Infrared presensitization photography at deuterium fluoride laser wavelengths

International Nuclear Information System (INIS)

Geary, J.M.; Ross, K.; Suter, K.

1989-01-01

Near-field irradiance distributions of a deuterium flouride laser system are obtained using infrared presensitization photography. This represents the shortest wavelength region to employ this technique thus far

Infrared Imaging for Inquiry-Based Learning

Science.gov (United States)

Xie, Charles; Hazzard, Edmund

2011-01-01

Based on detecting long-wavelength infrared (IR) radiation emitted by the subject, IR imaging shows temperature distribution instantaneously and heat flow dynamically. As a picture is worth a thousand words, an IR camera has great potential in teaching heat transfer, which is otherwise invisible. The idea of using IR imaging in teaching was first…

Variability in surface infrared reflectance of thirteen nitrile rubber gloves at key wavelengths for analysis of captan.

Science.gov (United States)

Phalen, R N; Que Hee, Shane S

2007-02-01

The aim of this study was to investigate the surface variability of 13 powder-free, unlined, and unsupported nitrile rubber gloves using attenuated total reflection Fourier transform infrared (ATR-FT-IR) spectrophotometry at key wavelengths for analysis of captan contamination. The within-glove, within-lot, and between-lot variability was measured at 740, 1124, 1252, and 1735 cm(-1), the characteristic captan reflectance minima wavelengths. Three glove brands were assessed after conditioning overnight at relative humidity (RH) values ranging from 2 +/- 1 to 87 +/- 4% and temperatures ranging from -8.6 +/- 0.7 to 59.2 +/- 0.9 degrees C. For all gloves, 1735 cm(-1) provided the lowest background absorbance and greatest potential sensitivity for captan analysis on the outer glove surface: absorbances ranged from 0.0074 +/- 0.0005 (Microflex) to 0.0195 +/- 0.0024 (SafeSkin); average within-glove coefficients of variation (CV) ranged from 2.7% (Best, range 0.9-5.3%) to 10% (SafeSkin, 1.2-17%); within-glove CVs greater than 10% were for one brand (SafeSkin); within-lot CVs ranged from 2.8% (Best N-Dex) to 28% (SafeSkin Blue); and between-lot variation was statistically significant (p < or = 0.05) for all but two SafeSkin lots. The RH had variable effects dependent on wavelength, being minimal at 1735, 1252, and 1124 cm(-1) and highest at 3430 cm(-1) (O-H stretch region). There was no significant effect of temperature conditioning. Substantial within-glove, within-lot, and between-lot variability was observed. Thus, surface analysis using ATR-FT-IR must treat glove brands and lots as different. ATR-FT-IR proved to be a useful real-time analytical tool for measuring glove variability, detecting surface humidity effects, and choosing selective and sensitive wavelengths for analysis of nonvolatile surface contaminants.

Infrared polarimetry of the reflection nebula near L 1551 IRS 5

Energy Technology Data Exchange (ETDEWEB)

Nagata, Tetsuya; Yamashita, Takuya; Sato, Shuji; Suzuki, Hiro; Hough, J H; Garden, R; Gatley, I

1986-11-01

The K-band polarization has been measured in the region extending 30 arcsec to the SW of L 1551 IRS5. The degree of polarization is exceptionally high, reaching approx. 67 per cent. The large polarizations and the azimuthal pattern of the position angles are attributed to scattering of infrared radiation from IRS5 by dust grains. The infrared brightness distribution resembles that of the optical nebulosity. It is proposed that infrared scattering occurs at the 'walls' of a cavity formed by the interaction of stellar winds with the ambient cloud.

Chemical profiling and adulteration screening of Aquilariae Lignum Resinatum by Fourier transform infrared (FT-IR) spectroscopy and two-dimensional correlation infrared (2D-IR) spectroscopy.

Science.gov (United States)

Qu, Lei; Chen, Jian-Bo; Zhang, Gui-Jun; Sun, Su-Qin; Zheng, Jing

2017-03-05

As a kind of expensive perfume and valuable herb, Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy is employed to establish a simple and quick method for the adulteration screening of ALR. First, the principal chemical constituents of ALR are characterized by FT-IR spectroscopy at room temperature and two-dimensional correlation infrared (2D-IR) spectroscopy with thermal perturbation. Besides the common cellulose and lignin compounds, a certain amount of resin is the characteristic constituent of ALR. Synchronous and asynchronous 2D-IR spectra indicate that the resin (an unstable secondary metabolite) is more sensitive than cellulose and lignin (stable structural constituents) to the thermal perturbation. Using a certified ALR sample as the reference, the infrared spectral correlation threshold is determined by 30 authentic samples and 6 adulterated samples. The spectral correlation coefficient of an authentic ALR sample to the standard reference should be not less than 0.9886 (p=0.01). Three commercial adulterated ALR samples are identified by the correlation threshold. Further interpretation of the infrared spectra of the adulterated samples indicates the common adulterating methods - counterfeiting with other kind of wood, adding ingredient such as sand to increase the weight, and adding the cheap resin such as rosin to increase the content of resin compounds. Results of this research prove that FT-IR spectroscopy can be used as a simple and accurate quality control method of ALR. Copyright © 2016 Elsevier B.V. All rights reserved.

Room temperature mid-IR single photon spectral imaging

DEFF Research Database (Denmark)

Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter; Pedersen, Christian

2012-01-01

Spectral imaging and detection of mid-infrared (mid-IR) wavelengths are emerging as an enabling technology of great technical and scientific interest; primarily because important chemical compounds display unique and strong mid-IR spectral fingerprints revealing valuable chemical information. Whi...... 20 % for polarized incoherent light at 3 \\mum. The proposed method is relevant for existing and new mid-IR applications like gas analysis and medical diagnostics....

Portable Long-Wavelength Infrared Camera for Civilian Application

Science.gov (United States)

Gunapala, S. D.; Krabach, T. N.; Bandara, S. V.; Liu, J. K.

1997-01-01

In this paper, we discuss the performance of this portable long-wavelength infrared camera in quantum efficiency, NEAT, minimum resolvable temperature differnce (MRTD), uniformity, etc. and its application in science, medicine and defense.

History of infrared detectors

Science.gov (United States)

Rogalski, A.

2012-09-01

This paper overviews the history of infrared detector materials starting with Herschel's experiment with thermometer on February 11th, 1800. Infrared detectors are in general used to detect, image, and measure patterns of the thermal heat radiation which all objects emit. At the beginning, their development was connected with thermal detectors, such as thermocouples and bolometers, which are still used today and which are generally sensitive to all infrared wavelengths and operate at room temperature. The second kind of detectors, called the photon detectors, was mainly developed during the 20th Century to improve sensitivity and response time. These detectors have been extensively developed since the 1940's. Lead sulphide (PbS) was the first practical IR detector with sensitivity to infrared wavelengths up to ˜3 μm. After World War II infrared detector technology development was and continues to be primarily driven by military applications. Discovery of variable band gap HgCdTe ternary alloy by Lawson and co-workers in 1959 opened a new area in IR detector technology and has provided an unprecedented degree of freedom in infrared detector design. Many of these advances were transferred to IR astronomy from Departments of Defence research. Later on civilian applications of infrared technology are frequently called "dual-use technology applications." One should point out the growing utilisation of IR technologies in the civilian sphere based on the use of new materials and technologies, as well as the noticeable price decrease in these high cost technologies. In the last four decades different types of detectors are combined with electronic readouts to make detector focal plane arrays (FPAs). Development in FPA technology has revolutionized infrared imaging. Progress in integrated circuit design and fabrication techniques has resulted in continued rapid growth in the size and performance of these solid state arrays.

New infrared observations of IRS 1, IRS 3, and the adjacent nebula in the OMC-2 cluster

International Nuclear Information System (INIS)

Pendelton, Y.; Werner, M.; Dinerstein, H.

1984-01-01

Recent reports show that near infrared reflection nebulae are often observed around embedded protostellar objects. New observations are here reported of the infrared cluster of low luminosity protostars in Orion Molecular Cloud 2 (OMC2). It has been determined that the asymmetric distribution of the extended emission seen about IRS1 is in fact another infrared reflection nebula. Observations of near infrared polarimetry, photometry, and spectrophotometry were carried out at the NASA Infrared Telescope Facility October 1982 and January 1983. (author)

OH/IR stars in the Galaxy

International Nuclear Information System (INIS)

Baud, B.

1978-01-01

Radio astronomical observations leading to the discovery of 71 OH/IR sources are described in this thesis. These OH/IR sources are characterized by their double peaked OH emission profile at a wavelength of 18 cm and by their strong IR infrared emission. An analysis of the distribution and radial velocities of a number of previously known and new OH/IR sources was performed. The parameter ΔV (the velocity separation between two emission peaks of the 18 cm line profile) was found to be a good criterion for a population classification with respect to stellar age

Ultra-broadband mid-wave-IR upconversion detection

DEFF Research Database (Denmark)

Barh, Ajanta; Pedersen, Christian; Tidemand-Lichtenberg, Peter

2017-01-01

In this Letter, we demonstrate efficient room temperature detection of ultra-broadband mid-wave-infrared (MWIR) light with an almost flat response over more than 1200 nm, exploiting an efficient nonlinear upconversion technique. Black-body radiation from a hot soldering iron rod is used as the IR...... test source. Placing a 20 mm long periodically poled lithium niobate crystal in a compact intra-cavity setup (> 20 WCW pump at 1064 nm), MWIR wavelengths ranging from 3.6 to 4.85 mu m are upconverted to near-infrared (NIR) wavelengths (820-870 nm). The NIR light is detected using a standard low...

Visualizing Infrared (IR) Spectroscopy with Computer Animation

Science.gov (United States)

Abrams, Charles B.; Fine, Leonard W.

1996-01-01

IR Tutor, an interactive, animated infrared (IR) spectroscopy tutorial has been developed for Macintosh and IBM-compatible computers. Using unique color animation, complicated vibrational modes can be introduced to beginning students. Rules governing the appearance of IR absorption bands become obvious because the vibrational modes can be visualized. Each peak in the IR spectrum is highlighted, and the animation of the corresponding normal mode can be shown. Students can study each spectrum stepwise, or click on any individual peak to see its assignment. Important regions of each spectrum can be expanded and spectra can be overlaid for comparison. An introduction to the theory of IR spectroscopy is included, making the program a complete instructional package. Our own success in using this software for teaching and research in both academic and industrial environments will be described. IR Tutor consists of three sections: (1) The 'Introduction' is a review of basic principles of spectroscopy. (2) 'Theory' begins with the classical model of a simple diatomic molecule and is expanded to include larger molecules by introducing normal modes and group frequencies. (3) 'Interpretation' is the heart of the tutorial. Thirteen IR spectra are analyzed in detail, covering the most important functional groups. This section features color animation of each normal mode, full interactivity, overlay of related spectra, and expansion of important regions. This section can also be used as a reference.

Ground-based Detection of Deuterated Water in Comet C/2014 Q2 (Lovejoy) at IR Wavelengths

Energy Technology Data Exchange (ETDEWEB)

Paganini, L.; Mumma, M. J.; Villanueva, G. L. [Goddard Center for Astrobiology, NASA Goddard Space Flight Center, Greenbelt, MD (United States); Gibb, E. L. [Department of Physics and Astronomy, University of Missouri, St. Louis, MO (United States)

2017-02-20

We conducted a deep search for deuterated water (HDO) in the Oort Cloud comet C/2014 Q2 (Lovejoy), through infrared (IR) spectroscopy with NIRSPEC at the Keck Observatory. In this Letter, we present our detections of HDO and water (H{sub 2}O) in comet Lovejoy on 2015 February 4 (post-perihelion) after 1 hr integration on source. The IR observations allowed simultaneous detection of H{sub 2}O and HDO, yielding production rates of 5.9 ± 0.13 × 10{sup 29} and 3.6 ± 1.0 × 10{sup 26} molecules s{sup −1}, respectively. The simultaneous detection permitted accurate determination of the isotopic ratio (D/H) in water of 3.02 ± 0.87 × 10{sup −4}, i.e., larger than the value for water in terrestrial oceans (or Vienna Standard Mean Ocean Water, VSMOW) by a factor of 1.94 ± 0.56. This D/H ratio in water exceeds the value obtained independently at millimeter wavelengths (0.89 ± 0.25 VSMOW; pre-perihelion). We discuss these parameters in the context of origins and emphasize the need for contemporaneous measurements of HDO and H{sub 2}O.

Ground-based Detection of Deuterated Water in Comet C/2014 Q2 (Lovejoy) at IR Wavelengths

International Nuclear Information System (INIS)

Paganini, L.; Mumma, M. J.; Villanueva, G. L.; Gibb, E. L.

2017-01-01

We conducted a deep search for deuterated water (HDO) in the Oort Cloud comet C/2014 Q2 (Lovejoy), through infrared (IR) spectroscopy with NIRSPEC at the Keck Observatory. In this Letter, we present our detections of HDO and water (H 2 O) in comet Lovejoy on 2015 February 4 (post-perihelion) after 1 hr integration on source. The IR observations allowed simultaneous detection of H 2 O and HDO, yielding production rates of 5.9 ± 0.13 × 10 29 and 3.6 ± 1.0 × 10 26 molecules s −1 , respectively. The simultaneous detection permitted accurate determination of the isotopic ratio (D/H) in water of 3.02 ± 0.87 × 10 −4 , i.e., larger than the value for water in terrestrial oceans (or Vienna Standard Mean Ocean Water, VSMOW) by a factor of 1.94 ± 0.56. This D/H ratio in water exceeds the value obtained independently at millimeter wavelengths (0.89 ± 0.25 VSMOW; pre-perihelion). We discuss these parameters in the context of origins and emphasize the need for contemporaneous measurements of HDO and H 2 O.

Coronal magnetic fields inferred from IR wavelength and comparison with EUV observations

Directory of Open Access Journals (Sweden)

Y. Liu

2009-07-01

Full Text Available Spectropolarimetry using IR wavelength of 1075 nm has been proved to be a powerful tool for directly mapping solar coronal magnetic fields including transverse component directions and line-of-sight component intensities. Solar tomography, or stereoscopy based on EUV observations, can supply 3-D information for some magnetic field lines in bright EUV loops. In a previous paper \\citep{liu08} the locations of the IR emission sources in the 3-D coordinate system were inferred from the comparison between the polarization data and the potential-field-source-surface (PFSS model, for one of five west limb regions in the corona (Lin et al., 2004. The paper shows that the region with the loop system in the active region over the photospheric area with strong magnetic field intensity is the region with a dominant contribution to the observed Stokes signals. So, the inversion of the measured Stokes parameters could be done assuming that most of the signals come from a relatively thin layer over the area with a large photospheric magnetic field strength. Here, the five limb coronal regions are studied together in order to study the spatial correlation between the bright EUV loop features and the inferred IR emission sources. It is found that, for the coronal regions above the stronger photospheric magnetic fields, the locations of the IR emission sources are closer to or more consistent with the bright EUV loop locations than those above weaker photospheric fields. This result suggests that the structures of the coronal magnetic fields observed at IR and EUV wavelengths may be different when weak magnetic fields present there.

$β'_{IR}$ at an Infrared Fixed Point in Chiral Gauge Theories

DEFF Research Database (Denmark)

Ryttov, Thomas A.; Shrock, Robert

2018-01-01

We present scheme-independent calculations of the derivative of the beta function, denoted $\\beta'_{IR}$, at a conformally invariant infrared (IR) fixed point, in several asymptotically free chiral gauge theories, namely SO($4k+2$) with $2 \\le k \\le 4$ with respective numbers $N_f$ of fermions...

Infrared

Science.gov (United States)

Vollmer, M.

2013-11-01

'Infrared' is a very wide field in physics and the natural sciences which has evolved enormously in recent decades. It all started in 1800 with Friedrich Wilhelm Herschel's discovery of infrared (IR) radiation within the spectrum of the Sun. Thereafter a few important milestones towards widespread use of IR were the quantitative description of the laws of blackbody radiation by Max Planck in 1900; the application of quantum mechanics to understand the rotational-vibrational spectra of molecules starting in the first half of the 20th century; and the revolution in source and detector technologies due to micro-technological breakthroughs towards the end of the 20th century. This has led to much high-quality and sophisticated equipment in terms of detectors, sources and instruments in the IR spectral range, with a multitude of different applications in science and technology. This special issue tries to focus on a few aspects of the astonishing variety of different disciplines, techniques and applications concerning the general topic of infrared radiation. Part of the content is based upon an interdisciplinary international conference on the topic held in 2012 in Bad Honnef, Germany. It is hoped that the information provided here may be useful for teaching the general topic of electromagnetic radiation in the IR spectral range in advanced university courses for postgraduate students. In the most general terms, the infrared spectral range is defined to extend from wavelengths of 780 nm (upper range of the VIS spectral range) up to wavelengths of 1 mm (lower end of the microwave range). Various definitions of near, middle and far infrared or thermal infrared, and lately terahertz frequencies, are used, which all fall in this range. These special definitions often depend on the scientific field of research. Unfortunately, many of these fields seem to have developed independently from neighbouring disciplines, although they deal with very similar topics in respect of the

Infrared-faint radio sources in the SERVS deep fields. Pinpointing AGNs at high redshift

NARCIS (Netherlands)

Maini, A.; Prandoni, I.; Norris, R. P.; Spitler, L. R.; Mignano, A.; Lacy, M.; Morganti, R.

2016-01-01

Context. Infrared-faint radio sources (IFRS) represent an unexpected class of objects which are relatively bright at radio wavelength, but unusually faint at infrared (IR) and optical wavelengths. A recent and extensive campaign on the radio-brightest IFRSs (S1.4 GHz≳ 10 mJy) has provided evidence

Effect of graphene on plasmonic metasurfaces at infrared wavelengths

Directory of Open Access Journals (Sweden)

Shinpei Ogawa

2013-11-01

Full Text Available Significant enhancement of infrared transmittance by the presence of a graphene layer on a plasmonic metasurface (PLM has been demonstrated. PLMs with different configurations were fabricated, and their transmittance with and without graphene was compared. Selective enhancement by graphene occurred at the plasmon resonance wavelength. The degree of enhancement was found to depend on the width of the gap between the periodic metal regions in the PLM. A maximum enhancement of ∼210% was achieved at a wavelength of 10 μm. The ability to achieve such a drastic increase in transmittance at the plasmon resonant wavelength is expected to lead to improvements in the performance of energy collecting devices and optical sensors.

Long wavelength infrared radiation thermometry for non-contact temperature measurements in gas turbines

Science.gov (United States)

Manara, J.; Zipf, M.; Stark, T.; Arduini, M.; Ebert, H.-P.; Tutschke, A.; Hallam, A.; Hanspal, J.; Langley, M.; Hodge, D.; Hartmann, J.

2017-01-01

The objective of the EU project "Sensors Towards Advanced Monitoring and Control of Gas Turbine Engines (acronym STARGATE)" is the development of a suite of advanced sensors, instrumentation and related systems in order to contribute to the developing of the next generation of green and efficient gas turbine engines. One work package of the project deals with the design and development of a long wavelength infrared (LWIR) radiation thermometer for the non-contact measurement of the surface temperature of thermal barrier coatings (TBCs) during the operation of gas turbine engines. For opaque surfaces (e.g. metals or superalloys) radiation thermometers which are sensitive in the near or short wavelength infrared are used as state-of-the-art method for non-contact temperature measurements. But this is not suitable for oxide ceramic based TBCs (e.g. partially yttria stabilized zirconia) as oxide ceramics are semi-transparent in the near and short wavelength infrared spectral region. Fortunately the applied ceramic materials are non-transparent in the long wavelength infrared and additionally exhibit a high emittance in this wavelength region. Therefore, a LWIR pyrometer can be used for non-contact temperature measurements of the surfaces of TBCs as such pyrometers overcome the described limitation of existing techniques. For performing non-contact temperature measurements in gas turbines one has to know the infrared-optical properties of the applied TBCs as well as of the hot combustion gas in order to properly analyse the measurement data. For reaching a low uncertainty on the one hand the emittance of the TBC should be high (>0.9) in order to reduce reflections from the hot surrounding and on the other hand the absorbance of the hot combustion gas should be low (<0.1) in order to decrease the influence of the gas on the measured signal. This paper presents the results of the work performed by the authors with focus on the implementation of the LWIR pyrometer and the

Results with the UKIRT infrared camera

International Nuclear Information System (INIS)

Mclean, I.S.

1987-01-01

Recent advances in focal plane array technology have made an immense impact on infrared astronomy. Results from the commissioning of the first infrared camera on UKIRT (the world's largest IR telescope) are presented. The camera, called IRCAM 1, employs the 62 x 58 InSb DRO array from SBRC in an otherwise general purpose system which is briefly described. Several imaging modes are possible including staring, chopping and a high-speed snapshot mode. Results to be presented include the first true high resolution images at IR wavelengths of the entire Orion nebula

Efficient femtosecond mid-infrared pulse generation by dispersivewave radiation in bulk lithium niobate crystal

DEFF Research Database (Denmark)

Zhou, Binbin; Guo, Hairun; Bache, Morten

2014-01-01

We experimentally demonstrate efficient mid-infrared pulse generation by dispersive wave radiation in bulk lithium niobate crystal. Femtosecond mid-IR pulses centering from 2.8–2.92 µm are generated using the single pump wavelengths from 1.25–1.45 µm.......We experimentally demonstrate efficient mid-infrared pulse generation by dispersive wave radiation in bulk lithium niobate crystal. Femtosecond mid-IR pulses centering from 2.8–2.92 µm are generated using the single pump wavelengths from 1.25–1.45 µm....

Design of visible and IR infrared dual-band common-path telescope system

Science.gov (United States)

Guo, YuLin; Yu, Xun; Tao, Yu; Jiang, Xu

2018-01-01

The use of visible and IR infrared dual-band combination can effectively improve the performance of photoelectric detection system,TV and IR system were designed with the common path by the common reflection optical system.A TV/IR infrared common-caliber and common-path system is designed,which can realize the Remote and all-day information.For the 640×512 cooled focal plane array,an infrared middle wave system was presented with a focal length of 600mm F number of 4 field of view(FOV) of 0.38°×0.43°, the system uses optical passive thermal design, has o compact structure and can meet 100% cold shield efficiency,meanwhile it meets the design requirements of lightweight and athermalization. For the 1920×1080 pixels CCD,a visible (TV) system ,which had 500mm focal length, 4F number,was completed.The final optical design along with their modulation transfer function is presented,showing excellent imaging performance in dual-band at the temperature range between -40° and 60°.

Silicon nitride photonics: from visible to mid-infrared wavelengths

Science.gov (United States)

Micó, Gloria; Bru, Luis A.; Pastor, Daniel; Doménech, David; Fernández, Juan; Sánchez, Ana; Cirera, Josep M.; Domínguez, Carlos; Muñoz, Pascual

2018-02-01

Silicon nitride has received a lot of attention during the last ten years, for applications such as bio-photonics, tele/datacom, optical signal processing and sensing. In this paper, firstly an updated review of the state of the art of silicon nitride photonics integration platforms will be provided. Secondly, our developments on a moderate confinement Si3N4 platform in the near-infrared will be presented. Finally, our steps towards establishing a Si3N4 based platform for broadband operation spanning from visible to mid-infrared wavelengths will be introduced.

AIRS/Aqua Level 1C Infrared (IR) resampled and corrected radiances V006

Data.gov (United States)

National Aeronautics and Space Administration — The AIRS Infrared (IR) level 1C data set contains AIRS infrared calibrated and geolocated radiances in W/m2/micron/ster. This data set is generated from AIRS level...

Femtosecond few-cycle mid-infrared laser pulses

DEFF Research Database (Denmark)

Liu, Xing

The few-cycle pulses of mid-infrared (mid-IR, wavelength 2-10 microns) have attracted increasing attention owing to their great potentials for high order harmonic generation, time-resolved spectroscopy, precision of cutting and biomedical science.In this thesis, mid-IR frequency conversion.......2 - 5.5 μm with only one fixed pump wavelength, a feature absent in Kerr media. Finally, we experimentally observe supercontinuum generation spanning 1.5 octaves, generated in a 10 mm long silicon-rich nitride waveguide pumped by 100 pJ femtosecond pulses from an erbium fiber laser. The waveguide has...

Photoionization Modeling of Infrared Fine-Structure Lines in Luminous Galaxies with Central Dust-Bounded Nebulae

National Research Council Canada - National Science Library

Fischer, Jacqueline; Allen, Robert; Dudley, C. C; Satyapal, Shobita; Luhman, Michael L; Wolfire, Mark G; Smith, Howard A

2001-01-01

Far-infrared spectroscopy of a small sample of IR-bright galaxies taken with the Infrared Space Observatory Long Wavelength Spectrometer has revealed a dramatic progression extending from strong fine...

Transformation optics and metamaterials at infrared wavelength: engineering of permittivity and permeability

Science.gov (United States)

Ghasemi, Rasta; Degiron, Aloyse; Leroux, Xavier; Lupu, Anatole; de Lustrac, André

2013-05-01

The transformation optics was introduced by J. Pendry and U. Leonhardt in 2006 [1,2]. In this method an initial space is transformed into a new space and this transformed space can be materialized by a material, which the electromagnetic parameters can be deduced from the metric of the transformed space. In the general case the electromagnetic parameters are anisotropic tensors. At microwave frequencies these materials can be realized using classical metamaterials like SRR form J. Pendry or ELC from D. Smith [3]. At infrared wavelengths this realization is a challenge because the dimensions of the metamaterials are much smaller than the wavelength and become nanometric. Then the design of these metamaterials must be simplified and original methods must be developed to allow the realization of these metamaterials with controlled electromagnetic properties. In this paper we describe the realization of a multilayer metamaterial working at infrared wavelength, which the permittivity and the permeability can be adjusted separately. We give some examples of realized multilayer materials operating around 150THz, with a comparison between the results of full wave simulations of these materials and their characterizations using a Fourier Transform Infrared Spectrometer.

High-definition Fourier Transform Infrared (FT-IR) Spectroscopic Imaging of Human Tissue Sections towards Improving Pathology

Science.gov (United States)

Nguyen, Peter L.; Davidson, Bennett; Akkina, Sanjeev; Guzman, Grace; Setty, Suman; Kajdacsy-Balla, Andre; Walsh, Michael J.

2015-01-01

High-definition Fourier Transform Infrared (FT-IR) spectroscopic imaging is an emerging approach to obtain detailed images that have associated biochemical information. FT-IR imaging of tissue is based on the principle that different regions of the mid-infrared are absorbed by different chemical bonds (e.g., C=O, C-H, N-H) within cells or tissue that can then be related to the presence and composition of biomolecules (e.g., lipids, DNA, glycogen, protein, collagen). In an FT-IR image, every pixel within the image comprises an entire Infrared (IR) spectrum that can give information on the biochemical status of the cells that can then be exploited for cell-type or disease-type classification. In this paper, we show: how to obtain IR images from human tissues using an FT-IR system, how to modify existing instrumentation to allow for high-definition imaging capabilities, and how to visualize FT-IR images. We then present some applications of FT-IR for pathology using the liver and kidney as examples. FT-IR imaging holds exciting applications in providing a novel route to obtain biochemical information from cells and tissue in an entirely label-free non-perturbing route towards giving new insight into biomolecular changes as part of disease processes. Additionally, this biochemical information can potentially allow for objective and automated analysis of certain aspects of disease diagnosis. PMID:25650759

Application of Fourier-transform infrared (FT-IR) spectroscopy for simple and easy determination of chylomicron-triglyceride and very low density lipoprotein-triglyceride.

Science.gov (United States)

Sato, Kenichi; Seimiya, Masanori; Kodera, Yoshio; Kitamura, Akihide; Nomura, Fumio

2010-02-01

Fourier-transform infrared (FT-IR) spectroscopy is a simple and reagent-free physicochemical analysis method, and is a potential alternative to more time-consuming and labor-intensive procedures. In this study, we aimed to use FT-IR spectroscopy to determine serum concentrations of chylomicron-triglyceride (TG) and very low density lipoprotein (VLDL)-TG. We analyzed a chylomicron fraction and VLDL fraction, which had been obtained by ultracentrifugation, to search for wavelengths to designate to each fraction. Then, partial least square (PLS) calibrations were developed using a training set of samples, for which TG concentrations had been determined by conventional procedures. Validation was conducted with another set of samples using the PLS model to predict serum TG concentrations on the basis of the samples' IR spectra. We analyzed a total of 150 samples. Serum concentrations of chylomicron-TG and VLDL-TG estimated by FT-IR spectroscopy agreed well with those obtained by the reference method (r=0.97 for both lipoprotein fractions). FT-IR spectrometric analysis required 15mul of serum and was completed within 1min. Serum chylomicron-TG and VLDL-TG concentrations can be determined with FT-IR spectroscopy. This rapid and simple test may have a great impact on the management of patients with dyslipidemia. Copyright 2009. Published by Elsevier B.V.

Mid-wavelength infrared unipolar nBp superlattice photodetector

Science.gov (United States)

Kazemi, Alireza; Myers, Stephen; Taghipour, Zahra; Mathews, Sen; Schuler-Sandy, Ted; Lee, Seunghyun; Cowan, Vincent M.; Garduno, Eli; Steenbergen, Elizabeth; Morath, Christian; Ariyawansa, Gamini; Scheihing, John; Krishna, Sanjay

2018-01-01

We report a Mid-Wavelength Infrared (MWIR) barrier photodetector based on the InAs/GaSb/AlSb type-II superlattice (T2SL) material system. The nBp design consists of a single unipolar barrier (InAs/AlSb SL) placed between a 4 μm thick p-doped absorber (InAs/GaSb SL) and an n-type contact layer (InAs/GaSb SL). At 80 K, the device exhibited a 50% cut-off wavelength of 5 μm, was fully turned-ON at zero bias and the measured QE was 50% (front side illumination with no AR coating) at 4.5 μm with a dark current density of 4.7 × 10-6 A/cm2 at Vb = 50 mV. At 150 K and Vb = 50 mV, the 50% cut-off wavelength increased to 5.3 μm, and the QE was 54% at 4.5 μm with a dark current of 5.0 × 10-4 A/cm2.

Infrared solar physics from the South Pole

Science.gov (United States)

Deming, Drake

1989-01-01

Infrared (IR) observations of the sun could greatly benefit from the quality of the South Pole as an IR site, and the potential for multi-day sequences of uninterrupted observations. A nearly continuous picture of the evolution of the magnetic field in solar active regions could be obtained using vector magnetographs, especially vector magnetographs which incorporate IR array detectors. Observations of the sun over a range of wavelengths in the IR continuum could also be used to study the vertical propagation characteristics of the solar p-mode oscillations.

Development of a two-wavelength IR laser absorption diagnostic for propene and ethylene

Science.gov (United States)

Parise, T. C.; Davidson, D. F.; Hanson, R. K.

2018-05-01

A two-wavelength infrared laser absorption diagnostic for non-intrusive, simultaneous quantitative measurement of propene and ethylene was developed. To this end, measurements of absorption cross sections of propene and potential interfering species at 10.958 µm were acquired at high-temperatures. When used in conjunction with existing absorption cross-section measurements of ethylene and other species at 10.532 µm, a two-wavelength diagnostic was developed to simultaneously measure propene and ethylene, the two small alkenes found to generally dominate the final decomposition products of many fuel hydrocarbon pyrolysis systems. Measurements of these two species is demonstrated using this two-wavelength diagnostic scheme for propene decomposition between 1360 and 1710 K.

IV-VI mid-IR tunable lasers and detectors with external resonant cavities

Science.gov (United States)

Zogg, H.; Rahim, M.; Khiar, A.; Fill, M.; Felder, F.; Quack, N.; Blunier, S.; Dual, J.

2009-08-01

Wavelength tunable emitters and detectors in the mid-IR wavelength region allow applications including thermal imaging and spectroscopy. Such devices may be realized using a resonant cavity. By mechanically changing the cavity length with MEMS mirror techniques, the wavelengths may be tuned over a considerable range. Vertical external cavity surface emitting lasers (VECSEL) may be applied for gas spectroscopy. Resonant cavity enhanced detectors (RCED) are sensitive at the cavity resonance only. They may be applied for low resolution spectroscopy, and, when arrays of such detectors are realized, as multicolor IR-FPA or IR-AFPA (IR-adaptive focal plane arrays). We review mid-infrared RCEDs and VECSELs using narrow gap IV-VI (lead chalcogenide) materials like PbTe and PbSe as the active medium. IV-VIs are fault tolerant and allow easy wavelength tuning. The VECSELs operate up to above room temperature and emit in the 4 - 5 μm range with a PbSe active layer. RCEDs with PbTe absorbing layers above 200 K operating temperature have higher sensitivities than the theoretical limit for a similar broad-band detector coupled with a passive tunable band-filter.

Laser-induced filaments in the mid-infrared

International Nuclear Information System (INIS)

Zheltikov, A M

2017-01-01

Laser-induced filamentation in the mid-infrared gives rise to unique regimes of nonlinear wave dynamics and reveals in many ways unusual nonlinear-optical properties of materials in this frequency range. The λ 2 scaling of the self-focusing threshold P cr , with radiation wavelength λ , allows the laser powers transmitted by single mid-IR filaments to be drastically increased without the loss of beam continuity and spatial coherence. When extended to the mid-infrared, laser filamentation enables new methods of pulse compression. Often working around the universal physical limitations, it helps generate few-cycle and subcycle field waveforms within an extraordinarily broad range of peak powers, from just a few up to hundreds of P cr . As a part of a bigger picture, laser-induced filamentation in the mid-infrared offers important physical insights into the general properties of the nonlinear-optical response of matter as a function of the wavelength. Unlike their near-infrared counterparts, which can be accurately described within the framework of perturbative nonlinear optics, mid-infrared filaments often entangle perturbative and nonperturbative nonlinear-optical effects, showing clear signatures of strong-field optical physics. With the role of nonperturbative nonlinear-optical phenomena growing, as a general tendency, with the field intensity and the driver wavelength, extension of laser filamentation to even longer driver wavelengths, toward the long-wavelength infrared, promises a hic sunt dracones land. (topical review)

Quantum Well Infrared Photodetectors: Device Physics and Light Coupling

Science.gov (United States)

Bandara, S. V.; Gunapala, S. D.; Liu, J. K.; Mumolo, J.; Luong, E.; Hong, W.; Sengupta, D. K.

1997-01-01

It is customary to make infrared (IR) detectors in the long wavelength range by utilizing the interband transition which promotes an electron across the band gap (Eg) from the valence band to the conduction.

Study on IR Properties of Reduced Graphene Oxide

Science.gov (United States)

Ma, Deyue; Li, Xiaoxia; Guo, Yuxiang; Zeng, Yurun

2018-01-01

Firstly, the reduced graphene oxide was prepared by modified hummer method and characterized. Then, the complex refractive index of reduced graphene oxide in IR band was tested and its IR absorption and radiation properties were researched by correlated calculation. The results show that reduced graphene oxide prepared by hummer method are multilayered graphene with defects and functional groups on its surface. Its absorption in near and far IR bands is strong, but it’s weaker in middle IR band. At the IR atmosphere Window, its normal spectral emissivity decreases with wavelength increasing, and its total normal spectral emissivity in 3 ∼ 5μm and 8 ∼ 14μm are 0.75 and 0.625, respectively. Therefore, reduced graphene oxide can be used as IR absorption and coating materials and have a great potential in microwave and infrared compatible materials.

Design of a compact athermalized infrared seeker

Science.gov (United States)

Gao, Qing-jia; Wang, Jian; Sun, Qiang

2017-07-01

In order to meet the application requirement of a certain long wavelength infrared (LWIR) seeker, a small volume, light weight and passively athermalized infrared (IR) objective is designed in this paper. The two-lens telephoto structure is adopted by merely using aluminum alloy as the housing material. By balancing the thermo-optical coefficient and thermal expansion coefficient of materials, an athermalized IR seeker with effective focal length of 90 mm and F number of 1.2 is achieved. The whole optical length is 75 mm, and the weight is only 234 g. The objective can remain fine imaging quality under temperature range from -40 °C to 60 °C, which is beneficial to the lightweight design of IR seekers.

Long wavelength infrared camera (LWIRC): a 10 micron camera for the Keck Telescope

Energy Technology Data Exchange (ETDEWEB)

Wishnow, E.H.; Danchi, W.C.; Tuthill, P.; Wurtz, R.; Jernigan, J.G.; Arens, J.F.

1998-05-01

The Long Wavelength Infrared Camera (LWIRC) is a facility instrument for the Keck Observatory designed to operate at the f/25 forward Cassegrain focus of the Keck I telescope. The camera operates over the wavelength band 7-13 {micro}m using ZnSe transmissive optics. A set of filters, a circular variable filter (CVF), and a mid-infrared polarizer are available, as are three plate scales: 0.05``, 0.10``, 0.21`` per pixel. The camera focal plane array and optics are cooled using liquid helium. The system has been refurbished with a 128 x 128 pixel Si:As detector array. The electronics readout system used to clock the array is compatible with both the hardware and software of the other Keck infrared instruments NIRC and LWS. A new pre-amplifier/A-D converter has been designed and constructed which decreases greatly the system susceptibility to noise.

The wavelength dependence of gold nanorod-mediated optical breakdown during infrared ultrashort pulses

Energy Technology Data Exchange (ETDEWEB)

Davletshin, Yevgeniy R.; Kumaradas, J. Carl [Department of Physics, Ryerson University, Toronto, ON (Canada)

2017-04-15

This paper investigates the wavelength dependence of the threshold of gold nanorod-mediated optical breakdown during picosecond and femtosecond near infrared optical pulses. It was found that the wavelength dependence in the picosecond regime is governed solely by the changes of a nanorod's optical properties. On the other hand, the optical breakdown threshold during femtosecond pulse exposure falls within one of two regimes. When the ratio of the maximum electric field from the outside to the inside of the nanorod is less then 7 (the absorption regime) the seed electrons are initiated by photo-thermal emission, and the wavelength dependence in the threshold of optical breakdown is the result of optical properties of the nanoparticle. When the ratio is greater than 7 (the near-field regime) more seed electrons are initiated by multiphoton ionization, and the wavelength dependence of the threshold of optical breakdown results from a combination of nanorod's optical properties and transitions in the order of multiphoton ionization. The findings of this study can guide the design of nanoparticle based optical breakdown applications. This analysis also deepens the understanding of nanoparticle-mediated laser induced breakdown for picosecond and femtosecond pulses at near infrared wavelengths. (copyright 2017 by WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Solitonic supercontinuum of femtosecond mid-IR pulses in W-type index tellurite fibers with two zero dispersion wavelengths

Directory of Open Access Journals (Sweden)

S. Kedenburg

2016-11-01

Full Text Available We present a detailed experimental parameter study on mid-IR supercontinuum generation in W-type index tellurite fibers, which reveals how the core diameter, pump wavelength, fiber length, and pump power dramatically influence the spectral broadening. As pump source, we use femtosecond mid-IR pulses from a post-amplified optical parametric oscillator tunable between 1.7 μm and 4.1 μm at 43 MHz repetition rate. We are able to generate red-shifted dispersive waves up to a wavelength of 5.1 μm by pumping a tellurite fiber in the anomalous dispersion regime between its two zero dispersion wavelengths. Distinctive soliton dynamics can be identified as the main broadening mechanism resulting in a maximum spectral width of over 2000 nm with output powers of up to 160 mW. We experimentally demonstrated that efficient spectral broadening with considerably improved power proportion in the important first atmospheric transmission window between 3 and 5 μm can be achieved in robust W-type tellurite fibers pumped at long wavelengths by ultra-fast lasers.

Development of an inverse distance weighted active infrared stealth scheme using the repulsive particle swarm optimization algorithm.

Science.gov (United States)

Han, Kuk-Il; Kim, Do-Hwi; Choi, Jun-Hyuk; Kim, Tae-Kuk

2018-04-20

Treatments for detection by infrared (IR) signals are higher than for other signals such as radar or sonar because an object detected by the IR sensor cannot easily recognize its detection status. Recently, research for actively reducing IR signal has been conducted to control the IR signal by adjusting the surface temperature of the object. In this paper, we propose an active IR stealth algorithm to synchronize IR signals from the object and the background around the object. The proposed method includes the repulsive particle swarm optimization statistical optimization algorithm to estimate the IR stealth surface temperature, which will result in a synchronization between the IR signals from the object and the surrounding background by setting the inverse distance weighted contrast radiant intensity (CRI) equal to zero. We tested the IR stealth performance in mid wavelength infrared (MWIR) and long wavelength infrared (LWIR) bands for a test plate located at three different positions on a forest scene to verify the proposed method. Our results show that the inverse distance weighted active IR stealth technique proposed in this study is proved to be an effective method for reducing the contrast radiant intensity between the object and background up to 32% as compared to the previous method using the CRI determined as the simple signal difference between the object and the background.

Properties of the Variation of the Infrared Emission of OH/IR Stars I. The K Band Light Curves

Directory of Open Access Journals (Sweden)

Kyung-Won Suh

2009-09-01

Full Text Available To study properties of the variation of the infrared emission of OH/IR stars, we collect and analyze the infrared observational data in K band for nine OH/IR stars. We use the observational data obtained for about three decades including recent data from the two micron all sky survey (2MASS and the deep near infrared survey of the southern sky (DENIS. We use Marquardt-Levenberg algorithm to determine the pulsation period and amplitude for each star and compare them with previous results of infrared and radio investigations.

Monitoring wine aging with Fourier transform infrared spectroscopy (FT-IR

Directory of Open Access Journals (Sweden)

Basalekou Marianthi

2015-01-01

Full Text Available Oak wood has commonly been used in wine aging but recently other wood types such as Acacia and Chestnut, have attracted the interest of the researchers due to their possible positive contribution to wine quality. However, only the use of oak and chestnut woods is approved by the International Enological Codex of the International Organisation of Vine and Wine. In this study Fourier Transform (FT-mid-infrared spectroscopy combined with Discriminant Analysis was used to differentiate wines aged in barrels made from French oak, American oak, Acacia and Chestnut and in tanks with oak chips, over a period of 12 months. Two red (Mandilaria, Kotsifali and two white (Vilana, Dafni native Greek grape varieties where used to produce four wines. The Fourier Transform Infrared (FT-IR spectra of the samples were recorded on a Zinc Selenide (ZnSe window after incubation at 40 °C for 30 min. A complete differentiation of the samples according to both the type of wood used and the contact time was achieved based on their FT-IR spectra.

Study on Angelica and its different extracts by Fourier transform infrared spectroscopy and two-dimensional correlation IR spectroscopy

Science.gov (United States)

Liu, Hong-xia; Sun, Su-qin; Lv, Guang-hua; Chan, Kelvin K. C.

2006-05-01

In order to develop a rapid and effective analysis method for studying integrally the main constituents in the medicinal materials and their extracts, discriminating the extracts from different extraction process, comparing the categories of chemical constituents in the different extracts and monitoring the qualities of medicinal materials, we applied Fourier transform infrared spectroscopy (FT-IR) associated with second derivative infrared spectroscopy and two-dimensional correlation infrared spectroscopy (2D-IR) to study the main constituents in traditional Chinese medicine Angelica and its different extracts (extracted by petroleum ether, ethanol and water in turn). The findings indicated that FT-IR spectrum can provide many holistic variation rules of chemical constituents. Use of the macroscopical fingerprint characters of FT-IR and 2D-IR spectrum can not only identify the main chemical constituents in medicinal materials and their different extracts, but also compare the components differences among the similar samples. This analytical method is highly rapid, effective, visual and accurate for pharmaceutical research.

Infrared Illuminated CdZnTe detectors with improved performance

International Nuclear Information System (INIS)

Ivanov, V.; Loutchanski, A.; Dorogov, P.; Khinoverov, S.

2013-06-01

It was found that IR illumination of a properly chosen wavelength and intensity can significantly improve spectrometric characteristics of CdZnTe quasi-hemispherical detectors [1]. Improving of the spectrometric characteristics is due to improvement of uniformity of charge collection by the detector volume. For operation at room temperature the optimal wavelength of IR illumination is about 940 nm, but for operation at lower temperature of -20 deg. C the optimal wavelengths of IR illumination is about 1050 nm. Infrared illumination can be performed using conventional low-power IR LEDs. Application of SMD LEDs allows produce miniature detection probes with IR illuminated CdZnTe detectors. We have fabricated and tested a variety of detection probes with CdZnTe quasi-hemispherical detectors from the smallest with volumes of 1-5 mm 3 to larger with volumes of 1.5 cm 3 and 4.0 cm 3 . The use of IR illumination significantly improves spectrometric characteristics of the probes operating at room temperature, especially probes with detectors of large volumes. The probe with the detector of 4 cm 3 without IR illumination had energy resolution of 24.2 keV at 662 keV and of 12.5 keV with IR illumination. (authors)

Exploration of the Infrared Sensitivity for a ZnSe Electrode of an IR Image Converter

Science.gov (United States)

Kurt, H. Hilal

2018-05-01

Significant improvement has been carried out in the field of the II-VI group semiconductor device technology. Semiconductors based on the II-VI group are attractive due to their alternative uses for thermal imaging systems and photonic applications. This study focuses on experimental work on the optical, electrical and structural characterization of an infrared (IR) photodetector zinc selenide (ZnSe). In addition, the IR sensitivity of the ZnSe has primarily been investigated by exploiting the IR responses of the material for various gas pressures, p, and interelectrode distances, d, in the IR converter. The experimental findings include the results of plasma current and plasma discharge emission under various illumination conditions in the IR region. The electron density distributions inside the gas discharge gap have also been simulated in two-dimensional media. Experimentally, the current-voltage, current-time, and discharge light emission plots are produced for a wide experimental parameter range. Consequently, the structural and optical properties have been studied through atomic force microscopy and Fourier-transform infrared spectroscopy techniques to obtain a comprehensive knowledge of the material.

Design and Calibration of a Dispersive Imaging Spectrometer Adaptor for a Fast IR Camera on NSTX-U

Science.gov (United States)

Reksoatmodjo, Richard; Gray, Travis; Princeton Plasma Physics Laboratory Team

2017-10-01

A dispersive spectrometer adaptor was designed, constructed and calibrated for use on a fast infrared camera employed to measure temperatures on the lower divertor tiles of the NSTX-U tokamak. This adaptor efficiently and evenly filters and distributes long-wavelength infrared photons between 8.0 and 12.0 microns across the 128x128 pixel detector of the fast IR camera. By determining the width of these separated wavelength bands across the camera detector, and then determining the corresponding average photon count for each photon wavelength, a very accurate measurement of the temperature, and thus heat flux, of the divertor tiles can be calculated using Plank's law. This approach of designing an exterior dispersive adaptor for the fast IR camera allows accurate temperature measurements to be made of materials with unknown emissivity. Further, the relative simplicity and affordability of this adaptor design provides an attractive option over more expensive, slower, dispersive IR camera systems. This work was made possible by funding from the Department of Energy for the Summer Undergraduate Laboratory Internship (SULI) program. This work is supported by the US DOE Contract No. DE-AC02-09CH11466.

Double Separation Method for Translation of the Infrared Information into a Visible Area

Directory of Open Access Journals (Sweden)

Ivana Žiljak

2009-06-01

Full Text Available Information visualization refers to the wavelength area ranging from 400 to 700 nm. Areas in lower wavelengths ranging from 100 to 400 nm are translated into the visual area with the goal to protect information visible only by applying instruments adapted for the ultraviolet area. Our recent research work refers to the infrared wavelength areas above the visible specter up to 1000 nm. The scientific contribution of this paper is in setting the double separation method for printing with CMYK printing inks with the goal to detect graphic information in the infrared area only. An algorithm has been created for making visual basics in the overall visible specter containing material that responds in the infrared section. This allows planning of areas in all coloring types for one and the same document that contains a secure piece of information. The system is based on double transition transformation of the visible RGB1 information recognition into CMYK2 in the same document. Secure information is recognized with the help of instruments in the set wavelength range. Most of the experiments have been carried out by analyzing the same set of RGB records. Each sample in the set was a test unit coming from another source containing different IR3 components. Thus an innovative method of color mixing has been set where colors appear respectively in daylight and separately according to IR light programming. New IR cryptography is proposed as shown in the experimental work.

A SPITZER IRS STUDY OF INFRARED VARIABILITY IN TRANSITIONAL AND PRE-TRANSITIONAL DISKS AROUND T TAURI STARS

International Nuclear Information System (INIS)

Espaillat, C.; Furlan, E.; D'Alessio, P.; Sargent, B.; Muzerolle, J.; Nagel, E.; Calvet, N.; Watson, Dan M.

2011-01-01

We present a Spitzer IRS study of variability in 14 T Tauri stars in the Taurus and Chamaeleon star-forming regions. The sample is composed of transitional and pre-transitional objects which contain holes and gaps in their disks. We detect variability between 5 and 38 μm in all but two of our objects on timescales of 2-3 years. Most of the variability observed can be classified as seesaw behavior, whereby the emission at shorter wavelengths varies inversely with the emission at longer wavelengths. For many of the objects we can reasonably reproduce the observed variability using irradiated disk models, particularly by changing the height of the inner disk wall by ∼20%. When the inner wall is taller, the emission at the shorter wavelengths is higher since the inner wall dominates the emission at 2-8 μm. The taller inner wall casts a larger shadow on the outer disk wall, leading to less emission at wavelengths beyond 20 μm where the outer wall dominates. We discuss how the possible presence of planets in these disks could lead to warps that cause changes in the height of the inner wall. We also find that crystalline silicates are common in the outer disks of our objects and that in the four disks in the sample with the most crystalline silicates, variability on timescales of 1 week is present. In addition to explaining the infrared variability described above, planets can create shocks and collisions which can crystallize the dust and lead to short timescale variability.

Infrared spectrometry of Venus: IR Fourier spectrometer on Venera 15 as a precursor of PFS for Venus express

Science.gov (United States)

Zasova, L. V.; Moroz, V. I.; Formisano, V.; Ignatiev, N. I.; Khatuntsev, I. V.

2004-01-01

Thermal infrared spectrometry in the range 6-40 μm with spectral resolution of 4.5-6.5 cm -1 was realized onboard of Venera 15 for the middle atmosphere of Venus investigations. The 3-D temperature and zonal wind fields ( h, ϕ, LT) in the range 55-100 km and the 3-D aerosol field ( h, ϕ, LT) in the range 55-70 km were retrieved and analyzed. The solar related waves at isobaric levels, generated by the absorbed solar energy, were investigated. In the thermal IR spectral range the, ν1, ν2 and ν3 SO 2 and the H 2O rotational (40 μm) and vibro-rotational (6.3 μm) absorption bands are observed and used for minor compounds retrieval. An advantage of the thermal infrared spectrometry method is that both the temperature and aerosol profiles, which need for retrieval of the vertical profiles of minor compounds, are evaluated from the same spectrum. The Fourier spectrometer on Venera-15 may be considered as a precursor of the Planetary Fourier Spectrometer (PI Prof. V. Formisano), which is included in the payload of the planned Venus Express mission. It has a spectral range 0.9-45 μm, separated into two channels: a short wavelength channel (SWC) in the range 0.9-5 μm and a long wavelength channel (LWC) from 6 to 45 μm, and spectral resolution of 1-2 cm -1. In the history of planetary Fourier spectrometry the PFS is a unique instrument, which possesses a short wavelength channel. A functioning of this instrument on the polar orbit with a good spatial and local time coverage will advance our knowledge in the fundamental problems of the Venus atmosphere.

Dual-wavelength green laser with a 4.5 THz frequency difference based on self-frequency- doubling in Nd3+ -doped aperiodically poled lithium niobate.

Science.gov (United States)

Maestre, H; Torregrosa, A J; Fernández-Pousa, C R; Rico, M L; Capmany, J

2008-05-01

We report a dual-wavelength continuous-wave laser at 542.4 and 546.8 nm based on an Nd(3+)-doped aperiodically poled lithium niobate crystal. Two fundamental infrared (IR) wavelengths at 1084.8 and 1093.6 nm are simultaneously oscillated and self-frequency-doubled to green. The aperiodic domain distribution patterned in the crystal allows for quasi-phase matched self-frequency-doubling of both IR fundamentals while avoiding their sum-frequency mixing.

INFRARED COLOR-COLOR DIAGRAMS FOR AGB STARS

Directory of Open Access Journals (Sweden)

Kyung-Won Suh

2007-09-01

Full Text Available We present infrared color-color diagrams of AGB stars from the observations at near and mid infrared bands. We compile the observations for hundreds of OH/IR stars and carbon stars using the data from the Midcourse Space Experiment (MSX, the two micron sky survey (2MASS, and the IRAS point source catalog (PSC. We compare the observations with the theoretical evolutionary tracks of AGB stars. From the new observational data base and the theoretical evolution tracks, we discuss the meaning of the infrared color-color diagrams at different wavelengths.

Infrared light-emitting diode radiation causes gravitropic and morphological effects in dark-grown oat seedlings

Science.gov (United States)

Johnson, C. F.; Brown, C. S.; Wheeler, R. M.; Sager, J. C.; Chapman, D. K.; Deitzer, G. F.

1996-01-01

Oat (Avena sativa cv Seger) seedlings were irradiated with IR light-emitting diode (LED) radiation passed through a visible-light-blocking filter. Infrared LED irradiated seedlings exhibited differences in growth and gravitropic response when compared to seedlings grown in darkness at the same temperature. Thus, the oat seedlings in this study were able to detect IR LED radiation. These findings call into question the use of IR LED as a safe-light for some photosensitive plant response experiments. These findings also expand the defined range of wavelengths involved in radiation-gravity (light-gravity) interactions to include wavelengths in the IR region of the spectrum.

New indicator for optimal preprocessing and wavelength selection of near-infrared spectra

NARCIS (Netherlands)

Skibsted, E. T. S.; Boelens, H. F. M.; Westerhuis, J. A.; Witte, D. T.; Smilde, A. K.

2004-01-01

Preprocessing of near-infrared spectra to remove unwanted, i.e., non-related spectral variation and selection of informative wavelengths is considered to be a crucial step prior to the construction of a quantitative calibration model. The standard methodology when comparing various preprocessing

Narrowband infrared emitters for combat ID

Science.gov (United States)

Pralle, Martin U.; Puscasu, Irina; Daly, James; Fallon, Keith; Loges, Peter; Greenwald, Anton; Johnson, Edward

2007-04-01

There is a strong desire to create narrowband infrared light sources as personnel beacons for application in infrared Identify Friend or Foe (IFF) systems. This demand has augmented dramatically in recent years with the reports of friendly fire casualties in Afghanistan and Iraq. ICx Photonics' photonic crystal enhanced TM (PCE TM) infrared emitter technology affords the possibility of creating narrowband IR light sources tuned to specific IR wavebands (near 1-2 microns, mid 3-5 microns, and long 8-12 microns) making it the ideal solution for infrared IFF. This technology is based on a metal coated 2D photonic crystal of air holes in a silicon substrate. Upon thermal excitation the photonic crystal modifies the emitted yielding narrowband IR light with center wavelength commensurate with the periodicity of the lattice. We have integrated this technology with microhotplate MEMS devices to yield 15mW IR light sources in the 3-5 micron waveband with wall plug efficiencies in excess of 10%, 2 orders of magnitude more efficient that conventional IR LEDs. We have further extended this technology into the LWIR with a light source that produces 9 mW of 8-12 micron light at an efficiency of 8%. Viewing distances >500 meters were observed with fielded camera technologies, ideal for ground to ground troop identification. When grouped into an emitter panel, the viewing distances were extended to 5 miles, ideal for ground to air identification.

Experimental realization of optical lumped nanocircuits at infrared wavelengths.

Science.gov (United States)

Sun, Yong; Edwards, Brian; Alù, Andrea; Engheta, Nader

2012-01-29

The integration of radiofrequency electronic methodologies on micro- as well as nanoscale platforms is crucial for information processing and data-storage technologies. In electronics, radiofrequency signals are controlled and manipulated by 'lumped' circuit elements, such as resistors, inductors and capacitors. In earlier work, we theoretically proposed that optical nanostructures, when properly designed and judiciously arranged, could behave as nanoscale lumped circuit elements--but at optical frequencies. Here, for the first time we experimentally demonstrate a two-dimensional optical nanocircuit at mid-infrared wavelengths. With the guidance of circuit theory, we design and fabricate arrays of Si3N4 nanorods with specific deep subwavelength cross-sections, quantitatively evaluate their equivalent impedance as lumped circuit elements in the mid-infrared regime, and by Fourier transform infrared spectroscopy show that these nanostructures can indeed function as two-dimensional optical lumped circuit elements. We further show that the connections among nanocircuit elements, in particular whether they are in series or in parallel combination, can be controlled by the polarization of impinging optical signals, realizing the notion of 'stereo-circuitry' in metatronics-metamaterials-inspired optical circuitry.

Tunable optical coherence tomography in the infrared range using visible photons

Science.gov (United States)

Paterova, Anna V.; Yang, Hongzhi; An, Chengwu; Kalashnikov, Dmitry A.; Krivitsky, Leonid A.

2018-04-01

Optical coherence tomography (OCT) is an appealing technique for bio-imaging, medicine, and material analysis. For many applications, OCT in mid- and far-infrared (IR) leads to significantly more accurate results. Reported mid-IR OCT systems require light sources and photodetectors which operate in mid-IR range. These devices are expensive and need cryogenic cooling. Here, we report a proof-of-concept demonstration of a wavelength tunable IR OCT technique with detection of only visible range photons. Our method is based on the nonlinear interference of frequency correlated photon pairs. The nonlinear crystal, introduced in the Michelson-type interferometer, generates photon pairs with one photon in the visible and another in the IR range. The intensity of detected visible photons depends on the phase and loss of IR photons, which interact with the sample under study. This enables us to characterize sample properties and perform imaging in the IR range by detecting visible photons. The technique possesses broad wavelength tunability and yields a fair axial and lateral resolution, which can be tailored to the specific application. The work contributes to the development of versatile 3D imaging and material characterization systems working in a broad range of IR wavelengths, which do not require the use of IR-range light sources and photodetectors.

Choice of Eye-Safe Radiation Wavelength in UV and Near IR Spectral Bands for Remote Sensing

OpenAIRE

M. L. Belov; V. A. Gorodnichev; D. A. Kravtsov; A. A. Cherpakova

2016-01-01

The introduction of laser remote sensing systems carries a particular risk to the human’s sense of vision. A structure of the eye, and especially the retina, is the main critical organ as related to the laser radiation.The work uses the optical models of the atmosphere, correctly working in both the UV and the near-IR band, to select the eye-safe radiation wavelengths in the UV (0.355 m) and near-IR (~ 1.54 and ~ 2 m) spectral bands from the point of view of recorded lidar signal value to ful...

Mid-infrared integrated photonics on silicon: a perspective

Directory of Open Access Journals (Sweden)

Lin Hongtao

2017-12-01

Full Text Available The emergence of silicon photonics over the past two decades has established silicon as a preferred substrate platform for photonic integration. While most silicon-based photonic components have so far been realized in the near-infrared (near-IR telecommunication bands, the mid-infrared (mid-IR, 2–20-μm wavelength band presents a significant growth opportunity for integrated photonics. In this review, we offer our perspective on the burgeoning field of mid-IR integrated photonics on silicon. A comprehensive survey on the state-of-the-art of key photonic devices such as waveguides, light sources, modulators, and detectors is presented. Furthermore, on-chip spectroscopic chemical sensing is quantitatively analyzed as an example of mid-IR photonic system integration based on these basic building blocks, and the constituent component choices are discussed and contrasted in the context of system performance and integration technologies.

Correcting the effect of refraction and dispersion of light in FT-IR spectroscopic imaging in transmission through thick infrared windows.

Science.gov (United States)

Chan, K L Andrew; Kazarian, Sergei G

2013-01-15

Transmission mode is one of the most common sampling methods for FT-IR spectroscopic imaging because the spectra obtained generally have a reasonable signal-to-noise ratio. However, dispersion and refraction of infrared light occurs when samples are sandwiched between infrared windows or placed underneath a layer of liquid. Dispersion and refraction cause infrared light to focus with different focal lengths depending on the wavelength (wavenumber) of the light. As a result, images obtained are in focus only at a particular wavenumber while they are defocused at other wavenumber values. In this work, a solution to correct this spread of focus by means of adding a lens on top of the infrared transparent window, such that a pseudo hemisphere is formed, has been investigated. Through this lens (or pseudo hemisphere), refraction of light is removed and the light across the spectral range has the same focal depth. Furthermore, the lens acts as a solid immersion objective and an increase of both magnification and spatial resolution (by 1.4 times) is demonstrated. The spatial resolution was investigated using an USAF resolution target, showing that the Rayleigh criterion can be achieved, as well as a sample with a sharp polymer interface to indicate the spatial resolution that can be expected in real samples. The reported approach was used to obtain chemical images of cross sections of cancer tissue and hair samples sandwiched between infrared windows showing the versatility and applicability of the method. In addition to the improved spatial resolution, the results reported herein also demonstrate that the lens can reduce the effect of scattering near the edges of tissue samples. The advantages of the presented approach, obtaining FT-IR spectroscopic images in transmission mode with the same focus across all wavenumber values and simultaneous improvement in spatial resolution, will have wide implications ranging from studies of live cells to sorption of drugs into tissues.

A Multi-Wavelength Thermal Infrared and Reflectance Scene Simulation Model

Science.gov (United States)

Ballard, J. R., Jr.; Smith, J. A.; Smith, David E. (Technical Monitor)

2002-01-01

Several theoretical calculations are presented and our approach discussed for simulating overall composite scene thermal infrared exitance and canopy bidirectional reflectance of a forest canopy. Calculations are performed for selected wavelength bands of the DOE Multispectral Thermal Imagery and comparisons with atmospherically corrected MTI imagery are underway. NASA EO-1 Hyperion observations also are available and the favorable comparison of our reflective model results with these data are reported elsewhere.

Silicon based mechanic-photonic wavelength converter for infrared photo-detection

Science.gov (United States)

Rudnitsky, Arkady; Agdarov, Sergey; Gulitsky, Konstantin; Zalevsky, Zeev

2017-06-01

In this paper we present a new concept to realize a mechanic-photonic wavelength converter in silicon chip by construction of nanorods and by modulating the input illumination at temporal frequency matched to the mechanic resonance of the nanorods. The use case is to realize an infrared photo detector in silicon which is not based on absorption but rather on the mechanical interaction of the nanorods with the incoming illumination.

IR-to-visible image upconverter under nonlinear crystal thermal gradient operation.

Science.gov (United States)

Maestre, H; Torregrosa, A J; Fernández-Pousa, C R; Capmany, J

2018-01-22

In this work we study the enhancement of the field-of-view of an infrared image up-converter by means of a thermal gradient in a PPLN crystal. Our work focuses on compact upconverters, in which both a short PPLN crystal length and high numerical aperture lenses are employed. We found a qualitative increase in both wavelength and angular tolerances, compared to a constant temperature upconverter, which makes it necessary a correct IR wavelength allocation in order to effectively increase the up-converted area.

Powerful infrared emitting diodes

Directory of Open Access Journals (Sweden)

Kogan L. M.

2012-02-01

Full Text Available Powerful infrared LEDs with emission wavelength 805 ± 10, 870 ± 20 and 940 ± 10 nm developed at SPC OED "OPTEL" are presented in the article. The radiant intensity of beam diode is under 4 W/sr in the continuous mode and under 100 W/sr in the pulse mode. The radiation power of wide-angle LEDs reaches 1 W in continuous mode. The external quantum efficiency of emission IR diodes runs up to 30%. There also has been created infrared diode modules with a block of flat Fresnel lenses with radiant intensity under 70 W/sr.

Extended short wavelength infrared HgCdTe detectors on silicon substrates

Science.gov (United States)

Park, J. H.; Hansel, D.; Mukhortova, A.; Chang, Y.; Kodama, R.; Zhao, J.; Velicu, S.; Aqariden, F.

2016-09-01

We report high-quality n-type extended short wavelength infrared (eSWIR) HgCdTe (cutoff wavelength 2.59 μm at 77 K) layers grown on three-inch diameter CdTe/Si substrates by molecular beam epitaxy (MBE). This material is used to fabricate test diodes and arrays with a planar device architecture using arsenic implantation to achieve p-type doping. We use different variations of a test structure with a guarded design to compensate for the lateral leakage current of traditional test diodes. These test diodes with guarded arrays characterize the electrical performance of the active 640 × 512 format, 15 μm pitch detector array.

Multiple scattering wavelength dependent backscattering of kaolin dust in the IR: Measurements and theory

Science.gov (United States)

Ben-David, Avishai

1992-01-01

Knowing the optical properties of aerosol dust is important for designing electro-optical systems and for modeling the effect on propagation of light in the atmosphere. As CO2 lidar technology becomes more advanced and is used for multiwavelength measurements, information on the wavelength dependent backscattering of aerosol dust particles is required. The volume backscattering coefficient of aerosols in the IR is relatively small. Thus, only a few field measurements of backscattering, usually at only a few wavelengths, are reported in the literature. We present spectral field measurements of backscattering of kaolin dust in the 9-11 micron wavelength range. As the quantity of dust increases, multiple scattering contributes more to the measured backscattered signal. The measurements show the effect of the dust quantity of the spectral backscatter measurements. A simple analytical two stream radiative transfer model is applied to confirm the measurements and to give insight to the multiple scattering spectra of backscattering.

The Investigation of Property of Radiation and Absorbed of Infrared Lights of the Biological Tissues

Science.gov (United States)

Pang, Xiao-Feng; Deng, Bo; Xiao, He-Lan; Cai, Guo-Ping

2010-04-01

The properties of absorption of infrared light for collagen, hemoglobin, bivine serum albumen (BSA) protein molecules with α- helix structure and water in the living systems as well as the infrared transmission spectra for person’s skins and finger hands of human body in the region of 400-4000 cm-1 (i.e., wavelengths of 2-20 μm) have been collected and determined by using a Nicolet Nexus 670 FT-IR Spectrometer, a Perkin Elmer GX FT-IR spectrometer, an OMA (optical multichannel analysis) and an infrared probe systems, respectively. The experimental results obtained show that the protein molecules and water can all absorb the infrared lights in the ranges of 600-1900 cm-1 and 2900-3900 cm-l, but their properties of absorption are somewhat different due to distinctions of their structure and conformation and molecular weight. We know from the transmission spectra of person’s finger hands and skin that the infrared lights with wavelengths of 2 μm-7 μm can not only transmit over the person’s skin and finger hands, but also be absorbed by the above proteins and water in the living systems. Thus, we can conclude from this study that the human beings and animals can absorb the infrared lights with wavelengths of 2 μm-7 μm.

Infrared polarimetry and photometry of BL Lac objects

Energy Technology Data Exchange (ETDEWEB)

Impey, C D; Brand, P W.J.L. [Edinburgh Univ. (UK); Wolstencroft, R D; Williams, P M [Royal Observatory, Edinburgh (UK)

1982-07-01

Infrared polarimetry and photometry have been obtained for a sample of 18 BL Lac objects. The data covers a period of one year and is part of a continuing monitoring programme; all observations were in the J,H and K wavebands. Large and variable degrees of polarization are a common property of the sample. Two BL Lac objects show wavelength-dependent polarization, with the polarization increasing towards shorter wavelengths, and two objects show evidence for position angle rotations over a five-day period. The relationship between changes in polarized and total flux is also discussed. The BL Lac objects cover an enormous range of infrared luminosity; the three most luminous having Lsub(IR) > 10/sup 46/ erg s/sup -1/ and the other end of the range having infrared luminosities similar to normal elliptical galaxies. These are the first published infrared polarimetric observations for eight of the sample.

Invisible Misconceptions: Student Understanding of Ultraviolet and Infrared Radiation

Science.gov (United States)

Libarkin, Julie C.; Asghar, Anila; Crockett, C.; Sadler, Philip

2011-01-01

The importance of nonvisible wavelengths for the study of astronomy suggests that student understanding of nonvisible light is an important consideration in astronomy classrooms. Questionnaires, interviews, and panel discussions were used to investigate 6-12 student and teacher conceptions of ultraviolet (UV) and infrared (IR). Alternative…

Multi-Wavelength Monitoring of GRS 1915+105

Science.gov (United States)

Bandyopadhyay, R.; Martini, P.; Gerard, E.; Charles, P. A.; Wagner, R. M.; Shrader, C.; Shahbaz, T.; Mirabel, I. F.

1997-01-01

Since its discovery in 1992, the superluminal X-ray transient GRS 1915+105 has been extensively observed in an attempt to understand its behaviour. We present here first results from a multi-wavelength campaign undertaken from July to September 1996. This study includes X-ray data from the RXTE All Sky Monitor and BATSE, two-frequency data from the Nancay radio telescope, and infrared photometry from the 1.8 m Perkins telescope at Lowell Observatory. The first long-term well-sampled IR light curve of GRS 1915+105 is presented herein and is consistent with the interpretation of this source as a long-period binary. We compare the various light curves, searching for correlations in the behaviour of the source at differing wavelengths and for possible periodicities.

Experimental characterization of dielectric-loaded plasmonic waveguide-racetrack resonators at near-infrared wavelengths

DEFF Research Database (Denmark)

Garcia, Cesar; Coello, Victor; Han, Zhanghua

2012-01-01

Dielectric-loaded plasmonic waveguide-racetrack resonators (WRTRs) were designed and fabricated for operating at near-infrared wavelengths (750–850 nm) and characterized using leakage-radiation microscopy. The transmission spectra of the WRTRs are found experimentally and compared to the calculat...

Subwavelength engineered fiber-to-chip silicon-on-sapphire interconnects for mid-infrared applications (Conference Presentation)

Science.gov (United States)

Alonso-Ramos, Carlos; Han, Zhaohong; Le Roux, Xavier; Lin, Hongtao; Singh, Vivek; Lin, Pao Tai; Tan, Dawn; Cassan, Eric; Marris-Morini, Delphine; Vivien, Laurent; Wada, Kazumi; Hu, Juejun; Agarwal, Anuradha; Kimerling, Lionel C.

2016-05-01

The mid-Infrared wavelength range (2-20 µm), so-called fingerprint region, contains the very sharp vibrational and rotational resonances of many chemical and biological substances. Thereby, on-chip absorption-spectrometry-based sensors operating in the mid-Infrared (mid-IR) have the potential to perform high-precision, label-free, real-time detection of multiple target molecules within a single sensor, which makes them an ideal technology for the implementation of lab-on-a-chip devices. Benefiting from the great development realized in the telecom field, silicon photonics is poised to deliver ultra-compact efficient and cost-effective devices fabricated at mass scale. In addition, Si is transparent up to 8 µm wavelength, making it an ideal material for the implementation of high-performance mid-IR photonic circuits. The silicon-on-insulator (SOI) technology, typically used in telecom applications, relies on silicon dioxide as bottom insulator. Unfortunately, silicon dioxide absorbs light beyond 3.6 µm, limiting the usability range of the SOI platform for the mid-IR. Silicon-on-sapphire (SOS) has been proposed as an alternative solution that extends the operability region up to 6 µm (sapphire absorption), while providing a high-index contrast. In this context, surface grating couplers have been proved as an efficient means of injecting and extracting light from mid-IR SOS circuits that obviate the need of cleaving sapphire. However, grating couplers typically have a reduced bandwidth, compared with facet coupling solutions such as inverse or sub-wavelength tapers. This feature limits their feasibility for absorption spectroscopy applications that may require monitoring wide wavelength ranges. Interestingly, sub-wavelength engineering can be used to substantially improve grating coupler bandwidth, as demonstrated in devices operating at telecom wavelengths. Here, we report on the development of fiber-to-chip interconnects to ZrF4 optical fibers and integrated SOS

A New Indicator for Optimal Preprocessing and Wavelengths Selection of Near-Infrared Spectra

NARCIS (Netherlands)

Skibsted, E.; Boelens, H.F.M.; Westerhuis, J.A.; Witte, D.T.; Smilde, A.K.

2004-01-01

Preprocessing of near-infrared spectra to remove unwanted, i.e., non-related spectral variation and selection of informative wavelengths is considered to be a crucial step prior to the construction of a quantitative calibration model. The standard methodology when comparing various preprocessing

Application of Fourier transform infrared (FT-IR) spectroscopy in determination of microalgal compositions.

Science.gov (United States)

Meng, Yingying; Yao, Changhong; Xue, Song; Yang, Haibo

2014-01-01

Fourier transform infrared spectroscopy (FT-IR) was applied in algal strain screening and monitoring cell composition dynamics in a marine microalga Isochrysis zhangjiangensis during algal cultivation. The content of lipid, carbohydrate and protein of samples determined by traditional methods had validated the accuracy of FT-IR method. For algal screening, the band absorption ratios of lipid/amide I and carbo/amide I from FT-IR measurements allowed for the selection of Isochrysis sp. and Tetraselmis subcordiformis as the most potential lipid and carbohydrate producers, respectively. The cell composition dynamics of I. zhangjiangensis measured by FT-IR revealed the diversion of carbon allocation from protein to carbohydrate and neutral lipid when nitrogen-replete cells were subjected to nitrogen limitation. The carbo/amide I band absorption ratio had also been demonstrated to depict physiological status under nutrient stress in T. subcordiformis. FT-IR serves as a tool for the simultaneous measurement of lipid, carbohydrate, and protein content in cell. Copyright © 2013 Elsevier Ltd. All rights reserved.

[Research on the temperature field detection method of hot forging based on long-wavelength infrared spectrum].

Science.gov (United States)

Zhang, Yu-Cun; Wei, Bin; Fu, Xian-Bin

2014-02-01

A temperature field detection method based on long-wavelength infrared spectrum for hot forging is proposed in the present paper. This method combines primary spectrum pyrometry and three-stage FP-cavity LCTF. By optimizing the solutions of three group nonlinear equations in the mathematical model of temperature detection, the errors are reduced, thus measuring results will be more objective and accurate. Then the system of three-stage FP-cavity LCTF was designed on the principle of crystal birefringence. The system realized rapid selection of any wavelength in a certain wavelength range. It makes the response of the temperature measuring system rapid and accurate. As a result, without the emissivity of hot forging, the method can acquire exact information of temperature field and effectively suppress the background light radiation around the hot forging and ambient light that impact the temperature detection accuracy. Finally, the results of MATLAB showed that the infrared spectroscopy through the three-stage FP-cavity LCTF could meet the requirements of design. And experiments verified the feasibility of temperature measuring method. Compared with traditional single-band thermal infrared imager, the accuracy of measuring result was improved.

Chemical fingerprinting of Arabidopsis using Fourier transform infrared (FT-IR) spectroscopic approaches.

Science.gov (United States)

Gorzsás, András; Sundberg, Björn

2014-01-01

Fourier transform infrared (FT-IR) spectroscopy is a fast, sensitive, inexpensive, and nondestructive technique for chemical profiling of plant materials. In this chapter we discuss the instrumental setup, the basic principles of analysis, and the possibilities for and limitations of obtaining qualitative and semiquantitative information by FT-IR spectroscopy. We provide detailed protocols for four fully customizable techniques: (1) Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS): a sensitive and high-throughput technique for powders; (2) attenuated total reflectance (ATR) spectroscopy: a technique that requires no sample preparation and can be used for solid samples as well as for cell cultures; (3) microspectroscopy using a single element (SE) detector: a technique used for analyzing sections at low spatial resolution; and (4) microspectroscopy using a focal plane array (FPA) detector: a technique for rapid chemical profiling of plant sections at cellular resolution. Sample preparation, measurement, and data analysis steps are listed for each of the techniques to help the user collect the best quality spectra and prepare them for subsequent multivariate analysis.

Current status of three-dimensional silicon photonic crystals operating at infrared wavelengths

Energy Technology Data Exchange (ETDEWEB)

LIN,SHAWN-YU; FLEMING,JAMES G.; SIGALAS,M.M.; BISWAS,R.; HO,K.M.

2000-05-11

In this paper, the experimental realization and promises of three-dimensional (3D) photonic crystals in the infrared and optical wavelengths will be described. Emphasis will be placed on the development of new 3D photonic crystals, the micro- and nano-fabrication techniques, the construction of high-Q micro-cavities and the creation of 3D waveguides.

Mid-infrared two-photon absorption in an extended-wavelength InGaAs photodetector

Science.gov (United States)

Piccardo, Marco; Rubin, Noah A.; Meadowcroft, Lauren; Chevalier, Paul; Yuan, Henry; Kimchi, Joseph; Capasso, Federico

2018-01-01

We investigate the nonlinear optical response of a commercial extended-wavelength In0.81Ga0.19As uncooled photodetector. Degenerate two-photon absorption in the mid-infrared range is observed using a quantum cascade laser emitting at λ = 4.5 μm as the excitation source. From the measured two-photon photocurrent signal, we extract a two-photon absorption coefficient β(2) = 0.6 ± 0.2 cm/MW, in agreement with the theoretical value obtained from the Eg-3 scaling law. Considering the wide spectral range covered by extended-wavelength InxGa1-xAs alloys, this result holds promise for applications based on two-photon absorption for this family of materials at wavelengths between 1.8 and 5.6 μm.

Kinetic inductance detectors for far-infrared spectroscopy

International Nuclear Information System (INIS)

Barlis, A.; Aguirre, J.; Stevenson, T.

2016-01-01

The star formation mechanisms at work in the early universe remain one of the major unsolved problems of modern astrophysics. Many of the luminous galaxies present during the period of peak star formation (at redshift of about 2.5) were heavily enshrouded in dust, which makes observing their properties difficult at optical wavelengths. However, many spectral lines exist at far-infrared wavelengths that serve as tracers of star formation. Here, we describe a detector system suitable for a balloon-borne spectroscopic intensity mapping experiment at far-infrared wavelengths. The system uses lumped-element kinetic inductance detectors (KIDs), which have the potential to achieve high sensitivity and low noise levels. KIDs consist of separate capacitive and inductive elements, and use the inductive element as the radiation absorber. We describe the design considerations, fabrication process, and readout scheme for a prototype LEKID array of 1600 pixels. - Highlights: • We describe a concept for a balloon-borne telescope for far-IR wavelengths. • Telescope would use high-sensitivity kinetic inductance detectors. • Design considerations and fabrication process for prototype detectors.

Kinetic inductance detectors for far-infrared spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Barlis, A., E-mail: abarlis@physics.upenn.edu [University of Pennsylvania Department of Physics and Astronomy, Philadelphia, Pennsylvania (United States); Aguirre, J. [University of Pennsylvania Department of Physics and Astronomy, Philadelphia, Pennsylvania (United States); Stevenson, T. [NASA Goddard Space Flight Center, Greenbelt, Maryland (United States)

2016-07-11

The star formation mechanisms at work in the early universe remain one of the major unsolved problems of modern astrophysics. Many of the luminous galaxies present during the period of peak star formation (at redshift of about 2.5) were heavily enshrouded in dust, which makes observing their properties difficult at optical wavelengths. However, many spectral lines exist at far-infrared wavelengths that serve as tracers of star formation. Here, we describe a detector system suitable for a balloon-borne spectroscopic intensity mapping experiment at far-infrared wavelengths. The system uses lumped-element kinetic inductance detectors (KIDs), which have the potential to achieve high sensitivity and low noise levels. KIDs consist of separate capacitive and inductive elements, and use the inductive element as the radiation absorber. We describe the design considerations, fabrication process, and readout scheme for a prototype LEKID array of 1600 pixels. - Highlights: • We describe a concept for a balloon-borne telescope for far-IR wavelengths. • Telescope would use high-sensitivity kinetic inductance detectors. • Design considerations and fabrication process for prototype detectors.

The TApIR experiment. IR absorption spectra of liquid hydrogen isotopologues; Das TApIR Experiment IR-Absorptionsspektren fluessiger Wasserstoffisotopologe

Energy Technology Data Exchange (ETDEWEB)

Groessle, Robin

2015-11-27

The scope of the thesis is the infrared absorption spectroscopy of liquid hydrogen isotopologues with the tritium absorption infrared spectroscopy (TApIR) experiment at the tritium laboratory Karlsruhe (TLK). The calibration process from the sample preparation to the reference measurements are described. A further issue is the classical evaluation of FTIR absorption spectra and the extension using the rolling circle filter (RCF) including the effects on statistical and systematical errors. The impact of thermal and nuclear spin temperature on the IR absorption spectra is discussed. An empirical based modeling for the IR absorption spectra of liquid hydrogen isotopologues is performed.

Characterization and modeling of microstructured chalcogenide fibers for efficient mid-infrared wavelength conversion.

Science.gov (United States)

Xing, Sida; Grassani, Davide; Kharitonov, Svyatoslav; Billat, Adrien; Brès, Camille-Sophie

2016-05-02

We experimentally demonstrate wavelength conversion in the 2 µm region by four-wave mixing in an AsSe and a GeAsSe chalcogenide photonic crystal fibers. A maximum conversion efficiency of -25.4 dB is measured for 112 mW of coupled continuous wave pump in a 27 cm long fiber. We estimate the dispersion parameters and the nonlinear refractive indexes of the chalcogenide PCFs, establishing a good agreement with the values expected from simulations. The different fiber geometries and glass compositions are compared in terms of performance, showing that GeAsSe is a more suited candidate for nonlinear optics at 2 µm. Building from the fitted parameters we then propose a new tapered GeAsSe PCF geometry to tailor the waveguide dispersion and lower the zero dispersion wavelength (ZDW) closer to the 2 µm pump wavelength. Numerical simulations shows that the new design allows both an increased conversion efficiency and bandwidth, and the generation of idler waves further in the mid-IR regions, by tuning the pump wavelength in the vicinity of the fiber ZDW.

Adding a dimension to the infrared spectra of interfaces: 2D SFG spectroscopy via mid-IR pulse shaping

Science.gov (United States)

Zanni, Martin

2012-02-01

Sum-frequency generation spectroscopy provides an infrared spectrum of interfaces and thus has widespread use in the materials and chemical sciences. In this presentation, I will present our recent work in developing a 2D pulse sequence to generate 2D SFG spectra of interfaces, in analogy to 2D infrared spectra used to measure bulk species. To develop this spectroscopy, we have utilized many of the tricks-of-the-trade developed in the 2D IR and 2D Vis communities in the last decade, including mid-IR pulse shaping. With mid-IR pulse shaping, the 2D pulse sequence is manipulated by computer programming in the desired frequency resolution, rotating frame, and signal pathway. We believe that 2D SFG will become an important tool in the interfacial sciences in an analogous way that 2D IR is now being used in many disciplines.

Advances in Mid-IR Fiber Lasers: Tellurite, Fluoride and Chalcogenide

Directory of Open Access Journals (Sweden)

Mario Christian Falconi

2017-06-01

Full Text Available A review on the recent progress in modeling and fabrication of medium infrared (Mid-IR fiber lasers is reported. The main objective is to illustrate some recent examples of continuous wave optical sources at wavelengths longer than those commonly employed in telecom applications and allowing high beam quality. A small number of Mid-IR lasers, among the large variety of schemes, glasses, dopants and pumping schemes reported in literature, is selected on the basis of their slope efficiency and threshold pump power. In particular, tellurite, fluoride and chalcogenide fiber lasers are considered. More details are given with reference to the novel pumping schemes.

Towards strong light-matter coupling at the single-resonator level with sub-wavelength mid-infrared nano-antennas

Energy Technology Data Exchange (ETDEWEB)

Malerba, M.; De Angelis, F., E-mail: francesco.deangelis@iit.it [Istituto Italiano di Tecnologia, Via Morego, 30, I-16163 Genova (Italy); Ongarello, T.; Paulillo, B.; Manceau, J.-M.; Beaudoin, G.; Sagnes, I.; Colombelli, R., E-mail: raffaele.colombelli@u-psud.fr [Centre for Nanoscience and Nanotechnology (C2N Orsay), CNRS UMR9001, Univ. Paris Sud, Univ. Paris Saclay, 91405 Orsay (France)

2016-07-11

We report a crucial step towards single-object cavity electrodynamics in the mid-infrared spectral range using resonators that borrow functionalities from antennas. Room-temperature strong light-matter coupling is demonstrated in the mid-infrared between an intersubband transition and an extremely reduced number of sub-wavelength resonators. By exploiting 3D plasmonic nano-antennas featuring an out-of-plane geometry, we observed strong light-matter coupling in a very low number of resonators: only 16, more than 100 times better than what reported to date in this spectral range. The modal volume addressed by each nano-antenna is sub-wavelength-sized and it encompasses only ≈4400 electrons.

Detecting infrared luminescence and non-chemical signaling of living cells: single cell mid-IR spectroscopy in cryogenic environments

Science.gov (United States)

Pereverzev, Sergey

2017-02-01

Many life-relevant interaction energies are in IR range, and it is reasonable to believe that some biochemical reactions inside cells can results in emission of IR photons. Cells can use this emission for non-chemical and non-electrical signaling. Detecting weak infrared radiation from live cells is complicated because of strong thermal radiation background and absorption of radiation by tissues. A microfluidic device with live cells inside a vacuum cryogenic environment should suppress this background, and thereby permit observation of live cell auto-luminescence or signaling in the IR regime. One can make IR-transparent windows not emitting in this range, so only the cell and a small amount of liquid around it will emit infrared radiation. Currently mid-IR spectroscopy of single cells requires the use of a synchrotron source to measure absorption or reflection spectra. Decreasing of thermal radiation background will allow absorption and reflection spectroscopy of cells without using synchrotron light. Moreover, cell auto-luminescence can be directly measured. The complete absence of thermal background radiation for cryogenically cooled samples allows the use IR photon-sensitive detectors and obtaining single molecule sensitivity in IR photo-luminescence measurements. Due to low photon energies, photo-luminescence measurements will be non-distractive for pressures samples. The technique described here is based upon US patent 9366574.

AXION DECAY AND ANISOTROPY OF NEAR-IR EXTRAGALACTIC BACKGROUND LIGHT

Energy Technology Data Exchange (ETDEWEB)

Gong, Yan; Chen, Xuelei [National Astronomical Observatories, Chinese Academy of Sciences, Beijing, 100012 (China); Cooray, Asantha; Mitchell-Wynne, Ketron [Department of Physics and Astronomy, University of California, Irvine, CA 92697 (United States); Zemcov, Michael [Center for Detectors, School of Physics and Astronomy, Rochester Institute of Technology, Rochester, NY 14623 (United States); Smidt, Joseph [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

2016-07-10

The extragalactic background light (EBL) is composed of the cumulative radiation from all galaxies and active galactic nuclei over cosmic history. In addition to point sources, the EBL also contains information from diffuse sources of radiation. The angular power spectra of the near-infrared intensities could contain additional signals, and a complete understanding of the nature of the infrared (IR) background is still lacking in the literature. Here we explore the constraints that can be placed on particle decays, especially candidate dark matter (DM) models involving axions that trace DM halos of galaxies. Axions with a mass around a few electronvolts will decay via two photons with wavelengths in the near-IR band and will leave a signature in the IR background intensity power spectrum. Using recent power spectra measurements from the Hubble Space Telescope and the Cosmic Infrared Background Experiment, we find that the 0.6–1.6 μ m power spectra can be explained by axions with masses around 4 eV. The total axion abundance Ω{sub a} ≃ 0.05, and it is comparable to the baryon density of the universe. The suggested mean axion mass and abundance are not ruled out by existing cosmological observations. Interestingly, the axion model with a mass distribution is preferred by the data, which cannot be explained by the standard quantum chromodynamics theory and needs further discussion.

The infrared luminosity function of AKARI 90 μm galaxies in the local Universe

Science.gov (United States)

Kilerci Eser, Ece; Goto, Tomotsugu

2018-03-01

Local infrared (IR) luminosity functions (LFs) are necessary benchmarks for high-redshift IR galaxy evolution studies. Any accurate IR LF evolution studies require accordingly accurate local IR LFs. We present IR galaxy LFs at redshifts of z ≤ 0.3 from AKARI space telescope, which performed an all-sky survey in six IR bands (9, 18, 65, 90, 140, and 160 μm) with 10 times better sensitivity than its precursor Infrared Astronomical Satellite. Availability of 160 μm filter is critically important in accurately measuring total IR luminosity of galaxies, covering across the peak of the dust emission. By combining data from Wide-field Infrared Survey Explorer (WISE), Sloan Digital Sky Survey (SDSS) Data Release 13 (DR 13), six-degree Field Galaxy Survey and the 2MASS Redshift Survey, we created a sample of 15 638 local IR galaxies with spectroscopic redshifts, factor of 7 larger compared to previously studied AKARI-SDSS sample. After carefully correcting for volume effects in both IR and optical, the obtained IR LFs agree well with previous studies, but comes with much smaller errors. Measured local IR luminosity density is ΩIR = 1.19 ± 0.05 × 108L⊙ Mpc-3. The contributions from luminous IR galaxies and ultraluminous IR galaxies to ΩIR are very small, 9.3 per cent and 0.9 per cent, respectively. There exists no future all-sky survey in far-IR wavelengths in the foreseeable future. The IR LFs obtained in this work will therefore remain an important benchmark for high-redshift studies for decades.

Pigments which reflect infrared radiation from fire

Science.gov (United States)

Berdahl, Paul H.

1998-01-01

Conventional paints transmit or absorb most of the intense infrared (IR) radiation emitted by fire, causing them to contribute to the spread of fire. The present invention comprises a fire retardant paint additive that reflects the thermal IR radiation emitted by fire in the 1 to 20 micrometer (.mu.m) wavelength range. The important spectral ranges for fire control are typically about 1 to about 8 .mu.m or, for cool smoky fires, about 2 .mu.m to about 16 .mu.m. The improved inventive coatings reflect adverse electromagnetic energy and slow the spread of fire. Specific IR reflective pigments include titanium dioxide (rutile) and red iron oxide pigments with diameters of about 1 .mu.m to about 2 .mu.m and thin leafing aluminum flake pigments.

An infrared diagnostic for magnetism in hot stars

Science.gov (United States)

Oksala, M. E.; Grunhut, J. H.; Kraus, M.; Borges Fernandes, M.; Neiner, C.; Condori, C. A. H.; Campagnolo, J. C. N.; Souza, T. B.

2015-06-01

Magnetospheric observational proxies are used for indirect detection of magnetic fields in hot stars in the X-ray, UV, optical, and radio wavelength ranges. To determine the viability of infrared (IR) hydrogen recombination lines as a magnetic diagnostic for these stars, we have obtained low-resolution (R~ 1200), near-IR spectra of the known magnetic B2V stars HR 5907 and HR 7355, taken with the Ohio State Infrared Imager/Spectrometer (OSIRIS) attached to the 4.1 m Southern Astrophysical Research (SOAR) Telescope. Both stars show definite variable emission features in IR hydrogen lines of the Brackett series, with similar properties as those found in optical spectra, including the derived location of the detected magnetospheric plasma. These features also have the added advantage of a lowered contribution of stellar flux at these wavelengths, making circumstellar material more easily detectable. IR diagnostics will be useful for the future study of magnetic hot stars, to detect and analyze lower-density environments, and to detect magnetic candidates in areas obscured from UV and optical observations, increasing the number of known magnetic stars to determine basic formation properties and investigate the origin of their magnetic fields. Based on observations obtained at the Southern Astrophysical Research (SOAR) telescope, which is a joint project of the Ministério da Ciência, Tecnologia, e Inovação (MCTI) da República Federativa do Brasil, the US National Optical Astronomy Observatory (NOAO), the University of North Carolina at Chapel Hill (UNC), and Michigan State University (MSU).

Diffusion of n-butane/iso-butane mixtures in silicalite-1 investigated using infrared (IR) microscopy

NARCIS (Netherlands)

Chmelik, C.; Heinke, L.; van Baten, J.M.; Krishna, R.

2009-01-01

Adsorption and diffusion of n-butane/iso-butane mixtures in individual silicalite-1 crystals has been investigated using infrared (IR) microscopy. The equilibrium sorption isotherm for an equimolar gas phase mixture is calculated using Configurational Bias Monte-Carlo simulations. The comparison

Polarimetry and photometry of active quasars at visual and near-infrared wavelengths

International Nuclear Information System (INIS)

Smith, P.S.

1986-01-01

The optical and near-infrared continua of highly luminous BL Lacertae (BL Lac) objects and optically violent variable (OVV) quasars are studied through simultaneous broad-band photometry and linear polarimetry. Nineteen BL Lacs and OVVs were monitored during a ∼1 1/2-year period, with the major aim of characterizing the wavelength-dependent polarization exhibited by these objects. Optical (UBVRI) observations were conducted at the UCSD/U. Minn. 1.5-m telescope on Mt. Lemmon, Arizona. Simultaneous (within 1 hr.) near-infrared (JHK) measurements were made using the KPNO 2.1-m telescope. Most of the BL Lac objects exhibit large variations in polarization and brightness on time scale of less than a week. The degree of fractional linear polarization (P) is not observed to be related to brightness or optical spectral index. Most BL Lacs did not show a preferred polarization position angle (theta). Wavelength-dependent P and theta are observed in almost all BL Lacs, but not always simultaneously. The OVV quasar 1156 + 295 shows behavior very similar to the BL Lac objects. 3C 345 Exhibited polarization properties that are quite different from those of the BL Lacs. This object showed a clear correlation between brightness and P

Short-Wavelength Infrared (SWIR) spectroscopy of low-grade metamorphic volcanic rocks of the Pilbara Craton

NARCIS (Netherlands)

Abweny, Mohammad S.; van Ruitenbeek, Frank J A; de Smeth, Boudewijn; Woldai, Tsehaie; van der Meer, Freek D.; Cudahy, Thomas; Zegers, Tanja; Blom, Jan Kees; Thuss, Barbara

This paper shows the results of Short-Wavelength Infrared (SWIR) spectroscopy investigations of volcanic rocks sampled from low-grade metamorphic greenstone belts of the Archean Pilbara Craton in Western Australia. From the reflectance spectra a range of spectrally active minerals were identified,

Far-IR transparency and dynamic infrared signature control with novel conducting polymer systems

Science.gov (United States)

Chandrasekhar, Prasanna; Dooley, T. J.

1995-09-01

Materials which possess transparency, coupled with active controllability of this transparency in the infrared (IR), are today an increasingly important requirement, for varied applications. These applications include windows for IR sensors, IR-region flat panel displays used in camouflage as well as in communication and sight through night-vision goggles, coatings with dynamically controllable IR-emissivity, and thermal conservation coatings. Among stringent requirements for these applications are large dynamic ranges (color contrast), 'multi-color' or broad-band characteristics, extended cyclability, long memory retention, matrix addressability, small area fabricability, low power consumption, and environmental stability. Among materials possessing the requirements for variation of IR signature, conducting polymers (CPs) appear to be the only materials with dynamic, actively controllable signature and acceptable dynamic range. Conventional CPs such as poly(alkyl thiophene), poly(pyrrole) or poly(aniline) show very limited dynamic range, especially in the far-IR, while also showing poor transparency. We have developed a number of novel CP systems ('system' implying the CP, the selected dopant, the synthesis method, and the electrolyte) with very wide dynamic range (up to 90% in both important IR regions, 3 - 5 (mu) and 8 - 12 (mu) ), high cyclability (to 105 cycles with less than 10% optical degradation), nearly indefinite optical memory retention, matrix addressability of multi-pixel displays, very wide operating temperature and excellent environmental stability, low charge capacity, and processability into areas from less than 1 mm2 to more than 100 cm2. The criteria used to design and arrive at these CP systems, together with representative IR signature data, are presented in this paper.

Single photon infrared emission spectroscopy: a study of IR emission from UV laser excited PAHs between 3 and 15 micrometers

Science.gov (United States)

Cook, D. J.; Schlemmer, S.; Balucani, N.; Wagner, D. R.; Harrison, J. A.; Steiner, B.; Saykally, R. J.

1998-01-01

Single-photon infrared emission spectroscopy (SPIRES) has been used to measure emission spectra from polycyclic aromatic hydrocarbons (PAHs). A supersonic free-jet expansion has been used to provide emission spectra of rotationally cold and vibrationally excited naphthalene and benzene. Under these conditions, the observed width of the 3.3-micrometers (C-H stretch) band resembles the bandwidths observed in experiments in which emission is observed from naphthalene with higher rotational energy. To obtain complete coverage of IR wavelengths relevant to the unidentified infrared bands (UIRs), UV laser-induced desorption was used to generate gas-phase highly excited PAHs. Lorentzian band shapes were convoluted with the monochromator-slit function in order to determine the widths of PAH emission bands under astrophysically relevant conditions. Bandwidths were also extracted from bands consisting of multiple normal modes blended together. These parameters are grouped according to the functional groups mostly involved in the vibration, and mean bandwidths are obtained. These bandwidths are larger than the widths of the corresponding UIR bands. However, when the comparison is limited to the largest PAHs studied, the bandwidths are slightly smaller than the corresponding UIR bands. These parameters can be used to model emission spectra from PAH cations and cations of larger PAHs, which are better candidate carriers of the UIRs.

Towards a petawatt-class few-cycle infrared laser system via dual-chirped optical parametric amplification.

Science.gov (United States)

Fu, Yuxi; Midorikawa, Katsumi; Takahashi, Eiji J

2018-05-16

Expansion of the wavelength range for an ultrafast laser is an important ingredient for extending its range of applications. Conventionally, optical parametric amplification (OPA) has been employed to expand the laser wavelength to the infrared (IR) region. However, the achievable pulse energy and peak power have been limited to the mJ and the GW level, respectively. A major difficulty in the further energy scaling of OPA results from a lack of suitable large nonlinear crystals. Here, we circumvent this difficulty by employing a dual-chirped optical parametric amplification (DC-OPA) scheme. We successfully generate a multi-TW IR femtosecond laser pulse with an energy of 100 mJ order, which is higher than that reported in previous works. We also obtain excellent energy scaling ability, ultrashort pulses, flexiable wavelength tunability, and high-energy stability, which prove that DC-OPA is a superior method for the energy scaling of IR pulses to the 10 J/PW level.

Fluorenyl benzothiadiazole and benzoselenadiazole near-IR fluorescent probes for two-photon fluorescence imaging (Conference Presentation)

Science.gov (United States)

Belfield, Kevin D.; Yao, Sheng; Kim, Bosung; Yue, Xiling

2016-03-01

Imaging biological samples with two-photon fluorescence (2PF) microscopy has the unique advantage of resulting high contrast 3D resolution subcellular image that can reach up to several millimeters depth. 2PF probes that absorb and emit at near IR region need to be developed. Two-photon excitation (2PE) wavelengths are less concerned as 2PE uses wavelengths doubles the absorption wavelength of the probe, which means 2PE wavelengths for probes even with absorption at visible wavelength will fall into NIR region. Therefore, probes that fluoresce at near IR region with high quantum yields are needed. A series of dyes based on 5-thienyl-2, 1, 3-benzothiadiazole and 5-thienyl-2, 1, 3-benzoselenadiazole core were synthesized as near infrared two-photon fluorophores. Fluorescence maxima wavelengths as long as 714 nm and fluorescence quantum yields as high as 0.67 were achieved. The fluorescence quantum yields of the dyes were nearly constant, regardless of solvents polarity. These diazoles exhibited large Stokes shift (GM), and high two-photon fluorescence figure of merit (FM , 1.04×10-2 GM). Cells incubated on a 3D scaffold with one of the new probes (encapsulated in Pluronic micelles) exhibited bright fluorescence, enabling 3D two-photon fluorescence imaging to a depth of 100 µm.

Multi-wavelength Observations of the Enduring Type IIn Supernovae 2005ip and 2006jd

DEFF Research Database (Denmark)

Stritzinger, Maximilian; Taddia, Francesco; Fransson, Claes

2012-01-01

We present an observational study of the Type IIn supernovae (SNe IIn) 2005ip and 2006jd. Broadband UV, optical, and near-IR photometry, and visual-wavelength spectroscopy of SN 2005ip complement and extend upon published observations to 6.5 years past discovery. Our observations of SN 2006jd...... extend from UV to mid-infrared wavelengths, and like SN 2005ip, are compared to reported X-ray measurements to understand the nature of the progenitor. Both objects display a number of similarities with the 1988Z-like subclass of SN IIn including (1) remarkably similar early- and late-phase optical...... spectra, (2) a variety of high-ionization coronal lines, (3) long-duration optical and near-IR emission, and (4) evidence of cold and warm dust components. However, diversity is apparent, including an unprecedented late-time r-band excess in SN 2006jd. The observed differences are attributed...

Hydrogenation of Very Long Wavelength Infrared Focal Plane Arrays Based on Type II Superlattices, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — We propose to advance the Ga-free InAs/InAsSb type II superlattice (T2SL) materials technology for very long wavelength infrared (VLWIR) focal plane arrays (FPAs) by...

Ultrafast stimulated Raman spectroscopy in the near-infrared region

International Nuclear Information System (INIS)

Takaya, Tomohisa

2016-01-01

A number of electronic transitions in the near-infrared wavelength region are associated with migration or delocalization of electrons in large molecules or molecular systems. Time-resolved near-infrared Raman spectroscopy will be a powerful tool for investigating the structural dynamic of samples with delocalized electrons. However, the sensitivity of near-infrared spontaneous Raman spectrometers is significantly low due to an extremely small probability of Raman scattering and a low sensitivity of near-infrared detectors. Nonlinear Raman spectroscopy is one of the techniques that can overcome the sensitivity problems and enable us to obtain time-resolved Raman spectra in resonance with near-IR transitions. In this article, the author introduces recent progress of ultrafast time-resolved near-infrared stimulated Raman spectroscopy. Optical setup, spectral and temporal resolution, and applications of the spectrometer are described. (author)

Infrared-faint radio sources in the SERVS deep fields. Pinpointing AGNs at high redshift

Science.gov (United States)

Maini, A.; Prandoni, I.; Norris, R. P.; Spitler, L. R.; Mignano, A.; Lacy, M.; Morganti, R.

2016-12-01

Context. Infrared-faint radio sources (IFRS) represent an unexpected class of objects which are relatively bright at radio wavelength, but unusually faint at infrared (IR) and optical wavelengths. A recent and extensive campaign on the radio-brightest IFRSs (S1.4 GHz≳ 10 mJy) has provided evidence that most of them (if not all) contain an active galactic nuclei (AGN). Still uncertain is the nature of the radio-faintest IFRSs (S1.4 GHz≲ 1 mJy). Aims: The scope of this paper is to assess the nature of the radio-faintest IFRSs, testing their classification and improving the knowledge of their IR properties by making use of the most sensitive IR survey available so far: the Spitzer Extragalactic Representative Volume Survey (SERVS). We also explore how the criteria of IFRSs can be fine-tuned to pinpoint radio-loud AGNs at very high redshift (z > 4). Methods: We analysed a number of IFRS samples identified in SERVS fields, including a new sample (21 sources) extracted from the Lockman Hole. 3.6 and 4.5 μm IR counterparts of the 64 sources located in the SERVS fields were searched for and, when detected, their IR properties were studied. Results: We compared the radio/IR properties of the IR-detected IFRSs with those expected for a number of known classes of objects. We found that IR-detected IFRSs are mostly consistent with a mixture of high-redshift (z ≳ 3) radio-loud AGNs. The faintest ones (S1.4 GHz 100 μJy), however, could be also associated with nearer (z 2) dust-enshrouded star-burst galaxies. We also argue that, while IFRSs with radio-to-IR ratios >500 can very efficiently pinpoint radio-loud AGNs at redshift 2 < z < 4, lower radio-to-IR ratios ( 100-200) are expected for higher redshift radio-loud AGNs.

IR spectral analysis for the diagnostics of crust earthquake precursors

Directory of Open Access Journals (Sweden)

R. M. Umarkhodgaev

2012-11-01

Full Text Available Some possible physical processes are analysed that cause, under the condition of additional ionisation in a pre-breakdown electric field, emissions in the infrared (IR interval. The atmospheric transparency region of the IR spectrum at wavelengths of 7–15 μm is taken into account. This transparency region corresponds to spectral lines of small atmospheric constituents like CH₄, CO₂, N₂O, NO₂, NO, and O₃. The possible intensities of the IR emissions observable in laboratories and in nature are estimated. The acceleration process of the electrons in the pre-breakdown electrical field before its adhesion to the molecules is analyzed. For daytime conditions, modifications of the adsorption spectra of the scattered solar emissions are studied; for nighttime, variations of emission spectra may be used for the analysis.

An X-ray and infrared survey of the Lynds 1228 cloud core

Energy Technology Data Exchange (ETDEWEB)

Skinner, Stephen L. [CASA, University of Colorado, Boulder, CO 80309-0389 (United States); Rebull, Luisa [Spitzer Science Center/Caltech, M/S 220-6, 1200 East California Blvd., Pasadena, CA 91125 (United States); Güdel, Manuel, E-mail: stephen.skinner@colorado.edu, E-mail: rebull@ipac.caltech.edu, E-mail: manuel.guedel@univie.ac.at [Department of Astrophysics, University of Vienna, Türkenschanzstr. 17, A-1180 Vienna (Austria)

2014-04-01

The nearby Lynds 1228 (L1228) dark cloud at a distance of ∼200 pc is known to harbor several young stars including the driving sources of the giant HH 199 and HH 200 Herbig-Haro (HH) outflows. L1228 has previously been studied at optical, infrared, and radio wavelengths but not in X-rays. We present results of a sensitive 37 ks Chandra ACIS-I X-ray observation of the L1228 core region. Chandra detected 60 X-ray sources, most of which are faint (<40 counts) and non-variable. Infrared counterparts were identified for 53 of the 60 X-ray sources using archival data from the Two Micron All-Sky Survey, the Spitzer Space Telescope, and the Wide-field Infrared Survey Explorer. Object classes were assigned using mid-IR colors for those objects with complete photometry, most of which were found to have colors consistent with extragalactic background sources. Seven young stellar object candidates were identified including the class I protostar HH 200-IRS which was detected as a faint hard X-ray source. No X-ray emission was detected from the luminous protostar HH 199-IRS. We summarize the X-ray and infrared properties of the detected sources and provide IR spectral energy distribution modeling of high-interest objects including the protostars driving the HH outflows.

Assessment of Azithromycin in Pharmaceutical Formulation by Fourier-transform Infrared (FT-IR Transmission Spectroscopy

Directory of Open Access Journals (Sweden)

Muhammad Ali Mallah

2011-12-01

Full Text Available A simple, rapid and economical method for azithromycin quantification in solid tablet and capsule formulations has been developed by applying Fourier-transform Infrared (FT-IR transmission spectroscopy for regular quality monitoring. The newly developed method avoids the sample preparation, except grinding for pellet formation and does not involve consumption of any solvent as it absolutely eliminates the need of extraction. KBr pellets were employed for the appraisal of azithromycin while acquiring spectra of standards as well as samples on FT-IR. By selecting the FT-IR carbonyl band (C=O in the region 1,744–1,709 cm−1 the calibration model was developed based on simple Beer’s law. The excellent regression coefficient (R2 0.999 was accomplished for calibration set having standard error of calibration equal to 0.01 mg. The current work exposes that transmission FT-IR spectroscopy can definitely be applied to determine the exact amount of azithromycin to control the processing and quality of solid formulations with reduced cost and short analysis time.

The TApIR experiment. IR absorption spectra of liquid hydrogen isotopologues

International Nuclear Information System (INIS)

Groessle, Robin

2015-01-01

The scope of the thesis is the infrared absorption spectroscopy of liquid hydrogen isotopologues with the tritium absorption infrared spectroscopy (TApIR) experiment at the tritium laboratory Karlsruhe (TLK). The calibration process from the sample preparation to the reference measurements are described. A further issue is the classical evaluation of FTIR absorption spectra and the extension using the rolling circle filter (RCF) including the effects on statistical and systematical errors. The impact of thermal and nuclear spin temperature on the IR absorption spectra is discussed. An empirical based modeling for the IR absorption spectra of liquid hydrogen isotopologues is performed.

Radiometric characterization of type-II InAs/GaSb superlattice (t2sl) midwave infrared photodetectors and focal plane arrays

Science.gov (United States)

Nghiem, Jean; Giard, E.; Delmas, M.; Rodriguez, J. B.; Christol, P.; Caes, M.; Martijn, H.; Costard, E.; Ribet-Mohamed, I.

2017-09-01

In recent years, Type-II InAs/GaSb superlattice (T2SL) has emerged as a new material technology suitable for high performance infrared (IR) detectors operating from Near InfraRed (NIR, 2-3μm) to Very Long Wavelength InfraRed (LWIR, λ > 15μm) wavelength domains. To compare their performances with well-established IR technologies such as MCT, InSb or QWIP cooled detectors, specific electrical and radiometric characterizations are needed: dark current, spectral response, quantum efficiency, temporal and spatial noises, stability… In this paper, we first present quantum efficiency measurements performed on T2SL MWIR (3-5μm) photodiodes and on one focal plane array (320x256 pixels with 30μm pitch, realized in the scope of a french collaboration ). Different T2SL structures (InAs-rich versus GaSb-rich) with the same cutoff wavelength (λc= 5μm at 80K) were studied. Results are analysed in term of carrier diffusion length in order to define the optimum thickness and type of doping of the absorbing zone. We then focus on the stability over time of a commercial T2SL FPA (320x256 pixels with 30μm pitch), measuring the commonly used residual fixed pattern noise (RFPN) figure of merit. Results are excellent, with a very stable behaviour over more than 3 weeks, and less than 10 flickering pixels, possibly giving access to long-term stability of IR absolute calibration.

Instrument for the detection of meteors in the infrared

Science.gov (United States)

Svedhem, H.; Koschny, D.; Ter Haar, J.

2014-07-01

The flux of interplanetary particles in the size range 2 mm to 20 m is poorly constrained due to insufficient data --- the larger bodies may be observed remotely by ground-based or space-based telescopes and the smaller particles are measured by in-situ impact detectors in space or by meteor cameras from ground. An infrared video rate imager in Earth orbit would enable a systematic characterization for an extended period, day and night, of the flux in this range by monitoring the bright meteor/fireball generated during atmospheric entry. Due to the low flux of meteoroids in this range a very large detector is required. With this method a large portion of the Earth atmosphere is in fact used as a huge detector. Such an instrument has never flown in Earth orbit. The only sensors of a similar kind fly on US defense satellites for monitoring launches of ballistic missiles. The data from these sensors, however, is largely inaccessible to scientists. The knowledge on emission of light by meteors/bolides at infrared wavelengths is very limited while it can be suspected that the continuum emission from meteors/bolides have stronger emission at infrared wavelengths than in the visible due to the likely low temperatures of these events. At the same time line emission is dominating over the continuum in the visible so it is not clear how this will compare with the continuum in the infrared. We have developed a bread-board version of an IR video rate camera, the SPOSH-IR. The instrument is based on an earlier technology development, SPOSH --- Smart Panoramic Optical Sensor Head, for operation in the visible range, but with the sensor replaced by a cooled IR detector and new infrared optics. The earlier work has proven the concept of the instrument and of automatic detection of meteors/bolides in the visible wavelength range. The new hardware has been built by Jena-Optronik, Jena, Germany and has been tested during several meteor showers in the Netherlands and at ESA's OGS

Identification and characterization of salmonella serotypes using DNA spectral characteristics by fourier transform infrared (FT-IR) spectroscopy

Science.gov (United States)

Analysis of DNA samples of Salmonella serotypes (Salmonella Typhimurium, Salmonella Enteritidis, Salmonella Infantis, Salmonella Heidelberg and Salmonella Kentucky) were performed using Fourier transform infrared spectroscopy (FT-IR) spectrometer by placing directly in contact with a diamond attenua...

Ultra-Broadband Infrared Pulses from a Potassium-Titanyl Phosphate Optical Parametric Amplifier for VIS-IR-SFG Spectroscopy

Science.gov (United States)

Isaienko, Oleksandr; Borguet, Eric

A non-collinear KTP-OPA to provide ultra-broadband mid-infrared pulses was designed and characterized. With proper pulse-front and phase correction, the system has a potential for high-time resolution vibrational VIS-IR-SFG spectroscopy.

Detection and classification of salmonella serotypes using spectral signatures collected by fourier transform infrared (FT-IR) spectroscopy

Science.gov (United States)

Spectral signatures of Salmonella serotypes namely Salmonella Typhimurium, Salmonella Enteritidis, Salmonella Infantis, Salmonella Heidelberg and Salmonella Kentucky were collected using Fourier transform infrared spectroscopy (FT-IR). About 5-10 µL of Salmonella suspensions with concentrations of 1...

Estimating the Infrared Radiation Wavelength Emitted by a Remote Control Device Using a Digital Camera

Science.gov (United States)

Catelli, Francisco; Giovannini, Odilon; Bolzan, Vicente Dall Agnol

2011-01-01

The interference fringes produced by a diffraction grating illuminated with radiation from a TV remote control and a red laser beam are, simultaneously, captured by a digital camera. Based on an image with two interference patterns, an estimate of the infrared radiation wavelength emitted by a TV remote control is made. (Contains 4 figures.)

Focal plane optics in far-infrared and submillimeter astronomy

Science.gov (United States)

Hildebrand, R. H.

1985-01-01

The construction of airborne observatories, high mountain-top observatories, and space observatories designed especially for infrared and submillimeter astronomy has opened fields of research requiring new optical techniques. A typical far-IR photometric study involves measurement of a continuum spectrum in several passbands between approx 30 microns and 1000 microns and diffraction-limited mapping of the source. At these wavelengths, diffraction effects strongly influence the design of the field optics systems which couple the incoming flux to the radiation sensors (cold bolometers). The Airy diffraction disk for a typical telescope at submillimeter wavelengths approx 100 microns-1000 microns is many millimeters in diameter; the size of the field stop must be comparable. The dilute radiation at the stop is fed through a Winston nonimaging concentrator to a small cavity containing the bolometer. The purpose of this paper is to review the principles and techniques of infrared field optics systems, including spectral filters, concentrators, cavities, and bolometers (as optical elements), with emphasis on photometric systems for wavelengths longer than 60 microns.

Focal plane optics in far-infrared and submillimeter astronomy

Science.gov (United States)

Hildebrand, R. H.

1986-02-01

The construction of airborne observatories, high mountain-top observatories, and space observatories designed especially for infrared and submillimeter astronomy has opened fields of research requiring new optical techniques. A typical far-IR photometric study involves measurement of a continuum spectrum in several passbands between approx 30 microns and 1000 microns and diffraction-limited mapping of the source. At these wavelengths, diffraction effects strongly influence the design of the field optics systems which couple the incoming flux to the radiation sensors (cold bolometers). The Airy diffraction disk for a typical telescope at submillimeter wavelengths approx 100 microns-1000 microns is many millimeters in diameter; the size of the field stop must be comparable. The dilute radiation at the stop is fed through a Winston nonimaging concentrator to a small cavity containing the bolometer. The purpose of this paper is to review the principles and techniques of infrared field optics systems, including spectral filters, concentrators, cavities, and bolometers (as optical elements), with emphasis on photometric systems for wavelengths longer than 60 microns.

Temperature-sensitive junction transformations for mid-wavelength HgCdTe photovoltaic infrared detector arrays by laser beam induced current microscope

Energy Technology Data Exchange (ETDEWEB)

Qiu, Weicheng [College of Photoelectric Science and Engineering, National University of Defense Technology, Changsha, Hunan 410073 (China); National Laboratory for Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai 200083 (China); Hu, Weida, E-mail: wdhu@mail.sitp.ac.cn; Lin, Tie; Yin, Fei; Zhang, Bo; Chen, Xiaoshuang; Lu, Wei [National Laboratory for Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai 200083 (China); Cheng, Xiang' ai, E-mail: xiang-ai-cheng@126.com; Wang, Rui [College of Photoelectric Science and Engineering, National University of Defense Technology, Changsha, Hunan 410073 (China)

2014-11-10

In this paper, we report on the disappearance of the photosensitive area extension effect and the unusual temperature dependence of junction transformation for mid-wavelength, n-on-p HgCdTe photovoltaic infrared detector arrays. The n-type region is formed by B{sup +} ion implantation on Hg-vacancy-doped p-type HgCdTe. Junction transformations under different temperatures are visually captured by a laser beam induced current microscope. A physical model of temperature dependence on junction transformation is proposed and demonstrated by using numerical simulations. It is shown that Hg-interstitial diffusion and temperature activated defects jointly lead to the p-n junction transformation dependence on temperature, and the weaker mixed conduction compared with long-wavelength HgCdTe photodiode contributes to the disappearance of the photosensitive area extension effect in mid-wavelength HgCdTe infrared detector arrays.

Characterization of a novel miniaturized burst-mode infrared laser system for IR-MALDESI mass spectrometry imaging.

Science.gov (United States)

Ekelöf, Måns; Manni, Jeffrey; Nazari, Milad; Bokhart, Mark; Muddiman, David C

2018-03-01

Laser systems are widely used in mass spectrometry as sample probes and ionization sources. Mid-infrared lasers are particularly suitable for analysis of high water content samples such as animal and plant tissues, using water as a resonantly excited sacrificial matrix. Commercially available mid-IR lasers have historically been bulky and expensive due to cooling requirements. This work presents a novel air-cooled miniature mid-IR laser with adjustable burst-mode output and details an evaluation of its performance for mass spectrometry imaging. The miniature laser was found capable of generating sufficient energy for complete ablation of animal tissue in the context of an IR-MALDESI experiment with exogenously added ice matrix, yielding several hundred confident metabolite identifications. Graphical abstract The use of a novel miniature 2.94 μm burst-mode laser in IR-MALDESI allows for rapid and sensitive mass spectrometry imaging of a whole mouse.

Fabrication of Large Area Fishnet Optical Metamaterial Structures Operational at Near-IR Wavelengths

Directory of Open Access Journals (Sweden)

Dennis W. Prather

2010-12-01

Full Text Available In this paper, we demonstrate a fabrication process for large area (2 mm × 2 mm fishnet metamaterial structures for near IR wavelengths. This process involves: (a defining a sacrificial Si template structure onto a quartz wafer using deep-UV lithography and a dry etching process (b deposition of a stack of Au-SiO2-Au layers and (c a ‘lift-off’ process which removes the sacrificial template structure to yield the fishnet structure. The fabrication steps in this process are compatible with today’s CMOS technology making it eminently well suited for batch fabrication. Also, depending on area of the exposure mask available for patterning the template structure, this fabrication process can potentially lead to optical metamaterials spanning across wafer-size areas.

Phase-matched generation of coherent soft and hard X-rays using IR lasers

Science.gov (United States)

Popmintchev, Tenio V.; Chen, Ming-Chang; Bahabad, Alon; Murnane, Margaret M.; Kapteyn, Henry C.

2013-06-11

Phase-matched high-order harmonic generation of soft and hard X-rays is accomplished using infrared driving lasers in a high-pressure non-linear medium. The pressure of the non-linear medium is increased to multi-atmospheres and a mid-IR (or higher) laser device provides the driving pulse. Based on this scaling, also a general method for global optimization of the flux of phase-matched high-order harmonic generation at a desired wavelength is designed.

Near-IR imaging of cracks in teeth

Science.gov (United States)

Fried, William A.; Simon, Jacob C.; Lucas, Seth; Chan, Kenneth H.; Darling, Cynthia L.; Staninec, Michal; Fried, Daniel

2014-02-01

Dental enamel is highly transparent at near-IR wavelengths and several studies have shown that these wavelengths are well suited for optical transillumination for the detection and imaging of tooth decay. We hypothesize that these wavelengths are also well suited for imaging cracks in teeth. Extracted teeth with suspected cracks were imaged at several wavelengths in the near-IR from 1300-1700-nm. Extracted teeth were also examined with optical coherence tomography to confirm the existence of suspected cracks. Several teeth of volunteers were also imaged in vivo at 1300-nm to demonstrate clinical potential. In addition we induced cracks in teeth using a carbon dioxide laser and imaged crack formation and propagation in real time using near-IR transillumination. Cracks were clearly visible using near-IR imaging at 1300-nm in both in vitro and in vivo images. Cracks and fractures also interfered with light propagation in the tooth aiding in crack identification and assessment of depth and severity.

Ultrafast Silicon Photonics with Visible to Mid-Infrared Pumping of Silicon Nanocrystals.

Science.gov (United States)

Diroll, Benjamin T; Schramke, Katelyn S; Guo, Peijun; Kortshagen, Uwe R; Schaller, Richard D

2017-10-11

Dynamic optical control of infrared (IR) transparency and refractive index is achieved using boron-doped silicon nanocrystals excited with mid-IR optical pulses. Unlike previous silicon-based optical switches, large changes in transmittance are achieved without a fabricated structure by exploiting strong light coupling of the localized surface plasmon resonance (LSPR) produced from free holes of p-type silicon nanocrystals. The choice of optical excitation wavelength allows for selectivity between hole heating and carrier generation through intraband or interband photoexcitation, respectively. Mid-IR optical pumping heats the free holes of p-Si nanocrystals to effective temperatures greater than 3500 K. Increases of the hole effective mass at high effective hole temperatures lead to a subpicosecond change of the dielectric function, resulting in a redshift of the LSPR, modulating mid-IR transmission by as much as 27%, and increasing the index of refraction by more than 0.1 in the mid-IR. Low hole heat capacity dictates subpicosecond hole cooling, substantially faster than carrier recombination, and negligible heating of the Si lattice, permitting mid-IR optical switching at terahertz repetition frequencies. Further, the energetic distribution of holes at high effective temperatures partially reverses the Burstein-Moss effect, permitting the modulation of transmittance at telecommunications wavelengths. The results presented here show that doped silicon, particularly in micro- or nanostructures, is a promising dynamic metamaterial for ultrafast IR photonics.

Infrared (IR) vs x-ray power generation in the SLAC Linac Coherent Light Source (LCLS)

International Nuclear Information System (INIS)

Tatchyn, R.

1993-05-01

The LCLS, a Free-Electron Laser (FEL) designed for operation at a first harmonic energy of 300 eV (λ congruent 40 Angstrom) in the Self-Amplified Spontaneous Emission (SASE) regime, will utilize electron bunches compressed down to durations of <0.5ps, or lengths of <150 μ. It is natural to inquire whether coherent radiation of this (and longer) wavelength will constitute a significant component of the total coherent output of the FEL. In this paper a determination of a simple upper bound on the IR that can be generated by the compressed bunches is outlines. Under the assumed operating parameters of the LCLS undulator, it is shown that that IR component of the coherent output should be strongly dominated by the x-ray component

Influence of Desorption Conditions on Analyte Sensitivity and Internal Energy in Discrete Tissue or Whole Body Imaging by IR-MALDESI

Science.gov (United States)

Rosen, Elias P.; Bokhart, Mark T.; Ghashghaei, H. Troy; Muddiman, David C.

2015-06-01

Analyte signal in a laser desorption/postionization scheme such as infrared matrix-assisted laser desorption electrospray ionization (IR-MALDESI) is strongly coupled to the degree of overlap between the desorbed plume of neutral material from a sample and an orthogonal electrospray. In this work, we systematically examine the effect of desorption conditions on IR-MALDESI response to pharmaceutical drugs and endogenous lipids in biological tissue using a design of experiments approach. Optimized desorption conditions have then been used to conduct an untargeted lipidomic analysis of whole body sagittal sections of neonate mouse. IR-MALDESI response to a wide range of lipid classes has been demonstrated, with enhanced lipid coverage received by varying the laser wavelength used for mass spectrometry imaging (MSI). Targeted MS2 imaging (MS2I) of an analyte, cocaine, deposited beneath whole body sections allowed determination of tissue-specific ion response factors, and CID fragments of cocaine were monitored to comment on wavelength-dependent internal energy deposition based on the "survival yield" method.

BOOTES-IR: near IR follow-up GRB observations by a robotic system

International Nuclear Information System (INIS)

Castro-Tirado, A.J.; Postrigo, A. de Ugarte; Jelinek, M.

2005-01-01

BOOTES-IR is the extension of the BOOTES experiment, which operates in Southern Spain since 1998, to the near IR (NIR). The goal is to follow up the early stage of the gamma ray burst (GRB) afterglow emission in the NIR, alike BOOTES does already at optical wavelengths. The scientific case that drives the BOOTES-IR performance is the study of GRBs with the support of spacecraft like INTEGRAL, SWIFT and GLAST. Given that the afterglow emission in both, the NIR and the optical, in the instances immediately following a GRB, is extremely bright (reached V = 8.9 in one case), it should be possible to detect this prompt emission at NIR wavelengths too. The combined observations by BOOTES-IR and BOOTES-1 and BOOTES-2 will allow for real time identification of trustworthy candidates to have a high redshift (z > 5). It is expected that, few minutes after a GRB, the IR magnitudes be H ∼ 7-10, hence very high quality spectra can be obtained for objects as far as z = 10 by larger instruments

Structurally Integrated Coatings for Wear and Corrosion (SICWC): Arc Lamp, InfraRed (IR) Thermal Processing

Energy Technology Data Exchange (ETDEWEB)

Mackiewicz-Ludtka, G.; Sebright, J. [Caterpillar Corp.

2007-12-15

The primary goal of this Cooperative Research and Development Agreement (CRADA) betwe1311 UT-Battelle (Contractor) and Caterpillar Inc. (Participant) was to develop the plasma arc lamp (PAL), infrared (IR) thermal processing technology 1.) to enhance surface coating performance by improving the interfacial bond strength between selected coatings and substrates; and 2.) to extend this technology base for transitioning of the arc lamp processing to the industrial Participant. Completion of the following three key technical tasks (described below) was necessary in order to accomplish this goal. First, thermophysical property data sets were successfully determined for composite coatings applied to 1010 steel substrates, with a more limited data set successfully measured for free-standing coatings. These data are necessary for the computer modeling simulations and parametric studies to; A.) simulate PAL IR processing, facilitating the development of the initial processing parameters; and B.) help develop a better understanding of the basic PAL IR fusing process fundamentals, including predicting the influence of melt pool stirring and heat tnmsfar characteristics introduced during plasma arc lamp infrared (IR) processing; Second, a methodology and a set of procedures were successfully developed and the plasma arc lamp (PAL) power profiles were successfully mapped as a function of PAL power level for the ORNL PAL. The latter data also are necessary input for the computer model to accurately simulate PAL processing during process modeling simulations, and to facilitate a better understand of the fusing process fundamentals. Third, several computer modeling codes have been evaluated as to their capabilities and accuracy in being able to capture and simulate convective mixing that may occur during PAL thermal processing. The results from these evaluation efforts are summarized in this report. The intention of this project was to extend the technology base and provide for

Development of plenoptic infrared camera using low dimensional material based photodetectors

Science.gov (United States)

Chen, Liangliang

Infrared (IR) sensor has extended imaging from submicron visible spectrum to tens of microns wavelength, which has been widely used for military and civilian application. The conventional bulk semiconductor materials based IR cameras suffer from low frame rate, low resolution, temperature dependent and highly cost, while the unusual Carbon Nanotube (CNT), low dimensional material based nanotechnology has been made much progress in research and industry. The unique properties of CNT lead to investigate CNT based IR photodetectors and imaging system, resolving the sensitivity, speed and cooling difficulties in state of the art IR imagings. The reliability and stability is critical to the transition from nano science to nano engineering especially for infrared sensing. It is not only for the fundamental understanding of CNT photoresponse induced processes, but also for the development of a novel infrared sensitive material with unique optical and electrical features. In the proposed research, the sandwich-structured sensor was fabricated within two polymer layers. The substrate polyimide provided sensor with isolation to background noise, and top parylene packing blocked humid environmental factors. At the same time, the fabrication process was optimized by real time electrical detection dielectrophoresis and multiple annealing to improve fabrication yield and sensor performance. The nanoscale infrared photodetector was characterized by digital microscopy and precise linear stage in order for fully understanding it. Besides, the low noise, high gain readout system was designed together with CNT photodetector to make the nano sensor IR camera available. To explore more of infrared light, we employ compressive sensing algorithm into light field sampling, 3-D camera and compressive video sensing. The redundant of whole light field, including angular images for light field, binocular images for 3-D camera and temporal information of video streams, are extracted and

Mid-infrared pulsed laser ultrasonic testing for carbon fiber reinforced plastics.

Science.gov (United States)

Kusano, Masahiro; Hatano, Hideki; Watanabe, Makoto; Takekawa, Shunji; Yamawaki, Hisashi; Oguchi, Kanae; Enoki, Manabu

2018-03-01

Laser ultrasonic testing (LUT) can realize contactless and instantaneous non-destructive testing, but its signal-to-noise ratio must be improved in order to measure carbon fiber reinforced plastics (CFRPs). We have developed a mid-infrared (mid-IR) laser source optimal for generating ultrasonic waves in CFRPs by using a wavelength conversion device based on an optical parametric oscillator. This paper reports a comparison of the ultrasonic generation behavior between the mid-IR laser and the Nd:YAG laser. The mid-IR laser generated a significantly larger ultrasonic amplitude in CFRP laminates than a conventional Nd:YAG laser. In addition, our study revealed that the surface epoxy matrix of CFRPs plays an important role in laser ultrasonic generation. Copyright © 2017 Elsevier B.V. All rights reserved.

A high-speed, eight-wavelength visible light-infrared pyrometer for shock physics experiments

Science.gov (United States)

Wang, Rongbo; Li, Shengfu; Zhou, Weijun; Luo, Zhen-Xiong; Meng, Jianhua; Tian, Jianhua; He, Lihua; Cheng, Xianchao

2017-09-01

An eight-channel, high speed pyrometer for precise temperature measurement is designed and realized in this work. The addition of longer-wavelength channels sensitive at lower temperatures highly expands the measured temperature range, which covers the temperature of interest in shock physics from 1500K-10000K. The working wavelength range is 400-1700nm from visible light to near-infrared (NIR). Semiconductor detectors of Si and InGaAs are used as photoelectric devices, whose bandwidths are 50MHz and 150MHz respectively. Benefitting from the high responsivity and high speed of detectors, the time resolution of the pyrometer can be smaller than 10ns. By combining the high-transmittance beam-splitters and narrow-bandwidth filters, the peak spectrum transmissivity of each channel can be higher than 60%. The gray-body temperatures of NaI crystal under shock-loading are successfully measured by this pyrometer.

Infrared observations of HDE 226868/Cyg X-1 and HDE 245770/AO535+26

International Nuclear Information System (INIS)

Persi, P.; Toniolo, M.F.; Spada, G.

1979-01-01

It is known from Copernicus ultraviolet observations that all O type stars are losing mass by stellar wind. The ionized expanding circumstellar envelope formed by the stellar wind is emitting through free-free and bound-free radiation processes. This radiation is detectable at the infrared wavelengths where the stellar continuum is negligible. The measurement of the IR excess (defined as the difference between the total flux and the stellar continuum at a given wavelength) and the knowledge of the terminal velocity of the envelope, allow one to derive for OB stars the mass loss rate. From the analysis of Ir observations of two O stars, HDE 226868 and HDE 245770, identified as optical counterpart of X-ray sources, an estimate is given of their mass loss rate. (Auth.)

Infrared Spectroscopy of Gas-Phase M+(CO2)n (M = Co, Rh, Ir) Ion-Molecule Complexes.

Science.gov (United States)

Iskra, Andreas; Gentleman, Alexander S; Kartouzian, Aras; Kent, Michael J; Sharp, Alastair P; Mackenzie, Stuart R

2017-01-12

The structures of gas-phase M + (CO 2 ) n (M = Co, Rh, Ir; n = 2-15) ion-molecule complexes have been investigated using a combination of infrared resonance-enhanced photodissociation (IR-REPD) spectroscopy and density functional theory. The results provide insight into fundamental metal ion-CO 2 interactions, highlighting the trends with increasing ligand number and with different group 9 ions. Spectra have been recorded in the region of the CO 2 asymmetric stretch around 2350 cm -1 using the inert messenger technique and their interpretation has been aided by comparison with simulated infrared spectra of calculated low-energy isomeric structures. All vibrational bands in the smaller complexes are blue-shifted relative to the asymmetric stretch in free CO 2 , consistent with direct binding to the metal center dominated by charge-quadrupole interactions. For all three metal ions, a core [M + (CO 2 ) 2 ] structure is identified to which subsequent ligands are less strongly bound. No evidence is observed in this size regime for complete activation or insertion reactions.

First tests of a multi-wavelength mini-DIAL system for the automatic detection of greenhouse gases

Science.gov (United States)

Parracino, S.; Gelfusa, M.; Lungaroni, M.; Murari, A.; Peluso, E.; Ciparisse, J. F.; Malizia, A.; Rossi, R.; Ventura, P.; Gaudio, P.

2017-10-01

Considering the increase of atmospheric pollution levels in our cities, due to emissions from vehicles and domestic heating, and the growing threat of terrorism, it is necessary to develop instrumentation and gather know-how for the automatic detection and measurement of dangerous substances as quickly and far away as possible. The Multi- Wavelength DIAL, an extension of the conventional DIAL technique, is one of the most powerful remote sensing methods for the identification of multiple substances and seems to be a promising solution compared to existing alternatives. In this paper, first in-field tests of a smart and fully automated Multi-Wavelength mini-DIAL will be presented and discussed in details. The recently developed system, based on a long-wavelength infrared (IR-C) CO2 laser source, has the potential of giving an early warning, whenever something strange is found in the atmosphere, followed by identification and simultaneous concentration measurements of many chemical species, ranging from the most important Greenhouse Gases (GHG) to other harmful Volatile Organic Compounds (VOCs). Preliminary studies, regarding the fingerprint of the investigated substances, have been carried out by cross-referencing database of infrared (IR) spectra, obtained using in-cell measurements, and typical Mixing Ratios in the examined region, extrapolated from the literature. First experiments in atmosphere have been performed into a suburban and moderately-busy area of Rome. Moreover, to optimize the automatic identification of the harmful species to be recognized on the basis of in cell measurements of the absorption coefficient spectra, an advanced multivariate statistical method for classification has been developed and tested.

Componential distribution analysis of food using near infrared ray image

Science.gov (United States)

Yamauchi, Hiroki; Kato, Kunihito; Yamamoto, Kazuhiko; Ogawa, Noriko; Ohba, Kimie

2008-11-01

The components of the food related to the "deliciousness" are usually evaluated by componential analysis. The component content and type of components in the food are determined by this analysis. However, componential analysis is not able to analyze measurements in detail, and the measurement is time consuming. We propose a method to measure the two-dimensional distribution of the component in food using a near infrared ray (IR) image. The advantage of our method is to be able to visualize the invisible components. Many components in food have characteristics such as absorption and reflection of light in the IR range. The component content is measured using subtraction between two wavelengths of near IR light. In this paper, we describe a method to measure the component of food using near IR image processing, and we show an application to visualize the saccharose in the pumpkin.

Optical properties of wet paper and simulation of the effect of autoprofiling on gas-fired IR drying

Energy Technology Data Exchange (ETDEWEB)

Ojala, K T; Lampinen, M J [Helsinki University of Technology (FI)

1991-12-01

Mathematical models are developed to determine the radiative heat transfer of gas-fired infrared dryers. These models are based on the calculation of radiation energy balance between the main surfaces and layers in the dryer section. The energy efficiency can be calculated, when the temperatures of the radiator and the optical properties of all parts of the dryer are known. A computer program is used for studying the autoprofiling effect in gas-fired infrared drying. Optical properties of paper samples of different moisture contents as a function of wavelength are systematically measured by using FT-IR spectrometer and integrating sphere techniques. These measurements covered the moisture content range of 6-150%. The total measured wavelength range is 1.0-20.0 {mu}m. The moisture content of paper increases the absorptivity mainly in two wavelength ranges, i.e. 1.4-2.6 {mu}m and 3.75-6.0 {mu}m. In these ranges, the difference between the absorptivity of two sheets (dry weight 41.1 g/m{sup 2}, moisture contents 6.0% and 20.8%) is 5-10%. Outside these ranges, the difference is less than 5%. The radiation properties of component surfaces of the IR dryer were measured or taken from literature. The dryer efficiency as a function of the moisture content of paper is calculated. The extent of the autoprofilling effect in gas-fired IR drying is hereby achieved for light weight coated paper web. In one simulation, before the dryer, the moisture difference between two sheets was 5.0% (=20% - 15%). After the dryer, the moisture difference was reduced to 4.5%. If the variation in moisture contents is high, the autoprofilling effect takes place and reduces the moisture variaton. (AB).

A Novel Infrared Gas Monitor

Science.gov (United States)

Wang, Yingding; Zhong, Hongjie

2000-03-01

In the paper a novel non-dispersive infrared(IR) gas monitor is described.It is based on the principle that certain gases absorb IR radiation at specific(and often unique) wavelengths.Conventional devices typically include several primary components:a broadband source, usually an incandescent filament,a rotating chopper shutter,a narrow-band filter,a sample tube and a detector. We have developed a number of IR light emitting diodes(LED) having narrow optical bandwidths and which can be intensity modulated by electrical means,for example InAsSbP(4.2 micron)LED.The IR LED can thus replace the thermal source,narrow-band filter and chopper assembly of the conventional IR gas monitor,yielding a solid state,low- powered,compact and almost maintenance-free instrument with high sensitivity and stability and which free of the effects of mechanical vibration too. The detector used in the IR gas monitor is the solid-state detector,such as PbS,PbSe, InSb,HgCdTe,TGS,LT and PZT detector etc. The different configuration of the IR gas monitor is designed.For example,two-path version for measuring methane concentration by monitoring the 3.31 micron absorption band,it can eliminate the interference effects,such as to compensate for LED intensity changes caused by power and temperature variations,and for signal fluctuations due to changes in detector bias. we also have designed portable single-beam version without the sample tube.Its most primary advantage is very cheap(about cost USD 30 ).It measures carbon dioxide concentration by monitoring the 4.25 micron absorption band.Thought its precisions is low,it is used to control carbon dioxide concentration in the air in the green houses and plastic houses(there are about twenty millon one in the China).Because more carbon dioxide will increase the quanity of vegetable and flower production to a greatextent. It also is used in medical,sanitary and antiepidemic applications,such as hospital, store,hotel,cabin and ballroom etc. Key words:infrared

HgCdTe Avalanche Photodiode Detectors for Airborne and Spaceborne Lidar at Infrared Wavelengths

Science.gov (United States)

Sun, Xiaoli; Abshire, James B.; Beck, Jeffrey D.; Mitra, Pradip; Reiff, Kirk; Yang, Guangning

2017-01-01

We report results from characterizing the HgCdTe avalanche photodiode (APD) sensorchip assemblies (SCA) developed for lidar at infrared wavelength using the high density vertically integrated photodiodes (HDVIP) technique. These devices demonstrated high quantum efficiency, typically greater than 90 between 0.8 micrometers and the cut-off wavelength, greater than 600 APD gain, near unity excess noise factor, 6-10 MHz electrical bandwidth and less than 0.5 fW/Hz(exp.1/2) noise equivalent power (NEP). The detectors provide linear analog output with a dynamic range of 2-3 orders of magnitude at a fixed APD gain without averaging, and over 5 orders of magnitude by adjusting the APD and preamplifier gain settings. They have been successfully used in airborne CO2 and CH4 integrated path differential absorption (IPDA) lidar as a precursor for space lidar applications.

These images show thermal infrared radiation from Jupiter at different wavelengths which are diagnos

Science.gov (United States)

2002-01-01

These images show thermal infrared radiation from Jupiter at different wavelengths which are diagnostic of physical phenomena The 7.85-micron image in the upper left shows stratospheric temperatures which are elevated in the region of the A fragment impact (to the left of bottom). Temperatures deeper in the atmosphere near 150-mbar are shown by the 17.2-micron image in the upper right. There is a small elevation of temperatures at this depth, indicated by the arrow, and confirmed by other measurements near this wavelength. This indicates that the influence of the impact of fragment A on the troposphere has been minimal. The two images in the bottom row show no readily apparent perturbation of the ammmonia condensate cloud field near 600 mbar, as diagnosed by 8.57-micron radiation, and deeper cloud layers which are diagnosed by 5-micron radiation.

Dual-wavelength DFB quantum cascade lasers: sources for multi-species trace gas spectroscopy

Science.gov (United States)

Kapsalidis, Filippos; Shahmohammadi, Mehran; Süess, Martin J.; Wolf, Johanna M.; Gini, Emilio; Beck, Mattias; Hundt, Morten; Tuzson, Béla; Emmenegger, Lukas; Faist, Jérôme

2018-06-01

We report on the design, fabrication, and performance of dual-wavelength distributed-feedback (DFB) quantum cascade lasers (QCLs) emitting at several wavelengths in the mid-infrared (mid-IR) spectrum. In this work, two new designs are presented: for the first one, called "Neighbour" DFB, two single-mode DFB QCLs are fabricated next to each other, with minimal lateral distance, to allow efficient beam-coupling into multi-pass gas cells. In addition, the minimal distance allows either laser to be used as an integrated heater for the other, allowing to extend the tuning range of its neighbour without any electrical cross-talk. For the second design, the Vernier effect was used to realize a switchable DFB laser, with two target wavelengths which are distant by about 300 cm^{-1}. These devices are promising laser sources for Tunable Diode Laser Absorption Spectroscopy applications targeting simultaneous detection of multiple gasses, with distant spectral features, in compact and mobile setups.

Multi-wavelength metal-dielectric nonpolarizing beam splitters in the near-infrared range

Science.gov (United States)

Hui Shi, Jin; Ping Wang, Zheng; Ying Guan, Chun; Yang, Jun; Shu Fu, Tian

2011-04-01

A 21-layer multi-wavelength metal-dielectric nonpolarizing cube beam splitter was designed by use of an optimization method and theoretically investigated in the near-infrared range. The angular dependence of the reflectance and differential phases induced by reflection and transmission were presented. The simulation results revealed that the non-polarizing effect could be achieved for both the amplitude and phase characteristics at 1310 and 1550 nm. The differences between the simulated and the target reflectance of 50% are less than 2% and differential phases are less than 5°in the range 1300-1320 nm and 1540-1550 nm for both p- and s-components.

First-Light Galaxies or Intrahalo Stars: Multi-Wavelength Measurements of the Infrared Background Anisotropies

Science.gov (United States)

Cooray, Asantha

The research program described in this proposal can be broadly described as data analysis, measurement, and interpretation of the spatial fluctuations of the unresolved cosmic IR background. We will focus primarily on the background at optical and near-IR wavelengths as probed by Hubble and Spitzer. As absolute background intensity measurements are challenging, the focus is on the spatial fluctuations similar to the anisotropiesof the cosmic microwave background (CMB). Measurements of the unresolved Spitzer fluctuations by two independent teams on multiple fields agree within the measurement errors. However, there are now two interpretations on the origin of the unresolved IRAC fluctuations. One involves a population of faint sources at very high redshifts (z > 6) during the epoch of reionization. The second interpretation involves the integrated emission from intrahalo light associated with diffuse stars in the outskirts of z of 1 to 3 dark matter halos of galaxies. We now propose to further test these two interpretations with a new set of measurements at shorter IR and optical wavelengths with HST/ACS and WFC3 overlapping with deep IRAC surveys. A multi-wavelength study from 0.5 to 4.5 micron will allow us to independently determine the relative contribution of intrahalo light and z > 8 faint galaxies to the unresolved IR fluctuations. We will also place strong limits on the surface density of faint sources at z > 8. Such a limit will be useful for planning deep surveys with JWST. Moving to the recent wide IRAC fields with the warm mission, we propose to study fluctuations at tens of degree angular scales. At such large angular scales IRAC fluctuations should trace diffuse Galactic light (DGL), ISM dust-scattered starlight in our Galaxy. We will measure the amplitude and slope of the DGL power spectrum and compare them to measurements of the Galactic dust power spectrum from IRAS and Planck and study if the large degree-scale fluctuations seen in CIBER can be

Infrared technology XVI; Proceedings of the Meeting, San Diego, CA, July 11-13, 1990

International Nuclear Information System (INIS)

Spiro, I.J.

1990-01-01

Various papers in infrared technology are presented. Individual topics addressed include: Field Observations and Measurement Experiment, GaAs/AlGAs multiquantum-well IR detectors, 256 x 256 PtSi hybrid array for astronomy applications, compact 128 InSb focal plane assembly for thermal imaging, statistical analysis of thermal images generated by line scanning, performance comparison of platinum silicide cameras, atmospheric applications of IR heterodyne laser detection, French activity in IR astronomy from stratospheric balloons, advances in IR technology at Paris Observatory, far-IR photoconductors, applications of IR bidimensional devices in astronomy, far-IR transmission spectra of YBa2Cu3O(7-d) thin films. Also considered are: far-IR multiple-path cell without internal mirrors, optical properties of solid-state laser-type materials in the near-IR, SOFRADIR IR focal plane array production, recent developments on Isocam long-wavelength channel detector, 128 x 128 3-5 micron focal plane arrays at 77-K and 200-K operation, digital test target for display evaluation, IR radiation from rocket plumes, 128 x 128 InGaAs detector array for 1.0-1.7 micron

Synchronous photoelectrical observations of flare stars in the visible and near infrared ranges

International Nuclear Information System (INIS)

Bruevich, V.V.; Kilyachkov, N.N.; Shevchenko, V.S.; Burnashov, V.I.; Grinin, V.P.; Koryshev, V.V.; Shakhovskaya, N.I.

1980-01-01

The results of synchronous photoelectrical observations of the AD Leo and EV Lac flare stars made in 1975 in the Crimea in B-filter and in the near infrared region (i-band, lambdasub(ef) approximately 0.85 μm) and the observations of the UV Cet and EV Lac stars made in 1976 in the Astronomical Institute Uzbek SSR in three passbands: U, isub(TiO)(lambdasub(ef)=0.71 μ) and isub(C)(lambdasub(ef)=0.80μm) are given. Practically all strong flares in the visible spectral range were followed by the IR-flares. In about 70% of the cases the predicted infrared negative preflares were observed. The amplitudes (in erg/s) of the negative flares are comparable with the amplitude of the optical flares. The analysis of the observed data shows that: a) the amplitudes and the energies of the positive IR flares are in average the larger the stronger is the optical flare; b) the amplitudes of the negative IR preflares are on the contrary the smaller the stronger is the optical flare; c) there are infrared flares the main energy out of which takes place in the infrared range of wavelengths; d) The U-i color shows a positive correlation with the amplitude of the flare in U: the stronger is the flare the bluer is its radiation

Infrared reflection nebulae in Orion Molecular Cloud

International Nuclear Information System (INIS)

Pendleton, Y.; Werner, M.W.; Capps, R.; Lester, D.; Hawaii Univ., Honolulu; Texas Univ., Austin)

1986-01-01

New observations of Orion Molecular Cloud 2 have been made from 1 to 100 microns using the NASA Infrared Telescope Facility and the Kuiper Airborne Observatory. An extensive program of polarimetry, photometry, and spectrophotometry has shown that the extended emission regions associated with two of the previously known near-infrared sources, IRS 1 and IRS 4, are infrared reflection nebulae, and that the compact sources IRS 1 and IRS 4 are the main luminosity sources in the cloud. The constraints from the far-infrared observations and an analysis of the scattered light from the IRS 1 nebula show that OMC-2/IRS 1 can be characterized by L of 500 solar luminosities or less and T of roughly 1000 K. The near-infrared albedo of the grains in the IRS 1 nebula is greater than 0.08. 27 references

IR and visible luminescence studies in the infrared multiphoton dissociation of 1,2-dibromo-1,1-difluoroethane

Science.gov (United States)

Pushpa, K. K.; Kumar, Awadhesh; Vatsa, R. K.; Naik, P. D.; Annaji Rao, K.; Mittal, J. P.; Parthasarathy, V.; Sarkar, S. K.

1995-07-01

The infrared multiphoton dissociation of 1,2-dibromo-1,1-difluoroethane gives rise to IR and visible luminescence. Vibrationally excited parent molecules dissociate via two primary channels yielding bromine and vibrationally excited HBr. The strong visible emission observed between 350 to 750 nm has been assigned to electronically excited carbene CF 2Br CH.

THE CHROMOSPHERIC SOLAR LIMB BRIGHTENING AT RADIO, MILLIMETER, SUB-MILLIMETER, AND INFRARED WAVELENGTHS

International Nuclear Information System (INIS)

De la Luz, V.

2016-01-01

Observations of the emission at radio, millimeter, sub-millimeter, and infrared wavelengths in the center of the solar disk validate the autoconsistence of semi-empirical models of the chromosphere. Theoretically, these models must reproduce the emission at the solar limb. In this work, we tested both the VALC and C7 semi-empirical models by computing their emission spectrum in the frequency range from 2 GHz to 10 THz at solar limb altitudes. We calculate the Sun's theoretical radii as well as their limb brightening. Non-local thermodynamic equilibrium was computed for hydrogen, electron density, and H − . In order to solve the radiative transfer equation, a three-dimensional (3D) geometry was employed to determine the ray paths, and Bremsstrahlung, H − , and inverse Bremsstrahlung opacity sources were integrated in the optical depth. We compared the computed solar radii with high-resolution observations at the limb obtained by Clark. We found that there are differences between the observed and computed solar radii of 12,000 km at 20 GHz, 5000 km at 100 GHz, and 1000 km at 3 THz for both semi-empirical models. A difference of 8000 km in the solar radii was found when comparing our results against the heights obtained from H α observations of spicules-off at the solar limb. We conclude that the solar radii cannot be reproduced by VALC and C7 semi-empirical models at radio—infrared wavelengths. Therefore, the structures in the high chromosphere provide a better measurement of the solar radii and their limb brightening as shown in previous investigations.

Influence of infrared stimulation on spectroscopy characteristics of co-planar grid CdZnTe detectors

International Nuclear Information System (INIS)

Fjodorov, V.; Ivanov, V.; Loutchanski, A.

2015-01-01

It was previously found that illumination with monochromatic infrared (IR) light with wavelengths close to the absorption edge of the CdZnTe exert significant positive influence on the spectrometric characteristics of quasi-hemispherical CdZnTe detectors at room temperature. In this paper, preliminary results of IR stimulation on the spectrometric characteristics of coplanar-grid CdZnTe detectors as well as results of further studies of planar and quasi-hemispherical detectors are presented. Coplanar-grid detectors of 10 mm x 10 mm x 10 mm from Redlen Technologies and commercial available IR LEDs with different wavelengths of 800-1000 nm were used in the experiments. Influence of intensity and direction of IR illumination on the detector's characteristics was studied. Analysis of signals shapes from the preamplifiers outputs at registration of alpha particles showed that IR illumination leads to a change in the shapes of these signals. This may indicate changes in electric fields distributions. An improvement in energy resolution at gamma-energy of 662 keV was observed with quasi-hemispherical and co-planar detectors at the certain levels of IR illumination intensity. The most noticeable effect of IR stimulation was observed with quasi-hemispherical detectors. It is due with optimization of charge collection conditions in the quasi-hemispherical detectors under IT stimulation. (authors)

MID-INFRARED ATOMIC FINE-STRUCTURE EMISSION-LINE SPECTRA OF LUMINOUS INFRARED GALAXIES: SPITZER/IRS SPECTRA OF THE GOALS SAMPLE

Energy Technology Data Exchange (ETDEWEB)

Inami, H. [National Optical Astronomy Observatory, Tucson, AZ 85719 (United States); Armus, L.; Stierwalt, S.; Díaz-Santos, T.; Surace, J.; Howell, J.; Marshall, J. [Spitzer Science Center, California Institute of Technology, CA 91125 (United States); Charmandaris, V. [Department of Physics and Institute of Theoretical and Computational Physics, University of Crete, GR-71003 Heraklion (Greece); Groves, B. [Max Planck Institute for Astronomy, Königstuhl 17, D-69117 Heidelberg (Germany); Kewley, L. [Research School of Astronomy and Astrophysics, The Australian National University, Cotter Road, Weston Creek, ACT 2611 (Australia); Petric, A. [Department of Astronomy, California Institute of Technology, MS 320-47, Pasadena, CA 91125 (United States); Rich, J. [The Observatories, Carnegie Institute of Washington, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Haan, S. [CSIRO Astronomy and Space Science, Marsfield, NSW 2122 (Australia); Evans, A. S. [Department of Astronomy, University of Virginia, P.O. Box 400325, Charlottesville, VA 22904 (United States); Mazzarella, J.; Lord, S. [Infrared Processing and Analysis Center, MS 100-22, California Institute of Technology, Pasadena, CA 91125 (United States); Appleton, P. [NASA Herschel Science Center, 770 South Wilson Avenue, Pasadena, CA 91125 (United States); Spoon, H. [Astronomy Department, Cornell University, Ithaca, NY 14853 (United States); Frayer, D. [National Radio Astronomy Observatory, P.O. Box 2, Green Bank, WV 24944 (United States); Matsuhara, H., E-mail: inami@noao.edu [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency (Japan); and others

2013-11-10

, suggesting the possibility of a compact energy source and stratified interstellar medium in their nuclei. We confirm a strong correlation between the sum of the [Ne II]{sub 12.8{sub μm}} and [Ne III]{sub 15.5{sub μm}} emission, as well as [S III]{sub 33.5{sub μm}}, with both the infrared luminosity and the 24 μm warm dust emission measured from the spectra, consistent with all three lines tracing ongoing star formation. Finally, we find no correlation between the hardness of the radiation field or the emission-line width and the ratio of the total infrared to 8 μm emission (IR8), a measure of the strength of the starburst and the distance of the LIRGs from the star-forming main sequence. This may be a function of the fact that the infrared luminosity and the mid-infrared fine-structure lines are sensitive to different timescales over the starburst, or that IR8 is more sensitive to the geometry of the region emitting the warm dust than the radiation field producing the H II region emission.

Performance of a convective, infrared and combined infrared- convective heated conveyor-belt dryer.

Science.gov (United States)

El-Mesery, Hany S; Mwithiga, Gikuru

2015-05-01

A conveyor-belt dryer was developed using a combined infrared and hot air heating system that can be used in the drying of fruits and vegetables. The drying system having two chambers was fitted with infrared radiation heaters and through-flow hot air was provided from a convective heating system. The system was designed to operate under either infrared radiation and cold air (IR-CA) settings of 2000 W/m(2) with forced ambient air at 30 °C and air flow of 0.6 m/s or combined infrared and hot air convection (IR-HA) dryer setting with infrared intensity set at 2000 W/m(2) and hot at 60 °C being blown through the dryer at a velocity of 0.6 m/s or hot air convection (HA) at an air temperature of 60 °C and air flow velocity 0.6 m/s but without infrared heating. Apple slices dried under the different dryer settings were evaluated for quality and energy requirements. It was found that drying of apple (Golden Delicious) slices took place in the falling rate drying period and no constant rate period of drying was observed under any of the test conditions. The IR-HA setting was 57.5 and 39.1 % faster than IR-CA and HA setting, respectively. Specific energy consumption was lower and thermal efficiency was higher for the IR-HA setting when compared to both IR-CA and HA settings. The rehydration ratio, shrinkage and colour properties of apples dried under IR-HA conditions were better than for either IR-CA or HA.

EFFECTS OF FATLIQURING PROCESS ON LEATHERS COLOURED WITH IR REFLECTIVE DYES AND PIGMENTS

Directory of Open Access Journals (Sweden)

MUTLU Mehmet Mete

2017-05-01

Full Text Available Black coloured materials and consumer goods are known to be heating up more, because they absorb sun radiation more than light colours. This heating is a problem for the users for black automotive or motorcycle leathers and also for dark shoes and boots which are exposed to sun heat. Human vision system can distinguish visible colours between the wavelengths of 390-700 nm. So reflecting the sun radiation in the infrared area of radiation spectrum higher than 700nm, is a solution for heating problem without affecting the visible colour. For this reason IR reflective dyes and pigments are designed. A leading Leather Chemical Company has developed an IR reflecting dyeing system for leather keeping the dark coloured leathers cooler under sun radiation. Additionally in theory, fat and water content of leather affects its heating properties. In this study, effect of natural, synthetic and waterproof fatliquoring systems on heating properties of leathers coloured with IR reflective dyes and pigments are investigated.

THE GREAT OBSERVATORIES ALL-SKY LIRG SURVEY: COMPARISON OF ULTRAVIOLET AND FAR-INFRARED PROPERTIES

International Nuclear Information System (INIS)

Howell, Justin H.; Armus, Lee; Surace, Jason A.; Petric, Andreea; Bridge, Carrie; Haan, Sebastian; Inami, Hanae; Mazzarella, Joseph M.; Chan, Ben H. P.; Madore, Barry F.; Evans, Aaron S.; Kim, Dong-Chan; Sanders, David B.; Appleton, Phil; Frayer, David T.; Lord, Steven; Schulz, Bernhard; Bothun, Greg; Charmandaris, Vassilis; Melbourne, Jason

2010-01-01

The Great Observatories All-sky LIRG Survey (GOALS) consists of a complete sample of 202 luminous infrared galaxies (LIRGs) selected from the IRAS Revised Bright Galaxy Sample (RBGS). The galaxies span the full range of interaction stages, from isolated galaxies to interacting pairs to late stage mergers. We present a comparison of the UV and infrared properties of 135 galaxies in GOALS observed by GALEX and Spitzer. For interacting galaxies with separations greater than the resolution of GALEX and Spitzer (∼2''-6''), we assess the UV and IR properties of each galaxy individually. The contribution of the FUV to the measured star formation rate (SFR) ranges from 0.2% to 17.9%, with a median of 2.8% and a mean of 4.0% ± 0.4%. The specific star formation rate (SSFR) of the GOALS sample is extremely high, with a median value (3.9 x 10 -10 yr -1 ) that is comparable to the highest SSFRs seen in the Spitzer Infrared Nearby Galaxies Survey sample. We examine the position of each galaxy on the IR excess-UV slope (IRX-β) diagram as a function of galaxy properties, including IR luminosity and interaction stage. The LIRGs on average have greater IR excesses than would be expected based on their UV colors if they obeyed the same relations as starbursts with L IR 11 L sun or normal late-type galaxies. The ratio of L IR to the value one would estimate from the IRX-β relation published for lower luminosity starburst galaxies ranges from 0.2 to 68, with a median value of 2.7. A minimum of 19% of the total IR luminosity in the RBGS is produced in LIRGs and ultraluminous infrared galaxies with red UV colors (β>0). Among resolved interacting systems, 32% contain one galaxy which dominates the IR emission while the companion dominates the UV emission. Only 21% of the resolved systems contain a single galaxy which dominates both wavelengths.

Highly doped InP as a low loss plasmonic material for mid-IR region.

Science.gov (United States)

Panah, M E Aryaee; Takayama, O; Morozov, S V; Kudryavtsev, K E; Semenova, E S; Lavrinenko, A V

2016-12-12

We study plasmonic properties of highly doped InP in the mid-infrared (IR) range. InP was grown by metal-organic vapor phase epitaxy (MOVPE) with the growth conditions optimized to achieve high free electron concentrations by doping with silicon. The permittivity of the grown material was found by fitting the calculated infrared reflectance spectra to the measured ones. The retrieved permittivity was then used to simulate surface plasmon polaritons (SPPs) propagation on flat and structured surfaces, and the simulation results were verified in direct experiments. SPPs at the top and bottom interfaces of the grown epilayer were excited by the prism coupling. A high-index Ge hemispherical prism provides efficient coupling conditions of SPPs on flat surfaces and facilitates acquiring their dispersion diagrams. We observed diffraction into symmetry-prohibited diffraction orders stimulated by the excitation of surface plasmon-polaritons in a periodically structured epilayer. Characterization shows good agreement between the theory and experimental results and confirms that highly doped InP is an effective plasmonic material aiming it for applications in the mid-IR wavelength range.

Sunlight-driven eco-friendly smart curtain based on infrared responsive graphene oxide-polymer photoactuators.

Science.gov (United States)

Leeladhar; Raturi, Parul; Singh, J P

2018-02-27

Photomechanical actuation is the conversion of light energy into mechanical energy through some smart materials. Infrared-responsive smart materials have become an emerging field of research due to easy availability and eco-friendly nature of their stimulus in the form of sunlight, which contains about 50% of near-infrared(nIR) making these materials useful at macro-scale photoactuator applications. Here, we demonstrate fabrication of highly versatile nIR triggered photoactuators based on graphene oxide/polycarbonate bilayers that offers fast, low-cost fabrication, large deflection, reversible actuation and wavelength-selective response. The photoactuators are realized by vacuum filtration of graphene oxide/water dispersion through polycarbonate membrane resulting graphene oxide/polymer bilayer structure. The photoactuation response was measured in the form of deflection from equilibrium position as a result of infrared-irradiation. The deflection is caused by the generated thermal stress at the interface of bilayers due to mismatch of thermal expansion coefficient as a results of nIR absorption by graphene oxide and subsequent temperature rise. A maximum deflection of 12 mm (circular-shaped structure with diameter 28 mm) with corresponding bending curvature of 0.33 cm -1 was shown by this photoactuator for illumination intensity of 106 mW/cm 2 . Few applications of these photoactuators such as sunlight-driven smart curtain, infrared actuated curtain and self-folding box are also demonstrated.

Development of integrated platform based on chalcogenides for sensing applications in the mid-infrared

Science.gov (United States)

Gutierrez-Arroyo, Aldo; Bodiou, Loïc.; Lemaitre, Jonathan; Baudet, Emeline; Baillieul, Marion; Hardy, Isabelle; Caillaud, Celine; Colas, Florent; Boukerma, Kada; Rinnert, Emmanuel; Michel, Karine; Bureau, Bruno; Nazabal, Virginie; Charrier, Joël.

2018-03-01

Mid-Infrared (mid-IR) spectral range, spanning from 2 μm to 20 μm, is ideal for chemical sensing using spectroscopy thanks to the presence of vibrational absorption bands of many liquid and gas substances in this wavelength range. Indeed, mid-IR spectroscopy allows simultaneous qualitative and quantitative analysis by, respectively, identifying molecules from their spectral signature and relating the concentrations of different chemical agents to their absorption coefficient according to Beer-Lambert law. In the last years, photonic integrated sensors based on mid-IR spectroscopy have emerged as a cheap, accurate, and compact solution that would enable continuous real-time on-site diagnostics and monitoring of molecular species without the need to collect samples for off-site measurements. Here, we report the design, processing and characterization of a photonic integrated transducer based on selenide ridge waveguides. Evanescent wave detection of chemical substances in liquid phase (isopropyl alcohol, C3H8O, and acetic acid, C2H4O2, both dissolved in cyclohexane) is presented using their absorption at a wavelength of 7.7 μm.

Emitted short wavelength infrared radiation for detection and monitoring of volcanic activity

Science.gov (United States)

Rothery, D. A.; Francis, P. W.; Wood, C. A.

1988-01-01

Thematic Mapper images from LANDSAT were used to monitor volcanoes. Achievements include: (1) the discovery of a magmatic precursor to the 16 Sept. 1986 eruption of Lascar, northern Chile, on images from Mar. and July 1985 and of continuing fumarolic activity after the eruption; (2) the detection of unreported major changes in the distribution of lava lakes on Erta'Ale, Ethiopia; and (3) the mapping of a halo of still-hot spatter surrounding a vent on Mount Erebus, Antarctica, on an image acquired 5 min after a minor eruption otherwise known only from seismic records. A spaceborne short wavelength infrared sensor for observing hot phenomena of volcanoes is proposed. A polar orbit is suggested.

[Study of near infrared spectral preprocessing and wavelength selection methods for endometrial cancer tissue].

Science.gov (United States)

Zhao, Li-Ting; Xiang, Yu-Hong; Dai, Yin-Mei; Zhang, Zhuo-Yong

2010-04-01

Near infrared spectroscopy was applied to measure the tissue slice of endometrial tissues for collecting the spectra. A total of 154 spectra were obtained from 154 samples. The number of normal, hyperplasia, and malignant samples was 36, 60, and 58, respectively. Original near infrared spectra are composed of many variables, for example, interference information including instrument errors and physical effects such as particle size and light scatter. In order to reduce these influences, original spectra data should be performed with different spectral preprocessing methods to compress variables and extract useful information. So the methods of spectral preprocessing and wavelength selection have played an important role in near infrared spectroscopy technique. In the present paper the raw spectra were processed using various preprocessing methods including first derivative, multiplication scatter correction, Savitzky-Golay first derivative algorithm, standard normal variate, smoothing, and moving-window median. Standard deviation was used to select the optimal spectral region of 4 000-6 000 cm(-1). Then principal component analysis was used for classification. Principal component analysis results showed that three types of samples could be discriminated completely and the accuracy almost achieved 100%. This study demonstrated that near infrared spectroscopy technology and chemometrics method could be a fast, efficient, and novel means to diagnose cancer. The proposed methods would be a promising and significant diagnosis technique of early stage cancer.

Tunability and Power Characteristics of the LEBRA Infrared FEL

CERN Document Server

Tanaka, Toshinari; Hayakawa, Yasushi; Mori, Akira; Nogami, Kyoko; Sato, Isamu; Yokoyama, Kazue

2004-01-01

Application of the infrared (IR) Free-Electron Laser (FEL) was started in October 2003 at the Laboratory for Electron Beam Research and Application (LEBRA) of Nihon University. The FEL system consisted of silver-coated copper mirrors has demonstrated wavelength tunability ranged from 940 to 6100 nm as a function of the electron energy and the undulator K-value. Wavelength dependence of the FEL output power has been measured in term of different electron beam currents, electron energies and the undulator K-values. Approximate 25 mJ/macropulse has been obtained in the range 2 to 3 microns, which corresponds to peak power of 2 MW, provided that the FEL pulse length is 0.4 ps as resulted from the measurement by an interferometric method. The power decrease observed in the longer wavelength range is due to a large diffraction loss in the FEL guiding optics and the vacuum ducts.

Research into the usage of integrated jamming of IR weakening and smoke-screen resisting the IR imaging guided missiles

Science.gov (United States)

Wang, Long-tao; Jiang, Ning; Lv, Ming-shan

2015-10-01

With the emergence of the anti-ship missle with the capability of infrared imaging guidance, the traditional single jamming measures, because of the jamming mechanism and technical flaws or unsuitable use, greatly reduced the survival probability of the war-ship in the future naval battle. Intergrated jamming of IR weakening + smoke-screen Can not only make jamming to the search and tracking of IR imaging guidance system , but also has feasibility in conjunction, besides , which also make the best jamming effect. The research conclusion has important realistic meaning for raising the antimissile ability of surface ships. With the development of guidance technology, infrared guidance system has expanded by ir point-source homing guidance to infrared imaging guidance, Infrared imaging guidance has made breakthrough progress, Infrared imaging guidance system can use two-dimensional infrared image information of the target, achieve the precise tracking. Which has Higher guidance precision, better concealment, stronger anti-interference ability and could Target the key parts. The traditional single infrared smoke screen jamming or infrared decoy flare interference cannot be imposed effective interference. So, Research how to effectively fight against infrared imaging guided weapons threat measures and means, improving the surface ship antimissile ability is an urgent need to solve.

Efficient and broadband Stokes wave generation by degenerate four-wave mixing at the mid-infrared wavelength in a silica photonic crystal fiber.

Science.gov (United States)

Yuan, Jinhui; Sang, Xinzhu; Wu, Qiang; Zhou, Guiyao; Yu, Chongxiu; Wang, Kuiru; Yan, Binbin; Han, Ying; Farrell, Gerald; Hou, Lantian

2013-12-15

Based on degenerate four-wave mixing (FWM), the broadband Stokes waves are efficiently generated at the mid-infrared wavelength above 2 μm, for the first time to our knowledge, by coupling the femtosecond pulses into the fundamental mode of a silica photonic crystal fiber designed and fabricated in our laboratory. Influences of the power and wavelength of pump pulses on the phase-matched frequency conversion process are discussed. When pump pulses with central wavelength of 815 nm and average power of 300 mW are used, the output power ratio of the Stokes wave generated at 2226 nm and the residual pump wave P(s)/P(res) is estimated to be 10.8:1, and the corresponding conversion efficiency η(s) and bandwidth B(s) of the Stokes wave can be up to 26% and 33 nm, respectively. The efficient and broadband Stokes waves can be used as the ultrashort pulse sources for mid-infrared photonics and spectroscopy.

Progress on type-II InAs/GaSb superlattice (T2SL) infrared photodetector : from MWIR to VLWIR spectral domains

Science.gov (United States)

Christol, P.; Rodriguez, J.-B.

2017-11-01

Infrared photodetectors based on type-II InAs/GaSb superlattice (T2SL) material has been given a lot of attention this past decade, in particular by U.S. laboratories. Among the advantages of this material system, one can cite the possibility to span a large Infrared (IR) range (3μm to 30 μm) by tailoring the band-gap independently from the lattice constant, allowing addressing many applications by the same fabrication process and the realization of multi-color IR sensors for high performance imaging systems. Recently, the maturity of the growth of the quantum structure by molecular beam epitaxy (MBE) and progress on the processing resulted in the demonstration of high-performance mega-pixel focal plane arrays (FPA) in both the mid-wavelength (MWIR) and the long-wavelength (LWIR) infrared spectral bands [1]. Consequently, InAs/GaSb T2SL photodetector can be now considered as a new infrared technology which can be complementary to InSb, MCT or QWIPs technologies. After some reminders on InAs/GaSb T2SL quantum structure properties, we present in this communication the results obtained by the IES laboratory, from Montpellier University, France, for photodiodes operating in the MWIR spectral domains. We then complete the paper by the main results reached by others laboratories for T2SL detectors operating from MWIR to VLWIR spectral ranges.

Power scaling of ultrafast mid-IR source enabled by high-power fiber laser technology

Energy Technology Data Exchange (ETDEWEB)

Zhou, Gengji

2017-11-15

Ultrafast laser sources with high repetition-rate (>10 MHz) and tunable in the mid-infrared (IR) wavelength range of 7-18 μm hold promise for many important spectroscopy applications. Currently, these ultrafast mid- to longwavelength-IR sources can most easily be achieved via difference-frequency generation (DFG) between a pump beam and a signal beam. However, current ultrafast mid- to longwavelength-IR sources feature a low average power, which limits their applications. In this thesis, we propose and demonstrate a novel approach to power scaling of DFG-based ultrafast mid-IR laser sources. The essence of this novel approach is the generation of a high-energy signal beam. Both the pump beam and the signal beam are derived from a home-built Yb-fiber laser system that emits 165-fs pulses centered at 1035 nm with 30-MHz repetition rate and 14.5-W average power (corresponding to 483-nJ pulse energy). We employ fiber-optic self-phase modulation (SPM) to broaden the laser spectrum and generate isolated spectral lobes. Filtering the rightmost spectral lobe leads to femtosecond pulses with >10 nJ pulse energy. Tunable between 1.1-1.2 μm, this SPM-enabled ultrafast source exhibits ∝100 times higher pulse energy than can be obtained from Raman soliton sources in this wavelength range. We use this SPM-enabled source as the signal beam and part of the Yb-fiber laser output as the pump beam. By performing DFG in GaSe crystals, we demonstrate that power scaling of a DFG-based mid-IR source can be efficiently achieved by increasing the signal energy. The resulting mid-IR source is tunable from 7.4 μm to 16.8 μm. Up to 5.04-mW mid-IR pulses centered at 11 μm are achieved. The corresponding pulse energy is 167 pJ, representing nearly one order of magnitude improvement compared with other reported DFG-based mid-IR sources at this wavelength. Despite of low pulse energy, Raman soliton sources have become a popular choice as the signal source. We carry out a detailed study on

Power scaling of ultrafast mid-IR source enabled by high-power fiber laser technology

International Nuclear Information System (INIS)

Zhou, Gengji

2017-11-01

Ultrafast laser sources with high repetition-rate (>10 MHz) and tunable in the mid-infrared (IR) wavelength range of 7-18 μm hold promise for many important spectroscopy applications. Currently, these ultrafast mid- to longwavelength-IR sources can most easily be achieved via difference-frequency generation (DFG) between a pump beam and a signal beam. However, current ultrafast mid- to longwavelength-IR sources feature a low average power, which limits their applications. In this thesis, we propose and demonstrate a novel approach to power scaling of DFG-based ultrafast mid-IR laser sources. The essence of this novel approach is the generation of a high-energy signal beam. Both the pump beam and the signal beam are derived from a home-built Yb-fiber laser system that emits 165-fs pulses centered at 1035 nm with 30-MHz repetition rate and 14.5-W average power (corresponding to 483-nJ pulse energy). We employ fiber-optic self-phase modulation (SPM) to broaden the laser spectrum and generate isolated spectral lobes. Filtering the rightmost spectral lobe leads to femtosecond pulses with >10 nJ pulse energy. Tunable between 1.1-1.2 μm, this SPM-enabled ultrafast source exhibits ∝100 times higher pulse energy than can be obtained from Raman soliton sources in this wavelength range. We use this SPM-enabled source as the signal beam and part of the Yb-fiber laser output as the pump beam. By performing DFG in GaSe crystals, we demonstrate that power scaling of a DFG-based mid-IR source can be efficiently achieved by increasing the signal energy. The resulting mid-IR source is tunable from 7.4 μm to 16.8 μm. Up to 5.04-mW mid-IR pulses centered at 11 μm are achieved. The corresponding pulse energy is 167 pJ, representing nearly one order of magnitude improvement compared with other reported DFG-based mid-IR sources at this wavelength. Despite of low pulse energy, Raman soliton sources have become a popular choice as the signal source. We carry out a detailed study on

Strong Solar Control of Infrared Aurora on Jupiter: Correlation Since the Last Solar Maximum

Science.gov (United States)

Kostiuk, T.; Livengood, T. A.; Hewagama, T.

2009-01-01

Polar aurorae in Jupiter's atmosphere radiate throughout the electromagnetic spectrum from X ray through mid-infrared (mid-IR, 5 - 20 micron wavelength). Voyager IRIS data and ground-based spectroscopic measurements of Jupiter's northern mid-IR aurora, acquired since 1982, reveal a correlation between auroral brightness and solar activity that has not been observed in Jovian aurora at other wavelengths. Over nearly three solar cycles, Jupiter auroral ethane emission brightness and solar 10.7 cm radio flux and sunspot number are positively correlated with high confidence. Ethane line emission intensity varies over tenfold between low and high solar activity periods. Detailed measurements have been made using the GSFC HIPWAC spectrometer at the NASA IRTF since the last solar maximum, following the mid-IR emission through the declining phase toward solar minimum. An even more convincing correlation with solar activity is evident in these data. Current analyses of these results will be described, including planned measurements on polar ethane line emission scheduled through the rise of the next solar maximum beginning in 2009, with a steep gradient to a maximum in 2012. This work is relevant to the Juno mission and to the development of the Europa Jupiter System Mission. Results of observations at the Infrared Telescope Facility (IRTF) operated by the University of Hawaii under Cooperative Agreement no. NCC5-538 with the National Aeronautics and Space Administration, Science Mission Directorate, Planetary Astronomy Program. This work was supported by the NASA Planetary Astronomy Program.

WW domain folding complexity revealed by infrared spectroscopy.

Science.gov (United States)

Davis, Caitlin M; Dyer, R Brian

2014-09-02

Although the intrinsic tryptophan fluorescence of proteins offers a convenient probe of protein folding, interpretation of the fluorescence spectrum is often difficult because it is sensitive to both global and local changes. Infrared (IR) spectroscopy offers a complementary measure of structural changes involved in protein folding, because it probes changes in the secondary structure of the protein backbone. Here we demonstrate the advantages of using multiple probes, infrared and fluorescence spectroscopy, to study the folding of the FBP28 WW domain. Laser-induced temperature jumps coupled with fluorescence or infrared spectroscopy have been used to probe changes in the peptide backbone on the submillisecond time scale. The relaxation dynamics of the β-sheets and β-turn were measured independently by probing the corresponding IR bands assigned in the amide I region. Using these wavelength-dependent measurements, we observe three kinetics phases, with the fastest process corresponding to the relaxation kinetics of the turns. In contrast, fluorescence measurements of the wild-type WW domain and tryptophan mutants exhibit single-exponential kinetics with a lifetime that corresponds to the slowest phase observed by infrared spectroscopy. Mutant sequences provide evidence of an intermediate dry molten globule state. The slowest step in the folding of this WW domain is the tight packing of the side chains in the transition from the dry molten globule intermediate to the native structure. This study demonstrates that using multiple complementary probes enhances the interpretation of protein folding dynamics.

THE CHROMOSPHERIC SOLAR LIMB BRIGHTENING AT RADIO, MILLIMETER, SUB-MILLIMETER, AND INFRARED WAVELENGTHS

Energy Technology Data Exchange (ETDEWEB)

De la Luz, V. [Conacyt—SCiESMEX, Instituto de Geofísica, Unidad Michoacán, Universidad Nacional Autónoma de México, Morelia, Michoacán, 58190, México (Mexico)

2016-07-10

Observations of the emission at radio, millimeter, sub-millimeter, and infrared wavelengths in the center of the solar disk validate the autoconsistence of semi-empirical models of the chromosphere. Theoretically, these models must reproduce the emission at the solar limb. In this work, we tested both the VALC and C7 semi-empirical models by computing their emission spectrum in the frequency range from 2 GHz to 10 THz at solar limb altitudes. We calculate the Sun's theoretical radii as well as their limb brightening. Non-local thermodynamic equilibrium was computed for hydrogen, electron density, and H{sup −}. In order to solve the radiative transfer equation, a three-dimensional (3D) geometry was employed to determine the ray paths, and Bremsstrahlung, H{sup −}, and inverse Bremsstrahlung opacity sources were integrated in the optical depth. We compared the computed solar radii with high-resolution observations at the limb obtained by Clark. We found that there are differences between the observed and computed solar radii of 12,000 km at 20 GHz, 5000 km at 100 GHz, and 1000 km at 3 THz for both semi-empirical models. A difference of 8000 km in the solar radii was found when comparing our results against the heights obtained from H α observations of spicules-off at the solar limb. We conclude that the solar radii cannot be reproduced by VALC and C7 semi-empirical models at radio—infrared wavelengths. Therefore, the structures in the high chromosphere provide a better measurement of the solar radii and their limb brightening as shown in previous investigations.

Measurement of Two-Phase Flow and Heat Transfer Parameters using Infrared Thermometry

Science.gov (United States)

Kim, Tae-Hoon; Kommer, Eric; Dessiatoun, Serguei; Kim, Jungho

2012-01-01

A novel technique to measure heat transfer and liquid film thickness distributions over relatively large areas for two-phase flow and heat transfer phenomena using infrared (IR)thermometry is described. IR thermometry is an established technology that can be used to measure temperatures when optical access to the surface is available in the wavelengths of interest. In this work, a midwave IR camera (3.6-5.1 microns) is used to determine the temperature distribution within a multilayer consisting of a silicon substrate coated with a thin insulator. Since silicon is largely transparent to IR radiation, the temperature of the inner and outer walls of the multilayer can be measured by coating selected areas with a thin, IR opaque film. If the fluid used is also partially transparent to IR, the flow can be visualized and the liquid film thickness can be measured. The theoretical basis for the technique is given along with a description of the test apparatus and data reduction procedure. The technique is demonstrated by determining the heat transfer coefficient distributions produced by droplet evaporation and flow boiling heat transfer.

CONTINUOUS MID-INFRARED STAR FORMATION RATE INDICATORS: DIAGNOSTICS FOR 0 < z < 3 STAR-FORMING GALAXIES

Energy Technology Data Exchange (ETDEWEB)

Battisti, A. J.; Calzetti, D. [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States); Johnson, B. D. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Elbaz, D., E-mail: abattist@astro.umass.edu [Laboratoire AIM-Paris-Saclay, CEA/DSM/Irfu, CNRS, Université Paris Diderot, Saclay, pt courrier 131, F-91191 Gif-sur-Yvette (France)

2015-02-20

We present continuous, monochromatic star formation rate (SFR) indicators over the mid-infrared wavelength range of 6–70 μm. We use a sample of 58 star-forming galaxies (SFGs) in the Spitzer–SDSS–GALEX Spectroscopic Survey at z < 0.2, for which there is a rich suite of multi-wavelength photometry and spectroscopy from the ultraviolet through to the infrared. The data from the Spitzer Infrared Spectrograph (IRS) of these galaxies, which spans 5–40 μm, is anchored to their photometric counterparts. The spectral region between 40–70 μm is interpolated using dust model fits to the IRS spectrum and Spitzer 70 and 160 μm photometry. Since there are no sharp spectral features in this region, we expect these interpolations to be robust. This spectral range is calibrated as a SFR diagnostic using several reference SFR indicators to mitigate potential bias. Our band-specific continuous SFR indicators are found to be consistent with monochromatic calibrations in the local universe, as derived from Spitzer, WISE, and Herschel photometry. Our local composite template and continuous SFR diagnostics are made available for public use through the NASA/IPAC Infrared Science Archive (IRSA) and have typical dispersions of 30% or less. We discuss the validity and range of applicability for our SFR indicators in the context of unveiling the formation and evolution of galaxies. Additionally, in the era of the James Webb Space Telescope this will become a flexible tool, applicable to any SFG up to z ∼ 3.

Long-wavelength germanium photodetectors by ion implantation

International Nuclear Information System (INIS)

Wu, I.C.; Beeman, J.W.; Luke, P.N.; Hansen, W.L.; Haller, E.E.

1990-11-01

Extrinsic far-infrared photoconductivity in thin high-purity germanium wafers implanted with multiple-energy boron ions has been investigated. Initial results from Fourier transform spectrometer(FTS) measurements have demonstrated that photodetectors fabricated from this material have an extended long-wavelength threshold near 192μm. Due to the high-purity substrate, the ability to block the hopping conduction in the implanted IR-active layer yields dark currents of less than 100 electrons/sec at temperatures below 1.3 K under an operating bias of up to 70 mV. Optimum peak responsivity and noise equivalent power (NEP) for these sensitive detectors are 0.9 A/W and 5 x 10 -16 W/Hz 1/2 at 99 μm, respectively. The dependence of the performance of devices on the residual donor concentration in the implanted layer will be discussed. 12 refs., 4 figs

Atomic Data for Stellar Astrophysics: from the UV to the IR

Science.gov (United States)

Wahlgren, Glenn M.

2011-01-01

The study of stars and stellar evolution relies heavily on the analysis of stellar spectra. The need for atomic line data from the ultraviolet (UV) to the infrared (lR) regions is greater now than ever. In the past twenty years, the time since the launch of the Hubble Space Telescope, great progress has been made in acquiring atomic data for UV transitions. The optical wavelength region, now expanded by progress in detector technology, continues to provide motivation for new atomic data. In addition, investments in new instrumentation for ground-based and space observatories has lead to the availability of high-quality spectra at IR wavelengths, where the need for atomic data is most critical. In this review, examples are provided of the progress made in generating atomic data for stellar studies, with a look to the future for addressing the accuracy and completeness of atomic data for anticipated needs.

Multispectral Detection with Metal-Dielectric Filters: An Investigation in Several Wavelength Bands with Temporal Coupled-Mode Theory

Science.gov (United States)

Lesmanne, Emeline; Espiau de Lamaestre, Roch; Boutami, Salim; Durantin, Cédric; Dussopt, Laurent; Badano, Giacomo

2016-09-01

Multispectral infrared (IR) detection is of great interest to enhance our ability to gather information from a scene. Filtering is a low-cost alternative to the complex multispectral device architectures to which the IR community has devoted much attention. Multilayer dielectric filters are standard in industry, but they require changing the thickness of at least one layer to tune the wavelength. Here, we pursue an approach based on apertures in a metallic layer of fixed thickness, in which the filtered wavelengths are selected by varying the aperture geometry. In particular, we study filters made of at least one sheet of resonating apertures in metal embedded in dielectrics. We will discuss two interesting problems that arise when one attempts to design such filters. First, metallic absorption must be taken into account. Second, the form and size of the pattern is limited by lithography. We will present some design examples and an attempt at explaining the filtering behavior based on the temporal coupled mode theory. That theory models the filter as a resonator interacting with the environment via loss channels. The transmission is solely determined by the loss rates associated with those channels. This model allows us to give a general picture of the filtering performance and compare their characteristics at different wavelength bands.

Toward optimal spatial and spectral quality in widefield infrared spectromicroscopy of IR labelled single cells.

Science.gov (United States)

Mattson, Eric C; Unger, Miriam; Clède, Sylvain; Lambert, François; Policar, Clotilde; Imtiaz, Asher; D'Souza, Roshan; Hirschmugl, Carol J

2013-10-07

Advancements in widefield infrared spectromicroscopy have recently been demonstrated following the commissioning of IRENI (InfraRed ENvironmental Imaging), a Fourier Transform infrared (FTIR) chemical imaging beamline at the Synchrotron Radiation Center. The present study demonstrates the effects of magnification, spatial oversampling, spectral pre-processing and deconvolution, focusing on the intracellular detection and distribution of an exogenous metal tris-carbonyl derivative 1 in a single MDA-MB-231 breast cancer cell. We demonstrate here that spatial oversampling for synchrotron-based infrared imaging is critical to obtain accurate diffraction-limited images at all wavelengths simultaneously. Resolution criteria and results from raw and deconvoluted images for two Schwarzschild objectives (36×, NA 0.5 and 74×, NA 0.65) are compared to each other and to prior reports for raster-scanned, confocal microscopes. The resolution of the imaging data can be improved by deconvolving the instrumental broadening that is determined with the measured PSFs, which is implemented with GPU programming architecture for fast hyperspectral processing. High definition, rapidly acquired, FTIR chemical images of respective spectral signatures of the cell 1 and shows that 1 is localized next to the phosphate- and Amide-rich regions, in agreement with previous infrared and luminescence studies. The infrared image contrast, localization and definition are improved after applying proven spectral pre-processing (principal component analysis based noise reduction and RMie scattering correction algorithms) to individual pixel spectra in the hyperspectral cube.

Design of mini-multi-gas monitoring system based on IR absorption

Energy Technology Data Exchange (ETDEWEB)

Tan, Q.L.; Zhang, W.D.; Xue, C.Y.; Xiong, J.J.; Ma, Y.C.; Wen, F. [Northern University of China, Taiyuan (China)

2008-07-15

In this paper, a novel non-dispersive infrared ray (IR) gas detection system is described. Conventional devices typically include several primary components: a broadband source (usually all incandescent filament), a rotating chopper shutter, a narrow-band filter, a sample tube and a detector. But we mainly use file mini-multi-channel detector, electrical modulation means and mini-gas-cell structure. To solve the problems of gas accidents in coal mines, and for family safety that results from using gas, this new IR detection system with integration, miniaturization and non-moving parts has been developed. It is based on the principle that certain gases absorb infrared radiation at specific (and often unique) wavelengths. The infrared detection optics principle used in developing this system is mainly analyzed. The idea of multi-gas detection is introduced and guided through the analysis of the single-gas detection. Through researching the design of cell structure, a cell with integration and miniaturization has been devised. By taking a single-chip microcomputer (SCM) as intelligence handling, the functional block diagram of a gas detection system is designed with the analyzing and devising of its hardware and software system. The way of data transmission on a controller area network (CAN) bus and wireless data transmission mode is explained. This system has reached the technology requirement of lower power consumption, mini-volume, wide measure range, and is able to realize multi-gas detection.

LOCAL LUMINOUS INFRARED GALAXIES. II. ACTIVE GALACTIC NUCLEUS ACTIVITY FROM SPITZER/INFRARED SPECTROGRAPH SPECTRA

Energy Technology Data Exchange (ETDEWEB)

Alonso-Herrero, Almudena; Pereira-Santaella, Miguel [Centro de Astrobiologia, INTA-CSIC, E-28850 Torrejon de Ardoz, Madrid (Spain); Rieke, George H. [Steward Observatory, University of Arizona, Tucson, AZ 85721 (United States); Rigopoulou, Dimitra [Astrophysics Department, University of Oxford, Oxford OX1 3RH (United Kingdom)

2012-01-01

We quantify the active galactic nucleus (AGN) contribution to the mid-infrared (mid-IR) and the total infrared (IR, 8-1000 {mu}m) emission in a complete volume-limited sample of 53 local luminous infrared galaxies (LIRGs, L{sub IR} = 10{sup 11}-10{sup 12} L{sub Sun }). We decompose the Spitzer Infrared Spectrograph low-resolution 5-38 {mu}m spectra of the LIRGs into AGN and starburst components using clumpy torus models and star-forming galaxy templates, respectively. We find that 50% (25/50) of local LIRGs have an AGN component detected with this method. There is good agreement between these AGN detections through mid-IR spectral decomposition and other AGN indicators, such as the optical spectral class, mid-IR spectral features, and X-ray properties. Taking all the AGN indicators together, the AGN detection rate in the individual nuclei of LIRGs is {approx}62%. The derived AGN bolometric luminosities are in the range L{sub bol}(AGN) = (0.4-50) Multiplication-Sign 10{sup 43} erg s{sup -1}. The AGN bolometric contribution to the IR luminosities of the galaxies is generally small, with 70% of LIRGs having L{sub bol}[AGN]/L{sub IR} {<=} 0.05. Only {approx_equal} 8% of local LIRGs have a significant AGN bolometric contribution L{sub bol}[AGN]/L{sub IR} > 0.25. From the comparison of our results with literature results of ultraluminous infrared galaxies (L{sub IR} = 10{sup 12}-10{sup 13} L{sub Sun }), we confirm that in the local universe the AGN bolometric contribution to the IR luminosity increases with the IR luminosity of the galaxy/system. If we add up the AGN bolometric luminosities we find that AGNs only account for 5%{sub -3%}{sup +8%} of the total IR luminosity produced by local LIRGs (with and without AGN detections). This proves that the bulk of the IR luminosity of local LIRGs is due to star formation activity. Taking the newly determined IR luminosity density of LIRGs in the local universe, we then estimate an AGN IR luminosity density of {Omega}{sup AGN

2.4-197 mu m spectroscopy of OH/IR stars : the IR characteristics of circumstellar dust in O-rich environments

NARCIS (Netherlands)

Sylvester, RJ; Kemper, F; Barlow, MJ; de Jong, T; Waters, LBFM; Tielens, AGGM; Omont, A

1999-01-01

Infrared spectra of a number of evolved O-rich stars have been obtained with the Short- and Long-Wavelength spectrometers on board the Infrared Space Observatory. The very broad wavelength coverage (2.4-197 mu m) obtained by combining observations made with the two spectrometers includes practically

Looking at Art in the IR and UV

Science.gov (United States)

Falco, Charles

2013-03-01

Starting with the very earliest cave paintings art has been created to be viewed by the unaided eye and, until very recently, it wasn't even possible to see it at wavelengths outside the visible spectrum. However, it is now possible to view paintings, sculptures, manuscripts, and other cultural artifacts at wavelengths from the x-ray, through the ultraviolet (UV), to well into the infrared (IR). Further, thanks to recent advances in technology, this is becoming possible with hand-held instruments that can be used in locations that were previously inaccessible to anything but laboratory-scale image capture equipment. But, what can be learned from such ``non-visible'' images? In this talk I will briefly describe the characteristics of high resolution UV and IR imaging systems I developed for this purpose by modifying high resolution digital cameras. The sensitivity of the IR camera makes it possible to obtain images of art ``in situ'' with standard museum lighting, resolving features finer than 0.35 mm on a 1.0x0.67 m painting. I also have used both it and the UV camera in remote locations with battery-powered illumination sources. I will illustrate their capabilities with images of various examples of Western, Asian, and Islamic art in museums on three continents, describing how these images have revealed important new information about the working practices of artists as famous as Jan van Eyck. I also will describe what will be possible for this type of work with new capabilities that could be developed within the next few years. This work is based on a collaboration with David Hockney, and benefitted from image analys research supported by ARO grant W911NF-06-1-0359-P00001.

From Modeling to Fabrication of Double Side Microstructured Silicon Windows for Infrared Gas Sensing in Harsh Environments

DEFF Research Database (Denmark)

Bergmann, René; Ivinskaya, Aliaksandra; Kafka, Jan Robert

2014-01-01

(∅1") were manufactured. The windows show high temperature resistant sub-wavelength anti-reflective surface microstructures on both side faces. Thus, a peak transmittance of 100% for a defined main wavelength (5 μm) and more than 90 % average transmittance for the wavelength range of 5-7 μm......Commercial infrared windows used for gas sensing in the mid-IR range usually possess an anti-reflective coating. Those coatings can normally not withstand harsh environments, particularly not high temperatures. With a simple “3-step” fabrication process, high temperature resistant silicon windows...... was achieved. The modeling of the anti-reflective microstructures, their fabrication process and final transmittance analysis of the windows is discussed....

Near infrared focal plane for the ISOCAM camera

International Nuclear Information System (INIS)

Epstein, G.; Stefanovitch, D.; Tiphene, D.; Carpentier, Y.; Lorans, D.

1988-01-01

ISOCAM is one of the science instruments in the Infrared Space Observatory. It is a 2-channel IR Astronomical Imager intended to observe at very low flux levels, thanks to the use of a liquid helium cooled telescope. This paper describes the Focal Plane Assembly design of the short wavelength channel. The operation of a 32 x 32 InSb CID-SAT array detector has been demonstrated. The problems encountered in the design of the cooled electronics and the component selection process are discussed in the light of specific ISO constraints, such as thermal control and radiation shielding. 6 references

Wavelength Selection For Laser Raman Spectroscopy of Putative Martian Habitats and Biomolecules

Science.gov (United States)

Wynn-Williams, D. D.; Newton, E. M. G.; Edwards, H. G. M.

Pigments are key potential biomarkers for any former life on Mars because of the selective pressure of solar radiation on any biological system that could have evolved at its surface. We have found that the near -Infrared laser Raman spectrometer available to use was eminently suitable for diagnostic analysis of pigments because of their minimal autofluorescence at its 1064 nm excitation wav elength. However, we have now evaluated a diverse range of excitation wavelengths to confirm this choice, to ensure that we have the best technique to seek for pigments and their derivatives from any former surface life on Mars. The Raman is weak relative to fluorescence, which results in elevated baseline and concurrent swamping of Raman bands. We confirm the molecular information available from near-IR FT Raman spectra for two highly pigmented UV-tolerant epilithic Antarctic lichens (Acarospora chlorop hana and Caloplaca saxicola) from Victoria Land, a whole endolithic microbial community and endolithic cyanobacterium Chroococcidiopsis from within translucent sandstone of the Trans -Antarctic Mountains, and the free- living cyanobacterium Nostoc commune from Alexander Island, Antarctic Peninsula region. We also show that much of the information we require on biomolecules is not evident from lasers of shorter wavelengths. A miniature 1064 nm Raman spectrometer with an In-Ga-As detector sensitive to IR is being developed by Montana State University (now existing as a prototype) as the prime instrument for a proposed UK-led Mars rover mission (Vanguard). Preliminary spectra from this system confirm the suitability of the near-IR laser.

Multi-wavelength study of infrared galaxies

International Nuclear Information System (INIS)

Marcillac, Delphine

2005-01-01

This thesis deals with a panchromatic study of luminous infrared galaxies (LIRGs) detected at 15 microns by ISOCAM (camera aboard ISO) and at 24 microns by MIPS (camera aboard the recently launched Spitzer satellite). These galaxies are today considered to be the Rosetta Stone of galaxy evolution since they are found to be far more numerous at high redshift and it is thought that a large part of stars seen in the local universe are born in such phases. The first part of this thesis presents a new study dedicated to dust emission of distant LIRGs in the mid-infrared range. Their dust emission has been compared to those of a local sample of LIRGs in addition to the prediction of several spectral energy distributions (SEDs) built on data available in the local universe. It has been shown that distant and local LIRGs present similar mid infrared spectral energy distribution: similar PAH bumps are detected in both local and distant LIRGs, however distant LIRGs show evidence of a stronger silicate absorption at 10 microns associated silicate grains. It also shows that distant LIRG mid infrared emission can be used together with local SEDs in order to estimate the total infrared luminosity. The second part of this thesis is dedicated to the burst of star formation and to the recent star formation history of these galaxies, which is responsible for the dust emission. This study was done thanks to a combination of high resolution spectra (R=2000 in the rest frame) obtained at VLT/FORS2 and the stellar population synthesis models called GALAXEV (Bruzual and Charlot, 2003). It has been shown that the burst of star formation has a duration of about 0.1 Gyear. About 10 % of the stellar content is formed during this burst of star formation. (author) [fr

The Infrared Astronomical Satellite (IRAS) mission

Science.gov (United States)

Neugebauer, G.; Habing, H. J.; Van Duinen, R.; Aumann, H. H.; Beichman, C. A.; Baud, B.; Beintema, D. A.; Boggess, N.; Clegg, P. E.; De Jong, T.

1984-01-01

The Infrared Astronomical Satellite (IRAS) consists of a spacecraft and a liquid helium cryostat that contains a cooled IR telescope. The telescope's focal plane assembly is cooled to less than 3 K, and contains 62 IR detectors in the survey array which are arranged so that every source crossing the field of view can be seen by at least two detectors in each of four wavelength bands. The satellite was launched into a 900 km-altitude near-polar orbit, and its cryogenic helium supply was exhausted on November 22, 1983. By mission's end, 72 percent of the sky had been observed with three or more hours-confirming scans, and 95 percent with two or more hours-confirming scans. About 2000 stars detected at 12 and 25 microns early in the mission, and identified in the SAO (1966) catalog, have a positional uncertainty ellipse whose axes are 45 x 9 arcsec for an hours-confirmed source.

[Application of wavelength selection algorithm to measure the effective component of Chinese medicine based on near-infrared spectroscopy].

Science.gov (United States)

Gu, Xiao-Yu; Xu, Ke-Xin; Wang, Yan

2006-09-01

Near infrared (NIR) spectroscopy has raised a lot of interest in the pharmaceutical industry because it is a rapid and cost-effective analytical type of spectroscopy with no need for extensive sample preparation, and with the easy-realizable ability of on-line application. The NIR technology can increase the quality control standard of the Chinese medicine and accelerate the entry into the international market. In the present paper, two methods for wavelength selection are applied to the measurement of borneol, one of which is the multiple-chain stepwise, which tends to select many variables in the same area containing valuable information, and the other is the mixture genetic algorithm, which incorporates simulated annealing so as to improve the local searching ability while maintaining the global searching ability. The results present that the number of wavelength is reduced to 16% compared with the original number of wavelength, and the prediction accuracy has increased 47.6%. Therefore, the method of wavelength selection is a good way to enhance the prediction accuracy and simplify the model in NIR region.

Infrared detectors and focal plane arrays; Proceedings of the Meeting, Orlando, FL, Apr. 18, 19, 1990

Science.gov (United States)

Dereniak, Eustace L.; Sampson, Robert E.

1990-09-01

The papers contained in this volume provide an overview of recent advances and the current state of developments in the field of infrared detectors and focal plane arrays. Topics discussed include nickel silicide Schottky-barrier detectors for short-wavelength infrared applications; high performance PtSi linear and focal plane arrays; and multispectral band Schottky-barrier IRSSD for remote-sensing applications. Papers are also presented on the performance of an Insi hybrid focal array; characterization of IR focal plane test stations; GaAs CCD readout for engineered bandgap detectors; and fire detection system for aircraft cargo bays.

low-Cost, High-Performance Alternatives for Target Temperature Monitoring Using the Near-Infrared Spectrum

Energy Technology Data Exchange (ETDEWEB)

Virgo, Mathew [Argonne National Lab. (ANL), Argonne, IL (United States); Quigley, Kevin J. [Argonne National Lab. (ANL), Argonne, IL (United States); Chemerisov, Sergey [Argonne National Lab. (ANL), Argonne, IL (United States); Vandegrift, George F. [Argonne National Lab. (ANL), Argonne, IL (United States)

2017-02-01

A process is being developed for commercial production of the medical isotope Mo-99 through a photo-nuclear reaction on a Mo-100 target using a highpower electron accelerator. This process requires temperature monitoring of the window through which a high-current electron beam is transmitted to the target. For this purpose, we evaluated two near infrared technologies: the OMEGA Engineering iR2 pyrometer and the Ocean Optics Maya2000 spectrometer with infrared-enhanced charge-coupled device (CCD) sensor. Measuring in the near infrared spectrum, in contrast to the long-wavelength infrared spectrum, offers a few immediate advantages: (1) ordinary glass or quartz optical elements can be used; (2) alignment can be performed without heating the target; and (3) emissivity corrections to temperature are typically less than 10%. If spatial resolution is not required, the infrared pyrometer is attractive because of its accuracy, low cost, and simplicity. If spatial resolution is required, we make recommendations for near-infrared imaging based on our data augmented by calculations

Infrared interference patterns for new capabilities in laser end point detection

International Nuclear Information System (INIS)

Heason, D J; Spencer, A G

2003-01-01

Standard laser interferometry is used in dry etch fabrication of semiconductor and MEMS devices to measure etch depth, rate and to detect the process end point. However, many wafer materials, such as silicon are absorbing at probing wavelengths in the visible, severely limiting the amount of information that can be obtained using this technique. At infrared (IR) wavelengths around 1500 nm and above, silicon is highly transparent. In this paper we describe an instrument that can be used to monitor etch depth throughout a thru-wafer etch. The provision of this information could eliminate the requirement of an 'etch stop' layer and improve the performance of fabricated devices. We have added a further new capability by using tuneable lasers to scan through wavelengths in the near IR to generate an interference pattern. Fitting a theoretical curve to this interference pattern gives in situ measurement of film thickness. Whereas conventional interferometry would only allow etch depth to be monitored in real time, we can use a pre-etch thickness measurement to terminate the etch on a remaining thickness of film material. This paper discusses the capabilities of, and the opportunities offered by, this new technique and gives examples of applications in MEMS and waveguides

Short wavelength infrared optical windows for evaluation of benign and malignant tissues

Science.gov (United States)

Sordillo, Diana C.; Sordillo, Laura A.; Sordillo, Peter P.; Shi, Lingyan; Alfano, Robert R.

2017-04-01

There are three short wavelength infrared (SWIR) optical windows outside the conventionally used first near-infrared (NIR) window (650 to 950 nm). They occur in the 1000- to 2500-nm range and may be considered second, third, and fourth NIR windows. The second (1100 to 1350 nm) and third windows (1600 to 1870 nm) are now being explored through label-free linear and multiphoton imaging. The fourth window (2100 to 2350 nm) has been mostly ignored because of water absorption and the absence of sensitive detectors and ultrafast lasers. With the advent of new technology, use of window IV is now possible. Absorption and scattering properties of light through breast and prostate cancer, bone, lipids, and intralipid solutions at these windows were investigated. We found that breast and prostate cancer and bone have longer total attenuation lengths at NIR windows III and IV, whereas fatty tissues and intralipid have longest lengths at windows II and III. Since collagen is the major chromophore at 2100 and 2350 nm, window IV could be especially valuable in evaluating cancers and boney tissues, whereas windows II and III may be more useful for tissues with high lipid content. SWIR windows may be utilized as additional optical tools for the evaluation of collagen in tissues.

Room temperature performance of mid-wavelength infrared InAsSb nBn detectors

Energy Technology Data Exchange (ETDEWEB)

Soibel, Alexander; Hill, Cory J.; Keo, Sam A.; Hoglund, Linda; Rosenberg, Robert; Kowalczyk, Robert; Khoshakhlagh, Arezou; Fisher, Anita; Ting, David Z.-Y.; Gunapala, Sarath D. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Dr., Pasadena, California 91030 (United States)

2014-07-14

In this work, we investigate the high temperature performance of mid-wavelength infrared InAsSb-AlAsSb nBn detectors with cut-off wavelengths near 4.5 μm. The quantum efficiency of these devices is 35% without antireflection coatings and does not change with temperature in the 77–325 K temperature range, indicating potential for room temperature operation. The current generation of nBn detectors shows an increase of operational bias with temperature, which is attributed to a shift in the Fermi energy level in the absorber. Analysis of the device performance shows that operational bias and quantum efficiency of these detectors can be further improved. The device dark current stays diffusion limited in the 150 K–325 K temperature range and becomes dominated by generation-recombination processes at lower temperatures. Detector detectivities are D*(λ) = 1 × 10{sup 9} (cm Hz{sup 0.5}/W) at T = 300 K and D*(λ) = 5 × 10{sup 9} (cm Hz{sup 0.5}/W) at T = 250 K, which is easily achievable with a one stage TE cooler.

Infrared studies of Seyfert galaxies and of the irregular galaxy M82

International Nuclear Information System (INIS)

Rodriguez Espinosa, J.M.

1985-01-01

Middle and far infrared studies of the irregular galaxy M82 and of Seyfert galaxies are presented. M 82 was observed spectrophotometrically from 8 to 13 microns at 6 different positions selected across its 10μm emitting region. The observations show that the mid-IR emitting region is fairly homogeneous and that similar physical processes are responsible for the emission observed throughout the central region of M82. A model is proposed to explain the 8 to 13μm spectrum of M82. A model accumulates 10 5 orion units in the central region of M82. The proposed model explains satisfactorily most of the observed properties of M82 from x-ray to radio wavelengths. It is also suggested that a similar model may be applied to other active nuclei, like the emission line galaxy NGC 1614 and the classical Seyfert 1 galaxy NGC 7469. For Seyfert galaxies, the dat analyzed are drawn from the recently released IRAS catalog. It is found that Seyfert galaxies are strong far infrared sources but, unlike the near and mid-IR emission from these sources, the far-IR emission does not appear to be produced by the active nucleus. Rather it is shown that the observed far-IR properties of Seyfert galaxies are consistent with their far-IR emission being produced in intense episodes of star formation taking place in or near the central regions of these galaxies

The initial scientific program at the NSLS infrared beamline

International Nuclear Information System (INIS)

Williams, G.P.

1989-01-01

Unique extraction optics (90 x 90 mrads) at the NSLS U4IR line offer high brightness beams at up to mm wavelengths with a ∼1ns pulse structure. Radiation from this port has now been carefully characterized and agrees well with calculations, making it 100--1000 times brighter than conventional sources in the middle and far infrared regions. Using rapid scan Michelson interferometers with liquid He cooled bolometer detectors we have been able for the first time to measure molecule substrate vibrations in surface science. We have also made the first measurements of the transmission of a film of the high Tc material YBaCuO in the BCS gap region. These initial experiments have demonstrated the advantages of the superior signal to noise available from this infrared beamline. 19 refs., 6 figs

HST/WFC3 Characteristics: gain, post-flash stability, UVIS low-sensitivity pixels, persistence, IR flats and bad pixel table

Science.gov (United States)

Gunning, Heather C.; Baggett, Sylvia; Gosmeyer, Catherine M.; Long, Knox S.; Ryan, Russell E.; MacKenty, John W.; Durbin, Meredith

2015-08-01

The Wide Field Camera 3 (WFC3) is a fourth-generation imaging instrument on the Hubble Space Telescope (HST). Installed in May 2009, WFC3 is comprised of two observational channels covering wavelengths from UV/Visible (UVIS) to infrared (IR); both have been performing well on-orbit. We discuss the gain stability of both WFC3 channel detectors from ground testing through present day. For UVIS, we detail a low-sensitivity pixel population that evolves during the time between anneals, but is largely reset by the annealing procedure. We characterize the post-flash LED lamp stability, used and recommended to mitigate CTE effects for observations with less than 12e-/pixel backgrounds. We present mitigation options for IR persistence during and after observations. Finally, we give an overview on the construction of the IR flats and provide updates on the bad pixel table.

IR spectral analysis for the diagnostics of crust earthquake precursors

Science.gov (United States)

Umarkhodgaev, R. M.; Liperovsky, V. A.; Mikhailin, V. V.; Meister, C.-V.; Naumov, D. Ju

2012-04-01

In regions of future earthquakes, a few days before the seismic shock, the emanation of radon and hydrogen is being observed, which causes clouds of increased ionisation in the atmosphere. In the present work the possible diagnostics of these clouds using infrared (IR) spectroscopy is considered, which may be important and useful for the general geophysical system of earthquake prediction and the observation of industrial emissions of radioactive materials into the atmosphere. Some possible physical processes are analysed, which cause, under the condition of additional ionisation in a pre-breakdown electrical field, emissions in the IR interval. In doing so, the transparency region of the IR spectrum at wavelengths of 7-15 μm is taken into account. This transparency region corresponds to spectral lines of small atmospheric constituents like CH4, CO2, N2O, NO2, NO, and O3. The possible intensities of the IR emissions observable in laboratories and in nature are estimated. The acceleration process of the electrons in the pre-breakdown electrical field before its adhesion to the molecules is analysed. The laboratory equipment for the investigation of the IR absorption spectrum is constructed for the cases of normal and decreased atmospheric pressures. The syntheses of ozone and nitrous oxides are performed in the barrier discharge. It is studied if the products of the syntheses may be used to model atmospheric processes where these components take part. Spectra of products of the syntheses in the wavelength region of 2-10 μm are observed and analysed. A device is created for the syntheses and accumulation of nitrous oxides. Experiments to observe the IR-spectra of ozone and nitrous oxides during the syntheses and during the further evolution of these molecules are performed. For the earthquake prediction, practically, the investigation of emission spectra is most important, but during the laboratory experiments, the radiation of the excited molecules is shifted by a

Investigation of conspicuous infrared star cluster and star-forming region RCW 38 IR Cluster

International Nuclear Information System (INIS)

Gyulbudaghian, A.L.; May, J.

2008-01-01

An infrared star cluster RCW 38 IR Cluster, which is also a massive star-forming region, is investigated. The results of observations with SEST (Cerro is Silla, Chile) telescope on 2.6-mm 12 CO spectral line and with SIMBA on 1.2-mm continuum are given. The 12 CO observations revealed the existence of several molecular clouds, two of which (clouds I and 2) are connected with the object RCW 38 IR Cluster. Cloud 1 is a massive cloud, which has a depression in which the investigated object is embedded. It is not excluded that the depression was formed by the wind and/or emission from the young bright stars belonging to the star cluster. Rotation of cloud 2, around the axis having SE-NW direction, with an angular velocity ω 4.6 · 10 -14 s -1 is also found. A red-shifted outflow with velocity ∼+5.6 km/s, in the SE direction and perpendicular to the elongation of cloud 2 has been also found. The investigated cluster is associated with an IR point source IRAS 08573-4718, which has IR colours typical for a, non-evolved embedded (in the cloud) stellar object. The cluster is also connected with a water maser. The SIMBA image shoves the existence of a central bright condensation, coinciding with the cluster itself, and two extensions. One of these extensions (the one with SW-NE direction) coincides, both in place and shape, with cloud 2, so that it is not excluded the possibility that this extension might be also rotating like cloud 2. In the vicinity of these extensions there are condensations resembling HH objects

Differentiation of Body Fluid Stains on Fabrics Using External Reflection Fourier Transform Infrared Spectroscopy (FT-IR) and Chemometrics.

Science.gov (United States)

Zapata, Félix; de la Ossa, Ma Ángeles Fernández; García-Ruiz, Carmen

2016-04-01

Body fluids are evidence of great forensic interest due to the DNA extracted from them, which allows genetic identification of people. This study focuses on the discrimination among semen, vaginal fluid, and urine stains (main fluids in sexual crimes) placed on different colored cotton fabrics by external reflection Fourier transform infrared spectroscopy (FT-IR) combined with chemometrics. Semen-vaginal fluid mixtures and potential false positive substances commonly found in daily life such as soaps, milk, juices, and lotions were also studied. Results demonstrated that the IR spectral signature obtained for each body fluid allowed its identification and the correct classification of unknown stains by means of principal component analysis (PCA) and soft independent modeling of class analogy (SIMCA). Interestingly, results proved that these IR spectra did not show any bands due to the color of the fabric and no substance of those present in daily life which were analyzed, provided a false positive. © The Author(s) 2016.

Bio-inspired, sub-wavelength surface structures for ultra-broadband, omni-directional anti-reflection in the mid and far IR.

Science.gov (United States)

Gonzalez, Federico Lora; Gordon, Michael J

2014-06-02

Quasi-ordered moth-eye arrays were fabricated in Si using a colloidal lithography method to achieve highly efficient, omni-directional transmission of mid and far infrared (IR) radiation. The effect of structure height and aspect ratio on transmittance and scattering was explored experimentally and modeled quantitatively using effective medium theory. The highest aspect ratio structures (AR = 9.4) achieved peak transmittance of 98%, with >85% transmission for λ = 7-30 μm. A detailed photon balance was constructed by measuring transmission, forward scattering, specular reflection and diffuse reflection to quantify optical losses due to near-field effects. In addition, angle-dependent transmission measurements showed that moth-eye structures provide superior anti-reflective properties compared to unstructured interfaces over a wide angular range (0-60° incidence). The colloidal lithography method presented here is scalable and substrate-independent, providing a general approach to realize moth-eye structures and anti-reflection in many IR-compatible material systems.

Robust infrared-shielding coating films prepared using perhydropolysilazane and hydrophobized indium tin oxide nanoparticles with tuned surface plasmon resonance.

Science.gov (United States)

Katagiri, Kiyofumi; Takabatake, Ryuichi; Inumaru, Kei

2013-10-23

Robust infrared (IR)-shielding coating films were prepared by dispersing indium tin oxide (ITO) nanoparticles (NPs) in a silica matrix. Hydrophobized ITO NPs were synthesized via a liquid phase process. The surface plasmon resonance (SPR) absorption of the ITO NPs could be tuned by varying the concentration of Sn doping from 3 to 30 mol %. The shortest SPR wavelength and strongest SPR absorption were obtained for the ITO NPs doped with 10% Sn because they possessed the highest electron carrier density. Coating films composed of a continuous silica matrix homogeneously dispersed with ITO NPs were obtained using perhydropolysilazane (PHPS) as a precursor. PHPS was completely converted to silica by exposure to the vapor from aqueous ammonia at 50 °C. The prepared coating films can efficiently shield IR radiation even though they are more than 80% transparent in the visible range. The coating film with the greatest IR-shielding ability completely blocked IR light at wavelengths longer than 1400 nm. The pencil hardness of this coating film was 9H at a load of 750 g, which is sufficiently robust for applications such as automotive glass.

Applications of FT-IR spectrophotometry in cancer diagnostics.

Science.gov (United States)

Bunaciu, Andrei A; Hoang, Vu Dang; Aboul-Enein, Hassan Y

2015-01-01

This review provides a brief background to the application of infrared spectroscopy, including Fourier transform-infrared spectroscopy, in biological fluids. It is not meant to be complete or exhaustive but to provide the reader with sufficient background for selected applications in cancer diagnostics. Fourier transform-infrared spectroscopy (FT-IR) is a fast and nondestructive analytical method. The infrared spectrum of a mixture serves as the basis to quantitate its constituents, and a number of common clinical chemistry tests have proven to be feasible using this approach. This review focuses on biomedical FT-IR applications, published in the period 2009-2013, used for early detection of cancer through qualitative and quantitative analysis.

Uncooled infrared photodetectors in Poland

Science.gov (United States)

Piotrowski, J.; Piotrowski, A.

2006-03-01

The history and present status of the middle and long wavelength Hg1-xCdxTe infrared detectors in Poland are reviewed. Research and development efforts in Poland were concentrated mostly on uncooled market niche. Technology of the infrared photodetectors has been developed by several research groups. The devices are based on mercury-based variable band gap semiconductor alloys. Modified isothermal vapour phase epitaxy (ISOVPE) has been used for many years for research and commercial fabrication of photoconductive, photoelectromagnetic and other devices. Bulk growth and liquid phase epitaxy was also used. At present, the fabrication of IR devices relies on low temperature epitaxial technique, namely metalorganic vapour phase deposition (MOCVD), frequently in combination with the ISOVPE. Photoconductive and photoelectromagnetic detectors are still in production. The devices are gradually replaced with photovoltaic devices which offer inherent advantages of no electric or magnetic bias, no heat load and no flicker noise. Potentially, the PV devices could offer high performance and very fast response. At present, the uncooled long wavelength devices of conventional design suffer from two issues; namely low quantum efficiency and very low junction resistance. It makes them useless for practical applications. The problems have been solved with advanced 3D band gap engineered architecture, multiple cell heterojunction devices connected in series, monolithic integration of the detectors with microoptics and other improvements. Present fabrication program includes devices which are optimized for operation at any wavelength within a wide spectral range 1-15 μm and 200-300 K temperature range. Special solutions have been applied to improve speed of response. Some devices show picoseconds range response time. The devices have found numerous civilian and military applications.

MicrOmega IR: a new infrared hyperspectral imaging microscope or in situ analysis

Science.gov (United States)

Vaitua, Leroi; Bibring, Jean-Pierre; Berthé, Michel

2017-11-01

MicrOmega IR is an ultra miniaturized Near Infrared hyperspectral microscope for in situ analysis of samples. It is designed to be implemented on board space planetary vehicles (lander and/or rovers). It acquires images of samples typically some 5 mm in width with a spatial sampling of 20 μm. On each pixel, MicrOmega acquires the spectrum in the spectral range 0.9 - 2.6 μm, with a possibility to extend the sensibility up to 4 μm. The spectrum will be measured in up to 300 contiguous spectral channels (600 in the extended range): given the diagnostic spectral features present in this domain, it provides the composition of each spatially resolved constituent. MicrOmega has thus the potential to identify: minerals, such as pyroxene and olivine, ferric oxides, hydrated phases such as phyllosilicates, sulfates and carbonates, ices and organics. The composition of the various phases within a given sample is a critical record of its formation and evolution. Coupled to the mapping information, it provides unique clues to describe the history of the parent body. In particular, the capability to identify hydrated grains and to characterize their adjacent phases has a huge potential in the search for potential bio-relics in Martian samples. This purely non destructive characterization enables further analyses (e.g. through mass spectrometry) to be performed, and/or to contribute to sample selection to return to Earth. MicrOmega IR is coupled to a visible microscope: MicrOmega VIS. Thus, the MicrOmega instrument is developed by an international consortium: IAS (Orsay, France), LESIA (Meudon, France), CBM (Orléans, France), University Of Bern (Bern, Switzerland), IKI (Moscow, Russia). This instrument (MicrOmega IR, MicrOmega VIS and the electronics) is selected for the ESA Exomars mission (launch scheduled for 2013). MicrOmega IR will be used in a reduced spectral range (0.9 - 2.6 μm), due to power, mass and thermal constraints: however, most minerals and other

The nature of OH/IR stars

International Nuclear Information System (INIS)

Herman, J.

1983-01-01

In this work masers in evolved stars are studied, in particular the emission from the OH radical. The time variability of the OH masers was measured over a period of five years with the Dwingeloo Radio Telescope. These single-dish observations proved that most of the underlying stars are very long period variables, apparently a kind of extension of the well-known long period Mira variables. The mean OH fluxes and epochs were obtained as well as a confirmation of the radiative coupling between the maser and the star (by comparison with infrared data provided by other observers), the degree of saturation, and, most important of all, a determination of the linear dimensions of the circumstellar shells. Multi-element interferometer observations were made in order to study the spatial structure of OH masers. By combining the phase lag measurements and the spatial extent distances to individual stars could be determined with a high, unprecedented accuracy. Infrared broad-band photometry was done in the wavelength region from 3 μm to 20 μm, where most of the energy of these objects is radiated. The space density and galactic distribution of OH/IR stars are discussed and compared with the appearance of OH masers in the solar neighbourhood. (Auth.)

Infrared and visible laser spectroscopy for highly-charged Ni-like ions

Science.gov (United States)

Ralchenko, Yuri

2017-10-01

Application of visible or infrared (IR) lasers for spectroscopy of highly-charged ions (HCI) has not been particularly extensive so far due to a mismatch in typical energies. We show here that the energy difference between the two lowest levels within the first excited configuration 3d9 4 s in Ni-like ions of heavy elements from ZN = 60 to ZN = 92 is within the range of visible or near-IR lasers. The wavelengths of these transitions are calculated within the relativistic model potential formalism and compared with other theoretical and limited experimental data. Detailed collisional-radiative simulations of non-Maxwellian and thermal plasmas are performed showing that photopumping between these levels using relatively moderate lasers is sufficient to provide a two-order of magnitude increase of the pumped level population. This accordingly results in a similar rise of the X-ray line intensity thereby allowing control of X-ray emission with visible/IR lasers.

Investigation of radiant millimeter wave/terahertz radiation from low-infrared signature targets

Science.gov (United States)

Aytaç, B.; Alkuş, Ü.; Sivaslıgil, M.; Şahin, A. B.; Altan, H.

2017-10-01

Millimeter (mm) and sub-mm wave radiation is increasingly becoming a region of interest as better methods are developed to detect in this wavelength range. The development of sensitive focal plane array (FPA) architectures as well as single pixel scanners has opened up a new field of passive detection and imaging. Spectral signatures of objects, a long standing area of interest in the Short Wave Infrared (SWIR), Mid-Wave (MWIR) and Long Wave-IR (LWIR) bands can now be assessed in the mm-wave/terahertz (THz) region. The advantage is that this form of radiation is not as adversely affected by poor atmospheric conditions compared to other bands. In this study, a preliminary experiment in a laboratory environment is performed to assess the radiance from targets with low infrared signatures in the millimeter wave/terahertz (THz) band (<1 THz). The goal of this approach is to be able to model the experimental results to better understand the mm-wave/THz signature of targets with low observability in the IR bands.

Micro and Nano Electromechanical Systems for Near-Zero Power Infrared Detection

Science.gov (United States)

Qian, Zhenyun

Light is one of the most important tools for human beings to probe and sense the physical world. Infrared (IR) radiation located in longer wavelengths than those of visible light carries rich information of an environment as it reveals the temperature distribution and chemical composition of objects. In addition, it has been utilized for communication and distance measurement owing to the atmospheric window and insensitiveness of human eyes to the IR radiation. As a result, IR detectors nowadays can be found in a wide variety of applications, including thermal imaging, automotive night vision, standoff chemical detection, remote control and laser ranging, just to mention a few. On the other hand, due to the recent fast development of the Internet of Things (IoT), there is a growing demand for miniaturized and power efficient unattended sensors that can be widely distributed in large volumes to form a wireless sensor networks capable of monitoring the environment with high accuracy and long lifetime. In this context, micro and nano electromechanical systems (MEMS/NEMS) may provide a huge impact, since they can be used for the implementation of miniaturized, low power, high-performance sensors and wireless communication devices fully compatible with standard integrated circuitry. This dissertation presents the design and the experimental verification of high performance uncooled IR detectors based on Aluminum Nitride (AlN) nano electromechanical resonators, and a first-of-its-kind near-zero power IR digitizer based on plasmonically-enhanced micromechanical photoswitches. The unique advantages of the piezoelectric AlN thin film in terms of scaling in thickness and transduction efficiency are exploited by the first experimental demonstration of ultra-fast (thermal time constant, tau ˜ 80 mus) and high resolution (noise equivalent power, NEP ˜ 656 pW/Hz1/2) AlN NEMS resonant IR detectors with reduced pixel size comparable to the state-of-the-art microbolometers

The role of near infrared radiation in photoaging of the skin.

Science.gov (United States)

Schroeder, Peter; Haendeler, Judith; Krutmann, Jean

2008-07-01

Infrared (IR) radiation is non-ionizing, electromagnetic radiation with wavelengths between 760 nm and 1 mm, which is further divided into IRA, IRB and IRC. IR accounts for more than half of the solar energy that reaches the human skin. While IRB and IRC do not penetrate deeply into the skin, more than 65% of IRA reaches the dermis. Human skin is increasingly exposed to IRA-radiation; most relevant sources are (i) natural solar radiation consisting of over 30% IRA, (ii) artificial IRA sources used for therapeutic or wellness purposes and (iii) artificial UV sources contaminated with IRA. As part of natural sunlight, IRA significantly contributes to extrinsic skin aging. This article reviews the cutaneous effects of IRA-radiation, the underlying molecular mechanisms and the available protective strategies.

Radioluminescence dating: the IR emission of feldspar

International Nuclear Information System (INIS)

Schilles, Thomas.; Habermann, Jan

2000-01-01

A new luminescence reader for radioluminescence (RL) measurements is presented. The system allows detection of RL emissions in the near infrared region (IR). Basic bleaching properties of the IR-RL emission of feldspars are investigated. Sunlight-bleaching experiments as a test for sensitivity changes are presented. IR-bleaching experiments were carried out to obtain information about the underlying physical processes of the IR-RL emission

Optical properties of wet paper and simulation of the effect of autoprofiling on gas-fired IR drying

Energy Technology Data Exchange (ETDEWEB)

Ojala, K T; Lampinen, M J

1991-01-01

We have developed new models to determine the radiative heat transfer of gas-fired infrared dryers. A computer program based on the mathematical models is developed further. This program is used for studying the autoprofiling effect in gas-fired infrared drying. Optical properties of paper samples of different moisture contents as a function of wavelength are systematically measured by using FT-lR specrometer and integraing sphere techniques. These measurements covered the moisture content range of 6- 150 %. A new wavelength range (1.2- 1.9 mm), not properly covered by our earlier measurements, is measured by using a liquid nitrogen cooled detector. The total measured wavelength range is 1.0-20.0 mm. The moisture dependence of the optical properties of coating are calculated by using a theoretical model developed in State Research Centre of Finland, Laboratory of Optoelectronics. The radiation properties of component surfaces of the IR dryer were either measured or taken from literature. The mathematical models are based on the calculation of radiation energy balance between the main surfaces and layers in the dryer section. The energy efficiency can be calculated, when the temperatures of the radiator and the optical properties of all parts of the dryer are known. A computer program based on the models is developed further. The dryer efficiency as a function of the moisture content of paper is calculated. The extent of the autoprofiling effect in gas-fired IR drying is hereby achieved for light weight coated paper web. If the variation in moisture contents is high, the autoprofiling effect takes place and reduces the moisture variation. However, if the moisture variation is low, it is not a very significant phenomenon. The simulation results are compared to a pilot coater trial made in Cenre Technique du Papier, Grenoble.

Visible to near-IR fluorescence from single-digit detonation nanodiamonds: excitation wavelength and pH dependence.

Science.gov (United States)

Reineck, Philipp; Lau, Desmond W M; Wilson, Emma R; Nunn, Nicholas; Shenderova, Olga A; Gibson, Brant C

2018-02-06

Detonation nanodiamonds are of vital significance to many areas of science and technology. However, their fluorescence properties have rarely been explored for applications and remain poorly understood. We demonstrate significant fluorescence from the visible to near-infrared spectral regions from deaggregated, single-digit detonation nanodiamonds dispersed in water produced via post-synthesis oxidation. The excitation wavelength dependence of this fluorescence is analyzed in the spectral region from 400 nm to 700 nm as well as the particles' absorption characteristics. We report a strong pH dependence of the fluorescence and compare our results to the pH dependent fluorescence of aromatic hydrocarbons. Our results significantly contribute to the current understanding of the fluorescence of carbon-based nanomaterials in general and detonation nanodiamonds in particular.

Analysis of the development of missile-borne IR imaging detecting technologies

Science.gov (United States)

Fan, Jinxiang; Wang, Feng

2017-10-01

Today's infrared imaging guiding missiles are facing many challenges. With the development of targets' stealth, new-style IR countermeasures and penetrating technologies as well as the complexity of the operational environments, infrared imaging guiding missiles must meet the higher requirements of efficient target detection, capability of anti-interference and anti-jamming and the operational adaptability in complex, dynamic operating environments. Missileborne infrared imaging detecting systems are constrained by practical considerations like cost, size, weight and power (SWaP), and lifecycle requirements. Future-generation infrared imaging guiding missiles need to be resilient to changing operating environments and capable of doing more with fewer resources. Advanced IR imaging detecting and information exploring technologies are the key technologies that affect the future direction of IR imaging guidance missiles. Infrared imaging detecting and information exploring technologies research will support the development of more robust and efficient missile-borne infrared imaging detecting systems. Novelty IR imaging technologies, such as Infrared adaptive spectral imaging, are the key to effectively detect, recognize and track target under the complicated operating and countermeasures environments. Innovative information exploring techniques for the information of target, background and countermeasures provided by the detection system is the base for missile to recognize target and counter interference, jamming and countermeasure. Modular hardware and software development is the enabler for implementing multi-purpose, multi-function solutions. Uncooled IRFPA detectors and High-operating temperature IRFPA detectors as well as commercial-off-the-shelf (COTS) technology will support the implementing of low-cost infrared imaging guiding missiles. In this paper, the current status and features of missile-borne IR imaging detecting technologies are summarized. The key

Ge-rich graded-index Si1-xGex devices for MID-IR integrated photonics

Science.gov (United States)

Ramirez, J. M.; Vakarin, V.; Liu, Q.; Frigerio, J.; Ballabio, A.; Le Roux, X.; Benedikovic, D.; Alonso-Ramos, C.; Isella, G.; Vivien, L.; Marris-Morini, D.

2018-02-01

Mid-infrared (mid-IR) silicon photonics is becoming a prominent research with remarkable potential in several applications such as in early medical diagnosis, safe communications, imaging, food safety and many more. In the quest for the best material platform to develop new photonic systems, Si and Ge depart with a notable advantage over other materials due to the high processing maturity accomplished during the last part of the 20th century through the deployment of the CMOS technology. From an optical viewpoint, combining Si with Ge to obtain SiGe alloys with controlled stoichiometry is also of interest for the photonic community since permits to increase the effective refractive index and the nonlinear parameter, providing a fascinating playground to exploit nonlinear effects. Furthermore, using Ge-rich SiGe gives access to a range of deep mid-IR wavelengths otherwise inaccessible (λ 2-20 μm). In this paper, we explore for the first time the limits of this approach by measuring the spectral loss characteristic over a broadband wavelength range spanning from λ = 5.5 μm to 8.5 μm. Three different SiGe waveguide platforms are compared, each one showing higher compactness than the preceding through the engineering of the vertical Ge profile, giving rise to different confinement characteristics to the propagating modes. A flat propagation loss characteristic of 2-3 dB/cm over the entire wavelength span is demonstrated in Ge-rich graded-index SiGe waveguides of only 6 μm thick. Also, the role of the overlap fraction of the confined optical mode with the Si-rich area at the bottom side of the epitaxial SiGe waveguide is put in perspective, revealing a lossy characteristic compared to the other designs were the optical mode is located in the Ge-rich area at the top of the waveguide uniquely. These Ge-rich graded-index SiGe waveguides may pave the way towards a new generation of photonic integrated circuits operating at deep mid-IR wavelengths.

Classification and structural analysis of live and dead salmonella cells using fourier transform infrared (FT-IR) spectroscopy and principle component analysis (PCA)

Science.gov (United States)

Fourier Transform Infrared Spectroscopy (FT-IR) was used to detect Salmonella typhimurium and Salmonella enteritidis foodborne bacteria and distinguish between live and dead cells of both serotypes. Bacteria were loaded individually on the ZnSe Attenuated Total Reflection (ATR) crystal surface and s...

THE EFFICIENCY AND WAVELENGTH DEPENDENCE OF NEAR-INFRARED INTERSTELLAR POLARIZATION TOWARD THE GALACTIC CENTER

Energy Technology Data Exchange (ETDEWEB)

Hatano, Hirofumi; Kurita, Mikio; Kanai, Saori; Sato, Shuji [Department of Astrophysics, Nagoya University, Chikusa-ku, Nagoya 464-8602 (Japan); Nishiyama, Shogo; Nakajima, Yasushi; Tamura, Motohide; Kandori, Ryo [National Astronomical Observatory of Japan, Mitaka, Tokyo 181-8858 (Japan); Nagata, Tetsuya; Yoshikawa, Tatsuhito [Department of Astronomy, Kyoto University, Sakyo-ku, Kyoto 606-8502 (Japan); Kato, Daisuke [Department of Astronomy, School of Science, University of Tokyo, Bunkyo-ku, Tokyo 113-0033 (Japan); Sato, Yaeko; Suenaga, Takuya, E-mail: hattan@z.phys.nagoya-u.ac.jp, E-mail: shogo.nishiyama@nao.ac.jp [Department of Astronomical Sciences, Graduate University for Advanced Studies (Sokendai), Mitaka, Tokyo 181-8858 (Japan)

2013-04-15

Near-infrared polarimetric imaging observations toward the Galactic center (GC) have been carried out to examine the efficiency and wavelength dependence of interstellar polarization. A total area of about 5.7 deg{sup 2} is covered in the J, H, and K{sub S} bands. We examined the polarization efficiency, defined as the ratio of the degree of polarization to color excess. The interstellar medium between the GC and us shows a polarization efficiency lower than that in the Galactic disk by a factor of three. Moreover we investigated the spatial variation of the polarization efficiency by comparing it with that of the color excess, degree of polarization, and position angle. The spatial variations of color excess and degree of polarization depend on the Galactic latitude, while the polarization efficiency varies independently of the Galactic structure. Position angles are nearly parallel to the Galactic plane, indicating a longitudinal magnetic field configuration between the GC and us. The polarization efficiency anticorrelates with dispersions of position angles. The low polarization efficiency and its spatial variation can be explained by the differences in the magnetic field directions along the line of sight. From the lower polarization efficiency, we suggest a higher strength of a random component relative to a uniform component of the magnetic field between the GC and us. We also derived the ratios of degree of polarization p{sub H} /p{sub J} = 0.581 {+-} 0.004 and p{sub K{sub S}}/p{sub H} = 0.620 {+-} 0.002. The power-law indices of the wavelength dependence of polarization are {beta}{sub JH} = 2.08 {+-} 0.02 and {beta}{sub HK{sub S}} = 1.76 {+-} 0.01. Therefore, the wavelength dependence of interstellar polarization exhibits flattening toward longer wavelengths in the range of 1.25-2.14 {mu}m. The flattening would be caused by aligned large-size dust grains.

Thermally Resilient, Broadband Optical Absorber from UV to IR Derived from Carbon Nanostructures

Science.gov (United States)

Kaul, Anupama B.; Coles, James B.

2012-01-01

Optical absorber coatings have been developed from carbon-based paints, metal blacks, or glassy carbon. However, such materials are not truly black and have poor absorption characteristics at longer wavelengths. The blackness of such coatings is important to increase the accuracy of calibration targets used in radiometric imaging spectrometers since blackbody cavities are prohibitively large in size. Such coatings are also useful potentially for thermal detectors, where a broadband absorber is desired. Au-black has been a commonly used broadband optical absorber, but it is very fragile and can easily be damaged by heat and mechanical vibration. An optically efficient, thermally rugged absorber could also be beneficial for thermal solar cell applications for energy harnessing, particularly in the 350-2,500 nm spectral window. It has been demonstrated that arrays of vertically oriented carbon nanotubes (CNTs), specifically multi-walled-carbon- nanotubes (MWCNTs), are an exceptional optical absorber over a broad range of wavelengths well into the infrared (IR). The reflectance of such arrays is 100x lower compared to conventional black materials, such as Au black in the spectral window of 350-2,500 nm. Total hemispherical measurements revealed a reflectance of approximately equal to 1.7% at lambda approximately equal to 1 micrometer, and at longer wavelengths into the infrared (IR), the specular reflectance was approximately equal to 2.4% at lambda approximately equal to 7 micrometers. The previously synthesized CNTs for optical absorber applications were formed using water-assisted thermal chemical vapor deposition (CVD), which yields CNT lengths in excess of 100's of microns. Vertical alignment, deemed to be a critical feature in enabling the high optical absorption from CNT arrays, occurs primarily via the crowding effect with thermal CVD synthesized CNTs, which is generally not effective in aligning CNTs with lengths less than 10 m. Here it has been shown that the

The "+" for CRIRES: enabling better science at infrared wavelength and high spectral resolution at the ESO VLT

Science.gov (United States)

Dorn, Reinhold J.; Follert, Roman; Bristow, Paul; Cumani, Claudio; Eschbaumer, Siegfried; Grunhut, Jason; Haimerl, Andreas; Hatzes, Artie; Heiter, Ulrike; Hinterschuster, Renate; Ives, Derek J.; Jung, Yves; Kerber, Florian; Klein, Barbara; Lavaila, Alexis; Lizon, Jean Louis; Löwinger, Tom; Molina-Conde, Ignacio; Nicholson, Belinda; Marquart, Thomas; Oliva, Ernesto; Origlia, Livia; Pasquini, Luca; Paufique, Jérôme; Piskunov, Nikolai; Reiners, Ansgar; Seemann, Ulf; Stegmeier, Jörg; Stempels, Eric; Tordo, Sebastien

2016-08-01

The adaptive optics (AO) assisted CRIRES instrument is an IR (0.92 - 5.2 μm) high-resolution spectrograph was in operation from 2006 to 2014 at the Very Large Telescope (VLT) observatory. CRIRES was a unique instrument, accessing a parameter space (wavelength range and spectral resolution) up to now largely uncharted. It consisted of a single-order spectrograph providing long-slit (40 arcsecond) spectroscopy with a resolving power up to R=100 000. However the setup was limited to a narrow, single-shot, spectral range of about 1/70 of the central wavelength, resulting in low observing efficiency for many scientific programmes requiring a broad spectral coverage. The CRIRES upgrade project, CRIRES+, transforms this VLT instrument into a cross-dispersed spectrograph to increase the simultaneously covered wavelength range by a factor of ten. A new and larger detector focal plane array of three Hawaii 2RG detectors with 5.3 μm cut-off wavelength will replace the existing detectors. For advanced wavelength calibration, custom-made absorption gas cells and an etalon system will be added. A spectro-polarimetric unit will allow the recording of circular and linear polarized spectra. This upgrade will be supported by dedicated data reduction software allowing the community to take full advantage of the new capabilities offered by CRIRES+. CRIRES+ has now entered its assembly and integration phase and will return with all new capabilities by the beginning of 2018 to the Very Large Telescope in Chile. This article will provide the reader with an update of the current status of the instrument as well as the remaining steps until final installation at the Paranal Observatory.

Laser cleaning of parchment: structural, thermal and biochemical studies into the effect of wavelength and fluence

International Nuclear Information System (INIS)

Kennedy, Craig J.; Vest, Marie; Cooper, Martin; Wess, Tim J.

2004-01-01

Laser cleaning of parchment is a novel technique that has the potential to provide contactless, chemical-free cleaning of historically important documents. However, the effect of laser cleaning on the collagenous structure of parchment is still poorly understood, as is the effect of the wavelength or the energy density (fluence level) used to clean parchment. In this study, small angle X-ray scattering (SAXS), shrinkage temperature (Ts) measurements by the micro hot table technique and SDS-polyacrylamide gel electrophoresis (SDS-PAGE) of parchment samples after laser cleaning reveal the effect of cleaning to the structural, thermal and molecular characteristics of parchment, respectively. The effect of cleaning at infrared (1064 nm), green (532 nm) and ultraviolet (266 nm) wavelengths at a range of fluence levels is investigated. SAXS is used to investigate the removal of dirt from parchment. Laser cleaning at IR or green wavelengths appears not to alter the collagen diffraction pattern from SAXS, the shrinkage activity or shrinkage temperature from Ts measurements or the molecular integrity of parchment as shown by SDS-PAGE. However, parchments cleaned at the ultraviolet wavelength display structural damage and a reduction in hydrothermal stability and molecular integrity

IR detectors for the Infrared Atmospheric Sounding Interferometer (IASI) instrument payload for the METOP-1 ESA polar platform

Science.gov (United States)

Royer, Michel; Lorans, Dominique; Bischoff, Isabelle; Giotta, Dominique; Wolny, Michel

1994-12-01

IASI is an Infrared Atmospheric Sounding Interferometer devoted to the operational meteorology and to atmospheric studies and is to be installed on board the second ESA Polar Platform called METOP-1, planned to be launched in the year 2000. The main purpose of this high performance instrument is to record temperature and humidity profiles. The required lifetime is 4 years. This paper presents the characteristics of the LW IR detection arrays for the IASI spectrometer which consist of HgCdTe de- tectors. SAT has to develop the Engineering Model, Qualification Model and Fight Models of detectors, each having 4 pixels and AR-coated microlenses in a dedicated space housing equipped with a flexible line and a connector. An array is composed of HgCdTe photoconductive detectors. For this long wavelength the array is sensitive from 8.26 micrometers to 15.5 micrometers . The detectors, with sensitive areas of 900 x 900 micrometers 2, are 100 K operating with passive cooling. High quality HgCdTe material is a key feature for the manufacturing of high performance photoconductive detectors. Therefore epitaxial HgCdTe layers are used in this project. These epilayers are grown at CEA/LETI on lattice matched CdZnTe substrates, by Te-rich liquid phase epitaxy, based on a slider technique. The Cd content in the layer is carefully adjusted to meet the required cut off wavelength on the devices. After growth of the epilayers, the samples are annealed under Hg pressure in order to convert them into N type mate- rials. The electrical transport properties of the liquid phase epitaxied wafers are, at 100 K, mobility (mu) over 150,000 cm2/V.s and electrical concentration N of 1.5 1015 cm-3, the residual doping level being 1014 cm-3 at low temperature. On these materials the feasibility study of long wavelength HgCdTe photoconductors has been achieved with the following results: the responsivity is 330 V/W. The bias voltage is Vp=300 mV for a 4 mW limitation of power for each element. The

ICP etching for InAs-based InAs/GaAsSb superlattice long wavelength infrared detectors

Science.gov (United States)

Huang, Min; Chen, Jianxin; Xu, Jiajia; Wang, Fangfang; Xu, Zhicheng; He, Li

2018-05-01

In this work, we study and report the dry etching processes for InAs-based InAs/GaAsSb strain-free superlattice long wavelength infrared (LWIR) detectors. The proper etching parameters were first obtained through the parametric studies of Inductively Coupled Plasma (ICP) etching of both InAs and GaSb bulk materials in Cl2/N2 plasmas. Then an InAs-based InAs/GaAsSb superlattice LWIR detector with PπN structure was fabricated by using the optimized etching parameters. At 80 K, the detector exhibits a 100% cut-off wavelength of 12 μm and a responsivity of 1.5 A/W. Moreover, the dark current density of the device under a bias of -200 mV reaches 5.5 × 10-4 A/cm2, and the R0A is 15 Ω cm2. Our results pave the way towards InAs-based superlattice LWIR detectors with better performances.

Thulium pumped mid-infrared 0.9–9μm supercontinuum generation in concatenated fluoride and chalcogenide glass fibers

DEFF Research Database (Denmark)

Kubat, Irnis; Petersen, Christian Rosenberg; Møller, Uffe Visbech

2014-01-01

of ZBLAN spanning the 0.9–4.1μm SC at the −30dB level. The ZBLAN fiber SC is then coupled into 10cm of As2Se3 chalcogenide Microstructured Optical Fiber (MOF) designed to have a zero-dispersion wavelength (λZDW) significantly below the 4.1μm InfraRed (IR) edge of the ZBLAN fiber SC, here 3.55μm...

ANALYTICAL MODEL OF A DIFFERENTIAL METHOD FOR RECEIVING AND PROCESSING SIGNALS OF THE INFRARED RANGE OF WAVELENGTHS

Directory of Open Access Journals (Sweden)

N. S. Akinshin

2017-01-01

Full Text Available One of the classic methods to improve the noise immunity of passive detection of infrared wavelength range (IKSO is a differential inclusion of pyrocatechol, placed at some distance. An analytical model of a differential method of receiving infrared radiation from moving objects is introduced. A comparison with experimental results for moving objects of different types is made. Differential inclusion of sensors can be used not only to compensate the external interference, but also to determine the boundaries of a temporary "slot", inside which the movable object is most likely to be detected. The temporal boundaries are used for the decision making about the type and parameters of the movable object in complexional device of object classification.The principle of operation of ikso, which is to record signals with diversity of pyrocatechol into the appropriate memory registers and output detection of the differential signal envelope. Subsequently, from the memory registers portions of a recording signal posted pyrocatechol are selected which are later processed to determine the temporal provisions of minimum minimore and maximum maximore. The direction of movement of the object abeam is determined by the delay or advance of the extrema of the signals of one sensor relative to another within a given temporal "slot".It is shown that aggregation should be the following – the tool with a maximum radius of the zone of sensitivity should be active and the basic, but if there is a more reliable piece of information about the detected object which can implement a more refined classification of the object (for example, a group of people, wheeled vehicles-tracked vehicles, etc.. The conclusion is made about the advantages of differential option to include spaced sensors.The results can be used in the development of infrared wavelengths passive detection in the conceptual design phase.

Very large scale heterogeneous integration (VLSHI) and wafer-level vacuum packaging for infrared bolometer focal plane arrays

Science.gov (United States)

Forsberg, Fredrik; Roxhed, Niclas; Fischer, Andreas C.; Samel, Björn; Ericsson, Per; Hoivik, Nils; Lapadatu, Adriana; Bring, Martin; Kittilsland, Gjermund; Stemme, Göran; Niklaus, Frank

2013-09-01

Imaging in the long wavelength infrared (LWIR) range from 8 to 14 μm is an extremely useful tool for non-contact measurement and imaging of temperature in many industrial, automotive and security applications. However, the cost of the infrared (IR) imaging components has to be significantly reduced to make IR imaging a viable technology for many cost-sensitive applications. This paper demonstrates new and improved fabrication and packaging technologies for next-generation IR imaging detectors based on uncooled IR bolometer focal plane arrays. The proposed technologies include very large scale heterogeneous integration for combining high-performance, SiGe quantum-well bolometers with electronic integrated read-out circuits and CMOS compatible wafer-level vacuum packing. The fabrication and characterization of bolometers with a pitch of 25 μm × 25 μm that are arranged on read-out-wafers in arrays with 320 × 240 pixels are presented. The bolometers contain a multi-layer quantum well SiGe thermistor with a temperature coefficient of resistance of -3.0%/K. The proposed CMOS compatible wafer-level vacuum packaging technology uses Cu-Sn solid-liquid interdiffusion (SLID) bonding. The presented technologies are suitable for implementation in cost-efficient fabless business models with the potential to bring about the cost reduction needed to enable low-cost IR imaging products for industrial, security and automotive applications.

The near-infrared radius-luminosity relationship for active galactic nuclei

Science.gov (United States)

Landt, Hermine; Bentz, Misty C.; Peterson, Bradley M.; Elvis, Martin; Ward, Martin J.; Korista, Kirk T.; Karovska, Margarita

2011-05-01

Black hole masses for samples of active galactic nuclei (AGNs) are currently estimated from single-epoch optical spectra. In particular, the size of the broad-line emitting region needed to compute the black hole mass is derived from the optical or ultraviolet continuum luminosity. Here we consider the relationship between the broad-line region size, R, and the near-infrared (near-IR) AGN continuum luminosity, L, as the near-IR continuum suffers less dust extinction than at shorter wavelengths and the prospects for separating the AGN continuum from host-galaxy starlight are better in the near-IR than in the optical. For a relationship of the form R∝Lα, we obtain for a sample of 14 reverberation-mapped AGN a best-fitting slope of α= 0.5 ± 0.1, which is consistent with the slope of the relationship in the optical band and with the value of 0.5 naïvely expected from photoionization theory. Black hole masses can then be estimated from the near-IR virial product, which is calculated using the strong and unblended Paschen broad emission lines (Paα or Paβ).

THE SPECTRAL ENERGY DISTRIBUTIONS AND INFRARED LUMINOSITIES OF z ≈ 2 DUST-OBSCURED GALAXIES FROM Herschel AND Spitzer

International Nuclear Information System (INIS)

Melbourne, J.; Soifer, B. T.; Desai, Vandana; Armus, Lee; Pope, Alexandra; Alberts, Stacey; Dey, Arjun; Jannuzi, B. T.; Bussmann, R. S.

2012-01-01

Dust-obscured galaxies (DOGs) are a subset of high-redshift (z ≈ 2) optically-faint ultra-luminous infrared galaxies (ULIRGs, e.g., L IR > 10 12 L ☉ ). We present new far-infrared photometry, at 250, 350, and 500 μm (observed-frame), from the Herschel Space Telescope for a large sample of 113 DOGs with spectroscopically measured redshifts. Approximately 60% of the sample are detected in the far-IR. The Herschel photometry allows the first robust determinations of the total infrared luminosities of a large sample of DOGs, confirming their high IR luminosities, which range from 10 11.6 L ☉ IR (8-1000 μm) 13.6 L ☉ . 90% of the Herschel-detected DOGs in this sample are ULIRGs and 30% have L IR > 10 13 L ☉ . The rest-frame near-IR (1-3 μm) spectral energy distributions (SEDs) of the Herschel-detected DOGs are predictors of their SEDs at longer wavelengths. DOGs with 'power-law' SEDs in the rest-frame near-IR show observed-frame 250/24 μm flux density ratios similar to the QSO-like local ULIRG, Mrk 231. DOGs with a stellar 'bump' in their rest-frame near-IR show observed-frame 250/24 μm flux density ratios similar to local star-bursting ULIRGs like NGC 6240. None show 250/24 μm flux density ratios similar to extreme local ULIRG, Arp 220; though three show 350/24 μm flux density ratios similar to Arp 220. For the Herschel-detected DOGs, accurate estimates (within ∼25%) of total IR luminosity can be predicted from their rest-frame mid-IR data alone (e.g., from Spitzer observed-frame 24 μm luminosities). Herschel-detected DOGs tend to have a high ratio of infrared luminosity to rest-frame 8 μm luminosity (the IR8 = L IR (8-1000 μm)/νL ν (8 μm) parameter of Elbaz et al.). Instead of lying on the z = 1-2 'infrared main sequence' of star-forming galaxies (like typical LIRGs and ULIRGs at those epochs) the DOGs, especially large fractions of the bump sources, tend to lie in the starburst sequence. While, Herschel-detected DOGs are similar to scaled up

Application of fourier-transform infrared (ft-ir) spectroscopy for determination of total phenolics of freeze dried lemon juices

International Nuclear Information System (INIS)

Sherazi, S.T.H.; Bhutto, A.A.; Mehesar, S.A.

2017-01-01

A cost effective and environmentally safe analytical method for rapid assessment of total phenolic content (TPC) in freeze dried lemon juice samples was developed using transmission Fourier-transform infrared spectroscopy (FT-IR) in conjunction with chemometric techniques. Two types of calibrations i.e. simple Beer's law and partial least square (PLS) were applied to investigate most accurate calibration model based on region from1420 to 1330 cm-1. The better analytical performance was obtained by PLS technique coefficient of determination (R2), root mean square error of calibration (RMSEC) with the value of 0.999 and 0.00864, respectively. The results of TPC in freeze dried lemon juice samples obtained by transmission FT-IR were compared with TPC observed by Folin-Ciocalteu (FC) assay and found to be comparable. Outcomes of the present study indicate that transmission FT-IR spectroscopic approach could be used as an alternative approach in place of Folin-Ciocalteu (FC) assay which is expensive and time-consuming conventional chemical methods for determination of the total phenolic content of lemon fruits. (author)

THE IMPLICATIONS OF M DWARF FLARES ON THE DETECTION AND CHARACTERIZATION OF EXOPLANETS AT INFRARED WAVELENGTHS

International Nuclear Information System (INIS)

Tofflemire, Benjamin M.; Wisniewski, John P.; Kowalski, Adam F.; Schmidt, Sarah J.; Kundurthy, Praveen; Hilton, Eric J.; Hawley, Suzanne L.; Holtzman, Jon A.

2012-01-01

We present the results of an observational campaign which obtained high-cadence, high-precision, simultaneous optical and IR photometric observations of three M dwarf flare stars for 47 hr. The campaign was designed to characterize the behavior of energetic flare events, which routinely occur on M dwarfs, at IR wavelengths to millimagnitude precision, and quantify to what extent such events might influence current and future efforts to detect and characterize extrasolar planets surrounding these stars. We detected and characterized four highly energetic optical flares having U-band total energies of ∼7.8 × 10 30 to ∼1.3 × 10 32 erg, and found no corresponding response in the J, H, or Ks bandpasses at the precision of our data. For active dM3e stars, we find that a ∼1.3 × 10 32 erg U-band flare (ΔU max ∼ 1.5 mag) will induce 31 erg U-band flare (ΔU max ∼ 1.6 mag) will induce <7.8 (J), <8.8 (H), and <5.1 (Ks) mmag of a response. A flare of this energy or greater should occur less than once per 10 hr. No evidence of stellar variability not associated with discrete flare events was observed at the level of ∼3.9 mmag over 1 hr timescales and at the level of ∼5.6 mmag over 7.5 hr timescales. We therefore demonstrate that most M dwarf stellar activity and flares will not influence IR detection and characterization studies of M dwarf exoplanets above the level of ∼5-11 mmag, depending on the filter and spectral type. We speculate that the most energetic megaflares on M dwarfs, which occur at rates of once per month, are likely to be easily detected in IR observations with sensitivity of tens of millimagnitudes. We also discuss how recent detections of line flux enhancements during M dwarf flares could influence IR transmission spectroscopic observations of M dwarf exoplanets.

Miniaturized multi channel infrared optical gas sensor system

Science.gov (United States)

Wöllenstein, Jürgen; Eberhardt, Andre; Rademacher, Sven; Schmitt, Katrin

2011-06-01

Infrared spectroscopy uses the characteristic absorption of the molecules in the mid infrared and allows the determination of the gases and their concentration. Especially by the absorption at longer wavelengths between 8 μm and 12 μm, the so called "fingerprint" region, the molecules can be measured with highest selectivity. We present an infrared optical filter photometer for the analytical determination of trace gases in the air. The challenge in developing the filter photometer was the construction of a multi-channel system using a novel filter wheel concept - which acts as a chopper too- in order to measure simultaneously four gases: carbon monoxide, carbon dioxide, methane and ammonia. The system consists of a broadband infrared emitter, a long path cell with 1.7m optical path length, a filter wheel and analogue and digital signal processing. Multi channel filter photometers normally need one filter and one detector per target gas. There are small detection units with one, two or more detectors with integrated filters available on the market. One filter is normally used as reference at a wavelength without any cross-sensitivities to possible interfering gases (e.g. at 3.95 μm is an "atmospheric window" - a small spectral band without absorbing gases in the atmosphere). The advantage of a filter-wheel set-up is that a single IR-detector can be used, which reduces the signal drift enormously. Pyroelectric and thermopile detectors are often integrated in these kinds of spectrometers. For both detector types a modulation of the light is required and can be done - without an additional chopper - with the filter wheel.

The continued optical to mid-infrared evolution of V838 Monocerotis

Energy Technology Data Exchange (ETDEWEB)

Loebman, S. R. [Department of Astronomy, University of Michigan, 830 Dennison, 500 Church Street, Ann Arbor, MI 48109-1042 (United States); Wisniewski, J. P. [Homer L. Dodge Department of Physics and Astronomy, The University of Oklahoma, 440 W. Brooks Street, Norman, OK 73019 (United States); Schmidt, S. J. [Department of Astronomy, Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States); Kowalski, A. F. [NASA Postdoctoral Program Fellow, NASA Goddard Space Flight Center, Code 671, Greenbelt, MD 20771 (United States); Barry, R. K. [NASA Goddard Space Flight Center, Laboratory for Exoplanets and Stellar Astrophysics, Code 667, Greenbelt, MD 20771 (United States); Bjorkman, K. S. [Ritter Observatory, MS #113, Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606-3390 (United States); Hammel, H. B. [AURA, 1212 New York Avenue NW, Suite 450, Washington, DC 20005 (United States); Hawley, S. L.; Szkody, P. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Hebb, L. [Department of Physics, Hobart and William Smith Colleges, 300 Pulteney Street, Geneva, NY 14456 (United States); Kasliwal, M. M. [The Observatories, Carnegie Institution for Science, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Lynch, D. K.; Russell, R. W. [The Aerospace Corporation, M2-266, P.O. Box 92957, Los Angeles, CA 90009-29257 (United States); Sitko, M. L., E-mail: sloebman@umich.edu [Department of Physics, University of Cincinnati, Cincinnati OH 45221 (United States)

2015-01-01

The eruptive variable V838 Monocerotis (V838 Mon) gained notoriety in 2002 when it brightened nine magnitudes in a series of three outbursts and then rapidly evolved into an extremely cool supergiant. We present optical, near-infrared (near-IR), and mid-IR spectroscopic and photometric observations of V838 Mon obtained between 2008 and 2012 at the Apache Point Observatory 3.5 m, NASA IRTF 3 m, and Gemini South 8 m telescopes. We contemporaneously analyze the optical and IR spectroscopic properties of V838 Mon to arrive at a revised spectral type L3 supergiant and effective temperature T{sub eff}∼2000–2200 K. Because there are no existing optical observational data for L supergiants, we speculate that V838 Mon may represent the prototype for L supergiants in this wavelength regime. We find a low level of Hα emission present in the system, consistent with interaction between V838 Mon and its B3V binary; however, we cannot rule out a stellar collision as the genesis event, which could result in the observed Hα activity. Based upon a two-component blackbody fit to all wavelengths of our data, we conclude that, as of 2009, a shell of ejecta surrounded V838 Mon at a radius of R=263±10 AU with a temperature of T=285±2 K. This result is consistent with IR interferometric observations from the same era and predictions from the Lynch et al. model of the expanding system, which provides a simple framework for understanding this complicated system.

The continued optical to mid-infrared evolution of V838 Monocerotis

International Nuclear Information System (INIS)

Loebman, S. R.; Wisniewski, J. P.; Schmidt, S. J.; Kowalski, A. F.; Barry, R. K.; Bjorkman, K. S.; Hammel, H. B.; Hawley, S. L.; Szkody, P.; Hebb, L.; Kasliwal, M. M.; Lynch, D. K.; Russell, R. W.; Sitko, M. L.

2015-01-01

The eruptive variable V838 Monocerotis (V838 Mon) gained notoriety in 2002 when it brightened nine magnitudes in a series of three outbursts and then rapidly evolved into an extremely cool supergiant. We present optical, near-infrared (near-IR), and mid-IR spectroscopic and photometric observations of V838 Mon obtained between 2008 and 2012 at the Apache Point Observatory 3.5 m, NASA IRTF 3 m, and Gemini South 8 m telescopes. We contemporaneously analyze the optical and IR spectroscopic properties of V838 Mon to arrive at a revised spectral type L3 supergiant and effective temperature T eff ∼2000–2200 K. Because there are no existing optical observational data for L supergiants, we speculate that V838 Mon may represent the prototype for L supergiants in this wavelength regime. We find a low level of Hα emission present in the system, consistent with interaction between V838 Mon and its B3V binary; however, we cannot rule out a stellar collision as the genesis event, which could result in the observed Hα activity. Based upon a two-component blackbody fit to all wavelengths of our data, we conclude that, as of 2009, a shell of ejecta surrounded V838 Mon at a radius of R=263±10 AU with a temperature of T=285±2 K. This result is consistent with IR interferometric observations from the same era and predictions from the Lynch et al. model of the expanding system, which provides a simple framework for understanding this complicated system.

Highly efficient dual-wavelength mid-infrared CW Laser in diode end-pumped Er:SrF2 single crystals

Science.gov (United States)

Ma, Weiwei; Qian, Xiaobo; Wang, Jingya; Liu, Jingjing; Fan, Xiuwei; Liu, Jie; Su, Liangbi; Xu, Jun

2016-11-01

The spectral properties and laser performance of Er:SrF2 single crystals were investigated and compared with Er:CaF2. Er:SrF2 crystals have larger absorption cross-sections at the pumping wavelength, larger mid-infrared stimulated emission cross-sections and much longer fluorescence lifetimes of the upper laser level (Er3+:4I11/2 level) than those of Er:CaF2 crystals. Dual-wavelength continuous-wave (CW) lasers around 2.8 μm were demonstrated in both 4at.% and 10at.% Er:SrF2 single crystals under 972 nm laser diode (LD) end pumping. The laser wavelengths are 2789.3 nm and 2791.8 nm in the former, and 2786.4 nm and 2790.7 nm in the latter, respectively. The best laser performance has been demonstrated in lightly doped 4at.% Er:SrF2 with a low threshold of 0.100 W, a high slope efficiency of 22.0%, an maximum output power of 0.483 W.

Analysis of Chuanxiong Rhizoma and its active components by Fourier transform infrared spectroscopy combined with two-dimensional correlation infrared spectroscopy.

Science.gov (United States)

Guo, Yizhen; Lv, Beiran; Wang, Jingjuan; Liu, Yang; Sun, Suqin; Xiao, Yao; Lu, Lina; Xiang, Li; Yang, Yanfang; Qu, Lei; Meng, Qinghong

2016-01-15

As complicated mixture systems, active components of Chuanxiong Rhizoma are very difficult to identify and discriminate. In this paper, the macroscopic IR fingerprint method including Fourier transform infrared spectroscopy (FT-IR), the second derivative infrared spectroscopy (SD-IR) and two-dimensional correlation infrared spectroscopy (2DCOS-IR), was applied to study and identify Chuanxiong raw materials and its different segmented production of HPD-100 macroporous resin. Chuanxiong Rhizoma is rich in sucrose. In the FT-IR spectra, water eluate is more similar to sucrose than the powder and the decoction. Their second derivative spectra amplified the differences and revealed the potentially characteristic IR absorption bands and combined with the correlation coefficient, concluding that 50% ethanol eluate had more ligustilide than other eluates. Finally, it can be found from 2DCOS-IR spectra that proteins were extracted by ethanol from Chuanxiong decoction by HPD-100 macroporous resin. It was demonstrated that the above three-step infrared spectroscopy could be applicable for quick, non-destructive and effective analysis and identification of very complicated and similar mixture systems of traditional Chinese medicines. Copyright © 2015 Elsevier B.V. All rights reserved.

Infrared studies of H II regions: the Sharpless regions S148, 184, 198, 206 and 269

International Nuclear Information System (INIS)

Pismis, Paris

1991-01-01

We present the results of a combined near-infrared and IRAS mapping study of five H II regions for which fairly complete information at optical and radio wavelengths previously existed. The near-infrared observations, carried out with the 2.1-m telescope at Observatorio de San Pedro Martir (Mexico), allowed us to study the the stellar content at the core of each nebula, while an analysis of extended near-infrared emission zones showed these to arise mainly from ionized gas (S148 and S206) or through scattering and thermal emission from dust grains surrounding a massive young star (S269-IRS2). The analysis of IRAS data, on the other hand, suggests that two different populations of grains contribute to the observed 12- to 100-μm fluxes. (author)

Multi-Wavelength Observations of Asteroid 2100 Ra-Shalom: Visible, Infrared, and Thermal Spectroscopy Results

Science.gov (United States)

Clark, Beth Ellen; Shepard, M.; Bus, S. J.; Vilas, F.; Rivkin, A. S.; Lim, L.; Lederer, S.; Jarvis, K.; Shah, S.; McConnochie, T.

2004-01-01

The August 2003 apparition of asteroid 2100 Ra-Shalom brought together a collaboration of observers with the goal of obtaining rotationally resolved multiwavelength spectra at each of 5 facilities: infrared spectra at the NASA Infrared Telescope Facility (Clark and Shepard), radar images at Arecibo (Shepard and Clark), thermal infrared spectra at Palomar (Lim, McConnochie and Bell), visible spectra at McDonald Observatory (Vilas, Lederer and Jarvis), and visible lightcurves at Ondrojev Observatory (Pravec). The radar data was to be used to develop a high spatial resolution physical model to be used in conjunction with spectral data to investigate compositional and textural properties on the near surface of Ra Shalom as a function of rotation phase. This was the first coordinated multi-wavelength investigation of any Aten asteroid. There are many reasons to study near-Earth asteroid (NEA) 2100 Ra-Shalom: 1) It has a controversial classification (is it a C- or K-type object)? 2) There would be interesting dynamical ramifications if Ra-Shalom is a K-type because most K-types come from the Eos family and there are no known dynamical pathways from Eos to the Aten population. 3) The best available spectra obtained previously may indicate a heterogeneous surface (most asteroids appear to be fairly homogeneous). 4) Ra-Shalom thermal observations obtained previously indicated a lack of regolith, minimizing the worry of space weathering effects in the spectra. 5) Radar observations obtained previously hinted at interesting surface structures. 6) Ra-Shalom is one of the largest Aten objects. And 7) Ra-Shalom is on a short list of proposed NEAs for spacecraft encounters and possible sample returns. Preliminary results from the visible, infrared, and thermal spectroscopy measurements will be presented here.

Forensic applications of infrared imaging for the detection and recording of latent evidence.

Science.gov (United States)

Lin, Apollo Chun-Yen; Hsieh, Hsing-Mei; Tsai, Li-Chin; Linacre, Adrian; Lee, James Chun-I

2007-09-01

We report on a simple method to record infrared (IR) reflected images in a forensic science context. Light sources using ultraviolet light have been used previously in the detection of latent prints, but the use of infrared light has been subjected to less investigation. IR light sources were used to search for latent evidence and the images were captured by either video or using a digital camera with a CCD array sensitive to IR wavelength. Bloodstains invisible to the eye, inks, tire prints, gunshot residue, and charred document on dark background are selected as typical matters that may be identified during a forensic investigation. All the evidence types could be detected and identified using a range of photographic techniques. In this study, a one in eight times dilution of blood could be detected on 10 different samples of black cloth. When using 81 black writing inks, the observation rates were 95%, 88% and 42% for permanent markers, fountain pens and ball-point pens, respectively, on the three kinds of dark cloth. The black particles of gunshot residue scattering around the entrance hole under IR light were still observed at a distance of 60 cm from three different shooting ranges. A requirement of IR reflectivity is that there is a contrast between the latent evidence and the background. In the absence of this contrast no latent image will be detected, which is similar to all light sources. The use of a video camera allows the recording of images either at a scene or in the laboratory. This report highlights and demonstrates the robustness of IR to detect and record the presence of latent evidence.

Quantitative gas analysis with FT-IR

DEFF Research Database (Denmark)

Bak, J.; Larsen, A.

1995-01-01

Calibration spectra of CO in the 2.38-5100 ppm concentration range (22 spectra) have been measured with a spectral resolution of 4 cm(-1), in the mid-IR (2186-2001 cm(-1)) region, with a Fourier transform infrared (FT-IR) instrument. The multivariate calibration method partial least-squares (PLS1...

RADIO MONITORING OF THE PERIODICALLY VARIABLE IR SOURCE LRLL 54361: NO DIRECT CORRELATION BETWEEN THE RADIO AND IR EMISSIONS

Energy Technology Data Exchange (ETDEWEB)

Forbrich, Jan, E-mail: jan.forbrich@univie.ac.at [University of Vienna, Department of Astrophysics, Türkenschanzstraße 17, A-1180 Vienna (Austria); Rodríguez, Luis F.; Palau, Aina; Zapata, Luis A. [Instituto de Radioastronomía y Astrofísica, UNAM, Apdo. Postal 3-72 (Xangari), 58089 Morelia, Michoacán (Mexico); Muzerolle, James [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Gutermuth, Robert A. [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States)

2015-11-20

LRLL 54361 is an infrared source located in the star-forming region IC 348 SW. Remarkably, its infrared luminosity increases by a factor of 10 over roughly one week every 25.34 days. To understand the origin of these remarkable periodic variations, we obtained sensitive 3.3 cm JVLA radio continuum observations of LRLL 54361 and its surroundings in six different epochs: three of them during the IR-on state and three during the IR-off state. The radio source associated with LRLL 54361 remained steady and did not show a correlation with the IR variations. We suggest that the IR is tracing the results of fast (with a timescale of days) pulsed accretion from an unseen binary companion, while the radio traces an ionized outflow with an extent of ∼100 AU that smooths out the variability over a period of the order of a year. The average flux density measured in these 2014 observations, 27 ± 5 μJy, is about a factor of two less than that measured about 1.5 years before, 53 ± 11 μJy, suggesting that variability in the radio is present, but over larger timescales than in the IR. We discuss other sources in the field, in particular two infrared/X-ray stars that show rapidly varying gyrosynchrotron emission.

Far infrared supplement: Catalog of infrared observations, second edition

International Nuclear Information System (INIS)

Gezari, D.Y.; Schmitz, M.; Mead, J.M.

1988-08-01

The Far Infrared Supplement: Catalog of Infrared Observations summarizes all infrared astronomical observations at far infrared wavelengths (5 to 1000 microns) published in the scientific literature from 1965 through 1986. The Supplement list contain 25 percent of the observations in the full Catalog of Infrared Observations (CIO), and essentially eliminates most visible stars from the listings. The Supplement is thus more compact than the main catalog, and is intended for easy reference during astronomical observations. The Far Infrared Supplement (2nd Edition) includes the Index of Infrared Source Positions and the Bibliography of Infrared Astronomy for the subset of far infrared observations listed

Invited Article: Multiple-octave spanning high-energy mid-IR supercontinuum generation in bulk quadratic nonlinear crystals

Directory of Open Access Journals (Sweden)

Binbin Zhou

2016-08-01

Full Text Available Bright and broadband coherent mid-IR radiation is important for exciting and probing molecular vibrations. Using cascaded nonlinearities in conventional quadratic nonlinear crystals like lithium niobate, self-defocusing near-IR solitons have been demonstrated that led to very broadband supercontinuum generation in the visible, near-IR, and short-wavelength mid-IR. Here we conduct an experiment where a mid-IR crystal is pumped in the mid-IR. The crystal is cut for noncritical interaction, so the three-wave mixing of a single mid-IR femtosecond pump source leads to highly phase-mismatched second-harmonic generation. This self-acting cascaded process leads to the formation of a self-defocusing soliton at the mid-IR pump wavelength and after the self-compression point multiple octave-spanning supercontinua are observed. The results were recorded in a commercially available crystal LiInS2 pumped in the 3-4 μm range with 85 fs 50 μJ pulse energy, with the broadest supercontinuum covering 1.6-7.0 μm. We measured up 30 μJ energy in the supercontinuum, and the energy promises to scale favorably with an increased pump energy. Other mid-IR crystals can readily be used as well to cover other pump wavelengths and target other supercontinuum wavelength ranges.

Cloud2IR: Infrared thermography and environmental sensors integrated in an autonomoussystem for long term monitoring of structures

Science.gov (United States)

Crinière, Antoine; Dumoulin, Jean; Mevel, Laurent; Andrade-Barroso, Guillermo

2016-04-01

Since late 2014, the project Cloud2SM aims to develop a robust information system able to assess the long term monitoring of civil engineering structures as well as interfacing various sensors and data. Cloud2SM address three main goals, the management of distributed data and sensors network, the asynchronous processing of the data through network and the local management of the sensors themselves [1]. Integrated to this project Cloud2IR is an autonomous sensor system dedicated to the long term monitoring of infrastructures. Past experimentations have shown the need as well as usefulness of such system [2]. Before Cloud2IR an initially laboratory oriented system was used, which implied heavy operating system to be used [3]. Based on such system Cloud2IR has benefited of the experimental knowledge acquired to redefine a lighter architecture based on generics standards, more appropriated to autonomous operations on field and which can be later included in a wide distributed architecture such as Cloud2SM. The sensor system can be divided in two parts. The sensor side, this part is mainly composed by the various sensors drivers themselves as the infrared camera, the weather station or the pyranometers and their different fixed configurations. In our case, as infrared camera are slightly different than other kind of sensors, the system implement in addition an RTSP server which can be used to set up the FOV as well as other measurement parameter considerations. The second part can be seen as the data side, which is common to all sensors. It instantiate through a generic interface all the sensors and control the data access loop (not the requesting). This side of the system is weakly coupled (see data coupling) with the sensor side. It can be seen as a general framework able to aggregate any sensor data, type or size and automatically encapsulate them in various generic data format as HDF5 or cloud data as OGC SWE standard. This whole part is also responsible of the

Extending laser plasma accelerators into the mid-IR spectral domain with a next-generation ultra-fast CO2 laser

Science.gov (United States)

Pogorelsky, I. V.; Babzien, M.; Ben-Zvi, I.; Polyanskiy, M. N.; Skaritka, J.; Tresca, O.; Dover, N. P.; Najmudin, Z.; Lu, W.; Cook, N.; Ting, A.; Chen, Y.-H.

2016-03-01

Expanding the scope of relativistic plasma research to wavelengths longer than the λ/≈   0.8-1.1 μm range covered by conventional mode-locked solid-state lasers would offer attractive opportunities due to the quadratic scaling of the ponderomotive electron energy and critical plasma density with λ. Answering this quest, a next-generation mid-IR laser project is being advanced at the BNL ATF as a part of the user facility upgrade. We discuss the technical approach to this conceptually new 100 TW, 100 fs, λ  =   9-11 μm CO2 laser BESTIA (Brookhaven Experimental Supra-Terawatt Infrared at ATF) that encompasses several innovations applied for the first time to molecular gas lasers. BESTIA will enable new regimes of laser plasma accelerators. One example is shock-wave ion acceleration (SWA) from gas jets. We review ongoing efforts to achieve stable, monoenergetic proton acceleration by dynamically shaping the plasma density profile from a hydrogen gas target with laser-produced blast waves. At its full power, 100 TW BESTIA promises to achieve proton beams at an energy exceeding 200 MeV. In addition to ion acceleration in over-critical plasma, the ultra-intense mid-IR BESTIA will open up new opportunities in driving wakefields in tenuous plasmas, expanding the landscape of laser wakefield accelerator (LWFA) studies into the unexplored long-wavelength spectral domain. Simple wavelength scaling suggests that a 100 TW CO2 laser beam will be capable of efficiently generating plasma ‘bubbles’ a thousand times greater in volume compared with a near-IR solid state laser of an equivalent power. Combined with a femtosecond electron linac available at the ATF, this wavelength scaling will facilitate the study of external seeding and staging of LWFAs.

Recent Developments in Quantum-Well Infrared Photodetectors

Science.gov (United States)

Gunapala, S. D.; Bandara, K. M. S. V.

1995-01-01

Intrinsic infrared (IR) detectors in the long wavelength range (8-20 Am) are based on an optically excited interband transition, which promotes an electron across the band gap (E(sub g)) from the valence band to the conduction band as shown. These photoelectrons can be collected efficiently, thereby producing a photocurrent in the external circuit. Since the incoming photon has to promote an electron from the valence band to the conduction band, the energy of the photon (h(sub upsilon)) must be higher than the E(sub g) of the photosensitive material. Therefore, the spectral response of the detectors can be controlled by controlling the E(sub g) of the photosensitive material. Examples for such materials are Hg(1-x), Cd(x), Te, and Pb(1-x), Sn(x), Te, in which the energy gap can be controlled by varying x. This means detection of very-long-wavelength IR radiation up to 20 microns requires small band gaps down to 62 meV. It is well known that these low band gap materials, characterized by weak bonding and low melting points, are more difficult to grow and process than large-band gap semiconductors such as GaAs. These difficulties motivate the exploration of utilizing the intersub-band transitions in multiquantum well (MQW) structures made of more refractory large-band gap semiconductors. The idea of using MQW structures to detect IR radiation can be explained by using the basic principles of quantum mechanics. The quantum well is equivalent to the well-known particle in a box problem in quantum mechanics, which can be solved by the time independent Schroudiner equation.

GROUND-BASED Paα NARROW-BAND IMAGING OF LOCAL LUMINOUS INFRARED GALAXIES. I. STAR FORMATION RATES AND SURFACE DENSITIES

Energy Technology Data Exchange (ETDEWEB)

Tateuchi, Ken; Konishi, Masahiro; Motohara, Kentaro; Takahashi, Hidenori; Kato, Natsuko Mitani; Kitagawa, Yutaro; Todo, Soya; Toshikawa, Koji; Sako, Shigeyuki; Uchimoto, Yuka K.; Ohsawa, Ryou; Asano, Kentaro; Kamizuka, Takafumi; Nakamura, Tomohiko; Okada, Kazushi [Institute of Astronomy, Graduate School of Science, The University of Tokyo, 2-21-1 Osawa, Mitaka, Tokyo 181-0015 (Japan); Ita, Yoshifusa [Astronomical Institute, Tohoku University, 6-3 Aoba, Aramaki, Aoba-ku, Sendai, Miyagi 980-8578 (Japan); Komugi, Shinya [Division of Liberal Arts, Kogakuin University, 2665-1, Hachioji, Tokyo 192-0015 (Japan); Koshida, Shintaro [Subaru Telescope, National Astronomical Observatory of Japan, Hilo, HI 96720 (United States); Manabe, Sho [Department of Earth and Planetary Sciences, Kobe University, Kobe 657-8501 (Japan); Nakashima, Asami, E-mail: tateuchi@ioa.s.u-tokyo.ac.jp [Department of Astronomy, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); and others

2015-03-15

Luminous infrared galaxies (LIRGs) are enshrouded by a large amount of dust produced by their active star formation, and it is difficult to measure their activity in optical wavelengths. We have carried out Paα narrow-band imaging observations of 38 nearby star forming galaxies including 33 LIRGs listed in the IRAS Revised Bright Galaxy Sample catalog with the Atacama Near InfraRed camera on the University of Tokyo Atacama Observatory (TAO) 1.0 m telescope (miniTAO). Star formation rates (SFRs) estimated from the Paα fluxes, corrected for dust extinction using the Balmer decrement method (typically A{sub V} ∼ 4.3 mag), show a good correlation with those from the bolometric infrared luminosity of the IRAS data within a scatter of 0.27 dex. This suggests that the correction of dust extinction for the Paα flux is sufficient in our sample. We measure the physical sizes and surface densities of infrared luminosities (Σ{sub L(IR)}) and the SFR (Σ{sub SFR}) of star forming regions for individual galaxies, and we find that most of the galaxies follow a sequence of local ultra-luminous or luminous infrared galaxies (U/LIRGs) on the L(IR)-Σ{sub L(IR)} and SFR-Σ{sub SFR} plane. We confirm that a transition of the sequence from normal galaxies to U/LIRGs is seen at L(IR) = 8 × 10{sup 10} L {sub ☉}. Also, we find that there is a large scatter in physical size, different from normal galaxies or ULIRGs. Considering the fact that most U/LIRGs are merging or interacting galaxies, this scatter may be caused by strong external factors or differences in their merging stages.

Analyzing Hydrogen Recombination Lines in the Infrared and Optical to Determine Extinction and SFRs of Local LIRGs

Science.gov (United States)

Payne, Anna; Inami, Hanae

2015-01-01

We report on measurements for dust extinction and star formation rates (SFRs) for luminous infrared galaxies (LIRGs). We utilized the hydrogen recombination lines Brα, Hα, and Hβ observed in the infrared and optical wavelengths with AKARI and the Lick Observatory's Kast Double spectrograph to produce spectra. By calculating Brα/Hα ratios for the target galaxies, extinction is estimated. A possible correlation between higher LIR, IR/UV, specific SFRs and higher Brα/Hα has been found. Through comparisons with Hα/Hβ, it may be possible to determine if Hα is, in fact, underestimating extinction, since Hα is more strongly affected by extinction compared to longer wavelengths such as Brα. The accuracy of using Hα in extinction corrections is important for SFR studies, and, thus, one goal is to find a more accurate reddening correction factor. Payne was supported by the NOAO/KPNO Research Experiences for Undergraduates (REU) Program which is funded by the National Science Foundation Research Experiences for Undergraduates Program (AST-1262829).

IR characteristic simulation of city scenes based on radiosity model

Science.gov (United States)

Xiong, Xixian; Zhou, Fugen; Bai, Xiangzhi; Yu, Xiyu

2013-09-01

Reliable modeling for thermal infrared (IR) signatures of real-world city scenes is required for signature management of civil and military platforms. Traditional modeling methods generally assume that scene objects are individual entities during the physical processes occurring in infrared range. However, in reality, the physical scene involves convective and conductive interactions between objects as well as the radiations interactions between objects. A method based on radiosity model describes these complex effects. It has been developed to enable an accurate simulation for the radiance distribution of the city scenes. Firstly, the physical processes affecting the IR characteristic of city scenes were described. Secondly, heat balance equations were formed on the basis of combining the atmospheric conditions, shadow maps and the geometry of scene. Finally, finite difference method was used to calculate the kinetic temperature of object surface. A radiosity model was introduced to describe the scattering effect of radiation between surface elements in the scene. By the synthesis of objects radiance distribution in infrared range, we could obtain the IR characteristic of scene. Real infrared images and model predictions were shown and compared. The results demonstrate that this method can realistically simulate the IR characteristic of city scenes. It effectively displays the infrared shadow effects and the radiation interactions between objects in city scenes.

Radiation-resistance assessment of IR fibres for ITER thermography diagnostic system

International Nuclear Information System (INIS)

Brichard, B.; Ierschot, S. van; Ooms, H.; Berghmans, F.; Reichle, R.; Pocheau, C.; Decreton, M.

2006-01-01

The actively cooled target plates in the divertor of ITER will be subjected to high thermal fluxes (∼ 10 MW/m 2 ). These target plates are compound structures of an armour material at the surface - either carbon fibre reinforced carbon (CFC) or tungsten - and a water cooled CuCrZr structure inside or below. The thermal limit of the interface between the two materials must not exceed 550 o C. Therefore, the temperature must be carefully monitored to prevent structural damages of the divertor plates. Non contact measurements of the temperature offer the advantage to avoid weakening of the cooling plate structure which is already quite complex to manufacture. Infrared thermography of the target surface is therefore considered as a possible solution. Recently a diagnostic concept for spectrally resolved ITER divertor thermography using optical fibres has been proposed by CEA-Cadarache. However, the divertor region will have to face high-radiation flux and the radiation-resistance of InfraRed (IR)-fibres must be evaluated. In collaboration with CEA-Cadarache, an irradiation program has been started at SCK-CEN (Mol, Belgium) with the aim to measure the radiation-induced absorption of different IR fibre candidates operating in the 1-5 μm range. We selected various commercially available IR technologies: ZrF 4 , Hollow-Waveguide, Sapphire and Chalcogenide. For wavelengths below 2 μm we also tested low-OH silica fibres. We carried out a gamma irradiation at a maximum dose-rate of 0.42 Gy/s up to a total dose of about 5000 Gy. We showed that the optical transmission of ZrF 4 fibres strongly decreased under gamma radiation, primarily for wavelengths below 2 μm. In this type of fibre typical optical losses can reach 50 % at 5000 Gy around 3 μm. Nevertheless, the optical transmission can be significantly recovered by performing a thermal annealing treatment at a temperature of 100 o C. We also irradiated a Silver-coated hollow waveguide fibre at the same dose-rate but up

THE SUB-mJy RADIO POPULATION OF THE E-CDFS: OPTICAL AND INFRARED COUNTERPART IDENTIFICATION

Energy Technology Data Exchange (ETDEWEB)

Bonzini, M.; Mainieri, V.; Padovani, P.; Rosati, P. [ESO, Karl-Schwarzschild-Strasse 2, D-85748 Garching (Germany); Kellermann, K. I. [National Radio Astronomy Observatory, 520 Edgemont Road, Charlottesville, VA 22903-2475 (United States); Miller, N. [Department of Astronomy, University of Maryland, College Park, MD 20742-2421 (United States); Tozzi, P.; Balestra, I. [INAF Osservatorio Astronomico di Trieste, via G.B. Tiepolo 11, I-34131, Trieste (Italy); Vattakunnel, S. [Dipartimento di Fisica Universit di Trieste, piazzale Europa 1, I-34127 Trieste (Italy); Brandt, W. N.; Luo, B. [Department of Astronomy and Astrophysics, Pennsylvania State University, University Park, PA 16802 (United States); Xue, Y. Q., E-mail: mbonzini@eso.org [Key Laboratory for Research in Galaxies and Cosmology, Department of Astronomy, University of Science and Technology of China, Chinese Academy of Sciences, Hefei, Anhui 230026 (China)

2012-11-15

We study a sample of 883 sources detected in a deep Very Large Array survey at 1.4 GHz in the Extended Chandra Deep Field South. This paper focuses on the identification of their optical and infrared (IR) counterparts. We use a likelihood-ratio technique that is particularly useful when dealing with deep optical images to minimize the number of spurious associations. We find a reliable counterpart for 95% of our radio sources. Most of the counterparts (74%) are detected at optical wavelengths, but there is a significant fraction (21%) that are only detectable in the IR. Combining newly acquired optical spectra with data from the literature, we are able to assign a redshift to 81% of the identified radio sources (37% spectroscopic). We also investigate the X-ray properties of the radio sources using the Chandra 4 Ms and 250 ks observations. In particular, we use a stacking technique to derive the average properties of radio objects undetected in the Chandra images. The results of our analysis are collected in a new catalog containing the position of the optical/IR counterpart, the redshift information, and the X-ray fluxes. It is the deepest multi-wavelength catalog of radio sources, which will be used for future study of this galaxy population.

Improvenments in environmental trace analysis by GC-IR and LC-IR.

NARCIS (Netherlands)

Visser, T.; Vredenbregt, M.J.; Jong, A.P.J.M.; Somsen, G.W.; Hankemeier, T.; Velthorst, N.H.; Gooijer, C.; Brinkman, U.A.T.

1997-01-01

Research has been carried out to enlarge the potential of infrared (IR) spectrometry as a detector in gas and liquid chromatography (GC and LC). The study has been directed to applications in environmental analysis. Examples of recently obtained results are presented. The analyte detectability of

Fast rise time IR detectors for lepton colliders

International Nuclear Information System (INIS)

Drago, A.; Bini, S.; Guidi, M. Cestelli; Marcelli, A.; Pace, E.

2016-01-01

Diagnostics is a fundamental issue for accelerators whose demands are continuously increasing. In particular bunch-by-bunch diagnostics is a key challenge for the latest generation of lepton colliders and storage rings. The Frascati Φ-factory, DAΦNE, colliding at 1.02 GeV in the centre of mass, hosts in the main rings few synchrotron radiation beamlines and two of them collect the synchrotron radiation infrared emission: SINBAD from the electron ring and 3+L from the positron ring. At DAΦNE each bucket is 2.7 ns long and particles are gathered in bunches emitting pulsed IR radiation, whose intensity in the long wavelength regime is directly proportional to the accumulated particles. Compact uncooled photoconductive HgCdTe detectors have been tested in both beamlines using dedicated optical layouts. Actually, the fast rise time of HgCdTe semiconductors give us the chance to test bunch-by-bunch devices for both longitudinal and transverse diagnostics. For the longitudinal case, single pixel detectors have been used, while for the transverse diagnostics, multi-pixel array detectors, with special custom design, are under test. This contribution will briefly describe the status of the research on fast IR detectors at DAΦNE, the results obtained and possible foreseen developments.

Characteristics of infrared point sources associated with OH masers

International Nuclear Information System (INIS)

Mu Jimang; Esimbek, Jarken; Zhou Jianjun; Zhang Haijuan

2010-01-01

We collect 3249 OH maser sources from the literature published up to April 2007, and compile a new catalog of OH masers. We look for the exciting sources of these masers and their infrared properties from IRAS and MSX data, and make a statistical study. MSX sources associated with stellar 1612 MHz OH masers are located mainly above the blackbody line; this is caused by the dust absorption of stellar envelopes, especially in the MSX A band. The mid-IR sources associated with stellar OH masers are concentrated in a small region in an [A]-[D] vs. [A]-[E] diagram with a small fraction of contamination; this gives us a new criterion to search for new stellar OH masers and distinguish stellar masers from unknown types of OH masers. IR sources associated with 1612 MHz stellar OH masers show an expected result: the average flux of sources with F60 > F25 increases with increasing wavelength, while those with F60 F25.

Monolithic photonic integration for visible and short near-infrared wavelengths: technologies and platforms for bio and life science applications

Science.gov (United States)

Porcel, Marco A. G.; Artundo, Iñigo; Domenech, J. David; Geuzebroek, Douwe; Sunarto, Rino; Hoofman, Romano

2018-04-01

This tutorial aims to provide a general overview on the state-of-the-art of photonic integrated circuits (PICs) in the visible and short near-infrared (NIR) wavelength ranges, mostly focusing in silicon nitride (SiN) substrates, and a guide to the necessary steps in the design toward the fabrication of such PICs. The focus is put on bio- and life sciences, given the adequacy and, thus, a large number of applications in this field.

Assessing various Infrared (IR) microscopic imaging techniques for post-mortem interval evaluation of human skeletal remains

Science.gov (United States)

Roider, Clemens; Ritsch-Marte, Monika; Pemberger, Nadin; Cemper-Kiesslich, Jan; Hatzer-Grubwieser, Petra; Parson, Walther; Pallua, Johannes Dominikus

2017-01-01

Due to the influence of many environmental processes, a precise determination of the post-mortem interval (PMI) of skeletal remains is known to be very complicated. Although methods for the investigation of the PMI exist, there still remains much room for improvement. In this study the applicability of infrared (IR) microscopic imaging techniques such as reflection-, ATR- and Raman- microscopic imaging for the estimation of the PMI of human skeletal remains was tested. PMI specific features were identified and visualized by overlaying IR imaging data with morphological tissue structures obtained using light microscopy to differentiate between forensic and archaeological bone samples. ATR and reflection spectra revealed that a more prominent peak at 1042 cm-1 (an indicator for bone mineralization) was observable in archeological bone material when compared with forensic samples. Moreover, in the case of the archaeological bone material, a reduction in the levels of phospholipids, proteins, nucleic acid sugars, complex carbohydrates as well as amorphous or fully hydrated sugars was detectable at (reciprocal wavelengths/energies) between 3000 cm-1 to 2800 cm-1. Raman spectra illustrated a similar picture with less ν2PO43−at 450 cm-1 and ν4PO43− from 590 cm-1 to 584 cm-1, amide III at 1272 cm-1 and protein CH2 deformation at 1446 cm-1 in archeological bone material/samples/sources. A semi-quantitative determination of various distributions of biomolecules by chemi-maps of reflection- and ATR- methods revealed that there were less carbohydrates and complex carbohydrates as well as amorphous or fully hydrated sugars in archaeological samples compared with forensic bone samples. Raman- microscopic imaging data showed a reduction in B-type carbonate and protein α-helices after a PMI of 3 years. The calculated mineral content ratio and the organic to mineral ratio displayed that the mineral content ratio increases, while the organic to mineral ratio decreases with

Assessing various Infrared (IR microscopic imaging techniques for post-mortem interval evaluation of human skeletal remains.

Directory of Open Access Journals (Sweden)

Claudia Woess

Full Text Available Due to the influence of many environmental processes, a precise determination of the post-mortem interval (PMI of skeletal remains is known to be very complicated. Although methods for the investigation of the PMI exist, there still remains much room for improvement. In this study the applicability of infrared (IR microscopic imaging techniques such as reflection-, ATR- and Raman- microscopic imaging for the estimation of the PMI of human skeletal remains was tested. PMI specific features were identified and visualized by overlaying IR imaging data with morphological tissue structures obtained using light microscopy to differentiate between forensic and archaeological bone samples. ATR and reflection spectra revealed that a more prominent peak at 1042 cm-1 (an indicator for bone mineralization was observable in archeological bone material when compared with forensic samples. Moreover, in the case of the archaeological bone material, a reduction in the levels of phospholipids, proteins, nucleic acid sugars, complex carbohydrates as well as amorphous or fully hydrated sugars was detectable at (reciprocal wavelengths/energies between 3000 cm-1 to 2800 cm-1. Raman spectra illustrated a similar picture with less ν2PO43-at 450 cm-1 and ν4PO43- from 590 cm-1 to 584 cm-1, amide III at 1272 cm-1 and protein CH2 deformation at 1446 cm-1 in archeological bone material/samples/sources. A semi-quantitative determination of various distributions of biomolecules by chemi-maps of reflection- and ATR- methods revealed that there were less carbohydrates and complex carbohydrates as well as amorphous or fully hydrated sugars in archaeological samples compared with forensic bone samples. Raman- microscopic imaging data showed a reduction in B-type carbonate and protein α-helices after a PMI of 3 years. The calculated mineral content ratio and the organic to mineral ratio displayed that the mineral content ratio increases, while the organic to mineral ratio

Assessing various Infrared (IR) microscopic imaging techniques for post-mortem interval evaluation of human skeletal remains.

Science.gov (United States)

Woess, Claudia; Unterberger, Seraphin Hubert; Roider, Clemens; Ritsch-Marte, Monika; Pemberger, Nadin; Cemper-Kiesslich, Jan; Hatzer-Grubwieser, Petra; Parson, Walther; Pallua, Johannes Dominikus

2017-01-01

Due to the influence of many environmental processes, a precise determination of the post-mortem interval (PMI) of skeletal remains is known to be very complicated. Although methods for the investigation of the PMI exist, there still remains much room for improvement. In this study the applicability of infrared (IR) microscopic imaging techniques such as reflection-, ATR- and Raman- microscopic imaging for the estimation of the PMI of human skeletal remains was tested. PMI specific features were identified and visualized by overlaying IR imaging data with morphological tissue structures obtained using light microscopy to differentiate between forensic and archaeological bone samples. ATR and reflection spectra revealed that a more prominent peak at 1042 cm-1 (an indicator for bone mineralization) was observable in archeological bone material when compared with forensic samples. Moreover, in the case of the archaeological bone material, a reduction in the levels of phospholipids, proteins, nucleic acid sugars, complex carbohydrates as well as amorphous or fully hydrated sugars was detectable at (reciprocal wavelengths/energies) between 3000 cm-1 to 2800 cm-1. Raman spectra illustrated a similar picture with less ν2PO43-at 450 cm-1 and ν4PO43- from 590 cm-1 to 584 cm-1, amide III at 1272 cm-1 and protein CH2 deformation at 1446 cm-1 in archeological bone material/samples/sources. A semi-quantitative determination of various distributions of biomolecules by chemi-maps of reflection- and ATR- methods revealed that there were less carbohydrates and complex carbohydrates as well as amorphous or fully hydrated sugars in archaeological samples compared with forensic bone samples. Raman- microscopic imaging data showed a reduction in B-type carbonate and protein α-helices after a PMI of 3 years. The calculated mineral content ratio and the organic to mineral ratio displayed that the mineral content ratio increases, while the organic to mineral ratio decreases with time

Radio and infrared observations of the faint nebula GM24

Energy Technology Data Exchange (ETDEWEB)

Rodriguez, L F; Roth, M; Tapia, M; Canto, J; Persi, P; Ferrari-Toniolo, M

1986-02-01

The faint nebulosity GM24=PP85 listed by Parsamian and Petrosian (1979) was observed at infrared (1-10 ..mu..m) and radio (6 cm and CO line) wavelengths in the vicinity of the CO hot spot reported by Torrelles et al. (1983). The radio continuum (6 cm) emission from a spherically symmetrical HII region was detected with the Very Large Array. Its position coincides with the brightest part of the visible nebulosity and a 1-4 ..mu..m emission peak. Their infrared maps made at the Observatorio Astronomico Nacional de San Pedro Martir, show two additional (1-10 ..mu..m) peaks located at distances approx. 30 arc sec from the compact HII region, all surrounded by extended near infrared (1-4 ..mu..m) emission. A detailed CO (J=1 ..-->.. 0) map of the whole molecular cloud was also obtained with the University of Texas Millimeter - Wave Telescope. Their results are interpreted in terms of the recent formation of three massive stars, one of which, having developed an HII region, is at a slightly later phase of its evolution. The extended near infrared emission may arise in a reflection nebula similar to NGC 7538-Irs 9. 4 references.

Fourier Transform Infrared Spectroscopy (FT-IR) and Simple Algorithm Analysis for Rapid and Non-Destructive Assessment of Developmental Cotton Fibers.

Science.gov (United States)

Liu, Yongliang; Kim, Hee-Jin

2017-06-22

With cotton fiber growth or maturation, cellulose content in cotton fibers markedly increases. Traditional chemical methods have been developed to determine cellulose content, but it is time-consuming and labor-intensive, mostly owing to the slow hydrolysis process of fiber cellulose components. As one approach, the attenuated total reflection Fourier transform infrared (ATR FT-IR) spectroscopy technique has also been utilized to monitor cotton cellulose formation, by implementing various spectral interpretation strategies of both multivariate principal component analysis (PCA) and 1-, 2- or 3-band/-variable intensity or intensity ratios. The main objective of this study was to compare the correlations between cellulose content determined by chemical analysis and ATR FT-IR spectral indices acquired by the reported procedures, among developmental Texas Marker-1 (TM-1) and immature fiber ( im ) mutant cotton fibers. It was observed that the R value, CI IR , and the integrated intensity of the 895 cm -1 band exhibited strong and linear relationships with cellulose content. The results have demonstrated the suitability and utility of ATR FT-IR spectroscopy, combined with a simple algorithm analysis, in assessing cotton fiber cellulose content, maturity, and crystallinity in a manner which is rapid, routine, and non-destructive.

THE INFRARED SPECTROSCOPY OF POLYCYCLIC AROMATIC HYDROCARBONS WITH FIVE- AND SEVEN-MEMBERED FUSED RING DEFECTS

International Nuclear Information System (INIS)

Ricca, Alessandra; Bauschlicher, Charles W. Jr; Allamandola, Louis J.

2011-01-01

Polycyclic aromatic hydrocarbon (PAH) growth and destruction are thought to proceed via the occasional incorporation of five- and seven-membered fused ring defects in the hexagonal carbon skeleton. Using density functional theory, this paper investigates the effect such five- and seven-membered fused ring defects have on the infrared spectra of ovalene, circumovalene, and circumcircumovalene. The defects make only small changes to the overall infrared (IR) spectra, both in the mid-IR and in the far-IR, of these species. In addition to small shifts in the positions of the bands between the PAHs with and without defects, the most common effect of the defects is to increase the number of bands. Except for an anion with the Stone-Wales defect, all of the species studied have the C-C stretching band at 6.3 μm or at longer wavelengths, the position in Classes B and C astronomical PAH spectra. In the case of the Stone-Wales anion, the band falls at 6.20 μm, suggesting that further study of defects is probably worthwhile, as some PAHs with defects might be important in those sources (Class A) that show a C-C stretching band that falls near 6.2 μm.

Fibre-optic laser-assisted infrared tumour diagnostics (FLAIR)

Science.gov (United States)

Bindig, U.; Müller, G.

2005-08-01

Laser based fibre-optic surgery procedures are commonly used in minimal invasive surgery. Despite the development of precise and efficient laser systems there are also innovative attempts in the field of bio-medical diagnostics. As a direct result of the tissue's optical properties most applications are focused on the visible wavelength range of the spectrum. The extension of the spectrum up to the mid-infrared (IR) region will offer a broad range of possibilities for novel strategies with a view to non-invasive diagnostics in medicine. We describe a method to detect differences between diseased and normal tissues, which involve Fourier transform IR microspectroscopy and fibre-optics methods. Regions of interest on 10 µm thin tissue sections were mapped using an IR microscope in transmission mode. After IR-mapping, the samples were analysed using standard pathological techniques. Quadratic discriminant and correlation analyses were applied to the IR maps obtained allowing differentiation between cancerous and normal tissue. The use of optical fibres, transparent in the mid-IR, allowed measurements to be made in the attenuated total reflectance (ATR)-mode at a remote location. The IR sensor is in contact with the sample that shows characteristic absorption lines. The total transmission of the fibre and the sample will decrease at these lines. This method can be used to determine the absorption of a sample in a non-destructive manner. In this paper we report on our efforts to develop an IR fibre-optic sensor for tissue identification as well as to differentiate between malignant and healthy tissue in vivo. We also describe the technical design of the laboratory set-up and the results of developments made. Silver halide fibres and a special sensor tip were used for the ATR measurements on tissue specimens. The results indicate that fibre-optic IR spectrometry will be a useful tool for bio-diagnostics.

Fibre-optic laser-assisted infrared tumour diagnostics (FLAIR)

International Nuclear Information System (INIS)

Bindig, U; Mueller, G

2005-01-01

Laser based fibre-optic surgery procedures are commonly used in minimal invasive surgery. Despite the development of precise and efficient laser systems there are also innovative attempts in the field of bio-medical diagnostics. As a direct result of the tissue's optical properties most applications are focused on the visible wavelength range of the spectrum. The extension of the spectrum up to the mid-infrared (IR) region will offer a broad range of possibilities for novel strategies with a view to non-invasive diagnostics in medicine. We describe a method to detect differences between diseased and normal tissues, which involve Fourier transform IR microspectroscopy and fibre-optics methods. Regions of interest on 10 μm thin tissue sections were mapped using an IR microscope in transmission mode. After IR-mapping, the samples were analysed using standard pathological techniques. Quadratic discriminant and correlation analyses were applied to the IR maps obtained allowing differentiation between cancerous and normal tissue. The use of optical fibres, transparent in the mid-IR, allowed measurements to be made in the attenuated total reflectance (ATR)-mode at a remote location. The IR sensor is in contact with the sample that shows characteristic absorption lines. The total transmission of the fibre and the sample will decrease at these lines. This method can be used to determine the absorption of a sample in a non-destructive manner. In this paper we report on our efforts to develop an IR fibre-optic sensor for tissue identification as well as to differentiate between malignant and healthy tissue in vivo. We also describe the technical design of the laboratory set-up and the results of developments made. Silver halide fibres and a special sensor tip were used for the ATR measurements on tissue specimens. The results indicate that fibre-optic IR spectrometry will be a useful tool for bio-diagnostics

Studies of Neutron Stars at Optical/IR Wavelengths

OpenAIRE

Mignani, R. P.; Bagnulo, S.; De Luca, A.; Israel, G. L.; Curto, G. Lo; Motch, C.; Perna, R.; Rea, N.; Turolla, R.; Zane, S.

2006-01-01

In the last years, optical studies of Isolated Neutron Stars (INSs) have expanded from the more classical rotation-powered ones to other categories, like the Anomalous X-ray Pulsars (AXPs) and the Soft Gamma-ray Repeaters (SGRs), which make up the class of the magnetars, the radio-quiet INSs with X-ray thermal emission and, more recently, the enigmatic Compact Central Objects (CCOs) in supernova remnants. Apart from 10 rotation-powered pulsars, so far optical/IR counterparts have been found f...

Sensing cocaine in saliva with attenuated total reflection infrared (ATR-IR) spectroscopy combined with a one-step extraction method

Science.gov (United States)

Hans, Kerstin M.-C.; Gianella, Michele; Sigrist, Markus W.

2012-03-01

On-site drug tests have gained importance, e.g., for protecting the society from impaired drivers. Since today's drug tests are majorly only positive/negative, there is a great need for a reliable, portable and preferentially quantitative drug test. In the project IrSens we aim to bridge this gap with the development of an optical sensor platform based on infrared spectroscopy and focus on cocaine detection in saliva. We combine a one-step extraction method, a sample drying technique and infrared attenuated total reflection (ATR) spectroscopy. As a first step we have developed an extraction technique that allows us to extract cocaine from saliva to an almost infrared-transparent solvent and to record ATR spectra with a commercially available Fourier Transform-infrared spectrometer. To the best of our knowledge this is the first time that such a simple and easy-to-use one-step extraction method is used to transfer cocaine from saliva into an organic solvent and detect it quantitatively. With this new method we are able to reach a current limit of detection around 10 μg/ml. This new extraction method could also be applied to waste water monitoring and controlling caffeine content in beverages.

Comparison of Fiber Optic and Conduit Attenuated Total Reflection (ATR) Fourier Transform Infrared (FT-IR) Setup for In-Line Fermentation Monitoring.

Science.gov (United States)

Koch, Cosima; Posch, Andreas E; Herwig, Christoph; Lendl, Bernhard

2016-12-01

The performance of a fiber optic and an optical conduit in-line attenuated total reflection mid-infrared (IR) probe during in situ monitoring of Penicillium chrysogenum fermentation were compared. The fiber optic probe was connected to a sealed, portable, Fourier transform infrared (FT-IR) process spectrometer via a plug-and-play interface. The optical conduit, on the other hand, was connected to a FT-IR process spectrometer via a knuckled probe with mirrors that had to be adjusted prior to each fermentation, which were purged with dry air. Penicillin V (PenV) and its precursor phenoxyacetic acid (POX) concentrations were determined by online high-performance liquid chromatography and the obtained concentrations were used as reference to build partial least squares regression models. Cross-validated root-mean-square errors of prediction were found to be 0.2 g L -1 (POX) and 0.19 g L -1 (PenV) for the fiber optic setup and 0.17 g L -1 (both POX and PenV) for the conduit setup. Higher noise-levels and spectrum-to-spectrum variations of the fiber optic setup lead to higher noise of estimated (i.e., unknown) POX and PenV concentrations than was found for the conduit setup. It seems that trade-off has to be made between ease of handling (fiber optic setup) and measurement accuracy (optical conduit setup) when choosing one of these systems for bioprocess monitoring. © The Author(s) 2016.

Photographic infrared spectroscopy and near infrared photometry of Be stars

International Nuclear Information System (INIS)

Swings, J.P.

1976-01-01

Two topics are tackled in this presentation: spectroscopy and photometry. The following definitions are chosen: photographic infrared spectroscopy (wavelengths Hα<=lambda<1.2 μ); near infrared photometry (wavebands: 1.6 μ<=lambda<=20 μ). Near infrared spectroscopy and photometry of classical and peculiar Be stars are discussed and some future developments in the field are outlined. (Auth.)

A multilevel multispectral data set analysis in the visible and infrared wavelength regions. [for land use remote sensing

Science.gov (United States)

Biehl, L. L.; Silva, L. F.

1975-01-01

Skylab multispectral scanner data, digitized Skylab color infrared (IR) photography, digitized Skylab black and white multiband photography, and Earth Resources Technology Satellite (ERTS) multispectral scanner data collected within a 24-hr time period over an area in south-central Indiana near Bloomington on June 9 and 10, 1973, were compared in a machine-aided land use analysis of the area. The overall classification performance results, obtained with nine land use classes, were 87% correct classification using the 'best' 4 channels of the Skylab multispectral scanner, 80% for the channels on the Skylab multispectral scanner which are spectrally comparable to the ERTS multispectral scanner, 88% for the ERTS multispectral scanner, 83% for the digitized color IR photography, and 76% for the digitized black and white multiband photography. The results indicate that the Skylab multispectral scanner may yield even higher classification accuracies when a noise-filtered multispectral scanner data set becomes available in the near future.

Interstellar extinction and polarization in the infrared

International Nuclear Information System (INIS)

Martin, P.G.; Whittet, D.C.B.

1990-01-01

The wavelength dependences of interstellar continuum extinction and polarization in the range 0.35-5 microns are examined. The existence of a universal extinction curve with power law index of about 1.8 extending from the near-IR to at least 5 microns appears to be established for both diffuse and dense cloud dust. The polarization yields evidence for some degree of universality in the 1.6-5 micron regime which may be represented by a power law with index 1.5-2.0, encompassing that for extinction. The form of the polarization curve in the IR seems independent of the wavelength at which the degree of polarization peaks in the optical, implying that variations in that wavelength are caused by changes in the optical properties of the particle at blue-visible rather than IR wavelengths. It is argued that the more significant alterations of the grain size distribution from one environment to another occur for the smaller particles. 47 refs

Influences of Pinpoint Plantar Long-Wavelength Infrared Light Irradiation (Stress-Free Therapy on Chorioretinal Hemodynamics, Atherosclerosis Factors, and Vascular Endothelial Growth Factor

Directory of Open Access Journals (Sweden)

Keisou Ishimaru

2018-03-01

Full Text Available Background: We previously reported that pinpoint plantar long-wavelength infrared light irradiation (stress-free therapy; SFT is useful for alleviating insulin resistance and improving intracranial blood flow in patients with type 2 diabetes mellitus. This study was undertaken to evaluate the influences of SFT on chorioretinal hemodynamics (retinal artery and vein blood flows as well as atherosclerosis-related factors (TG, LDL-C and VEGF in patients with dyslipidemia. Methods: Four patients with dyslipidemia received 15-minute irradiation with a stress-free apparatus (far-infrared wavelength, 30 mW. Using laser speckle flowgraphy, associations of chorioretinal blood flow with peripheral atherosclerosis-inducing factors/VEGF levels before and after irradiation were analyzed. Results: Chorioretinal blood flow increased, while TG/LDL-C levels decreased, after irradiation. VEGF tended to rise in cases with pre-irradiation baseline levels at the lower limit but tended to decrease in cases in which baseline levels had exceeded the normal range. Conclusion: SFT was suggested to enhance chorioretinal circulation and to normalize VEGF, thereby possibly contributing to amelioration of atherosclerosis-inducing factors. Abnormalities in chorioretinal hemodynamics are known to be highly involved in the pathophysiology of diabetic retinopathy and age-related macular degeneration, and anti-VEGF antibody has been used for treating these conditions. The necessity of risk management, involving chorioretinal blood flow, has been pointed out when dealing with central retinal vein occlusion, diabetes mellitus, ischemic cerebral/cardiac disease, dementia and so on. SFT is therefore a potential complementary medical strategy which can be expected to contribute to normalization of chorioretinal blood flow and atherosclerosis-inducing factors/VEGF levels, and thereby to the prevention of lifestyle-related chronic diseases. Keywords: Pinpoint plantar long-wavelength

Design analysis of doped-silicon surface plasmon resonance immunosensors in mid-infrared range.

Science.gov (United States)

DiPippo, William; Lee, Bong Jae; Park, Keunhan

2010-08-30

This paper reports the design analysis of a microfabricatable mid-infrared (mid-IR) surface plasmon resonance (SPR) sensor platform. The proposed platform has periodic heavily doped profiles implanted into intrinsic silicon and a thin gold layer deposited on top, making a physically flat grating SPR coupler. A rigorous coupled-wave analysis was conducted to prove the design feasibility, characterize the sensor's performance, and determine geometric parameters of the heavily doped profiles. Finite element analysis (FEA) was also employed to compute the electromagnetic field distributions at the plasmon resonance. Obtained results reveal that the proposed structure can excite the SPR on the normal incidence of mid-IR light, resulting in a large probing depth that will facilitate the study of larger analytes. Furthermore, the whole structure can be microfabricated with well-established batch protocols, providing tunability in the SPR excitation wavelength for specific biosensing needs with a low manufacturing cost. When the SPR sensor is to be used in a Fourier-transform infrared (FTIR) spectroscopy platform, its detection sensitivity and limit of detection are estimated to be 3022 nm/RIU and ~70 pg/mm(2), respectively, at a sample layer thickness of 100 nm. The design analysis performed in the present study will allow the fabrication of a tunable, disposable mid-IR SPR sensor that combines advantages of conventional prism and metallic grating SPR sensors.

Fourier transform infrared spectra applications to chemical systems

CERN Document Server

Ferraro, John R

1978-01-01

Fourier Transform Infrared Spectroscopy: Applications to Chemical Systems presents the chemical applications of the Fourier transform interferometry (FT-IR).The book contains discussions on the applications of FT-IR in the fields of chromatography FT-IR, polymers and biological macromolecules, emission spectroscopy, matrix isolation, high-pressure interferometry, and far infrared interferometry. The final chapter is devoted to the presentation of the use of FT-IR in solving national technical problems such as air pollution, space exploration, and energy related subjects.Researc

Fulfilling the pedestrian protection directive using a long-wavelength infrared camera designed to meet both performance and cost targets

Science.gov (United States)

Källhammer, Jan-Erik; Pettersson, Håkan; Eriksson, Dick; Junique, Stéphane; Savage, Susan; Vieider, Christian; Andersson, Jan Y.; Franks, John; Van Nylen, Jan; Vercammen, Hans; Kvisterøy, Terje; Niklaus, Frank; Stemme, Göran

2006-04-01

Pedestrian fatalities are around 15% of the traffic fatalities in Europe. A proposed EU regulation requires the automotive industry to develop technologies that will substantially decrease the risk for Vulnerable Road Users when hit by a vehicle. Automatic Brake Assist systems, activated by a suitable sensor, will reduce the speed of the vehicle before the impact, independent of any driver interaction. Long Wavelength Infrared technology is an ideal candidate for such sensors, but requires a significant cost reduction. The target necessary for automotive serial applications are well below the cost of systems available today. Uncooled bolometer arrays are the most mature technology for Long Wave Infrared with low-cost potential. Analyses show that sensor size and production yield along with vacuum packaging and the optical components are the main cost drivers. A project has been started to design a new Long Wave Infrared system with a ten times cost reduction potential, optimized for the pedestrian protection requirement. It will take advantage of the progress in Micro Electro-Mechanical Systems and Long Wave Infrared optics to keep the cost down. Deployable and pre-impact braking systems can become effective alternatives to passive impact protection systems solutions fulfilling the EU pedestrian protection regulation. Low-cost Long Wave Infrared sensors will be an important enabler to make such systems cost competitive, allowing high market penetration.

Enhanced Plasmonic Wavelength Selective Infrared Emission Combined with Microheater

Directory of Open Access Journals (Sweden)

Hiroki Ishihara

2017-09-01

Full Text Available The indirect wavelength selective thermal emitter that we have proposed is constructed using a new microheater, demonstrating the enhancement of the emission peak generated by the surface plasmon polariton. The thermal isolation is improved using a 2 μm-thick Si membrane having 3.6 and 5.4 mm outer diameter. The emission at around the wavelength of the absorption band of CO2 gas is enhanced. The absorption signal increases, confirming the suitability for gas sensing. Against input power, the intensity at the peak wavelength shows a steeper increasing ratio than the background intensity. The microheater with higher thermal isolation gives larger peak intensity and its increasing ratio against the input power.

Conceptual thermal design and analysis of a far-infrared/mid-infrared remote sensing instrument

Science.gov (United States)

Roettker, William A.

1992-07-01

This paper presents the conceptual thermal design and analysis results for the Spectroscopy of the Atmosphere using Far-Infrared Emission (SAFIRE) instrument. SAFIRE has been proposed for Mission to Planet Earth to study ozone chemistry in the middle atmosphere using remote sensing of the atmosphere in the far-infrared (21-87 microns) and mid-infrared (9-16 microns) spectra. SAFIRE requires that far-IR detectors be cooled to 3-4 K and mid-IR detectors to 80 K for the expected mission lifetime of five years. A superfluid helium dewar and Stirling-cycle cryocoolers provide the cryogenic temperatures required by the infrared detectors. The proposed instrument thermal design uses passive thermal control techniques to reject 465 watts of waste heat from the instrument.

Study on Senna alata and its different extracts by Fourier transform infrared spectroscopy and two-dimensional correlation infrared spectroscopy

Science.gov (United States)

Adiana, M. A.; Mazura, M. P.

2011-04-01

Senna alata L. commonly known as candle bush belongs to the family of Fabaceae and the plant has been reported to possess anti-inflammatory, analgesic, laxative and antiplatelet-aggregating activity. In order to develop a rapid and effective analysis method for studying integrally the main constituents in the medicinal materials and their extracts, discriminating the extracts from different extraction process, comparing the categories of chemical constituents in the different extracts and monitoring the qualities of medicinal materials, we applied Fourier transform infrared spectroscopy (FT-IR) associated with second derivative infrared spectroscopy and two-dimensional infrared correlation spectroscopy (2D-IR) to study the main constituents of S. alata and its different extracts (extracted by hexane, dichloromethane, ethyl acetate and methanol in turn). The findings indicated that FT-IR and 2D-IR can provide many holistic variation rules of chemical constituents. Use of the macroscopical fingerprint characters of FT-IR and 2D-IR spectrum can identify the main chemical constituents in medicinal materials and their extracts, but also compare the components differences among similar samples. In a conclusion, FT-IR spectroscopy combined with 2D correlation analysis provides a powerful method for the quality control of traditional medicines.

Near-infrared sources in the molecular cloud G35.2-0.74

International Nuclear Information System (INIS)

Tapia, M.; Roth, M.; Persi, P.; Ferrari-Toniolo, M.

1985-01-01

Near-infrared (1-4 μm) observations of the molecular cloud G35.2-0.74 reveal the presence of four infrared sources in the vicinity of two previously reported centres of recent star formation. The northern part of G35.2-0.74 contains three point sources which are interpreted as highly obscured stars. Irs 1 coincides with H 2 O and OH maser sources and seems to be a very young early-type star. The southern part of G35.2-0.74 shows a diffuse 2.2-μm source with a flux distribution in the short-wavelength region compatible with free-free emission and a large excess at lambda > or approx. 3 μm attributed to warm dust mixed with the gas. These data are consistent with a fully developed HII region. (author)

UV, visible and IR laser interaction with gelatine

International Nuclear Information System (INIS)

Oujja, M; Rebollar, E; Abrusci, C; Amo, A Del; Catalina, F; Castillejo, M

2007-01-01

In this work we investigate the effects on gelatine films of nanosecond pulsed laser irradiation at different laser wavelengths from the UV to the IR at 248, 266, 355, 532 and 1064 nm. We compared gelatines differing in gel strength values (Bloom 75 and 225) and in crosslinking degree. Formation of bubbles at the wavelengths in the UV (248 and 266 nm), melting and resolidification at 355 nm, and formation of craters by ablation in the VIS and IR (532 and 1064 nm) are the observed morphological changes. On the other hand, changes of the fluorescence behaviour of the films upon UV irradiation reveal chemical modifications of photolabile chromophores

Modeling the Infrared Reverberation Response of the Circumnuclear Dusty Torus in AGNs: The Effects of Cloud Orientation and Anisotropic Illumination

International Nuclear Information System (INIS)

Almeyda, Triana; Robinson, Andrew; Richmond, Michael; Vazquez, Billy; Nikutta, Robert

2017-01-01

The obscuring circumnuclear torus of dusty molecular gas is one of the major components of active galactic nuclei (AGN). The torus can be studied by analyzing the time response of its infrared (IR) dust emission to variations in the AGN continuum luminosity, a technique known as reverberation mapping. The IR response is the convolution of the AGN ultraviolet/optical light curve with a transfer function that contains information about the size, geometry, and structure of the torus. Here, we describe a new computer model that simulates the reverberation response of a clumpy torus. Given an input optical light curve, the code computes the emission of a 3D ensemble of dust clouds as a function of time at selected IR wavelengths, taking into account light travel delays. We present simulated dust emission responses at 3.6, 4.5, and 30 μ m that explore the effects of various geometrical and structural properties, dust cloud orientation, and anisotropy of the illuminating radiation field. We also briefly explore the effects of cloud shadowing (clouds are shielded from the AGN continuum source). Example synthetic light curves have also been generated, using the observed optical light curve of the Seyfert 1 galaxy NGC 6418 as input. The torus response is strongly wavelength-dependent, due to the gradient in cloud surface temperature within the torus, and because the cloud emission is strongly anisotropic at shorter wavelengths. Anisotropic illumination of the torus also significantly modifies the torus response, reducing the lag between the IR and optical variations.

Modeling the Infrared Reverberation Response of the Circumnuclear Dusty Torus in AGNs: The Effects of Cloud Orientation and Anisotropic Illumination

Energy Technology Data Exchange (ETDEWEB)

Almeyda, Triana; Robinson, Andrew; Richmond, Michael; Vazquez, Billy [School of Physics and Astronomy, Rochester Institute of Technology, Rochester, NY 14623 (United States); Nikutta, Robert, E-mail: tra3595@rit.edu [National Optical Astronomy Observatory, 950 N Cherry Ave, Tucson, AZ 85719 (United States)

2017-07-01

The obscuring circumnuclear torus of dusty molecular gas is one of the major components of active galactic nuclei (AGN). The torus can be studied by analyzing the time response of its infrared (IR) dust emission to variations in the AGN continuum luminosity, a technique known as reverberation mapping. The IR response is the convolution of the AGN ultraviolet/optical light curve with a transfer function that contains information about the size, geometry, and structure of the torus. Here, we describe a new computer model that simulates the reverberation response of a clumpy torus. Given an input optical light curve, the code computes the emission of a 3D ensemble of dust clouds as a function of time at selected IR wavelengths, taking into account light travel delays. We present simulated dust emission responses at 3.6, 4.5, and 30 μ m that explore the effects of various geometrical and structural properties, dust cloud orientation, and anisotropy of the illuminating radiation field. We also briefly explore the effects of cloud shadowing (clouds are shielded from the AGN continuum source). Example synthetic light curves have also been generated, using the observed optical light curve of the Seyfert 1 galaxy NGC 6418 as input. The torus response is strongly wavelength-dependent, due to the gradient in cloud surface temperature within the torus, and because the cloud emission is strongly anisotropic at shorter wavelengths. Anisotropic illumination of the torus also significantly modifies the torus response, reducing the lag between the IR and optical variations.

Characterization of process-induced damage in Cu/low-k interconnect structure by microscopic infrared spectroscopy with polarized infrared light

Energy Technology Data Exchange (ETDEWEB)

Seki, Hirofumi, E-mail: Hirofumi-Seki@trc.toray.co.jp; Hashimoto, Hideki [Toray Research Center, Inc., 3-3-7 Sonoyama, Otsu, Shiga 520-8567 (Japan); Ozaki, Yukihiro [Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1, Gakuen, Sanda, Hyogo 669-1337 (Japan)

2016-09-07

Microscopic Fourier-transform infrared (FT-IR) spectra are measured for a Cu/low-k interconnect structure using polarized IR light for different widths of low-k spaces and Cu lines, and for different heights of Cu lines, on Si substrates. Although the widths of the Cu line and the low-k space are 70 nm each, considerably smaller than the wavelength of the IR light, the FT-IR spectra of the low-k film were obtained for the Cu/low-k interconnect structure. A suitable method was established for measuring the process-induced damage in a low-k film that was not detected by the TEM-EELS (Transmission Electron Microscope-Electron Energy-Loss Spectroscopy) using microscopic IR polarized light. Based on the IR results, it was presumed that the FT-IR spectra mainly reflect the structural changes in the sidewalls of the low-k films for Cu/low-k interconnect structures, and the mechanism of generating process-induced damage involves the generation of Si-OH groups in the low-k film when the Si-CH{sub 3} bonds break during the fabrication processes. The Si-OH groups attract moisture and the OH peak intensity increases. It was concluded that the increase in the OH groups in the low-k film is a sensitive indicator of low-k damage. We achieved the characterization of the process-induced damage that was not detected by the TEM-EELS and speculated that the proposed method is applicable to interconnects with line and space widths of 70 nm/70 nm and on shorter scales of leading edge devices. The location of process-induced damage and its mechanism for the Cu/low-k interconnect structure were revealed via the measurement method.

Mid infrared resonant cavity detectors and lasers with epitaxial lead-chalcogenides

Science.gov (United States)

Zogg, H.; Rahim, M.; Khiar, A.; Fill, M.; Felder, F.; Quack, N.

2010-09-01

Wavelength tunable emitters and detectors in the mid-IR wavelength region allow applications including thermal imaging and gas spectroscopy. One way to realize such tunable devices is by using a resonant cavity. By mechanically changing the cavity length with MEMS mirror techniques, the wavelengths may be tuned over a considerable range. Resonant cavity enhanced detectors (RCED) are sensitive at the cavity resonance only. They may be applied for low resolution spectroscopy, and, when arrays of such detectors are realized, as multicolour IR-FPA or "IR-AFPA", adaptive focal plane arrays. We report the first room temperature mid-IR VECSEL (vertical external cavity surface emitting laser) with a wavelength above 3 μm. The active region is just 850 nm PbSe, followed by a 2.5 pair Bragg mirror. Output power is > 10 mW at RT.

Discrimination of different red wine by Fourier-transform infrared and two-dimensional infrared correlation spectroscopy

Science.gov (United States)

Zhang, Yan-ling; Chen, Jian-bo; Lei, Yu; Zhou, Qun; Sun, Su-qin; Noda, Isao

2010-06-01

Fourier-transform infrared spectroscopy (FT-IR) and two-dimensional infrared (2D IR) correlation spectroscopy were applied to analyze main components of liquid red wine with different sugar contents and volatilization residues of dry red wine from different manufactures. The infrared spectra, second derivative spectra of dry red wine show the typical peaks of alcohol, while the spectra of sweet wine are composed of the peaks of both alcohol and sugar, and the contribution of sugar enhanced as the increase of sugar content. Using principal component analysis (PCA) method, dry and sweet wine can be readily classified. Analysis of the infrared spectra of the volatilization residues of dry red wine samples from five different manufactures indicates that dry red wine may be composed of glycerol, carboxylic acids or esters and carboxyl ate, at the same time, different dry red wine show different characteristic peaks in the second derivative spectra and 2D IR correlation spectra, which can be used to discriminate the different manufactures and evaluate the quality of wine samples. The results suggested that infrared spectroscopy is a direct and effective method for the analysis of principle components of different red wines and discrimination of different red wines.

Peak response wavelengths of p- and n-type InxGa1-xAs-InP quantum well infrared photodetectors

International Nuclear Information System (INIS)

Fu, Y.; Willander, M.; Sengupta, D.K.

2005-01-01

p- and n-type In x Ga 1-x As-InP quantum wells are suitable for multi-color infrared photodetector applications in atmospheric windows due to improved barrier quality and carrier-transport properties. We apply the k.p method to study the energy band structures and optical transition properties, which show that the peak response wavelengths of p- and n-type In x Ga 1-x As-InP quantum well infrared photodetectors (QWIPs) are determined not only by the energy distance from the ground sublevels in the quantum well to the energy band edges of extended states, but also by the characteristics of the extended states. The optical phonon scattering process converts the broad absorption spectrum of the p-QWIP from 0 to 16 μm into a short-wavelength spectrum centered at 4.5 μm. The transport of electrons in the extended states of the n-QWIP is characterized by running wave boundary conditions, resulting in a theoretically optimal absorption rate by a 8-nm-thick In 0.53 Ga 0.47 As quantum well. Moreover, a conduction-band offset of 0.5 for an In x Ga 1-x As-InP (x=0.53) heterostructure gives the best data fitting of theoretical and experimental response peaks, whereas 0.55 is generally recommended in the literature. (orig.)

Comparative investigation of Fourier transform infrared (FT-IR) spectroscopy and X-ray diffraction (XRD) in the determination of cotton fiber crystallinity.

Science.gov (United States)

Liu, Yongliang; Thibodeaux, Devron; Gamble, Gary; Bauer, Philip; VanDerveer, Don

2012-08-01

Despite considerable efforts in developing curve-fitting protocols to evaluate the crystallinity index (CI) from X-ray diffraction (XRD) measurements, in its present state XRD can only provide a qualitative or semi-quantitative assessment of the amounts of crystalline or amorphous fraction in a sample. The greatest barrier to establishing quantitative XRD is the lack of appropriate cellulose standards, which are needed to calibrate the XRD measurements. In practice, samples with known CI are very difficult to prepare or determine. In a previous study, we reported the development of a simple algorithm for determining fiber crystallinity information from Fourier transform infrared (FT-IR) spectroscopy. Hence, in this study we not only compared the fiber crystallinity information between FT-IR and XRD measurements, by developing a simple XRD algorithm in place of a time-consuming and subjective curve-fitting process, but we also suggested a direct way of determining cotton cellulose CI by calibrating XRD with the use of CI(IR) as references.

Analysis of polymer foil heaters as infrared radiation sources

International Nuclear Information System (INIS)

Witek, Krzysztof; Piotrowski, Tadeusz; Skwarek, Agata

2012-01-01

Infrared radiation as a heat source is used in many fields. In particular, the positive effect of far-infrared radiation on living organisms has been observed. This paper presents two technological solutions for infrared heater production using polymer-silver and polymer-carbon pastes screenprinted on foil substrates. The purpose of this work was the identification of polymer layers as a specific frequency range IR radiation sources. The characterization of the heaters was determined mainly by measurement of the surface temperature distribution using a thermovision camera and the spectral characteristics were determined using a special measuring system. Basic parameters obtained for both, polymer silver and polymer carbon heaters were similar and were as follows: power rating of 10–12 W/dm 2 , continuous working surface temperature of 80–90 °C, temperature coefficient of resistance (TCR) about +900 ppm/K for polymer-carbon heater and about +2000 ppm/K for polymer-silver, maximum radiation intensity in the wavelength range of 6–14 μm with top intensity at 8.5 μm and heating time about 20 min. For comparison purposes, commercial panel heater was tested. The results show that the characteristics of infrared polymer heaters are similar to the characteristics of the commercial heater, so they can be taken into consideration as the alternative infrared radiation sources.

Mid-infrared, long wave infrared (4-12 μm) molecular emission signatures from pharmaceuticals using laser-induced breakdown spectroscopy (LIBS).

Science.gov (United States)

Yang, Clayton S-C; Brown, Ei E; Kumi-Barimah, Eric; Hommerich, Uwe H; Jin, Feng; Trivedi, Sudhir B; Samuels, Alan C; Snyder, A Peter

2014-01-01

In an effort to augment the atomic emission spectra of conventional laser-induced breakdown spectroscopy (LIBS) and to provide an increase in selectivity, mid-wave to long-wave infrared (IR), LIBS studies were performed on several organic pharmaceuticals. Laser-induced breakdown spectroscopy signature molecular emissions of target organic compounds are observed for the first time in the IR fingerprint spectral region between 4-12 μm. The IR emission spectra of select organic pharmaceuticals closely correlate with their respective standard Fourier transform infrared spectra. Intact and/or fragment sample molecular species evidently survive the LIBS event. The combination of atomic emission signatures derived from conventional ultraviolet-visible-near-infrared LIBS with fingerprints of intact molecular entities determined from IR LIBS promises to be a powerful tool for chemical detection.

Copernicus spectra and infrared photometry of 42 Orionis

International Nuclear Information System (INIS)

Johnson, H.M.; Snow, T.P. Jr.; Gehrz, R.D.; Hackwell, J.A.

1977-01-01

The Orion sword star 42 Ori is embedded in a nebula north of and separated from the Orion nebula. The B1 V star is probably normal. Other members of the multiple remain poorly defined, and the nebula may exhibit some peculiarities that may depend on them. Copernicus ultraviolet spectra of the star are described here, especially in the form of tables of wavelength identifications. The properties of the interstellar material in the line of sight are also discussed. We present infrared photometry which suggests that 3 less than or equal to R less than or equal to 3.5 for the interstellar matter in the direction of 42 Ori. The IR photometry provides no evidence for companion stellar or circumstellar components

Wavelength dependence of laser induced breakdown spectroscopy (LIBS) on questioned document investigation.

Science.gov (United States)

Elsherbiny, Nany; Aied Nassef, O

2015-07-01

The fast and nearly non-destructive criteria of laser induced breakdown spectroscopy (LIBS) technique has been exploited for forensic purposes, specifically, document investigation. The dependence of the optical emission spectra of different black gel ink samples on the excitation laser wavelength, namely the visible wavelength at λ=532 nm and the IR wavelength at λ=1064 nm, was studied. The inks of thirty black gel-ink pens comprising ten brands were analyzed to determine the variation of the chemical composition of ink and to discriminate among them with minimum mass removal and minimum damage to the document's paper. Under the adopted experimental conditions, the ability of the visible LIBS to differentiate among the different ink samples was successful compared to IR LIBS at the same laser pulse energy (~25 mJ/pulse, laser fluence is ~1400J·cm(-2) for visible laser and ~1100J·cm(-2) for IR laser) which could be attributed to the IR absorption effects by the black ink. However, the visible LIBS produces deeper crater with respect to that produced by IR LIBS. Applying IR LIBS with higher pulse energy of ~87mJ (laser fluence is ~4100J·cm(-2)), identification and differentiation of the adopted samples was performed with producing a larger-diameter but superficial crater. The plasma parameters are discussed at the adopted experimental conditions. The results support the potential of LIBS technique using both the visible and IR lasers to be commercially developed for forensic document examination. Copyright © 2015 Forensic Science Society. Published by Elsevier Ireland Ltd. All rights reserved.

Analysis of albumin Raman scattering in visible and near-infrared ranges

Science.gov (United States)

Lykina, Anastasia A.; Artemyev, Dmitry N.

2018-04-01

In this work the analysis of the shape and intensity of albumin Raman signals in visible and near-IR ranges was carried out. The experimental setup using lasers from the visible region first of all excites the fluorescence of the albumin solution, the main contribution to which is produced by sodium chloride, which is a component of the tested sample. At the same time, lasers from the near-infrared range excited the Raman signal of albumin most effectively. It was found that the highest ratio of Raman scattering to autofluorescence intensities in the detected signal was obtained using a laser with a wavelength of 1064 nm. To determine the albumin solution concentration by type of spectrum, a regression approach with the projection to latent structures method was applied. The lowest predicted error of albumin concentration of 2-3 g/l was obtained by using the near-infrared range lasers.

Using IR Imaging of Water Surfaces for Estimating Piston Velocities

Science.gov (United States)

Gålfalk, M.; Bastviken, D.; Arneborg, L.

2013-12-01

The transport of gasses dissolved in surface waters across the water-atmosphere interface is controlled by the piston velocity (k). This coefficient has large implications for, e.g., greenhouse gas fluxes but is challenging to quantify in situ. At present, empirical k-wind speed relationships from a small number of studies and systems are often extrapolated without knowledge of model performance. It is therefore of interest to search for new methods for estimating k, and to compare the pros and cons of existing and new methods. Wind speeds in such models are often measured at a height of 10 meters. In smaller bodies of water such as lakes, wind speeds can vary dramatically across the surface through varying degrees of wind shadow from e.g. trees at the shoreline. More local measurements of the water surface, through wave heights or surface motion mapping, could give improved k-estimates over a surface, also taking into account wind fetch. At thermal infrared (IR) wavelengths water has very low reflectivity (depending on viewing angle) than can go below 1%, meaning that more than 99% is heat radiation giving a direct measurement of surface temperature variations. Using an IR camera at about 100 frames/s one could map surface temperature structures at a fraction of a mm depth even with waves present. In this presentation I will focus on IR imaging as a possible tool for estimating piston velocities. Results will be presented from IR field measurements, relating the motions of surface temperature structures to k calculated from other simultaneous measurements (flux chamber and ADV-Based Dissipation Rate), but also attempting to calculate k directly from the IR surface divergence. A relation between wave height and k will also be presented.

Experimental comparison of performance degradation from terahertz and infrared wireless links in fog.

Science.gov (United States)

Su, Ke; Moeller, Lothar; Barat, Robert B; Federici, John F

2012-02-01

We describe a lab setup for analyzing impairments of terahertz (THz) and infrared (IR) free space links caused by local refraction index changes in the signal's propagation paths that could be induced by turbulence, particles, humidity, etc. A THz signal comprising a 2.5 Gb/s data load modulated on a carrier at 625 GHz, is launched through a weather emulating chamber, detected, and its performance analyzed. An IR beam at 1.5 um wavelength carrying the same data load is superposed with the THz beam, propagating through the same weather conditions and also performance analyzed. We modulate the IR channel with a usual non-return-to-zero (NRZ) format but use duobinary coding for driving our THz source, which enables signaling at high data rate and higher output power. As both beams pass through the same channel perturbations and as their degradations are recorded simultaneously we can simultaneously compare the weather impact on both. We investigate scintillation and fog attenuation effects for the THz and IR signals by measuring bit error rates (BER), signal power, and phase front distortions. © 2012 Optical Society of America

Mid-infrared nonlinear upconversion imaging and sensing

DEFF Research Database (Denmark)

Pedersen, Christian; Tidemand-Lichtenberg, Peter

2016-01-01

The mid-IR wavelength range is highly relevant for a number of applications related to gas spectroscopy and spectral analysis of complex molecules such as those including CH bounds. The main obstacles for exploitation of mid-IR applications include suitable and affordable mid-IR light sources...

Rapid, nondestructive estimation of surface polymer layer thickness using attenuated total reflection fourier transform infrared (ATR FT-IR) spectroscopy and synthetic spectra derived from optical principles.

Science.gov (United States)

Weinstock, B André; Guiney, Linda M; Loose, Christopher

2012-11-01

We have developed a rapid, nondestructive analytical method that estimates the thickness of a surface polymer layer with high precision but unknown accuracy using a single attenuated total reflection Fourier transform infrared (ATR FT-IR) measurement. Because the method is rapid, nondestructive, and requires no sample preparation, it is ideal as a process analytical technique. Prior to implementation, the ATR FT-IR spectrum of the substrate layer pure component and the ATR FT-IR and real refractive index spectra of the surface layer pure component must be known. From these three input spectra a synthetic mid-infrared spectral matrix of surface layers 0 nm to 10,000 nm thick on substrate is created de novo. A minimum statistical distance match between a process sample's ATR FT-IR spectrum and the synthetic spectral matrix provides the thickness of that sample. We show that this method can be used to successfully estimate the thickness of polysulfobetaine surface modification, a hydrated polymeric surface layer covalently bonded onto a polyetherurethane substrate. A database of 1850 sample spectra was examined. Spectrochemical matrix-effect unknowns, such as the nonuniform and molecularly novel polysulfobetaine-polyetherurethane interface, were found to be minimal. A partial least squares regression analysis of the database spectra versus their thicknesses as calculated by the method described yielded an estimate of precision of ±52 nm.

The gas-rich circumbinary disk of HR 4049. I. A detailed study of the mid-infrared spectrum

Energy Technology Data Exchange (ETDEWEB)

Malek, S. E.; Cami, J., E-mail: sarahemalek@gmail.com, E-mail: jcami@uwo.ca [Department of Physics and Astronomy, University of Western Ontario, London, ON N6A 3K7 (Canada)

2014-01-01

We present a detailed analysis of the mid-infrared spectrum of the peculiar evolved object HR 4049. The full Spitzer-IRS high-resolution spectrum shows a wealth of emission with prominent features from CO{sub 2} and H{sub 2}O and possible contributions from HCN and OH. We model the molecular emission and find that it originates from a massive (M ≳ 8 × 10{sup –3} M {sub ☉}), warm (T {sub ex} ≈ 500 K) and radially extended gas disk that is optically thick at infrared wavelengths. We also report less enrichment in {sup 17}O and {sup 18}O than previously found and a comparison of the Spitzer observations to earlier data obtained by the Short Wavelength Spectrometer on board the Infrared Space Observatory reveals that the CO{sub 2} flux has more than doubled in 10 yr time, indicating active and ongoing chemical evolution in the circumbinary disk. If the gas originates from interaction between the stellar wind and the dust, this suggests that the dust could be oxygen-rich in nature. The molecular gas plays a crucial role in the thermal properties of the circumbinary disk by allowing visible light to heat the dust and then trapping the infrared photons emitted by the dust. This results in higher temperatures and a more homogeneous temperature structure in the disk.

Differentiation of different mixed Listeria strains and also acid-injured, heat-injured, and repaired cells of Listeria monocytogenes using fourier transform infrared spectroscopy.

Science.gov (United States)

Nyarko, Esmond; Donnelly, Catherine

2015-03-01

Fourier transform infrared (FT-IR) spectroscopy was used to differentiate mixed strains of Listeria monocytogenes and mixed strains of L. monocytogenes and Listeria innocua. FT-IR spectroscopy was also applied to investigate the hypothesis that heat-injured and acid-injured cells would return to their original physiological integrity following repair. Thin smears of cells on infrared slides were prepared from cultures for mixed strains of L. monocytogenes, mixed strains of L. monocytogenes and L. innocua, and each individual strain. Heat-injured and acid-injured cells were prepared by exposing harvested cells of L. monocytogenes strain R2-764 to a temperature of 56 ± 0.2°C for 10 min or lactic acid at pH 3 for 60 min, respectively. Cellular repair involved incubating aliquots of acid-injured and heat-injured cells separately in Trypticase soy broth supplemented with 0.6% yeast extract for 22 to 24 h; bacterial thin smears on infrared slides were prepared for each treatment. Spectral collection was done using 250 scans at a resolution of 4 cm(-1) in the mid-infrared wavelength region. Application of multivariate discriminant analysis to the wavelength region from 1,800 to 900 cm(-1) separated the individual L. monocytogenes strains. Mixed strains of L. monocytogenes and L. monocytogenes cocultured with L. innocua were successfully differentiated from the individual strains when the discriminant analysis was applied. Different mixed strains of L. monocytogenes were also successfully separated when the discriminant analysis was applied. A data set for injury and repair analysis resulted in the separation of acid-injured, heat-injured, and intact cells; repaired cells clustered closer to intact cells when the discriminant analysis (1,800 to 600 cm(-1)) was applied. FT-IR spectroscopy can be used for the rapid source tracking of L. monocytogenes strains because it can differentiate between different mixed strains and individual strains of the pathogen.

THE MID-INFRARED EVOLUTION OF THE FU ORIONIS DISK

Energy Technology Data Exchange (ETDEWEB)

Green, Joel D.; Jones, Olivia C.; Poteet, Charles A.; Sargent, Benjamin A. [Space Telescope Science Institute, Baltimore, MD 21218 (United States); Keller, Luke D. [Department of Physics and Astronomy, Ithaca College, Ithaca, NY (United States); Yang, Yao-Lun; Evans II, Neal J. [Department of Astronomy, The University of Texas at Austin, Austin, TX 78712 (United States); Fischer, William J. [Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Rebull, Luisa M. [IPAC, Pasadena, CA 91125 (United States)

2016-11-20

We present new SOFIA-FORCAST observations obtained in 2016 February of the archetypal outbursting low-mass young stellar object FU Orionis, and we compare the continuum, solid-state, and gas properties with mid-infrared data obtained at the same wavelengths in 2004 with Spitzer -IRS. In this study, we conduct the first mid-infrared spectroscopic comparison of an FUor over a long time period. Over a 12-year period, UBVR monitoring indicates that FU Orionis has continued its steady decrease in overall brightness by ∼14%. We find that this decrease in luminosity occurs only at wavelengths ≲20 μ m. In particular, the continuum shortward of the silicate emission complex at 10 μ m exhibits a ∼12% (∼3 σ ) drop in flux density but no apparent change in slope; both the Spitzer and SOFIA spectra are consistent with a 7200 K blackbody. Additionally, the detection of water absorption is consistent with the Spitzer spectrum. The silicate emission feature at 10 μ m continues to be consistent with unprocessed grains, unchanged over 12 years. We conclude that either the accretion rate in FU Orionis has decreased by ∼12–14% over this time baseline or the inner disk has cooled, but the accretion disk remains in a superheated state outside the innermost region.

The Infrared Camera for RATIR, a Rapid Response GRB Followup Instrument

Science.gov (United States)

Rapchun, David A.; Alardin, W.; Bigelow, B. C.; Bloom, J.; Butler, N.; Farah, A.; Fox, O. D.; Gehrels, N.; Gonzalez, J.; Klein, C.; Kutyrev, A. S.; Lotkin, G.; Morisset, C.; Moseley, S. H.; Richer, M.; Robinson, F. D.; Samuel, M. V.; Sparr, L. M.; Tucker, C.; Watson, A.

2011-01-01

RATIR (Reionization and Transients Infrared instrument) will be a hybrid optical/near IR imager that will utilize the "J-band dropout" to rapidly identify very high redshift (VHR) gamma-ray bursts (GRBs) from a sample of all observable Swift bursts. Our group at GSFC is developing the instrument in collaboration with UC Berkeley (UCB) and University of Mexico (UNAM). RATIR has both a visible and IR camera, which give it access to 8 bands spanning visible and IR wavelengths. The instrument implements a combination of filters and dichroics to provide the capability of performing photometry in 4 bands simultaneously. The GSFC group leads the design and construction of the instrument's IR camera, equipped with two HgCdTe 2k x 2k Teledyne detectors. The cryostat housing these detectors is cooled by a mechanical cryo-compressor, which allows uninterrupted operation on the telescope. The host 1.5-m telescope, located at the UNAM San Pedro Martir Observatory, Mexico, has recently undergone robotization, allowing for fully automated, continuous operation. After commissioning in the spring of 2011, RATIR will dedicate its time to obtaining prompt follow-up observations of GRBs and identifying VHR GRBs, thereby providing a valuable tool for studying the epoch of reionization.

Infrared emission from protostars

International Nuclear Information System (INIS)

Adams, F.C.; Shu, F.H.

1985-01-01

The emergent spectral energy distribution at infrared to radio wavelengths is calculated for the simplest theoretical construct of a low-mass protostar. It is shown that the emergent spectrum in the infrared is insensitive to the details assumed for the temperature profile as long as allowance is made for a transition from optically thick to optically thin conditions and luminosity conservation isenforced at the inner and outer shells. The radiation in the far infrared and submillimeter wavelengths depends on the exact assumptions made for grain opacities at low frequencies. An atlas of emergent spectral energy distributions is presented for a grid of values of the instantaneous mass of the protostar and the mass infall rate. The attenuated contribution of the accretion shock to the near-infrared radiation is considered. 50 references

Selective treatment of carious dentin using a mid-infrared tunable pulsed laser at 6 μm wavelength range

Science.gov (United States)

Saiki, Masayuki; Ishii, Katsunori; Yoshikawa, Kazushi; Yasuo, Kenzo; Yamamoto, Kazuyo; Awazu, Kunio

2011-03-01

Optical technologies have good potential for caries detection, prevention, excavation, and the realization of minimal intervention dentistry. This study aimed to develop a selective excavation technique of carious tissue using the specific absorption in 6 μm wavelength range. Bovine dentin demineralized with lactic acid solution was used as a carious dentin model. A mid-infrared tunable pulsed laser was obtained by difference-frequency generation technique. The wavelength was tuned to 6.02 and 6.42 μm which correspond to absorption bands called amide I and amide II, respectively. The laser delivers 5 ns pulse width at a repetition rate of 10 Hz. The morphological change after irradiation was observed with a scanning electron microscope, and the measurement of ablation depth was performed with a confocal laser microscope. At λ = 6.02 μm and the average power density of 15 W/cm2, demineralized dentin was removed selectively with less-invasive effect on sound dentin. The wavelength of 6.42 μm also showed the possibility of selective removal. High ablation efficiency and low thermal side effect were observed using the nanosecond pulsed laser with λ = 6.02 μm. In the near future, development of compact laser device will open the minimal invasive laser treatment to the dental clinic.

Forensic Drug Identification, Confirmation, and Quantification Using Fully Integrated Gas Chromatography with Fourier Transform Infrared and Mass Spectrometric Detection (GC-FT-IR-MS).

Science.gov (United States)

Lanzarotta, Adam; Lorenz, Lisa; Voelker, Sarah; Falconer, Travis M; Batson, JaCinta S

2018-05-01

This manuscript is a continuation of a recent study that described the use of fully integrated gas chromatography with direct deposition Fourier transform infrared detection and mass spectrometric detection (GC-FT-IR-MS) to identify and confirm the presence of sibutramine and AB-FUBINACA. The purpose of the current study was to employ the GC-FT-IR portion of the same instrument to quantify these compounds, thereby demonstrating the ability to identify, confirm, and quantify drug substances using a single GC-FT-IR-MS unit. The performance of the instrument was evaluated by comparing quantitative analytical figures of merit to those measured using an established, widely employed method for quantifying drug substances, high performance liquid chromatography with ultraviolet detection (HPLC-UV). The results demonstrated that GC-FT-IR was outperformed by HPLC-UV with regard to sensitivity, precision, and linear dynamic range (LDR). However, sibutramine and AB-FUBINACA concentrations measured using GC-FT-IR were not significantly different at the 95% confidence interval compared to those measured using HPLC-UV, which demonstrates promise for using GC-FT-IR as a semi-quantitative tool at the very least. The most significant advantage of GC-FT-IR compared to HPLC-UV is selectivity; a higher level of confidence regarding the identity of the analyte being quantified is achieved using GC-FT-IR. Additional advantages of using a single GC-FT-IR-MS instrument for identification, confirmation, and quantification are efficiency, increased sample throughput, decreased consumption of laboratory resources (solvents, chemicals, consumables, etc.), and thus cost.

TES arrays for the short wavelength band of the SAFARI instrument on SPICA

Science.gov (United States)

Khosropanah, P.; Hijmering, R.; Ridder, M.; Gao, J. R.; Morozov, D.; Mauskopf, P. D.; Trappe, N.; O'Sullivan, C.; Murphy, A.; Griffin, D.; Goldie, D.; Glowacka, D.; Withington, S.; Jackson, B. D.; Audley, M. D.; de Lange, G.

2012-09-01

SPICA is an infra-red (IR) telescope with a cryogenically cooled mirror (~5K) with three instruments on board, one of which is SAFARI that is an imaging Fourier Transform Spectrometer (FTS) with three bands covering the wavelength of 34-210 μm. We develop transition edge sensors (TES) array for short wavelength band (34-60 μm) of SAFARI. These are based on superconducting Ti/Au bilayer as TES bolometers with a Tc of about 105 mK and thin Ta film as IR absorbers on suspended silicon nitride (SiN) membranes. These membranes are supported by long and narrow SiN legs that act as weak thermal links between the TES and the bath. Previously an electrical noise equivalent power (NEP) of 4×10-19 W/√Hz was achieved for a single pixel of such detectors. As an intermediate step toward a full-size SAFARI array (43×43), we fabricated several 8×9 detector arrays. Here we describe the design and the outcome of the dark and optical tests of several of these devices. We achieved high yield (<93%) and high uniformity in terms of critical temperature (<5%) and normal resistance (7%) across the arrays. The measured dark NEPs are as low as 5×10-19 W/√Hz with a response time of about 1.4 ms at preferred operating bias point. The optical coupling is implemented using pyramidal horns array on the top and hemispherical cavity behind the chip that gives a measured total optical coupling efficiency of 30±7%.

Ultraviolet versus infrared: Effects of ablation laser wavelength on the expansion of laser-induced plasma into one-atmosphere argon gas

International Nuclear Information System (INIS)

Ma Qianli; Motto-Ros, Vincent; Laye, Fabrice; Yu Jin; Lei Wenqi; Bai Xueshi; Zheng Lijuan; Zeng Heping

2012-01-01

Laser-induced plasma from an aluminum target in one-atmosphere argon background has been investigated with ablation using nanosecond ultraviolet (UV: 355 nm) or infrared (IR: 1064 nm) laser pulses. Time- and space-resolved emission spectroscopy was used as a diagnostics tool to have access to the plasma parameters during its propagation into the background, such as optical emission intensity, electron density, and temperature. The specific feature of nanosecond laser ablation is that the pulse duration is significantly longer than the initiation time of the plasma. Laser-supported absorption wave due to post-ablation absorption of the laser radiation by the vapor plume and the shocked background gas plays a dominant role in the propagation and subsequently the behavior of the plasma. We demonstrate that the difference in absorption rate between UV and IR radiations leads to different propagation behaviors of the plasma produced with these radiations. The consequence is that higher electron density and temperature are observed for UV ablation. While for IR ablation, the plasma is found with lower electron density and temperature in a larger and more homogenous axial profile. The difference is also that for UV ablation, the background gas is principally evacuated by the expansion of the vapor plume as predicted by the standard piston model. While for IR ablation, the background gas is effectively mixed to the ejected vapor at least hundreds of nanoseconds after the initiation of the plasma. Our observations suggest a description by laser-supported combustion wave for the propagation of the plasma produced by UV laser, while that by laser-supported detonation wave for the propagation of the plasma produced by IR laser. Finally, practical consequences of specific expansion behavior for UV or IR ablation are discussed in terms of analytical performance promised by corresponding plasmas for application with laser-induced breakdown spectroscopy.

THE IMPLICATIONS OF M DWARF FLARES ON THE DETECTION AND CHARACTERIZATION OF EXOPLANETS AT INFRARED WAVELENGTHS

Energy Technology Data Exchange (ETDEWEB)

Tofflemire, Benjamin M.; Wisniewski, John P.; Kowalski, Adam F.; Schmidt, Sarah J.; Kundurthy, Praveen; Hilton, Eric J.; Hawley, Suzanne L. [Astronomy Department, University of Washington, Box 351580, Seattle, WA 98195 (United States); Holtzman, Jon A., E-mail: tofflb@u.washington.edu, E-mail: jwisnie@u.washington.edu [Department of Astronomy, New Mexico State University, Box 30001, Las Cruces, NM 880033 (United States)

2012-01-15

We present the results of an observational campaign which obtained high-cadence, high-precision, simultaneous optical and IR photometric observations of three M dwarf flare stars for 47 hr. The campaign was designed to characterize the behavior of energetic flare events, which routinely occur on M dwarfs, at IR wavelengths to millimagnitude precision, and quantify to what extent such events might influence current and future efforts to detect and characterize extrasolar planets surrounding these stars. We detected and characterized four highly energetic optical flares having U-band total energies of {approx}7.8 Multiplication-Sign 10{sup 30} to {approx}1.3 Multiplication-Sign 10{sup 32} erg, and found no corresponding response in the J, H, or Ks bandpasses at the precision of our data. For active dM3e stars, we find that a {approx}1.3 Multiplication-Sign 10{sup 32} erg U-band flare ({Delta}U{sub max} {approx} 1.5 mag) will induce <8.3 (J), <8.5 (H), and <11.7 (Ks) mmag of a response. A flare of this energy or greater should occur less than once per 18 hr. For active dM4.5e stars, we find that a {approx}5.1 Multiplication-Sign 10{sup 31} erg U-band flare ({Delta}U{sub max} {approx} 1.6 mag) will induce <7.8 (J), <8.8 (H), and <5.1 (Ks) mmag of a response. A flare of this energy or greater should occur less than once per 10 hr. No evidence of stellar variability not associated with discrete flare events was observed at the level of {approx}3.9 mmag over 1 hr timescales and at the level of {approx}5.6 mmag over 7.5 hr timescales. We therefore demonstrate that most M dwarf stellar activity and flares will not influence IR detection and characterization studies of M dwarf exoplanets above the level of {approx}5-11 mmag, depending on the filter and spectral type. We speculate that the most energetic megaflares on M dwarfs, which occur at rates of once per month, are likely to be easily detected in IR observations with sensitivity of tens of millimagnitudes. We also

An applicable approach for extracting human heart rate and oxygen saturation during physical movements using a multi-wavelength illumination optoelectronic sensor system

Science.gov (United States)

Alharbi, Samah; Hu, Sijung; Mulvaney, David; Blanos, Panagiotis

2018-02-01

The ability to gather physiological parameters such as heart rate (HR) and oxygen saturation (SpO2%) during physical movement allows to continuously monitor personal health status without disrupt their normal daily activities. Photoplethysmography (PPG) based pulse oximetry and similar principle devices are unable to extract the HR and SpO2% reliably during physical movement due to interference in the signals that arise from motion artefacts (MAs). In this research, a flexible reflectance multi-wavelength optoelectronic patch sensor (OEPS) has been developed to overcome the susceptibility of conventional pulse oximetry readings to MAs. The OEPS incorporates light embittered diodes as illumination sources with four different wavelengths, e.g. green, orange, red, and infrared unlike the conventional pulse oximetry devices that normally measure the skin absorption of only two wavelengths (red and infrared). The additional green and orange wavelengths were found to be distinguish to the absorption of deoxyhemoglobin (RHb) and oxyhemoglobin (HbO2). The reliability of extracting physiological parameters from the green and orange wavelengths is due to absorbed near to the surface of the skin, thereby shortening the optical path and so effectively reducing the influence of physical movements. To compensate of MAs, a three-axis accelerometer was used as a reference with help of adaptive filter to reduce MAs. The experiments were performed using 15 healthy subjects aged 20 to 30. The primary results show that there are no significant difference of heart rate and oxygen saturation measurements between commercial devices and OEPS Green (r=0.992), Orange(r=0.984), Red(r=0.952) and IR(r=0.97) and SpO2% (r = 0.982, p = 0.894).

Finesse of transparent tissue cutting by ultrafast lasers at various wavelengths

Science.gov (United States)

Wang, Jenny; Schuele, Georg; Palanker, Daniel

2015-12-01

Transparent ocular tissues, such as the cornea and crystalline lens, can be ablated or dissected using short-pulse lasers. In refractive and cataract surgeries, the cornea, lens, and lens capsule can be cut by producing dielectric breakdown in the focus of a near-infrared (IR) femtosecond laser, which results in explosive vaporization of the interstitial water, causing mechanical rupture of the surrounding tissue. Here, we compare the texture of edges of lens capsule cut by femtosecond lasers with IR and ultraviolet (UV) wavelengths and explore differences in interactions of these lasers with biological molecules. Scanning electron microscopy indicates that a 400-nm laser is capable of producing very smooth cut edges compared to 800 or 1030 nm at a similar focusing angle. Using gel electrophoresis and liquid chromatography/mass spectrometry, we observe laser-induced nonlinear breakdown of proteins and polypeptides by 400-nm femtosecond pulses above and below the dielectric breakdown threshold. On the other hand, 800-nm femtosecond lasers do not produce significant dissociation even above the threshold of dielectric breakdown. However, despite this additional interaction of UV femtosecond laser with proteins, we determine that efficient cutting requires plasma-mediated bubble formation and that remarkably smooth edges are the result of reduced thresholds and smaller focal volume.

A ZnGeP{sub 2} Optical Parametric Oscillator with Mid-IR Output Power 3 W Pumped by a Tm, Ho:GdVO{sub 4} Laser

Energy Technology Data Exchange (ETDEWEB)

Bao-Quan, Yao; Guo-Li, Zhu; You-Lun, Ju; Yue-Zhu, Wang [National Key Laboratory of Tunable Laser Technology, Harbin Institute of Technology, Harbin 150080 (China)

2009-02-15

We report an efficient mid-infrared optical parametric oscillator (OPO) pumped by a pulsed Tm,Ho-codoped GdVO4 laser. The 10-W Tm,Ho:GdVO4 laser pumped by a 801 nm diode produces 20ns pulses with a repetition rate of 10kHz at wavelength of 2.048 {mu}m. The ZnGeP{sub 2} (ZGP) OPO produces 15-ns pulses in the spectral regions 3.65-3.8 {mu}m and 4.45-4.65 {mu}m simultaneously. More than 3 W of mid-IR output power can be generated with a total OPO slope efficiency greater than 58% corresponding to incident 2 {mu}m pump power. The diode laser pump to mid-IR optical conversion efficiency is about 12%.

Uncooled middle wavelength infrared photoconductors based on (111) and (100) oriented HgCdTe

Science.gov (United States)

Madejczyk, Paweł; Kębłowski, Artur; Gawron, Waldemar; Martyniuk, Piotr; Kopytko, Małgorzata; Stępień, Dawid; Rutkowski, Jarosław; Piotrowski, Józef; Piotrowski, Adam; Rogalski, Antoni

2017-09-01

We present progress in metal organic chemical vapor deposition (MOCVD) growth of (100) HgCdTe epilayers achieved recently at the Institute of Applied Physics, Military University of Technology and Vigo System S.A. It is shown that MOCVD technology is an excellent tool for the fabrication of different HgCdTe detector structures with a wide range of composition, donor/acceptor doping, and without post grown ex-situ annealing. Surface morphology, residual background concentration, and acceptor doping efficiency are compared in (111) and (100) oriented HgCdTe epilayers. At elevated temperatures, the carrier lifetime in measured p-type photoresistors is determined by Auger 7 process with about one order of magnitude difference between theoretical and experimental values. Particular progress has been achieved in the growth of (100) HgCdTe epilayers for medium wavelength infrared photoconductors operated in high-operating temperature conditions.

Infrared Organic Light-Emitting Diodes with Carbon Nanotube Emitters.

Science.gov (United States)

Graf, Arko; Murawski, Caroline; Zakharko, Yuriy; Zaumseil, Jana; Gather, Malte C

2018-03-01

While organic light-emitting diodes (OLEDs) covering all colors of the visible spectrum are widespread, suitable organic emitter materials in the near-infrared (nIR) beyond 800 nm are still lacking. Here, the first OLED based on single-walled carbon nanotubes (SWCNTs) as the emitter is demonstrated. By using a multilayer stacked architecture with matching charge blocking and charge-transport layers, narrow-band electroluminescence at wavelengths between 1000 and 1200 nm is achieved, with spectral features characteristic of excitonic and trionic emission of the employed (6,5) SWCNTs. Here, the OLED performance is investigated in detail and it is found that local conduction hot-spots lead to pronounced trion emission. Analysis of the emissive dipole orientation shows a strong horizontal alignment of the SWCNTs with an average inclination angle of 12.9° with respect to the plane, leading to an exceptionally high outcoupling efficiency of 49%. The SWCNT-based OLEDs represent a highly attractive platform for emission across the entire nIR. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Communication: IR spectroscopy of neutral transition metal clusters through thermionic emission

NARCIS (Netherlands)

Lapoutre, V. J. F.; Haertelt, M.; Meijer, G.; Fielicke, A.; Bakker, J. M.

2013-01-01

The resonant multiple photon excitation of neutral niobium clusters using tunable infrared (IR) radiation leads to thermionic emission. By measuring the mass-resolved ionization yield as a function of IR wavenumber species selective IR spectra are obtained for Nb-n (n = 5-20) over the 200-350 cm(-1)

Theory of infrared microspectroscopy for intact fibers.

Science.gov (United States)

Davis, Brynmor J; Carney, P Scott; Bhargava, Rohit

2011-01-15

Infrared microspectroscopy is widely used for the chemical analysis of small samples. In particular, spectral properties of small cylindrical samples are important in forensic analysis, understanding relationships between microstructure and mechanical properties in fibers or fiber composites, and development of cosmetics and drugs for hair. The diameters of the constituent cylinders are typically of the order of the central wavelength of light used to probe the sample. Hence, structure and material spectral response are coupled and recorded spectra are usually distorted to the extent of becoming useless for molecular identification. In this paper, we apply rigorous optical theory to predict the spectral distortions observed in IR microspectroscopic data of fibers. The theory is used, first, to compute the changes that are observed for cylinders of various dimensions under different instrument configurations when compared to the bulk spectrum from the same material. We provide a method to recover intrinsic material spectral response from fibers by correcting for distortion introduced by the cylindrical structure. The theory reported here should enable the routine use of IR microspectroscopy and imaging for the molecular analysis of cylindrical domains in complex materials.

Possible Mechanism of Infrared Radiation Reception: The Role of the Temperature Factor

Science.gov (United States)

Yachnev, I. L.; Penniyaynen, V. A.; Podzorova, S. A.; Rogachevskii, I. V.; Krylov, B. V.

2018-02-01

The role of the temperature factor in the mechanism of reception of the CO2 laser low-power infrared (IR) radiation (λ = 10.6 μm) by a sensory neuron membrane has been studied. Organotypic embryonic tissue culture has been used to measure and estimate the temperature of a sensory ganglia monolayer exposed to radiation at different energy densities. The effects of tissue exposure to low-power IR radiation have been investigated. It has been found that inhibition of tissue growth by radiation of low energy density (10-14-10-10 J/cm2) is replaced by tissue growth (10-7-10-4 J/cm2), and again followed by inhibition in the range of 0.1-6 J/cm2. A statistically significant specific reaction to nonthermal radiation has been detected at the radiation power density of 3 × 10-10 J/cm2, which is due to activation of the Na+,K+-ATPase transducer function. The mechanisms of interaction of IR radiation with embryonic nerve tissue have been considered. Low-power IR radiation with the wavelength of 10.6 μm has been demonstrated to specifically activate a novel signal transducer function of the sodium pump, which controls the reception of nonthermal IR radiation in the energy density range of 10-14 to 10-10 J/cm2.

GOODS-HERSCHEL: IMPACT OF ACTIVE GALACTIC NUCLEI AND STAR FORMATION ACTIVITY ON INFRARED SPECTRAL ENERGY DISTRIBUTIONS AT HIGH REDSHIFT

Energy Technology Data Exchange (ETDEWEB)

Kirkpatrick, Allison; Pope, Alexandra [Department of Astronomy, University of Massachusetts, Amherst, MA 01002 (United States); Alexander, David M. [Department of Physics, Durham University, Durham DH1 3LE (United Kingdom); Charmandaris, Vassilis [Department of Physics and Institute of Theoretical and Computational Physics, University of Crete, GR-71003, Heraklion (Greece); Daddi, Emmanuele; Elbaz, David; Gabor, Jared; Mullaney, James; Pannella, Maurilio; Aussel, Herve; Bournaud, Frederic; Dasyra, Kalliopi [Laboratoire AIM, CEA/DSM-CNRS-Universite Paris Diderot, Irfu/SAp, Orme des Merisiers, F-91191 Gif-sur-Yvette (France); Dickinson, Mark [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); Hwang, Ho Seong [Smithsonian Astrophysical Observatory, 60 Garden Street, Cambridge, MA 02138 (United States); Ivison, Rob [UK Astronomy Technology Centre, Royal Observatory, Blackford Hill, Edinburgh, EH9 3HJ (United Kingdom); Scott, Douglas [Department of Physics and Astronomy, University of British Columbia, 6224 Agricultural Road, Vancouver, BC V6T 1Z1 (Canada); Altieri, Bruno; Coia, Daniela [Herschel Science Centre, European Space Astronomy Centre, Villanueva de la Canada, E-28691 Madrid (Spain); Buat, Veronique [Laboratoire d' Astrophysique de Marseille (LAM), Universite d' Aix-Marseille, CNRS, UMR7326, 38 rue F. Joliot-Curie, F-13388 Marseille Cedex 13 (France); Dannerbauer, Helmut, E-mail: kirkpatr@astro.umass.edu [Institut fuer Astrophysik, Universitaet Wien, Tuerkenschanzstrasse 17, A-1180 Wien (Austria); and others

2012-11-10

We explore the effects of active galactic nuclei (AGNs) and star formation activity on the infrared (0.3-1000 {mu}m) spectral energy distributions (SEDs) of luminous infrared galaxies from z = 0.5 to 4.0. We have compiled a large sample of 151 galaxies selected at 24 {mu}m (S {sub 24} {approx}> 100 {mu}Jy) in the GOODS-N and ECDFS fields for which we have deep Spitzer IRS spectroscopy, allowing us to decompose the mid-IR spectrum into contributions from star formation and AGN activity. A significant portion ({approx}25%) of our sample is dominated by an AGN (>50% of the mid-IR luminosity) in the mid-IR. Based on the mid-IR classification, we divide our full sample into four sub-samples: z {approx} 1 star-forming (SF) sources, z {approx} 2 SF sources, AGNs with clear 9.7 {mu}m silicate absorption, and AGNs with featureless mid-IR spectra. From our large spectroscopic sample and wealth of multi-wavelength data, including deep Herschel imaging at 100, 160, 250, 350, and 500 {mu}m, we use 95 galaxies with complete spectral coverage to create a composite SED for each sub-sample. We then fit a two-temperature component modified blackbody to the SEDs. We find that the IR SEDs have similar cold dust temperatures, regardless of the mid-IR power source, but display a marked difference in the warmer dust temperatures. We calculate the average effective temperature of the dust in each sub-sample and find a significant ({approx}20 K) difference between the SF and AGN systems. We compare our composite SEDs to local templates and find that local templates do not accurately reproduce the mid-IR features and dust temperatures of our high-redshift systems. High-redshift IR luminous galaxies contain significantly more cool dust than their local counterparts. We find that a full suite of photometry spanning the IR peak is necessary to accurately account for the dominant dust temperature components in high-redshift IR luminous galaxies.

FAST VARIABILITY AND MILLIMETER/IR FLARES IN GRMHD MODELS OF Sgr A* FROM STRONG-FIELD GRAVITATIONAL LENSING

Energy Technology Data Exchange (ETDEWEB)

Chan, Chi-kwan; Psaltis, Dimitrios; Özel, Feryal; Marrone, Daniel [Steward Observatory and Department of Astronomy, University of Arizona, 933 N. Cherry Avenue, Tucson, AZ 85721 (United States); Medeiros, Lia [Department of Physics, Broida Hall, University of California, Santa Barbara, Santa Barbara, CA 93106 (United States); Sadowski, Aleksander [MIT Kavli Institute for Astrophysics and Space Research, 77 Massachusetts Avenue, Cambridge, MA 02139 (United States); Narayan, Ramesh, E-mail: chanc@email.arizona.edu [Institute for Theory and Computation, Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)

2015-10-20

We explore the variability properties of long, high-cadence general relativistic magnetohydrodynamic (GRMHD) simulations across the electromagnetic spectrum using an efficient, GPU-based radiative transfer algorithm. We focus on both standard and normal evolution (SANE) and magnetically arrested disk (MAD) simulations with parameters that successfully reproduce the time-averaged spectral properties of Sgr A* and the size of its image at 1.3 mm. We find that the SANE models produce short-timescale variability with amplitudes and power spectra that closely resemble those inferred observationally. In contrast, MAD models generate only slow variability at lower flux levels. Neither set of models shows any X-ray flares, which most likely indicates that additional physics, such as particle acceleration mechanisms, need to be incorporated into the GRMHD simulations to account for them. The SANE models show strong, short-lived millimeter/infrared (IR) flares, with short (≲1 hr) time lags between the millimeter and IR wavelengths, that arise from the combination of short-lived magnetic flux tubes and strong-field gravitational lensing near the horizon. Such events provide a natural explanation for the observed IR flares with no X-ray counterparts.

Time Resolved Detection of Infrared Synchrotron Radiation at DAΦNE

International Nuclear Information System (INIS)

Bocci, A.; Marcelli, A.; Drago, A.; Guidi, M. Cestelli; Pace, E.; Piccinini, M.; Sali, D.; Morini, P.; Piotrowski, J.

2007-01-01

Synchrotron radiation is characterized by a very wide spectral emission from IR to X-ray wavelengths and a pulsed structure that is a function of the source time structure. In a storage ring, the typical temporal distance between two bunches, whose duration is a few hundreds of picoseconds, is on the nanosecond scale. Therefore, synchrotron radiation sources are a very powerful tools to perform time-resolved experiments that however need extremely fast detectors. Uncooled IR devices optimized for the mid-IR range with sub-nanosecond response time, are now available and can be used for fast detection of intense IR sources such as synchrotron radiation storage rings. We present here different measurements of the pulsed synchrotron radiation emission at DAΦNE (Double Annular Φ-factory for Nice Experiments), the collider of the Laboratori Nazionali of Frascati (LNF) of the Istituto Nazionale di Fisica Nucleare (INFN), performed with very fast uncooled infrared detectors with a time resolution of a few hundreds of picoseconds. We resolved the emission time structure of the electron bunches of the DAΦNE collider when it works in a normal condition for high energy physics experiments with both photovoltaic and photoconductive detectors. Such a technology should pave the way to new diagnostic methods in storage rings, monitoring also source instabilities and bunch dynamics

Infrared reflection properties and modelling of in situ reflection measurements on plasma-facing materials in Tore Supra

International Nuclear Information System (INIS)

Reichle, R; Desgranges, C; Faisse, F; Pocheau, C; Lasserre, J-P; Oelhoffen, F; Eupherte, L; Todeschini, M

2009-01-01

Tore Supra has-like ITER-reflecting internal surfaces, which can perturb the machine protection systems based on infrared (IR) thermography. To ameliorate this situation, we have measured and modelled in the 3-5 μm wavelength range the bi-directional reflection distribution function (BRDF) of wall material samples from Tore Supra and conducted in situ reflection measurements and simulated them with the CEA COSMOS code. BRDF results are presented for B 4 C and carbon fibre composite (CFC) tiles. The hemispherical integrated reflection ranges from 0.12 for the B 4 C sample to 0.39 for a CFC tile from the limiter erosion zone. In situ measurements of the IR reflection of a blackbody source off an ICRH and an LHCD antenna of Tore Supra are well reproduced by the simulation.

Infrared reflection properties and modelling of in situ reflection measurements on plasma-facing materials in Tore Supra

Energy Technology Data Exchange (ETDEWEB)

Reichle, R; Desgranges, C; Faisse, F; Pocheau, C [CEA, IRFM, F-13108 Saint-Paul-lez-Durance (France); Lasserre, J-P; Oelhoffen, F; Eupherte, L; Todeschini, M [CEA, DAM, CESTA, F-33114 Le Barp (France)

2009-12-15

Tore Supra has-like ITER-reflecting internal surfaces, which can perturb the machine protection systems based on infrared (IR) thermography. To ameliorate this situation, we have measured and modelled in the 3-5 {mu}m wavelength range the bi-directional reflection distribution function (BRDF) of wall material samples from Tore Supra and conducted in situ reflection measurements and simulated them with the CEA COSMOS code. BRDF results are presented for B{sub 4}C and carbon fibre composite (CFC) tiles. The hemispherical integrated reflection ranges from 0.12 for the B{sub 4}C sample to 0.39 for a CFC tile from the limiter erosion zone. In situ measurements of the IR reflection of a blackbody source off an ICRH and an LHCD antenna of Tore Supra are well reproduced by the simulation.

Wavelength-dependent penetration depth of near infrared radiation into cartilage.

Science.gov (United States)

Padalkar, M V; Pleshko, N

2015-04-07

Articular cartilage is a hyaline cartilage that lines the subchondral bone in the diarthrodial joints. Near infrared (NIR) spectroscopy is emerging as a nondestructive modality for the evaluation of cartilage pathology; however, studies regarding the depth of penetration of NIR radiation into cartilage are lacking. The average thickness of human cartilage is about 1-3 mm, and it becomes even thinner as OA progresses. To ensure that spectral data collected is restricted to the tissue of interest, i.e. cartilage in this case, and not from the underlying subchondral bone, it is necessary to determine the depth of penetration of NIR radiation in different wavelength (frequency) regions. In the current study, we establish how the depth of penetration varies throughout the NIR frequency range (4000-10 000 cm(-1)). NIR spectra were collected from cartilage samples of different thicknesses (0.5 mm to 5 mm) with and without polystyrene placed underneath. A separate NIR spectrum of polystyrene was collected as a reference. It was found that the depth of penetration varied from ∼1 mm to 2 mm in the 4000-5100 cm(-1) range, ∼3 mm in the 5100-7000 cm(-1) range, and ∼5 mm in the 7000-9000 cm(-1) frequency range. These findings suggest that the best NIR region to evaluate cartilage with no subchondral bone contribution is in the range of 4000-7000 cm(-1).

Gitting of infrared data to the interstellar polarization law

Energy Technology Data Exchange (ETDEWEB)

Clarke, D

1984-02-15

The ability of Serkowski's law describing the wavelength dependence of interstellar polarization to encompass new infrared measurements in combination with optical data has been examined. Fitting by least-squares procedures reveals departures from the law in various wavelength zones or at specific wavelength points across the optical and infrared spectrum. These structures may be caused by a combination of effects such as normal experimental noise, complex interstellar clouds or systematic errors in the polarimetry but the possibility remains that some, particularly in the infrared, reflect the scattering properties of interstellar grains. 8 references.

Fitting of infrared data to the interstellar polarization law

Energy Technology Data Exchange (ETDEWEB)

Clarke, D [Glasgow Univ., Great Britain

1984-02-15

The ability of Serkowski's law describing the wavelength dependence of interstellar polarization to encompass new infrared measurements in combination with optical data has been examined. Fitting by least-squares procedures reveals departures from the law in various wavelength zones or at specific wavelength points across the optical and infrared spectrum. These structures may be caused by a combination of effects such as normal experimental noise, complex interstellar clouds or systematic errors in the polarimetry but the possibility remains that some, particularly in the infrared, reflect the scattering properties of interstellar grains.

CO Spectral Line Energy Distributions of Infrared-Luminous Galaxies and Active Galactic Nuclei

Science.gov (United States)

Papadopoulos, Padeli P.; van der Werf, Paul; Isaak, Kate; Xilouris, Emmanuel M.

2010-06-01

We report on new sensitive CO J = 6-5 line observations of several luminous infrared galaxies (LIRGs; L IR(8-1000 μm) >~ 1011 L sun), 36% (8/22) of them ultraluminous infrared galaxies (ULIRGs) (L IR>1012 L sun), and two powerful local active galactic nuclei (AGNs)—the optically luminous QSO PG 1119+120 and the powerful radio galaxy 3C 293—using the James Clerk Maxwell Telescope on Mauna Kea in Hawaii. We combine these observations with existing low-J CO data and dust emission spectral energy distributions in the far-infrared-submillimeter from the literature to constrain the properties of the star-forming interstellar medium (ISM) in these systems. We then build the first local CO spectral line energy distributions (SLEDs) for the global molecular gas reservoirs that reach up to high J-levels. These CO SLEDs are neither biased by strong lensing (which affects many of those constructed for high-redshift galaxies), nor suffer from undersampling of CO-bright regions (as most current high-J CO observations of nearby extended systems do). We find: (1) a significant influence of dust optical depths on the high-J CO lines, suppressing the J = 6-5 line emission in some of the most IR-luminous LIRGs, (2) low global CO line excitation possible even in vigorously star-forming systems, (3) the first case of a shock-powered high-excitation CO SLED in the radio galaxy 3C 293 where a powerful jet-ISM interaction occurs, and (4) unusually highly excitated gas in the optically powerful QSO PG 1119+120. In Arp 220 and possibly other (U)LIRGs very faint CO J = 6-5 lines can be attributed to significant dust optical depths at short submillimeter wavelengths immersing those lines in a strong dust continuum, and also causing the C+ line luminosity deficit often observed in such extreme starbursts. Re-analysis of the CO line ratios available for submillimeter galaxies suggests that similar dust opacities also may be present in these high-redshift starbursts, with genuinely low

CO SPECTRAL LINE ENERGY DISTRIBUTIONS OF INFRARED-LUMINOUS GALAXIES AND ACTIVE GALACTIC NUCLEI

International Nuclear Information System (INIS)

Papadopoulos, Padeli P.; Van der Werf, Paul; Isaak, Kate; Xilouris, Emmanuel M.

2010-01-01

We report on new sensitive CO J = 6-5 line observations of several luminous infrared galaxies (LIRGs; L IR (8-1000 μm) ∼> 10 11 L sun ), 36% (8/22) of them ultraluminous infrared galaxies (ULIRGs) (L IR >10 12 L sun ), and two powerful local active galactic nuclei (AGNs)-the optically luminous QSO PG 1119+120 and the powerful radio galaxy 3C 293-using the James Clerk Maxwell Telescope on Mauna Kea in Hawaii. We combine these observations with existing low-J CO data and dust emission spectral energy distributions in the far-infrared-submillimeter from the literature to constrain the properties of the star-forming interstellar medium (ISM) in these systems. We then build the first local CO spectral line energy distributions (SLEDs) for the global molecular gas reservoirs that reach up to high J-levels. These CO SLEDs are neither biased by strong lensing (which affects many of those constructed for high-redshift galaxies), nor suffer from undersampling of CO-bright regions (as most current high-J CO observations of nearby extended systems do). We find: (1) a significant influence of dust optical depths on the high-J CO lines, suppressing the J = 6-5 line emission in some of the most IR-luminous LIRGs, (2) low global CO line excitation possible even in vigorously star-forming systems, (3) the first case of a shock-powered high-excitation CO SLED in the radio galaxy 3C 293 where a powerful jet-ISM interaction occurs, and (4) unusually highly excitated gas in the optically powerful QSO PG 1119+120. In Arp 220 and possibly other (U)LIRGs very faint CO J = 6-5 lines can be attributed to significant dust optical depths at short submillimeter wavelengths immersing those lines in a strong dust continuum, and also causing the C + line luminosity deficit often observed in such extreme starbursts. Re-analysis of the CO line ratios available for submillimeter galaxies suggests that similar dust opacities also may be present in these high-redshift starbursts, with genuinely low

Characterization and Analysis of a Multicolor Quantum Well Infrared Photodetector

National Research Council Canada - National Science Library

Hanson, Nathan A

2006-01-01

...), mid-wavelength infrared (MWIR), and long-wavelength infrared (LWIR). Through photocurrent spectroscopy and performance analysis, this prototype detector can be classified and prepared for possible future use within the U.S. Armed Forces...

Infrared Spectroscopy of Metal Ion Complexes: Models for Metal Ligand Interactions and Solvation

Science.gov (United States)

Duncan, Michael

2006-03-01

Weakly bound complexes of the form M^+-Lx (M=Fe, Ni, Co, etc.; L=CO2, C2H2, H2O, benzene, N2) are prepared in supersonic molecular beams by laser vaporization in a pulsed-nozzle cluster source. These species are mass analyzed and size-selected in a reflectron time-of-flight mass spectrometer. Clusters are photodissociated at infrared wavelengths with a Nd:YAG pumped infrared optical parametric oscillator/amplifier (OPO/OPA) laser or with a tunable infrared free-electron laser. M^+-(CO2)x complexes absorb near the free CO2 asymmetric stretch near 2349 cm-1 but with an interesting size dependent variation in the resonances. Small clusters have blue-shifted resonances, while larger complexes have additional bands due to surface CO2 molecules not attached to the metal. M^+(C2H2)n complexes absorb near the C-H stretches in acetylene, but resonances in metal complexes are red-shifted with repect to the isolated molecule. Ni^+ and Co^+ complexes with acetylene undergo intracluster cyclization reactions to form cyclobutadiene. Transition metal water complexes are studied in the O-H stretch region, and partial rotational structure can be measured. M^+(benzene) and M^+(benzene)2 ions (M=V, Ti, Al) represent half-sandwich and sandwich species, whose spectra are measured near the free benzene modes. These new IR spectra and their assignments will be discussed as well as other new IR spectra for similar complexes.

Physics of the infrared spectrum

Science.gov (United States)

Deming, Drake; Jennings, Donald E.; Jefferies, John; Lindsey, Charles

1991-01-01

The IR bandpass is attractive for solar magnetic field studies in virtue of the proportionality to wavelength of the ratio of Zeeman splitting to line width. The large Zeeman splitting and optical thinness of the 12-micron observations render them especially useful for vector magnetic field derivations. The IR continuum, and many IR spectral lines, are formed in LTE and are useful in studies of the temperature structure of the solar atmosphere from the deepest observable photospheric layers to chromospheric altitudes. The far-IR continuum is an excellent thermometer for the upper photosphere and chromosphere.

Optimization of a miniature short-wavelength infrared objective optics of a short-wavelength infrared to visible upconversion layer attached to a mobile-devices visible camera

Science.gov (United States)

Kadosh, Itai; Sarusi, Gabby

2017-10-01

The use of dual cameras in parallax in order to detect and create 3-D images in mobile devices has been increasing over the last few years. We propose a concept where the second camera will be operating in the short-wavelength infrared (SWIR-1300 to 1800 nm) and thus have night vision capability while preserving most of the other advantages of dual cameras in terms of depth and 3-D capabilities. In order to maintain commonality of the two cameras, we propose to attach to one of the cameras a SWIR to visible upconversion layer that will convert the SWIR image into a visible image. For this purpose, the fore optics (the objective lenses) should be redesigned for the SWIR spectral range and the additional upconversion layer, whose thickness is mobile device visible range camera sensor (the CMOS sensor). This paper presents such a SWIR objective optical design and optimization that is formed and fit mechanically to the visible objective design but with different lenses in order to maintain the commonality and as a proof-of-concept. Such a SWIR objective design is very challenging since it requires mimicking the original visible mobile camera lenses' sizes and the mechanical housing, so we can adhere to the visible optical and mechanical design. We present in depth a feasibility study and the overall optical system performance of such a SWIR mobile-device camera fore optics design.

Infrared tip of the red giant branch and distances to the MAFFEI/IC 342 group

Energy Technology Data Exchange (ETDEWEB)

Wu, Po-Feng; Tully, R. Brent; Jacobs, Bradley A. [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Drive, HI 96822 (United States); Rizzi, Luca [W. M. Keck Observatory, 65-1120 Mamalahoa Hwy, Kamuela, HI 96743 (United States); Dolphin, Andrew E. [Raytheon, 1151 East Hermans Road, Tucson, AZ 85756 (United States); Karachentsev, Igor D. [Special Astrophysical Observatory, Russian Academy of Sciences, Nizhnij Arkhyz, Karachai-Cherkessian Republic 369167 (Russian Federation)

2014-07-01

In this paper, we extend the use of the tip of the red giant branch (TRGB) method to near-infrared wavelengths from the previously used I-band, using the Hubble Space Telescope (HST) Wide Field Camera 3 (WFC3). Upon calibration of a color dependency of the TRGB magnitude, the IR TRGB yields a random uncertainty of ∼5% in relative distance. The IR TRGB methodology has an advantage over the previously used Advance Camera for Surveys F606W and F814W filter set for galaxies that suffer from severe extinction. Using the IR TRGB methodology, we obtain distances toward three principal galaxies in the Maffei/IC 342 complex, which are located at low Galactic latitudes. New distance estimates using the TRGB method are 3.45{sub −0.13}{sup +0.13} Mpc for IC 342, 3.37{sub −0.23}{sup +0.32} Mpc for Maffei 1, and 3.52{sub −0.30}{sup +0.32} Mpc for Maffei 2. The uncertainties are dominated by uncertain extinction, especially for Maffei 1 and Maffei 2. Our IR calibration demonstrates the viability of the TRGB methodology for observations with the James Webb Space Telescope.

Laboratory oscillator strengths of Sc i in the near-infrared region for astrophysical applications

Science.gov (United States)

Pehlivan, A.; Nilsson, H.; Hartman, H.

2015-10-01

Context. Atomic data is crucial for astrophysical investigations. To understand the formation and evolution of stars, we need to analyse their observed spectra. Analysing a spectrum of a star requires information about the properties of atomic lines, such as wavelengths and oscillator strengths. However, atomic data of some elements are scarce, particularly in the infrared region, and this paper is part of an effort to improve the situation on near-IR atomic data. Aims: This paper investigates the spectrum of neutral scandium, Sc I, from laboratory measurements and improves the atomic data of Sc I lines in the infrared region covering lines in R, I, J, and K bands. Especially, we focus on measuring oscillator strengths for Sc I lines connecting the levels with 4p and 4s configurations. Methods: We combined experimental branching fractions with radiative lifetimes from the literature to derive oscillator strengths (f-values). Intensity-calibrated spectra with high spectral resolution were recorded with Fourier transform spectrometer from a hollow cathode discharge lamp. The spectra were used to derive accurate oscillator strengths and wavelengths for Sc I lines, with emphasis on the infrared region. Results: This project provides the first set of experimental Sc I lines in the near-infrared region for accurate spectral analysis of astronomical objects. We derived 63 log(gf) values for the lines between 5300 Å and 24 300 Å. The uncertainties in the f-values vary from 5% to 20%. The small uncertainties in our values allow for an increased accuracy in astrophysical abundance determinations.

Alignment control of columnar liquid crystals with wavelength tunable CO2 laser irradiation

International Nuclear Information System (INIS)

Monobe, Hirosato; Awazu, Kunio; Shimizu, Yo

2008-01-01

Infrared-induced alignment change with wavelength tunable CO 2 laser irradiation for columnar liquid crystal domains was investigated for a liquid crystalline triphenylene derivative. A uniformly aligned alignment change of domains was observed when a chopped linearly polarized infrared laser light corresponding to the wavelength of the aromatic C-O-C stretching vibration band (9.65 μm) was irradiated. The results strongly imply that the infrared irradiation is a possible technique for device fabrication by use of columnar mesophase as a liquid crystalline semiconductor

Inverted cones grating for flexible metafilter at optical and infrared frequencies

Energy Technology Data Exchange (ETDEWEB)

Brückner, Jean-Baptiste; Le Rouzo, Judikaël; Escoubas, Ludovic [Aix-Marseille Université, IM2NP, CNRS-UMR 7334, Domaine Universitaire de Saint-Jérôme, Service 231, 13397 Marseille Cedex 20 (France); Brissonneau, Vincent; Dubarry, Christophe [CEA-LITEN DTNM, 17 Avenue des Martyrs, 38054 Grenoble cedex 9 (France); Ferchichi, Abdelkerim; Gourgon, Cécile [LTM CNRS, Laboratoire des Technologies de la Microélectronique 17 Avenue des Martyrs, 38054 Grenoble cedex 9 (France); Berginc, Gérard [Thales Optronique S.A., 2 Avenue Gay Lussac, 78990 Elancourt (France)

2014-02-24

By combining the antireflective properties from gradual changes in the effective refractive index and cavity coupling from cone gratings and the efficient optical behavior of a tungsten film, a flexible filter showing very broad antireflective properties from the visible to short wavelength infrared region and, simultaneously, a mirror-like behavior in the mid-infrared wavelength region and long-infrared wavelength region has been conceived. Nanoimprint technology has permitted the replication of inverted cone patterns on a large scale on a flexible polymer, afterwards coated with a thin tungsten film. This optical metafilter is of great interest in the stealth domain where optical signature reduction from the optical to short wavelength infrared region is an important matter. As it also acts as selective thermal emitter offering a good solar-absorption/infrared-emissivity ratio, interests are found as well for solar heating applications.

β-Isocyanoalanine as an IR probe: comparison of vibrational dynamics between isonitrile and nitrile-derivatized IR probes.

Science.gov (United States)

Maj, Michał; Ahn, Changwoo; Kossowska, Dorota; Park, Kwanghee; Kwak, Kyungwon; Han, Hogyu; Cho, Minhaeng

2015-05-07

An infrared (IR) probe based on isonitrile (NC)-derivatized alanine 1 was synthesized and the vibrational properties of its NC stretching mode were investigated using FTIR and femtosecond IR pump-probe spectroscopy. It is found that the NC stretching mode is very sensitive to the hydrogen-bonding ability of solvent molecules. Moreover, its transition dipole strength is larger than that of nitrile (CN) in nitrile-derivatized IR probe 2. The vibrational lifetime of the NC stretching mode is found to be 5.5 ± 0.2 ps in both D2O and DMF solvents, which is several times longer than that of the azido (N3) stretching mode in azido-derivatized IR probe 3. Altogether these properties suggest that the NC group can be a very promising sensing moiety of IR probes for studying the solvation structure and dynamics of biomolecules.

Small-pixel long wavelength infrared focal plane arrays based on InAs/GaSb Type-II superlattice

Science.gov (United States)

Han, Xi; Jiang, Dongwei; Wang, Guowei; Hao, Hongyue; Sun, Yaoyao; Jiang, Zhi; Lv, Yuexi; Guo, Chunyan; Xu, Yingqiang; Niu, Zhichuan

2018-03-01

The paper reports a 640 × 512 long wavelength infrared focal plane arrays (FPAs) with 15 × 15 μm2 pixels pitch based on the type II InAs/GaSb superlattice. Material grown on a 3 in. GaSb substrate exhibits a 50% cutoff wavelength of 10.2 μm across the entire wafer. The peak quantum efficiency of the detector reaches 28% at 9.1 μm without anti-reflecting coating. Maximal resistance-area products of 8.95 Ω·cm2 at 77 K and 24.4 Ω·cm2 at 45 K are achieved in a single element device indicating that the generation-recombination and tunneling mechanisms dominate the device dark current, respectively. The peak Johnson Detectivity reaches 9.66 × 1011 cm Hz1/2/W at 9.1 μm with the bias voltage of 80 mV. In the whole zone, the operability and non-uniformity for the responsivity are 97.74% and 6.41% respectively. The average noise equivalent temperature difference of 31.9 mK at 77 K is achieved with an integration time of 0.5 ms, a 300 K background and f/2 optics.

Continuous-wave near-photon counting spectral imaging detector in the mid-infrared by upconversion

DEFF Research Database (Denmark)

Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter; Pedersen, Christian

2013-01-01

is usually measured in number of electrons. The second noise source is usually referred to as dark noise, which is the background signal generated over time. Dark noise is usually measured in electrons per pixel per second. For silicon cameras certain models like EM-CCD have close to zero read noise, whereas...... high-end IR cameras have read noise of hundreds of electrons. The dark noise for infrared cameras based on semiconductor materials is also substantially higher than for silicon cameras, typical values being millions of electrons per pixel per second for cryogenically cooled cameras whereas peltier...... cooled CCD cameras have dark noise measured in fractions of electrons per pixel per second. An ideal solution thus suggest the combination of an efficient low noise image wavelength conversion system combined with low noise silicon based cameras for low noise imaging in the IR region. We discuss image...

Mid-IR laser system for advanced neurosurgery

Science.gov (United States)

Klosner, M.; Wu, C.; Heller, D. F.

2014-03-01

We present work on a laser system operating in the near- and mid-IR spectral regions, having output characteristics designed to be optimal for cutting various tissue types. We provide a brief overview of laser-tissue interactions and the importance of controlling certain properties of the light beam. We describe the principle of operation of the laser system, which is generally based on a wavelength-tunable alexandrite laser oscillator/amplifier, and multiple Raman conversion stages. This configuration provides robust access to the mid-IR spectral region at wavelengths, pulse energies, pulse durations, and repetition rates that are attractive for neurosurgical applications. We summarize results for ultra-precise selective cutting of nerve sheaths and retinas with little collateral damage; this has applications in procedures such as optic-nerve-sheath fenestration and possible spinal repair. We also report results for cutting cornea, and dermal tissues.

Jupiter's Mid-Infrared Aurora: Solar Connection and Minor Constituents

Science.gov (United States)

Kostiuk, Theodore; Livengood, T.A.; Fast, K.E.; Hewagama, T.; Schmilling, F.; Sonnabend, G.; Delgado, J.

2009-01-01

High spectral resolution in the 12 pin region of the polar regions of Jupiter reveal unique information on auroral phenomena and upper stratospheric composition. Polar aurorae in Jupiter's atmosphere radiate; throughout the electromagnetic spectrum from X-ray through mid-infrared (mid-IR, 5 - 20 micron wavelength). Voyager IRIS data and ground-based. spectroscopic measurements of Jupiter's northern mid-IR aurora acquired since 1982, reveal a correlation between auroral brightness and solar activity that has not been observed in Jovian aurora at other wavelengths. Over nearly three solar cycles, Jupiter auroral ethane, emission brightness and solar 10.7-cm radar flux and sunspot number are positively correlated with high confidence. Ethane line emission intensity varies over tenfold between low and high scalar activity periods. Detailed measurements have been made using the GSFC HIPWAC spectrometer at the NASA IRTF since the last solar maximum, following the mid-IR emission through the declining phase toward solar minimum. An even more convincing correlation with solar activity is evident in these data. The spectra measured contain features that cannot be attributed to ethane and are most likely spectra of minor constituents whose molecular bands overlap the v9 band of ethane. Possible candidates are allene, propane, and other higher order hydrocarbons. These features appear to be enhanced in the active polar regions. Laboratory measurements at comparable spectral resolution of spectra of candidate molecules will be used to identify the constituents. Current analyses of these results will be described, including planned measurements on polar ethane line emission scheduled through the rise of the next solar maximum beginning in 2009, with a steep gradient to a maximum in 2012. This work is relevant to the Juno mission and to the development of the NASA/ESA Europa Jupiter System Mission.

Optical Determination of Lead Chrome Green in Green Tea by Fourier Transform Infrared (FT-IR Transmission Spectroscopy.

Directory of Open Access Journals (Sweden)

Xiaoli Li

Full Text Available The potential of Fourier transform infrared (FT-IR transmission spectroscopy for determination of lead chrome green in green tea was investigated based on chemometric methods. Firstly, the qualitative analysis of lead chrome green in tea was performed based on partial least squares discriminant analysis (PLS-DA, and the correct rate of classification was 100%. And then, a hybrid method of interval partial least squares (iPLS regression and successive projections algorithm (SPA was proposed to select characteristic wavenumbers for the quantitative analysis of lead chrome green in green tea, and 19 wavenumbers were obtained finally. Among these wavenumbers, 1384 (C = C, 1456, 1438, 1419(C = N, and 1506 (CNH cm-1 were the characteristic wavenumbers of lead chrome green. Then, these 19 wavenumbers were used to build determination models. The best model was achieved by least squares support vector machine (LS-SVMalgorithm with high coefficient of determination and low root-mean square error of prediction set (R2p = 0.864 and RMSEP = 0.291. All these results indicated the feasibility of IR spectra for detecting lead chrome green in green tea.

Measurement and modeling of low-wavelength losses in silica fibers and their impact at communication Wavelengths

DEFF Research Database (Denmark)

Pedersen, Anders Tegtmeier; Grüner-Nielsen, Lars; Rottwitt, Karsten

2009-01-01

Using the cutback technique, the attenuation of four different silica step-index fibers is measured in the very wide wavelength range of 190-1700 nm. The measured spectra are deconvolved into components describing Rayleigh scattering, infrared losses, Urbach edge, anomalous loss, and different...

Reactions of laser-ablated Co, Rh, and Ir with CO: Infrared spectra and density functional calculations of the metal carbonyl molecules, cations and anions in solid neon

International Nuclear Information System (INIS)

Zhou, M.; Andrews, L.

1999-01-01

Laser ablation produces metal atoms, cations, and electrons for reaction with CO during condensation in excess neon at 4 K. Infrared spectra are observed for the metal carbonyls, cations, and anions, which are identified from isotopic shifts ( 13 CO, C 18 O) and splittings using mixed isotopic precursors. Density functional calculations with pseudopotentials for Rh and Ir predict the observed carbonyl stretching frequencies within 1--2%. This characterization of the simple RhCO + , RhCO, and RhCO - (and Ir) species over a 350 cm -1 range provides a scale for comparison of larger catalytically active Rh and Ir carbonyl complexes in solution and on surfaces to estimate charge on the metal center. This work provides the first spectroscopic characterization of Rh and Ir carbonyl cations and anions except for the stable tetracarbonyl anions in solution

Heat transfer and energy efficiency in infrared paper dryers

Energy Technology Data Exchange (ETDEWEB)

Pettersson, Magnus

1999-11-01

Infrared (IR) dryers are widely used in the paper industry, mainly in the production of coated paper grades. The thesis deals with various aspects of heat transfer and energy use in infrared heaters and dryers as employed in the paper industry. Both gas-fired and electric IR dryers are considered and compared. The thesis also provides an introduction to infrared heaters and infrared drying, including a review of recent literature in the field. The transport of thermal radiation inside a paper sheet was investigated and different IR dryers were compared in terms of their ability to transfer energy to the internal parts of a paper sheet. Although there were evident differences in the absorption of radiation between gas-fired and electric IR dryers, the distinction was found not to be as important as has generally been believed. The main differences appeared to be due to the choice of a one- or a two-sided dryer solution, rather than the spectral distributions emitted by the dryers. A method for evaluating the radiation efficiency of IR heaters was proposed. An electric IR heater was evaluated in the laboratory. The radiation efficiency of the heater was shown to be strongly dependent on the power level. The maximum efficiency, found at high power level, was close to 60 %. A procedure for evaluation of the total energy transfer efficiency of an infrared paper dryer was proposed and used in the evaluation of an electric IR dryer operating in an industrial coating machine. The efficiency of the dryer was roughly 40 %. A model for an electric IR heater was developed. The model includes non-grey radiative heat transfer between the different parts of the heater, as well as conduction in reflector material and convective cooling of the surfaces. Using IR module voltage as the only input, model predictions of temperatures and heat flux were found to agree well with experimental data both at steady state and under transient conditions. The model was also extended to include

Infrared rotational light curves on Jupiter induced by wave activities and cloud patterns andimplications on brown dwarfs

Science.gov (United States)

Ge, Huazhi; Zhang, Xi; Fletcher, Leigh; Orton, Glenn S.; Sinclair, James Andrew; Fernandes,, Joshua; Momary, Thomas W.; Warren, Ari; Kasaba, Yasumasa; Sato, Takao M.; Fujiyoshi, Takuya

2017-10-01

Many brown dwarfs exhibit infrared rotational light curves with amplitude varying from a fewpercent to twenty percent (Artigau et al. 2009, ApJ, 701, 1534; Radigan et al. 2012, ApJ, 750,105). Recently, it was claimed that weather patterns, especially planetary-scale waves in thebelts and cloud spots, are responsible for the light curves and their evolutions on brown dwarfs(Apai et al. 2017, Science, 357, 683). Here we present a clear relationship between the direct IRemission maps and light curves of Jupiter at multiple wavelengths, which might be similar withthat on cold brown dwarfs. Based on infrared disk maps from Subaru/COMICS and VLT/VISIR,we constructed full maps of Jupiter and rotational light curves at different wavelengths in thethermal infrared. We discovered a strong relationship between the light curves and weatherpatterns on Jupiter. The light curves also exhibit strong multi-bands phase shifts and temporalvariations, similar to that detected on brown dwarfs. Together with the spectra fromTEXES/IRTF, our observations further provide detailed information of the spatial variations oftemperature, ammonia clouds and aerosols in the troposphere of Jupiter (Fletcher et al. 2016,Icarus, 2016 128) and their influences on the shapes of the light curves. We conclude that waveactivities in Jupiter’s belts (Fletcher et al. 2017, GRL, 44, 7140), cloud holes, and long-livedvortices such as the Great Red Spot and ovals control the shapes of IR light curves and multi-wavelength phase shifts on Jupiter. Our finding supports the hypothesis that observed lightcurves on brown dwarfs are induced by planetary-scale waves and cloud spots.

THE SPATIAL EXTENT OF (U)LIRGs IN THE MID-INFRARED. I. THE CONTINUUM EMISSION

International Nuclear Information System (INIS)

DIaz-Santos, T.; Charmandaris, V.; Armus, L.; Petric, A. O.; Howell, J. H.; Murphy, E. J.; Inami, H.; Haan, S.; Marshall, J. A.; Stierwalt, S.; Surace, J. A.; Mazzarella, J. M.; Veilleux, S.; Bothun, G.; Appleton, P. N.; Evans, A. S.; Sanders, D. B.

2010-01-01

We present an analysis of the extended mid-infrared (MIR) emission of the Great Observatories All-Sky LIRG Survey sample based on 5-15 μm low-resolution spectra obtained with the Infrared Spectrograph on Spitzer. We calculate the fraction of extended emission (FEE) as a function of wavelength for the galaxies in the sample, FEE λ , defined as the fraction of the emission which originates outside of the unresolved component of a source at a given distance. We find that the FEE λ varies from one galaxy to another, but we can identify three general types of FEE λ : one where FEE λ is constant, one where features due to emission lines and polycyclic aromatic hydrocarbons appear more extended than the continuum, and a third which is characteristic of sources with deep silicate absorption at 9.7 μm. More than 30% of the galaxies have a median FEE λ larger than 0.5, implying that at least half of their MIR emission is extended. Luminous Infrared Galaxies (LIRGs) display a wide range of FEE in their warm dust continuum (0 ∼ 13.2 μ m ∼ 13.2 μ m that we find in many LIRGs suggest that the extended component of their MIR continuum emission originates in scales up to 10 kpc and may contribute as much as the nuclear region to their total MIR luminosity. The mean size of the LIRG cores at 13.2 μm is 2.6 kpc. However, once the IR luminosity of the systems reaches the threshold of L IR ∼ 10 11.8 L sun , slightly below the regime of Ultra-luminous Infrared Galaxies (ULIRGs), all sources become clearly more compact, with FEE 13.2 μ m ∼ IR ∼> 10 11.25 L sun strongly increases in those classified as mergers in their final stage of interaction. The FEE 13.2 μ m is also related to the contribution of an active galactic nucleus (AGN) to the MIR emission. Galaxies which are more AGN dominated are less extended, independently of their L IR . We finally find that the extent of the MIR continuum emission is correlated with the far-IR IRAS log(f 60 μ m /f 100 μ m

Hollow-core infrared fiber incorporating metal-wire metamaterial

DEFF Research Database (Denmark)

Yan, Min; Mortensen, Asger

2009-01-01

Infrared (IR) light is considered important for short-range wireless communication, thermal sensing, spectroscopy, material processing, medical surgery, astronomy etc. However, IR light is in general much harder to transport than optical light or microwave radiation. Existing hollow-core IR...

Nanoscale Infrared Spectroscopy of Biopolymeric Materials

Science.gov (United States)

Curtis Marcott; Michael Lo; Kevin Kjoller; Craig Prater; Roshan Shetty; Joseph Jakes; Isao Noda

2012-01-01

Atomic Force Microscopy (AFM) and infrared (IR) spectroscopy have been combined in a single instrument capable of producing 100 nm spatial resolution IR spectra and images. This new capability enables the spectroscopic characterization of biomaterial domains at levels not previously possible. A tunable IR laser source generating pulses on the order of 10 ns was used...

INFRARED ABSORPTION LINES TOWARD NGC 7538 IRS 1: ABUNDANCES OF H{sub 2}, H{sub 3}{sup +}, AND CO

Energy Technology Data Exchange (ETDEWEB)

Goto, Miwa [Universitäts-Sternwarte München, Scheinerstr. 1, D-81679 Munich (Germany); Geballe, T. R. [Gemini Observatory, 670 North A‘ohoku Place, Hilo, HI 96720 (United States); Usuda, Tomonori, E-mail: mgoto@usm.lmu.de, E-mail: tgeballe@gemini.edu, E-mail: usuda@naoj.org [Subaru Telescope, 650 North A‘ohoku Place, Hilo, HI 96720 (United States)

2015-06-10

We report high-resolution near-infrared absorption spectroscopy of H{sub 2}, H{sub 3}{sup +}, and CO toward the young high mass object NGC 7538 IRS 1. The v = 1–0 H{sub 2} S(0) line and lines in the CO v = 2–0 band were detected; the v = 1–0 H{sub 2} S(1) line and the v = 1–0 H{sub 3}{sup +} lines [R(1, 1){sup l}, R(1, 0), R(1, 1){sup u}] were not detected. The line of sight traverses two clouds, with temperatures 45 and 259 K and with roughly equal column densities of CO. Assuming that H{sub 2} is at the same temperature as CO and that the two species are uniformly mixed, [H{sub 2}]/[CO] = 3600 ± 1200. NGC 7538 is the most distant object from the Galactic center for which [H{sub 2}]/[CO] has been directly measured using infrared absorption spectroscopy.

Study on the mechanism of using IR illumination to improve the carrier transport performance of CdZnTe detector

Science.gov (United States)

Mao, Yifei; Zhang, Jijun; Lin, Liwen; Lai, Jianming; Min, Jiahua; Liang, Xiaoyan; Huang, Jian; Tang, Ke; Wang, Linjun

2018-04-01

Different wavelength IR light (770-1150 nm) was used to evaluate the effect of IR light on the carrier transport performance of CdZnTe detector. The effective mobility-lifetime product (μτ*) of CdZnTe achieved 10-2 cm2 V-1 when the IR wavelength was in the range of 820-920 nm, but decreased to 1 × 10-4 cm2 V-1 when the wavelength was longer than 920 nm. The mechanism about how IR light affecting the carrier transport property of CdZnTe detector was analyzed with Shockley-Read-Hall model. The defect of doubly ionized Cd vacancy ([VCd]2-) was found to be the main factor that assist IR light affecting the μτ of CdZnTe detector. The photoconductive experiment under 770-1150 nm IR illumination was carried out, and three kinds of photocurrent curve were detected and analyzed by solving the Hecht equation. The experiments demonstrated the effect of [VCd]2- defect on the carrier transport property of CdZnTe detector under IR illumination.

Infrared laser system

International Nuclear Information System (INIS)

Cantrell, C.D.; Carbone, R.J.

1977-01-01

An infrared laser system and method for isotope separation may comprise a molecular gas laser oscillator to produce a laser beam at a first wavelength, Raman spin flip means for shifting the laser to a second wavelength, a molecular gas laser amplifier to amplify said second wavelength laser beam to high power, and optical means for directing the second wavelength, high power laser beam against a desired isotope for selective excitation thereof in a mixture with other isotopes. The optical means may include a medium which shifts the second wavelength high power laser beam to a third wavelength, high power laser beam at a wavelength coincidental with a corresponding vibrational state of said isotope and which is different from vibrational states of other isotopes in the gas mixture

Study and use of an infrared camera optimized for ground based observations in the 10 micron wavelength range

International Nuclear Information System (INIS)

Remy, Sophie

1991-01-01

Astronomical observations in the 10 micron atmospheric window provide very important information for many of astrophysical topics. But because of the very large terrestrial photon background at that wavelength, ground based observations have been impeded. On the other band, the ground based telescopes offer a greater angular resolution than the spatially based telescopes. The recent development of detector arrays for the mid infrared range made easier the development of infrared cameras with optimized detectors for astronomical observations from the ground. The CAMIRAS infrared camera, built by the 'Service d'Astrophysique' in Saclay is the instrument we have studied and we present its performances. Its sensitivity, given for an integration time of one minute on source and a signal to noise ratio of 3, is 0.15 Jy for punctual sources, and 20 mJy arcs"-"2 for extended sources. But we need to get rid of the enormous photon background so we have to find a better way of observation based on modulation techniques as 'chopping' or 'nodding'. Thus we show that a modulation about 1 Hz is satisfactory with our detectors arrays without perturbing the signal to noise ratio. As we have a good instrument and because we are able to get rid of the photon background, we can study astronomical objects. Results from a comet, dusty stellar disks, and an ultra-luminous galaxy are presented. (author) [fr

Fourier Transform Infrared Spectroscopy as a Tool in Analysis of Proteus mirabilis Endotoxins.

Science.gov (United States)

Żarnowiec, Paulina; Czerwonka, Grzegorz; Kaca, Wiesław

2017-01-01

Fourier transform infrared spectroscopy (FT-IR) was used to scan whole bacterial cells as well as lipopolysaccharides (LPSs, endotoxins) isolated from them. Proteus mirabilis cells, with chemically defined LPSs, served as a model for the ATR FT-IR method. The paper focuses on three steps of infrared spectroscopy: (1) sample preparation, (2) IR scanning, and (3) multivariate analysis of IR data (principal component analysis, PCA).

Raman and Fourier Transform Infrared (FT-IR) Mineral to Matrix Ratios Correlate with Physical Chemical Properties of Model Compounds and Native Bone Tissue.

Science.gov (United States)

Taylor, Erik A; Lloyd, Ashley A; Salazar-Lara, Carolina; Donnelly, Eve

2017-10-01

Raman and Fourier transform infrared (FT-IR) spectroscopic imaging techniques can be used to characterize bone composition. In this study, our objective was to validate the Raman mineral:matrix ratios (ν 1 PO 4 :amide III, ν 1 PO 4 :amide I, ν 1 PO 4 :Proline + hydroxyproline, ν 1 PO 4 :Phenylalanine, ν 1 PO 4 :δ CH 2 peak area ratios) by correlating them to ash fraction and the IR mineral:matrix ratio (ν 3 PO 4 :amide I peak area ratio) in chemical standards and native bone tissue. Chemical standards consisting of varying ratios of synthetic hydroxyapatite (HA) and collagen, as well as bone tissue from humans, sheep, and mice, were characterized with confocal Raman spectroscopy and FT-IR spectroscopy and gravimetric analysis. Raman and IR mineral:matrix ratio values from chemical standards increased reciprocally with ash fraction (Raman ν 1 PO 4 /Amide III: P Raman ν 1 PO 4 /Amide I: P Raman ν 1 PO 4 /Proline + Hydroxyproline: P Raman ν 1 PO 4 /Phenylalanine: P Raman ν 1 PO 4 /δ CH 2 : P Raman and IR mineral:matrix ratio values were strongly correlated ( P Raman mineral:matrix bone composition parameter correlates strongly to ash fraction and to its IR counterpart. Finally, the mineral:matrix ratio values of the native bone tissue are similar to those of both chemical standards and theoretical values, confirming the biological relevance of the chemical standards and the characterization techniques.

Simultaneous measurement of thermal diffusivity and effective infrared absorption coefficient in IR semitransparent and semiconducting n-CdMgSe crystals using photothermal radiometry

Energy Technology Data Exchange (ETDEWEB)

Pawlak, M., E-mail: mpawlak@fizyka.umk.pl [Institute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University, Grudziądzka 5/7, Toruń (Poland); Maliński, M. [Department of Electronics and Computer Science, Koszalin University of Technology, 2 Śniadeckich St., Koszalin 75-453 (Poland)

2015-01-10

Highlights: • The new method of determination of the effective infrared absorption coefficient is presented. • The method can be used for transparent samples for the excitation radiation. • The effect of aluminum foil on the PTR signal in a transmission configuration is discussed. - Abstract: In this paper we propose a new procedure of simultaneous estimation of the effective infrared optical absorption coefficient and the thermal diffusivity of solid state samples using the photothermal infrared radiometry method in the transmission configuration. The proposed procedure relies on the analysis of the frequency dependent signal obtained from the samples covered with thin aluminum foil. This method can be applied for both optically opaque and transparent samples. The proposed method is illustrated with the results of the thermal diffusivity and the effective IR absorption coefficient obtained for several Cd{sub 1−x}Mg{sub x}Se crystals.

Metallic nano-cavity lasers at near infrared wavelengths

NARCIS (Netherlands)

Hill, M.T.; Stockman, M.I.

2009-01-01

There has been considerable interest in nano-cavity lasers, both from a scientific perspective for investigating fundamental properties of lasers and cavities, and also to produce smaller and better lasers for low-power applications. Light confinement on a wavelength scale has been reported in

Shelf-life of infrared dry-roasted almonds

Science.gov (United States)

Infrared heating was recently used to develop a more efficient roasting technology than traditional hot air roasting. Therefore, in this study, we evaluated the shelf-life of almonds roasted with three different approaches, namely infrared [IR], sequential infrared and hot air [SIRHA], and regular h...

Infrared and Skin: Friend or Foe

Science.gov (United States)

Barolet, Daniel; Christiaens, François; Hamblin, Michael R

2016-01-01

In the last decade, it has been proposed that the sun's IR-A wavelengths might be deleterious to human skin and that sunscreens, in addition to their desired effect to protect against UV-B and UV-A, should also protect against IR-A (and perhaps even visible light). Several studies showed that NIR may damage skin collagen content via an increase in MMP-1 activity in the same manner as is known for UVR. Unfortunately, the artificial NIR light sources used in such studies were not representative of the solar irradiance. Yet, little has been said about the other side of the coin. This article will focus on key information suggesting that IR-A may be more beneficial than deleterious when the skin is exposed to the appropriate irradiance/dose of IR-A radiation similar to daily sun exposure received by people in real life. IR-A might even precondition the skin – a process called photoprevention - from an evolutionary standpoint since exposure to early morning IR-A wavelengths in sunlight may ready the skin for the coming mid-day deleterious UVR. Consequently IR-A appears to be the solution, not the problem. It does more good than bad for the skin. It is essentially a question of intensity and how we can learn from the sun. PMID:26745730

Atomic layer deposition of absorbing thin films on nanostructured electrodes for short-wavelength infrared photosensing

International Nuclear Information System (INIS)

Xu, Jixian; Sutherland, Brandon R.; Hoogland, Sjoerd; Fan, Fengjia; Sargent, Edward H.; Kinge, Sachin

2015-01-01

Atomic layer deposition (ALD), prized for its high-quality thin-film formation in the absence of high temperature or high vacuum, has become an industry standard for the large-area deposition of a wide array of oxide materials. Recently, it has shown promise in the formation of nanocrystalline sulfide films. Here, we demonstrate the viability of ALD lead sulfide for photodetection. Leveraging the conformal capabilities of ALD, we enhance the absorption without compromising the extraction efficiency in the absorbing layer by utilizing a ZnO nanowire electrode. The nanowires are first coated with a thin shunt-preventing TiO 2 layer, followed by an infrared-active ALD PbS layer for photosensing. The ALD PbS photodetector exhibits a peak responsivity of 10 −2  A W −1 and a shot-derived specific detectivity of 3 × 10 9  Jones at 1530 nm wavelength

Infrared spectroscopy of molecular submonolayers on surfaces by infrared scanning tunneling microscopy: tetramantane on Au111.

Science.gov (United States)

Pechenezhskiy, Ivan V; Hong, Xiaoping; Nguyen, Giang D; Dahl, Jeremy E P; Carlson, Robert M K; Wang, Feng; Crommie, Michael F

2013-09-20

We have developed a new scanning-tunneling-microscopy-based spectroscopy technique to characterize infrared (IR) absorption of submonolayers of molecules on conducting crystals. The technique employs a scanning tunneling microscope as a precise detector to measure the expansion of a molecule-decorated crystal that is irradiated by IR light from a tunable laser source. Using this technique, we obtain the IR absorption spectra of [121]tetramantane and [123]tetramantane on Au(111). Significant differences between the IR spectra for these two isomers show the power of this new technique to differentiate chemical structures even when single-molecule-resolved scanning tunneling microscopy (STM) images look quite similar. Furthermore, the new technique was found to yield significantly better spectral resolution than STM-based inelastic electron tunneling spectroscopy, and to allow determination of optical absorption cross sections. Compared to IR spectroscopy of bulk tetramantane powders, infrared scanning tunneling microscopy (IRSTM) spectra reveal narrower and blueshifted vibrational peaks for an ordered tetramantane adlayer. Differences between bulk and surface tetramantane vibrational spectra are explained via molecule-molecule interactions.

Recent advances in infrared astronomy

International Nuclear Information System (INIS)

Robson, E.I.

1980-01-01

A background survey is given of developments in infrared astronomy during the last decade. Advantages obtained in using infrared wavelengths to penetrate the Earth's atmosphere and the detectors used for this work are considered. Infrared studies of, among other subjects, the stars, dust clouds, the centre of our galaxy and the 3k cosmic background radiation, are discussed. (UK)

Solar Observations at Submillimeter Wavelengths

Science.gov (United States)

Kaufmann, P.

We review earlier to recent observational evidences and theoretical motivations leading to a renewed interest to observe flares in the submillimeter (submm) - infrared (IR) range of wavelengths. We describe the new solar dedicated submillimeter wave telescope which began operations at El Leoncito in the Argentina Andes: the SST project. It consists of focal plane arrays of two 405 GHz and four 212 GHz radiometers placed in a 1.5-m radome-enclosed Cassegrain antenna, operating simultaneously with one millisecond time resolution. The first solar events analyzed exhibited the onset of rapid submm-wave spikes (100-300 ms), well associated to other flare manifestations, especially at X-rays. The spikes positions were found scattered over the flaring source by tens of arcseconds. For one event an excellent association was found between the gamma-ray emission time profile and the rate of occurrence of submm-wave rapid spikes. The preliminary results favour the idea that bulk burst emissions are a response to numerous fast energetic injections, discrete in time, produced at different spatial positions over the flaring region. Coronal mass ejections were associated to the events studied. Their trajectories extrapolated to the solar surface appear to correspond to the onset time of the submm-wave spikes, which might represent an early signature of the CME's initial acceleration process.

Infrared laser damage thresholds in corneal tissue phantoms using femtosecond laser pulses

Science.gov (United States)

Boretsky, Adam R.; Clary, Joseph E.; Noojin, Gary D.; Rockwell, Benjamin A.

2018-02-01

Ultrafast lasers have become a fixture in many biomedical, industrial, telecommunications, and defense applications in recent years. These sources are capable of generating extremely high peak power that can cause laser-induced tissue breakdown through the formation of a plasma upon exposure. Despite the increasing prevalence of such lasers, current safety standards (ANSI Z136.1-2014) do not include maximum permissible exposure (MPE) values for the cornea with pulse durations less than one nanosecond. This study was designed to measure damage thresholds in corneal tissue phantoms in the near-infrared and mid-infrared to identify the wavelength dependence of laser damage thresholds from 1200-2500 nm. A high-energy regenerative amplifier and optical parametric amplifier outputting 100 femtosecond pulses with pulse energies up to 2 mJ were used to perform exposures and determine damage thresholds in transparent collagen gel tissue phantoms. Three-dimensional imaging, primarily optical coherence tomography, was used to evaluate tissue phantoms following exposure to determine ablation characteristics at the surface and within the bulk material. The determination of laser damage thresholds in the near-IR and mid-IR for ultrafast lasers will help to guide safety standards and establish the appropriate MPE levels for exposure sensitive ocular tissue such as the cornea. These data will help promote the safe use of ultrafast lasers for a wide range of applications.

Comet Mineralogy as Inferred from Infrared Spectra of Comets

Science.gov (United States)

Wooden, Diane H.

2006-01-01

For most comets, infrared (IR) spectroscopy (remote sensing) is the method through which we diagnose the mineralogy and size distribution of dust in their comae. The shape and contrast of the IR spectral features depend on the particle size: optically active minerals (absorbing of visible and near-IR solar photons) and submicron solid grains or highly porous (> 90% vacuum) grains primarily contribute to the shapes of the observed resonances. Comet mineralogies typically are determined by fitting thermal emission models of ensembles of discrete mineral grains to observed IR spectral energy distributions. The absorptivities (Q-abs) and scattering efficiencies (Q-scat) of the discrete mineral grains are computed using Mie scattering, Maxwell-Garnet mixing, Discrete Dipole Approximation, and Multi-Layered Sphere codes. These techniques when applied to crystalline minerals, specifically olivine (Mg_x, Fe_1-x)2 Si04, x>0.9, require the use of ellipsoidal shaped particles with elongated axial ratios or hollow spheres to produce the shapes of the resonances observed both from comet comae and laboratory samples. The wavelength positions of the distinct resonances from submicron-radii crystalline silicates, as well as their thermal equilibrium temperatures, constrain the crystalline olivine to have a relatively high Mg-content (x>0.9, or Fo>90). Only resonances computed for submicron Mg-rich crystalline olivine and crystalline orthopyroxene match the observed IR spectral features. However, this has led to the interpretation that micron-radii and larger crystals are absent from comet comae. Furthermore, the mass fraction of silicate crystals is dependent upon whether just the submicron portion of the size distribution is being compared or the submicron crystals compare to the aggregates of porous amorphous silicates that are computationally tractable as porous spheres. We will discuss the Deep Impact results as examples of these challenges to interpreting mid-IR spectra of

IR radiation characteristics of rocket exhaust plumes under varying motor operating conditions

Directory of Open Access Journals (Sweden)

Qinglin NIU

2017-06-01

Full Text Available The infrared (IR irradiance signature from rocket motor exhaust plumes is closely related to motor type, propellant composition, burn time, rocket geometry, chamber parameters and flight conditions. In this paper, an infrared signature analysis tool (IRSAT was developed to understand the spectral characteristics of exhaust plumes in detail. Through a finite volume technique, flow field properties were obtained through the solution of axisymmetric Navier-Stokes equations with the Reynolds-averaged approach. A refined 13-species, 30-reaction chemistry scheme was used for combustion effects and a k-ε-Rt turbulence model for entrainment effects. Using flowfield properties as input data, the spectrum was integrated with a line of sight (LOS method based on a single line group (SLG model with Curtis-Godson approximation. The model correctly predicted spectral distribution in the wavelengths of 1.50–5.50 μm and had good agreement for its location with imaging spectrometer data. The IRSAT was then applied to discuss the effects of three operating conditions on IR signatures: (a afterburning; (b chamber pressure from ignition to cutoff; and (c minor changes in the ratio of hydroxyl-terminated polybutadiene (HTPB binder to ammonium perchlorate (AP oxidizer in propellant. Results show that afterburning effects can increase the size and shape of radiance images with enhancement of radiation intensity up to 40%. Also, the total IR irradiance in different bands can be characterized by a non-dimensional chamber pressure trace in which the maximum discrepancy is less than 13% during ignition and engine cutoff. An increase of chamber pressure can lead to more distinct diamonds, whose distance intervals are extended, and the position of the first diamond moving backwards. In addition, an increase in HTPB/AP causes a significant jump in spectral intensity. The incremental rates of radiance intensity integrated in each band are linear with the increase of HTPB

LIFTING THE DUSTY VEIL WITH NEAR- AND MID-INFRARED PHOTOMETRY. II. A LARGE-SCALE STUDY OF THE GALACTIC INFRARED EXTINCTION LAW

International Nuclear Information System (INIS)

Zasowski, G.; Majewski, S. R.; Indebetouw, R.

2009-01-01

We combine near-infrared (Two Micron All Sky Survey) and mid-infrared (Spitzer-IRAC) photometry to characterize the IR extinction law (1.2-8 μm) over nearly 150 deg. of contiguous Milky Way midplane longitude. The relative extinctions in five passbands across these wavelength and longitude ranges are derived by calculating color excess ratios for G and K giant red clump stars in contiguous midplane regions and deriving the wavelength dependence of extinction in each one. Strong, monotonic variations in the extinction law shape are found as a function of angle from the Galactic center, symmetric on either side of it. These longitudinal variations persist even when dense interstellar regions, known a priori to have a shallower extinction curve, are removed. The increasingly steep extinction curves toward the outer Galaxy indicate a steady decrease in the absolute-to-selective extinction ratio (R V ) and in the mean dust grain size at greater Galactocentric angles. We note an increasing strength of the 8 μm extinction inflection at high Galactocentric angles and, using theoretical dust models, show that this behavior is consistent with the trend in R V . Along several lines of sight where the solution is most feasible, A λ /A K s as a function of Galactic radius (R GC ) is estimated and shown to have a Galactic radial dependence. Our analyses suggest that the observed relationship between extinction curve shape and Galactic longitude is due to an intrinsic dependence of the extinction law on Galactocentric radius.

Optimization of silicon waveguides for gas detection application at mid-IR wavelengths

Science.gov (United States)

Butt, M. A.; Kozlova, E. S.

2018-04-01

There are several trace gases such as N2O, CO, CO2, NO, H2O, NO2, NH3, CH4 etc. which have their absorption peaks in Mid-IR spectrum These gases strongly absorb in the mid-IR > 2.5 μm spectral region due to their fundamental rotational and vibrational transitions. In this work, we modelled and optimized three different kinds of waveguides such as rib, strip and slot based on silicon platform to obtain maximum evanescent field ratio. These waveguides are designed at 3.39 μm and 4.67 μm which correspond to the absorption line of methane (CH4) and carbon monoxide (CO) respectively.

The Reipurth 50 - north infrared source

International Nuclear Information System (INIS)

Casali, M.M.

1991-01-01

Near-infrared imaging, imaging polarimetry and CVF spectroscopy of Re50N reveal the presence of a single illuminating source, IRS1. The extinction around IRS1 seems to be distributed anisotropically, with a lower extinction path to the reflection nebula than in the line-of-sight. IRS1 appears to be a young steep-spectrum object, with the bulk of its IR emission coming from hot dust. Multiple scattering in the tail of the reflection nebula could explain its relatively blue colours away from IRS1. (author)

Pixelated coatings and advanced IR coatings

Science.gov (United States)

Pradal, Fabien; Portier, Benjamin; Oussalah, Meihdi; Leplan, Hervé

2017-09-01

Reosc developed pixelated infrared coatings on detector. Reosc manufactured thick pixelated multilayer stacks on IR-focal plane arrays for bi-spectral imaging systems, demonstrating high filter performance, low crosstalk, and no deterioration of the device sensitivities. More recently, a 5-pixel filter matrix was designed and fabricated. Recent developments in pixelated coatings, shows that high performance infrared filters can be coated directly on detector for multispectral imaging. Next generation space instrument can benefit from this technology to reduce their weight and consumptions.

A High-resolution Multi-wavelength Simultaneous Imaging System with Solar Adaptive Optics

Energy Technology Data Exchange (ETDEWEB)

Rao, Changhui; Zhu, Lei; Gu, Naiting; Rao, Xuejun; Zhang, Lanqiang; Bao, Hua; Kong, Lin; Guo, Youming; Zhong, Libo; Ma, Xue’an; Li, Mei; Wang, Cheng; Zhang, Xiaojun; Fan, Xinlong; Chen, Donghong; Feng, Zhongyi; Wang, Xiaoyun; Wang, Zhiyong, E-mail: gunaiting@ioe.ac.cn [The Key Laboratory on Adaptive Optics, Chinese Academy of Sciences, P.O. Box 350, Shuangliu, Chengdu 610209, Sichuan (China)

2017-10-01

A high-resolution multi-wavelength simultaneous imaging system from visible to near-infrared bands with a solar adaptive optics system, in which seven imaging channels, including the G band (430.5 nm), the Na i line (589 nm), the H α line (656.3 nm), the TiO band (705.7 nm), the Ca ii IR line (854.2 nm), the He i line (1083 nm), and the Fe i line (1565.3 nm), are chosen, is developed to image the solar atmosphere from the photosphere layer to the chromosphere layer. To our knowledge, this is the solar high-resolution imaging system with the widest spectral coverage. This system was demonstrated at the 1 m New Vaccum Solar Telescope and the on-sky high-resolution observational results were acquired. In this paper, we will illustrate the design and performance of the imaging system. The calibration and the data reduction of the system are also presented.

The Carnegie Hubble Program: The Infrared Leavitt Law in IC 1613

Science.gov (United States)

Scowcroft, Victoria; Freedman, Wendy L.; Madore, Barry F.; Monson, Andrew J.; Persson, S. E.; Seibert, Mark; Rigby, Jane R.; Melbourne, Jason

2013-01-01

We have observed the dwarf galaxy IC 1613 at multiple epochs in the midinfrared using Spitzer and the in the near-infrared using the new FourStar near-IR camera on Magellan. We have constructed Cepheid period luminosity relations in the J, H, Ks, [3.6] and [4.5] bands and have used the run of their apparent distance moduli as a function of wavelength to derive the line of sight reddening and distance to IC 1613. Using a nineband fit, we find E(BV ) = 0.050.01 mag and an extinction corrected distance modulus of 0 = 24.29 0.03statistical 0.03systematic mag. By comparing our multiband and [3.6] distance moduli to results from the tip of the red giant branch and red clump distance indicators, we find that metallicity has no measurable effect on Cepheid distances at 3.6 m in the metallicity range 1.0 [Fe/H] 0.2, hence derivations of the Hubble constant at this wavelength require no correction for metallicity.

[Infrared spectroscopic analysis of Guilin watermelon frost products].

Science.gov (United States)

Huang, Dong-lan; Chen, Xiao-kang; Xu, Yong-qun; Sun, Su-qin; Zhou, Qun; Lu, Wen-guan

2012-08-01

The objective of the present study is to analyze different products of Guilin watermelon frost by Fourier transform infrared spectroscopy (FTIR), second derivative infrared spectroscopy and two-dimensional correlation spectroscopy (2D-IR) under thermal perturbation. The structural information of the samples indicates that samples from the same factory but of different brands had some dissimilarities in the IR spectra, and the type and content of accessories of them were different compared with conventional IR spectra of samples, peaks at 638 and 616 cm(-1) all arise from anhydrous sodium sulfate in watermelon frost spray and watermelon frost capsule; the characteristic absorption peaks of the sucrose, dextrin or other accessories can be seen clearly in the spectra of watermelon frost throat-clearing buccal tablets, watermelon frost throat tablets and watermelon frost lozenge. And the IR spectra of watermelon frost lozenge is very similar to the IR spectra of sucrose, so it can be easily proved that the content of sucrose in watermelon frost lozenge is high. In the 2D-IR correlation spectra, the samples presented the differences in the position, number and relative intensity of autopeaks and correlation peak clusters. Consequently, the macroscopical fingerprint characters of FTIR, second derivative infrared spectra and 2D-IR spectra can not only provide the information about main chemical constituents in medical materials, but also analyze and identify the type and content of accessories in Guilin watermelon frost. In conclusion, the multi-steps IR macro-fingerprint method is rapid, effective, visual and accurate for pharmaceutical research.

Background–limited long wavelength infrared InAs/InAs1− xSbx type-II superlattice-based photodetectors operating at 110 K

Directory of Open Access Journals (Sweden)

Abbas Haddadi

2017-03-01

Full Text Available We report the demonstration of high-performance long-wavelength infrared (LWIR nBn photodetectors based on InAs/InAs1− xSbx type-II superlattices. A new saw-tooth superlattice design was used to implement the electron barrier of the photodetectors. The device exhibited a cut-off wavelength of ∼10 μ m at 77 K. The photodetector exhibited a peak responsivity of 2.65 A/W, corresponding to a quantum efficiency of 43%. With an R × A of 664 Ω · cm 2 and a dark current density of 8 × 10−5 A/cm2, under −80 mV bias voltage at 77 K, the photodetector exhibited a specific detectivity of 4.72 × 1011 cm· Hz / W and a background–limited operating temperature of 110 K.

Infrared technique for measuring steam density

International Nuclear Information System (INIS)

Snyder, S.C.; Baker, A.G.

1982-01-01

A prototype infrared steam densitometer using a two-wavelength, dual-beam technique was developed. Tests were performed on dry steam flows with this technique, which uses two narrow bandwidths of infrared light in the region of 0.9 to 3.0 μm. One wavelength is absorbed by steam, while the other is not. The latter wavelength is used to account for nonabsorptive light losses. In addition to the beam that traverses the steam flow, a reference beam that does not traverse the flow allows the light source to be monitored. The theory of the device is presented, along with a description of the components and of the system's operation. Test results are also presented

High-accuracy alignment based on atmospherical dispersion - technological approaches and solutions for the dual-wavelength transmitter

International Nuclear Information System (INIS)

Burkhard, Boeckem

1999-01-01

In the course of the progressive developments of sophisticated geodetic systems utilizing electromagnetic waves in the visible or near IR-range a more detailed knowledge of the propagation medium and coevally solutions of atmospherically induced limitations will become important. An alignment system based on atmospherical dispersion, called a dispersometer, is a metrological solution to the atmospherically induced limitations, in optical alignment and direction observations of high accuracy. In the dispersometer we are using the dual-wavelength method for dispersive air to obtain refraction compensated angle measurements, the detrimental impact of atmospheric turbulence notwithstanding. The principle of the dual-wavelength method utilizes atmospherical dispersion, i.e. the wavelength dependence of the refractive index. The difference angle between two light beams of different wavelengths, which is called the dispersion angle Δβ, is to first approximation proportional to the refraction angle: β IR ν(β blue - β IR ) = ν Δβ, this equation implies that the dispersion angle has to be measured at least 42 times more accurate than the desired accuracy of the refraction angle for the wavelengths used in the present dispersometer. This required accuracy constitutes one major difficulty for the instrumental performance in applying the dispersion effect. However, the dual-wavelength method can only be successfully used in an optimized transmitter-receiver combination. Beyond the above mentioned resolution requirement for the detector, major difficulties in instrumental realization arise in the availability of a suitable dual-wavelength laser light source, laser light modulation with a very high extinction ratio and coaxial emittance of mono-mode radiation at both wavelengths. Therefore, this paper focuses on the solutions of the dual-wavelength transmitter introducing a new hardware approach and a complete re-design of the in [1] proposed conception of the dual-wavelength

Atomic layer deposition of absorbing thin films on nanostructured electrodes for short-wavelength infrared photosensing

Energy Technology Data Exchange (ETDEWEB)

Xu, Jixian; Sutherland, Brandon R.; Hoogland, Sjoerd; Fan, Fengjia; Sargent, Edward H., E-mail: ted.sargent@utoronto.ca [Department of Electrical and Computer Engineering, University of Toronto, 10 King' s College Road, Toronto, Ontario M5S 3G4 (Canada); Kinge, Sachin [Advanced Technology, Materials and Research, Research and Development, Hoge Wei 33- Toyota Technical Centre, B-1930 Zaventem (Belgium)

2015-10-12

Atomic layer deposition (ALD), prized for its high-quality thin-film formation in the absence of high temperature or high vacuum, has become an industry standard for the large-area deposition of a wide array of oxide materials. Recently, it has shown promise in the formation of nanocrystalline sulfide films. Here, we demonstrate the viability of ALD lead sulfide for photodetection. Leveraging the conformal capabilities of ALD, we enhance the absorption without compromising the extraction efficiency in the absorbing layer by utilizing a ZnO nanowire electrode. The nanowires are first coated with a thin shunt-preventing TiO{sub 2} layer, followed by an infrared-active ALD PbS layer for photosensing. The ALD PbS photodetector exhibits a peak responsivity of 10{sup −2} A W{sup −1} and a shot-derived specific detectivity of 3 × 10{sup 9} Jones at 1530 nm wavelength.

Multiple infrared bands absorber based on multilayer gratings

Science.gov (United States)

Liu, Xiaoyi; Gao, Jinsong; Yang, Haigui; Wang, Xiaoyi; Guo, Chengli

2018-03-01

The present study offers an Ag/Si multilayer-grating microstructure based on an Si substrate. The microstructure exhibits designable narrowband absorption in multiple infrared wavebands, especially in mid- and long-wave infrared atmospheric windows. We investigate its resonance mode mechanism, and calculate the resonance wavelengths by the Fabry-Perot and metal-insulator-metal theories for comparison with the simulation results. Furthermore, we summarize the controlling rules of the absorption peak wavelength of the microstructure to provide a new method for generating a Si-based device with multiple working bands in infrared.

Infrared analysis for determining macronutrients in human milk

DEFF Research Database (Denmark)

Michaelsen, K F; Pedersen, S B; Skafte, L

1988-01-01

Infrared (IR) analysis is widely used for routine analysis of cow milk in dairies. The aim of this study was to evaluate the precision and accuracy of an IR analyzer (Milko-scan 104) for measuring protein, fat, carbohydrate, and, indirectly, the energy content of human milk. The results of the IR...

Impact of sensor-scene interaction on the design of an IR security surveillance system

International Nuclear Information System (INIS)

Claassen, J.P.; Phipps, G.S.

1982-01-01

Recent encouraging developments in infrared staring arrays with CCD readouts and in real time image processors working on and off the focal plane have suggested that technologies suitable for infrared security surveillance may be available in a two-to-five year time frame. In anticipation of these emerging technologies, an investigation has been undertaken to establish the design potential of a passive IR perimeter security system incorporating both detection and verification capabilities. To establish the design potential, it is necessary to characterize the interactions between the scene ad the sensor. To this end, theoretical and experimental findings were employed to document (1) the emission properties of scenes to include an intruder, (2) the propagation and emission characteristics of the intervening atmosphere, and (3) the reception properties of the imaging sensor. The impact of these findings are summarized in the light of the application constraints. Optimal wavelengths, intruder and background emission characteristics, weather limitations, and basic sensor design considerations are treated. Although many system design features have been identified to this date, continued efforts are required to complete a detailed system design to include the identifying processing requirements. A program to accomplish these objectives is presented

Search for bright stars with infrared excess

Energy Technology Data Exchange (ETDEWEB)

Raharto, Moedji, E-mail: moedji@as.itb.ac.id [Astronomy Research Division, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia)

2014-03-24

Bright stars, stars with visual magnitude smaller than 6.5, can be studied using small telescope. In general, if stars are assumed as black body radiator, then the color in infrared (IR) region is usually equal to zero. Infrared data from IRAS observations at 12 and 25μm (micron) with good flux quality are used to search for bright stars (from Bright Stars Catalogues) with infrared excess. In magnitude scale, stars with IR excess is defined as stars with IR color m{sub 12}−m{sub 25}>0; where m{sub 12}−m{sub 25} = −2.5log(F{sub 12}/F{sub 25})+1.56, where F{sub 12} and F{sub 25} are flux density in Jansky at 12 and 25μm, respectively. Stars with similar spectral type are expected to have similar color. The existence of infrared excess in the same spectral type indicates the existence of circum-stellar dust, the origin of which is probably due to the remnant of pre main-sequence evolution during star formation or post AGB evolution or due to physical process such as the rotation of those stars.

Infrared and radio emission from S0 galaxies

International Nuclear Information System (INIS)

Bally, J.; Thronson, H.A. Jr.

1989-01-01

Far-IR data are presented on 74 early-type S0 galaxies that were selected on the basis of the availability of radio-continuum measurements. Most of the galaxies are detected at IR wavelengths with IRAS, indicating the presence of a cold interstellar medium (ISM) in these galaxies. The mass of gas in these systems is estimated to lie in the range of 10 to the 7th to 10 to the 10th solar. The most massive ISM in some S0s approaches that found in some spirals. The brighter IR-emitting galaxies all lie close to a relationship established for gas-rich spiral galaxies. None of these galaxies have large ratio fluxes, suggesting that strong nuclear radio sources or extended radio lobes and jets are absent or suppressed. Strong radio emission is found among those galaxies that are either faint or not detected at IR wavelengths. The absence of an ISM suggests that these galaxies are of an earlier type that those that have large IR fluxes. 38 references

Short-wavelength infrared imaging using low dark current InGaAs detector arrays and vertical-cavity surface-emitting laser illuminators

Science.gov (United States)

Macdougal, Michael; Geske, Jon; Wang, Chad; Follman, David

2011-06-01

We describe the factors that go into the component choices for a short wavelength IR (SWIR) imager, which include the SWIR sensor, the lens, and the illuminator. We have shown the factors for reducing dark current, and shown that we can achieve well below 1.5 nA/cm2 for 15 μm devices at 7 °C. In addition, we have mated our InGaAs detector arrays to 640×512 readout integrated integrated circuits to make focal plane arrays (FPAs). The resulting FPAs are capable of imaging photon fluxes with wavelengths between 1 and 1.6 μm at low light levels. The dark current associated with these FPAs is extremely low, exhibiting a mean dark current density of 0.26 nA/cm2 at 0 °C. Noise due to the readout can be reduced from 95 to 57 electrons by using off-chip correlated double sampling. In addition, Aerius has developed laser arrays that provide flat illumination in scenes that are normally light-starved. The illuminators have 40% wall-plug efficiency and provide low-speckle illumination, and provide artifact-free imagery versus conventional laser illuminators.

Wide-field Spatio-Spectral Interferometry: Bringing High Resolution to the Far- Infrared

Science.gov (United States)

Leisawitx, David

Wide-field spatio-spectral interferometry combines spatial and spectral interferometric data to provide integral field spectroscopic information over a wide field of view. This technology breaks through a mission cost barrier that stands in the way of resolving spatially and measuring spectroscopically at far-infrared wavelengths objects that will lead to a deep understanding of planetary system and galaxy formation processes. A space-based far-IR interferometer will combine Spitzer s superb sensitivity with a two order of magnitude gain in angular resolution, and with spectral resolution in the thousands. With the possible exception of detector technology, which is advancing with support from other research programs, the greatest challenge for far-IR interferometry is to demonstrate that the interferometer will actually produce the images and spectra needed to satisfy mission science requirements. With past APRA support, our team has already developed the highly specialized hardware testbed, image projector, computational model, and image construction software required for the proposed effort, and we have access to an ideal test facility.

Pulsed infrared radiation excites cultured neonatal spiral and vestibular ganglion neurons by modulating mitochondrial calcium cycling.

Science.gov (United States)

Lumbreras, Vicente; Bas, Esperanza; Gupta, Chhavi; Rajguru, Suhrud M

2014-09-15

Cochlear implants are currently the most effective solution for profound sensorineural hearing loss, and vestibular prostheses are under development to treat bilateral vestibulopathies. Electrical current spread in these neuroprostheses limits channel independence and, in some cases, may impair their performance. In comparison, optical stimuli that are spatially confined may result in a significant functional improvement. Pulsed infrared radiation (IR) has previously been shown to elicit responses in neurons. This study analyzes the response of neonatal rat spiral and vestibular ganglion neurons in vitro to IR (wavelength = 1,863 nm) using Ca(2+) imaging. Both types of neurons responded consistently with robust intracellular Ca(2+) ([Ca(2+)]i) transients that matched the low-frequency IR pulses applied (4 ms, 0.25-1 pps). Radiant exposures of ∼637 mJ/cm(2) resulted in continual neuronal activation. Temperature or [Ca(2+)] variations in the media did not alter the IR-evoked transients, ruling out extracellular Ca(2+) involvement or primary mediation by thermal effects on the plasma membrane. While blockage of Na(+), K(+), and Ca(2+) plasma membrane channels did not alter the IR-evoked response, blocking of mitochondrial Ca(2+) cycling with CGP-37157 or ruthenium red reversibly inhibited the IR-evoked [Ca(2+)]i transients. Additionally, the magnitude of the IR-evoked transients was dependent on ryanodine and cyclopiazonic acid-dependent Ca(2+) release. These results suggest that IR modulation of intracellular calcium cycling contributes to stimulation of spiral and vestibular ganglion neurons. As a whole, the results suggest selective excitation of neurons in the IR beam path and the potential of IR stimulation in future auditory and vestibular prostheses. Copyright © 2014 the American Physiological Society.

Optical wavelength selection for portable hemoglobin determination by near-infrared spectroscopy method

Science.gov (United States)

Tian, Han; Li, Ming; Wang, Yue; Sheng, Dinggao; Liu, Jun; Zhang, Linna

2017-11-01

Hemoglobin concentration is commonly used in clinical medicine to diagnose anemia, identify bleeding, and manage red blood cell transfusions. The golden standard method for determining hemoglobin concentration in blood requires reagent. Spectral methods were advantageous at fast and non-reagent measurement. However, model calibration with full spectrum is time-consuming. Moreover, it is necessary to use a few variables considering size and cost of instrumentation, especially for a portable biomedical instrument. This study presents different wavelength selection methods for optical wavelengths for total hemoglobin concentration determination in whole blood. The results showed that modelling using only two wavelengths combination (1143 nm, 1298 nm) can keep on the fine predictability with full spectrum. It appears that the proper selection of optical wavelengths can be more effective than using the whole spectra for determination hemoglobin in whole blood. We also discussed the influence of water absorptivity on the wavelength selection. This research provides valuable references for designing portable NIR instruments determining hemoglobin concentration, and may provide some experience for noninvasive hemoglobin measurement by NIR methods.

A NEAR-INFRARED SPECTROSCOPIC STUDY OF YOUNG FIELD ULTRACOOL DWARFS

Energy Technology Data Exchange (ETDEWEB)

Allers, K. N. [Department of Physics and Astronomy, Bucknell University, Lewisburg, PA 17837 (United States); Liu, Michael C., E-mail: k.allers@bucknell.edu [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Drive, Honolulu, HI 96822 (United States)

2013-08-01

We present a near-infrared (0.9-2.4 {mu}m) spectroscopic study of 73 field ultracool dwarfs having spectroscopic and/or kinematic evidence of youth ( Almost-Equal-To 10-300 Myr). Our sample is composed of 48 low-resolution (R Almost-Equal-To 100) spectra and 41 moderate-resolution spectra (R {approx}> 750-2000). First, we establish a method for spectral typing M5-L7 dwarfs at near-IR wavelengths that is independent of gravity. We find that both visual and index-based classification in the near-IR provides consistent spectral types with optical spectral types, though with a small systematic offset in the case of visual classification at J and K band. Second, we examine features in the spectra of {approx}10 Myr ultracool dwarfs to define a set of gravity-sensitive indices based on FeH, VO, K I, Na I, and H-band continuum shape. We then create an index-based method for classifying the gravities of M6-L5 dwarfs that provides consistent results with gravity classifications from optical spectroscopy. Our index-based classification can distinguish between young and dusty objects. Guided by the resulting classifications, we propose a set of low-gravity spectral standards for the near-IR. Finally, we estimate the ages corresponding to our gravity classifications.

Rapid differentiation of Listeria monocytogenes epidemic clones III and IV and their intact compared with heat-killed populations using Fourier transform infrared spectroscopy and chemometrics.

Science.gov (United States)

Nyarko, Esmond B; Puzey, Kenneth A; Donnelly, Catherine W

2014-06-01

The objectives of this study were to determine if Fourier transform infrared (FT-IR) spectroscopy and multivariate statistical analysis (chemometrics) could be used to rapidly differentiate epidemic clones (ECs) of Listeria monocytogenes, as well as their intact compared with heat-killed populations. FT-IR spectra were collected from dried thin smears on infrared slides prepared from aliquots of 10 μL of each L. monocytogenes ECs (ECIII: J1-101 and R2-499; ECIV: J1-129 and J1-220), and also from intact and heat-killed cell populations of each EC strain using 250 scans at a resolution of 4 cm(-1) in the mid-infrared region in a reflectance mode. Chemometric analysis of spectra involved the application of the multivariate discriminant method for canonical variate analysis (CVA) and linear discriminant analysis (LDA). CVA of the spectra in the wavelength region 4000 to 600 cm(-1) separated the EC strains while LDA resulted in a 100% accurate classification of all spectra in the data set. Further, CVA separated intact and heat-killed cells of each EC strain and there was 100% accuracy in the classification of all spectra when LDA was applied. FT-IR spectral wavenumbers 1650 to 1390 cm(-1) were used to separate heat-killed and intact populations of L. monocytogenes. The FT-IR spectroscopy method allowed discrimination between strains that belong to the same EC. FT-IR is a highly discriminatory and reproducible method that can be used for the rapid subtyping of L. monocytogenes, as well as for the detection of live compared with dead populations of the organism. Fourier transform infrared (FT-IR) spectroscopy and multivariate statistical analysis can be used for L. monocytogenes source tracking and for clinical case isolate comparison during epidemiological investigations since the method is capable of differentiating epidemic clones and it uses a library of well-characterized strains. The FT-IR method is potentially less expensive and more rapid compared to genetic

Differentiation between probiotic and wild-type Bacillus cereus isolates by antibiotic susceptibility test and Fourier transform infrared spectroscopy (FT-IR).

Science.gov (United States)

Mietke, Henriette; Beer, W; Schleif, Julia; Schabert, G; Reissbrodt, R

2010-05-30

Animal feed often contains probiotic Bacillus strains used as feed additives. Spores of the non-pathogenic B. cereus var. toyoi (product name Toyocerin) are used. Distinguishing between toxic wild-type Bacillus cereus strains and this probiotic strain is essential for evaluating the quality and risk of feed. Bacillus cereus CIP 5832 (product name Paciflor was used as probiotic strain until 2001. The properties of the two probiotic strains are quite similar. Differentiating between probiotic strains and wild-type B. cereus strains is not easy. ss-lactam antibiotics such as penicillin and cefamandole exhibit an inhibition zone in the agar diffusion test of probiotic B. cereus strains which are not seen for wild-type strains. Therefore, performing the agar diffusion test first may make sense before FT-IR testing. When randomly checking these strains by Fourier transform infrared spectroscopy (FT-IR), the probiotic B. cereus strains were separated from wild-type B. cereus/B. thuringiensis/B. mycoides/B. weihenstephanensis strains by means of hierarchical cluster analysis. The discriminatory information was contained in the spectral windows 3000-2800 cm(-1) ("fatty acid region"), 1200-900 cm(-1) ("carbohydrate region") and 900-700 cm(-1) ("fingerprint region"). It is concluded that FT-IR spectroscopy can be used for the rapid quality control and risk analysis of animal feed containing probiotic B. cereus strains. (c) 2010 Elsevier B.V. All rights reserved.

Nighttime Infrared radiative cooling and opacity inferred by REMS Ground Temperature Sensor Measurements

Science.gov (United States)

Martín-Torres, Javier; Paz Zorzano, María; Pla-García, Jorge; Rafkin, Scot; Lepinette, Alain; Sebastián, Eduardo; Gómez-Elvira, Javier; REMS Team

2013-04-01

Due to the low density of the Martian atmosphere, the temperature of the surface is controlled primarily by solar heating, and infrared cooling to the atmosphere and space, rather than heat exchange with the atmosphere. In the absence of solar radiation the infrared (IR) cooling, and then the nighttime surface temperatures, are directly controlled by soil termal inertia and atmospheric optical thickness (τ) at infrared wavelengths. Under non-wind conditions, and assuming no processes involving latent heat changes in the surface, for a particular site where the rover stands the main parameter controlling the IR cooling will be τ. The minimal ground temperature values at a fixed position may thus be used to detect local variations in the total dust/aerosols/cloud tickness. The Ground Temperature Sensor (GTS) and Air Temperature Sensor (ATS) in the Rover Environmental Monitoring Station (REMS) on board the Mars Science Laboratory (MSL) Curiosity rover provides hourly ground and air temperature measurements respectively. During the first 100 sols of operation of the rover, within the area of low thermal inertia, the minimal nightime ground temperatures reached values between 180 K and 190 K. For this season the expected frost point temperature is 200 K. Variations of up to 10 K have been observed associated with dust loading at Gale at the onset of the dust season. We will use these measurements together with line-by-line radiative transfer simulations using the Full Transfer By Optimized LINe-by-line (FUTBOLIN) code [Martín-Torres and Mlynczak, 2005] to estimate the IR atmospheric opacity and then dust/cloud coverage over the rover during the course of the MSL mission. Monitoring the dust loading and IR nightime cooling evolution during the dust season will allow for a better understanding of the influence of the atmosphere on the ground temperature and provide ground truth to models and orbiter measurements. References Martín-Torres, F. J. and M. G. Mlynczak

IPHAS A-TYPE STARS WITH MID-INFRARED EXCESSES IN SPITZER SURVEYS

International Nuclear Information System (INIS)

Hales, Antonio S.; Barlow, Michael J.; Drew, Janet E.; Unruh, Yvonne C.; Greimel, Robert; Irwin, Michael J.; Gonzalez-Solares, Eduardo

2009-01-01

We have identified 17 A-type stars in the Galactic Plane that have mid-infrared (mid-IR) excesses at 8 μm. From observed colors in the (r' - Hα) - (r' - i') plane, we first identified 23,050 early A-type main-sequence (MS) star candidates in the Isaac Newton Photometric H-Alpha Survey (IPHAS) point source database that are located in Spitzer Galactic Legacy Mid-Plane Survey Extraordinaire Galactic plane fields. Imposing the requirement that they be detected in all seven Two Micron All Sky Survey and Infrared Astronomical Satellite bands led to a sample of 2692 candidate A-type stars with fully sampled 0.6 to 8 μm spectral energy distributions (SEDs). Optical classification spectra of 18 of the IPHAS candidate A-type MS stars showed that all but one could be well fitted using MS A-type templates, with the other being an A-type supergiant. Out of the 2692 A-type candidates 17 (0.6%) were found to have 8 μm excesses above the expected photospheric values. Taking into account non-A-Type contamination estimates, the 8 μm excess fraction is adjusted to ∼0.7%. The distances to these sources range from 0.7 to 2.5 kpc. Only 10 out of the 17 excess stars had been covered by Spitzer MIPSGAL survey fields, of which five had detectable excesses at 24 μm. For sources with excesses detected in at least two mid-IR wavelength bands, blackbody fits to the excess SEDs yielded temperatures ranging from 270 to 650 K, and bolometric luminosity ratios L IR /L * from 2.2 x 10 -3 - 1.9 x 10 -2 , with a mean value of 7.9 x 10 -3 (these bolometric luminosities are lower limits as cold dust is not detectable by this survey). Both the presence of mid-IR excesses and the derived bolometric luminosity ratios are consistent with many of these systems being in the planet-building transition phase between the early protoplanetary disk phase and the later debris disk phase.

Photometric Modeling and VIS-IR Albedo Maps of Dione From Cassini-VIMS

Science.gov (United States)

Filacchione, G.; Ciarniello, M.; D'Aversa, E.; Capaccioni, F.; Cerroni, P.; Buratti, B. J.; Clark, R. N.; Stephan, K.; Plainaki, C.

2018-03-01

We report about visible and infrared albedo maps and spectral indicators of Dione's surface derived from the complete Visual and Infrared Mapping Spectrometer (VIMS) data set acquired between 2004 and 2017 during the Cassini tour in Saturn's system. Maps are derived by applying a photometric correction necessary to disentangle the intrinsic albedo of the surface from illumination and viewing geometry occurring at the time of the observation. The photometric correction is based on the Shkuratov et al. (2011, https://doi.org/10.1016/j.pss.2011.06.011) method which yields values of the surface equigonal albedo. Dione's surface albedo maps are rendered at five visible (VIS: 0.35, 0.44, 0.55, 0.7, and 0.95 μm) and five infrared (IR: 1.046, 1.540, 1.822, 2.050, and 2.200 μm) wavelengths in cylindrical projection with a 0.5° × 0.5° angular resolution in latitude and longitude, corresponding to a spatial resolution of 4.5 km/bin. Apart from visible and infrared albedo maps, we report about the distribution of the two visible spectral slopes (0.35-0.55 and 0.55-0.95 μm) and water ice 2.050 μm band depth computed after having applied the photometric correction. The derived spectral indicators are employed to trace Dione's composition variability on both global and local scales allowing to study the dichotomy between the bright‐leading and dark‐trailing hemispheres, the distribution of fresh material on the impact craters and surrounding ejecta, and the resurfacing of the bright material within the chasmata caused by tectonism.

Fourier Transform Infrared Spectroscopy Part III. Applications.

Science.gov (United States)

Perkins, W. D.

1987-01-01

Discusses the use of the FT-IR spectrometer in analyses that were previously avoided. Examines some of the applications of this spectroscopy with aqueous solutions, circular internal reflection, samples with low transmission, diffuse reflectance, infrared emission, and the infrared microscope. (TW)

ON INFRARED EXCESSES ASSOCIATED WITH Li-RICH K GIANTS

Energy Technology Data Exchange (ETDEWEB)

Rebull, Luisa M. [Spitzer Science Center (SSC) and Infrared Science Archive (IRSA), Infrared Processing and Analysis Center - IPAC, 1200 E. California Blvd., California Institute of Technology, Pasadena, CA 91125 (United States); Carlberg, Joleen K. [NASA Goddard Space Flight Center, Code 667, Greenbelt, MD 20771 (United States); Gibbs, John C.; Cashen, Sarah; Datta, Ashwin; Hodgson, Emily; Lince, Megan [Glencoe High School, 2700 NW Glencoe Rd., Hillsboro, OR 97124 (United States); Deeb, J. Elin [Bear Creek High School, 9800 W. Dartmouth Pl., Lakewood, CO 80227 (United States); Larsen, Estefania; Altepeter, Shailyn; Bucksbee, Ethan; Clarke, Matthew [Millard South High School, 14905 Q St., Omaha, NE 68137 (United States); Black, David V., E-mail: rebull@ipac.caltech.edu [Walden School of Liberal Arts, 4230 N. University Ave., Provo, UT 84604 (United States)

2015-10-15

Infrared (IR) excesses around K-type red giants (RGs) have previously been discovered using Infrared Astronomy Satellite (IRAS) data, and past studies have suggested a link between RGs with overabundant Li and IR excesses, implying the ejection of circumstellar shells or disks. We revisit the question of IR excesses around RGs using higher spatial resolution IR data, primarily from the Wide-field Infrared Survey Explorer. Our goal was to elucidate the link between three unusual RG properties: fast rotation, enriched Li, and IR excess. Our sample of RGs includes those with previous IR detections, a sample with well-defined rotation and Li abundance measurements with no previous IR measurements, and a large sample of RGs asserted to be Li-rich in the literature; we have 316 targets thought to be K giants, about 40% of which we take to be Li-rich. In 24 cases with previous detections of IR excess at low spatial resolution, we believe that source confusion is playing a role, in that either (a) the source that is bright in the optical is not responsible for the IR flux, or (b) there is more than one source responsible for the IR flux as measured in IRAS. We looked for IR excesses in the remaining sources, identifying 28 that have significant IR excesses by ∼20 μm (with possible excesses for 2 additional sources). There appears to be an intriguing correlation in that the largest IR excesses are all in Li-rich K giants, though very few Li-rich K giants have IR excesses (large or small). These largest IR excesses also tend to be found in the fastest rotators. There is no correlation of IR excess with the carbon isotopic ratio, {sup 12}C/{sup 13}C. IR excesses by 20 μm, though relatively rare, are at least twice as common among our sample of Li-rich K giants. If dust shell production is a common by-product of Li enrichment mechanisms, these observations suggest that the IR excess stage is very short-lived, which is supported by theoretical calculations. Conversely, the

Analysis of bacteria on steel surfaces using reflectance micro-Fourier transform infrared spectroscopy.

Science.gov (United States)

Ojeda, Jesús J; Romero-González, María E; Banwart, Steven A

2009-08-01

Reflectance micro-Fourier transform infrared (FT-IR) analysis has been applied to characterize biofilm formation of Aquabacterium commune, a common microorganism present on drinking water distribution systems, onto the increasingly popular pipe material stainless steel EN1.4307. The applicability of the reflectance micro-FT-IR technique for analyzing the bacterial functional groups is discussed, and the results are compared to spectra obtained using more conventional FT-IR techniques: transmission micro-FT-IR, attenuated transmitted reflectance (ATR), and KBr pellets. The differences between the infrared spectra of wet and dried bacteria, as well as free versus attached bacteria, are also discussed. The spectra obtained using reflectance micro-FT-IR spectroscopy were comparable to those obtained using other FT-IR techniques. The absence of sample preparation, the potential to analyze intact samples, and the ability to characterize opaque and thick samples without the need to transfer the bacterial samples to an infrared transparent medium or produce a pure culture were the main advantages of reflectance micro-FT-IR spectroscopy.

AMA Conferences 2015. SENSOR 2015. 17th international conference on sensors and measurement technology. IRS2 2015. 14th international conference on infrared sensors and systems. Proceedings

International Nuclear Information System (INIS)

2015-01-01

This meeting paper contains presentations of two conferences: SENSOR 2015 and IRS 2 (= International conference on InfraRed Sensors and systems). The first part of SENSOR 2015 contains the following chapters: (A) SENSOR PRINCIPLES: A.1: Mechanical sensors; A.2: Optical sensors; A.3: Ultrasonic sensors; A.4: Microacoustic sensors; A.5: Magnetic sensors; A.6: Impedance sensors; A.7: Gas sensors; A.8: Flow sensors; A.9: Dimensional measurement; A.10: Temperature and humidity sensors; A.11: Chemosensors; A.12: Biosensors; A.13: Embedded sensors; A.14: Sensor-actuator systems; (B) SENSOR TECHNOLOGY: B.1: Sensor design; B.2: Numerical simulation of sensors; B.3: Sensor materials; B.4: MEMS technology; B.5: Micro-Nano-Integration; B.6: Packaging; B.7: Materials; B.8: Thin films; B.9: Sensor production; B.10: Sensor reliability; B.11: Calibration and testing; B.12: Optical fibre sensors. (C) SENSOR ELECTRONICS AND COMMUNICATION: C.1: Sensor electronics; C.2: Sensor networks; C.3: Wireless sensors; C.4: Sensor communication; C.5: Energy harvesting; C.6: Measuring systems; C.7: Embedded systems; C.8: Self-monitoring and diagnosis; (D) APPLICATIONS: D.1: Medical measuring technology; D.2: Ambient assisted living; D.3: Process measuring technology; D.4: Automotive; D.5: Sensors in energy technology; D.6: Production technology; D.7: Security technology; D.8: Smart home; D.9: Household technology. The second part with the contributions of the IRS 2 2015 is structured as follows: (E) INFRARED SENSORS: E.1: Photon detectors; E.2: Thermal detectors; E.3: Cooled detectors; E.4: Uncooled detectors; E.5: Sensor modules; E.6: Sensor packaging. (G) INFRARED SYSTEMS AND APPLICATIONS: G.1: Thermal imaging; G.2: Pyrometry / contactless temperature measurement; G.3: Gas analysis; G.4: Spectroscopy; G.5: Motion control and presence detection; G.6: Security and safety monitoring; G.7: Non-destructive testing; F: INFRARED SYSTEM COMPONENTS: F.1: Infrared optics; F.2: Optical modulators; F.3

Broadband infrared metamaterial absorber based on anodic aluminum oxide template

Science.gov (United States)

Yang, Jingfan; Qu, Shaobo; Ma, Hua; Wang, Jiafu; Yang, Shen; Pang, Yongqiang

2018-05-01

In this work, a broadband infrared metamaterial absorber is proposed based on trapezoid-shaped anodic aluminum oxide (AAO) template. Unlike traditional metamaterial absorber constructed from metal-dielectric-metal sandwich structure, our proposed absorber is composed of trapezoid-shaped AAO template with metallic nanowires inside. The infrared absorption efficiency is numerically calculated and the mechanism analysis is given in the paper. Owing to the superposition of multiple resonances produced by the nanowires with different heights, the infrared metamatrial absorber can keep high absorption efficiency during broad working wavelength band from 3.4 μm to 6.1 μm. In addition, the resonance wavelength is associated with the height of nanowires, which indicates that the resonance wavelength can be modulated flexibly through changing the heights of nanowires. This kind of design can also be adapted to other wavelength regions.

A MID-INFRARED VIEW OF THE HIGH MASS STAR FORMATION REGION W51A

Energy Technology Data Exchange (ETDEWEB)

Barbosa, C. L. [Laboratório Nacional de Astrofísica, R. dos Estados Unidos, Bairro das Nações, CEP 37504-364, Itajubá—MG (Brazil); Blum, R. D. [National Optical Astronomy Observatory, Tucson, AZ 85719 (United States); Damineli, A. [Instituto de Astronomia, Geofísica e Ciências Atmosféricas, Universidade de São Paulo, R. do Matão, 1226, Cid. Universitária, São Paulo 05508-900 (Brazil); Conti, P. S. [JILA, University of Colorado, Boulder, CO 80309-0440 (United States); Gusmão, D. M., E-mail: cassio.barbosa@pq.cnpq.br, E-mail: rblum@noao.edu, E-mail: augusto.damineli@iag.usp.br, E-mail: pconti@jila.colorado.edu, E-mail: danilo@univap.br [IP and D—Universidade do Vale do Paraíba, Av. Shishima Hifumi, 2911. São José dos Campos, SP, 12244-000 (Brazil)

2016-07-01

In this paper we present the results of a mid-infrared study of G49.5-0.4, or W51A, part of the massive starbirth complex W51. Combining public data from the Spitzer IRAC camera, and Gemini mid-infrared camera T-ReCS at 7.73, 9.69, 12.33, and 24.56 μ m, with a spatial resolution of ∼0.″5, we have identified the mid-infrared counterparts of eight ultracompact H ii regions, showing that two radio sources are deeply embedded in molecular clouds and another is a cloud of ionized gas. From the T-ReCS data we have unveiled the central core of the W51 region, revealing massive young stellar candidates. We modeled the spectral energy distribution of the detected sources. The results suggest that the embedded objects are sources with spectral types ranging from B3 to O5, but the majority of the fits indicate stellar objects with B1 spectral types. We also present an extinction map of IRS 2, showing that a region with lower extinction corresponds to the region where a proposed jet of gas has impacted the foreground cloud. From this map, we also derived the total extinction toward the enigmatic source IRS 2E, which amounts to ∼60 mag in the V band. We calculated the color temperature due to thermal emission of the circumstellar dust of the detected sources; the temperatures are in the interval of ∼100–150 K, which corresponds to the emission of dust located at 0.1 pc from the central source. Finally, we show a possible mid-infrared counterpart of a detected source at millimeter wavelengths that was found by Zapata et al. to be a massive young stellar object undergoing a high accretion rate.

Modelling and measurement of bandgap behaviour in medium-wavelength IR InAs/InAs0.815Sb0.185 strained-layer superlattices

Science.gov (United States)

Letka, Veronica; Keen, James; Craig, Adam; Marshall, Andrew R. J.

2017-10-01

InAs/InAs1-xSbx type-II strained-layer superlattices (SLS) are a structure with potential infrared detection applications, owing to its tunable bandgap and suppressed Auger recombination. A series of medium-wavelength infrared (MWIR) InAs/InAs0.815Sb0.185 SLS structures, grown as undoped absorption epilayers on GaAs, were fabricated using molecular beam epitaxy in order to study the dependence of the ground state transitions on temperature and superlattice period thickness. Photoluminescence peaks at 4 K were obtained with the use of a helium-cooled micro-PL system and an InSb detector, and temperature-dependent absorption spectra were measured in the range 77 K - 300 K on a Fourier Transform Infrared (FTIR) spectrometer, equipped with a 1370 K blackbody source and a DTGS detector. An nBn device sample with the absorber structure identical to one of the undoped samples was also grown and processed with the goal of measuring temperature-dependent spectral response. A model for superlattice band alignment was also devised, incorporating the Bir-Pikus transformation results for uniaxial and biaxial strain, and the Einstein oscillator model for bandgap temperature dependence. Absorption coefficients of several 1000 cm-1 throughout the entire MWIR range are found for all samples, and temperature dependence of the bandgaps is extracted and compared to the model. This and photoluminescence data also demonstrate bandgap shifts consistent with the different superlattice periods of the three samples.

Joint de-blurring and nonuniformity correction method for infrared microscopy imaging

Science.gov (United States)

Jara, Anselmo; Torres, Sergio; Machuca, Guillermo; Ramírez, Wagner; Gutiérrez, Pablo A.; Viafora, Laura A.; Godoy, Sebastián E.; Vera, Esteban

2018-05-01

In this work, we present a new technique to simultaneously reduce two major degradation artifacts found in mid-wavelength infrared microscopy imagery, namely the inherent focal-plane array nonuniformity noise and the scene defocus presented due to the point spread function of the infrared microscope. We correct both nuisances using a novel, recursive method that combines the constant range nonuniformity correction algorithm with a frame-by-frame deconvolution approach. The ability of the method to jointly compensate for both nonuniformity noise and blur is demonstrated using two different real mid-wavelength infrared microscopic video sequences, which were captured from two microscopic living organisms using a Janos-Sofradir mid-wavelength infrared microscopy setup. The performance of the proposed method is assessed on real and simulated infrared data by computing the root mean-square error and the roughness-laplacian pattern index, which was specifically developed for the present work.

High-speed high-sensitivity infrared spectroscopy using mid-infrared swept lasers (Conference Presentation)

Science.gov (United States)

Childs, David T. D.; Groom, Kristian M.; Hogg, Richard A.; Revin, Dmitry G.; Cockburn, John W.; Rehman, Ihtesham U.; Matcher, Stephen J.

2016-03-01

Infrared spectroscopy is a highly attractive read-out technology for compositional analysis of biomedical specimens because of its unique combination of high molecular sensitivity without the need for exogenous labels. Traditional techniques such as FTIR and Raman have suffered from comparatively low speed and sensitivity however recent innovations are challenging this situation. Direct mid-IR spectroscopy is being speeded up by innovations such as MEMS-based FTIR instruments with very high mirror speeds and supercontinuum sources producing very high sample irradiation levels. Here we explore another possible method - external cavity quantum cascade lasers (EC-QCL's) with high cavity tuning speeds (mid-IR swept lasers). Swept lasers have been heavily developed in the near-infrared where they are used for non-destructive low-coherence imaging (OCT). We adapt these concepts in two ways. Firstly by combining mid-IR quantum cascade gain chips with external cavity designs adapted from OCT we achieve spectral acquisition rates approaching 1 kHz and demonstrate potential to reach 100 kHz. Secondly we show that mid-IR swept lasers share a fundamental sensitivity advantage with near-IR OCT swept lasers. This makes them potentially able to achieve the same spectral SNR as an FTIR instrument in a time x N shorter (N being the number of spectral points) under otherwise matched conditions. This effect is demonstrated using measurements of a PDMS sample. The combination of potentially very high spectral acquisition rates, fundamental SNR advantage and the use of low-cost detector systems could make mid-IR swept lasers a powerful technology for high-throughput biomedical spectroscopy.

Infrared absorption of human breast tissues in vitro

Energy Technology Data Exchange (ETDEWEB)

Liu Chenglin [Department of Physics, Surface Physics Laboratory (National Key laboratory), Synchrotron Radiation Research Center, Fudan University, Shanghai 200433 (China); Physics Department of Yancheng Teachers' College, Yancheng 224002 (China); Zhang Yuan [Department of Physics, Surface Physics Laboratory (National Key laboratory), Synchrotron Radiation Research Center, Fudan University, Shanghai 200433 (China); Yan Xiaohui [Department of Physics, Surface Physics Laboratory (National Key laboratory), Synchrotron Radiation Research Center, Fudan University, Shanghai 200433 (China); Zhang Xinyi [Department of Physics, Surface Physics Laboratory (National Key laboratory), Synchrotron Radiation Research Center, Fudan University, Shanghai 200433 (China) and Shanghai Research Center of Acupuncture and Meridian, Pudong, Shanghai 201203 (China)]. E-mail: xy-zhang@fudan.edu.cn; Li Chengxiang [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China); Yang Wentao [Cancer Hospital, Medical Center, Fudan University, Shanghai 200032 (China); Shi Daren [Cancer Hospital, Medical Center, Fudan University, Shanghai 200032 (China)

2006-07-15

The spectral characteristics of human breast tissues in normal status and during different cancerous stages have been investigated by synchrotron radiation based Fourier transform infrared (SR-FTIR) absorption spectroscopy. Thanks to the excellent synchrotron radiation infrared (IR) source, higher resolving power is achieved in SR-FTIR absorption spectra than in conventional IR absorption measurements. Obvious variations in IR absorption spectrum of breast tissues were found as they change from healthy to diseased, or say in progression to cancer. On the other hand, some specific absorption peaks were found in breast cancer tissues by SR-FTIR spectroscopic methods. These spectral characteristics of breast tissue may help us in early diagnosis of breast cancer.

Modulation Transfer Function of Infrared Focal Plane Arrays

Science.gov (United States)

Gunapala, S. D.; Rafol, S. B.; Ting, D. Z.; Soibel, A.; Hill, C. J.; Khoshakhlagh, A.; Liu, J. K.; Mumolo, J. M.; Hoglund, L.; Luong, E. M.

2015-01-01

Modulation transfer function (MTF) is the ability of an imaging system to faithfully image a given object. The MTF of an imaging system quantifies the ability of the system to resolve or transfer spatial frequencies. In this presentation we will discuss the detail MTF measurements of 1024x1024 pixels mid -wavelength and long- wavelength quantum well infrared photodetector, and 320x256 pixels long- wavelength InAs/GaSb superlattice infrared focal plane arrays (FPAs). Long wavelength Complementary Barrier Infrared Detector (CBIRD) based on InAs/GaSb superlattice material is hybridized to recently designed and fabricated 320x256 pixel format ROIC. The n-type CBIRD was characterized in terms of performance and thermal stability. The experimentally measured NE delta T of the 8.8 micron cutoff n-CBIRD FPA was 18.6 mK with 300 K background and f/2 cold stop at 78K FPA operating temperature. The horizontal and vertical MTFs of this pixel fully delineated CBIRD FPA at Nyquist frequency are 49% and 52%, respectively.

Low background infrared (LBIR) facility

Data.gov (United States)

Federal Laboratory Consortium — The Low background infrared (LBIR) facility was originally designed to calibrate user supplied blackbody sources and to characterize low-background IR detectors and...

Trigger effect of infrared femtosecond laser irradiation on neoplasm in experimental cervical cancer

Science.gov (United States)

Gening, Tatyana; Voronova, Olga; Zolotovskii, Igor; Sysoliatin, Alexey; Dolgova, Dinara; Abakumova, Tatyana

2013-02-01

The present work discusses effect of infrared (IR) femtosecond laser irradiation on neoplasm of white mice with experimental cervical cancer- 5 (CC-5 on the 20th and 30th days after tumor transplantation). Tumor tissue was irradiated by femtosecond erbium doped fiber laser: the wavelength is 1.55 μm, average and peak powers are1,25 mW and 6kW, respectively, irradiation trials n=10. The average energy density (energy dose) on a tissue for two groups of animals was 0,24 J/cm2 and 0,36 J/cm2 for a single trial. Irradiation was followed by biochemical determination of LPO AOS parameters ("Lipid peroxidation-antioxidants" system): malondialdehyde (MDA), activity of superoxide dismutase (SOD), catalase and glutathione-reductase (GR), glutathione-S-transferase (GST). A subsequent morphological study of tumor tissue was performed. Mathematical analysis of data demonstrates a weak dependence of the studied parameters on energy dose. The latter implies the trigger effect of IR femtosecond laser irradiation on redox-dependent processes in neoplasm at experimental cervical cancer.

Infrared Radiative Properties of Food Materials

Science.gov (United States)

Precisely, infrared radiation is electromagnetic radiation whose wavelength is longer than that of visible light, but shorter than that of terahertz radiation and microwaves. The infrared portion of the electromagnetic spectrum spans roughly three orders of magnitude (750 nm to 100 µm) and has been...

Insight into regulation of emission color and photodeactivation process from heteroleptic to homoleptic Ir(III) complexes

Energy Technology Data Exchange (ETDEWEB)

Wang, Xin; Zheng, Danning; Feng, Songyan; Wang, Li, E-mail: chemwangl@henu.edu.cn; Li, Junfeng, E-mail: jfli@theochem.kth.se; Zhang, Jinglai, E-mail: zhangjinglai@henu.edu.cn

2017-03-15

The phosphorescent process of two heteroleptic ((DMDPI){sub 2}Ir(tftap) and (tftap){sub 2}Ir(DMDPI)) and one homoleptic (Ir(DMDPI){sub 3}) Ir(III) complexes (See ) is theoretically investigated by density functional theory (DFT) and quadratic response (QR) time-dependent density functional theory (TDDFT) calculations including spin-orbit coupling (SOC). Two or three triplet excited states are confirmed for three complexes, respectively. On the basis of the respective optimized triplet geometry, the emissive wavelength is determined by the ΔSCF-DFT method. Furthermore, the radiative rate constant (k{sub r}) is also calculated corresponding to each triplet state. Combination of k{sub r} and emissive energy, the emission rule is determined. It is found that complex (DMDPI){sub 2}Ir(tftap) follows the dual emission scenarios, while complexes (tftap){sub 2}Ir(DMDPI) and Ir(DMDPI){sub 3} obey the Kasha rule. The nonradiative rate constant (k{sub nr}) is qualitatively evaluated by the construction of triplet potential surface via metal centered ({sup 3}MC d-d) state. Finally, the sequence of quantum yield is compared by both k{sub r} and k{sub nr}. The quantum yield of homoleptic Ir(III) complex Ir(DMDPI){sub 3} is higher than that of heteroleptic Ir(III) complexes (DMDPI){sub 2}Ir(tftap) and (tftap){sub 2}Ir(DMDPI). However, the emissive wavelength of Ir(DMDPI){sub 3} is in the red color region rather than blue color.

Method for generation of tunable far infrared radiation from two-dimensional plasmons

Science.gov (United States)

Katz, Joseph (Inventor)

1989-01-01

Tunable far infrared radiation is produced from two-dimensional plasmons in a heterostructure, which provides large inversion-layer electron densities at the heterointerface, without the need for a metallic grating to couple out the radiation. Instead, a light interference pattern is produced on the planar surface of the heterostructure using two coherent laser beams of a wavelength selected to be strongly absorbed by the heterostructure in order to penetrate through the inversion layer. The wavelength of the far infrared radiation coupled out can then be readily tuned by varying the angle between the coherent beams, or varying the wavelength of the two interfering coherent beams, thus varying the periodicity of the photoconductivity grating to vary the wavelength of the far infrared radiation being coupled out.

Linearly Polarized IR Spectroscopy Theory and Applications for Structural Analysis

CERN Document Server

Kolev, Tsonko

2011-01-01

A technique that is useful in the study of pharmaceutical products and biological molecules, polarization IR spectroscopy has undergone continuous development since it first emerged almost 100 years ago. Capturing the state of the science as it exists today, "Linearly Polarized IR Spectroscopy: Theory and Applications for Structural Analysis" demonstrates how the technique can be properly utilized to obtain important information about the structure and spectral properties of oriented compounds. The book starts with the theoretical basis of linear-dichroic infrared (IR-LD) spectroscop

Infrared hyperspectral upconversion imaging using spatial object translation

DEFF Research Database (Denmark)

Kehlet, Louis Martinus; Sanders, Nicolai Højer; Tidemand-Lichtenberg, Peter

2015-01-01

In this paper hyperspectral imaging in the mid-infrared wavelength region is realised using nonlinear frequency upconversion. The infrared light is converted to the near-infrared region for detection with a Si-based CCD camera. The object is translated in a predefined grid by motorized actuators...

Mid-IR laser ultrasonic testing for fiber reinforced plastics

Science.gov (United States)

Kusano, Masahiro; Hatano, Hideki; Oguchi, Kanae; Yamawaki, Hisashi; Watanabe, Makoto; Enoki, Manabu

2018-04-01

Ultrasonic testing is the most common method to detect defects in materials and evaluate their sizes and locations. Since piezo-electric transducers are manually handled from point to point, it takes more costs for huge products such as airplanes. Laser ultrasonic testing (LUT) is a breakthrough technique. A pulsed laser generates ultrasonic waves on a material surface due to thermoelastic effect or ablation. The ultrasonic waves can be detected by another laser with an interferometer. Thus, LUT can realize instantaneous inspection without contacting a sample. A pulse laser with around 3.2 μm wavelength (in the mid-IR range) is more suitable to generate ultrasonic waves for fiber reinforced plastics (FRPs) because the light is well absorbed by the polymeric matrix. On the other hand, such a laser is not available in the market. In order to emit the mid-IR laser pulse, we came up with the application of an optical parametric oscillator and developed an efficient wavelength conversion device by pumping a compact Nd:YAG solid-state laser. Our mid-IR LUT system is most suitable for inspection of FRPs. The signal-to-noise ratio of ultrasonic waves generated by the mid-IR laser is higher than that by the Nd:YAG laser. The purpose of the present study is to evaluate the performance of the mid-IR LUT system in reflection mode. We investigated the effects of the material properties and the laser properties on the generated ultrasonic waves. In addition, C-scan images by the system were also presented.

Fleet Protection Using a Small UAV Based IR Sensor

National Research Council Canada - National Science Library

Buss, James R; Ax, Jr, George R

2005-01-01

A study was performed to define candidate electro-optical and infrared (EO/IR) sensor configurations and assess their potential utility as small UAV-based sensors surveilling a perimeter around surface fleet assets...

Red-IR stimulated luminescence in K-feldspar: Single or multiple trap origin?

DEFF Research Database (Denmark)

Andersen, Martin Thalbitzer; Jain, Mayank; Tidemand-Lichtenberg, Peter

2012-01-01

We investigate on the origins of the infra-red stimulated luminescence (IRSL) signals in 3 potassium feldspars based on IR-red spectroscopy (700–1050 nm) using a fiber-coupled tunable Ti:Sapphire laser, in combination with different thermal and optical (pre)treatments of the samples. We also...

The infrared radiation spectrum of acupoint taiyuan (LU 9) in asthma patients.

Science.gov (United States)

Zhou, Yu; Shen, Xue-yong; Wang, Li-zhen; Wei, Jian-zi; Cheng, Ke

2012-06-01

To analyze the distinctive pathological characteristics in the spectrums of spontaneous infrared radiation at the Taiyuan (LU 9) acupoint in patients with asthma. A highly sensitive infrared spectrum detecting device was used to detect the spectrums of spontaneous infrared radiation at Taiyuan (LU 9) in 37 asthma patients and 34 healthy volunteers. Asthma patients had significantly lower infrared intensity than that of the healthy volunteers (P>0.01). Asthma patients had significantly lower overall infrared radiation intensity at the left Taiyuan (LU 9) than that of healthy volunteers (P > 0.05), but there was no significant difference between healthy volunteers and asthma patients at the right Taiyuan (LU 9) (P > 0.05). The infrared radiation intensity of 17 wavelength spots at the left Taiyuan (LU 9) and 4 wavelength spots at the right Taiyuan (LU 9) in asthma patients were significantly lower than those of healthy volunteers (P > 0.05). At 2 microm, the infrared radiation intensity of asthma patients was significantly stronger than that of healthy volunteers (P > 0.05). At 19 wavelength spots in the healthy volunteers and at 4 wave-length spots in the asthma patients, the left Taiyuan (LU 9) showed a significantly stronger intensity than that of the right Taiyuan (LU 9) (P > 0.05S). By Pearson's chi2 test, healthy volunteers had more wavelength spots that were significantly different between the left and right Taiyuan (LU 9) than the asthma patients (P > 0.01). Changes in the infrared spectrum at the Taiyuan (LU 9) acupoint in asthma patients may reflect distinct pathological changes. Certain acupuncture points may be related to specific organs.

Infra-red process for colour fixation on fabrics

International Nuclear Information System (INIS)

Raymond, D.J.; Biau, D.

1983-01-01

Infra-red radiations find wide application in industrial processes as heating, drying, stoving and forming. The results are often far better than those from the other techniques: convection oven, gas IR etc ... They come from the electric IR specific advantages: energy direct transmission, emitter and product spectral coupling, possible selectivity. That is the case in the Textile Industry, where experiments showed that infra-red process heating could be efficient for colour fixation on fabrics. Shorter production cycles and energy saving are the main results

A MULTI-WAVELENGTH STUDY OF THE STAR-FORMING CORE AHEAD OF HH 80N

International Nuclear Information System (INIS)

Masque, Josep M.; Estalella, Robert; Osorio, Mayra; Anglada, Guillem; Girart, Josep M.; Garay, Guido; Calvet, Nuria; Beltran, Maria T.

2011-01-01

We present observations of continuum emission in the mid-infrared to millimeter wavelength range, complemented with ammonia observations, of the dense core ahead of the radio Herbig-Haro (HH) object HH 80N, found in the GGD 27 region. The continuum emission in all the observed bands peaks at the same position, consistent with the presence of an embedded object, HH 80N-IRS1, within the core. The distribution of the Very Large Array ammonia emission is well correlated with that of the dust, suggesting that photochemical effects caused by the nearby HH object do not play an important role in shaping this particular molecular emission. In order to unveil the nature of HH 80N-IRS1, we analyzed the continuum data of this source, using self-consistent models of protostellar collapse. We find that a young protostar surrounded by a slowly rotating collapsing envelope of radius ∼0.08 pc and 20 M sun plus a circumstellar disk of radius ∼300 AU and 0.6 M sun provide a good fit to the observed spectral energy distribution and to the maps at 350 μm, 1.2 mm, and 3.5 mm of HH 80N-IRS1. Besides, the Atacama Pathfinder Experiment and Plateau de Bure Interferometer continuum maps at 350 μm and 3.5 mm, respectively, reveal additional clumps in the continuum emission. Given the modeling results and the observed morphology of the emission, we propose a scenario consisting of a central embedded Class 0 object, HH 80N-IRS1, with the rest of the material of the HH 80N core possibly undergoing fragmentation that may lead to the formation of several protostars.

Simulation of attenuated total reflection infrared absorbance spectra: applications to automotive clear coat forensic analysis.

Science.gov (United States)

Lavine, Barry K; Fasasi, Ayuba; Mirjankar, Nikhil; Nishikida, Koichi; Campbell, Jay

2014-01-01

Attenuated total reflection (ATR) is a widely used sampling technique in infrared (IR) spectroscopy because minimal sample preparation is required. Since the penetration depth of the ATR analysis beam is quite shallow, the outer layers of a laminate or multilayered paint sample can be preferentially analyzed with the entire sample intact. For this reason, forensic laboratories are taking advantage of ATR to collect IR spectra of automotive paint systems that may consist of three or more layers. However, the IR spectrum of a paint sample obtained by ATR will exhibit distortions, e.g., band broadening and lower relative intensities at higher wavenumbers, compared with its transmission counterpart. This hinders library searching because most library spectra are measured in transmission mode. Furthermore, the angle of incidence for the internal reflection element, the refractive index of the clear coat, and surface contamination due to inorganic contaminants can profoundly influence the quality of the ATR spectrum obtained for automotive paints. A correction algorithm to allow ATR spectra to be searched using IR transmission spectra of the paint data query (PDQ) automotive database is presented. The proposed correction algorithm to convert transmission spectra from the PDQ library to ATR spectra is able to address distortion issues such as the relative intensities and broadening of the bands, and the introduction of wavelength shifts at lower frequencies, which prevent library searching of ATR spectra using archived IR transmission data.

Mid-infrared photonics in silicon and germanium

Science.gov (United States)

Soref, Richard

2010-08-01

Ingenious techniques are needed to extend group IV photonics from near-infrared to mid-infrared wavelengths. If achieved, the reward could be on-chip CMOS optoelectronic systems for use in spectroscopy, chemical and biological sensing, and free-space communications.

The Far-Infrared Emission Line and Continuum Spectrum of the Seyfert Galaxy NGC 1068

Science.gov (United States)

Spinoglio, Luigi; Smith, Howard A.; Gonzalez-Alfonso, Eduardo; Fisher, Jacqueline

2005-01-01

We report on the analysis of the first complete far-infrared spectrum (43-197 microns) of the Seyfert 2 galaxy NGC 1068 as observed with the Long Wavelength Spectrometer (LWS) onboard the Infrared Space Observatory (ISO). In addition to the 7 expected ionic fine structure emission lines, the OH rotational lines at 79, 119 and 163 microns were all detected in emission, which is unique among galaxies with full LWS spectra, where the 119 micron line, where detected, is always in absorption. The observed line intensities were modelled together with IS0 Short Wavelength Spectrometer (SWS) and optical and ultraviolet line intensities from the literature, considering two independent emission components: the AGN component and the starburst component in the circumnuclear ring of approximately 3kpc in size. Using the UV to mid-IR emission line spectrum to constrain the nuclear ionizing continuum, we have confirmed previous results: a canonical power-law ionizing spectrum is a poorer fit than one with a deep absorption trough, while the presence of a big blue bump is ruled out. Based on the instantaneous starburst age of 5 Myr constrained by the Br gamma equivalent width in the starburst ring, and starburst synthesis models of the mid- and far-infrared fine-structure line emission, a low ionization parameter (U=10(exp -3.5)) and low densities (n=100 cm (exp -3)) are derived. Combining the AGN and starburst components, we succeed in modeling the overall UV to far-IR atomic spectrum of SGC 1068, reproducing the line fluxes to within a factor 2.0 on average with a standard deviation of 1.4. The OH 119 micron emission indicates that the line is collisionally excited, and arises in a warm and dense region. The OH emission has been modeled using spherically symmetric, non-local, non-LTE radiative transfer models. The models indicate that the bulk of the emission arises from the nuclear region, although some extended contribution from the starburst is not ruled out. The OH abundance

Ammonia IR Absorbance Measurements with an Equilibrium Vapor Cell

National Research Council Canada - National Science Library

Field, Paul

2004-01-01

Infrared (IR) absorbance spectra were acquired for 18 ammonia vapor pressures. The vapor pressures were generated with 15 gravimetrically prepared aqueous solutions and three commercial aqueous solutions using a dynamic method I.E...

AMA Conferences 2015. SENSOR 2015. 17th international conference on sensors and measurement technology. IRS{sup 2} 2015. 14th international conference on infrared sensors and systems. Proceedings

Energy Technology Data Exchange (ETDEWEB)

NONE

2015-07-01

This meeting paper contains presentations of two conferences: SENSOR 2015 and IRS{sup 2} (= International conference on InfraRed Sensors and systems). The first part of SENSOR 2015 contains the following chapters: (A) SENSOR PRINCIPLES: A.1: Mechanical sensors; A.2: Optical sensors; A.3: Ultrasonic sensors; A.4: Microacoustic sensors; A.5: Magnetic sensors; A.6: Impedance sensors; A.7: Gas sensors; A.8: Flow sensors; A.9: Dimensional measurement; A.10: Temperature and humidity sensors; A.11: Chemosensors; A.12: Biosensors; A.13: Embedded sensors; A.14: Sensor-actuator systems; (B) SENSOR TECHNOLOGY: B.1: Sensor design; B.2: Numerical simulation of sensors; B.3: Sensor materials; B.4: MEMS technology; B.5: Micro-Nano-Integration; B.6: Packaging; B.7: Materials; B.8: Thin films; B.9: Sensor production; B.10: Sensor reliability; B.11: Calibration and testing; B.12: Optical fibre sensors. (C) SENSOR ELECTRONICS AND COMMUNICATION: C.1: Sensor electronics; C.2: Sensor networks; C.3: Wireless sensors; C.4: Sensor communication; C.5: Energy harvesting; C.6: Measuring systems; C.7: Embedded systems; C.8: Self-monitoring and diagnosis; (D) APPLICATIONS: D.1: Medical measuring technology; D.2: Ambient assisted living; D.3: Process measuring technology; D.4: Automotive; D.5: Sensors in energy technology; D.6: Production technology; D.7: Security technology; D.8: Smart home; D.9: Household technology. The second part with the contributions of the IRS{sup 2} 2015 is structured as follows: (E) INFRARED SENSORS: E.1: Photon detectors; E.2: Thermal detectors; E.3: Cooled detectors; E.4: Uncooled detectors; E.5: Sensor modules; E.6: Sensor packaging. (G) INFRARED SYSTEMS AND APPLICATIONS: G.1: Thermal imaging; G.2: Pyrometry / contactless temperature measurement; G.3: Gas analysis; G.4: Spectroscopy; G.5: Motion control and presence detection; G.6: Security and safety monitoring; G.7: Non-destructive testing; F: INFRARED SYSTEM COMPONENTS: F.1: Infrared optics; F.2: Optical

Direct evidence for the ring opening of monosaccharide anions in the gas phase: photodissociation of aldohexoses and aldohexoses derived from disaccharides using variable-wavelength infrared irradiation in the carbonyl stretch region

NARCIS (Netherlands)

Brown, D. J.; Stefan, S. E.; Berden, G.; Steill, J.D.; Oomens, J.; Eyler, J.R.; Bendiak, B.

2011-01-01

All eight d-aldohexoses and aldohexoses derived from the non-reducing end of disaccharides were investigated by variable-wavelength infrared multiple-photon dissociation (IRMPD) as anions in the negative-ion mode. Spectroscopic evidence supports the existence of a relatively abundant open-chain

Direct evidence for the ring opening of monosaccharide anions in the gas phase: photodissociation of aldohexoses and aldohexoses derived from disaccharides using variable-wavelength infrared irradiation in the carbonyl stretch region

NARCIS (Netherlands)

Brown, D. J.; Stefan, S. E.; G. Berden,; Steill, J. D.; Oomens, J.; Eyler, J. R.; Bendiak, B.

2011-01-01

All eight D-aldohexoses and aldohexoses derived from the non-reducing end of disaccharides were investigated by variable-wavelength infrared multiple-photon dissociation (IRMPD) as anions in the negative-ion mode. Spectroscopic evidence supports the existence of a relatively abundant open-chain

IR visible sum-frequency vibrational spectroscopy of Biphenyl-3 methylene thiol monolayer on gold and silver: effect of the visible wavelength on the SFG spectrum

Science.gov (United States)

Humbert, C.; Dreesen, L.; Mani, A. A.; Caudano, Y.; Lemaire, J.-J.; Thiry, P. A.; Peremans, A.

2002-04-01

We measured IR-visible sum-frequency generation spectra of CH 3-(C 6H 4) 2-(CH 2) 3-S-H (Biphenyl-3) self-assembled monolayers on a silver and a gold substrate. For the latter substrate, we observed different interference patterns between the resonant signal of the CH vibration and the non-resonant contribution of the substrate as a function of the visible beam wavelength. The non-linear response of the gold substrate is enhanced around 480 nm corresponding to the s-d interband transition. Such effect is not observed for the silver substrate the interband transition of which is located out of the investigated visible spectral range of 450-700 nm.

Affordable, Accessible, Immediate: Capture Stunning Images with Digital Infrared Photography

Science.gov (United States)

Snyder, Mark

2011-01-01

Technology educators who teach digital photography should consider incorporating an infrared (IR) photography component into their program. This is an area where digital photography offers significant benefits. Either type of IR imaging is very interesting to explore, but traditional film-based IR photography is difficult and expensive. In…

INFRARED SPECTRA AND PHOTOMETRY OF COMPLETE SAMPLES OF PALOMAR-GREEN AND TWO MICRON ALL SKY SURVEY QUASARS

Energy Technology Data Exchange (ETDEWEB)

Shi, Yong [School of Astronomy and Space Science, Nanjing University, Nanjing 210093 (China); Rieke, G. H.; Su, K. Y. L. [Department of Astronomy And Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Ogle, P. M. [Infrared Processing and Analysis Center, California Institute of Technology, 1200 East California Boulevard, Pasadena, CA 91125 (United States); Balog, Z., E-mail: yshipku@gmail.com [Max-Planck-Institut für Astronomie, Königstuhl 17, D-69117 Heidelberg (Germany)

2014-10-01

As a step toward a comprehensive overview of the infrared (IR) diagnostics of the central engines and host galaxies of quasars at low redshift, we present Spitzer Space Telescope spectroscopic (5-40 μm) and photometric (24, 70, and 160 μm) measurements of all Palomar-Green (PG) quasars at z < 0.5 and Two Micron All Sky Survey (2MASS) quasars at z < 0.3. We supplement these data with Herschel measurements at 160 μm. The sample is composed of 87 optically selected PG quasars and 52 near-IR-selected 2MASS quasars. Here we present the data, measure the prominent spectral features, and separate emission due to star formation from that emitted by the dusty circumnuclear torus. We find that the mid-IR (5-30 μm) spectral shape for the torus is largely independent of quasar IR luminosity with scatter in the spectral energy distribution (SED) shape of ≲0.2 dex. Except for the silicate features, no large difference is observed between PG (unobscured—silicate emission) and 2MASS (obscured—silicate absorption) quasars. Only mild silicate features are observed in both cases. When in emission, the peak wavelength of the silicate feature tends to be longer than 9.7 μm, possibly indicating effects on grain properties near the active galactic nucleus. The IR color is shown to correlate with the equivalent width of the aromatic features, indicating that the slope of the quasar mid- to far-IR SED is to first order driven by the fraction of radiation from star formation in the IR bands.

Micro- and nano-scale optical devices for high density photonic integrated circuits at near-infrared wavelengths

Science.gov (United States)

Chatterjee, Rohit

In this research work, we explore fundamental silicon-based active and passive photonic devices that can be integrated together to form functional photonic integrated circuits. The devices which include power splitters, switches and lenses are studied starting from their physics, their design and fabrication techniques and finally from an experimental standpoint. The experimental results reveal high performance devices that are compatible with standard CMOS fabrication processes and can be easily integrated with other devices for near infrared telecom applications. In Chapter 2, a novel method for optical switching using nanomechanical proximity perturbation technique is described and demonstrated. The method which is experimentally demonstrated employs relatively low powers, small chip footprint and is compatible with standard CMOS fabrication processes. Further, in Chapter 3, this method is applied to develop a hitless bypass switch aimed at solving an important issue in current wavelength division multiplexing systems namely hitless switching of reconfigurable optical add drop multiplexers. Experimental results are presented to demonstrate the application of the nanomechanical proximity perturbation technique to practical situations. In Chapter 4, a fundamental photonic component namely the power splitter is described. Power splitters are important components for any photonic integrated circuits because they help split the power from a single light source to multiple devices on the same chip so that different operations can be performed simultaneously. The power splitters demonstrated in this chapter are based on multimode interference principles resulting in highly compact low loss and highly uniform power splitting to split the power of the light from a single channel to two and four channels. These devices can further be scaled to achieve higher order splitting such as 1x16 and 1x32 power splits. Finally in Chapter 5 we overcome challenges in device

Characterization and identification of microorganisms by FT-IR microspectrometry

Science.gov (United States)

Ngo-Thi, N. A.; Kirschner, C.; Naumann, D.

2003-12-01

We report on a novel FT-IR approach for microbial characterization/identification based on a light microscope coupled to an infrared spectrometer which offers the possibility to acquire IR-spectra of microcolonies containing only few hundred cells. Microcolony samples suitable for FT-IR microspectroscopic measurements were obtained by a replica technique with a stamping device that transfers spatially accurate cells of microcolonies growing on solid culture plates to a special, IR-transparent or reflecting stamping plate. High quality spectra could be recorded either by applying the transmission/absorbance or the reflectance/absorbance mode of the infrared microscope. Signal to noise ratios higher than 1000 were obtained for microcolonies as small as 40 μm in diameter. Reproducibility levels were established that allowed species and strain identification. The differentiation and classification capacity of the FT-IR microscopic technique was tested for different selected microorganisms. Cluster and factor analysis methods were used to evaluate the complex spectral data. Excellent discrimination between bacteria and yeasts, and at the same time Gram-negative and Gram-positive bacterial strains was obtained. Twenty-two selected strains of different species within the genus Staphylococcus were repetitively measured and could be grouped into correct species cluster. Moreover, the results indicated that the method allows also identifications at the subspecies level. Additionally, the new approach allowed spectral mapping analysis of single colonies which provided spatially resolved characterization of growth heterogeneity within complex microbial populations such as colonies.

Obstacle-avoiding robot with IR and PIR motion sensors

Science.gov (United States)

Ismail, R.; Omar, Z.; Suaibun, S.

2016-10-01

Obstacle avoiding robot was designed, constructed and programmed which may be potentially used for educational and research purposes. The developed robot will move in a particular direction once the infrared (IR) and the PIR passive infrared (PIR) sensors sense a signal while avoiding the obstacles in its path. The robot can also perform desired tasks in unstructured environments without continuous human guidance. The hardware was integrated in one application board as embedded system design. The software was developed using C++ and compiled by Arduino IDE 1.6.5. The main objective of this project is to provide simple guidelines to the polytechnic students and beginners who are interested in this type of research. It is hoped that this robot could benefit students who wish to carry out research on IR and PIR sensors.

Multi-Wavelength Photomagnetic Imaging for Oral Cancer

Science.gov (United States)

Marks, Michael

In this study, a multi-wavelength Photomagnetic Imaging (PMI) system is developed and evaluated with experimental studies.. PMI measures temperature increases in samples illuminated by near-infrared light sources using magnetic resonance thermometry. A multiphysics solver combining light and heat transfer models the spatiotemporal distribution of the temperature change. The PMI system develop in this work uses three lasers of varying wavelength (785 nm, 808 nm, 860 nm) to heat the sample. By using multiple wavelengths, we enable the PMI system to quantify the relative concentrations of optical contrast in turbid media and monitor their distribution, at a higher resolution than conventional diffuse optical imaging. The data collected from agarose phantoms with multiple embedded contrast agents designed to simulate the optical properties of oxy- and deoxy-hemoglobin is presented. The reconstructed images demonstrate that multi-wavelength PMI can resolve this complex inclusion structure with high resolution and recover the concentration of each contrast agent with high quantitative accuracy. The modified multi-wavelength PMI system operates under the maximum skin exposure limits defined by the American National Standards Institute, to enable future clinical applications.

SAFARI : A Far Infrared Imaging FTS-Spectrometer for SPICA

NARCIS (Netherlands)

Goicoechea, J. R.; Roelfsema, P. R.; Jellema, W.; Swinyard, B. M.

The far-IR spectral window plays host to a critical range of both spectroscopic and photometric diagnostics with which to study our Galaxy and beyond, at wavelengths completely blocked by the Earth’s atmosphere. The proposed Japanese-led IR space telescope SPICA, with its cryogenically cooled ~3.2m

Acquisition of Infrared Variable Angle Spectroscopic Ellipsometer (IR-VASE)

Science.gov (United States)