WorldWideScience

Sample records for incident kinetic energies

  1. Total kinetic energy release in 239Pu(n ,f ) post-neutron emission from 0.5 to 50 MeV incident neutron energy

    Science.gov (United States)

    Meierbachtol, K.; Tovesson, F.; Duke, D. L.; Geppert-Kleinrath, V.; Manning, B.; Meharchand, R.; Mosby, S.; Shields, D.

    2016-09-01

    The average total kinetic energy (T K E ¯) in 239Pu(n ,f ) has been measured for incident neutron energies between 0.5 and 50 MeV. The experiment was performed at the Los Alamos Neutron Science Center (LANSCE) using the neutron time-of-flight technique, and the kinetic energy of fission fragments post-neutron emission was measured in a double Frisch-gridded ionization chamber. This represents the first experimental study of the energy dependence of T K E ¯ in 239Pu above neutron energies of 6 MeV.

  2. SCATPI, a subroutine for calculating πN cross sections and polarizations for incident pion kinetic energies between 90 and 300 MeV

    International Nuclear Information System (INIS)

    Walter, J.B.; Rebka, G.A. Jr.

    1979-03-01

    A subroutine, SCATPI, was written which calculates π + p elastic differential cross sections for incident pion kinetic energies between 90 and 310 MeV for π - p. The calculation is based upon the phase shift analysis of Carter, Bugg, and Carter, and is reliable to about 2% for π + p and 3% for π - p differential cross sections. SCATPI also calculates other scattering parameters for the π+-p systems. The calculations are compared with the measurements used in the phase shift analysis, and with selected recent measurements. The use of SCATPI is described. 14 figures, 4 tables

  3. Kinetic energy budget details

    Indian Academy of Sciences (India)

    Abstract. This paper presents the detailed turbulent kinetic energy budget and higher order statistics of flow behind a surface-mounted rib with and without superimposed acoustic excitation. Pattern recognition technique is used to determine the large-scale structure magnitude. It is observed that most of the turbulence ...

  4. Kinetic energy absorbing pad

    International Nuclear Information System (INIS)

    Bricmont, R.J.; Hamilton, P.A.; Ming Long Ting, R.

    1981-01-01

    Reactors, fuel processing plants etc incorporate pipes and conduits for fluids under high pressure. Fractures, particularly adjacent to conduit elbows, produce a jet of liquid which whips the broken conduit at an extremely high velocity. An enormous impact load would be applied to any stationary object in the conduit's path. The design of cellular, corrugated metal impact pads to absorb the kinetic energy of the high velocity conduits is given. (U.K.)

  5. Dimensional enhancement of kinetic energies

    DEFF Research Database (Denmark)

    Schleich, W.P.; Dahl, Jens Peder

    2002-01-01

    Simple thermodynamics considers kinetic energy to be an extensive variable which is proportional to the number N of particles. We present a quantum state of N noninteracting particles for which the kinetic energy increases quadratically with N. This enhancement effect is tied to the quantum...

  6. SCATPI, a subroutine for calculating. pi. N cross sections and polarizations for incident pion kinetic energies between 90 and 300 MeV. [In FORTRAN for CDC 6600 and 7600 and Xerox Sigma 7

    Energy Technology Data Exchange (ETDEWEB)

    Walter, J.B.; Rebka, G.A. Jr.

    1979-03-01

    A subroutine, SCATPI, was written which calculates ..pi../sup +/p elastic differential cross sections for incident pion kinetic energies between 90 and 310 MeV for ..pi../sup -/p. The calculation is based upon the phase shift analysis of Carter, Bugg, and Carter, and is reliable to about 2% for ..pi../sup +/p and 3% for ..pi../sup -/p differential cross sections. SCATPI also calculates other scattering parameters for the ..pi..+-p systems. The calculations are compared with the measurements used in the phase shift analysis, and with selected recent measurements. The use of SCATPI is described. 14 figures, 4 tables.

  7. Data on incident solar energy

    Science.gov (United States)

    Thekaekara, M. P.

    1974-01-01

    Instrumentation for solar irradiance monitoring, and radiation scales are discussed in a survey of incident solar energy data. The absolute accuracy and intrinsic reliability of the values of the solar constant and zero air mass solar spectrum proposed by the Institute of Environmental Sciences as an ASTM standard are evaluated. Extraterrestrial observations are used for deriving solar irradiance data at ground level for widely varying atmospheric parameters, with special reference to air pollution. The effects of diffuse sky radiance and those of varying slopes of the solar energy collecting surface are examined. Average values of solar energy available at different locations in the United States are included.

  8. Kinetic energy driven pairing in cuprate superconductors

    NARCIS (Netherlands)

    Maier, TA; Jarrell, M; Macridin, A; Slezak, C

    2004-01-01

    Pairing occurs in conventional superconductors through a reduction of the electronic potential energy accompanied by an increase in kinetic energy. In the underdoped cuprates, optical experiments show that pairing is driven by a reduction of the electronic kinetic energy. Using the dynamical cluster

  9. Fragment-mass, kinetic energy, and angular distributions for 234U(n ,f ) at incident neutron energies from En=0.2 MeV to 5.0 MeV

    Science.gov (United States)

    Al-Adili, A.; Hambsch, F.-J.; Pomp, S.; Oberstedt, S.; Vidali, M.

    2016-03-01

    This work investigates the neutron-induced fission of 234U and the fission-fragment properties for neutron energies between En=0.2 and 5.0 MeV with a special highlight on the prominent vibrational resonance at En=0.77 MeV. Angular, energy, and mass distributions were determined based on the double-energy technique by means of a twin Frisch-grid ionization chamber. The experimental data are parametrized in terms of fission modes based on the multimodal random neck-rupture model. The main results are a verified strong angular anisotropy and fluctuations in the energy release as a function of incident-neutron energy.

  10. Understanding Kinetic Energy paradox in Quantum Mechanics

    OpenAIRE

    Kornyushin, Yuri

    2008-01-01

    A concept of Kinetic Energy in Quantum Mechanics is analyzed. Kinetic Energy is not zero in many cases where there are no motion and flux. This paradox can be understood, using expansion of the wave function in Fourier integral, that is on the basis of virtual plane waves.

  11. Concepts of radial and angular kinetic energies

    DEFF Research Database (Denmark)

    Dahl, Jens Peder; Schleich, W.P.

    2002-01-01

    We consider a general central-field system in D dimensions and show that the division of the kinetic energy into radial and angular parts proceeds differently in the wave-function picture and the Weyl-Wigner phase-space picture, Thus, the radial and angular kinetic energies are different quantities...

  12. Light particle production in spallation reactions induced by protons of 0.8-2.5 GeV incident kinetic energy

    International Nuclear Information System (INIS)

    Herbach, Claus-Michael; Enke, Michael; Boehm, Andreas

    2002-01-01

    Absolute production cross sections have been measured simultaneously for neutrons and light charged particles in 0.8-2.5 GeV proton induced spallation reactions for a series of target nuclei from aluminum up to uranium. The high detection efficiency both for neutral and charged evaporative particles provides an event-wise access to the amount of projectile energy dissipated into nuclear excitation. Various intra nuclear cascade plus evaporation models have been confronted with the experimental data showing large discrepancies for hydrogen and helium production. (author)

  13. Nanostructured energy devices equilibrium concepts and kinetics

    CERN Document Server

    Bisquert, Juan

    2014-01-01

    Due to the pressing needs of society, low cost materials for energy devices have experienced an outstanding development in recent times. In this highly multidisciplinary area, chemistry, material science, physics, and electrochemistry meet to develop new materials and devices that perform required energy conversion and storage processes with high efficiency, adequate capabilities for required applications, and low production cost. Nanostructured Energy Devices: Equilibrium Concepts and Kinetics introduces the main physicochemical principles that govern the operation of energy devices. It inclu

  14. Lower bound for the nuclear kinetic energy

    Energy Technology Data Exchange (ETDEWEB)

    Dehesa, J.S. (Granada Univ. (Spain). Dept. de Fisica Nuclear); Galvez, F.J. (Granada Univ. (Spain). Dept. de Fisica Teorica)

    1985-06-27

    We argue that the kinetic energy of a many-fermion system is bounded from below by Kqsup(-2/3)A sup(5/3) / , with K = 0.565 where q is the number of spin states available to each particle and sup(1/2) is the root mean square radius of the single-particle density. A simple lower bound for the nuclear kinetic energy is found. Numerical values of the bound for several nuclei are shown, and a comparison with some self-consistent calculations and some pseudo-empirical values is made.

  15. Nonlocal kinetic-energy-density functionals

    International Nuclear Information System (INIS)

    Garcia-Gonzalez, P.; Alvarellos, J.E.; Chacon, E.

    1996-01-01

    In this paper we present nonlocal kinetic-energy functionals T[n] within the average density approximation (ADA) framework, which do not require any extra input when applied to any electron system and recover the exact kinetic energy and the linear response function of a homogeneous system. In contrast with previous ADA functionals, these present good behavior of the long-range tail of the exact weight function. The averaging procedure for the kinetic functional (averaging the Fermi momentum of the electron gas, instead of averaging the electron density) leads to a functional without numerical difficulties in the calculation of extended systems, and it gives excellent results when applied to atoms and jellium surfaces. copyright 1996 The American Physical Society

  16. Electric Vehicles Mileage Extender Kinetic Energy Storage

    Science.gov (United States)

    Jivkov, Venelin; Draganov, Vutko; Stoyanova, Yana

    2015-03-01

    The proposed paper considers small urban vehicles with electric hybrid propulsion systems. Energy demands are examined on the basis of European drive cycle (NEUDC) and on an energy recuperation coefficient and are formulated for description of cycle energy transfers. Numerical simulation results show real possibilities for increasing in achievable vehicle mileage at the same energy levels of a main energy source - the electric battery. Kinetic energy storage (KES), as proposed to be used as an energy buffer and different structural schemes of the hybrid propulsion system are commented. Minimum energy levels for primary (the electric battery) and secondary (KES) sources are evaluated. A strategy for reduced power flows control is examined, and its impact on achievable vehicle mileage is investigated. Results show an additional increase in simulated mileage at the same initial energy levels.

  17. Aircraft Measurements of Atmospheric Kinetic Energy Spectra

    DEFF Research Database (Denmark)

    Lundtang Petersen, Erik; Lilly, D. K.

    1983-01-01

    Wind velocity data obtained from a jet airliner are used to construct kinetic energy spectra over the range of wavelengths from 2.5 to 2500 km. The spectra exhibit an approximate -5/3 slope for wavelengths of less than about 150 km, steepening to about -2.2 at larger scales. These results support...

  18. Energy transfer and kinetics in mechanochemistry.

    Science.gov (United States)

    Chen, Zhiliang; Lu, Shengyong; Mao, Qiongjing; Buekens, Alfons; Wang, Yuting; Yan, Jianhua

    2017-11-01

    Mechanochemistry (MC) exerts extraordinary degradation and decomposition effects on many chlorinated, brominated, and even fluorinated persistent organic pollutants (POPs). However, its application is still limited by inadequate study of its reaction kinetic aspects. In the present work, the ball motion and energy transfer in planetary ball mill are investigated in some detail. Almost all milling parameters are summarised in a single factor-total effective impact energy. Furthermore, the MC kinetic between calcium oxide/Al and hexachlorobenzene is well established and modelled. The results indicate that total effective impact energy and reagent ratio are the two factors sufficient for describing the MC degradation degree of POPs. The reaction rate constant only depends on the chemical properties of reactants, so it could be used as an important index to appraise the quality of MC additives. This model successfully predicts the reaction rate for different operating conditions, indicating that it could be suitably applied for conducting MC reactions in other reactors.

  19. Evaluation of kinetic energy in flowing rivers

    Energy Technology Data Exchange (ETDEWEB)

    Faure, T. [National Research Council of Canada, Ottawa, ON (Canada). Canadian Hydraulics Centre

    2008-07-01

    New methods of evaluating the kinetic energy in rivers were discussed. Developed by the National Research Council's Canadian Hydraulics Centre, the numerical models were designed to generate hydrographs of river flow from dams; accommodate power density anomalies caused by the presence of islands in a river; and assess mean kinetic power rates. This presentation provided details of a simulation of 6 turbines located in close proximity to each other. The model was used to calculate velocity fields downstream of the turbines as well as changes in water surface elevation due to power production by the 6 75 kW turbines. Turbine power extraction and kinetic power in the upstream cross-section was assessed. The model showed that the turbines extracted 9 per cent of the river's 17,000 kW of estimated energy potential. The turbines were modelled by considering the porosity of the numerical elements at the location of the turbine and extracting known quantities of energy from the flow. The model was also used to calculate new hydrodynamics of the whole region with the turbines in place by assuming that energy was extracted over the entire depth of the location. The presentation included detailed charts of rivers modelled during the study. tabs., figs.

  20. Fragment mass-, kinetic energy- and angular distributions for 234U(n, f) at incident neutron energies from En = 0.2 to 5.0 MeV

    OpenAIRE

    Al-Adili, Ali; Hambsch, Franz-Josef; Stephan, Pomp; Stephan, Oberstedt; Vidali, M.

    2016-01-01

    This work investigates the neutron-induced fission of 234U and the fission-fragment properties for neutron energies between n = 0.2 MeV and 5.0 MeV with a special highlight on the prominent vibrational resonance at n = 0.77 MeV. Angular-, energy- and mass distributions were determined based on the double-energy (2E) technique by means of a Twin Frisch-Grid Ionization Chamber. The experimental data are parametrized in terms of fission modes based on the Multi-Modal Random Neck-Rupture model...

  1. Tandem mass spectrometry at low kinetic energy

    International Nuclear Information System (INIS)

    Cooks, R.G.; Hand, O.W.

    1987-01-01

    Recent progress in mass spectrometry, as applied to molecular analysis, is reviewed with emphasis on tandem mass spectrometry. Tandem instruments use multiple analyzers (sector magnets, quadrupole mass filters and time-of-flight devices) to select particular molecules in ionic form, react them in the gas-phase and then record the mass, momenta or kinetic energies of their products. The capabilities of tandem mass spectrometry for identification of individual molecules or particular classes of compounds in complex mixtures are illustrated. Several different types of experiments can be run using a tandem mass spectrometer; all share the feature of sifting the molecular mixture being analyzed on the basis of chemical properties expressed in terms of ionic mass, kinetic energy or charge state. Applications of mass spectrometry to biological problems often depend upon desorption methods of ionization in which samples are bombarded with particle beams. Evaporation of preformed charged species from the condensed phase into the vacuum is a particularly effective method of ionization. It is suggested that the use of accelerator mass spectrometers be extended to include problems of molecular analysis. In such experiments, low energy tandem mass spectrometry conducted in the eV or keV range of energies, would be followed by further characterization of the production ion beam using high selective MeV collision processes

  2. Redistribution of Kinetic Energy in Turbulent Flows

    Directory of Open Access Journals (Sweden)

    Alain Pumir

    2014-10-01

    Full Text Available In statistically homogeneous turbulent flows, pressure forces provide the main mechanism to redistribute kinetic energy among fluid elements, without net contribution to the overall energy budget. This holds true in both two-dimensional (2D and three-dimensional (3D flows, which show fundamentally different physics. As we demonstrate here, pressure forces act on fluid elements very differently in these two cases. We find in numerical simulations that in 3D pressure forces strongly accelerate the fastest fluid elements, and that in 2D this effect is absent. In 3D turbulence, our findings put forward a mechanism for a possibly singular buildup of energy, and thus may shed new light on the smoothness problem of the solution of the Navier-Stokes equation in 3D.

  3. On Kinetics Modeling of Vibrational Energy Transfer

    Science.gov (United States)

    Gilmore, John O.; Sharma, Surendra P.; Cavolowsky, John A. (Technical Monitor)

    1996-01-01

    Two models of vibrational energy exchange are compared at equilibrium to the elementary vibrational exchange reaction for a binary mixture. The first model, non-linear in the species vibrational energies, was derived by Schwartz, Slawsky, and Herzfeld (SSH) by considering the detailed kinetics of vibrational energy levels. This model recovers the result demanded at equilibrium by the elementary reaction. The second model is more recent, and is gaining use in certain areas of computational fluid dynamics. This model, linear in the species vibrational energies, is shown not to recover the required equilibrium result. Further, this more recent model is inconsistent with its suggested rate constants in that those rate constants were inferred from measurements by using the SSH model to reduce the data. The non-linear versus linear nature of these two models can lead to significant differences in vibrational energy coupling. Use of the contemporary model may lead to significant misconceptions, especially when integrated in computer codes considering multiple energy coupling mechanisms.

  4. Incident energy dependence of pt correlations at relativistic energies

    CERN Document Server

    Adams, J; Ahammed, Z; Amonett, J; Anderson, B D; Arkhipkin, D; Averichev, G S; Badyal, S K; Bai, Y; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellingeri-Laurikainen, A; Bellwied, R; Berger, J; Bezverkhny, B I; Bharadwaj, S; Bhasin, A; Bhati, A K; Bhatia, V S; Bichsel, H; Bielcik, J; Bielcikova, J; Billmeier, A; Bland, L C; Blyth, C O; Bonner, B E; Botje, M; Boucham, A; Bouchet, J; Brandin, A V; Bravar, A; Bystersky, M; Cadman, R V; Cai, X Z; Caines, H; Calderón de la Barca-Sanchez, M; Castillo, J; Catu, O; Cebra, D; Chajecki, Z; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, Y; Cheng, J; Cherney, M; Chikanian, A; Christie, W; Coffin, J P; Cormier, T M; Cramer, J G; Crawford, H J; Das, D; Das, S; Daugherity, M; De Moura, M M; Dedovich, T G; Derevshchikov, A A; Didenko, L; Dietel, T; Dogra, S M; Dong, W J; Dong, X; Draper, J E; Du, F; Dubey, A K; Dunin, V B; Dunlop, J C; Dutta, M R; Mazumdar; Eckardt, V; Edwards, W R; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Estienne, M; Fachini, P; Faivre, J; Fatemi, R; Fedorisin, J; Filimonov, K; Filip, P; Finch, E; Fine, V; Fisyak, Yu; Fu, J; Gagliardi, C A; Gaillard, L; Gans, J; Ganti, M S; Geurts, F; Ghazikhanian, V; Ghosh, P; González, J E; Gos, H; Grachov, O; Grebenyuk, O; Grosnick, D P; Guertin, S M; Guo, Y; Sen-Gupta, A; Gutíerrez, T D; Hallman, T J; Hamed, A; Hardtke, D; Harris, J W; Heinz, M; Henry, T W; Hepplemann, S; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Huang, H Z; Huang, S L; Hughes, E W; Humanic, T J; Igo, G; Ishihara, A; Jacobs, P; Jacobs, W W; Jedynak, M; Jiang, H; Jones, P G; Judd, E G; Kabana, S; Kang, K; Kaplan, M; Keane, D; Kechechyan, A; Khodyrev, V Yu; Kiryluk, J; Kisiel, A; Kislov, E M; Klay, J; Klein, S R; Koetke, D D; Kollegger, T; Kopytine, M; Kotchenda, L; Kowalik, K L; Krämer, M; Kravtsov, P; Kravtsov, V I; Krüger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kutuev, R K; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; Laue, F; Lauret, J; Lebedev, A; Lednicky, R; Lehocka, S; Le Vine, M J; Li, C; Li, Q; Li, Y; Lin, G; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, H; Liu, L; Liu, Q J; Liu, Z; Ljubicic, T; Llope, W J; Long, H; Longacre, R S; López-Noriega, M; Love, W A; Lu, Y; Ludlam, T; Lynn, D; Ma, G L; Ma, J G; Ma, Y G; Magestro, D; Mahajan, S; Mahapatra, D P; Majka, R; Mangotra, L K; Manweiler, R; Margetis, S; Markert, C; Martin, L; Marx, J N; Matis, H S; Matulenko, Yu A; McClain, C J; McShane, T S; Meissner, F; Melnik, Yu M; Meschanin, A; Miller, M L; Minaev, N G; Mironov, C; Mischke, A; Mishra, D K; Mitchell, J; Mohanty, B; Molnár, L; Moore, C F; Morozov, D A; Munhoz, M G; Nandi, B K; Nayak, S K; Nayak, T K; Nelson, J M; Netrakanti, P K; Nikitin, V A; Nogach, L V; Nurushev, S B; Odyniec, Grazyna Janina; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Pal, S K; Panebratsev, Yu A; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Peitzmann, T; Perevozchikov, V; Perkins, C; Peryt, W; Petrov, V A; Phatak, S C; Picha, R; Planinic, M; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potekhin, M V; Potrebenikova, E V; Potukuchi, B V K S; Prindle, D; Pruneau, C A; Putschke, J; Rakness, G; Raniwala, R; Raniwala, S; Ravel, O; Ray, R L; Razin, S V; Reichhold, D M; Reid, J G; Reinnarth, J; Renault, G; Retière, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Rose, A; Roy, C; Ruan, L; Russcher, M; Sahoo, R; Sakrejda, I; Salur, S; Sandweiss, J; Sarsour, M; Savin, I; Sazhin, P S; Schambach, J; Scharenberg, R P; Schmitz, N; Schweda, K; Seger, J; Seyboth, P; Shahaliev, E; Shao, M; Shao, W; Sharma, M; Shen, W Q; Shestermanov, K E; Shimansky, S S; Sichtermann, E P; Simon, F; Singaraju, R N; Smirnov, N; Snellings, R; Sood, G; Sørensen, P; Sowinski, J; Speltz, J; Spinka, H M; Srivastava, B; Stadnik, A; Stanislaus, T D S; Stock, R; Stolpovsky, A; Strikhanov, M N; Stringfellow, B C; Suaide, A A P; Sugarbaker, E R; Suire, C; Sumbera, M; Surrow, B; Swanger, M; Symons, T J M; Szanto de Toledo, A; Tai, A; Takahashi, J; Tang, A H; Tarnowsky, T J; Thein, D; Thomas, J H; Timoshenko, S; Tokarev, M; Trentalange, S; Tribble, R E; Tsai, O D; Ulery, J; Ullrich, T; Underwood, D G; Van Buren, G; Van Leeuwen, M; Van der Molen, A M; Varma, R; Vasilevski, I M; Vasilev, A N; Vernet, R; Vigdor, S E; Viyogi, Y P; Vokal, S; Voloshin, S A; Waggoner, W T; Wang, F; Wang, G; Wang, X L; Wang, Y; Wang, Z M; Ward, H; Watson, J W; Webb, J C; Westfall, G D; Wetzler, A; Whitten, C; Wieman, H; Wissink, S W; Witt, R; Wood, J; Wu, J; Xu, N; Xu, Z; Xu, Z Z; Yamamoto, E; Yepes, P; Yurevich, V I; Zborovský, I; Zhang, H; Zhang, W M; Zhang, Y; Zhang, Z P; Zoulkarneev, R; Zoulkarneeva, Y; Zubarev, A N

    2005-01-01

    We present results for two-particle transverse momentum correlations, , as a function of event centrality for Au+Au collisions at sqrt(sNN) = 20, 62, 130, and 200 GeV at the Relativistic Heavy Ion Collider. We observe correlations decreasing with centrality that are similar at all four incident energies. The correlations multiplied by the multiplicity density increase with incident energy and the centrality dependence may show evidence of processes such as thermalization, minijet production, or the saturation of transverse flow. The square root of the correlations divided by the event-wise average transverse momentum per event shows little or no beam energy dependence and generally agrees with previous measurements at the Super Proton Synchrotron.

  5. Kinetic energy factors in evaluation of athletes.

    Science.gov (United States)

    Jones, Jason N; Priest, Joe W; Marble, Daniel K

    2008-11-01

    It is established that speed and agility are critical attributes of sports performance. Performance timing of runs during agility course testing can be used to estimate acceleration, speed, or quickness. The authors of this research effort also report the energy of motion, or kinetic energy of the athlete, which considers not only the speed but also the mass of the athlete. An electronic timer was used to determine total run times as well as split performance times during a new 60-yd "run-shuttle" test. This newly designed agility test takes advantage of the technological capabilities of a laser timing device. Separate times for each of four run segments were recorded and converted to average speeds (m x s(-1)) as well as a quantitative factor of merit defined as the "K-factor." The purpose of this study was to describe the effects of training and to compare athletes and teams using measures of time, speed, and kinetic energy. Results of the analysis of total time on the 60-yd run-shuttle provided evidence of the effectiveness of the training programs. Split times of segments within the 60-yd run-shuttle provided information not available from conventional agility tests. Average speeds and K-factors identified discriminating characteristics of otherwise similar athletes. Our findings support the conclusion that training programs and athletic performance may be evaluated using the 60-yd run-shuttle with laser timer system. Coaches and trainers may find practical application of this technology for American football, soccer, basketball, baseball/softball, track and field, and field hockey.

  6. Study of the phase transition of zirconia submitted to low kinetic energy ionic irradiations

    International Nuclear Information System (INIS)

    Simeone, D.; Gosset, D.; Chevarier, A.; Baldinozzi, G.G.

    2002-01-01

    This study analyzes in detail the monoclinic → quadratic phase transition of zirconia under neutronic irradiation simulated with low kinetic energy ion implantations. Very pure monoclinic pellets of zirconia were irradiated with low kinetic energy ions for the generation of accumulations of defects. In order to take into account the low implantation depth of the incident ions, glazing incidence X-ray diffraction analysis was used and permitted to separate the effects produced by the ballistic collisions and the implantation peak of the incident ions on the irradiated material. The analysis of X-ray diffraction and Raman spectroscopy spectra allows to characterize the phase built under irradiation. It is shown that the quadratic phase produced under implantation is clearly linked with the damage profile. The neutron diffraction study of the monoclinic - quadratic transition of zirconia with respect to temperature has permitted to outline a model describing the behaviour of non-doped zirconia under irradiation. (J.S.)

  7. Variation of kinetic energy release with temperature and electron energy for unimolecular ionic transitions

    International Nuclear Information System (INIS)

    Rabia, M.A.; Fahmy, M.A.

    1992-01-01

    The kinetic energy released during seven unimolecular ionic transitions, generated from benzyl alcohol and benzyl amine have been studied as a function of ion source temperature and ionizing electron energy. Only, the kinetic energy released during H CN elimination from fragment [C 7 H 8 N]+ ion of benzyl amine displays a temperature dependence. For only two transitions, generated from benzyl alcohol, the kinetic energy released show a significant ionizing electron energy dependence. These results may reveal the role of the internal energy of reacting ions in producing the kinetic energy released some transitions produced from benzyl alcohol

  8. Spectral kinetic energy transfer in turbulent premixed reacting flows.

    Science.gov (United States)

    Towery, C A Z; Poludnenko, A Y; Urzay, J; O'Brien, J; Ihme, M; Hamlington, P E

    2016-05-01

    Spectral kinetic energy transfer by advective processes in turbulent premixed reacting flows is examined using data from a direct numerical simulation of a statistically planar turbulent premixed flame. Two-dimensional turbulence kinetic-energy spectra conditioned on the planar-averaged reactant mass fraction are computed through the flame brush and variations in the spectra are connected to terms in the spectral kinetic energy transport equation. Conditional kinetic energy spectra show that turbulent small-scale motions are suppressed in the burnt combustion products, while the energy content of the mean flow increases. An analysis of spectral kinetic energy transfer further indicates that, contrary to the net down-scale transfer of energy found in the unburnt reactants, advective processes transfer energy from small to large scales in the flame brush close to the products. Triadic interactions calculated through the flame brush show that this net up-scale transfer of energy occurs primarily at spatial scales near the laminar flame thermal width. The present results thus indicate that advective processes in premixed reacting flows contribute to energy backscatter near the scale of the flame.

  9. Fisher information, kinetic energy and uncertainty relation inequalities

    International Nuclear Information System (INIS)

    Luo Shunlong

    2002-01-01

    By interpolating between Fisher information and mechanical kinetic energy, we introduce a general notion of kinetic energy with respect to a parameter of Schroedinger wavefunctions from a statistical inference perspective. Kinetic energy is the sum of Fisher information and an integral of a parametrized analogue of quantum mechanical current density related to phase. A family of integral inequalities concerning kinetic energy and moments are established, among which the Cramer-Rao inequality and the Weyl-Heisenberg inequality, are special cases. In particular, the integral inequalities involving the negative order moments are relevant to the study of electron systems. Moreover, by specifying the parameter to a scale, we obtain a family of inequalities of uncertainty relation type which incorporate the position and momentum observables symmetrically in a single quantity. (author)

  10. Direct kinetic energy extraction from neutron Compton profiles

    Energy Technology Data Exchange (ETDEWEB)

    Senesi, R., E-mail: roberto.senesi@roma2.infn.it [Universita degli Studi di Roma ' Tor Vergata' , Dipartimento di Fisica, Via della Ricerca Scientifica 1, 00133 Roma (Italy); Centro NAST, Nanoscienze and Nanotecnologie and Strumentazione, Universita degli Studi di Roma ' Tor Vergata' , Via della Ricerca Scientifica 1, 00133 Roma (Italy)

    2012-01-01

    Deep inelastic neutron scattering experiments provide access to atomic momentum distributions and mean kinetic energies. These quantities are intimately connected to nuclear quantum effects associated to the equilibrium ground state of condensed systems. The method to derive the single particle mean kinetic energy, directly employing the sum rules associated to the scattering functions, from a set of deep inelastic neutron scattering spectra is discussed. This method does not make use of nonlinear fitting of the scattering spectra.

  11. Kinetic Storage as an Energy Management System

    International Nuclear Information System (INIS)

    Garcia-Tabares, L.

    2007-01-01

    The possibility of storing energy is increasingly important and necessary. The reason is that storage modifies the basic equation of the energy production balance which states that the power produced should equal the power consumed. When there is a storage device in the grid, this equation is modified such that, in the new balance, the energy produced should equal the algebraic sum of the energy consumed and the energy stored (positive in storage phase and negative when released). This means that the generation profile can be uncoupled from the consumption profile, with the resulting improvement of efficiency. Even small-sized storage systems can be very effective. (Author) 10 refs

  12. Renormalizing the kinetic energy operator in elementary quantum mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Coutinho, F A B [Faculdade de Medicina, Universidade de Sao Paulo e LIM 01-HCFMUSP, 05405-000 Sao Paulo (Brazil); Amaku, M [Faculdade de Medicina Veterinaria e Zootecnia, Universidade de Sao Paulo, 05508-970 Sao Paulo (Brazil)], E-mail: coutinho@dim.fm.usp.br

    2009-09-15

    In this paper, we consider solutions to the three-dimensional Schroedinger equation of the form {psi}(r) = u(r)/r, where u(0) {ne} 0. The expectation value of the kinetic energy operator for such wavefunctions diverges. We show that it is possible to introduce a potential energy with an expectation value that also diverges, exactly cancelling the kinetic energy divergence. This renormalization procedure produces a self-adjoint Hamiltonian. We solve some problems with this new Hamiltonian to illustrate its usefulness.

  13. Renormalizing the kinetic energy operator in elementary quantum mechanics

    International Nuclear Information System (INIS)

    Coutinho, F A B; Amaku, M

    2009-01-01

    In this paper, we consider solutions to the three-dimensional Schroedinger equation of the form ψ(r) = u(r)/r, where u(0) ≠ 0. The expectation value of the kinetic energy operator for such wavefunctions diverges. We show that it is possible to introduce a potential energy with an expectation value that also diverges, exactly cancelling the kinetic energy divergence. This renormalization procedure produces a self-adjoint Hamiltonian. We solve some problems with this new Hamiltonian to illustrate its usefulness.

  14. Renormalizing the Kinetic Energy Operator in Elementary Quantum Mechanics

    Science.gov (United States)

    Coutinho, F. A. B.; Amaku, M.

    2009-01-01

    In this paper, we consider solutions to the three-dimensional Schrodinger equation of the form [psi](r) = u(r)/r, where u(0) [is not equal to] 0. The expectation value of the kinetic energy operator for such wavefunctions diverges. We show that it is possible to introduce a potential energy with an expectation value that also diverges, exactly…

  15. Determination of kinetic energy release from metastable peak widths

    DEFF Research Database (Denmark)

    Petersen, Allan Christian; Sølling, Theis Ivan

    2017-01-01

    The kinetic energy that is released upon bond rupture is often represented as T1/2. A value that is derived from the FWHM of a fragment peak by the use of two different conversion formulas. The choice of formula depends on whether the peak is recorded by scanning a magnetic sector or an electrost......The kinetic energy that is released upon bond rupture is often represented as T1/2. A value that is derived from the FWHM of a fragment peak by the use of two different conversion formulas. The choice of formula depends on whether the peak is recorded by scanning a magnetic sector...

  16. Expressions For Total Energy And Relativistic Kinetic Energy At Low Speeds In Special Relativity Must Include Rotational And Vibrational As Well As Linear Kinetic Energies

    Science.gov (United States)

    Brekke, Stewart

    2017-09-01

    Einstein calculated the total energy at low speeds in the Special Theory of Relativity to be Etotal =m0c2 + 1 / 2m0v2 . However, the total energy must include the rotational and vibrational kinetic energies as well as the linear kinetic energies. If 1 / 2 Iω2 is the expression for the rotational kinetic energy of mass and 1 / 2 kx02 is the vibrational kinetic energy expression of a typical mass, the expression for the total energy of a mass at low speeds must be Etotal =m0c2 + 1 / 2m0v2 + 1 / 2 Iω2 + 1 / 2 kx02 . If this expression is correct, the relativistic kinetic energy of a mass. at low speeds must include the rotational and vibrational kinetic energies as well as the linear kinetic energies since according to Einstein K = (m -m0) c2 and therefore, K = 1 / 2m0v2 + 1 / 2 Iω2 + 1 / 2 kx02 .

  17. Evaluating rainfall kinetic energy - intensity relationships with observed disdrometric data

    Science.gov (United States)

    Angulo-Martinez, Marta; Begueria, Santiago; Latorre, Borja

    2016-04-01

    Rainfall kinetic energy is required for determining erosivity, the ability of rainfall to detach soil particles and initiate erosion. Its determination relay on the use of disdrometers, i.e. devices capable of measuring the drop size distribution and velocity of falling raindrops. In the absence of such devices, rainfall kinetic energy is usually estimated with empirical expressions relating rainfall energy and intensity. We evaluated the performance of 14 rainfall energy equations in estimating one-minute rainfall energy and event total energy, in comparison with observed data from 821 rainfall episodes (more than 100 thousand one-minute observations) by means of an optical disdrometer. In addition, two sources of bias when using such relationships were evaluated: i) the influence of using theoretical terminal raindrop fall velocities instead of measured values; and ii) the influence of time aggregation (rainfall intensity data every 5-, 10-, 15-, 30-, and 60-minutes). Empirical relationships did a relatively good job when complete events were considered (R2 > 0.82), but offered poorer results for within-event (one-minute resolution) variation. Also, systematic biases where large for many equations. When raindrop size distribution was known, estimating the terminal fall velocities by empirical laws produced good results even at fine time resolution. The influence of time aggregation was very high in the estimated kinetic energy, although linear scaling may allow empirical correction. This results stress the importance of considering all these effects when rainfall energy needs to be estimated from more standard precipitation records. , and recommends the use of disdrometer data to locally determine rainfall kinetic energy.

  18. The eddy kinetic energy budget in the Red Sea

    KAUST Repository

    Zhan, Peng

    2016-06-09

    The budget of eddy kinetic energy (EKE) in the Red Sea, including the sources, redistributions and sink, is examined using a high-resolution eddy-resolving ocean circulation model. A pronounced seasonally varying EKE is identified, with its maximum intensity occurring in winter, and the strongest EKE is captured mainly in the central and northern basins within the upper 200 m. Eddies acquire kinetic energy from conversion of eddy available potential energy (EPE), from transfer of mean kinetic energy (MKE), and from direct generation due to time-varying (turbulent) wind stress, the first of which contributes predominantly to the majority of the EKE. The EPE-to-EKE conversion occurs almost in the entire basin, while the MKE-to-EKE transfer appears mainly along the shelf boundary of the basin (200 miso-bath) where high horizontal shear interacts with topography. The EKE generated by the turbulent wind stress is relatively small and limited to the southern basin. All these processes are intensified during winter, when the rate of energy conversion is about four to five times larger than that in summer. The EKE is redistributed by the vertical and horizontal divergence of energy flux and the advection of the mean flow. As a main sink of EKE, dissipation processes is ubiquitously found in the basin. The seasonal variability of these energy conversion terms can explain the significant seasonality of eddy activities in the Red Sea. This article is protected by copyright. All rights reserved.

  19. Kinetic-energy absorber employs frictional force between mating cylinders

    Science.gov (United States)

    Conrad, E. W.

    1964-01-01

    A kinetic energy absorbing device uses a series of coaxial, mating cylindrical surfaces. These surfaces have high frictional resistance to relative motion when axial impact forces are applied. The device is designed for safe deceleration of vehicles impacting on landing surfaces.

  20. Kinetic Energy of a Free Quantum Brownian Particle

    Directory of Open Access Journals (Sweden)

    Paweł Bialas

    2018-02-01

    Full Text Available We consider a paradigmatic model of a quantum Brownian particle coupled to a thermostat consisting of harmonic oscillators. In the framework of a generalized Langevin equation, the memory (damping kernel is assumed to be in the form of exponentially-decaying oscillations. We discuss a quantum counterpart of the equipartition energy theorem for a free Brownian particle in a thermal equilibrium state. We conclude that the average kinetic energy of the Brownian particle is equal to thermally-averaged kinetic energy per one degree of freedom of oscillators of the environment, additionally averaged over all possible oscillators’ frequencies distributed according to some probability density in which details of the particle-environment interaction are present via the parameters of the damping kernel.

  1. Kinetics with deactivation of methylcyclohexane dehydrogenation for hydrogen energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Maria, G.; Marin, A.; Wyss, C.; Mueller, S.; Newson, E. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    The methylcyclohexane dehydrogenation step to recycle toluene and release hydrogen is being studied as part of a hydrogen energy storage project. The reaction is performed catalytically in a fixed bed reactor, and the efficiency of this step significantly determines overall system economics. The fresh catalyst kinetics and the deactivation of the catalyst by coke play an important role in the process analysis. The main reaction kinetics were determined from isothermal experiments using a parameter sensitivity analysis for model discrimination. An activation energy for the main reaction of 220{+-}11 kJ/mol was obtained from a two-parameter model. From non-isothermal deactivation in PC-controlled integral reactors, an activation energy for deactivation of 160 kJ/mol was estimated. A model for catalyst coke content of 3-17 weight% was compared with experimental data. (author) 3 figs., 6 refs.

  2. Split kinetic energy method for quantum systems with competing potentials

    International Nuclear Information System (INIS)

    Mineo, H.; Chao, Sheng D.

    2012-01-01

    For quantum systems with competing potentials, the conventional perturbation theory often yields an asymptotic series and the subsequent numerical outcome becomes uncertain. To tackle such a kind of problems, we develop a general solution scheme based on a new energy dissection idea. Instead of dividing the potential energy into “unperturbed” and “perturbed” terms, a partition of the kinetic energy is performed. By distributing the kinetic energy term in part into each individual potential, the Hamiltonian can be expressed as the sum of the subsystem Hamiltonians with respective competing potentials. The total wavefunction is expanded by using a linear combination of the basis sets of respective subsystem Hamiltonians. We first illustrate the solution procedure using a simple system consisting of a particle under the action of double δ-function potentials. Next, this method is applied to the prototype systems of a charged harmonic oscillator in strong magnetic field and the hydrogen molecule ion. Compared with the usual perturbation approach, this new scheme converges much faster to the exact solutions for both eigenvalues and eigenfunctions. When properly extended, this new solution scheme can be very useful for dealing with strongly coupling quantum systems. - Highlights: ► A new basis set expansion method is proposed. ► Split kinetic energy method is proposed to solve quantum eigenvalue problems. ► Significant improvement has been obtained in converging to exact results. ► Extension of such methods is promising and discussed.

  3. Evolution of Nagaoka phase with kinetic energy frustrating hopping

    Science.gov (United States)

    Lisandrini, F. T.; Bravo, B.; Trumper, A. E.; Manuel, L. O.; Gazza, C. J.

    2017-05-01

    We investigate, using the density-matrix renormalization group, the evolution of the Nagaoka state with t' hopping that frustrates the hole kinetic energy in the U =∞ Hubbard model on the square and anisotropic triangular lattices. We find that the Nagaoka ferromagnet survives up to a rather small tc'/t ˜0.2 . At this critical value, there is a transition to an antiferromagnetic phase that depends on the lattice: a Q =(Q ,0 ) spiral order, which continuously evolves with t', for the triangular lattice and the usual Q =(π ,π ) Néel order for the square lattice. Remarkably, the local magnetization takes its classical value for all considered t' (t'/t ≤1 ). Our results show that the recently found classical kinetic antiferromagnetism, a perfect counterpart of Nagaoka ferromagnetism, is a generic phenomenon in these kinetically frustrated electronic systems.

  4. Turbulent Kinetic Energy in the Energy Balance of a Solar Flare.

    Science.gov (United States)

    Kontar, E P; Perez, J E; Harra, L K; Kuznetsov, A A; Emslie, A G; Jeffrey, N L S; Bian, N H; Dennis, B R

    2017-04-14

    The energy released in solar flares derives from a reconfiguration of magnetic fields to a lower energy state, and is manifested in several forms, including bulk kinetic energy of the coronal mass ejection, acceleration of electrons and ions, and enhanced thermal energy that is ultimately radiated away across the electromagnetic spectrum from optical to x rays. Using an unprecedented set of coordinated observations, from a suite of instruments, we here report on a hitherto largely overlooked energy component-the kinetic energy associated with small-scale turbulent mass motions. We show that the spatial location of, and timing of the peak in, turbulent kinetic energy together provide persuasive evidence that turbulent energy may play a key role in the transfer of energy in solar flares. Although the kinetic energy of turbulent motions accounts, at any given time, for only ∼(0.5-1)% of the energy released, its relatively rapid (∼1-10  s) energization and dissipation causes the associated throughput of energy (i.e., power) to rival that of major components of the released energy in solar flares, and thus presumably in other astrophysical acceleration sites.

  5. Plasmadynamics and ionization kinetics of thermionic energy conversion

    Energy Technology Data Exchange (ETDEWEB)

    Lawless, J.L. Jr.; Lam, S.H.

    1982-02-01

    To reduce the plasma arc-drop, thermionic energy conversion is studied with both analytical and numerical tools. Simplifications are made in both the plasmadynamic and ionization-recombination theories. These are applied to a scheme proposed presently using laser irradiation to enhance the ionization kinetics of the thermionic plasma and thereby reduce the arc-drop. It is also predicted that it is possible to generate the required laser light from a thermionic-type cesium plasma. The analysis takes advantage of theoretical simplifications derived for the ionization-recombination kinetics. It is shown that large laser ionization enhancements can occur and that collisional cesium recombination lasing is expected. To complement the kinetic theory, a numerical method is developed to solve the thermionic plasma dynamics. To combine the analysis of ionization-recombination kinetics with the plasma dynamics of thermionic conversion, a finite difference computer program is constructed. It is capable of solving for both unsteady and steady thermionic converter behavior including possible laser ionization enhancement or atomic recombination lasing. A proposal to improve thermionic converter performance using laser radiation is considered. In this proposed scheme, laser radiation impinging on a thermionic plasma enhances the ionization process thereby raising the plasma density and reducing the plasma arc-drop. A source for such radiation may possibly be a cesium recombination laser operating in a different thermionic converter. The possibility of this being an energy efficient process is discussed. (WHK)

  6. Rotational and divergent kinetic energy in the mesoscale model ALADIN

    Directory of Open Access Journals (Sweden)

    V. Blažica

    2013-03-01

    Full Text Available Kinetic energy spectra from the mesoscale numerical weather prediction (NWP model ALADIN with horizontal resolution 4.4 km are split into divergent and rotational components which are then compared at horizontal scales below 300 km and various vertical levels. It is shown that about 50% of kinetic energy in the free troposphere in ALADIN is divergent energy. The percentage increases towards 70% near the surface and in the upper troposphere towards 100 hPa. The maximal percentage of divergent energy is found at stratospheric levels around 100 hPa and at scales below 100 km which are not represented by the global models. At all levels, the divergent energy spectra are characterised by shallower slopes than the rotational energy spectra, and the difference increases as horizontal scales become larger. A very similar vertical distribution of divergent energy is obtained by using the standard ALADIN approach for the computation of spectra based on the extension zone and by applying detrending approach commonly used in mesoscale NWP community.

  7. Nonequilibrium electron energy-loss kinetics in metal clusters

    CERN Document Server

    Guillon, C; Fatti, N D; Vallee, F

    2003-01-01

    Ultrafast energy exchanges of a non-Fermi electron gas with the lattice are investigated in silver clusters with sizes ranging from 4 to 26 nm using a femtosecond pump-probe technique. The results yield evidence for a cluster-size-dependent slowing down of the short-time energy losses of the electron gas when it is strongly athermal. A constant rate is eventually reached after a few hundred femtoseconds, consistent with the electron gas internal thermalization kinetics, this behaviour reflecting evolution from an individual to a collective electron-lattice type of coupling. The timescale of this transient regime is reduced in small nanoparticles, in agreement with speeding up of the electron-electron interactions with size reduction. The experimental results are in quantitative agreement with numerical simulations of the electron kinetics.

  8. Local kinetic-energy density of the Airy gas

    DEFF Research Database (Denmark)

    Vitos, Levente; Johansson, B.; Kollár, J.

    2000-01-01

    The Airy gas model is used to derive an expression for the local kinetic energy in the linear potential approximation. The expression contains an explicit Laplacian term 2/5((h) over bar(2)/2m)del(mu)(2)(r) that, according to jellium surface calculations, must be a universal feature of any accurate...... local description. Applied to the noble gases the expression reduces the errors by a factor of 50 over previous results obtained by the linear potential approximation....

  9. Kinetic energy and momentum distribution of isotopic liquid helium mixtures.

    Science.gov (United States)

    Boninsegni, Massimo

    2018-03-14

    The momentum distribution and atomic kinetic energy of the two isotopes of helium in a liquid mixture at temperature T = 2 K are computed by quantum Monte Carlo simulations. Quantum statistics is fully included for 4 He, whereas 3 He atoms are treated as distinguishable. Comparison of theoretical estimates with a collection of the most recent experimental measurements shows reasonable agreement for the energetics of 4 He and pure 3 He. On the other hand, a significant discrepancy (already observed in previous studies) is reported between computed and measured values of the 3 He kinetic energy in the mixture, especially in the limit of low 3 He concentration. We assess quantitatively the importance of Fermi statistics and find it to be negligible for a 3 He concentration ≲20%. Our results for the momentum distribution lend support to what was already hypothesized by other authors, namely, that the discrepancy is likely due to underestimation of the 3 He kinetic energy contribution associated with the tail of the experimentally measured momentum distribution.

  10. Incidence and kinetics of distant metastases in patients with operable breast cancer

    International Nuclear Information System (INIS)

    Kryj, M.; Maciejewski, B.; Withers, H.R.; Taylor, J.M.G.

    1997-01-01

    The purpose of this paper is to evaluate the incidence and kinetics of distant metastases in operable breast cancer and to relate these estimates to various tumor and patient characteristics. The records of 309 consecutive patients with operable breast cancer in stage T 1-4 N 0-1 M 0 were reviewed, and the incidence of distant metastases (DM) and death due to DM were evaluated. 195 patients had positive axillary nodes with following distribution of the number of nodes: 45% had 1-2 node, 16% had 3-4 nodes, 14% and 25% had 5-7 and more nodes, respectively. All patients were treated with radical mastectomy with axillary nodes dissection (the only treatment in 39% of cases). In 198 cases radical mastectomy was combined with radiotherapy and/or chemotherapy given pre- or postoperatively. Hormonal treatment was given in 27% of cases. Minimum follow-up was 10 years. Distant metastases were found in 150 cases (49%) and in 78 cases (25%) they develop early, during the first 18 months follow-up. Average rate of DM in N 0 cases was 25%. Number of involved nodes and extra-capsular invasion were found significant and independent prognostic factors. High risk (%)%) of DM and death due to DM correlate with age T 3 , more than 2 axillary nodes and or extra-capsular invasion. The linearity of the curves for freedom from DM and for freedom from death due to the DM suggest uniform distribution of progression rates with a median value for halving time for freedom from early DM of about 8 months, and of about 40 months for freedom from the DM occurring later than 18 months, being for whole group and average of 20 months. High incidence of DM is a significant cause of poor long-term survival. Early appearance (<18 month follow-up) of about half of the DM suggests that they are already present as subclinical micrometastases at the time of initial loco-regional treatment. The time of appearance of distant metastases is consistent with a wide range of metastatic cell burdens among patients

  11. Trivial constraints on orbital-free kinetic energy density functionals

    Science.gov (United States)

    Luo, Kai; Trickey, S. B.

    2018-03-01

    Approximate kinetic energy density functionals (KEDFs) are central to orbital-free density functional theory. Limitations on the spatial derivative dependencies of KEDFs have been claimed from differential virial theorems. We identify a central defect in the argument: the relationships are not true for an arbitrary density but hold only for the minimizing density and corresponding chemical potential. Contrary to the claims therefore, the relationships are not constraints and provide no independent information about the spatial derivative dependencies of approximate KEDFs. A simple argument also shows that validity for arbitrary v-representable densities is not restored by appeal to the density-potential bijection.

  12. Flywheels for Low-Speed Kinetic Energy Storage Systems

    Energy Technology Data Exchange (ETDEWEB)

    Portnov, G.; Cruz, I.; Arias, F.; Fiffe, R. P.

    2003-07-01

    A brief overview of different steel disc-type flywheels is presented. It contents the analysis of relationship between stress-state and kinetic energy of rotating body, comparison of the main characteristics of flywheels and description of their optimization procedures. It is shown that profiles of the discs calculated on a basis of plane stress-state assumption may be considered only as a starting point for its further improvement using 3-D approach. The aim of the review is to provide a designer for a insight into problem of shaping of steel flywheels. (Author) 19 refs.

  13. Flywheels for Low-Speed Kinetic Energy Storage Systems

    International Nuclear Information System (INIS)

    Portnov, G.; Cruz, I.; Arias, F.; Fiffe, R. P.

    2003-01-01

    A brief overview of different steel disc-type flywheels is presented. It contents the analysis of relationship between stress-state and kinetic energy of rotating body, comparison of the main characteristics of flywheels and description of their optimization procedures. It is shown that pro files of the discs calculated on a basis of plane stress-state assumption may be considered only as a starting point for its further improvement using 3-D approach. The aim of the review is to provide a designer for a insight into problem of shaping of steel flywheels. (Author) 19 refs

  14. Tunneling and reflection in unimolecular reaction kinetic energy release distributions

    Science.gov (United States)

    Hansen, K.

    2018-02-01

    The kinetic energy release distributions in unimolecular reactions is calculated with detailed balance theory, taking into account the tunneling and the reflection coefficient in three different types of transition states; (i) a saddle point corresponding to a standard RRKM-type theory, (ii) an attachment Langevin cross section, and (iii) an absorbing sphere potential at short range, without long range interactions. Corrections are significant in the one dimensional saddle point states. Very light and lightly bound absorbing systems will show measurable effects in decays from the absorbing sphere, whereas the Langevin cross section is essentially unchanged.

  15. Energy landscape and diffusion kinetics of lithiated silicon: A kinetic activation-relaxation technique study

    Science.gov (United States)

    Trochet, Mickaël; Mousseau, Normand

    2017-10-01

    With large specific and volumetric capacity, lithiated silicon is an excellent anode for lithium-ion batteries. Its application is challenged today, however, by the formation of an amorphous a -LixSi phase associated with a large volume change that occurs at relatively low Li concentration and remains only very partly understood at the microscopic level. In this paper, we characterize the full energy landscape associated with the onset of Li insertion in crystalline Si as a first step for understanding the lithiation process. We identify the diffusion mechanisms and migration energies for one to ten Li atoms in a Si crystal as well as the average lifetime of small lithium aggregates, using the kinetic activation-relaxation technique (kART), an off-lattice kinetic Monte-Carlo method with on-the-fly catalog building capabilities coupled to a newly developed force field (ReaxFF) used as potential based on ab initio results. We show that the short lifetimes of the bound states (from meV to ten meV) mean that Li atoms move in the interstitial sublattice with little interactions, explaining how high Li concentration in Si can be reached.

  16. Relationships between energy fluence and energy incident on, emitted by or imparted to a body.

    Science.gov (United States)

    Carlsson, C A

    1979-11-01

    From knowledge of the energy and angular distribution of the fluence around a body, the energy incident on, emitted by or imparted to a body can be calculated. The calculation is easily performed if the quantity 'vectorial fluence' is used. Examples taken from the literature are used to illustrate the erroneous results obtained by integrating energy fluence over area instead of integrating the scalar product of vectorial energy fluence and vectorial area.

  17. In situ photoemission spectroscopy using synchrotron radiation for O2 translational kinetic energy induced oxidation processes of partially-oxidized Si(001) surfaces

    International Nuclear Information System (INIS)

    Teraoka, Yuden; Yoshigoe, Akitaka

    2001-01-01

    The influence of translational kinetic energy of incident O 2 molecules for the passive oxidation process of partially-oxidized Si(001) surfaces has been studied by photoemission spectroscopy. The translational kinetic energy of O 2 molecules was controlled up to 3 eV by a supersonic seed beam technique using a high temperature nozzle. Two translational kinetic energy thresholds (1.0 eV and 2.6 eV) were found out in accordance with the first-principles calculation for the oxidation of clean surfaces. Si-2p photoemission spectra measured in representative translational kinetic energies revealed that the translational kinetic energy dependent oxidation of dimers and the second layer (subsurface) backbonds were caused by the direct dissociative chemisorption of O 2 molecules. Moreover, the difference in chemical bonds for oxygen atoms was found out to be as low and high binding energy components in O-1s photoemission spectra. Especially, the low binding energy component increased with increasing the translational kinetic energy that indicates the translational kinetic energy induced oxidation in backbonds. (author)

  18. Kinetic energy budget for electroconvective flows near ion selective membranes

    Science.gov (United States)

    Wang, Karen; Mani, Ali

    2017-11-01

    Electroconvection occurs when ions are driven from a bulk fluid through an ion-selective surface. When the driving voltage is beyond a threshold, this process undergoes a hydrodynamic instability called electroconvection, which can become chaotic due to nonlinear coupling between ion-transport, fluid flow, and electrostatic forces. Electroconvection significantly enhances ion transport and plays an important role in a wide range of electrochemical applications. We investigate this phenomenon by considering a canonical geometry consisting of a symmetric binary electrolyte between an ion-selective membrane and a reservoir using 2D direct numerical simulation (DNS). Our simulations reveal that for most practical regimes, DNS of electroconvection is expensive. Thus, a plan towards development of reduced-order models is necessary to facilitate the adoption of analysis of this phenomenon in industry. Here we use DNS to analyze the kinetic energy budget to shed light into the mechanisms sustaining flow and mixing in electroconvective flows. Our analysis reveals the relative dominance of kinetic energy sources, dissipation, and transport mechanisms sustaining electroconvection at different distances from the interface and over a wide range of input parameters. Karen Wang was supported by the National Defense Science & Engineering Graduate Fellowship (NDSEG). Ali Mani was supported by the National Science Foundation Award.

  19. Recommended Auger-electron kinetic energies for 42 elemental solids

    International Nuclear Information System (INIS)

    Powell, C.J.

    2010-01-01

    An analysis is presented of Auger-electron kinetic energies (KEs) from four data sources for 65 Auger transitions in 45 elemental solids. For each data source, a single instrument had been used to measure KEs for many elements. In order to compare KEs from two sources, it was necessary to recalibrate the energy scales of each instrument using recommended reference data. Mean KEs are given for most of the Auger transitions for which there were at least two independent measurements and for which differences from the mean KEs were considered acceptably small. In several cases, comparisons were made to published KE data to resolve discrepancies. We are able to recommend mean KEs for 59 Auger transitions from 42 elemental solids and to provide estimates of the uncertainties of these KEs. This compilation should be useful for the determination of chemical shifts of Auger peaks in Auger electron spectroscopy and X-ray photoelectron spectroscopy.

  20. Kinetic Energy of Tornadoes in the United States.

    Directory of Open Access Journals (Sweden)

    Tyler Fricker

    Full Text Available Tornadoes can cause catastrophic destruction. Here total kinetic energy (TKE as a metric of destruction is computed from the fraction of the tornado path experiencing various damage levels and a characteristic wind speed for each level. The fraction of the path is obtained from a model developed for the Nuclear Regulatory Commission that combines theory with empirical data. TKE is validated as a useful metric by comparing it to other indexes and loss indicators. Half of all tornadoes have TKE exceeding 62.1 GJ and a quarter have TKE exceeding 383.2 GJ. One percent of the tornadoes have TKE exceeding 31.9 TJ. April has more energy than May with fewer tornadoes; March has more energy than June with half as many tornadoes. September has the least energy but November and December have the fewest tornadoes. Alabama ranks number one in terms of tornado energy with 2.48 PJ over the period 2007-2013. TKE can be used to help better understand the changing nature of tornado activity.

  1. Kinetic Energy of Tornadoes in the United States.

    Science.gov (United States)

    Fricker, Tyler; Elsner, James B

    2015-01-01

    Tornadoes can cause catastrophic destruction. Here total kinetic energy (TKE) as a metric of destruction is computed from the fraction of the tornado path experiencing various damage levels and a characteristic wind speed for each level. The fraction of the path is obtained from a model developed for the Nuclear Regulatory Commission that combines theory with empirical data. TKE is validated as a useful metric by comparing it to other indexes and loss indicators. Half of all tornadoes have TKE exceeding 62.1 GJ and a quarter have TKE exceeding 383.2 GJ. One percent of the tornadoes have TKE exceeding 31.9 TJ. April has more energy than May with fewer tornadoes; March has more energy than June with half as many tornadoes. September has the least energy but November and December have the fewest tornadoes. Alabama ranks number one in terms of tornado energy with 2.48 PJ over the period 2007-2013. TKE can be used to help better understand the changing nature of tornado activity.

  2. Total Kinetic Energy and Fragment Mass Distribution of Neutron-Induced Fission of U-233

    Energy Technology Data Exchange (ETDEWEB)

    Higgins, Daniel James [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Schmitt, Kyle Thomas [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mosby, Shea Morgan [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Tovesson, Fredrik [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-09-29

    Properties of fission in U-233 were studied at the Los Alamos Neutron Science Center (LANSCE) at incident neutron energies from thermal to 40 MeV at both the Lujan Neutron Scattering Center flight path 12 and at WNR flight path 90-Left from Dec 2016 to Jan 2017. Fission fragments are observed in coincidence using a twin ionization chamber with Frisch grids. The average total kinetic energy (TKE) released from fission and fragment mass distributions are calculated from observations of energy deposited in the detector and conservation of mass and momentum. Accurate experimental measurements of these parameters are necessary to better understand the fission process and obtain data necessary for calculating criticality. The average TKE released from fission has been well characterized for several isotopes at thermal neutron energy, however, few measurements have been made at fast neutron energies. This experiment expands on previous successful experiments using an ionization chamber to measure TKE and fragment mass distributions of U-235, U-238, and Pu-239. This experiment requires the full spectrum of neutron energies and can therefore only be performed at a small number of facilities in the world. The required full neutron energy spectrum is obtained by combining measurements from WNR 90L and Lujan FP12 at LANSCE.

  3. ENERGY DISSIPATION IN MAGNETIC NULL POINTS AT KINETIC SCALES

    International Nuclear Information System (INIS)

    Olshevsky, Vyacheslav; Lapenta, Giovanni; Divin, Andrey; Eriksson, Elin; Markidis, Stefano

    2015-01-01

    We use kinetic particle-in-cell and MHD simulations supported by an observational data set to investigate magnetic reconnection in clusters of null points in space plasma. The magnetic configuration under investigation is driven by fast adiabatic flux rope compression that dissipates almost half of the initial magnetic field energy. In this phase powerful currents are excited producing secondary instabilities, and the system is brought into a state of “intermittent turbulence” within a few ion gyro-periods. Reconnection events are distributed all over the simulation domain and energy dissipation is rather volume-filling. Numerous spiral null points interconnected via their spines form null lines embedded into magnetic flux ropes; null point pairs demonstrate the signatures of torsional spine reconnection. However, energy dissipation mainly happens in the shear layers formed by adjacent flux ropes with oppositely directed currents. In these regions radial null pairs are spontaneously emerging and vanishing, associated with electron streams and small-scale current sheets. The number of spiral nulls in the simulation outweighs the number of radial nulls by a factor of 5–10, in accordance with Cluster observations in the Earth's magnetosheath. Twisted magnetic fields with embedded spiral null points might indicate the regions of major energy dissipation for future space missions such as the Magnetospheric Multiscale Mission

  4. Sensible Heat Flux Related to Variations in Atmospheric Turbulence Kinetic Energy on a Sandy Beach

    Science.gov (United States)

    2017-06-01

    FLUX RELATED TO VARIATIONS IN ATMOSPHERIC TURBULENCE KINETIC ENERGY ON A SANDY BEACH by Jessica S. Koscinski June 2017 Thesis Advisor...KINETIC ENERGY ON A SANDY BEACH 5. FUNDING NUMBERS 6. AUTHOR(S) Jessica S. Koscinski 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) Naval...Sensible heat flux, turbulence kinetic energy , surf zone 15. NUMBER OF PAGES 57 16. PRICE CODE 17. SECURITY CLASSIFICATION OF REPORT

  5. Functional derivative of the kinetic energy functional for spherically symmetric systems.

    Science.gov (United States)

    Nagy, Á

    2011-07-28

    Ensemble non-interacting kinetic energy functional is constructed for spherically symmetric systems. The differential virial theorem is derived for the ensemble. A first-order differential equation for the functional derivative of the ensemble non-interacting kinetic energy functional and the ensemble Pauli potential is presented. This equation can be solved and a special case of the solution provides the original non-interacting kinetic energy of the density functional theory. © 2011 American Institute of Physics

  6. Experimental evidence of the decrease of kinetic energy of hadrons in passing through atomic nuclei

    Science.gov (United States)

    Strugalski, Z.

    1985-01-01

    Hadrons with kinetic energies higher than the pion production threshold lose their kinetic energies monotonically in traversing atomic nuclei, due to the strong interactions in nuclear matter. This phenomenon is a crude analogy to the energy loss of charged particles in their passage through materials. Experimental evidence is presented.

  7. Mass independent kinetic energy reducing inlet system for vacuum environment

    Science.gov (United States)

    Reilly, Peter T. A. [Knoxville, TN

    2010-12-14

    A particle inlet system comprises a first chamber having a limiting orifice for an incoming gas stream and a micrometer controlled expansion slit. Lateral components of the momentum of the particles are substantially cancelled due to symmetry of the configuration once the laminar flow converges at the expansion slit. The particles and flow into a second chamber, which is maintained at a lower pressure than the first chamber, and then moves into a third chamber including multipole guides for electromagnetically confining the particle. The vertical momentum of the particles descending through the center of the third chamber is minimized as an upward stream of gases reduces the downward momentum of the particles. The translational kinetic energy of the particles is near-zero irrespective of the mass of the particles at an exit opening of the third chamber, which may be advantageously employed to provide enhanced mass resolution in mass spectrometry.

  8. Utilization of rotor kinetic energy storage for hybrid vehicles

    Science.gov (United States)

    Hsu, John S [Oak Ridge, TN

    2011-05-03

    A power system for a motor vehicle having an internal combustion engine, the power system comprises an electric machine (12) further comprising a first excitation source (47), a permanent magnet rotor (28) and a magnetic coupling rotor (26) spaced from the permanent magnet rotor and at least one second excitation source (43), the magnetic coupling rotor (26) also including a flywheel having an inertial mass to store kinetic energy during an initial acceleration to an operating speed; and wherein the first excitation source is electrically connected to the second excitation source for power cycling such that the flywheel rotor (26) exerts torque on the permanent magnet rotor (28) to assist braking and acceleration of the permanent magnet rotor (28) and consequently, the vehicle. An axial gap machine and a radial gap machine are disclosed and methods of the invention are also disclosed.

  9. Pathway and conversion of energy incident on auroral and sub-auroral ionosphere at substorm expansion onset

    Science.gov (United States)

    Ebihara, Y.; Tanaka, T.

    2017-12-01

    One explanation for SAPS/SAID is the poleward ionospheric electric field arising from a pair of Region 1 and Region 2 field-aligned currents (FACs). At substorm expansion onset, the FACs are intensified, resulting in intensification of energy incident on the auroral and sub-auroral ionosphere. Where does the energy comes from? Based on the results obtained by the global magnetohydrodynamics (MHD) simulation, we present energy flow and energy conversion associated with the Region 1 and Region 2 FACs that are intensified at the onset of substorm expansion. The cusp/mantle region transmits electromagnetic energy to almost the entire region of the magnetosphere. A part of electromagnetic energy is stored in the lobe in the growth phase. When reconnection takes place in the near-Earth tail region, the stored energy is released in addition to the continuously supplied one from the cusp/mantle dynamo. Two types of pathways of energy seem to be involved in the generation of the near-Earth dynamo that is associated with FACs at the expansion onset. The first type is related to the earthward fast flow in the plasma sheet. The electromagnetic energy coming from the lobe splits into the thermal energy and the kinetic energy. The kinetic energy is then converted to the thermal energy and the electromagnetic energy, in association of flow braking. The second type is that the plasma coming from the lobe goes into the inner magnetosphere directly. The electromagnetic energy is converted to the thermal energy, followed by the electromagnetic energy at off-equator. The near-Earth dynamo region seems to be embedded in the magnetospheric convection system. In this sense, the expansion onset may be regarded as a sudden, local intensification of the convection.

  10. A Comparison of Kinetic Energy and Momentum in Special Relativity and Classical Mechanics

    Science.gov (United States)

    Riggs, Peter J.

    2016-01-01

    Kinetic energy and momentum are indispensable dynamical quantities in both the special theory of relativity and in classical mechanics. Although momentum and kinetic energy are central to understanding dynamics, the differences between their relativistic and classical notions have not always received adequate treatment in undergraduate teaching.…

  11. Key role of molecular kinetic energy in early stages of pentacene island growth

    NARCIS (Netherlands)

    Wu, Yu; Toccoli, Tullio; Zhang, Jian; Koch, Norbert; Iacob, Erica; Pallaoro, Alessia; Iannotta, Salvatore; Rudolf, Petra

    Organic molecular beam deposition is studied systematically at thermal and hyperthermal regimes aiming at investigating the role of molecular kinetic energy on the growth mechanism of pentacene submonolayers on SiO (x) /Si. We show that the kinetic energy of the impinging molecule (E (k) ) plays a

  12. Kinetic Energy Dissipation on Labyrinth Configuration Stepped Spillway

    Directory of Open Access Journals (Sweden)

    Jaafar S. Maatooq

    2017-12-01

    Full Text Available In present work a labyrinth (zigzag, in shape has been used to configure the steps of stepped spillway by using the physical model. This configuration does not introduce previously by investigators or in construction techniques of dams or cascades. It would be expected to improve the flow over chute. A magnifying the width path of each step to become, LT, instead of, W, will induce the interlocking between the mainstream and that spread laterally due to labyrinth path. This phenomenon leads to reduce the jet velocities near the surfaces, thus minimizing the ability of cavitation and with increasing a circulation regions the ability of air entrainment be maximized. The results were encouraging, (e.g., the reverse performance has recorded for spillway slope. From the evaluation of outcome, the average recorded of percentage profits of kinetic energy dissipation with a labyrinth shape compared with the results of traditional shape were ranged between (13- 44%. Different predictive formulas have been proposed based on iteration analysis, can be recommended for evaluation and design.

  13. 18 CFR 1316.9 - Nuclear energy hazards and nuclear incidents.

    Science.gov (United States)

    2010-04-01

    ... 18 Conservation of Power and Water Resources 2 2010-04-01 2010-04-01 false Nuclear energy hazards... Text of Conditions and Certifications § 1316.9 Nuclear energy hazards and nuclear incidents. When so... documents or actions: Nuclear Energy Hazards and Nuclear Incidents (Applicable only to contracts for goods...

  14. The influence of waves on the tidal kinetic energy resource at a tidal stream energy site

    International Nuclear Information System (INIS)

    Guillou, Nicolas; Chapalain, Georges; Neill, Simon P.

    2016-01-01

    Highlights: • We model the influence of waves on tidal kinetic energy in the Fromveur Strait. • Numerical results are compared with field data of waves and currents. • The introduction of waves improve predictions of tidal stream power during storm. • Mean spring tidal stream potential is reduced by 12% during extreme wave conditions. • Potential is reduced by 7.8% with waves forces and 5.3% with enhanced friction. - Abstract: Successful deployment of tidal energy converters relies on access to accurate and high resolution numerical assessments of available tidal stream power. However, since suitable tidal stream sites are located in relatively shallow waters of the continental shelf where tidal currents are enhanced, tidal energy converters may experience effects of wind-generated surface-gravity waves. Waves may thus influence tidal currents, and associated kinetic energy, through two non-linear processes: the interaction of wave and current bottom boundary layers, and the generation of wave-induced currents. Here, we develop a three-dimensional tidal circulation model coupled with a phase-averaged wave model to quantify the impact of the waves on the tidal kinetic energy resource of the Fromveur Strait (western Brittany) - a region that has been identified with strong potential for tidal array development. Numerical results are compared with in situ observations of wave parameters (significant wave height, peak period and mean wave direction) and current amplitude and direction 10 m above the seabed (the assumed technology hub height for this region). The introduction of waves is found to improve predictions of tidal stream power at 10 m above the seabed at the measurement site in the Strait, reducing kinetic energy by up to 9% during storm conditions. Synoptic effects of wave radiation stresses and enhanced bottom friction are more specifically identified at the scale of the Strait. Waves contribute to a slight increase in the spatial gradient of

  15. Turbulent Kinetic Energy (TKE) Budgets Using 5-beam Doppler Profilers

    Science.gov (United States)

    Guerra, M. A.; Thomson, J. M.

    2016-12-01

    Field observations of turbulence parameters are important for the development of hydrodynamic models, understanding contaminant mixing, and predicting sediment transport. The turbulent kinetic energy (TKE) budget quantifies where turbulence is being produced, dissipated or transported at a specific site. The Nortek Signature 5-beam AD2CP was used to measure velocities at high sampling rates (up to 8 Hz) at Admiralty Inlet and Rich Passage in Puget Sound, WA, USA. Raw along-beam velocity data is quality controlled and is used to estimate TKE spectra, spatial structure functions, and Reynolds stress tensors. Exceptionally low Doppler noise in the data enables clear observations of the inertial sub-range of isotropic turbulence in both the frequency TKE spectra and the spatial structure functions. From these, TKE dissipation rates are estimated following Kolmogorov's theory of turbulence. The TKE production rates are estimated using Reynolds stress tensors together with the vertical shear in the mean flow. The Reynolds stress tensors are estimated following the methodology of Dewey and Stinger (2007), which is significantly improved by inclusion of the 5th beam (as opposed to the conventional 4). These turbulence parameters are used to study the TKE budget along the water column at the two sites. Ebb and flood production and dissipation rates are compared through the water column at both sites. At Admiralty Inlet, dissipation exceeds production during ebb while the opposite occurs during flood because the proximity to a lateral headland. At Rich Passage, production exceeds dissipation through the water column for all tidal conditions due to a vertical sill in the vicinity of the measurement site.

  16. Energy partitioning constraints at kinetic scales in low-β turbulence

    Science.gov (United States)

    Gershman, Daniel J.; F.-Viñas, Adolfo; Dorelli, John C.; Goldstein, Melvyn L.; Shuster, Jason; Avanov, Levon A.; Boardsen, Scott A.; Stawarz, Julia E.; Schwartz, Steven J.; Schiff, Conrad; Lavraud, Benoit; Saito, Yoshifumi; Paterson, William R.; Giles, Barbara L.; Pollock, Craig J.; Strangeway, Robert J.; Russell, Christopher T.; Torbert, Roy B.; Moore, Thomas E.; Burch, James L.

    2018-02-01

    Turbulence is a fundamental physical process through which energy injected into a system at large scales cascades to smaller scales. In collisionless plasmas, turbulence provides a critical mechanism for dissipating electromagnetic energy. Here, we present observations of plasma fluctuations in low-β turbulence using data from NASA's Magnetospheric Multiscale mission in Earth's magnetosheath. We provide constraints on the partitioning of turbulent energy density in the fluid, ion-kinetic, and electron-kinetic ranges. Magnetic field fluctuations dominated the energy density spectrum throughout the fluid and ion-kinetic ranges, consistent with previous observations of turbulence in similar plasma regimes. However, at scales shorter than the electron inertial length, fluctuation power in electron kinetic energy significantly exceeded that of the magnetic field, resulting in an electron-motion-regulated cascade at small scales. This dominance is highly relevant for the study of turbulence in highly magnetized laboratory and astrophysical plasmas.

  17. On the Equipartition of Kinetic Energy in an Ideal Gas Mixture

    Science.gov (United States)

    Peliti, L.

    2007-01-01

    A refinement of an argument due to Maxwell for the equipartition of translational kinetic energy in a mixture of ideal gases with different masses is proposed. The argument is elementary, yet it may work as an illustration of the role of symmetry and independence postulates in kinetic theory. (Contains 1 figure.)

  18. Determination of kinetic coefficients for proton-nucleus collisions at high energy

    International Nuclear Information System (INIS)

    Rizzato, C.M.

    1987-01-01

    From the effective proton dynamics, the approximations in the context of high energy collisions which lead to the Boltzmann equation, are established. From this equation, general expressions for the kinetic coefficients are deduced. Using a simple model, analytical expressions for kinetic coefficients are obtained. The importance of the effect of Pauli blocking is also shown. (author) [pt

  19. Energy Conservation Tests of a Coupled Kinetic-kinetic Plasma-neutral Transport Code

    Energy Technology Data Exchange (ETDEWEB)

    Stotler, D. P.; Chang, C. S.; Ku, S. H.; Lang, J.; Park, G.

    2012-08-29

    A Monte Carlo neutral transport routine, based on DEGAS2, has been coupled to the guiding center ion-electron-neutral neoclassical PIC code XGC0 to provide a realistic treatment of neutral atoms and molecules in the tokamak edge plasma. The DEGAS2 routine allows detailed atomic physics and plasma-material interaction processes to be incorporated into these simulations. The spatial pro le of the neutral particle source used in the DEGAS2 routine is determined from the uxes of XGC0 ions to the material surfaces. The kinetic-kinetic plasma-neutral transport capability is demonstrated with example pedestal fueling simulations.

  20. Raindrop Kinetic Energy Piezoelectric Harvesters and Relevant Interface Circuits: Review, Issues and Outlooks

    Directory of Open Access Journals (Sweden)

    Kok Gnee CHUA

    2016-05-01

    Full Text Available As an ecological source of renewable energy, the available kinetic energy of rainfall is not trifling, especially in tropical countries at the equators. The research on the use of piezoelectric transducer to harvest raindrop kinetic energy is gaining more and more attention recently. This article reviews the state-of-the-art energy harvesting technology from the conversion of raindrop kinetic energy using piezoelectric transducers as well as its interface circuits for vibration-based energy harvesters. Performance of different types of piezoelectric harvesters in terms of power output, area power density and energy conversion efficiency are compared. Summaries of key problems and suggestions on the optimization of the performance of the piezoelectric harvesters are also provided for future works.

  1. Near-surface circulation and kinetic energy in the tropical Indian Ocean derived from lagrangian drifters

    Digital Repository Service at National Institute of Oceanography (India)

    Shenoi, S.S.C.; Saji, P.K.; Almeida, A.M.

    Trajectories of 412 satellite-tracked drifting buoys deployed in the tropical Indian Ocean have been analyzed to document the surface circulation and kinetic energy field. Only drifters drogued at 15 m depth and having drag area ratio greater than...

  2. Seasonal variability in the vertical current structure and kinetic energy in the Central Indian Ocean Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Murty, V.S.N.; Savin, M.; RameshBabu, V.; Suryanarayana, A.

    apart, indicates the existence of anticyclonic gyral circulation. The depth variation of kinetic energy (KE) emphasises the bottom intensification of currents with minimum KE at deeper depths followed by relatively higher KE at abyssal depths...

  3. Efficient First-Principles Calculation of the Quantum Kinetic Energy and Momentum Distribution of Nuclei

    Science.gov (United States)

    Ceriotti, Michele; Manolopoulos, David E.

    2012-09-01

    Light nuclei at room temperature and below exhibit a kinetic energy which significantly deviates from the predictions of classical statistical mechanics. This quantum kinetic energy is responsible for a wide variety of isotope effects of interest in fields ranging from chemistry to climatology. It also furnishes the second moment of the nuclear momentum distribution, which contains subtle information about the chemical environment and has recently become accessible to deep inelastic neutron scattering experiments. Here, we show how, by combining imaginary time path integral dynamics with a carefully designed generalized Langevin equation, it is possible to dramatically reduce the expense of computing the quantum kinetic energy. We also introduce a transient anisotropic Gaussian approximation to the nuclear momentum distribution which can be calculated with negligible additional effort. As an example, we evaluate the structural properties, the quantum kinetic energy, and the nuclear momentum distribution for a first-principles simulation of liquid water.

  4. Efficient first-principles calculation of the quantum kinetic energy and momentum distribution of nuclei

    OpenAIRE

    Ceriotti, Michele; Manolopoulos, David E.

    2014-01-01

    Light nuclei at room temperature and below exhibit a kinetic energy which significantly deviates from the predictions of classical statistical mechanics. This quantum kinetic energy is responsible for a wide variety of isotope effects of interest in fields ranging from chemistry to climatology. It also furnishes the second moment of the nuclear momentum distribution, which contains subtle information about the chemical environment and has recently become accessible to deep inelastic neutron s...

  5. Critical analysis of major incidents risks in civil nuclear energy

    International Nuclear Information System (INIS)

    2000-09-01

    The differences existing between the PWR type reactors and the RBMK type reactors are explained as well as the risk associated to each type when it exists. The Ines scale, tool to give the level of an accident gravity comprises seven levels, the number seven is the most serious and corresponds to the Chernobyl accident; The number zero is of no consequence but must be mentioned as a matter of form. The incidents from 1 to 3 concern increasing incidents, affecting the nuclear power plant but not the external public. The accidents from 4 to 7 have a nature to affect the nuclear power plant and the environment. An efficient tool exists between nuclear operators it is made of the reports on incidents encountered by close reactors. Two others type reactors are coming, the high temperature type reactors and the fast neutrons reactors. different risks are evoked, terrorism, proliferation, transport and radioactive wastes. (N.C.)

  6. Investigation of the heavy nuclei fission with anomalously high values of the fission fragments total kinetic energy

    Science.gov (United States)

    Khryachkov, Vitaly; Goverdovskii, Andrei; Ketlerov, Vladimir; Mitrofanov, Vecheslav; Sergachev, Alexei

    2018-03-01

    Binary fission of 232Th and 238U induced by fast neutrons were under intent investigation in the IPPE during recent years. These measurements were performed with a twin ionization chamber with Frisch grids. Signals from the detector were digitized for further processing with a specially developed software. It results in information of kinetic energies, masses, directions and Bragg curves of registered fission fragments. Total statistics of a few million fission events were collected during each experiment. It was discovered that for several combinations of fission fragment masses their total kinetic energy was very close to total free energy of the fissioning system. The probability of such fission events for the fast neutron induced fission was found to be much higher than for spontaneous fission of 252Cf and thermal neutron induced fission of 235U. For experiments with 238U target the energy of incident neutrons were 5 MeV and 6.5 MeV. Close analysis of dependence of fission fragment distribution on compound nucleus excitation energy gave us some explanation of the phenomenon. It could be a process in highly excited compound nucleus which leads the fissioning system from the scission point into the fusion valley with high probability.

  7. Investigation of the heavy nuclei fission with anomalously high values of the fission fragments total kinetic energy

    Directory of Open Access Journals (Sweden)

    Khryachkov Vitaly

    2018-01-01

    Full Text Available Binary fission of 232Th and 238U induced by fast neutrons were under intent investigation in the IPPE during recent years. These measurements were performed with a twin ionization chamber with Frisch grids. Signals from the detector were digitized for further processing with a specially developed software. It results in information of kinetic energies, masses, directions and Bragg curves of registered fission fragments. Total statistics of a few million fission events were collected during each experiment. It was discovered that for several combinations of fission fragment masses their total kinetic energy was very close to total free energy of the fissioning system. The probability of such fission events for the fast neutron induced fission was found to be much higher than for spontaneous fission of 252Cf and thermal neutron induced fission of 235U. For experiments with 238U target the energy of incident neutrons were 5 MeV and 6.5 MeV. Close analysis of dependence of fission fragment distribution on compound nucleus excitation energy gave us some explanation of the phenomenon. It could be a process in highly excited compound nucleus which leads the fissioning system from the scission point into the fusion valley with high probability.

  8. Kinetic energy definition in velocity Verlet integration for accurate pressure evaluation.

    Science.gov (United States)

    Jung, Jaewoon; Kobayashi, Chigusa; Sugita, Yuji

    2018-04-28

    In molecular dynamics (MD) simulations, a proper definition of kinetic energy is essential for controlling pressure as well as temperature in the isothermal-isobaric condition. The virial theorem provides an equation that connects the average kinetic energy with the product of particle coordinate and force. In this paper, we show that the theorem is satisfied in MD simulations with a larger time step and holonomic constraints of bonds, only when a proper definition of kinetic energy is used. We provide a novel definition of kinetic energy, which is calculated from velocities at the half-time steps (t - Δt/2 and t + Δt/2) in the velocity Verlet integration method. MD simulations of a 1,2-dispalmitoyl-sn-phosphatidylcholine (DPPC) lipid bilayer and a water box using the kinetic energy definition could reproduce the physical properties in the isothermal-isobaric condition properly. We also develop a multiple time step (MTS) integration scheme with the kinetic energy definition. MD simulations with the MTS integration for the DPPC and water box systems provided the same quantities as the velocity Verlet integration method, even when the thermostat and barostat are updated less frequently.

  9. Generalizing a unified model of dark matter, dark energy, and inflation with a noncanonical kinetic term

    International Nuclear Information System (INIS)

    De-Santiago, Josue; Cervantes-Cota, Jorge L.

    2011-01-01

    We study a unification model for dark energy, dark matter, and inflation with a single scalar field with noncanonical kinetic term. In this model, the kinetic term of the Lagrangian accounts for the dark matter and dark energy, and at early epochs, a quadratic potential accounts for slow roll inflation. The present work is an extension to the work by Bose and Majumdar [Phys. Rev. D 79, 103517 (2009).] with a more general kinetic term that was proposed by Chimento in Phys. Rev. D 69, 123517 (2004). We demonstrate that the model is viable at the background and linear perturbation levels.

  10. Investigating the Interdependencies of the Energy Balance Closure and the Turbulent Kinetic Energy Budget.

    Science.gov (United States)

    Banerjee, T.; Zeeman, M. J.; De Roo, F.; Brugger, P.; Mauder, M.

    2016-12-01

    The energy balance residual (EBR), defined as the difference between the available energy (sum of net radiation and ground heat flux) and the turbulent fluxes of latent and sensible heat, is often found to have a large positive value. Several land surface experiments and flux networks report an average energy balance closure of approximately 80%. Although different factors can influence the energy balance closure across measurement campaigns, a significant EBR even when sites are horizontally with short canopies indicates of a systematic bias resulting from the general underestimation of the aerodynamic transport of energy, especially horizontal divergence of the mean advective fluxes and transport by low-frequency motions generally called `secondary circulations'. These low frequency local transports can occur from various processes such as coherent large scale organized motions, convective cells and even significant transient changes. Thus, we decided to study the budget of the turbulent kinetic energy (TKE) in conjunction with the energy balance closure. In the current work, this interdependency has been investigated using surface flux (Eddy Covariance) and remote sensing based measurements (triple 3d Doppler LiDAR, thermal imagery) from the ScaleX campaigns at the TERENO pre-alpine observatory Fendt in Southern Germany (with gentle topography), coupled with large eddy simulations (LES). Statistical methods ranging from dimensional reduction techniques to information theory has been used to extract the effects and significance of aforementioned processes towards explaining the observed annual average EBR of about 50 Wm-2. Initial results indicate a high correlation between EBR and the TKE dissipation rate, as well as the skewness of vertical velocity, confirming the role of secondary circulations. The role of transport and the advection terms will also be investigated. Overall, improved understanding of such connections between the fundamental mechanisms of TKE

  11. Work fluctuation theorems and free energy from kinetic theory

    Science.gov (United States)

    Brey, J. Javier; Ruiz-Montero, M. J.; Domínguez, Álvaro

    2018-01-01

    The formulation of the first and second principles of thermodynamics for a particle in contact with a heat bath and submitted to an external force is analyzed, by means of the Boltzmann-Lorentz kinetic equation. The possible definitions of the thermodynamic quantities are discussed in the light of the H theorem verified by the distribution of the particle. The work fluctuation relations formulated by Bochkov and Kuzovlev, and by Jarzynski, respectively, are derived from the kinetic equation. In addition, particle simulations using both the direct simulation Monte Carlo method and molecular dynamics, are used to investigate the practical accuracy of the results. Work distributions are also measured, and they turn out to be rather complex. On the other hand, they seem to depend very little, if any, on the interaction potential between the intruder and the bath.

  12. Incident energy dependence of scattering behavior of water molecules on Si (100) and graphite surfaces

    Science.gov (United States)

    Kihara, G.; Kotsubo, Y.; Yoshimoto, Y.; Kinefuchi, I.; Takagi, S.

    2016-11-01

    The interaction between water molecules and solid surfaces has a great impact on water vapor flows in nanostructures. We conduct molecular beam scattering experiments covering the incident energy range corresponding to the thermal energy at room temperature to investigate the scattering behavior of water molecules on silicon and graphite surfaces. The incident energy dependence of the scattering distributions exhibits opposite trends on these surfaces. Molecular dynamics simulations reveal that the difference is caused by the inertia effect of the incident molecules and the surface corrugations.

  13. The kinetic energy contribution U( ρ) to the potential energy in the Hougen-Bunker-Johns Hamiltonian

    Science.gov (United States)

    Sarka, K.; Bunker, P. R.

    1987-04-01

    The pseudo potential energy term U( ρ) obtained from the kinetic energy term of the Hougen-Bunker-Johns (HBJ) rotation-vibration Hamiltonian has been obtained in general to order of magnitude κ2Tv. The expression obtained is relatively easy to evaluate and should be used in any semirigid bender or nonrigid bender Hamiltonian that is derived from the HBJ Hamiltonian.

  14. Bounds on poloidal kinetic energy in plane layer convection

    Science.gov (United States)

    Tilgner, A.

    2017-12-01

    A numerical method is presented that conveniently computes upper bounds on heat transport and poloidal energy in plane layer convection for infinite and finite Prandtl numbers. The bounds obtained for the heat transport coincide with earlier results. These bounds imply upper bounds for the poloidal energy, which follow directly from the definitions of dissipation and energy. The same constraints used for computing upper bounds on the heat transport lead to improved bounds for the poloidal energy.

  15. Modeling on the Effect of Coal Loads on Kinetic Energy of Balls for Ball Mills

    Directory of Open Access Journals (Sweden)

    Yan Bai

    2015-07-01

    Full Text Available This paper presents a solution for the detection and control of coal loads that is more accurate and convenient than those currently used. To date, no research has addressed the use of a grinding medium as the controlled parameter. To improve the accuracy of the coal load detection based on the kinetic energy of balls in a tubular ball mill, a Discrete Element Method (DEM model for ball kinematics based on coal loads is proposed. The operating process for a ball mill and the ball motion, as influenced by the coal quality and the coal load, was analyzed carefully. The relationship between the operating efficiency of a coal pulverizing system, coal loads, and the balls’ kinetic energy was obtained. Origin and Matlab were utilized to draw the variation of parameters with increasing coal loads in the projectile and cascading motion states. The parameters include the balls’ real-time kinetic energy, the friction energy consumption, and the mill’s total work. Meanwhile, a method of balanced adjacent degree and a physical experiment were proposed to verify the considerable effect of the balls’ kinetic energy on coal loads. The model and experiment results indicate that a coal load control method based on the balls’ kinetic energy is therefore feasible for the optimized operation of a coal pulverizing system.

  16. Fission Fragment Mass Distributions and Total Kinetic Energy Release of 235-Uranium and 238-Uranium in Neutron-Induced Fission at Intermediate and Fast Neutron Energies

    Energy Technology Data Exchange (ETDEWEB)

    Duke, Dana Lynn [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-11-12

    This Ph.D. dissertation describes a measurement of the change in mass distributions and average total kinetic energy (TKE) release with increasing incident neutron energy for fission of 235U and 238U. Although fission was discovered over seventy-five years ago, open questions remain about the physics of the fission process. The energy of the incident neutron, En, changes the division of energy release in the resulting fission fragments, however, the details of energy partitioning remain ambiguous because the nucleus is a many-body quantum system. Creating a full theoretical model is difficult and experimental data to validate existing models are lacking. Additional fission measurements will lead to higher-quality models of the fission process, therefore improving applications such as the development of next-generation nuclear reactors and defense. This work also paves the way for precision experiments such as the Time Projection Chamber (TPC) for fission cross section measurements and the Spectrometer for Ion Determination in Fission (SPIDER) for precision mass yields.

  17. Electronic kinetic energy decrease as two metallic parallel C nanotubes are brought together from infinity

    International Nuclear Information System (INIS)

    March, Norman H.; Rubio, Angel

    2006-01-01

    By utilising the virial theorem, an expression is derived from the recent work of Dobson et al. for the initial decrease of electronic kinetic energy as two metallic parallel C nanotubes of equal diameter are brought together from infinity to a (still large) separation. To yield the dispersion energy proposed by Dobson et al. [J.F. Dobson, A. White, A. Rubio, Phys. Rev. Lett. 96 (2006) 073201], it is shown that it is the initial drop in the kinetic energy that is responsible for the long-range attractive interaction

  18. Energy Reflection from Gold Bombarded with keV Protons at Various Angles of Incidence

    DEFF Research Database (Denmark)

    Sørensen, H.

    1976-01-01

    The calorimetric deuterium film method operating at liquid‐helium temperature was used for measuring the energy reflection coefficient γ for 1–10‐keV protons incident on gold at angles of incidence up to 75°. H+2 and H+3 ions were used to obtain the lowest velocities. The growth with angle...

  19. Numerical Simulations of the Kinetic Energy Transfer in the Bath of a BOF Converter

    Science.gov (United States)

    Zhou, Xiaobin; Ersson, Mikael; Zhong, Liangcai; Jönsson, Pär

    2016-02-01

    The paper focuses on the fundamental aspects of the kinetic energy transfer from a top and bottom gas injection to the bath of the basic oxygen furnace (BOF) by applying a mathematical model. The analyses revealed that the energy transfer is less efficient when top lance height is lowered or the flowrate is increased in the top blowing operations. However, an inverse trend was found that the kinetic energy transfer is increased when the bottom flowrate is increased for the current bottom blowing operation conditions. The kinetic energy transfer index results indicated that the energy transfer for the bottom blowing is much more efficient than that of the top blowing operations. To understand the effects of the upper buoyant phase on the energy dissipation of the bulk liquid in the bath, different mass and physical properties of slag and foam were considered in the bottom blowing simulations. The slag on top of the bath is found to dissipate by 6.6, 9.4, and 11.2 pct for slag mass values of 5, 9, and 15 t compared to the case without slag atop the surface of the bath, respectively. The results showed that the kinetic energy transfer is not largely influenced by the viscosity of the upper slag or the foaming phases.

  20. Kinetic Kaleidoscope: Exploring Movement and Energy in the Visual Arts.

    Science.gov (United States)

    Herman, Gail Neary; Hollingsworth, Patricia

    Works of visual art contain an inner dynamism and energy that an individual's perceptual apparatus can translate into kinesthetic impressions, movement, and sound. Through this translation, a child's natural energies can interact with the artwork through multiple sensory experiences, enriching art appreciation. After a brief examination of the…

  1. Assessment of Kinetic Tidal Energy Resources Using SELFE

    Directory of Open Access Journals (Sweden)

    Manasa Ranjan Behera

    2014-09-01

    Full Text Available An investigation is carried out to study the theoretical tidal stream energy resource in the Singapore Strait to support the search for renewable energy in the effort to reduce the carbon footprints in the Southeast Asia. The tidal hydrodynamics in the Singapore Strait has been simulated using a Semi-implicit Eulerian-Lagrangian Finite-Element (SELFE model solving the 3D shallow water equations with Boussinesq approximations. Potential sites, with high tidal current (2.5 m/s and suitable for Tidal Energy Converter (TEC array installation to generate sustainable energy, have been identified. Further, various operational factors for installation of Tidal Energy Converters are considered before computing the theoretical power output for a typical TEC array. An approximate estimation of the possible theoretical power extraction from a TEC array shows an energy potential of up to 4.36% of the total energy demand of Singapore in 2011. Thus, the study suggests a detailed investigation of potential sites to quantify the total tidal stream energy potential in the Singapore Strait.

  2. FOR N+ 56Fe REACTION AROUND INCIDENT ENERGIES OF

    African Journals Online (AJOL)

    Cross section calculations have been carried out by some earlier scientists independent of energy surface imaginary potential. These have been characterized by a lot of disparity between authors and literature values. In this work, special attention was devoted to the increase in the accuracy of the calculation of nuclear ...

  3. Dynamic force spectroscopy of DNA hairpins: I. Force kinetics and free energy landscapes

    International Nuclear Information System (INIS)

    Mossa, A; Manosas, M; Forns, N; Huguet, J M; Ritort, F

    2009-01-01

    We investigate the thermodynamics and kinetics of DNA hairpins that fold/unfold under the action of applied mechanical force. We introduce the concept of the molecular free energy landscape and derive simplified expressions for the force dependent Kramers–Bell rates. To test the theory we have designed a specific DNA hairpin sequence that shows two-state cooperative folding under mechanical tension and carried out pulling experiments using optical tweezers. We show how we can determine the parameters that characterize the molecular free energy landscape of such sequences from rupture force kinetic studies. Finally we combine such kinetic studies with experimental investigations of the Crooks fluctuation relation to derive the free energy of formation of the hairpin at zero force

  4. Efficiency and Optimality of 2-period Gait from Kinetic Energy Point of View

    Science.gov (United States)

    Asano, Fumihiko

    This paper investigates the efficiency of a 2-period limit-cycle gait from the kinetic energy viewpoint. First, we formulate a steady 2-period gait by using simple recurrence formulas for the kinetic energy of an asymmetric rimless wheel. Second, we theoretically show that, in the case that the mean value of the hip angle is constant, the generated 2-period steady gait is less efficient than a 1-period symmetric one in terms of kinetic energy. Furthermore, we show that the symmetric gait is not always optimal from another viewpoint. Finally, we investigate the validity of the derived theory through numerical simulations of virtual passive dynamic walking using a compass-like biped robot.

  5. On the estimation of cooperativity in ion channel kinetics: activation free energy and kinetic mechanism of Shaker K+ channel.

    Science.gov (United States)

    Banerjee, Kinshuk; Das, Biswajit; Gangopadhyay, Gautam

    2013-04-28

    In this paper, we have explored generic criteria of cooperative behavior in ion channel kinetics treating it on the same footing with multistate receptor-ligand binding in a compact theoretical framework. We have shown that the characterization of cooperativity of ion channels in terms of the Hill coefficient violates the standard Hill criteria defined for allosteric cooperativity of ligand binding. To resolve the issue, an alternative measure of cooperativity is proposed here in terms of the cooperativity index that sets a unified criteria for both the systems. More importantly, for ion channel this index can be very useful to describe the cooperative kinetics as it can be readily determined from the experimentally measured ionic current combined with theoretical modelling. We have analyzed the correlation between the voltage value and slope of the voltage-activation curve at the half-activation point and consequently determined the standard free energy of activation of the ion channel using two well-established mechanisms of cooperativity, namely, Koshland-Nemethy-Filmer (KNF) and Monod-Wyman-Changeux (MWC) models. Comparison of the theoretical results for both the models with appropriate experimental data of mutational perturbation of Shaker K(+) channel supports the experimental fact that the KNF model is more suitable to describe the cooperative behavior of this class of ion channels, whereas the performance of the MWC model is unsatisfactory. We have also estimated the mechanistic performance through standard free energy of channel activation for both the models and proposed a possible functional disadvantage in the MWC scheme.

  6. Numerical simulation and decomposition of kinetic energy in the Central Mediterranean: insight on mesoscale circulation and energy conversion

    Directory of Open Access Journals (Sweden)

    R. Sorgente

    2011-08-01

    Full Text Available The spatial and temporal variability of eddy and mean kinetic energy of the Central Mediterranean region has been investigated, from January 2008 to December 2010, by mean of a numerical simulation mainly to quantify the mesoscale dynamics and their relationships with physical forcing. In order to understand the energy redistribution processes, the baroclinic energy conversion has been analysed, suggesting hypotheses about the drivers of the mesoscale activity in this area. The ocean model used is based on the Princeton Ocean Model implemented at 1/32° horizontal resolution. Surface momentum and buoyancy fluxes are interactively computed by mean of standard bulk formulae using predicted model Sea Surface Temperature and atmospheric variables provided by the European Centre for Medium Range Weather Forecast operational analyses. At its lateral boundaries the model is one-way nested within the Mediterranean Forecasting System operational products.

    The model domain has been subdivided in four sub-regions: Sardinia channel and southern Tyrrhenian Sea, Sicily channel, eastern Tunisian shelf and Libyan Sea. Temporal evolution of eddy and mean kinetic energy has been analysed, on each of the four sub-regions, showing different behaviours. On annual scales and within the first 5 m depth, the eddy kinetic energy represents approximately the 60 % of the total kinetic energy over the whole domain, confirming the strong mesoscale nature of the surface current flows in this area. The analyses show that the model well reproduces the path and the temporal behaviour of the main known sub-basin circulation features. New mesoscale structures have been also identified, from numerical results and direct observations, for the first time as the Pantelleria Vortex and the Medina Gyre.

    The classical kinetic energy decomposition (eddy and mean allowed to depict and to quantify the permanent and fluctuating parts of the circulation in the region, and

  7. Neutron emission effects on final fragments mass and kinetic energy distribution from low energy fission of {sup 234}U

    Energy Technology Data Exchange (ETDEWEB)

    Montoya, M.; Rojas, J. [Instituto Peruano de Energia Nuclear, Av. Canada 1470, Lima 41 (Peru); Lobato, I. [Facultad de Ciencias, Universidad Nacional de Ingenieria, Av. Tupac Amaru 210, Apartado Postal 31-139, Lima (Peru)]. e-mail: mmontoya@ipen.gob.pe

    2008-07-01

    The standard deviation of the final kinetic energy distribution ({sigma}{sub e}) as a function of mass of final fragments (m) from low energy fission of {sup 234}U, measured with the Lohengrin spectrometer by Belhafaf et al., presents a peak around m = 109 and another around m = 122. The authors attribute the first peak to the evaporation of a large number of neutrons around the corresponding mass number, i.e. there is no peak on the standard deviation of the primary kinetic energy distribution ({sigma}{sub E}) as a function of primary fragment mass (A). The second peak is attributed to a real peak on {sigma}{sub E}(A). However, theoretical calculations related to primary distributions made by H.R. Faust and Z. Bao do not suggest any peak on {sigma}{sub E}(A). In order to clarify this apparent controversy, we have made a numerical experiment in which the masses and the kinetic energy of final fragments are calculated, assuming an initial distribution of the kinetic energy without structures on the standard deviation as function of fragment mass. As a result we obtain a pronounced peak on {sigma}{sub e} (m) curve around m = 109, a depletion from m = 121 to m = 129, and an small peak around m = 122, which is not as great as that measured by Belhafaf et al. Our simulation also reproduces the experimental results on the yield of the final mass Y(m), the average number of emitted neutrons as a function of the provisional mass (calculated from the values of the final kinetic energy of the complementary fragments) and the average value of fragment kinetic energy as a function of the final mass. From our results we conclude that there are no peaks on the {sigma}{sub E} (A) curve, and the observed peaks on {sigma}{sub e} (m) are due to the emitted neutron multiplicity and the variation of the average fragment kinetic energy as a function of primary fragment mass. (Author)

  8. Dependence of ECH deposition profile on the modeling of incident wave energy

    International Nuclear Information System (INIS)

    Kritz, A.H.; Hsuan, H.; Matsuda, K.

    1986-06-01

    The ray tracing code, TORAY, is used to investigate the importance of modeling assumptions utilized in describing Electron Cyclotron Heating (ECH). In particular, we examine the dependence of the ECH deposition profile on the antenna pattern. We demonstrate that different assumptions for representing the incident wave energy by a finite number of rays lead to significantly different results for the energy deposition profile

  9. Bio-kinetic energy harvesting using electroactive polymers

    Science.gov (United States)

    Slade, Jeremiah R.; Bowman, Jeremy; Kornbluh, Roy

    2012-06-01

    In hybrid vehicles, electric motors are used on each wheel to not only propel the car but also to decelerate the car by acting as generators. In the case of the human body, muscles spend about half of their time acting as a brake, absorbing energy, or doing what is known as negative work. Using dielectric elastomers it is possible to use the "braking" phases of walking to generate power without restricting or fatiguing the Warfighter. Infoscitex and SRI have developed and demonstrated methods for using electroactive polymers (EAPs) to tap into the negative work generated at the knee during the deceleration phase of the human gait cycle and convert it into electrical power that can be used to support wearable information systems, including display and communication technologies. The specific class of EAP that has been selected for these applications is termed dielectric elastomers. Because dielectric elastomers dissipate very little mechanical energy into heat, greater amounts of energy can be converted into electricity than by any other method. The long term vision of this concept is to have EAP energy harvesting cells located in components of the Warfighter ensemble, such as the boot uppers, knee pads and eventually even the clothing itself. By properly locating EAPs at these sites it will be possible to not only harvest power from the negative work phase but to actually reduce the amount of work done by the Warfighter's muscles during this phase, thereby reducing fatigue and minimizing the forces transmitted to the joints.

  10. FLYWHEEL BASED KINETIC ENERGY RECOVERY SYSTEMS (KERS) INTEGRATED IN VEHICLES

    OpenAIRE

    THOMAS MATHEWS; NISHANTH D

    2013-01-01

    Today, many hybrid electric vehicles have been developed in order to reduce the consumption of fossil fuels; unfortunately these vehicles require electrochemical batteries to store energy, with high costs as well as poor conversion efficiencies. By integrating flywheel hybrid systems, these drawbacks can be overcome and can potentially replace battery powered hybrid vehicles cost effectively. The paper will explain the engineering, mechanics of the flywheel system and it’s working in detail. ...

  11. Balance of liquid-phase turbulence kinetic energy equation for bubble-train flow

    International Nuclear Information System (INIS)

    Ilic, Milica; Woerner, Martin; Cacuci, Dan Gabriel

    2004-01-01

    In this paper the investigation of bubble-induced turbulence using direct numerical simulation (DNS) of bubbly two-phase flow is reported. DNS computations are performed for a bubble-driven liquid motion induced by a regular train of ellipsoidal bubbles rising through an initially stagnant liquid within a plane vertical channel. DNS data are used to evaluate balance terms in the balance equation for the liquid phase turbulence kinetic energy. The evaluation comprises single-phase-like terms (diffusion, dissipation and production) as well as the interfacial term. Special emphasis is placed on the procedure for evaluation of interfacial quantities. Quantitative analysis of the balance equation for the liquid phase turbulence kinetic energy shows the importance of the interfacial term which is the only source term. The DNS results are further used to validate closure assumptions employed in modelling of the liquid phase turbulence kinetic energy transport in gas-liquid bubbly flows. In this context, the performance of respective closure relations in the transport equation for liquid turbulence kinetic energy within the two-phase k-ε and the two-phase k-l model is evaluated. (author)

  12. A Kinetic Study of Marginal Soil Energy Plant Helianthus annuus Stalk Pyrolysis

    Directory of Open Access Journals (Sweden)

    Huaxiao Yan

    2013-01-01

    Full Text Available The pyrolytic characteristics and kinetics of new marginal soil energy plant Helianthus annuus stalk were investigated using thermogravimetric (TG method from 50 to 800°C in an inert argon atmosphere at different heating rates of 5, 10, 20, and 30°C min−1. The kinetic parameters of activation energy and pre-exponential factor were deduced by Popescu, Flynn-Wall-Ozawa (FWO, and Kissinger-Akahira-Sunose (KAS methods, respectively. The results showed that three stages appeared in the thermal degradation process. The primary devolatilization stage of H. annuus stalk can be described by the Avrami-Erofeev function (n=4. The average activation energy of H. annuus stalk was only 142.9 kJ mol−1. There were minor kinetic compensation effects between the pre-exponential factor and the activation energy. The results suggest that H. annuus stalk is suitable for pyrolysis, and more importantly, the experimental results and kinetic parameters provided useful information for the design of pyrolytic processing system using H. annuus stalk as feedstock.

  13. Kinetic energy and added mass of hydrodynamically interacting gas bubbles in liquid

    NARCIS (Netherlands)

    Kok, Jacobus B.W.

    1988-01-01

    By averaging the basic equations on microscale, expressions are derived for the effective added mass density and the kinetic energy density of a mixture of liquid and gas bubbles. Due to hydrodynamic interaction between the bubbles there appears to be a difference between the effective added mass

  14. Employing Magnetic Levitation to Monitor Reaction Kinetics and Measure Activation Energy

    Science.gov (United States)

    Benz, Lauren; Cesafsky, Karen E.; Le, Tran; Park, Aileen; Malicky, David

    2012-01-01

    This article describes a simple and inexpensive undergraduate-level kinetics experiment that uses magnetic levitation to monitor the progress and determine the activation energy of a condensation reaction on a polymeric solid support. The method employs a cuvette filled with a paramagnetic solution positioned between two strong magnets. The…

  15. Kinetic Energy from Supernova Feedback in High-resolution Galaxy Simulations

    Science.gov (United States)

    Simpson, Christine M.; Bryan, Greg L.; Hummels, Cameron; Ostriker, Jeremiah P.

    2015-08-01

    We describe a new method for adding a prescribed amount of kinetic energy to simulated gas modeled on a cartesian grid by directly altering grid cells’ mass and velocity in a distributed fashion. The method is explored in the context of supernova (SN) feedback in high-resolution (˜10 pc) hydrodynamic simulations of galaxy formation. Resolution dependence is a primary consideration in our application of the method, and simulations of isolated explosions (performed at different resolutions) motivate a resolution-dependent scaling for the injected fraction of kinetic energy that we apply in cosmological simulations of a 109 M⊙ dwarf halo. We find that in high-density media (≳50 cm-3) with coarse resolution (≳4 pc per cell), results are sensitive to the initial kinetic energy fraction due to early and rapid cooling. In our galaxy simulations, the deposition of small amounts of SN energy in kinetic form (as little as 1%) has a dramatic impact on the evolution of the system, resulting in an order-of-magnitude suppression of stellar mass. The overall behavior of the galaxy in the two highest resolution simulations we perform appears to converge. We discuss the resulting distribution of stellar metallicities, an observable sensitive to galactic wind properties, and find that while the new method demonstrates increased agreement with observed systems, significant discrepancies remain, likely due to simplistic assumptions that neglect contributions from SNe Ia and stellar winds.

  16. Effect of microwave-assisted heating on chalcopyrite leaching of kinetics, interface temperature and surface energy

    Directory of Open Access Journals (Sweden)

    Tong Wen

    Full Text Available The microwave-assisted leaching was a new approach to intensify the copper recovery from chalcopyrite by hydrometallurgy. In this work, the effect of microwave-assisted heating on chalcopyrite leaching of kinetics, interfacial reaction temperature and surface energy were investigated. The activation energy of chalcopyrite leaching was affected indistinctively by the microwave-assisted heating (39.1 kJ/mol compared with the conventional heating (43.9 kJ/mol. However, the boiling point of the leaching system increased through microwave-assisted heating. Because of the improved boiling point and the selective heating of microwave, the interfacial reaction temperature increased significantly, which gave rise to the increase of the leaching recovery of copper. Moreover, the surface energy of the chalcopyrite through microwave-assisted heating was also enhanced, which was beneficial to strengthen the leaching of chalcopyrite. Keywords: Microwave-assisted heating, Chalcopyrite, Leaching kinetics, Interface temperature, Surface energy

  17. Cost-effectiveness and incidence of renewable energy promotion in Germany

    Energy Technology Data Exchange (ETDEWEB)

    Boehringer, Christoph [Oldenburg Univ. (Germany). Dept. of Economics; Landis, Florian [Eidgenoessische Technische Hochschule, Zurich (Switzerland); Tovar Reanos, Miguel Angel [Zentrum fuer Europaeische Wirtschaftsforschung GmbH (ZEW), Mannheim (Germany)

    2017-08-01

    Over the last decade Germany has boosted renewable energy in power production by means of massive subsidies. The flip side are very high electricity prices which raises concerns that the transition cost towards a renewable energy system will be mainly borne by poor households. In this paper, we combine computable general equilibrium and microsimulation analysis to investigate the cost-effectiveness and incidence of Germany's renewable energy promotion. We find that the regressive effects of renewable energy promotion could be ameliorated by alternative subsidy financing mechanisms which achieve the same level of electricity generation from renewable energy sources.

  18. Statistical properties of kinetic and total energy densities in reverberant spaces

    DEFF Research Database (Denmark)

    Jacobsen, Finn; Molares, Alfonso Rodriguez

    2010-01-01

    Many acoustical measurements, e.g., measurement of sound power and transmission loss, rely on determining the total sound energy in a reverberation room. The total energy is usually approximated by measuring the mean-square pressure (i.e., the potential energy density) at a number of discrete....... With the advent of a three-dimensional particle velocity transducer, it has become somewhat easier to measure total rather than only potential energy density in a sound field. This paper examines the ensemble statistics of kinetic and total sound energy densities in reverberant enclosures theoretically...... positions. The idea of measuring the total energy density instead of the potential energy density on the assumption that the former quantity varies less with position than the latter goes back to the 1930s. However, the phenomenon was not analyzed until the late 1970s and then only for the region of high...

  19. Buoyant production and consumption of turbulence kinetic energy in cloud-topped mixed layers

    Science.gov (United States)

    Randall, D. A.

    1984-01-01

    It is pointed out that studies of the entraining planetary boundary layer (PBL) have generally emphasized the role of buoyancy fluxes in driving entrainment. The buoyancy flux is proportional to the rate of conversion of the potential energy of the mean flow into the kinetic energy of the turbulence. It is not unusual for conversion to proceed in both directions simultaneously. This occurs, for instance, in both clear and cloudy convective mixed layers which are capped by inversions. A partitioning of the net conversion into positive parts, generating turbulence kinetic energy (TKE), and negative parts (TKE-consuming), would make it possible to include the positive part in the gross production rate, and closure would be achieved. Three different approaches to partitioning have been proposed. The present investigation is concerned with a comparison of the three partitioning theories. Particular attention is given to the cloud-topped mixed layer because in this case the differences between two partitioning approaches are most apparent.

  20. Fission fragment mass and total kinetic energy distributions of spontaneously fissioning plutonium isotopes

    Science.gov (United States)

    Pomorski, K.; Nerlo-Pomorska, B.; Bartel, J.; Schmitt, C.

    2018-03-01

    The fission-fragment mass and total kinetic energy (TKE) distributions are evaluated in a quantum mechanical framework using elongation, mass asymmetry, neck degree of freedom as the relevant collective parameters in the Fourier shape parametrization recently developed by us. The potential energy surfaces (PES) are calculated within the macroscopic-microscopic model based on the Lublin-Strasbourg Drop (LSD), the Yukawa-folded (YF) single-particle potential and a monopole pairing force. The PES are presented and analysed in detail for even-even Plutonium isotopes with A = 236-246. They reveal deep asymmetric valleys. The fission-fragment mass and TKE distributions are obtained from the ground state of a collective Hamiltonian computed within the Born-Oppenheimer approximation, in the WKB approach by introducing a neck-dependent fission probability. The calculated mass and total kinetic energy distributions are found in good agreement with the data.

  1. Kinetic energy of throughfall in a highly diverse forest ecosystem in the humid subtropics

    Science.gov (United States)

    Geißler, Christian; Kühn, Peter; Scholten, Thomas

    2010-05-01

    After decades of research it is generally accepted that vegetation is a key factor in controlling soil erosion. Therefore, in ecosystems where erosion is a serious problem, afforestation is a common measure against erosion. Most of the studies in the last decades focused on agricultural systems and less attention was paid to natural systems. To understand the mechanisms preventing soil erosion in natural systems the processes have to be studied in detail and gradually. The first step and central research question is on how the canopies of the tree layer alter the properties of rainfall and generate throughfall. Kinetic energy is a widely used parameter to estimate the erosion potential of open field rainfall and throughfall. In the past, numerous studies have shown that vegetation of a certain height enhances the kinetic energy under the canopy (Chapman 1948, Mosley 1982, Vis 1986, Hall & Calder 1993, Nanko et al. 2006, Nanko et al. 2008) in relation to open field rainfall. This is mainly due to a shift in the drop size distribution to less but larger drops possessing a higher amount of kinetic energy. In vital forest ecosystems lower vegetation (shrubs, herbs) as well as a continuous litter layer protects the forest soil from the impact of large drops. The influence of biodiversity, specific forest stands or single species in this process system is still in discussion. In the present study calibrated splash cups (after Ellison 1947, Geißler et al. under review) have been used to detect differences in kinetic energy on the scale of specific species and on the scale of forest stands of contrasting age and biodiversity in a natural forest ecosystem. The splash cups have been calibrated experimentally using a laser disdrometer. The results show that the kinetic energy of throughfall produced by the tree layer increases with the age of the specific forest stand. The average throughfall kinetic energy (J m-2) is about 2.6 times higher in forests than under open field

  2. Solving many-body Schrödinger equations with kinetic energy partition method

    Science.gov (United States)

    Chen, Yu-Hsin; Chao, Sheng D.

    2018-01-01

    We present a general formulation of our previously developed kinetic energy partition (KEP) method for solving many-bodySchrödinger equations. In atomic physics, as well as in general molecular and solid state physics, solving many-electronSchrödinger equations is a very challenging task, often called Dirac's challenge. The central problem is how to properly handle the electron-electron Coulomb repulsion interactions. Using the KEP solution scheme, in addition to dividing the kinetic energy into partial terms, the electron-electron Coulomb interaction is also separated into parts to be associated with a "negative mass" kinetic energy term. Therefore, the full Hamiltonian can be expressed as a simple sum of subsystem Hamiltonians, each representing an effective one-body problem. Using a Hartree-like product in constructing the wave-function, we achieve fast convergence in the calculations of the ground state energies. First, the model Moshinsky atoms are used to illustrate the solution procedure. We then apply this new KEP method to harmonium atoms and obtain precise energies with an error less than 5% using only two basis functions from each subsystem. It is thus very promising that this methodology, when further extended, can be useful for general many-body systems.

  3. Rock Cutting Depth Model Based on Kinetic Energy of Abrasive Waterjet

    Science.gov (United States)

    Oh, Tae-Min; Cho, Gye-Chun

    2016-03-01

    Abrasive waterjets are widely used in the fields of civil and mechanical engineering for cutting a great variety of hard materials including rocks, metals, and other materials. Cutting depth is an important index to estimate operating time and cost, but it is very difficult to predict because there are a number of influential variables (e.g., energy, geometry, material, and nozzle system parameters). In this study, the cutting depth is correlated to the maximum kinetic energy expressed in terms of energy (i.e., water pressure, water flow rate, abrasive feed rate, and traverse speed), geometry (i.e., standoff distance), material (i.e., α and β), and nozzle system parameters (i.e., nozzle size, shape, and jet diffusion level). The maximum kinetic energy cutting depth model is verified with experimental test data that are obtained using one type of hard granite specimen for various parameters. The results show a unique curve for a specific rock type in a power function between cutting depth and maximum kinetic energy. The cutting depth model developed here can be very useful for estimating the process time when cutting rock using an abrasive waterjet.

  4. Photodissociation dynamics of propene at 157.6 nm: Kinetic energy distributions and branching ratios

    International Nuclear Information System (INIS)

    Lee, S.-H.; Lee, Y.-Y.; Lee, Yuan T.; Yang Xueming

    2003-01-01

    Photodissociation dynamics of propene at 157.6 nm has been investigated in a molecular beam apparatus using the photofragment translational spectroscopic technique combined with the vacuum ultraviolet ionization method. Eleven photofragments have been successfully detected and ascribed to eight (five binary and three triple) dissociation channels: namely, C 3 H 5 +H, C 3 H 4 +H+H, C 3 H 4 +H 2 , C 3 H 3 +H 2 +H, C 2 H 4 +CH 2 , C 2 H 3 +CH 3 , C 2 H 2 +CH 4 , and C 2 H 2 +CH 3 +H. Their branching ratios have been determined to be 1%, 7%, 2 H 2 +CH 3 +H channel. In addition, the averaged kinetic energy releases and the fractions in translational energy have also been determined from the measured kinetic energy distributions. For the binary dissociation channels, the fractions in translational energy are less than 18% except the C 3 H 5 +H channel, whereas they are more than 42% for the triple dissociation channels. An intriguing finding indicates that the C 2 H 4 +CH 2 channel has a nearly identical kinetic energy distribution and a similar branching ratio to the C 2 H 3 +CH 3 channel, although the former undergoes a three-center elimination process different from the C-C bond rupture occurring in the latter

  5. Statistical model of a flexible inextensible polymer chain: The effect of kinetic energy

    Science.gov (United States)

    Pergamenshchik, V. M.; Vozniak, A. B.

    2017-01-01

    Because of the holonomic constraints, the kinetic energy contribution in the partition function of an inextensible polymer chain is difficult to find, and it has been systematically ignored. We present the first thermodynamic calculation incorporating the kinetic energy of an inextensible polymer chain with the bending energy. To explore the effect of the translation-rotation degrees of freedom, we propose and solve a statistical model of a fully flexible chain of N +1 linked beads which, in the limit of smooth bending, is equivalent to the well-known wormlike chain model. The partition function with the kinetic and bending energies and correlations between orientations of any pair of links and velocities of any pair of beads are found. This solution is precise in the limits of small and large rigidity-to-temperature ratio b /T . The last exact solution is essential as even very "harmless" approximation results in loss of the important effects when the chain is very rigid. For very high b /T , the orientations of different links become fully correlated. Nevertheless, the chain does not go over into a hard rod even in the limit b /T →∞ : While the velocity correlation length diverges, the correlations themselves remain weak and tend to the value ∝T /(N +1 ). The N dependence of the partition function is essentially determined by the kinetic energy contribution. We demonstrate that to obtain the correct energy and entropy in a constrained system, the T derivative of the partition function has to be applied before integration over the constraint-setting variable.

  6. Energy deposition by heavy ions: additivity of kinetic and potential energy contributions in hillock formation on CaF2.

    Science.gov (United States)

    Wang, Y Y; Grygiel, C; Dufour, C; Sun, J R; Wang, Z G; Zhao, Y T; Xiao, G Q; Cheng, R; Zhou, X M; Ren, J R; Liu, S D; Lei, Y; Sun, Y B; Ritter, R; Gruber, E; Cassimi, A; Monnet, I; Bouffard, S; Aumayr, F; Toulemonde, M

    2014-07-18

    Modification of surface and bulk properties of solids by irradiation with ion beams is a widely used technique with many applications in material science. In this study, we show that nano-hillocks on CaF2 crystal surfaces can be formed by individual impact of medium energy (3 and 5 MeV) highly charged ions (Xe(22+) to Xe(30+)) as well as swift (kinetic energies between 12 and 58 MeV) heavy xenon ions. For very slow highly charged ions the appearance of hillocks is known to be linked to a threshold in potential energy (Ep) while for swift heavy ions a minimum electronic energy loss per unit length (Se) is necessary. With our results we bridge the gap between these two extreme cases and demonstrate, that with increasing energy deposition via Se the Ep-threshold for hillock production can be lowered substantially. Surprisingly, both mechanisms of energy deposition in the target surface seem to contribute in an additive way, which can be visualized in a phase diagram. We show that the inelastic thermal spike model, originally developed to describe such material modifications for swift heavy ions, can be extended to the case where both kinetic and potential energies are deposited into the surface.

  7. Systematics of threshold incident energy for deep sub-barrier fusion hindrance

    International Nuclear Information System (INIS)

    Ichikawa, Takatoshi; Hagino, Kouichi; Iwamoto, Akira

    2007-01-01

    We systematically evaluate the potential energy at the touching configuration for heavy-ion reactions using various potential models. We point out that the energy at the touching point, especially that estimated with the Krappe-Nix-Sierk (KNS) potential, strongly correlates with the threshold incident energy for steep falloff of fusion cross sections observed recently for several systems at extremely low energies. This clearly indicates that the steep fall-off phenomenon can be attributed to the dynamics after the target and projectile touch with each other, e.g., the tunneling process and the nuclear saturation property in the overlap region

  8. Effects of a power and photon energy of incident light on near-field etching properties

    Science.gov (United States)

    Yatsui, T.; Saito, H.; Nishioka, K.; Leuschel, B.; Soppera, O.; Nobusada, K.

    2017-12-01

    We developed a near-field etching technique for realizing an ultra-flat surfaces of various materials and structures. To elucidate the near-field etching properties, we have investigated the effects of power and the photon energy of the incident light. First, we established theoretically that an optical near-field with photon energy lower than the absorption edge of the molecules can induce molecular vibrations. We used nanodiamonds to study the power dependence of the near-field etching properties. From the topological changes of the nanodiamonds, we confirmed the linear-dependence of the etching volume with the incident power. Furthermore, we studied the photon energy dependence using TiO2 nanostriped structures, which revealed that a lower photon energy results in a lower etching rate.

  9. On the ultrafast kinetics of the energy and electron transfer reactions in photosystem I

    Energy Technology Data Exchange (ETDEWEB)

    Slavov, Chavdar Lyubomirov

    2009-07-09

    The subject of the current work is one of the main participants in the light-dependent phase of oxygenic photosynthesis, Photosystem I (PS I). This complex carries an immense number of cofactors: chlorophylls (Chl), carotenoids, quinones, etc, which together with the protein entity exhibit several exceptional properties. First, PS I has an ultrafast light energy trapping kinetics with a nearly 100% quantum efficiency. Secondly, both of the electron transfer branches in the reaction center are suggested to be active. Thirdly, there are some so called 'red' Chls in the antenna system of PS I, absorbing light with longer wavelengths than the reaction center. These 'red' Chls significantly modify the trapping kinetics of PS I. The purpose of this thesis is to obtain better understanding of the above-mentioned, specific features of PS I. This will not merely cast more light on the mechanisms of energy and electron transfer in the complex, but also will contribute to the future developments of optimized artificial light-harvesting systems. In the current work, a number of PS I complexes isolated from different organisms (Thermosynechococcus elongatus, Chlamydomonas reinhardtii, Arabidopsis thaliana) and possessing distinctive features (different macroorganisation, monomers, trimers, monomers with a semibelt of peripheral antenna attached; presence of 'red' Chls) is investigated. The studies are primarily focused on the electron transfer kinetics in each of the cofactor branches in the PS I reaction center, as well as on the effect of the antenna size and the presence of 'red' Chls on the trapping kinetics of PS I. These aspects are explored with the help of several ultrafast optical spectroscopy methods: (i) time-resolved fluorescence ? single photon counting and synchroscan streak camera; and (ii) ultrafast transient absorption. Physically meaningful information about the molecular mechanisms of the energy trapping in PS I is

  10. Forward and inverse kinetic energy cascades in Jupiter’s turbulent weather layer

    Science.gov (United States)

    Young, Roland M. B.; Read, Peter L.

    2017-11-01

    Jupiter’s turbulent weather layer contains phenomena of many different sizes, from local storms up to the Great Red Spot and banded jets. The global circulation is driven by complex interactions with (as yet uncertain) small-scale processes. We have calculated structure functions and kinetic energy spectral fluxes from Cassini observations over a wide range of length scales in Jupiter’s atmosphere. We found evidence for an inverse cascade of kinetic energy from length scales comparable to the first baroclinic Rossby deformation radius up to the global jet scale, but also a forward cascade of kinetic energy from the deformation radius to smaller scales. This second result disagrees with the traditional picture of Jupiter’s atmospheric dynamics, but has some similarities with mesoscale phenomena in the Earth’s atmosphere and oceans. We conclude that the inverse cascade driving Jupiter’s jets may have a dominant energy source at scales close to the deformation radius, such as baroclinic instability.

  11. Effect of heating rate and kinetic model selection on activation energy of nonisothermal crystallization of amorphous felodipine.

    Science.gov (United States)

    Chattoraj, Sayantan; Bhugra, Chandan; Li, Zheng Jane; Sun, Changquan Calvin

    2014-12-01

    The nonisothermal crystallization kinetics of amorphous materials is routinely analyzed by statistically fitting the crystallization data to kinetic models. In this work, we systematically evaluate how the model-dependent crystallization kinetics is impacted by variations in the heating rate and the selection of the kinetic model, two key factors that can lead to significant differences in the crystallization activation energy (Ea ) of an amorphous material. Using amorphous felodipine, we show that the Ea decreases with increase in the heating rate, irrespective of the kinetic model evaluated in this work. The model that best describes the crystallization phenomenon cannot be identified readily through the statistical fitting approach because several kinetic models yield comparable R(2) . Here, we propose an alternate paired model-fitting model-free (PMFMF) approach for identifying the most suitable kinetic model, where Ea obtained from model-dependent kinetics is compared with those obtained from model-free kinetics. The most suitable kinetic model is identified as the one that yields Ea values comparable with the model-free kinetics. Through this PMFMF approach, nucleation and growth is identified as the main mechanism that controls the crystallization kinetics of felodipine. Using this PMFMF approach, we further demonstrate that crystallization mechanism from amorphous phase varies with heating rate. © 2014 Wiley Periodicals, Inc. and the American Pharmacists Association.

  12. Adaptive coarse graining method for energy transfer and dissociation kinetics of polyatomic species

    Science.gov (United States)

    Sahai, A.; Lopez, B.; Johnston, C. O.; Panesi, M.

    2017-08-01

    A novel reduced-order method is presented for modeling reacting flows characterized by strong non-equilibrium of the internal energy level distribution of chemical species in the gas. The approach seeks for a reduced-order representation of the distribution function by grouping individual energy states into macroscopic bins, and then reconstructing state population using the maximum entropy principle. This work introduces an adaptive grouping methodology to identify and lump together groups of states that are likely to equilibrate faster with respect to each other. To this aim, two algorithms have been considered: the modified island algorithm and the spectral clustering method. Both methods require a measure of dissimilarity between internal energy states. This is achieved by defining "metrics" based on the strength of the elementary rate coefficients included in the state-specific kinetic mechanism. Penalty terms are used to avoid grouping together states characterized by distinctively different energies. The two methods are used to investigate excitation and dissociation of N2 (g+1Σ) molecules due to interaction with N (S4u ) atoms in an ideal chemical reactor. The results are compared with a direct numerical simulation of the state-specific kinetics obtained by solving the master equations for the complete set of energy levels. It is found that adaptive grouping techniques outperform the more conventional uniform energy grouping algorithm by providing a more accurate description of the distribution function, mole fraction and energy profiles during non-equilibrium relaxation.

  13. The kinetic energy operator for distance-dependent effective nuclear masses: Derivation for a triatomic molecule

    Science.gov (United States)

    Khoma, Mykhaylo; Jaquet, Ralph

    2017-09-01

    The kinetic energy operator for triatomic molecules with coordinate or distance-dependent nuclear masses has been derived. By combination of the chain rule method and the analysis of infinitesimal variations of molecular coordinates, a simple and general technique for the construction of the kinetic energy operator has been proposed. The asymptotic properties of the Hamiltonian have been investigated with respect to the ratio of the electron and proton mass. We have demonstrated that an ad hoc introduction of distance (and direction) dependent nuclear masses in Cartesian coordinates preserves the total rotational invariance of the problem. With the help of Wigner rotation functions, an effective Hamiltonian for nuclear motion can be derived. In the derivation, we have focused on the effective trinuclear Hamiltonian. All necessary matrix elements are given in closed analytical form. Preliminary results for the influence of non-adiabaticity on vibrational band origins are presented for H3+.

  14. Budget of Turbulent Kinetic Energy in a Shock Wave Boundary-Layer Interaction

    Science.gov (United States)

    Vyas, Manan A.; Waindim, Mbu; Gaitonde, Datta V.

    2016-01-01

    Implicit large-eddy simulation (ILES) of a shock wave/boundary-layer interaction (SBLI) was performed. Quantities present in the exact equation of the turbulent kinetic energy transport were accumulated and used to calculate terms like production, dissipation, molecular diffusion, and turbulent transport. The present results for a turbulent boundary layer were validated by comparison with direct numerical simulation data. It was found that a longer development domain was necessary for the boundary layer to reach an equilibrium state and a finer mesh resolution would improve the predictions. In spite of these findings, trends of the present budget match closely with that of the direct numerical simulation. Budgets for the SBLI region are presented at key axial stations. These budgets showed interesting dynamics as the incoming boundary layer transforms and the terms of the turbulent kinetic energy budget change behavior within the interaction region.

  15. The kinetic energy operator for distance-dependent effective nuclear masses: Derivation for a triatomic molecule.

    Science.gov (United States)

    Khoma, Mykhaylo; Jaquet, Ralph

    2017-09-21

    The kinetic energy operator for triatomic molecules with coordinate or distance-dependent nuclear masses has been derived. By combination of the chain rule method and the analysis of infinitesimal variations of molecular coordinates, a simple and general technique for the construction of the kinetic energy operator has been proposed. The asymptotic properties of the Hamiltonian have been investigated with respect to the ratio of the electron and proton mass. We have demonstrated that an ad hoc introduction of distance (and direction) dependent nuclear masses in Cartesian coordinates preserves the total rotational invariance of the problem. With the help of Wigner rotation functions, an effective Hamiltonian for nuclear motion can be derived. In the derivation, we have focused on the effective trinuclear Hamiltonian. All necessary matrix elements are given in closed analytical form. Preliminary results for the influence of non-adiabaticity on vibrational band origins are presented for H 3 + .

  16. Revisiting the density scaling of the non-interacting kinetic energy.

    Science.gov (United States)

    Borgoo, Alex; Teale, Andrew M; Tozer, David J

    2014-07-28

    Scaling relations play an important role in the understanding and development of approximate functionals in density functional theory. Recently, a number of these relationships have been redefined in terms of the Kohn-Sham orbitals [Calderín, Phys. Rev. A: At., Mol., Opt. Phys., 2013, 86, 032510]. For density scaling the author proposed a procedure involving a multiplicative scaling of the Kohn-Sham orbitals whilst keeping their occupation numbers fixed. In the present work, the differences between this scaling with fixed occupation numbers and that of previous studies, where the particle number change implied by the scaling was accommodated through the use of the grand canonical ensemble, are examined. We introduce the terms orbital and ensemble density scaling for these approaches, respectively. The natural ambiguity of the density scaling of the non-interacting kinetic energy functional is examined and the ancillary definitions implicit in each approach are highlighted and compared. As a consequence of these differences, Calderín recovered a homogeneity of degree 1 for the non-interacting kinetic energy functional under orbital scaling, contrasting recent work by the present authors [J. Chem. Phys., 2012, 136, 034101] where the functional was found to be inhomogeneous under ensemble density scaling. Furthermore, we show that the orbital scaling result follows directly from the linearity and the single-particle nature of the kinetic energy operator. The inhomogeneity of the non-interacting kinetic energy functional under ensemble density scaling can be quantified by defining an effective homogeneity. This quantity is shown to recover the homogeneity values for important approximate forms that are exact for limiting cases such as the uniform electron gas and one-electron systems. We argue that the ensemble density scaling provides more insight into the development of new functional forms.

  17. Transmission of electrons through insulating PET foils: Dependence on charge deposition, tilt angle and incident energy

    Energy Technology Data Exchange (ETDEWEB)

    Keerthisinghe, D., E-mail: darshika.keerthisinghe@wmich.edu [Department of Physics, Western Michigan University, Kalamazoo, MI 49008 (United States); Dassanayake, B.S. [Department of Physics, University of Peradeniya, Peradeniya (Sri Lanka); Wickramarachchi, S.J. [Department of Physics, Western Michigan University, Kalamazoo, MI 49008 (United States); Stolterfoht, N. [Helmholtz-Zentrum Berlin für Materialien und Energie, D-14109 Berlin (Germany); Tanis, J.A. [Department of Physics, Western Michigan University, Kalamazoo, MI 49008 (United States)

    2016-09-01

    Transmission of electrons through insulating polyethylene terephthalate (PET) nanocapillaries was observed as a function of charge deposition, angular and energy dependence. Two samples with capillary diameters 100 and 200 nm and pore densities 5 × 10{sup 8}/cm{sup 2} and 5 × 10{sup 7}/cm{sup 2}, respectively, were studied for incident electron energies of 300, 500 and 800 eV. Transmission and steady state of the electrons were attained after a time delay during which only a few electron counts were observed. The transmission through the capillaries depended on the tilt angle with both elastic and inelastic electrons going through. The guiding ability of electrons was found to increase with the incident energy in contrast to previous measurements in our laboratory for a similar PET foil.

  18. Incident Energy Dependence of pt Correlations at RHIC

    Energy Technology Data Exchange (ETDEWEB)

    Adams, J.; Aggarwal, M. M.; Ahammed, Z.; Amonett, J.; Anderson, B. D.; Arkhipkin, D.; Averichev, G. S.; Badyal, S. K.; Bai, Y.; Balewski, J.; Barannikova, O.; Barnby, L. S.; Baudot, J.; Bekele, S.; Belaga, V. V.; Bellwied, R.; Berger, J.; Bezverkhny, B. I; Bharadwaj, S.; Bhasin, A.; Bhati, A. K.; Bhatia, V. S.; Bichsel, H.; Billmeier, A.; Bland, L. C.; Blyth, C. O.; Bonner, B. E.; Botje, M.; Boucham, A.; Brandin, A. V.; Bravar, A.; Bystersky, M.; Cadman, R. V.; Cai, X. Z.; Caines, H.; Castillo, J.; Cebra, D.; Chajecki, Z.; Chaloupka, P.; Chattopadhyay, S.; Chen, H. F.; Chen, Y.; Cheng, J.; Cherney, M.; Chikanian, A.; Christie, W.; Coffin, J. P.; Cormier, T. M.; Cramer, J. G.; Crawford, H. J.; Das, D.; Das, S.; de Moura, M. M.; Derevschikov, A. A.; Didenko, L.; Dietel, T.; Dogra, S. M.; Dong, W. J.; Dong, X.; Draper, J. E.; Du, F.; Dubey, A. K.; Dunin, V. B.; Dunlop, J. C.; Dutta Mazumdar, M. R.; Eckardt, V.; Edwards, W. R.; Efimov, L. G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Fachini, P.; Faivre, J.; Fatemi, R.; Fedorisin, J.; Filimonov, K.; Filip, P.; Finch, E.; Fine, V.; Fisyak, Y.; Fomenko, K.; Fu, J.; Gagliardi, C. A.; Gaillard, L.; Gans, J.; Ganti, M. S.; Gaudichet, L.; Geurts, F.; Ghazikhanian, V.; Ghosh, P.; Gonzalez, J. E.; Grachov, O.; Grebenyuk, O.; Grosnick, D.; Guertin, S. M.; Guo, Y.; Gupta, A.; Gutierrez, T. D.; Hallman, T. J.; Hamed, A.; Hardtke, D.; Harris, J. W.; Heinz, M.; Henry, T. W.; Hepplemann, S.; Hippolyte, B.; Hirsch, A.; Hjort, E.; Hoffmann, G. W.; Huang, H. Z.; Huang, S. L.; Hughes, E. W.; Humanic, T. J.; Igo, G.; Ishihara, A.; Jacobs, P.; Jacobs, W. W.; Janik, M.; Jiang, H.; Jones, P. G.; Judd, E. G.; Kabana, S.; Kang, K.; Kaplan, M.; Keane, D.; Khodyrev, V. Yu; Kiryluk, J.; Kisiel, A.; Kislov, E. M.; Klay, J.; Klein, S. R.; Koetke, D. D.; Kollegger, T.; Kopytine, M.; Kotchenda, L.; Kramer, M.; Kravtsov, P.; Kravtsov, V. I.; Krueger, K.; Kuhn, C.; Kulikov, A. I.; Kumar, A.; Kutuev, R. Kh

    2005-10-01

    We present results for two-particle transverse momentum correlations, Δpt,iΔt,j, as a function of event centrality for Au+Au collisions at √(sNN) = 20, 62, 130, and 200 GeV at the Relativistic Heavy Ion Collider. We observe correlations decreasing with centrality that are similar at all four incident energies. The correlations multiplied by the multiplicity density increase with incident energy and the centrality dependence may show evidence of processes such as thermalization, jet production, or the saturation of transverse flow. The square root of the correlations divided by the event-wise average transverse momentum per event shows little or no beam energy dependence and generally agrees with previous measurements at the Super Proton Synchrotron.

  19. State-to-State Internal Energy Relaxation Following the Quantum-Kinetic Model in DSMC

    Science.gov (United States)

    Liechty, Derek S.

    2014-01-01

    A new model for chemical reactions, the Quantum-Kinetic (Q-K) model of Bird, has recently been introduced that does not depend on macroscopic rate equations or values of local flow field data. Subsequently, the Q-K model has been extended to include reactions involving charged species and electronic energy level transitions. Although this is a phenomenological model, it has been shown to accurately reproduce both equilibrium and non-equilibrium reaction rates. The usefulness of this model becomes clear as local flow conditions either exceed the conditions used to build previous models or when they depart from an equilibrium distribution. Presently, the applicability of the relaxation technique is investigated for the vibrational internal energy mode. The Forced Harmonic Oscillator (FHO) theory for vibrational energy level transitions is combined with the Q-K energy level transition model to accurately reproduce energy level transitions at a reduced computational cost compared to the older FHO models.

  20. Kinetics of interaction from low-energy-ion bombardment of surfaces

    International Nuclear Information System (INIS)

    Horton, C.C.

    1988-01-01

    The kinetics of interaction from low energy oxygen ion bombardment of carbon and Teflon surfaces have been investigated. The surfaces were bombarded with 4.5 to 93 eV oxygen ions and emitted species were observed with a mass spectrometer. To obtain the kinetic information, the ion beam was square pulse modulated and reaction products were observed as a function of time. The kinetic information is contained in the response of the emitted species to the pulsed ion beam. Oxygen bombardment of carbon produced CO in three parallel branches with each following an adsorption-desorption process. The fast branch, with a rate constants of 12,000/sec, appeared to be sputter induced an was absent below about 19 eV. The medium and slow branches, with rate constants of 850/sec and 45/sec respectively, has little energy dependence and appeared to be due to chemical sputtering from two sites. The ratio of the fraction of the medium branch to that of the slow was constant at 1:3. The bombardment of Teflon produced CF in two parallel branches, with one following a series process and the other an adsorb-desorb process. The rate constant of the other branch were 22,000/sec and 7,000/sec and the rate constant of the other branch was 90/sec. The total signal fell monotonically with decreasing ion energy with the fraction for each branch holding constant at 71% for the series and 29% for the adsorb-desorb

  1. Recruiting at the edge: kinetic energy inhibits anchovy populations in the western Mediterranean.

    Science.gov (United States)

    Ruiz, Javier; Macías, Diego; Rincón, Margarita M; Pascual, Ananda; Catalán, Ignacio A; Navarro, Gabriel

    2013-01-01

    The Strait of Gibraltar replenishes the Mediterranean with Atlantic waters through an intense eastward current known as the Atlantic Jet (AJ). The AJ fertilizes the southwestern Mediterranean and is considered to be the ultimate factor responsible for the comparatively high fish production of this region. Here, we perform an analysis of the available historical catches and catch per unit effort (CPUE), together with a long series of surface currents, kinetic energy and chlorophyll concentration. We show that the high kinetic energy of the AJ increases primary production but also negatively impacts the recruitment of anchovy. We contend that anchovy recruitment in the region is inhibited by the advection and dispersion of larvae and post-larvae during periods of strong advection by the AJ. The inhibitory impact of kinetic energy on anchovy landings is not a transient but rather a persistent state of the system. An exceptional combination of events creates an outbreak of this species in the Alboran Sea. These events depend on the Mediterranean-Atlantic exchange of water masses and, therefore, are highly sensitive to climate changes that are projected, though not always negatively, for fish landings.

  2. Pyrolysis characteristics and kinetics of low rank coals by distributed activation energy model

    International Nuclear Information System (INIS)

    Song, Huijuan; Liu, Guangrui; Wu, Jinhu

    2016-01-01

    Highlights: • Types of carbon in coal structure were investigated by curve-fitted 13 C NMR spectra. • The work related pyrolysis characteristics and kinetics with coal structure. • Pyrolysis kinetics of low rank coals were studied by DAEM with Miura integral method. • DAEM could supply accurate extrapolations under relatively higher heating rates. - Abstract: The work was conducted to investigate pyrolysis characteristics and kinetics of low rank coals relating with coal structure by thermogravimetric analysis (TGA), the distributed activation energy model (DAEM) and solid-state 13 C Nuclear Magnetic Resonance (NMR). Four low rank coals selected from different mines in China were studied in the paper. TGA was carried out with a non-isothermal temperature program in N 2 at the heating rate of 5, 10, 20 and 30 °C/min to estimate pyrolysis processes of coal samples. The results showed that corresponding characteristic temperatures and the maximum mass loss rates increased as heating rate increased. Pyrolysis kinetics parameters were investigated by the DAEM using Miura integral method. The DAEM was accurate verified by the good fit between the experimental and calculated curves of conversion degree x at the selected heating rates and relatively higher heating rates. The average activation energy was 331 kJ/mol (coal NM), 298 kJ/mol (coal NX), 302 kJ/mol (coal HLJ) and 196 kJ/mol (coal SD), respectively. The curve-fitting analysis of 13 C NMR spectra was performed to characterize chemical structures of low rank coals. The results showed that various types of carbon functional groups with different relative contents existed in coal structure. The work indicated that pyrolysis characteristics and kinetics of low rank coals were closely associated with their chemical structures.

  3. Energy dependence of ion-induced sputtering yields from monoatomic solids at normal incidence

    International Nuclear Information System (INIS)

    Yamamura, Yasunori; Tawara, Hiro.

    1995-03-01

    The yields of the ion-induced sputtering from monoatomic solids at normal incidence for various ion-target combinations are presented graphically as a function of the incident ion energy. In order to fill the lack of the experimental data, the sputtering yields are also calculated by the Monte Carlo simulation code ACAT for some ion-target combinations. Each graph shows available experimental data points and the ACAT data, together with the sputtering yields calculated by the present empirical formula, whose parameters are determined by the best-fit to available data. (author)

  4. Monte Carlo simulation for fragment mass and kinetic energy distributions from the neutron-induced fission of {sup 235}U

    Energy Technology Data Exchange (ETDEWEB)

    Montoya, M.; Rojas, J. [Instituto Peruano de Energia Nuclear, Av. Canada 1470, Lima 41 (Peru); Saettone, E. [Facultad de Ciencias, Universidad Nacional de lngenieria, Av. Tupac Amaru 210, Apartado 31-139, Lima (Peru)

    2007-07-01

    The mass and kinetic energy distribution of nuclear fragments from the thermal neutron-induced fission of {sup 235}U have been studied using a Monte Carlo simulation. Besides reproducing the pronounced broadening on the standard deviation of the final fragment kinetic energy distribution ({sigma}{sub e}(m)) around the mass number m = 109, our simulation also produces a second broadening around m = 125 that is in agreement with the experimental data obtained by Belhafaf et al. These results are a consequence of the characteristics of the neutron emission, the variation in the primary fragment mean kinetic energy, and the yield as a function of the mass. (Author)

  5. Kinetic energy in the collective quadrupole Hamiltonian from the experimental data

    Directory of Open Access Journals (Sweden)

    R.V. Jolos

    2017-06-01

    Full Text Available Dependence of the kinetic energy term of the collective nuclear Hamiltonian on collective momentum is considered. It is shown that the fourth order in collective momentum term of the collective quadrupole Hamiltonian generates a sizable effect on the excitation energies and the matrix elements of the quadrupole moment operator. It is demonstrated that the results of calculation are sensitive to the values of some matrix elements of the quadrupole moment. It stresses the importance for a concrete nucleus to have the experimental data for the reduced matrix elements of the quadrupole moment operator taken between all low lying states with the angular momenta not exceeding 4.

  6. A method for ion distribution function evaluation using escaping neutral atom kinetic energy samples

    International Nuclear Information System (INIS)

    Goncharov, P.R.; Ozaki, T.; Veshchev, E.A.; Sudo, S.

    2008-01-01

    A reliable method to evaluate the probability density function for escaping atom kinetic energies is required for the analysis of neutral particle diagnostic data used to study the fast ion distribution function in fusion plasmas. Digital processing of solid state detector signals is proposed in this paper as an improvement of the simple histogram approach. Probability density function for kinetic energies of neutral particles escaping from the plasma has been derived in a general form taking into account the plasma ion energy distribution, electron capture and loss rates, superposition along the diagnostic sight line and the magnetic surface geometry. A pseudorandom number generator has been realized that enables a sample of escaping neutral particle energies to be simulated for given plasma parameters and experimental conditions. Empirical probability density estimation code has been developed and tested to reconstruct the probability density function from simulated samples assuming. Maxwellian and classical slowing down plasma ion energy distribution shapes for different temperatures and different slowing down times. The application of the developed probability density estimation code to the analysis of experimental data obtained by the novel Angular-Resolved Multi-Sightline Neutral Particle Analyzer has been studied to obtain the suprathermal particle distributions. The optimum bandwidth parameter selection algorithm has also been realized. (author)

  7. Chemical bond as a test of density-gradient expansions for kinetic and exchange energies

    International Nuclear Information System (INIS)

    Perdew, J.P.; Levy, M.; Painter, G.S.; Wei, S.; Lagowski, J.B.

    1988-01-01

    Errors in kinetic and exchange contributions to the molecular bonding energy are assessed for approximate density functionals by reference to near-exact Hartree-Fock values. From the molecular calculations of Allan et al. and of Lee and Ghosh, it is demonstrated that the density-gradient expansion does not accurately describe the noninteracting kinetic contribution to the bonding energy, even when this expansion is carried to fourth order and applied in its spin-density-functional form to accurate Hartree-Fock densities. In a related study, it is demonstrated that the overbinding of molecules such as N 2 and F 2 , which occurs in the local-spin-density (LSD) approximation for the exchange-correlation energy, is not attributable to errors in the self-consistent LSD densities. Contrary to expectations based upon the Gunnarsson-Jones nodality argument, it is found that the LSD approximation for the exchange energy can seriously overbind a molecule even when bonding does not create additional nodes in the occupied valence orbitals. LSD and exact values for the exchange contribution to the bonding energy are displayed and discussed for several molecules

  8. US lessons for energy industry restructuring: based on natural gas and California electricity incidences

    International Nuclear Information System (INIS)

    Lee, W.W.

    2004-01-01

    During the regulation and deregulation processes, the US experienced, besides temporary price spikes, several unhappy incidences; natural gas shortage in mid-1970s, gas bubble in 1980s, California power crisis, and high natural gas price in 2000-2001. This paper focuses on the US natural gas and California electricity industries, especially on the above-mentioned four incidences. Through analyzing their causes and effects, this paper tries to deduce some lessons, which would be helpful to prevent and/or overcome other probable incidences in the US as well as in other countries in a process of deregulation or planning to introduce competition in their energy industries. Main lessons deduced are encouragement of investment, minimization of political consideration, transmission of price signal to all the market players, outlet for any market interference, diversification of trading options, and minimum ambiguity on responsibility between regulators as well as watching on general market situation and correcting its flaws in timely manner

  9. US lessons for energy industry restructuring: based on natural gas and California electricity incidences

    International Nuclear Information System (INIS)

    Wonwoo Lee

    2004-01-01

    During the regulation and deregulation processes, the US experienced, besides temporary price spikes, several unhappy incidences; natural gas shortage in mid-1970s, gas bubble in 1980s, California power crisis, and high natural gas price in 2000-2001. This paper focuses on the US natural gas and California electricity industries, especially on the above-mentioned four incidences. Through analyzing their causes and effects, this paper tries to deduce some lessons, which would be helpful to prevent and/or overcome other probable incidences in the US as well as in other countries in a process of deregulation or planning to introduce competition in their energy industries. Main lessons deduced are encouragement of investment, minimization of political consideration, transmission of price signal to all the market players, outlet for any market interference, diversification of trading options, and minimum ambiguity on responsibility between regulators as well as watching on general market situation and correcting its flaws in timely manner. (Author)

  10. Analysis of incident-energy dependence of delayed neutron yields in actinides

    Energy Technology Data Exchange (ETDEWEB)

    Nasir, Mohamad Nasrun bin Mohd, E-mail: monasr211@gmail.com; Metorima, Kouhei, E-mail: kohei.m2420@hotmail.co.jp; Ohsawa, Takaaki, E-mail: ohsawa@mvg.biglobe.ne.jp; Hashimoto, Kengo, E-mail: kengoh@pp.iij4u.or.jp [Graduate School of Science and Engineering, Kindai University, Kowakae, Higashi-Osaka, 577-8502 (Japan)

    2015-04-29

    The changes of delayed neutron yields (ν{sub d}) of Actinides have been analyzed for incident energy up to 20MeV using realized data of precursor after prompt neutron emission, from semi-empirical model, and delayed neutron emission probability data (P{sub n}) to carry out a summation method. The evaluated nuclear data of the delayed neutron yields of actinide nuclides are still uncertain at the present and the cause of the energy dependence has not been fully understood. In this study, the fission yields of precursor were calculated considering the change of the fission fragment mass yield based on the superposition of fives Gaussian distribution; and the change of the prompt neutrons number associated with the incident energy dependence. Thus, the incident energy dependent behavior of delayed neutron was analyzed.The total number of delayed neutron is expressed as ν{sub d}=∑Y{sub i} • P{sub ni} in the summation method, where Y{sub i} is the mass yields of precursor i and P{sub ni} is the delayed neutron emission probability of precursor i. The value of Y{sub i} is derived from calculation of post neutron emission mass distribution using 5 Gaussian equations with the consideration of large distribution of the fission fragments. The prompt neutron emission ν{sub p} increases at higher incident-energy but there are two different models; one model says that the fission fragment mass dependence that prompt neutron emission increases uniformly regardless of the fission fragments mass; and the other says that the major increases occur at heavy fission fragments area. In this study, the changes of delayed neutron yields by the two models have been investigated.

  11. Kinetic energy distributions of sputtered neutral aluminum clusters: Al--Al6

    International Nuclear Information System (INIS)

    Coon, S.R.; Calaway, W.F.; Pellin, M.J.; Curlee, G.A.; White, J.M.

    1992-01-01

    Neutral aluminum clusters sputtered from polycrystalline aluminum were analyzed by laser postionization time-of-flight (TOF) mass spectrometry. The kinetic energy distributions of Al through Al 6 were measured by a neutrals time-of-flight technique. The interpretation of laser postionization TOF data to extract velocity and energy distributions is presented. The aluminum cluster distributions are qualitatively similar to previous copper cluster distribution measurements from our laboratory. In contrast to the steep high energy tails predicted by the single- or multiple- collision models, the measured cluster distributions have high energy power law dependences in the range of E -3 to E -4.5 . Correlated collision models may explain the substantial abundance of energetic clusters that are observed in these experiments. Possible influences of cluster fragmentation on the distributions are discussed

  12. Anisotropic kinetic energy release and gyroscopic behavior of CO2 super rotors from an optical centrifuge

    Science.gov (United States)

    Murray, Matthew J.; Ogden, Hannah M.; Mullin, Amy S.

    2017-10-01

    An optical centrifuge is used to generate an ensemble of CO2 super rotors with oriented angular momentum. The collision dynamics and energy transfer behavior of the super rotor molecules are investigated using high-resolution transient IR absorption spectroscopy. New multipass IR detection provides improved sensitivity to perform polarization-dependent transient studies for rotational states with 76 ≤ J ≤ 100. Polarization-dependent measurements show that the collision-induced kinetic energy release is spatially anisotropic and results from both near-resonant energy transfer between super rotor molecules and non-resonant energy transfer between super rotors and thermal molecules. J-dependent studies show that the extent and duration of the orientational anisotropy increase with rotational angular momentum. The super rotors exhibit behavior akin to molecular gyroscopes, wherein molecules with larger amounts of angular momentum are less likely to change their angular momentum orientation through collisions.

  13. Enzymatic Kinetic Isotope Effects from Path-Integral Free Energy Perturbation Theory.

    Science.gov (United States)

    Gao, J

    2016-01-01

    Path-integral free energy perturbation (PI-FEP) theory is presented to directly determine the ratio of quantum mechanical partition functions of different isotopologs in a single simulation. Furthermore, a double averaging strategy is used to carry out the practical simulation, separating the quantum mechanical path integral exactly into two separate calculations, one corresponding to a classical molecular dynamics simulation of the centroid coordinates, and another involving free-particle path-integral sampling over the classical, centroid positions. An integrated centroid path-integral free energy perturbation and umbrella sampling (PI-FEP/UM, or simply, PI-FEP) method along with bisection sampling was summarized, which provides an accurate and fast convergent method for computing kinetic isotope effects for chemical reactions in solution and in enzymes. The PI-FEP method is illustrated by a number of applications, to highlight the computational precision and accuracy, the rule of geometrical mean in kinetic isotope effects, enhanced nuclear quantum effects in enzyme catalysis, and protein dynamics on temperature dependence of kinetic isotope effects. © 2016 Elsevier Inc. All rights reserved.

  14. Notepad-like triboelectric generator for efficiently harvesting low-velocity motion energy by interconversion between kinetic energy and elastic potential energy.

    Science.gov (United States)

    Liu, Guanlin; Leng, Qiang; Lian, Jiawei; Guo, Hengyu; Yi, Xi; Hu, Chenguo

    2015-01-21

    Great attention has been paid to nanogenerators that harvest energy from ambient environments lately. In order to give considerable output current, most nanogenerators require high-velocity motion that in most cases can hardly be provided in our daily life. Here we report a notepad-like triboelectric generator (NTEG), which uses simple notepad-like structure to generate elastic deformation so as to turn a low-velocity kinetic energy into high-velocity kinetic energy through the conversion of elastic potential energy. Therefore, the NTEG can achieve high current output under low-velocity motion, which completely distinguishes it from tribogenerators previously reported. The factors that may affect the output performance are explored, including the number of slices, active length of slice, press speed, and vertical displacement. In addition, the working mechanism is systematically studied, indicating that the efficiency of the generator can be greatly enhanced by interconversion between kinetic energy and elastic potential energy. The short-circuit current, the open-circuit voltage, and power density are 205 μA and 470 V and 9.86 W/m(2), respectively, which is powerful enough to light up hundreds of light-emitting diodes (LEDs) and charge a commercial capacitor. Besides, NTEGs have been successfully applied to a self-powered door monitor.

  15. A generalized electron energy probability function for inductively coupled plasmas under conditions of nonlocal electron kinetics

    Science.gov (United States)

    Mouchtouris, S.; Kokkoris, G.

    2018-01-01

    A generalized equation for the electron energy probability function (EEPF) of inductively coupled Ar plasmas is proposed under conditions of nonlocal electron kinetics and diffusive cooling. The proposed equation describes the local EEPF in a discharge and the independent variable is the kinetic energy of electrons. The EEPF consists of a bulk and a depleted tail part and incorporates the effect of the plasma potential, Vp, and pressure. Due to diffusive cooling, the break point of the EEPF is eVp. The pressure alters the shape of the bulk and the slope of the tail part. The parameters of the proposed EEPF are extracted by fitting to measure EEPFs (at one point in the reactor) at different pressures. By coupling the proposed EEPF with a hybrid plasma model, measurements in the gaseous electronics conference reference reactor concerning (a) the electron density and temperature and the plasma potential, either spatially resolved or at different pressure (10-50 mTorr) and power, and (b) the ion current density of the electrode, are well reproduced. The effect of the choice of the EEPF on the results is investigated by a comparison to an EEPF coming from the Boltzmann equation (local electron kinetics approach) and to a Maxwellian EEPF. The accuracy of the results and the fact that the proposed EEPF is predefined renders its use a reliable alternative with a low computational cost compared to stochastic electron kinetic models at low pressure conditions, which can be extended to other gases and/or different electron heating mechanisms.

  16. Activation energy of etching for CR-39 as a function of linear energy transfer of the incident particles

    CERN Document Server

    Awad, E M

    1999-01-01

    In this work, we have studied the effect of the radiation damage caused by the incident particles on the activation energy of etching for CR-39 samples. The damage produced by the incident particle is expressed in terms of the linear energy transfer (LET). CR-39 samples from American Acrylic were irradiated to three different LET particles. These are N (LET sub 2 sub 0 sub 0 = 20 KeV/mu m) as a light particle, Fe (LET sub 2 sub 0 sub 0 = 110 KeV/mu m) as a medium particle and fission fragments (ff) from a sup 2 sup 5 sup 2 Cf source as heavy particles. In general the bulk etch rate was calculated using the weight difference method and the track etch rate was determined using the track geometry at various temperatures (50-90 deg. C) and concentrations (4-9 N) of the NaOH etchant. The average activation energy E sub b related to the bulk etch rate v sub b was calculated from 1n v sub b vs. 1/T. The average activation energy E sub t related to the track etch rate v sub t was estimated from 1n v sub t vs. 1/T. It...

  17. Sensory Agreement Guides Kinetic Energy Optimization of Arm Movements during Object Manipulation.

    Directory of Open Access Journals (Sweden)

    Ali Farshchiansadegh

    2016-04-01

    Full Text Available The laws of physics establish the energetic efficiency of our movements. In some cases, like locomotion, the mechanics of the body dominate in determining the energetically optimal course of action. In other tasks, such as manipulation, energetic costs depend critically upon the variable properties of objects in the environment. Can the brain identify and follow energy-optimal motions when these motions require moving along unfamiliar trajectories? What feedback information is required for such optimal behavior to occur? To answer these questions, we asked participants to move their dominant hand between different positions while holding a virtual mechanical system with complex dynamics (a planar double pendulum. In this task, trajectories of minimum kinetic energy were along curvilinear paths. Our findings demonstrate that participants were capable of finding the energy-optimal paths, but only when provided with veridical visual and haptic information pertaining to the object, lacking which the trajectories were executed along rectilinear paths.

  18. Gravitational attraction until relativistic equipartition of internal and translational kinetic energies

    Science.gov (United States)

    Bulyzhenkov, I. E.

    2018-02-01

    Translational ordering of the internal kinematic chaos provides the Special Relativity referents for the geodesic motion of warm thermodynamical bodies. Taking identical mathematics, relativistic physics of the low speed transport of time-varying heat-energies differs from Newton's physics of steady masses without internal degrees of freedom. General Relativity predicts geodesic changes of the internal heat-energy variable under the free gravitational fall and the geodesic turn in the radial field center. Internal heat variations enable cyclic dynamics of decelerated falls and accelerated takeoffs of inertial matter and its structural self-organization. The coordinate speed of the ordered spatial motion takes maximum under the equipartition of relativistic internal and translational kinetic energies. Observable predictions are discussed for verification/falsification of the principle of equipartition as a new basic for the ordered motion and self-organization in external fields, including gravitational, electromagnetic, and thermal ones.

  19. Numerical investigation of kinetic energy dynamics during autoignition of n-heptane/air mixture

    Science.gov (United States)

    Lucena Kreppel Paes, Paulo; Brasseur, James; Xuan, Yuan

    2015-11-01

    Many engineering applications involve complex turbulent reacting flows, where nonlinear, multi-scale turbulence-combustion couplings are important. Direct representation of turbulent reacting flow dynamics is associated with prohibitive computational costs, which makes it necessary to employ turbulent combustion models to account for the effects of unresolved scales on resolved scales. Classical turbulence models are extensively employed in reacting flow simulations. However, they rely on assumptions about the energy cascade, which are valid for incompressible, isothermal homogeneous isotropic turbulence. A better understanding of the turbulence-combustion interactions is required for the development of more accurate, physics-based sub-grid-scale models for turbulent reacting flows. In order to investigate the effects of reaction-induced density, viscosity, and pressure variations on the turbulent kinetic energy, Direct Numerical Simulation (DNS) of autoignition of partially-premixed, lean n-heptane/air mixture in three-dimensional homogeneous isotropic turbulence has been performed. This configuration represents standard operating conditions of Homogeneous-Charge Compression-Ignition (HCCI) engines. The differences in the turbulent kinetic energy balance between the present turbulent reacting flow and incompressible, isothermal homogeneous isotropic turbulence are highlighted at different stages during the autoignition process.

  20. An innovative approach to enhance methane hydrate formation kinetics with leucine for energy storage application

    International Nuclear Information System (INIS)

    Veluswamy, Hari Prakash; Kumar, Asheesh; Kumar, Rajnish; Linga, Praveen

    2017-01-01

    Highlights: • Innovative combinatorial hybrid approach to reduce nucleation stochasticity and enhance hydrate growth. • Methane hydrate growth curves are similar in UTR and STR configurations in presence of leucine. • Amalgamation of stirred (STR) and unstirred (UTR) configuration is demonstrated. • Reliable method for scale up and commercial production of Solidified Natural Gas (SNG). - Abstract: Natural gas storage in clathrate hydrates or solidified natural gas (SNG) offers the safest, cleanest and the most compact mode of storage aided by the relative ease in natural gas (NG) recovery with minimal cost compared to known conventional methods of NG storage. The stochastic nature of hydrate nucleation and the slow kinetics of hydrate growth are major challenges that needs to be addressed on the SNG production side. A deterministic and fast nucleation coupled with rapid crystallization kinetics would empower this beneficial technology for commercial application. We propose a hybrid combinatorial approach of methane hydrate formation utilizing the beneficial aspect of environmentally benign amino acid (leucine) as a kinetic promoter by combining stirred and unstirred reactor operation. This hybrid approach is simple, can easily be implemented and scaled-up to develop an economical SNG technology for efficient storage of natural gas on a large scale. Added benefits include the minimal energy requirement during hydrate growth resulting in overall cost reduction for SNG technology.

  1. Making waves: Kinetic processes controlling surface evolution during low energy ion sputtering

    International Nuclear Information System (INIS)

    Chan, W.L.; Chason, Eric

    2007-01-01

    When collimated beams of low energy ions are used to bombard materials, the surface often develops a periodic pattern or ''ripple'' structure. Different types of patterns are observed to develop under different conditions, with characteristic features that depend on the substrate material, the ion beam parameters, and the processing conditions. Because the patterns develop spontaneously, without applying any external mask or template, their formation is the expression of a dynamic balance among fundamental surface kinetic processes, e.g., erosion of material from the surface, ion-induced defect creation, and defect-mediated evolution of the surface morphology. In recent years, a comprehensive picture of the different kinetic mechanisms that control the different types of patterns that form has begun to emerge. In this article, we provide a review of different mechanisms that have been proposed and how they fit together in terms of the kinetic regimes in which they dominate. These are grouped into regions of behavior dominated by the directionality of the ion beam, the crystallinity of the surface, the barriers to surface roughening, and nonlinear effects. In sections devoted to each type of behavior, we relate experimental observations of patterning in these regimes to predictions of continuum models and to computer simulations. A comparison between theory and experiment is used to highlight strengths and weaknesses in our understanding. We also discuss the patterning behavior that falls outside the scope of the current understanding and opportunities for advancement

  2. Anomalous dissipation and kinetic-energy distribution in pipes at very high Reynolds numbers.

    Science.gov (United States)

    Chen, Xi; Wei, Bo-Bo; Hussain, Fazle; She, Zhen-Su

    2016-01-01

    A symmetry-based theory is developed for the description of (streamwise) kinetic energy K in turbulent pipes at extremely high Reynolds numbers (Re's). The theory assumes a mesolayer with continual deformation of wall-attached eddies which introduce an anomalous dissipation, breaking the exact balance between production and dissipation. An outer peak of K is predicted above a critical Re of 10^{4}, in good agreement with experimental data. The theory offers an alternative explanation for the recently discovered logarithmic distribution of K. The concept of anomalous dissipation is further supported by a significant modification of the k-ω equation, yielding an accurate prediction of the entire K profile.

  3. Kinetics studies of the F + HCl → HF + Cl reaction on an accurate potential energy surface

    Science.gov (United States)

    Lu, Dandan; Zhang, Ying; Li, Jun

    2018-02-01

    A full-dimensional electronic ground state potential energy surface for the hydrogen abstraction reaction F + HCl → HF + Cl is developed by using the permutation invariant polynomial neural network approach based on 6509 points computed at the level of CCSD(T)-F12a/AVTZ. Spin-orbit correction is also taken into account at the complete active space self-consistent field level. Theoretical thermal rate coefficients determined by the ring polymer molecular dynamics (RPMD) approach agree well with experiment, validating the accuracy of the PES. Kinetic isotope effect is also investigated.

  4. Hafnium- and Titanium-Coated Tungsten Powders for Kinetic Energy Penetrators, Phase 1, SBIR

    Science.gov (United States)

    1992-05-01

    the kinetics of its formation would be rather slow at the temperatures of interest due to the refractory nature of both hafnium and tungsten. With...0015/3). 6. T.B. Massalski, Binary Alloy Phase Diagrams (ASM, Metals Park, OH, 1986). 7. D.T. Vier, "Thermal and Other Properties of Refractories ...produces a strain rate of 1 x 105 in the test sample. This strain rate deposits )a. 3e she.r sb’ain energy in the test sample. ABAQUS , a finite

  5. Minimal Model of Quantum Kinetic Clusters for the Energy-Transfer Network of a Light-Harvesting Protein Complex.

    Science.gov (United States)

    Wu, Jianlan; Tang, Zhoufei; Gong, Zhihao; Cao, Jianshu; Mukamel, Shaul

    2015-04-02

    The energy absorbed in a light-harvesting protein complex is often transferred collectively through aggregated chromophore clusters. For population evolution of chromophores, the time-integrated effective rate matrix allows us to construct quantum kinetic clusters quantitatively and determine the reduced cluster-cluster transfer rates systematically, thus defining a minimal model of energy-transfer kinetics. For Fenna-Matthews-Olson (FMO) and light-havrvesting complex II (LCHII) monomers, quantum Markovian kinetics of clusters can accurately reproduce the overall energy-transfer process in the long-time scale. The dominant energy-transfer pathways are identified in the picture of aggregated clusters. The chromophores distributed extensively in various clusters can assist a fast and long-range energy transfer.

  6. Free-Free Transitions in the Presence of Laser Fields at Very Low Incident Electron Energy

    Science.gov (United States)

    Bhatia, A. K.; Sinha, Chandana

    2010-01-01

    We study the free-free transition in electron-hydrogenic systems in ground state in presence of an external laser field at very loud incident energies. The laser field is treated classically while the collision dynamics is treated quantum mechanically. The laser field is chosen to be monochromatic, linearly polarized and homogeneous. The incident electron is considered to be dressed by the laser in a nonperturbative manner by choosing a Volkov wave function for it. The scattering weave function for the electron is solved numerically by taking into account the effect of the electron exchange, short-range as well as of the long-range interactions to get the S and P wave phase shifts while for the higher angular momentum phase shifts the exchange approximation has only been considered. We calculate the laser assisted differential cross sections (LADCS) for the aforesaid free-free transition process for single photon absorption/emission. The laser intensity is chosen to be much less than the atomic field intensity. A strong suppression is noted in the LADCS as compared to the field free (FF) cross sections. Unlike the FF ones, the LADCS exhibit some oscillations having a distinct maximum at a low value of the scattering angle depending on the laser parameters as well as on the incident energies.

  7. Maximum proton kinetic energy and patient-generated neutron fluence considerations in proton beam arc delivery radiation therapy

    International Nuclear Information System (INIS)

    Sengbusch, E.; Perez-Andujar, A.; DeLuca, P. M. Jr.; Mackie, T. R.

    2009-01-01

    Several compact proton accelerator systems for use in proton therapy have recently been proposed. Of paramount importance to the development of such an accelerator system is the maximum kinetic energy of protons, immediately prior to entry into the patient, that must be reached by the treatment system. The commonly used value for the maximum kinetic energy required for a medical proton accelerator is 250 MeV, but it has not been demonstrated that this energy is indeed necessary to treat all or most patients eligible for proton therapy. This article quantifies the maximum kinetic energy of protons, immediately prior to entry into the patient, necessary to treat a given percentage of patients with rotational proton therapy, and examines the impact of this energy threshold on the cost and feasibility of a compact, gantry-mounted proton accelerator treatment system. One hundred randomized treatment plans from patients treated with IMRT were analyzed. The maximum radiological pathlength from the surface of the patient to the distal edge of the treatment volume was obtained for 180 deg. continuous arc proton therapy and for 180 deg. split arc proton therapy (two 90 degree sign arcs) using CT profiles from the Pinnacle (Philips Medical Systems, Madison, WI) treatment planning system. In each case, the maximum kinetic energy of protons, immediately prior to entry into the patient, that would be necessary to treat the patient was calculated using proton range tables for various media. In addition, Monte Carlo simulations were performed to quantify neutron production in a water phantom representing a patient as a function of the maximum proton kinetic energy achievable by a proton treatment system. Protons with a kinetic energy of 240 MeV, immediately prior to entry into the patient, were needed to treat 100% of patients in this study. However, it was shown that 90% of patients could be treated at 198 MeV, and 95% of patients could be treated at 207 MeV. Decreasing the

  8. Design and kinetic analysis of piezoelectric energy harvesters with self-adjusting resonant frequency

    Science.gov (United States)

    Yu-Jen, Wang; Tsung-Yi, Chuang; Jui-Hsin, Yu

    2017-09-01

    Vibration-based energy harvesters have been developed as power sources for wireless sensor networks. Because the vibration frequency of the environment is varied with surrounding conditions, how to design an adaptive energy harvester is a practical topic. This paper proposes a design for a piezoelectric energy harvester possessing the ability to self-adjust its resonant frequency in rotational environments. The effective length of a trapezoidal cantilever is extended by centrifugal force from a rotating wheel to vary its area moment of inertia. The analytical solution for the natural frequency of the piezoelectric energy harvester was derived from the parameter design process, which could specify a structure approaching resonance at any wheel rotating frequency. The kinetic equation and electrical damping induced by power generation were derived from a Lagrange method and a mechanical-electrical coupling model, respectively. An energy harvester with adequate parameters can generate power at a wide range of car speeds. The output power of an experimental prototype composed of piezoelectric thin films and connected to a 3.3 MΩ external resistor was approximately 70-140 μW at wheel speeds ranging from 200 to 700 RPM. These results demonstrate that the proposed piezoelectric energy harvester can be applied as a power source for the wireless tire pressure monitoring sensor.

  9. Hypovalency--a kinetic-energy density description of a 4c-2e bond.

    Science.gov (United States)

    Jacobsen, Heiko

    2009-06-07

    A bond descriptor based on the kinetic energy density, the localized-orbital locator (LOL), is used to characterize the nature of the chemical bond in electron deficient multi-center bonds. The boranes B(2)H(6), B(4)H(4), B(4)H(10), [B(6)H(6)](2-), and [B(6)H(7)](-) serve as prototypical examples of hypovalent 3c-2e and 4c-2e bonding. The kinetic energy density is derived from a set of Kohn-Sham orbitals obtained from pure density functional calculations (PBE/TZVP), and the topology of LOL is analyzed in terms of (3,-3) attractors (Gamma). The B-B-B and B-H-B 3c-2e, and the B-B-H-B 4c-2e bonding situations are defined by their own characteristic LOL profiles. The presence of one attractor in relation to the three or four atoms that are engaged in electron deficient bonding provides sufficient indication of the type of 3c-2e or 4c-2e bond present. For the 4c-2e bond in [B(6)H(7)](-) the LOL analysis is compared to results from an experimental QTAIM study.

  10. Kinetic energy classification and smoothing for compact B-spline basis sets in quantum Monte Carlo

    Science.gov (United States)

    Krogel, Jaron T.; Reboredo, Fernando A.

    2018-01-01

    Quantum Monte Carlo calculations of defect properties of transition metal oxides have become feasible in recent years due to increases in computing power. As the system size has grown, availability of on-node memory has become a limiting factor. Saving memory while minimizing computational cost is now a priority. The main growth in memory demand stems from the B-spline representation of the single particle orbitals, especially for heavier elements such as transition metals where semi-core states are present. Despite the associated memory costs, splines are computationally efficient. In this work, we explore alternatives to reduce the memory usage of splined orbitals without significantly affecting numerical fidelity or computational efficiency. We make use of the kinetic energy operator to both classify and smooth the occupied set of orbitals prior to splining. By using a partitioning scheme based on the per-orbital kinetic energy distributions, we show that memory savings of about 50% is possible for select transition metal oxide systems. For production supercells of practical interest, our scheme incurs a performance penalty of less than 5%.

  11. Energy Transfer Kinetics in Photosynthesis as an Inspiration for Improving Organic Solar Cells.

    Science.gov (United States)

    Nganou, Collins; Lackner, Gerhard; Teschome, Bezu; Deen, M Jamal; Adir, Noam; Pouhe, David; Lupascu, Doru C; Mkandawire, Martin

    2017-06-07

    Clues to designing highly efficient organic solar cells may lie in understanding the architecture of light-harvesting systems and exciton energy transfer (EET) processes in very efficient photosynthetic organisms. Here, we compare the kinetics of excitation energy tunnelling from the intact phycobilisome (PBS) light-harvesting antenna system to the reaction center in photosystem II in intact cells of the cyanobacterium Acaryochloris marina with the charge transfer after conversion of photons into photocurrent in vertically aligned carbon nanotube (va-CNT) organic solar cells with poly(3-hexyl)thiophene (P3HT) as the pigment. We find that the kinetics in electron hole creation following excitation at 600 nm in both PBS and va-CNT solar cells to be 450 and 500 fs, respectively. The EET process has a 3 and 14 ps pathway in the PBS, while in va-CNT solar cell devices, the charge trapping in the CNT takes 11 and 258 ps. We show that the main hindrance to efficiency of va-CNT organic solar cells is the slow migration of the charges after exciton formation.

  12. Kinetic energy density and agglomerate abrasion rate during blending of agglomerates into powders.

    Science.gov (United States)

    Willemsz, Tofan A; Hooijmaijers, Ricardo; Rubingh, Carina M; Tran, Thanh N; Frijlink, Henderik W; Vromans, Herman; van der Voort Maarschalk, Kees

    2012-01-23

    Problems related to the blending of a cohesive powder with a free flowing bulk powder are frequently encountered in the pharmaceutical industry. The cohesive powder often forms lumps or agglomerates which are not dispersed during the mixing process and are therefore detrimental to blend uniformity. Achieving sufficient blend uniformity requires that the blending conditions are able to break up agglomerates, which is often an abrasion process. This study was based on the assumption that the abrasion rate of agglomerates determines the required blending time. It is shown that the kinetic energy density of the moving powder bed is a relevant parameter which correlates with the abrasion rate of agglomerates. However, aspects related to the strength of agglomerates should also be considered. For this reason the Stokes abrasion number (St(Abr)) has been defined. This parameter describes the ratio between the kinetic energy density of the moving powder bed and the work of fracture of the agglomerate. The St(Abr) number is shown to predict the abrasion potential of agglomerates in the dry-mixing process. It appeared possible to include effects of filler particle size and impeller rotational rate into this concept. A clear relationship between abrasion rate of agglomerates and the value of St(Abr) was demonstrated. Copyright © 2011 Elsevier B.V. All rights reserved.

  13. Current redistribution and generation of kinetic energy in the stagnated Z pinch.

    Science.gov (United States)

    Ivanov, V V; Anderson, A A; Papp, D; Astanovitskiy, A L; Talbot, B R; Chittenden, J P; Niasse, N

    2013-07-01

    The structure of magnetic fields was investigated in stagnated wire-array Z pinches using a Faraday rotation diagnostic at the wavelength of 266 nm. The distribution of current in the pinch and trailing material was reconstructed. A significant part of current can switch from the main pinch to the trailing plasma preheated by x-ray radiation of the pinch. Secondary implosions of trailing plasma generate kinetic energy and provide enhanced heating and radiation of plasma at stagnation. Hot spots in wire-array Z pinches also provide enhanced radiation of the Z pinch. A collapse of a single hot spot radiates 1%-3% of x-ray energy of the Z pinch with a total contribution of hot spots of 10%-30%.

  14. Dependence of single-walled carbon nanotube adsorption kinetics on temperature and binding energy.

    Science.gov (United States)

    Rawat, D S; Krungleviciute, V; Heroux, L; Bulut, M; Calbi, M M; Migone, A D

    2008-12-02

    We present results for the isothermal adsorption kinetics of methane, hydrogen, and tetrafluoromethane on closed-ended single-walled carbon nanotubes. In these experiments, we monitor the pressure decrease as a function of time as equilibrium is approached, after a dose of gas is added to the cell containing the nanotubes. The measurements were performed at different fractional coverages limited to the first layer. The results indicate that, for a given coverage and temperature, the equilibration time is an increasing function of E/(k(B)T), where E is the binding energy of the adsorbate and k(B)T is the thermal energy. These findings are consistent with recent theoretical predictions and computer simulations results that we use to interpret the experimental measurements.

  15. Effective atomic numbers, electron densities and kinetic energy released in matter of vitamins for photon interaction

    Science.gov (United States)

    Shantappa, A.; Hanagodimath, S. M.

    2014-01-01

    Effective atomic numbers, electron densities of some vitamins (Retinol, Riboflavin, Niacin, Biotin, Folic acid, Cobalamin, Phylloquinone and Flavonoids) composed of C, H, O, N, Co, P and S have been calculated for total and partial photon interactions by the direct method for energy range 1 keV-100 GeV by using WinXCOM and kinetic energy released in matter (Kerma) relative to air is calculated in energy range of 1 keV-20 MeV. Change in effective atomic number and electron density with energy is calculated for all photon interactions. Variation of photon mass attenuation coefficients with energy are shown graphically only for total photon interaction. It is observed that change in mass attenuation coefficient with composition of different chemicals is very large below 100 keV and moderate between 100 keV and 10 MeV and negligible above 10 MeV. Behaviour of vitamins is almost indistinguishable except biotin and cobalamin because of large range of atomic numbers from 1(H) to 16 (S) and 1(H) to 27(Co) respectively. K a value shows a peak due to the photoelectric effect around K-absorption edge of high- Z constituent of compound for biotin and cobalamin.

  16. Effect of landing height on frontal plane kinematics, kinetics and energy dissipation at lower extremity joints.

    Science.gov (United States)

    Yeow, C H; Lee, P V S; Goh, J C H

    2009-08-25

    Lack of the necessary magnitude of energy dissipation by lower extremity joint muscles may be implicated in elevated impact stresses present during landing from greater heights. These increased stresses are experienced by supporting tissues like cartilage, ligaments and bones, thus aggravating injury risk. This study sought to investigate frontal plane kinematics, kinetics and energetics of lower extremity joints during landing from different heights. Eighteen male recreational athletes were instructed to perform drop-landing tasks from 0.3- to 0.6-m heights. Force plates and motion-capture system were used to capture ground reaction force and kinematics data, respectively. Joint moment was calculated using inverse dynamics. Joint power was computed as a product of joint moment and angular velocity. Work was defined as joint power integrated over time. Hip and knee joints delivered significantly greater joint power and eccentric work (phip joint in response to increasing landing height. Knee and hip joints acted as key contributors to total energy dissipation in the frontal plane with increase in peak ground reaction force (GRF). The hip joint was the top contributor to energy absorption, which indicated a hip-dominant strategy in the frontal plane in response to peak GRF during landing. Future studies should investigate joint motions that can maximize energy dissipation or reduce the need for energy dissipation in the frontal plane at the various joints, and to evaluate their effects on the attenuation of lower extremity injury risk during landing.

  17. Investigation of 234U(n,f) as a Function of Incident Neutron Energy

    Science.gov (United States)

    Al-Adili, A.; Hambsch, F.-J.; Oberstedt, S.; Pomp, S.

    2011-10-01

    Measurements of the reaction 234U(n,f) have been performed at incident neutron energies from 0.2 MeV to 5 MeV at the 7 MV Van De Graaf accelerator at IRMM. A twin Frisch-grid ionization chamber was used for fission-fragment detection. Parallel digital and analogue data acquisitions were applied in order to compare the two techniques. First results on the angular anisotropy and preliminary mass distributions are presented along with a first comparison between the two techniques.

  18. Theoretical model application to the evaluation of fission neutron data up to 20 MeV incidence energy

    International Nuclear Information System (INIS)

    Ruben, A.; Maerten, H.; Seeliger, D.

    1990-01-01

    A complex statistical theory of fission neutron emission combined with a phenomenological fission model has been used to calculate fission neutron data for 238 U. Obtained neutron multiplicities and energy spectra as well as average fragment energies for incidence energies from threshold to 20 MeV (including multiple-chance fission) are compared with traditional data representations. (author). 19 refs, 6 figs

  19. A Correction of Random Incidence Absorption Coefficients for the Angular Distribution of Acoustic Energy under Measurement Conditions

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2009-01-01

    Most acoustic measurements are based on an assumption of ideal conditions. One such ideal condition is a diffuse and reverberant field. In practice, a perfectly diffuse sound field cannot be achieved in a reverberation chamber. Uneven incident energy density under measurement conditions can cause...... discrepancies between the measured value and the theoretical random incidence absorption coefficient. Therefore the angular distribution of the incident acoustic energy onto an absorber sample should be taken into account. The angular distribution of the incident energy density was simulated using the beam...... tracing method for various room shapes and source positions. The averaged angular distribution is found to be similar to a Gaussian distribution. As a result, an angle-weighted absorption coefficient was proposed by considering the angular energy distribution to improve the agreement between...

  20. Kinetic-energy distributions of O- produced by dissociative electron attachment to physisorbed O2

    International Nuclear Information System (INIS)

    Huels, M.A.; Parenteau, L.; Michaud, M.; Sanche, L.

    1995-01-01

    We report measurements of the kinetic energy (E k ) distributions of O - produced by low-energy electron impact (5.5--19.5 eV) on disordered multilayers of O 2 physisorbed on a polycrystalline Pt substrate. The results confirm that dissociative electron attachment (DEA) proceeds via the formation of the 2 Π u , 2 Σ g + (I), and 2 Σ x + (II) (x=g and/or u) states of O 2 -* . We also find evidence for an additional resonance, namely the 2 Σ u + (I), positioned at about 10 eV above the neutral ground state in the Franck-Condon region, and dissociating into O - +O( 3 P). The measurements suggest that the autodetachment lifetimes of the 2 Σ u + (I) and 2 Σ g + (II) states may be longer than previously suggested. It is also observed that the effects of electron energy loss (EEL) in the solid prior to DEA, O - scattering in the solid after dissociation, and the charge-induced polarization energy of the solid, broaden the E k distributions, shift them to lower anion energies, and result in additional structure in them. The effects of EEL on the desorption dynamics of O - are estimated from high-resolution electron-energy-loss spectra and excitation functions for losses in the vicinity of the Schumann-Runge continuum of the physisorbed O 2 molecules. We find indications for an enhancement of the optically forbidden X 3 Σ g - →A 3 Σ u + transition, and observe that the gas-phase Rydberg bands, for energy losses above 7 eV, are not distinguishable in the condensed phase

  1. Energy analyses and drying kinetics of chamomile leaves in microwave-convective dryer

    Directory of Open Access Journals (Sweden)

    Ali Motevali

    2016-06-01

    Full Text Available Drying characteristics and energy aspects as well as mathematical modeling of thin layer drying kinetics of chamomile in a microwave-convective dryer are reported in this article. Drying experiments were carried out at 8 microwave power levels (200–900 W, air temperature of 50 °C, and air velocity of 0.5 m/s. Increasing the microwave output power from 200 to 900 W, decreased the drying time from 40 to 10 min. The drying process took place in the falling rate period. The Midilli et al. model showed the best fit to the experimental drying data. Moisture diffusivity values increase with decreasing moisture content down to 1.70 (kg water kg−1 dry matter but decrease with a further decrease in moisture content from 1.72 to 0.96 (kg water kg−1 dry matter. The average values of Deff increased with microwave power from 5.46 to 39.63 × 10−8 (m2 s−1. Energy consumption increased and energy efficiency decreased with moisture content of chamomile samples. Average specific energy consumption, energy efficiency and energy loss varied in the range 18.93–28.15 MJ kg−1 water, 8.25–13.07% and 16.79–26.01 MJ kg−1 water, respectively, while the best energy results were obtained at 400 W, 50 °C and 0.5 m s−1.

  2. Covalent bonds are created by the drive of electron waves to lower their kinetic energy through expansion

    Energy Technology Data Exchange (ETDEWEB)

    Schmidt, Michael W.; Ruedenberg, Klaus, E-mail: ruedenberg@iastate.edu [Department of Chemistry and Ames Laboratory USDOE, Iowa State University, Ames, Iowa 50011 (United States); Ivanic, Joseph [Advanced Biomedical Computing Center, Information Systems Program, Leidos Biomedical Research, Inc., Frederick National Laboratory for Cancer Research, Frederick, Maryland 21702 (United States)

    2014-05-28

    An analysis based on the variation principle shows that in the molecules H{sub 2}{sup +}, H{sub 2}, B{sub 2}, C{sub 2}, N{sub 2}, O{sub 2}, F{sub 2}, covalent bonding is driven by the attenuation of the kinetic energy that results from the delocalization of the electronic wave function. For molecular geometries around the equilibrium distance, two features of the wave function contribute to this delocalization: (i) Superposition of atomic orbitals extends the electronic wave function from one atom to two or more atoms; (ii) intra-atomic contraction of the atomic orbitals further increases the inter-atomic delocalization. The inter-atomic kinetic energy lowering that (perhaps counter-intuitively) is a consequence of the intra-atomic contractions drives these contractions (which per se would increase the energy). Since the contractions necessarily encompass both, the intra-atomic kinetic and potential energy changes (which add to a positive total), the fact that the intra-atomic potential energy change renders the total potential binding energy negative does not alter the fact that it is the kinetic delocalization energy that drives the bond formation.

  3. Covalent bonds are created by the drive of electron waves to lower their kinetic energy through expansion

    Science.gov (United States)

    Schmidt, Michael W.; Ivanic, Joseph; Ruedenberg, Klaus

    2014-05-01

    An analysis based on the variation principle shows that in the molecules H2+, H2, B2, C2, N2, O2, F2, covalent bonding is driven by the attenuation of the kinetic energy that results from the delocalization of the electronic wave function. For molecular geometries around the equilibrium distance, two features of the wave function contribute to this delocalization: (i) Superposition of atomic orbitals extends the electronic wave function from one atom to two or more atoms; (ii) intra-atomic contraction of the atomic orbitals further increases the inter-atomic delocalization. The inter-atomic kinetic energy lowering that (perhaps counter-intuitively) is a consequence of the intra-atomic contractions drives these contractions (which per se would increase the energy). Since the contractions necessarily encompass both, the intra-atomic kinetic and potential energy changes (which add to a positive total), the fact that the intra-atomic potential energy change renders the total potential binding energy negative does not alter the fact that it is the kinetic delocalization energy that drives the bond formation.

  4. Covalent bonds are created by the drive of electron waves to lower their kinetic energy through expansion

    Energy Technology Data Exchange (ETDEWEB)

    Schmidt, Michael W; Ivanic, Joseph; Ruedenberg, Klaus

    2014-05-28

    An analysis based on the variation principle shows that in the molecules H2 +, H2, B2, C2, N2, O2, F2, covalent bonding is driven by the attenuation of the kinetic energy that results from the delocalization of the electronic wave function. For molecular geometries around the equilibrium distance, two features of the wave function contribute to this delocalization: (i) Superposition of atomic orbitals extends the electronic wave function from one atom to two or more atoms; (ii) intra-atomic contraction of the atomic orbitals further increases the inter-atomic delocalization. The inter-atomic kinetic energy lowering that (perhaps counter-intuitively) is a consequence of the intra-atomic contractions drives these contractions (which per se would increase the energy). Since the contractions necessarily encompass both, the intra-atomic kinetic and potential energy changes (which add to a positive total), the fact that the intra-atomic potential energy change renders the total potential binding energy negative does not alter the fact that it is the kinetic delocalization energy that drives the bond formation.

  5. A flexible electrostatic kinetic energy harvester based on electret films of electrospun nanofibers

    Science.gov (United States)

    Lu, Y.; Capo-Chichi, M.; Leprince-Wang, Y.; Basset, P.

    2018-01-01

    This paper reports a paper-based electrostatic kinetic energy harvester (e-KEH) implementing multilayered electret films based on electrospun nanofibrous material. It is the first time that a fully flexible electret-based e-KEH is reported. The proposed electret, PVDF-PTFD nanofibrous covered by Parylene C, has a faster stabilization of surface potential than a planar thin film of Parylene C, and a higher stability of charge storage. With a maximum force of 0.5 N and a 3-layer electret, the device capacitance increases from 25 to 100 pF during a pressing operation. Working with the optimal resistive load of 16 MΩ, the device pressed manually delivers a peak instantaneous power up to 45.6 μW and an average energy of 54 nJ/stroke, corresponding to a peak instantaneous power density of 7.3 μW cm‑2 and an average energy density of 8.6 nJ cm‑2/stroke. Within 450 manual strokes, a 10 nF capacitor is charged up to 8.5 V by the prototype through a full-wave diode bridge. On a 1 μF capacitor, the energy delivery of 9.9 nJ/stroke has been obtained with a 10 Hz pressing movement excited by a vibrator with a maximum force of 0.5 N.

  6. Incident energy and charge deposition dependences of electron transmission through a microsized tapered glass capillary

    Energy Technology Data Exchange (ETDEWEB)

    Wickramarachchi, S.J. [Department of Physics, Western Michigan University, Kalamazoo, MI 49008 (United States); Ikeda, T. [RIKEN Nishina Center for Accelerator Based Science, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Dassanayake, B.S. [Department of Physics, Faculty of Science, University of Peradeniya (Sri Lanka); Keerthisinghe, D.; Tanis, J.A. [Department of Physics, Western Michigan University, Kalamazoo, MI 49008 (United States)

    2016-09-01

    An experimental study of electron transmission and guiding through a tapered glass capillary has been performed. Electrons were transmitted for tilt angles up to ∼6.5° and ∼9.5° (laboratory angles) for incident energies of 500 and 1000 eV, respectively. It is found that elastic and inelastic contributions give rise to distinguishable peaks in the transmitted profile. For 500 eV elastic transmission dominates the profile, while for 1000 eV both elastic and inelastic contributions are present. The transmission for both energies was studied as a function of the charge (time) deposition and found to be strongly dependent. Results suggest fundamental differences between 500 and 1000 eV incident electrons. For 500 eV the transmission slowly increases suggesting charge up of the capillary wall, reaching relative stability with infrequent breakdowns for all angles investigated. For 1000 eV for tilt angles near zero degrees the time dependent profile shows oscillations in the transmission, which never reached a stable condition, while for the larger angle investigated the transmission reached near equilibrium. Inelastic processes dominated the transmission for 1000 eV even at very small tilt angles, but was generally elastic (due to Coulomb deflection) for 500 eV even for the largest tilt angle measured.

  7. A subsynoptic-scale kinetic energy study of the Red River Valley tornado outbreak (AVE-SESAME 1)

    Science.gov (United States)

    Jedlovec, G. J.; Fuelberg, H. E.

    1981-01-01

    The subsynoptis-scale kinetic energy balance during the Red River Valley tornado outbreak is presented in order to diagnose storm environment interactions. Area-time averaged energetics indicate that horizontal flux convergence provides the major energy source to the region, while cross contour flow provides the greatest sink. Maximum energy variability is found in the upper levels in association with jet stream activity. Area averaged energetics at individual observation times show that the energy balance near times of maximum storm activity differs considerably from that of the remaining periods. The local kinetic energy balance over Oklahoma during the formation of a limited jet streak receives special attention. Cross contour production of energy is the dominant local source for jet development. Intense convection producing the Red River Valley tornadoes may have contributed to this local development by modifying the surrounding environment.

  8. Second crossover energy of insulating materials using stationary electron beam under normal incidence

    Energy Technology Data Exchange (ETDEWEB)

    Rau, E.I. [Institute of Microelectronics Technology of Russian Academy of Science, 142432 Chernogolovka, Moscow District (Russian Federation)], E-mail: rau@phys.msu.ru; Fakhfakh, S. [LaMaCop, Faculte des Sciences, Route Soukra km 3, BP 802, CP 3018 Sfax (Tunisia); Andrianov, M.V.; Evstafeva, E.N. [Institute of Microelectronics Technology of Russian Academy of Science, 142432 Chernogolovka, Moscow District (Russian Federation); Jbara, O. [UTAP/LASSI, EA 3802, Faculte des Sciences, BP 1039, 51687 Reims Cedex 2 (France)], E-mail: omar.jbara@univ-reims.fr; Rondot, S.; Mouze, D. [UTAP/LASSI, EA 3802, Faculte des Sciences, BP 1039, 51687 Reims Cedex 2 (France)

    2008-03-15

    The purpose of this paper is to give some aspects of charging effects on dielectric materials submitted to continuous electron beam irradiation in a scanning electron microscope (SEM). When the dielectric is irradiated continuously, the so-called total yield approach (TYA) used to predict the sign of the charge appeared on electron irradiated insulators fails because the charge accumulated in the dielectric interferes with the electrons emission processes. Based on previous experimental and theoretical works found in the literature, an analysis of the evolution of the electron yield curves {sigma} = f(E{sub 0}) of insulators during irradiation is given. The aim of this work is firstly to determine experimentally the second crossover energy E{sub 2C} under continuous electron irradiation (charging conditions) and secondly to demonstrate that the charge balance occurs at this beam energy and not at E{sub 2} the energy deduced from non-charging conditions (pulse primary electron beam experiments) as commonly asserted. It is however possible to apply the TYA by substituting the critical energy E{sub 2} for E{sub 2C}. The experimental procedure is based on simultaneous time dependent measurements of surface potential, leakage current and displacement current. The study underlines the difference between the landing energy of primary electrons E{sub L} at the steady state and the second crossover energy, E{sub 2C}, for charged samples. Some preliminary results are also obtained concerning the influence of the incident beam density on the energy E{sub 2C}. The samples used for this study are PMMA, polycrystalline silicone dioxide (p-SiO{sub 2}), polycrystalline alumina (p-Al{sub 2}O{sub 3}) and soda lime glass (SLG)

  9. Second crossover energy of insulating materials using stationary electron beam under normal incidence

    International Nuclear Information System (INIS)

    Rau, E.I.; Fakhfakh, S.; Andrianov, M.V.; Evstafeva, E.N.; Jbara, O.; Rondot, S.; Mouze, D.

    2008-01-01

    The purpose of this paper is to give some aspects of charging effects on dielectric materials submitted to continuous electron beam irradiation in a scanning electron microscope (SEM). When the dielectric is irradiated continuously, the so-called total yield approach (TYA) used to predict the sign of the charge appeared on electron irradiated insulators fails because the charge accumulated in the dielectric interferes with the electrons emission processes. Based on previous experimental and theoretical works found in the literature, an analysis of the evolution of the electron yield curves σ = f(E 0 ) of insulators during irradiation is given. The aim of this work is firstly to determine experimentally the second crossover energy E 2C under continuous electron irradiation (charging conditions) and secondly to demonstrate that the charge balance occurs at this beam energy and not at E 2 the energy deduced from non-charging conditions (pulse primary electron beam experiments) as commonly asserted. It is however possible to apply the TYA by substituting the critical energy E 2 for E 2C . The experimental procedure is based on simultaneous time dependent measurements of surface potential, leakage current and displacement current. The study underlines the difference between the landing energy of primary electrons E L at the steady state and the second crossover energy, E 2C , for charged samples. Some preliminary results are also obtained concerning the influence of the incident beam density on the energy E 2C . The samples used for this study are PMMA, polycrystalline silicone dioxide (p-SiO 2 ), polycrystalline alumina (p-Al 2 O 3 ) and soda lime glass (SLG)

  10. An efficient method for energy levels calculation using full symmetry and exact kinetic energy operator: Tetrahedral molecules

    Science.gov (United States)

    Nikitin, A. V.; Rey, M.; Tyuterev, Vl. G.

    2015-03-01

    A simultaneous use of the full molecular symmetry and of an exact kinetic energy operator (KEO) is of key importance for accurate predictions of vibrational levels at a high energy range from a potential energy surface (PES). An efficient method that permits a fast convergence of variational calculations would allow iterative optimization of the PES parameters using experimental data. In this work, we propose such a method applied to tetrahedral AB4 molecules for which a use of high symmetry is crucial for vibrational calculations. A symmetry-adapted contracted angular basis set for six redundant angles is introduced. Simple formulas using this basis set for explicit calculation of the angular matrix elements of KEO and PES are reported. The symmetric form (six redundant angles) of vibrational KEO without the sin(q)-2 type singularity is derived. The efficient recursive algorithm based on the tensorial formalism is used for the calculation of vibrational matrix elements. A good basis set convergence for the calculations of vibrational levels of the CH4 molecule is demonstrated.

  11. Report of the panel on the use of depleted uranium alloys for large caliber long rod kinetic energy penetrators

    International Nuclear Information System (INIS)

    Sandstrom, D.J.; Jessen, N.; Loewenstein, P.; Weirick, L.

    1980-01-01

    In early 1977 the National Materials Advisory Board, an operating unit in the Commission on Sociotechnical Systems of the National Research Council, NAS/NAE, formed a study committee on High Density Materials for Kinetic Energy Penetrators. The Specific objectives of the Committee were defined as follows. Assess the potential of two materials for use in kinetic energy penetrators, including such factors as: (a) properties (as applied to this application: strength, toughness, and dynamic behavior); (b) uniformity, reliability and reproducibility; (c) deterioration in storage; (d) production capability; (e) ecological impact; (f) quality assurance; (g) availability, and (h) cost. The Committee was divided into two Panels; one panel devoted to the study of tungsten alloys and the other devoted to the study of depleted uranium alloys for use in Kinetic energy penetrators. This report represents the findings and recommendation of the Panel on Uranium

  12. Effects of Neutron Emission on Fragment Mass and Kinetic Energy Distribution from Thermal Neutron-Induced Fission of 235U

    International Nuclear Information System (INIS)

    Montoya, M.; Rojas, J.; Saetone, E.

    2007-01-01

    The mass and kinetic energy distribution of nuclear fragments from thermal neutron-induced fission of 235 U(n th ,f) have been studied using a Monte-Carlo simulation. Besides reproducing the pronounced broadening in the standard deviation of the kinetic energy at the final fragment mass number around m = 109, our simulation also produces a second broadening around m = 125. These results are in good agreement with the experimental data obtained by Belhafaf et al. and other results on yield of mass. We conclude that the obtained results are a consequence of the characteristics of the neutron emission, the sharp variation in the primary fragment kinetic energy and mass yield curves. We show that because neutron emission is hazardous to make any conclusion on primary quantities distribution of fragments from experimental results on final quantities distributions

  13. Pseudo spectral collocation with Maxwell polynomials for kinetic equations with energy diffusion

    Science.gov (United States)

    Sánchez-Vizuet, Tonatiuh; Cerfon, Antoine J.

    2018-02-01

    We study the approximation and stability properties of a recently popularized discretization strategy for the speed variable in kinetic equations, based on pseudo-spectral collocation on a grid defined by the zeros of a non-standard family of orthogonal polynomials called Maxwell polynomials. Taking a one-dimensional equation describing energy diffusion due to Fokker–Planck collisions with a Maxwell–Boltzmann background distribution as the test bench for the performance of the scheme, we find that Maxwell based discretizations outperform other commonly used schemes in most situations, often by orders of magnitude. This provides a strong motivation for their use in high-dimensional gyrokinetic simulations. However, we also show that Maxwell based schemes are subject to a non-modal time stepping instability in their most straightforward implementation, so that special care must be given to the discrete representation of the linear operators in order to benefit from the advantages provided by Maxwell polynomials.

  14. Real-space grid representation of momentum and kinetic energy operators for electronic structure calculations.

    Science.gov (United States)

    Ninno, Domenico; Cantele, Giovanni; Trani, Fabio

    2018-03-08

    We show that the central finite difference formula for the first and the second derivative of a function can be derived, in the context of quantum mechanics, as matrix elements of the momentum and kinetic energy operators on discrete coordinate eigenkets |xn〉 defined on a uniform grid. Starting from the discretization of integrals involving canonical commutations, simple closed-form expressions of the matrix elements are obtained. A detailed analysis of the convergence toward the continuum limit with respect to both the grid spacing and the derivative approximation order is presented. It is shown that the convergence from below of the eigenvalues in electronic structure calculations is an intrinsic feature of the finite difference method. © 2018 Wiley Periodicals, Inc. © 2018 Wiley Periodicals, Inc.

  15. Releasable Kinetic Energy-Based Inertial Control of a DFIG Wind Power Plant

    DEFF Research Database (Denmark)

    Lee, Jinsik; Muljadi, Eduard; Sørensen, Poul Ejnar

    2016-01-01

    Wind turbine generators (WTGs) in a wind power plant (WPP) contain different levels of releasable kinetic energy (KE) because of the wake effects. This paper proposes a releasable KE-based inertial control scheme for a doubly fed induction generator (DFIG) WPP that differentiates the contributions...... of the WTGs depending on their stored KE. The proposed KE-based gain scheme aims to make use of the releasable KE in a WPP to raise the frequency nadir. To achieve this, two additional loops for the inertial control are implemented in each DFIG controller: the rate of change of frequency and droop loops....... The proposed scheme adjusts the two loop gains in a DFIG controller depending on its rotor speed so that a DFIG operating at a higher rotor speed releases more KE. The performance of the proposed scheme was investigated under various wind conditions. The results clearly indicate that the proposed scheme...

  16. Dietary Energy Density and Postmenopausal Breast Cancer Incidence in the Cancer Prevention Study II Nutrition Cohort.

    Science.gov (United States)

    Hartman, Terryl J; Gapstur, Susan M; Gaudet, Mia M; Shah, Roma; Flanders, W Dana; Wang, Ying; McCullough, Marjorie L

    2016-10-01

    Dietary energy density (ED) is a measure of diet quality that estimates the amount of energy per unit of food (kilocalories per gram) consumed. Low-ED diets are generally high in fiber and fruits and vegetables and low in fat. Dietary ED has been positively associated with body mass index (BMI) and other risk factors for postmenopausal breast cancer. We evaluated the associations of total dietary ED and energy-dense (high-ED) foods with postmenopausal breast cancer incidence. Analyses included 56,795 postmenopausal women from the Cancer Prevention Study II Nutrition Cohort with no previous history of breast or other cancers and who provided information on diet, lifestyle, and medical history in 1999. Multivariable-adjusted breast cancer incidence rate ratios (RRs and 95% CIs) were estimated for quintiles of total dietary ED and for the consumption of high-ED foods in Cox proportional hazards regression models. During a median follow-up of 11.7 y, 2509 invasive breast cancer cases were identified, including 1857 estrogen receptor-positive and 277 estrogen receptor-negative tumors. Median dietary ED was 1.5 kcal/g (IQR: 1.3-1.7 kcal/g). After adjusting for age, race, education, reproductive characteristics, and family history, high compared with low dietary ED was associated with a statistically significantly higher risk of breast cancer (RR for fifth quintile compared with first quintile: 1.20; 95% CI: 1.05, 1.36; P-trend = 0.03). The association between the amount of high-ED foods consumed and breast cancer risk was not statistically significant. We observed no differences by estrogen receptor status or effect modification by BMI, age, or physical activity. These results suggest a modest positive association between total dietary ED and risk of postmenopausal breast cancer. © 2016 American Society for Nutrition.

  17. Dynamics of entropy perturbations in assisted dark energy with mixed kinetic terms

    International Nuclear Information System (INIS)

    Karwan, Khamphee

    2011-01-01

    We study dynamics of entropy perturbations in the two-field assisted dark energy model. Based on the scenario of assisted dark energy, in which one scalar field is subdominant compared with the other in the early epoch, we show that the entropy perturbations in this two-field system tend to be constant on large scales in the early epoch and hence survive until the present era for a generic evolution of both fields during the radiation and matter eras. This behaviour of the entropy perturbations is preserved even when the fields are coupled via kinetic interaction. Since, for assisted dark energy, the subdominant field in the early epoch becomes dominant at late time, the entropy perturbations can significantly influence the dynamics of density perturbations in the universe. Assuming correlations between the entropy and curvature perturbations, the entropy perturbations can enhance the integrated Sachs-Wolfe (ISW) effect if the signs of the contributions from entropy perturbations and curvature perturbations are opposite after the matter era, otherwise the ISW contribution is suppressed. For canonical scalar field the effect of entropy perturbations on ISW effect is small because the initial value of the entropy perturbations estimated during inflation cannot be sufficiently large. However, in the case of k-essence, the initial value of the entropy perturbations can be large enough to affect the ISW effect to leave a significant imprint on the CMB power spectrum

  18. The kinetic and available potential energy budget of a winter extratropical cyclone system

    Science.gov (United States)

    Smith, P. J.; Dare, P. M.

    1986-01-01

    The energy budget of an extratropical cyclone system which traversed North America and intensified through the period January 9-11, 1975 is presented. The objectives of the study are: (1) to document the complete energy budget of a significant winter cyclone event, and (2) to comment on the significance of latent heat release (LHR) in the cyclone's evolution. Results reveal an overall increase in both kinetic (K) and available potential energy (A). K increases are accounted for by boundary flux convergence of K, while A increases are due to generation by LHR and K to A conversion. In addition, the general A increase is accompanied by a 24 h oscillation that is explained largely by the flux quantity in the A budget equation and is correlated with a similar fluctuation in the K to A conversion. LHR does not appear to be critical in the development of this cyclone system. Rather, LHR acts to increase the intensity of the event. It is hypothesized that the direct influence that LHR had on the deepening cyclone's reduced mass was augmented by an indirect influence, in which pre-existing dry dynamical forcing was enhanced by diabatic heating, thus leading to accelerated cyclone development at a later time.

  19. The energy landscape, folding pathways and the kinetics of a knotted protein.

    Directory of Open Access Journals (Sweden)

    Michael C Prentiss

    2010-07-01

    Full Text Available The folding pathway and rate coefficients of the folding of a knotted protein are calculated for a potential energy function with minimal energetic frustration. A kinetic transition network is constructed using the discrete path sampling approach, and the resulting potential energy surface is visualized by constructing disconnectivity graphs. Owing to topological constraints, the low-lying portion of the landscape consists of three distinct regions, corresponding to the native knotted state and to configurations where either the N or C terminus is not yet folded into the knot. The fastest folding pathways from denatured states exhibit early formation of the N terminus portion of the knot and a rate-determining step where the C terminus is incorporated. The low-lying minima with the N terminus knotted and the C terminus free therefore constitute an off-pathway intermediate for this model. The insertion of both the N and C termini into the knot occurs late in the folding process, creating large energy barriers that are the rate limiting steps in the folding process. When compared to other protein folding proteins of a similar length, this system folds over six orders of magnitude more slowly.

  20. Comminution of solids caused by kinetic energy of high shear strain rate, with implications for impact, shock, and shale fracturing.

    Science.gov (United States)

    Bazant, Zdenek P; Caner, Ferhun C

    2013-11-26

    Although there exists a vast literature on the dynamic comminution or fragmentation of rocks, concrete, metals, and ceramics, none of the known models suffices for macroscopic dynamic finite element analysis. This paper outlines the basic idea of the macroscopic model. Unlike static fracture, in which the driving force is the release of strain energy, here the essential idea is that the driving force of comminution under high-rate compression is the release of the local kinetic energy of shear strain rate. The density of this energy at strain rates >1,000/s is found to exceed the maximum possible strain energy density by orders of magnitude, making the strain energy irrelevant. It is shown that particle size is proportional to the -2/3 power of the shear strain rate and the 2/3 power of the interface fracture energy or interface shear stress, and that the comminution process is macroscopically equivalent to an apparent shear viscosity that is proportional (at constant interface stress) to the -1/3 power of this rate. A dimensionless indicator of the comminution intensity is formulated. The theory was inspired by noting that the local kinetic energy of shear strain rate plays a role analogous to the local kinetic energy of eddies in turbulent flow.

  1. Evolution of the Prompt Dipole γ-RAY Emission with Incident Energy in Fusion Reactions

    Science.gov (United States)

    Pierroutsakou, D.; Martin, B.; Inglima, G.; Boiano, A.; de Rosa, A.; di Pietro, M.; La Commara, M.; Mordente, R.; Romoli, M.; Sandoli, M.; Trotta, M.; Vardaci, E.; Glodariu, T.; Mazzocco, M.; Signorini, C.; Stroe, L.; Agodi, C.; Alba, R.; Colonna, M.; Coniglione, R.; Del Zoppo, A.; di Toro, M.; Maiolino, C.; Pellegriti, N.; Piattelli, P.; Santonocito, D.; Sapienza, P.; Cardella, G.; de Filippo, E.; Pagano, A.; Pirrone, S.; Baran, V.

    2005-12-01

    We studied the prompt dipole γ-ray emission, associated with entrance channel charge asymmetry effects, as a function of incident energy in the 32,36S + 100,96Mo (Elab=6 MeV/nucleon) and 36,40Ar + 96,92Zr fusion reactions (Elab= 16 and 15 MeV/nucleon, respectively). With the above reaction pairs the 132Ce compound nucleus was formed, from entrance channels having different charge asymmetries, at an excitation energy of 117 and 304 MeV with identical spin distribution. By studying the differential γ-ray multiplicity spectra related to the above fusion reactions, it was shown that at the higher compound nucleus excitation energy the Giant Dipole Resonance γ-ray intensity increases by ~14% for the more charge asymmetric system while at the lower one no difference between the data was seen within the experimental uncertainties. Calculations based on a collective bremsstrahlung analysis of the reaction dynamics are presented and compared with the experimental findings.

  2. Inner-shell excitation in heavy ion collisions up to intermediate incident energies

    International Nuclear Information System (INIS)

    Reus, T. de.

    1987-04-01

    Electronic excitations in collisions of very heavy ions with a total nuclear charge Z greater than 1/α ≅ 137 at bombarding energies reaching from 3.6 MeV/n up to 100 MeV/n are the subject of this thesis. The dynamical behaviour of the electron-positron-field is described within a semiclassical model, which is reviewed and extended to include electronic interactions via a mean field. A detailed comparison with experimental data of K-vacancy formation, δ-electron and positron emission shows an improved agreement compared with former calculations. Structures in spectra of positrons emitted in sub- and supercritical collision are discussed in two respects: Firstly as a signal of the vacuum decay in supercritical electromagnetic fields which evolve in the vicinity of long living giant nuclear molecules. Secondly as an atomic effect, which might be related to an instaneous formation of molecular 1sσ- and 2p 1/2 σ- levels. However, beyond this speculation the emission spectra of electrons and positrons in deep inelastic reactions have proven to be a powerful tool for measuring nuclear reaction or delay times in the order of 10 -21 s. This property was transfered to the domain of intermediate energy collisions. In first order perturbation theory we derived a scaling law, exhibiting how nuclear stopping times could be extracted from the emission spectra of high energetic δ-electrons. Quantitative calculations within a coupled channel code have been carried out for the system Pb+Pb, yielding cross sections of up to 20 nb for the emission of electrons with a kinetic energy of 50 MeV in 60 MeV/n-collisions. (orig./HSI)

  3. Neutron emission effects on fragment mass and kinetic energy distribution from fission of 239Pu induced by thermal neutrons

    International Nuclear Information System (INIS)

    Montoya, M.; Rojas, J.; Lobato, I.

    2010-01-01

    The average of fragment kinetic energy (E-bar sign*) and the multiplicity of prompt neutrons (ν(bar sign)) as a function of fragment mass (m*), as well as the fragment mass yield (Y(m*)) from thermal neutron-induced fission of 239 Pu have been measured by Tsuchiya et al.. In that work the mass and kinetic energy are calculated from the measured kinetic energy of one fragment and the difference of time of flight of the two complementary fragments. However they do not present their results about the standard deviation σ E *(m*). In this work we have made a numerical simulation of that experiment which reproduces its results, assuming an initial distribution of the primary fragment kinetic energy (E(A)) with a constant value of the standard deviation as function of fragment mass (σ E (A)). As a result of the simulation we obtain the dependence σ E *(m*) which presents an enhancement between m* = 92 and m* = 110, and a peak at m* = 121.

  4. Frequency Activated Fast Power Reserve for Wind Power Plant Delivered from Stored Kinetic Energy in the Wind Turbine Inertia

    DEFF Research Database (Denmark)

    Knüppel, Thyge; Thuring, P.; Kumar, S

    2011-01-01

    is proposed that delivers a short-term power reserve from the kinetic energy in the wind turbine (WT) inertia, while considering the inherent characteristics of a wind power plant. The aim is to contribute with a fast power reserve to stabilize the frequency drop during large and sudden production deficits...... and response characteristics, which have a large impact on the subsequent recovery period....

  5. Improved energy kinetics following high protein diet in McArdle's syndrome. A 31P magnetic resonance spectroscopy study

    DEFF Research Database (Denmark)

    Jensen, K E; Jakobsen, J; Thomsen, C

    1990-01-01

    A patient with McArdle's syndrome was examined using bicycle ergometry and 31P NMR spectroscopy during exercise. The patients working capacity was approximately half the expected capacity of controls. Muscle energy kinetics improved significantly during intravenous glucose infusion and after 6...

  6. Climatic variability of near-surface turbulent kinetic energy over the United States: implications for fire-weather predications

    Science.gov (United States)

    Warren E. Heilman; Xindi. Bain

    2013-01-01

    Recent research suggests that high levels of ambient near-surface atmospheric turbulence are often associated with rapid and sometimes erratic wildland fire spread that may eventually lead to large burn areas. Previous research has also examined the feasibility of using near-surface atmospheric turbulent kinetic energy (TKEs) alone or in...

  7. Climatic variability of a fire-weather index based on turbulent kinetic energy and the Haines Index

    Science.gov (United States)

    Warren E. Heilman; Xindi Bian

    2010-01-01

    Combining the Haines Index (HI) with near-surface turbulent kinetic energy (TKEs) through a product of the two values (HITKEs) has shown promise as an indicator of the atmospheric potential for extreme and erratic fire behavior in the U.S. Numerical simulations of fire-weather evolution during past wildland fire episodes in...

  8. Point-by-point model description of average prompt neutron data as a function of total kinetic energy of fission fragments

    International Nuclear Information System (INIS)

    Tudora, A.

    2013-01-01

    The experimental data of average prompt neutron multiplicity as a function of total kinetic energy of fragments <ν>(TKE) exhibit, especially in the case of 252 Cf(SF), different slopes dTKE/dν and different behaviours at low TKE values. The Point-by-Point (PbP) model can describe these different behaviours. The higher slope dTKE/dν and the flattening of <ν> at low TKE exhibited by a part of experimental data sets is very well reproduced when the PbP multi-parametric matrix ν(A,TKE) is averaged over a double distribution Y(A,TKE). The lower slope and the almost linear behaviour over the entire TKE range exhibited by other data sets is well described when the same matrix ν(A,TKE) is averaged over a single distribution Y(A). In the case of average prompt neutron energy in SCM as a function of TKE, different dTKE/dε slopes are also obtained by averaging the same PbP matrix ε(A,TKE) over Y(A,TKE) and over Y(A). The results are exemplified for 3 fissioning systems benefiting of experimental data as a function of TKE: 252 Cf(SF), 235 U(n th ,f) and 239 Pu(n th ,f). In the case of 234 U(n,f) for the first time it was possible to calculate <ν>(TKE) and <ε>(TKE) at many incident energies by averaging the PbP multi-parametric matrices over the experimental Y(A,TKE) distributions recently measured at IRMM for 14 incident energies in the range 0.3- 5 MeV. The results revealed that the slope dTKE/dν does not vary with the incident energy and the flattening of <ν> at low TKE values is more pronounced at low incident energies. The average model parameters dependences on TKE resulted from the PbP treatment allow the use of the most probable fragmentation approach, having the great advantage to provide results at many TKE values in a very short computing time compared to PbP and Monte Carlo treatments. (author)

  9. Critical analysis of major incidents risks in civil nuclear energy; Analyse critique des risques d'incidents majeurs dans l'energie nucleaire civile

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-09-01

    The differences existing between the PWR type reactors and the RBMK type reactors are explained as well as the risk associated to each type when it exists. The Ines scale, tool to give the level of an accident gravity comprises seven levels, the number seven is the most serious and corresponds to the Chernobyl accident; The number zero is of no consequence but must be mentioned as a matter of form. The incidents from 1 to 3 concern increasing incidents, affecting the nuclear power plant but not the external public. The accidents from 4 to 7 have a nature to affect the nuclear power plant and the environment. An efficient tool exists between nuclear operators it is made of the reports on incidents encountered by close reactors. Two others type reactors are coming, the high temperature type reactors and the fast neutrons reactors. different risks are evoked, terrorism, proliferation, transport and radioactive wastes. (N.C.)

  10. A code to determine the energy distribution, the incident energy and the flux of a beam of light ions into a stack of foils

    International Nuclear Information System (INIS)

    Sonzogni, A.A.; Romo, A.S.M.A.; Frosch, W.R.; Nassiff, S.J.

    1992-01-01

    The stacked-foil technique is one of the most used methods to obtain excitation functions of nuclear reactions using light ions as projectiles. The purpose of this program is the calculation of the energy of the beam in the stack, as well as to obtain the incident energy and the flux of the beam by using monitor excitation functions. (orig.)

  11. Jet energy loss in quark-gluon plasma. Kinetic theory with a Bhatnagar-Gross-Krook collisional kernel

    Energy Technology Data Exchange (ETDEWEB)

    Han, Cheng; Hou, De-fu; Li, Jia-rong [Central China Normal University, Key Laboratory of Quark and Lepton Physics (MOE) and Institute of Particle Physics, Wuhan, Hubei (China); Jiang, Bing-feng [Hubei University for Nationalities, Center for Theoretical Physics and School of Sciences, Enshi, Hubei (China)

    2017-10-15

    The dielectric functions ε{sub L}, ε{sub T} of the quark-gluon plasma (QGP) are derived within the framework of the kinetic theory with BGK-type collisional kernel. The collision effect manifested by the collision rate is encoded in the dielectric functions. Based on the derived dielectric functions we study the collisional energy loss suffered by a fast parton traveling through the QGP. The numerical results show that the collision rate increases the energy loss. (orig.)

  12. Molecular dynamics study of the nanosized droplet spreading: The effect of the contact line forces on the kinetic energy dissipation

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Hong Min [Department of Mechanical Engineering, Yonsei University, Seoul 120-749 (Korea, Republic of); Kondaraju, Sasidhar [Department of Mechanical Science, Indian Institute of Technology Bhubaneswar, Bhubaneswar, Odisha 751013 (India); Lee, Jung Shin [Department of Mechanical Engineering, Yonsei University, Seoul 120-749 (Korea, Republic of); Suh, Youngho; Lee, Joonho H. [Samsung Electronics, Mechatronics R& D Center, Hwaseong-si, Gyeonggi-do 445-330 (Korea, Republic of); Lee, Joon Sang, E-mail: joonlee@yonsei.ac.kr [Department of Mechanical Engineering, Yonsei University, Seoul 120-749 (Korea, Republic of)

    2017-07-01

    Highlights: • Contact line forces, including friction and spreading forces are directly calculated. • Overall trends of variations in contact line forces during droplet spreading process show characteristics of contact line forces. • Detail relations of contact line forces and atomic kinetics in the contact line provide a clear evidence of the possible energy dissipation mechanism in droplet spreading process. - Abstract: Recent studies have revealed that contact line forces play an important role in the droplet spreading process. Despite their significance, the physics related to them has been studied only indirectly and the effect of contact line forces is still being disputed. We performed a molecular dynamics simulation and mimicked the droplet spreading process at the nanoscale. Based on the results of the simulation, the contact line forces were directly calculated. We found that the forces acting on the bulk and the contact line region showed different trends. Distinct positive and negative forces, contact line spreading, and friction forces were observed near the contact line. We also observed a strong dependency of the atomic kinetics in the contact line region on the variations in the contact line forces. The atoms of the liquid in the contact line region lost their kinetic energy due to the contact line friction force and became partially immobile on the solid surface. The results of the current study will be useful for understanding the role of the contact line forces on the kinetic energy dissipation in the contact line region.

  13. A method for measurements of neutral fragments kinetic energies released to a specific dissociation threshold: optical translational spectroscopy

    International Nuclear Information System (INIS)

    Roney, A.; Frigon, C.; Larzilliere, M.

    1999-01-01

    The optical translational spectroscopy technique, based on the principles of fast ion beam laser spectroscopy (FIBLAS) and translational spectroscopy, allows the kinetic energies study of neutral fragments released through free dissociation of a neutral molecule. This method presents interesting features such as near-threshold energy measurements and selection of a specific dissociation limit. The fragments resulting from free dissociation (not induced) of neutral molecules, produced by charge exchange processes with a fast ion beam, are probed by laser radiation. Monitoring of the laser-induced fluorescence allows high-resolution spectra due to the kinematic compression of the velocity spread. Measurements of kinetic energies released to the second limit of dissociation H(1s) + H(2l) of H 2 are put forth and compared with those obtained by means of off-axis translational spectroscopy

  14. Attenuation of 10 MeV electron beam energy to achieve low doses does not affect Salmonella spp. inactivation kinetics

    International Nuclear Information System (INIS)

    Hieke, Anne-Sophie Charlotte; Pillai, Suresh D.

    2015-01-01

    The effect of attenuating the energy of a 10 MeV electron beam on Salmonella inactivation kinetics was investigated. No statistically significant differences were observed between the D 10 values of either Salmonella 4,[5],12:i:- or a Salmonella cocktail (S. 4,[5],12:i:-, Salmonella Heidelberg, Salmonella Newport, Salmonella Typhimurium, Salmonella) when irradiated with either a non-attenuated 10 MeV eBeam or an attenuated 10 MeV eBeam (~2.9±0.22 MeV). The results show that attenuating the energy of a 10 MeV eBeam to achieve low doses does not affect the inactivation kinetics of Salmonella spp. when compared to direct 10 MeV eBeam irradiation. - Highlights: • 10 MeV eBeam energy was attenuated to 2.9±0.22 MeV using HDPE sheets. • Attenuation of eBeam energy does not affect the inactivation kinetics of Salmonella. • Microbial inactivation is independent of eBeam energy in the range of 3–10 MeV

  15. Large-scale kinetic energy spectra from Eulerian analysis of EOLE wind data

    Science.gov (United States)

    Desbois, M.

    1975-01-01

    A data set of 56,000 winds determined from the horizontal displacements of EOLE balloons at the 200 mb level in the Southern Hemisphere during the period October 1971-February 1972 is utilized for the computation of planetary- and synoptic-scale kinetic energy space spectra. However, the random distribution of measurements in space and time presents some problems for the spectral analysis. Two different approaches are used, i.e., a harmonic analysis of daily wind values at equi-distant points obtained by space-time interpolation of the data, and a correlation method using the direct measurements. Both methods give similar results for small wavenumbers, but the second is more accurate for higher wavenumbers (k above or equal to 10). The spectra show a maximum at wavenumbers 5 and 6 due to baroclinic instability and then decrease for high wavenumbers up to wavenumber 35 (which is the limit of the analysis), according to the inverse power law k to the negative p, with p close to 3.

  16. Observations of the turbulent kinetic energy dissipation rate in the upper central South China Sea

    Science.gov (United States)

    Liang, Chang-Rong; Chen, Gui-Ying; Shang, Xiao-Dong

    2017-05-01

    Measurements of the turbulent kinetic energy dissipation rate ( ɛ), velocity, temperature, and salinity were obtained for the upper ocean of the central South China Sea (14.5° N, 117.0° E) during an experimental campaign from May 11 to 13, 2010. Dissipation in the diurnal mixed layer showed a diurnal variability that was strongly affected by the surface buoyancy flux. Dissipation was enhanced ( ɛ ˜ 10-7 W kg-1) at night due to the convective mixing and was weakened ( ɛ ˜ 10-9 W kg-1) in daytime due to the stratification. Dissipation in the thermocline varied with time under the influence of internal waves. Shear from high-frequency internal waves (period ˜8 h) played an important role in enhancing the turbulent mixing in the thermocline. In the period of strong high-frequency internal waves, the shear from high-frequency internal waves became strong and the depth-averaged ɛ in the thermocline was elevated by almost one order of magnitude. Compared with the dissipation in the thermocline, dissipation below was weaker (the time-averaged ɛ ˜ 10-10 W kg-1). The observation indicates that the dissipation rates during the measurements can be parameterized by the MacKinnon-Gregg model that is widely used in the continental shelf but are not in agreement with the Gregg-Henyey model used for the open ocean.

  17. Non-additive non-interacting kinetic energy of rare gas dimers.

    Science.gov (United States)

    Jiang, Kaili; Nafziger, Jonathan; Wasserman, Adam

    2018-03-14

    Approximations of the non-additive non-interacting kinetic energy (NAKE) as an explicit functional of the density are the basis of several electronic structure methods that provide improved computational efficiency over standard Kohn-Sham calculations. However, within most fragment-based formalisms, there is no unique exact NAKE, making it difficult to develop general, robust approximations for it. When adjustments are made to the embedding formalisms to guarantee uniqueness, approximate functionals may be more meaningfully compared to the exact unique NAKE. We use numerically accurate inversions to study the exact NAKE of several rare-gas dimers within partition density functional theory, a method that provides the uniqueness for the exact NAKE. We find that the NAKE decreases nearly exponentially with atomic separation for the rare-gas dimers. We compute the logarithmic derivative of the NAKE with respect to the bond length for our numerically accurate inversions as well as for several approximate NAKE functionals. We show that standard approximate NAKE functionals do not reproduce the correct behavior for this logarithmic derivative and propose two new NAKE functionals that do. The first of these is based on a re-parametrization of a conjoint Perdew-Burke-Ernzerhof (PBE) functional. The second is a simple, physically motivated non-decomposable NAKE functional that matches the asymptotic decay constant without fitting.

  18. Ballooning modes in the ELMO Bumpy Square configuration using the generalized kinetic energy principle

    International Nuclear Information System (INIS)

    Spong, D.A.

    1984-01-01

    In the bumpy square configuration, toroidal curvature is localized in the corner sections rather than uniformly distributed, as is the case in the existing circular ELMO Bumpy Torus (EBT) configuration. This feature, coupled with the fact that the magnetic field is higher in the corner sections, results in a number of distinct advantages with respect to particle confinement, heating, and transport. It might be expected, however, that ballooning modes should have some tendency to concentrate in the corner sections - especially along the outer field lines where the curvature and pressure gradients are unfavorable. Here we examine the stability of such a configuration using a ballooning mode equation derived from the generalized kinetic energy principle. The side and corner sections of the square are treated with a piecewise constant approximation and matched at a transition boundary to obtain the stability condition. This retains the ring-core coupling and yields both the low β/sub c/ diamagnetic well stabilization condition and a high-β/sub c/ stability limit analogous to the Lee-Van Dam-Nelson β/sub c/ limit, where β/sub c/ is the core plasma beta. Due to the high magnetic field in the corners and the relatively weak curvature there (approx. = 1/2 of the curvaure in the bumpy sections), this upper β/sub c/ limit is not significantly changed from that which would be present in the conventional circular bumpy torus configuration

  19. Energy resolution and efficiency of phonon-mediated kinetic inductance detectors for light detection

    Energy Technology Data Exchange (ETDEWEB)

    Cardani, L., E-mail: laura.cardani@roma1.infn.it [Dipartimento di Fisica, Sapienza Università di Roma, Piazzale Aldo Moro 2, 00185 Roma (Italy); Physics Department, Princeton University, Washington Road, 08544, Princeton, New Jersey (United States); Colantoni, I.; Coppolecchia, A. [Dipartimento di Fisica, Sapienza Università di Roma, Piazzale Aldo Moro 2, 00185 Roma (Italy); Cruciani, A.; Vignati, M.; Bellini, F.; Casali, N.; Cosmelli, C. [Dipartimento di Fisica, Sapienza Università di Roma, Piazzale Aldo Moro 2, 00185 Roma (Italy); INFN - Sezione di Roma, Piazzale Aldo Moro 2, 00185 Roma (Italy); Di Domizio, S. [Dipartimento di Fisica, Università degli Studi di Genova, Via Dodecaneso 33, 16146 Genova (Italy); INFN - Sezione di Genova, Via Dodecaneso 33, 16146 Genova (Italy); Castellano, M. G. [Istituto di Fotonica e Nanotecnologie - CNR, Via Cineto Romano 42, 00156 Roma (Italy); Tomei, C. [INFN - Sezione di Roma, Piazzale Aldo Moro 2, 00185 Roma (Italy)

    2015-08-31

    The development of sensitive cryogenic light detectors is of primary interest for bolometric experiments searching for rare events like dark matter interactions or neutrino-less double beta decay. Thanks to their good energy resolution and the natural multiplexed read-out, Kinetic Inductance Detectors (KIDs) are particularly suitable for this purpose. To efficiently couple KIDs-based light detectors to the large crystals used by the most advanced bolometric detectors, active surfaces of several cm{sup 2} are needed. For this reason, we are developing phonon-mediated detectors. In this paper, we present the results obtained with a prototype consisting of four 40 nm thick aluminum resonators patterned on a 2 × 2 cm{sup 2} silicon chip, and calibrated with optical pulses and X-rays. The detector features a noise resolution σ{sub E} = 154 ± 7 eV and an (18 ± 2)% efficiency.

  20. Total kinetic energy in four global eddying ocean circulation models and over 5000 current meter records

    KAUST Repository

    Scott, Robert B.

    2010-01-01

    We compare the total kinetic energy (TKE) in four global eddying ocean circulation simulations with a global dataset of over 5000, quality controlled, moored current meter records. At individual mooring sites, there was considerable scatter between models and observations that was greater than estimated statistical uncertainty. Averaging over all current meter records in various depth ranges, all four models had mean TKE within a factor of two of observations above 3500. m, and within a factor of three below 3500. m. With the exception of observations between 20 and 100. m, the models tended to straddle the observations. However, individual models had clear biases. The free running (no data assimilation) model biases were largest below 2000. m. Idealized simulations revealed that the parameterized bottom boundary layer tidal currents were not likely the source of the problem, but that reducing quadratic bottom drag coefficient may improve the fit with deep observations. Data assimilation clearly improved the model-observation comparison, especially below 2000. m, despite assimilated data existing mostly above this depth and only south of 47°N. Different diagnostics revealed different aspects of the comparison, though in general the models appeared to be in an eddying-regime with TKE that compared reasonably well with observations. © 2010 Elsevier Ltd.

  1. Mechanism of seasonal eddy kinetic energy variability in the eastern equatorial Pacific Ocean

    Science.gov (United States)

    Wang, Minyang; Du, Yan; Qiu, Bo; Cheng, Xuhua; Luo, Yiyong; Chen, Xiao; Feng, Ming

    2017-04-01

    Enhanced mesoscale eddy activities or tropical instability waves (TIWs) exist along the northern front of the cold tongue in the eastern equatorial Pacific Ocean. In this study, we investigate seasonal variability of eddy kinetic energy (EKE) over this region and its associated dynamic mechanism using a global, eddy-resolving ocean general circulation model (OGCM) simulation, the equatorial mooring data, and satellite altimeter observations. The seasonal-varying enhanced EKE signals are found to expand westward from 100°W in June to 180°W in December between 0°N and 6°N. This westward expansion in EKE is closely connected to the barotropically-baroclinically unstable zonal flows that are in thermal-wind balance with the seasonal-varying thermocline trough along 4°N. By adopting an 1½-layer reduced-gravity model, we confirm that the seasonal perturbation of the thermocline trough is dominated by the anticyclonic wind stress curl forcing, which develops due to southerly winds along 4°N from June to December.

  2. Kinetics and dynamics of near-resonant vibrational energy transfer in gas ensembles of atmospheric interest

    Science.gov (United States)

    McCaffery, Anthony J.

    2018-03-01

    This study of near-resonant, vibration-vibration (V-V) gas-phase energy transfer in diatomic molecules uses the theoretical/computational method, of Marsh & McCaffery (Marsh & McCaffery 2002 J. Chem. Phys. 117, 503 (doi:10.1063/1.1489998)) The method uses the angular momentum (AM) theoretical formalism to compute quantum-state populations within the component molecules of large, non-equilibrium, gas mixtures as the component species proceed to equilibration. Computed quantum-state populations are displayed in a number of formats that reveal the detailed mechanism of the near-resonant V-V process. Further, the evolution of quantum-state populations, for each species present, may be followed as the number of collision cycles increases, displaying the kinetics of evolution for each quantum state of the ensemble's molecules. These features are illustrated for ensembles containing vibrationally excited N2 in H2, O2 and N2 initially in their ground states. This article is part of the theme issue `Modern theoretical chemistry'.

  3. Exploring kinetic energy as a new marker of cardiac function in the single ventricle circulation.

    Science.gov (United States)

    Wong, James; Chabiniok, Radomir; Tibby, Shane M; Pushparajah, Kuberan; Sammut, Eva; Celermajer, David S; Giese, Daniel; Hussain, Tarique; Greil, Gerald F; Schaeffter, Tobias; Razavi, Reza

    2018-01-25

    Ventricular volumetric ejection fraction (VV EF) is often normal in patients with single ventricle circulations despite them experiencing symptoms related to circulatory failure. We sought to determine if kinetic energy (KE) could be a better marker of ventricular performance. KE was prospectively quantified using 4D flow MRI in 41 patients with a single ventricle circulation (aged 0.5 - 28 years) and compared to 43 healthy volunteers (aged 1.5 - 62 years) and 14 patients with left ventricular (LV) dysfunction (aged 28 - 79 years). Intraventricular end-diastolic blood was tracked through systole and divided into ejected and residual blood components. Two ejection fraction (EF) metrics were devised based on the KE of the ejected component over the total of both the ejected and residual components using: (1) instantaneous peak KE to assess KE EF or; (2) summating individual peak particle energy (PE) to assess PE EF. KE EF and PE EF had a smaller range than VV EF in healthy subjects (97.9 {plus minus} 0.8% vs. 97.3 {plus minus} 0.8% vs. 60.1 {plus minus} 5.2%). LV dysfunction caused a fall in KE EF (p =0.01) and PE EF (p =0.0001). VV EF in healthy LVs and single ventricle hearts was equivalent however KE EF and PE EF were lower (p <0.001) with a wider range indicating a spectrum of severity. Those reporting the greatest symptomatic impairment (NYHA II) had lower PE EF than asymptomatic subjects (p =0.0067). KE metrics are markers of healthy cardiac function. PE EF may be useful in grading dysfunction.

  4. Additivity of kinetic and potential energy contributions in modification of graphene supported on SiO2

    Science.gov (United States)

    Zhang, Xitong; Zhao, Shijun; Wang, Yuyu; Xue, Jianming

    2017-04-01

    The damage production induced by MeV highly charged ions (HCI) irradiations in graphene supported on a SiO2 substrate is investigated using molecular dynamics method. We get results in agreement with our recent experiments. We find that the electronic energy loss and potential energy deposition have similar effects on the defects creation in SiO2 substrate-supported graphene and both mechanisms of energy deposition seem to contribute in an additive way. The influences of the energy deposition depth and radius are studied. Only the energy deposited below the surface within 2.5 nm will induce the damage in graphene. Hence, the HCI can be a powerful tool to induce defects in graphene without causing deep damage of the substrate. When charge of incident Xeq+ is above 30, a nanopore is formed and the size of nanopore in graphene can be controlled by changing the incident charge state.

  5. Ventricular kinetic energy may provide a novel noninvasive way to assess ventricular performance in patients with repaired tetralogy of Fallot.

    Science.gov (United States)

    Jeong, Daniel; Anagnostopoulos, Petros V; Roldan-Alzate, Alejandro; Srinivasan, Shardha; Schiebler, Mark L; Wieben, Oliver; François, Christopher J

    2015-05-01

    Ventricular kinetic energy measurements may provide a novel imaging biomarker of declining ventricular efficiency in patients with repaired tetralogy of Fallot. Our purpose was to assess differences in ventricular kinetic energy with 4-dimensional flow magnetic resonance imaging between patients with repaired tetralogy of Fallot and healthy volunteers. Cardiac magnetic resonance, including 4-dimensional flow magnetic resonance imaging, was performed at rest in 10 subjects with repaired tetralogy of Fallot and 9 healthy volunteers using clinical 1.5T and 3T magnetic resonance imaging scanners. Right and left ventricular kinetic energy (KERV and KELV), main pulmonary artery flow (QMPA), and aortic flow (QAO) were quantified using 4-dimensional flow magnetic resonance imaging data. Right and left ventricular size and function were measured using standard cardiac magnetic resonance techniques. Differences in peak systolic KERV and KELV in addition to the QMPA/KERV and QAO/KELV ratios between groups were assessed. Kinetic energy indices were compared with conventional cardiac magnetic resonance parameters. Peak systolic KERV and KELV were higher in patients with repaired tetralogy of Fallot (6.06 ± 2.27 mJ and 3.55 ± 2.12 mJ, respectively) than in healthy volunteers (5.47 ± 2.52 mJ and 2.48 ± 0.75 mJ, respectively), but were not statistically significant (P = .65 and P = .47, respectively). The QMPA/KERV and QAO/KELV ratios were lower in patients with repaired tetralogy of Fallot (7.53 ± 5.37 mL/[cycle mJ] and 9.65 ± 6.61 mL/[cycle mJ], respectively) than in healthy volunteers (19.33 ± 18.52 mL/[cycle mJ] and 35.98 ± 7.66 mL/[cycle mJ], respectively; P tetralogy of Fallot. Quantification of ventricular kinetic energy in patients with repaired tetralogy of Fallot is a new observation. Future studies are needed to determine whether changes in ventricular kinetic energy can provide earlier evidence of ventricular dysfunction and guide future medical and

  6. The United States Department of Energy (DOE) Computerized Accident/Incident Reporting System (CAIRS)

    International Nuclear Information System (INIS)

    Briscoe, G.J.

    1993-01-01

    The Department of Energy's (DOE) Computerized Accident/Incident Reporting System (CAIRS) is a comprehensive data base containing more than 50,000 investigation reports of injury/illness, property damage and vehicle accident cases representing safety data from 1975 to the present for more than 150 DOE contractor organizations. A special feature is that the text of each accident report is translated using a controlled dictionary and rigid sentence structure called Factor Relationship and Sequence of Events (FRASE) that enhances the ability to retrieve specific types of information and to perform detailed analyses. DOE summary and individual contractor reports are prepared quarterly and annually. In addition, ''Safety Performance Profile'' reports for individual organizations are prepared to provide advance information to appraisal teams, and special topical reports are prepared for areas of concern such as an increase in the number of security injuries or environmental releases. The data base is open to all DOE and Contractor registered users with no access restrictions other than that required by the Privacy Act

  7. Calculation of nuclear data for incident energies to 200 MeV with the FKK-GNASH code system

    International Nuclear Information System (INIS)

    Chadwick, M.B.; Young, P.G.

    1993-02-01

    We describe how the FKK-GNASH code system has been extended to calculate nucleon-induced reactions up to 200 MeV, and used to predict (p,xn) and (p,xp) cross sections on 208 Pb at incident energies of 25, 45, 80 and 160 MeV, for an intermediate energy code intercomparison. Details of the reaction mechanisms calculated by FKK-GNASH are given, and the calculational procedure is described

  8. Plasma heating by kinetic Alfven wave

    International Nuclear Information System (INIS)

    Assis, A.S. de.

    1982-01-01

    The heating of a nonuniform plasma (electron-ion) due to the resonant excitation of the shear Alfven wave in the low β regime is studied using initially the ideal MHD model and posteriorly using the kinetic model. The Vlasov equation for ions and the drift kinetic equation for electrons have been used. Through the ideal MHD model, it is concluded that the energy absorption is due to the continuous spectrum (phase mixing) which the shear Alfven wave has in a nonuniform plasma. An explicit expression for the energy absorption is derived. Through the kinetic model it is concluded that the energy absorption is due to a resonant mode convertion of the incident wave into the kinetic Alfven wave which propagates away from the resonant region. Its electron Landau damping has been observed. There has been a concordance with the MHD calculations. (Author) [pt

  9. Pyrolysis Characteristics and Kinetics of Phoenix Tree Residues as a Potential Energy

    Directory of Open Access Journals (Sweden)

    H. Li

    2015-09-01

    Full Text Available By using a thermogravimetric analyser under argon atmosphere, the pyrolysis process and the kinetic model of phoenix tree residues (the little stem, middle stem, and leaf at a 30 °C min−1 heating rate and the phoenix tree mix at three different heating rates (10 °C min−1, 30 °C min−1, and 50 °C min−1 were examined. The catalyst and the co-pyrolysis samples were at a 30 °C min−1 heating rate. The catalysts were Na2CO3, ZnCl2 and CaO in a mass fraction of 5 %. The experimental results revealed that the phoenix tree residues pyrolysis process consisted of three stages: dehydration stage, main pyrolysis stage, and the slow decomposition of residues. As the heating rate increased, the pyrolysis characteristic temperature of the phoenix tree grew, there was a backward-shift of the pyrolysis rate curve, and the mass loss rate gradually increased. The phoenix tree residues’ activation energy changed throughout the whole pyrolysis process, and the pyrolysis temperature ranges of the three main components (cellulose, hemicellulose, and lignin existed in overlapping phenomenon. As compared to the little stem, middle stem, and leaf, the phoenix tree mix was more likely to be pyrolysed under the same heating rate. Different catalysts had a different impact on the pyrolysis: ZnCl2 moved the start point of the reaction to the lower temperatures, but did not speed up the reaction; Na2CO3 speeded up the reaction without changing the start point of the reaction; CaO speeded up the reaction, moved the start point of the reaction to higher temperatures.

  10. Observed near-inertial kinetic energy in the northwestern South China Sea

    Science.gov (United States)

    Chen, Gengxin; Xue, Huijie; Wang, Dongxiao; Xie, Qiang

    2013-10-01

    Based on more than 3 years of moored current-meter records, this study examined seasonal variability of near-inertial kinetic energy (NIKE) as well as all large (greater than one standard deviation from the mean) NIKE events related to storms and eddies in the northwestern South China Sea. The NIKE in the subsurface layer (30-450 m) exhibited obvious seasonal variability with larger values in autumn (herein defined as August, September, and October). All large NIKE events during the observation period were generated by passing storms. Most of the NIKE events had an e-folding timescale longer than 7 d. The phase velocity, vertical wavelength, and frequency shift of these events were examined. The maximum NIKE, induced by typhoon "Neoguri," was observed in April 2008. Normal mode analysis suggested that the combined effects of the first four modes determined the vertical distribution of NIKE with higher NIKE below 70 m but lower NIKE from 30 to 70 m. Another near-inertial oscillation event observed in August 2007 had the longest e-folding timescale of 13.5 d. Moreover, the NIKE propagated both upward and downward during this event. A ray-tracing model indicated that the smaller Brunt-Väisälä frequency and the stronger vertical shear of horizontal currents in an anticyclonic eddy and the near-inertial wave with larger horizontal scale facilitated the unusual propagation of the NIKE and the long decay timescale. Although the NIKE originated from wind, the water column structure affected by diverse oceanographic processes contributed substantially to its complex propagation and distribution.

  11. Extensive strain along gradient trajectories in the turbulent kinetic energy field

    Science.gov (United States)

    Gampert, Markus; Goebbert, Jens Henrik; Schaefer, Philip; Gauding, Michael; Peters, Norbert; Aldudak, Fettah; Oberlack, Martin

    2011-04-01

    Based on direct numerical simulations of forced turbulence, shear turbulence, decaying turbulence, a turbulent channel flow as well as a Kolmogorov flow with Taylor-based Reynolds numbers Reλ between 69 and 295, the normalized probability density function of the length distribution \\skew3\\tilde{P}(\\tilde{l}) of dissipation elements, the conditional mean scalar difference langΔkmidlrang at the extreme points as well as the scaling of the two-point velocity difference along gradient trajectories langΔunrang are studied. Using the field of the instantaneous turbulent kinetic energy k as a scalar, we find good agreement between the model equation for \\skew3\\tilde{P}(\\tilde{l}) as proposed by Wang and Peters (2008 J. Fluid Mech. 608 113-38) and the results obtained in the different direct numerical simulation cases. This confirms the independence of the model solution from both the Reynolds number and the type of turbulent flow, so that it can be considered universally valid. In addition, we show a 2/3 scaling for the mean conditional scalar difference. In the second part of the paper, we examine the scaling of the conditional two-point velocity difference along gradient trajectories. In particular, we compare the linear s/τ scaling, where τ denotes an integral time scale and s the separation arclength along a gradient trajectory in the inertial range as derived by Wang (2009 Phys. Rev. E 79 046325) with the s·a∞ scaling, where a∞ denotes the asymptotic value of the conditional mean strain rate of large dissipation elements.

  12. Influence of tall vegetation canopy on turbulence kinetic energy budget in the stable boundary layer

    Science.gov (United States)

    Babić, Karmen; Rotach, Mathias W.

    2017-04-01

    While a considerable amount of research has been done on turbulence kinetic energy (TKE) budget studies in the surface layer over horizontally homogeneous and flat (HHF) surfaces, little research focused on budgets above heterogeneous and rough surfaces. Only few studies have investigated TKE budgets above fetch-limited forest focusing on statically neutral conditions, while studies in the stable boundary layer (SBL) are still scarce in the literature. Therefore, we present turbulence characteristics above tall, deciduous forest in the wintertime SBL and make a comparison with a well-known results of HHF terrain. Turbulence measurements performed at five levels above the canopy height (approximately h = 18 m) allowed the investigation of combined influence of the roughness sublayer (RSL) found above tall vegetation and the internal boundary layer (IBL) on the TKE budget terms. Each term of the TKE budget is investigated within the framework of local similarity theory. Kolomogorov's similarity hypothesis assumes local isotropy within the inertial subrange. Testing the local isotropy hypothesis more thoroughly resulted in a ratio of the horizontal spectral densities (Sv/Su) approaching the 4/3, while the ratio of the vertical to the longitudinal spectral density (Sw/Su) was less than 1 for all levels indicating an anisotropic turbulence above the canopy. As a consequence, estimated values of TKE dissipation rate (ɛ) for the vertical component (ɛw) were smaller (underestimated) compared to the ɛ estimates obtained from the horizontal velocity components. This finding has a direct influence on the applicability of classical Kansas spectral models valid for HHF terrain as well as on the budget of wind variances. Additionally, the dimensionless wind shear function associated with "Kolmogorov turbulence" (existence of a well-defined inertial subrange with -5/3 slopes) was found to depart from linear prediction suggesting that the stability is a stronger determinant of

  13. Experimental study of the efficiency of transformation of the dense plasma hypersonic flow kinetic energy into a radiation

    International Nuclear Information System (INIS)

    Kamrukov, A.S.; Kozlov, N.P.; Myshelov, E.P.; Protasov, Yu.S.

    1981-01-01

    Analysis of physical specific features of radiator where plasma heating is performed with tbermalization of directed kinetic energy of dense plasma flows accelerated electrodynamically up to hypersonic velocities during its shock deceleration, is given. It is shown that the plasma heating method considered has a number of principle advantages as compared with methods most disseminated now for generation of dense intensively radiating plasma (current heating exploding method) and suggests new possibilities for construction of selective high brightness radiat.ion sources of ultraviolet and far vacuum ultraviolet ranges of spectrum. Radiation gas dynamic processes of hypersonic plasma flow deceleration formed with magnetoplasma compressors have been experimentally investigated on their interaction with condenced matters in vacuum and basic thermodynamic parameters of shock compressed plasma have been determined. It is shown that the conversion process of kinetic energy of high-velocity plasma flows to radiation is accomplished at very high efficiency-integral luminescence of shock compressed plasma can reach approximately 90% of initial kinetic energy of flow [ru

  14. Full-dimensional analytical potential energy surface describing the gas-phase Cl + C2H6 reaction and kinetics study of rate constants and kinetic isotope effects.

    Science.gov (United States)

    Rangel, Cipriano; Espinosa-Garcia, Joaquin

    2018-02-07

    Within the Born-Oppenheimer approximation a full-dimensional analytical potential energy surface, PES-2017, was developed for the gas-phase hydrogen abstraction reaction between the chlorine atom and ethane, which is a nine body system. This surface presents a valence-bond/molecular mechanics functional form dependent on 60 parameters and is fitted to high-level ab initio calculations. This reaction presents little exothermicity, -2.30 kcal mol -1 , with a low height barrier, 2.44 kcal mol -1 , and intermediate complexes in the entrance and exit channels. We found that the energetic description was strongly dependent on the ab initio level used and it presented a very flat topology in the entrance channel, which represents a theoretical challenge in the fitting process. In general, PES-2017 reproduces the ab initio information used as input, which is merely a test of self-consistency. As a first test of the quality of the PES-2017, a theoretical kinetics study was performed in the temperature range 200-1400 K using two approaches, i.e. the variational transition-state theory and quasi-classical trajectory calculations, with spin-orbit effects. The rate constants show reasonable agreement with experiments in the whole temperature range, with the largest differences at the lowest temperatures, and this behaviour agrees with previous theoretical studies, thus indicating the inherent difficulties in the theoretical simulation of the kinetics of the title reaction. Different sources of error were analysed, such as the limitations of the PES and theoretical methods, recrossing effects, and the tunnelling effect, which is negligible in this reaction, and the manner in which the spin-orbit effects were included in this non-relativistic study. We found that the variation of spin-orbit coupling along the reaction path, and the influence of the reactivity of the excited Cl( 2 P 1/2 ) state, have relative importance, but do not explain the whole discrepancy. Finally, the

  15. Neutron emission cross sections on 93Nb at 20 MeV incident energy

    International Nuclear Information System (INIS)

    Marcinkowski, A.; Kielan, D.

    1991-01-01

    Over the last years fully quantum-mechanical theories of nuclear reactions have been developed that provide, at least in principle, parameter-free methods of calculating double-differential continuum cross sections. The DWBA-based theory of direct processes to the continuum was derived by Tamura et al. The statistical theory of Feshback, Kerman and Koonin (FKK) introduced two reaction types in parallel as complementary mechanisms contributing to the preequilibrium decay. The multistep compound mechanism (MSC) results in symmetric angular distributions of the emitted particles, whereas the multistep direct mechanism (MSD) gives rise to the forward-peaked angular distributions. The theories of the MSC reactions differ in that the FKK theory incorporates the ''never come back'' hypothesis, which allowed the formulation of an applicable model that was successfully used in practical calculations. On the other hand the FKK theory of the MSD reactions differs conceptually from the theory of Tamura et al. and from the more general theory developed most recently by Nishioka et al. The latter theories were shown to be founded upon a postulated chaos located in the residual nucleus. In contrast, the theory of FKK assumes a chaotic interaction of the continuum particle to be emitted with the residual nucleus. The continuum or leading-particle statistics of the FKK theory results in the simple, convolution like, MSD cross section formula, which facilitates numerical calculations. Nevertheless two-step statistical DWBA calculations have been also performed. This paper extends the application of the FKK theory to the 93 Nb(n,xn) reaction at 20 MeV incident energy. (author). 14 refs, 1 fig

  16. Energy measurement of prompt fission neutrons in 239Pu(n,f) for incident neutron energies from 1 to 200 MeV

    CERN Document Server

    Chatillon, A; Granier, Th; Laurent, B; Taïeb, J; Noda, S; Haight, R C; Devlin, M; Nelson, R O; O’Donnell, J M

    2010-01-01

    Prompt fission neutron spectra in the neutron-induced fission of 239Pu have been measured for incident neutron energies from 1 to 200 MeV at the Los Alamos Neutron Science Center. Preliminary results are discussed and compared to theoretical model calculation.

  17. Free-Free Transitions in the Presence of Laser Fields and Debye Potential at Very Low Incident Electron Energies

    Science.gov (United States)

    Bhatia, Anand

    2012-01-01

    We study the free-free transition in electron-helium ion in the ground state and embedded in a Debye potential in the presence of an external laser field at very low incident electron energies. The laser field is treated classically while the collision dynamics is treated quantum mechanically. The laser field is chosen as monochromatic, linearly polarized and homogeneous. The incident electron is considered to be dressed by the laser field in a nonperturbative manner by choosing Volkov wave function for it. The scattering wave function for the incident electron on the target embedded in a Debye potential is solved numerically by taking into account the effect of electron exchange. We calculate the laser-assisted differential and total cross sections for free-free transition for absorption/emission of a single photon or no photon exchange. The results will be presented at the conference.

  18. Extension of a nuclear reaction calculation code CCONE toward higher incident energies. Multiple preequilibrium emission, and spectrum in laboratory system

    International Nuclear Information System (INIS)

    Iwamoto, Osamu

    2013-01-01

    A nuclear reaction calculation code CCONE, which was developed for nuclear data evaluation for JENDL/AC-2008 and JENDL-4, has been upgraded to improve the prediction accuracy for calculated cross sections at nucleon incident energies higher than 20 MeV. Multiple particle emission, in which nucleons and complex particles up to α-particle are involved, from pre-equilibrium reaction process was implemented based on the sequential-decay calculations for all produced exciton states within the framework of the two-component exciton model. The effect of velocity-change of particle-emitting nuclei on the multiple emission in preequilibrium and compound processes, which was not included in the previous evaluations, was taken into account to obtain spectra in the laboratory system using an average velocity approximation for each composite/compound nucleus. Calculated nucleon emission spectra at nucleon incident energies from 20 to 200 MeV were compared with experimental and evaluated data for the proton- and neutron-induced reactions on 27 Al. The present results are in good agreement with experimental data. It was found that their predictions were better than those of JENDL/HE-2007 especially for low emission energies at high incident energies. (author)

  19. Heat and turbulent kinetic energy budgets for surface layer cooling induced by the passage of Hurricane Frances (2004)

    Science.gov (United States)

    Huang, Peisheng; Sanford, Thomas B.; Imberger, JöRg

    2009-12-01

    Heat and turbulent kinetic energy budgets of the ocean surface layer during the passage of Hurricane Frances were examined using a three-dimensional hydrodynamic model. In situ data obtained with the Electromagnetic-Autonomous Profiling Explorer (EM-APEX) floats were used to set up the initial conditions of the model simulation and to compare to the simulation results. The spatial heat budgets reveal that during the hurricane passage, not only the entrainment in the bottom of surface mixed layer but also the horizontal water advection were important factors determining the spatial pattern of sea surface temperature. At the free surface, the hurricane-brought precipitation contributed a negligible amount to the air-sea heat exchange, but the precipitation produced a negative buoyancy flux in the surface layer that overwhelmed the instability induced by the heat loss to the atmosphere. Integrated over the domain within 400 km of the hurricane eye on day 245.71 of 2004, the rate of heat anomaly in the surface water was estimated to be about 0.45 PW (1 PW = 1015 W), with about 20% (0.09 PW in total) of this was due to the heat exchange at the air-sea interface, and almost all the remainder (0.36 PW) was downward transported by oceanic vertical mixing. Shear production was the major source of turbulent kinetic energy amounting 88.5% of the source of turbulent kinetic energy, while the rest (11.5%) was attributed to the wind stirring at sea surface. The increase of ocean potential energy due to vertical mixing represented 7.3% of the energy deposited by wind stress.

  20. Mineral solubility and free energy controls on microbial reaction kinetics: Application to contaminant transport in the subsurface

    Energy Technology Data Exchange (ETDEWEB)

    Taillefert, Martial [Georgia Inst. of Technology, Atlanta, GA (United States); Van Cappellen, Philippe [Univ. of Waterloo, ON (Canada)

    2016-11-14

    Recent developments in the theoretical treatment of geomicrobial reaction processes have resulted in the formulation of kinetic models that directly link the rates of microbial respiration and growth to the corresponding thermodynamic driving forces. The overall objective of this project was to verify and calibrate these kinetic models for the microbial reduction of uranium(VI) in geochemical conditions that mimic as much as possible field conditions. The approach combined modeling of bacterial processes using new bioenergetic rate laws, laboratory experiments to determine the bioavailability of uranium during uranium bioreduction, evaluation of microbial growth yield under energy-limited conditions using bioreactor experiments, competition experiments between metabolic processes in environmentally relevant conditions, and model applications at the field scale. The new kinetic descriptions of microbial U(VI) and Fe(III) reduction should replace those currently used in reactive transport models that couple catabolic energy generation and growth of microbial populations to the rates of biogeochemical redox processes. The above work was carried out in collaboration between the groups of Taillefert (batch reactor experiments and reaction modeling) at Georgia Tech and Van Cappellen (retentostat experiments and reactive transport modeling) at University of Waterloo (Canada).

  1. Kinetic study of low-temperature CO2 plasmas under non-equilibrium conditions. I. Relaxation of vibrational energy

    Science.gov (United States)

    Silva, T.; Grofulović, M.; Klarenaar, B. L. M.; Morillo-Candas, A. S.; Guaitella, O.; Engeln, R.; Pintassilgo, C. D.; Guerra, V.

    2018-01-01

    A kinetic model describing the time evolution of ∼70 individual CO2(X1Σ+) vibrational levels during the afterglow of a pulsed DC glow discharge is developed in order to contribute to the understanding of vibrational energy transfer in CO2 plasmas. The results of the simulations are compared against in situ Fourier transform infrared spectroscopy data obtained in a pulsed DC glow discharge and its afterglow at pressures of a few Torr and discharge currents of around 50 mA. The very good agreement between the model predictions and the experimental results validates the kinetic scheme considered here and the corresponding vibration–vibration and vibration–translation rate coefficients. In this sense, it establishes a reaction mechanism for the vibrational kinetics of these CO2 energy levels and offers a firm basis to understand the vibrational relaxation in CO2 plasmas. It is shown that first-order perturbation theories, namely, the Schwartz–Slawsky–Herzfeld and Sharma–Brau methods, provide a good description of CO2 vibrations under low excitation regimes.

  2. Search for high energy γ-rays emission in 28Si, 32Si+64Ni dissipative reactions at about 5 MeV/amu incident energy

    International Nuclear Information System (INIS)

    Agodi, C.; Alba, R.; Anzalone, A.; Coniglione, R.; Zoppo, A. del; Finocchiaro, P.; Maiolino, C.; Papa, M.; Piattelli, P.; Sapienza, P.; Wang, Q.; DeRosa, A.; Fioretto, E.; Inglima, G.; Romoli, M.; Sandoli, M.

    1991-01-01

    Photons emitted in the 28 Si+ 64 Ni and 32 S+ 64 Ni reactions at 143 MeV and 156 MeV incident energy respectively, have been detected in coincidence with the ejected charged fragments. An array of 48 BaF 2 γ-rays detector and 6 solid state silicon detector telescopes have been used. Photon energy spectra measured in the energy range from 2 to 20 MeV in coincidence with ejectiles coming from deep inelastic reactions, are consistent with statistical emission from the reaction products. (orig.)

  3. Search for high energy. gamma. -rays emission in sup 28 Si, sup 32 Si+ sup 64 Ni dissipative reactions at about 5 MeV/amu incident energy

    Energy Technology Data Exchange (ETDEWEB)

    Agodi, C.; Alba, R.; Anzalone, A.; Coniglione, R.; Zoppo, A. del; Finocchiaro, P.; Maiolino, C.; Papa, M.; Piattelli, P.; Sapienza, P.; Wang, Q. (Istituto Nazionale di Fisica Nucleare, Catania (Italy). Lab. Nazionale del Sud); Bellia, G.; Cavallaro, S.; Migneco, E.; Pappalardo, G.; Rizzo, F.; Russo, G. (Catania Univ. (Italy). Dipt. di Fisica Istituto Nazionale di Fisica Nucleare, Catania (Italy). Lab. Nazionale del Sud); Cardella, G.; Wang, G.S. (Istituto Nazionale di Fisica Nucleare, Catania (Italy)); DeRosa, A.; Fioretto, E.; Inglima, G.; Romoli, M.; Sandoli, M. (Naples-2 Univ. (Italy). Dipt. di Scienze Fisiche Istituto Nazionale di Fisica Nucleare, Naples (Italy))

    1991-11-01

    Photons emitted in the {sup 28}Si+{sup 64}Ni and {sup 32}S+{sup 64}Ni reactions at 143 MeV and 156 MeV incident energy respectively, have been detected in coincidence with the ejected charged fragments. An array of 48 BaF{sub 2} {gamma}-rays detector and 6 solid state silicon detector telescopes have been used. Photon energy spectra measured in the energy range from 2 to 20 MeV in coincidence with ejectiles coming from deep inelastic reactions, are consistent with statistical emission from the reaction products. (orig.).

  4. Kinetic Energy Losses and Efficiency of an Axial Turbine Stage in Numerical Modeling of Unsteady Flows

    Directory of Open Access Journals (Sweden)

    A. S. Laskin

    2015-01-01

    Full Text Available The article presents the results of numerical investigation of kinetic energy (KE loss and blading efficiency of the single-stage axial turbine under different operating conditions, characterized by the ratio u/C0. The calculations are performed by stationary (Stage method and nonstationary (Transient method methods using ANSYS CFX. The novelty of this work lies in the fact that the numerical simulation of steady and unsteady flows in a turbine stage is conducted, and the results are obtained to determine the loss of KE, both separately by the elements of the flow range and their total values, in the stage efficiency as well. The results obtained are compared with the calculated efficiency according to one-dimensional theory.To solve these problems was selected model of axial turbine stage with D/l = 13, blade profiles of rotor and stator of constant cross-section, similar to tested ones in inverted turbine when = 0.3. The degree of reactivity ρ = 0.27, the rotor speed was varied within the range 1000 ÷ 1800 rev/min.Results obtained allow us to draw the following conclusions:1. The level of averaged coefficients of total KE losses in the range of from 0.48 to 0.75 is from 18% to 21% when calculating by the Stage method and from 21% to 25% by the Transient one.2. The level of averaged coefficients of KE losses with the output speed of in the specified range is from 9% to 13%, and almost the same when in calculating by Stage and Transient methods.3. Levels of averaged coefficients of KE loss in blade tips (relative to the differential enthalpies per stage are changed in the range: from 4% to 3% (Stage and are stored to be equal to 5% (Transient; from 5% to 6% (Stage and from 6% to 8% (Transient.4. Coefficients of KE losses in blade tips GV and RB are higher in calculations of the model stage using the Transient method than the Stage one, respectively, by = 1.5 ÷ 2.5% and = 4 ÷ 5% of the absolute values. These are values to characterize the KE

  5. On the use of kinetic energy preserving DG-schemes for large eddy simulation

    Science.gov (United States)

    Flad, David; Gassner, Gregor

    2017-12-01

    -grid-scale models on top doesn't change much or in worst case decreases the fidelity even more. Finally, the core of this work is a novel LES strategy based on split form DG methods that are kinetic energy preserving. The scheme offers excellent stability with full control over the amount and shape of the added artificial dissipation. This premise is the main idea of the work and we will assess the LES capabilities of the novel split form DG approach when applied to shock-free, moderate Mach number turbulence. We will demonstrate that the novel DG LES strategy offers similar accuracy as the iLES methodology for well resolved cases, but strongly increases fidelity in case of more realistic coarse resolutions.

  6. Solar Sailing Kinetic Energy Interceptor (KEI) Mission for Impacting/Deflecting Near-Earth Asteroids

    Science.gov (United States)

    Wie, Bong

    2005-01-01

    A solar sailing mission architecture, which requires a t least ten 160-m, 300-kg solar sail spacecraft with a characteristic acceleration of 0.5 mm/sqs, is proposed as a realistic near- term option for mitigating the threat posed by near-Earth asteroids (NEAs). Its mission feasibility is demonstrated for a fictional asteroid mitigation problem created by AIAA. This problem assumes that a 200-m asteroid, designated 2004WR, was detected on July 4, 2004, and that the expected impact will occur on January 14, 2015. The solar sailing phase of the proposed mission for the AIAA asteroid mitigation problem is comprised of the initial cruise phase from 1 AU t o 0.25 AU (1.5 years), the cranking orbit phase (3.5 years), and the retrograde orbit phase (1 year) prior to impacting the target asteroid at its perihelion (0.75 AU from the sun) on January 1, 2012. The proposed mission will require at least ten kinetic energy interceptor (KEI) solar sail spacecraft. Each KEI sailcraft consists of a 160- m, 150-kg solar sail and a 150-kg microsatellite impactor. The impactor is to be separated from a large solar sail prior to impacting the 200-m target asteroid at its perihelion. Each 150-kg microsatellite impactor, with a relative impact velocity of at least 70 km/s, will cause a conservatively estimated AV of 0.3 cm/s in the trajectory of the 200-m target asteroid, due largely to the impulsive effect of material ejected from the newly-formed crater. The deflection caused by a single impactor will increase the Earth-miss-distance by 0.45Re (where Re denotes the Earth radius of 6,378 km). Therefore, at least ten KEI sailcraft will be required for consecutive impacts, but probably without causing fragmentation, to increase the total Earth-miss-distance by 4.5Re. This miss-distance increase of 29,000 km is outside of a typical uncertainty/error of about 10,000 km in predicting the Earth-miss- distance. A conventional Delta I1 2925 launch vehicle is capable of injecting at least two KEI

  7. Reshaping the Energy Landscape Transforms the Mechanism and Binding Kinetics of DNA Threading Intercalation.

    Science.gov (United States)

    Clark, Andrew G; Naufer, M Nabuan; Westerlund, Fredrik; Lincoln, Per; Rouzina, Ioulia; Paramanathan, Thayaparan; Williams, Mark C

    2018-02-06

    Molecules that bind DNA via threading intercalation show high binding affinity as well as slow dissociation kinetics, properties ideal for the development of anticancer drugs. To this end, it is critical to identify the specific molecular characteristics of threading intercalators that result in optimal DNA interactions. Using single-molecule techniques, we quantify the binding of a small metal-organic ruthenium threading intercalator (Δ,Δ-B) and compare its binding characteristics to a similar molecule with significantly larger threading moieties (Δ,Δ-P). The binding affinities of the two molecules are the same, while comparison of the binding kinetics reveals significantly faster kinetics for Δ,Δ-B. However, the kinetics is still much slower than that observed for conventional intercalators. Comparison of the two threading intercalators shows that the binding affinity is modulated independently by the intercalating section and the binding kinetics is modulated by the threading moiety. In order to thread DNA, Δ,Δ-P requires a "lock mechanism", in which a large length increase of the DNA duplex is required for both association and dissociation. In contrast, measurements of the force-dependent binding kinetics show that Δ,Δ-B requires a large DNA length increase for association but no length increase for dissociation from DNA. This contrasts strongly with conventional intercalators, for which almost no DNA length change is required for association but a large DNA length change must occur for dissociation. This result illustrates the fundamentally different mechanism of threading intercalation compared with conventional intercalation and will pave the way for the rational design of therapeutic drugs based on DNA threading intercalation.

  8. Study of the (16O,12C) reaction on even nickel isotopes at 60 MeV incident energy

    International Nuclear Information System (INIS)

    Berthier, B.

    1979-01-01

    Experimental results and Exact Finite Range DWBA analysis (EFR-DWBA) of ( 16 O, 12 C) transfer reactions on even nickel isotopes are presented. It is shown EFR-DWBA calculations which reproduce ( 16 O, 12 C) transfer data using optical model parameters deduced from elastic scattering analysis. The 58 Ni, 60 Ni, 62 Ni, 64 Ni( 16 O, 12 C) 62 Zn, 64 Zn, 66 Zn, 68 Zn reactions at 60 MeV incident energy leading to the ground state and the 2 + and 3 - low lying states in zinc isotopes and the 58 Ni, 60 Ni, 62 Ni, 64 Ni + 16 O elastic scattering at 60 MeV incident energy and 64 Zn, 66 Zn, 68 Zn + 12 C elastic scattering at 54 MeV in the range of scattering angles theta(c.m.)=17 0 - 100 0 have been measured

  9. Core-Shell Al-Polytetrafluoroethylene (PTFE) Configurations to Enhance Reaction Kinetics and Energy Performance for Nanoenergetic Materials.

    Science.gov (United States)

    Wang, Jun; Qiao, Zhiqiang; Yang, Yuntao; Shen, Jinpeng; Long, Zhang; Li, Zhaoqian; Cui, Xudong; Yang, Guangcheng

    2016-01-04

    The energy performance of solid energetic materials (Al, Mg, etc.) is typically restricted by a natural passivation layer and the diffusion-limited kinetics between the oxidizer and the metal. In this work, we use polytetrafluoroethylene (PTFE) as the fluorine carrier and the shielding layer to construct a new type of nano-Al based fuels. The PTFE shell not only prevents nano-Al layers from oxidation, but also assists in enhancing the reaction kinetics, greatly improving the stability and reactivity of fuels. An in situ chemical vapor deposition combined with the electrical explosion of wires (EEW) method is used to fabricate core-shell nanostructures. Studies show that by controlling the stoichiometric ratio of the precursors, the morphology of the PTFE shell and the energy performance can be easily tuned. The resultant composites exhibit superior energy output characters than that of their physically mixed Al/PTFE counterparts. This synthetic strategy might provide a general approach to prepare other high-energy fuels (Mg, Si). © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Theoretical modeling of energy redistribution and stereodynamics in CF scattering from Si(100) under grazing incidence

    NARCIS (Netherlands)

    Gou, F.; Gleeson, M. A.; Kleyn, A. W.

    2006-01-01

    We have simulated CF scattering from Si(100) using the molecular dynamics method. Translational energy loss spectra are presented. The shape of the energy loss distribution as a result of internal energy release is analyzed. At the classical turning point, the internal energy of the molecule is

  11. Separation-induced boundary layer transition: Modeling with a non-linear eddy-viscosity model coupled with the laminar kinetic energy equation

    International Nuclear Information System (INIS)

    Vlahostergios, Z.; Yakinthos, K.; Goulas, A.

    2009-01-01

    We present an effort to model the separation-induced transition on a flat plate with a semi-circular leading edge, using a cubic non-linear eddy-viscosity model combined with the laminar kinetic energy. A non-linear model, compared to a linear one, has the advantage to resolve the anisotropic behavior of the Reynolds-stresses in the near-wall region and it provides a more accurate expression for the generation of turbulence in the transport equation of the turbulence kinetic energy. Although in its original formulation the model is not able to accurately predict the separation-induced transition, the inclusion of the laminar kinetic energy increases its accuracy. The adoption of the laminar kinetic energy by the non-linear model is presented in detail, together with some additional modifications required for the adaption of the laminar kinetic energy into the basic concepts of the non-linear eddy-viscosity model. The computational results using the proposed combined model are shown together with the ones obtained using an isotropic linear eddy-viscosity model, which adopts also the laminar kinetic energy concept and in comparison with the existing experimental data.

  12. Inspection of 56Fe γ-Ray angular distributions as a function of incident neutron energy using optical model approaches

    Directory of Open Access Journals (Sweden)

    Vanhoy J.R.

    2017-01-01

    Full Text Available Neutron inelastic scattering cross sections measured directly through (n,n or deduced from γ-ray production cross sections following inelastic neutron scattering (n,n′γ are a focus of basic and applied research at the University of Kentucky Accelerator Laboratory (www.pa.uky.edu/accelerator. For nuclear data applications, angle-integrated cross sections are desired over a wide range of fast neutron energies. Several days of experimental beam time are required for a data set at each incident neutron energy, which limits the number of angular distributions that can be measured in a reasonable amount of time. Approximations can be employed to generate cross sections with a higher energy resolution, since at 125o, the a2P2 term of the Legendre expansion is identically zero and the a4P4 is assumed to be very small. Provided this assumption is true, a single measurement at 125o would produce the γ-ray production cross section. This project tests these assumptions and energy dependences using the codes CINDY/SCAT and TALYS/ECIS06/SCAT. It is found that care must be taken when interpreting γ-ray excitation functions as cross sections when the incident neutron energy is < 1000 keV above threshold or before the onset of feeding.

  13. Inspection of 56Fe γ-Ray angular distributions as a function of incident neutron energy using optical model approaches

    Science.gov (United States)

    Vanhoy, J. R.; Ramirez, A. P.; Alcorn-Dominguez, D. K.; Hicks, S. F.; Peters, E. E.; McEllistrem, M. T.; Mukhopadhyay, S.; Yates, S. W.

    2017-09-01

    Neutron inelastic scattering cross sections measured directly through (n,n) or deduced from γ-ray production cross sections following inelastic neutron scattering (n,n'γ) are a focus of basic and applied research at the University of Kentucky Accelerator Laboratory (www.pa.uky.edu/accelerator). For nuclear data applications, angle-integrated cross sections are desired over a wide range of fast neutron energies. Several days of experimental beam time are required for a data set at each incident neutron energy, which limits the number of angular distributions that can be measured in a reasonable amount of time. Approximations can be employed to generate cross sections with a higher energy resolution, since at 125o, the a2P2 term of the Legendre expansion is identically zero and the a4P4 is assumed to be very small. Provided this assumption is true, a single measurement at 125o would produce the γ-ray production cross section. This project tests these assumptions and energy dependences using the codes CINDY/SCAT and TALYS/ECIS06/SCAT. It is found that care must be taken when interpreting γ-ray excitation functions as cross sections when the incident neutron energy is < 1000 keV above threshold or before the onset of feeding.

  14. Coherent Pair Production by Photons in the 20-170 GeV Energy Range Incident on Crystals and Birefringence

    CERN Document Server

    Apyan, A.; Badelek, B.; Ballestrero, S.; Biino, C.; Birol, I.; Cenci, P.; Connell, S.H.; Eichblatt, S.; Fonseca, T.; Freund, A.; Gorini, B.; Groess, R.; Ispirian, K.; Ketel, T.J.; Kononets, Yu.V.; Lopez, A.; Mangiarotti, A.; van Rens, B.; Sellschop, J.P.F.; Shieh, M.; Sona, P.; Strakhovenko, V.; Uggerhoj, E.; Uggerhj, Ulrik Ingerslev; Unel, G.; Velasco, M.; Vilakazi, Z.Z.; Wessely, O.; Kononets, Yu.V.

    2003-01-01

    The cross section for coherent pair production by linearly polarised photons in the 20-170 GeV energy range was measured for photon aligned incidence on ultra-high quality diamond and germanium crystals. The theoretical description of coherent bremsstrahlung and coherent pair production phenomena is an area of active theoretical debate and development. However, under our experimental conditions, the theory predicted the combined cross section and polarisation experimental observables very well indeed. In macroscopic terms, our experiment measured a birefringence effect in pair production in a crystal. This study of this effect also constituted a measurement of the energy dependent linear polarisation of photons produced by coherent bremsstrahlung in aligned crystals. New technologies for manipulating high energy photon beams can be realised based on an improved understanding of QED phenomena at these energies. In particular, this experiment demonstrates an efficient new polarimetry technique. The pair product...

  15. High order magnetic optics for high dynamic range proton radiography at a kinetic energy of 800 MeV

    Energy Technology Data Exchange (ETDEWEB)

    Sjue, S. K. L., E-mail: sjue@lanl.gov; Mariam, F. G.; Merrill, F. E.; Morris, C. L.; Saunders, A. [Physics Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

    2016-01-15

    Flash radiography with 800 MeV kinetic energy protons at Los Alamos National Laboratory is an important experimental tool for investigations of dynamic material behavior driven by high explosives or pulsed power. The extraction of quantitative information about density fields in a dynamic experiment from proton generated images requires a high fidelity model of the proton imaging process. It is shown that accurate calculations of the transmission through the magnetic lens system require terms beyond second order for protons far from the tune energy. The approach used integrates the correlated multiple Coulomb scattering distribution simultaneously over the collimator and the image plane. Comparison with a series of static calibration images demonstrates the model’s accurate reproduction of both the transmission and blur over a wide range of tune energies in an inverse identity lens that consists of four quadrupole electromagnets.

  16. Review of kerma-area product and total energy incident on patients in radiography, mammography and CT

    International Nuclear Information System (INIS)

    Yao, Hai; He, Wenjun; Huda, Walter; Mah, Eugene

    2015-01-01

    This study estimated the energy incident on patients in radiography, mammography and CT using data related to X-ray beam quantity and quality. The total X-ray beam quantity is the average Air Kerma multiplied by the X-ray beam area and expressed as the Kerma-Area Product (Gy cm -2 ). The X-ray beam quality primarily depends on the target material (and anode angle), X-ray voltage (and ripple) as well as X-ray beam filtration. For any X-ray spectra, dividing total energy (fluence x mean energy) by the X-ray beam Kerma-Area Product yields the energy per Kerma-Area Product value (ε/KAP). Published data on X-ray spectra characteristics and energy fluence per Air Kerma conversion factors were used to determine 1/KAP factors. In radiography, ε/KAP increased from 6 mJ Gy -1 cm -2 at the lowest X-ray tube voltage (50 kV) to 25 mJ Gy -1 cm -2 at the highest X-ray tube voltage (140 kV). 1/KAP values ranged between 1 and 5 mJ Gy -1 cm -2 in mammography and between 24 and 42 mJ Gy -1 cm -2 in CT. Changes in waveform ripple resulted in variations in ε/KAP of up to 15 %, similar to the effect of changes resulting in the choice of anode angle. For monoenergetic X-ray photons, there was a sigmoidal-type increase in ε/KAP from 2 mJ Gy -1 cm -2 at 20 keV to 42 mJ Gy -1 cm -2 at 80 keV. However, between 80 and 150 keV, the ε/KAP shows variations with changing photon energy of <10 %. Taking the average spectrum energy to consist of monoenergetic X rays generally overestimates the true value of ε/KAP. This study illustrated that the energy incident on a patient in any area of radiological imaging can be estimated from the total X-ray beam intensity (KAP) when X-ray beam quality is taken into account. Energy incident on the patient can be used to estimate the energy absorbed by the patient and the corresponding patient effective dose. (authors)

  17. Turbulent kinetic energy budget in the boundary layer developing over an urban-like rough wall using PIV

    Science.gov (United States)

    Blackman, Karin; Perret, Laurent; Calmet, Isabelle; Rivet, Cédric

    2017-08-01

    In the present work, a boundary layer developing over a rough-wall consisting of staggered cubes with a plan area packing density λp = 25% is studied within the wind tunnel using Particle Image Velocimetry (PIV) to investigate the Turbulent Kinetic Energy (TKE) budget. To access the full TKE budget, an estimation of the dissipation (ɛ) using both the transport equation of the resolved-scale kinetic energy and Large-Eddy (LE) PIV models based on the use of a subgrid-scale model following the methodology used in large-eddy simulations is employed. A low-pass filter, larger than the Taylor microscale, is applied to the data prior to the computation of the velocity gradients ensuring a clear cutoff in the inertial range where the models are valid. The presence of the cube roughness elements has a significant influence on the TKE budget due to the region of strong shear that develops over the cubes. The shear layer is shown to produce and dissipate energy, as well as transport energy through advection, turbulent transport, and pressure transport. The recirculation region that forms through the interaction of the shear layer and the canopy layer, which is the region below the height of the cube roughness, creates rapid longitudinal evolution of the mean flow thereby inducing weak production. Finally, through stochastic estimation of the conditional average, it is shown that localized regions of backscatter (energy transfer from unresolved to resolved scales) and forward scatter (energy transfer from resolved to unresolved scales) occur as a result of coherent vortical structures.

  18. Controlling drug delivery kinetics from mesoporous titania thin films by pore size and surface energy

    Directory of Open Access Journals (Sweden)

    Karlsson J

    2015-07-01

    Full Text Available Johan Karlsson, Saba Atefyekta, Martin Andersson Department of Chemical and Biological Engineering, Chalmers University of Technology, Gothenburg, Sweden Abstract: The osseointegration capacity of bone-anchoring implants can be improved by the use of drugs that are administrated by an inbuilt drug delivery system. However, to attain superior control of drug delivery and to have the ability to administer drugs of varying size, including proteins, further material development of drug carriers is needed. Mesoporous materials have shown great potential in drug delivery applications to provide and maintain a drug concentration within the therapeutic window for the desired period of time. Moreover, drug delivery from coatings consisting of mesoporous titania has shown to be promising to improve healing of bone-anchoring implants. Here we report on how the delivery of an osteoporosis drug, alendronate, can be controlled by altering pore size and surface energy of mesoporous titania thin films. The pore size was varied from 3.4 nm to 7.2 nm by the use of different structure-directing templates and addition of a swelling agent. The surface energy was also altered by grafting dimethylsilane to the pore walls. The drug uptake and release profiles were monitored in situ using quartz crystal microbalance with dissipation (QCM-D and it was shown that both pore size and surface energy had a profound effect on both the adsorption and release kinetics of alendronate. The QCM-D data provided evidence that the drug delivery from mesoporous titania films is controlled by a binding–diffusion mechanism. The yielded knowledge of release kinetics is crucial in order to improve the in vivo tissue response associated to therapeutic treatments. Keywords: mesoporous titania, controlled drug delivery, release kinetics, alendronate, QCM-D

  19. Gas-phase reaction between calcium monocation and fluoromethane: Analysis of the potential energy hypersurface and kinetics calculations

    International Nuclear Information System (INIS)

    Varela-Alvarez, Adrian; Sordo, Jose A.; Rayon, V. M.; Redondo, P.; Barrientos, C.

    2009-01-01

    The gas-phase reaction between calcium monocation and fluoromethane: Ca + +CH 3 F→CaF + +CH 3 was theoretically analyzed. The potential energy hypersurface was explored by using density functional theory methodology with different functionals and Pople's, Dunning's, Ahlrichs', and Stuttgart-Dresden basis sets. Kinetics calculations (energy and total angular momentum resolved microcanonical variational/conventional theory) were accomplished. The theoretically predicted range for the global kinetic rate constant values at 295 K (7.2x10 -11 -5.9x10 -10 cm 3 molecule -1 s -1 ) agrees reasonably well with the experimental value at the same temperature [(2.6±0.8)x10 -10 cm 3 molecule -1 s -1 ]. Explicit consideration of a two transition state model, where the formation of a weakly bounded prereactive complex is preceded by an outer transition state (entrance channel) and followed by an inner transition state connecting with a second intermediate that finally leads to products, is mandatory. Experimental observations on the correlation, or lack of correlation, between reaction rate constants and second ionization energies of the metal might well be rationalized in terms of this two transition state model.

  20. Current-voltage and kinetic energy flux relations for relativistic field-aligned acceleration of auroral electrons

    Directory of Open Access Journals (Sweden)

    S. W. H. Cowley

    2006-03-01

    Full Text Available Recent spectroscopic observations of Jupiter's "main oval" auroras indicate that the primary auroral electron beam is routinely accelerated to energies of ~100 keV, and sometimes to several hundred keV, thus approaching the relativistic regime. This suggests the need to re-examine the classic non-relativistic theory of auroral electron acceleration by field-aligned electric fields first derived by Knight (1973, and to extend it to cover relativistic situations. In this paper we examine this problem for the case in which the source population is an isotropic Maxwellian, as also assumed by Knight, and derive exact analytic expressions for the field-aligned current density (number flux and kinetic energy flux of the accelerated population, for arbitrary initial electron temperature, acceleration potential, and field strength beneath the acceleration region. We examine the limiting behaviours of these expressions, their regimes of validity, and their implications for auroral acceleration in planetary magnetospheres (and like astrophysical systems. In particular, we show that for relativistic accelerating potentials, the current density increases as the square of the minimum potential, rather than linearly as in the non-relativistic regime, while the kinetic energy flux then increases as the cube of the potential, rather than as the square.

  1. Kinetic energy of Throughfall in subtropical forests of SE China - effects of tree canopy structure, functional traits, and biodiversity.

    Directory of Open Access Journals (Sweden)

    Christian Geißler

    Full Text Available Throughfall kinetic energy (TKE plays an important role in soil erosion in forests. We studied TKE as a function of biodiversity, functional diversity as well as structural stand variables in a secondary subtropical broad-leaved forest in the Gutianshan National Nature Reserve (GNNR in south-east China, a biodiversity hotspot in the northern hemisphere with more than 250 woody species present. Using a mixed model approach we could identify significant effects of all these variables on TKE: TKE increased with rarefied tree species richness and decreased with increasing proportion of needle-leaved species and increasing leaf area index (LAI. Furthermore, for average rainfall amounts TKE was decreasing with tree canopy height whereas for high rainfall amounts this was not the case. The spatial pattern of throughfall was stable across several rain events. The temporal variation of TKE decreased with rainfall intensity and increased with tree diversity. Our results show that more diverse forest stands over the season have to cope with higher cumulative raindrop energy than less diverse stands. However, the kinetic energy (KE of one single raindrop is less predictable in diverse stands since the variability in KE is higher. This paper is the first to contribute to the understanding of the ecosystem function of soil erosion prevention in diverse subtropical forests.

  2. From the Orbital Implementation of the Kinetic Theory to the Polarization Propagator Method in the Study of Energy Deposition Problems

    Science.gov (United States)

    Cabrera-Trujillo, R.; Cruz, S. A.; Soullard, J.

    The energy deposited by swift atomic-ion projectiles when colliding with a given target material has been a topic of special scientific interest for the last century due to the variety of applications of ion beams in modern materials technology as well as in medical physics. In this work, we summarize our contributions in this field as a consequence of fruitful discussions and enlightening ideas put forward by one of the main protagonists in stopping power theory during the last three decades: Jens Oddershede. Our review, mainly motivated by Jens' work, evolves from the extension of the orbital implementation of the kinetic theory of stopping through the orbital local plasma approximation, its use in studies of orbital and total mean excitation energies for the study of atomic and molecular stopping until the advances on generalized oscillator strength and sum rules in the study of stopping cross sections. Finally, as a tribute to Jens' work on the orbital implementation of the kinetic theory of stopping, in this work we present new results on the use of the Thomas-Fermi-Dirac-Weizsäcker density functional for the calculation of orbital and total atomic mean excitation energies. The results are applied to free-atoms and and extension is done to confined atoms - taking Si as an example - whereby target pressure effects on stopping are derived. Hence, evidence of the far-yield of Jens' ideas is given.

  3. A simultaneous measurement of the angular distribution, mass and kinetic energy of uranium-235 and thorium-232 fission fragments

    Science.gov (United States)

    El-Hajje, Refaat

    2000-10-01

    Simultaneous measurements of the angular distribution, mass distribution and average total kinetic energy of fission fragments produced by the neutron-induced fission of 235U and 232Th have been made using a gridded ionisation chamber. The neutron energy range used was thermal to 1.9 MeV for 235U and 1.4 to 1.7 MeV for 232Th. The following topics were investigated: the interdependence of the fission fragment angular and mass distribution; the anomalous behaviour of fragment anisotropy for 235U(n,f) at neutron energies En below 150 keV; the possible existence of a third symmetric mass peak for 232Th(n,f); the mass fine structure in 235 U(n,f) and 232Th(n,f); and the dependence of the fission fragment average total kinetic energy on the excitation energy of the fissioning nucleus. For this study, mono-energetic neutrons were produced by the L73i( p,n)74 Be and H31( p,n)31 He reactions. Four signals produced by the fission chamber were fed into a data acquisition system and processed by a specially modified comprehensive computer program. The results indicate that there is no interdependence between the angular and mass distributions of fragments for 235U(n,f) and for 232Th(n,f). The angular distribution of 235U fission fragments showed an anisotropy of less than one for En below 150 keV. For 232Th, the expected minimum in the anisotropy near En = 1.6 MeV was confirmed. No evidence for a third peak in the mass symmetry region of 232Th(n,f) was observed, within the yield sensitivity limitation of the chamber. Fine structure was observed in the mass yield distributions for 235U(n,f) and 232Th(n,f) at mass locations predicted by theory. The fission fragment average total kinetic energy for 235U(n,f) and 232Th(n,f) showed no significant dependence on the excitation energy of the fissioning nucleus. Possible reasons for some of these results are advanced.

  4. Hybrid Fluid/Kinetic Modeling Of Magnetized High Energy Density Plasmas

    Science.gov (United States)

    Hansen, David; Held, Eric; King, Jacob; Stoltz, Peter; Masti, Robert; Srinivasan, Bhuvana

    2017-10-01

    MHD modeling with an equation of state (EOS) of the Rayleigh-Taylor (RT) instabily in Z indicates that it is seeded by the electro-thermal instability. Large thermodynamic drives associated with gradients at the interface between the liner and the coronal regions distort distribution functions and likely lead to non-local transport effects in a plasma which varies from weakly to strongly coupled. In this work, we discuss using effective potential theory along with a Chapman-Ensksog-like (CEL) formalism to develop hybrid fluid/kinetic modeling capabilities for these plasmas. Effective potential theory addresses the role of Coulomb collisions on transport across coupling regimes and the CEL approach bridges the gap between full-blow kinetic simulations and the EOS tables, which only depend locally on density and temperature. Quantitative results on the Spitzer problem across coupling coupling regimes will be presented as a first step. DOE Grant No. DE-SC0016525.

  5. Implosion anisotropy of neutron kinetic energy distributions as measured with the neutron time-of-flight diagnostics at the National Ignition Facility

    Science.gov (United States)

    Hartouni, Edward; Eckart, Mark; Field, John; Grim, Gary; Hatarik, Robert; Moore, Alastair; Munro, David; Sayer, Daniel; Schlossberg, David

    2017-10-01

    Neutron kinetic energy distributions from fusion reactions are characterized predominantly by the excess energy, Q, of the fusion reaction and the variance of kinetic energy which is related to the thermal temperature of the plasma as shown by e.g. Brysk. High statistics, high quality neutron time-of-flight spectra obtained at the National Ignition Facility provide a means of measuring small changes to the neutron kinetic energy due to the spatial and temporal distribution of plasma temperature, density and velocity. The modifications to the neutron kinetic energy distribution as described by Munro include plasma velocity terms with spatial orientation, suggesting that the neutron kinetic energy distributions could be anisotropic when viewed by multiple lines-of-sight. These anisotropies provide a diagnostic of burn averaged plasma velocity distributions. We present the results of measurements made for a variety of DT implosions and discuss their possible physical interpretations. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344. Lawrence Livermore National Security, LLC.

  6. Variation of energy absorption and exposure buildup factors with incident photon energy and penetration depth for boro-tellurite (B2O3-TeO2) glasses

    Science.gov (United States)

    Sayyed, M. I.; Elhouichet, H.

    2017-01-01

    The gamma ray energy absorption (EABF) and exposure buildup factors (EBF) of (100-x)TeO2-xB2O3 glass systems (where x=5, 10, 15, 20, 22.5 and 25 mol%) have been calculated in the energy region 0.015-15 MeV up to a penetration depth of 40 mfp (mean free path). The five parameters (G-P) fitting method has been used to estimate both EABF and EBF values. Variations of EABF and EBF with incident photon energy and penetration depth have been studied. It was found that EABF and EBF values were higher in the intermediate energy region, for all the glass systems. Furthermore, boro-tellurite glass with 5 mol% B2O3, was found to present the lowest EABF and EBF values, hence it is superior gamma-ray shielding material. The results indicate that the boro-tellurite glasses can be used as radiation shielding materials.

  7. Energy

    CERN Document Server

    Foland, Andrew Dean

    2007-01-01

    Energy is the central concept of physics. Unable to be created or destroyed but transformable from one form to another, energy ultimately determines what is and isn''t possible in our universe. This book gives readers an appreciation for the limits of energy and the quantities of energy in the world around them. This fascinating book explores the major forms of energy: kinetic, potential, electrical, chemical, thermal, and nuclear.

  8. Effective energies and exposure determinations of two different energy X-ray beams incident on a personnel monitor

    International Nuclear Information System (INIS)

    Okuno, E.; Cruz, M.T. da

    1984-01-01

    The effective energy of one X or gamma ray beam can be determined by means of two thermoluminescent (TL) dosemeters mounted between suitable filters. However, it has been observed that personnel monitors exposed to two different energy ionizing radiations provide different effective energies depeding on the type of TL phosphor used. This fact could be a powerful tool for identifying exposures to radiation with quite different effective energies which are very common in practice. Two types of TL dosemeters were used : pellets of cold pressed natural fluoride and NaCl developed in our own laboratory, and LiF, TLD-100 from Harshaw Chemical Co.. Experimental results obtained with these combined dosemeters after irradiation with different sets of exposures and energy values of ionizing radiations are also presented. (Author) [pt

  9. Altered Right Ventricular Kinetic Energy Work Density and Viscous Energy Dissipation in Patients with Pulmonary Arterial Hypertension: A Pilot Study Using 4D Flow MRI.

    Directory of Open Access Journals (Sweden)

    Q Joyce Han

    Full Text Available Right ventricular (RV function has increasingly being recognized as an important predictor for morbidity and mortality in patients with pulmonary arterial hypertension (PAH. The increased RV after-load increase RV work in PAH. We used time-resolved 3D phase contrast MRI (4D flow MRI to derive RV kinetic energy (KE work density and energy loss in the pulmonary artery (PA to better characterize RV work in PAH patients.4D flow and standard cardiac cine images were obtained in ten functional class I/II patients with PAH and nine healthy subjects. For each individual, we calculated the RV KE work density and the amount of viscous dissipation in the PA.PAH patients had alterations in flow patterns in both the RV and the PA compared to healthy subjects. PAH subjects had significantly higher RV KE work density than healthy subjects (94.7±33.7 mJ/mL vs. 61.7±14.8 mJ/mL, p = 0.007 as well as a much greater percent PA energy loss (21.1±6.4% vs. 2.2±1.3%, p = 0.0001 throughout the cardiac cycle. RV KE work density and percent PA energy loss had mild and moderate correlations with RV ejection fraction.This study has quantified two kinetic energy metrics to assess RV function using 4D flow. RV KE work density and PA viscous energy loss not only distinguished healthy subjects from patients, but also provided distinction amongst PAH patients. These metrics hold promise as imaging markers for RV function.

  10. Altered Right Ventricular Kinetic Energy Work Density and Viscous Energy Dissipation in Patients with Pulmonary Arterial Hypertension: A Pilot Study Using 4D Flow MRI.

    Science.gov (United States)

    Han, Q Joyce; Witschey, Walter R T; Fang-Yen, Christopher M; Arkles, Jeffrey S; Barker, Alex J; Forfia, Paul R; Han, Yuchi

    2015-01-01

    Right ventricular (RV) function has increasingly being recognized as an important predictor for morbidity and mortality in patients with pulmonary arterial hypertension (PAH). The increased RV after-load increase RV work in PAH. We used time-resolved 3D phase contrast MRI (4D flow MRI) to derive RV kinetic energy (KE) work density and energy loss in the pulmonary artery (PA) to better characterize RV work in PAH patients. 4D flow and standard cardiac cine images were obtained in ten functional class I/II patients with PAH and nine healthy subjects. For each individual, we calculated the RV KE work density and the amount of viscous dissipation in the PA. PAH patients had alterations in flow patterns in both the RV and the PA compared to healthy subjects. PAH subjects had significantly higher RV KE work density than healthy subjects (94.7±33.7 mJ/mL vs. 61.7±14.8 mJ/mL, p = 0.007) as well as a much greater percent PA energy loss (21.1±6.4% vs. 2.2±1.3%, p = 0.0001) throughout the cardiac cycle. RV KE work density and percent PA energy loss had mild and moderate correlations with RV ejection fraction. This study has quantified two kinetic energy metrics to assess RV function using 4D flow. RV KE work density and PA viscous energy loss not only distinguished healthy subjects from patients, but also provided distinction amongst PAH patients. These metrics hold promise as imaging markers for RV function.

  11. Prompt Dipole gamma -Ray Emission in Fusion Heavy-Ion Collisions: Incident Energy Dependence

    Science.gov (United States)

    Martin, B.; Pierroutsakou, D.; Inglima, G.; Boiano, A.; de Rosa, A.; La Commara, M.; Romoli, M.; Sandoli, M.; Agodi, C.; Alba, R.; Coniglione, R.; Del Zoppo, A.; Maiolino, C.; Piattelli, P.; Santonocito, D.; Sapienza, P.; Cardella, G.; de Filippo, E.; Pagano, A.; Pirrone, S.; Glodariu, T.; Mazzocco, M.; Signorini, C.

    2007-04-01

    The evolution with beam energy of the prompt dipole radiation, related with entrance channel charge asymmetry effects, was studied in the fusion reactions: 36Ar+96Zr and 40Ar+92Zr at Elab=16 and 15.1 MeV/u, respectively. Both reactions populate, through entrance channels having different charge asymmetries, the same compound nucleus at the same average excitation energy and with identical spin distribution. By studying the gamma -ray energy spectra of the considered reactions, and by comparing the present result with previous ones obtained at lower energies, we deduce that the prompt dipole gamma -ray emission presents a maximum value at 9 MeV/u and decreases toward lower and higher energies. Moreover, the centroid and the width of the preequilibrium dipole component were found to remain constant, within the errors, by increasing the beam energy.

  12. Measurement of double differential cross sections of secondary neutrons in the incident energy range 9-13 MeV

    International Nuclear Information System (INIS)

    Tang Hongqing; Qi Bujia; Zhou Zuying; Sa Jun; Ke Zunjian; Sui Qingchang; Xia Haihong; Shen Guanren

    1992-01-01

    The status and technique of double differential cross section measurement of secondary neutrons in the incident neutron energy range 9 to 13 MeV is reviewed with emphasis on the work done at CIAE. There are scarce measurements of secondary neutron double differential cross sections in this energy region up to now. A main difficulty for this is lack of an applicable monoenergetic neutron source. When monoenergetic neutron energy reaches 8 Me/v, the break-up neutrons from the d + D or p + T reaction starts to become significant. It is difficult to get a pure secondary neutron spectrum induced only by monoenergetic neutrons. To solve this problem an abnormal fast neutron TOF facility was designed and tested. Double differential neutron emission cross sections of 238 U and 209 Bi at 10 MeV were obtained by combining the data measured by both normal and abnormal TOF spectrometers and a good agreement between measurement and calculation was achieved

  13. Preliminary proposals for extending the ENDF format to allow incident charged particles and energy-angle correlation for emitted particles

    International Nuclear Information System (INIS)

    MacFarlane, R.E.; Stewart, L.; Hale, G.M.; Dunford, C.L.

    1984-04-01

    This rewrite of Data Formats and Procedures for the Evaluated Nuclear Data File, ENDF pertains to the latest version, ENDF/B-VI. Earlier versions provided representations for neutron cross sections and distributions, photon production from neutron reactions, a limited amount of charged-particle production from neutron reactions, photo-atomic interaction data, thermal neutron scattering data, and radionuclide production and decay data (including fission products). This version allows higher incident energies, adds more complete descriptions of the distributions of emitted particles, and provides for incident charged particles and photo-nuclear data by partitioning the ENDF library into sublibraries. Decay data, fission product yield data, thermal scattering data, and photo-atomic data have also been formally placed in sublibraries. In addition, this rewrite represents an extensive update to the Version V manual

  14. Energy and Protein Supplementation Does Not Affect Protein and Amino Acid Kinetics or Pregnancy Outcomes in Underweight Indian Women.

    Science.gov (United States)

    Dwarkanath, Pratibha; Hsu, Jean W; Tang, Grace J; Anand, Pauline; Thomas, Tinku; Thomas, Annamma; Sheela, C N; Kurpad, Anura V; Jahoor, Farook

    2016-02-01

    In India, the prevalence of low birth weight is high in women with a low body mass index (BMI), suggesting that underweight women are not capable of providing adequate energy and protein for fetal growth. Furthermore, as pregnancy progresses, there is increased need to provide methyl groups for methylation reactions associated with the synthesis of new proteins and, unlike normal-BMI American women, low-BMI Indian women are unable to increase methionine transmethylation and remethylation rates as pregnancy progresses from trimester 1 to 3. This also negatively influences birth weight. The aim was to determine the effect of dietary supplementation with energy and protein from 12 ± 1 wk of gestation to time of delivery compared with no supplement on pregnancy outcomes, protein kinetics, and the fluxes of the methyl group donors serine and glycine. Protein kinetics and serine and glycine fluxes were measured by using standard stable isotope tracer methods in the fasting and postprandial states in 24 pregnant women aged 22.9 ± 0.7 y with low BMIs [BMI (in kg/m(2)) ≤18.5] at 12 ± 1 wk (trimester 1) and 30 ± 1 wk (trimester 3) of gestation. After the first measurement, subjects were randomly assigned to either receive the supplement (300 kcal/d, 15 g protein/d) or no supplement. Supplementation had no significant effect on any variable of pregnancy outcome, and except for fasting state decreases in leucine flux (125 ± 7.14 compared with 113 ± 5.06 μmol ⋅ kg(-1) ⋅ h(-1); P = 0.04) and nonoxidative disposal (110 ± 6.97 compared with 101 ± 3.69 μmol ⋅ kg(-1) ⋅ h(-1); P = 0.02) from trimesters 1 to 3, it had no effect on any other leucine kinetic variable or urea, glycine, and serine fluxes. We conclude that in Indian women with a low BMI, supplementation with energy and protein from week 12 of pregnancy to time of delivery does not improve pregnancy outcome, whole-body protein kinetics, or serine and glycine fluxes. © 2016 American Society for Nutrition.

  15. Landscape, kinetics, paths and statistics of curl flux, coherence, entanglement and energy transfer in non-equilibrium quantum systems

    International Nuclear Information System (INIS)

    Zhang, Zhedong; Wang, Jin

    2015-01-01

    We develop a population and flux landscape theory for general non-equilibrium quantum systems. We illustrate our theory by modelling the quantum transport of donor-acceptor energy transfer. We find two driving forces for the non-equilibrium quantum dynamics. The symmetric part of the driving force corresponds to the population landscape contribution which mainly governs the equilibrium part of dynamics while the anti-symmetric part of the driving force generates the non-equilibrium curl quantum flux which leads to the detailed-balance-breaking and time-irreversibility. The multi-loop structure of the flux emerges forms the flux-landscape. We study the trend of changes in population and flux-landscape with respect to the voltage (temperature difference induced by environments) and electronic coupling. Improving the voltage and electronic coupling in general facilitates the quantum transport by reducing the population landscape barriers between major states and increasing the mean value of the flux. A limit-cycle mode emerges when the underlying flux-landscape becomes funnelled with a significant gap between the largest flux loop and the rest of them. On the kinetic level, we find that multiple kinetic paths between quantum states emerge and illustrate the interference effects. The degree of interference is determined by the landscape and flux. Furthermore, we quantify kinetic rate which strongly correlates with the population landscape and flux. For quantum transport, we demonstrate that as the coherence or the quantum entanglement is enhanced, the flux and energy transfer efficiency are increased. Finally it is surprising that the non-equilibriumness quantified by voltage has a non-trivial contribution on strengthening the entanglement, which is attributed to the non-local feature of the quantum curl flux. (paper)

  16. Dynamic dual-energy chest radiography: a potential tool for lung tissue motion monitoring and kinetic study

    Science.gov (United States)

    Xu, Tong; Ducote, Justin L.; Wong, Jerry T.; Molloi, Sabee

    2011-02-01

    Dual-energy chest radiography has the potential to provide better diagnosis of lung disease by removing the bone signal from the image. Dynamic dual-energy radiography is now possible with the introduction of digital flat-panel detectors. The purpose of this study is to evaluate the feasibility of using dynamic dual-energy chest radiography for functional lung imaging and tumor motion assessment. The dual-energy system used in this study can acquire up to 15 frames of dual-energy images per second. A swine animal model was mechanically ventilated and imaged using the dual-energy system. Sequences of soft-tissue images were obtained using dual-energy subtraction. Time subtracted soft-tissue images were shown to be able to provide information on regional ventilation. Motion tracking of a lung anatomic feature (a branch of pulmonary artery) was performed based on an image cross-correlation algorithm. The tracking precision was found to be better than 1 mm. An adaptive correlation model was established between the above tracked motion and an external surrogate signal (temperature within the tracheal tube). This model is used to predict lung feature motion using the continuous surrogate signal and low frame rate dual-energy images (0.1-3.0 frames per second). The average RMS error of the prediction was (1.1 ± 0.3) mm. The dynamic dual energy was shown to be potentially useful for lung functional imaging such as regional ventilation and kinetic studies. It can also be used for lung tumor motion assessment and prediction during radiation therapy.

  17. Dynamic dual-energy chest radiography: a potential tool for lung tissue motion monitoring and kinetic study

    Energy Technology Data Exchange (ETDEWEB)

    Xu Tong [Department of Physics, Carleton University, 1125 Colonel By Drive, Ottawa, ON, K1S5B6 (Canada); Ducote, Justin L; Wong, Jerry T; Molloi, Sabee, E-mail: txu@physics.carleton.ca [Department of Radiological Sciences, University of California, Irvine, CA 92697 (United States)

    2011-02-21

    Dual-energy chest radiography has the potential to provide better diagnosis of lung disease by removing the bone signal from the image. Dynamic dual-energy radiography is now possible with the introduction of digital flat-panel detectors. The purpose of this study is to evaluate the feasibility of using dynamic dual-energy chest radiography for functional lung imaging and tumor motion assessment. The dual-energy system used in this study can acquire up to 15 frames of dual-energy images per second. A swine animal model was mechanically ventilated and imaged using the dual-energy system. Sequences of soft-tissue images were obtained using dual-energy subtraction. Time subtracted soft-tissue images were shown to be able to provide information on regional ventilation. Motion tracking of a lung anatomic feature (a branch of pulmonary artery) was performed based on an image cross-correlation algorithm. The tracking precision was found to be better than 1 mm. An adaptive correlation model was established between the above tracked motion and an external surrogate signal (temperature within the tracheal tube). This model is used to predict lung feature motion using the continuous surrogate signal and low frame rate dual-energy images (0.1-3.0 frames per second). The average RMS error of the prediction was (1.1 {+-} 0.3) mm. The dynamic dual energy was shown to be potentially useful for lung functional imaging such as regional ventilation and kinetic studies. It can also be used for lung tumor motion assessment and prediction during radiation therapy.

  18. The effect of vortex merging and non-merging on the transfer of modal turbulent kinetic energy content

    Science.gov (United States)

    Ground, Cody; Vergine, Fabrizio; Maddalena, Luca

    2016-08-01

    A defining feature of the turbulent free shear layer is that its growth is hindered by compressibility effects, thus limiting its potential to sufficiently mix the injected fuel and surrounding airstream at the supersonic Mach numbers intrinsic to the combustor of air-breathing hypersonic vehicles. The introduction of streamwise vorticity is often proposed in an attempt to counteract these undesired effects. This fact makes the strategy of introducing multiple streamwise vortices and imposing upon them certain modes of mutual interaction in order to potentially enhance mixing an intriguing concept. However, many underlying fundamental characteristics of the flowfields in the presence such interactions are not yet well understood; therefore, the fundamental physics of these flowfields should be independently investigated before the explicit mixing performance is characterized. In this work, experimental measurements are taken with the stereoscopic particle image velocimetry technique on two specifically targeted modes of vortex interaction—the merging and non-merging of two corotating vortices. The fluctuating velocity fields are analyzed utilizing the proper orthogonal decomposition (POD) in order to identify the content, organization, and distribution of the modal turbulent kinetic energy content of the fluctuating velocity eigenmodes. The effects of the two modes of vortex interaction are revealed by the POD analysis which shows distinct differences in the modal features of the two cases. When comparing the low-order eigenmodes of the two cases, the size of the structures contained within the first ten modes is seen to increase as the flow progresses downstream for the merging case, whereas the opposite is true for the non-merging case. Additionally, the relative modal energy contribution of the first ten eigenmodes increases as the vortices evolve downstream for the merging case, whereas in the non-merging case the relative modal energy contribution decreases

  19. Novel approaches to estimating the turbulent kinetic energy dissipation rate from low- and moderate-resolution velocity fluctuation time series

    Directory of Open Access Journals (Sweden)

    M. Wacławczyk

    2017-11-01

    Full Text Available In this paper we propose two approaches to estimating the turbulent kinetic energy (TKE dissipation rate, based on the zero-crossing method by Sreenivasan et al. (1983. The original formulation requires a fine resolution of the measured signal, down to the smallest dissipative scales. However, due to finite sampling frequency, as well as measurement errors, velocity time series obtained from airborne experiments are characterized by the presence of effective spectral cutoffs. In contrast to the original formulation the new approaches are suitable for use with signals originating from airborne experiments. The suitability of the new approaches is tested using measurement data obtained during the Physics of Stratocumulus Top (POST airborne research campaign as well as synthetic turbulence data. They appear useful and complementary to existing methods. We show the number-of-crossings-based approaches respond differently to errors due to finite sampling and finite averaging than the classical power spectral method. Hence, their application for the case of short signals and small sampling frequencies is particularly interesting, as it can increase the robustness of turbulent kinetic energy dissipation rate retrieval.

  20. Novel approaches to estimating the turbulent kinetic energy dissipation rate from low- and moderate-resolution velocity fluctuation time series

    Science.gov (United States)

    Wacławczyk, Marta; Ma, Yong-Feng; Kopeć, Jacek M.; Malinowski, Szymon P.

    2017-11-01

    In this paper we propose two approaches to estimating the turbulent kinetic energy (TKE) dissipation rate, based on the zero-crossing method by Sreenivasan et al. (1983). The original formulation requires a fine resolution of the measured signal, down to the smallest dissipative scales. However, due to finite sampling frequency, as well as measurement errors, velocity time series obtained from airborne experiments are characterized by the presence of effective spectral cutoffs. In contrast to the original formulation the new approaches are suitable for use with signals originating from airborne experiments. The suitability of the new approaches is tested using measurement data obtained during the Physics of Stratocumulus Top (POST) airborne research campaign as well as synthetic turbulence data. They appear useful and complementary to existing methods. We show the number-of-crossings-based approaches respond differently to errors due to finite sampling and finite averaging than the classical power spectral method. Hence, their application for the case of short signals and small sampling frequencies is particularly interesting, as it can increase the robustness of turbulent kinetic energy dissipation rate retrieval.

  1. Validation of a Numerical Program for Analyzing Kinetic Energy Potential in the Bangka Strait, North Sulawesi, Indonesia

    Science.gov (United States)

    Rompas, P. T. D.; Taunaumang, H.; Sangari, F. J.

    2018-02-01

    The paper presents validation of the numerical program that computes the distribution of marine current velocities in the Bangka strait and the kinetic energy potential in the form the distributions of available power per area in the Bangka strait. The numerical program used the RANS model where the pressure distribution in the vertical assumed to be hydrostatic. The 2D and 3D numerical program results compared with the measurement results that are observation results to the moment conditions of low and high tide currents. It found no different significant between the numerical results and the measurement results. There are 0.97-2.2 kW/m2 the kinetic energy potential in the form the distributions of available power per area in the Bangka strait when low tide currents, whereas when high tide currents of 1.02-2.1 kW/m2. The results show that to be enabling the installation of marine current turbines for construction of power plant in the Bangka strait, North Sulawesi, Indonesia.

  2. A study on the kinetics of high-energy phosphates in myocardium by phosphorous nuclear magnetic resonance

    International Nuclear Information System (INIS)

    Kusuoka, Hideo; Tsuneoka, Yutaka; Inoue, Michitoshi; Abe, Hiroshi; Watari, Hiroshi.

    1982-01-01

    Effect of artificial blood, FC 43 (Perfluorochemicals) on the kinetics of high-energy phosphate in the myocardium was evaluated by 31 P-NMR which permits a continuous and non-invasive assessment of in vivo phosphorus compounds. Cardiac perfusion was carried out on a excised rat heart with a Krebs-Henseleit modified solution and FC 43 alternately. Under the normal condition, ischemic condition, and at second perfusion amounts of intramyocardial creatine phosphoric acid, ATP, and inorganic phosphorus were determined by 31 P-NMR. Coronary flow was simultaneously estimated. The ischemic state due to interruption of perfusion resulted in a decrease in creatine phosphoric acid, which was associated with an increase in inorganic phosphorus and intracellular acidosis. No change of ATP amount was observed under ischemic state. With resumption of perfusion, the levels of creatine phosphoric acid and inorganic phosphorus rapidly returned to the normal. In the group of FC 43, coronary flow was 2.68 ml/min/g of the heart weight, about 1/2 of that of the Krebs-Henseleit group (5.68 ml/min/g of the heart weight). In controls, there was no difference between the two groups concerning creatine phosphoric acid level and recovery of creatine phospohric acid level after ischemia. These results showed that FC 43 supplies sufficient oxygen, and has no effect on the kinetics of energy in the myocardium. (Ueda, J.)

  3. Prediction of point-defect migration energy barriers in alloys using artificial intelligence for atomistic kinetic Monte Carlo applications

    Energy Technology Data Exchange (ETDEWEB)

    Castin, N. [Structural Materials Group, Nuclear Materials Science Institute, Studiecentrum voor Kerneenergie Centre d' etude de l' energie nucleaire (SCK CEN), Boeretang 200, B-2400 Mol (Belgium); Universite Libre de Bruxelles (ULB), Physique des Solides Irradies et Nanostructures (PSIN), CP234 Boulevard du triomphe, Brussels (Belgium); Malerba, L. [Structural Materials Group, Nuclear Materials Science Institute, Studiecentrum voor Kerneenergie Centre d' etude de l' energie nucleaire (SCK CEN), Boeretang 200, B-2400 Mol (Belgium)], E-mail: lmalerba@sckcen.be

    2009-09-15

    We significantly improved a previously proposed method to take into account chemical and also relaxation effects on point-defect migration energy barriers, as predicted by an interatomic potential, in a rigid lattice atomistic kinetic Monte Carlo simulation. Examples of energy barriers are rigorously calculated, including chemical and relaxation effects, as functions of the local atomic configuration, using a nudged elastic bands technique. These examples are then used to train an artificial neural network that provides the barriers on-demand during the simulation for each configuration encountered by the migrating defect. Thanks to a newly developed training method, the configuration can include a large number of neighbour shells, thereby properly including also strain effects. Satisfactory results have been obtained when the configuration includes different chemical species only. The problems encountered in the extension of the method to configurations including any number of point-defects are stated and solutions to tackle them are sketched.

  4. Kinetics and heterogeneity of energy transfer from light harvesting complex II to photosystem I in the supercomplex isolated from Arabidopsis.

    Science.gov (United States)

    Santabarbara, Stefano; Tibiletti, Tania; Remelli, William; Caffarri, Stefano

    2017-03-29

    State transitions are a phenomenon that maintains the excitation balance between photosystem II (PSII) and photosystem I (PSI-LHCI) by controlling their relative absorption cross-sections. Under light conditions exciting PSII preferentially, a trimeric LHCII antenna moves from PSII to PSI-LHCI to form the PSI-LHCI-LHCII supercomplex. In this work, the excited state dynamics in the PSI-LHCI and PSI-LHCI-LHCII supercomplexes isolated from Arabidopsis have been investigated by picosecond time-resolved fluorescence spectroscopy. The excited state decays were analysed using two approaches based on either (i) a sum of discrete exponentials or (ii) a continuous distribution of lifetimes. The results indicate that the energy transfer from LHCII to the bulk of the PSI antenna occurs with an average macroscopic transfer rate in the 35-65 ns -1 interval. Yet, the most satisfactory description of the data is obtained when considering a heterogeneous population containing two PSI-LHCI-LHCII supercomplexes characterised by a transfer time of ∼15 and ∼60 ns -1 , likely due to the differences in the strength and orientation of LHCII harboured to PSI. Both these values are of the same order of magnitude of those estimated for the average energy transfer rates from the low energy spectral forms of LHCI to the bulk of the PSI antenna (15-40 ns -1 ), but they are slower than the transfer from the bulk antenna of PSI to the reaction centre (>150 ns -1 ), implying a relatively small kinetics bottleneck for the energy transfer from LHCII. Nevertheless, the kinetic limitation imposed by excited state diffusion has a negligible impact on the photochemical quantum efficiency of the supercomplex, which remains about 98% in the case of PSI-LHCI.

  5. Measurement of turbulent spatial structure and kinetic energy spectrum by exact temporal-to-spatial mapping

    DEFF Research Database (Denmark)

    Buchhave, Preben; Velte, Clara Marika

    2017-01-01

    We present a method for converting a time record of turbulent velocity measured at a point in a flow to a spatial velocity record consisting of consecutive convection elements. The spatial record allows computation of dynamic statistical moments such as turbulent kinetic wavenumber spectra...... are access to the instantaneous velocity magnitude, in addition to the desired flow quantity, and a high temporal resolution in comparison to the relevant time scales of the flow. We map, without distortion and bias, notoriously difficult developing turbulent high intensity flows using three main aspects...

  6. Coupling the photon kinetics of soft photons with high energy photons

    Science.gov (United States)

    Silva, L. O.; Bingham, R.

    2017-10-01

    The description of electromagnetic fields based on the generalized photon kinetic theory, which takes advantage of the Wigner-Moyal description for the corresponding classical field theory, is capable of capturing collective plasma dynamics in the relativistic regime driven by broadband incoherent or partially coherent sources. We explore the possibility to extend this description to include the dynamics of hard photons in the plasma, whose interaction is dominated by single scattering processes. Examples of the modification of classical plasma instabilities due to the presence of hard photons is discussed. Work supported by the European Research Council (ERC-AdG-2015 InPairs Grant No. 695088).

  7. Use of latent heat storage to conserve energy during drying and its effect on drying kinetics of a food product

    Energy Technology Data Exchange (ETDEWEB)

    Devahastin, Sakamon; Pitaksuriyarat, Saovakhon [Department of Food Engineering, King Mongkut' s University of Technology Thonburi, 91 Pracha u-tid Road, Bangkok 10140 (Thailand)

    2006-10-15

    The present study aimed at investigating the feasibility of using a latent heat storage (LHS) with paraffin wax as a phase change material (PCM) to store excess solar energy and release it when the energy availability is inadequate or not available. First, attention was given on the heat transfer characteristics of the PCM during the charge and discharge periods of the LHS. The effects of inlet hot air temperature in the range of 70-90{sup o}C and inlet air velocities of 1 and 2ms{sup -1} on the charge time were determined, while during the discharge period only the effect of inlet ambient air velocity was considered. The effect of the use of LHS on the drying kinetics of sweet potato and the ability of the LHS to conserve energy during drying of sweet potato were also determined. It was found that the drying rate of sweet potato increased with a decrease of the inlet ambient air velocity. The amount of the energy extractable from the LHS was 1920 and 1386kJminkg{sup -1} and the energy savings was 40% and 34% when using an inlet ambient air velocity of 1 and 2ms{sup -1}, respectively. (author)

  8. Influence of the height of the vegetation cover in the variation of the kinetic energy of raindrops intercepted; Influencia de la altura de la cubierta vegetal en la variacion de la energia cinetica de las gotas de lluvia interceptadas

    Energy Technology Data Exchange (ETDEWEB)

    Roldan Soriano, M.

    2009-07-01

    The erosive capacity of raindrops is function of mass (size) and terminal velocity. Drop mass and velocity govern the inherent erosivity of rainfall through kinetic energy. Kinetic energy is a very important property of the rainfall because it is one of the sources of energy in the process of water erosion. Vegetative canopy intercepts the raindrops and causes a variation on this rainfall kinetic energy due to modification of diameters and velocities distributions. If the height of canopy is enough, the bigger intercepted drops could achieve high velocities and their kinetic energies can increases. In this paper a quantitative evaluation of the increase of kinetic energy of intercepted drops is obtained and it is showed that this kinetic energy increases exponentially with vegetation height. (Author) 9 refs.

  9. PFI-ZEKE (Pulsed Field Ionization-Zero Electron Kinetic Energy) para el estudio de iones

    Science.gov (United States)

    Castaño, F.; Fernández, J. A.; Basterretxea, A. Longarte. F.; Sánchez Rayo, M. N.; Martínez, R.

    Entre las áreas hacia donde ha evolucionado la Química en los últimos años están los estudios de sistemas con especies reactivas de alta energía y los dominados por fuerzas intermoleculares débiles, con energías de unas pocas kcal/mol. En efecto, el estudio de las propiedades de los iones, comenzando por su relación con la molécula neutra de la que procede, la energía de ionización, los estados vibracionales y rotacionales, energías de enlace de Van der Waals entre el ión y una amplia variedad de otras moléculas, sus confórmeros o isómeros y sus reacciones o semi-reacciones químicas están en la raíz de la necesidad de la espectroscopía conocida como PFI-ZEKE, Pulsed Field Ionization-Zero Electron Kinetic Energy. Entre las aplicaciones que requieren estos conocimientos se encuentran la generación de plasmas para la fabricación de semiconductores, memorias magnéticas, etc, así como los sistemas astrofísicos, la ionosfera terrestre, etc. La espectroscopía ZEKE es una evolución de las de fluorescencia inducida por láser, LIF, ionización multifotónica acrecentada por resonancia, REMPI, con uno y dos colores y acoplada a un sistema de tiempo de vuelo, REMPI-TOF-MS, y las espectroscopías de doble resonancia IR-UV y UV-UV. Sus espectros y la ayuda de cálculos ab inicio permite determinar las energías de enlace de complejos de van der Waals en estados fundamental y excitados, identificar confórmeros e isómeros, obtener energías de ionización experimentales aproximadas (100 cm-1) y otras variables de interés. Al igual que con LIF, REMPI y dobles resonancias, es posible utilizar muestras gaseosas, pero los espectros están muy saturados de bandas y su interpretación es difícil o imposible. Se evitan estas dificultades estudiando las moléculas o complejos en expansiones supersónicas, donde la T de los grados de libertad solo alcanzan unos pocos K. Para realizar experimentos de ZEKE hay que utilizar una propiedad recientemente

  10. Energy Reflection Coefficients for 5-10 keV He Ions Incident on Au, Ag, and Cu

    DEFF Research Database (Denmark)

    Schou, Jørgen; Sørensen, H.; Littmark, U.

    1978-01-01

    The calorimetric deuterium-film method was used for measurements of the energy reflection coefficient γ for normal incidence of 5-10 keV He ions on Cu, Ag and Au. A theoretical calculation of γ by means of transport theory gives fair agreement with the experimental results. The experimental data...... the experimental and theoretical results for the He ions are in acceptable agreement with other experimental and theoretical results. For He ions, the experimental γ-values are 20-30% above the values for hydrogen ions for the same value of ε...

  11. Interfacial mixing in high-energy-density matter with a multiphysics kinetic model.

    Science.gov (United States)

    Haack, Jeffrey R; Hauck, Cory D; Murillo, Michael S

    2017-12-01

    We have extended a recently developed multispecies, multitemperature Bhatnagar-Gross-Krook model [Haack et al., J. Stat. Phys. 168, 822 (2017)JSTPBS0022-471510.1007/s10955-017-1824-9], to include multiphysics capabilities that enable modeling of a wider range of physical conditions. In terms of geometry, we have extended from the spatially homogeneous setting to one spatial dimension. In terms of the physics, we have included an atomic ionization model, accurate collision physics across coupling regimes, self-consistent electric fields, and degeneracy in the electronic screening. We apply the model to a warm dense matter scenario in which the ablator-fuel interface of an inertial confinement fusion target is heated, but for larger length and time scales and for much higher temperatures than can be simulated using molecular dynamics. Relative to molecular dynamics, the kinetic model greatly extends the temperature regime and the spatiotemporal scales over which we are able to model. In our numerical results we observe hydrogen from the ablator material jetting into the fuel during the early stages of the implosion and compare the relative size of various diffusion components (Fickean diffusion, electrodiffusion, and barodiffusion) that drive this process. We also examine kinetic effects, such as anisotropic distributions and velocity separation, in order to determine when this problem can be described with a hydrodynamic model.

  12. Interfacial mixing in high-energy-density matter with a multiphysics kinetic model

    Science.gov (United States)

    Haack, Jeffrey R.; Hauck, Cory D.; Murillo, Michael S.

    2017-12-01

    We have extended a recently developed multispecies, multitemperature Bhatnagar-Gross-Krook model [Haack et al., J. Stat. Phys. 168, 822 (2017), 10.1007/s10955-017-1824-9], to include multiphysics capabilities that enable modeling of a wider range of physical conditions. In terms of geometry, we have extended from the spatially homogeneous setting to one spatial dimension. In terms of the physics, we have included an atomic ionization model, accurate collision physics across coupling regimes, self-consistent electric fields, and degeneracy in the electronic screening. We apply the model to a warm dense matter scenario in which the ablator-fuel interface of an inertial confinement fusion target is heated, but for larger length and time scales and for much higher temperatures than can be simulated using molecular dynamics. Relative to molecular dynamics, the kinetic model greatly extends the temperature regime and the spatiotemporal scales over which we are able to model. In our numerical results we observe hydrogen from the ablator material jetting into the fuel during the early stages of the implosion and compare the relative size of various diffusion components (Fickean diffusion, electrodiffusion, and barodiffusion) that drive this process. We also examine kinetic effects, such as anisotropic distributions and velocity separation, in order to determine when this problem can be described with a hydrodynamic model.

  13. Track etch parameters and annealing kinetics assessment of protons of low energy in CR-39 detector

    International Nuclear Information System (INIS)

    Jain, R.K.; Kumar, Ashok; Singh, B.K.

    2012-01-01

    Highlights: ► We calibrate CR-39 detector with very low energy protons. ► We establish linear relationship between track diameter and time/energy up to 200 keV. ► We determine activation energy of annealing using different models. ► We justify concept of single annealing activation energy in CR-39. - Abstract: In this paper threshold of the registration sensitivity of very low energy proton in CR-39 is investigated. Irradiation of CR-39 (poly-allyl-diglycol carbonate) was carried out with very low energy mono energetic protons of 20–60 keV from a mini proton accelerator. Nearly 10 4 /cm 2 fluence of protons was used. The variation of track diameter with etching time as well as proton energy response curve was carefully calibrated. The bulk and track etch rates were measured by using proton track diameters. Bulk etch rate was also measured by the thickness of removed surface layer. The thermal annealing of proton track at temperatures ranging from 100 to 200 °C in CR-39 was studied by several models. Activation energy of annealed CR-39 detectors was calculated by slope of track etch rate and temperature plot. The data of proton tracks of 200, 250 and 300 keV from 400 kV Van-de-Graaff accelerator was also used and compared with the track diameters of different energies of proton.

  14. A comparison of power output from linear and nonlinear kinetic energy harvesters using real vibration data

    Science.gov (United States)

    Beeby, Stephen P.; Wang, Leran; Zhu, Dibin; Weddell, Alex S.; Merrett, Geoff V.; Stark, Bernard; Szarka, Gyorgy; Al-Hashimi, Bashir M.

    2013-07-01

    The design of vibration energy harvesters (VEHs) is highly dependent upon the characteristics of the environmental vibrations present in the intended application. VEHs can be linear resonant systems tuned to particular frequencies or nonlinear systems with either bistable operation or a Duffing-type response. This paper provides detailed vibration data from a range of applications, which has been made freely available for download through the Energy Harvesting Network’s online data repository. In particular, this research shows that simulation is essential in designing and selecting the most suitable vibration energy harvester for particular applications. This is illustrated through C-based simulations of different types of VEHs, using real vibration data from a diesel ferry engine, a combined heat and power pump, a petrol car engine and a helicopter. The analysis shows that a bistable energy harvester only has a higher output power than a linear or Duffing-type nonlinear energy harvester with the same Q-factor when it is subjected to white noise vibration. The analysis also indicates that piezoelectric transduction mechanisms are more suitable for bistable energy harvesters than electromagnetic transduction. Furthermore, the linear energy harvester has a higher output power compared to the Duffing-type nonlinear energy harvester with the same Q factor in most cases. The Duffing-type nonlinear energy harvester can generate more power than the linear energy harvester only when it is excited at vibrations with multiple peaks and the frequencies of these peaks are within its bandwidth. Through these new observations, this paper illustrates the importance of simulation in the design of energy harvesting systems, with particular emphasis on the need to incorporate real vibration data.

  15. French energy resources and needs. Incidence on the development of the national nuclear programme

    International Nuclear Information System (INIS)

    Martin, Roger.

    1977-01-01

    The energy flux diagram for France in 1970, underlines the disparity observed between the utilization factors in the final stage: 75% for the domestic and tertiary sector, 75% for industry and siderurgy, 65% for agriculture, and 25% for transports. The total utilization factor is 47.5% (124.4 MTEC used for 137.6 MTEC unused; the unit used being the Million of Tons Equivalent to Coal. Two dates are arbitrarily envisaged (1985 and 2000) in the evolution of the French energy technology and structure. The energy flux diagram predicted for 1985 should asked to atom nearly a quarter of the resources, with an enhanced part from hydraulics (+30%) and should involve geothermy, heat wastes and solar energy. An extrapolation predicts a spectacular-growth for 2000 due to the uranium share as a compensation to the decrease in that from oil, as for the transformation stage a neat increase in the electricity share is predicted together with 'tele-heat' and hydrogen production and, at the stage of utilization the mass penetration of 'tele-heat', especially of nuclear origin. The problem of the evolution of energy resources is also discussed [fr

  16. Deposition of metallic clusters on a metallic surface at zero initial kinetic energy: Evidence for implantation and site exchanges

    Science.gov (United States)

    Nacer, B.; Massobrio, C.; Félix, C.

    1997-10-01

    We have investigated the deposition at zero impact kinetic energy of the Ag atom and clusters (Ag7,Ag19) on the (100) and (111) surfaces of Pd by molecular-dynamics simulations performed within the embedded-atom-method scheme. Our results elucidate the role played by the adsorption energy in determining the final morphology of the cluster/substrate system when ideal nondestructive deposition conditions are implemented. While implantation of the atom is not observed, we find a finite probability of site Ag-Pd exchanges in the case of clusters. Deposition-assisted mixing occurring at the topmost surface layer appears to be correlated to the size of the cluster and the orientation of the substrate, being higher for Ag7/Pd(100) and lower for Ag19/Pd(111). Total-energy calculations, combined with an analysis of the atomic motion, indicate that the structural transformation accompanying the deposition of the cluster provides the needed activation energy to induce the observed Ag-Pd atomic exchanges.

  17. Collisional effects on ion energy and angular distributions incident on RF-biased electrodes

    International Nuclear Information System (INIS)

    Qiu Huatan; Wang Younian; Ma Tengcai

    2002-01-01

    Taking into account elastic collisions and charge-exchange collisions between ions and neutral particles, the authors established a self-consistent model describing the dynamics of radio-frequency (RF) sheath driven by a sinusoidal current source, and also, using the Monte-Carlo Method, simulated energy and angle distributions of ions bombarding on RF-biased substrates. It has been shown from numerical results that as increasing the discharge pressure, bimodal-peaks distributions for the ion energy become gradually a single-peak distribution, and low-energy ions increase. The authors also found that the angle distribution of ions is narrow and almost do not change with increasing the discharge pressure

  18. Wideband metamaterial array with polarization-independent and wide incident angle for harvesting ambient electromagnetic energy and wireless power transfer

    Science.gov (United States)

    Zhong, Hui-Teng; Yang, Xue-Xia; Song, Xing-Tang; Guo, Zhen-Yue; Yu, Fan

    2017-11-01

    In this work, we introduced the design, demonstration, and discussion of a wideband metamaterial array with polarization-independent and wide-angle for harvesting ambient electromagnetic (EM) energy and wireless power transfer. The array consists of unit cells with one square ring and four metal bars. In comparison to the published metamaterial arrays for harvesting EM energy or wireless transfer, this design had the wide operation bandwidth with the HPBW (Half Power Band Width) of 110% (6.2 GHz-21.4 GHz), which overcomes the narrow-band operation induced by the resonance characteristic of the metamaterial. On the normal incidence, the simulated maximum harvesting efficiency was 96% and the HPBW was 110% for the random polarization wave. As the incident angle increases to 45°, the maximum efficiency remained higher than 88% and the HPBW remained higher than 83% for the random polarization wave. Furthermore, the experimental verification of the designed metamaterial array was conducted, and the measured results were in reasonable agreement with the simulated ones.

  19. Method of incident low-energy gamma-ray direction reconstruction in the GAMMA-400 gamma-ray space telescope

    International Nuclear Information System (INIS)

    Kheymits, M D; Leonov, A A; Zverev, V G; Galper, A M; Arkhangelskaya, I V; Arkhangelskiy, A I; Yurkin, Yu T; Bakaldin, A V; Suchkov, S I; Topchiev, N P; Dalkarov, O D

    2016-01-01

    The GAMMA-400 gamma-ray space-based telescope has as its main goals to measure cosmic γ-ray fluxes and the electron-positron cosmic-ray component produced, theoretically, in dark-matter-particles decay or annihilation processes, to search for discrete γ-ray sources and study them in detail, to examine the energy spectra of diffuse γ-rays — both galactic and extragalactic — and to study gamma-ray bursts (GRBs) and γ-rays from the active Sun. Scientific goals of GAMMA-400 telescope require fine angular resolution. The telescope is of a pair-production type. In the converter-tracker, the incident gamma-ray photon converts into electron-positron pair in the tungsten layer and then the tracks are detected by silicon- strip position-sensitive detectors. Multiple scattering processes become a significant obstacle in the incident-gamma direction reconstruction for energies below several gigaelectronvolts. The method of utilising this process to improve the resolution is proposed in the presented work. (paper)

  20. Medium-sized grazing incidence high-energy X-ray telescopes employing continuously graded multilayers

    DEFF Research Database (Denmark)

    Joensen, K. D.; Christensen, Finn Erland; Schnopper, H. W.

    1993-01-01

    The authors present a concept of continuously graded multilayer structures for medium-sized X-ray telescopes which is based on several material combinations. They show that the theoretical reflectivity characteristics of these structures make them very advantageous when applied to high energy X-r...

  1. Kinetics and

    Directory of Open Access Journals (Sweden)

    Mojtaba Ahmadi

    2016-11-01

    Full Text Available The aqueous degradation of Reactive Yellow 84 (RY84 by potassium peroxydisulfate (K2S2O8 has been studied in laboratory scale experiments. The effect of the initial concentrations of potassium peroxydisulfate and RY84, pH and temperature on RY84 degradation were also examined. Experimental data were analyzed using first and second-order kinetics. The degradation kinetics of RY84 of the potassium peroxydisulfate process followed the second-order reaction kinetics. These rate constants have an extreme values similar to of 9.493 mM−1min−1 at a peroxydisulfate dose of 4 mmol/L. Thermodynamic parameters such as activation (Ea and Gibbs free energy (ΔG° were also evaluated. The negative value of ΔGo and Ea shows the spontaneous reaction natural conditions and exothermic nature.

  2. Zero kinetic energy photoelectron spectroscopy of tryptamine and the dissociation pathway of the singly hydrated cation cluster

    Science.gov (United States)

    Gu, Quanli; Knee, J. L.

    2012-09-01

    The relative ionization energies of tryptamine conformations are determined by zero kinetic energy photoelectron spectroscopy and photoionization efficiency measurements. The relative cationic conformational stabilities are compared to the published results for the neutral molecule. In the cation, the interaction strength changes significantly between amino group and either the phenyl or the pyrrole moiety of the indole chromophore where most of the positive charge is located, leading to different conformational structures and relative conformer energies in the cation. In particular, the measured adiabatic ionization potential of isomer B is 60 928 ± 5 cm-1, at least 400 cm-1 higher than any of the 6 other tryptamine isomers which all have ionization potentials within 200 cm-1 of each other. In addition to the monomer, measurements were made on the A conformer of the tryptamine+-H2O complex including the ionization threshold and cation dissociation energy measured using a threshold photoionization fragmentation method. The water cluster exhibits an unexpectedly high ionization potential of 60 307 ± 100 cm-1, close to the conformer A monomer of 60 320 ± 100 cm-1. It also exhibits surprisingly low dissociation energy of 1750 ± 150 cm-1 compared to other H-bonding involved cation-H2O complexes which are typically several thousands of wavenumbers higher. Quantum chemical calculations indicate that upon ionization the structure of the parent molecule in the water complex remains mostly unchanged due to the rigid intermolecular double hydrogen bonded water molecule bridging the monomer backbone and its side chain thus leading to the high ionization potential in the water cluster. The surprisingly low dissociation energy measured in the cationic water complex is attributed to the formation of a much more stable structural isomer H+ in the exit channel.

  3. Simple Examples of the Interpretation of Changes in Kinetic and Potential Energy Under Galilean Transformations

    Science.gov (United States)

    Ginsberg, Edw. S.

    2018-02-01

    The compatibility of the Newtonian formulation of mechanical energy and the transformation equations of Galilean relativity is demonstrated for three simple examples of motion treated in most introductory physics courses (free fall, a frictionless inclined plane, and a mass/spring system). Only elementary concepts and mathematics, accessible to students at that level, are used. Emphasis is on pedagogy and concepts related to the transformation properties of potential energy.

  4. Evaluation of 242Pu data for the incident neutron energy range 0.1 - 6 MeV

    International Nuclear Information System (INIS)

    Vladuca, G.; Sin, M.; Tudora, A.

    1996-11-01

    This report presents the models and the procedures used for the calculation of the quantities required by Files 3, 4 and 5 of ENDF-6 for 242 Pu. These quantities are the integrated cross sections for the total, fission, scattering and gamma-capture reactions and the angular and energy distributions of the scattered neutrons for the incident neutron energies 0.01/6 MeV. The direct mechanism was treated with the coupled-channel method using a deformed optical potential defined by a set of actinide region parameters established by the authors. For the compound nucleus calculations, a new HRTW version of the statistical model extended to describe the fission at subbarrier energies was used. To describe the continuous part of the transition states spectrum, analytical expressions have been established. The energy distributions of the scattered neutrons have been calculated with an author's version of the Los Alamos model. The agreement of the calculations with the existing experimental data is good. (author)

  5. Predictive modeling capabilities from incident powder and laser to mechanical properties for laser directed energy deposition

    Science.gov (United States)

    Shin, Yung C.; Bailey, Neil; Katinas, Christopher; Tan, Wenda

    2018-01-01

    This paper presents an overview of vertically integrated comprehensive predictive modeling capabilities for directed energy deposition processes, which have been developed at Purdue University. The overall predictive models consist of vertically integrated several modules, including powder flow model, molten pool model, microstructure prediction model and residual stress model, which can be used for predicting mechanical properties of additively manufactured parts by directed energy deposition processes with blown powder as well as other additive manufacturing processes. Critical governing equations of each model and how various modules are connected are illustrated. Various illustrative results along with corresponding experimental validation results are presented to illustrate the capabilities and fidelity of the models. The good correlations with experimental results prove the integrated models can be used to design the metal additive manufacturing processes and predict the resultant microstructure and mechanical properties.

  6. Idempotent Dirac density matrix for ten-electron central field inhomogeneous electron liquids in terms of electron- and kinetic energy-densities

    International Nuclear Information System (INIS)

    March, N.H.

    2006-08-01

    A differential equation for the Dirac density matrix γ(r, r'), given ground-state electron- and kinetic energy-densities, has been derived by March and Suhai for one- and two-level occupancy. For ten-electron spin-compensated spherical systems, it is shown here that γ ≡ γ[ρ, t g ] where ρ and t g are electron- and kinetic energy-densities. The philosophy of March and Suhai is confirmed beyond two-level filling. An important byproduct of the present approach is an explicit expression for the one-body potential of DFT in terms of the p-shell electron density. (author)

  7. "Osteoporosis and orthopods" incidences of osteoporosis in distal radius fracture from low energy trauma.

    LENUS (Irish Health Repository)

    Bahari, Syah

    2007-07-01

    Fracture of the distal radius from low energy trauma is a common presentation to orthopaedic trauma services. This fragility type fracture is associated with underlying osteoporosis. Osteoporosis is a \\'silent disease\\' where fragility fracture is a common presentation. Orthopaedic surgeons may be the only physician that these patients encounter. We found a high percentage of female patients who sustained a fragility fracture of the distal radius have an underlying osteoporosis. Further management of osteoporosis is important to prevent future fragility fractures.

  8. Influence of the incident particle energy on the fission product mass distribution

    International Nuclear Information System (INIS)

    Gomes, I. C.

    1998-01-01

    For 238 U targets and the five elements considered here, the best yields of neutron-rich isotopes are obtained from neutrons in the 2-20 MeV range. High energy beams of neutrons, protons, and deuterons have comparable integral yields per element to neutrons below 20 MeV, but the distributions are peaked at lower neutron numbers. This is presumably due to a higher neutron multiplicity in the pre-equilibrium stage and/or the compound nucleus/fission stage. For 235 U targets there are high yields predicted especially for thermal neutrons, and also for the fast neutron spectrum. For the high energy neutrons, protons, and deuterons 235 U has no advantage over 238 U. A detailed comparison of the relative advantages of 235 U and 238 U for radioactive beam applications is beyond the scope of this study and will be addressed in the future. The present work is the first step of a more detailed analysis of various possible one- and two-step target geometry calculated with the LAHET code system. It is intended to serve as a guide in choosing geometry and beams for future studies. It is desirable to extend this study to higher beam energies, e.g. 200 to 1000 MeV, but at this time there is very little data against which to benchmark the analysis. Additional data would also permit comparisons of isotope yields beyond the tails of the distributions presented here, to even more neutron rich isotopes

  9. The economic concept of elasticity and their incidence in the Colombian energy market

    International Nuclear Information System (INIS)

    Perez Bedoya, Edigson

    1997-01-01

    There are two factors that affect the elasticity, in the first place the readiness of substitutes and in second place, the number of uses that can be given, the more numerous and better they are the substitutes, will be better the elasticity. The goods that have scarce and bad substitutes will Always spread to have small elasticity. The goods with many substitutes will spread to have great elasticity; if the demand is classified in elastic or inelastic it is an important consideration, especially for the energy politics, in the relative thing to market of specific goods, in this case the electric power. If the coefficient of elasticity of the electric power was very elastic, this would imply that an increase in the rate will generate a reduction proportionally in the energy consumption bigger, the companies that they offer or they distribute energy in the case of the electricity for example, they would obtain a smaller entrance for the sale of the electric power kWh. In the practice it is difficult that it happens, for the difficulty of finding substitutes for the electric power, in other words because the elasticity of the electric power demand is inelastic. If the national government establishes a minimum rate above the price of the market balance, the kWh sales, they could decrease, the same as the entrance of the companies of the electric sector, unless the guarantee price is accompanied by minimum quotas of purchase

  10. Enhancing Understanding of Magnetized High Energy Density Plasmas from Solid Liner Implosions Using Fluid Modeling with Kinetic Closures

    Science.gov (United States)

    Masti, Robert; Srinivasan, Bhuvana; King, Jacob; Stoltz, Peter; Hansen, David; Held, Eric

    2017-10-01

    Recent results from experiments and simulations of magnetically driven pulsed power liners have explored the role of early-time electrothermal instability in the evolution of the MRT (magneto-Rayleigh-Taylor) instability. Understanding the development of these instabilities can lead to potential stabilization mechanisms; thereby providing a significant role in the success of fusion concepts such as MagLIF (Magnetized Liner Inertial Fusion). For MagLIF the MRT instability is the most detrimental instability toward achieving fusion energy production. Experiments of high-energy density plasmas from wire-array implosions have shown the requirement for more advanced physics modeling than that of ideal magnetohydrodynamics. The overall focus of this project is on using a multi-fluid extended-MHD model with kinetic closures for thermal conductivity, resistivity, and viscosity. The extended-MHD model has been updated to include the SESAME equation-of-state tables and numerical benchmarks with this implementation will be presented. Simulations of MRT growth and evolution for MagLIF-relevant parameters will be presented using this extended-MHD model with the SESAME equation-of-state tables. This work is supported by the Department of Energy Office of Science under Grant Number DE-SC0016515.

  11. Kinetic energy distributions of molecular and cluster ions sputtered from self-assembled monolayers of octanethiol on gold

    International Nuclear Information System (INIS)

    Arezki, Bahia; Delcorte, Arnaud; Bertrand, Patrick

    2002-01-01

    Self-assembled monolayers (SAMs) of alkanethiols are an ideal model system to study the mechanisms that lead to emission of organic species under keV ion bombardment. In this contribution, we focus on the emission processes of gold-molecule cluster ions, which are not fully understood yet. To gain insights into these processes, monolayers of octanethiol CH 3 (CH 2 ) 7 SH adsorbed on gold are investigated using time-of-flight secondary ion mass spectrometry (ToF-SIMS). First, the static SIMS conditions are verified using the degradation of the SAM signals as a function of ion fluence. Second, the kinetic energy distributions (KEDs) of fragment, parent and cluster ions ejected upon 15 keV Ga + ion bombardment are measured. The peak maxima, FWHMs and high energy tails of the distributions are analyzed for Au-thiolate clusters, as well as thiol fragments. After calibration of the energy spectra using monoatomic ions, we find that the KEDs of all the clusters containing the thiolate molecule peak at about 1.2 eV. Besides, the distributions of the gold-molecule cluster ions including Au(M-H) 2 - , the most intense cluster peak in the spectrum, are significantly narrower than that of the hydrocarbon fragments

  12. ION KINETIC ENERGY CONSERVATION AND MAGNETIC FIELD STRENGTH CONSTANCY IN MULTI-FLUID SOLAR WIND ALFVÉNIC TURBULENCE

    Energy Technology Data Exchange (ETDEWEB)

    Matteini, L.; Horbury, T. S.; Schwartz, S. J. [The Blackett Laboratory, Imperial College London, SW7 2AZ (United Kingdom); Pantellini, F. [LESIA, Observatoire de Paris, CNRS, UPMC, Universit Paris-Diderot, 5 Place Jules Janssen, F-92195 Meudon (France); Velli, M. [Department of Earth, Planetary, and Space Sciences, UCLA, California (United States)

    2015-03-20

    We investigate the properties of plasma fluid motion in the large-amplitude, low-frequency fluctuations of highly Alfvénic fast solar wind. We show that protons locally conserve total kinetic energy when observed from an effective frame of reference comoving with the fluctuations. For typical properties of the fast wind, this frame can be reasonably identified by alpha particles which, due to their drift with respect to protons at about the Alfvén speed along the magnetic field, do not partake in the fluid low-frequency fluctuations. Using their velocity to transform the proton velocity into the frame of Alfvénic turbulence, we demonstrate that the resulting plasma motion is characterized by a constant absolute value of the velocity, zero electric fields, and aligned velocity and magnetic field vectors as expected for unidirectional Alfvénic fluctuations in equilibrium. We propose that this constraint, via the correlation between velocity and magnetic field in Alfvénic turbulence, is the origin of the observed constancy of the magnetic field; while the constant velocity corresponding to constant energy can only be observed in the frame of the fluctuations, the corresponding constant total magnetic field, invariant for Galilean transformations, remains the observational signature in the spacecraft frame of the constant total energy in the Alfvén turbulence frame.

  13. Fission-fragment angular distributions and total kinetic energies for 235U(n,f) from .18 to 8.83 MeV

    International Nuclear Information System (INIS)

    Meadows, J.W.; Budtz-Joergensen, C.

    1982-01-01

    A gridded ion chamber was used to measure the fission fragment angular distribution and total kinetic energy for the 235 U(n,f) reaction from 0.18 to 8.81 MeV neutron energy. The anisotropies are in generally good agreement with earlier measurements. The average total kinetic energy is approx. 0.2 MeV greater than the thermal value at neutron energies < 2 MeV and shows a sudden decrease of approx. 0.8 MeV between 4 and 5 MeV neutron energy, well below the (n, n'f) threshold. Possible causes of this decrease are a change in the mass distribution or decreased shell effects in the heavy fragment

  14. Simple Examples of the Interpretation of Changes in Kinetic and Potential Energy under Galilean Transformations

    Science.gov (United States)

    Ginsberg, Edw S.

    2018-01-01

    The compatibility of the Newtonian formulation of mechanical energy and the transformation equations of Galilean relativity is demonstrated for three simple examples of motion treated in most introductory physics courses (free fall, a frictionless inclined plane, and a mass/spring system). Only elementary concepts and mathematics, accessible to…

  15. Across-phase biomass pyrolysis stoichiometry, energy balance, and product formation kinetics

    Science.gov (United States)

    Predictive correlations between reactions occurring in the gas-, liquid- and solid-phases are necessary to economically utilize the thermochemical conversion of agricultural wastes impacting the food, water, and energy nexus. On the basis of an empirical mass balance (99.7%), this study established...

  16. Energy transfer within Zn-porphyrin dendrimers: Study of the singlet-singlet annihilation kinetics

    Czech Academy of Sciences Publication Activity Database

    Larsen, J.; Brüggemann, B.; Polívka, Tomáš; Sundström, V.; Akesson, E.; Sly, J.; Crossley, M.J.

    2005-01-01

    Roč. 109, č. 47 (2005), s. 10654-10662 ISSN 1089-5639 Institutional research plan: CEZ:AV0Z50510513 Keywords : Energy transfer * Zn-porphyrin Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.898, year: 2005

  17. Neutron scattering on natural iron at incident energies between 9.4 and 15.2 MeV

    International Nuclear Information System (INIS)

    Schmidt, D.; Mannhart, W.; Klein, H.; Nolte, R.

    1994-11-01

    Neutrons were scattered on a sample of natural iron at 12 incident energies in the range between 9.4 MeV and 15.2 MeV. Differential cross sections of the elastic scattering (natural iron) and of the inelastic scattering to the first excited level of 56 Fe (Q=-0.847 MeV) were determined for angles between 12.5 deg and 160 deg with total uncertainties between of 3% and 10%. Legendre polynomial least-squares fits resulted in integrated cross sections with uncertainties of 2% (elastic data) and 7% (inelastic data). The cross sections obtained in this work were compared with data from the literature. Inelastic scattering cross sections were determined within the scope of a pseudolevel analysis up to excitation energies of nearly 5.5 MeV. At higher excitation energies the scattering spectrum is contaminated by scattered breakup neutrons from the D+d source used hampering an analysis of the data. (orig.) [de

  18. Smooth transition from sudden to adiabatic states in heavy-ion fusion reactions at deep-subbarrier incident energies

    International Nuclear Information System (INIS)

    Takatoshi, Ichikawa; Kouichi, Hagino; Akira, Iwamoto

    2011-01-01

    We propose a novel extension of the standard coupled-channel (CC) model in order to account for the steep falloff of fusion cross sections at deep-subbarrier incident energies. We introduce a damping factor in the coupling potential in the CC model, simulating smooth transitions from sudden to adiabatic states in deep- subbarrier fusion reactions. The CC model extended with the damping factor can reproduce well not only the steep falloff of the fusion cross section but also the saturation of the logarithmic derivatives for the fusion cross sections at deep-subbarrier energies for the 16 O+ 208 Pb, 64 Ni+ 64 Ni, and 58 Ni+ 58 Ni reactions at the deep-subbarrier energies. The important point in our model is that the transition takes place at different places for each Eigen channel. We conclude that the smooth transition from the two-body to the adiabatic one-body potential is responsible for the steep falloff of the fusion cross section

  19. Charged pion coherent production in nucleus-nucleus collisions at incident energies between 86 and 330 MeV/nucleon

    International Nuclear Information System (INIS)

    Fassnacht, P.

    1984-01-01

    We have studied pion production in nucleus-nucleus collisions at foward angles for about twenty projectile target combinations. The incident energies were below or around 300 MeV/nucleon which is the threshold of the elementary reaction NN → NNπ. The study of the inclusive spectra shows some new ideas: shell effects in pion production, collective resonances excitations. These spectra have been analyzed following different models: hard-scattering models which describe the interaction on the basis of the elementary reaction NN → NNπ, statistical model and the pionic cloud model which is a coherent description of the interaction. In the study of the exclusive reactions, we established some empiric rules concerning the cross-section variations. These exclusive spectra were then analyzed in the framework of two-models: the semi-phenomenological model and the pionic fusion [fr

  20. Low-Velocity Impact Wear Behavior of Ball-to-Flat Contact Under Constant Kinetic Energy

    Science.gov (United States)

    Wang, Zhang; Cai, Zhen-bing; Chen, Zhi-qiang; Sun, Yang; Zhu, Min-hao

    2017-11-01

    The impact tests were conducted on metallic materials with different bulk hardness and Young's moduli. Analysis of the dynamics response during the tribological process showed that the tested materials had similar energy absorption, where the peak contact force increased as the tests continued. Moreover, wear volume decreased with the increase in Young's modulus of metals, except for Cr with a relatively low hardness. Wear rate was gradually reduced to a steady stage with increasing cycles, which was attributed to the decrease in contact stress and work-hardening effect. The main wear mechanism of impact was characterized by delamination, and the specific surface degradation mechanisms were depending on the mechanical properties of materials. The absorbed energy was used to the propagation of micro-cracks in the subsurface instead of plastic deformation, when resistance of friction wear and plastic behavior was improved. Hence, both the hardness and Young's modulus played important roles in the impact wear of metallic materials.

  1. Kinetics, Energetics and Infrared Lasing in High Energy Rocket Propellant Ingredients at Cryogenic Temperatures

    Science.gov (United States)

    1977-03-01

    group has achieved. The MINDO program determines the energy of a species, and thus its heat of formation, oy optimizing its geometry such as to...and H.A. McGee, Jr., J. Chem. Phys. 53, 782 (1970). 19. C.T. Kwon and H.A. McGee, Jr., Inorg. Chem. 9, 2458 (1970). 20. C.T. Kwon , H.A. McGee, Jr

  2. Study of the charge kinetics of MgO (1 1 0) subjected to high energy electron irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Boughariou, A., E-mail: aicha_boughariou@yahoo.fr [LaMaCoP, Université de Sfax pour le sud, Faculté des Sciences, 3038 Sfax Tunisie (Tunisia); Kallel, A. [LaMaCoP, Université de Sfax pour le sud, Faculté des Sciences, 3038 Sfax Tunisie (Tunisia); Blaise, G. [LPS, Université Paris-Sud XI, Batiment 510, Orsay 91405 (France)

    2014-09-15

    Highlights: • Variation of the logarithm of SEE yield with the injected dose in MgO (1 1 0) at high energy. • Critical energy E{sub C} of MgO (1 1 0). • Formation of an electrostatic mirror. • Breakdown phenomenon (current density effect). - Abstract: This article presents a study performed with a dedicated scanning electron microscope (SEM) on the electrical property evolution of magnesium oxide (1 1 0) single crystal during 15 and 30 keV irradiation. First, the charging behavior is studied during the charge injection process at low current density J{sub 0}, by measuring the logarithm of the secondary electron emission yield (lnσ). Next, we have investigated the dependence on the current density of the charge-trapping phenomena in MgO (1 1 0). The results shown that beyond the crossover energy E{sub 2}, the observed effects varies depending on whether the energy of the primary electrons is lower or higher than an energy called critical energy E{sub c} = 20 keV (in the case of MgO (1 1 0)). When irradiating the material at E{sub 0} < E{sub c} and at low J{sub 0}, self regulated regime is obtained, if J{sub 0} is sufficiently intense an aging regime is reached. This latter regime is characterized by a positive surface charge, when a negative charge was expected. At E{sub 0} > E{sub c}, and for low J{sub 0}, the detailed monitoring of the charge kinetic of MgO (1 1 0) at high primary energy E{sub 0} = 30 keV, permit to show that the combined effect of the increased negative surface potential during irradiation and extractor field below the surface of MgO fact that lnσ undergoes a strong slope failure at the beginning of the injection and stabilizes at a value much less than zero leading to the formation of an electrostatic mirror. At high J{sub 0}, the consequences of the charge accumulation are violent and a breakdown phenomenon is observed.

  3. Kinetic mechanism of molecular energy transfer and chemical reactions in low-temperature air-fuel plasmas.

    Science.gov (United States)

    Adamovich, Igor V; Li, Ting; Lempert, Walter R

    2015-08-13

    This work describes the kinetic mechanism of coupled molecular energy transfer and chemical reactions in low-temperature air, H2-air and hydrocarbon-air plasmas sustained by nanosecond pulse discharges (single-pulse or repetitive pulse burst). The model incorporates electron impact processes, state-specific N(2) vibrational energy transfer, reactions of excited electronic species of N(2), O(2), N and O, and 'conventional' chemical reactions (Konnov mechanism). Effects of diffusion and conduction heat transfer, energy coupled to the cathode layer and gasdynamic compression/expansion are incorporated as quasi-zero-dimensional corrections. The model is exercised using a combination of freeware (Bolsig+) and commercial software (ChemKin-Pro). The model predictions are validated using time-resolved measurements of temperature and N(2) vibrational level populations in nanosecond pulse discharges in air in plane-to-plane and sphere-to-sphere geometry; temperature and OH number density after nanosecond pulse burst discharges in lean H(2)-air, CH(4)-air and C(2)H(4)-air mixtures; and temperature after the nanosecond pulse discharge burst during plasma-assisted ignition of lean H2-mixtures, showing good agreement with the data. The model predictions for OH number density in lean C(3)H(8)-air mixtures differ from the experimental results, over-predicting its absolute value and failing to predict transient OH rise and decay after the discharge burst. The agreement with the data for C(3)H(8)-air is improved considerably if a different conventional hydrocarbon chemistry reaction set (LLNL methane-n-butane flame mechanism) is used. The results of mechanism validation demonstrate its applicability for analysis of plasma chemical oxidation and ignition of low-temperature H(2)-air, CH(4)-air and C(2)H(4)-air mixtures using nanosecond pulse discharges. Kinetic modelling of low-temperature plasma excited propane-air mixtures demonstrates the need for development of a more accurate

  4. High energy efficiency and high power density proton exchange membrane fuel cells: Electrode kinetics and mass transport

    Science.gov (United States)

    Srinivasan, Supramaniam; Velev, Omourtag A.; Parthasathy, Arvind; Manko, David J.; Appleby, A. John

    1991-01-01

    The development of proton exchange membrane (PEM) fuel cell power plants with high energy efficiencies and high power densities is gaining momentum because of the vital need of such high levels of performance for extraterrestrial (space, underwater) and terrestrial (power source for electric vehicles) applications. Since 1987, considerable progress has been made in achieving energy efficiencies of about 60 percent at a current density of 200 mA/sq cm and high power densities (greater than 1 W/sq cm) in PEM fuel cells with high (4 mg/sq cm) or low (0.4 mg/sq cm) platinum loadings in electrodes. The following areas are discussed: (1) methods to obtain these high levels of performance with low Pt loading electrodes - by proton conductor impregnation into electrodes, localization of Pt near front surface; (2) a novel microelectrode technique which yields electrode kinetic parameters for oxygen reduction and mass transport parameters; (3) demonstration of lack of water transport from anode to cathode; (4) modeling analysis of PEM fuel cell for comparison with experimental results and predicting further improvements in performance; and (5) recommendations of needed research and development for achieving the above goals.

  5. Analytical study on different blade-shape design of HAWT for wasted kinetic energy recovery system (WKERS)

    Science.gov (United States)

    Goh, J. B.; Jamaludin, Z.; Jafar, F. A.; Mat Ali, M.; Mokhtar, M. N. Ali; Tan, C. H.

    2017-06-01

    Wasted kinetic energy recovery system (WKERS) is a wind renewable gadget installed above a cooling tower outlet to harvest the discharged wind for electrical regeneration purpose. The previous WKERS is operated by a horizontal axis wind turbine (HAWT) with delta blade design but the performance is still not at the optimum level. Perhaps, a better blade-shape design should be determined to obtain the optimal performance, as it is believed that the blade-shape design plays a critical role in HAWT. Hence, to determine a better blade-shape design for a new generation of WKERS, elliptical blade, swept blade and NREL Phase IV blade are selected for this benchmarking process. NREL Phase IV blade is a modern HAWT’s blade design by National Renewable Energy Laboratory (NREL) research lab. During the process of benchmarking, Computational Fluid Dynamics (CFD) analysis was ran by using SolidWorks design software, where all the designs are simulated with linear flow simulation. The wind speed in the simulation is set at 10.0 m/s, which is compatible with the average wind speed produced by a standard size cooling tower. The result is obtained by flow trajectories of air motion, surface plot and cut plot of the applied blade-shape. Besides, the aspect ratio of each blade is calculated and included as one of the reference in the comparison. Hence, the final selection of the best blade-shape design will bring to the new generation of WKERS.

  6. Kinetic energy measurement of hydrogen in LHD peripheral plasma with a multi-wavelength-range fine-resolution spectrometer

    International Nuclear Information System (INIS)

    Fujii, Keisuke; Mizushiri, Keisuke; Nishioka, Tomomi; Shikama, Taiichi; Iwamae, Atsushi; Goto, Motoshi; Morita, Shigeru; Hasuo, Masahiro

    2010-01-01

    We have simultaneously measured high resolution emission spectra of the hydrogen atomic Balmer-α, -β, -γ lines and molecular Fulcher-α band for a LHD peripheral plasma generated under a central magnetic field strength of 0.4 T. It is found that the velocity distributions of excited atoms calculated from the Balmer-α, -β, and -γ line shapes show similar profiles to each other. The translational kinetic energy corresponding to the average velocity is about 13 eV, which is about 300 times larger than the rotational energy of hydrogen molecules estimated from the line intensities in the Fulcher-α band. The velocity distributions differ from Maxwellian and have a high velocity tail over 1x10 5 m/s. A correlation between the high velocity tail and the electron temperature and density is seen and suggesting the excited atoms having such high velocities to be generated by the charge exchange collisions from high velocity protons in the peripheral region.

  7. Modelling the mid-infrared drying of sweet potato: kinetics, mass and heat transfer parameters, and energy consumption

    Science.gov (United States)

    Onwude, Daniel I.; Hashim, Norhashila; Abdan, Khalina; Janius, Rimfiel; Chen, Guangnan

    2018-04-01

    This study investigated the drying kinetics, mass and heat transfer characteristics of sweet potato slices (0.4-0.6 cm thickness) during drying based on mid-infrared experimental set-up (intensity of 1100-1400 W/m2). Thin layer drying models were used to evaluate the drying kinetics of sweet potato slices. Two analytical models (Fick's diffusion model, and Dincer and Dost model) were used to study the mass transfer behaviour of sweet potato slices with and without shrinkage during mid-infrared drying. The heat transfer flux between the emitter and sweet potato slices was also investigated. Results demonstrated that an increase in infrared intensity from 1100 W/m2 to 1400 W/m2 resulted in increased in average radiation heat flux by 3.4 times and a 15% reduction in the overall drying time. The two-term exponential model was found to be the best in predicting the drying kinetics of sweet potato slices during mid-infrared drying. The specific heat consumption varied from 0.91-4.82 kWh/kg. The effective moisture diffusivity with and without shrinkage using the Fick's diffusion model varied from 2.632 × 10-9 to 1.596 × 10-8 m2/s, and 1.24 × 10-8 to 2.4 × 10-8 m2/s using Dincer and Dost model, respectively. The obtained values of mass transfer coefficient, Biot number and activation energy varied from 5.99 × 10-6 to 1.17 × 10-5 m/s, 0.53 to 2.62, and 12.83 kJ/mol to 34.64 kJ/mol, respectively. The values obtained for Biot number implied the existence of simultaneous internal and external resistances. The findings further explained that mid-infrared intensity of 1100 W/m2 did not significantly affect the quality of sweet potato during drying, demonstrating a great potential of applying low intensity mid-infrared radiation in the drying of agricultural crops.

  8. Effects of Geostrophic Kinetic Energy on the Distribution of Mesopelagic Fish Larvae in the Southern Gulf of California in Summer/Fall Stratified Seasons.

    Science.gov (United States)

    Contreras-Catala, Fernando; Sánchez-Velasco, Laura; Beier, Emilio; Godínez, Victor M; Barton, Eric D; Santamaría-Del-Angel, Eduardo

    2016-01-01

    Effects of geostrophic kinetic energy flux on the three-dimensional distribution of fish larvae of mesopelagic species (Vinciguerria lucetia, Diogenichthys laternatus, Benthosema panamense and Triphoturus mexicanus) in the southern Gulf of California during summer and fall seasons of stronger stratification were analyzed. The greatest larval abundance was found at sampling stations in geostrophic kinetic energy-poor areas ( 21 J/m3), where mesoscale eddies were present, the larvae of the dominant species had low abundance and were spread more evenly through the water column, in spite of the water column stratification. For example, in a cyclonic eddy, V. lucetia larvae (34 larvae/10m2) extended their distribution to, at least, the limit of sampling 200 m depth below the pycnocline, while D. laternatus larvae (29 larvae/10m2) were found right up to the surface, both probably as a consequence mixing and secondary circulation in the eddy. Results showed that the level of the geostrophic kinetic energy flux affects the abundance and the three-dimensional distribution of mesopelagic fish larvae during the seasons of stronger stratification, indicating that areas with low geostrophic kinetic energy may be advantageous for feeding and development of mesopelagic fish larvae because of greater water column stability.

  9. Dependence of secondary electron emission on the incident angle and the energy of primary electrons bombarding bowl-structured beryllium surfaces

    International Nuclear Information System (INIS)

    Kawata, Jun; Ohya, Kaoru.

    1994-01-01

    A Monte Carlo simulation of the secondary electron emission from beryllium is combined with a model of bowl structure for surface roughness, for analyzing the difference between the electron emissions for normal and oblique incidences. At normal incidence, with increasing the roughness parameter H/W, the primary energy E pm at which the maximum electron yield occurs becomes higher, and at more than the E pm , the decrease in the yield is slower; where H and W are the depth and width of the bowl structure, respectively. The dispersion of incident angle to the microscopic surface causes a small increase in the yield at oblique incidence, whereas the blocking of primary electrons from bombarding the bottom of the structure causes an opposite trend. The strong anisotropy in the polar angular distribution with respect to the azimuthal angle is calculated at oblique incidence. (author)

  10. Pseudorapidity distributions of charged particles as a function of centrality in Pb-Pb collisions at 158 and 40 GeV per nucleon incident energy

    CERN Document Server

    Abreu, M C; Alexa, C; Arnaldi, R; Ataian, M R; Baglin, C; Baldit, A; Bedjidian, Marc; Beolè, S; Boldea, V; Bordalo, P; Borges, G; Bussière, A; Capelli, L; Castanier, C; Castor, J I; Chaurand, B; Chevrot, I; Cheynis, B; Chiavassa, E; Cicalò, C; Claudino, T; Comets, M P; Constans, N; Constantinescu, S; Cortese, P; De Falco, A; De Marco, N; Dellacasa, G; Devaux, A; Dita, S; Drapier, O; Ducroux, L; Espagnon, B; Fargeix, J; Force, P; Gallio, M; Gavrilov, Yu K; Gerschel, C; Giubellino, P; Golubeva, M B; Gonin, M; Grigorian, A A; Grigorian, S; Grossiord, J Y; Guber, F F; Guichard, A; Gulkanian, H R; Hakobyan, R S; Haroutunian, R; Idzik, M; Jouan, D; Karavitcheva, T L; Kluberg, L; Kurepin, A B; Le Bornec, Y; Lourenço, C; Macciotta, P; MacCormick, M; Marzari-Chiesa, A; Masera, M; Masoni, A; Monteno, M; Musso, A; Petiau, P; Piccotti, A; Pizzi, J R; Prado da Silva, W L; Prino, F; Puddu, G; Quintans, C; Ramello, L; Ramos, S; Rato-Mendes, P; Riccati, L; Romana, A; Santos, H; Saturnini, P; Scalas, E; Scomparin, E; Serci, S; Shahoyan, R; Sigaudo, F; Silva, S; Sitta, M; Sonderegger, P; Tarrago, X; Topilskaya, N S; Usai, G L; Vercellin, Ermanno; Villatte, L; Willis, N

    2002-01-01

    The charged particle distributions $dN_{ch}/d\\eta$ have been measured by the NA50 experiment in Pb--Pb collisions at the CERN SPS. Measurements have been done at incident energies of 158 and 40 GeV per nucleon over a broad impact parameter range. Results obtained with two independent centrality estimators, namely the neutral transverse energy $E_T$ and the forward energy $E_{ZDC}$, are reported.}

  11. Turbulent kinetic energy of the ocean winds over the Kuroshio Extension from QuikSCAT winds (1999-2009)

    Science.gov (United States)

    Yu, Kai; Dong, Changming; King, Gregory P.

    2017-06-01

    We investigate mesoscale turbulence (10-1000 km) in the ocean winds over the Kuroshio Extension (28°N-40°N, 140°E-180°E) using the QuikSCAT data set (November 1999 to October 2009). We calculate the second (Djj) and third-order structure functions (Djjj) and the spatial variance (Vj) as a function of scale r (j=L,T denotes, respectively, the longitudinal (divergent) and transverse (vortical) component). The most interesting results of the analysis follow. Although both Vj>(r>) and Djj>(r>) measure the turbulent kinetic energy (TKE), we find that Vj>(r>) is the more robust measure. The spatial variance density (dVj/dr) has a broad peak near 450 km (close to the midlatitude Rossby radius of deformation). On interannual time scales, TKE correlates well with the El Niño 3.4 index. According to turbulence theory, the kinetic energy cascades downscale (upscale) if DLLL>(r>) (also skewness SL=DLLL/DLL3/2) is negative (positive). Our results for the Kuroshio Extension are consistent with a downscale cascade (indicating convergence dominates). Furthermore, classical turbulence theory predicts that SL=-0.3 and independent of r; however, we find SL varies strongly with r, from -4 at small scales to -0.3 at large scales. This nonclassical behavior implies strong-scale interaction, which we attribute to the rapid, and sometimes explosive, growth of storms in the region through baroclinic instability. Finally, we find that ST (a measure of cyclonic/anticyclonic asymmetry) is positive (cyclonic) and also varies strongly with r, from 4 at small scales to 0.5 at large scales. New turbulence models are needed to explain these results, and that will benefit Weather Prediction and climate modeling.Plain Language SummaryThe turbulent winds near the ocean surface give rise to air-sea heat and momentum exchange. The turbulence is caused by convective processes - processes generated at weather fronts, in squalls, tropical disturbances and extra-tropical cyclones. In order to improve

  12. Kinetics and energy efficiency for the degradation of 1,4-dioxane by electro-peroxone process.

    Science.gov (United States)

    Wang, Huijiao; Bakheet, Belal; Yuan, Shi; Li, Xiang; Yu, Gang; Murayama, Seiichi; Wang, Yujue

    2015-08-30

    Degradation of 1,4-dioxane by ozonation, electrolysis, and their combined electro-peroxone (E-peroxone) process was investigated. The E-peroxone process used a carbon-polytetrafluorethylene cathode to electrocatalytically convert O2 in the sparged ozone generator effluent (O2 and O3 gas mixture) to H2O2. The electro-generated H2O2 then react with sparged O3 to yield aqueous OH, which can in turn oxidize pollutants rapidly in the bulk solution. Using p-chlorobenzoic acid as OH probe, the pseudo-steady concentration of OH was determined to be ∼0.744×10(-9)mM in the E-peroxone process, which is approximately 10 and 186 times of that in ozonation and electrolysis using a Pt anode. Thanks to its higher OH concentration, the E-peroxone process eliminated 96.6% total organic carbon (TOC) from a 1,4-dioxane solution after 2h treatment with a specific energy consumption (SEC) of 0.376kWhg(-1) TOCremoved. In comparison, ozonation and electrolysis using a boron-doped diamond anode removed only ∼6.1% and 26.9% TOC with SEC of 2.43 and 0.558kWhg(-1) TOCremoved, respectively. The results indicate that the E-peroxone process can significantly improve the kinetics and energy efficiency for 1,4-dioxane mineralization as compared to the two individual processes. The E-peroxone process may thus offer a highly effective and energy-efficient alternative to treat 1,4-dioxane wastewater. Copyright © 2015 Elsevier B.V. All rights reserved.

  13. Energy

    CERN Document Server

    Robertson, William C

    2002-01-01

    Confounded by kinetic energy? Suspect that teaching about simple machines isn t really so simple? Exasperated by electricity? If you fear the study of energy is beyond you, this entertaining book will do more than introduce you to the topic. It will help you actually understand it. At the book s heart are easy-to-grasp explanations of energy basics work, kinetic energy, potential energy, and the transformation of energy and energy as it relates to simple machines, heat energy, temperature, and heat transfer. Irreverent author Bill Robertson suggests activities that bring the basic concepts of energy to life with common household objects. Each chapter ends with a summary and an applications section that uses practical examples such as roller coasters and home heating systems to explain energy transformations and convection cells. The final chapter brings together key concepts in an easy-to-grasp explanation of how electricity is generated. Energy is the second book in the Stop Faking It! series published by NS...

  14. Kinetic energy dissipation of a tuning fork immersed in superfluid helium at different frequencies of oscillations

    International Nuclear Information System (INIS)

    Gritsenko, I.A.; Klokol, K.A.; Sokolov, S.S.; Sheshin, G.A.

    2016-01-01

    An experimental study is made of the drag coefficient, which is the characteristics of energy dissipation during oscillations of the tuning forks, immersed in liquid helium. The experiments were performed in the temperature range from 0.1 to 3.5 K covering both the range of a hydrodynamic flow, and the ballistic regime of transfer of thermal excitations of superfluid helium below 0.6 K. It is found that there is the frequency dependence of the drag coefficient in the hydrodynamic limit, when the main dissipation mechanism is the viscous friction of the fluid against the walls of the oscillating body at temperatures above 0.7 K. In this case, the drag coefficient is proportional to the square root of the frequency of oscillation, and its temperature dependence in He II is determined by the respective dependence of the normal component density of the normal component and the viscosity of the fluid. At lower temperatures, the dependence of drag coefficient on the frequency is not available, and the magnitude of the dissipative losses is determined only by the temperature dependence of the density of the normal component. At the same time in the entire range of temperatures value of dissipative losses depends on the geometry of the oscillating body.

  15. Effects of chiral three-nucleon forces on 4He-nucleus scattering in a wide range of incident energies

    Science.gov (United States)

    Toyokawa, Masakazu; Yahiro, Masanobu; Matsumoto, Takuma; Kohno, Michio

    2018-02-01

    An important current subject is to clarify the properties of chiral three-nucleon forces (3NFs) not only in nuclear matter but also in scattering between finite-size nuclei. Particularly for elastic scattering, this study has just started and the properties are not understood for a wide range of incident energies (E_in). We investigate basic properties of chiral 3NFs in nuclear matter with positive energies by using the Brueckner-Hartree-Fock method with chiral two-nucleon forces at N3LO and 3NFs at NNLO, and analyze the effects of chiral 3NFs on 4He elastic scattering from targets ^{208}Pb, ^{58}Ni, and ^{40}Ca over a wide range of 30 ≲ E_in/A_P ≲ 200 MeV by using the g-matrix folding model, where A_P is the mass number of the projectile. In symmetric nuclear matter with positive energies, chiral 3NFs make the single-particle potential less attractive and more absorptive. The effects mainly come from the Fujita-Miyazawa 2π-exchange 3NF and become slightly larger as E_in increases. These effects persist in the optical potentials of 4He scattering. As for the differential cross sections of 4He scattering, chiral-3NF effects are large for E_in/A_P ≳ 60 MeV and improve the agreement of the theoretical results with the measured ones. Particularly for E_in/A_P ≳ 100 MeV, the folding model reproduces measured differential cross sections pretty well. Cutoff (Λ) dependence is investigated for both nuclear matter and 4He scattering by considering two cases of Λ=450 and 550 MeV. The uncertainty coming from the dependence is smaller than chiral-3NF effects even at E_in/A_P=175 MeV.

  16. Simultaneous application of microwave energy and hot air to whole drying process of apple slices: drying kinetics, modeling, temperature profile and energy aspect

    Science.gov (United States)

    Horuz, Erhan; Bozkurt, Hüseyin; Karataş, Haluk; Maskan, Medeni

    2018-02-01

    Drying kinetics, modeling, temperature profile and energy indices were investigated in apple slices during drying by a specially designed microwave-hot air domestic hybrid oven at the following conditions: 120, 150 and 180 W microwave powers coupled with 50, 60 and 70 °C air temperatures. Both sources of energy were applied simultaneously during the whole drying processes. The drying process continued until the moisture content of apple slices reached to 20% from 86.3% (wet basis, w.b). Drying times ranged from 330 to 800 min and decreased with increasing microwave power and air temperatures. The constant rate period was only observed at low microwave powers and air temperatures. Two falling rate periods were observed. Temperature of apple slices sharply increased within the first 60 min, then reached equilibrium with drying medium and finally increased at the end of the drying process. In order to describe drying behavior of apple slices nine empirical models were applied. The Modified Logistic Model fitted the best our experimental data ( R 2 = 0.9955-0.9998; χ 2 = 3.46 × 10-5-7.85 × 10-4 and RMSE = 0.0052-0.0221). The effective moisture and thermal diffusivities were calculated by Fick's second law and ranged from 1.42 × 10-9 to 3.31 × 10-9 m2/s and 7.70 × 10-9 to 12.54 × 10-9 m2/s, respectively. The activation energy ( Ea) values were calculated from effective moisture diffusivity ( Deff), thermal diffusivity ( α) and the rate constant of the best model ( k). The Ea values found from these three terms were similar and varied from 13.04 to 33.52 kJ/mol. Energy consumption and specific energy requirement of the hybrid drying of apple slices decreased and energy efficiency of the drying system increased with increasing microwave power and air temperature. Apples can be dried rapidly and effectively by use of the hybrid technique.

  17. The interaction of C60 on Si(111 7x7 studied by Supersonic Molecular Beams: interplay between precursor kinetic energy and substrate temperature in surface activated processes.

    Directory of Open Access Journals (Sweden)

    Lucrezia eAversa

    2015-06-01

    Full Text Available Buckminsterfullerene (C60 is a molecule fully formed of carbon that can be used, owing to its electronic and mechanical properties, as clean precursor for the growth of carbon-based materials, ranging from -conjugated systems (graphenes to synthesized species, e.g. carbides such as silicon carbide (SiC. To this goal, C60 cage rupture is the main physical process that triggers material growth. Cage breaking can be obtained either thermally by heating up the substrate to high temperatures (630°C, after C60 physisorption, or kinetically by using Supersonic Molecular Beam Epitaxy (SuMBE techniques. In this work, aiming at demonstrating the growth of SiC thin films by C60 supersonic beams, we present the experimental investigation of C60 impacts on Si(111 7x7 kept at 500°C for translational kinetic energies ranging from 18 to 30 eV. The attained kinetically activated synthesis of SiC submonolayer films is probed by in-situ surface electron spectroscopies (XPS and UPS. Furthermore, in these experimental conditions the C60-Si(111 7×7 collision has been studied by computer simulations based on a tight-binding approximation to Density Functional Theory, DFT. Our theoretical and experimental findings point towards a kinetically driven growth of SiC on Si, where C60 precursor kinetic energy plays a crucial role, while temperature is relevant only after cage rupture to enhance Si and carbon reactivity. In particular, we observe a counterintuitive effect in which for low kinetic energy (below 22 eV, C60 bounces back without breaking more effectively at high temperature due to energy transfer from excited phonons. At higher kinetic energy (22 < K < 30 eV, for which cage rupture occurs, temperature enhances reactivity without playing a major role in the cage break. These results are in good agreement with ab-initio molecular dynamics simulations. SuMBE is thus a technique able to drive materials growth at low temperature regime.

  18. Digesta kinetics, energy intake, grazing behavior, and body temperature of grazing beef cattle differing in adaptation to heat.

    Science.gov (United States)

    Sprinkle, J E; Holloway, J W; Warrington, B G; Ellist, W C; Stuth, J W; Forbes, T D; Greene, L W

    2000-06-01

    The objective of this study was to determine whether digesta kinetics, energy intake (EI, kcal ME intake x kg(-.75) x d(-1)), grazing behavior, or body temperature differed by breed, lactational state, or season of the year among cattle presumed to vary in adaptability to the subtropics. Two-year-old lactating and nonlactating Brahman x Angus (BA; n = 5, n = 5), Tuli x Angus (TA; n = 5, n = 4), and Angus (A; n = 4, n = 4) cows were used. During both early (ES) and late summer (LS), lactating cattle vs nonlactating cattle had greater gastrointestinal tract load (CM2) and EI (P .48). During LS, lactating cattle had decreased early morning rectal temperatures (P .26) late afternoon rectal temperatures compared with BA and TA. With data pooled over both grazing trials, BA cattle had the smallest CM2 (P .28) early morning rectal temperatures compared with BA during ES and LS. During LS, TA spent more time in the sun and less time in the shade than did either A or BA (P .50). During LS, EI for lactating A was greater than for BA and TA (P < .05), and EI for nonlactating BA was less than for A and TA (P < .05). Bite rate per minute for lactating cattle during ES was reduced (P < .03) by increased body condition score. Tuli x Angus cattle appear to be comparable to BA with respect to heat adaptation. It appears that EI demands are greater in a hot environment.

  19. Anisotropy of the proton kinetic energy in CsH2PO4 and KH2PO4

    Science.gov (United States)

    Finkelstein, Y.; Moreh, R.; Shchur, Ya.

    2018-02-01

    The strong anisotropy of the proton mean kinetic energy, Ke(H), in a single crystal of KH2PO4 (KDP), measured by deep inelastic neutron scattering (DINS), is compared with that calculated for its Cs analogue, CsH2PO4 (CDP) in the ferroelectric (FE) and paraelectric (PE) phases. Empirical lattice dynamics (LD) calculations were used to simulate the partial vibrational density of states shared by the protons (H-VDOS), from which Ke(H) values were deduced. Good agreement was found between the measured and calculated Ke(H) values of the two samples despite the different hydrogen bond dynamics. However, the directional components of Ke(H) in the two samples were quite different. In both cases, the Ke(H) tensor is nearly an ellipsoid of rotation: in KDP the shape is oblate around the major axis while being prolate in CDP. By resolving the directional Ke(H) values of the two non-equivalent protons of CDP, a possible signature of competing quantum effects is indicated.

  20. Linear free energy relationship and deuterium kinetic isotope effect observed on phospho and thiophosphoryl transfer reactions in some organophosphorous compounds

    International Nuclear Information System (INIS)

    Lumbiny, B J; Islam, M A; Rahman, M; Hui, Z; Quader, M A

    2014-01-01

    Tetracoordinated organophosphorous compounds were synthesized, characterized and nucleophilic substitution reaction were investigated by varying substituents around phosphorous centre or in nucleophile considering its utility in biological and environmental system. The reactivity is expressed in terms of second-order rate constant, k 2 and measured conductometrically. Linear Free Energy Relationship (LFER) tools mainly Hammett (ρ), Brönsted (β) LFER coefficients and deuterium kinetic isotope effects (KIEs) being determined for the pyridinolysis of 4 – chlorophenyl 4 – methoxy phenyl chlorophosphate, 1 in acetonitrile at 5.0 °C. The experimental data's were compared with those of structurally similar organophosphorous compounds reported earlier in quest for the mechanistic information. Nice linear correlation being found for Hammett (logk 2 vs σ x ), having negative value of the ρ X = −5.85 and Brönsted (logk 2 vs pK a(x) ) plots having large positive value for β X = 1.18 for 1 can be interpreted as S N 2 process with greater extent of bond formation in transition state (TS) of 1. The observed k H /k D values of 1 is 1.00 ± 0.05 and net KIE, 1.32 suggests the primary KIE and indicates frontside nucleophilic attack through the partial deprotonation of pyridine occurs by the hydrogen bonding in the rate-determining step.

  1. INVESTIGATION OF THE KINETICS OF DRYING SEEDS THISTLE IN VORTEX CHAMBER WITH MICROWAVE ENERGY SUPPLY

    Directory of Open Access Journals (Sweden)

    D. A. Kazartsev

    2015-01-01

    Full Text Available In the study of the current state of the theory, techniques and technologies for processing of milk thistle showed up a number of problems. One of those moments - the need to promptly provide quality and efficient process for drying seeds, but Russia has not produced special equipment for postharvest processing of seeds of milk thistle, and used for drying grain domestic appliances, represented mainly by mining and drum dryers, it is not suitable for thistle. This is due to the fact that, firstly, in the dewatering process is necessary to provide a relatively low final moisture drying product (5-6 %, and, secondly, to keep their beneficial substance in full, which imposes additional restrictions on the conditions of drying. One way of creating a new drying technology development and implementation in the industry of high-intensive devices with active hydrodynamic regimes with microwave energy supply, providing in many cases, higher technical and economic indicators. Therefore, the use of devices with swirling flow of heat-carrier for the intensification of the process of drying of dispersed materials is both theoretical interest and practical value. Microwave drying is based on the fact that the dielectric properties of water and dry food substances are different: the wet material is heated much faster than dry. During the microwave drying temperature wetter internal layers higher than the exterior more dehydrated (which creates a "right" - from the inner to the outer layers of the product - the gradient of moisture mass transfer is not realizable in any of the other known methods of drying. Milk thistle seeds have a unique composition: 25-32 % fatty oil, 15-17 % protein, 26 % fat, in the-soluble (B group and fat-soluble (A, D, E, K, F vitamins, mono- and disaccharides, macro- and trace elements (copper, zinc, selenium, dietary fiber and enzymes, mucus, up to 5 % (glucose, etc., phenolic compounds including flaviolignans 2-3% (silibinin

  2. Spatiotemporal Variability of Turbulence Kinetic Energy Budgets in the Convective Boundary Layer over Both Simple and Complex Terrain

    Energy Technology Data Exchange (ETDEWEB)

    Rai, Raj K. [Pacific Northwest National Laboratory, Richland, Washington; Berg, Larry K. [Pacific Northwest National Laboratory, Richland, Washington; Pekour, Mikhail [Pacific Northwest National Laboratory, Richland, Washington; Shaw, William J. [Pacific Northwest National Laboratory, Richland, Washington; Kosovic, Branko [National Center for Atmospheric Research, Boulder, Colorado; Mirocha, Jeffrey D. [Lawrence Livermore National Laboratory, Livermore, California; Ennis, Brandon L. [Sandia National Laboratories, Albuquerque, New Mexico

    2017-12-01

    The assumption of sub-grid scale (SGS) horizontal homogeneity within a model grid cell, which forms the basis of SGS turbulence closures used by mesoscale models, becomes increasingly tenuous as grid spacing is reduced to a few kilometers or less, such as in many emerging high-resolution applications. Herein, we use the turbulence kinetic energy (TKE) budget equation to study the spatio-temporal variability in two types of terrain—complex (Columbia Basin Wind Energy Study [CBWES] site, north-eastern Oregon) and flat (ScaledWind Farm Technologies [SWiFT] site, west Texas) using the Weather Research and Forecasting (WRF) model. In each case six-nested domains (three domains each for mesoscale and large-eddy simulation [LES]) are used to downscale the horizontal grid spacing from 10 km to 10 m using the WRF model framework. The model output was used to calculate the values of the TKE budget terms in vertical and horizontal planes as well as the averages of grid cells contained in the four quadrants (a quarter area) of the LES domain. The budget terms calculated along the planes and the mean profile of budget terms show larger spatial variability at CBWES site than at the SWiFT site. The contribution of the horizontal derivative of the shear production term to the total production shear was found to be 45% and 15% of the total shear, at the CBWES and SWiFT sites, respectively, indicating that the horizontal derivatives applied in the budget equation should not be ignored in mesoscale model parameterizations, especially for cases with complex terrain with <10 km scale.

  3. Kinetic isotope effects in the CH4 + H→CH3 + H2 system. Predictions of the LMR six-body potential-energy reaction hypersurface

    International Nuclear Information System (INIS)

    Marriott, T.D.

    1976-01-01

    Scope of Study: The purpose of this study was two-fold. First, it served to test, in part, the usefulness of the LMR six-body potential-energy surface (LMR-PES) for transition-state theory predictions of the kinetic isotope effects for both the forward and reverse reactions of CH 4 + H reversible CH 3 + H 2 . In this regard the agreement between experimental and theoretical isotope effects, assuming the former to be accurate, provides information about the accuracy of the curvature of the potential energy surface for motion both parallel and perpendicular to the reaction coordinate. Second, these isotope effects were used to assess the validity of a number of qualitative and semi-quantitative interpretations of kinetic isotope effects developed in physical organic chemistry with regard to this reaction system. The force constants and geometries obtained numerically from the LMR-PES were found to produce reasonable harmonic approximations to the reactant normal mode frequencies. Neglecting tunneling, the LMR-PES reasonably reproduces the experimental k/sub H//k/sub D/ values for the reactions CH 4 + H(D), CH 3 + HD(DH) and CD 2 + HD(DH). Since previous theoretical treatments of primary deuterium kinetic isotope effects have neglected the bending normal mode frequencies, a semi-quantitative study of the effect of neglecting bending frequencies on the VP, EXC, and ZPE elements as well as the transition-state theory kinetic isotope effects was performed. The Swain-Schaad relationship between primary deuterium and tritium kinetic isotope effects was shown to hold to a reasonable degree of accuracy for the LMR-PES reaction system. A relationship between 13-carbon and 14-carbon kinetic isotope effects similar to the Swain-Schaad relationship was derived

  4. An improved experimental scheme for simultaneous measurement of high-resolution zero electron kinetic energy (ZEKE) photoelectron and threshold photoion (MATI) spectra

    Science.gov (United States)

    Michels, François; Mazzoni, Federico; Becucci, Maurizio; Müller-Dethlefs, Klaus

    2017-10-01

    An improved detection scheme is presented for threshold ionization spectroscopy with simultaneous recording of the Zero Electron Kinetic Energy (ZEKE) and Mass Analysed Threshold Ionisation (MATI) signals. The objective is to obtain accurate dissociation energies for larger molecular clusters by simultaneously detecting the fragment and parent ion MATI signals with identical transmission. The scheme preserves an optimal ZEKE spectral resolution together with excellent separation of the spontaneous ion and MATI signals in the time-of-flight mass spectrum. The resulting improvement in sensitivity will allow for the determination of dissociation energies in clusters with substantial mass difference between parent and daughter ions.

  5. Numerical impact simulation of gradually increased kinetic energy transfer has the potential to break up folded protein structures resulting in cytotoxic brain tissue edema.

    Science.gov (United States)

    von Holst, Hans; Li, Xiaogai

    2013-07-01

    Although the consequences of traumatic brain injury (TBI) and its treatment have been improved, there is still a substantial lack of understanding the mechanisms. Numerical simulation of the impact can throw further lights on site and mechanism of action. A finite element model of the human head and brain tissue was used to simulate TBI. The consequences of gradually increased kinetic energy transfer was analyzed by evaluating the impact intracranial pressure (ICP), strain level, and their potential influences on binding forces in folded protein structures. The gradually increased kinetic energy was found to have the potential to break apart bonds of Van der Waals in all impacts and hydrogen bonds at simulated impacts from 6 m/s and higher, thereby superseding the energy in folded protein structures. Further, impacts below 6 m/s showed none or very slight increase in impact ICP and strain levels, whereas impacts of 6 m/s or higher showed a gradual increase of the impact ICP and strain levels reaching over 1000 KPa and over 30%, respectively. The present simulation study shows that the free kinetic energy transfer, impact ICP, and strain levels all have the potential to initiate cytotoxic brain tissue edema by unfolding protein structures. The definition of mild, moderate, and severe TBI should thus be looked upon as the same condition and separated only by a gradual severity of impact.

  6. An entropic approach to magnetized nonlocal transport and other kinetic phenomena in high-energy-density plasmas

    International Nuclear Information System (INIS)

    Del-Sorbo, Dario

    2015-01-01

    Hydrodynamic simulations in high-energy-density physics and inertial confinement fusion require a detailed description of energy fluxes. The leading mechanism is the electron transport, which can be a nonlocal phenomenon that needs to be described with quasistationary and simplified Fokker-Planck models in large scale hydrodynamic codes. My thesis is dedicated to the development of a new nonlocal transport model based on a fast-moving-particles collision operator and on a first moment Fokker-Planck equation, simplified with an entropic closure relation. Such a closure enables a better description of the electron distribution function in the limit of high anisotropies, where small scale electrostatic instabilities could be excited. This new model, so called M1, is successfully compared with the well known nonlocal electron transport model proposed by Schurtz, Nicolai and Busquet, using different collision operators, and with the reduced Fokker-Planck model, based on a small-anisotropies polynomial closure relation (P1). Several typical configurations of heat transport are considered. We show that the M1 entropic model may operate in two and three dimensions and is able to account for electron transport modifications in external magnetic fields. Moreover, our model enables to compute realistic electron distribution functions, which can be used for kinetic studies, as for the plasma stability in the transport zone. It is demonstrated that the electron energy transport may strongly modify damping of Langmuir and ion acoustic waves, while the simplified nonlocal transport models are not able to describe accurately the modifications of the distribution function and plasma wave damping. The structure of the M1 model allows to naturally take into account self-generated magnetic fields, which play a crucial role in multidimensional simulations. Moreover, magnetic fields could also be used for the focusing of energetic particles in alternative ignition schemes. The M1 model

  7. Kinetic energies of charged fragments resulting from multifragmentation and asymmetric fission of the C{sub 60} molecule in collisions with monocharged ions (2-130 keV)

    Energy Technology Data Exchange (ETDEWEB)

    Rentenier, A; Bordenave-Montesquieu, D; Moretto-Capelle, P; Bordenave-Montesquieu, A [Laboratoire CAR-IRSAMC, UMR 5589 CNRS - Universite Paul Sabatier, 118 Route de Narbonne, 31062 Toulouse Cedex (France)

    2003-04-28

    Multifragmentation and asymmetric fission (AF) of the C{sub 60} molecule induced by H{sup +}, H{sub 2}{sup +}, H{sub 3}{sup +} and He{sup +} ions at medium collision energies (2-130 keV) are considered. Momenta and kinetic energies of C{sub n}{sup +} fragment ions (n = 1- 12) are deduced from an analysis of time-of-flight spectra. In multifragmentation processes, momenta are found to be approximately constant when n > 2, a behaviour which explains that the most probable kinetic energy, as well as the width of the kinetic energy distributions, is found to be inversely proportional to the fragment size n; both momenta and kinetic energies are independent of the velocity and nature of the projectile, and hence of the energy deposit. A specific study of the AF shows that the kinetic energies of C{sub 2}{sup +}, C{sub 4}{sup +} and C{sub 6}{sup +} fragments are also independent of the collision velocity and projectile species; a quantitative agreement is found with values deduced from kinetic energy release measurements by another group in electron impact experiments, and the observed decrease when the mass of the light fragment increases is also reproduced. A quantitative comparison of AF and multifragmentation for the n = 2, 4 and 6 fragment ions shows that kinetic energies in AF exceed that in multifragmentation, a result which explains the oscillations observed when momenta or kinetic energies of fragments are plotted against the n-value. The AF yield is also found to scale with the energy deposit in the collision velocity range extending below the velocity at the maximum of the electronic stopping power; except for protons, it remains negligible with respect to multifragmentation as soon as the total energy deposit exceeds about 100 eV.

  8. Quantitative detection of benzene in toluene- and xylene-rich atmospheres using high-kinetic-energy ion mobility spectrometry (IMS).

    Science.gov (United States)

    Langejuergen, Jens; Allers, Maria; Oermann, Jens; Kirk, Ansgar; Zimmermann, Stefan

    2014-12-02

    One major drawback of ion mobility spectrometry (IMS) is the dependence of the response to a certain analyte on the concentration of water or the presence of other compounds in the sample gas. Especially for low proton affine analytes, e.g., benzene, which often exists in mixtures with other volatile organic compounds, such as toluene and xylene (BTX), a time-consuming preseparation is necessary. In this work, we investigate BTX mixtures using a compact IMS operated at decreased pressure (20 mbar) and high kinetic ion energies (HiKE-IMS). The reduced electric field in both the reaction tube and the drift tube can be independently increased up to 120 Td. Under these conditions, the water cluster distribution of reactant ions is shifted toward smaller clusters independent of the water content in the sample gas. Thus, benzene can be ionized via proton transfer from H3O(+) reactant ions. Also, a formation of benzene ions via charge transfer from NO(+) is possible. Furthermore, the time for interaction between ions and neutrals of different analytes is limited to such an extent that a simultaneous quantification of benzene, toluene, and xylene is possible from low ppbv up to several ppmv concentrations. The mobility resolution of the presented HiKE-IMS varies from R = 65 at high field (90 Td) to R = 73 at lower field (40 Td) in the drift tube, which is sufficient to separate the analyzed compounds. The detection limit for benzene is 29 ppbv (2 s of averaging) with 3700 ppmv water, 12.4 ppmv toluene, and 9 ppmv xylene present in the sample gas. Furthermore, a less-moisture-dependent benzene measurement with a detection limit of 32 ppbv with ca. 21 000 ppmv (90% relative humidity (RH) at 20 °C) water present in the sample gas is possible evaluating the signal from benzene ions formed via charge transfer.

  9. Rydberg gas theory of a glow discharge plasma: III. Formation, occupied state distributions, free energy, and kinetic control.

    Science.gov (United States)

    Mason, Rod S; Douglas, Peter

    2010-04-21

    It has been suggested that Rydberg gas atoms are involved in conducting electricity through a steady state flowing afterglow (FAG) discharge plasma (R. S. Mason, D. J. Mitchell and P. M. Dickinson, Phys. Chem. Chem. Phys., 2010, DOI: ). From known properties of Rydberg atoms, a statistical model is developed here to find the distribution of levels (principal quantum number n) occupied in such a hypothetical Rydberg gas. It behaves non-ideally at positive column plasma densities, predicting 30 120 kJ mol(-1) below ionisation level when 10(10) < or = N(R) < or = 10(11) atoms cm(-3)) but this is approximately 11 kJ mol(-1) higher than that of the equivalent free ion-electron gas; therefore if it exists in preference to the classical form of the plasma, it is controlled by kinetic factors. A mechanism is suggested by which this could occur. Thus, whilst ionization by high energy electron impact occurs at the Cathode Fall-Negative Glow (NG) boundary as usual, excitation of Rydberg atoms becomes more probable, by electrons slowed by collision and deceleration at the opposite NG-Positive Column (PC) plasma boundary. The atoms become stabilized after passing into the PC, by collisionally induced (nlm) mixing of states and the removal of free charge by charge transfer (and hence the passage of electric current through the Rydberg gas). The coupling of Rydberg states with the ionization continuum is poor; therefore, if the rate of their charge transfer is greater than that of their ionization, the Rydberg gas will remain relatively charge free and hence stable when it is conducting a current. When applied to the FAG plasma, the model provides a self-consistent interpretive framework for all its electrical, mass spectrometric and chemical behaviour. The effect on the optical spectroscopy of these plasmas is considered briefly.

  10. Evaluation of Scaling Approaches for the Oceanic Dissipation Rate of Turbulent Kinetic Energy in the Surface Ocean

    Science.gov (United States)

    Esters, L. T.; Ward, B.; Sutherland, G.; Ten Doeschate, A.; Landwehr, S.; Bell, T. G.; Christensen, K. H.

    2016-02-01

    The air-sea exchange of heat, gas and momentum plays an important role for the Earth's weather and global climate. The exchange processes between ocean and atmosphere are influenced by the prevailing surface ocean dynamics. This surface ocean is a highly turbulent region where there is enhanced production of turbulent kinetic energy (TKE). The dissipation rate of TKE (ɛ) in the surface ocean is an important process for governing the depth of both the mixing and mixed layers, which are important length-scales for many aspects of ocean research. However, there exist very limited observations of ɛ under open ocean conditions and consequently our understanding of how to model the dissipation profile is very limited. The approaches to model profiles of ɛ that exist, differ by orders of magnitude depending on their underlying theoretical assumption and included physical processes. Therefore, scaling ɛ is not straight forward and requires open ocean measurements of ɛ to validate the respective scaling laws. This validated scaling of ɛ, is for example required to produce accurate mixed layer depths in global climate models. Errors in the depth of the ocean surface boundary layer can lead to biases in sea surface temperature. Here, we present open ocean measurements of ɛ from the Air-Sea Interaction Profiler (ASIP) collected during several cruises in different ocean basins. ASIP is an autonomous upwardly rising microstructure profiler allowing undisturbed profiling up to the ocean surface. These direct measurements of ɛ under various types of atmospheric and oceanic conditions along with measurements of atmospheric fluxes and wave conditions allow us to make a unique assessment of several scaling approaches based on wind, wave and buoyancy forcing. This will allow us to best assess the most appropriate ɛ-based parameterisation for air-sea exchange.

  11. Effect of External Pressure and Catheter Gauge on Flow Rate, Kinetic Energy, and Endothelial Injury During Intravenous Fluid Administration in a Rabbit Model.

    Science.gov (United States)

    Hu, Mei-Hua; Chan, Wei-Hung; Chen, Yao-Chang; Cherng, Chen-Hwan; Lin, Chih-Kung; Tsai, Chien-Sung; Chou, Yu-Ching; Huang, Go-Shine

    2016-01-01

    The effects of intravenous (IV) catheter gauge and pressurization of IV fluid (IVF) bags on fluid flow rate have been studied. However, the pressure needed to achieve a flow rate equivalent to that of a 16 gauge (G) catheter through smaller G catheters and the potential for endothelial damage from the increased kinetic energy produced by higher pressurization are unclear. Constant pressure on an IVF bag was maintained by an automatic adjustable pneumatic pressure regulator of our own design. Fluids running through 16 G, 18 G, 20 G, and 22 G catheters were assessed while using IV bag pressurization to achieve the flow rate equivalent to that of a 16 G catheter. We assessed flow rates, kinetic energy, and flow injury to rabbit inferior vena cava endothelium. By applying sufficient external constant pressure to an IVF bag, all fluids could be run through smaller (G) catheters at the flow rate in a 16 G catheter. However, the kinetic energy increased significantly as the catheter G increased. Damage to the venous endothelium was negligible or minimal/patchy cell loss. We designed a new rapid infusion system, which provides a constant pressure that compresses the fluid volume until it is free from visible residual fluid. When large-bore venous access cannot be obtained, multiple smaller catheters, external pressure, or both should be considered. However, caution should be exercised when fluid pressurized to reach a flow rate equivalent to that in a 16 G catheter is run through a smaller G catheter because of the profound increase in kinetic energy that can lead to venous endothelium injury.

  12. Dynamical influence of gravity waves generated by the Vestfjella Mountains in Antarctica: radar observations, fine-scale modelling and kinetic energy budget analysis

    Directory of Open Access Journals (Sweden)

    Joel Arnault

    2012-02-01

    Full Text Available Gravity waves generated by the Vestfjella Mountains (in western Droning Maud Land, Antarctica, southwest of the Finnish/Swedish Aboa/Wasa station have been observed with the Moveable atmospheric radar for Antarctica (MARA during the SWEDish Antarctic Research Programme (SWEDARP in December 2007/January 2008. These radar observations are compared with a 2-month Weather Research Forecast (WRF model experiment operated at 2 km horizontal resolution. A control simulation without orography is also operated in order to separate unambiguously the contribution of the mountain waves on the simulated atmospheric flow. This contribution is then quantified with a kinetic energy budget analysis computed in the two simulations. The results of this study confirm that mountain waves reaching lower-stratospheric heights break through convective overturning and generate inertia gravity waves with a smaller vertical wavelength, in association with a brief depletion of kinetic energy through frictional dissipation and negative vertical advection. The kinetic energy budget also shows that gravity waves have a strong influence on the other terms of the budget, i.e. horizontal advection and horizontal work of pressure forces, so evaluating the influence of gravity waves on the mean-flow with the vertical advection term alone is not sufficient, at least in this case. We finally obtain that gravity waves generated by the Vestfjella Mountains reaching lower stratospheric heights generally deplete (create kinetic energy in the lower troposphere (upper troposphere–lower stratosphere, in contradiction with the usual decelerating effect attributed to gravity waves on the zonal circulation in the upper troposphere–lower stratosphere.

  13. Maintenance of the mean kinetic energy in the global ocean by the barotropic and baroclinic energy routes: the roles of JEBAR and Ekman dynamics

    Science.gov (United States)

    Aiki, Hidenori; Richards, Kelvin J.; Sakuma, Hirofumi

    2011-05-01

    In order to determine the maintenance mechanisms of the currents of the global ocean, this study investigates the budget of the annual mean kinetic energy (KE) in a high-resolution (0.1° × 0.1°) semi-global ocean simulation. The analysis is based on a separation of the mean KE using the barotropic (i.e., depth-averaged) and baroclinic (the residual) components of velocity. The barotropic and baroclinic KEs dominate in higher and lower latitudes, respectively, with their global average being comparable to each other. The working rates of wind forcing on the barotropic and baroclinic circulations in the global ocean are 243 and 747 gigawatts, respectively. This study presents at least three new results for the budget of the barotropic KE. Firstly, an energy diagram is rederived to show that the work of the barotropic component of the horizontal pressure gradient (HPG) is connected to the work related to the joint effect of baroclinicity and bottom relief (JEBAR), and then to the budget of potential energy (PE). Secondly, the model analysis shows that the globally averaged work of the barotropic HPG (which is connected to the work related to JEBAR and then to the budget of the PE) is nearly zero. This indicates that the wind- and buoyancy-induced barotropic circulations in the global ocean are of the same strength with opposite sign. Thirdly, it is found that the work of the wind forcing on the barotropic component of the simulated Antarctic Circumpolar Current (ACC) is canceled by the combined effect, in equal measure, of the work of the barotropic HPG and the work of dissipative processes for mean KE. This result makes a significant contribution to the discussion on the depth-integrated momentum balance of the ACC. The barotropic KE is dissipated by the effects of bottom frictional stress, lateral frictional stress, and the Reynolds stress, of which more than half is attributed to an unexpectedly large contribution from biharmonic horizontal friction. Future

  14. HETC-3STEP calculations of proton induced nuclide production cross sections at incident energies between 20 MeV and 5 GeV

    International Nuclear Information System (INIS)

    Takada, Hiroshi; Yoshizawa, Nobuaki; Ishibashi, Kenji.

    1996-08-01

    For the OECD/NEA code intercomparison, nuclide production cross sections of 16 O, 27 Al, nat Fe, 59 Co, nat Zr and 197 Au for the proton incidence with energies of 20 MeV to 5 GeV are calculated with the HETC-3STEP code based on the intranuclear cascade evaporation model including the preequilibrium and high energy fission processes. In the code, the level density parameter derived by Ignatyuk, the atomic mass table of Audi and Wapstra and the mass formula derived by Tachibana et al. are newly employed in the evaporation calculation part. The calculated results are compared with the experimental ones. It is confirmed that HETC-3STEP reproduces the production of the nuclides having the mass number close to that of the target nucleus with an accuracy of a factor of two to three at incident proton energies above 100 MeV for nat Zr and 197 Au. However, the HETC-3STEP code has poor accuracy on the nuclide production at low incident energies and the light nuclide production through the fragmentation process induced by protons with energies above hundreds of MeV. Therefore, further improvement is required. (author)

  15. Integral particle reflection coefficient for oblique incidence of photons as universal function in the domain of initial energies up to 300 keV

    Directory of Open Access Journals (Sweden)

    Ljubenov Vladan L.

    2014-01-01

    Full Text Available In this paper we present the results of calculations and analyses of the integral particle reflection coefficient of photons for oblique photon incidence on planar targets, in the domain of initial photon energies from 100 keV to 300 keV. The results are based on the Monte Carlo simulations of the photon reflection from water, concrete, aluminum, iron, and copper materials, performed by the MCNP code. It has been observed that the integral particle reflection coefficient as a function of the ratio of total cross-section of photons and effective atomic number of target material shows universal behavior for all the analyzed shielding materials in the selected energy domain. Analytical formulas for different angles of photon incidence have been proposed, which describe the reflection of photons for all the materials and energies analyzed.

  16. Energy and the global warming issue in developing countries: analyzing the incidence of the fuel carbon tax and its policy implications

    International Nuclear Information System (INIS)

    Siddayao, C.M.; Percebois, J.R.

    1992-01-01

    By changing the natural environment, energy resource use has repercussions for human welfare. So do policies that are proposed to deal with concerns over global climate warming, particularly with respect to carbon dioxide (CO 2 ). Among the major policy options identified are reduction of emission from fossil fuel consumption, as well as more rigorous forest management to avoid further deforestation. The basic approach to reducing carbon emissions from fossil fuels is through the efficient use of energy. Fuel switching, pollution prevention technologies, and the 'polluter pays' principle are also among the policy strategies often discussed. One of the proposed economic policy instruments in the 'polluter pays' category that could lead to more efficient use of energy and at the same time deal with the CO 2 problem is the carbon tax. This paper will focus on the incidence of the tax in the different sectors of a developing country and suggest the key issues in analyzing this incidence. This introduction will include a brief background discussion on the greenhouse gas (GHG) issue which has led to the proposal for the carbon tax. In section II, the incidence of the carbon tax will be reviewed. In section III, the key analytical issues for analyzing incidence of the tax on a sector-by-sector analysis of a national tax will be raised. In this version of this paper, the intended quantitative analysis is not presented; we hope to have partial results by the time of conference. 31 refs., 1 fig., 3 tabs

  17. Convergent sum of gradient expansion of the kinetic-energy density functional up to the sixth order term using Padé approximant

    Science.gov (United States)

    Sergeev, A.; Alharbi, F. H.; Jovanovic, R.; Kais, S.

    2016-04-01

    The gradient expansion of the kinetic energy density functional, when applied to atoms or finite systems, usually grossly overestimates the energy in the fourth order and generally diverges in the sixth order. We avoid the divergence of the integral by replacing the asymptotic series including the sixth order term in the integrand by a rational function. Padé approximants show moderate improvements in accuracy in comparison with partial sums of the series. The results are discussed for atoms and Hooke’s law model for two-electron atoms.

  18. Fission fragment yields and total kinetic energy release in neutron-induced fission of235,238U,and239Pu

    Science.gov (United States)

    Tovesson, F.; Duke, D.; Geppert-Kleinrath, V.; Manning, B.; Mayorov, D.; Mosby, S.; Schmitt, K.

    2018-03-01

    Different aspects of the nuclear fission process have been studied at Los Alamos Neutron Science Center (LANSCE) using various instruments and experimental techniques. Properties of the fragments emitted in fission have been investigated using Frisch-grid ionization chambers, a Time Projection Chamber (TPC), and the SPIDER instrument which employs the 2v-2E method. These instruments and experimental techniques have been used to determine fission product mass yields, the energy dependent total kinetic energy (TKE) release, and anisotropy in neutron-induced fission of U-235, U-238 and Pu-239.

  19. Thermal Rate Coefficients and Kinetic Isotope Effects for the Reaction OH + CH4 → H2O + CH3 on an ab Initio-Based Potential Energy Surface.

    Science.gov (United States)

    Li, Jun; Guo, Hua

    2018-03-15

    Thermal rate coefficients for the title reaction and its various isotopologues are computed using a tunneling-corrected transition-state theory on a global potential energy surface recently developed by fitting a large number of high-level ab initio points. The calculated rate coefficients are found to agree well with the measured ones in a wide temperature range, validating the accuracy of the potential energy surface. Strong non-Arrhenius effects are found at low temperatures. In addition, the calculations reproduced the primary and secondary kinetic isotope effects. These results confirm the strong influence of tunneling to this heavy-light-heavy hydrogen abstraction reaction.

  20. Energy-range relations for hadrons in nuclear matter

    Science.gov (United States)

    Strugalski, Z.

    1985-01-01

    Range-energy relations for hadrons in nuclear matter exist similarly to the range-energy relations for charged particles in materials. When hadrons of GeV kinetic energies collide with atomic nuclei massive enough, events occur in which incident hadron is stopped completely inside the target nucleus without causing particle production - without pion production in particular. The stoppings are always accompanied by intensive emission of nucleons with kinetic energy from about 20 up to about 400 MeV. It was shown experimentally that the mean number of the emitted nucleons is a measure of the mean path in nuclear matter in nucleons on which the incident hadrons are stopped.

  1. Factorial design for the evaluation of the interaction effect between particle size and heating rate in the kinetic energy of coal combustion

    Energy Technology Data Exchange (ETDEWEB)

    Avila, Ivonete; Silva, Eugenio A.G.; Mortari, Daniela A.; Crnkovic, Paula M.; Milioli, Fernando E. [University of Sao Paulo (EESC/USP), Sao Carlos, SP (Brazil). Engineering School. Group of Thermal and Fluids Engineering], Emails: iavila@sc.usp.br, eugenio.silva@usp.br, paulam@sc.usp.br, milioli@sc.usp.br

    2010-07-01

    This paper evaluates the behavior of kinetic energy for different heating rates ({alpha}) and particle sizes of the material in the study of the coal combustion process. It aims to obtain a response surface in a large range of particle size, using heating rates between the minimum and maximum values allowed by the equipment. Therefore it searches for a model to evaluate the interaction effect between particle size and the heating rate and to predict the activation energy of the process studied. The activation energy of the process was determined using the isoconversional model Model Free Kinetics. In this model, the activation energy (E{sub {alpha}}) is obtained as a function of the reaction extent ({alpha}). The subscript in E{sub {alpha}} designates the values related to a given value of conversion ({alpha}). All experiments were conducted in thermogravimetric balance using samples of a Brazilian coal (EC4500) witch average particle size between 163 to 650 {mu}m and heating rates between 10 and 40 deg C min{sup -1} in dynamic atmosphere of air. A central rotatable composite design was applied for the 2{sup 2} factorial design including 4 tests under the axial conditions and 3 repetitions in the central point. As expected, the results show that both the particle size and the heating rate affected significantly the values of activation energy of the coal combustion process obtained by the model used. (author)

  2. Full charge-density scheme with a kinetic-energy correction: Application to ground-state properties of the 4d metals

    DEFF Research Database (Denmark)

    Vitos, Levente; Kollár, J.; Skriver, Hans Lomholt

    1997-01-01

    We present a full charge-density technique to evaluate total energies from the output of self-consistent linear muffin-tin orbitals (LMTO) calculations in the atomic-sphere approximation (ASA). The Coulomb energy is calculated exactly from the complete, nonspherically symmetric charge density...... defined within nonoverlapping, space-filling Wigner-Seitz cells; the exchange-correlation energy is evaluated by means of the local-density approximation or the generalized gradient approximation applied to the complete charge-density; and the ASA kinetic energy is corrected for the nonspherically...... symmetric charge density by a gradient expansion. The technique retains most of the simplicity and the computational efficiency of the LMTO-ASA method, and calculations of atomic volumes and elastic constants of the 4d elements show that it has the accuracy of full-potential methods....

  3. Plasmas produced by incident laser in solids

    International Nuclear Information System (INIS)

    Oliveira Campos, D. de; Boeckelmann, H.K.

    1984-01-01

    The experimental arrangement for plasma production by incident laser in solids and a system of diagnostics are presented. The system of diagnostics allows: verify the plasma generation and expansion through the ultrahigh-speed photography; obtain measurements of temperature and density by spectroscopy (using an optical analyser of multichannels) and obtain measurements of kinetic energy of ions through his fly time, using a 'Faraday cup'. A vacuum system with an adsorption pump for pre-vacuum and ionic pump was used to reduce pressure and avoid mechanical vibrations and system contaminations. (M.C.K.) [pt

  4. Dependence of the annealing kinetics of A centers and divacancies on temperature, particle energy, and irradiation dose for n-Si crystals

    International Nuclear Information System (INIS)

    Pagava, T.A.

    2002-01-01

    n-Si crystals grown by the float-zone method with a phosphorus concentration of ∼6 x 10 13 cm -3 and irradiated with 2-MeV electrons and 25-MeV protons were studied. It is shown that the kinetics of the isochronous annealing of the A centers and divacancies (the annealing temperature and the rearrangement of radiation defects in the situation where the dissociation of one type of defects gives rise to more stable defects) depends in a complicated way on the energy, dose, and temperature of irradiation; i.e., this kinetics depends on the relation between the concentrations of various radiation defects and on the charge state of reacting primary radiation defects when they interact with each other, with impurity atoms, and with disordered regions. An increase in the concentration of divacancies in the temperature range of 180-210 deg. C is attributed to the dissociation of disordered regions

  5. Depth Resolution Dependence on Sample Thickness and Incident Energy in On-Axis Transmission Kikuchi Diffraction in Scanning Electron Microscope (SEM).

    Science.gov (United States)

    Brodu, Etienne; Bouzy, Emmanuel

    2017-12-01

    Transmission Kikuchi diffraction is an emerging technique aimed at producing orientation maps of the structure of materials with a nanometric lateral resolution. This study investigates experimentally the depth resolution of the on-axis configuration, via a twinned silicon bi-crystal sample specifically designed and fabricated. The measured depth resolution varies from 30 to 65 nm in the range 10-30 keV, with a close to linear dependence with incident energy and no dependence with the total sample thickness. The depth resolution is explained in terms of two mechanisms acting concomitantly: generation of Kikuchi diffraction all along the thickness of the sample, associated with continuous absorption on the way out. A model based on the electron mean free path is used to account for the dependence with incident energy of the depth resolution. In addition, based on the results in silicon, the use of the mean absorption coefficient is proposed to predict the depth resolution for any atomic number and incident energy.

  6. Holographic kinetic k-essence model

    Energy Technology Data Exchange (ETDEWEB)

    Cruz, Norman [Departamento de Fisica, Facultad de Ciencia, Universidad de Santiago de Chile, Casilla 307, Santiago (Chile)], E-mail: ncruz@lauca.usach.cl; Gonzalez-Diaz, Pedro F.; Rozas-Fernandez, Alberto [Colina de los Chopos, Instituto de Fisica Fundamental, Consejo Superior de Investigaciones Cientificas, Serrano 121, 28006 Madrid (Spain)], E-mail: a.rozas@cfmac.csic.es; Sanchez, Guillermo [Departamento de Matematica y Ciencia de la Computacion, Facultad de Ciencia, Universidad de Santiago de Chile, Casilla 307, Santiago (Chile)], E-mail: gsanchez@usach.cl

    2009-08-31

    We consider a connection between the holographic dark energy density and the kinetic k-essence energy density in a flat FRW universe. With the choice c{>=}1, the holographic dark energy can be described by a kinetic k-essence scalar field in a certain way. In this Letter we show this kinetic k-essential description of the holographic dark energy with c{>=}1 and reconstruct the kinetic k-essence function F(X)

  7. MANAGING THE LOAD SCHEDULE OF THE ADMINISTRATIVE BUILDING TAKING INTO ACCOUNT EMERGING RISKS WHEN CONNECTING THE KINETIC ENERGY STORAGE TO THE POWER SUPPLY SYSTEM

    Directory of Open Access Journals (Sweden)

    S. Yu. Shevchenko

    2017-12-01

    Full Text Available Purpose. The purpose of the paper is to analyze load schedules of the administrative building and develop a structural scheme for connecting the kinetic energy storage in the power supply system of this building, which will allow using it as a consumer regulator, as well as a theoretical study of the risks that arise. Methodology. To conduct the research, the theory of designing internal electrical networks of buildings, the theory of plotting electric load graphs, methods of the theory of electromechanical systems and for analyzing the risk system, the T. Saati method of hierarchies were used. Results. The structure of kinetic energy storage (KES connection to the power supply system of the administrative building is developed and the structural diagram of the KES proposed for installation is given, the average daily winter and summer load schedules are presented, a set of groups and subgroups of risks and their influence on the work of the power supply system of the building are connected with the connection of the KES. Originality. For the first time, the application of the kinetic energy storage in the power supply system of the building with the analysis of emerging risks is considered, which makes it possible to improve the reliability of the developed system and the efficiency of load regulation. Practical value. The application of the proposed scheme will make it possible to use administrative buildings as load regulators of the external power supply system, and also effectively manage the load in the internal power supply system of the building.

  8. Sidecut radius and kinetic energy: equipment designed to reduce risk of severe traumatic knee injuries in alpine giant slalom ski racing.

    OpenAIRE

    Kröll, Josef; Spörri, Jörg; Gilgien, Matthias; Schwameder, Hermann; Müller, Erich

    2016-01-01

    This is an Open Access article distributed in accordance with the Creative Commons Attribution Non Commercial (CC BY-NC 4.0) license, which permits others to distribute, remix, adapt, build upon this work non-commercially, and license their derivative works on different terms, provided the original work is properly cited and the use is non-commercial. See: http://creativecommons.org/ licenses/by-nc/4.0/ Background: Kinetic energy (Ekin) increases with speed by the power of 2...

  9. Activation energy and R. Chen frequency factor in the Randall and Wilkins original equation for second order kinetics. Emission curve simulated in Microsoft Excel algebra

    International Nuclear Information System (INIS)

    Moreno M, A.; Moreno B, A.

    2000-01-01

    In this work the incorporation of activation energy and frequency factor parameters proposed by R. Chen are presented in the original formulation of Randall and wilkins second order kinetics. The results concordance are compared between the calculus following the R. Chen methodology with those ones obtained by direct incorporation of the previously indicated in the Randall-Wilkins-Levy expression for a simulated thermoluminescent emission curve of two peaks with maximum peak temperature (tm): t m1=120 and t m2=190. (Author)

  10. Kinetic Typography

    DEFF Research Database (Denmark)

    van Leeuwen, Theo; Djonov, Emilia

    2014-01-01

    After discussing broad cultural drivers behind the development of kinetic typography, the chapter outlines an approach to analysing kinetic typography which is based on Halliday's theory of transitivity, as applied by Kress and Van Leeuwen to visual images....

  11. Kinetic Typography

    DEFF Research Database (Denmark)

    van Leeuwen, Theo; Djonov, Emilia

    2014-01-01

    After discussing broad cultural drivers behind the development of kinetic typography, the chapter outlines an approach to analysing kinetic typography which is based on Halliday's theory of transitivity, as applied by Kress and Van Leeuwen to visual images.......After discussing broad cultural drivers behind the development of kinetic typography, the chapter outlines an approach to analysing kinetic typography which is based on Halliday's theory of transitivity, as applied by Kress and Van Leeuwen to visual images....

  12. Theoretical Kinetics Analysis for Ḣ Atom Addition to 1,3-Butadiene and Related Reactions on the Ċ4H7 Potential Energy Surface.

    Science.gov (United States)

    Li, Yang; Klippenstein, Stephen J; Zhou, Chong-Wen; Curran, Henry J

    2017-10-12

    The oxidation chemistry of the simplest conjugated hydrocarbon, 1,3-butadiene, can provide a first step in understanding the role of polyunsaturated hydrocarbons in combustion and, in particular, an understanding of their contribution toward soot formation. On the basis of our previous work on propene and the butene isomers (1-, 2-, and isobutene), it was found that the reaction kinetics of Ḣ-atom addition to the C═C double bond plays a significant role in fuel consumption kinetics and influences the predictions of high-temperature ignition delay times, product species concentrations, and flame speed measurements. In this study, the rate constants and thermodynamic properties for Ḣ-atom addition to 1,3-butadiene and related reactions on the Ċ 4 H 7 potential energy surface have been calculated using two different series of quantum chemical methods and two different kinetic codes. Excellent agreement is obtained between the two different kinetics codes. The calculated results including zero-point energies, single-point energies, rate constants, barrier heights, and thermochemistry are systematically compared among the two quantum chemical methods. 1-Methylallyl (Ċ 4 H 7 1-3) and 3-buten-1-yl (Ċ 4 H 7 1-4) radicals and C 2 H 4 + Ċ 2 H 3 are found to be the most important channels and reactivity-promoting products, respectively. We calculated that terminal addition is dominant (>80%) compared to internal Ḣ-atom addition at all temperatures in the range 298-2000 K. However, this dominance decreases with increasing temperature. The calculated rate constants for the bimolecular reaction C 4 H 6 + Ḣ → products and C 2 H 4 + Ċ 2 H 3 → products are in excellent agreement with both experimental and theoretical results from the literature. For selected C 4 species, the calculated thermochemical values are also in good agreement with literature data. In addition, the rate constants for H atom abstraction by Ḣ atoms have also been calculated, and it is

  13. Kinetics of coffee industrial residue pyrolysis using distributed activation energy model and components separation of bio-oil by sequencing temperature-raising pyrolysis.

    Science.gov (United States)

    Chen, Nanwei; Ren, Jie; Ye, Ziwei; Xu, Qizhi; Liu, Jingyong; Sun, Shuiyu

    2016-12-01

    This study was carried out to investigate the kinetics of coffee industrial residue (CIR) pyrolysis, the effect of pyrolysis factors on yield of bio-oil component and components separation of bio-oil. The kinetics of CIR pyrolysis was analyzed using distributed activation energy model (DAEM), based on the experiments in thermogravimetric analyzer (TGA), and it indicated that the average of activation energy (E) is 187.86kJ·mol -1 . The bio-oils were prepared from CIR pyrolysis in vacuum tube furnace, and its components were determined by gas chromatography/mass spectrometry (GC-MS). Among pyrolysis factors, pyrolysis temperature is the most influential factor on components yield of bio-oil, directly concerned with the volatilization and yield of components (palmitic acid, linoleic acid, oleic acid, octadecanoic acid and caffeine). Furthermore, a new method (sequencing temperature-raising pyrolysis) was put forward and applied to the components separation of bio-oil. Based on experiments, a solution of components separation of bio-oil was come out. Copyright © 2016 Elsevier Ltd. All rights reserved.

  14. The effects of short work vs. longer work periods within intermittent exercise on V̇o2p kinetics, muscle deoxygenation, and energy system contribution.

    Science.gov (United States)

    McCrudden, Michael C; Keir, Daniel A; Belfry, Glen R

    2017-06-01

    We examined the effects of inserting 3-s recovery periods during high-intensity cycling exercise at 25-s and 10-s intervals on pulmonary oxygen uptake (V̇o 2p ), muscle deoxygenation [deoxyhemoglobin (HHb)], their associated kinetics (τ), and energy system contributions. Eleven men (24 ± 3 yr) completed two trials of three cycling protocols: an 8-min continuous protocol (CONT) and two 8-min intermittent exercise protocols with work-to-rest periods of 25 s to 3 s (25INT) and 10 s to 3 s (10INT). Each protocol began with a step-transition from a 20-W baseline to a power output (PO) of 60% between lactate threshold and maximal V̇o 2p (Δ60). This PO was maintained for 8 min in CONT, whereas 3-s periods of 20-W cycling were inserted every 10 s and 25 s after the transition to Δ60 in 10INT and 25INT, respectively. Breath-by-breath gas exchange measured by mass spectrometry and turbine and vastus lateralis [HHb] measured by near-infrared spectroscopy were recorded throughout. Arterialized-capillary lactate concentration ([Lac - ]) was obtained before and 2 min postexercise. The τV̇o 2p was lowest ( P 0.05) between conditions. Postexercise [Lac - ] was lowest ( P exercise speeded V̇o 2p kinetics and reduced overall V̇o 2p , suggesting an increased reliance on PCr-derived phosphorylation during the work period of INT compared with an identical PO performed continuously. NEW & NOTEWORTHY We report novel observations on the effects of differing heavy-intensity work durations between 3-s recovery periods on pulmonary oxygen uptake (V̇o 2p ) kinetics, muscle deoxygenation, and energy system contributions. Relative to continuous exercise, V̇o 2p kinetics are faster in intermittent exercise, and increased frequency of 3-s recovery periods improves microvascular O 2 delivery and reduces V̇o 2p and arterialized-capillary lactate concentration. The metabolic burden of identical intensity work is altered when performed intermittently vs. continuously. Copyright

  15. Supplementing energy and protein source at different rate of degradability to mixture of corn waste and coffee pod as basal diet on rumen fermentation kinetic of beef cattle

    Directory of Open Access Journals (Sweden)

    Dicky Pamungkas

    2010-03-01

    Full Text Available The use of corn waste and coffee pod as basal diet needs energy and protein supplementation in order to optimize rumen microbial growth. A research was done to study the appropriate supplement which is suitable based on the result of rumen fermentation kinetics. Four ruminally canulated cows, (205-224 kg of live weight were placed in individual cages. The basal diet (BD offered were corn waste and coffee pod mixture (80:20. Source of high degradable energy (HDE was cassava pomace; while the low degradable energy (LDE was arenga piñata waste. The high degradable protein (HDP was mixed-concentrate while the low degradable protein (LDP was leucaena leave meal. The supplementation of energy and protein to basal diet was in ratio of 50:50 based on dry matter. Feed offered were basal diet and the supplement at ratio of 60: 40 (3 % of LW. Observation was carried out for 4 periods (10 days/period. In each period, animal was fed one of the following diets: A = BD, B = BD+ HDE+LDP, C = BD+LDE+LDP, and D = BD+HDE+HDP. Rumen kinetics observed were: pH, and VFA, NH3 and rumen microbial protein concentrations. Rumen fluid was taken at the end of each period gradually along the course of 24 hours fermentation. The results showed that the diets gave significant effect (P < 0.05 on rumen pH. The lowest rumen pH (5.76 was observed on diet D at 2:00, 12 hours after feeding. Meanwhile, the highest pH (7.22 was found in animal fed diet A at 16:00. The total VFA on diet D of periode:1, 3 and 4 showed the highest level: 68.1 mmol/l; 75.37 mmol/l and 85.14 mmol/l respectively. The highest NH3 concentration was found in diet D followed by diet C, B and A. At 12:00 observation or at 4 h after morning feeding the highest NH3 was observed from diet D (41.94 mg/100 ml. It is concluded that diet D resulted in the best rumen fermentation kinetic, therefore it could be used in feed formulation in cattle diets.

  16. Simulation of hadron multiple production by cosmic-ray protons in the incident energy region of 1015 eV

    International Nuclear Information System (INIS)

    Takatsuka, Ichiro

    1984-01-01

    The simulation studies of the unusual cosmic ray families found by the experiment at Mt. Chacaltaya were performed. Those families have a larger number of hadrons than the normal families, or are the families with big transverse extension. The former is called Centauro or Mini-centauro, and the latter is called Binocular and Chiron. In the first simulation, the process was calculated, in which the Lorentz transformation of π-meson multiple production (C-jet) in the energy region of 10 14 eV was made, and the jet with raised energy was combined, and the families were formed. The second simulation was made for the energy region more than 300 TeV, in which the nucleon-antinucleon multiple production with large transverse momentum and the B particle multiple production with larger transverse momentum were assumed. The data used were the C-jet data observed at Mt. Chacaltaya. For the simulation, all the primary particles were considered to be protons. The results of the present simulation study showed that the families with strong hadron components observed at Mt. Chacaltaya might be the new type hadron multiple production such as nucleon-antinucleon multiple production or B-particle multiple production. The total energy of all the families increased with the energy of the primary particles. There are a few families having the same extent of energy and spread as the Chiron. (Kato, T.)

  17. Kinetic parameters, collision rates, energy exchanges and transport coefficients of non-thermal electrons in premixed flames at sub-breakdown electric field strengths

    KAUST Repository

    Bisetti, Fabrizio

    2014-01-02

    The effects of an electric field on the collision rates, energy exchanges and transport properties of electrons in premixed flames are investigated via solutions to the Boltzmann kinetic equation. The case of high electric field strength, which results in high-energy, non-thermal electrons, is analysed in detail at sub-breakdown conditions. The rates of inelastic collisions and the energy exchange between electrons and neutrals in the reaction zone of the flame are characterised quantitatively. The analysis includes attachment, ionisation, impact dissociation, and vibrational and electronic excitation processes. Our results suggest that Townsend breakdown occurs for E/N = 140 Td. Vibrational excitation is the dominant process up to breakdown, despite important rates of electronic excitation of CO, CO2 and N2 as well as impact dissociation of O2 being apparent from 50 Td onwards. Ohmic heating in the reaction zone is found to be negligible (less than 2% of peak heat release rate) up to breakdown field strengths for realistic electron densities equal to 1010 cm-3. The observed trends are largely independent of equivalence ratio. In the non-thermal regime, electron transport coefficients are insensitive to mixture composition and approximately constant across the flame, but are highly dependent on the electric field strength. In the thermal limit, kinetic parameters and transport coefficients vary substantially across the flame due to the spatially inhomogeneous concentration of water vapour. A practical approach for identifying the plasma regime (thermal versus non-thermal) in studies of electric field effects on flames is proposed. © 2014 Taylor & Francis.

  18. Distance-Independent Charge Recombination Kinetics in Cytochrome c - Cytochrome c Peroxidase Complexes: Compensating Changes in the Electronic Coupling and Reorganization Energies

    Science.gov (United States)

    Jiang, Nan; Kuznetsov, Aleksey; Nocek, Judith M.; Hoffman, Brian M.; Crane, Brian R.; Hu, Xiangqian; Beratan, David N.

    2013-01-01

    Charge recombination rate constants vary no more than three-fold for inter-protein ET in the Zn-substituted wild type (WT) cytochrome c peroxidase (CcP):cytochrome c (Cc) complex and in complexes with four mutants of the Cc protein (i.e., F82S, F82W, F82Y and F82I), despite large differences in the ET distance. Theoretical analysis indicates that charge recombination for all complexes involves a combination of tunneling and hopping via Trp191. For three of the five structures (WT and F82S(W)), the protein favors hopping more than that in the other two structures that have longer heme→ZnP distances (F82Y(I)). Experimentally observed biexponential ET kinetics is explained by the complex locking in alternative coupling pathways, where the acceptor hole state is either primarily localized on ZnP (slow phase) or on Trp191 (fast phase). The large conformational differences between the CcP:Cc interface for the F82Y(I) mutants compared to the WT and F82S(W) complexes are predicted to change the reorganization energies for the CcP:Cc ET reactions because of changes in solvent exposure and inter-protein ET distances. Since the recombination reaction is likely to occur in the inverted Marcus regime, an increased reorganization energy compensates the decreased role for hopping recombination (and the longer transfer distance) in the F82Y(I) mutants. Taken together, coupling pathway and reorganization energy effects for the five protein complexes explains the observed insensitivity of recombination kinetics to donor-acceptor distance and docking pose and also reveals how hopping through aromatic residues can accelerate long-range ET. PMID:23895339

  19. Kinetic sculpture

    OpenAIRE

    Joneta Witabora; Jonata Witabora

    2014-01-01

    Kinetic Sculpture was born from a long process of searching new approach in sculpture. The artists tried to escape from 'static' paradigm and tried to implement movement into their works: a sculpture that is mobile. Movement is always a fascinating phenomenon to eyes. Kinetic sculpture strength lies in its unique character in combining science and art. Kinetic Sculptures are really interesting pieces of art. It succeeds to fascinate human everytime. 

  20. A Kinetic-MHD Theory for the Self-Consistent Energy Exchange Between Energetic Particles and Active Small-scale Flux Ropes

    Science.gov (United States)

    le Roux, J. A.

    2017-12-01

    We developed previously a focused transport kinetic theory formalism with Fokker-plank coefficients (and its Parker transport limit) to model large-scale energetic particle transport and acceleration in solar wind regions with multiple contracting and merging small-scale flux ropes on MHD (inertial) scales (Zank et al. 2014; le Roux et al. 2015). The theory unifies the main acceleration mechanisms identified in particle simulations for particles temporarily trapped in such active flux rope structures, such as acceleration by the parallel electric field in reconnection regions between merging flux ropes, curvature drift acceleration in incompressible/compressible contracting and merging flux ropes, and betatron acceleration (e.g., Dahlin et al 2016). Initial analytical solutions of the Parker transport equation in the test particle limit showed that the energetic particle pressure from efficient flux-rope energization can potentially be high in turbulent solar wind regions containing active flux-rope structures. This requires taking into account the back reaction of energetic particles on flux ropes to more accurately determine the efficiency of energetic particles acceleration by small-scale flux ropes. To accomplish this goal we developed recently an extension of the kinetic theory to a kinetic-MHD level. We will present the extended theory showing the focused transport equation to be coupled to a solar wind MHD transport equation for small-scale flux-rope energy density extracted from a recently published nearly incompressible theory for solar wind MHD turbulence with a plasma beta of 1 (Zank et al. 2017). In the flux-rope transport equation appears new expressions for the damping/growth rates of flux-rope energy derived from assuming energy conservation in the interaction between energetic particles and small-scale flux ropes for all the main flux-rope acceleration mechanisms, whereas previous expressions for average particle acceleration rates have been

  1. Multicenter prospective cohort study of the incidence of adverse events associated with cosmetic dermatologic procedures: lasers, energy devices, and injectable neurotoxins and fillers.

    Science.gov (United States)

    Alam, Murad; Kakar, Rohit; Nodzenski, Michael; Ibrahim, Omer; Disphanurat, Wareeporn; Bolotin, Diana; Borovicka, Judy H; Pace, Natalie; Alster, Tina S; Arndt, Kenneth A; Beer, Kenneth R; Berlin, Joshua M; Bernstein, Leonard J; Brightman, Lori A; Butterwick, Kimberly; Cox, Sue Ellen; Chotzen, Vera; Fabi, Sabrina G; Fitzpatrick, Richard E; Geronemus, Roy G; Goldman, Mitchel P; Groff, William F; Kaminer, Michael S; Kilmer, Suzanne; Rohrer, Thomas E; Tanzi, Elizabeth L; Silva, Susan K; Yoo, Simon S; Weinkle, Susan H; Strasswimmer, John; Poon, Emily; Dover, Jeffrey S

    2015-03-01

    Common noninvasive to minimally invasive cosmetic dermatologic procedures are widely believed to be safe given the low incidence of reported adverse events, but reliable incidence data regarding adverse event rates are unavailable to date. To assess the incidence of adverse events associated with noninvasive to minimally invasive cosmetic dermatologic procedures, including those involving laser and energy devices, as well as injectable neurotoxins and fillers. A multicenter prospective cohort study (March 28, 2011, to December 30, 2011) of procedures performed using laser and energy devices, as well as injectable neurotoxins and soft-tissue augmentation materials, among 8 geographically dispersed US private and institutional dermatology outpatient clinical practices focused on cosmetic dermatology, with a total of 23 dermatologists. Participants represented a consecutive sample of 20 399 cosmetic procedures. Data acquisition was for 3 months (13 weeks) per center, with staggered start dates to account for seasonal variation. Web-based data collection daily at each center to record relevant procedures, by category type and subtype. Adverse events were detected by (1) initial observation by participating physicians or staff; (2) active ascertainment from patients, who were encouraged to self-report after their procedure; and (3) follow-up postprocedural phone calls to patients by staff, if appropriate. When adverse events were not observed by physicians but were suspected, follow-up visits were scheduled within 24 hours to characterize these events. Detailed information regarding each adverse event was entered into an online form. The main outcome was the total incidence of procedure-related adverse events (total adverse events divided by total procedures performed), as verified by clinical examination. Forty-eight adverse events were reported, for a rate of 0.24% (95% CI, 0.18%-0.31%). Overall, 36 procedures resulted in at least 1 adverse event, for a rate of 0

  2. Polarized proton induced pion production on 10B at 200, 225, 250 and 260 MeV incident energies

    International Nuclear Information System (INIS)

    Ziegler, W.; Auld, E.G.; Falk, W.R.; Giles, G.L.; Jones, G.; Lolos, G.J.; McParland, B.

    1985-02-01

    The angular distributions of both the differential cross-section and the analyzing power are presented for the 10 B(p,π) 11 B reaction leading to the ground and first excited states of 11 B. The differential cross-section shows very little angular structure or energy dependence, but the analyzing power exhibits a considerable energy dependence for both states. This dependence, similar to that observed for the 12 C(p,π + ) 13 C reaction, may be a signature of the fact that single-particle final states are involved

  3. Single-molecule fluorescence resonance energy transfer shows uniformity in TATA binding protein-induced DNA bending and heterogeneity in bending kinetics.

    Science.gov (United States)

    Blair, Rebecca H; Goodrich, James A; Kugel, Jennifer F

    2012-09-25

    TATA binding protein (TBP) is a key component of the eukaryotic RNA polymerase II transcription machinery that binds to TATA boxes located in the core promoter regions of many genes. Structural and biochemical studies have shown that when TBP binds DNA, it sharply bends the DNA. We used single-molecule fluorescence resonance energy transfer (smFRET) to study DNA bending by human TBP on consensus and mutant TATA boxes in the absence and presence of TFIIA. We found that the state of the bent DNA within populations of TBP-DNA complexes is homogeneous; partially bent intermediates were not observed. In contrast to the results of previous ensemble studies, TBP was found to bend a mutant TATA box to the same extent as the consensus TATA box. Moreover, in the presence of TFIIA, the extent of DNA bending was not significantly changed, although TFIIA did increase the fraction of DNA molecules bound by TBP. Analysis of the kinetics of DNA bending and unbending revealed that on the consensus TATA box two kinetically distinct populations of TBP-DNA complexes exist; however, the bent state of the DNA is the same in the two populations. Our smFRET studies reveal that human TBP bends DNA in a largely uniform manner under a variety of different conditions, which was unexpected given previous ensemble biochemical studies. Our new observations led to us to revise the model for the mechanism of DNA binding by TBP and for how DNA bending is affected by TATA sequence and TFIIA.

  4. Transport Theory for Kinetic Emission of Secondary Electrons from Solids

    DEFF Research Database (Denmark)

    Schou, Jørgen

    1980-01-01

    Kinetic secondary electron emission from a solid target resulting from incidence of keV electrons or keV and MeV ions is treated theoretically on the basis of ionization cascade theory. The energy and angular distribution and the yield of secondary electrons are calculated for a random target...... a spectrum which shows good agreement with experimental data. The electron- and proton-induced yields from aluminum are evaluated on the basis of existing low-energy-electron stopping-power data. The agreement with existing experimental data is good. Also, experimental yields from electrons, protons...

  5. Influence of Polarization of the Incident Beam on Integrated Intensities in X-Ray Energy-Dispersive Diffractometry

    DEFF Research Database (Denmark)

    Olsen, J. Staun; Buras, B.; Jensen, T.

    1978-01-01

    Polarization measurements of the primary X-ray beam produced by thick copper and tungsten anodes are reported and formulas derived for integrated intensities of Bragg reflections in energy-dispersive diffractometry with the polarization of the primary beam taken into account. It was found...

  6. Azimuthal angular distributions of K+ and K- mesons from Au+Au collisions at a kinetic beam energy of 1.5 AGeV

    International Nuclear Information System (INIS)

    Ploskon, M.

    2005-01-01

    The Kaon-Spectrometer (KaoS) at the heavy-ion synchrotron (SIS) at the Gesellschaft fuer Schwerionenforschung (GSI) in Darmstadt has been used to study production and propagation of K + and K - mesons from Au+Au collisions at a kinetic beam energy of 1.5 AGeV. The azimuthal angular distributions of particles as a function of the collision centrality and particle transverse momenta have been measured. We found a dependence of the K - meson azimuthal emission pattern on the transverse momentum. The antikaons registered with p t t > 0.5 GeV/c show strong out-of-plane enhancement. The emission patterns of K - can be explained in terms of two competing phenomena: one of them is indeed the influence of the attractive K - N potential, however, the second one originates from the strangeness-exchange process. (orig.)

  7. A Surface-Layer Study of the Transport and Dissipation of Turbulent Kinetic Energy and the Variances of Temperature, Humidity and CO_2

    Science.gov (United States)

    Hackerott, João A.; Bakhoday Paskyabi, Mostafa; Reuder, Joachim; de Oliveira, Amauri P.; Kral, Stephan T.; Marques Filho, Edson P.; Mesquita, Michel dos Santos; de Camargo, Ricardo

    2017-11-01

    We discuss scalar similarities and dissimilarities based on analysis of the dissipation terms in the variance budget equations, considering the turbulent kinetic energy and the variances of temperature, specific humidity and specific CO_2 content. For this purpose, 124 high-frequency sampled segments are selected from the Boundary Layer Late Afternoon and Sunset Turbulence experiment. The consequences of dissipation similarity in the variance transport are also discussed and quantified. The results show that, for the convective atmospheric surface layer, the non-dimensional dissipation terms can be expressed in the framework of Monin-Obukhov similarity theory and are independent of whether the variable is temperature or moisture. The scalar similarity in the dissipation term implies that the characteristic scales of the atmospheric surface layer can be estimated from the respective rate of variance dissipation, the characteristic scale of temperature, and the dissipation rate of temperature variance.

  8. A low-energy intensive electrochemical system for the eradication of Escherichia coli from ballast water: Process development, disinfection chemistry, and kinetics modeling

    International Nuclear Information System (INIS)

    Nadeeshani Nanayakkara, K.G.; Khorshed Alam, A.K.M.; Zheng Yuming; Paul Chen, J.

    2012-01-01

    The invasion of biological organisms via ballast water has created threats to the environment and human health. In this study, a cost-effective electrochemical disinfection reactor was developed to inactivate Escherichia coli, one of the IMO-regulated indicator microbes, in simulated ballast water. The complete inactivation of E. coli could be achieved within a very short time (150, 120, or 60 s) with an energy consumption as low as 0.0090, 0.0074 or 0.0035 kWh/m 3 for ballast water containing E. coli at concentrations of 10 8 , 10 7 and 10 6 CFU/100 mL, respectively. Electrochemical chlorination was the major disinfection mechanism in chloride-abundant electrolytes, whereas oxidants such as ozone and free radicals contributed to 20% of the disinfection efficiency in chloride-free electrolytes. Moreover, a disinfection kinetics model was successfully developed to describe the inactivation of E. coli.

  9. The Fisher-information-based uncertainty relation, Cramer-Rao inequality and kinetic energy for the D-dimensional central problem

    Energy Technology Data Exchange (ETDEWEB)

    Dehesa, J S [Departamento de Fisica Atomica, Molecular y Nuclear, Universidad de Granada, 18071-Granada (Spain); Gonzalez-Ferez, R [Departamento de Fisica Atomica, Molecular y Nuclear, Universidad de Granada, 18071-Granada (Spain); Sanchez-Moreno, P [Departamento de Fisica Atomica, Molecular y Nuclear, Universidad de Granada, 18071-Granada (Spain)

    2007-02-23

    The inequality >= (l+1/2){sup 2}, with L being the grand orbital quantum number, and its conjugate relation for ((r{sup 2}) (p{sup -2})) are shown to be fulfilled in the D-dimensional central problem. Their use has allowed us to improve the Fisher-information-based uncertainty relation (I{sub {rho}}I{sub {gamma}}{>=} const) and the Cramer-Rao inequalities ((r{sup 2})I{sub {rho}} {>=} D{sup 2}; (p{sup 2})I{sub {gamma}} {>=} D{sup 2}). In addition, the kinetic energy and the radial expectation value (r{sup 2}) are shown to be bounded from below by the Fisher information in position and momentum spaces, denoted by I{sub {rho}} and I{sub {gamma}}, respectively.

  10. Study of Pair and many-body interactions in rare-gas halide atom clusters using negative ion zero electron kinetic energy (ZEKE) and threshold photodetachment spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Yourshaw, Ivan [Univ. of California, Berkeley, CA (United States)

    1998-07-09

    The diatomic halogen atom-rare gas diatomic complexes KrBr-, XeBr-, and KrCl- are studied in this work by zero electron kinetic energy (ZEKE) spectroscopy in order to characterize the weak intermolecular diatomic potentials of these species. Also, the ZEKE and threshold photodetachment spectra of the polyatomic clusters ArnBr- (n = 2-9) and ArnI- (n = 2-19) are studied to obtain information about the non-additive effects on the interactions among the atoms. This work is part of an ongoing effort to characterize the pair and many-body potentials of the complete series of rare gas halide clusters. In these studies we obtain information about both the anionic and neutral clusters.

  11. IMFIT Integrated Modeling Applications Supporting Experimental Analysis: Multiple Time-Slice Kinetic EFIT Reconstructions, MHD Stability Limits, and Energy and Momentum Flux Analyses

    Science.gov (United States)

    Collier, A.; Lao, L. L.; Abla, G.; Chu, M. S.; Prater, R.; Smith, S. P.; St. John, H. E.; Guo, W.; Li, G.; Pan, C.; Ren, Q.; Park, J. M.; Bisai, N.; Srinivasan, R.; Sun, A. P.; Liu, Y.; Worrall, M.

    2010-11-01

    This presentation summarizes several useful applications provided by the IMFIT integrated modeling framework to support DIII-D and EAST research. IMFIT is based on Python and utilizes modular task-flow architecture with a central manager and extensive GUI support to coordinate tasks among component modules. The kinetic-EFIT application allows multiple time-slice reconstructions by fetching pressure profile data directly from MDS+ or from ONETWO or PTRANSP. The stability application analyzes a given reference equilibrium for stability limits by performing parameter perturbation studies with MHD codes such as DCON, GATO, ELITE, or PEST3. The transport task includes construction of experimental energy and momentum fluxes from profile analysis and comparison against theoretical models such as MMM95, GLF23, or TGLF.

  12. Kinetic approach

    Indian Academy of Sciences (India)

    Collapse of a Bose gas: Kinetic approach ... Thermodynamical, statistical and static properties of condensates; Ultracold and trapped gases; matter waves. ... of a harmonically trapped attractively interacting Bose gas below the condensation point by introducing a kinetic approach within the Hartee-Fock approximation.

  13. Analysis of Flow Cytometry DNA Damage Response Protein Activation Kinetics Following X-rays and High Energy Iron Nuclei Exposure

    Energy Technology Data Exchange (ETDEWEB)

    Universities Space Research Association; Chappell, Lori J.; Whalen, Mary K.; Gurai, Sheena; Ponomarev, Artem; Cucinotta, Francis A.; Pluth, Janice M.

    2010-12-15

    We developed a mathematical method to analyze flow cytometry data to describe the kinetics of {gamma}H2AX and pATF2 phosphorylations ensuing various qualities of low dose radiation in normal human fibroblast cells. Previously reported flow cytometry kinetic results for these DSB repair phospho-proteins revealed that distributions of intensity were highly skewed, severely limiting the detection of differences in the very low dose range. Distributional analysis reveals significant differences between control and low dose samples when distributions are compared using the Kolmogorov-Smirnov test. Radiation quality differences are found in the distribution shapes and when a nonlinear model is used to relate dose and time to the decay of the mean ratio of phosphoprotein intensities of irradiated samples to controls. We analyzed cell cycle phase and radiation quality dependent characteristic repair times and residual phospho-protein levels with these methods. Characteristic repair times for {gamma}H2AX were higher following Fe nuclei as compared to X-rays in G1 cells (4.5 {+-} 0.46 h vs 3.26 {+-} 0.76 h, respectively), and in S/G2 cells (5.51 {+-} 2.94 h vs 2.87 {+-} 0.45 h, respectively). The RBE in G1 cells for Fe nuclei relative to X-rays for {gamma}H2AX was 2.05 {+-} 0.61 and 5.02 {+-} 3.47, at 2 h and 24-h postirradiation, respectively. For pATF2, a saturation effect is observed with reduced expression at high doses, especially for Fe nuclei, with much slower characteristic repair times (>7 h) compared to X-rays. RBEs for pATF2 were 0.66 {+-} 0.13 and 1.66 {+-} 0.46 at 2 h and 24 h, respectively. Significant differences in {gamma}H2AX and pATF2 levels comparing irradiated samples to control were noted even at the lowest dose analyzed (0.05 Gy) using these methods of analysis. These results reveal that mathematical models can be applied to flow cytometry data to uncover important and subtle differences following exposure to various qualities of low dose radiation.

  14. Heparin kinetics

    International Nuclear Information System (INIS)

    Swart, C.A.M. de.

    1983-01-01

    The author has studied the kinetics of heparin and heparin fractions after intravenous administration in humans and in this thesis the results of this study are reported. Basic knowledge about the physico-chemical properties of heparin and its interactions with proteins resulting in anticoagulant and lipolytic effects are discussed in a review (chapter II), which also comprises some clinical aspects of heparin therapy. In chapter III the kinetics of the anticoagulant effect are described after intravenous administration of five commercial heparin preparations. A mathematical model is presented that fits best to these kinetics. The kinetics of the anticoagulant and lipolytic effects after intravenous injection of various 35 S-radiolabelled heparin fractions and their relationship with the disappearance of the radiolabel are described in chapter IV. Chapter V gives a description of the kinetics of two radiolabels after injection of in vitro formed complexes consisting of purified, 125 I-radiolabelled antithrombin III and various 35 S-radiolabelled heparin fractions. (Auth.)

  15. Thermodynamical properties and deexcitation of sources involved in collisions between light nuclei around 100 AMeV incident energy

    International Nuclear Information System (INIS)

    Borderie, B.; Gulminelli, F.; Rivet, M.F.; Dore, D.; Tassan-Got, L.; Bacri, Ch.O.; Ouatizerga, A.; Plagnol, E.; Squalli, M.; Chbihi, A.; Auger, G.; Benlliure, J.; Ecomard, P.; Le Fevre, A.; Marie, N.; Rosato, E.; Saint-Laurent, F.; Wieleczko, J.P.; Durand, D.; Bougault, R.; Brou, R.; Colin, J.; Cussol, D.; Laforest, R.; Lecolley, J.F.; Lefort, T.; Lopez, O.; Louvel, M.; Metivier, V.; Peter, J.; Steckmeyer, J.C.; Tamain, B.; Vient, E.; Parlog, M.; Bisquer, E.; Demeyer, A.; Guinet, D.; Lautesse, P.; Lebreton, L.; Charvet, J.L.; Dayras, R.; De Filippo, E.; Legrain, R.; Nalpas, L.; Volant, C.; Eudes, Ph.; Gourio, D.; Laville, J.L.; Rahmani, A.; Reposeur, T.

    1997-01-01

    Vaporization events, where all species have atomic numbers lower than 3, and deexcitation properties of quasi-projectiles involved in binary dissipative collisions between 36 Ar and 58 Ni are studied with the multidetector INDRA. Kinematical properties and chemical composition (mean values and variances) of vaporizing sources are derived over the excitation energy per nucleon range 8-28 MeV. These data are found in good agreement with the results of a model describing a gas of fermions and bosons in thermal and chemical equilibrium, which strongly suggests that thermodynamical equilibrium has been reached even for such sources produced in very extreme conditions of collisions. Finally, removing the constraint on atomic numbers lower than 3, the evolution of the chemical composition of quasi-projectiles is presented over the excitation energy range 0-25 AMeV. (authors)

  16. The secondary neutrons spectra of 235U, 238U for incident energy range 1-2.5 MeV

    International Nuclear Information System (INIS)

    Kornilov, N.V.; Kagalenko, A.B.; Balitsky, A.V.; Baryba, V.Ja.; Androsenko, P.A.; Androsenko, A.A.

    1993-01-01

    Spectra of inelastic scattered neutrons and fission neutrons were measured with neutron time of flight spectrometer. The solid tritium target was used as a neutron source. The energy distribution of neutrons on the sample was calculated with Monte-Carlo code, taking into account interaction income protons inside target and reaction kinematics. The detector efficiency was determined with 252 Cf source. The multiple scattering and absorption corrections were calculated with codes packet BRAND. Our results confirm ENDF/B-6 data library. (author)

  17. Turbulent Kinetic Energy Measurement Using Phase Contrast MRI for Estimating the Post-Stenotic Pressure Drop: In Vitro Validation and Clinical Application.

    Directory of Open Access Journals (Sweden)

    Hojin Ha

    Full Text Available Although the measurement of turbulence kinetic energy (TKE by using magnetic resonance imaging (MRI has been introduced as an alternative index for quantifying energy loss through the cardiac valve, experimental verification and clinical application of this parameter are still required.The goal of this study is to verify MRI measurements of TKE by using a phantom stenosis with particle image velocimetry (PIV as the reference standard. In addition, the feasibility of measuring TKE with MRI is explored.MRI measurements of TKE through a phantom stenosis was performed by using clinical 3T MRI scanner. The MRI measurements were verified experimentally by using PIV as the reference standard. In vivo application of MRI-driven TKE was explored in seven patients with aortic valve disease and one healthy volunteer. Transvalvular gradients measured by MRI and echocardiography were compared.MRI and PIV measurements of TKE are consistent for turbulent flow (0.666 400. The turbulence pressure drop correlates strongly with total TKE (R2 = 0.986. However, in vivo measurements of TKE are not consistent with the transvalvular pressure gradient estimated by echocardiography.These results suggest that TKE measurement via MRI may provide a potential benefit as an energy-loss index to characterize blood flow through the aortic valve. However, further clinical studies are necessary to reach definitive conclusions regarding this technique.

  18. Performance of electrochemical oxidation and photocatalysis in terms of kinetics and energy consumption. New insights into the p-cresol degradation.

    Science.gov (United States)

    Escudero, Carlos J; Iglesias, Olalla; Dominguez, Sara; Rivero, Maria J; Ortiz, Inmaculada

    2017-06-15

    This work reports the comparative performance of two Advanced Oxidation Processes (AOPs), electrochemical oxidation and photocatalysis, as individual technological alternatives for the treatment of effluents containing p-cresol. First, the influence of operating parameters in the oxidation and mineralization yield was carried out together with kinetic analysis. Boron Doped Diamond (BDD), RuO 2 and Pt as anodic materials, Na 2 SO 4 and NaCl as supporting electrolytes and different current densities were evaluated in electrochemical oxidation whereas the effect of TiO 2 concentration and radiation was studied in the photocatalytic degradation. Then, the parameter Electrical Energy per Order (E EO ) was calculated to compare the energy consumption in both AOPs, concluding that under the studied conditions the electrochemical treatment with BDD, Na 2 SO 4 and 125 A m -2 showed the best energy efficiency, with an E EO of 5.83 kW h m -3 order -1 for p-cresol and 58.05 kW h m -3 order -1 for DOC removal, respectively. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Comparison of electron-ion energy transfer in dense plasmas obtained from numerical simulations and quantum kinetic theory

    Science.gov (United States)

    Vorberger, J.; Gericke, D. O.

    2014-03-01

    We evaluate various analytical models for the electron-ion energy transfer and compare the results to data from molecular dynamics (MD) simulations. The models tested include energy transfer via strong binary collisions, Landau-Spitzer rates with different choices for the cut-off parameters in the Coulomb logarithm, rates based on Fermi's golden rule (FGR) and theories taking coupled collective modes (CM) into account. In search of a model easy to apply, we first analyze different approximations of the FGR energy transfer rate. Then, we investigate several numerical studies using MD simulations and try to uncover CM effects in the data obtained. Most MD data published so far, except one study by Murillo et al. [23], show no distinct CM effects and, thus, can be interpreted within a FGR or binary collision approach. We show that this finding is related to the parameter regime, in particular the initial temperature difference, considered in these investigations.

  20. Rupturing the hemi-fission intermediate in membrane fission under tension: Reaction coordinates, kinetic pathways, and free-energy barriers

    Science.gov (United States)

    Zhang, Guojie; Müller, Marcus

    2017-08-01

    Membrane fission is a fundamental process in cells, involved inter alia in endocytosis, intracellular trafficking, and virus infection. Its underlying molecular mechanism, however, is only incompletely understood. Recently, experiments and computer simulation studies have revealed that dynamin-mediated membrane fission is a two-step process that proceeds via a metastable hemi-fission intermediate (or wormlike micelle) formed by dynamin's constriction. Importantly, this hemi-fission intermediate is remarkably metastable, i.e., its subsequent rupture that completes the fission process does not occur spontaneously but requires additional, external effects, e.g., dynamin's (unknown) conformational changes or membrane tension. Using simulations of a coarse-grained, implicit-solvent model of lipid membranes, we investigate the molecular mechanism of rupturing the hemi-fission intermediate, such as its pathway, the concomitant transition states, and barriers, as well as the role of membrane tension. The membrane tension is controlled by the chemical potential of the lipids, and the free-energy landscape as a function of two reaction coordinates is obtained by grand canonical Wang-Landau sampling. Our results show that, in the course of rupturing, the hemi-fission intermediate undergoes a "thinning → local pinching → rupture/fission" pathway, with a bottle-neck-shaped cylindrical micelle as a transition state. Although an increase of membrane tension facilitates the fission process by reducing the corresponding free-energy barrier, for biologically relevant tensions, the free-energy barriers still significantly exceed the thermal energy scale kBT.

  1. Electrochemically enhanced reduction of hexavalent chromium in contaminated clay: Kinetics, energy consumption, and application of pulse current

    DEFF Research Database (Denmark)

    Sun, Tian Ran; Pamukcu, Sibel; Ottosen, Lisbeth M.

    2015-01-01

    Electrochemically enhanced reduction of Cr(VI) in clay medium is a technique based on inputting extra energy into the clay to drive the favorable redox reaction. In this study, the reducing reagent Fe(II) was transported into Cr(VI) spiked kaolinite clay by direct current to investigate...

  2. A Unified Kinetics and Equilibrium Experiment: Rate Law, Activation Energy, and Equilibrium Constant for the Dissociation of Ferroin

    Science.gov (United States)

    Sattar, Simeen

    2011-01-01

    Tris(1,10-phenanthroline)iron(II) is the basis of a suite of four experiments spanning 5 weeks. Students determine the rate law, activation energy, and equilibrium constant for the dissociation of the complex ion in acid solution and base dissociation constant for phenanthroline. The focus on one chemical system simplifies a daunting set of…

  3. 10B and 6Li nuclear data measurements for incident neutron energies up to 3 MeV

    OpenAIRE

    BEVILACQUA RICCARDO; HAMBSCH Franz-Josef; BENCARDINO RAFFAELE; GIORGINIS GEORGIOS; VIDALI Marzio; LAMIA L.; RUSKOV I.

    2012-01-01

    We present experimental methods for the measurement of the 10B(n,α)7Li and the 6Li(n,t)4He reactions for neutron energies up to 3 MeV, and preliminary data for the 10B(n,α0)/10B(n,α1γ) branching ratios. The experimental facilities were installed at GELINA and the Van de Graaff generator of the Institute for Reference Materials and Measurement of the European Commission. Our results show the need to investigate the MeV region for these reactions, since the ENDF/B-VII.1 evaluation agrees with o...

  4. Characterisation and dissolution of depleted uranium aerosols produced during impacts of kinetic energy penetrators against a tank

    International Nuclear Information System (INIS)

    Chazel, V.; Gerasimo, P.; Debouis, V.; Laroche, P.; Paquet, F.

    2003-01-01

    Aerosols produced during impacts of depleted uranium (DU) penetrators against the glacis (sloping armour) and the turret of a tank were sampled. The concentration and size distribution were determined. Activity median aerodynamic diameters were 1 μm (geometric standard deviation, s g = 3.7) and 2 μm (s g = 2.5), respectively, for glacis and turret. The mean air concentration was 120 Bq m -3 , i.e. 8.5 mg m -3 of DU. Filters analysed by scanning electron microscopy (SEM) and X ray diffraction showed two types of particles (fine particles and large molten particles) composed mainly of a mixture of uranium and aluminium. The uranium oxides were mostly U 3 O 8 , UO 2.25 and probably UO 3.01 and a mixed compound of U and Al. The kinetics of dissolution in three media (HCO 3 - , HCl and Gamble's solution) were determined using in-vitro tests. The slow dissolution rates were respectively slow, and intermediate between slow and moderate, and the rapid dissolution fractions were mostly intermediate between moderate and fast. According to the in-vitro results for Gamble's solution, and based on a hypothetical single acute inhalation of 90 Bq, effective doses integrated up to 1 y after incorporation were 0.54 and 0.56 mSv respectively, for aerosols from glacis and turret. In comparison, the ICRP limits are 20 mSv y -1 for workers and 1 mSv y -1 for members of public. A kidney concentration of approximately 0.1 μg U g -1 was predicted and should not, in this case, lead to kidney damage. (author)

  5. Wheelchair incidents

    NARCIS (Netherlands)

    Drongelen AW van; Roszek B; Hilbers-Modderman ESM; Kallewaard M; Wassenaar C; LGM

    2002-01-01

    This RIVM study was performed to gain insight into wheelchair-related incidents with powered and manual wheelchairs reported to the USA FDA, the British MDA and the Dutch Center for Quality and Usability Research of Technical Aids (KBOH). The data in the databases do not indicate that incidents with

  6. Free-Free Transitions of e-H System Inside a Dense Plasma Irradiated by a Laser Field at Very Low Incident Electron Energies

    Science.gov (United States)

    Bhatia, A. K.; Sinha, C.

    2012-01-01

    The free-free transition is studied for an electron-hydrogen in the ground state at low incident energies in the presence of an external homogenous, monochromatic, and linearly polarized laser-field inside a hot dense plasma.The effect of plasma screening is considered in the Debye-Huckel approximation. The calculations are performed in the soft photon limit, assuming that the plasma frequency is much higher than the laser frequency. The incident electron is considered to be dressed by the laser field in a nonperturbative manner by choosing the Volkov solutions in both the initial and final channels. The space part of the scattering wave function for the electron is solved numerically by taking into account the electron exchange. The laser-assisted differential and total cross sections are calculated for single-photon absorption /emission and no photon exchange in the soft photon limit, the laser intensity being much less than the atomic field intensity. The calculations have been carried out for various values of Debye parameter, ranging from 0.005 to 0.12. A strong suppression is noted in the laser-assisted cross sections as compared to the field-free situation. A significant difference is noted for the singlet and triplet cross sections. The suppression is much more in the triplet states.

  7. 10B and 6Li Nuclear Data Measurements for Incident Neutron Energies up to 3 MeV

    Science.gov (United States)

    Bevilacqua, R.; Hambsch, F.-J.; Bencardino, R.; Giorginis, G.; Vidali, M.; Lamia, L.; Ruskov, I.

    2014-05-01

    We present experimental methods for the measurement of the 10B(n,α)7Li and the 6Li(n,t)4He reactions for neutron energies up to 3 MeV, and preliminary data for the 10B(n,α0)/10B(n,α1γ) branching ratios. The experimental facilities were installed at GELINA and the Van de Graaff generator of the Institute for Reference Materials and Measurement of the European Commission. Our results show the need to investigate the MeV region for these reactions, since the ENDF/B-VII.1 evaluation agrees with our data up to 1.3 MeV and overestimates above this limit.

  8. Simultaneous spectral and temporal analyses of kinetic energies in nonequilibrium systems: theory and application to vibrational relaxation of O-D stretch mode of HOD in water.

    Science.gov (United States)

    Jeon, Jonggu; Lim, Joon Hyung; Kim, Seongheun; Kim, Heejae; Cho, Minhaeng

    2015-05-28

    A time series of kinetic energies (KE) from classical molecular dynamics (MD) simulation contains fundamental information on system dynamics. It can also be analyzed in the frequency domain through Fourier transformation (FT) of velocity correlation functions, providing energy content of different spectral regions. By limiting the FT time span, we have previously shown that spectral resolution of KE evolution is possible in the nonequilibrium situations [Jeon and Cho, J. Chem. Phys. 2011, 135, 214504]. In this paper, we refine the method by employing the concept of instantaneous power spectra, extending it to reflect an instantaneous time-correlation of velocities with those in the future as well as with those in the past, and present a new method to obtain the instantaneous spectral density of KE (iKESD). This approach enables the simultaneous spectral and temporal resolution of KE with unlimited time precision. We discuss the formal and novel properties of the new iKESD approaches and how to optimize computational methods and determine parameters for practical applications. The method is specifically applied to the nonequilibrium MD simulation of vibrational relaxation of the OD stretch mode in a hydrated HOD molecule by employing a hybrid quantum mechanical/molecular mechanical (QM/MM) potential. We directly compare the computational results with the OD band population relaxation time profiles extracted from the IR pump-probe measurements for 5% HOD in water. The calculated iKESD yields the OD bond relaxation time scale ∼30% larger than the experimental value, and this decay is largely frequency-independent if the classical anharmonicity is accounted for. From the integrated iKESD over intra- and intermolecular bands, the major energy transfer pathways were found to involve the HOD bending mode in the subps range, then the internal modes of the solvent until 5 ps after excitation, and eventually the solvent intermolecular modes. Also, strong hydrogen

  9. Monte Carlo simulation of electron depth distribution and backscattering for carbon films deposited on aluminium as a function of incidence angle and primary energy

    International Nuclear Information System (INIS)

    Dapor, Maurizio

    2005-01-01

    Carbon films are deposited on various substrates (polymers, polyester fabrics, polyester yarns, metal alloys) both for experimental and technological motivations (medical devices, biocompatible coatings, food package and so on). Computational studies of the penetration of electron beams in supported thin film of carbon are very useful in order to compare the simulated results with analytical techniques data (obtained by scanning electron microscopy and/or Auger electron spectroscopy) and investigate the film characteristics. In the present paper, the few keV electron depth distribution and backscattering coefficient for the special case of film of carbon deposited on aluminium are investigated, by a Monte Carlo simulation, as a function of the incidence angle and primary electron energy. The simulated results can be used as a way to evaluate the carbon film thickness by a set of measurements of the backscattering coefficient

  10. Neutron production in deuteron-induced reactions on Li, Be, and C at an incident energy of 102 MeV

    Directory of Open Access Journals (Sweden)

    Araki Shouhei

    2017-01-01

    Full Text Available Double-differential cross sections (DDXs of deuteron-induced neutron production reactions on Li, Be, and C at 102 MeV were measured at forward angles (≤ 25∘ by means of a time of flight method with NE213 liquid organic scintillators at the Research Center of Nuclear Physics, Osaka University. The experimental results were compared with model calculations with PHITS and DEURACS. The DEURACS calculation reproduces the experimental DDXs for C at very forward angles than the PHITS one. Moreover, the incident energy dependence of the Li(d,xn reaction was investigated by adding the DDX data measured previously at 25 and 40 MeV.

  11. Metal, bond energy, and ancillary ligand effects on actinide-carbon σ-bond hydrogenolysis. A kinetic and mechanistic study

    International Nuclear Information System (INIS)

    Lin, Z.; Marks, T.J.

    1987-01-01

    A kineticmechanistic study of actinide hydrocarbyl ligand hydrogenolysis (An-R + H 2 → An-H + RH) is reported. For the complex Cp' 2 TH(CH 2 -t-Bu)(O-t-Bu)(Cp' = eta 5 -Me 5 C 5 ), the rate law is first-order in organoactinide and first-order in H 2 , with k/sub H2/k/sub D2/ = 2.5 (4) and k/sub THF/k/sub toluene/ = 2.9 (4). For a series of complexes, hydrogenolysis rates span a range of ca. 10 5 with Cp' 2 ThCH 2 C(CH 3 ) 2 CH 2 ≅ Cp' 2 U(CH 2 -t-Bu) (too rapid to measure accurately) > Cp' 2 Th(CH 2 -t-Bu)[OCH(t-Bu) 2 ] = Cp' 2 Th(CH 2 -t-Bu)(O-t-Bu) > Cp' 2 Th(CH 2 -t-Bu)(Cl) > Me 2 Si(Me 4 C 5 ) 2 Th(n-Bu) 2 > Cp' 2 Th(n-Bu) 2 ≅ Cp' 2 ThMe 2 > Cp' 2 Th(Me)(O 3 SCF 3 ) > Cp' 2 Th(n-Bu)[OCG(t-Bu) 2 ] ≅ Cp' 2 Th(Me)[OSiMe 2 (t-Bu)] > Cp' 2 ZrMe 2 = Cp' 2 Th(rho-C 6 H 4 NMe 2 )(O-tu-Bu) > Cp' 2 Th(Ph)(O-t-Bu) > Cp' 2 U(Me)[OCH(t-Bu) 2 ] > Cp' 2 Th(Me)[OCH(t-Bu) 2 ]. In the majority of cases, the rate law is cleanly first-order in organoactinide over 3 or more half-lives. However, for Cp' 2 ThMe 2 → (Cp' 2 ThH 2 ) 2 , an intermediate is observe by NMR that is probably [Cp' 2 Th(Me)(μ-H)] 2 . For Cp' 2 Th(Me)(O 3 SCF 3 ), a follow-up reaction, which consumes Cp' 2 TH(H)(O 3 SCF 3 ) is detected. Variable-temperature kinetic studies yield ΔH** = 3.7 (2) kcalmol and ΔS double dagger = -50.8 (7) eu for Cp' 2 Th(CH 2 -t-Bu)(O-t-Bu) and ΔH double dagger = 9 (2) kcalmol and ΔS double dagger = -45 (5) eu for Cp' 2 U(Me)[OCH(O-t-Bu) 2

  12. Kinetic analysis of growth rate, ATP, and pigmentation suggests an energy-spilling function for the pigment prodigiosin of Serratia marcescens.

    Science.gov (United States)

    Haddix, Pryce L; Jones, Sarah; Patel, Pratik; Burnham, Sarah; Knights, Kaori; Powell, Joan N; LaForm, Amber

    2008-11-01

    Serratia marcescens is a gram-negative environmental bacterium and opportunistic pathogen. S. marcescens expresses prodigiosin, a bright red and cell-associated pigment which has no known biological function for producing cells. We present here a kinetic model relating cell, ATP, and prodigiosin concentration changes for S. marcescens during cultivation in batch culture. Cells were grown in a variety of complex broth media at temperatures which either promoted or essentially prevented pigmentation. High growth rates were accompanied by large decreases in cellular prodigiosin concentration; low growth rates were associated with rapid pigmentation. Prodigiosin was induced most strongly during limited growth as the population transitioned to stationary phase, suggesting a negative effect of this pigment on biomass production. Mathematically, the combined rate of formation of biomass and bioenergy (as ATP) was shown to be equivalent to the rate of prodigiosin production. Studies with cyanide inhibition of both oxidative phosphorylation and pigment production indicated that rates of biomass and net ATP synthesis were actually higher in the presence of cyanide, further suggesting a negative regulatory role for prodigiosin in cell and energy production under aerobic growth conditions. Considered in the context of the literature, these results suggest that prodigiosin reduces ATP production by a process termed energy spilling. This process may protect the cell by limiting production of reactive oxygen compounds. Other possible functions for prodigiosin as a mediator of cell death at population stationary phase are discussed.

  13. Departures of the electron energy distribution from a Maxwellian in hydrogen. I - Formulation and solution of the electron kinetic equation. II - Consequences

    Science.gov (United States)

    Shoub, E. C.

    1977-01-01

    The problem of calculating the steady-state free-electron energy distribution in a hydrogen gas is considered in order to study departures of that distribution from a Maxwellian at sufficiently low degrees of ionization. A model kinetic equation is formulated and solved analytically for the one-particle electron distribution function in a steady-state partially ionized hydrogen gas, and it is shown that the formal solution can be accurately approximated by using the WKB method. The solutions obtained indicate that the high-energy tail of the distribution is susceptible to distortion by imbalanced inelastic collisions for ionization fractions not exceeding about 0.1 and that such departures from a Maxwellian can lead to significant changes in the collisional excitation and ionization rates of ground-state hydrogen atoms. Expressions for the electron-hydrogen collision rates are derived which explicitly display their dependence on the hydrogen departure coefficients. The results are applied in order to compare self-consistent predictions with those based on the a priori assumption of a Maxwellian distribution for models of the thermal ionization equilibrium of hydrogen in the optically thin limit, spectral-line formation by a gas consisting of two-level atoms, and radiative transfer in finite slabs by a gas of four-level hydrogen atoms.

  14. Kinetic Interface

    DEFF Research Database (Denmark)

    2009-01-01

    A kinetic interface for orientation detection in a video training system is disclosed. The interface includes a balance platform instrumented with inertial motion sensors. The interface engages a participant's sense of balance in training exercises.......A kinetic interface for orientation detection in a video training system is disclosed. The interface includes a balance platform instrumented with inertial motion sensors. The interface engages a participant's sense of balance in training exercises....

  15. Experimental search for solar hidden photons in the eV energy range using kinetic mixing with photons

    International Nuclear Information System (INIS)

    Mizumoto, T.; Ohta, R.; Horie, T.; Suzuki, J.; Minowa, M.; Inoue, Y.

    2013-01-01

    We have searched for solar hidden photons in the eV energy range using a dedicated hidden photon detector. The detector consisted of a parabolic mirror with a diameter of 500 mm and a focal length of 1007 mm installed in a vacuum chamber, and a photomultiplier tube at its focal point. The detector was attached to the Tokyo axion helioscope, Sumico which has a mechanism to track the sun. From the result of the measurement, we found no evidence for the existence of hidden photons and set a limit on the photon-hidden photon mixing parameter χ depending on the hidden photon mass m γ'

  16. Exploring the Potential of Fulvalene Dimetals as Platforms for Molecular Solar Thermal Energy Storage: Computations, Syntheses, Structures, Kinetics, and Catalysis

    Energy Technology Data Exchange (ETDEWEB)

    Borjesson, K; Coso, D; Gray, V; Grossman, JC; Guan, JQ; Harris, CB; Hertkorn, N; Hou, ZR; Kanai, Y; Lee, D; Lomont, JP; Majumdar, A; Meier, SK; Moth-Poulsen, K; Myrabo, RL; Nguyen, SC; Segalman, RA; Srinivasan, V; Tolman, WB; Vinokurov, N; Vollhardt, KPC; Weidman, TW

    2014-10-03

    A study of the scope and limitations of varying the ligand framework around the dinuclear core of FvRu(2) in its function as a molecular solar thermal energy storage framework is presented. It includes DFT calculations probing the effect of substituents, other metals, and CO exchange for other ligands on Delta H-storage. Experimentally, the system is shown to be robust in as much as it tolerates a number of variations, except for the identity of the metal and certain substitution patterns. Failures include 1,1',3,3'-tetra-tert-butyl (4), 1,2,2',3'-tetraphenyl (9), diiron (28), diosmium (24), mixed iron-ruthenium (27), dimolybdenum (29), and di-tungsten (30) derivatives. An extensive screen of potential catalysts for the thermal reversal identified AgNO3-SiO2 as a good candidate, although catalyst decomposition remains a challenge.

  17. High Kinetic Energy Penetrator Shielding and High Wear Resistance Materials Fabricated with Boron Nitride Nanotubes (BNNTS) and BNNT Polymer Composites

    Science.gov (United States)

    Kang, Jin Ho (Inventor); Park, Cheol (Inventor); Sauti, Godfrey (Inventor); Smith, Michael W. (Inventor); Jordan, Kevin C. (Inventor); Lowther, Sharon E. (Inventor); Bryant, Robert George (Inventor)

    2015-01-01

    Boron nitride nanotubes (BNNTs), boron nitride nanoparticles (BNNPs), carbon nanotubes (CNTs), graphites, or combinations, are incorporated into matrices of polymer, ceramic or metals. Fibers, yarns, and woven or nonwoven mats of BNNTs are used as toughening layers in penetration resistant materials to maximize energy absorption and/or high hardness layers to rebound or deform penetrators. They can be also used as reinforcing inclusions combining with other polymer matrices to create composite layers like typical reinforcing fibers such as Kevlar.RTM., Spectra.RTM., ceramics and metals. Enhanced wear resistance and usage time are achieved by adding boron nitride nanomaterials, increasing hardness and toughness. Such materials can be used in high temperature environments since the oxidation temperature of BNNTs exceeds 800.degree. C. in air. Boron nitride based composites are useful as strong structural materials for anti-micrometeorite layers for spacecraft and space suits, ultra strong tethers, protective gear, vehicles, helmets, shields and safety suits/helmets for industry.

  18. Exploring the potential of fulvalene dimetals as platforms for molecular solar thermal energy storage: computations, syntheses, structures, kinetics, and catalysis.

    Science.gov (United States)

    Börjesson, Karl; Ćoso, Dušan; Gray, Victor; Grossman, Jeffrey C; Guan, Jingqi; Harris, Charles B; Hertkorn, Norbert; Hou, Zongrui; Kanai, Yosuke; Lee, Donghwa; Lomont, Justin P; Majumdar, Arun; Meier, Steven K; Moth-Poulsen, Kasper; Myrabo, Randy L; Nguyen, Son C; Segalman, Rachel A; Srinivasan, Varadharajan; Tolman, Willam B; Vinokurov, Nikolai; Vollhardt, K Peter C; Weidman, Timothy W

    2014-11-17

    A study of the scope and limitations of varying the ligand framework around the dinuclear core of FvRu2 in its function as a molecular solar thermal energy storage framework is presented. It includes DFT calculations probing the effect of substituents, other metals, and CO exchange for other ligands on ΔHstorage . Experimentally, the system is shown to be robust in as much as it tolerates a number of variations, except for the identity of the metal and certain substitution patterns. Failures include 1,1',3,3'-tetra-tert-butyl (4), 1,2,2',3'-tetraphenyl (9), diiron (28), diosmium (24), mixed iron-ruthenium (27), dimolybdenum (29), and ditungsten (30) derivatives. An extensive screen of potential catalysts for the thermal reversal identified AgNO3 -SiO2 as a good candidate, although catalyst decomposition remains a challenge. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Energy aAnalysis and Kinetics of Mint Leaves Dehydration Using Vibro-Fluidized Bed Heat Pump Dryer

    Directory of Open Access Journals (Sweden)

    S. M Ataei Ardestani

    2015-03-01

    Full Text Available Fluidized bed dryers have not yet been used for drying products such as mint leaves. This could be due to high porosity and low mechanical resistance resulting in poor quality of fluidization. Applying vibration has been recommended to overcome problems such as channeling and defluidization, and hence improving the fluidization quality. In this research, a laboratory scale vibro-fluidized bed heat pump dryer was designed and constructed for drying mint leaves. The experiments were conducted at vibration frequency of 80 Hz and amplitude of 3 mm. The velocity and temperature of the inlet air was controlled by an automatic control system. Experiments were carried out at 40, 50 and 60 °C, and two methods: heat pump drying (HPD and non-heat pump drying (NHPD. The results revealed that drying process primarily occurred in the falling rate period. Effective moisture diffusivity of the samples increased with increase in drying air temperature and varied from 4.26656×10-11 to 2.95872×10-10 m2 s-1 for the HPD method, and 3.71918×10-11 to 1.29196×10-10 m2 s-1 for the NHPD method and was within the reported range of 10-9 to 10-11 m2 s-1 for drying of food materials. The activation energy was determined to be 84 kJ mol-1 for the HPD and 54.34 kJ mol-1 for the NHPD, both have very good agreement with the results of other investigators. The coefficient of performance and specific moisture evaporation rate showed the acceptable performance of the heat pump system. Moreover, the energy consumption of the dryer for the NHPD method was more than the HPD method.

  20. Structure of ultrathin films of Co on Cu(111) from normal-incidence x-ray standing wave and medium-energy ion scattering measurements

    International Nuclear Information System (INIS)

    Butterfield, M.T.; Crapper, M.D.; Noakes, T.C.Q.; Bailey, P.; Jackson, G.J.; Woodruff, D.P.

    2000-01-01

    Applications of the techniques of normal-incidence x-ray standing wave (NIXSW) and medium-energy ion scattering (MEIS) to the elucidation of the structure of an ultrathin metallic film, Co on Cu(111), are reported. NIXSW and MEIS are shown to yield valuable and complementary information on the structure of such systems, yielding both the local stacking sequence and the global site distribution. For the thinnest films of nominally two layers, the first layer is of entirely fcc registry with respect to the substrate, but in the outermost layer there is significant occupation of hcp local sites. For films up to 8 monolayers (ML) thick, the interlayer spacing of the Co layers is 0.058±0.006 Aa smaller than the Cu substrate (111) layer spacing. With increasing coverage, the coherent fraction of the (1(bar sign)11) NIXSW decreases rapidly, indicating that the film does not grow in a fcc continuation beyond two layers. For films in this thickness range, hcp-type stacking dominates fcc twinning by a ratio of 2:1. The variation of the (1(bar sign)11) NIXSW coherent fraction with thickness shows that the twinning occurs close to the Co/Cu interface. For thicker films of around 20 ML deposited at room temperature, medium-energy ion scattering measurements reveal a largely disordered structure. Upon annealing to 300 deg. C the 20-ML films order into a hcp structure

  1. Erbium hydride decomposition kinetics.

    Energy Technology Data Exchange (ETDEWEB)

    Ferrizz, Robert Matthew

    2006-11-01

    Thermal desorption spectroscopy (TDS) is used to study the decomposition kinetics of erbium hydride thin films. The TDS results presented in this report are analyzed quantitatively using Redhead's method to yield kinetic parameters (E{sub A} {approx} 54.2 kcal/mol), which are then utilized to predict hydrogen outgassing in vacuum for a variety of thermal treatments. Interestingly, it was found that the activation energy for desorption can vary by more than 7 kcal/mol (0.30 eV) for seemingly similar samples. In addition, small amounts of less-stable hydrogen were observed for all erbium dihydride films. A detailed explanation of several approaches for analyzing thermal desorption spectra to obtain kinetic information is included as an appendix.

  2. Study of the cross-section of the reaction D + D → 4He + γ with incident energies below 6 MeV

    International Nuclear Information System (INIS)

    Degre, A.

    1969-01-01

    The measurement of the cross-section of the reaction D(d,γ) 4 He has been made for getting some information concerning the nuclear structure of 4 He and the existence of the d+d final state in the photo-decay of 4 He. The E1 transition is forbidden because of the selection rules of the isobaric spin which makes this reaction a useful tool for looking for a 2 + , T=0 state. In the reaction D(d,γ) 4 He, the photon is produced in an electrical quadrupolar transition which makes us expect a very low value for the cross-section, certainly in the magnitude order of 0.01 micro-barn (10 -32 cm 2 ) and a very important background noise (chiefly from cosmic origin). The measurement of this cross-section requires a dedicated efficient equipment. The incident deuteron beam is produced by a 5.5 MeV Van de Graaff accelerator, the beam intensity is about 1 μA and we use a gaseous deuterium target. The gamma detector is based on NaI(Tl) crystal combined with an XP-1031 photomultiplier. The NaI(Tl) crystal is surrounded by a scintillating plastic allowing the detection of anti-coincidence events and as a consequence the reduction of the cosmic background. We have measured the value of the differential cross-section at different angles: 0, 45, 90 and 135 degrees (Center of mass frame) for an incident energy of 3.64 MeV. We have added our results to others previously published in the literature, we see that they are complementary and as a whole show the non-existence of fine structure in the excitation curve

  3. Technical Note: On the impact of the incident electron beam energy on the primary dose component of flattening filter free photon beams.

    Science.gov (United States)

    Kuess, Peter; Georg, Dietmar; Palmans, Hugo; Lechner, Wolfgang

    2016-08-01

    For commercially available linear accelerators (Linacs), the electron energies of flattening filter free (FFF) and flattened (FF) beams are either identical or the electron energy of the FFF beam is increased to match the percentage depth dose curve (PDD) of the FF beam (in reference geometry). This study focuses on the primary dose components of FFF beams for both kinds of settings, studied on the same Linac. The measurements were conducted on a VersaHD Linac (Elekta, Crawley, UK) for both FF and FFF beams with nominal energies of 6 and 10 MV. In the clinical setting of the VersaHD, the energy of FFFM (Matched) beams is set to match the PDDs of the FF beams. In contrast the incident electron beam of the FFFU beam was set to the same energy as for the FF beam. Half value layers (HVLs) and a dual parameter beam quality specifier (DPBQS) were determined. For the 6 MV FFFM beam, HVL and DPBQS values were very similar compared to those of the 6 MV FF beam, while for the 10 MV FFFM and FF beams, only %dd(10)x and HVL values were comparable (differences below 1.5%). This shows that matching the PDD at one depth does not guarantee other beam quality dependent parameters to be matched. For FFFU beams, all investigated beam quality specifiers were significantly different compared to those for FF beams of the same nominal accelerator potential. The DPBQS of the 6 MV FF and FFFM beams was equal within the measurement uncertainty and was comparable to published data of a machine with similar TPR20,10 and %dd(10)x. In contrast to that, the DPBQS's two parameters of the 10 MV FFFM beam were substantially higher compared to those for the 10 MV FF beam. PDD-matched FF and FFF beams of both nominal accelerator potentials were observed to have similar HVL values, indicating similarity of their primary dose components. Using the DPBQS revealed that the mean attenuation coefficient was found to be the same within the uncertainty of 0.8% for 6 MV FF and 6 MV FFFM beams, while for 10 MV

  4. Technical Note: On the impact of the incident electron beam energy on the primary dose component of flattening filter free photon beams

    International Nuclear Information System (INIS)

    Kuess, Peter; Georg, Dietmar; Lechner, Wolfgang; Palmans, Hugo

    2016-01-01

    Purpose: For commercially available linear accelerators (Linacs), the electron energies of flattening filter free (FFF) and flattened (FF) beams are either identical or the electron energy of the FFF beam is increased to match the percentage depth dose curve (PDD) of the FF beam (in reference geometry). This study focuses on the primary dose components of FFF beams for both kinds of settings, studied on the same Linac. Methods: The measurements were conducted on a VersaHD Linac (Elekta, Crawley, UK) for both FF and FFF beams with nominal energies of 6 and 10 MV. In the clinical setting of the VersaHD, the energy of FFF M (Matched) beams is set to match the PDDs of the FF beams. In contrast the incident electron beam of the FFF U beam was set to the same energy as for the FF beam. Half value layers (HVLs) and a dual parameter beam quality specifier (DPBQS) were determined. Results: For the 6 MV FFF M beam, HVL and DPBQS values were very similar compared to those of the 6 MV FF beam, while for the 10 MV FFF M and FF beams, only %dd(10) x and HVL values were comparable (differences below 1.5%). This shows that matching the PDD at one depth does not guarantee other beam quality dependent parameters to be matched. For FFF U beams, all investigated beam quality specifiers were significantly different compared to those for FF beams of the same nominal accelerator potential. The DPBQS of the 6 MV FF and FFF M beams was equal within the measurement uncertainty and was comparable to published data of a machine with similar TPR 20,10 and %dd(10) x . In contrast to that, the DPBQS’s two parameters of the 10 MV FFF M beam were substantially higher compared to those for the 10 MV FF beam. Conclusions: PDD-matched FF and FFF beams of both nominal accelerator potentials were observed to have similar HVL values, indicating similarity of their primary dose components. Using the DPBQS revealed that the mean attenuation coefficient was found to be the same within the uncertainty of

  5. Part 1: Kinetic energy dependencies of selected ion-molecule reactions; Part 2: Photochemistry of (FSO sub 3 ) sub 2 , FSO sub 3 , and FNO

    Energy Technology Data Exchange (ETDEWEB)

    Burley, J.D.

    1991-07-01

    In Part 1, guided ion beam mass spectroscopy is used to study the ion-molecule reactions O{sup +}({sup 4}S) + H{sub 2}(D{sub 2}, HD), (O{sup +}{sup 4}S) + N{sub 2}, C{sup +}({sup 2}P) + O{sub 2} and C{sup +}(P) + N{sub 2}. Integral reaction cross sections are measured as a function of kinetic energy in the center-of-mass frame. Reaction mechanisms and dynamics are examined, and the results are compared to the predictions of phase space theory. In some cases, thermochemistry for neutral and ionic species is derived. In Part 2, photoabsorption cross sections are measured for peroxydisulfuryl difluoride, (FSO{sub 3}){sub 2}, and the fluorosulfate radical, FSO{sub 3}. Photoabsorption cross sections of nitrosyl fluoride, FNO, are also measured, and the FNO absorption spectrum is analyzed and assigned. Spectral results for FNO are compared to the predictions and ab initio calculations and to those obtained for the isoelectronic compound HONO. 259 refs., 34 figs., 9 tabs.

  6. Studies on fission with ALADIN. Precise and simultaneous measurement of fission yields, total kinetic energy and total prompt neutron multiplicity at GSI

    International Nuclear Information System (INIS)

    Martin, Julie-Fiona; Taieb, Julien; Chatillon, Audrey; Belier, Gilbert; Boutoux, Guillaume; Ebran, Adeline; Gorbinet, Thomas; Grente, Lucie; Laurent, Benoit; Pellereau, Eric; Alvarez-Pol, Hector; Ayyad, Yassid; Benlliure, Jose; Cortina Gil, Dolores; Caamano, Manuel; Fernandez Dominguez, Beatriz; Paradela, Carlos; Ramos, Diego; Rodriguez-Sanchez, Jose-Luis; Vargas, Jossitt; Audouin, Laurent; Tassan-Got, Laurent; Aumann, Thomas; Casarejos, Enrique; Farget, Fanny; Rodriguez-Tajes, Carme; Heinz, Andreas; Jurado, Beatriz; Kelic-Heil, Aleksandra; Kurz, Nikolaus; Nociforo, Chiara; Pietri, Stephane; Rossi, Dominic; Schmidt, Karl-Heinz; Simon, Haik; Voss, Bernd; Weick, Helmut

    2015-01-01

    A novel technique for fission studies, based on the inverse kinematics approach, is presented. Following pioneering work in the nineties, the SOFIA Collaboration has designed and built an experimental set-up dedicated to the simultaneous measurement of isotopic yields, total kinetic energies and total prompt neutron multiplicities, by fully identifying both fission fragments in coincidence, for the very first time. This experiment, performed at GSI, permits to study the fission of a wide variety of fissioning systems, ranging from mercury to neptunium, possibly far from the valley of stability. A first experiment, performed in 2012, has provided a large array of unprecedented data regarding the nuclear fission process. An excerpt of the results is presented. With this solid starter, further improvements of the experimental set-up are considered, which are consistent with the expected developments at the GSI facility, in order to measure more fission observables in coincidence. The completeness reached in the SOFIA data, permits to scrutinize the correlations between the interesting features of fission, offering a very detailed insight in this still unraveled mechanism. (orig.)

  7. Studies on fission with ALADIN. Precise and simultaneous measurement of fission yields, total kinetic energy and total prompt neutron multiplicity at GSI

    Energy Technology Data Exchange (ETDEWEB)

    Martin, Julie-Fiona; Taieb, Julien; Chatillon, Audrey; Belier, Gilbert; Boutoux, Guillaume; Ebran, Adeline; Gorbinet, Thomas; Grente, Lucie; Laurent, Benoit; Pellereau, Eric [CEA DAM Bruyeres-le-Chatel, Arpajon (France); Alvarez-Pol, Hector; Ayyad, Yassid; Benlliure, Jose; Cortina Gil, Dolores; Caamano, Manuel; Fernandez Dominguez, Beatriz; Paradela, Carlos; Ramos, Diego; Rodriguez-Sanchez, Jose-Luis; Vargas, Jossitt [Universidad de Santiago de Compostela, Santiago de Compostela (Spain); Audouin, Laurent; Tassan-Got, Laurent [CNRS/IN2P3, IPNO, Orsay (France); Aumann, Thomas [Technische Universitaet Darmstadt, Darmstadt (Germany); Casarejos, Enrique [Universidad de Vigo, Vigo (Spain); Farget, Fanny; Rodriguez-Tajes, Carme [CNRS/IN2P3, GANIL, Caen (France); Heinz, Andreas [Chalmers University of Technology, Gothenburg (Sweden); Jurado, Beatriz [CNRS/IN2P3, CENBG, Gradignan (France); Kelic-Heil, Aleksandra; Kurz, Nikolaus; Nociforo, Chiara; Pietri, Stephane; Rossi, Dominic; Schmidt, Karl-Heinz; Simon, Haik; Voss, Bernd; Weick, Helmut [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, Darmstadt (Germany)

    2015-12-15

    A novel technique for fission studies, based on the inverse kinematics approach, is presented. Following pioneering work in the nineties, the SOFIA Collaboration has designed and built an experimental set-up dedicated to the simultaneous measurement of isotopic yields, total kinetic energies and total prompt neutron multiplicities, by fully identifying both fission fragments in coincidence, for the very first time. This experiment, performed at GSI, permits to study the fission of a wide variety of fissioning systems, ranging from mercury to neptunium, possibly far from the valley of stability. A first experiment, performed in 2012, has provided a large array of unprecedented data regarding the nuclear fission process. An excerpt of the results is presented. With this solid starter, further improvements of the experimental set-up are considered, which are consistent with the expected developments at the GSI facility, in order to measure more fission observables in coincidence. The completeness reached in the SOFIA data, permits to scrutinize the correlations between the interesting features of fission, offering a very detailed insight in this still unraveled mechanism. (orig.)

  8. Profile of the horizontal wind variance near the ground in near neutral flow – K-theory and the transport of the turbulent kinetic energy

    Directory of Open Access Journals (Sweden)

    S. Yahaya

    2009-05-01

    Full Text Available This paper deals with the characteristics of the atmospheric turbulent flow in the vicinity of the ground, and particularly with the profile of the horizontal wind variance. The study is based on experimental measurements performed with fast cup anemometers located near the ground at 5 different levels (from 0.25 to 4 m and sampled at 1 Hz. The experiment was carried over two agricultural plots with various tillage treatments in a fallow semiarid area (Central Aragon, Spain. The results of this study reveal that near the ground surface and under moderate wind, the horizontal wind variance logarithmically increases with height, in direct relationship with the friction velocity and the roughness length scale. A theoretical development has allowed us to link this behaviour to the modeling of the turbulent kinetic energy (TKE transport through the eddy diffusivity. Thus, the study proposes a formulation of the similarity universal function of the horizontal wind variance. Besides, the formulation offers a new method for the determination of the friction velocity and the roughness length scale and can be used for the evaluation of the TKE transport rate.

  9. Incidents analysis

    International Nuclear Information System (INIS)

    Francois, P.

    1996-01-01

    We undertook a study programme at the end of 1991. To start with, we performed some exploratory studies aimed at learning some preliminary lessons on this type of analysis: Assessment of the interest of probabilistic incident analysis; possibility of using PSA scenarios; skills and resources required. At the same time, EPN created a working group whose assignment was to define a new approach for analysis of incidents on NPPs. This working group gave thought to both aspects of Operating Feedback that EPN wished to improve: Analysis of significant incidents; analysis of potential consequences. We took part in the work of this group, and for the second aspects, we proposed a method based on an adaptation of the event-tree method in order to establish a link between existing PSA models and actual incidents. Since PSA provides an exhaustive database of accident scenarios applicable to the two most common types of units in France, they are obviously of interest for this sort of analysis. With this method we performed some incident analyses, and at the same time explores some methods employed abroad, particularly ASP (Accident Sequence Precursor, a method used by the NRC). Early in 1994 EDF began a systematic analysis programme. The first, transient phase will set up methods and an organizational structure. 7 figs

  10. Effect of ski geometry and standing height on kinetic energy: equipment designed to reduce risk of severe traumatic injuries in alpine downhill ski racing.

    Science.gov (United States)

    Gilgien, Matthias; Spörri, Jörg; Kröll, Josef; Müller, Erich

    2016-01-01

    Injuries in downhill (DH) are often related to high speed and, therefore, to high energy and forces which are involved in injury situations. Yet to date, no study has investigated the effect of ski geometry and standing height on kinetic energy (EKIN) in DH. This knowledge would be essential to define appropriate equipment rules that have the potential to protect the athletes' health. During a field experiment on an official World Cup DH course, 2 recently retired world class skiers skied on 5 different pairs of skis varying in width, length and standing height. Course characteristics, terrain and the skiers' centre of mass position were captured by a differential Global Navigational Satellite System-based methodology. EKIN, speed, ski-snow friction force (FF), ground reaction force (FGRF) and ski-snow friction coefficient (CoeffF) were calculated and analysed in dependency of the used skis. In the steep terrain, longer skis with reduced width and standing height significantly decreased average EKIN by ∼ 3%. Locally, even larger reductions of EKIN were observed (up to 7%). These local decreases in EKIN were mainly explainable by higher FF. Moreover, CoeffF differences seem of greater importance for explaining local FF differences than the differences in FGRF. Knowing that increased speed and EKIN likely lead to increased forces in fall/crash situations, the observed equipment-induced reduction in EKIN can be considered a reasonable measure to improve athlete safety, even though the achieved preventative gains are rather small and limited to steep terrain. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://www.bmj.com/company/products-services/rights-and-licensing/

  11. Extension of a Kinetic Approach to Chemical Reactions to Electronic Energy Levels and Reactions Involving Charged Species with Application to DSMC Simulations

    Science.gov (United States)

    Liechty, Derek S.

    2014-01-01

    The ability to compute rarefied, ionized hypersonic flows is becoming more important as missions such as Earth reentry, landing high mass payloads on Mars, and the exploration of the outer planets and their satellites are being considered. Recently introduced molecular-level chemistry models that predict equilibrium and nonequilibrium reaction rates using only kinetic theory and fundamental molecular properties are extended in the current work to include electronic energy level transitions and reactions involving charged particles. These extensions are shown to agree favorably with reported transition and reaction rates from the literature for near-equilibrium conditions. Also, the extensions are applied to the second flight of the Project FIRE flight experiment at 1634 seconds with a Knudsen number of 0.001 at an altitude of 76.4 km. In order to accomplish this, NASA's direct simulation Monte Carlo code DAC was rewritten to include the ability to simulate charge-neutral ionized flows, take advantage of the recently introduced chemistry model, and to include the extensions presented in this work. The 1634 second data point was chosen for comparisons to be made in order to include a CFD solution. The Knudsen number at this point in time is such that the DSMC simulations are still tractable and the CFD computations are at the edge of what is considered valid because, although near-transitional, the flow is still considered to be continuum. It is shown that the inclusion of electronic energy levels in the DSMC simulation is necessary for flows of this nature and is required for comparison to the CFD solution. The flow field solutions are also post-processed by the nonequilibrium radiation code HARA to compute the radiative portion.

  12. Kinetic bridges.

    Science.gov (United States)

    1980-01-01

    This report on kinetic bridges is essentially a state-of-the-art study on two types of bridges whose location or physical characteristics are designed to be time dependent. The first type, called a "relocatable bridge", is essentially for use as a te...

  13. Hydroxylamine nitrate self-catalytic kinetics study with adiabatic calorimetry

    International Nuclear Information System (INIS)

    Liu Lijun; Wei Chunyang; Guo Yuyan; Rogers, William J.; Sam Mannan, M.

    2009-01-01

    Hydroxylamine nitrate (HAN) is an important member of the hydroxylamine compound family with applications that include equipment decontamination in the nuclear industry and aqueous or solid propellants. Due to its instability and autocatalytic behavior, HAN has been involved in several incidents at the Hanford and Savannah River Site (SRS) [Technical Report on Hydroxylamine Nitrate, US Department of Energy, 1998]. Much research has been conducted on HAN in different areas, such as combustion mechanism, decomposition mechanism, and runaway behavior. However, the autocatalytic decomposition behavior of HAN at runaway stage has not been fully addressed due to its highly exothermic and rapid decomposition behavior. This work is focused on extracting HAN autocatalytic kinetics and analyzing HAN critical behavior from adiabatic calorimetry measurements. A lumped autocatalytic kinetic model for HAN and associated model parameters are determined. Also the storage and handling critical conditions of diluted HAN solution without metal presence are quantified

  14. Heavy mesons production study in the reaction antip + d → 3He+X at an incident energy of 1450 MeV

    International Nuclear Information System (INIS)

    Loireleux, E.

    1990-02-01

    Study of heavy meson production in the antip + d → 3 He + X reaction has been performed at the Laboratoire National Saturne synchrotron at 1450 MeV incident energy. The helium 3 particles have been detected by means of the SPES III spectrometer in an angular range between -0.2 0 and 21 0 and for momenta between 600 MeV/c and 1400 MeV/c. In the first part of this work, we give a summary of the different experimental and theoretical results already obtained on the subject during the last twenty years. The second part of this thesis is devoted to the description of the experimental set-up by which this experiment was conducted, that is the spectrometer, the two kinds of wires chambers, the trigger and the read-out electronics associated with each detector. The calibration of the different parts of the detection and the beam characteristics - intensity and polarization - is studied in the third part. There is also a discussion about the data reduction and then the extraction of results obtained with the help of two and three pion phase spaces simulations in the spectrometer. The results are presented in the last part of this work. The differential cross sections and the analyzing powers have been established for the centre of mass angles varying in step of 10 degrees for the mesons π 0 , η and ω. A conclusion which indicates the prospects for a near future closes this thesis [fr

  15. Free-Free Transitions of the e-H System Inside a Dense Plasma Irradiated by a Laser Field at Very Low Incident-Electron Energies

    Science.gov (United States)

    Bhatia, A. K.; Sinha, C.

    2012-01-01

    The free-free transition is studied for an electron-hydrogen atom in ground state when a low-energy electron (external) is injected into hydrogenic plasma in the presence of an external homogenous, monochromatic, and linearly polarized laser field. The effect of plasma screening is considered in the Debye-Huckel approximation. The calculations are performed in the soft photon limit. The incident electron is considered to be dressed by the laser field in a nonperturbative manner by choosing the Volkov solutions in both the initial and final channels. The space part of the scattering wave function for the electron is solved numerically by taking into account the electron exchange. The laser-assisted differential and total cross sections are calculated for single-photon absorption or emission and no-photon exchange in the soft photon limit, the laser intensity being much less than the atomic field intensity. The calculations have been carried out for various values of Debye parameter, ranging from 0.005 to 0.12. A strong suppression is noted in the laser-assisted cross sections as compared to the field-free situation. A significant difference is noted for the singlet and triplet cross sections. The suppression is much more in the triplet states.

  16. Sidecut radius and kinetic energy: equipment designed to reduce risk of severe traumatic knee injuries in alpine giant slalom ski racing.

    Science.gov (United States)

    Kröll, Josef; Spörri, Jörg; Gilgien, Matthias; Schwameder, Hermann; Müller, Erich

    2016-01-01

    Kinetic energy (Ekin) increases with speed by the power of 2 and is considered a major risk factor for injuries in alpine ski racing. There is no empirical knowledge about the effect of ski geometry on Ekin. Consequently, the aim of this study was to investigate the influence of sidecut radius on the progress of Ekin while skiing through a multigate section in giant slalom (GS). 5 European-Cup level athletes skied on three different pairs of GS skis varying in sidecut radii (30, 35 and 40 m). Each athlete's position over time within a six gate section (including flat and steep terrain) was captured by the use of a differential Global Navigational Satellite System. Ekin, speed, time and path length were analysed for each pair of skis used. When using skis with greater sidecut radius, average Ekin was significantly lower over the entire six gate section, but not locally at every turn cycle. Particular decreases of Ekin were observed for both turns on the flat terrain, as well as for the turn at the terrain transition and the first turn on the steep terrain. The observed decreases in Ekin were found to be primarily explainable by increases in turn time. With respect to typical sport mechanisms that cause severe knee injuries, using skis with greater sidecut radius potentially provides additional injury preventative gain, particularly in specific areas within a run. However, this injury preventative gain during falls in GS should not be overestimated. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://www.bmj.com/company/products-services/rights-and-licensing/

  17. Physisorption kinetics

    CERN Document Server

    Kreuzer, Hans Jürgen

    1986-01-01

    This monograph deals with the kinetics of adsorption and desorption of molecules physisorbed on solid surfaces. Although frequent and detailed reference is made to experiment, it is mainly concerned with the theory of the subject. In this, we have attempted to present a unified picture based on the master equation approach. Physisorption kinetics is by no means a closed and mature subject; rather, in writing this monograph we intended to survey a field very much in flux, to assess its achievements so far, and to give a reasonable basis from which further developments can take off. For this reason we have included many papers in the bibliography that are not referred to in the text but are of relevance to physisorption. To keep this monograph to a reasonable size, and also to allow for some unity in the presentation of the material, we had to omit a number of topics related to physisorption kinetics. We have not covered to any extent the equilibrium properties of physisorbed layers such as structures, phase tr...

  18. Radiation incidents in dentistry

    International Nuclear Information System (INIS)

    Lovelock, D.J.

    1996-01-01

    Most dental practitioners act as their own radiographer and radiologist, unlike their medical colleagues. Virtually all dental surgeons have a dental X-ray machine for intraoral radiography available to them and 40% of dental practices have equipment for dental panoramic tomography. Because of the low energy of X-ray equipment used in dentistry, radiation incidents tend to be less serious than those associated with other aspects of patient care. Details of 47 known incidents are given. The advent of the 1985 and 1988 Ionising Radiation Regulations has made dental surgeons more aware of the hazards of radiation. These regulations, and general health and safety legislation, have led to a few dental surgeons facing legal action. Because of the publicity associated with these court cases, it is expected that there will be a decrease in radiation incidents arising from the practice of dentistry. (author)

  19. Association of PM2.5with diabetes, asthma, and high blood pressure incidence in Canada: A spatiotemporal analysis of the impacts of the energy generation and fuel sales.

    Science.gov (United States)

    Requia, Weeberb J; Adams, Matthew D; Koutrakis, Petros

    2017-04-15

    Numerous studies have reported an association between fine particulate matter (PM 2.5 ) and human health. Often these relationships are influenced by environmental factor that varies spatially and/or temporally. To our knowledge, there are no studies in Canada that have considered energy generation and fuel sales as PM 2.5 effects modifiers. Determining exposure and disease-specific risk factors over space and time is crucial for disease prevention and control. In this study, we evaluated the association of PM 2.5 with diabetes, asthma, and High Blood Pressure (HBP) incidence in Canada. Then we explored the impact of the energy generation and fuel sales on association changes. We fit an age-period-cohort as the study design, and we applied an over-dispersed Poisson regression model to estimate the risk. We conducted a sensitivity analysis to explore the impact of variation in clean energy rates and fuel sales on outcomes changes. The study included 117 health regions in Canada between 2007 and 2014. Our findings showed strong association of PM 2.5 with diabetes, asthma, and HBP incidence. A two-year increase of 10μg/m 3 in PM 2.5 was associated with an increased risk of 5.34% (95% CI: 2.28%; 12.53%) in diabetes incidence, 2.24% (95% CI: 0.93%; 5.38%) in asthma incidence, and 8.29% (95% CI: 3.44%; 19.98%) in HBP incidence. Our sensitivity analysis findings suggest higher risks of diabetes, asthma and HBP incidence when there is low clean energy generation. On the other hand, we found lower risk when we considered high rate of clean energy generation. For example, considering only diabetes incidence, we found that the risk in health regions with low rates of clean electricity is approximately 700% higher than the risk in health regions with high rates of clean electricity. Furthermore, our analysis suggested that the risk in regions with low fuel sales is 66% lower than the risk is health regions with low rates of clean electricity. Our study provides support for

  20. Stochastic kinetics

    International Nuclear Information System (INIS)

    Colombino, A.; Mosiello, R.; Norelli, F.; Jorio, V.M.; Pacilio, N.

    1975-01-01

    A nuclear system kinetics is formulated according to a stochastic approach. The detailed probability balance equations are written for the probability of finding the mixed population of neutrons and detected neutrons, i.e. detectrons, at a given level for a given instant of time. Equations are integrated in search of a probability profile: a series of cases is analyzed through a progressive criterium. It tends to take into account an increasing number of physical processes within the chosen model. The most important contribution is that solutions interpret analytically experimental conditions of equilibrium (moise analysis) and non equilibrium (pulsed neutron measurements, source drop technique, start up procedures)

  1. Anomalously fast kinetics of lipid monolayer buckling

    Science.gov (United States)

    Oppenheimer, Naomi; Diamant, Haim; Witten, Thomas A.

    2013-08-01

    We reexamine previous observations of folding kinetics of compressed lipid monolayers in light of the accepted mechanical buckling mechanism recently proposed by L. Pocivavsek [ScienceSCIEAS0036-807510.1126/science.1154069 320, 912 (2008)]. Using simple models, we set conservative limits on (a) the energy released in the mechanical buckling process and (b) the kinetic energy entailed by the observed folding motion. These limits imply a kinetic energy at least 30 times greater than the energy supplied by the buckling instability. We discuss possible extensions of the accepted picture that might resolve this discrepancy.

  2. Friction behaviour of TiAlN films around cubic/hexagonal transition: A 2D grazing incidence X-ray diffraction and electron energy loss spectroscopy study

    Energy Technology Data Exchange (ETDEWEB)

    Pinot, Y. [Université de Haute Alsace, Laboratoire Physique et Mécanique Textiles (EA 4365), F-68093 Mulhouse (France); Pac, M.-J., E-mail: marie-jose.pac@uha.fr [Université de Haute Alsace, Laboratoire Physique et Mécanique Textiles (EA 4365), F-68093 Mulhouse (France); Henry, P. [Université de Haute Alsace, Laboratoire Physique et Mécanique Textiles (EA 4365), F-68093 Mulhouse (France); Rousselot, C. [Université de Franche-Comté, FEMTO-ST (UMR CNRS 6174), F-25211 Montbéliard (France); Odarchenko, Ya.I.; Ivanov, D.A. [Université de Haute Alsace, Institut de Science des Matériaux de Mulhouse (UMR 7361 CNRS), F-68093 Mulhouse (France); Ulhaq-Bouillet, C.; Ersen, O. [Université de Strasbourg, Institut de Physique et Chimie des Matériaux de Strasbourg (UMR CNRS 7504), F-67087 Strasbourg (France); Tuilier, M.-H. [Université de Haute Alsace, Laboratoire Physique et Mécanique Textiles (EA 4365), F-68093 Mulhouse (France)

    2015-02-27

    The properties at different scales of Ti{sub 1−x}Al{sub x}N films deposited by reactive magnetron sputtering from TiAl sintered (S) targets produced by powder metallurgy are compared with those of a set of films previously deposited in the same conditions from mosaic targets (M) made of pure Ti and Al metals. For compositions close to the hcp/fcc transition (around x = 0.6), the friction behaviour, growth directions and organization of crystallized domains are found to be sensitive to the type of target used. The resistance to crack creation is higher for Ti{sub 0.54}Al{sub 0.46}N (S) and Ti{sub 0.38}Al{sub 0.62}N (S) than for Ti{sub 0.50}Al{sub 0.50}N (M) and Ti{sub 0.32}Al{sub 0.68}N (M). From the measurement of mechanical properties, toughness, and wear volumes and from the observation of wear tracks, it is found that films prepared from sintered targets exhibit a better wear resistance. Grazing incidence X-ray diffraction and electron energy loss spectroscopy in Transmission Electronic Microscopy are used to investigate the long- and short-range orders within the films. The morphology of Ti{sub 0.54}Al{sub 0.46}N (S) film can be considered as an array of crystalline domains having reciprocal-space vectors 111 and 200 directed along the meridian but with random in-plane orientation. Ti{sub 0.38}Al{sub 0.62}N (S) Al-rich film presents a random orientation of the crystalline domains whereas Ti{sub 0.32}Al{sub 0.68}N (M) deposited from composite targets exhibits a well-oriented fibrillar structure. The N K-edge Electron Energy Loss Near Edge Spectra are discussed with previous results of Extended X-ray Absorption Fine Structure Spectroscopy, which has evidenced different values of Al–N and Ti–N bond lengths, either octahedral (cubic-like) or tetrahedral (hexagonal-like) within Ti{sub 0.50}Al{sub 0.50}N (M) and Ti{sub 0.32}Al{sub 0.68}N (M) films. For similar compositions, films deposited from sintered alloys contain more nitrogen atoms in octahedral cubic

  3. Kinetic buffers.

    Science.gov (United States)

    Alibrandi, Giuseppe; Fabbrizzi, Luigi; Licchelli, Maurizio; Puglisi, Antonio

    2015-01-12

    This paper proposes a new type of molecular device that is able to act as an inverse proton sponge to slowly decrease the pH inside a reaction vessel. This makes the automatic monitoring of the concentration of pH-sensitive systems possible. The device is a composite formed of an alkyl chloride, which kinetically produces acidity, and a buffer that thermodynamically modulates the variation in pH value. Profiles of pH versus time (pH-t plots) have been generated under various experimental conditions by computer simulation, and the device has been tested by carrying out automatic spectrophotometric titrations, without using an autoburette. To underline the wide variety of possible applications, this new system has been used to realize and monitor HCl uptake by a di-copper(II) bistren complex in a single run, in a completely automatic experiment. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Kinetic theory of photophoresis

    International Nuclear Information System (INIS)

    Beresnev, S.A.; Chernyak, V.G.; Fomyagin, G.A.

    1988-01-01

    The force acting on an aerosol particle in one-sided illumination is calculated on the basis of solving a linearized gas-kinetic equation. A closed system of integral-moment equations describing photophoresis with arbitrary values of the Knudsen number and an arbitrary ratio of the particle and gas thermal conductivities is constructed. The possibility of arbitrary accommodation of the momentum and energy with interaction between the gas molecules and the particle surface is taken into account. The distribution of heat sources inside the radiation-absorbing particle is described by Mie theory. The results obtained are compared with the known theoretical and experimental data

  5. Ro-vibronic transition intensities for triatomic molecules from the exact kinetic energy operator; electronic spectrum for the C ˜ 1B2 ← X ˜ 1A1 transition in SO2

    Science.gov (United States)

    Zak, Emil J.; Tennyson, Jonathan

    2017-09-01

    A procedure for calculating ro-vibronic transition intensities for triatomic molecules within the Born-Oppenheimer approximation is reported. Ro-vibrational energy levels and wavefunctions are obtained with the DVR3D suite, which solves the nuclear motion problem with an exact kinetic energy operator. Absolute transition intensities are calculated both with the Franck-Condon approximation and with a full transition dipole moment surface. The theoretical scheme is tested on C ˜ 1B2 ← X ˜ 1A1 ro-vibronic transitions of SO2. Ab initio potential energy and dipole moment surfaces are generated for this purpose. The calculated ro-vibronic transition intensities and cross sections are compared with the available experimental and theoretical data.

  6. Ro-vibronic transition intensities for triatomic molecules from the exact kinetic energy operator; electronic spectrum for the C̃ 1B2 ← X̃ 1A1transition in SO2.

    Science.gov (United States)

    Zak, Emil J; Tennyson, Jonathan

    2017-09-07

    A procedure for calculating ro-vibronic transition intensities for triatomic molecules within the Born-Oppenheimer approximation is reported. Ro-vibrational energy levels and wavefunctions are obtained with the DVR3D suite, which solves the nuclear motion problem with an exact kinetic energy operator. Absolute transition intensities are calculated both with the Franck-Condon approximation and with a full transition dipole moment surface. The theoretical scheme is tested on C̃  1 B 2  ← X̃  1 A 1 ro-vibronic transitions of SO 2 . Ab initio potential energy and dipole moment surfaces are generated for this purpose. The calculated ro-vibronic transition intensities and cross sections are compared with the available experimental and theoretical data.

  7. Energy

    International Nuclear Information System (INIS)

    Meister, F.; Ott, F.

    2002-01-01

    This chapter gives an overview of the current energy economy in Austria. The Austrian political aims of sustainable development and climate protection imply a reorientation of the Austrian energy policy as a whole. Energy consumption trends (1993-1998), final energy consumption by energy carrier (indexed data 1993-1999), comparative analysis of useful energy demand (1993 and 1999) and final energy consumption of renewable energy sources by sector (1996-1999) in Austria are given. The necessary measures to be taken in order to reduce the energy demand and increased the use of renewable energy are briefly mentioned. Figs. 5. (nevyjel)

  8. Energy

    International Nuclear Information System (INIS)

    Meister, F.

    2001-01-01

    This chapter of the environmental control report deals with the environmental impact of energy production, energy conversion, atomic energy and renewable energy. The development of the energy consumption in Austria for the years 1993 to 1999 is given for the different energy types. The development of the use of renewable energy sources in Austria is given, different domestic heat-systems are compared, life cycles and environmental balance are outlined. (a.n.)

  9. The merits of cell kinetic parameters for the assessment of intrinsic cellular radiosensitivity to photon and high linear energy transfer neutron irradiation

    International Nuclear Information System (INIS)

    Theron, Therina; Slabbert, Jacobus; Serafin, Antonio; Boehm, Lothar

    1997-01-01

    Purpose: Differences in tumor response and intrinsic cellular radiosensitivity make the selection of patients for specific radiation modalities very difficult. The reasons for these differences are still unclear, but are thought to be due to genomic and cellular characteristics. Because radiosensitivities vary between cell cycle stages and because S phase cells are very radioresistant, cell cycle kinetic parameters could be a candidate for predicting intrinsic radiosensitivity. Methods and Materials: A panel of 15 tumor cell lines was analyzed for S phase content and potential doubling times (T pot ), and the influence of these parameters on the intrinsic radiosensitivity to 60 Coγ- and p(66)/Be neutron irradiation was assessed. Results: S phase content and T pot show a statistically significant correlation with the mean inactivation dose for photons. The correlation between cell kinetic parameters and the mean inactivation dose for neutrons showed the same trend as photon sensitivity but this was not found to be statistically significant. Conclusions: S phase content and T pot were identified as suitable criteria for predicting photon sensitivity. It is suggested that cell kinetic parameters could play a role in identifying neutron sensitive tumors if both tumor and normal cells are analyzed

  10. Theoretical Kinetics Analysis for $\\dot{H}$ Atom Addition to 1,3-Butadiene and Related Reactions on the $\\dot{C}$4H7 Potential Energy Surface

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yang [National Univ. of Ireland, Galway (Ireland). Combustion Chemistry Centre; Klippenstein, Stephen J. [Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division; Zhou, Chong-Wen [Beihang Univ., Beihang (China). School of Energy and Power Engineering; Curran, Henry J. [National Univ. of Ireland, Galway (Ireland). Combustion Chemistry Centre

    2017-09-29

    The oxidation chemistry of the simplest conjugated hydrocarbon, 1,3-butadiene, can provide a first step in understanding the role of poly-unsaturated hydrocarbons in combustion and, in particular, an understanding of their contribution towards soot formation. Based on our previous work on propene and the butene isomers (1-, 2- and isobutene), it was found that the reaction kinetics of H-atom addition to the C=C double bond plays a significant role in fuel consumption kinetics and influences the predictions of high-temperature ignition delay times, product species concentrations and flame speed measurements. In this study, the rate constants and thermodynamic properties for $\\dot{H}$-atom addition to 1,3-butadiene and related reactions on the $\\dot{C}$4H7 potential energy surface have been calculated using two different series of quantum chemical methods and two different kinetic codes. Excellent agreement is obtained between the two different kinetics codes. The calculated results including zero point energies, single point energies, rate constants, barrier heights and thermochemistry are systematically compared among the two quantum chemical methods. 1-methylallyl ($\\dot{C}$4H71-3) and 3-buten-1- yl ($\\dot{C}$4H71-4) radicals and C2H4 + $\\dot{C}$2H3 are found to be the most important channels and reactivity promoting products, respectively. We calculated that terminal addition is dominant (> 80%) compared to internal $\\dot{H}$-atom addition at all temperatures in the range 298 – 2000 K. However, this dominance decreases with increasing temperature. The calculated rate constants for the bimolecular reaction C4H6 + $\\dot{H}$ → products and C2H4 + $\\dot{C}$2H3 → products are in excellent agreement with both experimental and theoretical results from the literature. For selected C4 species the

  11. Grazing incidence diffraction : A review

    Energy Technology Data Exchange (ETDEWEB)

    Gilles, B. [LTPCM, ENSEEG. St. Martin d`Heres. (France)

    1996-09-01

    Different Grazing Incidence Diffraction (GID) methods for the analysis of thin films and multilayer structures are reviewed in three sections: the reflectivity is developed in the first one, which includes the non-specular diffuse scattering. The second one is devoted to the extremely asymmetric Bragg diffraction and the third one to the in-plane Bragg diffraction. Analytical formulations of the scattered intensities are developed for each geometry, in the framework of the kinetical analysis as well as the dynamical theory. Experimental examples are given to illustrate the quantitative possibility of the GID techniques.

  12. Double-differential beryllium neutron cross sections at incident neutron energies of 5. 9, 10. 1, and 14. 2 MeV. [5. 9 to 14. 2 MeV, differential cross sections, ENDF/B-IV

    Energy Technology Data Exchange (ETDEWEB)

    Drake, D.M.; Auchampaugh, G.F.; Arthur, E.D.; Ragan, C.E.; Young, P.G.

    1976-08-01

    Beryllium neutron-production cross sections were measured using the time-of-flight technique at incident neutron energies of 5.9, 10.1, and 14.2 MeV, and at laboratory angles of 25, 27.5, 30, 35, 45, 60, 80, 100, 110, 125, and 145/sup 0/. The differential elastic and inelastic cross sections are presented. Inelastic is defined here as those reactions that proceed through the states at 1.69-, 2.43-, 2.8-, and 3.06-MeV excitation energy in /sup 9/Be. Comparison of emission energy spectra with calculations using the ENDF/B-IV beryllium cross sections shows that the ENDF/B cross sections strongly overemphasize the low lying states in /sup 9/Be.

  13. Energy

    International Nuclear Information System (INIS)

    Bobin, J.L.

    1996-01-01

    Object of sciences and technologies, energy plays a major part in economics and relations between nations. Jean-Louis Bobin, physicist, analyses the relations between man and energy and wonders about fears that delivers nowadays technologies bound to nuclear energy and about the fear of a possible shortage of energy resources. (N.C.). 17 refs., 14 figs., 2 tabs

  14. Fission-fragment total kinetic energy and mass yields for neutron-induced fission of 235U and 238U with En =200 keV - 30 MeV

    Science.gov (United States)

    Duke, D. L.; Tovesson, F.; Brys, T.; Geppert-Kleinrath, V.; Hambsch, F.-J.; Laptev, A.; Meharchand, R.; Manning, B.; Mayorov, D.; Meierbachtol, K.; Mosby, S.; Perdue, B.; Richman, D.; Shields, D.; Vidali, M.

    2017-09-01

    The average Total Kinetic Energy (TKE) release and fission-fragment yields in neutron-induced fission of 235U and 238U was measured using a Frisch-gridded ionization chamber. These observables are important nuclear data quantites that are relevant to applications and for informing the next generation of fission models. The measurements were performed a the Los Alamos Neutron Science Center and cover En = 200 keV - 30 MeV. The double-energy (2E) method was used to determine the fission-fragment yields and two methods of correcting for prompt-neutron emission were explored. The results of this study are correlated mass and TKE data.

  15. Fission-fragment total kinetic energy and mass yields for neutron-induced fission of 235U and 238U with En =200 keV – 30 MeV

    Directory of Open Access Journals (Sweden)

    Duke D.L.

    2017-01-01

    Full Text Available The average Total Kinetic Energy (TKE release and fission-fragment yields in neutron-induced fission of 235U and 238U was measured using a Frisch-gridded ionization chamber. These observables are important nuclear data quantites that are relevant to applications and for informing the next generation of fission models. The measurements were performed a the Los Alamos Neutron Science Center and cover En = 200 keV – 30 MeV. The double-energy (2E method was used to determine the fission-fragment yields and two methods of correcting for prompt-neutron emission were explored. The results of this study are correlated mass and TKE data.

  16. Contaminated Mexican steel incident

    International Nuclear Information System (INIS)

    1985-01-01

    This report documents the circumstances contributing to the inadvertent melting of cobalt 60 (Co-60) contaminated scrap metal in two Mexican steel foundries and the subsequent distribution of contaminated steel products into the United States. The report addresses mainly those actions taken by US Federal and state agencies to protect the US population from radiation risks associated with the incident. Mexico had much more serious radiation exposure and contamination problems to manage. The United States Government maintained a standing offer to provide technical and medical assistance to the Mexican Government. The report covers the tracing of the source to its origin, response actions to recover radioactive steel in the United States, and return of the contaminated materials to Mexico. The incident resulted in significant radiation exposures within Mexico, but no known significant exposure within the United States. Response to the incident required the combined efforts of the Nuclear Regulatory Commission (NRC), Department of Energy, Department of Transportation, Department of State, and US Customs Service (Department of Treasury) personnel at the Federal level and representatives of all 50 State Radiation Control Programs and, in some instances, local and county government personnel. The response also required a diplomatic interface with the Mexican Government and cooperation of numerous commercial establishments and members of the general public. The report describes the factual information associated with the event and may serve as information for subsequent recommendations and actions by the NRC. 8 figures

  17. Kinetic Study of Calcination of Jakura Limestone Using Power Rate ...

    African Journals Online (AJOL)

    investigation into kinetics of calcinations of some large commercial deposits of limestone in Nigeria. The study is aimed at finding kinetic parameters for the purpose of energy saving, lime kiln design, modeling and simulation of lime kiln. In this study, kinetic of Jakura limestone calcination process using power rate law has ...

  18. Energy storage

    International Nuclear Information System (INIS)

    2012-01-01

    After having outlined the importance of energy storage in the present context, this document outlines that it is an answer to economic, environmental and technological issues. It proposes a brief overview of the various techniques of energy storage: under the form of chemical energy (hydrocarbons, biomass, hydrogen production), thermal energy (sensitive or latent heat storage), mechanical energy (potential energy by hydraulic or compressed air storage, kinetic energy with flywheels), electrochemical energy (in batteries), electric energy (super-capacitors, superconductor magnetic energy storage). Perspectives are briefly evoked

  19. Molecular dynamics study of the interactions of incident N or Ti atoms with the TiN(001) surface

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Zhenhai [National Key Laboratory for Precision Hot Processing of Metals & School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); School of Mechatronics Engineering, Harbin Institute of Technology, Harbin 150001 (China); Centre for Precision Manufacturing, Department of Design, Manufacture and Engineering Management, The University of Strathclyde, Glasgow G1 1XJ (United Kingdom); Zeng, Quanren [Centre for Precision Manufacturing, Department of Design, Manufacture and Engineering Management, The University of Strathclyde, Glasgow G1 1XJ (United Kingdom); Yuan, Lin [National Key Laboratory for Precision Hot Processing of Metals & School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Qin, Yi [Centre for Precision Manufacturing, Department of Design, Manufacture and Engineering Management, The University of Strathclyde, Glasgow G1 1XJ (United Kingdom); Chen, Mingjun [School of Mechatronics Engineering, Harbin Institute of Technology, Harbin 150001 (China); Shan, Debin, E-mail: d.b.shan@gmail.com [National Key Laboratory for Precision Hot Processing of Metals & School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China)

    2016-01-01

    Graphical abstract: - Highlights: • Interactions of incident N or Ti atoms with TiN(001) surface are studied by CMD. • The impact position of incident N on the surface determines the interaction modes. • Adsorption could occur due to the atomic exchange process. • Resputtering and reflection may simultaneously occur. • The initial sticking coefficient of N on TiN(001) is much smaller than that of Ti. - Abstract: The interaction processes between incident N or Ti atoms and the TiN(001) surface are simulated by classical molecular dynamics based on the second nearest-neighbor modified embedded-atom method potentials. The simulations are carried out for substrate temperatures between 300 and 700 K and kinetic energies of the incident atoms within the range of 0.5–10 eV. When N atoms impact against the surface, adsorption, resputtering and reflection of particles are observed; several unique atomic mechanisms are identified to account for these interactions, in which the adsorption could occur due to the atomic exchange process while the resputtering and reflection may simultaneously occur. The impact position of incident N atoms on the surface plays an important role in determining the interaction modes. Their occurrence probabilities are dependent on the kinetic energy of incident N atoms but independent on the substrate temperature. When Ti atoms are the incident particles, adsorption is the predominant interaction mode between particles and the surface. This results in the much smaller initial sticking coefficient of N atoms on the TiN(001) surface compared with that of Ti atoms. Stoichiometric TiN is promoted by N/Ti flux ratios larger than one.

  20. Incidência de ascite em diferentes categorias genéticas de frangos de corte alimentados com rações de alto nível energético Incidence of ascites on different genetic categories of broilers fed with high-energy diet

    Directory of Open Access Journals (Sweden)

    Manoel Garcia Neto

    2003-06-01

    Full Text Available O objetivo deste trabalho foi verificar a incidência de ascite em avós, matrizes e frangos de corte, de uma mesma linhagem comercial, alimentados com ração de alto nível energético, de um dia a 39 dias de idade. Todas as aves foram criadas como frangos de corte, recebendo ração ad libitum com 3.050 kcal/EM; foram utilizadas aves da linha fêmea e linha macho e frangos de corte. Um total de 2.700 aves foram usadas, alojadas ao acaso em um galpão experimental de 8x76 m, utilizando-se 27 boxes de 3x3,5 m, com 100 aves por divisão, sendo três repetições por tratamento, em esquema fatorial. A incidência de ascite não dependeu da categoria genética das aves.The objective of this work was to verify the incidence of ascites on grand parents, breeders and commercial broilers from the same genetic strain of birds, fed with high energy level ration, from the first day of age to 39 days old. All birds were grown as commercial broilers receiving a ration ad libitum with 3,050 kcal/ME; birds from female line, male line and commercial broilers were tested. A total of 2,700 birds were housed at random in a experimental facility of 8x76 m, with 27 compartments of 3x3.5 m each and 100 birds per division. A factorial design was used with three replications per treatment. The incidence of ascites was not dependent on genetic category.

  1. Incidence of low- and high-energy fractures in persons with and without HIV-infection: a Danish population-based cohort study

    DEFF Research Database (Denmark)

    Hansen, Ann-Brit E; Gerstoft, Jan; Kronborg, Gitte

    2012-01-01

    OBJECTIVE:: To compare fracture risk in persons with and without HIV-infection and to examine the influence of HAART initiation on risk of fracture. DESIGN:: Population-based nationwide cohort study using Danish registries. METHODS:: Outcome measures were time to first fracture at any site, time....../HCV-coinfected patients had increased risk of low-energy fracture, IRR of 1.6 (95% CI; 1.4-1.8) and 3.8 (95% CI; 3.0-4.9). However, only HIV/HCV-coinfected patients had increased risk of high-energy fracture, IRR of 2.4 (95 %CI; 2.0-2.9). Among HIV-monoinfected patients the risk of low-energy fracture was only...

  2. Effects of energy-dense nutrient-poor snacks on the incidence of metabolic syndrome: a prospective approach in Tehran Lipid and Glucose Study.

    Science.gov (United States)

    Mirmiran, Parvin; Bahadoran, Zahra; Delshad, Hossein; Azizi, Fereidoun

    2014-05-01

    Increased consumption of energy-dense, nutrient-poor snacks is one of the major, growing concerns in relation to the alarming trend of overweight, obesity, and metabolic disorders worldwide. The aim of this study was to investigate whether consumption of energy-dense snacks could affect the occurrence of metabolic syndrome after 3 y of follow-up in adults. This longitudinal study was conducted within the framework of the Tehran Lipid and Glucose Study between 2006 and 2008 and 2009 and 2011, on 1466 adults, ages 19 to 70 y. The usual intake of participants was measured using a validated semiquantitative food frequency questionnaire at baseline. Biochemical and anthropometric measurements were assessed at baseline and 3 y later. Multiple logistic regression models were used to estimate the occurrence of metabolic syndrome (MetS) in each quartile of energy-dense snacks. Participants in the highest quartile of energy-dense snack consumption were significantly younger (33.8 versus 43.1 y; P consumption of salty snacks increased more than 50% (OR, 1.56; 95% CI, 1.01-2.40). Consumption of soft drinks had a borderline effect on the risk for MetS. More than 361 kcal/d from total energy-dense snacks independently increased the occurrence of MetS in the fourth compared the first quartile category (OR, 1.53; 95% CI, 1.03-2.29). The findings of this study demonstrated that higher consumption of energy-dense snacks could be a dietary risk factor for development of MetS. Copyright © 2014 Elsevier Inc. All rights reserved.

  3. Dissociation kinetics of excited ions: PEPICO measurements of Os3(CO)12 — The 7-35 eV single ionization binding energy region

    Science.gov (United States)

    Schalk, Oliver; Josefsson, Ida; Geng, Ting; Richter, Robert; Sa'adeh, Hanan; Thomas, Richard D.; Mucke, Melanie

    2018-02-01

    In this article, we study the photoinduced dissociation pathways of a metallocarbonyl, Os3(CO)12, in particular the consecutive loss of CO groups. To do so, we performed photoelectron-photoion coincidence (PEPICO) measurements in the single ionization binding energy region from 7 to 35 eV using 45-eV photons. Zero-energy ion appearance energies for the dissociation steps were extracted by modeling the PEPICO data using the statistical adiabatic channel model. Upon ionization to the excited ionic states above 13 eV binding energy, non-statistical behavior was observed and assigned to prompt CO loss. Double ionization was found to be dominated by the knockout process with an onset of 20.9 ± 0.4 eV. The oscillator strength is significantly larger for energies above 26.6 ± 0.4 eV, corresponding to one electron being ejected from the Os3 center and one from the CO ligands. The cross section for double ionization was found to increase linearly up to 35 eV ionization energy, at which 40% of the generated ions are doubly charged.

  4. Energies

    International Nuclear Information System (INIS)

    2003-01-01

    In the framework of the National Debate on the energies in a context of a sustainable development some associations for the environment organized a debate on the nuclear interest facing the renewable energies. The first part presents the nuclear energy as a possible solution to fight against the greenhouse effect and the associated problem of the wastes management. The second part gives information on the solar energy and the possibilities of heat and electric power production. A presentation of the FEE (French wind power association) on the situation and the development of the wind power in France, is also provided. (A.L.B.)

  5. Reaction kinetics aspect of U3O8 kernel with gas H2 on the characteristics of activation energy, reaction rate constant and O/U ratio of UO2 kernel

    International Nuclear Information System (INIS)

    Damunir

    2007-01-01

    The reaction kinetics aspect of U 3 O 8 kernel with gas H 2 on the characteristics of activation energy, reaction rate constant and O/U ratio of UO 2 kernel had been studied. U 3 O 8 kernel was reacted with gas H 2 in a reduction furnace at varied reaction time and temperature. The reaction temperature was varied at 600, 700, 750 and 850 °C with a pressure of 50 mmHg for 3 hours in gas N 2 atmosphere. The reation time was varied at 1, 2, 3 and 4 hours at a temperature of 750 °C using similar conditions. The reaction product was UO 2 kernel. The reaction kinetic aspect between U 3 O 8 and gas H 2 comprised the minimum activation energy (ΔE), the reaction rate constant and the O/U ratio of UO 2 kernel. The minimum activation energy was determined from a straight line slope of equation ln [{D b . R o {(1 - (1 - X b ) ⅓ } / (b.t.Cg)] = -3.9406 x 10 3 / T + 4.044. By multiplying with the straight line slope -3.9406 x 10 3 , the ideal gas constant (R) 1.985 cal/mol and the molarity difference of reaction coefficient 2, a minimum activation energy of 15.644 kcal/mol was obtained. The reaction rate constant was determined from first-order chemical reaction control and Arrhenius equation. The O/U ratio of UO 2 kernel was obtained using gravimetric method. The analysis result of reaction rate constant with chemical reaction control equation yielded reaction rate constants of 0.745 - 1.671 s -1 and the Arrhenius equation at temperatures of 650 - 850 °C yielded reaction rate constants of 0.637 - 2.914 s -1 . The O/U ratios of UO 2 kernel at the respective reaction rate constants were 2.013 - 2.014 and the O/U ratios at reaction time 1 - 4 hours were 2.04 - 2.011. The experiment results indicated that the minimum activation energy influenced the rate constant of first-order reaction and the O/U ratio of UO 2 kernel. The optimum condition was obtained at reaction rate constant of 1.43 s -1 , O/U ratio of UO 2 kernel of 2.01 at temperature of 750 °C and reaction time of 3

  6. Methods of nonlinear kinetics

    OpenAIRE

    Gorban, A. N.; Karlin, I. V.

    2003-01-01

    Nonlinear kinetic equations are reviewed for a wide audience of specialists and postgraduate students in physics, mathematical physics, material science, chemical engineering and interdisciplinary research. Contents: The Boltzmann equation, Phenomenology and Quasi-chemical representation of the Boltzmann equation, Kinetic models, Discrete velocity models, Direct simulation, Lattice Gas and Lattice Boltzmann models, Minimal Boltzmann models for flows at low Knudsen number, Other kinetic equati...

  7. Interim report of the DOE [Department of Energy] Type B Investigation Group: Appendix C, Oral statements about the RSI [Radiation Sterilizers, Inc.] incident

    International Nuclear Information System (INIS)

    Hultgren, R.O.

    1990-07-01

    Sometime between April 28, 1988, and June 5, 1988, a 22-inch long by 2.625-inch diameter doubly encapsulated cesium-137 irradiation source began leaking in the RSI-Decatur, Georgia, irradiation facility. By November 1988 when the source was isolated, between 7 and 8 curies (0.4 grams) leaked. This source was one of 1576 produced at Hanford to isolate the highly radioactive elements of wastes stored in single-walled tanks there. The capsule was designed for long term storage in a benign controlled pool environment on the Hanford reservation. An investigation was conducted to evaluate the cause of the incident, the management and administrative matters including leasing and licensing, the capsule design and manufacture, and the capsule qualification process. This Appendix presents transcripts of oral testimony taken during this investigation and is include as an integral part of the factual data upon which the Findings of this report are based. The transcriptions in every case were made available to the individuals involved for correction of factual misstatements and to be cleaned of verbal idiosyncrasies that detract from the meaning of the text

  8. Nuclear data evaluations of neutron and proton incidence on Zr, Nb, and W for energy up to 200 MeV

    International Nuclear Information System (INIS)

    Kunieda, Satoshi; Shigyo, Nobuhiro; Ishibashi, Kenji

    2003-01-01

    Neutron and proton nuclear data were evaluated on Zr, Nb, and W for energy up to 200 MeV. To execute optical model calculations, spherical optical potentials were developed to reproduce experimental data for many elements. The GNASH nuclear model code was used to evaluate light-particle production cross sections. For neutron emission, giant resonance correction came to be performed in the code system. (author)

  9. Study of the incident pion deflection in passing through atomic nucleus

    International Nuclear Information System (INIS)

    Strugalski, Z.; Pawlak, T.; Pluta, J.

    1982-01-01

    Pion-xenon nucleus collision events at 3.5 GeV/c momentum are studied in which the incident pion is deflected only, without particle production; the deflection is accompanied by emission of nucleons. The multiplicity of the protons emitted is a measure of the nuclear matter layer thickness passed by the pion. It can be concluded that: a) a definite simple relation exists between the pion deflection angle and the thickness of the nuclear matter layer traversed by this pion; b) the deflection angle of the incident pion increases in a definite manner with increasing the thickness of the nuclear matter layer traversed by this pion; c) the average kinetic energy, average longitudinal momentum and average transverse momentum of the protons emitted do not depend on the pion deflection angle

  10. Electron-emission processes in highly charged Ar and Xe ions impinging on highly ordered pyrolytic graphite at energies just above the kinetic threshold

    NARCIS (Netherlands)

    Bodewits, E.; Hoekstra, R.; Dobes, K.; Aumayr, F.

    2014-01-01

    At keV energies, many electronic processes contribute to the emission of secondary electrons in the interaction of highly charged ions on surfaces. To unravel contributions resulting from isolated hollow atoms in front of the surface or embedded in the electron gas of the target, heavy highly

  11. Activation-energy for the reaction h+oh--]eaq- - kinetic determination of the enthalpy and entropy of solvation of the hydrated electron

    DEFF Research Database (Denmark)

    Hickle, B.; Sehested, Knud

    1985-01-01

    The reaction between atomic hydrogen and hydroxide ion in aqueous solutions H + OH- - eaq- + H20 has been studied by pulse radiolysis. The rate constant was measured at pH 11.7 and 12 by following the growth of the hydrated electron absorption at 600 nm. The activation energy of the reaction has ...

  12. Low temperature hot air drying of potato cubes subjected to osmotic dehydration and intermittent microwave: drying kinetics, energy consumption and product quality indexes

    Science.gov (United States)

    Dehghannya, Jalal; Bozorghi, Somayyeh; Heshmati, Maryam Khakbaz

    2017-10-01

    Hot-air drying is a slow energy-extensive process. Use of intermittent microwave (IM) in hot-air (HA) drying of food products is characterized with advantages including reduced process time, energy saving, and improved final quality. In this study, the effect of IM-HA drying following an osmotic dehydration (OD) pretreatment was analyzed on qualitative and quantitative properties of the output (i.e. effective moisture diffusion coefficient (Deff), shrinkage, bulk density, rehydration and energy consumption). Temperature and airflow velocity were fixed at 40°C and 1 m/s, respectively. The process variables included sucrose solution concentration at five levels (0 or control, 10, 30, 50 and 70 w/w%), microwave output power at four levels (0 or control, 360, 600 and 900 W), and pulse ratio at four levels (1, 2, 3 and 4). Use of osmotic dehydration in combination with IM-HA drying reduced the drying time by up to about 54%. Increasing the osmotic solution concentration to 30% and using higher pulse ratios increased the Deff. The lowest shrinkage and bulk density as well as the highest rehydration belonged to the 900 W microwave power and pulse ratio of 4. The lowest energy consumption was observed when using the 900 W power level, showing 63.27% less consumption than the HA drying method.

  13. Low temperature hot air drying of potato cubes subjected to osmotic dehydration and intermittent microwave: drying kinetics, energy consumption and product quality indexes

    Science.gov (United States)

    Dehghannya, Jalal; Bozorghi, Somayyeh; Heshmati, Maryam Khakbaz

    2018-04-01

    Hot-air drying is a slow energy-extensive process. Use of intermittent microwave (IM) in hot-air (HA) drying of food products is characterized with advantages including reduced process time, energy saving, and improved final quality. In this study, the effect of IM-HA drying following an osmotic dehydration (OD) pretreatment was analyzed on qualitative and quantitative properties of the output (i.e. effective moisture diffusion coefficient (Deff), shrinkage, bulk density, rehydration and energy consumption). Temperature and airflow velocity were fixed at 40°C and 1 m/s, respectively. The process variables included sucrose solution concentration at five levels (0 or control, 10, 30, 50 and 70 w/w%), microwave output power at four levels (0 or control, 360, 600 and 900 W), and pulse ratio at four levels (1, 2, 3 and 4). Use of osmotic dehydration in combination with IM-HA drying reduced the drying time by up to about 54%. Increasing the osmotic solution concentration to 30% and using higher pulse ratios increased the Deff. The lowest shrinkage and bulk density as well as the highest rehydration belonged to the 900 W microwave power and pulse ratio of 4. The lowest energy consumption was observed when using the 900 W power level, showing 63.27% less consumption than the HA drying method.

  14. Binding energy and preferred adsorption sites of CO on gold and silver-gold cluster cations: adsorption kinetics and quantum chemical calculations.

    Science.gov (United States)

    Neumaier, Marco; Weigend, Florian; Hampe, Oliver; Kappes, Manfred M

    2008-01-01

    We revisit the reactivity of trapped pure gold (Au(n)+, n cluster cations (Ag(m)Au(n)+, m + n adsorption sites, associated vibrational frequencies) of CO to the noble metal as a function of cluster size and composition. Starting from results for pure gold cluster cations for which an overall decrease of CO binding energy with increasing cluster size was experimentally observed--from about 1.09 +/- 0.1 eV (for n = 6) to below 0.65 +/- 0.1 eV (for n > 26) we demonstrate that metal--CO bond energies correlate with the total electron density and with the energy of the lowest unoccupied molecular orbital (LUMO) on the bare metal cluster cation as obtained by density functional theory (DFT) computations. This is a consequence of the predominantly sigma-donating character of the CO-M bond. Further support for this concept is found by contrasting the predictions of binding energies to the experimental results for small alloy cluster cations (Ag(m)Au(n)+, 4 adsorption sites and pre-screen favorable isomers.

  15. Classical Antiferromagnetism in Kinetically Frustrated Electronic Models

    Science.gov (United States)

    Sposetti, C. N.; Bravo, B.; Trumper, A. E.; Gazza, C. J.; Manuel, L. O.

    2014-05-01

    We study, by means of the density matrix renormalization group, the infinite U Hubbard model—with one hole doped away from half filling—in triangular and square lattices with frustrated hoppings, which invalidate Nagaoka's theorem. We find that these kinetically frustrated models have antiferromagnetic ground states with classical local magnetization in the thermodynamic limit. We identify the mechanism of this kinetic antiferromagnetism with the release of the kinetic energy frustration, as the hole moves in the established antiferromagnetic background. This release can occur in two different ways: by a nontrivial spin Berry phase acquired by the hole, or by the effective vanishing of the hopping amplitude along the frustrating loops.

  16. Effective delivery of sonication energy to fast settling and agglomerating nanomaterial suspensions for cellular studies: Implications for stability, particle kinetics, dosimetry and toxicity.

    Science.gov (United States)

    Cohen, Joel M; Beltran-Huarac, Juan; Pyrgiotakis, Georgios; Demokritou, Philip

    2018-04-01

    Typical in vitro assays used for high throughput toxicological screening and measuring nano-bio interactions are conducted by pipetting suspensions of engineered nanomaterials (ENMs) dispersed in nutrient-rich culture media directly onto cells. In order to achieve fairly monodisperse and stable suspensions of small agglomerates, ultrasonic energy is usually applied to break apart large agglomerates that can form upon suspension in liquid. Lack of standardized protocols and methods for delivering sonication energy can introduce variability in the ENM suspension properties ( e.g . agglomerate size, polydispersity, suspension stability over time), and holds significant implications for in vitro dosimetry, toxicity, and other nano-bio interactions. Careful assessment of particle transformations during dispersion preparation and sonication is therefore critical for accurate interpretation of in vitro toxicity studies. In this short communication, the difficulties of preparing stable suspensions of rapidly settling ENMs are presented. Furthermore, methods to optimize the delivery of the critical sonication energy required to break large agglomerates and prepare stable, fairly monodispersed suspensions of fast settling ENMs are presented. A methodology for the efficient delivery of sonication energy in a discrete manner is presented and validated using various rapidly agglomerating and settling ENMs. The implications of continuous vs. discrete sonication on average hydrodynamic diameter, and polydispersity was also assessed for both fast and slow settling ENMs. For the rapidly agglomerating and settling ENMs (Ag15%/SiO 2 , Ag and CeO 2 ), the proposed discrete sonication achieved a significant reduction in the agglomerate diameter and polydispersity. In contrast, the relatively slow agglomerating and settling Fe 2 O 3 suspension did not exhibit statistically significant differences in average hydrodynamic diameter or polydispersity between the continuous and discrete

  17. Single-electron capture for 2-8 keV incident energy and direct scattering at 6 keV in He[sup 2+]-He collisions

    Energy Technology Data Exchange (ETDEWEB)

    Bordenave-Montesquieu, D.; Dagnac, R. (Toulouse-3 Univ., 31 (France). Centre de Physique Atomique)

    1992-06-14

    We studied the single-electron capture as well as the direct processes occurring when a He[sup 2+] ion is scattered by a He target. Doubly differential cross sections were measured for single-electron capture with a collision energy ranging from 2 to 8 keV and a scattering angle varying from 10' to 3[sup o]30' (laboratory frame). Single-electron capture into excited states of He[sup +] was found to be the dominant process, confirming a previous experimental study. Elastic scattering and ionization differential cross sections were measured for E = 6 keV. (Author).

  18. Potential and Kinetic Electron Emissions from HOPG Surface Irradiated by Highly Charged Xenon and Neon Ions

    International Nuclear Information System (INIS)

    Yu-Yu, Wang; Yong-Tao, Zhao; Jian-Rong, Sun; De-Hui, Li; Jin-Yu, Li; Ping-Zhi, Wang; Guo-Qing, Xiao; Abdul, Qayyum

    2011-01-01

    Highly charged 129 Xe q+ (q = 10−30) and 40 Ne q+ (q = 4−8) ion-induced secondary electron emissions on the surface of highly oriented pyrolytic graphite (HOPG) are reported. The total secondary electron yield is measured as a function of the potential energy of incident ions. The experimental data are used to separate contributions of kinetic and potential electron yields. Our results show that about 4.5% and 13.2% of ion's potential energies are consumed in potential electron emission due to different Xe q+ -HOPG and Ne q+ -HOPG combinations. A simple formula is introduced to estimate the fraction of ion's potential energy for potential electron emission. (atomic and molecular physics)

  19. A kinetic model for estimating the boron activation energies in the FeB and Fe{sub 2}B layers during the gas-boriding of Armco iron: Effect of boride incubation times

    Energy Technology Data Exchange (ETDEWEB)

    Keddam, M. [Laboratoire de Technologie des Matériaux, Département de Sciences des Matériaux, Faculté de Génie Mécanique et Génie des Procédés, USTHB, B.P N°32, 16111, El-Alia, Bab-Ezzouar, Algiers (Algeria); Kulka, M., E-mail: michal.kulka@put.poznan.pl [Poznan University of Technology, Institute of Materials Science and Engineering, Pl. M.Sklodowskiej-Curie 5, 60-965 Poznan (Poland); Makuch, N.; Pertek, A. [Poznan University of Technology, Institute of Materials Science and Engineering, Pl. M.Sklodowskiej-Curie 5, 60-965 Poznan (Poland); Małdziński, L. [Poznan University of Technology, Institute of Machines and Motor Vehicles, Piotrowo Street 3, 60-965 Poznan (Poland)

    2014-04-01

    Graphical abstract: - Highlights: • The mass balance equations were formulated for the FeB and Fe{sub 2}B layers grown on Fe Armco by gas-boriding. • The effect of boride incubation times was incorporated in the present model. • The boride incubation time was shorter for FeB phase. • The calculated boron activation energies in FeB and Fe{sub 2}B were respectively close to 78.03 and 120.65 kJ mol{sup −1}. • The lower activation energy in FeB phase was characteristic of gas-boriding. - Abstract: The present work deals with a simulation of the growth kinetics of boride layers grown on Armco iron substrate. The formed boride layers (FeB + Fe{sub 2}B) are obtained by the gas-boriding in the temperature range of 1073–1273 K during a time duration ranging from 80 to 240 min. The used approach solves the mass balance equations at the two growing fronts: (FeB/Fe{sub 2}B) and (Fe{sub 2}B/Fe) under certain assumptions. To consider the effect of the incubation times for the borides formation, the temperature-dependent function Φ(T) was incorporated in the model. The following input data: (the boriding temperature, the treatment time, the upper and lower values of boron concentrations in FeB and Fe{sub 2}B and the experimental parabolic growth constants) are needed to determine the boron activation energies in the FeB and Fe{sub 2}B layers. The obtained values of boron activation energies were then compared with the values available in the literature. Finally, a good agreement was obtained between the simulated values of boride layers thicknesses and the experimental ones in the temperature range of 1073–1273 K.

  20. A semi-exclusive study of heavy-residue production in the 40Ar+Ag reaction at 35 MeV/u incident energy

    International Nuclear Information System (INIS)

    Bizard, G.; Brou, R.

    1985-01-01

    Heavy residues created in the reaction Ar+Ag at 35 MeV/u have been detected at various forward angles. Their velocity spectra (quite different from the corresponding spectra measured at 27 MeV/u) show that these events result both from central and peripheral reactions and that the fusion component has dramatically decreased. Coincident light charged particles spectra have been obtained in a large solid angle forward hodoscope. The analysis of these spectra allows to differentiate peripheral and central collisions. The proton spectra are analysed in terms of emitting sources. There is no need for a participant zone in peripheral reactions. Instead protons are emitted either from the target-like or from the projectile-like fragments. However projectile sequential emission is not sufficient to explain all the high energy protons

  1. Study of mechanisms and kinetics of Sodium-CO2 interactions. Contribution to the evaluation of an energy conversion system with supercritical CO2 for sodium fast breeder reactors

    International Nuclear Information System (INIS)

    Gicquel, L.

    2010-01-01

    This PhD study consisted in studying reactive mechanisms and kinetics of sodium-CO 2 interactions, in the frame of the assessment of an energy conversion system with supercritical CO 2 for fast breeder reactors cooled by sodium. The approach was the following. First of all, the interactions between sodium and CO 2 have been brought to light by laboratory experiments associated with products analysis. They have enabled the establishment of a coherent mechanism, in agreement with literature data, and gave preliminary indications on the reaction kinetics. In order to estimate a more detailed reaction kinetics, we tried to approach the phenomenon that appears in the case of a leak in a sodium-CO 2 heat exchanger. Geometry of such heat exchangers is not fixed for the moment, even if the development of compact exchangers is foreseen. Then, free jets of CO 2 in liquid sodium have been modeled in order to obtain, by identification, kinetics parameters of the reaction. Those parameters, estimated with such a geometry, will remain valid with a much complex geometry, that will better represent the real exchanger. An experimental bench has been defined and built to realize those jets. The first laboratory experiments have concluded in the existence of different reactive mechanisms according to the temperature level. A threshold has been brought to light around 500 C. Below this one, reaction appears moderated, or even, slow, with a medium exothermicity, and appears after an induction period that depends on the temperature,and which duration could reach several hours. At contrary, above this threshold, it seems rapid and more exothermic. Below 500 C, sodium oxalate is produced, and then reacts with sodium in an exothermic way, following the reactions: CO 2 + Na →1/4 Na 2 C 2 O 4 + 1/4 CO + 1/4 Na 2 CO 3 (5) 4 Na + Na 2 C 2 O 4 → 3 Na 2 O + CO + C (6) Above 500 C, sodium carbonate is produced, and can then possibly react with sodium in an endothermic way, following the

  2. Validation of Neutron Calculation Codes and Models by means of benchmark cases in the frame of the Binational Commission of Nuclear Energy. Kinetic Parameters, Temperature Coefficients and Power Distribution

    International Nuclear Information System (INIS)

    Dos Santos, Adimir; Siqueira, Paulo de Tarso D.; Andrade e Silva, Graciete Simões; Grant, Carlos; Tarazaga, Ariel E.; Barberis, Claudia

    2013-01-01

    In year 2008 the Atomic Energy National Commission (CNEA) of Argentina, and the Brazilian Institute of Energetic and Nuclear Research (IPEN), under the frame of Nuclear Energy Argentine Brazilian Agreement (COBEN), among many others, included the project “Validation and Verification of Calculation Methods used for Research and Experimental Reactors . At this time, it was established that the validation was to be performed with models implemented in the deterministic codes HUEMUL and PUMA (cell and reactor codes) developed by CNEA and those ones implemented in MCNP by CNEA and IPEN. The necessary data for these validations would correspond to theoretical-experimental reference cases in the research reactor IPEN/MB-01 located in São Paulo, Brazil. The staff of the group Reactor and Nuclear Power Studies (SERC) of CNEA, from the argentine side, performed calculations with deterministic models (HUEMUL-PUMA) and probabilistic methods (MCNP) modeling a great number of physical situations of de reactor, which previously have been studied and modeled by members of the Center of Nuclear Engineering of the IPEN, whose results were extensively provided to CNEA. In this paper results of comparison of calculated and experimental results for temperature coefficients, kinetic parameters and fission rates spatial distributions are shown. (author)

  3. Metabolic intervention in surgical patients. An assessment of the effect of somatostatin, ranitidine, naloxone, diclophenac, dipyridamole, or salbutamol infusion on energy and protein kinetics in surgical patients using stable and radioisotopes

    International Nuclear Information System (INIS)

    Shaw, J.H.; Wolfe, R.R.

    1988-01-01

    We have assessed the effect of a variety of forms of metabolic intervention on both energy and protein metabolism in 44 severely ill surgical patients. The patients were studied either in the basal state or while receiving total parenteral nutrition (TPN), and the metabolic effects were assessed using the primed-constant infusion of a combination of stable isotopes and radioisotopes. Somatostatin infusion, either in the basal state or in the TPN, did not change glucose kinetics, but there was a significant decrease in the rate of net protein catabolism (NPC). In the basal studies the rate of NPC decreased from 3.4 +/- 0.7 g/kg/d to 2.9 +/- 0.7 g/kg/d (p less than 0.002), while in the TPN patients the corresponding values were 1.48 +/- 0.61 g/kg/d and 1.10 +/- 0.50 g/kg/d, respectively (p less than 0.005). Histamine type 2 blockade with ranitidine did not significantly alter glucose kinetics, but in both the TPN patients and in the basal state ranitidine was associated with a significant decrease in the rate of NPC. In the basal state rate of NPC was 2.44 +/- 0.53 g/kg/d and during ranitidine infusion the value was 2.08 +/- 0.42 g/kg/d (p less than 0.04). Naloxone infusion did not alter glucose kinetics, but there was a significant decrease in the rate of NPC from a basal value of 2.6 +/- 0.6 g/kg/d to 2.3 +/- 0.5 g/kg/d (p less than 0.04). The infusion of the prostaglandin antagonists diclofenac or dipyridamole resulted in increases in the plasma insulin level, and as a result glucose turnover decreased in both groups. In the diclofenac group the rate of glucose turnover decreased from 14.4 +/- 1.7 mumol/kg/min to 12.6 +/- 1.3 mumol/kg/min (p less than 0.02). Neither prostaglandin antagonist resulted in any significant change in the rate of NPC

  4. Metabolic intervention in surgical patients. An assessment of the effect of somatostatin, ranitidine, naloxone, diclophenac, dipyridamole, or salbutamol infusion on energy and protein kinetics in surgical patients using stable and radioisotopes

    Energy Technology Data Exchange (ETDEWEB)

    Shaw, J.H.; Wolfe, R.R.

    1988-03-01

    We have assessed the effect of a variety of forms of metabolic intervention on both energy and protein metabolism in 44 severely ill surgical patients. The patients were studied either in the basal state or while receiving total parenteral nutrition (TPN), and the metabolic effects were assessed using the primed-constant infusion of a combination of stable isotopes and radioisotopes. Somatostatin infusion, either in the basal state or in the TPN, did not change glucose kinetics, but there was a significant decrease in the rate of net protein catabolism (NPC). In the basal studies the rate of NPC decreased from 3.4 +/- 0.7 g/kg/d to 2.9 +/- 0.7 g/kg/d (p less than 0.002), while in the TPN patients the corresponding values were 1.48 +/- 0.61 g/kg/d and 1.10 +/- 0.50 g/kg/d, respectively (p less than 0.005). Histamine type 2 blockade with ranitidine did not significantly alter glucose kinetics, but in both the TPN patients and in the basal state ranitidine was associated with a significant decrease in the rate of NPC. In the basal state rate of NPC was 2.44 +/- 0.53 g/kg/d and during ranitidine infusion the value was 2.08 +/- 0.42 g/kg/d (p less than 0.04). Naloxone infusion did not alter glucose kinetics, but there was a significant decrease in the rate of NPC from a basal value of 2.6 +/- 0.6 g/kg/d to 2.3 +/- 0.5 g/kg/d (p less than 0.04). The infusion of the prostaglandin antagonists diclofenac or dipyridamole resulted in increases in the plasma insulin level, and as a result glucose turnover decreased in both groups. In the diclofenac group the rate of glucose turnover decreased from 14.4 +/- 1.7 mumol/kg/min to 12.6 +/- 1.3 mumol/kg/min (p less than 0.02). Neither prostaglandin antagonist resulted in any significant change in the rate of NPC.

  5. LSENS - GENERAL CHEMICAL KINETICS AND SENSITIVITY ANALYSIS CODE

    Science.gov (United States)

    Bittker, D. A.

    1994-01-01

    which provides the relationships between the predictions of a kinetics model and the input parameters of the problem. LSENS provides for efficient and accurate chemical kinetics computations and includes sensitivity analysis for a variety of problems, including nonisothermal conditions. LSENS replaces the previous NASA general chemical kinetics codes GCKP and GCKP84. LSENS is designed for flexibility, convenience and computational efficiency. A variety of chemical reaction models can be considered. The models include static system, steady one-dimensional inviscid flow, reaction behind an incident shock wave including boundary layer correction, and the perfectly stirred (highly backmixed) reactor. In addition, computations of equilibrium properties can be performed for the following assigned states, enthalpy and pressure, temperature and pressure, internal energy and volume, and temperature and volume. For static problems LSENS computes sensitivity coefficients with respect to the initial values of the dependent variables and/or the three rates coefficient parameters of each chemical reaction. To integrate the ODEs describing chemical kinetics problems, LSENS uses the packaged code LSODE, the Livermore Solver for Ordinary Differential Equations, because it has been shown to be the most efficient and accurate code for solving such problems. The sensitivity analysis computations use the decoupled direct method, as implemented by Dunker and modified by Radhakrishnan. This method has shown greater efficiency and stability with equal or better accuracy than other methods of sensitivity analysis. LSENS is written in FORTRAN 77 with the exception of the NAMELIST extensions used for input. While this makes the code fairly machine independent, execution times on IBM PC compatibles would be unacceptable to most users. LSENS has been successfully implemented on a Sun4 running SunOS and a DEC VAX running VMS. With minor modifications, it should also be easily implemented on other

  6. Kinetic investigation of wood pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Thurner, F.; Mann, U.; Beck, S. R.

    1980-06-01

    The objective of this investigation was to determine the kinetics of the primary reactions of wood pyrolysis. A new experimental method was developed which enabled us to measure the rate of gas, tar, and char production while taking into account the temperature variations during the wood heating up. The experimental method developed did not require any sophisticated instruments. It facilitated the collection of gas, tar and residue (unreacted wood and char) as well as accurate measurement of the temperature inside the wood sample. Expressions relating the kinetic parameters to the measured variables were derived. The pyrolysis kinetics was investigated in the range of 300 to 400/sup 0/C at atmospheric pressure and under nitrogen atmosphere. Reaction temperature and mass fractions of gas, tar, and residue were measured as a function of time. Assuming first-order reactions, the kinetic parameters were determined using differential method. The measured activation energies of wood pyrolysis to gas, tar, and char were 88.6, 112.7, and 106.5 kJ/mole, respectively. These kinetic data were then used to predict the yield of the various pyrolysis products. It was found that the best prediction was obtained when an integral-mean temperature obtained from the temperature-time curve was used as reaction temperature. The pyrolysis products were analyzed to investigate the influence of the pyrolysis conditions on the composition. The gas consisted mainly of carbon dioxide, carbon monoxide, oxygen, and C/sub 3//sup +/-compounds. The gas composition depended on reaction time as well as reactor temperature. The tar analysis indicated that the tar consisted of about seven compounds. Its major compound was believed to be levoglucosan. Elemental analysis for the char showed that the carbon content increased with increasing temperature.

  7. MCFRS Incidents by Station

    Data.gov (United States)

    Montgomery County of Maryland — This dataset contains the monthly summary data indicating incident occurred in each fire station response area. The summary data is the incident count broken down by...

  8. Police Incident Reports Written

    Data.gov (United States)

    Town of Chapel Hill, North Carolina — This table contains incident reports filed with the Chapel Hill Police Department. Multiple incidents may have been reported at the same time. The most serious...

  9. Three kinds of high-energy Pb ion tracks on the LiF crystal surface at grazing angles of incidence

    CERN Document Server

    Vorobyova, I V

    2002-01-01

    Tracks induced on a surface of a LiF crystal by Pb ions with energy of 4.46 MeV/u were studied by the method of shadow replica electron microscopy. The irradiation was carried out at angles of 0.5 deg. and 2 deg. relative to the surface plane of the crystal. Lengths and widths of three kinds of tracks were compared: (1) surface tracks which are formed on a pure crystal surface; (2) island tracks which are formed in an island film of gold (with island radius and separation of <=5 nm) deposited on the crystal surface prior to irradiation and (3) island tracks which are formed in the same island film pressed against the crystal surface by the carbon layer. It was established: (1) At angle of irradiation of 0.5 deg. , the surface track formation is initiated at a point where the ion has not yet crossed the crystal surface, but rather moves above the surface plane at a distance of <=1 nm. (2) When the island track is formed in the free island film, the islands completely removed from the track zone. (3) When...

  10. Cyber Incidents Involving Control Systems

    Energy Technology Data Exchange (ETDEWEB)

    Robert J. Turk

    2005-10-01

    information available to Department of Homeland Security (DHS) and others who require it. This report summarizes the rise in frequency of cyber attacks, describes the perpetrators, and identifies the means of attack. This type of analysis, when used in conjunction with vulnerability analyses, can be used to support a proactive approach to prevent cyber attacks. CSSC will use this document to evolve a standardized approach to incident reporting and analysis. This document will be updated as needed to record additional event analyses and insights regarding incident reporting. This report represents 120 cyber security incidents documented in a number of sources, including: the British Columbia Institute of Technology (BCIT) Industrial Security Incident Database, the 2003 CSI/FBI Computer Crime and Security Survey, the KEMA, Inc., Database, Lawrence Livermore National Laboratory, the Energy Incident Database, the INL Cyber Incident Database, and other open-source data. The National Memorial Institute for the Prevention of Terrorism (MIPT) database was also interrogated but, interestingly, failed to yield any cyber attack incidents. The results of this evaluation indicate that historical evidence provides insight into control system related incidents or failures; however, that the limited available information provides little support to future risk estimates. The documented case history shows that activity has increased significantly since 1988. The majority of incidents come from the Internet by way of opportunistic viruses, Trojans, and worms, but a surprisingly large number are directed acts of sabotage. A substantial number of confirmed, unconfirmed, and potential events that directly or potentially impact control systems worldwide are also identified. Twelve selected cyber incidents are presented at the end of this report as examples of the documented case studies (see Appendix B).

  11. Incident Information Management Tool

    CERN Document Server

    Pejovic, Vladimir

    2015-01-01

    Flaws of\tcurrent incident information management at CMS and CERN\tare discussed. A new data\tmodel for future incident database is\tproposed and briefly described. Recently developed draft version of GIS-­‐based tool for incident tracking is presented.

  12. Principles of chemical kinetics

    CERN Document Server

    House, James E

    2007-01-01

    James House's revised Principles of Chemical Kinetics provides a clear and logical description of chemical kinetics in a manner unlike any other book of its kind. Clearly written with detailed derivations, the text allows students to move rapidly from theoretical concepts of rates of reaction to concrete applications. Unlike other texts, House presents a balanced treatment of kinetic reactions in gas, solution, and solid states. The entire text has been revised and includes many new sections and an additional chapter on applications of kinetics. The topics covered include quantitative rela

  13. Introduction to chemical kinetics

    CERN Document Server

    Soustelle, Michel

    2013-01-01

    This book is a progressive presentation of kinetics of the chemical reactions. It provides complete coverage of the domain of chemical kinetics, which is necessary for the various future users in the fields of Chemistry, Physical Chemistry, Materials Science, Chemical Engineering, Macromolecular Chemistry and Combustion. It will help them to understand the most sophisticated knowledge of their future job area. Over 15 chapters, this book present the fundamentals of chemical kinetics, its relations with reaction mechanisms and kinetic properties. Two chapters are then devoted to experimental re

  14. Activation-energy for the reaction h+oh--]eaq- - kinetic determination of the enthalpy and entropy of solvation of the hydrated electron

    DEFF Research Database (Denmark)

    Hickle, B.; Sehested, Knud

    1985-01-01

    been determined over the temperature range 15-60 "C as 6.3 f 0.6 kcal/mol(26.4 f 2.5 kJ/mol). From this value and the activation energy of the reverse reaction, the ea; enthalpy of formation AHf = -32.6 f 1.6 kcal/mol (-136.4 f 6.7 kJ/mol) and its standard entropy So = 16.7 f 5.4 cal/(mol deg) (69.8 f...... 22.5 J/(mol deg)) were calculated. The high entropy of solvation A& = 11.7 f 5.4 cal/(mol deg) (49 22.6 J/(mol deg)) when electrons are transferred from gas phase into aqueous solution indicates that the hydrated electron is a structure breaker....

  15. Kinetic Study of Curcumin on Modal Fabric

    Directory of Open Access Journals (Sweden)

    Abu Naser Md. Ahsanul Haque

    2018-03-01

    Full Text Available A kinetic study of curcumin on modal fabric was carried out using an initial dye concentration of 1 g/L at three different temperatures, 70 °C, 85 °C and 100 °C, at pH 7 and an material to liquor ratio of 1:20. Pseudo first-order and pseudo second-order kinetics were applied, and it was found that the adsorption kinetics of curcumin on modal fabric matched the pseudo second-order kinetic model. The activation energy was found to be equal to 71.14 kJ/mol, while the enthalpy and entropy of activation were 68.16 kJ/mol and –66.02 J/molK respectively.

  16. Kinetic Theory of the Inner Magnetospheric Plasma

    CERN Document Server

    Khazanov, George V

    2011-01-01

    This book provides a broad introduction to the kinetic theory of space plasma physics with the major focus on the inner magnetospheric plasma. It is designed to provide a comprehensive description of the different kinds of transport equations for both plasma particles and waves with an emphasis on the applicability and limitations of each set of equations. The major topics are: Kinetic Theory of Superthermal Electrons, Kinetic Foundation of the Hydrodynamic Description of Space Plasmas (including wave-particle interaction processes), and Kinetic Theory of the Terrestrial Ring Current. Distinguishable features of this book are the analytical solutions of simplified transport equations. Approximate analytic solutions of transport phenomena are very useful because they help us gain physical insight into how the system responds to varying sources of mass, momentum and energy and also to various external boundary conditions. They also provide us a convenient method to test the validity of complicated numerical mod...

  17. Fundamental aspects of plasma chemical physics kinetics

    CERN Document Server

    Capitelli, Mario; Colonna, Gianpiero; Esposito, Fabrizio; Gorse, Claudine; Hassouni, Khaled; Laricchiuta, Annarita; Longo, Savino

    2016-01-01

    Describing non-equilibrium "cold" plasmas through a chemical physics approach, this book uses the state-to-state plasma kinetics, which considers each internal state as a new species with its own cross sections. Extended atomic and molecular master equations are coupled with Boltzmann and Monte Carlo methods to solve the electron energy distribution function. Selected examples in different applied fields, such as microelectronics, fusion, and aerospace, are presented and discussed including the self-consistent kinetics in RF parallel plate reactors, the optimization of negative ion sources and the expansion of high enthalpy flows through nozzles of different geometries. The book will cover the main aspects of the state-to-state kinetic approach for the description of nonequilibrium cold plasmas, illustrating the more recent achievements in the development of kinetic models including the self-consistent coupling of master equations and Boltzmann equation for electron dynamics. To give a complete portrayal, the...

  18. Kinetic equation solution by inverse kinetic method

    International Nuclear Information System (INIS)

    Salas, G.

    1983-01-01

    We propose a computer program (CAMU) which permits to solve the inverse kinetic equation. The CAMU code is written in HPL language for a HP 982 A microcomputer with a peripheral interface HP 9876 A ''thermal graphic printer''. The CAMU code solves the inverse kinetic equation by taking as data entry the output of the ionization chambers and integrating the equation with the help of the Simpson method. With this program we calculate the evolution of the reactivity in time for a given disturbance

  19. Estimation of free energy barriers in the cytoplasmic and mitochondrial aspartate aminotransferase reactions probed by hydrogen-exchange kinetics of C alpha-labeled amino acids with solvent

    International Nuclear Information System (INIS)

    Julin, D.A.; Wiesinger, H.; Toney, M.D.; Kirsch, J.F.

    1989-01-01

    The existence of the postulated quinonoid intermediate in the cytoplasmic aspartate amino-transferase catalyzed transamination of aspartate to oxaloacetate was probed by determining the extent of transfer of tritium from the C alpha position of tritiated L-aspartate to pyridoxamine 5'-phosphate in single turnover experiments in which washout from the back-reaction was obviated by product trapping. The maximum amount of transferred tritium observed was 0.7%, consistent either with a mechanism in which a fraction of the net transamination reaction proceeds through a quinonoid intermediate or with a mechanism in which this intermediate is formed off the main reaction pathway. It is shown that transfer of labeled hydrogen from the amino acid to cofactor cannot be used to differentiate a stepwise from a concerted transamination mechanism. The amount of tritium transferred is a function of the rate constant for torsional equilibration about the epsilon-amino group of Lys-258, the presumptive abstractor of the C alpha proton; the relative rate constants for hydrogen exchange with solvent versus cofactor protonation; and the tritium isotope effect on this ratio. The free energy barriers facing the covalent intermediate between aldimine and keto acid product (i.e., ketimine and possibly quinonoid) were evaluated relatively by comparing the rates of C alpha-hydrogen exchange in starting amino acid with the rates of keto acid formation. The value of theta (= kexge/kprod) was found to be 2.6 for the reaction of cytoplasmic isozyme with aspartate and ca. 0.5 for that of the mitochondrial form with glutamate

  20. The Application of Biomimicry in Kinetic Facades

    Directory of Open Access Journals (Sweden)

    Wijdan Deyaa Abdul Jalil

    2016-10-01

    Full Text Available Biomimicry, as a way of thinking to go back to nature for inspiration, has its impact on many contemporary technological achievements. Some of them are used to design and construct kinetic facades in architecture, because of the importance role of facades in reducing sun radiation, that enter the building through using shading systems and components. In light of this, research problem is determined: "Do technologies which are inspired by biomimicry effect shading in kinetic facades through its characteristics in materials and the mechanics. So the research identifies its goal as: "To identify the types of kinetic facades in buildings and their characteristics as materials and shading mechanism associated with the biomimicry. The research explains the basic types of kinetic facades depending on the technology and materials used to provide the possibility of reducing solar radiation that enters the building. It also compares the case studies which have been chosen in their inspiration concept from biological world, which reflect on the system used of protecting against sun and reducing energy consumption as the designer teams suggest. The research concluded that kinetic façade which is depending on smart materials is self-responding and don't need energy to operate, so it is better in reducing consumption of energy.