC} exhibited by published secondary-to-primary oxygen isotope ratios. These results, when considered in the context of the expectations for chemical evolution, suggest that the reported oxygen isotope ratio trends, and perhaps those for carbon as well, require further investigation. The methods developed in this study for SiO isotopologue ratio measurements are equally applicable to Galactic oxygen, carbon, and nitrogen isotope ratio measurements, and should prove useful for future observations of these isotope systems.

  20. Silicon isotopes reveal recycled altered oceanic crust in the mantle sources of Ocean Island Basalts

    CERN Document Server

    Pringle, Emily A; Savage, Paul S; Jackson, Matthew G; Day, James M D

    2016-01-01

    The study of silicon (Si) isotopes in ocean island basalts (OIB) has the potential to discern between different models for the origins of geochemical heterogeneities in the mantle. Relatively large (several per mil per atomic mass unit) Si isotope fractionation occurs in low-temperature environments during biochemical and geochemical precipitation of dissolved Si, where the precipitate is preferentially enriched in the lighter isotopes relative to the dissolved Si. In contrast, only a limited range (tenths of a per mil) of Si isotope fractionation has been observed from high-temperature igneous processes. Therefore, Si isotopes may be useful as tracers for the presence of crustal material within OIB mantle source regions that experienced relatively low-temperature surface processes in a manner similar to other stable isotope systems, such as oxygen. Characterizing the isotopic composition of the mantle is also of central importance to the use of the Si isotope system as a basis for comparisons with other plan...

  1. Large recovery strain in Fe-Mn-Si-based shape memory steels obtained by engineering annealing twin boundaries.

    Science.gov (United States)

    Wen, Y H; Peng, H B; Raabe, D; Gutierrez-Urrutia, I; Chen, J; Du, Y Y

    2014-09-17

    Shape memory alloys are a unique class of materials that can recover their original shape upon heating after a large deformation. Ti-Ni alloys with a large recovery strain are expensive, while low-cost conventional processed Fe-Mn-Si-based steels suffer from a low recovery strain (twin boundaries. Reducing the density of twin boundaries is thus a critical factor for obtaining a large recovery strain in these steels. By significantly suppressing the formation of twin boundaries, we attain a tensile recovery strain of 7.6% in an annealed cast polycrystalline Fe-20.2Mn-5.6Si-8.9Cr-5.0Ni steel (weight%). Further attractiveness of this material lies in its low-cost alloying components and simple synthesis-processing cycle consisting only of casting plus annealing. This enables these steels to be used at a large scale as structural materials with advanced functional properties.

  2. 100 mm Engineered InP-on-Si Laminate Substrates for InP-based Multijunction Solar Cells

    Energy Technology Data Exchange (ETDEWEB)

    Atwater, Harry [California Inst. of Technology (CalTech), Pasadena, CA (United States)

    2012-06-25

    The project focused on fabrication of InP/Si laminate substrates as templates for growth of InGaAsP/InGaAs and InAlAs/InGaAsP/InGaAs multijunction solar cells. InP/Si template substrates were developed and used as templates for InGaAs solar growth. A novel feature of the program was development of the virtual substrate template, which enables a substrate to be formed with a lattice constant intermediate between those of GaAs and InP. Large-area virtual substrate templates were formed by transfer and bonding of dislocation free InGaAs films wafer onto silicon substrates.

  3. 100 mm Engineered InP-on-Si Laminate Substrates for InP-based Multijunction Solar Cells

    Energy Technology Data Exchange (ETDEWEB)

    Atwater, Harry [California Inst. of Technology (CalTech), Pasadena, CA (United States)

    2012-06-25

    The project focused on fabrication of InP/Si laminate substrates as templates for growth of InGaAsP/InGaAs and InAlAs/InGaAsP/InGaAs multijunction solar cells. InP/Si template substrates were developed and used as templates for InGaAs solar growth. A novel feature of the program was development of the virtual substrate template, which enables a substrate to be formed with a lattice constant intermediate between those of GaAs and InP. Large-area virtual substrate templates were formed by transfer and bonding of dislocation free InGaAs films wafer onto silicon substrates.

  4. Engineered Si electrode nanoarchitecture: a scalable postfabrication treatment for the production of next-generation Li-ion batteries.

    Science.gov (United States)

    Hassan, Fathy M; Chabot, Victor; Elsayed, Abdel Rahman; Xiao, Xingcheng; Chen, Zhongwei

    2014-01-08

    A novel, economical flash heat treatment of the fabricated silicon based electrodes is introduced to boost the performance and cycle capability of Li-ion batteries. The treatment reveals a high mass fraction of Si, improved interfacial contact, synergistic SiO2/C coating, and a conductive cellular network for improved conductivity, as well as flexibility for stress compensation. The enhanced electrodes achieve a first cycle efficiency of ∼84% and a maximum charge capacity of 3525 mA h g(-1), almost 84% of silicon's theoretical maximum. Further, a stable reversible charge capacity of 1150 mA h g(-1) at 1.2 A g(-1) can be achieved over 500 cycles. Thus, the flash heat treatment method introduces a promising avenue for the production of industrially viable, next-generation Li-ion batteries.

  5. Engineering of silicon-based ceramic fibers: Novel SiTaC(O) ceramic fibers prepared from polytantalosilane

    Energy Technology Data Exchange (ETDEWEB)

    Xie, Z., E-mail: xiezhengfang@163.com [State Key Laboratory of Advanced Ceramic Fibers and Composites, National University of Defense Technology, Changsha 410073 (China); Cao, S.; Wang, J. [State Key Laboratory of Advanced Ceramic Fibers and Composites, National University of Defense Technology, Changsha 410073 (China); Yan, X. [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Bernard, S., E-mail: Samuel.Bernard@univ-lyon1.fr [Laboratoire des Multimateriaux et Interfaces (UMR CNRS 5615), Universite de Lyon, Universite Lyon1, 43 bd du 11 Novembre 1918, 69622 Villeurbanne Cedex (France); Miele, P. [Laboratoire des Multimateriaux et Interfaces (UMR CNRS 5615), Universite de Lyon, Universite Lyon1, 43 bd du 11 Novembre 1918, 69622 Villeurbanne Cedex (France)

    2010-10-15

    Research highlights: {yields} This paper reports the preparation and characterization of a novel variety of silicon-based ceramic fibers. {yields} In the present paper, we provide a detailed picture of the preparation process of SiTaC(O) ceramic fibers from a polytantalosilane. {yields} We have fully characterized the polymer by FT-IR, NMR, chemical composition, GPC and TGA as well as the chemical composition, the structure, the texture, and the mechanical properties of the ceramic fibers by XPS, SEM, X-ray diffraction (XRD), and mechanical tests. - Abstract: A novel variety of silicon-based ceramic fibers has been prepared from a preceramic organosilicon polymers called polytantalocarbosilane (PTaCS). This melt-spinnable polymer has been synthesized by thermally induced reactions between tantalum (V) tetraethoxyacetylacetonate (Ta(Acac)(OEt){sub 4}) and polysilacarbosilane (PSCS). The polymer in which [-Si-C-]{sub n} chains are crosslinked via Ta-containing bridges as identified by infrared spectroscopy, XPS and NMR, is decomposed in high ceramic yield (76%) and can be spun in the molten state into fibers to be cured in air then pyrolyzed in flowing nitrogen at 1200 deg. C into amorphous SiTaC(O) fibers. Complete characterization of this new generation of silicon-based ceramic fibers was made based on mechanical tests, XRD and SEM. These fibers exhibit relatively good mechanical properties and excellent high-temperature stability with good oxidation resistance.

  6. High-k dielectrics based field plate edge termination engineering in 4H-SiC Schottky diode

    Science.gov (United States)

    Shankar, Bhawani; Gupta, Sanjeev K.; Taube, William R.; Akhtar, J.

    2016-12-01

    This paper develops a deep insight into the behaviour of high-k dielectric-based field plate on Ni/4H-SiC Schottky diode. It tries to explain the mechanism by which high-k materials outperform silicon dioxide, when used under the field plate. Phenomena like modulation of field enhancement factor, reshaping of equipotential contours and expansion of depletion region while maintaining fixed depletion ratio (length/width = 2.3) helps to understand the electrical behaviour of high-k dielectric-based field plate. High-k materials relaxed the equipotential contours under the field plate edge which resulted in electric field reduction up to 88% and significant drop from 6.6 to 2.2 in field enhancement factor at device edges. The study considers the field plate of different dielectrics (SiO2, Si3N4, Al203, HfO2) and in each case, analytically explores the optimisation of field plate parameters (overlap length and dielectric thickness, dielectric constant). All the investigations have been done using numerical simulations on calibrated setup.

  7. Study of NOx Emissions of S.I. Engine Fueled with Different Kinds of Hydrocarbon Fuels and Hydrogen

    Directory of Open Access Journals (Sweden)

    Qahtan A. Abass

    2010-01-01

    Full Text Available Liquefied petroleum gas (LPG, Natural gas (NG and hydrogen were used to operate spark ignition internal combustion engine Ricardo E6, to compare NOx emissions emitted from the engine, with that emitted from engine fueled with gasoline as a fuel.The study was done when engine operated at HUCR for gasoline, compared with its operation at HUCR for each fuel. Compression ratio, equivalence ratio and spark timing were studied at constant speed 25rps.The results appeared that NOx concentrations will be at maximum value in the lean side near the stoichiometric ratio, and reduced with moving away from this ratio for mixture at both sides, these concentrations were at its highest value when hydrogen used at CR=8:1, and got near to each other for the three hydrocarbon fuels used in the study, when the engine operated at HUCR for each fuel, but still hydrogen had maximum value, the main variable affect these concentrations was spark timing

  8. Effect of precipitation, sorption and stable of isotope on maximum release rates of radionuclides from engineered barrier system (EBS) in deep repository.

    Science.gov (United States)

    Malekifarsani, A; Skachek, M A

    2009-10-01

    The basic function of the engineered barrier system (EBS) in geological disposal is to prevent or limit the release of radionuclides into the underground environment. For this purpose, the vitrified waste is contained in an overpack to isolate it from contact with groundwater for a certain initial period of time. However, it is impossible to ensure complete containment for all time. Therefore, the eventual release of nuclides must be minimized after the overpack fails (AEC, 1984. Radioactive waste processing and disposal measures; JNC, 2000a. Project to establish the scientific and technical basis for HLW disposal in Japan--first progress report-H3. Geological Environment in Japan, JNC TN1410 2000-002; JNC, 2000b. H12: project to establish the scientific and technical basis for HLW disposal in Japan--repository design and engineering technology, JNC TN1410 2000-003.). Low-permeability buffer material is installed between the overpack and the host rock to ensure that radionuclide release from the vitrified waste is limited by diffusive transport rather than advective transport in groundwater. Nuclides released from the waste form precipitate when their concentrations in the porewater result in their elemental solubility limits being exceeded. This limits the concentrations of many nuclides in the buffer and thus limits the release rates to the surrounding rock. High sorption coefficients act to delay the transport of certain nuclides during their migration through the buffer (PNC, development and management of the technical knowledge base for the geological disposal of HLW. Supporting report 2: repository engineering technology). The presence of isotopes of the same element has the effect of reducing the effective solubility of some nuclides; a lower nuclide concentration is required for precipitation to occur if the presence of any isotopes of the same element is taken into account. The calculated release rates of radionuclides from the EBS (per waste package) are

  9. Study of SI-HCCI-SI Transition on a Port Fuel Injection Engine Equipped with 4VVAS%4VVAS双模式发动机SI-HCCI燃烧模式过渡研究

    Institute of Scientific and Technical Information of China (English)

    张岩; 谢辉; 周能辉; 陈韬; 赵华

    2008-01-01

    提出一种可以实现SI/HCCI双模式运行的汽油机方案.将自行设计和研制的基于进排气门升程和相位等4个变量连续可变的HCCI(Homogeneous Charge Compression Igniton)汽油机缸盖安装在单缸试验机上,建立了4VVAS-HCCI汽油机原理性样机平台.通过在该平台上的试验研究,探索了HCCI/SI两种燃烧模式过渡过程的动态控制策略.结果表明:配备4VVAS(4 Variable Valve Actuaion System)缸盖的发动机,可以根据工况需要运行于HCCI或SI(Spark Ignition)燃烧模式;通过4VVAS系统对内部残余废气快速有效管理,可以完成HCCI-SI动态平滑过渡;由于热惯性的存在,从SI向HCCI燃烧模式过渡难于从HCCI向SI过渡;对燃烧模式过渡过程的控制可以归结为对残余废气率的动态管理和对混合放热率型线的设计.

  10. System Design and Analysis of a Directly Air-Assisted Turbocharged SI Engine with Camshaft Driven Valves

    Directory of Open Access Journals (Sweden)

    Lino Guzzella

    2013-03-01

    Full Text Available The availability of compressed air in combination with downsizing and turbocharging is a promising approach to improve the fuel economy and the driveability of internal combustion engines. The compressed air is used to boost and start the engine. It is generated during deceleration phases by running the engine as a piston compressor. In this paper, a camshaft-driven valve is considered for the control of the air exchange between the tank and the combustion chamber. Such a valve system is cost-effective and robust. Each pneumatic engine mode is realized by a separate cam. The air mass transfer in each mode is analyzed. Special attention is paid to the tank pressure dependence. The air demand in the boost mode is found to increase with the tank pressure. However, the dependence on the tank pressure is small in the most relevant operating region. The air demand of the pneumatic start shows a piecewise continuous dependence on the tank pressure. Finally, a tank sizing method is proposed which uses a quasi-static simulation. It is applied to a compact class vehicle, for which a tank volume of less than 10 L is sufficient. A further reduction of the tank volume is limited by the specifications imposed on the pneumatic start.

  11. System Design and Analysis of a Directly Air-Assisted Turbocharged SI Engine with Camshaft Driven Valves

    Energy Technology Data Exchange (ETDEWEB)

    Voser, Christoph; Onder, Christopher; Guzzella, Lino [Institute for Dynamic Systems and Control, ETH Zurich (Switzerland)

    2013-04-15

    The availability of compressed air in combination with downsizing and turbocharging is a promising approach to improve the fuel economy and the driveability of internal combustion engines. The compressed air is used to boost and start the engine. It is generated during deceleration phases by running the engine as a piston compressor. In this paper, a camshaft-driven valve is considered for the control of the air exchange between the tank and the combustion chamber. Such a valve system is cost-effective and robust. Each pneumatic engine mode is realized by a separate cam. The air mass transfer in each mode is analyzed. Special attention is paid to the tank pressure dependence. The air demand in the boost mode is found to increase with the tank pressure. However, the dependence on the tank pressure is small in the most relevant operating region. The air demand of the pneumatic start shows a piecewise continuous dependence on the tank pressure. Finally, a tank sizing method is proposed which uses a quasi-static simulation. It is applied to a compact class vehicle, for which a tank volume of less than 10 L is sufficient. A further reduction of the tank volume is limited by the specifications imposed on the pneumatic start.

  12. 40 CFR 1045.605 - What provisions apply to engines already certified under the motor vehicle or Large SI programs?

    Science.gov (United States)

    2010-07-01

    ... engines under 40 CFR parts 85 and 86 or part 1048 for the appropriate model year. If you comply with all the provisions of this section, we consider the certificate issued under 40 CFR part 86 or 1048 for... meet all the applicable requirements from 40 CFR parts 85 and 86, or part 1048. This applies to...

  13. Optimization of Phase-Engineered a-Si:H-Based Multi-Junction Solar Cells: Final Technical Report, October 2001-July 2005

    Energy Technology Data Exchange (ETDEWEB)

    Wronski, C. R.; Collins, R. W.; Podraza, N. J.; Vlahos, V.; Pearce, J. M.; Deng, J.; Albert, M.; Ferreira, G. M.; Chen, C.

    2006-08-01

    The scope of the work under this subcontract has involved investigating engineered improvements in the performance and stability of solar cells in a systematic way, which included the following four tasks: (1) Materials research and device development; (2) Process improvement directed by real time diagnostics; (3) Device loss mechanisms; and (4) Characterization strategies for advanced materials Our work has resulted in new and important insights into the deposition of a-Si:H-based materials, as well as into the nature of the Staebler-Wronski Effect (SWE). Presumably, many of these insights will be used by industrial partners to develop more systematic approaches in optimizing solar cells for higher performance and stability. This effort also cleared up several serious misconceptions about the nature of the p-layer in cells and the SWE in materials and cells. Finally, the subcontract identified future directions that should be pursued for greater understanding and improvement.

  14. Biocompatibility studies of endothelial cells on a novel calcium phosphate/SiO{sub 2}-xerogel composite for bone tissue engineering

    Energy Technology Data Exchange (ETDEWEB)

    Thimm, Benjamin W; Unger, Ronald E; Kirkpatrick, C James [Institute of Pathology, Johannes Gutenberg-University Mainz, Langenbeckstr.1, 55101 Mainz (Germany); Neumann, Hans-Georg [DOT GmbH, Charles-Darwin-Ring 1a, 18059 Rostock (Germany)], E-mail: runger@uni-mainz.de

    2008-03-01

    The bone biomaterial BONITmatrix, a nanoporous, granular scaffold composed of hydroxylapatite, calcium phosphate and SiO{sub 2}, linked by a dense collagen mesh, was tested for its biocompatibility using endothelial cells (EC) in the form of macrovascular HUVEC, microvascular HDMEC and the endothelial cell line ISOHAS-1. Cells were examined for their adherence and growth on the biomaterial and this was followed by confocal laser scanning microscopy after vital staining or immunocytochemical reactions, as well as by scanning electron microscopy. Macro- and microvascular ECs predominantly spread on BONITmatrix-collagen mesh-covered surfaces and fibres and maintained their typical morphology. As ECs in vivo must build up a functional vasculature, the seeded cells were further tested for proinflammatory expression markers and cytokine expression after lipopolysaccharide stimulation. Protein-coating studies revealed that BONITmatrix-collagen scaffolds needed human blood serum coating to successfully support the growth of ECs. All cells expressed endothelium-specific surface marker proteins such as PECAM-1, VE-cadherin and vWF. The in vitro data support recent in vivo studies and indicate that this calcium phosphate/SiO{sub 2}-xerogel composite could be a useful scaffold material for tissue engineering.

  15. Engineering Graphene Quantum Dots for Enhanced Ultraviolet and Visible Light p-Si Nanowire-Based Photodetector.

    Science.gov (United States)

    Mihalache, Iuliana; Radoi, Antonio; Pascu, Razvan; Romanitan, Cosmin; Vasile, Eugenia; Kusko, Mihaela

    2017-08-30

    In this work, a significant improvement of the classical silicon nanowire (SiNW)-based photodetector was achieved through the realization of core-shell structures using newly designed GQD(PEI)s via simple solution processing. The poly(ethyleneimine) (PEI)-assisted synthesis successfully tuned both optical and electrical properties of graphene quantum dots (GQDs) to fulfill the requirements for strong yellow photoluminescence emission along with large band gap formation and the introduction of electronic states inside the band gap. The fabrication of a GQD(PEI)-based device was followed by systematic structural and photoelectronic investigation. Thus, the GQD(PEI)/SiNW photodetector exhibited a large photocurrent to dark current ratio (Iph/Idark up to ∼0.9 × 10(2) under 4 V bias) and a remarkable improvement of the external quantum efficiency values that far exceed 100%. In this frame, GQD(PEI)s demonstrate the ability to arbitrate both charge-carrier photogeneration and transport inside a heterojunction, leading to simultaneous attendance of various mechanisms: (i) efficient suppression of the dark current governed by the type I alignment in energy levels, (ii) charge photomultiplication determined by the presence of the PEI-induced electron trap levels, and (iii) broadband ultraviolet-to-visible downconversion effects.

  16. Control of fast non linear systems - application to a turbo charged SI engine with variable valve timing; controle des systemes rapides non lineaires - application au moteur a allumage commande turbocompresse a distribution variable

    Energy Technology Data Exchange (ETDEWEB)

    Colin, G.

    2006-10-15

    Spark ignition engine control has become a major issue for the compliance with emissions legislation while ensuring driving comfort. Engine down-sizing is one of the promising ways to reduce fuel consumption and resulting CO{sub 2} emissions. Combining several existing technologies such as supercharging and variable valve actuation, down-sizing is a typical example of the problems encountered in Spark Ignited (SI) engine control: nonlinear systems with saturation of actuators; numerous major physical phenomena not measurable; limited computing time; control objectives (consumption, pollution, performance) often competing. A methodology of modelling and model-based control (internal model and predictive control) for these systems is also proposed and applied to the air path of the down-sized engine. Models, physicals and generics, are built to estimate in-cylinder air mass, residual burned gases mass and air scavenged mass from the intake to the exhaust. The complete and generic engine torque control architecture for the turbo-charged SI engine with variable cam-shaft timing was tested in simulation and experimentally (on engine and vehicle). These tests show that new possibilities are offered in order to decrease pollutant emissions and optimize engine efficiency. (author)

  17. Combustion strategies for a SI direct injection natural gas engine; Darstellung verschiedener Betriebsstrategien an einem Erdgasmotor mit innerer Gemischbildung

    Energy Technology Data Exchange (ETDEWEB)

    Bohatsch, S.; Hoffmann, B.; Ferrari, A.; Chiodi, M.; Berner, H.J.; Bargende, M.

    2006-07-01

    Natural gas as a fuel for internal combustion engines is a combustion technology showing great promise for the reduction of CO{sub 2} and particulate matter. To demonstrate the potential of natural gas direct injection some experimental investigations were carried out using a single-cylinder engine with lateral injector position. For this different injection valve nozzles, piston crown geometries as well as operating strategies were investigated. First experimental results accompanied by additional CFD-simulation show that it is possible to control the burn rate by injection induced turbulence. Furthermore the results show that a short mixture preparation distance between injection nozzle and spark plug is necessary because of the poor fuel penetration during the injection process which is typical for gaseous fuels. (orig.)

  18. Engineering polypyrrole nanotubes by 100 MeV Si9+ ion beam irradiation: enhancement of antioxidant activity.

    Science.gov (United States)

    Upadhyay, J; Kumar, A

    2013-12-01

    In this work, the effect of 100 MeV Si(9+) ion beam with four different fluences on antioxidant and structural properties of polypyrrole nanotubes has been investigated. Polypyrrole nanotubes have been synthesized by reactive self degrade template method. Fragmentation of the polypyrrole nanotubes at higher fluence is revealed from the high resolution transmission electron micrograph (HRTEM) and X-ray diffraction (XRD) results. The decrease in characteristics band of polypyrrole in Fourier transmission of infrared spectra (FTIR) spectra suggests the main chain scission of polypyrrole during irradiation. The free radical scavenging activity of pristine and irradiated samples are evaluated by using α, α-diphenyl-β-picrylhydrazyl (DPPH) assay. The decline of the UV-visible absorbance at 516 nm suggests the neutralization of DPPH free radicals through the reaction with polypyrrole. Significant increase in antioxidant activity of polypyrrole nanotubes is observed with increase in ion fluence. © 2013.

  19. 硅基微型同位素电池的电输出理论模型及仿真%Modeling and Simulation for Electrical Output of Si-based Isotope Microbattery

    Institute of Scientific and Technical Information of China (English)

    程再军; 周鹏

    2015-01-01

    通过辐射伏特效应,研究硅基P-N结微型同位素电池的电输出理论模型.根据该模型,用Matlab编写程序模拟尺寸为1 mm ×1 mm的硅基微型同位素电池在3. 7 ×107 Bq63 Ni放射源照射下的电输出,并用该模型仿真硅基微电池的短路电流Isc 、开路电压Voc 和最大输出功率Pmax 与掺杂浓度的关系.仿真结果表明,开路电压随着掺杂浓度的增加而增大,而短路电流则随着掺杂浓度的增大而减小.同时,获得了电池具有最大输出功率密度时的最优化掺杂浓度参数,最大输出功率的P区、 N区最优化掺杂浓度值各为1 ×1020 cm-3和1 ×1015 cm-3.%This paper studied a theoretical model of Si-based P-N junction isotope microbattery’s output by the Betavoltaic effect. According to the model, electrical output performance of a 1 mm × 1 mm Si-based isotope microbattery under the irradiation of a 3. 7 × 107 Bq 63Ni source was simulated using Matlab, and Isc, Voc, Pmax were also simulated using the model. The results showed that the open circuit was increasing with doping concentration, and the short circuit current was decreasing with doping concentration. The optimal doping concentrations of P and N area for maximum output power were 1 × 1020 cm-3 and 1 × 1015 cm-3 .

  20. Analysis of the piston ring/liner oil film development during warm-up for an SI-engine

    DEFF Research Database (Denmark)

    Frølund, Kent; Schramm, Jesper; Tian, T.;

    2001-01-01

    A one-dimensional ring-pack lubrication model developed at MIT is applied to simulate the oil film behavior during the warm-up period of a Kohler spark ignition engine. This is done by making assumptions for the evolution of the ail temperatures during warm-up and that the oil control ring during...... downstrokes is fully, flooded. The ring-pack lubrication model includes features such as three different lubrication regimes, i.e., pure hydro-dynamic lubrication, boundary lubrication and pure asperity contact, nonsteady wetting of both inlet and outlet of the piston ring, capability to use all ring face...

  1. Sr, C and O isotopes as markers of alkaline disturbances in the Toarcian argillites of the Tournemire experimental platform (France). Case of a 15-years old engineered analogue.

    Science.gov (United States)

    Techer, I.; Boulvais, P.; Bartier, D.; Tinseau, E.

    2009-04-01

    In France, the concept of a geological disposal of high-activity and long-period nuclear wastes requires the use of concrete and cement-bearing materials as building structures or as waste containment packages, in conjunction with clayey barriers (e.g., compacted bentonite as an engineered barrier and/or argillite-type rocks as a geological barrier). Hydrolysis of cementitious phases is however known to produce hyper-alkaline pore fluids with pH ranging from 10 to 13.5 that will be in disequilibrium with the geological setting environment (argillite pore-water pH around 8). The disturbance of clayey rocks in contact with such materials is thus an important task in safety assessment studies of deep geological storage. This concerns the knowledge of mineral / solution paths but also the spatial extent of the alkaline plume into the clayey material. Experimental and modelling approaches were performed this last decade to answer these questions. In addition to these approaches, natural or engineered contexts in which a clayey formation has been in contact with cementitious materials can be considered as analogues of a deep geological storage for the study of argillite /cement interaction. Such contexts can be found in the IRSN Tournemire experimental platform in Aveyron (France). This platform is based on a tunnel, excavated between 1882 and 1886 through Domerian marls and Toarcian argillites, which is dedicated since 1990 to multidisciplinary research programs. In the frameworks of these programs, exploration boreholes were realized from the basement of the tunnel in the 1990 years. The boreholes were then filled with concrete and cement that are presently in contact with the Toarcian argillites for 15-20 years. One of this borehole - DM borehole - was overcored in 2005 in order to collect the Toarcian argillites in contact with the cement and the concrete. Mineralogical, petrographic and microstructural analyses have argued for a clear disturbance of the Toarcian

  2. Driving cycle simulation of a vehicle motored by a SI engine fueled with H sub 2 -enriched gasoline

    Energy Technology Data Exchange (ETDEWEB)

    Hacohen, J. (Exeter Univ. (GB). School of Engineering); Pinhasi, G.; Puterman, Y.; Sher, E. (Ben-Gurion Univ. of the Negev, Beersheba (IL). Dept. of Mechanical Engineering)

    1991-01-01

    In the present study, the effect of the amount of hydrogen supplement to a gasoline engine is theoretically investigated in terms of the vehicle performance running over a standard driving cycle. A rigorous mathematical model which considers the vehicle dynamics, transmission losses, the gas exchange and combustion processes inside the cylinder, as well as the chemical kinetics of the formation of the relevant products has been developed. The model was employed to predict the fuel consumption, engine power and the emission level of CO, HC, CO{sub 2} and NO{sub x} over the European ECE-15 and Japanese 10-mode driving cycles. Based on a previous work of the present authors, the hydrogen was considered to be produced by an on-board on-line auxiliary generator, which consumes a mixture of gasoline and water. It has been shown that a significant reduction in the total fuel consumption, in the order of 15 to 20% and an associated reduction in HC, CO and NO{sub x} emission levels, is achieved with only 6% of hydrogen enrichment (hydrogen to fuel mass ratio). (Author).

  3. Defect-engineered optical bandgap in self-assembled TiO{sub 2} nanorods on Si pyramids

    Energy Technology Data Exchange (ETDEWEB)

    Saini, C. P.; Barman, A.; Kanjilal, A., E-mail: aloke.kanjilal@snu.edu.in [Department of Physics, School of Natural Sciences, Shiv Nadar University, NH-91, Tehsil Dadri, Gautam Buddha Nagar, Uttar Pradesh 201 314 (India); Satpati, B.; Bhattacharyya, S. R. [Surface Physics and Material Science Division, Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Kolkata 700 064 (India); Kanjilal, D. [Inter-University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110 067 (India)

    2016-01-04

    Transformation of self-assembled crystalline TiO{sub 2} nanorods to amorphous layer, and the corresponding impact on optical-bandgap (E{sub g}) on Si pyramids are investigated by irradiating with 50 keV Ar{sup +}-ions. Initially, E{sub g} is found to be reduced from 3.23 to 2.94 eV up to a fluence of 1 × 10{sup 16} ions/cm{sup 2}, and discussed in terms of the rise in oxygen vacancies (V{sub O}). However, a sudden increase in E{sub g} to 3.38 eV is detected at a fluence of 1 × 10{sup 17} ions/cm{sup 2} through evolution of voids by over-saturating V{sub O}, manifesting the appearance of degenerate states by shifting the Fermi level above the conduction band minimum via Burstein-Moss effect.

  4. Mid-infrared metamaterial based on perforated SiC membrane: engineering optical response using surface phonon polaritons

    Energy Technology Data Exchange (ETDEWEB)

    Korobkin, D.; Urzhumov, Y.A.; Neuner, B. III; Shvets, G. [The University of Texas at Austin, Department of Physics, Austin, TX (United States); Zorman, C. [Case Western Reserve University, Department of Electrical Engineering, Cleveland, OH (United States); Zhang, Z.; Mayergoyz, I.D. [University of Maryland, Department of Electrical and Computer Engineering, College Park, MD (United States)

    2007-09-15

    We theoretically and experimentally study electromagnetic properties of a novel mid-infrared metamaterial: optically thin silicon carbide (SiC) membrane perforated by an array of sub-wavelength holes. Giant absorption and transmission is found using Fourier transformed infrared (FTIR) microscopy and explained by introducing a frequency-dependent effective permittivity {epsilon}{sub eff}({omega}) of the perforated film. The value of {epsilon}{sub eff}({omega}) is determined by the excitation of two distinct types of hole resonances: delocalized slow surface polaritons (SSPs) whose frequencies are largely determined by the array period, and a localized surface polariton (LSP) corresponding to the resonance of an isolated hole. Only SSPs are shown to modify {epsilon}{sub eff}({omega}) strongly enough to cause giant transmission and absorption. Because of the sub-wavelength period of the hole array, anomalous optical properties can be directly traced to surface polaritons, and their interpretation is not obscured by diffractive effects. Giant absorbance of this metamaterial can be utilized in designing highly efficient thermal radiation sources. (orig.)

  5. Molecular Chemistry and Engineering of Boron-Modified Polyorganosilazanes as New Processable and Functional SiBCN Precursors.

    Science.gov (United States)

    Viard, Antoine; Fonblanc, Diane; Schmidt, Marion; Lale, Abhijeet; Salameh, Chrystelle; Soleilhavoup, Anne; Wynn, Mélanie; Champagne, Philippe; Cerneaux, Sophie; Babonneau, Florence; Chollon, Georges; Rossignol, Fabrice; Gervais, Christel; Bernard, Samuel

    2017-07-06

    A series of boron-modified polyorganosilazanes was synthesized from a poly(vinylmethyl-co-methyl)silazane and controlled amounts of borane dimethyl sulfide. The role of the chemistry behind their synthesis has been studied in detail by using solid-state NMR spectroscopy, FTIR spectroscopy, and elemental analysis. The intimate relationship between the chemistry and the processability of these polymers is discussed. Polymers with low boron contents displayed appropriate requirements for facile processing in solution, such as impregnation of host carbon materials, which resulted in the design of mesoporous monoliths with a high specific surface area after pyrolysis. Polymers with high boron content are more appropriate for solid-state processing to design mechanically robust monolith-type macroporous and dense structures after pyrolysis. Boron acts as a crosslinking element, which offers the possibility to extend the processability of polyorganosilazanes and suppress the distillation of oligomeric fragments in the low-temperature region of their thermal decomposition (i.e., pyrolysis) at 1000 °C under nitrogen. Polymers with controlled and high ceramic yields were generated. We provide a comprehensive mechanistic study of the two-step thermal decomposition based on a combination of thermogravimetric experiments coupled with elemental analysis, solid-state NMR spectroscopy, and FTIR spectroscopy. Selected characterization tools allowed the investigation of specific properties of the monolith-type SiBCN materials. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Early flame development image comparison of low calorific value syngas and CNG in DI SI gas engine

    Science.gov (United States)

    >Ftwi Yohaness Hagos,

    2013-06-01

    The early flame development stage of syngas and CNG are analysed and compared from the flame images taken over 20° CA from the start of ignition. An imitated syngas with a composition of 19.2% H2, 29.6% CO, 5.3% CH4 and balance with nitrogen and carbon dioxide, which resembles the typical product of wood biomass gasification, was used in the study. A CCD camera triggered externally through the signals from the camshaft and crank angle sensors was used in capturing of the images. The engine was accessed through an endoscope access and a self-illumination inside the chamber. The results of the image analysis are further compared with the mass fraction burn curve of both syngas and CNG analysed from the pressure data. The analysis result of the flame image of syngas validates the double rapid burning stage of the mass fraction burn of syngas analysed from in-cylinder pressure data.

  7. Isotopes in Condensed Matter

    CERN Document Server

    G Plekhanov, Vladimir

    2013-01-01

    This book provides a concise introduction to the newly created sub-discipline of solid state physics isotopetronics. The role of isotopes in materials and their properties are describe  in this book. The problem of the enigma of the atomic mass in microphysics is briefly discussed.  The range of the applications of isotopes is wide: from biochemical process in living organisms to modern technical applications in quantum information. Isotopetronics promises to improve nanoelectronic and optoelectronic devices. With numerous illustrations this book is useful to researchers, engineers and graduate students.

  8. Development of SI-traceable C-peptide certified reference material NMIJ CRM 6901-a using isotope-dilution mass spectrometry-based amino acid analyses.

    Science.gov (United States)

    Kinumi, Tomoya; Goto, Mari; Eyama, Sakae; Kato, Megumi; Kasama, Takeshi; Takatsu, Akiko

    2012-07-01

    A certified reference material (CRM) is a higher-order calibration material used to enable a traceable analysis. This paper describes the development of a C-peptide CRM (NMIJ CRM 6901-a) by the National Metrology Institute of Japan using two independent methods for amino acid analysis based on isotope-dilution mass spectrometry. C-peptide is a 31-mer peptide that is utilized for the evaluation of β-cell function in the pancreas in clinical testing. This CRM is a lyophilized synthetic peptide having the human C-peptide sequence, and contains deamidated and pyroglutamylated forms of C-peptide. By adding water (1.00 ± 0.01) g into the vial containing the CRM, the C-peptide solution in 10 mM phosphate buffer saline (pH 6.6) is reconstituted. We assigned two certified values that represent the concentrations of total C-peptide (mixture of C-peptide, deamidated C-peptide, and pyroglutamylated C-peptide) and C-peptide. The certified concentration of total C-peptide was determined by two amino acid analyses using pre-column derivatization liquid chromatography-mass spectrometry and hydrophilic chromatography-mass spectrometry following acid hydrolysis. The certified concentration of C-peptide was determined by multiplying the concentration of total C-peptide by the ratio of the relative area of C-peptide to that of the total C-peptide measured by liquid chromatography. The certified value of C-peptide (80.7 ± 5.0) mg/L represents the concentration of the specific entity of C-peptide; on the other hand, the certified value of total C-peptide, (81.7 ± 5.1) mg/L can be used for analyses that does not differentiate deamidated and pyroglutamylated C-peptide from C-peptide itself, such as amino acid analyses and immunochemical assays.

  9. Absolute Calibration of Si iRMs used for Measurements of Si Paleo-nutrient proxies

    Science.gov (United States)

    Vocke, R. D., Jr.; Rabb, S. A.

    2016-12-01

    Silicon isotope variations (reported as δ30Si and δ29Si, relative to NBS28) in silicic acid dissolved in ocean waters, in biogenic silica and in diatoms are extremely informative paleo-nutrient proxies. The resolution and comparability of such measurements depend on the quality of the isotopic Reference Materials (iRMs) defining the delta scale. We report new absolute Si isotopic measurements on the iRMs NBS28 (RM 8546 - Silica Sand), Diatomite, and Big Batch using the Avogadro measurement approach and comparing them with prior assessments of these iRMs. The Avogadro Si measurement technique was developed by the German Physikalish-Technische Bundesanstalt (PTB) to provide a precise and highly accurate method to measure absolute isotopic ratios in highly enriched 28Si (99.996%) material. These measurements are part of an international effort to redefine the kg and mole based on the Planck constant h and the Avogadro constant NA, respectively (Vocke et al., 2014 Metrologia 51, 361, Azuma et al., 2015 Metrologia 52 360). This approach produces absolute Si isotope ratio data with lower levels of uncertainty when compared to the traditional "Atomic Weights" method of absolute isotope ratio measurement calibration. This is illustrated in Fig. 1 where absolute Si isotopic measurements on SRM 990, separated by 40+ years of advances in instrumentation, are compared. The availability of this new technique does not say that absolute Si isotopic ratios are or ever will be better for normal Si isotopic measurements when seeking isotopic variations in nature, because they are not. However, by determining the absolute isotopic ratios of all the Si iRM scale artifacts, such iRMs become traceable to the metric system (SI); thereby automatically conferring on all the artifact-based δ30Si and δ29Si measurements traceability to the base SI unit, the mole. Such traceability should help reduce the potential of bias between different iRMs and facilitate the replacement of delta

  10. Mass Spectrometric Investigation of Silicon Extremely Enriched in (28)Si: From (28)SiF4 (Gas Phase IRMS) to (28)Si Crystals (MC-ICP-MS).

    Science.gov (United States)

    Pramann, Axel; Rienitz, Olaf

    2016-06-01

    A new generation of silicon crystals even further enriched in (28)Si (x((28)Si) > 0.999 98 mol/mol), recently produced by companies and institutes in Russia within the framework of a project initiated by PTB, were investigated with respect to their isotopic composition and molar mass M(Si). A modified isotope dilution mass spectrometric (IDMS) method treating the silicon as the matrix containing a so-called virtual element (VE) existing of the isotopes (29)Si and (30)Si solely and high resolution multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) were applied in combination. This method succeeds also when examining the new materials holding merely trace amounts of (29)Si (x((29)Si) ≈ 5 × 10(-6) mol/mol) and (30)Si (x((30)Si) ≈ 7 × 10(-7) mol/mol) extremely difficult to detect with lowest uncertainty. However, there is a need for validating the enrichment in (28)Si already in the precursor material of the final crystals, silicon tetrafluoride (SiF4) gas prior to crystal production. For that purpose, the isotopic composition of selected SiF4 samples was determined using a multicollector magnetic sector field gas-phase isotope ratio mass spectrometer. Contaminations of SiF4 by natural silicon due to storing and during the isotope ratio mass spectrometry (IRMS) measurements were observed and quantified. The respective MC-ICP-MS measurements of the corresponding crystal samples show-in contrast-several advantages compared to gas phase IRMS. M(Si) of the new crystals were determined to some extent with uncertainties urel(M) Si)) on the degree of enrichment in (28)Si. This leads to a reduction of urel(M(Si)) during the past decade by almost 3 orders of magnitude and thus further reduces the uncertainty of the Avogadro constant NA which is one of the preconditions for the redefinition of the SI unit kilogram.

  11. Isotopic heterogeneity in synthetic and natural silicon carbide

    OpenAIRE

    Shiryaev, A. A.; Michael Wiedenbeck; Reutsky, V.; Polyakov, V.B.; Mel'nik, N. N.; Lebedev, A. A.; Yakimova, R.

    2008-01-01

    The distribution of both carbon and silicon isotopes in synthetic sublimation growth SiC wafers and in natural SiC grains was studied using secondary ion mass-spectrometry (SIMS). Significant variations in both isotopic ratios were observed which were broadly correlated with the crystalline perfection as documented by Raman microspectroscopy. Domains consisting of 15R (or with its admixture) are, on average, enriched in 12C isotope relative to 6H domains, and they also show larger scatter in ...

  12. Robust Adaptive PID Controller for a Class of Uncertain Nonlinear Systems: An Application for Speed Tracking Control of an SI Engine

    Directory of Open Access Journals (Sweden)

    Tossaporn Chamsai

    2015-01-01

    Full Text Available The sliding mode control (SMC technique with a first-order low-pass filter (LPF is incorporated with a new adaptive PID controller. It is proposed for tracking control of an uncertain nonlinear system. In the proposed control scheme, the adaptation law is able to update the PID controller online during the control process within a short period. The chattering phenomenon of the SMC can be alleviated by incorporation of a first-order LPF, while the robustness of the control system is similar to that of the sliding mode. In the closed-loop control analysis, the convergence condition in the reaching phase and the existence condition of the sliding mode were analyzed. The stability of the closed-loop control is guaranteed in the sense of Lyapunov’s direct method. The simulations and experimental applications of a speed tracking control of a spark ignition (SI engine via electronic throttle valve control architecture are provided to verify the effectiveness and the feasibility of the proposed control scheme.

  13. Oxygen Isotopes in Meteorites

    Science.gov (United States)

    Clayton, R. N.

    2003-12-01

    samples of oxygen-rich mineral grains that have formed in stellar atmospheres and have recorded the nucleosynthetic processes in individual stars. Similar samples are already available for carbon-rich grains, in the form of SiC and graphite, primarily from asymptotic giant branch (AGB) stars and supernovae (Anders and Zinner, 1993). These presolar grains have provided a wealth of detailed information concerning nucleosynthesis of carbon, nitrogen, silicon, calcium, titanium, and heavier elements (see Chapter 1.02). It is thought that such carbon-rich minerals should form only in environments with C/O>1, as in the late stages of AGB evolution, or in carbon-rich layers of supernovae. By analogy, one would expect to form oxide and silicate minerals in environments with C/O<1, as is common for most stars. Indeed there is evidence in infrared spectra for the formation of Al2O3 (corundum) and silicates, such as olivine (Speck et al., 2000) around evolved oxygen-rich stars. However, searches for such grains in meteorites have yielded only a very small population of corundum grains, a few grains of spinel and hibonite, and no silicates ( Nittler et al., 1997). The observed oxygen isotopic compositions of presolar corundum grains show clear evidence of nuclear processes in red-giant stars, and have had significant impact on the theory of these stars ( Boothroyd and Sackmann, 1999).There are several possible reasons for the failure to recognize and analyze large populations of oxygen-rich presolar grains:(i) they may not exist: oxygen ejected in supernova explosions may not condense into mineral grains on the short timescale available;(ii) they may be smaller in size than can be detected by applicable techniques (˜0.1 μm); and(iii) they may be destroyed in the laboratory procedures used to isolate other types of presolar grains.

  14. Effects of Port Shape on Steady Flow Characteristics in an SI Engine with Semi-Wedge Combustion Chamber (2) - Velocity Distribution (2)

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Inkyoung; Ohm, Inyong [Seoul Nat’l Univ. of Science and Technology, Seoul (Korea, Republic of)

    2017-02-15

    This study is the second investigation on the steady flow characteristics of an SI engine with a semi-edge combustion chamber as a function of the port shape with varying evaluation positions. For this purpose, the planar velocity profiles were measured from 1.75B, 1.75 times of bore position apart from the bottom of head, to 6.00B positions using particle – image velocimetry. The flow patterns were examined with both a straight and a helical port. The velocity profiles, streamlines, and centers of swirl were almost the same at the same valve lift regardless of the measuring position, which is quite different from the case of the pent-roof combustion chamber. All the eccentricity values of the straight port were out of distortion criterion 0.15 through the lifts and the position. However, the values of the helical port exceeded the distortion criterion by up to 4 mm lift, but decreased rapidly above the 3.00B position and the 5 mm lift. There always existed a relative offset effect in the evaluation of the swirl coefficient using the PIV method due to the difference of the ideal impulse swirl meter velocity profile assumption, except for the cylinder-center-base estimation that was below 4 mm of the straight port. Finally, it was concluded that taking the center as an evaluation basis and the assumption about the axial velocity profile did not have any qualitative effect on swirl evaluation, but affected the value owing to the detailed profile.

  15. Engineering of contact resistance between transparent single-walled carbon nanotube films and a-Si:H single junction solar cells by gold nanodots.

    Science.gov (United States)

    Kim, Jeehwan; Hong, Augustin J; Chandra, Bhupesh; Tulevski, George S; Sadana, Devendra K

    2012-04-10

    The viability of single-walled carbon nanotubes (SWCNTs) as a transparent conducting electrode on a-Si:H based single junction solar cells was explored. A Schottky barrier formed at a SWCNT/a-Si:H interface was removed by introducing high work function gold nanodots at the SWCNT/a-Si:H interface. This allows comparable device performance from SWCNT-electrode-based a-Si:H solar cells to that obtained by using conventional transparent conducting oxides. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Molecular hydrogen (H2) combustion emissions and their isotope (D/H) signatures from domestic heaters, diesel vehicle engines, waste incinerator plants, and biomass burning

    NARCIS (Netherlands)

    Vollmer, M.K.; Walter, S.; Mohn, J.; Steinbacher, M.; Bond, S.W.; Röckmann, T.; Reimann, S.

    2012-01-01

    Molecular hydrogen (H2), its stable isotope signature ( D), and the key combustion parameters carbon monoxide (CO), carbon dioxide (CO2), and methane (CH4) were measured from various combustion processes. H2 in the exhaust of gas and oil-fired heaters and of waste incinerator plants was generally de

  17. Molecular hydrogen (H2) combustion emissions and their isotope (D/H) signatures from domestic heaters, diesel vehicle engines, waste incinerator plants, and biomass burning

    NARCIS (Netherlands)

    Vollmer, M.K.; Walter, S.; Mohn, J.; Steinbacher, M.; Bond, S.W.; Röckmann, T.; Reimann, S.

    2012-01-01

    Molecular hydrogen (H2), its stable isotope signature ( D), and the key combustion parameters carbon monoxide (CO), carbon dioxide (CO2), and methane (CH4) were measured from various combustion processes. H2 in the exhaust of gas and oil-fired heaters and of waste incinerator plants was generally

  18. Leatherback Isotopes

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — SWFSC is currently working on a project identifying global marine isotopes using leatherback turtles (Dermochelys coriacea) as the indicator species. We currently...

  19. Isotopic chirality

    Energy Technology Data Exchange (ETDEWEB)

    Floss, H.G. [Univ. of Washington, Seattle, WA (United States)

    1994-12-01

    This paper deals with compounds that are chiral-at least in part, due to isotope substitution-and their use in tracing the steric course of enzyme reaction in vitro and in vivo. There are other applications of isotopically chiral compounds (for example, in analyzing the steric course of nonenzymatic reactions and in probing the conformation of biomolecules) that are important but they will not be discussed in this context.

  20. Isotopic Paleoclimatology

    Science.gov (United States)

    Bowen, R.

    Paleotemperature scales were calculated by H. C. Urey and others in the 1950s to assess past temperatures, and later work using the stable isotopes of oxygen, hydrogen, and carbon employed standards such as Peedee belemnite (PDB) and Standard Mean Ocean Water (SMOW). Subsequently, subjects as diverse as ice volume and paleotemperatures, oceanic ice and sediment cores, Pleistocene/Holocene climatic changes, and isotope chronostratigraphy extending back to the Precambrian were investigated.

  1. SI/HCCI双模发动机的研究现状和发展趋势%The Development and Trend of SI/HCCI Gasoline Dual-Engine

    Institute of Scientific and Technical Information of China (English)

    王海军

    2015-01-01

    SI/HCCI双模发动机在起动和高负荷工况下采用SI模式,在中、低负荷下采用HCCI模式,从而将HCCI发动机扩展到了全工况负荷.本文介绍了SI/HCCI切换实现的方式,并从燃烧、排放、油耗、切换瞬态过程等方面介绍了SI/HCCI双模发动机的研究现状,并指出了其产业化面临的问题及以后的发展趋势.

  2. Resolving the stellar sources of isotopically rare presolar silicate grains through Mg and Fe isotopic analyses

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ann N.; Messenger, Scott, E-mail: lan-anh.n.nguyen@nasa.gov [Robert M. Walker Laboratory for Space Science, Astromaterials Research and Exploration Science Directorate, NASA Johnson Space Center, Houston, TX 77058 (United States)

    2014-04-01

    We conducted multi-element isotopic analyses of 11 presolar silicate grains from the Acfer 094 meteorite having unusual O isotopic compositions. Eight grains are {sup 18}O-rich, one is {sup 16}O-rich, and two are extremely {sup 17}O-rich. We constrained the grains' stellar sources by measuring their Si and Mg isotopic ratios, and also the {sup 54}Fe/{sup 56}Fe and {sup 57}Fe/{sup 56}Fe ratios for five grains. The Mg and Fe isotopic measurements were conducted after surrounding matrix grains were removed for more accurate ratios. Most of the {sup 18}O-rich silicates had anomalous Mg isotopic ratios, and their combined isotopic constraints are consistent with origins in low-mass Type II supernovae (SNe II) rather than high-metallicity stars. The isotopic ratios of the {sup 16}O-rich silicate are also consistent with an SN origin. Mixing small amounts of interior stellar material with the stellar envelope replicated all measured isotopic ratios except for {sup 29}Si/{sup 28}Si and {sup 54}Fe/{sup 56}Fe in some grains. The {sup 29}Si/{sup 28}Si ratios of all SN-derived grains are matched by doubling the {sup 29}Si yield in the Ne- and Si-burning zones. The {sup 54}Fe/{sup 56}Fe ratios of the grains imply elemental fractionation in the Si/S zone, or introduction of isotopically solar Fe by secondary processing. The two highly {sup 17}O-rich silicates exhibited significant {sup 25}Mg and/or {sup 26}Mg enrichments and their isotopic ratios are best explained by strong dilution of 1.15 M {sub ☉} CO nova matter. We estimate that ∼12% and 1% of presolar silicates have SN and nova origins, respectively, similar to presolar SiC and oxides. This implies that asymptotic giant branch stars are the dominant dust producers in the galaxy.

  3. Compelling Research Opportunities using Isotopes

    Energy Technology Data Exchange (ETDEWEB)

    None

    2009-04-23

    Isotopes are vital to the science and technology base of the US economy. Isotopes, both stable and radioactive, are essential tools in the growing science, technology, engineering, and health enterprises of the 21st century. The scientific discoveries and associated advances made as a result of the availability of isotopes today span widely from medicine to biology, physics, chemistry, and a broad range of applications in environmental and material sciences. Isotope issues have become crucial aspects of homeland security. Isotopes are utilized in new resource development, in energy from bio-fuels, petrochemical and nuclear fuels, in drug discovery, health care therapies and diagnostics, in nutrition, in agriculture, and in many other areas. The development and production of isotope products unavailable or difficult to get commercially have been most recently the responsibility of the Department of Energy's Nuclear Energy program. The President's FY09 Budget request proposed the transfer of the Isotope Production program to the Department of Energy's Office of Science in Nuclear Physics and to rename it the National Isotope Production and Application program (NIPA). The transfer has now taken place with the signing of the 2009 appropriations bill. In preparation for this, the Nuclear Science Advisory Committee (NSAC) was requested to establish a standing subcommittee, the NSAC Isotope Subcommittee (NSACI), to advise the DOE Office of Nuclear Physics. The request came in the form of two charges: one, on setting research priorities in the short term for the most compelling opportunities from the vast array of disciplines that develop and use isotopes and two, on making a long term strategic plan for the NIPA program. This is the final report to address charge 1. NSACI membership is comprised of experts from the diverse research communities, industry, production, and homeland security. NSACI discussed research opportunities divided into three areas: (1

  4. Planetary and meteoritic Mg/Si and d30Si variations inherited from solar nebula chemistry

    CERN Document Server

    Dauphas, Nicolas; Burkhardt, Christoph; Kobayashi, Hiroshi; Kurosawa, Kosuke

    2015-01-01

    The bulk chemical compositions of planets are uncertain, even for major elements such as Mg and Si. This is due to the fact that the samples available for study all originate from relatively shallow depths. Comparison of the stable isotope compositions of planets and meteorites can help overcome this limitation. Specifically, the non-chondritic Si isotope composition of the Earth's mantle was interpreted to reflect the presence of Si in the core, which can also explain its low density relative to pure Fe-Ni alloy. However, we have found that angrite meteorites display a heavy Si isotope composition similar to the lunar and terrestrial mantles. Because core formation in the angrite parent-body (APB) occurred under oxidizing conditions at relatively low pressure and temperature, significant incorporation of Si in the core is ruled out as an explanation for this heavy Si isotope signature. Instead, we show that equilibrium isotopic fractionation between gaseous SiO and solid forsterite at 1370 K in the solar neb...

  5. (30)Si mole fraction of a silicon material highly enriched in (28)Si determined by instrumental neutron activation analysis.

    Science.gov (United States)

    D'Agostino, Giancarlo; Di Luzio, Marco; Mana, Giovanni; Oddone, Massimo; Pramann, Axel; Prata, Michele

    2015-06-01

    The latest determination of the Avogadro constant, carried out by counting the atoms in a pure silicon crystal highly enriched in (28)Si, reached the target 2 × 10(-8) relative uncertainty required for the redefinition of the kilogram based on the Planck constant. The knowledge of the isotopic composition of the enriched silicon material is central; it is measured by isotope dilution mass spectrometry. In this work, an independent estimate of the (30)Si mole fraction was obtained by applying a relative measurement protocol based on Instrumental Neutron Activation Analysis. The amount of (30)Si isotope was determined by counting the 1266.1 keV γ-photons emitted during the radioactive decay of the radioisotope (31)Si produced via the neutron capture reaction (30)Si(n,γ)(31)Si. The x((30)Si) = 1.043(19) × 10(-6) mol mol(-1) is consistent with the value currently adopted by the International Avogadro Coordination.

  6. 30Si Mole Fraction of a Silicon Material Highly Enriched in 28Si Determined by Instrumental Neutron Activation Analysis

    CERN Document Server

    D'Agostino, Giancarlo; Mana, Giovanni; Oddone, Massimo; Pramann, Axel; Prata, Michele

    2016-01-01

    The latest determination of the Avogadro constant, carried out by counting the atoms in a pure silicon crystal highly enriched in 28Si, reached the target 2x10-8 relative uncertainty required for the redefinition of the kilogram based on the Planck constant. The knowledge of the isotopic composition of the enriched silicon material is central; it is measured by isotope dilution mass spectrometry. In this work, an independent estimate of the 30Si mole fraction was obtained by applying a relative measurement protocol based on Instrumental Neutron Activation Analysis. The amount of 30Si isotope was determined by counting the 1266.1 keV gamma-photons emitted during the radioactive decay of the radioisotope 31Si produced via the neutron capture reaction 30Si(n,gamma)31Si. The x(30Si) = 1.043(19)x10-6 mol mol-1 is consistent with the value currently adopted by the International Avogadro Coordination.

  7. Engineering three-dimensionally electrodeposited Si-on-Ni inverse opal structure for high volumetric capacity Li-ion microbattery anode.

    Science.gov (United States)

    Liu, Hao; Cho, Hyung-Man; Meng, Ying Shirley; Li, Quan

    2014-06-25

    Aiming at improving the volumetric capacity of nanostructured Li-ion battery anode, an electrodeposited Si-on-Ni inverse opal structure has been proposed in the present work. This type of electrode provides three-dimensional bi-continuous pathways for ion/electron transport and high surface area-to-volume ratios, and thus exhibits lower interfacial resistance, but higher effective Li ions diffusion coefficients, when compared to the Si-on-Ni nanocable array electrode of the same active material mass. As a result, improved volumetric capacities and rate capabilities have been demonstrated in the Si-on-Ni inverse opal anode. We also show that optimization of the volumetric capacities and the rate performance of the inverse opal electrode can be realized by manipulating the pore size of the Ni scaffold and the thickness of the Si deposit.

  8. C/SiC复合材料推力室应用研究%Applied research of rocket engine thrusters made of ceramic matrix composite

    Institute of Scientific and Technical Information of China (English)

    刘志泉; 马武军

    2011-01-01

    C/SiC复合材料密度低、耐高温、抗氧化、抗烧蚀,并且具有非常好的高温力学性能,是制备高性能液体火箭发动机推力室的理想材料.本文从C/SiC复合材料燃烧室结构计算、无损探伤及C/SiC与金属连接等方面,论述了上海空间研究所在C/SiC复合材料应用于液体火箭发动机推力室方面的基础研究及应用进展.

  9. Silicon isotope study of thermal springs in Jiaodong Region,Shandong Province

    Institute of Scientific and Technical Information of China (English)

    徐跃通; 李红梅; 冯海霞; 周晨; 吴元芳; 张邦花

    2001-01-01

    Based on δ30Si and δ32Si isotope geochemistry, the origin and evolutionary mechanism of thermal springs in Jiaodong region are studied. The mean value of δ30Si of dissolved silica of thermal spring water in Jiaodong is 0.1‰. Thermal spring water ages using δ32Si dating method range from 387a to 965a.

  10. Morphology and Curie temperature engineering in crystalline La{sub 0.7}Sr{sub 0.3}MnO{sub 3} films on Si by pulsed laser deposition

    Energy Technology Data Exchange (ETDEWEB)

    Nori, Rajashree, E-mail: rajsre@ee.iitb.ac.in; Ganguly, U.; Ravi Chandra Raju, N.; Pinto, R.; Ramgopal Rao, V. [Centre of Excellence in Nanoelectronics, Department of Electrical Engineering, Indian Institute of Technology-Bombay (IIT-B), Mumbai 400076 (India); Kale, S. N. [Department of Applied Physics, Defence Institute of Advanced Technology (DIAT), Pune 411025 (India); Sutar, D. S. [Central Surface Analytical Facility, Indian Institute of Technology-Bombay (IIT-B), Mumbai 400076 (India)

    2014-01-21

    Of all the colossal magnetoresistant manganites, La{sub 0.7}Sr{sub 0.3}MnO{sub 3} (LSMO) exhibits magnetic and electronic state transitions above room temperature, and therefore holds immense technological potential in spintronic devices and hybrid heterojunctions. As the first step towards this goal, it needs to be integrated with silicon via a well-defined process that provides morphology and phase control, along with reproducibility. This work demonstrates the development of pulsed laser deposition (PLD) process parameter regimes for dense and columnar morphology LSMO films directly on Si. These regimes are postulated on the foundations of a pressure-distance scaling law and their limits are defined post experimental validation. The laser spot size is seen to play an important role in tandem with the pressure-distance scaling law to provide morphology control during LSMO deposition on lattice-mismatched Si substrate. Additionally, phase stability of the deposited films in these regimes is evaluated through magnetometry measurements and the Curie temperatures obtained are 349 K (for dense morphology) and 355 K (for columnar morphology)—the highest reported for LSMO films on Si so far. X-ray diffraction studies on phase evolution with variation in laser energy density and substrate temperature reveals the emergence of texture. Quantitative limits for all the key PLD process parameters are demonstrated in order enable morphological and structural engineering of LSMO films deposited directly on Si. These results are expected to boost the realization of top-down and bottom-up LSMO device architectures on the Si platform for a variety of applications.

  11. Sputter-deposited metallic and ceramic coatings for heat engines. Work performed from October 1980 to September 1983. [CoCrAlY; ZrO/sub 2/; Al/sub 2/O/sub 3/; Ni-SiC; quartz-SiC

    Energy Technology Data Exchange (ETDEWEB)

    Prater, J.T.; Moss, R.W.

    1984-04-01

    Progress in the development of metallic and ceramic coatings with improved high-temperature corrosion and erosion/wear resistance is reported. The objective was to develop coatings that would insure that future heat engines, notably gas turbines and diesels, would be able to operate efficiently on degraded fuel supplies. The majority of coatings investigated were prepared by sputter deposition. Research on sputter-deposited CoCrAlY coatings was directed at improving their low-temperature, hot corrosion resistance by introducing composition gradients and adding platinum. Studies on sputter-deposited ZrO/sub 2/ and Al/sub 2/O/sub 3/ coatings were conducted to improve the thermal cycling resistance of ceramic deposits on metal substrates by using combinations of graded transition layers, columnar ceramic structures, and dense sealing layers. Preliminary results on plasma-sprayed Ni-SiC and quartz-SiC coatings that showed good wear and oxidation resistance are also reported.

  12. The engineering sizing of the packed desorption column of hydrogen isotopes from Pb–17Li eutectic alloy. A rate based model using experimental mass transfer coefficients from a Melodie loop

    Energy Technology Data Exchange (ETDEWEB)

    Linek, V., E-mail: linekv@vscht.cz [Prague Institute of Chemical Technology, Department of Chemical Engineering, CZ-166 28 Prague 6 (Czech Republic); Košek, L. [Research Centre Řež, CZ-250 68 Husinec-Řež (Czech Republic); Moucha, T.; Rejl, F.J.; Kordač, M.; Valenz, L.; Opletal, M. [Prague Institute of Chemical Technology, Department of Chemical Engineering, CZ-166 28 Prague 6 (Czech Republic)

    2014-11-15

    Highlights: • The model of hydrogen isotopes desorption from lead lithium alloy in packed column is presented. • Mass transfer coefficient k{sub L}a are evaluated from Alpy's Melodie loop experiments. • Packing height and efficiency of packed columns in DEMO plant for DCLL and HCLL are evaluated. • Effects of liquid phase axial dispersion, surface tension and wettability of packing are evaluated. • Effect of flow rate of the purge gas on packing height and desorption efficiency is evaluated. - Abstract: The model of the desorption of hydrogen isotopes from lead lithium alloy in a packed column is derived from the first principles using the plug flow in the liquid phase either the plug flow or ideal mixing in the gas phases. Sievert's law of non-linear equilibrium is followed. The volumetric mass transfer coefficient k{sub L}a and its dependence on the liquid metal flow rate are evaluated on the basis of the Melodie loop experiments. The presented model is used for evaluation of the minimum flow rate of the purge gas for which the concentration of the isotope in the gas leaving the column is at its highest, while the driving force of the interfacial transport of the isotope is still not reduced and the tritium desorption efficiency is therefore retained. The potential effect of the axial dispersion in the gas and liquid phase is evaluated. Highlighted are the issues of the optimum packing geometric surface area, above which the efficiency starts to decrease, and of the role of the surface tension and the contact angle with regard to the wettability of the packing. On the basis of the findings related to these factors, the Mellapak 500 Y and Mellapak packings with flat surfaces are recommended for the tests aiming to intensify the tritium desorption efficiency in the packed columns. The models were used for the engineering sizing of the packed columns in two breeding blanket concepts for the DEMO plant – utilizing DCLL (dual coolant lead lithium

  13. Silicon isotopes reveal recycled altered oceanic crust in the mantle sources of Ocean Island Basalts

    Science.gov (United States)

    Pringle, Emily A.; Moynier, Frédéric; Savage, Paul S.; Jackson, Matthew G.; Moreira, Manuel; Day, James M. D.

    2016-09-01

    The study of silicon (Si) isotopes in Ocean Island Basalts (OIB) has the potential to discern between different models for the origins of geochemical heterogeneities in the mantle. Relatively large (∼several per mil per atomic mass unit) Si isotope fractionation occurs in low-temperature environments during biochemical and geochemical precipitation of dissolved Si, where the precipitate is preferentially enriched in the lighter isotopes relative to the dissolved Si. In contrast, only a limited range (∼tenths of a per mil) of Si isotope fractionation has been observed from high-temperature igneous processes. Therefore, Si isotopes may be useful as tracers for the presence of crustal material within OIB mantle source regions that experienced relatively low-temperature surface processes in a manner similar to other stable isotope systems, such as oxygen. Characterizing the isotopic composition of the mantle is also of central importance to the use of the Si isotope system as a basis for comparisons with other planetary bodies (e.g., Moon, Mars, asteroids). Here we present the first comprehensive suite of high-precision Si isotope data obtained by MC-ICP-MS for a diverse suite of OIB. Samples originate from ocean islands in the Pacific, Atlantic, and Indian Ocean basins and include representative end-members for the EM-1, EM-2, and HIMU mantle components. On average, δ30Si values for OIB (-0.32 ± 0.09‰, 2 sd) are in general agreement with previous estimates for the δ30Si value of Bulk Silicate Earth (-0.29 ± 0.07‰, 2 sd; Savage et al., 2014). Nonetheless, some small systematic variations are present; specifically, most HIMU-type (Mangaia; Cape Verde; La Palma, Canary Islands) and Iceland OIB are enriched in the lighter isotopes of Si (δ30Si values lower than MORB), consistent with recycled altered oceanic crust and lithospheric mantle in their mantle sources.

  14. A set of engineered Escherichia coli expression strains for selective isotope and reactivity labeling of amino acid side chains and flavin cofactors.

    Directory of Open Access Journals (Sweden)

    Jennifer Mehlhorn

    Full Text Available Biological reactions are facilitated by delicate molecular interactions between proteins, cofactors and substrates. To study and understand their dynamic interactions researchers have to take great care not to influence or distort the object of study. As a non-invasive alternative to a site-directed mutagenesis approach, selective isotope labeling in combination with vibrational spectroscopy may be employed to directly identify structural transitions in wild type proteins. Here we present a set of customized Escherichia coli expression strains, suitable for replacing both the flavin cofactor and/or selective amino acids with isotope enriched or chemically modified substrates. For flavin labeling we report optimized auxotrophic strains with significantly enhanced flavin uptake properties. Labeled protein biosynthesis using these strains was achieved in optimized cultivation procedures using high cell density fermentation. Finally, we demonstrate how this approach is used for a clear assignment of vibrational spectroscopic difference signals of apoprotein and cofactor of a flavin containing photoreceptor of the BLUF (Blue Light receptors Using FAD family.

  15. Stable isotope deltas: Tiny, yet robust signatures in nature

    Science.gov (United States)

    Brand, Willi A.; Coplen, Tyler B.

    2012-01-01

    Although most of them are relatively small, stable isotope deltas of naturally occurring substances are robust and enable workers in anthropology, atmospheric sciences, biology, chemistry, environmental sciences, food and drug authentication, forensic science, geochemistry, geology, oceanography, and paleoclimatology to study a variety of topics. Two fundamental processes explain the stable isotope deltas measured in most terrestrial systems: isotopic fractionation and isotope mixing. Isotopic fractionation is the result of equilibrium or kinetic physicochemical processes that fractionate isotopes because of small differences in physical or chemical properties of molecular species having different isotopes. It is shown that the mixing of radioactive and stable isotope end members can be modelled to provide information on many natural processes, including 14C abundances in the modern atmosphere and the stable hydrogen and oxygen isotopic compositions of the oceans during glacial and interglacial times. The calculation of mixing fractions using isotope balance equations with isotope deltas can be substantially in error when substances with high concentrations of heavy isotopes (e.g. 13C, 2H, and 18O ) are mixed. In such cases, calculations using mole fractions are preferred as they produce accurate mixing fractions. Isotope deltas are dimensionless quantities. In the International System of Units (SI), these quantities have the unit 1 and the usual list of prefixes is not applicable. To overcome traditional limitations with expressing orders of magnitude differences in isotope deltas, we propose the term urey (symbol Ur), after Harold C. Urey, for the unit 1. In such a manner, an isotope delta value expressed traditionally as−25 per mil can be written as−25 mUr (or−2.5 cUr or−0.25 dUr; the use of any SI prefix is possible). Likewise, very small isotopic differences often expressed in per meg ‘units’ are easily included (e.g. either+0.015 ‰ or+15 per meg

  16. Stable isotope deltas: tiny, yet robust signatures in nature.

    Science.gov (United States)

    Brand, Willi A; Coplen, Tyler B

    2012-09-01

    Although most of them are relatively small, stable isotope deltas of naturally occurring substances are robust and enable workers in anthropology, atmospheric sciences, biology, chemistry, environmental sciences, food and drug authentication, forensic science, geochemistry, geology, oceanography, and paleoclimatology to study a variety of topics. Two fundamental processes explain the stable isotope deltas measured in most terrestrial systems: isotopic fractionation and isotope mixing. Isotopic fractionation is the result of equilibrium or kinetic physicochemical processes that fractionate isotopes because of small differences in physical or chemical properties of molecular species having different isotopes. It is shown that the mixing of radioactive and stable isotope end members can be modelled to provide information on many natural processes, including (14)C abundances in the modern atmosphere and the stable hydrogen and oxygen isotopic compositions of the oceans during glacial and interglacial times. The calculation of mixing fractions using isotope balance equations with isotope deltas can be substantially in error when substances with high concentrations of heavy isotopes (e.g. (13)C, (2)H, and (18)O ) are mixed. In such cases, calculations using mole fractions are preferred as they produce accurate mixing fractions. Isotope deltas are dimensionless quantities. In the International System of Units (SI), these quantities have the unit 1 and the usual list of prefixes is not applicable. To overcome traditional limitations with expressing orders of magnitude differences in isotope deltas, we propose the term urey (symbol Ur), after Harold C. Urey, for the unit 1. In such a manner, an isotope delta value expressed traditionally as-25 per mil can be written as-25 mUr (or-2.5 cUr or-0.25 dUr; the use of any SI prefix is possible). Likewise, very small isotopic differences often expressed in per meg 'units' are easily included (e.g. either+0.015 ‰ or+15 per meg

  17. Optimal Zn-Modified Ca–Si-Based Ceramic Nanocoating with Zn Ion Release for Osteoblast Promotion and Osteoclast Inhibition in Bone Tissue Engineering

    Directory of Open Access Journals (Sweden)

    Jiangming Yu

    2017-01-01

    Full Text Available We investigated the slow release of Zn ion (Zn2+ from nanocoatings and compared the in vitro response of osteoblasts (MC3T3-E1 and proosteoclasts (RAW 264.7 cultured on Ca2ZnSi2O7 nanocoated with different Zn/Ca molar ratios on a Ti-6Al-4V (i.e., Ti substrate to optimize cell behaviors and molecule levels. Significant morphology differences were observed among samples. By comparing with pure Ti and CaSiO3 nanocoating, the morphology of Ca2ZnSi2O7 ceramic nanocoatings was rough and contained small nanoparticles or aggregations. Slow Zn2+ release from nanocoatings was observed and Zn2+ concentration was regulated by varying the Zn/Ca ratios. The cell-response results showed Ca2ZnSi2O7 nanocoating at different Zn/Ca molar ratios for osteoblasts and osteoclasts. Compared to other nanocoatings and Ti, sample Zn/Ca (0.3 showed the highest cell viability and upregulated expression of the osteogenic differentiation genes ALP, COL-1, and OCN. Additionally, sample Zn/Ca (0.3 showed the greatest inhibition of RAW 264.7 cell growth and decreased the mRNA levels of osteoclast-related genes OAR, TRAP, and HYA1. Therefore, the optimal Zn-Ca ratio of 0.3 in Ca2ZnSi2O7 ceramic nanocoating on Ti had a dual osteoblast-promoting and osteoclast-inhibiting effect to dynamically balance osteoblasts/osteoclasts. These optimal Zn-Ca ratios are valuable for Ca2ZnSi2O7 ceramic nanocoating on Ti-coated implants for potential applications in bone tissue regeneration.

  18. Molecular hydrogen (H2 combustion emissions and their isotope (D/H signatures from domestic heaters, diesel vehicle engines, waste incinerator plants, and biomass burning

    Directory of Open Access Journals (Sweden)

    T. Röckmann

    2012-03-01

    Full Text Available Molecular hydrogen (H2, its stable isotope signature (δD, and the key combustion parameters carbon monoxide (CO, carbon dioxide (CO2, and methane (CH4 were measured from various combustion processes. H2 in the exhaust of gas and oil-fired heaters and of waste incinerator plants was generally depleted compared to ambient intake air, while CO was significantly elevated. These findings contradict the often assumed co-occurring net H2 and CO emissions in combustion processes and suggest that previous H2 emissions from combustion may have been overestimated when scaled to CO emissions. For the heater exhausts, H2 and δD generally decrease with increasing fuel-to-air ratio, from ambient values of ∼0.5 ppm and +130‰ to 0.2 ppm and −206‰, respectively. These results are interpreted as a combination of an isotopically light H2 source from fossil fuel combustion and a D/H kinetic isotope fractionation of hydrogen in the advected ambient air during its partial removal during combustion. Diesel exhaust measurements from dynamometer test stand driving cycles show elevated H2 and CO emissions during cold-start and some acceleration phases. Their molar H2/CO ratios are 2/CO emission ratios, along with CO global emission inventories, we estimate global H2 emissions for 2000, 2005, and 2010. For road transportation (gasoline and diesel, we calculate 8.6 ± 2.1 Tg, 6.3 ± 1.5 Tg, and 4.1 ± 1.0 Tg, respectively, whereas the contribution from diesel vehicles has increased from 5% to 8% over this time. Other fossil fuel emissions are believed to be negligible but H2 emissions from coal combustion are unknown. For residential (domestic emissions, which are likely dominated by biofuel combustion, emissions for the same years are estimated at 2.7 ± 0.7 Tg, 2.8 ± 0.7 Tg, and 3.0 ± 0.8 Tg, respectively. Our wood combustion measurements are combined with results from the literature to calculate biomass burning emissions. For these estimates, we propose a

  19. Ge-on-Si optoelectronics

    Energy Technology Data Exchange (ETDEWEB)

    Liu Jifeng, E-mail: Jifeng.Liu@Dartmouth.edu [Thayer School of Engineering, Dartmouth College, Hanover, NH 03755 (United States); Camacho-Aguilera, Rodolfo; Bessette, Jonathan T.; Sun, Xiaochen [Microphotonics Center, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Wang Xiaoxin [Thayer School of Engineering, Dartmouth College, Hanover, NH 03755 (United States); Cai Yan; Kimerling, Lionel C.; Michel, Jurgen [Microphotonics Center, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States)

    2012-02-01

    Electronic-photonic synergy has become an increasingly clear solution to enhance the bandwidth and improve the energy efficiency of information systems. Monolithic integration of optoelectronic devices is the ideal solution for large-scale electronic-photonic synergy. Due to its pseudo-direct gap behavior in optoelectronic properties and compatibility with Si electronics, epitaxial Ge-on-Si has become an attractive solution for monolithic optoelectronics. In this paper we will review recent progress in Ge-on-Si optoelectronics, including photodetectors, electroabsorption modulators, and lasers. The performance of these devices has been enhanced by band-engineering such as tensile strain and n-type doping, which transforms Ge towards a direct gap material. Selective growth reduces defect density and facilitates monolithic integration at the same time. Ge-on-Si photodetectors have approached or exceeded the performance of their III-V counterparts, with bandwidth-efficiency product > 30 GHz for p-i-n photodiodes and bandwidth-gain product > 340 GHz for avalanche photodiodes. Enhanced Franz-Keldysh effect in tensile-strained Ge offers ultralow energy photonic modulation with < 30 fJ/bit energy consumption and > 100 GHz intrinsic bandwidth. Room temperature optically-pumped lasing as well as electroluminescence has also been achieved from the direct gap transition of band-engineered Ge-on-Si waveguides. These results indicate that band-engineered Ge-on-Si is promising to achieve monolithic active optoelectronic devices on a Si platform.

  20. Design of Turning Equipment of Niobium Ring-ceramic Matrix Composites Rocket Engine Thrusters%铌环-C/SiC复合材料喷管的车削工装设计

    Institute of Scientific and Technical Information of China (English)

    黎明; 顾力强; 郭洪勤

    2014-01-01

    A model of rocket engine adopts the ceramic matrix composites nozzle, on which a niobium ring was deposited to connect to the engine by means of electron beam welding. For turning the welding stage of niobium ring, this paper introduces a kind of process equipment design train of thought. By using combining process equipment to find new positioning base, it effectively solved the problem of the fracture of ceramic matrix composites. This technology completely satisfied the requirements of tolerance of welding stage by turning results. And it improves the performance of the engine much further.%某火箭发动机采用 C/SiC复合材料的喷管,并在喷管上沉积一个带焊接头的铌环,通过该铌环与发动机金属头部进行电子束焊接。现需要车削完成喷管铌环的焊接台阶等特征。本文介绍了一种工装设计的新思路,即通过组合车削工装寻找定位基准。通过实际加工证明:该工艺技术完全满足焊接台阶的形位公差要求,并有效地解决了 C/SiC 复合材料脆性断裂等难题,最终满足了发动机的性能指标。

  1. Molecular hydrogen (H2) combustion emissions and their isotope (D/H) signatures from domestic heaters, diesel vehicle engines, waste incinerator plants, and biomass burning

    Science.gov (United States)

    Vollmer, M. K.; Walter, S.; Mohn, J.; Steinbacher, M.; Bond, S. W.; Röckmann, T.; Reimann, S.

    2012-07-01

    Molecular hydrogen (H2), its stable isotope signature (δD), and the key combustion parameters carbon monoxide (CO), carbon dioxide (CO2), and methane (CH4) were measured from various combustion processes. H2 in the exhaust of gas and oil-fired heaters and of waste incinerator plants was generally depleted compared to ambient intake air, while CO was significantly elevated. These findings contradict the often assumed co-occurring net H2 and CO emissions in combustion processes and suggest that previous H2 emissions from combustion may have been overestimated when scaled to CO emissions. For the gas and oil-fired heater exhausts, H2 and δD generally decrease with increasing CO2, from ambient values of ~0.5 ppm and +130‰ to 0.2 ppm and -206‰, respectively. These results are interpreted as a combination of an isotopically light H2 source from fossil fuel combustion and a D/H kinetic isotope fractionation of hydrogen in the advected ambient air during its partial removal during combustion. Diesel exhaust measurements from dynamometer test stand driving cycles show elevated H2 and CO emissions during cold-start and some acceleration phases. While H2 and CO emissions from diesel vehicles are known to be significantly less than those from gasoline vehicles (on a fuel-energy base), we find that their molar H2/CO ratios (median 0.026, interpercentile range 0.12) are also significantly less compared to gasoline vehicle exhaust. Using H2/CO emission ratios, along with CO global emission inventories, we estimate global H2 emissions for 2000, 2005, and 2010. For road transportation (gasoline and diesel), we calculate 8.3 ± 2.2 Tg, 6.0 ± 1.5 Tg, and 3.8 ± 0.94 Tg, respectively, whereas the contribution from diesel vehicles is low (0.9-1.4%). Other fossil fuel emissions are believed to be negligible but H2 emissions from coal combustion are unknown. For residential (domestic) emissions, which are likely dominated by biofuel combustion, emissions for the same years are

  2. Refractive index spectral dependence, Raman and transmission spectra of high-purity $^{28}$Si, $^{29}$Si, $^{30}$Si, and $^{nat}$Si single crystals

    CERN Document Server

    Plotnichenko, V G; Kryukova, E B; Koltashev, V V; Sokolov, V O; Dianov, E M; Gusev, A V; Gavva, V A; Kotereva, T V; Churbanov, M F

    2011-01-01

    Precise measurement of the refractive index of stable silicon isotopes $^{28}$Si, $^{29}$Si, $^{30}$Si single crystals with enrichments above 99.9 at.% and a silicon single crystal $^{nat}$Si of natural isotopic composition is performed with the Fourier-transform interference refractometry method from 1.06 to more than 80 mkm with 0.1 cm$^{-1}$ resolution and accuracy of $2 \\times 10^{-5} ... 1 \\times 10^{-4}$. The oxygen and carbon concentrations in all crystals are within $5 \\times 10^{15}$ cm$^{-3}$ and the content of metal impurities is $10^{-5} ... 10^{-6}$ at.%. The peculiar changes of the refractive index in the phonon absorption region of all silicon single crystals are shown. The coefficients of generalized Cauchy dispersion function approximating the experimental refractive index values all over the measuring range are given. The transmission and Raman spectra are also studied.

  3. Silicon isotope evidence against an enstatite chondrite Earth.

    Science.gov (United States)

    Fitoussi, Caroline; Bourdon, Bernard

    2012-03-23

    The compositions of Earth materials are strikingly similar to those of enstatite chondrite meteorites in many isotope systems. Although this suggests that Earth largely accreted from enstatite chondrites, definitive proof of this model has been lacking. By comparing the silicon (Si) isotope signatures of several extraterrestrial materials with terrestrial samples, we show that they cannot be explained by core-formation scenarios involving a bulk Earth of enstatite chondrite composition. Si isotope similarities between the bulk silicate Earth and the Moon preclude the existence of a hidden reservoir in the lower mantle, a necessary condition of the enstatite chondrite model, and require an equilibrium process after the Moon-forming impact. A three-end-member chondritic mixing model for Earth reconciles the Si isotope similarities between enstatite chondrites and Earth.

  4. Metabolic Profiling as Well as Stable Isotope Assisted Metabolic and Proteomic Analysis of RAW 264.7 Macrophages Exposed to Ship Engine Aerosol Emissions: Different Effects of Heavy Fuel Oil and Refined Diesel Fuel

    Science.gov (United States)

    Sapcariu, Sean C.; Kanashova, Tamara; Dilger, Marco; Diabaté, Silvia; Oeder, Sebastian; Passig, Johannes; Radischat, Christian; Buters, Jeroen; Sippula, Olli; Streibel, Thorsten; Paur, Hanns-Rudolf; Schlager, Christoph; Mülhopt, Sonja; Stengel, Benjamin; Rabe, Rom; Harndorf, Horst; Krebs, Tobias; Karg, Erwin; Gröger, Thomas; Weiss, Carsten; Dittmar, Gunnar; Hiller, Karsten; Zimmermann, Ralf

    2016-01-01

    Exposure to air pollution resulting from fossil fuel combustion has been linked to multiple short-term and long term health effects. In a previous study, exposure of lung epithelial cells to engine exhaust from heavy fuel oil (HFO) and diesel fuel (DF), two of the main fuels used in marine engines, led to an increased regulation of several pathways associated with adverse cellular effects, including pro-inflammatory pathways. In addition, DF exhaust exposure was shown to have a wider response on multiple cellular regulatory levels compared to HFO emissions, suggesting a potentially higher toxicity of DF emissions over HFO. In order to further understand these effects, as well as to validate these findings in another cell line, we investigated macrophages under the same conditions as a more inflammation-relevant model. An air-liquid interface aerosol exposure system was used to provide a more biologically relevant exposure system compared to submerged experiments, with cells exposed to either the complete aerosol (particle and gas phase), or the gas phase only (with particles filtered out). Data from cytotoxicity assays were integrated with metabolomics and proteomics analyses, including stable isotope-assisted metabolomics, in order to uncover pathways affected by combustion aerosol exposure in macrophages. Through this approach, we determined differing phenotypic effects associated with the different components of aerosol. The particle phase of diluted combustion aerosols was found to induce increased cell death in macrophages, while the gas phase was found more to affect the metabolic profile. In particular, a higher cytotoxicity of DF aerosol emission was observed in relation to the HFO aerosol. Furthermore, macrophage exposure to the gas phase of HFO leads to an induction of a pro-inflammatory metabolic and proteomic phenotype. These results validate the effects found in lung epithelial cells, confirming the role of inflammation and cellular stress in the

  5. Metabolic Profiling as Well as Stable Isotope Assisted Metabolic and Proteomic Analysis of RAW 264.7 Macrophages Exposed to Ship Engine Aerosol Emissions: Different Effects of Heavy Fuel Oil and Refined Diesel Fuel.

    Science.gov (United States)

    Sapcariu, Sean C; Kanashova, Tamara; Dilger, Marco; Diabaté, Silvia; Oeder, Sebastian; Passig, Johannes; Radischat, Christian; Buters, Jeroen; Sippula, Olli; Streibel, Thorsten; Paur, Hanns-Rudolf; Schlager, Christoph; Mülhopt, Sonja; Stengel, Benjamin; Rabe, Rom; Harndorf, Horst; Krebs, Tobias; Karg, Erwin; Gröger, Thomas; Weiss, Carsten; Dittmar, Gunnar; Hiller, Karsten; Zimmermann, Ralf

    2016-01-01

    Exposure to air pollution resulting from fossil fuel combustion has been linked to multiple short-term and long term health effects. In a previous study, exposure of lung epithelial cells to engine exhaust from heavy fuel oil (HFO) and diesel fuel (DF), two of the main fuels used in marine engines, led to an increased regulation of several pathways associated with adverse cellular effects, including pro-inflammatory pathways. In addition, DF exhaust exposure was shown to have a wider response on multiple cellular regulatory levels compared to HFO emissions, suggesting a potentially higher toxicity of DF emissions over HFO. In order to further understand these effects, as well as to validate these findings in another cell line, we investigated macrophages under the same conditions as a more inflammation-relevant model. An air-liquid interface aerosol exposure system was used to provide a more biologically relevant exposure system compared to submerged experiments, with cells exposed to either the complete aerosol (particle and gas phase), or the gas phase only (with particles filtered out). Data from cytotoxicity assays were integrated with metabolomics and proteomics analyses, including stable isotope-assisted metabolomics, in order to uncover pathways affected by combustion aerosol exposure in macrophages. Through this approach, we determined differing phenotypic effects associated with the different components of aerosol. The particle phase of diluted combustion aerosols was found to induce increased cell death in macrophages, while the gas phase was found more to affect the metabolic profile. In particular, a higher cytotoxicity of DF aerosol emission was observed in relation to the HFO aerosol. Furthermore, macrophage exposure to the gas phase of HFO leads to an induction of a pro-inflammatory metabolic and proteomic phenotype. These results validate the effects found in lung epithelial cells, confirming the role of inflammation and cellular stress in the

  6. Metabolic Profiling as Well as Stable Isotope Assisted Metabolic and Proteomic Analysis of RAW 264.7 Macrophages Exposed to Ship Engine Aerosol Emissions: Different Effects of Heavy Fuel Oil and Refined Diesel Fuel.

    Directory of Open Access Journals (Sweden)

    Sean C Sapcariu

    Full Text Available Exposure to air pollution resulting from fossil fuel combustion has been linked to multiple short-term and long term health effects. In a previous study, exposure of lung epithelial cells to engine exhaust from heavy fuel oil (HFO and diesel fuel (DF, two of the main fuels used in marine engines, led to an increased regulation of several pathways associated with adverse cellular effects, including pro-inflammatory pathways. In addition, DF exhaust exposure was shown to have a wider response on multiple cellular regulatory levels compared to HFO emissions, suggesting a potentially higher toxicity of DF emissions over HFO. In order to further understand these effects, as well as to validate these findings in another cell line, we investigated macrophages under the same conditions as a more inflammation-relevant model. An air-liquid interface aerosol exposure system was used to provide a more biologically relevant exposure system compared to submerged experiments, with cells exposed to either the complete aerosol (particle and gas phase, or the gas phase only (with particles filtered out. Data from cytotoxicity assays were integrated with metabolomics and proteomics analyses, including stable isotope-assisted metabolomics, in order to uncover pathways affected by combustion aerosol exposure in macrophages. Through this approach, we determined differing phenotypic effects associated with the different components of aerosol. The particle phase of diluted combustion aerosols was found to induce increased cell death in macrophages, while the gas phase was found more to affect the metabolic profile. In particular, a higher cytotoxicity of DF aerosol emission was observed in relation to the HFO aerosol. Furthermore, macrophage exposure to the gas phase of HFO leads to an induction of a pro-inflammatory metabolic and proteomic phenotype. These results validate the effects found in lung epithelial cells, confirming the role of inflammation and cellular

  7. Silicon isotopes in angrites and volatile loss in planetesimals

    Science.gov (United States)

    Moynier, Frédéric; Savage, Paul S.; Badro, James; Barrat, Jean-Alix

    2014-01-01

    Inner solar system bodies, including the Earth, Moon, and asteroids, are depleted in volatile elements relative to chondrites. Hypotheses for this volatile element depletion include incomplete condensation from the solar nebula and volatile loss during energetic impacts. These processes are expected to each produce characteristic stable isotope signatures. However, processes of planetary differentiation may also modify the isotopic composition of geochemical reservoirs. Angrites are rare meteorites that crystallized only a few million years after calcium–aluminum-rich inclusions and exhibit extreme depletions in volatile elements relative to chondrites, making them ideal samples with which to study volatile element depletion in the early solar system. Here we present high-precision Si isotope data that show angrites are enriched in the heavy isotopes of Si relative to chondritic meteorites by 50–100 ppm/amu. Silicon is sufficiently volatile such that it may be isotopically fractionated during incomplete condensation or evaporative mass loss, but theoretical calculations and experimental results also predict isotope fractionation under specific conditions of metal–silicate differentiation. We show that the Si isotope composition of angrites cannot be explained by any plausible core formation scenario, but rather reflects isotope fractionation during impact-induced evaporation. Our results indicate planetesimals initially formed from volatile-rich material and were subsequently depleted in volatile elements during accretion. PMID:25404309

  8. Silicon isotopes in angrites and volatile loss in planetesimals.

    Science.gov (United States)

    Pringle, Emily A; Moynier, Frédéric; Savage, Paul S; Badro, James; Barrat, Jean-Alix

    2014-12-02

    Inner solar system bodies, including the Earth, Moon, and asteroids, are depleted in volatile elements relative to chondrites. Hypotheses for this volatile element depletion include incomplete condensation from the solar nebula and volatile loss during energetic impacts. These processes are expected to each produce characteristic stable isotope signatures. However, processes of planetary differentiation may also modify the isotopic composition of geochemical reservoirs. Angrites are rare meteorites that crystallized only a few million years after calcium-aluminum-rich inclusions and exhibit extreme depletions in volatile elements relative to chondrites, making them ideal samples with which to study volatile element depletion in the early solar system. Here we present high-precision Si isotope data that show angrites are enriched in the heavy isotopes of Si relative to chondritic meteorites by 50-100 ppm/amu. Silicon is sufficiently volatile such that it may be isotopically fractionated during incomplete condensation or evaporative mass loss, but theoretical calculations and experimental results also predict isotope fractionation under specific conditions of metal-silicate differentiation. We show that the Si isotope composition of angrites cannot be explained by any plausible core formation scenario, but rather reflects isotope fractionation during impact-induced evaporation. Our results indicate planetesimals initially formed from volatile-rich material and were subsequently depleted in volatile elements during accretion.

  9. Highly effective strain-induced band-engineering of (111) oriented, direct-gap GeSn crystallized on amorphous SiO2 layers

    Science.gov (United States)

    Li, Haofeng; Wang, Xiaoxin; Liu, Jifeng

    2016-03-01

    We demonstrate highly effective strain-induced band-engineering of (111) oriented direct-gap Ge1-xSnx thin films (0.074 GeSn films also demonstrate high thermal stability, offering both excellent direct-gap optoelectronic properties and fabrication/operation robustness for integrated photonics.

  10. 40 CFR 86.447-2006 - What provisions apply to motorcycle engines below 50 cc that are certified under the Small SI...

    Science.gov (United States)

    2010-07-01

    ... 40 CFR part 90 or 1051 for the appropriate model year. If you comply with all the provisions of this section, we consider the certificate issued under 40 CFR part 90 or 1051 for each engine or vehicle to... that apply to vehicles that are certified to chassis-based standards under 40 CFR part 1051....

  11. The silicon isotope record of early silica diagenesis

    Science.gov (United States)

    Tatzel, Michael; von Blanckenburg, Friedhelm; Oelze, Marcus; Schuessler, Jan A.; Bohrmann, Gerhard

    2015-10-01

    The heavy isotopes of silicon are strongly enriched in some of the youngest, early diagenetically formed porcellanite layers from the Southwest Indian Ridge (Pleistocene) and the Maud Rise (Pliocene). These porcellanite layers are composed of opal-CT and were formed by the conversion of amorphous silica (opal-A) from siliceous sediment via dissolution-reprecipitation. Their bulk δ30Si values range between 1.7 and 2.3‰. Detritus-poor siliceous sediment surrounding these layers is significantly lower at -0.3 to 1.5‰. Sequential chemical extractions of bulk siliceous sediment show (i) preferential dissolution of diatoms featuring higher δ30Si than radiolaria and Al-Si components. The detailed investigation of porcellanite layers by micro-scale Si isotope and Al/Si analyses using UV femtosecond laser ablation ICP mass spectrometry show that (ii) precipitation of authigenic aluminum silicates enriched in light Si isotopes drives pore waters to even higher δ30Si. We suggest that the same processes redistributed stable silicon isotopes in precursor siliceous sediments of ancient chert. We infer that past environmental conditions can be reconstructed with high fidelity from the stable Si isotope composition of chert when initial seawater Si concentrations were high (such as in the Precambrian). Exchange of Si between layers during phase transformation (from opal-A to opal-CT and from opal-CT to quartz) is impeded when variable amounts of detrital minerals are present, because they control rates of silica phase transformation and hence the timing of dissolution-reprecipitation during burial.

  12. Sol-Gel SiO2-CaO-P2O5 biofilm with surface engineered for medical application

    Directory of Open Access Journals (Sweden)

    Sonia Regina Federman

    2007-06-01

    Full Text Available Sol-gel film in the SiO2-CaO-P2O5 system was prepared from TEOS, TEP, alcohol and hydrated calcium nitrate in an acidic medium. The coatings were deposited on stainless steel using the dip-coating technique. After deposition, the composite was submitted to heat treatment, at different temperatures and exposure times to investigate the influence of such parameters on the surface morphology of the composite. The coated surfaces were characterized by AFM, SEM and FTIR. The present study showed that the formation of different textures (an important parameter in implant fixation could be controlled by temperature and time of heat treatment.

  13. Radionuclides, stable isotopes, inorganic constituents, and organic compounds in water from selected wells and springs from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman Area, Idaho, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Bartholomay, R.C.; Edwards, D.D.; Campbell, L.J.

    1994-10-01

    The US Geological Survey and the Idaho Department of Water Resources, in response to a request from the US Department of Energy, sampled 19 sites as part of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman area. Water samples were collected and analyzed for selected radionuclides, stable isotopes, inorganic constituents, and organic compounds. The samples were collected from seven irrigation wells, four domestic wells, two springs, one stock well, three dairy wells, one observation well, and one commercial well. Two quality assurance samples also were collected and analyzed. None of the radionuclide, inorganic constituent, or organic compound concentrations exceeded the established maximum contaminant levels for drinking water. Most of the radionuclide and inorganic constituent concentrations exceeded their respective reporting levels. All samples analyzed for surfactants and dissolved organic carbon had concentrations that equaled or exceeded their reporting levels. The ethylbenzene concentration in one water sample exceeded the reporting level.

  14. Color-tunable electroluminescence from Eu-doped TiO(2)/p(+)-Si heterostructured devices: engineering of energy transfer.

    Science.gov (United States)

    Zhu, Chen; Lv, Chunyan; Wang, Canxing; Sha, Yiping; Li, Dongsheng; Ma, Xiangyang; Yang, Deren

    2015-02-09

    We report on color-tunable electroluminescence (EL) from TiO(2):Eu/p(+)-Si heterostructured devices using different TiO(2):Eu films in terms of Eu content and annealing temperature. It is found that the Eu-related emissions are activated by the energy transferred from TiO(2) host via oxygen vacancies, at the price of weakened oxygen-vacancy-related emissions. Both the higher Eu content and the higher annealing temperature for TiO(2):Eu films facilitate the aforementioned energy transfer. In this context, the dominant EL from the TiO(2):Eu/p(+)-Si heterostructured devices can be transformed from oxygen-vacancy-related emissions into Eu-related emissions with increasing Eu-content and annealing temperature for TiO(2):Eu films, exhibiting different colors of emanated light. We believe that this work sheds light on developing silicon-based red emitters using the Eu-doped oxide semiconductor films.

  15. Surface Engineering of Polycrystalline Silicon for Long-term Mechanical Stress Endurance Enhancement in Flexible Low Temperature Poly-Si Thin-Film Transistors.

    Science.gov (United States)

    Chen, Bo-Wei; Chang, Ting-Chang; Hung, Yu-Ju; Huang, Shin-Ping; Chen, Hua-Mao; Liao, Po-Yung; Lin, Yu-Ho; Huang, Hui-Chun; Chiang, Hsiao-Cheng; Yang, Chung-I; Zheng, Yu-Zhe; Chu, Ann-Kuo; Li, Hung-Wei; Tsai, Chih-Hung; Lu, Hsueh-Hsing; Wang, Terry Tai-Jui; Chang, Tsu-Chiang

    2017-02-08

    Surface morphology in polycrystalline silicon (poly-Si) film is an issue regardless of whether conventional excimer laser annealing (ELA) or the newer metal-induced lateral crystallization (MILC) process is used. This paper investigates the stress distribution while undergoing long-term mechanical stress and the influence of stress on electrical characteristics. Our simulated results show that the non-uniform stress in the gate insulator is more pronounced near the polysilicon/gate insulator edge and at the two sides of the polysilicon protrusion. This stress results in defects in the gate insulator and leads to a non-uniform degradation phenomenon, which affects both the performance and reliability in thin-film transistors (TFTs). The degree of degradation is similar regardless of bending axis (channel-length axis, channel-width axis) or bending type (compression, tension), which means that the degradation is dominated by the protrusion effects. Furthermore, by utilizing long-term electrical bias stresses after undergoing long-tern bending stress, it is apparent that the carrier injection is severe in the sub-channel region, which confirms that the influence of protrusions is crucial. To eliminate the influence of surface morphology in poly-Si, three kinds of laser energy density were used during crystallization to control the protrusion height. The device with lowest protrusions demonstrates the smallest degradation after undergoing long-term bending.

  16. 40 CFR 60.4239 - What are my compliance requirements if I am a manufacturer of stationary SI internal combustion...

    Science.gov (United States)

    2010-07-01

    ... engines in 40 CFR part 90 or 40 CFR part 1054, and manufacturers of stationary SI emergency engines that... I am a manufacturer of stationary SI internal combustion engines >19 KW (25 HP) that use gasoline or... manufacturer of stationary SI internal combustion engines >19 KW (25 HP) that use gasoline or a manufacturer...

  17. Performance, emission and combustion characteristics of a branched higher mass, C3 alcohol (isopropanol blends fuelled medium duty MPFI SI engine

    Directory of Open Access Journals (Sweden)

    Harish Sivasubramanian

    2017-04-01

    Full Text Available With growing concerns about environmental pollution caused by automobiles, biofuels containing oxygen – also known as oxygenates – are being researched very rigorously. In this article, we have inspected the use of isopropanol/gasoline blends, as fuel in a 4 – cylinder Spark Ignition engine with Multi-Point Fuel Injection System. Isopropanol was mixed with Unleaded Gasoline in proportions of 10, 20 and 30% by volume (IPA10, IPA20 and IPA30. It is found that with the use of isopropanol/gasoline blends in Spark Ignition Engine, Brake Thermal Efficiency and NOx emissions increased whereas carbon monoxide and hydrocarbon emissions decreased. When the spark timing was retarded by 2 degrees, it was found that isopropanol/gasoline blends emitted lower NOx emissions than those at original spark timing. Isopropanol blends also increased the in-cylinder pressure values and heat release rate values.

  18. Stable isotope studies

    Energy Technology Data Exchange (ETDEWEB)

    Ishida, T.

    1992-01-01

    The research has been in four general areas: (1) correlation of isotope effects with molecular forces and molecular structures, (2) correlation of zero-point energy and its isotope effects with molecular structure and molecular forces, (3) vapor pressure isotope effects, and (4) fractionation of stable isotopes. 73 refs, 38 figs, 29 tabs.

  19. Present status and strategic plan for the stable isotope reference materials at the IAEA.

    Science.gov (United States)

    Assonov, Sergey; Groening, Manfred

    2016-04-01

    The presentation will give the overview of the stable isotope reference materials (SI-RMs) under distribution by the IAEA, its stable isotope laboratory and capacities related to material testing & production as well as future plans. Historically, most of the IAEA reference materials were produced and made available via collaborations with expert stable isotope laboratories worldwide. The IAEA plans include several directions as follows: • Maintaining the scale-defining SI-RMs at the highest level and introducing adequate replacements when needed; • Monitoring existing SI-RMs for any potential alteration(s) and of isotopic values assigned; • Identifying and then addressing the needs for new SI-RMs, with the priority to address the most critical applications (environmental and climate related applications, human health, food safety studies) and newly emerging analytical isotope techniques; • Performing all measurements aimed for characterisation of new SI-RMs and the corresponding uncertainty evaluation in accordance to the latest metrological concepts; • Promoting metrological approaches on traceability and uncertainty evaluation in every day practice of stable isotope measurements; • Expanding the IAEA capacities for SI-RMs by (i) planning a renewed laboratory at IAEA; (ii) enlarging collaboration with expert laboratories aimed to help IAEA in production and characterisation of new SI-RMs. These major directions will help to address the increasing demand for Stable Isotope Reference Materials.

  20. Cfd Aided Development of a Si-Di Engine Aide au développement d'un moteur à injection directe d'essence par modélisation 3D

    Directory of Open Access Journals (Sweden)

    Henriot S.

    2006-12-01

    Full Text Available Gasoline Direct Injection (GDI appears to be the most relevant way to improve fuel efficiency of SI engines. But today, GDI is essentially regarded as a suitable technology for relatively high displacement engines, and the literature shows that the R&D effort on GDI engines is generally made for bores larger than 80 mm. For small bore engines (bore below 75 mm, locating an injector in already congested cylinder heads, with ultra lean stratified combustion capability while maintaining high engine specific power and proper cylinder head cooling is a real challenge. For such an engine, IFP is developing a 3-valve per cylinder engine (NSDI-3, based on a narrow spacingconcept, with a spark-plug-close-to-the-injector design and a suitable piston to confine the gasoline spray within the vicinity of the ignition location. This paper describes the contribution of 3D modeling to the development of this engine, from the initial work during the design of the prototype combustion chamber, to the development and tuning of the prototype engine on the test bench. Depuis quelques années, l'injection directe d'essence apparaÎt comme l'une des voies d'investigation les plus performantes pour améliorer le rendement des moteurs à allumage commandé. Cependant, cette technologie est, actuellement, plutôt réservée aux moteurs de cylindrée assez importante, et les travaux de R&D présentés dans la littérature font surtout état de développement pour des moteurs d'alésage supérieur à 80 mm. En ce qui concerne les petits moteurs (alésage inférieur à 75 mm, implanter un injecteur dans une culasse déjà largement encombrée, avec un fort potentiel de combustion en mélange très pauvre stratifié, tout en maintenant de bonnes performances moteur et un circuit de refroidissement bien dimensionné, constitue un véritable défi. Pour un tel moteur, l'Institut français du pétrole (IFP développe une solution à 3 soupapes par cylindre (NSDI-3, basée sur

  1. 3C-SiC nanocrystal growth on 10° miscut Si(001) surface

    Energy Technology Data Exchange (ETDEWEB)

    Deokar, Geetanjali, E-mail: gitudeo@gmail.com [INSP, UPMC, CNRS UMR 7588, 4 place Jussieu, Paris F-75005 (France); D' Angelo, Marie; Demaille, Dominique [INSP, UPMC, CNRS UMR 7588, 4 place Jussieu, Paris F-75005 (France); Cavellin, Catherine Deville [INSP, UPMC, CNRS UMR 7588, 4 place Jussieu, Paris F-75005 (France); Faculté des Sciences et Technologie UPEC, 61 av. De Gaulle, Créteil F-94010 (France)

    2014-04-01

    The growth of 3C-SiC nano-crystal (NC) on 10° miscut Si(001) substrate by CO{sub 2} thermal treatment is investigated by scanning and high resolution transmission electron microscopies. The vicinal Si(001) surface was thermally oxidized prior to the annealing at 1100 °C under CO{sub 2} atmosphere. The influence of the atomic steps at the vicinal SiO{sub 2}/Si interface on the SiC NC growth is studied by comparison with the results obtained for fundamental Si(001) substrates in the same conditions. For Si miscut substrate, a substantial enhancement in the density of the SiC NCs and a tendency of preferential alignment of them along the atomic step edges is observed. The SiC/Si interface is abrupt, without any steps and epitaxial growth with full relaxation of 3C-SiC occurs by domain matching epitaxy. The CO{sub 2} pressure and annealing time effect on NC growth is analyzed. The as-prepared SiC NCs can be engineered further for potential application in optoelectronic devices and/or as a seed for homoepitaxial SiC or heteroepitaxial GaN film growth. - Highlights: • Synthesis of 3C-SiC nanocrystals epitaxied on miscut-Si using a simple technique • Evidence of domain matching epitaxy at the SiC/Si interface • SiC growth proceeds along the (001) plane of host Si. • Substantial enhancement of the SiC nanocrystal density due to the miscut • Effect of the process parameters (CO{sub 2} pressure and annealing duration)

  2. Fusion of Si28+Si28,30: Different trends at sub-barrier energies

    Science.gov (United States)

    Montagnoli, G.; Stefanini, A. M.; Esbensen, H.; Jiang, C. L.; Corradi, L.; Courtin, S.; Fioretto, E.; Grebosz, J.; Haas, F.; Jia, H. M.; Mazzocco, M.; Michelagnoli, C.; Mijatović, T.; Montanari, D.; Parascandolo, C.; Scarlassara, F.; Strano, E.; Szilner, S.; Torresi, D.

    2014-10-01

    Background: The fusion excitation function of the system Si28+Si28 at energies near and below the Coulomb barrier is known only down to ≃15 mb. This precludes any information on both coupling effects on sub-barrier cross sections and the possible appearance of hindrance. For Si28+Si30 even if the fusion cross section is measured down to ≃50 μb, the evidence of hindrance is marginal. Both systems have positive fusion Q values. While Si28 has a deformed oblate shape, Si30 is spherical. Purpose: We investigate 1. the possible influence of the different structure of the two Si isotopes on the fusion excitation functions in the deep sub-barrier region and 2. whether hindrance exists in the Si+Si systems and whether it is strong enough to generate an S-factor maximum, thus allowing a comparison with lighter heavy-ion systems of astrophysical interest. Methods: Si28 beams from the XTU Tandem accelerator of the INFN Laboratori Nazionali di Legnaro were used. The setup was based on an electrostatic beam separator, and fusion evaporation residues (ER) were detected at very forward angles. Angular distributions of ER were measured. Results: Fusion cross sections of Si28+Si28 have been obtained down to ≃600 nb. The slope of the excitation function has a clear irregularity below the barrier, but no indication of a S-factor maximum is found. For Si28+Si30 the previous data have been confirmed and two smaller cross sections have been measured down to ≃4 μb. The trend of the S-factor reinforces the previous weak evidence of hindrance. Conclusions: The sub-barrier cross sections for Si28+Si28 are overestimated by coupled-channels calculations based on a standard Woods-Saxon potential, except for the lowest energies. Calculations using the M3Y+repulsion potential are adjusted to fit the Si28+Si28 and the existing Si30+Si30 data. An additional weak imaginary potential (probably simulating the effect of the oblate Si28 deformation) is required to fit the low-energy trend of

  3. A global Ge isotope budget

    Science.gov (United States)

    Baronas, J. Jotautas; Hammond, Douglas E.; McManus, James; Wheat, C. Geoffrey; Siebert, Christopher

    2017-04-01

    We present measurements of Ge isotope composition and ancillary data for samples of river water, low- and high-temperature hydrothermal fluids, and seawater. The dissolved δ74Ge composition of analyzed rivers ranges from 2.0 to 5.6‰, which is significantly heavier than previously determined values for silicate rocks (δ74Ge = 0.4-0.7‰, Escoube et al., Geostand. Geoanal. Res., 36(2), 2012) from which dissolved Ge is primarily derived. An observed negative correlation between riverine Ge/Si and δ74Ge signatures suggests that the primary δ74Ge fractionation mechanism during rock weathering is the preferential incorporation of light isotopes into secondary weathering products. High temperature (>150 °C) hydrothermal fluids analyzed in this study have δ74Ge of 0.7-1.6‰, most likely fractionated during fluid equilibration with quartz in the reaction zone. Low temperature (25-63 °C) hydrothermal fluids are heavier (δ74Ge between 2.9‰ and 4.1‰) and most likely fractionated during Ge precipitation with hydrothermal clays. Seawater from the open ocean has a δ74Gesw value of 3.2 ± 0.4‰, and is indistinguishable among the different ocean basins at the current level of precision. This value should be regulated over time by the isotopic balance of Ge sources and sinks, and a new compilation of these fluxes is presented, along with their estimated isotopic compositions. Assuming steady-state, non-opal Ge sequestration during sediment authigenesis likely involves isotopic fractionation Δ74Gesolid-solution that is -0.6 ± 1.8‰.

  4. Comparison of the emissions and SFC for 10:1 and 12:1 compression ratio 1.8 litre SI engines using lean mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Andrews, G.; Osses, M.; Desai, M.; Haralambidis, E. [Leeds Univ. (United Kingdom); Ounzain, A.; Robertson, G. [Ford Motor Co. Ltd., Dagenham (United Kingdom)

    1996-12-31

    A standard 10:1 compression ratio Ford Zetec engine was modified to a 12:1 compression ratio and investigated over the lean combustion region with a comparison with the base 10:1 compression ratio engine. All the comparisons were carried out at the same power output as for stoichiometric operation, using throttle adjustments to achieve the increased power as the mixture was made leaner. The aim of the higher compression ratio was to increase the power in the lean combustion region and thus to extend the lean burning limit for the same power output. The lean limit was then set as the wide open throttle lean combustion for a desired power output. The power outputs studied were 10 and 15KW at 1500 r/min, which is typical of the low power urban drive cycle in the EC emissions test cycle. Additional reductions in NOx using spark timing control was also investigated for lean mixtures. The lean burning capability at different conditions was investigated at the minimum fuel consumption spark timing and at 5% above the minimum SFC, but still below the SFC for stoichiometric operation. The borderline detonation limit (BLDL) as detected using a cylinder pressure transducer and spark timing loops were limited by the BLDL timing. The higher compression ratio was shown to extend the lean burning limit from 22/1 to 26/1 at constant 10KW power output. This was accompanied by an increase by NOx, hydrocarbons and CO. The extended lean limit was not effectively useable at 10 KW power due to the large increase in hydrocarbons for mixtures leaner than 22/1. Thus the lower NOx emissions in this region could not be exploited and there was little advantage, from a lean combustion viewpoint, of operation at 12/1 compression ratio. However, at the 15KW power output condition there were clear SFC advantages and smaller NOx reductions for the higher CR lean burn engine. (author)

  5. Presolar Grains and Their Isotopic Anomalies in Meteorites

    Institute of Scientific and Technical Information of China (English)

    林杨挺; 王世杰

    2001-01-01

    Study on presolar grains including diamond, silicon carbide, graphite, silicon nitrite (Si3N4), corundum and spinel isolated from meteorites is summarized in this paper. Except for nanometer-sized diamond, the other grains are micrometers to submicrometers in size. The presolar grains survived mainly in the fine -grained matrix of primitive chondrites and were isolated by chemical treatments. Diamond contains Xe isotopes (Xe-HL), typically produced in p- and r-processes, probably formed in supernovae. Mainstream silicon carbides are enriched in 29, 30Si and 13C, but depleted in 15N. They also contain various s-process products, consistent with calculations of AGB stars. Other silicon carbides exhibit much larger isotopic anomalies and are classified as groups X, Y, Z and AB. Among them, group X of SiC is characterized by enrichment of 28Si and daughter isotopes of various short-lived nuclides, suggesting an origin from supernovae. Graphite can be divided into four density fractions with distinct isotopic compositions. They may form in AGB stars, novae and supernovae, respectively. Si3N4 is similar to X-SiC in isotopic composition. Corundum is classified as four groups based on their oxygen isotopic compositions. AGB and red giant stars are possible sources for the oxide. More comprehensive study of presolar grains, especially discovery of the other types of oxides and silicates, isotopic analyses of individual submicrometer-sized grains and distribution of presolar grains among various chemical groups and petrographic types of chondrites will provide new information on nucleosynthesis, stellar evolution and formation of the solar nebula.

  6. Presolar Grains and Their Isotopic Anomalies in Meteorites

    Institute of Scientific and Technical Information of China (English)

    林杨挺; 王世杰

    2001-01-01

    Study on presolar grains including diamond,silicon carbide,graphite,silicon nitrite(Si3N4),coundum and spinel isolated from meteorites is summarized in this paper.Except for nanometer-sized diamond,the other grains are micrometers to submicrometers in size.The presolar grains survived mainly in the fine-grained matrix of primitive chondrites and were isolated by chemical treatments.Diamond contains Xe isotopes(Xe-HL),typically produced in p-and r-processes,probably formed in supernovae.Mainstream silicon carbides are enriched in 29,30Si and 13C,but depleted in 15N.They also contain various s-process products,consistent with calculations of AGB stars.Other silicon carbides exhibit much larger isotopic anomalies and are classified as groups X,Y,Z and AB.Among them,group X of SiC is characterized by enrichment of 28Si and daughter isotopes of various short-lived nuclides,suggesting an origin from supernovae.Graphite can be divided into four density fractions with distince isotopic compositions.They may form in AGB stars,novae and supernovae,respctively,Si3N4 is similar to X-SiC in isotopic composition.Corundum is classified as four groups based on theid oxygen isotopic compositions.AGB and red giang stare are possible sources for the oxide.More comprehensive study of presolar grains,especially discovery of the other types of oxides and silicates,isotopic analyses of individual submicrometer-sized grains and distribution of presolar grains among various chemical groups and petropaphic types of chondrites will provide new information on nucleosynthesis,stellar evolution and formation of the solar nebula.

  7. 2D-C/[SiC-(B-C)]复合材料在航空发动机燃烧室中的自愈合行为研究%Self-healing Behavior of 2D-C/[SiC-(B-C)] Composite in Aero-engine Combustion Chamber

    Institute of Scientific and Technical Information of China (English)

    刘光海; 成来飞; 栾新刚; 刘永胜

    2011-01-01

    采用以B-C陶瓷为基体自愈合改性组元的2D-C/[SiC-(B-C)]以及经过硅硼玻璃改性的2D-C/[SiC-(B-C)]制备浮壁瓦片,分别在1000、1200、1350℃下对其进行发动机燃烧室环境考核.对考核后的浮壁瓦片进行取样,并在室温下进行拉伸强度以及三点弯曲强度测试.结果发现:经过环境考核试样的力学性能都有不同程度的提高,拉伸强度和三点弯曲强度随着考核温度的升高而提高,其中三点弯曲强度的升高速率更快.通过SEM观察,B-C自愈合组元氧化生成的玻璃相以及改性硅硼玻璃相在考核过程中有效地封填了试样的孔隙和裂纹.最后通过力学性能测试结合SEM观察,初步分析了两种复合材料在航空发动机燃烧室中的愈合机制.%2D-C/[SiC-(B-C)] samples modified by B-C ceramic as self-healing component and boron-silicon glass phase were assessed by environmental engine experiments at 1000℃, 1200℃, 1350℃. Furthermore, tensile strength and three point bending strength of the samples were tested at room temperature after assessment. The results showed that the tensile strength and three point bending strength increased with the increase of assessment temperature, however, three point bending mechanical properties increased at a higher rate. SEM results showed that the glass phase generated by oxidization of B-C self-healing component and the boron oxide glass phase filled pores and cracks effectively. According to the experiments results, the self-healing mechanisms in aero-engine combustion chamber of such two samples were discussed.

  8. Nanosized Mesoporous Bioactive Glass/Poly(lactic-co-glycolic Acid Composite-Coated CaSiO3 Scaffolds with Multifunctional Properties for Bone Tissue Engineering

    Directory of Open Access Journals (Sweden)

    Mengchao Shi

    2014-01-01

    Full Text Available It is of great importance to prepare multifunctional scaffolds combining good mechanical strength, bioactivity, and drug delivery ability for bone tissue engineering. In this study, nanosized mesoporous bioglass/poly(lactic-co-glycolic acid composite-coated calcium silicate scaffolds, named NMBG-PLGA/CS, were successfully prepared. The morphology and structure of the prepared scaffolds were characterized by scanning electron microscopy and X-ray diffraction. The effects of NMBG on the apatite mineralization activity and mechanical strength of the scaffolds and the attachment, proliferation, and alkaline phosphatase activity of MC3T3 cells as well as drug ibuprofen delivery properties were systematically studied. Compared to pure CS scaffolds and PLGA/CS scaffolds, the prepared NMBG-PLGA/CS scaffolds had greatly improved apatite mineralization activity in simulated body fluids, much higher mechanical property, and supported the attachment of MC3T3 cells and enhanced the cell proliferation and ALP activity. Furthermore, the prepared NMBG-PLGA/CS scaffolds could be used for delivering ibuprofen with a sustained release profile. Our study suggests that the prepared NMBG-PLGA/CS scaffolds have improved physicochemical, biological, and drug-delivery property as compared to conventional CS scaffolds, indicating that the multifunctional property of the prepared scaffolds for the potential application of bone tissue engineering.

  9. Nanosized mesoporous bioactive glass/poly(lactic-co-glycolic acid) composite-coated CaSiO3 scaffolds with multifunctional properties for bone tissue engineering.

    Science.gov (United States)

    Shi, Mengchao; Zhai, Dong; Zhao, Lang; Wu, Chengtie; Chang, Jiang

    2014-01-01

    It is of great importance to prepare multifunctional scaffolds combining good mechanical strength, bioactivity, and drug delivery ability for bone tissue engineering. In this study, nanosized mesoporous bioglass/poly(lactic-co-glycolic acid) composite-coated calcium silicate scaffolds, named NMBG-PLGA/CS, were successfully prepared. The morphology and structure of the prepared scaffolds were characterized by scanning electron microscopy and X-ray diffraction. The effects of NMBG on the apatite mineralization activity and mechanical strength of the scaffolds and the attachment, proliferation, and alkaline phosphatase activity of MC3T3 cells as well as drug ibuprofen delivery properties were systematically studied. Compared to pure CS scaffolds and PLGA/CS scaffolds, the prepared NMBG-PLGA/CS scaffolds had greatly improved apatite mineralization activity in simulated body fluids, much higher mechanical property, and supported the attachment of MC3T3 cells and enhanced the cell proliferation and ALP activity. Furthermore, the prepared NMBG-PLGA/CS scaffolds could be used for delivering ibuprofen with a sustained release profile. Our study suggests that the prepared NMBG-PLGA/CS scaffolds have improved physicochemical, biological, and drug-delivery property as compared to conventional CS scaffolds, indicating that the multifunctional property of the prepared scaffolds for the potential application of bone tissue engineering.

  10. Laser Isotope Enrichment for Medical and Industrial Applications

    Energy Technology Data Exchange (ETDEWEB)

    Leonard Bond

    2006-07-01

    Laser Isotope Enrichment for Medical and Industrial Applications by Jeff Eerkens (University of Missouri), Jay Kunze (Idaho State University), and Leonard Bond (Idaho National Laboratory) The principal isotope enrichment business in the world is the enrichment of uranium for commercial power reactor fuels. However, there are a number of other needs for separated isotopes. Some examples are: 1) Pure isotopic targets for irradiation to produce medical radioisotopes. 2) Pure isotopes for semiconductors. 3) Low neutron capture isotopes for various uses in nuclear reactors. 4) Isotopes for industrial tracer/identification applications. Examples of interest to medicine are targets to produce radio-isotopes such as S-33, Mo-98, Mo-100, W-186, Sn-112; while for MRI diagnostics, the non-radioactive Xe-129 isotope is wanted. For super-semiconductor applications some desired industrial isotopes are Si-28, Ga-69, Ge-74, Se-80, Te-128, etc. An example of a low cross section isotope for use in reactors is Zn-68 as a corrosion inhibitor material in nuclear reactor primary systems. Neutron activation of Ar isotopes is of interest in industrial tracer and diagnostic applications (e.g. oil-logging). . In the past few years there has been a sufficient supply of isotopes in common demand, because of huge Russian stockpiles produced with old electromagnetic and centrifuge separators previously used for uranium enrichment. Production of specialized isotopes in the USA has been largely accomplished using old ”calutrons” (electromagnetic separators) at Oak Ridge National Laboratory. These methods of separating isotopes are rather energy inefficient. Use of lasers for isotope separation has been considered for many decades. None of the proposed methods have attained sufficient proof of principal status to be economically attractive to pursue commercially. Some of the authors have succeeded in separating sulfur isotopes using a rather new and different method, known as condensation

  11. On the atomic structure of liquid Ni-Si alloys: a neutron diffraction study

    Energy Technology Data Exchange (ETDEWEB)

    Gruner, S; Marczinke, J; Hoyer, W [Institute of Physics, Chemnitz University of Technology, D-09107 Chemnitz (Germany); Hennet, L [CNRS-CEMHTI, University of Orleans, F-45071 Orleans (France); Cuello, G J, E-mail: sascha.gruner@physik.tu-chemnitz.d [Institute Laue-Langevin, PO Box 156, F-38042 Grenoble (France)

    2009-09-23

    The atomic structure of the liquid NiSi and NiSi{sub 2} alloys is investigated by means of neutron diffraction experiments with isotopic substitution. From experimental data-sets obtained using four Ni isotopes, partial structure factors and pair correlation functions are obtained by applying a reverse Monte Carlo modelling approach. Both alloys were found to exhibit a strong tendency to hetero-coordination within the first coordination shell. In particular, covalent Si-Si bonds with somewhat greater distances seem to influence the structure of the liquid NiSi alloy.

  12. Silicon Isotopic Fractionation of CAI-like Vacuum Evaporation Residues

    Energy Technology Data Exchange (ETDEWEB)

    Knight, K; Kita, N; Mendybaev, R; Richter, F; Davis, A; Valley, J

    2009-06-18

    Calcium-, aluminum-rich inclusions (CAIs) are often enriched in the heavy isotopes of magnesium and silicon relative to bulk solar system materials. It is likely that these isotopic enrichments resulted from evaporative mass loss of magnesium and silicon from early solar system condensates while they were molten during one or more high-temperature reheating events. Quantitative interpretation of these enrichments requires laboratory determinations of the evaporation kinetics and associated isotopic fractionation effects for these elements. The experimental data for the kinetics of evaporation of magnesium and silicon and the evaporative isotopic fractionation of magnesium is reasonably complete for Type B CAI liquids (Richter et al., 2002, 2007a). However, the isotopic fractionation factor for silicon evaporating from such liquids has not been as extensively studied. Here we report new ion microprobe silicon isotopic measurements of residual glass from partial evaporation of Type B CAI liquids into vacuum. The silicon isotopic fractionation is reported as a kinetic fractionation factor, {alpha}{sub Si}, corresponding to the ratio of the silicon isotopic composition of the evaporation flux to that of the residual silicate liquid. For CAI-like melts, we find that {alpha}{sub Si} = 0.98985 {+-} 0.00044 (2{sigma}) for {sup 29}Si/{sup 28}Si with no resolvable variation with temperature over the temperature range of the experiments, 1600-1900 C. This value is different from what has been reported for evaporation of liquid Mg{sub 2}SiO{sub 4} (Davis et al., 1990) and of a melt with CI chondritic proportions of the major elements (Wang et al., 2001). There appears to be some compositional control on {alpha}{sub Si}, whereas no compositional effects have been reported for {alpha}{sub Mg}. We use the values of {alpha}Si and {alpha}Mg, to calculate the chemical compositions of the unevaporated precursors of a number of isotopically fractionated CAIs from CV chondrites whose

  13. Evaluation of CVI SiC/SiC Composites for High Temperature Applications

    Science.gov (United States)

    Kiser, D.; Almansour, A.; Smith, C.; Gorican, D.; Phillips, R.; Bhatt, R.; McCue, T.

    2017-01-01

    Silicon carbide fiber reinforced silicon carbide (SiC/SiC) composites are candidate materials for various high temperature turbine engine applications because of their high specific strength and good creep resistance at temperatures of 1400 C (2552 F) and higher. Chemical vapor infiltration (CVI) SiC/SiC ceramic matrix composites (CMC) incorporating Sylramic-iBN SiC fiber were evaluated via fast fracture tensile tests (acoustic emission damage characterization to assess cracking behavior), tensile creep testing, and microscopy. The results of this testing and observed material behavior degradation mechanisms are reviewed.

  14. Characterization of SiC-SiC composites for accident tolerant fuel cladding

    Science.gov (United States)

    Deck, C. P.; Jacobsen, G. M.; Sheeder, J.; Gutierrez, O.; Zhang, J.; Stone, J.; Khalifa, H. E.; Back, C. A.

    2015-11-01

    Silicon carbide (SiC) is being investigated for accident tolerant fuel cladding applications due to its high temperature strength, exceptional stability under irradiation, and reduced oxidation compared to Zircaloy under accident conditions. An engineered cladding design combining monolithic SiC and SiC-SiC composite layers could offer a tough, hermetic structure to provide improved performance and safety, with a failure rate comparable to current Zircaloy cladding. Modeling and design efforts require a thorough understanding of the properties and structure of SiC-based cladding. Furthermore, both fabrication and characterization of long, thin-walled SiC-SiC tubes to meet application requirements are challenging. In this work, mechanical and thermal properties of unirradiated, as-fabricated SiC-based cladding structures were measured, and permeability and dimensional control were assessed. In order to account for the tubular geometry of the cladding designs, development and modification of several characterization methods were required.

  15. Influence of liquid structure on diffusive isotope separation in molten silicates and aqueous solutions

    Science.gov (United States)

    Watkins, James M.; DePaolo, Donald J.; Ryerson, Frederick J.; Peterson, Brook T.

    2011-06-01

    Molecular diffusion in natural volcanic liquids discriminates between isotopes of major ions (e.g., Fe, Mg, Ca, and Li). Although isotope separation by diffusion is expected on theoretical grounds, the dependence on mass is highly variable for different elements and in different media. Silicate liquid diffusion experiments using simple liquid compositions were carried out to further probe the compositional dependence of diffusive isotopic discrimination and its relationship to liquid structure. Two diffusion couples consisting of the mineral constituents anorthite (CaAl 2Si 2O 8; denoted AN), albite (NaAlSi 3O 8; denoted AB), and diopside (CaMgSi 2O 6; denoted DI) were held at 1450 °C for 2 h and then quenched to ambient pressure and temperature. Major-element as well as Ca and Mg isotope profiles were measured on the recovered quenched glasses. In both experiments, Ca diffuses rapidly with respect to Si. In the AB-AN experiment, D Ca/ D Si ≈ 20 and the efficiency of isotope separation for Ca is much greater than in natural liquid experiments where D Ca/ D Si ≈ 1. In the AB-DI experiment, D Ca/ D Si ≈ 6 and the efficiency of isotope separation is between that of the natural liquid experiments and the AB-AN experiment. In the AB-DI experiment, D Mg/ D Si ≈ 1 and the efficiency of isotope separation for Mg is smaller than it is for Ca yet similar to that observed for Mg in natural liquids. The results from the experiments reported here, in combination with results from natural volcanic liquids, show clearly that the efficiency of diffusive separation of Ca isotopes is systematically related to the solvent-normalized diffusivity - the ratio of the diffusivity of the cation ( D Ca) to the diffusivity of silicon ( D Si). The results on Ca isotopes are consistent with available data on Fe, Li, and Mg isotopes in silicate liquids, when considered in terms of the parameter D cation/ D Si. Cations diffusing in aqueous solutions display a similar relationship

  16. 40 CFR 60.4231 - What emission standards must I meet if I am a manufacturer of stationary SI internal combustion...

    Science.gov (United States)

    2010-07-01

    ... SI engines in 40 CFR part 90 or 1054, as follows: If engine replacement is . . . and manufacturing... part 90. (4) at or above 225 cc January 1, 2011 or later 40 CFR part 1054. (b) Stationary SI internal... standards and other requirements for new nonroad SI engines in 40 CFR part 1048. Stationary SI...

  17. Advanced Environmental Barrier Coatings Developed for SiC/SiC Composite Vanes

    Science.gov (United States)

    Lee, Kang N.; Fox, Dennis S.; Eldridge, Jeffrey I.; Zhu, Dongming; Bansal, Narottam P.; Miller, Robert A.

    2003-01-01

    Ceramic components exhibit superior high-temperature strength and durability over conventional component materials in use today, signifying the potential to revolutionize gas turbine engine component technology. Silicon-carbide fiber-reinforced silicon carbide ceramic matrix composites (SiC/SiC CMCs) are prime candidates for the ceramic hotsection components of next-generation gas turbine engines. A key barrier to the realization of SiC/SiC CMC hot-section components is the environmental degradation of SiC/SiC CMCs in combustion environments. This is in the form of surface recession due to the volatilization of silica scale by water vapor. An external environmental barrier coating (EBC) is a logical approach to achieve protection and long-term durability.

  18. Creep Behavior of Hafnia and Ytterbium Silicate Environmental Barrier Coating Systems on SiC/SiC Ceramic Matrix Composites

    Science.gov (United States)

    Zhu, Dongming; Fox, Dennis S.; Ghosn, Louis J.; Harder, Bryan

    2011-01-01

    Environmental barrier coatings will play a crucial role in future advanced gas turbine engines because of their ability to significantly extend the temperature capability and stability of SiC/SiC ceramic matrix composite (CMC) engine components, thus improving the engine performance. In order to develop high performance, robust coating systems for engine components, appropriate test approaches simulating operating temperature gradient and stress environments for evaluating the critical coating properties must be established. In this paper, thermal gradient mechanical testing approaches for evaluating creep and fatigue behavior of environmental barrier coated SiC/SiC CMC systems will be described. The creep and fatigue behavior of Hafnia and ytterbium silicate environmental barrier coatings on SiC/SiC CMC systems will be reported in simulated environmental exposure conditions. The coating failure mechanisms will also be discussed under the heat flux and stress conditions.

  19. METHOD OF ISOTOPE CONCENTRATION

    Science.gov (United States)

    Spevack, J.S.

    1957-04-01

    An isotope concentration process is described which consists of exchanging, at two or more different temperature stages, two isotopes of an element between substances that are physically separate from each other and each of which is capable of containing either of the isotopes, and withdrawing from a point between at least two of the temperatare stages one of the substances containing an increased concentration of the desired isotope.

  20. Molybdenum isotopic composition of single silicon carbides from supernovae.

    Energy Technology Data Exchange (ETDEWEB)

    Amari, S.; Clayton, R. N.; Davis, A. M.; Lewis, R. S.; Pellin, M. J.

    1999-02-03

    Presolar silicon carbide grains form in a variety of types of stars, including asymptotic giant branch red giant stars and supernovae. The dominant mechanisms of heavy element nucleosynthesis, the s-process and r-process, are thought to occur in AGB stars and supernovae, respectively. We have previously reported that mainstream SiC grains have strong enrichments in the s-process isotopes of Sr, Zr and Mo. We report here the first measurements of Mo isotopes in X-type SiC grains, which have previously been identified as having formed from supernova ejecta.

  1. Landscape cultivation alters δ30Si signature in terrestrial ecosystems

    Science.gov (United States)

    Vandevenne, Floor; Delvaux, Claire; Hughes, Harold; Ronchi, Benedicta; Clymans, Wim; Barao, Ana Lucia; Govers, Gerard; Cornelis, Jean Thomas; André, Luc; Struyf, Eric

    2015-04-01

    Despite increasing recognition of the importance of biological Si cycling in controlling dissolved Si (DSi) in soil and stream water, effects of human cultivation on the Si cycle remain poorly understood. Sensitive tracer techniques to identify and quantify Si in the soil-plant-water system could be highly relevant in addressing these uncertainties. Stable Si isotopes are promising tools to define Si sources and sinks along the ecosystem flow path, as intense fractionation occurs during chemical weathering and uptake of dissolved Si in plants. Yet they remain underexploited in the end product of the soil-plant system: the soil water. Here, stable Si isotope ratios (δ30Si) of dissolved Si in soil water were measured along a land use gradient (continuous forest, continuous pasture, young cropland and continuous cropland) with similar parent material (loess) and homogenous bulk mineralogical and climatological (Belgium). Soil water δ30Si signatures are clearly separated along the gradient, with highest average signatures in continuous cropland (+1.61%), intermediate in pasture (+1.05%) and young cropland (+0.89%) and lowest in forest soil water (+0.62%). Our data do not allow distinguishing biological from pedogenic/lithogenic processes, but point to a strong interaction of both. We expect that increasing export of light isotopes in disturbed land uses (i.e. through agricultural harvest), and higher recycling of 28Si and elevated weathering intensity (including clay dissolution) in forest systems will largely determine soil water δ30Si signatures of our systems. Our results imply that soil water δ30Si signature is biased through land management before it reaches rivers and coastal zones, where other fractionation processes take over (e.g. diatom uptake and reverse weathering in floodplains). In particular, a direct role of agriculture systems in lowering export Si fluxes towards rivers and coastal systems has been shown. Stable Si isotopes have a large potential

  2. Effects of Exhaust Pipe Heat Insulation on Unregulated Emissions from Gasohol Fueled SI Engine%醇类燃料发动机排气管保温降低醇醛排放研究

    Institute of Scientific and Technical Information of China (English)

    刘方杰; 苗家轩; 刘圣华; 魏衍举; 徐斌; 吴健

    2014-01-01

    The effects of exhaust pipe insulation on unregulated emissions of a spark ignition (SI) engine fueled with M10 (10% of methanol in blend by volume) and E10 (10% of ethanol in blend by volume) blends respectively were experimentally investigated with gas chromatography (equipped with a pulsed discharge helium ionization detector,PDHID).Experimental results show that methanol and ethanol emissions decreased after exhaust pipe heat insulation.After exhaust pipe heat insulation designed,aldehyde emissions did not change obviously at low engine load conditions (Tc < 850 K),but aldehyde emissions decreased significantly at middle-high engine load conditions (Tc ≥ 850 K),and the decreasing range of unregulated emissions increased with exhaust temperature rising.It is conducive to the oxidation of unregulated emissions with prolonging the reaction time of unregulated emissions in high temperature environment after exhaust pipe heat insulation designed.Unregulated emissions decreased significantly with exhaust pipe heat insulation when the exhaust temperature (Tc) was higher than about 900 K.Exhaust temperature and reaction time had a greater influence on the oxidation of alcohol and aldehyde emissions.%通过对发动机排气管隔热保温,在JL368Q3型电喷汽油机上开展了醇类燃料发动机排气管保温降低醇醛排放的研究,采用气相色谱-氦离子化检测器(PDHID)快速检测方法检测发动机的醇醛排放.结果表明:与排气管保温前相比,排气管保温后醇排放降低,低负荷工况下(Tc <850 K)醛排放变化不大,中高负荷工况下(Tc≥850 K)醛排放降低,醇醛排放降幅随排气温度升高而变大.排气管保温延长了排气在高温下的反应时间,有利于未燃醇、醛的快速氧化,转速为4 000 r/min、负荷高于21 N·m时(Tc≥900 K),排气管保温后未燃醇、醛排放降低70%以上.排气温度和高温下的氧化反应时间对醇醛的氧化影响较大.

  3. Statistical clumped isotope signatures

    NARCIS (Netherlands)

    Röckmann, T.; Popa, M. E.; Krol, M. C.; Hofmann, M. E. G.

    2016-01-01

    High precision measurements of molecules containing more than one heavy isotope may provide novel constraints on element cycles in nature. These so-called clumped isotope signatures are reported relative to the random (stochastic) distribution of heavy isotopes over all available isotopocules of a m

  4. Reduced thermal conductivity of isotopically modulated silicon multilayer structures

    DEFF Research Database (Denmark)

    Bracht, H.; Wehmeier, N.; Eon, S.;

    2012-01-01

    We report measurements of the thermal conductivity of isotopically modulated silicon that consists of alternating layers of highly enriched silicon-28 and silicon-29. A reduced thermal conductivity of the isotopically modulated silicon compared to natural silicon was measured by means of time......-resolved x-ray scattering. Comparison of the experimental results to numerical solutions of the corresponding heat diffusion equations reveals a factor of three lower thermal conductivity of the isotope structure compared to natural Si. Our results demonstrate that the thermal conductivity of silicon can...

  5. Study of gas (CNG) SI engine with pre-chamber. Improvement of the indicated thermal efficiency on lean mixture with EGR and supercharging; Fukushitsushiki hibana tenka asshuku tennen gas (CNG) engine ni kansuru kenkyu. Kakyu to EGR ni yoru kihakuiki no netsukoritsu kaizen

    Energy Technology Data Exchange (ETDEWEB)

    Yonetani, H.; Fukutani, I. [Polytechnic University, Kanagawa (Japan)

    1998-10-15

    As lean burn of compressed natural gas (CNG) is applied to conventional gasoline engines, a combustion period largely increases, resulting in large combustion fluctuation and low thermal efficiency. Heterogeneous spacial air/fuel ratios also have an effect on combustion in lean burn area. By preparing a pre-chamber for a combustion chamber of high- compression ratio CNG pre-mixing SI engines to utilize premixture turbulence, rapid flame propagation is obtained in lean burn area, resulting high combustion performance. Furthermore, study was made on improvement of combustion performance in lean burn area under various compression ratios, intake pressures, pre-chamber shapes and EGR ratios. As a result, lean burn operation at high intake pressure by supercharging showed possible improvement of a thermal efficiency and expansion of inflammable limits. Higher thermal efficiency in lean burn area was also obtained by using higher compression ratios considering heat loss. Although EGR was effective in controlling NOx formed in lean burn area, strict control of both air excess rate and EGR rate was required to prevent lower thermal efficiency. 2 refs., 8 figs., 1 tab.

  6. Generation of Radixenon Isotopes

    Energy Technology Data Exchange (ETDEWEB)

    McIntyre, Justin I.; Bowyer, Ted W.; Hayes, James C.; Heimbigner, Tom R.; Morris, Scott J.; Panisko, Mark E.; Pitts, W. K.; Pratt, Sharon L.; Reeder, Paul L.; Thomas, Charles W.

    2003-06-30

    Pacific Northwest National Laboratory has developed an automated system for separating Xe from air and can detect the following radioxenon isotopes, 131mXe, 133mXe, 133Xe, and 135Xe. This report details the techniques used to generate the various radioxenon isotopes that are used for the calibration of the detector as well as other isotopes that have the potential to interfere with the fission produced radioxenon isotopes. Fission production is covered first using highly enriched uranium followed by a description and results from an experiment to produce radioxenon isotopes from neutron activation of ambient xenon.

  7. Isotopes in heterogeneous catalysis

    CERN Document Server

    Hargreaves, Justin SJ

    2006-01-01

    The purpose of this book is to review the current, state-of-the-art application of isotopic methods to the field of heterogeneous catalysis. Isotopic studies are arguably the ultimate technique in in situ methods for heterogeneous catalysis. In this review volume, chapters have been contributed by experts in the field and the coverage includes both the application of specific isotopes - Deuterium, Tritium, Carbon-14, Sulfur-35 and Oxygen-18 - as well as isotopic techniques - determination of surface mobility, steady state transient isotope kinetic analysis, and positron emission profiling.

  8. Silica cycling and isotopic composition in northern Marguerite Bay on the rapidly-warming western Antarctic Peninsula

    Science.gov (United States)

    Annett, Amber L.; Henley, Sian F.; Venables, Hugh J.; Meredith, Michael P.; Clarke, Andrew; Ganeshram, Raja S.

    2017-05-01

    The Southern Ocean is a key region for silica (Si) cycling, and the isotopic signatures established here influence the rest of the world's oceans. The climate and ecosystem of the Southern Ocean are changing rapidly, with the potential to impact Si cycling and isotope dynamics. This study examines high-resolution time-series dataset of dissolved Si concentrations and isotopic signatures, particulate Si concentrations and diatom speciation at a coastal site on the western Antarctic Peninsula (WAP), in order to characterise changes in Si cycling with respect to changes occurring in productivity and diatom assemblages. Dissolved and particulate Si phases reflect the dominant control of biological uptake, and combined with isotopic fractionation were consistent with a season of low/intermediate productivity. Biogenic Si is tightly coupled to both chlorophyll and particulate organic carbon at the sampling site, consistent with diatom-dominated phytoplankton assemblages along the WAP. Variability in diatom speciation has a negligible impact on the isotopic signature of dissolved Si in surface waters, although this is unlikely to hold for sediments due to differential dissolution of diatom species. A continued decline in diatom productivity along the WAP would likely result in an increasing unused Si inventory, which can potentially feed back into Si-limited areas, promoting diatom growth and carbon drawdown further afield.

  9. Photoluminescence of isotopically purified silicon: how sharp are bound exciton transitions?

    Science.gov (United States)

    Karaiskaj, D; Thewalt, M L; Ruf, T; Cardona, M; Pohl, H J; Deviatych, G G; Sennikov, P G; Riemann, H

    2001-06-25

    We report the first high resolution photoluminescence studies of isotopically pure Si (99.896% (28)Si). New information is obtained on isotopic effects on the indirect band gap energy, phonon energies, and phonon broadenings, which is in good agreement with calculations and previous results obtained in Ge and diamond. Remarkably, the linewidths of the no-phonon boron and phosphorus bound exciton transitions in the (28)Si sample are much narrower than in natural Si and are not well resolved at our maximum instrumental resolution of approximately 0.014 cm(-1). The removal of the dominant broadening resulting from isotopic randomness in natural Si reveals new fine structure in the boron bound exciton luminescence.

  10. Driving and engine cycles

    CERN Document Server

    Giakoumis, Evangelos G

    2017-01-01

    This book presents in detail the most important driving and engine cycles used for the certification and testing of new vehicles and engines around the world. It covers chassis and engine-dynamometer cycles for passenger cars, light-duty vans, heavy-duty engines, non-road engines and motorcycles, offering detailed historical information and critical review. The book also provides detailed examples from SI and diesel engines and vehicles operating during various cycles, with a focus on how the engine behaves during transients and how this is reflected in emitted pollutants, CO2 and after-treatment systems operation. It describes the measurement methods for the testing of new vehicles and essential information on the procedure for creating a driving cycle. Lastly, it presents detailed technical specifications on the most important chassis-dynamometer cycles around the world, together with a direct comparison of those cycles.

  11. Advanced Environmental Barrier Coatings Development for Si-Based Ceramics

    Science.gov (United States)

    Zhu, Dong-Ming; Choi, R. Sung; Robinson, Raymond C.; Lee, Kang N.; Bhatt, Ramakrishna T.; Miller, Robert A.

    2005-01-01

    Advanced environmental barrier coating concepts based on multi-component HfO2 (ZrO2) and modified mullite systems are developed for monolithic Si3N4 and SiC/SiC ceramic matrix composite (CMC) applications. Comprehensive testing approaches were established using the water vapor cyclic furnace, high pressure burner rig and laser heat flux steam rig to evaluate the coating water vapor stability, cyclic durability, radiation and erosion resistance under simulated engine environments. Test results demonstrated the feasibility and durability of the environmental barrier coating systems for 2700 to 3000 F monolithic Si3N4 and SiC/SiC CMC component applications. The high-temperature-capable environmental barrier coating systems are being further developed and optimized in collaboration with engine companies for advanced turbine engine applications.

  12. Variations of δ 30Si and Ge/Si with weathering and biogenic input in tropical basaltic ash soils under monoculture

    Science.gov (United States)

    Opfergelt, S.; Cardinal, D.; André, L.; Delvigne, C.; Bremond, L.; Delvaux, B.

    2010-01-01

    In soils, silicon released by mineral weathering can be retrieved from soil solution through clay formation, Si adsorption onto secondary oxides and plant uptake, thereby impacting the Si-isotopic signature and Ge/Si ratio of dissolved Si (DSi) exported to rivers. Here we use these proxies to study the contribution of biogenic Si (BSi) in a soil-plant system involving basaltic ash soils differing in weathering degree under intensive banana cropping. δ 30Si and Ge/Si ratios were determined in bulk soils (banana phytoliths and a stable phytolith pool from previous forested vegetation. δ 30Si and Ge/Si values of clay fractions in poorly developed volcanic soils, isotopically heavier and Ge-depleted in surface horizons, support the occurrence of a DSi source from banana phytolith dissolution, available for Si sequestration in clay-sized secondary minerals (clay minerals formation and Si adsorption onto Fe-oxide). In the soil-plant system, δ 30Si and Ge/Si are thus highly relevant to trace weathering and input of DSi from phytoliths in secondary minerals, although not quantifying the net input of BSi to DSi.

  13. Current Status and Recent Research Achievements in SiC/SiC Composites

    Energy Technology Data Exchange (ETDEWEB)

    Katoh, Yutai; Snead, Lance L.; Henager, Charles H.; Nozawa, T.; Hinoki, Tetsuya; Ivekovic, Aljaz; Novak, Sasa; Gonzalez de Vicente, Sehila M.

    2014-12-01

    The development and maturation of the silicon carbide fiber-reinforced silicon carbide matrix (SiC/SiC) composite system for fusion applications has seen the evolution from fundamental development and understanding of the material system and its behavior in a hostile irradiation environment to the current effort which essentially is a broad-based program of technology, directed at moving this material class from a laboratory curiosity to an engineering material. This paper lays out the recent international scientific and technological achievements in the development of SiC/SiC composite material technologies for fusion application and will discuss future research directions. It also reviews the materials system in the larger context of progress to maturity as an engineering material for both the larger nuclear community and for general engineering applications.

  14. Current status and recent research achievements in SiC/SiC composites

    Energy Technology Data Exchange (ETDEWEB)

    Katoh, Y., E-mail: katohy@ornl.gov [Oak Ridge National Laboratory, Oak Ridge, TN (United States); Snead, L.L. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); Henager, C.H. [Pacific Northwest National Laboratory, Richland, WA (United States); Nozawa, T. [Japan Atomic Energy Agency, Rokkasho, Aomori (Japan); Hinoki, T. [Institute of Advanced Energy, Kyoto University, Kyoto (Japan); Iveković, A.; Novak, S. [Jožef Stefan Institute, Ljubljana (Slovenia); Gonzalez de Vicente, S.M. [EFDA Close Support Unit, Garching (Germany)

    2014-12-15

    The silicon carbide fiber-reinforced silicon carbide matrix (SiC/SiC) composite system for fusion applications has seen a continual evolution from development a fundamental understanding of the material system and its behavior in a hostile irradiation environment to the current effort which is directed at a broad-based program of technology maturation program. In essence, over the past few decades this material system has steadily moved from a laboratory curiosity to an engineering material, both for fusion structural applications and other high performance application such as aerospace. This paper outlines the recent international scientific and technological achievements towards the development of SiC/SiC composite material technologies for fusion application and discusses future research directions. It also reviews the materials system in the larger context of progress to maturity as an engineering material for both the larger nuclear community and broader engineering applications.

  15. Effect of Adventitious Carbon on the Environmental Degradation of SiC/BN/SiC Composites

    Science.gov (United States)

    Ogbuji, L. U. J. T.; Yun, H. M.; DiCarlo, J.

    2002-01-01

    Pesting remains a major obstacle to the application of SiC/SiC composites in engine service and selective degradation of the boron nitride interphase at intermediate temperatures is of primary concern. However, significant progress has been made on interphase improvement recently and we now know more about the phenomenon and ways to suppress it. By screening SiC/BN/SiC materials through characterization of strength and microstructures after exposure in a burner rig, some factors that control pesting in these composites have been determined. A key precaution is careful control of elemental carbon presence in the interphase region.

  16. 40 CFR 60.4238 - What are my compliance requirements if I am a manufacturer of stationary SI internal combustion...

    Science.gov (United States)

    2010-07-01

    ... I am a manufacturer of stationary SI internal combustion engines â¤19 KW (25 HP) or a manufacturer... Standards of Performance for Stationary Spark Ignition Internal Combustion Engines Compliance Requirements... SI internal combustion engines ≤19 KW (25 HP) or a manufacturer of equipment containing such engines...

  17. Oxygen Isotopes and Origin of Opal in an Antarctic Ureilite

    Science.gov (United States)

    Downes, H.; Beard, A. D.; Franchi, I. A.; Greenwood, R. C.

    2016-08-01

    Fragments of opal (SiO2.nH2O) in several internal chips of a single Antarctic polymict ureilite meteorite Elephant Moraine (EET) 83309 have been studied by NanoSIMS to determine their oxygen isotope compositions and hence constrain their origin.

  18. Problems in event based engine control

    DEFF Research Database (Denmark)

    Hendricks, Elbert; Jensen, Michael; Chevalier, Alain Marie Roger

    1994-01-01

    Physically a four cycle spark ignition engine operates on the basis of four engine processes or events: intake, compression, ignition (or expansion) and exhaust. These events each occupy approximately 180° of crank angle. In conventional engine controllers, it is an accepted practice to sample...... the engine variables synchronously with these events (or submultiples of them). Such engine controllers are often called event-based systems. Unfortunately the main system noise (or disturbance) is also synchronous with the engine events: the engine pumping fluctuations. Since many electronic engine...... problems on accurate air/fuel ratio control of a spark ignition (SI) engine....

  19. Si/SiGe MMIC's

    Science.gov (United States)

    Luy, Johann-Friedrich; Strohm, Karl M.; Sasse, Hans-Eckard; Schueppen, Andreas; Buechler, Josef; Wollitzer, Michael; Gruhle, Andreas; Schaeffler, Friedrich; Guettich, Ulrich; Klaassen, Andreas

    1995-04-01

    Silicon-based millimeter-wave integrated circuits (SIMMWIC's) can provide new solutions for near range sensor and communication applications in the frequency range above 50 GHz. This paper gives a survey on the state-of-the-art performance of this technology and on first applications. The key devices are IMPATT diodes for mm-wave power generation and detection in the self-oscillating mixer mode, p-i-n diodes for use in switches and phase shifters, and Schottky diodes in detector and mixer circuits. The silicon/silicon germanium heterobipolar transistor (SiGe HBT) with f(sub max) values of more than 90 GHz is now used for low-noise oscillators at Ka-band frequencies. First system applications are discussed.

  20. Silicon Isotopic Fractionation in a Tropical Soil-Plant System

    Science.gov (United States)

    Opfergelt, S.; Delstanche, S.; Cardinal, D.; Andre, L.; Delvaux, B.

    2006-12-01

    Silica fluxes to soil solutions and water streams are controlled by both abiotic and biotic processes occurring in a Si soil-plant cycle that can be significant in comparison with Si weathering input and hydrological output. The quantification of Si-isotopic fractionation by these processes is highly promising to study the Si soil-plant cycle. Therein, the fate of aqueous monosilicic acid H4SiO4, as produced by silicate weathering, may take four paths: (1) uptake by plants and recycling through falling litter, (2) formation of clay minerals, (3) specific adsorption onto Al and Fe oxides, (4) leaching in drainage waters and export from watersheds. Here we report on detailed Si-isotopic compositions of various Si pools in a tropical soil-plant system involving old stands of banana (Musa acuminata Colla, cv Grande Naine) cropped on a weathering sequence of soils derived from andesitic volcanic ash and pumice deposits in Cameroon, West Africa. Si-isotopic compositions were measured by MC-ICP-MS in dry plasma mode with external Mg doping with a reproducibility of 0.08 permil (2stdev). Results were expressed as delta29Si vs NBS28. The compositions were determined in plant parts, bulk soils, clay fractions (less than 2um) and stream waters used for crop irrigation. Of the weathering sequence, we selected young (Y) and old (O) volcanic soils (vs). Yvs are rich in weatherable minerals, and contain large amounts of pumice gravels; their clay fraction (10-35 percent) contains allophane, halloysite and ferrihydrite. Oppositely, Ovs are strongly weathered and fine clayey soils (75-96 percent clay) rich in halloysite, kaolinite, gibbsite and goethite. Intra-plant fractionation between roots and shoots and within shoots confirmed our previous data measured on banana plants grown in hydroponics. The bulk plant isotopic composition was heavier at Ovs than at Yvs giving a fractionation factor per atomic mass unit between plants and their irrigation water Si source (+0.61 permil) of

  1. Discovery of the Cobalt Isotopes

    OpenAIRE

    Szymanski, T.; Thoennessen, M.

    2009-01-01

    Twenty-six cobalt isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  2. Discovery of the Arsenic Isotopes

    CERN Document Server

    Shore, A; Heim, M; Schuh, A; Thoennessen, M

    2009-01-01

    Twenty-nine arsenic isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  3. Myths of Isotopic Reference Materials Busted

    Science.gov (United States)

    Coplen, T.

    2007-12-01

    During the past several years, the determination of the isotopic abundances of elements including H, Li, B, C, N, O, Mg, Si, S, Cl, Ca, Cr, Fe, Cu, Zn, Tl, and Se has substantially increased because of expanded use in hydrology, environmental studies, microbiology, forensic investigations, atmospheric investigations, oceanography, etc. Improvements in instrumentation enable increasingly precise isotope-amount-ratio measurements in these fields, but these improvements in precision commonly do not lead to improvements in accuracy because of the lack or improper use of isotopic reference materials. When properly used, these critically important materials enable any laboratory worldwide to measure the same homogeneous sample and report the same isotopic abundance within analytical uncertainty. For example, for stable isotopic analysis of gaseous hydrogen samples, the agreement among 36 laboratories worldwide before normalization to any hydrogen gas reference material was 11.8 per mill. After normalization to anchors (gaseous H isotopic reference materials) at each end of the delta H-2 scale, the agreement was 0.85 per mill, an improvement of more than an order of magnitude. Consistency of delta C-13 measurements often can be improved by nearly 50 percent by anchoring the delta C-13 scale with two isotopic reference materials differing substantially in C-13 mole fraction, namely NBS 19 calcite and L-SVEC lithium carbonate. Agreement of delta C-13 values of four expert laboratories analyzing USGS40 L- glutamic acid by CF-IRMS methods improved from 0.084 to 0.015 per mill with use of the two scale anchors (NBS 19 and L-SVEC). Solid oxygen isotopic reference materials (IAEA-600 caffeine, IAEA-601 and IAEA-602 benzoic acids, IAEA-NO-3, USGS32, USGS34, and USGS35 nitrates, NBS-127, IAEA-SO-5, and IAEA-SO-6 barium sulfates) are poorly calibrated. Calibrating these solids to the VSMOW-SLAP reference water scale has been very difficult because both the solids and reference

  4. Intracellular Cadmium Isotope Fractionation

    Science.gov (United States)

    Horner, T. J.; Lee, R. B.; Henderson, G. M.; Rickaby, R. E.

    2011-12-01

    Recent stable isotope studies into the biological utilization of transition metals (e.g. Cu, Fe, Zn, Cd) suggest several stepwise cellular processes can fractionate isotopes in both culture and nature. However, the determination of fractionation factors is often unsatisfactory, as significant variability can exist - even between different organisms with the same cellular functions. Thus, it has not been possible to adequately understand the source and mechanisms of metal isotopic fractionation. In order to address this problem, we investigated the biological fractionation of Cd isotopes within genetically-modified bacteria (E. coli). There is currently only one known biological use or requirement of Cd, a Cd/Zn carbonic anhydrase (CdCA, from the marine diatom T. weissfloggii), which we introduce into the E. coli genome. We have also developed a cleaning procedure that allows for the treating of bacteria so as to study the isotopic composition of different cellular components. We find that whole cells always exhibit a preference for uptake of the lighter isotopes of Cd. Notably, whole cells appear to have a similar Cd isotopic composition regardless of the expression of CdCA within the E. coli. However, isotopic fractionation can occur within the genetically modified E. coli during Cd use, such that Cd bound in CdCA can display a distinct isotopic composition compared to the cell as a whole. Thus, the externally observed fractionation is independent of the internal uses of Cd, with the largest Cd isotope fractionation occurring during cross-membrane transport. A general implication of these experiments is that trace metal isotopic fractionation most likely reflects metal transport into biological cells (either actively or passively), rather than relating to expression of specific physiological function and genetic expression of different metalloenzymes.

  5. SiC/Si{sub 3}N{sub 4} nanotubes from peanut shells

    Energy Technology Data Exchange (ETDEWEB)

    Qadri, S. B.; Rath, B. B.; Gorzkowski, E. P.; Feng, C.R. [Materials Science and Component Technology Directorate, Naval Research Laboratory, Washington D.C., 20375 (United States)

    2016-06-15

    Nanotubes and nanoparticles of SiC and Si{sub 3}N{sub 4} were produced from the thermal treatment of peanut shells in argon and nitrogen atmospheres respectively, at temperatures in excess of 1350°C. Using x-ray diffraction, Raman spectroscopy and transmission electron microscopy analysis, the processed samples in argon atmosphere were shown to consist of 2H and 3C polytypes of SiC nanoparticles and nanotubes. Whereas the samples prepared in nitrogen atmosphere consisted of α-phase of Si{sub 3}N{sub 4}. Nanostructures formed by a single direct reaction provide a sustainable synthesis route for nanostructured SiC and Si{sub 3}N{sub 4}, for potential engineering applications due to their exceptional mechanical and electro-optic properties.

  6. Study on the Effect of the Separating Unit Optimization on the Economy of Stable Isotope Separation

    Directory of Open Access Journals (Sweden)

    YANG Kun

    2015-01-01

    Full Text Available An economic criterion called as yearly net profit of single separating unit (YNPSSU was presented to evaluate the influence of structure optimization on the economy. Using YNPSSU as a criterion, economic analysis was carried out for the structure optimization of separating unit in the case of separating SiF4 to obtain the 28Si and 29Si isotope. YNPSSU was calculated and compared with that before optimization. The results showed that YNPSSU was increased by 12.3% by the structure optimization. Therefore, the structure optimization could increase the economy of the stable isotope separation effectively.

  7. Delivery of completed irradiation vehicles and the quality assurance document to the High Flux Isotope Reactor for irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Petrie, Christian M. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); McDuffee, Joel Lee [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Katoh, Yutai [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Terrani, Kurt A. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

    2015-10-01

    This report details the initial fabrication and delivery of two Fuel Cycle Research and Development (FCRD) irradiation capsules (ATFSC01 and ATFSC02), with associated quality assurance documentation, to the High Flux Isotope Reactor (HFIR). The capsules and documentation were delivered by September 30, 2015, thus meeting the deadline for milestone M3FT-15OR0202268. These irradiation experiments are testing silicon carbide composite tubes in order to obtain experimental validation of thermo-mechanical models of stress states in SiC cladding irradiated under a prototypic high heat flux. This document contains a copy of the completed capsule fabrication request sheets, which detail all constituent components, pertinent drawings, etc., along with a detailed summary of the capsule assembly process performed by the Thermal Hydraulics and Irradiation Engineering Group (THIEG) in the Reactor and Nuclear Systems Division (RNSD). A complete fabrication package record is maintained by the THIEG and is available upon request.

  8. Silicon and oxygen isotopic trends in Mesozoic radiolarites

    Science.gov (United States)

    Bôle, Maximlien; Baumgartner Peter, O.; Lukas, Baumgartner; Anne-Sophie, Bouvier; Rie, Hori; Masayuki, Ikeda

    2016-04-01

    Silicon and oxygen isotopes (δ30Si and δ18O) of siliceous tests (diatoms, sponges and radiolarians) preserve environmental signatures in unconsolidated sediments, but few studies show such signatures for ancient biosilicieous rocks. In Precambrian cherts from greenstone belts, small scaled isotopic variations were interpreted as a primary diagenetic feature. They were used, coupled to mean δ18O, to reconstruct seawater temperature at which cherts precipitated. Here, we examine stable isotopes in Mesozoic biogenic cherts that may also preserve an environmental signature. We measured δ30Si and δ18O in situ by SIMS, in the chalcedony of individual radiolarian tests preserved in Mesozoic radiolarites. Microanalysis of chalcedony, rather than the bulk rock isotopic composition, is likely to reveal a palaeoenvironmental signal, since it is derived from biogenic opal, the most mobile silica phase during earliest diagenesis. Our data reveal clear trends through several Mesozoic radiolarite sections from Panthalassa (Kiso River, Japan) and Western Tethys (Sogno, Italy). δ18O records measured in radiolarites show a relatively good correlation to δ18O-variations of Mesozoic low magnesium calcite shells, which are commonly used as a palaeotemperature proxy. Once these variations, attributed to seawater temperature, are removed, the residual δ18O trends are opposite to the δ30Si trends. δ30Si increases from Middle Triassic to Early Jurassic in the Kiso River sections and decrease during the Middle Jurassic in the Sogno section. The observed d30Si-trends are likely to represent a palaeoenvironmental signal, because they are not compatible with simple models of progressive diagenesis along P/T-paths (or depth below sea bottom in drill holes). Among the palaeoenvironmental factors that may have influenced these trends are the oceanic silica cycle changing though time, oceanic circulation and/or the palaeogeographic location of each studied site. Siliceous organisms are

  9. 与Si工艺兼容的Si/SiGe/Si HBT研究%The Study of Si/SiGe/Si HBT and Its Compatibility with Si Process

    Institute of Scientific and Technical Information of China (English)

    廖小平

    2001-01-01

    我们对Si/SiGe/Si HBT及其Si兼容工艺进行了研究,在研究了一些关键的单项工艺的基础上,提出了五个高速Si/SiGe/Si HBT结构和一个低噪声Si/SiGe/Si HBT结构,并已研制成功台面结构Si/SiGe/Si HBT和低噪声Si/SiGe/Si HBT,为进一步高指标的Si/SiGe/Si HBT的研究建立了基础.

  10. Chromium isotope variations

    DEFF Research Database (Denmark)

    D'Arcy, Joan Mary

    is incorporated into carbonates. Hence, ancient carbonates can potentially record the Cr isotopic composition (δ53Cr ‰) of seawater in the geological past. Reliable application and interpretation of this proxy requires a detailed knowledge about processes that fractionate Cr on the Earth’s surface...... deposited during the Early Ordovician — a time of known redox instability in ancient oceans – exhibit a significant positive Cr isotope excursion of +0.5‰. This excursion is interpreted as the reductive drawn down of dissolved Cr in seawater in response to the development of a proximal anoxic sink......, and the quantification the Cr isotope composition of major Cr fluxes into and out of ocean. This thesis adds to the current knowledge of the Cr isotope system and is divided into two studies. The focus of the first study was to determine what processes control the Cr isotopic compositionof river water and to quantify...

  11. Isotopes in Greenland Precipitation

    DEFF Research Database (Denmark)

    Faber, Anne-Katrine

    Greenland ice cores offer a unique opportunity to investigate the climate system behaviour. The objective of this PhD project is to investigate isotope modelling of present- day conditions and conduct model-data comparison using Greenland ice cores. Thus this thesis investigates how the integration...... of model and data can be used to improve the understanding of climate changes. This is done through analysis of isotope modelling, observations and ice core measurements. This dissertation comprises three projects: (1) Modelling the isotopic response to changes in Arctic sea surface conditions, (2......) Constructing a new Greenland database of observations and present-day ice core measurements, and (3) Performance test of isotope-enabled CAM5 for Greenland. The recent decades of rapid Arctic sea ice decline are used as a basis for an observational-based model experiment using the isotope-enabled CAM model 3...

  12. Species-dependent silicon isotope fractionation in unialgal cultures of marine diatoms

    Science.gov (United States)

    Sutton, J. N.; Varela, D. E.; Brzezinski, M. A.; Beucher, C.

    2011-12-01

    Variations in the natural abundance of stable isotopes of silicon (expressed as δ30Si in %) are a key tool for studying the marine silicon (Si) cycle in modern and ancient oceans. In particular, this tool can be used to track relative differences in silicic acid drawdown in surface waters by siliceous microplankton. Diatoms are siliceous phytoplankton that dominate the cycling of Si in the oceans. They represent a major source of primary production and are important in the transfer of Si, nitrogen, phosphorus, and atmospheric carbon to the deep sea. Previous investigations of Si isotope fractionation in diatom cultures have ruled out the influence of temperature (12-22°C) and shown that Si fractionation was invariant in different species of temperate diatoms (De La Rocha et al. 1997). However, the application of this proxy for marine paleo-silicon reconstructions has typically only been used in polar regions, such as the Southern Ocean, where high primary production rates give rise to diatom-rich sediments. Here, we present results on the fractionation of Si isotopes by four species of polar diatoms grown in semi-continuous cultures (Chaetoceros brevis, Fragilariopsis kerguelensis, Porosira glacialis, and Thalassiosira antarctica). To compare with previous studies (De La Rocha et al, 1997), we also tested Si isotope fractionation by two species of temperate diatoms (Thalassiosira pseudonana and Thalassiosira weissflogii). The temperate species yielded Si isotope fractionation (Δ30Si) values of -0.81 % (±0.12, SD, n=11) for T. pseudonana and -1.03% (±0.09, SD, n=3) for T. weissflogii, that are identical to the previously reported fractionation of -1.1 % (±0.4, SD, n=6) (De La Rocha et al. 1997). Similarly, our data for polar species F. kerguelensis, P. glacialis and T. antarctica suggest a fractionation of -0.7 to -1.1 %. Interestingly, our preliminary results from Chaetoceros brevis cultures show a Si isotope fractionation value of about -2.61 % (±0.05, SD

  13. 40 CFR 60.4233 - What emission standards must I meet if I am an owner or operator of a stationary SI internal...

    Science.gov (United States)

    2010-07-01

    ... I am an owner or operator of a stationary SI internal combustion engine? 60.4233 Section 60.4233... if I am an owner or operator of a stationary SI internal combustion engine? (a) Owners and operators of stationary SI ICE with a maximum engine power less than or equal to 19 KW (25 HP) manufactured...

  14. 40 CFR 60.4243 - What are my compliance requirements if I am an owner or operator of a stationary SI internal...

    Science.gov (United States)

    2010-07-01

    ... I am an owner or operator of a stationary SI internal combustion engine? 60.4243 Section 60.4243... requirements if I am an owner or operator of a stationary SI internal combustion engine? (a) If you are an owner or operator of a stationary SI internal combustion engine that is manufactured after July 1,...

  15. Dictionary of nuclear engineering

    Energy Technology Data Exchange (ETDEWEB)

    Sube, R.

    1985-01-01

    Ralf Sube, an experienced compiler of three wellknown four-language reference works has now prepared this glossary of nuclear engineering terms in English, German, French and Russian. Based on the proven lexicography of the Technik-Worterbuch series, it comprises about 30,000 terms in each language covering the following: Nuclear and Atomic Physics; Nuclear Radiation and Isotopes; Nuclear Materials; Nuclear Facilties; Nuclear Power Industry; Nuclear Weapons.

  16. Uranium isotopes fingerprint biotic reduction

    Science.gov (United States)

    Stylo, Malgorzata; Neubert, Nadja; Wang, Yuheng; Monga, Nikhil; Romaniello, Stephen J.; Weyer, Stefan; Bernier-Latmani, Rizlan

    2015-01-01

    Knowledge of paleo-redox conditions in the Earth’s history provides a window into events that shaped the evolution of life on our planet. The role of microbial activity in paleo-redox processes remains unexplored due to the inability to discriminate biotic from abiotic redox transformations in the rock record. The ability to deconvolute these two processes would provide a means to identify environmental niches in which microbial activity was prevalent at a specific time in paleo-history and to correlate specific biogeochemical events with the corresponding microbial metabolism. Here, we demonstrate that the isotopic signature associated with microbial reduction of hexavalent uranium (U), i.e., the accumulation of the heavy isotope in the U(IV) phase, is readily distinguishable from that generated by abiotic uranium reduction in laboratory experiments. Thus, isotope signatures preserved in the geologic record through the reductive precipitation of uranium may provide the sought-after tool to probe for biotic processes. Because uranium is a common element in the Earth’s crust and a wide variety of metabolic groups of microorganisms catalyze the biological reduction of U(VI), this tool is applicable to a multiplicity of geological epochs and terrestrial environments. The findings of this study indicate that biological activity contributed to the formation of many authigenic U deposits, including sandstone U deposits of various ages, as well as modern, Cretaceous, and Archean black shales. Additionally, engineered bioremediation activities also exhibit a biotic signature, suggesting that, although multiple pathways may be involved in the reduction, direct enzymatic reduction contributes substantially to the immobilization of uranium. PMID:25902522

  17. Metal stable isotope signatures as tracers in environmental geochemistry.

    Science.gov (United States)

    Wiederhold, Jan G

    2015-03-03

    The biogeochemical cycling of metals in natural systems is often accompanied by stable isotope fractionation which can now be measured due to recent analytical advances. In consequence, a new research field has emerged over the last two decades, complementing the traditional stable isotope systems (H, C, O, N, S) with many more elements across the periodic table (Li, B, Mg, Si, Cl, Ca, Ti, V, Cr, Fe, Ni, Cu, Zn, Ge, Se, Br, Sr, Mo, Ag, Cd, Sn, Sb, Te, Ba, W, Pt, Hg, Tl, U) which are being explored and potentially applicable as novel geochemical tracers. This review presents the application of metal stable isotopes as source and process tracers in environmental studies, in particular by using mixing and Rayleigh model approaches. The most important concepts of mass-dependent and mass-independent metal stable isotope fractionation are introduced, and the extent of natural isotopic variations for different elements is compared. A particular focus lies on a discussion of processes (redox transformations, complexation, sorption, precipitation, dissolution, evaporation, diffusion, biological cycling) which are able to induce metal stable isotope fractionation in environmental systems. Additionally, the usefulness and limitations of metal stable isotope signatures as tracers in environmental geochemistry are discussed and future perspectives presented.

  18. Future downsizing of S.I. engines. Potentials and limits of 2- and 3-cylinder concepts; Zukuenftiges Downsizing bei Ottomotoren-. Potentiale und Grenzen von 2- und 3-Zylinder Konzepten

    Energy Technology Data Exchange (ETDEWEB)

    Weinowski, R.; Sehr, A.; Wedowski, S.; Heuer, S.; Hamm, T.; Tiemann, C. [FEV Motorentechnik GmbH, Aachen (Germany)

    2009-07-01

    Actually, downsizing in connection with loading represents a promising way for a sustainable reduction of the emissions of carbon dioxide at combustion engines. In the segment of the small cars with small engine capacity, beside 4 cylinder engines already today increasingly 3 cylinder engines are used. An ongoing reduction of the engine capacity leads to the question whether a further reduction of the single cylinder engine capacity is meaningful or a transition to two cylinders is the better solution. Furthermore, in this particularly price sensitive segment of vehicles the question according to the technical segment as well as the associated costs is to be considered. On the basis of the state of the art of gasoline engines with low capacity the possible potentials by downsizing regarding to the emissions of carbon dioxide with comparable road performances are analysed, and the limit of the meaningful single cylinder capacity volume is regarded. Apart from the design of the combustion chamber from constructional and thermodynamic view, here also the question of the response mode of a possible loading aggregate, the maximally presentable performance of the engine, the emission level as well as the friction of the engine play an important role. Additionally, the authors of the contribution under consideration shortly evaluate the NVH behaviour of 2 cylinder engines and 3 cylinder engines.

  19. PIE of nuclear grade SiC/SiC flexural coupons irradiated to 10 dpa at LWR temperature

    Energy Technology Data Exchange (ETDEWEB)

    Koyanagi, Takaaki [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Katoh, Yutai [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2017-03-01

    Silicon carbide fiber-reinforced SiC matrix (SiC/SiC) composites are being actively investigated for accident-tolerant core structures of light water reactors (LWRs). Owing to the limited number of irradiation studies previously conducted at LWR-coolant temperature, this study examined SiC/SiC composites following neutron irradiation at 230–340°C to 2.0 and 11.8 dpa in the High Flux Isotope Reactor. The investigated materials are chemical vapor infiltrated (CVI) SiC/SiC composites with three different reinforcement fibers. The fiber materials were monolayer pyrolytic carbon (PyC)-coated Hi-NicalonTM Type-S (HNS), TyrannoTM SA3 (SA3), and SCS-UltraTM (SCS) SiC fibers. The irradiation resistance of these composites was investigated based on flexural behavior, dynamic Young’s modulus, swelling, and microstructures. There was no notable mechanical properties degradation of the irradiated HNS and SA3 SiC/SiC composites except for reduction of the Young’s moduli by up to 18%. The microstructural stability of these composites supported the absence of degradation. In addition, no progressive swelling from 2.0 to 11.8 dpa was confirmed for these composites. On the other hand, the SCS composite showed significant mechanical degradation associated with cracking within the fiber. This study determined that SiC/SiC composites with HNS or SA3 SiC/SiC fibers, a PyC interphase, and a CVI SiC matrix retain their properties beyond the lifetime dose for LWR fuel cladding at the relevant temperature.

  20. Engineering Encounters: Engineering Adaptations

    Science.gov (United States)

    Gatling, Anne; Vaughn, Meredith Houle

    2015-01-01

    Engineering is not a subject that has historically been taught in elementary schools, but with the emphasis on engineering in the "Next Generation Science Standards," curricula are being developed to explicitly teach engineering content and design. However, many of the scientific investigations already conducted with students have…

  1. Engineering Encounters: Engineering Adaptations

    Science.gov (United States)

    Gatling, Anne; Vaughn, Meredith Houle

    2015-01-01

    Engineering is not a subject that has historically been taught in elementary schools, but with the emphasis on engineering in the "Next Generation Science Standards," curricula are being developed to explicitly teach engineering content and design. However, many of the scientific investigations already conducted with students have…

  2. Interface structure between epitaxial NiSi2 and Si

    Institute of Scientific and Technical Information of China (English)

    Wei-Long Liu; Wen-Jauh Chen; Ting-Kan Tsai; Hsun-Heng Tsai; Shu-Huei Hsieh

    2006-01-01

    The interface structure between the Si and NiSi2 epitaxially grown on the ((-1)12) Si substrate was studied using high resolution transmission electron microscopy and computer image simulation. The results showed that the interface between Si and NiSi2 epitaxially grown on the ((-1)12) Si substrate has six different types: type A NiSi2 ((-1)11 )/( (-1)11 ) Si, type A NiSi2 (001)/(001) Si, type B NiSi2 (1(-1)(-1))/(1(-1)1) Si, type B NiSi2 ((-1)12)/(1(-1)2) Si, type B NiSi2 (2(-2)1)/(001) Si, and type B NiSi2 (1(-1)(4))/( 1(-1)0 ) Si. And there are one or more different atomic structures for one type of interface.

  3. 射频 Si/SiGe/Si HBT的研究%Studies on RF Si/SiGe/Si HBT

    Institute of Scientific and Technical Information of China (English)

    廖小平; 殷刚毅

    2003-01-01

    Si/SiGe/Si HBT与Si工艺兼容的研究基础上,对射频Si/SiGe/Si HBT的射频特性和制备工艺进行了研究,分析了与器件结构有关的关键参数寄生电容和寄生电阻与Si/SiGe/Si HBT的特征频率fT和最高振荡频率fmax的关系,成功地制备了fT为2.5 GHz、fmax为2.3 GHz的射频Si/SiGe/Si HBT,为具有更好的射频性能的Si/SiGe/Si HBT的研究建立了基础.

  4. Si/SiGe heterointerfaces in one-, two-, and three-dimensional nanostructures: their impact on SiGe light emission

    Science.gov (United States)

    Lockwood, David; Wu, Xiaohua; Baribeau, Jean-Marc; Mala, Selina; Wang, Xialou; Tsybeskov, Leonid

    2016-03-01

    Fast optical interconnects together with an associated light emitter that are both compatible with conventional Si-based complementary metal-oxide- semiconductor (CMOS) integrated circuit technology is an unavoidable requirement for the next-generation microprocessors and computers. Self-assembled Si/Si1-xGex nanostructures, which can emit light at wavelengths within the important optical communication wavelength range of 1.3 - 1.55 μm, are already compatible with standard CMOS practices. However, the expected long carrier radiative lifetimes observed to date in Si and Si/Si1-xGex nanostructures have prevented the attainment of efficient light-emitting devices including the desired lasers. Thus, the engineering of Si/Si1-xGex heterostructures having a controlled composition and sharp interfaces is crucial for producing the requisite fast and efficient photoluminescence (PL) at energies in the range 0.8-0.9 eV. In this paper we assess how the nature of the interfaces between SiGe nanostructures and Si in heterostructures strongly affects carrier mobility and recombination for physical confinement in three dimensions (corresponding to the case of quantum dots), two dimensions (corresponding to quantum wires), and one dimension (corresponding to quantum wells). The interface sharpness is influenced by many factors such as growth conditions, strain, and thermal processing, which in practice can make it difficult to attain the ideal structures required. This is certainly the case for nanostructure confinement in one dimension. However, we demonstrate that axial Si/Ge nanowire (NW) heterojunctions (HJs) with a Si/Ge NW diameter in the range 50 - 120 nm produce a clear PL signal associated with band-to-band electron-hole recombination at the NW HJ that is attributed to a specific interfacial SiGe alloy composition. For three-dimensional confinement, the experiments outlined here show that two quite different Si1-xGex nanostructures incorporated into a Si0.6Ge0.4 wavy

  5. Si/SiGe heterointerfaces in one-, two-, and three-dimensional nanostructures: their impact on SiGe light emission

    Directory of Open Access Journals (Sweden)

    David J. Lockwood

    2016-03-01

    Full Text Available Fast optical interconnects together with an associated light emitter that are both compatible with conventional Si-based complementary metal-oxide- semiconductor (CMOS integrated circuit technology is an unavoidable requirement for the next-generation microprocessors and computers. Self-assembled Si/Si1-xGex nanostructures, which can emit light at wavelengths within the important optical communication wavelength range of 1.3 – 1.55 μm, are already compatible with standard CMOS practices. However, the expected long carrier radiative lifetimes observed to date in Si and Si/Si1-xGex nanostructures have prevented the attainment of efficient light-emitting devices including the desired lasers. Thus, the engineering of Si/Si1-xGex heterostructures having a controlled composition and sharp interfaces is crucial for producing the requisite fast and efficient photoluminescence (PL at energies in the range 0.8-0.9 eV. In this paper we assess how the nature of the interfaces between SiGe nanostructures and Si in heterostructures strongly affects carrier mobility and recombination for physical confinement in three dimensions (corresponding to the case of quantum dots, two dimensions (corresponding to quantum wires, and one dimension (corresponding to quantum wells. The interface sharpness is influenced by many factors such as growth conditions, strain, and thermal processing, which in practice can make it difficult to attain the ideal structures required. This is certainly the case for nanostructure confinement in one dimension. However, we demonstrate that axial Si/Ge nanowire (NW heterojunctions (HJs with a Si/Ge NW diameter in the range 50 – 120 nm produce a clear PL signal associated with band-to-band electron-hole recombination at the NW HJ that is attributed to a specific interfacial SiGe alloy composition. For three-dimensional confinement, the experiments outlined here show that two quite different Si1-xGex nanostructures incorporated into a Si

  6. Isotopes in Greenland Precipitation

    DEFF Research Database (Denmark)

    Faber, Anne-Katrine

    the Arctic Ocean. A comprehensive database is created based on ice core and weather station data from Greenland within the period 1890-2014. Present day annual and seasonal mean values are computed for 326 locations in Greenland. Parameterization of the spatial distribution of temperature and δ18O are used...... of model and data can be used to improve the understanding of climate changes. This is done through analysis of isotope modelling, observations and ice core measurements. This dissertation comprises three projects: (1) Modelling the isotopic response to changes in Arctic sea surface conditions, (2......) Constructing a new Greenland database of observations and present-day ice core measurements, and (3) Performance test of isotope-enabled CAM5 for Greenland. The recent decades of rapid Arctic sea ice decline are used as a basis for an observational-based model experiment using the isotope-enabled CAM model 3...

  7. Perchlorate isotope forensics

    Science.gov (United States)

    Böhlke, J.K.; Sturchio, N.C.; Gu, B.; Horita, J.; Brown, G.M.; Jackson, W.A.; Batista, J.; Hatzinger, P.B.

    2005-01-01

    Perchlorate has been detected recently in a variety of soils, waters, plants, and food products at levels that may be detrimental to human health. These discoveries have generated considerable interest in perchlorate source identification. In this study, comprehensive stable isotope analyses ( 37Cl/35Cl and 18O/17O/ 16O) of perchlorate from known synthetic and natural sources reveal systematic differences in isotopic characteristics that are related to the formation mechanisms. In addition, isotopic analyses of perchlorate extracted from groundwater and surface water demonstrate the feasibility of identifying perchlorate sources in contaminated environments on the basis of this technique. Both natural and synthetic sources of perchlorate have been identified in water samples from some perchlorate occurrences in the United States by the isotopic method. ?? 2005 American Chemical Society.

  8. Isotope Production Facility (IPF)

    Data.gov (United States)

    Federal Laboratory Consortium — The Los Alamos National Laboratory has produced radioactive isotopes for medicine and research since the mid 1970s, when targets were first irradiated using the 800...

  9. Calcium stable isotope geochemistry

    Energy Technology Data Exchange (ETDEWEB)

    Gausonne, Nikolaus [Muenster Univ. (Germany). Inst. fuer Mineralogie; Schmitt, Anne-Desiree [Strasbourg Univ. (France). LHyGeS/EOST; Heuser, Alexander [Bonn Univ. (Germany). Steinmann-Inst. fuer Geologie, Mineralogie und Palaeontologie; Wombacher, Frank [Koeln Univ. (Germany). Inst. fuer Geologie und Mineralogie; Dietzel, Martin [Technische Univ. Graz (Austria). Inst. fuer Angewandte Geowissenschaften; Tipper, Edward [Cambridge Univ. (United Kingdom). Dept. of Earth Sciences; Schiller, Martin [Copenhagen Univ. (Denmark). Natural History Museum of Denmark

    2016-08-01

    This book provides an overview of the fundamentals and reference values for Ca stable isotope research, as well as current analytical methodologies including detailed instructions for sample preparation and isotope analysis. As such, it introduces readers to the different fields of application, including low-temperature mineral precipitation and biomineralisation, Earth surface processes and global cycling, high-temperature processes and cosmochemistry, and lastly human studies and biomedical applications. The current state of the art in these major areas is discussed, and open questions and possible future directions are identified. In terms of its depth and coverage, the current work extends and complements the previous reviews of Ca stable isotope geochemistry, addressing the needs of graduate students and advanced researchers who want to familiarize themselves with Ca stable isotope research.

  10. Isotopically controlled semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Haller, E.E.

    2004-11-15

    A review of recent research involving isotopically controlled semiconductors is presented. Studies with isotopically enriched semiconductor structures experienced a dramatic expansion at the end of the Cold War when significant quantities of enriched isotopes of elements forming semiconductors became available for worldwide collaborations. Isotopes of an element differ in nuclear mass, may have different nuclear spins and undergo different nuclear reactions. Among the latter, the capture of thermal neutrons which can lead to neutron transmutation doping, can be considered the most important one for semiconductors. Experimental and theoretical research exploiting the differences in all the properties has been conducted and will be illustrated with selected examples. Manuel Cardona, the longtime editor-in-chief of Solid State Communications has been and continues to be one of the major contributors to this field of solid state physics and it is a great pleasure to dedicate this review to him.

  11. Isotopes through the looking glass

    Science.gov (United States)

    Mårtensson Pendrill, Ann Marie

    2000-08-01

    Nuclear distributions affect many aspects of atomic spectra. As an example, recent experimental results for the hyperfine anomaly in Fr isotopes are considered. These depend on nuclear charge and magnetization distributions. The variations in charge radii for these isotopes were studied earlier by measuring optical isotope shifts. The hyperfine anomalies for the odd-odd isotopes involve the neutron distributions, of interest for studies of parity nonconserving effects along a chain of isotopes.

  12. Quantitative imaging of cells with multi-isotope imaging mass spectrometry (MIMS)—Nanoautography with stable isotope tracers

    Science.gov (United States)

    McMahon, Greg; Glassner, Brian J.; Lechene, Claude P.

    2006-07-01

    We describe some technical aspects of the application of multi-isotope imaging mass spectrometry (MIMS) to biological research, particularly the use of isotopic tags to localize and measure their incorporation into intracellular compartments. We touch on sample preparation, on image formation, on drift correction and on extraction of quantitative data from isotope ratio imaging. We insist on the wide variety of sample types that can be used, ranging from whole cells prepared directly on Si supports, to thin sections of cells and tissues on Si supports, to ultrathin TEM sections on carbon-coated grid. We attempt to dispel the myth of difficulties in sample preparation, which we view as a needless deterrent to the application of MIMS to the general biological community. We present protocols for the extraction of isotope ratio data from mass images. We illustrate the benefits of using sequential image plane acquisition followed by the application of an autocorrelation algorithm (nanotracking) to remove the effects of specimen drift. We insist on the advantages to display the isotope ratios as hue saturation intensity images.

  13. Enzymatic synthesis and RNA interference of nucleosides incorporating stable isotopes into a base moiety.

    Science.gov (United States)

    Hatano, Akihiko; Shiraishi, Mitsuya; Terado, Nanae; Tanabe, Atsuhiro; Fukuda, Kenji

    2015-10-15

    Thymidine phosphorylase was used to catalyze the conversion of thymidine (or methyluridine) and uracil incorporating stable isotopes to deoxyuridine (or uridine) with the uracil base incorporating the stable isotope. These base-exchange reactions proceeded with high conversion rates (75-96%), and the isolated yields were also good (64-87%). The masses of all synthetic compounds incorporating stable isotopes were identical to the theoretical molecular weights via EIMS. (13)C NMR spectra showed spin-spin coupling between (13)C and (15)N in the synthetic compounds, and the signals were split, further proving incorporation of the isotopes into the compounds. The RNA interference effects of this siRNA with uridine incorporating stable isotopes were also investigated. A 25mer siRNA had a strong knockdown effect on the MARCKS protein. The insertion position and number of uridine moieties incorporating stable isotopes introduced into the siRNA had no influence on the silencing of the target protein. This incorporation of stable isotopes into RNA and DNA has the potential to function as a chemically benign tracer in cells.

  14. Methods of isotopic geochronology

    Science.gov (United States)

    Gorokhov, I. M.; Levchenkov, O. A.

    Papers are presented on such topics as the age of the chemical elements; the age of meteorites, the moon, and the earth; isotopic ages of the most ancient terrestrial formations; and the Archean evolution of Enderby Land in the Antarctic as evidenced by isotopic dating. Consideration is also given to a uranium-lead geochronology technique for investigating Precambrian ore deposits, a Pb-Pb technique of zircon dating, and the potentials and limitations of Sm-Nd geochronology.

  15. Diffusion in isotopically controlled semiconductor systems

    Science.gov (United States)

    Bracht, H.

    1999-12-01

    Isotopically controlled heterostructures of 28Si/natSi and Al71GaAs/Al69GaAs/71GaAs have been used to study the self-diffusion process in this elemental and compound semiconductor material. The directly measured Si self-diffusion coefficient is compared with the self-interstitial and vacancy contribution to self-diffusion which were deduced from metal diffusion experiments. The remarkable agreement between the Si self-diffusion coefficients and the individual contributions to self-diffusion shows that both self-interstitials and vacancies mediate Si self-diffusion. The Ga self-diffusion in undoped AlGaAs was found to decrease with increasing Al concentration. The activation enthalpy of Ga and Al diffusion in GaAs and of Ga diffusion in AlGaAs all lie in the range of (3.6±0.1) eV, but with different pre-exponential factors. The doping dependence of Ga self-diffusion reveals a retardation (enhancement) of Ga diffusion under p-type (n-type) doping compared to intrinsic conditions. All experimental results on the group-III atom diffusion are accurately described if vacancies on the group-III sublattice are assumed to mediate the Ga self- and Al-Ga interdiffusion in undoped AlGaAs and the Ga self-diffusion in Be- and Si-doped GaAs with an active dopant concentration of 3×1018 cm-3. The doping dependence of Ga self-diffusion in GaAs provides strong evidence that neutral, singly and doubly charged Ga vacancies govern the self-diffusion process.

  16. Advanced Natural Gas Reciprocating Engine(s)

    Energy Technology Data Exchange (ETDEWEB)

    Pike, Edward

    2014-03-31

    The objective of the Cummins ARES program, in partnership with the US Department of Energy (DOE), is to develop advanced natural gas engine technologies that increase engine system efficiency at lower emissions levels while attaining lower cost of ownership. The goals of the project are to demonstrate engine system achieving 50% Brake Thermal Efficiency (BTE) in three phases, 44%, 47% and 50% (starting baseline efficiency at 36% BTE) and 0.1 g/bhp-hr NOx system out emissions (starting baseline NOx emissions at 2 – 4 g/bhp-hr NOx). Primary path towards above goals include high Brake Mean Effective Pressure (BMEP), improved closed cycle efficiency, increased air handling efficiency and optimized engine subsystems. Cummins has successfully demonstrated each of the phases of this program. All targets have been achieved through application of a combined set of advanced base engine technologies and Waste Heat Recovery from Charge Air and Exhaust streams, optimized and validated on the demonstration engine and other large engines. The following architectures were selected for each Phase: Phase 1: Lean Burn Spark Ignited (SI) Key Technologies: High Efficiency Turbocharging, Higher Efficiency Combustion System. In production on the 60/91L engines. Over 500MW of ARES Phase 1 technology has been sold. Phase 2: Lean Burn Technology with Exhaust Waste Heat Recovery (WHR) System Key Technologies: Advanced Ignition System, Combustion Improvement, Integrated Waste Heat Recovery System. Base engine technologies intended for production within 2 to 3 years Phase 3: Lean Burn Technology with Exhaust and Charge Air Waste Heat Recovery System Key Technologies: Lower Friction, New Cylinder Head Designs, Improved Integrated Waste Heat Recovery System. Intended for production within 5 to 6 years Cummins is committed to the launch of next generation of large advanced NG engines based on ARES technology to be commercialized worldwide.

  17. Advanced Environmental Barrier Coating Development for SiC-SiC Ceramic Matrix Composite Components

    Science.gov (United States)

    Zhu, Dongming; Harder, Bryan; Bhatt, Ramakrishna; Kiser, Doug; Wiesner, Valerie L.

    2016-01-01

    This presentation reviews the NASA advanced environmental barrier coating (EBC) system development for SiCSiC Ceramic Matrix Composite (CMC) components for next generation turbine engines. The emphasis has been placed on the current design challenges of the 2700F environmental barrier coatings; coating processing and integration with SiCSiC CMCs and component systems; and performance evaluation and demonstration of EBC-CMC systems. This presentation also highlights the EBC-CMC system temperature capability and durability improvements through advanced compositions and architecture designs, as shown in recent simulated engine high heat flux, combustion environment, in conjunction with mechanical creep and fatigue loading testing conditions.

  18. Si-based Nanoparticles: a biocompatibility study

    Science.gov (United States)

    Rivolta, I.; Lettiero, B.; Panariti, A.; D'Amato, R.; Maurice, V.; Falconieri, M.; Herlein, N.; Borsella, E.; Miserocchi, G.

    2010-10-01

    Exposure to silicon nanoparticles (Si-NPs) may occur in professional working conditions or for people undergoing a diagnostic screening test. Despite the fact that silicon is known as a non-toxic material, in the first case the risk is mostly related to the inhalation of nanoparticles, thus the most likely route of entry is across the lung alveolar epithelium. In the case of diagnostic imaging, nanoparticles are usually injected intravenously and Si-NPs could impact on the endothelial wall. In our study we investigated the interaction between selected Si-based NPs and an epithelial lung cell line. Our data showed that, despite the overall silicon biocompatibility, however accurate studies of the potential toxicity induced by the nanostructure and engineered surface characteristics need to be accurately investigated before Si nanoparticles can be safely used for in vivo applications as bio-imaging, cell staining and drug delivery.

  19. Diesel engines vs. spark ignition gasoline engines -- Which is ``greener``?

    Energy Technology Data Exchange (ETDEWEB)

    Fairbanks, J.W. [Dept. of Energy, Washington, DC (United States)

    1997-12-31

    Criteria emissions, i.e., NO{sub x}, PM, CO, CO{sub 2}, and H{sub 2}, from recently manufactured automobiles, compared on the basis of what actually comes out of the engines, the diesel engine is greener than spark ignition gasoline engines and this advantage for the diesel engine increases with time. SI gasoline engines tend to get out of tune more than diesel engines and 3-way catalytic converters and oxygen sensors degrade with use. Highway measurements of NO{sub 2}, H{sub 2}, and CO revealed that for each model year, 10% of the vehicles produce 50% of the emissions and older model years emit more than recent model year vehicles. Since 1974, cars with SI gasoline engines have uncontrolled emission until the 3-way catalytic converter reaches operating temperature, which occurs after roughly 7 miles of driving. Honda reports a system to be introduced in 1998 that will alleviate this cold start problem by storing the emissions then sending them through the catalytic converter after it reaches operating temperature. Acceleration enrichment, wherein considerable excess fuel is introduced to keep temperatures down of SI gasoline engine in-cylinder components and catalytic converters so these parts meet warranty, results in 2,500 times more CO and 40 times more H{sub 2} being emitted. One cannot kill oneself, accidentally or otherwise, with CO from a diesel engine vehicle in a confined space. There are 2,850 deaths per year attributable to CO from SI gasoline engine cars. Diesel fuel has advantages compared with gasoline. Refinery emissions are lower as catalytic cracking isn`t necessary. The low volatility of diesel fuel results in a much lower probability of fires. Emissions could be improved by further reducing sulfur and aromatics and/or fuel additives. Reformulated fuel has become the term covering reducing the fuels contribution to emissions. Further PM reduction should be anticipated with reformulated diesel and gasoline fuels.

  20. Ru isotope heterogeneity in the solar protoplanetary disk

    Science.gov (United States)

    Fischer-Gödde, Mario; Burkhardt, Christoph; Kruijer, Thomas S.; Kleine, Thorsten

    2015-11-01

    Nucleosynthetic isotope anomalies in bulk chondrites and differentiated meteorites reflect variable proportions of isotopically diverse presolar components in bulk planetary bodies, but the origin of these heterogeneities is not well understood. Here, the Ru isotope composition of a comprehensive suite of iron meteorites and bulk samples of ordinary, enstatite and carbonaceous chondrites, as well as acid leachates and an insoluble residue of the Allende chondrite are examined using newly developed multi-collector inductively coupled plasma mass spectrometry techniques. Except for IAB iron meteorites and enstatite chondrites, all investigated meteorites show well-resolved Ru isotope anomalies. Of these, within-group Ru isotopic variations observed for samples from a given chemical group of iron meteorites reflect secondary neutron capture induced Ru isotope shifts during prolonged cosmic ray-exposure. After correction of these cosmogenic effects using Pt isotopes as a neutron-dose monitor, the remaining Ru isotope anomalies are nucleosynthetic in nature and are consistent with a deficit in s-process Ru in iron meteorite parent bodies. Similarly, Ru isotope anomalies in bulk ordinary and carbonaceous chondrites also reflect a deficiency in s-process Ru. The sequential dissolution of Allende reveals the presence of an HF-soluble s-process carrier, which is either an unidentified presolar phase or a component that incorporated s-process Ru liberated from SiC grains during nebular or parent body processes. We show that varying proportions of the s-process carrier identified in Allende resulted in the correlated Ru isotope anomalies observed for bulk meteorites, and that all meteorites (except possibly IAB irons and enstatite chondrites) are depleted in this s-process component relative to Ru from the Earth's mantle. Bulk meteorites exhibit correlated Ru and Mo isotope anomalies, reflecting variable deficits of a common s-process component, but some iron meteorites and

  1. 40 CFR 60.4242 - What other requirements must I meet if I am a manufacturer of stationary SI internal combustion...

    Science.gov (United States)

    2010-07-01

    ... I am a manufacturer of stationary SI internal combustion engines or equipment containing stationary SI internal combustion engines or a manufacturer of equipment containing such engines? 60.4242... Ignition Internal Combustion Engines Compliance Requirements for Manufacturers § 60.4242 What other...

  2. Technique development for modulus, microcracking, hermeticity, and coating evaluation capability characterization of SiC/SiC tubes

    Energy Technology Data Exchange (ETDEWEB)

    Hu, Xunxiang [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Ang, Caen K. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Singh, Gyanender P. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Katoh, Yutai [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

    2016-08-01

    Driven by the need to enlarge the safety margins of nuclear fission reactors in accident scenarios, research and development of accident-tolerant fuel has become an important topic in the nuclear engineering and materials community. A continuous-fiber SiC/SiC composite is under consideration as a replacement for traditional zirconium alloy cladding owing to its high-temperature stability, chemical inertness, and exceptional irradiation resistance. An important task is the development of characterization techniques for SiC/SiC cladding, since traditional work using rectangular bars or disks cannot directly provide useful information on the properties of SiC/SiC composite tubes for fuel cladding applications. At Oak Ridge National Laboratory, experimental capabilities are under development to characterize the modulus, microcracking, and hermeticity of as-fabricated, as-irradiated SiC/SiC composite tubes. Resonant ultrasound spectroscopy has been validated as a promising technique to evaluate the elastic properties of SiC/SiC composite tubes and microcracking within the material. A similar technique, impulse excitation, is efficient in determining the basic mechanical properties of SiC bars prepared by chemical vapor deposition; it also has potential for application in studying the mechanical properties of SiC/SiC composite tubes. Complete evaluation of the quality of the developed coatings, a major mitigation strategy against gas permeation and hydrothermal corrosion, requires the deployment of various experimental techniques, such as scratch indentation, tensile pulling-off tests, and scanning electron microscopy. In addition, a comprehensive permeation test station is being established to assess the hermeticity of SiC/SiC composite tubes and to determine the H/D/He permeability of SiC/SiC composites. This report summarizes the current status of the development of these experimental capabilities.

  3. Magnesium isotope fractionation during differentiation of Harney Peak granite

    Science.gov (United States)

    Ke, S.; Teng, F.; Walker, R. J.

    2009-12-01

    Although numerous studies have sought to constrain the Mg isotopic composition of mantle rocks, few studies have focused on the Mg isotopic compositions of crustal rocks, particularly evolved igneous rocks, such as granites. Granites are a major component of the upper continental crust and can be produced by partial melting of the deep continental crust. Studies of granites, therefore, can potentially provide important constraints on Mg isotopic composition variations in the continental crust as related to sources and petrogenetic processes. In order to explore the behavior of Mg isotopes during partial melting of continental crust, as well as granite differentiation, we have begun a study of a set of well-characterized samples from S-type Harney Peak granite, its potential source rocks and associated Tin Mountain pegmatite from Black Hills, South Dakota, USA. δ26Mg values of Harney Peak granites and Tin Mountain pegmatite vary significantly (from -0.69 to +0.11), well beyond the range of their potential source rocks (from -0.40 to +0.15) — early Proterozoic schists and late Archean metagranites. The large Mg isotopic variations within the granite suite likely, in part, reflect heterogeneities in source rocks, as previously shown for oxygen and Nd isotopes. A greater cause of the variations may be fractionations that occur during partial melting and subsequent differentiation of granitic melts, as suggested by the correlations between δ26Mg with SiO2, Al2O3, Na2O and Sr.

  4. Privacy and Yin Si

    Institute of Scientific and Technical Information of China (English)

    胡迪

    2007-01-01

    <正>“Privacy” is translated as yin si in Chinese.Traditionally,in the Chinese mind,yin si is associated with something that is closed or unfair.If someone is said to have yin si,meddlers(好事者) will be attracted to pry(打探) into his or her affairs.So people always state that they don’t have yin si.

  5. Electroluminescence of Si Nanocrystal-Doped SiO2

    Institute of Scientific and Technical Information of China (English)

    CHEN Dan; XIE Zhi-Qiang; WU Qian; ZHAO You-Yuan; LU Ming

    2007-01-01

    @@ We perform a comparative study on the electroluminescence (EL) and photoluminescence (PL) of Si nanocrystaldoped SiO2 (nc-Si:SiO2) and SiO2, and clarify whether the contribution from Si nanocrystals in the EL of nc-Si:SiO2 truly exists. The results unambiguously indicate the presence of EL of Si nanocrystals. The difference of peak positions between the EL and PL spectra are discussed. It is found that the normal method of passivation to enhance the PL of Si nanocrystals is not equally effective for the EL, hence new methods need to be explored to promote the EL of Si nanocrystals.

  6. Quadrupole collectivity in silicon isotopes approaching neutron number N=28

    Science.gov (United States)

    Campbell, C. M.; Aoi, N.; Bazin, D.; Bowen, M. D.; Brown, B. A.; Cook, J. M.; Dinca, D.-C.; Gade, A.; Glasmacher, T.; Horoi, M.; Kanno, S.; Motobayashi, T.; Riley, L. A.; Sagawa, H.; Sakurai, H.; Starosta, K.; Suzuki, H.; Takeuchi, S.; Terry, J. R.; Yoneda, K.; Zwahlen, H.

    2007-08-01

    Quadrupole deformation parameters, |β|, have been deduced for 36,38,40Si from measured inelastic proton-scattering cross sections. Due to the strong Z=14 subshell gap, low-lying quadrupole collectivity in these nuclei is attributed to the excitation of valence neutrons. Enhanced collectivity at N=26 indicates a reduced N=28 shell gap at large neutron excess in this chain of isotopes. Data are compared to large-scale shell-model calculations and prior Coulomb excitation measurements on 36,38Si.

  7. Self-Powered, High-Speed and Visible-Near Infrared Response of MoO(3-x)/n-Si Heterojunction Photodetector with Enhanced Performance by Interfacial Engineering.

    Science.gov (United States)

    Zhao, Chuanxi; Liang, Zhimin; Su, Mingze; Liu, Pengyi; Mai, Wenjie; Xie, Weiguang

    2015-11-25

    Photodetectors with a wide spectrum response are important components for sensing, imaging, and other optoelectronic applications. A molybdenum oxide (MoO(3-x))/Si heterojunction has been applied as solar cells with great success, but its potential in photodetectors has not been explored yet. Herein, a self-powered, high-speed heterojunction photodetector fabricated by coating an n-type Si hierarchical structure with an ultrathin hole-selective layer of molybdenum oxide (MoO(3-x)) is first investigated. Excellent and stable photoresponse performance is obtained by using a methyl group passivated interface. The heterojunction photodetector demonstrated high sensitivity to a wide spectrum from 300 to 1100 nm. The self-powered photodetector shows a high detectivity of (∼6.29 × 10(12) cmHz(1/2) W(-1)) and fast response time (1.0 μs). The excellent photodetecting performance is attributed to the enhanced interfacial barrier height and three-dimensional geometry of Si nanostructures, which is beneficial for efficient photocarrier collection and transportation. Finally, our devices show excellent long-term stability in air for 6 months with negligible performance degradation. The thermal evaporation method for large-scale fabrication of MoO(3-x)/n-Si photodetectors makes it suitable for self-powered, multispectral, and high-speed response photodetecting applications.

  8. Engineering Encounters: Reverse Engineering

    Science.gov (United States)

    McGowan, Veronica Cassone; Ventura, Marcia; Bell, Philip

    2017-01-01

    This column presents ideas and techniques to enhance your science teaching. This month's issue shares information on how students' everyday experiences can support science learning through engineering design. In this article, the authors outline a reverse-engineering model of instruction and describe one example of how it looked in our fifth-grade…

  9. Differences between mono-generic and mixed diatom silicon isotope compositions trace present and past nutrient utilisation off Peru

    Science.gov (United States)

    Doering, Kristin; Ehlert, Claudia; Grasse, Patricia; Crosta, Xavier; Fleury, Sophie; Frank, Martin; Schneider, Ralph

    2016-03-01

    In this study we combine for the first time silicon (Si) isotope compositions of small mixed diatom species (δ30SibSiO2) and of large handpicked mono-generic (i.e. genus = Coscinodiscus) diatom samples (δ30SiCoscino) with diatom assemblages extracted from marine sediments in the Peruvian upwelling region in order to constrain present and past silicate utilisation. The extension of a previous core-top data set from the Peruvian shelf demonstrates that δ30SiCoscino values record near-complete Si utilisation, as these are similar to the isotopic composition of the subsurface source waters feeding the upwelling. In contrast, the δ30SibSiO2 of small mixed diatom species increase southward along the shelf as well as towards the shore. We attribute highest δ30SibSiO2 values partly to transient iron limitation but primarily to the gradual increase of Si isotope fractionation within the seasonal diatom succession, which are mainly recorded by small diatom species during intense bloom events. In contrast, lower δ30SibSiO2 values are related to initial Si isotope utilisation during periods of weak upwelling, when low Si(OH)4 concentrations do not permit intense blooms and small diatom species record substantially lower δ30Si signatures. As such, we propose that the intensity of the upwelling can be deduced from the offset between δ30SibSiO2 and δ30SiCoscino (Δ30Sicoscino-bSiO2), which is low for strong upwelling conditions and high for prevailing weak upwelling. We apply the information extracted from surface sediments to generate a record of the present-day main upwelling region covering the past 17,700 years and find that this location has also been characterized by a persistent offset (Δ30Sicoscino-bSiO2). By comparison with the diatom assemblages we show that the coastal upwelling system changed markedly between weak and strong upwelling conditions. In addition, our model calculations to quantify species-specific Si isotope fractionation effects based on the

  10. Isotope geochemistry. Biological signatures in clumped isotopes of O₂.

    Science.gov (United States)

    Yeung, Laurence Y; Ash, Jeanine L; Young, Edward D

    2015-04-24

    The abundances of molecules containing more than one rare isotope have been applied broadly to determine formation temperatures of natural materials. These applications of "clumped" isotopes rely on the assumption that isotope-exchange equilibrium is reached, or at least approached, during the formation of those materials. In a closed-system terrarium experiment, we demonstrate that biological oxygen (O2) cycling drives the clumped-isotope composition of O2 away from isotopic equilibrium. Our model of the system suggests that unique biological signatures are present in clumped isotopes of O2—and not formation temperatures. Photosynthetic O2 is depleted in (18)O(18)O and (17)O(18)O relative to a stochastic distribution of isotopes, unlike at equilibrium, where heavy-isotope pairs are enriched. Similar signatures may be widespread in nature, offering new tracers of biological and geochemical cycling.

  11. Stable isotopes. Applications and production; Les isotopes stables. Applications - production

    Energy Technology Data Exchange (ETDEWEB)

    Goldstein, S.; Louvet, P.; Soulie, E. [eds.

    1994-12-31

    This conference presents 46 communications concerning stable isotope production, utilization and application, grouped in 6 sessions and posters. The various themes are: biological applications (pharmacology, medical diagnosis, metabolism and protein studies, toxicity and response studies, labelled compounds), analysis procedures (NMR analysis for macromolecules, tracer studies), nuclear applications (utilization of stable isotopes in nuclear reactors), biological, physical and chemical applications (mass transfer, mobility, crystallography, isotopic exchange), stable isotope production (ion chromatography, ion cyclotron resonance, cryogenic distillation).

  12. Deformation of C isotopes

    CERN Document Server

    Kanada-Enyo, Y

    2004-01-01

    Systematic analysis of the deformations of proton and neutron densities in even-even C isotopes was done based on the method of antisymmetrized molecular dynamics. The $E2$ transition strength was discussed in relation to the deformation. We analyze the $B(E2;2^+_1\\to 0^+_1)$ in $^{16}$C, which has been recently measured to be abnormally small. The results suggest the difference of the deformations between proton and neutron densities in the neutron-rich C isotopes. It was found that stable proton structure in C isotopes plays an important role in the enhancement the neutron skin structure as well as in the systematics of $B(E2)$ in the neutron-rich C.

  13. Velcro-Inspired SiC Fuzzy Fibers for Aerospace Applications.

    Science.gov (United States)

    Hart, Amelia H C; Koizumi, Ryota; Hamel, John; Owuor, Peter Samora; Ito, Yusuke; Ozden, Sehmus; Bhowmick, Sanjit; Syed Amanulla, Syed Asif; Tsafack, Thierry; Keyshar, Kunttal; Mital, Rahul; Hurst, Janet; Vajtai, Robert; Tiwary, Chandra Sekhar; Ajayan, Pulickel M

    2017-04-05

    The most recent and innovative silicon carbide (SiC) fiber ceramic matrix composites, used for lightweight high-heat engine parts in aerospace applications, are woven, layered, and then surrounded by a SiC ceramic matrix composite (CMC). To further improve both the mechanical properties and thermal and oxidative resistance abilities of this material, SiC nanotubes and nanowires (SiCNT/NWs) are grown on the surface of the SiC fiber via carbon nanotube conversion. This conversion utilizes the shape memory synthesis (SMS) method, starting with carbon nanotube (CNT) growth on the SiC fiber surface, to capitalize on the ease of dense surface morphology optimization and the ability to effectively engineer the CNT-SiC fiber interface to create a secure nanotube-fiber attachment. Then, by converting the CNTs to SiCNT/NWs, the relative morphology, advantageous mechanical properties, and secure connection of the initial CNT-SiC fiber architecture are retained, with the addition of high temperature and oxidation resistance. The resultant SiCNT/NW-SiC fiber can be used inside the SiC ceramic matrix composite for a high-heat turbo engine part with longer fatigue life and higher temperature resistance. The differing sides of the woven SiCNT/NWs act as the "hook and loop" mechanism of Velcro but in much smaller scale.

  14. Mechanical engineer's reference book

    CERN Document Server

    Parrish, A

    1973-01-01

    Mechanical Engineer's Reference Book: 11th Edition presents a comprehensive examination of the use of Systéme International d' Unités (SI) metrication. It discusses the effectiveness of such a system when used in the field of engineering. It addresses the basic concepts involved in thermodynamics and heat transfer. Some of the topics covered in the book are the metallurgy of iron and steel; screw threads and fasteners; hole basis and shaft basis fits; an introduction to geometrical tolerancing; mechanical working of steel; high strength alloy steels; advantages of making components as castings

  15. The Present Status of SiC/SiC R and D for Nuclear Application in Japan

    Energy Technology Data Exchange (ETDEWEB)

    Kohyama, Akira, E-mail: kohyama@mmm.muroran-it.ac.jp [OASIS, Muroran Institute of Technology 27-1 Mizumoto-cho, Muroran 050-8585 (Japan)

    2011-10-29

    SiC/SiC R and D for nuclear application in Japan is quite active under the coordinated activities of Atomic Energy Society of Japan's committee on 'Applications of Ceramic Materials for Advanced Nuclear Power Systems' and mainly government funded nuclear engineering/materials activities collaborating academia and industries. Start with the brief introduction of those activities, representing research activities are introduced. ITER and BA related SiC/SiC activities are emphasized, followed by introductions of extensive OASIS, Muroran Institute of Technology activities. The importance of international collaboration and strategic planning is mentioned.

  16. Si/SiO2和Si/SiNx/SiO2超晶格的能带结构%Band structure of Si/SiO2 and Si/SiNx/SiO2 superlattices

    Institute of Scientific and Technical Information of China (English)

    魏屹; 董成军; 徐明

    2010-01-01

    利用Kronig-Penney模型从理论上计算了Si/SiO2和Si/Si/SiNx/SiO2多层膜结构中量子阱的能带结构,进一步分析了各亚层薄膜厚度对能带结构和有效质量的影响.结果发现,适当减少亚层的厚度都能使得纳米Si薄膜的带隙发生明显宽化.在Si/SiO2超晶格中,Si量子阱层带隙能量随着Si层厚度的变化符合EPLL(eV)=1.6+0.7/d2关系,与我们的计算结果十分吻合.在Si/SiNdSiO2超晶格系统中,可以通过控制各亚层厚度,尤其是Si和SiNx层厚度,均能够有效地控制发光.

  17. Atomic Weights and Isotopic Compositions

    Science.gov (United States)

    SRD 144 Atomic Weights and Isotopic Compositions (Web, free access)   The atomic weights are available for elements 1 through 111, and isotopic compositions or abundances are given when appropriate.

  18. Influence of liquid structure on diffusive isotope separation in molten silicates and aqueous solutions

    Energy Technology Data Exchange (ETDEWEB)

    Watkins, J.M.; DePaolo, D.J.; Ryerson, F.J.; Peterson, B.

    2011-03-01

    Molecular diffusion in natural volcanic liquids discriminates between isotopes of major ions (e.g., Fe, Mg, Ca, and Li). Although isotope separation by diffusion is expected on theoretical grounds, the dependence on mass is highly variable for different elements and in different media. Silicate liquid diffusion experiments using simple liquid compositions were carried out to further probe the compositional dependence of diffusive isotopic discrimination and its relationship to liquid structure. Two diffusion couples consisting of the mineral constituents anorthite (CaAl{sub 2}Si{sub 2}O{sub 8}; denoted AN), albite (NaAlSi{sub 3}O{sub 8}; denoted AB), and diopside (CaMgSi{sub 2}O{sub 6}; denoted DI) were held at 1450°C for 2 h and then quenched to ambient pressure and temperature. Major-element as well as Ca and Mg isotope profiles were measured on the recovered quenched glasses. In both experiments, Ca diffuses rapidly with respect to Si. In the AB–AN experiment, D{sub Ca}/D{sub Si} ~ 20 and the efficiency of isotope separation for Ca is much greater than in natural liquid experiments where D{sub Ca}/D{sub Si} ~ 1. In the AB–DI experiment, D{sub Ca}/D{sub Si} ~ 6 and the efficiency of isotope separation is between that of the natural liquid experiments and the AB–AN experiment. In the AB–DI experiment, D{sub Mg}/D{sub Si} ~ 1 and the efficiency of isotope separation for Mg is smaller than it is for Ca yet similar to that observed for Mg in natural liquids. The results from the experiments reported here, in combination with results from natural volcanic liquids, show clearly that the efficiency of diffusive separation of Ca isotopes is systematically related to the solvent-normalized diffusivity—the ratio of the diffusivity of the cation (D{sub Ca}) to the diffusivity of silicon (D{sub Si}). The results on Ca isotopes are consistent with available data on Fe, Li, and Mg isotopes in silicate liquids, when considered in terms of the parameter D{sub cation

  19. s-Process Os isotope enrichment in ureilites by planetary processing

    Science.gov (United States)

    Goderis, S.; Brandon, A. D.; Mayer, B.; Humayun, M.

    2015-12-01

    Ubiquitous nucleosynthetic isotope anomalies relative to the terrestrial isotopic composition in Mo, Ru, and other elements are known from both bulk chondrites and differentiated meteorites, but Os isotope ratios reported from such meteorites have been found to be indistinguishable from the terrestrial value. The carriers of s- and r-process Os must thus have been homogeneously distributed in the solar nebula. As large Os isotope anomalies are known from acid leachates and residues of primitive chondrites, the constant relative proportions of presolar s- and r-process carriers in such chondrites must have been maintained during nebular processes. It has long been assumed that partial melting of primitive chondrites would homogenize the isotopic heterogeneity carried by presolar grains. Here, ureilites, carbon-rich ultramafic achondrites dominantly composed of olivine and low-Ca pyroxene, are shown to be the first differentiated bulk Solar System materials for which nucleosynthetic Os isotope anomalies have been identified. These anomalies consist of enrichment in s-process Os heterogeneously distributed in different ureilites. Given the observed homogeneity of Os isotopes in all types of primitive chondrites, this Os isotope variability among ureilites must have been caused by selective removal of s-process-poor Os host phases, probably metal, during rapid localized melting on the ureilite parent body. While Mo and Ru isotope anomalies for all meteorites measured so far exhibit s-process deficits relative to the Earth, the opposite holds for the Os isotope anomalies in ureilites reported here. This might indicate that the Earth preferentially accreted olivine-rich restites and inherited a s-process excess relative to smaller meteorite bodies, consistent with Earth's high Mg/Si ratio and enrichment of s-process nuclides in Mo, Ru, and Nd isotopes. Our new Os isotope results imply that caution must be used when applying nucleosynthetic isotope anomalies as provenance

  20. Advanced Environmental Barrier Coating Development for SiC/SiC Ceramic Matrix Composites: NASA's Perspectives

    Science.gov (United States)

    Zhu, Dongming

    2016-01-01

    This presentation reviews NASA environmental barrier coating (EBC) system development programs and the coating materials evolutions for protecting the SiC/SiC Ceramic Matrix Composites in order to meet the next generation engine performance requirements. The presentation focuses on several generations of NASA EBC systems, EBC-CMC component system technologies for SiC/SiC ceramic matrix composite combustors and turbine airfoils, highlighting the temperature capability and durability improvements in simulated engine high heat flux, high pressure, high velocity, and with mechanical creep and fatigue loading conditions. The current EBC development emphasis is placed on advanced NASA 2700F candidate environmental barrier coating systems for SiC/SiC CMCs, their performance benefits and design limitations in long-term operation and combustion environments. Major technical barriers in developing environmental barrier coating systems, the coating integrations with next generation CMCs having the improved environmental stability, erosion-impact resistance, and long-term fatigue-environment system durability performance are described. The research and development opportunities for advanced turbine airfoil environmental barrier coating systems by utilizing improved compositions, state-of-the-art processing methods, and simulated environment testing and durability modeling are discussed.

  1. Development and Characterization of SiC)/ MoSi2-Si3N4(p) Hybrid Composites

    Science.gov (United States)

    Hebsur, Mohan G.

    1998-01-01

    Intermetallic compound MoSi2 has long been known as a high temperature material that has excellent oxidation resistance and electrical/thermal conductivity. Also its low cost, high melting point (2023 C), relatively low density (6.2 g/cu cm versus 9 g/cu cm for current engine materials), and ease of machining, make it an attractive structural material. However, the use of MoSi2 has been hindered due to its poor toughness at low temperatures, poor creep resistance at high temperatures, and accelerated oxidation (also known as 'pest' oxidation) at temperatures between approximately 450 and 550 C. Continuous fiber reinforcing is very effective means of improving both toughness and strength. Unfortunately, MoSi2 has a relatively high coefficient of thermal expansion (CTE) compared to potential reinforcing fibers such as SiC. The large CTE mismatch between the fiber and the matrix resulted in severe matrix cracking during thermal cycling. Addition of about 30 to 50 vol % of Si3N4 particulate to MoSi2 improved resistance to low temperature accelerated oxidation by forming a Si2ON2 protective scale and thereby eliminating catastrophic 'pest failure'. The Si3N4 addition also improved the high temperature creep strength by nearly five orders of magnitude, doubled the room temperature toughness and significantly lowered the CTE of the MoSi2 and eliminated matrix cracking in SCS-6 reinforced composites even after thermal cycling. The SCS-6 fiber reinforcement improved the room temperature fracture toughness by seven times and impact resistance by five times. The composite exhibited excellent strength and toughness improvement up to 1400 C. More recently, tape casting was adopted as the preferred processing of MoSi2-base composites for improved fiber spacing, ability to use small diameter fibers, and for lower cost. Good strength and toughness values were also obtained with fine diameter Hi-Nicalon tow fibers. This hybrid composite remains competitive with ceramic matrix

  2. Modes of planetary-scale Fe isotope fractionation

    Science.gov (United States)

    Schoenberg, Ronny; Blanckenburg, Friedhelm von

    2006-12-01

    Fe isotope composition of lithospheric mantle xenoliths are representative for an undisturbed melt source, and second, HED and SNC meteorites, representing melting products of 4Vesta and Mars silicate mantles would be expected to show a similar fractionation towards heavy isotope compositions. This is not observed. Four international granitoid standards with SiO 2 contents between 60 and 70 wt.% yield δ56Fe/ 54Fe values between 0.118‰ and 0.132‰. An investigation of the alpine Bergell igneous rock suite revealed a positive correlation between Fe isotope compositions and SiO 2 contents — from gabbros and tonalites ( δ56Fe/ 54Fe ≈ 0.03 to 0.09‰) to granodiorites and silicic dykes ( δ56Fe/ 54Fe ≈ 0.14 to 0.23‰). Although in this suite δ56Fe/ 54Fe correlates with δ18O values and radiogenic isotopes, open-system behavior to explain the heavy iron is not undisputed. This is because an obvious assimilant with the required heavy Fe isotope composition has so far not been identified. Alternatively, the relatively heavy granite compositions might be obtained by fractional crystallisation of the melt. Ultimately, further detailed studies on natural rocks and the experimental determination of mineral/melt fractionation factors at magmatic conditions are required to unravel whether or not iron isotope fractionation takes place during partial mantle melting and crystal fractionation.

  3. Discoveries of isotopes by fission

    Indian Academy of Sciences (India)

    M Thoennessen

    2015-09-01

    Of the about 3000 isotopes presently known, about 20% have been discovered in fission. The history of fission as it relates to the discovery of isotopes as well as the various reaction mechanisms leading to isotope discoveries involving fission are presented.

  4. Graphene/SiC(0001) interface structures induced by Si intercalation and their influence on electronic properties of graphene

    Science.gov (United States)

    Visikovskiy, Anton; Kimoto, Shin-ichi; Kajiwara, Takashi; Yoshimura, Masamichi; Iimori, Takushi; Komori, Fumio; Tanaka, Satoru

    2016-12-01

    Epitaxial graphene growth on SiC surfaces is considered advantageous in terms of device application. However, the first graphitic layer on SiC transforms to a buffer layer because of strong coupling with the substrate. The properties of several subsequent layers are also significantly degraded. One method to decouple graphene from the substrate is Si intercalation. In the present work, we report observation and analysis of interface structures formed by Si intercalation in between the graphene layer and the SiC(0001) surface depending on Si coverage and influence of these interfaces on graphene electronic structure by means of low-energy electron diffraction (LEED), scanning tunneling microscopy (STM), angle-resolved photoemission spectroscopy (ARPES), and theoretical first-principles calculations. The STM appearance of observed periodic interface structures strongly resembles previously known Si-rich phases on the SiC(0001) surface. Based on the observed range of interface structures we discuss the mechanism of graphene layer decoupling and differences in stability of the Si-rich phases on clean SiC(0001) and in the graphene/SiC(0001) interface region. We also discuss a possibility to tune graphene electronic properties by interface engineering.

  5. Film Cooled Recession of SiC/SiC Ceramic Matrix Composites: Test Development, CFD Modeling and Experimental Observations

    Science.gov (United States)

    Zhu, Dongming; Sakowski, Barbara A.; Fisher, Caleb

    2014-01-01

    SiCSiC ceramic matrix composites (CMCs) systems will play a crucial role in next generation turbine engines for hot-section component applications because of their ability to significantly increase engine operating temperatures, reduce engine weight and cooling requirements. However, the environmental stability of Si-based ceramics in high pressure, high velocity turbine engine combustion environment is of major concern. The water vapor containing combustion gas leads to accelerated oxidation and corrosion of the SiC based ceramics due to the water vapor reactions with silica (SiO2) scales forming non-protective volatile hydroxide species, resulting in recession of the ceramic components. Although environmental barrier coatings are being developed to help protect the CMC components, there is a need to better understand the fundamental recession behavior of in more realistic cooled engine component environments.In this paper, we describe a comprehensive film cooled high pressure burner rig based testing approach, by using standardized film cooled SiCSiC disc test specimen configurations. The SiCSiC specimens were designed for implementing the burner rig testing in turbine engine relevant combustion environments, obtaining generic film cooled recession rate data under the combustion water vapor conditions, and helping developing the Computational Fluid Dynamics (CFD) film cooled models and performing model validation. Factors affecting the film cooled recession such as temperature, water vapor concentration, combustion gas velocity, and pressure are particularly investigated and modeled, and compared with impingement cooling only recession data in similar combustion flow environments. The experimental and modeling work will help predict the SiCSiC CMC recession behavior, and developing durable CMC systems in complex turbine engine operating conditions.

  6. Layered Systems Engineering Engines

    Science.gov (United States)

    Breidenthal, Julian C.; Overman, Marvin J.

    2009-01-01

    A notation is described for depicting the relationships between multiple, contemporaneous systems engineering efforts undertaken within a multi-layer system-of-systems hierarchy. We combined the concepts of remoteness of activity from the end customer, depiction of activity on a timeline, and data flow to create a new kind of diagram which we call a "Layered Vee Diagram." This notation is an advance over previous notations because it is able to be simultaneously precise about activity, level of granularity, product exchanges, and timing; these advances provide systems engineering managers a significantly improved ability to express and understand the relationships between many systems engineering efforts. Using the new notation, we obtain a key insight into the relationship between project duration and the strategy selected for chaining the systems engineering effort between layers, as well as insights into the costs, opportunities, and risks associated with alternate chaining strategies.

  7. Engineer Ethics

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Dae Sik; Kim, Yeong Pil; Kim, Yeong Jin

    2003-03-15

    This book tells of engineer ethics such as basic understanding of engineer ethics with history of engineering as a occupation, definition of engineering and specialized job and engineering, engineer ethics as professional ethics, general principles of ethics and its limitation, ethical theory and application, technique to solve the ethical problems, responsibility, safety and danger, information engineer ethics, biotechnological ethics like artificial insemination, life reproduction, gene therapy and environmental ethics.

  8. Microwave joining of SiC ceramics and composites

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, I.; Silberglitt, R.; Tian, Y.L. [FM Technologies, Inc., Fairfax, VA (United States); Katz, J.D. [Los Alamos National Lab., NM (United States)

    1997-04-01

    Potential applications of SiC include components for advanced turbine engines, tube assemblies for radiant burners and petrochemical processing and heat exchangers for high efficiency electric power generation systems. Reliable methods for joining SiC are required in order to cost-effectively fabricate components for these applications from commercially available shapes and sizes. This manuscript reports the results of microwave joining experiments performed using two different types of SiC materials. The first were on reaction bonded SiC, and produced joints with fracture toughness equal to or greater than that of the base material over an extended range of joining temperatures. The second were on continuous fiber-reinforced SiC/SiC composite materials, which were successfully joined with a commercial active brazing alloy, as well as by using a polymer precursor.

  9. GEOCHRONOMETRY ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20040631 Chen Jiangfeng (School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui) ; Xie Zhi Relationships Between Rb-Sr, Ar - Ar Geochronometers and Oxygen Isotopic Equilibrium of Intrusions from Eastern Anhui Province, China (Geological Journal of China Universities, ISSN 1006 - 7493, CN 32 -

  10. GEOCHRONOMETRY & ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20090432 Zhou Shuqing (School of Energy Resources, China University of Geosciences Beijing 100083, China); Huang Haiping Stable Isotopic Records vs. Important Events in Life Evolution and the Concurrent Environment (Geological Review, ISSN0371-5736, CN11-1952, 54(2), 2008, p.225-231, 3 illus., 1 table, 77 refs.)

  11. GEOCHRONOMETRY & ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20141014Wang Hairan(State Key Laboratory of Continental Dynamics,Department of Geology,Northwest University,Xi’an710069,China);Zhao Hongge Theory and Application of Zircon U-Pb Isotope Dating Technique(Geology and Resources,ISSN1671-1947,CN21-1458/P,22(3),2013,p.229

  12. GEOCHRONOMETRY & ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20072750 Huang Sijing(State Key Laboratory of Oil/Gas Reservoir Geology and Exploitation,Chengdu University of Technology,Chengdu 610059,China);Pei Changrong Age Calibration for the Boundary between Lower and Middle Triassic by Strontium Isotope Stratigraphy in Eastern Sichuan Province

  13. GEOCHRONOMETRY & ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20070454 Bao Zengkuan (Institute of High Energy Physics, CAS, Beijing 100049, China); Yuan Wanming Apatite (U-Th)/He Dating and Its Application (Acta Petrologica et Mineralogica, ISSN1000-6524, CN11-1966/P, 24(2), 2005, p.126-132, 2 illus., 25 refs.) Key words: isotopic geochronology

  14. Isotopic Implicit Surface Meshing

    NARCIS (Netherlands)

    Boissonnat, Jean-Daniel; Cohen-Steiner, David; Vegter, Gert

    2004-01-01

    This paper addresses the problem of piecewise linear approximation of implicit surfaces. We first give a criterion ensuring that the zero-set of a smooth function and the one of a piecewise linear approximation of it are isotopic. Then, we deduce from this criterion an implicit surface meshing algor

  15. Isotope hydrograph separation

    Energy Technology Data Exchange (ETDEWEB)

    Fritz, P. [UFZ-Umweltforschungszentrum, Centre of Environmental Research Leipzig-Halle, Leipzig (Germany)

    2000-07-01

    Storm-runoff thus reflects the complex hydraulic behaviour of drainage basins and water-links of such systems. Water of different origin may participate in the events and in this lecture, the application of isotope techniques to separate storm hydrographs into different components will be presented.

  16. Forensic Stable Isotope Biogeochemistry

    Science.gov (United States)

    Cerling, Thure E.; Barnette, Janet E.; Bowen, Gabriel J.; Chesson, Lesley A.; Ehleringer, James R.; Remien, Christopher H.; Shea, Patrick; Tipple, Brett J.; West, Jason B.

    2016-06-01

    Stable isotopes are being used for forensic science studies, with applications to both natural and manufactured products. In this review we discuss how scientific evidence can be used in the legal context and where the scientific progress of hypothesis revisions can be in tension with the legal expectations of widely used methods for measurements. Although this review is written in the context of US law, many of the considerations of scientific reproducibility and acceptance of relevant scientific data span other legal systems that might apply different legal principles and therefore reach different conclusions. Stable isotopes are used in legal situations for comparing samples for authenticity or evidentiary considerations, in understanding trade patterns of illegal materials, and in understanding the origins of unknown decedents. Isotope evidence is particularly useful when considered in the broad framework of physiochemical processes and in recognizing regional to global patterns found in many materials, including foods and food products, drugs, and humans. Stable isotopes considered in the larger spatial context add an important dimension to forensic science.

  17. Isotopic tracing of ore-forming source materials for Dexing porphyry copper deposit of Jiangxi, China

    Institute of Scientific and Technical Information of China (English)

    Peng QIAN; Jianjun LU

    2008-01-01

    Dexing copper deposit is the biggest porphyry copper deposit in China. By researching isotopes of C,Si and Cu from the samples of Tongchang and Fujiawu ore-field, the authors found that δ13CPDB values of siderite were close to the δ13CPDB value of original magma; δ30Si values of the samples at the ore-forming stage were close to the δ30Si value range of magma, δ30Si values of partial samples were far away from it; Cu isotopic compositions of massive chalcopyrite formed at the early ore-forming stage are higher than that of veinal chalcopyrite formed at the later ore-forming stage. The results show that ore-forming materials were mainly derived from the porphyry body, and part of them were from wall rock materials.

  18. Aperiodic SiSn/Si multilayers for thermoelectric applications

    Science.gov (United States)

    Tonkikh, A. A.; Zakharov, N. D.; Eisenschmidt, C.; Leipner, H. S.; Werner, P.

    2014-04-01

    We report on novel defect-free SiSn/Si heterostructures grown pseudomorphically on Si(001) substrates using temperature-modulated molecular beam epitaxy. This approach results in a sustainable epitaxial growth for SiSn/Si multilayers. Transmission electron microscopy and electron diffraction manifest that SiSn layers possess a diamond lattice structure. X-ray diffraction reveals up to 9.5 at% Sn in the crystal lattice of SiSn layers.

  19. 40 CFR 60.4235 - What fuel requirements must I meet if I am an owner or operator of a stationary SI gasoline fired...

    Science.gov (United States)

    2010-07-01

    ... am an owner or operator of a stationary SI gasoline fired internal combustion engine subject to this... What fuel requirements must I meet if I am an owner or operator of a stationary SI gasoline fired internal combustion engine subject to this subpart? Owners and operators of stationary SI ICE subject...

  20. Phase Stability and Thermal Conductivity of Composite Environmental Barrier Coatings on SiC/SiC Ceramic Matrix Composites

    Science.gov (United States)

    Benkel, Samantha; Zhu, Dongming

    2011-01-01

    Advanced environmental barrier coatings are being developed to protect SiC/SiC ceramic matrix composites in harsh combustion environments. The current coating development emphasis has been placed on the significantly improved cyclic durability and combustion environment stability in high-heat-flux and high velocity gas turbine engine environments. Environmental barrier coating systems based on hafnia (HfO2) and ytterbium silicate, HfO2-Si nano-composite bond coat systems have been processed and their stability and thermal conductivity behavior have been evaluated in simulated turbine environments. The incorporation of Silicon Carbide Nanotubes (SiCNT) into high stability (HfO2) and/or HfO2-silicon composite bond coats, along with ZrO2, HfO2 and rare earth silicate composite top coat systems, showed promise as excellent environmental barriers to protect the SiC/SiC ceramic matrix composites.

  1. Silane activation by laser-ablated Be atoms: Formation of HBeSiH3 and HBe(μ-H)3Si molecules

    Science.gov (United States)

    Zhao, Jie; Yu, Wenjie; Xu, Bing; Huang, Tengfei; Wang, Xuefeng

    2017-03-01

    Laser-ablated beryllium atoms have been reacted with silane molecules during condensation in excess neon and argon at 4 K. Absorptions due to HBeSiH3 and HBe(μ-H)3Si were observed and identified on the basis of isotopic IR spectroscopy, deuterium substitution with SiD4, and quantum chemical frequency calculations. The observed results show excited Be atom (1P1:2s12p1) can insert into Sisbnd H bond spontaneously and the insertion product rearranges to HBe(μ-H)3Si upon photolysis. The electron localization function (ELF) analysis suggests that 3c-2e hydrogen bridge bond (Besbnd Hsbnd Si) was formed by the donation of electrons for Sisbnd H σ bond to the empty p orbital of Be atom for HBe(μ-H)3Si molecule, which shows much difference from Csbnd H bond complexes.

  2. Four Engineers...

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    There are four engineers traveling in a car;a mechanical engineer,a chemical engi-neer,an electrical engineer and a comput-er engineer.The car breaks down.“Sounds to me as if the pistons have seized.We ll have to strip down the engine before we canget the car working again,”says the mechanical

  3. Water isotopes in desiccating lichens

    Science.gov (United States)

    Cuntz, Matthias; Máguas, Cristina; Lakatos, Michael

    2009-01-01

    The stable isotopic composition of water is routinely used as a tracer to study water exchange processes in vascular plants and ecosystems. To date, no study has focussed on isotope processes in non-vascular, poikilohydric organisms such as lichens and bryophytes. To understand basic isotope exchange processes of non-vascular plants, thallus water isotopic composition was studied in various green-algal lichens exposed to desiccation. The study indicates that lichens equilibrate with the isotopic composition of surrounding water vapour. A model was developed as a proof of concept that accounts for the specific water relations of these poikilohydric organisms. The approach incorporates first their variable thallus water potential and second a compartmentation of the thallus water into two isotopically distinct but connected water pools. Moreover, the results represent first steps towards the development of poikilohydric organisms as a recorder of ambient vapour isotopic composition. PMID:19888598

  4. The Oceanic Biogeochemical Cycle of Zinc and Its Isotopes

    Science.gov (United States)

    Vance, D.; Little, S. H.; de Souza, G. F.; Cullen, J. T.; Lohan, M. C.

    2014-12-01

    Zinc (Zn) is the most abundant trace metal in the phytoplankton that dominate vertical carbon export in the ocean, the diatoms. But the strong relationship between the vertical distributions of Zn and the silicon (Si) that makes up the opal hard parts of diatoms represents a long-standing puzzle. Zn is overwhelmingly co-located with phosphate in the organic matter of diatom cells, not with Si in opal, and is regenerated with phosphate in the upper ocean, not with Si in the deep. The resolution of this apparent paradox is key both to an understanding of the global oceanic cycling of Zn, and to the rates and mechanisms by which biologically-assimilated trace metals are returned to the photic zone. Here, we show that oceanic dissolved Zn exhibits significant isotopic variation in the upper ocean that is consistent with vertical cycling. However, we suggest that the isotopically homogeneous global deep ocean Zn pool is largely sourced from the Southern Ocean. This leads to a new view of the global oceanic cycling of this important trace metal, one that is consistent with the unique physiology of Southern Ocean diatoms, the coupling of Zn and Si in the global deep ocean, and the emerging paradigm for global ocean nutrient dynamics. Our data and interpretation imply a small Zn pool that is biologically cycled in the upper ocean, but is to a great extent decoupled from the much larger Southern-Ocean-dominated deep ocean pool.

  5. Evidence for depletion of heavy silicon isotopes at comet 67P/Churyumov-Gerasimenko

    Science.gov (United States)

    Rubin, M.; Altwegg, K.; Balsiger, H.; Berthelier, J.-J.; Bieler, A.; Calmonte, U.; Combi, M.; De Keyser, J.; Engrand, C.; Fiethe, B.; Fuselier, S. A.; Gasc, S.; Gombosi, T. I.; Hansen, K. C.; Hässig, M.; Le Roy, L.; Mezger, K.; Tzou, C.-Y.; Wampfler, S. F.; Wurz, P.

    2017-05-01

    Context. The Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) was designed to measure the composition of the gas in the coma of comet 67P/Churyumov-Gerasimenko, the target of the European Space Agency's Rosetta mission. In addition to the volatiles, ROSINA measured refractories sputtered off the comet by the interaction of solar wind protons with the surface of the comet. Aims: The origin of different solar system materials is still heavily debated. Isotopic ratios can be used to distinguish between different reservoirs and investigate processes occurring during the formation of the solar system. Methods: ROSINA consisted of two mass spectrometers and a pressure sensor. In the ROSINA Double Focusing Mass Spectrometer (DFMS), the neutral gas of cometary origin was ionized and then deflected in an electric and a magnetic field that separated the ions based on their mass-to-charge ratio. The DFMS had a high mass resolution, dynamic range, and sensitivity that allowed detection of rare species and the known major volatiles. Results: We measured the relative abundance of all three stable silicon isotopes with the ROSINA instrument on board the Rosetta spacecraft. Furthermore, we measured 13C/12C in C2H4, C2H5, and CO. The DFMS in situ measurements indicate that the average silicon isotopic composition shows depletion in the heavy isotopes 29Si and 30Si with respect to 28Si and solar abundances, while 13C to 12C is analytically indistinguishable from bulk planetary and meteorite compositions. Although the origin of the deficiency of the heavy silicon isotopes cannot be explained unambiguously, we discuss mechanisms that could have contributed to the measured depletion of the isotopes 29Si and 30Si.

  6. Carbon isotopic characterization of formaldehyde emitted by vehicles in Guangzhou, China

    Science.gov (United States)

    Hu, Ping; Wen, Sheng; Liu, Yonglin; Bi, Xinhui; Chan, Lo Yin; Feng, Jialiang; Wang, Xinming; Sheng, Guoying; Fu, Jiamo

    2014-04-01

    Formaldehyde (HCHO) is the most abundant carbonyl compound in the atmosphere, and vehicle exhaust emission is one of its important anthropogenic sources. However, there is still uncertainty regarding HCHO flux from vehicle emission as well as from other sources. Herein, automobile source was characterized using HCHO carbon isotopic ratio to assess its contributions to atmospheric flux and demonstrate the complex production/consumption processes during combustion in engine cylinder and subsequent catalytic treatment of exhaust. Vehicle exhausts were sampled under different idling states and HCHO carbon isotopic ratios were measured by gas chromatograph-combustion-isotopic ratio mass spectrometry (GC-C-IRMS). The HCHO directly emitted from stand-alone engines (gasoline and diesel) running at different load was also sampled and measured. The HCHO carbon isotopic ratios were from -30.8 to -25.7‰ for gasoline engine, and from -26.2 to -20.7‰ for diesel engine, respectively. For diesel vehicle without catalytic converter, the HCHO carbon isotopic ratios were -22.1 ± 2.1‰, and for gasoline vehicle with catalytic converter, the ratios were -21.4 ± 0.7‰. Most of the HCHO carbon isotopic ratios were heavier than the fuel isotopic ratios (from -29 to -27‰). For gasoline vehicle, the isotopic fractionation (Δ13C) between HCHO and fuel isotopic ratios was 7.4 ± 0.7‰, which was higher than that of HCHO from stand-alone gasoline engine (Δ13Cmax = 2.7‰), suggesting additional consumption by the catalytic converter. For diesel vehicle without catalytic converter, Δ13C was 5.7 ± 2.0‰, similar to that of stand-alone diesel engine. In general, the carbon isotopic signatures of HCHO emitted from automobiles were not sensitive to idling states or to other vehicle parameters in our study condition. On comparing these HCHO carbon isotopic data with those of past studies, the atmospheric HCHO in a bus station in Guangzhou might mainly come from vehicle emission for

  7. Chromium isotope variations

    DEFF Research Database (Denmark)

    D'Arcy, Joan Mary

    is incorporated into carbonates. Hence, ancient carbonates can potentially record the Cr isotopic composition (δ53Cr ‰) of seawater in the geological past. Reliable application and interpretation of this proxy requires a detailed knowledge about processes that fractionate Cr on the Earth’s surface...... deposited during the Early Ordovician — a time of known redox instability in ancient oceans – exhibit a significant positive Cr isotope excursion of +0.5‰. This excursion is interpreted as the reductive drawn down of dissolved Cr in seawater in response to the development of a proximal anoxic sink...... of ancient marine sediments can be a useful tool for understanding the cycling of redox sensitive elements on a local scale....

  8. Performance and driveline analyses of engine capacity in range extender engine hybrid vehicle

    Science.gov (United States)

    Praptijanto, Achmad; Santoso, Widodo Budi; Nur, Arifin; Wahono, Bambang; Putrasari, Yanuandri

    2017-01-01

    In this study, range extender engine designed should be able to meet the power needs of a power generator of hybrid electrical vehicle that has a minimum of 18 kW. Using this baseline model, the following range extenders will be compared between conventional SI piston engine (Baseline, BsL), engine capacity 1998 cm3, and efficiency-oriented SI piston with engine capacity 999 cm3 and 499 cm3 with 86 mm bore and stroke square gasoline engine in the performance, emission prediction of range extender engine, standard of charge by using engine and vehicle simulation software tools. In AVL Boost simulation software, range extender engine simulated from 1000 to 6000 rpm engine loads. The highest peak engine power brake reached up to 38 kW at 4500 rpm. On the other hand the highest torque achieved in 100 Nm at 3500 rpm. After that using AVL cruise simulation software, the model of range extended electric vehicle in series configuration with main components such as internal combustion engine, generator, electric motor, battery and the arthemis model rural road cycle was used to simulate the vehicle model. The simulation results show that engine with engine capacity 999 cm3 reported the economical performances of the engine and the emission and the control of engine cycle parameters.

  9. Airborne Emissions from Si/FeSi Production

    Science.gov (United States)

    Kero, Ida; Grådahl, Svend; Tranell, Gabriella

    2017-02-01

    The management of airborne emissions from silicon and ferrosilicon production is, in many ways, similar to the management of airborne emissions from other metallurgical industries, but certain challenges are highly branch-specific, for example the dust types generated and the management of NO X emissions by furnace design and operation. A major difficulty in the mission to reduce emissions is that information about emission types and sources as well as abatement and measurement methods is often scarce, incomplete and scattered. The sheer diversity and complexity of the subject presents a hurdle, especially for new professionals in the field. This article focuses on the airborne emissions from Si and FeSi production, including greenhouse gases, nitrogen oxides, airborne particulate matter also known as dust, polyaromatic hydrocarbons and heavy metals. The aim is to summarize current knowledge in a state-of-the-art overview intended to introduce fresh industry engineers and academic researchers to the technological aspects relevant to the reduction of airborne emissions.

  10. Airborne Emissions from Si/FeSi Production

    Science.gov (United States)

    Kero, Ida; Grådahl, Svend; Tranell, Gabriella

    2016-10-01

    The management of airborne emissions from silicon and ferrosilicon production is, in many ways, similar to the management of airborne emissions from other metallurgical industries, but certain challenges are highly branch-specific, for example the dust types generated and the management of NO X emissions by furnace design and operation. A major difficulty in the mission to reduce emissions is that information about emission types and sources as well as abatement and measurement methods is often scarce, incomplete and scattered. The sheer diversity and complexity of the subject presents a hurdle, especially for new professionals in the field. This article focuses on the airborne emissions from Si and FeSi production, including greenhouse gases, nitrogen oxides, airborne particulate matter also known as dust, polyaromatic hydrocarbons and heavy metals. The aim is to summarize current knowledge in a state-of-the-art overview intended to introduce fresh industry engineers and academic researchers to the technological aspects relevant to the reduction of airborne emissions.

  11. GEOCHRONOMETRY & ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    <正>20050934 Chen Zhihong (Chinese Academy of Geological Sciences, Beijing 100037, China); Lu Songnian Age of the Fushui Intermediate-Mafic Intrusive Complex in the Qinling Orogen, New Zircon U - Pb and Whole -Rock Sm and Nd Isotope Chronological Evidence (Geological Bulletin of China, ISSN 1671-2552, CN11-4648/P, 23(4), 2004, p. 322-328, 3 illus. , 3 tables, 10 refs. )

  12. GEOCHRONOMETRY &ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20131727 Huang Xiaowen(State Key Laboratory of Ore Deposit Geochemistry,Institute of Geochemistry,Chinese Academy of Sciences,Guiyang 550002,China);Qi Liang Preliminary Study on Sample-Preparation for Re-Os Isotopic Dating of Pyrite(Geochimica,ISSN0379-1726,CN44-1398/P,41(4),2012,p.380-386,3illus.,2tables,25refs)Key words:pyrite,Re-Os dating

  13. GEOCHRONOMETRY & ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20132601 Cui Yurong(Tianjin Institute of Geology and Mineral Resources,China Geological Survey,Tianjin 300170,China);Zhou Hongying In Situ LA-MC-ICP-MS U-Pb Isotopic Dating of Monazite(Acta Geoscientica Sinica,ISSN0375-5444,CN11-1856/P,33(6),2012,p.865-876,6illus.,4tables,41refs.)Key words:monazite,U-Pb dating

  14. Prose Writer Si Yu

    Institute of Scientific and Technical Information of China (English)

    1996-01-01

    SI Yu, pen name of Zhan Shaojuan, is well known through her prose works. During the recent more than ten years, Chinese prose writing has developed rapidly, from its previous level to the present flourishing conditions. Si Yu is a distinguished woman writer, whose creative prose alternately displays either

  15. ISOTOPE METHODS IN HOMOGENEOUS CATALYSIS.

    Energy Technology Data Exchange (ETDEWEB)

    BULLOCK,R.M.; BENDER,B.R.

    2000-12-01

    The use of isotope labels has had a fundamentally important role in the determination of mechanisms of homogeneously catalyzed reactions. Mechanistic data is valuable since it can assist in the design and rational improvement of homogeneous catalysts. There are several ways to use isotopes in mechanistic chemistry. Isotopes can be introduced into controlled experiments and followed where they go or don't go; in this way, Libby, Calvin, Taube and others used isotopes to elucidate mechanistic pathways for very different, yet important chemistries. Another important isotope method is the study of kinetic isotope effects (KIEs) and equilibrium isotope effect (EIEs). Here the mere observation of where a label winds up is no longer enough - what matters is how much slower (or faster) a labeled molecule reacts than the unlabeled material. The most careti studies essentially involve the measurement of isotope fractionation between a reference ground state and the transition state. Thus kinetic isotope effects provide unique data unavailable from other methods, since information about the transition state of a reaction is obtained. Because getting an experimental glimpse of transition states is really tantamount to understanding catalysis, kinetic isotope effects are very powerful.

  16. Stellar Origins of Extremely $^{\\text{13}}C$- and $^{15}N$-enriched Presolar SiC Grains: Novae or Supernovae?

    CERN Document Server

    Liu, Nan; Alexander, Conel M O'D; Wang, Jianhuan; Pignatari, Marco; Jose, Jordi; Nguyen, Ann

    2016-01-01

    Extreme excesses of $^{13}C$ ($^{12}C$/$^{13}C$<10) and $^{15}N$ ($^{14}N$/$^{15}N$<20) in rare presolar SiC grains have been considered diagnostic of an origin in classical novae, though an origin in core collapse supernovae (CCSNe) has also been proposed. We report C, N, and Si isotope data for 14 submicron- to micron-sized $^{13}C$- and $^{15}N$-enriched presolar SiC grains ($^{12}C$/$^{13}C$<16 and $^{14}N$/$^{15}N$<~100) from Murchison, and their correlated Mg-Al, S, and Ca-Ti isotope data when available. These grains are enriched in $^{13}C$ and $^{15}N$, but with quite diverse Si isotopic signatures. Four grains with $^{29,30}Si$ excesses similar to those of type C SiC grains likely came from CCSNe, which experienced explosive H burning occurred during explosions. The independent coexistence of proton- and neutron-capture isotopic signatures in these grains strongly supports heterogeneous H ingestion into the He shell in pre-supernovae. Two of the seven putative nova grains with $^{30}Si$ e...

  17. Nuclear physics and stable isotopes; Physique nucleaire et isotopes stables

    Energy Technology Data Exchange (ETDEWEB)

    Goutte, D. [CEA Centre d`Etudes de Saclay, 91 - Gif-sur-Yvette (France). Dept. d`Astrophysique, de la Physique des Particules, de la Physique Nucleaire et de l`Instrumentation Associee

    1994-12-31

    The aim of this paper is to show that fundamental research in nuclear physics requires utilization of stable isotopes; stable isotopes are essential as target material since a large quantity of nucleus have to be studied in order to appreciate all the complexity of the nuclear structure, but also as a tool, such as beams, for the same purpose. Examples are given with samarium, tin and germanium isotopes. 7 figs.

  18. Engineering ceramics

    CERN Document Server

    Bengisu, Murat

    2001-01-01

    This is a comprehensive book applying especially to junior and senior engineering students pursuing Materials Science/ Engineering, Ceramic Engineering and Mechanical Engineering degrees. It is also a reference book for other disciplines such as Chemical Engineering, Biomedical Engineering, Nuclear Engineering and Environmental Engineering. Important properties of most engineering ceramics are given in detailed tables. Many current and possible applications of engineering ceramics are described, which can be used as a guide for materials selection and for potential future research. While covering all relevant information regarding raw materials, processing properties, characterization and applications of engineering ceramics, the book also summarizes most recent innovations and developments in this field as a result of extensive literature search.

  19. Engineering and Software Engineering

    Science.gov (United States)

    Jackson, Michael

    The phrase ‘software engineering' has many meanings. One central meaning is the reliable development of dependable computer-based systems, especially those for critical applications. This is not a solved problem. Failures in software development have played a large part in many fatalities and in huge economic losses. While some of these failures may be attributable to programming errors in the narrowest sense—a program's failure to satisfy a given formal specification—there is good reason to think that most of them have other roots. These roots are located in the problem of software engineering rather than in the problem of program correctness. The famous 1968 conference was motivated by the belief that software development should be based on “the types of theoretical foundations and practical disciplines that are traditional in the established branches of engineering.” Yet after forty years of currency the phrase ‘software engineering' still denotes no more than a vague and largely unfulfilled aspiration. Two major causes of this disappointment are immediately clear. First, too many areas of software development are inadequately specialised, and consequently have not developed the repertoires of normal designs that are the indispensable basis of reliable engineering success. Second, the relationship between structural design and formal analytical techniques for software has rarely been one of fruitful synergy: too often it has defined a boundary between competing dogmas, at which mutual distrust and incomprehension deprive both sides of advantages that should be within their grasp. This paper discusses these causes and their effects. Whether the common practice of software development will eventually satisfy the broad aspiration of 1968 is hard to predict; but an understanding of past failure is surely a prerequisite of future success.

  20. Electroluminescence from Si/SiO2 films deposited on p-Si substrates

    Institute of Scientific and Technical Information of China (English)

    马书懿; 萧勇; 陈辉

    2002-01-01

    The structure of Au/Si/SiO2/p-Si has been fabricated using the magnetron sputtering technique. It has a verygood rectifying behaviour. Visible electroluminescence (EL) has been observed from the Au/Si/SiO2/p-Si structureat a forward bias of 5V or larger. A broad band with one peak around 650-660 nm appears in all the EL spectra ofthe structure. The effects of the thickness of the Si layer in the Si/SiO2 films and of the input electrical power on ELspectra are studied systematically.

  1. Influence of Si on Interfacial Combination of SiCp/Al-Mg-Si Composite

    Institute of Scientific and Technical Information of China (English)

    Han Jianmin; Li Ronghua; Li Mingwei; Cui Shihai; Li Weijing; Wang Jinhua

    2004-01-01

    The scanning electron microscopy (SEM) analysis results of Si distribution in the interface between SiC reinforcements and aluminum matrix of a stir casting SiCp/Al-Mg-Si composite were presented. Results show that there is Si precipitation deposit on the interface of the composite and Si connects with SiC reinforcements in one side and connects with aluminum matrix in the other side. Si phase plays as a connecting bridge, which contributes to the interfacial combination of SiCp/Al composite.

  2. Nickel isotopes and methanogens

    Science.gov (United States)

    Neubeck, A.; Ivarsson, M.

    2013-12-01

    Methanogens require Ni for their growth and as a consequence the microbial fractionation of Ni isotopes can be used as a biomarker for activity of methanogenic communities1. Anaerobic laboratory experiments was performed using methanogens to investigate methanogenic growth in a modified nutrient media2 with olivine Fo91 (5g/l) added as an additional mineral nutrient source and as the only H2 provider. One of the investigated methanogens showed an increased growth in the experiments with added olivine. There were also a close relationship between the mobilized Ni and the growth of the methanogen. Ni is an element that previously has been neglected in the study of fossilized microorganisms and their interaction with mineral substrates and, thus, there are no records or published data of Ni in association with microfossils. However, we have detected enrichments of Ni in fossilized microorganisms and ichno-fossils, respectively, from three separate locations. Ni is not present in the host rock in any of the samples. Thus, Ni is present in association with fossilized microorganisms from environments and more extensive analysis is required to understand the magnitude, uptake, preservation and fractionation of Ni in microfossils. In order to analyze Ni isotope fractionation from microbe-mineral interaction, we plan to use a high-resolution Laser-Ablation Time-of-Flight Mass Spectrometer (LMS)3. In situ profile ablation will provide detailed and localized data on fractionation patterns between microfossils and their host rock. Also, this technique will allow us to identify the change in Ni isotopic fractionation in rock samples caused by abiotic and biogenic processes in a faster and easier way and with less risk for contamination compared to the wet chemistry analyses of Ni isotopes. 1. Cameron, V., Vance, D., Archer, C. & House, C. H. A biomarker based on the stable isotopes of nickel. Proceedings of the National Academy of Sciences 106, 10944-10948 (2009). 2. Schn

  3. Do Speleothem Stable Isotope Records Contain Hidden Tropical Cyclone Histories? Exploring C-O Isotope Correlation Patterns for Indicators of Tropical Cyclone Masking

    Science.gov (United States)

    Frappier, A. E.; Rossington, C.

    2013-12-01

    The newly-described tropical cyclone masking effect on stable isotope paleohydrological signals in speleothem records arises from the intermittent delivery of large pulses of isotopically distinct tropical cyclone rain. Recent work shows that 18-O depleted tropical cyclone stormwater depresses the δ18O value of speleothem calcite for months to years following a tropical cyclone event, masking the background stable isotope signal of persistent climate variability. Periods of high local storm activity can lead to speleothem calcite paleohydrological signals with significant wet biases on interannual to decadal timescales. Because speleothem carbon isotope ratios are independent of tropical cyclone rainfall, tropical speleothems are known to exhibit moderate C-O isotope covariation over time, periods when C-O isotope covariation breaks down and δ18O values are low may provide a marker for times when tropical cyclone masking is important. If so, existing speleothem stable isotope records from tropical cyclone-prone regions may contain signatures of tropical cyclone masking in the temporal evolution of C-O isotope covariation patterns. We present results from an exploratory analysis of several published speleothem records that are candidates for containing tropical cyclone masking signals. For each speleothem, overall C-O isotope covariation coefficients were calculated, and transient covariation patterns were analyzed using a sliding correlation index, the Covariation of Stable Isotopes (CoSI) index, and Local Correlation (LoCo). Local tropical cyclone historical and paleotempest records are compared and a method is presented to test for the presence of tropical cyclone masking intervals. The implications for speleothem paleoclimatology and paleotempestology are discussed.

  4. Therapeutic use of radioactive isotopes

    CERN Multimedia

    Caroline Duc

    2013-01-01

    In December, researchers from ISOLDE-CERN, the Paul Scherrer Institute (PSI) and the Institut Laue-Langevin (ILL) published the results of an in vivo study which successfully proved the effectiveness of four terbium isotopes for diagnosing and treating cancerous tumours.   Four terbium isotopes suitable for clinical purposes. “ISOLDE is the only installation capable of supplying terbium isotopes of such purity and intensity in the case of three out of the four types used in this study,” explains Karl Johnson, a physicist at ISOLDE.  “Producing over a thousand different isotopes, our equipment offers the widest choice of isotopes in the world!” Initially intended for fundamental physics research, ISOLDE has diversified its activities over time to invest in various projects in the materials science, biochemistry and nuclear medicine fields. The proof-of-concept study has confirmed that the four terbium isotopes 149Tb, 152Tb, 155Tb produ...

  5. Ti Isotopes: Echoes of Grain-Scale Heterogenaity in the Protoplanetary Disk

    Science.gov (United States)

    Jordan, M. K.; Kohl, I. E.; McCain, K. A.; Simon, J. I.; Young, E. D.

    2017-01-01

    Calcium-aluminum-rich inclusions (CAIs) are the oldest surviving solids to have formed in the Solar System. Their chemical and isotopic compositions provide a record of the conditions present in the protoplanetary disk where they formed and can aid our understanding of how solids formed in the solar nebula, an important step in the eventual process of planet building. The isotopic compositions of CAIs are primarily controlled by volatility. Evaporation/sublimation are well understood through both theory and experimental work to produce an enrichment in the heavy isotopes of an element, but less is understood about the effects of condensation. Mass-dependent fractionation can potentially provide a record of nebular condensation. Ti is not likely to experience evaporation due to its refractory nature, making it a useful tool for assessing the effects of condensation. We have undertaken a study of the stable isotope fractionation of Ti isotopes as a tracer of processes that predate the last evaporation events affecting CAIs. We compare the 49Ti/47Ti stable isotope ratio with excess 50Ti common in CAIs. We have collected Ti, Mg, Si, and Ca isotope data for a suite of CAIs in order to search for heterogeneity in each of these isotope systems, and for potential correlations among them. We compare our results to expectations for condensation.

  6. Interface engineering of Graphene-Silicon heterojunction solar cells

    Science.gov (United States)

    Xu, Dikai; Yu, Xuegong; Yang, Lifei; Yang, Deren

    2016-11-01

    Graphene has attracted great research interests due to its unique mechanical, electrical and optical properties, which opens up a huge number of opportunities for applications. Recently, Graphene-Silicon (Grsbnd Si) solar cell has been recognized as one interesting candidate for the future photovoltaic. Since the first Grsbnd Si solar cell reported in 2010, Grsbnd Si solar cell has been intensively investigated and the power converse efficiency (PCE) of it has been developed to 15.6%. This review presents and discusses current development of Grsbnd Si solar cell. Firstly, the basic concept and mechanism of Grsbnd Si solar cell are introduced. Then, several key technologies are introduced to improve the performance of Grsbnd Si solar cells, such as chemical doping, annealing, Si surface passivation and interlayer insertion. Particular emphasis is placed on strategies for Grsbnd Si interface engineering. Finally, new pathways and opportunities of "MIS-like structure" Grsbnd Si solar cells are described.

  7. Investigating and engineering spin-orbit torques in heavy metal/Co{sub 2}FeAl{sub 0.5}Si{sub 0.5}/MgO thin film structures

    Energy Technology Data Exchange (ETDEWEB)

    Loong, Li Ming; Deorani, Praveen; Qiu, Xuepeng; Yang, Hyunsoo, E-mail: eleyang@nus.edu.sg [Department of Electrical and Computer Engineering, National University of Singapore, Singapore 117576 (Singapore)

    2015-07-13

    Current-induced spin-orbit torques (SOTs) have the potential to revolutionize magnetization switching technology. Here, we investigate SOT in a heavy metal (HM)/Co{sub 2}FeAl{sub 0.5}Si{sub 0.5} (CFAS)/MgO thin film structure with perpendicular magnetic anisotropy (PMA), where the HM is either Pt or Ta. Our results suggest that both the spin Hall effect and the Rashba effect contribute significantly to the effective fields in the Pt underlayer samples. Moreover, after taking the PMA energies into account, current-induced SOT-based switching studies of both the Pt and Ta underlayer samples suggest that the two HM underlayers yield comparable switching efficiency in the HM/CFAS/MgO material system.

  8. Creep, Fatigue and Fracture Behavior of Environmental Barrier Coating and SiC-SiC Ceramic Matrix Composite Systems: The Role of Environment Effects

    Science.gov (United States)

    Zhu, Dongming; Ghosn, Louis J.

    2015-01-01

    Advanced environmental barrier coating (EBC) systems for low emission SiCSiC CMC combustors and turbine airfoils have been developed to meet next generation engine emission and performance goals. This presentation will highlight the developments of NASAs current EBC system technologies for SiC-SiC ceramic matrix composite combustors and turbine airfoils, their performance evaluation and modeling progress towards improving the engine SiCSiC component temperature capability and long-term durability. Our emphasis has also been placed on the fundamental aspects of the EBC-CMC creep and fatigue behaviors, and their interactions with turbine engine oxidizing and moisture environments. The EBC-CMC environmental degradation and failure modes, under various simulated engine testing environments, in particular involving high heat flux, high pressure, high velocity combustion conditions, will be discussed aiming at quantifying the protective coating functions, performance and durability, and in conjunction with damage mechanics and fracture mechanics approaches.

  9. Silicon isotope ratio measurements by inductively coupled plasma tandem mass spectrometry for alteration studies of nuclear waste glasses.

    Science.gov (United States)

    Gourgiotis, Alkiviadis; Ducasse, Thomas; Barker, Evelyne; Jollivet, Patrick; Gin, Stéphane; Bassot, Sylvain; Cazala, Charlotte

    2017-02-15

    High-level, long-lived nuclear waste arising from spent fuel reprocessing is vitrified in silicate glasses for final disposal in deep geologic formations. In order to better understand the mechanisms driving glass dissolution, glass alteration studies, based on silicon isotope ratio monitoring of (29)Si-doped aqueous solutions, were carried out in laboratories. This work explores the capabilities of the new type of quadrupole-based ICP-MS, the Agilent 8800 tandem quadrupole ICP-MS/MS, for accurate silicon isotope ratio determination for alteration studies of nuclear waste glasses. In order to avoid silicon polyatomic interferences, a new analytical method was developed using O2 as the reaction gas in the Octopole Reaction System (ORS), and silicon isotopes were measured in mass-shift mode. A careful analysis of the potential polyatomic interferences on SiO(+) and SiO2(+) ion species was performed, and we found that SiO(+) ion species suffer from important polyatomic interferences coming from the matrix of sample and standard solutions (0.5M HNO3). For SiO2(+), no interferences were detected, and thus, these ion species were chosen for silicon isotope ratio determination. A number of key settings for accurate isotope ratio analysis like, detector dead time, integration time, number of sweeps, wait time offset, memory blank and instrumental mass fractionation, were considered and optimized. Particular attention was paid to the optimization of abundance sensitivity of the quadrupole mass filter before the ORS. We showed that poor abundance sensitivity leads to a significant shift of the data away from the Exponential Mass Fractionation Law (EMFL) due to the spectral overlaps of silicon isotopes combined with different oxygen isotopes (i.e. (28)Si(16)O(18)O(+), (30)Si(16)O(16)O(+)). The developed method was validated by measuring a series of reference solutions with different (29)Si enrichment. Isotope ratio trueness, uncertainty and repeatability were found to be <0

  10. Study on the Effect of the Separating Unit Optimization on the Economy of Stable Isotope Separation

    OpenAIRE

    Yang, Kun; MOU Hong

    2015-01-01

    An economic criterion called as yearly net profit of single separating unit (YNPSSU) was presented to evaluate the influence of structure optimization on the economy. Using YNPSSU as a criterion, economic analysis was carried out for the structure optimization of separating unit in the case of separating SiF4 to obtain the 28Si and 29Si isotope. YNPSSU was calculated and compared with that before optimization. The results showed that YNPSSU was increased by 12.3% by the structure optimization...

  11. Lithium isotope separation by laser

    Energy Technology Data Exchange (ETDEWEB)

    Arisawa, T.; Maruyama, Y.; Suzuki, Y.; Shiba, K.

    1982-01-01

    A lithium isotope separation was performed using a laser isotope separation method. It was found that the lithium atoms with a natural isotopic abundance enhanced its /sup 6/Li concentration up to over 90% by tuning the laser wavelength to the /sup 2/Psub(1/2) of /sup 6/Li. Too high power, however, leads to a loss of enrichment due to the power broadening effect which was analysed by the equation of motion of density matrices.

  12. Radio-frequency integrated-circuit engineering

    CERN Document Server

    Nguyen, Cam

    2015-01-01

    Radio-Frequency Integrated-Circuit Engineering addresses the theory, analysis and design of passive and active RFIC's using Si-based CMOS and Bi-CMOS technologies, and other non-silicon based technologies. The materials covered are self-contained and presented in such detail that allows readers with only undergraduate electrical engineering knowledge in EM, RF, and circuits to understand and design RFICs. Organized into sixteen chapters, blending analog and microwave engineering, Radio-Frequency Integrated-Circuit Engineering emphasizes the microwave engineering approach for RFICs. Provide

  13. Environmental Barrier Coating Development for SiC/SiC Ceramic Matrix Composites: Recent Advances and Future Directions

    Science.gov (United States)

    Zhu, Dongming

    2016-01-01

    This presentation briefly reviews the SiC/SiC major environmental and environment-fatigue degradations encountered in simulated turbine combustion environments, and thus NASA environmental barrier coating system evolution for protecting the SiC/SiC Ceramic Matrix Composites for meeting the engine performance requirements. The presentation will review several generations of NASA EBC materials systems, EBC-CMC component system technologies for SiC/SiC ceramic matrix composite combustors and turbine airfoils, highlighting the temperature capability and durability improvements in simulated engine high heat flux, high pressure, high velocity, and with mechanical creep and fatigue loading conditions. This paper will also focus on the performance requirements and design considerations of environmental barrier coatings for next generation turbine engine applications. The current development emphasis is placed on advanced NASA candidate environmental barrier coating systems for SiC/SiC CMCs, their performance benefits and design limitations in long-term operation and combustion environments. The efforts have been also directed to developing prime-reliant, self-healing 2700F EBC bond coat; and high stability, lower thermal conductivity, and durable EBC top coats. Major technical barriers in developing environmental barrier coating systems, the coating integrations with next generation CMCs having the improved environmental stability, erosion-impact resistance, and long-term fatigue-environment system durability performance will be described. The research and development opportunities for turbine engine environmental barrier coating systems by utilizing improved compositions, state-of-the-art processing methods, and simulated environment testing and durability modeling will be briefly discussed.

  14. Cyclic oxidation study of MoSi{sub 2}-Si{sub 3}N{sub 4} base composites

    Energy Technology Data Exchange (ETDEWEB)

    Kowalik, R.W. [Naval Air Warfare Center, Patuxent River, MD (United States). Aircraft Div.; Hebsur, M.G. [NASA Lewis Research Center, Cleveland, OH 44135-3191 (United States)

    1999-03-15

    A series of MoSi{sub 2}-Si{sub 3}N{sub 4} base composites was evaluated for potential Navy gas turbine engine applications. The composites underwent cyclic oxidation testing to determine their oxidation and thermal shock resistance. Specimens were exposed to 900 C for 55 min followed by a 5 min air-cool. After 500 cycles, the specimens were examined for phase transformations, weight and elemental changes, and thermal shock resistance. (orig.) 9 refs.

  15. 40 CFR 60.4240 - What are my compliance requirements if I am a manufacturer of stationary SI internal combustion...

    Science.gov (United States)

    2010-07-01

    ... certify their stationary SI ICE using the certification procedures required in 40 CFR part 1048, subpart C... other requirements for new nonroad SI engines in 40 CFR part 90 or 40 CFR part 1054, and manufacturers... stationary SI ICE using the certification procedures required in 40 CFR part 90, subpart B, or 40 CFR...

  16. Density relative change and interface zone mutual diffusion of BiFeO3 films prepared on Si (1 0 0), SiO2 and SiO2/Si (1 0 0)

    Science.gov (United States)

    Xiao, RenZheng; Wang, ZeSong; Yuan, XianBao; Zhou, JianJun; Mao, ZhangLiang; Su, HuaShan; Li, Bo; Fu, DeJun

    2016-10-01

    The mutual diffusion taken place in the interface zone between BiFeO3 (BFO) films and substrates (Si (1 0 0), SiO2 and SiO2/Si (1 0 0)) has been revealed by energy dispersive X-ray spectroscopy (EDS) and Rutherford Backscattering Spectrometry (RBS). RBS spectra provide the relative atomic concentrations of Bi, Fe, Si, and O elements changed with the samples' depth as analyzed by RBS spectra fitting SIMNRA software. A certain width of the intermixing layer is probably formed between BFO films and individual substrate which is attributed to mutual diffusion in the interface zone during annealing process. The mechanism of concerted exchange component can explain the interface zone mutual diffusion phenomenon between BFO films and substrates. The width of the interface zone between BFO film and Si (1 0 0), SiO2, and SiO2/Si (1 0 0) substrate is about 1.94 × 1017, 2.01 × 1017 and 3.05 × 1017 atoms/cm2, respectively, which are equivalent to 30.9, 36.7, and 52.9 nm, respectively. It has been declared that the effect on density relative to BFO film is loosen or attenuation is presented in the interface zone, which can be interpreted as a migration or diffusion of various atoms during the annealing. This can also provide an evidence of atomic dynamics and defect engineering on interface diffusion.

  17. The effect of donors on lateral gated quantum-devices in Si/SiGe heterostructures

    Science.gov (United States)

    Lin, Xi; Hu, Jingshi; Lai, A.; Zhang, Z.; Maclean, K.; Xie, Y. H.; Kastner, M. A.

    2011-03-01

    Much activity has focused on the development of quantum dots in Si/SiGe because of its potentially very long decoherence times (T2). However, to fabricate well-controlled quantum dots in Si/SiGe heterostructures, one must overcome complications that do not arise in GaAs/AlGaAs heterostructures. We demonstrate that switching charge noise and donor-layer conduction can lead to instability and cross-coupling among the tunnel barriers, thus making it difficult to achieve highly stable and tunable quantum devices in a Si/SiGe heterostructure. In particular, we have used an integrated charge-sensing quantum point contact to investigate the charge motion that originates from the excess donors, and present a systematic capacitance measurement to show how the donor layer affects device function in devices with large (~ 100 μ m 2) gates as well as nanometer-size ones. This work has been supported by the Nanoscale Science and Engineering Center program of NSF (PHY-0117795), NSF (DMR-0701386).

  18. Mechanical engineering

    CERN Document Server

    Darbyshire, Alan

    2010-01-01

    Alan Darbyshire's best-selling text book provides five-star high quality content to a potential audience of 13,000 engineering students. It explains the most popular specialist units of the Mechanical Engineering, Manufacturing Engineering and Operations & Maintenance Engineering pathways of the new 2010 BTEC National Engineering syllabus. This challenging textbook also features contributions from specialist lecturers, ensuring that no stone is left unturned.

  19. Hyperpolarization of 29Si by Resonant Nuclear Spin Transfer from Optically Hyperpolarized 31P Donors

    Science.gov (United States)

    Dluhy, Phillip; Salvail, Jeff; Saeedi, Kamyar; Thewalt, Mike; Simons, Stephanie

    2014-03-01

    Recent developments in nanomedicine have allowed nanoparticles of silicon containing hyperpolarized 29Si to be imaged in vivo using magnetic resonance imaging. The extremely long relaxation times and isotropy of the Si lattice make polarized 29Si isotopes ideal for these sorts of imaging methods. However, one of the major difficulties standing in the path of widespread adoption of these techniques is the slow rate at which the 29Si is hyperpolarized and the limited maximum hyperpolarization achievable. In this talk, I will describe an effective method for hyperpolarization of the 29Si isotopes using resonant optical pumping of the donor bound exciton transitions to polarize the 31P donor nuclei, and a choice of static magnetic field that conserves energy during spin flip flops between donor nuclear and 29Si spins to facilitate diffusion of this polarization. Using this method, we are able to polarize greater than 10% of the 29Si centers in 64 hours without seeing saturation of the 29Si polarization.

  20. Assessment of total efficiency in adiabatic engines

    Science.gov (United States)

    Mitianiec, W.

    2016-09-01

    The paper presents influence of ceramic coating in all surfaces of the combustion chamber of SI four-stroke engine on working parameters mainly on heat balance and total efficiency. Three cases of engine were considered: standard without ceramic coating, fully adiabatic combustion chamber and engine with different thickness of ceramic coating. Consideration of adiabatic or semi-adiabatic engine was connected with mathematical modelling of heat transfer from the cylinder gas to the cooling medium. This model takes into account changeable convection coefficient based on the experimental formulas of Woschni, heat conductivity of multi-layer walls and also small effect of radiation in SI engines. The simulation model was elaborated with full heat transfer to the cooling medium and unsteady gas flow in the engine intake and exhaust systems. The computer program taking into account 0D model of engine processes in the cylinder and 1D model of gas flow was elaborated for determination of many basic engine thermodynamic parameters for Suzuki DR-Z400S 400 cc SI engine. The paper presents calculation results of influence of the ceramic coating thickness on indicated pressure, specific fuel consumption, cooling and exhaust heat losses. Next it were presented comparisons of effective power, heat losses in the cooling and exhaust systems, total efficiency in function of engine rotational speed and also comparison of temperature inside the cylinder for standard, semi-adiabatic and full adiabatic engine. On the basis of the achieved results it was found higher total efficiency of adiabatic engines at 2500 rpm from 27% for standard engine to 37% for full adiabatic engine.

  1. The spectroscopic studies of glasses in the BPO 4(GaPO 4)-SiO 2 system

    Science.gov (United States)

    Adamczyk, A.

    2002-09-01

    FTIR spectroscopic structural studies of gel-derived glasses in BPO 4-SiO 2 and BPO 4(GaPO 4)-SiO 2 systems are presented. 10B isotope substitution, spectra subtraction procedure and B 3+→Ga 3+ substitution were applied to distinguish the bands, originating from B-O, P-O and Si-O bond vibrations. The spectra of borophosphosilicate glasses containing 10B isotope have also been presented. Changes in the band positions helped to assign bands due to the different B-O bonds vibrations. The spectra subtraction procedure, due to the lowering of intensity of bands assigned to Si-O bonds vibrations, enabled to observe bands at 966 and 1225 cm -1, due to broken Si-O - bridges and (PO 2) - terminal groups, respectively.

  2. Cold regions isotope applications

    Energy Technology Data Exchange (ETDEWEB)

    Perrigo, L.D.; Divine, T.E.

    1976-04-01

    Pacific Northwest Laboratories (PNL) started the Cold Regions Isotope Applications Program in FY-1975 to identify special conditions in the Arctic and similar geographic areas (Cold Regions) where radioisotope power, heater, or sterilization systems would be desirable and economically viable. Significant progress was made in the first year of this program and all objectives for this initial 12-month period were achieved. The major conclusions and recommendations resulting for this effort are described below. The areas of interest covered include: radiosterilization of sewage; heating of septic tanks; and radioisotope thermoelectric generators as power sources for meteorological instruments and navigational aids. (TFD)

  3. Stirling Isotope Power System Program. Final report, January 1978-December 1980

    Energy Technology Data Exchange (ETDEWEB)

    1980-12-01

    The Stirling Isotope Power System (SIPS) design is discussed, including the control system and engine starter. The development, of fabrication, and testing of the SIPS converter are presented. The work performed on the Isotope Heat Source Assembly is described. The ancillary equipment, system integration and qualification, and safety are discussed. The safety discussion consists primarily of prediction of dose rates around the IHS and the influence on handling equipment design. Reliability and quality assurance are included. (MHR)

  4. Investigation on the preparation of Si/mullite/Yb_2Si_2O_7 environmental barrier coatings onto silicon carbide

    Institute of Scientific and Technical Information of China (English)

    许越; 闫钊通

    2010-01-01

    With the development of aero-engine,gas import temperatures of hot section structural materials are increasingly higher.Metal alloy materials due to the rapidly decreased mechanical properties at relative high temperature are gradually replaced with silicon-based non-oxide silicon carbide ceramics.However,silicon carbide ceramic materials tend to spall and deform in engine combustion environment,need environmental barrier coatings for the protection of the matrix.The preparation of Si/mullite/Yb2Si2O7 envir...

  5. 汽油机掺烧甲醇裂解气试验研究%Experimental Study on Performance of SI Engine Fueled with Gasoline and Dissociated Methanol Blends

    Institute of Scientific and Technical Information of China (English)

    谢满; 蒋炎坤

    2016-01-01

    在1台电喷汽油机上进行了掺烧甲醇裂解气试验研究,设计了甲醇裂解系统,利用发动机高温排气裂解甲醇,并将裂解气送入气缸燃烧,研究了掺烧甲醇裂解气对发动机经济性和动力性的影响.试验结果表明:在管式裂解器中,甲醇裂解的主要产物是H2和CO,体积分数分别为60.7%~64.8%,19.1%~23.1%;汽油掺烧甲醇裂解气会导致发动机输出扭矩降低,发动机当量燃料消耗率下降,热效率增加,甲醇替代比为20%时,不同负荷下当量燃料消耗率均下降6%以上,最大可降低8.8%,有效热效率由原机32.47%提高到35.57%;原机和掺烧裂解气发动机的有效热效率均随过量空气系数的增加而增加,相同过量空气系数条件下,掺烧裂解气发动机热效率比原机高.%The experimental study on performance of an electronic control injection gasoline engine fueled with gasoline and dissociated methanol blends was conducted .The dissociation system for methanol was designed ,methanol was dissociated with the high temperature exhaust in the dissociated reactor ,the dissociated methanol gas joined in the combustion of gasoline and the influences of dissociated methanol on the fuel economy and engine power were researched .The main components of dissoci-ated methanol were hydrogen and carbon monoxide ,60 .7%-64 .8% and 19 .1%-23 .1% volume fraction respectively .The par-ticipation of dissociated methanol would lead to output torque ,and equivalent specific fuel consumption decrease and effective thermal efficiency increase .The equivalent specific fuel consumption decreased by 6% to 8 .8% and the effective thermal effi-ciency increased from 32 .47% to 35 .57% when the proportion of methanol substitution was 20% .The effective thermal effi-ciency for the original engine and the engine fueled with dissociated methanol blends both increased with the increase of excess air coefficient .Gasoline engine fueled with the blends had higher effective

  6. Introduction of atomic H into Si3N4/SiO2/Si stacks

    Institute of Scientific and Technical Information of China (English)

    JIN Hao; WEBER K.J.; LI Weitang; BLAKERS A.W.

    2006-01-01

    Atomic H generated by a plasma NH3 source at 400 ℃ was demonstrated to passivate dehydrogenated Si3N4/SiO2/Si stacks effectively by bonding with defectsin the Si3N4 film and at the Si-SiO2 interface. A subsequent anneal in N2 after atomic H reintroduction was demonstrated to further improve passivation of the Si-SiO2 interface. Isothermal and isochronal anneals in N2 were carried out in order to determine the optimized annealing conditions.

  7. Measurement and analysis of thermal conductivity of isotopically controlled silicon layers by time-resolved X-ray scattering

    Energy Technology Data Exchange (ETDEWEB)

    Eon, S.; Frieling, R.; Bracht, H. [Institute for Materials Physics, University of Muenster, 48149 Muenster (Germany); Plech, A. [Institute for Photon Science and Synchrotron Radiation (IPS), 76344 Eggenstein-Leopoldshafen (Germany)

    2016-11-15

    Nanostructuring is considered to be an efficient way to tailor phonon scattering and to reduce the thermal conductivity while keeping good electronic properties. This can be ideally realized by mass modulation of chemical identical elements. In this work, we report measurements of the crossplane thermal conductivity of isotopically modulated {sup 28}Si/{sup 30}Si multilayer structures and of isotopically pure {sup 28}Si layers by means of time-resolved X-ray scattering. Compared to earlier investigations, an improved measurement technique has been applied to determine the cooling behavior of a top gold metal layer after laser excitation with picosecond time resolution until thermal equilibration is established. Detailed analysis of the cooling behavior not only confirms a reduced thermal conductivity of {sup 28}Si/{sup 30}Si multilayer structures compared to natural and isotopically enriched {sup 28}Si layers but also provides evidence of direct laser heating of the Si layer. This and extrinsic effects affecting the cooling behavior of the gold layer are taken into account to determine the thermal conductivity by means of the pump-and-probe measurement technique. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  8. Design, construction, and operation of a laboratory scale reactorfor the production of high-purity, isotopically enriched bulksilicon

    Energy Technology Data Exchange (ETDEWEB)

    Ager III, J.W.; Beeman, J.W.; Hansen, W.L.; Haller, E.E.

    2004-12-20

    The design and operation of a recirculating flow reactor designed to convert isotopically enriched silane to polycrystalline Si with high efficiency and chemical purity is described. The starting material is SiF{sub 4}, which is enriched in the desired isotope by a centrifuge method and subsequently converted to silane. In the reactor, the silane is decomposed to silicon on the surface of a graphite starter rod (3 mm diameter) heated to 700-750 C. Flow and gas composition (0.3-0.5% silane in hydrogen) are chosen to minimize the generation of particles by homogeneous nucleation of silane and to attain uniform deposition along the length of the rod. Growth rates are 5 {micro}m/min, and the conversion efficiency is greater than 95%. A typical run produces 35 gm of polycrystalline Si deposited along a 150 mm length of the rod. After removal of the starter rod, dislocation-free single crystals are formed by the floating zone method. Crystals enriched in all 3 stable isotopes of Si have been made: {sup 28}Si (99.92%), {sup 29}Si (91.37%), and {sup 30}Si (88.25%). Concentrations of electrically active impurities (P and B) are as low as mid-10{sup 13} cm{sup -3}. Concentrations of C and O lie below 10{sup 16} and 10{sup 15} cm{sup -3}, respectively.

  9. Technical Research for Dedicated Isotope Production Reactor of South Africa

    Institute of Scientific and Technical Information of China (English)

    ZOU; Yao; LIU; Xing-min; CHEN; Hui-qiang; SUN; Zhen; WU; Yuan-yuan

    2012-01-01

    <正>Research reactor plays an important part in nuclear science and technology, application and power development. Currently, many countries in Middle East and Africa are ready to develop their own nuclear industry. South Africa sent its User Requirements Specification (URS) for a dedicated isotope production reactor to several institutes or companies, among of which Department of Reactor Engineering Research and Design (DRERD) in China Institute of Atomic Energy (CIAE) is a competitive candidate.

  10. Neutron single-particle strength in silicon isotopes: Constraining the driving forces of shell evolution

    CERN Document Server

    Stroberg, S R; Tostevin, J A; Bader, V M; Baugher, T; Bazin, D; Berryman, J S; Brown, B A; Campbell, C M; Kemper, K W; Langer, C; Lunderberg, E; Lemasson, A; Noji, S; Otsuka, T; Recchia, F; Walz, C; Weisshaar, D; Williams, S

    2015-01-01

    Shell evolution is studied in the neutron-rich silicon isotopes 36,38,40 Si using neutron single-particle strengths deduced from one-neutron knockout reactions. Configurations involving neutron excita- tions across the N = 20 and N = 28 shell gaps are quantified experimentally in these rare isotopes. Comparisons with shell model calculations show that the tensor force, understood to drive the col- lective behavior in 42 Si with N = 28, is already important in determining the structure of 40 Si with N = 26. New data relating to cross-shell excitations provide the first quantitative support for repulsive contributions to the cross-shell T = 1 interaction arising from three-nucleon forces.

  11. Silicon Isotope Fractionation by Banana Under Continuous Nutrient and Silica Flux

    Science.gov (United States)

    Opfergelt, S.; Cardinal, D.; Henriet, C.; Delvaux, B.; André, L.

    2004-12-01

    Silicon is absorbed by plants as aqueous H4SiO4 with other essential nutrients, and precipitates in aerial parts of the plant as phytolith, a biogenic opal. Phytoliths are restored to the soil by decomposition of organic debris from plant material. The role of higher plants in the biogeochemical cycle of silicon is therefore major although it is still poorly studied. Biomineralization processes are known to fractionate the three stable silicon isotopes with a preferential uptake of light isotopes. Therefore, following some preliminary results from Douthitt (1982), and studies presented in recent conferences (Ziegler et al., 2002; Ding et al., 2003), we suspect that phytolith production by plants could also fractionate the silicon isotopes. Inversely, intensity of phytolith-related isotopic fractionations might contribute to a better understanding of the soil-plant silicon cycle. Our study focused on banana, a silicon accumulating plant (>1% Si, dry weight).Musa acuminata cv Grande Naine has been grown in hydroponics under controlled conditions (light, temperature, humidity, nutrients) during six weeks. The nutrient supply was kept constant: three batches of five plants were grown with a continuous nutrient solution flow of 5, 50 and 100 ppm SiO2 respectively. Si isotopic compositions were measured in the source solution, and in silica extracted from the various parts of banana (roots, pseudostems, midribs and petioles, leaves), using a Nu Plasma multicollector mass spectrometer (MC-ICP-MS) operating in dry plasma mode. The results are expressed as δ 29Si relatively to the NBS28 standard, with an average precision of ± 0.03‰ . Silicon contents and morphological studies of phytoliths were also achieved. Banana δ 29Si varied between -0.18 and -0.76‰ with a source solution at -0.02‰ . Values of δ 29Si were less fractionated, relatively to the nutrient solution, in roots, where no phytoliths have been observed until now, than in upper parts of banana where

  12. SYNTHESIS OF SiC WHISKER AND ITS APPLICATION IN COMPOSITE MATERIALS

    Institute of Scientific and Technical Information of China (English)

    王启宝; 郭梦熊

    1997-01-01

    The SiC whiskers (SiCw) synthesized from rice hulls is studied in this paper. The properties of the application in the composite materials are tested, and also compared with the SiCw produced in US and Japan, the results indicate that the SiCw produced by this method is mainly straight crystals with multi nodes on face, the main type is β-SiC. It has many advantages such as high strength and excellent oxidation resistance to high temperature. The Si3N4 ceramic composite materials reinforced and toughened with the SiCw, δRT∫ of the material is (856±22)MPa, δ1300℃t is approximately (418.5±14.2) MPa and KIC is approximately (11.3±1.0) MPa·m1/2. Besides, the application of the SiCw in the engineering materials of mining is forecasted.

  13. Visualisation of Gasoline and Exhaust Gases Distribution in a 4-Valve Si Engine; Effects of Stratification on Combustion and Pollutants Visualisation de la répartition du carburant et des gaz brûlés dans un moteur à 4 soupapes à allumage commandé ; effet de la stratification sur la combustion et les polluants

    Directory of Open Access Journals (Sweden)

    Deschamps B.

    2006-12-01

    Full Text Available sAn indirect method to map the burned gases in SI engine has been developed. It is based on visualisation by Laser Induced Fluorescence of the unburned mixture seeded with biacetyl. Both internally and externally recirculated burned gases are monitored. This diagnostic is complementary to the LIF technique applied to measure the gasoline distribution. These LIF gasoline and burned gases measurements are applied in a 4-valve optical access SI engine for a large range of operating conditions. These include variations of both fuel injection and burned gas recirculation modes causing different types of stratification leading to very distinct heat release and exhaust emissions characteristics. Tumble level and spark location are also modified. The observation of the actual stratification in the engine forms a sound basis explanation of the engine performance. Parameters allowing an optimisation of NOx and HC levels can be inferred, and in particular the effectiveness of recirculation and fuel injection strategies. The conclusions are confirmed by measurements in a single engine cylinder conventional head with the same geometry. Une méthode indirecte pour cartographier les gaz brûlés dans un moteur à allumage commandé a été développée. Elle est fondée sur une visualisation à partir de la fluorescence induite par laser (LIF du mélange air-carburant non brûlé et ensemencé avec du biacétyl. Les gaz brûlés provenant à la fois des recirculations internes et externes sont observés. Ce type de diagnostic est complémentaire des techniques de LIF utilisées pour observer la distribution du carburant. Ces mesures de concentration sont réalisées dans un moteur à 4 soupapes avec accès optiques, pour une gamme étendue de conditions opératoires. Celles-ci comprennent des variations des modes d'injection du carburant et des modes de recirculation des gaz brûlés, provoquant ainsi différents types de stratifications qui correspondent

  14. Magnesium Isotopic Composition of Subducting Marine Sediments

    Science.gov (United States)

    Hu, Y.; Teng, F. Z.; Plank, T. A.; Huang, K. J.

    2015-12-01

    Subducted marine sediments have recently been called upon to explain the heterogeneous Mg isotopic composition (δ26Mg, ‰) found in mantle wehrlites (-0.39 to +0.09 [1]) in the context of a homogeneous mantle (-0.25 ± 0.07 [2]). However, no systematic measurements of δ26Mg on marine sediments are currently available to provide direct support to this model. To characterize the Mg inputs to global subduction zones, we measured δ26Mg data for a total of 90 marine sediments collected from 12 drill sites outboard of the world's major subduction zones. These sediments span a 1.73‰ range in δ26Mg. The detritus-dominated sediments have δ26Mg (-0.59 to +0.53) comparable to those of weathered materials on continents (e.g. -0.52 to +0.92 [3]), while the calcareous oozes yield δ26Mg (as light as -1.20) more similar to the seawater value (-0.83 [4]). The negative correlation between δ26Mg and CaO/Al2O3 in these sediments indicates the primary control of mineralogy over the Mg isotopic distribution among different sediment types, as carbonates are enriched in light Mg isotopes (-5.10 to -0.40 [5]) whereas clay-rich weathering residues generally have heavier δ26Mg (e.g. up to +0.65 in saprolite [6]). In addition, chemical weathering and grain-size sorting drive sediments to a heavier δ26Mg, as indicated by the broad positive trends between δ26Mg with CIA (Chemical Index of Alteration [7]) and Al2O3/SiO2, respectively. Collectively, the arc systems sampled in this study represent ~30% of global arc length and the extrapolated global Mg flux of subducting marine sediments accounts for ~9% of the yearly Mg riverine input with a flux-weighted average δ26Mg at -0.26. Subduction of these heterogeneous sediments may not cause significant mantle heterogeneity on a global scale, but the highly variable Mg fluxes and δ26Mg of sediments delivered to different trenches are capable of producing local mantle variations. Volcanic rocks sourced from these mantle domains are thus

  15. Ab Initio Nuclear Structure and Reaction Calculations for Rare Isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Draayer, Jerry P. [Louisiana State Univ., Baton Rouge, LA (United States)

    2014-09-28

    We have developed a novel ab initio symmetry-adapted no-core shell model (SA-NCSM), which has opened the intermediate-mass region for ab initio investigations, thereby providing an opportunity for first-principle symmetry-guided applications to nuclear structure and reactions for nuclear isotopes from the lightest p-shell systems to intermediate-mass nuclei. This includes short-lived proton-rich nuclei on the path of X-ray burst nucleosynthesis and rare neutron-rich isotopes to be produced by the Facility for Rare Isotope Beams (FRIB). We have provided ab initio descriptions of high accuracy for low-lying (including collectivity-driven) states of isotopes of Li, He, Be, C, O, Ne, Mg, Al, and Si, and studied related strong- and weak-interaction driven reactions that are important, in astrophysics, for further understanding stellar evolution, X-ray bursts and triggering of s, p, and rp processes, and in applied physics, for electron and neutrino-nucleus scattering experiments as well as for fusion ignition at the National Ignition Facility (NIF).

  16. Calcium isotopes in wine

    Science.gov (United States)

    Holmden, C. E.

    2011-12-01

    The δ 44/40Ca values of bottled wine vary between -0.76% to -1.55% on the seawater scale and correlate weakly with inverse Ca concentration and Mg/Ca ratio, such that the lowest δ 44/40Ca values have the highest Ca concentrations and lowest Mg/Ca ratios. The correlation is notable in the sense that the measured wines include both whites and reds sampled from different wine growing regions of the world, and cover a wide range of quality. Trends among the data yield clues regarding the cause of the observed isotopic fractionation. White wines, and wines generally perceived to be of lower quality, have lower δ 44/40Ca values compared to red wines and wines of generally perceived higher quality. Quality was assessed qualitatively through sensory evaluation, price, and scores assigned by critics. The relationship between δ 44/40Ca and wine quality was most apparent when comparing wines of one varietal from one producer from the same growing region. In the vineyard, wine quality is related to factors such as the tonnage of the crop and the ripeness of the grapes at the time of harvesting, the thickness of the skins for reds, the age of the vines, as well as the place where the grapes were grown (terroir). Quality is also influenced by winemaking practices such as fermentation temperature, duration of skin contact, and barrel ageing. Accordingly, the relationship between δ 44/40Ca and wine quality may originate during grape ripening in the vineyard or during winemaking in the cellar. We tested the grape ripening hypothesis using Merlot grapes sampled from a vineyard in the Okanagan, British Columbia, using sugar content (degrees Brix) as an indicator of ripeness. The grapes were separated into pulp, skin, and pip fractions and were analyzed separately. Thus far, there is no clear evidence for a systematic change in δ 44/40Ca values associated with progressive ripening of grapes in the vineyard. On the day of harvesting, the δ 44/40Ca value of juice squeezed from

  17. Electronic Structure of Si1-xIVx/Si Superlattices on Si(001)

    Institute of Scientific and Technical Information of China (English)

    CHEN Jie; L(U) Tie-Yu; HUANG Mei-Chun

    2007-01-01

    We have preformed systematical ab initio studies of the structural and electronic properties of short-period Si1-xIVx/Si (x = 0.125, 0.25, 0.5,IV=Ge, Sn) superlattices (SLs) grown along the [001] direction on bulk Si. The present calculations reveal that the Si0.875 Ge0.125/Si, Si0.75 Ge0.25/Si and Si0.875Sn0.125/Si axe the Γ-point direct bandgap semiconductors. The technological importance lies in the expectation that the direct gap Si1-xIVx/Si SLs may be used as components in integrated optoelectronic devices, in conjunction with the already well-established and highly advanced silicon technology.

  18. Photoelectric properties of n-SiC/n-Si heterojunctions

    Directory of Open Access Journals (Sweden)

    Semenov A. V.

    2012-10-01

    Full Text Available Photovoltaic effect in isotype heterotructure formed by nanocrystalline silicon carbide films on single crystal n-Si substrates (n-SiC/n-Si heterojunction was studied. The films were produced by direct ionic deposition method. The model that takes into account the quantum wells and potential barriers caused by band offsets was proposed to explain the current-voltage characteristics and photovoltaic properties of the heterostructure n-SiC/n-Si.

  19. Investigation of Coulomb scattering on sSi/Si0.5Ge0.5/sSOI quantum-well p-MOSFETs

    Science.gov (United States)

    Jiao, Wen; Qiang, Liu; Chang, Liu; Yize, Wang; Bo, Zhang; Zhongying, Xue; Zengfeng, Di; Wenjie, Yu; Qingtai, Zhao

    2016-09-01

    sSi/Si0.5Ge0.5/sSOI quantum-well (QW) p-MOSFETs with HfO2/TiN gate stack were fabricated and characterized. According to the low temperature experimental results, carrier mobility of the strained Si0.5Ge0.5 QW p-MOSFET was mainly governed by phonon scattering from 300 to 150 K and Coulomb scattering below 150 K, respectively. Coulomb scattering was intensified by the accumulated inversion charges in the Si cap layer of this Si/SiGe heterostructure, which led to a degradation of carrier mobility in the SiGe channel, especially at low temperature. Project supported by the National Natural Science Foundation of China (Nos. 61306126, 61306127, 61106015) and the CAS International Collaboration and Innovation Program on High Mobility Materials Engineering.

  20. Gate-defined quantum dot devices in undoped Si/SiGe heterostructures for spin qubit applications

    Science.gov (United States)

    Volk, Christian; Martins, Frederico; Marcus, Charles M.; Kuemmeth, Ferdinand

    Spin qubits based on few electron quantum dots in semiconductor heterostructures are among the most promising systems for realizing quantum computation. Due to its low concentration of nuclear-spin-carrying isotopes, silicon is of special interest as a host material. We characterize gate-defined double and triple quantum dot devices fabricated from undoped Si/Si0.7Ge0.3 heterostructures. Our device architecture is based on integrating all accumulation and depletion mode gates in a single gate layer. This allows us to omit the commonly used global accumulation gate in order to achieve a more local control of the potential landscape in the device. We present our recent progress towards implementing spin qubits in these structures. Support through the EC FP7- ICT project SiSPIN no. 323841, and the Danish National Research Foundation is acknowledged.

  1. Interfacial reaction of eutectic AuSi solder with Si (100) and Si (111) surfaces

    Science.gov (United States)

    Jang, Jin-Wook; Hayes, Scott; Lin, Jong-Kai; Frear, Darrel R.

    2004-06-01

    The dissolution behavior of Si (100) and (111) dies by eutectic AuSi solder was investigated. On the Si (100) surface, the dissolution primarily occurred by the formation of craters resulting in a rough surface. The dissolution of the Si (111) resulted in a relatively smooth surface. The morphology of the Si (100) surface during a AuSi soldering reaction exhibited more time-dependent behavior and the etching craters on a Si (100) surface grew larger with time whereas Si (111) did not significantly change. This difference was ascribed to the surface energy differences between Si (111) and (100) surfaces that resulted in the two- and three-dimensional dissolution behaviors, respectively. This difference plays an important role in the formation of voids during the AuSi die bonding. The etching craters on Si (100) act as a AuSi solder sink and the regions surrounded by etch pits tend to become voids. For Si (111), flat surfaces were observed in the voided regions. Cross section analysis showed that no solder reaction occurred in the voided region of the Si (111) surface. This suggests the possibility of the formation of a thin inert layer in a potentially voided region prior to assembly. To achieve void-free die bonding, different parameters must be adjusted to the Si (100) and Si (111) surfaces with the AuSi alloy.

  2. Rotational spectra, potential function, Born Oppenheimer breakdown and magnetic shielding of SiSe and SiTe

    Science.gov (United States)

    Giuliano, Barbara M.; Bizzocchi, Luca; Grabow, Jens-Uwe

    2008-09-01

    The pure rotational spectra of 18 isotopic species of SiSe (8) and SiTe (10) have been measured in their X1Σ + electronic state with a pulsed-jet resonator Fourier transform microwave spectrometer. The molecules were prepared by a combined DC discharge/laser ablation technique and stabilised in a supersonic jet of Ar. Global multi-isotopologue analyses yielded spectroscopic Dunham parameters Y01, Y11, Y21, Y31 and Y02 for both species, as well as effective Born-Oppenheimer breakdown (BOB) coefficients δ01 for Si, Se and Te. A direct fit of the same data sets to an appropriate radial Hamiltonian yielded analytic potential energy functions and BOB radial functions for the X1Σ + electronic state of both SiSe and SiTe. Additionally, the magnetic hyperfine interactions produced by the uneven mass number A nuclei 29Si, 77Se and 125Te were observed, yielding first determinations of the corresponding nuclear spin-rotation coupling constants.

  3. Beta-decay Study of Proton-rich Nucleus 24Si

    Institute of Scientific and Technical Information of China (English)

    SUN; Li-jie; XU; Xin-xing; LIN; Cheng-jian; WANG; Jian-song; FANG; De-qing; LI; Zhi-huan; WANG; Yu-ting; LI; Jing; YANG; Lei; MA; Nan-ru; WANG; Kang; ZANG; Hong-liang; WANG; Hong-wei; LI; Chen; SHI; Chen-zhong; NIE; Mao-wu; MA; Jun-bing; MA; Peng; JIN; Shi-lun; HUANG; Mei-rong; WANG; Jian-guo; BAI; Zhen; YANG; Yan-yun; LI; Xiu-fang; LI; He; YANG; Feng; JIA; Hui-ming; ZHANG; Huan-qiao; LIU; Zu-hua; BAO; Peng-fei; WANG; Dong-xi

    2015-01-01

    The experiment ofβdecay of 24Si was performed at the Heavy Ion Research Facility in Lanzhou(HIRFL).Two double-sided silicon strip detectors(DSSD)of thickness 149μm and66μm are used to stop the isotopes of interest,which also serve asβ-delayed proton decay detectors.

  4. Correlation between Light Emissions from Amorphous-Si:H/SiO2 and nc-Si/SiO2 Multilayers

    Institute of Scientific and Technical Information of China (English)

    MA Zhong-Yuan; HUANG Xin-Fan; CHEN Kun-Ji; FENG Duan; HAN Pei-Gao; LI Wei; CHEN De-Yuan; WEI De-Yuan; QIAN Bo; LI Wei; XU Jun; XU Ling

    2007-01-01

    We investigate the properties of light emission from amorphous-Si:H/SiO2 and nc-Si/SiO2 multilayers (MLs). The size dependence of light emission is well exhibited when the a-Si:H sublayer thickness is thinner than 4nm and the interface states are well passivated by hydrogen. For the nc-Si/SiO2 MLs, the oxygen modified interface states and nanocrystalline silicon play a predominant role in the properties of light emission. It is found that the light emission from nc-Si/SiO2 is in agreement with the model of interface state combining with quantum confinement when the size of nc-Si is smaller than 4 nm. The role of hydrogen and oxygen is discussed in detail.

  5. Comparison of element and isotope diffusion of K and Ca in multicomponent silicate melts

    Science.gov (United States)

    van der Laan, Sieger; Zhang, Youxue; Kennedy, Allen K.; Wyllie, Peter J.

    1994-05-01

    Recent experimental work has shown that the homogenization of elemental concentrations can be much slower than that of isotopic ratios when there are strong concentration gradients in SiO 2 and Al 2O 3. The ramifications of this result for magma homogenization and other petrological problems related to diffusion are significant. We report here a comparison of experimental profiles of elemental concentrations and isotopic fractions of K and Ca in rhyolite-andesite (large concentration gradients) and rhyolite-rhyolite (small concentration gradients) melt couples. When the concentration profile and the isotopic profile of the same element in a single couple are compared, the former is much shorter than the latter in the rhyolite-andesite couple, consistent with other recent studies. However, the lengths of both concentration and isotopic profiles are similar in the rhyolite-rhyolite couple. Therefore, diffusion of an element or oxide may be decoupled from or coupled with isotopic 'diffusion', depending on whether large concentration gradients of major components are present. When the two couples are compared, the intrinsic effective binary diffusivities obtained from isotopic profiles are similar for each element in the two couples, whereas the effective binary diffusivity of K obtained from the concentration profile in the rhyolite-rhyolite couple is 37 times that in the rhyolite-andesite couple. Therefore, isotopic homogenization is roughly independent of elemental homogenization and the presence of SiO 2, Al 2O 3, and other concentration gradients, whereas elemental homogenization is strongly affected by concentration gradients. Our experimental data (isotopic and concentration profiles including uphill diffusion profiles) can be modeled quantitatively to a good approximation using a modified effective binary diffusion model in which the flux of a component is assumed to be proportional to its activity gradient instead of its concentration gradient. Therefore, the

  6. Engineering Cartilage

    Science.gov (United States)

    ... Research Matters NIH Research Matters March 3, 2014 Engineering Cartilage Artistic rendering of human stem cells on ... situations has been a major goal in tissue engineering. Cartilage contains water, collagen, proteoglycans, and chondrocytes. Collagens ...

  7. Industrial Engineering

    DEFF Research Database (Denmark)

    Karlsson, Christer

    2015-01-01

    Industrial engineering is a discipline that is concerned with increasing the effectiveness of (primarily) manufacturing and (occasionally).......Industrial engineering is a discipline that is concerned with increasing the effectiveness of (primarily) manufacturing and (occasionally)....

  8. Governing Engineering

    DEFF Research Database (Denmark)

    Buch, Anders

    2011-01-01

    Abstract: Most people agree that our world faces daunting problems and, correctly or not, technological solutions are seen as an integral part of an overall solution. But what exactly are the problems and how does the engineering ‘mind set’ frame these problems? This chapter sets out to unravel...... dominant perspectives in challenge perception in engineering in the US and Denmark. Challenge perception and response strategies are closely linked through discursive practices. Challenge perceptions within the engineering community and the surrounding society are thus critical for the shaping...... of engineering education and the engineering profession. Through an analysis of influential reports and position papers on engineering and engineering education the chapter sets out to identify how engineering is problematized and eventually governed. Drawing on insights from governmentality studies the chapter...

  9. Governing Engineering

    DEFF Research Database (Denmark)

    Buch, Anders

    2012-01-01

    Most people agree that our world face daunting problems and, correctly or not, technological solutions are seen as an integral part of an overall solution. But what exactly are the problems and how does the engineering ‘mind set’ frame these problems? This chapter sets out to unravel dominant...... perspectives in challenge per-ception in engineering in the US and Denmark. Challenge perception and response strategies are closely linked through discursive practices. Challenge perceptions within the engineering community and the surrounding society are thus critical for the shaping of engineering education...... and the engineering profession. Through an analysis of influential reports and position papers on engineering and engineering education the chapter sets out to identify how engineering is problematized and eventually governed. Drawing on insights from governmentality studies the chapter strives to elicit the bodies...

  10. Computer Engineers.

    Science.gov (United States)

    Moncarz, Roger

    2000-01-01

    Looks at computer engineers and describes their job, employment outlook, earnings, and training and qualifications. Provides a list of resources related to computer engineering careers and the computer industry. (JOW)

  11. Biochemical Engineering.

    Science.gov (United States)

    Dunnill, P.

    1979-01-01

    Biochemical engineering as a scientific discipline is becoming accepted in England and is drawing many young men and women to its ranks. This article focuses on how engineering came to embrace the biological sciences. (Author/SA)

  12. Engineering _ litteraturliste

    DEFF Research Database (Denmark)

    Sillasen, Martin Krabbe; Daugbjerg, Peer; Nielsen, Keld

    2017-01-01

    Litteraturliste udarbejdet som grundlag for artiklen ”Engineering – svaret på naturfagenes udfordringer?”......Litteraturliste udarbejdet som grundlag for artiklen ”Engineering – svaret på naturfagenes udfordringer?”...

  13. Prosthetic Engineering

    Science.gov (United States)

    ... Overview CoE for Limb Loss Prevention and Prosthetic Engineering Menu Menu VA Center of Excellence for Limb ... ZIP code here Enter ZIP code here Prosthetic Engineering - Overview Our aim is to improve prosthetic prescription ...

  14. Heavy silicon isotopic composition of silicic acid and biogenic silica in Arctic waters over the Beaufort shelf and the Canada Basin

    Science.gov (United States)

    Varela, D. E.; Brzezinski, M. A.; Beucher, C. P.; Jones, J. L.; Giesbrecht, K. E.; Lansard, B.; Mucci, A.

    2016-06-01

    The silicon isotopic composition of silicic acid (δ30Si(OH)4) and biogenic silica (δ30Si-bSiO2) were measured for the first time in marine Arctic waters from the Mackenzie River delta to the deep Canada Basin in the late summer of 2009. In the upper 100 m of the water column, δ30Si(OH)4 signals (+1.82‰ to +3.08‰) were negatively correlated with the relative contribution of Mackenzie River water. The biogenic Si isotope fractionation factor estimated using an open system model, 30ɛ = -0.97 ± 0.17‰, agrees well with laboratory and global-ocean estimates. Nevertheless, the δ30Si dynamics of this region may be better represented by closed system isotope models that yield lower values of 30ɛ, between -0.33‰ and -0.41‰, depending on how the contribution of sea-ice diatoms is incorporated. In the upper 400 m, δ30Si-bSiO2 values were among the heaviest ever measured in marine suspended bSiO2 (+2.03‰ to +3.51‰). A positive correlation between δ30Si-bSiO2 and sea-ice cover implies that heavy signals can result from isotopically heavy sea-ice diatoms introduced to pelagic assemblages. Below the surface bSiO2 production zone, the δ30Si(OH)4 distribution followed that of major water masses. Vertical δ30Si(OH)4 profiles showed a minimum (average of +1.84 ± 0.10‰) in the upper halocline (125-200 m) composed of modified Pacific water and heavier average values (+2.04 ± 0.11‰) in Atlantic water (300-500 m deep). In the Canada Basin Deep Water (below 2000 m), δ30Si(OH)4 averaged +1.88 ± 0.12‰, which represents the most positive value ever measured anywhere in the deep ocean. Since most Si(OH)4 enters the Arctic from shallow depths in the Atlantic Ocean, heavy deep Arctic δ30Si(OH)4 signals likely reflect the influx of relatively heavy intermediate Atlantic waters. A box model simulation of the global marine δ30Si(OH)4 distribution successfully reproduced the observed patterns, with the δ30Si(OH)4 of the simulated deep Arctic Ocean being the

  15. Monolithically Integrated Ge-on-Si Active Photonics

    Directory of Open Access Journals (Sweden)

    Jifeng Liu

    2014-07-01

    Full Text Available Monolithically integrated, active photonic devices on Si are key components in Si-based large-scale electronic-photonic integration for future generations of high-performance, low-power computation and communication systems. Ge has become an interesting candidate for active photonic devices in Si photonics due to its pseudo-direct gap behavior and compatibility with Si complementary metal oxide semiconductor (CMOS processing. In this paper, we present a review of the recent progress in Ge-on-Si active photonics materials and devices for photon detection, modulation, and generation. We first discuss the band engineering of Ge using tensile strain, n-type doping, Sn alloying, and separate confinement of Γ vs. L electrons in quantum well (QW structures to transform the material towards a direct band gap semiconductor for enhancing optoelectronic properties. We then give a brief overview of epitaxial Ge-on-Si materials growth, followed by a summary of recent investigations towards low-temperature, direct growth of high crystallinity Ge and GeSn alloys on dielectric layers for 3D photonic integration. Finally, we review the most recent studies on waveguide-integrated Ge-on-Si photodetectors (PDs, electroabsorption modulators (EAMs, and laser diodes (LDs, and suggest possible future research directions for large-scale monolithic electronic-photonic integrated circuits on a Si platform.

  16. Si-nanocrystal-based nanofluids for nanothermometry.

    Science.gov (United States)

    Cardona-Castro, M A; Morales-Sánchez, A; Licea-Jiménez, L; Alvarez-Quintana, J

    2016-06-10

    The measurement of local temperature in nanoscale volumes is becoming a technological frontier. Photoluminescent nanoparticles and nanocolloids are the natural choice for nanoscale temperature probes. However, the influence of a surrounding liquid on the cryogenic behavior of oxidized Si-nanocrystals (Si-NCs) has never been investigated. In this work, the photoluminescence (PL) of oxidized Si-NCs/alcohol based nanocolloids is measured as a function of the temperature and the molecule length of monohydric alcohols above their melting-freezing point. The results unveil a progressive blue shift on the emission peak which is dependent on the temperature as well as the dielectric properties of the surrounding liquid. Such an effect is analyzed in terms of thermal changes of the Si-NCs bandgap, quantum confinement and the polarization effects of the embedding medium; revealing an important role of the dielectric constant of the surrounding liquid. These results are relevant because they offer a general insight to the fundamental behavior of photoluminescent nanocolloids under a cooling process and moreover, enabling PL tuning based on the dielectric properties of the surrounding liquid. Hence, the variables required to engineer PL of nanofluids are properly identified for use as temperature sensors at the nanoscale.

  17. Si-nanocrystal-based nanofluids for nanothermometry

    Science.gov (United States)

    Cardona-Castro, M. A.; Morales-Sánchez, A.; Licea-Jiménez, L.; Alvarez-Quintana, J.

    2016-06-01

    The measurement of local temperature in nanoscale volumes is becoming a technological frontier. Photoluminescent nanoparticles and nanocolloids are the natural choice for nanoscale temperature probes. However, the influence of a surrounding liquid on the cryogenic behavior of oxidized Si-nanocrystals (Si-NCs) has never been investigated. In this work, the photoluminescence (PL) of oxidized Si-NCs/alcohol based nanocolloids is measured as a function of the temperature and the molecule length of monohydric alcohols above their melting-freezing point. The results unveil a progressive blue shift on the emission peak which is dependent on the temperature as well as the dielectric properties of the surrounding liquid. Such an effect is analyzed in terms of thermal changes of the Si-NCs bandgap, quantum confinement and the polarization effects of the embedding medium; revealing an important role of the dielectric constant of the surrounding liquid. These results are relevant because they offer a general insight to the fundamental behavior of photoluminescent nanocolloids under a cooling process and moreover, enabling PL tuning based on the dielectric properties of the surrounding liquid. Hence, the variables required to engineer PL of nanofluids are properly identified for use as temperature sensors at the nanoscale.

  18. Engineering Motion

    Science.gov (United States)

    Tuttle, Nicole; Stanley, Wendy; Bieniek, Tracy

    2016-01-01

    For many teachers, engineering can be intimidating; teachers receive little training in engineering, particularly those teaching early elementary students. In addition, the necessity of differentiating for students with special needs can make engineering more challenging to teach. This article describes a professional development program…

  19. Engineering Motion

    Science.gov (United States)

    Tuttle, Nicole; Stanley, Wendy; Bieniek, Tracy

    2016-01-01

    For many teachers, engineering can be intimidating; teachers receive little training in engineering, particularly those teaching early elementary students. In addition, the necessity of differentiating for students with special needs can make engineering more challenging to teach. This article describes a professional development program…

  20. A comparative study of electroluminescence from Ge/SiO2 and Si/SiO2 films

    Institute of Scientific and Technical Information of China (English)

    Ma Shu-Yi; Chen Hui; Xiao Yong; Ma Zi-Jun; Sun Ai-Min

    2004-01-01

    Ge/SiO2 and Si/SiO2 films were deposited using the two-target alternation magnetron sputtering technique. The Au/Ge/SiO2/p-Si and Au/Si/SiO2/p-Si structures were fabricated and their electroluminescence (EL) characteristics were comparatively studied. Both Au/Ge/SiO2/p-Si and Au/Si/SiO2/p-Si structures have rectifying property. All the EL spectra from the two types of the structure have peak positions around 650-660 nm. The EL mechanisms of the structures are discussed.

  1. Simulating the modern δ30Si distribution in the oceans and in marine sediments

    Science.gov (United States)

    Gao, S.; Wolf-Gladrow, D. A.; Völker, C.

    2016-02-01

    The δ30Si of biogenic silica (δ30SiBSi) in marine sediments is a promising proxy for the reconstruction of silicic acid utilization by diatoms in the geological past. The application of this proxy, however, requires an understanding of the modern δ30Si distributions and their controlling mechanisms. Here we present results from a modern climate simulation with a coupled ocean-sediment model that includes a prognostic formulation of biogenic silica production with concurrent silicon isotopic fractionation. In agreement with previous studies, biological fractionation combined with physical transport and mixing determines the oceanic distribution of simulated δ30Si. A new finding is a distinct seasonal cycle of δ30Si in the surface ocean, which is inversely related to that of silicic acid concentration and mixed layer depth. We also provide the first simulation results of sedimentary δ30Si, which reveal that (1) the δ30SiBSi distribution in the surface sediment reflects the exported δ30SiBSi signal from the euphotic zone and (2) the dissolution of biogenic silica in the sediment acts as a source of relatively light δ30Si into the bottom waters of the polar oceans, while it is a source of heavier δ30Si to the subtropical South Atlantic and South Pacific.

  2. The δ30Si Proxy: Utility, Application and Challenges (Invited)

    Science.gov (United States)

    Brzezinski, M. A.

    2009-12-01

    The discovery that diatoms fractionate isotopes of Si when forming their cell walls opened the possibility of using the isotopic composition of Si within diatom frustules to reconstruct past levels of relative silicic acid use in ocean surface waters. This presentation will review efforts at proxy calibration including challenges with validating the fractionation factor, ɛ, in the modern ocean and the complexity imposed by a new discovery that isotopes of Si are fractionated during the dissolution of diatom silica. Paleorecords of δ30Si in diatom frustules will be summarized relative to their implications for changes in glacial atmospheric pCO2 levels. δ30Si and δ15N records from the Southern Ocean show that the dynamics of nitrate and silicic acid use are nearly completely out of phase on glacial timescales in both the Antarctic and the Subantarctic likely driven by varying inputs of iron to the Southern Ocean which alters nutrient consumption ratios by phytoplankton. Increased inputs of iron during glacial periods caused the Southern Ocean to switch from being a silicic acid trap that exports nitrate to low latitudes, to a nitrate trap that exports excess silicic acid. This change has been referred to the Silicic Acid Leakage Hypothesis (SALH) which proposes that enhanced export of silicic acid during glacial times may have contributed to the lowering of atmospheric pCO2 by altering ocean alkalinity through enhanced diatom growth at low latitudes at the expense of production by coccolithophores. An often overlooked consequence of silicic acid leakage is that the export of nitrate from the Southern Ocean is simultaneously reduced which would lower overall productivity at low latitudes. This would not necessarily eliminate the effect of Si leakage on atmospheric pCO2 as recent modeling efforts show that the decrease is driven mainly by the ratio of silicic acid: nitrate leaving the Southern Ocean rather than by the absolute amount of silicic acid or nitrate

  3. a-Si/c-Si heterojunction solar cells on SiSiC ceramic substrates

    Institute of Scientific and Technical Information of China (English)

    LI Xudong; XU Ying; CHE Xiaoqi

    2006-01-01

    Silicon thin-film solar cells are considered to be one of the most promising cells in the future for their potential advantages, such as low cost, high efficiency, great stability, simple processing, and none-pollution. In this paper, latest progress on poly-crystalline silicon solar cells on ceramic substrates achieved by our group was reported. Rapid thermal chemical vapor deposition (RTCVD) was used to deposited poly-crystalline silicon thin films, and the grains of as-grown film were enlarged by Zone-melting Recrystallization (ZMR). As a great changein cell's structure, traditional diffused pn homojunction was replaced by a-Si/c-Si heterojunction, which lead is to distinct improvement in cell's efficiency.A conversion efficiency of 3.42% has been achieved on 1cm2 a-Si/c-Si heterojunction solar cell ( Isc =16.93 mA, Voc =310.9 mV, FF =06493, AM =1.5 G,24 ℃), while the cell with diffused homojunction only gotan efficiency of 0.6%. It indicates that a-Si emitter formed at low temperature might be more suitable for thin film cell on ceramics.

  4. Hydrogen isotope separation for fusion power applications

    Energy Technology Data Exchange (ETDEWEB)

    Smith, R., E-mail: robert.smith@ccfe.ac.uk [EURATOM/CCFE Fusion Association, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); JET-EFDA, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Whittaker, D.A.J.; Butler, B.; Hollingsworth, A.; Lawless, R.E.; Lefebvre, X.; Medley, S.A.; Parracho, A.I.; Wakeling, B. [EURATOM/CCFE Fusion Association, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); JET-EFDA, Culham Science Centre, Abingdon OX14 3DB (United Kingdom)

    2015-10-05

    Highlights: • Summary of the tritium plant, the Active Gas Handling System (AGHS), at JET. • Review of the Water Detritiation System (WDS) under construction. • Design of the new Material Detritiation Facility (MDF). • Review of problems in fusion related to metal/hydrogen system. - Abstract: The invited talk given at MH2014 in Salford ranged over many issues associated with hydrogen isotope separation, fusion machines and the hydrogen/metal systems found in the Joint European Torus (JET) machine located near Oxford. As this sort of talk does not lend itself well to a paper below I have attempted to highlight some of the more pertinent information. After a description of the Active Gas Handling System (AGHS) a brief summary of isotope separation systems is described followed by descriptions of three major projects currently being undertaken by the Tritium Engineering and Science Group (TESG), the upgrade to the Analytical Systems (AN-GC) at the AGH, the construction of a Water Detritiation System (WDS) and a Material Detritiation Facility (MDF). Finally, a review of some of the challenges facing fusion with respect to metal/hydrogen systems is presented.

  5. Features of Mg2Si Layer Growth in Si/Mg2Si Multilayers

    Directory of Open Access Journals (Sweden)

    L.E. Konotopskyi

    2016-06-01

    Full Text Available Features of magnesium siliced layer growth in Si/Mg2Si multilayers in initial state and after thermal annealing were studied by methods of transmission electron microscopy and X-Ray scattering. As-deposited magnesium silicide layers are amorphous with nanocrystal inclusions of metastable h-Mg2Si. Formation of Mg2Si in hexagonal modification occurs under the influence of stress produced by silicon layers. At T = 723 К Mg2Si layers finished crystallizes in hexagonal modification, with some coarsening of grains. That is accompanied with 7.3 % reduction in period of the Si/Mg2Si multilayer.

  6. Transport and electroluminescence mechanism in Au/(Si/SiO2)/P-Si film

    Institute of Scientific and Technical Information of China (English)

    ZHANG Kai-biao; MA Shu-yi; MA Zi-jun; CHEN Hai-xia

    2006-01-01

    The samples of Au/(Si/SiO2)/p-Si structure were fabricated by using the R.F magnetron sputtering technique.Its carrier transport and electroluminescence mechanism were studied from the I-V curves and EL spectra by using the Configuration Coordinate as a theoretical model.The result indicates that there are two defect centers in SiO2 films.The electron in Au and the hole in p-Si went into SiO2 film by the Fowler-Nordheim tunneling model at a high bias voltage and recombined through these defect centers in SiO2 film.

  7. Photoreflectance Spectroscopy for Study of Si/SiGe/Si Heterostructure

    Institute of Scientific and Technical Information of China (English)

    Liu Zhihong; Chen Changchun; Lin Huiwang; Xiong Xiaoyi; Dou Weizhi; Tsien Pei-Hsin

    2004-01-01

    UHVCVD-grown Si/Si1- xGex/Si heterostructure was investigated by Photoreflectance spectroscopy (PR). The principle of PR used in semiconductor film was thoroughly described. According to the E1 transition energy in the Si1- xGex alloy, the Ge content in SiGe film with constant composition can be accurately characterized. In this study, determine the composition uniformity of larger diameter SiGe epiwafer by PR mapping technique was determined. These results show PR is very promising for Si1- xGex epilayer characterization with constant Ge content and can provide film measurements for production-worthy line monitor.

  8. Competition from Isotopic Modelling

    Directory of Open Access Journals (Sweden)

    Virginie Fabre

    2011-01-01

    Full Text Available During later MOIS3, in Europe two populations were present, autochthonous Neanderthals and modern humans. Ecological competition between these two populations has often been evoked but never demonstrated. Our aim is to establish whether resource competition occurred. In this paper, in order to examine the possibility of ecological competition between these two populations, 599 isotopic data were subjected to rigorous statistical treatment and analysis through mixing models. The aim of this paper was to compare dietary strategies of Neanderthals and modern humans over time. Our conclusions suggest that Neanderthals and modern humans shared dietary habits in the particular environmental context of MOIS3 characterised in Europe by climatic deterioration. In this environmental context, the resource competition between Neanderthals and modern humans may have accelerated the disappearance of the Neanderthal population.

  9. A Laboratory and Theoretical Study of Silicon Hydroxide SiOH

    Science.gov (United States)

    McCarthy, M. C.; Tamassla, F.; Woon, David E.; Thaddeus, P.

    2011-01-01

    The rotational spectrum of the triatomic free radical SiOH in its X 2A' ground electronic state has been observed in a supersonic molecular beam by Fourier transform microwave spectroscopy. The fundamental (10,1 yields 00,0) transition has been detected for normal SiOH and for three rare isotopic species: (30)SiOH, Si(18)OH, and SiOD. The same transition has also been observed in two of three excited vibrational states, v2 and v3, for the most abundant species. Precise spectroscopic constants, including those that describe the effective spin doubling and hydrogen hyperfine structure, have been derived for each isotopic species or vibrational state. To complement the laboratory work, theoretical calculations of the structure, dipole moment, and energies of the X 2A' and low-lying 1 2A'' states have also been undertaken at the coupled cluster level of theory. In agreement with theoretical predictions, we conclude from the hyperfine constants that SiOH is a best described as a pi-type radical, with the unpaired electron localized on a p orbital on the silicon atom. Assuming a bond angle of 118.5 deg, the Si-O bond length is 1.647(2) Angstroms and the O-H bond length is 0.969(4) Angstrom.

  10. Oxide layer dissolution in Si/SiO{sub x}/Si wafer bonded structures

    Energy Technology Data Exchange (ETDEWEB)

    Pippel, E.; Werner, P.; Goesele, U. [Max-Planck-Institut fuer Mikrostrukturphysik, Halle (Germany); Vdovin, V. [Institute for Chemical Problems of Microelectronics, Moscow (Russian Federation); Institute of Rare Metals Giredmet, Moscow (Russian Federation); Zakharov, N.

    2009-10-15

    The evolution of the interfaces of hydrophilic-bonded Si wafers and the corresponding low-angle twist boundary have been analysed in relation to thermal annealing and their relative crystallographic orientation. Two orientation relationships were investigated: Si<001>/Si<001> and Si<001>/Si<110>, where the interfaces are separated by thin native SiO2 layers. The interfaces were analysed by TEM and STEM/EELS. It is found that the decomposition rate of the intermediate oxide layer and the formation of a Si-Si bonded interface depend very much on the lattice mismatch and on the twist angle. The velocity of the dissolution of the thin oxide layers and the formation of Si-Si bonds at the bonding interface depend on the orientation relations of the corresponding wafers. The processes of interface fusion and the dissolution of oxide layer are discussed. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  11. The property of Si/SiGe/Si heterostructure during thermal budget characterized by HRXRD

    Institute of Scientific and Technical Information of China (English)

    CHEN Chang-Chun; LIU Zhi-Hong; HUANG Wen-Tao; DOU Wei-Zhi; ZHANG Wei; TSIEN Pei-Hsin; ZHU De-Zhang

    2003-01-01

    Si/SiGe/Si heterostructures grown by ultra-high-vacuum chemical vapor deposition (UHVCVD) werecharacterized by Rutherford backscattering/Channeling (RBS/C) together with high resolution X ray diffraction(HRXRD). High quality SiGe base layer was obtained. The Si/SiGe/Si heterostructures were subject to conventionalfurnace annealing and rapid thermal annealing with temperature between 750 ℃ and 910 ℃. Both strain and its re-laxation degree in SiGe layer are calculated by HRXRD combined with elastic theory, which are never reported inother literatures. The rapid thermal annealing at elevated temperature between 880 ℃ and 910 ℃ for very short timehad almost no influence on the strain in Si0.84Ge0. 16 epilayer. However, high temperature (900℃) furnace annealingfor 1h prompted the strain in Si0.84Ge0.16 layer to relax.

  12. Isotope Effects in ESR Spectroscopy

    Directory of Open Access Journals (Sweden)

    Werner Herrmann

    2013-06-01

    Full Text Available In order to present the relationship between ESR spectroscopy and isotope effects three levels are considered: (i ESR spectroscopy is described on a general level up to the models for interpretation of the experimental spectra, which go beyond the usually used time and mass independent spin-Hamilton operator, (ii the main characteristics of the generalized isotope effects are worked out, and finally (iii the basic, mainly quantum mechanical effects are used to describe the coupling of electron spins with the degrees of freedom, which are accessible under the selected conditions, of the respective paramagnetic object under investigation. The ESR parameters and the respective models are formalized so far, that they include the time and mass depending influences and reflect the specific isotope effects. Relations will be established between the effects in ESR spectra to spin relaxation, to spin exchange, to the magnetic isotope effect, to the Jahn-Teller effects, as well as to the influence of zero-point vibrations. Examples will be presented which demonstrate the influence of isotopes as well as the kind of accessible information. It will be differentiated with respect to isotope effects in paramagnetic centres itself and in the respective matrices up to the technique of ESR imaging. It is shown that the use of isotope effects is indispensable in ESR spectroscopy.

  13. Si/SiGe/Si HBT的直流特性和低频噪声%Si/SiGe/Si HBT's DC Characterization and Its Low-frequency Noise

    Institute of Scientific and Technical Information of China (English)

    廖小平; 张中平

    2003-01-01

    在对Si/SiGe/Si HBT及其Si兼容工艺的研究基础上,研制成功低噪声Si/SiGe/Si HBT,测试和分析了它的直流特性和低频噪声特性,为具有更好的低噪声性能的Si/SiGe/Si HBT的研究建立了基础.

  14. Kinetic study on the H + SiH4 abstraction reaction using an ab initio potential energy surface.

    Science.gov (United States)

    Cao, Jianwei; Zhang, Zhijun; Zhang, Chunfang; Bian, Wensheng; Guo, Yin

    2011-01-14

    Variational transition state theory calculations with the correction of multidimensional tunneling are performed on a 12-dimensional ab initio potential energy surface for the H + SiH(4) abstraction reaction. The surface is constructed using a dual-level strategy. For the temperature range 200-1600 K, thermal rate constants are calculated and kinetic isotope effects for various isotopic species of the title reaction are investigated. The results are in very good agreement with available experimental data.

  15. The $^{13}C$-pockets in AGB Stars and Their Fingerprints in Mainstream SiC Grains

    CERN Document Server

    Liu, Nan; Gallino, Roberto; Savina, Michael R; Bisterzo, Sara; Gyngard, Frank; Pellin, Michael J; Dauphas, Nicolas

    2015-01-01

    We identify three isotopic tracers that can be used to constrain the $^{13}C$-pocket and show the correlated isotopic ratios of Sr and Ba in single mainstream presolar SiC grains. These newly measured data can be explained by postprocess AGB model calculations with large $^{13}C$-pockets with a range of relatively low $^{13}C$ concentrations, which may suggest that multiple mixing processes contributed to the $^{13}C$-pocket formation in parent AGB stars.

  16. Computational engineering

    CERN Document Server

    2014-01-01

    The book presents state-of-the-art works in computational engineering. Focus is on mathematical modeling, numerical simulation, experimental validation and visualization in engineering sciences. In particular, the following topics are presented: constitutive models and their implementation into finite element codes, numerical models in nonlinear elasto-dynamics including seismic excitations, multiphase models in structural engineering and multiscale models of materials systems, sensitivity and reliability analysis of engineering structures, the application of scientific computing in urban water management and hydraulic engineering, and the application of genetic algorithms for the registration of laser scanner point clouds.

  17. Albumin pre-coating enhances intracellular siRNA delivery of multifunctional amphiphile/siRNA nanoparticles

    Directory of Open Access Journals (Sweden)

    Kummitha CM

    2012-10-01

    Full Text Available China M Kummitha, Anthony S Malamas, Zheng-Rong LuDepartment of Biomedical Engineering, Case Western Reserve University, Cleveland, OH, USAAbstract: Nonspecific association of serum molecules with short-interfering RNA (siRNA nanoparticles can change their physiochemical characteristics, and results in reduced cellular uptake in the target tissue during the systemic siRNA delivery process. Serum albumin is the most abundant protein in the body and has been used to modify the surface of nanoparticles, to inhibit association of other serum molecules. Here, we hypothesized that surface modification of lipid-based nanoparticular siRNA delivery systems with albumin could prevent their interaction with serum proteins, and improve intracellular uptake. In this study, we investigated the influence of albumin on the stability and intracellular siRNA delivery of the targeted siRNA nanoparticles of a polymerizable and pH-sensitive multifunctional surfactant N-(1-aminoethyliminobis[N-(oleoylcysteinylhistinyl-1-aminoethylpropionamide] (EHCO in serum. Serum resulted in a significant increase in the size of targeted EHCO/siRNA nanoparticles and inhibited cellular uptake of the nanoparticles. Coating of targeted EHCO/siRNA nanoparticles with bovine serum albumin at 9.4 µM prior to cell transfection improved cellular uptake and gene silencing efficacy of EHCO/siRNA targeted nanoparticles in serum-containing media, as compared with the uncoated nanoparticles. At a proper concentration, albumin has the potential to minimize interactions of serum proteins with siRNA nanoparticles for effective systemic in vivo siRNA delivery.Keywords: multifunctional, lipid nanoparticles, RNA interference, pH-sensitive amphiphile, siRNA

  18. Isotope-edited infrared spectroscopy.

    Science.gov (United States)

    Buchner, Ginka S; Kubelka, Jan

    2012-01-01

    Isotope-edited infrared (IR) spectroscopy is a powerful tool for studying structural and dynamical properties of peptides and proteins with site-specific resolution. Labeling of selected amide carbonyls with (13)C results in detectable sidebands of amide I' vibrations, which provide information about local conformation and/or solvent exposure without structural perturbation to the protein. Incorporation of isotopically labeled amino acids at specific positions is achieved by the chemical synthesis of the studied proteins. We describe the basic procedures for synthesis of (13)C isotopically edited protein samples, experimental IR spectroscopic measurements, and analysis of the site-specific structural changes from the thermal unfolding IR data.

  19. Carbon isotope geochemistry and geobiology

    Science.gov (United States)

    Desmarais, D.

    1985-01-01

    Carbon isotope fractionation values were used to understand the history of the biosphere. For example, plankton analyses confirmed that marine extinctions at the end of the Cretaceous period were indeed severe (see Hsu's article in Sundquist and Broeker, 1984). Variations in the isotopic compositions of carbonates and evaporitic sulfates during the Paleozoic reflect the relative abundances of euxinic (anoxic) marine environments and organic deposits from terrestrial flora. The carbon isotopic composition of Precambrian sediments suggest that the enzyme ribulose bisphosphate carboxylase has existed for perhaps 3.5 billion years.

  20. Effect of Si/Si1-yCy/Si Barriers on the Characteristics of Si1-xGex/Si Resonant Tunneling Structures

    Institute of Scientific and Technical Information of China (English)

    HAN Ping; CHENG Xue-Mei; Masao Sakuraba; YoungCheon Jeong; Takashi Matsuura; Junichi Murota

    2000-01-01

    P-type double barrier resonant tunneling diodes (RTD) with the single Si0.6Ge0.4 quantum well and double Si0.6 Ge0.4 spacer have been realized by using an ultra clean low-pressure chemical vapor deposition system. The effect of Si1-yCy layer on the characteristics of the devices was shown by comparing the current-voltage (Ⅰ-Ⅴ) characteristics of RTD's of the barriers of Si layers with that of Si/Si1-yCy/Si structures. The peak voltage was gradually increased and the resonant current decreased obviously with increasing C content in the Si/Si1-yCy/Si barriers. The origin of the phenomena above can be attributed to the C related deep acceptor levels in the Si/Si1-yCy/Si barriers. The possible mechanism for the observed Ⅰ-Ⅴcharacteristics was shown more clearly by increasing C content to 3% and changing the thicknesses of Si and Si1-yCy layers in the Si/Si1-yCy/Si barriers.